LINKAGES BETWEEN CLIMATE CHANGE AND STRATOSPHERIC OZONE DEPLETION ROBERT C. WORREST,* KATIE D, SMYTHE,** ALEXANDER M. TAIT** *U.S, Environmental Protection Agency, Office of Research and Development, Washington, DC; **Science and Policy Associates, Washington, DC INTRODUCTION Alterations of the earth's atmosphere by human activities are now of regional and global proportion. In the last decade scientists, policy makers, and the general public have focused increasing concern on ozone depletion in the upper atmosphere and on global climate change. These two problems are closely interrelated and both are of truly global scale. Two primary areas link the issue of stratospheric ozone depletion to global climate change: atmospheric processes and ecological processes. Atmospheric processes establish a linkage through the dual roles of certain trace gases in promoting global warming and in depleting the ozone layer. The primary radiatively active trace gases are carbon dioxide, nitrous oxide, chlorofluorocarbons, methane, and tropospheric ozone. In the troposphere, the atmosphere up to 10 miles above the earth's surface, these compounds function as greenhouse gases. At increased levels they can contribute to global climate change. Many of these gases also influence the concentration of ozone in the stratosphere, the atmospheric layer located between 10-30 miles above the earth's surface. This diffuse layer of ozone in the stratosphere protects life on earth from harmful solar radiation. A reduction of this layer could have very important impacts on the earth's systems. The second mode of interaction revolves around various ecological processes. Physical, chemical, and biological activities of plants and animals are affected directly by global climate change and by increased ultraviolet radiation resulting from depletion of stratospheric ozone. The purposes of this paper are to: 1) provide general background on the stratospheric ozone depletion issue, and 2) discuss the linkages surrounding both the atmospheric and ecological processes. BACKGROUND The natural distribution of ozone in the earth's atmosphere is not uniform. It is concentrated primarily in a thin layer in the stratosphere where it blocks most of the ultraviolet radiation in the 290 to 320 nm range from reaching the earth's surface. This is known as the ultraviolet-B (or UV-B) range and it can be damaging to humans, biological organisms, and man-made materials. Many gases emitted from man's industrial and agricultural activities can accumulate in the earth's atmosphere and ultimately contribute to alterations in the vertical distribution of stratospheric ozone. These gases accumulate in the lower atmosphere (troposphere) and then gradually migrate upward into the stratosphere where they contribute to depletion of stratospheric ozone. The atmospheric and chemical processes involved in the destruction of ozone are extremely complex and are reviewed elsewhere [e.g., 1], but the following section will summarize one the most important interactions. 1 ------- Scientists have demonstrated that in recent years the release into the atmosphere of halogens containing chlorine and bromine — such as chlorofluorocarbons (CFCs) and halons — has resulted in the destruction of the protective ozone layer in the stratosphere. Short wavelength radiation hitting the stratosphere causes a breakup of the chlorofluorocarbons releasing the chlorine radicals (see figure 1). A chlorine radical destroys stratospheric ozone through a catalytic cycle producing oxygen molecules. After converting ozone to oxygen, the radical—now chlorine oxide—then reacts with an oxygen atom from another ozone molecule and emerges unchanged, ready to destroy more ozone. FIGURE 1. The catalytic cycle of a chlorine radical breaking down ozone into oxygen molecules. Less ozone in the stratosphere will result in a greater transmission of ultraviolet radiation to the surface of the earth, causing detrimental effects. Because of the long atmospheric lifetimes of CFCs and halons, scientists expect stratospheric ozone to continue to decrease into the middle of the next century even if emissions are curtailed worldwide [2]. TABLE I. Trace gases affecting ozone concentrations and global climate change. Trace Gas (Formula) Primary Source Ave. Life in Atmos. ODP* GP** CFC-11 (CFC13) Refrigerant/AC, 75 Plastic Foams, Aerosols yrs 1.0 0.40 CFC-12 (CF2C12) Refrigerant/AC,110 1. Plastic Foams, Sterilants ,0 1.00 CFC-113 (C2F3C13) Solvents 90 0.8 0.3- ¦0.8 Halon 1211 (CF2ClBr) Fire Exting. 25 3.0 2 Halon 1301 (CF3Br) Fire Exting. 110 10.0 0.80 Carbon (CC14) Tetrachloride Industrial 67 Processes 1.1 0.05 Methyl Chloroform (CH3CC13) Industrial and 8 Natural Processes 0.1 0.01 Nitrous Oxide (N20) Fossil Fuels 150 — 0.016 Methane (CH4) Biogenic Activity, 11 — 0.001 Carbon Dioxide (C02) Carbon Monox. (CO) Fossil Fuels Motor Vehicles Fossil Fuels 7 0.4 0.00005 2 ------- * ozone depletion potential (CFC-11 =1.0) ** greenhouse potential (CFC-12 =1.0) Table 1 provides a summary of the major trace gases that contribute to ozone depletion, including their primary uses, atmospheric lifetime, and projected annual increase. Currently, the primary focus of regulations and mitigation options are on CFCs and halons, as depicted in the Montreal Protocol [3]. The treaty document was officially ratified in December 1988; regulatory provisions become effective in July 1989. The agreement calls for a freeze of CFC production (at 1986 levels) by 1989, a 20 percent decrease in production by 1993, and an additional 30 percent decrease by 1998. Several recent national and international work group reports detailed discussions of the growing concern about stratospheric ozone depletion and assessment of scientific bases underlying such concern [e.g., 1, 4, 5]. A report by the Ozone Trends Panel has also highlighted the issue of stratospheric ozone depletion [6]. The panel's report describes the global decrease in stratospheric ozone in recent years and the probable role of CFCs and other ozone-depleting compounds in the development of the Antarctic ozone hole. ATMOSPHERIC INTERACTIONS Many of the atmospheric trace gases, such as chloro-fluorocarbons, are relatively transparent in the visible region of the solar spectrum. They do, however, absorb the long wavelength radiation that is radiated back from the surface of the earth, resulting in the greenhouse effect. In addition to CFCs, other gases contribute to the greenhouse effect, including: carbon dioxide, methane, nitrous oxide, and tropospheric ozone. The effects of these gases on global warming is cumulative because each blocks different wavelength radiation. Their concentrations have been increasing over time, some more dramatically than others. This point is particularly important because of their relatively long atmospheric lifetimes, especially CFCs, halons and nitrous oxide. Chlorofluorocarbons (CFCs). The release of CFCs and other chlorine-containing compounds decreased initially in the 1970s as a result of regulatory action to ban selected, non- essential CFC compounds used as aerosol propellants. This regulation was enacted in several countries, including the United States. Currently, CFC production and consumption are increasing due at least in part to the involvement of newly industrialized and lesser developed countries in CFC use. In addition to breaking down ozone through the action of chlorine radicals, chlorofluorocarbons contribute to the greenhouse effect. Estimates put the CFC contribution to global temperature change at 20-25 percent, although under the Montreal Protocol it would be reduced to 15-20 percent. Nitrous Oxide (N20). Nitrous oxide in the atmosphere originates from both natural and man-made sources, including many bacterial processes involved in the nitrification or denitrification cycles. Recently, nitrous oxide has been increasing at a rate of ------- V about 0.2% annually. In the atmosphere N20 is partly converted into nitrogen oxides (NOx). Nitrous oxide (N20) plays a role in both ozone depletion and global climate change. The N20 functions as a greenhouse gas contributing to global warming. Converted to nitrogen oxides (NOx) it destroys stratospheric ozone in a catalytic cycle similar to that of chlorine radicals. On the other hand, nitrogen oxides can serve as a temporary sink for the ozone depleting chlorine monoxide (CIO), so the net effect is uncertain. NOx also is a precursor to acid deposition. Carbon Dioxide (C02). The concentration of C02 has been increasing in recent years by an average of about 0.5% annually. Carbon dioxide links the issue of stratospheric ozone depletion to that of the global climate change issue primarily because of its role as a greenhouse gas. As such, it will absorb solar radiation being radiated from the surface of the earth and re-radiate it in all directions increasing the global warming. Because it is a greenhouse gas C02 modifies the temperature structure of the atmosphere, cooling the stratosphere# Less ozone is destroyed if the stratosphere is cooler, so the effect of C02 acting alone is to decrease ozone depletion in the stratosphere. Methane (CH4). Methane has been increasing fairly constantly at a rate of about 1% annually. Resulting from both natural and man-made processes, methane is involved in several important reactions in the atmosphere. Through its effect on the amounts of water vapor in the stratosphere methane can lead to destruction of stratospheric ozone. Water droplets may act as a surface upon which the reactions that destroy ozone occur. The increase or decrease of ozone depletion will depend upon where the water vapor is produced. Ozone depletion will increase if water vapor increases in the stratosphere. But an increase in water vapor in the troposphere will heighten the greenhouse effect—water vapor is the most important greenhouse gas—and decrease ozone depletion through cooling the stratosphere. A further effect of methane occurs in the troposphere. Here, when methane is oxidized, it will produce an increase in the amount of tropospheric ozone. This reaction occurs in the presence of nitrogen oxide. Natural sources of methane include natural wetlands, arctic tundra, agricultural crops such as rice paddies, and ruminate animals. Man-made sources of CH4 include the production of fossil fuels such as natural gas and oil, and cement production. The natural processes contribute about half of the total methane production. Carbon Monoxide (CQ^. Carbon monoxide is not a radiatively important trace gas, but it is involved indirectly in both stratospheric ozone destruction and global warming. Carbon monoxide controls the concentration of the hydroxy1 radical (OH) in the troposphere, which has a direct effect on the concentration of methane. The concentration of methane, as described earlier, plays a role in the amount of tropospheric ozone as well as stratospheric ozone. Methane is also a very important contributor to the greenhouse effect. Although calculations are highly variable, estimates indicate that the concentration of carbon monoxide is increasing at about 1% per year. 4 ------- Stratospheric and Tropospheric Ozone ((A . Based on current scenarios, the stratospheric component of the total ozone column is calculated to decrease over time, whereas the tropospheric constituents of the total ozone column will increase. Whether or not there will be an overall increase in the level of ultraviolet radiation reaching the surface of the earth is still uncertain. Even if the levels of ultraviolet radiation at the earth's surface were not to change, the photochemical reactions involving ultraviolet radiation and the interaction of ozone with various other atmospheric gases would alter the distribution of ozone in the atmospheric column. Changes in the concentration and altitude of ozone will play a major role in altering temperature and atmospheric processes affecting current climate and perhaps add to long-term global climate change. Increased levels of ultraviolet radiation reaching the earth's surface also will increase the production of ozone at ground level through photochemical reactions. These conditions affect regional air quality. Tropospheric ozone formation takes place in the presence of nitrogen oxide. In addition, hydrogen peroxide (H202) is produced, which is a strong oxidant and a catalyst in the production of sulfuric acid from sulfur dioxide. These two processes illustrate the linkage between stratospheric ozone depletion and acid deposition. Sulfur dioxide and nitrogen oxides are the two major precursors to acid deposition. Trace gases affecting ozone also contribute to global climate change. Any efforts by humans to address the potential problems in either area will influence the other. If global warming were to begin, efforts to address the rise in greenhouse gases could increase ozone depletion. Restraints imposed on the buildup of carbon dioxide, methane, and nitrous oxide to control their contribution to global warming, might reduce their role as moderators of potential ozone depletion in high CFC emission scenarios [7]. ECOLOGICAL INTERACTIONS A major consequence of decreasing the ozone layer is an increase in the transmission of UV-B radiation to the earth's surface. Scientists have identified many potentially serious effects on the environment and on human health from increased exposure to UV-B radiation. These include damage to: agricultural crops, forests, marine organisms, human health (eye disease, immune system, skin cancer), and certain materials. Changes associated with an altered global climate, such as increased C02 levels, interact with the effects of UV-B radiation. Terrestrial Ecosystems. In assessing the impact of increased exposure of crops and terrestrial ecosystems to UV-B radiation it must be recognized that existing knowledge is in many ways deficient. The effects of enhanced levels of UV-B radiation have been studied in species from only a few representatives of the major terrestrial ecosystems. We derive most of our knowledge from studies focused upon agricultural crops and conducted at mid- latitudes. Despite uncertainties due to the complexities of field experiments, the data presently available suggest that plant photosynthesis is vulnerable to increased levels of solar UV-B radiation [1]. Unlike drought or other geographically isolated stresses, stratospheric ozone depletion would affect all areas of the world, including ecosystems whose UV-B sensitivity has not been investigated. 5 ------- In general, UV radiation causes reduced leaf and stem growth, lower total dry weight, and lower photosynthetic activity in sensitive cultivars of plant species [8]. Less photosynthesis decreases the amount of C02 fixed by plants and exacerbates the rise in C02 levels. Higher C02 may lead to global warming. This shows a direct link from an effect of stratospheric ozone depletion through terrestrial ecosystems to climate change. Increased levels of UV-B radiation also may affect forest productivity. Only limited data are available on coniferous species, but about one-half of the species of seedlings studied were adversely affected by UV-B radiation [9]. Existing data also suggest that increased UV-B radiation will modify the distribution and abundance of plants. Even small changes in competitive balance over a period of time can result in large changes in community structure and composition [10]. Aquatic Ecosystems. Current evidence indicates that ambient solar UV-B radiation is an important limiting ecological factor in marine ecosystems. Even small increases of UV-B exposure could result in significant ecosystem changes [11]. In marine plant communities a change in species composition rather than a decrease in net production would be the probable result of enhanced UV-B exposure [12]. A change in community composition at the base of food webs may produce instabilities within ecosystems that likely would affect higher trophic levels [13]. Inhibition of marine microbial activity by increasing UV-B radiation could have important consequences for several global biogeochemical cycles. Phytoplankton photosynthesis in the upper layer of the oceans provides a sink for approximately 80% of the anthropogenic CO2 released to the atmosphere. Bacterial activity in the oceans provides probably the most important global source of CH3I and CH3C1 (the only significant natural source of chlorine to the stratosphere). Microorganisms in aquatic ecosystems produce large quantities of methane and nitrous oxide. Chemical and photochemical oxidation of natural organic matter in water bodies produces carbon monoxide. Enhanced UV-B radiation, resulting from stratospheric ozone depletion, can alter these processes and affect the levels of the various greenhouse gases in the atmosphere. Human Health. Depletion of the ozone layer, resulting in large part from CFCs in the stratosphere, leads to increased UV-B radiation. The UV-B radiation has many adverse affects on human health. Kripke [14], van der Leun [15], and the U.S. EPA [1] summarize the potential health effects of UV-B radiation. Probably the best defined health effects are increases in skin cancer cases expected to result from even small increases in UV-B radiation reaching the earth's surface. However, skin cancer affects only a small minority of the world's population, light- skinned Caucasians, and therefore is not a significant global problem. Another important health concern — with potentially more extensive impacts on more diverse human populations than skin cancer — is the effect of increased UV- B radiation on human immune suppression. Adverse ocular effects have also been documented from enhanced UV-B radiation, including an increase in the incidence of cataracts in exposed populations. CFCs, as mentioned above, are important greenhouse gases and contribute to global climate change. Several elements of climate change could have important human health effects. Higher temperatures will increase heat stress in humans, especially among the elderly. Increased temperature combined with changes in precipitation distribution could alter the geographic distribution of diseases and parasites, providing vectors for the northward movement of tropical diseases. 6 ------- STATE OF KNOWLEDGE Table 2 illustrates differences in our state of knowledge regarding various anticipated biological effects and their potential global impact, as viewed by an expert subcommittee of EPA's Science Advisory Board [16]. One of the present dilemmas we face is that our current state of knowledge of effects that have the greatest potential for widespread global impacts is low. For example, the current knowledge of potential effects of increased UV-B radiation on the human immune system is relatively low, but the global impact on human health could be quite high. TABLE II. Potential effects of increased UV-B radiation resulting from decreased stratospheric ozone Potential Effects State of Knowledge Global Impact Plant Life Low High Aquatic Life Low High Skin Cancer Moderate to high Moderate Immune System Low High Cataracts Moderate Low Climate impacts* Moderate Moderate Tropospheric Ozone Moderate Low** * Contribution of both stratospheric ozone depletion itself and gases causing such depletion to climate changes. ** Impact could be high in selected areas typified by local or regional scale surface-level ozone pollution problems. Modified from Kripke [16]. POLICY INFORMATION NEEDS Many uncertainties remain regarding the effects of stratospheric ozone depletion and global climate change. With both of these issues, scientists should structure research around questions that are explicitly relevant to policy decisions. Using "policy-relevant questions" as the framework for research provides the rationale for undertaking specific initiatives. The questions that follow are based on fundamental information needs relevant to stratospheric ozone 7 ------- depletion, including a question addressing the information needed about linkages between ozone depletion and climate change (question 4). 1) How widespread are the potential effects of UV-B radiation? What populations, systems or substances are at greatest risk? An increase in UV-B radiation will continue to exert some degree of influence on man and the environment for the foreseeable future. This stress will transcend regional and national boundaries, exerting significant effects on widely separated ecosystems and populations. These two attributes make understanding the effects of UV-B radiation on biological and human systems of critical importance. 2) How intensive are the effects of UV-B irradiance? What are the doses that would pose a significant risk? The response of systems to UV-B radiation may differ significantly for different life stages of the same species as well as by latitude and season. What are the specific dose-response relationships, and what mechanisms are involved? Identification of basic and common mechanisms of damage will allow extrapolation of dose-response models to other systems not yet studied. 3) If the dose of UV-B radiation is reduced, what is the anticipated rate and extent of recovery of sensitive systems? Organisms and ecosystems generally (but not always) recover from environmental stress. It is important to know to what degree and at what rate individual organisms and ecosystems can repair the damage inflicted by enhanced UV-B irradiance. In managed ecosystems (agriculture and silvaculture), UV-B tolerant species may replace less tolerant species. In natural ecosystems some species may be able to adapt over time to increasing UV-B irradiance. 4) What interactions occur between increased UV-B radiation, global climate change and atmospheric pollutants? The composition of the atmosphere depends to a large degree on the natural and man-made emissions of greenhouse gases such as carbon dioxide, CFCs, methane, and nitrous oxide. If new data suggested that increasing UV-B radiation would alter biogeochemical cycles involving these chemicals and result in a disruption of ecosystems or change in global climate, additional regulation to protect the stratospheric ozone layer may be necessary. 5) What mitigation options can be applied? To which systems? Chemicals with less ozone-depleting potential can be used as alternative substances, such as for aerosol propellants. But substitutes are not currently available for some ozone- depleting compounds. Recovery and reuse of substances also is a viable option. We also need to develop mitigative responses to the effects of UV-B radiation, including the replacement of sensitive species with more UV-B tolerant species. Options relevant to the human system are more tenuous and are important to investigate. Policy makers and scientists should periodically review and revise this list of questions to reflect the current state of science. CURRENT ACTIVITIES The depletion of stratospheric ozone and subsequent increase in UV-B radiation is a problem of global proportions, and one that is not occurring in an environmental vacuum. Other changes are occurring, including global climate change and acid deposition/air pollution. Scientists must examine these issues collectively through an integrated research approach. 8 ------- A concerted effort is recently underway in the United States and numerous other countries in response to plans and initiatives under the International Geosphere-Biosphere Program (IGBP), also known as the Global Change Program. IGBP, which was launched in 1986 by the International Council of Scientific Unions [17], is the first international attempt to integrate research on global climate change and stratospheric ozone depletion. Reports by the National Academy of Sciences' Committee on Global Change [18], and the White House's Committee on Earth Sciences [19] describe the work proposed by the U.S. federal agencies. Agencies involved in the U.S. Global Change Program include the following: Department of Agriculture (USDA) Department of Energy (DOE) Department of the Interior (DOI) Environmental Protection Agency (EPA) National Oceanic and Atmospheric Administration (NOAA) National Science Foundation (NSF) National Aeronautics and Space Administration (NASA) Success in addressing the global problems facing us today relies upon such international and interagency coordination. It is also important to address the related global problems as parts of a whole: stratospheric ozone depletion, global climate change, and acid deposition are intricately linked. 9 ------- REFERENCES 1. U.S. EPA. 1987. Risks to crops and terrestrial ecosystems from enhanced UV-B radiation. Pages (11)1-31 in Assessing the Risks of Trace Gases that Can Modify the Stratosphere, J. Hoffman (ed.) USEPA 400/1-87/001C. U.S. Env. Prot. Agency, Washington, DC. 2. Crawford, M. 1987. Landmark ozone treaty negotiated. Science, 237, 1557. 3. United Nations Environment Programme. 1987. Montreal Protocol on Substances that Deplete the Ozone Layer - Final Act. UNEP, Nairobi, Kenya. 4. Schneider, T.; Lee, S.D.; Grant, L.D.; & Wolters, G.; eds. 1988. Atmospheric ozone research and its policy implications: third US-Dutch international symposium. Elsevier, Amsterdam, The Netherlands (in press). 5. World Meteorology Organization (WMO) and Canada Department of the Environment. 1988. Proceedings of the World Conference on the Changing Atmosphere. 6. Watson, R.T. and Ozone Trends Panel, Prather, M, J. and Ad Hoc Theory Panel, and Kurylo M.J. and NASA Panel for Data Evaluation. 1988. Present State of Knowledge of the Upper Atmosphere 1988: An Assessment Report. NASA Reference Publication 1208. National Aeronautics and Space Administration, Office of Space Science and Applications, Washington, DC. 7. Miller, A.S. and I. Mintzer. 1986. The sky is the limit: strategies for protecting the ozone layer. Research Report #3, World Resources Institute, Washington, DC. 8. Tevini, M. and W. iwanzik. 1986. Effects of UV-B radiation on growth and development of cucumber seedlings. In Stratospheric Ozone Reduction, Solar UV Radiation and Plant Life, R.C. Worrest and M.M. Caldwell (eds.), Springer-Verlag, Heidelberg. 9. Teramura, A.H. and J. Sullivan. 1988. Annual Report to the U.S. Environmental Protection Agency: The Effects of Changing Climate and Stratospheric Ozone Modification on Plants. Univ. of Maryland, College Park, Maryland (USA). 10. Gold, W.G. and M.M. Caldwell. 1983. The effects of ultraviolet-B radiation on plant competition in terrestrial ecosystems'. Physiol. Plant. 58. 435-444. 11. Damkaer, D.M. 1982. Possible influence of solar UV radiation in the evolution of marine zooplankton, In The Role of Solar Ultraviolet Radiation in Marine Ecosystems, J. Calkins (ed.), Plenum, New York. 12. Worrest, R.C, 1983, Impact of solar ultraviolet-B (290-320 rati) upon marine microalgae. Physiol. Plant. Ji£, 428-434. 13. Kelly, J.R. 1986. How might enhanced levels of solar UV-B radiation affect marine ecosystems? In Effects of Changes in Stratospheric Ozone and Global Climate, J.G. Titus (ed.). U.S. Environ. Prot. Agency and United Nations Environment Prog., Washington, D.C. 14. Kripke, M. 1988. Health effects of stratospheric ozone depletion: an overview. In: Schneider, T.; Lee, S.D.; Grant, L.D.; & Wolters, G.; eds. 1988. 10 ------- Atmospheric ozone research and its policy implications: third US-Dutch international symposium. Elsevier, Amsterdam, The Netherlands (in press). 15. van der Leun, J.C. 1988. Effects of increased UV-B on human health. In: Schneider, T.; Lee, S.D.; Grant, L.D.; & Wolters, G.; eds. 1988. Atmospheric ozone research and its policy implications: third US-Dutch international symposium. Elsevier, Amsterdam, The Netherlands (in press). 16. Kripke, M. 1987. Review of EPA's Assessment of the Risks of Stratospheric Modification. Prep, by the Stratospheric Ozone Subcommittee, Science Advisory Board. SAB-EC-87-025, U.S. Environ. Prot. Agency, Washington, DC. 17. international Council of Scientific Unions. 1986. The International Geosphere-Biosphere Program: A Study of Global Change. Rept. No. 1. ICSU 21st General Assembly, Bern, Switzerland. 18. National Academy of Sciences. 1988. Toward an Understanding of Global Change: Initial Priorities for U.S. Contributions to the International Geosphere-Biosphere Program. National Academy Press, Washington, DC. 19. Committee on Earth Sciences. 1989. Our Changing Planet: A U.S. Strategy for Global Change Research. Rept. to Accompany the President's FY90 Budget. Washington, DC. 11 ------- NOTICE This document has been reviewed in accordance with U.S. Environmental Protection Agency policy and approved for publication. Mention of trade names or commercial products does not constitute endorse- ment or recommendation for use. ii ------- TECHNICAL REPORT DATA (Please read Instructions on the reverse before completing' 1. REPORT NO. 2. EPA/600/D-89/127 3-Re PB90-112590 4, TITLE AND SUBTITLE Linkage Between Climate Change and Stratospheric Ozone Depletion 5. REPORT OATE ) 6. PERFORMING ORGANIZATION CODE PFhiitOoijts 7. AUTHOR(S) R. C. Worrest A. M. Tait K. D. Smythe 8. PERFORMING ORGANIZATION REPORT NO. 9. PERFORMING ORGANIZATION NAME AND ADDRESS U. S. EPA Office of Research and Development/OEPER 401 M Street, SW Washington, DC 20460 10. PROGRAM ELEMENT NO. 11. CONTRACT/GRANT NO. 12. SPONSORING AGENCY NAME AND ADDRESS Center for Environmental Information, INC. 33 S. Washington St Rochester, NY 14608 13. TYPE OF REPORT AND PERIOD COVERED 14. SPONSORING AGENCY CODE EPA/600/16 15. SUPPLEMENT ARY NOTES 16. ABSTRACT Two primary areas link the issue of stratospheric ozone depletion to global climate change: atmospheric processes and ecological processes. Atmospheric processes establish a linkage through the dual roles of certain trace gases in promoting global warming and in depleting the ozone layer. The primary radiatively active trace gases are carbon dioxide, nitrous oxide, chlorofluorocarbons, methane, and tropospheric ozone. In the troposphere, the atmosphere up to 10 miles above the earth's surface, these compounds function as greenhouse gases. At increased levels they can contribute to global climate change. Many of these gases also influence the concentration of ozone in the stratosphere, the atmospheric layer located between 10 -30 miles above the earth's surface. This diffuse layer of ozone in the stratosphere protects life on earth from harmful solar radiation. A reduction of this layer could have very important impacts on the earth's systems. The second mode of interaction revolves around various ecological processes. Physical, chemical, and biological activities of plants and animals are affected directly by global climate change and by increased ultraviolet radiation resulting from depletion of stratospheric ozone. 17. KEY WORDS AND DOCUMENT ANALYSIS DESCRIPTORS b. I DENTIF IERS/OPEN ENDED TERMS c. COSATl Field/Group C» loWl C Uvvv«»,<4* U* A i c. ue^lrl! (s f-e«vs.W ft 13. DISTRIBUTION STATEMENT 19, SECURITY CLASS (ThisReport) 21. NO. OF PAGES IV 20. SECURITY CLASS (This page) 22. PRICE EPA Form 2220-1 (9-73) REPRODUCED BY U.S. DEPARTMENT OF COMMERCE NATIONAL TECHNICAL INFORMATION SERVICE SPRINGFIELD, VA. 22161 ------- |