BACKGROUND DOCUMENT
REPORT ON REVISIONS TO 5th EDITION AP-42
CHAPTER 15 - ORDNANCE DETONATION
EMISSION FACTORS DEVELOPED BASED ON EXPLODING ORDNANCE EMISSION STUDY
PHASE II SERIES 6 TESTING CONDUCTED AT ABERDEEN PROVING GROUND,
MARYLAND
Prepared for:
U.S. Army Environmental Center
ATTN: SFIM-AEC-ATT
Aberdeen Proving Ground, Maryland 21010-5401
September 2006
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NOTICE
The information in this document has been funded by the U.S. Army Environmental Center
(USAEC) and prepared by MACTEC Federal Programs, Inc., under Contract No. GS-10F-0131K, Order
No. W911S0-04-F-0016. It has been reviewed by the U.S. Environmental Protection Agency (EPA)
Office of Air Quality Planning and Standards (OAQPS) and has been approved for publication. Mention
of trade names or commercial products does not constitute endorsement or recommendation for use.
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TABLE OF CONTENTS
1.0 INTRODUCTION 1
2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS 3
2.1 Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide 3
2.2 Sulfur Hexafluoride, Ammonia, Carbon Monoxide, Carbon Dioxide, and Methane 5
2.3 Total Suspended Particulate 6
2.4 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 or 2.5 Microns .. 6
2.5 Metals 6
2.6 Volatile Organic Compounds 6
2.7 Semivolatile Organic Compounds and Polycyclic Aromatic Hydrocarbons 7
2.8 Dioxin and Furan Compounds 7
2.9 Acid Gases 7
2.10 Hydrogen Cyanide 7
2.11 Aldehydes and Carbonyl Compounds 7
2.12 Hydrocarbons, n-Hexane, and Sulfur Hexafluoride 8
2.13 Energetic Materials 8
2.14 Total Carbon 8
2.15 Hexavalent Chromium 9
2.16 Perchlorate 9
2.17 Mercury 9
3.0 TEST DATA ANALYSIS AND RATINGS 9
3.1 EPA Guidance Regarding Test Data Quality Ratings 9
3.2 Analysis of Test Data 10
3.3 Test Data Quality Ratings 16
4.0 EMISSION FACTOR CALCULATIONS 18
4.1 Correction of Sample Volume to Standard Conditions 20
4.2 Incorporation of Analytical Detection Limits to the Test Data 20
4.3 Determination of Background Concentration 20
4.4 Determination of Test Compound Concentration 21
4.5 Determination of Background-Corrected Concentration 21
4.6 Determination of Dilution-Corrected Concentration 23
4.7 Determination of Mass of Compound Released 23
4.8 Determination of Emission Factors 24
4.9 Determination of Average Emission Factors 24
4.10 Determination of Total Emission Factors for DODIC B642 24
4.11 Determination of Total Emission Factors for DODIC C511 24
4.12 Determination of Average Emission Factors for DODIC G911 25
5.0 EMISSION FACTOR RATINGS 25
5.1 Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data 26
5.2 Emission Factor Ratings Assigned - Based on All Available Test Data 26
6.0 REFERENCES 36
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TABLE OF CONTENTS (cont.)
APPENDIX A: COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
ORDNANCE INCLUDED IN EXPLODING ORDNANCE EMISSION STUDY
PHASE II SERIES 6 TESTING AT ABERDEEN PROVING GROUND,
MARYLAND
APPENDIX B: NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN EXPLODING
ORDNANCE EMISSION STUDY PHASE II SERIES 6 TESTING AT ABERDEEN
PROVING GROUND, MARYLAND
APPENDIX C: PUBLIC COMMENTS ON AP-42 SECTIONS FOR ORDNANCE INCLUDED IN
EXPLODING ORDNANCE EMISSION STUDY PHASE II SERIES 6 TESTING AT
ABERDEEN PROVING GROUND, MARYLAND
LIST OF TABLES
No. Title Page
1 Ordnance for Which Emission Factors Were Developed 1
2 Ordnance Net Explosive Weight 2
3 Sampling and Analytical Methods Used 4
4 Selected Analytical Method for Compounds Analyzed Using Two Analytical Methods 12
5 Compounds for Which Large Relative Percent Differences Were Noted Between Test Runs 14
6 Compounds Found in the Method Blank at Levels Between 20 Percent and 50 Percent of
Both Test Values 16
7 Downgraded Data Quality Ratings 16
8 Ordnance Categorization for Emission Factor Correlation Assessment 27
LIST OF FIGURES
No. Title Page
1 Calculation of background-corrected concentration 22
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1.0 INTRODUCTION
Due to the lack of credible data concerning emissions from training ordnance when used in their
tactical configurations, the U.S. Army Environmental Center (USAEC) established a program to quantify
emissions from the detonation of ordnance. This document presents background information concerning
the development of air emission factors for five types of ordnance used during training exercises at U.S.
Army installations. The air emission factors were developed from test data collected by USAEC.
Ordnance for which emission factors have been developed and their corresponding AP-42 sections are
identified in Table 1. To help readers easily find those emission factors of interest, the ordnance are
organized according to their Department of Defense Identification Code (DODIC).
TABLE 1 ORDNANCE FOR WHICH EMISSION FACTORS WERE DEVELOPED
DODIC
Ordnance Description
AP-42 Section
B642
M720 60-mm High Explosive Cartridge (projectile only)
15.2.10
C511a
M490 105-mm Target Practice Tracer Cartridge
(Ml3 tracer only)
15.3.5
G911
MK3A2 Offensive Hand Grenade
15.5.4
K051
M604 Anti-Tank Practice Mine Fuze
15.7.2
L720
M26 Target Kill Simulator
15.8.20
a The M13 tracer that was tested is also a component of DODIC C520. the M724 105-mm Target
Practice Discarding Sabot Tracer (TPDS-T) Cartridge: therefore, the emission factors presented
herein are also applicable to the burning of the DODIC C520 tracer.
It should be noted that the air emission factors documented herein for DODIC B642 are only
associated with the detonation of the projectile/warhead. It should also be noted that the air emission
factors documented herein for DODIC C511 are only associated with the combustion of the tracer
compound. Emissions associated with the propelling charge for DODIC C511 are not addressed in this
report except in Appendix A.
The emission factors described in this document are based on data obtained during testing
conducted at Aberdeen Proving Ground, Maryland, as presented in the final test report titled Report No. 6
for the Exploding Ordnance Emission Study Phase II1 and the document titled Detailed Test Plan No. 6
for the Exploding Ordnance Emission Study Phase II.2 These documents were supplemented by
additional data provided by the testing contractor.3 For each ordnance, two test runs were conducted.
Five items were detonated per run for DODICs C511 and K051, while one item was detonated per run for
the other three ordnance. Source test protocols were developed by USAEC before any testing was
conducted and were reviewed by the U.S. Environmental Protection Agency's (EPA's) Emission
Measurement Center. The tests were conducted between November 6 and November 21, 2002.
The compounds that were measured for DODICs B642, C511, K051, and L720 included carbon
monoxide (CO), carbon dioxide (C02), oxides of nitrogen (NOx), sulfur dioxide (S02), ammonia (NH3),
methane (CH4), total suspended particulate (TSP), particulate matter with an aerodynamic diameter less
than or equal to 10 microns (PM-10), particulate matter with an aerodynamic diameter less than or equal
to 2.5 microns (PM-2.5), metals, volatile organic compounds (VOC), semivolatile organic compounds
(SVOC), dioxin and fiiran compounds, acid gases, hydrogen cyanide (HCN), aldehydes and carbonyl
compounds, hydrocarbons, polycyclic aromatic hydrocarbons (PAH), energetic materials, total carbon,
hexavalent chromium, and perchlorate. The compounds that were measured for DODIC G911 included
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CO, C02, NOx, S02, NH3, CH4 aldehydes and carbonyl compounds, hydrocarbons, total carbon, and
hexavalent chromium. Within each of the AP-42 sections, only emission factors for criteria pollutants,
carbon dioxide, methane, hazardous air pollutants (as defined by § 112(b)(1) of the Clean Air Act [CAA]),
and toxic chemicals (as defined by §313 of the Emergency Planning and Community Right-to-Know Act
[EPCRA]) are presented.
The emission factors were developed on a "per item" basis and on a "per net explosive weight
(NEW)" basis. Users should choose the appropriate emission factor to estimate emissions based upon the
data available; either factor is equally valid. The NEW of each ordnance tested is provided in the
corresponding AP-42 section and in Table 2.
TABLE 2 ORDNANCE NET EXPLOSIVE WEIGHT
DODIC
Ordnance Description
NEW (lb/item)a
B642
M720 60-mm High Explosive Cartridge (projectile only)
7.91 E-01
C511
M490 105-mm Target Practice Tracer Cartridge
(Ml3 tracer only)
1.43 E-02
G911
MK3A2 Offensive Hand Grenade
4.96 E-01
K051
M604 Anti-Tank Practice Mine Fuze
3.81 E-02
L720
M26 Target Kill Simulator
1.35
a NEW values were obtained from Reference 1.
This document includes five sections in addition to this Introduction. Section 2 of this document
identifies the compounds measured during the test program and describes the emission measurement
methods used. Section 3 includes a discussion of the emission factor final test report and ratings for the
test data contained therein. Section 4 describes the calculations and methodologies used to develop
emission factors for each type of compound measured. Section 5 describes the methodology used to rate
the emission factors and provides emission factor ratings for each type of compound measured. Section 6
includes a complete list of the references cited in this document.
There are two appendices included with this document. Appendix A identifies, by ordnance type,
all of the compounds for which analyses were performed and the emission factors that were developed.
[Note: Compounds present in the method blank at greater than 50 percent of test levels are excluded from
Appendix A as described in Section 3.2.4], Appendix A also identifies the minimum detection levels
associated with all compounds that were not detected. Emission factors and minimum detection levels
presented in Appendix A were determined from the most accurate method if two sampling or analytical
methods were used to measure one compound. Appendix B presents the new AP-42 sections for the five
ordnance that were tested.
In addition to this document, there are electronic databases available on the web
(http://www.epa.gov/ttn/chief/ap42/index.html) that contain the data used in the development of the
emission factors. The general procedures that were followed to develop these emission factors can be
found at the same web address under the title Procedures for Preparing Emission Factor Documents4
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2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS
The USAEC Exploding Ordnance Series 6 testing was conducted in the Large Octagon Test
Chamber (LOTC) located at the Aberdeen Test Center (ATC), Maryland. The LOTC is an eight-sided
steel structure with flat ends. Internally, the eight sides were increased to 16 sides by welding steel plates
over each wall seam. This design strengthened the LOTC and removed sharp interior corners that would
inhibit gaseous mixing during the testing. Additional plates were added to the upper and lower internal
corners to create a more parabolic shape. The interior volume is approximately 2,400 cubic feet. Interior
wall-to-wall distance is 14.5 feet, with a floor-to-ceiling height of 14 feet.
The measurement assembly and instrument enclosure are mounted on rollers in vertical tracks.
After ordnance detonation, the assembly is lowered by an electric hoist from the top of the LOTC through
the center of the ceiling and into the chamber. A metal cover on top of the assembly seals the interior
when the assembly has been lowered into the LOTC. The LOTC has two flanged viewing ports for video
recording and two ports with hinged internal doors through which the mixing fans are inserted.
A number of different test methods were employed to collect and analyze the emission data that
were used to develop emission factors for detonation of ordnance. Table 3 identifies each emission test
method used; bracketed information identifies the purpose of using the method. The emissions data were
collected using EPA test methods published in Title 40 of the Code of Federal Regulations, Part 50
(40 CFR 50); 40 CFR 60; 40 CFR 63; and in Compendium of Methods for the Determination of Toxic
Organic Compounds in Ambient Air? Some of the sample analytical procedures used were from EPA
Office of Solid Waste (OSW) publication SW-846, Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods6 and the National Institute for Occupational Safety and Health (NIOSH)
Manual of Analytical Methods (NMAM). fourth Edition. Additional sampling and analytical procedures
were taken from Internal Operating Procedures (IOP) developed by the ATC Chemistry Team and from
Standard Operating Procedures (SOP) developed by the U.S. Army Center for Health Promotion and
Preventive Medicine (USACHPPM) Directorate of Laboratory Sciences (DLS). Where necessary, the
test methods were adapted to reflect application to the unique testing of ordnance detonation in the
LOTC.
The following sections identify and briefly describe the test methods used to measure each
compound or group of compounds. Additional information regarding the operation of the LOTC and the
test methods used is presented in Reference 2. EPA-approved methods were used by the laboratories that
provided sampling and analysis data.
2.1 Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide
Real-time concentrations of CO, C02, NOx, and S02 that resulted from the detonation of
ordnance in the LOTC were measured using a continuous emissions measurement system (CEMS). The
final test report1 states that the compounds were measured using EPA reference methods as described in
the following paragraph. Although the report does include results for some quality control checks, due to
a lack of calibration data, conformance with the stated methodologies could not be confirmed.
CO sampling and analysis was conducted in accordance with 40 CFR Part 60, Appendix A,
Method 10 - Determination of Carbon Monoxide Emissions from Stationary Sources, with a Thermo
Environmental Instruments, Inc. (TEI) nondispersive infrared analyzer. C02 sampling and analysis was
conducted in accordance with 40 CFR Part 60, Appendix A, Method 3A - Determination of Oxygen and
Carbon Dioxide Concentrations in Emissions from Stationary Sources, with a TEI nondispersive infrared
analyzer. NOx sampling and analysis was conducted in accordance with 40 CFR Part 60, Appendix A,
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TABLE 3 SAMPLING AND ANALYTICAL METHODS USED
Compound
Test Method
CO
co2
NOx
so2
sf6, nh3, CO,
C02, and CH4
TSP
PM-10 and
PM-2.5
Metals
voc
PAH
SVOC
Dioxins and
Furans
Acid Gases
40 CFR 60, Appendix A, EPA Method 10 - Determination of Carbon Monoxide
Emissions from Stationary Sources [sampling and analysis]
40 CFR 60, Appendix A, EPA Method 3A - Determination of Oxygen and Carbon
Dioxide Concentrations in Emissions from Stationary Sources (Instrumental Analyzer
Procedure) [sampling and analysis]
40 CFR 60, Appendix A, EPA Method 7E - Determination of Nitrogen Oxides
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
40 CFR 60, Appendix A, EPA Method 6C - Determination of Sulfur Dioxide
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
40 CFR 63, Appendix A, EPA Proposed Method 320 - Measurement of Vapor Phase
Organic and Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR)
Spectroscopy [sampling and analysis]
40 CFR 60, Appendix A, EPA Method 17- Determination of Particulate Emissions
from Stationary Sources (In-Stack Filtration Method) [sampling]
40 CFR 50, Appendix B - Reference Method for the Determination of Suspended
Particulate Matter as in the Atmosphere (High Volume Method) [analysis]
40 CFR 50. Appendix J - Reference Method for the Determination of Particulate
Matter as PM-K) in the Atmosphere |sampling and analvsis|
Metal sample was obtained from TSP sample [sampling]
40 CFR 50, Appendix G Modified - Reference Method for Determination of Lead in
Suspended Particulate Matter Collected from Ambient Air [analysis]
EPA Compendium Method TO-14A -Determination of Volatile Organic Compounds
(VOCs) in Ambient Air Using Specially Prepared Canisters with Subsequent Analysis
by Gas Chromatography [sampling and analysis]
EPA Compendium Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS) [sampling and analysis]
EPA Compendium Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS) [sampling and analysis]
SW-846 Method 8270 Modified (SW8270M) - Semivolatile Organic Compounds by
Gas Chromatography/Mass Spectrometry (GC/MS) [analysis]
EPA Compendium Method TO-9A - Determination ofPolychlorinated,
Polybrominated, and Brominated/Chlorinated Dibenzo-p-Dioxins and Dibenzofurans
in Ambient Air [sampling and analysis]
NIOSH Method 7903 - Inorganic Acids [sampling and analysis]
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TABLE 3 (cont.)
Compound
Test Method
Hydrogen
Cyanide
Aldehydes and
Carbonyls
Hydrocarbons
and n-Hexane
SFfi
Energetic
Materials
Total Carbon
Hexavalent
Chromium
Perchlorate
NIOSH Method 7904 - Aerosol and Gas Cyanides [sampling]
ATC IOP No. 231 - Analysis of Cyanide and Sulfide by Ion Chromatography
[analysis]
EPA Compendium Method TO-11A - Determination of Formaldehyde in Ambient Air
Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography
(HPLC) [sampling and analysis]
40 CFR 60, Appendix A, EPA Method 18 - Measurement of Gaseous Organic
Compound Emissions by Gas Chromatography [sampling and analysis]
40 CFR 60, Appendix A, EPA Method 18 - Measurement of Gaseous Organic
Compound Emissions by Gas Chromatography [sampling]
Project specific IOP, IR and gas chromatography with electron capture detection
(GC/ECD) [analysis]
EPA Compendium Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS) [sampling]
USACHPPM SOP CAD 26.2 - Procedure for Analysis of Explosives in Ambient Air
and USACHPPM SOP CAD 69.1 -Procedure for Analysis ofPropellant Components
in Ambient. A ir |analysis |
NIOSH Method 5040 - Diesel Particulate Matter as Elemental Carbon [sampling and
analysis |
OSHA Method ID-215 - Hexavalent Chromium in Workplace Atmospheres [sampling
and analysis]
EPA Method 314 - Determination of Perchlorate in Drinking Water Using Ion
Chromatography [sampling and analysis]
Method 7E - Determination of Nitrogen Oxides Emissions from Stationary Sources, with a TEI Model
No. 10AR chemiluminescent analyzer. S02 sampling and analysis was conducted in accordance with
40 CFR Part 60, Appendix A, Method 6C - Determination of Sulfur Dioxide Emissions from Stationary
Sources, with a TEI 43H pulsed fluorescent analyzer.
Each analyzer channel sampled at approximately 0.15 cubic feet per minute (ft3/min) through
Teflon-lined polyethylene tubing with Mine Safety Appliance (MSA) ultra type H cartridge filters used to
control particulate. An inline Balston® 95S6 filter was used to trap condensation. Due to the ambient
condition of the samples, no heated probes or sample lines were used. Data was collected four times per
second.
2.2 Sulfur Hexafluoride, Ammonia, Carbon Monoxide, Carbon Dioxide, and Methane
Extractive Fourier Transform Infrared (FTIR) spectroscopy was used to measure real-time
concentrations of the SF6 tracer gas, NH3, CO, C02, and CH4, as well as to identify qualitatively the
presence of other permanent gas species using protocols modified from procedures in 40 CFR 63,
Appendix A, EPA Proposed Method 320 - Measurement of Vapor Phase Organic and Inorganic
Emissions by Extractive Fourier Transform Infrared (FTIR) Spectroscopy. Samples were drawn
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continuously from the LOTC at a nominal rate of 0.5 ft3/min using a Teflon-lined polyethylene tube and
an Alcatel Pascal® rotary vane-type pump, for a minimum of 20 minutes. The FTIR spectra were
collected and stored at a minimum of every 20 seconds.
2.3 Total Suspended Particulate
The TSP concentration that resulted from the detonation of ordnance in the LOTC was
determined using a modified sampling and analysis procedure based on 40 CFR 60, Appendix A,
Reference Method 17 - Determination of Particulate Emissions from Stationary Sources (In-Stack
Filtration Method). A Graseby Model PS-1 ambient air sampling module equipped with a quartz fiber
filter was connected by a flex line to the Method 17 metering system. The metering system extracted test
chamber air through a particulate filter at a nominal rate of 1 ft3/min for a target minimum sampling time
of 20 minutes. The TSP concentration was computed, in accordance with 40 CFR 50, Appendix B -
Reference Method for the Determination of Suspended Particulate Matter as in the Atmosphere, by
dividing the mass of TSP collected by the volume of air sampled, corrected to standard conditions.
2.4 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 or 2.5 Microns
The PM-10 and PM-2.5 concentrations that resulted from the detonation of ordnance in the
LOTC were determined using a sampling and analysis procedure based on 40 CFR 50, Appendix J -
Reference Method for the Determination of Particulate Matter as PM-10 in the Atmosphere. An ambient
sampler with a Graseby Model No. G246B dichotomous PM-10 size-selective inlet head was used to
collect the PM-10 and smaller particulate at a sampling rate of 0.6 ft3/min for 20 minutes. The PM-10
fraction was then passed through a virtual impactor to separate the particulate larger than PM-2.5 from
PM-2.5. The PM-10 and PM-2.5 modules were equipped with polytetrafluorethylene (PTFE) particulate
filters that were weighed before and after sampling in accordance with 40 CFR 50, Appendix B. The
particulate concentrations were computed by dividing the mass of PM-10 and PM-2.5 collected by the
respective volume of air sampled, corrected to standard conditions.
2.5 Metals
Metal concentrations that resulted from the detonation of ordnance in the LOTC were determined
using particulate matter from the TSP samples collected as described in Section 2.3. The analyses
followed the procedures of 40 CFR 50, Appendix G - Reference Method for the Determination of Lead in
Suspended Particulate Matter Collected from Ambient Air. The method was modified to use inductively
coupled plasma (ICP) spectroscopy for analysis and to include additional metals. Concentrations of target
metals were computed by dividing the mass of metal collected by the volume of air sampled, corrected to
standard conditions.
2.6 Volatile Organic Compounds
VOC concentrations that resulted from the detonation of ordnance in the LOTC were determined
using procedures from the Second Supplement to Compendium of Methods for the Determination of Toxic
Organic Compounds in Ambient Air, Method TO-14A - Determination of Volatile Organic Compounds
(VOCs) in Ambient Air Using Specially-Prepared Canisters with Subsequent Analysis by Gas
Chromatography. Air samples were collected for 20 minutes using a Scientific Instrument Specialists,
Inc., pressurized canister sampler and 6-liter silicon-lined SUMMA canister that was certified VOC-free
prior to use. An analysis by gas chromatography/mass spectrometry in full scan mode (GC/MS/SCAN)
followed. Unknown compounds were tentatively identified using computerized mass spectral matching
techniques.
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2.7 Semivolatile Organic Compounds and Polycyclic Aromatic Hydrocarbons
SVOC and PAH concentrations that resulted from the detonation of ordnance in the LOTC were
determined based on procedures found in Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass Spectrometry (GC/MS). During
each run, samples were collected using a Graseby, Model PS-1 ambient air sampling module equipped
with a quartz fiber filter and XAD-2 adsorbent resin cartridge. The sampling module was connected to a
stack source airflow metering system with a flex line and used to sample for 20 minutes at a nominal rate
of 1.0 ft3/min. Following sampling, the filters and resin cartridges underwent solvent extraction and
analysis by GC/MS analysis in selected ion monitoring (SIM) mode. The sample extracts were
reanalyzed in scan mode following modified procedures in SW-846 Method 8270 - Semivolatile Organic
Compounds by Gas Chromatography/Mass Spectrometry (GC/MS). Modifications are described in the
USACHPPM SOP SV 72.6 - Analysis of SW-846 Extracts for Semivolatile Organics by EPA
Method 8270C. Unknown compounds were tentatively identified using computerized mass spectral
matching techniques.
2.8 Dioxin and Furan Compounds
Polychlorinated dibenzodioxin (PCDD) and polychlorinated dibenzofuran (PCDF) compound
concentrations that resulted from the detonation of ordnance in the LOTC were determined based on
procedures found in Method TO-9A - Determination of Polychlorinated, Polybrominated and
Brominated/ Chlorinated Dibenzo-p-Dioxins and Dibenzofurans in Ambient Air. Samples were collected
using Graseby, Model PS-1 ambient air sampling module quipped with a quartz fiber filter and
polyurethane foam (PUF) packed cartridge. The sampling module was connected to a stack source
airflow metering system with a flex line and used to sample for 20 minutes at a nominal rate of
1.0 ft3/min. After sampling, the filters and cartridges underwent extraction and analysis by GC/High
Resolution Mass Spectroscopy according to Method TO-9A.
2.9 Acid Gases
Acid gas concentrations that resulted from the detonation of ordnance in the LOTC were
determined based on procedures found in NIOSH Method 7903 - Inorganic Acids. Acid gases were
collected by using silica gel sorbent tubes (ORBO-53) and a sampling pump. Sample gases were passed
through the sorbent tubes for 20 minutes at a nominal rate of 0.01 ft3/min. Analysis was performed
according to NIOSH Method 7903 by ion chromatography as detailed in ATC IOP No. 372 - Anion
Analysis Using the ASM Column.
2.10 Hydrogen Cyanide
HCN concentrations that resulted from the detonation of ordnance in the LOTC were determined
using NIOSH Method 7904 - Aerosol and Gas Cyanides, but utilizing modified sampling and analytical
procedures. The sample gas was drawn through an 0.8 micrometer PVC filter and an impinger containing
0.1 normal potassium hydroxide (KOH) for 20 minutes at a nominal rate of 0.01 ft3/min. The impinger
solution and extracted filter were analyzed by ion chromatography in accordance with NIOSH
Method 7904 and ATC IOP No. 231 - Analysis of Cyanide and Sulfide by Ion Chromatography.
2.11 Aldehydes and Carbonyl Compounds
Aldehyde and carbonyl compound concentrations that resulted from the detonation of ordnance in
the LOTC were determined using EPA Compendium Method TO-11A - Determination of Formaldehyde
in Ambient Air Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography
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(HPLC), but utilizing modified sampling and analytical procedures. Dinitrophenylhydrazine (DNPH)
laden cartridge tubes were used as a direct probe to trap and derivatize aldehyde and carbonyl
compounds. Sample gases were extracted for 20 minutes (nominal) from the test chamber through ozone
denuders at a rate of 0.05 ft3/min using a diaphragm pump, manifold, critical orifice and needle valve.
Analysis was by reverse-phase HPLC with ultraviolet (UV) detection using Compendium
Method TO-11A modified as detailed in ATC IOP 227 Rev. 3.0 - Analysis of Formaldehyde and Other
Carbonyl Compounds by High Performance Liquid Chromatography.
2.12 Hydrocarbons, n-Hexane, and Sulfur Hexafluoride
Hydrocarbon, n-hexane, and SF6 concentrations that resulted from the detonation of ordnance in
the LOTC were sampled using 40 CFR 60, Appendix A, EPA Method 18 - Measurement of Gaseous
Organic Compound Emissions by Gas Chromatography. The samples were collected in Tedlar® bags at a
nominal rate of 0.04 ft3/min for 20 minutes. Analysis for the light hydrocarbons was by gas
chromatography with a flame ionization detector (GC/FID) in accordance with 40 CFR 60, Appendix A,
EPA Method 18. SF6 was analyzed by GC/MS or by gas chromatography with electron capture detection
(GC/ECD). This measurement served as a backup to the FTIR measurement of SF6.
2.13 Energetic Materials
Energetic compound concentrations that resulted from the detonation of ordnance in the LOTC
were determined based on procedures found in EPA Compendium Method TO-13A - Determination of
Polycyclic Aromatic Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS). Samples were collected using a Grasebv Model PS-1 sampling module equipped
with a quartz fiber particulate filter in series with an XAD-2 adsorbent resin cartridge. The PS-1
sampling module was connected by flex line to a stack source airflow metering system and was used to
sample for 20 minutes at approximately 1.0 ftVmin.
Analyses followed procedures outlined in USACHPPM, Directorate of Laboratory Sciences,
Chromatographic Analysis Division - Procedure for Analysis of Explosives in Ambient Air, Standard
Operating Procedure CAD 26.2. This operating procedure specifically addresses the extraction and
analysis of XAD-2 resin used to sample energetic compounds from air. The energetic compounds were
extracted from the XAD-2 resin using isoamyl acetate and analyzed by gas chromatography with electron
capture detection (GC/ECD) or gas chromatography with mass spectrometry (GC/MS). A surrogate
compound (3,4-dinitrotoluene) was added to the XAD-2 resin prior to sampling. The quartz fiber filter
used in conjunction with the XAD-2 resin was extracted and analyzed separately to characterize the
energetic materials present as particulate solids. The filter was placed in a vial containing isoamyl acetate
immediately after testing to preserve the sample and prevent sublimation of any of the analytes. No
surrogate compound was used in the analysis of the filter portion of the sample.
2.14 Total Carbon
Total carbon concentrations that resulted from the detonation of ordnance in the LOTC were
determined based on the procedures in NIOSH Method 5040 - Diesel Particulate Matter as Elemental
Carbon. Samples were collected at a rate of 2.0 1pm using an APEX Instruments Model No. 623 meter
console. A dry gas meter contained in the console was used to measure the sample volume. Flow rates
were verified using an electronic flow meter. The particulate sample was collected on a 37-mm heat-
treated quartz fiber filter and was analyzed using a thermo-optical analyzer to differentiate between
organic and elemental carbon.
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2.15 Hexavalent Chromium
Hexavalent chromium concentrations that resulted from the detonation of ordnance in the LOTC
were determined based on the procedures in OSHA Method ID-215 - Hexavalent Chromium in
Workplace Atmospheres. Since particulate results from previous weapons firing showed that a large
fraction of the total particulate produced was less than 2.5 microns in size, the method was modified to
utilize a 0.8-(.un pore size polyvinyl chloride (PVC) filter instead of a 5-f.im PVC filter. Samples were
collected at a rate of 2.0 1pm using an APEX Instruments Model No. 623 meter console. A dry gas meter
contained in the console was used to measure the sample volume. Flow rates were verified using an
electronic flow meter. The filter media was extracted and analyzed using ion chromatography with post-
column derivatization and detection with a UV-Vis detector.
2.16 Perchlorate
Perchlorate concentrations that resulted from the detonation of ordnance in the LOTC were
determined based on the procedures in Method 314 - Determination of Perchlorate in Drinking Water
Using Ion Chromatography. The sampling was performed using a 50-mm Teflon open face filter cassette
with 2-micron pore size Teflon filters. A midget impinger with deionized water was used to trap
perchloric acid vapor. Samples were collected at a rate of 1.0 to 2.0 1pm using an APEX Instruments
Model No. 623 meter console. A dry gas meter contained in the console was used to measure the sample
volume. Flow rates were verified using an electronic flow meter. The filter media was extracted and both
the filter extract and the impinger solution were analyzed using ion chromatography with conductivity
detection.
3.0 TEST DATA ANALYSIS AND RATINGS
3.1 EPA Guidance Regarding Test Data Quality Ratings
Prior to inclusion of emission factors in AP-42, the reliability of the underlying emission test data
must be appraised in accordance with the rating system specified in Reference 4. Under this rating
system, test data are assigned a rating from A to D, where an "A" rating is assigned to the highest quality
data. The criteria used to assign a specific data quality rating are summarized below.
A Tests are performed by using an EPA reference test method, or when not applicable, a sound
methodology. Tests are reported in enough detail for adequate validation and raw data are
provided that can be used to duplicate the emission results presented in the report.
B Tests are performed by a generally sound methodology, but lacking enough detail for adequate
validation. Data are insufficient to completely duplicate the emission result presented in the
report.
C Tests are based on an unproven or new methodology, or are lacking a significant amount of
background information.
D Tests are based on a generally unacceptable method, but the method may provide an order-of-
magnitude value for the source.
Four specific criteria are identified in Reference 4 for consideration to assist in the assignment of
a test data quality rating. These four criteria are:
1. Source operation. If the manner in which the source was operated is well documented in the
report and the source was operating within typical parameters during the test, an "A" rating
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should be assigned. If the report stated parameters that were typical, but lacked detailed
information, a "B" rating should be assigned. If there is reason to believe the operation was not
typical, a "C" or "D" rating should be assigned.
2. Test methods and sampling procedures. In developing the ratings, the estimated accuracy and
precision of the test method as well as the adequacy of the documentation should be considered.
In general, if a current EPA reference test method, appropriate for the source, was followed, the
rating should be higher ("A" or "B"). If other methods were used, an assessment should be made
of their validity. If it is judged that the method was likely to be inaccurate or biased, a lower
rating ("C" or "D") should be given. A complete report should indicate whether any procedures
deviated from standard methods and explain any deviations. If deviations were reported, an
evaluation should be made of whether these were likely to influence the test results.
3. Process information. During testing, many variations in the process can occur without warning
and sometimes without being noticed. Such variations can induce wide deviations in sampling
results. If a large variation between test run results cannot be explained by information contained
in the site final test report or from test reports of other sources, the data are suspect and should be
given a lower rating or excluded. However, it should be recognized that a process may have
highly variable emissions and a lower rating may not be appropriate solely on the basis of wide
deviations in sampling results.
4. Analysis and calculations. Ideally, final test reports should contain original raw data sheets and
other documentation such as gas parameters (dry cubic feet per minute, oxygen percentage),
calculation sheets, or example calculations describing how the calculated emission results were
obtained. If there are data sheets, the nomenclature and equations used should be compared to
those specified by EPA to establish equivalency. The depth of review of the calculations should
be dictated by the reviewers' confidence in the ability and conscientiousness of the tester, based
on such factors as consistency of results and completeness of other areas of the final test report.
Reports may indicate that raw data sheets were available, but were not included. If the final test
report is of high quality based on the other criteria, the quality rating should not be lowered due to
a lack of data sheets.
An overall test data quality rating should be assigned based upon the ratings assigned for each of the four
criteria.
3.2 Analysis of Test Data
Data included in the final test report,1 the detailed test plan,2 and in the analytical data supporting
the test report3 were rated in accordance with the rating system described above. Results for each of the
four criteria described above are presented in the following sections.
3.2.1 Source Operations
The manner in which the ordnance were deployed (i.e., used) is documented in the final test
report. With the exceptions of the adaptations discussed below that were made to facilitate testing in the
LOTC, each ordnance that was tested was deployed in a manner similar to that which would occur in the
field. DODICs B642 (M720 60-mm High Explosive Cartridge) and C511 (105-mm Target Practice
Tracer Cartridge) were modified to allow for static detonation using an RP-2 detonator. The RP-2
detonators were also used during the background runs so that emissions associated with the detonators
could be subtracted from the total emissions associated with the test runs. The tests appear to have
replicated typical ordnance operating parameters; consequently, the test data should be assigned an "A"
rating based on this criterion.
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3.2.2 Test Methods and Sampling Procedures
The test methods and sampling procedures were evaluated as being appropriate and consistent
with EPA test methods or sound methodology. Except as noted below, no problems of any significance
were identified; consequently, the test data should be assigned an "A" rating based on this criterion.
3.2.2.1 CEMS-Measured Data
CEMS raw data were provided for the tests,3 but not for the pre- and post-test quality control
(QC) activities. CEMS QC measures specified under 40 CFR 60, Appendix A, EPA Methods 3A, 7E,
and 6C were not followed. Furthermore, none of the calibration gas certifications were supplied. There
was no evidence of bias in the data; however, based on the issues noted above, the test data for the
CEMS-measured compounds (i.e., CO, C02, NOx, and S02) should be assigned a "B" rating based on this
criterion.
3.2.2.2 Compounds Sampled or Analyzed Using More than One Test Method or Analytical Method
Thirty-four compounds were either sampled or analyzed using two methods; these compounds are
identified in Table 4. For each of these compounds, emission factors were calculated based upon the data
measured using the more appropriate test or analytical method; data obtained using the less appropriate
method were ignored. The more appropriate method was identified by reviewing the methods and the
target compound lists associated with each method. If a specific compound appeared on the target
compound list for one method but not the other, the method targeting the compound was selected. If a
specific compound appeared on the target compound lists for both methods, the method judged to provide
the most accurate data was selected.
If a compound was analyzed using both the SW8270M (SVOC) and TO-14A (VOC) methods,
the TO-14A method analysis was judged to be more accurate and was therefore selected. For compounds
analyzed using both the SW8270M (SVOC) and TO-13A (PAH) methods, the TO-13A value was
selected because TO-13A allowed quantification of compounds at lower levels than SW8270M. For
compounds sampled using a CEMS and FTIR spectroscopy, the CEMS measurements were judged to be
more accurate. For compounds analyzed using both SW8270M (SVOC) and SOP CAD 26.2 (energetic
materials), the SOP CAD 26.2 data were selected because SOP CAD 26.2 allows detection of compounds
at lower levels than SW8270M. If a compound analyzed using both the TO-11A (aldehydes) and
TO-14A (VOC) methods, the TO-11A method analysis was judged to be more accurate and was therefore
selected. For compounds analyzed using both Method 18 (hydrocarbons) and TO-14A (VOC), and for
which the compounds appeared on both target compound lists, the Method 18 analysis was judged to be
more accurate and was selected. For compounds analyzed using both Method 18 (hydrocarbons) and
FTIR spectroscopy, the Method 18 analysis was judged to be more accurate and was selected.
Occasionally, the compound measurement from the less accurate method was chosen because the
compound was present in the method blank of the preferred method. In addition, if a compound sampled
under two methods had poor precision between test runs for the sampling method that would have been
more accurate under normal circumstances, data from the other method were used to calculate emission
factors. These cases are also noted in the footnotes to Table 4.
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TABLE 4 SELECTED ANALYTICAL METHOD FOR COMPOUNDS ANALYZED USING
TWO ANALYTICAL METHODS
Compound
Selected Method
Other Method Employed
Carbon dioxide
40 CFR 60, Method 3A (CEMS)
40 CFR 63, Method 320 (FTIR)
Carbon monoxide
40 CFR 60, Method 10 (CEMS)
40 CFR 63, Method 320 (FTIR)
Methane
40 CFR 60, Method 18 (Hydrocarbons)
40 CFR 63, Method 320 (FTIR)
Acenaphthene
TO-13A (PAH)
SW8270M (SVOC)
Acenaphthylene
TO-13A (PAH)
SW8270M (SVOC)
Acrolein3
TO-11A (Aldehydes)
TO-14A (VOC)
Anthracene
TO-13A (PAH)
SW8270M (SVOC)
Benzo[a]anthraceneb
TO-13A (PAH)
SW8270M (SVOC)
Benzo [b] fluoranthene
TO-13A (PAH)
SW8270M (SVOC)
Benzo [k] fluoranthene
TO-13A (PAH)
SW8270M (SVOC)
Benzo [g,h,i]perylene
TO-13A (PAH)
SW8270M (SVOC)
Benzo [a]pyrenec
TO-13A (PAH)
SW8270M (SVOC)
1,3-Butadiene
40 CFR 60 Method 18 (Hydrocarbons)
TO-14A (VOC)
Chrysene
TO-13A (PAH)
SW8270M (SVOC)
Dibenz[a,h]anthracened
TO-13A (PAH)
SW8270M (SVOC)
1,2-Dichlorobenzene
TO-14A (VOC)
SW8270M (SVOC)
1,3 -Dichlorobenzene
TO-14A (VOC)
SW8270M (SVOC)
1,4-Dichlorobenzene
TO-14A (VOC)
SW8270M (SVOC)
2,4-Dinitrotoluene
SOP CAD 26.2 (Energetics)
SW8270M (SVOC)
2,6-Dinitrotoluene
SOP CAD 26.2 (Energetics)
SW8270M (SVOC)
Fluoranthene
TO-13A (PAH)
SW8270M (SVOC)
Fluorene
TO-13A (PAH)
SW8270M (SVOC)
Hexachlorobutadiene
TO-14A (VOC)
SW8270M (SVOC)
Hexachloroethane
TO-14A (VOC)
SW8270M (SVOC)
Hexane
40 CFR 60, Method 18 (Hydrocarbons)
TO-14A (VOC)
Indeno[ 1,2,3 -cd]pyrenec
TO-13A (PAH)
SW8270M (SVOC)
Naphthalene
TO-13A (PAH)
SW8270M (SVOC)
Nitrobenzene
SOP CAD 26.2 (Energetics)
SW8270M (SVOC)
Phenanthreneb
TO-13A (PAH)
SW8270M (SVOC)
Propylene6
40 CFR 60, Method 18 (Hydrocarbons)
TO-14A (VOC)
Pyrene
TO-13A (PAH)
SW8270M (SVOC)
1,2,4-Trichlorobenzene
TO-14A (VOC)
SW8270M (SVOC)
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TABLE 4 (cont.)
Compound
Selected Method
Other Method Employed
Acetone3
Pentane
TO-11A (Aldehydes)
40 CFR 60, Method 18 (Hydrocarbons)
TO-14A (VOC)
TO-14A (VOC)
a For DODICs B642, C511, K051, and L720, data collected from the VOC sampling method were used
to develop emission factors for this compound because the holding time was exceeded for the data
collected using the aldehyde sampling method.
b For DODIC C511, data collected from SVOC sampling methods were used to develop emission factors
because this compound was present in the PAH method blank at a level greater than 20 percent of the
test values.
c For DODIC C511, data collected from the SVOC sampling method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between PAH
test samples.
d For DODICs B642 and K051, data collected from the SVOC sampling method were used to develop
emission factors because this compound had a relative percent difference greater than 100 percent
between PAH test samples.
e For DODIC L720, data collected from the VOC sampling method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between
hydrocarbon test samples.
3.2.2.3 Tentatively Identified Compounds
During the analysis of the SVOC data, the 20 highest nontarget "peaks"' were tentatively
identified using computerized mass spectral matching techniques. Similarly, during the analysis of the
VOC data, the 20 highest nontarget "peaks" were tentatively identified. Emission factors were developed
for these tentatively identified compounds (TICs) if all of the following criteria were met.
1. The TIC corresponded to a unique compound (e.g., ethylbenzene). Emission factors were not
developed if the TIC corresponded to a class of compounds (e.g., unknown alcohol).
2. The TIC was not identified using another analysis method that provided higher confidence data.
Emission factors were developed based upon the higher confidence analysis method if such data
were available.
3. The TIC was not present in the method blank. Emission factors were not developed if the TIC
was found in the corresponding method blank.
No SVOCs were tentatively identified as unique compounds, were not identified using a higher
confidence method, and were not present in the method blank varied. However, the number of VOC that
were tentatively identified as unique compounds, were not identified using a higher confidence method,
and were not present in the method blank varied from one to nine compounds per ordnance. Emission
factors were developed for all of these TICs, but because of the uncertainty in the true identity of the
TICs, the test data were assigned a "C" rating.
3.2.3 Process Information
Ordnance are manufactured to tight tolerances and are expected to deploy in a very repeatable
fashion. Consequently, the test data should be assigned an "A" rating based upon this criterion.
However, large relative percent differences (i.e., greater than 100 percent) between test runs were noted
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for several compounds. Specific instances in which these differences were noted are identified in Table 5.
The equation below illustrates calculation of relative percent difference:
, . ...... test 1 concentration - test 2 concentration
relative percent difference = x 100%
average of test 1 and test 2 concentrations
Due to the large relative percent differences between test runs, the test data specifically identified
in Table 5 were assigned a "C" rating. The remainder of the data should be assigned an "A" rating based
on this criterion.
TABLE 5 COMPOUNDS FOR WHICH LARGE RELATIVE PERCENT DIFFERENCES
WERE NOTED BETWEEN TEST RUNS
Compound
Applicable DODIC
Acrylonitrile
B642, K051
Benzene
K051
Benzo(e)pyrene
C511
Benzyl chloride
C511
Butyraldehyde
G911
Chlorobenzene
C511
1,2-Dichloroethane
L720 ¦;
Ethylbenzene
C511 -
Ethylene
K051, L720
Hexachlorobenzene
K051
1,2,3,4,7,8 -Hexachlorodibenzofuran
L720
Hydrochloric acid
C511
Lead
K051
Methylene chloride
B642
Methyl isobutyl ketone
C511
Methyl methacrylate
C511, K051
Methyl tert-butyl ether
L720
2,3,7,8 -T etrachlorodibenzofuran
C511
1,2,4-Trimethylbenzene
C511
m-Xylene and p-Xylene
B642, C511
o-Xylene
C511
Acetylene
C511, L720
2-Butyne
L720
Calcium
L720
Ethane
L720
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TABLE 5 (cont.)
Compound
Applicable DODIC
Methyl ethyl ketone
L720
Octane
L720
Propyne
L720
1,3,5,-Trinitrobenzene
L720
2,4,6-Trinitrotoluene
L720
3.2.4 Analysis and Calculations
The test report,1 detailed test plan,2 and analytical data supporting the test report3 were reviewed
to determine whether they contained all of the original raw data, other documentation, and example
calculations. Although the test report did not contain raw field data, the data were made available upon
request. The test report also lacked certain calibration data. However, the missing information was
judged insufficient to result in a downgrade of the test data quality rating.
The raw data and sample calculations presented in the final test report, detailed test plan, and
analytical data supporting the test report were reviewed to determine if the emission factors presented in
the report could be duplicated. Where differences were found between the emission factors calculated
using the Excel spreadsheets and those presented in the test report, an examination was made to determine
the reason for the differences.
Several minor errors were noted in the calculation of the emission factors within the test report,
particularly with respect to correcting the sample volumes to standard conditions and the incorporation of
analytical detection limits into the emission factors (see Sections 4.1 and 4.2). The emission factors
presented in AP-42 are based upon the corrected spreadsheets. Based upon the raw data, other
documentation, and the Excel spreadsheet calculations, the test data should be assigned an "A" rating.
Emission factors developed for compounds present in the method blank at levels of 20 percent to
50 percent of test values were assumed to be biased high. Two compounds met this criterion.
Specifically, 1,2,3,4,6,7,8,9-octachlorodibenzo-p-dioxin met this criterion for DODIC C511 and
1,2,3,4,6,7,8,9-octachlorodibenzofuran met this criteria for DODIC L720. For these compounds, the test
data were assigned a "B" rating.
When compounds were found in the method blank at levels greater than 50 percent of both test
values, the data were assumed to be suspect and no emission factors were developed. Three compounds
met this criterion. Specifically, 1,2,3,4,7,8-hexachlorodibenzofuran and 1,2,3,4,6,7,8,9-
octachlorodibenzofuran met the criterion for DODIC C511, and 1,2,3,4,6,7,8,9-octachlorodibenzo-p-
dioxin met this criterion for DODIC L720.
The test report1 indicated that the recommended holding times to extraction and subsequent
analysis were exceeded for aldehyde and carbonyl compounds and hexavalent chromium compounds for
some of the ordnance tested. For all DODICs, the holding times for the aldehyde and carbonyl samples
were exceeded by 4 to 9 days. As a result, the aldehyde and carbonyl test data for these DODICs were
assigned a "B" rating. In addition, the holding times for the hexavalent chromium samples were exceeded
by between 4 and 11 days. Since hexavalent chromium may convert to trivalent chromium during
extended holding times, these test data were assigned a "C" rating. Those compounds whose data quality
was downgraded as a result of holding time exceedances are identified in Table 6.
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TABLE 6 COMPOUNDS SIGNIFICANTLY EXCEEDING THE HOLDING TIMES FOR
EXTRACTION AND/OR ANALYSIS
Compound
Applicable DODIC
Acetaldehyde
All DODICs
Acrolein
G911
Butyraldehyde
All DODICs
Hexavalent chromium3
B642, C511, G911, K051
Crotonaldehyde
All DODICs
Formaldehyde
All DODICs
Propionaldehyde
All DODICs
Acetone
G911
Benzaldehyde
All DODICs
2,5-Dimethylbenzaldehyde
All DODICs
Hexaldehyde
All DODICs
Isovaleraldehyde
All DODICs
o,m,p-Tolualdehyde
All DODICs
Valeraldehyde
All DODICs
a For this compound, test data w ere assigned a "C" rating.
3.3 Test Data Quality Ratings
Upon completing the analysis described in the preceding section of this document, the test data
quality ratings assigned as a result of the four criteria were reviewed. This review led to a downgrading
of some of the test data from an "A" rating to either a "B" rating or a "C" rating. Table 7 identifies the
data quality ratings for all compounds that did not receive an "A" rating.
TABLE 7 DOWNGRADED DATA QUALITY RATINGS
Compound
Data Quality
Rating
Applicable DODIC
Carbon dioxide
B
All DODICs
Carbon monoxide
B
All DODICs
Oxides of nitrogen
B
All DODICs
Sulfur dioxide
B
All DODICs
Acetaldehyde
B
All DODICs
Acrolein
B
G911
Acrylonitrile
C
B642, K051
Benzene
C
K051
Benzo(e)pyrene
C
C511
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TABLE 7 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Benzyl chloride
C
C511
Butyraldehyde
B
B642, C511, K051, L720
Butyraldehyde
C
G911
Chlorobenzene
C
C511
Hexavalent chromium
C
B642, C511, G911, K051
Crotonaldehyde
B
All DODICs
1,2-Dichloroethane
C
L720
Ethylbenzene
C
C511
Ethylene
C
K051, L720
Formaldehyde
B
All DODICs
Hexachlorobenzene
C
K051
1,2,3,4,7,8 -Hexachlorodibenzofuran
C
L720
Hydrochloric acid
C
C511
Lead
C
K051
Methylene chloride
/ C
B642
Methyl ethyl ketone
/ (
L720
Methyl isobutyl ketone
C
C511
Methyl methacrylate
c
C511, K051
Methyl tert-butyl ether
c
L720
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
B
C511
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
B
L720
Propionaldehyde
B
B642, C511, G911, K051, L720
2,3,7,8 -T etrachlorodibenzofuran
C
C511
1,2,4-Trimethylbenzene
C
C511
m-Xylene and p-Xylene
C
B642, C511
o-Xylene
C
C511
Acetone
B
G911
Acetylene
C
C511, L720
Benzaldehyde
B
All DODICs
Benzofuran
C
L720
1,3-Butadiyne
C
L720
1-Butanol
C
C511
l-Buten-3-yne
C
L720
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TABLE 7 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
2-Butyne
C
L720
Calcium
C
L720
2,5-Dimethylbenzaldehyde
B
All DODICs
Ethane
C
L720
1,4-bis(Ethynyl)benzene
C
L720
Furan
C
C511
Furan, tetrahydro-
C
C511
1,3 -Hexadien-5 -yne
C
L720
Hexaldehyde
B
All DODICs
lH-Indene, 1-methyl -
C
L720
Indene
C
L720
Isovaleraldehyde
B
All DODICs
Octane
C
L720
Phenylethyne
C
L720
1,2-Propadiene
/ c
B642. C51 1. K051
Propyne
r C
L720
Thiophene
c
L720
o,m,p-Tolualdehyde
B
All DODICs
1,3,5,-Trinitrobenzene
C
L720
2,4,6-Trinitrotoluene
C
L720
Valeraldehyde
B
All DODICs
4.0 EMISSION FACTOR CALCULATIONS
The methodologies and procedures that were used to develop emission factors from the test data
are described in this section. A similar approach was used to calculate emission factors for TSP, PM-10,
PM-2.5, metals, SVOC, PAH, and energetic materials. The calculation steps that were performed for
each sample and each configuration are summarized below.
1. The sample volumes associated with the background and test runs were corrected to the EPA
Stationary Source Program standard temperature and pressure (i.e., 68°F and 29.92 inches of
mercury).
2. For compounds for which more than one test sample was obtained, analytical detection limits
were incorporated into the test data.
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3. The background compound concentration was calculated by dividing the mass of compound
detected during the background run by the background run sample volume corrected to standard
conditions.
4. The test compound concentration was calculated by dividing the mass of compound detected
during the test run by the test run sample volume corrected to standard conditions.
5. A background-corrected concentration was calculated by subtracting the background
concentration from the test concentration.
6. A dilution-corrected concentration was calculated by dividing the background-corrected
concentration by the test dilution correction factor.
7. The mass of compound released during the test run was calculated by multiplying the dilution-
corrected concentration by the volume of the LOTC.
8. Emission factors for each sample and test run were calculated by dividing the mass of compound
released by the number of ordnance detonated during the test run or by the NEW detonated
during the test run, as appropriate.
9. Average emission factors were calculated for each compound.
Because concentration data (i.e., milligrams per cubic meter [mg/m3], parts per million by volume
[ppmv], or parts per billion by volume [ppbv]) were recorded for VOC, hydrocarbons, FTIR-measured
compounds, and CEMS-measured compounds, it was not necessary to calculate a corrected sample
volume as described in step 1 or to calculate background and test concentrations as described in steps 3
and 4. Detection limits were applied directly to test compound concentrations of VOC, hydrocarbons,
FTIR-measured compounds, and CEMS-measured compounds, as described in step 2. Where present,
ppmv and ppbv values were converted to mg/nr\ Emission factors for VOC and hydrocarbons were then
estimated in accordance with steps 5 through 9 described above. FTIR- and CEMS-measured compound
emission factors were estimated in accordance with steps 5 through 9 described above, except that step 6,
the dilution correction, was not required. FTIR- and CEMS-measured concentrations were determined
from initial steady-state points that occurred prior to significant dilution.
Test and background concentrations of acid gases, hydrogen cyanide, aldehydes, dioxin/furan,
total carbon, hexavalent chromium, and perchlorate compounds were provided by the laboratory. The
laboratory calculated the concentrations based upon the sample volumes as measured at actual conditions.
Concentration data received from the laboratory were corrected for volume at Stationary Source Program
standard conditions and analytical detection limits were incorporated as described in step 2. Emission
factors for these compounds were then estimated in accordance with steps 5 through 9 described above.
The following sections describe each of the nine emission factor calculation steps listed above in
more detail. In addition, Section 4.10 discusses the calculation of total emission factors for DODIC
B642, the propelling charge of which was previously tested as described in the final test report titled
Report No. 4 for the Firing Point Emission Study Phase if and for which emission factors were
previously estimated as described in Report on Revisions to 5th Edition AP-42 Chapter 15 - Ordnance
Detonation, Emission Factors Developed Based on Firing Point Emission Study Phase II Series 4 Testing
Conducted at Aberdeen Proving Ground, Maryland9 Section 4.12 discusses the calculation of total
emission factors for DODIC C511, which was previously tested as described in the final test report titled
Report No. 5 for the Firing Point Emission Study Phase II10 and for which emission factors were
previously estimated as described in Report on Revisions to 5th Edition AP-42 Chapter 15 - Ordnance
Detonation, Emission Factors Developed Based on Firing Point Emission Study Phase II Series 5 Testing
Conducted at Aberdeen Proving Ground, Maryland,n
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Ordnance Detonation
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Finally, Section 4.12 discusses the calculation of average emission factors for DODIC G911,
which was previously tested as described in the final test report titled Report No. 2 for the Exploding
Ordnance Emission Study Phase II12 and for which emission factors were previously estimated as
described in Report on Revisions to 5th Edition AP-42 Chapter 15 - Ordnance Detonation, Emission
Factors Developed Based on Exploding Ordnance Emission Study Phase II Series 2 Testing Conducted at
Aberdeen Proving Ground, Maryland,13
4.1 Correction of Sample Volume to Standard Conditions
Because sample volumes were initially reported at actual conditions, calculations to correct the
sample volumes to the EPA Stationary Source Program standard temperature of 68°F and pressure of
29.92 inches of Hg (20°C and 760 mm Hg) were performed. To obtain the sample volume at EPA
Stationary Source Program standard conditions (Vstat), the sample volume at actual conditions (Vact) was
multiplied by the ratio of pressure at actual conditions (Pact) to temperature at actual conditions (Tact) and
by the ratio of temperature at Stationary Source Program standard conditions (Tstat) to pressure at
Stationary Source Program standard conditions (Pstat). This calculation is illustrated by the following
equation:
P T
T/" -y» act -y. stat
stat act y-r p
act stat
4.2 Incorporation of Analytical Detection Limits to the Test Data
In most cases, more than one test sample was obtained for a specific compound (i.e., more than
one test run was conducted). When multiple samples were obtained for the same compound, a
comparison was made of all the sample data collected. Based upon the results of the comparison, the
following adjustments were made to the test data:
1. If all of the samples indicated that a compound was "not detected," the sample data were not
adjusted.
2. If all of the samples indicated that a compound was detected, the sample data were not adjusted.
3. If one or more of the samples indicated that a compound was detected and one or more of the
samples indicated that a compound was not detected, the "not detected" values were replaced
with a value equal to one half of the compound's analytical detection limit. The assumption
inherent to this adjustment was that the measured presence of a compound in one or more
samples was indicative of the compound's presence in all samples. The analytical detection
limits for each sample were obtained from the analytical data supporting the test report.
4.3 Determination of Background Concentration
For TSP, PM-10, PM-2.5, metals, SVOC, and PAH, the background compound concentration
(BC) was calculated by dividing the mass of compound detected during the background run (Bkgd mass)
by the background run sample volume corrected to EPA Stationary Source Program standard conditions
(Bkgd Vstat). The background concentration calculation is illustrated by the following equation:
Bkgd mass
BC =
Bkgd K,a,
The background compound concentrations of acid gases, hydrogen cyanide, aldehydes,
dioxin/furan compounds, total carbon, hexavalent chromium, and perchlorate provided by the lab were
20
Ordnance Detonation
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calculated using the sample volume at actual conditions (Bkgd Vact). In order to correct the
concentrations to EPA Stationary Source Program standard conditions (Bkgd Vstat), the uncorrected
concentrations (Bkgd UC) were multiplied by the ratio of volume at actual conditions to volume at
standard conditions. This calculation is illustrated by the following equation:
BC = Bkgd UC x Bkgd Vact
Bkgd Kat
FTIR- and CEMS-measured compounds were not sampled for during the background runs.
However, background data were recorded for each test run between the time the FTIR and CEMS began
sampling and the time of detonation. The only FTIR- or CEMS-measured compound for which
significant background concentrations were recorded was C02. The C02 background concentration was
assumed to equal a representative value over the sampling period. Background concentrations for the
other FTIR- and CEMS-measured compounds were assumed to be zero.
4.4 Determination of Test Compound Concentration
For TSP, PM-10, PM-2.5, metals, SVOC, PAH, and energetic materials, the test compound
concentration (TC) was calculated by dividing the mass of compound detected during the test run (Test
mass) by the test run sample volume corrected to EPA Stationary Source Program standard conditions
(Test Vstat)- This test compound calculation is illustrated by the following equation:
^ _ Test mass
1'csl Vxk„
Test compound concentrations of acid gases, hydrogen cyanide, aldehydes, dioxin/furan
compounds, total carbon, hexavalent chromium, and perchlorate provided by the lab were calculated
using the sample volume at actual conditions. In order to correct the concentrations to EPA Stationary
Source Program standard conditions, the uncorrected concentrations (Test UC) were multiplied by the
ratio of the volume at actual conditions (Test Vact) to the volume at EPA Stationary Source Program
standard conditions (Test Vstat). This calculation is illustrated by the following equation:
Test V
TC = Test UC x ±^LL«sl
For VOC, hydrocarbons, FTIR-measured compounds, and CEMS-measured compounds, sample
volume correction was not required. VOC and hydrocarbon test concentration values were used directly.
Test concentrations of CEMS- and FTIR-measured compounds were determined based upon the initial
steady-state values reached after detonation. The time at which a compound's concentration reached an
initial steady state was determined by visually inspecting plots of the concentration data versus time. The
initial steady state corresponds to the time at which a compound was well mixed within the LOTC, but
before the compound's concentration began to decrease at a steady rate due to dilution.
4.5 Determination of Background-Corrected Concentration
For all compounds, the calculation of the background-corrected concentration (BCC) was
dependent on whether the background (BC) and test concentrations (TC) were detected and whether they
were less than, equal to, or greater than one another. The procedures used to calculate the background-
corrected concentration for each sampling train and compound are described below and are displayed
graphically in Figure 1.
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Ordnance Detonation
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No
Was TC Detected?
Yes
No
Was BC Detected?
Yes
No
Was TC > BC?
Yes
BCC = TC
BCC = 0
BCC = ND
BCC = TC - BC
TC = Test Concentration
BC = Background Concentration
ND = Not Detected
BCC = Background-Corrected
Concentration
Figure 1 Calculation of background-corrected concentration.
22
Ordnance Detonation
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1. If the test concentration was not detected (ND), the background-corrected concentration equaled
ND.
2. If the test concentration was detected and the background concentration was not detected, the
background-corrected concentration equaled the test concentration.
3. If the test and background concentrations were detected and the test concentration was less than
or equal to the background concentration, the background-corrected concentration equaled 0.
4. If the test and background concentrations were detected and the test concentration was greater
than the background concentration, the background concentration was subtracted from the test
concentration. This calculation is illustrated by the following equation:
BCC = TC - BC
RP-2 detonators were used in the detonation of DODICs B642 and C511, but are not used when
the weapons are tactically detonated. To quantify emissions associated with the detonators and thereby
allow the emissions to be subtracted from the resulting emission factors, the detonators were used during
the background runs. As a result, it was necessary to correct these background concentrations for
dilution. This was accomplished by multiplying the background concentration by the ratio of test dilution
correction factor (DCFtest) to background dilution correction factor (DCFbackground) prior to completing
either step 3 or step 4 as described above. The calculation of the background-corrected concentration for
those DODICs that were tested with a detonator is illustrated by the following equation:
DCF
BCC = TC - BC x r—-22—
¦ ^ ^ background
4.6 Determination of Dilution-Corrected Concentration
The dilution-corrected concentration (DCC) was calculated by dividing the background-corrected
concentration by the applicable test dilution correction factor. This calculation is illustrated by the
following equation:
DCC= BCC
DCFtest
With the exception of CEMS- and FTIR-measured compounds, dilution correction factors were
obtained from the test contractor.3 Because the test concentrations of CEMS- and FTIR-measured
compounds were obtained prior to dilution, it was not necessary to calculate a dilution corrected
concentration for these compounds.
4.7 Determination of Mass of Compound Released
The mass of compound released was calculated by multiplying the dilution-corrected
concentration by the volume of the LOTC. This calculation is illustrated by the following equation:
Mass compound released = DCC x LOTC volume
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4.8 Determination of Emission Factors
Once the mass of compound released was calculated, two emission factors were developed for
each sample and for each test run: the mass of compound released per item (i.e., per single ordnance) and
the mass of compound released per pound NEW. The NEW for all ordnance were determined from
Reference 1.
4.9 Determination of Average Emission Factors
Steps 1 through 8, as described in Sections 4.1 through 4.8, are applicable to individual samples
within individual test runs. The final step in the emission factor calculation process was to calculate
average emission factors for each compound in terms of mass released per item and mass released per
pound NEW. The average emission factors for each compound were calculated as the arithmetic mean of
the individual samples associated with the compound. If all samples indicated that the compound was not
detected (ND), then the average emission factor was assigned a value of ND. [Note: The minimum
detection levels associated with the compounds that were not detected are presented in Appendix A.]
Total dioxin/furan emission factors were calculated by summing the average emission factors for
all dioxin/furan compounds. Samples of energetic materials and perchlorate were collected using both
filters and resin packed cartridges. However, the filter and resin were analyzed separately. Because the
filter and resin packed cartridge were arranged in series, average emission factors calculated for the filter
were added to average emission factors calculated for resin packed cartridge to determine total emission
factors.
4.10 Determination of Total Emission Factors for DODIC B642
Under the current test series, emissions generated by the use of the w arhead associated with
DOCIC B642 were quantified.' However, as described in References 8 and 9, emissions generated by the
use of the propelling charge associated with DODIC B642 were previously quantified. Total emissions
factors, in terms of pounds of emissions per item, were calculated by summing the emission factors for
the use of the propelling charge with the emission factors for the use of the warhead. Total emissions
factors, in terms of pounds of emissions per pound NEW, were calculated by dividing the total emissions
per item by the sum of the NEWs for the propelling charge and the warhead. The emission factors
developed for this test series are presented in Appendix A, along with the total emission factors developed
for the ordnance.
4.11 Determination of Total Emission Factors for DODIC C511
Under the current test series, emissions generated by the burning of the tracer associated with
DOCIC C511 were quantified.1 However, as described in References 10 and 11, emissions generated by
the use of the propelling charge associated with DODIC C511 were previously quantified. Total
emissions factors, in terms of pounds of emissions per item, were calculated by summing the emission
factors for the use of the propelling charge with the emission factors for the burning of the tracer. Total
emissions factors, in terms of pounds of emissions per pound NEW, were calculated by dividing the total
emissions per item by the sum of the NEWs for the propelling charge and the tracer. The emission factors
developed for this test series are presented in Appendix A, along with the total emission factors developed
for the ordnance.
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4.12 Determination of Average Emission Factors for DODIC G911
As described in References 12 and 13, DODIC G911 was previously tested. Under the current
test series, the ordnance was re-tested to obtain additional CEM, FTIR, aldehyde and carbonyl,
hydrocarbon, total carbon, hexavalent chromium, and perchlorate data. Emission factor data from the two
test series were compared. Emissions were similar and were used to develop an average emission factor
for the ordnance.
The average emission factor for each compound that was tested in both series was determined as
the arithmetic mean of the emission factors associated with each test. If both of the emission factors were
"ND," then the average emission factor was assigned a value of ND. If a compound was assigned a value
of ND for at least one but not all test series, then the ND values were ignored when calculating the
arithmetic average emission factor. For the compounds that were only tested in one test series, the
average emission factor was assigned the value for the single test.
5.0 EMISSION FACTOR RATINGS
The emission factors were appraised in accordance with the rating system specified in
Reference 4. Under this rating system, emission factors are assigned a rating from A to E, where an "A"
rating is assigned to the highest quality factors. The criteria used to assign a specific emission factor
rating are summarized below.
A Excellent. The emission factor was developed primarily from A- and B-rated source test data
taken from many randomly chosen facilities in the industry population. The source category
population was sufficiently specific to minimize variability.
B Above average. The emission factor was developed primarily from A- or B-rated test data from a
moderate number of facilities. Although no specific bias was evident, it was not clear if the
facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
C Average. The emission factor was developed primarily from A-, B-, and/or C-rated test data from
a reasonable number of facilities. Although no specific bias was evident, it was not clear if the
facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
D Below average. The emission factor was developed primarily from A-, B-, and C-rated test data
from a small number of facilities, and there may have been reason to suspect that these facilities
did not represent a random sample of the industry. There also may have been evidence of
variability within the source category population.
E Poor. The emission factor was developed from C- and D-rated test data from a very limited
number of facilities, and there may have been reason to suspect that the facilities tested did not
represent a random sample of the industry. There also may have been evidence of variability
within the source category population.
Two analyses were conducted to assign ratings to the ordnance emission factors. First, an
analysis was conducted on an ordnance-specific basis. Second, an analysis was conducted using all
available ordnance emission factor data. The second analysis was conducted to determine whether a
sufficient correlation existed between emission factors for different but similar ordnance to allow the
number of test data points to be increased to the point that higher emission factor ratings could be
9/06
Ordnance Detonation
25
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assigned than were possible when using the ordnance-specific approach. Both analyses are described
below.
5.1 Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data
As previously described, emission factor ratings are dependent upon the test data quality, the
number of test data points, the amount of variability present within a source category population, and the
randomness of the source category sample. The following test data facts pertain to these rating criteria:
1. As described in Section 3 of this Background Document, the ordnance test data was primarily
rated A or B. The test data for a few compounds was rated C.
2. Only two tests were conducted per ordnance.
3. Ordnance are manufactured to very tight tolerance levels so there is little variability within a
specific type of ordnance.
4. There was no evidence that suggested the tested items within each type of ordnance were
specially selected.
Emission factor ratings were assigned based upon these facts. The rationale used to accept or
reject specific emission factor ratings follow.
A: Rejected. The number of test data points was deemed to be insufficient to assign an A emission
factor rating.
B: Rejected. The number of test data points was deemed to be insufficient to assign a B emission
factor rating.
C: Accepted for most ordnance. The emission factors were developed using A- and B-rated test
data, there is little variability among items, and there was no evidence that suggested the tested
items were specially selected. Because of the limited number of data points, a C rating was
deemed appropriate for this set of circumstances.
D: Accepted for some ordnance. The emission factors were developed using C-rated test data, there
is little variability among items, and there was no evidence that suggested the tested items were
specially selected. Because of the limited number of data points, a D rating was deemed
appropriate for this set of circumstances.
E: Rejected. The ordnance described in this report were developed primarily using A- and B-rated
test data rather than C- or D-rated data, there is little variability among items, and there was no
evidence that suggested the tested items were specially selected. Therefore, an E emission factor
rating was deemed inappropriate.
5.2 Emission Factor Ratings Assigned - Based on All Available Test Data
The proceeding sections of this Background Document concern the emission measurement
methods, data analysis, and calculations used to develop emission factors for specific ordnance.
However, USAEC's ordnance emission factor development program includes more than 200 ordnance
that have been tested under more than 25 separate test series. Because many of these ordnance are similar
in size and/or chemical composition, a statistical analysis was conducted to assess the similarity of the
emission factors developed for similar ordnance. The results of this analysis were used to reevaluate the
emission factor ratings assigned on an ordnance-specific basis.
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USAEC characterized individual ordnance as falling into one of 17 separate categories,
depending upon the size and/or chemical composition of the ordnance. The ordnance and their respective
categories are identified in Table 8 along with a comment field describing the number of data points.
TABLE 8 ORDNANCE CATEGORIZATION FOR EMISSION FACTOR
CORRELATION ASSESSMENT
Category
DODIC
Ordnance Description
Test
Series
Comment
CS
G963a
K765a
M73A CS Riot Control Agent Hand
Grenade
CS Riot Control Agent Capsule
DPG VI
DPG VI
Data not yet
available
G900
TH3 AN-M14 Incendiary Grenade
E05
G911
MK3A2 Offensive Hand Grenade
E02
G911
MK3A2 Offensive Hand Grenade
E06
K010
M4 Field Incendiary Burster
E05
K145
M18A1 Antipersonnel Mine
E02
M023
Ml 12 Demolition Block Charge
EOl
M030
1/4-Pound Demolition Block Charge
EOl
M030
1/4-Pound Demolition Block Charge
E03
M031
1/2-Pound Demolition Block Charge
DPG IV A
M032
1-Pound Demolition Block Charge
E02
M032
1-Pound Demolition Block Charge
E03
M130a
M6 Electric Blasting Cap
DPG VII
Demolition
M130a
M6 Electric Blasting Cap
E07
20+ data points
M131a
M7 Blasting Cap
E07
M241
M10 High Explosive Universal Destructor
DPG IVB
M456
PETN Type 1 Detonating Cord
DPG IV A
M500a
M21 REEF Line Cutter
FP10
M591
Ml Military Dynamite Demolition Block
Charge
EOl
M913
M58A3 Linear Demolition Charge
E03
ML05a
MK24 High Explosive Cutter
EOll
ML09
Linear Demolition Charge, Shaped 20 gr/ft
DPG IV A
ML15
Linear Demolition Charge, Shaped
225 gr/ft
DPG IV A
ML47a
Mil Blasting Cap
E07
MM50a
M221 Shaped Charge
EOll
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TABLE 8 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
MN02a
M12 Blasting Cap
E07
MN03a
M13 Blasting Cap
E07
MN06a
M14 Blasting Cap
E07
Demolition,
continued
MN07a
MN08a
M15 Delay Blasting Cap
M81 Igniter
EOll
E09
20+ data points
MN68a
M151 Booster Demolition Charge
DPG VIII
None
PAX-11, Granular Powder Burn
E04
None
PAX-11, Molded Pellet Detonation
E04
G878a
M228 Practice Hand Grenade Fuse
DPG VI
K051
M604 Anti-Tank Practice Mine Fuze
E06
N278a
M564 MTSQ Fuze
EOll
Fuze
N285a
N286a
M577 Fuze
M582 Fuze
E09
E07
<10 data points
N335
M557 Point Detonating Fuze
E05
N340
M739A1 Point Detonating Fuze
E05
N464a
M732 Fuze
E09
G881
M67 Fragmentation Grenade
EOl
Grenade
G978
M82 Smoke Simulant Screening Grenade
Launcher
DPG V
<10 data points
G982
Terephthalic Acid Smoke Hand Grenade
DPG V
GG09a
M84 Non-Lethal Stun Hand Grenade
E012
B535
M583A1 40-mm White Star Parachute
DPG IVB
Cartridge
B536
M585 40-mm White Star Cluster Cartridge
DPG IVB
B627
M83A3, M83A2, & M83A1 60-mm
DPG V
Illuminating Cartridge with Fuze
Illumination
D505
M485A2 155-mm Illumination Round
(projectile)
DPG I
20+ data points
L305
Ml95 Green Star Parachute Signal Flare
DPG I
L306
M158 Red Star Cluster Signal Illumination
DPG II
L307
Ml59 White Star Cluster Signal
Illumination
DPG II
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TABLE 8 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
Illumination,
continued
L311
L312
L314
L367a
L410a
M126A1 Red Star Parachute Signal Flare
M127A1 White Star Parachute Signal
Flare
M125A1 Green Star Cluster Signal Flare
M22 Anti-Tank, Guided Missile, and
Rocket Launching Simulator
M206 Aircraft Countermeasure Flare
DPGII
DPGI
DPG I
DPG VI
DPG VI
20+ data points
Inert
HAlla
Rocket, 2.75-inch Flechette with M255A1
Warhead
DPG VIII
Data not yet
available
Large
C511
C784a
C785a
M490 105-mm Target Practice Tracer
Cartridge (tracer)
M831 120-mm Target Practice Tracer
Cartridge
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge
E06
E012
E012
Only 1 data
point yet
available
Medium
bait
BA15a
Ml001 40-mm HVCC Cartridge
M769 60-mm FRP Cartridge
E012
E012
Data not yet
available
Medium-FP
A652
A940
A976
B129a
B519
B584
B505a
M220 20-mm TP-T Cartridge
M910 25-mm Target Practice Discarding
Sabot Tracer Cartridge
M793 25-mm Target Practice Tracer
Cartridge
M789 30 mm CTG
M781 40-mm Practice Cartridge
M918 40-mm Practice Cartridge
M662 40-mm Red Star Parachute
Cartridge
FP9
FP8
FP8
E09
FP2
FP2
DPG VIII
10+ data points
Mine
K042a
M88 Volcano Practice Canister Mine
DPG VIII
Data not yet
available
Mortar
CA03
XM929 120 mm Smoke Cartridge with
M7334A1 Fuze
DPG V
Only 1 data
point
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TABLE 8 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
B542
M430 40-mm High Explosive Dual
Purpose (HEDP) Cartridge (projectile)
E03
B571
M383 40-mm High Explosive Cartridge
(projectile)
E03
B632
M49A4 60-mm High Explosive Cartridge
(projectile)
E03
B642
M720 60-mm High Explosive Cartridge
(projectile)
E06
Projectile
BZ-13a
M888 60-mm Cartridge with M935 PD
Fuze
EOll
10+ data points
C995
M136 AT4 Recoilless Rifle, 84-mm
Cartridge (projectile)
E03
H557
M72A3 66-mm High Explosive Antitank
Rocket (warhead)
EOl
H708a
M73 3 5-mm Subcaliber Practice Rocket
DPG VIII
None3
PAX-21. 60-mm Mortar
E08
PJ02
FIM-92A Stinger-Basic Guided Missile
(warhead)
E06
B642
M720 60-mm High Explosive Cartridge
(propelling charge)
FP4
B653a
M766 60-mm Short Range Practice Mortar
Cartridge
FP10
C226
M301A3 81-mm Illuminating Cartridge
(propelling charge)
FP4
C379
M934 120-mm High Explosive Cartridge
(Zone 1 - propelling charge)
FP8
Propellant
C511
M490 105-mm Target Practice Tracer
Cartridge (propelling charge)
FP5
20+ data points
C784
M831 120-mm Target Practice Tracer
Cartridge (propelling charge)
FP5
C785
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge (propelling charge)
FP5
C868
M821 81-mm High Explosive Cartridge
(propelling charge)
FP4
C876
M880 81-mm Target Practice Short Range
Cartridge (propelling charge)
FP4
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Ordnance Detonation
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TABLE 8 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
CA09
M931 120-mm Full Range Practice
Cartridge (Zone 1 - propelling charge)
FP8
CA09
M931 120-mm Full Range Practice
Cartridge (Zone 4 - propelling charge)
FP8
D533
M119A2 155-mm Propelling Charge
(Zone 7)
FP5
D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP1
D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP5
D540
M3 155-mm Propelling Charge (Zone 3,
M284 Cannon)
FP1
Propellant,
continued
D540
D540
M3 155-mm Propelling Charge (Zone 5,
Ml99 Cannon)
M3A1 155-mm Propelling Charge
(Zone 3. M l 99 Cannon)
FP1
FP1
20+ data points
D540
M3A1 155-mm Propelling Charge
(Zone 3. M284 Cannon)
FP1
D541
M4A2 155-mm Propelling Charge
(Zone 7)
FP5
M174a
MK209 Impulse Cartridge
FP10
M842a
Ml Squib
E07
M842a
M79 Igniter
E09
MD73a
M796 Impulse Cartridge
FP10
PJ02
FIM-92A Stinger-Basic Guided Missile
(flight motor)
FP7
PJ02
FIM-92A Stinger-Basic Guided Missile
(launch motor)
E05
H975a
M274 2.75-inch Signature Smoke with
H872 Warhead
DPG VIII
Pyrotechnic
L366
L495
M74A1 Projectile Air Burst Simulator
M49A1 Surface Trip Flare
DPGIVB
DPG II
20+ data points
L508a
M72 Red Railroad Warning Fuse
DPG VI
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TABLE 8 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
L592
TOW Blast Simulator
DPGV
L594
M115A2 Ground Burst Simulator
DPGI
L595a
M9 Liquid Projectile Air Burst Simulator
E012
L596
Ml 10 Flash Artillery Simulator
DPG I
L598
Ml 17 Flash Booby Trap Simulator
DPG I
L599
Ml 18 Illuminating Booby Trap Simulator
DPG II
L600
Ml 19 Whistling Booby Trap Simulator
DPG II
L601
M116A1 Hand Grenade Simulator
DPG I
L602
M21 Artillery Flash Simulator
DPG IVB
L709
M25 Target Hit Simulator
E02
Pyrotechnic,
continued
L709
XM25 Target Hit Simulator
DPGV
20+ data points
L720
M26 Target Kill Simulator
E06
M327a
Coupling Base Firing Device
FP10
M448a
M2 Percussion Detonator
EOll
M626a
M 1 Push Igniter
E09
M627a
M5 Pressure Release Igniter
FP10
M630
Ml Pull Igniter
DPGV
M630a
Ml Pull Igniter
E09
M670a
M700 Blasting Fuse
EOll
M766a
M60 Igniter
E09
ML03a
Ml42 Firing Device
EOll
H459
Rocket, 2.75-inch Flechette, MK40 Mod 3
FP7
Motor (propelling rocket)
H557
M72A3 66-mm High Explosive Antitank
FP4
Rocket (propelling rocket)
H557
M72A3 66-mm High Explosive Antitank
FP7
Rocket/Missile
Rocket (propelling rocket)
10+ data points
H708
M73 35-mm Subcaliber Practice Rocket
FP9
Motor
Rocket, 2.75-inch M267 Practice
H974
Warhead, MK66 Mod 3 Motor (propelling
rocket)
FP7
32
Ordnance Detonation
9/06
-------
TABLE 8 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
A010
M220 10 Gage Blank/Subcaliber Salute
Cartridge
FP9
AO 11
12 Gage #00 Shot Cartridge
FP9
A017a
12 Gage #9 Shot Cartridge
FP10
A059
M855 5.56-mm Ball Cartridge (fired from
the M16A1 Rifle)
FP3
A059
M855 5.56-mm Ball Cartridge (fired from
the M16A2 Rifle)
FP3
A059
M855 5.56-mm Ball Cartridge (No-Lead)
FP4
A063
M856 5.56-mm Tracer Cartridge
FP3
A065
M862 5.56-mm Practice Ball Cartridge
FP3
A066
M193 5.56-mm Ball Cartridge
FP6
A068
M196 5.56-mm Tracer Cartridge
FP6
A080
M200 5.56-mm Blank Cartridge
FP3
A086
.22 Caliber Long Rifle Ball Cartridge
FP4
Small Arm-FP
A106
.22 Caliber Standard Velocity Long Rifle
Ball Cartridge
FP4
20+ data points
Alll
M82 7.62-mm Blank Cartridge
FP3
A131
M62 7.62-mm Tracer Cartridge
FP6
A136
Ml 18 7.62-mm Ball Match Cartridge
FP6
A143
M80 7.62-mm Ball Cartridge
FP3
A171
M852 7.62-mm Ball Match Cartridge
FP6
A182
Ml .30 Caliber Ball Cartridge
FP6
A212
M2 .30 Caliber Ball Cartridge
FP6
A218
M25 .30 Caliber Tracer Cartridge
FP9
A247
M72 .30 Caliber Ball Match Cartridge
FP6
A363
M882 9-mm Ball Cartridge
FP3
A365
Ml81 14.5-mm Trainer-Spotter Cartridge
with 3-sec Delay (Artillery)
DPGV
A366a
M182 14.5-mm Cartridge
EOll
A400
M41 .38 Caliber Special Ball Cartridge
FP9
A403
.38 Caliber Special Blank Cartridge
FP9
9/06
Ordnance Detonation
33
-------
TABLE 8 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
A475
M1911 .45 Caliber Ball Cartridge
FP3
A518
M903 .50 Caliber SLAP Cartridge
FP9
Small Arm-FP,
continued
A518a
A525
M962 .50 Caliber SLAP/T
M2 .50 Caliber Armor Piercing Cartridge
FP10
FP8
20+ data points
A557
M17 .50 Caliber Tracer Cartridge
FP3
A557
M33 .50 Caliber Ball Cartridge
FP3
A598
M1A1 .50 Caliber Blank Cartridge
FP3
C870a
M819 (IUK) 81-mm Red Phosphorous
Smoke
DPG VII
G815a
Red Phosphorous Smoke Screening
Grenade Launcher (UK)
DPG VII
G930
Hexachloroethane Smoke Grenade
DPG V
G940
M18 Green Smoke Hand Grenade
DPG III
G945
M18 Yellow Smoke Hand Grenade
DPG III
Smoke
G950
M18 Red Smoke Hand Grenade
DPG III
10+ data points
G950
M18 Red Smoke Hand Grenade (new
formulation)
DPG V
G955
M18 Violet Smoke Hand Grenade
DPG III
G955
Ml8 Violet Smoke Hand Grenade (new
formulation)
DPG V
K866a
ABC-M5 HC Ground Smoke Pot (MILES)
DPG VII
K867a
M4A2 Floating Smoke Pot
DPG VII
a Although testing may have been completed, emission factors for this ordnance have not yet been
analyzed for inclusion in AP-42; therefore, these data were not included when the data correlation was
assessed.
Within each of the 17 ordnance categories identified by USAEC, emission factors for each
compound were compared. To allow the comparison of emission factors for ordnance with similar
constituents but significant differences in net explosive weight, the comparison was made using the
normalized emission factor units of mass of compound released per pound NEW. Based upon
information provided by EPA,14 the following procedures were used to assess the data correlation:
1. The relative standard deviation, defined as the standard deviation divided by the mean, was
calculated for each compound within each ordnance category.
2. If the relative standard deviation was less than 1.0, the evaluated emission factors were
considered to demonstrate good correlation. As such, the rating for these emission factors could
be elevated to a maximum of an A, depending on the number of data points within the evaluated
ordnance category.
34
Ordnance Detonation
9/06
-------
3. If the relative standard deviation was between 1.0 and 2.0, the evaluated emission factors were
considered to demonstrate fair correlation. As such, the rating for these emission factors could be
elevated to a maximum of a B, depending on the number of data points within the evaluated
ordnance category.
4. If the relative standard deviation was greater than 2.0, the evaluated emission factors were
considered to demonstrate poor correlation. As such, the emission factor rating could not be
elevated, regardless of the amount of data available.
A poor correlation between emission factors was not necessarily construed as being indicative of poor test
data. Rather, a poor correlation was more likely to indicate that the ordnance included in the category
were not as similar in nature as anticipated by USAEC when the ordnance categories were defined.
In addition to assessing the data correlation, an assessment was made of the number of test data
points available within each of the 17 ordnance categories. Because each ordnance test consisted of two
test data points (i.e., two test runs per ordnance or two independent sampling trains were used during an
ordnance test), the number of test data points available in each of the ordnance categories varied from 2 to
68. Based upon information provided by EPA,14 the following assumptions were used to assess whether
sufficient category-specific test data points were available to justify elevating the emission factor ratings
based on ordnance-specific data only:
1. If 20 or more data points were available, the emission factor rating could be elevated to a
maximum of an A, provided that the data also demonstrated a good correlation.
2. If at least 10 but less than 20 data points were available, the emission factor rating could be
elevated to a maximum of a B. provided that the data also demonstrated a good correlation.
3. If less than 10 data points were available, the emission factor rating could not be elevated,
regardless of the data correlation.
4. If the data demonstrated a fair correlation and 20 or more data points were available, the emission
factor rating could be elevated to a maximum of a B.
5. If the data demonstrated a fair correlation and at least 10 but less than 20 data points were
available, the emission factor rating could be elevated to a maximum of a C.
Using the criteria specified above, the emission factor ratings assigned to ordnance in each of the
17 ordnance categories were reevaluated. This evaluation indicated that some of the emission factor
ratings associated with ordnance included in nine categories could be elevated from a C or D rating to an
A or B rating. These nine categories are:
1.
Demolition
2.
Illumination
3.
Medium - Firing Point
4.
Projectiles
5.
Propellants
6.
Pyrotechnics
7.
Rocket/Missile
8.
Small Arms - Firing Point
9.
Smokes
A final assessment was made as to the emission factor rating assigned based on ordnance-specific
test data only. If the original emission factor data rating assigned was a C, then the emission factor rating
was elevated to an A or B, as appropriate, based upon the data for the whole ordnance category. If the
original emission factor data rating assigned was a D, then the emission factor rating was elevated to a B
9/06
Ordnance Detonation
35
-------
or C, as appropriate, based upon the data for the whole ordnance category. The analysis is documented in
an Excel spreadsheet that is located on the EPA website at:
http: //www .epa. gov/ttn/chief/ a p42/i ndex.html.
Within the current test series, DODIC B642 was included in the Projectile category, which
included more than 10 test data points. As a result, some emission factor ratings associated with this
ordnance were elevated. DODIC C511 was included in the Large category, which included less than
10 data points. As a result, the emission factor ratings associated with this ordnance were not elevated.
DODIC G911 was included in the Demolition category, which included more than 20 test data points. As
a result, some emission factor ratings associated with this ordnance were elevated. DODIC K051 was
included in the Fuze category, which included less than 10 data points. As a result, the emission factor
ratings associated with this ordnance were not elevated. DODIC L720 was included in the Pyrotechnic
category, which included more than 20 test data points. As a result, some emission factor ratings
associated with this ordnance were elevated. The emission factor ratings assigned are presented in
Appendix A.
6.0 REFERENCES
1. Report No. 6 for the Exploding Ordnance Emission Study Phase II, Military Environmental
Technology Demonstration Center, U.S. Army Aberdeen Test Center, Aberdeen Proving Ground,
MD, March 2005.
2. Detailed Test Plan No. 6 for the Exploding Ordnance Emission Study Phase II, Military
Environmental Technology Demonstration Center. U.S. Army Aberdeen Test Center, Aberdeen
Proving Ground, MD, November 2002.
3. Supporting information including Excel spreadsheets, analytical results, field notes, and case
summaries supplied upon request by the Applied Science Test Team - Chemistry Unit, U.S.
Army Aberdeen Test Center, Aberdeen Proving Ground, MD, April 2005 and May 2005.
4. Procedures for Preparing Emission Factor Documents, EPA-454/R-95-015, U.S. Environmental
Protection Agency, Research Triangle Park, NC, November 1997.
5. Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air,
Second Supplement, EPA/600/4-89/018, U.S. Environmental Protection Agency, Research
Triangle Park, NC, June 1988.
6. Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S.
Environmental Protection Agency, http://www.epa.gov/epaoswer/hazwaste/test/sw846.htm.
7. National Institute for Occupational Safety and Health (NIOSH) Manual of Analytical Methods
(NMAM), Fourth Edition, National Institute for Occupational Safety and Health, Cincinnati, OH.
8. Report No. 4 for the Firing Point Emission Study Phase II, Military Environmental Technology
Demonstration Center, U.S. Army Aberdeen Test Center, Aberdeen Proving Ground, MD,
September 2002.
9. Background Document, Report on Revisions to 5th Edition AP-42 Chapter 15 - Ordnance
Detonation, Emission Factors Developed Based on Firing Point Emission Study Phase II Series 4
36
Ordnance Detonation
9/06
-------
Testing Conducted at Aberdeen Proving Ground, Maryland, MACTEC Federal Programs, Inc.,
Research Triangle Park, NC, July 2006.
10. Report No. 5 for the Firing Point Emission Study Phase II, Military Environmental Technology
Demonstration Center, U.S. Army Aberdeen Test Center, Aberdeen Proving Ground, MD,
September 2003.
11. Background Document, Report on Revisions to 5th Edition AP-42 Chapter 15 - Ordnance
Detonation, Emission Factors Developed Based on Firing Point Emission Study Phase II Series 5
Testing Conducted at Aberdeen Proving Ground, Maryland, MACTEC Federal Programs, Inc.,
Research Triangle Park, NC, July 2006.
12. Report No. 2 for the Exploding Ordnance Emission Study Phase II, Military Environmental
Technology Demonstration Center, U.S. Army Aberdeen Test Center, Aberdeen Proving Ground,
MD, December 2003.
13. Background Document, Report on Revisions to 5th Edition AP-42 Chapter 15 - Ordnance
Detonation, Emission Factors Developed Based on Exploding Ordnance Emission Study Phase II
Series 2 Testing Conducted at Aberdeen Proving Ground, Maryland, MACTEC Federal
Programs, Inc., Research Triangle Park, NC, July 2006.
14. Information regarding the relationship between emission factor data correlation, the number of
data points available, and the resulting emission factor rating assigned supplied upon request by
Mr. Ron Myers, Measurement Policy Group. Office of Air Quality Planning and Standards, U.S.
Environmental Protection Agency. Research Triangle Park, NC. June 2006.
9/06
Ordnance Detonation
37
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38
Ordnance Detonation
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APPENDIX A
COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR ORDNANCE
INCLUDED IN EXPLODING ORDNANCE EMISSION STUDY PHASE II SERIES 6 TESTING
AT ABERDEEN PROVING GROUND, MARYLAND
9/06
Ordnance Detonation
A-l
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A-2 Ordnance Detonation 9/06
-------
TABLE A1 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC B642, M720 60-MM HIGH EXPLOSIVE CARTRIDGE (PROJECTILE ONLY)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
4.2 E-01
5.3 E-01
--
630-08-0
Carbon monoxidef
4.8 E-02
6.1 E-02
--
7439-92-1
Leadf
4.4 E-04
5.5 E-04
--
74-82-8
Methanef
1.5 E-03
1.9 E-03
--
--
Oxides of nitrogenf
5.3 E-03
6.6 E-03
--
--
PM-2.5f
3.0 E-02
3.8 E-02
--
~
PM-10f
6.5 E-02
8.2 E-02
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulatef
7.3 E-02
9.3 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthenef
6.3 E-08
7.9 E-08
--
208-96-8
Acenaphthylene
1.4 E-06
1.8 E-06
--
75-07-0
Acetaldehyde
3.2E-05
4.0 E-05
--
75-05-8
Acetonitrilef
ND
ND
2.9 E-04
107-02-8
Acrolein
ND
ND
1.1 E-03
107-13-1
Acrylonitrile8
2.4 E-07
3.1 E-07
--
107-05-1
Allyl chloride
ND
ND
8.9 E-04
7429-90-5
Aluminumf
1.9 E-03
2.3 E-03
--
7664-41-7
Ammoniaf
2.6 E-03
3.3 E-03
--
120-12-7
Anthracenef
1.2 E-07
1.5 E-07
--
7440-36-0
Antimony
ND
ND
6.2 E-02
7440-38-2
Arsenic
ND
ND
6.2 E-02
7440-39-3
Barium
7.6 E-05
9.6 E-05
--
71-43-2
Benzenef
3.3 E-06
4.2 E-06
--
56-55-3
Benzo [a] anthracenef
7.9 E-08
1.0 E-07
--
205-99-2
Benzo [b] fluoranthenef
7.4 E-08
9.4 E-08
--
207-08-9
Benzo [k] fluoranthene
2.0 E-07
2.6 E-07
--
191-24-2
Benzo [g,h,i]perylenef
3.9 E-08
4.9 E-08
--
50-32-8
Benzo [a]pyrenef
5.0 E-08
6.3 E-08
~
192-97-2
Benzo [e]pyrenef
7.2 E-08
9.1 E-08
--
100-44-7
Benzyl chloride
ND
ND
2.6 E-04
7440-41-7
Beryllium
ND
ND
3.1 E-02
75-25-2
Bromoform
ND
ND
5.3 E-04
9/06
Ordnance Detonation
A-3
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.6 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.6 E-02
106-99-0
1,3-Butadiene
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
4.0 E-04
85-68-7
Butylbenzylphthalate
ND
ND
1.6 E-02
123-72-8
Butyraldehyde
ND
ND
7.7 E-03
7440-43-9
Cadmium
ND
ND
3.1 E-02
75-15-0
Carbon disulfide
ND
ND
3.2 E-04
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-04
106-47-8
4-Chloroaniline
ND
ND
1.6 E-02
108-90-7
Chlorobenzene
ND
ND
2.4 E-04
75-45-6
Chlorodifluoromethane
ND
ND
2.5 E-04
75-00-3
Chloroethane
ND
ND
6.2 E-04
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.6 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.6 E-02
67-66-3
Chloroform
ND
ND
4.0 E-04
74-87-3
Chloromethanef
6.1 E-07
7.8 E-07
--
91-58-7
2-Chloronaphthalene
ND
ND
1.6 E-02
95-57-8
2-Chlorophenol
ND
ND
1.6 E-02
7005-72-3
4-Chlorophenyl-phenylether
ND
ND
1.6 E-02
7440-47-3
Chromium
7.2 E-05
9.1 E-05
--
18540-29-9
Hexavalent chromium11
3.4 E-06
4.3 E-06
--
218-01-9
Chrysenef
1.2 E-07
1.6 E-07
--
7440-48-4
Cobalt
2.1 E-05
2.7 E-05
--
7440-50-8
Copper
1.0 E-03
1.3 E-03
--
106-44-5
p-Cresol
ND
ND
1.6 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.7 E-03
98-82-8
Cumene
ND
ND
2.0 E-04
57-12-5
Particulate cyanide
ND
ND
1.3 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.6 E-02
132-64-9
Dibenzofuran
ND
ND
1.6 E-02
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-04
84-74-2
Dibutyl phthalate
ND
ND
1.6 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
4.9 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
4.3 E-04
A-4
Ordnance Detonation
9/06
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
4.3 E-04
75-27-4
Dichlorobromomethane
ND
ND
4.1 E-04
75-71-8
Dichlorodifluoromethane
4.0 E-08
5.0 E-08
--
75-34-3
1,1 -Dichloroethane
ND
ND
3.7 E-04
107-06-2
1,2-Dichloroethane
ND
ND
2.1 E-04
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.6E-02
78-87-5
1,2-Dichloropropane
ND
ND
3.3 E-04
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
5.0 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.6 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.6 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.5 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.6 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.6 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.5 E-04
606-20-2
2,6-Dinitrotoluene
ND
ND
6.5 E-04
123-91-1
1,4-Dioxane
ND
ND
3.3 E-04
--
Total dioxin/furan compounds
5.9 E-ll
7.5 E-ll
--
140-88-5
Ethyl acrylate
ND
ND
1.7 E-04
100-41-4
Ethylbenzene
ND
ND
3.1 E-04
74-85-1
Ethylenef
8.0 E-05
1.0 E-04
--
117-81-7
bis(2-Ethylhexyl)phthalatef
3.6 E-07
4.5 E-07
--
206-44-0
Fluoranthene
6.2 E-07
7.9 E-07
--
86-73-7
Fluorene
7.0 E-08
8.8 E-08
--
50-00-0
Formaldehyde
2.8 E-05
3.6 E-05
--
76-13-1
Freon 113
ND
ND
5.5 E-04
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
4.4 E-12
5.6 E-12
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
4.6 E-12
5.8 E-12
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
1.4 E-12
1.8 E-12
118-74-1
Hexachlorobenzene
ND
ND
1.6 E-02
87-68-3
Hexachlorobutadiene
ND
ND
7.6 E-04
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.6 E-02
9/06
Ordnance Detonation
A-5
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
5.5 E-13
6.9 E-13
--
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
1.4 E-12
1.8 E-12
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
1.4 E-12
1.8 E-12
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
4.2 E-12
5.3 E-12
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
1.5 E-12
1.9 E-12
--
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
2.6 E-13
3.3 E-13
--
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
1.5 E-12
2.0 E-12
--
67-72-1
Hexachloroethane
ND
ND
5.9 E-04
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
1.9 E-05
2.4 E-05
--
74-90-8
Hydrogen cyanidef
7.7 E-04
9.7 E-04
--
7664-39-3
Hydrogen fluoride
4.0 E-05
5.1 E-05
--
193-39-5
Indeno [ 1,2,3 -cd]pyrene
2.7 E-08
3.4 E-08
--
78-59-1
Isophorone
ND
ND
1.6 E-02
7439-92-1
Lead
4.4 E-04
5.5 E-04
~
7439-96-5
Manganesef
2.2 E-04
2.8 E-04
~
96-33-3
Methyl acrylate
ND
ND
2.5 E-04
74-95-3
Methylene bromide
ND
ND
5.1 E-04
75-09-2
Methylene chloride11
0
0
--
74-88-4
Methyl iodide
ND
ND
3.5 E-04
108-10-1
Methyl isobutyl ketone
ND
ND
3.3 E-04
80-62-6
Methyl methacrylate
ND
ND
4.6 E-04
91-57-6
2-Methylnaphthalene
ND
ND
1.6 E-02
95-48-7
2-Methylphenol
ND
ND
1.6 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalenef
2.9 E-06
3.6 E-06
--
7440-02-0
Nickel
1.2 E-04
1.5 E-04
--
7697-37-2
Nitric acidf
2.4 E-05
3.1 E-05
--
100-01-6
4-Nitroaniline
ND
ND
1.6 E-02
98-95-3
Nitrobenzene
ND
ND
6.5 E-04
55-63-0
Nitroglycerin
4.5 E-07
5.7 E-07
--
88-75-5
2-Nitrophenol
ND
ND
1.6 E-02
100-02-7
4-Nitrophenol
ND
ND
1.6 E-02
A-6
Ordnance Detonation
9/06
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
62-75-9
n-Nitrosodimethylamine
ND
ND
1.6 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.6 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.6 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
1.8 E-ll
2.3 E-ll
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
8.6 E-12
1.1 E-ll
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
1.1 E-12
1.4 E-12
--
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
1.8 E-12
2.3 E-12
--
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
3.4 E-12
4.2 E-12
--
87-86-5
Pentachlorophenol
ND
ND
1.6 E-02
85-01-8
Phenanthrenef
9.9 E-07
1.3 E-06
--
108-95-2
Phenol
2.2 E-06
2.7 E-06
--
123-38-6
Propionaldehyde
7.1 E-06
8.9 E-06
--
115-07-1
Propylenef
2.1 E-05
2.7 E-05
--
129-00-0
Pyrene
6.9 E-07
8.7 E-07
--
7782-49-2
Selenium
ND
ND
6.2 E-02
7440-22-4
Silver
1.3 E-05
1.6 E-05
--
100-42-5
Styrenef
4.6 E-07
5.9 E-07
--
7664-93-9
Sulfuric acid
ND
ND
9.6 E-02
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1.6 E-12
2.0 E-12
--
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
3.6 E-12
4.5 E-12
--
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-04
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-04
127-18-4
T etrachloroethy lene
ND
ND
4.1 E-04
7440-28-0
Thallium
ND
ND
6.2 E-02
108-88-3
Toluenef
3.2 E-07
4.0 E-07
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.3 E-03
71-55-6
1,1,1 -T richloroethane
ND
ND
4.4 E-04
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-04
75-69-4
Trichlorofluoromethane
2.3 E-08
2.9 E-08
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.6 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
4.9 E-04
95-63-6
1,2,4-Trimethylbenzene
ND
ND
2.5 E-04
540-84-1
2,2,4-Trimethylpentane
ND
ND
1.9 E-04
9/06
Ordnance Detonation
A-7
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
108-05-4
Vinyl acetate
ND
ND
3.9 E-04
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
2.1 E-05
106-42-3,
108-38-3
m-Xylene, p-Xyleneh
1.1 E-07
1.3 E-07
--
95-47-6
o-Xylene
ND
ND
4.9 E-04
7440-66-6
Zincf
3.6 E-04
4.6 E-04
—
Other Po
lutants
67-64-1
Acetone
2.7 E-07
3.4 E-07
--
74-86-2
Acetylenef
8.6 E-05
1.1 E-04
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
6.5 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.5 E-04
100-52-7
Benzaldehyde
ND
ND
7.7 E-03
100-51-6
Benzyl alcohol
ND
ND
1.6 E-02
108-86-1
Bromobenzene
ND
ND
3.9 E-04
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butene
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calciumf
2.2 E-04
2.8 E-04
--
7440-44-0
Elemental carbon
1.7 E-02
2.2 E-02
--
7440-44-0
Organic carbon
2.9 E-04
3.7 E-04
--
7440-44-0
Total carbonf
1.8 E-02
2.2 E-02
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.6 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.6 E-02
124-48-1
Dibromochloromethane
ND
ND
5.2 E-04
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-04
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.8 E-04
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
2.8 E-04
84-66-2
Diethylphthalate
ND
ND
1.6 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.7 E-03
117-84-0
Di-n-octylphthalate
ND
ND
1.6 E-02
74-84-0
Ethanef
3.7 E-05
4.6 E-05
--
A-8
Ordnance Detonation
9/06
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
141-78-6
Ethyl acetate
ND
ND
1.4 E-03
97-63-2
Ethyl methacrylate
ND
ND
3.3 E-04
622-96-8
4-Ethyltoluene
ND
ND
3.0 E-04
142-82-5
n-Heptane
ND
ND
2.1 E-04
66-25-1
Hexaldehyde
ND
ND
7.7 E-03
591-78-6
2-Hexanone
ND
ND
2.9 E-04
2691-41-0
HMX
ND
ND
6.5 E-03
10035-10-6
Hydrogen bromide
ND
ND
8.7 E-02
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.7 E-03
7439-95-4
Magnesiumf
1.2 E-04
1.5 E-04
--
78-93-3
Methyl ethyl ketone
2.9 E-06
3.7 E-06
--
98-83-9
alpha-Methylstyrene
ND
ND
2.9 E-04
479-45-8
Methyl-2,4,6-trinitrophenylnitramine
ND
ND
6.5 E-04
88-74-4
2-Nitroaniline
ND
ND
1.6 E-02
99-09-2
3-Nitroaniline
ND
ND
1.6 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.5 E-04
99-08-1
3-Nitrotoluene
ND
ND
6.5 E-04
99-99-0
4-Nitrotoluene
ND
ND
8.1 E-03
111-65-9
Octane
ND
ND
1.9 E-04
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.3 E-01
7664-38-2
Phosphoric acid
ND
ND
9.6 E-02
463-49-0
1,2-Propadiene1
3.2 E-07
4.1 E-07
--
74-98-6
Propane
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl
ND
ND
4.7 E-02
74-99-7
Propyne
ND
ND
3.3 E-02
121-82-4
RDX
3.6 E-07
4.6 E-07
--
7440-24-6
Strontium
9.8 E-06
1.2 E-05
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.3 E-02
25323-89-1
Trichloroethane
ND
ND
3.0 E-04
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
2.5 E-04
99-35-4
1,3,5 -T rinitrobenzenef
ND
ND
6.5 E-04
118-96-7
2,4,6-Trinitrotoluenef
6.8 E-08
8.6 E-08
--
110-62-3
Valeraldehyde
ND
ND
7.7 E-03
9/06
Ordnance Detonation
A-9
-------
TABLE A1 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 7.91 E-01 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor rated D because the factor is for a tentatively identified compound.
A-10
Ordnance Detonation
9/06
-------
TABLE A2 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC B642, M720 60-MM MORTAR HIGH EXPLOSIVE CARTIDGE (TOTAL)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxide8
4.3 E-01
5.0 E-01
--
630-08-0
Carbon monoxidef
6.4 E-02
7.5 E-02
--
7439-92-1
Lead8
4.4 E-04
5.2 E-04
--
74-82-8
Methane8
1.6 E-03
1.9 E-03
--
--
Oxides of nitrogen8
5.4 E-03
6.4 E-03
--
~
PM-2.58
3.1 E-02
3.7 E-02
--
--
PM-108
6.5 E-02
7.7 E-02
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate8
7.4 E-02
8.7 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
6.3 E-08
7.4 E-08
--
208-96-8
Acenaphthylene
1.4 E-06
1.7 E-06
--
75-07-0
Acetaldehyde8
3.6 E-05
4.3 E-05
--
75-05-8
Acetonitrile8
7.8 E-07
9.2 E-07
--
107-02-8
Acrolein
ND
ND
1.1 E-03
107-13-1
Acrylonitrile8
2.8 E-06
3.3 E-06
--
107-05-1
Allyl chloride
ND
ND
8.9 E-04
7429-90-5
Aluminum8
1.9 E-03
2.2 E-03
--
7664-41-7
Ammonia8
2.6 E-03
3.1 E-03
--
120-12-7
Anthracene8
1.2 E-07
1.4 E-07
--
7440-36-0
Antimony
2.3 E-06
2.7 E-06
--
7440-38-2
Arsenic
ND
ND
1.1 E-05
7440-39-3
Barium
7.8 E-05
9.2 E-05
--
71-43-2
Benzene8
1.8 E-05
2.1 E-05
--
56-55-3
Benzo [a] anthracene8
7.9 E-08
9.3 E-08
--
205-99-2
Benzo [b] fluoranthene8
7.4 E-08
8.7 E-08
--
207-08-9
Benzo [k] fluoranthene
2.0 E-07
2.4 E-07
--
191-24-2
Benzo [g,h,i]perylene8
4.4 E-08
5.2 E-08
--
50-32-8
Benzo [a]pyrene8
5.2 E-08
6.1 E-08
--
192-97-2
Benzo [e]pyrene8
7.2 E-08
8.6 E-08
~
100-44-7
Benzyl chloride
ND
ND
2.6 E-04
7440-41-7
Beryllium
ND
ND
1.1 E-05
75-25-2
Bromoform
ND
ND
5.3 E-04
9/06
Ordnance Detonation
A-ll
-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.6 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.6 E-02
106-99-0
1,3-Butadiene
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
4.0 E-04
85-68-7
Butylbenzylphthalate
ND
ND
1.6 E-02
123-72-8
Butyraldehyde
ND
ND
7.7 E-03
7440-43-9
Cadmium
ND
ND
1.1 E-05
75-15-0
Carbon disulfide
ND
ND
3.2 E-04
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-04
463-58-1
Carbonyl sulfide
2.5 E-06
3.0 E-06
--
106-47-8
4-Chloroaniline
ND
ND
1.6 E-02
108-90-7
Chlorobenzene
ND
ND
2.4 E-04
75-45-6
Chlorodifluoromethane
ND
ND
2.5 E-04
75-00-3
Chloroethane
ND
ND
6.2 E-04
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.6 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.6 E-02
67-66-3
Chloroform
ND
ND
4.0 E-04
74-87-3
Chloromethane8
6.1 E-07
7.3 E-07
--
91-58-7
2-Chloronaphthalene
ND
ND
1.6 E-02
95-57-8
2-Chlorophenol
ND
ND
1.6 E-02
7005-72-3
4-Chlorophenyl-phenylether
ND
ND
1.6 E-02
7440-47-3
Chromium
7.2 E-05
8.5 E-05
--
218-01-9
Chrysene8
3.4 E-06
4.0 E-06
--
7440-48-4
Cobalt
1.2 E-07
1.5 E-07
--
7440-50-8
Copper
2.4 E-05
2.8 E-05
--
106-44-5
p-Cresol
1.0 E-03
1.2 E-03
--
4170-30-3
Crotonaldehyde
ND
ND
1.6 E-02
98-82-8
Cumene
ND
ND
2.0 E-04
57-12-5
Particulate cyanide
6.8 E-07
8.0 E-07
--
53-70-3
Dibenz [a,h] anthracene8
0
0
--
132-64-9
Dibenzofuran
ND
ND
1.6 E-02
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-04
84-74-2
Dibutyl phthalate
ND
ND
3.9 E-04
95-50-1
1,2-Dichlorobenzene
ND
ND
4.9 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
4.3 E-04
A-12
Ordnance Detonation
9/06
-------
TABLE A2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
4.3 E-04
75-27-4
Dichlorobromomethane
ND
ND
4.1 E-04
75-71-8
Dichlorodifluoromethane
0
0
--
75-34-3
1,1 -Dichloroethane
4.0 E-08
4.7 E-08
--
107-06-2
1,2-Dichloroethane
2.9 E-07
3.4 E-07
--
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
2.1 E-04
78-87-5
1,2-Dichloropropane
ND
ND
3.3 E-04
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
2.3 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
5.0 E-04
131-11-3
Dimethyl phthalate
ND
ND
1.6 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
3.4 E-03
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
6.5 E-04
51-28-5
2,4-Dinitrophenol
ND
ND
1.6 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
3.4 E-03
606-20-2
2,6-Dinitrotoluene
ND
ND
6.5 E-04
123-91-1
1,4-Dioxane
ND
ND
3.3 E-04
--
Total dioxin/furan compounds
0
0
--
122-39-4
Diphenyl amine
5.9 E-ll
7.0 E-ll
--
140-88-5
Ethyl acrylate
ND
ND
1.7 E-04
100-41-4
Ethylbenzenef
0
0
--
74-85-1
Ethylenef
9.4 E-05
1.1 E-04
--
117-81-7
bis(2-Ethylhexyl)phthalate8
3.6 E-07
4.2 E-07
--
206-44-0
Fluoranthene
6.2 E-07
7.3 E-07
--
86-73-7
Fluorene
7.0 E-08
8.2 E-08
--
50-00-0
Formaldehyde8
5.6 E-05
6.7 E-05
--
76-13-1
Freon 113
ND
ND
5.5 E-04
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
4.4 E-12
5.2 E-12
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
4.6 E-12
5.4 E-12
—
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
1.4 E-12
1.6 E-12
118-74-1
Hexachlorobenzene
ND
ND
1.6 E-02
87-68-3
Hexachlorobutadiene
ND
ND
7.6 E-04
9/06
Ordnance Detonation
A-13
-------
TABLE A2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.6 E-02
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
5.5 E-13
6.5 E-13
--
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
1.4 E-12
1.7 E-12
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
1.4 E-12
1.7 E-12
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
4.2 E-12
5.0 E-12
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
1.5 E-12
1.8 E-12
--
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
2.6 E-13
3.1 E-13
--
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
1.5 E-12
1.8 E-12
--
67-72-1
Hexachloroethane
ND
ND
5.9 E-04
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
1.9 E-05
2.2 E-05
--
74-90-8
Hydrogen cyanide8
7.9 E-04
9.3 E-04
--
7664-39-3
Hydrogen fluoride
4.0 E-05
4.8 E-05
--
193-39-5
Indeno [ 1,2,3 -cd]pyrene
2.7 E-08
3.2 E-08
--
78-59-1
Isophorone
ND
ND
1.6 E-02
7439-92-1
Lead
4.4 E-04
5.2 E-04
--
7439-96-5
Manganese8
2.2 E-04
2.6 E-04
--
96-33-3
Methyl acrylate
ND
ND
2.5 E-04
74-95-3
Methylene bromide
ND
ND
5.1 E-04
75-09-2
Methylene chloride11
3.0 E-06
3.5 E-06
--
74-88-4
Methyl iodide
ND
ND
3.5 E-04
108-10-1
Methyl isobutyl ketone
ND
ND
3.3 E-04
80-62-6
Methyl methacrylate
1.5 E-07
1.7 E-07
--
91-57-6
2-Methylnaphthalene
ND
ND
1.6 E-02
95-48-7
2-Methylphenol
ND
ND
1.6 E-02
1634-04-4
Methyl tert-butyl ether
0
0
--
91-20-3
Naphthalenef
3.1 E-06
3.7 E-06
~
7440-02-0
Nickel
1.2 E-04
1.4 E-04
~
7697-37-2
Nitric acid8
3.4 E-05
4.0 E-05
~
100-01-6
4-Nitroaniline
ND
ND
1.6 E-02
98-95-3
Nitrobenzene
ND
ND
6.5 E-04
55-63-0
Nitroglycerin
4.5 E-07
5.4 E-07
--
88-75-5
2-Nitrophenol
ND
ND
1.6 E-02
A-14
Ordnance Detonation
9/06
-------
TABLE A2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
100-02-7
4-Nitrophenol
ND
ND
1.6 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.6 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.6 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.6 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
1.8 E-ll
2.1 E-ll
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
8.6 E-12
1.0 E-ll
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
1.1 E-12
1.3 E-12
--
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
1.8 E-12
2.1 E-12
--
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
3.4 E-12
4.0 E-12
--
87-86-5
Pentachlorophenol
ND
ND
1.6 E-02
85-01-8
Phenanthrene8
9.9 E-07
1.2 E-06
--
108-95-2
Phenol
2.2 E-06
2.6 E-06
--
123-38-6
Propionaldehyde
7.1 E-06
8.3 E-06
--
115-07-1
Propylene8
2.3 E-05
2.8 E-05
--
129-00-0
Pyrene
6.9 E-07
8.1 E-07
--
7782-49-2
Selenium
ND
ND
1.1 E-05
7440-22-4
Silver
1.3 E-05
1.5 E-05
--
100-42-5
Styrene
7.7 E-07
9.1 E-07
--
7664-93-9
Sulfuric acid
ND
ND
9.6 E-02
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1.6 E-12
1.9 E-12
--
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
3.6 E-12
4.2 E-12
--
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-04
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-04
127-18-4
T etrachloroethy lene
ND
ND
4.1 E-04
7440-28-0
Thallium
ND
ND
1.1 E-05
108-88-3
Toluene8
1.1 E-06
1.2 E-06
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.3 E-03
71-55-6
1,1,1 -Trichloroethane
1.1 E-07
1.3 E-07
--
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-04
75-69-4
Trichlorofluoromethane
2.3 E-08
2.7 E-08
~
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.6 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.6 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
4.9 E-04
9/06
Ordnance Detonation
A-15
-------
TABLE A2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
95-63-6
1,2,4-Trimethylbenzene
0
0
--
540-84-1
2,2,4-Trimethylpentane
ND
ND
1.9 E-04
7440-62-2
Vanadium
ND
ND
--
108-05-4
Vinyl acetate
ND
ND
3.9 E-04
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
2.1 E-05
106-42-3,
108-38-3
m-Xylene, p-Xylene
1.1 E-07
1.2 E-07
--
95-47-6
o-Xylene
0
0
--
7440-66-6
Zinc8
3.6 E-04
4.3 E-04
—
Other Po
lutants
67-64-1
Acetone
1.4 E-06
1.6 E-06
--
74-86-2
Acetylene8
9.5 E-05
1.1 E-04
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
6.5 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.5 E-04
100-52-7
Benzaldehyde
ND
ND
7.7 E-03
100-51-6
Benzyl alcohol
ND
ND
1.6 E-02
108-86-1
Bromobenzene
ND
ND
3.9 E-04
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butene
ND
ND
--
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calcium8
2.2 E-04
2.7 E-04
--
7440-44-0
Elemental carbon
1.7 E-02
2.0 E-02
--
7440-44-0
Organic carbon
2.9 E-04
3.5 E-04
--
7440-44-0
Total carbon8
1.8 E-02
2.1 E-02
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.6 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.6 E-02
124-48-1
Dibromochloromethane
ND
ND
5.2 E-04
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-04
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.8 E-04
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
2.8 E-04
84-66-2
Diethylphthalate
ND
ND
1.6 E-02
A-16
Ordnance Detonation
9/06
-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.7 E-03
117-84-0
Di-n-octylphthalate
ND
ND
1.6 E-02
74-84-0
Ethane
3.7 E-05
4.3 E-05
--
141-78-6
Ethyl acetate
ND
ND
1.4 E-03
97-63-2
Ethyl methacrylate
ND
ND
3.3 E-04
622-96-8
4-Ethyltoluene
ND
ND
3.0 E-04
110-00-9
Furan1
9.9 E-08
1.2 E-07
--
142-82-5
Heptane
ND
ND
2.1 E-04
66-25-1
Hexaldehyde
ND
ND
7.7 E-03
591-78-6
2-Hexanone
ND
ND
2.9 E-04
592-41-6
1-Hexene1
1.2 E-07
1.5 E-07
--
2691-41-0
HMX
ND
ND
6.5 E-03
10035-10-6
Hydrogen bromide
ND
ND
8.7 E-02
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.7 E-03
7439-95-4
Magnesium8
1.2 E-04
1.4 E-04
--
78-93-3
Methyl ethyl ketone
2.9 E-06
3.5 E-06
--
98-83-9
alpha-Methylstyrene
ND
ND
2.9 E-04
479-45-8
Methyl-2,4,6-trinitrophenylnitramine
ND
ND
6.5 E-04
88-74-4
2-Nitroaniline
ND
ND
1.6 E-02
99-09-2
3-Nitroaniline
ND
ND
1.6 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.5 E-04
99-08-1
3-Nitrotoluene
ND
ND
6.5 E-04
99-99-0
4-Nitrotoluene
ND
ND
3.4 E-03
111-65-9
Octane
ND
ND
1.9 E-04
78-11-5
Pentaerythritol tetranitrate
ND
ND
6.9 E-03
109-66-0
Pentane
ND
ND
7.2 E-02
14797-73-0
Perchlorate
ND
ND
--
7664-38-2
Phosphoric acid
ND
ND
9.6 E-02
463-49-0
1,2-Propadiene1
3.2 E-07
3.8 E-07
74-98-6
Propane
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl
ND
ND
4.7 E-02
74-99-7
Propyne
ND
ND
3.3 E-02
121-82-4
RDX
3.6 E-07
4.3 E-07
--
1066-40-6
Silanol, trimethyl-1
3.3 E-07
3.9 E-07
--
9/06
Ordnance Detonation
A-17
-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.3 E-02
25323-89-1
Trichloroethane
ND
ND
3.0E-04
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
2.5 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
6.5 E-04
118-96-7
2,4,6-Trinitrotoluene8
6.8 E-08
8.0 E-08
--
110-62-3
Valeraldehyde
ND
ND
7.7 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 8.46 E-01 pounds per item (propellant
base charge and two propellant increments).
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
1 Emission factor rated D because the factor is for a tentatively identified compound.
A-18
Ordnance Detonation
9/06
-------
TABLE A3 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC C511, M490 105-MM TARGET PRACTICE TRACER CARTRIDGE (Ml3 TRACER ONLY)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3'd
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxide
2.5 E-03
1.7 E-01
--
630-08-0
Carbon monoxide
2.7 E-05
1.9 E-03
--
7439-92-1
Lead
ND
ND
4.5 E-02
74-82-8
Methane
4.7 E-06
3.3 E-04
--
--
Oxides of nitrogen
2.0 E-04
1.4 E-02
--
--
PM-2.5
5.5 E-03
3.8 E-01
--
--
PM-10
5.9 E-03
4.1 E-01
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
5.9 E-03
4.1 E-01
--
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
4.7 E-10
3.3 E-08
--
208-96-8
Acenaphthylene
0
0
--
75-07-0
Acetaldehyde
ND
ND
7.6 E-03
75-05-8
Acetonitrile
3.3 E-08
2.3 E-06
--
107-02-8
Acrolein
3.1 E-06
2.2 E-04
--
107-13-1
Acrylonitrile
9.5 E-07
6.6 E-05
--
107-05-1
Allyl chloride
1.1 E-07
8.0 E-06
--
7429-90-5
Aluminum
2.5 E-06
1.8 E-04
~
7664-41-7
Ammonia
ND
ND
3.5 E-01
120-12-7
Anthracene
4.4 E-10
3.1 E-08
--
7440-36-0
Antimony
ND
ND
4.5 E-02
7440-38-2
Arsenic
ND
ND
4.5 E-02
7440-39-3
Barium
9.1 E-05
6.4 E-03
--
71-43-2
Benzene
2.6 E-06
1.8 E-04
~
56-55-3
Benzo [a] anthracene
ND
ND
1.6 E-02
205-99-2
Benzo [b] fluoranthene
6.8 E-10
4.8 E-08
--
207-08-9
Benzo [k] fluoranthene
6.5 E-ll
4.5 E-09
~
191-24-2
Benzo [g,h,i]perylene
9.4 E-10
6.5 E-08
~
50-32-8
Benzo [a]pyrene
ND
ND
1.6 E-02
192-97-2
Benzo [e]pyrene6
6.4 E-10
4.5 E-08
--
100-44-7
Benzyl chloride6
9.6 E-08
6.7 E-06
~
7440-41-7
Beryllium
ND
ND
2.3 E-02
75-25-2
Bromoform
ND
ND
5.3 E-04
9/06
Ordnance Detonation
A-19
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb
Minimum
Detection Level
mg/m3d
lb per item
lb per lb
NEWC
74-83-9
Bromomethane
2.1 E-07
1.5 E-05
--
101-55-3
4-Bromophenylphenylether
ND
ND
1.6 E-02
106-99-0
1,3-Butadiene
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
4.0 E-04
85-68-7
Butylbenzylphthalate
ND
ND
1.6 E-02
123-72-8
Butyraldehyde
ND
ND
7.4 E-03
7440-43-9
Cadmium
ND
ND
2.3 E-02
75-15-0
Carbon disulfide
ND
ND
3.2 E-04
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-04
106-47-8
4-Chloroaniline
ND
ND
1.6 E-02
108-90-7
Chlorobenzene6
1.9 E-06
1.3 E-04
--
75-45-6
Chlorodifluoromethane
ND
ND
2.5 E-04
75-00-3
Chloroethane
ND
ND
6.2 E-04
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.6 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.6 E-02
67-66-3
Chloroform
ND
ND
4.0 E-04
74-87-3
Chloromethane
1.2 E-06
8.7 E-05
--
91-58-7
2-Chloronaphthalene
ND
ND
1.6 E-02
95-57-8
2-Chlorophenol
ND
ND
1.6 E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.6 E-02
7440-47-3
Chromium
ND
ND
2.3 E-02
18540-29-9
Hexavalent chromium6
ND
ND
5.5 E-04
218-01-9
Chrysene
4.8 E-10
3.3 E-08
--
7440-48-4
Cobalt
ND
ND
4.5 E-02
7440-50-8
Copper
2.5 E-06
1.7 E-04
--
106-44-5
p-Cresol
ND
ND
1.6 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.4 E-03
98-82-8
Cumene
ND
ND
2.0 E-04
57-12-5
Particulate cyanide
ND
ND
1.1 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.6 E-05
132-64-9
Dibenzofuran
ND
ND
1.6 E-02
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-04
84-74-2
Dibutyl phthalate
3.1 E-07
2.2 E-05
--
95-50-1
1,2-Dichlorobenzene
ND
ND
4.9 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
4.3 E-04
A-20
Ordnance Detonation
9/06
-------
TABLE A3 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
106-46-7
1,4-Dichlorobenzene
ND
ND
4.3 E-04
75-27-4
Dichlorobromomethane
ND
ND
4.1 E-04
75-71-8
Dichlorodifluoromethane
7.0 E-10
4.9 E-08
--
75-34-3
1,1 -Dichloroethane
ND
ND
3.7 E-04
107-06-2
1,2-Dichloroethane
ND
ND
2.1 E-04
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.6E-02
78-87-5
1,2-Dichloropropane
ND
ND
3.3 E-04
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
5.0 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.6 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.6 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.4 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.6 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.6 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.4 E-04
606-20-2
2,6-Dinitrotoluene
ND
ND
6.4 E-04
123-91-1
1,4-Dioxane
ND
ND
3.3 E-04
--
Total dioxin/furan compounds
9.5 E-13
6.6 E-ll
--
140-88-5
Ethyl acrylate
1.5 E-07
1.0 E-05
--
100-41-4
Ethylbenzene6
3.2 E-07
2.2 E-05
--
74-85-1
Ethylene
ND
ND
2.3 E-02
117-81-7
bis(2-Ethylhexyl)phthalate
1.8 E-06
1.2 E-04
--
206-44-0
Fluoranthene
1.5 E-09
1.0 E-07
--
86-73-7
Fluorene
9.9 E-ll
6.9 E-09
--
50-00-0
Formaldehyde
9.9 E-08
6.9 E-06
--
76-13-1
Freon 113
1.4 E-06
9.7 E-05
--
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
1.0 E-13
7.0 E-12
~
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
2.6 E-14
1.8 E-12
~
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
3.4 E-14
2.3 E-12
118-74-1
Hexachlorobenzene
ND
ND
1.6 E-02
87-68-3
Hexachlorobutadiene
ND
ND
7.6 E-04
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.6 E-02
9/06
Ordnance Detonation
A-21
-------
TABLE A3 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
9.5 E-10
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
1.0 E-09
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
9.1 E-10
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
3.4 E-14
2.4 E-12
--
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
1.5 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
3.0 E-14
2.1 E-12
--
67-72-1
Hexachloroethane
ND
ND
5.9 E-04
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid6
6.8 E-05
4.8 E-03
~
74-90-8
Hydrogen cyanide
ND
ND
1.8 E-02
7664-39-3
Hydrogen fluoride
ND
ND
9.7 E-02
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
ND
1.6 E-02
78-59-1
Isophorone
ND
ND
1.6 E-02
7439-92-1
Lead
ND
ND
4.5 E-02
7439-96-5
Manganese
1.2 E-06
8.3 E-05
--
96-33-3
Methyl acrylate
ND
ND
2.5 E-04
74-95-3
Methylene bromide
ND
ND
5.1 E-04
75-09-2
Methylene chloride
1.2 E-07
8.7 E-06
--
74-88-4
Methyl iodide
ND
ND
3.5 E-04
108-10-1
Methyl isobutyl ketone6
6.3 E-08
4.4 E-06
--
80-62-6
Methyl methacrylate6
1.9 E-08
1.3 E-06
~
91-57-6
2-Methylnaphthalene
ND
ND
1.6 E-02
95-48-7
2-Methylphenol
ND
ND
1.6 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene
1.3 E-08
9.0 E-07
--
7440-02-0
Nickel
ND
ND
4.5 E-02
7697-37-2
Nitric acid
ND
ND
8.7 E-02
100-01-6
4-Nitroaniline
ND
ND
1.6 E-02
98-95-3
Nitrobenzene
ND
ND
3.2 E-03
55-63-0
Nitroglycerin
3.5 E-07
2.4 E-05
--
88-75-5
2-Nitrophenol
ND
ND
1.6 E-02
100-02-7
4-Nitrophenol
ND
ND
1.6 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.6 E-02
A-22
Ordnance Detonation
9/06
-------
TABLE A3 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.6 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.6 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
6.3 E-13
4.4 E-ll
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
1.8 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
ND
ND
2.1 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
3.9 E-14
2.7 E-12
--
87-86-5
Pentachlorophenol
ND
ND
1.6 E-02
85-01-8
Phenanthrene
ND
ND
1.6 E-02
108-95-2
Phenol
ND
ND
1.6 E-02
123-38-6
Propionaldehyde
ND
ND
7.4 E-03
115-07-1
Propylene
ND
ND
3.5 E-02
129-00-0
Pyrene
1.6 E-09
1.1 E-07
--
7782-49-2
Selenium
ND
ND
4.5 E-02
7440-22-4
Silver
ND
ND
4.8 E-03
100-42-5
Styrene
ND
ND
3.0 E-04
7664-93-9
Sulfuric acid
ND
ND
9.6 E-02
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
2.4 E-16
1.7 E-14
~
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran6
6.3 E-14
4.4 E-12
~
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-04
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-04
127-18-4
T etrachloroethy lene
ND
ND
4.1 E-04
7440-28-0
Thallium
ND
ND
4.5 E-02
108-88-3
Toluene
4.0 E-07
2.8 E-05
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.3 E-03
71-55-6
1,1,1 -Trichloroethane
7.0 E-08
4.9 E-06
--
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-04
75-69-4
Trichlorofluoromethane
4.0 E-10
2.8 E-08
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.6 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.6 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
4.9 E-04
95-63-6
1,2,4-Trimethylbenzenee
2.0 E-08
1.4 E-06
--
540-84-1
2,2,4-Trimethylpentane
ND
ND
1.9 E-04
108-05-4
Vinyl acetate
ND
ND
3.9 E-04
9/06
Ordnance Detonation
A-23
-------
TABLE A3 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
75-01-4
Vinyl chloride
7.5 E-07
5.2 E-05
--
75-35-4
Vinylidene chloride
ND
ND
2.1 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylenee
1.0 E-06
7.1 E-05
--
95-47-6
o-Xylenee
3.1 E-07
2.2 E-05
--
7440-66-6
Zinc
4.1 E-06
2.9 E-04
--
Other Po
lutants
67-64-1
Acetone
5.2 E-07
3.6 E-05
--
74-86-2
Acetylene6
1.1 E-06
7.6 E-05
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
6.4 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.4 E-04
100-52-7
Benzaldehyde
ND
ND
7.4 E-03
100-51-6
Benzyl alcohol
ND
ND
1.6 E-02
108-86-1
Bromobenzene
ND
ND
3.9 E-04
106-97-8
Butane
ND
ND
5.3 E-02
71-36-3
l-Butanolf
1.1 E-07
7.8 E-06
--
106-98-9
1-Butene
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calcium
1.7 E-07
1.2 E-05
--
7440-44-0
Elemental carbon
1.5 E-05
1.0 E-03
--
7440-44-0
Organic carbon
8.6 E-05
6.0 E-03
--
7440-44-0
Total carbon
1.0 E-04
7.1 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.6 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.6 E-02
124-48-1
Dibromochloromethane
ND
ND
5.2 E-04
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-04
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.8 E-04
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
2.8 E-04
84-66-2
Diethylphthalate
ND
ND
1.6 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.4 E-03
117-84-0
Di-n-octylphthalate
ND
ND
1.6 E-02
74-84-0
Ethane
ND
ND
2.5 E-02
A-24
Ordnance Detonation
9/06
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb
Minimum
Detection Level
mg/m3d
lb per item
lb per lb
NEWC
141-78-6
Ethyl acetate
ND
ND
1.4 E-03
97-63-2
Ethyl methacrylate
ND
ND
3.3 E-04
622-96-8
4-Ethyltoluene
ND
ND
3.0 E-04
110-00-9
Furanf
2.5 E-07
1.8 E-05
--
109-99-9
Furan, tetrahydro-f
1.1 E-07
7.5 E-06
--
142-82-5
n-Heptane
ND
ND
2.1 E-04
66-25-1
Hexaldehyde
ND
ND
7.4 E-03
591-78-6
2-Hexanone
ND
ND
2.9 E-04
2691-41-0
HMX
ND
ND
6.4 E-03
10035-10-6
Hydrogen bromide
ND
ND
8.7 E-02
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.4 E-03
7439-95-4
Magnesium
2.0 E-03
1.4 E-01
--
78-93-3
Methyl ethyl ketone
1.1 E-07
7.5 E-06
--
98-83-9
alpha-Methylstyrene
ND
ND
2.9 E-04
479-45-8
Methyl-2,4,6-trinitrophenylnitramine
ND
ND
6.4 E-04
88-74-4
2-Nitroaniline
ND
ND
1.6 E-02
99-09-2
3-Nitroaniline
ND
ND
1.6 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.4 E-04
99-08-1
3-Nitrotoluene
ND
ND
6.4 E-04
99-99-0
4-Nitrotoluene
ND
ND
8.0 E-03
111-65-9
Octane
ND
ND
1.9 E-04
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.2 E-01
7664-38-2
Phosphoric acid
ND
ND
8.7 E-02
463-49-0
l,2-Propadienef
1.8 E-07
1.3 E-05
--
74-98-6
Propane
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl
ND
ND
4.7 E-02
74-99-7
Propyne
ND
ND
3.3 E-02
121-82-4
RDX
ND
ND
6.4 E-04
7440-24-6
Strontium
5.5 E-04
3.8 E-02
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.2 E-02
25323-89-1
Trichloroethane
ND
ND
3.0 E-04
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
2.5 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
6.4 E-04
9/06
Ordnance Detonation
A-25
-------
TABLE A3 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
118-96-7
2,4,6-Trinitrotoluene
ND
ND
6.4 E-04
110-62-3
Valeraldehyde
ND
ND
7.4 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c NEW = net explosive weight. The NEW for this ordnance is 1.43 E-02 pounds per item.
d Data provided for compounds that were not detected.
e Emission factor rated D because the factor is based upon C-rated test data.
f Emission factor rated D because the factor is for a tentatively identified compound.
A-26
Ordnance Detonation
9/06
-------
TABLE A4 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC C511, M490 105-MM TARGET PRACTICE TRACER CARTRIDGE (TOTAL)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3'd
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxide
7.6
6.3 E-01
--
630-08-0
Carbon monoxide
1.3 E-01
1.1 E-02
--
7439-92-1
Lead
6.8 E-04
5.6 E-05
--
74-82-8
Methane
4.7 E-06
3.9 E-07
--
--
Oxides of nitrogen
2.6 E-02
2.1 E-03
--
--
PM-2.5
7.8 E-02
6.5 E-03
--
--
PM-10
2.0 E-01
1.7 E-02
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
2.9 E-01
2.4 E-02
--
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
3.6 E-07
3.0 E-08
--
208-96-8
Acenaphthylene
0
0
--
75-07-0
Acetaldehyde
6.9 E-05
5.7 E-06
--
75-05-8
Acetonitrile
3.3 E-08
2.7 E-09
--
107-02-8
Acrolein
3.1 E-06
2.6 E-07
--
107-13-1
Acrylonitrile
9.5 E-07
7.8 E-08
--
107-05-1
Allyl chloride
1.1 E-07
9.4 E-09
--
7429-90-5
Aluminum
2.7 E-03
2.2 E-04
--
7664-41-7
Ammonia
ND
ND
3.5 E-01
120-12-7
Anthracene
1.3 E-07
1.1 E-08
--
7440-36-0
Antimony
ND
ND
1.4 E-03
7440-38-2
Arsenic
ND
ND
1.4 E-03
7440-39-3
Barium
2.2 E-04
1.8 E-05
--
71-43-2
Benzene
2.6 E-06
2.2 E-07
--
56-55-3
Benzo [a] anthracene
1.4 E-07
1.1 E-08
~
205-99-2
Benzo [b] fluoranthene
1.2 E-07
1.0 E-08
~
207-08-9
Benzo [k] fluoranthene
1.4 E-07
1.1 E-08
~
191-24-2
Benzo [g,h,i]perylene
1.9 E-07
1.6 E-08
--
50-32-8
Benzo [a]pyrene
7.9 E-08
6.6 E-09
~
192-97-2
Benzo [e]pyrene
1.1 E-07
8.9 E-09
~
100-44-7
Benzyl chloride
9.6 E-08
8.0 E-09
~
7440-41-7
Beryllium
ND
ND
1.4 E-03
75-25-2
Bromoform
ND
ND
5.3 E-04
9/06
Ordnance Detonation
A-27
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb
Minimum
Detection Level
mg/m3d
lb per item
lb per lb
NEWC
74-83-9
Bromomethane
2.1 E-07
1.8 E-08
--
101-55-3
4-Bromophenylphenylether
ND
ND
2.7 E-03
106-99-0
1,3-Butadiene
ND
ND
3.4 E-02
75-65-0
t-Butyl alcohol
ND
ND
4.0 E-04
85-68-7
Butylbenzylphthalate
ND
ND
2.7 E-03
123-72-8
Butyraldehyde
ND
ND
5.1 E-03
7440-43-9
Cadmium
ND
ND
1.4 E-03
75-15-0
Carbon disulfide
ND
ND
3.2 E-04
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-04
106-47-8
4-Chloroaniline
ND
ND
2.7 E-03
108-90-7
Chlorobenzene
1.9 E-06
1.6 E-07
--
75-45-6
Chlorodifluoromethane
ND
ND
2.5 E-04
75-00-3
Chloroethane
ND
ND
6.2 E-04
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
2.7 E-03
111-44-4
bis(2-Chloroethyl)ether
ND
ND
2.7 E-03
67-66-3
Chloroform
ND
ND
4.0 E-04
74-87-3
Chloromethane
1.2 E-06
1.0 E-07
--
91-58-7
2-Chloronaphthalene
ND
ND
2.7 E-03
95-57-8
2-Chlorophenol
ND
ND
2.7 E-03
7005-72-3
4-Chlorophenyl-phenylether
ND
ND
2.7 E-03
7440-47-3
Chromium
2.2 E-05
1.8 E-06
--
18540-29-9
Hexavalent chromium6
8.4 E-06
6.9 E-07
--
218-01-9
Chrysene
2.2 E-07
1.9 E-08
--
7440-48-4
Cobalt
1.6 E-05
1.4 E-06
--
7440-50-8
Copper
7.0 E-04
5.8 E-05
--
106-44-5
p-Cresol
ND
ND
2.7 E-03
4170-30-3
Crotonaldehyde
ND
ND
5.1 E-03
98-82-8
Cumene
ND
ND
2.0 E-04
57-12-5
Particulate cyanide
ND
ND
1.1 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
2.7 E-06
132-64-9
Dibenzofuran
ND
ND
2.7 E-03
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-04
84-74-2
Dibutyl phthalate
3.1 E-07
2.6 E-08
--
95-50-1
1,2-Dichlorobenzene
ND
ND
4.9 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
4.3 E-04
A-28
Ordnance Detonation
9/06
-------
TABLE A4 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
106-46-7
1,4-Dichlorobenzene
ND
ND
4.3 E-04
75-27-4
Dichlorobromomethane
ND
ND
4.1 E-04
75-71-8
Dichlorodifluoromethane
7.3 E-06
6.0 E-07
--
75-34-3
1,1 -Dichloroethane
ND
ND
3.7 E-04
107-06-2
1,2-Dichloroethane
ND
ND
2.1 E-04
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
2.7 E-03
78-87-5
1,2-Dichloropropane
ND
ND
3.3 E-04
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
5.0 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
2.7 E-03
131-11-3
Dimethyl phthalate
ND
ND
2.7 E-03
99-65-0
1,3 -Dinitrobenzene
ND
ND
1.4 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
2.7 E-03
51-28-5
2,4-Dinitrophenol
ND
ND
2.7 E-03
121-14-2
2,4-Dinitrotoluene
ND
ND
1.4 E-04
606-20-2
2,6-Dinitrotoluene
ND
ND
1.4 E-04
123-91-1
1,4-Dioxane
ND
ND
3.3 E-04
--
Total dioxin/furan compounds
4.2 E-09
3.5 E-10
--
140-88-5
Ethyl acrylate
1.5 E-07
1.2 E-08
--
100-41-4
Ethylbenzene
3.2 E-07
2.6 E-08
--
74-85-1
Ethylene
ND
ND
1.8 E-02
75-21-8
Ethylene oxidef
5.0 E-05
4.1 E-06
--
117-81-7
bis(2-Ethylhexyl)phthalate
1.6 E-04
1.4 E-05
--
206-44-0
Fluoranthene
6.7 E-07
5.6 E-08
~
86-73-7
Fluorene
5.1 E-07
4.2 E-08
~
50-00-0
Formaldehyde
2.2 E-04
1.8 E-05
--
76-13-1
Freon 113
1.4 E-06
1.2 E-07
~
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
3.6 E-10
3.0 E-ll
~
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
7.9 E-ll
6.6 E-12
~
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
3.4 E-14
2.8 E-15
118-74-1
Hexachlorobenzene
ND
ND
2.7 E-03
87-68-3
Hexachlorobutadiene
ND
ND
7.6 E-04
9/06
Ordnance Detonation
A-29
-------
TABLE A4 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.7 E-03
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
4.7 E-12
3.9 E-13
--
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
1.3 E-ll
1.1 E-12
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
1.5 E-ll
1.3 E-12
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
ND
ND
3.7 E-10
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
3.4 E-14
2.8 E-15
~
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
4.4 E-10
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
3.0 E-14
2.5 E-15
~
67-72-1
Hexachloroethane
ND
ND
5.9 E-04
110-54-3
Hexane
ND
ND
5.4 E-02
7647-01-0
Hydrochloric acid
6.8 E-05
5.6 E-06
~
74-90-8
Hydrogen cyanide
2.6 E-04
2.1 E-05
~
7664-39-3
Hydrogen fluoride
ND
ND
9.7 E-02
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
ND
2.7 E-03
78-59-1
Isophorone
ND
ND
2.7 E-03
7439-92-1
Lead
6.8 E-04
5.6 E-05
--
7439-96-5
Manganese
3.3 E-04
2.7 E-05
~
96-33-3
Methyl acrylate
ND
ND
2.5 E-04
74-95-3
Methylene bromide
ND
ND
5.1 E-04
75-09-2
Methylene chloride
1.2 E-07
1.0 E-08
--
74-88-4
Methyl iodide
ND
ND
3.5 E-04
108-10-1
Methyl isobutyl ketone
6.3 E-08
5.2 E-09
--
80-62-6
Methyl methacrylate
1.9 E-08
1.6 E-09
~
91-57-6
2-Methylnaphthalene
ND
ND
2.7 E-03
95-48-7
2-Methylphenol
ND
ND
2.7 E-03
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene
1.9 E-06
1.6 E-07
--
7440-02-0
Nickel
6.4 E-05
5.3 E-06
~
7697-37-2
Nitric acid
1.2E-03
9.5 E-05
--
100-01-6
4-Nitroaniline
ND
ND
2.7 E-03
98-95-3
Nitrobenzene
ND
ND
1.4 E-04
55-63-0
Nitroglycerin
3.5 E-07
2.9 E-08
--
88-75-5
2-Nitrophenol
ND
ND
2.7 E-03
A-30
Ordnance Detonation
9/06
-------
TABLE A4 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
100-02-7
4-Nitrophenol
ND
ND
2.7 E-03
62-75-9
n-Nitrosodimethylamine
ND
ND
2.7 E-03
86-30-6
n-Nitrosodiphenylamine
ND
ND
2.7 E-03
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
2.7 E-03
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
3.6 E-09
3.0 E-10
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
1.6 E-10
1.3 E-ll
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
6.2 E-10
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
ND
ND
4.2 E-10
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
3.9 E-14
3.2 E-15
--
87-86-5
Pentachlorophenol
ND
ND
2.7 E-03
85-01-8
Phenanthrene
1.4 E-06
1.1 E-07
--
108-95-2
Phenol
7.9 E-05
6.5 E-06
--
123-38-6
Propionaldehyde
ND
ND
5.1 E-03
115-07-1
Propylene
ND
ND
2.6 E-02
129-00-0
Pyrene
3.8 E-07
3.1 E-08
~
7782-49-2
Selenium
2.1 E-05
1.8 E-06
~
7440-22-4
Silver
ND
ND
1.4 E-03
100-42-5
Styrene
ND
ND
3.0 E-04
7664-93-9
Sulfuric acid
ND
ND
9.6 E-02
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
2.4 E-16
2.0 E-17
~
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
6.3 E-14
5.2 E-15
~
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-04
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-04
127-18-4
T etrachloroethy lene
ND
ND
4.1 E-04
7440-28-0
Thallium
ND
ND
1.4 E-03
108-88-3
Toluene
3.0 E-06
2.5 E-07
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.3 E-03
71-55-6
1,1,1 -Trichloroethane
7.0 E-08
5.8 E-09
--
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-04
75-69-4
Trichlorofluoromethane
4.0 E-10
3.3 E-ll
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
2.7 E-03
88-06-2
2,4,6-Trichlorophenol
ND
ND
2.7 E-03
96-18-4
1,2,3 -T richloropropane
ND
ND
4.9 E-04
9/06
Ordnance Detonation
A-31
-------
TABLE A4 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
95-63-6
1,2,4-Trimethylbenzene
2.0 E-08
1.7 E-09
--
540-84-1
2,2,4-Trimethylpentane
6.0 E-05
4.9 E-06
--
7440-62-2
Vanadium
ND
ND
1.4 E-03
108-05-4
Vinyl acetate
ND
ND
3.9 E-04
75-01-4
Vinyl chloride
7.5 E-07
6.2 E-08
--
75-35-4
Vinylidene chloride
ND
ND
2.1 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene
1.0E-06
8.5 E-08
--
95-47-6
o-Xylene
3.1 E-07
2.6 E-08
--
7440-66-6
Zinc
6.5 E-03
5.4 E-04
--
Other Po
lutants
67-64-1
Acetone
7.8 E-05
6.5 E-06
--
74-86-2
Acetylene
1.1 E-06
9.0 E-08
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
1.4 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
1.4 E-04
100-52-7
Benzaldehyde
ND
ND
5.1 E-03
100-51-6
Benzyl alcohol
ND
ND
2.7 E-03
108-86-1
Bromobenzene
ND
ND
3.9 E-04
106-97-8
Butane
ND
ND
5.3 E-02
71-36-3
l-Butanolf
1.1 E-07
9.2 E-09
--
106-98-9
1-Butene
ND
ND
3.5 E-02
590-18-1
cis-Butene
ND
ND
3.5 E-02
624-64-6
trans-Butene
ND
ND
3.5 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
3.4 E-02
7440-70-2
Calcium
4.0 E-03
3.3 E-04
--
7440-44-0
Elemental carbon
2.7 E-04
2.2 E-05
--
7440-44-0
Organic carbon
1.8 E-02
1.5 E-03
--
7440-44-0
Total carbon
1.8 E-02
1.5 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
2.7 E-03
59-50-7
4-Chloro-3 -methylphenol
ND
ND
2.7 E-03
124-48-1
Dibromochloromethane
ND
ND
5.2 E-04
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-04
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.8 E-04
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
2.8 E-04
A-32
Ordnance Detonation
9/06
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb
Minimum
Detection Level
mg/m3d
lb per item
lb per lb
NEWC
84-66-2
Diethylphthalate
ND
ND
2.7 E-03
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
5.1 E-03
117-84-0
Di-n-octylphthalate
ND
ND
2.7 E-03
74-84-0
Ethane
ND
ND
2.5 E-02
64-17-5
Ethanolf
2.6 E-05
2.2 E-06
--
141-78-6
Ethyl acetate
ND
ND
1.4 E-03
97-63-2
Ethyl methacrylate
ND
ND
3.3 E-04
622-96-8
4-Ethyltoluene
ND
ND
3.0 E-04
110-00-9
Furanf
2.5 E-07
2.1 E-08
--
109-99-9
Furan, tetrahydro-f
1.1 E-07
8.9 E-09
--
142-82-5
Heptane
ND
ND
2.1 E-04
66-25-1
Hexaldehyde
ND
ND
5.1 E-03
104-76-7
1-Hexanol, 2-ethylf
2.6 E-05
2.2 E-06
--
591-78-6
2-Hexanone
ND
ND
2.9 E-04
2691-41-0
HMX
ND
ND
2.8 E-04
10035-10-6
Hydrogen bromide
ND
ND
8.7 E-02
75-28-5
Isobutane
ND
ND
3.6 E-02
590-86-3
Isovaleraldehyde
ND
ND
5.1 E-03
7439-95-4
Magnesium
2.8 E-03
2.3 E-04
--
78-93-3
Methyl ethyl ketone
2.0 E-05
1.6 E-06
--
624-91-9
Methyl nitritef
3.9 E-05
3.3 E-06
--
98-83-9
alpha-Methyl styrene
ND
ND
2.9 E-04
479-45-8
Methyl-2,4,6-trinitrophenylnitramine
ND
ND
1.4 E-04
88-74-4
2-Nitroaniline
ND
ND
2.7 E-03
99-09-2
3-Nitroaniline
ND
ND
2.7 E-03
88-72-2
2-Nitrotoluene
ND
ND
1.4 E-04
99-08-1
3-Nitrotoluene
ND
ND
1.4 E-04
99-99-0
4-Nitrotoluene
ND
ND
1.4 E-04
506-42-3
9-Octadecan-l-ol, (E)-f
6.6 E-05
5.5 E-06
--
111-65-9
Octane
ND
ND
1.9 E-04
109-66-0
Pentane
ND
ND
4.5 E-02
14797-73-0
Perchlorate
ND
ND
1.2 E-01
7664-38-2
Phosphoric acid
ND
ND
8.7 E-02
463-49-0
l,2-Propadienef
1.8 E-07
1.5 E-08
--
74-98-6
Propane
ND
ND
3.7 E-02
9/06
Ordnance Detonation
A-33
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb
Minimum
Detection Level
mg/m3d
lb per item
lb per lb
NEWC
115-11-7
1-Propene, 2-methyl
ND
ND
3.5 E-02
74-99-7
Propyne
ND
ND
3.3 E-02
121-82-4
RDX
ND
ND
1.4 E-04
7440-24-6
Strontium
5.5 E-04
4.5 E-05
--
544-63-8
Tetradecanoic acidf
9.7 E-05
8.0 E-06
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
1.5 E-02
25323-89-1
Trichloroethane
ND
ND
3.0 E-04
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
2.5 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
1.4 E-04
118-96-7
2,4,6-Trinitrotoluene
4.2 E-05
3.5 E-06
--
110-62-3
Valeraldehyde
ND
ND
5.1 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c NEW = net explosive weight. The NEW for this ordnance is 1.43 E-02 pounds per item.
d Data provided for compounds that were not detected.
e Emission factor rated D because the factor is based upon C-rated test data.
f Emission factor rated D because the factor is for a tentatively identified compound.
A-34
Ordnance Detonation
9/06
-------
TABLE A5 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC G911, MK3A2 OFFENSIVE HAND GRENADE
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
5.6 E-01
1.1
630-08-0
Carbon monoxide8
1.2 E-02
2.5 E-02
74-82-8
Methane8
3.1 E-04
6.2 E-04
--
Oxides of nitrogenf
7.7 E-03
1.6 E-02
7446-09-5
Sulfur dioxide
4.9 E-05
9.8 E-05
Hazardous Air Pollutants and Toxic Chemicals
75-07-0
Acetaldehyde8
4.4 E-05
8.9 E-05
--
107-02-8
Acrolein
4.7 E-06
9.5 E-06
--
7664-41-7
Ammonia
ND
ND
3.5 E-01
106-99-0
1,3-Butadiene8
ND
ND
7.2 E-02
123-72-8
Butyraldehydeh
5.2 E-06
1.0 E-05
--
18540-29-9
Hexavalent chromium11
5.4 E-06
1.1 E-05
--
4170-30-3
Crotonaldehyde
5.2 E-06
1.0 E-05
--
74-85-1
Ethylene8
3.4 E-04
6.8 E-04
--
50-00-0
Formaldehyde
ND
ND
7.1 E-03
110-54-3
n-Hexane
ND
ND
7.2 E-02
123-38-6
Propionaldehyde
8.0 E-06
1.6 E-05
--
115-07-1
Propylene8
8.3 E-05
1.7 E-04
—
Other Po
lutants
67-64-1
Acetone
1.3 E-05
2.5 E-05
--
74-86-2
Acetylene8
2.0 E-04
4.1 E-04
--
100-52-7
Benzaldehyde
5.1 E-06
1.0 E-05
--
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butene
2.1 E-05
4.2 E-05
--
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene8
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-44-0
Elemental carbon8
6.8 E-03
1.4 E-02
--
7440-44-0
Organic carbon8
3.9 E-03
7.8 E-03
--
7440-44-0
Total carbon8
1.1 E-02
2.1 E-02
--
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.1 E-03
74-84-0
Ethane8
2.0 E-05
4.1 E-05
--
9/06
Ordnance Detonation
A-35
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
66-25-1
Hexaldehyde
ND
ND
7.1 E-03
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.1 E-03
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.3 E-01
74-98-6
Propane
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl-8
1.4 E-05
2.9 E-05
--
74-99-7
Propyne8
1.4 E-05
2.9 E-05
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.1 E-02
110-62-3
Valeraldehyde
2.0 E-06
4.0 E-06
--
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 4.96 E-01 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance
of test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
and number
and number
A-36
Ordnance Detonation
9/06
-------
TABLE A6 COMPOUNDS ANALYZED AND AVERAGE EMISSION FACTORS DEVELOPED
FOR DODIC G911, MK3A2 OFFENSIVE HAND GRENADE
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
6.2 E-01
1.3
--
630-08-0
Carbon monoxide8
1.4 E-02
2.8 E-02
--
7439-92-1
Lead
3.3 E-04
6.7 E-04
--
74-82-8
Methane8
2.9 E-04
5.9 E-04
--
--
Oxides of nitrogenf
7.4 E-03
1.5 E-02
--
--
PM-2.58
2.0 E-02
4.0 E-02
--
--
PM-10
3.5 E-02
7.0 E-02
--
7446-09-5
Sulfur dioxide
4.9 E-05
9.8 E-05
--
12789-66-1
Total suspended particulate
3.9 E-02
7.9 E-02
--
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
8.7 E-08
1.8 E-07
--
208-96-8
Acenaphthylene8
1.1 E-06
2.3 E-06
--
75-07-0
Acetaldehyde8
5.8 E-05
1.2 E-04
--
75-05-8
Acetonitrile8
2.1 E-05
4.2 E-05
--
107-02-8
Acrolein
4.7 E-06
9.5 E-06
--
107-13-1
Acrylonitrile8
3.9 E-06
7.8 E-06
--
107-05-1
Allyl chloride
ND
ND
8.9 E-04
7429-90-5
Aluminum8
3.1 E-04
6.2 E-04
--
7664-41-7
Ammonia
ND
ND
3.5 E-01
120-12-7
Anthracene8
1.5 E-07
3.0 E-07
--
7440-36-0
Antimony
ND
ND
2.1 E-02
7440-38-2
Arsenic
ND
ND
2.1 E-02
7440-39-3
Barium
3.3 E-04
6.6 E-04
--
71-43-2
Benzene8
3.7 E-05
7.5 E-05
--
56-55-3
Benzo [a] anthracene
1.1 E-07
2.2 E-07
--
205-99-2
Benzo [b] fluoranthene
8.0 E-08
1.6 E-07
--
207-08-9
Benzo [k] fluoranthene
6.6 E-08
1.3 E-07
~
191-24-2
Benzo [g,h,i]perylene
8.8 E-08
1.8 E-07
~
50-32-8
Benzo [a]pyrene
8.1 E-08
1.6 E-07
~
192-97-2
Benzo [e]pyrene
1.2 E-07
2.4 E-07
--
100-44-7
Benzyl chloride
ND
ND
2.6 E-04
7440-41-7
Beryllium
ND
ND
2.1 E-02
75-25-2
Bromoform
ND
ND
5.3 E-04
9/06
Ordnance Detonation
A-37
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.6 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
3.1 E-02
106-99-0
1,3-Butadiene8
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
4.0 E-04
85-68-7
Butylbenzylphthalatef
1.7 E-06
3.4 E-06
--
123-72-8
Butyraldehyde
5.2 E-06
1.0 E-05
--
7440-43-9
Cadmium
1.8 E-05
3.6 E-05
--
75-15-0
Carbon disulfide
1.7 E-06
3.4 E-06
--
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-04
106-47-8
4-Chloroaniline
ND
ND
3.1 E-02
108-90-7
Chlorobenzene
ND
ND
2.4 E-04
75-45-6
Chlorodifluoromethane
ND
ND
2.5 E-04
75-00-3
Chloroethane
ND
ND
6.2 E-04
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.6 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.6 E-02
67-66-3
Chloroform
ND
ND
4.0 E-04
74-87-3
Chloromethane8
1.5 E-07
3.0 E-07
--
91-58-7
2-Chloronaphthalene
ND
ND
1.6 E-02
95-57-8
2-Chlorophenol
ND
ND
1.6 E-02
7005-72-3
4-Chlorophenyl-phenylether
ND
ND
1.6 E-02
7440-47-3
Chromium8
2.8 E-05
5.6 E-05
--
18540-29-9
Hexavalent chromium1
3.1 E-06
6.3 E-06
--
218-01-9
Chrysene
1.3 E-07
2.6 E-07
--
7440-48-4
Cobalt8
ND
ND
2.1 E-02
7440-50-8
Copper8
2.3 E-04
4.6 E-04
--
106-44-5
p-Cresol
ND
ND
1.6 E-02
4170-30-3
Crotonaldehyde
5.2 E-06
1.0 E-05
--
98-82-8
Cumene8
ND
ND
2.0 E-04
57-12-5
Particulate cyanide
ND
ND
1.7 E-02
53-70-3
Dibenz [a,h] anthracene
3.0 E-08
6.1 E-08
--
132-64-9
Dibenzofuran
ND
ND
1.6 E-02
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-04
84-74-2
Dibutyl phthalatef
3.2 E-06
6.4 E-06
--
95-50-1
1,2-Dichlorobenzene
ND
ND
4.9 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
4.3 E-04
A-38
Ordnance Detonation
9/06
-------
TABLE A6 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
4.3 E-04
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
1.6 E-02
75-27-4
Dichlorobromomethane8
ND
ND
4.1 E-04
75-71-8
Dichlorodifluoromethane
0
0
--
75-34-3
1,1 -Dichloroethane
ND
ND
3.7 E-04
107-06-2
1,2-Dichloroethane
3.7 E-07
7.4 E-07
--
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.6 E-02
78-87-5
1,2-Dichloropropane
ND
ND
3.3 E-04
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
5.0 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.6 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.6 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.5 E-03
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.6 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.6 E-02
121-14-2
2,4-Dinitrotoluene
1.4 E-05
2.8 E-05
--
606-20-2
2,6-Dinitrotoluene
ND
ND
1.3 E-03
123-91-1
1,4-Dioxane
ND
ND
3.3 E-04
--
Total dioxin/furan compounds
2.9 E-10
5.9 E-10
--
140-88-5
Ethyl acrylate
ND
ND
1.7 E-04
100-41-4
Ethylbenzene8
8.5 E-07
1.7 E-06
--
74-85-1
Ethylene8
3.2 E-04
6.4 E-04
--
117-81-7
bis(2-Ethylhexyl)phthalatef
6.5 E-06
1.3 E-05
--
206-44-0
Fluoranthene8
3.2 E-07
6.4 E-07
--
86-73-7
Fluorene8
2.0 E-07
4.0 E-07
--
50-00-0
Formaldehyde
4.3 E-05
8.6 E-05
--
76-13-1
Freon 113s
ND
ND
5.5 E-04
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
2.1 E-ll
4.2 E-ll
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
2.8 E-12
5.6 E-12
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
3.4 E-09
118-74-1
Hexachlorobenzene
ND
ND
1.6 E-02
87-68-3
Hexachlorobutadiene
ND
ND
7.6 E-04
9/06
Ordnance Detonation
A-39
-------
TABLE A6 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.6 E-02
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
3.8 E-09
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
5.4 E-13
1.1 E-12
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
8.5 E-13
1.7 E-12
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
2.2 E-09
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
3.2 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
2.9 E-09
67-72-1
Hexachloroethane
ND
ND
5.9 E-04
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
ND
ND
2.1 E-01
74-90-8
Hydrogen cyanide
2.6 E-04
5.2 E-04
--
7664-39-3
Hydrogen fluoride
ND
ND
2.1 E-01
193-39-5
Indeno [ 1,2,3 -cd]pyrene
4.1 E-08
8.4 E-08
--
78-59-1
Isophorone
ND
ND
1.6 E-02
7439-92-1
Lead
3.3 E-04
6.7 E-04
--
7439-96-5
Manganese8
6.2 E-05
1.3 E-04
--
96-33-3
Methyl acrylate
ND
ND
2.5 E-04
74-95-3
Methylene bromide
ND
ND
5.1 E-04
75-09-2
Methylene chloride8
9.4 E-07
1.9 E-06
--
74-88-4
Methyl iodide
ND
ND
3.5 E-04
108-10-1
Methyl isobutyl ketone
ND
ND
3.3 E-04
80-62-6
Methyl methacrylate
ND
ND
4.6 E-04
91-57-6
2-Methylnaphthalene
ND
ND
1.6 E-02
95-48-7
2-Methylphenol
ND
ND
1.6 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene8
2.2 E-06
4.4 E-06
--
7440-02-0
Nickel8
1.5 E-05
3.0 E-05
--
7697-37-2
Nitric acid8
1.1 E-04
2.2 E-04
--
100-01-6
4-Nitroaniline
ND
ND
1.6 E-02
98-95-3
Nitrobenzene
ND
ND
6.5 E-04
55-63-0
Nitroglycerin
ND
ND
6.5 E-04
88-75-5
2-Nitrophenol
ND
ND
1.6 E-02
100-02-7
4-Nitrophenol
ND
ND
1.6 E-02
A-40
Ordnance Detonation
9/06
-------
TABLE A6 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
62-75-9
n-Nitrosodimethylamine
ND
ND
1.6 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.6 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.6 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
2.6 E-10
5.2 E-10
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
8.7 E-12
1.8 E-ll
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
4.0 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
ND
ND
3.3 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
1.8 E-09
87-86-5
Pentachlorophenol
ND
ND
1.6 E-02
85-01-8
Phenanthrene8
7.1 E-07
1.4 E-06
--
108-95-2
Phenol
1.7 E-06
3.5 E-06
--
123-38-6
Propionaldehyde
8.0 E-06
1.6 E-05
--
115-07-1
Propylene8
7.9 E-05
1.6 E-04
--
129-00-0
Pyrene8
4.8 E-07
9.6 E-07
--
7782-49-2
Selenium
ND
ND
2.1 E-02
7440-22-4
Silver
ND
ND
2.1 E-02
100-42-5
Styrene
ND
ND
3.0 E-04
7664-93-9
Sulfuric acid
3.7 E-05
7.5 E-05
--
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
2.4 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
1.3 E-12
2.6 E-12
--
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-04
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-04
127-18-4
T etrachloroethy lene
ND
ND
4.1 E-04
7440-28-0
Thallium
ND
ND
2.1 E-02
108-88-3
Toluene8
8.4 E-06
1.7 E-05
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.3 E-03
71-55-6
1,1,1 -T richloroethane
ND
ND
4.4 E-04
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-04
75-69-4
Trichlorofluoromethane
ND
ND
3.4 E-04
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.6 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.6 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
4.9 E-04
95-63-6
1,2,4-Trimethylbenzene8
4.4 E-07
8.9 E-07
--
9/06
Ordnance Detonation
A-41
-------
TABLE A6 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
540-84-1
2,2,4-Trimethylpentane8
ND
ND
1.9 E-04
7440-62-2
Vanadium
3.9 E-03
8.0 E-03
--
108-05-4
Vinyl acetate
ND
ND
3.9 E-04
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
2.1 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene8
7.7 E-07
1.6 E-06
--
95-47-6
o-Xylene8
2.3 E-07
4.7 E-07
--
7440-66-6
Zinc8
6.6 E-03
1.3 E-02
—
Other Po
lutants
67-64-1
Acetone
1.3 E-05
2.6 E-05
--
74-86-2
Acetylene8
1.9 E-04
3.9 E-04
--
35572-78-2
2-Amino-4,6-dinitrotoluene8
4.7 E-07
9.4 E-07
--
19406-51-0
4-Amino-2,6-dinitrotoluene
3.3 E-07
6.7 E-07
--
100-52-7
Benzaldehyde
5.1 E-06
1.0 E-05
--
100-51-6
Benzyl alcohol
ND
ND
1.6 E-02
108-86-1
Bromobenzene
ND
ND
3.9 E-04
460-12-8
1,3-Butadiyne1
1.8 E-06
3.7 E-06
--
106-97-8
Butane
ND
ND
5.3 E-02
123-73-9
2-Butenal, (E)-J
1.5 E-06
3.1 E-06
--
106-98-9
1-Butene
2.0 E-05
4.0 E-05
--
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
78-94-4
3-Buten-2-oneJ
3.6 E-06
7.2 E-06
--
689-97-4
l-Buten-3-yne1
1.3 E-06
2.7 E-06
--
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calciumf
4.8 E-04
9.6 E-04
--
7440-44-0
Elemental carbon8
5.7 E-03
1.2 E-02
--
7440-44-0
Organic carbon8
2.8 E-03
5.6 E-03
--
7440-44-0
Total carbon8
8.5 E-03
1.7 E-02
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.6 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.6 E-02
124-48-1
Dibromochloromethane
ND
ND
5.2 E-04
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-04
A-42
Ordnance Detonation
9/06
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.8 E-04
84-66-2
Diethylphthalate
ND
ND
1.6 E-02
5779-94-2
2,5-Dimethylbenzaldehyde
0
0
--
117-84-0
Di-n-octylphthalate
ND
ND
1.6 E-02
74-84-0
Ethane8
1.9 E-05
3.9 E-05
--
141-78-6
Ethyl acetate
ND
ND
1.4 E-03
97-63-2
Ethyl methacrylate
ND
ND
3.3 E-04
622-96-8
4-Ethyltoluene8
0
0
--
142-82-5
Heptane8
6.6 E-07
1.3 E-06
--
592-76-7
l-HepteneJ
6.1 E-06
1.2 E-05
--
66-25-1
Hexaldehyde
ND
ND
7.1 E-03
591-78-6
2-Hexanone
ND
ND
2.9 E-04
630-06-8
Hexatriacontane1
7.5 E-06
1.5 E-05
--
2691-41-0
HMX
ND
ND
1.3 E-03
592-41-6
1-Hexene1
1.3 E-05
2.6 E-05
--
10035-10-6
Hydrogen bromide
ND
ND
2.0 E-01
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.1 E-03
7439-95-4
Magnesium8
2.9 E-03
5.9 E-03
--
75-52-5
Methane, nitro-h
2.2 E-06
4.5 E-06
--
78-93-3
Methyl ethyl ketone
1.6 E-06
3.2 E-06
--
98-83-9
alpha-Methylstyrene
ND
ND
2.9 E-04
479-45-8
Methyl-2,4,6-trinitrophenylnitramine
ND
ND
6.5 E-04
88-74-4
2-Nitroaniline
ND
ND
1.6 E-02
99-09-2
3-Nitroaniline
ND
ND
1.6 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.5 E-04
99-08-1
3-Nitrotoluene
ND
ND
6.5 E-04
99-99-0
4-Nitrotoluene
ND
ND
6.5 E-04
111-65-9
Octane
6.6 E-07
1.3 E-06
--
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.3 E-01
7664-38-2
Phosphoric acid
ND
ND
2.0 E-01
74-98-6
Propane
ND
ND
3.7 E-02
78-85-3
2-Propenal, 2-methyl-
2.0 E-06
4.1 E-06
--
115-11-7
1-Propene, 2-methyl-8
1.3 E-05
2.7 E-05
--
9/06
Ordnance Detonation
A-43
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-99-7
Propyne8
1.4 E-05
2.7 E-05
--
121-82-4
RDX
7.7 E-06
1.6 E-05
--
7440-24-6
Strontium
2.9 E-03
5.9 E-03
--
7440-32-6
Titanium
1.8 E-05
3.6 E-05
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.1 E-02
25323-89-1
Trichloroethane
ND
ND
3.0E-04
108-67-8
1,3,5 -T rimethy lbenzene8
0
0
--
99-35-4
1,3,5 -T rinitrobenzene8
4.2 E-06
8.5 E-06
--
118-96-7
2,4,6-Trinitrotoluene
2.7 E-05
5.5 E-05
--
110-62-3
Valeraldehyde
2.0 E-06
4.0 E-06
--
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance varies from 4.94E-01 to 4.96E-01 pounds
per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
1 Emission factor rated D because the factor is for a tentatively identified compound.
J Emission factor rated D because the factor is based upon C-rated test data.
A-44
Ordnance Detonation
9/06
-------
TABLE A7 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC K051, M604 ANTI-TANK PRACTICE MINE FUZE
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3'd
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxide
3.6 E-03
9.6 E-02
--
630-08-0
Carbon monoxide
2.2 E-04
5.8 E-03
--
7439-92-1
Lead6
1.5 E-05
3.9 E-04
--
74-82-8
Methane
0
0
--
--
Oxides of nitrogen
ND
ND
9.6 E-01
--
PM-2.5
1.5 E-02
4.1 E-01
--
--
PM-10
2.0 E-02
5.2 E-01
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
1.9 E-02
5.1 E-01
--
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
0
0
--
208-96-8
Acenaphthylene
0
0
--
75-07-0
Acetaldehyde
ND
ND
7.8 E-03
75-05-8
Acetonitrile
6.1 E-08
1.6 E-06
--
107-02-8
Acrolein
ND
ND
7.5 E-03
107-13-1
Acrylonitrile6
3.6 E-07
9.4 E-06
--
107-05-1
Allyl chloride
ND
ND
8.9 E-04
7429-90-5
Aluminum
3.9 E-04
1.0 E-02
--
7664-41-7
Ammonia
ND
ND
3.5 E-01
120-12-7
Anthracene
3.2 E-09
8.4 E-08
--
7440-36-0
Antimony
9.0 E-06
2.4 E-04
--
7440-38-2
Arsenic
ND
ND
2.0 E-02
7440-39-3
Barium
1.6 E-06
4.3 E-05
--
71-43-2
Benzene6
2.0 E-07
5.2 E-06
--
56-55-3
Benzo [a] anthracene
5.6 E-09
1.5 E-07
--
205-99-2
Benzo [b] fluoranthene
1.4 E-08
3.6 E-07
--
207-08-9
Benzo [k] fluoranthene
5.2 E-08
1.4 E-06
~
191-24-2
Benzo [g,h,i]perylene
1.1 E-08
2.9 E-07
--
50-32-8
Benzo [a]pyrene
5.6 E-09
1.5 E-07
~
192-97-2
Benzo [e]pyrene
6.0 E-09
1.6 E-07
~
100-44-7
Benzyl chloride
ND
ND
2.6 E-04
7440-41-7
Beryllium
ND
ND
1.2 E-02
75-25-2
Bromoform
ND
ND
5.3 E-04
9/06
Ordnance Detonation
A-45
-------
TABLE A7 (cont.)
CASRN3
Compound
Emission Factorb
Minimum
Detection Level
mg/m3d
lb per item
lb per lb
NEWC
74-83-9
Bromomethane
ND
ND
3.6 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.7 E-02
106-99-0
1,3-Butadiene
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
4.0 E-04
85-68-7
Butylbenzylphthalate
ND
ND
1.7 E-02
123-72-8
Butyraldehyde
ND
ND
7.5 E-03
7440-43-9
Cadmium
5.8 E-05
1.5 E-03
--
75-15-0
Carbon disulfide
ND
ND
3.2 E-04
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-04
106-47-8
4-Chloroaniline
ND
ND
1.7 E-02
108-90-7
Chlorobenzene
ND
ND
2.4 E-04
75-45-6
Chlorodifluoromethane
ND
ND
2.5 E-04
75-00-3
Chloroethane
ND
ND
6.2 E-04
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.7 E-02
67-66-3
Chloroform
ND
ND
4.0 E-04
74-87-3
Chloromethane
ND
ND
2.9 E-04
91-58-7
2-Chloronaphthalene
ND
ND
1.7 E-02
95-57-8
2-Chlorophenol
ND
ND
1.7 E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.7 E-02
7440-47-3
Chromium
ND
ND
1.2 E-02
18540-29-9
Hexavalent chromium6
ND
ND
5.7 E-04
218-01-9
Chrysene
1.0 E-08
2.6 E-07
--
7440-48-4
Cobalt
ND
ND
2.3 E-02
7440-50-8
Copper
4.9 E-06
1.3 E-04
--
106-44-5
p-Cresol
ND
ND
1.7 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.5 E-03
98-82-8
Cumene
ND
ND
2.0 E-04
57-12-5
Particulate cyanide
ND
ND
1.1 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.7 E-02
132-64-9
Dibenzofuran
ND
ND
1.7 E-02
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-04
84-74-2
Dibutyl phthalate
ND
ND
1.7 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
4.9 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
4.3 E-04
A-46
Ordnance Detonation
9/06
-------
TABLE A7 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
106-46-7
1,4-Dichlorobenzene
ND
ND
4.3 E-04
75-27-4
Dichlorobromomethane
ND
ND
4.1 E-04
75-71-8
Dichlorodifluoromethane
0
0
--
75-34-3
1,1 -Dichloroethane
ND
ND
3.7 E-04
107-06-2
1,2-Dichloroethane
ND
ND
2.1 E-04
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.7E-02
78-87-5
1,2-Dichloropropane
ND
ND
3.3 E-04
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
5.0 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.5 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.5 E-04
606-20-2
2,6-Dinitrotoluene
ND
ND
6.5 E-04
123-91-1
1,4-Dioxane
ND
ND
3.3 E-04
--
Total dioxin/furan compounds
1.4 E-10
3.6 E-09
--
140-88-5
Ethyl acrylate
ND
ND
1.7 E-04
100-41-4
Ethylbenzene
ND
ND
3.1 E-04
74-85-1
Ethylene6
1.0 E-06
2.6 E-05
--
117-81-7
bis(2-Ethylhexyl)phthalate
0
0
--
206-44-0
Fluoranthene
4.2 E-08
1.1 E-06
--
86-73-7
Fluorene
5.7 E-10
1.5 E-08
--
50-00-0
Formaldehyde
3.7 E-08
9.7 E-07
--
76-13-1
Freon 113
ND
ND
5.5 E-04
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
1.2 E-12
3.0 E-ll
~
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
1.9 E-ll
5.1 E-10
~
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
4.6 E-12
1.2 E-10
--
118-74-1
Hexachlorobenzene6
8.6 E-06
2.2 E-04
~
87-68-3
Hexachlorobutadiene
ND
ND
7.6 E-04
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
9/06
Ordnance Detonation
A-47
-------
TABLE A7 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
1.3 E-13
3.5 E-12
--
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
2.3 E-13
6.1 E-12
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
4.5 E-13
1.2 E-ll
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
5.6 E-12
1.5 E-10
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
2.1 E-12
5.6 E-ll
~
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
1.9 E-13
5.1 E-12
--
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
1.9 E-12
4.9 E-ll
~
67-72-1
Hexachloroethane
ND
ND
5.9 E-04
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
2.0 E-04
5.3 E-03
~
74-90-8
Hydrogen cyanide
ND
ND
1.8 E-02
7664-39-3
Hydrogen fluoride
ND
ND
9.9 E-02
193-39-5
Indeno [ 1,2,3 -cd]pyrene
1.9 E-08
4.9 E-07
~
78-59-1
Isophorone
ND
ND
1.7 E-02
7439-92-1
Lead6
1.5 E-05
3.9 E-04
~
7439-96-5
Manganese
8.3 E-07
2.2 E-05
--
96-33-3
Methyl acrylate
ND
ND
2.5 E-04
74-95-3
Methylene bromide
ND
ND
5.1 E-04
75-09-2
Methylene chloride
6.4 E-08
1.7 E-06
--
74-88-4
Methyl iodide
ND
ND
3.5 E-04
108-10-1
Methyl isobutyl ketone
ND
ND
3.3 E-04
80-62-6
Methyl methacrylate6
2.7 E-08
7.0 E-07
--
91-57-6
2-Methylnaphthalene
ND
ND
1.7 E-02
95-48-7
2-Methylphenol
ND
ND
1.7 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene
3.0 E-09
7.8 E-08
--
7440-02-0
Nickel
ND
ND
2.3 E-02
7697-37-2
Nitric acid
ND
ND
9.8 E-02
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
ND
ND
6.5 E-04
55-63-0
Nitroglycerin
ND
ND
6.5 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
A-48
Ordnance Detonation
9/06
-------
TABLE A7 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
2.1 E-ll
5.5 E-10
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
6.3 E-ll
1.7 E-09
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
1.6 E-12
4.3 E-ll
--
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
1.2 E-12
3.2 E-ll
~
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
1.6 E-12
4.1 E-ll
~
87-86-5
Pentachlorophenol
ND
ND
1.7 E-02
85-01-8
Phenanthrene
3.3 E-08
8.6 E-07
--
108-95-2
Phenol
ND
ND
1.7 E-02
123-38-6
Propionaldehyde
ND
ND
7.5 E-03
115-07-1
Propylene
ND
ND
3.5 E-02
129-00-0
Pyrene
2.5 E-08
6.5 E-07
~
7782-49-2
Selenium
ND
ND
2.0 E-02
7440-22-4
Silver
ND
ND
2.0 E-03
100-42-5
Styrene
ND
ND
3.0 E-04
7664-93-9
Sulfuric acid
ND
ND
9.8 E-02
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1.1 E-ll
2.8 E-10
~
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
3.0 E-12
7.8 E-ll
~
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-04
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-04
127-18-4
T etrachloroethy lene
ND
ND
4.1 E-04
7440-28-0
Thallium
ND
ND
2.3 E-02
108-88-3
Toluene
4.8 E-08
1.3 E-06
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.3 E-03
71-55-6
1,1,1 -T richloroethane
ND
ND
4.4 E-04
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-04
75-69-4
Trichlorofluoromethane
0
0
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-02
95-63-6
1,2,4-Trimethylbenzene
ND
ND
2.5 E-04
540-84-1
2,2,4-Trimethylpentane
ND
ND
1.9 E-04
9/06
Ordnance Detonation
A-49
-------
TABLE A7 (cont.)
Emission Factorb
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWC
Detection Level
mg/m3d
108-05-4
Vinyl acetate
ND
ND
3.9 E-04
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
2.1 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene
ND
ND
4.0 E-04
95-47-6
o-Xylene
ND
ND
4.9 E-04
7440-66-6
Zinc
1.3 E-03
3.5 E-02
—
Other Po
lutants
67-64-1
Acetone
1.3 E-07
3.4 E-06
--
74-86-2
Acetylene
6.4 E-07
1.7 E-05
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
6.5 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.5 E-04
100-52-7
Benzaldehyde
ND
ND
7.5 E-03
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
3.9 E-04
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butene
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calcium
2.6 E-07
6.8 E-06
--
7440-44-0
Elemental carbon
4.0 E-05
1.1 E-03
--
7440-44-0
Organic carbon
1.9 E-05
5.0 E-04
--
7440-44-0
Total carbon
5.9 E-05
1.6 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.7 E-02
124-48-1
Dibromochloromethane
ND
ND
5.2 E-04
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-04
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.8 E-04
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
2.8 E-04
84-66-2
Diethylphthalate
ND
ND
1.7 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.5 E-03
117-84-0
Di-n-octylphthalate
ND
ND
1.7 E-02
74-84-0
Ethane
ND
ND
2.5 E-02
A-50
Ordnance Detonation
9/06
-------
TABLE A7 (cont.)
CASRN3
Compound
Emission Factorb
Minimum
Detection Level
mg/m3d
lb per item
lb per lb
NEWC
141-78-6
Ethyl acetate
ND
ND
1.4 E-03
97-63-2
Ethyl methacrylate
ND
ND
3.3 E-04
622-96-8
4-Ethyltoluene
ND
ND
3.0 E-04
142-82-5
n-Heptane
ND
ND
2.1 E-04
66-25-1
Hexaldehyde
ND
ND
7.5 E-03
591-78-6
2-Hexanone
ND
ND
2.9 E-04
2691-41-0
HMX
ND
ND
6.5 E-03
10035-10-6
Hydrogen bromide
ND
ND
9.8 E-02
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.5 E-03
7439-95-4
Magnesium
7.0 E-07
1.8 E-05
--
78-93-3
Methyl ethyl ketone
ND
ND
8.1 E-04
98-83-9
alpha-Methylstyrene
ND
ND
2.9 E-04
479-45-8
Methyl-2,4,6-trinitrophenylnitramine
ND
ND
6.5 E-04
88-74-4
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.5 E-04
99-08-1
3-Nitrotoluene
ND
ND
6.5 E-04
99-99-0
4-Nitrotoluene
ND
ND
3.2 E-03
111-65-9
Octane
ND
ND
1.9 E-04
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.3 E-01
7664-38-2
Phosphoric acid
ND
ND
9.8 E-02
463-49-0
l,2-Propadienef
5.9 E-08
1.6 E-06
--
74-98-6
Propane
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl
ND
ND
4.7 E-02
74-99-7
Propyne
ND
ND
3.3 E-02
121-82-4
RDX
ND
ND
6.5 E-04
7440-24-6
Strontium
ND
ND
2.3 E-02
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.3 E-02
25323-89-1
Trichloroethane
ND
ND
3.0 E-04
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
2.5 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
6.5 E-04
118-96-7
2,4,6-Trinitrotoluene
ND
ND
6.5 E-04
110-62-3
Valeraldehyde
ND
ND
7.5 E-03
9/06
Ordnance Detonation
A-51
-------
TABLE A7 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c NEW = net explosive weight. The NEW for this ordnance is 3.81 E-02 pounds per item.
d Data provided for compounds that were not detected.
e Emission factor rated D because the factor is based upon C-rated test data.
f Emission factor rated D because the factor is for a tentatively identified compound.
A-52
Ordnance Detonation
9/06
-------
TABLE A8 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC L720, M26 TARGET KILL SIMULATOR
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxide8
3.9 E-01
2.9 E-01
--
630-08-0
Carbon monoxide8
2.1 E-01
1.5 E-01
--
7439-92-1
Lead8
ND
ND
4.7 E-02
74-82-8
Methane
1.2 E-04
8.9 E-05
--
--
Oxides of nitrogen8
4.4 E-04
3.2 E-04
--
--
PM-2.5
2.7 E-02
2.0 E-02
--
--
PM-108
5.2 E-02
3.8 E-02
--
7446-09-5
Sulfur dioxide
3.2 E-05
2.4 E-05
--
12789-66-1
Total suspended particulate8
6.8 E-02
5.0 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
1.9 E-06
1.4 E-06
--
208-96-8
Acenaphthylene
3.2 E-04
2.4 E-04
--
75-07-0
Acetaldehyde
1.1 E-05
7.8 E-06
--
75-05-8
Acetonitrile8
1.5 E-06
1.1 E-06
--
107-02-8
Acrolein
1.8 E-05
1.3 E-05
--
107-13-1
Acrylonitrile8
3.2 E-07
2.4 E-07
--
107-05-1
Allyl chloride
ND
ND
8.9 E-04
7429-90-5
Aluminum8
ND
ND
4.7 E-02
7664-41-7
Ammonia
ND
ND
3.5 E-01
120-12-7
Anthracene
7.6 E-06
5.6 E-06
--
7440-36-0
Antimony
ND
ND
4.7 E-02
7440-38-2
Arsenic
ND
ND
4.7 E-02
7440-39-3
Barium
ND
ND
2.3 E-02
71-43-2
Benzene
3.8 E-03
2.8 E-03
--
56-55-3
Benzo [a] anthracene
6.6 E-06
4.9 E-06
--
205-99-2
Benzo [b] fluoranthene
2.7 E-05
2.0 E-05
--
207-08-9
Benzo [k] fluoranthene
3.5 E-05
2.6 E-05
--
191-24-2
Benzo [g,h,i]perylene
8.4 E-06
6.3 E-06
--
50-32-8
Benzo [a]pyrene
8.9 E-06
6.6 E-06
--
192-97-2
Benzo [e]pyrene
5.6 E-06
4.2 E-06
~
100-44-7
Benzyl chloride
ND
ND
2.6 E-04
7440-41-7
Beryllium
ND
ND
2.3 E-02
75-25-2
Bromoform
ND
ND
5.3 E-04
9/06
Ordnance Detonation
A-53
-------
TABLE A8 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.6 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
8.2 E-02
106-99-0
1,3-Butadiene
4.9 E-05
3.6 E-05
--
75-65-0
t-Butyl alcohol
ND
ND
4.0 E-04
85-68-7
Butylbenzylphthalate8
ND
ND
8.2 E-02
123-72-8
Butyraldehyde
ND
ND
7.8 E-03
7440-43-9
Cadmium
ND
ND
2.3 E-02
75-15-0
Carbon disulfide8
2.4 E-06
1.8 E-06
--
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-04
106-47-8
4-Chloroaniline
ND
ND
8.2 E-02
108-90-7
Chlorobenzene
8.0 E-07
6.0 E-07
--
75-45-6
Chlorodifluoromethane
ND
ND
2.5 E-04
75-00-3
Chloroethane
ND
ND
6.2 E-04
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
8.2 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
8.2 E-02
67-66-3
Chloroform
ND
ND
4.0 E-04
74-87-3
Chloromethane
2.3 E-06
1.7 E-06
--
91-58-7
2-Chloronaphthalene
ND
ND
8.2 E-02
95-57-8
2-Chlorophenol
ND
ND
8.2 E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
8.2 E-02
7440-47-3
Chromium8
ND
ND
2.3 E-02
18540-29-9
Hexavalent chromium
ND
ND
5.6 E-04
218-01-9
Chrysene
8.9 E-06
6.6 E-06
--
7440-48-4
Cobalt
ND
ND
4.7 E-02
7440-50-8
Copper
ND
ND
4.7 E-02
106-44-5
p-Cresol
ND
ND
8.2 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.8 E-03
98-82-8
Cumene
ND
ND
2.0 E-04
57-12-5
Particulate cyanide
ND
ND
1.0 E-02
53-70-3
Dibenz [a,h] anthracene
6.6 E-07
4.9 E-07
--
132-64-9
Dibenzofuran
ND
ND
8.2 E-02
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-04
84-74-2
Dibutyl phthalate
ND
ND
8.2 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
4.9 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
4.3 E-04
A-54
Ordnance Detonation
9/06
-------
TABLE A8 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
4.3 E-04
75-27-4
Dichlorobromomethane
ND
ND
4.1 E-04
75-71-8
Dichlorodifluoromethane
0
0
--
75-34-3
1,1 -Dichloroethane
ND
ND
3.7 E-04
107-06-2
1,2-Dichloroethane1
7.8 E-06
5.8 E-06
--
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
8.2 E-02
78-87-5
1,2-Dichloropropane
ND
ND
3.3 E-04
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
5.0 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
8.2 E-02
131-11-3
Dimethyl phthalate
ND
ND
8.2 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.4 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
8.2 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
8.2 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.4 E-04
606-20-2
2,6-Dinitrotoluene
ND
ND
6.4 E-04
123-91-1
1,4-Dioxane
ND
ND
3.3 E-04
--
Total dioxin/furan compounds
4.1 E-12
3.0 E-12
--
140-88-5
Ethyl acrylate
ND
ND
1.7 E-04
100-41-4
Ethylbenzene
3.8 E-06
2.8 E-06
--
74-85-1
Ethylene11
1.1 E-03
8.4 E-04
--
117-81-7
bis(2-Ethylhexyl)phthalate
3.4 E-06
2.5 E-06
--
206-44-0
Fluoranthene
4.1 E-05
3.0 E-05
--
86-73-7
Fluorene
4.5 E-06
3.3 E-06
--
50-00-0
Formaldehyde
7.4 E-07
5.5 E-07
--
76-13-1
Freon 113
ND
ND
5.5 E-04
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin8
1.9 E-13
1.4 E-13
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
6.0 E-13
4.4 E-13
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
2.4 E-13
1.8 E-13
--
118-74-1
Hexachlorobenzene
ND
ND
8.2 E-02
87-68-3
Hexachlorobutadiene
ND
ND
7.6 E-04
77-47-4
Hexachlorocyclopentadiene
ND
ND
8.2 E-02
9/06
Ordnance Detonation
A-55
-------
TABLE A8 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
3.6 E-10
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
3.9 E-10
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
3.4 E-10
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran1
2.4 E-13
1.8 E-13
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
2.0 E-13
1.5 E-13
--
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
1.7 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
1.7 E-13
1.3 E-13
--
67-72-1
Hexachloroethane
ND
ND
5.9 E-04
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
1.3 E-05
9.7 E-06
--
74-90-8
Hydrogen cyanide
ND
ND
1.8 E-02
7664-39-3
Hydrogen fluoride
ND
ND
8.7 E-02
193-39-5
Indeno [ 1,2,3 -cd]pyrene
1.7 E-05
1.2 E-05
--
78-59-1
Isophorone
ND
ND
8.2 E-02
7439-92-1
Lead
ND
ND
4.7 E-02
7439-96-5
Manganese8
ND
ND
2.3 E-02
96-33-3
Methyl acrylate
ND
ND
2.5 E-04
74-95-3
Methylene bromide
ND
ND
5.1 E-04
75-09-2
Methylene chloride
2.4 E-06
1.8 E-06
--
74-88-4
Methyl iodide
ND
ND
3.5 E-04
108-10-1
Methyl isobutyl ketone
ND
ND
3.3 E-04
80-62-6
Methyl methacrylate
ND
ND
4.6 E-04
91-57-6
2-Methylnaphthalene
4.6 E-05
3.4 E-05
--
95-48-7
2-Methylphenol
ND
ND
8.2 E-02
1634-04-4
Methyl tert-butyl ether1
0
0
--
91-20-3
Naphthalene
1.0 E-03
7.7 E-04
--
7440-02-0
Nickel8
6.1 E-06
4.5 E-06
~
7697-37-2
Nitric acid
ND
ND
8.7 E-02
100-01-6
4-Nitroaniline
ND
ND
8.2 E-02
98-95-3
Nitrobenzene
ND
ND
6.4 E-04
55-63-0
Nitroglycerin
ND
ND
6.4 E-04
88-75-5
2-Nitrophenol
ND
ND
8.2 E-02
100-02-7
4-Nitrophenol
ND
ND
8.2 E-02
A-56
Ordnance Detonation
9/06
-------
TABLE A8 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
62-75-9
n-Nitrosodimethylamine
ND
ND
8.2 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
8.2 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
8.2 E-02
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
1.2 E-12
9.0 E-13
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
1.1 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
1.5 E-13
1.1 E-13
--
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
2.2 E-13
1.6 E-13
--
87-86-5
Pentachlorophenol
ND
ND
8.2 E-02
85-01-8
Phenanthrene
4.2 E-05
3.1 E-05
--
108-95-2
Phenol
ND
ND
8.2 E-02
123-38-6
Propionaldehyde
ND
ND
7.7 E-03
115-07-1
Propylene8
1.5 E-04
1.1 E-04
--
129-00-0
Pyrene
2.5 E-05
1.9 E-05
--
7782-49-2
Selenium
ND
ND
4.7 E-02
7440-22-4
Silver
ND
ND
4.8 E-03
100-42-5
Styrene
2.4 E-04
1.8 E-04
--
7664-93-9
Sulfuric acid
ND
ND
8.7 E-02
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
7.1 E-10
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
9.1 E-13
6.7 E-13
--
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-04
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-04
127-18-4
T etrachloroethy lene
ND
ND
4.1 E-04
7440-28-0
Thallium
ND
ND
4.7 E-02
108-88-3
Toluene
2.1 E-04
1.5 E-04
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.3 E-03
71-55-6
1,1,1 -T richloroethane
ND
ND
4.4 E-04
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-04
75-69-4
Trichlorofluoromethane
0
0
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
8.2 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
8.2 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
4.9 E-04
95-63-6
1,2,4-Trimethylbenzene
ND
ND
2.5 E-04
540-84-1
2,2,4-Trimethylpentane
ND
ND
1.9 E-04
9/06
Ordnance Detonation
A-57
-------
TABLE A8 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
108-05-4
Vinyl acetate
ND
ND
3.9 E-04
75-01-4
Vinyl chloride
3.1 E-07
2.3 E-07
--
75-35-4
Vinylidene chloride
ND
ND
2.1 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene
6.9 E-06
5.1 E-06
--
95-47-6
o-Xylene
2.6 E-06
2.0 E-06
--
7440-66-6
Zincf
ND
ND
2.3 E-02
Other Po
lutants
67-64-1
Acetone8
8.3 E-07
6.1 E-07
--
74-86-2
Acetylene11
2.7 E-03
2.0 E-03
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
6.4 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.4 E-04
100-52-7
Benzaldehyde
4.7 E-05
3.5 E-05
--
100-51-6
Benzyl alcohol
ND
ND
8.2 E-02
271-89-6
Benzofurank
2.1 E-05
1.6 E-05
--
108-86-1
Bromobenzene
ND
ND
3.9 E-04
460-12-8
1,3-Butadiynek
3.3 E-05
2.5 E-05
--
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butene
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene8
ND
ND
4.7 E-02
689-97-4
l-Buten-3-ynek
5.2 E-05
3.8 E-05
--
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne1
1.9 E-05
1.4 E-05
--
7440-70-2
Calcium1
2.3 E-05
1.7 E-05
--
7440-44-0
Elemental carbon
1.9 E-02
1.4 E-02
--
7440-44-0
Organic carbon
7.8 E-04
5.8 E-04
--
7440-44-0
Total carbon
2.0 E-02
1.5 E-02
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
8.2 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
8.2 E-02
124-48-1
Dibromochloromethane
ND
ND
5.2 E-04
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-04
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.8 E-04
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
2.8 E-04
84-66-2
Diethylphthalate8
ND
ND
8.2 E-02
A-58
Ordnance Detonation
9/06
-------
TABLE A8 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.8 E-03
117-84-0
Di-n-octylphthalate
ND
ND
8.2 E-02
74-84-0
Ethane11
2.5 E-05
1.9 E-05
--
141-78-6
Ethyl acetate
ND
ND
1.4 E-03
97-63-2
Ethyl methacrylate
ND
ND
3.3 E-04
622-96-8
4-Ethyltoluene
2.6 E-07
1.9 E-07
--
935-14-8
1,4-bis(Ethynyl)benzenek
4.5 E-06
3.3 E-06
--
142-82-5
n-Heptane
ND
ND
2.1 E-04
66-25-1
Hexaldehyde
ND
ND
7.8 E-03
10420-90-3
1,3 -Hexadien-5 -ynek
2.2 E-06
1.6 E-06
--
591-78-6
2-Hexanone
ND
ND
2.9 E-04
2691-41-0
HMX
ND
ND
6.4 E-03
10035-10-6
Hydrogen bromide
ND
ND
8.7 E-02
767-59-9
lH-Indene, 1-methyl-k
1.8 E-06
1.4 E-06
--
95-13-6
Indenek
1.2 E-04
8.9 E-05
--
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.8 E-03
7439-95-4
Magnesium8
ND
ND
4.7 E-02
78-93-3
Methyl ethyl ketone1
1.9 E-07
1.4 E-07
--
98-83-9
alpha-Methylstyrene
6.7 E-06
5.0 E-06
--
479-45-8
Methyl-2,4,6-trinitrophenylnitramine
ND
ND
6.4 E-04
88-74-4
2-Nitroaniline
ND
ND
8.2 E-02
99-09-2
3-Nitroaniline
ND
ND
8.2 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.4 E-04
99-08-1
3-Nitrotoluene
ND
ND
6.4 E-04
99-99-0
4-Nitrotoluene
ND
ND
1.6 E-03
111-65-9
Octane1
8.2 E-07
6.0 E-07
--
536-74-3
Phenylethynek
2.0 E-04
1.5 E-04
--
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.2 E-01
7664-38-2
Phosphoric acid
ND
ND
8.7 E-02
74-98-6
Propane
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl
ND
ND
4.7 E-02
74-99-7
Propyne1
6.7 E-05
5.0 E-05
--
121-82-4
RDX
ND
ND
6.4 E-04
9/06
Ordnance Detonation
A-59
-------
TABLE A8 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
7440-24-6
Strontium
ND
ND
4.7 E-02
110-02-1
Thiophene1
2.7E-06
2.0E-06
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.3 E-02
25323-89-1
Trichloroethane
ND
ND
3.0E-04
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
2.5 E-04
99-35-4
1,3,5-Trinitrobenzene1
0
0
--
118-96-7
2,4,6-Trinitrotoluene1
8.6 E-07
6.4 E-07
--
110-62-3
Valeraldehyde
ND
ND
7.8 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 1.35 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
1 Emission factor rated D because the factor is based upon C-rated test data.
J Emission factor was originally rated D because the factor is for a tentatively identified compound, but
because of correlation with emission factors for similar ordnance and number of data points the factor
was upgraded from a D rating to a C rating.
k Emission factor rated D because the factor is for a tentatively identified compound.
A-60
Ordnance Detonation
9/06
-------
APPENDIX B
NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN EXPLODING ORDNANCE
EMISSION STUDY PHASE II SERIES 6 TESTING AT ABERDEEN PROVING GROUND,
MARYLAND
Electronic versions of the new AP-42 sections for ordnance included in Exploding Ordnance
Emission Study Phase II Series 6 testing at Aberdeen Proving Ground, Maryland, are located on the EPA
website at: http://www.epa.gov/ttn/chief/ap42/index.html.
9/06
Ordnance Detonation
B-l
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B-2 Ordnance Detonation 9/06
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APPENDIX C
PUBLIC COMMENTS ON AP-42 SECTIONS FOR ORDNANCE INCLUDED IN
EXPLODING ORDNANCE EMISSION STUDY PHASE II SERIES 6 TESTING AT
ABERDEEN PROVING GROUND, MARYLAND
9/06
Ordnance Detonation
C-l
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Ordnance Detonation
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