BACKGROUND DOCUMENT
REPORT ON REVISIONS TO 5th EDITION AP-42
CHAPTER 15 - ORDNANCE DETONATION
EMISSION FACTORS DEVELOPED BASED ON PHASE IV-B TESTING
CONDUCTED AT DUGWAY PROVING GROUND, UTAH
Prepared for:
U.S. Army Environmental Command
ATTN: IMAE-ATT
Aberdeen Proving Ground. Maryland 21010-5401
June 2007
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NOTICE
The information in this document has been funded by the U.S. Army Environmental Command
(USAEC) and prepared by MACTEC Federal Programs, Inc., under Contract No. GS-10F-01571K, Order
No. W911SR-05-F-0023. It has been reviewed by the U.S. Environmental Protection Agency (EPA)
Office of Air Quality Planning and Standards (OAQPS) and has been approved for publication. Mention
of trade names or commercial products does not constitute endorsement or recommendation for use.
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TABLE OF CONTENTS
1.0 INTRODUCTION 1
2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS 2
2.1 Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide 4
2.2 Total Suspended Particulate 5
2.3 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 Microns 5
2.4 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 2.5 Microns 5
2.5 Metals 6
2.6 Hydrochloric Acid, Chlorine, and Ammonia 6
2.7 Volatile Organic Compounds 6
2.8 Semivolatile Organic Compounds 6
2.9 Dioxin and Furan Compounds 7
2.10 Formaldehyde 7
2.11 Hydrogen Cyanide 7
2.12 Energetic Materials 7
2.13 Tracer Compound 7
3.0 TEST DATA ANALYSIS AND RATING 8
3.1 EPA Guidance Regarding Test Data Quality Ratings 8
3.2 Analysis of Test Data 9
3.3 Test Data Quality Ratings 15
4.0 EMISSION FACTOR CALCULATIONS 19
4.1 Incorporation of Analytical Detection-Limits to the Test Data 20
4.2 Determination of Background Concentration 20
4.3 Determination of Test Compound Concentration 21
4.4 Determination of Background-Corrected Concentration 21
4.5 Determination of Dilution-Corrected Concentration 21
4.6 Determination of Mass of Compound Released 21
4.7 Determination of Emission Factors 23
4.8 Determination of Average Emission Factors 23
5.0 EMISSION FACTOR RATINGS 23
5.1 Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data 24
5.2 Emission Factor Ratings Assigned - Based on All Available Test Data 24
6.0 REFERENCES 33
APPENDIX A: COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
ORDNANCE INCLUDED IN PHASE IV-B TESTING AT DUGWAY
PROVING GROUND, UTAH
APPENDIX B: NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN PHASE IV-B
TESTING AT DUGWAY PROVING GROUND, UTAH
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LIST OF TABLES
No. Title Page
1 Ordnance for Which Emission Factors were Developed 1
2 Ordnance Net Explosive Weight 2
3 Sampling and Analytical Methods Used 3
4 Selected Sampling or Analytical Method for Compounds Measured Using Two Sampling or
Analytical Methods 10
5 Compounds for Which Large Relative Percent Differences Were Noted Between Test
Runs or Sample Trains 12
6 Downgraded Data Quality Ratings 15
7 Ordnance Categorization for Emission Factor Correlation Assessment 25
LIST OF FIGURES
No. Title Page
1 Calculation of background-corrected concentration (BCC) 22
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1.0 INTRODUCTION
Due to the lack of credible data concerning emissions from training ordnance when used in their
tactical configurations, the U.S. Army Environmental Command (USAEC) established a program to
quantify emissions from the detonation of ordnance. This document presents background information
concerning the development of air emission factors for five ordnance types used during training exercises
at U.S. Army installations. The air emission factors were developed from test data collected by USAEC.
Ordnance for which emission factors have been developed and their corresponding AP-42 sections are
identified in Table 1. To help readers easily find those emission factors of interest, the ordnance are
organized according to their Department of Defense Identification Code (DODIC).
TABLE 1 ORDNANCE FOR WHICH EMISSION FACTORS WERE DEVELOPED
DODIC
Ordnance Description
AP-42 Section
B535
M583A1 40-mm White Star Parachute Cartridge
15.2.3
B536
M585 40-mm White Star Cluster Cartridge
15.2.4
L366
M74A1 Air Burst Projectile Simulator
15.8.7
L602
M21 Artillery Flash Simulator
15.8.18
M241
M10 High Explosive Universal Destructor
15.9.11
The emission factors described in this document are based on data obtained during testing
conducted at Dugway Proving Ground, Utah, as presented in the final test report titled Sampling Results
for AEC Phase IV-B Emission Characterization of Exploding Ordnance and Smoke/Pyrotechnics1 and the
document titled Detailed Test Plan for Phase IV-B Emission Characterization of Exploding Ordnance2
These documents were supplemented by additional data provided by the testing contractor.3 For each
ordnance, two test runs were conducted. Two items per run were detonated for the M583A1 white star
parachute cartridge (DODIC B535) and the M585 white star cluster cartridge (DODIC B536). Five items
per run were detonated for the M74A1 projectile air burst simulator (DODIC L366) and the M21 flash
artillery simulator (L602). One item per run was detonated for the M10 high explosive (HE) universal
destructor (DODIC M241). Source test protocols were developed by USAEC before any testing was
conducted and were reviewed by the U.S. Environmental Protection Agency's (EPA's) Emission
Measurement Center. The tests were conducted between April 23 and 25, 2002.
The compounds that were measured included carbon monoxide (CO), carbon dioxide (C02),
oxides of nitrogen (NOx), sulfur dioxide (S02), total suspended particulate (TSP), particulate matter with
an aerodynamic diameter less than or equal to 10 microns (PM-10), particulate matter with an
aerodynamic diameter less than or equal to 2.5 microns (PM-2.5), metals, hydrogen chloride (HC1),
chlorine (Cl2), ammonia (NH3), volatile organic compounds (VOC), semivolatile organic compounds
(SVOC), formaldehyde, hydrogen cyanide, energetics, dioxins/furans (PCDD/PCDF), and sulfur
hexafluoride (SF6). Within each of the AP-42 sections, only emission factors for criteria pollutants,
carbon dioxide, hazardous air pollutants (as defined by § 112(b)( 1) of the Clean Air Act [CAA]), and toxic
chemicals (as defined by §313 of the Emergency Planning and Community Right-to-Know Act [EPCRA])
are presented.
The emission factors were developed on a "per item" basis and on a "per net explosive weight
(NEW)" basis. Users should choose the appropriate emission factor to estimate emissions based upon the
data available; either factor is equally valid. The NEW of each ordnance tested is provided in the
corresponding AP-42 section and in Table 2.
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TABLE 2 ORDNANCE NET EXPLOSIVE WEIGHT
DODIC
Ordnance Description
NEW (lb/item)a
B535
M583A1 40-mm White Star Parachute Cartridge
2.07 E-01
B536
M585 40-mm White Star Cluster Cartridge
1.91 E-01
L366
M74A1 Air Burst Projectile Simulator
8.99 E-02
L602
M21 Artillery Flash Simulator
9.38 E-02
M241
M10 HE Universal Destructor
2.86 E-01
aNEW values were obtained from References 1, 2, and 3.
This document includes five sections in addition to this Introduction. Section 2 of this document
identifies the compounds measured during the test program and describes the emission measurement
methods used. Section 3 includes a discussion of the emission factor final test report and ratings for the
test data contained therein. Section 4 describes the calculations and methodologies used to develop
emission factors for each type of compound measured. Section 5 describes the methodology used to rate
the emission factors and provides emission factor ratings for each type of compound measured. Section 6
includes a complete list of the references cited in this document.
There are two appendices included with this document. Appendix A identifies, by ordnance type,
all of the compounds for which analyses were performed and the emission factors that were developed.
[Note: Compounds present in the method blank at greater than 50 percent of test levels are excluded from
Appendix A as described in Section 3.2.4. | Appendix A also identifies the minimum detection levels
associated with all compounds that were not detected. Emission factors and minimum detection levels
presented in Appendix A were determined from the most accurate method if two sampling or analytical
methods were used to measure one compound. Appendix B presents the new AP-42 sections for the five
ordnance that were tested.
In addition to this document, there are electronic databases available on the web
(http://www.epa.gov/ttn/chief/ap42/index.htiril) that contain the data used in the development of the
emission factors. The general procedures that were followed to develop these emission factors can be
found at the same web address under the title Procedures for Preparing Emission Factor Documents4
2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS
The USAEC Phase IV-B series testing was conducted in a thermal treatment characterization
facility known as the BangBox™ Test Chamber located at Dugway Proving Ground, Utah. The BangBox
is a 50-foot diameter hemispheric dome with a total volume of 1,000 cubic meters. It is constructed of
polyvinyl-chloride-coated polyester fabric anchored to a concrete pad. The structure is kept rigid by a
constant injection of fresh air and a semi-rigid air lock. During sampling, fans inside the BangBox kept
the gases and particles mixed while samplers located inside the chamber or connected to the chamber by
short probes measured the contaminants. Real-time analyzers were electronically connected to a data
recorder. In addition to the samplers and fans, the BangBox contained a shrapnel shield, an automatically
regulated inflation blower, and environmental control equipment.
A number of different test methods were employed to collect and analyze the emissions data that
were used to develop emission factors for detonation of ordnance. Table 3 identifies each emission test
method used; bracketed information identifies the purpose of using the method. The emissions data were
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collected using EPA test methods published in Title 40 of the Code of Federal Regulations, Part 50
(40 CFR 50); 40 CFR 60; and in Compendium of Methods for the Determination of Toxic Organic
Compounds in Ambient Air5 Some of the sample analytical procedures used were from EPA Office of
Solid Waste (OSW) publication SW-846, Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods 6 Where necessary, the test methods were adapted to reflect application to the unique testing of
ordnance detonation in the BangBox.
TABLE 3 SAMPLING AND ANALYTICAL METHODS USED
Compound
Test Method
CO
40 CFR 60, Appendix A, EPA Method 10 - Determination of Carbon Monoxide
Emissions from Stationary Sources [sampling and analysis]
o
o
40 CFR 60, Appendix A, EPA Method 3A - Determination of Oxygen and Carbon
Dioxide Concentrations in Emissions from Stationary Sources (Instrumental Analyzer
Procedure) [sampling and analysis]
NOx
40 CFR 60, Appendix A, EPA Method 7E - Determination of Nitrogen Oxides
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
so2
40 CFR 60, Appendix A, EPA Method 6C - Determination of Sulfur Dioxide
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
TSP
40 CFR 50. Appendix B - Reference Method for the Determination of Suspended
Particulate Matter as in the Atmosphere (High Volume Method) [sampling and
analysis |
PM-10
40 CFR 50, Appendix J - Reference Method for the Determination of Particulate
Matter as PM-10 in the Atmosphere [sampling and analysis]
EPA Compendium Method 10-2.2 - Sampling of Ambient Air for PM10 Using an
Andersen Dichotomous Sampler [sampling and analysis]
PM-2.5
EPA Compendium Method 10-2.2 - Sampling of Ambient Air for PM10 Using an
Andersen Dichotomous Sampler [sampling and analysis]
Tapered Element Oscillating Microbalance (TEOM) [sampling and analysis]
Metals
Metal sample was obtained from TSP sample [sampling]
40 CFR 60, Appendix A, EPA Method 29 - Determination of Metals Emissions from
Stationary Sources [analysis]
SW-846 Method 601 OA - Inductively Coupled Plasma-Atomic Emission Spectrometry
[analysis for metals except mercury]
SW-846 Method 7470 - Mercury in Liquid Waste (Manual Cold-Vapor Technique)
[analysis mercury]
HC1, CL2, and
nh3
40 CFR 60, Appendix A, EPA Method 26 - Determination of Hydrogen Halide and
Halogen Emissions from Stationary Sources (Non-Isokinetic Method) [sampling]
SW-846 Method 9057 - Determination of Chloride from HCI/C12 Emission Sampling
Train (Methods 0050 and 0051) by Anion Chromatography [analysis]
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TABLE 3 (cont.)
Compound
Test Method
voc
Speciated VOC
svoc
Dioxins and
Furans
Formaldehyde
Hydrogen
Cyanide
Energetic
Materials
Tracer
Compound
(SF6)
EPA Compendium Method TO-12 - Method for the Determination of Non-Methane
Organic Compounds (NMOC) in Ambient Air Using Cryogenic Preconcentration and
Direct Flame Ionization Detection (FID) [sampling and analysis]
EPA Compendium Method TO-12 - Method for the Determination of Non-Methane
Organic Compounds (NMOC) in Ambient Air Using Cryogenic Preconcentration and
Direct Flame Ionization Detection (FID) [sampling and analysis]
EPA Compendium Method TO-13 - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS) [sampling]
SW-846 Method 8270 - Semivolatile Organic Compounds by Gas Chromatography/
Mass Spectrometry (GC/MS) [analysis]
EPA Compendium Method TO-9 - Determination of Poly chlorinated,
Polybrominated, and Brominated/Chlorinated Dibenzo-p-Dioxins and Dibenzofurans
in Ambient Air [sampling]
SW-846 Method 8290 - Polychlorinated Dibenzodioxins (PCDDs) and
Poly chlorinated Dibenzofurans (PCDFs) by High-Resolution Gas
Chromatography/High-Resolution Mass Spectrometry (HRGC/HRMS) [analysis]
EPA Compendium Method TO-11A - Determination of formaldehyde in Ambient Air
Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography
(HPLC) |sampling and analysis|
EPA Conditional Test Method 033 - Sampling and Analysis for Hydrogen Cyanide
Emissions from Stationary Sources [sampling and analysis]
EPA Compendium Method TO-13 - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS) [sampling]
SW-846 Method 8095 - Explosives by Gas Chromatography [analysis]
Grab sample [sampling]
Gas Chromatograph/Electron Capture Detector [analysis]
The following sections identify and briefly describe the test methods used to measure each
compound or group of compounds. Additional information regarding the operation of the BangBox and
the test methods used is presented in Reference 1. EPA-approved methods were used by the laboratories
that provided sampling and analysis data.
2.1 Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide
Real-time concentrations of CO, C02, NOx, and S02 that resulted from the use of ordnance in the
BangBox were measured using a continuous emissions measurement system (CEMS). CO sampling and
analysis was conducted in accordance with 40 CFR Part 60, Appendix A, Method 10 - Determination of
Carbon Monoxide Emissions from Stationary Sources. C02 sampling and analysis was conducted in
accordance with 40 CFR Part 60, Appendix A, Method 3A - Determination of Oxygen and Carbon
Dioxide Concentrations in Emissions from Stationary Sources. NOx sampling and analysis was
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conducted in accordance with 40 CFR Part 60, Appendix A, Method 7E - Determination of Nitrogen
Oxides Emissions from Stationary Sources. S02 sampling and analysis was conducted in accordance with
40 CFR Part 60, Appendix A, Method 6C- Determination of Sulfur Dioxide Emissions from Stationary
Sources. For each run, the target minimum sampling time was 30 minutes.
2.2 Total Suspended Particulate
The TSP concentration that resulted from the use of ordnance in the BangBox was determined
using a high-volume sampling and analysis procedure based on 40 CFR 50, Appendix B - Reference
Method for the Determination of Suspended Particulate Matter as in the Atmosphere (High-Volume
Method). During each run, duplicate samples were obtained using two high-volume samplers operating
simultaneously. Each sampler was equipped with a quartz-fiber filter that was weighed before and after
sampling. For each run, the target minimum sampling time was 20 minutes. The sampling rate was
recorded continuously using a computerized data acquisition system (DAS). The TSP concentration was
computed by dividing the mass of TSP collected by the volume of air sampled, corrected to standard
conditions.
2.3 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 Microns
The PM-10 concentration that resulted from the use of ordnance in the BangBox was determined
using two different sampling and analysis procedures. A high-volume sampler was used to obtain a
sample for each run in accordance with 40 CFR 50, Appendix J - Reference Method for the Determination
of Particulate Matter as PM-10 in the Atmosphere. The sampler was equipped with a quartz-fiber filter
that was weighed before and after sampling. For each run. the target minimum sampling time was
20 minutes. The sampling rate was recorded continuously using a computerized DAS. The PM-10
concentration was computed by dividing the mass of PM-10 collected by the volume of air sampled,
corrected to standard conditions.
A dichotomous sampler was also used to sample and analyze for PM-10 in accordance with EPA
Compendium Method 10-2.2 - Sampling of Ambient Air for PM10 Using an Andersen Dichotomous
Sampler. The sample stream initially passed through an impactor that removed particles larger than
PM-10. The remaining particles were mechanically separated into fractions larger and smaller than
PM-2.5 and were collected on two separate filters. The PM-10 concentration was computed by dividing
the mass of particles collected on both filters by the total volume of air sampled, corrected to standard
conditions.
2.4 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 2.5 Microns
The PM-2.5 concentration that resulted from the use of ordnance in the BangBox was determined
using two different sampling and analysis procedures. A dichotomous sampler was used to sample and
analyze for PM-2.5 in accordance with EPA Compendium Method 10-2.2 - Sampling of Ambient Air for
PMio Using an Andersen Dichotomous Sampler. The sample stream initially passed through an impactor
that removed particles larger than PM-10. The remaining particles were mechanically separated into
fractions larger and smaller than PM-2.5 and were collected on two separate filters. The PM-2.5
concentration was computed by dividing the mass of particles collected on the PM-2.5 and smaller filter
by the volume of air sampled through that filter, corrected to standard conditions.
A real-time tapered element oscillating microbalance (TEOM) analyzer was also used to measure
continuous PM-2.5 concentrations. The sample stream passed through a mechanical separator at a
constant flow rate to remove particles larger than 2.5 microns. Particulate matter was collected on a
hydrophobic filter material which was continuously weighed during each sampling run. The PM-2.5
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concentration was computed by dividing the mass of particles collected by the volume of air sampled,
corrected to standard conditions.
2.5 Metals
Metal concentrations that resulted from the use of ordnance in the BangBox were determined
using particulate matter from the TSP samples collected as described in Section 2.2. After the TSP total
weight gain was determined in the laboratory, a portion of the TSP filter was digested with concentrated
hydrogen fluoride and nitric acid per 40 CFR 60, Appendix A, Method 29 - Determination of Metals
Emissions from Stationary Sources. The digestate was then analyzed for metals (except mercury) using
inductively coupled argon plasma (ICAP) emission spectroscopy in accordance with SW-846
Method 601 OA - Inductively Coupled Plasma-Atomic Emission Spectrometry. Mercury was determined
by cold vapor atomic absorption spectroscopy (CVAAS) in accordance with SW-846 Method 7470 -
Mercury in Liquid Waste (Manual Cold-Vapor Technique). The concentration of each target metal was
computed by dividing the mass of metal collected by the volume of air sampled, corrected to standard
conditions.
2.6 Hydrochloric Acid, Chlorine, and Ammonia
Hydrochloric acid (HC1), chlorine (Cl2), and ammonia (NH3) concentrations that resulted from
the use of ordnance in the BangBox were sampled in accordance with 40 CFR Part 60, Appendix A,
Method 26 - Determination of Hydrogen Chloride Emissions from Stationary Sources. During each run,
chamber gases were pulled through two sets of impingers in series containing dilute sulfuric acid and
sodium hydoxide solutions. Collected samples were analyzed using SW-846 Method 9057 -
Determination of Chloride from HCl/Cl2 Emission Sampling Train (Methods 0050 and 0051) by Anion
Chromatography. The concentrations of HC1, Cl2. and NH;, were computed by dividing the mass
collected by the volume of air sampled, corrected to standard conditions. HC1 was also measured by a
continuous analyzer, but these results were not used for development of emission factors. For each run,
the target minimum sampling time was 30 minutes.
2.7 Volatile Organic Compounds
VOC concentrations that resulted from the use of ordnance in the BangBox were determined
using two methods from the Second Supplement to Compendium of Methods for the Determination of
Toxic Organic Compounds in Ambient Air. (1) Method TO-12 - Method for the Determination of Non-
methane Organic Compounds in Ambient Air using Cryogenic Preconcentration and Direct Flame
Ionization Detection and (2) Method TO-14 - Determination of Volatile Organic Compounds in Ambient
Air Using SUMMA Passivated Canister Sampling and Gas Chromatographic Analysis. For both
procedures, air samples were collected in stainless steel 6-liter SUMMA® canisters. The minimum
sampling time for each VOC canister was 10 minutes.
2.8 Semivolatile Organic Compounds
SVOC concentrations that resulted from the use of ordnance in the BangBox were determined
based on procedures found in Method TO-13 - Determination of Polycyclic Aromatic Hydrocarbons
(PAHs) in Ambient Air Using Gas Chromatography/Mass Spectrometry (GC/MS). During each run,
duplicate samples were collected using two PS-1 samplers that contained special sampling inlets (i.e.,
aluminum sampling modules) designed to hold quartz fiber filters to collect particulate matter, followed
by XAD-2 adsorbent resin cartridges for collection of vapor phase SVOCs. A 20-minute sampling time
was targeted. Following sampling, the filters and resin cartridges underwent solvent extraction and the
mass of SVOC collected was quantitatively determined by GC/MS analysis following procedures in
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SW-846 Method 8270 - Semivolatile Organic Compounds by Gas Chromatography/Mass Spectrometry
(GC/MS). Unknown compounds, if any, were tentatively identified using computerized mass spectral
matching techniques of the highest non-target "peaks."
2.9 Dioxin and Furan Compounds
Dioxin and furan compound concentrations that resulted from the use of ordnance in the
BangBox were determined based on procedures found in Method TO-9 - Determination of
Polychlorinated, Polybrominated, and Brominated/Chlorinated Dibenzo-p-Dioxins and Dibenzofurans in
Ambient Air. During each run, duplicate samples were obtained using two modified PS-1 samplers. The
modified samplers used standard quartz filters, but the adsorbent cartridges contained XAD-2 resin
sandwiched between polyurethane foam (PUF) plugs. A minimum sampling time of 20 minutes was
targeted. After sampling, the filters and adsorbent cartridges underwent extraction with the appropriate
solvent(s). The mass of dioxin and furan compounds collected was quantitatively determined following
SW-846 Method 8290 - Polychlorinated Dibenzodioxins (PCDDs) and Polychlorinated Dibenzofurans
(PCDFs) by High-Resolution Gas Chromatography/High-Resolution Mass Spectrometry (HRGC/HRMS).
2.10 Formaldehyde
Formaldehyde concentrations that resulted from the use of ordnance in the BangBox were
determined using EPA Compendium Method TO-11A - Determination of Formaldehyde in Ambient Air
Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography (HPLC), but using
modified sampling and analytical procedures. Dinitrophenylhydrazine (DNPH) laden cartridge tubes
were used as a direct probe to trap the formaldehyde. A minimum sampling time of 20 minutes was
targeted. The tubes were analyzed by HPLC with an ultraviolet (UV) absorption detector.
2.11 Hydrogen Cyanide
Hydrogen cyanide (HCN) concentrations that resulted from the use of ordnance in the BangBox
were determined using EPA Conditional Test Method (CTM) 033 - Sampling and Analysis for Hydrogen
Cyanide Emissions from Stationary Sources. The sample gas was drawn through a heated quartz-fiber
filter and two impingers containing 0.1 normal sodium hydroxide (NaOH). A minimum sampling time of
30 minutes was targeted. The impinger solution and extracted filter were analyzed by ion
chromatography.
2.12 Energetic Materials
Energetic compound concentrations that resulted from the use of ordnance in the BangBox were
determined using EPA Compendium Method TO-13 - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass Spectrometry (GC/MS). During
each run, duplicate samples were obtained using two modified PS-1 samplers. The modified samplers
used standard quartz filters, but the adsorbent cartridges contained XAD-2 resin. A minimum sampling
time of 20 minutes was targeted. After sampling, the filters and adsorbent cartridge were extracted with
acetonitrile. The effluent was then analyzed following the procedures outlined in SW-846 Method 8095 -
Explosives by Gas Chromatography.
2.13 Tracer Compound
Sulfur hexafluoride (SF6) was used as a tracer compound during each run to estimate the amount
of sample dilution that occurred as a result of ambient air entering the BangBox during the run. Grab
samples were collected five times during each run using evacuated canisters. A minimum sampling time
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of 2 minutes was targeted for each canister. The canisters were analyzed for the tracer compound using a
GC with an electron capture detector.
3.0 TEST DATA ANALYSIS AND RATING
3.1 EPA Guidance Regarding Test Data Quality Ratings
Prior to inclusion of emission factors in AP-42, the reliability of the underlying emission test data
must be appraised in accordance with the rating system specified in Reference 4. Under this rating
system, test data are assigned a rating from A to D, where an "A" rating is assigned to the highest quality
data. The criteria used to assign a specific data quality rating are summarized below.
A Tests are performed by using an EPA reference test method, or when not applicable, a sound
methodology. Tests are reported in enough detail for adequate validation and raw data are
provided that can be used to duplicate the emission results presented in the report.
B Tests are performed by a generally sound methodology, but lacking enough detail for adequate
validation. Data are insufficient to completely duplicate the emission result presented in the
report.
C Tests are based on an unproven or new methodology, or are lacking a significant amount of
background information.
D Tests are based on a generally unacceptable method, but the method may provide an order-of-
magnitude value for the source.
Four specific criteria arc identified in Reference 5 for consideration to assist in the assignment of
a test data quality rating. These four criteria arc:
1. Source operation. If the manner in which the source was operated is well documented in the
report and the source was operating within typical parameters during the test, an "A" rating
should be assigned. If the report stated parameters that were typical, but lacked detailed
information, a "B" rating should be assigned. If there is reason to believe the operation was not
typical, a "C" or "D" rating should be assigned.
2. Test methods and sampling procedures. In developing the ratings, the estimated accuracy and
precision of the test method as well as the adequacy of the documentation should be considered.
In general, if a current EPA reference test method, appropriate for the source, was followed, the
rating should be higher ("A" or "B"). If other methods were used, an assessment should be made
of their validity. If it is judged that the method was likely to be inaccurate or biased, a lower
rating ("C" or "D") should be given. A complete report should indicate whether any procedures
deviated from standard methods and explain any deviations. If deviations were reported, an
evaluation should be made of whether these were likely to influence the test results.
3. Process information. During testing, many variations in the process can occur without warning
and sometimes without being noticed. Such variations can induce wide deviations in sampling
results. If a large variation between test run results cannot be explained by information contained
in the site final test report or from test reports of other sources, the data are suspect and should be
given a lower rating or excluded. However, it should be recognized that a process may have
highly variable emissions and a lower rating may not be appropriate solely on the basis of wide
deviations in sampling results.
4. Analysis and calculations. Ideally, final test reports should contain original raw data sheets and
other documentation such as gas parameters (dry cubic feet per minute, oxygen percentage),
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calculation sheets, or example calculations describing how the calculated emission results were
obtained. If there are data sheets, the nomenclature and equations used should be compared to
those specified by EPA to establish equivalency. The depth of review of the calculations should
be dictated by the reviewers' confidence in the ability and conscientiousness of the tester, based
on such factors as consistency of results and completeness of other areas of the final test report.
Reports may indicate that raw data sheets were available, but were not included. If the final test
report is of high quality based on the other criteria, the quality rating should not be lowered due to
a lack of data sheets.
An overall test data quality rating should be assigned based upon the ratings assigned for each of the four
criteria.
3.2 Analysis of Test Data
Data included in the final test report1 were rated in accordance with the rating system described
above. Results for each of the four criteria are presented in the following sections.
3.2.1 Source Operations
The manner by which the ordnance were deployed (i.e., used) is documented in the final test
report. Each of the ordnance that was tested was deployed in a manner similar to that which would occur
in the field. The tests appear to have replicated typical ordnance operating parameters; consequently, the
test data should be assigned an "A" rating based on this criterion.
3.2.2 Test Methods and Sampling Procedures
The test methods and sampling procedures were evaluated as being appropriate and consistent
with EPA test methods or sound methodology. Except as noted below, no problems of any significance
were identified; consequently, the test data should be assigned an "A" rating based on this criterion.
3.2.2.1 CEMS-Measured Data
Although summaries of the CEMS data were provided for the tests,1 raw CEMS data were not
provided for the tests or for the pre- and post-test quality control (QC) activities. Furthermore, none of
the calibration gas certifications were supplied. There was no evidence of bias in the data; however,
based on the issues noted above, the test data for the CEMS-measured compounds (i.e., CO, C02, NOx,
and S02) should be assigned a "B" rating based on this criterion.
3.2.2.2 Compounds Sampled or Analyzed Using More than One Test Method or Analytical Method
Twenty-nine compounds were either sampled or analyzed using two methods; these compounds
are identified in Table 4. For each of these compounds, emission factors were calculated based upon the
data measured using the more appropriate test or analytical method; data measured using the less
appropriate method were ignored. The more appropriate method was identified by reviewing the methods
and the target compound lists associated with each method. If a specific compound appeared on the target
compound list for one method but not the other, the method targeting the compound was selected. If a
specific compound appeared on the target compound lists for both methods, the method judged to provide
the most accurate data was selected.
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TABLE 4 SELECTED SAMPLING OR ANALYTICAL METHOD FOR COMPOUNDS MEASURED
USING TWO SAMPLING OR ANALYTICAL METHODS
Compound
Selected Method
Other Method Employed
PM-10
40 CFR 50, Appendix J (PM-10)
10-2.2 (PM-10)
PM-2.5
10-2.2 (PM-2.5)
TEOM (PM-2.5)
Acetophenone
TO-14 (VOC)
SW8720 (SVOC)
Benzene
TO-14 (VOC)
TO-12 (VOC)
1,3-Butadiene3
TO-14 (VOC)
TO-12 (VOC)
1,2-Dichlorobenzene
TO-14 (VOC)
SW8720 (SVOC)
1,3 -Dichlorobenzene
TO-14 (VOC)
SW8720 (SVOC)
1,4-Dichlorobenzene
TO-14 (VOC)
SW8720 (SVOC)
1,3 -Dinitrobenzene
SW8095 (Energetics)
SW8720 (SVOC)
2,4-Dinitrotoluene
SW8095 (Energetics)
SW8720 (SVOC)
2,6-Dinitrotolueneb
SW8095 (Energetics)
SW8720 (SVOC)
Ethyl benzene
TO-14 (VOC)
TO-12 (VOC)
Hexachlorobutadiene
TO-14 (VOC)
SW8720 (SVOC)
Hexachloroethane
TO-14 (VOC)
SW8720 (SVOC)
Hydrochloric acid
40 CFR 60 Method 26 (HC1)
CEMS (HC1)
2-Methylnaphthalene
TO-14 (VOC)
SW8720 (SVOC)
Methyl tert-butyl ether
TO-14 (VOC)
TO-12 (VOC)
Naphthalene
SW8720 (SVOC)
TO-14 (VOC)
Nitrobenzene
TO-14 (VOC)
SW8720 (SVOC)
Styrene
TO-14 (VOC)
TO-12 (VOC)
Toluene
TO-14 (VOC)
TO-12 (VOC)
1,2,4-Trichlorobenzene
TO-14 (VOC)
SW8720 (SVOC)
1,2,4-Trimethylbenzene
TO-14 (VOC)
TO-12 (VOC)
m-Xylene, p-Xylene
TO-14 (VOC)
TO-12 (VOC)
o-Xylene
TO-14 (VOC)
TO-12 (VOC)
p-Ethyltoluene
TO-14 (VOC)
TO-12 (VOC)
d-Limonene
TO-14 (VOC)
TO-12 (VOC)
1,3,5 -T rimethy lbenzene
TO-14 (VOC)
TO-12 (VOC)
1,3,5 -T rinitrobenzene
SW8095 (Energetics)
SW8720 (SVOC)
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TABLE 4 (continued)
a For DODIC L366, data collected from the TO-12 sampling method was used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between the
TO-14 test samples.
b For DODICs B535 and B536, data collected from the SVOC sampling method were used to develop
emission factors because these compounds had a relative percent difference greater than 100 percent
between energetics test samples.
For PM-10, which was sampled using 40 CFR 50, Appendix J (high volume) and the 10-2.2
(dichotomous) methods, the Appendix J sampling method was judged to be more accurate because of the
larger sample volume and was selected. For PM-2.5, which was sampled using the 10-2.2 (dichotomous)
method and a TEOM, the 10-22 sampling method was judged to be more accurate and was therefore
selected. For hydrochloric acid, which was analyzed using CEMS and 40 CFR 60 Method 26, the
Method 26 analysis was judged to be more accurate and was selected. For compounds analyzed using
both the TO-12 (VOC) and TO-14 (VOC) methods, the TO-14 method analysis was judged to be more
accurate and was selected. For compounds analyzed using both the SW8270 (SVOC) and TO-14 (VOC)
methods, the TO-14 method analysis was judged to be more accurate and was selected. [Note:
Naphthalene was analyzed using both SW8270 (SVOC) and TO-14 (VOC), but only appears on the target
compound list for SW8270; therefore, this method analysis was selected.] For compounds analyzed using
both the SW8270 (SVOC) and SW8095 (energetics) methods, the SW8095 method analysis was judged
to be more accurate and was selected.
Occasionally, the compound measurement from the less accurate method was chosen because the
compound had poor precision between test runs for the sampling method that would have been more
accurate under normal circumstances. These cases are noted in the footnotes to Table 4.
3.2.2.3 Tentatively Identified Compounds
During the analysis of the SVOC data, the highest nontarget "peaks" were tentatively identified
using computerized mass spectral matching techniques. Emission factors were developed for these
tentatively identified compounds (TICs) if all of the following criteria were met.
1. The TIC corresponded to a unique compound (e.g., ethylbenzene). Emission factors were not
developed if the TIC corresponded to a class of compounds (e.g., unknown alcohol).
2. The TIC was not identified using another analysis method that provided higher confidence data.
Emission factors were developed based upon the higher confidence analysis method if such data
were available.
3. The TIC was not present in the method blank. Emission factors were not developed if the TIC
was found in the corresponding method blank.
The number of SVOC that were tentatively identified as unique compounds, were not identified
using a higher confidence method, and were not present in the method blank varied from three to six
compounds per ordnance. Emission factors were developed for all of these TICs, but because of the
uncertainty in the true identity of the TICs, the test data were assigned a "C" rating.
3.2.3 Process Information
Ordnance are manufactured to tight tolerances and are expected to deploy in a very repeatable
fashion. Consequently, the test data should be assigned an "A" rating based upon this criterion.
However, large relative percent differences (i.e., greater than 100 percent) between test runs or sample
6/07
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trains were noted for several compounds. Specific instances in which these differences were noted are
identified in Table 5. The equation below illustrates calculation of relative percent difference:
, . ...... test 1 concentration - test 2 concentration
relative percent difference = x 100%
average of test 1 and test 2 concentrations
TABLE 5 COMPOUNDS FOR WHICH LARGE RELATIVE PERCENT DIFFERENCES
WERE NOTED BETWEEN TEST RUNS OR SAMPLE TRAINS
Compound
Applicable DODIC
Carbon monoxide
L602
Lead
B535
Oxides of nitrogen
B535
PM-10
B535
PM-2.5
B535
Sulfur dioxide
B535
TSP
B535
Aluminum
B535
Antimony
B535
Barium
B535
Cadmium
L602
Chlorine
L602
Chromium
B535
Cobalt
B535
Cumene
B535, B536, M241
Ethylbenzene
M241
Ethylene
L602
1,2,3,4,6,7,8 -Heptachlorodibenzofuran
L366
1,2,3,4,7,8,9-Heptachlorodibenzofuran
L366, M241
1,2,3,4,7,8 -Hexachlorodibenzo
-p-dioxin
L366
1,2,3,6,7,8-Hexachlorodibenzo
-p-dioxin
L366
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
L366, L602
1,2,3,4,7,8 -Hexachlorodibenzofuran
L366
1,2,3,6,7,8-Hexachlorodibenzofuran
L366
1,2,3,7,8,9-Hexachlorodibenzofuran
L366, M241
2,3,4,6,7,8-Hexachlorodibenzofuran
L366
Hexane
B535, L366, M241
Hydrogen cyanide
B536
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TABLE 5 (cont.)
Compound
Applicable DODIC
Manganese
B535
Nitroglycerin
B536, L366
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
L366
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
L366
1,2,3,7,8-Pentachlorodibenzofuran
L366
2,3,4,7,8-Pentachlorodibenzofuran
L366
Phenol
B536
Propylene
L602
Selenium
B535
2,3,7,8-Tetrachlorodibenzo-p-dioxin
L366
2,3,7,8 -T etrachlorodibenzofuran
L366
1,2,4-Trimethylbenzene
M241
2,2,4-Trimethylpentane
B535, L366
m-Xylene, p-Xylene
M241
o-Xylene
M241
4-Amino-2,6-dinitrotoluene
L366. 1.602
1-Butene
B535, L602
i-Butene
L602
cis-2-Butene
B535
trans-2-Butene
B535, L602
Cyclopentane
B536, L366
Cyclopentene
B535, B536
n-Decane
L366
Diethylphthalate
B536
2,3 -Dimethylbutane
B535, B536, L366, M241
2,3-Dimethylhexane
B535, L366, M241
2,4-Dimethylhexane
B535, L366
2,5-Dimethylhexane
B535, L366, M241
2,3 -Dimethylpentane
B535, L366, M241
2,4-Dimethylpentane
B535, L366
Di-n-octylphthalate
L602
3-Ethylhexane
B535, M241
m-Ethyltoluene
M241
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TABLE 5 (cont.)
Compound
Applicable DODIC
o-Ethyltoluene
B536, M241
p-Ethyltoluene
M241
n-Heptane
B535
1-Hexene
B536
cis-2-Hexene
L366
trans-2-Hexene
B536
Indane
L366, L602, M241
Isoprene
B535
Magnesium
B535
Methacrolein
M241
Methane-nitro
B536
3 -Methyl-1 -butene
B536
2-Methyl-2-butene
B536
Methylcyclohexane
B535, M241
Methylcyclopentane
B535. L366. M241
2-Methylheptane
M241
2-Methylhexane
B535. L366. M241
3 -Methylhexane
B535
2-Methylpentane
B535, L366, M241
3-Methylpentane
B535, L366, M241
2-Methyl-1 -pentene
B535, L602
2-Methyl-2-pentene
B535, B536, L366
2-Nitrotoluene
B536, L602
i-Pentane
B536
1-Pentene
B536
cis-2-Pentene
B536
trans-2-Pentene
B535, L602
n-Propylbenzene
M241
RDX
B535
1,2,3 -T rimethy lbenzene
M241
1,3,5 -T rimethy lbenzene
M241
2,2,4-Trimethyhexane
B535, M241
2,3,4-Trimethylpentane
B535, L366, M241
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TABLE 5 (cont.)
Compound
Applicable DODIC
2,4,4-Trimethyl-l-pentene
L366
Due to the large relative percent differences between test runs, the test data specifically identified
in Table 5 were assigned a "C" rating. The remainder of the data should be assigned an "A" rating based
on this criterion.
3.2.4 Analysis and Calculations
The test report,1 detailed test plan,2 and analytical data supporting the test report3 were reviewed
to determine whether they contained all of the original raw data, other documentation, and example
calculations. Although the test report did not contain raw field data, the data were made available upon
request. The test report also lacked certain calibration data. However, the missing information was
judged insufficient to result in a downgrade of the test data quality rating.
The raw data and sample calculations presented in the final test report, detailed test plan, and
analytical data supporting the test report were reviewed to determine if the emission factors presented in
the report could be duplicated. Where differences were found between the emission factors calculated
using the Excel spreadsheets and those presented in the test report, an examination was made to determine
the reason for the differences.
Several minor errors were noted in the calculation of the emission factors within the test report,
particularly with respect to the incorporation of "'0'" values into the emission factors (see Sections 4.4).
The emission factors presented in AP-42 are based upon the corrected spreadsheets. Based upon the raw
data, other documentation, and the Excel spreadsheet calculations, the test data should be assigned an "A"
rating.
Emission factors developed for compounds present in the method blank at levels of 20 percent to
50 percent of both test values were assumed to be biased high. Silver met this criterion for DODIC L366
and was assigned a "B" rating.
When compounds were found in the method blank at levels greater than 50 percent of both test
values, the data were assumed to be suspect and no emission factors were developed. Silver met this
criterion for DODICs B535, B536, and M241.
3.3 Test Data Quality Ratings
Upon completing the analysis described in the preceding section of this document, the test data
quality ratings assigned as a result of the four criteria were reviewed. This review led to a downgrading
of some of the test data from an "A" rating to either a "B" rating or a "C" rating. Table 6 identifies the
data quality ratings for all compounds that did not receive an "A" rating.
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TABLE 6 DOWNGRADED DATA QUALITY RATINGS
Compound
Data Quality
Rating
Applicable DODIC
Carbon dioxide
B
All DODICs
Carbon monoxide
B
B535, B536, L366, M241
Carbon monoxide
C
L602
Lead
C
B535
Oxides of nitrogen
B
B536, L366, L602, M241
Oxides of nitrogen
C
B535
PM-10
C
B535
PM-2.5
C
B535
Sulfur dioxide
B
B536, L366, L602, M241
Sulfur dioxide
C
B535
TSP
C
B535
Aluminum
C
B535
Antimony
C
B535
Barium
C
B535
Cadmium
/ C
L602
Chlorine
/ (
L602
Chromium
C
B535
Cobalt
c
B535
Cumene
c
B535, B536, M241
Ethylbenzene
c
M241
Ethylene
c
L602
1,2,3,4,6,7,8 -Heptachlorodibenzofuran
c
L366
1,2,3,4,7,8,9-Heptachlorodibenzofuran
c
L366, M241
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
c
L366
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
c
L366
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
c
L366, L602
1,2,3,4,7,8 -Hexachlorodibenzofuran
c
L366
1,2,3,6,7,8-Hexachlorodibenzofuran
c
L366
1,2,3,7,8,9-Hexachlorodibenzofuran
c
L366, M241
2,3,4,6,7,8-Hexachlorodibenzofuran
c
L366
Hexane
c
B535, L366, M241
Hydrogen cyanide
c
B536
Manganese
c
B535
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TABLE 6 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Nitroglycerin
C
B536, L366
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
C
L366
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
c
L366
1,2,3,7,8-Pentachlorodibenzofuran
c
L366
2,3,4,7,8-Pentachlorodibenzofuran
c
L366
Phenol
c
B536
Propylene
c
L602
Selenium
c
B535
Silver
B
L366
2,3,7,8-Tetrachlorodibenzo-p-dioxin
C
L366
2,3,7,8 -T etrachlorodibenzofuran
C
L366
1,2,4-Trimethylbenzene
C
M241
2,2,4-Trimethylpentane
C
B535, L366
m-Xylene, p-Xylene
c
M241
o-Xylene
: C
M241
4-Amino-2,6-dinitrotoluene
r C
L366. L602
1-Butene
c
B535, L602
i-Butene
c
L602
cis-2-Butene
c
B535
trans-2-Butene
c
B535, L602
Cyclopentane
c
B536, L366
Cyclopentene
c
B535, B536
n-Decane
c
L366
Diethylphthalate
c
B536
2,3 -Dimethylbutane
c
B535, B536, L366, M241
2,3-Dimethylhexane
c
B535, L366, M241
2,4-Dimethylhexane
c
B535, L366
2,5-Dimethylhexane
c
B535, L366, M241
2,3 -Dimethylpentane
c
B535, L366, M241
2,4-Dimethylpentane
c
B535, L366
Di-n-octylphthalate
c
L602
Docosane
c
M241
Dotriacontane
c
M241
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TABLE 6 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
1 -Ethenyl-4-ethylbenzene
C
B536, L366
Ethylbenzaldehyde
C
B535, B536
4-Ethylbenzaldehyde
c
L366, L602
Ethylbenzoic acid
c
L602
3-Ethylhexane
c
B535, M241
m-Ethyltoluene
c
M241
o-Ethyltoluene
c
B536, M241
p-Ethyltoluene
c
M241
n-Heptane
c
B535
Hexadecanoic acid
c
L602, M241
1-Hexene
c
B536
cis-2-Hexene
c
L366
trans-2-Hexene
c
B536
Indane
c
L366. L602. M241
Isoprene
/ c
B535
Magnesium
' (
B535
Methacrolein
C
M241
Methane, nitro-
c
B536
4-Methylbenzenesulfonamide
c
L366
3 -Methyl-1 -butene
c
B536
2-Methyl-2-butene
c
B536
Methylcyclohexane
c
B535, M241
Methylcyclopentane
c
B535, L366, M241
10-Methyleicosane
c
M241
Methyl ester-benzoic acid
c
B536
2-Methylheptane
c
M241
2-Methylhexane
c
B535, L366, M241
3 -Methylhexane
c
B535
10-Methylnonadecane
c
M241
2-Methylpentane
c
B535, L366, M241
3-Methylpentane
c
B535, L366, M241
4-Methyl-2-pentanol
c
L602
2-Methyl-1 -pentene
c
B535, L602
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TABLE 6 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
2-Methyl-2-pentene
C
B535, B536, L366
1 -Methyl-1 -propenylbenzene
C
L366
1 -Methyl-2-(2-propenyl)-benzene
c
B535, B536
2-Nitrotoluene
c
B536, L602
Octadecanoic acid
c
M241
9-Octadecenamide, (Z)-
c
B536
i-Pentane
c
B536
1-Pentene
c
B536
cis-2-Pentene
c
B536
trans-2-Pentene
c
B535, L602
Phosphoric acid triphenyl ester
c
B535
n-Propylbenzene
c
M241
RDX
c
B535
1,2,3 -Trimethy lbenzene
c
M241
1,3,5 -Trimethy lbenzene
/ c
M241
2,2,4-Trimethyhexane
B535, M241
2,3,4-Trimethylpentane
c
B535, L366, M241
2,4,4-Trimethyl-1 -pentene
c
L366
4.0 EMISSION FACTOR CALCULATIONS
The methodologies and procedures that were used to develop emission factors from the test data
are described in this section. A similar approach was used to calculate emission factors for TSP, PM-10,
PM-2.5, metals, HC1, Cl2, NH3, SVOC, dioxin/furan compounds, formaldehyde, hydrogen cyanide, and
energetic materials. The calculation steps that were performed for each sampling train and each run are
summarized below.
1. For compounds for which more than one test sample was obtained, analytical detection limits
were incorporated into the test data.
2. The background compound concentration was calculated by dividing the mass of compound
detected during the background run by the background run sample volume.
3. The test compound concentration was calculated by dividing the mass of compound detected
during the test run by the test run sample volume.
4. A background-corrected concentration was calculated by subtracting the background
concentration from the test concentration.
5. A dilution-corrected concentration was calculated by dividing the background-corrected
concentration by the dilution correction factor.
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6. The mass of compound released during the test run was calculated by multiplying the dilution-
corrected concentration by the volume of the BangBox.
7. Emission factors for each sample and sampling train or test run were calculated by dividing the
mass of compound released by the number of ordnance detonated during the test run or by the
NEW detonated during the test run, as appropriate.
8. Average emission factors were calculated for each compound.
Because concentration data (i.e., milligrams per cubic meter [mg/m3], parts per million by volume
[ppmv], or parts per billion by volume [ppbv]) were recorded for VOC and CEMS-measured compounds,
it was not necessary to calculate background and test concentrations as described in steps 2 and 3.
Detection limits were applied directly to test compound concentrations of VOC and CEMS-measured
compounds, as described in step 1. Where present, ppmv and ppbv values were converted to mg/m3.
Emission factors for VOC and CEMS-measured compounds were then estimated in accordance with
steps 4 through 8 described above.
The following sections describe each of the eight emission factor calculation steps listed above in
more detail.
4.1 Incorporation of Analytical Detection-Limits to the Test Data
In many cases, more than one test sample was obtained for a specific compound (i.e., more than
one sample was obtained for a given test run or more than one test run was conducted). When multiple
samples were obtained for the same compound, a comparison w as made of all the sample data collected.
Based upon the results of the comparison, the following adjustments were made to the test data:
1. If all of the samples indicated that a compound was "not detected," the sample data were not
adjusted.
2. If all of the samples indicated that a compound was detected, the sample data were not adjusted.
3. If one or more of the samples indicated that a compound was detected and one or more of the
samples indicated that a compound was not detected, the "not detected" values were replaced
with a value equal to one half of the compound's analytical detection limit. The assumption
inherent to this adjustment was that the measured presence of a compound in one or more
samples was indicative of the compound's presence in all samples. The analytical detection
limits for each sample were obtained from the test data report.
4.2 Determination of Background Concentration
For TSP, PM-10, PM-2.5, metals, HC1, Cl2, NH3, SVOC, dioxin/furan compounds, formaldehyde,
hydrogen cyanide, and energetic materials, the background compound concentration (BC) was calculated
by dividing the mass of compound detected during the background run (Bkgd mass) by the background
run sample volume (Bkgd V). This calculation is illustrated by the following equation:
Bkgd mass
BC =
Bkgd V
For VOC compounds, the background run data were used directly. Background data for CEMS-
measured compounds were recorded for each test run between the time the CEMS began sampling and
the time of detonation. The background concentrations were assumed to equal representative values over
the sampling period.
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4.3 Determination of Test Compound Concentration
For TSP, PM-10, PM-2.5, metals, HC1, Cl2, NH3, SVOC, dioxin/furan compounds, formaldehyde,
hydrogen cyanide, and energetic materials, the test compound concentration (TC) was calculated by
dividing the mass of compound measured during the test run (Test mass) by the test run sample volume
(Test V). This calculation is illustrated by the following equation:
_ Test mass
TC =
TestV
For VOC compounds, the test run data were used directly. For CEMS-measured compounds, the
test compound concentration was determined as the arithmetic mean of the test data collected from the
initial steady-state point until the end of the test.
4.4 Determination of Background-Corrected Concentration
For all compounds, the calculation of the background-corrected concentration (BCC) was
dependent on whether the background (BC) and test (TC) concentrations were detected and whether they
were less than, equal to, or greater than one another. The procedures used to calculate the background-
corrected concentration for each sampling train and compound are described below and are displayed
graphically in Figure 1.
1. If the test concentration was not detected (ND), the background-corrected concentration equaled
ND.
2. If the test concentration was detected and the background concentration was not detected, the
background-corrected concentration equaled the test concentration.
3. If the test and background concentrations w ere detected and the test concentration was less than
or equal to the background concentration, the background-corrected concentration equaled 0.
4. If the test and background concentrations were detected and the test concentration was greater
than the background concentration, the background concentration was subtracted from the test
concentration. This calculation is illustrated by the following equation:
BCC =TC-BC
4.5 Determination of Dilution-Corrected Concentration
The dilution-corrected concentration (DCC) was calculated by dividing the background-corrected
concentration by the applicable dilution correction factor (DCF). This calculation is illustrated by the
following equation:
DCC = —
DCF
4.6 Determination of Mass of Compound Released
The mass of compound released was calculated by multiplying the dilution-corrected
concentration by the volume of the BangBox. This calculation is illustrated by the following equation:
Mass compound released = DCC x BangBox volume
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No
Was TC Detected?
Yes
No
Was BC Detected?
Yes
No
Was TC > BC?
Yes
BCC = ND
BCC = TC
BCC = 0
BCC = TC - BC
TC = Test Concentration
BC = Background Concentration
ND = Not Detected
BCC = Background-Corrected
Concentration
Figure 1 Calculation of background-corrected concentration (BCC).
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4.7 Determination of Emission Factors
Once the mass of compound released was calculated, two emission factors were developed for
each sample or sampling train and for each test run: the mass of compound released per item (i.e., per
single ordnance) and the mass of compound released per pound NEW. The NEW for all ordnance were
determined from References 1 and 3.
4.8 Determination of Average Emission Factors
Steps 1 through 7, as described in Sections 4.1 through 4.7, are applicable to individual samples
or sampling trains within individual test runs. The final step in the emission factor calculation process
was to calculate average emission factors for each compound in terms of mass released per item and mass
released per pound NEW. The average emission factors for each compound were calculated as the
arithmetic mean of the individual samples associated with the compound. If all samples indicated that the
compound was not detected (ND), then the average emission factor was assigned a value of ND. [Note:
The minimum detection levels associated with the compounds that were not detected are presented in
Appendix A.] Total dioxin/furan emission factors were calculated by summing the average emission
factors for all dioxin/furan compounds.
5.0 EMISSION FACTOR RATINGS
The emission factors were appraised in accordance with the rating system specified in
Reference 4. Under this rating system, emission factors are assigned a rating from A to E, where an "A"
rating is assigned to the highest quality factors. The criteria used to assign a specific emission factor
rating are summarized below.
A Excellent. The emission factor was developed primarily from A- and B-rated source test data
taken from many randomly chosen facilities in the industry population. The source category
population was sufficiently specific to minimize variability.
B Above average. The emission factor was developed primarily from A- or B-rated test data from a
moderate number of facilities. Although no specific bias was evident, it was not clear if the
facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
C Average. The emission factor was developed primarily from A-, B- and/or C-rated test data from
a reasonable number of facilities. Although no specific bias was evident, it was not clear if the
facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
D Below average. The emission factor was developed primarily from A-, B-, and C-rated test data
from a small number of facilities, and there may have been reason to suspect that these facilities
did not represent a random sample of the industry. There also may have been evidence of
variability within the source category population.
E Poor. The emission factor was developed from C- and D-rated test data from a very limited
number of facilities, and there may have been reason to suspect that the facilities tested did not
represent a random sample of the industry. There also may have been evidence of variability
within the source category population.
Two analyses were conducted to assign ratings to the ordnance emission factors. First, an
analysis was conducted on an ordnance-specific basis. Second, an analysis was conducted using all
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available ordnance emission factor data. The second analysis was conducted to determine whether a
sufficient correlation existed between emission factors for different but similar ordnance to allow the
number of test data points to be increased to the point that higher emission factor ratings could be
assigned than were possible when using the ordnance-specific approach. Both analyses are described
below.
5.1 Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data
As previously described, emission factor ratings are dependent upon the test data quality, the
number of test data points, the amount of variability present within a source category population, and the
randomness of the source category sample. The following test data facts pertain to these rating criteria:
1. As described in Section 3 of this Background Document, the ordnance test data was primarily
rated A or B. The test data for a few compounds was rated C.
2. Two tests were conducted or two sampling trains were used per ordnance.
3. Ordnance are manufactured to very tight tolerance levels so there is little variability within a
specific type of ordnance.
4. There was no evidence that suggested the tested items within each type of ordnance were
specially selected.
Emission factor ratings were assigned based upon these facts. The rationale used to accept or
reject specific emission factor ratings follow.
A: Rejected. The number of test data points w as deemed to be insufficient to assign an A emission
factor rating.
B: Rejected. The number of test data points was deemed to be insufficient to assign a B emission
factor rating.
C: Accepted for most ordnance. The emission factors were developed using A- and B-rated test
data, there is little variability among items, and there was no evidence that suggested the tested
items were specially selected. Because of the limited number of data points, a C rating was
deemed appropriate for this set of circumstances.
D: Accepted for some ordnance. The emission factors were developed using C-rated test data, there
is little variability among items, and there was no evidence that suggested the tested items were
specially selected. Because of the limited number of data points, a D rating was deemed
appropriate for this set of circumstances.
E: Rejected. The ordnance described in this report were developed primarily using A- and B-rated
test data rather than C- or D-rated data, there is little variability among items, and there was no
evidence that suggested the tested items were specially selected. Therefore, an E emission factor
rating was deemed inappropriate.
5.2 Emission Factor Ratings Assigned - Based on All Available Test Data
The proceeding sections of this Background Document concern the emission measurement
methods, data analysis, and calculations used to develop emission factors for specific ordnance.
However, USAEC's ordnance emission factor development program includes more than 200 ordnance
that have been tested under more than 25 separate test series. Because many of these ordnance are similar
in size and/or chemical composition, a statistical analysis was conducted to assess the similarity of the
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emission factors developed for similar ordnance. The results of this analysis were used to reevaluate the
emission factor ratings assigned on an ordnance-specific basis.
USAEC characterized individual ordnance as falling into one of 17 separate categories,
depending upon the size and/or chemical composition of the ordnance. The ordnance and their respective
categories are identified in Table 7 along with a comment field describing the number of data points.
TABLE 7 ORDNANCE CATEGORIZATION FOR EMISSION FACTOR
CORRELATION ASSESSMENT
Category
DODIC
Ordnance Description
Test
Series
Comment
CS
G963a
K765a
M73A CS Riot Control Agent Hand
Grenade
CS Riot Control Agent Capsule
DPG VI
DPG VI
Data not yet
available
G900
TH3 AN-M14 Incendiary Grenade
E05
G911
MK3A2 Offensive Hand Grenade
E02
G911
MK3A2 Offensive Hand Grenade
E06
K010
M4 Field Incendiary Burster
E05
K145
M18A1 Antipersonnel Mine
E02
M023
M112 Demolition Block Charge
EOl
M030
1/4-Pound Demolition Block Charge
EOl
M030 .
1/4-Pound Demolition Block Charge
E03
M031
1/2-Pound Demolition Block Charge
DPG IV A
M032
1-Pound Demolition Block Charge
E02
M032
1-Pound Demolition Block Charge
E03
Demolition
M130a
M130a
M6 Electric Blasting Cap
M6 Electric Blasting Cap
DPG VII
E07
20+ data points
M131a
M7 Blasting Cap
E07
M241
M10 High Explosive Universal Destructor
DPG IVB
M456
PETN Type 1 Detonating Cord
DPG IV A
M500a
M21 REEF Line Cutter
FP10
M591
Ml Military Dynamite Demolition Block
Charge
EOl
M913
M58A3 Linear Demolition Charge
E03
ML05a
MK24 High Explosive Cutter
EOll
ML09
Linear Demolition Charge, Shaped 20 gr/ft
DPG IV A
ML15
Linear Demolition Charge, Shaped
225 gr/ft
DPG IV A
ML47a
Mil Blasting Cap
E07
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TABLE 7 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
MM50a
M221 Shaped Charge
EOll
MN02a
M12 Blasting Cap
E07
MN03a
M13 Blasting Cap
E07
Demolition,
continued
MN06a
MN07a
M14 Blasting Cap
M15 Delay Blasting Cap
E07
EOll
20+ data points
MN08a
M81 Igniter
E09
MN68a
M151 Booster Demolition Charge
DPG VIII
None
PAX-11, Granular Powder Burn
E04
None
PAX-11, Molded Pellet Detonation
E04
G878a
M228 Practice Hand Grenade Fuse
DPG VI
K051
M604 Anti-Tank Practice Mine Fuze
E06
N278a
M564 MTSQ Fuze
EOll
Fuze
N285a
N286a
M577 Fuze
M5 82 Fuze
E09
E07
<10 data points
N335
M557 Point Detonating Fuze
E05
N340
M739A1 Point Detonating Fuze
E05
N464a
M732 Fuze
E09
G881
M67 Fragmentation Grenade
EOl
Grenade
G978
M82 Smoke Simulant Screening Grenade
Launcher
DPG V
<10 data points
G982
Terephthalic Acid Smoke Hand Grenade
DPG V
GG09a
M84 Non-Lethal Stun Hand Grenade
E012
B535
M583A1 40-mm White Star Parachute
DPG IVB
Cartridge
B536
M585 40-mm White Star Cluster Cartridge
DPG IVB
B627
M83A3, M83A2, & M83A1 60-mm
DPG V
Illuminating Cartridge with Fuze
Illumination
D505
M485A2 155-mm Illumination Round
(projectile)
DPG I
20+ data points
L305
Ml95 Green Star Parachute Signal Flare
DPG I
L306
M158 Red Star Cluster Signal Illumination
DPG II
L307
Ml59 White Star Cluster Signal
Illumination
DPG II
L311
M126A1 Red Star Parachute Signal Flare
DPG II
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TABLE 7 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
L312
M127A1 White Star Parachute Signal
Flare
DPGI
Illumination,
continued
L314
L367a
M125A1 Green Star Cluster Signal Flare
M22 Anti-Tank, Guided Missile, and
Rocket Launching Simulator
DPGI
DPG VI
20+ data points
L410a
M206 Aircraft Countermeasure Flare
DPG VI
Inert
HAlla
Rocket, 2.75-inch Flechette with M255A1
Warhead
DPG VIII
Data not yet
available
C511
M490 105-mm Target Practice Tracer
Cartridge (tracer)
E06
Only 1 data
point yet
available
Large
C784a
C785a
M831 120-mm Target Practice Tracer
Cartridge
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge
E012
E012
Medium
bait
BA15a
Ml001 40-mm HVCC Cartridge
M769 60-mm FRP Cartridge
E012
E012
Data not yet
available
A652
M220 20-mm TP-T Cartridge
FP9
A940
M910 25-mm Target Practice Discarding
Sabot Tracer Cartridge
FP8
Medium-FP
A976
B129a
M793 25-mm Target Practice Tracer
Cartridge
M789 30 mm CTG
FP8
E09
10+ data points
B519
M781 40-mm Practice Cartridge
FP2
B584
M918 40-mm Practice Cartridge
FP2
B505a
M662 40-mm Red Star Parachute
DPG VIII
Cartridge
Mine
K042a
M88 Volcano Practice Canister Mine
DPG VIII
Data not yet
available
Mortar
CA03
XM929 120 mm Smoke Cartridge with
M7334A1 Fuze
DPG V
Only 1 data point
B542
M430 40-mm High Explosive Dual
Purpose (HEDP) Cartridge (projectile)
E03
Projectile
B571
M383 40-mm High Explosive Cartridge
(projectile)
E03
10+ data points
B632
M49A4 60-mm High Explosive Cartridge
(projectile)
E03
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TABLE 7 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
B642
M720 60-mm High Explosive Cartridge
(projectile)
E06
BZ-13a
M888 60-mm Cartridge with M935 PD
Fuze
EOll
Projectile,
continued
C995
H557
M136 AT4 Recoilless Rifle, 84-mm
Cartridge (projectile)
M72A3 66-mm High Explosive Antitank
Rocket (warhead)
E03
EOl
10+ data points
H708a
M73 3 5-mm Subcaliber Practice Rocket
DPG VIII
None3
PAX-21, 60-mm Mortar
E08
PJ02
FIM-92A Stinger-Basic Guided Missile
(warhead)
E06
B642
M720 60-mm High Explosive Cartridge
(propelling charge)
FP4
B653a
M766 60-mm Short Range Practice Mortar
Cartridge
FP10
C226
M301A3 81-mm Illuminating Cartridge
(propelling charge)
FP4
C379
M934 120-mm High Explosive Cartridge
(Zone 1 - propelling charge)
FP8
C511
M490 105-mm Target Practice Tracer
Cartridge (propelling charge)
FP5
C784
M831 120-mm Target Practice Tracer
Cartridge (propelling charge)
FP5
Propellant
C785
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge (propelling charge)
FP5
20+ data points
C868
M821 81-mm High Explosive Cartridge
(propelling charge)
FP4
C876
M880 81-mm Target Practice Short Range
Cartridge (propelling charge)
FP4
CA09
M931 120-mm Full Range Practice
Cartridge (Zone 1 - propelling charge)
FP8
CA09
M931 120-mm Full Range Practice
Cartridge (Zone 4 - propelling charge)
FP8
D533
M119A2 155-mm Propelling Charge
(Zone 7)
FP5
D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP1
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TABLE 7 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP5
D540
M3 155-mm Propelling Charge (Zone 3,
M284 Cannon)
FP1
D540
M3 155-mm Propelling Charge (Zone 5,
Ml99 Cannon)
FP1
D540
M3A1 155-mm Propelling Charge
(Zone 3, Ml99 Cannon)
FP1
Propellant,
continued
D540
D541
M3A1 155-mm Propelling Charge
(Zone 3, M284 Cannon)
M4A2 155-mm Propelling Charge
(Zone 7)
FP1
FP5
20+ data points
M174a
MK209 Impulse Cartridge
FP10
M842a
Ml Squib
E07
M842a
M79 Igniter
E09
MD73a
M796 Impulse Cartridge
FP10
PJ02
FIM-92A Stinger-Basic Guided Missile
(flight motor)
FP7
PJ02
FIM-92A Stinger-Basic Guided Missile
(launch motor)
E05
H975a
M274 2.75-inch Signature Smoke with
H872 Warhead
DPG VIII
L366
M74A1 Projectile Air Burst Simulator
DPGIVB
L495
M49A1 Surface Trip Flare
DPG II
L508a
M72 Red Railroad Warning Fuse
DPG VI
L592
TOW Blast Simulator
DPG V
Pyrotechnic
L594
L595a
M115A2 Ground Burst Simulator
M9 Liquid Projectile Air Burst Simulator
DPG I
E012
20+ data points
L596
Ml 10 Flash Artillery Simulator
DPG I
L598
Ml 17 Flash Booby Trap Simulator
DPG I
L599
Ml 18 Illuminating Booby Trap Simulator
DPG II
L600
Ml 19 Whistling Booby Trap Simulator
DPG II
L601
M116A1 Hand Grenade Simulator
DPG I
L602
M21 Artillery Flash Simulator
DPG IVB
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TABLE 7 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
L709
M25 Target Hit Simulator
E02
L709
XM25 Target Hit Simulator
DPGV
L720
M26 Target Kill Simulator
E06
M327a
Coupling Base Firing Device
FP10
M448a
M2 Percussion Detonator
EOll
Pyrotechnic,
continued
M626a
M627a
Ml Push Igniter
M5 Pressure Release Igniter
E09
FP10
20+ data points
M630
Ml Pull Igniter
DPGV
M630a
Ml Pull Igniter
E09
M670a
M700 Blasting Fuse
EOll
M766a
M60 Igniter
E09
ML03a
Ml42 Firing Device
EOll
H459
Rocket, 2.75-inch Flechette, MK40 Mod 3
Motor (propelling rocket)
FP7
H557
M72A3 66-mm High Explosive Antitank
Rocket (propelling rocket)
FP4
Rocket/Missile
H557
M72A3 66-mm High Explosive Antitank
Rocket (propelling rocket)
FP7
10+ data points
H708
M73 35-mm Subcaliber Practice Rocket
Motor
FP9
H974
Rocket, 2.75-inch M267 Practice
Warhead, MK66 Mod 3 Motor (propelling
rocket)
FP7
A010
M220 10 Gage Blank/Subcaliber Salute
Cartridge
FP9
AO 11
12 Gage #00 Shot Cartridge
FP9
A017a
12 Gage #9 Shot Cartridge
FP10
Small Arm-FP
A059
A059
M855 5.56-mm Ball Cartridge (fired from
the M16A1 Rifle)
M855 5.56-mm Ball Cartridge (fired from
the M16A2 Rifle)
FP3
FP3
20+ data points
A059
M855 5.56-mm Ball Cartridge (No-Lead)
FP4
A063
M856 5.56-mm Tracer Cartridge
FP3
A065
M862 5.56-mm Practice Ball Cartridge
FP3
A066
M193 5.56-mm Ball Cartridge
FP6
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TABLE 7 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
A068
M196 5.56-mm Tracer Cartridge
FP6
A080
M200 5.56-mm Blank Cartridge
FP3
A086
.22 Caliber Long Rifle Ball Cartridge
FP4
A106
.22 Caliber Standard Velocity Long Rifle
Ball Cartridge
FP4
Alll
M82 7.62-mm Blank Cartridge
FP3
A131
M62 7.62-mm Tracer Cartridge
FP6
A136
Ml 18 7.62-mm Ball Match Cartridge
FP6
A143
M80 7.62-mm Ball Cartridge
FP3
A171
M852 7.62-mm Ball Match Cartridge
FP6
A182
Ml .30 Caliber Ball Cartridge
FP6
A212
M2 .30 Caliber Ball Cartridge
FP6
Small Arm-FP,
continued
A218
A247
M25 .30 Caliber Tracer Cartridge
M72 .30 Caliber Ball Match Cartridge
FP9
FP6
20+ data points
A363
M882 9-nim Ball Cartridge
FP3
A365
M 181 14.5-mm Trainer-Spotter Cartridge
with 3-sec Delay (Artillery)
DPGV
A366a
M182 14.5-mm Cartridge
EOll
A400
M41 .38 Caliber Special Ball Cartridge
FP9
A403
.38 Caliber Special Blank Cartridge
FP9
A475
M1911 .45 Caliber Ball Cartridge
FP3
A518
M903 .50 Caliber SLAP Cartridge
FP9
A518a
M962 .50 Caliber SLAP/T
FP10
A525
M2 .50 Caliber Armor Piercing Cartridge
FP8
A557
M17 .50 Caliber Tracer Cartridge
FP3
A557
M33 .50 Caliber Ball Cartridge
FP3
A598
M1A1 .50 Caliber Blank Cartridge
FP3
C870a
M819 (IUK) 81-mm Red Phosphorus
Smoke
DPG VII
Smoke
G815a
G930
Red Phosphorus Smoke Screening
Grenade Launcher (UK)
Hexachloroethane Smoke Grenade
DPG VII
DPGV
10+ data points
G940
M18 Green Smoke Hand Grenade
DPG III
G945
M18 Yellow Smoke Hand Grenade
DPG III
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TABLE 7 (cont.)
Category
DODIC
Ordnance Description
Test
Series
Comment
G950
M18 Red Smoke Hand Grenade
DPG III
G950
Ml8 Red Smoke Hand Grenade (new
formulation)
DPGV
Smoke,
continued
G955
G955
M18 Violet Smoke Hand Grenade
Ml8 Violet Smoke Hand Grenade (new
formulation)
DPG III
DPGV
10+ data points
K866a
ABC-M5 HC Ground Smoke Pot (MILES)
DPG VII
K867a
M4A2 Floating Smoke Pot
DPG VII
a Although testing may have been completed, emission factors for this ordnance have not yet been
analyzed for inclusion in AP-42; therefore, these data were not included when the data correlation was
assessed.
Within each of the 17 ordnance categories identified by USAEC, emission factors for each
compound were compared. To allow the comparison of emission factors for ordnance with similar
constituents but significant differences in net explosive weight, the comparison was made using the
normalized emission factor units of mass of compound released per pound NEW. Based upon
information provided by EPA,' the following procedures were used to assess the data correlation:
1. The relative standard deviation, defined as the standard deviation divided by the mean, was
calculated for each compound within each ordnance category.
2. If the relative standard deviation was less than 1.0, the evaluated emission factors were
considered to demonstrate good correlation. As such, the rating for these emission factors could
be elevated to a maximum of an A, depending on the number of data points within the evaluated
ordnance category.
3. If the relative standard deviation was between 1.0 and 2.0, the evaluated emission factors were
considered to demonstrate fair correlation. As such, the rating for these emission factors could be
elevated to a maximum of a B, depending on the number of data points within the evaluated
ordnance category.
4. If the relative standard deviation was greater than 2.0, the evaluated emission factors were
considered to demonstrate poor correlation. As such, the emission factor rating could not be
elevated, regardless of the amount of data available.
A poor correlation between emission factors was not necessarily construed as being indicative of poor test
data. Rather, a poor correlation was more likely to indicate that the ordnance included in the category
were not as similar in nature as anticipated by USAEC when the ordnance categories were defined.
In addition to assessing the data correlation, an assessment was made of the number of test data
points available within each of the 17 ordnance categories. Because each ordnance test consisted of two
test data points (i.e., two test runs per ordnance or two independent sampling trains were used during an
ordnance test), the number of test data points available in each of the ordnance categories varied from 2 to
68. Based upon information provided by EPA,7 the following assumptions were used to assess whether
sufficient category-specific test data points were available to justify elevating the emission factor ratings
based on ordnance-specific data only:
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1. If 20 or more data points were available, the emission factor rating could be elevated to a
maximum of an A, provided that the data also demonstrated a good correlation.
2. If at least 10 but less than 20 data points were available, the emission factor rating could be
elevated to a maximum of a B, provided that the data also demonstrated a good correlation.
3. If less than 10 data points were available, the emission factor rating could not be elevated,
regardless of the data correlation.
4. If the data demonstrated a fair correlation and 20 or more data points were available, the emission
factor rating could be elevated to a maximum of a B.
5. If the data demonstrated a fair correlation and at least 10 but less than 20 data points were
available, the emission factor rating could be elevated to a maximum of a C.
Using the criteria specified above, the emission factor ratings assigned to ordnance in each of the
17 ordnance categories were reevaluated. This evaluation indicated that some of the emission factor
ratings associated with ordnance included in nine categories could be elevated from a C or D rating to an
A or B rating. These nine categories are:
1.
Demolition
2.
Illumination
3.
Medium - Firing Point
4.
Projectiles
5.
Propellants
6.
Pyrotechnics
7.
Rocket/Missile
8.
Small Arms - Firing Point
9.
Smokes
A final assessment was made as to the emission factor rating assigned based on ordnance-specific
test data only. If the original emission factor data rating assigned was a C, then the emission factor rating
was elevated to an A or B, as appropriate, based upon the data for the whole ordnance category. If the
original emission factor data rating assigned was a D, then the emission factor rating was elevated to a B
or C, as appropriate, based upon the data for the whole ordnance category. The analysis is documented in
an Excel spreadsheet that is located on the EPA website at:
htto: //www .epa. gov/ttn/chief/ a p42/i ndex.html.
Within the current test series, DODICs B535 and B536 were included in the Illumination
category, DODICs L366 and L602 were included in the Pyrotechnic category, and DODIC M241 was
included in the Demolition category. All three of these categories include more than 20 data points. As a
result, some emission factor ratings associated with each of these ordnance were elevated. The emission
factor ratings assigned are presented in Appendix A.
6.0 REFERENCES
1. Sampling Results for AEC Phase IV-B Emission Characterization of Exploding Ordnance and
Smoke/Pyrotechnics, URS Group, Inc., Oak Ridge, TN, October 2004.
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33
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2. Detailed Test Plan for Phase IV-B Emission Characterization of Exploding Ordnance:
[DODIC# B535J Cartridge 40-mm White Star Parachute (M583A1), [DODIC# B536] Cartridge
40-mm White Star Cluster (M585), [DODIC# L366] Simulator Projectile Air Burst (M74A1),
[DODIC# L602] Simulator Flash Artillery (M21), [DODIC# M241] Destructor HE Universal
(Ml0), West Desert Test Center, U.S. Army Dugway Proving Ground, UT, April 2002.
3. Supporting information including Excel spreadsheets supplied upon request by the U.S. Army
Dugway Proving Ground test support contractor, URS Group, Inc., Oak Ridge, TN, January
2005.
4. Procedures for Preparing Emission Factor Documents, EPA-454/R-95-015, U.S. Environmental
Protection Agency, Research Triangle Park, NC, November 1997.
5. Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air,
Second Supplement, EPA/600/4-89/017, U.S. Environmental Protection Agency, Research
Triangle Park, NC, June 1988.
6. Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S.
Environmental Protection Agency, http://www.epa.gov/epaoswer/hazwaste/test/sw846.htm.
7. Information regarding the relationship between emission factor data correlation, the number of
data points available, and the resulting emission factor rating assigned supplied upon request by
Mr. Ron Myers, Measurement Policy Group, Office of Air Quality Planning and Standards, U.S.
Environmental Protection Agency, Research Triangle Park. NC, June 2006.
34
Ordnance Detonation
6/07
-------
APPENDIX A
COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR ORDNANCE
INCLUDED IN PHASE IV-B TESTING AT DUGWAY PROVING GROUND, UTAH
6/07
Ordnance Detonation
A-l
-------
This page left blank intentionally.
A-2 Ordnance Detonation 6/07
-------
TABLE A1 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC B535, M583A1 40-MM WHITE STAR PARACHUTE CARTRIDGE
Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxidef
1.5 E-02
7.2 E-02
--
630-08-0
Carbon monoxidef
5.0 E-03
2.4 E-02
--
7439-92-1
Lead11
1.6 E-04
7.9 E-04
--
~
Oxides of nitrogen8
1.4 E-03
6.5 E-03
--
~
PM-2.5h
2.5 E-02
1.2 E-01
--
~
PM-108
2.9 E-02
1.4 E-01
--
7446-09-5
Sulfur dioxide
4.0 E-05
1.9 E-04
--
~
Total nonmethane hydrocarbons8
1.2 E-03
6.0 E-03
--
12789-66-1
Total suspended particulate8
3.6 E-02
1.7 E-01
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.2 E-04
208-96-8
Acenaphthvlene
ND
ND
1.2 E-04
75-07-0
Acetaldehyde
ND
ND
1.8 E-04
75-05-8
Acetonitrile
2.2 E-07
1.1 E-06
--
98-86-2
Acetophenone
ND
ND
5.0 E-04
107-02-8
Acrolein8
ND
ND
2.3 E-04
107-13-1
Acrylonitrile8
ND
ND
2.2 E-04
107-05-1
Allyl chloride
ND
ND
3.2 E-04
7429-90-5
Aluminum8
1.4 E-05
6.8 E-05
--
92-67-1
4-Aminobiphenyl
ND
ND
2.5 E-03
7664-41-7
Ammonia
ND
ND
4.5 E-02
62-53-3
Aniline
ND
ND
1.8 E-03
120-12-7
Anthracene
ND
ND
1.2 E-04
7440-36-0
Antimony11
1.3 E-05
6.2 E-05
--
7440-38-2
Arsenic
ND
ND
1.4 E-05
7440-39-3
Barium11
1.5 E-05
7.3 E-05
--
71-43-2
Benzene8
1.7 E-05
8.5 E-05
--
92-87-5
Benzidine
ND
ND
1.3 E-02
56-55-3
Benzo [a] anthracene
ND
ND
1.4 E-04
205-99-2
Benzo [b] fluoranthene
ND
ND
2.7 E-04
207-08-9
Benzo [k] fluoranthene
ND
ND
1.5 E-04
191-24-2
Benzo |g,h,i]perylene
ND
ND
4.0 E-04
6/07
Ordnance Detonation
A-3
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
50-32-8
Benzo[a]pyrene
ND
ND
1.2E-04
100-44-7
Benzyl chloride
ND
ND
5.3 E-04
7440-41-7
Beryllium
ND
ND
4.6 E-06
74-83-9
Bromomethane
ND
ND
4.0 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.2 E-04
106-99-0
1,3-Butadiene8
3.3 E-06
1.6 E-05
--
71-36-3
n-Butanol
ND
ND
3.1 E-04
85-68-7
Butylbenzylphthalate
ND
ND
1.5 E-04
123-72-8
Butyraldehyde
ND
ND
3.0 E-04
7440-43-9
Cadmium8
3.3 E-08
1.6 E-07
--
86-74-8
Carbazole
ND
ND
1.6 E-04
56-23-5
Carbon tetrachloride8
3.7 E-07
1.8 E-06
--
7782-50-5
Chlorine
ND
ND
2.1 E-02
106-47-8
4-Chloroaniline
ND
ND
1.5 E-03
108-90-7
Chlorobenzene
ND
ND
4.7 E-04
75-00-3
Chloroethane
ND :
ND
2.7 E-04
111-91-1
bis(2-Chloroethoxy)mcthanc
. ND
ND
1.2 E-04
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.4 E-04
67-66-3
Chloroform
ND
ND
5.0 E-04
74-87-3
Chloromethane
ND
ND
2.1 E-04
108-60-1
bis(2-Chloro-1 -methylethyl)ether
ND
ND
1.9 E-04
91-58-7
2-Chloronaphthalene
ND
ND
1.2 E-04
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.2 E-04
7440-47-3
Chromium
3.6 E-07
1.7 E-06
--
218-01-9
Chrysene
ND
ND
1.6 E-04
7440-48-4
Cobalt
7.6 E-08
3.7 E-07
--
7440-50-8
Copper5
4.3 E-06
2.1 E-05
--
98-82-8
Cumeneh
0
0
--
110-82-7
Cyclohexane
3.0 E-06
1.4 E-05
--
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.5 E-04
132-64-9
Dibenzofuran
ND
ND
1.2 E-04
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-04
84-74-2
Dibutylphthalate
ND
ND
2.5 E-03
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-04
A-4
Ordnance Detonation
6/07
-------
TABLE A1 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-04
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
1.8E-03
75-71-8
Dichlorodifluoromethane
ND
ND
5.0 E-04
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-04
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-04
540-59-0
1,2-Dichloroethene
ND
ND
4.0 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.2 E-04
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-04
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
4.6 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-04
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.2 E-04
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.3 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.6 E-03
131-11-3
Dimethyl phthalate
ND
ND
1.2 E-04
99-65-0
1,3-Dinitrobenzcnc
ND
ND
5.6 E-05
534-52-1
4,6-Dinitro-o-crcsol
ND''":;
ND
2.2 E-03
51-28-5
2,4-Dinitrophenol
ND
ND
5.5 E-03
121-14-2
2,4-Dinitrotoluene
ND
ND
3.4 E-05
606-20-2
2,6-Dinitrotoluene
ND
ND
1.2 E-04
--
Total dioxin/furan compounds
8.1 E-12
3.9E-11
--
122-39-4
Diphenylamine
ND
ND
1.2 E-04
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.2 E-04
100-41-4
Ethylbenzene8
6.2 E-07
3.0 E-06
--
74-85-1
Ethylene8
4.4 E-05
2.1 E-04
--
117-81-7
bis(2-Ethylhexyl)phthalate
ND
ND
2.5 E-03
206-44-0
Fluoranthene
ND
ND
1.3 E-04
86-73-7
Fluorene
ND
ND
1.2 E-04
50-00-0
Formaldehyde
4.7 E-06
2.3 E-05
--
76-13-1
Freon 113
5.7 E-07
2.8 E-06
--
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
1.5 E-12
7.4 E-12
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
ND
ND
6.3 E-10
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
8.0E-10
118-74-1
Hexachlorobenzene
ND
ND
1.2 E-04
6/07
Ordnance Detonation
A-5
-------
TABLE A1 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-03
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.5 E-03
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
6.0E-10
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
6.0E-10
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
6.0E-10
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
0
0
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
3.7 E-10
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
4.6 E-10
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
3.7 E-10
67-72-1
Hexachloroethane
ND
ND
9.8 E-04
110-54-3
Hexaneh
2.7 E-06
1.3 E-05
--
7647-01-0
Hydrochloric acid
ND
ND
4.5 E-02
74-90-8
Hydrogen cyanide
9.4 E-07
4.5 E-06
--
193-39-5
Indeno [ 1,2.3-cd | pv rene
. ND
ND
1.3 E-04
78-59-1
Isophorone
•; ND
ND
1.2 E-04
67-63-0
Isopropyl alcohol
ND
ND
2.5 E-04
7439-92-1
Lead11
1.6 E-04
7.9 E-04
5.0 E-04
7439-96-5
Manganese
2.5 E-07
1.2 E-06
--
7439-97-6
Mercury
ND
ND
3.1 E-06
75-09-2
Methylene chloride
3.8 E-03
1.9 E-02
--
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-04
556-61-6
Methyl isothiocyanate
ND
ND
3.0 E-04
90-12-0
1 -Methylnaphthalene
ND
ND
5.9 E-04
91-57-6
2-Methylnaphthalene
4.3 E-07
2.1 E-06
--
95-48-7
2-Methylphenol
ND
ND
7.5 E-04
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene8
1.5 E-06
7.7 E-06
--
134-32-7
1 -Naphthylamine
ND
ND
2.5 E-03
91-59-8
2-Naphthylamine
ND
ND
2.5 E-03
7440-02-0
Nickelf
1.2 E-07
5.7 E-07
--
100-01-6
4-Nitroaniline
ND
ND
5.0 E-04
98-95-3
Nitrobenzene
ND
ND
1.1 E-05
55-63-0
Nitroglycerin
ND
ND
1.7 E-04
A-6
Ordnance Detonation
6/07
-------
TABLE A1 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
88-75-5
2-Nitrophenol
ND
ND
1.2 E-04
100-02-7
4-Nitrophenol
ND
ND
8.2 E-04
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.2 E-04
62-75-9
N-Nitrosodimethylamine
ND
ND
1.2 E-04
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.2 E-04
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.2 E-04
100-75-4
N-Nitrosopiperidine
ND
ND
1.2 E-04
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-
p-dioxin
6.6 E-12
3.2 E-ll
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
ND
ND
2.9E-10
608-93-5
Pentachlorobenzene
ND
ND
1.2 E-04
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
4.3 E-10
57117-41-6
1,2,3,7,8-Pcntachlorodibenzofuran
ND
ND
3.4E-10
57117-31-4
2,3,4,7,8-Pcntachlorodibcnzofuran
¦ ND
ND
3.2 E-10
82-68-8
Pentachloronitrobcnzcne
- - ND
ND
1.2 E-04
87-86-5
Pentachlorophcnol
= ND
ND
6.2 E-03
85-01-8
Phenanthrene
ND
ND
1.2 E-04
108-95-2
Phenol
2.3 E-07
1.1 E-06
--
7723-14-0
Phosphorus8
2.5 E-05
1.2 E-04
--
123-38-6
Propionaldehyde
ND
ND
2.4 E-04
115-07-1
Propylene
9.9 E-06
4.8 E-05
--
129-00-0
Pyrene
ND
ND
1.3 E-04
110-86-1
Pyridine
ND
ND
1.8 E-04
7782-49-2
Selenium11
4.4 E-08
2.1 E-07
--
100-42-5
Styrene8
5.5 E-07
2.7 E-06
--
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
3.4 E-10
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
ND
ND
2.9 E-10
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-04
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-04
7440-28-0
Thallium
ND
ND
2.3 E-05
108-88-3
Toluene8
0
0
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-04
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-04
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-04
6/07
Ordnance Detonation
A-7
-------
TABLE A1 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
79-01-6
Trichloroethylene
ND
ND
5.4 E-04
75-69-4
Trichlorofluoromethane
0
0
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
3.2 E-04
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.9 E-04
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-04
95-63-6
1,2,4-Trimethylbenzene
4.1 E-07
2.0 E-06
--
540-84-1
2,2,4-Trimethylpentaneh
2.8 E-06
1.4 E-05
--
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
4.0 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene8
2.2 E-06
1.1 E-05
--
95-47-6
o-Xylene
4.8 E-07
2.3 E-06
--
7440-66-6
Zinc
4.1 E-06
2.0 E-05
--
Other Pollutants
64-19-7
Acetic acid8
ND
ND
2.5 E-04
67-64-1
Acetone8
: 0
0
--
592-20-1
1-Acetoxyacetone
- ND
ND
4.8 E-04
74-86-2
Acetylene8
2.7 11-05
1.3 E-04
--
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
2.2 E-05
100-52-7
Benzaldehyde8
ND
ND
4.4 E-04
271-89-6
Benzofuran
ND
ND
4.9 E-04
65-85-0
Benzoic acid
ND
ND
1.1 E-02
100-47-0
Benzonitrile
ND
ND
4.3 E-04
100-51-6
Benzyl alcohol
ND
ND
8.7 E-03
107-04-0
1 -Bromo-2-chloroethane
ND
ND
5.9 E-04
74-97-5
Bromochloromethane
6.2 E-07
3.0 E-06
--
3017-95-6
2-Bromo-1 -chloropropane
ND
ND
6.5 E-04
75-28-5
i-Butane
0
0
--
106-97-8
n-Butane8
1.1 E-06
5.5 E-06
--
431-03-8
2,3-Butanedione
ND
ND
3.6 E-04
123-73-9
trans-2-Butenal
ND
ND
2.9 E-04
106-98-9
1-Butene
1.9 E-06
9.1 E-06
--
115-11-7
i-Butene
5.4 E-07
2.6 E-06
~
590-18-1
cis-2-Butene
7.7 E-07
3.7 E-06
~
624-64-6
trans-2-Butene
1.2 E-06
5.6 E-06
~
A-8
Ordnance Detonation
6/07
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
109-69-3
1-Chlorobutane
ND
ND
3.9 E-04
622-98-0
1 -Chloro-4-ethylbenzene
ND
ND
5.8 E-04
95-49-8
1 -Chloro-2-methylbenzene
ND
ND
5.3 E-04
108-41-8
1 -Chloro-3-methylbenzene
ND
ND
5.3 E-04
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.5 E-04
90-13-1
1 -Chloronaphthalene
ND
ND
1.2 E-04
95-57-8
2-Chlorophenol
ND
ND
1.2 E-04
2698-41-1
CS2
ND
ND
3.2 E-04
2074-87-5
Cyanogen
ND
ND
1.1 E-04
287-92-3
Cyclopentane
4.0 E-07
1.9 E-06
--
120-92-3
Cyclopentanone
ND
ND
3.5 E-04
142-29-0
Cyclopentene
1.7 E-07
8.2 E-07
--
930-30-3
2-Cyclopenten-1 -one
ND
ND
3.4 E-04
124-18-5
n-Decane
6.9 E-08
3.3 E-07
--
13466-78-9
delta 3-Carene
ND
ND
1.0 E-04
3018-12-0
Dichloroacetonitrile
ND :
ND
4.6 E-04
616-21-7
1,2-Dichlorobutane
ND
ND
5.3 E-04
32768-54-0
1,2-Dichloro-3 -methylbenzene
ND
ND
6.7 E-04
594-37-6
1,2-Dichloro-2-methylpropane
ND
ND
5.3 E-04
513-88-2
1,1 -Dichloro-2-propanone
ND
ND
5.3 E-04
10061-01-5
cis 1,3-Dichloro-l-propene
ND
ND
4.6 E-04
84-66-2
Diethylphthalate
ND
ND
1.8 E-04
75-83-2
2,2-Dimethylbutane
6.6 E-08
3.2 E-07
--
79-29-8
2,3 -Dimethylbutaneh
3.4 E-07
1.7 E-06
--
624-92-0
Dimethyldisulfide
ND
ND
3.9 E-04
625-86-5
2,5 -Dimethylfuran
ND
ND
4.0 E-04
1071-26-7
2,2-Dimethylheptane
ND
ND
1.0 E-04
584-94-1
2,3-Dimethylhexaneh
2.0 E-07
9.9 E-07
--
589-43-5
2,4-Dimethylhexaneh
4.8 E-07
2.3 E-06
--
592-13-2
2,5-Dimethylhexaneh
4.1 E-07
2.0 E-06
--
565-59-3
2,3 -Dimethylpentaneh
1.4 E-06
6.6 E-06
--
108-08-7
2,4-Dimethylpentaneh
8.2 E-07
4.0 E-06
--
463-82-1
2,2-Dimethylpropane
ND
ND
1.0 E-04
3658-80-8
Dimethyltrisulfide
ND
ND
5.2 E-04
117-84-0
Di-n-octylphthalate
ND
ND
1.4 E-04
6/07
Ordnance Detonation
A-9
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-84-0
Ethane8
6.7 E-06
3.2 E-05
--
64-17-5
Ethanol
ND
ND
1.9E-04
53951-50-1
Ethylbenzaldehyde1
3.8 E-06
1.8 E-05
--
1678-91-7
Ethylcyclohexane
ND
ND
1.0E-04
619-99-8
3-Ethylhexaneh
3.4 E-07
1.6 E-06
--
620-14-4
m-Ethyltoluene8
1.4 E-07
6.5 E-07
--
611-14-3
o-Ethyltoluene8
6.6 E-08
3.2 E-07
--
622-96-8
p-Ethyltoluene8
5.5 E-07
2.7 E-06
--
--
F22
ND
ND
9.8 E-04
98-01-1
2-Furaldehyde8
ND
ND
4.0 E-04
498-60-2
3-Furaldehyde
ND
ND
4.0 E-04
110-00-9
Furan
ND
ND
2.8 E-04
111-71-7
Heptanal8
ND
ND
4.7 E-04
142-82-5
n-Heptaneh
1.4 E-06
6.9 E-06
--
110-43-0
2-Heptanone
ND
ND
4.7 E-04
66-25-1
Hexanal
ND''":;
ND
4.2 E-04
591-78-6
2-Hexanone
ND
ND
4.2 E-04
592-41-6
1-Hexene8
1.6 E-06
7.8 E-06
--
7688-21-3
cis-2-Hexene
2.0 E-07
9.9 E-07
--
4050-45-7
trans-2-Hexene
2.7 E-07
1.3 E-06
--
496-11-7
Indane
1.6 E-07
7.9 E-07
--
78-79-5
Isopreneh
6.6 E-08
3.2 E-07
--
5989-27-5
d-Limonene
ND
ND
1.0 E-04
7439-95-4
Magnesium8
1.1 E-02
5.1 E-02
--
78-85-3
Methacrolein
ND
ND
2.9 E-04
75-52-5
Methane, nitro-8
9.1 E-07
4.4 E-06
--
104-85-8
4-Methylbenzonitrile
ND
ND
4.9 E-04
563-80-4
3 -Methyl-2-butanone
ND
ND
3.6 E-04
563-45-1
3 -Methyl-1 -butene
1.0 E-07
4.9 E-07
--
563-46-2
2-Methyl-1 -butene
1.4 E-07
6.5 E-07
--
513-35-9
2-Methyl-2-butene8
ND
ND
1.0 E-04
108-87-2
Methylcyclohexaneh
7.5 E-07
3.6 E-06
--
96-37-7
Methylcyclopentane11
1.6 E-06
7.6 E-06
~
78-93-3
Methyl ethyl ketone8
ND
ND
3.0 E-04
620-02-0
5 -Methyl-2-furaldehyde
ND
ND
4.6 E-04
A-10
Ordnance Detonation
6/07
-------
TABLE A1 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
534-22-5
2-Methylfuran
ND
ND
3.4 E-04
930-27-8
3-Methylfuran
ND
ND
3.4 E-04
592-27-8
2-Methylheptane8
4.7 E-07
2.3 E-06
--
591-76-4
2-Methylhexaneh
1.3 E-06
6.3 E-06
--
589-34-4
3 -Methylhexaneh
1.5 E-06
7.3 E-06
--
66-27-3
Methyl methane sulfonate
ND
ND
1.4 E-04
624-91-9
Methylnitrite
ND
ND
2.5 E-04
107-83-5
2-Methylpentaneh
1.7 E-06
8.3 E-06
--
96-14-0
3 -Methylpentaneh
1.3 E-06
6.3 E-06
--
763-29-1
2-Methyl-1 -penteneh
1.7 E-07
8.2 E-07
--
625-27-4
2-Methyl-2-penteneh
2.7 E-07
1.3 E-06
--
691-37-2
4-Methyl-1 -pentene
ND
ND
1.0 E-04
691-38-3
cis-4-Methyl-2-pentene
ND
ND
1.0 E-04
1587-04-8
l-Methyl-2-(2-propenvl)-benzene1
1.3 E-05
6.3 E-05
--
554-14-3
2-Methylthiophene
ND
ND
4.1 E-04
616-44-4
3-Methylthiophene
ND'":;
ND
4.1 E-04
479-45-8
Metln 1-2.4.6-
trinitrophenylnitramine
ND
ND
6.1 E-05
78-94-4
Methyl vinyl ketone
ND
ND
2.9 E-04
88-74-4
2-Nitroaniline
ND
ND
1.2 E-04
99-09-2
3-Nitroaniline
ND
ND
5.0 E-04
88-72-2
2-Nitrotoluene
ND
ND
2.9 E-05
99-99-0
4-Nitrotoluene
ND
ND
2.1 E-05
124-19-6
Nonanal
ND
ND
5.9 E-04
111-84-2
n-Nonane
2.7 E-05
1.3 E-04
--
821-55-6
2-Nonanone
ND
ND
5.9 E-04
--
ocs
ND
ND
2.5 E-04
124-13-0
Octanal
ND
ND
5.3 E-04
111-65-9
n-Octane8
2.7 E-07
1.3 E-06
--
1600-37-9
1,1,2,3,3 -Pentachloro-1 -propene
ND
ND
8.9 E-04
110-62-3
Pentanal
ND
ND
3.6 E-04
78-78-4
i-Pentane
1.4 E-07
6.6 E-07
--
109-66-0
n-Pentane
8.1 E-07
3.9 E-06
--
600-14-6
2,3-Pentanedione
ND
ND
4.2 E-04
107-87-9
2-Pentanone8
ND
ND
3.6 E-04
6/07
Ordnance Detonation
A-ll
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
96-22-0
3-Pentanone
ND
ND
3.6E-04
109-67-1
1-Pentene8
2.7 E-07
1.3 E-06
--
627-20-3
cis-2-Pentene8
1.3 E-07
6.4 E-07
--
646-04-8
trans-2-Penteneh
4.0 E-07
1.9 E-06
--
1629-58-9
l-Penten-3-one
ND
ND
3.5 E-04
625-33-2
3-Penten-2-one
ND
ND
3.5 E-04
78-11-5
PETN
ND
ND
7.4 E-06
536-74-3
Phenylacetylene
ND
ND
6.1 E-04
115-86-6
Phosphoric acid triphenyl ester11
5.5 E-06
2.7 E-05
--
80-56-8
alpha-Pinene
ND
ND
1.0 E-04
127-91-3
beta-Pinene
ND
ND
1.0 E-04
74-98-6
Propane8
1.7 E-06
8.1 E-06
--
103-65-1
n-Propylbenzene8
6.6 E-08
3.2 E-07
--
121-82-4
RDXh
5.1 E-07
2.5 E-06
--
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.2 E-04
58-90-2
2,3,4,6-Tetrachlorophenol
ND :
ND
1.6 E-04
109-99-9
Tetrahydrofuran
ND
ND
3.0 E-04
110-02-1
Thiophene
ND
ND
3.5 E-04
98-03-3
2-Thiophenecarboxaldehyde
ND
ND
4.7 E-04
546-06-2
Trichloroacetonitrile
ND
ND
6.0 E-04
526-73-8
1,2,3 -T rimethy lbenzene
3.3 E-07
1.6 E-06
--
108-67-8
1,3,5 -T rimethy lbenzene
2.8 E-07
1.3 E-06
--
16747-26-5
2,2,4-Trimethylhexaneh
1.4 E-07
6.6 E-07
--
565-75-3
2,3,4-Trimethylpentaneh
5.5 E-07
2.6 E-06
--
107-39-1
2,4,4-Trimethyl-1 -pentene
ND
ND
1.0 E-04
107-40-4
2,4,4-Trimethyl-2-pentene
ND
ND
1.0 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
4.4 E-05
118-96-7
2,4,6-Trinitrotoluene
ND
ND
2.2 E-05
A-12
Ordnance Detonation
6/07
-------
TABLE A1 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 2.07 E-01 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number of
test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number of
test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor rated D because the factor is for a tentatively identified compound.
6/07
Ordnance Detonation
A-13
-------
TABLE A2 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC B536, M585 40-MM WHITE STAR CLUSTER CARTRIDGE
Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxidef
2.6 E-02
1.4 E-01
--
630-08-0
Carbon monoxidef
9.5 E-03
5.0 E-02
--
7439-92-1
Lead
0
0
--
--
Oxides of nitrogenf
3.4 E-04
1.8 E-03
--
--
PM-2.5
3.5 E-03
1.8 E-02
--
~
PM-10f
2.6 E-03
1.3 E-02
--
7446-09-5
Sulfur dioxide8
0
0
--
~
Total nonmethane hydrocarbons8
1.9 E-03
9.7 E-03
--
12789-66-1
Total suspended particulatef
3.2 E-03
1.7 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.2 E-04
208-96-8
Acenaphthylene
ND
ND
1.2 E-04
75-07-0
Acetaldehyde
ND
ND
1.8 E-04
75-05-8
Acetonitrile
1.4 E-06
7.4 E-06
--
98-86-2
Acetophenone
" ND'
ND
5.0 E-04
107-02-8
Acrolein8
ND
ND
2.3 E-04
107-13-1
Acrylonitrile8
ND
ND
2.2 E-04
107-05-1
Allyl chloride
ND
ND
3.2 E-04
7429-90-5
Aluminumf
1.1 E-05
5.6 E-05
--
92-67-1
4-Aminobiphenyl
ND
ND
2.4 E-03
7664-41-7
Ammonia
ND
ND
4.6 E-02
62-53-3
Aniline
ND
ND
1.7 E-03
120-12-7
Anthracene
ND
ND
1.2 E-04
7440-36-0
Antimony
0
0
--
7440-38-2
Arsenic
ND
ND
1.3 E-05
7440-39-3
Barium
3.6 E-06
1.9 E-05
--
71-43-2
Benzenef
3.1 E-05
1.6 E-04
--
92-87-5
Benzidine
ND
ND
1.2 E-02
56-55-3
Benzo [a] anthracene
ND
ND
1.4 E-04
205-99-2
Benzo [b] fluoranthene
ND
ND
2.6 E-04
207-08-9
Benzo [k] fluoranthene
ND
ND
1.5 E-04
191-24-2
Benzo |g,h,i]perylene
ND
ND
3.8 E-04
A-14
Ordnance Detonation
6/07
-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
50-32-8
Benzo[a]pyrene
ND
ND
1.2E-04
100-44-7
Benzyl chloride
ND
ND
5.3 E-04
7440-41-7
Beryllium
ND
ND
4.5 E-06
74-83-9
Bromomethane
ND
ND
4.0 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.2 E-04
106-99-0
1,3-Butadiene8
4.5 E-06
2.3 E-05
--
71-36-3
n-Butanol
ND
ND
3.1 E-04
85-68-7
Butylbenzylphthalate
ND
ND
1.4 E-04
123-72-8
Butyraldehyde
ND
ND
3.0 E-04
7440-43-9
Cadmium8
1.9 E-08
9.8 E-08
--
86-74-8
Carbazole
ND
ND
1.5 E-04
56-23-5
Carbon tetrachloride8
1.2 E-07
6.3 E-07
--
7782-50-5
Chlorine
ND
ND
2.3 E-02
106-47-8
4-Chloroaniline
ND
ND
1.4 E-03
108-90-7
Chlorobenzene
ND
ND
4.7 E-04
75-00-3
Chloroethane
' .. ND
ND
2.7 E-04
111-91-1
bis(2-Chloroethoxy)mcthanc
;: ND
ND
1.2 E-04
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.3 E-04
67-66-3
Chloroform
ND
ND
5.0 E-04
74-87-3
Chloromethane
ND
ND
2.1 E-04
108-60-1
bis(2-Chloro-1 -methylethyl)ether
ND
ND
1.8 E-04
91-58-7
2-Chloronaphthalene
ND
ND
1.2 E-04
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.2 E-04
7440-47-3
Chromium8
0
0
--
218-01-9
Chrysene
ND
ND
1.5 E-04
7440-48-4
Cobalt8
5.5 E-08
2.9 E-07
--
7440-50-8
Copper1
1.4 E-06
7.6 E-06
--
98-82-8
Cumeneh
1.6 E-07
8.6 E-07
--
110-82-7
Cyclohexane
1.5 E-06
7.9 E-06
--
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.4 E-04
132-64-9
Dibenzofuran
ND
ND
1.2 E-04
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-04
84-74-2
Dibutylphthalate
ND
ND
2.4 E-03
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-04
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-04
6/07
Ordnance Detonation
A-15
-------
TABLE A2 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-04
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
1.8E-03
75-71-8
Dichlorodifluoromethane
ND
ND
5.0 E-04
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-04
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-04
540-59-0
1,2-Dichloroethene
ND
ND
4.0 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.2 E-04
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-04
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
4.6 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-04
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.2 E-04
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.2 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.5 E-03
131-11-3
Dimethyl phthalate
ND
ND
1.2 E-04
99-65-0
1,3-Dinitrobenzcnc
ND
ND
5.9 E-05
534-52-1
4,6-Dinitro-o-crcsol
ND''":;
ND
2.1 E-03
51-28-5
2,4-Dinitrophenol
ND
ND
5.2 E-03
121-14-2
2,4-Dinitrotoluene
ND
ND
3.6 E-05
606-20-2
2,6-Dinitrotoluene
ND
ND
1.2 E-04
--
Total dioxin/furan compounds
0
0
--
122-39-4
Diphenylamine
ND
ND
1.2 E-04
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.2 E-04
100-41-4
Ethylbenzene8
1.2 E-06
6.3 E-06
--
74-85-1
Ethylene8
4.6 E-05
2.4 E-04
--
117-81-7
bis(2-Ethylhexyl)phthalate
ND
ND
2.4 E-03
206-44-0
Fluoranthene
ND
ND
1.3 E-04
86-73-7
Fluorene
ND
ND
1.2 E-04
50-00-0
Formaldehyde
6.1 E-06
3.2 E-05
--
76-13-1
Freon 113
5.0 E-07
2.6 E-06
--
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
0
0
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
ND
ND
7.5 E-10
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
9.1 E-10
118-74-1
Hexachlorobenzene
ND
ND
1.2 E-04
A-16
Ordnance Detonation
6/07
-------
TABLE A2 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-03
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.4 E-03
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
7.1 E-10
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
7.2E-10
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
7.1 E-10
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
ND
ND
5.3 E-10
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
5.3 E-10
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
6.4 E-10
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
5.3 E-10
67-72-1
Hexachloroethane
ND
ND
9.8 E-04
110-54-3
Hexane
2.6 E-07
1.4E-06
--
7647-01-0
Hydrochloric acid
ND
ND
4.6 E-02
1634-04-4
Hydrogen cyanide'1
1.2 E-05
6.4 E-05
--
193-39-5
Indeno [ 1,2.3 -cd | pv rcne
¦ - ND
ND
1.3 E-04
78-59-1
Isophorone
ND
ND
1.2 E-04
67-63-0
Isopropyl alcohol
ND
ND
2.5 E-04
7439-92-1
Lead
0
0
4.8 E-04
7439-96-5
Manganese8
1.3 E-07
7.0 E-07
--
7439-97-6
Mercury
ND
ND
3.0 E-06
75-09-2
Methylene chloride
6.3 E-03
3.3 E-02
--
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-04
556-61-6
Methyl isothiocyanate
ND
ND
3.0 E-04
90-12-0
1 -Methylnaphthalene
ND
ND
5.9 E-04
91-57-6
2-Methylnaphthalene
ND
ND
5.9 E-04
95-48-7
2-Methylphenol
ND
ND
7.1 E-04
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene8
7.2 E-07
4.2 E-06
--
134-32-7
1 -Naphthylamine
ND
ND
2.4 E-03
91-59-8
2-Naphthylamine
ND
ND
2.4 E-03
7440-02-0
Nickelf
8.2 E-08
4.3 E-07
--
100-01-6
4-Nitroaniline
ND
ND
4.8 E-04
98-95-3
Nitrobenzene
ND
ND
1.2 E-05
55-63-0
Nitroglycerin11
8.6 E-08
4.5 E-07
--
6/07
Ordnance Detonation
A-17
-------
TABLE A2 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
88-75-5
2-Nitrophenol
ND
ND
1.2 E-04
100-02-7
4-Nitrophenol
ND
ND
7.8 E-04
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.2 E-04
62-75-9
N-Nitrosodimethylamine
ND
ND
1.2 E-04
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.1 E-04
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.2 E-04
100-75-4
N-Nitrosopiperidine
ND
ND
1.2 E-04
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-
p-dioxin
0
0
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
ND
ND
5.2E-10
608-93-5
Pentachlorobenzene
ND
ND
1.2 E-04
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
8.4E-10
57117-41-6
1,2,3,7,8-Pentachlorodibenzofuran
ND
ND
5.9E-10
57117-31-4
2,3,4,7,8-Pcntachlorodibenzofuran
ND
ND
5.6E-10
82-68-8
Pentachloronitrobenzene
: ¦ ND
ND
1.2 E-04
87-86-5
Pentachlorophcnol
•; ND
ND
5.9E-03
85-01-8
Phenanthrene
ND
ND
1.2 E-04
108-95-2
Phenol11
8.0 E-07
4.2 E-06
--
7723-14-0
Phosphorus8
4.3 E-06
2.3 E-05
--
123-38-6
Propionaldehyde
ND
ND
2.4 E-04
115-07-1
Propylene8
2.0 E-05
1.1 E-04
--
129-00-0
Pyrene
ND
ND
1.3 E-04
110-86-1
Pyridine
ND
ND
1.8 E-04
7782-49-2
Selenium
1.3 E-09
6.6 E-09
--
100-42-5
Styrene8
1.1 E-06
6.0 E-06
--
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
6.1 E-10
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
ND
ND
5.2E-10
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-04
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-04
7440-28-0
Thallium
ND
ND
2.3 E-05
108-88-3
Toluene8
0
0
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-04
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-04
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-04
A-18
Ordnance Detonation
6/07
-------
TABLE A2 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
79-01-6
Trichloroethylene
ND
ND
5.4 E-04
75-69-4
Trichlorofluoromethane
1.7E-07
8.7 E-07
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
3.1 E-04
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.8 E-04
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-04
95-63-6
1,2,4-Trimethylbenzene
6.7 E-07
3.5 E-06
--
540-84-1
2,2,4-Trimethylpentane
3.3 E-07
1.7 E-06
--
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
4.0 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene8
4.1 E-06
2.2 E-05
--
95-47-6
o-Xylene
9.4 E-07
4.9 E-06
--
7440-66-6
Zinc
1.2 E-05
6.2 E-05
--
Other Po
lutants
64-19-7
Acetic acid8
ND
ND
2.5 E-04
67-64-1
Acetone8
2.2 H-07
1.2 E-06
--
592-20-1
1-Acetoxyacetone
: ND
ND
4.8 E-04
74-86-2
Acetylene8
7.9 E-05
4.1 E-04
--
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
2.3 E-05
100-52-7
Benzaldehyde8
3.6 E-07
1.9 E-06
--
271-89-6
Benzofuran
ND
ND
4.9 E-04
65-85-0
Benzoic acid
ND
ND
1.1 E-02
100-47-0
Benzonitrile
ND
ND
4.3 E-04
100-51-6
Benzyl alcohol
ND
ND
8.3 E-03
107-04-0
1 -Bromo-2-chloroethane
ND
ND
5.9 E-04
74-97-5
Bromochloromethane
1.4 E-06
7.3 E-06
--
3017-95-6
2-Bromo-1 -chloropropane
ND
ND
6.5 E-04
123-73-9
trans-2-Butenal
ND
ND
2.9 E-04
75-28-5
i-Butane
7.9 E-07
4.1 E-06
--
106-97-8
n-Butane8
3.3 E-07
1.7 E-06
--
431-03-8
2,3-Butanedione
ND
ND
3.6 E-04
123-73-9
trans-2-Butenal
ND
ND
2.9 E-04
106-98-9
1-Butene8
2.6 E-06
1.3 E-05
--
115-11-7
i-Butene
4.7 E-06
2.4 E-05
--
590-18-1
cis-2-Butene8
1.2 E-06
6.2 E-06
--
6/07
Ordnance Detonation
A-19
-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
624-64-6
trans-2-Butene8
2.6 E-06
1.3 E-05
--
109-69-3
1-Chlorobutane
ND
ND
3.9 E-04
622-98-0
1 -Chloro-4-ethylbenzene
ND
ND
5.8 E-04
95-49-8
1 -Chloro-2-methylbenzene
ND
ND
5.3 E-04
108-41-8
1 -Chloro-3-methylbenzene
ND
ND
5.3 E-04
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.5 E-04
90-13-1
1 -Chloronaphthalene
ND
ND
1.2 E-04
95-57-8
2-Chlorophenol
ND
ND
1.2 E-04
2698-41-1
CS2
ND
ND
3.2 E-04
2074-87-5
Cyanogen
ND
ND
1.1 E-04
287-92-3
Cyclopentane
6.6 E-08
3.4 E-07
--
120-92-3
Cyclopentanone
ND
ND
3.5 E-04
142-29-0
Cyclopenteneh
1.6 E-07
8.6 E-07
--
930-30-3
2-Cyclopenten-1 -one
ND
ND
3.4 E-04
124-18-5
n-Decane
9.9 E-08
5.2 E-07
--
13466-78-9
delta 3-Carene
ND ¦¦
ND
1.0 E-04
3018-12-0
Dichloroacetonitrile
:. nd
ND
4.6 E-04
616-21-7
1,2-Dichlorobutane
ND
ND
5.3 E-04
32768-54-0
1,2-Dichloro-3 -methylbenzene
ND
ND
6.7 E-04
594-37-6
1,2-Dichloro-2-methylpropane
ND
ND
5.3 E-04
513-88-2
1,1 -Dichloro-2-propanone
ND
ND
5.3 E-04
10061-01-5
cis 1,3-Dichloro-l-propene
ND
ND
4.6 E-04
84-66-2
Diethylphthalateh
3.3 E-07
1.7 E-06
--
75-83-2
2,2-Dimethylbutane
3.9 E-07
2.1 E-06
--
79-29-8
2,3 -Dimethylbutaneh
1.3 E-07
6.9 E-07
--
624-92-0
Dimethyldisulfide
ND
ND
3.9 E-04
625-86-5
2,5 -Dimethylfuran
ND
ND
4.0 E-04
1071-26-7
2,2-Dimethylheptane
ND
ND
1.0 E-04
584-94-1
2,3-Dimethylhexane
9.9 E-08
5.2 E-07
--
589-43-5
2,4-Dimethylhexane
0
0
--
592-13-2
2,5-Dimethylhexane
0
0
--
565-59-3
2,3 -Dimethylpentane
6.6 E-08
3.4 E-07
--
108-08-7
2,4-Dimethylpentane
6.6 E-08
3.4 E-07
--
463-82-1
2,2-Dimethylpropane
ND
ND
1.0 E-04
3658-80-8
Dimethyltrisulfide
ND
ND
5.2 E-04
A-20
Ordnance Detonation
6/07
-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
117-84-0
Di-n-octylphthalate
ND
ND
1.3 E-04
74-84-0
Ethane8
3.9 E-06
2.1 E-05
--
64-17-5
Ethanol
ND
ND
1.9 E-04
3454-07-7
1 -Ethenyl-4-ethylbenzene1
4.5 E-06
2.3 E-05
--
53951-50-1
Ethylbenzaldehyde1
3.7 E-06
1.9 E-05
--
1678-91-7
Ethylcyclohexane
ND
ND
1.0 E-04
619-99-8
3-Ethylhexane
1.3 E-07
6.9 E-07
--
620-14-4
m-Ethyltoluene8
2.0 E-07
1.0 E-06
--
611-14-3
o-Ethyltoluene
1.3 E-07
6.9 E-07
--
622-96-8
p-Ethyltoluene8
6.0 E-07
3.2 E-06
--
--
F22
ND
ND
9.8 E-04
98-01-1
2-Furaldehyde8
ND
ND
4.0 E-04
498-60-2
3-Furaldehyde
ND
ND
4.0 E-04
110-00-9
Furan
ND
ND
2.8 E-04
111-71-7
Heptanal8
ND
ND
4.7 E-04
142-82-5
n-Heptane
4.0 11-07
2.1 E-06
--
110-43-0
2-Heptanone
^ ND
ND
4.7 E-04
66-25-1
Hexanal
ND
ND
4.2 E-04
591-78-6
2-Hexanone
ND
ND
4.2 E-04
592-41-6
1-Hexene
3.0 E-07
1.5 E-06
--
7688-21-3
cis-2-Hexene
9.9 E-08
5.2 E-07
--
4050-45-7
trans-2-Hexeneh
3.3 E-07
1.7 E-06
--
496-11-7
Indane
4.3 E-07
2.2 E-06
--
78-79-5
Isoprene
1.8 E-05
9.3 E-05
--
5989-27-5
d-Limonene
ND
ND
1.0 E-04
7439-95-4
Magnesiumf
1.0 E-03
5.3 E-03
--
78-85-3
Methacrolein
ND
ND
2.9 E-04
75-52-5
Methane, nitro-
1.8 E-06
9.6 E-06
--
104-85-8
4-Methylbenzonitrile
ND
ND
4.9 E-04
563-80-4
3 -Methyl-2-butanone
ND
ND
3.6 E-04
563-45-1
3 -Methyl-1 -buteneh
1.1 E-06
5.5 E-06
--
563-46-2
2-Methyl-1 -butene
1.9 E-06
1.0 E-05
--
513-35-9
2-Methyl-2-butene
3.0 E-07
1.5 E-06
~
108-87-2
Methylcyclohexane
6.6 E-08
3.4 E-07
~
96-37-7
Methylcyclopentane
2.0 E-07
1.0 E-06
~
6/07
Ordnance Detonation
A-21
-------
TABLE A2 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
78-93-3
Methyl ethyl ketone8
2.1 E-07
1.1 E-06
--
93-58-3
Methyl ester-benzoic acid1
4.3 E-06
2.2 E-05
--
620-02-0
5 -Methyl-2-furaldehyde
ND
ND
4.6 E-04
534-22-5
2-Methylfuran
ND
ND
3.4 E-04
930-27-8
3-Methylfuran
ND
ND
3.4 E-04
592-27-8
2-Methylheptane8
1.3 E-07
6.9 E-07
--
591-76-4
2-Methylhexane
0
0
--
589-34-4
3 -Methylhexane
2.0 E-07
1.0 E-06
--
66-27-3
Methyl methane sulfonate
ND
ND
1.3 E-04
624-91-9
Methylnitrite
ND
ND
2.5 E-04
107-83-5
2-Methylpentane
2.0 E-07
1.0 E-06
--
96-14-0
3 -Methylpentane
1.3 E-07
6.9 E-07
--
763-29-1
2-Methyl-1 -pentene
ND
ND
1.0 E-04
625-27-4
2-Methyl-2-penteneh
5.9 E-07
3.1 E-06
--
691-37-2
4-Methyl-1 -pentene
ND
ND
1.0 E-04
691-38-3
cis-4-Methyl-2-pentene
ND
ND
1.0 E-04
1587-04-8
l-Methyl-2-(2-propcnyl)-bcnzcnc'
1.1 E-05
5.6 E-05
--
554-14-3
2-Methylthiophene
ND
ND
4.1 E-04
616-44-4
3 -Methylthiophene
ND
ND
4.1 E-04
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.4 E-05
78-94-4
Methyl vinyl ketone
ND
ND
2.9 E-04
88-74-4
2-Nitroaniline
ND
ND
1.2 E-04
99-09-2
3-Nitroaniline
ND
ND
4.8 E-04
88-72-2
2-Nitrotolueneh
2.7 E-07
1.4 E-06
--
99-99-0
4-Nitrotoluene
ND
ND
2.2 E-05
124-19-6
Nonanal
ND
ND
5.9 E-04
111-84-2
n-Nonane
4.0 E-05
2.1 E-04
--
821-55-6
2-Nonanone
ND
ND
5.9 E-04
--
ocs
ND
ND
2.5 E-04
301-02-0
9-Octadecenamide, (Z)-1
7.7 E-06
4.0 E-05
--
124-13-0
Octanal
ND
ND
5.3 E-04
111-65-9
n-Octane8
1.3 E-07
6.9 E-07
--
1600-37-9
1,1,2,3,3 -Pentachloro-1 -propene
ND
ND
8.9 E-04
110-62-3
Pentanal
ND
ND
3.6 E-04
A-22
Ordnance Detonation
6/07
-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
78-78-4
i-Pentaneh
0
0
--
109-66-0
n-Pentane
6.6 E-08
3.4 E-07
--
600-14-6
2,3-Pentanedione
ND
ND
4.2 E-04
107-87-9
2-Pentanone8
ND
ND
3.6E-04
96-22-0
3-Pentanone
ND
ND
3.6 E-04
109-67-1
1-Pentene
1.6 E-07
8.6 E-07
--
627-20-3
cis-2-Pentene
1.6 E-07
8.6 E-07
--
646-04-8
trans-2-Pentene
ND
ND
1.0 E-04
1629-58-9
l-Penten-3-one
ND
ND
3.5 E-04
625-33-2
3-Penten-2-one
ND
ND
3.5 E-04
78-11-5
PETN
ND
ND
7.7 E-06
536-74-3
Phenylacetylene
ND
ND
6.1 E-04
80-56-8
alpha-Pinene
ND
ND
1.0 E-04
127-91-3
beta-Pinene
ND
ND
1.0 E-04
74-98-6
Propane8
3.4 E-06
1.8 E-05
--
103-65-1
n-PropylbenzcncB
1.3 E-07
6.9 E-07
--
121-82-4
RDX
0
0
--
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.2 E-04
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
1.5 E-04
109-99-9
Tetrahydrofuran
ND
ND
3.0 E-04
110-02-1
Thiophene
ND
ND
3.5 E-04
98-03-3
2-Thiophenecarboxaldehyde
ND
ND
4.7 E-04
546-06-2
Trichloroacetonitrile
ND
ND
6.0 E-04
526-73-8
1,2,3 -T rimethy lbenzene
1.1 E-06
5.5 E-06
--
108-67-8
1,3,5 -T rimethy lbenzene
0
0
--
16747-26-5
2,2,4-Trimethylhexane
6.6 E-08
3.4 E-07
--
565-75-3
2,3,4-Trimethylpentane
2.0 E-07
1.0 E-06
~
107-39-1
2,4,4-Trimethyl-1 -pentene
ND
ND
1.0 E-04
107-40-4
2,4,4-Trimethyl-2-pentene
ND
ND
1.0 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
4.6 E-05
118-96-7
2,4,6-Trinitrotoluene
ND
ND
2.3 E-05
6/07
Ordnance Detonation
A-23
-------
TABLE A2 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 1.91 E-01 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number of
test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number of
test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor rated D because the factor is for a tentatively identified compound.
A-24
Ordnance Detonation
6/07
-------
TABLE A3 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC L366, M74A1 AIR BURST PROJECTILE SIMULATOR
Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxide8
1.7 E-02
1.9 E-01
--
630-08-0
Carbon monoxide8
5.2 E-03
5.7 E-02
--
7439-92-1
Lead8
1.4 E-03
1.5 E-02
--
--
Oxides of nitrogen8
8.6 E-04
9.6 E-03
--
--
PM-2.5
4.0 E-03
4.4 E-02
--
--
PM-108
5.8 E-03
6.4 E-02
--
7446-09-5
Sulfur dioxide
4.3 E-05
4.8 E-04
--
~
Total nonmethane hydrocarbons
4.9 E-04
5.5 E-03
--
12789-66-1
Total suspended particulate8
1.0 E-02
1.1 E-01
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.2 E-04
208-96-8
Acenaphthvlene
ND
ND
1.2 E-04
75-07-0
Acetaldehyde
ND
ND
1.8 E-04
75-05-8
Acetonitrile8
5.4 H-07
5.9 E-06
--
98-86-2
Acetophenone8
ND
ND
5.0 E-04
107-02-8
Acrolein
ND
ND
2.3 E-04
107-13-1
Acrylonitrile8
7.6 E-07
8.4 E-06
--
107-05-1
Allyl chloride
ND
ND
3.2 E-04
7429-90-5
Aluminum8
2.6 E-04
2.9 E-03
--
92-67-1
4-Aminobiphenyl
ND
ND
2.3 E-03
7664-41-7
Ammonia
ND
ND
5.3 E-02
62-53-3
Aniline
ND
ND
1.7 E-03
120-12-7
Anthracene
ND
ND
1.2 E-04
7440-36-0
Antimony
8.9 E-05
9.9 E-04
--
7440-38-2
Arsenic
ND
ND
3.4 E-05
7440-39-3
Barium
1.9 E-05
2.1 E-04
--
71-43-2
Benzene
3.9E-06
4.4 E-05
~
92-87-5
Benzidine
ND
ND
1.2 E-02
56-55-3
Benzo [a] anthracene
ND
ND
1.3 E-04
205-99-2
Benzo [b] fluoranthene
ND
ND
2.5 E-04
207-08-9
Benzo [k] fluoranthene
ND
ND
1.4 E-04
191-24-2
Benzo |g,h,i]perylene
ND
ND
3.7 E-04
6/07
Ordnance Detonation
A-25
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
50-32-8
Benzo[a]pyrene
ND
ND
1.2E-04
100-44-7
Benzyl chloride
ND
ND
5.3 E-04
7440-41-7
Beryllium
ND
ND
5.4 E-06
74-83-9
Bromomethane
ND
ND
4.0 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.2 E-04
106-99-0
1,3-Butadiene
4.0 E-07
4.4 E-06
--
71-36-3
n-Butanol
ND
ND
3.1 E-04
85-68-7
Butylbenzylphthalate8
ND
ND
1.4 E-04
123-72-8
Butyraldehyde
ND
ND
3.0 E-04
7440-43-9
Cadmium
2.6 E-07
2.9 E-06
--
86-74-8
Carbazole
ND
ND
1.5 E-04
56-23-5
Carbon tetrachloride
3.3 E-10
3.6E-09
--
7782-50-5
Chlorine
ND
ND
2.5 E-02
106-47-8
4-Chloroaniline
ND
ND
1.4 E-03
108-90-7
Chlorobenzene
ND
ND
4.7 E-04
75-00-3
Chloroethane
ND :
ND
2.7 E-04
111-91-1
bis(2-Chlorocthoxy)mcthanc
ND
ND
1.2 E-04
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.3 E-04
67-66-3
Chloroform
ND
ND
5.0 E-04
74-87-3
Chloromethane
ND
ND
2.1 E-04
108-60-1
bis (2-Chloro-l-methylethyl) ether
ND
ND
1.7 E-04
91-58-7
2-Chloronaphthalene
ND
ND
1.2 E-04
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.2 E-04
7440-47-3
Chromium8
9.9 E-07
1.1 E-05
--
218-01-9
Chrysene
ND
ND
1.5 E-04
7440-48-4
Cobalt
4.1 E-08
4.5 E-07
--
7440-50-8
Copper
5.5 E-06
6.1 E-05
--
98-82-8
Cumene
ND
ND
1.0 E-04
110-82-7
Cyclohexane
7.1 E-07
7.9 E-06
--
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.4 E-04
132-64-9
Dibenzofuran
ND
ND
1.2 E-04
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-04
84-74-2
Dibutylphthalate
ND
ND
2.3 E-03
95-50-1
o-Dichlorobenzene
ND
ND
6.1 E-04
541-73-1
m-Dichlorobenzene
ND
ND
6.1 E-04
A-26
Ordnance Detonation
6/07
-------
TABLE A3 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
p-Dichlorobenzene
ND
ND
6.1 E-04
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
1.7E-03
75-71-8
Dichlorodifluoromethane
ND
ND
5.0 E-04
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-04
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-04
540-59-0
1,2-Dichloroethene
ND
ND
4.0 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.2 E-04
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-04
10061-02-6
trans-1,3-Dichloro-1 -propene
ND
ND
4.6 E-04
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.2 E-04
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.2 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.4 E-03
131-11-3
Dimethyl phthalate
ND
ND
1.2 E-04
99-65-0
1,3-Dinitrobcnzcnc
ND
ND
6.2 E-05
534-52-1
4,6-Dinitro-o-crcsol
ND :
ND
2.0 E-03
51-28-5
2,4-Dinitrophcnol
NR.
ND
5.1 E-03
121-14-2
2,4-Dinitrotoluene
ND
ND
3.7 E-05
606-20-2
2,6-Dinitrotoluene
8.9E-08
9.9 E-07
--
--
Total dioxin/furan compounds
1.6E-10
1.8E-09
--
122-39-4
Diphenylamine
ND
ND
1.2 E-04
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.2 E-04
100-41-4
Ethylbenzene
5.1 E-07
5.7 E-06
--
74-85-1
Ethylene8
7.7 E-06
8.6 E-05
--
117-81-7
bis(2-Ethylhexyl)phthalate
ND
ND
2.3 E-03
206-44-0
Fluoranthene
ND
ND
1.2 E-04
86-73-7
Fluorene
ND
ND
1.2 E-04
50-00-0
Formaldehyde
2.9 E-06
3.2 E-05
--
76-13-1
Freon 113
6.1 E-08
6.8 E-07
--
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin8
1.0 E-ll
1.2 E-10
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuranh
4.5 E-12
5.0 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuranh
2.8 E-12
3.1 E-ll
—
118-74-1
Hexachlorobenzene
ND
ND
1.2 E-04
6/07
Ordnance Detonation
A-27
-------
TABLE A3 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-03
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.3 E-03
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxinh
2.5 E-12
2.7 E-ll
--
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxinh
3.4 E-12
3.7 E-ll
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxinh
5.4 E-12
6.0 E-ll
--
70648-26-9
1,2,3,4,7,8-
Hexachlorodibenzofuranh
1.8 E-12
2.0 E-ll
--
57117-44-9
1,2,3,6,7,8-
Hexachlorodibenzofuranh
2.3 E-12
2.5 E-ll
--
72918-21-9
1,2,3,7,8,9-
Hexachlorodibenzofuranh
4.4 E-12
4.9 E-ll
--
60851-34-5
2,3,4,6,7,8-
Hexachlorodibenzofuran'1
1.9 E-12
2.1 E-ll
~
67-72-1
Hexachlorocthane
¦ ND
ND
9.8 E-04
110-54-3
I lexanc
4.0 E-07
4.5 E-06
~
7647-01-0
Hydrochloric acid
:: ND
ND
5.3 E-02
1634-04-4
Hydrogen cyanide
ND
ND
9.5 E-03
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
ND
1.2 E-04
78-59-1
Isophorone
ND
ND
1.2 E-04
67-63-0
Isopropyl alcohol
ND
ND
2.5 E-04
7439-92-1
Lead8
1.4 E-03
1.5 E-02
--
7439-96-5
Manganese8
1.9 E-06
2.1 E-05
~
7439-97-6
Mercury
ND
ND
3.6 E-06
75-09-2
Methylene chloride
1.9 E-03
2.2 E-02
--
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-04
556-61-6
Methyl isothiocyanate
ND
ND
3.0 E-04
90-12-0
1 -Methylnaphthalene
7.5 E-08
8.4 E-07
--
91-57-6
2-Methylnaphthalene
1.2E-08
1.3 E-07
~
95-48-7
2-Methylphenol
ND
ND
6.9 E-04
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene
3.0 E-07
3.5 E-06
--
134-32-7
1 -Naphthylamine
ND
ND
2.3 E-03
91-59-8
2-Naphthylamine
ND
ND
2.3 E-03
7440-02-0
Nickel8
1.8 E-07
2.0 E-06
--
A-28
Ordnance Detonation
6/07
-------
TABLE A3 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
100-01-6
4-Nitroaniline
ND
ND
4.6 E-04
98-95-3
Nitrobenzene
ND
ND
1.2 E-05
55-63-0
Nitroglycerin11
4.7 E-10
5.2 E-09
--
88-75-5
2-Nitrophenol
ND
ND
1.2 E-04
100-02-7
4-Nitrophenol
ND
ND
7.6 E-04
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.2 E-04
62-75-9
N-Nitrosodimethylamine
ND
ND
1.2 E-04
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.0 E-04
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.2 E-04
100-75-4
N-Nitrosopiperidine
ND
ND
1.2 E-04
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-
p-dioxin
3.1 E-ll
3.5 E-10
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuranh
1.1 E-ll
1.2 E-10
--
608-93-5
Pentachlorobcnzcne
ND
ND
1.2 E-04
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxinh
3.4 E-12
3.8 E-ll
--
57117-41-6
l,2,3,7,8-Pcntachlorodibenzofuranh
3.0 I•-12
3.4 E-ll
--
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuranh
2.4 E-12
2.6 E-ll
--
82-68-8
Pentachloronitrobenzene
ND
ND
1.2 E-04
87-86-5
Pentachlorophenol
ND
ND
5.8E-03
85-01-8
Phenanthrene
ND
ND
1.2 E-04
108-95-2
Phenol
1.7 E-07
1.8 E-06
--
7723-14-0
Phosphorus8
4.0 E-06
4.5 E-05
--
123-38-6
Propionaldehyde
ND
ND
2.4 E-04
115-07-1
Propylene8
2.3 E-06
2.6 E-05
--
129-00-0
Pyrene
ND
ND
1.2 E-04
110-86-1
Pyridine
ND
ND
1.7 E-04
7782-49-2
Selenium
1.2E-08
1.3 E-07
--
7440-22-4
Silver
8.9 E-08
9.9 E-07
~
100-42-5
Styrene
2.4 E-07
2.7 E-06
~
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-
dioxinh
1.1 E-ll
1.3 E-10
--
51207-31-9
2,3,7,8 -T etrachlorodibenzofuranh
6.1 E-ll
6.8 E-10
~
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-04
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-04
6/07
Ordnance Detonation
A-29
-------
TABLE A3 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
7440-28-0
Thallium
ND
ND
2.8 E-05
108-88-3
Toluene
0
0
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-04
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-04
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-04
79-01-6
Trichloroethylene
ND
ND
5.4 E-04
75-69-4
Trichlorofluoromethane
0
0
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
3.0 E-04
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-04
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-04
95-63-6
1,2,4-Trimethylbenzene
4.9 E-07
5.4 E-06
--
540-84-1
2,2,4-Trimethylpentaneh
2.4 E-07
2.7 E-06
--
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
4.0 E-04
106-42-3,
m-Xylene, p-Xvlene
" 2.2 E-06
2.4 E-05
--
108-38-3
95-47-6
o-Xylene
2.3 E-07
2,6 E-06
--
7440-66-6
Zincf
4.9 E-06
5.4 E-05
--
Other Pollutants
64-19-7
Acetic acid
ND
ND
2.5 E-04
67-64-1
Acetone8
0
0
--
592-20-1
1 -Acetoxyacetone
ND
ND
4.8 E-04
74-86-2
Acetylene8
5.2 E-06
5.7 E-05
--
19406-51-0
4-Amino-2,6-dinitrotolueneh
4.3 E-08
4.8 E-07
--
100-52-7
Benzaldehyde
2.8 E-08
3.1 E-07
--
271-89-6
Benzofuran
ND
ND
4.9 E-04
65-85-0
Benzoic acid
ND
ND
1.1 E-02
100-47-0
Benzonitrile
ND
ND
4.3 E-04
100-51-6
Benzyl alcohol
ND
ND
8.1 E-03
107-04-0
1 -Bromo-2-chloroethane
ND
ND
5.9 E-04
74-97-5
Bromochloromethane
5.9 E-07
6.6 E-06
~
3017-95-6
2-Bromo-1 -chloropropane
ND
ND
6.5 E-04
123-73-9
trans-2-Butenal
ND
ND
2.9 E-04
75-28-5
i-Butane
2.7 E-08
3.1 E-07
--
106-97-8
n-Butane
8.2 E-08
9.2 E-07
~
A-30
Ordnance Detonation
6/07
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
431-03-8
2,3-Butanedione
ND
ND
3.6 E-04
106-98-9
1-Butene
3.2E-07
3.5 E-06
--
115-11-7
i-Butene
2.1 E-07
2.3 E-06
--
590-18-1
cis-2-Butene
3.9E-08
4.4 E-07
--
624-64-6
trans-2-Butene8
3.7 E-07
4.1 E-06
--
109-69-3
1-Chlorobutane
ND
ND
3.9 E-04
622-98-0
1 -Chloro-4-ethylbenzene
ND
ND
5.8 E-04
95-49-8
1 -Chloro-2-methylbenzene
ND
ND
5.3 E-04
108-41-8
1 -Chloro-3-methylbenzene
ND
ND
5.3 E-04
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.4 E-04
90-13-1
1 -Chloronapthalene
ND
ND
1.2 E-04
95-57-8
2-Chlorophenol
ND
ND
1.2 E-04
2698-41-1
CS2
ND
ND
3.2 E-04
2074-87-5
Cyanogen
ND
ND
1.1 E-04
287-92-3
Cyclopentaneh
2.7 F.-08
3.1 E-07
--
120-92-3
Cyclopentanonc
;; ND
ND
3.5 E-04
142-29-0
Cyclopentene
3.9 E-08
4.4 E-07
--
930-30-3
2-Cyclopenten-1 -one
ND
ND
3.4 E-04
124-18-5
n-Decaneh
1.6 E-07
1.8 E-06
--
13466-78-9
delta 3-Carene
ND
ND
1.0 E-04
3018-12-0
Dichloroacetonitrile
ND
ND
4.6 E-04
616-21-7
1,2-Dichlorobutane
ND
ND
5.3 E-04
32768-54-0
1,2-Dichloro-3 -methylbenzene
ND
ND
6.7 E-04
594-37-6
1,2-Dichloro-2-methylpropane
ND
ND
5.3 E-04
513-88-2
1,1 -Dichloro-2-propanone
ND
ND
5.3 E-04
10061-01-5
cis 1,3-Dichloro-l-propene
ND
ND
4.6 E-04
84-66-2
Diethylphthalate8
ND
ND
1.7 E-04
75-83-2
2,2-Dimethylbutane
0
0
--
79-29-8
2,3 -Dimethylbutaneh
2.7 E-08
3.1 E-07
--
624-92-0
Dimethyldisulfide
ND
ND
3.9 E-04
625-86-5
2,5 -Dimethylfuran
ND
ND
4.0 E-04
1071-26-7
2,2-Dimethylheptane
ND
ND
1.0 E-04
584-94-1
2,3-Dimethylhexaneh
2.7 E-08
3.1 E-07
--
589-43-5
2,4-Dimethylhexaneh
8.0 E-08
8.9 E-07
--
592-13-2
2,5-Dimethylhexaneh
8.0 E-08
8.9 E-07
--
6/07
Ordnance Detonation
A-31
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
565-59-3
2,3 -Dimethylpentaneh
1.4 E-07
1.5 E-06
--
108-08-7
2,4-Dimethylpentaneh
8.0 E-08
8.9 E-07
--
463-82-1
2,2-Dimethylpropane
ND
ND
1.0 E-04
3658-80-8
Dimethyltrisulfide
ND
ND
5.2 E-04
117-84-0
Di-n-octylphthalate
ND
ND
1.3 E-04
74-84-0
Ethane8
6.8 E-07
7.6 E-06
--
64-17-5
Ethanol
ND
ND
1.9 E-04
3454-07-7
1 -Ethenyl-4-ethylbenzene1
2.0 E-06
2.3 E-05
--
4748-78-1
4-Ethylbenzaldehyde1
7.6 E-07
8.4 E-06
--
1678-91-7
Ethylcyclohexane
ND
ND
1.0 E-04
619-99-8
3-Ethylhexane
1.1 E-07
1.2 E-06
--
620-14-4
m-Ethyltoluene
1.6 E-07
1.8 E-06
--
611-14-3
o-Ethyltoluene
2.1 E-07
2.3 E-06
--
622-96-8
p-Ethyltoluene
4.1 E-07
4.5 E-06
--
--
F22
ND
ND
9.8 E-04
98-01-1
2-Furaldehyde
ND :
ND
4.0 E-04
498-60-2
3-Furaldehyde
ND
ND
4.0 E-04
110-00-9
Furan
ND
ND
2.8 E-04
111-71-7
Heptanal
ND
ND
4.7 E-04
142-82-5
n-Heptane
4.6 E-07
5.1 E-06
--
110-43-0
2-Heptanone
ND
ND
4.7 E-04
66-25-1
Hexanal
ND
ND
4.2 E-04
591-78-6
2-Hexanone
ND
ND
4.2 E-04
592-41-6
1-Hexene
ND
ND
1.0 E-04
7688-21-3
cis-2-Hexeneh
2.7 E-08
3.1 E-07
--
4050-45-7
trans-2-Hexene
5.3 E-08
5.9 E-07
--
496-11-7
Indaneh
0
0
--
78-79-5
Isoprene
ND
ND
1.0 E-04
5989-27-5
d-Limonene
ND
ND
1.0 E-04
7439-95-4
Magnesium8
7.8 E-05
8.6 E-04
--
78-85-3
Methacrolein
ND
ND
2.9 E-04
75-52-5
Methane, nitro-
4.1 E-07
4.5 E-06
--
70-55-3
4-Methylbenzenesulfonamide1
1.2 E-05
1.3 E-04
--
104-85-8
4-Methylbenzonitrile
ND
ND
4.9 E-04
563-80-4
3 -Methyl-2-butanone
ND
ND
3.6 E-04
A-32
Ordnance Detonation
6/07
-------
TABLE A3 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
563-45-1
3 -Methyl-1 -butene
ND
ND
1.0 E-04
563-46-2
2-Methyl-1 -butene
4.0 E-08
4.5 E-07
--
513-35-9
2-Methyl-2-butene
ND
ND
1.0 E-04
108-87-2
Methylcyclohexane
1.3 E-07
1.5 E-06
--
96-37-7
Methylcyclopentaneh
2.9 E-07
3.3 E-06
--
78-93-3
Methyl ethyl ketone
2.3 E-08
2.5 E-07
--
620-02-0
5 -Methyl-2-furaldehyde
ND
ND
4.6 E-04
534-22-5
2-Methylfuran
ND
ND
3.4 E-04
930-27-8
3-Methylfuran
ND
ND
3.4 E-04
592-27-8
2-Methylheptane
1.6 E-07
1.8 E-06
--
591-76-4
2-Methylhexaneh
1.4 E-07
1.5 E-06
--
589-34-4
3 -Methylhexane
1.6 E-07
1.8 E-06
--
66-27-3
Methyl methane sulfonate
ND
ND
1.3 E-04
624-91-9
Methylnitrite
ND
ND
2.5 E-04
107-83-5
2-Methylpentaneh
1.6 E-07
1.8 E-06
--
96-14-0
3-Methylpentaneh
2.2 E-07
2.4 E-06
--
763-29-1
2-Methyl-1 -pentene
: ND
ND
1.0 E-04
625-27-4
2-Methyl-2-penteneh
0
0
--
691-37-2
4-Methyl-1 -pentene
ND
ND
1.0 E-04
691-38-3
cis-4-Methyl-2-pentene
ND
ND
1.0 E-04
768-00-3
1 -Methyl-1 -propenylbenzene1
1.2 E-06
1.3 E-05
--
554-14-3
2-Methylthiophene
ND
ND
4.1 E-04
616-44-4
3 -Methylthiophene
ND
ND
4.1 E-04
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.7 E-05
78-94-4
Methyl vinyl ketone
ND
ND
2.9 E-04
88-74-4
2-Nitroaniline
ND
ND
1.2 E-04
99-09-2
3-Nitroaniline
ND
ND
4.6 E-04
88-72-2
2-Nitrotoluene
ND
ND
3.1 E-05
99-99-0
4-Nitrotoluene
ND
ND
2.3 E-05
124-19-6
Nonanal
ND
ND
5.9 E-04
111-84-2
n-Nonane
1.1 E-05
1.2 E-04
--
821-55-6
2-Nonanone
ND
ND
5.9 E-04
--
ocs
ND
ND
2.5 E-04
6/07
Ordnance Detonation
A-33
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
124-13-0
Octanal
ND
ND
5.3 E-04
1600-37-9
1,1,2,3,3 -Pentachloro-1 -propene
ND
ND
8.9 E-04
110-62-3
Pentanal
ND
ND
3.6 E-04
78-78-4
i-Pentane
5.5 E-08
6.1 E-07
--
109-66-0
n-Pentane
8.2 E-08
9.2 E-07
--
600-14-6
2,3-Pentanedione
ND
ND
4.2 E-04
107-87-9
2-Pentanone
ND
ND
3.6 E-04
96-22-0
3-Pentanone
ND
ND
3.6 E-04
109-67-1
1-Pentene
ND
ND
1.0 E-04
627-20-3
cis-2-Pentene
ND
ND
1.0 E-04
646-04-8
trans-2-Pentene
ND
ND
1.0 E-04
1629-58-9
l-Penten-3-one
ND
ND
3.5 E-04
625-33-2
3-Penten-2-one
ND
ND
3.5 E-04
536-74-3
Phenylacetylene
ND
ND
6.1 E-04
78-11-5
PETN
ND
ND
8.0 E-06
80-56-8
alpha-Pinene
ND'":;
ND
1.0 E-04
127-91-3
beta-Pinene
ND
ND
1.0 E-04
74-98-6
Propane
2.6 E-07
2.9 E-06
--
103-65-1
n-Propylbenzene
5.3 E-08
5.9 E-07
--
121-82-4
RDX
4.4 E-06
4.9 E-05
--
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.2 E-04
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
1.5 E-04
109-99-9
Tetrahydrofuran
ND
ND
3.0 E-04
110-02-1
Thiophene8
2.4 E-07
2.7 E-06
--
98-03-3
2-Thiophenecarboxaldehyde
ND
ND
4.7 E-04
546-06-2
Trichloroacetonitrile
ND
ND
6.0 E-04
526-73-8
1,2,3 -T rimethy lbenzene
1.4 E-07
1.5 E-06
--
108-67-8
1,3,5 -T rimethy lbenzene
2.9 E-07
3.3 E-06
--
16747-26-5
2,2,4-Trimethylhexane
5.3 E-08
5.9 E-07
--
565-75-3
2,3,4-Trimethylpentaneh
1.1 E-07
1.2 E-06
--
107-39-1
2,4,4-Trimethyl-1 -penteneh
9.0 E-08
1.0 E-06
--
107-40-4
2,4,4-Trimethyl-2-pentene
ND
ND
1.0 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
4.8 E-05
A-34
Ordnance Detonation
6/07
-------
TABLE A3 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 8.99 E-02 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number of
test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number of
test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor rated D because the factor is for a tentatively identified compound.
6/07
Ordnance Detonation
A-35
-------
TABLE A4 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC L602, M21 ARTILLERY FLASH SIMULATOR
Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxide8
0
0
--
630-08-0
Carbon monoxide
1.3 E-05
1.3 E-04
--
7439-92-1
Lead8
2.0 E-03
2.1 E-02
--
--
Oxides of nitrogen8
2.8 E-03
3.0 E-02
--
--
PM-2.5
1.7 E-02
1.8 E-01
--
--
PM-108
3.2 E-02
3.5 E-01
--
7446-09-5
Sulfur dioxide
2.6 E-02
2.7 E-01
--
~
Total nonmethane hydrocarbons
3.6E-04
3.9 E-03
~
12789-66-1
Total suspended particulate8
4.8 E-02
5.1 E-01
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.7 E-04
208-96-8
Acenaphthvlene
ND
ND
1.7 E-04
75-07-0
Acetaldehyde
ND
ND
1.8 E-04
75-05-8
Acetonitrile8
3,6 E-07
3.8 E-06
--
98-86-2
Acetophenone8
ND
ND
5.0 E-04
107-02-8
Acrolein
ND
ND
2.3 E-04
107-13-1
Acrylonitrile8
ND
ND
2.2 E-04
107-05-1
Allyl chloride
ND
ND
3.2 E-04
7429-90-5
Aluminum8
5.8 E-03
6.2 E-02
--
92-67-1
4-Aminobiphenyl
ND
ND
3.5 E-03
7664-41-7
Ammonia
ND
ND
4.9 E-02
62-53-3
Aniline
ND
ND
2.6 E-03
120-12-7
Anthracene
ND
ND
1.7 E-04
7440-36-0
Antimony
1.2 E-04
1.2 E-03
--
7440-38-2
Arsenic
ND
ND
5.0 E-05
7440-39-3
Barium
6.7 E-03
7.1 E-02
--
71-43-2
Benzene
1.3 E-06
1.4 E-05
--
92-87-5
Benzidine
ND
ND
1.8 E-02
56-55-3
Benzo [a] anthracene
ND
ND
2.0 E-04
205-99-2
Benzo [b] fluoranthene
ND
ND
3.8 E-04
207-08-9
Benzo [k] fluoranthene
ND
ND
2.2 E-04
191-24-2
Benzo |g,h,i]perylene
ND
ND
5.6 E-04
A-36
Ordnance Detonation
6/07
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
50-32-8
Benzo[a]pyrene
ND
ND
1.7 E-04
100-44-7
Benzyl chloride
ND
ND
5.3 E-04
7440-41-7
Beryllium
ND
ND
1.7 E-05
74-83-9
Bromomethane
ND
ND
4.0 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.7 E-04
106-99-0
1,3-Butadiene
1.2 E-07
1.2 E-06
--
71-36-3
n-Butanol
ND
ND
3.1 E-04
85-68-7
Butylbenzylphthalate8
1.0 E-07
1.1 E-06
--
123-72-8
Butyraldehyde
ND
ND
3.0 E-04
7440-43-9
Cadmium11
1.0 E-05
1.1 E-04
--
86-74-8
Carbazole
ND
ND
2.2 E-04
56-23-5
Carbon tetrachloride
0
0
--
7782-50-5
Chlorine11
9.4 E-04
1.0 E-02
--
106-47-8
4-Chloroaniline
ND
ND
2.1 E-03
108-90-7
Chlorobenzene
ND
ND
4.7 E-04
75-00-3
Chloroethane
ND'":;
ND
2.7 E-04
111-91-1
bis(2-Chloroethoxy)mcthanc
ND
ND
1.7 E-04
111-44-4
bis(2-Chloroethyl)ether
ND
ND
2.0 E-04
67-66-3
Chloroform
ND
ND
5.0 E-04
74-83-9
Chloromethane
ND
ND
4.0 E-04
108-60-1
bis(2-Chloro-1 -methylethyl)ether
ND
ND
2.7 E-04
91-58-7
2-Chloronaphthalene
ND
ND
1.7 E-04
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.7 E-04
7440-47-3
Chromium8
2.0 E-05
2.1 E-04
--
218-01-9
Chrysene
ND
ND
2.2 E-04
7440-48-4
Cobalt
1.0 E-06
1.1 E-05
--
7440-50-8
Copper
8.1 E-04
8.6 E-03
--
98-82-8
Cumene
ND
ND
1.9 E-04
110-82-7
Cyclohexane
1.0 E-06
1.1 E-05
--
53-70-3
Dibenz [a,h] anthracene
ND
ND
2.1 E-04
132-64-9
Dibenzofuran
ND
ND
1.7 E-04
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-04
84-74-2
Dibutylphthalate
ND
ND
3.5 E-03
95-50-1
o-Dichlorobenzene
ND
ND
6.1 E-04
541-73-1
m-Dichlorobenzene
ND
ND
6.1 E-04
6/07
Ordnance Detonation
A-37
-------
TABLE A4 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
p-Dichlorobenzene
ND
ND
6.1 E-04
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
2.6 E-03
75-71-8
Dichlorodifluoromethane
ND
ND
5.0 E-04
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-04
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-04
540-59-0
1,2-Dichloroethene
ND
ND
4.0 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.7 E-04
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-04
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
4.6 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-04
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.7 E-04
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.8 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
2.2 E-03
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-04
99-65-0
1,3-Dinitrobcnzcnc
ND
ND
8.4 E-05
534-52-1
4,6-Dinitro-o-crcsol
ND :
ND
3.0 E-03
51-28-5
2,4-Dinitrophcnol
NR.
ND
7.7 E-03
121-14-2
2,4-Dinitrotoluene
ND
ND
5.1 E-05
606-20-2
2,6-Dinitrotoluene
2.3 E-07
2.5 E-06
--
--
Total dioxin/furan compounds
4.4E-11
4.6E-10
--
122-39-4
Diphenylamine
ND
ND
1.7 E-04
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.7 E-04
100-41-4
Ethylbenzene
7.3 E-07
7.7 E-06
--
74-85-1
Ethylene
3.3 E-06
3.5 E-05
--
117-81-7
bis(2-Ethylhexyl)phthalate
ND
ND
3.5 E-03
206-44-0
Fluoranthene
ND
ND
1.9 E-04
86-73-7
Fluorene
ND
ND
1.7 E-04
50-00-0
Formaldehyde
3.0 E-06
3.2 E-05
--
76-13-1
Freon 113
8.8 E-08
9.4 E-07
--
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin8
1.0 E-ll
1.1 E-10
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
1.2 E-12
1.3 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
2.6 E-09
118-74-1
Hexachlorobenzene
ND
ND
1.8 E-04
A-38
Ordnance Detonation
6/07
-------
TABLE A4 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-03
77-47-4
Hexachlorocyclopentadiene
ND
ND
3.5 E-03
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
2.2 E-09
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
9.4 E-13
1.0 E-ll
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxinh
1.2 E-12
1.3 E-ll
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
ND
ND
9.7 E-09
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
1.0 E-09
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
1.3 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
1.1 E-09
67-72-1
Hexachloroethane
ND
ND
9.8 E-04
110-54-3
Hexane
6.6 E-07
7.0 E-06
--
7647-01-0
Hydrochloric acid
ND
ND
4.9 E-02
1634-04-4
Hydrogen cyanide
¦ ND
ND
8.9 E-03
193-39-5
Indeno [ 1,2.3-cd | pv rene
ND
ND
1.9 E-04
78-59-1
Isophorone
= ND
ND
1.7 E-04
67-63-0
Isopropyl alcohol
ND
ND
2.5 E-04
7439-92-1
Lead8
2.0 E-03
2.1 E-02
7.0 E-04
7439-96-5
Manganese8
4.1 E-06
4.4 E-05
--
7439-97-6
Mercury
ND
ND
1.1 E-05
75-09-2
Methylene chloride
1.4 E-03
1.5 E-02
--
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-04
556-61-6
Methyl isothiocyanate
ND
ND
3.0 E-04
90-12-0
1 -Methylnaphthalene
ND
ND
5.9 E-04
91-57-6
2-Methylnaphthalene
ND
ND
5.9 E-04
95-48-7
2-Methylphenol
ND
ND
1.0 E-03
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene
6.8 E-07
7.0 E-06
--
134-32-7
1 -Naphthylamine
ND
ND
3.5 E-03
91-59-8
2-Naphthylamine
ND
ND
3.5 E-03
7440-02-0
Nickel8
7.3 E-07
7.8 E-06
--
100-01-6
4-Nitroaniline
ND
ND
7.0 E-04
55-63-0
Nitroglycerin
ND
ND
2.6 E-04
6/07
Ordnance Detonation
A-39
-------
TABLE A4 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
88-75-5
2-Nitrophenol
ND
ND
1.7 E-04
100-02-7
4-Nitrophenol
ND
ND
1.2 E-03
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.7 E-04
62-75-9
N-Nitrosodimethylamine
ND
ND
1.7 E-04
86-30-6
N-Nitrosodiphenylamine
ND
ND
3.0 E-04
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.7 E-04
100-75-4
N-Nitrosopiperidine
ND
ND
1.7 E-04
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-
p-dioxin
2.8 E-ll
3.0 E-10
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
1.7 E-12
1.8 E-ll
2.0 E-09
608-93-5
Pentachlorobenzene
ND
ND
1.7 E-04
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
1.9 E-09
57117-41-6
1,2,3,7,8-Pcntachlorodibenzofuran
ND
ND
1.3 E-09
57117-31-4
2,3,4,7,8-Pcntachlorodibcnzofuran
¦ ND
ND
1.2 E-09
82-68-8
Pentachloronitrobcnzcne
ND
ND
1.7 E-04
87-86-5
Pentachlorophcnol
= ND
ND
8.7 E-03
85-01-8
Phenanthrene
ND
ND
1.7 E-04
108-95-2
Phenol
2.8 E-07
3.0 E-06
--
7723-14-0
Phosphorus8
2.0 E-05
2.1 E-04
--
123-38-6
Propionaldehyde
ND
ND
2.4 E-04
115-07-1
Propylene
9.0 E-07
9.6 E-06
--
129-00-0
Pyrene
ND
ND
1.9 E-04
110-86-1
Pyridine
ND
ND
2.6 E-04
7782-49-2
Selenium
5.1 E-08
5.4 E-07
--
7440-22-4
Silver
ND
ND
1.1 E-04
100-42-5
Styrene
4.4 E-07
4.7 E-06
--
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
1.6 E-09
51207-31-9
2,3,7,8-Tetrachlorodibenzofuran
ND
ND
1.4 E-09
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-04
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-04
7440-28-0
Thallium
ND
ND
8.3 E-05
108-88-3
Toluene
0
0
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-04
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-04
A-40
Ordnance Detonation
6/07
-------
TABLE A4 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-04
79-01-6
Trichloroethylene
ND
ND
5.4 E-04
75-69-4
Trichlorofluoromethane
0
0
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
4.5 E-04
88-06-2
2,4,6-Trichlorophenol
ND
ND
2.6 E-04
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-04
95-63-6
1,2,4-Trimethylbenzene
6.1 E-07
6.5 E-06
--
540-84-1
2,2,4-Trimethylpentane
7.7 E-07
8.2 E-06
--
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
4.0 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene
3.1 E-06
3.3 E-05
--
95-47-6
o-Xylene
1.0 E-06
1.1 E-05
--
7440-66-6
Zincf
6.0 E-05
6.4 E-04
--
Other Pollutants
64-19-7
Acetic acid
ND
ND
2.5 E-04
67-64-1
Acetone8
1.9 11-08
2.0 E-07
--
592-20-1
1 -Acetoxyacetone
ND
ND
4.8 E-04
74-86-2
Acetylene8
1.7 E-06
1.8 E-05
--
19406-51-0
4-Amino-2,6-dinitrotolueneh
6.1 E-08
6.5 E-07
--
100-52-7
Benzaldehyde
3.3 E-07
3.5 E-06
--
271-89-6
Benzofuran
ND
ND
4.9 E-04
65-85-0
Benzoic acid
5.5 E-05
5.8 E-04
--
100-47-0
Benzonitrile
ND
ND
4.3 E-04
100-51-6
Benzyl alcohol
ND
ND
1.2E-02
107-04-0
1 -Bromo-2-chloroethane
ND
ND
5.9 E-04
74-97-5
Bromochloromethane
3.6 E-07
3.8 E-06
--
3017-95-6
2-Bromo-1 -chloropropane
ND
ND
6.5 E-04
123-73-9
trans-2-Butenal
ND
ND
2.9 E-04
75-28-5
i-Butane
1.9 E-07
2.1 E-06
--
106-97-8
n-Butane
4.1 E-07
4.4 E-06
--
431-03-8
2,3-Butanedione
ND
ND
3.6 E-04
106-98-9
1-Buteneh
2.8 E-07
3.0 E-06
--
115-11-7
i-Buteneh
2.5 E-07
2.7 E-06
--
590-18-1
cis-2-Butene
5.4 E-08
5.7 E-07
--
6/07
Ordnance Detonation
A-41
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
624-64-6
trans-2-Butene
1.4 E-07
1.5 E-06
--
109-69-3
1-Chlorobutane
ND
ND
3.9 E-04
622-98-0
1 -Chloro-4-ethylbenzene
ND
ND
5.8 E-04
95-49-8
1 -Chloro-2-methylbenzene
ND
ND
5.3 E-04
108-41-8
1 -Chloro-3-methylbenzene
ND
ND
5.3 E-04
59-50-7
4-Chloro-3-methylphenol
ND
ND
2.2 E-04
90-13-1
1 -Chloronapthalene
ND
ND
1.7 E-04
95-57-8
2-Chlorophenol
ND
ND
1.7 E-04
2698-41-1
CS2
ND
ND
3.2 E-04
2074-87-5
Cyanogen
ND
ND
1.1 E-04
287-92-3
Cyclopentane
2.9 E-08
3.0 E-07
--
120-92-3
Cyclopentanone
ND
ND
3.5 E-04
142-29-0
Cyclopentene
5.7 E-08
6.1 E-07
--
930-30-3
2-Cyclopenten-1 -one
ND
ND
3.4 E-04
124-18-5
n-Decane
2.9 E-08
3.0 E-07
--
13466-78-9
delta 3-Carene
;; ND
ND
1.0 E-04
3018-12-0
Dichloroacetonitrile
. ND
ND
4.6 E-04
616-21-7
1,2-Dichlorobutane
ND
ND
5.3 E-04
32768-54-0
1,2-Dichloro-3 -methylbenzene
ND
ND
6.7 E-04
594-37-6
1,2-Dichloro-2-methylpropane
ND
ND
5.3 E-04
513-88-2
1,1 -Dichloro-2-propanone
ND
ND
5.3 E-04
10061-01-5
cis 1,3-Dichloro-l-propene
ND
ND
4.6 E-04
84-66-2
Diethylphthalate8
ND
ND
2.6 E-04
75-83-2
2,2-Dimethylbutane
2.9 E-08
3.0 E-07
--
79-29-8
2,3 -Dimethylbutane
1.1 E-07
1.2 E-06
--
624-92-0
Dimethyldisulfide
ND
ND
3.9 E-04
625-86-5
2,5 -Dimethylfuran
ND
ND
4.0 E-04
1071-26-7
2,2-Dimethylheptane
ND
ND
1.0 E-04
584-94-1
2,3-Dimethylhexane
5.7 E-08
6.1 E-07
--
589-43-5
2,4-Dimethylhexane
1.4 E-07
1.5 E-06
--
592-13-2
2,5-Dimethylhexane
1.4 E-07
1.5 E-06
--
565-59-3
2,3 -Dimethylpentane
4.9 E-07
5.2 E-06
--
108-08-7
2,4-Dimethylpentane
2.0 E-07
2.1 E-06
--
463-82-1
2,2-Dimethylpropane
ND
ND
1.0 E-04
3658-80-8
Dimethyltrisulfide
ND
ND
5.2 E-04
A-42
Ordnance Detonation
6/07
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
117-84-0
Di-n-octylphthalateh
1.6 E-07
1.7 E-06
--
74-84-0
Ethane8
0
0
--
64-17-5
Ethanol
ND
ND
1.9 E-04
4748-78-1
4-Ethylbenzaldehyde1
1.7 E-06
1.8 E-05
--
28134-31-8
Ethylbenzoic acid1
2.6 E-06
2.8 E-05
--
1678-91-7
Ethylcyclohexane
ND
ND
1.0 E-04
619-99-8
3-Ethylhexane
1.4 E-07
1.5 E-06
--
620-14-4
m-Ethyltoluene
2.0 E-07
2.1 E-06
--
611-14-3
o-Ethyltoluene
1.7 E-07
1.8 E-06
--
622-96-8
p-Ethyltoluene
4.7 E-07
5.0 E-06
~
--
F22
ND
ND
9.8 E-04
98-01-1
2-Furaldehyde
ND
ND
4.0 E-04
498-60-2
3-Furaldehyde
ND
ND
4.0 E-04
110-00-9
Furan
ND
ND
2.8 E-04
111-71-7
Heptanal
ND
ND
4.7 E-04
142-82-5
n-Heptane
4.9 E-07
5.2 E-06
--
110-43-0
2-Heptanone
: ND
ND
4.7 E-04
57-10-3
Hexadecanoic acid1
2.5 E-06
2.6 E-05
--
66-25-1
Hexanal
ND
ND
4.2 E-04
591-78-6
2-Hexanone
ND
ND
4.2 E-04
592-41-6
1-Hexene
2.5 E-07
2.7 E-06
--
7688-21-3
cis-2-Hexene
5.7E-08
6.1 E-07
--
4050-45-7
trans-2-Hexene
5.7E-08
6.1 E-07
~
496-11-7
Indane1
3.3 E-08
3.5 E-07
~
78-79-5
Isoprene
ND
ND
1.0 E-04
5989-27-5
d-Limonene
ND
ND
1.0 E-04
7439-95-4
Magnesium8
2.3 E-04
2.5 E-03
--
78-85-3
Methacrolein
ND
ND
2.9 E-04
75-52-5
Methane, nitro-
3.8 E-07
4.0 E-06
--
104-85-8
4-Methylbenzonitrile
ND
ND
4.9 E-04
563-80-4
3 -Methyl-2-butanone
ND
ND
3.6 E-04
563-45-1
3 -Methyl-1 -butene
ND
ND
1.0 E-04
563-46-2
2-Methyl-1 -butene
2.9 E-08
3.0 E-07
--
513-35-9
2-Methyl-2-butene
ND
ND
1.0 E-04
108-87-2
Methylcyclohexane
2.6 E-07
2.7 E-06
--
6/07
Ordnance Detonation
A-43
-------
TABLE A4 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
96-37-7
Methylcyclopentane
3.7E-07
4.0 E-06
--
78-93-3
Methyl ethyl ketone
9.2 E-08
9.8 E-07
--
620-02-0
5 -Methyl-2-furaldehyde
ND
ND
4.6 E-04
534-22-5
2-Methylfuran
ND
ND
3.4 E-04
930-27-8
3-Methylfuran
ND
ND
3.4 E-04
592-27-8
2-Methylheptane
1.7E-07
1.8 E-06
--
591-76-4
2-Methylhexane
3.7 E-07
4.0 E-06
--
589-34-4
3 -Methylhexane
5.1 E-07
5.5 E-06
--
66-27-3
Methyl methane sulfonate
ND
ND
1.9 E-04
624-91-9
Methylnitrite
ND
ND
2.5 E-04
107-83-5
2-Methylpentane
4.3 E-07
4.6 E-06
--
96-14-0
3 -Methylpentane
3.7 E-07
4.0 E-06
--
108-11-2
4-Methyl-2-pentanof
5.6 E-06
5.9 E-05
--
763-29-1
2-Methyl-1 -penteneh
1.4 E-08
1.5 E-07
--
625-27-4
2-Methyl-2-pentene
" 5.7 E-08
6.1 E-07
--
691-37-2
4-Methyl-1 -pentene
ND
ND
1.0 E-04
691-38-3
cis-4-Methyl-2-pentene
':: ND
ND
1.0 E-04
554-14-3
2-Methylthiophene
ND
ND
4.1 E-04
616-44-4
3 -Methylthiophene
ND
ND
4.1 E-04
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
9.2 E-05
78-94-4
Methyl vinyl ketone
ND
ND
2.9 E-04
88-74-4
2-Nitroaniline
ND
ND
1.7 E-04
99-09-2
3-Nitroaniline
ND
ND
7.0 E-04
88-72-2
2-Nitrotolueneh
4.9 E-08
5.3 E-07
--
99-99-0
4-Nitrotoluene
ND
ND
3.1 E-05
124-19-6
Nonanal
ND
ND
5.9 E-04
111-84-2
n-Nonane
4.8 E-06
5.1 E-05
--
821-55-6
2-Nonanone
ND
ND
5.9 E-04
--
ocs
ND
ND
2.5 E-04
124-13-0
Octanal
ND
ND
5.3 E-04
111-65-9
n-Octane
1.7 E-07
1.8 E-06
--
1600-37-9
1,1,2,3,3 -Pentachloro-1 -propene
ND
ND
8.9 E-04
110-62-3
Pentanal
ND
ND
3.6 E-04
78-78-4
i-Pentane
3.3 E-07
3.5 E-06
--
A-44
Ordnance Detonation
6/07
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
109-66-0
n-Pentane
3.6 E-07
3.9 E-06
--
600-14-6
2,3-Pentanedione
ND
ND
4.2 E-04
107-87-9
2-Pentanone
ND
ND
3.6E-04
96-22-0
3-Pentanone
ND
ND
3.6 E-04
109-67-1
1-Pentene
ND
ND
1.0 E-04
627-20-3
cis-2-Pentene
2.9 E-08
3.0 E-07
--
646-04-8
trans-2-Penteneh
0
0
~
1629-58-9
l-Penten-3-one
ND
ND
3.5 E-04
625-33-2
3-Penten-2-one
ND
ND
3.5 E-04
78-11-5
PETN
ND
ND
1.1 E-05
536-74-3
Phenylacetylene
ND
ND
6.1 E-04
80-56-8
alpha-Pinene
ND
ND
1.0 E-04
127-91-3
beta-Pinene
ND
ND
1.0 E-04
74-98-6
Propane
2.9 E-08
3.0 E-07
--
103-65-1
n-Propylbenzenc
1.7 E-07
1.8 E-06
--
121-82-4
RDX
5.5 H-06
5.8 E-05
--
95-94-3
1,2,4,5-Tetrachlorobcnzcnc
':; ND
ND
1.7 E-04
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
2.3 E-04
109-99-9
Tetrahydrofuran
ND
ND
3.0 E-04
110-02-1
Thiophene8
ND
ND
3.5 E-04
98-03-3
2-Thiophenecarboxaldehyde
ND
ND
4.7 E-04
546-06-2
Trichloroacetonitrile
ND
ND
6.0 E-04
526-73-8
1,2,3 -T rimethy lbenzene
5.4 E-08
5.7 E-07
--
108-67-8
1,3,5 -T rimethy lbenzene
1.7 E-07
1.9 E-06
--
16747-26-5
2,2,4-Trimethylhexane
2.6 E-07
2.7 E-06
--
565-75-3
2,3,4-Trimethylpentane
2.0 E-07
2.1 E-06
~
107-39-1
2,4,4-Trimethyl-1 -pentene
ND
ND
1.0 E-04
107-40-4
2,4,4-Trimethyl-2-pentene
ND
ND
1.0 E-04
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
6.6 E-05
118-96-7
2,4,6-Trinitrotoluene
ND
ND
3.3 E-05
6/07
Ordnance Detonation
A-45
-------
TABLE A4 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 9.38 E-02 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number of
test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number of
test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor rated D because the factor is for a tentatively identified compound.
A-46
Ordnance Detonation
6/07
-------
TABLE A5 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC M241, M10 HIGH EXPLOSIVE UNIVERSAL DESTRUCTOR
Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxidef
4.4 E-01
1.5
--
630-08-0
Carbon monoxide8
1.3 E-02
4.4 E-02
--
7439-92-1
Lead
3.3 E-02
1.2 E-01
--
--
Oxides of nitrogenf
5.5 E-03
1.9 E-02
--
--
PM-2.58
5.4 E-02
1.9 E-01
--
--
PM-10
1.1 E-01
3.9 E-01
--
7446-09-5
Sulfur dioxide
1.4 E-03
5.0 E-03
--
~
Total nonmethane hydrocarbons8
2.5 E-03
8.8 E-03
--
12789-66-1
Total suspended particulate
2.3 E-01
7.9 E-01
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
ND
ND
1.4E-04
208-96-8
Acenaphthvlene8
ND
ND
1.4E-04
75-07-0
Acetaldehyde8
ND
ND
1.8E-04
75-05-8
Acetonitrile8
2,5 E-06
8.7 E-06
--
98-86-2
Acetophenone
: ND
ND
5.0E-04
107-02-8
Acrolein
ND
ND
2.3 E-04
107-13-1
Acrylonitrile8
5.0 E-07
1.7 E-06
--
107-05-1
Allyl chloride
ND
ND
3.2 E-04
7429-90-5
Aluminum8
4.7 E-03
1.7 E-02
--
92-67-1
4-Aminobiphenyl
ND
ND
2.7 E-03
7664-41-7
Ammonia
ND
ND
4.6 E-02
62-53-3
Aniline
ND
ND
2.0 E-03
120-12-7
Anthracene8
ND
ND
1.4 E-04
7440-36-0
Antimony
2.6 E-03
9.0 E-03
--
7440-38-2
Arsenic
ND
ND
2.4 E-04
7440-39-3
Barium
1.8 E-03
6.2 E-03
--
71-43-2
Benzene8
2.7 E-05
9.5 E-05
--
92-87-5
Benzidine
ND
ND
1.4 E-02
56-55-3
Benzo [a] anthracene
ND
ND
1.6 E-04
205-99-2
Benzo [b] fluoranthene
ND
ND
3.0 E-04
207-08-9
Benzo [k] fluoranthene
ND
ND
1.7 E-04
191-24-2
Benzo |g,h,i]perylene
ND
ND
4.4 E-04
6/07
Ordnance Detonation
A-47
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
50-32-8
Benzo[a]pyrene
ND
ND
1.4 E-04
100-44-7
Benzyl chloride
ND
ND
5.3 E-04
7440-41-7
Beryllium
ND
ND
8.1 E-06
74-83-9
Bromomethane
ND
ND
4.0 E-04
101-55-3
4-Bromophenylphenylether
ND
ND
1.4 E-04
106-99-0
1,3-Butadiene8
2.4 E-06
8.5 E-06
--
71-36-3
n-Butanol
ND
ND
3.1 E-04
85-68-7
Butylbenzylphthalatef
4.1 E-06
1.4 E-05
--
123-72-8
Butyraldehyde
ND
ND
3.0 E-04
7440-43-9
Cadmium
1.7 E-03
6.0 E-03
--
86-74-8
Carbazole
ND
ND
1.7 E-04
56-23-5
Carbon tetrachloride
1.4 E-06
4.8 E-06
--
7782-50-5
Chlorine
2.7 E-04
9.5 E-04
--
106-47-8
4-Chloroaniline
ND
ND
1.6 E-03
108-90-7
Chlorobenzene
ND
ND
4.7 E-04
75-00-3
Chloroethane
ND'":;
ND
2.7 E-04
111-91-1
bis(2-Chloroethoxy)mcthanc
ND
ND
1.4 E-04
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.5 E-04
67-66-3
Chloroform
ND
ND
5.0 E-04
74-87-3
Chloromethane8
ND
ND
2.1 E-04
108-60-1
bis(2-Chloro-1 -methylethyl)ether
ND
ND
2.1 E-04
91-58-7
2-Chloronaphthalene
ND
ND
1.4 E-04
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.4 E-04
7440-47-3
Chromium8
3.7 E-04
1.3 E-03
--
218-01-9
Chrysene
ND
ND
1.7 E-04
7440-48-4
Cobalt8
5.5 E-06
1.9 E-05
--
7440-50-8
Copper8
2.6 E-03
9.0 E-03
--
98-82-8
Cumeneh
3.4 E-07
1.2 E-06
--
110-82-7
Cyclohexane8
4.3 E-06
1.5 E-05
--
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.6 E-04
132-64-9
Dibenzofuran
ND
ND
1.4 E-04
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-04
84-74-2
Dibutylphthalatef
ND
ND
2.7 E-03
95-50-1
o-Dichlorobenzene
ND
ND
6.1 E-04
541-73-1
m-Dichlorobenzene
ND
ND
6.1 E-04
A-48
Ordnance Detonation
6/07
-------
TABLE A5 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-46-7
p-Dichlorobenzene
ND
ND
6.1 E-04
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
2.0 E-03
75-71-8
Dichlorodifluoromethane8
ND
ND
5.0 E-04
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-04
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-04
540-59-0
1,2-Dichloroethene
ND
ND
4.0 E-04
120-83-2
2,4-Dichlorophenol
ND
ND
1.4 E-04
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-04
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
4.6 E-04
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-04
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.4 E-04
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.4 E-04
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-03
131-11-3
Dimethyl phthalate
ND
ND
1.4 E-04
99-65-0
1,3-Dinitrobcnzcnc
ND
ND
6.6 E-05
534-52-1
4,6-Dinitro-o-crcsol
ND''":;
ND
2.4 E-03
51-28-5
2,4-Dinitrophcnol
ND
ND
6.0 E-03
121-14-2
2,4-Dinitrotoluene
ND
ND
4.0 E-05
606-20-2
2,6-Dinitrotoluene
2.0 E-06
6.9 E-06
2.4 E-05
--
Total dioxin/furan compounds
1.0E-09
3.6E-09
--
122-39-4
Diphenylamine
ND
ND
1.4 E-04
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.4 E-04
100-41-4
Ethylbenzene
3.8 E-06
1.3 E-05
--
74-85-1
Ethylene8
5.9 E-05
2.1 E-04
--
117-81-7
bis(2-Ethylhexyl)phthalatef
1.0 E-05
3.6 E-05
--
206-44-0
Fluoranthene8
ND
ND
1.5 E-04
86-73-7
Fluorene8
ND
ND
1.4 E-04
50-00-0
Formaldehyde
2.0 E-05
7.1 E-05
--
76-13-1
Freon 113s
1.0 E-06
3.6 E-06
--
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
1.9 E-10
6.6 E-10
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
2.1 E-ll
7.5 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuranh
4.2 E-12
1.5 E-ll
—
118-74-1
Hexachlorobenzene
ND
ND
1.4 E-04
6/07
Ordnance Detonation
A-49
-------
TABLE A5 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-03
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.7 E-03
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
1.2 E-ll
4.0 E-ll
--
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
2.8 E-ll
9.9 E-ll
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
3.8 E-ll
1.3 E-10
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
7.3 E-12
2.6 E-ll
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
4.2 E-12
1.5 E-ll
--
72918-21-9
1,2,3,7,8,9-
Hexachlorodibenzofuranh
1.2 E-12
4.3 E-12
~
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
4.7 E-12
1.6 E-ll
--
67-72-1
Hexachloroethane
ND
ND
9.8 E-04
110-54-3
Hexaneh
3.8E-06
1.3 E-05
~
7647-01-0
Hydrochloric acid
ND
ND
4.6 E-02
74-90-8
Hydrogen cyanide
1.6 E-04
5.4 E-04
--
193-39-5
Indeno [ 1,2.3 -cd | pyrcnc
ND
ND
1.5 E-04
78-59-1
Isophorone
ND
ND
1.4 E-04
67-63-0
Isopropyl alcohol
ND
ND
2.5 E-04
7439-92-1
Lead
3.3 E-02
1.2 E-01
--
7439-96-5
Manganese8
8.7 E-05
3.0 E-04
~
7439-97-6
Mercury
1.9 E-08
6.6 E-08
--
75-09-2
Methylene chloride8
8.5 E-03
2.9 E-02
~
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-04
556-61-6
Methyl isothiocyanate
ND
ND
3.0 E-04
90-12-0
1 -Methylnaphthalene
ND
ND
5.9 E-04
91-57-6
2-Methylnaphthalene
9.7E-07
3.4E-06
--
95-48-7
2-Methylphenol
ND
ND
8.2 E-04
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-04
91-20-3
Naphthalene8
3.5 E-06
1.2 E-05
--
134-32-7
1 -Naphthylamine
ND
ND
2.7 E-03
91-59-8
2-Naphthylamine
ND
ND
2.7 E-03
7440-02-0
Nickel8
7.8 E-06
2.7 E-05
--
100-01-6
4-Nitroaniline
ND
ND
5.4 E-04
98-95-3
Nitrobenzene
ND
ND
1.3 E-05
A-50
Ordnance Detonation
6/07
-------
TABLE A5 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
55-63-0
Nitroglycerin
ND
ND
2.0 E-04
88-75-5
2-Nitrophenol
ND
ND
1.4 E-04
100-02-7
4-Nitrophenol
ND
ND
9.0 E-04
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.4 E-04
62-75-9
N-Nitrosodimethylamine
ND
ND
1.4 E-04
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.4 E-04
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.4 E-04
100-75-4
N-Nitrosopiperidine
ND
ND
1.4 E-04
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-
p-dioxin
6.4 E-10
2.2 E-09
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
4.2 E-ll
1.4 E-10
--
608-93-5
Pentachlorobenzene
ND
ND
1.4 E-04
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
1.2 E-ll
4.3 E-ll
--
57117-41-6
1,2,3,7,8-Pcntachlorodibcnzofuran
•• ¦ 2.5 E-12 ,
8.8 E-12
--
57117-31-4
2,3,4,7,8-Pcntachlorodibcnzotliran
2.7 I12
9.3 E-12
--
82-68-8
Pentachloronitrobenzcne
. ND
ND
1.4 E-04
87-86-5
Pentachlorophenol
ND
ND
6.8 E-03
85-01-8
Phenanthrene8
ND
ND
1.4 E-04
108-95-2
Phenol
1.6 E-06
5.5 E-06
--
7723-14-0
Phosphorus8
1.2 E-04
4.1 E-04
--
123-38-6
Propionaldehyde
ND
ND
2.4 E-04
115-07-1
Propylene8
1.5 E-05
5.3 E-05
--
129-00-0
Pyrene8
ND
ND
1.4 E-04
110-86-1
Pyridine
ND
ND
2.0 E-04
7782-49-2
Selenium
5.4E-07
1.9 E-06
--
100-42-5
Styrene
9.7 E-07
3.4 E-06
--
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
2.6 E-12
8.9 E-12
--
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
4.5 E-12
1.6 E-ll
~
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-04
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-04
7440-28-0
Thallium
ND
ND
4.1 E-05
108-88-3
Toluene8
0
0
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-04
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-04
6/07
Ordnance Detonation
A-51
-------
TABLE A5 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-04
79-01-6
Trichloroethylene
ND
ND
5.4 E-04
75-69-4
Trichlorofluoromethane
3.9E-07
1.4 E-06
--
95-95-4
2,4,5-Trichlorophenol
ND
ND
3.5 E-04
88-06-2
2,4,6-Trichlorophenol
ND
ND
2.0 E-04
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-04
95-63-6
1,2,4-Trimethylbenzene
2.8 E-06
9.6 E-06
--
540-84-1
2,2,4-Trimethylpentane8
5.2 E-06
1.8 E-05
--
75-01-4
Vinyl chloride
ND
ND
2.6 E-04
75-35-4
Vinylidene chloride
ND
ND
4.0 E-04
106-42-3,
108-38-3
m-Xylene, p-Xylene
1.3 E-05
4.5 E-05
--
95-47-6
o-Xylene
4.3 E-06
1.5 E-05
--
7440-66-6
Zinc8
5.3 E-03
1.9 E-02
--
Other Pollutants
64-19-7
Acetic acid
ND'
ND
2.5 E-04
67-64-1
Acetone
3.2 E-07
1.1 E-06
--
592-20-1
1 -Acetoxyacetone
ND
ND
4.8 E-04
74-86-2
Acetylene8
3.5 E-05
1.2 E-04
--
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
2.6 E-05
100-52-7
Benzaldehyde
2.5 E-06
8.9 E-06
--
271-89-6
Benzofuran
ND
ND
4.9 E-04
65-85-0
Benzoic acid
ND
ND
1.3 E-02
100-47-0
Benzonitrile
ND
ND
4.3 E-04
100-51-6
Benzyl alcohol
ND
ND
9.5 E-03
107-04-0
1 -Bromo-2-chloroethane
ND
ND
5.9 E-04
74-97-5
Bromochloromethane
1.3 E-06
4.5 E-06
--
3017-95-6
2-Bromo-1 -chloropropane
ND
ND
6.5 E-04
123-73-9
trans-2-Butenal
ND
ND
2.9 E-04
75-28-5
i-Butane
3.9 E-07
1.4 E-06
--
106-97-8
n-Butane
2.5 E-06
8.7 E-06
--
431-03-8
2,3-Butanedione
ND
ND
3.6 E-04
106-98-9
1-Butene
6.1 E-06
2.1 E-05
--
115-11-7
i-Butene
1.9 E-06
6.5 E-06
--
590-18-1
cis-2-Butene
5.3 E-07
1.9 E-06
--
A-52
Ordnance Detonation
6/07
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
624-64-6
trans-2-Butene8
2.8 E-06
9.7 E-06
--
109-69-3
1-Chlorobutane
ND
ND
3.9 E-04
622-98-0
1 -Chloro-4-ethylbenzene
ND
ND
5.8 E-04
95-49-8
1 -Chloro-2-methylbenzene
ND
ND
5.3 E-04
108-41-8
1 -Chloro-3-methylbenzene
ND
ND
5.3 E-04
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.7 E-04
90-13-1
1 -Chloronapthalene
ND
ND
1.4 E-04
95-57-8
2-Chlorophenol
ND
ND
1.4 E-04
2698-41-1
CS2
ND
ND
3.2 E-04
2074-87-5
Cyanogen
ND
ND
1.1 E-04
287-92-3
Cyclopentane8
3.9 E-07
1.4 E-06
--
120-92-3
Cyclopentanone
ND
ND
3.5 E-04
142-29-0
Cyclopentene
5.3 E-07
1.9 E-06
--
930-30-3
2-Cyclopenten-1 -one
ND
ND
3.4 E-04
124-18-5
n-Decane8
" 2.7 E-07
9.3 E-07
--
13466-78-9
delta 3-Carene
ND
ND
1.0 E-04
3018-12-0
Dichloroacetonitrile
':: ND
ND
4.6 E-04
616-21-7
1,2-Dichlorobutane
ND
ND
5.3 E-04
32768-54-0
1,2-Dichloro-3 -methylbenzene
ND
ND
6.7 E-04
594-37-6
1,2-Dichloro-2-methylpropane
ND
ND
5.3 E-04
513-88-2
1,1 -Dichloro-2-propanone
ND
ND
5.3 E-04
10061-01-5
cis 1,3-Dichloro-l-propene
ND
ND
4.6 E-04
84-66-2
Diethylphthalate
ND
ND
2.0 E-04
75-83-2
2,2-Dimethylbutane8
0
0
--
79-29-8
2,3 -Dimethylbutane
5.2 E-07
1.8 E-06
--
624-92-0
Dimethyldisulfide
ND
ND
3.9 E-04
625-86-5
2,5 -Dimethylfuran
ND
ND
4.0 E-04
1071-26-7
2,2-Dimethylheptane
ND
ND
1.0 E-04
584-94-1
2,3-Dimethylhexaneh
3.9 E-07
1.4 E-06
--
589-43-5
2,4-Dimethylhexane8
9.2 E-07
3.2 E-06
--
592-13-2
2,5-Dimethylhexaneh
6.5 E-07
2.3 E-06
--
565-59-3
2,3 -Dimethylpentane
2.0 E-06
6.8 E-06
--
108-08-7
2,4-Dimethylpentane8
1.2 E-06
4.1 E-06
--
463-82-1
2,2-Dimethylpropane
ND
ND
1.0 E-04
3658-80-8
Dimethyltrisulfide
ND
ND
5.2 E-04
6/07
Ordnance Detonation
A-53
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
117-84-0
Di-n-octylphthalate8
3.1 E-06
1.1 E-05
--
629-97-0
Docosane1
8.9 E-06
3.1 E-05
--
544-85-4
Dotriacontane1
7.9 E-06
2.7 E-05
--
74-84-0
Ethane8
8.0 E-06
2.8 E-05
--
64-17-5
Ethanol
ND
ND
1.9E-04
1678-91-7
Ethylcyclohexane
ND
ND
1.0 E-04
619-99-8
3-Ethylhexaneh
6.5 E-07
2.3 E-06
--
620-14-4
m-Ethyltoluene
9.1 E-07
3.2 E-06
--
611-14-3
o-Ethyltoluene
7.8 E-07
2.7 E-06
--
622-96-8
p-Ethyltoluene
2.1 E-06
7.3 E-06
--
--
F22
ND
ND
9.8 E-04
98-01-1
2-Furaldehyde
ND
ND
4.0 E-04
498-60-2
3-Furaldehyde
ND
ND
4.0 E-04
110-00-9
Furan
ND
ND
2.8 E-04
111-71-7
Heptanal
ND
ND
4.7 E-04
142-82-5
n-Heptane8
2.9 E-06
1.0 E-05
--
110-43-0
2-Heptanone
ND
ND
4.7 E-04
57-10-3
Hexadecanoic acid1
4.5 E-06
1.6 E-05
--
66-25-1
Hexanal
ND
ND
4.2 E-04
591-78-6
2-Hexanone
ND
ND
4.2 E-04
592-41-6
1-Hexene8
4.5 E-06
1.6 E-05
--
7688-21-3
cis-2-Hexene8
3.9 E-07
1.4 E-06
--
4050-45-7
trans-2-Hexene8
5.3 E-07
1.9 E-06
--
496-11-7
Indaneh
5.9 E-07
2.1 E-06
--
78-79-5
Isoprene
ND
ND
1.0 E-04
5989-27-5
d-Limonene
ND
ND
1.0 E-04
7439-95-4
Magnesium8
4.3 E-03
1.5 E-02
--
78-85-3
Methacroleinh
1.1 E-05
3.8 E-05
--
75-52-5
Methane, nitro-8
2.5 E-06
8.7 E-06
~
104-85-8
4-Methylbenzonitrile
ND
ND
4.9 E-04
563-80-4
3 -Methyl-2-butanone
ND
ND
3.6 E-04
563-45-1
3 -Methyl-1 -butene8
5.3 E-07
1.9 E-06
--
563-46-2
2-Methyl-1 -butene
4.0 E-07
1.4 E-06
~
513-35-9
2-Methyl-2-butene
ND
ND
1.0 E-04
108-87-2
Methylcyclohexane
1.3 E-06
4.6 E-06
--
A-54
Ordnance Detonation
6/07
-------
TABLE A5 (cont.)
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
96-37-7
Methylcyclopentane
2.0 E-06
6.8 E-06
--
54833-23-7
10-Methyleicosane1
6.2 E-06
2.2 E-05
--
78-93-3
Methyl ethyl ketonef
4.8 E-07
1.7 E-06
--
620-02-0
5 -Methyl-2-furaldehyde
ND
ND
4.6 E-04
534-22-5
2-Methylfuran
ND
ND
3.4 E-04
930-27-8
3-Methylfuran
ND
ND
3.4 E-04
592-27-8
2-Methylheptaneh
7.8 E-07
2.7 E-06
--
591-76-4
2-Methylhexane
1.8 E-06
6.4 E-06
--
589-34-4
3 -Methylhexane8
4.3 E-06
1.5 E-05
--
66-27-3
Methyl methane sulfonate
ND
ND
1.5 E-04
624-91-9
Methylnitrite
ND
ND
2.5 E-04
56862-62-5
10-Methylnonadecane1
6.8 E-06
2.4 E-05
--
107-83-5
2-Methylpentaneh
2.0 E-06
6.8 E-06
--
96-14-0
3 -Methylpentane11
1.3 E-06
4.6 E-06
--
763-29-1
2-Methyl-1 -pentene
ND
ND
1.0 E-04
625-27-4
2-Methyl-2-pentcneB
1.3 11-07
4.5 E-07
--
691-37-2
4-Methyl-1 -pentene
':: ND
ND
1.0 E-04
691-38-3
cis-4-Methyl-2-pentene
ND
ND
1.0 E-04
554-14-3
2-Methylthiophene
ND
ND
4.1 E-04
616-44-4
3 -Methylthiophene
ND
ND
4.1 E-04
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
7.2 E-05
78-94-4
Methyl vinyl ketone
ND
ND
2.9 E-04
88-74-4
2-Nitroaniline
ND
ND
1.4 E-04
99-09-2
3-Nitroaniline
ND
ND
5.4 E-04
88-72-2
2-Nitrotoluene
ND
ND
2.6 E-05
99-99-0
4-Nitrotoluene
ND
ND
--
124-19-6
Nonanal
ND
ND
5.9 E-04
111-84-2
n-Nonane
4.5 E-05
1.6 E-04
--
821-55-6
2-Nonanone
ND
ND
5.9 E-04
--
ocs
ND
ND
2.5 E-04
57-11-4
Octadecanoic acid1
4.6 E-06
1.6 E-05
--
124-13-0
Octanal
ND
ND
5.3 E-04
111-65-9
n-Octane
9.1 E-07
3.2 E-06
--
1600-37-9
1,1,2,3,3 -Pentachloro-1 -propene
ND
ND
8.9 E-04
6/07
Ordnance Detonation
A-55
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb,c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
110-62-3
Pentanal
ND
ND
3.6 E-04
78-78-4
i-Pentane
5.4E-07
1.9 E-06
--
109-66-0
n-Pentane
2.5 E-06
8.8 E-06
--
600-14-6
2,3-Pentanedione
ND
ND
4.2 E-04
107-87-9
2-Pentanone
ND
ND
3.6 E-04
96-22-0
3-Pentanone
ND
ND
3.6 E-04
109-67-1
1-Pentene
ND
ND
1.0 E-04
627-20-3
cis-2-Pentene
2.7 E-07
9.3 E-07
--
646-04-8
trans-2-Pentene
ND
ND
1.0 E-04
1629-58-9
l-Penten-3-one
ND
ND
3.5 E-04
625-33-2
3-Penten-2-one
ND
ND
3.5 E-04
78-11-5
PETN
ND
ND
8.6 E-06
536-74-3
Phenylacetylene
ND
ND
6.1 E-04
80-56-8
alpha-Pinene
ND
ND
1.0 E-04
127-91-3
beta-Pinene
ND
ND
1.0 E-04
74-98-6
Propane
3.4 E-06
1.2 E-05
--
103-65-1
n-Propylbenzcnch
6.5 11-07
2.3 E-06
--
121-82-4
RDX
1.8E-04
6.4 E-04
--
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.4 E-04
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
1.8 E-04
109-99-9
Tetrahydrofuran
ND
ND
3.0 E-04
110-02-1
Thiophene
ND
ND
3.5 E-04
98-03-3
2-Thiophenecarboxaldehyde
ND
ND
4.7 E-04
546-06-2
Trichloroacetonitrile
ND
ND
6.0 E-04
526-73-8
1,2,3 -T rimethy lbenzeneh
2.5 E-03
8.8 E-03
--
108-67-8
1,3,5 -T rimethy lbenzene
7.9 E-07
2.8 E-06
--
16747-26-5
2,2,4-Trimethylhexaneh
3.9 E-07
1.4 E-06
--
565-75-3
2,3,4-Trimethylpentane
9.1 E-07
3.2 E-06
--
107-39-1
2,4,4-Trimethyl-1 -pentene
ND
ND
1.0 E-04
107-40-4
2,4,4-Trimethyl-2-pentene
ND
ND
1.0 E-04
99-35-4
1,3,5 -T rinitrobenzene8
ND
ND
5.2 E-05
118-96-7
2,4,6-Trinitrotoluene
ND
ND
2.6 E-05
A-56
Ordnance Detonation
6/07
-------
TABLE A5 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = net explosive weight. The NEW for this ordnance is 2.86 E-01 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number of
test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number of
test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor rated D because the factor is for a tentatively identified compound.
6/07
Ordnance Detonation
A-57
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A-58 Ordnance Detonation 6/07
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APPENDIX B
NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN PHASE IV-B TESTING
AT DUGWAY PROVING GROUND, UTAH
Electronic versions of the new AP-42 sections for ordnance included in Phase IV-B testing at
Dugway Proving Ground, Utah, are located on the EPA website at:
http://www.epa. gov/ttn/chicf/ap42/indc\.htm 1.
6/07
Ordnance Detonation
B-l
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B-2 Ordnance Detonation 6/07
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