BACKGROUND DOCUMENT
REPORT ON REVISIONS TO 5th EDITION AP-42
CHAPTER 15 - ORDNANCE DETONATION
EMISSION FACTORS DEVELOPED BASED ON PHASE VI TESTING
CONDUCTED AT DUGWAY PROVING GROUND, UTAH
Prepared for:
U.S. Army Environmental Command
ATTN: IMAE-ATT
Aberdeen Proving Ground. Maryland 21010-5401
June 2008
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NOTICE
The information in this document has been funded by the U.S. Army Environmental Command
(USAEC) and prepared by MACTEC Federal Programs, Inc., under Contract No. GS-10F-0157K, Order
No. W911SR-05-F-0023. It has been reviewed by the U.S. Environmental Protection Agency (EPA)
Office of Air Quality Planning and Standards (OAQPS) and has been approved for publication. Mention
of trade names or commercial products does not constitute endorsement or recommendation for use.
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TABLE OF CONTENTS
1.0 INTRODUCTION 1
2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS 2
2.1 Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide 4
2.2 Total Suspended Particulate 5
2.3 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 or 2.5 Microns .. 5
2.4 Metals 5
2.5 Hydrochloric Acid, Chlorine, and Ammonia 5
2.6 Volatile Organic Compounds 6
2.7 Semivolatile Organic Compounds 6
2.8 Dioxin and Furan Compounds 6
2.9 Aldehyde and Carbonyl Compounds 6
2.10 Energetic Materials 7
2.11 Hydrogen Cyanide 7
2.12 Perchlorate 7
2.13 Tracer Compound 7
3.0 TEST DATA ANALYSIS AND RATING 7
3.1 EPA Guidance Regarding Test Data Quality Ratings 7
3.2 Analysis of Test Data 8
3.3 Test Data Quality Ratings 14
4.0 EMISSION FACTOR CALCULATIONS 18
4.1 Incorporation of Analytical Detection-Limits to the Test Data 19
4.2 Determination of Background Concentration 19
4.3 Determination of Test Compound Concentration 20
4.4 Determination of Background-Corrected Concentration 20
4.5 Determination of Dilution-Corrected Concentration 20
4.6 Determination of Mass of Compound Released 20
4.7 Determination of Emission Factors 22
4.8 Determination of Average Emission Factors 22
5.0 EMISSION FACTOR RATINGS 22
5.1 Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data 23
5.2 Emission Factor Ratings Assigned - Based on All Available Test Data 23
6.0 REFERENCES 33
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TABLE OF CONTENTS (cont.)
APPENDIX A:
COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
ORDNANCE INCLUDED IN PHASE VI TESTING AT DUGWAY PROVING
GROUND, UTAH
APPENDIX B:
NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN PHASE VI
TESTING AT DUGWAY PROVING GROUND, UTAH
LIST OF TABLES
No. Title Page
1 Ordnance for Which Emission Factors were Developed 1
2 Ordnance Net Explosive Weight 2
3 Sampling and Analytical Methods Used 3
4 Selected Sampling or Analytical Method for Compounds Measured Using Two
Sampling or Analytical Methods 10
5 Compounds for Which Large Relative Percent Differences Were Noted Between Test Runs
or Sample Trains 11
6 Compounds Found In the Method Blank at Levels Between 20 Percent and 50 Percent of Both
Test Values . 13
7 Compounds Found In the Method Blank at Levels Greater than 50 Percent of Both Test Values... 13
8 Downgraded Data Quality Ratings 15
9 Ordnance Categorization for Emission Factor Correlation Assessment 25
LIST OF FIGURES
No. Title Page
1 Calculation of background-corrected concentration (BCC) 21
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1.0 INTRODUCTION
Due to the lack of credible data concerning emissions from training ordnance when used in their
tactical configurations, the U.S. Army Environmental Command (USAEC) established a program to
quantify emissions from the detonation of ordnance. This document presents background information
concerning the development of air emission factors for six ordnance types used during training exercises
at U.S. Army installations. The air emission factors were developed from test data collected by USAEC.
Ordnance for which emission factors have been developed and their corresponding AP-42 sections are
identified in Table 1. To help readers easily find those emission factors of interest, the ordnance are
organized according to their Department of Defense Identification Code (DODIC).
TABLE 1 ORDNANCE FOR WHICH EMISSION FACTORS WERE DEVELOPED
DODIC
Ordnance Description
AP-42 Section
G878
M228 Practice Hand Grenade Fuse
15.5.1
G963
M7A3 CS Riot Control Agent Hand Grenade
15.5.10
K765
CS Riot Control Agent Capsule
15.7.5
L367
M22 Anti-Tank Guided Missile and Rocket Launching
Simulator
15.8.8
L410
M206 Aircraft Countermeasure Flare
15.8.16
L508
M72 Red Railroad Warning Fusee
15.8.21
The emission factors described in this document are based on data obtained during testing
conducted at Dugway Proving Ground. Utah, as presented in the final test report titled Sampling Results
for AEC Phase VI Emission Characterization of Exploding, Ordnance and Smoke/Pyrotechnics1 and the
document titled Detailed Test Plan for Phase VI Emission Characterization of Exploding Ordnance and
Smoke/Pyrotechnics.2 These documents were supplemented by additional data provided by the testing
contractor.3 For each ordnance, two test runs were conducted. Between one and 47 items were detonated
per run, depending upon the ordnance tested. Source test protocols were developed by USAEC before
any testing was conducted and were reviewed by the U.S. Environmental Protection Agency's (EPA's)
Emission Measurement Center. The tests were conducted between June 21 and 26, 2004.
The compounds that were measured included carbon monoxide (CO), carbon dioxide (C02),
oxides of nitrogen (NOx), sulfur dioxide (S02), total suspended particulate (TSP), particulate matter with
an aerodynamic diameter less than or equal to 10 microns (PM-10), particulate matter with an
aerodynamic diameter less than or equal to 2.5 microns (PM-2.5), metals, hydrogen chloride (HC1),
chlorine (Cl2), ammonia (NH3), volatile organic compounds (VOC), semivolatile organic compounds
(SVOC), dioxins/furans (PCDD/PCDF), aldehydes and carbonyls, energetic materials, hydrogen cyanide,
perchlorate, and sulfur hexafluoride (SF6). Within each of the AP-42 sections, only emission factors for
criteria pollutants, carbon dioxide, hazardous air pollutants (as defined by § 112(b)(1) of the Clean Air Act
[CAA]), and toxic chemicals (as defined by §313 of the Emergency Planning and Community Right-to-
Know Act [EPCRA]) are presented.
With the exception of DODICs K765 and L508, the emission factors were developed on a "per
item" basis and on a "per net explosive weight (NEW)" basis. Users should choose the appropriate
emission factor to estimate emissions based upon the data available; either factor is equally valid. The
NEW of each ordnance tested is provided in the corresponding AP-42 section and in Table 2. Because
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DODICs K765 and L508 do not have a defined NEW, the emission factors were only developed on a "per
item" basis for these two items.
TABLE 2 ORDNANCE NET EXPLOSIVE WEIGHT
DODIC
Ordnance Description
NEW (lb/item)a
G878
M228 Practice Hand Grenade Fuse
4.50 E-03
G963
M7A3 CS Riot Control Agent Hand Grenade
7.50 E-01
K765
CS Riot Control Agent Capsule
NA
L367
M22 Anti-Tank Guided Missile and Rocket Launching
Simulator
3.12 E-02
L410
M206 Aircraft Countermeasure Flare
2.84 E-01
L508
M72 Red Railroad Warning Fusee
NA
aNEW value obtained from References 1 and 4.
This document includes five sections in addition to this Introduction. Section 2 of this document
identifies the compounds measured during the test program and describes the emission measurement
methods used. Section 3 includes a discussion of the emission factor final test report and ratings for the
test data contained therein. Section 4 describes the calculations and methodologies used to develop
emission factors for each type of compound measured. Section 5 describes the methodology used to rate
the emission factors and provides emission factor ratings for each type of compound measured. Section 6
includes a complete list of the references cited in this document.
There are two appendices included with this document. Appendix A identifies, by ordnance type,
all of the compounds for which analyses were performed and the emission factors that were developed.
[Note: Compounds present in the method blank at greater than 50 percent of test levels are excluded from
Appendix A as described in Section 3.2.4.] Appendix A also identifies the minimum detection levels
associated with all compounds that were not detected. Emission factors and minimum detection levels
presented in Appendix A were determined from the most accurate method if two sampling or analytical
methods were used to measure one compound. Appendix B presents the new AP-42 sections for the six
ordnances that were tested.
In addition to this document, there are electronic databases available on the web
(http://www.epa.gov/ttn/chief/ap42/index.html') that contain the data used in the development of the
emission factors. The general procedures that were followed to develop these emission factors can be
found at the same web address under the title Procedures for Preparing Emission Factor Documents5 and
Draft Detailed Procedures for Preparing Emission Factors6
2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS
The USAEC Phase VI series testing was conducted in the Smoke Characterization Test Chamber
(Smoke Chamber) located at Dugway Proving Ground, Utah. The Smoke Chamber is an aluminum-lined
chamber with an interior volume of approximately 820 cubic feet. The chamber is approximately 7 feet
wide, 20 feet long, and 6 feet tall for 2/3 of its length and 5 feet tall for the remainder. During sampling,
fans inside the chamber keep the gases mixed while stainless steel probes extract gas samples from the
chamber through 12 sample ports. Gases extracted from the chamber are replaced by ambient air that
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enters the chamber through six '/2-inch diameter vent lines that are distributed along one side of the
chamber. An electrical firing circuit is used to remotely detonate the ordnance and release the tracer gas.
A number of different test methods were employed to collect and analyze the emission data that
were used to develop emission factors for detonation of ordnance. Table 3 identifies each emission test
method used; bracketed information identifies the purpose of using the method. The emissions data were
collected using EPA test methods published in Title 40 of the Code of Federal Regulations, Part 51
(40 CFR 51); 40 CFR 60; and in Compendium of Methods for the Determination of Toxic Organic
Compounds in Ambient Air? Some of the sample analytical procedures used were from EPA Office of
Solid Waste (OSW) publication SW-846, Test Methods for Evaluating Solid Waste, Physical/Chemical
Methods,8 Where necessary, the test methods were adapted to reflect application to the unique testing of
ordnance detonation in the Smoke Chamber.
TABLE 3 SAMPLING AND ANALYTICAL METHODS USED
Compound
Test Method
CO
40 CFR 60, Appendix A, EPA Method 10 - Determination of Carbon Monoxide
Emissions from Stationary Sources [sampling and analysis]
o
o
40 CFR 60, Appendix A, EPA Method 3A - Determination of Oxygen and Carbon
Dioxide Concentrations in Emissions from Stationary Sources (Instrumental Analyzer
Procedure) [sampling and analysis]
NOx
40 CFR 60, Appendix A, EPA Method 7E - Determination of Nitrogen Oxides
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
so2
40 CFR 60. Appendix A. EPA Method 6C - Determination of Sulfur Dioxide
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
TSP
40 CFR 60, Appendix A, EPA Method 5 - Determination of Particulate Matter from
Stationary Sources [sampling and analysis]
PM-10 and
PM-2.5
40 CFR 51, Appendix A, EPA Method 201A - Determination of PM-10 Emissions
(Constant Sampling Rate Procedure) [sampling and analysis]
Metals
Metal sample was obtained from TSP sample [sampling]
40 CFR 60, Appendix A, EPA Method 29 - Determination of Metals Emissions from
Stationary Sources [analysis]
SW-846 Method 601 OA - Inductively Coupled Plasma-Atomic Emission Spectrometry
[analysis for metals except mercury]
SW-846 Method 7470 - Mercury in Liquid Waste (Manual Cold-Vapor Technique)
[analysis mercury]
HC1, CL2,
and NH3
40 CFR 60, Appendix A, EPA Method 26 - Determination of Hydrogen Chloride
Emissions from Stationary Sources [sampling]
EPA Conditional Test Method 027 - Procedure for Collection and Analysis of
Ammonia in Stationary Sources [analysis]
voc
EPA Compendium Method TO-12 -Method for the Determination of Non-Methane
Organic Compounds (NMOC) in Ambient Air Using Cryogenic Preconcentration and
Direct Flame Ionization Detection (FID) [sampling and analysis]
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TABLE 3 (cont.)
Compound
Test Method
Speciated
voc
svoc
Dioxins and
Furans
Aldehydes
and
Carbonyls
Energetic
Materials
Hydrogen
Cyanide
Perchlorate
Tracer
Compound
(SF6)
EPA Compendium Method TO-14 -Determination of Volatile Organic Compounds
(VOCs) in Ambient Air Using SUMMA Passivated Canister Sampling and Gas
Chromatographic Analysis [sampling and analysis]
SW-846 Method 0010 - Modified Method 5 Sampling Train [sampling]
SW-846 Method 8270 - Semivolatile Organic Compounds by Gas Chromatography/
Mass Spectrometry (GC/MS) [analysis]
40 CFR 60, Appendix A, EPA Method 23 - Determination of Polychlorinated
Dibenzo-p-dioxins and Polychlorinated Dibenzofurans from Municipal Waste
Combustors [sampling]
SW-846 Method 8290 - Polychlorinated Dibenzodioxins (PCDDs) and
Polychlorinated Dibenzofurans (PCDFs) by High-Resolution Gas
Chromatography/High-Resolution Mass Spectrometry (HRGC/HRMS) [analysis]
EPA Compendium Method TO-11A - Determination of Formaldehyde in Ambient Air
Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography
(HPLC) [sampling and analysis]
SW-846 Method 0010 - Modified Method 5 Sampling Train [sampling]
SW-846 Method 8095 - Explosives by Gas Chromatography [analysis]
EPA Conditional Test Method 033 - Sampling and Analysis for Hydrogen Cyanide
Emissions from Stationary Sources | sampling and analysis |
Perchlorate sample was obtained from TSP sample |sampling]
EPA Method 314 - Determination of Perchlorate in Drinking Water Using Ion
Chromatography [analysis]
Grab sample [sampling]
Gas Chromatograph/Electron Capture Detector [analysis]
The following sections identify and briefly describe the test methods used to measure each
compound or group of compounds. Additional information regarding the operation of the Smoke
Chamber and the test methods used is presented in Reference 1. EPA-approved methods were used by
the laboratories that provided sampling and analysis data.
2.1 Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide
Real-time concentrations of CO, C02, NOx, and S02 that resulted from the use of ordnance in the
Smoke Chamber were measured using a continuous emissions measurement system (CEMS). CO
sampling and analysis was conducted in accordance with 40 CFR Part 60, Appendix A, Method 10 -
Determination of Carbon Monoxide Emissions from Stationary Sources. C02 sampling and analysis was
conducted in accordance with 40 CFR Part 60, Appendix A, Method 3A - Determination of Oxygen and
Carbon Dioxide Concentrations in Emissions from Stationary Sources. NOx sampling and analysis was
conducted in accordance with 40 CFR Part 60, Appendix A, Method 7E - Determination of Nitrogen
Oxides Emissions from Stationary Sources. S02 sampling and analysis was conducted in accordance with
40 CFR Part 60, Appendix A, Method 6C- Determination of Sulfur Dioxide Emissions from Stationary
Sources. For each run, the target minimum sampling time was 20 minutes.
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2.2 Total Suspended Particulate
The TSP concentration that resulted from the use of ordnance in the Smoke Chamber was
determined using a sampling and analysis procedure based on 40 CFR 60, Appendix A, EPA Method 5 -
Determination of Particulate Matter from Stationary Sources. During each run, duplicate samples were
obtained using samplers operating simultaneously. For each run, the target minimum sampling time was
20 minutes. The TSP concentration was computed by dividing the mass of TSP collected by the volume
of air sampled, corrected to standard conditions.
2.3 Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 or 2.5 Microns
The PM-10 and PM-2.5 concentrations that resulted from the use of ordnance in the Smoke
Chamber were determined using a modified sampling and analysis procedure based on 40 CFR 51,
Appendix A, Method 201A - Determination of PM-10 Emissions (Constant Sampling Rate Procedure).
The sample was collected using a short probe and two cyclones in series. Particles larger than 10 microns
were removed in the first cyclone. Particles between 10 and 2.5 microns passed through the first cyclone
but not the second. Particles smaller than 2.5 microns passed through the second cyclone and were
captured on a filter. Each fraction was measured gravimetrically. The particulate concentrations were
computed by dividing the mass of PM-10 and PM-2.5 collected by the volume of air sampled, corrected
to standard conditions.
2.4 Metals
Metal concentrations that resulted from the use of ordnance in the Smoke Chamber were
determined using particulate matter from the TSP samples collected as described in Section 2.2. After the
TSP total weight gain was determined in the laboratory, a portion of the TSP filter was digested with
concentrated hydrogen fluoride and nitric acid per 40 CFR 60. Appendix A. Method 29 - Determination
of Metals Emissions from Stationary Sources. The digestate was then analyzed for metals (except
mercury) using inductively coupled argon plasma (ICAP) emission spectroscopy in accordance with
SW-846 Method 601 OA - Inductively Coupled Plasma-Atomic Emission Spectrometry. Mercury was
determined by cold vapor atomic absorption spectroscopy (CVAAS) in accordance with SW-846
Method 7470 - Mercury in Liquid Waste (Manual Cold-Vapor Technique). The concentration of each
target metal was computed by dividing the mass of metal collected by the volume of air sampled,
corrected to standard conditions.
2.5 Hydrochloric Acid, Chlorine, and Ammonia
Hydrochloric acid (HC1), chlorine (Cl2), and ammonia (NH3) concentrations that resulted from
the use of ordnance in the Smoke Chamber were sampled in accordance with 40 CFR 60, Appendix A,
Method 26 - Determination of Hydrogen Chloride Emissions from Stationary Sources. During each run,
chamber gases were pulled through two sets of impingers in series containing dilute sulfuric acid and
sodium hydoxide solutions. The HC1 and NH3 were absorbed in the sulfuric acid solution, while the Cl2
passed through and was absorbed by the sodium hydroxide solution. HC1 and Cl2 were measured in
accordance with 40 CFR 60, Appendix A, EPA Method 26. NH3 was measured in accordance with EPA
Conditional Test Method 027 - Procedure for Collection and Analysis of Ammonia in Stationary Sources.
The concentrations of HC1, Cl2, and NH3 were computed by dividing the mass collected by the volume of
air sampled, corrected to standard conditions. For each run, the target minimum sampling time was
20 minutes.
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2.6 Volatile Organic Compounds
VOC concentrations that resulted from the use of ordnance in the Smoke Chamber were
determined using two methods from the Second Supplement to Compendium of Methods for the
Determination of Toxic Organic Compounds in Ambient Air. (1) Method TO-12 -Method for the
Determination of Non-methane Organic Compounds in Ambient Air using Cryogenic Preconcentration
and Direct Flame Ionization Detection and (2) Method TO-14 - Determination of Volatile Organic
Compounds in Ambient Air Using SUMMA Passivated Canister Sampling and Gas Chromatographic
Analysis. For both procedures, air samples were collected in stainless steel 6-liter SUMMA® canisters.
Two or three identical canisters were used for each test run. The minimum sampling time for each VOC
canister was 10 minutes.
2.7 Semivolatile Organic Compounds
SVOC concentrations that resulted from the use of ordnance in the Smoke Chamber were
determined based on procedures found in SW-846 Method 0010 - Modified Method 5 Sampling Train.
During each run, duplicate samples were collected using two PS-1 samplers that contained special
sampling inlets (i.e., aluminum sampling modules) designed to hold 100-mm diameter quartz fiber filters
to collect particulate matter, followed by XAD-2 adsorbent resin cartridges for collection of vapor phase
SVOCs. A 20-minute sampling time was targeted. Following sampling, the filters and resin cartridges
underwent solvent extraction and the mass of SVOC collected was quantitatively determined by GC/MS
analysis following procedures in SW-846 Method 8270 - Semivolatile Organic Compounds by Gas
Chromatography/Mass Spectrometry (GC/MS). Unknown compounds, if any, were tentatively identified
using computerized mass spectral matching techniques of the highest non-target "peaks."
2.8 Dioxin and Furan Compounds
Dioxin and furan compound concentrations that resulted from the use of ordnance in the Smoke
Chamber were determined based on procedures found in 40 CFR 60, Appendix A, EPA Method 23 -
Determination ofPolychlorinated Dibenzo-p-dioxins and Poly chlorinated Dibenzofurans from Municipal
Waste Combustors. During each run, duplicate samples were obtained using two modified PS-1
samplers. The modified samplers used standard quartz filters, but the adsorbent cartridges contained
XAD-2 resin sandwiched between polyurethane foam (PUF) plugs. A minimum sampling time of
20 minutes was targeted. After sampling, the filters and adsorbent cartridges underwent extraction with
the appropriate solvent(s). The mass of dioxin and furan compounds collected was quantitatively
determined following SW-846 Method 8290 - Polychlorinated Dibenzodioxins (PCDDs) and
Polychlorinated Dibenzofurans (PCDFs) by High-Resolution Gas Chromatography/High-Resolution
Mass Spectrometry (HRGC/HRMS).
2.9 Aldehyde and Carbonyl Compounds
Aldehyde and carbonyl compound concentrations that resulted from the use of ordnance in the
Smoke Chamber were determined using EPA Compendium Method TO-11A - Determination of
Formaldehyde in Ambient Air Using Adsorbent Cartridge Followed by High Performance Liquid
Chromatography (HPLC), but using modified sampling and analytical procedures.
Dinitrophenylhydrazine (DNPH) laden cartridge tubes were used as a direct probe to trap and derivatize
aldehyde and carbonyl compounds. A minimum sampling time of 20 minutes was targeted. Analysis
was by HPLC with ultraviolet (UV) absorption detection.
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2.10 Energetic Materials
Energetic compound concentrations that resulted from the use of ordnance in the Smoke Chamber
were determined based on procedures found in SW-846 Method 0010 - Modified Method 5 Sampling
Train. Samples were collected using combination quartz filter/adsorbent cartridges. The adsorbent
cartridges contained XAD-2 polymeric resin beads. A minimum sampling time of 20 minutes was
targeted. After sampling, the filters and adsorbent cartridge were extracted with isoamyl acetate. The
effluent was then analyzed following the procedures outlined in SW-846 Method 8095 - Explosives by
Gas Chromatography.
2.11 Hydrogen Cyanide
Hydrogen cyanide (HCN) concentrations that resulted from the use of ordnance in the Smoke
Chamber were determined using EPA Conditional Test Method (CTM) 033 - Sampling and Analysis for
Hydrogen Cyanide Emissions from Stationary Sources. The sample gas was drawn through a heated
quartz-fiber filter and two impingers containing 0.1 normal sodium hydroxide (NaOH). A minimum
sampling time of 20 minutes was targeted. The pH of the impingers was measured after sampling to
ensure that all cyanide was retained. The impinger solution and extracted filter were analyzed by ion
chromatography.
2.12 Perchlorate
Perchlorate concentrations that resulted from the use of ordnance in the Smoke Chamber were
determined using particulate matter from the TSP samples collected as described in Section 2.2. After the
TSP total weight gain was determined in the laboratory, the perchlorates were leached from the filter by
shaking small strips of the filter in reagent water for 1 hour. Ion chromatography was then used to
analyze the digestate in accordance with EPA Method 3 14 - Determination of Perchlorate in Drinking
Water Using Ion Chromatography.
2.13 Tracer Compound
Sulfur hexafluoride (SF6) was used as a tracer compound during each run to estimate the amount
of sample dilution that occurred as a result of ambient air entering the Smoke Chamber during the run.
Grab samples were collected five times during each run using evacuated 1-L canisters. A minimum
sampling time of 2 minutes was targeted for each canister. The canisters were analyzed for the tracer
compound using a GC with an electron capture detector.
3.0 TEST DATA ANALYSIS AND RATING
3.1 EPA Guidance Regarding Test Data Quality Ratings
Prior to inclusion of emission factors in AP-42, the reliability of the underlying emission test data
must be appraised in accordance with the rating system specified in Reference 5. Under this rating
system, test data are assigned a rating from A to D, where an "A" rating is assigned to the highest quality
data. The criteria used to assign a specific data quality rating are summarized below.
A Tests are performed by using an EPA reference test method, or when not applicable, a sound
methodology. Tests are reported in enough detail for adequate validation and raw data are
provided that can be used to duplicate the emission results presented in the report.
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B Tests are performed by a generally sound methodology, but lacking enough detail for adequate
validation. Data are insufficient to completely duplicate the emission result presented in the
report.
C Tests are based on an unproven or new methodology, or are lacking a significant amount of
background information.
D Tests are based on a generally unacceptable method, but the method may provide an order-of-
magnitude value for the source.
Four specific criteria are identified in Reference 5 for consideration to assist in the assignment of
a test data quality rating. These four criteria are:
1. Source operation. If the manner in which the source was operated is well documented in the
report and the source was operating within typical parameters during the test, an "A" rating
should be assigned. If the report stated parameters that were typical, but lacked detailed
information, a "B" rating should be assigned. If there is reason to believe the operation was not
typical, a "C" or "D" rating should be assigned.
2. Test methods and sampling procedures. In developing the ratings, the estimated accuracy and
precision of the test method as well as the adequacy of the documentation should be considered.
In general, if a current EPA reference test method, appropriate for the source, was followed, the
rating should be higher ("A" or "B"). If other methods were used, an assessment should be made
of their validity. If it is judged that the method was likely to be inaccurate or biased, a lower
rating ("C" or "D") should be given. A complete report should indicate whether any procedures
deviated from standard methods and explain any deviations. If deviations were reported, an
evaluation should be made of whether these were likely to influence the test results.
3. Process information. During testing, many variations in the process can occur without warning
and sometimes without being noticed. Such variations can induce wide deviations in sampling
results. If a large variation between test run results cannot be explained by information contained
in the site final test report or from test reports of other sources, the data are suspect and should be
given a lower rating or excluded. However, it should be recognized that a process may have
highly variable emissions and a lower rating may not be appropriate solely on the basis of wide
deviations in sampling results.
4. Analysis and calculations. Ideally, final test reports should contain original raw data sheets and
other documentation such as gas parameters (dry cubic feet per minute, oxygen percentage),
calculation sheets, or example calculations describing how the calculated emission results were
obtained. If there are data sheets, the nomenclature and equations used should be compared to
those specified by EPA to establish equivalency. The depth of review of the calculations should
be dictated by the reviewers' confidence in the ability and conscientiousness of the tester, based
on such factors as consistency of results and completeness of other areas of the final test report.
Reports may indicate that raw data sheets were available, but were not included. If the final test
report is of high quality based on the other criteria, the quality rating should not be lowered due to
a lack of data sheets.
An overall test data quality rating should be assigned based upon the ratings assigned for each of the four
criteria.
3.2 Analysis of Test Data
Data included in the final test report1 were rated in accordance with the rating system described
above. Results for each of the four criteria are presented in the following sections.
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3.2.1 Source Operations
The manner by which the ordnance were deployed (i.e., used) is documented in the final test
report. Each of the ordnance that was tested was deployed in a manner similar to that which would occur
in the field. The tests appear to have replicated typical ordnance operating parameters; consequently, the
test data should be assigned an "A" rating based on this criterion.
3.2.2 Test Methods and Sampling Procedures
The test methods and sampling procedures were evaluated as being appropriate and consistent
with EPA test methods or sound methodology. Except as noted below, no problems of any significance
were identified; consequently, the test data should be assigned an "A" rating based on this criterion.
3.2.2.1 CEMS-Measured Data
Although summaries of the CEMS data were provided for the tests,1 raw CEMS data were not
provided for the tests or for the pre- and post-test quality control (QC) activities. Furthermore, none of
the calibration gas certifications were supplied. There was no evidence of bias in the data; however,
based on the issues noted above, the test data for the CEMS-measured compounds (i.e., CO, C02, NOx,
and S02) should be assigned a "B" rating based on this criterion.
3.2.2.2 Compounds Sampled or Analyzed Using More than One Test Method or Analytical Method
Twelve compounds were either sampled or analyzed using two methods; these compounds are
identified in Table 4. For each of these compounds, emission factors were calculated based upon the data
measured using the more appropriate test or analytical method: data measured using the less appropriate
method were ignored. The more appropriate method was identified by reviewing the methods and the
target compound lists associated with each method, If a specific compound appeared on the target
compound list for one method but not the other, the method targeting the compound was selected. If a
specific compound appeared on the target compound lists for both methods, the method judged to provide
the most accurate data was selected.
For compounds analyzed using both the TO-11A (aldehydes) and TO-14 (VOC) methods, the
TO-11A method analysis was judged to be more accurate and was selected. For compounds analyzed
using both the TO-12 (VOC) and TO-14 (VOC) methods, the TO-14 method analysis was judged to be
more accurate and was selected. For compounds analyzed using both the SW8270 (SVOC) and TO-14
(VOC) methods, the TO-14 method analysis was judged to be more accurate and was selected. [Note:
Naphthalene was analyzed using both SW8270 (SVOC) and TO-14 (VOC), but only appears on the target
compound list for SW8270; therefore, this method analysis was selected.] For compounds analyzed using
both the SW8270 (SVOC) and SW8095 (energetics) methods, the SW8095 method analysis was judged
to be more accurate and was selected.
Occasionally, the compound measurement from the less accurate method was chosen because the
compound had poor precision between test runs for the sampling method that would have been more
accurate under normal circumstances. These cases are noted in the footnotes to Table 4.
6/08
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TABLE 4 SELECTED SAMPLING OR ANALYTICAL METHOD FOR COMPOUNDS MEASURED
USING TWO SAMPLING OR ANALYTICAL METHODS
Compound
Selected Method
Other Method Employed
1,2-Dichlorobenzene
TO-14 (VOC)
SW8270 (SVOC)
1,3 -Dichlorobenzene
TO-14 (VOC)
SW8270 (SVOC)
1,4-Dichlorobenzene
TO-14 (VOC)
SW8270 (SVOC)
1,3 -Dinitrobenzene3
SW8095 (Energetics)
SW8270 (SVOC)
2,4-Dinitrotolueneb'c
SW8095 (Energetics)
SW8270 (SVOC)
2,6-Dinitrotoluene
SW8095 (Energetics)
SW8270 (SVOC)
Hexachlorobutadiene
TO-14 (VOC)
SW8270 (SVOC)
Naphthalene4®
SW8270 (SVOC)
TO-14 (VOC)
Nitrobenzenef
SW8095 (Energetics)
SW8270 (SVOC)
1,2,4-Trichlorobenzene
TO-14 (VOC)
SW8270 (SVOC)
Acetone
TO-11A (Aldehydes)
TO-14 (VOC)
1,3,5 -T rinitrobenzene8
SW8095 (Energetics)
SW8270 (SVOC)
a For DODIC L508, data analyzed using the SW8270 analytical method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between the
SW8095 analytical results.
b For DODIC G878, data analyzed using the SW8270 analytical method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between the
SW8095 analytical results.
c For DODIC L410, data collected from the SW8270 analytical method were used to develop emission
factors because this compound was present in the SW8095 method blank or field blank at a level
greater than 20 percent of the test values.
d For DODIC G878, data analyzed using the TO-14 analytical method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between the
SW8270 analytical results.
e For DODICs K765, L367, L410, and L508, data collected from the TO-14 analytical method were used
to develop emission factors because this compound was present in the SW8270 method blank or field
blank at a level greater than 50 percent of the test values.
f For DODIC G963, data collected from the SW8270 analytical method were used to develop emission
factors because this compound was present in the SW8095 method blank or field blank at a level
greater than 20 percent of the test values.
8 For DODICs G963 and K765 data analyzed using the SW8270 analytical method were used to develop
emission factors because this compound had a relative percent difference greater than 100 percent
between the SW8095 analytical results.
3.2.2.3 Tentatively Identified Compounds
During the analysis of the VOC and SVOC data, the highest nontarget "peaks" were tentatively
identified using computerized mass spectral matching techniques. Emission factors were developed for
these tentatively identified compounds (TICs) if all of the following criteria were met.
1. The TIC corresponded to a unique compound (e.g., fluorene). Emission factors were not
developed if the TIC corresponded to a class of compounds (e.g., unknown alcohol).
10
Ordnance Detonation
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2. The TIC was not identified using another analysis method that provided higher confidence data.
Emission factors were developed based upon the higher confidence analysis method if such data
were available.
3. The TIC was not present in the method blank. Emission factors were not developed if the TIC
was found in the corresponding method blank.
The number of VOC that were tentatively identified as unique compounds, were not identified
using a higher confidence method, and were not present in the method blank varied from two to
seven compounds per ordnance. The number of SVOC that were tentatively identified as unique
compounds, were not identified using a higher confidence method, and were not present in the method
blank varied from nine to 24 compounds per ordnance. Emission factors were developed for all of these
TICs, but because of the uncertainty in the true identity of the TICs, the test data were assigned a "C"
rating.
3.2.3 Process Information
Ordnances are manufactured to tight tolerances and are expected to deploy in a very repeatable
fashion. Consequently, the test data should be assigned an "A" rating based upon this criterion.
However, large relative percent differences (i.e., greater than 100 percent) between test runs or sample
trains were noted for several compounds. Specific instances in which these differences were noted are
identified in Table 5. The equation below illustrates calculation of relative percent difference:
7 , .. test 1 concentration - test 2 concentration
relative percent difference = : x 100%
average of test 1 and test 2 concentrations
Due to the large relative percent differences between test runs, the test data specifically identified
in Table 5 were assigned a "C" rating. The remainder of the data should be assigned an "A" rating based
on this criterion.
TABLE 5 COMPOUNDS FOR WHICH LARGE RELATIVE PERCENT DIFFERENCES
WERE NOTED BETWEEN TEST RUNS OR SAMPLE TRAINS
Compound
Applicable DODIC
Total nonmethane hydrocarbons
K765
Chlorine
G878, G963
Chlorobenzene
K765
2,6-Dinitrotoluene
K765
Ethylbenzene
K765
Ethylene
L367, L410
bis(2-Ethylhexyl)phthalate
L508
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
L367
Hexane
L410
Hydrochloric acid
G963
Methylene chloride
L508
2-Methylphenol
K765
6/08
Ordnance Detonation
11
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TABLE 5 (cont.)
Compound
Applicable DODIC
Nitroglycerin
L508
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
L367, L410
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
G963, L367, L508
Styrene
K765
2,3,7,8 -T etrachlorodibenzofuran
L508
1,2,4-Trimethylbenzene
L367
m-Xylene, p-Xylene
K765, L367
Benzene, l-chloro-3-methyl -
K765
n-Butane
L367
1-Butene
L410
o-Chlorobenzalmalononitrile
K765
Isobutane
L367
2-Nitrotoluene
L410
4-Nitrotoluene
L508
PETN
G963jL508
RDX
G963. K765. L508
Tetrahydrofuran
K765,.
2,4,6-Trinitrotoluene
G878, K765, L508
3.2.4 Analysis and Calculations
The test report,1 detailed test plan,2 and analytical data supporting the test report3 were reviewed
to determine whether they contained all of the original raw data, other documentation, and example
calculations. Although the test report did not contain raw field data, the data were made available upon
request. The test report also lacked certain calibration data. However, the missing information was
judged insufficient to result in a downgrade of the test data quality rating.
The raw data and sample calculations presented in the final test report, detailed test plan, and
analytical data supporting the test report were reviewed to determine if the emission factors presented in
the report could be duplicated. Where differences were found between the emission factors calculated
using the Excel spreadsheets and those presented in the test report, an examination was made to determine
the reason for the differences.
Several minor errors were noted in the calculation of the emission factors within the test report,
particularly with respect to the incorporation of "0" values into the emission factors (see Section 4.4) and
the net explosive weight assumed for each ordnance. The emission factors presented in AP-42 are based
upon the corrected spreadsheets. Based upon the raw data, other documentation, and the Excel
spreadsheet calculations, the test data should be assigned an "A" rating.
12
Ordnance Detonation
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Emission factors developed for compounds present in the method blank at levels of 20 percent to
50 percent of both test values were assumed to be biased high. Several compounds met this criterion and
are identified in Table 6. For these compounds, the test data were assigned a "B" rating.
TABLE 6 COMPOUNDS FOUND IN THE METHOD BLANK AT LEVELS BETWEEN
20 PERCENT AND 50 PERCENT OF BOTH TEST VALUES
Compound
Applicable DODIC
Total nonmethane hydrocarbons
L367
Cadmium
L410
Chromium
G963, K765, L367, L410, L508
Copper
L367
1,2,3,4,7,8 -Hexachlorodibenzofuran
G963, K765
Manganese
L367
Nickel
L508
Nitroglycerin
L508
Thallium
L508
Zinc
G963, K765, L367, L508
Isobutane
L410
Magnesium
L367. L410
4-Nitrotoluene
L508
Propane
1.410
When compounds were found in the method blank at levels greater than 50 percent of both test
values, the data were assumed to be suspect and no emission factors were developed. The compounds
that met this criterion are listed in Table 7.
TABLE 7 COMPOUNDS FOUND IN THE METHOD BLANK AT LEVELS GREATER THAN
50 PERCENT OF BOTH TEST VALUES
Compound
Applicable DODIC
Acetaldehyde
G878, K765, L367, L410
Aluminum
all DODICs
Antimony
all DODICs
Arsenic
all DODICs
Barium
G963, K765, L367, L410, L508
Beryllium
G963, K765
Butylbenzylphthalate
G878, K765
Cadmium
G878, G963, K765, L367, L508
Copper
G878, G963, K765, L410, L508
6/08
Ordnance Detonation
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TABLE 7 (cont.)
Compound
Applicable DODIC
1,2,3,4,6,7,8-Heptachlorodibenzofuran
all DODICs
1,2,3,4,7,8 -Hexachlorodibenzofuran
L508
Lead
all DODICs
Manganese
G878, G963, K765, L410, L508
Nickel
G963, K765, L367, L410
Nitrobenzene
L508
Phosphorus
all DODICs
Propionaldehyde
G878, L410
Thallium
G878, G963, K765, L367, L410
n-Butane
G878, L410, L508
Eicosane
K765, L410, L508
Heneicosane
L367, L508
Heptadecane
G878, K765, L410, L508
Hexadecane
G878, K765, L367, L410
HMX
all DODICs
Isobutane
G878. L508
Magnesium
G878, G963. K765. L508
Methyl ethyl ketone
L367
4-Nitrotoluene
G878, L367
Nonadecane
L508
Pentadecane
G878, K765, L367, L410, L508
Tetradecane
all DODICs
Tetryl
G878, K765, L367, L410, L508
3.3 Test Data Quality Ratings
Upon completing the analysis described in the preceding section of this document, the test data
quality ratings assigned as a result of the four criteria were reviewed. This review led to a downgrading
of some of the test data from an "A" rating to either a "B" rating or a "C" rating. Table 8 identifies the
data quality ratings for all compounds that did not receive an "A" rating.
14
Ordnance Detonation
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TABLE 8 DOWNGRADED DATA QUALITY RATINGS
Compound
Data Quality
Rating
Applicable DODIC
Carbon dioxide
B
All DODICs
Carbon monoxide
B
All DODICs
Oxides of nitrogen
B
All DODICs
Sulfur dioxide
B
All DODICs
Total nonmethane hydrocarbons
C
K765
Total nonmethane hydrocarbons
B
L367
Cadmium
B
L410
Chlorine
C
G878, G963
Chlorobenzene
C
K765
Chromium
B
G963, K765, L367, L410, L508
Copper
B
L367
2,6-Dinitrotoluene
C
K765
Ethylbenzene
C
K765
Ethylene
C
L367. L410
bis(2-Ethylhexyl)phthalate
/ C
L508
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
/ (
L367
1,2,3,4,7,8 -Hexachlorodibenzofuran
B
G963, K765
Hexane
C
L410
Hydrochloric acid
C
G963
Manganese
B
L367
Methylene chloride
C
L508
2-Methylphenol
C
K765
Nickel
B
L508
Nitroglycerin
C
L508
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
C
L367, L410
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
C
G963, L367, L508
Propanedinitrile
C
K765
Propanedinitrile, (phenylmethylene)-
C
G963
Styrene
C
K765
2,3,7,8 -T etrachlorodibenzofuran
C
L508
Thallium
B
L508
1,2,4-Trimethylbenzene
C
L367
m-Xylene, p-Xylene
C
K765, L367
6/08
Ordnance Detonation
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TABLE 8 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Zinc
B
G963, K765, L367, L508
Benzaldehyde, 2-chloro-
C
G963, K765
Benzaldehyde, 3-chloro-
C
G963
Benzene, l-chloro-2-methyl-
C
G963, K765
Benzene, l-chloro-3-methyl -
C
K765, G963
1,2-Benzenedicarboxylic acid,
bis(2-methylpropyl)ester
C
G878, L410, L508
1,2-Benzenedicarboxylic acid, butyl 2-me
C
L367, L410, L508
1,2-Benzenediol, 4-( 1,1 -dimethylethyl)-
C
L508
Benzofuran
C
G963
Benzonitrile
C
G963
Bicyclo [4.2.0] octa-1,3,5 -triene
C
G963
n-Butane
C
L367
1-Butene
C
L410
2-Butene
c
L508
2-Butenedinitrile, (E)-
/ C
G963
3-Butenoic acid
¦ ¦ c
K765
3-Buten-2-one
c
G963
o-Chlorobenzalmalononitrile
c
K765
2-Chlorobenzyl cyanide
c
K765
2-Chlorohydrocinnamonitrile
c
G963, K765
Cyclohexadecane
c
K765
1,3,5,7-Cyclooctatetraene
c
G878, G963, L367, L508
Cyclopentene
c
L410
Cyclopropane, 1-propenyl-
c
K765
Disulfide, dimethyl
c
K765
Dodecene, 2-methyl-6-propyl
c
K765
Eicosane, 10-methyl-
c
L508
4-Ethylbenzoic acid
c
L508
2-Furancarboxaldehyde
c
G963
2-Furancarboxaldehyde, 5-(hydroxymethyl)
c
G963
2,5-Furandione, dihydro-3-methyl
c
L508
2,5-Furandione, dihydro-3-methylene
c
G963
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Ordnance Detonation
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TABLE 8 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Furfural
C
L508
Heptacosane
C
G878, K765, L410, L508
Heptacosane, 1-chloro-
c
L508
Heptadecane, 2,6,10,15 -tetramethyl-
c
L508
Hexadecane
c
L410
n-Hexadecanoic acid
c
G963, L508
Hexanedioic acid, bis (2-ethylhexyl) ester
c
G878, G963, K765, L367, L410
Hexatriacontane
c
L508
Isobutane
c
L367
Isobutane
B
L410
5 -Isoquinolinecarbonitrile
C
G963
Magnesium
B
L367, L410
Malononitrile, o-chlorobenzyl-
C
K765
Methanamine, N-methoxy-
C
G878. L367
Methane, nitro-
/ c
G878. L367
10-Methylnonadecane
r C
G878
2-Nitrotoluene
c
L410
4-Nitrotoluene
c
L508
Nonacosane
c
L367, L410
Octacosane
c
K765, L410, L508
Octadecane
c
K765, L508
Oxetanone, 4,4-dimethyl-
c
G878
Oxirane-2,2-dicarbonitrile, 3-
c
K765
(2-chlorophenyl)
Pentadecane
c
L410
Pentadecane, 8-heptyl
c
L367
PETN
c
G963, L508
Phenylethyne
c
G963
Propane
B
L410
Propanenitrile
c
K765
2-Propenamide, 3-(2-chlorophenyl)-2-
c
G963, K765
cyano-
1-Propene, 2-methyl-
c
G878, K765, L410, L508
6/08
Ordnance Detonation
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TABLE 8 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
2-Propenenitrile, 3-(4-chlorophenyl)-
C
K765
1-Propyne
C
G963, L410
Pyrrole
c
K765
1-H-Pyrrole
c
K765
Pyrrolo [ 1,2-a]pyrazine-1,4-dione,
hexahydro
c
K765
3 -Quinolinecarbonitrile
c
G963
Quinoline, 2-chloro-
c
G963
RDX
c
G963, K765, L508
Tetracosane
c
L508
Tetradecane
c
L410
Tetradecanoic acid
c
G963
T etrahydrofuran
c
K765
Tetratetracontane
c
G878, K765. L508
Tetratriacontane
:";C
K765. L410. L508
1,2,3 -Trimethy lbenzene
/'¦c
L508
2,4,6-Trinitrotoluene
c
G878, K765, L508
Tritetracontane
c
G878, L508
4.0 EMISSION FACTOR CALCULATIONS
The methodologies and procedures that were used to develop emission factors from the test data
are described in this section. A similar approach was used to calculate emission factors for TSP, PM-10,
PM-2.5, metals, HC1, Cl2, NH3, SVOC, dioxin/furan compounds, aldehydes and carbonyls, energetic
materials, hydrogen cyanide, and perchlorate. The calculation steps that were performed for each
sampling train and each run are summarized below.
1. For compounds for which more than one test sample was obtained, analytical detection limits
were incorporated into the test data.
2. The background compound concentration was calculated by dividing the mass of compound
detected during the background run by the background run sample volume.
3. The test compound concentration was calculated by dividing the mass of compound detected
during the test run by the test run sample volume.
4. A background-corrected concentration was calculated by subtracting the background
concentration from the test concentration.
5. A dilution-corrected concentration was calculated by dividing the background-corrected
concentration by the dilution correction factor.
18 Ordnance Detonation 6/08
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6. The mass of compound released during the test run was calculated by multiplying the dilution-
corrected concentration by the volume of the Smoke Chamber.
7. Emission factors for each sample and sampling train or test run were calculated by dividing the
mass of compound released by the number of ordnance detonated during the test run or by the
NEW detonated during the test run, as appropriate.
8. Average emission factors were calculated for each compound.
Because concentration data (i.e., parts per million by volume [ppmv] or parts per billion by
volume [ppbv]) were recorded for VOC and CEMS-measured compounds, it was not necessary to
calculate background and test concentrations as described in steps 2 and 3. Detection limits were applied
directly to test compound concentrations of VOC and CEMS-measured compounds, as described in
step 1. As appropriate, ppmv and ppbv values were converted to mg/m3. Emission factors for VOC and
CEMS-measured compounds were then estimated in accordance with steps 4 through 8 described above.
The following sections describe each of the eight emission factor calculation steps listed above in
more detail.
4.1 Incorporation of Analytical Detection-Limits to the Test Data
In many cases, more than one test sample was obtained for a specific compound (i.e., more than
one sample was obtained for a given test run or more than one test run was conducted). When multiple
samples were obtained for the same compound, a comparison was made of all the sample data collected.
Based upon the results of the comparison, the following adjustments were made to the test data:
1. If all of the samples indicated that a compound was "not detected," the sample data were not
adjusted.
2. If all of the samples indicated that a compound was detected, the sample data were not adjusted.
3. If one or more of the samples indicated that a compound was detected and one or more of the
samples indicated that a compound was not detected, the "not detected" values were replaced
with a value equal to one half of the compound's analytical detection limit. The assumption
inherent to this adjustment was that the measured presence of a compound in one or more
samples was indicative of the compound's presence in all samples. The analytical detection
limits for each sample were obtained from the test report.
4.2 Determination of Background Concentration
For TSP, PM-10, PM-2.5, metals, HC1, Cl2, NH3, SVOC, dioxin/furan compounds, aldehydes and
carbonyls, energetic materials, hydrogen cyanide, and perchlorate compounds, the background compound
concentration (BC) was calculated by dividing the mass of compound detected during the background run
(Bkgd mass) by the background run sample volume (Bkgd V). This calculation is illustrated by the
following equation:
Bkgd mass
BC =
Bkgd V
For VOC compounds, the background run data were used directly. Background data for CEMS-
measured compounds were recorded for each test run between the time the CEMS began sampling and
the time of detonation. The background concentrations were assumed to equal representative values over
the sampling period.
6/08
Ordnance Detonation
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4.3 Determination of Test Compound Concentration
For TSP, PM-10, PM-2.5, metals, HC1, Cl2, NH3, SVOC, dioxin/furan compounds, aldehydes and
carbonyls, energetic materials, hydrogen cyanide, and perchlorate compounds, the test compound
concentration (TC) was calculated by dividing the mass of compound measured during the test run (Test
mass) by the test run sample volume (Test V). This calculation is illustrated by the following equation:
_ Test mass
TC =
TestV
For VOC compounds, the test run data were used directly. For CEMS-measured compounds, the
test compound concentration was determined as the arithmetic mean of the test data collected from the
initial steady-state point until the end of the test.
4.4 Determination of Background-Corrected Concentration
For all compounds, the calculation of the background-corrected concentration (BCC) was
dependent on whether the background (BC) and test (TC) concentrations were detected and whether they
were less than, equal to, or greater than one another. The procedures used to calculate the background-
corrected concentration for each sampling train and compound are described below and are displayed
graphically in Figure 1.
1. If the test concentration was not detected (ND), the background-corrected concentration equaled
ND.
2. If the test concentration was detected and the background concentration was not detected, the
background-corrected concentration equaled the test concentration.
3. If the test and background concentrations w ere detected and the test concentration was less than
or equal to the background concentration, the background-corrected concentration equaled 0.
4. If the test and background concentrations were detected and the test concentration was greater
than the background concentration, the background concentration was subtracted from the test
concentration. This calculation is illustrated by the following equation:
BCC =TC-BC
4.5 Determination of Dilution-Corrected Concentration
The dilution-corrected concentration (DCC) was calculated by dividing the background-corrected
concentration by the applicable dilution correction factor (DCF). This calculation is illustrated by the
following equation:
DCC
DCF
4.6 Determination of Mass of Compound Released
The mass of compound released was calculated by multiplying the dilution-corrected
concentration by the volume of the Smoke Chamber. This calculation is illustrated by the following
equation:
Mass compound released = DCC x Smoke Chamber volume
20
Ordnance Detonation
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No
Was TC Detected?
Yes
No
Was BC Detected?
Yes
No
Was TC > BC?
Yes
BCC = ND
BCC = TC
BCC = 0
BCC = TC - BC
TC = Test Concentration
BC = Background Concentration
ND = Not Detected
BCC = Background-Corrected
Concentration
Figure 1 Calculation of background-corrected concentration (BCC).
6/08 Ordnance Detonation 21
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4.7 Determination of Emission Factors
Once the mass of compound released was calculated, two emission factors were developed for
each sample or sampling train and for each test run: the mass of compound released per item (i.e., per
single ordnance) and the mass of compound released per pound NEW. The NEW for all ordnance were
determined from References 1 and 4. Because DODICs K765 and L508 do not have a defined NEW, the
emission factors were only developed on a "per item" basis for these two items.
4.8 Determination of Average Emission Factors
Steps 1 through 7, as described in Sections 4.1 through 4.7, are applicable to individual samples
or sampling trains within individual test runs. The final step in the emission factor calculation process
was to calculate average emission factors for each compound in terms of mass released per item and mass
released per pound NEW. The average emission factors for each compound were calculated as the
arithmetic mean of the individual samples associated with the compound. If all samples indicated that the
compound was not detected (ND), then the average emission factor was assigned a value of ND. [Note:
The minimum detection levels associated with the compounds that were not detected are presented in
Appendix A.] Total dioxin/furan emission factors were calculated by summing the average emission
factors for all dioxin/furan compounds.
5.0 EMISSION FACTOR RATINGS
The emission factors were appraised in accordance with the rating system specified in
Reference 5. Under this rating system, emission factors are assigned a rating from A to E, where an "A"
rating is assigned to the highest quality factors. The criteria used to assign a specific emission factor
rating are summarized below.
A Excellent. The emission factor was developed primarily from A- and B-rated source test data
taken from many randomly chosen facilities in the industry population. The source category
population was sufficiently specific to minimize variability.
B Above average. The emission factor was developed primarily from A- or B-rated test data from a
moderate number of facilities. Although no specific bias was evident, it was not clear if the
facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
C Average. The emission factor was developed primarily from A-, B- and/or C-rated test data from
a reasonable number of facilities. Although no specific bias was evident, it was not clear if the
facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
D Below average. The emission factor was developed primarily from A-, B-, and C-rated test data
from a small number of facilities, and there may have been reason to suspect that these facilities
did not represent a random sample of the industry. There also may have been evidence of
variability within the source category population.
E Poor. The emission factor was developed from C- and D-rated test data from a very limited
number of facilities, and there may have been reason to suspect that the facilities tested did not
represent a random sample of the industry. There also may have been evidence of variability
within the source category population.
Two analyses were conducted to assign ratings to the ordnance emission factors. First, an
analysis was conducted on an ordnance-specific basis. Second, an analysis was conducted using all
22
Ordnance Detonation
6/08
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available ordnance emission factor data. The second analysis was conducted to determine whether a
sufficient correlation existed between emission factors for different but similar ordnance to allow the
number of test data points to be increased to the point that higher emission factor ratings could be
assigned than were possible when using the ordnance-specific approach. Both analyses are described
below.
5.1 Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data
As previously described, emission factor ratings are dependent upon the test data quality, the
number of test data points, the amount of variability present within a source category population, and the
randomness of the source category sample. The following test data facts pertain to these rating criteria:
1. As described in Section 3 of this Background Document, the ordnance test data was primarily
rated A or B. The test data for a few compounds was rated C.
2. Two tests were conducted or two sampling trains were used per ordnance.
3. Ordnance are manufactured to very tight tolerance levels so there is little variability within a
specific type of ordnance.
4. There was no evidence that suggested the tested items within each type of ordnance were
specially selected.
Emission factor ratings were assigned based upon these facts. The rationale used to accept or
reject specific emission factor ratings follow.
A: Rejected. The number of test data points w as deemed to be insufficient to assign an A emission
factor rating.
B: Rejected. The number of test data points was deemed to be insufficient to assign a B emission
factor rating.
C: Accepted for most ordnance. The emission factors were developed using A- and B-rated test
data, there is little variability among items, and there was no evidence that suggested the tested
items were specially selected. Because of the limited number of data points, a C rating was
deemed appropriate for this set of circumstances.
D: Accepted for some ordnance. The emission factors were developed using C-rated test data, there
is little variability among items, and there was no evidence that suggested the tested items were
specially selected. Because of the limited number of data points, a D rating was deemed
appropriate for this set of circumstances.
E: Rejected. The ordnance described in this report were developed primarily using A- and B-rated
test data rather than C- or D-rated data, there is little variability among items, and there was no
evidence that suggested the tested items were specially selected. Therefore, an E emission factor
rating was deemed inappropriate.
5.2 Emission Factor Ratings Assigned - Based on All Available Test Data
The proceeding sections of this Background Document concern the emission measurement
methods, data analysis, and calculations used to develop emission factors for specific ordnance.
However, USAEC's ordnance emission factor development program includes more than 200 ordnance
that have been tested under more than 25 separate test series. Because many of these ordnance are similar
in size and/or chemical composition, a statistical analysis was conducted to assess the similarity of the
emission factors developed for similar ordnance. The results of this analysis were used to reevaluate the
emission factor ratings assigned on an ordnance-specific basis.
6/08
Ordnance Detonation
23
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USAEC characterized individual ordnance as falling into one of 17 separate categories,
depending upon the size and/or chemical composition of the ordnance. The ordnance and their respective
categories are identified in Table 9 along with a comment field describing the number of data points.
Within each of the 17 ordnance categories identified by USAEC, emission factors for each
compound were compared. To allow the comparison of emission factors for ordnance with similar
constituents but significant differences in net explosive weight, the comparison was made using the
normalized emission factor units of mass of compound released per pound NEW. Based upon
information provided by EPA,9 the following procedures were used to assess the data correlation:
1. The relative standard deviation, defined as the standard deviation divided by the mean, was
calculated for each compound within each ordnance category.
2. If the relative standard deviation was less than 1.0, the evaluated emission factors were
considered to demonstrate good correlation. As such, the rating for these emission factors could
be elevated to a maximum of an A, depending on the number of data points within the evaluated
ordnance category.
3. If the relative standard deviation was between 1.0 and 2.0, the evaluated emission factors were
considered to demonstrate fair correlation. As such, the rating for these emission factors could be
elevated to a maximum of a B, depending on the number of data points within the evaluated
ordnance category.
4. If the relative standard deviation was greater than 2.0, the evaluated emission factors were
considered to demonstrate poor correlation. As such, the emission factor rating could not be
elevated, regardless of the amount of data available.
A poor correlation between emission factors was not necessarily construed as being indicative of poor test
data. Rather, a poor correlation was more likely to indicate that the ordnance included in the category
were not as similar in nature as anticipated by USAEC when the ordnance categories were defined.
In addition to assessing the data correlation, an assessment was made of the number of test data
points available within each of the 17 ordnance categories. Because each ordnance test consisted of two
test data points (i.e., two test runs per ordnance or two independent sampling trains were used during an
ordnance test), the number of test data points available in each of the ordnance categories varied from 2 to
68. Based upon information provided by EPA,9 the following assumptions were used to assess whether
sufficient category-specific test data points were available to justify elevating the emission factor ratings
based on ordnance-specific data only:
1. If 20 or more data points were available, the emission factor rating could be elevated to a
maximum of an A, provided that the data also demonstrated a good correlation.
2. If at least 10 but less than 20 data points were available, the emission factor rating could be
elevated to a maximum of a B, provided that the data also demonstrated a good correlation.
3. If less than 10 data points were available, the emission factor rating could not be elevated,
regardless of the data correlation.
4. If the data demonstrated a fair correlation and 20 or more data points were available, the emission
factor rating could be elevated to a maximum of a B.
5. If the data demonstrated a fair correlation and at least 10 but less than 20 data points were
available, the emission factor rating could be elevated to a maximum of a C.
24 Ordnance Detonation 6/08
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TABLE 9 ORDNANCE CATEGORIZATION FOR EMISSION FACTOR
CORRELATION ASSESSMENT
Category
DODIC
Ordnance Description
Test Series
Comment
CS
G963
M7A3 CS Riot Control Agent Hand
Grenade
DPG VI
<10 data points
K765
CS Riot Control Agent Capsule
DPG VI
G900
TH3 AN-M14 Incendiary Grenade
EO 5
G911
MK3A2 Offensive Hand Grenade
EO 2
G911
MK3A2 Offensive Hand Grenade
EO 6
K010
M4 Field Incendiary Burster
EO 5
K145
M18A1 Antipersonnel Mine
EO 2
M023
Ml 12 Demolition Block Charge
EO 1
M030
1/4-Pound Demolition Block Charge
EO 1
M030
1/4-Pound Demolition Block Charge
EO 3
M031
1/2-Pound Demolition Block Charge
DPG IV-A
M032
1-Pound Demolition Block Charge
EO 2
M032
1 -Pound Demolition Block Charge
EO 3
M130
M6 Electric Blasting Cap
EO 7
M131
M7 Non-Electric Blasting Cap
EO 7
M241
M10 High Explosive Universal Destructor
DPG IV-B
Demolition
M456
M500a
PETN Type 1 Detonating Cord
M21 Cartridge Actuated Cutter
DPG IV-A
EO 10
20+ data points
M591
Ml Military Dynamite Demolition Block
Charge
EO 1
M913
M58A3 Linear Demolition Charge
EO 3
ML05a
MK24 Powder Actuated Cutter
EO 11
ML09
Linear Demolition Charge, Shaped 20 gr/ft
DPG IV-A
ML15
Linear Demolition Charge, Shaped
225 gr/ft
DPG IV-A
ML47
Mil Non-Electric Blasting Cap with
30-foot Shock Tube
EO 7
MM50a
M221 Clipped Shaped Demolition Charge
EO 11
MN02
Mil Non-Electric Blasting Cap with
500-foot Shock Tube
EO 7
MN03
Mil Non-Electric Blasting Cap with
1,000-foot Shock Tube
EO 7
MN06
M14 Non-Electric Time Delay Blasting
Cap
EO 7
6/08
Ordnance Detonation
25
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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment
MN06
M14 Non-Electric Time Delay Blasting
Cap
EO 7
MN07a
M15 Non-Electric Time Delay Blasting
Cap
M81 Time Blasting Fuse Igniter
EO 11
Demolition,
continued
MN08
EO 9
20+ data points
MN68a
M151 Booster Demolition Charge
DPG VIII
None
PAX-11, Granular Powder Burn
EO 4
None
PAX-11, Molded Pellet Detonation
EO 4
G878
M228 Practice Hand Grenade Fuse
DPG VI
K051
M604 Anti-Tank Practice Mine Fuse
EO 6
N278a
M564 Mechanical Time and Super Quick
(MTSQ) Fuse
EO 11
Fuse
N285
M577A1 Mechanical Time and Super
Quick (MTSQ) Fuse
EO 9
10+ data points
N286
M582 Mechanical Time and Super Quick
(MTSQ) Fuse
EO 7
N335
M557 Point Detonating Fuse
EO 5
N340
M739A1 Point Detonating Fuse
EO 5
N464
M732 Proximity Fuse
EO 9
G881
M67 Fragmentation Grenade
EO 1
Grenade
G978
G982
M82 Smoke Simulant Screening Grenade
Launcher
M83 Terephthalic Acid (TA) Smoke
Practice Hand Grenade
DPG V-B
DPG V-A
<10 data points
GG09a
M84 Non-Lethal Stun Hand Grenade
EO 12
B535
M583A1 40-mm White Star Parachute
DPG I V-B
Cartridge
B536
M585 40-mm White Star Cluster Cartridge
DPG I V-B
B627
M83A3 60-mm Illuminating Cartridge
(projectile only)
DPG V-B
Illumination
D505
M485A2 155-mm Illumination Round
(projectile only)
DPG I
20+ data points
L305
Ml95 Green Star Parachute Signal Flare
DPG I
L306
M158 Red Star Cluster Signal Illumination
DPG II
L307
Ml59 White Star Cluster Signal
Illumination
DPG II
26
Ordnance Detonation
6/08
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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment
L311
M126A1 Red Star Parachute Signal Flare
DPGII
L312
M127A1 White Star Parachute Signal Flare
DPGI
Illumination,
continued
L314
L367
M125A1 Green Star Cluster Signal Flare
M22 Anti-Tank Guided Missile and Rocket
Launching Simulator
DPG I
DPG VI
20+ data points
L410
M206 Aircraft Countermeasure Flare
DPG VI
Inert
HAlla
Rocket, 2.75-inch Flechette with M255A1
Warhead
Unclear
Data not yet
available
C511
M490 105-mm Target Practice Tracer
Cartridge (Ml3 tracer only)
EO 6
Large
C784a
M831 120-mm Target Practice Tracer
Cartridge
EO 12
Only 1 data point
yet available
C785a
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge
EO 12
Medium
BAir
BA15a
Ml001 40-mm HVCC Cartridge
M769 60-mm Full Range Practice
Cartridge
EO 12
EO 12
Data not yet
available
A652
M220 20-mm Target Practice Tracer
Cartridge
FP 9
A940
M910 25-mm Target Practice Discarding
Sabot Tracer Cartridge
FP 8
Medium-FP
A976
M793 25-mm Target Practice Tracer
Cartridge
FP 8
10+ data points
B505a
M662 40-mm Red Star Parachute Cartridge
DPG VIII
B519
M781 40-mm Practice Cartridge
FP 2
B584
M918 40-mm Practice Cartridge
FP 2
Mine
K042a
M88 Volcano Practice Canister Mine
DPG VIII
Data not yet
available
Mortar
CA03
XM929 120-mm White Phosphorus Smoke
Cartridge (projectile only)
DPG V-B
Only 1 data point
B129
M789 30-mm High Explosive Dual
Purpose (HEDP) Cartridge (projectile only)
EO 9
Projectile
B542
M430 40-mm High Explosive Dual
Purpose (HEDP) Cartridge (projectile only)
EO 3
10+ data points
B571
M383 40-mm High Explosive Cartridge
(projectile only)
EO 3
6/08
Ordnance Detonation
27
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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment
B632
M49A4 60-mm High Explosive Cartridge
(projectile only)
EO 3
B642
M720 60-mm High Explosive Cartridge
(projectile only)
EO 6
B643a
M888 60-mm High Explosive Cartridge
(projectile only)
EO 11
Projectile,
continued
C995
H557
M136 AT4 Recoilless Rifle, 84-mm
Cartridge (projectile only)
M72A3 66-mm High Explosive Antitank
Rocket (projectile only)
EO 3
EO 1
10+ data points
H708a
M73 3 5-mm Subcaliber Practice Rocket
DPG VIII
None
M720 60-mm Mortar HE Cartridge with
PAX-21 Charge (projectile only)
EO 8
PJ02
FIM-92A Stinger-Basic Guided Missile
(projectile only)
EO 6
B627
M83A3 60-mm Illuminating Cartridge
(propelling charge only)
FP 10
B642
M720 60-mm High Explosive Cartridge
(propelling charge only)
FP 4
B645
M766 60-mm Short Range Practice Mortar
Cartridge (propelling charge only)
FP 10
C226
M301A3 81-mm Illuminating Cartridge
(propelling charge only)
FP 4
C379
M934 120-mm High Explosive Cartridge
(Zone 1 - propelling charge only)
FP 8
Propellant
C511
M490 105-mm Target Practice Tracer
Cartridge (propelling charge only)
FP 5
20+ data points
C784
M831 120-mm Target Practice Tracer
Cartridge (propelling charge only)
FP 5
C785
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge (propelling charge
only)
FP 5
C868
M821 81-mm High Explosive Cartridge
(propelling charge only)
FP 4
C876
M880 81-mm Target Practice Short Range
Cartridge (propelling charge only)
FP 4
CA09
M931 120-mm Full Range Practice
Cartridge (Zone 1 - propelling charge only)
FP 8
28
Ordnance Detonation
6/08
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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment
CA09
M931 120-mm Full Range Practice
FP 8
Cartridge (Zone 4 - propelling charge)
D533
M119A2 155-mm Propelling Charge
(Zone 7)
FP 5
D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP 1
D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP 5
D540
M3 155-mm Propelling Charge (Zone 3,
M284 Cannon)
FP 1
D540
M3 155-mm Propelling Charge (Zone 5,
Ml99 Cannon)
FP 1
Propellant,
continued
D540
M3A1 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP 1
20+ data points
D540
M3A1 155-mm Propelling Charge (Zone 3,
M284 Cannon)
FP 1
D541
M4A2 155-mm Propelling Charge (Zone 7)
FP 5
M174a
.50 Caliber Blank Cartridge (Electrically
Initiated)
EO 10
M842a
Ml Squib
Unclear
MD73a
M796 Impulse Cartridge
EO 11
MN60a
M79 Electric Match Igniter
EO 9
PJ02
FIM-92A Stinger-Basic Guided Missile
(launch motor)
EO 5
PJ02
FIM-92A Stinger-Basic Guided Missile
(flight motor)
FP 7
H975a
Rocket, 2.75-inch M274 Signature Smoke
with H872 Warhead
Unclear
L366
M74A1 Projectile Air Burst Simulator
DPGIV-B
L495
M49A1 Surface Trip Flare
DPGII
Pyrotechnic
L508
L592
M72 Red Railroad Warning Fusee
TOW Blast Simulator
DPG VI
DPG V-A
20+ data points
L594
M115A2 Ground Burst Simulator
DPG I
L595a
M9 Liquid Projectile Air Burst Simulator
EO 12
L596
Ml 10 Flash Artillery Simulator
DPG I
L598
Ml 17 Flash Booby Trap Simulator
DPG I
6/08
Ordnance Detonation
29
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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment
L599
Ml 18 Illuminating Booby Trap Simulator
DPGII
L600
Ml 19 Whistling Booby Trap Simulator
DPGII
L601
M116A1 Hand Grenade Simulator
DPG I
L602
M21 Artillery Flash Simulator
DPG IV-B
L709
M25 Target Hit Simulator
EO 2
L709
XM25 Target Hit Simulator
DPG V-B
L720
M26 Target Kill Simulator
EO 6
M327a
Firing Device Coupling Base
EO 11
Pyrotechnic,
continued
M448a
M2A1 8-second Delay Percussion
Detonator
EO 10
20+ data points
M626
Ml Pressure Type Demolition Firing
Device
EO 9
M627a
M5 Pressure Release Igniter
Unclear
M630
Ml Pull Type Demolition Firing Device
DPG V-A
M630
Ml Pull Type Demolition Firing Device
EO 9
M670a
M700 Time Blasting Fuse
EO 11
M766
M60 Time Blasting Fuse Igniter
EO 9
ML03a
M142 Multipurpose Demolition Firing
Device
EO 10
H459
Rocket, 2.75-inch Flechette, MK40 Mod 3
FP 7
Motor (propelling rocket only)
H557
M72A3 66-mm High Explosive Antitank
Rocket (propelling rocket only)
FP 4
Rocket/Missile
H557
M72A3 66-mm High Explosive Antitank
Rocket (propelling rocket only)
FP 7
10+ data points
H708
M73 35-mm Subcaliber Practice Rocket
FP 9
(motor only)
Rocket, 2.75-inch M267 Practice Warhead,
H974
MK66 Mod 3 Motor (propelling rocket
only)
FP 7
A010
M220 10 Gage Blank/Subcaliber Salute
Cartridge
FP 9
Small Arm-FP
AO 11
A017
12 Gage #00 Shot Cartridge
12 Gage #9 Shot Cartridge
FP 9
FP 10
20+ data points
A059
M855 5.56-mm Ball Cartridge (fired from
the M16A1 Rifle)
FP 3
30
Ordnance Detonation
6/08
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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment
A059
M855 5.56-mm Ball Cartridge (fired from
the M16A2 Rifle)
FP 3
A059
M855 5.56-mm Ball Cartridge (No-Lead)
FP 4
A063
M856 5.56-mm Tracer Cartridge
FP 3
A065
M862 5.56-mm Practice Ball Cartridge
FP 3
A066
M193 5.56-mm Ball Cartridge
FP 6
A068
M196 5.56-mm Tracer Cartridge
FP 6
A080
M200 5.56-mm Blank Cartridge
FP 3
A086
.22 Caliber Long Rifle Ball Cartridge
FP 4
A106
.22 Caliber Standard Velocity Long Rifle
Ball Cartridge
FP 4
Alll
M82 7.62-mm Blank Cartridge
FP 3
A131
M62 7.62-mm Tracer Cartridge
FP 6
A136
Ml 18 7.62-mm Ball Match Cartridge
FP 6
A143
M80 7.62-mm Ball Cartridge
FP 3
A171
M852 7.62-mm Ball Match Cartridge
FP 6
Small Arm-FP,
continued
A182
A212
Ml .30 Caliber Ball Cartridge
M2 .30 Caliber Ball Cartridge
FP 6
FP 6
20+ data points
A218
M25 .30 Caliber Tracer Cartridge
FP 9
A247
M72 .30 Caliber Ball Match Cartridge
FP 6
A363
M882 9-mm Ball Cartridge
FP 3
A365
M181A1 14.5-mm Artillery Training
Cartridge
DPG V-A
A366a
M182 14.5-mm Cartridge
Unclear
A400
M41 .38 Caliber Special Ball Cartridge
FP 9
A403
.38 Caliber Special Blank Cartridge
FP 9
A475
M1911 .45 Caliber Ball Cartridge
FP 3
A518
M903 .50 Caliber SLAP Cartridge
FP 9
A518
M962 .50 Caliber SLAP-T Cartridge
FP 10
A525
M2 .50 Caliber Armor Piercing Cartridge
FP 8
A557
M17 .50 Caliber Tracer Cartridge
FP 3
A557
M33 .50 Caliber Ball Cartridge
FP 3
A598
M1A1 .50 Caliber Blank Cartridge
FP 3
6/08
Ordnance Detonation
31
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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment
C870
M819 81-mm Red Phosphorus Smoke
Cartridge
DPG VII
G815
L8A3 Red Phosphorus Smoke Screening
Grenade Launcher (UK)
DPG VII
G930
AN-M8 Hexachloroethane (HC) Smoke
Hand Grenade
DPG V-A
G940
M18 Green Smoke Hand Grenade
DPG III
Smoke
G945
G950
M18 Yellow Smoke Hand Grenade
M18 Red Smoke Hand Grenade
DPG III
DPG III
20+ data points
G950
Ml8 Red Smoke Hand Grenade (new
formulation)
DPG V-A
G955
M18 Violet Smoke Hand Grenade
DPG III
G955
Ml8 Violet Smoke Hand Grenade (new
formulation)
DPG V-A
K866
ABC-M5 30-pound HC Smoke Pot
DPG VII
K867
M4A2 Floating Tvpe HC Smoke Pot
DPG VII
a Although testing may have been completed, emission factors for this ordnance have not yet been
analyzed for inclusion in AP-42: therefore, these data were not included in the data correlation.
Using the criteria specified above, the emission factor ratings assigned to ordnance in each of the
17 ordnance categories were reevaluated. This evaluation indicated that some of the emission factor
ratings associated with ordnance included in ten categories could be elevated from a C or D rating to an A
or B rating. These ten categories are:
1.
Demolition
2.
Fuse
3.
Illumination
4.
Medium - Firing Point
5.
Projectile
6.
Propellant
7.
Pyrotechnic
8.
Rocket/Missile
9.
Small Arm - Firing Point
10.
Smoke
A final assessment was made as to the emission factor rating assigned based on ordnance-specific
test data only. If the original emission factor data rating assigned was a C, then the emission factor rating
was elevated to an A or B, as appropriate, based upon the data for the whole ordnance category. If the
original emission factor data rating assigned was a D, then the emission factor rating was elevated to a B
or C, as appropriate, based upon the data for the whole ordnance category. The analysis is documented in
an Excel spreadsheet that is located on the EPA website at: http://www.epa.gov/ttn/chief/ap42/index.html.
32
Ordnance Detonation
6/08
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Within the current test series, DODIC G878 was included in the Fuse category, which includes
more than 10 test data points. As a result, some emission factor ratings associated with this ordnance
were elevated. DODICs L367 and L410 were included in the Illumination category, and DODIC L508
was included in the Pyrotechnic category. Both of these categories include more than 20 data points. As
a result, some emission factor ratings associated with these three ordnances were aslso elevated.
DODICs G963 and K765 were included in the CS category, which includes less than 10 test data points.
As a result, none of the emission factor ratings associated with these ordnance were elevated. The
emission factor ratings assigned are presented in Appendix A.
6.0 REFERENCES
1. Sampling Results for AEC Phase VI Emission Characterization of Exploding Ordnance and
Smoke/Pyrotechnics, URS Group, Inc., Oak Ridge, TN, April 2006.
2. Detailed Test Plan for Phase VI Emission Characterization of Exploding Ordnance and
Smoke/Pyrotechnics, West Desert Test Center, U.S. Army Dugway Proving Ground, UT, June
2004.
3. Supporting information including Excel spreadsheets supplied upon request by the U.S. Army
Dugway Proving Ground test support contractor, URS Group, Inc., Oak Ridge, TN, February
2007.
4. Munitions Items Disposition Action System (MIDAS) website, https://midas.dac.armv.mil/. U.S.
Army Defense Ammunition Center. McAlester. OK. December 2007.
5. Procedures for Preparing Emission Factor Documents, EPA-454/R-95-015, U.S. Environmental
Protection Agency, Research Triangle Park, NC, November 1997.
6. Draft Detailed Procedures for Preparing Emission Factors, U.S. Environmental Protection
Agency, Research Triangle Park, NC, June 2006.
7. Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air,
Second Supplement, EPA/600/4-89/017, U.S. Environmental Protection Agency, Research
Triangle Park, NC, June 1988.
8. Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S.
Environmental Protection Agency, http://www.epa.gov/epaoswer/hazwaste/test/sw846.htm.
9. Information regarding the relationship between emission factor data correlation, the number of
data points available, and the resulting emission factor rating assigned supplied upon request by
Mr. Ron Myers, Measurement Policy Group, Office of Air Quality Planning and Standards, U.S.
Environmental Protection Agency, Research Triangle Park, NC, June 2006.
6/08
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34
Ordnance Detonation
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APPENDIX A
COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR ORDNANCE
INCLUDED IN PHASE VI TESTING AT DUGWAY PROVING GROUND, UTAH
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A-2 Ordnance Detonation 6/08
-------
TABLE A1 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC G878, M228 PRACTICE HAND GRENADE FUSE
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxidef
1.7 E-04
3.8 E-02
--
630-08-0
Carbon monoxide
1.1 E-05
2.4 E-03
--
~
Oxides of nitrogenf
4.0 E-05
8.7 E-03
--
~
PM-2.5f
9.4 E-05
2.0 E-02
--
--
PM-10f
1.1 E-04
2.3 E-02
--
7446-09-5
Sulfur dioxide
1.1 E-05
2.3 E-03
--
~
Total nonmethane hydrocarbons
3.2E-07
6.9 E-05
--
12789-66-1
Total suspended particulatef
1.2 E-04
2.6 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.4 E-03
208-96-8
Acenaphthylene
ND
ND
1.4 E-03
75-05-8
Acetonitrile
ND
ND
1.9 E-02
98-86-2
Acetophenone
ND ,
ND
6.5 E-03
53-96-3
2-Acetylam i nofl uorene
^ ND
ND
1.4 E-03
107-02-8
Acrolein
3.0 E-08
6.4 E-06
--
107-13-1
Acrylonitrile
ND
ND
9.9 E-03
107-05-1
Allyl chloride
ND
ND
1.4 E-02
92-67-1
4-Aminobiphenyl
ND
ND
2.7 E-02
7664-41-7
Ammonia
3.5 E-07
7.6 E-05
--
62-53-3
Aniline
ND
ND
2.0 E-02
120-12-7
Anthracene
ND
ND
1.4 E-03
7440-39-3
Barium
5.2 E-06
1.1 E-03
--
71-43-2
Benzene
4.6 E-08
9.9 E-06
--
92-87-5
Benzidine
ND
ND
1.4E-01
56-55-3
Benzo [a] anthracene
ND
ND
1.6 E-03
205-99-2
Benzo [b] fluoranthene
ND
ND
3.0 E-03
207-08-9
Benzo [k] fluoranthene
ND
ND
1.7 E-03
191-24-2
Benzo [g,h,i]perylene
ND
ND
4.3 E-03
50-32-8
Benzo [a]pyrene
ND
ND
1.4 E-03
100-44-7
Benzyl chloride
ND
ND
5.8 E-03
7440-41-7
Beryllium
ND
ND
2.7 E-04
75-25-2
Bromoform
ND
ND
1.2 E-02
6/08
Ordnance Detonation
A-3
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
4.3 E-03
101-55-3
4-Bromophenylphenylether
ND
ND
1.4 E-03
106-99-0
1,3-Butadiene
ND
ND
2.5 E-03
71-36-3
n-Butanol
ND
ND
1.4 E-02
123-72-8
Butyraldehyde
ND
ND
1.3 E-02
86-74-8
Carbazole
ND
ND
1.7 E-03
75-15-0
Carbon disulfide
2.7 E-08
5.9 E-06
--
56-23-5
Carbon tetrachloride
ND
ND
7.0 E-03
7782-50-5
Chlorine8
6.1 E-07
1.3 E-04
--
106-47-8
4-Chloroaniline
ND
ND
1.6 E-02
108-90-7
Chlorobenzene
ND
ND
5.2 E-03
75-00-3
Chloroethane
ND
ND
3.0 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.4 E-03
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.5 E-03
67-66-3
Chloroform
ND
ND
5.4 E-03
108-60-1
bis(2-Chloroisopropvl)ether
ND ¦¦¦'
ND
2.1 E-03
74-87-3
Chloromethane
ND
ND
9.5 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.4 E-03
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.4 E-03
7440-47-3
Chromium
2.1 E-06
4.6 E-04
--
218-01-9
Chrysene
ND
ND
1.7 E-03
7440-48-4
Cobalt
ND
ND
1.5 E-03
4170-30-3
Crotonaldehyde
ND
ND
6.3 E-02
98-82-8
Cumene
ND
ND
5.5 E-03
110-82-7
Cyclohexane
ND
ND
3.8 E-03
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.6 E-03
132-64-9
Dibenzofuran
ND
ND
1.4 E-03
106-93-4
1,2-Dibromoethane
ND
ND
8.6 E-03
84-74-2
Dibutylphthalate
ND
ND
2.7 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.7 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.7 E-03
106-46-7
1,4-Dichlorobenzene
ND
ND
6.7 E-03
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
2.0 E-02
75-27-4
Dichlororobromomethane
ND
ND
7.5 E-03
75-71-8
Dichlorodifluoromethane
ND
ND
5.5 E-03
A-4
Ordnance Detonation
6/08
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
75-34-3
1,1 -Dichloroethane
ND
ND
4.5 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.5 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.4 E-03
78-87-5
1,2-Dichloropropane
ND
ND
5.2 E-03
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
5.1 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.8 E-03
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.4 E-03
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.4 E-03
119-93-7
3,3 '-Dimethylbenzidine
ND
ND
1.4E-01
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.4 E-03
99-65-0
1,3 -Dinitrobenzene
ND
ND
1.5 E-03
534-52-1
4,6-Dinitro-o-cresol
ND
ND
2.4 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
5.9 E-02
121-14-2
2,4-Dinitrotolucnc
ND
ND
1.4 E-03
606-20-2
2,6-Dinitrotolucnc
ND ¦¦¦'
ND
4.2 E-04
88-85-7
Dinoseb
ND
ND
2.7 E-03
123-91-1
1,4-Dioxane
ND
ND
1.6 E-02
--
Total dioxin/furan compounds
3.1 E-13
6.8E-11
--
122-39-4
Diphenylamine
ND
ND
1.4 E-03
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.4 E-03
100-41-4
Ethylbenzene
ND
ND
4.9 E-03
74-85-1
Ethylene
4.8 E-08
1.0E-05
--
117-81-7
bis(2-Ethylhexyl)phthalate
1.9E-08
4.2 E-06
~
206-44-0
Fluoranthene
ND
ND
1.5 E-03
86-73-7
Fluorene
ND
ND
1.4 E-03
50-00-0
Formaldehyde
1.2E-07
2.6 E-05
--
76-13-1
Freon 113
ND
ND
8.6 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
5.4 E-14
1.2 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
1.7 E-08
118-74-1
Hexachlorobenzene
ND
ND
1.4 E-03
87-68-3
Hexachlorobutadiene
ND
ND
4.9 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.7 E-02
6/08
Ordnance Detonation
A-5
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
1.0 E-08
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
1.0 E-08
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
1.0 E-08
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
ND
ND
6.7 E-09
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
6.7 E-09
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
1.0 E-08
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
6.7 E-09
67-72-1
Hexachloroethane
ND
ND
1.5 E-03
110-54-3
Hexane
ND
ND
3.9 E-03
7647-01-0
Hydrochloric acid
ND
ND
1.1 E-01
74-90-8
Hydrogen cyanide
ND
ND
7.3 E-02
193-39-5
Indeno [ 1,2.3 -cdjpv rene
ND
ND
1.5 E-03
78-59-1
Isophorone
ND
ND
1.4 E-03
67-63-0
Isopropyl alcohol
/. ND
ND
1.1 E-02
120-58-1
Isosafrole
• ; ND
ND
1.4 E-03
7439-97-6
Mercury
ND
ND
4.2 E-04
126-98-7
Methacrylonitrile
ND
ND
1.3 E-02
96-33-3
Methyl acrylate
ND
ND
1.6 E-02
56-49-5
3 -Methy lcholanthrene
ND
ND
1.4 E-03
75-09-2
Methylene chloride
4.6 E-08
1.0E-05
--
108-10-1
Methyl isobutyl ketone
ND
ND
4.6 E-03
80-62-6
Methyl methacrylate
ND
ND
1.9 E-02
91-57-6
2-Methylnaphthalene
ND
ND
1.4 E-03
95-48-7
2-Methylphenol
ND
ND
8.1 E-03
1634-04-4
Methyl tert-butyl ether
ND
ND
4.0 E-03
91-20-3
Naphthalene
ND
ND
2.4 E-02
134-32-7
1 -Naphthylamine
ND
ND
2.7 E-02
91-59-8
2-Naphthylamine
ND
ND
2.7 E-02
7440-02-0
Nickel
7.0 E-07
1.5 E-04
--
100-01-6
4-Nitroaniline
ND
ND
5.4 E-03
98-95-3
Nitrobenzene
ND
ND
1.0 E-03
55-63-0
Nitroglycerin
ND
ND
8.8 E-04
88-75-5
2-Nitrophenol
ND
ND
1.4 E-03
A-6
Ordnance Detonation
6/08
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
100-02-7
4-Nitrophenol
ND
ND
8.9 E-03
79-46-9
2-Nitropropane
ND
ND
1.7E-02
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.4 E-03
55-18-5
N-Nitrosodiethylamine
ND
ND
1.4 E-03
62-75-9
N-Nitrosodimethylamine
ND
ND
1.4 E-03
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.4 E-03
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.4 E-03
59-89-2
N-Nitrosomorpholine
ND
ND
1.4 E-03
100-75-4
N-Nitrosopiperidine
ND
ND
1.4 E-03
99-55-8
5 -Nitro-o-toluidine
ND
ND
2.2 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
2.0 E-13
4.3 E-ll
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
6.1 E-14
1.3 E-ll
--
608-93-5
Pentachlorobcnzcne
ND
ND
1.4 E-03
40321-76-4
1,2,3,7,8-Pcntachlorodibcnzo-p-
dioxin
ND,,,
ND
6.7 E-09
57117-41-6
1,2,3,7,8-Pcntachlorodibenzofuran
: ND
ND
3.3 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
5.4 E-09
76-01-7
Pentachloroethane
ND
ND
1.4 E-03
82-68-8
Pentachloronitrobenzene
ND
ND
1.4 E-03
87-86-5
Pentachlorophenol
ND
ND
6.8 E-02
85-01-8
Phenanthrene
ND
ND
1.4 E-03
108-95-2
Phenol
4.3 E-09
9.4 E-07
--
115-07-1
Propylene
1.5 E-08
3.3 E-06
--
129-00-0
Pyrene
ND
ND
1.4 E-03
110-86-1
Pyridine
ND
ND
2.0 E-03
94-59-7
Safrole
ND
ND
1.4 E-03
7782-49-2
Selenium
ND
ND
1.1 E-03
7440-22-4
Silver
2.4 E-09
5.1 E-07
--
100-42-5
Styrene
ND
ND
4.8 E-03
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
5.4 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
ND
ND
5.4 E-09
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.7 E-03
127-18-4
T etrachloroethy lene
ND
ND
7.6 E-03
108-88-3
Toluene
9.6 E-09
2.1 E-06
--
6/08
Ordnance Detonation
A-7
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
95-53-4
o-Toluidine
ND
ND
1.7 E-02
120-82-1
1,2,4-Trichlorobenzene
ND
ND
3.4 E-02
71-55-6
1,1,1 -T richloroethane
ND
ND
6.1 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
6.1 E-03
79-01-6
Trichloroethylene
ND
ND
6.0 E-03
75-69-4
Trichlorofluoromethane
ND
ND
6.3 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
3.5 E-03
88-06-2
2,4,6-Trichlorophenol
ND
ND
2.0 E-03
96-18-4
1,2,3 -T richloropropane
ND
ND
2.8 E-02
95-63-6
1,2,4-Trimethylbenzene
ND
ND
5.5 E-03
540-84-1
2,2,4-Trimethylpentane
ND
ND
2.1 E-02
108-05-4
Vinyl acetate
ND
ND
1.6 E-02
75-01-4
Vinyl chloride
ND
ND
1.6 E-02
75-35-4
Vinylidene chloride
ND
ND
4.4 E-03
106-42-3,
m-Xylene, p-Xvlene
ND
ND
4.9 E-03
108-38-3
95-47-6
o-Xylene
ND
ND
4.9 E-03
7440-66-6
Zinc
5.7E-07
1.2 E-04
—
Other Po
lutants
67-64-1
Acetone
1.3 E-07
2.9 E-05
--
74-86-2
Acetylene
2.3 E-08
5.0E-06
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
1.8 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
1.8 E-04
100-52-7
Benzaldehyde
ND
ND
6.3 E-02
84-69-5
1,2-Benzenedicarboxylic acid, bis(2-
methyl propy l)esterh
1.8 E-08
3.9 E-06
--
65-85-0
Benzoic acid
ND
ND
1.2E-01
100-51-6
Benzyl alcohol
ND
ND
9.5 E-02
106-98-9
1-Butene
ND
ND
1.0 E-02
590-18-1
cis-2-Butene
ND
ND
1.0 E-02
624-64-6
trans-2-Butene
ND
ND
1.0 E-02
107-14-2
Chloroacetonitrile
ND
ND
3.5 E-02
2698-41-1
o-chlorobenzalmalononitrile
ND
ND
2.7 E-03
109-69-3
1-Chlorobutane
ND
ND
4.2 E-02
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.7 E-03
A-8
Ordnance Detonation
6/08
-------
TABLE A1 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
90-13-1
1 -Chloronaphthalene
ND
ND
1.4E-03
95-57-8
2-Chlorophenol
ND
ND
1.4 E-03
629-20-9
1,3,5,7-Cyclooctatetraeneh
1.1 E-08
2.4 E-06
--
287-92-3
Cyclopentane
ND
ND
1.3 E-02
124-18-5
n-Decane
ND
ND
2.7 E-02
124-48-1
Dibromochloromethane
ND
ND
9.5 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.4 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
5.1 E-03
87-65-0
2,6-Dichlorophenol
ND
ND
1.4 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
5.1 E-03
141-93-5
1,3 -Diethylbenzene
ND
ND
2.5 E-02
105-05-5
1,4-Diethylbenzene
ND
ND
2.5 E-02
84-66-2
Diethylphthalate
ND
ND
2.0 E-03
5779-94-2
2,5-Dimethv lbenzal dehvde
ND
ND
1.3 E-01
75-83-2
2,2-Dimethylbutane
ND
ND
1.6 E-02
79-29-8
2,3-Dimethylbutane
ND
ND
1.6 E-02
565-59-3
2,3-Dimethylpcntanc
':: ND
ND
1.9 E-02
108-08-7
2,4-Dimethylpentane
ND
ND
1.9 E-02
117-84-0
Di-n-octylphthalate
1.1 E-09
2.4 E-07
--
74-84-0
Ethane
ND
ND
1.4 E-02
64-17-5
Ethanol
ND
ND
8.6 E-03
60-29-7
Ethyl ether
ND
ND
1.4 E-02
97-63-2
Ethyl methacrylate
ND
ND
5.2 E-02
62-50-0
Ethyl methane sulfonate
ND
ND
1.4 E-03
620-14-4
m-Ethyltoluene
ND
ND
2.3 E-02
611-14-3
o-Ethyltoluene
ND
ND
2.3 E-02
622-96-8
p-Ethyltoluene
ND
ND
2.3 E-02
593-49-7
Heptacosaneh
1.2 E-08
2.7 E-06
--
142-82-5
n-Heptane
ND
ND
4.6 E-03
1888-71-7
Hexachloropropene
ND
ND
1.9 E-03
66-25-1
Hexaldehyde
ND
ND
6.3 E-02
103-23-1
Hexanedioic acid, bis(2-ethylhexyl)
ester11
5.2 E-09
1.1 E-06
--
591-78-6
2-Hexanone
ND
ND
1.9 E-02
592-41-6
1-Hexene
ND
ND
1.6 E-02
6/08
Ordnance Detonation
A-9
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
78-79-5
Isoprene
ND
ND
1.3 E-02
590-86-3
Isovaleraldehyde
ND
ND
6.3 E-02
5989-27-5
d-Limonene
ND
ND
2.5 E-02
1117-97-1
Methanamine, N-methoxy-h
2.6 E-08
5.7 E-06
--
75-52-5
Methane, nitro-h
2.4 E-08
5.2 E-06
--
108-87-2
Methylcyclohexane
ND
ND
1.8 E-02
96-37-7
Methylcyclopentane
ND
ND
1.6 E-02
78-93-3
Methyl ethyl ketone
4.1 E-09
8.9 E-07
--
592-27-8
2-Methylheptane
ND
ND
2.1 E-02
589-81-1
3 -Methy lheptane
ND
ND
2.1 E-02
591-76-4
2-Methylhexane
ND
ND
1.9 E-02
589-34-4
3 -Methy lhexane
ND
ND
1.9 E-02
66-27-3
Methyl methane sulfonate
ND
ND
1.5 E-03
56862-62-5
10-Methylnonadecaneh
1.8 E-08
3.8 E-06
--
107-83-5
2-Methylpentane
ND
ND
1.6 E-02
96-14-0
3-Methylpentane
ND ¦¦¦'
ND
1.6 E-02
88-74-4
2-Nitroaniline
ND
ND
1.4 E-03
99-09-2
3-Nitroaniline
ND
ND
5.4 E-03
10595-95-6
N -Nitrosomethylethylamine
ND
ND
2.2 E-03
930-55-2
N-Nitrosopyrrolidine
ND
ND
1.4 E-03
88-72-2
2-Nitrotoluene
ND
ND
9.1 E-04
111-84-2
n-Nonane
ND
ND
2.4 E-02
111-65-9
n-Octane
ND
ND
2.1 E-02
1823-52-5
2-Oxetanone, 4,4- dimethyl-11
5.5 E-08
1.2 E-05
--
78-78-4
i-Pentane
ND
ND
1.4 E-02
109-66-0
n-Pentane
ND
ND
1.3 E-02
109-67-1
1-Pentene
ND
ND
1.3 E-02
627-20-3
cis-2-Pentene
ND
ND
1.3 E-02
646-04-8
trans-2-Pentene
ND
ND
1.3 E-02
14797-73-0
Perchlorate
ND
ND
1.5 E-02
78-11-5
PETN
ND
ND
9.4 E-04
62-44-2
Phenacetin
ND
ND
1.4 E-03
80-56-8
alpha-Pinene
ND
ND
2.5 E-02
127-91-3
beta-Pinene
ND
ND
2.5 E-02
74-98-6
Propane
ND
ND
2.0 E-02
A-10
Ordnance Detonation
6/08
-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
115-11-7
1-Propene, 2-methyl-h
1.9 E-08
4.1 E-06
--
103-65-1
n-Propylbenzene
ND
ND
5.5 E-03
121-82-4
RDX
ND
ND
1.2 E-04
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.4 E-03
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
1.8 E-03
109-99-9
Tetrahydrofuran
ND
ND
3.3 E-03
7098-22-8
T etratetracontaneh
1.3 E-08
2.8 E-06
--
529-20-4
o-Tolualdehyde
ND
ND
6.3 E-02
526-73-8
1,2,3 -T rimethylbenzene
ND
ND
2.2 E-02
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
5.5 E-03
565-75-3
2,3,4-Trimethylpentane
ND
ND
2.1 E-02
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
1.2 E-03
118-96-7
2,4,6-Trinitrotoluene8
9.0 E-10
2.0 E-07
--
7098-21-7
Tritetracontaneh
1.5 E-08
3.3 E-06
--
1120-21-4
Undecane
ND
ND
2.9 E-02
110-62-3
Valeraldehyde
ND
ND
6.3 E-02
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 4.50 E-03 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated D because the factor is based upon C-rated test data.
h Emission factor rated D because the factor is for a tentatively identified compound.
6/08
Ordnance Detonation
A-ll
-------
TABLE A2 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC G963, M7A3 CS RIOT CONTROL AGENT HAND GRENADE
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxide
9.1 E-02
1.1 E-01
--
630-08-0
Carbon monoxide
3.4 E-02
4.1 E-02
--
--
Oxides of nitrogen
1.4E-03
1.7 E-03
--
--
PM-2.5
3.7 E-02
4.5 E-02
--
--
PM-10
4.2 E-02
5.1 E-02
--
7446-09-5
Sulfur dioxide
5.1 E-05
6.1 E-05
--
~
Total nonmethane hydrocarbons
5.6E-03
6.7 E-03
--
12789-66-1
Total suspended particulate
1.8 E-02
2.2 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.6 E-02
208-96-8
Acenaphthylene
ND
ND
1.6 E-02
75-07-0
Acetaldehyde
ND
ND
7.5 E-02
75-05-8
Acetonitrile
3.3E-04;
3.9 E-04
--
98-86-2
Acetophenone
3.3 11-06
3.9E-06
--
53-96-3
2-Acetylaminofluorene
: ND
ND
1.6 E-02
107-02-8
Acrolein
1.0E-03
1.2 E-03
--
107-13-1
Acrylonitrile
1.1 E-04
1.3 E-04
~
107-05-1
Allyl chloride
ND
ND
2.6 E-01
92-67-1
4-Aminobiphenyl
ND
ND
3.1 E-01
7664-41-7
Ammonia
5.6 E-05
6.7 E-05
--
62-53-3
Aniline
ND
ND
2.3 E-01
120-12-7
Anthracene
ND
ND
1.6 E-02
71-43-2
Benzene
2.3 E-04
2.7 E-04
--
92-87-5
Benzidine
ND
ND
1.6
56-55-3
Benzo [a] anthracene
ND
ND
1.8 E-02
205-99-2
Benzo [b] fluoranthene
ND
ND
3.4 E-02
207-08-9
Benzo [k] fluoranthene
ND
ND
1.9 E-02
191-24-2
Benzo [g,h,i]perylene
ND
ND
5.0 E-02
50-32-8
Benzo [a]pyrene
ND
ND
1.6 E-02
100-44-7
Benzyl chloride
ND
ND
1.1 E-01
75-25-2
Bromoform
ND
ND
2.2 E-01
74-83-9
Bromomethane
ND
ND
8.3 E-02
A-12
Ordnance Detonation
6/08
-------
TABLE A.2 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
101-55-3
4-Bromophenylphenylether
ND
ND
1.6 E-02
106-99-0
1,3-Butadiene
1.1 E-05
1.3 E-05
--
71-36-3
n-Butanol
ND
ND
2.5 E-01
85-68-7
Butylbenzylphthalate
ND
ND
1.9 E-02
123-72-8
Butyraldehyde
1.2 E-05
1.5 E-05
--
86-74-8
Carbazole
ND
ND
2.0 E-02
75-15-0
Carbon disulfide
ND
ND
6.7 E-02
56-23-5
Carbon tetrachloride
ND
ND
1.3 E-01
7782-50-5
Chlorinef
4.7 E-05
5.6 E-05
--
106-47-8
4-Chloroaniline
ND
ND
1.9 E-01
108-90-7
Chlorobenzene
3.6E-04
4.4 E-04
--
75-00-3
Chloroethane
ND
ND
5.6 E-02
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.6 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.8 E-02
67-66-3
Chloroform
ND
ND
1.0 E-01
108-60-1
bis(2-Chloroisopropvl)ether
ND ¦¦¦'
ND
2.4 E-02
74-87-3
Chloromethane
3.9 E-05
4.7 E-05
--
91-58-7
2-Chloronaphthalene
ND
ND
1.6 E-02
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.6 E-02
7440-47-3
Chromium
1.0 E-06
1.2 E-06
--
218-01-9
Chrysene
ND
ND
2.0 E-02
7440-48-4
Cobalt
ND
ND
3.6E-03
4170-30-3
Crotonaldehyde
ND
ND
1.9 E-01
98-82-8
Cumene
ND
ND
1.1 E-01
110-82-7
Cyclohexane
ND
ND
7.3 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.9 E-02
132-64-9
Dibenzofuran
ND
ND
1.6 E-02
106-93-4
1,2-Dibromoethane
ND
ND
1.6 E-01
84-74-2
Dibutylphthalate
ND
ND
3.1 E-01
95-50-1
1,2-Dichlorobenzene
ND
ND
1.3 E-01
541-73-1
1,3 -Dichlorobenzene
ND
ND
1.3 E-01
106-46-7
1,4-Dichlorobenzene
ND
ND
1.3 E-01
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
2.3 E-01
75-27-4
Dichlororobromomethane
ND
ND
1.4 E-01
75-71-8
Dichlorodifluoromethane
ND
ND
1.1 E-01
6/08
Ordnance Detonation
A-13
-------
TABLE A.2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
75-34-3
1,1 -Dichloroethane
ND
ND
8.6 E-02
107-06-2
1,2-Dichloroethane
ND
ND
8.6 E-02
120-83-2
2,4-Dichlorophenol
ND
ND
1.6 E-02
78-87-5
1,2-Dichloropropane
ND
ND
9.9 E-02
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
9.7 E-02
76-14-2
Dichlorotetrafluoroethane
ND
ND
1.5 E-01
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.6 E-02
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.6 E-02
119-93-7
3,3 '-Dimethylbenzidine
ND
ND
1.6
105-67-9
2,4-Dimethylphenol
ND
ND
2.0 E-01
131-11-3
Dimethyl phthalate
ND
ND
1.6 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
1.8 E-03
534-52-1
4,6-Dinitro-o-cresol
ND
ND
2.8 E-01
51-28-5
2,4-Dinitrophenol
ND
ND
6.9 E-01
121-14-2
2,4-Dinitrotolucnc
ND
ND
3.7 E-04
606-20-2
2,6-Dinitrotolucnc
ND
ND
5.2 E-04
88-85-7
Dinoseb
':: ND
ND
3.1 E-02
123-91-1
1,4-Dioxane
ND
ND
3.0 E-01
--
Total dioxin/furan compounds
4.7E-10
5.6E-10
--
122-39-4
Diphenylamine
ND
ND
1.6 E-02
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.6 E-02
100-41-4
Ethylbenzene
4.4 E-06
5.2 E-06
--
74-85-1
Ethylene
1.1 E-03
1.3 E-03
--
117-81-7
bis(2-Ethylhexyl)phthalate
ND
ND
3.1 E-01
206-44-0
Fluoranthene
ND
ND
1.7 E-02
86-73-7
Fluorene
6.4 E-07
7.7 E-07
--
50-00-0
Formaldehyde
5.3 E-04
6.3 E-04
--
76-13-1
Freon 113
ND
ND
1.6 E-01
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
3.3 E-ll
4.0 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
4.4 E-08
118-74-1
Hexachlorobenzene
ND
ND
1.6 E-02
87-68-3
Hexachlorobutadiene
ND
ND
8.9 E-01
77-47-4
Hexachlorocyclopentadiene
ND
ND
3.1 E-01
A-14
Ordnance Detonation
6/08
-------
TABLE A.2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
2.8 E-08
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
2.2 E-08
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
2.8 E-08
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
2.1 E-ll
2.5 E-ll
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
6.7E-12
8.0E-12
--
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
2.2 E-08
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
1.8E-12
2.2E-12
--
67-72-1
Hexachloroethane
ND
ND
1.7E-02
110-54-3
Hexane
ND
ND
7.5 E-02
7647-01-0
Hydrochloric acidf
3.5 E-04
4.2 E-04
--
74-90-8
Hydrogen cyanide
1.0 E-03
1.2 E-03
--
193-39-5
Indeno [ 1,2.3 -cdjpv rene
ND
ND
1.7 E-02
78-59-1
Isophorone
ND
ND
1.6 E-02
67-63-0
Isopropyl alcohol
ND
ND
2.0E-01
120-58-1
Isosafrole
• ; ND
ND
1.6 E-02
7439-97-6
Mercury
ND
ND
1.0 E-03
126-98-7
Methacrylonitrile
ND
ND
4.5 E-01
96-33-3
Methyl acrylate
ND
ND
5.7E-01
56-49-5
3 -Methy lcholanthrene
ND
ND
1.6 E-02
75-09-2
Methylene chloride
5.2E-06
6.3 E-06
~
108-10-1
Methyl isobutyl ketone
ND
ND
8.7 E-02
80-62-6
Methyl methacrylate
ND
ND
6.7 E-01
91-57-6
2-Methylnaphthalene
1.2E-06
1.4 E-06
--
95-48-7
2-Methylphenol
3.5 E-06
4.1 E-06
~
1634-04-4
Methyl tert-butyl ether
ND
ND
7.7 E-02
91-20-3
Naphthalene
1.2E-05
1.4 E-05
--
134-32-7
1 -Naphthylamine
ND
ND
3.1 E-01
91-59-8
2-Naphthylamine
ND
ND
3.1 E-01
100-01-6
4-Nitroaniline
ND
ND
6.3 E-02
98-95-3
Nitrobenzene
ND
ND
1.8 E-02
55-63-0
Nitroglycerin
4.8 E-05
5.7 E-05
--
88-75-5
2-Nitrophenol
ND
ND
1.6 E-02
100-02-7
4-Nitrophenol
ND
ND
1.0 E-01
6/08
Ordnance Detonation
A-15
-------
TABLE A.2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
79-46-9
2-Nitropropane
ND
ND
5.9E-01
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.6E-02
55-18-5
N-Nitrosodiethylamine
ND
ND
1.6E-02
62-75-9
N-Nitrosodimethylamine
ND
ND
1.6E-02
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.8 E-02
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.6 E-02
59-89-2
N-Nitrosomorpholine
ND
ND
1.6 E-02
100-75-4
N-Nitrosopiperidine
ND
ND
1.6 E-02
99-55-8
5 -Nitro-o-toluidine
ND
ND
2.5 E-01
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
1.5 E-10
1.8 E-10
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuranf
1.3 E-ll
1.5 E-ll
--
608-93-5
Pentachlorobenzene
ND
ND
1.6 E-02
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
1.7 E-08
57117-41-6
1,2,3,7,8-Pcntachlorodibenzofuran
4.5 E-ll
5.4 E-ll
--
57117-31-4
2,3,4,7,8-Pcntachlorodibenzofuran
4.8 E-ll
5.8 E-ll
--
76-01-7
Pentachloroethane
ND
ND
1.6 E-02
82-68-8
Pentachloronitrobenzene
ND
ND
1.6 E-02
87-86-5
Pentachlorophenol
ND
ND
7.5 E-01
85-01-8
Phenanthrene
1.9E-06
2.2 E-06
--
108-95-2
Phenol
3.8 E-05
4.6 E-05
--
109-77-3
Propanedinitrile,
(phenylmethylene)-8
9.3 E-05
1.1 E-04
--
123-38-6
Propionaldehyde
ND
ND
1.9 E-01
115-07-1
Propylene
2.4 E-04
2.9 E-04
~
129-00-0
Pyrene
ND
ND
1.6 E-02
110-86-1
Pyridine
ND
ND
2.3 E-02
94-59-7
Safrole
ND
ND
1.6 E-02
7782-49-2
Selenium
9.9 E-08
1.2E-07
--
7440-22-4
Silver
ND
ND
5.1 E-03
100-42-5
Styrene
1.7 E-05
2.0 E-05
~
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
1.7 E-08
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
1.4 E-10
1.7 E-10
~
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
1.5 E-01
A-16
Ordnance Detonation
6/08
-------
TABLE A.2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
127-18-4
T etrachloroethy lene
ND
ND
1.4E-01
108-88-3
Toluene
6.4 E-05
7.7 E-05
--
95-53-4
o-Toluidine
ND
ND
2.0 E-01
120-82-1
1,2,4-Trichlorobenzene
ND
ND
6.2 E-01
71-55-6
1,1,1 -T richloroethane
ND
ND
1.2 E-01
79-00-5
1,1,2-Trichloroethane
ND
ND
1.2 E-01
79-01-6
Trichloroethylene
ND
ND
1.1 E-01
75-69-4
Trichlorofluoromethane
ND
ND
1.2 E-01
95-95-4
2,4,5-Trichlorophenol
ND
ND
4.1 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
2.4 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
5.0 E-01
95-63-6
1,2,4-Trimethylbenzene
ND
ND
1.0 E-01
540-84-1
2,2,4-Trimethylpentane
ND
ND
7.6 E-01
108-05-4
Vinyl acetate
ND
ND
2.9 E-01
75-01-4
Vinyl chloride
" 1.2 E-05
1.5 E-05
2.9 E-01
75-35-4
Vinylidene chloride
ND
ND
8.5 E-02
106-42-3,
108-38-3
m-Xylene, p-Xvlene
':: ND
ND
9.3 E-02
95-47-6
o-Xylene
ND
ND
9.3 E-02
7440-66-6
Zinc
6.5 E-05
7.8 E-05
—
Other Po
lutants
67-64-1
Acetone
2.2 E-05
2.7 E-05
--
74-86-2
Acetylene
6.1 E-04
7.3 E-04
--
35572-78-2
2-Amino-4,6-dinitrotoluene
1.3 E-05
1.5 E-05
--
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
2.2 E-04
100-52-7
Benzaldehyde
1.5 E-05
1.8 E-05
--
89-98-5
Benzaldehyde, 2-chloro-8
5.9 E-05
7.0 E-05
--
587-04-2
Benzaldehyde, 3-chloro-8
1.5 E-04
1.8 E-04
--
95-49-8
Benzene, l-chloro-2-methyl-8
1.3 E-04
1.5 E-04
--
108-41-8
Benzene, l-chloro-3-methyl-8
2.4 E-04
2.9 E-04
--
65-85-0
Benzoic acid
ND
ND
1.4
271-89-6
Benzofuran8
1.2 E-05
1.5 E-05
--
100-47-0
Benzonitrile8
1.9 E-04
2.3 E-04
--
100-51-6
Benzyl alcohol
ND
ND
1.1
694-87-1
Bicyclo [4.2.0] octa-1,3,5 -triene8
5.8 E-05
7.0 E-05
--
6/08
Ordnance Detonation
A-17
-------
TABLE A.2 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
106-97-8
n-Butane
1.6E-06
1.9 E-06
--
106-98-9
1-Butene
3.1 E-05
3.7 E-05
--
590-18-1
cis-2-Butene
5.6E-06
6.7 E-06
--
624-64-6
trans-2-Butene
1.1 E-05
1.4 E-05
--
764-42-1
2-Butenedinitrile, (E)-8
1.3 E-05
1.6 E-05
--
78-94-4
3-Buten-2-one8
1.2 E-04
1.4 E-04
--
107-14-2
Chloroacetonitrile
ND
ND
1.3
2698-41-1
o-chlorobenzalmalononitrile
1.7E-02
2.0 E-02
--
2856-63-5
2-Chlorobenzyl cyanide
6.9 E-06
8.3 E-06
--
109-69-3
1-Chlorobutane
ND
ND
1.6
7315-17-5
2-Chlorohydrocinnamonitrile8
8.1 E-06
9.7 E-06
--
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.9 E-02
90-13-1
1 -Chloronaphthalene
2.2 E-06
2.6 E-06
--
95-57-8
2-Chlorophenol
2.8 E-05
3.4 E-05
--
629-20-9
1,3,5,7-Cyclooctatetraene8
7.3 E-05
8.7 E-05
~
287-92-3
Cyclopentane
ND
ND
4.7 E-01
124-18-5
n-Decane
':: ND
ND
9.5 E-01
124-48-1
Dibromochloromethane
ND
ND
1.8 E-01
156-59-2
cis-1,2-Dichloroethene
ND
ND
8.5 E-02
156-60-5
trans-1,2-Dichloroethene
ND
ND
9.7 E-02
87-65-0
2,6-Dichlorophenol
ND
ND
1.6 E-02
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
9.7 E-02
141-93-5
1,3 -Diethylbenzene
ND
ND
8.9 E-01
105-05-5
1,4-Diethylbenzene
ND
ND
8.9 E-01
84-66-2
Diethylphthalate
ND
ND
2.3 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
3.8 E-01
75-83-2
2,2-Dimethylbutane
ND
ND
5.7 E-01
79-29-8
2,3-Dimethy lbutane
ND
ND
5.7 E-01
565-59-3
2,3-Dimethy lpentane
ND
ND
6.7 E-01
108-08-7
2,4-Dimethylpentane
ND
ND
6.7 E-01
117-84-0
Di-n-octylphthalate
ND
ND
1.8 E-02
74-84-0
Ethane
1.3 E-04
1.5 E-04
--
64-17-5
Ethanol
1.3 E-05
1.5 E-05
--
60-29-7
Ethyl ether
ND
ND
4.9 E-01
97-63-2
Ethyl methacrylate
ND
ND
1.9
A-18
Ordnance Detonation
6/08
-------
TABLE A.2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
62-50-0
Ethyl methane sulfonate
ND
ND
1.6E-02
620-14-4
m-Ethyltoluene
ND
ND
8.0E-01
611-14-3
o-Ethyltoluene
ND
ND
8.0E-01
622-96-8
p-Ethyltoluene
ND
ND
8.0E-01
98-01-1
2-Furancarboxaldehyde8
7.7 E-05
9.2 E-05
--
67-47-0
2-Furancarboxaldehyde, 5-
(hydroxymethyl)8
1.0 E-05
1.2 E-05
--
2170-03-8
2,5-Furandione, dihydro-3-
methylene-8
2.0 E-04
2.3 E-04
--
142-82-5
n-Heptane
ND
ND
8.7 E-02
1888-71-7
Hexachloropropene
ND
ND
2.3 E-02
57-10-3
n-Hexadecanoic acid8
8.9 E-06
1.1 E-05
--
66-25-1
Hexaldehyde
ND
ND
1.9E-01
103-23-1
Hexanedioic acid, bis(2-ethylhexyl)
ester8
1.0 E-05
1.2 E-05
--
591-78-6
2-Hexanone
¦ ND
ND
3.4 E-01
592-41-6
1-Hexene
ND
ND
5.6 E-01
75-28-5
Isobutane
ND
ND
2.0 E-02
78-79-5
Isoprene
ND
ND
4.5 E-01
27655-41-0
5 -Isoquinolinecarbonitrile8
8.4 E-05
1.0 E-04
--
590-86-3
Isovaleraldehyde
ND
ND
1.9 E-01
5989-27-5
d-Limonene
ND
ND
4.6 E-01
108-87-2
Methylcyclohexane
ND
ND
6.5 E-01
96-37-7
Methylcyclopentane
ND
ND
5.6 E-01
78-93-3
Methyl ethyl ketone
1.8 E-05
2.2 E-05
--
592-27-8
2-Methylheptane
ND
ND
7.4 E-01
589-81-1
3 -Methy lheptane
ND
ND
7.6 E-01
591-76-4
2-Methylhexane
ND
ND
6.7 E-01
589-34-4
3 -Methy lhexane
ND
ND
6.7 E-01
66-27-3
Methyl methane sulfonate
ND
ND
1.8 E-02
107-83-5
2-Methylpentane
ND
ND
5.7 E-01
96-14-0
3 -Methy lpentane
ND
ND
5.7 E-01
88-74-4
2-Nitroaniline
ND
ND
1.6 E-02
99-09-2
3-Nitroaniline
ND
ND
6.3 E-02
10595-95-6
N -Nitrosomethylethylamine
ND
ND
2.6 E-02
930-55-2
N-Nitrosopyrrolidine
ND
ND
1.6 E-02
6/08
Ordnance Detonation
A-19
-------
TABLE A.2 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
88-72-2
2-Nitrotoluene
ND
ND
1.1 E-03
99-99-0
4-Nitrotoluene
4.9 E-05
5.9 E-05
--
111-84-2
n-Nonane
ND
ND
8.5 E-01
111-65-9
n-Octane
ND
ND
7.6 E-01
78-78-4
i-Pentane
ND
ND
4.8 E-01
109-66-0
n-Pentane
ND
ND
4.8 E-01
109-67-1
1-Pentene
ND
ND
4.7 E-01
627-20-3
cis-2-Pentene
ND
ND
4.7 E-01
646-04-8
trans-2-Pentene
ND
ND
4.7 E-01
14797-73-0
Perchlorate
1.9E-06
2.2 E-06
--
78-11-5
PETNf
1.3 E-05
1.5 E-05
--
62-44-2
Phenacetin
ND
ND
1.6E-02
536-74-3
Phenylethyne8
2.2 E-05
2.7 E-05
--
80-56-8
alpha-Pinene
ND
ND
4.6 E-01
127-91-3
beta-Pinene
ND
ND
4.6 E-01
74-98-6
Propane
9.1 E-06
1.1 E-05
--
3533-10-6
2-Propenamide. 3-(2-chlorophenvl)-
2-cyano-8
1.6 H-05
1.9 E-05
--
103-65-1
n-Propylbenzene
ND
ND
1.0 E-01
74-99-7
1-Propyne8
1.1 E-04
1.3 E-04
--
34846-64-5
3 -Quinolinecarbonitrile8
4.3 E-05
5.2 E-05
--
612-62-4
Quinoline, 2-chloro-8
1.1 E-05
1.3 E-05
--
121-82-4
RDX1
1.6 E-06
1.9 E-06
--
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.6 E-02
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
2.0 E-02
544-63-8
Tetradecanoic acid8
7.0 E-06
8.3 E-06
--
109-99-9
Tetrahydrofuran
ND
ND
6.3 E-02
479-45-8
Tetryl
ND
ND
3.3 E-01
529-20-4
o-Tolualdehyde
ND
ND
1.9 E-01
526-73-8
1,2,3 -T rimethylbenzene
ND
ND
8.0 E-01
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
1.0 E-01
565-75-3
2,3,4-Trimethylpentane
ND
ND
7.6 E-01
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
1.6 E-02
118-96-7
2,4,6-Trinitrotoluene
1.1 E-05
1.3 E-05
--
1120-21-4
Undecane
ND
ND
1.0
A-20
Ordnance Detonation
6/08
-------
TABLE A.2 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
110-62-3
Valeraldehyde
ND
ND
1.9 E-01
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 7.50 E-01 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated D because the factor is based upon C-rated test data.
8 Emission factor rated D because the factor is for a tentatively identified compound.
6/08
Ordnance Detonation
A-21
-------
TABLE A3 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC K765, CS RIOT CONTROL AGENT CAPSULE
Emission
Minimum
CASRN3
Compound
Factor
Detection Level
lb per itemb c
mg/m3,d
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxide
9.0 E-05
--
630-08-0
Carbon monoxide
1.0 E-05
--
--
Oxides of nitrogen
1.8 E-06
--
--
PM-2.5
2.9 E-05
--
--
PM-10
3.2 E-05
--
7446-09-5
Sulfur dioxide
6.3 E-08
~
~
Total nonmethane hydrocarbons6
1.0 E-05
~
12789-66-1
Total suspended particulate
2.8 E-05
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
1.3 E-03
208-96-8
Acenaphthylene
ND
1.3 E-03
75-05-8
Acetonitrile
1.5 E-06
~
98-86-2
Acetophenone
ND
6.3 E-03
53-96-3
2-Acetylaminofluorcnc
ND
1.3 E-03
107-02-8
Acrolein
4.4 E-08
~
107-13-1
Acrylonitrile
ND
1.8 E-02
107-05-1
Allyl chloride
ND
1.3 E-02
92-67-1
4-Aminobiphenyl
ND
2.6 E-02
7664-41-7
Ammonia
2.1 E-06
~
62-53-3
Aniline
ND
1.9 E-02
120-12-7
Anthracene
ND
1.3 E-03
71-43-2
Benzene
8.8 E-08
--
92-87-5
Benzidine
ND
1.3 E-01
56-55-3
Benzo [a] anthracene
ND
1.5 E-03
205-99-2
Benzo [b] fluoranthene
ND
2.9 E-03
207-08-9
Benzo [kjfluoranthene
ND
1.6 E-03
191-24-2
Benzo [g,h,i]perylene
ND
4.2 E-03
50-32-8
Benzo [a]pyrene
ND
1.3 E-03
100-44-7
Benzyl chloride
ND
5.3 E-03
75-25-2
Bromoform
ND
1.1 E-02
74-83-9
Bromomethane
ND
3.9 E-03
101-55-3
4-Bromophenylphenylether
ND
1.3 E-03
A-22
Ordnance Detonation
6/08
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
106-99-0
1,3-Butadiene
ND
2.2 E-03
71-36-3
n-Butanol
ND
1.2E-02
123-72-8
Butyraldehyde
6.2 E-08
--
86-74-8
Carbazole
ND
1.7 E-03
75-15-0
Carbon disulfide
ND
3.2 E-03
56-23-5
Carbon tetrachloride
ND
6.4 E-03
106-47-8
4-Chloroaniline
ND
1.6E-02
108-90-7
Chlorobenzene6
9.5 E-08
--
75-00-3
Chloroethane
1.4 E-08
--
111-91-1
bis(2-Chloroethoxy)methane
ND
1.3 E-03
111-44-4
bis(2-Chloroethyl)ether
ND
1.5 E-03
67-66-3
Chloroform
ND
5.0 E-03
108-60-1
bis(2-Chloroisopropyl)ether
ND
2.0 E-03
74-87-3
Chloromethane
9.0 E-08
--
91-58-7
2-Chloronaphthalcnc
ND
1.3 E-03
7005-72-3
4-Chlorophenylphenyl ether
ND
1.3 E-03
7440-47-3
Chromium
2.1 E-08
--
218-01-9
Chrysene
ND
1.7 E-03
7440-48-4
Cobalt
ND
1.5 E-03
4170-30-3
Crotonaldehyde
ND
5.0 E-02
98-82-8
Cumene
ND
5.0 E-03
110-82-7
Cyclohexane
ND
3.5 E-03
53-70-3
Dibenz [a,h] anthracene
ND
1.6 E-03
132-64-9
Dibenzofuran
ND
1.3 E-03
106-93-4
1,2-Dibromoethane
ND
7.8 E-03
84-74-2
Dibutylphthalate
ND
2.6 E-02
95-50-1
1,2-Dichlorobenzene
ND
6.1 E-03
541-73-1
1,3 -Dichlorobenzene
ND
6.1 E-03
106-46-7
1,4-Dichlorobenzene
ND
6.1 E-03
91-94-1
3,3 '-Dichlorobenzidine
ND
1.9 E-02
75-27-4
Dichlororobromomethane
ND
6.8 E-03
75-71-8
Dichlorodifluoromethane
ND
5.0 E-03
75-34-3
1,1 -Dichloroethane
ND
4.1 E-03
107-06-2
1,2-Dichloroethane
ND
4.1 E-03
120-83-2
2,4-Dichlorophenol
ND
1.3 E-03
6/08
Ordnance Detonation
A-23
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
78-87-5
1,2-Dichloropropane
ND
4.7 E-03
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
4.6 E-03
76-14-2
Dichlorotetrafluoroethane
ND
7.1 E-03
60-11-7
p-Dimethylaminoazobenzene
ND
1.3 E-03
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
1.3 E-03
119-93-7
3,3 '-Dimethylbenzidine
ND
1.3 E-01
105-67-9
2,4-Dimethylphenol
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
1.3 E-03
99-65-0
1,3 -Dinitrobenzene
4.6 E-08
~
534-52-1
4,6-Dinitro-o-cresol
ND
2.3 E-02
51-28-5
2,4-Dinitrophenol
ND
5.8 E-02
121-14-2
2,4-Dinitrotoluene
ND
3.0E-04
606-20-2
2,6-Dinitrotoluenee
2.5 E-08
--
88-85-7
Dinoseb
ND
2.6 E-03
123-91-1
1,4-Dioxane
Total dioxin/furan compounds
ND
2.4 11-12
1.5 E-02
122-39-4
Diphenvlaminc
ND
1.3 E-03
122-66-7
1,2-Diphenylhydrazine
ND
1.3 E-03
100-41-4
Ethylbenzene6
4.1 E-08
--
74-85-1
Ethylene
8.9 E-08
--
117-81-7
bis(2-Ethylhexyl)phthalate
ND
2.6 E-02
206-44-0
Fluoranthene
ND
1.4 E-03
86-73-7
Fluorene
ND
1.3 E-03
50-00-0
Formaldehyde
7.0 E-09
--
76-13-1
Freon 113
ND
7.8 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
3.9 E-13
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
1.4 E-08
118-74-1
Hexachlorobenzene
ND
1.3 E-03
87-68-3
Hexachlorobutadiene
ND
4.3 E-02
77-47-4
Hexachlorocyclopentadiene
ND
2.6 E-02
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
1.1 E-08
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
8.1 E-09
A-24
Ordnance Detonation
6/08
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
1.1 E-08
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
3.9E-13
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
1.6E-13
--
72918-21-9
1,2,3,7,8, 9-Hexachlorodibenzofuran
ND
8.1 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
1.3 E-13
~
67-72-1
Hexachloroethane
ND
1.4E-03
110-54-3
Hexane
2.4 E-08
--
7647-01-0
Hydrochloric acid
ND
1.0 E-01
74-90-8
Hydrogen cyanide
6.5 E-06
~
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
1.4 E-03
78-59-1
Isophorone
ND
1.3 E-03
67-63-0
Isopropyl alcohol
ND
1.0E-02
120-58-1
Isosafrole
ND
1.3 E-03
7439-97-6
Mercury
ND
4.1E-04
126-98-7
Methacrvlonitrile
: ND
2.2 E-02
96-33-3
Methyl acrvlate
ND
2.9 E-02
56-49-5
3 -Methylcholanthrene
ND
1.3 E-03
75-09-2
Methylene chloride
2.0 E-07
--
108-10-1
Methyl isobutyl ketone
ND
4.2 E-03
80-62-6
Methyl methacrylate
ND
3.3 E-02
91-57-6
2-Methylnaphthalene
1.9E-09
--
95-48-7
2-Methylphenole
4.2 E-08
~
1634-04-4
Methyl tert-butyl ether
ND
3.7 E-03
91-20-3
Naphthalene
ND
2.1 E-02
134-32-7
1 -Naphthylamine
ND
2.6 E-02
91-59-8
2-Naphthylamine
ND
2.6 E-02
100-01-6
4-Nitroaniline
ND
5.3 E-03
98-95-3
Nitrobenzene
ND
1.0 E-03
55-63-0
Nitroglycerin
ND
8.8 E-04
88-75-5
2-Nitrophenol
ND
1.3 E-03
100-02-7
4-Nitrophenol
ND
8.7 E-03
79-46-9
2-Nitropropane
ND
3.0 E-02
924-16-3
N-Nitroso-di-n-butylamine
ND
1.3 E-03
55-18-5
N-Nitrosodiethylamine
ND
1.3 E-03
6/08
Ordnance Detonation
A-25
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
62-75-9
N-Nitrosodimethylamine
ND
1.3 E-03
86-30-6
N-Nitrosodiphenylamine
ND
2.3 E-03
621-64-7
N-Nitroso-di-n-propylamine
ND
1.3 E-03
59-89-2
N-Nitrosomorpholine
ND
1.3 E-03
100-75-4
N-Nitrosopiperidine
ND
1.3 E-03
99-55-8
5 -Nitro-o-toluidine
ND
2.1 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
1.1 E-12
~
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
9.8 E-14
~
608-93-5
Pentachlorobenzene
ND
1.3 E-03
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
5.4E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
4.5 E-14
~
57117-31-4
2,3.4.7,8-Pcntachlorodibcnzofuran
1.3E-13
~
76-01-7
Pentachloroethane
ND
1.3 E-03
82-68-8
Pentachloronitrobcnzcnc
ND
1.3 E-03
87-86-5
Pentaehlorophcnol
ND .
6.6 E-02
85-01-8
Phenanthrene
ND
1.3 E-03
108-95-2
Phenol
2.1 E-07
--
109-77-3
Propanedinitrilef
1.4 E-06
--
123-38-6
Propionaldehyde
ND
5.0 E-02
115-07-1
Propylene
1.4 E-07
--
129-00-0
Pyrene
ND
1.4 E-03
110-86-1
Pyridine
ND
1.9 E-03
94-59-7
Safrole
ND
1.3 E-03
7782-49-2
Selenium
ND
1.0 E-03
7440-22-4
Silver
ND
2.1 E-03
100-42-5
Styrene6
3.0 E-08
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
5.4E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
3.2 E-14
--
79-34-5
1,1,2,2-Tetrachloroethane
ND
7.0 E-03
127-18-4
T etrachloroethy lene
ND
6.9 E-03
108-88-3
Toluene
6.5 E-07
--
95-53-4
o-Toluidine
ND
1.7 E-02
120-82-1
1,2,4-Trichlorobenzene
ND
3.0 E-02
A-26
Ordnance Detonation
6/08
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
71-55-6
1,1,1 -Trichloroethane
ND
5.5 E-03
79-00-5
1,1,2-Trichloroethane
ND
5.5 E-03
79-01-6
Trichloroethylene
ND
5.5 E-03
75-69-4
Trichlorofluoromethane
ND
5.7 E-03
95-95-4
2,4,5-Trichlorophenol
ND
3.4 E-03
88-06-2
2,4,6-Trichlorophenol
ND
2.0 E-03
96-18-4
1,2,3 -T richloropropane
ND
2.4 E-02
95-63-6
1,2,4-Trimethylbenzene
2.6 E-08
~
540-84-1
2,2,4-Trimethylpentane
ND
3.8 E-02
108-05-4
Vinyl acetate
ND
1.4 E-02
75-01-4
Vinyl chloride
ND
1.4 E-02
75-35-4
Vinylidene chloride
ND
4.0 E-03
106-42-3,
108-38-3
m-Xylene, p-Xylenee
6.6 E-08
~
95-47-6
o-Xylene
: 2.7 E-08
~
7440-66-6
Zinc
1.8 E-06
—
Other Pollutants
67-64-1
Acetone
1.7 E-07
--
74-86-2
Acetylene
ND
1.1 E-02
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
1.8E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
1.8E-04
100-52-7
Benzaldehyde
ND
5.0 E-02
89-98-5
Benzaldehyde, 2-chloro-f
1.3 E-06
--
95-49-8
Benzene, l-chloro-2-methylf
3.2 E-06
~
108-41-8
Benzene, l-chloro-3-methyl-f
3.2 E-06
~
65-85-0
Benzoic acid
ND
1.2E-01
100-51-6
Benzyl alcohol
ND
9.2 E-02
106-97-8
n-Butane
1.4 E-07
--
106-98-9
1-Butene
ND
9.3 E-03
590-18-1
cis-2-Butene
ND
9.3 E-03
624-64-6
trans-2-Butene
ND
9.3 E-03
625-38-7
3-Butenoic acidf
2.5 E-07
--
107-14-2
Chloroacetonitrile
ND
6.3 E-02
2698-41-1
o-Chlorobenzalmalononitrilee
2.4 E-05
--
2856-63-5
2-Chlorobenzyl cyanidef
1.2 E-07
~
6/08
Ordnance Detonation
A-27
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
109-69-3
1-Chlorobutane
ND
7.7 E-02
7315-17-5
2-Chlorohydrocinnamonitrilef
2.2 E-07
--
59-50-7
4-Chloro-3-methylphenol
ND
1.6E-03
90-13-1
1 -Chloronaphthalene
ND
1.3 E-03
95-57-8
2-Chlorophenol
2.9 E-08
--
295-65-8
Cyclohexadecanef
8.9 E-08
~
287-92-3
Cyclopentane
ND
2.3 E-02
4663-21-2
Cyclopropane, l-propenyl-f
1.7 E-07
~
124-18-5
n-Decane
ND
4.7 E-02
124-48-1
Dibromochloromethane
ND
8.7 E-03
156-59-2
cis-1,2-Dichloroethene
ND
4.0 E-03
156-60-5
trans-1,2-Dichloroethene
ND
4.6 E-03
87-65-0
2,6-Dichlorophenol
ND
1.3 E-03
10061-01-5
cis-1.3-Dichloropropene
ND
4.6 E-03
141-93-5
1,3-Dicthylbenzene
ND
4.5 E-02
105-05-5
1,4-Diethylbenzene
ND
4.5 E-02
5779-94-2
2,5-Dimcthylbcnzaldchyde
ND
1.0E-01
75-83-2
2,2-Dimethylbutane
ND
2.9 E-02
79-29-8
2,3 -Dimethylbutane
ND
2.9 E-02
565-59-3
2,3 -Dimethylpentane
ND
3.3 E-02
108-08-7
2,4-Dimethylpentane
ND
3.3 E-02
117-84-0
Di-n-octylphthalate
ND
1.5 E-03
624-92-0
Disulfide, dimethylf
2.1 E-07
--
55045-08-4
Dodecene, 2-methyl-6-propylf
8.0 E-08
--
74-84-0
Ethane
1.6 E-07
--
64-17-5
Ethanol
1.5 E-06
--
60-29-7
Ethyl ether
ND
2.5 E-02
97-63-2
Ethyl methacrylate
ND
9.5 E-02
62-50-0
Ethyl methanesulfonate
ND
1.3 E-03
620-14-4
m-Ethyltoluene
ND
4.0 E-02
611-14-3
o-Ethyltoluene
ND
4.0 E-02
622-96-8
p-Ethyltoluene
2.5 E-08
--
593-49-7
Heptacosanef
7.0 E-08
--
142-82-5
n-Heptane
2.0 E-08
--
1888-71-7
Hexachloropropene
ND
1.9 E-03
A-28
Ordnance Detonation
6/08
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
66-25-1
Hexaldehyde
ND
5.0E-02
103-23-1
Hexanedioic acid, bis(2-ethylhexyl)
este/
1.4 E-08
--
591-78-6
2-Hexanone
ND
1.7E-02
592-41-6
1-Hexene
ND
2.8 E-02
75-28-5
Isobutane
8.2 E-08
--
78-79-5
Isoprene
ND
2.3 E-02
590-86-3
Isovaleraldehyde
ND
5.0 E-02
5989-27-5
d-Limonene
ND
2.3 E-02
2698-41-1
Malononitrile, o-chlorobenzyl-f
9.5 E-07
--
108-87-2
Methylcyclohexane
ND
3.3 E-02
96-37-7
Methylcyclopentane
ND
2.8 E-02
78-93-3
Methyl ethyl ketone
4.1 E-08
--
592-27-8
2-Methylheptane
ND
3.7 E-02
589-81-1
3-Methylheptane
ND '
3.8 E-02
591-76-4
2-Mcthylhcxane
ND
3.3 E-02
589-34-4
3-Mcthylhexane
ND
3.3 E-02
66-27-3
Methyl methane sulfonate
ND
1.4E-03
107-83-5
2-Methylpentane
ND
2.9 E-02
96-14-0
3 -Methylpentane
ND
2.9 E-02
88-74-4
2-Nitroaniline
ND
1.3 E-03
99-09-2
3-Nitroaniline
ND
5.3 E-03
10595-95-6
N -Nitrosomethylethylamine
ND
2.2 E-03
930-55-2
N-Nitrosopyrrolidine
ND
1.3 E-03
88-72-2
2-Nitrotoluene
ND
9.1 E-04
99-99-0
4-Nitrotoluene
ND
7.6 E-04
111-84-2
n-Nonane
ND
4.3 E-02
593-45-3
Octadecanef
6.9 E-08
--
111-65-9
n-Octane
ND
3.8 E-02
3513-08-4
Oxirane-2,2-dicarbonitrile, 3-(2-
chlorophenylf
3.1 E-07
--
78-78-4
i-Pentane
1.4 E-07
--
109-66-0
n-Pentane
ND
2.4 E-02
109-67-1
1-Pentene
ND
2.3 E-02
627-20-3
cis-2-Pentene
ND
2.3 E-02
6/08
Ordnance Detonation
A-29
-------
TABLE A3 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
646-04-8
trans-2-Pentene
ND
2.3 E-02
14797-73-0
Perchlorate
ND
1.2E-03
78-11-5
PETN
6.6 E-07
--
62-44-2
Phenacetin
ND
1.3 E-03
80-56-8
alpha-Pinene
ND
2.3 E-02
127-91-3
beta-Pinene
ND
2.3 E-02
74-98-6
Propane
1.5 E-07
~
107-12-0
Propanenitrilef
1.1 E-07
~
3533-10-6
2-Propenamide, 3 -(2-chlorophenyl)-
2-cyano-f
1.4 E-07
~
115-11-7
1-Propene, 2-methyl-f
3.8 E-07
~
28446-72-2
2-Propenenitrile, 3-(4-
chlorophenyl)-f
9.4 E-08
--
103-65-1
n-Propylbenzene
ND
5.0 E-03
109-97-7
Pyrrole
; : 6.0 E-07
~
109-97-7
1-H-Pyrrole1
: .5.3 E-07
~
19179-12-5
Pyrrolo| 1.2-a|pvrazine-1.4-dione.
hexahydro1
: 2.0 E-07
--
121-82-4
RDXe
8.5 E-10
~
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
1.3 E-03
58-90-2
2,3,4,6-Tetrachlorophenol
ND
1.7 E-03
109-99-9
T etrahy drofuran6
2.7 E-08
--
7098-22-8
T etratetracontanef
1.7 E-08
~
14167-59-0
T etratriacontanef
5.4 E-08
~
529-20-4
o-Tolualdehyde
ND
5.0 E-02
526-73-8
1,2,3 -T rimethylbenzene
ND
4.0 E-02
108-67-8
1,3,5 -T rimethylbenzene
ND
5.0 E-03
565-75-3
2,3,4-Trimethylpentane
ND
3.8 E-02
99-35-4
1,3,5 -T rinitrobenzene
ND
1.3 E-03
118-96-7
2,4,6-Trinitrotoluenee
3.9 E-08
--
1120-21-4
Undecane
ND
5.2 E-02
110-62-3
Valeraldehyde
ND
5.0 E-02
A-30
Ordnance Detonation
6/08
-------
TABLE A3 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d Data provided for compounds that were not detected.
e Emission factor rated D because the factor is based upon C-rated test data.
f Emission factor rated D because the factor is for a tentatively identified compound.
6/08
Ordnance Detonation
A-31
-------
TABLE A4 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC L367, M22 ANTI-TANK GUIDED MISSILE AND ROCKET LAUNCHING SIMULATOR
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxidef
1.1 E-02
3.1 E-01
--
630-08-0
Carbon monoxidef
4.3 E-05
1.2 E-03
--
--
Oxides of nitrogen8
2.5 E-03
7.0 E-02
--
--
PM-2.5
1.3 E-02
3.8 E-01
--
--
PM-108
1.4 E-02
4.0 E-01
--
7446-09-5
Sulfur dioxide8
7.6 E-05
2.2 E-03
--
--
Total nonmethane hydrocarbons'1
7.3 E-06
2.1 E-04
--
12789-66-1
Total suspended particulatef
1.9 E-02
5.5 E-01
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.3 E-03
208-96-8
Acenaphthylene
ND
ND
1.3 E-03
75-05-8
Acetonitrile
ND
ND
2.0 E-02
98-86-2
Acetophenone
ND ,
ND
6.3 E-03
53-96-3
2-Acetylam i nofl uorene
^ ND
ND
1.3 E-03
107-02-8
Acrolein8
; ND
ND
1.1 E-02
107-13-1
Acrylonitrile8
ND
ND
1.0 E-02
107-05-1
Allyl chloride
ND
ND
1.5 E-02
92-67-1
4-Aminobiphenyl
ND
ND
2.6 E-02
7664-41-7
Ammonia
ND
ND
6.8 E-02
62-53-3
Aniline
ND
ND
1.9 E-02
120-12-7
Anthracene
ND
ND
1.3 E-03
71-43-2
Benzenef
3.2 E-06
9.0 E-05
--
92-87-5
Benzidine
ND
ND
1.3 E-01
56-55-3
Benzo [a] anthracene
ND
ND
1.5 E-03
205-99-2
Benzo [b] fluoranthene
ND
ND
2.9 E-03
207-08-9
Benzo [k] fluoranthene
ND
ND
1.6 E-03
191-24-2
Benzo [g,h,i]perylene
ND
ND
4.2 E-03
50-32-8
Benzo [a]pyrene
ND
ND
1.3 E-03
100-44-7
Benzyl chloride
ND
ND
6.3 E-03
7440-41-7
Beryllium
ND
ND
2.8 E-04
75-25-2
Bromoform
ND
ND
1.3 E-02
74-83-9
Bromomethane
ND
ND
4.7 E-03
A-32
Ordnance Detonation
6/08
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
101-55-3
4-Bromophenylphenylether
ND
ND
1.3 E-03
106-99-0
1,3-Butadienef
ND
ND
2.7 E-03
71-36-3
n-Butanol
ND
ND
1.4 E-02
85-68-7
Butylbenzylphthalate
ND
ND
1.6 E-03
123-72-8
Butyraldehyde
ND
ND
1.4 E-02
86-74-8
Carbazole
ND
ND
1.7 E-03
75-15-0
Carbon disulfide8
ND
ND
3.8 E-03
56-23-5
Carbon tetrachloride8
ND
ND
7.7 E-03
106-47-8
4-Chloroaniline
ND
ND
1.6 E-02
108-90-7
Chlorobenzene
ND
ND
5.6 E-03
75-00-3
Chloroethane
ND
ND
3.2 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.3 E-03
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.5 E-03
67-66-3
Chloroform
ND
ND
5.9 E-03
108-60-1
bis(2-Chloroisopropvl)cther
ND
ND
2.0 E-03
74-87-3
Chloromethanc
ND ¦¦¦'
ND
9.7 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.3 E-03
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.3 E-03
7440-47-3
Chromium8
3.5 E-07
9.9 E-06
--
218-01-9
Chrysene
ND
ND
1.7 E-03
7440-48-4
Cobalt8
ND
ND
1.6 E-03
7440-50-8
Copper1
5.3 E-07
1.5 E-05
--
4170-30-3
Crotonaldehyde
ND
ND
5.0 E-02
98-82-8
Cumene
ND
ND
6.0 E-03
110-82-7
Cyclohexane
ND
ND
4.2 E-03
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.6 E-03
132-64-9
Dibenzofuran
ND
ND
1.3 E-03
106-93-4
1,2-Dibromoethane
ND
ND
9.4 E-03
84-74-2
Dibutylphthalate
ND
ND
2.6 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
7.3 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
7.3 E-03
106-46-7
1,4-Dichlorobenzene
ND
ND
7.3 E-03
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
1.9 E-02
75-27-4
Dichlororobromomethane
ND
ND
8.2 E-03
75-71-8
Dichlorodifluoromethane
ND
ND
6.0 E-03
6/08
Ordnance Detonation
A-33
-------
TABLE A4 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
75-34-3
1,1 -Dichloroethane
ND
ND
4.9 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.9 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.3 E-03
78-87-5
1,2-Dichloropropane
ND
ND
5.6 E-03
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
5.5 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
8.5 E-03
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.3 E-03
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.3 E-03
119-93-7
3,3 '-Dimethylbenzidine
ND
ND
1.3 E-01
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.3 E-03
99-65-0
1,3 -Dinitrobenzene
ND
ND
1.6 E-03
534-52-1
4,6-Dinitro-o-cresol
ND
ND
2.3 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
5.8 E-02
121-14-2
2,4-Dinitrotolucnc
ND
ND
3.2E-04
606-20-2
2,6-Dinitrotolucnc
ND ¦¦¦'
ND
4.5 E-04
88-85-7
Dinoseb
ND
ND
2.6 E-03
123-91-1
1,4-Dioxane
ND
ND
1.7 E-02
--
Total dioxin/furan compounds
4.5 E-ll
1.3 E-09
--
122-39-4
Diphenylamine
ND
ND
1.3 E-03
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.3 E-03
100-41-4
Ethylbenzene8
2.8 E-07
7.9 E-06
--
74-85-1
Ethylene1
5.6 E-07
1.6 E-05
--
117-81-7
bis(2-Ethylhexyl)phthalate8
1.6 E-06
4.5 E-05
--
206-44-0
Fluoranthene
ND
ND
1.4 E-03
86-73-7
Fluorene
ND
ND
1.3 E-03
50-00-0
Formaldehyde8
7.9 E-07
2.2 E-05
--
76-13-1
Freon 113
ND
ND
9.4 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxinh
2.8 E-12
8.0 E-ll
~
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
1.1 E-08
118-74-1
Hexachlorobenzene
ND
ND
1.3 E-03
87-68-3
Hexachlorobutadiene
ND
ND
5.0 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.6 E-02
A-34
Ordnance Detonation
6/08
-------
TABLE A4 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
7.9 E-09
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
7.9 E-09
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
7.9 E-09
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
ND
ND
5.3 E-09
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
5.3 E-09
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
5.3 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
5.3 E-09
67-72-1
Hexachloroethane
ND
ND
1.4E-03
110-54-3
Hexane
ND
ND
4.3 E-03
7647-01-0
Hydrochloric acid
ND
ND
1.0E-01
74-90-8
Hydrogen cyanide
9.0 E-07
2.6 E-05
--
193-39-5
Indeno [ 1,2.3 -cdjpv rene
ND
ND
1.4 E-03
78-59-1
Isophorone
ND
ND
1.3 E-03
67-63-0
Isopropyl alcohol
ND
ND
1.1 E-02
120-58-1
Isosafrole
• ; ND
ND
1.3 E-03
7439-96-5
Manganese8
5.8 E-06
1.6 E-04
--
7439-97-6
Mercury
ND
ND
4.4 E-04
126-98-7
Methacrylonitrile
ND
ND
1.3 E-02
96-33-3
Methyl acrylate
ND
ND
1.6 E-02
56-49-5
3 -Methy lcholanthrene
ND
ND
1.3 E-03
75-09-2
Methylene chloride
5.9 E-07
1.7 E-05
--
108-10-1
Methyl isobutyl ketone
ND
ND
5.0 E-03
80-62-6
Methyl methacrylate
ND
ND
1.9 E-02
91-57-6
2-Methylnaphthalene8
3.3 E-08
9.4 E-07
--
95-48-7
2-Methylphenol
ND
ND
7.9 E-03
1634-04-4
Methyl tert-butyl ether
ND
ND
4.4 E-03
91-20-3
Naphthalene8
ND
ND
2.4 E-02
134-32-7
1 -Naphthylamine
ND
ND
2.6 E-02
91-59-8
2-Naphthylamine
ND
ND
2.6 E-02
100-01-6
4-Nitroaniline
ND
ND
5.3 E-03
98-95-3
Nitrobenzene
ND
ND
1.1 E-03
55-63-0
Nitroglycerin
ND
ND
9.4 E-04
88-75-5
2-Nitrophenol
ND
ND
1.3 E-03
6/08
Ordnance Detonation
A-35
-------
TABLE A4 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
100-02-7
4-Nitrophenol
ND
ND
8.7 E-03
79-46-9
2-Nitropropane
ND
ND
1.7E-02
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.3 E-03
55-18-5
N-Nitrosodiethylamine
ND
ND
1.3 E-03
62-75-9
N-Nitrosodimethylamine
ND
ND
1.3 E-03
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.3 E-03
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.3 E-03
59-89-2
N-Nitrosomorpholine
ND
ND
1.3 E-03
100-75-4
N-Nitrosopiperidine
ND
ND
1.3 E-03
99-55-8
5 -Nitro-o-toluidine
ND
ND
2.1 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxinh
3.6 E-ll
1.0 E-09
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuranh
6.6 E-12
1.9 E-10
~
608-93-5
Pentachlorobcnzcne
ND
ND
1.3 E-03
40321-76-4
1,2,3,7,8-Pcntachlorodibcnzo-p-
dioxin
ND,,,
ND
5.3 E-09
57117-41-6
1,2,3,7,8-Pcntachlorodibenzofuran
: ND
ND
2.6 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
5.3 E-09
76-01-7
Pentachloroethane
ND
ND
1.3 E-03
82-68-8
Pentachloronitrobenzene
ND
ND
1.3 E-03
87-86-5
Pentachlorophenol
ND
ND
6.6 E-02
85-01-8
Phenanthrene
ND
ND
1.3 E-03
108-95-2
Phenol8
1.3 E-07
3.6 E-06
--
123-38-6
Propionaldehyde
ND
ND
5.0 E-02
115-07-1
Propylenef
ND
ND
2.1 E-02
129-00-0
Pyrene
ND
ND
1.4 E-03
110-86-1
Pyridine
ND
ND
1.9 E-03
94-59-7
Safrole
ND
ND
1.3 E-03
7782-49-2
Selenium
ND
ND
1.1 E-03
7440-22-4
Silver
ND
ND
2.2 E-03
100-42-5
Styrene8
ND
ND
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-
dioxin8
ND
ND
5.3 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
ND
ND
2.6 E-09
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
8.4 E-03
A-36
Ordnance Detonation
6/08
-------
TABLE A4 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
127-18-4
T etrachloroethy lene
ND
ND
8.3 E-03
108-88-3
Toluene8
2.8 E-07
8.1 E-06
--
95-53-4
o-Toluidine
ND
ND
1.7 E-02
120-82-1
1,2,4-Trichlorobenzene
ND
ND
3.5 E-02
71-55-6
1,1,1 -T richloroethane
ND
ND
6.7 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
6.6 E-03
79-01-6
Trichloroethylene
ND
ND
6.6 E-03
75-69-4
Trichlorofluoromethane
ND
ND
6.9 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
3.4 E-03
88-06-2
2,4,6-Trichlorophenol
ND
ND
2.0 E-03
96-18-4
1,2,3 -T richloropropane
ND
ND
2.8 E-02
95-63-6
1,2,4-Trimethylbenzeneh
3.8 E-07
1.1 E-05
--
540-84-1
2,2,4-Trimethylpentane
ND
ND
2.2 E-02
108-05-4
Vinyl acetate
ND
ND
1.6 E-02
75-01-4
Vinyl chloride
ND
ND
1.6 E-02
75-35-4
Vinylidene ch 1 o ri de
ND ¦¦¦'
ND
4.8 E-03
106-42-3,
108-38-3
m-Xylene, p-Xvlene'
3.0 E-07
8.5 E-06
--
95-47-6
o-Xylene
ND
ND
5.3 E-03
7440-66-6
Zinc
1.6 E-05
4.5 E-04
—
Other Po
lutants
67-64-1
Acetonef
1.2 E-06
3.4 E-05
--
74-86-2
Acetylenef
8.0 E-07
2.3 E-05
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
1.9 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
1.9 E-04
100-52-7
Benzaldehyde8
ND
ND
5.0 E-02
17851-53-5
1,2-Benzenedicarboxylic acid, butyl
2-methyl1
8.6 E-07
2.4 E-05
--
65-85-0
Benzoic acid
ND
ND
1.2E-01
100-51-6
Benzyl alcohol
ND
ND
9.2 E-02
106-97-8
n-Butane1
8.5 E-07
2.4 E-05
--
106-98-9
1-Butenef
ND
ND
1.1 E-02
590-18-1
cis-2-Butenef
ND
ND
1.1 E-02
624-64-6
trans-2-Butenef
ND
ND
1.1 E-02
107-14-2
Chloroacetonitrile
ND
ND
3.8 E-02
6/08
Ordnance Detonation
A-37
-------
TABLE A4 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
2698-41-1
o-chlorobenzalmalononitrile
ND
ND
2.6 E-03
109-69-3
1-Chlorobutane
ND
ND
4.6 E-02
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.6 E-03
90-13-1
1 -Chloronaphthalene
ND
ND
1.3 E-03
95-57-8
2-Chlorophenol
ND
ND
1.3 E-03
629-20-9
1,3,5,7-Cyclooctatetraene1
1.6 E-06
4.6 E-05
--
287-92-3
Cyclopentane
ND
ND
1.3 E-02
124-18-5
n-Decane
ND
ND
2.7 E-02
124-48-1
Dibromochloromethane
ND
ND
1.0 E-02
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.8 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
5.5 E-03
87-65-0
2,6-Dichlorophenol
ND
ND
1.3 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
5.5 E-03
141-93-5
1,3 -Diethylbenzene
ND
ND
2.6 E-02
105-05-5
1,4-Diethyl benzene
ND
ND
2.6 E-02
5779-94-2
2,5-Dimethylbcnzaldehyde
ND
ND
1.0 E-01
75-83-2
2,2-Dimethvlbutane
':: ND
ND
1.6 E-02
79-29-8
2,3-Dimethylbutane
ND
ND
1.6 E-02
565-59-3
2,3 -Dimethylpentane
ND
ND
1.9 E-02
108-08-7
2,4-Dimethylpentane
ND
ND
1.9 E-02
117-84-0
Di-n-octylphthalate
ND
ND
1.5 E-03
74-84-0
Ethanef
4.2 E-07
1.2 E-05
--
64-17-5
Ethanol
ND
ND
8.8 E-03
60-29-7
Ethyl ether
ND
ND
1.4 E-02
97-63-2
Ethyl methacrylate
ND
ND
5.7 E-02
62-50-0
Ethyl methane sulfonate
ND
ND
1.3 E-03
620-14-4
m-Ethyltoluene8
ND
ND
2.3 E-02
611-14-3
o-Ethyltoluene8
ND
ND
2.3 E-02
622-96-8
p-Ethyltoluenef
2.7 E-07
7.7 E-06
--
142-82-5
n-Heptane
ND
ND
5.0 E-03
1888-71-7
Hexachloropropene
ND
ND
1.9 E-03
66-25-1
Hexaldehyde
ND
ND
5.0 E-02
103-23-1
Hexanedioic acid, bis(2-ethylhexyl)
ester1
3.9 E-07
1.1 E-05
""
591-78-6
2-Hexanone
ND
ND
1.9 E-02
A-38
Ordnance Detonation
6/08
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
592-41-6
1-Hexene8
ND
ND
1.6 E-02
75-28-5
Isobutane1
5.7 E-07
1.6 E-05
--
78-79-5
Isoprene
ND
ND
1.3 E-02
590-86-3
Isovaleraldehyde
ND
ND
5.0 E-02
5989-27-5
d-Limonene
ND
ND
2.6 E-02
7439-95-4
Magnesiumf
3.2 E-03
9.1 E-02
--
1117-97-1
Methanamine, N-methoxy-1
6.7 E-07
1.9 E-05
--
75-52-5
Methane, nitro-k
8.7 E-07
2.5 E-05
--
108-87-2
Methylcyclohexane
ND
ND
1.9 E-02
96-37-7
Methylcyclopentane
ND
ND
1.6 E-02
592-27-8
2-Methylheptane8
ND
ND
2.1 E-02
589-81-1
3 -Methy lheptane
ND
ND
2.2 E-02
591-76-4
2-Methylhexane
ND
ND
1.9 E-02
589-34-4
3 -Methy lhexane
ND
ND
1.9 E-02
66-27-3
Methyl methanesulfonate
ND
ND
1.4 E-03
107-83-5
2-Methylpentane
ND ¦¦¦'
ND
1.6 E-02
96-14-0
3-Methylpentane
ND
ND
1.6 E-02
88-74-4
2-Nitroaniline
ND
ND
1.3 E-03
99-09-2
3-Nitroaniline
ND
ND
5.3 E-03
10595-95-6
N -Nitrosomethylethylamine
ND
ND
2.2 E-03
930-55-2
N-Nitrosopyrrolidine
ND
ND
1.3 E-03
88-72-2
2-Nitrotoluene
ND
ND
9.7 E-04
630-03-5
Nonacosane1
6.0 E-07
1.7 E-05
--
111-84-2
n-Nonane
ND
ND
2.4 E-02
111-65-9
n-Octane8
ND
ND
2.2 E-02
71005-15-7
Pentadecane, 8-heptyl-1
8.3 E-07
2.4 E-05
--
78-78-4
i-Pentane
ND
ND
1.4 E-02
109-66-0
n-Pentane8
ND
ND
1.4 E-02
109-67-1
1-Pentene8
ND
ND
1.3 E-02
627-20-3
cis-2-Pentene8
ND
ND
1.3 E-02
646-04-8
trans-2-Pentene
ND
ND
1.3 E-02
14797-73-0
Perchlorate
ND
ND
1.3 E-03
78-11-5
PETN
ND
ND
1.0 E-03
62-44-2
Phenacetin
ND
ND
1.3 E-03
80-56-8
alpha-Pinene
ND
ND
2.6 E-02
6/08
Ordnance Detonation
A-39
-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
127-91-3
beta-Pinene
ND
ND
2.6 E-02
74-98-6
Propanef
ND
ND
2.2 E-02
103-65-1
n-Propylbenzene8
ND
ND
6.0 E-03
121-82-4
RDX
ND
ND
1.3 E-04
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.3 E-03
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
1.7 E-03
109-99-9
T etrahy drofuran8
ND
ND
3.6 E-03
529-20-4
o-Tolualdehyde
ND
ND
5.0 E-02
526-73-8
1,2,3 -T rimethylbenzene
ND
ND
2.3 E-02
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
6.0 E-03
565-75-3
2,3,4-Trimethylpentane
ND
ND
2.2 E-02
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
1.3 E-03
118-96-7
2,4,6-Trinitrotoluene
ND
ND
1.9 E-04
1120-21-4
Undecane
ND
ND
3.0 E-02
110-62-3
Valeraldehyde8
ND
ND
5.0 E-02
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 3.12 E-02 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a B rating.
J Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
k Emission factor for a tentatively identified compound, but because of correlation with emission factors
for similar ordnance and number of data points the factor was upgraded from a D rating to a B rating.
1 Emission factor rated D because the factor is for a tentatively identified compound.
A-40
Ordnance Detonation
6/08
-------
TABLE A5 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC L410, M206 AIRCRAFT COUNTERMEASURE FLARE
Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxidef
1.1 E-02
3.4 E-02
--
630-08-0
Carbon monoxidef
1.3 E-03
4.2 E-03
--
--
Oxides of nitrogen8
1.3 E-04
4.3 E-04
--
~
PM-2.5
6.2 E-03
2.0 E-02
--
~
PM-108
6.2 E-03
2.0 E-02
--
7446-09-5
Sulfur dioxide8
7.9 E-06
2.6 E-05
--
--
Total nonmethane hydrocarbons8
4.0 E-04
1.3 E-03
--
12789-66-1
Total suspended particulatef
8.6 E-03
2.8 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.3 E-03
208-96-8
Acenaphthylene
ND
ND
1.3 E-03
75-05-8
Acetonitrile
ND
ND
1.9 E-02
98-86-2
Acetophenone
ND ,
ND
6.3 E-03
53-96-3
2-Acetylam i nofl uorene
^ ND
ND
1.3 E-03
107-02-8
Acrolein8
; ND
ND
1.0 E-02
107-13-1
Acrylonitrile8
ND
ND
9.5 E-03
107-05-1
Allyl chloride
ND
ND
1.4 E-02
92-67-1
4-Aminobiphenyl
ND
ND
2.6 E-02
7664-41-7
Ammonia
ND
ND
4.9 E-02
62-53-3
Aniline
ND
ND
1.9 E-02
120-12-7
Anthracene
ND
ND
1.3 E-03
71-43-2
Benzenef
8.4 E-06
2.8 E-05
--
92-87-5
Benzidine
ND
ND
1.3 E-01
56-55-3
Benzo [a] anthracene
ND
ND
1.5 E-03
205-99-2
Benzo [b] fluoranthene
ND
ND
2.9 E-03
207-08-9
Benzo [k] fluoranthene
ND
ND
1.6 E-03
191-24-2
Benzo [g,h,i]perylene
ND
ND
4.2 E-03
50-32-8
Benzo [a]pyrene
ND
ND
1.3 E-03
100-44-7
Benzyl chloride
ND
ND
5.8 E-03
7440-41-7
Beryllium
ND
ND
2.3 E-04
75-25-2
Bromoform
ND
ND
1.2 E-02
74-83-9
Bromomethane
ND
ND
4.3 E-03
6/08
Ordnance Detonation
A-41
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
101-55-3
4-Bromophenylphenylether
ND
ND
1.3 E-03
106-99-0
1,3-Butadienef
4.3 E-07
1.4 E-06
--
71-36-3
n-Butanol
ND
ND
1.3 E-02
85-68-7
Butylbenzylphthalate
ND
ND
1.6 E-03
123-72-8
Butyraldehyde
ND
ND
1.3 E-02
7440-43-9
Cadmium8
8.2 E-08
2.7 E-07
--
86-74-8
Carbazole
ND
ND
1.7 E-03
75-15-0
Carbon disulfide8
1.5 E-07
4.8 E-07
--
56-23-5
Carbon tetrachloride8
ND
ND
7.0 E-03
106-47-8
4-Chloroaniline
ND
ND
1.6 E-02
108-90-7
Chlorobenzene
ND
ND
5.2 E-03
75-00-3
Chloroethane
ND
ND
3.0 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.3 E-03
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.5 E-03
67-66-3
Chloroform
ND
ND
5.4 E-03
108-60-1
bis(2-Chloroisopropvl)ether
ND ¦¦¦'
ND
2.0 E-03
74-87-3
Chloromethane
ND
ND
9.0 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.3 E-03
7005-72-3
4-Chlorophenylphenyl ether
ND
ND
1.3 E-03
7440-47-3
Chromium8
6.6 E-07
2.2 E-06
--
218-01-9
Chrysene
ND
ND
1.7 E-03
7440-48-4
Cobalt8
ND
ND
1.3 E-03
4170-30-3
Crotonaldehyde
ND
ND
5.0 E-02
98-82-8
Cumene
ND
ND
5.5 E-03
110-82-7
Cyclohexane
ND
ND
3.8 E-03
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.6 E-03
132-64-9
Dibenzofuran
ND
ND
1.3 E-03
106-93-4
1,2-Dibromoethane
ND
ND
8.6 E-03
84-74-2
Dibutylphthalate
ND
ND
2.6 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.7 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.7 E-03
106-46-7
1,4-Dichlorobenzene
ND
ND
6.7 E-03
91-94-1
3,3 '-Dichlorobenzidine
ND
ND
1.9 E-02
75-27-4
Dichlororobromomethane
ND
ND
7.5 E-03
75-71-8
Dichlorodifluoromethane
ND
ND
5.5 E-03
A-42
Ordnance Detonation
6/08
-------
TABLE A5 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
75-34-3
1,1 -Dichloroethane
ND
ND
4.5 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.5 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.3 E-03
78-87-5
1,2-Dichloropropane
ND
ND
5.2 E-03
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
ND
5.1 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.8 E-03
60-11-7
p-Dimethylaminoazobenzene
ND
ND
1.3 E-03
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
ND
1.3 E-03
119-93-7
3,3 '-Dimethylbenzidine
ND
ND
1.3 E-01
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.3 E-03
99-65-0
1,3 -Dinitrobenzene
ND
ND
1.6 E-03
534-52-1
4,6-Dinitro-o-cresol
ND
ND
2.3 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
5.8 E-02
121-14-2
2,4-Dinitrotolucnc
ND
ND
1.3 E-03
606-20-2
2,6-Dinitrotolucnc
1.7 H-08
5.4 E-08
--
88-85-7
Dinoseb
:: ND
ND
2.6 E-03
123-91-1
1,4-Dioxane
ND
ND
1.6 E-02
--
Total dioxin/furan compounds
2.7E-11
8.7E-11
--
122-39-4
Diphenylamine
ND
ND
1.3 E-03
122-66-7
1,2-Diphenylhydrazine
ND
ND
1.3 E-03
100-41-4
Ethylbenzene8
ND
ND
4.9 E-03
74-85-1
Ethylene1
1.6 E-05
5.2 E-05
--
117-81-7
bis(2-Ethylhexyl)phthalate8
2.4 E-06
7.8 E-06
--
206-44-0
Fluoranthene
ND
ND
1.4 E-03
86-73-7
Fluorene
ND
ND
1.3 E-03
50-00-0
Formaldehyde8
2.3 E-06
7.5 E-06
--
76-13-1
Freon 113
ND
ND
8.6 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
3.2 E-12
1.1 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
7.9 E-09
118-74-1
Hexachlorobenzene
ND
ND
1.3 E-03
87-68-3
Hexachlorobutadiene
ND
ND
4.7 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
2.6 E-02
6/08
Ordnance Detonation
A-43
-------
TABLE A5 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
7.9 E-09
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
7.9 E-09
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
7.9 E-09
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
ND
ND
2.6 E-09
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
2.6 E-09
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
5.3 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
5.3 E-09
67-72-1
Hexachloroethane
ND
ND
1.4E-03
110-54-3
Hexaneh
3.7 E-08
1.2 E-07
--
7647-01-0
Hydrochloric acid
ND
ND
7.4 E-02
74-90-8
Hydrogen cyanide
9.0 E-06
2.9 E-05
--
193-39-5
Indeno [ 1,2.3 -cdjpv rene
ND
ND
1.4 E-03
78-59-1
Isophorone
ND
ND
1.3 E-03
67-63-0
Isopropyl alcohol
ND
ND
1.1 E-02
120-58-1
Isosafrole
• ; ND
ND
1.3 E-03
7439-97-6
Mercury
ND
ND
3.6E-04
126-98-7
Methacrylonitrile
ND
ND
1.2 E-02
96-33-3
Methyl acrylate
ND
ND
1.5 E-02
56-49-5
3 -Methy lcholanthrene
ND
ND
1.3 E-03
75-09-2
Methylene chloride
7.8 E-06
2.6 E-05
--
108-10-1
Methyl isobutyl ketone
ND
ND
4.6 E-03
80-62-6
Methyl methacrylate
ND
ND
1.8 E-02
91-57-6
2-Methylnaphthalene8
ND
ND
1.3 E-03
95-48-7
2-Methylphenol
ND
ND
7.9 E-03
1634-04-4
Methyl tert-butyl ether
ND
ND
4.0 E-03
91-20-3
Naphthalene8
ND
ND
2.3 E-02
134-32-7
1 -Naphthylamine
ND
ND
2.6 E-02
91-59-8
2-Naphthylamine
ND
ND
2.6 E-02
100-01-6
4-Nitroaniline
ND
ND
5.3 E-03
98-95-3
Nitrobenzene
ND
ND
1.1 E-03
55-63-0
Nitroglycerin
ND
ND
9.4 E-04
88-75-5
2-Nitrophenol
ND
ND
1.3 E-03
100-02-7
4-Nitrophenol
ND
ND
8.7 E-03
A-44
Ordnance Detonation
6/08
-------
TABLE A5 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
79-46-9
2-Nitropropane
ND
ND
1.6E-02
924-16-3
N-Nitroso-di-n-butylamine
ND
ND
1.3 E-03
55-18-5
N-Nitrosodiethylamine
ND
ND
1.3 E-03
62-75-9
N-Nitrosodimethylamine
ND
ND
1.3 E-03
86-30-6
N-Nitrosodiphenylamine
ND
ND
2.3 E-03
621-64-7
N-Nitroso-di-n-propylamine
ND
ND
1.3 E-03
59-89-2
N-Nitrosomorpholine
ND
ND
1.3 E-03
100-75-4
N-Nitrosopiperidine
ND
ND
1.3 E-03
99-55-8
5 -Nitro-o-toluidine
ND
ND
2.1 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxinh
1.8 E-ll
5.8 E-ll
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
5.5 E-12
1.8 E-ll
--
608-93-5
Pentachlorobenzene
ND
ND
1.3 E-03
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
5.3 E-09
57117-41-6
1,2,3,7,8-Pentachlorodibenzofuran
• •. ND
ND
2.6 E-09
57117-31-4
2,3,4,7,8-Pcntachlorodibenzofuran
: ND
ND
2.6 E-09
76-01-7
Pentachloroethane
ND
ND
1.3 E-03
82-68-8
Pentachloronitrobenzene
ND
ND
1.3 E-03
87-86-5
Pentachlorophenol
ND
ND
6.6 E-02
85-01-8
Phenanthrene
ND
ND
1.3 E-03
108-95-2
Phenol8
0
0
--
115-07-1
Propylenef
8.7 E-06
2.8 E-05
--
129-00-0
Pyrene
ND
ND
1.4 E-03
110-86-1
Pyridine
ND
ND
1.9 E-03
94-59-7
Safrole
ND
ND
1.3 E-03
7782-49-2
Selenium
ND
ND
9.0 E-04
7440-22-4
Silver
ND
ND
1.8 E-03
100-42-5
Styrene8
2.9 E-07
9.7 E-07
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-
dioxin8
ND
ND
5.3 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
ND
ND
2.6 E-09
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.7 E-03
127-18-4
T etrachloroethy lene
ND
ND
7.6 E-03
108-88-3
Toluene8
2.6 E-07
8.4 E-07
--
6/08
Ordnance Detonation
A-45
-------
TABLE A5 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
95-53-4
o-Toluidine
ND
ND
1.7 E-02
120-82-1
1,2,4-Trichlorobenzene
ND
ND
3.2 E-02
71-55-6
1,1,1 -T richloroethane
ND
ND
6.1 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
6.1 E-03
79-01-6
Trichloroethylene
ND
ND
6.0 E-03
75-69-4
Trichlorofluoromethane
ND
ND
6.3 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
3.4 E-03
88-06-2
2,4,6-Trichlorophenol
ND
ND
2.0 E-03
96-18-4
1,2,3 -T richloropropane
ND
ND
2.6 E-02
95-63-6
1,2,4-Trimethylbenzene
ND
ND
5.5 E-03
540-84-1
2,2,4-Trimethylpentane
ND
ND
2.0 E-02
108-05-4
Vinyl acetate
ND
ND
1.5 E-02
75-01-4
Vinyl chloride
ND
ND
1.5 E-02
75-35-4
Vinylidene chloride
ND
ND
4.4 E-03
106-42-3,
108-38-3
m-Xylene, p-Xylcnce
ND
ND
4.9 E-03
95-47-6
o-Xylene
;. NE)
ND
4.9 E-03
7440-66-6
Zinc
3 .2 E-05
1.1 E-04
—
Other Po
lutants
67-64-1
Acetonef
3.7 E-06
1.2 E-05
--
74-86-2
Acetylenef
5.8 E-05
1.9 E-04
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
1.9 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
1.9 E-04
100-52-7
Benzaldehyde8
ND
ND
5.0 E-02
84-69-5
1,2-Benzenedicarboxylic acid, bis(2-
methyl propy l)esterk
6.9 E-07
2.3 E-06
--
17851-53-5
1,2-Benzenedicarboxylic acid, butyl
2-methylk
7.8 E-07
2.6 E-06
--
65-85-0
Benzoic acid
ND
ND
1.2E-01
100-51-6
Benzyl alcohol
ND
ND
9.2 E-02
106-98-9
1-Butene1
1.3 E-06
4.1 E-06
--
590-18-1
cis-2-Butenef
4.3 E-07
1.4 E-06
--
624-64-6
trans-2-Butenef
4.6 E-07
1.5 E-06
--
107-14-2
Chloroacetonitrile
ND
ND
3.5 E-03
2698-41-1
o-chlorobenzalmalononitrile
ND
ND
2.6 E-03
109-69-3
1-Chlorobutane
ND
ND
4.2 E-02
A-46
Ordnance Detonation
6/08
-------
TABLE A5 (cont.)
Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.6 E-03
90-13-1
1 -Chloronaphthalene
ND
ND
1.3 E-03
95-57-8
2-Chlorophenol
ND
ND
1.3 E-03
287-92-3
Cyclopentane
ND
ND
1.3 E-02
142-29-0
Cyclopentenek
2.9 E-06
9.6 E-06
--
124-18-5
n-Decane
ND
ND
2.5 E-02
124-48-1
Dibromochloromethane
ND
ND
9.5 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.4 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
5.1 E-03
87-65-0
2,6-Dichlorophenol
ND
ND
1.3 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
5.1 E-03
141-93-5
1,3 -Diethylbenzene
ND
ND
2.4 E-02
105-05-5
1,4-Diethylbenzene
ND
ND
2.4 E-02
5779-94-2
2,5-Dimethv lbenzal dehvde
ND
ND
1.0 E-01
75-83-2
2,2-Dimethylbutane
ND
ND
1.5 E-02
79-29-8
2,3-Dimethylbutane
ND
ND
1.5 E-02
565-59-3
2,3-Dimethylpentane
':: ND
ND
1.8 E-02
108-08-7
2,4-Dimethylpentane
ND
ND
1.8 E-02
117-84-0
Di-n-octylphthalate
ND
ND
1.5 E-03
74-84-0
Ethanef
6.3 E-06
2.1 E-05
--
64-17-5
Ethanol
ND
ND
8.2 E-03
60-29-7
Ethyl ether
ND
ND
1.3 E-02
97-63-2
Ethyl methacrylate
ND
ND
5.2 E-02
62-50-0
Ethyl methane sulfonate
ND
ND
1.3 E-03
620-14-4
m-Ethyltoluene8
ND
ND
2.2 E-02
611-14-3
o-Ethyltoluene8
ND
ND
2.2 E-02
622-96-8
p-Ethyltoluenef
ND
ND
5.5 E-03
593-49-7
Heptacosanek
9.1 E-07
3.0 E-06
--
142-82-5
n-Heptane
ND
ND
4.6 E-03
1888-71-7
Hexachloropropene
ND
ND
1.9 E-03
544-76-3
Hexadecanek
2.2 E-07
7.2 E-07
--
66-25-1
Hexaldehyde
ND
ND
5.0 E-02
103-23-1
Hexanedioic acid, bis(2-ethylhexyl)
ester1^
4.1 E-07
1.3 E-06
""
591-78-6
2-Hexanone
ND
ND
1.8 E-02
6/08
Ordnance Detonation
A-47
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
592-41-6
1-Hexene8
ND
ND
1.5 E-02
2691-41-0
HMX
1.4 E-05
4.7 E-05
--
75-28-5
Isobutane8
4.1 E-06
1.3 E-05
--
78-79-5
Isoprene
ND
ND
1.2 E-02
590-86-3
Isovaleraldehyde
ND
ND
5.0 E-02
5989-27-5
d-Limonene
ND
ND
2.4 E-02
7439-95-4
Magnesiumf
2.8 E-03
9.0 E-03
--
108-87-2
Methylcyclohexane
ND
ND
1.8 E-02
96-37-7
Methylcyclopentane
ND
ND
1.5 E-02
78-93-3
Methyl ethyl ketone8
ND
ND
3.3 E-03
592-27-8
2-Methylheptane8
ND
ND
2.0 E-02
589-81-1
3 -Methy lheptane
ND
ND
2.0 E-02
591-76-4
2-Methylhexane
ND
ND
1.8 E-02
589-34-4
3 -Methy lhexane
ND
ND
1.8 E-02
66-27-3
Methyl methanesulfonate
ND
ND
1.4 E-03
107-83-5
2-Methylpentane
ND ¦¦¦'
ND
1.5 E-02
96-14-0
3-Methylpentane
ND
ND
1.5 E-02
88-74-4
2-Nitroaniline
ND
ND
1.3 E-03
99-09-2
3-Nitroaniline
ND
ND
5.3 E-03
10595-95-6
N -Nitrosomethylethylamine
ND
ND
2.2 E-03
930-55-2
N-Nitrosopyrrolidine
ND
ND
1.3 E-03
88-72-2
2-Nitrotolueneh
1.9 E-07
6.1 E-07
--
99-99-0
4-Nitrotoluene
ND
ND
8.1 E-04
630-03-5
Nonacosanek
8.1 E-07
2.6 E-06
--
111-84-2
n-Nonane
ND
ND
2.3 E-02
630-02-4
Octacosanek
2.5 E-07
8.2 E-07
--
111-65-9
n-Octane8
ND
ND
2.0 E-02
629-62-9
Pentadecanek
1.9 E-07
6.3 E-07
--
78-78-4
i-Pentane
4.0 E-07
1.3 E-06
--
109-66-0
n-Pentane8
2.5 E-07
8.1 E-07
--
109-67-1
1-Pentene8
ND
ND
1.3 E-02
627-20-3
cis-2-Pentene8
ND
ND
1.3 E-02
646-04-8
trans-2-Pentene
ND
ND
1.3 E-02
14797-73-0
Perchlorate
ND
ND
1.0 E-03
78-11-5
PETN
ND
ND
1.0 E-03
A-48
Ordnance Detonation
6/08
-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
62-44-2
Phenacetin
ND
ND
1.3 E-03
80-56-8
alpha-Pinene
ND
ND
2.4 E-02
127-91-3
beta-Pinene
ND
ND
2.4 E-02
74-98-6
Propanef
2.8 E-06
9.1 E-06
--
115-11-7
1-Propene, 2-methyl -
1.9 E-06
6.3 E-06
--
103-65-1
n-Propylbenzene8
ND
ND
5.5 E-03
74-99-7
l-Propynek
1.0 E-04
3.3 E-04
--
121-82-4
RDX
ND
ND
1.3 E-04
95-94-3
1,2,4,5-Tetrachlorobenzene
ND
ND
1.3 E-03
58-90-2
2,3,4,6-Tetrachlorophenol
ND
ND
1.7 E-03
629-59-4
Tetradecanek
5.6 E-07
1.8 E-06
--
109-99-9
T etrahy drofuran8
1.3 E-07
4.3 E-07
--
14167-59-0
T etratriacontanek
6.7 E-07
2.2 E-06
--
529-20-4
o-Tolualdehyde
ND
ND
5.0 E-02
526-73-8
1,2,3-Trimethylbcnzenc
ND
ND
2.1 E-02
108-67-8
1,3,5-Trimethylbcnzene
ND
ND
5.5 E-03
565-75-3
2,3,4-Trimethylpcntanc
':: ND
ND
2.0 E-02
99-35-4
1,3,5 -Trinitrobenzene
ND
ND
1.3 E-03
118-96-7
2,4,6-Trinitrotoluene
ND
ND
1.9 E-04
1120-21-4
Undecane
ND
ND
2.8 E-02
110-62-3
Valeraldehyde8
ND
ND
5.0 E-02
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 2.84 E-01 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor rated D because the factor is based upon C-rated test data.
1 Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a B rating.
J Emission factor for a tentatively identified compound, but because of correlation with emission factors
for similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
k Emission factor rated D because the factor is for a tentatively identified compound.
6/08
Ordnance Detonation
A-49
-------
TABLE A6 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC L508, M72 RED RAILROAD WARNING FUSEE
Emission
Minimum
CASRN3
Compound
Factor
Detection Level
lb per itemb c
mg/m3,d
Carbon Dioxide, Criteria Pollutants, Total Nonmethane Hydrocarbons,
and Total Suspended Particulates
124-38-9
Carbon dioxidef
8.5 E-02
--
630-08-0
Carbon monoxidef
2.1 E-03
--
--
Oxides of nitrogen6
9.7 E-03
~
--
PM-2.56
4.4 E-03
~
--
PM-10f
4.6 E-03
--
7446-09-5
Sulfur dioxide
5.6 E-03
~
~
Total nonmethane hydrocarbonsf
2.6 E-04
~
12789-66-1
Total suspended particulate6
4.9 E-03
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
9.1 E-04
208-96-8
Acenaphthylene
5.0 E-08
--
75-07-0
Acctaldchyde1
ND '
1.4 E-02
75-05-8
Acetonitrile
3 .4 E-06
~
98-86-2
Acctophcnone1
; 5.7E-07
~
53-96-3
2-Acetylaminofluorene
ND
9.1 E-04
107-02-8
Acroleinf
9.0 E-06
--
107-13-1
Acrylonitrile
9.3 E-07
~
107-05-1
Allyl chloride
ND
1.4 E-02
92-67-1
4-Aminobiphenyl
ND
1.8 E-02
7664-41-7
Ammonia
6.7 E-06
--
62-53-3
Aniline
ND
1.3 E-02
120-12-7
Anthracene
ND
9.1 E-04
71-43-2
Benzene
2.7 E-05
--
92-87-5
Benzidine
ND
9.3 E-02
56-55-3
Benzo [a] anthracene
ND
1.1 E-03
205-99-2
Benzo [b] fluoranthene
ND
2.0 E-03
207-08-9
Benzo [kjfluoranthene
ND
1.1 E-03
191-24-2
Benzo [g,h,i]perylene
ND
2.9 E-03
50-32-8
Benzo [a]pyrene
ND
9.1 E-04
100-44-7
Benzyl chloride
ND
5.8 E-03
7440-41-7
Beryllium
ND
1.8 E-04
75-25-2
Bromoform
ND
1.2 E-02
A-50
Ordnance Detonation
6/08
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
74-83-9
Bromomethane
ND
4.3 E-03
101-55-3
4-Bromophenylphenylether
ND
9.1 E-04
106-99-0
1,3-Butadiene
ND
2.5 E-03
71-36-3
n-Butanol
ND
1.3 E-02
85-68-7
Butylbenzylphthalate
ND
1.1 E-03
123-72-8
Butyraldehyde
ND
3.6 E-02
86-74-8
Carbazole
ND
1.2 E-03
75-15-0
Carbon disulfidef
1.2 E-06
--
56-23-5
Carbon tetrachloride
ND
7.0 E-03
106-47-8
4-Chloroaniline
ND
1.1 E-02
108-90-7
Chlorobenzene
ND
5.2 E-03
75-00-3
Chloroethane
ND
3.0 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
9.1 E-04
111-44-4
bis(2-Chloroethvl)ether
ND
1.0 E-03
67-66-3
Chloroform
ND
5.4 E-03
108-60-1
bis(2-Chloroisopropyl)ether
ND
1.4 E-03
74-87-3
Chloromethane
ND
9.0 E-03
91-58-7
2-Chloronaphthalene
ND
9.1 E-04
7005-72-3
4-Chlorophenylphenyl ether
ND
9.1 E-04
7440-47-3
Chromium
3.7 E-07
--
218-01-9
Chrysene
ND
1.2 E-03
7440-48-4
Cobalt
ND
1.0 E-03
4170-30-3
Crotonaldehyde
ND
3.6 E-02
98-82-8
Cumene
ND
5.5 E-03
110-82-7
Cyclohexane
ND
3.8 E-03
53-70-3
Dibenz [a,h] anthracene
ND
1.1 E-03
132-64-9
Dibenzofuran
7.2 E-08
--
106-93-4
1,2-Dibromoethane
ND
8.6 E-03
84-74-2
Dibutylphthalate
ND
1.8 E-02
95-50-1
1,2-Dichlorobenzene
ND
6.7 E-03
541-73-1
1,3 -Dichlorobenzene
ND
6.7 E-03
106-46-7
1,4-Dichlorobenzene
ND
6.7 E-03
91-94-1
3,3 '-Dichlorobenzidine
ND
1.3 E-02
75-27-4
Dichlororobromomethane
ND
7.5 E-03
75-71-8
Dichlorodifluoromethanef
ND
5.5 E-03
6/08
Ordnance Detonation
A-51
-------
TABLE A6 (cont.)
Emission
Minimum
CASRN3
Compound
Factor
lb per itemb,c
Detection Level
mg/m3'd
75-34-3
1,1 -Dichloroethane
ND
4.5 E-03
107-06-2
1,2-Dichloroethane
ND
4.5 E-03
120-83-2
2,4-Dichlorophenol
ND
9.1 E-04
78-87-5
1,2-Dichloropropane
ND
5.2 E-03
10061-02-6
trans-1,3 -Dichloro-1 -propene
ND
5.1 E-03
76-14-2
Dichlorotetrafluoroethane
ND
7.8 E-03
60-11-7
p-Dimethylaminoazobenzene
ND
9.1 E-04
57-97-6
7,12-Dimethylbenz[a]anthracene
ND
9.3 E-04
119-93-7
3,3 '-Dimethylbenzidine
ND
9.1 E-02
105-67-9
2,4-Dimethylphenol
ND
1.1 E-02
131-11-3
Dimethyl phthalate
ND
9.1 E-04
99-65-0
1,3 -Dinitrobenzene
ND
9.5 E-04
534-52-1
4,6-Dinitro-o-cresol
ND
1.6 E-02
51-28-5
2,4-Dinitrophenol
ND
4.0 E-02
121-14-2
2,4-Dinitrotolucnc
ND
2.1 E-04
606-20-2
2,6-Dinitrotolucnc
ND
3.0 E-04
88-85-7
Dinoscb
ND
1.8 E-03
123-91-1
1,4-Dioxane
Total dioxin/furan compounds
ND
1.5 E-ll
1.6 E-02
122-39-4
Diphenylamine
ND
9.1 E-04
122-66-7
1,2-Diphenylhydrazine
ND
9.1 E-04
100-41-4
Ethylbenzene
6.2 E-07
--
74-85-1
Ethylenef
9.8 E-05
--
117-81-7
bis(2-Ethylhexyl)phtlialate8
4.4 E-07
--
206-44-0
Fluoranthene
ND
9.8 E-04
86-73-7
Fluorene
3.3 E-08
--
50-00-0
Formaldehyde
3.8 E-07
--
76-13-1
Freon 113
ND
8.6 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
3.6 E-12
~
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
5.6E-09
118-74-1
Hexachlorobenzene
ND
9.1 E-04
87-68-3
Hexachlorobutadiene
ND
4.7 E-02
77-47-4
Hexachlorocyclopentadiene
ND
1.8 E-02
A-52
Ordnance Detonation
6/08
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
3.7E-09
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
3.7E-09
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
3.7E-09
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
3.7E-09
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
3.7E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
1.9E-09
67-72-1
Hexachloroethane
ND
9.8 E-04
110-54-3
Hexane
ND
3.9E-03
7647-01-0
Hydrochloric acidf
9.0 E-05
--
74-90-8
Hydrogen cyanide
ND
4.6 E-02
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
9.8 E-04
78-59-1
Isophorone
ND
9.1 E-04
67-63-0
Isopropvl alcohol
ND
1.1 E-02
120-58-1
Isosafrole
ND
9.1 E-04
7439-97-6
Mercury
ND
2.9 E-04
126-98-7
Methacrylonitrile
ND
1.2 E-02
96-33-3
Methyl acrylate
ND
1.5 E-02
56-49-5
3 -Methylcholanthrene
ND
9.1 E-04
75-09-2
Methylene chloride8
2.0 E-06
--
108-10-1
Methyl isobutyl ketone
ND
4.6 E-03
80-62-6
Methyl methacrylate
ND
1.8 E-02
91-57-6
2-Methylnaphthalene
3.8E-07
--
95-48-7
2-Methylphenol
ND
5.5 E-03
1634-04-4
Methyl tert-butyl ether
ND
4.0 E-03
91-20-3
Naphthalene
1.6 E-06
--
134-32-7
1 -Naphthylamine
ND
1.8 E-02
91-59-8
2-Naphthylamine
ND
1.8 E-02
7440-02-0
Nickel
3.8 E-07
--
100-01-6
4-Nitroaniline
ND
3.6 E-03
98-95-3
Nitrobenzene
ND
1.0 E-03
55-63-0
Nitroglycerin8
2.6 E-07
~
88-75-5
2-Nitrophenol
7.1 E-07
~
100-02-7
4-Nitrophenol
6.1 E-07
--
6/08
Ordnance Detonation
A-53
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
79-46-9
2-Nitropropane
ND
1.6E-02
924-16-3
N-Nitroso-di-n-butylamine
ND
9.1 E-04
55-18-5
N-Nitrosodiethylamine
ND
9.1 E-04
62-75-9
N-Nitrosodimethylamine
ND
9.1 E-04
86-30-6
N-Nitrosodiphenylamine
ND
1.6E-03
621-64-7
N-Nitroso-di-n-propylamine
ND
9.1 E-04
59-89-2
N-Nitrosomorpholine
ND
9.1 E-04
100-75-4
N-Nitrosopiperidine
ND
9.1 E-04
99-55-8
5 -Nitro-o-toluidine
ND
1.5 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
dioxin
8.0 E-12
~
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
3.0 E-12
~
608-93-5
Pentachlorobenzene
ND
9.1 E-04
40321-76-4
1,2.3,7,8 - Pc ntach 1 o rod i benzo-p-
dioxin
ND
3.7E-09
57117-41-6
1,2.3,7,8-Pcntachlorodibcnzoturan
ND
1.9E-09
57117-31-4
2,3,4,7,8-Pcntachlorodibcnzotiiran
ND
3.6E-09
76-01-7
Pentachloroethane
ND
9.1 E-04
82-68-8
Pentachloronitrobenzene
ND
9.1 E-04
87-86-5
Pentachlorophenol
ND
4.5 E-02
85-01-8
Phenanthrene
8.0E-08
--
108-95-2
Phenolf
5.0 E-07
--
123-38-6
Propionaldehyde
ND
3.6 E-02
115-07-1
Propylene6
3.5 E-05
--
129-00-0
Pyrene
ND
9.6 E-04
110-86-1
Pyridine
ND
1.3 E-03
94-59-7
Safrole
ND
9.1 E-04
7782-49-2
Selenium
ND
7.1 E-04
7440-22-4
Silver
ND
1.4 E-03
100-42-5
Styrenef
ND
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
3.6E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran8
1.3 E-13
~
79-34-5
1,1,2,2-Tetrachloroethane
ND
7.7 E-03
127-18-4
T etrachloroethy lene
ND
7.6 E-03
7440-28-0
Thallium
7.1 E-08
--
A-54
Ordnance Detonation
6/08
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
108-88-3
Toluene
6.4 E-06
--
95-53-4
o-Toluidine
ND
1.2 E-02
120-82-1
1,2,4-Trichlorobenzene
ND
3.2E-02
71-55-6
1,1,1 -Trichloroethane
ND
6.1 E-03
79-00-5
1,1,2-Trichloroethane
ND
6.1 E-03
79-01-6
Trichloroethylene
ND
6.0 E-03
75-69-4
Trichlorofluoromethane
ND
6.3 E-03
95-95-4
2,4,5-Trichlorophenol
ND
2.4 E-03
88-06-2
2,4,6-Trichlorophenol
ND
1.4 E-03
96-18-4
1,2,3 -T richloropropane
ND
2.6 E-02
95-63-6
1,2,4-Trimethylbenzene
ND
5.5 E-03
540-84-1
2,2,4-Trimethylpentane
ND
2.0 E-02
108-05-4
Vinyl acetate
ND
1.5 E-02
75-01-4
Vinyl chloride
ND
1.5 E-02
75-35-4
Vinylidene chloride
ND
4.4 E-03
106-42-3,
108-38-3
m-Xylene. p-Xylene
9.2 11-07
--
95-47-6
o-Xylene
5.0 E-07
--
7440-66-6
Zincf
7.7 E-06
--
Other Pollutants
67-64-1
Acetone
ND
3.6 E-02
74-86-2
Acetylenef
9.1 E-06
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
1.3 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
1.3 E-04
100-52-7
Benzaldehyde
ND
3.6 E-02
84-69-5
1,2-Benzenedicarboxylic acid, bis(2-
methyl propyl)esterh
9.9 E-07
--
17851-53-5
1,2-Benzenedicarboxylic acid, butyl
2-methylh
8.1 E-07
~
98-29-3
1,2-Benzenediol, 4-(l,l-
dimethylethyl)-h
1.3 E-06
65-85-0
Benzoic acid
1.8E-05
~
100-51-6
Benzyl alcohol
ND
6.4 E-02
106-98-9
1-Butene
5.1 E-06
--
107-01-7
2-Buteneh
1.7 E-06
~
590-18-1
cis-2-Butene
6.2 E-07
~
6/08
Ordnance Detonation
A-55
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
624-64-6
trans-2-Butenef
9.9 E-07
--
107-14-2
Chloroacetonitrile
ND
3.5 E-03
2698-41-1
o-chlorobenzalmalononitrile
ND
1.8E-03
109-69-3
1-Chlorobutane
ND
4.2 E-02
59-50-7
4-Chloro-3-methylphenol
ND
1.1 E-03
90-13-1
1 -Chloronaphthalene
ND
9.1 E-04
95-57-8
2-Chlorophenol
ND
9.1 E-04
629-20-9
1,3,5,7-Cyclooctatetraeneh
6.9 E-07
--
287-92-3
Cyclopentane
ND
1.3 E-02
124-18-5
n-Decane
ND
2.5 E-02
124-48-1
Dibromochloromethane
ND
9.5 E-03
156-59-2
cis-1,2-Dichloroethene
ND
4.4 E-03
156-60-5
trans-1,2-Dichloroethene
ND
5.1 E-03
87-65-0
2,6-Dichlorophenol
ND
9.1 E-04
10061-01-5
cis-1,3-Dichloropropene
ND
5.1 E-03
141-93-5
1,3-Dicthylbenzene
ND
2.4 E-02
105-05-5
1,4-Dicthylbcnzene
ND
2.4 E-02
5779-94-2
2,5-Dimethylbenzaldehyde
ND
7.1 E-02
75-83-2
2,2-Dimethylbutane
ND
1.5 E-02
79-29-8
2,3 -Dimethylbutane
ND
1.5 E-02
565-59-3
2,3 -Dimethylpentane
ND
1.8 E-02
108-08-7
2,4-Dimethylpentane
ND
1.8 E-02
117-84-0
Di-n-octylphthalate
ND
1.0 E-03
6418-46-8
Eicosane, 10-methyl-h
7.2 E-07
--
74-84-0
Ethanef
1.7 E-05
--
64-17-5
Ethanol
2.1 E-07
--
619-64-7
4-Ethylbenzoic acidh
4.6 E-07
--
60-29-7
Ethyl ether
ND
1.3 E-02
97-63-2
Ethyl methacrylate
ND
5.2 E-02
62-50-0
Ethyl methanesulfonate
ND
9.1 E-04
620-14-4
m-Ethyltoluene
ND
2.2 E-02
611-14-3
o-Ethyltoluene
ND
2.2 E-02
622-96-8
p-Ethyltoluene
2.5 E-07
--
4100-80-5
2,5-Furandione, dihydro-3-methyl-11
3.5 E-06
--
98-01-1
Furfural11
1.6 E-06
--
A-56
Ordnance Detonation
6/08
-------
TABLE A6 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
593-49-7
Heptacosaneh
8.8 E-07
--
62016-79-9
Heptacosane, l-chloro-h
7.3 E-07
--
54833-48-6
Heptadecane, 2,6,10,15-
tetramethyl-h
8.9 E-07
--
142-82-5
n-Heptane
ND
4.6 E-03
1888-71-7
Hexachloropropene
ND
1.3 E-03
57-10-3
n-Hexadecanoic acidh
1.2 E-06
--
66-25-1
Hexaldehyde
ND
3.6E-02
591-78-6
2-Hexanone
ND
1.8E-02
630-06-8
Hexatriacontaneh
8.3 E-07
--
592-41-6
1-Hexene
1.5 E-06
~
78-79-5
Isoprene
ND
1.2E-02
590-86-3
Isovaleraldehyde
ND
3.6E-02
5989-27-5
d-Limonene
ND
2.4 E-02
108-87-2
Methylcvclohcxanc
ND
1.8E-02
96-37-7
Methvlcyclopcntane
: ND
1.5 E-02
78-93-3
Methyl ethyl ketone
J 2.1 E-06
~
592-27-8
2-Methylheptane
ND
2.0 E-02
589-81-1
3 -Methylheptane
ND
2.0 E-02
591-76-4
2-Methylhexane
ND
1.8 E-02
589-34-4
3 -Methylhexane
ND
1.8 E-02
66-27-3
Methyl methane sulfonate
ND
1.0 E-03
107-83-5
2-Methylpentane
ND
1.5 E-02
96-14-0
3 -Methylpentane
ND
1.5 E-02
88-74-4
2-Nitroaniline
ND
9.1 E-04
99-09-2
3-Nitroaniline
ND
3.6 E-03
10595-95-6
N -Nitrosomethylethylamine
ND
1.5 E-03
930-55-2
N-Nitrosopyrrolidine
ND
9.1 E-04
88-72-2
2-Nitrotoluene
ND
6.4 E-04
99-99-0
4-Nitrotoluene8
6.9 E-07
--
111-84-2
n-Nonane
ND
2.3 E-02
630-02-4
Octacosaneh
1.1 E-06
--
593-45-3
Octadecaneh
9.0 E-07
--
111-65-9
n-Octane
ND
2.0 E-02
78-78-4
i-Pentane
ND
1.3 E-02
6/08
Ordnance Detonation
A-57
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TABLE A6 (cont.)
CASRN3
Compound
Emission
Factor
lb per itemb,c
Minimum
Detection Level
mg/m3'd
109-66-0
n-Pentane
ND
1.3 E-02
109-67-1
1-Pentene
ND
1.3 E-02
627-20-3
cis-2-Pentene
ND
1.3 E-02
646-04-8
trans-2-Pentene
ND
1.3 E-02
14797-73-0
Perchlorate
ND
8.2 E-04
78-11-5
PETN8
4.3 E-08
--
62-44-2
Phenacetin
ND
9.1 E-04
80-56-8
alpha-Pinene
ND
2.4 E-02
127-91-3
beta-Pinene
ND
2.4 E-02
74-98-6
Propane
2.9 E-06
--
115-11-7
1-Propene, 2-methyl-h
7.2 E-06
--
103-65-1
n-Propylbenzene
ND
5.5 E-03
121-82-4
RDX8
3.0 E-08
~
95-94-3
1,2,4,5 -T etrachlorobenzene
ND
9.1 E-04
58-90-2
2,3.4.6-Tctrachlorophenol
ND
1.2 E-03
646-31-1
Tetraeosanc'1
8.5 11-07
--
109-99-9
Tetrahvdrofuran
1.2E-07
~
7098-22-8
T etratetracontaneh
6.2 E-07
~
14167-59-0
T etratriacontaneh
8.9 E-07
--
529-20-4
o-Tolualdehyde
ND
3.6 E-02
526-73-8
1,2,3 -T rimethylbenzene
ND
2.1 E-02
108-67-8
1,3,5 -T rimethylbenzene
ND
5.5 E-03
565-75-3
2,3,4-Trimethylpentane
ND
2.0 E-02
99-35-4
1,3,5 -T rinitrobenzene
ND
8.5 E-04
118-96-7
2,4,6-Trinitrotoluene8
1.1 E-07
--
7098-21-7
Tritetracontaneh
3.8 E-07
--
1120-21-4
Undecane
ND
2.8 E-02
110-62-3
Valeraldehyde
ND
3.6 E-02
A-58
Ordnance Detonation
6/08
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TABLE A6 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d Data provided for compounds that were not detected.
e Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
f Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated D because the factor is based upon C-rated test data.
h Emission factor rated D because the factor is for a tentatively identified compound.
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A-60 Ordnance Detonation 6/08
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APPENDIX B
NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN PHASE VI TESTING
AT DUGWAY PROVING GROUND, UTAH
Electronic versions of the new AP-42 sections for ordnance included in Phase VI testing at
Dugway Proving Ground, Utah, are located on the EPA web site at:
http://www.Epa.gov/ttn/chief/ap42/index.html.
6/08
Ordnance Detonation
B-l
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B-2 Ordnance Detonation 6/08
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