BACKGROUND DOCUMENT
REPORT ON REVISIONS TO 5th EDITION AP-42
CHAPTER 15 - ORDNANCE DETONATION
EMISSION FACTORS DEVELOPED BASED ON EXPLODING ORDNANCE EMISSION STUDY
PHASE II SERIES 7 TESTING CONDUCTED AT ABERDEEN PROVING GROUND,
MARYLAND
Prepared for:
U.S. Army Environmental Command
ATTN': IMAE-ATT
Aberdeen Proving Ground, Maryland 21010-5401
February 2008

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NOTICE
The information in this document has been funded by the U.S. Army Environmental Command
(USAEC) and prepared by MACTEC Federal Programs, Inc., under Contract No. GS-10F-0157K, Order
No. W911SR-05-F-0023. It has been reviewed by the U.S. Environmental Protection Agency (EPA)
Office of Air Quality Planning and Standards (OAQPS) and has been approved for publication. Mention
of trade names or commercial products does not constitute endorsement or recommendation for use.

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TABLE OF CONTENTS
1.0 INTRODUCTION	1
2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS	2
2.1	Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide	5
2.2	Sulfur Hexafluoride, Ammonia, Carbon Monoxide, Carbon Dioxide, and Methane	6
2.3	Total Suspended Particulate	6
2.4	Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 or 2.5 Microns .. 6
2.5	Metals	6
2.6	Volatile Organic Compounds	6
2.7	Semivolatile Organic Compounds and Polycyclic Aromatic Hydrocarbons	7
2.8	Dioxin and Furan Compounds	7
2.9	Acid Gases	7
2.10	Hydrogen Cyanide	7
2.11	Aldehyde and Carbonyl Compounds	8
2.12	Hydrocarbons, n-Hexane, and Sulfur Hexafluoride	8
2.13	Energetic Materials	8
2.14	Total Carbon	8
2.15	Hexavalent Chromium	9
2.16	Perchlorate	9
3.0 TEST DATA ANALYSIS AND RATINGS	9
3.1	EPA Guidance Regarding Test Data Quality Ratings	9
3.2	Analysis of Test Data	10
3.3	Test Data Quality Ratings	18
4.0 EMISSION FACTOR CALCULATIONS	22
4.1	Correction of Sample Volume to Standard Conditions	23
4.2	Incorporation of Analytical Detection Limits to the Test Data	23
4.3	Determination of Background Concentration	24
4.4	Determination of Test Compound Concentration	24
4.5	Determination of Background-Corrected Concentration	25
4.6	Determination of Dilution-Corrected Concentration	25
4.7	Determination of Mass of Compound Released	27
4.8	Determination of Emission Factors	27
4.9	Determination of Average Emission Factors	27
5.0 EMISSION FACTOR RATINGS	27
5.1	Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data	28
5.2	Emission Factor Ratings Assigned - Based on All Available Test Data	29
6.0 REFERENCES	38
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TABLE OF CONTENTS (cont.)
APPENDIX A: COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
ORDNANCE INCLUDED IN EXPLODING ORDNANCE EMISSION STUDY
PHASE II SERIES 7 TESTING AT ABERDEEN PROVING GROUND,
MARYLAND
APPENDIX B: NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN EXPLODING
ORDNANCE EMISSION STUDY PHASE II SERIES 7 TESTING AT ABERDEEN
PROVING GROUND, MARYLAND
LIST OF TABLES
No. Title	Page
1	Ordnance for Which Emission Factors Were Developed	1
2	Ordnance Net Explosive Weight	2
3	Sampling and Analytical Methods Used	3
4	Selected Analytical Method for Compounds Analyzed Using Two Analytical Methods	12
5	Compounds for Which Large Relative Percent Differences Were Noted Between Test Runs	14
6	Compounds Found in the Method Blank at Levels Greater Than 50 Percent of Both Test
Values	16
7	Compounds Significantly Exceeding the Holding Times for Extraction and/or Analysis	16
8	Downgraded Data Quality Ratings	18
9	Ordnance Categorization for Emission Factor Correlation Assessment	30
LIST OF FIGURES
No. Title	Page
1 Calculation of background-corrected concentration	26
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1.0 INTRODUCTION
Due to the lack of credible data concerning emissions from training ordnance when used in their
tactical configurations, the U.S. Army Environmental Command (USAEC) established a program to
quantify emissions from the detonation of ordnance. This document presents background information
concerning the development of air emission factors for seven types of ordnance used during training
exercises at U.S. Army installations. The air emission factors were developed from test data collected by
USAEC. Ordnance for which emission factors have been developed and their corresponding AP-42
sections are identified in Table 1. To help readers easily find those emission factors of interest, the
ordnance are organized according to their Department of Defense Identification Code (DODIC).
TABLE 1 ORDNANCE FOR WHICH EMISSION FACTORS WERE DEVELOPED
DODIC
Ordnance Description
AP-42 Section
M130
M6 Electric Blasting Cap
15.9.08
M131
M7 Non-Electric Blasting Cap
15.9.09
ML47
Mil Non-Electric Blasting Cap with 30-foot Shock Tube
15.9.31
MN02
M12 Non-Electric Blasting Cap with 500-foot Shock Tube
15.9.33
MN03
M13 Non-Electric Blasting Cap with 1,000-foot Shock Tube
15.9.34
MN06
M14 Non-Electric Time Delay Blasting Cap
15.9.35
N286
M582 Mechanical Time and Super Quick (MTSQ) Fuse
15.10.3
The emission factors described in this document are based on data obtained during testing
conducted at Aberdeen Proving Ground, Maryland, as presented in the final test report titled Report No. 7
for the Exploding Ordnance Emission Study Phase //' and the document titled Detailed Test Plan No. 7
for the Exploding Ordnance Emission Study Phase II.2 These documents were supplemented by
additional data provided by the testing contractor.3 For each ordnance, two test runs were conducted.
Twenty-five items were detonated per run for DODIC Ml30, 20 items were detonated per run for
DODICs M131 and ML47, 15 items were detonated per run for DODIC MN02, 10 items were detonated
per run for DODICs MN03 and MN06, and 5 items were detonated per run for DODIC N286. Source test
protocols were developed by USAEC before any testing was conducted and were reviewed by the U.S.
Environmental Protection Agency's (EPA's) Emission Measurement Center. The tests were conducted
between August 26 and September 4, 2003.
The compounds that were measured included carbon monoxide (CO), carbon dioxide (C02),
oxides of nitrogen (NOx), sulfur dioxide (S02), ammonia (NH3), methane (CH4), total suspended
particulate (TSP), particulate matter with an aerodynamic diameter less than or equal to 10 microns
(PM-10), particulate matter with an aerodynamic diameter less than or equal to 2.5 microns (PM-2.5),
metals, volatile organic compounds (VOC), semivolatile organic compounds (SVOC), dioxin and fiiran
compounds, acid gases, hydrogen cyanide (HCN), aldehydes and carbonyl compounds, hydrocarbons,
polycyclic aromatic hydrocarbons (PAH), energetic materials, total carbon, hexavalent chromium, and
perchlorate. Within each of the AP-42 sections, only emission factors for criteria pollutants, carbon
dioxide, methane, hazardous air pollutants (as defined by § 112(b)(1) of the Clean Air Act [CAA]), and
toxic chemicals (as defined by §313 of the Emergency Planning and Community Right-to-Know Act
[EPCRA]) are presented.
The emission factors were developed on a "per item" basis and on a "per net explosive weight
(NEW)" basis. Users should choose the appropriate emission factor to estimate emissions based upon the
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data available; either factor is equally valid. The NEW of each ordnance tested is provided in the
corresponding AP-42 section and in Table 2.
TABLE 2 ORDNANCE NET EXPLOSIVE WEIGHT
DODIC
Ordnance Description
NEW (lb/item)a
M130
M6 Electric Blasting Cap
2.92 E-03
M131
M7 Non-Electric Blasting Cap
2.76 E-03
ML47
Mil Non-Electric Blasting Cap with 30-foot Shock Tube
2.73 E-03
MN02
M12 Non-Electric Blasting Cap with 500-foot Shock Tube
6.18 E-03
MN03
M13 Non-Electric Blasting Cap with 1,000-foot Shock Tube
1.11 E-02
MN06
M14 Non-Electric Time Delay Blasting Cap
2.59 E-02
N286
M582 Mechanical Time and Super Quick (MTSQ) Fuse
5.27 E-02
a NEW values were obtained from References 1 and 3.
This document includes five sections in addition to this Introduction. Section 2 of this document
identifies the compounds measured during the test program and describes the emission measurement
methods used. Section 3 includes a discussion of the emission factor final test report and ratings for the
test data contained therein. Section 4 describes the calculations and methodologies used to develop
emission factors for each type of compound measured. Section 5 describes the methodology used to rate
the emission factors and provides emission factor ratings for each type of compound measured. Section 6
includes a complete list of the references cited in this document.
There are two appendices included with this document. Appendix A identifies, by ordnance type,
all of the compounds for which analyses were performed and the emission factors that were developed.
[Note: Compounds present in the method blank at greater than 50 percent of test levels are excluded from
Appendix A as described in Section 3.2.4], Appendix A also identifies the minimum detection levels
associated with all compounds that were not detected. Emission factors and minimum detection levels
presented in Appendix A were determined from the most accurate method if two sampling or analytical
methods were used to measure one compound. Appendix B presents the new AP-42 sections for the
seven ordnance that were tested.
In addition to this document, there are electronic databases available on the web
(http://www.epa.gov/ttn/chief/ap42/index.html') that contain the data used in the development of the
emission factors. The general procedures that were followed to develop these emission factors can be
found at the same web address under the titles Procedures for Preparing Emission Factor Documents4
and Draft Detailed Procedures for Preparing Emission Factors5
2.0 COMPOUNDS MEASURED AND EMISSION MEASUREMENT METHODS
The USAEC Exploding Ordnance Series 7 testing was conducted in the Large Octagon Test
Chamber (LOTC) located at the Aberdeen Test Center (ATC), Maryland. The LOTC is an eight-sided
steel structure with flat ends. Internally, the eight sides were increased to 16 sides by welding steel plates
over each wall seam. This design strengthened the LOTC and removed sharp interior corners that would
inhibit gaseous mixing during the testing. Additional plates were added to the upper and lower internal
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corners to create a more parabolic shape. The interior volume is approximately 2,400 cubic feet. Interior
wall-to-wall distance is 14.5 feet, with a floor-to-ceiling height of 14 feet.
The measurement assembly and instrument enclosure are mounted on rollers in vertical tracks.
After ordnance detonation, the assembly is lowered by an electric hoist from the top of the LOTC through
the center of the ceiling and into the chamber. A metal cover on top of the assembly seals the interior
when the assembly has been lowered into the LOTC. The LOTC has two flanged viewing ports for video
recording and two ports with hinged internal doors through which the mixing fans are inserted.
A number of different test methods were employed to collect and analyze the emission data that
were used to develop emission factors for detonation of ordnance. Table 3 identifies each emission test
method used; bracketed information identifies the purpose of using the method. The emissions data were
collected using EPA test methods published in Title 40 of the Code of Federal Regulations, Part 50
(40 CFR 50); 40 CFR 60; 40 CFR 63; and in Compendium of Methods for the Determination of Toxic
Organic Compounds in Ambient Air6 Some of the sample analytical procedures used were from EPA
Office of Solid Waste (OSW) publication SW-846, Test Methods for Evaluating Solid Waste,
Physical/Chemical Methods1 and the National Institute for Occupational Safety and Health (NIOSH)
Manual of Analytical Methods (NMAM), Fourth Edition,8 Additional sampling and analytical procedures
were taken from Internal Operating Procedures (IOP) developed by the ATC Chemistry Team and from
Standard Operating Procedures (SOP) developed by the U.S. Army Center for Health Promotion and
Preventive Medicine (USACHPPM) Directorate of Laboratory Sciences (DLS). Where necessary, the
test methods were adapted to reflect application to the unique testing of ordnance detonation in the
LOTC.
TABLE 3 SAMPLING AND ANALYTICAL METHODS USED
Compound
Test Method
CO
40 CFR 60, Appendix A, EPA Method 10 - Determination of Carbon Monoxide
Emissions from Stationary Sources [sampling and analysis]
co2
40 CFR 60, Appendix A, EPA Method 3A - Determination of Oxygen and Carbon
Dioxide Concentrations in Emissions from Stationary Sources (Instrumental Analyzer
Procedure) [sampling and analysis]
NOx
40 CFR 60, Appendix A, EPA Method 7E - Determination of Nitrogen Oxides
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
so2
40 CFR 60, Appendix A, EPA Method 6C - Determination of Sulfur Dioxide
Emissions from Stationary Sources (Instrumental Analyzer Procedure) [sampling and
analysis]
sf6, nh3, CO,
C02, and CH4
40 CFR 63, Appendix A, EPA Proposed Method 320 - Measurement of Vapor Phase
Organic and Inorganic Emissions by Extractive Fourier Transform Infrared (FTIR)
Spectroscopy [sampling and analysis]
TSP
40 CFR 60, Appendix A, EPA Method 17- Determination of Particulate Emissions
from Stationary Sources (In-Stack Filtration Method) [sampling]
40 CFR 50, Appendix B - Reference Method for the Determination of Suspended
Particulate Matter as in the Atmosphere (High Volume Method) [analysis]
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TABLE 3 (cont.)
Compound
Test Method
PM-10 and
PM-2.5
Metals
voc
svoc
PAH
Dioxins and
Furans
Acid Gases
Hydrogen
Cyanide
Aldehydes and
Carbonyls
Hydrocarbons
and n-Hexane
SF6
40 CFR 60, Appendix A, EPA Method 17- Determination of Particulate Emissions
from Stationary Sources (In-Stack Filtration Method) [sampling]
40 CFR 50, Appendix B - Reference Method for the Determination of Suspended
Particulate Matter as in the Atmosphere (High Volume Method) [analysis]
Metal sample was obtained from TSP sample [sampling]
40 CFR 50, Appendix G, Modified - Reference Method for Determination of Lead in
Suspended Particulate Matter Collected from Ambient Air [analysis]
EPA Compendium Method TO-14A -Determination of Volatile Organic Compounds
(VOCs) in Ambient Air Using Specially Prepared Canisters with Subsequent Analysis
by Gas Chromatography [sampling and analysis]
EPA Compendium Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS) [sampling and analysis]
SW-846 Method 8270 Modified (SW8270M) - Semivolatile Organic Compounds by
Gas Chromatography/Mass Spectrometry (GC/MS) [analysis]
EPA Compendium Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC MS) | sampling and analysis |
EPA Compendium Method TO-9A - Determination of Polychlorinated,
Polybrominated, and Brominated/Chlorinated Dibenzo-p-Dioxins and Dibenzofurans
in Ambient Air [sampling and analysis]
NIOSH Method 7903 - Inorganic Acids [sampling and analysis]
NIOSH Method 7904 - Aerosol and Gas Cyanides [sampling]
ATC IOP No. 231 - Analysis of Cyanide and Sulfide by Ion Chromatography
[analysis]
EPA Compendium Method TO-11A - Determination of Formaldehyde in Ambient Air
Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography
(HPLC) [sampling and analysis]
40 CFR 60, Appendix A, EPA Method 18 - Measurement of Gaseous Organic
Compound Emissions by Gas Chromatography [sampling]
USACHPPM SOP CAD 64.1 - Procedure for the Identification and Measurement of
CI Through C6 Hydrocarbons and Sulfur Hexafluoride in Tedlar Gas Bags [analysis]
40 CFR 60, Appendix A, EPA Method 18 - Measurement of Gaseous Organic
Compound Emissions by Gas Chromatography [sampling]
Project specific IOP, IR and gas chromatography with electron capture detection
(GC/ECD) [analysis]	
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TABLE 3 (cont.)
Compound
Test Method
Energetic
Materials
Total Carbon
Hexavalent
Chromium
Perchlorate
EPA Compendium Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS) [sampling]
USACHPPM SOP CAD 26.3 - Procedure for Analysis of Explosives in Ambient Air
and USACHPPM SOP CAD 69.2 - Procedure for Analysis ofPropellant
Components in Ambient Air [analysis]
NIOSH Method 5040 - Diesel Particulate Matter as Elemental Carbon [sampling and
analysis]
OSHA Method ID-215 - Hexavalent Chromium in Workplace Atmospheres
[sampling]
USACHPPM SOP CAD 70.1 - [analysis]
ATC IOP No. 412 - Analysis of Perchlorate Ion by Ion Chromatography with the
AS-16 Column [sampling]
EPA Method 314 - Determination of Perchlorate in Drinking Water Using Ion
Chromatography [analysis]	
The following sections identify and briefly describe the test methods used to measure each
compound or group of compounds. Additional information regarding the operation of the LOTC and the
test methods used is presented in Reference 2. EPA-approved methods were used by the laboratories that
provided sampling and analysis data.
2.1 Carbon Monoxide, Carbon Dioxide, Oxides of Nitrogen, and Sulfur Dioxide
Real-time concentrations of CO, C02, NOx, and S02 that resulted from the use of ordnance in the
LOTC were measured using a continuous emissions measurement system (CEMS). The final test report1
states that the compounds were measured using EPA reference methods as described in the following
paragraph. Although the report does include results for some quality control checks, due to a lack of
calibration data, conformance with the stated methodologies could not be confirmed.
CO sampling and analysis was conducted in accordance with 40 CFR Part 60, Appendix A,
Method 10 - Determination of Carbon Monoxide Emissions from Stationary Sources, with a Thermo
Environmental Instruments, Inc. (TEI) Model No. 41C nondispersive infrared analyzer. C02 sampling
and analysis was conducted in accordance with 40 CFR Part 60, Appendix A, Method 3A -
Determination of Oxygen and Carbon Dioxide Concentrations in Emissions from Stationary Sources,
with a TEI Model No. 48C nondispersive infrared analyzer. NOx sampling and analysis was conducted in
accordance with 40 CFR Part 60, Appendix A, Method 7E - Determination of Nitrogen Oxides Emissions
from Stationary Sources, with a TEI Model No. 42C-HL chemiluminescent analyzer. S02 sampling and
analysis was conducted in accordance with 40 CFR Part 60, Appendix A, Method 6C - Determination of
Sulfur Dioxide Emissions from Stationary Sources, with a TEI 43H pulsed fluorescent analyzer.
Each analyzer channel sampled at approximately 0.5 cubic feet per minute (ft3/min) through
Teflon tubing with Mine Safety Appliance (MSA) ultra type H cartridge filters used to control particulate.
Although the testing was conducted at ambient conditions, heated probes and sample lines were used to
control condensation. Data were collected four times per second.
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2.2	Sulfur Hexafluoride, Ammonia, Carbon Monoxide, Carbon Dioxide, and Methane
Extractive FTIR spectroscopy was used to measure real-time concentrations of the SF6 tracer gas,
NH3, CO, C02, and CH4 as well as to qualitatively identify other permanent gas species using protocols
modified from procedures published in 40 CFR 63, Appendix A, EPA Proposed Method 320 -
Measurement of Vapor Phase Organic and Inorganic Emissions by Extractive Fourier Transform
Infrared (FTIR) Spectroscopy. Samples were drawn continuously from the LOTC at a nominal rate of
0.5 ft3/min using a Teflon-lined polyethylene tube and an Alcatel Pascal® rotary vane-type pump, for a
minimum of 20 minutes. During sampling, the FTIR spectra were collected and stored every 30 seconds.
2.3	Total Suspended Particulate
The TSP concentration that resulted from the use of ordnance in the LOTC was determined using
a modified sampling and analysis procedure based on 40 CFR 60, Appendix A, Reference Method 17 -
Determination of Particulate Emissions from Stationary Sources (In-Stack Filtration Method). An Air
Metrics TSP ambient air sampling module equipped with a quartz fiber filter was connected by a flex line
to the Method 17 metering system. The metering system extracted test chamber air through a particulate
filter at a nominal rate of 10 liters per minute (L/min) for a target minimum sampling time of 20 minutes.
The TSP concentration was computed, in accordance with 40 CFR 50, Appendix B - Reference Method
for the Determination of Suspended Particulate Matter as in the Atmosphere, by dividing the mass of TSP
collected by the volume of air sampled, corrected to standard conditions.
2.4	Particulate Matter with an Aerodynamic Diameter Less than or Equal to 10 or 2.5 Microns
PM10 and PM2 5 concentrations that resulted from the use of ordnance in the LOTC were
determined using a modified sampling and analysis procedure based on 40 CFR 60, Appendix A,
modified EPA Method 17 - Determination of Particulate Emissions from Stationary Sources (In-Stack
Filtration Method). An ambient sampler with Air Metrics PM-10 and PM-2.5 ambient air sampling
modules was used to collect the PM-10 and PM-2.5 samples at a sampling rate of 5 L/min for 20 minutes.
The PM-10 and PM-2.5 modules were equipped with polytetrafluorethylene (PTFE) particulate filters that
were weighed before and after sampling in accordance with 40 CFR 50, Appendix B - Reference Method
for the Determination of Suspended Particulate Matter as in the Atmosphere. The particulate
concentrations were computed by dividing the mass of PM-10 and PM-2.5 collected by the respective
volume of air sampled, corrected to standard conditions.
2.5	Metals
Metal concentrations that resulted from the use of ordnance in the LOTC were determined using
particulate matter from the TSP samples collected as described in Section 2.3. The analyses followed the
procedures of 40 CFR 50, Appendix G - Reference Method for the Determination of Lead in Suspended
Particulate Matter Collected from Ambient Air. The method was modified to use inductively coupled
plasma-atomic emission spectroscopy (ICP-AES) for analysis and to include additional metals.
Concentrations of target metals were computed by dividing the mass of metal collected by the volume of
air sampled, corrected to standard conditions.
2.6	Volatile Organic Compounds
VOC concentrations that resulted from the use of ordnance in the LOTC were determined using
procedures from the Second Supplement to Compendium of Methods for the Determination of Toxic
Organic Compounds in Ambient Air, Method TO-14A - Determination of Volatile Organic Compounds
(VOCs) in Ambient Air Using Specially-Prepared Canisters with Subsequent Analysis by Gas
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Chromatography. Air samples were collected for 20 minutes using a XonTech, Inc., pressurized canister
sampler and silicon-lined 6-liter SUMMA canister that were certified VOC-free prior to use. An analysis
by gas chromatography/mass spectrometry in full scan mode (GC/MS/SCAN) followed. Unknown
compounds were tentatively identified using computerized mass spectral matching techniques.
2.7	Semivolatile Organic Compounds and Polycyclic Aromatic Hydrocarbons
SVOC and PAH concentrations that resulted from the use of ordnance in the LOTC were
determined based on procedures found in Method TO-13A - Determination of Polycyclic Aromatic
Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass Spectrometry (GC/MS). During
each run, samples were collected using a TISCH® Model No. T E-1002 ambient air sampling module
equipped with a quartz fiber filter and XAD-2 adsorbent resin cartridge. The sampling module was
connected by flex line to a stack source airflow metering system. The metering system extracted the
sample at a nominal rate of 28 L/min for 20 minutes. Following sampling, the filters and resin cartridges
underwent solvent extraction and analysis by GC/MS analysis in selected ion monitoring (SIM) mode.
The sample extracts were reanalyzed with the mass spectrometer in scan mode following modified
procedures in SW-846 Method 8270 - Semivolatile Organic Compounds by Gas Chromatography/Mass
Spectrometry (GC/MS). Modifications are described in the USACHPPM SOP SV 72.6 - Analysis of SW-
846 Extracts for Semivolatile Organics by EPA Method 8270C. Unknown compounds were tentatively
identified using computerized mass spectral matching techniques.
2.8	Dioxin and Furan Compounds
Polychlorinated dibenzodioxin (PCDD) and polvchlorinated dibenzofuran (PCDF) compound
concentrations that resulted from the use of ordnance in the LOTC were determined based on procedures
found in Method TO-9A - Determination ofPolychlbrinated, Polybrominated and Brominated/
Chlorinated Dibenzo-p-Dioxins and Dibenzofiirans in Ambient Air. Samples were collected using a
TISCH TE-1002 ambient air sampling module with a quartz fiber particulate filter and a polyurethane
foam (PUF) packed cartridge. The sampling module was connected to a stack source airflow metering
system with a flex line and used to sample for 20 minutes at a nominal rate of 28 L/min. After sampling,
the filters and cartridges underwent extraction and analysis by GC/High Resolution Mass Spectroscopy
according to Method TO-9A.
2.9	Acid Gases
Acid gas concentrations that resulted from the use of ordnance in the LOTC were determined
based on procedures found in NIOSH Method 7903 - Inorganic Acids. Acid gases were collected by
using silica gel sorbent tubes (catalog No. 226-10-03 available from SKC, Inc.) and a sampling pump
using an APEX Instruments Model No. 623 meter console. Sample gases were passed through the
sorbent tubes for 20 minutes at a nominal rate of 0.5 L/min. Analysis was performed according to
NIOSH Method 7903, by ion chromatography as detailed in ATC IOP No. 372 - Anion Analysis Using
the ASM Column.
2.10	Hydrogen Cyanide
HCN concentrations that resulted from the use of ordnance in the LOTC were determined using
NIOSH Method 7904 - Aerosol and Gas Cyanides, but using modified sampling and analytical
procedures. The sample gas was drawn through a 1 micrometer PVC filter and a Teflon impinger
containing 25 mL of 0.1 normal potassium hydroxide (KOH) for 20 minutes at a nominal rate of 1 L/min.
The impinger solution and extracted filter were analyzed by ion chromatography in accordance with
NIOSH Method 7904 and ATC IOP No. 231 - Analysis of Cyanide and Sulfide by Ion Chromatography.
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2.11	Aldehyde and Carbonyl Compounds
Aldehyde and carbonyl compound concentrations that resulted from the use of ordnance in the
LOTC were determined using EPA Compendium Method TO-11A - Determination of Formaldehyde in
Ambient Air Using Adsorbent Cartridge Followed by High Performance Liquid Chromatography
(HPLC), but using modified sampling and analytical procedures. Dinitrophenylhydrazine (DNPH) laden
cartridge tubes were used as a direct probe to trap and derivatize aldehyde and carbonyl compounds.
Sample gases were extracted for 20 minutes (nominal) from the test chamber through ozone denuders at a
rate of 0.05 ft3/min using a diaphragm pump, manifold, critical orifice and needle valve. Analysis was by
reverse-phase HPLC with ultraviolet (UV) detection using Compendium Method TO-11A modified as
detailed in ATC IOP 389.3 - Analysis of Formaldehyde and Other Carbonyl Compounds by High
Performance Liquid Chromatography.
2.12	Hydrocarbons, n-Hexane, and Sulfur Hexafluoride
Hydrocarbon, n-hexane, and SF6 concentrations that resulted from the use of ordnance in the
LOTC were sampled using 40 CFR 60, Appendix A, EPA Method 18 - Measurement of Gaseous Organic
Compound Emissions by Gas Chromatography. The samples were collected in Tedlar® bags at a nominal
rate of 0.4 L/min for 20 minutes. Analysis for the light hydrocarbons was by gas chromatography with a
flame ionization detector (GC/FID) in accordance with USACHPPM SOP CAD 64.1 - Procedure for the
Identification and Measurement of CI Through C6 Hydrocarbons and Sulfur Hexafluoride in Tedlar Gas
Bags. SF6 was analyzed by gas chromatography with electron capture detection (GC/ECD). This
measurement served as a backup to the FTIR measurement of SF6.
2.13	Energetic Materials
Energetic compound concentrations that resulted from the use of ordnance in the LOTC were
determined based on procedures found in EPA Compendium Method TO-13A - Determination of
Polycyclic Aromatic Hydrocarbons (PAHs) in Ambient Air Using Gas Chromatography/Mass
Spectrometry (GC/MS). Samples were collected using a TISCH TE-1002 ambient air sampling module
equipped with a quartz fiber particulate filter and an XAD-2 adsorbent resin cartridge. The sampling
module was used to sample for 20 minutes at a rate of approximately 28 L/min.
Analyses followed procedures outlined in USACHPPM SOP CAD 26.3 - Procedure for Analysis
of Explosives in Ambient Air and USACHPPM SOP CAD 69.2 - Procedure for Analysis ofPropellant
Components in Ambient Air. These operating procedures specifically address the extraction and analysis
of XAD-2 resin used to sample energetic and propellant compounds from air. The compounds were
extracted from the XAD-2 resin using isoamyl acetate and analyzed by gas chromatography with electron
capture detection (GC/ECD) or gas chromatography with mass spectrometry (GC/MS). A surrogate
compound (3,4-dinitrotoluene) was added to the XAD-2 resin prior to sampling. The quartz fiber filter
used in conjunction with the XAD-2 resin was extracted and analyzed separately to characterize the
energetic materials present as particulate solids. The filter was placed in a vial containing isoamyl acetate
immediately after testing to preserve the sample and prevent sublimation of any of the analytes. No
surrogate compound was used in the analysis of the filter portion of the sample.
2.14	Total Carbon
Total carbon concentrations that resulted from the use of ordnance in the LOTC were determined
based on the procedures in NIOSH Method 5040 - Diesel Particulate Matter as Elemental Carbon.
Samples were collected at a rate of 2.0 L/min using an APEX Instruments Model No. 623 meter console.
A dry gas meter contained in the console was used to measure the sample volume. Flow rates were
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verified using an electronic flow meter. The particulate sample was collected on a 37-mm heat-treated
quartz fiber filter and was analyzed using a thermo-optical analyzer to differentiate between organic and
elemental carbon.
2.15	Hexavalent Chromium
The hexavalent chromium concentrations that resulted from the use of ordnance in the LOTC
were determined based on modified procedures in OSHA Method ID-215 - Hexavalent Chromium in
Workplace Atmospheres. Since particulate results from previous weapons firing showed that a large
fraction of the total particulate produced was less than 2.5 microns in size, the method was modified to
use a 0.8-(.un pore size polyvinyl chloride (PVC) filter instead of a 5-f.im PVC filter. Samples were
collected at a rate of 3.5 L/min using an APEX Instruments Model No. 623 meter console. A dry gas
meter contained in the console was used to measure the sample volume. Flow rates were verified using
an electronic flow meter. The filter media was extracted and analyzed using ion chromatography with
post-column derivatization and detection with a UV-Vis detector.
2.16	Perchlorate
Perchlorate concentrations that resulted from the use of ordnance in the LOTC were determined
based on the procedures in ATC IOP No. 412 - Analysis of Perchlorate Ion by Ion Chromatography with
the AS-16 Column and EPA Method 314 - Determination of Perchlorate in Drinking Water Using Ion
Chromatography. Particulate perchlorate sampling was performed using a Savillex No. 1130 Teflon
filter. A Teflon impinger with 25 mL of deionized water was used to trap perchloric acid vapor. Samples
were drawn at a rate of 1.5 L/min via an APEX Instruments Model No. 623 meter console. A dry gas
meter contained in the console w as used to measure the sample volume. Flow rates were verified using
an electronic flow meter. The filter media was extracted using deionized water and both the filter extract
and the impinger solution were analyzed using ion chromatography with conductivity detection.
3.0	TEST DATA ANALYSIS AND RATINGS
3.1	EPA Guidance Regarding Test Data Quality Ratings
Prior to inclusion of emission factors in AP-42, the reliability of the underlying emission test data
must be appraised in accordance with the rating system specified in Reference 4. Under this rating
system, test data are assigned a rating from A to D, where an "A" rating is assigned to the highest quality
data. The criteria used to assign a specific data quality rating are summarized below.
A Tests are performed by using an EPA reference test method, or when not applicable, a sound
methodology. Tests are reported in enough detail for adequate validation and raw data are
provided that can be used to duplicate the emission results presented in the report.
B Tests are performed by a generally sound methodology, but lacking enough detail for adequate
validation. Data are insufficient to completely duplicate the emission result presented in the
report.
C Tests are based on an unproven or new methodology, or are lacking a significant amount of
background information.
D Tests are based on a generally unacceptable method, but the method may provide an order-of-
magnitude value for the source.
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Four specific criteria are identified in Reference 4 for consideration to assist in the assignment of
a test data quality rating. These four criteria are:
1.	Source operation. If the manner in which the source was operated is well documented in the
report and the source was operating within typical parameters during the test, an "A" rating
should be assigned. If the report stated parameters that were typical, but lacked detailed
information, a "B" rating should be assigned. If there is reason to believe the operation was not
typical, a "C" or "D" rating should be assigned.
2.	Test methods and sampling procedures. In developing the ratings, the estimated accuracy and
precision of the test method as well as the adequacy of the documentation should be considered.
In general, if a current EPA reference test method, appropriate for the source, was followed, the
rating should be higher ("A" or "B"). If other methods were used, an assessment should be made
of their validity. If it is judged that the method was likely to be inaccurate or biased, a lower
rating ("C" or "D") should be given. A complete report should indicate whether any procedures
deviated from standard methods and explain any deviations. If deviations were reported, an
evaluation should be made of whether these were likely to influence the test results.
3.	Process information. During testing, many variations in the process can occur without warning
and sometimes without being noticed. Such variations can induce wide deviations in sampling
results. If a large variation between test run results cannot be explained by information contained
in the site final test report or from test reports of other sources, the data are suspect and should be
given a lower rating or excluded. However, it should be recognized that a process may have
highly variable emissions and a lower rating may not be appropriate solely on the basis of wide
deviations in sampling results.
4.	Analysis and calculations. Ideally, final test reports should contain original raw data sheets and
other documentation such as gas parameters (dry cubic feet per minute, oxygen percentage),
calculation sheets, or example calculations describing how the calculated emission results were
obtained. If there arc data sheets, the nomenclature and equations used should be compared to
those specified by EPA to establish equivalency. The depth of review of the calculations should
be dictated by the reviewers' confidence in the ability and conscientiousness of the tester, based
on such factors as consistency of results and completeness of other areas of the final test report.
Reports may indicate that raw data sheets were available, but were not included. If the final test
report is of high quality based on the other criteria, the quality rating should not be lowered due to
a lack of data sheets.
An overall test data quality rating should be assigned based upon the ratings assigned for each of the four
criteria.
3.2 Analysis of Test Data
Data included in the final test report,1 the detailed test plan,2 and in the analytical data supporting
the test report3 were rated in accordance with the rating system described above. Results for each of the
four criteria described above are presented in the following sections.
3.2.1 Source Operations
The manner by which the ordnance were deployed (i.e., used) is documented in the final test
report. With the exception of the adaptations discussed below that were made to facilitate testing in the
LOTC, each ordnance that was tested was deployed in a manner similar to that which would occur in the
field. M6 electric blasting caps were used to initiate the detonation of DODICs ML47, MN02, and
MN03; Daveyfire electric matches were used to initiate DODICs M131 and MN06; and, RP-2 detonators
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were used to initiate DODIC N286. The initiators were also used during the background runs so that
emissions associated with the initiators could be subtracted from the total emissions associated with the
initiators and ordnance. The tests appear to have replicated typical ordnance operating parameters;
consequently, the test data should be assigned an "A" rating based on this criterion.
3.2.2 Test Methods and Sampling Procedures
The test methods and sampling procedures were evaluated as being appropriate and consistent
with EPA test methods or sound methodology. Except as noted below, no problems of any significance
were identified; consequently, the test data should be assigned an "A" rating based on this criterion.
3.2.2.1	CEMS-Measured Data
CEMS data were provided for the tests,3 but not for the pre- and post-test quality control (QC)
activities. CEMS QC measures specified under 40 CFR 60, Appendix A, EPA Methods 3A, 7E, and 6C
were not followed. Furthermore, none of the calibration gas certifications were supplied. There was no
evidence of bias in the data, but based on the issues noted above, the test data for the CEMS-measured
compounds (i.e., CO, C02, NOx, and S02) should be assigned a "B" rating based on this criterion.
3.2.2.2	Compounds Sampled or Analyzed Using More than One Test Method or Analytical Method
Thirty-four compounds were either sampled or analyzed using two methods; these compounds are
identified in Table 4. For each of these compounds, emission factors were calculated based upon the data
measured using the more appropriate test or analytical method; data obtained using the less appropriate
method were ignored. The more appropriate method was identified by reviewing the methods and the
target compound lists associated with each method. If a specific compound appeared on the target
compound list for one method but not the other, the method targeting the compound was selected. If a
specific compound appeared on the target compound lists for both methods, the method judged to provide
the most accurate data was selected.
If a compound was analyzed using both the SW8270M (SVOC) and TO-14A (VOC) methods,
the TO-14A method analysis was judged to be more accurate and was therefore selected. For compounds
analyzed using both the SW8270M (SVOC) and TO-13A (PAH) methods, the TO-13A value was
selected because TO-13A allowed quantification of compounds at lower levels than SW8270M. For
compounds sampled using FTIR spectroscopy and a CEMS, the CEMS measurements were judged to be
more accurate. For compounds analyzed using both SW8270M (SVOC) and SOP CAD 26.3 (energetic
materials), the SOP CAD 26.3 data were selected because SOP CAD 26.3 allows detection of compounds
at lower levels than SW8270M. If a compound was analyzed using both the TO-14A (VOC) and
TO-11A (aldehydes) methods, the TO-11A method analysis was judged to be more accurate and was
therefore selected. For compounds analyzed using both TO-14A (VOC) and Method 18 (hydrocarbons),
and for which the compounds appeared on both target compound lists, the Method 18 analysis was judged
to be more accurate and was selected. For compounds analyzed using both FTIR spectroscopy and
Method 18 (hydrocarbons), the Method 18 analysis was judged to be more accurate and was selected.
Occasionally, the compound measurement from the less accurate method was chosen because the
compound was present in the method blank of the preferred method. In addition, if a compound sampled
under two methods had poor precision between test runs for the sampling method that would have been
more accurate under normal circumstances, data from the other method were used to calculate emission
factors. These cases are also noted in the footnotes to Table 4.
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TABLE 4 SELECTED ANALYTICAL METHOD FOR COMPOUNDS ANALYZED USING
TWO ANALYTICAL METHODS
Compound
Selected Method
Other Method Employed
Carbon dioxide
40 CFR 60, Method 3A (CEMS)
40 CFR 63, Method 320 (FTIR)
Carbon monoxide
40 CFR 60, Method 10 (CEMS)
40 CFR 63, Method 320 (FTIR)
Methane
40 CFR 60, Method 18 (Hydrocarbons)
40 CFR 63, Method 320 (FTIR)
Acenaphthene
TO-13A (PAH)
SW8270M (SVOC)
Acenaphthylene
TO-13A (PAH)
SW8270M (SVOC)
Acrolein
TO-11A (Aldehydes)
TO-14A (VOC)
Anthracene3
TO-13A (PAH)
SW8270M (SVOC)
Benzo[a]anthracene
TO-13A (PAH)
SW8270M (SVOC)
Benzo [b] fluoranthene
TO-13A (PAH)
SW8270M (SVOC)
Benzo [k] fluoranthene
TO-13A (PAH)
SW8270M (SVOC)
Benzo [g,h,i]perylene
TO-13A (PAH)
SW8270M (SVOC)
Benzo [a]pyrene
TO-13A (PAH)
SW8270M (SVOC)
1,3-Butadiene
40 CFR 60 Method 18 (Hydrocarbons)
TO-14A (VOC)
Chrysene
TO-13A (PAH)
SW8270M (SVOC)
Dibenz [a,h] anthracene
TO-13A (PAH)
SW8270M (SVOC)
1,2-Dichlorobenzene
TO-14A (VOC)
SW8270M (SVOC)
1,3 -Dichlorobenzene
TO-14A (VOC)
SW8270M (SVOC)
1,4-Dichlorobenzene
TO-14A (VOC)
SW8270M (SVOC)
2,4-Dinitrotoluene
SOP CAD 26.3 (Energetics)
SW8270M (SVOC)
2,6-Dinitrotoluene
SOP CAD 26.3 (Energetics)
SW8270M (SVOC)
Fluoranthene
TO-13A (PAH)
SW8270M (SVOC)
Fluorene
TO-13A (PAH)
SW8270M (SVOC)
Hexachlorobutadieneb
TO-14A (VOC)
SW8270M (SVOC)
Hexachloroethane
TO-14A (VOC)
SW8270M (SVOC)
Hexane
40 CFR 60, Method 18 (Hydrocarbons)
TO-14A (VOC)
Indeno[ 1,2,3 -cd]pyrenec
TO-13A (PAH)
SW8270M (SVOC)
Naphthalene
TO-13A (PAH)
SW8270M (SVOC)
Nitrobenzene
SOP CAD 26.3 (Energetics)
SW8270M (SVOC)
Phenanthrene
TO-13A (PAH)
SW8270M (SVOC)
Propylened
40 CFR 60, Method 18 (Hydrocarbons)
TO-14A (VOC)
Pyrene6
TO-13A (PAH)
SW8270M (SVOC)
l,2,4-Trichlorobenzeneb
TO-14A (VOC)
SW8270M (SVOC)
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TABLE 4 (cont.)
Compound
Selected Method
Other Method Employed
Acetone
Pentanef
TO-11A (Aldehydes)
40 CFR 60, Method 18 (Hydrocarbons)
TO-14A (VOC)
TO-14A (VOC)
a For DODIC MN06, data collected from the SVOC sampling method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between PAH
test samples.
b For DODIC N286, data collected from the SVOC sampling method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between VOC
test samples.
c For DODIC ML47, data collected from the SVOC sampling method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between PAH
test samples.
d For all ordnance, data collected from the VOC sampling methods were used to develop emission factors
because this compound was present in the hydrocarbon method blank at a level greater than 20 percent
of the test values.
e For DODIC M131, data collected from the SVOC sampling method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between PAH
test samples.
f For DODIC MN06, data collected from the VOC sampling method were used to develop emission
factors because this compound had a relative percent difference greater than 100 percent between
hydrocarbon test samples.
3.2.2.3 Tentatively Identified Compounds
During the analysis of the SVOC data, the 20 highest nontarget "peaks" were tentatively
identified using computerized mass spectral matching techniques. Similarly, during the analysis of the
VOC data, the 20 highest nontarget "peaks" were tentatively identified. Emission factors were developed
for these tentatively identified compounds (TICs) if all of the following criteria were met.
1.	The TIC corresponded to a unique compound (e.g., ethylbenzene). Emission factors were not
developed if the TIC corresponded to a class of compounds (e.g., unknown alcohol).
2.	The TIC was not identified using another analysis method that provided higher confidence data.
Emission factors were developed based upon the higher confidence analysis method if such data
were available.
3.	The TIC was not present in the method blank. Emission factors were not developed if the TIC
was found in the corresponding method blank.
The number of SVOCs that were tentatively identified as unique compounds, were not identified
using a higher confidence method, and were not present in the method blank varied from 0 to
15 compounds per ordnance. The number of VOC that were tentatively identified as unique compounds,
were not identified using a higher confidence method, and were not present in the method blank varied
from 1 to 18 compounds per ordnance. Emission factors were developed for all of these TICs, but
because of the uncertainty in the true identity of the TICs, the test data were assigned a "C" rating.
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3.2.3 Process Information
Ordnance are manufactured to tight tolerances and are expected to deploy in a very repeatable
fashion. Consequently, the test data should be assigned an "A" rating based upon this criterion.
However, large relative percent differences (i.e., greater than 100 percent) between test runs were noted
for several compounds. Specific instances in which these differences were noted are identified in Table 5.
The equation below illustrates calculation of relative percent difference:
TABLE 5 COMPOUNDS FOR WHICH LARGE RELATIVE PERCENT DIFFERENCES
WERE NOTED BETWEEN TEST RUNS
Compound
Applicable DODIC
Acetaldehyde
M131, N286
Acetonitrile
M130, MN03
Acrylonitrile
M130
Antimony
MN03
Barium
M131
Benzene
M130
Hexavalent Chromium
M131, MN06
Copper
MN03
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
M130
1,2,3,4,6,7,8-Heptachlorodibenzofuran
ML47, N286
1,2,3,4,7,8,9-Heptachlorodibcnzofuran
Ml 30;
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
M130
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
M130
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
Ml30, ML47
1,2,3,7,8,9-Hexachlorodibenzofuran
M130
2,3,4,6,7,8-Hexachlorodibenzofuran
M130
Methyl acrylate
MN06
Nickel
M130
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
M130
Toluene
M130
Zinc
N286
Acetylene
M131
1-Butene
MN02
Cyclopropane, ethyl-
ML47
Phosphoric acid
M131, N286
RDX
MN03
2,4,6-Trinitrotoluene
M130, MN06
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, .	......	test 1 concentration - test 2 concentration
relative percent difference =	x 100%
average of test 1 and test 2 concentrations
Due to the large relative percent differences between test runs, the test data specifically identified
in Table 5 were assigned a "C" rating. The remainder of the data should be assigned an "A" rating based
on this criterion.
3.2.4 Analysis and Calculations
The test report,1 detailed test plan,2 and analytical data supporting the test report3 were reviewed
to determine whether they contained all of the original raw data, other documentation, and example
calculations. Although the test report did not contain raw field data, the data were made available upon
request. The test report also lacked certain calibration data. However, the missing information was
judged insufficient to result in a downgrade of the test data quality rating.
The raw data and sample calculations presented in the final test report, detailed test plan, and
analytical data supporting the test report were reviewed to determine if the emission factors presented in
the report could be duplicated. Where differences were found between the emission factors calculated
using the Excel spreadsheets and those presented in the test report, an examination was made to determine
the reason for the differences.
Several minor errors were noted in the calculation of the emission factors within the test report,
particularly with respect to correcting the sample volumes to standard conditions and the incorporation of
analytical detection limits into the emission factors (see Sections 4.1 and 4.2). The emission factors
presented in AP-42 are based upon the corrected spreadsheets. Based upon the raw data, other
documentation, and the Excel spreadsheet calculations, the test data should be assigned an "A" rating.
Emission factors developed for compounds present in the method blank at levels of 20 percent to
50 percent of test values were assumed to be biased high. Four compounds met this criterion.
Specifically, antimony met this criterion for DODICs M131 and ML47; bis(2-ethylhexyl)phthalate met
this criterion for DODIC MN06; 1,2,3,4,6,7,8,9-octachlorodibenzo-p-dioxin met this criterion for DODIC
ML47; and ethanone, l-(3,4-dimethylphenyl) met this criterion for DODICs M130, MN02, and MN03.
For these compounds, the test data were assigned a "B" rating.
When compounds were found in the method blank at levels greater than 50 percent of both test
values, the data were assumed to be suspect and no emission factors were developed. The compounds
that met this criterion are listed in Table 6.
The test report1 indicated that the recommended holding times to extraction and subsequent
analysis were exceeded for acid gases, hexavalent chromium, SVOC, and PAH compounds for some of
the ordnance tested. Specifically:
•	For DODICs M131, MN02, MN03, MN06, and N286, the acid gas samples were analyzed 1 day
after they were extracted rather than being analyzed immediately after extraction. This
exceedance was considered negligible; therefore, the quality of these data were not downgraded.
•	For all DODICs, the recommended holding times for the hexavalent chromium samples were
exceeded by between 18 and 27 days. These test data were assigned a "C" rating.
•	For DODICs Ml30 and ML47, the recommended holding times from extraction to analysis for
the PAH and SVOC samples were exceeded by between 0 and 4 days. These exceedances were
considered negligible; therefore, the quality of these data were not downgraded.
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TABLE 6 COMPOUNDS FOUND IN THE METHOD BLANK AT LEVELS GREATER THAN
50 PERCENT OF BOTH TEST VALUES
Compound
Applicable DODIC
bis(2-Ethylhexyl)phthalate
M130, M131, ML47, MN02, MN03, N286
1,2,3,4,6,7,8 -Heptachlorodibenzo-p-dioxin
MN03
1,2,3,4,6,7,8 -Heptachlorodibenzofuran
MN03
1,2,3,4,7,8,9-Heptachlorodibenzofuran
MN03
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
MN03
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
MN03
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
MN03
1,2,3,4,7,8 -Hexachlorodibenzofuran
MN03
1,2,3,6,7,8-Hexachlorodibenzofuran
MN03
1,2,3,7,8,9-Hexachlorodibenzofuran
MN03
2,3,4,6,7,8-Hexachlorodibenzofuran
MN03
Hydrochloric acid
M131, ML47, MN06
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
M131, MN02, MN03, N286
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
M131. MN02, MN03. N286
Sulfuric acid
ML47
1-Butanol, 3-methyl-, acetate
M130, M131, ML47, MN02, N286
Ethanone, l-(3,4-dimethylphenyl)
M131
Isobutylene
M130, M131, ML47, MN02, N286
3-Penten-2-one, 4-methyl
M130
Propane
MN03
• For DODIC M131, the recommended holding times from extraction to analysis for the SVOC
samples were exceeded by between 0 and 7 days. These test data were assigned a "B" rating.
Those compounds whose data quality was downgraded as a result of holding time exceedances are
identified in Table 7.
TABLE 7 COMPOUNDS SIGNIFICANTLY EXCEEDING THE HOLDING TIMES FOR
EXTRACTION AND/OR ANALYSIS
Compound
Data Quality
Rating
Applicable DODIC
4-Bromophenylphenylether
B
M131
Butylbenzylphthalate
B
M131
4-Chloroaniline
B
M131
bis(2-Chloroethoxy)methane
B
M131
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TABLE 7 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Bis(2-chloroethyl)ether
B
M131
2-Chloronaphthalene
B
M131
2-Chlorophenol
B
M131
4-chlorophenyl-phenylether
B
M131
Hexavalent chromium
C
All DODICs
p-Cresol
B
M131
Dibenzofuran
B
M131
Dibutyl phthalate
B
M131
2,4-Dichlorophenol
B
M131
2,4-Dimethylphenol
B
M131
Dimethyl phthalate
B
M131
4,6-Dinitro-2-methylphenol
B
M131
2,4-Dinitrophenol
B
M131
Hexachlorobenzene
B
Ml 31
Hexachlorocyclopentadiene
B
M131
Isophorone
B
M131
2-Methylnaphthalene
B
M131
2-Methylphenol
B
M131
4-Nitroaniline
B
M131
2-Nitrophenol
B
M131
4-Nitrophenol
B
M131
n-Nitrosodimethylamine
B
M131
n-Nitrosodiphenylamine
B
M131
n-Nitroso-di-n-propylamine
B
M131
Pentachlorophenol
B
M131
Phenol
B
M131
Pyrene
B
M131
2,4,5-Trichlorophenol
B
M131
2,4,6-Trichlorophenol
B
M131
Benzyl alcohol
B
M131
bis(2-Chloroisopropyl)ether
B
M131
4-Chloro-3-methylphenol
B
M131
Diethylphthalate
B
M131
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TABLE 7 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Di-n-octylphthalate
B
M131
2-Nitroaniline
B
M131
3-Nitroaniline
B
M131
3.3 Test Data Quality Ratings
Upon completing the analysis described in the preceding section of this document, the test data
quality ratings assigned as a result of the four criteria were reviewed. This review led to a downgrading
of some of the test data from an "A" rating to either a "B" rating or a "C" rating. Table 8 identifies the
data quality ratings for all compounds that did not receive an "A" rating.
TABLE 8 DOWNGRADED DATA QUALITY RATINGS
Compound
Data Quality
Rating
Applicable DODIC
Carbon dioxide
B
All DODICs
Carbon monoxide
B
All DODICs
Oxides of nitrogen
B
All DODICs
Sulfur dioxide
B
All DODICs
Acetaldehyde
.'. (
M131, N286
Acetonitrile
C
M130, MN03
Acrylonitrile
C
M130
Antimony
B
M131, ML47
Antimony
C
MN03
Barium
C
M131
Benzene
C
M130
Biphenyl
C
MN06
4-Bromophenylphenylether
B
M131
2-Butenal
C
MN06
Butylbenzylphthalate
B
M131
4-Chloroaniline
B
M131
bis(2-Chloroethoxy)methane
B
M131
bis(2-Chloroethyl)ether
B
M131
2-Chloronaphthalene
B
M131
2-Chlorophenol
B
M131
4-Chlorophenyl-phenylether
B
M131
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TABLE 8 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Hexavalent chromium
C
All DODICs
Copper
C
MN03
p-Cresol
B
M131
Dibenzofuran
B
M131
Dibutyl phthalate
B
M131
2,4-Dichlorophenol
B
M131
2,4-Dimethylphenol
B
M131
Dimethyl phthalate
B
M131
4,6-Dinitro-2-methylphenol
B
M131
2,4-Dinitrophenol
B
M131
bis(2-Ethylhexyl)phthalate
B
MN06
1,2,3,4,6,7,8 -Heptachlorodibenzo-p-dioxin
C
M130
1,2,3,4,6,7,8 -Heptachlorodibenzofuran
C
ML47, N286
1,2,3,4,7,8,9-Heptachlorodibenzofuran
C
VI130
Hexachlorobenzene
B
M131
Hexachlorocyclopentadiene
B
M131
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
(
M130
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
C
M130
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
C
Ml30, ML47
1,2,3,7,8,9-Hexachlorodibenzofuran
C
M130
2,3,4,6,7,8-Hexachlorodibenzofuran
C
M130
Isophorone
B
M131
Methyl acrylate
C
MN06
2-Methylnaphthalene
B
M131
2-Methylphenol
B
M131
Nickel
C
M130
4-Nitroaniline
B
M131
2-Nitrophenol
B
M131
4-Nitrophenol
B
M131
n-Nitrosodimethylamine
B
M131
n-Nitrosodiphenylamine
B
M131
n-Nitroso-di-n-propylamine
B
M131
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
B
ML47
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TABLE 8 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
C
M130
Pentachlorophenol
B
M131
Phenol
B
M131
Pyrene
B
M131
Toluene
C
M130
2,4,5-Trichlorophenol
B
M131
2,4,6-Trichlorophenol
B
M131
Zinc
C
N286
Acetic acid, methyl ester
C
MN06
Acetylene
C
M131
Benzaldehyde
C
M130
Benzaldehyde, 4-hydroxy-3,5 -di-methoxy
C
MN06
Benzenesulfonamide, N-butyl-
C
N286
Benzoic acid
C
M130
Benzyl alcohol
B
M131
1,2-Butadiene
C
MN02, MN03
1,3-Butadiyne
c
ML47, MN02
1-Butene
c
MN02
l-Buten-3-yne
c
ML47, MN02, MN03
bis(2-Chloroisopropyl)ether
B
M131
4-Chloro-3-methylphenol
B
M131
Cyclodecane
C
MN03
1,3-Cyclopentadiene
C
MN02
Cyclopentanone
C
MN06
2-Cyclopenten-l-one, 2-methyl-
C
MN06
2-Cyclopenten-l-one, 3-methyl-
C
MN06
Cyclopropane, 1,2-dimethyl-, cis-
C
MN02
Cyclopropane, ethyl-
C
ML47, MN02, MN03
1-Decene
C
MN02, MN03
2-Decene, (E)-
C
MN03
2-Decene, (Z)-
C
MN03
cis-3-Decene
C
MN03
trans-3-Decene
C
MN02
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TABLE 8 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Diethylphthalate
B
M131
Di-n-octylphthalate
B
M131
1-Dodecene
C
MN02, MN03
2-Dodecene, (Z)-
C
MN03
Ethanone, l-(3,4-dimethylphenyl)
C
M130, MN02, MN03
Ethanone, l-(4-ethylphenyl)
C
M130, MN02, MN03
Ethanone, l-(2-furanyl)-
C
MN06
Ethanone, l-(4-hydroxy-3,5-
dimethoxyphenyl)-
C
MN06
Furan
C
MN06
2-Furancarboxaldehyde
C
MN06
2-Furancarboxaldehyde, 5-methyl-
C
MN06
2-Furanmethanol
C
MN06
Furan, 2-methyl-
C
MN06
Heptadecane
C
MN06
1-Heptene
/ C
ML47
1,5-Hexadiene
¦ ¦ ¦ c
MN02
1-Hexene
c
ML47, MN06
Indene
c
MN02, MN03, MN06
Isobutane
c
M130
Methane, nitro-
c
M130, ML47, N286
2-Nitroaniline
B
M131
3-Nitroaniline
B
M131
1-Octene
C
MN03
4-Octene, (E)-
C
MN03
Oxirane, ethenyl-
C
ML47
1,3-Pentadiene
C
MN03
1,3-Pentadiene, (E)-
C
MN03
1,3-Pentadiene, (Z)-
C
ML47, MN02
2,3-Pentanedione
C
MN06
1-Pentene
C
MN03, MN06
1-Pentene, 3-ethyl-4-methyl-
C
MN03
2-Pentene, (Z)-
C
MN06
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TABLE 8 (cont.)
Compound
Data Quality
Rating
Applicable DODIC
Phenol, 2,6-dimethoxy-
C
MN06
Phenol, 2,6-dimethoxy-4-(2-propenyl)-
C
MN06
Phenol, 2-methoxy-4-methyl
c
MN06
Phosphoric acid
c
M131, N286
2-Propenal, 2-methyl-
c
MN06
RDX
c
MN03
1-Tetradecene
c
MN02, MN03
Thiophene
c
MN06
2,4,6-Trinitrotoluene
c
M130, MN06
1-Undecanol
c
MN02
4.0 EMISSION FACTOR CALCULATIONS
The methodologies and procedures that were used to develop emission factors from the test data
are described in this section. A similar approach was used to calculate emission factors for SVOC and
PAH compounds. The calculation steps that were performed for each sample and each configuration are
summarized below.
1.	The sample volumes associated with the background and test runs were corrected to the EPA
Stationary Source Program standard temperature and pressure (i.e., 68°F and 29.92 inches of
mercury).
2.	For compounds for which more than one test sample was obtained, analytical detection limits
were incorporated into the test data.
3.	The background compound concentration was calculated by dividing the mass of compound
detected during the background run by the background run sample volume corrected to standard
conditions.
4.	The test compound concentration was calculated by dividing the mass of compound detected
during the test run by the test run sample volume corrected to standard conditions.
5.	A background-corrected concentration was calculated by subtracting the background
concentration from the test concentration.
6.	A dilution-corrected concentration was calculated by dividing the background-corrected
concentration by the test dilution correction factor.
7.	The mass of compound released during the test run was calculated by multiplying the dilution-
corrected concentration by the volume of the LOTC.
8.	Emission factors for each sample and test run were calculated by dividing the mass of compound
released by the number of ordnance detonated during the test run or by the NEW detonated
during the test run, as appropriate.
9.	Average emission factors were calculated for each compound.
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Because concentration data (i.e., parts per million by volume [ppmv] or parts per billion by
volume [ppbv]) were recorded for VOC, hydrocarbons, FTIR-measured compounds, and CEMS-
measured compounds, it was not necessary to calculate a corrected sample volume as described in step 1
or to calculate background and test concentrations as described in steps 3 and 4. Detection limits were
applied directly to test compound concentrations as described in step 2. As appropriate, ppmv and ppbv
values were converted to mg/m3. Emission factors for VOC, hydrocarbons, and CEMS-measured
compounds were then estimated in accordance with steps 5 through 9 described above. FTIR-measured
compound emission factors were also estimated in accordance with steps 5 through 9 described above,
except that step 6, the dilution correction, was not required. FTIR-measured concentrations were
determined from initial steady-state points that occurred prior to significant dilution.
Test and background concentrations of TSP, PM-10, PM-2.5, metal, acid gas, hydrogen cyanide,
aldehyde, dioxin/furan, total carbon, hexavalent chromium, energetic, and perchlorate compounds were
provided by the laboratory. The laboratory calculated the concentrations based upon the sample volumes
as measured at actual conditions. Concentration data received from the laboratory were corrected for
volume at Stationary Source Program standard conditions and analytical detection limits were
incorporated as described in step 2. Emission factors for these compounds were then estimated in
accordance with steps 5 through 9 described above.
4.1	Correction of Sample Volume to Standard Conditions
Because sample volumes were initially reported at actual conditions, calculations to correct the
sample volumes to the EPA Stationary Source Program standard temperature of 68°F and pressure of
29.92 inches of Hg (20°C and 760 mm Hg) were performed. To obtain the sample volume at EPA
Stationary Source Program standard conditions (Vslal). the sample volume at actual conditions (Vact) was
multiplied by the ratio of pressure at actual conditions (Pacl) to temperature at actual conditions (Tact) and
by the ratio of temperature at Stationary Source Program standard conditions (Tstat) to pressure at
Stationary Source Program standard conditions (Pstat). This calculation is illustrated by the following
equation:
P T
JT 	 T7" y. act y. stat
V stat ~ V act X J,	p
act	stat
4.2	Incorporation of Analytical Detection Limits to the Test Data
In most cases, more than one test sample was obtained for a specific compound (i.e., more than
one test run was conducted). When multiple samples were obtained for the same compound, a
comparison was made of all the sample data collected. Based upon the results of the comparison, the
following adjustments were made to the test data:
1.	If all of the samples indicated that a compound was "not detected," the sample data were not
adjusted.
2.	If all of the samples indicated that a compound was detected, the sample data were not adjusted.
3.	If one or more of the samples indicated that a compound was detected and one or more of the
samples indicated that a compound was not detected, the "not detected" values were replaced
with a value equal to one half of the compound's analytical detection limit. The assumption
inherent to this adjustment was that the measured presence of a compound in one or more
samples was indicative of the compound's presence in all samples. The analytical detection
limits for each sample were obtained from the analytical data supporting the test report.
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4.3 Determination of Background Concentration
For SVOC and PAH compounds, the background compound concentration (BC) was calculated
by dividing the mass of compound detected during the background run (Bkgd mass) by the background
run sample volume corrected to EPA Stationary Source Program standard conditions (Bkgd Vstat). The
background concentration calculation is illustrated by the following equation:
^>Q _ Bkgd mass
Bkgd K,a,
The background compound concentrations of TSP, PM-10, PM-2.5, metals, acid gases, hydrogen
cyanide, aldehydes, dioxin/furan compounds, total carbon, hexavalent chromium, energetics, and
perchlorate provided by the lab were calculated using the sample volume at actual conditions (Bkgd Vact).
In order to correct the concentrations to EPA Stationary Source Program standard conditions (Bkgd Vstat),
the uncorrected concentrations (Bkgd UC) were multiplied by the ratio of volume at actual conditions to
volume at standard conditions. This calculation is illustrated by the following equation:
BC = Bkgd UC x Bkgd Vact
Bkgd Vstat
FTIR- and CEMS-measured compounds were not sampled for during the background runs.
However, background data were recorded for each test run between the time the FTIR and CEMS began
sampling and the time of detonation. The only FTIR- or CEMS-measured compound for which
significant background concentrations were recorded was C02. The C02 background concentration was
assumed to equal a representative value over the sampling period. Background concentrations for the
other FTIR- and CEMS-measured compounds were assumed to be zero.
4.4 Determination of Test Compound Concentration
For SVOC and PAH compounds, the test compound concentration (TC) was calculated by
dividing the mass of compound detected during the test run (Test mass) by the test run sample volume
corrected to EPA Stationary Source Program standard conditions (Test Vstat). This test compound
calculation is illustrated by the following equation:
Test mass
Test compound concentrations of TSP, PM-10, PM-2.5, metals, acid gases, hydrogen cyanide,
aldehydes, dioxin/furan compounds, total carbon, hexavalent chromium, energetics, and perchlorate
provided by the lab were calculated using the sample volume at actual conditions. In order to correct the
concentrations to EPA Stationary Source Program standard conditions, the uncorrected concentrations
(Test UC) were multiplied by the ratio of the volume at actual conditions (Test Vact) to the volume at EPA
Stationary Source Program standard conditions (Test Vstat). This calculation is illustrated by the
following equation:
Test V
TC = Test UC x
For VOC, hydrocarbons, FTIR-measured compounds, and CEMS-measured compounds, sample
volume correction was not required. VOC and hydrocarbon test concentration values were used directly.
24
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Test concentrations of CEMS-measured compounds were determined as the average values measured
over the test duration. Test concentrations of FTIR-measured compounds were determined based upon
the initial steady-state values reached after detonation. The time at which a compound's concentration
reached an initial steady state was determined by visually inspecting plots of the concentration data versus
time. The initial steady state corresponds to the time at which a compound was well mixed within the
LOTC, but before the compound's concentration began to decrease at a steady rate due to dilution.
4.5 Determination of Background-Corrected Concentration
For all compounds, the calculation of the background-corrected concentration (BCC) was
dependent on whether the background (BC) and test concentrations (TC) were detected and whether they
were less than, equal to, or greater than one another. The procedures used to calculate the background-
corrected concentration for each sampling train and compound are described below and are displayed
graphically in Figure 1.
1.	If the test concentration was not detected (ND), the background-corrected concentration equaled
ND.
2.	If the test concentration was detected and the background concentration was not detected, the
background-corrected concentration equaled the test concentration.
3.	If the test and background concentrations were detected and the test concentration was less than
or equal to the background concentration, the background-corrected concentration equaled 0.
4.	If the test and background concentrations were detected and the test concentration was greater
than the background concentration, the background concentration w as subtracted from the test
concentration. This calculation is illustrated by the following equation:
BCC = 7 ( ¦ - BC
M6 electric blasting caps were used to initiate the detonation of DODICs ML47, MN02, and
MN03. In addition, Daveyfire electric matches were used to initiate the detonation of DODICs M131 and
MN06. Finally, RP-2 exploding bridgewire detonators were used to initiate the detonation of DODIC
N286. To quantify emissions associated with the initiators and thereby allow the emissions to be
subtracted from the resulting emission factors, the initiators were used during the background runs. As a
result, it was necessary to correct these background concentrations for dilution. This was accomplished
by multiplying the background concentration by the ratio of test dilution correction factor (DCFtest) to
background dilution correction factor (DCFbackground) prior to completing either step 3 or step 4 as
described above. The calculation of the background-corrected concentration for those DODICs that were
tested with a detonator is illustrated by the following equation:
DCF
BCC = TC - BC x	^—
DCF
background
4.6 Determination of Dilution-Corrected Concentration
The dilution-corrected concentration (DCC) was calculated by dividing the background-corrected
concentration by the applicable test dilution correction factor. This calculation is illustrated by the
following equation:
DCC= BCC
DCFtest
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No
Was TC Detected?
Yes
No
Was BC Detected?
Yes
No
Was TC > BC?
Yes
BCC = ND
BCC = TC
BCC = TC - BC
BCC = 0
TC = Test Concentration
BC = Background Concentration
ND = Not Detected
BCC = Background-Corrected
Concentration
26
Figure 1 Calculation of background-corrected concentration.
Ordnance Detonation
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With the exception of FTIR-measured compounds, dilution correction factors were obtained from
the test contractor.3 Because the test concentrations of FTIR-measured compounds were obtained prior to
dilution, it was not necessary to calculate a dilution corrected concentration for these compounds.
4.7	Determination of Mass of Compound Released
The mass of compound released was calculated by multiplying the dilution-corrected
concentration by the volume of the LOTC. This calculation is illustrated by the following equation:
Mass compound released = DCC x LOTC volume
4.8	Determination of Emission Factors
Once the mass of compound released was calculated, two emission factors were developed for
each sample and for each test run: the mass of compound released per item (i.e., per single ordnance) and
the mass of compound released per pound NEW. The NEW for all ordnance were determined from
Reference 1.
4.9	Determination of Average Emission Factors
Steps 1 through 8, as described in Sections 4.1 through 4.8, are applicable to individual samples
within individual test runs. The final step in the emission factor calculation process was to calculate
average emission factors for each compound in terms of mass released per item and mass released per
pound NEW. The average emission factors for each compound were calculated as the arithmetic mean of
the individual samples associated with the compound. If all samples indicated that the compound was not
detected (ND), then the average emission factor was assigned a value of ND. |Note: The minimum
detection levels associated with the compounds that were not detected are presented in Appendix A.]
Total dioxin/furan emission factors were calculated by summing the average emission factors for
all dioxin/furan compounds. Samples of energetic materials were collected using both filters and resin
packed cartridges. However, the filter and resin were analyzed separately. Because the filter and resin
packed cartridge were arranged in series, average emission factors calculated for the filter were added to
average emission factors calculated for resin packed cartridge to determine total emission factors.
5.0 EMISSION FACTOR RATINGS
The emission factors were appraised in accordance with the rating system specified in
Reference 4. Under this rating system, emission factors are assigned a rating from A to E, where an "A"
rating is assigned to the highest quality factors. The criteria used to assign a specific emission factor
rating are summarized below.
A Excellent. The emission factor was developed primarily from A- and B-rated source test data
taken from many randomly chosen facilities in the industry population. The source category
population was sufficiently specific to minimize variability.
B Above average. The emission factor was developed primarily from A- or B-rated test data from a
moderate number of facilities. Although no specific bias was evident, it was not clear if the
facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
C Average. The emission factor was developed primarily from A-, B-, and/or C-rated test data from
a reasonable number of facilities. Although no specific bias was evident, it was not clear if the
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facilities tested represented a random sample of the industry. As with the "A" rating, the source
category population was sufficiently specific to minimize variability.
D Below average. The emission factor was developed primarily from A-, B-, and C-rated test data
from a small number of facilities, and there may have been reason to suspect that these facilities
did not represent a random sample of the industry. There also may have been evidence of
variability within the source category population.
E Poor. The emission factor was developed from C- and D-rated test data from a very limited
number of facilities, and there may have been reason to suspect that the facilities tested did not
represent a random sample of the industry. There also may have been evidence of variability
within the source category population.
Two analyses were conducted to assign ratings to the ordnance emission factors. First, an
analysis was conducted on an ordnance-specific basis. Second, an analysis was conducted using all
available ordnance emission factor data. The second analysis was conducted to determine whether a
sufficient correlation existed between emission factors for different but similar ordnance to allow the
number of test data points to be increased to the point that higher emission factor ratings could be
assigned than were possible when using the ordnance-specific approach. Both analyses are described
below.
5.1 Emission Factor Ratings Assigned - Based on Ordnance-Specific Test Data
As previously described, emission factor ratings are dependent upon the test data quality, the
number of test data points, the amount of variability present within a source category population, and the
randomness of the source category sample. The following test data facts pertain to these rating criteria:
1.	As described in Section 3 of this Background Document, the ordnance test data was primarily
rated A or B. The test data for a few compounds was rated C.
2.	Only two tests were conducted per ordnance.
3.	Ordnance are manufactured to very tight tolerance levels so there is little variability within a
specific type of ordnance.
4.	There was no evidence that suggested the tested items within each type of ordnance were
specially selected.
Emission factor ratings were assigned based upon these facts. The rationale used to accept or
reject specific emission factor ratings follow.
A: Rejected. The number of test data points was deemed to be insufficient to assign an A emission
factor rating.
B: Rejected. The number of test data points was deemed to be insufficient to assign a B emission
factor rating.
C: Accepted for most ordnance. The emission factors were developed using A- and B-rated test
data, there is little variability among items, and there was no evidence that suggested the tested
items were specially selected. Because of the limited number of data points, a C rating was
deemed appropriate for this set of circumstances.
D: Accepted for some ordnance. The emission factors were developed using C-rated test data, there
is little variability among items, and there was no evidence that suggested the tested items were
specially selected. Because of the limited number of data points, a D rating was deemed
appropriate for this set of circumstances.
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E: Rejected. The ordnance described in this report were developed primarily using A- and B-rated
test data rather than C- or D-rated data, there is little variability among items, and there was no
evidence that suggested the tested items were specially selected. Therefore, an E emission factor
rating was deemed inappropriate.
5.2 Emission Factor Ratings Assigned - Based on All Available Test Data
The proceeding sections of this Background Document concern the emission measurement
methods, data analysis, and calculations used to develop emission factors for specific ordnance.
However, USAEC's ordnance emission factor development program includes more than 200 ordnance
that have been tested under more than 25 separate test series. Because many of these ordnance are similar
in size and/or chemical composition, a statistical analysis was conducted to assess the similarity of the
emission factors developed for similar ordnance. The results of this analysis were used to reevaluate the
emission factor ratings assigned on an ordnance-specific basis.
USAEC characterized individual ordnance as falling into one of 17 separate categories,
depending upon the size and/or chemical composition of the ordnance. The ordnance and their respective
categories are identified in Table 9 along with a comment field describing the number of data points.
Within each of the 17 ordnance categories identified by USAEC, emission factors for each
compound were compared. To allow the comparison of emission factors for ordnance with similar
constituents but significant differences in net explosive weight, the comparison was made using the
normalized emission factor units of mass of compound released per pound NEW. Based upon
information provided by EPA.'1 the following procedures were used to assess the data correlation:
1.	The relative standard deviation, defined as the standard deviation divided by the mean, was
calculated for each compound within each ordnance category.
2.	If the relative standard deviation was less than 1.0, the evaluated emission factors were
considered to demonstrate good correlation. As such, the rating for these emission factors could
be elevated to a maximum of an A, depending on the number of data points within the evaluated
ordnance category.
3.	If the relative standard deviation was between 1.0 and 2.0, the evaluated emission factors were
considered to demonstrate fair correlation. As such, the rating for these emission factors could be
elevated to a maximum of a B, depending on the number of data points within the evaluated
ordnance category.
4.	If the relative standard deviation was greater than 2.0, the evaluated emission factors were
considered to demonstrate poor correlation. As such, the emission factor rating could not be
elevated, regardless of the amount of data available.
A poor correlation between emission factors was not necessarily construed as being indicative of poor test
data. Rather, a poor correlation was more likely to indicate that the ordnance included in the category
were not as similar in nature as anticipated by USAEC when the ordnance categories were defined.
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TABLE 9 ORDNANCE CATEGORIZATION FOR EMISSION FACTOR
CORRELATION ASSESSMENT
Category
DODIC
Ordnance Description
Test Series
Comment
CS
G963a
K765a
M73A CS Riot Control Agent Hand
Grenade
CS Riot Control Agent Capsule
DPG VI
DPG VI
Data not yet
available

G900
TH3 AN-M14 Incendiary Grenade
EO 5


G911
MK3A2 Offensive Hand Grenade
EO 2


G911
MK3A2 Offensive Hand Grenade
EO 6


K010
M4 Field Incendiary Burster
EO 5


K145
M18A1 Antipersonnel Mine
EO 2


M023
Ml 12 Demolition Block Charge
EO 1


M030
1/4-Pound Demolition Block Charge
EO 1


M030
1/4-Pound Demolition Block Charge
EO 3


M031
1/2-Pound Demolition Block Charge
DPG IV-A


M032
1-Pound Demolition Block Charge
EO 2


M032
1 -Pound Demolition Block Charge
EO 3


M130a
M6 Electric Blasting Cap
DPG VII


M130
M6 Electric Blasting Cap
EO 7


M131
M7 Non-Electric Blasting Cap
EO 7

Demolition
M241
M10 High Explosive Universal Destructor
DPG IV-B
20+ data points

M456
PETN Type 1 Detonating Cord
DPG IV-A


M500a
M21 REEF Line Cutter
EO 10


M591
Ml Military Dynamite Demolition Block
Charge
EO 1


M913
M58A3 Linear Demolition Charge
EO 3


ML05a
MK24 High Explosive Cutter
EO 11


ML09
Linear Demolition Charge, Shaped 20 gr/ft
DPG IV-A


ML15
Linear Demolition Charge, Shaped
225 gr/ft
DPG IV-A


ML47
Mil Non-Electric Blasting Cap with
30-foot Shock Tube
EO 7


MM50a
M221 Shaped Charge
EO 11


MN02
Mil Non-Electric Blasting Cap with
500-foot Shock Tube
EO 7


MN03
Mil Non-Electric Blasting Cap with
1,000-foot Shock Tube
EO 7

30

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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment

MN06
M14 Non-Electric Time Delay Blasting
Cap
EO 7

Demolition,
continued
MN07a
MN08a
MN68a
M15 Delay Blasting Cap
M81 Igniter
M151 Booster Demolition Charge
EO 11
EO 9
DPG VIII
20+ data points

None
PAX-11, Granular Powder Burn
EO 4


None
PAX-11, Molded Pellet Detonation
EO 4


G878a
M228 Practice Hand Grenade Fuse
DPG VI


K051
M604 Anti-Tank Practice Mine Fuse
EO 6


N278a
M564 Mechanical Time and Super Quick
(MTSQ) Fuse
EO 11

Fuse
N285a
N286
M577 Fuse
M582 Mechanical Time and Super Quick
(MTSQ) Fuse
EO 9
EO 7
<10 data points

N335
M557 Point Detonating Fuse
EO 5


N340
M739A1 Point Detonating Fuse
EO 5


N464a
M732 Fuse
EO 9


G881
M67 Fragmentation Grenade
EO 1

Grenade
G978
G982
M82 Smoke Simulant Screening Grenade
Launcher
M83 Terephthalic Acid (TA) Smoke
Practice Hand Grenade
DPG V-B
DPG V-A
<10 data points

GG09a
M84 Non-Lethal Stun Hand Grenade
EO 12


B535
M583A1 40-mm White Star Parachute
DPG I V-B


Cartridge


B536
M585 40-mm White Star Cluster Cartridge
DPG I V-B


B627
M83A3 60-mm Illuminating Cartridge
(projectile only)
DPG V-B


D505
L305
M485A2 155-mm Illumination Round
DPG I
DPG I

Illumination
(projectile only)
Ml95 Green Star Parachute Signal Flare
20+ data points

L306
M158 Red Star Cluster Signal Illumination
DPG II


L307
Ml59 White Star Cluster Signal
Illumination
DPG II


L311
M126A1 Red Star Parachute Signal Flare
DPG II


L312
M127A1 White Star Parachute Signal Flare
DPG I

02/08
Ordnance Detonation
31

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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment

L314
M125A1 Green Star Cluster Signal Flare
DPGI

Illumination,
continued
L367a
M22 Anti-Tank, Guided Missile, and
Rocket Launching Simulator
DPG VI
20+ data points

L410a
M206 Aircraft Countermeasure Flare
DPG VI

Inert
HAlla
Rocket, 2.75-inch Flechette with M255A1
DPG VIII
Data not yet
Warhead
available

C511
M490 105-mm Target Practice Tracer
Cartridge (Ml3 tracer only)
EO 6

Large
C784a
M831 120-mm Target Practice Tracer
Cartridge
EO 12
<10 data points

C785a
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge
EO 12

Medium
bait
BA15a
Ml001 40-mm HVCC Cartridge
M769 60-mm FRP Cartridge
EO 12
EO 12
Data not yet
available

A652
M220 20-mm Target Practice Tracer
Cartridge
FP 9


A940
M910 25-mm Target Practice Discarding
Sabot Tracer Cartridge
FP 8

Medium-FP
A976
M793 25-mm Target Practice Tracer
Cartridge
FP 8
10+ data points

B129a
M789 30-mm Cartridge
EO 9


B505a
M662 40-mm Red Star Parachute Cartridge
DPG VIII


B519
M781 40-mm Practice Cartridge
FP 2


B584
M918 40-mm Practice Cartridge
FP 2

Mine
K042a
M88 Volcano Practice Canister Mine
DPG VIII
Data not yet
available
Mortar
CA03
XM929 120-mm White Phosphorus Smoke
Cartridge (projectile only)
DPG V-B
<10 data points

B542
M430 40-mm High Explosive Dual
Purpose (HEDP) Cartridge (projectile only)
EO 3


B571
M383 40-mm High Explosive Cartridge
(projectile only)
EO 3

Projectile
B632
M49A4 60-mm High Explosive Cartridge
(projectile only)
EO 3
10+ data points

B642
M720 60-mm High Explosive Cartridge
(projectile only)
EO 6


BZ-13a
M888 60-mm Cartridge
EO 11

32
Ordnance Detonation
02/08

-------
TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment

C995
M136 AT4 Recoilless Rifle, 84-mm
Cartridge (projectile only)
EO 3

Projectile,
continued
H557
H708a
M72A3 66-mm High Explosive Antitank
Rocket (projectile only)
M73 3 5-mm Subcaliber Practice Rocket
EO 1
DPG VIII
10+ data points

None
M720 60-mm Mortar HE Cartridge with
PAX-21 Charge (projectile only)
EO 8


PJ02
FIM-92A Stinger-Basic Guided Missile
(projectile only)
EO 6


B627
M83A3 60-mm Illuminating Cartridge
(propelling charge only)
FP 10


B642
M720 60-mm High Explosive Cartridge
(propelling charge only)
FP 4


B645
M766 60-mm Short Range Practice Mortar
Cartridge (propelling charge only)
FP 10


C226
M301A3 81-mm Illuminating Cartridge
(propelling charge only)
FP 4


C379
M934 1.20-mm High Explosive Cartridge
(Zone 1 - propelling charge only)
FP 8


C511
M490 105-mm Target Practice Tracer
Cartridge (propelling charge only)
FP 5

Propellant
C784
C785
M831 120-mm Target Practice Tracer
Cartridge (propelling charge only)
M865 120-mm Target Practice Discarding
Sabot Tracer Cartridge (propelling charge
only)
FP 5
FP 5
20+ data points

C868
M821 81-mm High Explosive Cartridge
(propelling charge only)
FP 4


C876
M880 81-mm Target Practice Short Range
Cartridge (propelling charge only)
FP 4


CA09
M931 120-mm Full Range Practice
Cartridge (Zone 1 - propelling charge only)
FP 8


CA09
M931 120-mm Full Range Practice
Cartridge (Zone 4 - propelling charge)
FP 8


D533
M119A2 155-mm Propelling Charge (Zone
7)
FP 5


D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP 1

02/08
Ordnance Detonation
33

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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment

D540
M3 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP 5


D540
M3 155-mm Propelling Charge (Zone 3,
M284 Cannon)
FP 1


D540
M3 155-mm Propelling Charge (Zone 5,
Ml99 Cannon)
FP 1


D540
M3A1 155-mm Propelling Charge (Zone 3,
Ml99 Cannon)
FP 1

Propellant,
continued
D540
D541
M3A1 155-mm Propelling Charge (Zone 3,
M284 Cannon)
M4A2 155-mm Propelling Charge (Zone 7)
FP 1
FP 5
20+ data points

M174a
MK209 Impulse Cartridge
EO 10


M842a
Ml Squib
Unclear


MD73a
M796 Impulse Cartridge
EO 10


MN60a
M79 Igniter
EO 9


PJ02
FIM-92A Stinger-Basic Guided Missile
(launch motor)
EO 5


PJ02
FIM-92A Stinger-Basic Guided Missile
(flight motor)
FP 7


H975a
Rocket, 2.75-inch M274 Signature Smoke
with H872 Warhead
DPG VIII


L366
M74A1 Projectile Air Burst Simulator
DPGIV-B


L495
M49A1 Surface Trip Flare
DPG II


L508a
M72 Red Railroad Warning Fuse
DPG VI


L592
TOW Blast Simulator
DPG V-A


L594
M115A2 Ground Burst Simulator
DPG I

Pyrotechnic
L595a
L596
M9 Liquid Projectile Air Burst Simulator
Ml 10 Flash Artillery Simulator
EO 12
DPG I
20+ data points

L598
Ml 17 Flash Booby Trap Simulator
DPG I


L599
Ml 18 Illuminating Booby Trap Simulator
DPG II


L600
Ml 19 Whistling Booby Trap Simulator
DPG II


L601
M116A1 Hand Grenade Simulator
DPG I


L602
M21 Artillery Flash Simulator
DPG IV-B


L709
M25 Target Hit Simulator
EO 2


L709
XM25 Target Hit Simulator
DPG V-B

34
Ordnance Detonation
02/08

-------
TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment

L720
M26 Target Kill Simulator
EO 6


M327a
Coupling Base Firing Device
EO 10


M448a
M2 Percussion Detonator
EO 11


M626a
Ml Push Type Demolition Firing Device
EO 9

Pyrotechnic,
continued
M627a
M630
M5 Pressure Release Igniter
Ml Pull Type Demolition Firing Device
EO 10
DPG V-A
20+ data points

M630a
Ml Pull Type Demolition Firing Device
EO 9


M670a
M700 Blasting Fuse
EO 11


M766a
M60 Igniter
EO 9


ML03a
Ml42 Firing Device
EO 11


H459
Rocket, 2.75-inch Flechette, MK40 Mod 3
FP 7


Motor (propelling rocket only)


H557
M72A3 66-mm High Explosive Antitank
Rocket (propelling rocket only)
FP 4

Rocket/Missile
H557
M72A3 66-mm High Explosive Antitank
Rocket (propelling rocket only)
FP 7
10+ data points

H708
M73 35-mm Subcaliber Practice Rocket
FP 9


(motor only)
Rocket, 2.75-inch M267 Practice Warhead,


H974
MK66 Mod 3 Motor (propelling rocket
only)
FP 7


A010
M220 10 Gage Blank/Subcaliber Salute
Cartridge
FP 9


AO 11
12 Gage #00 Shot Cartridge
FP 9


A017
12 Gage #9 Shot Cartridge
FP 10


A059
M855 5.56-mm Ball Cartridge (fired from
the M16A1 Rifle)
FP 3

Small Arm-FP
A059
A059
M855 5.56-mm Ball Cartridge (fired from
the M16A2 Rifle)
M855 5.56-mm Ball Cartridge (No-Lead)
FP 3
FP 4
20+ data points

A063
M856 5.56-mm Tracer Cartridge
FP 3


A065
M862 5.56-mm Practice Ball Cartridge
FP 3


A066
M193 5.56-mm Ball Cartridge
FP 6


A068
M196 5.56-mm Tracer Cartridge
FP 6


A080
M200 5.56-mm Blank Cartridge
FP 3


A086
.22 Caliber Long Rifle Ball Cartridge
FP 4

02/08
Ordnance Detonation
35

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TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment

A106
.22 Caliber Standard Velocity Long Rifle
Ball Cartridge
FP 4


Alll
M82 7.62-mm Blank Cartridge
FP 3


A131
M62 7.62-mm Tracer Cartridge
FP 6


A136
Ml 18 7.62-mm Ball Match Cartridge
FP 6


A143
M80 7.62-mm Ball Cartridge
FP 3


A171
M852 7.62-mm Ball Match Cartridge
FP 6


A182
Ml .30 Caliber Ball Cartridge
FP 6


A212
M2 .30 Caliber Ball Cartridge
FP 6


A218
M25 .30 Caliber Tracer Cartridge
FP 9


A247
M72 .30 Caliber Ball Match Cartridge
FP 6

Small Arm-FP,
continued
A363
A365
M882 9-mm Ball Cartridge
M181A1 14.5-mm Artillery Training
Cartridge
FP 3
DPG V-A
20+ data points

A366a
Ml82 14.5-mm Cartridge
EO 11


A400
M41 .38 Caliber Special Ball Cartridge
FP 9


A403
.38 Caliber Special Blank Cartridge
FP 9


A475
M1911 .45 Caliber Ball Cartridge
FP 3


A518
M903 .50 Caliber SLAP Ball Cartridge
FP 9


A518
M962 .50 Caliber SLAP-Tracer Cartridge
FP 10


A525
M2 .50 Caliber Armor Piercing Cartridge
FP 8


A557
M17 .50 Caliber Tracer Cartridge
FP 3


A557
M33 .50 Caliber Ball Cartridge
FP 3


A598
M1A1 .50 Caliber Blank Cartridge
FP 3


C870a
M819 81-mm Red Phosphorous Smoke
(IUK)
DPG VII


G815a
Red Phosphorous Smoke Screening
Grenade Launcher (UK)
DPG VII

Smoke
G930
G940
AN-M8 Hexachloroethane (HC) Smoke
Hand Grenade
M18 Green Smoke Hand Grenade
DPG V-A
DPG III
10+ data points

G945
M18 Yellow Smoke Hand Grenade
DPG III


G950
M18 Red Smoke Hand Grenade
DPG III


G950
Ml8 Red Smoke Hand Grenade (new
formulation)
DPG V-A

36
Ordnance Detonation
02/08

-------
TABLE 9 (cont.)
Category
DODIC
Ordnance Description
Test Series
Comment

G955
M18 Violet Smoke Hand Grenade
DPG III

Smoke,
continued
G955
K866a
Ml8 Violet Smoke Hand Grenade (new
formulation)
ABC-M5 HC Ground Smoke Pot (MILES)
DPG V-A
DPG VII
10+ data points

K867a
M4A2 Floating Smoke Pot
DPG VII

a Although testing may have been completed, emission factors for this ordnance have not yet been
analyzed for inclusion in AP-42; therefore, these data were not included when the data correlation was
assessed.
In addition to assessing the data correlation, an assessment was made of the number of test data
points available within each of the 17 ordnance categories. Because each ordnance test consisted of two
test data points (i.e., two test runs per ordnance or two independent sampling trains were used during an
ordnance test), the number of test data points available in each of the ordnance categories varied from 2 to
66. Based upon information provided by EPA,9 the following assumptions were used to assess whether
sufficient category-specific test data points were available to justify elevating the emission factor ratings
based on ordnance-specific data only:
1.	If 20 or more data points were available, the emission factor rating could be elevated to a
maximum of an A, provided that the data also demonstrated a good correlation.
2.	If at least 10 but less than 20 data points w ere available, the emission factor rating could be
elevated to a maximum of a B. provided that the data also demonstrated a good correlation.
3.	If less than 10 data points were available, the emission factor rating could not be elevated,
regardless of the data correlation.
4.	If the data demonstrated a fair correlation and 20 or more data points were available, the emission
factor rating could be elevated to a maximum of a B.
5.	If the data demonstrated a fair correlation and at least 10 but less than 20 data points were
available, the emission factor rating could be elevated to a maximum of a C.
Using the criteria specified above, the emission factor ratings assigned to ordnance in each of the
17 ordnance categories were reevaluated. This evaluation indicated that some of the emission factor
ratings associated with ordnance included in nine categories could be elevated from a C or D rating to an
A or B rating. These nine categories are:
1.
Demolition
2.
Illumination
3.
Medium - Firing Point
4.
Projectiles
5.
Propellants
6.
Pyrotechnics
7.
Rocket/Missile
8.
Small Arms - Firing Point
9.
Smokes

A final assessment was made as to the emission factor rating assigned based on ordnance-specific
test data only. If the original emission factor data rating assigned was a C, then the emission factor rating
02/08
Ordnance Detonation
37

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was elevated to an A or B, as appropriate, based upon the data for the whole ordnance category. If the
original emission factor data rating assigned was a D, then the emission factor rating was elevated to a B
or C, as appropriate, based upon the data for the whole ordnance category. The analysis is documented in
an Excel spreadsheet that is located on the EPA website at: http://www.epa.gov/ttn/chief/ap42/index.html.
Within the current test series, DODICs M130, M131, ML47, MN02, MN03, and MN06 were
included in the Demolition category, which included more than 20 test data points. As a result, some
emission factor ratings associated with these ordnance were elevated. DODIC N286 was included in the
Fuse category, which included less than 10 data points. As a result, the emission factor ratings associated
with this ordnance were not elevated. The emission factor ratings assigned are presented in Appendix A.
6.0 REFERENCES
1.	Report No. 7 for the Exploding Ordnance Emission Study Phase II, Military Environmental
Technology Demonstration Center, U.S. Army Aberdeen Test Center, Aberdeen Proving Ground,
MD, February 2006.
2.	Detailed Test Plan No. 7 for the Exploding Ordnance Emission Study Phase II, Military
Environmental Technology Demonstration Center, U.S. Army Aberdeen Test Center, Aberdeen
Proving Ground, MD, August 2003.
3.	Supporting information including Excel spreadsheets, analytical results, field notes, and case
summaries supplied upon request by the Applied Science Test Team - Chemistry Unit, U.S.
Army Aberdeen Test Center. Aberdeen Proving Ground. MD. January 2007.
4.	Procedures for Preparing Emission Factor Documents,EPA-454/R-95-015, U.S. Environmental
Protection Agency, Research Triangle Park, NC, November 1997.
5.	Draft Detailed Procedures for Preparing Emission Factors, U.S. Environmental Protection
Agency, Research Triangle Park, NC, June 2006.
6.	Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air,
Second Supplement, EPA/600/4-89/018, U.S. Environmental Protection Agency, Research
Triangle Park, NC, June 1988.
7.	Test Methods for Evaluating Solid Waste, Physical/Chemical Methods (SW-846), U.S.
Environmental Protection Agency, http://www.epa.gov/epaoswer/hazwaste/test/sw846.htm.
8.	National Institute for Occupational Safety and Health (NIOSH) Manual of Analytical Methods
(NMAM), Fourth Edition, National Institute for Occupational Safety and Health, Cincinnati, OH.
9.	Information regarding the relationship between emission factor data correlation, the number of
data points available, and the resulting emission factor rating assigned supplied upon request by
Mr. Ron Myers, Measurement Policy Group, Office of Air Quality Planning and Standards, U.S.
Environmental Protection Agency, Research Triangle Park, NC, June 2006.
38
Ordnance Detonation
02/08

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APPENDIX A
COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR ORDNANCE
INCLUDED IN EXPLODING ORDNANCE EMISSION STUDY PHASE II SERIES 7 TESTING
AT ABERDEEN PROVING GROUND, MARYLAND
02/08
Ordnance Detonation
A-l

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A-2	Ordnance Detonation	02/08

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TABLE A1 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC M130, M6 ELECTRIC BLASTING CAP


Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
7.2 E-04
2.4 E-01
--
630-08-0
Carbon monoxide8
3.2 E-04
1.1 E-01
--
7439-92-1
Lead
1.5 E-04
5.1 E-02
--
74-82-8
Methane
4.5 E-06
1.6E-03
--
--
Oxides of nitrogenf
7.7 E-05
2.6 E-02
--
--
PM-2.58
2.4 E-04
8.2 E-02
--
~
PM-10
4.0 E-04
1.4 E-01
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
4.1 E-04
1.4 E-01
--
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
ND
ND
1.7 E-05
208-96-8
Acenaphthylene8
0
0
--
75-07-0
Acetaldehyde
1.5 E-07
5.3 E-05
~
75-05-8
Acetonitrile1
2.3 E-06
7.8 E-04
~
107-02-8
Acrolein
ND
ND
7.6 E-03
107-13-1
Acrylonitrile1
2.7 E-08
9.3 E-06
--
107-05-1
Allyl chloride
ND
ND
3.2 E-03
7429-90-5
Aluminum8
2.3 E-05
8.0 E-03
~
7664-41-7
Ammonia8
5.0 E-05
1.7 E-02
--
120-12-7
Anthracene8
ND
ND
8.5 E-05
7440-36-0
Antimony
0
0
~
7440-38-2
Arsenic
ND
ND
2.0 E-03
7440-39-3
Barium
6.2 E-08
2.1 E-05
--
71-43-2
Benzene1
6.9 E-08
2.3 E-05
~
56-55-3
Benzo [a] anthracene8
ND
ND
1.7 E-05
205-99-2
Benzo [b] fluoranthene8
ND
ND
1.7 E-05
207-08-9
Benzo [k] fluoranthene8
ND
ND
1.7 E-05
191-24-2
Benzo [g,h,i]perylene
ND
ND
1.7 E-05
50-32-8
Benzo [a]pyrene8
ND
ND
1.7 E-05
192-97-2
Benzo [e]pyrene
ND
ND
1.7 E-05
100-44-7
Benzyl chloride
ND
ND
5.3 E-03
7440-41-7
Beryllium
ND
ND
2.0 E-03
75-25-2
Bromoform
ND
ND
1.1 E-02
02/08
Ordnance Detonation
A-3

-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.9E-03
101-55-3
4-Bromophenylphenylether
ND
ND
1.7 E-02
106-99-0
1,3-Butadiene8
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
3.1 E-03
85-68-7
Butylbenzylphthalatef
ND
ND
1.7 E-02
123-72-8
Butyraldehyde
ND
ND
7.6 E-03
7440-43-9
Cadmium
ND
ND
2.0 E-03
75-15-0
Carbon disulfide
ND
ND
3.2 E-03
56-23-5
Carbon tetrachloride
ND
ND
6.4 E-03
106-47-8
4-Chloroaniline
ND
ND
1.7 E-02
108-90-7
Chlorobenzene
ND
ND
4.7 E-03
75-45-6
Chlorodifluoromethane
ND
ND
3.6 E-03
75-00-3
Chloroethane
ND
ND
2.7 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.7 E-02
67-66-3
Chloroform
ND
ND
5.0 E-03
74-87-3
Chloromethane
ND
ND
2.1 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.7 E-02
95-57-8
2-Chlorophenol
ND
ND
1.7 E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.7 E-02
7440-47-3
Chromium
1.3 E-07
4.6 E-05
--
18540-29-9
Hexavalent chromium1
ND
ND
5.8E-01
218-01-9
Chrysene
ND
ND
1.7 E-05
7440-48-4
Cobalt8
1.1 E-08
3.7 E-06
--
7440-50-8
Copper8
3.1 E-07
1.1 E-04
--
106-44-5
p-Cresol
ND
ND
1.7 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.6 E-03
98-82-8
Cumene8
ND
ND
5.0 E-03
57-12-5
Particulate cyanide
ND
ND
1.2 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.7 E-05
132-64-9
Dibenzofuran
ND
ND
1.7 E-02
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-03
84-74-2
Dibutyl phthalate8
ND
ND
1.7 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-03
A-4
Ordnance Detonation
02/08

-------
TABLE A1 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-03
75-27-4
Dichlorobromomethane
ND
ND
6.8 E-03
75-71-8
Dichlorodifluoromethane8
ND
ND
5.0 E-03
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-03
75-43-4
Dichlorofluoromethane
ND
ND
4.3 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.7 E-02
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-03
10061-02-6
trans-1,3-Dichloropropene
ND
ND
4.6 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-03
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.6 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.6 E-04
606-20-2
2,6-Dinitrotoluene8
ND
ND
6.6 E-04
123-91-1
1,4-Dioxane
ND
ND
3.7 E-03
--
Total dioxin/furan compounds
1.1 E-12
3.7E-10
--
140-88-5
Ethyl acrylate
ND
ND
4.2 E-03
100-41-4
Ethylbenzene8
ND
ND
4.4 E-03
74-85-1
Ethylene
2.6 E-07
8.8 E-05
--
206-44-0
Fluoranthene8
2.3 E-09
7.9 E-07
--
86-73-7
Fluorene
ND
ND
1.7 E-05
50-00-0
Formaldehyde
5.9 E-07
2.0 E-04
--
76-13-1
Freon 113
ND
ND
7.8 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxinJ
8.7 E-14
3.0 E-ll
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
7.8 E-14
2.7 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
HeptachlorodibenzofuranJ
6.1 E-14
2.1 E-ll
--
118-74-1
Hexachlorobenzene
ND
ND
1.7 E-02
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
02/08
Ordnance Detonation
A-5

-------
TABLE A1 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxinJ
1.3 E-14
4.5 E-12
--
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxinJ
1.5 E-14
5.1 E-12
--
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxinJ
2.1 E-14
7.2 E-12
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
3.1 E-14
1.1 E-ll
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
2.5 E-14
8.5 E-12
--
72918-21-9
1,2,3,7,8,9-
Hexachlorodibenzofuran1
1.9 E-14
6.5 E-12
--
60851-34-5
2,3,4,6,7,8-
HexachlorodibenzofuranJ
2.3 E-14
7.9 E-12
~
67-72-1
Hexachloroethane
ND
ND
9.8 E-03
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
2.6 E-06
9.0 E-04
~
74-90-8
Hydrogen cyanide8
2.2 E-05
7.4 E-03
~
7664-39-3
Hydrogen fluoride
ND
ND
2.0E-01
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
ND
1.7 E-05
78-59-1
Isophorone
ND
ND
1.7 E-02
7439-96-5
Manganese8
2.5 E-07
8.4 E-05
--
96-33-3
Methyl acrylate
ND
ND
3.6 E-03
74-95-3
Methylene bromide
ND
ND
7.2 E-03
75-09-2
Methylene chloride
0
0
~
74-88-4
Methyl iodide
ND
ND
5.9 E-03
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-03
80-62-6
Methyl methacrylate
ND
ND
4.2 E-03
91-57-6
2-Methylnaphthalene
ND
ND
1.7 E-02
95-48-7
2-Methylphenol
ND
ND
1.7 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-03
91-20-3
Naphthalene8
6.7 E-09
2.3 E-06
--
7440-02-0
Nickel1
1.4 E-07
4.7 E-05
--
7697-37-2
Nitric acidf
ND
ND
1.1 E-01
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
4.8 E-09
1.6 E-06
~
55-63-0
Nitroglycerin
ND
ND
6.6 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
A-6
Ordnance Detonation
02/08

-------
TABLE A1 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-
p-dioxin
3.9 E-13
1.3 E-10
--
39001-02-0
1,2,3,4,6,7,8,9-
OctachlorodibenzofuranJ
3.0 E-13
1.0 E-10
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
2.8 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
ND
ND
2.2 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
2.2 E-09
87-86-5
Pentachlorophenol
ND
ND
1.7 E-02
85-01-8
Phenanthrene8
3.4 E-09
1.2 E-06
--
108-95-2
Phenol
ND
ND
1.7 E-02
123-38-6
Propionaldehyde
4.3 E-08
1.5 E-05
--
115-07-1
Propylene8
3.1 E-08
1.0 E-05
--
129-00-0
Pyrenef
1.7 E-09
5.9 E-07
~
7782-49-2
Selenium
ND
ND
2.0 E-03
7440-22-4
Silver
ND
ND
2.0 E-03
100-42-5
Styrene8
ND
ND
4.3 E-03
7664-93-9
Sulfuric acid
ND
ND
1.2E-01
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
2.2 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
1.6E-14
5.5 E-12
--
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
7.0 E-03
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-03
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-03
7440-28-0
Thallium
ND
ND
2.0 E-03
108-88-3
Toluene1
3.4 E-08
1.1 E-05
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-03
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-03
75-69-4
Trichlorofluoromethane
ND
ND
5.7 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-03
02/08
Ordnance Detonation
A-7

-------
TABLE A1 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
95-63-6
1,2,4-Trimethylbenzene8
ND
ND
5.0 E-03
540-84-1
2,2,4-Trimethylpentane8
ND
ND
4.8 E-03
7440-62-2
Vanadium
1.1 E-08
3.7 E-06
--
108-05-4
Vinyl acetate
ND
ND
3.6 E-03
75-01-4
Vinyl chloride
ND
ND
2.6 E-03
75-35-4
Vinylidene chloride
ND
ND
4.0 E-03
106-42-3,
108-38-3
m-Xylene, p-Xylene8
ND
ND
4.4 E-03
95-47-6
o-Xylene8
ND
ND
4.4 E-03
7440-66-6
Zinc
2.4 E-07
8.3 E-05
—
Other Po
lutants
67-64-1
Acetone
ND
ND
7.3 E-02
74-86-2
Acetylene8
2.3 E-07
7.9 E-05
--
35572-78-2
2-Amino-4,6-dinitrotoluene8
ND
ND
6.6 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.6 E-04
100-52-7
Benzaldehydek
ND
ND
7.6 E-03
65-85-0
Benzoic acidk
9.4 E-09
3.2 E-06
--
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
6.5 E-03
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butenef
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calciumf
1.1 E-06
3.6 E-04
--
7440-44-0
Elemental carbonf
8.0 E-06
2.7 E-03
--
7440-44-0
Organic carbon8
1.4 E-05
4.9 E-03
--
7440-44-0
Total carbon8
2.2 E-05
7.6 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.7 E-02
124-48-1
Dibromochloromethane
ND
ND
8.7 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.0 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.0 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
4.6 E-03
A-8
Ordnance Detonation
02/08

-------
TABLE A1 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
84-66-2
Diethylphthalate
ND
ND
1.7E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.6 E-03
117-84-0
Di-n-octylphthalate8
ND
ND
1.7E-02
74-84-0
Ethane8
ND
ND
2.5 E-02
3637-01-2
Ethanone, l-(3,4-dimethylphenyl)k
1.4 E-10
4.9 E-08
~
937-30-4
Ethanone, l-(4-ethylphenyl)k
8.4 E-ll
2.9 E-08
~
141-78-6
Ethyl acetate
ND
ND
3.7 E-03
97-63-2
Ethyl methacrylate
ND
ND
4.7 E-03
622-96-8
4-Ethyltoluene8
ND
ND
5.0 E-03
142-82-5
n-Heptane8
ND
ND
4.2 E-03
66-25-1
Hexaldehyde
ND
ND
7.6 E-03
591-78-6
2-Hexanone
ND
ND
4.2 E-03
2691-41-0
HMX
ND
ND
1.6 E-03
10035-10-6
Hydrogen bromide
ND
ND
1.2 E-01
75-28-5
Isobutanek
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.6 E-03
7439-95-4
Magnesium8
9.8 E-07
3.3 E-04
--
75-52-5
Methane, nitro-h
1.8 E-08
6.2 E-06
--
78-93-3
Methyl ethyl ketone
ND
ND
3.0 E-03
98-83-9
alpha-Methylstyrene
ND
ND
4.9 E-03
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.6 E-04
88-74-7
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.6 E-04
99-08-1
3-Nitrotoluene
ND
ND
3.3 E-03
99-99-0
4-Nitrotoluene
ND
ND
6.6 E-04
111-65-9
Octane8
ND
ND
4.8 E-03
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.3 E-01
7664-38-2
Phosphoric acid
ND
ND
1.0 E-01
74-98-6
Propane8
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl8
0
0
--
74-99-7
Propyne8
ND
ND
3.3 E-02
121-82-4
RDX
3.6 E-08
1.2 E-05
--
02/08
Ordnance Detonation
A-9

-------
TABLE A1 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.2 E-02
25323-89-1
Trichloroethene
ND
ND
5.0 E-03
108-67-8
1,3,5 -T rimethy lbenzene8
ND
ND
5.0 E-03
99-35-4
1,3,5 -T rinitrobenzene8
ND
ND
6.6 E-04
118-96-7
2,4,6-Trinitrotoluene1
5.1 E-09
1.8 E-06
--
110-62-3
Valeraldehyde
ND
ND
7.6 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 2.92 E-03 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a B rating.
1 Emission factor was originally rated D because the factor is for a tentatively identified compound, but
because of correlation with emission factors for similar ordnance and number of data points the factor
was upgraded from a D rating to a C rating.
J Emission factor rated D because the factor is based upon C-rated test data.
k Emission factor rated D because the factor is for a tentatively identified compound.
A-10
Ordnance Detonation
02/08

-------
TABLE A2 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC M131, M7 NON-ELECTRIC BLASTING CAP


Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
8.2 E-04
3.0 E-01
--
630-08-0
Carbon monoxide8
2.9 E-04
1.1 E-01
--
7439-92-1
Lead
2.6 E-04
9.5 E-02
--
74-82-8
Methane
5.2E-06
1.9E-03
--
--
Oxides of nitrogenf
7.1 E-05
2.6 E-02
--
--
PM-2.58
3.4 E-04
1.2 E-01
--
--
PM-10
4.9 E-04
1.8 E-01
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
5.1 E-04
1.9 E-01
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
ND
ND
1.7 E-05
208-96-8
Acenaphthylene8
9.3 E-10
3.4 E-07
--
75-07-0
Acetaldehyde1
0
0
~
75-05-8
Acetonitrile8
2.7 E-06
9.8 E-04
--
107-02-8
Acrolein
ND
ND
7.3 E-03
107-13-1
Acrylonitrile8
4.9 E-07
1.8 E-04
~
107-05-1
Allyl chloride
ND
ND
3.2 E-03
7429-90-5
Aluminum8
2.6 E-05
9.6 E-03
--
7664-41-7
Ammonia8
4.1 E-05
1.5 E-02
~
120-12-7
Anthracene8
ND
ND
8.5 E-05
7440-36-0
Antimony
1.4 E-08
5.0 E-06
~
7440-38-2
Arsenic
ND
ND
2.0 E-03
7440-39-3
Barium1
1.5 E-06
5.3 E-04
--
71-43-2
Benzene8
7.3 E-08
2.7 E-05
~
56-55-3
Benzo [a] anthracene8
ND
ND
1.7 E-05
205-99-2
Benzo [b] fluoranthene8
ND
ND
1.7 E-05
207-08-9
Benzo [k] fluoranthene8
ND
ND
1.7 E-05
191-24-2
Benzo [g,h,i]perylene
ND
ND
1.7 E-05
50-32-8
Benzo [a]pyrene8
ND
ND
1.7 E-05
192-97-2
Benzo [e]pyrene
ND
ND
1.7 E-05
100-44-7
Benzyl chloride
ND
ND
5.3 E-03
7440-41-7
Beryllium
ND
ND
2.0 E-03
75-25-2
Bromoform
ND
ND
1.1 E-02
02/08
Ordnance Detonation
A-ll

-------
TABLE A2 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.9 E-03
101-55-3
4-Bromophenylphenylether
ND
ND
1.7 E-02
106-99-0
1,3-Butadiene8
3.5 E-07
1.3 E-04
--
75-65-0
t-Butyl alcohol
ND
ND
3.1 E-03
85-68-7
Butylbenzylphthalatef
ND
ND
1.7 E-02
123-72-8
Butyraldehyde
ND
ND
7.3 E-03
7440-43-9
Cadmium
ND
ND
2.0 E-03
75-15-0
Carbon disulfide
ND
ND
3.2 E-03
56-23-5
Carbon tetrachloride
ND
ND
6.4 E-03
106-47-8
4-Chloroaniline
ND
ND
1.7 E-02
108-90-7
Chlorobenzene
ND
ND
4.7 E-03
75-45-6
Chlorodifluoromethane
ND
ND
3.6 E-03
75-00-3
Chloroethane
ND
ND
2.7 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.7 E-02
67-66-3
Chloroform
ND
ND
5.0 E-03
74-87-3
Chloromethane
ND
ND
2.1 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.7 E-02
95-57-8
2-Chlorophenol
ND
ND
1.7 E-02
7005-72-3
4-Chlorophenyl-phenylether
ND
ND
1.7 E-02
7440-47-3
Chromium
1.4 E-07
5.0 E-05
--
18540-29-9
Hexavalent chromium11
1.4 E-05
5.0 E-03
--
218-01-9
Chrysene
ND
ND
1.7 E-05
7440-48-4
Cobalt8
ND
ND
2.0 E-03
7440-50-8
Copper8
1.9 E-07
6.9 E-05
--
106-44-5
p-Cresol
ND
ND
1.7 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.3 E-03
98-82-8
Cumene8
ND
ND
5.0 E-03
57-12-5
Particulate cyanide
ND
ND
1.2 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.7 E-05
132-64-9
Dibenzofuran
ND
ND
1.7 E-02
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-03
84-74-2
Dibutyl phthalate8
ND
ND
1.7 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-03
A-12
Ordnance Detonation
02/08

-------
TABLE A2 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-03
75-27-4
Dichlorobromomethane
ND
ND
6.8 E-03
75-71-8
Dichlorodifluoromethane8
ND
ND
5.0 E-03
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-03
75-43-4
Dichlorofluoromethane
ND
ND
4.3 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.7 E-02
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-03
10061-02-6
trans-1,3-Dichloropropene
ND
ND
4.6 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-03
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.6 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.6 E-04
606-20-2
2,6-Dinitrotoluene8
ND
ND
6.6 E-04
123-91-1
1,4-Dioxane
ND
ND
3.7 E-03
--
Total dioxin/furan compounds
2.5 E-14
8.9E-12
--
140-88-5
Ethyl acrylate
ND
ND
4.2 E-03
100-41-4
Ethylbenzene8
ND
ND
4.4 E-03
74-85-1
Ethylene
5.0E-07
1.8E-04
--
206-44-0
Fluoranthene8
1.7 E-09
6.2 E-07
--
86-73-7
Fluorene
ND
ND
1.7 E-05
50-00-0
Formaldehyde
2.4 E-07
8.8 E-05
--
76-13-1
Freon 113
ND
ND
7.8 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
1.6 E-14
5.7 E-12
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
ND
ND
3.7 E-09
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
4.2 E-09
118-74-1
Hexachlorobenzene
ND
ND
1.7 E-02
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
02/08
Ordnance Detonation
A-13

-------
TABLE A2 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
1.5 E-09
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
1.5 E-09
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
1.5 E-09
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
8.7E-15
3.2E-12
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
1.1 E-09
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
1.1 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
1.1 E-09
67-72-1
Hexachloroethane
ND
ND
9.8 E-03
110-54-3
Hexane
ND
ND
7.2 E-02
74-90-8
Hydrogen cyanide8
1.5 E-05
5.4 E-03
--
7664-39-3
Hydrogen fluoride
ND
ND
1.0E-01
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
ND
1.7 E-05
78-59-1
Isophorone
ND
ND
1.7 E-02
7439-96-5
Manganese8
2.1 E-07
7.5 E-05
--
96-33-3
Methyl acrylate
ND
ND
3.6 E-03
74-95-3
Methylene bromide
ND
ND
7.2 E-03
75-09-2
Methylene chloride
0
0
--
74-88-4
Methyl iodide
ND
ND
5.9 E-03
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-03
80-62-6
Methyl methacrylate
3.8E-08
1.4 E-05
--
91-57-6
2-Methylnaphthalene
ND
ND
1.7 E-02
95-48-7
2-Methylphenol
ND
ND
1.7 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-03
91-20-3
Naphthalene8
8.2 E-09
3.0 E-06
--
7440-02-0
Nickel8
5.5 E-08
2.0 E-05
--
7697-37-2
Nitric acidf
ND
ND
1.0E-01
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
ND
ND
6.6 E-04
55-63-0
Nitroglycerin
ND
ND
6.6 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7 E-02
A-14
Ordnance Detonation
02/08

-------
TABLE A2 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7 E-02
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
2.5 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
ND
ND
2.0 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
1.9 E-09
87-86-5
Pentachlorophenol
ND
ND
1.7 E-02
85-01-8
Phenanthrene8
3.1 E-09
1.1 E-06
--
108-95-2
Phenol
ND
ND
1.7 E-02
123-38-6
Propionaldehyde
ND
ND
7.3 E-03
115-07-1
Propylene8
5.5 E-08
2.0 E-05
--
129-00-0
Pyrenef
ND
ND
1.7 E-02
7782-49-2
Selenium
ND
ND
2.0 E-03
7440-22-4
Silver
ND
ND
2.0 E-03
100-42-5
Styrene8
ND
ND
4.3 E-03
7664-93-9
Sulfuric acid
ND
ND
1.0E-01
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
2.0 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofiiran
ND
ND
1.6 E-09
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
7.0 E-03
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-03
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-03
7440-28-0
Thallium
ND
ND
2.0 E-03
108-88-3
Toluene8
ND
ND
3.8 E-03
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-03
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-03
75-69-4
Trichlorofluoromethane
ND
ND
5.7 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-03
95-63-6
1,2,4-Trimethylbenzene8
ND
ND
5.0 E-03
540-84-1
2,2,4-Trimethylpentane8
ND
ND
4.8 E-03
7440-62-2
Vanadium
ND
ND
2.0 E-03
108-05-4
Vinyl acetate
ND
ND
3.6 E-03
75-01-4
Vinyl chloride
ND
ND
2.6 E-03
75-35-4
Vinylidene chloride
ND
ND
4.0 E-03
02/08
Ordnance Detonation
A-15

-------
TABLE A2 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
106-42-3,
108-38-3
m-Xylene, p-Xylene8
ND
ND
4.4 E-03
95-47-6
o-Xylene8
ND
ND
4.4 E-03
7440-66-6
Zinc
1.8 E-07
6.7 E-05
—
Other Po
lutants
67-64-1
Acetone
ND
ND
7.1 E-02
74-86-2
Acetylene11
2.1 E-07
7.5 E-05
--
35572-78-2
2-Amino-4,6-dinitrotoluene8
ND
ND
6.6 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.6 E-04
100-52-7
Benzaldehyde
ND
ND
7.3 E-03
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
6.5 E-03
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butenef
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calciumf
9.9 E-07
3.6 E-04
--
7440-44-0
Elemental carbonf
4.2 E-06
1.5 E-03
--
7440-44-0
Organic carbon8
1.7 E-05
6.0 E-03
--
7440-44-0
Total carbon8
2.1 E-05
7.6 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.7 E-02
124-48-1
Dibromochloromethane
ND
ND
8.7 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.0 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.0 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
4.6 E-03
84-66-2
Diethylphthalate
ND
ND
1.7 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.3 E-03
117-84-0
Di-n-octylphthalate8
ND
ND
1.7 E-02
74-84-0
Ethane8
ND
ND
2.5 E-02
141-78-6
Ethyl acetate
ND
ND
3.7 E-03
97-63-2
Ethyl methacrylate
ND
ND
4.7 E-03
622-96-8
4-Ethyltoluene8
ND
ND
5.0 E-03
A-16
Ordnance Detonation
02/08

-------
TABLE A2 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
142-82-5
n-Heptane8
ND
ND
4.2 E-03
66-25-1
Hexaldehyde
ND
ND
7.3 E-03
591-78-6
2-Hexanone
ND
ND
4.2 E-03
2691-41-0
HMX
ND
ND
1.6 E-03
10035-10-6
Hydrogen bromide
ND
ND
1.0 E-01
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.3 E-03
7439-95-4
Magnesium8
1.1 E-06
3.8 E-04
~
78-93-3
Methyl ethyl ketone
ND
ND
3.0 E-03
98-83-9
alpha-Methylstyrene
ND
ND
4.9 E-03
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.6 E-04
88-74-7
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.6 E-04
99-08-1
3-Nitrotoluene
ND
ND
3.4 E-03
99-99-0
4-Nitrotoluene
ND
ND
6.6 E-04
111-65-9
Octane8
ND
ND
4.8 E-03
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.3 E-01
7664-38-2
Phosphoric acid1
9.7 E-07
3.5 E-04
--
74-98-6
Propane8
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl8
1.5 E-07
5.5 E-05
--
74-99-7
Propyne8
ND
ND
3.3 E-02
121-82-4
RDX
3.1 E-07
1.1 E-04
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.2 E-02
25323-89-1
Trichloroethene
ND
ND
5.0 E-03
108-67-8
1,3,5 -T rimethy lbenzene8
ND
ND
5.0 E-03
99-35-4
1,3,5 -T rinitrobenzene8
ND
ND
6.6 E-04
118-96-7
2,4,6-Trinitrotoluene8
2.3 E-08
8.2 E-06
--
110-62-3
Valeraldehyde
ND
ND
7.3 E-03
02/08
Ordnance Detonation
A-17

-------
TABLE A2 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 2.76 E-03 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor was originally rated D because the factor is for a tentatively identified compound, but
because of correlation with emission factors for similar ordnance and number of data points the factor
was upgraded from a D rating to a C rating.
1 Emission factor rated D because the factor is based upon C-rated test data.
A-18
Ordnance Detonation
02/08

-------
TABLE A3 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC ML47, Ml 1 NON-ELECTRIC BLASTING CAP WITH 30-FOOT SHOCK TUBE


Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
1.8 E-03
6.5 E-01
--
630-08-0
Carbon monoxide8
3.1 E-04
1.2 E-01
--
7439-92-1
Lead
1.3 E-04
4.8 E-02
--
74-82-8
Methane
2.8 E-05
1.0E-02
--
--
Oxides of nitrogenf
4.5 E-05
1.7 E-02
--
--
PM-2.58
2.9 E-04
1.1 E-01
--
--
PM-10
4.6 E-04
1.7 E-01
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
4.8 E-04
1.8 E-01
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
ND
ND
1.7 E-05
208-96-8
Acenaphthylene8
4.3 E-09
1.6 E-06
--
75-07-0
Acetaldehyde
1.6E-07
5.9 E-05
--
75-05-8
Acetonitrile8
1.3 E-06
4.9 E-04
--
107-02-8
Acrolein
ND
ND
7.5 E-03
107-13-1
Acrylonitrile8
3.2 E-07
1.2 E-04
--
107-05-1
Allyl chloride
ND
ND
3.2 E-03
7429-90-5
Aluminum8
5.5 E-05
2.0 E-02
--
7664-41-7
Ammonia8
0
0
~
120-12-7
Anthracene8
ND
ND
8.5 E-05
7440-36-0
Antimony
0
0
--
7440-38-2
Arsenic
ND
ND
2.1 E-03
7440-39-3
Barium
1.2 E-07
4.5 E-05
--
71-43-2
Benzene8
2.1 E-06
7.8 E-04
~
56-55-3
Benzo [a] anthracene8
ND
ND
1.7 E-05
205-99-2
Benzo [b] fluoranthene8
ND
ND
1.7 E-05
207-08-9
Benzo [k] fluoranthene8
1.8 E-09
6.7 E-07
~
191-24-2
Benzo [g,h,i]perylene
2.6 E-09
9.5 E-07
--
50-32-8
Benzo [a]pyrene8
1.7 E-09
6.2 E-07
~
192-97-2
Benzo [e]pyrene
ND
ND
1.7 E-05
100-44-7
Benzyl chloride
ND
ND
5.3 E-03
7440-41-7
Beryllium
ND
ND
2.1 E-03
75-25-2
Bromoform
ND
ND
1.1 E-02
02/08
Ordnance Detonation
A-19

-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.9 E-03
101-55-3
4-Bromophenylphenylether
ND
ND
1.7 E-02
106-99-0
1,3-Butadiene8
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
3.1 E-03
85-68-7
Butylbenzylphthalatef
ND
ND
1.7 E-02
123-72-8
Butyraldehyde
ND
ND
7.5 E-03
7440-43-9
Cadmium
ND
ND
2.1 E-03
75-15-0
Carbon disulfide
ND
ND
3.2 E-03
56-23-5
Carbon tetrachloride
ND
ND
6.4 E-03
106-47-8
4-Chloroaniline
ND
ND
1.7 E-02
108-90-7
Chlorobenzene
ND
ND
4.7 E-03
75-45-6
Chlorodifluoromethane
ND
ND
3.6 E-03
75-00-3
Chloroethane
ND
ND
2.7 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.7 E-02
67-66-3
Chloroform
ND
ND
5.0 E-03
74-87-3
Chloromethane
ND
ND
2.1 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.7 E-02
95-57-8
2-Chlorophenol
ND
ND
1.7 E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.7 E-02
7440-47-3
Chromium
2.4 E-07
8.6 E-05
--
18540-29-9
Hexavalent chromium1
2.2 E-05
8.2 E-03
--
218-01-9
Chrysene
ND
ND
1.7 E-05
7440-48-4
Cobalt8
1.8 E-08
6.8 E-06
--
7440-50-8
Copper8
2.3 E-07
8.5 E-05
--
106-44-5
p-Cresol
ND
ND
1.7 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.5 E-03
98-82-8
Cumene8
ND
ND
5.0 E-03
57-12-5
Particulate cyanide
ND
ND
1.2 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.7 E-05
132-64-9
Dibenzofuran
ND
ND
1.7 E-02
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-03
84-74-2
Dibutyl phthalate8
ND
ND
1.7 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-03
A-20
Ordnance Detonation
02/08

-------
TABLE A3 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-03
75-27-4
Dichlorobromomethane
ND
ND
6.8 E-03
75-71-8
Dichlorodifluoromethane8
ND
ND
5.0 E-03
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-03
75-43-4
Dichlorofluoromethane
ND
ND
4.3 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.7E-02
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-03
10061-02-6
trans-1,3 -Dichloropropene
ND
ND
4.6 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-03
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.7 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.7 E-04
606-20-2
2,6-Dinitrotoluene8
ND
ND
6.7 E-04
123-91-1
1,4-Dioxane
ND
ND
3.7 E-03
--
Total dioxin/furan compounds
3.5 E-13
1.3 E-10
--
140-88-5
Ethyl acrylate
ND
ND
4.2 E-03
100-41-4
Ethylbenzene8
ND
ND
4.4 E-03
74-85-1
Ethylene
1.0 E-05
3.8 E-03
--
206-44-0
Fluoranthene8
4.4 E-09
1.6 E-06
--
86-73-7
Fluorene
ND
ND
1.7 E-05
50-00-0
Formaldehyde
5.3 E-07
1.9 E-04
--
76-13-1
Freon 113
ND
ND
7.8 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
8.6 E-15
3.1 E-12
--
67562-39-4
1,2,3,4,6,7,8-
HeptachlorodibenzofuranJ
1.0 E-13
3.8 E-ll
--
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
2.1 E-09
118-74-1
Hexachlorobenzene
ND
ND
1.7 E-02
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
02/08
Ordnance Detonation
A-21

-------
TABLE A3 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
9.3 E-10
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
9.4 E-10
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxinJ
5.6 E-14
2.1 E-ll
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
2.0 E-14
7.5 E-12
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
9.9 E-10
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
1.1 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
9.9 E-10
67-72-1
Hexachloroethane
ND
ND
9.8 E-03
110-54-3
Hexane
ND
ND
7.2 E-02
74-90-8
Hydrogen cyanide8
6.9 E-06
2.5 E-03
~
7664-39-3
Hydrogen fluoride
ND
ND
1.0 E-01
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
ND
1.7 E-02
78-59-1
Isophorone
ND
ND
1.7 E-02
7439-96-5
Manganese8
3.2 E-07
1.2 E-04
~
96-33-3
Methyl acrylate
ND
ND
3.6 E-03
74-95-3
Methylene bromide
ND
ND
7.2 E-03
75-09-2
Methylene chloride
5.2 E-07
1.9 E-04
--
74-88-4
Methyl iodide
ND
ND
5.9 E-03
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-03
80-62-6
Methyl methacrylate
ND
ND
4.2 E-03
91-57-6
2-Methylnaphthalene
ND
ND
1.7 E-02
95-48-7
2-Methylphenol
ND
ND
1.7 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-03
91-20-3
Naphthalene8
7.5 E-08
2.7 E-05
--
7440-02-0
Nickel8
6.9 E-08
2.5 E-05
--
7697-37-2
Nitric acidf
1.8 E-06
6.4 E-04
--
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
ND
ND
6.7 E-04
55-63-0
Nitroglycerin
ND
ND
6.7 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7 E-02
A-22
Ordnance Detonation
02/08

-------
TABLE A3 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7 E-02
3268-87-9
1,2,3,4,6,7,8,9-Octachlorodibenzo-
p-dioxin
1.3 E-13
4.7 E-ll
--
39001-02-0
1,2,3,4,6,7,8,9-
Octachlorodibenzofuran
1.8E-14
6.7 E-12
--
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
2.0 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
ND
ND
2.3 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
2.0 E-09
87-86-5
Pentachlorophenol
ND
ND
1.7 E-02
85-01-8
Phenanthrene8
4.1 E-09
1.5 E-06
--
108-95-2
Phenol
ND
ND
1.7 E-02
123-38-6
Propionaldehyde
ND
ND
7.5 E-03
115-07-1
Propylene8
2.0 E-06
7.5 E-04
~
129-00-0
Pyrenef
6.3 E-09
2.3 E-06
~
7782-49-2
Selenium
ND
ND
2.1 E-03
7440-22-4
Silver
1.4E-08
5.1 E-06
~
100-42-5
Styrene8
5.8 E-08
2.1 E-05
~
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
1.2 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
1.7 E-14
6.3 E-12
--
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
7.0 E-03
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-03
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-03
7440-28-0
Thallium
ND
ND
2.1 E-03
108-88-3
Toluene8
2.4 E-07
8.8 E-05
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-03
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-03
75-69-4
Trichlorofluoromethane
ND
ND
5.7 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-03
95-63-6
1,2,4-Trimethylbenzene8
ND
ND
5.0 E-03
540-84-1
2,2,4-Trimethylpentane8
ND
ND
4.8 E-03
7440-62-2
Vanadium
2.2E-10
7.9 E-08
--
108-05-4
Vinyl acetate
ND
ND
3.6 E-03
02/08
Ordnance Detonation
A-23

-------
TABLE A3 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
75-01-4
Vinyl chloride
ND
ND
2.6 E-03
75-35-4
Vinylidene chloride
ND
ND
4.0 E-03
106-42-3,
108-38-3
m-Xylene, p-Xylene8
ND
ND
4.4 E-03
95-47-6
o-Xylene8
ND
ND
4.4 E-03
7440-66-6
Zinc
3.4 E-07
1.2 E-04
--
Other Po
lutants
67-64-1
Acetone
ND
ND
7.2 E-02
74-86-2
Acetylene8
4.2 E-06
1.5 E-03
--
35572-78-2
2-Amino-4,6-dinitrotoluene8
ND
ND
6.7 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.7 E-04
100-52-7
Benzaldehyde
ND
ND
7.5 E-03
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
6.5 E-03
460-12-8
1,3-Butadiynek
3.7 E-08
1.4 E-05
--
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butenef
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
689-97-4
l-Buten-3-ynek
2.2 E-07
8.2 E-05
--
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calciumf
1.9 E-06
6.9 E-04
--
7440-44-0
Elemental carbonf
9.2 E-06
3.4 E-03
--
7440-44-0
Organic carbon8
1.0 E-05
3.7 E-03
--
7440-44-0
Total carbon8
1.9 E-05
7.1 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3-methylphenol
ND
ND
1.7 E-02
1191-96-4
Cyclopropane, ethyl-8
1.7 E-07
6.2 E-05
--
124-48-1
Dibromochloromethane
ND
ND
8.7 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.0 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.0 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
4.6 E-03
84-66-2
Diethylphthalate
ND
ND
1.7 E-02
5779-94-2
2,5 -Dimethylbenzaldehyde
ND
ND
7.5 E-03
A-24
Ordnance Detonation
02/08

-------
TABLE A3 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
117-84-0
Di-n-octylphthalate8
ND
ND
1.7 E-02
74-84-0
Ethane8
2.9 E-06
1.1 E-03
--
141-78-6
Ethyl acetate
ND
ND
3.7 E-03
97-63-2
Ethyl methacrylate
ND
ND
4.7 E-03
622-96-8
4-Ethyltoluene8
ND
ND
5.0 E-03
142-82-5
n-Heptane8
ND
ND
4.2 E-03
592-76-7
1-Heptenek
7.3 E-08
2.7 E-05
--
66-25-1
Hexaldehyde
ND
ND
7.5 E-03
591-78-6
2-Hexanone
ND
ND
4.2 E-03
592-41-6
1-Hexenek
5.8 E-07
2.1 E-04
--
2691-41-0
HMX
ND
ND
1.6 E-03
10035-10-6
Hydrogen bromide
ND
ND
1.0 E-01
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.5 E-03
7439-95-4
Magnesium8
2.1 E-06
7.7 E-04
--
75-52-5
Methane, nitro-h
4.6 E-08
1.7 E-05
--
78-93-3
Methyl ethyl ketone
ND
ND
3.0 E-03
98-83-9
alpha-Methylstyrene
ND
ND
4.9 E-03
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.7 E-04
88-74-7
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.7 E-04
99-08-1
3-Nitrotoluene
ND
ND
3.3 E-03
99-99-0
4-Nitrotoluene
ND
ND
6.7 E-04
111-65-9
Octane8
ND
ND
4.8 E-03
930-22-3
Oxirane, ethenyl-k
2.6 E-08
9.6 E-06
--
1574-41-0
1,3-Pentadiene, (Z)-k
5.1 E-08
1.8 E-05
--
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.4 E-01
7664-38-2
Phosphoric acid
ND
ND
1.0 E-01
74-98-6
Propane8
3.5 E-07
1.3 E-04
--
115-11-7
1-Propene, 2-methyl8
3.2 E-08
1.2 E-05
--
74-99-7
Propyne8
4.4 E-07
1.6 E-04
--
121-82-4
RDX
5.2 E-08
1.9 E-05
--
02/08
Ordnance Detonation
A-25

-------
TABLE A3 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.3 E-02
25323-89-1
Trichloroethene
ND
ND
5.0 E-03
108-67-8
1,3,5 -T rimethy lbenzene8
ND
ND
5.0 E-03
99-35-4
1,3,5 -T rinitrobenzene8
ND
ND
6.7 E-04
118-96-7
2,4,6-Trinitrotoluene8
1.8 E-08
6.4 E-06
--
110-62-3
Valeraldehyde
ND
ND
7.5 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 2.73 E-03 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor was originally rated D because the factor is for a tentatively identified compound, but
because of correlation with emission factors for similar ordnance and number of data points the factor
was upgraded from a D rating to a B rating.
1 Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
J Emission factor rated D because the factor is based upon C-rated test data.
k Emission factor rated D because the factor is for a tentatively identified compound.
A-26
Ordnance Detonation
02/08

-------
TABLE A4 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC MN02, M12 NON-ELECTRIC BLASTING CAP WITH 500-FOOT SHOCK TUBE


Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
1.1 E-03
1.7E-01
--
630-08-0
Carbon monoxide8
2.9 E-03
4.8E-01
--
7439-92-1
Lead
5.3 E-05
8.6 E-03
--
74-82-8
Methane
4.1 E-04
6.6 E-02
--
--
Oxides of nitrogenf
1.2E-04
1.9E-02
--
--
PM-2.58
1.2 E-04
2.0 E-02
--
--
PM-10
2.2 E-04
3.5 E-02
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
2.5 E-04
4.1 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
2.5 E-09
4.1 E-07
--
208-96-8
Acenaphthylene8
2.8 E-08
4.4 E-06
--
75-07-0
Acetaldehyde
0
0
--
75-05-8
Acetonitrile8
6.2 E-06
1.0 E-03
--
107-02-8
Acrolein
7.6 E-08
1.2 E-05
~
107-13-1
Acrylonitrile8
1.2 E-06
2.0 E-04
~
107-05-1
Allyl chloride
ND
ND
3.2 E-03
7429-90-5
Aluminum8
3.7 E-05
5.9 E-03
--
7664-41-7
Ammonia8
4.7 E-06
7.5 E-04
~
120-12-7
Anthracene8
ND
ND
8.4 E-05
7440-36-0
Antimony
3.7 E-08
5.9 E-06
~
7440-38-2
Arsenic
ND
ND
2.0 E-03
7440-39-3
Barium
2.2 E-09
3.6 E-07
--
71-43-2
Benzene8
1.1 E-05
1.8 E-03
~
56-55-3
Benzo [a] anthracene8
4.9 E-09
7.9 E-07
~
205-99-2
Benzo [b] fluoranthene8
4.8 E-09
7.7 E-07
--
207-08-9
Benzo [k] fluoranthene8
3.4 E-09
5.6 E-07
~
191-24-2
Benzo [g,h,i]perylene
1.4 E-08
2.2 E-06
~
50-32-8
Benzo [a]pyrene8
9.4 E-09
1.5 E-06
~
192-97-2
Benzo [e]pyrene
6.5 E-09
1.0 E-06
~
100-44-7
Benzyl chloride
ND
ND
5.3 E-03
7440-41-7
Beryllium
ND
ND
2.0 E-03
75-25-2
Bromoform
ND
ND
1.1 E-02
02/08
Ordnance Detonation
A-27

-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.9 E-03
101-55-3
4-Bromophenylphenylether
ND
ND
1.7E-02
106-99-0
1,3-Butadiene8
1.8E-06
2.9 E-04
--
75-65-0
t-Butyl alcohol
ND
ND
3.1 E-03
85-68-7
Butylbenzylphthalatef
ND
ND
1.7E-02
123-72-8
Butyraldehyde
ND
ND
7.5 E-03
7440-43-9
Cadmium
ND
ND
2.0 E-03
75-15-0
Carbon disulfide
ND
ND
3.2 E-03
56-23-5
Carbon tetrachloride
ND
ND
6.4 E-03
106-47-8
4-Chloroaniline
ND
ND
1.7E-02
108-90-7
Chlorobenzene
ND
ND
4.7 E-03
75-45-6
Chlorodifluoromethane
ND
ND
3.6 E-03
75-00-3
Chloroethane
ND
ND
2.7 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7E-02
111-44-4
Bis(2-chloroethyl)ether
ND
ND
1.7E-02
67-66-3
Chloroform
ND
ND
5.0 E-03
74-87-3
Chloromethane
ND
ND
2.1 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.7E-02
95-57-8
2-Chlorophenol
ND
ND
1.7E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.7E-02
7440-47-3
Chromium
1.3 E-07
2.1 E-05
--
18540-29-9
Hexavalent chromium1
1.6E-05
2.5 E-03
--
218-01-9
Chrysene
4.6 E-09
7.4 E-07
--
7440-48-4
Cobalt8
ND
ND
2.0 E-03
7440-50-8
Copper8
2.8 E-07
4.4 E-05
--
106-44-5
p-Cresol
ND
ND
1.7E-02
4170-30-3
Crotonaldehyde
ND
ND
7.5 E-03
98-82-8
Cumene8
ND
ND
5.0 E-03
57-12-5
Particulate cyanide
ND
ND
1.2E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.7 E-05
132-64-9
Dibenzofuran
ND
ND
1.7E-02
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-03
84-74-2
Dibutyl phthalate8
ND
ND
1.7E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-03
A-28
Ordnance Detonation
02/08

-------
TABLE A4 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-03
75-27-4
Dichlorobromomethane
ND
ND
6.8 E-03
75-71-8
Dichlorodifluoromethane8
ND
ND
5.0 E-03
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-03
75-43-4
Dichlorofluoromethane
ND
ND
4.3 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.7 E-02
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-03
10061-02-6
trans-1,3-Dichloropropene
ND
ND
4.6 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-03
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.7 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
6.7 E-04
606-20-2
2,6-Dinitrotoluene8
ND
ND
6.7 E-04
123-91-1
1,4-Dioxane
ND
ND
3.7 E-03
--
Total dioxin/furan compounds
7.0 E-14
1.1 E-ll
--
140-88-5
Ethyl acrylate
ND
ND
4.2 E-03
100-41-4
Ethylbenzene8
1.1 E-07
1.7 E-05
--
74-85-1
Ethylene
7.4 E-05
1.2E-02
--
206-44-0
Fluoranthene8
5.0 E-09
8.0 E-07
--
86-73-7
Fluorene
4.5 E-09
7.3 E-07
--
50-00-0
Formaldehyde
7.6 E-07
1.2 E-04
--
76-13-1
Freon 113
ND
ND
7.8 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
8.7E-16
1.4E-13
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuran
ND
ND
1.8 E-09
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
2.1 E-09
118-74-1
Hexachlorobenzene
ND
ND
1.7 E-02
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
02/08
Ordnance Detonation
A-29

-------
TABLE A4 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
9.6E-10
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
1.0 E-09
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
ND
ND
9.6E-10
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
ND
ND
7.6E-10
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
ND
ND
8.4E-10
72918-21-9
1,2,3,7,8, 9-Hexachlorodibenzofuran
ND
ND
8.7E-10
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
ND
ND
8.3 E-10
67-72-1
Hexachloroethane
ND
ND
9.8 E-03
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
0
0
--
74-90-8
Hydrogen cyanide8
7.2 E-05
1.2E-02
--
7664-39-3
Hydrogen fluoride
ND
ND
1.0E-01
193-39-5
Indeno[ 1,2,3 -cd]pyrene
6.2 E-09
1.0 E-06
~
78-59-1
Isophorone
ND
ND
1.7 E-02
7439-96-5
Manganese8
1.2E-07
2.0 E-05
--
96-33-3
Methyl acrylate
ND
ND
3.6 E-03
74-95-3
Methylene bromide
ND
ND
7.2 E-03
75-09-2
Methylene chloride
1.9 E-06
3.2 E-04
--
74-88-4
Methyl iodide
ND
ND
5.9 E-03
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-03
80-62-6
Methyl methacrylate
ND
ND
4.2 E-03
91-57-6
2-Methylnaphthalene
ND
ND
1.7 E-02
95-48-7
2-Methylphenol
ND
ND
1.7 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-03
91-20-3
Naphthalene8
2.8 E-07
4.5 E-05
--
7440-02-0
Nickel8
1.8E-08
3.0 E-06
--
7697-37-2
Nitric acidf
ND
ND
1.0E-01
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
ND
ND
6.7 E-04
55-63-0
Nitroglycerin
ND
ND
6.7 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7 E-02
A-30
Ordnance Detonation
02/08

-------
TABLE A4 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7E-02
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
1.3 E-09
57117-41-6
1,2,3,7,8-Pentachlorodibenzofuran
ND
ND
1.9 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
1.9 E-09
87-86-5
Pentachlorophenol
ND
ND
1.7E-02
85-01-8
Phenanthrene8
5.5 E-09
8.8 E-07
--
108-95-2
Phenol
ND
ND
1.7E-02
123-38-6
Propionaldehyde
ND
ND
7.5 E-03
115-07-1
Propylene8
7.2 E-06
1.2E-03
--
129-00-0
Pyrenef
1.1 E-08
1.8 E-06
--
7782-49-2
Selenium
ND
ND
2.0 E-03
7440-22-4
Silver
ND
ND
2.0 E-03
100-42-5
Styrene8
5.7 E-07
9.2 E-05
--
7664-93-9
Sulfuric acid
ND
ND
1.0E-01
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
1.4 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
ND
ND
1.1 E-09
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
7.0 E-03
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-03
127-18-4
T etrachloroethylene
ND
ND
6.9 E-03
7440-28-0
Thallium
ND
ND
2.0 E-03
108-88-3
Toluene8
1.0 E-06
1.7E-04
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-03
71-55-6
1,1,1 -Trichloroethane
ND
ND
5.5 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-03
75-69-4
Trichlorofluoromethane
ND
ND
5.7 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-03
95-63-6
1,2,4-Trimethylbenzene8
5.9 E-08
9.6 E-06
--
540-84-1
2,2,4-Trimethylpentane8
ND
ND
4.8 E-03
7440-62-2
Vanadium
ND
ND
2.0 E-03
108-05-4
Vinyl acetate
ND
ND
3.6 E-03
75-01-4
Vinyl chloride
ND
ND
2.6 E-03
02/08
Ordnance Detonation
A-31

-------
TABLE A4 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
75-35-4
Vinylidene chloride
ND
ND
4.0 E-03
106-42-3,
108-38-3
m-Xylene, p-Xylene8
1.1 E-07
1.7 E-05
--
95-47-6
o-Xylene8
ND
ND
4.4 E-03
7440-66-6
Zinc
1.1 E-06
1.8E-04
—
Other Po
lutants
67-64-1
Acetone
ND
ND
7.3 E-02
74-86-2
Acetylene8
1.6E-05
2.6 E-03
--
35572-78-2
2-Amino-4,6-dinitrotoluene8
ND
ND
6.7 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.7 E-04
100-52-7
Benzaldehyde
ND
ND
7.5 E-03
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
6.5 E-03
590-19-2
1,2-Butadiene1
1.2 E-07
2.0 E-05
--
460-12-8
1,3-Butadiyne1
1.2 E-07
2.0 E-05
--
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Buteneh
6.2 E-07
1.0E-04
--
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
689-97-4
l-Buten-3-yne1
8.2 E-07
1.3 E-04
--
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
5.6 E-07
9.1 E-05
--
7440-70-2
Calciumf
1.9 E-06
3.1 E-04
--
7440-44-0
Elemental carbonf
1.6E-05
2.6 E-03
--
7440-44-0
Organic carbon8
1.2E-05
2.0 E-03
--
7440-44-0
Total carbon8
2.8 E-05
4.6 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.7 E-02
542-92-7
1,3 -CyclopentadieneJ
1.3 E-07
2.1 E-05
--
930-18-7
Cyclopropane, 1,2-dimethyl-, cis-J
1.1 E-07
1.7 E-05
--
1191-96-4
Cyclopropane, ethyl-J
8.7 E-07
1.4 E-04
--
872-05-9
l-DeceneJ
6.9 E-07
1.1 E-04
--
19150-21-1
trans-S-Decene"
5.6 E-07
9.1 E-05
~
124-48-1
Dibromochloromethane
ND
ND
8.7 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.0 E-03
A-32
Ordnance Detonation
02/08

-------
TABLE A4 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.0 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
4.6 E-03
84-66-2
Diethylphthalate
ND
ND
1.7E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.5 E-03
117-84-0
Di-n-octylphthalate8
ND
ND
1.7E-02
112-41-4
1-Dodecene1
7.9 E-07
1.3 E-04
--
74-84-0
Ethane8
2.0 E-05
3.3 E-03
--
3637-01-2
Ethanone, 1 -(3,4-dimethylphenyl)-J
5.3 E-07
8.6 E-05
--
937-30-4
Ethanone, l-(4-ethylphenyl)-J
3.3 E-07
5.3 E-05
--
141-78-6
Ethyl acetate
ND
ND
3.7 E-03
97-63-2
Ethyl methacrylate
ND
ND
4.7 E-03
622-96-8
4-Ethyltoluene8
ND
ND
5.0 E-03
142-82-5
n-Heptane8
ND
ND
4.2 E-03
592-42-7
l,5-HexadieneJ
1.6 E-07
2.6 E-05
--
66-25-1
Hexaldehyde
ND
ND
7.5 E-03
591-78-6
2-Hexanone
ND
ND
4.2 E-03
2691-41-0
HMX
ND
ND
1.6 E-03
10035-10-6
Hydrogen bromide
ND
ND
1.0E-01
95-13-6
Indene1
1.7 E-07
2.8 E-05
--
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.5 E-03
7439-95-4
Magnesium8
1.0E-06
1.6 E-04
~
78-93-3
Methyl ethyl ketone
5.4 E-08
8.7 E-06
~
98-83-9
alpha-Methylstyrene
ND
ND
4.9 E-03
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.7 E-04
88-74-7
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.7 E-04
99-08-1
3-Nitrotoluene
ND
ND
3.3 E-03
99-99-0
4-Nitrotoluene
ND
ND
6.7 E-04
111-65-9
Octane8
ND
ND
4.8 E-03
1574-41-0
1,3-Pentadiene, (Z)-J
2.9 E-07
4.6 E-05
--
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.4E-01
02/08
Ordnance Detonation
A-33

-------
TABLE A4 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
7664-38-2
Phosphoric acid
ND
ND
1.0E-01
74-98-6
Propane8
1.0E-06
1.6E-04
--
115-11-7
1-Propene, 2-methyl8
1.2E-07
1.9E-05
--
74-99-7
Propyne8
1.0E-06
1.7E-04
--
121-82-4
RDX
0
0
--
1120-36-1
1-Tetradecene1
1.7E-07
2.7 E-05
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.3 E-02
25323-89-1
Trichloroethene
ND
ND
5.0 E-03
108-67-8
1,3,5 -T rimethy lbenzene8
ND
ND
5.0 E-03
99-35-4
1,3,5 -T rinitrobenzene8
ND
ND
6.7 E-04
118-96-7
2,4,6-Trinitrotoluene8
ND
ND
6.7 E-04
112-42-5
l-UndecanolJ
2.5 E-07
4.1 E-05
--
110-62-3
Valeraldehyde
ND
ND
7.5 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 6.18 E-03 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a B rating.
1 Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
J Emission factor rated D because the factor is for a tentatively identified compound.
A-34
Ordnance Detonation
02/08

-------
TABLE A5 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC MN03, M13 NON-ELECTRIC BLASTING CAP WITH 1,000-FOOT SHOCK TUBE


Emission Factorb,c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
1.3 E-03
1.2 E-01
--
630-08-0
Carbon monoxide8
6.5 E-03
5.9 E-01
--
7439-92-1
Lead
5.5 E-05
5.0 E-03
--
74-82-8
Methane
9.1 E-04
8.2 E-02
--
--
Oxides of nitrogenf
2.7 E-04
2.5 E-02
--
--
PM-2.58
1.6 E-04
1.4 E-02
--
--
PM-10
2.5 E-04
2.2 E-02
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
2.7 E-04
2.4 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
2.7 E-09
2.5 E-07
--
208-96-8
Acenaphthylene8
3.3 E-08
3.0 E-06
--
75-07-0
Acetaldehyde
0
0
--
75-05-8
Acetonitrileh
1.3 E-05
1.2 E-03
--
107-02-8
Acrolein
ND
ND
7.6 E-03
107-13-1
Acrylonitrile8
2.5 E-06
2.2 E-04
--
107-05-1
Allyl chloride
ND
ND
3.2 E-03
7429-90-5
Aluminum8
3.7 E-05
3.3 E-03
--
7664-41-7
Ammonia8
3.2 E-06
2.9 E-04
~
120-12-7
Anthracene8
ND
ND
8.4 E-05
7440-36-0
Antimony1
2.1 E-07
1.9 E-05
~
7440-38-2
Arsenic
ND
ND
2.0 E-03
7440-39-3
Barium
8.2 E-09
7.3 E-07
--
71-43-2
Benzene8
2.5 E-05
2.2 E-03
~
56-55-3
Benzo [a] anthracene8
4.7 E-09
4.2 E-07
~
205-99-2
Benzo [b] fluoranthene8
4.7 E-09
4.2 E-07
--
207-08-9
Benzo [k] fluoranthene8
3.3 E-09
3.0 E-07
~
191-24-2
Benzo [g,h,i]perylene
1.9 E-08
1.7 E-06
~
50-32-8
Benzo [a]pyrene8
1.0 E-08
9.1 E-07
~
192-97-2
Benzo [e]pyrene
7.2 E-09
6.5 E-07
~
100-44-7
Benzyl chloride
ND
ND
5.3 E-03
7440-41-7
Beryllium
ND
ND
2.0 E-03
75-25-2
Bromoform
ND
ND
1.1 E-02
02/08
Ordnance Detonation
A-35

-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.9E-03
101-55-3
4-Bromophenylphenylether
ND
ND
1.7E-02
106-99-0
1,3-Butadiene8
2.0 E-06
1.8E-04
--
75-65-0
t-Butyl alcohol
ND
ND
3.1 E-03
85-68-7
Butylbenzylphthalatef
ND
ND
1.7E-02
123-72-8
Butyraldehyde
ND
ND
7.6 E-03
7440-43-9
Cadmium
ND
ND
2.0 E-03
75-15-0
Carbon disulfide
ND
ND
3.2 E-03
56-23-5
Carbon tetrachloride
ND
ND
6.4 E-03
106-47-8
4-Chloroaniline
ND
ND
1.7E-02
108-90-7
Chlorobenzene
ND
ND
4.7 E-03
75-45-6
Chlorodifluoromethane
ND
ND
3.6 E-03
75-00-3
Chloroethane
ND
ND
2.7 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7E-02
111-44-4
Bis(2-chloroethyl)ether
ND
ND
1.7E-02
67-66-3
Chloroform
ND
ND
5.0 E-03
74-87-3
Chloromethane
ND
ND
2.1 E-03
91-58-7
2-Chloronaphthalene
ND
ND
1.7E-02
95-57-8
2-Chlorophenol
ND
ND
1.7E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.7E-02
7440-47-3
Chromium
1.1 E-07
9.7 E-06
--
18540-29-9
Hexavalent chromium11
3.8E-05
3.4E-03
--
218-01-9
Chrysene
4.4 E-09
3.9 E-07
--
7440-48-4
Cobalt8
ND
ND
2.0 E-03
7440-50-8
Copper11
1.0 E-06
9.0 E-05
--
106-44-5
p-Cresol
ND
ND
1.7E-02
4170-30-3
Crotonaldehyde
ND
ND
7.6 E-03
98-82-8
Cumene8
ND
ND
5.0 E-03
57-12-5
Particulate cyanide
ND
ND
1.3 E-02
53-70-3
Dibenz [a,h] anthracene
3.6E-10
3.2E-08
--
132-64-9
Dibenzofuran
ND
ND
1.7 E-02
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-03
84-74-2
Dibutyl phthalate8
ND
ND
1.7 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-03
A-36
Ordnance Detonation
02/08

-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-03
75-27-4
Dichlorobromomethane
ND
ND
6.8 E-03
75-71-8
Dichlorodifluoromethane8
ND
ND
5.0 E-03
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-03
75-43-4
Dichlorofluoromethane
ND
ND
4.3 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.7 E-02
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-03
10061-02-6
trans-1,3-Dichloropropene
ND
ND
4.6 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-03
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.5 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
1.7 E-02
606-20-2
2,6-Dinitrotoluene8
ND
ND
1.7 E-02
123-91-1
1,4-Dioxane
ND
ND
3.7 E-03
--
Total dioxin/furan compounds
ND
ND
--
140-88-5
Ethyl acrylate
ND
ND
4.2 E-03
100-41-4
Ethylbenzene8
7.9 E-08
7.1 E-06
--
74-85-1
Ethylene
1.6E-04
1.4E-02
--
206-44-0
Fluoranthene8
5.6E-09
5.0 E-07
--
86-73-7
Fluorene
5.1 E-09
4.6 E-07
--
50-00-0
Formaldehyde
8.7 E-07
7.8 E-05
--
76-13-1
Freon 113
ND
ND
7.8 E-03
87-68-3
Hexachlorobutadiene
ND
ND
1.1 E-02
87-68-3
Hexachlorobutadiene
ND
ND
1.7 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
67-72-1
Hexachloroethane
ND
ND
9.8 E-03
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
1.1 E-06
9.7 E-05
--
74-90-8
Hydrogen cyanide8
1.7E-04
1.5 E-02
--
7664-39-3
Hydrogen fluoride
ND
ND
1.0E-01
193-39-5
Indenof 1,2,3-cd]pyrene
7.1 E-09
6.3 E-07
--
02/08
Ordnance Detonation
A-37

-------
TABLE A5 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
78-59-1
Isophorone
ND
ND
1.7 E-02
7439-96-5
Manganese8
9.0 E-08
8.0 E-06
--
96-33-3
Methyl acrylate
ND
ND
3.6 E-03
74-95-3
Methylene bromide
ND
ND
7.2 E-03
75-09-2
Methylene chloride
2.5 E-06
2.3 E-04
--
74-88-4
Methyl iodide
ND
ND
5.9 E-03
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-03
80-62-6
Methyl methacrylate
ND
ND
4.2 E-03
91-57-6
2-Methylnaphthalene
ND
ND
1.7 E-02
95-48-7
2-Methylphenol
ND
ND
1.7 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-03
91-20-3
Naphthalene8
3.2 E-07
2.9 E-05
--
7440-02-0
Nickel8
ND
ND
2.0 E-03
7697-37-2
Nitric acidf
ND
ND
1.0 E-01
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
ND
ND
6.5 E-04
55-63-0
Nitroglycerin
ND
ND
6.5 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7 E-02
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
5.0 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
ND
ND
1.8 E-09
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
ND
ND
1.6 E-09
87-86-5
Pentachlorophenol
ND
ND
1.7 E-02
85-01-8
Phenanthrene8
6.0 E-09
5.4 E-07
--
108-95-2
Phenol
ND
ND
1.7 E-02
123-38-6
Propionaldehyde
ND
ND
7.6 E-03
115-07-1
Propylene8
1.3 E-05
1.2E-03
--
129-00-0
Pyrenef
1.3 E-08
1.2 E-06
--
7782-49-2
Selenium
ND
ND
2.0 E-03
7440-22-4
Silver
ND
ND
2.0 E-03
100-42-5
Styrene8
5.0 E-07
4.5 E-05
--
A-38
Ordnance Detonation
02/08

-------
TABLE A5 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
7664-93-9
Sulfuric acid
ND
ND
1.0 E-01
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
1.2 E-09
51207-31-9
2,3,7,8-Tetrachlorodibenzofuran
ND
ND
1.1 E-09
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
7.0 E-03
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-03
127-18-4
Tetrachloroethylene
ND
ND
6.9 E-03
7440-28-0
Thallium
ND
ND
2.0 E-03
108-88-3
Toluene8
1.4 E-06
1.2 E-04
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
7.5 E-03
71-55-6
1,1,1 -Trichloroethane
ND
ND
5.5 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-03
75-69-4
T richlorofluoromethane
ND
ND
5.7 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-02
96-18-4
1,2,3-Trichloropropane
ND
ND
6.1 E-03
95-63-6
1,2,4-Trimethylbenzene8
ND
ND
5.0 E-03
540-84-1
2,2,4-Trimethylpentane8
ND
ND
4.8 E-03
7440-62-2
Vanadium
ND
ND
2.0 E-03
108-05-4
Vinyl acetate
ND
ND
3.6 E-03
75-01-4
Vinyl chloride
ND
ND
2.6 E-03
75-35-4
Vinylidene chloride
ND
ND
4.0 E-03
106-42-3,
108-38-3
m-Xylene, p-Xylene8
7.9 E-08
7.1 E-06
--
95-47-6
o-Xylene8
ND
ND
4.4 E-03
7440-66-6
Zinc
1.1 E-06
9.7 E-05
--
Other Po
lutants
67-64-1
Acetone
ND
ND
7.4 E-02
74-86-2
Acetylene8
2.6 E-05
2.3 E-03
--
35572-78-2
2-Amino-4,6-dinitrotoluene8
ND
ND
6.5 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.5 E-04
100-52-7
Benzaldehyde
ND
ND
7.6 E-03
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
6.5 E-03
590-19-2
1.2-Butadiene1
8.0 E-08
7.2 E-06
--
106-97-8
Butane
ND
ND
5.3 E-02
02/08
Ordnance Detonation
A-39

-------
TABLE A5 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
106-98-9
1-Butenef
1.4 E-06
1.3 E-04
--
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
689-97-4
l-Buten-3-yne1
5.4 E-07
4.9 E-05
--
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calciumf
1.8 E-06
1.6 E-04
--
7440-44-0
Elemental carbonf
1.2 E-05
1.1 E-03
--
7440-44-0
Organic carbon8
1.5 E-05
1.4 E-03
--
7440-44-0
Total carbon8
2.8 E-05
2.5 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.7 E-02
293-96-9
CyclodecaneJ
7.2 E-07
6.5 E-05
--
1191-96-4
Cyclopropane, ethyl-J
4.2 E-07
3.7 E-05
--
872-05-9
l-DeceneJ
1.0 E-06
9.3 E-05
--
20063-97-2
2-Decene, (E)-J
9.3 E-07
8.4 E-05
--
20348-51-0
2-Decene, (Z)-J
2.1 E-07
1.9 E-05
--
19398-86-8
cis-3-DeceneJ
2.1 E-07
1.9 E-05
--
124-48-1
Dibromochloromethane
ND
ND
8.7 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.0 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.0 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
4.6 E-03
84-66-2
Diethylphthalate
ND
ND
1.7 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.6 E-03
117-84-0
Di-n-octylphthalate8
ND
ND
1.7 E-02
112-41-4
1-Dodecene1
1.1 E-06
1.0 E-04
--
7206-26-0
2-Dodecene, (Z)-J
1.9 E-06
1.7 E-04
--
74-84-0
Ethane8
5.6 E-05
5.0 E-03
--
3637-01-2
Ethanone, 1 -(3,4-dimethylphenyl)-J
5.7 E-07
5.1 E-05
--
937-30-4
Ethanone, l-(4-ethylphenyl)-J
3.3 E-07
3.0 E-05
--
141-78-6
Ethyl acetate
ND
ND
3.7 E-03
97-63-2
Ethyl methacrylate
ND
ND
4.7 E-03
622-96-8
4-Ethyltoluene8
ND
ND
5.0 E-03
142-82-5
n-Heptane8
ND
ND
4.2 E-03
66-25-1
Hexaldehyde
ND
ND
7.6 E-03
A-40
Ordnance Detonation
02/08

-------
TABLE A5 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
591-78-6
2-Hexanone
ND
ND
4.2 E-03
2691-41-0
HMX
ND
ND
1.6 E-03
10035-10-6
Hydrogen bromide
ND
ND
1.0 E-01
95-13-6
Indene1
1.7 E-07
1.5 E-05
--
75-28-5
Isobutane
ND
ND
4.8 E-02
115-11-7
Isobutylene
0
0
--
590-86-3
Isovaleraldehyde
ND
ND
7.6 E-03
7439-95-4
Magnesium8
1.1 E-06
9.9 E-05
--
78-93-3
Methyl ethyl ketone
8.0E-08
7.2 E-06
--
98-83-9
alpha-Methylstyrene
ND
ND
4.9 E-03
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.5 E-04
88-74-7
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.5 E-04
99-08-1
3-Nitrotoluene
ND
ND
3.3 E-03
99-99-0
4-Nitrotoluene
ND
ND
6.5 E-04
111-65-9
Octane8
ND
ND
4.8 E-03
111-66-0
1-Octene"
2.1 E-07
1.9 E-05
--
14850-23-8
4-Octene, (E)-J
1.7 E-07
1.5 E-05
--
504-60-9
l,3-PentadieneJ
1.0 E-07
9.1 E-06
--
2004-70-8
1,3-Pentadiene, (E)-J
1.0 E-07
9.1 E-06
--
109-66-0
Pentane
ND
ND
6.0 E-02
109-67-1
1-Pentene1
4.2 E-07
3.7 E-05
--
61847-80-1
1-Pentene, 3-ethyl-4-methyl-
1.7 E-07
1.5 E-05
~
14797-73-0
Perchlorate
ND
ND
1.3 E-01
7664-38-2
Phosphoric acid
ND
ND
1.0 E-01
115-11-7
1-Propene, 2-methyl8
0
0
--
74-99-7
Propyne8
1.3 E-06
1.2 E-04
~
121-82-4
RDX1
4.8 E-08
4.3 E-06
--
1120-36-1
1-Tetradecene1
3.5 E-07
3.1 E-05
~
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.3 E-02
25323-89-1
Trichloroethene
ND
ND
5.0 E-03
108-67-8
1,3,5 -T rimethy lbenzene8
ND
ND
5.0 E-03
99-35-4
1,3,5 -T rinitrobenzene8
ND
ND
6.5 E-04
02/08
Ordnance Detonation
A-41

-------
TABLE A5 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
118-96-7
2,4,6-Trinitrotoluene8
ND
ND
6.5 E-04
110-62-3
Valeraldehyde
ND
ND
7.6 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 1.11 E-02 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
1 Emission factor rated D because the factor is based upon C-rated test data.
J Emission factor rated D because the factor is for a tentatively identified compound.
A-42
Ordnance Detonation
02/08

-------
TABLE A6 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC MN06, M14 NON-ELECTRIC TIME DELAY BLASTING CAP


Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3,e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxidef
6.8 E-03
2.6E-01
--
630-08-0
Carbon monoxide8
1.8E-03
6.8 E-02
--
7439-92-1
Lead
3.8 E-05
1.5 E-03
--
74-82-8
Methane
1.7E-04
6.6 E-03
--
--
Oxides of nitrogenf
5.7 E-04
2.2 E-02
--
--
PM-2.58
2.3 E-03
8.8 E-02
--
--
PM-10
2.3 E-03
9.0 E-02
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
2.3 E-03
9.1 E-02
—
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene8
1.1 E-08
4.2 E-07
~
208-96-8
Acenaphthylene8
1.6E-07
6.1 E-06
~
75-07-0
Acetaldehyde
7.3 E-05
2.8 E-03
~
75-05-8
Acetonitrile8
8.5 E-05
3.3 E-03
~
107-02-8
Acrolein
ND
ND
8.1 E-03
107-13-1
Acrylonitrile8
1.4E-06
5.5 E-05
--
107-05-1
Allyl chloride
ND
ND
1.6 E-02
7429-90-5
Aluminum8
4.8 E-06
1.8 E-04
~
7664-41-7
Ammonia8
3.2 E-04
1.2 E-02
~
120-12-7
Anthracene8
ND
ND
1.7 E-02
7440-36-0
Antimony
0
0
--
7440-38-2
Arsenic
ND
ND
2.0 E-03
7440-39-3
Barium
0
0
~
71-43-2
Benzene8
7.9 E-05
3.0 E-03
--
56-55-3
Benzo [a] anthracene8
1.7 E-08
6.7 E-07
~
205-99-2
Benzo [b] fluoranthene8
3.2 E-08
1.3 E-06
~
207-08-9
Benzo [k] fluoranthene8
ND
ND
1.7 E-05
191-24-2
Benzo [g,h,i]perylene
7.5 E-09
2.9 E-07
~
50-32-8
Benzo [a]pyrene8
7.8 E-09
3.0 E-07
--
192-97-2
Benzo [e]pyrene
1.9 E-08
7.5 E-07
~
100-44-7
Benzyl chloride
ND
ND
2.6 E-02
7440-41-7
Beryllium
ND
ND
2.0 E-03
92-52-4
Biphenyl1
2.7 E-06
1.0 E-04
--
02/08
Ordnance Detonation
A-43

-------
TABLE A6 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
75-25-2
Bromoform
ND
ND
5.3 E-02
74-83-9
Bromomethane
ND
ND
2.0 E-02
101-55-3
4-Bromophenylphenylether
ND
ND
1.7 E-02
106-99-0
1,3-Butadiene8
ND
ND
4.5 E-02
4170-30-3
2-ButenalJ
9.6 E-07
3.7 E-05
--
75-65-0
t-Butyl alcohol
ND
ND
1.5 E-02
85-68-7
Butylbenzylphthalatef
ND
ND
1.7 E-02
123-72-8
Butyraldehyde
ND
ND
8.1 E-03
7440-43-9
Cadmium
ND
ND
2.0 E-03
75-15-0
Carbon disulfide
1.5 E-05
5.9E-04
--
56-23-5
Carbon tetrachloride
ND
ND
3.2 E-02
106-47-8
4-Chloroaniline
ND
ND
1.7 E-02
108-90-7
Chlorobenzene
ND
ND
2.4 E-02
75-45-6
Chlorodifluoromethane
ND
ND
1.8 E-02
75-00-3
Chloroethane
ND
ND
1.3 E-02
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7 E-02
111-44-4
bis(2-Chloroethyl)ether
ND
ND
1.7 E-02
67-66-3
Chloroform
ND
ND
2.5 E-02
74-87-3
Chloromethane
4.9 E-05
1.9E-03
--
91-58-7
2-Chloronaphthalene
ND
ND
1.7 E-02
95-57-8
2-Chlorophenol
ND
ND
1.7 E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.7 E-02
7440-47-3
Chromium
ND
ND
2.0 E-03
18540-29-9
Hexavalent chromium11
1.0 E-05
3.9E-04
--
218-01-9
Chrysene
1.5 E-07
5.6 E-06
--
7440-48-4
Cobalt8
ND
ND
2.0 E-03
7440-50-8
Copper8
6.4 E-08
2.5 E-06
--
106-44-5
p-Cresol
2.4 E-06
9.2 E-05
--
4170-30-3
Crotonaldehyde
ND
ND
8.1 E-03
98-82-8
Cumene8
ND
ND
2.5 E-02
57-12-5
Particulate cyanide
ND
ND
1.2 E-02
53-70-3
Dibenz [a,h] anthracene
4.7 E-09
1.8 E-07
--
132-64-9
Dibenzofuran
ND
ND
1.7 E-02
106-93-4
1,2-Dibromoethane
ND
ND
3.9 E-02
84-74-2
Dibutyl phthalate8
ND
ND
1.7 E-02
A-44
Ordnance Detonation
02/08

-------
TABLE A6 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
95-50-1
1,2-Dichlorobenzene
ND
ND
3.1 E-02
541-73-1
1,3 -Dichlorobenzene
ND
ND
3.1 E-02
106-46-7
1,4-Dichlorobenzene
ND
ND
3.1 E-02
75-27-4
Dichlorobromomethane
ND
ND
3.4 E-02
75-71-8
Dichlorodifluoromethane8
ND
ND
2.5 E-02
75-34-3
1,1 -Dichloroethane
ND
ND
2.1 E-02
107-06-2
1,2-Dichloroethane
ND
ND
2.1 E-02
75-43-4
Dichlorofluoromethane
ND
ND
2.1 E-02
120-83-2
2,4-Dichlorophenol
ND
ND
1.7 E-02
78-87-5
1,2-Dichloropropane
ND
ND
2.4 E-02
10061-02-6
trans-1,3-Dichloropropene
ND
ND
2.3 E-02
76-14-2
Dichlorotetrafluoroethane
ND
ND
3.6 E-02
105-67-9
2,4-Dimethylphenol
1.5 E-06
5.8 E-05
--
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
8.3 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
51-28-5
2,4-Dinitrophenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
8.3 E-04
606-20-2
2,6-Dinitrotoluene8
ND
ND
8.3 E-04
123-91-1
1,4-Dioxane
ND
ND
1.8 E-02
140-88-5
Ethyl acrylate
ND
ND
2.1 E-02
100-41-4
Ethylbenzene8
8.8 E-07
3.4 E-05
--
74-85-1
Ethylene
6.6 E-05
2.6 E-03
--
117-81-7
bis(2-Ethylhexyl)phthalatef
0
0
--
206-44-0
Fluoranthene8
5.4E-08
2.1 E-06
--
86-73-7
Fluorene
1.6 E-07
6.1 E-06
--
50-00-0
Formaldehyde
1.1 E-05
4.4 E-04
--
76-13-1
Freon 113
ND
ND
3.9 E-02
118-74-1
Hexachlorobenzene
ND
ND
1.7 E-02
87-68-3
Hexachlorobutadiene
ND
ND
5.4 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
67-72-1
Hexachloroethane
ND
ND
4.9 E-02
110-54-3
Hexane
1.0 E-06
3.9 E-05
--
74-90-8
Hydrogen cyanide8
9.9 E-06
3.8 E-04
--
7664-39-3
Hydrogen fluoride
3.5 E-06
1.4 E-04
--
02/08
Ordnance Detonation
A-45

-------
TABLE A6 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
193-39-5
Indeno [ 1,2,3 -cd]pyrene
5.0E-09
1.9 E-07
--
78-59-1
Isophorone
ND
ND
1.7E-02
7439-96-5
Manganese8
1.5 E-07
6.0 E-06
--
96-33-3
Methyl acrylate1
4.1 E-07
1.6 E-05
--
74-95-3
Methylene bromide
ND
ND
3.6E-02
75-09-2
Methylene chloride
3.1 E-06
1.2E-04
--
74-88-4
Methyl iodide
ND
ND
3.0E-02
108-10-1
Methyl isobutyl ketone
ND
ND
2.1 E-02
80-62-6
Methyl methacrylate
ND
ND
2.1 E-02
91-57-6
2-Methylnaphthalene
3.0 E-07
1.2 E-05
--
95-48-7
2-Methylphenol
2.0 E-06
7.6 E-05
--
1634-04-4
Methyl tert-butyl ether
ND
ND
1.8 E-02
91-20-3
Naphthalene8
1.2 E-06
4.8 E-05
--
7440-02-0
Nickel8
ND
ND
2.0 E-03
7697-37-2
Nitric acidf
2.3 E-06
8.9 E-05
--
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
ND
ND
6.6 E-03
55-63-0
Nitroglycerin
ND
ND
8.3 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7 E-02
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7 E-02
87-86-5
Pentachlorophenol
ND
ND
1.7 E-02
85-01-8
Phenanthrene8
2.1 E-07
8.0 E-06
--
108-95-2
Phenol
3.0 E-06
1.2E-04
--
123-38-6
Propionaldehyde
1.4E-05
5.3 E-04
--
115-07-1
Propylene8
5.0E-05
2.0 E-03
~
129-00-0
Pyrenef
4.0 E-08
1.5 E-06
--
7782-49-2
Selenium
ND
ND
2.0 E-03
7440-22-4
Silver
ND
ND
2.0 E-03
100-42-5
Styrene8
4.3 E-07
1.7 E-05
--
7664-93-9
Sulfuric acid
2.7 E-05
1.1 E-03
~
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
3.5 E-02
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
3.5 E-02
A-46
Ordnance Detonation
02/08

-------
TABLE A6 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
127-18-4
T etrachloroethy lene
ND
ND
3.4E-02
7440-28-0
Thallium
ND
ND
2.0 E-03
108-88-3
Toluene8
1.0E-05
4.0 E-04
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
3.8E-02
71-55-6
1,1,1 -T richloroethane
ND
ND
2.8 E-02
79-00-5
1,1,2-Trichloroethane
ND
ND
2.8 E-02
75-69-4
Trichlorofluoromethane
ND
ND
2.9 E-02
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
3.1 E-02
95-63-6
1,2,4-Trimethylbenzene8
4.3 E-07
1.7 E-05
--
540-84-1
2,2,4-Trimethylpentane8
4.1 E-07
1.6 E-05
--
7440-62-2
Vanadium
ND
ND
2.0 E-03
108-05-4
Vinyl acetate
ND
ND
1.8 E-02
75-01-4
Vinyl chloride
ND
ND
1.3 E-02
75-35-4
Vinylidene chloride
ND
ND
2.0 E-02
106-42-3,
108-38-3
m-Xylene, p-Xylene8
2.2 E-06
8.6 E-05
--
95-47-6
o-Xylene8
8.8 E-07
3.4 E-05
--
7440-66-6
Zinc
2.8 E-07
1.1 E-05
—
Other Po
lutants
79-20-9
Acetic acid, methyl ester1
4.3 E-06
1.7 E-04
--
67-64-1
Acetone
2.8 E-05
1.1 E-03
--
74-86-2
Acetylene8
4.3 E-06
1.7 E-04
~
35572-78-2
2-Amino-4,6-dinitrotoluene8
ND
ND
8.3 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
8.3 E-04
100-52-7
Benzaldehyde
ND
ND
8.1 E-03
134-96-3
Benzaldehyde, 4-hydroxy-3,5-di-
methoxyJ
1.9 E-06
7.4 E-05
--
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
3.3 E-02
106-97-8
Butane
3.8 E-06
1.5 E-04
--
106-98-9
1-Butene
3.6 E-06
1.4 E-04
--
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
02/08
Ordnance Detonation
A-47

-------
TABLE A6 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
107-00-6
1-Butynef
ND
ND
4.5 E-02
503-17-3
2-Butyne
1.6E-06
6.1 E-05
--
7440-70-2
Calciumf
1.5 E-07
6.0 E-06
--
7440-44-0
Elemental carbonf
2.8 E-05
1.1 E-03
--
7440-44-0
Organic carbon8
1.3 E-03
4.9 E-02
--
7440-44-0
Total carbon8
1.3 E-03
5.0E-02
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.7 E-02
120-92-3
CyclopentanoneJ
2.3 E-06
9.1 E-05
--
1120-73-6
2-Cyclopenten-l-one, 2-methyl-J
1.1 E-06
4.2 E-05
--
488-10-8
2-Cyclopenten-l-one, 3-methyl-J
2.3 E-06
9.1 E-05
--
124-48-1
Dibromochloromethane
ND
ND
4.3 E-02
156-59-2
cis-1,2-Dichloroethene
ND
ND
2.0 E-02
156-60-5
trans-1,2-Dichloroethene
ND
ND
2.0 E-02
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
2.3 E-02
84-66-2
Diethylphthalate
ND
ND
1.7 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
8.1 E-03
117-84-0
Di-n-octylphthalate8
ND
ND
1.7 E-02
74-84-0
Ethane8
3.3 E-05
1.3 E-03
--
1192-62-7
Ethanone, l-(2-furanyl)-J
2.8 E-06
1.1 E-04
--
2478-38-8
Ethanone, l-(4-hydroxy-3,5-
dimethoxyphenyl)-
1.3 E-06
5.0 E-05
--
141-78-6
Ethyl acetate
ND
ND
1.8 E-02
97-63-2
Ethyl methacrylate
ND
ND
2.4 E-02
622-96-8
4-Ethyltoluene8
ND
ND
2.5 E-02
110-00-9
FuranJ
7.9 E-06
3.1 E-04
--
98-01-1
2-FurancarboxaldehydeJ
9.0 E-06
3.5 E-04
--
620-02-0
2-Furancarboxaldehyde, 5-methyl-J
1.8 E-06
7.0 E-05
--
98-00-0
2-FuranmethanolJ
2.9 E-06
1.1 E-04
--
534-22-5
Furan, 2-methyl-
4.6 E-06
1.8 E-04
--
629-78-7
HeptadecaneJ
2.1 E-06
7.9 E-05
--
142-82-5
n-Heptane8
1.0 E-06
3.9 E-05
--
66-25-1
Hexaldehyde
ND
ND
8.1 E-03
591-78-6
2-Hexanone
1.2 E-06
4.5 E-05
--
592-41-6
1-Hexene1
3.1 E-06
1.2 E-04
--
A-48
Ordnance Detonation
02/08

-------
TABLE A6 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
2691-41-0
HMX
ND
ND
1.6 E-03
10035-10-6
Hydrogen bromide
ND
ND
1.0E-01
95-13-6
Indene1
2.5 E-06
9.7 E-05
--
75-28-5
Isobutane
ND
ND
4.8 E-02
115-11-7
Isobutylene
2.7 E-06
1.1 E-04
--
590-86-3
Isovaleraldehyde
ND
ND
8.1 E-03
7439-95-4
Magnesium8
5.2E-08
2.0 E-06
--
78-93-3
Methyl ethyl ketone
3.3 E-05
1.3 E-03
--
98-83-9
alpha-Methylstyrene
ND
ND
2.5 E-02
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
8.3 E-04
88-74-7
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
8.3 E-04
99-08-1
3-Nitrotoluene
ND
ND
6.6 E-03
99-99-0
4-Nitrotoluene
ND
ND
4.1 E-03
111-65-9
Octane8
1.1 E-06
4.3 E-05
--
109-66-0
Pentane
2.0 E-06
7.8 E-05
--
600-14-6
2,3-PentanedioneJ
1.3 E-06
5.0 E-05
--
109-67-1
1-Pentene1
1.4 E-06
5.3 E-05
--
627-20-3
2-Pentene, (Z)-J
1.0 E-06
4.0 E-05
--
14797-73-0
Perchlorate
ND
ND
1.6E-01
91-10-1
Phenol, 2,6-dimethoxy-
3.5 E-06
1.3 E-04
--
6627-88-9
Phenol, 2,6-dimethoxy-4-(2-
propenyl)-J
2.2 E-06
8.4 E-05
~
93-51-6
Phenol, 2-methoxy-4-methylJ
1.7 E-06
6.6 E-05
--
7664-38-2
Phosphoric acid
ND
ND
1.0E-01
74-98-6
Propane8
1.2 E-05
4.5 E-04
~
78-85-3
2-Propenal, 2-methyl-
2.0 E-06
7.6 E-05
~
115-11-7
1-Propene, 2-methyl8
2.7 E-06
1.1 E-04
~
74-99-7
Propyne8
3.7 E-06
1.4 E-04
--
121-82-4
RDX
ND
ND
8.3 E-04
110-02-1
Thiophene1
9.5 E-07
3.7 E-05
~
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.5 E-02
25323-89-1
Trichloroethene
ND
ND
2.5 E-02
02/08
Ordnance Detonation
A-49

-------
TABLE A6 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
108-67-8
1,3,5 -T rimethy lbenzene8
ND
ND
2.5 E-02
99-35-4
1,3,5 -T rinitrobenzene8
ND
ND
8.3 E-04
118-96-7
2,4,6-Trinitrotolueneh
1.3 E-07
5.0E-06
--
110-62-3
Valeraldehyde
ND
ND
8.1 E-03
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 2.59 E-02 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated A because of correlation with emission factors for similar ordnance and number
of test data points.
8 Emission factor rated B because of correlation with emission factors for similar ordnance and number
of test data points.
h Emission factor based upon C-rated test data, but because of correlation with emission factors for
similar ordnance and number of data points the factor was upgraded from a D rating to a C rating.
1 Emission factor rated D because the factor is based upon C-rated test data.
J Emission factor rated D because the factor is for a tentatively identified compound.
A-50
Ordnance Detonation
02/08

-------
TABLE A7 COMPOUNDS ANALYZED AND EMISSION FACTORS DEVELOPED FOR
DODIC N286, M582 MECHANICAL TIME AND SUPER QUICK (MTSQ) FUSE


Emission Factorb c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
Carbon Dioxide, Criteria Pollutants, Methane, and Total
Suspended Particulate
124-38-9
Carbon dioxide
3.0E-02
5.6E-01
--
630-08-0
Carbon monoxide
2.4 E-03
4.6 E-02
--
7439-92-1
Lead
5.0E-04
9.4 E-03
--
74-82-8
Methane
4.4 E-05
8.3 E-04
--
--
Oxides of nitrogen
1.1 E-03
2.0 E-02
--
--
PM-2.5
1.0E-02
1.9E-01
--
--
PM-10
1.5 E-02
2.9E-01
--
7446-09-5
Sulfur dioxide
ND
ND
2.7 E-01
12789-66-1
Total suspended particulate
1.6 E-02
3.1 E-01
--
Hazardous Air Pollutants and Toxic Chemicals
83-32-9
Acenaphthene
ND
ND
1.7 E-05
208-96-8
Acenaphthylene
4.8 E-08
9.0 E-07
--
75-07-0
Acetaldehydef
3.7 E-06
6.9 E-05
--
75-05-8
Acetonitrile
7.6 E-06
1.4 E-04
--
107-02-8
Acrolein
ND
ND
7.4 E-03
107-13-1
Acrylonitrile
5.2E-07
9.9 E-06
--
107-05-1
Allyl chloride
ND
ND
3.2 E-03
7429-90-5
Aluminum
1.8 E-03
3.4 E-02
~
7664-41-7
Ammonia
1.3 E-04
2.4 E-03
--
120-12-7
Anthracene
ND
ND
8.5 E-05
7440-36-0
Antimony
4.0 E-06
7.5 E-05
~
7440-38-2
Arsenic
ND
ND
5.1 E-03
7440-39-3
Barium
2.6 E-06
5.0 E-05
--
71-43-2
Benzene
1.0 E-06
1.9 E-05
~
56-55-3
Benzo [a] anthracene
ND
ND
1.7 E-05
205-99-2
Benzo [b] fluoranthene
ND
ND
1.7 E-05
207-08-9
Benzo [k] fluoranthene
1.1 E-08
2.0 E-07
--
191-24-2
Benzo [g,h,i]perylene
ND
ND
1.7 E-05
50-32-8
Benzo [a]pyrene
ND
ND
1.7 E-05
192-97-2
Benzo [e]pyrene
ND
ND
1.7 E-05
100-44-7
Benzyl chloride
ND
ND
5.3 E-03
7440-41-7
Beryllium
ND
ND
5.1 E-03
75-25-2
Bromoform
ND
ND
1.1 E-02
02/08
Ordnance Detonation
A-51

-------
TABLE A7 (cont.)
CASRN3
Compound
Emission Factorb'c
Minimum
Detection Level
mg/m3e
lb per item
lb per lb
NEWd
74-83-9
Bromomethane
ND
ND
3.9 E-03
101-55-3
4-Bromophenylphenylether
ND
ND
1.7 E-02
106-99-0
1,3-Butadiene
ND
ND
4.5 E-02
75-65-0
t-Butyl alcohol
ND
ND
3.1 E-03
85-68-7
Butylbenzylphthalate
ND
ND
1.7 E-02
123-72-8
Butyraldehyde
ND
ND
7.4 E-03
7440-43-9
Cadmium
1.5 E-07
2.8 E-06
--
75-15-0
Carbon disulfide
ND
ND
3.2 E-03
56-23-5
Carbon tetrachloride
ND
ND
6.4 E-03
106-47-8
4-Chloroaniline
ND
ND
1.7 E-02
108-90-7
Chlorobenzene
ND
ND
4.7 E-03
75-45-6
Chlorodifluoromethane
ND
ND
3.6 E-03
75-00-3
Chloroethane
ND
ND
2.7 E-03
111-91-1
bis(2-Chloroethoxy)methane
ND
ND
1.7 E-02
111-44-4
Bis(2-chloroethyl)ether
ND
ND
1.7 E-02
67-66-3
Chloroform
ND
ND
5.0 E-03
74-87-3
Chloromethane
5.7 E-08
1.1 E-06
--
91-58-7
2-Chloronaphthalene
ND
ND
1.7 E-02
95-57-8
2-Chlorophenol
ND
ND
1.7 E-02
7005-72-3
4-chlorophenyl-phenylether
ND
ND
1.7 E-02
7440-47-3
Chromium
8.6 E-06
1.6E-04
--
18540-29-9
Hexavalent chromiumf
ND
ND
5.8 E-01
218-01-9
Chrysene
ND
ND
1.7 E-05
7440-48-4
Cobalt
3.1 E-07
6.0 E-06
--
7440-50-8
Copper
6.3 E-05
1.2E-03
--
106-44-5
p-Cresol
ND
ND
1.7 E-02
4170-30-3
Crotonaldehyde
ND
ND
7.4 E-03
98-82-8
Cumene
ND
ND
5.0 E-03
57-12-5
Particulate cyanide
ND
ND
1.2 E-02
53-70-3
Dibenz [a,h] anthracene
ND
ND
1.7 E-05
132-64-9
Dibenzofuran
ND
ND
1.7 E-02
106-93-4
1,2-Dibromoethane
ND
ND
7.8 E-03
84-74-2
Dibutyl phthalate
ND
ND
1.7 E-02
95-50-1
1,2-Dichlorobenzene
ND
ND
6.1 E-03
541-73-1
1,3 -Dichlorobenzene
ND
ND
6.1 E-03
A-52
Ordnance Detonation
02/08

-------
TABLE A7 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
106-46-7
1,4-Dichlorobenzene
ND
ND
6.1 E-03
75-27-4
Dichlorobromomethane
ND
ND
6.8 E-03
75-71-8
Dichlorodifluoromethane
ND
ND
5.0 E-03
75-34-3
1,1 -Dichloroethane
ND
ND
4.1 E-03
107-06-2
1,2-Dichloroethane
ND
ND
4.1 E-03
75-43-4
Dichlorofluoromethane
ND
ND
4.3 E-03
120-83-2
2,4-Dichlorophenol
ND
ND
1.7E-02
78-87-5
1,2-Dichloropropane
ND
ND
4.7 E-03
10061-02-6
trans-1,3-Dichloropropene
ND
ND
4.6 E-03
76-14-2
Dichlorotetrafluoroethane
ND
ND
7.1 E-03
105-67-9
2,4-Dimethylphenol
ND
ND
1.7 E-02
131-11-3
Dimethyl phthalate
ND
ND
1.7 E-02
99-65-0
1,3 -Dinitrobenzene
ND
ND
6.6 E-04
534-52-1
4,6-Dinitro-2-methylphenol
ND
ND
1.7 E-02
121-14-2
2,4-Dinitrotoluene
ND
ND
1.7 E-02
606-20-2
2,6-Dinitrotoluene
ND
ND
1.7 E-02
606-20-2
2,6-Dinitrotoluene
ND
ND
6.6 E-04
123-91-1
1,4-Dioxane
ND
ND
3.7 E-03
--
Total dioxin/furan compounds
6.6E-12
1.3 E-10
--
140-88-5
Ethyl acrylate
ND
ND
4.2 E-03
100-41-4
Ethylbenzene
ND
ND
4.4 E-03
74-85-1
Ethylene
3.2E-06
6.0 E-05
--
206-44-0
Fluoranthene
2.3 E-08
4.3 E-07
--
86-73-7
Fluorene
1.1 E-08
2.2 E-07
--
50-00-0
Formaldehyde
2.0 E-06
3.8 E-05
--
76-13-1
Freon 113
ND
ND
7.8 E-03
35822-46-9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-
dioxin
3.6 E-13
6.8E-12
--
67562-39-4
1,2,3,4,6,7,8-
Heptachlorodibenzofuranf
3.4 E-13
6.4E-12
~
55673-89-7
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
ND
ND
3.8 E-09
118-74-1
Hexachlorobenzene
ND
ND
1.7 E-02
87-68-3
Hexachlorobutadiene
ND
ND
1.7 E-02
77-47-4
Hexachlorocyclopentadiene
ND
ND
1.7 E-02
02/08
Ordnance Detonation
A-53

-------
TABLE A7 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
39227-28-6
1,2,3,4,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
8.0 E-10
57653-85-7
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
ND
ND
8.2 E-10
19408-74-3
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
2.6 E-14
4.9 E-13
--
70648-26-9
1,2,3,4,7,8-Hexachlorodibenzofuran
3.9 E-13
7.5 E-12
--
57117-44-9
1,2,3,6,7,8-Hexachlorodibenzofuran
1.5 E-13
2.9E-12
--
72918-21-9
1,2,3,7,8,9-Hexachlorodibenzofuran
ND
ND
1.5 E-09
60851-34-5
2,3,4,6,7,8-Hexachlorodibenzofuran
1.4 E-13
2.7 E-12
--
67-72-1
Hexachloroethane
ND
ND
9.8 E-03
110-54-3
Hexane
ND
ND
7.2 E-02
7647-01-0
Hydrochloric acid
2.2 E-06
4.1 E-05
--
74-90-8
Hydrogen cyanide
7.7 E-05
1.5 E-03
~
7664-39-3
Hydrogen fluoride
ND
ND
1.0 E-01
193-39-5
Indeno [ 1,2,3 -cd]pyrene
ND
ND
1.7 E-05
78-59-1
Isophorone
ND
ND
1.7 E-02
7439-96-5
Manganese
1.1 E-05
2.2 E-04
--
96-33-3
Methyl acrylate
ND
ND
3.6 E-03
74-95-3
Methylene bromide
ND
ND
7.2 E-03
75-09-2
Methylene chloride
0
0
--
74-88-4
Methyl iodide
ND
ND
5.9 E-03
108-10-1
Methyl isobutyl ketone
ND
ND
4.2 E-03
80-62-6
Methyl methacrylate
ND
ND
4.2 E-03
91-57-6
2-Methylnaphthalene
ND
ND
1.7 E-02
95-48-7
2-Methylphenol
ND
ND
1.7 E-02
1634-04-4
Methyl tert-butyl ether
ND
ND
3.7 E-03
91-20-3
Naphthalene
1.9E-07
3.5 E-06
--
7440-02-0
Nickel
2.8 E-06
5.3 E-05
--
7697-37-2
Nitric acid
ND
ND
1.0 E-01
100-01-6
4-Nitroaniline
ND
ND
1.7 E-02
98-95-3
Nitrobenzene
ND
ND
6.6 E-04
55-63-0
Nitroglycerin
ND
ND
6.6 E-04
88-75-5
2-Nitrophenol
ND
ND
1.7 E-02
100-02-7
4-Nitrophenol
ND
ND
1.7 E-02
62-75-9
n-Nitrosodimethylamine
ND
ND
1.7 E-02
A-54
Ordnance Detonation
02/08

-------
TABLE A7 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
86-30-6
n-Nitrosodiphenylamine
ND
ND
1.7 E-02
621-64-7
n-Nitroso-di-n-propylamine
ND
ND
1.7 E-02
40321-76-4
1,2,3,7,8-Pentachlorodibenzo-p-
dioxin
ND
ND
2.7 E-09
57117-41-6
1,2,3,7,8 -Pentachlorodibenzofuran
1.7E-13
3.2 E-12
--
57117-31-4
2,3,4,7,8-Pentachlorodibenzofuran
2.5 E-13
4.7 E-12
--
87-86-5
Pentachlorophenol
ND
ND
1.7 E-02
85-01-8
Phenanthrene
4.3 E-08
8.1 E-07
--
108-95-2
Phenol
ND
ND
1.7 E-02
123-38-6
Propionaldehyde
ND
ND
7.4 E-03
115-07-1
Propylene
9.2 E-07
1.7E-05
--
129-00-0
Pyrene
2.1 E-08
3.9 E-07
--
7782-49-2
Selenium
ND
ND
5.1 E-03
7440-22-4
Silver
1.7 E-07
3.3 E-06
~
100-42-5
Styrene
ND
ND
4.3 E-03
7664-93-9
Sulfuric acid
ND
ND
1.0 E-01
1746-01-6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
ND
ND
1.1 E-09
51207-31-9
2,3,7,8 -T etrachlorodibenzofuran
1.2 E-13
2.3 E-12
~
630-20-6
1,1,1,2-Tetrachloroethane
ND
ND
7.0 E-03
79-34-5
1,1,2,2-Tetrachloroethane
ND
ND
7.0 E-03
127-18-4
T etrachloroethy lene
ND
ND
6.9 E-03
7440-28-0
Thallium
ND
ND
5.1 E-03
108-88-3
Toluene
2.1 E-07
4.0 E-06
--
120-82-1
1,2,4-Trichlorobenzene
ND
ND
1.7 E-02
71-55-6
1,1,1 -T richloroethane
ND
ND
5.5 E-03
79-00-5
1,1,2-Trichloroethane
ND
ND
5.5 E-03
75-69-4
Trichlorofluoromethane
ND
ND
5.7 E-03
95-95-4
2,4,5-Trichlorophenol
ND
ND
1.7 E-02
88-06-2
2,4,6-Trichlorophenol
ND
ND
1.7 E-02
96-18-4
1,2,3 -T richloropropane
ND
ND
6.1 E-03
95-63-6
1,2,4-Trimethylbenzene
ND
ND
5.0 E-03
540-84-1
2,2,4-Trimethylpentane
ND
ND
4.8 E-03
7440-62-2
Vanadium
4.4 E-07
8.3 E-06
--
108-05-4
Vinyl acetate
ND
ND
3.6 E-03
75-01-4
Vinyl chloride
ND
ND
2.6 E-03
02/08
Ordnance Detonation
A-55

-------
TABLE A7 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level
mg/m3e
75-35-4
Vinylidene chloride
ND
ND
4.0 E-03
106-42-3,
108-38-3
m-Xylene, p-Xylene
ND
ND
4.4 E-03
95-47-6
o-Xylene
ND
ND
4.4 E-03
7440-66-6
Zincf
2.1 E-04
4.0 E-03
—
Other Po
lutants
67-64-1
Acetone
ND
ND
7.1 E-02
74-86-2
Acetylene
2.4 E-06
4.6 E-05
--
35572-78-2
2-Amino-4,6-dinitrotoluene
ND
ND
6.6 E-04
19406-51-0
4-Amino-2,6-dinitrotoluene
ND
ND
6.6 E-04
100-52-7
Benzaldehyde
ND
ND
7.4 E-03
3622-84-2
Benzenesulfonamide, N-butyl-8
4.5 E-07
8.5 E-06
--
100-51-6
Benzyl alcohol
ND
ND
1.7 E-02
108-86-1
Bromobenzene
ND
ND
6.5 E-03
106-97-8
Butane
ND
ND
5.3 E-02
106-98-9
1-Butene
ND
ND
4.7 E-02
590-18-1
cis-Butene
ND
ND
4.7 E-02
624-64-6
trans-Butene
ND
ND
4.7 E-02
107-00-6
1-Butyne
ND
ND
4.5 E-02
503-17-3
2-Butyne
ND
ND
4.5 E-02
7440-70-2
Calcium
3.0E-05
5.7 E-04
--
7440-44-0
Elemental carbon
1.4 E-04
2.6 E-03
--
7440-44-0
Organic carbon
8.1 E-05
1.5 E-03
--
7440-44-0
Total carbon
2.2 E-04
4.2 E-03
--
39638-32-9
bis(2-Chloroisopropyl)ether
ND
ND
1.7 E-02
59-50-7
4-Chloro-3 -methylphenol
ND
ND
1.7 E-02
124-48-1
Dibromochloromethane
ND
ND
8.7 E-03
156-59-2
cis-1,2-Dichloroethene
ND
ND
4.0 E-03
156-60-5
trans-1,2-Dichloroethene
ND
ND
4.0 E-03
10061-01-5
cis-1,3 -Dichloropropene
ND
ND
4.6 E-03
84-66-2
Diethylphthalate
ND
ND
1.7 E-02
5779-94-2
2,5 -Dimethy lbenzaldehyde
ND
ND
7.4 E-03
117-84-0
Di-n-octylphthalate
ND
ND
1.7 E-02
74-84-0
Ethane
1.1 E-06
2.1 E-05
--
141-78-6
Ethyl acetate
ND
ND
3.7 E-03
A-56
Ordnance Detonation
02/08

-------
TABLE A7 (cont.)


Emission Factorb'c
Minimum
CASRN3
Compound
lb per item
lb per lb
NEWd
Detection Level


mg/m3e
97-63-2
Ethyl methacrylate
ND
ND
4.7 E-03
622-96-8
4-Ethyltoluene
ND
ND
5.0 E-03
142-82-5
n-Heptane
ND
ND
4.2 E-03
66-25-1
Hexaldehyde
ND
ND
7.4 E-03
591-78-6
2-Hexanone
ND
ND
4.2 E-03
2691-41-0
HMX
ND
ND
1.6 E-03
10035-10-6
Hydrogen bromide
ND
ND
1.0 E-01
75-28-5
Isobutane
ND
ND
4.8 E-02
590-86-3
Isovaleraldehyde
ND
ND
7.4 E-03
7439-95-4
Magnesium
3.0 E-05
5.6 E-04
--
75-52-5
Methane, nitro-8
9.2 E-08
1.7 E-06
--
78-93-3
Methyl ethyl ketone
ND
ND
3.0 E-03
98-83-9
alpha-Methylstyrene
ND
ND
4.9 E-03
479-45-8
Methyl-2,4,6-
trinitrophenylnitramine
ND
ND
6.6 E-04
88-74-7
2-Nitroaniline
ND
ND
1.7 E-02
99-09-2
3-Nitroaniline
ND
ND
1.7 E-02
88-72-2
2-Nitrotoluene
ND
ND
6.6 E-04
99-08-1
3-Nitrotoluene
ND
ND
3.4 E-03
99-99-0
4-Nitrotoluene
ND
ND
6.6 E-04
111-65-9
Octane
ND
ND
4.8 E-03
109-66-0
Pentane
ND
ND
6.0 E-02
14797-73-0
Perchlorate
ND
ND
1.4 E-01
7664-38-2
Phosphoric acidf
4.3 E-06
8.1 E-05
--
74-98-6
Propane
ND
ND
3.7 E-02
115-11-7
1-Propene, 2-methyl
2.6 E-07
4.9 E-06
--
74-99-7
Propyne
ND
ND
3.3 E-02
121-82-4
RDX
1.4 E-06
2.6 E-05
--
1334-78-7
o,m,p-Tolualdehyde
ND
ND
2.2 E-02
25323-89-1
Trichloroethene
ND
ND
5.0 E-03
108-67-8
1,3,5 -T rimethylbenzene
ND
ND
5.0 E-03
99-35-4
1,3,5 -T rinitrobenzene
4.7 E-08
8.8 E-07
--
118-96-7
2,4,6-Trinitrotoluene
6.5 E-08
1.2 E-06
--
110-62-3
Valeraldehyde
ND
ND
7.4 E-03
02/08
Ordnance Detonation
A-57

-------
TABLE A7 (cont.)
a CASRN = Chemical Abstracts Service Registry Number.
b ND = nondetected.
c Emission factors rated C unless otherwise noted.
d NEW = Net explosive weight. The NEW for this compound is 5.27 E-02 pounds per item.
e Data provided for compounds that were not detected.
f Emission factor rated D because the factor is based upon C-rated test data.
8 Emission factor rated D because the factor is for a tentatively identified compound.
A-58
Ordnance Detonation
02/08

-------
APPENDIX B
NEW AP-42 SECTIONS FOR ORDNANCE INCLUDED IN EXPLODING ORDNANCE
EMISSION STUDY PHASE II SERIES 7 TESTING AT ABERDEEN PROVING GROUND,
MARYLAND
Electronic versions of the new AP-42 sections for ordnance included in Exploding Ordnance
Emission Study Phase II Series 7 testing at Aberdeen Proving Ground, Maryland, are located on the EPA
website at: http://www.epa.gov/ttn/chief/ap42/index.html.
02/08
Ordnance Detonation
B-l

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B-2	Ordnance Detonation	02/08

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