&EPA
Leaching Environmental
Assessment Framework (LEAF)
How-To Guide
Understanding the LEAF Approach
APPENDICES
SW-846 Update VI
Revision 0
October 2017
-------
Table of Contents
Appendix A; Leaching Methods in the U.S. and European Union A- l
Appendix B: Full Graphical LEAF Results for Case Studies (Section 5) B-l
Ml Case Study i: Mvaluatlog Coal Combysijoin lly Ash for Use as Construction 1'iU Materia! B--2
Leaching Environmental Assessment Framework (LEAF) How-To Guide
Table of Contents
-------
Appendix A: Leaching Methods in the U.S. and European Union
Table A-l. U.S. and European Leaching Tests
Analogous European Methods
Test Type
U.S. EPA
Method
Soil, sediments,
compost and
sludge
Waste
Mining waste
Construction
products
pH dependence test
1313
ISO/TS 21268-4®
EN 14429b
-
EN 14997
-
Percolation test
1314
ISO/TS 21268-3®
CEN/TS 14405
FprCEN/TS 16637-3®
-
NEN 7373
-
NEN 7373
NEN 7374®
-
NEN 7374®
Monolith test
1315
-
PrEN 15863
-
CEN/TS 16637-2®
-
NEN 7375
-
NEN 7375
-
NVN 7376®
-
NVN 7376®
Compacted granular test
1315
-
NEN 7347
-
CEN/TS 16637-2®
L/S dependence test
1316
No European equivalent
Redox capacity
N/A
-
CEN/TS 16660
-
-
Acid rock drainage
N/A
EN 15875
Reactive surfaces
N/A
EN ISO 12782 pts 1-5
Vienna
-
-
Source: van der Sloot et al. (2015)
a Test is applicable to organic constituents
b Not yet adopted in the CEN/TC 351 working group for construction products, but highly relevant for the European
Construction Products Regulation (CPR).
CEN - European Committee for Standardization; iviviv.ce/?.eu (accessed 25 Nov. 2016)
EN -validated European standard
FprCEN/TS - European standard, preliminary technical specification that needs to undergo validation
ISO/TS - International standard
NEN -Dutch standard (validated)
NVN - Dutch preliminary standard (standard without validation)
PrEN - European standard, preliminary full EN test method that has undergone validation, in voting for acceptance
by member states (minimal changes anticipated).
TS -Technical specification
Vienna -Vienna Agreement; ISO standards can be adopted as European standards with the EN-ISO reference
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix A:Leaching Methods in the U.S. and European Union
-------
Table A-2. Online References for Various Leaching Test Methods
Method
URL
Last Access
U.S. EPA Methods
1313,1314,1315
and 1316
http://www3.epa.gov/epawaste/hazard/testmethods/sw846/new_meth.htm
20-NOV-2016
EN 14997
http://standards.cen. eu/dyn/www/f?p=204:110:0:::: FSP_PROJECT, FSP_0RG_ID:3
9446,62 73&cs=l DF6C4C988FB5E443807EE81C2F0B1229
20-NOV-2016
FprCEN/TS 16637-3
http://standards.cen. eu/dyn/www/f?p=CEN WEB :110:0::: :FSP_ORGJD, FSP_PROJ
ECT:510793,34858& cs=19FA 1DFBB93378D5502AB79E8A707343E
20-NOV-2016
CEN/TS 16637-2
http://standards.cen. eu/dyn/www/f?p=CENWEB:110:0::::FSP_ORG_ID, FSP_PROJ
E CT:510793,34857& cs=l FC07D076AA 7B4CAFA674FA865A0A 7F4 C
20-NOV-2016
ISO/TS 21268-4
h ttp://www. iso. org/iso/h ome/store/cata!ogue_ tc/catalogue_detail. h tm ?csn umb
er=39105
20-NOV-2016
ISO/TS 21268-3
h ttp://www. iso. org/iso/iso_ catalogue/catalogue_ tc/catalogue_detail. h tm ?csn u
mber=44147
20-NOV-2016
NEN 7373
https://www.nen. nl/NEN-Shop-2/Standard/NEN-73 732004-nl.htm
20-NOV-2016
NEN 7375
https://www.nen. nl/NEN-Shop-2/Standard/NEN-73752004-nl.htm
20-NOV-2016
NVN 7376
https://www.nen. nl/NEN-Shop-2/Standard/NVN-73 762004-nl.htm
20-NOV-2016
NEN 7347
https://www.nen. nl/NEN-Shop-2/Standard/NEN-734 72006-en.htm
20-NOV-2016
PrEN 14405
h ttp://infostore. saiglobal. com/store/details, aspx ?ProductlD=l 762692
20-NOV-2016
EN 15863
http://infostore.saiglobal.com/store/details. aspx?ProductlD=l678717
20-NOV-2016
EN ISO 12782-1
http://www.iso.org/iso/catalogue_tc/catalogue_detail.htm ?csnumber=51697
20-NOV-2016
EN ISO 12782-2
http://www.iso.org/iso/catalogue_tc/catalogue_detail.htm ?csnumber=51698
20-NOV-2016
EN ISO 12782-3
http://www.iso.org/iso/catalogue_tc/catalogue_detail.htm ?csnumber=51699
20-NOV-2016
EN ISO 12782-4
http://www.iso.org/iso/catalogue_tc/catalogue_detail.htm ?csnumber=51700
20-NOV-2016
EN ISO 12782-5
h ttp://www. iso. org/iso/catalogue_tc/catalogue_detail. h tm ?csn um ber=51701
20-NOV-2016
CEN/TS 16660
http://standards.cen. eu/dyn/www/f?p=204:110:0::::FSP_PROJECT:39665&cs=13 7
E16928DF0300D78675778C7955F973
20-NOV-2016
EN 15875
http://shop. bsigroup.com/ProductDetail/?pid=0000000000302 71066
20-NOV-2016
EN 14429
h ttp://infostore. saiglobal. com/store/details, aspx ?ProductlD=l678643
20-NOV-2016
Note: most methods are available to download for a publication fee.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix A:Leaching Methods in the U.S. and European Union
-------
Appendix B: Graphical and Tabular LEAF Results for Case Study
(Section 5)
This appendix provides LEAF testing data in graphical and tabular form for the material and constituents
discussed in the hypothetical case study (Section 5). Graphical data is presented "as produced" from
LeachXS™ Lite with minor modifications to provide consistency in formatting for the data series. Tabular
data, including interpolated pH-dependent concentrations, availability determination and leaching
assessment over a user-defined pH domain from Method 1313, is "as produced" directly from the
reporting features of the LeachXS™ program.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
B.l Case Study: Evaluating Coal Combustion Fly Ash for Use as Construction
Fill Material
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Figure B-l. Method 1313 results for a low-carbon coal fly ash (EaFA):
Titration curve, antimony, arsenic, barium, boron and cadmium.
8 10
PH
EaFA 1314
12
14
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
B-2
-------
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Figure B-2. Method 1313 results for a low-carbon coal fly ash (EaFA):
Chromium, lead, molybdenum, selenium and thallium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
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4 | i i i | i i i | i i i | i i i | i i i 11
0 2 4 6 8 10
L/S (L/kg-dry)
0.001
0.0001
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L/S (L/kg-dry)
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0 2 4 6 8 10
L/S (L/kg-dry)
0.1
0 2 4 6 8 10
L/S (L/kg-dry)
0.0001
0
4 6
L/S (L/kg-dry)
—•— EaFA_1313 O Natural pH Indicator -0-EaFA_1316 —A—EaFA_1314
Figure B-3. Method 1314 results for a low-carbon coal fly ash (EaFA):
Eluate pH, antimony and arsenic.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
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L/S (L/kg-dry)
10
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0.001
4 6
L/S (L/kg-dry)
100
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S
4 6
L/S (L/kg-dry)
4 6
L/S (L/kg-dry)
EaFA_1313 O Natural pH Indicator — O - EaFA_1316
4 6
L/S (L/kg-dry)
EaFA 1314
Figure B-4. Method 1314 results for a low-carbon coal fly ash (EaFA):
Barium, boron and cadmium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
J-5
-------
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EaFA_1313 O Natural pH Indicator — O - EaFA_1316
0.01
4 6
L/S (L/kg-dry)
EaFA 1314
Figure B-5. Method 1314 results for a low-carbon coal fly ash (EaFA):
Chromium, lead and molybdenum.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EaFA_1313 O Natural pH Indicator — O - EaFA_1316 —A—EaFA_1314
Figure B-6. Method 1314 results for a low-carbon coal fly ash (EaFA):
Selenium and thallium.
0 2 4 6 8 10
L/S (L/kg-dry)
0.1
0 2 4 6 8 10
L/S (L/kg-dry)
0.1
0.01
0.001
0.0001
0 2 4 6 8 10
L/S (L/kg-dry)
4 6 8 10
L/S (L/kg-dry)
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
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EaFA 1314
Figure B-7. Method 1316 results for a low-carbon coal fly ash (EaFA):
Eluate pH, antimony and arsenic.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
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Figure B-8. Method 1316 results for a low-carbon coal fly ash (EaFA):
Barium, boron and cadmium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
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Figure B-9. Method 1316 results for a low-carbon coal fly ash (EaFA):
Chromium, lead and molybdenum.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
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Figure B-10. Method 1316 results for a low-carbon coal fly ash (EaFA):
Selenium and thallium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313
Sample: EaFA (P,1,1)
Analysis report according to EPA Method 1313
Created by LeachXS'", version 2.0.92 (18-Oct-2016)
Report created on 25-Jan-2G17 2:49 PM
Material Information
Sample ID
Sample Name
Sample Replicate
Test Replicate
Category
Subcategory
Full Name
Description
Origin
Sample Database
EaFA (P,l,l)
EaFA
A
A
Coal Combustion
Fly Ash
EaFA
Fly Ash / Unit 1 / Facility Ea
EPA LEAF Methods validation
C:\Users\User\Documents\LeachXS User Objects\
DATABASES\LEAF Guide (16-Dec-2016).mdb
Test Parameters
Start Date
End Date
Particle Size
Contact Interval
Solids Content
19-Apr-10
20-Apr-10
0.3 mm
24.0 h
100 %
Legend
pH Acidity
E(h) Redox potential
K(25°C) Conductivity at 25 °C
L/S-dry Liquid-to-solid ratio
M Dry mass
V Volume Dl water
Total V Total liquid volume
N/A Not analyzed or measured
N/C Not calculated
V(acid) Volume of added acid
[acid] Concentration of added acid
V(base) Volume of added base
[base] Concentration of added base
[H30+] Acid neutralization capacity
[OH-] Base neutralization capacity
Concentrations below the method detection limit (MDL) are reported between parentheses as half of the MDL.
Report Date: 25-Jan-2017
page 1
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphicai and Tabular LEAF Results for Case Study (Section 5)
B-12
-------
EPA Method IBIS
Fraction Information
Fraction
PH
m
K(2S"C)
L/S-dty
M
V
Total V
mV
mS/cm
1/kq
kqdry
ml
ml
9
2.08
N/A
173
10.0
0.0400
387
400
8
3,85
N/A
4,51
10,0
0.-0400
398
400
7
5.40
N/A
2,88
10.0
0,0400
400
400
6
6,99
N/A
2,71
10.0
0.0400
400
400
5
7.97
N/A
2.75
10.0
0.0400
400
400
4
3,26
N/A
3.26
10.0
0,0400
399
400
3
10.4
N/A
3.25
10.0
0.0400
398
4 00
2
12.0
N/A
10.9
10.0
0,0400
392
400
1
13,1
H/A
108
10.0
0.0400
336
400
Titration Information
Fraction
pH
V(acid}
[add]
V(basej
/tee/
l"3Or]
(OH]
ml
mol/L
iwl
mol/L r
ool/kg dry tm
it/kg dry
3
2,08
13,0
2,00
0.650
8
3,85
2,00
2.00
0.100
7
a
5.40
SL QO
0.400
2.00
0.0200
D
5
7,97
0.400
1,00
0.0100
4
9.26
1,50
1.00
0,0375
3
10.4
2,50
1.00
0.0625
2
12.0
8.00
1.00
0.200
1
13,1
64.0
1,00
1.60
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313
Sample: EaFA
Concentration in mg/l
Fraction
9
8
7
6
S
4
3
2
1
pH
2.08
3.85
5.40
6.99
7.97
9.26
10.4
12.0
13.1
At
128
32,0
0.335
0.202
1,21
17.7
27,1
33.8
37,0
As
1,55
0.0900
0=0417
0.0784
0,199
0.560
1.05
1.01
9,69
B
3.25
3.82
4,98
4,62
4.38
4.50
4.64
4.99
9.77
B3
0.875
0.220
0.281
0.260
0.256
0.562
0.903
0.921
0.659
Be
0,441
0.142
0,00258
(0,000320)
(0.000320)
(0,000320)
(0,000320)
(0.000329)
(0.000320)
Br"
(0,00871)
0.658
0,687
0.515
0,598
0.700
0,652
0.722
0.827
Ca
141
140
167
155
135
111
87.3
40.9
9,20
Cd
0.0555
0.0427
0.0311
0.00580
0.00470
0.00460
0.00461
0.00505
0.00540
cr
1.64
1,57
1.25
1.30
1.28
130
1.26
1,30
4.19
Co
0.419
0.214
0,252
0.0261
0,00430
0,00140
0.00118
0.000726
(0.000207)
Cr
1.96
0,175
(0.000249}
0.0422
0.134
0,223
0.248
0.306
0.392
Cs
0.0542
0.0239
0.0172
0.0130
0.0148
0.0188
0.0218
0.0282
0.0336
Cu
3,16
1.91
0.0394
o.ooosoo
(0.000351}
(0,000351!
0.000900-
0,00192
0.0179
DiC
0,138
0,150
0,154
(0.0650)
(0.0650}
0,653
1,93
7.95
29.2
DOC
1.69
1,04
1.06
1.15
1.21
1,83
3.19
9.66
142
f
0.0945
3.34
0.409
1,70
2,05
3.13
3.62
3,91
9,38
Fe
33.9
0,419
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
0.0202
0,0339
K
22,1
18.6
25,1
25,0
55,3
135
190
441
1719
Is
1.51
2,12
3.26
3.24
2.97
2.70
2.56
2,23
1,56
Mg
14.0
7.69
830
7,49
5,10
2.86
0,111
(0.000500)
(0.000500)
Mn
1.84
1,17
0.982
0,268
0,0324
(0.000171)
{0,000171)
(0.000171)
(0.000171)
Mo
0.334
0.108
0.552
3.32
3.49
3.70
3.83
3.77
332
Report Date: 25-Jan-2017
page3
-------
EPA Method 1313 Sample: EaFA (P,l,l)
Concentration in mg/t
Fraction
9
8
7
6
S
4
3
2
1
PH
2.08
SMS
5.40
6.99
7.97
9.26
10.4
12.0
13.1
Na
3,85
4,51
6.63
8,45
6,27
6.35
6.50
6.80
8.92
m.
0.762
0,513
0.603
0.0646
0.00310
(0.000365)
(0.000365)
(0.000365)
(0.000365)
N02"
(0.00916)
(0.00316)
(0.00916)
(0,00916|
(0.00916)
(0,00316)
(0.00915)
0.0582
1.14
NO/
47S6
584
94,3
0.916
0.755
0.757
0.612
0.657
0.668
P
2.42
0.0629
(0.00185)
0.0163
0,0396
0.0854
0.0430
0.0372
0.209
Pb
0,257
0.00510
0.00150
0.000900
0.000700
(0.000115)
(0.000115)
(0.000115)
(0,000115)
pg43"
1.01
(0.0118)
(0.0118)
(0.0118)
0.123
0,814
1,33
1.36
2.05
Be
0,00119
(0,000120)
(0.000120)
(0.000120)
|0.000120)
(0.000120)
0.00141
0.00223
0.00309
s
59.0
104
152
164
160
163
160
162
185
Sb
0,0227
0,0525
0.0717
0.148
0.138
0.126
0.143
0.147
0.181
Se
0.546
0.0841
0.230
0,922
1.64
4.01
4,92
5.60
6.88
Ss
72.2
18.0
6.17
1.43
0.535
0.278
0.720
3.76
30,6
Sn
10,000350)
(0.000350)
(0.000350)
(0,000350)
(0,00035-0)
(0.000350)
(0.000350)
(0.000350)
(0.000350)
S042'
426
414
401
425
421
416
418
411
430
Sr
5.56
3,07
3.09
2,54
2.30
2.10
1,96
1.64
0.916
n
1.50
0.00373
(0.00100)
(0.00100)
(0.00100)
fO.OOlOO)
(0.00100)
(0.00100)
(0.00100)
T!
0.256
0.0940
0.0322
0.0101
0.00630
0.00350
0,00290
0.00290
0.00320
U
0.451
0.0155
(0.000150)
(0.000150)
(0.000150)
(0.000150)
0.00107
0.00415
0.0292
V
6.64
0,0818
0.0794
0.158
0.209
0.832
2.07
2.74
5.21
In
1,63
1,16
1.14
(0.000500)
(0.000500)
(0.000500)
(0.000500)
(0.000500)
0.0567
Report Date: 25-Jan-2017
page 4
-------
EPA Method 1313
Sample; EaFA(P,l,l)
Method Detection limit in rng/i
Fraction
9
8
7
6
s
4
3
2
i
pH
2.08
3.85
5,40
6,99
7.97
9.26
10.4
12.0
13.1
AI
0.00100
0.00100
0.00100
0,00100
0.(30100
0.00100
0.00100
0.00100
0,00100
As
0,000640
0.000540
0.000640
0,000640
0.000540
0,000640
0.000640
0.000640
0,000640
B
0,00100
0.00100
0.00100
0.00100
0,0-0100
0.00100
0.00100
0.00100
0,00100
Ba
0.00100
0.00100
0,00100
0,00100
Q.00100
0.00100
0.00100
0.00100
0.0010Q
Be
0,000640
0.000640
0,000640
0,000640
0,000640
0.000640
0,000640
0.000640
0.000640
Br
0.0174
0.0174
0.0174
0,0174
0.0174
0,0174
0.0174
0.0174
0.0174
C3
0.00260
0.00260
0,00260
0.00260
0,00260
0.00260
0.00260
0,00260
0.00260
Cd
0.000170
0.000170
0.000170
0,000170
0.000170
0,000170
0.000170
0.000170
0.000170
cr
0.00643
0.00649
0.00649
0,00649
0.00649
0,00649
0.00649
0.00649
0.00649
Co
0.000414
0.000414
0.000414
0.000414
0,000414
0,000414
0.000414
0.000414
0.000414
Cr
0.000497
0.000497
0,000497
0.000497
0.000497
0.000497
0,000497
0.000497
0,000497
cs
0.000490
0.000490
0.000490
0.000490
0,000490
0.000490
0.000490
0.000490
0.000490
Cu
0.000701
0,000701
0.000701
0,000701
0.000701
0,000701
0.000701
0.000701
0.000701
DIG
0.130
0.130
0.130
0.130
0.130
Q.130
0.130
0.130
0.130
DOC
0.170
0.170
0.170
0.170
0.170
0,170
0.170
0.170
0.170
F"
0,00705
0.00705
0.00705
0.00705
0.00705
0.00705
0.00705
0.00705
0,00705
Fe
0.00200
0.00200
0.00200
0.00200
0.00200
0.00200
0.00200
0.00200
0.00200
K
0.00160
0.00160
0.00160
0.00160
0.00160
0,00160
0.00160
0.00160
0,00160
U
0.00190
0.00190
0.00190
0,00150
0.00190
0.00190
0.00190
0.-00190
0,00190
Mg
0.00100
0.00100
0.00100
0.00100
0.00100
0,00100
0.00100
0.00100
0.00100
Mn
0.000342
0,000342
0.000342
0.000342
0,000342
0.000342
0,000342
0.000342
0,000342
Mo
0.00120
0.00120
0.00120
0.00120
0.00120
0,00120
0,00120
0.00120
0.00120
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
pages
-------
EPA Method 1313
Sample: EaFA(P,l,l)
Method Detection limit in rog/t
Fraction
9
8
7
6
s
4
3
2
1
pH
2.03
3.85
5.40
6.99
737
9.26
10.4
12.0
13.1
m
0.00250
0.00250
0.00250
0.00250
0.00250
0.00250
0.00250
0.00250
0.00250
m
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
0,000730
0.0183
0.0183
0.0183
0.0183
0.0183
0.0183
0.0183
0.0183
0.0183
N03"
0.0258
0.0258
0.0258
0=0258
0.0258
0.0253
0.0258
0.025S
0.0258
p
0.00370
0.00370
0.00370
0,00370
0.00370
0.00370
0.00370
0.00370
0.00370
Pb
0.000230
0,000230
0.000230
0.000230
0.000230
0.000230
0.000230
0,000230
0.000230
P043'
0.0237
0.0237
0.0237
0,0237
0.0237
0.0237
0.0237
0.0237
0.0237
Re
0.000240
0.000240
0.000240
0.00024-0
0.000240
0,000240
0.000240
0.000240
0-000240
S
0.00680
0.00680
0.00680
0.00680
0.00680
0.00680
0.00680
0.00680
0.00680
sb
7.94E-05
7.94E-05
7.94E-05
7.94E-05
7.94E-05
7.94E-Q5
7.94E-05
7.94E-05
7.94E-05
Se
0.0150
0.0150
0.0150
0.0150
0.0150
0.0150
0.0150
0.0150
0.0150
Si
0.00110
0.00110
0.00110
0.00110
0.00110
0.00110
0,00110
0.00110
0.00110
3n
0,000700
0,000700
0.000700
0,000700
0,000700
0.000700
0,000700
0,000700
0.000700
S042'
0.0208
0.0208
0.0208
0.0208
0.0208
0.0208
0.0208
0.0208
0.0208
Sr
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0,00100
0.00100
0.00100
TS
0.00200
0,00200
0.00200
0.00200
0.00200
0.00200
0.00200
0.00200
0.00200
Tl
0.000510
0.000510
0.000510
0.000510
0.000510
0.000510
0,000510
0.000510
0.000510
U
0.000300
0.-000300
0.000300
0.000300
0.000300
0.000300
0,000300
0.000300
0.000300
V
0.00150
0,00150
0.00150
0.00150
0.00150
0.00150
0.00150
0.00150
0.00150
Zn
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
page 6
-------
EPA Method 1313 Sample: EaFA
Release in mg/kj
Fractbn
9
8
7
6
5
4
3
2
I
pH
2,08
3.&5
5.40
6.99
7.97
9.26
10,4
12.0
13.1
At
1280
320
3,35
2.02
12.1
177
271
338
370
As
15.5
0,900
0,417
0.784
1.99
5.60
10.5
10.1
96,9
B
32.5
38.2
49.8
45.2
43,8
45.0
46.4
49.9
97,7
Ba
8.76
2,20
2.81
2.60
2.56
5.62
9,03
9.21
6.59
Be
4.41
1,42
0.0258
(0.00320)
(0.00320)
(0.00320)
(0,00320)
(0,00320)
(0.00320)
if'
(0,0871)
6.68
6.S7
5.15
5.98
7.00
6.52
7,22
8.2?
Ca
1413
1395
1673
1551
1351
1111
873
409
92.0
cd
0,555
0.427
0.311
0,05 SO
0.0470
0,0460
0.0461
0,0505
0.0540
cr
16.4
15,7
12,5
13,0
12,8
13,0
12.6
13.0
41,9
Co
4,19
2.14
2,52
0.261
0.0430
0.0140
0,0118
0.00726
(0.00207)
Cr
13,6
1,75
10.00249)
0.422
1,34
2.23
2.4S
3.06
3.92
Cs
0.642
0.239
0=172
0.130
0.14S
0.188
0,218
0,282
0.336
Cu
31.6
19.1
0.894
0.00900
{0.00351}
(0.00351)
0,00900
0.0192
0,179
OIC
1.38
1.50
1.54
{0.650}
(0.650)
6.53
19.3
79,5
292
DOC
16,9
10=4
10.6
11.5
12.2
18.3
31.9
96.6
1416
F"
0.945
33.4
4.09
17.0
20.5
31.3
36.2
33.1
93.8
Fe
339
4.19
(0.0100)
(0,0100!
(0.0100)
(0.0100)
(0.0100)
0,202
0.339
K
221
186
261
250
553
1348
1901
4406
1.72E+Q4
Li
15,1
21.2
32.6
32.4
29-7
27,0
25,6
22-3
15.6
Mg
140
76.9
89.0
74,9
51.0
28,6
1.11
(0.00500)
(0.00500)
Mn
18.4
11.7
9,82
2,68
0.324
(0.00171)
(0,00171)
(0.00171)
(0.00171}
Mo
3.34
1.08
5.,52
33.2
34.9
37.0
3S.3
37.7
39,2
Report Date: 25-Jan-2017
page?
-------
EPA Method 1313 Sample; EaFA (P,l,l)
Release in mg/kj
Fraction
9
8
7
6
5
4
3
2
1
pH
2.08
3.85
SAO
6.99
7.97
9,26
10.4
12.0
13.1
Na
38.5
45.1
66.3
64,5
62.7
63.9
65.0
68=0
89.2
Mi
7.62
5,19
6,03
0.646
0,0910
(0.Q0365)
(0.00365)
(0.00365)
(0.00365)
NOj"
(0.0916)
(0.0916)
(0.0916)
(0.0916)
(0.0916)
(0.0916)
(0.0915)
0.582
11.4
NO,"
4,79 E+04
5839
949
9.16
7.55
7.57
6.12
6.57
6,68
P
24.2
0.629
(0.0185)
0.163
0.396
0.S54
0.430
0.372
2,09
Pb
2.57
0.0610
0.0150
0.00900
0.00700
(0.00115)
(0.00115)
(0.00115)
(0.00115)
PQ**
10.1
(0.118)
(0.118)
(0.118)
1.23
8.14
133
13.6
20.5
Re
0.0119
(0.00120)
(0.00120)
(0.00120)
(0.00120)
(0.00120)
0.0141
0.0223
0.0309
S
690
1039
1522
1638
1599
1631
1605
1621
1854
Sb
0.227
0.525
0.717
1.48
1.38
1.26
1.43
1.47
1.81
Se
5.46
0.841
2.30
9.22
16.4
40.1
43.2
56.0
§8,8
Si
722
180
61.7
14.3
5.35
2.78
7.20
37,6
306
Sn
{0.00350)
(0,00350)
(0.00350)
(0.00350)
(0.00350)
(0.00350)
(0.00350)
(0.00350)
(0.00350)
so42"
4263
4145
4011
4251
4214
4160
4130
4109
4298
Sr
55.6
30,7
30.9
25>4
23.0
21.0
19,6
16.4
9,16
Ti
15.0
0.0373
(0.0100)
(0.0100)
(0.0100)
(0.0100)
(0.0100)
(0.0100)
(0,0100)
II
2.56
0.940
0,322
0.101
0,0680
0.0350
0.0290
0,0290
0.0320
U
4.51
0.155
(0.00150)
(0.00150)
(0.00150)
(0.00150)
0.0107
0.0415
0.292
V
65.4
0.818
0.794
1,58
2.09
8.32
20.7
27.4
52.1
Zrs
16.3
11,6
11.4
(0.00500)
(0.00500)
(0.00500)
(0.00500)
(0.00500)
0.567
Report Date; 25-Jan-2017
pages
-------
EPA Method 1313 Sample: EaFA (P,l,l)
Interpolated Concentration in mg/L
Fraction
1
2
3
4
S
6
7
8
9
10
pH
2,00
4.00
5. SO
6.99
7.00
8.0®
9.00
10,5
12.0
13.0
At
12S
20,6
0.324
0.202
0,206
1.29
10.3
27.4
33.8
36,6
As
1.77
0.0835
0.0433
0.0784
0.07S1
0.203
0,455
1.05
1.05
7,64
B
3,23
3.92
4.35
4.62
4,62
4.38
4.48
4.65
5,05
9,10
83
0.921
0.225
0.279
0.260
0.260
0,261
0.480
0,904
0.915
0.682
Be
0.441
0.0963
0.00226
(0.000320)
(0,000320)
(0,000320}
(0.000320)
(0.000320)
(0.000320)
(0.000320)
Br'
10.00871}
0.670
0.675
0.515
0.516
0.600
0,678
0.655
0.724
0.816
Ca
141
142
167
155
155
134
116
S4.3
39,S
10.8
cd
0.0555
0.0414
0,0280
0.00580
0.00579
0.00470
0.00452
0-00463
0-00506
0.00536
cr
1,55
1,53
125
1.30
1.30
1.2S
1.30
1.26
1.32
3.71
Co
0,413
0.218
0.219
0.0261
0.0256
0.00419
0.00176
0.00115
0.000710
(0.000207)
Cr
1,96
0.0927
(0.000249)
0.0422
0.0427
0,136
0.201
0.250
0.30S
0.382
Cs
0.0642
0,0232
0.0169
0.0130
0.0130
0.0149
0.0179
0.0221
0.0283
0.0330
Cu
3,16
1.42
0.0670
0.000900
Q.OOG8S1
(0.000351)
{0.000351)
0.000931
0.00200
0.0142
D1C
0.137
0.150
0.146
(0.0650}
(0,0650)
(0.0650)
0.410
2.05
8.13
25,4
DOC
1.72
1.04
1,06
1.15
1,15
1.22
1,68
336
10.1
107
f
0.0804
2.73
0.447
1,70
1.70
2.07
2.87
3,63
3,97
8.55
Fe
33,9
0.234
(0.00100)
(0.00100)
(0,00100)
(0,00100)
(0,00100)
(0.00100)
0.0204
0.0321
K
22,3
19,2
26,0
25.0
25.2
56.5
113
197
451
1490
ti
1.48
2,21
3.26
3,24
3.24
2.95
2,75
2,54
2.22
1.62
Mg
14.0
7.80
8.81
7.43
7.46
5,03
3.22
0,0867
(0.000500)
(0.000500)
Mr?
1.84
1.15
0.905
0,268
0.262
0.0287
0.000492
(0.000171)
(0.000171)
(0.000171)
Mo
0.351
0.126
0.618
3.32
3,33
3,50
3.66
3.82
3.77
3.90
Report Date: 25-Jan-2017
page 9
-------
EPA Method 1313 Sample: EaFA (P,l,l)
Interpolated Concentration In mg/L
Fraction
i
2
3
4
5
6
7
8
9
JO
PH
2.00
4.00
5.50
6.99
7,00
8,00
9.00
10.5
12.0
13.0
Na
3,82
4.68
6.62
6.45
¦6.45
6.27
6.37
6.52
6,83
8.67
Ni
0.762
0.526
0.524
0.0646
0,0634
G.Q0844
(0.000365)
(0.000365)
(0.000365)
(0,000365)
NO,"
(0.00916)
(0.00916)
(0.00916)
(0.00916)
(0.00916)
(0.00916)
(0.00916)
(0.00916)
0.0613
0.831
N
-------
EPA Method 1313 Sample: EaFA (P,l,l)
Interpolated Release in mg/k|
Fractf&n
I
2
J
4
5
6
7
8
9
10
2.00
4.00
5.50
6.99
7,00
8.00
9.00
10.5
12.0
13.0
Al
1281
206
3,24
2.02
2.06
123
103
274
339
361
As
17.7
0.835
0.433
0.784
0.791
2.03
4,54
10.5
10.6
75.3
8
32.3
39.1
43,5
46,2
46.2
43.8
44.8
46.5
50,7
89,7
8a
9.22
2,25
2,79
2.60
2,60
2,61
4.30
9,04
S.18
6.72
Be
4,42
0,963
0.0226
(O.QO320)
(0.00320)
(0.00320)
(0.00320)
(0.00320)
(0.00321)
(0.00315)
Br"
(0.0872)
6,70
6,75
5.15
5.16
6.00
6.78
6,56
7.25
8.03
C3
1415
1419
1655
1551
1549
1345
1155
844
399
106
Cd
0.556
0.414
0,280
(3.0580
0,0579
0,0470
0.0462
0.0463
0.0507
0.0528
cr
16.5
153
12,5
13,0
13.0
12.8
13.0
12,6
13.3
36,5
Co
4,19
2.18
2=19
0.261
0.256
0.0419
0.0175
0.0116
0.00712
(0.00204)
Cr
19.6
0.327
(0.00248)
0,422
0.427
1.36
2.01
2,50
3.08
3.77
Cs
0,643
0,231
0.169
0.130
0.130
0.149
0.179
0,221
0,2S4
0,325
Cu
31,§
14.2
0.670
0,00300
0.00891
(0.00351)
(0.00350)
0,00932
0.0200
0.139
DIC
1,38
1.50
1,46
(0,650)
(0.650)
{0,650)
4.10
20,5
81.5
251
DOC
17.3
10.4
10.6
11.5
11.5
12,2
16,8
33.6
101
1052
r
0.805
27,3
4.47
17,0
17.0
20,7
28.7
36.3
39.8
84.3
Fe
339
2,34
(0.01000)
(0,0100)
(0.0100)
|0.0100)
(0.00999)
(0.0100)
0.204
0.316
K
223
192
250
250
252
565
1125
1975
4523
1.47E+04
Li
14.8
22.1
32,6
32.4
32.4
29.6
27.5
25.5
22.3
16.0
Mg
141
78.0
88,1
74,9
74,5
50.3
32.1
0.868
(0.00501)
(0.00493)
Mn
IS. 5
11.5
9,05
2.68
2.52
0,287
0,00492
(0,00171)
(0.00171)
(0.00168)
Mo
3.52
1.26
6,18
33,2
33.3
35,0
36.6
38.2
37.8
38.5
Report Date: 25-Jan~2017
page 11
-------
EPA Method 1313 Sample: EaFA (P,l,l)
Interpolated Release in mg/kj
Fraction
1
2
3
4
5
6
7
8
9
JO
PH
2.00
4.00
5.50
6.39
7.00
8.00
9.00
10.5
12.0
13.0
Na
33.3
46.8
66,2
64.5
64.5
62.7
63.7
65,2
68.5
35.4
Ni
7.63
5,26
5.24
0.646
0.634
0.0844
(0.00365)
(0.00365)
(0.00366)
(0.00360)
NO;,'
10.0917)
{0,0915}
(0,0915)
(0,0916)
(0.0916)
(0.0916)
(0.0915)
(0.0916)
0,615
8,19
NO,"
4.79E+04
4836
709
3.16
9.14
7.55
7,56
6.14
6,5-S
6.57
P
24.2
0.447
(0.0185)
0.163
0,165
0.403
0.731
0.427
0.385
1.72
Pb
2.57
0.0532
0,0145
0.00300
0.00898
0.00671
(0.00115)
(0.00115)
(0.00115)
(0,00113|
POi'
12.3
(0.118)
(0.113)
(0.118)
(0.118)
1.29
5.55
13.4
13,8
19.3
Re
0.0132
(0.00120)
(0.00120)
(0.00120)
(0.00120)
(0.00120)
(0.00120)
0,0144
0.0225
0.0294
s
678
1078
1525
1638
1637
1599
1624
1606
1629
1801
Sb
0.219
0,541
0.751
1.48
1,48
1.38
1.23
1.43
1.48
1.74
Se
5.95
0,327
2,51
9.22
9.28
16.7
33.4
43.6
56.3
66,3
SI
722
162
56.3
14.3
14.1
5.27
3.17
7.76
39,1
242
Sr>
{0.00350)
(0.00350)
(0.00350)
(0,00350)
(0.00350)
(0,00350)
(0.00350)
(0.00350)
(0.00351)
(0,00345)
SO/
4274
4130
4025
4251
4251
4213
4159
4180
4122
4214
Sr
55.7
30/7
30.5
25.4
25.4
22.9
21,4
19.5
16.3
9.53
II
15,0
0.0328
(0.01000)
(0.0100)
(0.0100)
(0.0100)
(0.00999)
(0.0100)
(0.0100)
(0.00985)
Tl
2,56
0.847
0.299
0.101
0,101
0.0670
0.0400
0,0290
0.0291
0,0312
U
4.52
0.0989
(0.00150)
(0.00150)
(0.00150)
(0.00150)
(0,00150)
0,0114
0.0431
0.234
¥
66.5
0,815
0.830
1.55
1.58
2.16
6.29
21.0
27.E
48.0
In
16.4
11,5
6.99
(0.00500)
(0.00500)
(0.00500)
(0.00500)
(Q.00500)
(0,00501)
0.340
Report Date: 25-Jan-2017
page 12
-------
EPA Method 1313
Sample; EaFA (P,l,l)
Assessment on interpolated values; available content on as measured values
Available Content From pH range {2,9,13}, on as measured values.
Scenario min pH 5.5
Scenario max pH 9
Reporting Limit (mg/L) Concentration {mg/L} Release (mg/kg} Available (mg/kg)
min
max
min
max
max at pH
mm
max
at p H
AS
0.00100
0.00100
0.202
10.3
9.00
2.02
103
1280
2.08
As
0.000640
0.000640
0.0433
0.455
9.00
0.433
4.54
96.9
13.1
B
0.00100
0.00100
4,38
4.95
5.50
43,8
49.5
97.7
13.1
Ba
0.00100
0.00100
0.260
0.480
9.00
2.60
4.80
8.76
2,OS
Be
0.000640
0.000640
(0.000320}
0.00226
5,50
(0.00320)
0.0226
4.41
2.08
Br"
0.0174
0.0174
0.515
0.678
9.00
5.15
6.78
8,27
13.1
Ca
0.00260
0.00260
11&
167
5.50
1155
1665
1413
2.08
Cd
0.000170
0,000170
0.00462
0.0280
5.50
0.0462
0.280
0.555
2.08
cr
0.00649
0.00649
1,25
1,30
6.99
12.5
13,0
41.9
13.1
Co
0.000414
0,000414
0.00176
0.219
5.50
0.0175
2,13
4.19
2.0S
Cr
0.000497
0.000497
(0.000249)
0,201
9.00
(0,00248)
2.01
13.6
2.,08
Cs
0.000430
0.000490
0.0130
0.0179
9.00
0.130
0,179
0.642
2,08
€u
0.000701
0.000701
(0.000351)
0.0670
5.50
(0,00350)
0,670
31,6
2.0S
D1C
0.130
0.130
(0.0650)
0.410
9.00
{0.850)
4.10
292
13,1
DOC
0.170
0.170
1.06
1.68
9.00
10.6
16,8
1416
13.1
F
0.00705
0.00705
0.447
2.87
9.00
4.47
28.7
93.S
13.1
Fe
0.00200
0.00200
(0.00100)
(o.ooioo)
5.50
(0.00539)
(0,0100)
339
2.OS
K
0.00160
0.00160
25,0
113
9,00
250
1126
785
5.67
Li
0.00190
0.00190
2.75
3.26
5,50
27.5
32.6
27.0
9.26
Mg
0.00100
0.00100
3.22
8,81
5,50
32.1
88.1
140
2.08
Mn
0.000342
0.000342
0,000492
0,905
5.50
0.00492
9.05
18.4
2.08
Mo
0,00120
0.00120
0.61S
3.66
9.00
6.18
36.6
39.2
13,1
Report Date: 25-Jan-2Q17
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
page 13
-------
EPA Method 1313
Sample; EaFA{P,l,l)
Assessment on interpolated values; available content on as measured values
Available Content From pH range (2,9,13), on as measured values.
Scenario min pH 5.5
Scenario max pH 9
Reporting Limit fmg/L) Concentration (mg/L) Release (mg/kg} Available (mg/kg)
mm
max
min
max
max at pH
mm
mm
at pH
Ns
0.00250
o nn?^n
6,27
6,62
5,50
62.7
66.2
89,2
13.1
HI
0,000730
0.000730
(0.000365}
0.524
5,50
(0.00365)
5,24
7,62
2.08
hg2
0,0183
i 1^
(0,00916)
(0,00916)
5,50
(0.0915)
(0.0916)
11.4
13.1
no3"
0.0258
0.0258
0.755
70.9
5.50
7,55
709
2.39E+04
5.67
p
0.00370
0.00370
(0.00185)
0.0731
9,00
{0.0185)
0.731
24,2
2.08
Pb
po/"
0,000230
0.000230
(0.000115)
0.00145
5,50
(0.00115)
0.0145
2.57
2.0B
0.0237
0.0237
(0.0118)
0.556
9.00
(0.118)
5.56
20.5
13.1
Re
0.000240
0.000240
(0.000120)
(0.000120}
5.50
(0,00120)
(0.00120)
0.0309
13.1
S
0.00680
0.00680
153
164
6,99
1529
1638
1854
13,1
sb
7.94E-05
7.94E-05
0.0751
0,148
6.99
0.751
1.48
1.81
13.1
Se
0,0150
0,0150
0.251
3.34
9,00
2,51
33.4
68.8
13,1
Si
0.00110
O.OO'llO
0.317
5.63
5.50
3.17
56.3
722
2,05
Sn
0,000700
0.000700
(0.000350)
(0,000350)
5,50
(0.00350)
(0.00350)
0.00350
13.1
so/
0.0208
0,0208
403
425
6.93
4025
4251
4293
13.1
Sr
0.00100
0.00100
2.14
3,05
5.50
21.4
30.5
55,6
2.08
I!
Q.G0200
0.00200
(0.00100)
(0.0010Q)
5.50
(0.00999)
(0.0100)
15,0
2.08
It
0.000510
0.000510
0.00400
0.0299
5,50
0.0400
0.299
2.56
2.08
U
0.000300
0.000300
(0.000150)
(0.000150)
5.50
(0.00150)
(0,00150)
4,51
2,08
V
0.00150
0.00150
0.0830
0.630
9.00
0,830
6.29
66,4
2.03
Zn
0.00100
0.00100
(0.000500)
0.699
5.50
(0.00500)
6.99
16.3
2.08
Report Date: 25-ian-2017
page 14
-------
EPA Method 1314
Analysis report according to EPA Method 1314
Created by LaachXS~. version 2.0.92 |18-Oct-2G16J
Report crested on 25-Jas>2017 3:00 PM
Material Information
Sample ID
Sample Name
Sample Replicate
Test Replicate
Category
Subcategory
Full Name
Description
Origin
Sample Database
EaFA
EafA
A
A
Coal Combustion
Fly Ash
Coal combustion fly ash from Facility £a
Fly Ash/Unit 1/Facility Ea
EPA LEAF Methods validation
C:\Users\User\Documents\LeachXS User Objects^
DATABASeS\lEAF Guide (16-Dec-2016).mdb
Test Parameters
Start Date
End Date
Eluate
Solids Content
Bed Length
Column Diameter
Bed Volume
As Tested Mass
Dry Mass
Temperature
Fiowrate
FSowrate
15-Jun-iO
23-Jun-10
0.3 mm
100 %
30,0 cm
4.80 cm
543 cm'
0,541 kg
0.541 kg
21.0 X
432 ml/day
0.798 L/Sperday
Report Date: 25~Jan-2Q17
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314
Legend
pH Acidity
E(h) Redox potential
K(25°C) Conductivity at 25 ®€
I L/S-dry Cumulative llquid-to-soiid ratio,, in L/kg
L/S-dry Liquid-to-solid ratio effraction, in l/kg
V Volume
IV Cumulative volume
IS}/A Not analyzed or measured
N/C Not calculated
Concentrations below the method detection limit (MDL) are reported between parentheses as half of the MDL.
Cumulative releases calculated with any concentration below the MDL are listed between parentheses.
Fraction Information
Fraction
Z L/S-dry
pH
m
K(2SXj
L/S-dry
V
IV
L/kg
mV
mS/cm
L/kg
ml
mi
1
0,208
4.20
HfA
6.55
0.208
112
112
2
0.511
4.86
N/A
2.21
0.303
164
276
3
1,06
6.01
M/A
2.04
0.549
297
573
4
1.56
6.76
N/A
2.04
0,503
272
845
5
2,11
7.07
N/A
1.50
0.551
298
1143
6
4,50
6.78
M/A
0.283
2.39
1290
2433
7
5..05
7.02
N/A
0.0649
0.549
297
2730
S
3,59
7,16
N/A
0.0564
4.55
2459
5188
3
10,2
7,59
N/A
0.0411
0.576
311
5500
Sample: EaFA (C,l,l)
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
page 2
-------
EPA Method 1314 Sample: EaFA (C,l,l)
Concentration in mi
Fraction
1
2
3
4
S
6
7
8
9
I L/S-diy
0,208
0.511
1,06
1,56
2.11
4.50
5.05
9.59
10.2
pH
4.10
4.86
6.01
6.76
7.07
6.78
7.02
7.16
7.59
M
30 7
2.50
0,627
0.102
0.155
1.74
1.94
2.56
2,63
As
1,07
0,0919
0,0235
0.0160
0,0268
0.195
0.650
2.32
2,37
B
157
12.8
5.39
2.89
1.95
0.901
0.572
0.381
0,252
Bs
1.43
0,541
0.347
0.232
0,329
1.42
2.24
1.33
0.938
Be
0.110
0.0334
0.00737
0,00283
(0.000320)
(0.000320]
(0,000320)
|0,000320)
(0.000320)
Br"
37.8
1.67
0.339
{0.00871}
(0.00871)
0.0552.
0.0595
0.0286
0.0211
Ca
SOI
733
706
661
484
79.5
12.9
9.75
8.20
Cd
1,42
0.0261
0,0190
0.0135
0.0114
0.00372
0.00147
0=000330
(8.50E-05)
cr
94.3
3.44
2,65
0.532
0.418
0.161
0,111
0,0639
0,0419
Co
8.01
0.0190
0.00820
0.00415
0.00399
0.000700
(0.000207)
(0.000207)
(0.000207)
Cr
5.32
0.0553
0.00111
10.000243}
0.000580
0.0163
0.0333
0.0525
0.0563
Cs
0.894
0,0132
0.00526
0.00322
0,.00227
0,00124
0.000382
0.000873
0.000730
Gu
23.9
0.571
0.0S63
0.0192
0.0128
0.00503
(0.000351)
(0.000351)
10.000351]
DSC
0.157
0.147
0.135
(6.5QE-05)
1.26
1,88
1,50
0.982
1,35
DOC
0,0686
1.53
1,47
0.958
0,385
2,88
1,21
1,08
1,24
F"
7,82
0,704
1,02
2.55
2,66
2.49
2,24
1.09
0.470
Fe
16.0
1.72
0,601
0.0241
(0.00100)
{0,00100}
(0.00100)
{0,00100}
(0.00100}
K
1609
15,4
5.29
3.15
2.15
0,312
0.582
0.483
0.442
LI
413
0,513'
0.220
0.143
0.143
0.0985
0.0667
0,0548
0.0470
Mg
247
6,95
3,06
0,942
0.326
0,0912
0,0523
0.0644
0.0891
Mn
30.8
0,258
0,160
0.0S99
0,0469
0,00830
0.00229
(0.000171)
(0.000171)
Mo
0.379
223
17.4
12.6
11.7
3.87
1.71
0.448
0.150
Report Date: 25-Jan--2017
page 3
-------
EPA Method 1314 Sample: EaFA (C,i,l}
Concentration In mi
Fraction
J
2
3
4
5
6
7
8
9
I l/S-dry
0.208
0.511
1.06
1.56
2.11
4.50
5.05
9.59
10.2
pH
4.20
4.86
6.91
6.76
7,07
6.78
7,02
7.16
7.59
Ma
129
0.928
0.394
0.270
0.290
0.430
0.541
0.333
0.243
Ni
23.4
0.0943
0.0462
0.0328
0.0163
(0,000355)
(0,000355)
(0.000365)
(0,000365)
NOj"
(0.00316)
(0.00915)
(0.00916)
(0,00916)
(0.00916)
(0.00915)
(0.00916)
(0.00916)
(0.00916)
NOj"
14.4
4,89
0.454
(0.0129)
(0.0129)
0,058-2
0.136
0.0478
0.0592
P
1.41
(0,00185)
(0.00185)
(0.00185)
(0.00185)
(0.00185)
(0.00185)
0.0759
0.145
Pb
0.0275
0,000313
(0.000115)
(0.000115)
(0.000115)
(0.000115)
(0.000115)
(0.000115)
(0.000115)
pot
(0.0118)
(0.0118)
(0.0123)
(0.0118)
(0.0118)
1.71
1.78
1,20
0,782
Re
(0,000120)
0.000272
0.000308
0.000545
0,000916
0.00255
0.00301
0.000787
0.000268
S
1754
554
544
518
357
53.6
2.80
1,53
1.07
Sb
0.0754
0.175
0.232
0,304
0,382
0.327
0.262
0.155
0.0965
Se
1,06
0.415
1.14
5.79
6.93
5.83
6.25
4.12
2.68
Si
41.7
5.39
3.35
2.32
1.13
0.511
0.435
0,538
0,600
Sri
0.00261
0.000799
(0.000350)
(0.000350)
(0.000350)
(0.000350}
(0.000350)
(Q.000350)
(0,000350)
so/"
3404
2008
1918
1314
1240
146
5.45
2,94
2.06
Sr
13.3
6.57
8.S5
8.41
6.17
1.60
0,517
0.303
0.244
Ti
0.273
(0.00100)
(0.00100)
(0,00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
T!
0.511
0.0201
0,00866
0,004-86
0.Q0331
(0.000255)
(0,000255)
(0.000255)
(0.000255)
U
0.221
0.00184
(0.000150)
(0,000150)
(0.000150)
(0.000150)
(0.000150)
|0.000150)
(0,000150)
V
0.538
0.173
0.118
0.0655
0.0952
1.47
2.22
2.32
2.75
2n
45.0
0.0922
0.0411
0,0600
0.0441
0.0275
0.0179
0.00840
0.00530
Report Date: 25-Jan-2017
page 4
-------
EPA Method 1314
Sample; EaFA {C,i,l}
Method Detection limit In mg/l
Fraction
I
2
3
4
5
6
7
8
9
I L/S-dry
0.208
0,511
1.06
1.56
2.11
4,50
5.05
9.59
10.2
PH
4.20
4.86
6.01
6,76
7.07
6,78
7.02
7.16
7.59
Al
Q.0010G
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
As
0,000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
B
0,00100
0,00100
0.00100
0.00100
0.00100
0.00100
0,00100
O.OOIOQ
0.00100
63
0,00100
0.00100
0.00100
0.00100
0.Q0100
0.00100
0,00100
0.00100
0.00100
Be
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
0,000640
Br"
0,0174
0.0174
0.0174
0.0174
0,0174
0.0174
0.0174
0.0174
0.0174
Ca
0.00260
0.00260
0.00260
0.00260
0.00260
0.00260
0.00260
0,00260
0.00260
Cd
0,000170
0.000170
0.000170
0.000170
0.000170
0,000170
0.000170
0.000170
0.000170
cr
0,00649
0,00649
0.00649
0.00649
0.00649
0.00649'
0.00649
0.00649
0.00649
Co
0.000414
Q„000414
0.000414
0.000414
0.000414
0.000414
0.000414
0.000414
0.000414
Cr
0.000497
0.000497
0.000497
0.000497
0.000497
0.000497
0.000497
0.000497
0.000497
Cs
0.000490
0.000490
0.000490
0.000490
0.000490
0.000490
0.000430
0.000490
0.000430
Cu
0.000701
0.000701
0.000701
0.000701
0.000701
0.000701
0,000701
0.000701
0.000701
DIC
0.000130
0.000130
0.000130
0,000130
0.000130
0.000130
0.000130
0.000130
0.000130
DOC
0.000170
0,000170
0.000.170
0.000170
0.000170
0.000170
0,000170
0.000170
0.000170
F*
0.00705
0.00705
0.00705
0.00705
0.00705
0,00705
0.00705
0,00705
0.00705
Fe
0,00200
0.00200
0.CK5200
0.00200
0.00200
0.00200
0.00200
Q.00200
0.00200
K
0.00160
0.00160
0.00180
0.00160
0.00160
0.00160
0.00160
0.00160
0.00160
ti
0.00190
0,00190
0.00190
0.00190
0.00190
0.00190
0.00190
0.00190
0.00190
M|
0.00100
0.00100
0.00100
0.00100
O.OOIOQ
0.00100
0.00100
0.00100
0.00100
Mr*
0,000342
0.000342
0.000342
0.000342
0,000342
0.000342
0.000342
0.000342
0.000342
Mo
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
Report Date: 25-ian-2017
page 5
-------
EPA Method 1314 Sample; EaFA (C,l,l)
Method Detection Limit in mg/L
Fraction
I
2
3
4
S
6
7
8
9
Z l/S-dry
0.208
0.511
1.06
1S6
1,11
4.50
5.05
9,59
10.2
P»
4,20
4.86
6.01
6.76
7.Q7
6.78
7.02
7.16
7.59
m
0-00250
0.00250
0.00250
0.00250
0.00250
0,00250
0.00250
0.00250
0.00250
m
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
HO{
0.0183
0,0183
0.0183
0.0183
0.0183
0,0183
0,0183
0.0183
0.0183
NOj"
0.0258
0.0258
0,0258
0.0258
0.0258
0.0258
0.0258
0,0258
0.0258
P
0,00370
0.00370
0.00370
0.00370
0.00370
0.00370
0.00370
0.00370
0,00370
Pb
0.000230
0,000230
0,00023-0
0.000230
0.000230
0,000230
0.000230
0.000230
0.000230
po/"
0,0237
0.0237
0.0237
0.0237
0.0237
0.0237
0.0237
0.0237
0.0237
Re
0.000240
0.000240
0.000240
0,000240
0.000240
0.000240
0.000240
0.000240
0.000240
S
0.00680
o.ooeso
0.00680
0.00580
0.00680
0,00680
0,00680
0.00680
0.00680
5b
7.94E-05
7.34E-05
7.94E-05
7.94E-05
7.94E-05
7.94E-05
7.S4E-Q5
7.94E-05
7.94E-05
Se
0,0150
0.0150
0,0150
0.0150
0.0150
0.0150
0.0150
0.0150
0,0150
Si
0.00110
0,00110
0.00110
0.00110
0,00110
0,00110
0.00110
0,00110
0.00110
Sn
0.000700
0.000700
0.000700
0.000700
0.000700
0,000700
0,000700
0.000700
0.000700
so/'
0,0208
0,0208
0,0208
0,0208
0.0203
0.0208
0.0208
0.0208
0.0208
Sf
0,00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0,00100
If
0,00200
0.00200
0.00200
0.00200
0.00200
0.00200
0.00200
0,00200
0.00200
Ti
0.000510
0,000510
0.000510
0.000510
0,000510
0,000510
0,000510
0.000510
0.000510
U
0.000300
0,000300
0.000300
0.000300
0.000300
0.000300
0.000300
0.000300
0.000300
V
0.00150
0.00150
0.00150
0.00150
0.00150
0,00150
0.00150
0.00150
0.00150
Zft
0,00100
0.00100
0.00100
0.00100
0.00100
0,00100
0.00100
0.00100
0.00100
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
page6
-------
EPA Method 1314
Sample: EaFA(C,l,l)
Cumulative Release in mi
Fraction
1
2
3
4
S
6
7
8
P
I L/S-dff
0,208
Q.S11
1.06
1.56
2.11
4. SO
5.05
9.59
10.2
pH
4.10
4.86
6.01
6,76
7.07
§.78
7.02
7.16
7,59
Al
53,7
64.5
64.8
64.3
65.0
69.1
70.2
81.8
83.3
As
0.221
0.249
0,262
0,270
0.285
0,751
1,11
11.6
13,0
B
32.7
36.5
39.5
40,5
42.0
44,2
44.5
46,2
46.4
Ba
0,297
0,461
0,651
0.768
0.949
4.34
5.56
11.6
12.2
Be
0.0223
0,0330
0.0373
0.0388
(0.0389)
(0.0397)
{0.0399)
(0.0413)
10.0415}
Br"
7.85
8.36
8.55
(8.55)
(8-55)
(8.69)
(8.72)
(8-85}
(8,86]
Ca
104
326
714
1046
1313
1503
1510
1554
1559
cd
0.295
0.303
0.314
0.320
0.327
0.336
0.336
0,338
(0.338)
CI"
19.6
20.7
22.1
22.4
22.6
23.0
23.0
23,3
23,4
Co
1.66
1,67
1.68
1.68
1.68
1,68
(lv6S)
(1.68)
(1,68)
Cr
1,11
1.13
L13
(1,13)
[1.131
(1.17]
(liS)
(1,42)
(1.46)
Cs
0.186
0,19-0
0.193
0.194
0,196
0.199
0.199
0.203
0.203
Cu
4.97
5.14
5.19
5.20
5,20
5.22
|5.22)
{5,22)
(5,221
DSC
0.0326
0.0770
0,151
(0.151)
(0.848)
(5.33)
(6.15)
(10.6)
(11,4)
DOC
0,0143
0,478
1.28
1.76
2.25
9.12
3,78
14.7
15,4
F"
1.63
1.84
2,40
3.68
5,15
11.1
12.3
17.3
17.5
Fe
3.32
3.84
4,17
4.18
(4,181
(4-iai
(4.18}
(4.131
(4,19)
K
335
339
342
344
345
347
347
350
350
LI
8.58
8.73
8.85
8.93
9.00
9,24
9.28
9,52
9,55
Mg
51.4
53.5
55,2
55.7
55.9
56,1
56.1
56,4
56,5
Mn
6.41
6,49
ass
6.62
6,65
6.67
6.67
(6.67}
(6.67]
Mo
0.0787
5,83
16.4
22,7
29.2
38.4
39.4
41.4
41.5
Report Date: 25-Jan--2017
page 7
-------
EPA Method 1314
Sample: EaFA{C,l,l}
Cumulative Release In mi
Fraction
I
2
3
4
5
6
7
8
9
ZL/S-dty
0.208
0.511
1.06
1.56
2.11
4,50
5.05
9.59
10.2
pw
4,28
4.86
6.01
6.76
7.07
6.78
7.02
7.16
7.59
m
26.9
27,2
27.4
27,5
27.7
28.7
29.0
30.5
30,7
Ni
4.87
4.89
4,92
4.94
4.95
(4.95)
(4-35)
14.95}
(4,35)
NOj'
(0.00190)
(0.00468)
(0.00970)
(0.0143)
(0.0194)
(0.0412)
(0.0462)
(0.0878)
(0.0931)
m5
3.00
4.48
4,73
(4-73)
(4.74)
(4.88)
(4.95)
(5.17)
(5.20)
p
0.233
(0.293)
(0.234}
(0.295)
(0,296)
(0,301)
(0.302)
(0,647)
(0.730)
Pb
0,00572
0.00581
(0.0058S)
(0.00593)
(0.00600)
(0.00627)
(0.00633)
(0.00685)
(0,00692)
PO/'
(0,00246)
{0,00604}
(0.0125)
(0.0185)
(0.0250)
(4,111
(5.09)
110,6)
(11,0)
Re
(2.50E-05}
(0.000107)
(0.000276)
(0.000551)
(0.00106)
(0.00714)
(0.00379)
(0.0124)
(0.0125)
S
365
532
831
1091
1288
1416
1417
1424
1425
Sb
0.0157
0.0688
0.156
0.349
0,559
1.34
1,43
2.19
2,24
Se
0,221
0.346
0.973
3.S9
7.71
21.6
25.0
43.8
45.3
8.67
10.3
12,1
13.3
13.9
15.4
15,6
18.1
18.4
sn
0.000543
0.0007S5
(0,000977)
(0.00115}
(0.00135)
(0.00218)
(0,00237)
(0.00396)
(0.00417)
so/"
1955
2564
3616
4529
5212
5561
5564
5578
5579
ST
2.77
4.76
3,62
13.9
17.3
21.1
21.4
22.7
22,9
Ti
0,0567
(0.0570)
(0.0576)
(0.0581)
(0.0586)
(0,0610)
(0.0616)
(0.0661)
(0.0667)
IS
0.106
0.112
0,117
0.120
0.121
(0.122)
(0.122)
(0.123)
(0.123)
u
0.0460
0.0465
(0.0466)
(0.0467)
(0.0468)
(0.0471)
(0.0472)
(0.0479)
(0.0480)
V
0.112
0.154
0.229
0.262
0.314
3.81
5.03
15,6
17.2
in
9.36
9,39
9.41
9.44
9.46
9,53
9.54
9.58
3.5S
Report Date: 25-Jan-2017
page
-------
EPA Method 1314
Assessment
Concentration (mg/L) Cumulative Release
max
atpN at Zt
./S-cfry
at I 1/5=10,2 (mg/kg)
At
307
4.20
0.208
83.3
As
2/37
7,59
10.2
13.0
B
157
4.20
0,208
46.4
Ba
2,24
7,02
5.05
12.2
Be
0.110
4.20
0.208
{O.0415I
Br"
37,8
4.20
0.208
{8.86)
Ca
733
4.86
0,511
1559
ed
1.42
4,20
0.20S
(0.338)
cr
94.3
4.20
0.208
23.4
Co
8.01
4.20
0.20S
(1.68)
Cr
5.32
4.20
0.20S
(1-46)
Cs
0,894
4.20
0.208
0.203
C.y
23.9
4,20
0.203
(5.22)
DC
1,88
6.78
4.50
(11.4)
DOC
2.88
6.78
4,50
15,4
F"
7.82
4.20
0.208
17.5
Fe
16.0
4.20
0.208
(4-19)
K
1609
4.20
0.208
350
Li
41.3
4.20
0,208
9.55
Mg
247
4.20
0.20S
56.5
Mil
30.8
4.20
0.208
(6-67)
22.3
4.86
0.511
41.5
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314
Assessment
Concentration (mg/L)
mux at pH at H
/S-dry
Cumulative Release
at 11/5=20.2 (mg/kg)
Na
123
4,20
0.208
30.7
Ni
23,4
4.20
0.208
{4,95)
NO,'
{0.00916}
4.20
0.208
(0,0931)
NOj"
144
4.20
0.208
(S.20)
P
1,41
4.20
0.208
{0.730)
Pb
0,0275
4.20
0.208
(0,00692)
PQa3"
1.78
7.02
5.05
(11.0)
Re
0.00301
7.02
5.05
(0,0125)
S
1754
4.20
0.208
1425
5b
0.382
7.07
2.11
2.24
Se
6,93
7.07
2.11
45.3
Ss
41,7
4.20
0.208
18,4
Sn
0.00261
4.20
0,208
(0.00417)
so/"
9404
4.20
0.208
5579
Sf
13,3
4.20
0.20S
22.9
Ti
0,273
4,20
0.2G8
(0,0567)
II
0,511
4.20
0.208
(0.123)
U
0.221
4,20
0,208
(0.04S0)
V
2.75
7.59
10.2
17,2
Zrc
45.0
4.20
0.208
9.58
Report Date: 25-Jan-2G17
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append ¦
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Analysis report according to EPA Method 1316
Crested bv LeachXS"", version 2.0.92 (18rOcr-2Q16)
Report created on 25-Jan-2017 3m PM
Material Information
Sample ID EaFA
Sample Name EafA
Sample Replicate A
Test Replicate A
Category Coal Combustion
Subcategory Fly Ash
Full Name EaFA
Description Fly Ash / Unit 1 / Facility Ea
Origin EPA LEAF Methods validation
Sample Database C:\Users\User\Documertts\LeachX5 User Objects\
DATA BASE S\LE A F Guide {16-Dec-2016).mrib
Test Parameters
Start Date 28-Apr-iO
End Date 29-Apr-10
Particle Size 0.3 mm
Contact Interval 24,0 h
Solids Content 100 %
Temperature 21.0 X
Report Date: 25-Jan-201?
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Sample: EaFA-Ref (B,l,l)
Legend
pH Acidity
E(h) Redox potential
fC|25aCf Conductivity at 25 X
L/S-dry Liquid-to-solid ratio, in L/kg
M Mass, as tested
V Volume of eluant
Total V Tcta^ iiquid volume
N/A Not analyzed or measured
N/C Not calculated
Concentrations below the method detection limit {MDL) are reported between parentheses as half of the MDL,
Fraction Information
Fraction
n
L/S-dry
pH
m
K(2S*C)
M
¥
Total ¥
L/kq
mV
mS/cm
q
ml
mL
4
1,00
7,00
N/A
3.99
100
100
100
3
2.0Q
6.68
N/A
6.61
50,0
100
100
2
5.00
5.53
N/A
3,96
40.0
200
200
1
10.0
6.99
N/A
2.71
40,0
400
400
Report Date: 25-Jan-2017
page 2
-------
EPA Method 1316
Sample: EaFA-Ref (B,l,l}
Concentration In mj
Fraction
4
3
2
J
l/5-tlry
1.00
2,00
5,00
10.0
m
7,09
6.68
6,59
6,99
Al
0,431
0.279
0.186
0.202
As
0.186
0,221
0.172
0.0784
B
37,6
18,2
8,16
4.62
8 3
0.179
0.195
0.182
0.260
Be
(0,000320)
p
1
(0.000320)
0.00872
Br"
9.72
4,59
2.06
1.14
Ca
446
645
294
155
Ctf
0.0231
0,0162
0,00696
0.00933
cr
23.0
15.2
6.13
1.39
Co
0.108
0.181
0.0779
0.0293
Cr
0,0259
0,0160
0.0139
0.0422
Cs
0,104
0.0618
0.0277
0.00636
Cu
0.0267
0.0207
0.0139
0.00342
0!C
0.861
0.455
0.217
(0.0650)
DOC
338
2.19
1,20
1.05
F*
38-8
35.7
23.9
6.34
Fe
(0.00100)
{0.00100}
10.00100)
(0.00100)
K
202
104
42.S
25.0
U
33.5
15.4
6.70
3.24
M|
54,4
30,6
12,9
7.49
Mn
1.62
1.50
0.683
0.268
Mo
27,6
13,0
6.37
3.32
Report Date: 25-Jan-2G17
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append ¦
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
page 3
-------
EPA Method 1316
Concentration In mi
Fraction
4
3
2
1
L/S-dry
LOO
2.00
5.00
10.0
PH
7,09
6.68
6.59
6.99
m
5S.9
28.2
11.3
6.45
Ni
0351
0,429
0,186
0.0646
NOj'
(0.00916;
{0.00916}
(0.00916)
(0,00916)
no5"
9.56
5=57
2.53
0.806
p
0,0617
0,0571
0.0413
0.0163
Pb
0.0247
{0.000115)
(0.000115)
(0.000115)
PO/'
0.3S4
0.516
0354
0.251
Re
0.000257
(0.000120)
(0.000120)
(0.000120)
S
773
684
309
164
Sb
0.544
0.496
0.340
0.167
Se
1.78
1.40
1.24
0.922
2,62
2.79
2.69
1.43
sn
(0,000350)
(0.000350)
(0.000350)
(0.000350)
so/"
3543
3861
1421
589
ST
6.74
7.22
3.69
2.54
Ti
(0.00100)
(0.00100)
(0.00100)
(0.00100)
IS
0.0336
0.0266
0.0142
0,0208
u
0.00635
0,00131
(Q.000150)
(0.000150)
V
0,401
0347
0.316
0.158
in
0,0923
0.0971
0.0220
(0.000500)
Report Date: 25-Jan-2017
-------
EPA Method 1316
Method Detection Limit in mg/l
Fraction
4
3
2
1
L/S-Ctty
LOO
2.00
5.00
10.0
pfi
7,09
6.68
6.59
6.99
Ai
0.00100
0,00100
0.00100
0.00100
As
0.000640
0.000640
0.000640
0.000640
B
0,00100
0.00100
0,00100
0.00100
8a
0,00100
0.00100
0,00100
0.00100
Be
0,000640
0.000640
0.000640
0.000640
Br'
0,0174
0,0174
0.0174
0.0174
Ca
0.00260
0.00260
0.00260
0,00260
C d
0,000170
0.000170
0.000170
0.000170
cr
0.00649
0.00649
0.00649
0.00649
Co
0.000414
0.,000414
0,000414
0,000414
Cf
0.000497
0.000497
0.000437
0.000497
Cs
0.000490
0.000490
0.000430
0.000490
Cu
0.000701
0.000701
0.000701
0.000701
DIC
0,130
0.130
0.130
0.130
DOC
0,170
0.170
0.170
0.170
F"
0.00705
0.00705
0.00705
0.00705
Fe
0.00200
0.00200
0.00200
0.00200
K
0.00160
0.00160
0,00160
0.00160
Li
0.00190
0.00190
0.00190
0.00190
Mg
0.00100
0.00100
0.00100
0.00100
Mn
0.000342
0.000342
0.000342
0.000342
Mo
0.00120
0.00120
0.00120
0.00120
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Sample; EaFA-Ref (6,1,1}
Method Detection limit In mg/L
Fraction
4
3
2
i
L/S-dry
IMG
2.00
5.00
10.0
pH
7,09
6.68
6.59
6.99
m.
0.00250
0,00250
0.00250
. ..:=o
Ni
0.000730
0.000730
0.000730
£ C00730
no;
0,0183
0.0183:
0.0183
0,0183
no3"
0.0258
0.025S
0.0258
0.0258
p
0,00370
0.00370
0.00370
0.00370
Pb
0.000230
0.000230
0.000230
0.000230
P04*
0,0237
0.0237
0.0237
0:0237
Re
0.000240
0.000240
0.000240
0.000240
S
0.00680
0.00680
0.00680
0.00630
Sb
7.94E-05
7.S4E-05
7.94E-05
7.94E-05
Se
0.0150
0.0150
0.0150
0.0150
SI
0,00110
0.00110
0.00110
0.00110
O.0OO7QO
0.000700
0.000700
0.000700
so/"
9.0208
0.0208
0.0208
0.0208
Sr
0.00100
0.00100
0,00100
0.00100
Ti
0.00200
0.00200
0,00200
0.00200
Tl
0.000510
0.000510
0.000510
0.000510
U
Q.O0Q3OO
0.000300
0.000300
0.000300
V
0.00150
0.00150
0.00150
0.00150
Zn
0,00100
0.00100
0,00100
0,00100
Report Date: 25-ian-2017
page 6
-------
EPA Method 1316
Release in m\
Fraction
4
3
2
1
L/S-dry
LOO
2.00
5M
10.0
7,00
6.68
6,59
6.99
Ai
0.431
0,558
0,929
2.02
As
0,186
0,443
0.860
0.734
B
37.6
36.4
40.8
46.2
Ba
0,179
0.391
0.910
2.60
Be
0,000320
0.000640
0.00150
0.0872
Br*
9J2
9.19
10,3
11,4
Ca
446
1290
1470
1551
Cd
0.0231
0.0324
0.0348
0,0933
cr
23.0
30.5
30.6
13.9
Co
0.108
0.362
0.390
0.293
Cr
0.0259
0.0320
0.0695
0.422
Cs
0.104
0.124
0.139
0.0636
Cu
0.0257
0.0415
0,0697
0.0342
DIC
0.S61
0.310
1.09
0.550
DOC
3,38
4.38
6.00
10.5
F"
38,8
71.4
119
69,4
Fe
0,00100
0.00200
0.00500
0.0100
K
202
208
214
250
ti
33.6
30.8
33.5
32.4
Mg
54,4
61.2
64.3
74.3
Mn
1.62
3,01
3.42
2.56
Mo
27,6
26.0
31.8
33.2
Report Date: 25-Jan-2017
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Release In mj
Fraction
4
3
2
J
t/S-dry
1,00
2.00
5,00
10.0
P"
7,00
6.68
6.59
6,99
Na
59,9
56.5
56.5
64.5
Ni
0351
0.858
0.931
0.646
no;
0.00916
0.0183
0.0458
0.0316
NO,"
9,56
11.1
12.6
8,06
P
0.0617
0,114
0.207
0.163
Pb
0,0247
0.000230
0.000575
0.00115
PQi"
0.384
1,03
1.77
2.51
Re
0.000257
0.000240
0.00-0600
0.00120
S
773
1367
1543
1638
Sb
0.644
0.392
1.70
1.67
Se
1.78
2.80
6.22
3.22
Si
2,62
5,58
13,5
14.3
Sn
0,000350
0.000700
0,00175
0.00350
so/"
3948
7721
7106
5SS6
Sr
6.74
14.4
18,4
25.4
Ti
0,00100
0,00200
0.00500
0.0100
IS
0.0336
0,0532
0.0710
0,208
U
0.00635
0.00262
0.000750
0,00150
V
0.401
0.694
1.58
1,58
In
0.0923
0.194
0,110
0,00500
Report Date: 25~Jan-2Q17
Leaching Environmental Assessment Framework (LEAF) How-To Guide Append"-
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
0.001 I ' 11 I ' 11 I 11 1 I ' 11 I ' 11 I 11 'I ' 11 I
0 2 4 6 8 10 12 14
PH
0.001
0.0001
0.001
0.001
0.0001
0.001
0.0001
0 2 4 6 8
PH
0.0001
0 2 4
—•— CaFA_1313 ~ CaFA_1313 (Interpolated) —A— CaFA_1314 --O- CaFA_1316
Figure B-ll. Method 1313 results for a high-carbon coal fly ash (CaFA):
Titration curve, antimony, arsenic, barium, boron and cadmium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
100
oi
E
E
3
E
o
!_
£
u
0.1
0.0001
1
1
1
1
/]_ DW
i—^ I
(3—-U j
? i
_J LLOQ
j MDL
PH
10
12
14
10
1 -r
CI
E
"D
O
u
0.01
0.001
¦ DW \
™ ^ *
! LLOQ Y
'J—
1 ' 1 i 1 1 1 i 1 1 1 I ¦ ¦ ¦ ¦
10
12
14
PH
CI
E
E
3
C
u
"D
£
O
Z
100
10
1
0.1
0.01
0.001
CI
E
E
.3
"E
_0)
"3
(/>
10
0.1
0.01
0.001
0.0001
0.0001
0 2
CI
E
E
3
« 0.01
DW
0.001
0
2
4
6
8
10
12
14
PH
—CaFA_1313 ~ CaFA_1313 (Interpolated) —CaFA_1314 -«t>- CaFA_1316
Figure B-12. Method 1313 results for a high-carbon coal fly ash (CaFA):
Chromium, lead, molybdenum, selenium and thallium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
11
0.1
Ol
E
>
c
o
E
4-1
c
<
0.01
0.001
0.01 -
0.001
4 6
L/S (L/kg-dry)
10
LLOQ
¦ DW
MDL
AA AAA A
0 2 4 6 J
10
L/S (L/kg-dry)
0.0001
4 6
L/S (L/kg-dry)
CaFA_1313 ~ CaFA_1313 (Interpolated)
¦o
Ol
Ol
E
0.01 -
0.001
0.0001
¦o
Ol
a
~oi
E
0.01 -
0.001 -
0.0001
•CaFA 1314
4 6
L/S (L/kg-dry)
4 6
L/S (L/kg-dry)
CaFA 1316
Figure B-13. Method 1314 results for a low-carbon coal fly ash (CaFA):
Eluate pH, antimony and arsenic.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
B-46
-------
0.01
0.001
0.0001
100
10
1
0.1
0.01
0.001
0.0001
oi 0.01
s
£
_3
¦I 0.001
<0
u
1000
0.001
0.0001
4 6
L/S (L/kg-dry)
4 6
L/S (L/kg-dry)
0 2 4 6 8 10
L/S (L/kg-dry)
0 2 4 6 8 10
L/S (L/kg-dry)
1000
O)
"5
E
100
0.0001
0 2 4 6 8 10
L/S (L/kg-dry)
0.00001
0 2
4 6 8 10
L/S (L/kg-dry)
—•— CaFA_1313 ~ CaFA_1313 (Interpolated) —A— CaFA_1314 --O- CaFA_1316
Figure B-14. Method 1314 results for a low-carbon coal fly ash (CaFA):
Barium, boron and cadmium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
CI
E
E
3
'i
s
u
0.0001
0.01
0.001
4 6
L/S (L/kg-dry)
¦o
O)
Jd
~oi
E
u
0.01 -r
0.001
4 6
L/S (L/kg-dry)
Ol
E
"O
O
u
0.01
0.001
4 6
L/S (L/kg-dry)
0.01 -
¦o
oi
oi
E
» 0.001
0.0001
4 6
L/S (L/kg-dry)
Ol
E
E
3
C
<0
•a
.a
o
Z
0.1 -
0.0001
100
0.01
0.001
¦o
Ol
a
Ol
s
4 6
L/S (L/kg-dry)
CaFA_1313 ~ CaFA_1313 (Interpolated)
4 6
L/S (L/kg-dry)
•CaFA 1314
CaFA 1316
Figure B-15. Method 1314 results for a low-carbon coal fly ash (CaFA):
Chromium, lead and molybdenum.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
B-48
-------
10
0.1
0.01
0.001
LLOQ
"MOt
0.0001
0 2 4 6 8 10
L/S (L/kg-dry)
2 4 6 8 10
L/S (L/kg-dry)
10
¦a
CI
CI
E
« ; 3 o.ooi
£ "3
DC
H
0.001 I ' 11 I ' 11 I ' 11 I ' 11 I ' 11 I1 0.0001
02468 10 0246
L/S (L/kg-dry) L/S (L/kg-dry)
—•— CaFA_1313 ~ CaFA_1313 (Interpolated) —A— CaFA_1314 --O- CaFA_1316
Figure B-16. Method 1314 results for a low-carbon coal fly ash (CaFA):
Selenium and thallium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
13
12.5 -¦
12 -¦
11.5 -¦
11
4 6
L/S (L/kg-dry)
10
oi
E
>
c
o
E
4-1
c
<
0.01
0.001
4 6
L/S (L/kg-dry)
¦o
CI
CI
E
0.01 -
0.001
4 6
L/S (L/kg-dry)
0.001
0.0001
0.1
"DW#^'
0.01
4 6
L/S (L/kg-dry)
LLOQ
MDL
10
¦c
CI
a
"oi
E
0.1 -
0.01
4 6
L/S (L/kg-dry)
CaFA_1313 ~ CaFA_1313 (Interpolated)
•CaFA 1314
CaFA 1316
Figure B-17. Method 1316 results for a high-carbon coal fly ash (CaFA):
Eluate pH, antimony and arsenic.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
10
1
0.1
0.01
0.001
0.0001
100
4 #-
~DW—
10
1 "f
0.1 -t
0.01
0.001
0.0001
0
CI
E
E
3
'i
"C
<0
U
0.1
0.01
0.001 T
0.0001
4 6
L/S (L/kg-dry)
4 6
L/S (L/kg-dry)
V-
4 6
L/S (L/kg-dry)
LLOQ
MDL
100
DW
LLOQ
MDL
10
DW
LLOQ
MDL
10
at
CI
E
1000
¦o
ci
a
CI
S
100 -
4 6
L/S (L/kg-dry)
4 6
L/S (L/kg-dry)
&
¦c
CI
a
"ci
E
» 0.01
0.001
4 6
L/S (L/kg-dry)
CaFA_1313 ~ CaFA_1313 (Interpolated)
•CaFA 1314
CaFA 1316
Figure B-18. Method 1316 results for a high-carbon coal fly ash (CaFA):
Barium, boron and cadmium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
10
10
oi
E
E
3
E
o
!_
£
u
1
0.1
0.01 -fe
0.001
0.0001
DW
LLOQ
MDL
4 6
L/S (L/kg-dry)
10
1 - =
CI
£ 0.1 ^
E
3
"i o.oi -k
o
u
0.001
0.0001
DW
LLOQ
MDL
4 6
L/S (L/kg-dry)
10
0.1
Ol
E
"O
o
a
0.01
0.001
100
'
"o
N
\
DW
X
S
LLOQ
/
/
/
/
7—
i
MDL
0 2 4 6
8 10
L/S (L/kg-dry)
oi
E
E
3
C
<0
"U
A
>¦
o
Z
0.01
0.001 -fe
0.0001
'
:
- O
— ¦ — ¦ — —
DW
LLOQ
MDL
' 11 1 ' 11 1 ' 11 1 ' 11 1 ' 11 1
0
4 6
L/S (L/kg-dry)
10
&
¦o
Ol
"oi
E
0.01
100
4 6
L/S (L/kg-dry)
¦o
Ol
a
Ol
E
4 6
L/S (L/kg-dry)
CaFA_1313 ~ CaFA_1313 (Interpolated)
•CaFA 1314
CaFA 1316
Figure B-19. Method 1316 results for a high-carbon coal fly ash (CaFA):
Chromium, lead and molybdenum.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
1
10
0.1
0.01
0.001
0.0001
<#-
4 6
L/S (L/kg-dry)
DW
LLOQ
MDLl
10
¦c
CI
CI
E
1
0.1
4 6
L/S (L/kg-dry)
10
0.1
CI
E
£
_~
To
0.01
0.001
LLOQ
MDL
o - -
o—
--O
DW
' 11 1 ' 11 1 ' 11 1 ' 11 1 ' 11 1
4 6
L/S (L/kg-dry)
10
¦c
CI
a
~ci
E
0.01 -
0.001
4 6
L/S (L/kg-dry)
CaFA_1313 ~ CaFA_1313 (Interpolated)
•CaFA 1314
CaFA 1316
Figure B-20. Method 1316 results for a high-carbon coal fly ash (CaFA):
Selenium and thallium.
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313
Sample: CaFA (P,1,1}
Analysis report according to EPA Method 1313
Created by LeaebXS™, version 2-0.92 (18-0tt-2016[
Report created on Z5-Jar>-20I7 2:45 PM
Material Information
Sample ID CaFA (P,l,l}
Sample Name CaFA
Sample Replicate A
Test Replicate A
Category Coal Combustion
Subcategory Ffy Ash
Full Name CaFA
Description Coai combustion fly ash from Facility Ca
Origin EPA LEAF Methods validation
Sample Database C:\Users\User\Documents\LeachX5 User Objects\
DATABASES\LEAF Guide (16-Dec-20i6).mdb
Test Parameters
Start Date 19-Apr-10
End Date 20-Apr-lQ
Pi*"1"'* r::= 0.3 mm
Conta 24.0 h
SoSit - t 100 %
Legend
pH
Acidity
V(acid)
Volume of added acid
m
Redox potential
[acid}
Concentration of added acid
K(25X}
Conductivity at 25 "C
V(base}
Volume of added base
L/S-dry
Liquid-to-solid ratio
[base]
Concentration of added base
M
Dry mass
[H30+]
Add neutralization capacity
V
Volume Di water
(OH-}
Base neutralization capacity
Total V
Total liquid volume
N/A
Not analyzed or measured
N/C
Not calculated
Concentrations below the method dectection limit (MDL) are reported between parentheses as half of the MDL
Report Date: 25-Jan-2017 page 1
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313
Sample: CaFA (P,l,l)
Fraction Information
0
pH
m
K(25X)
L/S-dry
M
V
Total V
mV
mS/cm
L/kq
kqdrv
ml
ml
1
2.01
295
89,8
10.0
0.O4QG
310
400
2
3.96
180
15,5
10.0
0.0400
381
400
3
5.54
B6.4
17,2
10.0
0.0400
387
400
4
6.54
21.3
12.7
10.0
0.0400
387
400
5
9.15
-127
12.4
10.0
0.0400
391
400
6
10.9
-231
9.44
10,0
0.0400
394
400
7
12.0
-296
7.54
10,0
0.0400
400
400
8
13.2
-367
99.9
14.2
0.0400
484
568
Titration Information
Fraction pH V(acid} [acid] V{base) [basej [H30*J [OH]
mi moi/L mol/kg dn
n
P"
V(acid)
ml
[odd]
mof/L
1
2.01
90.0
2.00
2
3.95
19.0
2.00
3
5.54
13.5
2,,00
4
6,64
13.0
2.00
5
9.15
9.00
2.00
6
10.9
6.10
2.00
7
12.0
8
13.2
4.50
0.950
0,675
0.650
0,450
0,305
84,0 1.00 2.10
Report Date; 25-Jan-2017
page 2
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313 Sample: CaFA (P, 1,1}
Concentration in mg/l
Fraction
1
2
3
4
5
6
7
8
pH
2.01
3.96
5,54
6.64
9.15
10.9
12.0
13,2
M
1583
96.7
0.0419
0=0693
0.0163
1.86
3.01
1.12
As
4,.90
0.875
0.0603
0.0456
0.101
0.0630
0.0337
0=151
B
63.0
50.3
43.7
41.8
33.7
27.8
17.6
11.1
8a
8,25
2.88
1.45
1.38
0.630
1.69
2,73
5,08
Be
0.580
0,119
0.00301
0,00301
0.00301
0.00301
0,00301
0.00301
Br"
(0,160}
(0.160)
(0,160)
(0.160)
(0.160)
(0.160)
(0.160)
(0.160)
Ca
3537
1784
1356
1318
1065
865
318
97,6
Cd
0.210
0,162
0.106
0.0940
0.00339
0.00341
0.00343
0.00412
cr
{2-07}
(2.07)
(2.07)
(2-07}
(2.07|
(2-07)
{2.07}
12,07}
Co
131
0.402
0.222
0.204
0,00574
0.00206
0.00206
0.00206
co/"
0.225
0.278
0.339
0.356
0.365
0.383
0.481
0.408
Cr
9.41
0.761
0,00563
0,0348
0.0406
0,0511
0.626
0.874
Cs
0.0334
0.00477
0.00477
0.00477
0.00477
0.00477
0.00477
0.00477
Cu
9.72
2.41
0.0288
0.0164
0.00350
0.00350
0.00350
0.0151
DIC
3,25
0.932
2.84
1.40
3.89
1.68
0.742
6.21
DOC
6.66
5.84
5.41
4.03
1.06
1.50
1.69
5=42
Fe
318
19.5
(0.00145)
(0.00145)
(0.00145)
(0,00145)
(0.00145)
(0.00145)
r
{0.000500)
0.00364
(0.000500}
(0.000500)
0.00230
0.00249
(0.000500)
10.000500)
Hg
1.3GE-05
3.40E-Q5
(3.00E-06)
9.00E-06
(3.00E-06)
(3.00E-06)
(3.00E-06)
(3.00E-06)
K
32.8
6.12
4.85
4.S7
3.85
3.16
2,02
1556
Mg
260
91.1
58.5
56.1
31,7
1.31
(0.000500)
(0.000500)
Mn
56.1
21.6
15.7
14.3
0.4-35
0,00924
0.004S3
0,0360
Mo
3.73
0.644
1.10
1.2.S
1,94
1.87
1.99
2,24
Report Date: 25-Jan-2017
page 3
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313 Sample: CaFA (P,1,1)
Concentration in rog/t
Fraction
i
2
3
4
5
6
7
8
pH
2.01
3.96
5.54
6.64
9.15
10.9
12.0
13,2
m
22.6
8,02
6.66
6.61
5.89
5,64
4.73
133
m
3,45
0,732
0.485
0.492
0.100
0.0430
0.0157
0,00363
ncv
(0.000500)
{0.000500}
(0.000500}
(0.000500)
(0.000500)
(0.000500)
{0.000500)
(0.000500}
no;
2.65E+04
238
238
4345
3066
2023
3.32
8=20
?h
1.26
0.103
0,00298
0.00114
0.00114
0.00114
0.00256
0.0870
PQti5"
{1,04}
(1.04)
(1,04)
{1,04)
(1.04)
{1.041
(1.04)
(1.04)
Re
0.00459
0,00459
0.00459
0,00459
0.00459
0.00459
0.00459
0.00459
Sb
0.678
0.0941
0.0266
0.0294
0.0531
0.0753
0.00278
0.00733
5e
4.5?
0.901
0.142
0,141
0.336
0.548
0.339
0.-8Q5
51
1295
144
44=0
39.7
12,2
2.89
3,38
3.40
Sri
0.523
0.0520
0.00349
0.00349
0.00349
0,00349
0.00349
0.00349
S042*
223
237
327
271
258
259
115
165
Sr
22,6
8.13
5.43
5.23
3,15
2.55
1,79
1.35
Ti
110
4.49
0.00612
0.00261
0,00133
0.00201
(0.000500)
(0.000500)
n
0,101
0,0460
0,0161
0.0148
0,00253
0.00253
0,00253
0,00253
u
2.02
0.258
0,00133
0.90133
0.00133
0.00133
0.00133
0.00133
V
365
3.38
0.184
0.196
0.74a
1.12
0.363
0.488
Zn
12.3
3,83
1.S4
1.47
0.267
0,0773
0.0360
0,0838
Report Date; 25-Jan~2017 page 4
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313
Sample: CaFA(P,l,l}
Method Detection limit in mg/l
Fraction
J
2
J
4
S
6
7
8
pH
2.01
3.96
5.54
6.64
9.15
10.9
12.0
13,2
Ai
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
As
0.000640
0,000640
0,000640
0.000640
0.000640
0,000640
0.000640
0.000640
B
0.00100
0,00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
Ba
0.000570
0,000570
0.000570
0,000570
0.000570
0.000570
0.000570
0.000570
Be
0,000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000640
Br
0.320
0.320
0.320
0.320
0.320
0.320
0320
0.320
ca
0.00350
0.00350
0.00350
0.00350
0,00350
0.00350
0.00350
0.00350
Cd
0.000170
0.000170
0.000170
0.000170
0.000170
0.000170
0.000170
0.000170
cr
4,13
4.13
4,13
4,13
4.13
4.13
4,13
4.13
Co
0.000410
0.0004.10
0.000410
0.000410
0,000410
0.000410
0.000410
0,000410
co32"
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
Cr
0.000500
0.000500
0.000500
0.000500
0.0Q05Q0
0.000500
0,000500
0.000500
Cs
0.00100
0.00100
0.00100
G.OOIOG
0.00100
0.00100
0.00100
0.00100
Cu
0.000700
0.000700
0.000700
0.000700
0.000700
0.000700
0.000700
0.000700
DIC
0.0700
0.0700
0.0700
0.0700
0,0700
0.0700
0.0700
0.0700
DOC
0.0900
0.0900
0.0900
0.09C0
0.0900
0.0900
0.0900.
0.0900
Fe
0.00290
0.00290
0.00290
0.00290
0.00290
0.00290
0,00290
0.00290
r
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
Hg
6.GQE-06
6.00E-06
6.00E-06
6.00E-06
6.00E-06
6.00E-06
6.00E-06
6.00E-06
K
0.00150
0.00150
0.00150
0.00150
0.00150
0.00150
0.00150
0.00150
Mg
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0,00100
0.00100
Mn
0.000340
0.000340
0,000340
0.000340
0.000340
0.000340
0.000340
0.000340
Mo
0.000760
0.000760
0.000750
0.000760
0,000750
0.000760
0.000760
0.000760
Report Date: 25-Jan-2017
page 5
-------
EPA Method 1313 Sample: CaFA (P, 1,1}
Method Detection Limit in mg/L
Fraction
1
2
3
4
5
6
7
8
pH
2.01
3.96
5,54
6.64
9.15
10.9
12.0
13,2
Na
0,00350
0.00350
0.00350
0,00350
0.00350
0.00350
0.00350
0.00350
Ni
0.000730
0.000730
0.000730
0.000730
0.000730
0.000730
0,000730
0.000730
NO/
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
NO,"
0.475
0.475
0.475
0.475
0.475
0.475
0.475
0.475
Pb
0.000230
0.000230
0.000230
0.000230
0.000230
0.000230
0.000230
0.000230
PQS3'
2.08
2.08
2.08
2.08
2.08
2..0S
2,08
2,8S
RS
0.000240
0.000240
0.000240
0.000240
0.000240
0.000240
0.000240
0.000240
Sb
S.QQE-05
8.00E-05
S.QQE-05
8.0QE-05
8.00E-05
S.D0E-Q5
8.00E-05
S.0GE-O5
Se
0.000520
0.000520
0.000520
0,000520
0.000520
0.000520
0.000520
0.000520
Si
0.00280
0.00280
0.00280
0.00280
0.00230
0.00280
0.00280
0.00280
Sn
0.000700
0.000700
0.000700
0.000700
0.000700
0.000700
0.000700
0.000700
so4a'
0.505
0,505
0.505
0,505
0,505
0.505
0.505
0.505
Sr
0,00100
0.00100
0,.00100
0.00100
0.00100
0.00100
0.00100
0.00100
Ti
0.00100
0.00100
0.00100
0.00100
0.00100
0,00100
0.00:100
0.00100
Tl
0.000510
0,000510
0,000510
0.000510
0.000510
0.000510
0.000510
0.000510
U
0.000300
0.000300
0.000300
0.000300
0.000300
0.000300
0,000300
0,000300
V
0.000310
0.000310
0,000310
0.000310
0.000310
0.000310
0.000310
0.000310
Zfl
Q.000320
0,000920
0,000920
0,000920
0-.000920
0,000920
0,000920
0,000920
Report Date: 25-Jan-2017
page 6
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313 Sample: CaFA (Pfl,l)
Release In mg/k|
Fraction
1
2
3
4
5
6
7
8
pH
2.01
3.96
5.54
6.64
9.15
10.9
12.0
13.2
At
1.58E+04
967
0,419
0.693
0,169
IS. 6
30,1
16,0
As
43.0
S.75
0,503
0.456
1,01
0.630
0.337
2.14
B
630
503
437
418
337
278
176
157
Ba
82.5
28.8
14.5
13.8
6.90
16.9
27.3
72,1
Be
5,80
1.13
0.0301
0.0301
0,0301
0.0301
0.0301
0,0428
Br*
{¦L60}
(1.60)
(1-50)
{1-60}
fl.60}
(1-60)
{i.m}
(2.27)
Cs
3.54E+04
1.78E+04
1.36E+C4
1.32E+04
1.07E+04
8652
3178
1386
€d
2.10
1,62
1,06
0.940
0.0339
0.0341
0.0343
0.05S5
cr
(20,7)
(20.7}
(2.0,7)
(20,7}
(20.7)
120,7}
(20.7}
(29-3)
Co
19.1
4,02
2.22
2.04
0.0574
0,0206
0.0206
0.0293
COi1'
2.26
2JS
3=89
3.56
3.65
3,83
4.S1
5.80
Cr
94.1
7,61
0.0563
0.348
0.40S
0.511
6,26
12.4
Cs
0.334
0.0477
0.0477
0.0477
0.0477
0.0477
0,0477
0,0677
Cu
97,2
24.1
0.288
0.164
0,0350
0.0350
0.0350
0,214
DJC
32.5
9.32
28,4
14.0
38.9
15.8
7.42
8S.2
DOC
66.6
58.4
54,1
40.3
10.6
15.0
16.9
76.9
Fe
3182
195
(0.0145)
("0.0145)
(0.0145)
(0,0145)
{0.0145}
(0.0206)
f
(0,00500)
0.0364
(0.00500)
(0.00500)
0.0230
0.0249
(0.00500)
(0.00710)
Hg
0.000190
0.000340
(3.00E-05)
3.00E-Q5
(3.00E-05)
{3.00E-05}
(3.00E-05)
(4.26E-05)
K
328
61.2
48.5
48.7
38.5
31.6
20.2
2.21E+04
Mg
2600
911
585
551
317
13.1
(0.00500)
(0.00710)
Mn
561
216
157
143
4,85
0.0924
0.0483
0,512
Mo
373
6.44
11.0
12,8
19.4
18.7
19.9
31.8
Report Date: 25-Jan-2017
page?
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313 Sample: CaFA (P,l,l)
Release in mi
Fraction
1
2
3
4
S
6
7
S
pH
2.01
3.96
5.54
6.64
9.15
10.9
12.0
13.2
Na
226
80.2
66.5
66.1
58.9
56,4
47.3
282
No
34.5
7.82
4,85
4.92
1.00
0.430
0,157
0.0516
NO,"
{0.00500}
{0.00500}
(0.00500)
(0.00500)
(0.00500)
(0.00500)
(0.00500)
(0.00710)
no3-
2.65E+05
2375
2375
4.35E+04
3.07E+04
2.02E+04
33.2
116
Pb
12,6
1.03
0.0298
0.0114
0.0114
0.0114
0.0256
1.23
P043'
(10.4)
110.4}
(10,4}
(10,4}
(10.4)
110,4}
{10.4)
(14.8}
Re
0,0459
0.0459
0.0459
0.0459
0.0459
0.0459
0.0459
0.0652
Sb
6.78
0.941
0.266
0.294
0.531
0.753
0.0278
0.104
Se
45.7
9.01
1.42
1,41
3.36
5.48
3.39
11.4
Si
1.23E+04
1438
440
397
122
28,3
33,8
48.3
Sn
5.23
0.520
0.0349
0.0349
0.034-9
0.0349
0.Q349
0.0496
so/"
2231
2365
3274
2711
25-B1
2587
1150
2346
Sf
226
81.3
54.3
52.3
31.5
25.5
17.9
19.1
Ti
1100
44,9
0.0612
0.0261
0.0133
0.0201
(0.00500)
(0-00710)
I!
1.01
0.460
0.161
0.148
0.0253
0.0253
0.0253
0.0359
U
20.2
2.58
0.0133
0.0133
0.0133
0,0133
0.0133
0.0189
V
365
33.8
1.84
1,96
7,48
11.2
3.63
6.93
In
123
38.3
18,4
14,7
2.67
0.773
0.360
1.19
Report Date: 25-Jan-2017
page
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313 Sample: CaFA (P,l,l)
Interpolated Concentration in mg/t
tetion
1
2
3
4
S
6
7
8
9
pH
2.00
4.00
5. SO
?.m
8.00
9.00
10,5
12.0
13.0
Af
1583
73,5
0.0510
0.0566
0.0323
0.0184
0.636
3,01
1.33
As
4,90
0.8 IS
0.0645
0.0511
0.0703
0,0967
0.0702
0.0337
0.117
B
63.0
50.1
43.8
40,5
37,2
34.2
29.1
17.6
12.0
83
8.25
2.S3
1,47
1.25
0.948
0.720
1.37
2.73
4.5-8
Be
0.580
0.108
0.00330
0.00301
0.00301
0.00301
0.00301
0.00301
0.00301
Br'
(0.160)
(0.160)
(0.160)
(0.160)
(0,160)
(0.160)
(0.160)
(0.150)
(0.160)
Ca
3537
1772
1365
1278
1174
1079
907
318
119
cd
0.210
0.151
0.107
0.0584
0.0155
0.00414
0.00340
0.00343
O.OO40Q
CI
{2.0?}
(2-07)
(2.07)
(2.07)
(2.07)
(2.07)
f2.07)
(2.07)
(2.07)
Co
1,91
0.396
0.225
0.122
0.02S5
0.00710
0.00261
0.00205
0.00206
COs2'
0.226
0.231
0.386
0.357
0.361
0.365
0.379
0.481
0.419
Cr
3,41
0.672
0.00637
0.0356
0.0378
0.0402
0.0485
0.626
0.826
Cs
0.0334
0.00477
0,00477
0.00477
0.00477
0.00477
0.00477
0.00477
0,00477
Cu
9.72
2,15
0.0323
0.0131
0.00710
0.00384
0.00350
0.00350
0.0118
DIC
3.27
0.958
2,76
1.62
2.43
3.66
2.03
0.742
4,36
DOC
6,66
5,82
5.42
3,33
1.96
1.15
1.38
1.69
4.46
Fe
318
15.4
(0.00145)
(0.00145)
(0.00145)
(0.00145)
(0.00145)
(0-00145)
(0,00145)
r
(0.000500)
0.00344
(0.000500)
(0.000500)
0.00108
0.00209
0.00244
(0.000500)
(0.000500)
Hg
'1.39E-05
3.16E-05
(3.00E-06)
7.14E-06
{3.O0E-O6)
(3.00E-06)
(3..00E-06)
(3.00E-06)
(3.00E-06)
K
33,1
5,08
4.88
4.71
4.29
3.91
3.31
2.02
514
Mg
260
90.1
59.2
51.7
41.2
32.8
2.71
(0.000500)
(0.000500)
Mr?
56.1
21.5
15.9
8.79
2.28
0.593
0.0223
0.00483
0.0258
Mo
3.73
0.653
1.0S
1.36
1.60
1.S3
1,89
1,99
2,19
page 9
-------
EPA Method 1313
Sample: C3f A
interpolated Concentration In
Fraction
1
2
J
4
5
6
7
8
9
pH
2.00
4,00
5.50
7.00
8,00
9,00
10.5
12,0
13.0
Ha-
22.6
7.98
6,69
5,50
6.21
5.93
5.70
4,73
15.6
Hi
3.45
0.773
0.431
0.391
0.208
0.110
0.0521
0.0157
0.00463
NO."
{0.000500}
(0.000500)
(0,000500)
(0.0005005
(0.000500)
(0.000500)
(0.000500)
(0.000500)
(0.000500)
no;
2.65E+04
238
238
4133
3597
3131
2225
3.32
7,06
Pb
1.26
0.0942
0.00325
0,00114
0.00114
0.00114
0.00114
0.00256
0.0483
po/-
(1.M)
(1.04)
{1.04}
{1.04)
(1.04}
(1.04)
fl-04)
Re
0.00459
0.00459
0.00459
0.00453
0.00459
0.00459
0.00459
0.00459
0.00459
Sb
0,678
Q.0911
0.0275
0.0320
0.0405
0.0513
0.0695
0.,00278
Q.O0624
Se
4.57
0.360
0.149
0.150
0,226
0.319
0.490
0.339
0.697
Si
1295
140
45.4
33,5
20.S
13,1
4.02
3.3S
3.40
Sn
0.523
0.0485
0.00374
0.00349
0.00349
0.00349
0.00349
0.00349
0,00349
SQi'
223
238
325
269
264
25S
259
115
156
8r
22.6
8.04
5,43
4,86
3.98
3.25
2.68
1.79
1.41
Ti
110
3.80
0.00724
0.00237
G.00I81
0.00139
0.00183
(0.000500)
(0.000500)
Ti
0.101
0.0448
0.0155
0.0115
0.00568
0,00281
0.00253
0.00253
0.00253
U
2,02
0.225
0.00152
0,00133
0,00133
0,00133
0.00133
0.00133
0.00133
V
35.5
3.14
0.198
0.237
0,405
0.691
1.02
0.363
0.465
In
12.3
3.76
1.88
1,15
0.582
0,295
0.103
0.0360
0.0728
Report Dste: 25-Jsn-2017 page 10
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313
Sample: CaFA {P,l,l}
iated Release
etion
1
2
3
4
S
6
7
8
9
pH
2.00
4.00
5. SO
?.m
8.00
9.00
10.5
12,0
13.0
Af
1.58E+Q4
795
0.510
0,565
0.324
0.184
6.37
30,1
18.4
As
49,0
8,18
0.645
0.511
0.707
0.968
0.704
0.337
1,63
B
630
501
439
404
374
342
291
176
166
83
82.6
28.3
14,7
12.5
9.52
7,20
13.8
27.3
63.4
Be
5.80
1,08
0.0331
0,0301
0,0302
0.0301
0.0302
0.0301
0.0417
Br'
(1-60)
(1.60}
(l,SO)
(1.W)
|1,60)
(1.60)
(1.60)
(2.22)
Ca
3.54E+04
1.77E+04
1.37E+04
1.28E+04
1.18E+04
1.Q8E+04
9088
3178
1646
cd
2.11
1.60
1,07
0,583
0.156
0,0414
0.0341
0.0343
0.0554
CI
<20.?|
(20.6)
(20,?)
(20.6)
(20.7)
120.7)
{20,7)
(20.7)
(28.6)
Co
19.2
3.95
2,25
1.22
0.296
0.0710
0.0261
0,0206
0,0286
COs2'
2.26
2.81
3.86
3.57
3.63
3..SS
3,80
4,81
5.81
Cr
54.2
6.72
0.0637
0.355
0,380
0.402
0.486
6,26
11,4
Cs
0,334
0.0477
0,0477
0.0475
0,0479
0.0477
0.0478
0.0477
0.0661
Cu
37.3
21.5
0.323
0.131
0.0713
0.0384
0.0351
0.0350
0.164
DIC
32.8
9.58
27=5
16.2
24.4
36,6
20.4
7.42
60.4
DOC
66,7
5S.2
54,2
33.2
19.7
11.5
13.9
16.9
61.8
Fe
3185
153
(0.0145)
(0.0145)
(0.0146)
(0.0145)
(0.0145)
(0.0145)
(0.0201)
r
{0.00500)
0.0344
(0.00500)
(0.00499)
0.0109
0.0209
0.0245
(0.00500)
(0.00693)
Hg
0.000190
0.000316
(3D0E-Q5)
7..13E-05
{3.01E-05)
(3.00E-05)
(3.00E-05)
(3.00E-05)
(4.16E-Q5)
K
332
60.8
48,8
47.0
43.1
39.1
33,1
20,2
7121
Mg
2502
900
532
516
413
328
27.1
(0.00500)
(0.00693)
Mr?
551
215
159
S7.S
22.9
5.94
0.229
0.0483
0.357
Mo
37,4
6,53
10.8
13.6
16.1
18,9
18.9
19,9
30,4
Report Date: 25-Jan-2017
page II
-------
EPA Method 1313 Sample: CaFA (P,l,l)
interpolated Release in mg/kj
Fraction
1
2
3
4
5
6
7
8
9
pH
2.00
4.00
5,50
7.00
8.00
9.0Q
10.5
12.0
13.0
Ma
226
79.8
68.9
64,3
62,4
533
57.1
47.3
217
Ni
34.6
7,72
4,91
3.31
2.09
1.10
0,522
0,157
0.0642
NOj'
{0.00500}
{0.00500}
(0.00500}
(0.00499)
(0.00502}
{0.00500}
{0.00501}
(0.00500}
(0-00693}
NO,"
2.65E+05
2374
2376
4.13E+04
3.61E+04
3.13E+04
2.23E+04
33.2
97,7
Pb
12.6
0.942
0,0326
0.0114
0.0114
0.0114
0,0114
0,0256
0.669
POft3"
(10.4)
|10.41
(10,4)
fl0,4|
(10,4)
(10.4)
(10.4)
Re
0,0450
0.0459
0.0459
0.0459
0.0461
0.0453
0.0460
0,0459
0.0636
Sb
6.79
0.911
0,275
0.319
0.407
0.513
0.696
0,0278
0.0854
Se
45,7
8.60
149
1.60
2,27
3.19
4.91
3.39
9.66
Si
1.30E+04
1335
454
335
210
131
40.3
33,8
47,1
Sn
5.24
0.485
0,0374
0.0349
0.0351
0.0349
0.0350
0.0349
0.0484
S042'
2232
2384
3249
2688
2652
2590
2590
1150
2154
Sr
226
80.4
54.8
48,6
39.3
32.5
26,8
17.9
19.6
Ti
1101
38.0
0-0724
0.0236
0,0182
0.0139
0.0183
(0.00500}
(0.00693)
II
1.01
0.448
0,165
0.115
0.0570
0,0281
0.0253
0.0253
0.0350
U
20.2
2„25
0,0152
0.0133
0.0133
0.0133
0.0133
0,0133
0.0184
V
366
31.4
1.98
2,37
4,07
6,31
10.2
3,63
6,44
Zfl
123
37,6
18,8
11,5
5,85
2.95
1.03
0.360
1,01
Report Date: 25-Jan-2Q17
page 12
-------
EPA Method 1313
Sample; CaFA (P,l,l)
Assessment on interpolated values; available content on as measured values
Available Content From pH range {2,5,13), an as measured values.
Scenario min pH 7
Scenario max pH 12
Reporting Limit (mg/i) Concentration (mg/L} Release (mg/kg) Available (mg/kg)
min
max
min
max
max at pH
mm
ma*
atpH
A!
0.00100
0.00100
0,0184
3.01
12.0
0.184
30.1
1.58E+04
2.01
As
0.000640
0.000640
0,0337
0.0967
9.00
0,337
0.968
49,0
2.01
B
0,00100
0.00100
17,6
40,5
7,00
176
404
630
2,01
8a
0.000570
0.000570
0.720
2,73
12,0
7.20
27.3
82,5
2.01
Be
0.000640
0.000640
0.00301
0,00301
7,00
0,0301
0.0302
5m
2.01
Br*
0.320
0.320
(0.160)
(0.160)
7,00
(1.61)
2.27
13,2
Ca
0.00350
0.00350
318
1278
7,00
3178
1.28E+04
3.54E+Q4
2,01
Cd
0.000170
0.000170
0.00340
0.0584
7,00
0.0341
0.583
2,10
2,01
cr
4.13
4.13
(2„Q7)
(2,07}
7,00
{20.6)
(20.7)
29.3
13.2
Co
0.000410
0.000410
0.00206
0.122
7,00
0.0206
1,22
19.1
2.01
CO/'
0.00100
0.00100
0.357
0.481
12.0
3.57
4,81
5.80
13.2
Cr
Q.000500
0,000500
0.0356
0,626
12.0
0.355
6.2S
94.1
2.01
Cs
0,00100
0.00100
0.00477
0.00477
12.0
0.0476
0,0479
0,334
2.01
Cu
0,000700
0.000700
0.00350
0.0131
7.00
0.0350
0.131
97.2
2.01
D1C
0,0700
0.0700
0.742
3,66
9.00
7.42
3S.6
88,2
13.2
DOC
0.0900
0.0900
1.15
3.33
7,00
11.5
33.2
76,9
13,2
Fe
0.00290
0.00290
(0.00145)
(0.00145)
7,00
(0.0145)
{0.0146}
31S2
2.01
r
0.00100
0.00100
(0.000500)
0.00244
10,5
(0.00499)
0.0245
0,0230
9,15
Hg
6.00E-06
6.00E-Q6
(3.00E-06)
7.14E-06
7,00
(3.0OE-O5)
7.13E-05
0.000190
2.01
K
0.00150
0.00150
2.02
4,71
7,00
20.2
47.0
1.11E+04
11,2
Mg
0.00100
0.00100
(0.000500)
51,7
7.00
(0.00500)
516
2600
2,01
Mn
0,000340
0.000340
0,00483
8.79
7.00
0.0483
87.8
561
2,01
Mo
0.000760
0.000760
1.36
1.39
12,0
13.6
19,9
37,3
2,01
Report Date: 25-ian-201?
page 13
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1313
Sample: CaFA (P,l,l)
Assessment on interpolated values; available content on as measured values
Available Content From pH range {2,9,13}, on as measured values.
Scenario min pH 7
Scenario max pH 12
Reporting Limit (mg/L} Concentration (mg/L) Release (nig/kg) Available (mg/kg)
min
mm
min
/no*
max at pH
mm
max
aipH
N a
0.00350
0.00350
4.73
6.50
7,00
47.3
64.9
282
13.2
Mi
0.000730
0.000730
0.0157
0.391
7,00
0.157
3.91
34.5
2.01
no;
0.00100
0.00100
(0.000500)
(0.000500}
7.00
(0.00499)
(0,00502)
0.00941
13.2
no3"
0.475
0.475
3.32
4133
7.00
33.2
4.13E+04
1.54E+G4
11.2
Pb
0.000230
0.000230
0.00114
0.00256
12,0
0.0114
0.0256
12.6
2.01
>043"
2,08
2.08
(1.04)
(1-M)
7,00
{10.4}
|10.4)
14.8
13.2
Re
0.000240
0,000240
0.00459
0,00459
12.0
0.0459
0.0461
0.0652
13,2
sb
8.00E-05
B.Q0E-Q5
0,00278
0.0695
10.5
0,0278
0.696
6.78
2,01
Se
0,000520
0.000520
0.160
0.490
10.5
1.60
4.91
45.7
2,01
Si
0.00280
0.00230
3.38
33.5
7.00
33.S
335
1.29E+04
2.01
Sn
0.000700
0,000700
0.00349
0.00349
7,00
0.0343
0.0351
5.23
2.01
so/"
0.505
0,505
115
269
7.00
1150
2688
25S1
9.15
Sr
0.00100
0.00100
1.79
4.86
7,00
17,5
48.6
226
2.01
Ti
0.00100
0.00100
(0.000500}
0.00237
7.00
(Q.00500}
0.0236
1100
2.01
Tl
0.000510
0.000510
0.00253
0.0115
7,00
0.0253
0.115
1-01
2.01
u
0.000300
0.000300
0.00133
0.00133
7.00
0.0133
0.0133
20.2
2.01
V
0.000310
0.000310
0,237
1.02
10.5
2.37
10.2
365
2.01
Zn
0.000320
0.000920
0.0360
1.15
7.00
0.360
11.5
123
2.01
Report Date: 25-Jan-2017
page 14
-------
EPA Method 1314
Sample: CaFA {C,1,1}
Analysis report according to EPA Method 1314
Crested by LeacnXS*", version 2.0..92 ilS-Oct-2016)
Report crested on 25-Jan-2017 2:59 PM
Material information
Sample ID
Sample Name
Sample Replicate
Test Replicate
Category
Subcategory
Fuif Name
Description
Origin
Sample Database
CaFA (C,lA)
CaFA
A
A
Coal Combustion
Fly Ash
CaFA
Coal combustion fly ash from Facility Ca
EPACCR Report 3
C:\U-sers\User\Documents\LeachXS User ObJects\
DATABA5ES\LEAF Guide (16-Dec-2016).r
Test Parameters
Start Date 2-Mar-iO
End Date 18-Mar-IO
Eiuate
0,3
mm
Solids Content
100.0
%
Bed Length
30,0
cm
Column Diameter
4,80
cm
Bed Volume
543
cm3
As Tested Mass
0.696
kg
Dry Mass
0.636
kg
Temperature
21,0
X
Flowrate
433
mi/day
Ffowrate
0.631
L/S per day
Report Date; 25-Jan-2017 page 1
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314
Sample: CaFA (C,l,l)
Legend
pB
Acidity
m
Redox potential
K(25°C}
Conductivity at 25
1 L/S-dry
Cumulative liquid-to-solid ratio, in L/kg
L/S-dry
Liquid-to-solid ratio of fraction, in l/kg
V
Volume
IV
Cumulative volume
N/A
Not analyzed or measured
N/C
Not calculated
Concentrations below the method deleft/on limit (MDL) are reported between parentheses as haffof the MDL,
Cumulative releases calculated with any concentration below the MDL are listed between parentheses.
Fraction information
Fraction
I L/S-dry
pH
E(.h)
K(25Yj
L/S-dry
V
IV
L/kg
m¥
mS/cm
L/kg
ml
mi
i
0.204
12.5
N/A
16.0
0,204
142
142
2
0,510
12.5
N/A
14.4
0.307
213
355
3
1.02
12,3
N/A
8.13
0.513
35?
712
4
1,53
12,2
N/A
7.S2
0,509
354
1067
5
2.05
12.4
N/A
12.3
0.513
357
1424
6
4.43
12,2
N/A
10.1
239
1661
3085
7
4,38
12,0
N/A
10.0
0,546
380
3465
S
3-60
11.8
N/A
3,51
4,62
3218
6682
9
10.1
11.5
N/A
2,01
0,510
355
7037
Report Date: 25-ian-2017
page 2
-------
EPA Method 1314 Sample: CaFA (C,l,l)
Concentration In m
Fraction
1
2
5
4
5
6
7
s
9
I L/S-dry
0,204
0.510
1.02
J.53
2.05
4.43
4.98
9.60
10.1
pH
12,5
12,5
123
12.2
12.4
12.2
12.0
11.8
11.5
AI
0.248
0.514
0,389
0.387
0.103
1.07
0.610
9.72
8.60
As
0,00141
0.000-852
(0,000320)
(0.000320)
(0.000320)
(0.000320)
(0.000320)
0.00330
0.0178
B
16,0
9,37
9.86
10.6
11.6
15.7
20,7
17.6
9.33
Ba
396
224
118
87.3
65.8
34.5
16.4
4.64
2,38
Be
(0.000320)
(0,.000320}
(0,000320)
(0,000320)
(0.000320)
(0.000320)
(0.000320)
(0.000320)
(0,000320)
Ca
910
998
377
905
S64
782
699
266
140
Cd
(S.50E-05)
(8.50E-05)
(8.50E-05)
(8.50E-05)
(8.50E-05)
(8.50E-05)
(8.50E-05)
0.00351
(8.50E-05)
Co
0,0200
0.0104
0.00677
0.00402
0.00378
0.00344
(0.000900)
0.00203
0.00285
Cf
0,0351
0.00849
0.0063.3
0.00442
0.00509
0,00625
0.00334
0.0776
0.314
Cs
0.0118
0.00226
0.000770
(0.000245)
(0.000245)
(0.000245)
(0.000245)
(0,000245)
(0.000245)
Cu
0.0147
0.0185
0.0170
0.0161
0.00758
0.0108
0.00689
0.00559
0.00412
D!C
0.000843
0,00142
0.00123
0.000703
0.000291
(6.50E-05)
0.000715
0.00347
0.00511
DOC
0.0100
0.00516
0.00406
0.00442
0.00391
0.00549
0.00474
0.00930
0,00660
Fe
10.00100}
(0,00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
K
28,4
3*72
2.05
1.64
1,53
1.51
1.38
0.830
0.537
Li
21.0
2.60
1.32
0.923
0.740
0,528
0.396
0,254
0.163
Mg
0.0160
0,0289
0.0178
0.0115
0,0245
0.0150
0.109
0.0139
0.00998
Mn
(0,000170)
(0.000170)
(0.000170)
(0.000170)
(0.000170)
(0.000170)
(0.000170)
0.00388
0.00355
Mo
1.00
0.317
0.282
0.239
0.202
0.175
0=170
4.70
0.653
Report Date: 25-Jan-2017
page3
-------
EPA Method 1314
Sample: CaFA (C,l,l}
Concentration In mj
Fraction
1
2
3
4
5
6
7
8
9
I L/S-diy
0.204
0,510
1.02
1.53
2.05
4.43
4.98
9.60
10.1
jM
12.5
12.5
12,3
12.2
12.4
12.2
12.0
11.8
11.5
m
111
47.4
26.3
17,7
13.4
7 AO
3,68
1.06
0.662
Ni
0.0282
0.0303
0.0289
0.0272
0.0247
0,0256
0.0184
0,00496
0.00136
P
0.00799
{0,00185}
0.0120
0,00654
{0.00185)
(0.00185)
(0,00185)
(0.00135)
(0,00185)
Pb
0.00153
0.00841
0.0152
0,0115
0.00864
0.00511
0.00343
(0.000115)
(0.000115)
Re
0.126
0,0443
0.00241
0.00106
0.000740
0.000467
0.000374
(0.000120)
(0.000120)
5
0.514
0,137
0.121
0.0843
0.0769
6.98
6.36
3.45
9.16
Sb
0.000396
0,000993
0.00148
0.00175
0.00175
0.00275
0,00452
0.0182
0,0385
Se
0.556
0.638
0.584
0.241
0.830
0.484
0.562
0.351
0.381
Si
0.680
0.282
0.2o5
0.303
0.237
0.265
0.325
1.65
3.64
Sri
(0.000350)
(0.000350)
(0.000350)
(0.000350)
(0.000350)
fO.000350)
(0,000350)
(0.000350)
(0.000350)
5f
76.6
15.3
4,89
3.69
3,14
2.26
1.73
1.14
0.872
Ti
(0,00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
(0.00100)
T!
(0.000255)
(0.000255)
(0.000255)
(0.000255)
(0.000255)
(0.000255)
(0,000255)
(0,000255)
(0,000255)
U
(0.000150)
(0.000150)
(0.000150)
(0.000150)
(0.000150)
(0.000150)
(0,000150)
(0.000150)
(0.000150)
V
0.0948
0.104
0.100
0.0943
0.0896
0.0822
0.0759
0.216
0.708
In
0.0266
0.00989
0.00502
0.00414
(0.000500)
0.0392
(0.000500)
0.00840
(0.000500)
Report Date: 25-Jan-2017
page 4
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314 Sample: CaFA (C,l,l)
Method Detection Limit in mt
Fraction
I
2
5
4
5
6
7
8
9
I l/S-dry
0.204
0.510
1.02
1.53
2.05
4.43
4.98
9.60
10.1
12.5
12.5
123
12.2
12.4
12.2
12.0
11.8
11.5
Ai
0.00100
0.00100
0,00100
0.00100
0.00100
0.00100
0.00100
0.00100
0,00100
As
0,000640
0.000640
0.000640
0.000640
0.000640
0.000640
0.000540
0.000640
0.000640
B
o.ooioo
0.00100
0,00100
0.00100
0.00100
0.00100
0.00100
0,00100
0,00100
Ba
O.OOIOO
O.OOIOO
O.OOIOO
0,00100
0.00100
0.00100
0.00100
0,00100
0.00100
Be
0,000640
0,000640
0.000640
0.000640
0,000640
0.000640
0,000640
0.000640
0,000640
Ca
0.00260
0.00260
0.00260
0.00260
0.00260
0,00260
0.00260
0,00260
0.00260
Cd
0,000170
0.000170
0.000170
0.000170
0.000170
0,000170
0,000170
0.000170
0.000170
Co
0.00180
0,00180
O.OOISO
0.00180
0.00180
0.00180
0.00180
O.OOISO
0.00180
Cf
0:,00120
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
Cs
0.000490
0.000490
0.000490
0.000490
0,000490
0.000490
0.000490
0.000490
0.000490
Of
0.00.370
0.00370
0,00370
0,00370
0.00370
0.00370
0.00370
0.00370
0.00370
D!C
0-000130
0.000130
0.000130
0.000130
0.000130
0.000130
0.000130
0.000130
0.000130
DOC
0.000170
0.000170
0,.000170
0.000170
0.000170
0.000170
0.000170
0.000170
0,000170
Fe
0.00200
0.00200
0.00200
0.00200
0,00200
0.00200
0.00200
0.00200
0.00200
K
0.00150
0.00160
0.00160
0,00160
0.00160
0.00160
0.00160
0.00160
0.00160
li
0.00190
0.00190
0.00190
0,00190
0.00190
0,00190
0.00190
0,00190
0,00190
Mg
0,00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
0.00100
Mn
0,000340
0,000340
0.000340
0.000340
0.000340
0.000340
0.000340
0.000340
0.000340
Mo
0,00120
0.00120
0.00120
0.00120
0.00120
0.00120
0.00120
0,00120
0.00120
pageS
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314 Sample; Ca FA (C,14)
Method Detection Limit in i
Fraction
I
2
3
4
5
6
7
8
9
I L/S-dry
0.204
0.S10
1.02
1S3
2.05
4.43
4.98
9.60
10.1
pH
12.5
12,5
12.3
12.2
12.4
12.2
12.Q
11.8
11,5
Na
0.00250
0,00250
0.00250
0,00250
0,00250
0.00250
0.00250
0.00250
0.00250
Mi
0.000730
0,000730
0.000730
0.000730
0,000730
0.000730
0.000730
0.000730
0.000730
P
0.00370
0.0Q370
0.00370
0,00370
0.00370
0.00370
0.00370
0.00370
0,00370
Pb
0,000230
0.000230
0.000230
0.000230
0.000230
0.000230
0.000230
0,000230
0.000230
Re
0.000240
0.000240
0.000240
0.000240
0,000240
0,000240
0.000240
0.000240
0,000240
S
0.00680
0,00680
0.00680
0.006S0
0,00680
0.00680
0.00680
0.00680
0,00680
Sb
8.00E-05
8.00E-05
8.00E-05
S.00E-05
S.00E-05
8.D0E-05
8.00E-05
8.00E-05
6.00E-05
Se
0.0150
0.0150
0.0150
0.0150
0.0150
0,0150
0.0150
0.0150
0.0150
Si
0.00110
0.00110
0.00110
0.00110
0,0011.0
0.00110
0.00110
0.00110
0,00110
Srt
0,000700
0.000700
0.000700
0.000700
0.000700
0.000700
0,000700
0.000700
0.000700
Sr
0,00100
0.00100
0,00100
0.00100
0,00100
0.00100
0.00100
0.00100
0.00100
Ti
0,00200
0.00200
0.00200
0.00200
0.00200
0,00200
0.00200
0,00200
0.00200
TI
0.000510
0.000510
0.000510
0.000510
0.000510
0.000510
0.000510
0.000510
0,000510
U
0,000300
0.000300
0,000300
0.000300
0.000300
0.000300
0.000300
0.000300
0.000300
V
0.00150
0.00150
0.00150
0.00150
0.00150
0,00150
0,00150
0,00150
0,00150
In
0,00100
0,00100
0.00100
0.00100
0.00100
0.00100
0.00100
0,00100
0,00100
Report Date: 25-Jan-2017
page 6
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA. Method 1314
Sample; CaFA (C,l,l)
Cumulative Release in mi
Fraction
I
2
J
4
5
6
7
8
9
1 L/S-dry
0.204
0.5 JO
1.02
1.53
2.05
4,43
4.98
9.60
10.1
pH
12.5
12.5
12.3
12.2
12.4
12.2
12.0
11,.8
11.5
Ai
0.0506
0,208
0.408
0.605
0,658
3.20
3.54
48.5
52.9
As
0,000237
0.000548
(0.000713)
(0.000876)
(0.00104)
(O.OOlSOj
(0.00198)
(0.0172)
(0.0263)
B
3.25
6.12
11.2
16,6
22,5
59.9
71.2
152
157
Ba
so.e
149
210
254
288
370
379
401
402
Be
(6.52E-05)
{0.000163}
(0.000328)
(0,000491)
(0.000655)
(0.00142)
(0,00159)
(0.00307)
(0.00324)
Ca
185
451
993
1454
1897
3763
4145
5376
5447
Cd
(1.73E-05)
(4.34E-05)
(8.70E-05)
(0.000130)
(0.000174)
(0.000377)
(0.000423)
(0.0167)
(0.0167)
Co
0,00408
0.00726
0.0107
0.0128
0.0147
0,0229
(0,0234)
(0,0328)
(0.0343)
Cr
0.00714
0.00974
0.0130
0.0152
0.0179
0,0328
0.0346
0.393
0.553
Cs
0.00240
0,00310
0,00343
(0.00362)
(0.00374)
(0.00433)
(0.00446)
(0.00559)
(0.00572)
Cu
0,00299
0.00854
0.0174
0.0256
0.0235
0.0552
0.0589
0.0848
0.0869
OiC
0.000172
0,000605
0.00123
0.00159
0.00174
(0.00190)
(0.00229)
(0.0183)
(0.0210)
DOC
0,00204
0.00363
0.00571
0.00796
0.00997
0.0231
0.0257
0.0686
0.0720
Fe
(0.000204)
(0,000510)
(0.00102)
(0.00153)
(0.00205)
(0.00443)
(0.00498)
(0.00960)
(0.0101)
K
5.79
6.93
7.38
8.82
9,60
13,2
14.0
17,8
18.1
U
4.2S
5.08
5.76
§,23
5.61
7,87
8.03
9.26
9,34
m
0.00326
0.0121
0.0213
0.0272
0.0397
0.0754
0.135
0.200
0.205
Mn
(3.46E-05)
(8.67E-05)
(0,000174)
(0.000261)
(0.000348)
(0,000754)
(0.000846)
(0.0188)
(0.0206)
Mo
0.204
0.301
0.446
0.567
0.671
1,09
1.18
22.9
23,3
Report Date: 25-Jan-2Q17
page 7
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314
Sample: CaFA (C,l,l)
Cumulative Release in
Fraction
I
2
3
4
5
6
7
S
9
I l/S-dry
0.204
0.510
1,02
1.53
2,05
4.43
4.98
9.60
10.1
P"
12,5
12,5
12.3
12.2
12,4
12.2
12.0
11.8
11.5
Na
22.6
37.1
50.6
59,7
66.5
84.2
86.2
31,1.
91.4
Ni
0,00574
0,0150
0.0299
0.0437
0.0564
0.118
0.128
0.150
0.151
P
0.00163
(0.00219}
(0.00833)
(0.0117)
(0,0126)
<0.0170}
(0.0180)
(0.0266)
(0.0275)
Pb
0.000312
0,00289
0,0107
0.0166
0.0210
0.0332
0.0351
(0,0356)
(0.0356)
Re
0.0257
0.0392
0.0405
0.0410
0.0414
0.0425
0.0427
(0.0433)
(0.0433)
S
0.105
0.147
0.209
0.252
0.291
17,0
20.4
36,4
41,0
Sb
S.06E-05
0.000385
0.00114
0.00204
0.00294
0.00950
0.0120
0.0961
0.U6
Se
0.113
0.309
0.609
0.731
1.16
2.31
2.62
4.24
4.43
Si
0,13.8
0,225
0.361
0.515
0,637
1.27
1.45
9.08
10.3
Sn
(7,131-05)
(0.000179}
(0.000358)
(0.000537)
(0.000716)
(0.00155}
(0.00174)
(0.00336)
(0.00354)
Sr
15.6
20.3
22.8
24.7
26.3
31,7
32.6
37.9
38.4
Ti
(0.000204)
(0.000510}
(0.00102)
(0.00153)
(0.00205)
(0.00443)
(0.00498)
(0.00960)
(0.0101)
Tl
(5.19E-05)
(0.000130)
(0.000261)
(0,000391)
(0,000522)
(0.00113)
(0.00127)
(0.00245}
(0.00258)
U
(3.05E-Q5)
(7.55E-05)
(0.000154)
(0.000230)
(0.000307)
(0.000665}
(0.000747)
(0.00144)
(0.00152)
V
0.0193
0.0511
0.103
0.151
0.196
0.393
0.434
1.43
1,79
2n
0.00542
0,00846
0.0110
0.0131
10.0134)
(0.107}
(0.107)
(0.146)
(0.146)
page 8
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314
Sample: CaFA {C,l,l}
Assessment
Concentration fmg/L) Cumulative Release
max at pH at i L/S-dry at I L/S=10.1 (nig/kg)
At
9,72
11.8
9.60
52.9
As
0.0178
11.5
10.1
(0.0263)
8
20,7
12.0
4.38
157
Ba
396
12.5
0.204
402
Be
(0.000320)
11.5
10.1
(0,00324)
Ca
998
12,5
0.510
5447
cd
0,00351
11.8
9.60
{0,0167)
Co
0,0200
12,5
0,204
(0.0343)
Cr
0,314
11.5
10.1
0.553
Cs
0,0118
12.5
0.204
{0.00572)
Cu
0,0185
12,5
0.510
0,0859
0!C
0,00511
11.5
10,1
(0.0210)
DOC
0.0100
12,5
0.204
0,0720
Fe
(0-00100)
11.5
10.1
{0.0101)
K
28,4
12,5
0,204
13.1
Li
21.0
12.5
0.204
9.34
Mg
0,109
12.0
4.38
0.205
Nfn
0,00388
11.8
9.60
(0.0206)
Mo
4,70
11.8
9.60
233
Report Date: 25-Jan-2017
page9
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1314
Sample; CaFA {C,l»l}
Assessment
Concentration (mg/L) Cumulative Release
mm
atpN at SI
/S-cfry
at I L/S-10,1 (mg/kg)
m
111
12.5
0.204
31.4
Ni
0,0303
12.5
0.510
0.151
P
0.0120
123
1.02
(0.0275)
Pb
0.0152
12.3
1.02
(0.0356)
Re
0.126
12.5
0.204
(0.0433)
S
S.,16
11.5
10.1
41.0
Sb
0,0385
11.5
10.1
0.116
Se
0,830
12.4
2,05
4.43
Si
3.64
11.5
10.1
10,9
Sn
(0.000350)
11.5
10.1
(0.00354)
Sr
76.6
12.5
0.204
38.4
Ti
(0.00100)
11.5
10.1
(0.0101)
Tl
(0.000255)
11.5
10.1
(0.00258)
U
(0.000150)
11.5
10.1
(0.00152)
V
0.708
11.5
10,1
1.79
In
0.0392
12.2
4.43
(0.146)
Report Date: 25-Jan-2G17 page 10
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Sample; CaFA
Analysis report according to EPA Method 1316
Created by LeKhXS"*, version 2,0.92 (lS-Oct-2016}
Report crested on 25-Jao-201? 3:01 PM
Material Information
Sample ID
Sample Mams
Sample Replicate
Test Replicate
Category
Subcategory
Full Name
Description
Origin
Sample Database
CaFA {0,1,1]
CaFA
A
A
Coal Combustion
Fly Ash
CaFA
Coal combustion fly a.sh from Facility Ca
EPA Report 3
C:\Users\User\Docunients\LeachXS User ObJee?s\
DATABASES\LEAF Guide (16-Dec-2Q16).mdb
Test Parameters
Start Date
End Date
Particle Size
Contact Interval
Solids Content
Temperature
28-Apr-10
29-Apr-10
0.3 mm
24,0 h
100 %
25.0 X
Report Date: 25-Jao~2G17
page 1
-------
EPA Method 1316
Sample: CaFA 10,1,1}
Legend
pH Acidity
E(h) Redox potential
K(25°C} Conductivity at 25 X
L/S-dry Liquid-to-solid ratio, in L/kg
fvT Mass, 3S tested
V '^eluant
Total V TctdMi r iii volume
N/A Nc sulked or measured
N/C Not calculated
Concentrations below the method detection limit (MDL) are reported between parentheses m half of the MDL
Fraction information
Fraction
n
L/S-dry
pH
mV
K{25*C)
mS/cm
M
§
V
mi
Total V
ml
4
LOG
12.1
-2S9
23.4
100
100
100
3
2.00
12,0
-23?
20.1
50.0
100
100
2
5.00
11.8
-286
12.7
40.Q
200
200
I
10.0
12.0
-296
7,54
40.0
400
400
Report Date: 25-Jan-2G17 page 2
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Concentration in mi
Fraction
4
3
2
i
L/S-dfy
LOO
2.00
5.00
10.0
12.1
22,0
11.8
12.0
A!
0.367
0.381
0.223
3,01
As
0,0158
0.0206
0.0307
0.0337
B
66.0
52.6
30.7
17,6
Ba
4,.35
4,73
3,91
2.73
Be
0,00301
0.00301
0.00301
0.00301
Br"
(0,160}
(0,160)
(0.150)
(0.160)
Ca
1115
1014
527
318
Cd
0.0182
0.0125
0.00535
0.00343
Cl"
(2,07)
(2.07)
|2.07)
(2-07)
Co
0.00206
0.00206
0.00206
0.00206
co3*
0.314
0.305
0.355
0.481
Cf
2.32
1.66
0,751
0.626
Cs
0,013477
0.00477
0.00477
0.00477
Gu
0.00895
0.00999
0.00350
0.00350
DSC
3.93
1.67
6.19
N/A
DOC
10,5
0.540
5.52
N/A
Fe
(0.00145)
(0.00145)
(0.00145)
(G.00145)
f
10.000500)
{0.000500}
(0,000500)
(O.G005GO)
Hg
9.CQE-06
(3.00E-06)
(3.0GE-Q6)
(3.00E-06)
K
10.4
5.63
2.65
2.02
mE
0,390
(0,000500)
(0.000500)
(0,000500)
Mn
0,00413
0.00403
0.00171
0.00453
Mo
10.9
7.42
3.52
1.99
Report Date: 25-Jan-2017
Sample: CaFA (B.1,1)
page 3
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Concentration In mi
Fraction
4
3
2
1
L/S-dry
LOO
2,00
5.00
10.0
PH
12,1
12,0
11.8
12,0
m
33,7
19.0
8.63
4.73
Ni
0.0654
0.0679
0.0343
0.0157
NOj'
(0,000500)
(0,000500)
(0.000500)
(0,000500)
no5"
26.1
22.0
10.7
3.32
Pb
0,0353
0.0259
0.00795
0.00256
PO/"
(1,041
{1.04}
(1-04)
{1*04}
Re
0.0259
0,015-9
0.00459
0,00459
Sb
0,00278
0.00278
0.00278
0.00278
Se
0,224
0.261
0,318
0.339
Si
16.3
0.538
2,77
3,3-8
Sn
0,00349
0.00349
0.00349
0.00349
so/"
258
268
210
115
Sr
13.8
8,30
3.65
1,79
Ti
(0.000500)
(0,000500)
(0.000500)
(0.000500)
T!
0.00253
0.00253
0.00253
0.00253
U
0,00133
0.00133
0.00133
0.00133
V
0.0583
0,0704
0,157
0.363
Zn
0.0805
0.0654
0,0338
0.0360
Report Date: 25-Jan-2017
Sample: CaFA (6,1,1}
page 4
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Sample: CaFA 10,1,1}
Method Detection Limit in ms
Fraction
4
3
2
J
l/5-tlry
1.00
2,00
5,00
10.0
m
12.1
12.0
11.8
12.0
Al
0.00100
0,00100
0.00100
0,00100
As
0,000640
0.000640
0.000640
0.000640
B
0.00100
0.00100
0,00100
0.00100
8 3
0.000570
0,000570
0.000570
0.000570
Be
0,000640
0.000640
0,000640
0.000640
Br'
0,320
0,320
0.320
0,320
Ca
0,00350
0.00350
0,00350
0.00350
Ctf
0,000170
0.000170
0.000170
0.000170
cr
4.13
4.13
4.13
4,13
Co
0.000410
0,000410
0.000410
0.000410
CO/'
0,00100
0.00100
0.00100
0,00100
Cr
0,000500
0.000500
0,000500
0.000500
Cs
0.00100
0.00100
0.00100
0.00100
Of
0.000700
0,000700
0.000700
0.000700
DIC
0,0700
0.0700
0.0700
N/A
DOC
0,0900
0.0900
0.0900
N/A
Fe
0.00290
0.00230
0.00290
0.00290
F
0,00100
0.00100
0,00100
0.00100
Hg
6.00E-06
6.00E-06
6.Q0E-06
6.00E-06
K
0.00150
0,00150
0,00150
0.00150
Mg
0.00100
0.00100
0,00100
0.00100
Mr
0.000340
0,000340
0.000340
0.000340
Mo
0.000760
0.000760
0.000760
0.000760
Report Date: 25-Jan-2017 page 5
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Sample: CaFA (B,l,l)
Method Detection Limit in mg/l
Fraction
4
3
2
1
L/S-dry
1.00
2.00
5,00
10.0
pH
12.1
12.0
11.8
12,0
m
0,00350
0.00350
0.00350
0.00350
m
0.000730
0,000730
0.000730
0=000730
NO/
0,00100
0.00100
0.00100
0.00100
NOj
0,475
0,475
0.475
0.475
Pb
0,000230
0,00023-0
0.000230
0.000230
po/'
2.08
2.08
2.08
2,08
Re
0.000240
0.000240
0,000240
0.000240
Sb
8.00E-05
8.0QE-0S
8.00E-05
8.00E-05
Se
0,000520
0-000520
0.000520
0.000520
St
0.00280
0.002S0
0.00280
0.00280
$n
0.000700
0.000700
0.000700
0.000700
so/-
0.505
0,505
0.505
0.505
Sr
0.00100
0,00100
o.ooioo
0.00100
Ti
0.00100
0,00100
0.00100
0.00100
n
0.000510
0.000510
0,000510
0.000510
u
0,000300
0.000300
0.000300
0.000300
V
0.000310
0,000310
0.000310
0.000310
m
0.000920
0.000920
0.000920
0.000920
Report Date: 25-Jan-2017
page 6
-------
EPA Method 1318
Release m m
Fraction
4
3
2
J
L/S-dry
LOO
2.00
5,00
10.0
PH
12.1
12.0
11.8
12.0
M
0-367
0.763
1,11
30.1
As
0.0158
0.0413
0,153
0.337
8
66.0
105
153
176
B 3
4.95
9,46
19.5
27.3
Be
0.00301
0.00602
0.0151
0.0301
Br"
0.160
0.320
0.800
1.60
C3
1115
2028
2636
3178
OS
0.0162
0.0250
0.0267
0.0343
cr
2.07
4,13
10.3
20.7
Co
0.00206
0,00412
0,0103
0.0206
C032"
0.314
0.610
1.78
4.81
Cr
2.32
3,32
3,76
6.26
Cs
0.00477
0.00954
0.0238
0.0477
Cu
0.00835
0.0200
0.0175
0.0350
DiC
3,93
3,34
30,3
N/C
DOC
10,5
1,08
27.6
N/C
Fe
0,00145
0,00290
0.00725
0.0145
F"
0.000500
0.00100
0.00250
0.00500
Hg
9.00E-06
6.00E-06
1.50E-Q5
3.O0E-O5
K
10.4
113
13.2
20.2
Mg
0.990
0,00100
0.00250
0.00500
Mn
0.00413
0.00807
0.00854
0.0483
Mo
10.9
14.8
17,6
13,9
Report Date: 25-Jan-2017
Sample: CaFA (6,1,11
page 7
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Release In i
Fraction
L/S-dry
4
1.00
12.1
3
2,00
12.0
2
5,00
11.8
J
10.0
12.0
Ma
Ni
N02~
NO,"
PQS
Sb
Se
Si
Sn
Sr
Ts
V
z n
33.7
0.0654
0,000500
26.1
0,0353
1.04
0.0253
0.00273
0.224
16.3
0,00349
258
13.8
0.000500
0,00253
0,00133
0,0583
0.0805
38.0
0,136
0.00100
43.9
0,0519
2,08
0,0318
0.00557
0.522
1.08
0.00698
536
16.6
0.00100
0.00506
0,00266
0.141
0.131
43.1
0.172
0.00250
53.5
0.0338
5,20
0,0230
0.0139
1.59
13.3
0.0175
1052
IS .2
0.00250
0.0127
0.00664
0.733
0.169
47.3
0.157
0,00500
33.2
0.0256
10.4
0.0459
0,0278
3.39
33.8
0.0349
1150
17.9
0.00500
0.0253
0.0133
3,63
0.360
Report Date: 25-Jan-2G17
Sample: CaFA 10,1,1}
page
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
-------
EPA Method 1316
Sample: CaFA {6,1,1}
Assessment
Reporting Limit (mg/l} Concentration {mg/L} Release (mg/kg)
mm
max
mm
max
max at L/S
max at pH
min
max
max at L/S
max atpH
Ai
1.00
1.00
223
3013
10.0
12.0
367
3.01E+C4
10.0
12.0
As
0.540
0.640
15.8
33.7
10.0
12,0
15.8
337
10.0
12.0
8
1.00
1.00
1.76E+04
5.60E+04
1.00
12.1
6.60E+04
1.76E+05
10..O
12.0
Bs
0.570
0.570
2732
4947
1.00
12,1
4947
2.73E+04
10.0
12.0
Be
0.640
0.640
3.01
3.01
10.0
12.0
3.01
30,1
10.0
12.0
Br"
320
320
(1§0)
|160|
10,0
12.0
(ieo)
(1600)
10.0
12.0
Ca
3.50
3.50
3.18E+05
1.11E+Q6
1.00
12.1
1.11E+06
3.18E+06
10.0
12.0
Cd
0.170
0.170
3,43
16.2
1.00
12a
16.2
34.3
10,0
12,0
cr
4130
4130
(2065)
(2065)
io.o
12.0
(2065)
(2.07E+04)
10.0
12.0
Co
0,410
0.410
2.05
2.06
10.0
12.0
2.06
20.6
10.0
12,0
CO,2'
1.00
1,00
305
481
10.0
12.0
314
4807
10.0
12,0
Cr
0.500
0.500
626
2323
1.00
12.1
2323
6256
10.0
12.0
C5
1,00
1,00
4.77
4.77
10.0
12,0
4,77
47.7
10.0
12.0
Cu
0,700
0.700
3,50
3,99
2,00
12.0
8.35
35*0
10.0
12.0
OIC
70,0
70.0
1672
6187
5,00
11.8
3344
3.09E+04
5,00
11.8
DOC
90.0
90.0
540
1.05E+04
1.00
12.1
1080
2.76E+04
5.00
11.8
Fe
2.90
2,30
(1.45)
(1.45)
10.0
12.0
(1-45)
|145)
10,0
12.0
r
1.00
1.00
(0.500)
(0.500)
10.0
12.0
(0.500)
{5,00}
10.0
12.0
Hg
0,00600
0.00600
(0.00300)
0.00900
1.00
12,1
(0.00600)
(0.0300)
10.0
12.0
K
1.50
1.50
2024
1.04E+O4
1,00
12.1
1.04E+04
2.02E+04
10.0
12.0
m
1.00
1.00
(0.500)
990
1,00
12.1
(1.00)
990
1.00
12.1
Mn
0.340
0.340
1.71
4.83
10.0
12.0
4.13
48,3
10.0
12.0
MO
0,760
0.760
1985
1.09E+04
1.00
12,1
1.03E+04
1.99E+04
10,.0
12.0
Report Date: 25-ian-2017
page 9
-------
EPA Method 1316
Sample: CaFA {6,1,1}
Assessment
Reporting Limit (mg/l} Concentration {mg/L} Release (mg/kg)
mm
max
mm
max
mas of L/S
max at pH
min
max
max at L/S
max atpH
m
330
3.50
4727
3.37E+04
LOO
12,1
3.37E+04
4.73E+C4
10.0
12.0
Hi
0.730
0.730
15.7
67.9
2.00
12,0
65,4
172
5.00
11.8
NO/
1.00
1.00
(0,500]
(0.500)
10,0
12.0
(0.500)
15.00}
10,0
12.0
NO,"
475
475
3321
2.61E+04
1.00
12.1
2.61E+04
5.35E+04
5.00
11.8
Ph
0.230
0.230
2,5§
35.3
1.00
12,1
25,6
51,9
2.00
12.0
po/'
2080
2080
{1040)
(1040}
10,0
12,0
(1040)
(1.04E+Q4)
10.0
12.0
Re
0,240
0.240
4,59
25.3
1.0Q
12-1
23.0
45.9
10.0
12.0
Sb
0,0800
0.0800
2.7 S
2.78
iO.O
12,0
2.78
27.B
10,0
12.0
Se
0.520
0.520
224
333
io.o
12,0
224
3386
10.0
12.0
Si
2.80
2.80
53S
1.63E+04
i.OO
12.1
1077
3.38E+04
10,0
12.0
Sr>
0,700
0.700
3.49
3.49
io.o
12.0
3.49
34.5
10.0
12,0
so/"
505
505
1.15E+05
2.68E+Q5
2.00
12,0
2.58E+G5
1.15E+06
10.0
12.0
Sr
1..00
1.00
1793
1.38E+04
i.OO
12,1
1.38E+04
1.32E+04
5.00
11.8
Ti
1,00
1.00
{0,500|
(0.500)
io.o
12,0
(0.500)
(5-00)
10.0
12,0
Ts
0.510
0.510
2.53
2.53
10.0
12,0
2.53
25,3
10.0
12.0
U
0.300
0.300
1,33
1,33
10,0
12,0
1.33
13.3
10,0
12.0
V
0.310
0.310
58.3
363
10,0
12.0
58.3
3627
10.0
12.0
Zn
0.920
0.920
33.8
SO.5
1.00
12,1
80,5
350
10.0
12.0
Report Date: 25-ian-2017 pag<
Leaching Environmental Assessment Framework (LEAF) How-To Guide Appendix
Appendix B:Graphical and Tabular LEAF Results for Case Study (Section 5)
------- |