&EPA g^,protec,ior Analytical Methods Approved for Compliance Monitoring under the Long Term 2 Enhanced Surface Water Treatment Rule Analysis for the following contaminants shall be conducted in accordance with the methods in the following table, or their equivalent as determined by EPA. The methods for Cryptosporidium are listed at 40 CFR 141.704, the methods for enumeration of E. coli in source water are listed in Table 1H at 40 CFR 136.3(a) and the methods for turbidity are listed at 40 CFR 141.74. Additional approved methods are listed in Appendix A to Subpart C of Part 141. The CFR is the legal reference for approved methods and takes precedence over this table. The table should accurately reflect the analytical methods information published in 40 CFR 141. If discrepancies are found, please notify the Safe Drinking Water Hotline (800- 426-4791) so that EPA can correct the table. Contaminant Cryptosporidium: Systems must analyze at least a 10 L sample or a packed pellet volume of at least 2 mL. Systems unable to process a 10 L sample must analyze as much sample volume as can be filtered by two filters approved by EPA for the methods listed, up to a packed pellet volume of at least 2 mL. Method Organization Reference Title Date EPA Publication Number 1622 EPA Cryptosporidium in Water by Filtration/IMS/FA December 2005 EPA-815-R-05-001 1623 EPA Cryptosporidium and Giardia in Water by Filtration/IMS/FA December 2005 EPA-815-R-05-002 1623.1 EPA Cryptosporidium and Giardia in Water by Filtration/IMS/FA January 2012 EPA-816-R-12-001 Office of Water (MS - 4606 M) EPA 821-F-17-001 February 2017 ------- Page 2 of 12 Contaminant Escherichia coli: The time from sample collection to initiation of analysis may not exceed 30 hours. The State may approve on a case-by-case basis the holding of an E.coli sample for up to 48 hours between sample collection and initiation of analysis if the State determines that analyzing an E.coli sample within 30 hours is not feasible. E. coli samples held between 30 to 48 hours must be analyzed by the Colilert reagent version of Standard Method 9223B as listed in § 136.3 (a) Table 1H of this title. Systems must maintain samples between 0°C and 10°C during storage and transit to the laboratory. Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. Method Organization Reference Title Date Notes 9221B.2 F- 2006 Standard Methods Online Online version. Approval year is designated by the last 4 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. 2006 Samples shall be enumerated by the multiple-tube or multiple-well procedure. Using multiple-tube procedures, employ an appropriate tube and dilution configuration of the sample as needed and report the Most Probable Number (MPN). The multiple-tube fermentation test is used in 9221B.2-2006. Lactose broth may be used in lieu of lauryl tryptose broth (LTB), if at least 25 parallel tests are conducted between this broth and LTB using the water samples normally tested, and this comparison demonstrates that the false-positive rate and false-negative rate for total coliform using lactose broth is less than 10 percent. No requirement exists to run the completed phase on 10 percent of all total coliform-positive tubes on a seasonal basis. After prior enrichment in a presumptive medium for total coliform using 9221B.2-2006, all presumptive tubes or bottles showing any amount of gas, growth or acidity within 48 + 3 h of incubation shall be submitted to 9221 F- 2006. Commercially available EC-MUG medium or EC medium supplemented in the laboratory with 50 ng/mL of MUG may be used. 9223 B-2004 Colilert® Standard Methods Online Online version. Approval year is designated by the last 4 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. 2004 Multiple tube or multiple well These tests are collectively known as defined substrate tests, where, for example, a substrate is used to detect the enzyme p-glucuronidase produced by E. coli Descriptions of the Colilert®, Colilert-18®, and Quanti-Tray® may be obtained from IDEXX Laboratories Inc. ------- Page 3 of 12 Method Organization Reference Title Date Notes 9223 B-2004 Colilert-18® Standard Methods Online Online version. Approval year is designated by the last 4 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. 2004 Multiple tube or multiple well These tests are collectively known as defined substrate tests, where, for example, a substrate is used to detect the enzyme p-glucuronidase produced by E. coli Colilert-18® is an optimized formulation of the Colilert® for the determination of total coliforms and E.coli that provides results within 18 h of incubation at 35° C, rather than the 24 h required for the Colilert® test, and is recommended for marine water samples. Descriptions of the Colilert®, Colilert-18®, and Quanti-Tray® may be obtained from IDEXX Laboratories Inc. 991.15 Colilert® AOAC International Official Methods of Analysis of AOAC International, 16th Edition, Volume 1, Chapter 17 1995 Multiple tube or multiple well These tests are collectively known as defined substrate tests, where, for example, a substrate is used to detect the enzyme p-glucuronidase produced by E. coli Descriptions of the Colilert®, Colilert-18®, and Quanti-Tray® may be obtained from IDEXX Laboratories Inc. 991.15 Colilert-18® AOAC International Official Methods of Analysis of AOAC International, 16th Edition, Volume 1, Chapter 17 1995 Multiple tube or multiple well These tests are collectively known as defined substrate tests, where, for example, a substrate is used to detect the enzyme p-glucuronidase produced by E. coli Colilert-18® is an optimized formulation of the Colilert® for the determination of total coliforms and E.coli that provides results within 18 h of incubation at 35° C, rather than the 24 h required for the Colilert® test, and is recommended for marine water samples. Descriptions of the Colilert®, Colilert-18®, and Quanti-Tray® may be obtained from IDEXX Laboratories Inc. ------- Page 4 of 12 Method Organization Reference Title Date Notes 1103.1 EPA EPA Method 1103.1: Escherichia coli (E.coli) in Water by Membrane Filtration Using membrane- Thermotolerant Escherichia coli Agar (mTEC), EPA-821-R- 10-002, March 2010. 2010 A 0.45-nm membrane filter (MF) or other pore size certified by the manufacturer to fully retain organisms to be cultivated and to be free of extractables which could interfere with their growth. Because the MF technique usually yields low and variable recovery from chlorinated wastewaters, the Most Probable Number method will be required to resolve any controversies. Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. When the MF method has not been used previously to test waters with high turbidity, large numbers of nonconform bacteria, or samples that may contain organisms stressed by chlorine, a parallel test should be conducted with a multiple-tube technique to demonstrate applicability and comparability of results. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. ------- Page 5 of 12 Method Organization Reference Title Date Notes 9222 B- 2006/9222 G- 2006 Standard Methods Online Online version. Approval year is designated by the last 4 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. 2006 A 0.45-nm membrane filter (MF) or other pore size certified by the manufacturer to fully retain organisms to be cultivated and to be free of extractables which could interfere with their growth. Because the MF technique usually yields low and variable recovery from chlorinated wastewaters, the Most Probable Number method will be required to resolve any controversies. Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. When the MF method has not been used previously to test waters with high turbidity, large numbers of nonconform bacteria, or samples that may contain organisms stressed by chlorine, a parallel test should be conducted with a multiple-tube technique to demonstrate applicability and comparability of results. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. Subject total coliform positive samples determined by 9222B-2006 or other membrane filter procedure to 9222G-2006 using NA-MUG medium. ------- Page 6 of 12 Method Organization Reference Title Date Notes 9222 D/9222 G Standard Methods Standard Methods for the Examination of Water and Wastewater, 20th edition 1998 A 0.45-nm membrane filter (MF) or other pore size certified by the manufacturer to fully retain organisms to be cultivated and to be free of extractables which could interfere with their growth. Because the MF technique usually yields low and variable recovery from chlorinated wastewaters, the Most Probable Number method will be required to resolve any controversies. Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. When the MF method has not been used previously to test waters with high turbidity, large numbers of noncoliform bacteria, or samples that may contain organisms stressed by chlorine, a parallel test should be conducted with a multiple-tube technique to demonstrate applicability and comparability of results. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. Subject total coliform positive samples determined by 9222B-2006 or other membrane filter procedure to 9222G-2006 using NA-MUG medium. ------- Page 7 of 12 Method Organization Reference Title Date Notes 9213 D-2007 Standard Methods Online Online version. Approval year is designated by the last 4 digits. Only online versions cited in the regulations or in Appendix A to Subpart C of Part 141 are approved. 2007 A 0.45-nm membrane filter (MF) or other pore size certified by the manufacturer to fully retain organisms to be cultivated and to be free of extractables which could interfere with their growth. Because the MF technique usually yields low and variable recovery from chlorinated wastewaters, the Most Probable Number method will be required to resolve any controversies. Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. When the MF method has not been used previously to test waters with high turbidity, large numbers of nonconform bacteria, or samples that may contain organisms stressed by chlorine, a parallel test should be conducted with a multiple-tube technique to demonstrate applicability and comparability of results. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. ------- Page 8 of 12 Method Organization Reference Title Date Notes D5392-93 ASTM International Annual Book of ASTM Standards - Water and Environmental Technology. Section 11.02. 1996 A 0.45-nm membrane filter (MF) or other pore size certified by the manufacturer to fully retain organisms to be cultivated and to be free of extractables which could interfere with their growth. Because the MF technique usually yields low and variable recovery from chlorinated wastewaters, the Most Probable Number method will be required to resolve any controversies. Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. When the MF method has not been used previously to test waters with high turbidity, large numbers of noncoliform bacteria, or samples that may contain organisms stressed by chlorine, a parallel test should be conducted with a multiple-tube technique to demonstrate applicability and comparability of results. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. ------- Page 9 of 12 Method Organization Reference Title Date Notes D5392-93 ASTM International Annual Book of ASTM Standards - Water and Environmental Technology. Section 11.02. 1999 A 0.45-nm membrane filter (MF) or other pore size certified by the manufacturer to fully retain organisms to be cultivated and to be free of extractables which could interfere with their growth. Because the MF technique usually yields low and variable recovery from chlorinated wastewaters, the Most Probable Number method will be required to resolve any controversies. Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. When the MF method has not been used previously to test waters with high turbidity, large numbers of nonconform bacteria, or samples that may contain organisms stressed by chlorine, a parallel test should be conducted with a multiple-tube technique to demonstrate applicability and comparability of results. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. ------- Page 10 of 12 Method Organization Reference Title Date Notes A 0.45-nm membrane filter (MF) or other pore size certified by the manufacturer to fully retain organisms to be cultivated and to be free of extractables which could interfere with their growth. Because the MF technique usually yields low and variable recovery from chlorinated wastewaters, the Most Probable Number method will be required to resolve any controversies. D5392-93 ASTM International Annual Book of ASTM Standards - Water and Environmental Technology. Section 11.02. 2000 Tests must be conducted to provide organism enumeration (density). Select the appropriate configuration of tubes/filtrations and dilutions/volumes to account for the quality, character, consistency, and anticipated organism density of the water sample. When the MF method has not been used previously to test waters with high turbidity, large numbers of noncoliform bacteria, or samples that may contain organisms stressed by chlorine, a parallel test should be conducted with a multiple-tube technique to demonstrate applicability and comparability of results. To assess the comparability of results obtained with individual methods, it is suggested that side-by-side tests be conducted across seasons of the year with the water samples routinely tested in accordance with the most current Standard Methods for the Examination of Water and Wastewater or EPA alternate test procedure (ATP) guidelines. 1603 EPA EPA Method 1603: Escherichia coli (E. coli) in Water by Membrane Filtration Using Modified membrane-Thermotolerant Escherichia coli Agar (Modified mTEC), EPA-821-R- 14-010, September 2014. 2014 1604 EPA EPA Method 1604: Total Coliforms and Escherichia coli (E.coli) in Water by Membrane Filtration by Using a Simultaneous Detection Technique (Ml Medium), EPA 821-R-02-024, September 2002. 2002 Preparation and use of Ml agar with a standard membrane filter procedure is set forth in the article, Brenner et al. 1993. New Medium for the Simultaneous Detection of Total Coliform and Escherichia coli in Water. Appl. Environ. Microbiol. 59: 3534-3544 ------- Page 11 of 12 Method Organization Reference Title Date Notes mColiBlue- 24® Hach Company A description of the mColiBlue24® test may be obtained from Hach Company. Water Quality Parameters Turbidity: §141.704(c) Systems must use methods for turbidity measurement approved in 141.74 (a] Method Organization Reference Title Date Notes 2130 B Standard Methods Standard Methods for the Examination of Water and Wastewater, 18th Edition 1992 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stabilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin 2130 B Standard Methods Standard Methods for the Examination of Water and Wastewater, 19th Edition 1995 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin 2130 B Standard Methods Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin 2130 B Standard Methods Standard Methods for the Examination of Water and Wastewater, 21st Edition 2005 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin 2130 B Standard Methods Standard Methods for the Examination of Water and Wastewater, 22nd Edition 2012 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin 180.1 EPA Methods for the Determination of Inorganic Substances in Environmental Samples, EPA/600/R-93/100, August 1993 1993 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin Method 2 Great Lakes Instruments Great Lakes Instruments Method 2, Turbidity, November 2, 1992 1992 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin 1). ------- Page 12 of 12 Method Organization Reference Title Date Notes 10133 Hach Hach FilterTrak Method 10133 Determination of Turbidity by Laser Nephelometry January 2000 Revision 2.0 2000 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stabilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin M5271 Leek Mitchell Mitchell Method M5271, Revision 1.1, Determination of Turbidity by Laser Nephelometry, March 5, 2009 2009 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin M5331 Leek Mitchell Mitchell Method M5331, Revision 1.1, Determination of Turbidity by LED Nephelometry, March 5, 2009 2009 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin AMI Turbiwell Swan Analytische Instrumente AG Continuous Measurement of Turbity Using ASWAN AMI Turbiwell Turbidimeter, August 2009 2009 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin AQ4500 Thermo Scientific Orion Method AQ.4500, Revision 1.0, Determination of Turbidity by LED Nephelometry, May 8, 2009 2009 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin M5331, Rev. 1.2 Leek Mitchell Mitchell Method M5331, Revision 1.2, Determination of Turbidity by LED or Laser Nephelometry, February 2016 2016 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin 10258 Hach Company Hach Method 10258, Determination of Turbidity by 360° Nephelometry, January 2016 2016 Styrene divinyl benzene beads (e.g. AMCO-AEPA-1 or equivalent) and stablilized formazin (e.g. Hach StablCal™ or equivalent) are acceptable substitutes for formazin ------- |