EP.A-600-R-92-025 February 1992 INDOOR AIR QUALITY DATA BASE FOR ORGANIC COMPOUNDS by Max M. Samfield (Consultant) U. S. Environmental Protection Agency Air and Energy Engineering Research Laboratory Indoor Air Branch Research Triangle Park, NC 27711 Project Officer: Bruce A. Tichenor Prepared for: U. S. Environmental Protection Agency Office of Research and Development Washington, DC 20460 ------- TECHNICAL REPORT DATA {Please read Instructions on the reverse before completi- 1. RFPORT NO. EPA-600-R-92-02 5 2. 3 PB92-158U68 4. title and subtitle Indoor .Air Quality Data Base for Organic Compounds 5. REPORT DATE February 1992 6. PERFORMING ORGANIZATION CODE 7. AUTHOR(S) Max M. Samfield 8. PERFORMING ORGANIZATION REPORT NO. 9. PERFORMING ORGANIZATION NAME AND ADDRESS 10. PROGRAM ELEMENT NO. See Block 12 11. CONTRACT/GRANT NO. NA (Inhouse) 12. SPONSORING AGENCY NAME AND ADDRESS EPA, Office of Research and Development 13. TYPE OF REPORT AND PERIOD COVERED Final report; 1-11/91 Air and Energy Engineering Research Laboratory Research Triangle Park, North Carolina 27711 14. SPONSORING AGENCY CODE EPA/600/13 i5. supplementary notes project officer is Bruce A. Tichenor, Mail Drop 54, 919/ 541-2991. 16. abstract rpj^e rep0rt gives results of the compilation of a data base for concentra- tions of organic compounds measured indoors. Based on a review of the literature from 1979 through 1990, the data base contains information on over 220 compounds ranging in molecular weight from 30 to 446. The compounds are arranged in order of increasing number of carbon atoms, from 1 to 31. The data base contains the number of carbon atoms; the name of the compound; its empirical formula; its molecular weight; the odor threshold (when available); the minimum, maximum, median, and mean concentrations; the standard deviation; the reference number; the sampling time; and the type of building. All concentration data are given in micro- grams per cubic meter. The following compounds were the most frequently reported: formaldehyde, tetrachloroethylene, 1,1,1-trichloroethane, trichloroethylene, ben- zene, p-dichlorobenzene, toluene, ethylbenzene, xylenes, decane, and undecane. A- bout 50% of the reported compounds contained 9 carbon atoms or fewer, and 90% hnd 23 carbon atoms or fewer. Sampling times for the pollutants varied from as little as 15 minutes to as long as 2 weeks. Grab sampling, real time sampling, and integrated sampling methods were used. Odor thresholds for the reported pollutants were, in general, three to five orders of magnitude higher than those measured. •; 17. KEY WORDS AND DOCUMENT ANALYSIS a- DESCRIPTORS b.IDENTIFIERS/OPEN ENDED TERMS c. COSATI Field/Group Pollution Organic Compounds Data Pollution Control Stationary Sources Data Bases Indoor Air 13 B 07C 14G 18. DISTRIBUTION STATEMENT Release to Public 19. SECURITY CLASS (This Report) Unclassified 21. NO. OF PAGES 73 20. SECURITY CLASS (This page) Unclassified 22. PRICE EPA Form 2220-1 (9-73) i ------- ABSTRACT A data base for concentrations of organic compounds measured indoors has been compiled. Based on a review of the literature from 1979 through 1990, the data base contains information on over 220 compounds ranging in molecular weight from 30 to 446. The compounds are arranged in order of increasing number of carbon atoms - from one to thirty-one. The data base is presented in a 13 column table containing the following information: number of carbon atoms, name of compound, empirical formula, molecular weight, odor threshold (when available), minimum, maximum, median, and mean concentrations, standard deviation, reference number, sampling time, and type of building. All concentration data are given in //g/m3. The following compounds were the most frequently reported: formaldehyde, tetrachloroethylene, 1,1,1- trichloroethane, trichloroethylene, benzene, p-dichlorobenzene, toluene, ethylbenzene, xylenes, decane, and undecane. About 50% of the reported compounds contained nine carbon atoms or fewer, and 90% had 23 carbon atoms or fewer. Sampling times for the pollutants varied from as little as 15 minutes to as long as two weeks. Grab-sampling, real time sampling, and integrated sampling methods were used. Odor thresholds for the pollutants reported were, in general, three to five orders of magnitude higher than the measured concentrations. ------- CONTENTS Abstract - — ii Introduction 1 Data Base Description 1 Observations 3 Appendix A: Indoor Air Quality Data Base of Organic Compounds A-1 Appendix B: Sources of Indoor Organic Compounds B-1 Appendix C: References C-1 iii ------- INTRODUCTION Several years ago it was determined that many pollutants found in ambient air were present to a larger extent in indoor air. Thus, it was recognized that indoor air might present problems with regard to potential health effects. Since most of the efforts directed toward ambient air analysis were with respect to the criteria pollutants, it was natural that these pollutants would be the first to be studied in indoor air. In indoor air, pollutants such as carbon dioxide, carbon monoxide, nitrogen oxides, and particulate matter have been extensively studied. Of the organic compounds, particularly the volatile organic compounds (VOCs), only formaldehyde has been extensively studied in indoor air. Yet many sources of organic compounds in indoor air have their origins in commonly used materials. Such materials include caulking compounds, hair sprays, rug cleaners, and paints and varnishes. In addition, building materials and interior furnishings (such as furniture, floor tile, draperies, and rugs) may be sources of organic compounds. It was felt that there was a need to develop a data base for concentrations of organic compounds found in indoor air. The initial requirements for such a data base were: (a) It should be computerized in such a manner that additional compounds could easily be added; (b) The organic compounds should be arranged by the number of carbon atoms in the molecule; (c) The data base should contain a reference list; and (d) There should also be a data base listing the sources and potential sources of the organic compounds in the primary data base. The purpose of this report is to provide workers in the field with a hard copy of the current data base. Since the data base is updated periodically, computer disks are not being made available. Updates to the current report are planned. DATA BASE DESCRIPTION Appendix A presents the data base. It contains approximately 220 organic compounds ranging from 1-carbon atom compounds to 31-carbon atom compounds. These compounds range in molecular weight from 30 to 446. The compounds are arranged in order of increasing number of carbon atoms. The data are taken from the references listed in Appendix C. Reference numbers are listed in the column labeled REF in the data base. The odor threshold values in the fifth column of the primary data base were taken from the following references: 1 ------- Amoore, J. E., and E. Hautala, "Odor as an Aid to Chemical Safety: Odor Thresholds Compared with Threshold Limit Values and Volatilities for 214 Industrial Chemicals in Air and Water Dilutions," Journal of Applied Toxicology. Vol.3, No. 6, p. 272, 1983. Fazzalari, F. A., Compilation of Odor and Taste Threshold Values Data. ASTM Data Series DS 48A, American Society for Testing and Materials, Philadelphia, PA, 1978. Hellman, T. M., and F. H. Small, "Characterization of the Odor Properties of 101 Petrochemicals Using Sensory Methods," Journal of the Air Pollution Control Association. Vol. 24, No. 10, p. 979, 1974. Leonardos, G., D. Kendall, and N. Barnard, "Odor Threshold Determinations of 53 Odorant Chemicals," Journal of the Air Pollution Control Association. Vol. 19, No. 2, p. 91, 1969. Ruth, J. H., "Odor Thresholds and Irritation Levels of Several Chemical Substances: A Review," Journal of the American Industrial Hygiene Association, p. A-142, March, 1986. Summer, W., Odour Pollution of Air: Causes and Control. CRC Press, Cleveland, OH, 1971. In cases where several odor threshold values are given for the same compound, the values may differ by as much as an order of magnitude. This should not be surprising in view of the subjective judgement required in such tests. Also, different investigators used different test methods and the number of subjects involved varied considerably. In some cases, impurities in the test materials may have altered the results. In many cases, the literature data had to be converted from ppm or ppbv to /;g/m3. Minimum, maximum, median, and/or mean concentrations (in //g/m3) are presented in the appropriate column. In those cases where compounds were identified but not quantified, all the columns are blank. In most cases, decimal notation is used; for very large and very small numbers, scientific notation is used. The standard deviations of the data are also given, when available. The column labeled TIME (second from last column) is the sampling time in hours, except where otherwise indicated. In this column, a "D" indicates the time in days and a "W" indicates weeks. 2 ------- In the column labeled BLDG. TYPE, the type of building investigated is given as follows: A = Apartment; AU = Automobile; CB = Commercial Building; H = Hospital; MH = Mobile Home; NH = Nursing Home; OB = Office Building; R = Residence; S = School; and V = Various types of buildings. Appendix B contains information on "Sources of Indoor Organic Compounds." It lists substantiated and possible sources for most of the indoor pollutants contained in the data base. The information in Appendix B should be used with some caution, because the composition of materials and products changes over time as manufacturers alter their manufacturing processes and products. OBSERVATIONS A review of the data shows concentrations of pollutants ranging from below the quantification level to more than 80,000 //g/m3. There is a paucity of data on the standard deviation of concentration values reported in the literature. It is important for users of the data to know the standard deviation in order to know how much confidence to place in the reported values. Other than listing the standard deviation, when reported, this report makes no effort to judge the quality of the data. To do this, the reader should obtain a copy of the reference and use his or her own judgement. About 50% of the compounds listed contained 9 carbon atoms or fewer; about 90% had 23 carbon atoms or fewer. The following compounds were the most frequently reported: formaldehyde, tetrachloroethylene, 1,1,1-trichIoroethane, trichloroethylene, benzene, p- dichlorobenzene, toluene, ethylbenzene, xylenes, decane, and undecane. Sampling times for the pollutants varied widely - from as little as 15 minutes to as long as two weeks. Grab sampling, real time sampling, and integrated sampling were used. Odor thresholds for the pollutants were, in general, three to five orders of magnitude higher than the concentrations actually measured. One cannot, therefore, expect to detect the presence of a pollutant through odor alone. 3 ------- Appendix A Indoor Air Quality Data Base of Organic Compounds (Abbreviations are defined at end of Appendix.) c COMPOUND FORMULA MOL. WT. ODOR pg/m' MEAS. CONC. S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 1 FORMALDEHYDE CH20 30 60-200 62 27 1 4-7D R, A 1470 78 96 2 8-24 R 106 114 2 6-24 R 62 62 2 6-24 R 40 62 2 6-24 R 146 112 2 6-24 R 131 69 2 6-24 R 319 144 2 6-24 R 319 76 2 6-24 R <13.7 634 2.01 18 1W MH <13.7 626 2.11 18 1W MH 18.4 634 1.96 18 1W MH 20.3 428 1.73 18 1W MH 20.3 416 1.79 18 1W MH 31.4 428 1.61 18 1W MH 36-237 23 24 OB 8-166 23 24 R 48-424 23 24 S 14-46 23 24 S 8-166 23 24 36-199 23 24 49 36 6 OB 49 9 6 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. (M/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 1 METHYLENE CHLORIDE CH2CI2 86 6.60e + 06 286 3 0.26-3 R 6.40e + 05 286 3 0.26-3 R 6000 670 1 4-7D R, A 14.3 9.4 6 R 1 CARBON TETRACHLORIDE CCI4 164 1.26e + 06 14 2.2 2.6 2 4 6-12 V 3.00e + 05 46 16 6 12 6.3 1 4-7D R, A 26 <4 6 8-168 R 6 <4 6 8-168 R 26 <4 6 8-168 R 11 0.6 17 12 R 4 0.2 17 12 R 2 0.3 17 12 R 1 17 12 R 0.4 17 12 R 2 0.6 17 12 R 46 6 R 10.13 33.2 6 R 1 CHLOROFORM CHCI3 119 3.30e + 06 200 3.4 8 21 4 6-12 V 2.60e + 06 6.9 3 0.26-3 R 16 1.9 1 4-70 R. A 110 <11 16 6-12 R 96 <12 16 6-12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR ^g/m5 MEAS. CONC. (pg/m't S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 1 CHLOROFORM CHCI3 119 68 <8 16 6-12 R 26 <6 16 6-12 R 63 <11 16 6-12 R 28 <6 16 6-12 R 36 <6 16 6-12 R 210 6.9 17 12 R 34 4.4 17 12 R 16 4.6 17 12 R 6 1.3 17 12 R 18 1.8 17 12 R 6 0.8 17 12 R 43.9 42 6 R 0.066 3.39 32 R 1 BROMODICHLOROM ETHANE CBrCI2 162 4 6-12 V 1 DIBROMOCHLOROMETHANE CBr2CI 207 4 6-12 V 1 DICHLOROMETHANE CH2CI2 84 0.66 7.84 32 R 2.6 32.4 37 OB 1 BROMOFORM CHBr3 263 4 6-12 V ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR (/g/m3 MEAS. CONC. (wj/m't S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 1 TRICHLOROFLUOROMETHANE (F-11) CCI3F 137 86.7 230 39 1 4-7 D R, A 28,000 26.6 48 37 OB 2 1,1 DICHLOROETHYLENE C2H2CI2 07 4.30e + 06 10.7 6.8 6 R 13 12 6 R 2 TETRACHLOROETHYLENE C2CI4 166 3.20e + 06 260 6.4 10 26 4 6-12 V 31,400 18 16 6 21 3 0.26-3 R 21 3 0.26-3 R 47 18 1 4-7 D R, A 107 6.3 7 2-3 MH 49 <2 6 8-168 R 206 <2 6 8-168 R 182 <2 6 8-168 R <1.0 617 4.6 12 14 2W R 11 <2 16 6-12 R 4 <1 16 6-12 R 61 <1 16 6-12 CB 62 <1 16 6-12 CB 13 <4 16 6-12 H 8 <4 16 6-12 R 220 <4 16 6-12 R 240 6.7 17 12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR W/mJ MEAS. CONC. U/Q/m5} S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 2 TETRACHLOROETHYIENE C2CI4 166 97 6.9 17 12 R 67 16 17 12 R 7B 7.6 17 12 R 63 3 17 12 R 3 1.7 17 12 R 2 1,1,1-TRICHLOROETHANE C2H3CI3 133 2.10e + 06 880 60 126 4 6-12 V 14 3 0.26-3 R 183 3 0.26-3 R 60 21 1 4-7D R, A <1.0 264 4.3 7.9 14 2W R 260 41 16 6-12 R 63 24 16 6-12 R 1000 <6 16 6-12 R 360 <4 16 6-12 R 86 <6 16 6-12 R 26 <5 16 6-12 R 100 62 16 6-12 R 14 16 OB 17 16 OB 7 16 OB 40.98 16 OB 10.69 16 S 3.09 16 NH ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. Ovg/m'> S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 2 1,1,1 -TRICHLORO ETHAN E C2H3CI3 133 870 48 17 12 R 110 9.2 17 12 R 170 36 17 12 R 170 9.2 17 12 R 87 9.3 17 12 R 12 2.8 17 12 R 13.6 119.7 37 OB 2 TRICHLOROETHANE C2H3CI3 133 7.2 68.2 37 OB 2 TRICHLOROETHYLENE C2HCI3 131 1.36e + 06 47 2.3 3.6 6.2 4 6-12 V 10.2 6.8 6 26 3 0.26-3 R 86 18 1 4-7D R, A 11 <2 6 8-168 R 106 <2 6 8-168 R 30 <2 6 8-168 R <1.0 1200 4.6 13 14 2W R 32 1.1 17 12 R 32 1.3 17 12 R 7 2.4 17 12 R 49 2.8 17 12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR pg/m3 MEAS. CONC. (//g/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 2 TRICHLOROETHYLENE C2HCI3 131 11 1.1 17 12 R 4 0.8 17 12 R 10.2 6 R 36,000 32 OB 32,000 72,000 32 R 19,000 81,000 32 R 2 VINYUDENE CHLORIDE C2H2CI2 97 2.00e+ 06 4 6-12 V 2 1,2-DICHLOROETHANE C2H4CI2 99 4.60a + 06 4 6-12 V 12.3 9.6 6 R 2.06 36 12 H 1.49 36 12 H 2.21 36 12 H 4.61 36 12 OB 2 ETHYLAMINE C2H7N 46 110 760 10 486 1.7 10 2 ACETIC ACID C2H402 60 38,000 600 10 2,600 16.7 10 40 244 1 4-7 OB, R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR /Aj/m3 MEAS. CONC. fc/g/m'l S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 2 ACET ALDEHYDE C2H40 44 1,980 48 17 1 4-7D R, A 20 2.1 24 8 OB 2 ETHANOl C2H60 46 93,000 767 3 0.26-3 R 2.07e + 06 1374 3 0.26-3 R 408 3 0.26-3 R 2 N-NITROSO-DIMETHYLAMINE C2H6N20 74 0.33 0.17 8 AU 3 PROPANE C3H8 44 1.80e + 06 42 3 0.26-3 R 3 ISOPROPANOL (PROPANOL-2) C3H80 60 90,000 140 3 0.26-3 R 268 3 0.26-3 R 80 3 0.26-3 R 6.9 24 8 OB 14.8 137 37 OB 3 ACETONE (PROPANONE) C3H60 68 7.70e + 06 167 39 1 4-7D R, A 2.12« + 06 7.6 24 8 OB 47,600 28.8 67 37 OB 3 LACTIC ACID C3H603 90 1.60e + 06 1.8 10 OB 0.6 10 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR MEAS. CONC. UAj/m3) S.D. REF. TIME h BLDO. TYPE MIN MAX MEDIAN MEAN 3 PYRUVIC ACID C3H403 88 6.8 10 OB 6.1 10 OB 3 1,2-DICHLOROPROPANE C3H6CI2 113 46 160 1 4-7D R 3 1,3-DICHLOROPROPENE C3H4CI2 111 62.4 36 6 R 3 DIBROMOCHIOROPROPANE C3H5Br2CI 237 96 4 6-12 V 4 ETHYLACETATE C4H802 88 3.68e + 06 1.0 204 6.8 12 14 2W R 19.6 9 26 1 4-7D R 4.8 24 8 OB 4 BUTANE C4H10 68 16,900 440 3 0.26-3 R 440 3 0.26-3 R 408 3 0.26-3 R 679 3 0.26-3 R 4 ISOBUTANE C4H10 58 1967 3 0.26-3 R 4 DIETHYLAMINE C4H11N 73 76 10 OB 4 DIMETHYLACET AMIDE C4H100N 88 1.61e + 06 4767 10 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR /JQ/m3 MEAS. CONC. U/g/m'J S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 4 1,4-DlOXANE C4H802 88 7.07 4 26 12 R 10.8 1 26 12 R 4 N-BUTANOL C4H100 74 33,000 81 18 7 2-3 MH 3.26e + 05 <1 11 < 1 1 14 2W R 4 l-BUTANOL C4H100 74 33,000 <1 20 2 3 14 2W R 20 1 4-7D R 4 BUTANAL C4H80 72 788 34 2.7 1 4-7D R, A 4 2-BUTANONE (MEK) C4H80 72 8,400 38 7.9 1 4-7D R. A 737 <1.0 26 6.3 6.2 14 2W R 6.2 41 37 OB 4 DICHLORVOS (DDVP) C4H704CI2P 221 0.6 10 21 R 2.3 0.12 28 24 R 0.021 1.48 0.086 43 24 R 0.001 0.002 0.003 43 24 R 4 2-ETHOXY-ETHANOL (CElLOSOLVEl C4H1002 90 220 6 60 1 4-7D R 2,040 4 CHLOROETHYL VINYL ETHER C4H7CI0 106 26.1 16 6 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. (w/m3» S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 4 N-NITROSOMORPHOLINE C4H8N02 102 0.6 0.13 8 AU 5 PENTANE C6H12 72 6,600 102 3 0.26-3 R 327 3 0.26-3 R 36 3 0.26-3 R 423 3 0.26-3 R 5 l-AMYL ALCOHOL CBH120 78 36,000 <1 10 <1 1 3 26,200 3 6 PROPYL ACETATE C6H1002 102 210 0.8 24 8 OB 5 2-M ETHYL BUTANE {ISOPENTANE) C6H12 72 166 3 0.26-3 R 1224 3 0.25-3 R 117 3 0.26-3 R 699 3 0.26-3 R 31.9 81.6 37 OB 6 2-PENTANONE C6H100 86 0.037 31 6 N-HEXANE C6H14 86 6.60e + 06 39 3 0.26-3 R 79 3 0.26-3 R 11 3 0.26-3 R 240 3 0.26-3 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR VQfm3 MEAS. CONC. (//gAn3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 6 N-HEXANE C6H14 86 690 71 1 4-7D R, A 338 6 6 8-168 R 107 4 6 8-168 R 178 3 6 8-168 R 2 46 7.9 9.0 14 2W R 19 24 8 OB 10 24 37 OB 6 CYCLOHEXANE C6H12 84 1,190 26 2 6 8-168 R 1,440 22 1 6 8-168 R 366 1 6 8-168 R <1.0 29 6.8 7.4 14 2W R 6 CYCLOHEXANONE C6H100 98 626 1 6 1 4-7D R 480 6 2-HEXANONE (N-BUTYL KETONE) C6H120 100 0.87 24 8 OB 6 HEXANAL C6H120 100 39 63 10 1 4-7D R, A <1.0 11 1 2 13 6 4-METHYL-2-PENTANONE C6H120 102 2,100 <1.0 12 <1.0 1.0 14 2W R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR /yg/m3 MEAS. CONC. (/jg/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 6 METHYLCYCLOPENTANE C6H12 84 273 3 0.26-3 R 2.1 79 13 16 14 2W R 6 2-METHYLPENTANE (ISOHEXANE) C6H14 86 289 47 3 0.26-3 R 104 3 0.26-3 R 36 3 0.26-3 R 662 3 0.26-3 R 2.1 24 8 OB 6 3-METHYLPENTANE C6H14 86 64 3 0.26-3 R 7 3 0.26-3 R 190 3 0.26-3 R 3 6 8-168 R 101 3 6 8-168 R 62 2 6 8-168 R 1.6 24 8 OB 6 BENZENE C6H6 78 1.80c + 06 120 13 20 22 4 6-12 V 4,500 9.4 4.1 6 140 3 0.26-3 R 176 3 0.26-3 R 78 3 0.26-3 R 6338 3 0.26-3 R 204 62 1 4-7D R. A 24 7 6 8-168 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR #/Q/m3 MEAS. CONC. S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 6 BENZENE C6H0 78 148 7 6 8-168 R 63 6 6 8-168 R <1.0 39 7.8 9.3 14 2W R 120 12 17 12 R 61 2.6 17 12 R 42 16 17 12 R 40 1.6 17 12 R 27 4.9 17 12 R 21 4.6 17 12 R 9.4 4.1 6 R 1.66 36 12 H 2.13 36 12 H 2.88 36 12 H 2.74 36 12 OB 4.96 36 12 OB 1.70 36 12 NH 2.44 36 12 NH 6.61 36 12 OB 4.60 36 12 S 3.13 36 12 NH 6 CHLOROBENZENE C6H6CI 112 1,060 4 6-12 6.8 4.8 6 3 <0.4 6 8-168 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m* MEAS. CONC. fc/g/m5) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 6 CHLOROBENZENE C6H6CI 112 <0.4 <0.4 6 8-168 R 27 <0.4 6 8-168 R 6 O-DICHLOROBENZENE C0H4CI2 147 12,000 4 6-12 V 33 62 6 1.2 0.6 7 2-3 MH 6 M-DICHLOROBENZENE C6H4CI2 147 4 6-12 V 13 3.9 6 B.6 1.6 7 2-3 MH 6.0 <0.6 6 8-168 R 9.0 <0.6 6 8-168 R 6.0 <0.6 6 8-168 R 6 P-DICHLOROBENZENE C6H4C12 147 90,000 686 3 0.26-3 R 1005 3 0.26-3 R 172 3 0.26-3 R 230 66 1 4-7D R, A 69 7.9 7 2-3 MH 299 <0.6 6 8-168 R 138 2.0 6 8-168 R 240 <0.6 6 8-168 R 28 <22 16 6-12 R 12 <2 16 6-12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) > i o> c COMPOUND FORMULA MOL. WT. ODOR ^g/m3 MEAS. CONC. (M/ml S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 6 P-DICHLOROBENZENE C6H4CI2 147 470 <3 16 6-12 R 600 <2 16 6-12 R 84 <4 16 6-12 R 69 <6 16 6-12 R 67 <1 16 6-12 R 6 M.P-DICHLOROBENZENE C6H4CI2 147 1200 3.4 41 160 4 6-12 V <1.0 1270 4.7 22 14 2W R 910 40 17 12 R 1600 44 17 12 R 120 14 17 12 R 190 16 17 12 R 170 14 17 12 R 7 0.9 17 12 R 6 1,2,3-TRICHLOROBENZENE C6H3CI3 181 3 <0.8 6 8-168 R 3 <0.8 6 8-168 R 28 <0.8 6 8-168 R 6 1,2,4-TRICHLOROBENZENE C6H3CI3 181 6 <0.8 6 8-168 R 16 <0.8 6 8-168 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR ^g/m3 MEAS. CONC. (//g/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 6 1,3,6-TRICHLOROBENZENE C6H3CI3 181 33 <0.8 6 8-168 R <0.8 6 8-168 R 8 <0.8 6 8-168 R 6 <0.8 6 8-168 R 6 HEXACHLOROBENZENE C6CI0 286 0.021 0.00126 28 24 R 6 TETRACHLOROPHENOL C6H2CI40 231 29 R 6 GAMMA-BHC C6H6CI6 201 0.245 0.0202 28 24 R 6 2-ETHOXYETHYLACETATE C6H1203 132 300 2.16 16 12 CB 9.68 16 12 CB 1.31 16 12 CB 1.67 16 12 CB 6 PENTACHLOROPHENOL C6HCI60 266 3.1 22 3-8 OB 38 22 3-8 OB 6 ALPHA-BHC C6H6CI6 291 0.032 0.0012 28 6 ISO-BUTYLACETATE C6H1202 116 2,180 100 1 4-7D R 17,000 1.0 33 1.0 2.0 14 2W R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR j/g/m3 MEAS. CONC. fc/g/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN e BUTYLACETATE C6H1202 116 33,100 6 34 1 4-7D R 36,000 1.4 24 8 OB 38,000 1.0 204 3.1 6.1 14 2W R 2.63 16 OB 1.48 16 S 16 NH 6.34 36 12 OB 1.22 36 12 N 2.63 36 12 OB 1.48 36 12 S 7 TOLUENE C7H8 92 1,40e + 06 4 6-12 V 44,000 27 16.6 6 8,030 68 27 2 6-24 R 17,600 62 96 6 666 62 2 6-24 R 41 27 6 84 3 0.26-3 R 314 3 0.26-3 R 60 3 0.26-3 R 272 3 0.26-3 R 378 128 1 4-7D R, A 40 0 7 2-3 MH 626 23 6 8-168 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR pg/m3 MEAS. CONC. (//g/m3) S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 7 TOLUENE C7H8 92 697 40 6 8-168 R 2262 43 6 8-168 R 11 678 62 76 14 2W R 27.2 6 R 96.1 6 R 7 BUTYL ACRYLATE C7H1202 128 31.4 48 10 OB 11 17 10 OB 7 M ETHYLCYCLOHEXAN E C7H14 98 2.00e + 06 33 2 6 8-168 R 60 1 6 8-168 R 604 1 6 8-168 R 1.1 61 3.6 6.6 14 2W R 1.1 24 8 OB 7 HEPTANE (3-METHVLHEXANEl C7H16 100 9.30e + 06 70 16 1 4-7D R, A 4.40e + 06 30 3 6 8-168 R 2.00e4 06 68 3 6 8-168 R 666 2 6 8-168 R 1.6 82 8 7 14 2W R 7.8 24 8 OB 3.1 12.6 37 OB 4.0 14.7 37 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR Vg/m3 MEAS. CONC. Oaj/ttO S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 7 1-HEPTENE U-HEPTYLENE) C7H14 98 3.2 16.6 38 4 OB 7 2-METHYLHEXANE C7H16 100 19 3 6 8-168 R 64 2 6 8-168 R 278 2 8 8-168 R 0.6 0.2 39 6W CB 14 2 6 8-168 R 44 2 6 8-168 R 233 1 6 8-168 R 0.6 0.2 39 6W CB 7 DIM ETHYLCYCLOPENTANES C7H14 98 9 <1 6 8-168 R 13 <1 6 8-168 R 148 <1 6 8-168 R 7 BENZALDEHYDE C7H60 106 3,700 2 30 1 4-7D R 8 17.8 36 6 R 20.7 28 6 R 8 ETHYLBENZENE C8H10 106 400 320 6.9 13 34 4 6-12 V 8,700 4.4 3.2 6 12 4.4 2 6-24 R 10.6 21 6 161 10.6 2 6-24 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR /AJ/m3 MEAS. CONC. (M/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 8 ETHYLBENZENE C8H10 106 22 3 0.26-3 R 35 3 0.26-3 R 109 27 1 4-7D R, A 117 2 6 8-168 R 46 3 6 8-168 R 138 2 6 8-168 R 1.6 161 6.6 10 14 2W R 66 <4 16 6-12 R 19 <3 16 6-12 R 17 <3 16 6-12 R 12 <3 16 6-12 R 27 <4 16 6-12 R 60 <4 16 6-12 R 800 <6 16 6-12 R 63 16 OB 64 16 OB 47 16 OB 10.2 16 OB 2.69 16 S 0.97 16 NH 310 8.8 17 12 R 170 6.1 17 12 R 28 7.6 17 12 R 22 -0.7 17 12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR #/g/ m5 MEAS. CONC. fc/o/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 8 ETHYLBENZENE C8H10 106 33 2.2 17 12 R 9 2.4 17 12 R 4.4 3.2 6 R 10.6 21 6 R 8 STYRENE C8H8 104 2,100 64 3.1 6.9 4 6-12 V 430 36 3.0 7 2-3 MH 202 <1.0 41 1.2 2.6 14 2W R 63 1.9 17 12 R 9 1.6 17 12 R 10 1.9 17 12 R 6 17 12 R 2 0.4 17 12 R 4 0.3 17 12 R <1 9 1 4-7D R 1.00 36 12 H 1.07 36 12 H 1.33 36 12 H 2.62 36 12 OB 2.87 36 12 OB 2.99 36 12 N 1.27 36 12 N 2.36 36 12 OB 1.32 36 12 S ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. 0/g/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 8 STYRENE C8H8 104 1.19 36 12 N 8 XYLENES C8H10 106 I.OOe + 06 2076 10 OB 348 1B5 10 OB 169 9 6 8-168 R 178 12 6 8-168 R 763 10 6 8-108 R 120 8.1 17 12 R 160 10 17 12 R 61 16 17 12 R 41 17 12 R 86 7.6 17 12 R 26 7.7 17 12 R 16.6 16 6 R 44.2 91 6 R 8 O-XYLENE C8H10 106 4,600 48 6.2 7.8 8.6 4 6-12 V 36 3 0.26-3 R 18 3 0.26-3 R 1312 3 0.26-3 R 132 26 1 4-7D R, A 112 9.1 7 2-3 MH 1.2 46 4.9 7.0 14 2W R 47 <6 16 6-12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //fl/m3 MEAS. CONC. t/ig/m3) S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 8 O-XYLENE C8H10 106 18 <6 16 6-12 R 24 <6 16 6-12 R 14 <6 16 6-12 R 18 <6 16 6-12 R 64 <6 16 6-12 R 420 <7 16 6-12 R 44 3.0 17 12 R 94 6.2 17 12 R 19 6.3 17 12 R 26 0.2 17 12 R 27 2.3 17 12 R 11 3.2 17 12 R 8 M.P-XYIENE C8H10 106 120 16 21 24 4 6-12 V 17 16 6 64 17 2 6-24 R 44 91 6 697 44 2 6-24 R 13 3 0.26-3 R 106 3 0.26-3 R 40 3 0.26-3 R 266 3 0.26-3 R 390 1 4-7D R, A 346 7 ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. OOOR /Aj/m3 MEAS. CONC. 0/g/m5) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 8 M.P-XYLENE C8H10 106 3.3 304 16 23 14 2W R 170 20 16 6-12 R 61 <8 16 6-12 R 74 16 16 6-12 R 46 17 16 6-12 R 76 11 16 6-12 R 160 17 16 6-12 R 1200 13 16 6-12 R 8 M-XYLENE C8H10 106 830 4 6-12 V 36 3 0.26-3 R 2261 3 0.26-3 R 6.88 36 12 H 3.13 36 12 H 9.91 36 12 H 41.63 36 12 OB 16.06 36 12 OB 23.8 36 12 NH 6.33 36 12 NH 27.11 36 12 OB 8.72 36 12 S 2.96 36 12 NH ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //fl/m3 MEAS. CONC. U/g/ms) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 8 P-XYLENE C8H10 106 3,100 18 3 0.26-3 R 769 3 0.26-3 R 8 DIMETHYL BENZENE (1,2) C8H10 106 8.7 26 37 OB 8 DIMETHYL BENZENE (1,3-1,4) C8H10 106 18.1 64.6 37 OB 8 1-OCTENE («-OCTYLENE) C8H10 124 2.1 38 4 OB 8 ISOOCTANE (2-METHYL-HEPTANE1 C8H18 114 1.006 + 06 62 3 0.26-3 R 1.8 24 8 OB 1.8 8 37 OB 8 N-OCTANE (TRIMETHYL PENTANE) C8H18 114 7.10e + 06 66 14 1 4-7D R, A 1.00e + 06 36 1 6 8-168 R 7.26c+ 06 60 2 6 8-168 R 633 1 6 8-168 R <1.0 64 2.8 4.9 14 2W R 36 1.9 17 12 R 19 2.1 17 12 R 2 1.0 17 12 R 1.8 24 8 OB 1.8 8 37 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR j/g/m3 MEAS. CONC. S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 8 2-BROMOOCTANE (OCTYL BROMIDE) C8H17Br 193 1.1 24 8 OB 8 2-ETHYLHEXANOL C8H190 113 399 <1 10 <1 2 14 2W R 8 RONNEL C8H803CI3PS 322 0.2 2 21 R 0.02 1.6E-4 28 24 R 8 2,4 -D C8H6CI203 221 0.048 0.0018 28 24 R 8 CHLOROTHALONIL C8C14N2 266 0.264 0.00691 28 24 R 8 ATRA2INE C8H14CIN6 216 28 24 R 8 DIMETHYLCYCLOHEXANE C8H16 122 3.1 37 OB 1.3 39 6W CB 8 M ETH YL-M ETHYL-ETH EN YL- CYCLOHEXENE C8H17 116 0.361 31 8 ETHENYL BENZENE C8H8 104 0.146 31 8 DIMETHYLBENZENE C8H10 106 0.782 31 8 TRIM ETHYL-PENTAN EDIOL C8H1802 146 0.236 31 ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. (po/ml S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 9 NONANE C9H20 128 3.40e + 06 76 3 0.26-3 R 60,000 166 27 1 4-7D R, A 3.41e + 06 278 3 6 8-168 R 269 4 6 8-168 R 407 6 6 8-168 R 98 10.6 2 6-24 R 36 6.4 2 6-24 R <1.0 101 4.2 9.7 14 2W R 10.6 149 37 OB 9 2,6-DlM ETHYL-H EPTAN E C9H20 128 1.6 24 8 OB 9 ETHYL TOLUENE C9H12 120 20 3 0.26-3 R 40 3 0.26-3 R 9 2-ETHYL TOLUENE C9H12 120 0.8 1.3 38 4 OB 9 3-ETHYL TOLUENE C9H12 120 12 26.6 38 4 OB 9 4-ETHYL TOLUENE C9H12 120 7.3 7.6 38 4 OB 9 TRIMETHYLCYCLOHEXANE (1,3,6) C9H22 130 4,600 1,200 37 24 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR ^g/m5 MEAS. CONC. U/g/ml S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 9 METHYL ETHYL CYCLOHEXANE C9H18 126 3.8 0.3 39 6W CB 3.0 0.2 39 6W CB 9 O-ETHYLTOLUENE C9H12 120 186 3 0.26-3 R 0.66 36 12 H 8.89 36 12 OB 2.08 36 12 OB 4.01 36 12 N 0.73 36 12 N 1.60 36 12 OB 0.74 36 12 S 9 M.P-ETHYLTOLUENE C9H12 120 405 3 0.26-3 R 9 M-ETHYLTOLUENE C9H12 120 26 16 OB 31 16 OB 26 16 OB 6.07 16 08 2.62 16 S 0.9 16 NH 9 CUMENE C9H12 120 147 30 3 0.26-3 R 39 7 2.2 2 6-24 R 13 1.3 2 6-24 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m5 MEAS. CONC. S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 9 CUMENE C9H12 120 10.6 26 6 R 6.4 6.8 6 R 9 QUINOLINE C9H7N 129 40,900 0.0013 0.016 11 8 R 0.031 0.0012 11 8 R 9 ISOQU1NOLINE C9H7N 129 0.014 0.00093 11 8 R 0.001 0.01 11 8 R 9 INDANE (HYDRINDENE) C9H10 118 20 1 4-7D R 9 1,2,3 TRIMETHYLBENZENE C9H12 120 18B 3 0.26-3 R 24 <0.3 6 8-168 R 40 1 6 8-168 R 16 <0.3 6 8-168 R <1.0 83 1.9 3.6 14 2W R 9 1,2,4 TRIMETHYLBENZENE C9H12 120 460 20 3 0.26-3 R 60 3 0.26-3 R 976 3 0.26-3 R 160 1 4-7D R, A 166 4 6 8-168 R 276 6 6 8-168 R 400 6 6 8-168 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL WT. ODOR j/g/m3 MEAS. CONC. U/g/m5} S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 9 1,2,4 TRIMETHYLBENZENE C9H12 120 <1.0 312 6.4 11 14 2W R 72 16 OB 92 16 OB 66 16 OB 6.28 16 OB 2.8 16 S 0.98 16 NH 9 1,3,6 TRIMETHYLBENZENE C9H12 120 4,500 69 13 1 4-7D R, A (MESITYLENE) 37 1 6 8-168 R 99 2 6 8*168 R 93 2 6 8-168 R 2 1.4 2 6-24 R 39 6.7 2 6-24 R <1.0 111 2 3.9 14 2W R 1.4 0.7 6 R 6.7 9.2 6 R 4.1 37 OB 9 N-PROPYLBENZENE C0H12 120 100 18 <0.3 6 8-168 R 27 1.0 6 8-168 R 16 0.4 6 8-168 R 6.0 36 12 OB 1.13 36 12 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //fl/m* MEAS. CONC. (M/m3) S.O. REF. TIME h BLDG. TYPE M1N MAX MEDIAN MEAN 9 N-PROPYLBENZENE C9H12 120 2.99 36 12 N 0.70 36 12 N 1.22 36 12 N 0.66 36 12 S 9 1 + N-PROPYIBENZENE C0H12 120 <1.0 89 3 4.6 14 2W R 9 ISOPROPYLBENZENE C9H12 120 120 6 <0.3 6 8-168 R 11 0.3 6 8-168 R 10 <0.3 6 8-168 R 0.31 36 12 H 0.33 36 12 H 3.94 36 12 OB 0.67 36 12 OB 2.27 36 12 N 0.33 36 12 N 0.79 36 12 OB 0.36 36 12 S 9 O-METHYLETHYLBENZENE C9H12 120 1.000 61 1.0 6 8-168 R 72 2.0 6 8-168 R 166 1.0 6 8-168 R <1.0 103 2.3 4.4 14 2W R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR f^fm3 MEAS. CONC. (wj/m3) S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 9 M-METHYLETHYLBENZENE C9H12 120 1,000 82 3.0 6 R 166 3.0 6 R 227 3.0 6 R 9 P-METHYLETHYLBENZENE C9H12 120 1,000 64 1.0 6 R 77 2.0 6 R 94 2.0 6 R 9 0 + P-METHYLETHYLBENZENE C9H12 120 <1.0 229 6.0 8.9 14 2W R 9 NONANAL C9H1BO 142 374 82 12 1 4-7D R, A 44 13 7 2-3 MH 9 1-NONENE (NONYLENE1 C9H18 126 0.2 38 4 OB 9 CHLORPYRIFOS C9H11CI3N03PS 361 0.023 2.2 0.17 0.47 19 24 R 0.B1 34.6 20 R 0.014 16 2.4 27 24 R 2.2 0.17 0.36 28 24 R 0.118 0.28 0.198 43 24 R 0.006 0.007 0.00660 43 24 R 9 CAPTAN C9H8CL3N02S 301 0.044 0.00186 28 24 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL WT. ODOR #/Q/m* MEAS. CONC. (M/mt S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 9 FOLPET C9H4CI3N02S 297 0.074 0.00678 28 24 R 10 DECANE C10H22 142 11,000 18 3 0.26-3 R 148 3 0.26-3 R 1100 92 1 4-7D R, A 807 8.0 6 8-168 R 433 9.0 6 8-168 R 906 14 6 8-168 R 39 12 2 6-24 R 81 8.9 2 6-24 R <1.0 136 6.8 14 14 2W R 160 21 16 6-12 R 64 18 16 6-12 R 110 <7 16 6-12 R 38 <6 16 6-12 R 17 <3 16 6-12 R 49 <8 16 6-12 R 360 13 16 6-12 R 420 16 OB 620 16 06 370 16 OB 2.26 16 OB 6.98 16 S 1.87 16 NH ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. fc/g/m5) S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 10 DECANE C10H22 142 8 17 12 R 16 1.6 17 12 R 21 0.7 17 12 R 12.4 12 6 R 8.9 12 6 R 10 N-BUTYLBENZENE C10H14 134 30 0.8 6 8-168 R 40 0.9 6 8-168 R 20 1.0 6 8-168 R 10 1,2 OIETHYLBENZENE C10H14 134 0.2 3.6 38 4 OB 10 1,3-DIETHYLBENZENE C10H14 134 0.5 38 4 OB 10 1,2.3,6-TETRAMETHYLBENZENE C10H14 134 1.7 38 4 OB 10 1,2,4,6-TETRAMETHYLBENZENE C10H14 134 3.1 38 4 OB 10 P-METHYUSOPROPYLBENZENE C10H14 134 11 0.6 6 8-168 R 32 0.7 6 8-168 R 10 1.0 6 8-168 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR fiQl m' MEAS. CONC. fc/g/m'l S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 10 LIMONENE C10H16 136 66 23 3 0.26-3 R 10 232 3 0.26-3 R 34 3 0.26-3 R 480 140 1 4-7D R, A 165 12 7 2-3 MH 773 18 6 8-168 R 216 26 6 8-168 R 693 46 6 8-168 R 24 10.3 2 6-24 R 167 20.8 2 6-24 R <1.0 316 11 26 14 2W R 10.3 7.9 6 R 20.8 32 6 R 10 PINENE C10H16 130 847 23 3 0.26-3 R 10 •-PIN EN E C10H16 136 16 606 102 1 4-7D R, A 77 13 7 2-3 MH <1.0 97 7.7 11 14 2W R 16 16 08 16 16 OB 12 16 OB 16 OB 2.66 16 S ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //Q/m5 MEAS. CONC. (//g/nrv1) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 10 •-PINENE C10H16 136 16 NH 39 6.0 17 12 R 29 4.0 17 12 R 3 1.2 17 12 R 10 b-PINENE C10H16 136 104 17 1 4-7D R, A <1.0 11 <1.0 1.3 14 2W R 10 a-TERPINENE C10H16 136 2,330 <1.0 37 2.9 4.1 14 2W R 1.0 38 4 OB 10 CAMPHENE C10H16 136 1.00c+ 06 278 26 7 2-3 MH 1.4 38 4 OB 10 CAMPHOR C10H160 162 8,760 3 14 1 4-7D R 7,800 10 NAPHTHALENE (TETRALIN) C10H12 132 38.800 37 3 0.26-3 R 1,600 70 11 1 4-7D R, A 63 9.4 7 2-3 MH 4 <0.3 6 8-168 R 14 <0.3 6 8-168 R 7 <0.3 6 8-168 R 76 9.4 2 6-24 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. CfQ/nv5) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 10 NAPHTHALENE (TETRALIN) C10H12 132 676 17.6 2 6-24 R <1.0 14 2.1 2.3 14 2W R 1 80 1 R 9.4 21 6 R 17.6 78 6 R 10 CHLORDANE C10H6CI8 410 26.7 6 3.3 12 4 R 8.4 0.23 5.6 1.6 19 24 R 2.76 1.33 12 4 R 4.7 2.66 12 4 R 4.48 3.94 12 4 R 2.80 3.32 12 4 R 3.32 1.38 12 4 R 6.01 0.97 12 4 R 0.30 0.28 12 4 R 1.61 1.13 12 4 R 4.48 1.70 12 4 R 2.39 2.06 12 4 R 3.32 1.06 12 4 R 2.34 0.78 12 4 R 6.81 6.01 12 4 R 2.77 2.69 12 4 R 3.00 87.7 20 R 0.191 0.212 0.206 43 24 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR //g/m3 MEAS. CONC. (//g/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 10 CHLORDANE C10H6CI8 410 0.036 0.263 0.144 43 24 R 10 MALATHION C10H1706PS2 330 14,700 3.00 130 6.06 20 R 13,600 0.1 10 21 R 0.2 2 21 R 0.021 28 24 R 10 DACTHAL C10H6CW04 332 0.00042 28 24 R 1.7 0.61 27 24 R 10 EUCALYPTOLE (CINEOLE) C10H180 154 36 1 4-7D R 3.0 0.076 0.324 28 24 R 10 HEPTACHLOR C10H6CI7 370 333 2 1.2 12 4 R 306 0.016 1.6 0.4 19 24 R 0.01 0.01 12 4 R 1.41 0.64 12 4 R 1.06 0.41 12 4 R 1.18 0.28 12 4 R 1.27 0.24 12 4 R 1.80 1.47 12 4 R 1.00 0.47 12 4 R 0.31 0.088 27 24 R 1.6 0.16 28 24 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL WT. ODOR //g/m3 MEAS. CONC. U/g/m'l S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 10 HEPTACHLOR C10H6C17 370 0.064 0.134 0.099 43 24 R 0.005 0.036 0.02 43 24 R 10 NICOTINE C10H14N2 162 3.08e + 06 -0.0003 13 168 OB -0.0006 13 168 OB 14 10 OB <0.022 10 OB 10 •-DECYLENE (DECENE-11 C10H20 140 1.0 76.8 38 4 OB 10 p-CYMENE C10H14 134 0.4 84 38 4 OB 11 UNDECANE C11H24 166 23,000 69 3 0.26-3 R 960 80 1 4-7D R, A 41 4.3 7 2-3 MH 229 3.0 6 8-168 R 191 6.0 6 8-168 R 446 9.0 6 8-168 R 38 8.2 2 6-24 R 116 12 2 6-24 R <1.0 88 6.7 10 14 2W R 280 32 16 6-12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) > i ¦F* c COMPOUND FORMULA MOL. WT. ODOR /Aj/m5 MEAS. CONC. (pg/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 11 UNDECANE C11H24 166 120 30 16 6-12 R 63 <4 16 6-12 R 31 <6 16 6-12 R 11 <3 16 6-12 R 11 <3 16 6-12 R 140 10 16 6-12 R 210 16 08 220 16 OB 200 16 OB 2.86 16 OB 6.77 16 S 16 NH 9 1.1 17 12 R 72 3.6 17 12 R 16 2.6 17 12 R 8.2 9 6 R 12.0 18 6 R 11 1 -METHYLNAPHTH ALENE C11H10 142 0.6 <0.3 6 8-168 R 2.0 <0.3 6 8-168 R 0.9 <0.3 6 8-168 R 2 6 1 4-7D R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR M/m® MEAS. CONC. (//g/m3) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 11 2-METHYLNAPHTHALENE C11H10 142 96 7 2.6 2 6-24 R 68 17 2.6 2 6-24 R 10 14 1 4-7D R 2.6 1.9 6 R 2.6 4.2 6 R 11 PROPOXUR C11H16N03 209 0.047 7.9 0.7 19 24 R 0.66 0.23 27 24 R 7.92 0.093 0.628 28 24 R 0.141 0.316 0.239 43 24 R 0.011 0.016 0.014 43 24 R 11 BENDIOCARB C11H13N04 223 1.6 0.086 28 24 R 12 DODECANE C12H26 170 37,000 220 20 1 4-70 R, A 40 1 6 8-168 R 118 2 6 8-168 R 96 4 6 8-168 R 10 4.2 2 6-24 R 676 13.7 2 6-24 H <1.0 36 3.7 6.6 14 2W R 8 1.7 17 12 R 64 3.1 17 12 R 4 1.1 17 12 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR MQ/m3 MEAS. CONG. (//g/m3( S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 12 DODECANE C12H26 170 4.2 3 6 R 13.7 74 6 R 12 DIAZINON C12H21N203PS 304 0.069 13.7 1.1 19 24 R 0.61 34.6 2.6 20 R 0.2 2 21 R 8.8 1.4 27 24 R 13.7 0.073 0.42 28 24 R 0.089 0.322 0.206 43 24 R 0.001 0.01 0.0066 43 24 R 12 ALDRIN C12H8CI6 366 263 1.40 1.66 1.48 20 R 0.3 26 R 0.12 26 R 1.4 26 R 1.03 26 R 1.84 0.031 28 R 12 ORTHO-PH ENYLPH ENOL C12H100 170 1.04 0.062 0.096 28 24 R 0.04 0.08 0.06 43 24 R 0.027 0.043 0.07 43 24 R 12 4-PH EN YLCYCLOH EX EN E (4-PC) C12H14 168 2.1 <0.1 70 30 A, OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL WT. ODOR fjQ/m3 MEAS. CONC. (M/m3) S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 12 UNDECENE-1 (UNDECYLENE-*) C12H22 166 0.8 38 4 OB 12 LAURIC ACID C12H2402 200 2.68«-<-06 0.0016 33 84 OB 13 TRIDECANE C13H28 184 20 3.1 1 4-7D R, A 13 1 6 8-168 R 18 1 6 8-168 R 38 2 6 8-168 R 6 2.3 2 6-24 R 113 16.6 2 6-24 R <1.0 79 4.7 6.3 14 2W R 2.3 1.3 6 R 16.6 26 6 R 6.0 112 37 OB 13 TRIDECANOIC ACID (TRIDECYLIC) C13H2602 214 0.0006 33 84 OB 14 MYRISTIC ACID (TETRADECANOIC) C14H2802 228 1.02e + 06 0.006 33 84 OB 0.0006 33 84 OB 14 TETRADECANE C14H30 198 67 7 2-3 MH 7 6 8-168 R 8 6 8-168 R 46 6 8-168 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR j/Q/m3 MEAS. CONC. U/o/m3» S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 14 TETRADECANE C14H30 198 6 2 6-24 R 76 2 6-24 R 7.6 10 6 R 3.2 1.3 6 R 36.1 246 37 OB 14 PHENANTHRENE C14H10 178 0.072 0.06 11 8 R 0.13 0.1 11 8 R 14 ANTHRACENE C14H10 178 0.0037 0.0029 11 0.0081 0.0068 11 16 PENTADECANE C16H32 212 3 0.9 6 8-168 R 4 1.0 6 8-168 R 6 2.0 6 8-168 R 6 2.8 2 6-24 R 12 1.9 2 6-24 R 2.8 6 R 1.9 2.4 6 R 16 NONYLPHENOL ISOMERS C16H240 220 -0.030 13 168 OB -0.016 13 168 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR j/g/m3 MEAS. CONC. (M/m3) S.D. REF. TIME h BLD6. TYPE MIN MAX MEDIAN MEAN 16 PENTADECANOIC ACID C16H3002 242 0.002 33 84 OB 0.0001 33 84 OB 16 DIBUTYLPHTHALATE C16H2204 278 -0.0002 13 168 OB 16 HEXADECANE C16H34 226 2 0.8 6 8-168 R 3 0.3 6 8-168 R 4 1.0 6 8-168 R 6 3.7 2 6-24 R 21 3.8 2 6-24 R 3.7 6 R 3.8 4.7 6 R 16 HEXADECANE (BRANCHED) C16H34 226 -0.0002 13 168 OB -0.004 13 168 OB 16 FLUORANTHENE C16H10 202 -0.023 -0.016 11 8 R -0.037 -0.028 11 8 R 16 PYRENE C16H10 202 0.011 0.0075 11 8 R 0.018 0.013 11 8 R 16 1-NITROPYRENE C16H902N 247 6.90e-06 2.60e-06 11 8 R ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR ^g/m3 MEAS. CONC. toj/m5) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 16 3-NITROFLUORANTHENE C16H0O2N 247 0.00014 6.00e-06 11 8 R 16 PALMITIC ACID C16H3202 266 1.14e + 08 0.06 33 84 OB 0.008 33 84 OB 17 HEPTADECANOIC ACID (MARGARICJ C17H3402 270 0.003 33 84 OB 0.0001 33 84 OB 17 OLEIC ACID C17H3402 282 0.0036 33 84 OB 0.0002 33 84 OB 18 CHRYSENE C18H12 228 0.0014 0.0012 11 8 R 0.003 0.0062 11 8 R 18 CYCLOPENTA(C,D)PYRENE C18H10 226 0.00069 0.00062 11 8 R 0.00062 0.00029 11 8 R 18 BENZO(A)ANTHRACENE C18H12 228 0.00067 0.00064 11 8 R 0.0022 0.0013 11 8 R 18 STEARIC ACID C18H3602 284 1.90o + 08 0.046 33 84 OB 0.006 33 84 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR py/m3 MEAS. CONC. t^g/m') S.D. REF. TIME h BLDQ. TYPE MIN MAX MEDIAN MEAN 19 BUTYLBENZYLPHTHALATE C19H2004 312 -0.020 13 168 OB -0.001 13 168 OB 19 NONADECANOIC ACID C19H3802 298 0.002 33 84 OB 20 ABIETIC ACID (SYLVIC) C20H3002 302 0.001 33 84 OB 20 BENZOFLUORANTHENES C20H12 262 0.0018 0.0016 11 8 R 0.0068 0.0034 11 8 R 20 BENZOtAJPYRENE C20H12 262 0.0011 0.00092 11 8 R 0.0033 0.002 11 8 R 20 BENZO(E)PYRENE C20H12 262 0.001 0.00091 11 8 R 0.0031 0.002 11 8 R 20 ARACHIDIC ACID (EICOSANOIC) C20H4002 313 0.011 33 84 OB 21 HENEICOSANOIC ACID C21H4202 326 0.006 33 84 OB 22 DIHEPTYLPHTHALATE C22H3404 362 -0.001 13 168 OB 22 BEHENIC ACID (DOCOSANOIC) C22H4402 341 0.013 33 84 OB 0.0003 33 84 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR j/Q/m3 MEAS. CONC. U/Q/m5) S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 22 INDENO|1,2,3-C,D)PYRENE C22H12 276 0.0009 0.0008 11 8 R 0.0026 0.0016 11 8 R 23 N-TRICOSANE C23H48 326 -0.002 13 168 OB -0.003 13 168 OB 24 N-TETRACOSANE C24H60 339 -0.003 13 168 OB -0.004 13 168 OB 24 Dl (2-ETHYLH EXYLtPHTH ALATE C24H3804 390 -0.056 13 168 OB -0.020 13 168 OB 24 TRIS(2-ETHYLHEXYUPHOSPHATE C24HB104P 434 -0.006 13 168 OB 24 LIGNOCERIC ACID C24H4802 369 0.0066 33 84 OB 24 BENZO(G,H,l)PERYLENE C24H14 302 0.0017 0.0016 11 8 R 0.0028 0.0022 11 8 R 24 CORONENE C24H12 300 0.0031 0.0014 11 8 R 0.0017 0.0013 11 8 R 24 TRICOSANOIC ACID C24H4802 368 0.0066 33 84 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR j/g/m3 MEAS. CONC. OAj/m'j S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 26 N-PENTACOSANE C26H62 363 -0.004 13 168 OB 26 BIS(2-ETHYLHEXYL)AZELATE C26H4804 413 -0.008 13 168 OB -0.010 13 168 OB 26 DINONYL PHTHALATE C26H4204 418 -0.016 13 168 OB 26 PENTACOSANOIC ACID C26H6202 396 0.001 33 84 OB 26 N-HEXACOSANE C26H64 367 -0.007 13 168 OB -0.006 13 168 OB 27 N-HEPTACOSANE C27H56 381 -0.040 13 168 OB -0.020 13 168 OB 27 HEXACOSANOIC ACID C27H6402 410 0.001 33 84 OB 28 DIDECYL PHTHALATE C28H4604 446 -0.020 13 168 OB 28 N-OCTACOSANE C28H68 396 -0.010 13 168 OB -0.006 13 168 OB 29 N-NONACOSANE C29H60 409 -0.040 13 168 OB -0.026 13 168 OB ------- Indoor Air Quality Data Base Of Organic Compounds (Cont.) c COMPOUND FORMULA MOL. WT. ODOR VQtm' MEAS. CONC. to/ml S.D. REF. TIME h BLDG. TYPE MIN MAX MEDIAN MEAN 30 N-TR1ACONTANE C30H62 423 — 0.030 13 168 06 -0.016 13 168 OB 30 TRIACONTANE (BRANCHED) C30H62 423 -0.030 13 168 OB -0.020 13 168 OB 31 N-HENTRIACONTANE C31H64 437 -0.140 13 168 OB -0.100 13 168 OB 31 HENTRIACONTANE (BRANCHED) C31H64 437 -0.075 13 168 OB -0.066 13 168 OB - Definitions : BLDG. TYPE is the type of building investigated: A = Apartment; AU = Automobile; CB = Commercial Building; H = Hospital; MH = Mobile Home; NH = Nursing Home; OB = Office Building; R = Residence; S = School; and V = Various types of buildings. TIME is the sampling time in hours, except: D = days and W = weeks. - Refer to Appendix C for References. ------- Appendix B Sources of Indoor Organic Compounds c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 1 FORMALDEHYDE CH20 Unvented radiant gas apace heaters, upholstery fabric, latex backed fabric, plywood, particle board, paneling, new clothing, fiberglass, paper plates & cups, ceiling panels, duct liners, unvented convective kerosene space heaters, unvented range-top cast iron burner, unvented gas oven, unvented one year old oven, urea foam insulation, floor covering, wallpaper caulking compounds, jointing compound, floor varnish, adhesive, fiberboard, chipboard, linoleum, floor lacquer, calcium silicate sheet, needle felt, gypsum board, insulation sheets, tobacco smoke, auto exhaust melamine resins, acetal resins, phenolic resins 1 METHYLENE CHLORIDE CH2CI2 paint removers, aerosol finishers, degreasing solvent 1 CARBON TETRACHLORIDE CCI4 grease cleaners, adhesives, foam insulation, inks rodenticides, fluorocarbons 11/12 1 CHLOROFORM CHCI3 weter, adhesives, foam insulation, inks fluorocarbon 22 1 BROMODICHLOROMETHANE CBrCI2 1 DIBROMOCHLOROMETHANE CBr2CI 1 BROMOFORM CHBr3 medicinals 1 TRICHLOROFIUOROMETHANE (F-11) CCI3F refrigerant 2 TETRACHLOROETHYLENE C2CI4 dry cleaning, adhesives, foam insulation, inks 2 1,1,1 -TRICHLOROETHANE C2H3CI3 dry cleaning, cleaning fluid 2 TRICHLOROETHYLENE C2HCI3 adhesives, foam insulation, inks, photo films, tape, coatings, lubricants, rubber solvent for paints and varnishes, dry cleaning 2 VINYLIDENE CHLORIDE C2H2CI2 2 1,2-DICHLOROETHANE C2H4CI2 adhesives, foam insulation, tape 2 ETHYLAMINE C2H7N 2 ACETIC ACID C2H402 tobacco smoke food preservative, cooking, solvent for gums, resins, volatile oils, textiles 2 ACETALDEHYDE C2H40 auto exhaust perfumes, flavors, dyes, tobacco smoke B-1 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 2 ETHANOL C2H60 fiberboard solvent, antifreeze, tobacco smoke 2 N-NITROSO-DIMETYLAM1NE C2H6N20 auto interior furnishings gasoline 3 PROPANE C3H8 auto exhaust fuel gas, refrigerant, tobacco smoke 3 ISOPROPANOL C3H80 particle board antifreeze, solvent for gums, shellac, essential oils, cosmetics 3 ACETONE (PROPANONE) C3H60 lacquer solvent, auto exhaust tobacco smoke, pharmaceuticals 3 LACTIC ACID C3H603 3 PYRUVIC ACID C3H403 medicinal ointments 3 1,2-DICHLOROPROPANE C3H6CI2 3 DIBROMOCHLOROPROPANE C3H5Br2CI 4 ETHYLACETATE C4H802 linoleum floor covering artificial fruit essences, solvent for varnishes & lacquers, perfume, artificial leather 4 BUTANE C4H10 fuel, tobacco smoke 4 ISOBUTANE C4H10 fuel 4 DIETHYLAMINE C4H11N resins, dyes, pharmaceuticals, synthetic rubber 4 DIMETHYLACETAMIDE C4H100N solvent for many organic reactions 4 N-BUTYLACETATE C4H1002 floor lacquer 4 I-BUTYIACET ATE C4H10O2 floor lacquer 4 1,4-DIOXANE C4H802 solvent for many oils, waxes, dyes, cellulose acetate 4 N-BUTANOL C4H10O edge sealing molding tape, jointing compound, cement flagstone, linoleum flavors, perfumes, industrial cleaners, paint removers 4 l-BUTANOL C4H100 floor covering, floor lacquer, architectural coating tobacco smoke, plasticizers 4 BUTANAL C4H80 B-2 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 4 2-BUTANONE (MEK) C4H80 floor/wall covering, calcium silicate sheet, fiberboard, caulking compounds, particle board, tobacco smoke, architectural coating, auto exhaust, wood stain synthetic resins, tobacco smoke 4 DICHLORVOS (DDVP) C4H704CI2P insecticide 4 2-ETHOXY-ETHANOL (CELLOSOLVE) C4H1002 epoxy paint 4 N-NITROSOMORPHOUNE auto interior furnishings gasoline 5 PENTANE C5H12 tobacco smoke 5 l-AMYL ALCOHOL C5H120 solvent in organic syntheses 5 PROPYL ACETATE C5H1002 flavors, perfumes, plastics 5 2-METHYl BUTANE (ISOPENTANE) CSH12 6 N-HEXANE C6H14 chipboard, gypsum board, insulation foam, floor covering, wallpaper, wood stain, floor wax, tobacco smoke 6 CYCLOHEXANE C6H12 needle felt, tobacco smoke solvent for lacquers and resins, paint and varnish remover 6 CYCLOHEXANONE C6H100 solvent for many resins fats, waxes and DDT 6 2-HEXANONE (N-BUTYL KETONE) C6H120 6 HEXANAL C6H120 auto exhaust, polyurethane, floor wax 6 4-METHYL-2-PENTAN0NE C6H120 floor/wall covering, tobacco smoke 6 METHYLCYCLOPENTANE C6H12 tobacco smoke 6 2-METHYLPENTANE (ISOHEXANE) C6H14 chipboard, gypsum board, insulation foam, floor covering, wall paper, tobacco smoke 6 3-METHYLPENTANE C6H14 tobacco smoke 6 BENZENE C6H6 tobacco smoke, adhesives, spot cleaners, paint remover, particle board, foam insulation, inks, photo film, auto exhaust, wood stain detergents 6 CHLOROBENZENE C6H5CI solvent for paints and insecticides 6 O-DICHLOROBENZENE C6H4CI2 deodorizers, moth crystals B-3 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 6 M-DICHLOROBENZENE C6H4CI2 deodorizers, moth crystals 6 P-DICHLOROBENZENE C6H4CI2 deodorizers, moth crystals 6 M,P-DICHLOROBENZENE C6H4CI2 deodorizers, moth crystals 6 1,2,3-TRICHLOROBENZENE C6H3CI3 termiticide 6 1,2,4-TRICHLOROBENZENE C6H3CI3 6 1,3,5-TRICHLOROBENZENE C6H3CI3 6 HEXACHIOROBENZENE C6CI8 fungicide 6 TETRACHLOROPHENOL C6H2CI40 wood preservative 6 GAMMA-BHC C6H6CI6 insecticide 6 2-ETHOXYETHYLACETATE C6H1203 floor lacquer, epoxy paints 6 PENTACHLOROPHENOL C6HCI50 wood preservative 6 ALPHA-BHC C6H6CI6 insecticide 6 ISO-BUTYLACETATE C6H1202 flavorings, solvent 6 BUTYLACETATE C6H1202 floor lacquer 7 TOLUENE C7H8 solvent-based adhesive, water-based adhesive, edge-sealing molding tape, wallpaper, jointing compound, calcium silicate sheet, needle felt, floor covering, vinyl coated wallpaper, caulking compound, paint, chipboard, linoleum floor covering, kerosene heaters, tobacco smoke, architectural coating, auto exhaust gasoline 7 BUTYL ACRYLATE C7H1202 used as monomer in polymers and resins for textile and leather finishes 7 METHYICYCLOHEXANE C7H14 7 HEPTANE C7H16 floor covering, floor varnish, kerosene heaters, particle board, adhesives, floor wax, glass cleaner 7 2-METHYLHEXANE C7H16 7 3-METHYLHEXANE C7H16 7 DIMETHYLCYCLOPENTANES C7H14 7 BENZALDEHYDE C7H60 fiberboard, particle board, auto exhaust B-4 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 8 ETHYLBENZENE C8H10 floor/wall covering, insulation foam, chipboard, caulking compounds, Jointing compound, fiberboard, calcium silicate sheet, adhesives, floor lacquer, grease cleaners, photo film, architectural coating, polyurethane solvents 8 STYRENE C8H8 insulation foam, jointing compound, fiberboard, tobacco smoke, adhesives, inks, photo film, lubricants unsaturated polyester resins 8 XYLENES C8H10 needle felt, adhesives, jointing compound, wallpaper, caulking compounds, floor covering, floor lacquer, grease cleaners, shoe dye, tobacco smoke gasoline 8 O-XYLENE C8H10 needle felt, adhesives, jointing compound, wallpaper, caulking compounds, floor covering, floor lacquer, grease cleaners, shoe dye, tobacco smoke 8 M,P-XYLENE C8H10 needle felt, adhesives, jointing compound, wallpaper, caulking compounds, floor covering, floor lacquer, grease cleaners, shoe dye, tobacco smoke 8 M-XYLENE C8H10 needle felt, adhesives, jointing compound, wallpaper, caulking compounds, floor covering, floor lacquer, grease cleaners, shoe dye, tobacco smoke, kerosene heaters 8 P-XYLENE C8H10 needle felt, adhesives, jointing compound, wallpaper, caulking compounds, floor covering, floor lacquer, grease cleaners, shoe dye. tobacco smoke, kerosene heaters 8 DIMETHYL BENZENE C8H10 floor adhesive 8 ISOOCTANE (2-METHYL-HEPTANEI C8H18 floor covering, floor varnish, adhesives gasoline 8 N-OCTANE C8H18 floor covering, adhesives, floor varnish, kerosene heaters, floor wax 8 2-BROMOOCTANE (OCTYL BROMIDE) C8H17Br used in organic syntheses 8 2-ETHYLHEXANOL C8H190 8 RONNEL C8H803CI3PS insecticide B-5 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 8 2,4 - D C8H6CI203 insecticide 8 CHLOROTHALONIL C8CI4N2 Insecticide 8 ATRAZINE C8H14CIN5 insecticide 9 NONANE C9H20 wallpaper, caulking compounds, floor covering, chipboard, adhesives, cement flagstone, jointing compound, floor varnish, kerosene heaters, floor wax, wood stain, polyurethane 9 2,5-DIMETHYL-HEPTANE C9H20 9 ETHYL TOLUENE C9H12 floor wax 9 TRIMETHYLCYCLOHEXANE C9H18 floor wax 9 O-ETHYLTOLUENE C9H12 floor wax 9 M.P-ETHYLTOLUENE C9H12 floor wax 9 M-ETHYLTOLUENE C9H12 floor wax 9 CUMENE C9H12 petroleum solvents 9 QUINOLINE C9H7N used in dyos, solvent for resins 9 ISOQUINOUNE C9H7N used in synthesis of dyes and insecticides, rubber accelerator 9 INDANE (HYDRINDENE) C9H10 coal tar 9 1,2,3 TRIMETHYLBENZENE C9H12 floor/wall covering, floor wax 9 1,2,4 TRIMETHYLBENZENE C9H12 floor/wall covering, linoleum floor covering, caulking compound, vinyl coated wallpaper, needle felt, jointing compound, cement flagstone, floor varnish, chipboard, floor wax 9 1,3,5 TRIMETHYLBENZENE C9H12 caulking compounds, floor/wall covering, floor wax, wood stain, polyurethane 9 N-PROPYLBENZENE C9H12 adhesives, floor/wall covering, chipboard, needle felt, paint, caulking compounds, insulation foam, kerosene heaters B-6 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 9 1+ N-PROPYLBENZENE C9H12 adhesives, floor/wall covering, chipboard, needle felt, paint, caulking compounds, insulation foam, kerosene heaters 9 ISOPROPYLBENZENE C9H12 floor/wall covering, paint, insulation foam, jointing compound, architectural coating 9 O-METHYLETHYLBENZENE C9H12 9 M-METHYLETHYIBENZENE C9H12 9 P-METHYLETHYLBENZENE C9H12 9 O + P-METHYLETHYLBENZENE C9H12 architectural coating 9 NONANAL C9H180 insecticide 9 1-NONENE C9H18 floor wax 9 CHLORPYRIFOS C9H11CI3N03PS insecticide 9 CAPTAN C9H8CI3N02S insecticide 9 FOLPET C9H4CI3N02S insecticide 10 DECANE C10H22 jointing compound, needle felt, cNpboard, floor varnish, wallpaper, fiberboard, cement flagstone, floor/wall covering, adhesives, caulking compounds, kerosene heaters, wood stain, polyurethane, floor wax, architectural coating 10 N-BUTYLBENZENE C10H14 solvent 10 P-METHYLISOPROPYLBENZENE C10H14 10 LIMONENE C10H16 paint, adhesives, chipboard, floor wax, ceiling cleaner 10 PINENE C10H16 camphor, insecticides, solvents, plasticizers, perfumes 10 a-PINENE C10H16 cement flagstone, fiberboard, gypsum board, adhesive, insulation sheets, chipboard, calcium silicate sheet 10 b-PINENE C10H16 10 a-TERPINENE C10H16 oil of lemon 10 CAMPHENE C10H16 essential oils 10 CAMPHOR C10H160 moth crystals B-7 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 10 NAPHTHALENE (TETRALIN) C10H12 moth crystals 10 CHLORDANE C10H6CI8 insecticide 10 MALATHION C10H1906PS2 insecticide 10 DACTHAL C10H6CI404 herbicide 10 EUCAIYPTOLE (CINEOLE) C10H18O medicinal use 10 HEPTACHLOR C10H5CI7 insecticide 10 NICOTINE C10H14N2 tobacco smoke 10 MALATHION C10H17O6PS2 insecticide 10 DACTHAL C10H6CI4O4 insecticide 10 p-CYMENE C10H14 ceiling cleaner, ceramic-floor cleaner, desk cleaner 11 UNDECANE C11H24 wallpaper, gypsum board, floor/wall covering, jointing compound, cement flagstone, caulking compound, chipboard, needle felt, floor varnish, paints, paint removers, architectural coating, wood stain, polyurethane, floor wax, desk cleaner, stone-floor cleaner, ceiling cleaner 11 1 -METHYLNAPHTHALENE C11H10 11 2-METHYLNAPHTHALENE C11H10 11 PROPOXUR C11H15N03 insecticide 11 BENDIOCARB C11H13N04 insecticide 12 DODECANE C12H26 floor varnish, floor/wall covering, kerosene heaters, architectural coating 12 DIAZINON C12H21N203PS insecticide 12 ALDRIN C12HSCI6 insecticide 12 ORTHO PHENYLPHENOL C12H100 tobacco smoke 12 4-PHENYLCYCL0HEXENE (4-PC) C12H14 latex backing on carpets 13 TRIDECANE C13H28 kerosene heaters, architectural coating 14 TETRADECANE C14H30 kerosene heaters 14 PHENANTHRENE C14H10 unvented gas burner 14 ANTHRACENE C14H10 unvented gas burner B-8 ------- Sources of Indoor Organic Compounds (cont.) c COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES 15 PENTADECANE C15H32 15 NONYLPHENOL ISOMERS C15H240 lubricating oil additives, resins, plasticizers, surf ace active agents 16 DIBUTYLPHTHALATE C16H2204 plastios 16 HEXADECANE C16H34 16 HEXADECANE (BRANCHED) C16H34 16 FLUORANTHENE C16H10 unvented gas burner, tobacco smoke 16 PYRENE C16H10 unvented gas burner, tobacco smoke 16 1-NITROPYRENE C16H902N 16 3-NITROFLUORANTHENE C16H902N 18 CHRYSENE C18H12 unvented gas burner, tobacco smoke 18 CYCLOPENTA(C,D)PYRENE C18H10 18 BENZO(A)ANTHRACENE C18H12 tobacco smoke, auto exhaust 19 BUTYLBENZYLPHTHALATE C19H2004 20 BENZOFLUORANTHENES C20H12 unvented gas burner, vented wood- burning stove, tobacco smoke 20 BENZO(A>PYRENE C20H12 vented vwood-burning stova, unvented gas burner, unvented coal-burning stove, tobacco smoke, auto exhaust 20 BENZO(E)PYRENE C20H12 cook stove, tobacco smoke 22 DIHEPTYLPHTHALATE C22H3404 22 INDENO(1,2,3-C,D)PYRENE C22H12 vented wood-burning stove, unvented gas burner, tobacco smoke 23 N-TRICOSANE C23H48 24 N-TETRACOSANE C24H50 24 DI(2-ETHYLHEXYL)PHTHALATE C24H3804 24 TRIS(2-ETHYLHEXYL)PHOSPHATE C24H5104P 24 BENZO|G.H,l)PERYLENE C24H14 vented wood-burning stove, tobacco smoke 24 CORONENE C24H12 25 N-PENTACOSANE C25H52 25 BIS(2-ETHYLHEXYL)AZELATE C25H4804 B-9 ------- c 26 26 27 28 28 29 30 30 31 31 Sources of Indoor Organic Compounds (cont.) COMPOUND FORMULA SUBSTANTIATED SOURCES POSSIBLE SOURCES DINONYL PHTHALATE C26H4204 N-HEXACOSANE C26H54 N-HEPTACOSANE C27H56 DIDECYL PHTHALATE C28H4604 N-OCTACOSANE C28H58 N-NONACOSANE C29H60 N-TRIACONTANE C30H62 TRIACONTANE (BRANCHED) C30H62 N-HENTRIACONTANE C31H64 HENTRIACONTANE (BRANCHED) C31H64 B-10 ------- Appendix C References" 1. De Bortoli, M., H. Knoppel, E. Pecchio, A. Peil, L. Rogora, H. Schauenburg, H. Schlitt, and H. Vissers. Measurements of Indoor Air Quality and Comparison with Ambient Air. Commission of the European Communities, Publication No. EUR 9656 EN, Joint Research Centre, Ispra, Italy, 1985. 2. Hawthorne, A. R., R. B. Gammage, C. S. Dudney, B. E. Hingerty, D. D. Schuresko, D. C. Parzyck, D. R. Womack, S. A. Morris, R. R. Westley, D. A. White, and J.M. Schrimshrt. An Indoor Air Quality Study of Forty East Tennessee Homes. ORNL-5965, Oak Ridge National Laboratory, Oak Ridge, TN, 1984. 3. New Jersey State Department of Health. Pomona Oaks Exposure Assessment: Volatile Organics in Well Water and Indoor Air. Trenton, NJ, 1984 4. Wallace, L. A., E. D. Pellizzari, T. D. Hartwell, C. M. Sparacino, and H. S. Zelon. Personal Exposure to Volatile Organics and Other Compounds Indoors and Outdoors-The TEAM Study. EPA Report No. 600/D-83-082 (NTIS PB83-231357), U. S. Environmental Protection Agency, Washington, DC, 1983. 5. Gupta K. C., A. G. Ulsamer, and R. Gammage. Volatile Organic Compounds in Residential Air: Levels, Sources and Toxicity. Paper No. 84-1.3, Presented at the 77th annual meeting of the Air Pollution Control Association, San Francisco, CA, 1984. 6. Lebret, E. Air Pollution in Dutch Homes: An Exploratory Study in Environmental Epidemiology. Report R-138, 1985-221, Wageningen Agricultural University, The Netherlands, 1985. 7. Monteith, D. K., T. H. Stock, and W. E. Seifert, Jr. Sources and Characterization of Organic Air Contaminants Inside Manufactured Housing. In: Proceedings of the Third International Conference on Indoor Air Quality and Climate, Vol.4, pp. 285-290, Swedish Council for Building Research, Stockholm, Sweden, 1984. "References cited in Appendix A. C-1 ------- 8. Dropkin, D. Sampling of Automobile Interiors for Organic Emissions. EPA Report No. EPA-600/3-85-008 (NTIS PB85-172567), U. S. Environmental Protection Agency, Atmospheric Sciences Research Laboratory, Research Triangle Park, NC, 1985. 9. Turiel, I., C. D. Hollowell, R. R. Miksch, J. V. Rudy, R. A. Young, and M. J. Coye. The Effects of Reduced Ventilation on Indoor Air Quality in an Office Building. Atmospheric Environment, Vol.17, pp. 51-64, 1983. 10. Yocum, J. E., N. H. Hijazi, and J. J. Zoldak. Use of Direct Analysis Mass Spectrometry to Solve Indoor Air Quality Problems. In: Proceedings of the Third International Conference on Indoor Air Quality and Climate, Vol.4, pp. 245-250, Swedish Council for Building Research, Stockholm, Sweden, 1984. 11. Wilson, N. K. Pilot Study of Sampling and Analysis for Polynuclear Aromatic Compounds in Indoor Air. Presented at the Congress of Pacific Basin Chemical Societies, Honolulu, HI, 1984. 12. Wright, C. G., and R. B. Leidy. Chlordane and Heptachlor in the Ambient Air of Houses Treated for Termites. Bulletin of Environmental Contaminant Toxicology, Vol. 28, pp. 617-623, 1982. 13. Weschler, C.J. Indoor-Outdoor Relationships for Nonpolar Organic Constituents of Aerosol Particles. Environmental Science and Technology, Vol. 18, pp. 648-652, 1984 14. Krause, C., W. Mailahn, R. Nagel, C. Schulz, B. Seifert, and D. Ullrich. Occurrence of Volatile Organic Compounds in the Air of 500 Homes in the Federal Republic of Germany. In: Proceedings of the Fourth International Conference on Indoor Air Quality and Climate, Vol.1, pp. 102-106, Institute for Water, Soil, and Air Hygiene, Berlin, West Germany, 1987. 15. Wallace, L. A., T. D. Hartwell, K. Perritt, L. S. Sheldon, L. Michael, and E. D. Pellizzari. The Influence of Personal Activities on Exposure to Volatile Organic Compounds. In: Proceedings of the Fourth International Conference on Indoor Air Quality and Climate, Vol.1, pp. 117-121, Institute for Water, Soil, and Air Hygiene, Berlin, West Germany, 1987. C-2 ------- 16. Jungers, R. H., and L. S. Sheldon. Characterization of Volatile Organic Chemicals in Public Access Buildings. In: Proceedings of the Fourth International Conference on Indoor Air Quality and Climate, Vol. 1, pp. 144-148, Institute for Water, Soil, and Air Hygiene, Berlin, West Germany, 1987. 17. Wallace, L. A., and C. A. Clayton. Volatile Organic Compounds in 600 US Homes: Major Sources of Personal Exposure. In: Proceedings of the Fourth International Conference on Indoor Air Quality and Climate, Vol. 1, pp. 183-188, Institute for Water, Soil, and Air Hygiene, Berlin, West Germany, 1987. 18. Sexton, K., K. Liu, and M. X. Petreas. Formaldehyde Concentrations Inside Private Residences: A Mail-Out Approach to Indoor Air Monitoring. Journal of the Air Pollution Control Association, Vol. 36, pp. 698-704, 1986. 19. Lewis, R. G., and A. E. Bond. Non-Occupational Exposure to Household Pesticides. In: Proceedings of the Fourth International Conference on Indoor Air Quality and Climate, Vol. 1, pp. 195-199, Institute for Water, Soil, and Air Hygiene, Berlin, West Germany, 1987. 20. Olds, K. L. Indoor Airborne Concentrations of Termiticides in Department of the Army Family Housing. In: Proceedings of the Fourth International Conference on Indoor Air Quality and Climate, Vol. 1, pp. 205-209, Institute for Water, Soil, and Air Hygiene, Berlin, West Germany, 1987. 21. Reinert, J. C. Pesticides in the Indoor Environment. In: Proceedings of the Third International Conference on Indoor Air Quality and Climate, Vol. 1, pp. 233-238, Swedish Council for Building Research, Stockholm, Sweden, 1984. 22. Levin, H., and J. Hahn. Pentachlorophenol in Indoor Air: The Effectiveness of Sealing Exposed Pressure-Treated Wood Beams and Improving Ventilation in Office Buildings to Address Public Health Concerns and Reduce Occupant Complaints. In: Proceedings of the Third International Conference on Indoor Air Quality and Climate, Vol. 5, pp. 123-130, Swedish Council for Building Research, Stockholm, Sweden, 1984. C-3 ------- 23. Kalinic, N., K. Sega, and A. Sisovic. Formaldehyde Levels in Selected Indoor Microenvironments. In: Proceedings of the Third International Conference on Indoor Air Quality and Climate, Vol. 3, pp. 145-148, Swedish Council for Building Research, Stockholm, Sweden, 1984. 24. Black, M. S., C. W. Bayer, and H. L. Brackett. An Office Building IAQ Problem Involving Volatile Organic Compounds. In: Proceedings of the ASHRAE Conference IAQ 87, pp. 72-87, American Society of Heating, Refrigerating, and Air-Conditioning Engineers, Inc., Atlanta, GA, 1987. 25. Wallace, L. The Total Exposure Assessment Methodology (TEAM) Study: Summary and Analysis: Vol. 1. EPA Report No. EPA-600/6- 87-002a (NTIS PB88-100060), U. S. Environmental Protection Agency, Office of Research and Development, Washington, DC, 1987. 26. Pyle, B. E., and A. D. Williamson. Radon Mitigation Studies: Nashville Demonstration. EPA Report No. EPA-600/8-90-061 (NTIS PB90- 257791), U. S. Environmental Protection Agency, Air and Energy Engineering Research Laboratory, Research Triangle Park, NC, 1990. 27. Lewis, R. G., A. E. Bond, T. R. Fitz-Simons, D. E. Johnson, and J. P. Hsu. Monitoring for Non-Occupational Exposure to Pesticides in Indoor and Personal Respiratory Air. Paper No. 86-37.4, Presented at the 79th Annual Meeting of the Air Pollution Control Association, Minneapolis, MN, 1986. 28. Immerman, F. W., and J. L. Schaum. Non-Occupational Pesticide Exposure Study (NOPES). EPA Report No. EPA-600/3-90-003 (NTIS PB90-152224), U. S. Environmental Protection Agency, Atmospheric Research and Exposure Assessment Laboratory, Research Triangle Park, NC, 1990. 29. Gebefugi, I., H. Parlar, and F. Korte. Occurrence of Pentachlorophenol in Enclosed Environments. Ecotoxicology and Environmental Safety, Vol. 3, pp. 269-300, 1979. 30. Walsh, D. W. Preliminary Evaluation of the Environmental Concentration and Toxicity of 4-Phenylcyclohexene: An Emission of New Carpeting. Master of Science Thesis, The University of Arizona, Tucson, AZ, 1986. C-4 ------- 31. Shah, J. J., and E. K. Heyerdahl. National Ambient Volatile Organic Compounds (VOCs) Data Base Update. EPA Report No. EPA/600/3- 88-010a (NTIS PB88-195631), U. S. Environmental Protection Agency, Washington, DC, 1988. 32. Andelman, J. B. Human Exposures to Volatile Halogenated Organic Chemicals in Indoor and Outdoor Air. Environmental Health Perspective, Vol. 62, pp. 313-318, 1985. 33. Weschler, C. J., and K. L. Fong. Characterization of Organic Species Associated with Indoor Aerosol Particles. Environment International, Vol. 12, pp. 93-77, 1986. 34. Bond, A. E., R. G. Lewis, F. W. Immerman, and R. W. Whitmore. A Study of Residential Exposure to Pesticides in Two Urban Areas of the United States. In: Proceedings of the Fifth International Conference on Indoor Air Quality and Climate, Vol. 2, pp. 683-688, Canada Mortgage and Housing Corporation, Ottawa, Canada, 1990. 35. Hollowell, C. D., and R. R. Miksch. Sources and Concentrations of Organic Compounds in Indoor Environments. Bulletin of the New York Academy of Medicine, Vol. 57, pp. 962-977, 1981 36. Sheldon L., H. Zelon, J. Sickles, C. Eaton, and T. Hartwell. Indoor Air Quality in Public Buildings, Volume II. EPA Report No. EPA- 600/6-88-009b (NTIS PB89-102511), U. S. Environmental Protection Agency, Environmental Monitoring Systems Laboratory, Research Triangle Park, NC, 1988. 37. Grot, R. A., A. Persily, A. T. Hodgson, and J. M. Daisey. (1989). Environmental Evaluation of the Portland East Federal Office Building - Preoccupancy and Early Occupancy Results. NIST Report No. NISTIR 89-4066, U. S. Department of Commerce, National Institute of Standards and Technology, Gaithersburg, MD, 1989. 38. Gebefugi, I. L., and F. Korte. Source of Organics in the Air of an Office Building. In: Proceedings of the Fifth International Conference on Indoor Air Quality and Climate, Vol. 2, pp. 701-706, Canada Mortgage and Housing Corporation, Ottawa, Canada, 1990. 39. Shields, H. C., and C. J. Weschler. Three Years of Indoor/Outdoor VOC Measurements in Neenah, Wl. In: Proceedings of the Fifth International Conference on Indoor Air Quality and Climate, Vol. 2, pp. 771-776, Canada Mortgage and Housing Corporation, Ottawa, Canada, 1990. C-5 ------- |