Managing Debris after a Natural Disaster: Evaluation of the Combustion of Storm-Generated Vegetative and C&D Debris in an Air Curtain Burner: Source Emissions Measurement Results


Managing Debris after a Natural Disaster
EPA/600/R-16/353
Appendix A: CEM Data
CEM C&D Run l.pdf
jj CEM C&D Run 2.pdf
^)CEM C&D Run 3.pdf
_jCEM Plots.pdf
jcEM Vegetative Run l.pdf
jJcEM Vegetative Run 2.pdf
jjcEM Vegetative Run 3.pdf
^Master ACD Data Sheet r2_QCwith DLs.xls
A-1

-------
Calculated Data Summary-C&D Run 1
Stack Stack Stack Stack Stack Stack
Time
02
C02
CO
NOx
S02
THC


%
%
ppm
ppm
ppm
ppm

Sampling
20.13
0.73
103.40
11.17
5.11
13.88
Mean
Interval
0.36
0.36
85.94
6.32
5.16
14.16
S.D.
13:37 -19:25
20.15
0.69
76.51
9.96
2.56
8.82
Median
13:37
19.80
1.18
97
12
5.6
5
13:38
19.73
1.25
114
12
4.7
5
13:39
19.79
1.19
128
12
4.0
6
13:40
19.84
1.10
140
11
3.5
7
13:41
19.86
1.12
119
11
3.1
8
13:42
19.95
0.98
148
10
2.8
8
13:43
19.72
1.23
161
12
2.6
10
13:44
19.60
1.32
199
12
2.3
9
13:45
19.81
1.15
153
11
2.2
8
13:46
19.76
1.20
156
11
1.9
9
13:47
19.83
1.14
173
11
1.9
9
13:48
20.00
1.00
147
9
1.8
8
13:49
20.05
0.93
155
9
1.7
10
13:50
20.00
0.95
160
10
1.5
9
13:51
20.06
0.91
110
9
1.4
7
13:52
20.41
0.53
82
6
1.4
6
13:53
20.82
0.18
40
2
1.3
5
13:54
20.52
0.50
107
5
1.2
9
13:55
20.40
0.59
122
6
1.3
9
13:56
20.36
0.59
124
6
1.2
7
13:57
20.37
0.66
100
7
1.1
9
13:58
20.15
0.81
161
8
1.1
11
13:59
20.25
0.72
126
8
1.1
8
14:00
20.39
0.58
104
6
1.1
10
14:01
20.37
0.61
137
7
1.1
11
14:02
20.07
0.90
176
9
1.1
14
14:03
19.95
1.02
246
10
1.2
14
14:04
20.01
0.98
196
10
0.9
13
14:05
20.01
1.00
206
10
0.9
12
14:06
20.05
0.94
195
9
1.0
13
14:07
20.14
0.90
185
9
0.9
14
14:08
20.09
0.89
201
9
1.0
13
14:09
20.37
0.61
116
7
0.8
11
14:10
20.41
0.57
133
6
0.8
10
14:11
20.63
0.36
103
4
0.7
11

-------
Calculated Data Summary-C&D Run 2
Stack Stack Stack Stack Stack Stack
Time
02
C02
CO
NOx
S02
THC


%
%
ppm
ppm
ppm
ppm

Sampling
20.31
0.82
185.97
10.09
24.42
55.91
Mean
Interval
0.47
0.41
151.41
6.27
9.46
63.53
S.D.
8:15-13:05
20.37
0.77
137.57
8.87
24.21
27.33
Median
8:15
20.78
0.29
57
2
13.0
10
8:16
20.71
0.35
49
3
12.9
11
8:17
20.72
0.35
84
3
13.1
34
8:18
20.87
0.18
98
2
13.5
28
8:19
20.81
0.25
53
3
13.8
13
8:20
20.73
0.35
36
4
13.6
12
8:21
20.61
0.48
44
6
13.4
12
8:22
20.67
0.40
43
5
13.3
12
8:23
20.61
0.50
44
7
13.3
12
8:24
20.58
0.53
53
7
13.3
13
8:25
20.59
0.51
56
6
13.3
15
8:26
20.48
0.62
72
8
13.4
16
8:27
20.58
0.53
78
6
13.5
20
8:28
20.54
0.58
90
7
13.6
20
8:29
20.55
0.57
94
7
14.0
25
8:30
20.64
0.47
85
5
14.1
25
8:31
20.68
0.42
79
5
13.9
24
8:32
20.59
0.51
80
7
13.5
21
8:33
20.32
0.79
79
11
13.9
17
8:34
20.39
0.74
95
9
14.5
22
8:35
20.65
0.46
87
5
14.0
22
8:36
20.63
0.47
90
6
13.5
25
8:37
20.53
0.57
118
7
13.5
33
8:38
20.10
1.07
107
13
13.6
19
8:39
19.92
1.20
89
15
14.5
17
8:40
20.15
0.95
102
12
14.6
20
8:41
20.50
0.63
126
8
14.0
24
8:42
20.42
0.74
146
9
13.9
33
8:43
20.39
0.73
143
10
14.1
29
8:44
20.40
0.71
113
9
14.2
30
8:45
20.47
0.63
126
7
14.4
37
8:46
20.26
0.85
135
9
14.4
31
8:47
20.56
0.55
139
6
14.4
40
8:48
20.41
0.76
138
8
14.2
31
8:49
20.22
0.92
138
10
14.4
33

-------
Calculated Data Summary-C&D Run 3
Stack Stack Stack Stack Stack Stack
Time
02
C02
CO
NOx
S02
THC


%
%
ppm
ppm
ppm
ppm

Sampling
20.48
0.63
99.03
6.38
5.63
21.73
Mean
Interval
0.30
0.25
70.49
3.35
3.40
23.23
S.D.
1615-19:45
20.47
0.64
88.64
6.37
5.03
14.66
Median
16:15
19.71
1.44
60
13
15.4
11
16:16
20.21
1.08
35
10
10.7
9
16:17
20.82
0.96
41
9
9.2
10
16:18
21.00
1.07
36
11
8.2
8
16:19
20.86
1.00
31
9
7.2
8
16:20
20.52
0.78
22
6
5.9
7
16:21
20.34
0.77
27
6
5.3
10
16:22
20.39
0.68
64
5
5.3
15
16:23
20.21
0.83
96
7
6.0
27
16:24
20.26
0.77
245
6
7.4
110
16:25
20.60
0.42
397
3
7.2
159
16:26
20.57
0.44
370
4
6.3
126
16:27
20.57
0.46
258
4
6.7
75
16:28
20.56
0.47
264
4
6.0
114
16:29
20.52
0.51
350
4
6.8
120
16:30
20.37
0.68
295
6
6.1
85
16:31
20.06
0.98
244
10
8.1
48
16:32
20.22
0.85
139
8
8.1
28
16:33
20.31
0.76
68
8
7.3
20
16:34
20.32
0.75
105
7
7.5
27
16:35
20.32
0.75
89
8
7.0
19
16:36
20.16
0.90
34
10
7.8
13
16:37
20.14
0.94
36
10
8.5
16
16:38
20.30
0.78
92
8
8.1
19
16:39
20.27
0.79
56
8
7.3
10
16:40
20.19
0.88
30
9
7.5
7
16:41
20.22
0.86
30
9
7.5
6
16:42
20.25
0.84
20
9
6.8
6
16:43
20.24
0.84
17
9
6.5
5
16:44
20.29
0.80
16
8
6.6
5
16:45
20.48
0.61
65
6
5.8
24
16:46
20.52
0.55
117
5
5.6
33
16:47
20.50
0.57
115
5
5.4
30
16:48
20.53
0.55
106
5
4.9
24
16:49
20.52
0.54
75
5
4.5
13

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20.5
Veg Run 1 - 02
20.0
19.5
18.5
18.0
10:00
11:00
12:00
13:00
Time
Figure A-1. Measured 02 Concentrations, Vegetative Run 1
3.5 -I
Veg Run 1 - C02
3.0 -
2.5 -
| 2.0 -
o
>
0.5 -
10:00
11:00
12:00
13:00
Time
Figure 4-6. Measured C02 Concentrations, Veg Run 1

-------
Veg Run 1 - CO
200
150
E
Q.
Q.
100
50 -
10:00
11:00
12:00
13:00
Time
Figure 4-7. Measured CO Concentrations, Veg Run 1
70 -
Veg Run 1 - THC
60 -
50 -
E
Q.
Q.
30 -
20 -
10 -
10:00
11:00
12:00
13:00
Time
Figure 4-8. Measured THC Concentrations, Veg Run 1

-------
Veg Run 1 - NOx
20 -
15 -
E
Q.
10 -
5 -
0 -
10:00
11:00
12:00
13:00
Time
Figure 4-9. Measured NOx Concentrations, Veg Run 1
Veg Run 1 - S02
40 -
30 -
E
Q.
Q.
20 -
10 -
10:00
11:00
12:00
13:00
Time
Figure 4-10. Measured S02 Concentrations, Veg Run 1
Veg Run 2-02
20.5
20.0
0)
E
§ 19.5
19.0
16:00
16:30
17:00
17:30
18:00
18:30
Time

-------
Figure 4-11. Measured 02 Concentrations, Veg Run 2
Veg Run 2 - CO:
2.0 -
0)
E
o
>
0.5 -
16:00
16:30
17:00
17:30
18:00
18:30
Time
Figure 4-12. Measured C02 Concentrations, Veg Run 2
Veg Run 2 - CO
200
150
E
Q.
Q.
100
50 -
16:00
16:30
17:00
17:30
18:00
18:30
Time
Figure 4-13. Measured CO Concentrations, Veg Run 2

-------
35 -
Veg Run 2 - THC
30 -
25 -
i 20 -
Q.
15 -
10 -
5 -
16:00
16:30
17:00
17:30
18:00
18:30
Time
Figure 4-14. Measured THC Concentrations, Veg Run 2
20 -
Veg Run 2 - NOx
15 -
5 -
0 -
16:00
16:30
17:00
17:30
18:00
18:30
Time
Figure 4-15. Measured NOx Concentrations, Veg Run 2
35 H
Veg Run 2 - S02
30 -
25 -
E 20 -
Q.
Q.
15 -
10 -
5 -
16:00
16:30
17:00
17:30
18:00
18:30
Time

-------
Figure 4-16. Measured S02 Concentrations, Veg Run 2
Veg Run 3-02
20.0
19.5
19.0
18.5
18.0
17.5
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-17. Measured 02 Concentrations, Veg Run 3
3.5 -
Veg Run 3 - C02
3.0 -
2.5 -
2.0 -
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-18. Measured C02 Concentrations, Veg Run 3

-------
Veg Run 3 - CO
600
500
400
300
200
100
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-19. Measured CO Concentrations, Veg Run 3
Veg Run 3 - THC
80 -
60 -
40 -
20 -
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-20. Measured THC Concentrations, Veg Run 3
5 -
Veg Run 3 - NOx
4 -
3 -
0 -
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time

-------
Figure 4-21. Measured NOx Concentrations, Veg Run 3
Veg Run 3 - S02
50 -
40 -
30 -
20 -
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-22. Measured S02 Concentrations, Veg Run 3
21.0
C&D Run 1 - 02
20.5
20.0
19.5
19.0
16:00
17:00
18:00
19:00
Time
Figure 4-23. Measured 02 Concentrations, C&D Run 1

-------
C&D Run 1 - C02
0)
E
_3
o
>
0.5 -
16:00
17:00
18:00
19:00
Time
Figure 4-24. Measured C02 Concentrations, C&D Run 1
C&D Run 1 - CO
300
a. 200
100
16:00
17:00
18:00
19:00
Time
Figure 4-25. Measured CO Concentrations, C&D Run 1
C&D Run 1 -
THC
80 -
60 -
E
Q.
Q.
40 -
20 -
16:00
17:00
18:00
19:00
Time

-------
Figure 4-26. Measured THC Concentrations, C&D Run 1
C&D Run 1 - NOx
E
Q.
Q.
5 -
16:00
17:00
18:00
19:00
Time
Figure 4-27. Measured NOx Concentrations, C&D Run 1
C&D Run 1 - S02
£ 20
5 -
16:00
17:00
18:00
19:00
Time
Figure 4-28. Measured S02 Concentrations, C&D Run 1

-------
C8D Run 2-02
21.0
20.5
20.0
19.5
19.0
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-29. Measured 02 Concentrations, C&D Run 2
C&D Run 2 - C02
2.0 -
0.5 -
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-30. Measured C02 Concentrations, C&D Run 2
700
C&D Run 2 - CO
600
500
400
300
200
100
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time

-------
Figure 4-31. Measured CO Concentrations, C&D Run 2
350
C&D Run 2 - THC
300
250
200
150
100
50
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-32. Measured THC Concentrations, C&D Run 2
70
C&D Run 2 - NOx
60
50
40
30
20
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-33. Measured NOx Concentrations, C&D Run 2

-------
C&D Run 2 - S 02
25 -
20 -
E
Q.
15 -
10 -
5 -
09:00
09:30
10:00
10:30
11:00
11:30
12:00
Time
Figure 4-34. Measured S02 Concentrations, C&D Run 2
C&D Run 3 - 02
21.0
<1)
J 20.5
"o
>
20.0
16:30
17:00
17:30
18:00
18:30
19:00
19:30
Time
Figure 4-35. Measured 02 Concentrations, C&D Run 3
O&D Run 3 - u02
0)
E
o
>
0.6 -
0.4 -
0.2 ^
16:30
17:00
17:30
18:00
18:30
19:00
19:30
Time

-------
Figure 4-36. Measured C02 Concentrations, C&D Run 3
400
C&D Run 3 - CO
300
£ 200
100
16:30
17:00
17:30
18:00
18:30
19:00
19:30
Time
Figure 4-37. Measured CO Concentrations, C&D Run 3
160
C&D Run 3 - THC
140
120
100
E
§: so -
60 -
40 -
20 -
16:30
17:00
17:30
18:00
18:30
19:00
19:30
Time
Figure 4-38. Measured THC Concentrations, C&D Run 3

-------
C&D Run 3 - NOx
15 -
E
Q.
Q.
5 -
16:30
17:00
17:30
18:00
18:30
19:00
19:30
Time
Figure 4-39. Measured NOx Concentrations, C&D Run 3
C&D Run 3 - S Z>2
16 -
14 -
12 -
E
Q.
Q.
6 -
4 -
16:30
17:00
17:30
18:00
18:30
19:00
19:30
Time
Figure 4-40. Measured S02 Concentrations, C&D Run 3

-------
Calculated Data Summary-Vegetative Run 1
Stack Stack Stack Stack Stack Stack
Time
02
C02
CO
NOx
S02
THC


%
%
ppm
ppm
ppm
ppm

Sampling
19.11
1.96
63.63
20.85
6.09
13.51
Mean
Interval
0.77
0.79
78.49
11.48
4.99
33.18
S.D.
8:29-13:50
19.15
1.93
32.02
19.33
5.48
3.77
Median
8:29
19.34
1.64
85
28
16.3
21
8:30
19.65
1.30
50
23
12.8
11
8:31
20.38
0.71
7
9
9.4
4
8:32
20.41
0.68
5
8
6.6
4
8:33
20.43
0.62
3
8
5.2
4
8:34
20.79
0.25
-1
3
4.5
6
8:35
19.79
1.39
5
18
3.8
19
8:36
19.27
1.78
11
24
4.0
23
8:37
19.22
1.86
13
24
4.9
27
8:38
18.85
2.23
13
29
4.3
28
8:39
18.92
2.12
12
26
5.0
8
8:40
18.90
2.22
9
26
5.1
8
8:41
18.71
2.40
9
27
5.5
9
8:42
18.72
2.39
9
27
5.4
11
8:43
18.60
2.49
11
28
5.2
12
8:44
18.82
2.27
15
25
5.9
11
8:45
19.06
2.02
21
23
5.6
11
8:46
19.32
1.78
28
19
4.8
10
8:47
19.17
1.94
24
21
4.0
9
8:48
19.35
1.79
28
19
3.9
9
8:49
19.00
2.13
21
23
3.4
8
8:50
18.92
2.21
15
23
3.2
7
8:51
19.02
2.08
14
22
3.6
7
8:52
19.33
1.79
30
18
3.2
8
8:53
19.12
2.03
23
21
2.4
6
8:54
18.91
2.24
16
23
2.5
6
8:55
18.40
2.74
37
30
3.6
5
8:56
17.72
3.35
43
40
9.6
5
8:57
18.22
2.92
19
33
11.8
5
8:58
18.57
2.55
18
28
10.6
5
8:59
19.10
2.06
28
22
8.5
5
9:00
18.80
2.30
15
24
7.2
4
9:01
18.54
2.58
16
27
6.7
4
9:02
18.97
2.12
33
22
6.6
6
9:03
19.24
1.87
44
19
5.7
6
9:04
19.19
1.93
48
20
5.2
5
9:05
18.96
2.16
46
28
5.6
5
9:06
18.64
2.45
17
29
8.7
4
9:07
18.61
2.47
13
28
9.6
4
9:08
18.60
2.52
12
27
9.6
4
9:09
18.60
2.53
15
26
9.0
4
9:10
18.60
2.52
21
25
8.7
4
9:11
18.53
2.58
20
26
8.8
3
9:12
18.74
2.40
15
24
8.2
3
9:13
18.46
2.74
200
28
7.0
16
9:14
18.14
2.99
66
42
8.7
7
9:15
18.17
2.98
162
42
11.3
31
9:16
17.91
3.16
388
42
11.8
62
9:17
18.28
2.76
465
35
14.1
244
9:18
18.23
2.95
333
39
12.0
64
9:19
17.48
3.62
294
45
12.6
57
9:20
18.03
3.01
326
38
15.0
250
9:21
19.16
1.93
617
21
17.7
357
9:22
18.90
2.28
585
28
15.6
245
9:23
17.66
3.47
346
46
13.9
69
9:24
17.28
3.81
223
53
16.8
46
9:25
17.33
3.83
173
56
17.5
29
9:26
17.15
3.91
72
62
17.8
16
9:27
17.31
3.83
136
59
17.6
23
9:28
16.96
4.14
125
63
19.1
15
9:29
17.16
3.92
85
60
19.2
16
9:30
17.48
3.63
134
54
16.8
20
9:31
17.16
3.94
94
59
16.2
14
9:32
17.33
3.75
150
56
16.1
17
9:33
17.31
3.78
138
56
15.7
16
9:34
17.38
3.76
128
55
14.7
14
9:35
17.38
3.66
100
55
14.4
11
9:36
19.41
1.62
34
24
12.2
6
9:37
20.06
1.13
29
16
7.9
6
9:38
20.11
1.05
27
14
6.0
5
9:39
20.09
1.05
17
14
5.0
4
9:40
20.11
1.03
12
13
4.5
4
9:41
20.13
0.99
15
13
4.2
4
9:42
19.04
2.07
23
27
4.5
4
9:43
19.50
1.56
15
20
5.4
4
9:44
19.31
1.90
12
23
5.2
4
9:45
19.31
1.92
21
23
5.0
4

-------
Calculated Data Summary-Vegetative Run 2
Stack Stack Stack Stack Stack Stack
Time
02
C02
CO
NOx
S02
THC


%
%
ppm
ppm
ppm
ppm

Sampling
19.77
1.23
72.01
12.98
2.06
8.89
Mean
Interval
0.50
0.53
32.85
7.47
2.82
7.40
S.D.
15:32 -18:47
19.70
1.30
67.14
12.50
1.46
6.28
Median
15:32
20.29
0.49
83
3
21.6
9
15:33
20.63
0.24
48
1
12.9
8
15:34
20.63
0.25
48
1
9.0
7
15:35
20.59
0.33
54
2
6.8
7
15:36
20.52
0.41
48
2
6.3
6
15:37
20.66
0.28
37
1
5.1
5
15:38
20.71
0.21
30
1
4.5
5
15:39
20.60
0.33
53
2
4.2
8
15:40
20.24
0.68
67
7
5.0
6
15:41
20.10
0.91
54
10
6.1
6
15:42
19.80
1.01
52
12
6.5
5
15:43
19.70
1.33
50
15
6.2
4
15:44
19.71
1.16
42
13
6.5
4
15:45
20.10
0.88
57
8
4.7
6
15:46
20.23
0.77
40
7
3.5
4
15:47
19.97
0.97
61
9
3.4
7
15:48
20.12
0.94
90
7
2.8
10
15:49
19.58
1.41
102
13
2.5
6
15:50
19.91
0.98
60
9
2.3
7
15:51
20.65
0.36
51
2
2.4
11
15:52
20.65
0.33
62
2
1.2
14
15:53
20.65
0.33
63
2
1.6
14
15:54
20.69
0.26
69
1
0.8
17
15:55
20.68
0.27
78
1
0.9
19
15:56
20.71
0.26
76
1
-0.2
19
15:57
20.70
0.25
74
1
0.4
17
15:58
20.73
0.21
65
1
0.4
19
15:59
20.71
0.23
76
1
1.1
22
16:00
20.70
0.25
78
1
0.4
21
16:01
20.68
0.28
85
1
0.1
24
16:02
20.65
0.30
97
2
0.7
26
16:03
20.70
0.26
80
2
0.3
21
16:04
20.69
0.25
72
1
0.6
19
16:05
20.68
0.26
82
2
0.1
20
16:06
20.65
0.34
85
2
0.1
19

-------
Calculated Data Summary-Vegetative Run 3
Stack Stack Stack Stack Stack Stack
Time
02
C02
CO
NOx
S02
THC


%
%
ppm
ppm
ppm
ppm

Sampling
19.14
1.76
93.73
29.15
2.38
8.16
Mean
Interval
1.33
1.40
101.90
17.02
5.44
13.40
S.D.
5:30-12:20
19.19
1.75
68.10
25.27
0.79
3.01
Median
5:30
20.69
0.32
298
0
2.5
35
5:31
20.69
0.27
281
0
2.5
26
5:32
20.77
0.12
145
0
2.2
21
5:33
20.77
0.09
157
0
2.2
20
5:34
20.79
0.05
127
0
2.1
25
5:35
20.79
0.03
121
0
1.9
15
5:36
20.82
0.00
75
0
1.9
13
5:37
20.84
-0.03
48
0
1.8
9
5:38
20.78
0.00
144
0
1.9
23
5:39
20.76
0.03
163
0
1.9
14
5:40
20.84
-0.04
48
0
1.8
7
5:41
20.84
-0.06
41
0
1.4
7
5:42
20.86
-0.07
37
0
1.8
7
5:43
20.86
-0.07
27
0
1.6
5
5:44
20.86
-0.07
19
0
2.0
6
5:45
20.85
-0.07
26
0
1.7
7
5:46
20.79
-0.05
119
0
1.7
13
5:47
20.78
-0.03
140
0
1.7
16
5:48
20.78
-0.02
140
0
1.5
11
5:49
20.85
-0.06
58
0
1.4
6
5:50
20.84
-0.06
76
0
1.4
9
5:51
20.78
-0.03
135
0
1.3
11
5:52
20.82
-0.03
88
0
1.2
7
5:53
20.87
-0.07
26
0
1.0
4
5:54
20.89
-0.09
15
0
0.9
3
5:55
20.89
-0.09
6
0
0.9
2
5:56
20.90
-0.09
2
0
0.8
2
5:57
20.89
-0.09
9
0
0.8
3
5:58
20.88
-0.09
25
0
0.8
3
5:59
20.88
-0.09
21
0
0.6
2
6:00
20.90
-0.09
6
0
0.7
2
6:01
20.90
-0.10
9
0
0.4
2
6:02
20.90
-0.10
5
0
0.5
2
6:03
20.85
-0.10
2
0
0.6
2
6:04
20.82
-0.10
1
0
1.2
2

-------
6:05
20.82
-0.10
3
0
1.3
3
6:06
20.82
-0.10
5
1
1.5
3
6:07
20.82
-0.10
5
1
1.5
3
6:08
20.82
-0.10
5
1
1.6
3
6:09
20.82
-0.10
6
2
1.6
3
6:10
20.82
-0.10
6
2
1.6
3
6:11
20.82
-0.10
6
3
1.4
3
6:12
20.81
-0.10
7
5
1.2
3
6:13
20.81
-0.10
7
7
0.6
3
6:14
20.80
-0.10
7
11
-0.1
3
6:15
20.78
-0.10
8
15
-0.5
3
6:16
20.77
-0.10
8
19
-0.7
3
6:17
20.75
-0.10
8
22
-0.7
3
6:18
20.73
-0.10
8
25
-0.7
3
6:19
20.72
-0.10
8
28
-0.7
3
6:20
20.72
-0.10
9
30
-0.7
3
6:21
20.72
-0.10
9
32
-0.7
3
6:22
20.72
-0.10
9
33
-0.7
3
6:23
20.73
-0.10
9
35
-0.7
3
6:24
20.73
-0.10
9
36
-0.7
3
6:25
20.73
-0.10
9
37
-0.7
3
6:26
20.74
-0.10
9
38
-0.7
3
6:27
20.74
-0.10
9
39
-0.7
2
6:28
20.74
-0.10
10
40
-0.7
3
6:29
20.75
-0.10
10
41
-0.7
3
6:30
20.74
-0.10
10
42
-0.7
3
6:31
20.74
-0.10
10
43
-0.7
3
6:32
20.74
-0.10
10
44
-0.7
3
6:33
20.74
-0.10
10
45
-0.7
3
6:34
20.74
-0.10
10
45
-0.7
3
6:35
20.74
-0.10
10
46
-0.7
3
6:36
20.75
-0.10
9
47
-0.7
3
6:37
20.74
-0.10
10
47
-0.7
3
6:38
20.74
-0.10
10
48
-0.7
3
6:39
20.74
-0.10
10
49
-0.7
3
6:40
20.75
-0.10
10
49
-0.7
3
6:41
20.75
-0.10
10
50
-0.7
3
6:42
20.75
-0.10
10
50
-0.7
3
6:43
20.75
-0.10
9
50
-0.7
3
6:44
20.75
-0.10
10
51
-0.7
3
6:45
20.75
-0.10
10
51
-0.7
2
6:46
20.75
-0.10
10
52
-0.7
2
6:47
20.75
-0.10
10
52
-0.7
2

-------
Master ACD Data Sheet r2_QCwith DLs.xls
Metals (pg/Nm 3)
Barium
Beryllium
Chromium
Cobalt
Lead
Mercury
Nickel
Selenium
Silver
PAHs (ng/Nm3)
Naphthal ene
2-Methylnaphthalene
Acenap hthylene
Acenap hthene
Fluorene
Phenanthrene
Anthracene
Fluoranth ene
Pyrene
Benzo(a)A nthracene
Benzo(b)Fluoranthene
Benzo(k)Fluoranthene
Benzo(e)Pyrene
Benzo(a)Pyrene
Perylene
Veg Run 1 Veg Run 2 VegRun3
Veg Run 1
32573
5487
4209
Veg Run 2
34192
6244
3444
C&D Run 1
39 77
21 62
Veg Run 3
77266
6733
7564
C&D Run 1
71159
10332
23001
29992
49461
5577
18179
49724
14312
21731
C&D Run 3
72690
22079
32439
12449
4399
3448
Veg Run 1 Veg Run 2 Veg Run 3 C&D Run 1 C&D Run 2 C&D Run 3 Average Veg Average C&D
160 17
41 71
575 62
5446
143 28
25043
297 35
5597 78
526 55
23 49
Veg Run 1 Veg Run 2 Veg Run 3 C&D Run 1
3038
5824
40670
3925
57635
31791
4323
5603
23100
13906
2333
21226
164943
7679
90313
129 59
54 00
4928 19
368 25
INDeno(1,2,3-cd)Pyrene
1219E
177127
394301
17158
89642
397382
54216
195302
82249
32961
46823
16173
27940
12476
1405
23843
C&D Run 2
1557485
399895
659476
216712
655571
126019
248981
87976
68954
77785
70313
22079
Average Veg f
1 345485
5 45726
' 36269
5 2963
12272
90342
5736
42699
19338
339533
567518
49304
182915
571979
123687
244677
311'
Filterable Particulate
d Gases (mg/Nm3)
Veg Run 1 Veg Run 2 Veg Run 3 C&D Run 1
M5 PM aNDA
C&D Run 2
45 56
30 28
Veg Run 1 Veg Run 2 Veg Run 3 C&D Run 1 C&D Run 2 C&D Run 3 Average Veg Average C&D
SVOCs (pg/Nm 3)
N-Nitrosodimethylamine
s-Dichloroethyl ether
2-Chlorophenol
1.3-Dichlorobenzene
1.4-Dichlorobenzene
Benzyl Alcohol
1.2-Dichlorobenzene
2-Methylphenol
Bis(2-chloroisopropyl)ether
3 &4-Methylphenol
N-nitroso-di-n -propylamine
Hexachloroeth ane
Nitrobenzene
Isophorone
2-Nitrophenol
2,4-Dimethylphenol
Bis (2-chloroethoxy)m ethane
2,4-Dichlorophenol
1.2.4	-Trichlorobenzene
Naphthal ene
p-Chloroaniline
Hexachloro- 1,3-butadiene
4-Chloro-3-m ethyl phenol
2-Methylnaphthal ene
1-Methylnaphthal	ene
Hexachlorocyclopentadiene
2,4,6 -Trichlorophenol
2.4.5	-Trichlorophenol
2-Chloronaphthal	ene
2-Nitroaniline
1,4-Dinitrobenzene
Dimethyl phthalate
1.3-Dinitrobezene
Acenap hthylene
2,6-Dinitrotoluene
1,2-Dinitrobenzene
3-Nitroaniline
Acenaphthene
2.4-Dinitrophenol
4-Nitrophenol
Dibenzofuran
2,4-Dinitrotoluene
2,3,4,6-Tetrachlorophenol
2,3,5,6-Tetrachlorophenol
Diethylphthalate
4-Chlorophenyl phenyl ether
Fluorene
4-Nitroaniline
4,6-Dinitro-2-m ethylphenol
Diphenylamine
Azobenzene
4-Bromophenyl phenyl ether
Hex achloroben zene
Pentachlorophenol
Phenanthrene
Anthracene
Carbazole
Di-n-butyl phthalate
Fluoranthene
Benzyl butyl phthalate
Bis (2-ethylhexyl)adi pate
Ben z[a]anthracene
Bis(2-ethylhexyl) phthalate
Di-n-octyl phthalate
Ben zo[b]fluoranthene
Ben zo[k]fluoranthene
Ben zo[a]pyrene
o laboratory analysis
Veg Run 1 Veg Run 2 Veg Run 3 C&D Run 1 C&D Run 2 C&D Run 3
C&D Run 1 C&D Run 2 C&D Run 3
578 39
27743
4246
56 07
271 30
296 1 3
INDeno[1,2,3-cd]pyrene
Veg Run 1 Veg Run 2 Veg Run 3 C&D Run 1 C&D Run 2 C&D Run 3
Veg Run 1 Veg Run 2 Veg Run 3 C&D Run 1 C&D Run 2 C&D Run 3
Chlor
tieth an
Vinyl chloride
1,3-Butadiene
Bromometh ane
Chloroethane
Trichloromonofluor
1,1-dichloroethene
4999 6
1724 7
5834 0
306 3
1

-------
Master ACD Data Sheet r2_QCwith DLs.xls
1.1.2-trichloro-1,2,2-trifluoroethane
Ethanol
Carbon disulfide
Isopropyl alcohol
Methylene chloride
t-1,2-dichloroethene
Hexane
Methyl-t-butyl ether (MTBE)
1.1-Dichloroeth	ane
Vinyl acetate
cis-1,2-dichloroethene
Cyclohexane
Chloroform
Ethyl Acetate
Tetrahydrofuran
1.1.1-trichloroethane
Carbon Tetrachloride
2-Butanone
Heptane
Benzene
1.2-dichloro	ethane
Trichloro ethylene
1,2-dichloro propane
Bromodichlorom ethane
cis-1,3-dichloropropene
Toluene
4-Methyl-2-pentanone (MIBK)
t-1,3-dichloropropene
Tetrachloroethylene
1.1.2-trichloroethane
Dibromochlorom ethane
1.2-dibromoethane
2-Hexanone
Ethylben zene
Chlorobenzene
m/p-Xylene
0-Xylene
Styrene
Tribromom ethane
1,1,2,2-tetrachloroethane
1-ethyl-4-m	ethylbenzene
1,3,5-trimethylbenzene
1,2,4-trim ethylbenzene
1.3-dichlorobenzene
1.4-dichloro	benzene
Benzyl chloride
1,2-dichlorobenzene
1,1,2,3,4,4-h exachloro-1,3-butadiene
1,2,4-trichlorobenzene
PM (m g/Nm3)
Filterable Particulate PM2.5
Organic CoNDensible Particulate
Inorganic CoNDensible Particulate
Total Particulate 
-------
Appendix B: Field Data
.Andersen PM10
.Asbestos
. CEMs
. Method 5-26A
Method 9
.Method 0010
. Method 23
. Method 29
. PM2.5-M202
-------
ISOKINETIC SAMPLING FIELD DATA
RTI/EPA
K FACTOR SETUP DATA
i "^^AjCD-PMlO-
TEST DATE
Slack Temp.
Av«. Dd. P
PLA-VT LOCATION • CITY/STATF
Chalmette, LA
Meter Tetnp.
SAMPLING LOCATION
RUN START/STOP TIME
Air Curtain Destructor


BAROM
Straps Ra*
STATIC
prroT
meter box
k factor
PRESSURE
PRESSURE
TtJBE
DELTA
OPERATORS
CAL. FAC,
GAMMA (Y)
Intermediate L^«t tlvrt.
in. H2Q)
F>trt«
NUMBER
INSIDE DlA.
0.
NUMBER
FILTERS)
FLUE GAS
IMPINGES
PITOT
SAMPLE TRAiN LFak CHECK.
number
TARE
PTTOT
NUMBER
THERM
THERM,
LEAK
initial
FINAL
NUMBER
NUMBER
*
FLUB
DRY OAS
METER
TEMP, (dei P>
IN OUT
FILTER
DRY OAS
METER READING
(cubic feoft
SAMPLE
TRAIN
VACUUM
t«t Hi)
PITOT
heading
(in H2Q1
DELTA H
ORIFICE
Cat men
PROBB
TEMP,
Sfol-R
POINT
NUMBER
OVEN
TEMP.
TEMP.
TEMP;
blc .tf
£? z>n
C 7y. 5"3
-------
7-B
ISOKINETIC SAMPLING FIELD DATA
			—			 PL.IVT NAME

RTI/EPA
Kv. iN > L MHrB
^"^-ACD-PMlO- f
		 PLANT LOCATION - UTY ST UK

Chalmette, LA

				 	SAMPLING LOCATION
	' /
Air Curtain Destructor

POINT
NUMBER
elapsed
TEST
TIME
(mia.)
DRY OAS
METER READING
(cubic feel)
	7 	
PITOT
READING
i in. H2C>\
DELtAH
ORIFICE
(in, H20)
PROBE
TEMP.
fde*.F)
FLUB
GAS
TEMP.
(J«-P)
DRY GAS
METER
TEMP, 
^4-

125
7t7.3?
esil
<0.Qr(
zrr
-2,7 r
4/
ff


\Z
/
1

130

0. 75
' ffi.G/

2,7 r

0#%

2- j"2.
<2,7 r~
n
' f^



rr

j

170
7*3. K
ws

Zrz~
2-7 r
*1
ez


rr



175
7T
"
*1



f2-
I*
I

190

to.rl
0,hty
0H$-
06*
znz.
2s>r
ft
rf


fo
(0


200
rrr.v,
0,93
0&O
£r~?.
<£?-*?$ 0>Q>0
2sry
27>*~
9*


yy
It


210
Zrr.fY
M3>

zc y
Z7f
n
r^i

7f
If



215
761.2-/

06&
U
(Z



230
7Cr. 1t-

0,6*
Z


n



ft-



235
79/. /
0.93
0.6#
Z9&
t?r<
fi,
n



	I	
iy



240
7? 5. *f

C a\ G#

z?ri
^ 1
r?



n



245
7?r. &/

0,6*0
Z9&
wr i
?Zk
rz


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/y



260
?rz-'S2~
0.9%
oj#
Z*rt>
&?r d
ft d
?z

<
ry
ir



265
7r
-ri
Total
Run Time
Total Volume Metered
Avg. S^RT
Delta P
Avg, Delta H




Avg Hue
Gju Temp
Avg, Dry G*»
Meier Temp.



ARCADIS U.S., Inc.
2 T
Page	of
-------
7-C
ISOKINETIC SAMPLING FIELD DATA
RUN NUMBm
RTl/EPA
PVI10
plant location - rrrvOTATc
TEST DATE
Chalmette, LA
SAMPI INC KX'A fKW
RUN START^TOPnMB
\ir Curtain Destructor

dry gas
METER
TEMP. (dtg. F)
IN OUT
SAMPLE
DRY GAS
METER READING
.cubic feet)
prror
READING
to. H2Q)
DELTAH
ORIFICE
(in. H2Q)
PROBE
rEMP
OVEN
POINT
VUMBER
TRAIN
TEMP
TEMP
TEMP
VACUUM
TEMP.
?fb, 7fo
7- 72-
n
a
747
iP'°.Zr
c?7

7C
2*
T.itaJ
Run Pirne
H'taJ Volume Metered
Avg. SQRT
Delta P

pr

tffc

Avg Hue
G*.i r<"mp
A\g. Dry Oa*
Meter JVmn.

rs

ARCADIS U.S., Inc.
Page	3
-------
ISOKINETIC SAMPLING FIFI.D DATA
plant n ame
RUN NUMBER
RTI/EPA
K FACTOR SETUP DATA
7'^r"ACD-PMiQ- /
Stack Temp.
PLANT LOCATION - CITY*tatt
fESTDATE
Chalmette. LA
Avg. Del. P
Meier Temp.
% H20
SAMPLING LOCATION
RUN ST^oUTSTOP TIME
Air Curtain Destructor
MEHSR BOX
Rate
K FACTOR
BAROM
PRESSURE
Qt>. Hi)
staitc
PRESSURE
(jn. H2Qi
PITOT
tube
N02ZUS
DELTA
CAL. FAC
OPERATORS
Zr$~F>
tmcnnpMue Leak IM.
NUMBER
INSIDE DIA
<£«£//
number
/.?

QAMMA (Y1
FILTERfs)
FLUE GAS
PITOT
SAMPLE TRAIN LEAK fHOTr
NUMBER
tare
PITOT
NUMBER
THERM
fHERM.
INITIAL
final
NUMBER
NUMBER

elapsed
TEST
TIME
(min.)
FLUB
DRY OAS
METE*
TEMP, (del P)
IN OUT
W\
FILTER
OVEN
TEMP.
i&Lfi
DRY OAS
METER READING
(cufek feet)
SAMPLE
TRAIN
VACUUM
PfTOT
DELTA H
ORIFICE
(in, H2Q}
PROBfl
HEMP.
(^3LH
POINT
NUMBER
READING
AUX
TEMP.
iio. H2Q)
TEMP.
<$n. OOL-
0.Z7,
A*-3f
%
cfzaJv
- n
(P/(f. v/
z?
W*-. n
crw, 72-
-------
5-B
ISOKINETIC SAMPLING FIELD DATA
• ^ 1 >L,LU Ut\ I A
	•	—			 plant name

RTT/EPA
RUN NLMbfcK
			—	 PLANT L OCATION • (TTY STA IF

Chalmette, LA
h/frr! 0 rf
		 SAMPLING LOCATION
—V 
FLUB
GAS
TEMP.
(*feg.
DRY GAS
METER
TEMP fdeg. F)
IN OUT
#Wi
FILTER
OVEN
TEMP.
Jdcj.
IMP.
EOT
TEMP.
SAMPLE
TRAIN
VACUUM
(ta.
AUX.
TEMP.
A/ ^f*~
125
ft'.ir

£>3e
~i*r?

f 3


130
135
140
145
150
155
160
165
170
175
180
185

03?

r
^ &
-------
ISOKINETIC SAMPLING FIELD DATA
plant name
RUN NUMBER
RTI/EPA
K FACTOR SETUP Data
ACD-PM10-
Stacfc Temp.
PLANT LOCATION - CITY/STATB
rESTDATE
Chalmette. LA
Av'n Del, p
SAMPLING LOCATION
RUN START/STOP TIME
/ryr-
Air Curtain Destructor
% H20
S*mpfr Rag
BAROM
PRESSURE
tin. Hi)
STATIC
PRESSURE
PITOT
METERBOX
K FACTOR
rUBfi
DELTA
CAL FAC
Imermediaie Leak Checki
OPERATORS
OS) h
(in. H2Q)
NUMBER
INSIDE DIA
NUMBER
otzn
GAMMA (Y)
aft?
FILTERS)
FLUE GAS
THERM
NUMBER
IMPfNGER
PfTOT
SAMPLE TRAIN LEAK CHECK
INITIAL
NUMBER
TARE
PITOT
NUMBER
rHERM.
LEAK
FINAL
NUMBER
CHECK
DRY OAS
METE*
rF-MP «kf. F)
IN OUT

9/2, 7v
4\f. 
-------
7-B
ISOKINETIC SAMPLING FIELD DATA
				PLOT N'AME

RTI/EPA

			—			PLANT LOCATION - CITVS1ME

Chalmette, LA
('/zr/'Of
					SAMPLING LOCATION
	/				
Air Curtain Destructor

POINT
NUMBER
ELAPSED
TEST
TIME
(rnia.1
DRY OAS
METER READING
'cubic fed}
prrcrr
reading
(i(L H201
DELTAH
ORIFICB
(in. H20>
PROBE
TEMP.
CJ«.B
FLUB
OAS
TEMP.
(ifcftF)
DRY OAS
METER
TEMP. (deg. i
IN OUT
FILTER
OVEN
*) TEMP.
fUefcPy
IMP.
EOT
TEMP,
SAMPLE
TRAIN
V ACIT.'M
AUX [
TEMP. I

120
W
&k1
/
Z+fCr

73
?*}
' a/ 4-


	R I

125
f
0.
t-Sf
2^11?

7?
71
)

	1 ^	
!(,


130
'm. Vf


zw

?Z
71

rv
n

	

135
fr>. sv
an
1.0*1

3^-c?

7<,
I
ry
AP



140
Ifo. fr
o.W

Z*~0
Z&o
?3
7
?1
71
i/
rc
£-/
	1
-	 J

160












165












170












175












180












185












190












195












200












205












210












215












220












225












230












235












240












245












'250












255












260












265











IVtai
Run Time
Tnrai Volume Metered
Avg. MjRT
DeftaP
Avg. Delta H
/L*
ifsr
*7
/. «=»r—
Avg Hue
Gfu femp
Avg. Dry Qa
Meter Temp.
2^0z>
77

ARCADIS U.S., Inc.
Page Zrof_^~~
-------
5-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
RTl/EPA
K FACTOR SETUP DATA
I^-^ACD-PMIO- /
Stack Temp.
PLANT LOCATION- CITY/STATE
TEST DATE
\va. Del. P
Chaimette, LA
SAMPLING LOCATION
RUN START/STOP TIME
% H20
Air Curtain Destructor
Smpte Rate
BAROM
STATIC
prror
METER BOX
K FACTOR
PRESSURE
PRESSURE
TUBE
NOZZI.E
DELTA
CAL. FAC
U*k Check*
OPERATORS
I in. H2Q)
NUMBER
INSIDE DIA.
G-s. ho
NUMBER
GAMMA 00

FILTERS)
FLUE GAS
THERM-
NUMBER
fMPiNGER
THERM.
NUMBER
PfTOT
SAMPLE TRAIN LEA
NUMBER
prror
NUMBER
INITIAL
FINAL
FLUB
DRY OAS
METER
TEMP, (dfeg, F)
IN OUT
FILTER
OVEN
TEMP.
DRY OAS
METER READING
cubfefecti
SAMPLE
TRAIN
VACUUM
(ia Hg)
prror
READING
(at H2Q;
DELTA H
ORfflCE
(iiL H2Q)
PROBB
TEMP.
POINT
NUMBER
A OX
TEMP.
TEMP
(cubic ft
m.ifa
iff'. $$
iff. ~?s
T*otrL
%
f*°Sx
iff. $
-------
5-B
ISOKINETIC SAMPLING FIELD DATA
RTI/EPA
RIN NTMRFB
o- u -ACD-PMIO- /
Chalmette, LA
PL INT LOCATION CrTY-ST vr E

Air Curtain Destructor
SAMPLING LOCATION
RL N START/STOP TM
0T** - /2.7T
1011. V7
PTTOT
READING
(in H2Q)
^¦5 I
4-11
DELTAH
ORIRCH
fin. H2C
e?r?(
o7,
0.7/
OSI1 p. 7/
2L
QJ/ €Jf
I 0.71
PROBE
TEMP,
(dcg. F
7<±
Zr
JT
cs
kl_
(*1

SAMPLE
TRAIN
VAOOTM
(in. Hj
r
r
2
265
I'.raj
Run Time
Tr
*.ST-)
*• ?/
Avg Flue
Gai Temo
Avg. Dry Gaa
Meter Temo
/7f


ARCADIS U.S., Inc.
p 2~- 2—
Page __ of		
-------
6-A
PLANT NAME
RUN NUMBER

RTI/EPA
?-<2£»acd-pmio- l~
Stack Temp.


PLANT LOCATION - CITY/STATE
TEST DATE



Chalmette, LA

Meter Temp.


SAMPLING LOCATION
/ r
RUN START/STOP TIME
* H20


Air Curtain Destruct
or


/*//
Sample Rate


OPERATORS
BAROM.
PRESSURE
(in. H«>
STATIC
PRESSURE
f in. H20)
PtTOT
TUBE
Cp

METER six
K FACTOR at


N02
-ZLE
NUMBER
DELTA
HO
CAL. FAC
GAMMA (Y)
Intermediate Leak Checks

NUMBER
INSIDE DIA.


frS ,h0


off

OMi
vzxr?
/?
if a


FILT
ER(s)
PtTOT
NUMBER
FLUEGAS
THERM.
NUMBER
IMPING ER
THERM.
NUMBER
prror
LEAK
CHECK
SAMPLE TRAIN LEAK CHECK


NUMBER
TARE
INITIAL
FINAL




in. Hr
cfm
Ha
cfm








15
0. cay
jr
0.»(


POINT
NUMBER
ELAPSED
TEST
TIME
(milt)
DRY GAS
METER READING
(cubic feet)
PTTOT
READING
(in. H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP.
(«UMt. P)
FLUE
GAS
TEMP.
(de*.F)
DRY GAS
METER
TEMP. (deg. F1
IN OUT
FILTER
OVEN
TEMP.
(deg.F)
IMP.
EXIT
TEMP.
SAMPLE
TRAIN
VACUUM
AUX.
TEMP.

0

o.w
!Q*t
J ft
/ tf-v*
;;
19

97

	fdcg- &

5
/M
W¥
2-f? /
(y
Z&
iy
y


30

W9
oy
If/
/y^
So
IS


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r


35
lof. oY
0,9 Y
hoy.
2S/

fO
7*


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r


40
¦—
0S*1

2^f
19*
fo
7p


a
i*~



45
lit- o#
aytf
>.W
W
/Y a
3./f
°W/
1.0f-
2
/¥*
ft
T9


rr



)T o
f


100


<.oy
zfy
tlf
ez-


r#
/£?


105
/V?. 


110
/r*. of

i.oy
2~vy
/if 9
n
ft


r/
//


115


m
2 yZ
ffyo
93

if


//










ARCA
DIS U.S
Inc.

Total
Run Time
Total Volume Metered
Avg, SQRT
Delta P
Avg. Delta H

Avg Flue
Gas Temp
Avg. Dry Ga*














Page
f of

*
<£j
-------
5-B
ISOKINETIC SAMPLING FIELD DATA
RTI/EPA
RUN M 'MRFg
-ACD-PMIO- 2-
PLA.VT LOCATION - CtTY/STATR
Chalmette, LA
rest date
(0
SAMPLING LOCATmW
\ir Curtain Destructor
m.1* START/STOP Tnup
/*/r- /
-------
7
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K FACTOR SETUP DATA
RTI/EPA Q
<24~-acd/
Stack Temp.


PLANT LOCATION • CITY/ST ATE
TEST DATE
Av*. Del. P
c.v f

Chalmette, LA

Meter Temp.
f*

SAMPLING LOCATION
t /
RUN START/STOP TIME
% H20
z^

Air Curtain Destructor
n%!f - rfz#
Sarapk Rate
0.75

OPERATORS
BAROM.
PRESSURE
(in- Hr)
STATIC
PRESSURE
(id- H20)
prror
TUBE
Cp
NOZZLE
METER BOX
K FACTOR «


NUMBER
DELTA
H9
CAL. FAC.
GAMMA (Y)
Intermediate Le*k Checks
Pyrites
NUMBER
INSIDE DJA.


6-5


off


ZoKi
f'f



FILT
ER(s)
PITOT
NUMBER
FLUE GAS
THERM.
NUMBER
IMPtNGER
THERM.
NUMBER
pttot
LEAK
CHECK
SAMPLE TRAIN LEAK CHECK


NUMBER
TARE
INITIAL
FINAL




in. H*
cfra
in. H*
cfm








15
O/Cr 0**
r-
O,


POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
DRY GAS
METER READING
(cubic foa)
prrerr
READW0
(to. H20)
DELTA H
ORIFICE
(fat H20>
PROBE
TEMP.
(Aw.P>
FLUE
GAS
TEMP,
DRY GAS
METER
TEMP. (deg. F)
IN OUT
FILTER
OVEN
TEMP.
(dea-F)
IMP.
EXIT
TEMP.
(dea.Fl
SAMPLE
TRAIN
VACUUM
AUX
TEftP
idea. F)

0


!.

.£2
aw

2/1 &
tn,
ff
f*


r?
(



65

QM
1*1
Z3j
/tt
ft
»


S1
(



70
Ma-
O.cff
t.0f
zz-r

V
fo


Sf
/



75
til. If
0.
2*1 <
?o7

-------
8
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER.

RTI/EPA £
'^b-ACD-waasA- /
Stack Temp.
/7r~

PLANT LOCATION - CITY/STATE
TEST DATE
Av*. Del P


Chalmette, LA

Meter Terap.
¦ft?

SAMPLING LOCATION
	1	1	—
RUN START/STOP TIME
% H20


Air Curtain Destruct
or

Sampie Rale
0.75

OPERATORS
BAROM.
PRESSURE
(in. Hg)
STATIC
PRESSURE
(in. H20)
pttot
TUBE
Cp

METER BOX
K FACTOR*


N02
ZLE
NUMBER
DELTA
H®
CAL. FAC.
GAMMA lY)
Intermediate Leak Checks

NUMBER
INSIDE DIA.



%&
DELTA H
ottmm
(in.H20>
PROBE
TEMP.
(de«.F>
FLUE
GAS
TEMP,
(deg, F)
DRY GAS
METER
THMP- (Jef. F)
IN OUT
FILTER
OVEN
TEMP.
IMP.
EXIT
TEMP.
(detF)
SAMPLE
TRAIN
VACUUM
AUK
TEMP.

0
fw. y£ £
o.ii
f.V°
W
/?
-------
9
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN MEMBER
K FACTOR SETUP DATA
RTl/EPA C-
ns %"Sf3
^-ACD-mmA-- c-
Stack Tenq).


PLANT LOCATION - CITY/STATE
TESTDATE
Avg. Del. P
4,0J

Chalmette, LA

Meter Temp.
f2^

r°


/
f/ A-

5

OM>
LoC



(f/
/

rr
1



10

O/ffl


/W
IV



Tf
(



15
f?/ .££-
oM
£.V
f



20
. 7/
0<(» 3


flS
It


ZAfU
tie

a


&7
f



30


2*Y

/Zf

2
Zo
o.ty
Z
Z.o¥
LH 3
tzr
]>
2'0y
WS
t2S>

fo


r?
(


100
(Of 7.77
0.6 3
2.ay
Z<
-------
PRE-TEST AND POST-TEST CALIBRATION SUMMARY
Source Description:
ACD New Orleans
Calibration Curve Parameters
Sample Type:
End of Transfer Tube
Monitor
Slope
Intercept
Test Method(s):
EPA3A, 10, 6C, 25A



Test Number:
ACD CEM 1
Servomex 02
1.007
-0.060
Date:
06/24/08
CAI C02
1.015
-0.071


CAI CO
1.037
-4.770


CAI S02
1.087
-1.631


VIG THC
0.941
0.000


Eco Physics NC
1.120
-0.028
Monitor		Direct Calibration	Pre-Test Bias Check — — Post-Test Bias Check —
Site, Gas (Units) Gas Tag	Monitor	% Monitor	% Monitor	%	%
Range	Value Reading	Error Response	Error Response	Error	Drift
Servomex	0.00	0.00	0.0%	0.00	0.0%	0.12	0.5%	0.5%
Stack 02 (%)	9.01	9.00	0.0%
0-25%	19.00	19.00	0.0%	18.90	-0.4%	18.97	-0.1%	0.3%
Cal Analylical	0.00	0.09	0.5%	0.05	0.3%	0.09	0.5%	0.2%
Stack C02(%)	8.93	9.58	3.3%	9.63	3.5%	9.51	2.9%	-0.6%
0-20%	19.00	19.00	0.0%	18.88	-0.6%	18.70	-1.5%	-0.9%
Cal Analylical	0	-1	-0.1%	1	0.1%	8	0.8%	0.7%
Stack CO(ppm)	450	445	-0.5%	436	-1.4%	441	-0.9%	0.5%
0-1000 ppm	900	900	0.0%
Cal Analylical	0	0	0.0%	3	0.6%	0	0.0%	-0.6%
Stack S02(ppm)	225	238	2.7%	209	-3.1%	208	-3.5%	-0.4%
0-500 ppm	450	450	0.1%
VIG	0	0	0.0%	0	0.0%	0	0.0%	0.0%
Stack THC(ppm P	450	440	-1.0%	440	-1.0%	516	6.6%	7.6%
0-1000 ppm	900	902	0.2%
0	0	0.0%	0	0.0%	0	0.1%	0.1%
Stack NOx (ppm)	95	100	2.5%	89	-3.1%	81	-7.1%	-4.0%
0-200 ppm	190	190	0.0%
-------
PRE-TEST AND POST-TEST CALIBRATION SUMMARY
Source Description:
ACD New Orleans
Calibration Curve Parameters
Sample Type:
End of Transfer Tube
Monitor
Slope
Intercept
Test Method(s):
EPA3A, 10, 6C, 25A



Test Number:
ACD CEM 2
Servomex 02
1.008
-0.116
Date:
06/24/08
CAI C02
1.023
-0.061


CAI CO
1.053
2.686


CAI S02
1.040
-2.341


VIG THC
0.923
0.923


Eco Physics NC
1.018
-0.977
Monitor		Direct Calibration	Pre-Test Bias Check — — Post-Test Bias Check —
Site, Gas (Units) Gas Tag	Monitor	% Monitor	% Monitor	%	%
Range	Value Reading	Error Response	Error Response	Error	Drift
Servomex	0.00	0.00	0.0%	0.12	0.5%	0.11	0.4%	0.0%
Stack 02 (%)	9.01	9.00	0.0%
0-25%	19.00	19.00	0.0%	18.97	-0.1%	18.94	-0.2%	-0.1%
Cal Analylical	0.00	0.09	0.5%	0.09	0.5%	0.03	0.2%	-0.3%
Stack C02(%)	8.93	9.58	3.3%	9.51	2.9%	9.49	2.8%	-0.1%
0-20%	19.00	19.00	0.0%	18.70	-1.5%	18.57	-2.2%	-0.6%
Cal Analylical	0	1	0.1%	0	0.0%	-5	-0.5%	-0.5%
Stack CO(ppm)	450	444	-0.6%	422	-2.8%	427	-2.3%	0.5%
0-1000 ppm	900	900	0.0%
Cal Analylical	0	0	0.0%	4	0.9%	0	0.0%	-0.9%
Stack S02(ppm)	225	233	1.6%	224	-0.1%	213	-2.5%	-2.4%
0-500 ppm	450	448	-0.4%
VIG	0	0	0.0%	0	0.0%	-2	-0.2%	-0.2%
Stack THC(ppm P	450	452	0.2%	452	0.2%	521	7.1%	6.9%
0-1000 ppm	900	903	0.3%
0	1	0.5%	1	0.3%	1	0.7%	0.4%
Stack NOx (ppm)	95	101	2.9%	92	-1.5%	97	0.8%	2.2%
0-200 ppm	190	190	0.2%
-------
PRE-TEST AND POST-TEST CALIBRATION SUMMARY
Source Description:
ACD New Orleans
Calibration Curve Parameters
Sample Type:
End of Transfer Tube
Monitor
Slope
Intercept
Test Method(s):
EPA3A, 10, 6C, 25A



Test Number:
ACD CEM 3
Servomex 02
1.004
-0.100
Date:
06/25/08
CAI C02
1.015
-0.086


CAI CO
1.033
-1.807


CAI S02
1.080
-0.810


VIG THC
1.003
0.000


Eco Physics NC
1.036
-0.114
Monitor		Direct Calibration	Pre-Test Bias Check — — Post-Test Bias Check —
Site, Gas (Units) Gas Tag	Monitor	% Monitor	% Monitor	%	%
Range	Value Reading	Error Response	Error Response	Error	Drift
Servomex	0.00	0.06	0.2%	0.09	0.4%	0.11	0.4%	0.1%
Stack 02 (%)	9.01	9.08	0.3%
0-25%	19.00	19.09	0.4%	18.94	-0.2%	19.12	0.5%	0.7%
Cal Analylical	0.00	0.01	0.1%	-0.07	-0.4%	0.24	1.2%	1.6%
Stack C02(%)	8.93	9.79	4.3%	9.67	3.7%	9.48	2.8%	-0.9%
0-20%	19.00	19.03	0.2%	18.97	-0.2%	18.63	-1.9%	-1.7%
Cal Analylical	0	-1	-0.1%	-1	-0.1%	4	0.4%	0.5%
Stack CO(ppm)	450	446	-0.4%	437	-1.3%	439	-1.2%	0.2%
0-1000 ppm	900	900	0.0%
Cal Analylical	0	0	0.0%	1	0.3%	0	0.0%	-0.3%
Stack S02(ppm)	225	237	2.3%	208	-3.4%	210	-2.9%	0.5%
0-500 ppm	450	450	0.1%
VIG	0	0	0.0%	0	0.0%	0	0.0%	0.0%
Stack THC(ppm P	450	449	-0.1%	449	-0.1%	448	-0.2%	-0.1%
0-1000 ppm	900	903	0.3%
0	0	0.1%	0	0.0%	0	0.1%	0.0%
Stack NOx (ppm)	95	99	2.0%	94	-0.5%	90	-2.7%	-2.2%
0-200 ppm	190	189	-0.5%
-------
PRE-TEST AND POST-TEST CALIBRATION SUMMARY
Source Description:
ACD New Orleans
Calibration Curve Parameters
Sample Type:
End of Transfer Tube
Monitor
Slope
Intercept
Test Method(s):
EPA3A, 10, 6C, 25A



Test Number:
ACD CEM 4
Servomex 02
1.003
-0.100
Date:
06/25/08
CAI C02
1.026
-0.154


CAI CO
1.038
-2.698


CAI S02
1.033
-0.103


VIG THC
1.014
-0.507


Eco Physics NC
1.033
-0.124
Monitor		Direct Calibration	Pre-Test Bias Check — — Post-Test Bias Check —
Site, Gas (Units) Gas Tag	Monitor	% Monitor	% Monitor	%	%
Range	Value Reading	Error Response	Error Response	Error	Drift
Servomex	0.00	0.06	0.2%	0.11	0.4%	0.09	0.4%	-0.1%
Stack 02 (%)	9.01	9.08	0.3%
0-25%	19.00	19.09	0.4%	19.12	0.5%	18.97	-0.1%	-0.6%
Cal Analylical	0.00	0.01	0.1%	0.24	1.2%	0.06	0.3%	-0.9%
Stack C02(%)	8.93	9.79	4.3%	9.48	2.8%	9.55	3.1%	0.4%
0-20%	19.00	19.03	0.2%	18.63	-1.9%	18.72	-1.4%	0.4%
Cal Analylical	0	-1	-0.1%	4	0.4%	1	0.1%	-0.3%
Stack CO(ppm)	450	446	-0.4%	439	-1.2%	434	-1.6%	-0.5%
0-1000 ppm	900	900	0.0%
Cal Analylical	0	2	0.3%	0	0.0%	0	0.0%	0.0%
Stack S02(ppm)	225	229	0.8%	210	-2.9%	226	0.1%	3.1%
0-500 ppm	450	448	-0.3%
VIG	0	0	0.0%	0	0.0%	1	0.1%	0.1%
Stack THC(ppm P	450	449	-0.1%	448	-0.2%	441	-0.9%	-0.7%
0-1000 ppm	900	903	0.3%
0	0	0.0%	0	0.1%	0	0.1%	0.0%
Stack NOx (ppm)	95	97	0.8%	90	-2.7%	94	-0.3%	2.4%
0-200 ppm	190	187	-1.5%
-------
PRE-TEST AND POST-TEST CALIBRATION SUMMARY
Source Description:
ACD New Orleans
Calibration Curve Parameters
Sample Type:
End of Transfer Tube
Monitor
Slope
Intercept
Test Method(s):
EPA3A, 10, 6C, 25A



Test Number:
ACD CEM 5
Servomex 02
1.009
-0.111
Date:
06/26/08
CAI C02
1.008
-0.015


CAI CO
1.079
-2.319


CAI S02
1.115
-14.045


VIG THC
1.012
-1.012


Eco Physics NC
1.072
-0.054
Monitor		Direct Calibration	Pre-Test Bias Check — — Post-Test Bias Check —
Site, Gas (Units) Gas Tag	Monitor	% Monitor	% Monitor	%	%
Range	Value Reading	Error Response	Error Response	Error	Drift
Servomex	0.00	0.06	0.2%	0.09	0.4%	0.13	0.5%	0.2%
Stack 02 (%)	9.01	9.09	0.3%
0-25%	19.00	19.06	0.2%	18.95	-0.2%	18.92	-0.3%	-0.1%
Cal Analylical	0.00	0.00	0.0%	0.03	0.2%	0.00	0.0%	-0.2%
Stack C02(%)	8.93	9.36	2.2%	9.34	2.1%	9.33	2.0%	0.0%
0-20%	19.00	19.00	0.0%	18.81	-1.0%	18.93	-0.4%	0.6%
Cal Analylical	0	0	0.0%	0	0.0%	4	0.4%	0.4%
Stack CO(ppm)	450	447	-0.3%	417	-3.3%	422	-2.8%	0.5%
0-1000 ppm	900	901	0.1%
Cal Analylical	0	0	-0.1%	0	0.0%	25	5.0%	5.0%
Stack S02(ppm)	225	232	1.5%	214	-2.2%	215	-2.0%	0.2%
0-500 ppm	450	451	0.1%
VIG	0	0	0.0%	0	0.0%	2	0.2%	0.2%
Stack THC(ppm P	450	445	-0.5%	445	-0.5%	446	-0.4%	0.1%
0-1000 ppm	900	896	-0.4%
0	0	0.1%	0	0.0%	0	0.1%	0.1%
Stack NOx (ppm)	95	99	2.1%	90	-2.3%	87	-4.1%	-1.8%
0-200 ppm	190	191	0.5%
-------
PRE-TEST AND POST-TEST CALIBRATION SUMMARY
Source Description:
ACD New Orleans
Calibration Curve Parameters
Sample Type:
End of Transfer Tube
Monitor
Slope
Intercept
Test Method(s):
EPA3A, 10, 6C, 25A



Test Number:
ACD CEM 6
Servomex 02
1.010
-0.106
Date:
06/26/08
CAI C02
1.003
-0.010


CAI CO
1.077
-4.524


CAI S02
1.134
-2.779


VIG THC
1.011
-1.517


Eco Physics NC
1.086
-0.109
Monitor		Direct Calibration	Pre-Test Bias Check — — Post-Test Bias Check —
Site, Gas (Units) Gas Tag	Monitor	% Monitor	% Monitor	%	%
Range	Value Reading	Error Response	Error Response	Error	Drift
Servomex	0.00	0.06	0.2%	0.13	0.5%	0.08	0.3%	-0.2%
Stack 02 (%)	9.01	9.09	0.3%
0-25%	19.00	19.06	0.2%	18.92	-0.3%	18.92	-0.3%	0.0%
Cal Analylical	0.00	0.00	0.0%	0.00	0.0%	0.02	0.1%	0.1%
Stack C02(%)	8.93	9.36	2.2%	9.33	2.0%	8.94	0.0%	-2.0%
0-20%	19.00	19.00	0.0%	18.93	-0.4%	18.97	-0.2%	0.2%
Cal Analylical	0	0	0.0%	4	0.4%	4	0.4%	0.0%
Stack CO(ppm)	450	447	-0.3%	422	-2.8%	422	-2.8%	0.0%
0-1000 ppm	900	901	0.1%
Cal Analylical	0	2	0.3%	2	0.3%	3	0.6%	0.3%
Stack S02(ppm)	225	230	1.0%	193	-6.3%	208	-3.4%	3.0%
0-500 ppm	450	450	-0.1%
VIG	0	0	0.0%	2	0.2%	1	0.1%	-0.1%
Stack THC(ppm P	450	445	-0.5%	446	-0.4%	447	-0.3%	0.1%
0-1000 ppm	900	896	-0.4%
0	0	0.1%	0	0.1%	0	0.1%	0.0%
Stack NOx (ppm)	95	99	2.1%	87	-4.1%	88	-3.3%	0.7%
0-200 ppm	190	191	0.5%
-------
1
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K FACTOR SETUP DATA
RTI/EPA
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-------
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PLANT NAME
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K FACTOR SETT iP DATA
RTI/EPA (£
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ARCADIS U.S., Inc.
P / f
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Page	of.
-------
2-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RCN NUMBER

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PL \NT LOCATION • t'lTV STATF
FFST DATE

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2-B
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ARCADIS U.S., Inc.
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Page	of ^
-------
3-A
ISOKINETIC SAMPLING FIELD DATA
PL ANT N AME
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-------
3-B
ISOKINETIC SAMPLING FIELD DATA
	 PLANT \.\ME

RTI/EPA ^
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	 PLANT L(X \TION CITY,'ST \TH

Chalinette, LA

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ARCADIS U.S., Inc.
Page of
-------
4-A
ISOKINETIC SAMPLING FIELD DATA
PLWTWME
RL N \L MBER
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I-------
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RU N NUMBER
K FACTOR SETt P DATA
RTI/EPA (
r^ACD-MOOlO- /
Slack Temp.


PI-ANT LOCATION - CITY STATE
TEST DATE
Av*. Del, P


Chalmette, LA
6/26/<0#
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SAMPLING LOCATION
RUN START/STOP TIME
* H20


Air Curtain Destrucl
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125
130
135
140
145
150
155
160
165
170
175
180
185
190
195
200
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215
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2-------
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ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN Nl MBER
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TEST DATE
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Chalniette. LA
TESTDATF.
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Air Curtain Destructor	
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2 , Z 7-------
1-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER

RTI/EPA £
•/^•-ACD-M23- 1
Stack Temp.


PLANT LOCATION - CITY/STATE
TEST DATE



Chalmette, LA




SAMPLING LOCATION
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Air Curtain Destrucf
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0.75

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INSIDE DlA,



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-//*/
0.84
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Cm. H20)
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FLUE
GAS
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i	
-------
1-B
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
RTI/EPA ^
1 -ACD-M23- 1
PLANT LOCATION - CITY/STATE
TEST DATE
Chaimette, LA

SAMPLING LOCATION
	-/¦		
RUN START/STOP TIMF
Air Curtain Destructor
€?V
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90
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130
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ARCADIS U.S., Inc.

Total
Run Time
Total Volume Metered
Avg. SORT
Delta P
Ave. Delta H

Avg FIu<
Gas Temp
Avg. Dry Gas
z_
Paee of


/Vo.0f z.

/. 3r



fc<;
-------
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER

RTI/EPA ^
'&f -ACD-M23- Z—
Stack Temp.


PLANT LOCATION - CITY/STATE
TEST DATE
Ave. Del. P


Chalmette, LA
b/ZY/t?e
	*—	
Meter Temp.


SAMPLING LOCATION
RUN START/STOP TIME
% H20


Air Curtain Destruct
or


/syr^/r
Sample Reft?
0.75

OPERATORS
BAROM.
PRESSURE
. <.in-
STATIC
PRESSURE
(in. H20)
PITOT
TUBE
Cp

METER BOX
K FACTOR =r


N02
21X-.
NUMBER
DELTA
H®
CAL. FAC.
GAMMA (Y>
Intermediate Leak Checks

NUMBER
INSIDE DIA.


h°,31 /^
Zo.&L
-I/-Y
0.84



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F1LT
ER(s)
PfTOT
NUMBER
FLUE GAS
THERM.
NUMBER
IMPINGER
THERM.
NUMBER
PITOT
LEAK
CHECK
SAMPLE TRAIN LEAK CHFCK


NUMBER
TARE
INITIAL
FINAL




in. Hg
cfm










15
0,0000




POINT
NUMBER
ELAPSED
TEST
TIME
(mill.)
DRY GAS
METER READING
(cubic feet)
PITOT
READING
fin. H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP.
FLUE
GAS
TEMP,
(deg. F>
DRY GAS
METER
TEMP. (deg. F
IN OUT
BLTER
OVEN
i TEMP.
(tteK. F)
IMP.
EXIT
TEMP.
SAMPLE
TRAIN
VACUUM
AUX.
TEMP,

0
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65
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G
MA

105

0.
-------
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME

RTI/EPA
-ACD-M23- y
PLANT LOCATION - CITY/STATE
TEST DATE
Chalmette, LA

SAMPLING LOCATION
RUN START/STOP TIME
Air Curtain Destructor

POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
DRY GAS
METER READING
(cubic feet)
prroT
READING
(in. H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP.
(F)
FLUB
GAS
TEMP
Idea. F)
DRY GAS
METER
TEMP. (deg. F
IN OUT
FILTER
OVEN
TEMP.
(de«. F)
IMP.
EXIT
TEMP,
(dejt F)
SAMPLE
TRAIN
VACUUM
AUX.
TEMP.

120
5& 7,
0 ,V3
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/96
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125
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ARCADIS U.S., Inc.

Total
Run Time
Total Volume Metered
Avg. SQRT
Delta P
Avg, Delia H

Avg Rue
Go* Temp
Avg. Dry Gas
Paee ^"of 2—


M. <&3
CM (p
L 33

<£tt~ /

#?r
-------
3-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K FACTOR SFTUPDATA
RTI/EPA ^
-ACD-M23- (
Stack Temp.


PLANT LOCATION - CITY/STATE
TESJ DATE



Chalmette, LA
cnyos
Meter Terr^>.


SAMPLING LOCATION
t		r	*	
RUN START/STOP TIME
% H20


Air Curtain Destruct
or


/SJ3 - /Y32
Sample Rate
0.75

OPERATORS
BAROM.
PRESSURE
(in. Hr)
STATIC
PRESSURE
(in. H20)
P!TOT
TUBE
Cp

METER BOX
K FACTOR ®


N02
Jl£
NUMBER
DELTA
H#
CAL. FAC.
GAMMA (Y)
IntermediiW Leak Checks

NUMBER
INSIDE DIA.




~\o,f
044?
ty
03}2-

l-¥(



FILT
ER(s)
PITOT
NUMBER
FLUE GAS
THERM.
NUMBER
1MPINGER
THERM.
NUMBER
PITOT
LEAK
CHECKS
SAMPLE TRAIN LEAK CHECK


NUMBER
TARE
INITIAL
FINAL




in. Hg
cfm
in. Hg
cfm








15

Zc?



POINT
NUMBER
ELAPSED
TEST
TIME
(mia.)
DRY OAS
METER READING
(cubic feet)
PITOT
READING
(in. H20)
DELTA H
ORIFICE
, g.H20)
PROBE
TEMP.
(
#7

^53

/6


35
u (,*.<)
0,2X
2.01
/f 7


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D.53

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0,7a .8-
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60
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S?TF
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—/ -¦/	
/3


105

QM<
R.- Gas
Meter Temp.



ARCADIS U.S., Inc.
Page ^ of ^
-------
3-B
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
RTI/EPA
-ACD-M23- /
plant LOCATION - CRY/STATE
TEST DATE
Chalmette, LA

SAMPLING LOCATION
i—f.—fee/	
RUN START/STOP TIME
Air Curtain Destructor

POINT
NUMBER
ELAPSED
TEST
TIME
tmin.)
DRY GAS
METER READING
(cubic feet)
prror
READING
(in. H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP,
(de*. F)
FLUE
GAS
TEMP.
(des-F)
DRY GAS
METER
TEMP. (tieg. P
IN OUT
FILTER
OVEN
TEMP,
(deft F)
IMP.
Exrr
TEMP.
SAMPLE
TRAIN
VACUUM
AUX.
TEMP.

120
~7 35 , /

a.ay

.2.8 O
/AS
CjC
6 3. 55*
6"7
/V


125
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130
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331
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-------
4-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER

RTI/EPA
/; '^T"\CD-M23- 2-
Slack Temp.


PLANT LOCATION - CITY/STATE
TEST DATF



Chalmette, LA
fr/ll/oX



SAMPLING LOCATION
/	V y
RUN START/STOP TIME
t H20


Air Curtain Destm
ctor


tR&Q'/IZ

0.75



barom.
STATIC
pitot


METER BOX
K FACTOR -


OP!
FI
NUMBER
5RATORS
LTER(s)
TARE
PRESSURE
i in. Hg}
PITOT
PRESSURE
on. H20)
-te.r
FLUE GAS
THERM.
TUBE
	 ('P 	
—m.
IMPINGER
THERM.
N
NUMBER
PITOT
LEAK
OZZLE
INSIDE DM
O-Z^l.
1?
NUMBER
SAMPLE TR^
4ITIAL
DELTA
H#
^ /.ft
ViN LEAK CHEC
CAL FAC.
GAMMA (Y
0s???
K
l;«ermcdi*ie Le*k Check*
Fyriiei
POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
NUMBER
DRY
METERR
(cubic
NUMBER
OAS
EADING
feet)
NUMBER
PITOT
READING
(in. H20)
CHECK
DELTA H
ORIFICE
(in. H20)
in. Ha
15
PROBE
TEMP.
(derF)
cfm
0.&+
FLUE
GAS
TEMP.
ideitF)
. in- hR
1 Q,9& oc
'S
DRY GAS
METER
TEMP, (ikf. F
IN OUT
cfm
) 1 &.O00-
FILTER
OVEN
) TEMP,
(dec. F)
IMP.
EXIT
TEMP.
SAMPLE
TRAIN
VACUUM
AUX. I
TEMP. I
«i««.n I

0
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, Ht
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5" ^

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90
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ARCADIS U S
, Inc.

I'.nal
Run Time
E'tfiil Volume McJcrcti
\vg SQRT
-J3eiiaP	 -


Avgpluc A
vg. Dr>' Gas














Page ^
of ^
-------
4-B
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME

RTI/EPA ^
Zf-ACD-M23-2L
PLWT LOCATION CFTY/STATH

Chal metre. LA
MZtfoiT
SAMPLING LOCATK5N

Air Curtain Destructor
/T3& -/¦?&&
POINT
NUMBER
fcLAPSED
TEST
TIME
imin.l
DRY GAS
METER READING
'cubic fwt)
PITOT
READING
tin- H20)
DELTAH
ORIFICE
(in. H20)
PROBE
TEMP.
(J**. F)
HLUE
GAS
TEMP.
^Y/
w

* O
/£>
— - —	1

140


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145


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94

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51
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92

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^.30
r2YA
^ 15
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220
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cQ e>uH

Avg Flue
Avg. Dry Gas

7A(-0
4? 3. (/op (
9.V

'

»7d

-------
5-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K FACTOR SFTTPHATA
RTI/EPA
C'^-ACD-M23- 1
Stack Temp.


PLANT LOCATION - CITY/STATE
TEST DATE



Chalmette, LA
b!2bTo#
Meter Temp.


SAMPLING LOCATION
f t 	
RUN START/STOP TIME
% H20


Air Curtain Destruct
or



0^0 }
Sample Rate
0.75

OPERATORS
BAROM.
PRESSURE
(id. HjO
STATIC
PRESSURE
(in. H20)
PITOT
TUBE
Cp

METER BOX
K FACTOR =


N07
ziT-
NUMBER
DELTA
HQ
CAL. FAC.
GAMMA 
PROBE
TEMP.
3!
).*1


//0
ft


.5


10
70,7
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fic
93
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no
%
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3,31
A3?
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(1

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5A
	f	
1

F-------
5-B
ISOKLNETIC SAMPLING FIELD DATA
PLANT NAME

RTI/EPA
£>v2£-ACD-M23- /
PLANT LOCATION - CITY/STATE

Chalmette, LA

SAMPLING LOCATION
—/		
Air Curtain Destructor

POINT
NUMBER
ELAPSED
TEST
TIME
(min.(
DRY GAS
METER READING
(cubic feet)
PETOT
READING
(in- H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP.
(deR. F)
FLUE
GAS
TEMP.
Idea. F)
DRY OAS
METER
TEMP. (deg. F
IN OUT
FILTER
OVEN
TEMP,
(dea. F)
IMP.
Exrr
TEMP.
S.AMPLE
TRAIN
VACUUM
AUX.
TEMP.

120
131.3
« H5
<7. < 5 (f

!8T?
lit
tc>A.

_5"A
?


125
/3S.5
,Sf
s%
"7


170
!(,<*,0

un
A3S-
A07
in
/ft

S7
7


175
/7A.3
• X7

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cue,
tn
m%

sr
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180
/ 7-5,3
,Z7
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£«e
id
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-7


185
rib. 74k











190












195












200












205












210












215












220












225












230












235












240/off













































































ARCAI
DIS U.S., Inc.

Total
Run Time
Total Volume Metered
Avg. SQRT
Delta P
Av«, Delta H

Avg Rue
Avg. Dry Gas
z 2_
Paee of

/
-------
6-A
PLANT NAME
RUN NUMBER

RTI/EPA
r^-ACD-M23-Z
Stack Temp.


PLANT LOCATION - CITY/STATE
TEST DATE



Chalmette, LA
b/zBM
2
§ ;


SAMPLING LOCATION
/ /
RUN START/STOP TIME
% H20


Air Curtain Destruct
or


/C (5-/fbf
Sample Raic
0.75

OPERATORS
BAROM.
PRESSURE
(in. Ha)
STATIC
PRESSURE
{in. H20)
PITOT
TUBE
Cp


	/	:	
METER BOX
K FACTOR =»


NOi
'7\ F.
NUMBER
DELTA
H®
CAL. FAC.
GAMMA (Y)
Intermediate Leak Checks

NUMBER
INSIDE DIA.




—(0t C
0f7


1° Z2&
/.f/
0.4?*/


FILT
ER(s)
PITOT
NUMBER
FLUE GAS
THERM.
NUMBER
IMPINGER
THERM.
NUMBER
PITOT
LEAK
CHECK
SAMPLE TRAIN LEAK CHFCK


NUMBER
TARE
INITIAL
FINAL




in.Hg
cfm










15

/J-
O, GO* O


POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
DRY OAS
METER READING
(cubic feet)
PITOT
READING
(in. H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP,
(deg. F>
FLUE
GAS
TEMP,
(dcg. F)
DRY GAS
METER
TEMP, (deg, F)
IN OUT
FILTER
OVEN
TEMP.
IMP,
EXIT
TEMP,
SAMPLE
TRAIN
VACUUM
AUX.
TEMP.

0
m, 7 eg
oyk
m
Zkf
/At
fte

6r



5
in.i

1.H-?
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10
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25
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6


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40
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sy
aic,
%
7


45
A/9.7
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m
%-$

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J"


50
£3 5,0
OS?
3.7?
<2.55
fltf

CO
^7

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-it.
//


115
A1H.I
* Co

2.53
llo
V
r?
P.S7
5°l
_±4	

T.xaJ
Run Time
Total Volume Metered
Avg, SQRT
Delia P





ARCADIS U.S., Inc.
Avg Flue
Gas Tcrrq>
Avg. Dry Gas
Meter Temp,



-------
6-B
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
RTI/EPA
^i^ACD-M23- 2-
PLANT LOCATION - CITY/STATE
TEST DATE
Chalmette, LA

SAMPLING LOCATION
	f-	^	
RUN START/STOP TIME
Air Curtain Destructor
/£ /r- /f(/r
POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
DRY GAS
METER READING
{cubic feet)
pitot
READING
(in. H20)
DELTAH
ORIFICE
(in. H20)
PROBE
TEMP.


120

0 r(p
3.9d

/
J 3?
(!jpO
/Q


130
3/6 . 6
SJs>
3,7y
p25J
I5X

r>
JL^S-

IX


135
2>/6.l
0 •(/
3 <75
,25 V
/a


337
6<3
1?


140
33.0.-3
0.6
3,6-^
<^5?
/*?

m
237
(p!
(1


145
33S. Co
5e Cp
3,63

/ 73
V

sczr
(c (
n


150
336 . !?
0.6
3A0
^?55

V

Z.3J
(o oL
13


155
3 3G,i.
Q'lX
3/7 

HM*
0IS7
/1/
/M
ft
asr
V?
/6


200
3^3,1
0,(A


/<£>&
/<\X
w

cn
16


205
3
<9*6-3

^ 52
/£/
m


99
/o


210












215












220












225












230












235












240/off












































































Total
Run Time
Total Volume Metered
Avg. SQRT
I»ta P
\vr. Delta H
Z-/C
2/f. 2s/(,


Avg Flue
Gas Temp
Avg. Dry Ga*
Meter Temp.
/Vio

-------
1
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K FACTOR SETUP DATA
RTi/EPA
ACD-M29- t
Stack Temp.
Z7T

PLANT LOCATION • CITY/STATE
TEST DATE
Ayr. Del. P
G "i3

Chalmette, LA
muog
Meter Temp.


SAMPLING LOCATION
' ft
RUN START/STOP TIME
% H20


Air Curtain Destructor
iosrlaik
S*mpie Rjue
0.75

OPERATORS
BAROM-
PRESSURE
(in- Ha)
STATIC
PRESSURE
(in. H20)
PITOT
TUBE
Cp
o.T^H
NOZZLE
METER BOX
K FACTOR a
*
¦J

NUMBER
DELTA
CAL. FAC.
GAMMA 
PROBE
TEMP,
(de*.F>
FLUE
GAS
TEMP.
(derF)
DRY GAS
METER
TEMP, (deg. F)
IN OUT
FILTER
OVEN
TEMP.
(dea-F)
IMP.
EXIT
TEMP,
(dei. F)
SAMPLE
TRAIN
VACUUM
(in. Ha>
AUX,
TEMP.
(des.P)

0
r
0. V3
(-U-

27v
<**
Cf7

^
! 7-7—

mr

*?4


3


35
310-30

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?7

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3-2


40
273. crV

i Z~l~
7^7
Qiy
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77
¦3 VI
5" J
7


45
D-7&. lo
c
I. 2Z.
3/7
27T
11
9<
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50
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3 ^


55

c> ^3
1 22,



12.


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60

O H~\
/ 22.
7\ctc?
P7 5"


2MI




65
^LSSS) °) 2
Q- 13
/. T~L

P7V
1?
ffl


C"


70
212 • °t£
a HI
I 27.
2rc
27V

<10
D.17
—4	1	
sy
0-7


75
2°ti . G%
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D-<=)S?

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~ "^-7
ST
—-?	4	


80
. Di
a ¦ WX
/.IX
7
-------
2
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K. FACTOR SETUP DATA
RTl/EPA
£?V^CD-M29- 2
Stack Temp.
i7j-

PLANT LOCATION - CITY/STATE
TEST DATE
Avg. Del. P
o.i 3

Chalmette, LA
G/7^/o3
Meter Temp.
9r-

SAMPLING LOCATION
' V
RUN START/STOP TIME
% H20
2_

Air Curtain Destructor
rfic //7/fe
Sample Rite
0.75

OPERATORS
BAROM.
PRESSURE
(in. Hg)
STATIC
PRESSURE
(in. H20)
PITOT
TUBE
Cp
NOZZLE
METER BOX
KFACTOR=
^ -el

NUMBER
DELTA
CAL. FAC.
GAMMA (Y)
Intermediate Leak Checks
Fyrite*
NUMBER
INSIDE DIA.



JO-Ob
-/W
0.84
0-&&7-
0-ZS1

l.bi



FlLTER(s)
PITOT
NUMBER
FLUE GAS
THERM.
NUMBER
1MPINGER
THERM.
NUMBER
PITOT
LEAK
CHECK
SAMPLE TRAIN LEAK CHECK


NUMBER
TARE
INITIAL "
FINAL




m. H*
efm
in. H*
cfra







S
15

r~
° ¦ o


POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
DRY OAS
METER READING
(cabk fert)
PITOT
READING
(in. H20)
DELTAH
ORIFICE
(in. H20>
PROBE
TEMP.
(de*.F)
FLUE
GAS
TEMP,
(dea. F)
DRY GAS
METER
TEMP. (deg. F)
IN OUT
FILTER
OVEN
TEMP.
(detF)
IMP.
EXIT
TEMP.
SAMPLE
TRAIN
VACUUM
(in. Hg)
AUX.
TEMP.
(lieK. F)

0
32*. 2-
(J-1/?
t.2, ?




ZAk
(de^.F)
1


5


7.^5
Z^o
Z7T

cf 7
ZGH

I


10
131^7

'-2-Z-
Zone?
Wt
 1
-------
10
ISOKINETIC SAMPLING FIELD DATA
plant name
RUN NUMBER
K. FACTOR SETUP DATA
RTI/EPA
ACD-M29- /
Stack Temp.
PLANT LOCATION • CITY/STATT

rEST DATE
Avg. Del. P
Chalmette, LA

Meter Temp
SAMPLING LOCATION
RUN START/STOP TIME
% H20
Air Curtain Destructor

K FACTOR
BAROM.
STATIC
PTTOT
METER BOX
TUBE
DELTA
CAL. FAC
iraerroedntc Lc*k Chccki
OPERATORS
Lin- H20)
NUMBER INSIDE DIA
NUMBER
GAMMA
ai^r	f.&j o
FILTER^)
FLUE GAS
THERM.
NUMBER
IMPINGER
THERM.
PTTOT
SAMPLE TRAIN LEAK CHECK
NUMBER
[ARE
P1TOT
NUMBER
INITIAL
FINAL
NUMBER
CHECK
0. eo &o
FLUB
DRY GAS
METER
"TEMP. (deg. F)
W OUT
FILTER
OVEN
TEMP.
SAMPLE
TRAIN
DRY OAS
METER READING
(cubfcfect}
DELTA H
PROBE
TEMP.
POINT
NUMBER
READING
ORIFICE
TEMP.
TEMP.
VACUUM
(BL Hg)
(M.H2Q)
(ta. H2Q)
V^rvV^/
&.L?-
7
fC>
W.Sl-
<9. 22-
f?
ifo \qz

f?

Wr. it-
oat-
if


tfe?KST
V6^. fi
M.?9
7?
l?0 Iff
91
W. 11
W
Vo


ARCADIS U.S., Inc.
( f
Page ot'	
-------
4
ISOKINETIC SAMPLING FIELD DATA
PLANT SAME
RLN NLMBER
K 1- VI TOR StTL'P DATA
RT1.EPA
£-#"aCD M29- £-
Stack T<*mp.
I7r

PI WTUM'xriOS < 'I T'YrS r TT
IF ST DALE
Avg CV} P
D.1f

Chulmette, LA
apjoj
Meier TVmp
n H20)
PITOT
rt be
CP
NOZZLE
METER BOX
K FACTOR ®


M MBER
DELTA
CAL. FAC.
GAMMA (Y)
Initfrmednie Le*k Chectu
Fvriie*
NUMBER
INSIDE DIA.




-Mr
0.84

0.1*1
07
SAMPLE
TRAIN
VACUUM
(in. Hi)
AUX.
TEMP,


0
IU
•.If
Zf
l/iz^

2-


20
*>24*. 3 I

1.3



81


2—


25
<3o. v
O.Hi
^'31



s£
2HI
47
^•7


30
s-^y.U

2-31
231
HI
11
n

c?



35
SVo-71

p..

ax
fj
rs
Hf
C7



40

C7.V1
P.2.?

H7-
n

333
CV



45


2. zi1
jP-
1^3
Sf
S"\

C/



50
 V->
P116

1*1

So
o?s-

?• y


70
'7
o-H-j
O.Z7

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?Z
11

c 1
3 > b


75



105
C *3 . 1 q

2-V>l
^7
in
ry
77
23r
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^•y


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fH'
77
27 /
67
H-c


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Ci"X . 17
o-Hllz.zilZla
ifi

It
OC(
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5- 0


120/oir
in. 
Run Time
Toul Vulume Mfirred
(Vila P
UK. Olu H

1 la* fi-mp
Mctrr


l*


-------
6
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K. FACTOR SETUP DATA
RT1/EPA
-ACD-M29-.J
Stack Temp.
off-

PLANT LOCATION - CITY/STATE
TEST DATE
Av*. Dei. P
al/

Chalmette, LA
MbF>*
Meter Temp.
fC

SAMPLING LOCATION
/ '
RUN START/STOP TIME
% H20
Z_

Air Curtain Destructor

Sample Rale
0.75

OPERATORS
BAROM.
PRESSURE
_ H«)
STATIC
PRESSURE
fin. H20)
PITOT
TUBE
... CP
NOZZLE
METER BOX
KFACTOR =
V, V4

NUMBER
DELTA
H«
CAL. FAC.
GAMMA (Y)
Intermediate Leak Checki
Fvrite*
NUMBER
INSIDE DIA.


no,.it, u.
io.ct,
~\*.r
0.84

O.ZXH
oioii
f •fel
OMt


F7LT
ER(s)
prroT
NUMBER
FLUE GAS
THERM.
NUMBER
IMPINGER
THERM.
NUMBER
PITOT
LEAK
CHECK/
SAMPLE TRAIN LEAK CHECK


NUMBER
TARE
INITIAL '
FINAL




in. Hg
cfm
in. He
cfm








15

7
O.OOr?


POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
DRY OAS
METER READING
(cubic feet)
PITOT
READING
(in. H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP,
(deg. F)
FLUE
GAS
TEMP,
(deff. F)
DRY GAS
METER
TEMP. (deg. F)
IN OUT
FILTER
OVEN
TEMP.
(de#.F)
IMP.
EXIT
TEMP.
SAMPLE
TRAIN
VACUUM
AUX,
TEMP.

0
(all* W
o-y)
W
237
)f4>

'86
zz
0-HQ


/7r
77
To
pjy
		


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m
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105
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2r£
S7
H-x


110
7/3 .a
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/•



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7f-$ ^


Page _
-------
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER

RTI/EPA
-ACD-M29- "Z-
Slack Temp.
/Jo

PLANT LOCATION - CITY/STATE
TEST DATE

0. if

Chalmette, LA


Oy

SAMPLING LOCATION
RUN START/STOP TIME
% H20
z.

Air Curtain Destruct
or


(bn

0.75

OPERATORS
BAROM.
PRESSURE
(in- Hg)
STATIC
PRESSURE
(in. H20)
P1TOT
TUBE
Cp

METER BOX
K FACTOR =


N02
T\ p
NUMBER
DELTA
H9
CAL. FAC.
GAMMA (Y)
lofennediate Le*k Checks

NUMBER
INSIDE DIA.





0.84

oin
QW1
At J
O.Q/PZ-


FILT
ER(»)
PITOT
NUMBER
FLUE GAS
THERM.
NUMBER
IMPINGER
THERM.
NUMBER
prror
LEAK
CHECK
SAMPLE TRAIN IJ-AK CWFCK


NUMBER
TARE
INITIAL *
FINAL




in-Hg
cfm










15
0.0
/*
O.&o p


POINT
NUMBER
ELAPSED
TEST
TIME
(min.)
DRY OAS
METER READING
(cubic feet)
PITOT
READING
(fn. H20)
DELTA H
ORIFICE
(in. H201
PROBE
TEMP.
fdcR.n
FLUE
OAS
TEMP.
(de*« F)
DRY GAS
METER
TEMP. (deg. F
IN OUT
FILTER
OVEN
TEMP,
(deg. F)
IMP.
EXIT
TEMP.
(deg. F>
SAMPLE
TRAIN
VACUUM
AUX.
TEMP.

0
12L - S-rf
0.1 if
ZK
zqo
l^O
1C
»7b
212,

2.
	ircg- *•)

5
1Z9.il
O.Vi
Z.h1
zrl>
IZf
9*
fo
Z*i7
T7
J


55
771-1$
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2.7'QZ

331
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J 1	
3"' ^


100
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/p. y
?v


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v	
^  °i I

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p#

%z
Qsri
C^L.



110
S"Z-i. ol
o-.Qo
Z ¦ 11
24/
121
W

a4i

5- S


115
£3 4. oC
a- C*
2^1
9H*
13# '
73
n

£w
£<¦ &


120/off
93*1. 2/7

Total
Run Time
Total Volume Metered
Avg. SQRT
Delia P
Avu. Delta H
/*>
//b.brr


Avg Flue
Gas Temp
Avg, Dry Gas
Meter Temp.
/^•7
9o./

ARCADIS U.S., Inc.
' /
	 Page 	
-------
5-A
ISOKINETIC SAMPLING PIFim rata
PLANT Name
RI N NI'MBER
RTI/EPA
K FACTOR SETUP DATA

Sfck Temp
PLANT LOCATION ¦ CITY/STAtr
TESTDATC
Chalmette, LA
Avg. Dd. P
C?/2?
Mctcf Temp,
SAMPLING LOCATION
RUN START/STOPJIMB
Air Curtain Destructor
% H20
BARCM
static
prrot
METER BOX
KFACTOR
PRESSURE
PRESSURE
TUBE
DELTA
CAL FAC
OPERATORS
tntcrmcaurt Leak ChecJu
hl H20
NUMBER
INSIDE DlA.
a 2-//
NUMBER
2ort>
GAMMA iY
FtLTER(s)
FLUE GAS
IMPINGER
prrcrr
SAMPLE TRAIN t Pa* CHECK
NUMBER
tare
pttot
THERM
THERM.
INITIAL
FINAL
NUMBER
NUMBER
NUMBER

FLUB
DRY OAS
METER
TEMP, (de§. F)
IN OUT
FILTER
OVEN
TEMP
DRY GAS
METER READING
(cubic feet!
SAMPLE
TRAIN
VACUUM
(ift-Hg)
prrcrr
READING
(m. H2Q]
DELTA H
ORIFICE
(in. H201
PROBB
TEM*
ms
POINT
NUMBER
TIME
FEMP.
TEMP
. or'
b°,l- ~7~r
^02.2/
7oYS-l
lot,, e/
Icq.If
I'lf#
&.fa

Hf. (. ?7
n
-712.1?
Sk
7
79^76/
I3-°I ? /tiff Sto^/e^r
/ -1 !2S -"p* J 2/2 4	's	f
C/rfrvosc?
Rim Time I Totaj Volume Metered
Avg. SQRT
Delta P

//2- ( Yt tftr
o.e>r^
o.ir
Avg Flue
Oaj r
Avg. Dry C,*s
Mctct TcraiL-
^?r


ARCADIS U.S., Inc.
Page ^ of ^
-------
2-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER
K FACTOR SFTI IP DATA
RTI/EPA
£'£aCD-PM2.5- 1
Stack Temp.


PLANT LOCATION - CITY/STATE
. TEST DATE
Avg. Del. P
0.12-

Chalmette, LA
tIMot
Meter Temp.


SAMPLING LOCATION
RUN START/S^OP TIME
% H20
Z-

Air Curtain Destructor
Ofyf/fe
Sample Rate


OPERATORS
BAROM.
PRESSURE
(in. Kg)
STATIC
PRESSURE
(in. H20)
PfTOT
TUBE
	 cp
NOZZLE
METER BOX
K FACTOR =


NUMBER
DELTA
H#
CAL. FAC.
GAMMA (Y>
Intermediate Leak Check*
Fyrites
NUMBER
INSIDE DIA.




-K.r
o-tf

O.Z//

I-/I
J


FILT
ER(s)
PfTOT
NUMBER
FLUE GAS
THERM.
NUMBER
IMPINGER
THERM.
NUMBER
pitot
LEAK
CHECK
SAMPLE TRAIN LEAK CHECK


NUMBER
TARE
INITIAL
FINAL




in. Hr
cftn
in. Hr
efra







s
15

<2*
O.


POINT
NUMBER
ELAPSED
TEST
TIME
(mm.)
DRY OAS
METER READING
(cubic feet)
pitot
READING
(in. H20)
DELTA H
ORIFICE
(in. H20)
PROBE
TEMP.
(deft. F)
FLUE
OAS
TEMP.
(dejt.F)
DRY GAS
METER
TEMP, (deg, F)
IN OUT
FILTER
OVEN
TEMP.
(deg.F)
IMP.
exrr
TEMP.
(de«. F)
SAMPLE
TRAIN
VACUUM
AUX.
TEMP,
(dea. F>

0
lirnbt-

6,
1S
ft


(c(?
2



15
777. ft

0.Y
Z9
2

%Z~
*¦¥/
2 99
If*

9z



7



45
7S?.

ay/
2^2
3
0.2-1-

2vr
If*
%



rto
17



75
7 ?t.<*~


2^f?~





C7
ti



80
772 *?f
0.2Z-
0.1/
Z9/Z

ic


/
r6
2-2

1

85
?/fc

o.fy
2 fX
$ &o
c)6
V

f	
Ft

\
i
?tAs ft L
90












95












100












105












110












115











Total
Run Time
Total Volume Metered
Avg. SQRT
Delta P
Avg. Delia H
*?€>
3z.rr
-------
3-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER

RTI/EPA (
7 ^ACD-PM2.5- "Z-
Stack Temp.


PLANT LOCATION - CITY/STATE
TEST DATE
Avg. Dei. P


Chalmette, LA
MW/02
Merer Temp.


SAMPLING LOCATION
	r—r-t	
RUN STAR7/STOP TIME
% H20


Air Curtain Destruct
or

/syjy /c: ??
Sample Rate


OPERATORS
BAROM.
PRESSURE
<,in-
STATIC
PRESSURE
(in. H20)
PITOT
TUBE
Cp

METER BOX
K FACrOR »


NC2
2LE
NUMBER
DELTA
H»
CAL. FAC.
GAMMA (Y)
Iruermcdiile Leak Checks

NUMBER
INSIDE DIA.


&s; no

-lo, r


&Z//
zom
a e?
afff


F1LT
HR(s)
P1TOT
NUMBER
FLUE GAS
THERM.
NUMBER
i MPINGER
THERM.
NUMBER
prroT
LEAK
CHECK
SAMPLE TRAIN LEAK CHECK


NUMBER
TARE
INITIAL
FINAL




in. H*
cfm
in. Hit
cfra








15

2^sr



POINT
NUMBER
ELAPSED
TEST
TIME
(mio.)
DRY GAS
METER READING
(cubic feet)
PITOT
READING
(in. H20)
DELTA H
ORIFICE
PROBE
TEMP.
(de*. F)
FLUE
GAS
TEMP,
(deg. F)
DRY GAS
METER
TEMP. (deg. F
IN OUT
FILTER
OVEN
TEMP.

IMP.
EXIT
TEMP.
(detB
SAMPLE
TRAIN
VACUUM
AUX
TEMP.

0
Tit.ni?
0-W


<2^0 0
SI
92
4/4-
72-

vn-

5
7
-------
4-A
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER

RTI/EPA £
*^-ACD-PM2.5~ 1
Stack Temp.
)7r-

PL-ANT LOCATION - CITY/STATE
TEST DATE
Avr. Dd. P


Chalmette, LA
i>IU>IOS
Meter Temp.
7 r

SAMPLING LOCATION
RUN START/STOP TIME
%H20
2^

Air Curtain Destruct
or


0z.
V


10
07.
'Jr
0-76
2^2
774
ff

f
& o
£


15
ft
0.76

n?

?3

cy
//


35

*>.$/
*-7£
2,15"
m
/<&


J'7
//


40

A 2/
A
2<4Kf
/7r
ft*
9?

r#
/ ?


45
Ml. yr
0. 5/

^3
/7?
f?
is

r?
/?


50
6
0-V
0. )6
2h 3
nr

??

e?



55
ftf.ft
*¦*>!


n>(*
?7
f3


^3


60
%/-











65












70












75












80












85












90












95












100












105












110












115












ARCADIS U.J
L Inc.

Total
Run Time
Total Volume Metered
Avg. SQRT
Delta P
Avg. Deiia H

Avg Flue
o
r/4
o.yn
07 G

Z~77 «
1? «
IV
-------
ISOKINETIC SAMPLING FIELD DATA
PLANT NAME
RUN NUMBER

RTI/EPA
r '^ACD-PM2.5-2-

/F&

PLANT LOCATION - CITY/STATE
TEST DATE



Chalmette, LA

Meter Temp.
	 7 7
f Q

SAMPLING LOCATION
/ /
RUN START/STOP TIME
% H20


Air Curtain Destruct
or


/iH///<£•



OPERATORS
BAROM.
PRESSURE
..
STATIC
PRESSURE
(in. H20)
PITOT
TUBE
Cp


METER BOX
K FACTOR a


N02
-2LE
NUMBER
DELTA
H®
CAL. FAC.
GAMMA (Y)
Irttcrmcd i*le


NUMBER
INSIDE D1A.


f ftO
3t
t
&
/Y


30


/•/2-
23*?
I2s#
n
7f

C? f
/?


35
lot,???


21?-
r<*$
9*
9?


29

Page
/ /
of
-------
Appendix C: Analytical Results
J Acid Gases (Method 26_26A),PDF
] Asbestos Results.pdf
: ]BV Lab Report ll-08.pdf
J Filterable Particulate (Method 5),PDF
] Filterable Particulate_Particle Sizing (Method 5). PDF
| Method 29_Metals.pdf
| PAH Results.pdf
•JPCB_Results.pdf
jPCDD_PCDFResults.pdf
;JPM10_Condiensible Particulate (Method 201A_202J.PDF
~ | ProxUlt.pdf
: | TCLP Lab Final Report.pdf
- -1 VOC_SVOC.pdf
C-1
-------
Client/Plait Name; AB CADIS	Date Itec'd In lab: 07/ ITS**
Analyst: TCS	Dale of Analysis:	
Analysis Method: EPA Method 26/26A	Analyte(s):. HCl HF, IIBr. C12, Br2
Sample Matrix & Oompon«*n«!>
0,1 N H?S0, , 0,1 N NaOH + DI H,Q rm. t;S
Summary of Sample Prep;
Scn.'ipltrs wt:ce final volumed in the lab by TCS prior to analysis by ion
chromatography. NaOH samples were pretreateel prior to analysis with,
ion-ev.chan^e resin to reduce sodium ion interference durlnq 01^
andlypis,
Summary of Instrumentation:
8himari?,u C1)0-6B . PRP -Xlt'O Column 1 Vx-l . Irnm.	40 pi Inj Vol
Eluexii: -imM Fnth«li< Acid pH 3.6	Flow Rate: 2 mis/mi u
Gain C'.2 pS/cm	Temp: 4 0"G
Analytical Detection Limit(s): U.3S4 ppm HCl	0.405 ppm Cl2
0 . b!-0 upin HF	0, 952 ppm Br;;
O.m&Ii ppm HEr
Summary of QA Audit Sample Analysis:
See Analytical Datre wit-hiti ±lot limits.)
Summary nf Sample Spike Analysis:
InchVidu.nl spike r^coveiie>- were [performed iti thfl lab for each ati.ilyl e.
(.-Ve a.iivlxviduai D.ita Sheet ft foi specific .spile recovery result t:.)
Miscellaneous Comments.Regarding Sample Analysis: (Note unusual catch weights, interferences, odd sample
behavior, and steps taken to confirm unusual results. Also note any deviations from standard analyiical
procedures, together with justification and possible affect on rcsuiis. Specify samples m hen applicable)
None,
To ihc be,si of niy knowledge this analytical data has been checked ihoioughiv for completeness and the results
presented arc avx. urate. erroi-frcc,	and hu\e been performed and validated in accordance with i!k
approved method(s).
Lab QA Oft5« .* Stt: nature
Date
-------
Hydrogen Chloride (I tethod 26/2'	lytical Date Stieet
Chent Name:
• p..jc
I Analyst:
ARCADIS
RN007I60
j U B S\ A K C A L) i S\RN0G!6D\i iCL.WBI
TCS
HI
07

Chloride Standard Calibration Curve by Linear Regression








%
CL





Calculated
Deviation
Cone
Standard Areas
Average
%

Std Cone.
from
(ppm)
ini. 1
ini, 2
Area
Diff

(pom)
Actual
1.00
'
268 iO
?!«I0
!
2f>SI0
0 00%
					1
1 00
-0 10%
10 0
265956
20S37S
2(> 7 i 67
0 45%

(S 'Hi
o5%
20.0
>
553486
5-15:' ¦! i
i 3S"-o

20.2
J 07%
30 0
805262
8094SK
807360
0 26°'o

29 <>
-0 3(>'"o
Standard Curve

Slope:
27> 05
Y-lnt.
-153
LoD (ppm):
0,3

Field Samples in:
0.1 N H2SG4










SAMPLE
KCI
SAMPLE
Irr '
Inj 2
AVER At ] \m
s
<10000
<10000
	 " 1
<10000
0.00%
i
1
I
260
<0.100
I-ACD-M5/26A-1) 1
73%25
7-11 AS')
740657
0,14%
2
315
17.8
J-ACD-M5/26A-02
bST'i
661«7
66097
0.15%
2
330
1.66
n-ACD-M5/26A-01
117093
116335
I ifi?) 4
0 32%
32
300
42.7
II- ACD-M5/26 A-02
1^261
1 ?'6>S2
1979)3
ti hS°.<.
32
345
83.2
I1-ACD-M5/26A-03
?52.»56
755y5o
754306
0.22%
32
330
349
AUDIT REPORT










Average
%
Expected
Calculated
Percent

lni, 1

Area
Dev.
ppm Ci
ppm C!
Dirt
IN-HOUSE r
405992
405321
r
657
_T
0.08%
15.0
1
15.0
n n't.
! mat?8X.spik6 ;
|ni ,
inj. 2
Ayeiagc
Area
%
Dev.
Expected
ppm CI
Calculated
ppm CI
%
Recovery
Sample I.D.
I-ACD-M5/26A-02
r~226037
i 	i'
229910
227074
0,85%
7,50
, |
7.22
963%
Note:
0,5
mis of the above sample was spiked with



0,5
mis of a
15 0
ppm chloride standard


Printing Dstr
23-JUI-2006
Printing Time
08:02 AW
-------
Hydrogen Fluoride (EPA Method 2SA* Analytical Data Sheet
			.,.,.iiJiiiiiii.,..,,,,,.j^...„„.wa^i-...3|	'"'	'l"""^ag^atn^*|17"rr*Mmg"'r~' ""'	*' 	|.	„ mi I..,.-.!-. ... ..in I- 		i-^iiiii.^^a^ i II . I. II.......1I.....I1 Iir -. rnn ""..TIT 11	in,,., ^.^..i.^iiiriinm-am—
( Client Name
1 Fiie Pathway.
Analyst.
ARCADIS, Inc.
C:\JOBS\ARCADIS\RN007160\HF.WB1
ICS
im.
File;
Dale.
RN007160
HF
07/22/2008
'
Fluoride Standard Calibration Curve by Linear iegrw,ion
%
Deviation
from
Actua
F
Cone.
Cppm)
Standard Areas
lni. 1 Inj. 2
Average
Aiea
%
Diff

Calculated
Sid Cone,
(ppm)
0.50
1,00
3.00
5.00
i
ms
7S6S
37 W5
62934
!
2036
7»B
36512
63396
2017
7836
36854
63165
!
0.94%
0.41%
0.93%
0.37%
p
I
0.522
0,946
3.0C>
4.97
4.45%
-5.42%
l.r,4%
-0.53m);
0.


Field Samples in:
0.1 N" H2S04


Sample
ID
inj. 1
Area
Inj. 2
Area
Average
Area
%
Diff.
Dilution
Factor
Sample
Volume
(mis)
HF
Catch
unw)
FIELD BLANK
_T
< 201?
1
<2017
<2017
I
O.oo%
1
1
I
260
< 0,143
I-ACD-M5/26A-0!
5559
6073
5816
4.42%
2
315
0.53ft
1-ACD-M5/26A-02
3591
3852
3742
4.02%
2
330
11.45®
If-ACD-M3/2t» A-01
3 784
¦nm
W5
2.85%
4
<00
0.833
TI-ACD-M5/26A-02

10511
10184
3 I7u/f
4
345
1.62
H-ACD-MS/26A-03
8421
9075
8748
3.74":,
4
380
1,62
***•* AUDIT REPORT —«»






I IN-HOUSE
"U1
_ J"j- 2 _
Average
Area
%
Dev.
Expected
ppmF
Calculated
pp,n F
Percent
DilT
21458
T T
19995
20727
" " 	"i
3.53%
2.00
r
1.88
-5.79%
MATRIX SPIKE'


Avemge
Area
%
Dev.
Expected
ppni P
Calculated
ppm F

Sample l.D.
lni. 1
Inj. 2
%
Recovery
I-ACD-M5/26A-02
Note:
16791
0.5
0.5
i 		r—	r
J 7507 17153 2.07% 3.25
tnls of the above sample was spiked with
r m fluoride standard.
i
1.30
104.0%
Printing Date
23-Jui-?008
Printing Tmw
08:04 AM
-------
Hydrogen Bron '	tefiod 26/26A) Analytical Data Sheet
ileal Name
II File Pathway:
| Analyst
ARCADIS Inc.
c \JOBS\Ai-:cAu.^h?Miti<; ibk wb i
ICS
Job Num. RN007160
Date	07 L ft

Bromide Stanesaid Califeiation Curve by Linear Regression
OA
Br-





Calculated
Deviation
Cone
Standard Areas
Average
%

Sid Gone
from
(ppm)
Ini 1
Ini 2
Area
Dirf

(ppm)
Actual
} 00
I
10993
! 	
1(^98
10846
I
1.36%
t r
r
1.02
2.50%
5 00
57296
57514
57405
o i"r»

4.96
-O.StW
lU 0
11*701
i19078
117391
1.44%

iQ.O
0.19%
15 0

176835
176397
u 25%

15 0
0.0
Standarc

Slope:
11846
Y-iut.
-1296
LoD
OS


Field Samples in:
0.1 N H2S04








SAMPLE
HBr
SAMPLE
|,„ H
In; 2
AVERAGE
%
DILUTION
\ OI UME
CATCH
CD
AREA
AREA
AREA
Diff,
FACTOR
(ml)
(niK)
FIELD BLANK
f———
< 10000
1	
<10000
<10000
!
0.00%
r " ¦ r
i
' ' 1
260
< 0.251
I-ACD-M5/26A-01
<10000
A
O
<10000
0.00%
2
31S
<0.617
I-ACD-M5/26A-02
<10000
<10000
<10000
0.00%
2
330
< 9.647
E-ACD-M5/26A-01
<10000
<10000
< 3 0000
0.00%
4
300
<1,18
H-ACD-MS/2'iA-02
<10000
<]0000
< 10000
0 00%
4
345
< 1.35
H-ACD-MS/26A-03
< moot)
<10000
<10000
0 00%
4
380
< 1.49
AUDIT REPORT







j


Average
%
Expected
Calculated
Percent

Inj, 1
In). 2
Area
Dev.
ppm Br-
ppm Br-
Diff.
1 IN-HOUSE AUDIT
929315
i i
92537
92738
T ~
0.22W
	f
8.00
7,94
-0,77%



Average
%
Expected
Calculated
%
Sample I.D.
Ini. 1
inj. 2
Awa
Dev.
ppm Br-
ppm Br~
Recoverv
H-ACD-M5/2f*A-03
•'} t08^
405(14
40797
t
0.72%
1
3.75
3.55
94 8%
Note:
0 50
ml of the above sample was spiked with



O 50
ml of 3
7.5
ppm standard.


Printing Dato

23-Jul-2008

Printing Time
oe (fe \M

-------
Chlorine (EPA Method 26/26A) Analytical Data Sheet
Client Name:
File Pathway;
(j Analyst:
ARCADIS. Inc.
C:UOBS\ARCAD(S\RN007!
ICS
50\CL2.WB1
jm. RN©071ii
CL2
07/22/2008

Chloride Standard Calibration Curve by Linear Regression

Cl-





Calculated
yo
Deviate!!
Conc.
Standard Areas
Avctage
%

Std Corse.
fium
(ppm)
Inj, 1
Inj. 2
Area
Diff.

(Ppm)
Actual
0 50u
i
1 1S84
I 	
1241;
r_
121 of>
f
2J 1%

-		 	r
0.485
2.%%
10.0
265956
26b" 3 78
26? J t">7
0-15%

9.91
~;i,87%
20.0
53 S3 96
553-486
545941
1.38%

20.2
] W\,
30.0
S05262
80945?!
807360
0.26%

24' 9
-0 iv%
Standard Curve

Slope:
27049
Y-Ini:
-<>50
LoD (ppm):
0.405


Field Samples in:
0.1 NNaOll



Inj. 1




Sample
€12
Sample
Inj. 2
Average
%
Dilution
Volume
Catch
ID
Area
Area
Area
Diff.
	
Factor
tnili
f'Ug)
FIELD BLANK
T
20664
j———
20871
20768
0.50%
1
1
			 I
270
0.217
1-ACD-M5/26A-01
61600
57352
59176
3 57%
1
255
0.570
i-AC D-M SIX >A-02
*
-
44111
44435
u 73%
1
315
0.529
II-ACD-M5/26A-0)
101126
10646<1
104795
I 50%
1
245
0.958
TI-ACD-M5/26A-02
i 20151
l!83fW
(I <>260
0.75%
1
300
1.33
1I-ACD-M5/26A-0?
141660
143802
14273!
0 T-%
1
310
1.65
AUDIT REPORT
Inj. 1
ins. 2
Average
Area
%
Dev.
Expected
ppm Cl-
Calculated
ppm Cl-
Percent
Diff.
IN-HOUSE
405992
i
405321
405057
"l T
0 0S%
	-T
15.0
15.0
0.22% 1
MATRIX SPtKS >


Average
Area

fixpcotal
ppm Ci
Calculated
ppm Cr-
%
Recovery
Sample I.D.
Inj. 1
fni. 2
" V
Dev.
U-ACD-M5/26A-03
Note:
II4S42,
0.5
U 5
i i ] i r
114133 1)4488 0,3 i% 3 75
rnl of the above sample was spiked with
mi of a 30 ppm diloiide standard.
r~
3 61
96.2%
Printing Date

23-Jul-2QC8

Printing Time

03:19 AM

-------
Bromine (I lethod 26/26A) Analytical Data Sheet
ARCADSS, inc.
G. U G 3 3\AR CADI S\RN007160\B R 2. WB1
1
jm.
File:
Date:
RN007160
BR2
07/23/2006
1
liromide Standard Calibration Curve by Linear Regression

Br




Calculated
/o
Deviation
Cone
Standard Areas
Average
%
Sid Cone
trom
(PPm)
Inj, 1
Inj 2
Atea
Diff.
tppm)
Actual
1.00
i
i 0993

10846
1 ' I
136%
i
1.02
2.m)%
5.00
5*?196
ST-q.i
57.-; 0*
0 1?%
4 397
0 25'?:.
{%,()
0.00%
Standard Curve

Slope*
11846
Y-Itrt. -12Qe
LoD (ppm):
54

Field Samples in:
0.1 NNaOir








SAMPLE
Bt-2
SAMPLE
Inj. J
Inj. 2
AVERAGF
% DILUTION
VOLUME
Catch
ID
AREA
AREA
AREA
DIFF FACTOR
(nils)
Ones}
HF1D BLANK
1 I
<10000
<10000
<10000
l 	r
0.00% 1
			 r
270
< 0,257
1-ACD-M5/26A-01
- 10000
<10000
< J 0000
0.00% 1
255
<0.243
1-ACD-M5/26A-02	- fOOOO
H-ACD-MS/26A-01	- !00(H)
II AOD-M5/?dA-02	< i 000(1
li-ACl VM5/26A-03	"• H1«00
<10000
10(100
v lOtHK)
< 1000(1
<	10000
<	K'MjOO
<10000
<	ioooo
0.00%
0 00%
o oon
0 00%
315
245
300
m
<	O.3O0
<	0.234
<	0.286
<	0.2^6
IT REPO
Inj. 1
Inj. 2
A\erage
Aiea
%
Dev.
Expected
Ppm Br
Calculate,!
ppm Br
Percent
Diff
1 IN-HOUSE
P
92537
92738
1	
0.22%
8.00
7.94
-0.77%
Sample i D
Inj. i
N-2
Average
Area
%
Dev.
Expected
opus Br
Calculated
ppm Br
%
Recovery
Note:
'8644
0,5
0 :s
S0677 ' "/9661 ' i.28% 7.50
mis of the above sample was spiked with
im bromide standard
	°	i
rt.83
91.1%
Printing Data
23-Ju1-2008
Printing Time
07:36 AM
-------
Xnstiriiifisxit« Slixxusicisii CDD"~6A C
Eluent: 4 mM Phthalic Acid pH :
Gain 0.2 piS/oia 40 ill laj Vol
i.Vc	i' c;i'h'"0!n\chi\>tnu*«i» r'
Method ; c:\e2chr&ni\nietf»O£fe\m26-150,rnrt
Sample IP i>.5 J'f Via
/".tDiiired • Jul 21, 15 5?-^2
limit	1 of 1
L
Channel A Results
Peak Name
ehlorid«	2.17	U'?34
P>r om.ule	3.0?	.''>556
c.\e.
i'ehroni\chrom\mOD"l 60 001 -- Channel A
25
Peak Name
r25
M
i
1
1
i
v
0
1
t
s

try
-25
Minutes
10
15
M
i
1
1
i
v
0
1
t
s
-------
' . > »• i mi-'> 11	» "tl/-' '> Limn* luxltcr ®~C '..00 15Q*<4 . lima
i;' ifeni ;	. 'i1 Ii 1 u ?i /i: -i11 141 . 6 I* Iii>* '."tf - • 1 3 au ¦ w. i
'tci2is ! ,	f m 4 ! \ 1 11 i s 'T'-iv;* * s.U
l'ik	i""'Csxi urotuVJa'CiU.unOir.' i tiu uwft
Merhort	^'.czcljivirihrit^ho ;i2o~ I *0S U' r.NJ1
Channel A Results
F-i'v.K huiae	Ret
Fluoride	1.57
Chl'.ici tie	2.25
Brojiicie	3.17
c:\ezelirom\cliroin\m007160,006 - Channel A
M
i
1
1
i
v
0
1
t
s
Peak Name
M
i
1
1
i
v
0
1
t
s
Minutes
-------
"it..- > • "iir-.t : Mai> ,il;n '"l- "A 'Jolmnn: n m . . , IM vJ „ .*> 150x4. lima	1 A
l' '	- i tun i lit ii& l 11. i J rs , 6	T* 1 j )* i • i , r cils/min.
Gain 0,2 iiS/om 40 p,l Inj Vol	Temp 40 C
FiH	.	16if,i!0>*
Mu1
Sairiple ID ;
Acquired : JnPi 20" *8 i 6
1 A
P1
am-
Fluoride
	<.					:
Bromide
1.57
2.28
3.12
766 0
: 6 5 96
57298
c:\e2ciirom\cliromVn0071 nO.OOT - Channel A
M
i
I
1
i
v
0
1
t
s
Peak M am e
M
i
1
1
i
v
0
1
t
s
5	10
Minutes
-------
risae^t: c'n juiHsr'i fT*T)~S« "oluanr M ,ji . x> n c\L y i ci » r.r - lima	Page i ot 1
r\	,	! ,\K -1,1 ii _ 1 f	^ 1 r 11 , . 6	I1 ] . T ri ' ^ , * L ' a= 1 J i „ji
' " 1 0	"I'l ''-f1 J. LV.J \' l'	'tl_lilL> '' 1 .
ic	: k ,n.7Ui'i«n.chui»H\iii{i{i~li5u UOP
'Vletiun)	• c >e£.diK»Ji»\mt*Uii;ii% nro-if'i.Eud
Sfanpk ID . .*-TNl„> i a
Auiujred	i Jul 2} 2oOS »0.4] .25
, A Results
Fluoride
Clilor lie
Bt on'ide
Ret Tiiae
3.12
37195
111*/ Oi
M
i
1
1
i
v
0
1
t
s
c:\ezclffonf ch ronton (XT7160.008 — Channel A
'70
Peak Name
20-
10
4i
Kn.^x.
Minutes
10
-100
-90
-70
-50
15
M
i
1
1
i
v
0
1
t
s
-------
J">- ' "	" v - 1 u CDC	6.A
Iluent;	4 imM Fhthalic Acid pH 3
('•' xi-	i _ 3 vc j
K'Jf	w 4CirIitoTn,ciaorti,'i^:Oo I
Akihwd	«-
Handle 10	; S'iTsJii -1 a
--1qu'-rrd	¦ jo) 21, 2(H>S X7.i2.13
PR'J?-
Page 1 o± 1
Ch
A Results
P 03. 1; Naine
F luor a rlL->
L 1L± U J. j_U.
-------
i.' . . ii	r~i-t ^	ll un Iton PRP-X100 I
-' i- r"; 1 >> I Mr,- „<1	, i'	6	M r, ,i Rate J 1.75 m)
Gain 0.2 ftS/cm 40	|il liij	Vol	Terap 40' C
File	•	O'O
n.iv-thiiu . i*:Vr>itfOT>vS!tvt(u  22. 2008 2*,5"':?C
Channel A Results
P O a K Kfijll'r'
Chloride
Ret Time
2,17
M
i
1
1
i
v
0
1
t
s
c:\ezchrom\chrom\m007160.045 - Channel A
25-r
Peak Name
•I
^s-

5	10
Minutes
-------
~ n. nr uw-t r	r	\ 1 c 1 i»aa*: TJ-m_ i i u i TV*- Zi'	i.c'.lmii	Page 1 ot 1 (1)
F ' u • I 'riM b t'i! 1 > . i l< -"--'I *- H - u	IIi T\_t r - j , " ri , i J z ' ]i .
;c.n< i1. , aJ'cui -k> ]'! In «"o 1	^vt,L|; ii_, r
ri!.-	v*w?i1iioi!i\fri!Ofii RKui^Jo1' 'J t!
Method vA t' -xhivuitviei noti-Mr 16 - i "n s.uei
v'.aripielD SIN!) 1 b
ALUUim! " Jul ??. 20'!g K. 33 5f>
Channel
3* i\ ^nir*	1I 1 i.iTtfc"	„Ax^&
Fluoi:ida	1. 55	03b
Ciller ide	2.23	26010
B r om id-ri	3,10	10 n 'j H
cAe^chroimdiromYRN0071 oO 044 - Channel A
Peak Name
M
i
1
1
i
v
0
1
t
s

-§


r

~
8

p.....


m
1
d
q
11;
tq ^
—
- • Kl
-Ai
6
5	10
Minutes
-------
					Inuxt	BQ.Cffi 1 ot i C *- 3
Eluent:	4 ittM Phthalic Acid pH 3.6 flow Rate; 1,75 mis/mill
"f' 1 . I I? «	11 c" * lT r' * "j J L J i 1 V 1 1 ^" Itljv VH' Z3
i*ik-	. t, w-_ ^roii^ehr.^nxkNuu" 1 (»)a>4^
Meitoft	; c:vr.'tttv>Tt.mcihu Jvir<2>> Ii> md
Saifii.icLD	; SW>2h
Acquired	I Jul 22, 2b'IS h>,59 2>n
A Results
y«cii N "aae	Ret Time	Aiea
Fluoride	1 „ 55	"?f;03
Chloride	2.2?	26C278
Brojiiide	3,07	57 51 1
c:\e7.ch rom\chrom\RJN 00 7] 60.045 - Channel A
M
i
1
1
i
v
0
1
t
s
Peak Name
M
i
1
I
i
v
0
1
t
s
Mu i. lies
-------
Instrumenti Shimadzu CDD-6A C
Eluetrt; 4 iaM Ph.th.alic Acid pH 3
Gain 0,2 p.S/cm 40 p.1 Xnj Vol
riie	inczdianiiViTAvrtiOo "i>kVj 1 <
ilriJiiHi c;1 rtrii'ir>et(	" rniei
JE STN71 $ ^
At uuiretJ • Jul T2, 1 '> 57 01
lum
1 ot I
Channel A Results
sa,Jo Name
F113 or e
ChLcr Isle
Bromide
1.55
2.30
3.07
¦j j_ 2
5534 86
1191 j 7 fi
e:\ezchrom\etemi\m00716Q.041 -- Channel A
1
1
i
V
0
1
t
s
Peak Name
400
-50
M
i
I
1
i
v
0
1
t
s
10
ss
-------
"* 11" t*r ,.iuAf ^ ; Jin Hf.'l" i i ' i P
Eluent: 4 itiM Ph-thallc Acic
Gain 0,2 |iS/cm 40 p.1 Ir
[ STNLV-U.
\(quirt d Jul ?2, 17 09.47
1mm
Page I ot 1
aiel A Res Hits
Pi-a?; Ma;na
Fluoride	1.55	i- ;?y6
ChJoi'jde	2,32
Bromide	3,08
c:\ezchrom\chroiri\rn007160.042 -- Channel A
IGOt
M
i
1
1
i
v
0
1
t
s
Peak Nati
ae
-100
-50
Minutes
10
15
M
i
1
1
i
v
0
1
t
s
-------
Instrument5 Shimadzu CDD-6A C
Eluent: 4 itM Phthalic Acid pH •
Gain 0.2 ]iS/cm. 40 |il Xnj Vol
1'ik	il'rZ(|i.«'l till .nil
hltlhM t, 'c^t!<-T!is\faeSh,»M7<;n 1 n«ct
Sample ID ; /ufliFl a
Acquired : ,tuJ ,11 J>>0S ] 7:24:5"
iel A Results
Peak 1J ain >:
Fluoi; i'le
CLloricle
51 Cuii i cit
Ret Time
1 c c
e:^e.zclirom\ehroii]Hii00'?lo().0{0 - Channel A
M
i
1
1
i
v
0
1
t
s
100-
•100
Peak Name

1 f

-50
:U» 3. j_
Minutes
10
15
M
i
1
1
i
v
0
1
t
s
-------
* j- iin.-iii; ,-t j,i iJ' u r PM-f ^	in* Him-11 t*on PRP-X100 j ' n , 1mm
i n >t" • Jill .1"!,-. i " i-1 j i	p -tr 1,75 si]
'J.u i ¦ i, 2 jj,- 'a	>1 , 1 .i n o	'I i-jm -t 1
1 !tc	. i
Meihcvi . i
hmppk Mi . *' LOT b
AwjtVod . Jul :i.'Kv^ ' ".22.32
Channel A Results
Peak Naiti^	Ret lime
Fluoride	l.bS
Chicrxde	2,28
Bromide	3,07
o:Vzolirom\chrom\m007IoO 043 - Channel A
100-
M
i
1
1
i
v
0
1
t
s
Peak Name
r-Ji-iJ
100
•50
M
i
1
1
i
v
0
1
t
s
5	10
Minutes
15
-------
Instrument: Shimadzu CDD-SA	C
Eluent:	4 aM Phthalic Acid pH I
' 0.	1,1, ' « Hi *1'' 11 i ^ l'i 1 • 1
1 lie	t.-.fiLiiroin'xiauiii'iiiOl,'" \> ui ?
Mdthvs	, c.1 c-'ctuoasauetu^uV"!t,ID	; H2MM XPiKL7 j
Actfia-tti	: .tu: Zi IS
>; 1 l u I ; i limit	Page ± Qt 1
• ,TI J [ij
A Re.?uIts
Pccii-c Hahu.
Flu/'t Ida
<>_ I"'2or iris
B con tide
R-i-t r irfi;
1.52
2. 63
3,17
1 O**" ¦> b
f q /*n Q -j
OO O /O1U
41089
ci\ezc!irom\chrom\ni007160,017 - Channel A
M
i
1
1
i
v
0
1
t
s
500
350-
250
150'
1QG-
Peak Name
I
(V
-500
450
-350
-300
-250
-200
150
-100
-50
15
M
i
1
1
i
v
0
1
t
s

-------
instrument! Shimadau CDD-6A (
Kli. uf, i -i Tih	Mi' .Cii t;H
G^in G * 2 p-S/cm 40 Inj Vol
Fife	. c"c/asmi;\iti.oin'ii-0u">»<.0.0lS
MuKxl . c	'iei
Sampie ID U;SOi S^IKEb
iUcjitireJ Jul 2!. 2ui« 2112-41
im	Page l ot 1
Channel A
Its
Peak Njjtl£
Flu^'j.ide
Ch iC'i iae
B rorai dc
Ret, Time
*i r. n
=«. » J *L*
3.17
c: ¦ ezchi-oin\chrora\rri007160.018 - Channel A
M
i
1
1
i
v
0
1
t
s
500
350-
300
250
150
Peak Nome
O
t.
CQ'
C\~
5	10
Minutes
¦500
450
-350
•300
¦250
¦200
-150
100
-50
15
M
i
1
1
i
v
0
1
t
s
-------
1mm	Pa,3e 1 °± 1 ED
Method
Sample ID
Acquire..!
c:\ezchrcMm\mtthods\M
Q2S04 SFlkc 3
Jul 25, jcr.g 06 ^ J?.
Channel A pecults
P^i) }* }¦! cililt
Ret
2.20
2.98
M
i
1
1
i
v
0
1
i
s
c \ezckromVk"O!D\Rn007160,033 - Channel A,
25
15
Peak Na
Hie
UJ-U'
? «
J—J.
5	10
MmuVb
r25
-10
15
M
i
1
1
i
v
0
1
t
s
-------
												
Eluent: 4 MM Plitlialic Acid.
'-_!_< i L t<„2 iu£ '-iii 1" 1 Tr>_
File	r '.c/s-iti.iiTncluoin.rJtOM
xVirthix! • c:xc/tlt>-;nisV>ieilu\Ls'J,i.2o-
Saiaple ID • t^CHSPKSb
Acquit id " fill 2 \ 2utJR u6'28'15
Page 1 o± 1.
Channel A Results
P-ir.iiL hklaife"
Chloc i'ie
£' r oip idt
2.18
3.00
'.:9D10
18774
c:\ezchrom\chrom\Rji0li7160.034 - Channel A
M
i
1
1
i
v
0
1
t
s
Peak Maine
M
i
1
1
i
v
0
1
t
s
Khmitrt-
-------
lri=."t r,in'	r! i rial n •. >¦ r Luitm:
1 111" .*i t :	. l" 11 i n i c \ • m 1 i-p 5
' a id l .	1." •- i -i 0 ->] J V> I	T:
i*'k	t.uvcliroui\cliti-a*i'.,nO'!' iMi i (16
KlcthO't	csw*iiaviUii'ieil tnpt
Samplefl>	, N <10R STIKF .<
At (jjiireti	>oS ?1. 2008 2?
Channel A Its
EwaK Nam.-	k^f
Bromide	2.93
c:\ezchrom\ehrom\rn007160,106 ~ Channel A
25-
gkName
M
i
1
1
i
v
0
1
t
s
15-
10
1:
Minutes
-------
T^c? f- J-t , ft\	p. J i b . t	. } i - "i - i ) -	r- -
Eluent: 4 10M Phthalic Acid pH 3
Gain 0,2 nS/oiu 40 ]ii Inj Vol
File	; c:\ezchrom\chromVn007KS0.107
ftteiliou	.in-1
irucpltlD • NAOjH SPjKI" b
.-wquir&i : lal "1 ""OS On:06:18
Channel A Results
Ivjal. "I ir,te	Ret Time
CM-ex-iele j/Jfc?	—S^rifr
Bromide '	2.93
c:\ezchromWhrom Vn00?16CU07 ~ Channel A
25-
:,k Nc
ne
Minutes
-------
In- >, h->', : '< I'lH-nj'.u ~.»J. .1 Column; i »„ j. j. i n.- H j- F~ T i, * n 1 J D;< 4 . Jicit	Page I ot I
L i U l I *	, JI.1 F 1 t » < 1 \ i i I V 1 u t h , 6	r ] '">Tj 7 I ; I , , r, * I I - / ill r,
_!_	-U> -ji, U;j V" 1	;'|i C
cue	. czdrMfi\ehrjttrimHj"i6ii> J((i
Ivi^bofl	; c '.tvciiWiNi icihv)p£KLC .*
Wnr«i	: Jai 2S„2>imc>i.58:l4 .
. A Results
Peak Name	Ret Time	Area
Chi oxide	2.18	11'
?:\ezchrom\cjirotii^rnOO?!ot).200 ~ Channel A
v
P^uJk Isi s
-------
Instrument: Sh.in.adzu CDD-6A C
Eluent: 4 ibM Plithalic Acid pH 3
'.ail. 0,1	•'i"> (I J 1 /.<-
[*ik	• c k/cUwncltf j;it R-.00 1*>* .\>1
MefUuci	v.' ,e_u
%-q»;ad • Jul	IS
Page 1 ot 1 (1)
lei A
Its
'eak Maine
CIiIoridG
Bromide
Ret Time
2.18
2,97
Are*
c:\ezehrom\ehroin\ RnOO7 160 201 - Channel A
25
M
i
1
I
i
v
0
1
t
s
15-
Peak Name
0

10
¦25
¦20
15
10
M
i
1
1
i
v
0
1
t
s
Minute
-------
Shxmacizu CD
1 F f [ u.f i •
•ill i
Page 1 ot I
pH
File	'H t
Viahr-d	;	,5 > t er
Sample ID	: FlULB BLANK a
Acquired	: Jul Zs, 2008 « 7\* .''28
leJ A Results
Pa3> N/aie
(	i
Ret Time
2,18
Area
5081
e"\ezohroTn\ch.rom\m(}071oO.Ol 1 -- Channel A
M
i
1
1
i
v
0
1
t
50 r
Peak Name
¦50

25
M
i
1
1
i
v
0
1
t
s
0
5	10
Mmnks
15
-------
n;
i
1 ot 1
(^ b L . j )	) J 1 1 ui	"i	1 C
,',Ir	* t >e uluc«n\tIu"<«iiiMt>U. K>0 i5i'*
Method	: c \e?Li>rjiim:<'rhofl5'\«i2o-iJO i»icf
NaupleLD	:	F'L'lNk D
Acquired	; Jui IL MuS' 23¦ 5J 15
Channe 1 A
Peak Name
Chloride
Ret Time
2.18
Area
e.
\e?c 1 it orri V}irciii\m007160.019 — Channel A.
500!
450
350-
300
Peak Name
200-
l>0-j
500
450
-350
¦300
-250
-200
¦150
10C
-50
M
i
1
1
i
v
0
1
t
s
10
15
-------
Instrtmer

Eluent: •*
atM Phthalic Acid pH 3
Gain 0,2
]iS/cm 40 ill Inj Vol
File :
c.wzcIifiviiVriirnn'ruOO"71 •' i>
futiiioJ :
x'ichioirjV.netlioriMU!^'.-! tad
Sample IP .
FIELD BLANK fJAOTt a
/cqa'i©.!
Jul 21/100^ hOo.ui
Channel
A RO-'Ult 3
I
JN ci iTl-------
Instrument: Shimadzu CDD-6A	iuiiin;	: 'rot PF.r i-.0 1 .1 • ,, l ia i	Pa3'e 1 °£ 1 O)
3 i „. i ¦ . ; 4 wJi ,"tiri 11 i ; ;,uiJ ; E< >.S	i''ln" «-, > i-* j. 1.
'.n.ij, i..' • riii	jjj. it ) v\' !	Tcjyp 4.,' €
Fik	. c ' '.zrfroii!1 ch! oimVR*h>,v I 09.103
mdbod c U ,3chroiii^nci!uxd^?\f2o ! ~-o ;s
-------
Instrument: Shimadzu CDD-6A (
Eluenti 4 &M Phtlialic Acid pH :
Gain 0,2 pS/cm 40 ]il Inj Vol
>* wvUuotrnCtti.iiti niOo' itHVM 2
h irfSiot . -"	met'vd j«'C;>-1 *0 ,»e,
Sauipk* in i-i u :mj4 a
Acquired ' Jul ?1, ll:;28:li
Channel A Results
Ei&k	Ret Time	Area
E	!	1,50
Chlot icte	2.28
c:\ezchrom\d]ro!Pltii007ldQ 012 — Channel A
M
i
1
1
i
v
0
1
t
s
Pdcik Na
M
l
1
1
l
v
0
1
t
s
Minutes
-------
i" i -i,t . : Ij,j in ia- 11 Onjt-'	¦" ">1 uu : Kdw ] t.nn	'"r " 1mm	Page 1 ot 1
i'l i"ht 1 S \uM 1 \t h-i I tViC ] • i	F'o.* r..r€* i "r i,i i - Mir.
'..a: a O.J |ii fh " u L -.J. 1 / >1	To tup. -t 0
!•" it	L-,^a^om\di! jni'\itJjo lw <>j3
viefhc.l . Ci'eh.\ii'iiursetliccti''jii\ 1 ?0 mrl
Santyle IT . T-2 H2S0 I ;i
kquiicfi : Jii! 21, 2ui'b'jij
Cbc^'Hcl A Results
1 }¦ i'C^tie	Ret Tin'ta
F Luoria:	1.4 8
Chi or itics	2.ZQ
):\ezchrom\chrom\mOO'7160.013 -- Channel A
50-
t50
Peak Maine
25
•25
M
i
1
1
i
v
0
1
t
s
0
5	10
Minnies
15
-------
Instrument: Shiiaadzu CDD-6A C
Eluent i *4 rail Phthalic Acid pH 3
Gain 0,2 p»S/cm 40 pi Inj Vol
:¦ ill	• * • \e/ckv*inc lira»r> ,nit¥» 1: mi .0. <1
i\!c:!;f4 c/fztltn'I.s>i a
1mm
1 ot 1
j11 ? I. A lU-rults
P^-ur N jrut	Ret Time
Fluorid*	1.4 P	3784
Chi or id'?	933858
c:\ozchroTn\cbjotn\m007160JI4 - Channel A
Peak Na::
1
0
5	ib
M inures
15
-------
Instruments Shimadzu CDD-6A Column; Hamilton PRP-X1CQ 150x4,1mm
"In .;j . : i'iM It"1	j V i 1. '• l	F 1l <	=. J , i "¦ in.1 5 i . i.
¦ !•) Li' u. - |t? ' ciu 40 i .t j ~ r i	Ttu_ 10
Fik-	i *<*/-tItr.-nt\cl>) ui!s<>i'7i! 0; 3
t\ it,hod • c -,.e/c! .roi! >\rarv'i to-sjti » 6-1 Muna"
i> apple iO ' U-2. H.1:»u4 a
Acquired . JuI2L20y{f2l-il.l#
Channel A Penults
Peak Nome	Ret Time
Fluoride	1,48	9666
Chlcciao	2,38	I i>On 103
c'\ezchi'ori)\chrom\m007i60.015 -- Channel A
5Qt
Peak N<
25-
ne
-50
ii Uj->
•25
M
i
1
I
i
v
0
1
t
s
0
5	ib
JVUjnii.es
15
-------
Instrument: Shiatadzu CDD-6A	C
Eluent; 4 mH Phthalic Acid	pH 3
Gain 0,2 jiS/cm 40 |il Inj	Vol
i'iic . i..vc»rd>i"D!a'U¦£"<^ iiVnOi' 7, o!u)} i >
tvltiliod ; t ¦•f?dro"i\r»!dt\f+ m'2>> !) mri
S;unpk ID : K2Kih a
Squired : Jul 21 2iH>S 21:^1 \1
1 ot I
Channel A Results
1
Name
r"-~- Tie
Chi. i i.Je
Ret Time
jU
: o
iJ 1
c .ezchrorr^ehrom\rnOOTl60.016 - Channel A
M
i
1
1
i
V
0
1
t
s
50-r
Peak Na
lie
h {'•
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-50
-25
10
15
Wirai1et>
M
i
I
1
i
v
0
1
t
s
-------
Instrument: Sliimacisu CDD-6A C
Eluant: 4 mH Phthalic Acid pH 3
Sain 0,2 pS/cm 40 p.1 Inj Vol
Me	, c
i\ [f'Ux! v.. si a iironi	e .net
,vrupte£^ M
\camrcii . .h'i ]1, 2»0K ''?,v '^4^
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.. 1mm
1 ot 1
. A Results
-4:	Ret Time	Area
Fluoride	] „ 4B	o013
Chloride	2.23	7416 8 ^
c:\ezchrom\clirom\m007160.020 -- Channel A
M
i
1
1
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v
0
1
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M
i
1
1
i
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0
1
t
s
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-------
J fV	i't: ."Jn i. =i Jr n 0!'i.> < \
f littu! -	-i ull'i i [\i* 1 in \ t	cl f_Jn _»
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File	• c • ca ^tmm< h omVn->»i7! t>c 0 ^!
Method	• >. u^vhi nrn	-15t .inct
^»j«e«L'	: i-~ u^u-i
«
-------
I rxs t r ura © n
Eluent: 4
Gain 0.~
i">k
Mc-hoJ
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Shimadzu CDD-6A C
4 mM Blxthalic Acid pH 3
]iS/oXtt 40 ]iX Xrxj VoX
v, ,t*ai,.:'Oi»f\c!jiou»\ti"tp I«'!' • 1*12
. \tAil,0!T.«teili>xK J)C'• ! mtt
, TT-1 H2S04 I
. Jul 22, 20US 01:54-ti .
1mm
1 ot 1
Channel A Results
te	Ret Time	Area
Flui-i id>ri	1.48
!	2,32
c:\ezchrom\elirom\rn0Q7160.022 — Channel A
-50
M
i
1
1
i
v
0
1
t
s
Peak Null
i-50
ie
25
10
15
M
i
1
1
i
v
0
1
t
s
M unites
-------
Instrument: Sh.iniadzu CDD-6A C
Eluent: 4 mM Ph.tlia.Iic Acid pH 3
Gain G * 2 ]iS/cel 40 Inj Vol
r s!c	1 t ^irnronrrhrfim .11'.•> J cV; 01>
Akibuci *	i,V)toei
Sample!} : H-2H2S04
Acquired : Jul 22, 200^ 0?,.^ 05
Imta
I ot 1
"harmel A Resu i. t s
FtJo"1*: NajiK
Ret Time
Area
F 1 dor iii'-ir
Chioride
c:\ezchiom\chrom\ni007160.023 - Channel A
M
i
1
1
i
v
0
1
t
s
Peak Na
M
i
1
1
i
v
0
1
t
s
-------
„ 1 m, ] ' . "•hm i I1 u i I -	"uluirn; JrL-.:.o.i r . i - ir i, 11	4 .< " xi '•:! Ti-Ih.j i * i Z
FiU	. r ¦ i'-;inf>ni\d« om11'
Maru'd	c c \hfi>mvi:'e,!ie.i'->i 1 hi ;acl
ed	im s-nsu.' h
learned	in! 2? 2uQX u3 )<-2?
Chaanel A Rusulns
Peak Name	Ret Time	Area
Fluoride	1.4 8	9075
.:\ezchrom\chrom\rn0071 <50,024 - Channel A
50-
M
i
1
1
i
v
0
1
t
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Peak Maps
25-
150
25
M
i
1
1
l
v
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1
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Minnies
10
15
-------
lmm	Page 1 ot 1
Eluent: 4 rtiM Phthalic Acid pH 3,6	Flow Rate; 1,75 mls/mirs.
Gain 0.2 p»S/citi 40 Xnj Vol
1-tiv'	• 1 ftJiKXfi\« IliOlO tffU'l" > t 0,*'l 1
MoUic.'i	rt
S,trii|iK n>	11-1 ' L'WX .<
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-------
Eluent:
Gain 0• I
Fs'c
Method
ID
<\tqn!r<, ci
i lIlM
COlUBUi
X ot i
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jiS/cm 40 ]il Inj Vol
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c.\c/t'K(<>iii\ii	1ni rnel
11 '2	^ v i
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I Same
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Ret Time
2.35
Area
c;\ezchrooi1,'chroni\m007160.0) - Channel A
M
i
1
1
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0
1
t
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Peak Name
M
i
1
1
i
v
0
1
t
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Minutes
-------
; bin .1 CJ.L- la
Column;
Eluent; 4 mM Piitfaallc Acid pH 3,6
Gain 0,2 pS/cm 4 0 |il inj Vol
Filer	c .eiciiroiiuciuviix'snvHt' > u'j, 22
Method i ¦ \tixhi uut«i «?Uu v t>,\ 112 o • t1 0 met
Sainpdcli) Zk>	.< : ,1
-iCijUirea Jo J '»,» 35
:ii anne 1 A
1 ot 1
Pea'-: Nhme
Chloride
Ret Time
2.60
Area
c:\ezchrom\chrom\mQ07160.029 - Channel A
M
i
1
1
i
v
0
1
t
s
Peak Name
M
i
1
1
i
v
0
1
t
s
5	10
Minutes
-------
Grsixx 0, 2 |iS/cm 4.0 |il Inj Vol
Fiic	c	1 >'' w3t;
MjhwA C	Ul2i"} 'Hi.("Id
ID . JI-I \r.Si) 1 > :b
Atqutrca . Jul _!2, 2oOH i*K2\5t>
Channel A Results
leak Mc-otie	Ret Time
Chloride	2.30
c:\e^ciirom\chroii]\ni007160,030 - Channel A
25-
0
5
10
15
Minutes
-------
1 • - • '.rate: • ' % n«rl"i M %
Eluent t 4 aiM Phthalic Acid pH I
Gain 0,2 pB/cm 4 0 ]il Inj Vol
i1 lie	: »•. nciif om\!a otn\i i f< >0 7 i '>0. u i I
Method c ^-y.iiac.irhiik'ShiHiMt-aiiv-ISC.rari
Sari'p'e !P !t-2 a2SOi 32 b
.-Uqnircri . Jul 22 ?'1u8 i 5 0], Hi
linia	Page 1 ot 1
i
>« ;tu i- t A Results
i '.?aic Nan,-	Ret Time	Area
Chloride	7. .37	]
c:\ezchrom\chrom\rn007160.031 - Channel A
50t
t50
Peak Name
M
i
1
1
i
v
0
1
t
s
-25
M
i
1
1
i
v
0
1
t
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5	If)
Minutes
15
-------
i , nr L-.pt": 0"hiTn=iu 'i > P." 1 >f
' iii" ir- i'iK i'hlL-	l-	i
Gain. 0,2 pS/cm 40 ]il Inj Vol
file	, < :>t-.'d!ram^Siiou«l jiOo~]ni) c>2
Method : s :\ezficAiAriieuiixiHdi^t -1V sue;
Sami-'uli' • d-MilHU-i Uli
Aiii'ired Jul 2? 2cKts> i w> ~i: -
Channel A Results
l-ecuc. N'-artiw
Ret Tim-;
Chloride
c:\ezchroin\chrom\m007160.032 - Channel A
M
i
1
1
l
v
0
1
t
s
Peak Name
5	10
Minutes
-------
L.i ' a	',1'!'= -Y " . num.	r *. '« 'u . ' V " >,.» ' ,1m	Page 1 of 1 {'£)
E] ut4it	i nili i'tit i.-i i i r -¦'¦j '.i pi f ' C Fx >u r._ > > . 1.^3 itJ i iii
1 t ,1,.	pR/Cfi"! iU jU L ri"- Vi 1 "riiip *t-J c
file	: c.,e;\iinmAeliuw JirKKi",360 tiH
iVktii'H;	• c.',ivc>ttiV"meihoJs^T/6-l 50.met
Ivuirfilt ID	1- 3 NAOH a
Acqittr«!	Jul 21 200S 20.31:4S
Channel A Results
tfc-jk lame	Ret Time	nr^c.
Chloride	-.20	61600
c:\e?.chrom\chroiu\RnOO 7160 101 -- Channel A
25-
15
10
1-25
Peak Name
¦20
-15
-10
M
i
1
1
i
v
0
1
t
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-5-L
0
5 "	ib
Minutes
-------
Tn rv lV	£]j lbi-^ ii h.\ T'i r '-'t.n ?V -	i'-lLi\! Irom	Page I ot 1 (J)
r Jt-	, ia>I phi nr.!,.' -V,.] } , 1 - . li f 1 J, ,:>->• . " t> L; euu
i „ ia 0,	' iil: •* en1 10 J-i-> ' -1 10 C
ItSe	, tAeLckv>ie\dvoiriTviii)>'*I^y
Vtcthod	, ,«ci
Aainpk* U)	I- 2 NAOi I a
Acquired	, Jul ,U, 20'<8 21 o"5 33 ^
Chaanej A faults
i '0.\ i-------
Instrument; Shimadzu GDD-6A C
Eluent; 4 nffll Plithalic Acid pH 3
ui. n O.I; v
-------
22	1 O iT 1 ( t) )
Eluent: 4 laM Ptitlialic Acid pH 3.8	Flow Rate; 1,75 mls/aiii
Gain 0. 2 pS/crn 40 jil Inj Vol	Temp 40 C
File	c. .^TCtTOitAc'ireirARi.!>00 1 M
KkihOk! . cV'clax tii	M2e- (
Sample U* . H-liWOiis
Ai-quireJ ; Jul 21,2008 22'l^.Oi ¦
A Results
Ret Time	Area
Chloride	2.22	120151
c:\ezchi*om\d]rom\Rji007Id0«l04 ~ Channel A
v
Peak Name
Minuter
-------
It> = 11 uf,->x,r ;	jru '"I'C'-'o/.	'jluran: Hvr o,u ?"• C- ' 3 "U	r,i ft	Page 1 at 1
iLlui-fi I J Hi" "PJ i t '.-if-' i	d |H 3, 6	^"1 >\r K^n	L.T'"< iuIj.1-1ja
! 1 u».v i-i ^
L'ile	c: ',ei r hrom'wl ux ti i* t: "Ow "» <"mVimv'i]ei;«Hib\ir.?6-l""nj.iiiet
Sample ID : M-iMAOf-ia
Acquired ; Jul 21 200S 22:54,4S .
Channel A
]	ae
Chloiids
Ret Time
2,22
Area
14166 0
M
i
I
1
i
v
0
1
t
s
c:\ezchrofn\chrom\m007160.105 - Channel A
25-
15
Peak Name

U
10
-25
-20
r15
-10
-4-3
15
M
i
1
1
i
v
0
1
t
s
Minutes
-------
, .11 ,-,1.	„1,, ,'.n, !	j imrt:	l t r i, PI -.---1 r-u J'.n,,4.1mm	Pa
-------
ins tr hen
Bluer), t;
Gain 0.*
File
MUllrtii
Fasnplt ff •
Ac.jUucd
; Shimadzu
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3/cm 40
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. ,/v-rclii	>'' I
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et
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1 Name
Chioxide
Ret
z, zu
AI fd
44 ill
c :\e7chroirs\chroxn\Rii00? 160.110 - Channel A
M
i
i
1
i
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0
1
t
s
Peak Name
u
M
i
1
1
i
v
0
1
t
s
Minutes
-------
L j, i, 1 1 ITp	^ t 1 M r*. ,V. li J 1 i ? T' — ^ tj^- 1 t Lf611 r;	Ti Lr f ~ L ) j 1t * J"-: , [ Hi '&	X^SCJ© 2. OtT X (X^)
Einent;	4 mM Phthalic Acid pH 3,6 Flow Rate; 1,75 mls/min
"n n n,2 ]i?''i-i,i	41"'1 ]a 1 « u i i l "!"vrjp 4 >) G
Tiic1	: c, .tvcitt"orri'.chroui.Rnu">:1h
CliAxinei A Ret u
Ee.vc Name
CIiIol ide
Ret Time
2.17
106164
c:\ezclirom\chrom\Rri007160,111 - Channel A.
M
i
1
1
i
v
0
1
t
s
Peak Name
M
i
1
1
i
v
0
1
t
s
Mamies
-------
I.it-1 •'jc : _'h.inic-.J'; u bit tV
Eluent: 4 mM Phthalic Acid pH 3
Gain. 0.2 pS/cst 40 p.l Txij Vol
I"tie	. c.:\e2c:iroiE\cliuiii'iil»00"?i6s) U2
Malta J . c vcjdvfiP'iadltod^iviJS-1> met
S,na,iklD a-i .VuJll b
.Acqu»mi : MZ2 2008 (H:u5;02
•ii .i:ar
1mm
Page 1 ot 1 (13)
"liannel A Results
F€ .\k li^UC
Chlori.'le
Fi1? c IxiOt
2.22
11
M
i
1
1
i
v
0
1
t
s
c:\e7chrom\chj-om\RjiG07160.112 - Channel A
15-
Peak Name
j
u
V-
Minutes
10
-25
10
M
i
1
1
i
v
0
1
t
s
-------
u.i f -in - -i, hiiruf1 *i ,*ti^	i' iiiim
Eluent: 4 mM Phthalic Acid	pH 3,6
Sain 0.2 ]iS/cm 40 p.1 Inj	Vol 1
Me , i V/cii?f40\rmMTitiifk« • 160 II-
J'tA.x" • c.\e-.*ciirora\i(j»-ilKtA:' Mid- f	i.:c;
Sant|>le ID : iM N
Acquired : Jul 21 0.*-4<> 47 .
'RP-.'i i ' i' -ri.j.m	Page I ot 1 (14)
:i ,k t.i
Channel A Resales
Peak Name	Ret 1 last-	Ai-*a
Chio rids	2.22	143 8 0 2
c-l>c7chrom\r!u-orn^1x007160.113 - Channel A
M
i
1
1
i
v
0
1
t
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-25
45
40
M
i
1
1
i
v
0
1
t
s
10
15

-------
August 15, 2008
Gene Stephenson
ARCADIS
4915 Prospectus Drive
Suite F
Durham, NC 27713-
Bureau Veritas Work Order No. A0807141
Reference: BURN PROJECT-NEW ORLEANS
Dear Gene Stephenson:
Bureau Veritas North America, Inc. received 5 samples on 7/21/2008 2:57:31 PM and
reported on 8/13/2008 4:24:35 PM for the analyses presented in the following report.
The results apply only to the samples analyzed in this project. Sample cassettes and all
preparations will be retained until written authorization to return these items has been
received.
We appreciate the opportunity to assist you. If you have any questions concerning the
report, please contact the analyst whose name appears on the report or myself at (770)
499-7500.
Sincerely,
C~~		 I'
AlanM. Segrave, P.G.
Director, Laboratory Services
Bureau Veritas North America,	Inc.
Health? Safety, and hrrvirmmentaf Services	Mam: (/"/()) 499--7500
3380 Chastam Meadows Parkway, Suite 300	Pax: ('/"/'()) 499-7511
Keiuiesaw, GA 30144	www.us.bureauveatas.com
-------
I
CASE NARRATIVE
Date: 15-Aug-08
CLIENT:
Project:
ARCADIS
BURN PROJECT-NEW ORLEANS
Work Order No A0807141
Report Date: 13-Aug-08
Three air sample cassettes (water impinger) and two bulk samples were received at Bureau Veritas
North America, Inc., Kennesaw, Georgia, facility on July 21, 2008. Samples were logged into the
laboratory information management system (LIMS) and provided an internal work order number as
indicated in the header above. All samples were analyzed according to cited methods below and the
project Quality Assurance Project Plan (dated June 20, 2008, Revision 0), with the following
modifications:
The particle loading for each sample was estimated as shown below.
BVNA Workorder ID	ClientSampID:	Estimated % Particle
The water impinger samples were sonicated and the entire volume was filtered onto new MCE 47 mm
0.45 micron filters. The filters were then ashed in a muffle furnace to remove organic partilces that may
be present. The ashed residue was also treated with dilute hydrochloric acid to remove solubles. This
material was then suspended in 100 ml deionized water and sonicated. The entire contents were then
filtered onto MCE 47 mm 0.45 micron filters. Portions of the filter were then prepared and examined as
indicated below.
For transmission electron microscopy (TEM) analysis, an equal number of grid openings were examined
on at least two prepared grids. Samples were analyzed to achieve an analytical sensitivity of 0.0005
structures/cubic centimeter (str/cc) on "Air" designated samples and 0.005 str/cc on "Worker"
designated samples. TEM analysis was performed at a nominal calibrated screen magnification of
20,000X. Counting rules used followed a modified ISO (the International Organization for
Standardization) 10312:1995 protocol where asbestos structures >0.5 um in length with a length to
width aspect ratio of >3:1 were quantified, plus all compact matrices and compact clusters as defined by
ISO 10312 regardless of aspect ratio. Structures were identified as chrysotile, amphibole asbestos or
forsterite (forsterite is defined as having asbestiform morphology and elemental composition consistent
with forsterite) using morphology, selected area electron diffraction, and energy-dispersive x-ray
spectroscopy. The analysis was terminated upon completion of the grid opening that met the required
analytical sensitivity outlined above or identification of 100 asbestos structures in a minimum of 4 grid
openings. Results for TEM ISO analysis were reported as total asbestos str/cc including a breakdown
according to the following ranges by length:
loading by TEM
A0807141-001A
A0807141-002A
A0807141-003A
RUN #11-ACD-ASB-01
RUN #ll-ACD-ASB-02
RUN #ll-ACD-ASB-03
20-30%
30-40%
20-30%
1 of 20
-------
I
CLIENT:
ARCADIS

Project:
BURN PROJECT-NEW ORLEANS

Work Order No
A0807141
Report Date: 13-Aug-08
a)	> 0.5 to 5.0 (im
b)	>5.0 to 10.0 |im
c)	>10.0 |im
The report quantifies "Total Asbestos" and "Total Forsterite" as any asbestos structure or forsterite
structure, respectively, >0.5 (im in length with an aspect ratio >3:1, plus all compact matrices and
compact clusters as defined by ISO 10312 regardless of aspect ratio. Phase contrast microscopy-
equivalent structures (PCME), asbestos structures and forsterite structures >5 (im in length and from 0.2
to 3.0 |im in diameter with an aspect ratio >3:1, are also reported.
Results for phase contrast microscopy (PCM) analysis are reported as total concentration for all fibers
expressed as fibers/cc. Counting Rules A were used where fibers >5.0 |im in length and >0.25 |_im in
width with a length to width aspect ratio of >3:1 were counted. Approximately 400X magnification was
used during the analysis. The analysis was terminated upon counting 100 fibers, with a minimum of 10
fields counted.
Sample cassettes and all preparations will be retained until written authorization to return these items has
been received.
References
ISO (the International Organization for Standardization), Ambient Air -Determination of Asbestos
Fibers -Direct Transfer Transmission Electron Microscopy Method, ISO 10312:1995, (1st Ed. 1995-05-
01).
"Asbestos and Other Fibers by PCM: Method 7400" - NIOSH Manual of Analytical Methods, 4th
Edition, U.S. Department of HHS, NIOSH Publ. 94-113, 1994.
Bureau Veritas North America, Inc, Internal Procedure for Characterizing Asbestiform Forsterite from
Heat Altered Chrysotile, June 2008
NIOSH Manual of Analytical Methods
Note: Forsterite fibers and asbestos were materials that were examined as part of the analysis below.
Use of EPA/600/R-93/116 satisfies applicable requirements of the USEPA's "Interim Method for the
Determination of Asbestos in Bulk Insulation Sample", EPA-600/M4-82-020, December 1982,
published as Appendix E to Subpart E of 40CFR763. Bulk samples analyzed by New York State
2 Of 20
-------
CLIENT:
ARCADIS

Project:
BURN PROJECT-NEW ORLEANS

Work Order No
A0807141
Report Date: 13-Aug-08
methods follow stratified point counting methods (198.1) or Method 198.6 for PLM non-friable
organically bound materials (NYSDOH Lab Code -11645). Percentages are visual estimations. The
reliable limit of quantitation of the method is 1%, although asbestos may be qualitatively detected at
concentrations less than 1%. Samples for which asbestos is detected at <1% are reported as trace,
"<1%". "None Detected" indicates that no asbestos fibers were observed. NESHAP requires point
counting of a bulk sample when the result is <10% by a method other than point counting. EPA,
however states that if 3 mounts of the sample are analyzed and the asbestos percentage is <10% by
visual estimation, the client may elect to assume the amount to be greater than 1% or require verification
by point counting. If the result by point counting is different than the result obtained by visual
estimation, the point count result will be used. Sample friability or non-friability noted on the report is a
requirement for the State of California and refers only to the condition of the sample under macroscopic
examination. It does not imply friability or non-friability for the sample as collected or observed in the
field as determined by the person collecting the sample. The Kennesaw, Georgia lab is accredited by
NVLAP -Lab Code 101125-0.
(a)Polarized- light microscopy is not consistently reliable in detecting asbestos in floor coverings and
similar non-friable organically bound materials. Quantitative electron microscopy is currently the only
method that can be used to determine if this material can be considered or treated as non-asbestos
containing. When analysis of such materials by PLM yields results negative for the presence of asbestos,
Bureau Veritas recommends utilizing quantitative transmission electron microscopy (TEM). For more
information, contact the laboratory.
References
McCrone, Walter C. 1980. The Asbestos Particle Atlas. Ann Arbor, MI: Ann Arbor Science
Publishers, Inc.
United States Environmental Protection Agency. Environmental Monitoring Systems Laboratory.
1982. Interim Method for the Determination of Asbestos in Bulk Insulation Samples. EPA-600/M4-82-
020. Washington: GPO, December.
United States Environmental Protection Agency. Method for the Determination of Asbestos in Bulk
Building Materials. EPA-600/R-93/116, July 1993 (PLM)
Fed. Reg. Vol. 55, No.224, 11/20/90, p.48415 (NESHAP)
EPA Memorandum 5/8/1991 -NESHAP Clarifications
NYSDOH Methods 198.1/198.6
QUANTITATIVE ANALYSIS OF BULK SAMPLES FOR ASBESTOS AND FORSTERITE FIBERS
-------
CLIENT:
ARCADIS

Project:
BURN PROJECT-NEW ORLEANS

Work Order No
A0807141
Report Date: 13-Aug-08
USING TRANSMISSION ELECTRON MICROSCOPY (TEM)
Upon receipt in the laboratory, samples are ground until homogeneous. Each sample is weighed in a
tared silica crucible. The sample is placed in a muffle furnace at a temperature of 480 degrees C for 3
hours. The sample is allowed to cool to room temperature and immediately weighed to record ashed
sample weight.
Approximately 1 ml of nondiluted HCL acid is slowly added to remove calcite and dolomite from the
ashed sample. After evolution of C02 gas has ceased, the sample is immediately diluted with ultra-pure
water. The sample is then dispersed in 50 ml of ultra-pure water and filtered onto a pre-weighed 47 mm,
0.45 um pore size, MCE filter. The filter is dried on a slide warmer and weighed once again.
A 1 cm2 portion of the filter is cut and placed in a clean silica crucible. Approximately 250 ul of both 20
ppm methyl cellulose solution and isopropyl alcohol are added and ultra-sonicated for 1 minute to
remove the deposited sample into suspension. Approximately 3 ul of the suspension is pipetted onto a
carbon-coated copper TEM grid and allowed to dry.
Grids are examined in the TEM at 15,000X magnification. Asbestos or forsterite (forsterite is defined as
having asbestiform morphology and elemental composition consistent with forsterite) using morphology,
selected area electron diffraction, and energy-dispersive x-ray spectroscopy. From TEM examination, a
visual area estimation is made of asbestos or forsterite in the final residue. Percent asbestos or forsterite
in the final residue is then extrapolated using gravimetric records to percent asbestos or forsterite in the
total sample.
References
Chatfield Method for Quantitative Analysis of Bulk Samples for Asbestos Using Transmission Electron
Microscopy (unpublished).
Bureau Veritas North America, Inc, Internal Procedure for Characterizing Asbestiform Forsterite from
Heat Altered Chrysotile, June 2008
-------

ANALYTICAL RESULTS
CLIENT:	ARCADIS
Work Order No.: A0807141
Client Reference: BURN PROJECT-NEW ORLEANS
Date: 15-Aug-O
Sample Type:	Air
Method Reference:	NIOSH 7400A
RL (fibers/mm2):	5 .0
Analyst:	JP
Date Sampled:	06/25/2008
Date Received:	07/21/2008
Date Analyzed:	07/30/2008
Report Date:	08/13/2008
Lab
Sample

Air Volume
Fiber Concentration

ID
Identification

(liters) (fibers/mm2) (fibers/filter)
(fibers/cc)
001A
RUN #II-ACD-ASB-01

1000
49
64,000
0.064
002A
RUN #ll-ACD-ASB-02

1000
21
27,000
0.027
003A
RUN #ll-ACD-ASB-03

1000
31
41,000
0.041



Microscope Documentation




Instrument
Manufacturer
Model
Field Area (mm2)
Calibration Date

PCM 2
Olympus
BH-2
0.008008
2/27/2008

Analyst(s) Name/Date:

8/15/2008
5 of 20
-------
I
ANALYTICAL RESULTS
Date: 15-Aug-O
CLIENT:	ARCADIS
Work Order No.:	A0807141
Client Reference:	BURN PROJECT-NEW ORLEANS
Method Reference:	EPA-600/M4-82-020/EPA/600/R-93/116/NYELAP 198.1
Sample Type: Bulk
Date Received: 7/21/2008
Report Date: 13-Aug-08
Lab ID
Client Sample ID
Analyst Date Sampled
Date Analyzed
004A COMPOSITE ASH SAMPLE 1
KC
06/26/2008
07/22/2008
Layer POB	Sample Morphology	Asbestos	%
(1) 100 Homogeneous Black/Beige/Grey Ash None Detected
Layer Comment: No forsterite found in sample.
005A COMPOSITE ASH SAMPLE 2	KC
Other Fibers
Non-Detected
%
06/26/2008
Particulate
Ash
Granular Minerals
Mica
Opaque Material
Quartz
07/22/2008
Layer POB
Sample Morphology
Asbestos
%
Other Fibers %
Particulate
(1) 100 Homogeneous Black/Beige/Grey Ash None Detected	Fibrous glass 1%	Ash
Granular Minerals
Mica
Opaque Material
Quartz
Metal
Layer Comment: No forsterite found in sample. Metal layer not analyzed.

Microscope Documentation

Instrument
Manufacturer Model
Description
PLM 5
Olympus BH-2
Olympus Polarizing Microscope
The reliable limit of quantitation of the method is 1%, although asbestos maybe qualitatively detected at concentrations less than 1%. Samples
which asbestos is detected at <1% are reported as trace, "<1%". "None Detected" indicates that no asbestos fibers were observed.
Analyses) Name/Date:
8/13/2008
6 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Date: 15-Aug-(
Analytical Method
Sample Type
Reporting Limit (% by Weight)
TEM Full-Quantitative Analysis EPA/600/R-93/1	Date Received:
Bulk	Report Date:
0.1	Grid Box Identification:
7/21/2008 2:57:31 PM
8/13/2008 4:24:35 PM
07-29-08C-1
Lab Sample
Client Sample
Date
Analysis

Sample Description
Asbestos
Total Asbestos
No.
Identification
Sampled
Date
Analyst
(Morphology)
Identification (%)*
(%)**
A0807141-004A
COMPOSITE ASH
06/26/08
08/11/08
KRP
Black/Beige/Grey
None Detected —
<0.1

SAMPLE 1
@12:00 am
@8:39 pm

Ash


No forsterite found in sample.






A0807141-005A
COMPOSITE ASH
06/26/08
08/11/08
KRP
Black/Beige/Grey
None Detected —
<0.1

SAMPLE 2
@12:00 am
@8:39 pm

Ash


No forsterite found in sample.






Instrument
TEM Microscope Documentation
Accelerating
*Magnification Voltage Calibration Date
TEM 1/D675	17861x 100 KeV 7/28/2008
TEM 1/D675	14400x 100 KeV 7/7/2008
'Magnification = Calibrated screen magnification at 15.000X. For ISO Method 10312 the calibrated screen magnification is at 20.000X
Result is less than the indicated limit of detection.	—: Not Requested or Not Applicable.
The visual area estimation of asbestos content in the final residue.
The calculated total percent asbestos in the sample as received.
Analyst(s) Name/Date:

i it
8/13/2008
7 of
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Date: 15-Aug-i
Analytical Method: TEM -ISO 10312 Method, 1995 (modified)
Sample Type: Air
Date Received
Report Date
Grid Opening Size
7/21/2008 2:57:3
8/13/2008 4:24:3
0.0104 mm2
Lab Sample
Client Sample
Date
Air

EFA
Analysis
Grid Box
No.
Identification
Sampled
Vol. (L)
Filter
(mm2)
Date
Analyst Identification
A0807141-001A RUN #II-ACD-ASB-01 06/25/08 1000 MCE Filter, 1320 08/11/08 KRP 07-21-08E-1
@12:00 am	,45um	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos 5.0 - 10.0 (b)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos >10.0 (c)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Asbestos
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 0.5 - 5.0 (g)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 5.0 -10.0 (h)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite > 10.0 (f)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Forsterite
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary >5.0 (e)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary 0.5 - 5.0 (d)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
PCME
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
MCEF: Mixed Cellulose Ester Filter	s/cc: Structures per cubic centimeter of air collected.
s/mm2: Structures per square millimeter	<: Result is less than the indicated limit of detection.
: No Results (Air Volume is 0)
Note 1: Structures counted contain fibers which met >5:1 (length:width) aspect ratio and wer > 0.5um in lengt
Note 2: AE1ERA sampling criteria requires that >1200 liters of air be collected on 0.45um filters. Deviation from thses requirements
may results in a high analytical sensitivity. Structurs/cc values are based on client air volumes.
8 of
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Date: 15-Aug-i
Analytical Method: TEM -ISO 10312 Method, 1995 (modified)
Sample Type: Air
Date Received
Report Date
Grid Opening Size
7/21/2008 2:57:3
8/13/2008 4:24:3
0.0104 mm2
Lab Sample
Client Sample
Date
Air

EFA
Analysis
Grid Box
No.
Identification
Sampled
Vol. (L)
Filter
(mm2)
Date
Analyst Identification
A0807141-002A RUN #II-ACD-ASB-02 06/26/08 1000 MCE Filter, 1320 08/11/08 KRP 07-21-08E-1
@12:00 am	,45um	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos 5.0 - 10.0 (b)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos >10.0 (c)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Asbestos
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 0.5 - 5.0 (g)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 5.0 -10.0 (h)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite > 10.0 (f)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Forsterite
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary >5.0 (e)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary 0.5 - 5.0 (d)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
PCME
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
MCEF: Mixed Cellulose Ester Filter	s/cc: Structures per cubic centimeter of air collected.
s/mm2: Structures per square millimeter	<: Result is less than the indicated limit of detection.
: No Results (Air Volume is 0)
Note 1: Structures counted contain fibers which met >5:1 (length:width) aspect ratio and wer > 0.5um in lengt
Note 2: AE1ERA sampling criteria requires that >1200 liters of air be collected on 0.45um filters. Deviation from thses requirements
may results in a high analytical sensitivity. Structurs/cc values are based on client air volumes.
9 of
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Date: 15-Aug-i
Analytical Method: TEM -ISO 10312 Method, 1995 (modified)
Sample Type: Air
Date Received
Report Date
Grid Opening Size
7/21/2008 2:57:3
8/13/2008 4:24:3
0.0104 mm2
Lab Sample
Client Sample
Date
Air

EFA
Analysis
Grid Box
No.
Identification
Sampled
Vol. (L)
Filter
(mm2)
Date
Analyst Identification
A0807141-003A RUN #II-ACD-ASB-03 06/26/08 1000 MCE Filter, 1320 08/11/08 KRP 07-21-08E-1
@12:00 am	,45um	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos 5.0 - 10.0 (b)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos >10.0 (c)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Asbestos
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 0.5 - 5.0 (g)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 5.0 -10.0 (h)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite > 10.0 (f)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Forsterite
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary >5.0 (e)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary 0.5 - 5.0 (d)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
PCME
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
MCEF: Mixed Cellulose Ester Filter	s/cc: Structures per cubic centimeter of air collected.
s/mm2: Structures per square millimeter	<: Result is less than the indicated limit of detection.
: No Results (Air Volume is 0)
Note 1: Structures counted contain fibers which met >5:1 (length:width) aspect ratio and wer > 0.5um in lengt
Note 2: AE1ERA sampling criteria requires that >1200 liters of air be collected on 0.45um filters. Deviation from thses requirements
may results in a high analytical sensitivity. Structurs/cc values are based on client air volumes.
far, 1 uk
Analyst(s) Name/Date: '	\	8/13/2008
10 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-001A RUN #II-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos 5.0 - 10.0 (b)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos >10.0 (c)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Asbestos
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 0.5 - 5.0 (g)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 5.0 -10.0 (h)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite > 10.0 (f)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Forsterite
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary >5.0 (e)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary 0.5 - 5.0 (d)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
PCME
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
1
A1
G4D
0
0


0.0
0.0

2
A1
G4B
0
0


0.0
0.0

3
A1
F4D
0
0


0.0
0.0

4
A1
F4B
0
0


0.0
0.0

11 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-001A RUN #II-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
5
A1
C5A
0
0


0.0
0.0

6
A1
C5C
0
0


0.0
0.0

7
A1
E5A
0
0


0.0
0.0

8
A1
E5C
0
0


0.0
0.0

9
A1
F5A
0
0


0.0
0.0

10
A1
F5C
0
0


0.0
0.0

11
A1
G5A
0
0


0.0
0.0

12
A1
G5C
0
0


0.0
0.0

13
A1
H5A
0
0


0.0
0.0

14
A1
H5C
1
0

MD100
4.2
1.6
Tremolite
15
A1
H5C
0
1
CDQ
MF
4.2
0.2
Tremolite
16
A2
E4C
0
0


0.0
0.0

17
A2
F4A
0
0


0.0
0.0

18
A2
F4C
0
0


0.0
0.0

19
A2
G4A
0
0


0.0
0.0

20
A2
G4C
0
0


0.0
0.0

21
A2
H4A
0
0


0.0
0.0

22
A2
H4C
0
0


0.0
0.0

12 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-001A RUN #II-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID:
07-21-08E-1-A1-5

TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
23
A2
F3C
0
0


0.0
0.0

24
A2
F3A
0
0


0.0
0.0

25
A2
E3A
0
0


0.0
0.0

26
A2
C3A
0
0


0.0
0.0

27
A2
C3C
0
0


0.0
0.0

Totals: 1	1
TEM Microscope Documentation
Accelerating
	Instrument	*Magnification Voltage Calibration Date	
TEM 1/D675	17861x 100 KeV 7/28/2008
*Magnification = Calibrated screen magnification at 15,000X. For ISO Method 10312 the calibrated screen magnification is at 20,000X
13 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-002A RUN #II-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos 5.0 - 10.0 (b)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos >10.0 (c)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Asbestos
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 0.5 - 5.0 (g)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 5.0 -10.0 (h)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite> 10.0 (f)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Forsterite
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary >5.0 (e)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary 0.5 - 5.0 (d)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
PCME
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
1
B1
C4C
0
0


0.0
0.0

2
B1
E4A
0
0


0.0
0.0

3
B1
E4C
0
0


0.0
0.0

4
B1
F4A
0
0


0.0
0.0

14 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-002A RUN #II-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
5
B1
G4D
0
0


0.0
0.0

6
B1
G4B
0
0


0.0
0.0

7
B1
F4D
0
0


0.0
0.0

8
B1
F4B
0
0


0.0
0.0

9
B1
E4D
0
0


0.0
0.0

10
B1
E4B
0
0


0.0
0.0

11
B1
C4D
0
0


0.0
0.0

12
B1
E5A
0
0


0.0
0.0

13
B1
E5C
0
0


0.0
0.0

14
B2
C4A
0
0


0.0
0.0

15
B2
C4C
0
0


0.0
0.0

16
B2
E4A
0
0


0.0
0.0

17
B2
E4C
0
0


0.0
0.0

18
B2
F4A
0
0


0.0
0.0

19
B2
F4C
0
0


0.0
0.0

20
B2
G4A
0
0


0.0
0.0

21
B2
G4C
0
0


0.0
0.0

22
B2
H4A
0
0


0.0
0.0

15 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-002A RUN #II-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID:
07-21-08E-1-B1-5

TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
23
B2
H4C
0
0


0.0
0.0

24
B2
H4D
0
0


0.0
0.0

25
B2
H4B
0
0


0.0
0.0

26
B2
G4D
0
0


0.0
0.0

Totals: 0	0
TEM Microscope Documentation
Accelerating
	Instrument	*Magnification Voltage Calibration Date	
TEM 1/D675	17861x 100 KeV 7/28/2008
*Magnification = Calibrated screen magnification at 15,000X. For ISO Method 10312 the calibrated screen magnification is at 20,000X
16 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-003A RUN #II-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos 5.0 - 10.0 (b)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Asbestos >10.0 (c)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Asbestos
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 0.5 - 5.0 (g)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite 5.0 -10.0 (h)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Forsterite > 10.0 (f)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Total Forsterite
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary >5.0 (e)
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
Primary 0.5 - 5.0 (d)
26
3.7
3.7
1
0
0.0049
< 0.0049
0.0049
0
< 0.022
PCME
26
3.7
< 3.7
0
0
< 0.0049
< 0.0049
0.0049
0
< 0.022
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
1
CI
C4B
1
0

MD100
2.5
2.0
Tremolite
2
CI
C4B
0
1
CDQ
MF
1.6
0.4
Tremolite
3
CI
F4C
0
0


0.0
0.0

4
CI
G4A
0
0


0.0
0.0

17 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Report Date: 8/13/2008 4:24:35 PM
Date: 15-Aug-t
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0807141-003A RUN #II-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 KRP 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
5
CI
G4C
0
0


0.0
0.0

6
CI
H4A
0
0


0.0
0.0

7
CI
H4C
0
0


0.0
0.0

8
CI
H4D
0
0


0.0
0.0

9
CI
H4B
0
0


0.0
0.0

10
CI
G4D
0
0


0.0
0.0

11
CI
G4B
0
0


0.0
0.0

12
CI
F4D
0
0


0.0
0.0

13
CI
F4B
0
0


0.0
0.0

14
CI
E4B
0
0


0.0
0.0

15
C2
G4A
0
0


0.0
0.0

16
C2
G4C
0
0


0.0
0.0

17
C2
H4A
0
0


0.0
0.0

18
C2
H4C
0
0


0.0
0.0

19
C2
H4D
0
0


0.0
0.0

20
C2
G4D
0
0


0.0
0.0

21
C2
G4B
0
0


0.0
0.0

22
C2
F4D
0
0


0.0
0.0

18 of 20
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0807141
Date: 15-Aug-t
Analytical Method
Sample Type
Date Received
TEM -ISO 10312 Method, 1995 (modified)
Air
7/21/2008 2:57:31 PM
Filtration Filter: MCE Filter, ,45um
Effective Filter Area: 1320 mm2
Grid Opening Size: 0.0104 mm2
Report Date: 8/13/2008 4:24:35 PM
Lab Sample
Client Sample
Date
Prep
Air
Dilution
Analysis Grid Box
No.
Identification
Sampled
Date
Vol. (L)
Factor
Date Analyst Identification
A0807141-003A RUN #II-ACD-ASB-03
06/26/08
07/21/08
1000
1
08/11/08 KRP 07-21-08E-1





@12:00 am @5:51 pm


@9:06 pm
GridBoxID:
07-21-08E-1-C1-5











TEM Count Details





Grid
Slumber of Structures
Identifi-
Structure
Length
Width



Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment


23
C2
F4B
0
0


0.0
0.0



24
C2
E4D
0
0


0.0
0.0



25
C2
E4B
0
0


0.0
0.0



26
C2
C4D
0
0


0.0
0.0



27
C2
C4B
0
0


0.0
0.0




Totals:
1
1










TEM Microscope Documentation







Accelerating




Instrument
*Magnification Voltage Calibration Date



TEM 1/D675

17861x
100 KeV 7/28/2008



'Magnification = Calibrated screen magnification at 15.000X. For ISO Method 10312 the calibrated screen magnification is at 20.000X
(a):	Asbestos Structure >= 0.5 um to 5.0 um
(b):	Asbestos Structure >5.0 um to 10.0 um
(c):	Asbestos Structure >10.0 um
(d)	:Primary Structures >= 0.5 um to 5.0 um
(e):	Primary Structures >5.0 um
(s/cc): Structure(s)/cubic centimeter of air..	mm2: square millimeter
<: Result is less than the limit of detection. s/mm2: Structures per square millimeter
:No Results (Air Volume is 0)	um:micrometer
: Format = "AA ###" where "AA" is the ISO pneumonic for the structure type.
"###" represents the number of structures in each of the Asbestos Structure criteria
noted in (a) - (c). Quantification greater than 9 is denoted with a "+" symbol.
Analyses) Name/Date:
8/13/2008
19 of 20
-------
Arcadfs
4918 Prospectus Drive
Durham, MC 27713
(919) 544-4636
CHAIN OF CUSTODY RECORD
Project Description:
Arcadis charge #:
Pag®_
/ i *"-y
of 1


	 			 Responsible Arnariip Party
Sample ID
Date
Collected
Sample Description
Numbar of
Contflifiisn
Analyses Heegufaed ]
!
Run 4 II-ACD-AS8-Q1
OS/25/08
Asbetos train jmpinoer water
i?)D7Tmr
1
Please call Gene ® 919-544-4535 / !
RM# IS-ACD-ASB-U2
06/26/08
Asbeios train impinper water

1
Pisase caO Gene ( 4 llf\ /") -J""
Run * II-ACD-ASB-Q3
OS/26/06
As&stos train tmpinger water

1
Please call Gsns /





~r	 -i
^ s
Composite ash samole 1
06/26/08
Comoosite ash sample collected before operation on 6/26/08

1
		 ' ' ' 	1
Please call Gene ?
Composite ash sample 2
06/27/08
Composite ash sample collected morning of 6/27/08
c rtrn 1
1
Please cell Gen® jj





j



* ¦
	
|
Please don't bee
!tn work
until Purchase req Is received








1











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i i i



i i i
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L**-$ i
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Samples collected by:
(signature)
Samples relinquished by:
(signature)
Samples received by:
(signature)
Chariy King

TvuX
'
-------
November 06, 2008
Gene Stephenson
ARCADIS
4915 Prospectus Drive
Suite F
Durham, NC 27713-
Bureau Veritas Work Order No. A0810163
Reference: BURN PROJECT-NEW ORLEANS
Dear Gene Stephenson:
Bureau Veritas North America, Inc. received 3 samples on 10/22/2008 10:17:28 AM and
reported on 11/6/2008 9:11:27 AM for the analyses presented in the following report.
The results apply only to the samples analyzed in this project. Please note that any
unused portion of the samples will be discarded after a thirty-day holding period, unless
you have requested otherwise.
We appreciate the opportunity to assist you. If you have any questions concerning the
report, please contact the analyst whose name appears on the report or myself at (770)
499-7500.
Sincerely,
AlanM. Segrave, P.G.
Director, Laboratory Services
Bureau Veritas North America, Inc.
biea/fb, Safety, and hmiromnenfuf Services
3380 Chastam Meadows Parkway, Suite 300
Kennesaw, GA 30144
Maui: (770) 499 .'7500
Fax: (770) 499-7511
-------
I
CASE NARRATIVE	Date: 06-Nov-08
CLIENT:
ARCADIS

Project:
BURN PROJECT-NEW ORLEANS

Work Order No
A0810163
Report Date: 06-Nov-08
Three air sample cassettes (water impinger) were received at Bureau Veritas North America, Inc.,
Kennesaw, Georgia, facility on July 21, 2008. Samples were logged into the laboratory information
management system (LIMS) and provided an internal work order number as indicated in the header
above. All samples were analyzed according to cited methods below and the project Quality Assurance
Project Plan (dated June 20, 2008, Revision 0), with the following modifications:
The particle loading for each sample was estimated as shown below.
BVNA Workorder ID	Clients ampID:	Estimated % Particle loading by TEM
A0810163-001A	RUN #11-ACD-ASB-01	20-30%
A0810163-002A	RUN #ll-ACD-ASB-02	30-40%
A0810163-003A	RUN #ll-ACD-ASB-03	20-30%
The water impinger samples were sonicated and the entire volume was filtered onto new MCE 47 mm
0.45 micron filters. The filters were then ashed in a muffle furnace to remove organic particles that may
be present. The ashed residue was also treated with dilute hydrochloric acid to remove solubles. This
material was then suspended in 100 ml deionized water and sonicated. The entire contents were then
filtered onto MCE 47 mm 0.45 micron filters. Portions of the filter were then prepared and examined as
indicated below.
For transmission electron microscopy (TEM) analysis, an equal number of grid openings were examined
on at least two prepared grids. Samples were analyzed to achieve an analytical sensitivity of 0.0005
structures/cubic centimeter (str/cc) on "Air" designated samples and 0.005 str/cc on "Worker"
designated samples. TEM analysis was performed at a nominal calibrated screen magnification of
20,000X. Counting rules used followed a modified ISO (the International Organization for
Standardization) 10312:1995 protocol where asbestos structures >0.5 um in length with a length to
width aspect ratio of >3:1 were quantified, plus all compact matrices and compact clusters as defined by
ISO 10312 regardless of aspect ratio. Structures were identified as chrysotile, amphibole asbestos or
forsterite (forsterite is defined as having asbestiform morphology and elemental composition consistent
with forsterite) using morphology, selected area electron diffraction, and energy-dispersive x-ray
spectroscopy. The analysis was terminated upon completion of the grid opening that met the required
analytical sensitivity outlined above or identification of 100 asbestos structures in a minimum of 4 grid
openings. Results for TEM ISO analysis were reported as total asbestos str/cc including a breakdown
according to the following ranges by length:
a)	> 0.5 to 5.0 tun
b)	>5.0 to 10.0 |im
1 Of 32
-------
I
CLIENT:
ARCADIS

Project:
BURN PROJECT-NEW ORLEANS

Work Order No
A0810163
Report Date: 06-Nov-08
c) >10.0 |jm
The report quantifies "Total Asbestos" and "Total Forsterite" as any asbestos structure or forsterite
structure, respectively, >0.5 (im in length with an aspect ratio >3:1, plus all compact matrices and
compact clusters as defined by ISO 10312 regardless of aspect ratio. Phase contrast microscopy-
equivalent structures (PCME), asbestos structures and forsterite structures >5 |im in length and from 0.2
to 3.0 |im in diameter with an aspect ratio >3:1, are also reported.
After analysis was completed for project A0807141 additional analysis was requested by the client. The
above listed samples were relogged in as project AO 810163 and 68 additional openings were analyzed
for each sample. The original results were incorporated into this report.
Sample cassettes and all preparations will be retained until written authorization to return these items has
been received.
References
ISO (the International Organization for Standardization), Ambient Air -Determination of Asbestos
Fibers -Direct Transfer Transmission Electron Microscopy Method, ISO 10312:1995, (1st Ed. 1995-05-
01).
"Asbestos and Other Fibers by PCM: Method 7400" - NIOSH Manual of Analytical Methods, 4th
Edition, U.S. Department of HHS, NIOSH Publ. 94-113, 1994.
Bureau Veritas North America, Inc, Internal Procedure for Characterizing Asbestiform Forsterite from
Heat Altered Chrysotile, June 2008
2 Of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Date: 06-Nov-08
Analytical Method: TEM -ISO 10312 Method, 1995 (modified)
Sample Type: Air
Date Received
Report Date
Grid Opening Size
10/22/2008 10:1
11/6/2008 9:11:2
0.0104 mm2
Lab Sample
Client Sample
Date
Air

EFA
Analysis
Grid Box
No.
Identification
Sampled
Vol. (L)
Filter
(mm2)
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 1000 MCE Filter, 1320 08/11/08 CG 07-21-08E-1
@12:00 am	,45um	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
94
1.0
7.1
7
0
0.0094
< 0.0013
0.0013
0.0043
0.019
Asbestos 5.0 - 10.0 (b)
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
Asbestos >10.0 (c)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Asbestos
94
1.0
8.2
8
0
0.011
< 0.0013
0.0013
0.0051
0.021
Forsterite 0.5 - 5.0 (g)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite 5.0 -10.0 (h)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite > 10.0 (f)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Forsterite
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary >5.0 (e)
94
1.0
4.1
4
0
0.0054
< 0.0013
0.0013
0.0020
0.013
Primary 0.5 - 5.0 (d)
94
1.0
4.1
4
0
0.0054
< 0.0013
0.0013
0.0020
0.013
PCME
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
MCEF: Mixed Cellulose Ester Filter	s/cc: Structures per cubic centimeter of air collected.
s/mm2: Structures per square millimeter	<: Result is less than the indicated limit of detection.
: No Results (Air Volume is 0)
Note 1: Structures counted contain fibers which met	>3:1 (length:width) aspect ratio and were > 0.5um in length.
3 of
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Date: 06-Nov-08
Analytical Method: TEM -ISO 10312 Method, 1995 (modified)
Sample Type: Air
Date Received
Report Date
Grid Opening Size
10/22/2008 10:1
11/6/2008 9:11:2
0.0104 mm2
Lab Sample
Client Sample
Date
Air

EFA
Analysis
Grid Box
No.
Identification
Sampled
Vol. (L)
Filter
(mm2)
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 1000 MCE Filter, 1320 08/11/08 CG 07-21-08E-1
@12:00 am	,45um	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
94
1.0
2.0
2
0
0.0027
< 0.0013
0.0013
0
< 0.0083
Asbestos 5.0 - 10.0 (b)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Asbestos >10.0 (c)
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
Total Asbestos
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
Forsterite 0.5 - 5.0 (g)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite 5.0 -10.0 (h)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite > 10.0 (f)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Forsterite
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary >5.0 (e)
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
Primary 0.5 - 5.0 (d)
94
1.0
2.0
2
0
0.0027
< 0.0013
0.0013
0
< 0.0083
PCME
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
MCEF: Mixed Cellulose Ester Filter	s/cc: Structures per cubic centimeter of air collected.
s/mm2: Structures per square millimeter	<: Result is less than the indicated limit of detection.
: No Results (Air Volume is 0)
Note 1: Structures counted contain fibers which met	>3:1 (length:width) aspect ratio and were > 0.5um in length.
4 of
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Date: 06-Nov-08
Analytical Method: TEM -ISO 10312 Method, 1995 (modified)
Sample Type: Air
Date Received
Report Date
Grid Opening Size
10/22/2008 10:1
11/6/2008 9:11:2
0.0104 mm2
Lab Sample
Client Sample
Date
Air

EFA
Analysis
Grid Box
No.
Identification
Sampled
Vol. (L)
Filter
(mm2)
Date
Analyst Identification
A0810163-003A RUN #ll-ACD-ASB-03 06/26/08 1000 MCE Filter, 1320 08/11/08 CG 07-21-08E-1
@12:00 am	,45um	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
Asbestos 5.0 - 10.0 (b)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Asbestos >10.0 (c)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Asbestos
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
Forsterite 0.5 - 5.0 (g)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite 5.0 -10.0 (h)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite > 10.0 (f)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Forsterite
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary >5.0 (e)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary 0.5 - 5.0 (d)
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
PCME
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
MCEF: Mixed Cellulose Ester Filter	s/cc: Structures per cubic centimeter of air collected.
s/mm2: Structures per square millimeter	<: Result is less than the indicated limit of detection.
: No Results (Air Volume is 0)
Note 1: Structures counted contain fibers which met >3:1 (length:width) aspect ratio and were > 0.5um in length.
Analyst(s) Name/Date: 	^	11/6/2008
5 of
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
94
1.0
7.1
7
0
0.0094
< 0.0013
0.0013
0.0043
0.019
Asbestos 5.0 - 10.0 (b)
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
Asbestos >10.0 (c)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Asbestos
94
1.0
8.2
8
0
0.011
< 0.0013
0.0013
0.0051
0.021
Forsterite 0.5 - 5.0 (g)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite 5.0 -10.0 (h)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite> 10.0 (f)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Forsterite
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary >5.0 (e)
94
1.0
4.1
4
0
0.0054
< 0.0013
0.0013
0.0020
0.013
Primary 0.5 - 5.0 (d)
94
1.0
4.1
4
0
0.0054
< 0.0013
0.0013
0.0020
0.013
PCME
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
1
A1
G4D
0
0


0.0
0.0

2
A1
G4B
0
0


0.0
0.0

3
A1
F4D
0
0


0.0
0.0

4
A1
F4B
0
0


0.0
0.0

6 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
5
A1
C5A
0
0


0.0
0.0

6
A1
C5C
0
0


0.0
0.0

7
A1
E5A
0
0


0.0
0.0

8
A1
E5C
0
0


0.0
0.0

9
A1
F5A
0
0


0.0
0.0

10
A1
F5C
0
0


0.0
0.0

11
A1
G5A
0
0


0.0
0.0

12
A1
G5C
0
0


0.0
0.0

13
A1
H5A
0
0


0.0
0.0

14
A1
H5C
1
0

MD100
4.2
1.6
Tremolite
15
A1
H5C
0
1
CDQ
MF
4.2
0.2
Tremolite
16
A2
E4C
0
0


0.0
0.0

17
A2
F4A
0
0


0.0
0.0

18
A2
F4C
0
0


0.0
0.0

19
A2
G4A
0
0


0.0
0.0

20
A2
G4C
0
0


0.0
0.0

21
A2
H4A
0
0


0.0
0.0

22
A2
H4C
0
0


0.0
0.0

7 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
23
A2
F3C
0
0


0.0
0.0

24
A2
F3A
0
0


0.0
0.0

25
A2
E3A
0
0


0.0
0.0

26
A2
C3A
0
0


0.0
0.0

27
A2
C3C
0
0


0.0
0.0

28
A3
C4A
0
0


0.0
0.0

29
A3
E4A
0
0


0.0
0.0

30
A3
E4C
0
0


0.0
0.0

31
A3
F4A
0
0


0.0
0.0

32
A3
F4C
0
0


0.0
0.0

33
A3
G4A
0
0


0.0
0.0

34
A3
G4C
0
0


0.0
0.0

35
A3
H4A
0
0


0.0
0.0

36
A3
H4C
0
0


0.0
0.0

37
A3
H4D
0
0


0.0
0.0

38
A3
H4B
0
0


0.0
0.0

39
A3
G4D
0
0


0.0
0.0

40
A4
C4A
0
0


0.0
0.0

8 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
41
A4
C4C
0
0


0.0
0.0

42
A4
E4A
0
0


0.0
0.0

43
A4
E4C
0
0


0.0
0.0

44
A4
F4A
0
0


0.0
0.0

45
A4
F4C
1
0

MD100
11.3
6.0
Tremolite
46
A4
F4C
0
1
ADQ
MF
3.4
0.3
Tremolite
47
A4
G4A
0
0


0.0
0.0

48
A4
G4C
0
0


0.0
0.0

49
A4
H4A
0
0


0.0
0.0

50
A4
H4C
0
0


0.0
0.0

51
A4
H4D
1
0

MD 100
3.1
1.4
Tremolite
52
A4
H4D
0
1
ADQ
MF
1.5
0.2
Tremolite
53
A4
H4B
0
0


0.0
0.0

54
A4
G4D
0
0


0.0
0.0

55
A4
G4B
0
0


0.0
0.0

56
A4
F4D
0
0


0.0
0.0

57
A4
F4B
0
0


0.0
0.0

58
A4
E4D
0
0


0.0
0.0

9 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
59
A4
E4B
0
0


0.0
0.0

60
A4
C4D
0
0


0.0
0.0

61
A4
C4B
0
0


0.0
0.0

62
A4
E5A
0
0


0.0
0.0

63
A4
E5C
0
0


0.0
0.0

64
A4
F5A
0
0


0.0
0.0

65
A4
F5C
0
0


0.0
0.0

66
A4
G5A
0
0


0.0
0.0

67
A4
G5C
0
0


0.0
0.0

68
A4
H5A
0
0


0.0
0.0

69
A4
H5C
0
0


0.0
0.0

70
A5
E4A
0
0


0.0
0.0

71
A5
E4C
1
0

MD100
2.9
0.8
Tremolite
72
A5
E4C
0
1
ADQ
MF
2.9
0.3
Tremolite
73
A5
F4A
0
0


0.0
0.0

74
A5
F4C
0
0


0.0
0.0

75
A5
G4A
0
0


0.0
0.0

76
A5
G4C
0
0


0.0
0.0

10 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-A1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
77
A5
H4C
0
0


0.0
0.0

78
A5
H4D
0
0


0.0
0.0

79
A5
H4B
0
0


0.0
0.0

80
A5
G4D
0
0


0.0
0.0

81
A5
G4B
1
0

MD100
7.7
4.5
Chrysotile
82
A5
G4B
0
1
CM
MF
2.7
0.1
Chrysotile
83
A5
F4D
1
0

MD 100
3.1
2.6
Chrysotile
84
A5
F4D
0
1
CM
MF
1.2
0.1
Chrysotile
85
A5
F4B
0
0


0.0
0.0

86
A5
E4D
0
0


0.0
0.0

87
A5
E4B
0
0


0.0
0.0

88
A5
C4D
0
0


0.0
0.0

89
A5
C4B
0
0


0.0
0.0

90
A5
C5A
0
0


0.0
0.0

91
A5
C5C
0
0


0.0
0.0

92
A5
E5A
0
0


0.0
0.0

93
A5
E5C
0
0


0.0
0.0

94
A5
F5A
0
0


0.0
0.0

11 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-001A RUN #11-ACD-ASB-01 06/25/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID:
07-21-08E-1-A1-5

TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
95
A5
G5A
1
1
NAM
F
8.3
0.6
Non-Regulated Amphibole
96
A5
G5C
1
0

MD100
6.4
2.6
Tremolite
97
A5
G5C
0
1
ADQ
MF
6.4
0.3
Tremolite
98
A5
H5A
1
0

MD 100
7.0
5.1
Actinolite
99
A5
H5A
0
1
ADQ
MF
3.6
0.4
Actinolite
100
A5
H5C
0
0


0.0
0.0

101
A5
H5D
0
0


0.0
0.0

102
A5
K4A
0
0


0.0
0.0

Totals: 9	9
TEM Microscope Documentation
Accelerating
	Instrument	*Magnification Voltage Calibration Date	
TEM 2/D686	19880x 100 KeV 9/30/2008
*Magnification = Calibrated screen magnification at 15,000X. For ISO Method 10312 the calibrated screen magnification is at 20,000X
12 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
94
1.0
2.0
2
0
0.0027
< 0.0013
0.0013
0
< 0.0083
Asbestos 5.0 - 10.0 (b)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Asbestos >10.0 (c)
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
Total Asbestos
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
Forsterite 0.5 - 5.0 (g)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite5.0 -10.0 (h)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite > 10.0 (f)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Forsterite
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary >5.0 (e)
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
Primary 0.5 - 5.0 (d)
94
1.0
2.0
2
0
0.0027
< 0.0013
0.0013
0
< 0.0083
PCME
94
1.0
1.0
1
0
0.0013
< 0.0013
0.0013
0
< 0.0060
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
1
B1
C4C
0
0


0.0
0.0

2
B1
E4A
0
0


0.0
0.0

3
B1
E4C
0
0


0.0
0.0

4
B1
F4A
0
0


0.0
0.0

13 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
5
B1
G4D
0
0


0.0
0.0

6
B1
G4B
0
0


0.0
0.0

7
B1
F4D
0
0


0.0
0.0

8
B1
F4B
0
0


0.0
0.0

9
B1
E4D
0
0


0.0
0.0

10
B1
E4B
0
0


0.0
0.0

11
B1
C4D
0
0


0.0
0.0

12
B1
E5A
0
0


0.0
0.0

13
B1
E5C
0
0


0.0
0.0

14
B2
C4A
0
0


0.0
0.0

15
B2
C4C
0
0


0.0
0.0

16
B2
E4A
0
0


0.0
0.0

17
B2
E4C
0
0


0.0
0.0

18
B2
F4A
0
0


0.0
0.0

19
B2
F4C
0
0


0.0
0.0

20
B2
G4A
0
0


0.0
0.0

21
B2
G4C
0
0


0.0
0.0

22
B2
H4A
0
0


0.0
0.0

14 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
23
B2
H4C
0
0


0.0
0.0

24
B2
H4D
0
0


0.0
0.0

25
B2
H4B
0
0


0.0
0.0

26
B2
G4D
0
0


0.0
0.0

27
B3
C4A
1
1
CD
F
1.9
0.1
Chrysotile
28
B3
C4C
0
0


0.0
0.0

29
B3
E4A
0
0


0.0
0.0

30
B3
E4C
0
0


0.0
0.0

31
B3
F4A
1
1
ADQ
F
1.9
0.3
Tremolite
32
B3
F4C
0
0


0.0
0.0

33
B3
G4A
0
0


0.0
0.0

34
B3
G4C
0
0


0.0
0.0

35
B3
G4D
0
0


0.0
0.0

36
B3
F4D
0
0


0.0
0.0

37
B3
F4B
0
0


0.0
0.0

38
B3
E4D
0
0


0.0
0.0

39
B3
E4B
0
0


0.0
0.0

40
B3
C4D
0
0


0.0
0.0

15 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
41
B3
C5C
0
0


0.0
0.0

42
B3
E5A
0
0


0.0
0.0

43
B3
E5C
0
0


0.0
0.0

44
B3
G5A
0
0


0.0
0.0

45
B3
G3D
0
0


0.0
0.0

46
B3
C3B
0
0


0.0
0.0

47
B3
E3B
0
0


0.0
0.0

48
B3
E3D
0
0


0.0
0.0

49
B3
C3D
0
0


0.0
0.0

50
B3
F3B
1
1
ADQ
F
14.6
0.8
Tremolite
51
B3
F3D
0
0


0.0
0.0

52
B3
G3B
0
0


0.0
0.0

53
B4
C4A
0
0


0.0
0.0

54
B4
C4C
0
0


0.0
0.0

55
B4
E4A
0
0


0.0
0.0

56
B4
E4C
0
0


0.0
0.0

57
B4
F4A
0
0


0.0
0.0

58
B4
F4C
0
0


0.0
0.0

16 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
59
B4
G4A
0
0


0.0
0.0

60
B4
G4C
0
0


0.0
0.0

61
B4
H4A
0
0


0.0
0.0

62
B4
H4C
0
0


0.0
0.0

63
B4
H4D
0
0


0.0
0.0

64
B4
H4B
0
0


0.0
0.0

65
B4
G4D
0
0


0.0
0.0

66
B4
G4B
0
0


0.0
0.0

67
B4
F4D
0
0


0.0
0.0

68
B4
F4B
0
0


0.0
0.0

69
B4
E4D
0
0


0.0
0.0

70
B4
E4B
0
0


0.0
0.0

71
B4
C4D
0
0


0.0
0.0

72
B4
C4B
0
0


0.0
0.0

73
B4
C5C
0
0


0.0
0.0

74
B4
E5A
0
0


0.0
0.0

75
B4
E5C
0
0


0.0
0.0

76
B4
F5A
0
0


0.0
0.0

17 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-B1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
77
B4
F5C
0
0


0.0
0.0

78
B4
G5A
0
0


0.0
0.0

79
B4
G5C
0
0


0.0
0.0

80
B4
H5A
0
0


0.0
0.0

81
B4
H5C
0
0


0.0
0.0

82
B4
K4A
0
0


0.0
0.0

83
B5
E4A
0
0


0.0
0.0

84
B5
F4C
0
0


0.0
0.0

85
B5
G4A
0
0


0.0
0.0

86
B5
H4D
0
0


0.0
0.0

87
B5
H4B
0
0


0.0
0.0

88
B5
G4D
0
0


0.0
0.0

89
B5
G4B
0
0


0.0
0.0

90
B5
F4D
0
0


0.0
0.0

91
B5
F5A
0
0


0.0
0.0

92
B5
F5C
0
0


0.0
0.0

93
B5
G5A
0
0


0.0
0.0

94
B5
G5C
0
0


0.0
0.0

18 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-002A RUN #ll-ACD-ASB-02 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID:
07-21-08E-1-B1-5

TEM Count Details


Grid
Number of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary Total
cation
Type *
(um)
(um)
Comment
Totals: 3	3
TEM Microscope Documentation
Accelerating
	Instrument	*Magnification Voltage Calibration Date	
TEM 2/D686	19880x 100 KeV 9/30/2008
*Magnification = Calibrated screen magnification at 15,000X. For ISO Method 10312 the calibrated screen magnification is at 20,000X
19 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-003A RUN #ll-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
Analysis
Grid
Openings
Counted
Reporting
Limit
(s/mm2)
Total
Structures
(s/mm2)
Structures Counted
Total Concentration
95 % Confidence Limit
Low High
Asbestos
Non-
Asbestos
Asbestos
(s/cc)
Non-Asbestos
(s/cc)
Sensitivity
(s/cc)
Asbestos 0.5 - 5.0 (a)
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
Asbestos 5.0 - 10.0 (b)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Asbestos >10.0 (c)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Asbestos
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
Forsterite 0.5 - 5.0 (g)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite5.0 -10.0 (h)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Forsterite > 10.0 (f)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Total Forsterite
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary >5.0 (e)
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
Primary 0.5 - 5.0 (d)
94
1.0
3.1
3
0
0.0040
< 0.0013
0.0013
0
< 0.011
PCME
94
1.0
< 1.0
0
0
< 0.0013
< 0.0013
0.0013
0
< 0.0060
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
1
CI
C4B
1
0

MD100
2.5
2.0
Tremolite
2
CI
C4B
0
1
CDQ
MF
1.6
0.4
Tremolite
3
CI
F4C
0
0


0.0
0.0

4
CI
G4A
0
0


0.0
0.0

20 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-003A RUN #ll-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
5
CI
G4C
0
0


0.0
0.0

6
CI
H4A
0
0


0.0
0.0

7
CI
H4C
0
0


0.0
0.0

8
CI
H4D
0
0


0.0
0.0

9
CI
H4B
0
0


0.0
0.0

10
CI
G4D
0
0


0.0
0.0

11
CI
G4B
0
0


0.0
0.0

12
CI
F4D
0
0


0.0
0.0

13
CI
F4B
0
0


0.0
0.0

14
CI
E4B
0
0


0.0
0.0

15
C2
G4A
0
0


0.0
0.0

16
C2
G4C
0
0


0.0
0.0

17
C2
H4A
0
0


0.0
0.0

18
C2
H4C
0
0


0.0
0.0

19
C2
H4D
0
0


0.0
0.0

20
C2
G4D
0
0


0.0
0.0

21
C2
G4B
0
0


0.0
0.0

22
C2
F4D
0
0


0.0
0.0

21 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-003A RUN #ll-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
23
C2
F4B
0
0


0.0
0.0

24
C2
E4D
0
0


0.0
0.0

25
C2
E4B
0
0


0.0
0.0

26
C2
C4D
0
0


0.0
0.0

27
C2
C4B
0
0


0.0
0.0

28
C3
C4A
0
0


0.0
0.0

29
C3
C4C
0
0


0.0
0.0

30
C3
E4A
0
0


0.0
0.0

31
C3
E4C
0
0


0.0
0.0

32
C3
F4A
0
0


0.0
0.0

33
C3
F4C
0
0


0.0
0.0

34
C3
G4A
0
0


0.0
0.0

35
C3
G4C
0
0


0.0
0.0

36
C3
H4A
0
0


0.0
0.0

37
C3
H4C
0
0


0.0
0.0

38
C3
G4D
0
0


0.0
0.0

39
C3
G4B
0
0


0.0
0.0

40
C3
F4D
0
0


0.0
0.0

22 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-003A RUN #ll-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
41
C3
F4B
0
0


0.0
0.0

42
C3
E4D
0
0


0.0
0.0

43
C3
E4B
0
0


0.0
0.0

44
C3
C4D
0
0


0.0
0.0

45
C3
C4B
1
1
ADQ
F
2.2
0.2
Actinolite
46
C3
C5C
0
0


0.0
0.0

47
C3
E5A
0
0


0.0
0.0

48
C3
E5C
0
0


0.0
0.0

49
C3
F5A
0
0


0.0
0.0

50
C3
F5C
0
0


0.0
0.0

51
C3
G5A
0
0


0.0
0.0

52
C3
G5C
0
0


0.0
0.0

53
C3
H5A
0
0


0.0
0.0

54
C3
H5C
1
1
ADQ
F
4.0
0.2
Actinolite
55
C3
F3A
0
0


0.0
0.0

56
C3
F3C
0
0


0.0
0.0

57
C3
E3C
0
0


0.0
0.0

58
C4
C4A
0
0


0.0
0.0

23 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-003A RUN #ll-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
59
C4
C4C
0
0


0.0
0.0

60
C4
E4A
0
0


0.0
0.0

61
C4
E4C
0
0


0.0
0.0

62
C4
F4A
0
0


0.0
0.0

63
C4
F4C
0
0


0.0
0.0

64
C4
G4A
0
0


0.0
0.0

65
C4
G4C
0
0


0.0
0.0

66
C4
H4A
0
0


0.0
0.0

67
C4
H4C
0
0


0.0
0.0

68
C4
H4D
0
0


0.0
0.0

69
C4
H4B
0
0


0.0
0.0

70
C4
G4D
0
0


0.0
0.0

71
C4
G4B
0
0


0.0
0.0

72
C4
F4D
0
0


0.0
0.0

73
C4
F4B
0
0


0.0
0.0

74
C4
E4D
0
0


0.0
0.0

75
C4
E4B
0
0


0.0
0.0

76
C4
C4D
0
0


0.0
0.0

24 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter:
Effective Filter Area:
Grid Opening Size:
MCE Filter, ,45um
1320 mm2
0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-003A RUN #ll-ACD-ASB-03 06/26/08 07/21/08 1000	1 08/11/08 CG 07-21-08E-1
@12:00 am @5:51 pm	@9:06 pm
GridBoxID: 07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
77
C4
C4B
0
0


0.0
0.0

78
C4
C5A
0
0


0.0
0.0

79
C4
C5C
0
0


0.0
0.0

80
C4
E5A
0
0


0.0
0.0

81
C4
E5C
0
0


0.0
0.0

82
C4
F5A
0
0


0.0
0.0

83
C4
F5C
0
0


0.0
0.0

84
C4
G5A
0
0


0.0
0.0

85
C4
G5C
0
0


0.0
0.0

86
C4
H5A
0
0


0.0
0.0

87
C4
H5C
0
0


0.0
0.0

88
C5
C4A
0
0


0.0
0.0

89
C5
C4C
0
0


0.0
0.0

90
C5
E4A
0
0


0.0
0.0

91
C5
E4C
0
0


0.0
0.0

92
C5
F4A
0
0


0.0
0.0

93
C5
F4C
0
0


0.0
0.0

94
C5
G4A
0
0


0.0
0.0

25 of 32
-------
I
ANALYTICAL RESULTS
Client: ARCADIS
Client Reference No.: BURN PROJECT-NEW ORLEANS
Work Order No.: A0810163
Analytical Method
Sample Type
Date Received
Report Date:
TEM -ISO 10312 Method, 1995 (modified)
Air
10/22/2008 10:17:28 AM
11/6/2008 9:11:27 AM
Date: 06-Nov-08
Filtration Filter: MCE Filter, ,45um
Effective Filter Area: 1320 mm2
Grid Opening Size: 0.0104 mm2
Lab Sample
Client Sample
Date
Prep
Air Dilution
Analysis
Grid Box
No.
Identification
Sampled
Date
Vol. (L) Factor
Date
Analyst Identification
A0810163-003A RUN #1 l-ACD-ASB-03
06/26/08 07/21/08
@12:00 am @5:51 pm
1000
08/11/08
@9:06 pm
CG
07-21-08E-1
GridBoxID:
07-21-08E-1-C1-5
TEM Count Details


Grid
Slumber of Structures
Identifi-
Structure
Length
Width

Rec
Grid
Opening ID
Primary
Total
cation
Type *
(um)
(um)
Comment
95
C5
G4C
0
0


0.0
0.0



Totals:
3
3





Instrument
TEM 2/D686
TEM Microscope Documentation
Accelerating
*Magnification Voltage Calibration Date
19880x 100 KeV 9/30/2008
'Magnification = Calibrated screen magnification at 15.000X. For ISO Method 10312 the calibrated screen magnification is at 20.000X
(a):	Asbestos Structure >= 0.5 um to 5.0 um
(b):	Asbestos Structure >5.0 um to 10.0 um
(c):	Asbestos Structure >10.0 um
(d)	:Primary Structures >= 0.5 um to 5.0 um
(e):	Primary Structures >5.0 um
(s/cc):Structure(s)/cubic centimeter of air.
<: Result is less than the limit of detection.
:No Results (Air Volume is 0)
: Format = "AA ###" where "AA" is the ISO pneumonic for the structure type.
"###" represents the number of structures in each of the Asbestos Structure criteria
noted in (a) - (c). Quantification greater than 9 is denoted with a "+" symbol.
mm2: square millimeter
s/mm2: Structures per square millimeter
um: micrometer
Analyses) Name/Date:
Okt&Jfct
11/6/2008
26 of 32
-------
RTI
INTERNATIONAL
3040 Gomwallis Road e PO Box 12194
Research Triangle Park, NO
27709-2194 • USA
Telephone: 919 541-7470
Fax: 919 541-7386
osc@rti.org
MEMORANDUM
To:

I f"' /' i
From: Owen S. Crankshaw
Date:
Ly/ x / / £- =->

ft- (" \y G i- dri1 i * f H, M J> y
ry #>
/ f '
/}rc^.c( /,j
/
CiA/' f~i"' ,
---J
f) e.A J € '£> * J"-' !

(s&Vi t > (' y fi wv Gs? "
C- /w g_
/' /¦ V iP V<- f*£\ o£_. „X,_ /f P
<£- yC^r/'-'l c
/ .. ' ,
frit 'j~& 
-------
To	Kelly Smith/USA/VERITAS@VERITAS
cc	Kuntal Parikh/USA/VERITAS@VERITAS
bcc
Subject	Fw: additional grid counting on asbestos samples
Kelly:
RTI is sending us several samples back so we can	analyze additional grid openings on several samples.
See me when you get the RTI package-.
Alan M. Segrave, P.G.
Division Manager, Laboratory Services
v <	Bureau Veritas Worth America, Inc.
" '	Health, Safety and Environmental Services
3380 Chastain Meadows Parkway, Suite 300
Kennesaw. GA 30144
Office: 770.499.7500
BWgjgBl Fax: 770.499.7511
alan.searave@us.bureauveritas.com
mvw.us.bureauveritas.com
Alan Segrave/USAA/ERITAS
i0/2i/2008 04:04 PM

If you would like to fill out a customer satisfaction survey please follow this link:
http://www.survcvmonkev.com/s.aspx?sm=AJS6tpD91zrdWds94qFa4Q 3d 3d
Tills m&tcrisil is confidential and intended solclv for tTie person to wliom it is addressed If* tins is received in error plense conto
the number provided.
	Forwarded by Alan Segrave/USA/VERITAS on 10/21/2008 04:03 PM —
"Crankshaw, Owen S."
	To Alan Segrave/USA/VERITAS@VERITAS
J» 10/21/2008 03:52 PM	cc
Subject FW: additional grid counting on asbestos samples
FYl. Package arriving tomorrow.
Regards --
O.
	Original Message	
From: Crankshaw, Owen S.
Sent: Tuesday, October 21, 2008 3:45 PM
To: 'Lemicux.PaulSepamail.epa.gov'
Subject: RE: ciddil.ional grid counting on asbestos samples
BV was snipped the grids the" prepped plus the original filters they
used for prep. In case they cannot get enough grid openings from the
prepped grids, they can always make new ones from the filters.
Owen
	Original Message	
From: Lemieux.Paal0epamail.epa.gov [mailto:Lemieux.Pan 1 Sepama1], .epa.gov]
Sent: Tuesday, October 21, 2008 3:4.3 PM
To: Northeim, Coleen M.
Cc: Miller.Andy@epamail.epa.gov; Miller.AndySepamail.epa.gov;
gstephensonHarcadis-us.com; Wilmoth.Rogergepamail.epa.gov;
-------
Juhdnnes.Lee@arcadis-us.com; Wood.Joe@epamail.epa.gov; Crankshaw, Owen
S. ; Drees.Lauren@epamail.cpa.gov; Olexsey.Bob@epamai~ . epa . gov
Subject: RE: additional grid counting on asbestos samples
Thanks — docs that include abcuc 67 grids per sample which was about
what Roger' figured we could do for 1000?
Paul M. Lsmieux, PhD
OS EPA Office of Research and Development
NHSRC/DCMD
Disposal Program Area Lead
919-541-0962"
919-5 41-0496 fax
513-300-9958 cell
lemieux.paul@epa.gov
29 of 32
-------
Bureau Veritas N»rth America, Inc	INTERNAL CHAIN'OF-
3380 Cliastain Meadows Parkway
"""•	CUiTQDf IEC0II
Sent To:	COC: 1141
RTI	TEL: (912) 954-1747
3040 Cornwallis Road/Bldg 6	FAX: !8-A«g-08
Research Triangle Park, NC 27709	Client ID RT! BY: KS
Sample !D	Client SD	Matrix	Collection Date Bottle iype
A0807141-005A
COMPOSITE ASH SAMPLE
Bulk
6/26/2008

A0807141-004A
COMPOSITE ASH SAMPLE
Bulk
6/26/2008

AD807141-003A
RUN #!l-ACD-ASB-03
Air
6/26/2008

A0807141-002A
RUN #il-ACD-ASB-02
Air
6/26/2008

A0807141-001A
RUN #II-ACD-ASB-01
Air
6/25/2008


Cr9i
'Lj- L

S"a'hn//ej
n,\r ke^Z ^
/f'ir
f j • a

5/ >s5;'
<*7
>c
" /?
"7*
Comments:
Relinquished by: (Signature)
Received by: (Signature)
Ma
i rpt
30 of 32
-------
ARCADIS
REQUEST FOR PURCHASING ACTION / PURCHASE ORDER®
Database Compliant
1072007
m
Bill to: ARCADIS, 4915 (Prospectus Drive, Suite F, Durham, NC 27713
VENDOR
Bureau Veritas
PHONE
(770) 499-7500
CONTACT
Alan Segrsve
(770) 499-7511
EMAIL 1 WEBSITE
www.us.bureauveritas.corn
PROPOSED VENDOR / MANUFACTURER
MAMUFACT. SUBSTITUTION OK?
r YES
Te\p!d
NO*
in Special instructions/ConrTients
REOUISmONER
DATE
Gene Stephenson
10/21/2003
APPROVAL (SIGNATURE)
DATE


OLS APPROVAL
>»» DATE REQUIRED ««<

10/31/2008
Shipto:
DROP SHIP
ARCADIS
4915 Prospectus Drive
Suite F
Durham. NC 27713
(919) 544-4535
EPA
109 TW Alexander Drive
Building E Loading Dock
RTP, NC 27711
PURCHASE ORDER NUMBER
KB64S02
CONTRACT DATE
TOTAL EST. COST
10/22/2008
$1,216,00
PAGE PACES
CONTRACT#
1 OF 1

SPECIAL INSTRUCTIONS/COMMENTS
e-mail results to: gene.stephenson@arcadis-us.com
FOR OFFICIAL USE ONLY
Prepay and Add
ARCADI
tSk
ITEM
PROJECT
PHASE
TASK
% SPLIT
DESCRIPTION
PART NUMBER
QTY
UNIT
UNIT PRICE
EXT
SHIP 1
SHIP?
SHIP 3

RN007160
0G01
0Q004

ISO 10312 for abesios, sensitivity=0.G05 str/cc

201
ea
$5.00
$1005.00








analyze 67 additional grid openings on each of 3 samples returned













from RTI













































































I


























$1,005.00



VENDORS; To avoid delays In payment, please confirm price and delivery by FAX or email.
>
73
O
>
2
cft
~
EPA CUSTODIAN
SAFETY
APPROVAL DATE
UN-PLANT DESTINATION!
Gene Stephenson
COMTACT
Rick Bullock
BUYER'S SIGNATURE
PHONE: (S19) 544-4535
FAX: (919) 544-5690
EMAIL: DurhsmPurchasirsg@arcadis-us.com
To print with Terms
and Conditions, select
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1.1 This Purchase Order becomes a contract when (T)	signed"
acknowledgement is received by ARCADIS ("Purchaser") or (2) when delivery
ail goods, equipment, materials and/or installation seivices purchased or
delivered hereunder to be merchantable. fit for the purpose intended, free
from defects in material or workmanship, and in conformance strictly with the
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K3
-------
919 544 5690
ARCADIS Durham
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2/2
32 of 32
-------
Client Plant Name; AkCAfHs CD,
A;>ulyvt: I INI
Analysis Mfihotl: jfPAJU iIilv'5.
Sample Malm S. t (mipmients:
In i - i ": taken lo eoniinti u'lusiwl results. A No note run deviations from standard aualM'^al
procedures, together v. ith justi Heal ion anil possible al'feei on results SpeoilS samples when applicable.}
No modifications to EPA Method 6 analytical procedure were made.
See Data Sheets for individual sample descriptions.
Confirmation of Data Review:
()A Uifieei Sien.ifi,1"- '	JLi,	'' ¦		Date
-idh Pn.m N< tnei . i ab oll\ Otlicei i
Date Rec'd in hh-_ • >_/_! yufi
Date of Anai^i*: 	t-J'm)S
AnalyK'ts.): f ihei ibie P.nt.t nl.ife
-------
Resolution Analytics, Inc.
Specialists in High Pei romance Liquid € htomamgraph)
Repori Summary
RFA#:
EPA Method 5
Filterable
Sample m
Particulate
Acetone Blank
0.2 mg (100 mL)
I-ACD-M5/26A-FB
5,1 mg
I-ACD-M5/26A-1
138.0 mg
1-ACD-M5/26A-2
87,4 mg
II-ACD-M5/26A-1
115,1 nig
1I-ACD-M5/26A-2
125.2 mg
U-A( D-M5/26A-3
101.1 mg
-------
te Rso
fiirn Ni
Filter Contains
PARTICULATE SAMPLING LABORATORY RESUL78
.p, , ;;n
07/15/03	Pegs 1 of 3
Pile Pathway: C' 1 \ > >P / /I
Pate i
07/29 | 8f¥L
RQ-5177
4 ') (1 "if bA £1
503
Date !mi
D&is
Date

07/29
07/28
Tarn Wt, g
RINSE SAMPLE WT.,
BNL @
BNL
SO ml)
f. 7694
1.75§5
1010$
ml)
07/29
mm
80
rM> n g
Rinse- Cdlch, mg.
Rinse Blank Residue, mg,
Met Rtt se C mj
F/L TERABLE PARTICULA TE, mg.
127.5
10.6
10,5
138.0
Hi 5
6.0
r w
f?.4
Blank B&8H&I #
mo.
1440
Tarn vw,,
Residue,
Volume
ly. mg/mt
, mg/mg
- Limit mg/mg
mg.
mg,
ml,
Visual Inspection of Fitters
r,un ID
L^'or
Texture:
,M m-t
R^hUS'^C^h yi
Visual Inspection of Rinses
¦xt.lti tU
f ))'<"
Textuw:
Foreign Matter
i oi y
"Am <
WWi
BR
FILM
NONE
MEDIUM
WN
BLACK
..J
hIL H
l-AC-t
V26A~0t
3.6248
3.6240
0.0008
4$
Q.2
0.6
5.1
.. 1 I n* fArf
M« r w .>;
WH/7E
N^Nt
LOW
WHITE/BROWN
i-lL l\'1
NONE
Mcn'iw
Mi P Mu
£RQi\'N
G/M/Vf (LA FED
NONL
LOW
Miscellaneous w I
ls:
Pririlmg Date'
as-Jui-oB
01:03 PM
-------
	PARTICULATE SAMPLING LABO VY *ESIJL7S
JSEPA / RTI	»«
Date Received: 07/15/08
P%iW Nurturr
himarne
CW'KKW ."Ji'/i
T#
Pais 1 Init
arm bnl
2135
07/2 3
Baggie Tars Wi, g,
f nu T,i'. Ht tj
/->/ TLP "<\Mm
er#
Date
ing
1551 __

Date
_
07/29
07/28
rare 1*1. g. f
RINSE SAMPLE WT„ 3
BNL m
BNL
25 ml)
' ^ ' t» * %
i r'^J ( nf) ,	
3,5094
3 5093
r-'.v @
I '' ml) _

FtitOl Cc?fr ft, WQ
R/nse Catch, mg.
Rinse Bkmk R&skhw, rng.
Net Rhis*. Cjtch, my.

. 0
3.2
0 0
V-
i}3 S
f f. ?
tl 1
11 t>

91.«
8.8
S.I
9.5
PI TERABLB PARmLAlB, mg.

115 1
125 Z

101.1








Visual inspection o f Filters \





Ron (L' I'-a^D
1. .."OiW i.3
Ff-1 r // e ^ '
Foreign Matter;
Ri i ill « C'> : Ij>

II ncr tei*2i>A i3. /I 4
UlaCI
J rail j
Nl Wsh








Visual Inspection of \



Legend: in) - hnj wr-
n
1
r&xiw&.
A/ V ' f
'jK m m;


NOA'fc
M f //M4
hh «,>!! rt» nfs N*>h ,
Pnnjiny Oats:
-------
RE£G*-Nt Si ANK l AliOR* TORY RESULTS (Version 04,28,92)
is: US EPA / RTI
_ i ' )	' >	3 of 3	fife Pathway:
Sample KMSonMwr#	1445
Oat® 1 Iffl"?
07/28 a«t
07/25 BML @
( 100 ml)
-------
PARTICULATE WORKSHEET
GHENT SfCad,k' " ' ' - '•	kfa #
ANALYST fML	METHOD	PATE
Run #
Filter
acetone Rinse
NOZZLE
Cyclone
McCl.2	
Ohlorofo
Tnutiw		
sm/Ethes 		
Of H2D !MP(NSES

CONT,#
Fi£_ref? #
Tare Wt^g)
Cpnt.#
vauiwU
Cdnt.#
VOL.(Ml!
Cdnt,#
voi—Imu
Cnn' ' #
VP La'MU
r~ ™~
i

- , i


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; - ' : 1


r
ml
t IF/






_



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•







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!
1










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i





-------
fir cadis
CHAIN OF CUSTODY RECORD
IZ1E Prospectus Drive
MC 2"713	F',eSjhr
tzz_





Samples collected by; 	
(signature) 		Date: 		l ate nr iraed
Samples	.¦ 				
>¦ i	Data:
Sarrtf
-------
Arcadis
4915 Prospectus Drive
Ouf.irr., ii'Z 2 '"13
544-<35 35
CHAIN OF CUSTODY RECORD
Page _
of
ID
3«.tc ! SanpV inscription
OuHtCied j
Number of
Containers
Analyses Required
~ f


RUN # !f-ACD-pml0-O1
^ 'CviC -V 1
1

RUM # iS-ACD-pnnlO-Oi
06/25/08



Ac.qr ts
mU$ if-ACO-pmlO-Ot
06/25/08




RUN f H-AGD-pm10-01
06/25/08



¦Aeiur.-s
RUN#IMCI>pm«H>1
MS/08


,
digits
RUN # »-ACD-pfll1M1
06/25/08



iVeignts
RUN#ll-ACD-pm10-01
06/25/08
Km*. J2

1
Aeigfits
RUN # lI-ACD-emlO-OI


1
weights
ROW # i!-ACD-pm10-01


1
weights

















1
weights


1
weights


1
weights






•
/ >-nlis-


i
wisiqhis




Samples collected by:
(signature)
Samples "clwqursned by;
«,HrC nature)
Samp
5-3' 1 U'*I
Date:
Date
Dale shipped;
-------
Arcsdis
A-»15 Prospectus Drive
Dirt+sm, NC 27713
:91P.;-S44-4636
CHAIN OF CUSTODY RECORD
spjiorr
•ge #:
ResponsibleAr-ig- Far,
Page.
jSaninte 10
Data
Collected
Sample Description
Number of
Containers
Analyses Required
!





RUN # ii-ACD-omlO-03
08/28/08


<
WeiCibi
[run # lf-ACD-pmi0-03
06/28/06


1

IrUM # J!-ACn-pmi0-03
T- s T»


,

j RUN. # lM.CD-pmlO-03




[RUM# l)-ACP-wniO-Q3
06/26/08



V, til.*
i-
IftUN# fl-ACD-pmt0»03
06/26/08


1
¦weight
[RUM # Sj-ACD-eml0-03
06/26/08


1
weight
(run # il-ACO-pmlO-03



i
weiahi
IsUNM-ACD-pmlO-OS | £»l28/0i


1
weight










T
-------
Client/Plant Name: \'<» \Dtlicet ^iL'iuUiiv
-5 , ^"
I 'etc 	, ' / '' -J
t" i Huae Netrut I ab 
-------
Specialists in High Performance Liquid C'luvmatogrnpbs	\/
pmia Report Summary MM
RFA#: 080715
Sample id
Filterable
Particulate
Organic
Particulate
Inorganic
Particulate
Total
Particulate
Acetone Blank
Mi;Cl2 Blank
H20 Blank
0.2 mg (100 nil)
0.3 mg (90 ml)
0.5 mg (100 ml)

FIELD BLANK
1,9 nig
0.9 mg
0.8 mg
3.6 mg
EI-ACD-PM2.5-1
77.8 trig
2.4 mg
84.1 mg
86.5 mg
R1-ACD-PM2.5 -2
54.7 nig
1.0 rag
20.0 mg
21.0 rag
R2-ACD-PM2.5 -1
35.3 tug
1,3 mg
19.8 mg
21.1 nig
R2-AC D-PM2.5 -2
46.8 rug
3.8 mg
21.7 mg
72.3 mg
R2-ACD-PM2.5 -3
17.3 nig
0.6 mg
29.6 mg
47.5 mg
Sample m
< lOflM
Particulate
> 10 JIM
Particulate
Filterable
Particulate

FIELD BLANK
1.9 Olg
0.0 mg
1.9 mg

R1-ACD-PM2.5 -1
56.U nsg
21.8 mg
77 J mg

R1-ACD-PM2.5 -2
46.1 nig
8.6 nag
54.7 mg

R2-ACD-PM2.5-1
26,1 tug
9.2 mg
353 mg

R2-AC D-PM2.5 -2
30 6 tug
16.2 mg
4<\8 mg

R2-ACD-PM2.5 -3
15 6 mg
1.7 Rig
17.3 mg

-------
Resolution Analvikx Inc. A
Specialist in High Perk«r.»sncc Liquid C}irwt«'it«>u!ap»iv
V
Report Summary

RFA#:

Stage jo
ffi- ACD - PMJO -/

Stage 0
3.5 mg

Stage 1
0.8 mg

Stage 2
1.3 mg

Stage 3
3.6 mg

Stage 4
3.5 nig

Stage 5
6,4 mg

StACE 6
9.5 mg

Stack 7
19.7 mg

Solid Filter
141.9 mg

Prec.tttkr Rinse


Stage id
Ml- ACD - PM10 -2

Stage 0
0.9 mg

Stage I
0.1 mg

Sl4€E 2
2 J mg

Sr\(.n 3
1.2 mg

Stage 4
3.1 mg

STACiE 5
4.7 my

Stage 6
7.3 mg

Stack 7
8.5 mg

Solid Filter
St>.c> nig

Precutti-.r Rfnse


-------
Resolution Aiw y ncs. Inc.
Specialists in High Performance Liquid Chromatography
V

Report Summary

KFA#:
Stage w
R2-ACD-PM10-J
Stage 0
1.2 mg
Stage !
1.0 mg
Stage 2
33 mg
Stage 3
3.1 mg
Stage 4
4.4 mg
Stage 5
1 2 mg
Stage §
(>.3 nig
Stack 7
12.8 tog
Solid Filter
85.9 mg
Pre< i iter Rinse

Stage id
R2~ ACD - PM10 -2
Stage II
2.0 mg
Stage I
3.2 mg
Stage 2
5.3 mg
Stages .
2.0 mg
Stage 4
1.4 mg
Stage 5
4.8 mg
Stage 6
3.7 mg
Stage 7
3.1 nig
Solid Filter
38.6 mg
Prix ! iter Rinse

-------
Resolution Analytics. Inc.
Specialists in High PerfWiiwnce Liquid C'lironwto^raphy
Report Summary
RFA#:

Stage m
R2-ACD-PM10-3
Stack 0
17.8 mg
Stage I
2.8 nig
Stage 2
3.7 mg
Stage 3
1.9 tag
Stage 4
1.4 mg
Stage 5
3.1 rag
Stage 6
10.0 mg
Stack 7
20.7 mg
Solid Filter
83.7 mg
Precutter Rinse

Stage m
ACD-PM10-FB
Stagf. I)
0.2 rag
Stage 1
0.1 mg
Stage 2
0.6 mg
Stage 3
1,4 mg
Si age 4
1.1 mg
Stage 5
Li mg
Stage 6
1.6 mg
Stage ?
0,7 nig
Solid Filter
2,5 mg
Pbechttkr Rinse

-------
	 SUMMAR Y OF PARTICLE SIZING ANALYSIS
pi -I i nL K // USt r H	t i
ill / ' ~ V '/i ut . (V',	Fitefidhie.
M,f 1 • v i t1 I 'u f1	/ Vio I a! 6	Fli® Pjth f •' U' ^li^\
Sample MenUftmtmn
' Run Number
•FB
Samph
briqqie Wl q
I'lhfUt I irr It' .j
I «MtF iY! <<
i>atriple klenljtmation
Init Date
Rinse
ml)
If-ft | Dritft
BNL 07/29
It RA-68S
Init I Date
3 5474
843

07/29 3 t^'Jv
it- RB-8BS
Date

614
Stage 4
3?
Date
07/2
# RASBS
I lie
1311
m.wj
pl/tH # .4 TrtO" W< t/
SM'.tLL H¦! ti	
* tinph-• I lentificahori
L<£ugi' > I ti/r Wt 11
hilti'i # S Tute W
S4/W-U Wt "W
f RT G8o
Init ; Dalt«
BNL 07/29
# R4-638
J »_W
4 J 867
0,1426
OiaIH
Ja3fc'
"
? "I'fM
_ I <><567
0.1606
'J 00 i if
0,0
ERR
ERR
ir :*w
u j.'>sc
0.001 J
?'J1
Date _ oYayr 7
07/2.9
J Jo /6
# RB-6B8 (J I-I2J
i) a'07
07/29
# R6-6S7
3 4504
_ 0J MC
0.0011
150b
jrirt-up
07/2
3.9291
3.7362
# SF-670	-npj
f) "i ;
Wnf-" Am] "omnMil!
STAGE 0 CA TCH, mg.	I) 2
STAGE 1 CATCH, mg.	01
stage i catch, ma.	oo*
STAGE 3 CATCH, mg.	14
STAGE 4 CATCH, mu,	i<
STAGE 5 CATCH, mg.	11
STAGE 6 CATCH, mg.	1 ti
STAGE 7 CA TCH. mg,	0 7
BACK-UF FILTER CATCH, m>(	7 5
bf-.R
Pfinftng D#e
0*S*WI
-------
SUMMARV OF PARTICLE SIZING ANALYSE
¦ i	Rli > USi-l*A
Method: PARTICLE SIZINi
Dote Rec&ived 07/15/08

0-01
Sample Identification
& Rinse Volume
Init Date
ml)
10000
7.0000
0.0000
1407
i ,11./' <*>
F ti&nsffi®: A RCA D IS
Hie Path C:UQBS\0\ARCADiS. WB1
ctor Tw.
\NDERSEN
Data..
2271
rfd,.' t
43
Daib
BaggmTarB Wt., g.
Ftf*' t \ l tir \ w a
SAMPLE WT„ g.
Sampfo Identification
i
BNL 07m
P RA 6't"
Init [Date
# RS-677 ~S 1389*
Date
07/ZU 3V47I
?4-o n, r> i;;ge
	 J
;i»J _ __
Date sLue >
C'.tfJyttthl'C Wt t)
Ft'tri >' & TVf Vtt a
SAMPLE WT, g.
Sd'jif)l-* hit Illlllftiioii
BNL arm
# RB-678
3.6414
3.4955
0.0036
1503

07/29 V 10
_ 1 fiShG
# RA-679
0,0035
t >ato
140"
0772$
# RB-B79
H.itf
BaggieTam Wt., g,
f nir.i it & Tare- W> q
S'WirtEWT g
BNL 07/29
# RA-680
3,6552
3.4852
0.160S"
0 001-5
07/29 J t
3.4694
§ RB-680
0tU9'
07/29 3.7794
¦
t SF on*!	n 'Qii
Pi!"
0,0
ERR
ERR
Notes Ana
STAGE 0 CATCH, mg.	3,5
STAGE 1 CATCH, mg	5 8
STAGE 2 CATCH, mg.	1.3
STAGS 3 CATCH, mg.	3 6
STAGE 4 CATCH, mg.	3 5
STAGE 5 CATCH, mg.	6.4
STAGE S CATCH, mg,	9.5
STAGB 1 CATCH, mg.	« 7
BACK-UP PILWR CA TCH, m(	141 it
ERR
Printing Dole
07SMJ8
Printing Time
£»;Si PM
-------
SUMMARY Of PARTICLE SIZING ANALYSIS
' ,) <«». -« Rli USf-HA
Method: PARTICLE SIZING
D	js 3 of 6
Analysis By >'fa.je Fr,t Run Number:	1-ACD-PM10-02

[nit
Date
Rinse
RFA#
Filename:
cffe Psth C:\JOBS\CMRCAD.

:cm
iii
—ifi'-L
Stogv -
BaggieTam W1.t g,
c-lri # S T,,P Wl i'
SAMPLE WT,, Q-
SztmpiB Idantificatkifl
B.Mj.neT^ie Wt u
I lit' i k ft rrtrp lA'f i
07/2.9
# RA-683
3 507/
^ 3i>TJ
0 16 tQ
'10033
07/29
# RA-682
Dale
n;/?B
* RB >}83
3 5 JI 1
3 JL il'-1
jJj '">'/
0.9028
3 S5IK'
3 7Q'jC
0 144:1
0.0047
SetmplP I'lfllllflt dltrttt
Init Date
If 14
Stage 6
Date
IU2
st„n 7
547
Date
back-up
BNL 07/29
# RA-684
STAGE 0 CATCH, mg.
STAGE ! CATCH, trig.
STAGE 2, CATCH, mg
STAGE 3 CATCH, mg.
STAGE4 CATCH, mg,
STAGE 5 CATCH, mg
STAGE S CATCH, mg,
STAGE 7 CATCH, mg
BACK-UP FILTER CATCH, my.
o?m
# RB-684
3.7056
3 o
0.1428
0.0085
07/29
# SI
4,0648
"7- ft
" 0 JO'T
0.0869

Notes And
ERR

ERH

as

0.1

2.8

1.2

3.5

4.7

7.3

8.5

16.9

ERR
Printing Oat#
07/29/1*
04:59 PM
-------
Analys"
Sample
SUMMARY Of PARTICLE SIZING ANALYSIS
KH'USBPA
Method: PARTICLE SIZING
Oats R&c&iv&tf: Q?/1$/'08
Ri n h'nenhct
•'LL'i pWl 1U-U1
I nit j Date
•f 6
r i. 0807 \
Filsnanw	,r
rll ¦ I , hi ' W'.i. tin V »5/ •!' ti/'W
ANl
! Rinse Volume:
Sample
BaggieTam Wl., g.
r Hfi >< \ ! if i W i,'
£> >KirlE 14 ' i.
, ?irjij kh tiUf,i dtiun
ml)
triit
Date
BNL 07/29
# RA-6B9
Init Date
BNL 07/29
* RB-69C
Init I Date
1440
Stage 3

Date
S'iiii/f
07/29 ? WT
	,< >£JP
# Re-688 _ i) I-I J. '
I i 00 hi
Date
	,'ihj
%ltf»
07/29 j cm!
¦i ?Jh9
# R4-697 _ _ ti 1BMI
" :/ M4-i
	pro
Date Sl^jt ,
Date
07/5
3,6600
# RA-690 _
0.0033
186
Date SlAjf '
07/2
_ 162-19
# RB-691 ~ Pit IP
oooi:
119
Date R •• h-U(>
BoiiQIflw IVr i?
riW' 11/ & f -tic Wt g
SAMt'Lt \A'[ g 	
STAGE 0 CATCH, mg.
STAGE J CATCH, mg,
STAGE 2 CA fCH, mg.
STAGE 3 CATCH, mg.
STAGE4 CATCH, mg,
STAGS S CATCH, mg,
STAGE 6 CATCH, mg.
STAGE 7 CATCH, mg.
BACK-UP FILTER CATCH, mg
ERR
1.1
1.0
3„>
3.1
4.4
1.1
9.3
12,5
85.9
07/20 1 K-5i
J "78*>
# RB-692 0 1444
0.0128
ERR
Notes And Comments:
0?/2« ¦/ I710
... dfr'tQ
# SF-671 u '.Oui
O'lS-y-)
Printing Dafe
07/i9/08
8459 PM
-------
SUMMARY OF PARTICLE SIZING ANALYSIS
r ,.(hk fin, us:-PA	-1 ,1 050715
Method: PARTICLE SIZING	FUendine:	ARCAOIS
0 i-\'t	f >F B	File F c * /(>Jr' > WCAOtz •
Anaivctt Pf' Sfa;*t hut Run fV"./r?bpf	II-ACD-PM10-Q2	U"f ivt?1	AT1
Sample Identification
Init j Date
t Volume,	{
oanrp/et fwjutiiuaitvtt
Init
Date
}

Date

Date

n,< Mif7aa 14" q
Filter # & Tam Wt„ g,
XWhi\T
BNL
#
07/29
RA-697

#
07/29
RB-697 "
4.1888
_ ¦< i>P"
it
f* IJOoJ
07/29
# RA-698
, ,1,1(0
3.833$
n |g?7
'F7>f '5;
Sample Identification
Init
Date


Date
1401
Stage 4
Date
• ———
B^qsjiuTcif l/W ih oc-?r«
07/29
# RB-700 ^

07/2
# SF-673
1 06b?
3.8276
0.2021
(}



no
ERR
ERR *-*

A/ofss A/?d



STAGED CATCH, mg.
STAGE 1 CATCH, mg.
STAGE 2 CATCH, mg,
STAGE 3 CATCH, mg.
STAGE 4 CATCH, mg.
STAGE 5 CATCH, mg.
STAGE § CATCH, mg
SI AGE 7 CATCH, mg.
back.up filter catch, mg.
ERR

2.0
3.2
5.3
2.0
1.4
4.6
3.7
3.1
38 6





Printing Date
07/29/08
Printing Time
04:59 PM
-------
SUMMARY OF PARTICLE SIZING ANALYSIS
r'^n 'v R77 • 1/SitfA
Method: PARTICLE SUING
Date Received: 07/1'§/Q8
!	By Ssauf Co: hurtihpi
Sample Identification
1 Rinse Volume:
BaggmTam Wl, g,
"f ¦'*. T"ir» M-' n
sa/WP(* H T i;
Sample hicntmcj 'ion
Biggie I are WL. g
# & Tatr h? g
sampl r wt ,1
Samph hit n"i~
0~ 'Jtl j 704J
3,5595
# R.
	Wjij_
Qjtc BtiA Uf>
d 1 gtjf r,M.» 'A't
r ;/ioi # a' I ve Wl V
MW'LtH/f (i
SMGEO CATCH, mg.
STAGE t CATCH, mg.
sraee z catch, mg,
STAGE 3 CATCH, rag.
STAGE 4 CATCH, mg.
STAGE S CATCH, mi|.
517e3£ S CATCH, mg.
STAGE 7 CATCH, mg.
BACK-UP FILTER CATCH, mg.
BNL Of,99
1l HA-704
0.0
ERR
6W
17.8
i.i?
3.7
I J)
1.4
5 f
10.0
2d 7
83.7
07/29 3.5328
3 T,(n
# hr ,v( o.i-1.'/
U.i
07/29 ¦> 7*4 I
	:-w:
# SF-674 _ 0 hosf
tj iWr
•
-------
PARTICULATE WORKSHEET
Client t ~	;	RFA # ^ r 'f f L
ANALYST|.'fl|}-;ll/ ''a'AI- A	METHOD	DATE "ijicjjrl
Run # -
Filter
acetone
Rinse
Ncszzle Cyclone
meclz	roiusNf		
OHLDROFDEM/ETHEfi	
Df HZO fMPWSER
CdntJ •
Filter # |tark Wt.Ib!
CONT.#
Vol.Cml)
CONT.#
: vol.[ml)
CONT,#
vai-wu
CONT. ir
- vauiwu
-f/'AsTi _ £T











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-------
PARTICULATE WORKSHEET
C UETNT
analyst
Method
R FA #
Date
M£:Cl.2		 Tdloeme
Chl a	m/Et ws p
Rum #
F (LTER
AcrroNE Sinse
nozzle Cyclone
Of HZD !mpshger
n-r.fr I Filter # ITawe WT.Iell Cot
gdnt,#
VnL.IMU
VOLrtMLi 1 C DNT.f
Cony.# » Vol,!;
VDL,(M'.t
-------
PARTICULATE WORKSHEET
CiltHT ir-.Flt			UFA # tc,
ANALYST J 	METHOD	DATE


1 $- -- -':1:'" '."'" "'•' 7'"tr¦' '" '¦¦
i (vi £ c: :-.'.
:"Cu.:fNr: -	
r__.

:, f~>- Li N ;.v

Filter


. K» 5 N S E.
:mdzzl e

' C h :.\..i~s:¦¦¦ •::] x .w •::-¦•r
D s ' H 2 LI-
1 -- "
1—*<-.v^-*- '¦aft--'/- ;Si:v..;:g: I
5 CiLISiT.#
F:ltk~ #
Taps -Wt.Cs;
CDNT,#
Vl3: - £ r-:i_ t
Cunt,#
VDL'.lMi.!
iJONT,®
¦ ¦¦ VC!
77/:;r

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J?15 Pfjspac^us Drive
'Ji rr-'tr, we, 27~13
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Samples collected by:
(signature)
Sa
CHAIN OF CUSTODY RECORD
Project Description:
Arcadis ctwge # •
S&spo i bla ~iyc , Pd^,
£W4..5j2Q2
pm2.5/202
pm2.5/202
pm2 5/2Q2
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Number of
Contains
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Dale shipped: 		
-Date:
-------
Arcadis
'^1? Prospecitffe Drive
D.<-h?m NO 77712
;£'1S) 5^4 <1535
CHAIN OF CUSTODY RECORD
Project Description;
Arcadis charae#:
Pas®.
of	1
Sample iii 1 Date 1 'Sample Description
Cowrie if
Number of
Container®
Analyses Required










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Samples collected by;
(signature)
Samples feline
/I
Date:
Dale shipped:
-------
f First Analytical Laboratories	Td <9i,j>v42«,?
^	FAX f919^ 929-8688
1126 Burning Tree Dr. Chapel Hill, NC 27517	www.firstanaiyticaiiabs.com
	
ANALYSIS REPORT
Project #: 80709	Report Date: 25-Jul-08
Client: Arcadis	Date Received: 15-Jul-08
Client Project ID: RN0071 60.0001.00004
Total Micrograms in Sample
Sample
Sb
As
Ba

Be
Cd
Cr

V9
V9
V9

V9
V9
V9
ACD-M29-FB Front
< 1.0
< 0.5
< 4
<
0.03
2.46
0.8
ACD-M29-FB Back
< 1.2
< 0.6
< 5
<
0.04
1.90
1.6
I-ACD-M29-01 Front
11.5
79.8
16

0.05
7.12
45.4
I-ACD-M29-01 Back







I-ACD-M29-02 Front
24.4
8.2
13

0.06
6.16
37.3
I-ACD-M29-02 Back
< 1.2
< 0.6
< 5
<
0.04
1.46
1.1
I-ACD-M29-03 Front
4.0
202
29

0.05
12.2
21.2
I-ACD-M29-03 Back
< 1.2
< 0.6
< 5
<
0.04
0.35
1.2
II-ACD-M29-01 Front
119
65.3
28

0.04
22.6
12.5
II-ACD-M29-01 Back
< 1.2
< 0.6
< 5
<
0.04
2.16
1.3
II-ACD-M29-02 Front
338
11.9
57

0.06
57.1
22.6
II-ACD-M29-02 Back
< 1.2
0.8
< 5
<
0.04
0.52
1.4
II-ACD-M29-03 Front
15.7
749
25
<
0.03
27.0
199
II-ACD-M29-03 Back
6.5
29.1
< 5
<
0.04
0.57
1.4
QC SUMMARY
Spike, %Rec. Front	93% 108% 99% 90% 92% 107%
Spike, %Rec. Back	85% 110% 98% 102% 101% 91%
4 of 58
-------
First Analytical Laboratories Tel (919)942-860?
^	FAX f919^ 929-8688
1126 Burning Tree Dr. Chapel Hill, NC 27517 www.firstanaiyticaiiabs.com
ANALYSIS REPORT
Project #: 80709
Client: Arcadis
Client Project ID: RN0071 60.0001.00004
Report Date: 25-Jul-08
Date Received: 15-Jul-08

Total Micrograms
in Sample




Sample

Co
Pb
Mn
Ni

Se
Ag


V9
V9
V9
V9

V9
V9
ACD-M29-FB Front
<
1.0
< 0.5
2.4
< 1.0
<
1.0
< 0.1
ACD-M29-FB Back
<
1.2
< 0.6
11.1
2.0
<
1.2
< 0.1
I-ACD-M29-01 Front
<
1.0
121
43.2
47.2

1.5
1.2
I-ACD-M29-01 Back








I-ACD-M29-02 Front
<
1.0
138
42.8
50.6
<
1.0
1.0
I-ACD-M29-02 Back
<
1.2
< 0.6
12.0
1.5
<
1.2
< 0.1
I-ACD-M29-03 Front
<
1.0
103
108
23.0
<
1.0
0.6
I-ACD-M29-03 Back
<
1.2
< 0.6
14.3
2.9
<
1.2
< 0.1
II-ACD-M29-01 Front
<
1.0
977
80.5
15.7
<
1.0
0.6
II-ACD-M29-01 Back
<
1.2
< 0.6
11.4
3.6
<
1.2
< 0.1
II-ACD-M29-02 Front
<
1.0
912
59.8
18.0
<
1.0
0.9
II-ACD-M29-02 Back
<
1.2
0.7
8.4
3.9
<
1.2
< 0.1
II-ACD-M29-03 Front

1.9
2010
80.7
135
<
1.0
1.3
II-ACD-M29-03 Back
<
1.2
< 0.6
4.9
3.5
<
1.2
< 0.1
QC SUMMARY
Spike, %Rec. Front	102% 100% 94% 97% 83% 75%
Spike, %Rec. Back	105% 102% 83% 96% 99% 85%
5 of 58
-------
First Analytical Laboratories Tel (919)942-860?
^	FAX f919^ 929-8688
1126 Burning Tree Dr. Chapel Hill, NC 27517 www.firstanaiyticaiiabs.com
ANALYSIS REPORT
Project #: 80709	Report Date: 25-Jul-08
Client: Arcadis	Date Received: 15-Jul-08
Client Project ID: RN0071 60.0001.00004
Total Micrograms of Mercury in Analytical Fraction
Sample	Fracl Frac2B Frac3A Frac3B Frac3C Total
V9	V9	V9	V9	V9	V9
ACD-M29-FB
< 0.4
<
1.2
< 0.2
< 0.4
< 0.6
< 2.8
I-ACD-M29-01
< 0.4


< 0.2
< 0.4
< 0.6
< 1.6
I-ACD-M29-02
< 0.4
<
1.3
< 0.2
< 0.4
< 0.6
< 2.9
I-ACD-M29-03
< 0.4
<
1.5
< 0.2
< 0.4
< 0.6
< 3.1
II-ACD-M29-01
< 0.4
<
1.3
< 0.2
< 0.4
4.1
4.1
II-ACD-M29-02
< 0.4
<
1.5
< 0.2
< 0.4
8.7
8.7
II-ACD-M29-03
< 0.4
<
1.4
< 0.2
< 0.4
1.8
1.8
QC SUMMARY
Back Spike, %Recov.	105%
6 of 58
-------
ANTIMONY
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 23-Jul-08
MDL = 10.0 ^g/L
Postdig'n spike conc. = 100.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


yg/L
m/l
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
4.2
4.2
100
1


<
1.00
I-ACD-M29-01
80709.11-1
115.2
115.2
100
1



11.52
I-ACD-M29-02
80709.12-1
121.9
243.8
100
2



24.38
I-ACD-M29-03
80709.13-1
39.9
39.9
100
1



3.99
II-ACD-M29-01
80709.21-1
118.6
1186
100
10



118.6
II-ACD-M29-02
80709.22-1
169.2
3384
100
20



338.4
II-ACD-M29-03
80709.23-1
156.5
156.5
100
1



15.65
BACK HALVES









ACD-M29-FB
80709.B-2A
2.0
2.0
100
1
288
238
<
1.21
I-ACD-M29-02
80709.12-2A
-0.7
-0.7
100
1
335
285
<
1.18
I-ACD-M29-03
80709.13-2A
-3.9
-3.9
100
1
377
327
<
1.15
II-ACD-M29-01
80709.21-2A
3.2
3.2
100
1
323
273
<
1.18
II-ACD-M29-02
80709.22-2A
-3.3
-3.3
100
1
363
313
<
1.16
II-ACD-M29-03
80709.23-2A
18.6
55.8
100
3
357
307

6.49
FRONT SPIKE
BACK SPIKE
80709.11-IS	207.8
80709.12-2AS	84.7
% REC = 92.6%
% REC = 84.7%
7 of 58
-------
ANTIMONY
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 23-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard 1 20.0	0.034
Standard 2 50.0	0.080
Standard 3 100.0	0.141
Standard 4 200.0	0.273
Calibration Verifications
98.3
0.7
CCV1 = 100 109.3
CCB1 =0	1.7
CCV2 = 100 98.8
CCB2 = 0	-4.8
ICV= 100	107.1	CCV3 = 100
ICB = 0	-2.2	CCB3 = 0
8 of 58
-------
ARSENIC
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 22-Jul-08
MDL =
Postdig'n spike conc. =
5.0 /ig/L
100.0 /ig/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


m/l
Mg/L
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
2.1
2.1
100
1


<
0.50
I-ACD-M29-01
80709.11-1
79.8
797.6
100
10



79.76
I-ACD-M29-02
80709.12-1
81.8
81.8
100
1



8.18
I-ACD-M29-03
80709.13-1
202.1
2021
100
10



202.1
II-ACD-M29-01
80709.21-1
65.3
653.2
100
10



65.32
II-ACD-M29-02
80709.22-1
59.7
119.4
100
2



11.94
II-ACD-M29-03
80709.23-1
149.8
7490
100
50



749.0
BACK HALVES









ACD-M29-FB
80709.B-2A
-0.6
-0.6
100
1
288
238
<
0.61
I-ACD-M29-02
80709.12-2A
-3.8
-3.8
100
1
335
285
<
0.59
I-ACD-M29-03
80709.13-2A
4.4
4.4
100
1
377
327
<
0.58
II-ACD-M29-01
80709.21-2A
1.9
1.9
100
1
323
273
<
0.59
II-ACD-M29-02
80709.22-2A
6.5
6.5
100
1
363
313

0.75
II-ACD-M29-03
80709.23-2A
124.9
249.8
100
2
357
307

29.05
FRONT SPIKE
BACK SPIKE
80709.11-1S	188.1
80709.12-2AS	110.3
% REC = 108.3%
% REC = 110.3%
9 of 58
-------
ARSENIC
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 22-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard! 10.0	0.032
Standard 2 50.0	0.139
Standard 3 100.0	0.269
Standard 4 200.0	0.544
Calibration Verifications
ICV= 100	96.7	CCV3 = 100 106.2
ICB = 0	-0.3	CCB3 = 0	1.0
CCV1 = 100	109.3
CCB1 =0	1.3
CCV2 = 100	103.9
CCB2 = 0	0.7
10 of 58
-------
BARIUM*
ICP ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis	MDL = 40.0 /Jg/L
Proj. #: 80709	Postdig'n spike conc. = 1000.0 /Jg/L
Date: 23-Jul-08
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


m/l
m/l
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
40
40
100
1


<
4.00
I-ACD-M29-01
80709.11-1
157
157
100
1



15.70
I-ACD-M29-02
80709.12-1
134
134
100
1



13.40
I-ACD-M29-03
80709.13-1
291
291
100
1



29.10
II-ACD-M29-01
80709.21-1
283
283
100
1



28.30
II-ACD-M29-02
80709.22-1
566
566
100
1



56.60
II-ACD-M29-03
80709.23-1
247
247
100
1



24.70
BACK HALVES









ACD-M29-FB
80709.B-2A
40
40
100
1
288
238
<
4.84
I-ACD-M29-02
80709.12-2A
40
40
100
1
335
285
<
4.70
I-ACD-M29-03
80709.13-2A
40
40
100
1
377
327
<
4.61
II-ACD-M29-01
80709.21-2A
40
40
100
1
323
273
<
4.73
II-ACD-M29-02
80709.22-2A
40
40
100
1
363
313
<
4.64
II-ACD-M29-03
80709.23-2A
40
40
100
1
357
307
<
4.65
FRONT SPIKE
80709.12-1S
1120



% REC =
98.6%


BACK SPIKE
80709.12-2AS
982



% REC =
98.2%


* Analysis performed by Mircobac
11 Of 58
-------
BERYLLIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 22-Jul-08
MDL = 0.3 ijg/L
Postdig'n spike conc. = 5.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


m/l
m/l
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
0.22
0.22
100
1


<
0.030
I-ACD-M29-01
80709.11-1
0.53
0.53
100
1



0.053
I-ACD-M29-02
80709.12-1
0.58
0.58
100
1



0.058
I-ACD-M29-03
80709.13-1
0.45
0.45
100
1



0.045
II-ACD-M29-01
80709.21-1
0.39
0.39
100
1



0.039
II-ACD-M29-02
80709.22-1
0.57
0.57
100
1



0.057
II-ACD-M29-03
80709.23-1
0.26
0.26
100
1


<
0.030
BACK HALVES









ACD-M29-FB
80709.B-2A
0.09
0.09
100
1
288
238
<
0.036
I-ACD-M29-02
80709.12-2A
0.04
0.04
100
1
335
285
<
0.035
I-ACD-M29-03
80709.13-2A
0.29
0.29
100
1
377
327
<
0.035
II-ACD-M29-01
80709.21-2A
0.00
0.00
100
1
323
273
<
0.035
II-ACD-M29-02
80709.22-2A
-0.02
-0.02
100
1
363
313
<
0.035
II-ACD-M29-03
80709.23-2A
0.03
0.03
100
1
357
307
<
0.035
FRONT SPIKE
80709.11-1S
5.05



% REC =
90.4%


BACK SPIKE
80709.12-2AS
5.08



% REC =
101.6%


12 of 58
-------
BERYLLIUM
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 22-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard! 0.5	0.015
Standard 2 2.0	0.056
Standard 3 5.0	0.134
Standard 4 10.0	0.255
Calibration Verifications
ICV = 5	5.21	CCV3 = 5	5.11
ICB = 0	0.19	CCB3 = 0	0.19
CCV1 = 5	5.09
CCB1 = 0	0.20
CCV2 = 5	5.21
CCB2 = 0	0.06
13 of 58
-------
CADMIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis	MDL = 0.2 /Jg/L
Proj. #: 80709	Postdig'n spike conc. = 5.0 /Jg/L
Date: 23-Jul-08
Test Dig'te	Dil'n Total Volume
>lume Dig'd
ml	ml
Client
FAL
Sol'n
Conc
FV
Factor


m/l
m/l
ml

FRONT HALVES





ACD-M29-FB
80709.B-l
1.23
24.6
100
20
I-ACD-M29-01
80709.11-1
3.56
71.2
100
20
I-ACD-M29-02
80709.12-1
3.08
61.6
100
20
I-ACD-M29-03
80709.13-1
6.08
121.6
100
20
II-ACD-M29-01
80709.21-1
3.76
225.6
100
60
II-ACD-M29-02
80709.22-1
5.71
570.5
100
100
II-ACD-M29-03
80709.23-1
2.70
269.8
100
100
BACK HALVES
ACD-M29-FB
I-ACD-M29-02
I-ACD-M29-03
II-ACD-M29-01
II-ACD-M29-02
II-ACD-M29-03
FRONT SPIKE
BACK SPIKE
80709.B-2A
80709.12-2A
80709.13-2A
80709.21-2A
80709.22-2A
80709.23-2A
80709.11-1S
80709.12-2AS
3.14	15.70
4.13	12.39
1.51	3.02
3.65	18.25
2.22	4.44
2.44	4.88
8.14
9.19
100	5
100	3
100	2
100	5
100	2
100	2
288	238
335	285
377	327
323	273
363	313
357	307
REC =	91.6%
REC =	101.2%
Total
2.460
7.120
6.160
12.160
22.560
57.050
26.980
1.900
1.456
0.348
2.159
0.515
0.567
14 of 58
-------
CADMIUM
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 23-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard 1 0.5	0.036
Standard 2 2.0	0.148
Standard 3 5.0	0.325
Standard 4 10.0	0.544
Calibration Verifications
ICV = 5	4.60
ICB = 0	0.10
CCV1 = 5	4.54
CCB1 = 0	-0.01
CCV2 = 5	4.64
CCB2 = 0	-0.02
CCV3 = 5	5.04
CCB3 = 0	-0.02
CCV4 = 5	5.26
CCB4 = 0	0.08
15 of 58
-------
CHROMIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 22-Jul-08
MDL = 5.0 ijg/L
Postdig'n spike conc. = 50.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume

Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd
Total


m/l
m/l
ml

ml
ml

FRONT HALVES








ACD-M29-FB
80709.B-l
8.4
8.4
100
1


0.84
I-ACD-M29-01
80709.11-1
45.4
454.0
100
10


45.40
I-ACD-M29-02
80709.12-1
37.3
373.0
100
10


37.30
I-ACD-M29-03
80709.13-1
21.2
212.0
100
10


21.20
II-ACD-M29-01
80709.21-1
41.7
125.1
100
3


12.51
II-ACD-M29-02
80709.22-1
22.6
226.0
100
10


22.60
II-ACD-M29-03
80709.23-1
39.8
1990.0
100
50


199.00
BACK HALVES








ACD-M29-FB
80709.B-2A
13.4
13.4
100
1
288
238
1.62
I-ACD-M29-02
80709.12-2A
9.7
9.7
100
1
335
285
1.14
I-ACD-M29-03
80709.13-2A
10.0
10.0
100
1
377
327
1.15
II-ACD-M29-01
80709.21-2A
11.1
11.1
100
1
323
273
1.31
II-ACD-M29-02
80709.22-2A
12.2
12.2
100
1
363
313
1.41
II-ACD-M29-03
80709.23-2A
11.7
11.7
100
1
357
307
1.36
FRONT SPIKE
BACK SPIKE
80709.11-1S	98.8
80709.12-2AS	55.4
% REC
% REC
106.8%
91.4%
16 of 58
-------
CHROMIUM
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 22-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard! 10.0	0.148
Standard 2 20.0	0.293
Standard 3 50.0	0.669
Standard 4 100.0	1.249
Calibration Verifications
ICV = 50	47.5	CCV3 = 50 44.6
ICB = 0	0.4	CCB3 = 0	1.0
CCV1 = 50	48.5
CCB1 = 0	0.7
CCV2 = 50	47.3
CCB2 = 0	1.1
17 of 58
-------
COBALT
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 23-Jul-08
MDL = 10.0^g/L
Postdig'n spike conc. = 100.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


m/l
m/l
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
1.7
1.7
100
1


<
1.00
I-ACD-M29-01
80709.11-1
7.4
7.4
100
1


<
1.00
I-ACD-M29-02
80709.12-1
9.1
9.1
100
1


<
1.00
I-ACD-M29-03
80709.13-1
6.8
6.8
100
1


<
1.00
II-ACD-M29-01
80709.21-1
5.7
5.7
100
1


<
1.00
II-ACD-M29-02
80709.22-1
8.1
8.1
100
1


<
1.00
II-ACD-M29-03
80709.23-1
19.4
19.4
100
1



1.94
BACK HALVES









ACD-M29-FB
80709.B-2A
1.8
1.8
100
1
288
238
<
1.21
I-ACD-M29-02
80709.12-2A
0.6
0.6
100
1
335
285
<
1.18
I-ACD-M29-03
80709.13-2A
3.4
3.4
100
1
377
327
<
1.15
II-ACD-M29-01
80709.21-2A
0.9
0.9
100
1
323
273
<
1.18
II-ACD-M29-02
80709.22-2A
2.8
2.8
100
1
363
313
<
1.16
II-ACD-M29-03
80709.23-2A
0.8
0.8
100
1
357
307
<
1.16
FRONT SPIKE
80709.11-1S
102.4



% REC =
102.4%


BACK SPIKE
80709.12-2AS
105.2



% REC =
105.2%


18 of 58
-------
COBALT
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 23-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard 1 20.0	0.087
Standard 2 50.0	0.207
Standard 3 100.0	0.403
Standard 4 200.0	0.792
Calibration Verifications
ICV= 100	105.5	CCV3 = 100 110.7
ICB = 0	2.2	CCB3 = 0	NA
CCV1 = 100	106.7
CCB1 = 0	3.9
CCV2 = 100	108.8
CCB2 = 0	2.0
19 of 58
-------
LEAD
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 18-Jul-08
MDL =
Postdig'n spike conc. =
5.0 /ig/L
100.0 jJg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


m/l
m/l
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
1.8
1.8
100
1


<
0.50
I-ACD-M29-01
80709.11-1
60.7
1214
100
20



121.4
I-ACD-M29-02
80709.12-1
69.1
1382
100
20



138.2
I-ACD-M29-03
80709.13-1
51.5
1030
100
20



103.0
II-ACD-M29-01
80709.21-1
97.7
9770
100
100



977.0
II-ACD-M29-02
80709.22-1
91.2
9120
100
100



912.0
II-ACD-M29-03
80709.23-1
50.3
20120
100
400



2012
BACK HALVES









ACD-M29-FB
80709.B-2A
3.3
3.3
100
1
288
238
<
0.61
I-ACD-M29-02
80709.12-2A
2.4
2.4
100
1
335
285
<
0.59
I-ACD-M29-03
80709.13-2A
4.0
4.0
100
1
377
327
<
0.58
II-ACD-M29-01
80709.21-2A
2.4
2.4
100
1
323
273
<
0.59
II-ACD-M29-02
80709.22-2A
6.2
6.2
100
1
363
313

0.72
II-ACD-M29-03
80709.23-2A
4.5
4.5
100
1
357
307
<
0.58
FRONT SPIKE
BACK SPIKE
80709.11-1S	160.3
80709.12-2AS	101.6
% REC = 99.6%
% REC = 101.6%
20 of 58
-------
LEAD
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 18-Jul-08
Calibration Data

True Cone.


yg/L
Abs.
Blank
0.0
0.000
Standard 1
10.0
0.023
Standard 2
50.0
0.104
Standard 3
100.0
0.202
Standard 4
200.0
0.342
Calibration Verifications
ICV = 100	98.3
ICB = 0	-1.0
CCV1 = 100	104.0
CCB1 = 0	-0.2
CCV2 = 100	100.9
CCB2 = 0	0.3
CCV3 = 100	103.5
CCB3 = 0	-0.6
CCV4 = 100	103.0
CCB4 = 0	-1.9
21 of 58
-------
MANGAN ESE
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 16-Jul-08
MDL = 5.0 ijg/L
Postdig'n spike conc. = 50.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume
Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd


m/l
m/l
ml

ml
ml
FRONT HALVES







ACD-M29-FB
80709.B-l
23.7
23.7
100
1


I-ACD-M29-01
80709.11-1
21.6
432
100
20


I-ACD-M29-02
80709.12-1
42.8
428
100
10


I-ACD-M29-03
80709.13-1
54.1
1082
100
20


II-ACD-M29-01
80709.21-1
80.5
805
100
10


II-ACD-M29-02
80709.22-1
59.8
598
100
10


II-ACD-M29-03
80709.23-1
80.7
807
100
10


BACK HALVES







ACD-M29-FB
80709.B-2A
91.9
91.9
100
1
288
238
I-ACD-M29-02
80709.12-2A
51.2
102.4
100
2
335
285
I-ACD-M29-03
80709.13-2A
61.9
123.8
100
2
377
327
II-ACD-M29-01
80709.21-2A
48.2
96.4
100
2
323
273
II-ACD-M29-02
80709.22-2A
36.0
72.0
100
2
363
313
II-ACD-M29-03
80709.23-2A
21.2
42.4
100
2
357
307
FRONT SPIKE
80709.11-1S
68.5



% REC =
93.8%
BACK SPIKE
80709.12-2AS
92.9



% REC =
83.4%
Total
2.37
43.2
42.8
108.2
80.5
59.8
80.7
11.12
12.04
14.27
11.41
8.35
4.93
22 of 58
-------
MANGAN ESE
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 16-Jul-08
Calibration Data

True Cone.


yg/L
Abs.
Blank
0.0
0.000
Standard 1
10.0
0.242
Standard 2
20.0
0.433
Standard 3
50.0
0.990
Standard 4
100.0
1.601
Calibration Verifications
ICV = 50	52.1
ICB = 0	2.4
CCV1 = 50	52.0
CCB1 = 0	0.0
CCV2 = 50	53.8
CCB2 = 0	0.9
CCV3 = 50	54.0
CCB3 = 0	1.3
CCV4 = 50	49.7
CCB4 = 0	0.9
23 of 58
-------
NICKEL
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 16-Jul-08
MDL = 10.0^g/L
Postdig'n spike conc. = 100.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume

Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd
Total


m/l
m/l
ml

ml
ml

FRONT HALVES








ACD-M29-FB
80709.B-l
-1.3
-1.3
100
1


< 1.00
I-ACD-M29-01
80709.11-1
94.3
471.5
100
5


47.15
I-ACD-M29-02
80709.12-1
101.2
506.0
100
5


50.60
I-ACD-M29-03
80709.13-1
76.5
229.5
100
3


22.95
II-ACD-M29-01
80709.21-1
78.4
156.8
100
2


15.68
II-ACD-M29-02
80709.22-1
90.0
180.0
100
2


18.00
II-ACD-M29-03
80709.23-1
67.6
1352.0
100
20


135.20
BACK HALVES








ACD-M29-FB
80709.B-2A
16.2
16.2
100
1
288
238
1.96
I-ACD-M29-02
80709.12-2A
12.5
12.5
100
1
335
285
1.47
I-ACD-M29-03
80709.13-2A
25.4
25.4
100
1
377
327
2.93
II-ACD-M29-01
80709.21-2A
30.3
30.3
100
1
323
273
3.58
II-ACD-M29-02
80709.22-2A
33.2
33.2
100
1
363
313
3.85
II-ACD-M29-03
80709.23-2A
30.1
30.1
100
1
357
307
3.50
FRONT SPIKE
BACK SPIKE
80709.11-1S	191.6
80709.12-2AS	108.6
% REC = 97.3%
% REC = 96.1%
24 of 58
-------
NICKEL
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 16-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard 1 20.0	0.067
Standard 2 50.0	0.174
Standard 3 100.0	0.338
Standard 4 200.0	0.661
Calibration Verifications
ICV= 100	106.7
ICB = 0	-1.4
CCV1 = 100	101.2
CCB1 = 0	0.6
CCV2 = 100	99.3
CCB2 = 0	1.0
CCV3 = 100	94.6
CCB3 = 0	1.6
CCV4 = 100	101.1
CCB4 = 0	1.7
CCV5 = 100	98.2
CCB5 = 0	0.1
25 of 58
-------
SELENIUM
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 17-Jul-08
MDL = 10.0^g/L
Postdig'n spike conc. = 100.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


m/l
m/l
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
-2.3
-2.3
100
1


<
1.00
I-ACD-M29-01
80709.11-1
14.7
14.7
100
1



1.47
I-ACD-M29-02
80709.12-1
6.9
6.9
100
1


<
1.00
I-ACD-M29-03
80709.13-1
2.1
2.1
100
1


<
1.00
II-ACD-M29-01
80709.21-1
3.3
3.3
100
1


<
1.00
II-ACD-M29-02
80709.22-1
4.6
4.6
100
1


<
1.00
II-ACD-M29-03
80709.23-1
3.7
3.7
100
1


<
1.00
BACK HALVES









ACD-M29-FB
80709.B-2A
-0.2
-0.2
100
1
288
238
<
1.21
I-ACD-M29-02
80709.12-2A
6.0
6.0
100
1
335
285
<
1.18
I-ACD-M29-03
80709.13-2A
-1.9
-1.9
100
1
377
327
<
1.15
II-ACD-M29-01
80709.21-2A
-0.8
-0.8
100
1
323
273
<
1.18
II-ACD-M29-02
80709.22-2A
2.1
2.1
100
1
363
313
<
1.16
II-ACD-M29-03
80709.23-2A
-0.5
-0.5
100
1
357
307
<
1.16
FRONT SPIKE
80709.11-1S
97.8



% REC =
83.1%


BACK SPIKE
80709.12-2AS
98.9



% REC =
98.9%


26 of 58
-------
SELENIUM
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 17-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard 1 20.0	0.047
Standard 2 50.0	0.105
Standard 3 100.0	0.211
Standard 4 200.0	0.411
Calibration Verifications
ICV= 100	97.6	CCV3 = 100 101.6
ICB = 0	-1.6	CCB3 = 0	0.6
CCV1 = 100 106.1
CCB1 =0	1.7
CCV2 = 100 100.8
CCB2 = 0	-1.4
27 of 58
-------
SILVER
GFAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 17-Jul-08
MDL = 1.0 ijg/L
Postdig'n spike conc. = 10.0 /Jg/L
Sample ID

Test
Dig'te

Dil'n
Total
Volume


Client
FAL
Sol'n
Conc
FV
Factor
Volume
Dig'd

Total


m/l
m/l
ml

ml
ml


FRONT HALVES









ACD-M29-FB
80709.B-l
0.5
0.5
100
1


<
0.10
I-ACD-M29-01
80709.11-1
4.1
12.4
100
3



1.24
I-ACD-M29-02
80709.12-1
3.2
9.7
100
3



0.97
I-ACD-M29-03
80709.13-1
1.9
5.6
100
3



0.56
II-ACD-M29-01
80709.21-1
1.9
5.6
100
3



0.56
II-ACD-M29-02
80709.22-1
3.0
9.0
100
3



0.90
II-ACD-M29-03
80709.23-1
4.3
12.9
100
3



1.29
BACK HALVES









ACD-M29-FB
80709.B-2A
0.8
0.8
100
1
288
238
<
0.12
I-ACD-M29-02
80709.12-2A
0.6
0.6
100
1
335
285
<
0.12
I-ACD-M29-03
80709.13-2A
0.8
0.8
100
1
377
327
<
0.12
II-ACD-M29-01
80709.21-2A
0.5
0.5
100
1
323
273
<
0.12
II-ACD-M29-02
80709.22-2A
0.2
0.2
100
1
363
313
<
0.12
II-ACD-M29-03
80709.23-2A
0.5
0.5
100
1
357
307
<
0.12
FRONT SPIKE
BACK SPIKE
80709.11-1S	11.6
80709.12-2AS	8.5
% REC = 75.0%
% REC = 85.1%
28 of 58
-------
SILVER
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 17-Jul-08
Calibration Data	True Cone.
/J g/L	Abs.
Blank 0.0	0.000
Standard! 5.0	0.116
Standard 2 10.0	0.230
Standard 3 20.0	0.437
Standard 4 30.0	0.644
Calibration Verifications
ICV = 20	20.3
ICB = 0	-0.1
CCV1 = 20	19.7
CCB1 = 0	0.1
CCV2 = 20	19.9
CCB2 = 0	0.1
CCV3 = 20	20.2
CCB3 = 0	0.1
CCV4 = 20	19.9
CCB4 = 0	-0.6
CCV5 = 20	19.9
CCB5 = 0	0.4
29 of 58
-------
M E RC U RY
CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis
Proj. #: 80709
Date: 16-Jul-08
MDL =
Spike conc. =
0.2 /ig/L
5.0 /ig/L
Sample ID

Test
Dig'te



Digst'd

Client
FAL
Sol'n
Conc
FV
Dil'n
Volume
Vol.



m/l
yg/L
ml
Factor
ml
ml

FRONT HALVES








ACD-M29-FB
80709.B-l
-0.13
-0.13
100
1
100
5
<
I-ACD-M29-01
80709.11-1
-0.15
-0.15
100
1
100
5
<
I-ACD-M29-02
80709.12-1
-0.11
-0.11
100
1
100
5
<
I-ACD-M29-03
80709.13-1
-0.04
-0.04
100
1
100
5
<
II-ACD-M29-01
80709.21-1
-0.03
-0.03
100
1
100
5
<
II-ACD-M29-02
80709.22-1
0.09
0.09
100
1
100
5
<
II-ACD-M29-03
80709.23-1
-0.02
-0.02
100
1
100
5
<
FRACTIONS 2B








ACD-M29-FB
80709.B-2B
-0.06
-0.06
100
1
288
5
<
I-ACD-M29-02
80709.12-2B
-0.01
-0.01
100
1
335
5
<
I-ACD-M29-03
80709.1 3-2B
-0.09
-0.09
100
1
377
5
<
II-ACD-M29-01
80709.21-2B
-0.04
-0.04
100
1
323
5
<
II-ACD-M29-02
80709.22-2B
0.18
0.18
100
1
363
5
<
II-ACD-M29-03
80709.23-2B
-0.03
-0.03
100
1
357
5
<
BACK SPK
80709.11-2BS
5.23



%REC =
104.6%

FRACTIONS 3A








ACD-M29-FB
80709.B-3A
-0.15
-0.15
100
1
93
10
<
I-ACD-M29-01
80709.11-3A
-0.06
-0.06
100
1
89
10
<
I-ACD-M29-02
80709.12-3A
-0.07
-0.07
100
1
90
10
<
I-ACD-M29-03
80709.1 3-3A
-0.14
-0.14
100
1
93
10
<
II-ACD-M29-01
80709.21-3A
-0.09
-0.09
100
1
94
10
<
II-ACD-M29-02
80709.22-3A
-0.10
-0.10
100
1
92
10
<
II-ACD-M29-03
80709.23-3A
-0.12
-0.12
100
1
99
10
<
Total
0.40
0.40
0.40
0.40
0.40
0.40
0.40
1.15
1.34
1.51
1.29
1.45
1.43
0.19
0.18
0.18
0.19
0.19
0.18
0.20
30 of 58
-------
M E RC U RY
CVAA ANALYSIS RUN SUMMARY AND CALCULATION WORKSHEET
Client: Arcadis	MDL = 0.2 /Jg/L
Proj. #: 80709	Spike conc. = 5.0 /Jg/L
Date: 16-Jul-08
Sample ID Test	Dig'te Digst'd
Client FAL Sol'n	Conc	FV Dil'n Volume Vol.
/ig/L	/J g/L	ml Factor	ml ml
FRACTIONS 3B
ACD-M29-FB
80709.B-3B
-0.07
-0.07
100
1
386
20
I-ACD-M29-01
80709.11-3B
0.02
0.02
100
1
423
20
I-ACD-M29-02
80709.12-3B
-0.09
-0.09
100
1
375
20
I-ACD-M29-03
80709.1 3-3B
-0.05
-0.05
100
1
369
20
II-ACD-M29-01
80709.21-3B
-0.14
-0.14
100
1
430
20
II-ACD-M29-02
80709.22-3B
0.01
0.01
100
1
439
20
II-ACD-M29-03
80709.23-3B
-0.02
-0.02
100
1
418
20
FRACTIONS 3C
ACD-M29-FB
80709.B-3C
0.00
0.00
100
1
150
5
I-ACD-M29-01
80709.11-3C
-0.04
-0.04
100
1
140
5
I-ACD-M29-02
80709.12-3C
0.01
0.01
100
1
139
5
I-ACD-M29-03
80709.1 3-3C
0.02
0.02
100
1
153
5
II-ACD-M29-01
80709.21-3C
1.35
1.35
100
1
150
5
II-ACD-M29-02
80709.22-3C
2.62
2.62
100
1
165
5
II-ACD-M29-03
80709.23-3C
0.57
0.57
100
1
156
5
Total
<	0.39
<	0.42
<	0.38
<	0.37
<	0.43
<	0.44
<	0.42
<	0.60
<	0.56
<	0.56
<	0.61
4.05
8.65
1.78
31 of 58
-------
M E RC U RY
QUALITY CONTROL DATA
Client: Arcadis
Proj. #: 80709
Date: 16-Jul-08
Calibration Data

True conc., /Jg/L
Abs.
Blank
0.00
0.000
Standard 1
0.50
0.012
Standard 2
1.00
0.021
Standard 3
2.00
0.052
Standard 4
5.00
0.132
Standard 5
10.00
0.254
Calibration Verifications
ICV = 5	5.24
ICB = 0	-0.09
CCV1 = 5	5.00
CCB1 = 0	-0.13
CCV2 = 5	5.50
CCB2 = 0	0.03
CCV3 = 5	5.27
CCB3 = 0	-0.11
CCV4 = 5	5.13
CCB4 = 0	-0.08
CCV5 = 5	5.09
CCB5 = 0	-0.16
32 of 58
-------
Arcadis
4915 Prospectus Drive
Durham, NC 27713
(919) 544-4535
Sample ID
RUN # I-ACD-M29-Q1
RUN # I-ACD-M29-01
RUN # I-ACD-M29-01
RUN # I-ACD-M29-Q1
RUN # [-ACD-M29-01
RUN # [-ACD-M29-01
RUN # 1-ACD-M29-02
RUN # 1-ACD-M29-02
RUN # 1-ACD-M29-02
RUN # 1-ACD-M29-02
RUN # I-ACD-M29-02
RUN # I-ACD-M29-02
RUN # I-ACD-M29-03
RUN # 1-ACD-M29-03
RUN # I-ACD-M29-Q3
RUN # I-ACD-M29-03
RUN # I-ACD-M29-03
RUN # I-ACD-M29-03
Date
Collected
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/24/08
06/25/08
06/25/08
06/25/08
06/25/08
06/25/08
06/25/08
Sample Description
m29 dry filter
front half 0.1 NHNQ3 rinse
HNQ3/H2Q2 reagent plus HN03 rinse
empty impinger HN03 rinse
8N HCL rinse
m29 dry filter
front half 0.1 N HNQ3 rinse
HNQ3/H2Q2 reagent plus HNQ3 rinse
empty impinger HNQ3 rinse
8N HCL rinse
m29 dry filter
front half 0.1 N HN03 rinse
HNQ3/H2Q2 reaoent.Plus HN03 rinse
empty impinger HNQ3 rinse
8N HCL rinse
CHAIN OF CUSTODY RECORD
Project Description: New Orleans
Arcadis charge#: RN00716Q.Q001.00004
Responsible Arcadis Party:
-80709
of
Gene Stephenson
Number of
Containers
Analyses Required
M29 for As, Sb. Ba
M29 for As, Sb, Ba
M29 for As, Sb, Ba
M29 for As. Sb, Ba
M29 for As. Sb. Ba
M29 for As, Sb, Ba,
M29 for As. Sb,
M29 for As. Sb.
M29 for As, Sb.
M29 for As, Sb.
M29 for As, Sb, Ba
M29 for As, Sb.Ba,
M29forAs. Sb. Ba,
Be
Be
Be
Be
Be.
Be.
Cd. Cr. Co. Pb. Mn, Ni. Se. Ag, Hq
Cd. Cr. Co. Pb,
Cd. Cr. Co. Pb,
Cd. Cr. Co. Pb,
Cd, Cr, Co, Pb,
Cd, Cr, Co. Pb,
Mn. Ni. Se. Ao, Hq
Mn, Ni, Se, Ag. Hg
LOST
Mn, Ni, Se, Ag. Hg
Mn, Ni, Se, Ag. Hg
Mn, Ni, Se, Ag. Hg
Cd, Cr, Co, Pb, Mn. N
Cd. Cr, Co, Pb.
Cd. Cr, Co, Pb,
Be. Cd, Cr. Co. Pb,
Cd, Cr. Co, Pb,
Cd, Cr. Co, Pb,
Mn. N
Se, Ag, Hg
Se, Ag, Hg
S8.-*a. Hfl
Se,.
Lii2_
Se. Ag, Hg
Se. As. Hg
!, Cd, Cr, Co. Pb. Mn, Ni. Se. Ag. Hg
M29 for As. Sb. Ba. Be. Cd. Cr. Co. Pb. Mn. Ni. Se. Ag. Hg
M29 for As, Sb. Ba. Be. Cd- Cr- Co. Pb- Mn. Ni. Se. Ag. Ha
M29 for As. Sb. Ba. Be. Cd. Cr, Co. Pb, Mn, Ni. Se. Ag, Hg
M29 for As, Sb, Ba. Be. Cd. Cr, Co. Pb, Mn, Ni. Se. Ag. Hg
1IM29for As, Sb. Ba, Be. Cd, Cr, Co, Pb, Mn, Ni, Se, Ag, Hg
HI

Samples collected by:
(signature)
Samples relinquished by:
(signature)
Samples received by:
(signature)

Date:

Date shipped:

fit.

¥-
Date:
: 7ft
sfog
33 of 58
-------
Arcadis	CHAIN OF CUSTODY RECORD
4915 Prospectus Drive
Durham, NC 27713	Project Description: Now Orleans -80709	Page	2	of	3.
(919)544-4535	Arcadis charge#: RN007160.0Q01.00004
Responsible Arcadis Party:
Sample ID
Date
Collected
Sample Description
Number of
Containers
Analyses Required
RUN # H-ACD-M29-01
06/25/08
m29 dry filter
Gene Stephenson
1
M29 for As. Sb, 8a, Be, Cd, Cr, Co, Pb, Ma Ni, Se, Aa. Hq
Run # II-ACD-M29-01
06/25/08
front half 0,1 N HN03 rinse

1
M29 for As, Sb, Ba, Be. Cd. Cr. Co, Pb, Mn, Ni, Se. An. Hq
Run # IJ-ACD-M29-01
06/25/08
HN03/H202 reaqent plus HN03 rinse

1
M29 for As, Sb, 8a, Be, Cd. Cr. Co, Pb, Mn, Ni. Se. Aa. Hq
Run # N-ACD-M29-Q1
06/25/08
empty impinger HN03 rinse

1
M29 for As. Sb, Ba, Be, Gd. Cr. Co. Pb. Mn, Ni. Se. Aa, Ha
Run # II-ACD-M29-01
Run # H-ACD-M29-G1
06/25/08
06/25/08
KMN04/H2S04 manant nltis KNM04 rinsa

1
M29 for As, Sb, Ba. Be, Cd. Cr. Co. Pb. Mn. Ni. Se. Aa. Ha
8N HCL rinse

1
M29 for As, Sb, Ba, Be, Cd, Cr. Co. Pb. Mn. Ni, Se, Aa. Hg






RUN # II-ACD-M29-02
06/26/08
m29 dry filter

1
M29 for As, Sb. Ba. Be. Cd, Cr, Co, Pb. Mn, Ni, Se, Aa. Ha
RUN # II-ACD-M29-02
06/26/08
front half 0.1 NHN03 rinse

1
M29 for As, Sb, Ba. Be. Cd, Cr, Co, Pb, Mn, Ni, Se, Aa, Hq
RUN # II-ACD-M29-02
06/26/08
HN03/H202 reaqent plus HN03 rinse

1
M29 for As, Sb, Ba, Be, Cd, Cr. Co. Pb. Mn, Ni. Se. Aq, Hq
RUN # II-ACD-M29-02
06/26/08
empty impinger HN03 rinse

1
M29 for As. Sb, Ba, Be. Cd, Cr, Co, Pb, Mn, Ni, Se. Aq. Hq
RUN # II-ACD-M29-02
06/26/08
KMNO4/H2$04 reaaent oiys KNM04 rinse

1
M29 for As, Sb, Ba. Be. Cd. Cr, Co, Pb, Mn, Ni, Se, Ag, Hq
RUN # I1-ACD-M29-Q2
06/26/08
8N HCL rinse

1
M29 for As. Sb, Ba, Be, Cd, Cr. Co, Pb, Mn, Ni, Se, Aa, Hq






RUN # H-ACD-M29-03
06/26/08
m29 dry filter

1
M29 for As. Sb, Ba. Be. Cd. Cr, Co. Pb, Mn, Ni, Se. Aq, Hq
RUN # II-ACD-M29-03
06/26/08
front half 0.1 N HN03 rinse

1
M28 for As. Sb, Ba, Be, Cd. Cr. Co. Pb. Mn. Ni, Se, Aq. Hq
RUN # II-ACD-M29-03
06/26/08
HNQ3/H202 reasent olus HN03 rinse

1
M29 far As, Sb. Ba. Be. Cd. Cr. Co. Pb, Mn. Ni. Se. Aa. Ha
RUN# H-ACD-M29-03
06/26/08
empty impinger HN03 rinse

1
M29for As. Sb. Ba. Be. Cd. Cr. Co. Pb. Mn, Ni. Se. Aa. Ha
RUN # li-ACD~M29-03
06/26/08
KyNG4/H?S£J4 raanant Dta KNM04 rinss

1
M29 for As. Sb, Ba, Be, Cd. Cr, Co. Pb, Mn. Ni, Se, Aa. Ho
RUN # II-ACD-M29-03
06/26/08
8N HCL rinse

1
M29 for As. Sb. Ba. Be. Cd, Cr, Co, Pb, Mn, Ni. Se, Aq, Hq
Samples collected by:
(signature)
Samples relinquished toy:
(signature)
Samples received by:
(signature)
—-
Date:
Date shipped:
Date:
Date:
"/S-o?
34 of 58
-------
Arcadis
4915 Prospectus Drive
Durham, NC 27713
(919) 544-4535
CHAIN OF CUSTODY RECORD
-80 7 0 9
Project Description: New Orleans
Arcadis charge # : RN007160.0001.00004
Page_
of
Sample ID
Date
Collected
Sample Description
Number of
Containers
Analyses Required
RUN # ACD-M29-FB
06/25/08
m29 drv filter
Gene Stephenson
1
M29 for As. Sb, Ba. Be. Cd. Cr, Co, Pb, Mn. Ni. Se, An. Hq
Run # ACD-M29-FB
06/25/08
front half 0-1 N HN03 rinse

1
M29 for As. Sb, Ba, Be. Cd. Cr. Co. Pb. Mn. Ni. Se. Aq. Hq
Run # AGD-M29-FB
06/25/03
HNO3/H202 reaqent plus HN03 rinse

1
M29 for As. Sb, Ba. Be. Cd. Cr. Co. Pb. Mn. Ni. Se. Aq. Hq
Run # ACD-M29-FB
06/25/08
empty impinaer HN03 rinse

1
M29 for As. Sb. Ba. Be, Cd, Cr, Co. Pb. Mn. Ni. Se. Aq. Hq
Run # ACD-M29-FB
Run # ACD-M29-FB
06/25/08
06/25/08
KMNO4/H2S04 reaaerrt Dlus KNM04 rinse

1
M29 for As, Sb, Ba, Be, Cd, Cr, Co, Pb. Mn. Ni, Se, Aq, Hq
8N HCL rinse

1
M29 for As. Sb. Ba, Be. Cd. Cr. Co. Pb. Mn, Ni. Se. Aq, Hq




















































































Samples collected by:
(signature)
Samples relinquished by:
(signature)
Samples received by:
(signature)
Date:
Date shipped:
Date: 7-/^0?
Date: ifiZfoX
35 of 58
-------
ARCADIS
REQUEST FOR PURCHASING ACTION I PURCHASE ORDER
,©
Database Compliant
10/2007
&
Bill to: ARCADIS, 4915 Prospectus Drive, Suite F, Durham, NC 27713
VENDOR
CONTACT
First Analytical
Bill Wadlin
PHONE
FAX
(919)942-8607
(919)929-8688
E-MAIL ADDRESS
WWW.FIRSTANALYTICALLABS.COM
PROPOSED VENDOR / MANUFACTURER
MANUFACT, SUBSTITUTION OK?

YES S NO*
'explain in Special Instructions/Comments
REQU1SITIONER
DATE
Gene Stephenson
7/11/2008
APPROVAL (SIGNATURE)
DATE


OLS APPROVAL
»»> DATE REQUIRED ««««

7/25/2008
Ship to:
C DROP SHIP
samples will be delivered to First Analytical Tuesday, July 15
8 0 7 0 9
ARCADIS
4915 Prospectus Drive
Suite F
Durham, NC 27713
(919)544-4535
r EPA
109 TW Alexander Drive
Building E Loading Dock
RTP, NC 27711
PURCHASE ORDER NUMBER
RB64103
CONTRACT DATE
TOTAL EST. COST
7/11/2008
$5,120.00
PAGE PAGES
CONTRACT#
1 OF 1

SPECIAL INSTRUCTIONS I COMMENTS
e-mail results to: genestephenson@arcadis-us.com
FOR OFFICIAL USE ONLY
SHIP ¥IA[
TERMS[
FREIGHtf
NET 30
Prepay and Add
ARCADIS
£9
ITEM
PROJECT
PHASE
TASK
% SPLIT
DESCRIPTION
PART NUMBER
QTY
UNIT
UNIT PRICE
EXT
SHIP 1
SHIP 2
SHIP 3
1
RN007160
0001
00004
100%
M29 metals analysis

7
ea
$610.00
$4270.00


































































































































$4,270.00

VENDORS: To avoid delays in payment, please confirm price and delivery by FAX or email.
CHEMICAL?
r YES S- NO
EPA CUSTODIAN
SAFETY
APPROVAL DATE
IN-PLANT DESTINATION
B-1
CONTACT
PHONE
Rick Bullock
36of 58
BUYER'S SIGNATURE
PHONE: (919) 54+4535
FAX: (919)544-5690
EMAIL: DurtiamPurchasing@arcadis-us.com
DATE
To print with Terms
and Conditions, select
2-sided, flip on short edge
-------
Instr. A
GFAA Raw Data
Corr. Coeff. 0.99886
Sample_ID
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Units
Dilu
Rec
Std_U 1
Std_U 2
RSD
Calib Blank
Sb
23-Jul-08
8:40:57
-0.0337

m/l




0.20
20 ppb
Sb
23-Jul-08
8:48:18
0.0343

yg/L




7.58
50 ppb
Sb
23-Jul-08
8:55:46
0.0798

yg/L




10.30
100 ppb
Sb
23-Jul-08
9:03:17
0.1410

yg/L




3.93
200 ppb
Sb
23-Jul-08
9:10:52
0.2727

yg/L




1.94
ICV
Sb
23-Jul-08
9:20:15
0.1569
107.126
m/l


102.023
112.230
6.74
ICB
Sb
23-Jul-08
9:27:35
-0.0039
-2.167
yg/L


0.993
-5.327
206.10
80709.LB
Sb
23-Jul-08
9:35:09
-0.0043
-2.289
m/l


4.189
-8.766
400.20
80709.LCS
Sb
23-Jul-08
9:42:48
0.1504
102.065
m/l
2

103.599
100.531
2.13
80709.B-l
Sb
23-Jul-08
9:50:25
0.0071
4.150
m/l


-0.478
8.779
157.70
80709.11-1
Sb
23-Jul-08
9:54:14


yg/L
10

110.659


80709.11-1
Sb
23-Jul-08
10:03:09
0.1671
115.181
m/l


121.689
108.673
7.99
80709.11-1
Sb
23-Jul-08
10:10:42
0.2770
207.781
m/l

92.6
212.258
203.304
3.05
80709.12-1
Sb
23-Jul-08
10:18:14
0.3295
255.411
m/l


261.454
249.368
3.35
80709.13-1
Sb
23-Jul-08
10:22:00


yg/L


0.726


80709.12-1
Sb
23-Jul-08
10:31:46
0.1756
121.942
m/l
2

122.172
121.712
0.27
80709.13-1
Sb
23-Jul-08
10:39:16
0.0159
9.273
m/l
3

5.203
13.344
62.07
CCV
Sb
23-Jul-08
10:46:46
0.1597
109.317
yg/L


111.098
107.535
2.30
CCB
Sb
23-Jul-08
10:54:05
0.0030
1.694
yg/L


1.753
1.635
4.94
80709.21-1
Sb
23-Jul-08
11:01:28
0.4796
401.074
m/l
3

401.227
400.922
0.05
80709.22-1
Sb
23-Jul-08
11:08:54
0.8607
812.686
m/l
3

782.850
842.522
5.19
80709.23-1
Sb
23-Jul-08
11:16:17
0.2177
156.487
m/l
3

147.937
165.037
7.73
80709.13-1
Sb
23-Jul-08
11:26:37
0.0644
39.858
m/l


40.486
39.230
2.23
80709.21-1
Sb
23-Jul-08
11:34:05
0.1714
118.574
Mg/L
10

118.120
119.027
0.54
80709.22-1
Sb
23-Jul-08
11:41:29
0.2328
169.228
yg/L
20

169.840
168.616
0.51
80709.B-2A
Sb
23-Jul-08
11:48:51
0.0035
1.999
yg/L


2.216
1.782
15.38
80709.12-2A
Sb
23-Jul-08
11:56:09
-0.0013
-0.730
yg/L


-4.143
2.683
661.20
80709.12-2A
Sb
23-Jul-08
12:03:40
0.1275
84.678
m/l

84.67
81.495
87.861
5.32
CCV
Sb
23-Jul-08
12:11:09
0.1461
98.757
yg/L


99.582
97.933
1.18
CCB
Sb
23-Jul-08
12:18:28
-0.0086
-4.837
yg/L


-4.975
-4.698
4.05
80709.13-2A
Sb
23-Jul-08
12:25:45
-0.0070
-3.910
yg/L


-6.810
-1.010
104.80
80709.21-2A
Sb
23-Jul-08
12:33:04
0.0055
3.187
yg/L


-0.185
6.559
149.60
80709.22-2A
Sb
23-Jul-08
12:40:27
-0.0059
-3.268
m/l


0.667
-7.204
170.20
80709.23-2A
Sb
23-Jul-08
12:47:52
0.0314
18.638
Mg/L
3

18.208
19.067
3.26
CCV
Sb
23-Jul-08
12:55:22
0.1456
98.341
yg/L


101.234
95.448
4.16
CCB
Sb
23-Jul-08
13:02:41
0.0011
0.661
yg/L


2.753
-1.431
447.40
37 of 58
-------
Instr. B
GFAA Raw Data
Sample_ID
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Ur
Calib Blank
As
22-Jul-08
9:53:57
-0.0021

m/l
10 PPB AS
As
22-Jul-08
10:01:07
0.0316

yg/L
50 PPB AS
As
22-Jul-08
10:08:20
0.1392

yg/L
100 PPB AS
As
22-Jul-08
10:15:36
0.2691

yg/L
200 PPB AS
As
22-Jul-08
10:22:56
0.5436

yg/L
ICV
As
22-Jul-08
10:33:01
0.2628
96.705
yg/L
ICB
As
22-Jul-08
10:40:10
-0.0008
-0.287
yg/L
80709.LB
As
22-Jul-08
10:47:29
0.0066
2.435
m/l
80709.LCS
As
22-Jul-08
10:54:53
0.2703
99.480
m/l
80709.B-l
As
22-Jul-08
11:02:16
0.0058
2.124
m/l
80709.11-1
As
22-Jul-08
11:05:56


yg/L
80709.11-1
As
22-Jul-08
11:16:29
0.2167
79.759
m/l
80709.11-1
As
22-Jul-08
11:23:51
0.5111
188.087
m/l
80709.12-1
As
22-Jul-08
11:31:08
0.0252
9.285
m/l
80709.13-1
As
22-Jul-08
11:38:24
0.5492
202.124
m/l
80709.21-1
As
22-Jul-08
11:45:37
0.1775
65.321
m/l
CCV
As
22-Jul-08
11:52:53
0.2969
109.268
yg/i
CCB
As
22-Jul-08
12:00:03
0.0035
1.279
yg/L
80709.12-1
As
22-Jul-08
12:10:06
0.2223
81.818
m/l
80709.22-1
As
22-Jul-08
12:17:18
0.0397
14.616
m/l
80709.23-1
As
22-Jul-08
12:24:25
1.8404
677.338
m/l
80709.B-2A
As
22-Jul-08
12:31:30
-0.0018
-0.646
m/l
80709.12-2A
As
22-Jul-08
12:38:32
-0.0103
-3.807
Mg/L
80709.12-2A
As
22-Jul-08
12:45:48
0.2997
110.286
m/l
80709.13-2A
As
22-Jul-08
12:52:50
0.0120
4.426
Mg/L
80709.21-2A
As
22-Jul-08
12:59:55
0.0053
1.944
yg/L
CCV
As
22-Jul-08
13:07:08
0.2822
103.874
yg/L
CCB
As
22-Jul-08
13:14:19
0.0020
0.724
yg/L
80709.22-1
As
22-Jul-08
13:23:42
0.1623
59.726
m/l
80709.23-1
As
22-Jul-08
13:30:48
0.4069
149.762
Mg/L
80709.22-2A
As
22-Jul-08
13:37:54
0.0175
6.453
yg/L
80709.23-2A
As
22-Jul-08
13:41:28


yg/L
80709.23-2A
As
22-Jul-08
13:50:24
0.3393
124.872
yg/L
CCV
As
22-Jul-08
13:57:39
0.2886
106.205
yg/L
CCB
As
22-Jul-08
14:04:46
0.0026
0.963
Mg/L
38 of 58
Corr. Coeff. 0.99987
Dilu Rec Std U 1 Std U 2 RSD
447.10
11.29
3.60
2.60
1.49


99.658
93.753
4.32


-2.297
1.723
990.40


3.820
1.051
80.38


93.841
105.120
8.02


1.909
2.339
14.30


40.262


10

77.922
81.596
3.26
10
108.3
192.570
183.603
3.37
10

9.478
9.091
2.95
10

205.000
199.247
2.01
10

66.973
63.668
3.58


112.612
105.924
4.33


1.284
1.275
0.49


83.889
79.747
3.58
10

14.750
14.482
1.30
10

690.473
664.203
2.74


-0.087
-1.205
122.20


-3.198
-4.416
22.61

110.2
107.481
113.092
3.60


2.839
6.013
50.70


5.079
-1.190
227.90


108.961
98.786
6.93


0.682
0.765
8.03
2

61.598
57.854
4.43
50

156.191
143.333
6.07


6.286
6.620
3.66


239.598


2

121.196
128.548
4.16


108.865
103.545
3.54


-0.829
2.755
263.20
-------
Instr. A
GFAA Raw Data
SamplelD
EL
Sam_Date
Sam_Time
Calib Blank
Be
22-Jul-08
9:12:39
Calib Blank
Be
22-Jul-08
9:20:40
0.5 PPB
Be
22-Jul-08
9:27:26
2.0 PPB
Be
22-Jul-08
9:34:19
5.0 PPB
Be
22-Jul-08
9:41:14
10.0 PPB
Be
22-Jul-08
9:48:07
ICV
Be
22-Jul-08
10:16:39
ICB
Be
22-Jul-08
10:23:14
80709.LB
Be
22-Jul-08
10:29:56
80709.LCS
Be
22-Jul-08
10:36:42
80709.B-l
Be
22-Jul-08
10:43:25
80709.11-1
Be
22-Jul-08
10:50:07
80709.11-1
Be
22-Jul-08
10:57:12
80709.12-1
Be
22-Jul-08
11:03:49
80709.13-1
Be
22-Jul-08
11:10:25
80709.21-1
Be
22-Jul-08
11:16:59
CCV
Be
22-Jul-08
11:23:49
CCB
Be
22-Jul-08
11:30:24
80709.22-1
Be
22-Jul-08
11:36:55
80709.23-1
Be
22-Jul-08
11:43:29
80709.B-2A
Be
22-Jul-08
11:50:08
80709.12-2A
Be
22-Jul-08
11:56:48
80709.12-2A
Be
22-Jul-08
12:03:51
80709.13-2A
Be
22-Jul-08
12:10:32
80709.21-2A
Be
22-Jul-08
12:17:18
80709.22-2A
Be
22-Jul-08
12:24:05
CCV
Be
22-Jul-08
12:30:58
CCB
Be
22-Jul-08
12:37:35
80709.23-2A
Be
22-Jul-08
12:44:19
CCV
Be
22-Jul-08
12:51:12
CCB
Be
22-Jul-08
12:57:49
Mean_Sig Mean ST Cal Units


m/l
0.0043

m/l
0.0150

m/l
0.0556

m/l
0.1343

m/l
0.2552

m/l
0.1388
5.213
m/l
0.0059
0.195
m/l
0.0051
0.170
m/l
0.1406
5.282
m/l
0.0065
0.218
m/l
0.0157
0.530
M/L
0.1347
5.048
M/L
0.0171
0.578
M/L
0.0134
0.451
M/L
0.0118
0.394
M/L
0.1359
5.094
M/L
0.0059
0.197
M/L
0.0170
0.574
M/L
0.0077
0.257
M/L
0.0028
0.091
M/L
0.0011
0.040
Mg/L
0.1356
5.082
M/L
0.0086
0.286
Mg/L
-0.0001
-0.004
yg/L
-0.0007
-0.022
Mg/L
0.1387
5.206
Mg/L
0.0018
0.061
m/l
0.0009
0.032
Mg/L
0.1362
5.107
Mg/L
0.0058
0.194
Mg/L
39 of 58
Corr. Coeff. 0.99998
Dilu Rec
20
90.36
101.6
Std_U 1 Std U 2 RSD


166.10


2.45


13.82


2.42


2.51
5.100
5.326
3.06
0.197
0.192
1.95
0.093
0.246
63.92
5.299
5.265
0.45
0.318
0.118
65.00
0.444
0.617
23.07
4.840
5.256
5.83
0.701
0.455
30.08
0.455
0.448
1.17
0.393
0.395
0.32
4.969
5.219
3.46
0.198
0.195
1.02
0.635
0.514
14.90
0.287
0.227
16.54
0.043
0.140
74.74
-0.177
0.256
771.60
5.135
5.028
1.49
0.258
0.314
13.96
0.020
-0.029
797.10
-0.062
0.019
265.30
5.282
5.130
2.06
0.160
-0.038
230.70
-0.077
0.140
484.30
4.943
5.272
4.56
0.355
0.033
117.00
-------
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-------
Instr. B
GFAA Raw Data
Corr. Coeff. 0.99877
80709.22-2A
Cd
23-Jul-08
13:16:33
0.0271
0.370
Mg/L
10
0.413
0.326
16.66
CCV
Cd
23-Jul-08
13:24:16
0.3035
4.448
yg/L

4.386
4.510
1.97
CCB
Cd
23-Jul-08
13:31:53
-0.0018
-0.025
yg/L

0.006
-0.056
177.70
80709.23-2A
Cd
23-Jul-08
13:39:31
0.0685
0.942
yg/L
5
0.967
0.917
3.74
CCV
Cd
23-Jul-08
13:47:15
0.2973
4.345
yg/L

4.275
4.416
2.29
CCB
Cd
23-Jul-08
13:54:51
0.0006
0.008
yg/L

0.063
-0.048
1046.00
Calib Blank
Cd
23-Jul-08
14:05:29
-0.0006

yg/L



148.00
Reslope
Cd
23-Jul-08
14:13:10
0.3022

yg/L



2.82
CCV
Cd
23-Jul-08
14:23:41
0.3041
5.036
yg/L

5.033
5.040
0.10
CCB
Cd
23-Jul-08
14:31:18
-0.0014
-0.021
yg/L

0.027
-0.069
326.70
80709.22-1
Cd
23-Jul-08
14:38:55
0.3390
5.705
yg/L
100
5.645
5.765
1.48
80709.12-2A
Cd
23-Jul-08
14:46:28
0.2542
4.129
yg/L
3
4.070
4.189
2.04
80709.12-2A
Cd
23-Jul-08
14:54:12
0.4831
9.186
yg/L
3 101.1
9.149
9.223
0.57
80709.13-2A
Cd
23-Jul-08
15:01:43
0.0968
1.512
yg/L
2
1.437
1.588
7.08
80709.21-2A
Cd
23-Jul-08
15:09:17
0.2264
3.646
yg/L
5
3.614
3.677
1.21
80709.22-2A
Cd
23-Jul-08
15:16:52
0.1411
2.224
yg/L
2
2.273
2.174
3.14
80709.23-2A
Cd
23-Jul-08
15:24:30
0.1543
2.439
yg/L
2
2.427
2.451
0.68
CCV
Cd
23-Jul-08
15:32:14
0.3160
5.261
yg/L

5.111
5.411
4.03
CCB
Cd
23-Jul-08
15:39:48
0.0049
0.076
Mg/L

0.071
0.080
8.67
41 of 58
-------
Instr. A
GFAA Raw Data
Corr. Coeff. 0.99879
Sample_ID
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Units
Dilu Rec
Std_U 1
Std_U 2
RSD
Calib Blank
Cr
22-Jul-08
13:44:56
0.0249

m/l



58.43
Calib Blank
Cr
22-Jul-08
13:52:26
0.0319

M/L



1.92
1 0 ppb Cr
Cr
22-Jul-08
13:59:58
0.1402

M/L



0.94
20 ppb Cr
Cr
22-Jul-08
14:07:37
0.2274

M/L



25.06
50 ppb Cr
Cr
22-Jul-08
14:15:12
0.6686

M/L



1.99
1 00 ppb Cr
Cr
22-Jul-08
14:22:46
1.2485

M/L



1.41
20 ppb Cr
Cr
22-Jul-08
14:39:38
0.2930

M/L



3.10
1 0 ppb Cr
Cr
22-Jul-08
14:50:34
0.1480

M/L



1.34
ICV
Cr
22-Jul-08
14:58:58
0.6448
47.547
M/L

47.267
47.827
0.83
ICB
Cr
22-Jul-08
15:06:21
0.0057
0.369
M/L

0.641
0.097
104.30
80709.LB
Cr
22-Jul-08
15:13:46
-0.0045
-0.289
M/L

-0.204
-0.373
41.24
80709.LCS
Cr
22-Jul-08
15:21:12
0.6468
47.714
M/L
2
47.316
48.112
1.18
80709.B-l
Cr
22-Jul-08
15:28:35
0.1251
8.353
M/L

8.384
8.322
0.53
80709.11-1
Cr
22-Jul-08
15:35:57
0.3184
22.140
M/L
20
22.315
21.965
1.12
80709.11-1
Cr
22-Jul-08
15:44:58
0.6183
45.395
M/L
10
45.145
45.646
0.78
80709.11-1
Cr
22-Jul-08
15:52:31
1.2321
98.762
M/L
10 106.7
98.611
98.913
0.22
80709.12-1
Cr
22-Jul-08
15:59:56
0.5166
37.276
M/L
10
37.537
37.014
0.99
80709.13-1
Cr
22-Jul-08
16:07:23
0.3052
21.165
M/L
10
21.351
20.979
1.24
CCV
Cr
22-Jul-08
16:14:56
0.6565
48.501
M/L

48.479
48.524
0.07
CCB
Cr
22-Jul-08
16:22:20
0.0104
0.680
M/L

1.195
0.165
107.10
80709.21-1
Cr
22-Jul-08
16:29:46
0.1653
11.135
M/L
10
11.242
11.029
1.35
80709.22-1
Cr
22-Jul-08
16:37:18
0.3248
22.611
M/L
10
22.636
22.586
0.16
80709.23-1
Cr
22-Jul-08
16:44:52
2.3050
205.516
M/L
10
198.803
212.230
4.62
80709.B-2A
Cr
22-Jul-08
16:52:31
0.2377
16.272
M/L

17.969
14.575
14.75
80709.21-1
Cr
22-Jul-08
17:02:32
0.5728
41.737
Mg/L
3
43.133
40.341
4.73
80709.23-1
Cr
22-Jul-08
17:10:07
0.5491
39.839
yg/L
50
40.156
39.521
1.13
80709.B-2A
Cr
22-Jul-08
17:17:44
0.1979
13.429
M/L

13.930
12.929
5.27
80709.12-2A
Cr
22-Jul-08
17:25:25
0.1443
9.678
Mg/L

9.710
9.647
0.46
80709.12-2A
Cr
22-Jul-08
17:33:04
0.7399
55.398
yg/L
91.43
54.604
56.191
2.03
CCV
Cr
22-Jul-08
17:40:39
0.6420
47.316
Mg/L

47.170
47.463
0.44
CCB
Cr
22-Jul-08
17:48:03
0.0176
1.150
Mg/L

1.787
0.512
78.39
80709.13-2A
Cr
22-Jul-08
17:55:38
0.1487
9.981
m/l

9.881
10.080
1.41
80709.21-2A
Cr
22-Jul-08
18:03:23
0.1641
11.053
Mg/L

11.111
10.996
0.74
80709.22-2A
Cr
22-Jul-08
18:11:07
0.1801
12.175
yg/L

12.259
12.091
0.97
80709.23-2A
Cr
22-Jul-08
18:18:49
0.0595
3.914
yg/L
3
3.929
3.899
0.55
CCV
Cr
22-Jul-08
18:26:26
0.6084
44.594
yg/L

44.211
44.977
1.22
CCB
Cr
22-Jul-08
18:33:49
0.0148
0.965
m/l

1.272
0.657
45.05
42 of 58
-------
Instr. A
GFAA Raw Data
Corr. Coeff. 1.00000
Sample_ID
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Units Dilu
Rec
Std_U 1
Std_U 2
RSD
Calib Blank
Co
23-Jul-08
13:56:25
-0.0043

yg/L



39.16
20 ppb Co
Co
23-Jul-08
14:03:48
0.0875

yg/L



7.07
50 ppb Co
Co
23-Jul-08
14:11:16
0.2068

yg/L



7.07
100 ppb Co
Co
23-Jul-08
14:18:41
0.4027

yg/L



2.62
200 ppb Co
Co
23-Jul-08
14:26:04
0.7921

yg/L



2.37
ICV
Co
23-Jul-08
14:38:07
0.4241
105.498
yg/L

107.736
103.260
3.00
ICB
Co
23-Jul-08
14:45:19
0.0111
2.209
yg/L

0.734
3.685
94.46
80709.LB
Co
23-Jul-08
14:52:35
-0.0118
-1.884
yg/L

-1.355
-2.413
39.73
80709.LCS
Co
23-Jul-08
14:59:50
0.4275
106.385
M g/L 2

109.085
103.685
3.59
80709.B-l
Co
23-Jul-08
15:07:04
0.0088
1.718
Mg/L

2.202
1.233
39.87
80709.11-1
Co
23-Jul-08
15:14:14
0.0346
7.420
yg/L

3.480
11.360
75.09
80709.11-1
Co
23-Jul-08
15:21:37
0.4118
102.354
yg/L
102.3
103.484
101.224
1.56
80709.12-1
Co
23-Jul-08
15:30:11
0.0422
9.096
yg/L

10.222
7.970
17.51
80709.13-1
Co
23-Jul-08
15:37:27
0.0324
6.835
yg/L

6.286
7.384
11.36
80709.21-1
Co
23-Jul-08
15:44:46
0.0269
5.671
yg/L

8.877
2.466
79.92
CCV
Co
23-Jul-08
15:52:07
0.4287
106.678
yg/L

105.767
107.589
1.21
CCB
Co
23-Jul-08
15:59:21
0.0189
3.886
yg/L

1.510
6.262
86.47
80709.22-1
Co
23-Jul-08
16:06:38
0.0377
8.097
yg/L

5.148
11.046
51.50
80709.23-1
Co
23-Jul-08
16:14:04
0.0850
19.399
yg/L

22.101
16.698
19.69
80709.B-2A
Co
23-Jul-08
16:21:30
0.0090
1.767
yg/L

2.681
0.853
73.11
80709.12-2A
Co
23-Jul-08
16:28:59
0.0034
0.639
yg/L

0.498
0.779
31.17
80709.12-2A
Co
23-Jul-08
16:36:28
0.4230
105.235
yg/L
105.2
106.039
104.432
1.08
80709.13-2A
Co
23-Jul-08
16:43:58
0.0166
3.366
yg/L

4.976
1.756
67.65
80709.21-2A
Co
23-Jul-08
16:51:33
0.0026
0.934
yg/L

4.315
-2.447
511.90
80709.22-2A
Co
23-Jul-08
16:59:06
0.0137
2.758
yg/L

1.020
4.496
89.10
CCV
Co
23-Jul-08
17:06:32
0.4371
108.841
yg/L

109.633
108.049
1.03
CCB
Co
23-Jul-08
17:13:45
0.0100
2.005
yg/L

3.802
0.207
126.70
80709.23-2A
Co
23-Jul-08
17:21:11
0.0038
0.813
yg/L

2.523
-0.896
297.20
CCV
Co
23-Jul-08
17:28:38
0.4444
110.714
yg/L

107.075
114.352
4.65
CCV
Co
23-Jul-08
17:36:01
0.4548
113.375
yg/L

116.450
110.301
3.83
43 of 58
-------
Instr. B
GFAA Raw Data
Corr. Coeff. 0.99980
Sample_ID
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Units
Dilu
Rec
Std_U 1
Std_U 2
RSD
Calib Blank
Pb
1 8-Jul-08
7:53:51
0.0215

yg/L




1.05
10 ppb Pb
Pb
1 8-Jul-08
8:01:20
0.0234

yg/L




12.76
50 ppb Pb
Pb
1 8-Jul-08
8:08:54
0.1040

yg/L




0.22
100 ppb Pb
Pb
1 8-Jul-08
8:16:27
0.2024

yg/L




1.86
200 ppb Pb
Pb
1 8-Jul-08
8:23:59
0.3417

yg/L




1.02
ICV
Pb
1 8-Jul-08
8:31:59
0.1883
93.748
yg/L


92.747
94.750
1.51
ICB
Pb
1 8-Jul-08
8:39:19
-0.0115
-4.876
yg/L


-3.933
-5.820
27.36
80710.LB
Pb
1 8-Jul-08
8:46:44
-0.0150
-6.333
yg/L


-5.420
-7.245
20.37
80710.LCS
Pb
1 8-Jul-08
8:54:11
0.1835
90.976
yg/L


90.534
91.418
0.69
80710.FB
Pb
1 8-Jul-08
9:01:39
-0.0103
-4.340
yg/L


-4.438
-4.242
3.18
Calib Blank
Pb
1 8-Jul-08
9:09:30
-0.0180

yg/L




13.07
Reslope
Pb
1 8-Jul-08
9:17:00
0.2039

yg/L




1.02
ICV
Pb
1 8-Jul-08
9:32:19
0.2010
98.312
yg/L


97.578
99.047
1.06
ICB
Pb
1 8-Jul-08
9:39:36
-0.0023
-0.968
yg/L


-1.087
-0.849
17.40
80710.LB
Pb
1 8-Jul-08
9:47:01
0.0019
0.796
yg/L


-0.264
1.855
188.30
80710.LCS
Pb
1 8-Jul-08
9:54:28
0.1968
95.857
yg/L


95.354
96.360
0.74
80710.FB
Pb
1 8-Jul-08
10:01:53
0.0034
1.425
yg/L


3.491
-0.640
204.90
80710.10-1
Pb
1 8-Jul-08
10:09:14
0.3962
240.521
yg/L


241.783
239.258
0.74
80710.10-1S
Pb
1 8-Jul-08
10:16:31
0.5058
359.573
yg/L


357.068
362.077
0.98
80710.10-2
Pb
1 8-Jul-08
10:23:49
0.3084
168.420
yg/L


166.192
170.648
1.87
80710.10-2D
Pb
1 8-Jul-08
10:31:00
0.3086
168.580
yg/L


167.662
169.498
0.77
80710.10-3
Pb
1 8-Jul-08
10:38:13
0.2518
129.474
yg/L


129.308
129.641
0.18
CCV
Pb
1 8-Jul-08
10:49:32
0.2052
100.748
yg/L


102.290
99.206
2.16
CCB
Pb
1 8-Jul-08
10:56:54
0.0012
0.510
yg/L


0.213
0.808
82.49
80710.10-1
Pb
1 8-Jul-08
11:04:11
0.1665
78.870
yg/L
3

77.811
79.928
1.90
80710.10-1S
Pb
1 8-Jul-08
11:11:27
0.2195
109.296
yg/L
3

113.847
104.744
5.89
80710.10-4
Pb
1 8-Jul-08
11:18:44
0.0510
21.920
yg/L


21.708
22.132
1.37
80710.10-6
Pb
1 8-Jul-08
11:26:02
0.0413
17.624
yg/L


16.776
18.473
6.81
80710.10-7
Pb
1 8-Jul-08
11:33:21
0.0419
17.880
yg/L


19.589
16.172
13.51
CCV
Pb
1 8-Jul-08
11:40:53
0.2108
104.035
yg/L


104.105
103.965
0.09
CCB
Pb
1 8-Jul-08
11:48:15
-0.0004
-0.160
yg/L


0.659
-0.980
722.60
80709.LB
Pb
1 8-Jul-08
12:07:35
-0.0024
-0.984
yg/L


-3.366
1.398
342.30
80709.LCS
Pb
1 8-Jul-08
12:14:59
0.2000
97.702
yg/L


96.804
98.600
1.30
80709.B-l
Pb
1 8-Jul-08
12:22:21
0.0044
1.811
yg/L


0.631
2.991
92.17
80709.11-1
Pb
1 8-Jul-08
12:29:42
0.1321
60.723
yg/L
20

58.947
62.500
4.14
80709.11-1
Pb
1 8-Jul-08
12:37:15
0.2971
160.271
yg/L
20
99.54
158.338
162.204
1.71
44 of 58
-------
Instr. B
GFAA Raw Data
Corr. Coeff. 0.99980
80709.12-1
Pb
1 8-Jul-08
12:44:34
0.1483
69.116
Mg/L
20
70.733
67.500
3.31
80709.13-1
Pb
1 8-Jul-08
12:51:52
0.1139
51.543
yg/L
20
50.487
52.599
2.90
80709.21-1
Pb
1 8-Jul-08
12:59:03
0.6414
589.379
yg/L
20
589.283
589.475
0.02
CCV
Pb
1 8-Jul-08
13:06:31
0.2054
100.852
yg/L

101.329
100.374
0.67
CCB
Pb
1 8-Jul-08
13:13:55
0.0007
0.297
yg/L

-0.786
1.381
515.70
80709.22-1
Pb
1 8-Jul-08
13:21:05
0.6186
541.026
yg/L
20
548.377
533.675
1.92
80709.23-1
Pb
1 8-Jul-08
13:28:21
0.9553
3793.141
yg/L
20
3864.161
3722.122
2.65
80709.B-2A
Pb
1 8-Jul-08
13:35:40
0.0078
3.254
yg/L

3.936
2.572
29.64
80709.21-1
Pb
1 8-Jul-08
13:49:34
0.2000
97.734
yg/L
100
98.084
97.384
0.51
80709.22-1
Pb
1 8-Jul-08
13:56:50
0.1887
91.214
yg/L
100
90.695
91.734
0.80
80709.23-1
Pb
1 8-Jul-08
14:04:06
0.1115
50.342
yg/L
400
50.233
50.450
0.31
80709.12-2A
Pb
1 8-Jul-08
14:11:23
0.0057
2.363
yg/L

0.174
4.552
131.00
80709.12-2A
Pb
1 8-Jul-08
14:18:57
0.2066
101.590
yg/L

101.5 101.219
101.962
0.52
CCV
Pb
1 8-Jul-08
14:26:27
0.2099
103.542
yg/L

105.538
101.546
2.73
CCB
Pb
1 8-Jul-08
14:33:47
-0.0015
-0.626
yg/L

-1.295
0.043
151.10
80709.13-2A
Pb
1 8-Jul-08
14:41:07
0.0095
3.955
yg/L

5.857
2.053
68.00
80709.21-2A
Pb
1 8-Jul-08
14:48:32
0.0059
2.439
yg/L

3.446
1.433
58.35
80709.22-2A
Pb
1 8-Jul-08
14:56:03
0.0149
6.246
yg/L

5.790
6.702
10.33
80709.23-2A
Pb
1 8-Jul-08
15:03:36
0.0108
4.514
yg/L

5.605
3.423
34.17
CCV
Pb
1 8-Jul-08
15:11:11
0.2090
102.970
yg/L

103.202
102.738
0.32
CCB
Pb
1 8-Jul-08
15:18:32
-0.0045
-1.871
yg/L

-1.392
-2.350
36.23
45 of 58
-------
Instr. B
GFAA Raw Data
Corr. Coeff. 0.99987
Sample_ID
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Units
Dilu Rec
Std_U 1
Std_U 2
RSD
Calib Blank
Mn
16-Jul-08
7:31:30
-0.0519

m/l



15.97
10 ppb Mn
Mn
16-Jul-08
7:38:26
0.2417

M/L



5.57
20 ppb Mn
Mn
16-Jul-08
7:45:27
0.4331

M/L



2.10
50 ppb Mn
Mn
16-Jul-08
7:52:23
0.9898

M/L



1.86
100 ppb Mn
Mn
16-Jul-08
7:59:19
1.6014

M/L



1.46
ICV
Mn
16-Jul-08
8:16:49
1.0110
52.147
M/L

50.112
54.182
5.52
ICB
Mn
16-Jul-08
8:23:37
0.0592
2.413
M/L

2.887
1.939
27.80
80705.LB
Mn
16-Jul-08
8:30:25
0.0387
1.568
M/L

1.659
1.478
8.12
80705.LCS
Mn
16-Jul-08
8:37:12
1.5708
96.947
M/L

94.094
99.800
4.16
80705.B-l
Mn
16-Jul-08
8:43:57
0.2600
11.072
M/L

11.155
10.988
1.06
80705.12-1
Mn
16-Jul-08
8:50:43
0.2401
10.181
M/L
20
9.796
10.566
5.35
80705.12-1
Mn
16-Jul-08
9:00:27
0.7470
35.820
M/L
5
34.723
36.917
4.33
80705.12-1
Mn
16-Jul-08
9:07:22
1.4015
81.566
M/L
5 91.49
79.992
83.141
2.73
80705.13-1
Mn
16-Jul-08
9:14:09
0.3447
14.969
M/L
2
15.683
14.255
6.74
80705.15-1
Mn
16-Jul-08
9:20:58
1.7082
110.925
M/L
5
107.293
114.556
4.63
CCV
Mn
16-Jul-08
9:30:08
1.0702
56.141
M/L

55.367
56.915
1.95
CCV
Mn
16-Jul-08
9:37:04
1.0557
55.152
M/L

53.778
56.526
3.52
CCB
Mn
16-Jul-08
9:43:54
0.0838
3.430
M/L

3.577
3.284
6.04
80705.15-1
Mn
16-Jul-08
9:50:41
0.8861
44.117
M/L
20
42.618
45.616
4.80
80705.B-2A
Mn
16-Jul-08
9:57:31
0.1135
4.685
M/L

5.621
3.749
28.25
80705.12-2A
Mn
16-Jul-08
10:04:25
0.3982
17.505
M/L

16.884
18.126
5.02
80705.12-2A
Mn
16-Jul-08
10:11:30
1.1695
63.201
M/L
91.39
62.434
63.968
1.72
80705.13-2A
Mn
16-Jul-08
10:18:26
0.2889
12.385
M/L

12.876
11.894
5.61
80705.15-2A
Mn
16-Jul-08
10:25:24
0.2396
10.158
M/L

10.606
9.710
6.24
CCV
Mn
16-Jul-08
10:32:24
1.0048
51.713
Mg/L

51.258
52.169
1.25
CCB
Mn
16-Jul-08
10:39:12
0.0483
1.965
M/L

2.229
1.702
18.97
80709.LB
Mn
16-Jul-08
11:11:44
0.0285
1.152
Mg/L

0.985
1.320
20.51
80709.LCS
Mn
16-Jul-08
11:18:31
0.9575
48.624
yg/L
2
48.144
49.104
1.40
80709.B-l
Mn
16-Jul-08
11:25:14
0.5476
24.955
yg/L

25.246
24.665
1.65
80709.11-1
Mn
16-Jul-08
11:31:57
0.5111
23.083
yg/i
20
22.881
23.285
1.24
80709.11-1
Mn
16-Jul-08
11:38:52
1.2508
69.323
yg/i
20 92.47
68.409
70.237
1.87
80709.12-1
Mn
16-Jul-08
11:46:54
0.8579
42.372
yg/L
10
42.494
42.249
0.41
80709.13-1
Mn
16-Jul-08
11:53:43
1.5765
97.514
yg/L
10
94.045
100.983
5.03
80709.21-1
Mn
16-Jul-08
12:00:36
1.3927
80.809
yg/L
10
80.065
81.552
1.30
CCV
Mn
16-Jul-08
12:07:33
1.0806
56.857
yg/L

56.691
57.023
0.41
CCV
Mn
16-Jul-08
12:14:30
1.0803
56.839
yg/L

57.342
56.335
1.25
46 of 58
-------
Instr. B
GFAA Raw Data
Corr. Coeff. 0.99987
Calib Blank
Mn
16-Jul-08
12:21:45
0.0832

m/l




18.32
Reslope
Mn
16-Jul-08
12:28:35
0.9167

m/l




3.24
CCV
Mn
16-Jul-08
12:39:14
0.9452
51.963
m/l


51.827
52.099
0.37
CCB
Mn
16-Jul-08
12:46:03
-0.0010
-0.037
m/l


1.047
-1.121
4164.00
80709.LB
Mn
16-Jul-08
12:52:47
-0.0388
-1.680
m/l


-0.686
-2.673
83.62
80709.LCS
Mn
16-Jul-08
12:59:31
0.9107
49.595
m/l
2

48.600
50.590
2.84
80709.B-l
Mn
16-Jul-08
13:06:13
0.4859
23.701
m/l


24.262
23.141
3.34
80709.11-1
Mn
16-Jul-08
13:12:57
0.4474
21.621
m/l
20

21.585
21.658
0.24
80709.11-1
Mn
16-Jul-08
13:19:53
1.1673
68.496
m/l
20
93.75
67.477
69.516
2.10
80709.12-1
Mn
16-Jul-08
13:26:39
0.8073
42.754
m/l
10

45.068
40.441
7.65
80709.13-1
Mn
16-Jul-08
13:33:26
0.9750
54.093
m/l
20

51.137
57.048
7.73
80709.21-1
Mn
16-Jul-08
13:40:18
1.3118
80.538
m/l
10

78.921
82.156
2.84
CCV
Mn
16-Jul-08
13:47:12
0.9709
53.771
m/l


54.363
53.180
1.56
CCB
Mn
16-Jul-08
13:54:01
0.0215
0.944
M/L


1.379
0.509
65.19
80709.22-1
Mn
16-Jul-08
14:00:52
1.0546
59.847
M/L
10

57.707
61.986
5.06
80709.23-1
Mn
16-Jul-08
14:07:47
1.3138
80.705
M/L
10

81.005
80.405
0.53
80709.B-2A
Mn
16-Jul-08
14:14:44
1.4368
91.933
M/L


90.326
93.541
2.47
80709.12-2A
Mn
16-Jul-08
14:21:41
1.4631
94.474
M/L


97.324
91.624
4.27
80709.12-2A
Mn
16-Jul-08
14:28:42
1.7716
128.141
M/L

67.33
122.320
133.963
6.42
80709.12-2A
Mn
16-Jul-08
14:45:29
0.9336
51.163
M/L
2

51.230
51.097
0.18
80709.12-2A
Mn
16-Jul-08
14:52:32
1.4465
92.881
M/L
2
83.43
89.864
95.897
4.59
80709.13-2A
Mn
16-Jul-08
14:59:35
1.0814
61.870
M/L
2

64.959
58.781
7.06
CCV
Mn
16-Jul-08
15:06:33
0.9740
53.990
M/L


53.784
54.197
0.54
CCB
Mn
16-Jul-08
15:13:24
0.0284
1.251
Mg/L


1.809
0.694
63.00
80709.21-2A
Mn
16-Jul-08
15:20:21
0.8898
48.188
yg/L
2

46.100
50.277
6.13
80709.22-2A
Mn
16-Jul-08
15:27:21
0.3645
17.579
yg/L
2

25.749
9.410
65.72
80709.23-2A
Mn
16-Jul-08
15:34:21
0.0704
3.126
yg/i
2

3.974
2.278
38.36
80709.22-2A
Mn
16-Jul-08
15:52:14
0.6988
35.954
yg/i
2

37.291
34.616
5.26
80709.23-2A
Mn
16-Jul-08
15:59:16
0.4391
21.176
yg/L
2

21.104
21.247
0.48
CCV
Mn
16-Jul-08
16:06:12
0.9120
49.677
yg/L


49.756
49.597
0.23
CCB
Mn
16-Jul-08
16:13:00
0.0215
0.944
yg/L


1.436
0.453
73.65
47 of 58
-------
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-------
Instr. A
GFAA Raw Data
Corr. Coeff. 0.99996
80709.13-1
Ni
16-Jul-08
13:26:41
0.1580
46.355
m/l
5
50.138
42.572
11.54
80709.21-1
Ni
16-Jul-08
13:34:03
0.1166
34.124
m/l
5
32.940
35.307
4.91
80709.22-1
Ni
16-Jul-08
13:41:26
0.1135
33.231
m/l
5
26.461
40.002
28.81
80709.22-1
Ni
16-Jul-08
13:48:48
0.0918
26.862
m/l
5
33.378
20.347
34.30
80709.23-1
Ni
16-Jul-08
13:56:13
0.9586
293.982
m/l
5
296.571
291.393
1.25
CCV
Ni
16-Jul-08
14:18:32
0.3194
94.552
m/l

93.712
95.393
1.26
CCB
Ni
16-Jul-08
14:25:45
0.0055
1.587
m/l

2.994
0.180
125.30
80709.13-1
Ni
16-Jul-08
14:41:26
0.2593
76.504
m/l
3
78.588
74.419
3.85
80709.21-1
Ni
16-Jul-08
14:48:46
0.2657
78.413
m/l
2
80.161
76.666
3.15
80709.22-1
Ni
16-Jul-08
14:56:09
0.3042
89.986
m/l
2
87.007
92.965
4.68
80709.23-1
Ni
16-Jul-08
15:16:09
0.2293
67.555
m/l
20
69.292
65.818
3.64
80709.B-2A
Ni
16-Jul-08
15:23:37
0.0555
16.198
m/l

16.289
16.108
0.79
80709.12-2A
Ni
16-Jul-08
15:31:07
0.0428
12.481
M/L

12.923
12.040
5.00
80709.12-2A
Ni
16-Jul-08
15:38:39
0.3661
108.640
M/L

96.15 108.684
108.596
0.06
80709.13-2A
Ni
16-Jul-08
15:46:10
0.0868
25.386
M/L

25.585
25.186
1.11
CCV
Ni
16-Jul-08
15:53:34
0.3412
101.131
M/L

97.915
104.347
4.50
CCB
Ni
16-Jul-08
16:00:47
0.0058
1.689
M/L

1.888
1.490
16.65
80709.21-2A
Ni
16-Jul-08
16:08:15
0.1035
30.291
Mg/L

32.191
28.390
8.87
80709.22-2A
Ni
16-Jul-08
16:15:48
0.1135
33.224
M/L

31.082
35.365
9.12
80709.23-2A
Ni
16-Jul-08
16:23:21
0.1034
30.268
Mg/L

34.273
26.262
18.71
80709.23-2A
Ni
16-Jul-08
16:30:54
0.1029
30.094
yg/L

33.090
27.097
14.08
CCV
Ni
16-Jul-08
16:38:20
0.3316
98.220
Mg/L

97.045
99.396
1.69
CCB
Ni
16-Jul-08
16:45:35
0.0002
0.057
Mg/L

-0.789
0.902
2116.00
49 of 58
-------
Instr. I
Sampl
Calib E
20 ppfc
50 ppfc
100 pp
200 pp
ICV
ICB
80705
80705
80705
80705
80705
80705
80705
80705
CCV
CCB
80705
80705
80705
80705
CCV
CCB
80613
80613
80613
80613
80613
80613
80613
80613
CCV
CCB
80613
80613
80613
GFAA Raw Data
Corr. Coeff. 0.99962
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Ur
Se
1 7-Jul-08
8:51:59
0.0035

m/l
Se
1 7-Jul-08
8:59:16
0.0472

M/L
Se
1 7-Jul-08
9:06:38
0.1051

M/L
Se
1 7-Jul-08
9:14:04
0.2108

M/L
Se
1 7-Jul-08
9:21:33
0.4108

M/L
Se
1 7-Jul-08
9:29:51
0.2019
97.564
M/L
Se
1 7-Jul-08
9:37:07
-0.0032
-1.552
M/L
Se
1 7-Jul-08
9:44:34
-0.0077
-3.718
M/L
Se
1 7-Jul-08
9:52:08
0.2012
97.212
M/L
Se
1 7-Jul-08
9:59:38
-0.0128
-6.183
M/L
Se
1 7-Jul-08
10:07:07
0.0007
0.339
M/L
Se
1 7-Jul-08
10:14:38
0.1950
94.219
M/L
Se
1 7-Jul-08
10:22:04
-0.0088
-4.229
M/L
Se
1 7-Jul-08
10:29:27
-0.0015
-0.725
M/L
Se
1 7-Jul-08
10:36:48
0.0001
0.046
M/L
Se
1 7-Jul-08
10:44:12
0.2067
99.900
M/L
Se
1 7-Jul-08
10:51:28
0.0001
0.025
M/L
Se
1 7-Jul-08
10:58:45
-0.0038
-1.815
M/L
Se
1 7-Jul-08
11:06:16
0.2095
101.210
M/L
Se
1 7-Jul-08
11:13:31
0.0017
0.845
M/L
Se
1 7-Jul-08
11:20:44
-0.0015
-0.705
M/L
Se
1 7-Jul-08
11:28:06
0.2078
100.423
M/L
Se
1 7-Jul-08
11:35:22
0.0076
3.676
M/L
Se
1 7-Jul-08
12:03:09
-0.0003
-0.165
Mg/L
Se
1 7-Jul-08
12:10:41
0.1892
91.430
M/L
Se
1 7-Jul-08
12:18:13
0.0018
0.852
Mg/L
Se
1 7-Jul-08
12:25:41
0.2364
114.244
yg/L
Se
1 7-Jul-08
12:33:10
0.2137
103.281
Mg/L
Se
1 7-Jul-08
12:40:35
0.0012
0.580
Mg/L
Se
1 7-Jul-08
12:47:58
0.0304
14.693
m/l
Se
1 7-Jul-08
12:55:29
0.2517
121.635
Mg/L
Se
1 7-Jul-08
13:02:55
0.2072
100.098
Mg/L
Se
1 7-Jul-08
13:10:10
0.0055
2.657
Mg/L
Se
1 7-Jul-08
13:17:26
0.0500
24.167
Mg/L
Se
1 7-Jul-08
13:24:41
0.0222
10.736
m/l
Se
1 7-Jul-08
13:31:54
-0.0067
-3.249
Mg/L
94.21
101.2
5
20
106.9
Std_U 1
Std_U 2
RSD


81.04


22.21


0.12


1.86


1.45
95.126
100.003
3.53
-3.211
0.106
151.10
-1.281
-6.155
92.68
99.303
95.120
3.04
-7.068
-5.298
20.23
-2.009
2.688
978.50
92.875
95.563
2.02
-1.823
-6.635
80.46
-3.961
2.511
631.00
2.176
-2.085
6595.00
103.501
96.299
5.10
1.032
-0.982
5778.00
-2.331
-1.299
40.20
102.471
99.948
1.76
-0.179
1.869
171.30
-0.917
-0.493
42.46
99.639
101.206
1.10
3.292
4.060
14.78
4.137
-4.467
3690.00
86.442
96.417
7.71
1.668
0.035
135.50
111.865
116.622
2.94
104.687
101.874
1.93
2.719
-1.559
521.60
15.197
14.189
4.85
121.615
121.655
0.02
100.291
99.906
0.27
2.233
3.081
22.56
25.733
22.600
9.17
9.461
12.010
16.78
-2.357
-4.142
38.84
50 of 58
-------
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U U
-------
Instr. A
GFAA Raw Data
Corr. Coeff. 0.99986
Sample_ID
EL
Sam_Date
Sam_Time Mean Sig
Mean_ST
Cal_Units
Dilu Rec
Std_U 1
Std_U 2
RSD
Calib Blank
Ag
1 7-Jul-08
7:55:40
0.1462

yg/L



2.23
5 ppb Ag
Ag
1 7-Jul-08
8:03:04
0.1157

yg/L



2.56
10 ppb Ag
Ag
1 7-Jul-08
8:10:37
0.2297

yg/L



0.13
20 ppb Ag
Ag
1 7-Jul-08
8:18:11
0.4375

yg/L



0.62
30 ppb Ag
Ag
1 7-Jul-08
8:25:48
0.6437

yg/L



0.23
ICV
Ag
1 7-Jul-08
8:36:04
0.4479
20.264
yg/L

20.053
20.475
1.47
ICB
Ag
1 7-Jul-08
8:43:27
-0.0018
-0.076
yg/L

0.091
-0.243
310.00
80705.LB
Ag
1 7-Jul-08
8:51:03
0.0005
0.022
yg/L

-0.025
0.069
301.10
80705.LCS
Ag
1 7-Jul-08
8:58:44
0.4544
20.584
yg/L
5
20.447
20.720
0.94
80705.B-l
Ag
1 7-Jul-08
9:06:24
0.0201
0.859
yg/L

1.111
0.607
41.51
80705.12-1
Ag
1 7-Jul-08
9:14:03
0.0525
2.250
yg/L

2.279
2.222
1.81
80705.12-1
Ag
1 7-Jul-08
9:21:39
0.2217
9.699
yg/L
74.48
9.403
9.996
4.32
80705.12-1
Ag
1 7-Jul-08
9:31:48
0.0249
1.064
yg/L
2
1.091
1.037
3.60
80705.12-1
Ag
1 7-Jul-08
9:39:24
0.1984
8.657
yg/L
2 75.93
8.499
8.815
2.58
80705.13-1
Ag
1 7-Jul-08
9:47:00
0.0034
0.147
yg/L
2
0.048
0.245
95.17
CCV
Ag
1 7-Jul-08
9:54:34
0.4373
19.750
yg/L

19.713
19.787
0.27
CCB
Ag
1 7-Jul-08
10:01:56
-0.0015
-0.065
yg/L

0.062
-0.193
275.70
80705.15-1
Ag
1 7-Jul-08
10:09:24
0.0508
2.178
yg/L
2
2.132
2.223
2.96
80705.B-2A
Ag
1 7-Jul-08
10:16:54
0.0009
0.037
yg/L

0.251
-0.177
823.20
80705.12-2A
Ag
1 7-Jul-08
10:24:23
0.0267
1.140
yg/L

1.078
1.203
7.75
80705.12-2A
Ag
1 7-Jul-08
10:32:00
0.2054
8.969
yg/L
78.28
8.859
9.079
1.74
80705.13-2A
Ag
1 7-Jul-08
10:39:26
0.0298
1.275
yg/L

1.353
1.197
8.62
80705.15-2A
Ag
1 7-Jul-08
10:46:50
0.0273
1.167
yg/L

1.225
1.108
7.11
CCV
Ag
1 7-Jul-08
10:54:19
0.4362
19.700
yg/L

19.710
19.691
0.07
CCB
Ag
1 7-Jul-08
11:01:43
0.0016
0.070
yg/L

0.180
-0.039
220.40
IQC20
Ag
1 7-Jul-08
11:11:11
0.4163
18.741
yg/L

18.472
19.010
2.03
80709.LB
Ag
1 7-Jul-08
11:18:52
-0.0011
-0.049
yg/L

0.081
-0.178
374.80
80709.LCS
Ag
1 7-Jul-08
11:26:33
0.4299
19.394
yg/L
5
19.496
19.292
0.74
80709.B-l
Ag
1 7-Jul-08
11:34:12
0.0104
0.445
yg/L

0.554
0.337
34.43
80709.11-1
Ag
1 7-Jul-08
11:41:48
0.1330
5.756
yg/L
2
5.705
5.808
1.27
80709.11-1
Ag
1 7-Jul-08
11:49:25
0.2607
11.475
yg/L
2
9.895
13.056
19.47
80709.11-1
Ag
1 7-Jul-08
11:57:00
0.2953
13.053
yg/L
2 72.96
12.877
13.228
1.90
80709.12-1
Ag
1 7-Jul-08
12:04:32
0.1154
4.982
yg/L
2
4.894
5.070
2.50
CCV
Ag
1 7-Jul-08
12:12:07
0.4398
19.872
yg/L

19.990
19.753
0.84
CCB
Ag
1 7-Jul-08
12:19:31
0.0014
0.061
yg/L

0.154
-0.032
216.90
80709.13-1
Ag
1 7-Jul-08
12:26:57
0.0658
2.827
yg/L
2
2.859
2.794
1.63
52 of 58
-------
Instr. A
GFAA Raw Data
Corr. Coeff. 0.99986
80709.21-1
Ag
1 7-Jul-08
12:34:26
0.0687
2.949
Mg/L
2

3.114
2.785
7.89
80709.22-1
Ag
1 7-Jul-08
12:41:52
0.1003
4.321
yg/L
2

4.226
4.417
3.12
80709.11-1
Ag
1 7-Jul-08
12:52:43
0.0961
4.138
yg/L
3

4.008
4.267
4.42
80709.11-1
Ag
1 7-Jul-08
13:00:20
0.2645
11.639
yg/L
3
75.01
11.543
11.736
1.17
80709.12-1
Ag
1 7-Jul-08
13:12:20
0.1521
6.625
yg/L
3

9.818
3.431
68.17
80709.12-1
Ag
1 7-Jul-08
13:19:51
0.0752
3.232
yg/L
3

3.315
3.150
3.61
80709.13-1
Ag
1 7-Jul-08
13:27:23
0.0437
1.871
yg/L
3

1.974
1.768
7.80
CCV
Ag
1 7-Jul-08
13:34:58
0.4459
20.169
yg/L


19.964
20.374
1.44
CCB
Ag
1 7-Jul-08
13:42:21
0.0030
0.127
yg/L


0.171
0.084
48.04
80709.21-1
Ag
1 7-Jul-08
13:49:46
0.0437
1.872
yg/L
3

1.788
1.955
6.33
80709.22-1
Ag
1 7-Jul-08
13:57:13
0.0696
2.988
yg/L
3

2.947
3.028
1.92
80709.23-1
Ag
1 7-Jul-08
14:04:37
0.0997
4.297
yg/L
3

4.283
4.311
0.47
80709.B-2A
Ag
1 7-Jul-08
14:12:00
0.0189
0.807
yg/L


0.787
0.826
3.37
80709.12-2A
Ag
1 7-Jul-08
14:19:20
0.0136
0.580
yg/L


0.588
0.572
1.97
80709.12-2A
Ag
1 7-Jul-08
14:26:53
0.1952
8.514
yg/L

85.14
8.279
8.749
3.91
80709.13-2A
Ag
1 7-Jul-08
14:34:14
0.0176
0.752
yg/L


0.843
0.660
17.12
80709.21-2A
Ag
1 7-Jul-08
14:41:40
0.0122
0.521
yg/L


0.599
0.443
21.20
CCV
Ag
1 7-Jul-08
14:49:15
0.4407
19.917
yg/L


19.641
20.193
1.96
CCB
Ag
1 7-Jul-08
14:56:38
-0.0015
-0.065
yg/L


-0.115
-0.014
110.70
80709.22-2A
Ag
1 7-Jul-08
15:04:04
0.0045
0.190
yg/L


0.224
0.157
25.00
80709.23-2A
Ag
1 7-Jul-08
15:11:36
0.0106
0.452
yg/L


0.512
0.392
18.78
CCV
Ag
1 7-Jul-08
15:19:11
0.4407
19.917
yg/L


19.842
19.992
0.53
CCB
Ag
1 7-Jul-08
15:26:34
0.0095
0.405
yg/L


0.495
0.315
31.43
53 of 58
-------
BOTO^t fl\t?££A)£S	^
P E R K IN -- E L M E R M 110 0	©8/0 7 /' 16 F' A 6 E ^ 1
sr r- ^ == se ss: ss ~~ n: sz ==: r:s zz :s2 zz r= ;=: jss s= :rr sz =3 =r is: zz ~ zs s= ~= ur:--	:::= ™ -::: ss: ~:r. zz zz:.r ^ ;=: rr ss r~ —: :"n r.~ =:- r.r: ;r.; --- r= ™ ~~
H8	AA-BG BG
MAIN: 0,001	PA 0,. 027 0.067
Pl-I 0.001 0.003
;::: :zz -:: zz zz: :::~:r_ :u::::- ^:r::-:::: :=:: :::::zz zz: ::r: z:z zz z:z::::: -::: :::z zz: :::z :z:\ :::z:zz :::z:::::	:::_zz == zz zz ss s: zs zz zz: :zz rss zz zz zz zz rs zs z= ss =: =.- ™ ~ zz sr.: rr: =5
0. O 0 0 A U T 0 Z E R 0
:::.:::"::::: :n::	~~ :;:n i;::: u:" ":::~r. r»; ~~ zz zz zz ™ ™ ~ ~ ™ zz: stn zz un: zz zz zz zz: zz zz ~ — ~ zz zz zz zz zzz zz zz zz :^z zz zzz ™ ™ zz zz zzz zz: zz zz zzt zs. zn ss: zzz zsi zzz zzz
HG	AA-BG BG
MAIN:: 0.012	PA 0.214 -0.023
PH 0.012 -0.002
zzzz:zzzz:izz~zzz:,.zz7.z.zzzzizizzz:zz:zz:zz:z:ztzzzz:*.zzzz;zz.zzzz:zz:zz:zz:zz:zz:zz:zz:zz::zz~zzzzz: = ss:s=:=n:c:srs2s:=s;ss::=s=:=;=2su:ss2s=s:=i:=s:sri2r:ss~sr:s
0.50 1.STANDARD
^::	zz: zz: zz: zz: "z zz: zz: zz: zz: zz: z:z zz -zz: -zr, :zz zz zz zz zz: zz. zz: zz zzz zz zz zzz z:z zz zz zz zz zz zz: zz r~: zz zzi zz ^ zz. ~ =3 zz ~= zz zzz zz zzz zz zz ~ = ss zz zz: z
HG	AA-BG BG
MAIN: 0.85 UG/L PA 0.438 0.013
PH 0.02 i 0.001
zz ™~zz :zz zz zzz ~rz ~z zzz zz: zz: z^ s: zz :zz :zz tzz zz izz z:z :zz :ss zz n;r ™ zz tzz zz: zz zz zz: zz ™ n^: zz: zz: ~ ~ =: zz zz zz ™ zz: zz ™ zz: zz ~ ~ sz ~ ~ ~ ~ zs zz zz zz ~ rr ~ zz zz ~ zz zz
E"61 Sample concentration greater than highest standard
~r -- r= zz zz zz zrz z:; zz z~ zz zz :.™ :zz :zz :zz r™:.™ :sr r: n-- :::r:::: -r r= ru; rr zz :zz zz ::z :zz zz :zz :zz zz ;zz z:z zz, ::r ™ zz: zz: zz zz zz zz zzrr -=::~ :=: :z= = zz; zz zzzzzzzzzzzzzzzz
1.00 2.STANDARD
HG	AA-BB BG
MAIN; 5.89 UG/L PA 0.899 -0.018
PH 0.052 -0.001
zzzzzz zz zz zz zz zz: ir.z zr. ::z zzzzzzz:z:zzzz:zz zz zz zz:zz z^z zz ;zz zz zz zz:-zz zz ::zrzzzzzzzz:zzzzzz:zzzz:zzzzzzzz:z:zzz:zzzzzz:zz:zzzzzzzzzz:zz:zz:zzzzzzzz:zz:zzzzzzzzzz:zzzzzz
E61 Sample concentration greater than highest standard
zrzzz zz ":r :.-rr -= _™ rzz zz zz zz zz: z:r. :zz zz zz :zz zz -r zz: zz zzzzzz z:z zx zz zz :zz:zz zz zz zz s:: z~ -s: zzzz:zz:zzzzz:zzzzzzz:zzzzzzzzz2zz;zz:zzzz:zzz:zzzzzzzzzzz:zzzzzzzz
2.06 3.STANDARD
~r. zz zz: zz zz zz zz: zz: zz: zz zz: zz: zz: zz: zz: zz zz: zz n:::::::: zx zz. zz: zzzzzz zz:::: zz zz zz zz zz: -:: zz zz zz zz zz: zz zz: zz: zz:zzzz sr.::::: zz: nr: zz zz zzzzzzzz:zzzzzz:zz:zzzzzz:zzzzzz
HG	AA-BG BG
MAIN: 4.59 UG/L PA 2.468 0.033
PH 0.132 0.002
zz zz zzzz zz :zz zz z:z :zz zz zz :z: zz zz :zz :zz zz: zz zz zz zz :zz zz :zz zz zz zz zz: ::z z:: zz: zz: :zz zz zz zz: zz zz zz zz zz zz :zz zz zz zz z:z zz zz zz ::z rj: zz z:z zz:zzzz ?zz zz zz zz: zz zz. r_-r zz zz: zz
E61 Sample concentration greater than highest standard
~ zz izz :zz :zzzz^rr.zz zz zz zz :zz zz zz zz zz: zz: zz in: zz: zz: z:z zz zz :zz zz zz zz :zz ::z zz zz zz ur:: zz: zz zz z:z zz :zz zz zz zz zz zz vsz zz zz zz zz rr zz zz zz zz zz zzzz zzz zs
4.97 4.STANDARD
zz zzzzzz zz zz zz: sr. rr zz -t:: zz zz zz zz zz zz. rt:: zz zz: zz: r^: zz: ™ :zz zz zz zz zz 'zz zz::™. zz: zz: zz zz: ?zz zz rr zzz zz:zss tzz zz zzr, zz: zz: zz zs zz zz zz zz zz: zz zz zz zzr. zz zz zz zr. zz zz zz
HG	AA-BG BG
MAIN: 8.65 UG/L PA 4.469 0.048
PH 0.254 0.000
v.?, j:; zz zz z:z :z: :rzz:: --z zz :zz :::z z:z zz :zz zz :zz :zz :zz :zz zz zz: z:z zz: zz zz r.zzz:zzzz:.?zzx: zz: zz: zzzzzzzzz :zz zzzzzz^: zzzzzz zzzzzz zz zz zz zzzzzz zzzzzz zzzzzz zzzzzz
E 61 S a m p 1 e c o n c e n t r a* t i cs n g r e a t e? r than f»i q h e s t s t a n d at r d
::::: r:" n~ zz zz: :zz ™ »:r :;u::::~ zz::::: :zz ::r. zz zz :zz zzz zz:~ z:z :zz zz ™ zz :z:zz: zz™: zz: zzz zz zz zz zz zz zz zz:zz — :z: :zz :zz ^ :r" int.* z:: ~zz zz zz zz zz zz zz zz zzzzzz: zz
9.74 5.STANDARD
54 of 58
-------
PERKIN-ELMER	M 1100	@6/07/16 PAGE
HGh DISPLAY CALIBRATION MODE
r*i	i*r . i ir»
c.uc.ric.r* i i n\3
r^r'Ai/ i ir- t r«i it
rc.nr% HLIOTI
PRINTER:	ON
rsr* r>/\rin.	Ak!
DS3 wn.n i	VIM
UN1T5 ;	U0/L
CH.MASS;
^"1 A
y. Y4
0.254
ABS.
si
r PEAK AREA tn\
HS
MAIN:
HG
MAIN:
AA-BG BG HG
5.24 UG/L. PA 2.186 -0.035 MAIN;
PH 0.134 -O.003
XCS	AA-BG BG
-0.09 UG/L PA—O.009 -0.026
P H -0. 002 - O. O 01
— I	AA—BG BG Hu
-0.16 UG/L PA—0.032 -0.108 MAIN;
PH-0.004 —0.006
HG	|\r \	AA-BG BG HG
MAIN: -0.14 UG/L PA-O,024 -0.046 MAIN:
PH-O.004 -0.002
AA-BG BG
-0.09 UG/L PA-O.008 -0.077
PH-O.002 ~0.005
AA—BG BG
-0.16 UG/L PA—0.013 -0.087
PH-O. 004 --0. 006
HG	\1-~\	AA-BG BG HG
MAIN: -0.11 UG/L PA-O.040 -0.058 MAIN:
PH-O.003 -0.004
AA-BG BG
-0.11 UG/ L... PA-0.014 -0. 075
P H—0. O03 --0. 004
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
-0.02 UG/L
24-1
-0.02 UG/L
AA-BG BG HG
PA-0. 008 —0 ..111 MAIN:
PH-O.000 —0.006
AA-BG BG HG
PA 0.020 -0.062 MAIN;
PH-O.000 -0.003
AA-BG BG	HG
0.00 UG/L PA O.054	-0.094	MAIN;
PH 0.000	-0.004
2"?"*	AA-BG BG	HG
0. 08 UG/L. PA 0.058 -0. 088	MAI N;
PH 0.002 -0.005
hg *B>-Z£
MAIN; -0.03 UG/L
A A—BG
PA—O.003
PH-O.001
. HG	COb	AA-BG
W MAIN; -0.13 UG/L. PA-O. Oil
PH-O.003
BG	HG
-0.077	MAIN;
-0. 005
BG	HG
<:56%f'S8	MAIN;
0. 000
AA-BG BG
-0.06 LJG/L PA-O. 012 -0.073
P H-0.002 -0.005
AA-BG BG
-0.03 UG/L PA 0.031 -0.028
PH-O.001 -0.002
AA-BG BG
0.17 UG/L PA 0.065 -0.120
PH 0.004 -0.005
AA—BG BG
- 0.11 U G /1... P A 0. 017 - 0.074
P H - O» 003 ~ 0. 0 O 4
CjCM	AA-BG BG
5.00 UG/L PA 2,225 -0.082
PH 0.128 -0.005
AA-BG BG
-0.08 UG/L PA-O.022 -0.075
PH-O.002 -0.005
-------
PERKIN-ELMER
M 1100
08/07/16
PAGE"

4/
loml
H6
MAIN:
HG
MAIN!
1-1G
MAINs
HG
MAINs
HG
MAIN:
HG
MA IN s
Hti
MAIN:
HG
MAIN:
HG
MAIM:
HG
MAINs
He
MAIN:
12--Z&	AA-BG BG
-0.02 UG/L PA--0. 015 -0.101
PH-0.000 -0.005
\Z'2^>	AA-BG BG
5.22 UG/L PA 2.674 -0.030
PH 0.134 -0.002
MAIN:
HG
MAIN:
AA-BG BG HG
	0. 1 1 UG/L PA--0.054 -0.047 MAIN:
PH-0.003 -0.003
AA-BG BG HG
PA-O.O01 -0.041 MAIN:
P H - 0. O O 2 - 0. O O 2
-0.08 UG/L
AA-BG	BG HG
0.19 UG/L PA 0.112	-0.134 MAIN:
PH 0.005	-0.006
2 AA-BG	BG HG
0.00 UG/ L PA 0.032	•-0. 090 MAIN:
PH 0.000	-0.005
A A—B G	Bl-j HG
-0.13 UG/L PA-0.041	-0.078 MAIN;
PH-0.003	-0.004
AA—BG Bl-j
0.00 UG/L PA-O.009 -0.102
PH 0.000 -0.006
AA-BG BG
5.24 UG/L PA 2.485 -0.030
PH O.134 -0.004
AA—BG BG
-0.06 UG/L, PA-O. 012 -0.092
P H - 0 . 002 -0, 005
AA-BG BG
0.00 UG/L. PA 0.015 -0.066
PH 0.000 -O.004
AA-BG BG
0.16 UG/L PA 0.114 -0.118
PH 0.004 -0.006
AA—BG BG
-0.05 UG/L PA 0.039 -0.090
P H -0. 001 -0. 006
Ccv
5.50 UG/L
AA-BG BG HG
PA 2.252 -0.010 MAIN;
PH 0.141 -0.001
AA-BG BG
-0.17 UG/L PA-O.066 -0.072
P H -0. 004 -0. 003
CO 13	AA-BG BG
0.03 UG/L PA-O.037 -0.004
PH 0.001 0.000
j \-\? ^	AA—BG BG	HG
-0.05 UG/L PA 0.001 -0.093	MAIN-.
PH-0.001 -0.005
12-3/*"	AA-BG BG	HG
-0.09 UG/L PA-O.021 -0.065	MAIN:
PH-0.002 -0.004
>3-^3 A	AA-BG BG	HG
-0.08 UG/L PA-O.017 -0.059	MAIN:
PH-0.002 -0.004
AA-BG BG
-0.06 UG/L PA 0.020	-0.118
PH-0,002	-0.008
AA-BG BG
¦0.05 UG/L PA-O.021	-0.110
PH-0.001	-0.006
AA-BG BG
-0.19 UG/L PA-0.041	-0.092
PH-0.005	-0.001
HG
MAINs
HG
MAIN:
2 on I
HG
MAIN:
HG
MAIN;
AA-BG BG	HG
-0.06 UG/L PA~0.Oil	-0.049	MAIN:
PH-0.002	-0.001
(K	AA-BG* BG	HG
-0.14 UG/L PA-O.015	-0.1O4	MAIN:
PH-0.004	-0.004
-0.13 UG/L
AA—BG E<0 HG
PA-O.044 -0.036 MAIN:
PH-0.003 -0„002
8"2>B	AA-BG BG HG
-0.11 UG/L PA-O.012 -0.101 MAIN:
PH-0.003 -O.004
56 of 58
/% /\ r*-, r*\	j-~. r—.
A h B G BG
-u.11 UG/L PA-O.U43 —O¦o69
P H -0. 003 -0. 004
AA—BG BG
-0.05 UG/L PA 0.005 -0.076
P H - 0 . 0 01 - 0. 0 O 3
AA-BG bfc
-0.11 UG/L. PA 0.010 -0.142
PH-0.003 -0.006
AA-BG BG
-0.02 UG/L PA 0.013 -0.121
P H—O. O O O — O. O O 7
-------
PERK 1 N-EL.MER
M 1100
08/07/16 PAGE 4
, HG
ZOrM MAIN:
\K
5m i
HG
MAIN:
HG
MAIN:
MAIN;
HG
MAIN:
HG
MAIN;
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
HG
MAIN:
U-33	AA-BG BG	HG
0. 14 UG/ L PA-0. 009 --0. 090	MAINs
F'H 0.004 -0.004
QC&	AA-BG BG	HB
-0.11 UG/L PA 0.004 -0.073	MAIN:
P H -0.003 -0. O 0 4
I "2-"33-	AA-BG BG	HG
-0,05 UG/L PA-0.016 -0„081	MAIN:
PH-0.001 -0.005
l"B>"3 B	AA-BG BG	HG
-0.06 UG/L PA—O.017 -0.085	MAIN:
PH-O.002 -0.005
2-\~3&>	AA-BG BG	HG
-0. 14 UG / L. PA 0. 010 -0. 063	MA IN:
PH-O.004 -0.004
AA-BG BG	HB
-O.O0 UG/L PA 0.002 -0.120	MAIN:
PH-O.002 -0.005
-23 -33	AA-BG BG	HB
0.02 UG/L PA 0.019 -0.111	MAIN:
PH 0.000 -0.006
B-S	AA-BG BG	HG
0.03 UG/L PA 0.013 -0.146	MAIN:
PH 0.001 -0.008
W3C-	AA-BG BG	HG
-0.02 UG/L PA 0.032 -0.124	MAIN:
PH-O.000 -0.006
CO V	AA-BG BG	HG
5.13 UG/L PA 2.303 -0.021	MAIN:
PH 0.131 -0.002
CCV	AA-BG BG
5.27 UG/L PA 2.336 -0.028
PH 0.135 -0.003
U-"2>S	AA-BG BG
-0.11 UG/L PA-0.027 -0.095
PH-O. 003 ~0. 005
AA-BG	BG
-0.13 UG/L PA-0., 050	-0.103
PH-O.003	-0.005
AA-BG	BG
-0.03 UG/L PA~0.013	-0.132
PH-O.001	-0.008
AA-BG	BG
-0. 13 UG/ L.. PA-0. 010	--0. 092
PH-O.003	-0.005
AA-BG	BG
0.09 UG/L PA 0.023	-0.151
PH 0.002	—0.006
AA-BG	BG
-0.05 UG/L PA 0.004	-0.122
PH-O.001	~0.006
AA~BG	BG
- 0. 0 3 UG/L. PA - 0.014	- 0. 0 7 3
PH-O.001	-0.003
AA-BG	BG
-0.06 UG/L PA 0.014	-0.139
PH-O.002	-0.008
CO(3 AA-BG	BB
-0.08 UG/L PA-0.018	-0.040
PH-O.002	-0.000
AA-BG BG	HG
-O.05 UG/L PA 0.005	-0.115	MAIN;
PH-O.001	-0.005
AA-BB BG	HG
0.03 UG/L PA 0.046	-0.142	MAIN:
PH 0.OO1	-0.006
AA—BG BG	HG
1.45 UG/L PA 0.642 0.019	MAIN:
PH 0.03.7 0.000
AA-BB BG	HG
2.77 UG/L PA 1.169	-0.100	MAIN:
PH 0.071	-0.004
AA-BG BG
0.06 UG/L PA 0.006 -0.123
PH 0.002 -0.006
AA-BG BG
O.00 UG/L PA 0.029 -0.099
PH 0.000 -0.004
AA-BG BG
1.25 UG/L PA 0.572 -0.023
PH 0.032 -0.004
AA-BG BG
2.47 UG/L PA 1.068 -0.051
PH 0.063 -0.003
, HG	Z- 9AA-BG BG HG
M/ MAIN: 0.53 UG/L PA 0.229 -0.037 MAIN:
PH 0.014 -0.002
57 of 58
AM—BG BG
0.61 UG/L PA 0.275 -0.106
PH O.O16 —O.UU4
-------
PERKIIM-ELMER	M 1100	©8/07/16 PAGE
HG	C^v	AA-BG BG HG	QG&	AA-BG BG
5.09 UG/L PA 2.321 -0.063 MAIN; -0.16 UG/L PA-0.027 -0.050
PH 0.130 -0.002	PH-0.004 -0,002
If—I .
58 of 58
-------
Datafile: e: 080729V21 J Client ID: MB1_6042_PAH_SDS'
Acquired: 29 Jul 2008 23:03:35 X Lab ID: MB1_6042_PAH_SDS
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
Actual
Name	RT
Naphthalene	8. 59 •/"
2-Methylnaphchalene	9,75 S
Acenaphthylene	11.54/"
Acenaphthene	11.90
Fluorene	13.02/
Phenanthrene	15.24 f
Anthracene	15.37
Fluoranthexie	18.12/'
Pyrene	18.68 /
Benzo(a)Anthracene	21.60 /"
Chrysene	21.72 /
Benzo(b)Fluoranthene	24,91
Benzo(k)Fluoranthene	- /
Benzo(e)Pyrene	25.94 /"
Benzo(a)Pyrene	26.15 ^
Perylene	- /
Indeno(1,2,3-cd)Pyrene	- ¦/""
Diben z o(a,h)Anthracene	- /
Benzo(ghi1Perylene	33.27 /
PAH Ax
0.6
-1,0
QC
~
ES/SS
4.0
-0.6
Pred
RRT
1.0004
1.0003
1.0003
1.0003
1.0003
1.0002
1.0002
1.0002
1.0001
1.0001
1.0001
1,0001
1.0001
1.0001
,0001
.0042
.0002
, 0002
1,
1.
1.
1,
1.0004
Analytical Perspectives
Wt/Vol: 1 Train
J Level: 4.ng/Trai
fttlOl/
ICAL: MM6_FAH_080118_18JAN08
Nominal ES spike: 40 ng-
Checkcode;
px-^kJ
Actual
RRT
Diff
Sees
Response
m
"j^£aS- Conc
RHP ,ng/Train
Noise

DL
1.0004
0
8.39E+07
-
1.09^
' 814
2.03E+04
0
60200
1.0003
0
3.80E+06
-
1.11
44.1
1.38E+04
0
53500
1.0003
0
8.99E+04
-
0.86
0.816
8.69E+03
0
29400
1.0003
0
3.65E+05
-
1.00
4. 56
8.75E+03
0
40800
1.0000
+ 0.4
3.66E+06
-
1.05
48.3
6.82E+03
0
35300
1.0002
0
4.01E+06
-
1.12
29.4
1.08E+04
0
32300
1.0002
0
1.70E+05
-
1.09
1.39
1.08E+04
0
34300
1.0001
-0.1
1.44E+06
-
1.02
9.76
1.45E+04
0
41000
4.0001
0
7.90E+05
-
1.03
4.24
1.45E+04
0
30500
0.9993
-1.0
1.28E+05
-
1.00
1.17
4.70E+03
0
20600
1.0000
-0.1
1.02E+05
-
1.11
0.91
4.70E+03
0
22800
1,0005
+ 0.6
2.16E+05
-
0.99
1.72
4.96E+03
0
27100
-

-
-
0.90
ND
4.96E+03
0
30300
0,9999
-0.3
6.91E+04
-
0.93
0.557
4.96E+03
0
30700
0.9998
-0.5
1.05E+05
-
0.86
1
4.96E+03
0
42700
-

-
-
0.90
ND
4.96E+03
0
49200
-

-
-
0.93
ND
3.95E+03
0
73300
-

-
-
0.89
ND
3.18E+03
0
77200
1.0006
+ 0.4
1.07E+05
-
0.95
1.21
3.95E+03
0
67500


Page 1 of 2
Printed: 8/5/2008 2:29 PM
-------
Datafile: e: 080729V21
Client ID: MB1_6Q42_PAH_SDS
Lab ID: MB1 6042 PAH SDS
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift jsecsi
PAH Ax
0.6
-1.0
ES/SS
4.0
-0.6
Name
Actual
RT
Fred
RKT
13 C6-Naphthalene
13 C6-2-Methylnaphthalene
13 C6-Acenaphthylene
13C6-Acenaphthene
13C6-Fluorene
13C6-Phenanthrene
13C6-Anthraeene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a!Anthracene
13 C6-Chrysene
13C6-Benzo(b)Fluoranthene
13C6-Benzo(k)Fluoranthene
13C4-Benza(e)Pyrene
13C4-Benzo(a)Pyrene
dl2-Perylene
13C6-Indeno(1,2,3-cd)Pyrene
13C6-Dibenzo(ah!Anthracene
13C12-Benzo(ghi)Perylene
8.58
9.75
11.54
11.89
13.01
15.24
15.36
IB. 12
18.68
21.61
21.72
24.90
25.03
25.94
26.16
26.38
31.63
31.85
33 .26
0.8857
1.0063
0.9757
1.0057
1.1002
1.2890
1.2995
0.9724
1.0025
1.1602
1.1656
0.9557
0.9597
0.9956
1.0040
1.0124
1.2143
1.2217
1.2766
AS--Anthracene
15.32
1.2897
SS-Fluorene
SS-Terphenyl
12.94
19.03
0.9949
1.0506
JS-Methylnaphthalene
JS-Acenaphthene
JS-Pyrene
JS-Benzo(a)Pyrene
9.69
11.83
18.63
26.06
Analytical Perspectives
Wt/Vol: 1 Train
ICAL: MM6 PAH 080118 18JAN08
Actual
RRT
0.8858
1.0063
0,9758
1.0058
1.1002
1.2889
1.2993
0.9724
1.0025
1.1601
1.1655
0.9556
0.9603
0.9955
1.0037
1.0123
1.2139
1.2221
1.2765
Diff
Sees
+0.1
0
+0.1
+0.1
0
-0.1
-0.1
0
0
-0.1
-0.1
-0.2
+0.9
-0.2
-0.5
-0.2
-0.6
+0.6
-0.2
Response
3.79E+06
3.10E+06
5.13E+06
3.21E+06
2.88E+06
4.88E+06
4.49E+06
5.79E+06
7.22E+06
4.37E+06
4.04E+06
1.02E+07
1.24E+07
1.07E+07
9.73E+06
7.58E+06
6.08E+06
6.53E+06
7.48E+06
Ra
RRF
1.51
0.96
1.79
1.06
1.11
1.76
64
25
30
06
02
21
60
30
39
1.36
0.81
1.00
1.15
Recv.
69.9
90.4
94.8
99.9
85.7
91.6
90.7
91.5
109.0
81.4
78.3
106.0
98.2
103.0
87.9
70.1
95.0
82.5
81.8
1.2953
+4.0
4.07E+06
1.44
93.6
0,9949
1.0505
0
-0.1
3.01E+06
3.Q1E+06
3,59E+06
3.03E+06
5.08E+06
3.97E+06
0.96
0.54 /
109.0
97.1
Page 2 of 2
Printed: 8/5/2008 2:29 PM
-------
AP Lab ID: MB1_6042_PAH_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PAH_SDS
VSIR expt; pah_db5_0801 GC: pah_db5-SPLT5 Vial: 72
Acq: 29-Jul-2008 23:05:35
User: CEM Datafile: 080729V21
Rel. Int.
100%-
Fn 1
130.9920
QC Check
7.02-10.55
0%-
1 I '
7.5
¦ I '
8.0
8.5
9.0
i f i
9.5
10.0
Abs. Int.
4.92e7
2.46e7
-j—t- O.OOeO
10.5 RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
Abs. Int.
-5.98e7
2.99e7
i i O.OOeO
17.0RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17 02-23.01
0%-
18.0
19.0
T t "i ¦" i" ¦¦¦¦>	i	i		i	r	*	i	|	t	i	r	i	|	i1
20.0	21.0
1 i | f i i y ) «
22.0
Abs. Int.
3,14e7
1.57e7
¦O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01
0%-
24.0
1		1	»y—»"T*"
26.0
28.0
30.0
1—1—1—<~
"32.o'
Results: P:\P9400_P9499\P9464_6042 PAH\resoumes\MB1_e042_PAH_SDS.utp_res. saved 01-Aug-2008 10:44 (CM)
AP UltraTmee-PrcTV3.9S2 User/System: CM/CMP4-015 see: S12-47S ~
34.0
Abs. Int.
r 2.53e7
¦ 1,27e7
¦O.OOeO
RT
Peak annotation: Areas, Centmids
PKD: n/a Printed: 01-Aug-20Q8 14:04:39 Page 1 of 9
-------
AP Lab ID: MB1_6042_PAH_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn1 100%-
128.0626
Analyte
4a 2.03e4
B,40-10.20
0%-
Naphthalene
Rel. Int.
pn •) 100%-
134.0827
Standard
4 i	» "| i
9,0	9.2	9.4	9,6
Abs, Int.
4.92e7
2 46e7
O.OOeO
10.2 RT
Results: P:\P940O_P9499SPg464_SO42 PAH\resources\MB1jS042_PAH_$D$.utp_reS, saved 01-Aug-200S 10:44 (CM)
AP UltraTmce-Pm V3.992 User/System: CM/CMP4-01S cc: 2872, 1304, 6101. 6126, 3158 see: 512-478
Peak annotation: Areas. CentnMs
Revised: 0l-Aug-2008 10:11:04 (CM) Printed: Ol-Aug-2008 14:04:56 Page 2 Of 9
-------
AP Lab ID: MB1_6042_PAH_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PAH_SDS
VSIR expt; pah_db5 0801 GC: pah_db5-SPLT5 Vial:
72
Acq; 29-Jul-2008 23:05:35
User: CEM Datafile: 080729V21
Rel. Int.
Fn 2 100%-
152.0636
Analyte
4o 869e3
11.50-12.30
0%-
11.5
T
11.6
Rel. Int.
Fn 2 100% —i
158.0827
Standard
4o2.18e3
11.50-12.30
0%-
ES-Acenaphthylene
5.1 See
11.54
11.5
11.6
11.7
I I j I I I I | 1
12.1
—i—i—t—|—i i
12.2
¦ i '
11.7
11.8
11.9
12.0
12.1
12.2
Abs. Int.
-5.55e6
• 2.77e6
-O.OOeO
12.3 RT
Abs. Int.
- 3.46e6
1.73e6
O.OOeO
12.3RT
Rel. Int.
Fn 2 100%-
154.0783
Analyte
4a 8.75e3
11.50-12.30
0%-
11.5
Rel. Int.
Fn 2 100%-
160.0984
Standard
4o1.96e3
11.50-12.30
0%-
I 11 1
11.5
Rel. Int.
Fn 2 100%-
164.1410
Standard
4o 1,40e3
11.50-12.30
0%-
/
Acenaphthene
3.65e5
11.90
11.9
ES-Acenaphthene
3.21 e6
11.89
-i—|—r—i—i—i—|—r-
11.6
12.0
12.3RT
11.5
11.6
—>—|—i—«—i—i—|—i—r—i—i—|—r—i—i—i—|—r*"i—i—
11.7	11.8	11.9
JS-Acenaphthene
3.03e6
11.83
1 I 1
11.7
• I"'"
12.0
11 I '
12.1
11.8
11.9
12,0
T-'-
-i—j—i—i—i—
12.1
12.2
Abs. Int.
- 1,33e6
6.66e5
O.OOeO
Abs. Int.
-2.16e6
1.08e6
-O.OOeO
12.3 RT
Abs. Int.
2.11e6
¦ 1,05e6
O.OOeO
12.2
12.3RT
Rel. Int.
Fn 2 100%-
168.9888
QC Check
11.50-12.30"
Abs. Int.
-5.82e7
-2.91e7
0%-r
11.5
-j—n—i—i | » i i
11.6
11.7
11.
11.9
Results: P:\P9400_P9499\P94S4_6042 PAHIresourcei\MB1j6042_PAH_SDS.utp_fes. saved OI-Aug-2008 10:44 (CM)
AP UltmTrace-Pro ¥3.992 User/System: CM/CMP4-01S cc: 7951. 9599, 2038, 4448, 1531 see: 512-478
Revised
| i i i i | i n r
12.1
-•'I'1
12.2
-O.OOeO
12.3RT
Peak annotation: Areas, Centmids
01-Aug-2008 10:12:25 (CM) Printed: 0t-Aug-2008 14:05:10 Page 3 of 9.
-------
AP Lab ID: MB1_6Q42_PAH_SDS
Instr: AutoSpee-Premier MM6
Sample ID: MB1_6042_PAH_SDS
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 72
Rel. Int.
100%-
Fn 2
166.0783
Analyte
4cr6.82e3
1270-16.50
0%-
Fluorene
3.66e6
13.02

u
Acq: 29-Jul-2008 23:05:35
User: CEM Datafile: 080729V21
Abs. Int.
-2.44e6
A
Rel. Int.
100%-
Fn 2
172.0984
Standard
4o 1.75e3
12.70-16.50
0%-
| i" l"f i"" I |
13.0
ES-Fluorer>e
2.83e6
13.01
II
13,0
r", r*>' |iri
13.5
¦A
3.1 oes
13.97
	i' t			i f' irV|1-*li	i i i | i i T i | i i i "i" | il i "i | i "t 1 t "p-f r i 	r i 	'i	i -i	i—|—r
14.0	14.5	15.0	15.5	16.0
-i—|—i—i—i—i—|—i—i—i1 r1 | % "I—*—i—|—j—*—i—!—|—i—i—i—i—|—i—i—i—i—|—r-
13.5	14.0	14.5	15.0
15.5
I I 1 I I I T
16.0
-1,22e6
-O.OOeO
RT
Abs. Int.
-1,85e6
•9.25e5
¦O.OOeO
RT
Rel. Int.
100%-,
Fn 2
178.0783
Analyte
40 1.08e4
12.70-16.50 "
0%-
Rel. Int.
100%-
Fn 2
184.0984
Standard
4a 1,27e3
12.70-16.50
0%-
5.05e5
13.02
I i i1^ »"¦
13.0
A.
5.74e5
13.43
13.0
13.5
8.29e6
14.27
¦A
At

Phenant e
4.01.
15,5

5.77e5
14.50
T*r i-r | "i *i^*1 i* |»
14.0	14.5
TT-
15.0
1—'I"1!1 i—i—1-~!—i—i-"i "j—r
15.5	16.0
ES-Pherianthrene
4 08e6
15.24
13.5
14.0
14.5
L
A.
Abs. Int.
-5.03e6
•2.52e6
15.0
T-'-
15.5
¦ I-""'
16.0
1 V I f V V
¦O.OOeO
RT
Abs. Int.
-3,00e6
1.50e6
• O.OOeO
RT
Rel. Int.
100%
Fn 2
168,9888
QC Check
12.70-16.50
Results: P:\P9400_P9499W9464_6042 PAH\resources\MB 1_6042_PAH_SDSutp_res. saved OI-Aug-2008 10:44 (CM)
AP UltraTmce-Pm V3.992 User/System: CM/CMP4-015 cc: 7945, 2006, 7998, 9735 see; 512-478
Abs, Int.
-5.98e7
-2,99e7
O.OOeO
RT
Peak annotation: Areas. Centmids
Revised: Ol-Aug-2008 10:13:00 (CM) Printed: 01-Aug-2008 14:05:23 Page 4 of 9
-------
AP Lab ID: MB1_6D42_PAH_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
176,1410
Standard
4 o 1,67e3
12.00-16.50
Sample ID: MB1_6042_PAH_SDS
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 72
Acq: 29-Jul-2008 23:05:35
User: CEM Datafile: 080729V21
SS-Fluorene
3,01e6
12.94
0% » i i i | i i I i | i i i i | 1 i if i t i i I j1
12.0	12 5	13.0
Rel. Int.
100%-
Fn 2
188.1410
Standard
4o 1.7le3
12,00-16.50
0%-
i | i i \ i | i i i i | r i i i | i i i i [ i i i i [ i i 1 i" r |1 «111 'i i1 ^ i i i i ^ i i » i | i i i I | i i > i | i i i 11 O.OOeO
13.5	14.0	14.5	15.0	15.5	16,0	RT
AS-Anthracene
4,07ee	Abs int.
15.32
12.0
	i'""!'""*""!"'"!					|"'"l	!	I	I	|" 'f "I' 1 f "|—1
12.5	13.0	13.5
¦ I"'
14,0
¦¦ r | i i i i | i	i1 i1 "i111 j'1111 i i '
14,5	15.0
L
T"T"
15.5
¦p i"i i i | i i i i O.OOeO
16,0	RT
Rel, Int.
100%-
Fn 2
168.9888
QC Check
12.00-16.50'
0%-
~f—1 t "T"
12.0
' 1 1
12.5
| t i i i | r i
13.0
¦ I '
13.5
14.0
t
1 ( 1
14,5
15,0
15.5
j r i i i | f i i i O.OOeO
16.0	RT
Results: P:\P9400_P9499\P9464_6042 PA.HVesourcesWB 1_6042_PAH_ SOS utp_res. saved 01-Aug-200B 10:44 (CM)
AP UltmTrace-Pio V3.992 User/System; CMJCMP4-015 cc: 5927. 1580 see: 512-47$
Peak annotation: Areas, Centmids
Revised: 01-Aug-2008 10:10:55 (CM) Printed: 0l-Aug-2008 14:05:36 Page 5 ot 9
-------
AP Lab ID: MB1_6042_PAH_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PAH_SDS
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 72
Acq: 29-Jul-2008 23:05:35
User: CEM Datafile: 080729V21
Rel. Int.
Fn 3 100%-
202,0783
Analyte
4o 1,45e4
17,50-22,50 :
0%-
Rel. Int.
Fn 3 100%
208,0984
Standard
4a 5.32e3
17.50-22,50 1
0%-
Rel. Int.
Fn 3 100%q
205,0883
Standard
4o 3.88e3
17.50-22 50
o%.
Fluoranthene
1,4466
18.12
Pyr<
?.90eS
18.68
I '
18.0
ES-Fluoranthene
5.79e6
18.12
t I | ! I I
19 0
—I—
18.0
18.0
19.0
ES-Pvrene
7.22e6
18.68
19,0
20.0
21.0
20.0
21.0
20.0
21,0
¦l1 I * | 1
22,0
6.63eS
21.60
22.0
22.0
Abs. Int.
-7.63e6
•3.82e6
-O.OOeO
RT
Abs, Int.
- 3.48e6
1.74e6
¦O.OOeO
RT
Abs. Int.
r4.62eS
-2.31e6
O.OOeO
RT
Rel. Int.
Fn 3 100%!
228.0939
Analyte
4o 4.70e3
17.50-22.50
0%
Rel. Int.
Fn 3 100%^
234.1140
Standard
4o 1 38e3
17.50-22.50
0%
•A-
1.14e6
18.71
18.0
6.30e41.58e5
18.90 19.07
18.0
19.0
i*1! i ' i
20.0
r "f"1! ^r"
21.0
BenzfalXnthraceo^'
t.28eS
21.60
22.0
19.0
20.0
-1	¦	1	
21.0
ES-Benz(a)Anthrace
4.376'
7e6
21.61
Abs. Int.
-7.11e5
3.56e5
•O.OOeO
RT
Abs. Int.
-2.30e6
-1.15e6
O.OOeO
| '* I 1 I J * I I !
22.0	RT
Rel. Int.
Fn 3 100%
218.9856
QC Check
17,50-22.50'
Results: P:\P9400_
AP UltraTmce-Pm
P9499\P9464_6042 PAHVesounxs\MBl_6042_PAH_SDS.utp_ms, saved 01-Aug-2008 10:44 (CM)
V3 992 User/System: CMCMP4-01S cc: 1566, 8909, 4731. 7616. 3074 see: 512-478
Abs. Int.
3.l4e7
-1 57e7
O.OOeO
RT
Peak annotation: Areas. Centroids
Revised: 01-Aug-200B 10:13:35 (CM) Printed: 01-Aug-2008 14:05:48 Page 6 of 9
-------
AP Lab ID: MB1_6042_PAH_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
212.1410
Standard
4o 3.99e3
18.00-20.00 \
Sample ID; MB1_6042_PAH_SDS
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 72
JS-Pyrene
5.Q8e6
18.63
0%-
Acq: 29-Jul-2008 23:05:35
User: CEM Datafile: 080729V21
Abs. int.
-2.99e6
r > i f j i i i i | i i r > | i i i i | i < i i | i i i i 1
18.2	18.4	18.6
'"'"I	; l | i i i i | i i i i ( ¦ i ¦
19,6
19.8
-1.01 e6
-O.OOeO
RT
Rel. Int.
100% -
Fn 3
218.9856 •
QC Check
18.00-20.00"
Abs. Int.
- 3.09e7
¦1.55e7
0%-
18.2
18.4
18.6
18.8
19.0
Results: P:\P9400_P9499\P9464_6042 PAffiresources'MBi_6042_PAH_$D$.utp_m$. saved 01-Aug-200S 10:44 (CM)
AP UltraTrace-Pro V3.992 User/System: CMCMP4-015 cc: 9328. 1218 see: 512-478
19.2
19.4
19.6
19.8
-O.OOeO
RT
Peak annotation: Areas, Centmids
Revised: 01-Aug-2008 10:11:14 (CM} Printed: 01-Aug-2008 14:06:04 Page 7ol9
-------
AP Lab ID: MB1_6042_PAH_SDS
Instr: AutoSpec-Premier MM6
Ret, Int.
100%-
Fn 4
252.0939
Analyte
4o 4.96e3
23.50-28.00
Rel. Int.
100%-
Fn 4
258.1140
Standard
4o 1.26e3
23.50-28.00
0%-
Sample ID: MB1_6042_PAH_SDS
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 72
T""i	i	i	t	t	r"v
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o 2.54e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
264.1692
Standard
4o 2.18e3
23.50-28.00
0%-
24.0
Benz(b)Fluoranthene
2.l6e5
24.91
Benz(^|r(6eaB
-------
AP Lab ID: MB1_6042_PAH_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
pn 4 100%-
276.0939
Analyte
4o 3 95e3
29.0-36,0
0%-
Sample ID: MB1_6042_PAH_SDS
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial; 72
Bertz((jh||Perytene
33,27 f
29.0
30.0
31,0
32.0
33.0
34.0
Rel. Int.
pn 4 100%-
282.1140
Standard
4o 3.06e3
29.0-36.0
0%-
ES-lndM 23-cd)Pyre
6.08 e6
31.63
lift
29.0
30.0
31,0
32.0
Rel, Int.
4 100%
288,1342
Standard
4o 1.34e3
29,0-36,0
Rel. Int.
Fn4 100%
278.1096
Analyte
4a 3.18e3
29.0-36.0
Rel. Int.
Fn 4 100%-
284.1297
Standard
4o 1,28e3
29.0-36.0
0%-
r*1 [ T I I I [ I I t I | r
33.0
ES-8enz(ghi)Peryl
7,48e6
33,26
34,0
Acq: 29-Jul-2008 23:05:35
User: CEM Datafile: 080729V21
Abs. Int.
-3,33e4
35.0
35.0
ES-Dibenz(ah)Anthr
6.53e6
31,85
29.0
30.0
31.0
i f I I I I f t t I I
¦1.67e4
-O.OOeO
36.0 RT
Abs. Int.
1,18e6
¦5.88e5
-O.OOeO
36.0 RT
Abs. Int.
1,25e6
6 23e5
O.OOeO
36.0 RT
Abs. Int.
2!4e4
1.07e4
O.OOeO
36.0 RT
Abs. Int.
9 35e5
-4.67e5
33,0
34.0
35.0
-O.OOeO
36.0 RT
Rel. Int.
Fn 4 100%
292.9824
QC Check
29.0-36.0
32.0
Results; P:\P9400_P9499\P94G4_6042 PAH\ftesouftes'MB1_6042_PAH_SDSMtp_res. saved 01-Aug-200B 10:44 (CM)
AP UltraTrace-Pm" V3.992 User/System: CM/CMP4-015 cc. 9778. 9928. 4569, 9160. 6493 see: 512-478
33.0
34.0
Revised. 01-Aug-200B 10:15:35 (CM)
Abs, Int.
-2.53e?
-1,27e7
O.OOeO
36.0 RT
Pea* annotation: Areas, Cenimids
Printed: 01-Aug-200B 14:08:30 Page 9 of S ,
-------
Datafile: e: 080729V22
Acquired: 29 Jul 2008 23:45:06
Client ID: Run# ACD-M23-FB
Lab ID: P9464 6042 PAH 001

Stats
Largest *ve RT shift (sees)
Largest -ve RT shift (sees)
PAH Ax
1.0
-1.7
ES/SS
4.1
-0. 8
Name
Actual
RT
QC
Pred
RET
Naphthalene
8.
58
S
l
0004
2-Methyl naphthalene
9.
75
/
l
0003
Acenaphthylene
11
.53
S
l
0003
Acenaphthene
11
.89
/
l
0003
Fluorene
13
01
y
l
0003
Phenanthreae
15
24
r
l
0002
Anthracene
IS
36
/
1
0002
Fluoranthene
18
11
y
l
0002
Pyrene
18
67
s
i
0001
Benzo(a)Anthracene
21
61
s
i
0001
Chrysene
21
71
/
i
0001
Benzo(b)Fluoranthene
24
91
w
l
0001
Benzo(k)Fluoranthene
25
00
s
l
0001
Benzo(e)Pyrene
25
94
s
l
0001
Benzo(a)Pyrene
26
15
/
i
0001
Perylene
26
48
/
i
0042
mdeno (1, 2, 3 - cd)Pyrene
31
63
y
l
0002
Dibenzo(a,h)Anthracene


s
i
0002
Benzo(ghi)Perylene
33
.25
/
i
0004
Analytical Perspectives
/
Wt/Vol: 1 Train '
J Level: 4 ng/Train'

ICAL: MM6 PAH 080118 18JAN08

Nominal ES spike: 40 ng/
Checkcode:

Actual
'Biff



Cone



RRT
Sees
Response
Ra
ERF /eg/Train
Noise

DIa
1.0005
+0.1
1.06E+08
-
1.09
1,460
2.48E+04
1
05000
1.0003
0
6.51E+06
-
1.11
111
1.24E+04
0
69300
1.0003
0
3.78E+07
-
0.86
493
1.34E+04
0
60300
1.0003
0
8.07E+05
-
1.00
14 . 8
1.04E+04
0
71100
1.0007
+0.3
5.37E+06
-
1. 05
100
9.18E+03
0
66400
1.0002
0
1.40E+07
-
1.12
147
1.01E+04
0
44400
1.0002
0
4.18E+05
-
1.09
4.91
1.01E+04
0
47600
1.0002
0
3.99E+06
-
1.02
37 . 9
1.03E+04
0
39900
1.0001
0
2.22E+06
-
1.03
18.3
1.03E+04
0
34000
1.0000
-0.1
2.21E+05
-
1.00
2.85
3.76E+03
0
23700
0.9999
-0.3
4.08E+05
-
1.11
4.95
3.76E+03
0
24600
1.0008
+ 1. 0
5.07E+05
-
0.99
5.74
5.12E+03
0
37800
0.9997
-0.6
1.68E+05
-
0.90
1.72
5.12E+03
0
43900
1.0001
0
2.27E+05
-
0.93
2.52
5.12E+03
0
44000
0.9994
-1.1
1.71E+05
-
0.86
2.08
5.12E+03
0
58400
1.0031
-1.7
4.84E+04
-
0.90
0.727
5.12E+03
0
68800
1.0001
-0.2
1.59E+05
-
0.93
3.19
3.87E+03
1
05000
-

-
-
0.89
ND
3.28E+03
1
10000
0.9998
-1.2
1.43E+05
-
0.95
2.31
3.87E+03
0
92600
/
fy
Page 1 of 2
Printed: 8/5/2008 2:28 PM
-------
Datafile: e: 080729V22
Client ID: Run# ACD-M23-FB
Lab ID: P9464 6042 PAH 001
Scats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
PAH Ax
1.0
-1.7
SS7SS
4 .1
-0.8
Name
Actual
RT
Pred
RRT
13C6-Naphthalene
13C6-2-Methylnaphthalene
13C6-Acenaphthylene
13 C6-Acenaphthene
13C6-Fluorene
13C6-Phenanthrene
13C6-Anthraeene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo{a)Anthracene
13C6-Chrysene
X3C6-Benzo(b)Fluoranthene
13C6-Benzo(k)Fluoranthene
13C4-Benzo(e)Pyrene
13C4-Benzo(a)Pyrene
dl2-Perylene
13C6-lndeno(1,2,3-cd)Pyrene
13C6-Dibenzo(ah)Anthracene
13C12-Benzo(ghi)Perylene
8.58
9.74
11.53
11.89
13.00
15.23
15.36
18.11
18; 67
21.61
21.71
24 .89
25.01
25.94
26.17
26.40
31.63
31.85
33.26
.8857
.0063
.9757
,0057
.1002
.2890
1.2995
0.9724
1.0025
1.1602
.1656
.9557
.9597
.9956
.0040
.0124
1.2143
1.2217
1.2766
AS--Anthracene
15.31
1.2897
SS-Fluorene
SS-Terphenyl
12.94
19.03
0.9949
1.0506
JS-Methylnaphthalene
JS-Acenaphthene
JS-Pyrene
JS-Benzo(a)Pyrene
9.68
11.82
18.62
26.06
Analytical Perspectives
Wt/Vol: 1 Train
ICAL: MM6 PAH 080118 18JAN08
Actual
Dlff





RRT
Sees
Response
Ra
RRF
/
Recv,
0.8858
+0.1
2.67E+06
_
1.51
y
67.0
1.0064
+0.1
2.11E + 06
-
0.96
V
83.7
0.9757
0
3.58E+06
-
1.79

88.7
1.0058
+ 0.1
2.18E+06
-
1.06

91.1
1.1002
0
2.04E+06
-
1.11

81.5
1.2890
0
3.40E+06
-
1.76

85.8
1.2994
-0.1
3.13E+06
-
1.64

84.8
0.9724
0
4.13E+06
-
1.25

83.3
1.0025
0
4.70E+06
-
1.30

90.7
1.1602
0
3.10E+06
-
1.06

73.7
1.1657
+0.1
2.96E+06
-
1.02

73.3
0.9554
-0.5
7.17E+06
-
1.21

95.7
0.9598
+0.2
8.69E+06
-
1.60

88.2
0.9954
-0.3
7.75E+06
-
1.30

96.3
1.0042
+0.3
7.63E+06
-
1.39

88.7
1.0130
+0.9
5.89E+06
-
1.36

70.0
1.2138
-0.8
4.29E+06
-
0.81

86.4
1.2222
+ 0.8
4.84E+06
-
1.00

78.7
1.2763
-0.5
5.24E+06
-
1.15

73.7
1.2955
+4.1
3.10E+06
-
1.44

95.8
0.9949
0
2.01E+06
-
0.96
y
103.0
1.0506
0
2.02E+06
-
0.54
91.2
-
-
2.64E+06
-
_

-
-
-
2.26E+06
-
-

-
98E+06
09E+06
Page 2 of 2
Printed: 8/5/2008 2:28 PM
-------
AP Lab ID: P9464_6Q42_PAH_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
Acq: 29-Jul-2008 23:45:06
User CEM Datafile: 080729V22
Rel. Int.
100%-
Fn 1
130.9920
QC Check
7.02-10.55
0%-
I—r-1
7.5
8.0
"I	T	1	1	1	T	1	1	1	J	T"
8.5
r "j t r-
9.0
T—f-T
9.5
10.0
Abs, Int.
-4 75e7
•2,38e7
4-O.OOeO
10.5 RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
Abs. Int.
-5.84e7
2.92e7
O.OOeO
17.0RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.00'
0%-
18.0
*~1	'f	'j	I
19.0
	1	'«¦" ' [ " I
20.0
21.0
i 4 | « i i r | i
22.0
Abs. Int.
- 3.04e?
1.52e7
O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35,01
0%-
24.0
-l	1	1	r
26.0
' I '
28.0
i	|	i	i	r	i	I1"
30,0
32.0
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_OQ1.utp_m$, saved Of-Aug-2OO0 13:55 (CM)
AP UltraTrace-Pro V3.992 User/System: CM/CMP4-015 see: 450-564	~
i—,		
34.0
Abs. Int.
- 2.39e7
1.19e7
O.OOeO
RT
Peak annotation: Areas, Centroids ,
PUD n/a Printed: 61-Aug-2008 14:06:42 Paget of 9 /
-------
AP Lab ID: P9464_6042_PAH_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
Rel. Int.
pn i 100%-
128.0626
Analyte
40 2.48e4
8.40-10.20
0%-
Naphthalene
1.06e8
8.58
T I I I 1 I I
Rel. Int.
Fn1 100%-
134.0827
Standard
4o1.43e3
8.40-10,20
0%-
Rel. Int.
Fn1 100%-
142.0783
Analyte
4o 1 24e4
8.40-10.20
0%-
Rel. Int.
Fn1 100%-
148.0984
Standard
4o1,50e3
8,40-10.20
0%-
Rel. Int.
Fn1 100%-
152.1410
Standard
4o 1.36e3
8,40-10.20
0%-
Acq: 29-Jul-2008 23:45:06
User: CEM Datafile: 080729V22
Abs. Int.
-8.87e7
8,8
9.0
¦ i ¦
9.2
• i ¦
9.4
¦ i ¦
9.6
9.8
4.43e7
O.OOeO
—l—l—l—|—l—l—i—1—|—j—l—'—r
10.0	RT
ES-Na|hihalene
8.58
Abs. Int.
-2 20e6
-1.10e6
8.8	9.0
9.2
I	I	I	I
9,4	9.6
» I 1 " ' 1 I ' 1 ' ' I ' ¦ 1 1 I
9.8	10.0
2-M ethyl naphthalene
6,51e6
9.7S
i [ r i i f | i i i i | i
8.6	88
9,0
¦ i 1
9.2

i
9.4
1 1 I 1 ' 11 I '
9.6
¦O.OOeO
RT
Abs. Int.
-4,98e6
-2.49e6
; » i i » I'i > r i |'i
9,8	10,0
ES-2-*teth^oaphtha
9.74
-r vr t ft— f
8.6
8.8
¦r-|-r
9,0
T'"
9.2
"»~T
9.4
i	f"T""T""T""T""i	i	r""i	i	r"
T | T T » ?
-O.OOeO
RT
Abs. Int.
-1.62e6
8.09e5
9.6	9.6
J S-Mefrignaghthale
0,68
10,0
I I I I I f
8.6
r
8,8
I | I I
9,0
I I I | I I I I | I 1 I I | I
9.2	9.4
9.6
,rT"r
9.8
' I '
10.0
-O.OOeO
RT
Abs. Int.
-2,00e6
1 00e6
•O.OOeO
RT
Rel. Int.
Fn 1 100%-
130.9920
QC Check
8.40-10.20
0%-
-i—r-i	i	|	t	i	i	i	|	i	i	i	r		
8.6	8.8
i | i i i i | i i i r | i i
9.0	9.2
< | I I I » |
9.4
9.6
T'-
9.8
Results: P:\P94QO_P9499\P94B4_6042 PAHVesoun:es\P9464_6042_PAH_O0 l.utp_res. saved OI-Aug-2008 13:55 {CM)
AP UltraTrace-Pm V3.992 User/System: CM/CMP4-015 cc: 1828. ~3263, 7065.0067. 9195 see: 450-564
	r""t	r""i	i	r""%	r
Abs, Int.
4.75e7
¦2,38e7
•O.OOeO
RT
10.0
Peak annotation: Areas, Centroids
Revised: 01-Aug-2008 10:34:34 (CM} Printed: G tf 4.0$, 54 P300 2. Off 5

-------
AP Lab ID: P9464_6042_PAH_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5..0801 GO: pah_db5-SPLT5 Vial: 73
Rel Int. 3,
fn2 100%
152.0636
Analyte
4o 1.34e4
11,50-12.30 }
Acenaphthytene
I.78e7
II.S3
0%-
Acq: 29-Jul-2008 23:45:06
User: CEM Datafile: 080729V22
Abs. Int.
-2.81e7
Rel. Int.
pn 2 100%
158.0827
Standard
4o 2.36e3
11.50-12.30
11.5	11.6
ES-Acenaphthytene
11.7
8.03eS
11.77
' I '
11.9
12.0
-r-|—r
12.1
11 I 1
12,2
3.58e6
11.53
11.5
11.6
11.7
11.8
'"T	T	I	I	T	T	1	1	f	T	1""
12,0
12.1
Rel. Int.
pn 2 100%
154.0783
Analyte
4o 1,04e4
11.50-12.30 -I
0%
Acenaphthene
8.07e5
11,89
11.5
i 1 I % I I i
11.6
¦ i ¦
11.7
11.8
Rel. Int.
pn2 100%-
160.0984
Standard
4 a 1.92e3
11.50-12.30
0%-
i	i
11.9
ES-Acenaphthene
2.18e6
11.89
12.0
1 I 1
12.1
i—r—i—i—j1 11 i i i 1 j—i—i—i—i—|—i—i—i—r—|—i i i—t—|-
11.5	11.6	11.7
Rel. Int.
pn 2 100%-
164.1410
Standard
4a1,59e3
11 50-12 30
0%-
t 1 "I	» ""I" T ""T	|
11.8
JS-Acenaphthene
2.26e6
11.82
"i	t	|	i	r	<	i	|	i"
12.0
' I 1
12.1
I I 1 I I I I I
11.5
11.6
11.7
111!
11,8
11.9
12.0
12.1
	'	1
12.2
1 I '
12.2
T-r*
12.2
12.2
1,40e7
¦O.OOeO
12,3 RT
Abs. Int.
2.60e6
• 1,30e6
O.OOeO
12.3RT
Abs. Int.
-5 99e5
- 3,00e5
-O.OOeO
12.3 RT
Abs, Int.
1,47e6
7,36e5
O.OOeO
12.3RT
Abs. Int.
r 1 65e6
•8 25e5
¦O.OOeO
12.3RT
Rel. Int.
pn2 100%
168.9888
QC Check
11.50-12.30
Results: P:\P9400_P9499\P94S4_W42 PAH\msources\PS4B4_S042_PAH_001.utp_ms, saved 01-Aug-2008 13:55 (CM)
AP UltmTmce-Pm V3.992 User/System: CM/CMP4-015 
-------
AP Lab ID; P9464_6042_PAH_0Q1
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
Rel. Int.
100%-
Fn 2
166.0783
Analyte
4a 9.18e3
12.70-16.50
0%-
jL
Rel. Int.
100%-
Fn 2
172.0984
Standard
4o 1.30e3
12.70-16.50
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o 1.01e4
12.70-16.50
0%-
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o 1.48e3
12.70-16.50
0%-
Fluorene
5.37e6
13.01
Acq: 29-Jul-2008 23:45:06
User: OEM Datafile: 080729V22
Abs. Int.
3.33e6
1.67e6
13.0

¦y r-pf i 'fO pi
13.5
A -i i Ar-|
14.0
f* { 1 V
14.5
A
' I "*
15.0
15.5
I ' 1 1 ' I 1
16.0
ES-Fluorene
2.04e6
13.00
0% 1 | I I I I ' | " I I 1 1	1	1	1	1—I I I I | I I I I [ I I I I ] I I I I |
13.0	13.5	14.0	14.5
15.0
l/"1.
| JP1 I I I | I I ! I | I I
15.5
16.0
Phenanthrene
1.40e7
15.24

p ^ A	r ^

13.0
13.5
14.0
A-
VXs
/
-T-r-
-t—r—i—|—i—i—(""V | ** i o i—i—j—r
15.0
15.5
I i 1 • ' ¦ I '
16.0
ES-Phenanthrene
3.40eB
15.23
13.0
13.5
14.0
14.5
15.0
^		' I ' ' '
15.5
16.0
-r-»-0.00e0
RT
Abs. Int.
r1.33e6
6.64e5
l i i i i
¦O.OOeO
RT
Abs. Int.
r8.92e6
• 4.46e6
T—i—A-
- O.OOeO
RT
Abs. Int.
-2 05e6
1 02e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12,70-16.50'
0%-
13,0
13.5
1 I 1
14,0
"1	1	1	T	1""
14.5
15.0
• I '
15.5
Results: P:\P9400_P9499\P9464_6042 PAHSmsoumes\P9464_6042_PAfi_00lMtp_ms, saved 01-Aug-200B 13:55 (CM)
AP UltraTrace-Pno' V3.992 User/System: CWCMP4-01S ce:6148, 9922, 6620, 5344 see: 450-564
16.0
Abs, Int.
5.78e7
¦2.89e7
-O.OOeO
RT
Peak annotation: Areas, Cenlnoids
Revised: 01-Aug-2008 10:27:28 (CM) Printed: Ol-Aug-2008 14:07:17 Page 4 of 9
-------
AP Lab ID; P9464_6042_PAH_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-,
Fn 2
176.1410
Standard
4o 1,55e3
12.00-16.50
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
12.0
Rel. Int.
100%-
Fn 2
188.1410
Standard
4o2.l7e3
12.00-16.50
SS-Fluorene
2.Q1e6
12.94
Acq: 29-Jul-2008 23:45:06
User: CEM Datafile: 080729V22
Abs. Int.
1 38e6
12.5 ' '
13.0
'[•rmyi ifi | i i < t j i i t i |
13.5	14.0	14.5
II U' |
15.0
i i i'i i n I i
15.5
| I I I''!' |
16.0
AS-Anthracene
3.10e6
15,31
6 90e5
-7-r--O.OOeO
RT
Abs. Int.
~1.99e6
0%-i I i i | i i i i | i i i t | 'i1 f i "i | pi i i | i i i i | i i i i [ i i r i f i
12.0	12.5	13.0	13.5	14.0
r' 1 		 i 1 			 1 1 1 i ¦
14.5	15.0
S"V* ^"i'["i>fi|iiii|ii!i|iiii^ O.OOeO
-9.95e5
15.5
16.0
RT
Rel. Int.
100%-,
Fn 2
168.9888
QC Check
12.00-16.50
0%-
12.0
12.5
13.0
-i—|—i I »
13.5
	'	I	'	
14.0
' I '
14.5
1 ' ' I '
15.0
15.5
1 I '
16.0
Abs. int.
5.78e7
• 2.89e7
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHVesources\P9464 6042 PAH_001.utp_nes, saved OJ-di/g-2008 13:55 (CM)
AP UilmTmce-Pm V3.992 User/System: CWCMP4-01S cc: 0467, 4529 see: 450-564
Peak annotation: Areas, Centmids
Revised: OUAug-2003 10:34:25 (CM) Printed: 01-Aug-20Q8 14:07:28 Page 5 of 9 J
-------
AP Lab ID: P9464_6042_PAH_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
Acq: 29-Jul-2008 23:45:06
User: CEM Datafile: 080729V22
Rel. Int.
Fn 3 100%-
202,0783
Analyte
4o1.03e4
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-
208.0984
Standard
4o 5.30e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%1
205.0883
Standard
40 3.63e3
17.50-22.50
0%
/
Fluoranthene
3.99e6
18.11
A
Pyrene
2.22e6
18.67
-rA—
1 I I
18.0
ES-Fluoranthene
4.13e6
18.11
19.0
20.0
21.0
18.0
18.0
19,0
ES-Pyrene
4.70e6
18.67
19,0
20,0
20.0
—,—
21.0
21.0
22.0
—I—
22.0
22,0
Abs. Int.
-1.01 b7
¦5.07e6
•O.OOeO
RT
Abs. tnt.
-2.55e6
• 1.28e6
•O.OOeO
RT
Abs. Int.
- 2.96e6
1.48e6
-O.OOeO
RT
Rel. Int.
Fn 3 1«»%-
228.0939
Analyte
4o 3 76e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-
234.1140
Standard
4o1.45e3
17.50-22,50
0%-
18,0
18.0

19-0
19.0
20.0
/ /
Benz(^Arjtt|racene
21.0
22.0
20,0
V V I |
21,0
ES-Benz(a)Anthrace
3.1 u&S
21.61
22.0
Abs. Int.
r-5,82e5
•2.91e5
¦O.OOeO
RT
Abs. Int.
-1.60e6
•8.00e5
¦O.OOeO
RT
Rel. Int.
Fn 3 100%
218,9856
GC Check
17.50-22.50 j
Abs. Int.
3 04e7
1.52e7
O.OOeO
RT
Results-' P:IP9400_P94991P9464_6042 PAH^esources\P9464_6042_PAH_001 utp_re$. saved 01-Aug-2008 13:55 (CM)
AP Ultra Trace-Pro V3 992 User/System: CM/CMP4-015 cc 3301. 6822. 9340. 2324. 0328 see: 450-564
Peak annotation: Areas. Centmkts J
Revised: 01-Aug-2008 10:28:28 (CM) Printed: 01-Aug-2008 14:07.39 Page 6 of 9 /
-------
AP Lab ID; P9464_6042_PAH_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
212.1410
Standard
4a 4.Q6e3
18.00-20.00
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
Acq: 29-Jul-2008 23:45:06
User: CEM Datafile: 080729V22
JS-Pyrer>e
3.98e6
18.62
Rel. Int.
100%-
Fn 3
244,1974
Standard
40 1,44e3
18,00-20.00 •
I 1 I J J I ! » I J' I I I I | I I I I J f I I I | I I 1
18.2	18,4	18.6
SS-Terphinyl
2,02e6
19.03
0% I i I I I I I I I I I I 1 I I 1 I I I	f I '*'	I"!' ) I l"i	>""}	
18.2	18,4	18.6
	I1 i "i i"	i | r"'i i i ji •r" r'i'T'Y'i-ttt*
18,8 "	19.0
~i~f i~i r i | i i i i | f"
19,2	19.4
i | i i < i j i i i r | i i i i | i
19.6	19.8
Rel. Int.
100%-
Fn 3
218,9856
QC Check
18.00-20.00"
0%-
18,2
' I 1
18,4
18.6
I I I | 1 I
18.8
19.0
19.2
I | f I I I | 1 I
19.4
1 | i 1 T ! | I 1
19.6
¦'¦1 ' '
19.8
I i i i
Results: P:\P94O0_P9499\P9464_6042 PAH\msourcss\P9464_6042_PAH_001.utp_ws, saved 01-Aug-2008 13:65 (CM)
AP UltraTrace-PnT V3 992 Userkystem: CWCMP4-015 cc 0395, 1703 see: 450-564
Peak annotation: Areas. Centroids
Revised: 01-Aug-2008 10:34:47 (CM) Printed: 01-Aug-2008 14:07:51 Page 7 of 9
-------

AP Lab ID: P9464_6042_PAH_Q01
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 4
252.0939
Analyte
4o 5.12e3
23.50-28.00
Rel. Int.
100%-
Fn 4
258,1140
Standard
4a 1.56e3
23.50-28.00
0%-
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
Rel. Int.
100%
Fn 4
256.1073
Standard
4o 2.74e3 •
23.50-28.00
0%-
Rel. Int.
100%.
Fn 4
264.1692
Standard
4o2.17e3 •
23.50-28.00 •
0%-
Benz(b)F!uorantherie
5.07el
24.^
Da n i (ck\Ch.irafnn

ES-Benz(b)Fluorant
7.17e6
24.8§
—I—I—I—I—I—|—I—I—!—I—J—J—I—I—I—|—r-
24,0	24.5
^"i i i i ; i i i i | i i r*Y
25.5
26.0
ES-Benz(e)Pyrene
7 75e6
25BS~Benz(a)Pyrene
7.63e6
26.17
26,5
27.0
' ' I ' * ' I ' ' ' ' I
24.0
V | I I I I j I t "1 I ( T I f I ) I I I I | * I I I |
24.5	25,0	25.5
Acq: 29-Jul-2008 23:45:06
User: CEM Datafile: 080729V22
Abs. Int.
-1.37e5
BenzjKlFluorarithene
68e5
I" ' 1	>	¦	I	
26.0
'' I 1 11 1 I
26.5
27.0
ES-Perylene
5.89 e6
26.40
JS-Benz(a)Pyrene
3.09e6
26.06
TTmrr
24.0
l—| i i i i | i i i i | i i i i |[ i i i t | i i r i f i i t i j i i i i *|
24.5	25.0	25.5	26.0
27,5
27.5
-6.86e4
j i t i i O.OOeO
RT
Abs. Int.
-2.76e6
1.38e6
~i—i—0, OOeO
RT
Abs. Int.
-2.51e6
•1.25e6
* 'i'" r i j i i	i"" r 		
26.5	27.0
IN |	'	i	i—i—|—i—i—i—i—j—i—r-
27.5
-O.OOeO
RT
Abs. Int.
-1 66e6
8 28e5
¦O.OOeO
RT
Rel. Int.
100%
Fn 4
292.9824
QC Check '
23 50-28 00"
0%-
24.0
1 I |
I I I | I 1
24.5
25.0
25.5
i i r | i
26.0
1 I | I
26.5
Results P:\P9400_PS499\P9464 6042 PAHVesources\P9464 6042 PAH001 utpres. saved 01-Aug-2008 13:55 (CM)
AP UltraTiace-Pro V3.992 Userkystem: CWCMP4-01S cc: 0733. 2883. 5466, 9033 see: 450-564
27.0
27.5
Abs. Int.
-2,39e7
-1.19e7
-O.OOeO
RT
Peak annotation: Areas. Centroitis
Revised: 01-Aug-2008 13:55:30 fCMj Printed: 01-Aug-2008 14:08:02 Page 8 of 9
-------
AP Lab ID: P9464_6042_PAH_001
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn 4 ^ 00%
276,0939
Analyte
4a 3.87e3
29.0-36.0
Rel. Int.
Fn4 100%
282.1140
Standard
40 3.08e3
29.0-36.0
Sample ID: Run# ACD-M23-FB
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 73
BenzfghiSI
ane
nd(123-cd)Pyrene/'
1.5Se5 /
33.25
31.63
Acq: 29-Jul-2008 23:45:06
User: CEM Datafile: 080729V22
Abs. Int.
4,S7e4
2,44e4
0%-
	i	¦	'	¦¦ ' I ¦ ¦ • i I
31.0	32.0
ES-lrid(123-cd)Pyre
4.29e6
31.63
I I I | I I » I | 1 I I I | 1
33.0	34.0
i i i i i i ¦ i
29.0
30.0
1 I 1 1
31.0
Rel. Int.
Fn 4 100%-
288.1342
Standard
4 o 1.58e3
290-360
0%-
ht "i" i t | t r	t	i	| i i i i
330
ES-Benz(ahi)Peryl
5.24e6
33.26
i i i i i i
34.0
35.0
29,0
1 I ' ' ' < I i i 1 ' I '
30.0	31.0
f I I I 1 | I I I I | ' I
2,0	33.0
-t t-r—r1
Rel, Int.
Fn 4 100%-
278.1096
Analyte
4o 3.28e3
29.0-360
0%-
34.0
35.0

29.0
30.0
310
Rel. Int.
pn 4 100%-
284.1297
Standard
4a 1,64e3
29.0-36.0
0%-
32.0
ES-Dibenz(ah)Anihr
4.84e6
31,85
33. o'
1 I '
34.0
350
29,0
30.0
31.0
32.0
'I J 		I	I	I I I I ! | I I I I j	 1
33.0	34.0
T r
35.0
-i—I—i—r-
OOeO
36.0RT
Abs. Int.
- 8.08e5
4.0465
¦O.OOeO
36,0 RT
Abs. Int.
-8.94e5
-4.47e5
O.OOeO
36.0 RT
Abs. Int.
2.00e4
1.00e4
O.OOeO
36.0 RT
Abs, Int.
-6.76e5
¦3.38e5
O.OOeO
36.0 RT
Rel. Int.
pn 4 100%
292,9824
QC Check
29,0-36,0
0%
29,0
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464 6042 PAH001 utp_res. saved 01-Aug-2008 13:55 (CM)
AP UHraTmce-Pro V3.992 User/System: CM/CMP4-015 cc: 5859. 6951, 5310, 3025, 8232 see: 450-564
Abs, Int.
-2.37e7
1.19e7
O.OOeO
36.0 RT
Peek annotation: Areas, Centrales
Revises!: 01-Avg-2008 10:34:13 (CM) Printed: 01-Aug-2008 14:08:13 Page 9 of 9
-------
~atafile: e: 080729V23
Acquired: 30 Jul 2008 00:24:38
Client ID: Run# I-ACD-M23-1
Lab ID: P9464 6042 PAH 002
Wt/Vol: 1 Train
J Level: 4 ng/Traipu^	—^
ICAL: MM6 PAH 080118_18JAN08
Nominal ES spike: 40 ng—'
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees!
Name
Naphthalene
2-Methylnaphthalene
Acenapbtbylene
Acenapbthene
Fluorene
tfr Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)Anthracene
Chrysene
Benzo(b)Fluoranthene
Benzo(k>Fluoranthene
Benzo(elPyrene
Benzo(a)Pyrene
Perylene
Indeno(1,2,3-cd)Pyrene
Diberizo (a,h) Anthracene
Benzo(ghi)Perylene
^ M-~<*
Actual
RT
8.59 S
9.75 /
11.54/
11.90 /
13.02 S
15.24 f
15.36 X
18,12 /
18.68 f
21.61 /
21.71
24 . 91
25.02
25.94
26.16
26.48
31.64
31.78
33.27
PAH Ax
0.9
-2.3
QC
s
/
~
/
/•
sjj	O
ES/SS
4.0
-1.3
Pred
RRT
.0004
.0003
.0003
.0003
.0003
.0002
.0002
.0002
1.0001
1.0001
1.0001
1.0001
1.0001
1.0001
1.0001
1.0042
1.0002
1.0002
1.0004
t; M
Checkcode

Actual
Diff


J^CO'-'tonc


SKT
Sees
Response
Ra
RRT
yng/Train _
Noise
DL
1.0001
-0.2
2.82E+09
-
1
0 %J
39,700
2.07E+05
11.90000
1.0003
a
1.44E+09
-
1
11
21,900
1.07E+O4
0.99500
1.0003
0
1.42E+09
_
0
86
16,800
2.72E+05
12.60000
1.0003
0
1.16E+08
-
1
00
1, 920
1.79E+05
10.50000
1.0006
+ 0 .2
2.24E+08

1
05
3,680
1.32E+05
8.13000
1.0002
0
2.24E+09
-
1
12
21,200
1.30E+04
0.52600
1.0002
0
2.34E+08
-
1
09
2,480
1.30E+04
0.53100
1.0002
0
1.15E+09
-
1
02
9,280
4.20E+04
1.36000
1.0001
0
9.20E+08
-
1
03
5,830
4.20E+04
1.13000
1.0001
0
6.98E+07
-
1
00
795
1.30E+04
0.71100
1.0001
0
1.36E+08
-
1
11
1, 500
1.30E+04
0.70900
1.0007
+0.9
1.051+08
-
0
99
1,100
1.01E+04
0.68100
1.0004
+0.5
3.64E+07
-
0
90
341
1.01E+04
0.77600
1.0001
0
5.64E+07
-
0
93
598
1.01E+04
0.80600
1.0001
0
2.86E+07
-
0
86
341
1.01E+04
1.08000
1.0042
0
3.59E+06
-
0
90
53.7
1.01E+04
1.26000
1.0002
0
2.04E+07
-
0
93
386
6.30E+03
1.57000
0.9990
-2,3
3.39E+06
-
0
89
66.8
6.12E+03
1.97000
1.0003
-0.2
2.95E+07
-
0
95
452
6.3OE+03
1.51000
/
Analytical Perspectives
Page 1 of 2
Printed: 8/5/2008 2:28 PM
-------
Datafile: e: 080729V23
Client ID: Run# I-ACD-M23-1
Lab ID: P9464 6042 PAH 002
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
PAH Ax
0.9
-2.3
ES/SS
4.0
-1.3
Name
Actual
ET
Pred
RRT
13C6-Naphthalene
13C6•2 -Kethylnaphthaiene
13C6-Acenaphthylene
13C6-Acenaphthene
13C6-Fluorene
13C6-Phenanthrene
13C6-Anthracene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a)Anthracene
13C6-Chrysene
13C6-Benzo (b( Fluorarithene
13C6-Boiizo (k)Fluoranthene
13C4-Benzo(ei Pyrene
13C4-Benzo(a)Pyrene
<312-Perylene
13C6-Indeno(1,2,3-cd)Pyrene
13C6-Dibenzo(ah)Anthracene
13C12-Benzo(ghilPerylene
8.59
9.75
11.54
11.89
13.01
15.24
15.36
18.12
18.6?
21.61
21,71
24.90
25.01
25.94
26.15
26.37
31.63
31.81
33.26
0.8857
1.0063
0.9757
1.0057
1.1002
1.2890
1.2995
0.9724
1.0025
1.1602
1.1656
0.9557
0.9597
0.9956
1.0040
1.0124
1.2143
1.2217
1.2766
AS--Anthracene
15.32
1.2897
SS-Fluorene
SS-Terphenyl
12.94
19.03
0.9949
1.0506
JS-Methylnaphtha! ene
JS-Acenaphthene
JS-Pyrene
JS-Benzo(a)Pyrene
9.69
11.82
18.63
26.06
Analytical Perspectives
Wt/Vol; 1 Train	ICAL: MM6
Actual
RRT
0.8864
1.0065
.9759
.0058
.1002
.2891
.2993
.9725
.0025
.1601
.1654
. 9555
0.9598
0.9956
1.0040
1.0122
1.2139
1.2209
1.2767
1.2954
0.9949
1.0504
Diff
Sec b
+ 0.4
+ 0.1
+ 0.1
+ 0.1
0
+ 0.1
-0.1
+ 0.1
0
-0.1
-0.2
-0.3
+ 0.2
0
0
-0.3
-0.6
-1.3
+ 0.2
+4.0
0
-0.2
Response
2.61E+06
2.37E+Q6
,94E+06
.42E+06
.31E+06
.78E+06
,47E+06
4.86E+06
6.12E+06
3.52E+06
3.28E+06
7.77E+06
9.50E+06
8.11E+06
7.77E+06
5.91E+06
4.55E+06
4.54E+06
5.51E+06
2.73E+06
2.28E+06
2.32E+06
Ha
RRF
1.51
0.96
1.79
1.06
1.11
1.76
1.64
1.25
1.30
1.06
1.02
1.21
1.60
1.30
1.39
1.36
0.81
1.00
1.15
1.44
0.96
0.54

J
2.93E+06
2.41E+06
4.16E+06
3.16E+06
PAH 080118 18JAN08
Recv,
58.8
84. 5
91.6
95.0
86.6
89.4
88.0
93.7
113.0
79.9
77.6
101.0
94.0
98.4
88.1
68.6
89.3
71.9
75.6
79.1
103.0
89.2
Page 2 of 2
Printed; 8/5/2008 2:28 PW
-------
AP Lab ID: P9464_6042_PAH_002
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
Acq: 30-Jul-2008 00:24:38
User: CEM Datafile: 080729V23
Rel. int.
100%-,
Fn 1
130-9920
QC Check
7.02-10.55
0%-
¦ I '
7.5
8.0
i | i
8.5
9.0
9.5
10.0
Abs. Int.
-4.53e7
2.27e7
¦O.OOeO
10.5 RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
10.59-17.00'
0%4
< | I I t I | I I > I | I >
11.0	12.0
13.0
14.0
1 I 1
15.0
16,0
r 1 i i i i
Abs. Int.
-5.51e7
2.76e7
•O.OOeO
17.0 RT
Rel. Int.
100%-
Fn 3
218-9856
QC Check
17.02-23-00
0%-
'"I	t	t	I	y	1	1	1	1	 'I
18.0
19 0
-i—'—'—'—1—i—'
20.0
i'	|	i	y	i	r	|	»¦¦¦¦
21.0
I 1 I 1 I I t
Abs. Int.
- 2.97e7
•1.49e7
22 0
-O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01
0%-
24.0
->—1—r
26.0
28.0
30.0
32.0
34.0
Abs. Int.
-2.30e7
¦1.15e7
¦O.OOeO
RT
Results P:\P940Q_P9499\P9464_6042 PAH\nBSOurcesV:V464_6042_PAH_002 utp_res. saved 01-Aug-2008 13:56 (CM)
AP Ultra Trace-Pro V3.992 User/System: CM/CMP4-015 see: 940-020
Peak annotation: Areas, Centroids
PHD: ft/a Printed: 01-Aug-200S 14:08:25 Paget of 9
-------
AP Lab ID: P9464_6042_PAH_002
Instr: AutoSpec-Premier MM6
Naphthalene
Rel. Int.
Fn1 100%-q
128.0626
Analyte
4 o 2.07e5
8.40-10.20
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
0%-
Rel. Int.
Fn 1 100%^
134.0827
Standard
4o 2.44e3
8.40-10.20
0%-
Ret. Int.
Fn 1 100%^
142.0783
Analyte
4o 1.87e4
8.40-10.20
0%-
Rei. Int.
Fn1 100%*
148.0984
Standard
40 1.9563
8,40-10.20
0%-
Rel. Int.
Fn 1 100%l
152.1410
Standard
4o 2,34e3
8.40-10.20
0%-
ES-Naphthalene
2.61e6
8.59
'I	i r""i i | »"!' i i |
8.6
-i—»—i—i—|—i—i—i—i—| i i—i	i	
8.6
3.52e5
8.60
	;
8.6
2.75e5
8.60
i"i'i j ^ t
8,6
8.8
9.0
9.2
¦ i ¦
9.4
96
9.8
8.8
l r | 1T"|'" i ¦ | "i—r—i—i—|—i—I—I—i—]—i—i—i—i—|—i—%—i—i—|—r
9.0	9.2	9.4
T
' I '
9.6
Acq: 30-Ju1-2008 00:24:38
User: CEM Datafile: 080729V23
Abs. Int.
1.07e9
• 5.37e8
•O.OOeO
RT
Abs. Int.
•1.62e6
-8.08e5
10.0
9.8
2-Methyl naphthalene
1.4469
10.0
9.75
¦ I •
8.8
9.0
¦ i >
9.2
9.4
9.6
10.0
ES-2-Mettyi naphtha
-i-T-r
8.8
¦ i ¦
9.0
9.2
9.4
• i • • • ¦ i • ¦
9.6
JS-Methylnaphihale
2.93e6
9.69
10.0
8.8
-1—I—|—I—I—I—I—{—I—l""f	I ""|	1—!—I—I—|—I—I—I—I—|—I—I—I—I—|—I—I—I—I—|—I—I T I
9.0	9.2	9.4	9.6
1 1 1
9.8
10.0
-O.OOeO
RT
Abs. Int.
-1,01e9
5.07e8
O.OOeO
RT
Abs. Int.
-1,70e6
-8.51e5
| f
-O.OOeO
RT
Abs. Int.
-2.15e6
1.08e6
-O.OOeO
RT
Rel. Int.
pn i 100%-
130.9920
QC Check
8.40-10.20
Q%-
'W
~\r
8.8
¦T-1-1"
9.0
"r"T~r
9.2
T*"
9.4
Results: P:\P9400_P9499\P9464_6042 PAH\rescurces\P9464_S042_PAH_002.utp_res. saved 01-Aug-2008 13:56 (CM)
AP UltraTrace-Pm V3M2 Usei/System: CM/CMP4-015 cc: 3355. ~5S70~4181, 6949. 5384 see: 940-020
9.6
Revised: 01-Aug-2008 11:05:57 (CM)
Abs. Int.
4.52e7
2 26e7
O.OOeO
RT
Peak annotation: Areas. Centroids - y
Printed: 01-Aug-2008 14:08:37 Page 2 of 9 ^
-------
AP Lab ID: P9464_6042_PAH_002
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expl: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
Rel. Int.
pn 2 100%
152.0636
Analyte
4o2.72e5
11.50-12.30
Acenaphthyie
I.42e9
II.54
Acq: 30-Jul-2008 00:24:38
User: CEM Datafile: 080729V23
Abs. Int.
1,04e9
•5.21e8
T—*T—I—I—]—I—1—1	F—|—I—1—1—T—|—T-
11.6	11.7
I 		' 1 1 I 1 ' 1 1 I 1 1
11.8	11.9
12,0
12.1
ES-Acenaphlhylene
Rel int. « K :
pn 2 100%- 11 54
158.0827
Standard
4a 3.51e3
11.50-12.30
Rel. Int.
Fn 2 100%-
154.0783
Analyte
40 1,79e5
11.50-12.30
0%-
11.5
Rel. Int.
Fn 2 100%-
160.0984
Standard
4o 2.64e3
11.50-12.30
0%-
r-1-
11.5
Rel. Int
Fn2 100%
164.1410
Standard
4o2 44e3
11 50-12.30 1
0%
r-r"
11.5
11.6
11.7
* 1 "
11.8
11.9
Aoenaphthene .
i.i6e8 /
11.90 J
12.0
12.1
I | f «
11.6
1 I 1
11.7
11.8
11.9
ES-Acenaphthene
2.42e6
11.89
12.0
¦T | I t
12.1
t f f 1 T t
11.6
¦¦¦I	|	t	r	¦«	i	|	>¦	y	y "i •
11.7	11.8
12.0
"t""| f i *i"r j t » "I""
12.1
JS-Acenaphthene
2.41e6
11.82
—>—f—'—i—i—i—[—i—i—i—i—|—r-
11.6	11.7
11.8
11,9
12,0
12.1
-'-"I	
12.2
12.2
12,2
¦O.OOeO
12.3 RT
Abs. Int.
-2.52e6
¦1.26e6
¦O.OOeO
12.3RT
Abs. Int.
-7.75B7
•3,87e7
¦O.OOeO
12.3 RT
Abs. Int.
1.73e6
•8.63e5
O.OOeO
"i—I T-f	*	»	)¦	r	i	i	r
12.2	12.3RT
' I "
12.2
Abs. Int.
-1.57e6
-7.86e5
¦ O.OOeO
12.3RT
Rel. Int.
Fn 2 100%
168.9888
QC Check
11.50-12,30
Results: P:\P9400_P9499\P9464_6042 PAH\resource$\P9464_6042_PAH_002Mlp_res. saved 01-Aug-2008 13:56 (CM}
AP UttraTrace-Pm V3.992 User/System: CM/CMP4-015 cc: 2199, 5448. 8086, 4509, 8160 SCC: 940-020
t [ i
12.2
Abs. Int.
-5.40e7
2.70e7
O.OOeO
12.3 RT
Revised: 01-Avg-2008 11:06:01 (CM!
Peak annotation: Areas, Cent raids
Printed: 01-Aug-2008 14:08:48 Page 3 of 9
-------
AP Lab ID: P9464_6042_PAH_002
Inslr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
Rel. Int.
100%
Fn 2
166.0783
Analyte
4o 1,32e5
12.70-16.50 1
Fluoren©
2.24e8
13.02
0%-
M
Rel. Int.
100%-
Fn 2
172.0984
Standard
40 3 32e3
12.70*16.50
0%-
13.0
ES-FIuorene
2.31 e6
13.01
t ¦Pri-

13.5
14,0
14.5
15,0
15,5
\ i i
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o1.30e4
12.70-16.50
0%-
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o2.25e3
12,70-16.50
0%-
13.0
13.5
I 1 J1 I I I
14.0
I i i f f I 'y "ifif	
14.5
I | I ! I I pi I (
15.0	15.5
Phenanthrene
2 24e9/
15.24/
I I | I I 1 T f I V I
13.0
i	|	i	i	i	i""My	»	i	t ¦¦¦
13.5
14.0
14.5
/
1 jittiraeene
2.34e8
15.36
JXr
15.0
15.5
ES-Phenanthrene
3.78e6
1S.24
13.0
' 1 1
13.5
II
X
14.0
14.5
15.0
I | I
15.5
Acq: 30-Jul-2008 00:24:38
User: CEM Datafile: 080729V23
Abs. Int.
-1 30e8
-r-f—r-
16.0
' I '
16.0
16.0
6.51e7
¦O.OOeO
fill
16,0
RT
Abs. Int.
-1.56e6
-7.79e5
-O.OOeO
RT
Abs. Int.
-1.07e9
¦5,36e8
-O.OOeO
RT
Abs. Int.
-2.27e6
¦ 1.14e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
168,9888
QC Check
12.70-16,50'
0%-
"¦r	T	t	J	I	T	T"'
13.0
13,5
'T	*	]	r	f	f	
14,0
""t	I	y.-yy-y"!	r	%			,	f	1	,			|	T..|
14.5
15.0
15.5
Abs. Int.
-5.51e7
•2.76e7
16.0
~l—r—r—t—i—-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_002 ulp_res. saved 01-Aug-2008 13:56 (CM)
AP UltraTraee-Pm V3M2 User/System: CIWCMP4-015 cc: 3734, 1165. 1246, 3712 see: 940-020
Peak annotation: Am as, CentmitSs
Revised: 01-Aug-2Q08 11:00:43 (CM} Printed: 01-Aug-20tm 14:08:59 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
176.1410
Standard
4o 2.36e3
12.00-16.50
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
Acq: 30-Jul-2008 00:24:38
User: OEM Oatafile: 080729V23
SS-Fluonene
2.28e6
12.94
0%-
12.0
f 11 |	I		 		I | II| 			|f | j 			 iy	T""! 1 ! [ I I I 1 '"t"'1	1 I I < I "t ') I 'I I I | 1 I I yifi|riT^	' r | I I i I | I1""'?'1		*|"^t	i""l	 O.OOSO
12.5
13.0
13.5
14.0
14.5
15.0
15.5
16.0
Rel. Int.
100%-
Fn 2
188.1410
Standard
4o 3.00e3
12,00-16.50 •
AS-Anthracene
2.73e6
15.32
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.00-16.50
Results: P:\P9400_P9499\P9464_6042 PAHVesources\P9464_6042_PAH_002utp_res. saved 01-Aug-2008 13:5S (CM)
AP UttmTmce-Pm V3.992 Useihystem: CM/CMP4-01S cc: 5331, 1523 see: 94£MB0
I 1 '
15.5
Peak annotation: Areas, Centroids
Revised: Ol-Aug-2008 11:05:50 (CM) Printed: 01-Aug-2008 14:09:10 Page 5 of 9
-------
AP Lab ID: P9464_6042_PAH_002
Iristr. AutoSpec-Premier MM6
Rel. Int.
pn 3 100%-
202.0783
Analyte
4a 4.20e4
17.50-22.50
0%-
Rel. Int.
Fn 3 100%
208.0984
Standard
4a 7.69e3
17.50-22.50
0%
Rel. Int.
Fn 3 100%"
205.0883
Standard
4a 3.41 e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-
228.0939
Analyte
4a1.30e4
17.50-22.50
0%-
Rel. Int.
Fn 3 100yol
234.1140
Standard
4o 2.34e3
17.50-22.50 :
0%
Fluoranthene
1.l5e9
16.12
Sample ID: Run# I-ACD-M23-1
J VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
Pyrene
9.20e8
18.68
Acq: 30-Jul-2008 00:24:38
User: GEM Datafile: 080729V23
Abs. Int.
-7.60e8
"'i	r	i""
18.0
ES-Fluoranthene
4.66e6
16.12
i_L
19.0
20.0
21.0
3 80e8
22.0
18.0
A -,a A	
18.0
—1—
18.0
18.0
-O.OOeO
RT
Abs. Int.
-3.05e6
-1.53e6
19.0
20.0
	i	>"
21.0
ES-FVrene
6.12e6
18,67
-i—(—i—i—i—i—|—i—i—¦—i—- O.OOeO
22.0	RT
Abs. Int.
3.61e6
1,81e6
19.0

20.0
8.13e6
18.71
.	P—r
	1	
21.0
2,2le7
21.07
22.0
t¦¦ 'g--1 i 0.OOeO
RT
Cfirysene
/1.36e8
/ 21.71
BenzfalAnthricene
6.9"
S.98e7
21.61
T—	I	"T "
19.0
—,—
20.0
A
—r
21.0
ilk
i 'i—»
Abs. Int.
-6.81e7
¦3.40e7
22,0
ES-Benz(aJAnthrace
3.52e6
21.61
19.0
20.0
21.0
-O.OOeO
RT
Abs. Int.
-1.84e6
•9.22e5
—i—i—i—.—>-0.00e0
22.0	RT
Rel. Int.
Fn 3 100%
218.9856
QC Check
17.50-22.50
0%-
—I—1
18.0
19.0
20.0
21.0
Rest/fe P:\P94OO_P9490\P9464_6O42 PAH)resources\P9464_6042_PAH_002.ulp_res, saved 01-Aug-2008 13:56 (CM}
AP UltraTrace-Pm V3.992 User/System: CM/CMP4-015 cc:~4484, 6278, B898, 0965. 2679 see: 940-020
22.0
Abs. Int.
-2.97e7
-1.49e7
•O.OOeO
RT
Peak annotation: Areas. Centwkls
Revised: 01-Aug-2008 11:05:19 (CM) Printed: 01-Aug-2008 14:09:22 Page 6 of 9
-------
AP Lab ID: F9464_6042_PAH_002
Instr; AutoSpec-Premier MM6
Re I, Int.
100%-
Fn 3
212.1410
Standard
4o 4.46e3
18.00-20.00
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
JS-
S-Pyrene
4.16e6
18.63
0% T I I 'Ff T' I I I | I I I I | I I T I1 |
18.2	18.4
Rel. Int.
100%-
Fn 3
244.1974
Standard
4o1.70e3
18.00-20.00
0% i i i i | ")"'t i i | i i"?t ' ' 'i'"*'
i ¦ ¦ ¦ ¦ i
18.6
Acq: 30-Jul-2Q08 00:24:38
User: OEM Datafile: 080729V23
Abs. Int.
r2.53e6
-1.27e6
iji i| mt n | n ; i i j i i i i i | i i p*i |! i i i r r i"i	i I1 i » i1 i | i i t i [ i i i i | i'" 'I i i" j i i I 'i O.OOeO
18,8	19.0	19.2	19.4	19.6	19.8	RT
18.2
18.4
I | I I I' I | I I !""l )'"l' III)
18.6	18.8
SS-Terphenyl
2.32e6
19.03
19.0

' I i [ I I I
19.4
• i i i I i
19.6
-r-fi-
19.8
Abs. Int.
-1.43ei
-7.14e5
i I i i i1	
-O.OOeO
RT
Rel. Int.
100%-,
Fn 3
218.9856
OC Check
18.00-20.00
0%-
""»""1—t—I—|—t—T"
18.2
18.4
18.6
18.8
19.0
19.2
19.4
19.6
| I I I } | » 1 I I |
19.8
Abs. Int.
2.89e7
•1.44e7
¦O.OOeO
RT
Results: P:\P9400_P9499\PS464_6042 PAHteSOUKesW464_6042_PAH_002.utp_re$. saved 01-Aug-200B 13:56 (CM)
AP Ultra Trace-Pro 1/3.992 User/System: CM/CMP4-015 cc: 2624, 7456 see: 940-020
Peak annotation: Areas. CentmidS /
Revised: 01-Aug-200d ir 06 06 (CM} Printed: Ot-Aug-2008 14:03:33 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH_002
Instr: AutoSpec-Premier MM6
Rel, Int.
100%-
Fn 4
252.0939
Analyle
4o 1.01e4
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
258.1140
Standard
4o 1,93e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o 2.57e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
264,1692
Standard
4o 1 ,?8e3
23,50-28.00
0%-
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah,db5_0801 GC: pah_db5-SPLT5 Vial: 74
BenzfblFluoranlhene
. 1,05e8,

24.0
24,5
Fluoranthene
64e7/
SOW
till	1	T
25.0
ES-Benz(b)Fluorant
?.77e6
24.90
A
5.64eT
rene
2,86e
26.16
Acq: 30-Jul-2008 00:24:38
User: CEM Datafile: 080729V23
Abs. Int.
2.69e7
¦1.35e7
25.5
26.0
26.5
1 I 1 1
27.0
I I I I 1 I 1
27.5
' I 1 ' ' ' I 1 ' ' 1 I '
24.0	24.5
-O.OOeO
RT
Abs. Int.
-3.00e6
-1.50e6
i | I'l1 TT | l lmT I | l l l
26,0
ES-Benz(e)Pyrene
8.11e6
2^--Benz{a)Pyreme
26,15
H | I I I I ) I I I I [ * I
26.5	27.0
"-r-|—I 1 I—I [ 1 I I—I ) I t i i | i ¦'! T I J i
24,0	24.5	25.0
25,5
-i—i—i—i—i—|—i—*—i—i—|—i—i—i—i—0 .OOeO
27,5	RT
Abs, Int.
2.69e6
¦ 1.35e6
26,0
t—I—I | I f 1 I I | 1
26.5
ES-Peiyiene
5.91 e6
26,37
27.0
• I ¦
27.5
JS-Benz(a)Pytene
3 16e6
26,06
24.0
¦nr
I | I I I I | ) I I I | T I I I ) i t	i '
24.5	25.0	25,5
-O.OOeO
RT
Abs. Int.
-1 78e6
-8.90e5
it1"! I r I—1 if I ""I' ¥ I ] 1'!' I |—I—I—I—I—|—I—I—I—I—|—I—1—1—I—I—I—I—I—I—0 .OOeO
26.0	26,5	27.0	27,5	RT
Rel. Int.
100%-
Fn 4
292,9824
GC Check
23.50-28,00"
0%-
l l I I | I f I 1 | I I
24.0
I | 1 I I I
24,5
—T	1 I I
25,0
I t t 1 | I I 1 1
25.5
26.0
26.5
I | I
I | I
27,0
' I '
27.5
Abs. Int.
-2.29e7
• 1.14e7
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6Q42 PAHVesources\P9464_6042_PAH_002 utp_res. saved 01-Aug-2008 13:56 (CM)
AP UUraTrace-Pm V3.992 User/System: CM/CMP4-015 cc: 6013, 34?T,~W94, 2000 see: 940-020
Peak annotation: Areas. Centroids
Revised: 01-Aug-2008 13:56:20 {CM} Printed: 01-Aug-2008 14:09:43 Page 8ofS
-------
AP Lab ID: P9464_6042_PAH_002
Instr: AutoSpec-Premier MM6
Rel. Int.
pn4 100%
276.0939
Analyte
4o 6.30e3
29.0-36.0
0%
29.0
Rel. Int.
Fn4 100%-
282.1140
Standard
40 3.33e3
29.0-36.0
0%-
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 74
Ind 123-cd)Pyrene
2.04e7
31.64
33.27
Acq: 30-Jui-2008 00:24:38
User CEM Datafile: 080729V23
Abs. Int.
¦4.96e6
• 2.48e6
1 I 1
34.0
35.0
6S-lnd£l|3wgJ)Pyre
31.63
	i	i	i i
29,0
Rel. Int.
Fn 4 100%"
288.1342
Standard
4o 1.35e3
29.0-36.0
0%-
29.0
Rel. Int.
pn 4 100%-
278.1096
Anatyte
4o6 12e3
29.0-36.0
0%-
29.0
Rel. Int.
Fn 4 100%-
284.1297
Standard
4o 1 60e3
29.0-36.0
0%-
29.0
1 | I I I I I
30.0
'i1 i i | t r i i
31.0
32.0
¦T i i t i i i i i—i t ¦ t ¦ i—i—r-1—i—i—i—r-T-
33.0	34.0
ES-Benz^ghi)Peryl
33 26
35,0
-i—i—i—r
r-"-
30,0
1 I '
31.0
T-r-
DibenzfahlAnthrace
3.39e6
31.78
-Y-—
33.0
1 I * | I
34.0
l l |—r
35.0
30,0
31.0
j | I I I t J I 1
32.0
* | 1 1 t 1
33.0
34.0
35,0
ES-Dibenz(ah)Anthr
4.54e6
31.81
™1~r
30.0
"" l	i	i—r-
31.0
¦O.OOeO
36.0 RT
Abs. Int.
-8.76e5
•4.38e5
•O.OOeO
36.0 RT
Abs. Int.
-8.92e5
•4.46e5
¦O.OOeO
36.0 RT
I I I I
Abs. Int.
-4.48e5
2.24e5
I.OOeO
36.0RT
32.0
¦ i	r	|	i ""i1 i1 i" | ¦ i i i
33.0
I | I I	I'	I' " | 	'I	'I "T ' [—r
34.0	35,0
Abs. Int.
-7.06e5
3.53eS
¦O.OOeO
36.0RT
Rel, Int.
pn 4 100%
292.9824
QC Check
29.0-36.0
29.0
30.0
31.0
32.0
[till
33.0
t I | I t t
34.0
35,0
Abs. Int.
2 30e7
1.15e7
O.OOeO
36.0RT
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_002 utp_ms saved OUAug-2008 13:56 (CM)
APUltmTmce-Pm V3.992 Useihysiem: CM/CMP4-015 cc: 3807, 8911 6361. 7816, 6958 see: 940-020
Peak annotation: Areas, Centroids
Revised: 01-Aug-2008 11:06:42 (CM) Printed: 01-Aug-2008 14:09:56 Page 9 of 9
-------
Datafile: e: 080730V14
Acquired: 30 Jul 2008 17:57:26-''
Client ID: Run# I-ACD-M23-1
Lab ID: P9464 6042 PAH 002-SPL300

Wt/Vol: 1 Train
J Level: 4 ngfTrain
2.


ICAL: MM6 PAH 080118 18JAN08
Nominal ES spike: 40 ng
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
•}£" Naphthalene
2-Methylnaphthalene
Acenapbthylene
Acenaphther.e
Fluorene
J)8r Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzol a)Anthracene '
Chrysene
Benzo»
QC
ES/SS
3.8
-1.7
Pred
RRT
1.0005
1.0003
1.0003
1.0003
1.0004
1.0003
1.0003
1.0001
1.0001
1.0001
0.9998
1.0002
1.0003
1.0000
0.9997
1.0044
1.0002
0.9989
1.0004

Actual
RRT
1.0003
1.0003
1.0004
1.0003
1.0005
1.0002
1.0004
1.0001
1.0002
1.0000
.0001
.0007
.0011
.0002
.0004
1.0036
1.0009
1.0002
Diff
Sees
-0.1
0
+ 0.1
0
+ 0.1
-0.1
+0.1
0
+0.1
-0.1
+0.4
+ 0.7
+1.2
*0.3
•-1.1
-1.3
fl.3
-0.4
Checkcode:
Cone
r|(o
/
Response
Ra
RRF
/ng/Train ./ * Noise
! —	r
DL
2.33E+08
-
ljjjj-*
130,000 Jt
2.99E+04
56.80000
2.84E+07
-
1.11
23,700
8 -10E+03
21.10000
2.04E+07
-
0.86
15,800
9.55E+03
23.70000
1.88E+06
-
1.00
1,740
9.55E+03
40.70000
3.40E+06
-
1.05
3,320
6.46E+03
26.20000
4.95E+07
-
1.12
25,700 M
5.50E+03
11.80000
3.72E+06
-
1.09
2,870
5.50E+03
15.50000
1.68E+07
-
1.02
9,470
7.14E+G3
17.80000
1.33E+07
-
1.03
5,540
7.14E+03
11.70000
8.27E+05
-
1.00
756
2.39E+03
13.10000
1.47E+06
-
1.11
1,310
2.39E+03
10.40000
1.26E+06
-
0.99
1,080
3.40E+03
24.30000
6.10E+05
-
0.90
405
3.40E+03
17,20000
8.09E+05
-
0.93
543
3.40E+03
20.60000
3.91E+05
-
0.86
392
3.40E+03
29.00000
8.07E+04
-
0.90
88.7
3.40E+03
36.10000
2.24E+05
-
0.93
449
2.09E+03
32.70000
-
-
0.89
ND
1.78E+03
#VALUE!
4.Q3E+05
-
0.95
368
2.09E+03
24.00000
K H
Analytical Perspectives
Page 1 of 2
Printed: 8/5/2008 2:2a PM
-------
Datafile: e: 080730V14
Client ID: Run# I-ACD-M23-1
Lab ID: P9464 6042 PAH 002-SPL300
Wt/Vol: 1 Train
Stats
Largest tve RT shift (sees!
Largest -ve RT shift (sees)
PAH Ax
1.3
-1.3
ES/SS
3.8
-1.7
Actual
RT
Pred
RUT
Actual
RRT
Diff
Sees
13C6-Naphthalene
13C6-2-Methylnaphthalene
13C6-Acenaphthylene
13C6-Acenaphther.e
13C6-Fluorene
13C6-Phenan threne
13C6-Anthracene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a)Anthracene
13C6-Chryser.e
13C6-Benzo(b)Fluoranthene
13C6-Benzo(k)Fluoranthene
13C4-Benzo(e) Pyrene
13C4-Benzo(a)Pyrene
dl2-Perylene
13C6-Indeno(l,2,3-cdi Pyrene
13C6-Dibenzo(ah)Anthracene
13C12-Benzo(ghi)Perylene
AS--Anthracene
8.56
9.75
11.54
11.90
13.02
15.25
15.37
18.12
18.68
21.62
21.71
24.91
25.01
25	.95
26.16
26	.38
31.62
0.00
33.27
15.32
0.8855
1.0063
0.9757
1.0059
1.1003
1.2892
1.2995
0.9725
1.0025
1.1602
1.1663
0.9557
0.9604
0.9958
1.0046
1.0127
1.2144
1.2235
1.2772
1.2897
0.8838
1.0063
0.9756
1.0059
1.1003
1.2885
1.2989
0.9726
1.0024
1.1603
1.1652
0.9556
0.9598
0.9956
1.0035
1.0122
1.2133
0.0000
1.2764
1.2950
-1.0
0
-0.1
0
0
-0.5
-0.4
+0.1
-0.1
+0.1
-1.2
-0.2
-0.9
-0.3
-1.7
-0.8
-1.7
-1.3
+ 3.8
SS-Fluorene
SS-Terphenyl
12.95
19.04
0.9949
1.0507
0.9947
1.0503
-0.2
-0.4
J S-Methylnaphtha i ene
J S-Acenaphthene
JS-Pyrene
JS-Benzo(a)Pyrene
9.69
11.83
18.63
26,06
Analytical Perspectives
Page 2 of 2
ICAL: MM6 PAH 080118 18JAN08
Response	Ra	RRF /	Recv.
6.58E+04	-	1.51 \/	90.3
4.32E+04	-	0.96	93.5
6.032+04	-	1.79	72.7
4.35E+04	-	1.06	8B.4
3.90E+04	-	1.11	75.0
6.89E+04	-	1.76	84.5
4.78E+04	-	1.64	62.9
6.95E+04	-	1.25	88.7
9.34E+04	-	1.30	114.0
4.38E+04	-	1.06	65.9
4.02E+04	-	1.02	63.0
9.47E+04	-	1.21	78.3
1.34E+05	-	1.60	84.1
1.28E+05	-	1.30	98.5
9.24E+04	-	1.39	66.4
8.05E+04	-	1.36	59.2
4.31E+04	-	0.81	53.6
O.OOE+OO	-	1.00
9.25E+04	-	1.15	80.5
/
3.99E+04	-	1.44	59.8
J
4.12E+04	-	0.96 J	111.0
3.06E+04	-	0.54	82.2
4.83E+04	-
4.64E+04	-
6.29E+04	-	-
4.99E+04	-	-
Printed: 8/5/2008 2:28 PM
-------
AP Lab ID: P9464_6042_PAH_002-SPL300
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 74
Acq: 30-Jul-2008 17:57:26
User: OEM Datafile: 080730V14
Rel. Int.
100%-
Fn 1
130.9920
QC Check
7.02-10.55
0%-
7.5
r-|—,
8.0
8.5
1 I '
9.0
9.5
10.0
Abs. Int.
-6.74e7
•3.37e7
¦O.OOeO
10.5 RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
o%-v
Abs. Int.
8.04e7
4.02e7
O.OOeO
17.0RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.01
0%-
ia.o
19.0
20.0
21.0
22.0
Abs. Int.
-4.27e7
¦2.13e7
¦O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01
0%-
24.0
26.0
28.0
30.0
32.0
Results: P:\P9400_P9499\P9464_6042 PAMte3OUKes\P9464_604Z_PAH_002-SPL300.utp_res. saved 31-Jut-2008 14:38 (CM)
AP l/#ra Trace-Pro V3.992 User/System: CMCMP4-OI5 see: T89-568
34.0
Abs. Int.
-3.54e7
¦ 1,77e7
•O.OOeO
RT
Peak annotation: Areas, Cenlroids
PKO: n/a Printed: 31-Jut-2008 16:40:44 Page 1 of 9
-------
AP Lab ID: P9464_6042_PAH_002-SPL300
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 74
Rel. Int.
Fn! 100%-
128.0626
Analyte
4o 2.99e4
8.40-10.20
0%-
Rel. Int.
Fn 1 100%-,
134.0827
Standard
4a 1.38e3
8.40-10.20 :
Naphthalene

p°l, ^
Acq: 30-Jul-2008 17:57:26
User: CEM Datafile: 080730V14
Abs. Int.
1 93e8
•9.65e7
"j	1	I	1	%	'(	1	*	t	t	J	»	I	y	|»""J	1	1	»¦¦¦"»	j	*	r-H—T-i T
8.8	S.O	9.2
¦ i ¦
9.4
	i	T""'j	y	»	>¦	rm|(		<	i	|	%	't	i	%	|	i	*	t	i1	|	I""1
9.6	9.8	10.0
ES-Naphthalene
6,5864
8.58
Rel. Int.
Fn1 100%-
142.0783
Analyte
4o8.10e3
8.40-10.20
0%-
Rel. Int.
Fn1 100%.
148.0984
Standard
4o 1,07e3
8.40-10.20
0%-
Rel. Int.
Pni 100%-
152.1410
Standard
4o 9.84e2
8.40-10.20
0%-
8.6
8.8
9.0
	i	i	%	|	r	r	i	r	|"""r
9.2	9.4
	|	i	i	i	r	|""'t	r1"
9.6
1ST"
2-Methyl naphthalene
2.84e7
9.75
T-rr
8.6
1,06e4
8.57
TT-r
8.8
T"1"
90
¦ i ¦
9.2
I
9.4
¦ i 1
9.6
9.8
ES-2-Methytnaphtha
4.32e4
9.75
8.6
?.42e3
8.57
8.8
I ' ' ' 1 I 1
9.0
9.2
—I I | 1 t > 1 | 1 f I 1 | > I I < [ I
9.4	9.6	9.8
JS-Methylnaphthale
4.83e4
9.69
8.6
' I '
8.8
9.0
1 I 1
9.2
¦ i ¦
9.4
9.6
9.8
•O.OOeO
10.2 RT
Abs. Int.
-7,12e4
-3.56e4
I I I I I I t I
-O.OOeO
10.0
100~
-'•'I '
10.0
10.0
10,2 RT
Abs. Int.
-2,09e7
¦1.05e7
•O.OOeO
10.2 RT
Abs. Int.
i-5.47e4
-2.74e4
•O.OOeO
10.2 RT
Abs. Int.
-S.37e4
2 68e4
¦O.OOeO
10 2 RT
Rel. Int.
Fn 1 100%-
130.9920
QC Check
8.40-10.20 "
Abs. Int.
-6 74e7
-3.37e7
0%-
¦ | i i i i | t i r i | t
8.6	8.8
| i i r i j i i
9.0
TT
9.2
f | I I 1 I | t
9.4
9.6
'*	1	'	¦	
9.8
1 > \ ) I I I 1 |
10.0
-O.OOeO
10.2 RT
Results: P:\P9400^P9499\P9464_6042 PAH)resources\P9464J6042_PAH_002-SPL300.utp_ms, saved 31-M-2008 14:38 (CM)	Peak annotation: Areas, Centroids
AP UltraTrace-PncT V3 992 UsertSystem: CM/CMP4-015 cc: 9364, 9369.~B614. 0365, 2086 see: 189-568	RevisBd: 31-M-2008 14:37:15 (CM) Printed: 31-Jul-20Q8 16:40:55 Page 2 of 9
-------
AP Lab ID: P9464_6042_PAH_002-SPL300
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC; pah_db5-SPLT300 Vial: 74
Rel. Int.
Fn 2 100%'
152,0636
Analyte
4o 9,55e3
11.50-12.30
Acenap
2.( .
11.55
Acq: 30-Jul-2008 17:57!26
User: CEM Datafile: 080730V14
Abs. Int.
!.44e7
•7.19e6
'»	|	t	t	I	T	|	1	1"" 1—]	1~
11.6	11.7
11.8
-j—i—r—i—f | '1*1—i—i—|—i i i—i—[—i—i—r—r—|—i i i—i—|—r—i—i—i—f—f—if1* |—r-
11,9	12.0	12.1	12.2
Rel. Int.
Fn2 100% ¦
158.0827
Standard
4o1.18e3
11.50-12.30
0%
ES-Acenaphthylene
6.03e4
11.54
'0 f
11.5
11.6
11 11 I '
11.7
' I 1 » • ' I 1 1 ' 1 I
11.8
Rel. Int
Fn 2 100%q
154.0783
Analyte
4cr 9.55e3
11.50-12.30
0%
Rel. Int.
Fn 2 100%
160.0984
Standard
4o 1.26e3
11 50-12.30
I.70e5
II.54
Aeenaonthene
~pnin
,B8e6
I ' ' 1 ' I ' ' ' ' I
12.0
-r-r-f
12.1
ES-AcenapMherie
4.35e4
11.90
0%-
11.5
11.6
11.7
Rel. Int.
Fn 2 100%-
164.1410
Standard
4o9.39e2
11.50-12,30
0%-
I	I
11.8
JS-Acenaphthene
4.64e4
11,83
11.9
12.0
12 1
Ifflllllllllff
11.5
11.6
11.7
11.8
Itllllfllllft
11.9
12.0
12.1
12.2
12.2
' 1 ¦
12,2
-r-r
•O.OOeO
12,3 RT
Abs. int.
-6.48e4
•3.24e4
-O.OOeO
12 3RT
Abs, Int.
-1.22e6
•6.12e5
•O.OOeO
12.3RT
Abs. Int.
-4.07e4
-2,03e4
•O.OOeO
12.3RT
Abs. Int.
-4,81e4
2.40e4
O.OOeO
12.3RT
Rel. Int.
Fn 2 100%'
168.9888
QC Check
11.50-12.30
0%——!—i—i—r—{—i—*—i—i—|-
11.5	11.6
Abs. Int.
i-7.79e7
-3.89e7
O.OOeO
12.3 RT
Results: P \P94O0_P9499\P9464_6O42 PAH\resources\P9464_6042_PAH_002-SPL300utp_res. saved 31-JUI-2008 14:38 (CM)	Peak annotation: Areas, CentmJds
AP Ultra Trace-Pro' V3.992 User/System CM/CMP4-01S cc- 8734, 1268. 6255, 1116, 4836 see 189-568	Revised: 31-Jul-2008 14:37:20 (CM) Printed: 31-Jut-2008 16:41:04 Page 3 of 9
-------
AP Lab ID: P9464_6042_PAH_002-SPL300
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_08D1 GC: pah_db5-SPLT300 Vial: 74
Rel, Int.
100%-
Fn 2
186.0783
Analyte
4cj 6.46e3
12.70-16.50
0%-
Fluorene
3.40eS
13.03
Acq: 30-Jul-2008 17:57:26
User: CEM Datafiie: 080730V14
Abs. Int.
-2.03e6
¦1.01e6
-N\
i i" i ¦» i ¦
Rel. Int.
100%-
Fn 2
172.0984
Standard
4c 1.34e3
12.70-16.50
0%-
13.0
ES-Fluorene
3.90e4
13.02
¦A
13.5
T" I" | I '	I I
14.0
¦ i ¦
14.5
15.0
¦ i ¦
15.5
16.0
I ' 1 • ' I 1
13.0
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o 5.50e3
12.70-16.50
0%-
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o 9.94e2
12.70-16.50
0%-
l • 1 1 1 f '
13.5
14.0
' I ' ' ' ' I
14.5
' ' I '
15.0
,MJ	1	T	f	1	|	T	T	T	T	J	T	*	t	*	J	t	I	1,MI
15.5	16.0
-O.OOeO
RT
Abs Int.
~4.51e4
2.25e4
Phenanthrene,
4.95e7 /
15.25 /
/
Anthracene
3.72e6
15.38
13.0
' I ¦ i i i | ' i i > | >
13.5	14.0
|f i i "T	»	|	i	't	r	>	|	i	i	i	>	j	i	i	i	
14.5	15.0
I
-A-
15.5
16.0
ES-Phenanthrene
6.89e4
15.25
13.0
' I '
13.5
14.0
' I '
14,5
{ f \ i I | I I I I |
15.0
	I	
15.5
T I *
16.0
I i i—i—i—*—O.OOeO
RT
Abs. Int.
-3 06e7
-i—i—i—r—i—r
1.53e7
•O.OOeO
RT
Abs. Int,
-6 02e4
•3.01e4
—I—*—*—i—i—-O.OOeO
RT
Rel. Int.
100%
Fn 2
168.9888
QC Check J
12.70-16.50
0%
Abs. Int.
.04e7
4.02e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\fesauPce$\P9464_6042_PAH_002-SPL300.utp_res, saved 31-M-2008 14:38 (CM)	Peak annotation: Areas. CentroidS
AP UltraTrace-Pro V3992 User/System: CWCMP4-01S cc.4145. 3448. 1790. 0065 scc:"l89-568	Revised: 31-Jul-2008 14 30:28 (CM) Printed 31-Jul-2008 16.41 13 PagS 4 of 9
-------
AP Lab ID: P9464_6042_PAH_002-SPL300
Instr; AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
176.1410
Standard
4o 1,34e3
12.00-16.50
Rel. Int.
100%-
Fn 2
188.1410
Standard
4o 1.37e3
12.00-16,50 f
0%-
12.0
SS-FIuorene
4.12B4
12.95
Sample ID; Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 74
Acq: 30-Jul-2008 17:57:26
User: CEM Datafile: 080730V14
Abs, Int.
-4.82e4
AS-Anthracene
3.99e4
15.32
—i—t—i—i—j—i—i—¦—i—p
12.5
13.0
13.5
i j i i i t ; i » i t j i i i r | i t y r | %
14.0	14,5	15,0
2.41e4
I
15.5
OOOeO
RT
Abs. Int.
-4.93e4
-2.46e4
—i—r-i—t—|—i—i—i—i—j—i—i—i i O.OQeO
16.0	RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.00-16.50
0%
12.0
I I | 1 I I I ' | "T1"
12.5
13.0
,mt	^	*	r	r""T""y"" t""V"
13.5
14.0
14.5
' I '
15.0
Results: P:V9400_P9499\P9464_6Q42 PAHVesources\P9464_6042_PAH_002SPL300Mtp_res. Saved 31-M-2008 14:38 (CM)
AP UltraTrace-Pm V3 992 User/System: CM/CMP4-015 cc: 1412, 9860 see: 189-568
* |"r "T' T ""I	I	t	r""T	t	j""T"T""T""T""		1	T"
15.5	16.0
Abs. Int,
- 8 04e7
4 02e7
¦O.OOeO
RT
Peak annotation: Areas, Centmids
Revised 31-Jul-200B 14:37:08 (CM) Printed: 31-Jut-20W 16:41:23 Page 5 of 9

-------
AP Lab ID: P9464_6042_PAH .002-SPL300
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn 3 100%-
202.0783
Analyte
4o7.14e3
17.50-22.50
0%-
Rel. Int.
Fn3 100%-
208.0984
Standard
4cr4.05e3
17.S0-22.5O
0%-
Rel. Int.
Fn 3 100%1
205.0883
Standard
4o 2.36e3
17.50-22,50
Rel. Int.
Fn 3 100%
228.0939
Analyte
4c2.39e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-q
234.1140
Standard
4o 1.03«3
17.50-22,50 -I
Ruoranlhene
1.68e7
18.13
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 74
Pyrene
1,33e7
18.68
Acq; 30-Jul-2008 17:57:26
User: CEM Datafile: 080730V14
Abs. Int.
-1.03e7
18.0
ES-Fluoranthene
6.95e4
18.12
19.0
20,0
21.0
22.0
18.0
19.0
20.0
21.0
22.0
ES-Pyrene
9,34e4
18.68
18,0
i
19.0
•, i r • i [ f i-
20,0
A
Benz(a!Anthracene
21.62
5.15e6
-O.OOeO
RT
Abs, Int.
-5.73e4
-2.8Se4
| . , Tssss^^ | V 1 T" ! t | ^ssS=T=^
21.0	22.0
ES-Benz(a)Anthrace
4.38e4
21.621
-O.OOeO
RT
Abs. Int.
- 7.69e4
3.85e4
OOeO
Abs. Int.
-7.78e5
3.89e5
¦ O.OOeO
RT
Abs. Int.
-3,83e4
1 92e4
OOeO
Rel. Int.
Fn 3 100%
218.9856
QC Check
17,50-22.50
18.0
190
20,0
Results: P:\P9400_PS499\P9464_6042 PAHSresoumes\P9464_6042_PAH_002-SPL3WMtfl_re$, saved 31-Jul-20O8 14:38 (CM)
AP UttraTrace-Pro V3.992 User/System: CM/CMP4-C15 cc 8371, 8568, 1827. 5116, 4954 sec: 189-568
21,0
Revised: 31-Jul-2008 14:36:26 (CM)
22.0
Abs. Int.
-4.27e7
2.13e7
O.OOeO
RT
Peak annotation: Areas. Centroids
Printed; 31-M-2008 16:41:32 PagB 6 of 9
-------
AP Lab ID: P9464_6042„ PAH_002-SPL300
Instr: AutoSpec-Premier MM6
Rel. Int.
100%'
Fn 3
212,1410
Standard
4o 2 59e3
18.00-20.00
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 74
JS-Pvrene
6,29e4
18.63
ft
Acq: 30-Jul-2008 17:57:26
User: CEM Dataflle: 080730V14
Abs. Int.
r5.68e4
2.84e4
Rel. Int.
100%
Fn 3
244.1974
Standard
4o 1.32e3
18.00-20.00
SS-Te
19.04
D m 		I	,'"t I I I I I I I I I I I I
O.OOeO
RT
Abs. Int.
-3.77e4
1.88e4
O.OOeO
RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
18.00-20.00
0%-
18.2
18.4
18.6
18.8
I1 I
i [ I 1
19.0
% 1 | I I I I J
19.2
t ir | f
19.4
i j i
' I '
19.6
' I 1
19.8
Abs. Irit.
-4.18e?
¦2.0967
¦O.OOeO
RT
Results: P \P940Q_P9499\P9464_6042 PAH\rescurces\P9464_6042_PAH_002-SPL300vtp_res. saved 31-Jul-2008 14:38 (CM)
AP UHraTrace-Pro V3.992 User/System CM/CMP4-01S cc: 7467. 2109 see: 189-568
Peak annotation: Areas. Centroids
Revised: 31-Jul-2008 14:37:11 (CM) Primed: 31-Jul-2008 16:41:41 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH_002-SPL300
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4o3 40e3
23.50-28.00
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 74
0%-
BenzfWFIuoranthene
1.26e8
24.9r

BenlffilFtuoranttfene
1085/
5.04
26.48
Acq: 30-Jul-2G08 17:57:26
User: CEM Datafile: 080730V14
Abs. Int.
-3.27e5
24.0
24.5
25.0
i r | i i v * | i
25,5
26.0
26.5
27.0
I I I I | 1
27.5
1.64e5
Rel. Int.
100%-
Fn 4
258.1140
Standard
4o 1 06e3
23.50-28.00
0%-
ES-BerizJk)Fluorant
ES-Benz|b)Piiftkrit
I I ¦—r-1—|—I I I 1 |—I I I I ; I I I I | I
24.0	24.5
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o 1.72e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
264.1692
Standard
4o 1 02e3
23.50-28.00
0%-
24.0
1 1 1
24.0
25.0
' I ' ' ¦ ' I ¦-
25.5
1 I ' 1 1 ' I ¦
26.0
I | 1
26.5
27.0
""I	j""T""T""TMMTMM|	TMM1	1	1	J	1	1	1	f"
27.5
-O.OOeO
RT
Abs. Int.
-6.11e4
•3.05e4
ES-Benzfe)Pyrene
" 26.16
24.5
25.0
1 1 ' 1 ' ' I tt i » | i » i r | > i i r | i i i i 	t	>¦	>¦	i	[¦	i	i	i	i	|	¦!	i	i	t	I	»	i	r	r	y	
25.5	26.0	26.5	27.0	27,5
ES-Perylene
JS-BTJgyfene mS4
26,06	'*
-O.OOeO
RT
Abs. Int.
-5.30e4
2.65e4
24.5
[ I I 1 > | t •
25.0
I ' ' 1 1 ( ¦
25.5
26.0
26.5
27.0
-O.OOeO
RT
Abs. Int.
-3.83e4
¦ 1.91e4
27.5
—i—?—i-1- O.OOeO
RT
Rel. Int.
100%-
Fn 4
292 9824
QC Check
23.50-28.00
0%-
	r""i	i	i	|	r-
24.0
I I f I I 1 I*
24.5
25.0
25.5
	r""i	i'"
26.0
¦ i ¦
26.5
—|—I—I—I I |—I			—|—f—I—I' ¦ —r-
27.0	27.5
Abs. Int.
-3.53e7
1.77e?
-t—y i i ? i ¦ O.OOeO
RT
Results: P:\P9400_PS499\P9464_6042 PAffimsourcesW464_6042_PAH_002-SPL3Q0,utp_res. saved 31Jul-2008 14:38 (CM)	Peak annotation: Areas. Centroids
AP Ultra Trace-Pro V3 992 User/System CIWCMP4-015 cc: 9493. 8501 2278. 6253 see: *89-568	Revised: 31-Jul-2008 14:35:03 (CM) Printed: 31-Ju)-2008 16:41:50 Page 8 of 9
-------
AP Lab ID; P9464_6042_PAH_002-SPL300
Instr: AutoSpec-Premier MM6
Rel. Int
pn4 100%
276,0939
Analyte
4o209e3
29.0-36.0
Rel. Int.
pn4 100%-
282.1140
Standard
40 2.20e3
29.0-36.0
Sample ID: Run# I-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 74
Beriz(ghiil
0%-
29.0
Rel. Int,
pn 4 100%-q
288.1342
Standard
40 1.0163
29.0-36.0
0%-
29.0
Rel. Int.
pn4 100%-
278.1096
Analyte
4o 1.78e3
29.0-36,0
0%-
29.0
I 1 • 1 ' I
32.0
ES-!nd^123-cd)Pyre
31,62
30.0
" I 11 11 I 1
31.0
T
32.0
"j	1	T	T	1	J	1	X	I	T""
33,0
'"T	T	T	T'"
34.0
ES-Benz(ghi)Peryl
9.25e4
33.27
I 1 1 I I
30.0
31.0
l!|llIIJT1ll|f(
32.0
33.0
34,0
Acq: 30-Ju 1-2008 17:57:26
User: CEM Datafile: 080730V14
Abs Int.
-9.88e4
33.27
Indn 23-cd)Pyrene
2.24e5
31,65
35,0
35.0
4.94e4
OOeO
36.0 RT
Abs. Int.
-3.10e4
1 55e4
•OOOeO
360RT
Abs. Int.
3.57e4
-1 79e4
| i i i ;
•O.OOeO
36.0RT
Abs. Int.
-2.92e4
• 1 46e4
30.0
31,0
32.0
I j I I
33.0

•O.OOeO
34,0
35.0
36.0RT
Rel. Int.
Fn 4 100%'
264.1297
Standard
4o1.16e3
29.0-36.0
0%-
29.0
» I I > I
30.0
31.0
32.0
-f	T	f	1	J 1 1"
33.0
34.0
35.0
Abs. Int.
-2.54e4
¦ 1,27e4
¦O.OOeO
36.0RT
Rel, Int.
Fn 4 100%
292.9824
QC Check j
29.0-36,0
Abs. Int.
-3.54e7
1,77e7
i i i j O.OOeO
36.0RT
Results: P:\P9400_P9499\PQ464_6042 PAHVesources\P9464_6042_PAH_002-SPL300.vtp_res. saved 31-Jul-200S 14:38 (CM)	Peak annotation: Areas. Centivids
AP UftmTrace-Pro V3.982 User/System: CM/CMP4-015 cc: lo29. 2355, 6052. 3645, 0764 see: 189-568	Revised: 31-Jul-2008 14:36:06 (CM) Printed: 31-Jui-2008 16:42:00 Page 9 of 9
-------
Datafile: e: 080729V24
Acquired: 30 Jul 2008 01:04:11
Client ID; Run# I-ACD-M23-2
Lab ID: P9464 6042 PAH 003-/
Wt/Vol: 1 Train
J Level: 4^

ICAL: MM6 PAH 080118 18JAN08.
Nominal ES spike: 40 ng
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees!
Name
Naphthalene
2-Methylnaphthalene
Ac enaph thylana
Acenaphthene
Pluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)Anthracene
Chrysene
Benzo(b)Fluoranthene
Benzo(k)Fluoranthene
Benzo(e)Pyrene
Benzo(a)Pyrene
Perylene
Indeno(1,2,3-cd)Pyrene
Dibenzo(a,h)Anthracene
Benzo(ghi)Perylene
QlAfI

PAH Ax
1.5
-4,0
/
Actual
m
8.58 /"
9.75 /
11.53/
11.89/
13.0l/
15.24 /
15.36
18, ll/
18.67/
21.60 f
21.70 /
24.9a/
25.01 Z'
25.93 S
26.14 S
26.47 /
31.66 /
31.78 S
33.26 /
QC
ft-
uj Sps^o
ES/SS
-0.2
Pred
Actual
Diff
Checkcade:
Cone
i«iv
EST
RBT
Sees
Response
Ra
RHT
/ngrtrai*.

Noise

DL
1.0004
1.0000
-0.2
2.78E+09
-
>
1.09
/
40,700 /
1
20E+05
7
09000
1.0003
1.0002
-0.1
1.57E+09
-
1.11
/?5,200f,lt-
1
39E+04
0
79600
1.0003
1.0003
0
1.13E+09
-
0.86
13,900
2
31E+05
10
60000
1.0003
1.0003
0
1.O9E+08
-
1.00
1,890
1
63E+05
10
40000
1.0003
1.0006
+0.2
2.46E+08
-
1.05
4,270
1
15E+05
7
44000
1.0002
1.0002
0
2.25E+09
-
1.12
22,200
1
07E+04
0
45600
1.0002
1.0003
+0.1
2.20E+08
-
1.09
2,450
1
07E+04
0
43000
1.0002
1.0002
0
1.20E+09
-
1 . 02
10,100
3
33E+04
1
13000
1.0001
1.0001
0
9.24E+08
-
1.03
6,080
3
33E+04
0
89600
1.0001
1.0001
0
8.71E+07
-
1.00
1,020
8
02E+03
0
44800
1.0001
1.0002
+0.1
1.61E+08
-
1.11
1,830
8
02E+03
0
45000
1.0001
1.0006
+0.7
1.18E+08
-
0.99
1,250
8
69E+03
0
62300
1.0001
1.0002
+0.2
4.33E+07
-
0.90
421
8
69E+03
0
67300
1.0001
1.0001
0
6,21E+07
-
0.93
663
8
69E+03
0
70700
1.0001
0.9996
-0.8
1.57E+07
-
0.86
189
8
69E+03
0
96400
1.0042
1.0040
-0.3
1.37E+06
-
0 . 90
20.2
8
69E+03
1
08000
1.0002
1.0010
+1.5
2.51E+07
-
0.93
493
8
28E+03
2
18000
1.0002
0.9981
-4.0
3.85E+06
-
0.89
70.5
5
47E+03
1
82000
1.0004
1.0003
-0.2
3.12E+07
-
0.95
499
8
28E+03
2
09000

Analytical Perspectives
Page 1 of 2
Printed: 8/5/2008 2:28 PM
-------
Datafile: e: 080729V24
Client ID: Run# I-ACD-M23-2
Lab ID: P9464 6042 PAH 003
Stats
Largest -ve RT shift (sees)
Largest -ve RT shift (sees)
PAH Ax
1.5
-4.0
ss/ss
4.2
-0.2
Nome
Actual
RT
Pred
RET
1306-NaphthaJene
13C6-2-Mechy; naphtha1, er.e
13C6-Aeenaphthylene
13C6-Acenaphthene
13C6-Fluorer>e
13C6-Phenar.threne
13C6-Anthracene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a)Anthracene
13C6-Chrysene
13C6-Benzo(b)Fluoranthene
13C6-Benzo(k)Fluoranthene
13C4-Benzo(e)Pyrene
13C4-Benzo(a)Pyrene
dl2-Perylene
13C6-Indeno(1,2,3-cd)Pyrene
13C6-Dibenzo(ah 1 Anthracene
13C12-Benzo(ghi)Perylene
8.58
9.74
11.53
11.88
13.00
15,23
15.35
18.11
18.67
21.60
21.70
24.89
25.00
25.93
26.15
26.37
31.62
31.84
33 .25
0.8857
1.0063
0.9757
1.0057
1.1002
1.2890
1.2995
0.9724
1.0025
1.1602
1.1656
0.9557
0.9597
0.9956
1.0040
1.0124
1.2143
1.2217
1.2766
AS—Anthracene
15.31
1.2897
SS-Fluorene
SS-Terphenyl
12.93
19.02
0.9949
1.0506
JS-Methy1naphthalene
JS-Acenaphthene
JS-Pyrene
JS-Benzola)Pyrene
9.68
11.81
18.62
26.05
Analytical Perspectives
Wt/Vol: 1 Train
ICAL: MM6 PAH 080118 18JAN08
Actual
Dlff





RRT
Sees
Response
Ra
RRF
1
Recv.
0.8863
+0.3
2.51E.06
-
1.51
J
64.8
1.0065
+0.1
2.24E+06
-
0.96

91,4
0.9758
+0.1
3.76E+06
-
1.79

94.2
1.0058
+0.1
2.31E+06
-
1.06

97.8
1.1003
+0.1
2.19E+06
-
1.11

/m.s
1.2893
+ 0.2
3.61E+06
-
1.76

91.9
1.2995
0
3.31E+06
-
1.64

90.5
0.9724
0
4.64E+06
-
1.25

102.0
1.0024
-0.1
5.89E+06
-
1.30

124.0
1.1601
-0.1
3.43E+06
-
1.06

88.8
1.1656
0
3,16E+06
-
1.02

85.1
0.9557
0
7.66E+06
-
1.21

104 . 0
0.9601
+ 0.6
9.14E+06
-
1.60

94.5
0.9957
+ 0.2
8.05E+06
-
1.30

102.0
1.0042
+0.3
7.67E+06
-
1.39

90.7
1.0123
-0.2
5.98E+06
-
1.36

72.5
1.2143
0
4.39E+06
-
0.81

89.9
1.2226
+ 1.4
4.89E+06
-
1.00

80. 8
1.2768
+0.3
5.29E+06
-
1.15

75. 8
1.2956
+4.2
2.14E+06
-
1.44
/
66.6
0.9949
0
2.23E+06
_
0.96
J
106.0
1.0504
-0.2
2.34E+06
-
0.54
/
94.0

2,56E+06
2.23E+06
3.66E+06
3.03E+06
Page 2 of 2
Printed: 8/5/2008 2:28 PM
-------
AP Lab ID: P9464_6042 _PAH_003
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expl: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 75
Acq: 30-Jui-2008 01:04:10
User: CEM Datafile: 080729V24
Rel. Int.
100%-
Fn 1
130.9920
QC Check
7.02-10.55
0%-
I I I I | f I t r—jitiijii
7.5	8,0
8.5
w
I I '
9.5
10.0
Abs, Int.
~ 4.34®7
2.17e7
•O.OOeO
10.5 RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
10,59-17.00
0%-
11.0
120
1 I I | I f I 1	1
13,0

14.0
i f i i 1 t r-'j'-j i t
15.0
16.0
Abs. Int.
-5 32e7
•2.66e7
—i—i—f~ O.OOeO
17.0 RT
Rel, Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.00
0%-
18.0
» | f I I
19,0
I i I I I I I
20.0
21.0
22.0
Abs. Int.
-2.89e7
1,45e7
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
292,9824
QC Check
23,02-35.01'
0%-
Abs. Int.
r2,20e7
1.10e7
t—j—i	1	r-
24.0
T—1—""
26.0
28.0
30.0
32.0
¦i *—*—I » ¦ r 1 r T" ¦¦¦¦¦¦¦?	%	t	i""
34.0
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\msoume$\P94$4_6042_PAHj003.utp_res, saved 01-Aug-2008 11:24 (CM)
AP UltraTrace-Pro V3.992 User/System: CM/CMP4-015 see: 321-686
Peak annotation: Areas, Centroitfs
PKD. n/a Printed: 01-Aug-2008 14:10:08 Page 1 of 9
-------
AP Lab ID: P9464_6042_PAH..003
Instr: AutoSpec-Premier MM6
Rel. int.
Fn1 100%-
128.0626
Analyte
4ct 1.20e5
8.40-10.20
0%-
Naphthalene
Sample 10: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Viai: 75
Acq: 30-Jul-2008 01:04:10
User: GEM Datafile: 080729V24
Int
-1.0?e
8.8
I | I I I I | I 1 1 I | I I ( I | !
9.0	9.2
¦ • 			 ¦
¦i' f-i—»—!—r—|—i—»—r—i—p-%—r-i" i 11 11—i—11! !,j—?—r-
9.4	9.6	9.8
-5.37e8
O.OOeO
I 1 | I I I I | I 1 I I
10.0	RT
Rel. Int
pn1 100%-
134.0827
Standard
4a 1,70e3
8,40-10.20
0%-
ES-Naphthalene
2.51 e6
8.58
8.6
T-|-r
8.8
I J I ! I I | I '1 ""f"T "|	f
9.0	9.2
9,4
9.6
Rel. Int.
pni 100%-
142.0783
Analyte
4o 1 39e4
8.40-10.20
0%-
<^"c ' (£7>/0* - * ~ij
c Z%1 *5 /-w.* -
i ¦ ¦ i
2-Methyl naphthalene
1.57ei
9.75
I i i i i I i
10.0
Abs. Int.
-1.57e6
•?.85e5
¦ i 1
8.6
"T~r
8,8
I I t | I I
9.0
Rel. Int.
pn •] 100%
148.0984
Standard
401,27e3 1
8.40-10,20
0%-
	1	|""T"T

8.6
> ¦ i | > i i » | i t i "i	|—r
8.8	9,0
|!l«lf!ltlJ!Tl![VI!f|l!!V|!?!tjfV iM | I f 1 I jfl I f ! j I I I I J t f I t
9.2	9,4	9.6	9,8	10.0
ES-2-Meth
2.2'
9,74

¦O.OOeO
RT
Abs, Int
-1.03e9
5.17e8
"»	y	»	»'	I	I	|	I	I	I	I	|	I	1	1	1	|""
9.2	9.4
Rel. Int.
pn t 100%-
152.1410
Standard
4o 1.98e3
8.40-10.20
0%-
•"i	i	|	i	i	i		|IM"S	¦!	t'""i	|	i	rM
9.6	9,8
J S-Methylnaphthale
2,58e6
>.68
-O.OOeO
RT
Abs. Int.
-1.59e6
7.93e5
10,0
2.81 e5
8.60
l ll i—i—i—i—r-
I
8,6
-i—[—i—i—i—r—|—i—i—r—i—|—r—i—i—i—|—r—i—j—i—|—r
8,8	9,0	9,2
9.4
9.6
9.8
—i—ft ¦
10.0
¦O.OOeO
RT
Abs. Int.
-1,94e6
¦9.69e5
O.OOeO
RT
Rel. Int.
Fn1 100%-
130.9920
QC Check
8.40-10,20 '
0%-
""r""T""T""T""T. "I
8.6
8,8
I I ) I I I I | I I
9,0
T—f—I—!	1—I | I—I	I	I—|-T"
9.2	9.4
I 1 ' ¦ 1 I '
9.6
9.8
' I '
10.0
Abs. Int.
-4.34e7
2 17e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\iesous°ces\P9464_6042_PAH_003.utp_re$, saved 01-Aug-2008 11:24 (CM)
AP UltraTrace-Pro V3.992 User/System: CM/CMP4-015 cc: 6010, 0001, 4497, 6156, 8353 see: 321-686
Peak annotation: Areas, Centroids
Revised: 01-Aug-2008 11 23:30 (CM) Printed: 01-Aug-2008 14:10:19 Page 2 of 9
-------
AP Lab ID: P9464_6042_PAH_003
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 75
Rel. Int.
pn 2 100%
152.0636
Analyte
4o 2.31e5
11.50-12.30
Acenaphthyli
I.13e9
II.53
Acq: 30-Ju!-2008 01:04:10
User: CEM Datafile: 080729V24
Abs. Int.
-8.18e8
—i—i—i i i
11,6
11.7
-t—j—r-
11.8
11.9
12.0
' I 1
12.1
ES-AcenapWtiyiene
Rel. Int. 3.7ee6
Pn 2 100%
158.0827
Standard
4o3.81e3
11.50-12.30
11.53
11.5
11.6
1 I '
11.7
11.8
Rel. Int.
pn 2 100%-
154.0783
Analyte
4
-------
AP Lab ID: P9464_6042_PAH 003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
166.0783
Analyte
4o 1.15e5
12.70-16.50
Fluorane
2.46e8
13.01
0%-

Sample ID; Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Viai: 75
Acq: 30-Ju!-2008 01:04:10
User: CEM Datafile: 080729V24
Abs. Int.
-1,45e8
I I 	> T" I	 ¦ I'""

13.0
r 1 • ' '
13.5
14.0
Re!. Int.
100%-
Fn 2
172,0984
Standard
4o2.33e3
12,70-16.50
0%-
ES-Fiuorene
2.19e6
13.00
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o1,07e4
12.70-16.50
0%-
ffc.
0	„ L—	3 y _
1	-—|.i}
*,0
«$ "I
[' I I I 1 I 1 I < l"! 1 F 1 I ] t I I I ] 1 T I I [ T
14.5	15.0	15.5
I 0 o
•7.27e7
16,0
)"¦ I "T
¦ I 1
13.0
¦ r	'	
13.0
13.5
14.0
i i i i I i i i
14.5
15.0
1 1 1 / ' I '
/ 15.5
i—!—i—I—i—i—r-
Phenarithrefie
2.25e9
15.24
-i—I—i—r-
13,5
T
14.0
' I '
14.5
I | I I I
15.0
t inthracene
2,20e8
15.36
JL.-A,
15.5
TT
16.0
"i—i—i—I—i—i—r-
16.0
-O.OOeO
RT
Abs. Inl.
-1,48e6
¦7.40e5
O.OOeO
RT
Abs, InU
1.07e9
5.35e8
O.OOeO
RT
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o 1,97e3
12.70-16.50
0%-
13,0
ES-Phenanthrene
3.61 e6
15.23 |
| I t 1 I I | I 1 1 1	1 » I	* I | » I
13.5	14.0
14,5
| i t i i | » r t
15.0
/ i f i i
' I •
15.5
I | 1 1 I I | 1 I I !
16.0
Abs. Int.
-2.31e6
1.16e6
¦O.OOeO
RT
Rel. Int.
100% ¦
Fn 2
168.9888
QC Check
12.70-16.50'
0%-
"V"
> I '
13.0
i i I | l 1 l r |—r-
13.5
1 r*
14.0
"'1	1	T	J	»"
14,5
15.0
I I I | I
15,5
t I | I I I I
16.0
Abs. Int.
-5.32e7
•2.66e7
ii ii- O.OOeO
RT
Results: P:\P9400_P9499V9464_B042 PAH\resotmxs\P9464__6042_PAH_Q03.utp_ms, saved 01~Aug-2008 11:24 (CM)
AP UttraTrace-Pro V3.992 User/System: CM/CMP4-015 cc 7394. 3520. 2293, 5605 see: 321-686
Peak annotation: Areas. Centroids
Revised: OI-Aug-2008 11:22:04 (CM) Printed: 01-Aug-2008 14:10:42 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-,
Fn 2
176.1410
Standard
4a 2.91 e3
12.00-16.50
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 75
SS-Fluorene
2.23 e6
12.93
Acq: 30-Ju1-2008 01:04:10
User: CEM Datafile: 080729V24
Abs. Int.
1,54e6
0% l"T I I | I I I I | I T' I I | I I I l' | l I I I [	I" ""I	I	| I I I >'"f I" "I	I	I | I I I I' | Ol I I | I 1 I I '| I1 I I I |
12.0
12.5
13.0
13.5
14.0
14.5
15.0
i > j i | i 'i i c | 1
15.5
16.0
Rel. Int.
100%-
Fn 2
188.1410
Standard
4o3 10e3
12.00-16.50
AS-Anthracene
2.14e6
15,31
• 0% 	I1"""?	i		'I	I »>"¦[	I11'I I J I f-l'H i"f i ¦ i ' > r I1"
12.0
12.5
13.0
I 1 1
13.5
i i I i
14.0
-Hn-
14.5
["i "i"!""! i "i i
15,0
15.5
¦n*
16.0
7.72e5
D.OOeO
RT
Abs. Int.
r-1,40e6
•7.01e5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.00-16.50
0%-
12.0
12.5
13.0
I I |
13.5
14.0
i | t I I i |
14.5
' I ¦
15.0
[ *
15.5
'' I
16.0
Abs. tnt,
-5.32e7
-2.66e7
O.OOeO
RT
Results: P:\P940Q_P9499\P9464_6042 PAH\re$ourvesW9464_6Q42_PAH_003.utp_res, saved 01-Aug-2008 11:24 (CM)
AP U/iraTrace-Pro V3.992 User/System: CWCMP4-015 cc: 6352, 7723 see: 321-686
Peak annotation Areas, Centroids
Revised: 0l-Aug-2008 11:23:20 (CM) Printed: 01-Aug-2008 14:10:53 Page 5 of 9

-------
AP Lab ID: P9464_6042_PAHJ)03
Instr: AutoSpec-Premier MM6
Rel. Int.
pn 3 100%-
202.0783
Analyte
4o 3,33e4
17.50-22.50
0%-
Re!. Int.
Pn 3 100%-
208.0984
Standard
4o 7.69e3
17.50-22,50
0%-
Rel. Int.
Fn3 100%'
205.0883
Standard
4o 4.76e3
17.50-22.50
0%-
Rei. Int.
Fn 3 100%-
228.0939
Analyte
4o8.02e3
17.50-22.50 •
0%-
Rel, Int.
pn 3 100%-
234.1140
Standard
4cr 2.06e3
17.50-22.50
0%-
Fluoranthene
1.2069
18.11
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 75
Pyrene
9.24e8
18.67
Acq: 30-Jul-2008 01:04:10
User: CEM Datafile: 080729V24
Abs. Int.
7.80e8
-3.90e8
18.0
ES-Fluoranthene
4.64e6
18.11
19.0
20.0
21,0
22.0
—
18.0
19.0
20.0
21.0
I—r—r
1—I—r-
22.0
ES-Pyrene
5,89e6
18.67
T^l"^ A
18.0
r V	P1	
19.0
JL
20.0
18.0
19.0
21.0
2.5467
21.06
A
22,0
1.6168
21.70
Benzfajwitfir
20.0
21.0
22.0
ES-Benz(a)Anthrace
3.43e6
21.60
18.0
19.0
	i	i	y	'i""
20.0
—r
21.0
22.0
O.OOeO
RT
Abs, Int.
-2.91 e6
-1,46e6
-O.OOeO
RT
Abs. Int.
-3.63e6
-1.82e6
-O.OOeO
RT
Abs. Int.
-8.15e7
-4.07e7
-O.OOeO
RT
Abs. Int.
-1.80e6
9.02e5
•O.OOeO
RT
Rel. Int.
Fn 3 100%-
218.9856
QC Check
17.50-22,50"
0%-
18.0
19.0
20.0
21.0
22.0
Abs. Int.
-2,88e7
-1.44e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\rsSources\P9464_6042_PAH_003utp_fBS. saved 01-Aug-2008 11:24 (CM)
AP UttraTrace-Pro V3 992 User/System: CM/CUP4-015 cc: 7399, 9165, 0545, 3248. 8383 see: 321-686
Peak annotation: Areas, Centnoids
Revised: 01-Aug-20Q8 11:22:24 (CM) Printed¦ 01-Aug-2008 14:11:05 Page 6 of 9
-------
AP Lab ID: P9464_6042_PAH_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 3
212.1410 •
Standard
4o 3.56e3
18.00-20.00 •
Sample ID: Run# I-ACD-M23-2
VS1R expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 75
JS-Pvrene
3.66ee
18.62
Acq: 30-Jul-2008 01:04:10
User: CEM Dataflle: 080729V24
Abs Int.
•2.16e6
1.09e€
O.OOeO
18.6
18.8
Rel, Int.
100%-
Fn 3
244.1974
Standard
4a 1,72e3
18,00-20.00
19.0
SS-Ten
19.02
fv
I i i i i |" i i iT'fiTi i | i i i i i'T'i 11)111 r-pi"! i i" ] i i i i
19.2	19.4	19.6	19.8	RT
0% 1 i i i i f i i i i | i i i ¦" i | i i i i | i
18.2
18.4
f i i i i | i i i"l ) r i > > | i
18,6	18.8
^miT,T'r"l",l CT=T8
19.0
19.2	19,4	19.6	19.8
Abs. Int.
-1,4486
-7.20e5
-O.OOeO
RT
Rel. Int.
100%-
Abs. Int.
-2.79e7
Fn 3
218,9856
QC Check
18.00-20.00"
-1.39e7
0% I I t I | "I lll|llll|ffll»| T—
18,2	18.4
1 I ' 1 ' ' I
18.6
18,8
19.0
Results; P:\P9400_P9499W9464_6042 PAHVcsources\P9464_6042_PAH_003. utp_res. saved 01-Aug-2008 11:24 (CM)
AP UltraTrace-Pm V3.992 User/System CM/CMP4~01S cc; 9436. 9436 see: 321~686
I I | I 1 I I j
19.2	19.4
i j i i i i ) i i t i [ i	»""» i"j ! ¦'> i | t i i i 0.OOeO
19.6	19.8	RT
Peak annotation; Areas, Centroids
Revised: OUAug-2008 1 1:23:40 (CM) Printed: OUAug-2008 14:11:16 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH _003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4o 8.69e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
258.1140
Standard
4o 1.69e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o 2.66e3
23.50-28.00
0%-
Rel. Int.
10D%-
Fn 4
264.1692
Standard
4a 2.40e3
23.50-28.00
0%-
24.0
24.0
24.0
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 75
Benz(b)Fluoranthene
y /
Ben Fluoranthene
f».33e?
25.01
¦			
24.5
25.5
enz e Kvrene
6.21e
25.93
Acq: 30-Jul-2008 01:04:10
User: CEM Datafile: 080729V24
Abs. Int.
-3.10e7
260
26.5
27.0
27.5
ES-BenztWFIuorant
7.66e6
24.69
24.5
25.0
I ' ¦ * i | >
25.5
—r—|—r-i—i"! |—i i	1 i—|—i—r-
26.0
ES-Benz(e)Pyrene
8.05e6
2STO--Bera(a) Pyrene
7.67e8
28.15
26,5
1 I | I
27.0
24.5
I 'T '
25.0
25.5
26.0
26.5
ES-Perylene
5.98eB
26,37
27.0
27.5
JS-Benz(a)Pyrene
3.03e6
26.05
24.0
¦A-
24.5
I | 1 I I I ]
250
25.5
26.0
1' I fl I I
26.5
if [ i t T i ; i
27.0
t i i | r
27.5
¦1.55e7
-j-i-J-OOOeO
RT
Abs. Int.
2.88e6
1.44e6
i i | i i i i | ! i i i O.OOeO
27.5	RT
Abs. Int.
r 2.65e6
1,33e6
-O.OOeO
RT
Abs. Int.
-1.79e6
8.96e5
O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28,00
0%-
24.0
24.5
25.0
25.5
26.0
I j I T » I | *
26.5
[ I I t I | I 1
27.0
27.5
Abs. Int.
-2.20e7
¦1.10e7
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHVesources'P9464_6042_PAH_003 utp_res. saved 01-Aug-2008 11:24 (CM}
AP UltraTrace-Pm V3 992 User/System: CM/CMP4-015 cc: 3822. 9942. 0276, 7804 see: 321-686
Peak annotation: Areas, Centroids
Revised: 01-Aug-2008 11:23:52 (CM) Printed: 01-Aug-2008 14:11:27 Page 8 of 9
-------
AP Lab ID: P9464_6042_PAH_003
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn 4 100%-
276.0939
Analyte
4o 8 28e3
29.0-36 0
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial; 75
0%-
lnd(123-cd)Pyrerie
2.5te7
31,66
Benz(|hi)Pefyi«
33.26
29.0
Rel. Int.
Fn 4 100%-
282.1140
Standard
4o 3.43e3
29.0-36 0
0%-
29.0
Rel. Int.
Fn4 100%-
288.1342
Standard
4o1.75e3
29.0-36.0
0%-
29.0
Rel. Int.
Fn 4 100%-
278.1096
Analyte
4o 5.47e3
29.0-36.0
29.0
Rel. Int.
Fn 4 100%-
284.1297
Standard
4a 1.96e3
29.0-36.0
0%-
30.0
31.0
Acq; 30-Jul-2008 01:04:10
User: CEM Datafile: 080729V24
Abs. Int.
-5.10e6
32.0
I I J I * I I I p
33.0
i—r-
34.0
- 2.55e6
O.OOeO
» j I 1 f f | I I T »
35.0	36.0 RT
ES-lnd(123-cd)Pyre
4.3" "
31.62
r	I 1 I I | I I | | I' | r1 1 I—jr
30.0	31.0	32.0
33.0
-|—i i	r '» I1 ¦ i	i	t	»
34,0
35.0
ES-Benz(ghi)Pery1
5.29e"
I I I 1
30.0
| t -
31.0
-T-t-
33.25
34.0
DibenzfaMAnth se
3.85e(
30.0
31.0
32.0
ES-Dibenz(ah)Anthf
4.89e6
31.84
33.0
34.0
35,0
29.0
¦T-T-l"!
30,0
31.0
32.0
I'f 1 1'1 1| I iTT| I 1 1 V |
33.0	34.0
1 1 1 I '
35.0
Abs. Int.
-8.27e5
-4.14e5
-O.OOeO
36.0 RT
Abs, Int.
-8 47e5
-4.23e5
-O.OOeO
36.0RT
31.78
Abs. int.
-5.06e5
2.53e5
O.OOeO
360RT
Abs. tnt,
-6.83e5
•3.41e5
¦O.OOeO
36.0 RT
Rel. Int.
Fn 4 100%
292.9824
QC Check
29.0-36.0
0%
| I t I I | t
34.0
Abs. Int.
-2 18e7
1.09e7
O.OOeO
29.0
Results: P:\P9400_P9499SP9464_6042 PAH\re$oun;es\P9464_6042_PAH_003,utp_res. saved 01-Aug-2008 11:24 (CM)
AP UltraTrace-Prx} V3.992 Useikystem: CM/CMP4-01S cc: 0939, 2720, 5605. 0463, 6691 sec: 321-686	Revised: 01-Aug-200B 11:21:52 (CM)
36,0 RT
Peak annotation: Areas, Centroids
Printed: 0}-Aug-2008 14:11:39 Page 9 of 9
-------
Datafile: e:080730V15 ^
Acquired; 30 Jul 2008 18:36:57 x
Client ID: Run# I-ACD-M23-2
Lab ID: P9464 6042 PAH 003-SPL300

Wt/Vol: 1 Train
J Level: 4 n
g/Traity

ICAL: MM6 PAH 080118 18JAN08
Nominal ES spike: 40 ng
Stats
Largest +ve RT shift (sees!
Largest -ve RT shift (sees)
PAH Ax
1.8
-0.3
ES/SS
3.8
-1.7
Checkcode:
0X

Actual


Fred
Actual
Diff



Cone
BMW 1 ng/Trsia-


Kama
RT

QC

RUT
RRT
Sees
Response
Ra
Noise
Dh
Naphthalene
8.
56

1
0005
1.0003
-0.1
2
15E+08
-
1
09
138,000-#" ,
25,100^'^'
1.91E+04
36.40000
-Methyl naphtha 1 ene
9.
75
/

1
0003
1.0001
i
O
3
OOE+07
-
1
11
6.84E+03
21.00000
Acenaph thylene
11
55
S

1
0003
1.0003
0
1
54E+07
_
0
86
14,200""!'?' i
^9.48E+03
32.40000
Aeenaphthene
11
91


1
0003
1.0003
0
1
58E+06
-
1
00
1,520 i*FT
7.24E+03
28.30000
Fluorene
13
03
/

1
0004
1.0007
+0.2
3
40E+06
-
1
05
3,350
6,18E+03
24.90000
Phenanthrene
15
25
/

1
0003
1.0002
-0.1
4
45E+07
-
1
12
28, 600 4*.
5.36E+03
16.10000
Anthracene
15
38
/

1
0003
1.0004
+0.1
3
03E+06
-
1
09
2,560
5.362+03
16.70000
Fluoranthene
18
13


1
0001
1.0003
+0.2
1
50E+07
-
1
02
10,400
5.89E+03
16.00000
Pyrene
18
68

1
0001
1.0002
+0.1
1
15E+07
-
1
03
6,530
5.89E+03
14.10000
Ben zo(a}Anthracene
21
62


1
0001
0.9999
-0.3
6
88E+05
-
1
00
941
2.44E+03
17.60000
Chrysene
21
73
/

0
9998
1.0005
+0.9
1
69E+06
-
1
11
1,610
2.44E+03
11.30000
Benzo(b)Fluoranthene
24
90
fC/
1
0002
1-0000
-0.3
5
65E+05
-
0
99
852
3.11E+03
39.00000
Benzo(k)Fluoranthene
25
04
>

1
0003
1.0008
+0.8
3
68E+05
-
0
90
379
3.11E+03
19.50000
Benzo(e)Pyrene
25
95


1
0000
1.0002
+0.3
6
27E+05
~
0
93
€86
3.11E+03
27.90000
Benzo(a)Pyrene
26
16
/

0
9997
1.0001
+0.6
1
32E+05
-
0
86
216
3.11E+03
40.50000
Perylene


/

1
0044
-


-
-
0
90
ND
3.11E+03
39.30000
Indeno(1,2,3-cd)Pyrene
31
68


1
0002
0.0000

2
22E+05
-
0
93
#VALUE!
2.05E+03
~VALUE!
Dibenzo(a, h)Anthracene


y

0
9989
-


-
-
0
89
ND
1.48E+03
#VALDE!
Benzo(ghi)Perylene
33
30
/

1
0004
1.0013
+1.8
3
61E+05
-
0
95
628
2.05E+03
49.50000
-------
Dataflle: e: 080730V1S
Client ID: Run# I-ACD-M23-2
Lab ID: P9464_6042_PAH_003-SPL300
Wt/Vol: 1 Train
Stats
Largest +ve RT shift (sees I
Largest -ve RT shift (sees)
Name
13C6-Naphthalene
13C6 - 2 -Methylnaphthalene
13C6-Acenaphthylcnc
13C6-Acenaphthene
13C6-Fluorene
i 3C6 - Phenar. threne
13C6-Anthracene
13C6-Fluoranthene
13C3-Fyreae
13C6~Benza fa)Anthracene
13C6~Chrysene
13C6-Benzofb|Fluoranthene
13C6-Benza(k!Fluoranthene
13C4-BenzoleiPyrene
13C4-Benzo fa)Pyrene
-------
AP Lab ID: P9464_6042_PAH_003-SPL300
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 75
Acq: 30-Jul-2008 18:36:57
User: CEM Datafile: 080730V15
Rel. Int.
100%-
Fn 1
130,9920
QC Check
7.02-10 55
—
0%-
' I 1
7.5
	t	J	T	T	1	*	|	*	T	1""
8.0
r~~r-'
8.5
9,0
Abs, Int.
6.72e7
•3.36e7
9.5
10.0
* i—|—i-O.OOeO
10.5 RT
Rel, Int.
100%-
Abs. Int.
-8 08e7
Fn 2
168.9888
QC Check
10.59-17.00
-4.04e7
0% i—i—i—j—
11.0
| I I I I j I I I I | I t
120
13.0
14.0
-O.OOeO
15.0
16.0
17.0 RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.00'
0%-
'—I—'
18.0
19.0
20.0
21.0
22.0
Abs. Int.
• 4 22e7
2.11e7
• O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01
0%-
24.0
26.0
28.0
30.0
32.0
34.0
Abs. Int.
-3.49e7
1.75e7
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\msoun;es\P9464_6042_PAH_003-SPl300.utp_ms. saved 31-Jul-2008 14:58 {CM)
AP UltraTmce-Pm V3 992 User/System CWCMP4-015 see: 932-428
Peak annotation: Areas. Centroids
PKO: n/a Printed: 31-Jut-2008 16:42:10 Page 1 of 9
-------
AP Lab ID: P9464_6042_PAH_003-SPL3G0
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn i 100%-
128.0626
Analyte
4o 1 91e4
8.40-10.20
0%-
Sarnple ID: Run# I-ACD-M23-2
VSIR expt; pah_db5_0801 GC: pah_db5-SPLT300 Vial: 75
Rel. Int.
pn 1 100%
134.0827
Standard
4o 1 46e3
8.40-10.20 -
Rel. Int.
pn -| 100%-
142.0783
Analyte
40 6 84e3
8.40-10.20
0%-
Rel. Int.
pn1 100%-
148.0984
Standard
4o 1,00e3
8.40-10.20
0%-
Rel. Int.
Fn 1 100% ¦
152.1410
Standard
4o1.20e3
8.40-10.20
0%-
Naphthalene
Acq: 30-Jul-2008 18:36:57
User: CEM Datafile: 080730V15
Abs. Int.
-1.80e8
T 1 | I I I I | f I I I | T I
8.8
9.0
I | I V I V |
9.2
1 I
9.4
T""!—I * ¥ *—[• * I T I j—T
9.6	9.8
-9.01e7
O.OOeO
| I I I I J I 1 I 1 | I I I
10.0	10.2 RT
ES-Naphthalene
5.76e4
8.56
"i—r-T—f—|—r~
T-'-
8.6
T*"
8.6
8.6
2-Methytnaphthalene
3.00e7
9.75
8.8
9,0
1 i -
9.2
9.4
¦ i ¦
9.6
10.0
ES-2-M ethyl naphtha
4.30e4
9.75
8.8
9.0
¦ i •
9.2
¦ i "
9.4
¦ i ¦ • ¦ ¦ i
9.6
JS-Methylnaphthale
4.12e4
9 68
9.8
10.0
Abs. Int.
-7,12e4
3.56e4
OOeO
-rTr
8.8
9,0
9.2
9.4
I \ I I I 1 | I I \ < | I
9.6	9.8
I | I I I I | I1 I I I |
10,0
10.2 RT
Abs. Int.
-2.19e7
1.09e7
•O.OOeO
10.2 RT
Abs. Int.
-4.87e4
-2.43e4
-O.OOeO
10.2 RT
Abs. Int.
-5.36e4
-2 68e4
-O.OOeO
10.2 RT
Rel. Int.
Fn 1 100%-
130.9920
QC Check
8.40-10.20
Abs. Int.
-6.72e7
• 3.36e7
0%-
1 ( 1 * 1 1 r 1 ' ' 1 i '
8.6	8.8
J l i l I | * i—i—r	y	i—y"i	i	
9.0	9.2
	i	i	>	[	r	r""t	r	
9.4	9.6
9.8
10.0
-O.OOeO
10.2 RT
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9«64_6042_PAH 003-SPL300 utp_rGS. saved 31-Jul-2008 14:SB (CM)	Peak annotation: Areas, CentroidS
AP UttraTrace-Pro V3 992 User/System: CM/CMP4-015 cc: 9066, ~3120, B070. 8812. 4406 see: 932-428	Revised: 31-M-2008 14:58:07 (CM) Printed: 31-Jut-2008 18:42:20 Page 2 Of 9
-------
AP Lab ID: P9464_6042_PAH_003-SPL300
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 75
Rel. Int,
Fn2 100%-
152.0636
Analyte
4a 9.48e3
11.50-12,30
0%-
Acenaphthyle
1.54e7
11.55
Acq: 30-Jul-2008 18:36:57
User: GEM Datafile: 080730V15
Abs. Int.
-1.05e7
11.5
ES-Acenaphthylene
Rel. Int. s o®64
11.7
I | « I » I | I % I
11.8
11.9
12.0
1 I 1
12.1
12.2
Fn 2 100%
158.0827
Standard
4o1,05e3
11.50-12.30
0%'
r-"-
11.5
Rel. Int.
Fn 2 100%
154.0783
Analyte
4o 7,24e3
11.50-12.30 :
0%Jf
11.5
Re!. Int.
Fn 2 100%-
160.0984
Standard
4o1.07e3
11.50-12.30
0%-
115
Rel. Int.
Fn 2 100% ¦
164.1410
Standard
4o 1 04e3
11.50-12.30
0%-
r-r"
11.5
11.65
1 1 1 ' ' I ' »
11.6
T~T"
» | f I I « j
11.7
	[¦	i	i	r	r	|	t	r	T" r1 |—r
11.8	11.9
Acenaphthene
I.61	e5
II.54
11.6
11.7
i i I i i i i I i
11.8
ipmn
I.58e6
II.91
| I I I < | I
12.0
12.1	12.2
| I 		I	|	I	I	I !
11.9
ES-Acenaphthene
4.16e4
11.90
12.0
12.1
11 i"
12.2
T
11.6
11.7
11.8
11.9
1 I '
12.0
1 I '
12.1
fill
12.2
JS-Acenaphttiene
3,78e4
11.83
I |—I—I—!—r-
11.6
1 I •
11.7
11.
11.9
-i—i—i—i—j—i—i—i—i—
12.0
¦5.24e6
¦O.OOeO
12.3RT
Abs. Int.
5.16e4
2 58e4
O.OOeO
12.3 RT
Abs. Int.
-1.12e6
•5.60e5
•O.OOeO
12.3RT
Abs. Int.
-4.31 e4
•2,16e4
O.OOeO
12.3 RT
"I	T	I	|	J	1—f	r	|	T	f—1	I	|	T—T	1	1 J 1 ¦» T	1	r
12.1	12.2
Abs. Int.
-4.11e4
2.05e4
O.OOeO
12.3 RT
Rel Int.
Fn 2 100%
168.9888
QC Check
11.50-12.30
11-5	11.6	11.7	11.8	11.9	12.0
Results: P:\P9400_P9499\P94B4_6042 PAH\resources\P9464_6042_PAH_003-SPL300.utp_res. saved 31-M-2008 14:58 (CM)
I I 1 | I 1 I I [
12.2
Abs, Int.
84e7
3.92e7
OOeO
12.3 RT
AP UllraTrnce-Pro V3.992 User/System: CM/CMP4-015 cc: 1577, 6782. 0373, 1247, 36S4 see: 932-428
Peak annotation: Areas, Centrokis
Revised: 31-Jut-2008 14:50:17 {CMJ Printed: 31-Jui-2008 16:42:29 Page 3 of 9/
-------
AP Lab ID: P9464_6042_PAH_003-SPL300
Instr; AutoSpec-Premier MM6
Rel, Int.
100%
Fn 2
166.0783
Analyte
4o6.18e3
12.70-16.50
Rel. Int.
100%
Fn 2
172.0984
Standard
4o 1.16e3
12.70-16.50
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o 5.35e3
12.70-16.50
0%-
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Viat: 75
Acq: 30-Jul-2008 18:36:57
User: OEM Datafile: 080730V15
Abs. Int.
-2.09e6
F uorene
3.40e6
13.03
0% ) 'i 			 'i "i
ES-Fluorene
3.86e4
13.02
16.0
Ptienanltirene
4.45e7
15.25
y
/
""1	1	t	I'	»¦"
130
13.5
14.0
1 I ' 1
14.5
1 1 | *
15.0
Anthracene
1 3.03e6
1 15.38
\	A ¦ ,
15.5
'"I	J	T	1	i	>	|	
16.0
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o 1 21e3
12.70-16.50
0%-
ES-Phenanthrene
5.56e4
15.25
1.05e6
O.OOeO
RT
Abs. Int.
• 4.48e4
2.24e4
-i—i—i—?—¦- O.OOeO
RT
13.0	13.5	14.0
14.5
15.0
15.5
t T | I i T t |
16.0
Abs. Int.
-2.77e7
• 1,39e7
-O.OOeO
RT
Abs. Int.
-4.80e4
¦2.40e4
•O.OOeO
RT
Rel. Int.
100%
Fn 2
168.9688
QC Check
12.70-16,50
'f	T	|	T	t	T	J	]	t	T	!	1	|	t	»	I	T	
15.5	16.0
Abs. Int.
8,05e7
4.02e7
-O.OOeO
RT
Results: P \P9400_P9499\P9464_604Z PAHVe sources\P9464_6042_PAH 003-SPL300 utp_nes. saved 31-Jut-200B 14:58 (CM)	Peak annotation: Areas, Centmids
AP UltmTmce-PrcT V3 952 User/System: CM/CMP4-Q15 cc: 0832, 4423, 9087, 7010 see: 932-428	Revised: 31-Ju!-2008 14:52:53 (CM) Printed: 31-Jul-2008 16:42:38 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAHJ)03-SPL300
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
176-1410
Standard
4o 1,27e3
12,00-16.50
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 75
0%-
SS-Fluorene
3.4864
12,95
12.0
Rel. Int.
100%-
Ffi 2
188.1410
Standard
4o1.43e3
12.00-16.50
0%-
12.0
Acq: 30-Jul-2008 18:36:57
User: CEM Datafile: 080730V15
Abs. Int.
4,32e4
12.5
13.0
' I ' '
13.5
"¦ jim*	r	"
14.0
14.5
11(1
15.0
1 	i 1 • ' " r"",,n
15.5
AS-Anthracene
Z.16e4
15,33
•2.16e4
O.OOeO
	r„„,	,	f	|	,„„T	T	T
16.0	RT
' ' ' I 1
12.5
	'J	I	%	I	|	»	I""
13.0
1 I '
13.5
14.0
14.5
| I I % < | I I f I | I f
15.0
15.5
16.0
Abs. Int.
-3,34e4
1.67e4
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
168,9888
QC Check
12,00-16.50'
0%-
12.0
12.5
1 I 1 1 '
13,0
' I '
13.5
' I '
14,0
14.5
15.0
Results: P:\P94Q0_P9499\P9464_e042 PAHSmsaurces'P9464jS042_PAH_003-SPL300.titp_iB$, saved 31-Jut-2008 14:58 (CM)
AP UltmTmce-Pm V3.992 User/System: CM/CMP4-015 cc: 6458, 6428 see: 932-428
1 1 ' ' 1 1 I
15.5
—I—*—1—f—
16.0
Abs. Int.
-8,05e7
-4.02e7
¦O.OOeO
RT
Peak annotation: Areas, Centroids
Revised: 3UJul-2008 14 58:02 (CM) Printed: 31-Jut-2008 16 42:47 Page 5 of 9
-------
AP Lab ID: P9464_6042_PAH_003-SPL300
Instr: AutoSpec-Premier MM6
Rel, Int.
Fn 3 100%-
202.0783
Analyte
4o 5.89e3
17.50-22-50
0%-
Rel. Int.
Fn3 100%
208.0984
Standard
4o 4.07e3
17.50-22.50
Rel. Int.
Fn 3 100%
205.0883
Standard
4a2 15e3
17.50-22 50
Rel. Int.
pn 3 100%-
228.0939
Analyte
4a 2.44e3
17.50-22.50
0%-
Fluoranthene /
1.5067 /
18.13 /
,	Sample ID: Run# I-ACD-M23-2
f VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 75
Pyrene
1.15e7
18.68
Acq: 30-Jul-2008 18:36:57
User: CEM Datafile: 080730V15
Abs. Int.
-8.48eS
-t	t	!—™r
-r
18.0
—I—1
19.0
20.0
i 1 -~i	r~
( i	1	r
—I—
21.0
l l I	r-
•4.24e6
22.0
ES-Fluoranthene
5.67e4
18.12
18.0
Chiysene
/ 1.69e6
/ 21.73
BenzfaqArrthrAcene
Casesfl
21.62
19.0
	['	1	1""
20.0
JV_
21.0
r j	V" ' V	T"		1	
22.0
-O.OOeO
RT
Abs. Int.
-5.45e4
2.72e4
OOeO
6.8204
18.68
1.7464
17.87
tt—rf
Abs. Int.
-5.87e4
2.93e4
.OOeO
Abs. Int.
-6.78e5
¦ 3.39e5
¦O.OOeO
RT
Rel. Int.
Fn 3 100%
234.1140
Standard
4o 1,07e3
17.50-22.50
ES-Benz|a)Anttirace
Abs. Int.
-3.63e4
1.81e4
OOeO
Rel, Int.
Fn 3 100%
218.9856
QC Check
17.50-22 50
Results: P:\P9400_P949S\P94B4jB042 PAH\resaume$\P9464_6042_PAH_003-SPL300.utp_ms, saved 31-Jut-2008 14:58 (CM)
AP UllraTmce-Pm" V3.992 User/System: CM/CMP4-015 cc. 8729. 0223. 2533, 7428, 2959 see: 932-428
Abs. Int.
22e7
F-2.1187
O.OOeO
RT
Peak annotation: Areas, Centroids
Revised: 31-Jut-2008 14:54:37 (CM) Printed: 31-Jul-2008 16:42:57 Page 6 of 9
-------
AP Lab ID: P9464_6042 PAH. 003-SPL300
Instr: AutoSpec-Premier MM6
Re), Int.
100%-
Fn 3
212.1410
Standard
40 2.5Oe3
16.00-20.00 ¦
0%-
Rel. Int.
100%-
Fn3
244,1974
Standard
4o 1,33e3
18,00-20.00
0%-
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial; 75
JS-Pyrene
4.87e4
18.63
n
Acq: 30-Jul-2QQ8 18:36:57
User: CEM Datafile: 080730V15
Abs. Int.
-3.98e4
18.2
18.4	18.6
18.8
19,0
SS-Terphenyl
2.82e4
19.04
19.2
19,4
i i i ) i
19 6
i ( f i i i | i i
19.8
1,99e4
| 1 T T | | 1 | | t j | f | 1"| | | i | | | | | | J |
18.2	18.4	18,6
18.8
-O.OOeO
RT
Abs. Int.
-3.36e4
1,68e4
19,0
19,2
¦i fpr i i i | i i i i | i i i i ^ t i f i [ » > t i |
19,4	19.6	19,8
O.OOeO
RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
18.00-20,00
0%-
18.2
18,4
18.6
18.8
19,0
19.2
19.4
19.6
19.8
Abs. int.
-4.19e7
¦2.09e7
¦O.OOeO
RT
Results: P:\P9400_P949S\P9464_6042 PAH*esources\P9464_6042_PAH_003-SPL300utp_res. saved 31-JUI-2008 14:58 (CMS
AP Ultra Trace-Pro V3.992 User/System: CM/CMP4-015 cc: 1972, 6503 see: 932-428
Peak annotation: Areas, Centmids ,
Revised: 31-Jul-2008 14:58 11 (CM) Printed: 3t-Jut-2008 16:43:06 Page 7 of 9 /
-------
AP Lab ID: P9464_6042_PAH_003-SP1300
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4o3.11e3
23.50-28.00
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 75
0%-
Rel. Int.
100%
Fn 4
258.1140
Standard
4a 7.97e2
23.50-28.00
Re!. Int.
100%
Fn 4
256.1073
Standard
4a 1,34e3
23.50-2800
Benz(b)Fluoranthene
5.65e5
24.9Y
(Fluoranthene
3.68e5
04^
26.16
Acq: 30-Jul-2008 18(36:57
User: GEM Datafile: 080730V15
Abs. Int.
-2 50e5
Be^a^e	/
1 1 I 1
24.0
24.5
25.0
ES-BenzfK)Fluorant
8.63e4
25.02
25.5
-*—|—i—t r ¦ t | i i i i j i i t i |
26.5
26.0
27.0
27.5
24.0
ES-Benzfe)Pyrene
72p§$-Be5nzggPyrene
26.15
1.25e5
-j—i—i11 i"' O.OOeO
RT
Abs. Int.
- 5 10e4
ES-BenzOyFli|orant
5.3Be4
24.91
2.55e4
O.OOeO
RT
Abs. Int.
-4.00e4
- 2.00e4
0%-
Rel. Int.
100%-
Fn 4
264.1692
Standard
4o 1.25e3
23.50-28.00
0%-
240
24.0
24.5
24.5
25.0	25.5
T-T-T1'"!	1	1	f	I	|'	J	I	'I	I	|	'I	I	%	*	|	I	I	f	I	|[	»'	I	t1	>'	j	I"""|	I	¥'""1	t	1""
26.0	26.5	27.0	27.5
ES-Perytene
5.44e4
26.38
JS-Benz(a)Pyrene
2.65e4
26.06
25.0
25.5
' t 1
26.0
26.5
27.0
27.5
1 1 '
-O.OOeO
RT
Abs. Int.
-3.29e4
¦ 1.64e4
O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28.00'
0%-
24.0
24.5
250
,Mi	i	i	i	jMMT	r	r»»T""j""T""r"
25.5
mT""J	1	?	—j—
26.0	26.5
Abs. Int.
3.48e7
-1.74e7
O.OOeO
RT
27.0	27.5
Results: P:\P94O0_P9499\P9464_6O42 PAH\msaurces\P9464_W42_PAH_003-SPL300,utp_res, saved 31-JUI-2008 14:58 (CM)	Peak annotation: Areas, Cenlmids
AP UltraTrace-Prt) V3.992 User/System: CM/CMP4-01S cc 4377. 3915. 9752. 0227 scc~932-42B	Revised: 31-M-2008 14:58:24 (CM) Printed: 31-Jul-200B 16:43:15 Page 8 of 9
-------
AP Lab ID: P9464_6042_PAH_003-SPL300
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn 4 100%-
276,0939
Analyte j
4a 2.05e3 •
29.0-36.0
Sample ID: Run# I-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT300 Vial: 75
Benz(ghi)f
lnd(l23-cd)Pyrene
2.22e5
31.68
Acq: 30-Jul-2008 18:36:57
User: CEM Datafile: 080730V15
Abs. Int.
-7.26e4
33.30
3 63e4
OOeO
31.0
32.0
33.0
34.0
35.0
36.0 RT
Rel. Int.
Fn 4 100%-
282.1140
Standard
4o 1 59e3
29.0-36.0
0%-
29.0
Rel. Int.
Fn4 100%-
288.1342
Standard
4a 6.87e2
29.0-36.0
0%-
29.0
I ' • • ' I '
30,0
30.0
( ' '
31.0
"'T	f	T	T	If
I I I \ 1 t 1 t
—i—i—i ¦ t	r	i	i	*	i	*	i	i	t	r	i	i	i	i	|	f	»	r	rM
31.0
32.0
Abs. Int.
-2,46e4
¦ 1,23e4
¦O.OOeO
33.0
ES--Benz(ghi)Peryl
4.85e
-------
Datafile: e: 080729V25
Acquired: 30 Jul 2008 01:43:37
Client ID: Run# I-ACD-M23-3
Lab ID: P9464 6042 PAH 004
Stats
Largest +ve RT shift (seesI
Largest -ve RT shift (sees!
Name
£ Naphthalene
jf 2-Methylnaphthalene
ft ftcenaph thy 1 «ne
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
4. Pyrene
Benzo(aI Anthracene
Chrysene
Benzo(bi Fluoranthene
Benzo(k!Fluoranthene
Benzo(elPyrene
Benzo(a)Pyrene
Perylene
Indeno(1,2,3-cd)Pyrene
Bibertzo {a, h) Anthracene
Benzo(ghi)Perylene
.	(i fl'S* *V
*	M $P MOO
Actual
RT
8.60 /
9.75 /
11.54 /
11.89 /
13.01 S
15.25 /
15.3? /
18.13/*
18.69 /
21.61 ^
21.71 /
24.92 HI
25.01 ^
25,94 '
26.15
PAH Ax
0,9
-2.1
ec

31.66
31.78
33.27

/
ES/SS
4.4
-0.9
Pred
rrt
1.0004
1.0003
0003
0003
0003
0002
0002
0002
0001
0001
0001
0001
0001
0001
0001
0042
.0002
.0002
.0004
Analytical Perspectives
WWVol: 1 Train /
J Level: 4 ng/Train^,.
ICAL: MM6_PAH_080118_18JAN08
Nominal ES spike: 40 ng-^






Checkcode


Actual
Vitt


"T

/Ttonc


RRT
Sees
Response
Ra
RRF
/nff/Train
Noise
DL
0.9982
-1.1
4.79B+Q9
-
1
09
41.100^
23,100 /
4.28E+04
2 .81000
1.0002
-0.1
1.86E+09
-
1
11
1.46E+04
0,64100
1.0003
0
2.31E+09
-

86
22,300/
2.37E+05
9.35000
1.0003
0
9.15E+07
-
1
00
1,130 /
3.58E+04
1.52000
1.0003
0
1.27E+09
-
1
05
15,700
4.72E+04
2.10000
0.9999
-0.3
3.99E+09
-

12
33,300
1.33E+04
0.65900
1.0003
+0.1
7.21E+08
-
1
09
5, 680
1.33E+04
0.38900
1.0001
-0.1
3.46E+09
-
1
02
23,600
7.25E+04
2.53000
1.0001
0
3.25E+09
-
1
03
10,800
7.25E+04
1.13000
1.0001
0
4.99E+08
-
1
00
3, 930
1.59E+04
0.56700
1.0002
+ 0.1
1.24E+09
-
1
11
9,420
1.59E+04
0.59200
1.0007
+ 0.9
1.363-09
-
0
99
8,750
1.72E+04
0.73800
1.0002
+0.2
5.13E+08
-
0
90
3,260
1.72E+04
0.84300
1.0001
0
6.37E+08
-
0
93
4,280
1.72E+04
0.82600
1.0000
-0.2
4.56E+07
-
0
86
384
1.72E+D4
1.28000
-

-
-
0
90
ND
1.72E+04
1.46000
1.0007
+ 0.9
2.76E+08
-
0
93
3,150
9.51E+03
1.41000
0.9991
-2.1
3.05E+07
-
0
89
369
8.07E+03
1.63000
1.0008
+ 0.8
2.4OE+08
-
0
95
2,400
9.51E+03
1.40000

Page 1 of 2
Printed: 8/5/2008 2:28 PM
-------
Datafite: e: 080729V25
Client ID: Run# I-ACD-M23-3
Lab ID: P9464 6042 PAH 004
Stats
Largest • ve RT shift {sees)
Largest -ve RT shift (sees)
PAH Ax
0.9
-2.1
ES/SS
4.4
-0.9
Name
Actual
RT
Fred
RRT
13C6-Naphthalene
13C6-2-Methylnaphthalene
13C6-Acenaphthylene
13 C6-Acenaphthene
13C6-Fluorene
13 C6-Phenanthrene
13C6-Anthracene
13C6-F luoranther.e
13C3-Pyrene
13C6-Benza(a)Anthracene
13C6-Chrysene
13C6-3enzo(bi Fluoranthene
13C6-Benzo{k)Fluoranthene
13C4-Benzo(e)Pyrene
13C4-Benzo(a)Pyrene
dl2-Perylene
13C6-In
-------
AP Lab ID: P9464_6042_PAH_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 76
Acq: 30-Jul-2008 01:43:37
User: CEM Datafile: 080729V25
Rel. Int.
100%
Fn 1
130.9920
OC Check
7.02-10.55
Abs. tnt.
-4.24e7
2.12e7
O.OOeO
10.5 RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
Abs. Int.
- 5.20e?
2.60e7
O.OOeO
17.0RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.01'
0%-
1)1)11
18.0
""I	>'	'I	|	1	1"
19.0
| 7— I I I | I ! 1 I |
20.0
21.0
22.0
	1	F	1	j1
Abs. Int.
-2.75e7
-1.37e7
-O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01
0%-
24.0
26,0
28.0
30.0
32.0
Results: P
-------
AP Lab ID: P9464_6042_PAHJ)04
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah ,db5_0801 GC: pah_db5-SPLT5 Vial: 76
Rel. Int.
pn t 100%-
128-0626
Analyte
4a 4.28e4
8-40-10.20
0%-
Naphthalene
4.7969
8.60
Acq: 30-Jul-2008 01:43:37
User: CEM Datafile: 080729V25
Abs-lnt.""N
¦5.37e8
Rel. Int.
jrn •( 100%-
134.0827
Standard
4o 1 98e3
8.40-10.20
0%-
I ' ' ' 1
8.6
ES-Nanhihalene
4.28e6
8.61
1 [ I I 1 I | I ? ( k |—i i i i j
8.8	9.0
9.2
9.4
" I ¦
96
9.8
10.0
t i i t r i
'"I	f	I	I"l f I I I t | I > I '"T '"I	I"
9.0	9.2
Rel. int.
pnI 100%-
142.0783
Analyte
4o 1.46e4
8.40-10.20
0%-
	r„„,	|	|	|	r....T	r„„T„,j„„T„„T,.11^1,1
94	9.6	9,
2-Methyl naphthalene
1.8669
9.75
10.0
• I '
8.6
T"-
8.8
9.0
"f1 i' 'f '*—j—r
9,2
Rel. Int.
Fn 1 100%
148.0984
Standard
4a 1,40e3
8,40-10.20 1
0%-
I ] 1 t I 1 J I 1 1 [ J I I I » | t'l 1 J | T I 1 f [ *( T I J f
9.4	9.6	9.8	10.0
ES-2-Methylnaphtha
2.91eS
9.75
1.80eS
9.94
-O.OOeO
RT
Abs. Int.
-1 41e6
7.06e5
O.OOeO
RT
Abs-tfil_
1 -07e9V
•5.33e8
i l l i I i—r-
9.0
9.2
Rel. Int.
Fn1 100%-
152.1410
Standard
4o 2.34e3
8.40-10,20
0%-
-j—r—%—i—i—f—(—»—i—t—j—*—r-r—I—J—t-i—r-1—|—i—i i i—|—i ) i—r—i—i—|—i » > i
9.4	9.6	9.8	10.0
J S-Methyl naphtha le
3.81e§
9.69
-O.OOeO
RT
Abs. Int,
-2.06e6
1.03e6
8.8
9.0
I t"mi	t	f	|	t	r	-r—t—t—j— r
9.2	9.4
9.6
9.8
I f 1 I t I | I I t 1
10.0
-O.OOeO
RT
Abs. Int.
-2.88e6
¦ 1.44e6
•O.OOeO
RT
Rel, Int.
Fn 1 100%-
130.9920
QC Check
8.40-10 20 '
0% i ¦ ,

i | a i i i | i
86
¦ i ¦
8.8
lll1"llTllllTmT""T""j,""1	T""'l	r
9.0
i j i 1 I I yf>i t [		»¦
9 2	9.4	9.6
9.8
' l '
10.0
Abs. Int.
-4.19e7
-2.09e7
i i i i i 0. OOeO
RT
Results: P:\P940Q_P9499\P9464_6O42 PAH\resounces\P94S4_6042_PAH_004.utp_res. saved Ot-Aug-2008 11:40 (CM)
AP UltraTrace-Pm V3.992 UserfSyStem: CM/CMP4-015 CC~8912~5218~3258. 9020, 7620 see: 671-163
Peak annotation: Areas. CentroUs s
Revised; OI-Aug-2008 11:39:22 (CM) Printed: 01-Aug-200B 14:12:02 Page 2 of 9 ^
-------
AP Lab ID: P9464_.6042_PAH_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Via!: 76
Rel. Int.
Fn2 100%
152.0636
Analyte
4o2 37e5
11.50-12.30
Acenaphthylene
2.31 e9
11.54
Acq: 30-Jul-2008 01:43:37
User: CEM Datafile: 080729V25
AfcTIbt.?
r j1 j i1 t "f	^	t	r	t	r	j	r	t	v r
11.9	, 12.0
Acenaphthene	/
LiSe?	/
I | t 1 I t
12.1
1 I I I | I > I
12.2
O.OOeO
12.3 RT
11.6
I ¦ 1 11 I 1
11.7
11.88
Abs. Int.
~6.20e7
-3.10e7
11.8
11.9
ES-Acenaphthene
3.2Se6
11.89
12.0
12,1
12.2

O.OOeO
12.3RT
116
11.7
11.8
JS-Aceriaphthene
3.31e6
11.82
11.9
	i	I	i	r	t	i	j	¦>¦¦¦
12.0
' I 1 ' ' '
12.1
f r i [ > i t i | t
12,2
Abs. Int.
-2.38e6
¦1.19e6
11.6
	I	i * ¦ 1 I i '
11.7
-O.OOeO
12.3RT
Abs. Int.
2 31e6
¦1.16e6
11.8
11,9
—| » t r
12.0	12,1
O.OOaO
! r 7' ( i | i i i i | r i i i
12.2	12.3 RT
Rel. Int.
pn 2 100%
168.9886
QC Check
11.50-12,30
Abs. Int.
5.08e7
2.54e7
O.OOeO
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_B042_PAH_004.alp_ms. saved 01-Aug-2008 11:40 (CM)
AP UttmTrace-Pro V3.992 User/System. CM/CMP4-015 cc: 4256, 9315, 7159, 9679. 4829 see: 671-163
Revised Q1-Aug-20Q8 11:39:26 (CM)
12.3 RT
Peak annotation: Areas. Centnsids
Printed: Of-Aug-2008 14:12:13 Page 3 of 9
-------
AP Lab ID: P9464_6042_PAH_004
instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah db5-SPLT5 Vial: 76
Rel. Int.
100%-
Fn 2
166.0783
Analyte
4o4.72e4
12.70-16.50
0%-
Fluorene
I.27e9
13.01
Acq: 3Q-Jul-2008 01:43:37
User: CEM Datafile: 080729V25
Abs. Int.
-8,04eS
Rel. Int.
100%
Fn 2
172.0984
Standard
4o3 56e3
12.70-16.50
0%-
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o 1,33e4
12.70-1650
0%-
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o 1,99e3
12.70-16.50
Wo-
13.0
ES-Fluorene
3,07e6
13.01
13.5
' I '
14.0
14.5
I < ' 1 ¦ I 1 1 ' I I I ' I 1 I '
15.0	15.5
I | I I I I f I I I 1
16.0
JX
13.0
' I 1 | I
13.5
T1
14.0
¦ I '
14.5
15.0
r
Phenanthfene
3.99e9
15.25
15.5
% I » | I I
t [ t I f
16.0
n
¦ i -
13.0
13.5
' I •
14.0
' I 1 1 1
14.5
—f—I—I—*—|—r
15.0
™L
A nthracerie
7.21e8
15.37
15.5
ES-Anthracene
4.67e6
15.36
16.0
-I—I—r-
ES-Phenanthr
4,29e6
15.25
ine
' I '
13.0
I 1 > 1 1 I '
13.5
» i » i i r > r
14.0
14.5
15.0
ilrr
15.5
16.0
•4.02e8
-O.OOeO
RT
Abs. Int.
r 2 15e6
1.08e6
•O.OOeO
RT
Abs. Int. -
-5.37e8
I t I I I 1 I 1 I I I 1
-O.OOeO
RT
Abs. Int.
-3.16e6
1 58e6
•O.OOeO
RT
Rel Int.
100%-
Fn 2
168.9888
QC Check
12.70-16.50"
Q%-
13.0
' I ' ' '
13.5
¦T	^	i	i	r	r	11,1
14.0
I | t 1 >
14.5
1 I ' ¦ 1
15.0
15.5
16.0
Results: P:\P9400_P9499\P9464_6042 PAH\msaurces\P9464_6042_PAH_004.utp_res. saved 01-Aug-2008 11:40 (CM)
AP UltraTrace-Pm V3M2 User/System: CM/CMP4-015 cc 4279. 4397, 1993, 1500 see: 671-163
Abs, Int.
- 5 20e7
¦2.60e7
O.OOeO
RT
Peak annotation: Areas, Centmids
Revised: 01-Aug-2008 11:34:48 (CM) Printed: 01-Auq-2003 14:12:24 Page 4 of 9
-------
AP Lab ID: P9464_ 6042_PAH_004
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
176,1410
Standard
4o 2.95e3
12.00-16.50
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 76
SS-Fluorsne
3,OOe6
12.94
Acq: 30-Jul-2008 01:43:37
User: OEM Datafile: 080729V25
Abs, Int.
- 1.99e6
2.61e5
15.27
ttA
Rel. Int.
100%-,
Fn 2
188.1410
Standard
4a 2.98e3
12.00-16.50 •
I | ! I I ! | I I I I | I
15.5	16.0
9.97e5
AS-Anthracene
2.66e6
15.32
	|	i	»	>	i i i	i i | i i i i" | i i i i [ i
13.5	14,0	14.5

-i-fi-l O.OOeO
RT
Abs. Int.
-1 89e6
•9.43e5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.00-16,50"
Abs. Int.
-5.20e7
-2.60e7
0%-
12 0
12.5
13.0
I 1 1 •
13.5
14,0
i r | i i r
14,5
15.0
	f	y..|	f	f	
15.5	16.0
O.OOeO
RT
Results: P:\P940O_P9499\P9464_6O42 PAH\msounces\P9464_6042_PAH_004.utp_res, saved 01-Aug-2008 11:40 (CM)
AP UltraTmce-Prv V3.992 User/System: CM/CMP4-015 cc: 2822, 6312 see: 671-163
Peak annotation: Areas, Centroids
Revised: 0l-Aug-2008 11:39:05 (CM) Printed: 01-Aug-200a 14:12:36 Page 5 of 9
-------
AP Lab ID: P9464_6042_PAH_004
Instr: AutoSpee-Premier MM6
Rel. Int.
pn 3 100%-
202.0783
Analyte
4o 7.25e4
17,50-22.50
0%-
Rel. Int.
Fn 3 100%-
208.0984
Standard
4g 5.51e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-q
205.0883
Standard
4o 5.45e3
17.50-22,50
0%
Rel. Int.
Fn 3 100%-
228.0939
Analyte
40 1 59e4
17.50-22.50
0%-
Rel. Int.
Fn 3 100%^
234.1140
Standard
40 2.40e3
17.50-22.50 1
0%
Fluorantherii
3.46e9
18.13
n
/
Ssmplo IP; Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Viai:
76
Pyrene
3.2589
18.69
h
18,0
ES-Fluoranthene
5,76e6
18.12
19.0
4.25e5
18.6S
		
18.0
19.0
ES-Pyrene
1.17e7
18.68
7.19e6
18.13
18.0
19.0
1 I I
18.0
19.0
Acq: 30-Jul-2008 01:43:37
User: CEM Datafile: 080729V25
•5.37e8
III?
20.0
21.0
22.0
I
20.0
—I—i—i-
21.0
i | ini r
22.0
"T	I	P"
20.0
21.0
T

22.0
Chrysene
1,24e9
/ 21.71
BenztafAnlhri
4,S9e8fl
21.61
A
20.0
21.0
22.0
ES-BenzlajAnthrace
—1_
18.0
I 1 f I
19.0
"1	1	1	I""
7	, ,r	r.
i r i
20.0
21.0
22.0
-O.OOeO
RT
Abs. Int.
-2.83e6
- 1.42e6
-O.OOeO
RT
Abs. Int.
-6.22e6
3.11e6
-O.OOeO
RT
Abs. Int.
-6.37e8
-3.19e8
-O.OOeO
RT
Abs. Int.
-2.81e6
•1.41e6
¦O.OOeO
RT
Rel. Int.
Fn 3 100%-
218.9856
QC Check
17.50-22.50"
0%-
~V
18.0
~r
19.0
lilt
20.0
—1—I—
21.0
~1	( I
( t	1	1	j	!	i	r	r~
22.0
Abs. Int.
- 2.73e7
1.36e7
¦O.OOeO
RT
Results: P:SP9400_P9499V39464_6042 PAH\resoufze$\P9464_6042_PAH_004 utp_res. saved 01-Aug-200B 11:40 (CM)
AP Ultra Trace-Pro V3 992 User/System CM/CMP4-915 cc: 6624, 1403, 0518. 6491. 2736 see: 671-163
Revised:
Peak annotation: Areas. Centrokis
Ol-Aug-2008 11:35:44 (CM) Printed: 01-Aug-20QS 14 12 47 Page 6 of 9
-------
AP Lab ID: P9464_6042_PAH_004
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
212.1410
Standard
40 3.96e3
18.00-20.00
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 76
0%-
Rel. Int.
100%-
Fn 3
244.1974
Standard
4o1.72e3
18.00-20.00
kITiS1 i i t i i
16.63
Acq: 30-Jul-2008 01:43:37
User: GEM Dstafile: 080729V25
Abs. Int.
3.35e6
I 1 I | 1 I f 1 | I I , I | V I » 'f*[ > »	| I I I I | » 1 \ I j *T**1 I [ » I I I | I 1 I I 1 1 1 | 1 1 ' ' | ' » 1 1 | 1 1 T * \ ' ' f T J 1
18.2	18.4	18.6	18.8	19.0	19.2	19.4	19.6	19.8
SS-Terphenyl
3.18e6
19.03
1 68e6
¦O.OOeO
RT
Abs. Int.
-1.9Se6
-9.74e5
0% i i i i |'> | i i i i | i i i i | i i i i | i i i i ] i i iiirfpr'I11 i i | r"i"
18.2	18.4	18.6
18.8
19.0
•'i i i I i
19,2
19.4
1 ' ' ' "i""1"
19.6
i I i i i i | i i i i O.OOeO
19.8	RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
18.00-20.00"
Abs. Int.
-2.65e7
• I.32e7
0%-
18.2
18.4
18.6
~n~
18.8
19 0
Results: P:
-------
AP Lab ID: P9464_6042_PAH 004
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4o 1,72e4
23.50-28.00
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 76
0%-
BenzftriFluoranthene
l-3Be9
fluoranthene
5,13e8
S5.01
r i t i I i i l i
24.0
24.5
Benz(a0ggfie
25.94
/
/
Rel. Int.
100%-
Fn 4
258.1140
Standard
40 1.76e3
23.50-28,00
0%-
25.0
ES-Benzfb) Fluorant
1.26e7
24,90
1=»-
-1 f1 » i i i | » i ft i p i r
25.5	26.0
26.5
I 1 1 * ' I '
24.0
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o 3.27e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
264,1692
Standard
4o 2.54e3
23.50-28.00
24,5
» | i ii > |
25.0
25.5
26.0
ES-Benz[e)Pyrene
25.94
SS--Benzs'a)Pyrene
" 1.10e7
26.15
26.5
""1	1	|	I	'I	'I	I""
24.0
24.5
25,0
25.5
Acq: 30-Jul-2008 01:43:37
User: CEM Datafile: 080729V25
Abs. Int.
-3.52e8
27,0
27.0
27.5
27.5
26.0
JS-BenzfalPwene
4,S4e6
28,06
0%^ ¦¦¦¦,,
24.0
| » l l t | l i i » | f r r \ j i i i t f
24.5	25.0
25,5
¦1,76e8
-O.OOeO
RT
Abs. Int.
-4.74e6
¦2.37e6
|i	i | i	i—i—i—|—i—i—i—i—|—i—r—i—i—|—r—i—i—i—|~t—t—r—i—|—i—r-
26,5	27.0	27.5
ES-Perylerte
8.93b6
26.38
-O.OOeO
RT
Abs. Int.
-4.49e6
¦2.25e6
I I I ^ I I i1"!11 | i'
26.0
1 I I 1 | I I I I 1"ft V
26.5	27.0
27.5
-O.OOeO
RT
Abs. Int.
-2.62e6
1 31e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28.00"
0%-
1 1 I 1
24.0
' 1 I 1 '
24.5
25.0
Abs. Int.
r 2.07e7
1.03e7
O.OOeO
25.5
i | i r l ! | l I l I | i—*—i—!—|—r i i—r—I—i—r—i—i—I—i—i—»—i—j—t—i—j ? ¦[ »—t—r—r
26.0	26,5	27,0	27.5	RT
Results: P:\P9400_P9499\P9464_6042 PAHSmsoume$SP9464_W42_PAH_004.utp_m$, saved 01-Aug-2008 11:40 (CM)
AP UltraTrace-Pro V3 992 User/System: CWCMP4-01S cc: 9026, 9391, 1614, 2613 see: 671-163
Peak annotation: Areas, Centmids
Revised: 01-Aug-2008 11:39:40 (CM) Printed: 01-Aug-200B 14:13:10 Page B of 9
-------
AP Lab ID: P9464_6042_PAH_004
Instr: AutoSpec-Premier MM6
Ret. Int.
Fri 4 100%-
276.0939
Analyte
4o9.51e3
29.0-36.0
0%-
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 76
lnd(123-cd)Pyrene
2.76e8
31.66
29.0
i
30.0
Rel. Int.
pn4 100%'
282.1140
Standard
4cr3,BQe3
29.0-36.0
0%-
31.0	32.0
ES-Ind(123-cd)Pyre
7.55e6
31.63
Benzfghi
33.27
33.0
34.0
I I t 1
lift
	T	I	T	I	t	*	T Y	TI>'"T	t
29.0
Rel. Int.
Fn 4 100%-
288.1342
Standard
4o 1.88e3
29.0-36.0
0%-
29.0
Rel. Int.
pn 4 100%-
278.1096
Analyte
4o 8 07e3
29.0-36.0
0%-
29.0
Rel. Int.
pn 4 100%^
284.1297
Standard
4o 2.00e3
29,0-36.0
0%-
29.0
30.0
31.0
32.0
^"iii
33.0
ES--Benz(ghi)Peryl
8.43«
33.26
34.0
I I I 1 1 I I I I
30.0
j i i i i | t i i r | — i—T'-r "i—j t t
31.0	32/0
DibenzfahlAntfneee
3.051 "
Hf—\ t |' I I I i—f—r
33.0	34.0
j i	i j 'i i nr <
30.0
31.76
Acq: 30-Jul-2008 01:43:37
User: CEM Datafile: 080729V25
Abs. Int.
-4.82e7
35.0
35.0
35.0
t— * * i—i—i—i i	'I "T	l	I	I' I—i—i—i—i—i—i—r
i i 111 i I 1
31.0
32.0
ES-Dibenz(ah)Anthr
7.42e6
31.82
33.0
34.0
30.0
31.0
i t i i
33.0
1 I '
34.0
I 1 f t t "
I I T I I I I
35.0
¦2.41e7
•O.OOeO
36.0 RT
Abs. Int.
-1,47e6
•7.33e5
-O.OOeO
36.0 RT
Abs. Int.
1.44e6
• 7 20e5
-O.OOeO
36.0RT
Abs. Int.
3.74e6
1.87e6
1 j i i i 't	j	t	t	t	t—y	t	r	y
35,0
-O.OOeO
36.0 RT
Abs. Int.
1.12e6
•5.59e5
-O.OOeO
36.0 RT
Rel. Int.
Fn4 100%-
292.9824
QC Check
29.0-36.0
0%-
29.0
30.0
31.0
32.0
33.0
34.0
35.0
Abs. Int.
- 2.10e7
-1,05e7
-O.OOeO
36.0 RT
Results: P]P9400^P9499\P9464_6042 PAH\resources\P9464_6042_PAH_0Q4.utp_ms. saved 01-Aug-2008 11:40 (CM)
AP UUraTrace-Pro V3.992 User/System: CM/CMP4-01S cc:4883.~82B2, 1741,0733, 8178 see: 671-163
Peak annotation: Amos. Centmids /
Revised: Q1-Aug-2008 11:37:55 (CM) Printed: 01-Aug-2Q08 14:13:22 Page 9 of 9^
-------
Datafile: e: 080730V16
Acquired: 30 Jul 2008 19:16:29
Client ID: Run# I-ACD-M23-3
Lab ID: P9464 6042 PAH 004-SPL400 ^
Wt/Vol: 1 Train ^
J Level: 4 ngfTraip

6lg
ICAL: MM6_PAH_080118_18JAN08
Nominal ES spike: 40 ng-



Stats

PAH Ax ES/SS


Largest +ve RT shift
(sees)

2.8 3.8


Largest -ve RT shift
(sees)
Actual
-0.3 -2.5
Pred
Actual

Name

RT
QC BUT
RRT

Naphthalene

8.56 ^
1.0005
0.9999
*
2-Methylnaphthalene

9.75 X
1.0003
1.0003
¥r
Acenaphthylene

11.55 f
11.90 /
1.0003
1.0003

Acenaphthene

1.0003
1.0003

Fluorene

13.02 y
1.0004
1.0002
*
Phenanthrene

15.25 y
1.0003
1.0002

Anthracene

15.39 /
1.0003
1.0013
*
Fluoranthene

18.12S*
1.0001
1.0003
*
Pyrene

18.68 ^
1.0001
1.0002

Benzo (a) Anthracene

21.62 ^
1.0001
1.0002

Chrysene

21.73 /
0.9998
1.0005

Benzo(b)Fluoranthene

24.92 y
1.0002
1.0007

Benzo(k)Fluoranthene

25.04 f
1.0003
1.0011

Benzo(e)Pyrene

25.96 /
1.0000
1.0007

Benzo(a)Pyrene

26.16 /
. /
0.9997
1.0003

Perylene

1.0044
-

Indeno(1,2,3-cd)Pyrene

31.69 /
1.0002
1.0011

Dibenzo{a,h)Anthracene

31.79 f,
33.31 '
0.9989
0.0000

Benzo(ghi)Perylene

1.0004
1.0018
x k/m fAvK-°
0 ^
d 4-0


Checkcode:
Diff
Sees
-0.3
0
0
0
-o.z
-0.1
+ 0.9
+ 0.2
+ 0.1
+ 0.1
+ 0.9
+ 0.7
+ 1.2
+1.1
+0.9
+1.7
+2.8
Response
1.35E+09
3.79E+07
4.89E+07
1.10E+06
1.55E+07
2. 89E+08
9.97E+06
1.33E+08
1.01E+08
3.32E+06
1.14E+07
8.48E+06
5.72E+06
5.53E+06
3.20E+05
1.74E+06
1.84E+05
1.95E+06

Cone


RRF /
ng/Train
Noise
DL
1.0^
381,000 As
1.30E+04
12.70000
1.11
33,200 4*
5.57E+03
17.00000
0.86
37,300 f
8.38E+03
25.90000
1.00
1,080
4.89E+03
21.10000
1.05
14,100
4.345'03
15.00000
1.12
122,000 (k
4.64E+Q3
7.49000
1.09
9,710
4.64E+03
16.10000
1.02
66,800
7.72E+03
13.70000
1.03
25,800
7.72E+03
7.85000
O
O
3,390
1.74E+03
12.10000
l.n
9,480
1.74E+03
8.39000
0.99
10,500
3.22E+03
25.90000
0.90
5,740
3-22E+03
26.60000
0.93
4,980
3.22E+03
22. 00000
0.86
482
3.22E+03
35.60000
0.90
ND
3.22E+03
41.90000
0.93
14,400
1.73E+03
38.70000
0.89
ffVALUE!
1.43E+03
#VALUE!
0.95
3,050
1.73E+03
36.30000


Analytical Perspectives
Page 1 of 2
Printed: 8/5/2008 2:27 PM
-------
Datafile: e: 080730V16
Client ID: Run# I-ACD-M23-3
Lab ID: P9464_6042_PAH_004-SPL400
Wt/Vol: 1 Train
StaCs
Largest *ve RT shift (sees)
Largest -ve RT shift (sees)
Actual
Name	RT
13C6-Naphthalene	8.56
13C6-2~Methylnaphthalene	9.74
13C6-Acenaphthylene	11.54
13C6-Acenaphthene	11.90
13C6-Fluorene	13.02
13C6-Phenanthrene	15.25
13C6-Anthracene	15.37
13C6-Fluoranthene	18.12
13C3-Pyrene	18.68
13C6-Benzo(a)Anthracene	21.61
13C6~Chrysene	21.72
13C6-Benzo(b)Fluoranthene	24.90
13C6-Benzo(k)Fluoranthene	25.02
\ 3C4-Benzo(e) Pyrene	25.94
13C4-Benzola)Pyrene	26.15
dl2-Perylene	26.38
13C6-Indeno(l,2.3-cd)Pyrene	31.65
13C6-Dibenzo(ah)Anthracene	0.00
13C12-Benzo(ghi)Perylene	33.25
AS--Anthracene	15.32
SS-Fluorene	12.95
SS-Tcrphcnyl	19.03
JS-Methylnaphthalene	9.68
JS-Acenaphthene	11.83
JS Pyrene	18.63
JS-Benzo(a)Pyrene	26.06
PAH Ax ES/SS
2.8	3.8
Pred	Actual	Diff
RRT RRT	Sees
0.8855	0.8842	-0.8
1.0063	1.0064	+0.1
0.9757	0.9757	0
1.0059	1.0058	-0.1
1.1003	1.1004	+0.1
1.2892	1.2886	-0.4
1.2995	1.2989	-0.4
0.9725	0.9725	0
1.0025	1.0025	0
1.1602	1.1599	-0.3
1.1663	1.1657	-0.7
0.9557	0.9555	-0.3
0.9604	0.9598	-0.9
0.9958	0.9953	-0.8
1.0046	1.0033	-2.0
1.0127	1.0120	-1.1
1.2144	1.2144	0
1.2235	0.0000
1.2772	1.2756	-2.5
1.2897	1.2950	+3.8
0.9949	0.9947	-0.2
1.0507	1.0505	-0.2
Analytical Perspectives
Page 2 of 2
ICAL: MM6 PAH 080118 18JAN08
—	"	"" /
1.30E+05	-	1.51 ^	191.0 /
4.11E+04	-	0.96	95.3 S
6.11E+04	-	1.79	83.4^
4.06E+04	-	1.06	93.5
4 .172 + 04	-	1.11	91.7
8.45E+04	-	1.76	117.0 -**'
3.78E+04	-	1.64	56.4
7.83E+04	-	1.25	92.9 /
1.52E+05	-	1.30	173.0
3.91E+04	-	1.06	54.7
4.32E+04	-	1.02	62.9
6.52E+04	-	1.21	105.0
8.87E+04	-	1.60	108.0
9.54E+04	-	1.30	143.0
6.16E+04	-	1.39	86.1
5.25E+04	-	1.36	75.2
1.05E + 04	-	0.81	25.3
O.OOE+OO	-	1.00
5.41E+04	-	1.15	91.5
/
3.08E+04	-	1.44	52.3
4.05E+04	-	0.96 /	102.0
2.80E+04	-	0.54	66.8
4.51E+04	-
4.10E+04	-	-
6.76E+04	-
2.56E+04	-	-
Printed: 8/5/2008 2:27 PM
-------
AP Lab ID: P9464_6042_PAH_004-SPL400
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_08Q1 GC: pah_db5-SPLT400 Vial: 76
Acq: 30-Jul-2008 19:16:29
User: CEM Datafile: 080730V16
Rel, Int.
100%-
Fn 1
130.9920
QC Check
7.02-10,55
VT"
0%-
f—i—i—r-
1 I '
7.5
8.0
¦ I ¦
8.5
9.0
1 I '
9.5
10.0
Abs. Int.
-6.62e7
•3.31e7
¦ i l I O.OOeO
105 RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
13.0
15.0
Abs. Int.
-8.02e7
4.01 e7
O.OOeO
17.0 RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17 02-23.01
0%-
18.0
t	i	r
19.0
20,0
21.0
22,0
Abs, Int.
-4.23e7
•2,12e7
¦O.OOeO
23.0 RT
Rel. Int.
100%
Fn 4
292.9824
QC Check
23 02-35.01
r
30.0
Results: P:\P9400_P9499V9464_6043 PAH)resourossV>9464_6042_PAH_004SPL400.utp_res. saved 31-Jul-2008 15:09 (CM)
AP UltraTrace-Pro V3.992 User/System: CWCMP4-015 scc~404-199
Abs. Int.
-3.45e7
1.73e7
-O.OOeO
RT
Peak annotation: Areas. Centmids
PKD: n/a Printed: 01-Aug-2008 16:05:23 Page 1 of 9 -
-------
AP Lab ID: P9464_6042_PAH_004-SPL400
I nstr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Via!: 76
Rel. Int.
i 100%-
128.0626
Analyte
4o1.30e4
8.40-10.20
0%-
Naphthalene
1.35e9
8.56
Acq: 30-Jul-2008 19:16:29
User: CEM Datafile: 080730V16
Abs. Int.
1.05e9
5.27e8
I I | ) f I
8.8
f | I ! I I | I » I » J T-
9,0	9.2
9.4
9.6
• i ¦
9.8
10.0
Rel. Int.
pn •) 100%-
134.0827
Standard
4o 1.26e3
8.40-10.20
ES-Naphthalene
1,30e5
8,56
Rel. Int.
Fn 1 100%-
142,0783
Analyte
4o 5.56e3
8.40-10.20 1
0%-
Rel. Int.
Fn1 100%-
148.0984
Standard
4o 1,02e3
8.40-10.20
0%-
Rel. Int.
Fn1 100%-
152,1410
Standard
4o 9.71 e2
8.40-10,20
0%-
j	t	1	f	y"j""T""T""T""T""|"" T
8.6	8.8
| I I I I | I 1 > T J1
9.0
	r	F""T""1		*	f	|»"J»»V
9,2	9.4
9.6
2-Methylnaphthalene
3.?9e?
9.75
8.8
9.0
9.2
¦ i ¦
9.4
¦ i ¦
9.6
9.8
ES-2-Methylnaphtha
4.1 fe4
9.74
10.0
	i	r	
8.6
8.8
"1	['	I	I	'I	»	|	'1	1	1	1""| I ' t 1
9.0	9.2
1II|IIII|IV!I|1
9,4	9,6
9,8
10,0
JS-Methyjnaphihale
4,B1e4
9.68
•O.OOeO
10.2 RT
Abs. Int.
1.17eS
•5.84e4
O.OOeO
I | I I t I | / I I I | I I I » | I \ I t j 1 t I
10.0	10.2 RT
Abs. Int.
~2,92e7
¦ 1,46e7
I.OOeO
10.2 RT
Abs. Int.
-4,99e4
2,50e4
¦O.OOeO
10.2 RT
I | f
8,6
I i i i i | j i i i | f i i i | * i i i j
8.8	9,0
9.2
I | i I f
9.4
» I I I f I
9.6
T—r
9.8
Abs. Int.
-5,05e4
-2.53e4
O.OOeO
10.0	10.2 RT
Rel. Int.
Fni 100%-
130.9920
QC Check ¦
8.40-10.20 "
Abs. Int.
-6.62e7
-3.31e7
0%-
"rT-r
8.6
8.8
9.0
9.2
'I 1 ' 11 I
9.4
"T-mr
9.6
O.OOeO
¦T	T""V""|	1	1	%	f—t" V r"1	r""Y""T""T
9.8	10,0	10.2 RT
Results: P:\P9400_P9499\P9464_6042 PAHVe$ources\P9464_6O42_PAH_004-SPL400ijtp_res. saved 31-M-20Q8 15:09 (CM}	Peak annotation: Areas, Centroids
AP UltraTrace-Pro V3 992 User/System: GM/CMP4-015 cc: 6954, 6709, 5746, 2620, 9393 see: 404-199	Revised 31-Jul-2003 15:07:20 (CM) Printed: 01-Aug-2008 16 05:29 Page 2 Of 9"
-------
AP Lab ID: P9464_6042_PAH 004-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
Frt 2 100%"
152,0636
Analyte
4o 8.38e3
11.50-12.30
0%-
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5..0801 GC: pah_db5-SPLT400 Vial: 76
11.55
Acq: 30-Jul-2008 19:16:29
User; CEM Datafile: 080730V16
Abs. Int.
-3.18e7
n-
11.5
ES-Acenaphthylene
Rel. Int. 6 jfe4
Fn 2 100% 11'54
158 0827
Standard
4o 1 22e3
11.50-12.30
Rel. Int.
Fn2 100%
154.0783
Analyte
4o4.89e3
11.50-12.30
11.6
1 I 1
11.7
11.8
-j—i—i—i—t ¦¦[¦" i—i—i—i—j—
11.9
•1.69e7
O.OOeO
12.0
-]—i—i—i—i—|—i—i—i—i—*—i-T—i—|—i—I—t—i—| i i—t—r
12.1	12.2	12.3RT
Abs. Int.
-5,38e4
2.69e4
O.OOeO
i i i i [ ( ! i i j i i t i i r r
12.1	12.2	12.3RT
Acenaphthene
.foee
11.90
12.3RT
Rel. Int.
Fn 2 100%-
160.0984
Standard
4o 1.55e3
11.50-12.30
0%-
11.5
Rel. Int.
Fn 2 100%
164.1410
Standard
4a 1.29e3
11.50-12.30 ^
0%
I 1 1 1 1 I '
11,5
ES-Acenaptithene
4.06e4
11.90
1 I 1 ' 1 1 I '
11.6
11.7
• i ¦ ¦ • • i *
11.8
JS-Acenaphthene
4.10e4
1183
I | I I I I | I I 1 1 f 1 t
11.9	12.0
12.1
Abs, Int.
-7,49e5
3.74e5
O.OOeO
Abs. Int.
-3.97e4
-1 J8e4
O.OOeO
¦¦¦»	i		*	t	r	i	¦{	i	!¦	t	v
12.2	12.3RT
1 i	
11.6
11.7
4 | I
11.8
"T—j—I	I	T	I	1—I—|—|—J—j	1—|—(—1—j	1-
11.9	12.0
-]—ii i i ^ i i i i | i i i i | i j i * |
12.1	12.2
Abs, Int.
-4.24e4
•2 12e4
¦O.OOeO
12.3RT
Rel. Int.
Fn 2 100%-
168.9888 ;
QC Check ¦
11,50-12,30'
Abs. Int.
-7.78e7
-3 89e7
0%-
11.5
—i—i—i—i—|—i—i—i—i | i—i—i—i [ i
11.6	11.7
-T-T-
1 I ' ' I ' I I ' 1 ' I r-
11.8	11.9
—i—i—i—i—^—i—i—i—i—
12.0
' "I	""
12.1
I ' 1 ' « I ' '
12.2
¦ , , O.OOeO
12.3RT
Results: P:\P9400_P9499SP9464_6042 PAHVesourtes\P9464_6042_PAH_004-SPL400 utp_ms. saved 31-Jul-2008 15:09 (CM)	Peak annotation: Areas, Centmids
AP UHraTrace-Pro V3.992 User/System: CM/CMP4-015 cc: 2668, 6104, 0383, S624, 3586 see: 404-199	Revised: 31-JUI-2008 15:07:27 (CM) Printed: 01-Aug-2008 16:05:34 Page 3 of 9 •
-------
AP Lab ID: P9464_6042_PAH_004-SPL400
Instr: AutoSpec-Premier MM6
Rel, Int.
100%
Fn 2
166.0783
Analyte
4o4.34e3
12.70-16.50
Rel. Int.
100%-
Fn 2
172,0984
Standard
4a 1,25e3
12.70-16.50
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o4.64e3
12.70-16.50 •
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT4Q0 Vial: 76
0%-
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o9.36e2
12.70-16.50
0%-
13.0
1 I 1 1
13.0
Phenanthrene
2.89e8
15.25 /
J
i r i | i i r
13.5
I ' 1 1 ' I '
14.0
14,5
15.0
15.5
ES-Phenanthrene
8.45e4
15.25
£ B-Antfiracene
3.78e4
15.37
¦ I '
13.5
Acq: 30-Jul-2008 19:16:29
User: CEM Datafile: 080730V16
Abs. Int.
9,74e6
Fluorene
1.5567
13.02
4.17e4
' I '
16.0
4.87e6
O.OOeO
RT
Abs. Int.
-4,75e4
2.38e4
O.OOeO
RT
Abs. Int.
-1.89e8
9.44e7
-O.OOeO
RT
Abs. Int.
-7.23e4
3.62e4
14.0
14.5
15.0
15.5
16.0
•O.OOeO
RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
12.70-16.50 J
r
16.0
Abs. Int.
7.97e7
3.99e7
-O.OOeO
RT
Results: P:\P9400_P9499SP9464_B042 PAHVssaurces\P9l64_6042_PAH_004-SPL400.utp_resl saved 3l-Jul-2006 15:09 (CM)	Peak annotation: Areas, Centmids
AP UltmTmce-Pro V3.692 User/System: CM/CMP4-015 cc 1343. 8223. 9372. 7933 see: 404-199	Revised: 31-Jul-2008 15:01:15 (CM) Printed: Q1-Aug-2008 16:05:39 Page 4 of 9
-------
AP Lab ID; P9464_6Q42_PAH_004-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
176.1410
Standard
4a 1.12e3
12.00-16.50
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 76
0%-
12.0
Rel. Int.
100%-
Fn 2
188.1410
Standard
4c 1 40e3
12.00-16.50
0%-
Acq: 30-Jul-2008 19:16:29
User: CEM Datafile: 08Q730V16
Abs, Int.
-4.95e4
SS-Fluorene
4.05e4
12.95
12 5
13.0
13.5
14.0
14.5
15.0
15.5
T
16.0
•2.47e4
AS-Anthracene
3.0Be4
15.32
r—i—i t O.OOeO
RT
Abs, Int.
- 3.27e4
12.0
' I '
12.5
11 I '
13.0

13.5
i * | t i % i | i r
14.0
14.5
15.0
15.5
16.0
-1.63e4
O.OOeO
RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.00-16.50
0%-
12.0
-r-f-r-
12.5
13.0
I | I I I
13.5
t | \ I
14.0
14.5
' I '
15,0
' I 1
15.5
' I '
16.0
Abs. Int.
-7.97e7
- 3,99e7
•O.OOeO
RT
Results: P:\P9400 P9499\P9464 6042 PAH\resources\P9464 6042 PAH_004-SPL400Mtp_res, saved 31-Jul-2Q08 15:09 (CM)
AP UltraTmce-Pm V3.992 User/System: CMCMP4-015 cc: 1S22. 4055 see: 404-199
Peak annotation: Areas, Centrvids
Revised: 31-Jut-2008 15:07:10 (CM) Printed: 01-Aug-2008 16:05-44 Page 5 of 9 ^
-------
AP Lab ID: P9464_6Q42_PAH_004-SPL400
Instr; AutoSpec-Premier MM6
Sample ID: Run# 1-ACD-M23-3
Rel, Int.
Fn 3 100°/^
202.0783
Analyte
4o 7.72e3
17,50-22.50
0%-
Rel. Int.
Fn 3 100%
208.0984
Standard
4o4.26e3
17.50-22.50
0%'
Rel. Int.
pn 3 100%-
205.0883
Standard
4cr 2.11e3
17.50-22.50
0%-
Fluaranttiene
1,33e8
18.12
y VS1R expt: pah db5_0801 GC: pah_db5-SPLT400 Vial: 76
Acq: 30-Jul-S
User: CEM Datafile:
Pyrene
1.01eB
18.68
18.0
ES-Fluoranthene
7.83e4
18.12
19,0
20.0
ES-Pvrene
1.S2eS
18.68
21.0
i ; t
22.0
18.0
19,0
20.0
21,0
7=
>0S 19:16:29
080730V16
Abs. Int.
8.23e7
•4.11e7
-O.OOeO
RT
Abs. Int.
~7.17e4
3.58e4
O.OOeO
RT
Abs. Int.
r 1.11e5
¦5.53e4
220
¦O.OOeO
RT
Rel. Int.
Fn 3 100%-
228.0939
Analyte
4a1.74e3
17.50-22.50
0%-
—!—
18.0
19.0
20.0
¦A
21.0
—i—i—p
Benzfamnlfiiicerte
3,32
21 j
22.0
Abs. Int.
-4.41e6
-2.20e6
¦O.OOeO
RT
Rel. Int.
Fn 3 100%-
234,1140
Standard
4a 1,26e3
17,50-22.50
0%-
18.0
19.0
ES-Benz(a)Anthrace
3.91e4
21,81
20.0
21.0
22.0
Abs. Int.
- 3,43e4
¦1.7164
¦O.OOeO
RT
Rel. Int.
Fn 3 100%'
218.9856
QC Check
17,50-22.50'
18,0
19.0
20.0
21.0
22.0
Abs. Int.
-4.23e7
2.11e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_004-SPL400.utp_res, saved 31-Jul-2008 15:09 {CM}	Peak annotation: Areas, Centroids /
AP UltraTrace-Pro V3.992 User/System: CM/CMP4-015 cc: 4340, 4915, 5771, 8291, 3310 see: 404-199	Revised: 31-M-200B 15:06:23 (CM) Printed: 01-Aug-2008 16:05:49 Page 6 of 9 S
-------
AP Lab ID: P9464_6042_PAH_004-SPL400
Instr: AutoSpec-Premier MM6
Ret. Int.
100%
Fn 3
212.1410
Standard
4o 2,80e3
18.00-20.00
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 76
0%-
Acq: 30-Jul-2008 19:16:29
User: CEM Datafile: 080730V16
Abs. Int.
-5.34e4
JS-Pvrene
18.63
T I t > 1 f
18,2
r | t t t » | "i ¦r-T"TmymT"T"TmTm|mT"Tml	iT...T.lll
-------
AP Lab ID: P9464_6042_PAH_004-SPL400
Instr: AutoSpec-Premier MMS
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4o 3.22e3
23.50-28.00
0%-
Sample ID; Run# I-ACD-M23-3
VSIR expt: pah_.db5.0801 GC: pah_db5-SPLT400 Vial: 76
Benz(b)Fluoranthene
8.48 e6
24.:
Acq: 30-Jul-2008 19:16:29
User: CEM Datafle: 080730V16
Abs. Int.
-1,88e6
i i i i I i i i "i	|	r i i"
24.0
Benz(e)Pyrene
S.53et
F uoranthene
5.72e6
25.04
alPwene
3.2ue
26,16
Rel. Int.
100%-
Fn 4
258.1140
Standard
4o 9.10e2
23.50-28.00
I i i i i1 I i i i i 'I i i i i | i i i i | i
24.5	25.0	25.5
ES-BenzfblFluorartt
24.90
0%—'—i—r—i—i—|—i—i—i—i—]—r—*—i—i—p~r-
24.0
24.5
' I '
25.0
1 I '
25.5
-rr"
26.0
T-T-
26.5
27.0
,M|""T	r""T,,MT""|	T""l	1	1	J""
27.5
9.3Be5
O.OOeO
RT
Abs. Int.
-4.10e4
•2.05e4
Rel. Int.
100%
Fn 4
256.1073
Standard
4o1.13e3
23.50-28.00
Rel. Int.
100%-
Fn 4
264.1692
Standard
4o1.31e3
23.50-28.00
ES-Benz(e)Pyrene
8.54e4
2S®fl-Benz(a*Pvrene
25.0
0%-
ES-Perylene
JS"B62nil^y,ene SzsS3ee4
26.06
-O.OOeO
RT
Abs. Int.
-4.62e4
2 31e4
O.OOeO
RT
Abs. Int.
-3.15e4
1,58e4
¦¦¦¦r	f	[	i	r	<	¦!	if	r	i	i	i	|m"f	i"s "i i t i '» ¦
24.0	24.5
25.0
25.5
26.0
265
27.0
—t—|—i—!—i—i—p-1—i—i—i— O.OOeO
27,5	RT
Rel. Int.
100%
Fn 4
292.9824
QC Check
23.50-28.00 •
25.5
26.0
26.5
Abs. Int.
- 3.45e7
1,7367
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\resovrce$'iP9464_6Q42_PAH_004-SPL400.utp_res, saved 31~Jul~2008 15:09 (CM)	Peak annotation: Areas, Centroids
AP UltraTrace-Pro V3 992 User/System CWCMP4-0tS cc 7528. 5343. 5548. 4053 see. 404-199	Revised: 31-Jul-2008 15:07:55 (CM) Printed: 01-Aug-2008 16:06:00 Page 8 of 9
-------
AP Lab ID: P9464_6042_PAH_004-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn4 100%-
276,0939
Analyte
4o 1.73e3
29.0-36.0
0%-
29.0

30.0
Sample ID: Run# I-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 76
lnd(123-cd)Pyrene
31.69
Benz({jhj||^ifylene
33.31
31.0
32.0
33.0
34.0
Acq: 30-Jul-2008 19:16:29
User: CEM Datafile: 080730V16
Abs. Int.
-2.91e5
35.0
1,45e5
•OOOeO
36.0 RT
Re!. Int.
Pn4 100%-
282.1140
Standard
4o2.07e3
29.0-36.0
0%-
29.0
Rel. Int.
Fn4 100%-
28B.1342
Standard
4o 8.56e2
29.0-36.0
Rel. Int.
Fn 4 100%
278.1096
Analyte
4a 1 43e3
29.0-36.0
30.0
31.0
"¦¦r	r	r	i""
i i i i
32.0
33.0
ES"Benz(^J)Pefyl
34.0
35.0
""T	r	T	T,M
Abs. Int.
-2.57e4
•1.28e4
¦ O.OOeO
36.0 RT
33.25
Dibenz/ah
31.79
Abs. Int.
-2 42e4
1.21e4
OOeO
36.0 RT
Abs. Int.
4,34e4
2.17e4
OOeO
36.0 RT
Rel. Int.
Fn 4 100%
284.1297
Standard
4a 9.86e2
29.0-36.0 -i
0%-
till
29.0
| t 1

30.0
1 I '
31.0
1 1 1 I 1
32.0
33.0
1 I 1
34.0
35.0
Abs. Int.
-2.14e4
• 107e4
•O.OOeO
36.0RT
Rel. Int.
Fn 4 100%
292.9824
QC Check
29.0-36.0
Abs. Int.
~3.45e7
-1.72e7
O.OOeO
36.0 RT
Results: P:\P9400_P9499m464_6042 Pmrnsamxsm464_6042_PAH_004-SPL400.utp_res, saved 31-Jut-2008 15:09 (CM)	Peak annotation: Areas. Centmids
AP UltmTmce-Pro V3.992 UserTsystem: CWCMP4-015 cc: 1021. 8319. 5785. 0246. 936? see: 404-199	Revised 3IM-200B 15:07:00 (CM) Printed Oi-Aug-2008 16 06 05 Page 9 of 9^
-------
Datafile: e: 080729V26 ./ Client ID; Run# II-ACD-M23-1'
Acquired: 30 Jul 2008 02:23:08Lab ID: P9464_6Q42_PAH 005
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees I
^ Naphthalene
* 2-Methylnaphthalene
& Acenaphthyier.e
Accnaphther.e
Fluorerie
•A Phenantbrene
4r Anthracene
tk Fluoranthene
Jc Pyrene
Benzo i a)Anthracene
Chrysene
Benzo fb)Fluoranthene
BenzoIk)Fluoranthene
Benzole)Pyrene
Benzo Sa)Pyrene
Perylene
Indent)(1, 2, 3-cd) Pyrene
Dibenzo(a,h)Anthracene
Benzoighi)Perylene
* $gAvi
Actual
RT
8,61 S
9,76 '
11.56-""
11.90 f
13 .02/
15.26 /
15.38 /
18.14/*
18.69 ^
21.62 /
21.72 /
24 . S3
25.03
25.95 /*
26.17/
26.49
SI.67^
31.79
33.29 /
PAH Ax
1.1
-3.2
QC

ES/SS
4.3
-1.0
Pred
VMT
0004
0003
0003
0003
0003
0002
0002
0002
0001
0001
0001
0001
0001
0001
0001
0042
0002
0002
0004



Analytical Perspectives
Wt/Voi: 1 Train	^[W\
J Level: 4 ng/Traiir^ I f 11
ICAL: MM6_PAH_080118_18JAN08
Nominal ES spike: 40 ng^
Checkcode

Actual
Diff



M—Cone



RRT
Sees
Response
Ha
RJtF
/ng/Trslp

Noise
DL
0.9990
-0.7
4.99E+09
-
1
09
46.600 \
5
94E+05
38.60000
1.0002
-0.1
2.36E+09
-
1
11
32.200
1
25E+04
0.68600
1.0001
-0.1
3.32E+09
-
0
86
37,700
1
20E+06
65.30000
1.0003
0
4.59E+08
-
1
00
5,570
3
10E+05
13.10000
1.0004
+0.1
2.10E+09
-
1
05
29,100
4
Q4E+05
23.00000
0.9999
-0.3
4.15E+09
-
1
12
37,000
1
91E+04
1.04000
1.0002
0
1.82S >09
-
1
09
15,200
1
91E+04
0.61100
1.0001
-0.1
3.50E+09
-
1
02
26,200
4
26E+05
16.30000
1.0001
0
3. 45E+09
-
1
03
10,400
4
26E+05
6.58000
1.0001
0
1.24E+09
-
1
00
10,700
1
05E+05
4.09000
1.0001
0
1.63E+09
-
1
11
13,600
1
05E+05
4.34000
1.0008
+ 1.0
2.29E+09
-
0
99
15,200
2
70E+04
1.20000
1.0004
+ 0.5
7.96E+08
-
0
90
5,250
2
70E+O4
1.30000
1.0001
0
1.31E-09
-
0
93
9,070
2
70E+04
1.31000
1.0001
0
5.34E+08
-
0
86
4,050
2
70E+04
1.70000
1.0040
-0.3
4.83E+07
-
0
90
456
2
70E+04
2.19000
1.0008
+ 1.1
7.05E+08
-
0
93
7,740
5
49E+04
7.42000
0.9985
-3.2
8.93E+07
-
0
89
1, 010
3
23E+04
6.20000
1.0003
-0.2
7.65E+08
-
0
95
7,140
5
49E+04
7.32000
<«<•?
Page 1 of 2
Printed: 8/5/2008 2:27 PM
-------
Datafile: e: 080729V26
Client ID: Run# II-ACD-M23-1
Lab ID: P9464 6042 PAH 005
Stats
Largest +ve ST shift (sees!
Largest -ve RT shift (sees)
PAH Ax
1.1
-3.2
ES/SS
4.3
-1. D
Name
Actual
RT
Fred
RRT
13C6-Naphthalene
13C6-2-Methylnaphthalene
13C6-Acenaphtfaylene
13C6-Acenaphthene
13C6-Fluorene
13C6-Phenanthrene
13C6-Anthracene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a)Anthracene
13C6-Chrysene
13C6-Benzo(b)Fluoranthene
13C6-Benzo(k)Fluoranthene
13C4-Benzo(e)Pyrene
13C4-Benzo(a)Pyrene
dl2-Ferylene
13C6-Indeno(l,2,3-cd)Pyrene
13C6-Dibenzo(ah)Anthracene
13C12-Benzo(ghi)Perylene
8, 61
9,76
11.55
11.90
13.02
15.26
15.37
18.13
18.69
21.62
21.72
24.91
25.02
25.95
26.17
26.39
31.64
31.84
33.28
0.8857
1.0063
0.9757
1.0057
1.1002
1.2890
1.2995
0.9724
1.0025
1.1602
1.1656
0.9557
0.9597
0.9956
1.0040
1.0124
1.2143
1.2217
1.2766
AS--Anthracene
15.33
1.2897
SS-Fluorene
SS-Terpher.yl
12.95
19.04
0.9949
1.0506
JS-Methylnaphthalene
JS-Acenaphthene
JS-Pyrene
JS-Benzo(a)Pyrene
9.70
11.83
18.64
26.07
Analytical Perspectives
Wt/Vol: 1 Train
ICAL: MM6 PAH 080118 18JAN08
Actual
RRT
0.8884
1.0068
0.9767
1.0059
1.1005
1.2902
1.2995
0.9729
1.0028
1.1598
1.1653
0.9558
0.9599
0.9957
.0040
.0123
.2142
.2216
.2769
1.2957
0.9947
1.0497
Diff
sees
+1.6
+0.3
+0.7
+0.1
+0.2
+0.9
0
+0.6
+0.3
-0.4
-0.3
+0.2
+0.3
+0.2
0
-0.2
-0.2
-0,2
+0.5
+4.3
-0.2
-1.0
Response
3 .94E+06
2.63E+Q6
4.10E+06
3.30E+06
2.74E+06
4.01E+06
4.41E+06
.24E+06
.29E+07
.63E+06
.32S+06
. 22E+07
1.35E+07
1.24E+07
1.22E+07
9.37E+06
7.84E+06
7.91E+06
9.05E+06
1.58E+06
3.3 5E+06
3.16E+06
RRF
1.51
0.	96
1.79
1.	06
1.11
1,76
1.64
1.25
1.30
1.06
1.02
1.21
1.60
1.30
1.39
1.36
0.81
1.00
1.15
1.44
0.96
0.54

/
Recv.
73.9
78-1
72.2
98.0
77.6
71.6
84.8
85.4
202.0
88.9
86.3
106.0
88.6
99,9
91.9
72.2
102.0
83.1
82.4
34.7
128.0
113,0
3.53E+06
3.18E+06
4.93E+06
4.77E+Q6
Page 2 of 2
Printed: 8/5/2008 2:27 PM
-------
AP Lab ID: P9464_6042_PAH„005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 77
Acq: 30-Jul-2008 02:23:08
User: CEM Oatafile: 080729V26
Re I. Int.
100%>
Fn 1
130-9920
QC Check
7 02-10 55
Abs. Int.
-3.8707
1.93e7
O.OOeO
10.5 RT
Rel Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
[ I I % I | I I I
16.0
Abs. Int.
-4,84e7
2.42e?
-O.OOeO
17.0RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.00
0%-
I I I I f I
18.0
'	I	'
19.0
I I I f
20.0
21.0
22.0
Abs. Int.
i-2.58e?
-1.29e7
¦O.OOeO
RT
Rel. Int.	Abs. int.
r1.97e7
100%-,
Fn 4
292.9824
QC Check
23.02-35.01
O.OOeO
RT
0%
34.0
24.0
26.0
30.0
32.0
28.0
Results: P:\P9400_P9499\P9464jB042 PAH\resource$\P9464_6042_PAH_005utp_nss. saved 01-Aug-2008 13:17 (CMj
AP UltmTmce-Pm V3.992 User/System: CM/CMP4-015 see: 504-428
Peak annotation: Areas, Centrords
PKD: n/a Printed: 01 -Aug-2008 14:13:36 Page 1 of 9 .
-------
AP Lab ID: P9464_6042_PAH_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_dbS_0801 GC; pah_db5-SPLT5 Vial: 77
Rel. Int.
Fn ! 100%1
128.0626
Analyte
4o 5.94e5
8.40-10.20
0%-
Naphthalene
4.99e9
8.S1
Acq: 30-Jul-2008 02:23:08
User: CEM Datafile: 080729V26
¦\ 07e
• 5.37e8
Rel. Int.
Fn 1 100%-
134,0827
Standard
4o 2.88e3
8.40-10.20
0%-
—|—i—rh—i—p-1—i illn i—|—r—i—i i ]—i—r-i—r-j—i—i—i—i | i
8.6	8.8	9.0
ES-Naphthalene
3.94e6
8.61
i)iiii f" i 	i i i | i
9.2	9.4
9.6
T-f-r
98
1 I
10.0

'f'T f |11 r-"t	|		r""ymi	|	i	i	»	i		r"r""|	i	i	i	i	|im
8.6	8.8	9.0	9.2
r | I i I l j l l l l | I
9.4	9.6
Rel. Int.
Fn 1
142.0783
Analyte
4o1.25e4
8.40-10.20
0%-
T11 I l t l I l I 'I 'I I t
9.8 / 10.0
ihthaienar
e9 /
9.76 /
-O.OOeO
RT
Abs. Int.
-1.44e6
7.18e5
8.6
8.8
9.0
1 I 1
9,2
9.4
• l 1
9,6
Rel. Int.
pn -I 100%'
148.0984
Standard
4o2.69e3
8.40-10.20
0%-
9.8
ES2-Methyf naphtha
2.83e6
9.76
O.OOeO
RT
Abs^lntx
C-1.07e$U
v			
-5.37e8
O.OOeO
RT
Abs. Int.
-1,65e6
-8,26e5
| > i 1 "i "'I' i i i i I t—i I I j—i t l !—|—r—i—r—i—j—p
9,2	9.4	9.6
I I r;—I——r—T—!—T—f——I *	 |—r—I—I—I—| I 1	1	
9.8	10.0
Rel. int.
pn -j 100%-
152.1410
Standard
4o 3,51 e3
8,40-10.20
0%-
JS-Methylnaphthale
3 53eti
9.70
-O.OOeO
RT
Abs. Int.
-2.62e6
-1.3le6
i—¦¦¦->!'
8.6
1 I I I | I > l i | l i l l | 1 l l 1 | l < l 1 | i l i
8,8	9 0	9.2
i | i i i i | i i i i | i i i' »-y f ivf { r
9.4	9.6	9,6
i j i rr-i | i i i i j i i i i
10,0
¦O.OOeO
RT
Ret. Int.
Fn 1 100%-
130.9920
QC Ctieck
8.40-10.20
0%-
r i i i **[**r*f->T ¦ t
8.6
8.8
9,0
¦ i ¦
9.2
¦ i •
9.4
¦ i •
9.6
9,8
Abs, Int.
-3.87e7
-1,93e7
O.OOeO
10 0	RT
Results: P\P9400_P9499\P9464_6042 PAH\resources
-------
AP Lab ID: P9464_6042_PAH_0Q5
Instr: AutoSpec-Premier MM6
Rel, Int.
Fn 2 100%.
152.0636
Analyte
4o 1,20e6
11,50-12.30
0%-
Acenaphthyle
3.32e9
11.56
11.5	11.6
ES-Acenaphtnylene
Rel. Int.	4-1 %6
pn 2 100%- 1155
158.0827 :
Standard
4a 4.00e3 -
11.50-12.30 :
0%-
T-T"
11.5
11.6
Rel. Int.
Fn2 100%-
154.0783
Analyte
4o3.10e5
11.50-12.30
0%-
I i i i i | i
11.5
11.6
Rel. Int.
Fn 2 100%-
160.0984
Standard
4oS.02e3
11.50-12.30
0%-
Sampie ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 77
Acq: 30-Ju1-2008 02:23:08
User: CEM Datafile: 080729V26
Abs. int.
5.37e8
1 I 1
11.7
11.
11.9
12.0
I—I—I—I—|—I—I—I—!—]—! I I—I—| I I T I
12.1	12.2
1 I 1
11.7
1 I 1 1 ' 1 I '
11.8
12.0
12.1
Acenaphthent
11.90
¦ i '
11.7
I | I
11.8
I | t I
I I I I I I
11.9
12.0
12.1
ES-Acenaphthene
3,30e6
11.90
11.5
1 I ¦
11.6
11.7
11.8
12.0
12.1
Rel. Int.
Fn 2 100%-
164.1410
Standard
4o 4.56e3
11.50-12.30
0%-
JS-Acenaphthene
3.18e6
11.83
11.5
i -hi- | | ,t | | I
11.6
11.7
11.8
11.9
12.0
• i ¦
12.1
12.2
' i 1 1	' » r
12.2
12,2
12.2
I.OOeO
12.3 RT
Abs. Int.
-2.16e6
1.08e6
¦O.OOeO
12.3 RT
Abs. Int.
-3.02e8
1.51e8
O.OOeO
12.3 RT
Abs. Int.
-2 38e6
1.19e6
¦O.OOeO
12.3 RT
Abs. Int.
- 2.27e6
1.13e6
-O.OOeO
12.3 RT
Rel. Int.	Abs. Int.
pn 2 100%-j.
168.9888
QC Check ¦
11.50-12.30"
r4.76e7
0%'
12.0
12.2
Results: P:\P9400_P9499\P9464_6042 PAHVe$oumB$\P9464_6042_PAH_Q05.utp_fBS, saved 0l-Aug-2008 13:17 (CM)	Peak annotation: Areas. Ccntroids
AP UltrzTrace-Pm V3.992 User/System: CM/CMP4-015 cc: 1440, 0878,~S0B9. 8874. 4899 see: 504-428	Revised 01-Aug 2008 13:16.53 (CM) Printed: 01-Aug-2008 14:13:59 Page 3 of 9 ^
-------
AP Lab ID: P9464_6042_PAH_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah„db5_0801 GC: pah_db5-SPLT5 Vial: 77
Rel. Int.
100%
Fn 2
166.0783
Analyte
4o 4.04e5
12.70-16,50
Fluorene
2.10e9
13.02
0%-
Rel. Int.
100%-
Fn 2
172.0984
Standard
4o 4.51e3
12.70-16.50
0%-
1
Acq: 30.Jul.2008 02:23:08
User: CEM Datafile: 080729V26
Abs. Int.
-1.06e9
1
13.0
ES-Fluorene
2 74e6
13.02
A
i y i r f f i i
13,5
14.0
14.5
15.0
I I f ! V 1 I I | 1 I I I 1 I I I
5.32e8
15.5
16.0
¦ I * * *
13.5
i I i i i i I f i i i I i
14.0	14.5
m|	i""»1 i1 i \—rMir	i	t		i	
-O.QOeO
RT
Abs. Int.
-1.68e6
8.42e5
15.0
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o 1 91e4
12.70-16,50
0%-
15.
Phenanttrfene
15.26
16.0
i i r T* | i rs 1
13.0
¦ T~ '1—|—I—I—I—f^S|
13.5
¦ O.OOeO
RT
AbsJnt
fT07e&
5.37e8
' 1 I 1
14.0
r-1 ¦¦¦
14.5
I I t f I I I
15.0
,',HK
O.OOeO
	r	!¦	t	|	i	!¦	t	i	|	i	r	*	i	|	r	t	i	r
15.5	16.0	RT
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o 3.23e3
12.70-16.50
0%-
ES-Anihracerte
4.4le6
15,37
ES-Phenanthr
4.01e6
15.26
ne
13.0
13,5
'	1	''
14.0
14.5
"S1* | i i t f
15.0
I I \
15.5
I I | I I I I | I
16.0
Abs. Int.
- 2.89e6
¦ 1.44e6
O.OOeO
RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12,70-16.50'
0%-
I I I I | I
13.0
' I '
13.5
m,l	r	y	*	i	|	r	»	i	r	|	t	i	»	i	j	t	y	j	*	j	t	rn
14.0	14.5
15.0
""i	i	i	t	r	y	y	i	t	f	f	i	t	y	f	»	t	y	»	i	t	y	»	im
Abs. Int.
-4,84e7
2 42e7
15.5
16.0
O.OOeO
RT
Results: P:\P9400_P9499\P9454_6042 PAH\resaurces\P9464_6042_PAH_005. utp_res. saved 01-Aug-2008 13:17 (CM)
AP UltmTrace-Pm V3.992 User/System: CM/CMP4-015 cc: 6256, 6451,~3S69, 6605 see: 504-428
Peak annotation: Areas, Centroids
Revised: 01-Aug-2008 13:15:09 (CM) Printed: 01-Aug-2Q08 14:14:10 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_005
Iristr: AutoSpec-Premier MM6
Rel. Int.
100%-,
Fn 2
176.1410
Standard
4a 4 86e3
12.00-16,50 ¦
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GO: pah_db5-SPLT5 Vial: 77
0%-
SS-Fluorene
3.35e6
12.95
Acq: 30-Jul-2008 02:23:08
User: CEM Dataflle: 080729V26
Abs Int.
-2.30e6
12.0
i i it i i i i j11'"1 O'i ii i i1'i'pi
12.5	13.0
i i i i'i ^ i ^ i \ c i i i i y i tO1 i
13.5
14.0
'A i i^Trrr| i i i i [ i i i i 'fV I i i )
1.15e6
14.5
15.0
Rel. Int.
100%-
Fn 2
188.1410
Standard
4a 5.79@3
12.00-16.50 -I
15.5
AS-Anthracene
» S8e6
15.33
I		 O.OOeO
16.0	RT
Abs, Int.
1 09e6
0 A>— i i i r |—i—i t t-|
15.0
16.0
•5.47e5
t i t i O.OOeO
RT
Rel. Int.
100%-

Fn 2
168.9888
QC Check
12,00-16.50"
Abs. Int.
-4.84e7
-2.42e7
Results: P:
-------
AP Lab ID: P9464_6042_PAH_005
Instr: AutoSpec-Premier MMB
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 77
Rel. Int.
Fn 3 100%-
202.0783
Analyte
4o 4.26e5
17.50-22.50
0%-
^—(—r
-A-
Fkioranthene
3.50e9
18.14
S
Pyrene
3.45e9
18.69
Rel. Int.
j:n 3 100%'
208.0984
Standard
4o 1.02e4
17.50-22.50
0%'
Rel. Int.
Fn 3 100%"
205,0883
Standard
4 o 1.10e4
17.50-22.50
0%-
Rel. Int.
Fn 3 100%^
228.0939
Analyte
4o 1 05e5
17.50-22.50
0%
Rel. Int.
Fn 3 100%-
234.1140
Standard
4a 4.96e3
17.50-22.50
0%-
—r~
18.0
ES-Fluoranthene
5.24e6
18.13

19.0
20.0
21.0
Acq: 30-Jul-2008 02:23:08
User: CEM Datafile: 080729V26
Abs. Int.
riT07e9~"
-5.37e8
-O.OOeO
RT
Abs. Int.
-2.58e6
-l.29e6
22.0

18.0
19.0

—I—
20.0
I I | i 1 I 1 |	
21.0
¦"T"	I**"	f	
22.0

A^k ,A,
18,0
ES-Pyrerte
1.29e7
18.69

—
19.0
t I | t mt
20.0
-A-
| I
21.0
7
22.0
BenziaWuithracerte
f.24e9
21.62
—I	
18.0
19.0
20.0
21.0
A-
i i i
22.0
ES-Benz(a)AnUirace
l.B3e6
18.0
—I—r-
19.0
-A-
20.0
—I—
21.0
21.62
-O.OOeO
RT
Abs, Int.
-6.33e6
•3.17e6
•O.OOeO
RT
Abs, Int.
r—8.23e8
•4.11e8
-O.OOeO
RT
Abs. Int.
- 2.59e6
¦ 1,29e6
22.0
•O.OOeO
RT
Rel. int.
Fn 3 100%-q
218.9856
QC Check
17.50-22.50
Results: P:\P9400_P9499\P9464_6042 PAHSfssou/ces\P9464_6042_PAH_005.utp_res. saved 01-Aug-2008 13:17 (CM)
AP UltmTmce-Pm V3.992 User/System: CM/CMP4-015 cc: 9140. 2987, 5102, 6386. 5684 see: 504-428
21.0
Revised: 01-Aug-2008
Abs. Int.
2.55e7
1.28e7
O.OOeO
RT
Peak annotation: Aneas, Centroids
13:15:35 (CM) Printed: 01-Aug-2008 14:14:33 Page Sot 9
-------
AP Lab ID; P9464_6042_PAH_005
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 3
212,1410
Standard
4o 5.61e3
18.00-20.00
3,61 e5
18.14
Sample ID: Run# II-ACD-M23-1
VSIRexpt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 77
JS-Pyrene
4.93e6
18.64
0%-
Acq: 30-Jul-2008 02:23:08
User: GEM Datafile: 080729V26
Abs. Int.
-2.97e6
i i-i i	i | i	'i i i i j ! i t -i-f i f ¦ i |
Rel. Int.
100%-
Fn 3
244.1974
Standard
4o 2.51e3
18.00-20.00
0%-
18.2
18.4
18.6
I 1 1 ' 1 I
18.8
"r " H
19.0
T"-
-•-n-
19.2

-r-p*-
19.4
1.49e6
19.6
SS-Terprtenyl
3.lte6
19.04
MJalfeTMTaMTaalTlll^MTfeanriaa9lllTH'll^IIHVllllTlllTlll^r11 -O.OOeO
19.8	RT
Abs. Int.
-1.96e6
"fTW"') "iii i | 1 I	i | i i i r | i i»
-9.78e5

18.2
18.4
18.6
18.8
19.0
19.2
19.4
¦j r i j t I > i | i i i i j i i f i | i r i l 0 .OOeO
19.6	19.8	RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
18.00-20.00"
Abs. tnt.
-2 51e7
- 1.26e7
0%-
18.2
' I '
18.4
ii)ii
18.6
f t I I | T
18.8
19.0
Results: P:\P9400_P9499\P9464 6042 PAHtesaurce$\P9464 6042 PAH_005.utp_ms, saved 01-Aug-2008 13:17 (CM)
AP U/fraTrace-Pro V3.992 UsenSystem CMCMP4-C1S cc: 9411,8295 see: 504-42B
19.2
19,4
' > '
19.6
19.8
-O.OOeO
RT
Revised: 01-Aug-2008 13:17:01 (CM)
Peak annotation: Areas, Centmisis
Printed: 01-Aug~2008 14:14:44 Page 7 of 9 •
-------
AP Lab ID: P9464_6042_PAH_005
Instr: AutoSpec-Premier MM6
Re!. Int.
100%-
Fn 4
252,0939
Arialyte
4o2.70e4
23.50-28.00
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 77
o%-
Rel. Int.
100%-
Fn 4
258.1140
Standard
4o1.88e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
256.1073
Standard
40 4.04e3
23.50-28.00
BenzfblFluoranthene
2 29e9
24.9^
fluoranthene
.9668/
soy
BenzfelPyrene
I.3le9
25.95
24.0
24.5
f i t | i r f i i" i T	I 9
25.0
ES-Benz(b) Fluorant
1,22e7
24.91

25.5
BenzrajPyren
5.34e8
26.17
/
Acq: 30-Jul-2008 02:23:08
User: CEM Datafile: 080729V26
Abs, Int.
5 45e8
2.73e8
26.5
27.0
27.5
	J	I	»	I	f	
24.0
24.5
25.0
i-T-r-
25.5
I |
2S.0
	'	I	¦	
26.5
1 ) I 1 I I | I I 1 I | I
27.0	27.5
ES-Benz(e)Pyrene
j^-BenziaJPyrene
zwra ^ 22e7
26.17
0% i i i i |
i" i I | f i m | t i i1 i | t
24.0	24.5
25.0
25.5
26.0
Rel. Int.
100%
Fn 4
264.1692
Standard
4o 3.03e3
23.50-28.00 •
' ' 1 I ¦
26.5
ES-Perytene
8.37e6
26.38
27.0
27.5
0%-
JS-Senz^a)Pyrei
26.07
| I 1 I I j ! 1 I f*^1 I I I I | I
24.0	24.5
I i i i < I i
25.0
-O.OOeO
RT
Abs. Int.
-4.61e6
2.31e6
O.OOeO
RT
Abs. Int.
-4 43e6
-2.21e6
1 I I | I I t I f I I'll | ! I I t j"Ip I I T [ I I I I | i I I ! | I I I 1 [ I 1 I I | I I I
25.5	26.0	26.5	27.0	27.5
-O.OOeO
RT
Abs. Int.
-2,73e6
¦ 1 37e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 4
292.9824
GC Check J
23.50-28.00
0%-
I ' ' ' ' I •
24.0
24.5
¦ I 1
25.0
i | t r
t | > i t i | t » i r ] r
25.5	26,0
26.5
Results: P:\P9400_PS499\P94S4_6042 PAH\resourt:es'iP9464_6042_PAH_005vtp_fes. saved 01-Aug-2008 13:17 (CM)
AP UttraTrace-Pro V3 992 User/System: CM/CMP4-015 cc:~tS74, 3736, 6430, 3130 see: 504-428
' I '
27,0
27.5
» » | I I
Abs. Int.
1.92e7
9 59e6
•O.OOeO
RT
Peek annotation: Areas. Centroids
Revised: 01Aug-2008 13:17:10 (CM) Printed: 01-Aug-2008 14:14:56 Page 6 of 9
y
-------
AP Lab ID: P9464_6042_PAH_005
Instr: AutoSpec-Premier MM6
Rel, Int.
Fn 4 100%.
276.0939
Analyte
4a 5.49e4
29.0-36.0
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 77
0%-
29.0
Rel. Int.
Fn 4 100%-
282.1140
Standard
4o5.12e3
29 0-36.0
0%-
29.0
Rel. Int.
pn 4 100%-
288.1342
Standard
4o 2 51e3
29.0-36.0
0%-
29.0
Rel. Int.
Fn 4 ^00%-
278.1096
Analyte
4o 3.23e4
29.0-36.0
29.0
Rel. Int.
Fn 4 100%-
284.1297
Standard
4o2.79e3
29.0-36.0
0%-
29.0
lrnJ(i23-cd)Pyrene
7.05e8
31.67
BerK(|h||^ytene
33.29

30.0
31.0
Acq: 30-Jul-2008 02:23:08
User: CEM Datafile: 080729V26
Abs, Int.
-1.35e8
33.0
r~* ' ' ¦ i ¦
34.0
•6.74e7
O.OOeO
i | > i r r | i i i
35.0	36.0 RT
ES-li
lnd|123-aI)Pyre
31.64
30.0
31.0
j""'!1" t 1 1 | i I i i [ f r 'T t y r y ¦
32.0	33.0
ES-Benz(ghi)Peryl
9.0586
33.28
t	|"	T	T	T	1	I""
34.0
Abs. Int.
-1.61e6
•8.04eS
O.OOeO
¦¦¦I	i	r	[	r	r	r	t	|	%	i	f	t
35.0	36.0 RT
n 1 r
30.0
31.0
32.0
Dibenz|ah|Anthf^e
31.79 /
33.0
Abs. Int.
-1,59e6
-7.96e5
T_r-
t-|—r
34.0
till
O.OOeO
35.0
36.0 RT
30.0
31.0
32.0
ES-Dibenz(ah)Anthr
7.91 e6
31.84
f	1	1	1	1	[¦	T	T""
33.0
34.0
35.0
30.0
31.0
Abs. Int.
-1.04e7
-5.19e6
-O.OOeO
36.0 RT
Abs. Int.
1.18e6
5.89e5

I I I I
O.OOeO
32.0
33.0
34.0
35,0
36.0 RT
Rel. Int.
Fn 4 100%-
292.9824
QC Check
29.0-36.0
33.0
Results- P.\P9400_P9499\P9464_€042 PAH\resources\P9464_6042_PAH_005ntp_n>s. Saved 01-Aug-2008 13:17 (CM)
AP Ultra Trace-Pro V3 992 User/System: CM/CMP4-01S cc: 1146, 3172, 2115, 0803, 4635 see: 504-428
34.0
Revised: 01 -Aug-2008 13:13:56 (CM)
Abs. Jrit.
-1.97e7
9 83e6
O.OOeO
36.0 RT
Peak annotation: Areas. Centmids
Printed: 01-Aug-2008 14:15 07 Page 9 of 9
-------
Datafile: e: 080730V17
Acquired: 30 Jul 2008 19:56:01
Client ID: Run# II-ACD-M23-1
Lab ID: P9464 6042 PAH 005-SPL400 ./"
Wt/Vol: 1 Train
J Level: 4 rig/Train


ICAL: MM6 PAH 080118 18JAN08
Nominal ES spike: 40 ng

Stats

PAH Ax
ES/SS






Checkcode:




Largest tve RT shift
(sees)

#VALU£!
3.8











Largest -ve RT shift
(sees)

IVALUE!
-1.7

/








y
H«a#

Actual

Fred
Actual
Diff


OH— cone




RT
QC
RRT
RRT
Sees
Response
Ra
RRF
jnq/jraln

Noise

DL
if Naphthalene

8.56"^,
9,75 S

1.0005
0.9999
-0.3
1,40E+09
_
1
09
396,000 M
3
34E+04
32
90000
jt" 2-Methylnaphthalsne


1.0003
1.0003
0
8.02E+07
-
1
11
57,500 4*
6
89E+03
17
20000
Acenapnlhylene

11.55/"

1.0003
1.0000
-0,2
1.94E+08
-
0
86
128,000
-------
Datafile: e: 080730V17
Client ID: Run# II-ACD-M23-1
Lab ID: P9464 6042 PAH 005-SPL400
Wt/Vol: 1 Train
Stats
Largest +ve RT shift (sees)
Largest •ve RT shift (sees)
Name
Actual
RT
PAH Ax
#VALUE!
IVALUE!
ES/SS
3.8
-1.7
Pred
RRT
Actual
RRT
oiff
Sees
13C6-Naphthalene
13 C6-2-Methylnaphthalene
13C6-Acenaphthylene
13C6-Acenaphthene
13C6-Fluorene
13C6-Phenanthrene
13C6-Anthracene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a)Anthracene
13C6-Chrysene
13C6-Benza(b! Fluoranthene
13C6-3enzo(k)Fluoranthene
13C4-Benzo(e)Pyrene
13C4-Benzofa)Pyrene
dl2-Perylene
13C6-Indeno(1,2,3-cd)Pyrene
13C6-Dibenzo(ah)Anthracene
13012-Benzo(ghii Perylene
8.56
9.74
11.55
11.90
13.02
15.25
15.37
18.12
18.68
21.61
21.71
24.91
25.01
25.95
26.15
26.38
0.00
0.00
0.00
0.8855
1.0063
0.9757
1.0059
1.1003
1.2892
1.2995
0.9725
1.0025
1.1602
1.1663
0.9557
0.9604
0.9958
1.0046
1.0127
1.2144
1.2235
1.2772
0.8843
1.0064
0.9760
1.0058
1.1002
1.2888
1.2991
0.9724
1.0023
1.1599
1.1652
0.9557
0.9598
0.9959
1.0035
1.0121
0.0000
0.0000
0.0000
-0.7
+ 0.1
+ 0.2
-0.1
-0.1
-0.3
-0.
-0.
-0.
-0.
-1.
0
-0.9
+ 0.2
-1.7
-0.9
AS —Anthracene
15.32
1.2897
1.2951
+ 3.8
SS-Fluorene
SS-Terphenyl
12.95
19.03
0.9949
1.0507
0.9949
1.0504
0
-0.3
JS-Methylnaph thalene
JS-Acer.aphtiiene
JS-Pyrene
JS-Benzo(a)Pyrene
9.68
11.83
18.63
26.06
Analytical Perspectives
Page 2 of 2
ICAL: MM6_PAH_080118_18JAN08
Response	Ra.	RRF .	Recv.
1.31E+05	-	1.51	194.0
5.02E+04	-	0.96	118.0
7.05E+04	-	1.79	108.0
4.70E+04	-	1.06	121.0
4.23E+04	-	1.11	105.0
8.97E+04	-	1,76	140.0.
5.08E+04	-	1.64	85.1-
9.14E+04	-	1.25	112.0
2.01E+05	-	1.30	236.0
3.54E+04	-	1.06	51.1
3.82E+04	-	1.02	57.4
7.28E+04	-	1.21	83.3
1.05E+05	-	1.60	90.8
9.82E+04	-	1.30	105.0
7.09E+04	-	1.39	70.6
6.06E+04	-	1.36	61.8
0.00E+00	-	0.81
0.00E+00	-	1.00
0¦00B+00	—	1.15	—
2.37E+04	-	1.44 f	45.2
4.12E+04	-	0.96	102.0
3.50E+04	-	0.54 /	71.6
4.46E+04	-
3.65E+04	-
6.55E+04	-	-
3.60E+04	-
Printed: 8/5/2008 2:27 PM
-------
AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AutoSpee-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
Acq: 30-Jul-2008 19:56:01
User: CEM Datafile: 080730V17
Rel. Int.
100%-,
Fn 1
130.9920
QC Check
7,02-10.55
0%-

' ' T
7.5
"j	r	T	T	1	|	T	T	r	T	Y"
9.5
10~5 RT
8,0
8.5
1 1 '
9,0
10.0
Rel. Int.
100%-
Fn 2
168.9888
QC Check
10.59-17.00"
0%-
-i—i—1—r-
~V~
' I 1 '
15,0
11.0
12.0
I I I | I I I
13.0
14.0
16.0
17.0 RT
Rel. Int.
100%-
Fn 3
218,9856
QC Check
17.02-23.01
f-t-—r-
0%-
18.0
19.0
20.0
21.0
22.0
23.0 RT
Rel, Int.
100%
Fn 4
292,9824
QC Check
23,02-35.01
24.0
26.0
| g 1 t t |
28.0
30.0
Results: P:\P9400_P9499\P9464_8042 PAH\re5Ources\P9464_6042_PAH_O05-SPL400.utp_ms, saved 31-Jul-2008 15:53 (CM)
AP UttmTrace-Pro V3.992 User/System: CM/CMP4-015 see: 158-332
32.0	34,0
Peak annotation: Areas. Cenlroids
PKD: n/a Printed: 31-Jui-2008 16:43:35 Page 1 of 9
-------
AP Lab ID: P9464. ,6042_PAH_005-SPL400
Instr; AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
Rel. Int.
pn1 100%-
128.0626
Analyte
4o3.34e4
8.40-10.20
0%-
Rel. Int.
pn -| 100%-
134.0827
Standard
4o 1.35e3
8.40-10.20
0%-
Rel. Int.
Fn1 100%-
142.0783
Analyte
4o 6.89e3
8.40-10.20
0%-
Rel. Int.
pn -| 100%-
148.0984
Standard
4a 9.65e2
8,40-10.20
0%-
Rel. Int.
i 100%-
152.1410
Standard
4o 1,02e3
8.40-10.20
0%-
Naphthalene
1.40ei
8.56
Acq: 30-Jul-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
1.06e9
5.29e8
8.8
9.0
9.2
9.4
T1-
9.6
I | I I I I | I I
9.8
I '
10.0
ES-Naphthalene
1.3leS
8.56
8.6
T''
8.8
9.0
9.2
T
' I ' '
9.4
9.6
9.8
2-Methylnaphthalene
8.02e7
9.75
I | »
10.0
8,6
—I—[-¦>' T—IT
8.8
9.0	9,2
9.4
1 1 I » 1 1 1 I
9,6
1 | f—»—I—I | "
9.8
1 I 1
10.0
ES-2-Methyinaphtha
5.02e4
9.74
8.6
4.07e4
8.57
8.8
9.0
fi|irri|iiiv|ivii—j—r~
9.2	9.4
i ""i	!¦	r	i	>	}	
9.6
JS-Meiiylnaphttate
4.46e4
9.68
"r"T~ir
9.8
I ' 1 ' ' I '
10.0
¦ i •
8.6
8,8
9,0
9.2
-r-r-r
9,4
9.6
9.8
	f	|	T	I	t	f" |' 1
10.0
•O.OOeO
RT
Abs. Int.
-1,12e5
¦5.61e4
¦O.OOeO
RT
Abs. Int.
-6.16e7
¦3.08e7
¦O.OOeO
RT
Abs. Int.
r 5.23e4
-2.61e4
-O.OOeO
RT
Abs. Int.
-4.77e4
¦2.38e4
•O.OOeO
RT
Rel. Int.
pn i 100%-
130.9920
QC Check
8.40-10.20
I | I I I I | 1 I I » j I I I I | I
8,6	8,8
| I 1 I I | I I I I (
9.0	9,2
Abs. Int.
6.43e7
3.22e7
O.OOeO
RT
10.0
Results; P\PS400_P9499\P9464_6042 PAH\msource$V>9464_6042_PAH_W$$PL400.utp_ms, saved 31-Jul-2008 15:53 (CM)	Peak annotation: Areas, Centrotds
AP UltraTrace-Pro V3.992 User/System: CWCMP4-C15 cc: 2696, 0628, 0442, 4163. 4B66 see: 158-332	Revised: 31-M-2003 15 53 03 (CM) PrffltG(S~ 31 -Jui-2008 1&43i44 P3QB 2 of 9
-------
AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
Rel. Int.
Fn2 100%-
152.0636
Analyte
4o 2.07e4 ¦
11.50-12.30 :
Acenaphthyiene
1.94e8
11.55
Acq: 30-Jul-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
1.30e8
¦6.49e7
11.7
11.8
• 1 1
11.9
| i i i i | r i i i |
12,0
t | i t r
12.1
1 I I | I
12.2
11.55
£S-Acervaphthylene
Rel. Int.	?.05e4
pn 2 100%-
158.0827
Standard
4o 1,05e3
11.50-12.30
0%
I 1 1,1 I
11.5
Rel. Int.
Fn2 100%-
154.0783
Arialyte
4a 1 09e4
11.50-12.30
11.5
Rel. Int.
Fn 2 100%1
160.0984
Standard
4o I.41e3
11.50-12.30
0%
i ¦
11.5
Rel. Int.
Fn2 100%-
164.1410
Standard
4o 1.05e3
11.50-12.30
0%-
i1^
11.5
f f 1 | I I I »
11.6
11.7	11.8
1 1 t | I 1 »
11,9
11.6
11.7	'
Acenaphthene
5.62e6
11.90
12,0
12,1
12.2
11.8
r i i j i i r"
11.9
ES-Acenaphthene
4.70e4
11.90
I i i i i I
12.0
i i i i I i i
T1"
12.1
11,6
¦ i ¦
11.7
11.8
JS-Acenaphthene
3,65e4
11,83
11.9
¦¦¦t	i	r	'i'1"
12.0
12,1
12,2
11.6
11.7
11.8
11.9
12.0
12.1
12.2
•O.OOeO
12.3RT
Abs. Int.
6.23e4
¦3,11e4
¦O.OOeO
12.3RT
Abs, Int.
-3.61e6
1 81e6
•O.OOeO
12.3RT
Abs. Int.
4.94e4
• 2.47e4
¦O.OOeO
12.3 RT
Abs. Int.
-3.52e4
¦1.76e4
I.OOeO
12,3 RT
Rel. Int.
Fn 2 100%
168.9888
QC Check
11.50-12.30
0%-V
11.5	11.6	11.7	11.8	11.9
Results: P:\P94O0_PS499\P9464_6O42 PAHtesources\P9464_6042_PAH_005-SPL400utp_res. saved 31-Jul-2008 15:53 (CM)
AP UltraTmee-Pro~ V3 992 User/System: CM/CMP4-015 cc 7497. 7924. 3833. 8059. 9101 see: 158-332
Abs. Int.
-7.66e?
3.83e7
O.OOeO
12 3 RT
Peak annotation: Areas. Certtmids
Revised: 31-Juf-2008 15:53:09 (CM} Printed: 31-Jut-2008 16:43:53 Page 3 of 9
-------
AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
166.0783
Analyte
4a 4.89e3
12.70-16.50
Fluorene
3 25e7
13,02
0%
-A	a/ \
Rel, Int.
100%
Fn 2
172.0984
Standard
4o 1.21e3
12.70-16,50
i ' ' 1 * "i""'
13.0
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4o 5.31e3
12.70-16.50
0%-
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
Acq: 30-Jul-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
-2.07e7
A—
ES-Fuorene
4.23e4
13.02
-!—i—i | i—i—r~
14.0
14.5
15.0
15.5
16,0
Rel. Int.
100%-
Fn 2
184,0984
Standard
4o 1.08e3
12.70-16.50
0%-
13.5
14.0
14.5
15.0
i i | i > i i—|—r-
15.5
Phenanthrene
3.24e8 /
15.25 /
/
¦¦¦¦I	!¦	f	t	|	¦!	i	y	i	mi	f	t	i	|	t	'»	i""
13,0	13,5
14.0
14.5
' I 1
15.0
, Anthracene
2,43e7
15.37
V /-s
l~'~
15.5
ES-Phenanthrene
8.97e4
15.25
EJP-Anthraeene
5.08e4
15.37
J. i

13.0
13,5
14.0
14,5
15.0
15.5
16.0
1 I '
16.0
16,0
¦ 1,04e7
. , , O.OOeO
RT
Abs. Int.
-4.98e4
2.49e4
i |—r—i—i—i—O.OOeO
RT
Abs. int.
2.12e8
-1.06e8
•O.OOeO
RT
Abs. Int.
-6.72e4
-3.36e4
-i—r—i—O.OOeO
RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.70-16.50
Abs, fnt,
-7.82e7
-3.91 e7
0%-
1 I ' ' 1 ' I
13.0
,MT	T	T	f	T	T	I""
13.5
14.0
14.5
' I ' 1 ' 1 I
15.0
15.5
'	16.0
-O.OOeO
RT
Results: P:\P94O0_P9499\P9464_6O42 PAH^esotirces\P9464_6042_PAH_005-SPL400utp_res. saved 31-Jul-2008 15:53 (CM)
AP UttraTrace-Pm 1/3,992 User/System: CIWCMP4-01S cc: 1413, 6460, 0526, 6451 scc~l5B-332
Peak annotation: Areas, Centroitis
Revised: 31-M-2008 15:47:49 {CM•) Printed: 31-Jul-2008 16:44:03 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
176.1410
Standard
4o 1.l6e3
12.00-16.50
SS-Fluorene
4,i2e4
12.95
0% - i i i i j i
12.0
Rel. Int.
100%-
Fn 2
188.1410
Standard
4a 1.51e3
12.00-16,50
12,0
12.5
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
| i r i i | i t i i [
13.0	13.5
14.0
14.5
15.0
15.5
AS-Anthraoene
2.3?e4
15.32
Acq: 30-JuI-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
-4,29e4
16.0
2 15e4

>[1111
12,5
t I f t * \
13.0
13.5
14.0
14.5
-r-pt-
15.0
15.5
' 1 I '
16.0
0.0060
RT
Abs. Int.
-3.27e4
1.64e4
•O.OOeO
RT
Rel. Int.
100%-
Abs. Int.
-7 82e7
Fn 2
168.9888
QC Check
12,00-16,50"
-3.91e7
0%-
12.0
12.5
-i—i—|—i—i—r-
13.0
13.5
T
14.0
-r
14.5
Results: P:\P940O_P9499\P9464_6O42 PAH\resources\P9464_6042_PAH_005.SPL400utp_res. saved 31-Jul-2008 15:53 (CM)
AP UltraTrace-Pro V3.992 User/System CM/CMP4-015 cc: 93 IB, 5805 see: 158-332
15~0
15,5
-I—I—I—|—I—!—
16,0
-O.OOeO
RT
Peak annotation: Areas, Centroids
Revised 31-Ju!-200B 15:52:54 (CM) Printed: 31-Ju!-2008 16:44:12 Page 5 of 9
-------

AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn 3 100%-
202.0783
Analyte
40 9 87e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%
208.0984
Standard
4a 4.05e3
17.50-22.50
0%
Rel. Int.
Fn 3 100%'
205.0883
Standard
4o 1,76e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-
228.0939
Analyte
4o 2.92e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-
234.1140
Standard
4o 1 36e3
17.50-22.50
Wo-
Fluoranthen
1.48e8
18.13

Sample ID: Run# II-ACD-M23-1
VSIR expl: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
Pyrene
1.39e8
18,60

18.0
ES-Fluoranthene
9.14e4
18.12
19.0
18.0
ES-Pyrene
2.01 e5
18.68
20.0
21.0
22.0
20.0
21.0
| r i t i j
' 220
Benz(a)Anttiracene
a64e6/l
21.62
19.0
X
20.0
21.0
22.0
ES-Benz(a)Anthrace
3.54e4
21.61
3.G7e4
Acq: 30-Jul-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
-9.03e7
-4.52e7
-O.OOeO
RT
Abs. Int.
-6.74e4
-3.37e4
O.OOeO
RT
Abs. Int.
-1.4le5
- 7 06e4
-O.OOeO
RT
Abs. Int.
-6.44e6
- 3.22e6
'"I	r	
•O.OOeO
RT
Abs. Int.
-3.06e4
¦1.53e4
18.0
19.0
20,0
21.0
22.0
-O.OOeO
RT
Rel. Int.
Fn3 100%
218.9856
QC Check
17.50-22.50
18.0
19.0
20.0
21.0
22.0
Abs. Int.
-4 07e7
2.04e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_00S-SPL40autp_nas. saved 31-Jul-2008 15:53 (CM)	Peak annotation: Areas, CentrviOs /
AP UmTrnce-Pm V3 992 Uset/Sysiem: CM/CMP4-01S cc: 7069. 8507, 0103, 7813, 6799 sec: 158-332	Revised: 3!-Jul-2008 15:51:54 (CM) Printed: 31-M-2008 16:44:21 Page 6 of 9
-------
AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
212,1410
Standard
4o 2.88e3
18.00-20.00
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
0%-
Rel. Int.
100%-
Fn 3
244.1974
Standard
4o1,18e3
18.00-20.00
JS-Pyrene
6.55e4
18.63
Acq: 3Q-Jul-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
-4,83e4
18.2
18.4
18.6
18.8
19.0
SS-Terphenyl
3.5004
19.03
19.2
1 i ¦
19.4
• I '
19.6
-2.42e4
« i' i i i i O.OOeO
19.8	RT
Abs. Int.
3.26e4
0% i i i » i i i i i i i i i i j i
r
18.2
18.4
	I	I		|		t				,	
18.6	18.8	19.0
	[		i	|-"i	
19.2	19.4
1 t i I t I I
19.6
' I '
19.8
•1.63e4
•O.OOeO
RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
18.00-20.00
0%-
18.2
I I | t »
18.4
18.6
	r„„v„„y„.T„„
18.8	19.0
19.2
19.4
Results: P:\P94QO_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_005-SPL400Mtp^res. saved 31-Jul-2008 15:53 (CM)
AP UttraTrace-Pro V3.992 User/System: CM/CMP4-01S cc: 6118,0122 see: 158-332
I | t I f < }
19.6
r > I i >
19.8
Abs. Int.
-4.06e7
2.03e7
O.OOeO
RT
Peak annotation: Areas. Centroids
Revised: 31-Jul-200a 15:53:16 (CM) Printed: 31-Jul-2Q08 16:44:30 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4a 4.69e3
23.50-28.00
0%-
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Via!: 77
Benz(b)Fluoranthene
A - 1.40e7
^y-^4 93^
Benim}Fluoranthene
18.48e6
\2S.0-y

24.0
Rel. Int.
100%-
Fn 4
258.1140
Standard
4a 8.08e2
23.50-28.00
0%-
I I I I I 1 1
24.0
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o 1 41e3
23.50-28.00
0%-
' ¦ ' t '
24.0
Rel. Int.
100%
Fn 4
264.1692
Standard
4o 1,23e3
23.50-28.00
24.5
e rwene
1.04e7
aiPvtene
2.65e6
26.17
Acq: 30-Ju 1-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
-2.93e6
26.0
i ) i i r i j i i i i )
27.0
ES-Benz(b)Fluorant
7.28e4
24.91
24.5
25.0
25.5
26.0
26.5
27.0
ES-Benz(e)Pyrerte
9.r£*
2!
3reBeriz(a)Pyrene
7.09e4
24.5
25.0
25.5
26.0
26.5
27.0
ES-Perylene
6.08e4
JS-Benz(a)Pyrene 26 38
3.6Qe4
26.06
24.0
| » I f t
24.5
27.5
27.5
27.5
25.0
25.5
26.0
26.5
27.0
1 | r » > i |
27.5
1.46e6
-O.OOeO
RT
Abs. Int.
-3.86e4
1.93e4
26.15
-O.OOeO
RT
Abs. Int.
-4.07e4
¦2.03e4
•O.OOeO
RT
Abs. Int.
-3.14e4
1.57e4
-O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28.00'
0%-
24.0
24.5
J ' !—1	I—
25.0
' | I I—i—|—I * f—f " ['
25.5
*"T1 'T—p*—r t-
26.0
26.5
27.0
27.5
Abs. Int.
-3.34e7
• 1,67e7
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHVesaurces\P9464_6042_PAH 005-SPL400 utp res. saved 31-Jul-2008 15:53 (CM)	Peak annotation: Areas, Centroids
AP UttraTrace-Pro V3.992 User/Syslem: CM/CMP4-015 cc: 6254. 7548, 5093. 9632 sec 158-332	Revised: 31-M-2Q0S 15:53:27 (CM) Printed: 31-Jul-2008 18:44:40 Page 8 of 9
-------
AP Lab ID: P9464_6042_PAH_005-SPL400
Instr: AuloSpec-Premier MM6
Rel. Int.
pn ^ 100%-
276-0939
Analyte
4o 3.58e3
29.0-36.0
0%-
Sample ID: Run# II-ACD-M23-1
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT400 Vial: 77
Benz(ghi]|l
lnd(123-cd)Pyrene
3.8166
31.70
i i i i
33.32
Acq: 30-Jul-2008 19:56:01
User: CEM Datafile: 080730V17
Abs. Int.
6.73e5
¦ 3.37e5
29.0
30.0
31.0
32.0
33.0
34.0
35.0
¦O.OOeO
36.0 RT
Rel. Int
pn 4 100%-
282.1140
Standard
4o 1.94e3
29.0-360
0%
lilt
29.0
30.0
"T	|	1	»	?	f	I	t	T""
31,0
32.0
33.0
340
mr	*	f	
'"T	T	T	V"
35.0
Abs. Int.
-2.77e4
1.39e4
O.OOeO
36.0 RT
Rel. Int.
pn 4 100%
288.1342
Standard
4a 8,70e2
29.0-36.0
0%
29.0
Rel. Int.
pn4 100%-
278.1096
Analyte
4o 2.96e3
29.0-360
0%
| 1 I I » |
33.0
I I j
34.0
DibenzfaMAnthrace
4,22e5
31.78
Abs. Int.
-2.14e4
1 07e4
O.OOeO
29.0
30.0
31.0
32.0
33.0
34.0
35.0
36.0 RT
Abs. Int.
7.08e4
3.54e4
O.OOeO
36.0 RT
Rel. Int.
Pn 4 100%-
284.1297
Standard
4o 9.36e2
29.0-36.0
0%-
29,0
30.0
31.0
32.0
' I '
33.0
y | »
34.0
35.0
Abs, Int,
-1 92e4
9 61e3
O.OOeO
36.0 RT
Rel. Int.
Fn4 100%
292.9824
QC Check
29.0-36.0
32.0
33.0
Results: P:\PS4W_P9499\P9464_6042 PAH\mS0urve$\P9464_6042_PAH_0Q5-SPL4W.utp_ms. saved 31-Jut-2008 15:53 (CM)
AP UltraTmce-Pro V3.992 User/System: CM/CMP4-015 cc; 2211. 4550. 4953, 8705. 4241 sec: 158-332
34.0
Revised: 31-Jut-2008 15:52:22 (CM)
Abs. Int.
r3.34e7
1,67e7
O.OOeO
36,0 RT
Peak annotation: Areas. Centmids .
Printed: 31-Jut-200S 16:44:49 Page 9 of S
-------
Datafile: e: 080729V27 yj	Client ID: Run# II-ACD-M23-2 \/
Acquired: 30 Jul 2008 03:02:34 < Lab ID: P9464_6042_PAH_0Q6 ^
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
Name
Naphthalene
2-Methylnaphthalene
•4 Acenaphthylene
Acenaphthene
if Fluorene
Phenanthrene
# Anthracene
^ Fluoranthene
Pyrene
Benzo(a)Anthracene
Chrysene
Benzo(b)Fluoranthene
Benzo(k)Fluoranthene
Benzo(elPyrene
Benzo(a)Pyrene
Perylene
Indent) (1,2,3 -cd) Pyrene
Dibenzo(a,h>Anthracene
Benzo{ghi!Perylene
Actual
RT
PAH Ax
1.0
-2.1
QC
8.60^
9.75 /
11.55
H.89 y
13.02/
15.25/
15.37/
18.13/
18.68 ^
21.61'^
21.71 /
24.92	/
25.01 '
25.94 /
26.16
26.48 /
31. 65/
31.78 /
33.28 /

ES/SS
4.8
-1.6
Fred
RET
1.0004
1.0003
1.0003
1.0003
1.0003
1.0002
1.0002
1.0002
1.0001
1.0001
1.0001
1.0001
1.0001
1.0001
1.0001
1.0042
1.0002
1.0002
1.0004
4. r*T«T~w >
Cjs»*
Analytical Perspectives
Wt/Vol: 1 Train
J Level: 4 ng/Train

MM6 PAH 080118 18JAN08
Nominal ES spike: 40 ng

Actual
Dif f
Checkcode:



RST
Sees
Response
Ra
RRF
^ig/TraJji
Noise
DL
0
9987
-0.9
5.51E+Q9
-
1
09
48,700
1.41E+06
96.90000
1
0000
-0.2
3.G1E+09
-
1
11
48,400
1.73E+04
1.27000
0
9998
-0.3
3.69E+09
-
0
86
46.200
2.12E+06
132.00000
1
0003
0
1.39E+Q9
-
1
00
21.200
6.99E+Q5
40.50000
1
0005
+0.2
2.80E+09
-
1
05
49,000
9.17E+05
74.40000
0
9998
-0.4
4.87E+09
-
1
12
46,400
2.74E+04
1.81000
1
0001
-0.1
2.61E+09
-
1
09
26,300
2.74E+04
1.20000
1
0001
-0.1
3.75E+09
-
1
02
33,100
8.65E+05
41.60000
1
0002
+0.1
3.54E+09
-
1
03
9,780
8.65E+05
14.90000
1
0001
0
2.01E+09
-
1
00
19,900 —-
2.50E+05
11.60000
1
0001
0
2.28E+09
-
1
11
22,300
2.50E+05
12.30000
1
0008
+ 1.0
3.00E+09
-
0
99
23,000
3.22E+04
1.68000
1
0004
+ 0.4
9.19E+08
-
0
90
7,120
3.22E+04
1.72000
1
0001
0
1.76E+09
-
0
93
13,900
3.22E+04
1.78000
1
0000
-0.2
1.33E+09
-
0
86
11,200
3.22E+04
2.16000
1
0039
-0.5
1.53E+08
-
0
90
1,590
3.22E+04
2.74000
1
0003
+0.2
7.13E+08
-
0
93
8,900
1.33E+05
20.20000
0
9991
-2.1
1.80E+08
-
0
89
2 , 400
5.26E+04
10.10000
1
0004
0
8.88E+08
-
0
95
9,670 y
1.33E+05
20.10000
3
&
AA

frO
Page 1 of 2
Printed: 8/5/2Q0a 2:2? PM
-------
Datafile: e: 080729V27
Client ID: Run# II-ACD-M23-2
Lab ID: P9464 6042 PAH 006
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
PAH Ax
1,0
-2.1
ES/SS
4.8
-1.6
Name
Actual
ST
prea
RRT
l3C6-Naphthalene
13 C6- 2-Methylnaphtha i cno
13G6-Acanaphthy1ene
13C6-Acenaphthene
13C6-Fluorene
13C6 -Phenanthrene
13C6-Anthracene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a)Anthracene
13C6-Chrysene
13C6-Benzo (b) Fluoranthene
13C6-Benzo(k)Fluoranthene
13 C4-Benzo(e)Pyrene
13C, -Benzo (a) Pyrene
dl2-Perylene
13C6-Indeno(1.2,3-cd)Pyrene
13C6-Dibenzo(ah)Anthracene
13C12-Benzo(
-------
AP Lab ID: P9464_6042_PAH_006
Instr: AutoSpec-Prernier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 78
Acq: 30-Jul-2008 03:02:34
User: CEM Datafile: 080729V27
Rel. Int.
100%
Fn 1
130,9920
QC Check
7.02-10.55
Abs. Int.
- 3.53e7
l.77e7
O.OOeO
| > I T 1 |
10.5 RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
1 I 1 t I I i I I I I I I I I I
j—j—j
15.0
0% 111!
Abs. Int.
-4.35e7
2.17e7
O.OOeO
17.0 RT
Rel. Int.
100%-,
Fn 3
218.9856
QC Check
17 02-23.01
0%-
18.0
19.0
20.0
21.0
22.0
Abs. Int.
r2.35e7
•1.18e7
-O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23,02-35.01
0%-
24.0
26.0
28,0
30.0
1 | 1 I I
32.0
34.0
i—i—.—.—(- 0, OOeO
RT
Abs, Int.
-1,81e7
9.06e6
Res Ms: P:\P94O0_P9499\P9464_6O42 PAH\resource$\P9464_6042_PAH_006Mtp_res, saved 01-Aug-2003 13:27 (CM)
AP UltraTrace-Pm V3.9S2 User/System CMJCMP4-01S sex: 048-005
Peak annotation: Areas, Centroids
PKD: n/a Printed: 01~Aug~2Q0B 14:15:20 Page 1 of 9
-------
AP Lab ID: P9464_6042_PAH_006
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn1 100%-
128.0626
Analyte
4o 1.41e6
8.40-10.20
Rel. Int.
Pni 100%-
134.0827
Standard
4o 3.92e3
8.40-10.20
Naphthalene
s.51e9
8.60
ES-Naphthalene
4.!7e6
8.61
0%-

; ' r "I "¦ t" i t -T
86
Rel. Int.
Fn1 100%-
142.0783
Analyte
4o 1,73e4
8.40-10.20
0%-
Rel. Int.
Fn 1 100%
148,0984
Standard
4a 3.24e3
8.40-10,20
0%-
Rel. Int.
Fn 1 100%-
152.1410
Standard
4o 2.87e3
8.40-10.20
0%-
8.6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 78
Acq: 30-Jul-2008 03:02:34
User: CEM Datafile: 080729V27
Int
1.07S
5.37e8
O.OOeO
10,2 RT
Abs. Int.
-1,37e6
-6.83e5

8.8
I "i i i i | i i i i | i i i i | i
9.0	9.2
¦ i ¦
9.4
8.8
9.0
¦ i ¦
9.2
9.4

i i I i i i i I i inr| ' ' 1
9.6	9.8 ,
2-Metfiylnaphthalene
3.0ie9 /
9.75 '

^	I"''
10.0
	I O.OOeO
10.2 RT
Abs I
r
9.6
| e I I I 'l [ I
10.0
ES-2-Methylnaphtha
2.24e6
9.75
I i" "I f '"f',""i' i i t" i i i fn-1" i | i i t i | i i i i |
9,2	9.4	9.6

I I I I I I I I
10.0
JS-Methylnaphthale
2.97©6
9.68
9.0
¦ i ¦
9.2
• i ¦
9.4
96
< T '
10.0
5.37e8
O.OOeO
10.2 RT
Abs. Int.
-1,32e6
6.62e5
O.OOeO
10,2 RT
Abs. Int.
-2,10e6
¦1.05e6
•O.OOeO
10.2 RT
Rel. Int.
pn ^ 100%'
130.9920
QC Check
8.40-10.20 '
Results: P:V*9400_P9499\P9464_6042 PAH\resources\P9464_6O42_PAH_006 utp_res. saved 01-Aug-2008 13:27 (CM}
AP UlimTrace-Pm V3 992 User/System: CM/CMP4-015 ce: 5498, ~1B?6, 4968, 2166, 5083 see: 048-005
Abs. Int.
-3,53e7
1.7767
O.OOeO
Revised: Q1-Aug-2008 13:19:19 (CM)
10.2 RT
Peak annotation: Areas, Centmids
Printed: 01-Atsg-2Q08 14:15:31 Page 2 of
-------
AP Lab ID; P9464_6042_PAH_006
Instr: AutoSpec-Premier MM6
Acenaphthytene
Rel. Int.
Fn2 100%-q	1155
152.0636
Analyte
4o 2.12e6
11.50-12 30
0%-
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial:
78
Acq: 30-Jul-2008 03:02:34
User: CEM Dataflle: 080729V27
Abs-int.
-1.07e9
11.5	11.6
ES-AcenaphUiylerte
Rel. Int.	3,'«e6
pn 2 100%- 1158
158.0827
Standard
4o 7,41 e3
11,50-12.30 }
I
11.7
11.
—i—i—|—r*"i—i—I—j~
11.9
T-y-r-
12.0
i t | I I * f | I r i ¦T |
12.1
T
12,2
-5.37e8
¦ . f O.OOeO
12.3RT
0%-
11.5
Rel. Int.
Fn2 100%-
154.0783
Analyte
4er 6.99e5
11.50-12.30
0%
11.5
Rel. Int.
Fn2 100%-
160.0984
Standard
4o 7.42e3
11.50-12.30
Rel. Int.
Fn 2 100%
164,1410
Standard
4 o 4.70e3
11 50-12 30 ^
T"11-
11.7
11.8
11.6
I | I i I I
11.7
11.8
Acenaphtnene
I.39e9
II.89
Abs. Int.
-1 ,88e6
9.42e5
12.0
12.1
12.2
-i—i—r—O.OOeO
12.3RT
Abs. Int.
9.06e8
¦4.53e8
IJI111
12.0
	'	1 I
12,1
' I 1
12.2
ES-Acenaphthene
2,64e6
11.89
l l | l l l i—|—i—i—i—i—|—i—!—I—I—|—i—i—r—i—f
11.7	11.8
JS-Arenaphthene
f
j ii i i" [ i
11,9

12,0
12.1
	1	| I—I—I—!—|	1 1
11.7
-i—i—i i " | i i i i | i
11.8	11.9
-I—I—i—J—1—r
12,0
' ''	) 1 '
'	I	
12,1
—!—I—|—T-
12.2
-I-"-
- O.OOeO
12.3 RT
Abs. Int.
1.75e6
¦8.73e5
~l—r-i—i—i—|—i—i—i i | i—i * i 0. OOeO
12.2	12.3 RT
Abs. Int.
1,96e6
-9.81 e5
-O.OOeO
12.3RT
Rel, Int.
Fn 2 100%
168.9888
QC Check ¦
11.50-12.30
o%-V
11.5
11.6
11.7
11.8
11.9
Results: P:\P84W_P9499\P9464__6042 PAHte$owtes\P9464_6042_PAH_006.utp_res. saved 01-Aug-2008 13:27 (CM)
AP t/flra Trace-Pro V3.992 UserfSystem: CM/CMP4-015 cc: 0755, 0373, 0397, 6046, 4797 see: 048-005
12.0
Revised:
1 t I 1 | I
12.1
¦""1"
12.2
"¦¦r	i	j	t	%	%	r"
Abs, Int.
-4.29e7
¦2,15e7
¦O.OOeO
12.3RT
Peak annotation: Areas. Centrokls
01-Aug-2008 13:26:20 (CM) Printed: 0l-Aug-2008 14:15:42 Page 3 of 9
-------
AP Lab ID: P9464_6042_PAH_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 78
Rel. Int.
100%
Fn 2
166-0783
Analyte
4o 9.17e5
12.70-16.50 -
0%-
Fluorene
2.80e9
13.02
UJ
Acq: 30-Jul-2008 03:02:34
User: CEM Datafile: 080729V27
Absr-fnt.-
S'
t

Re!. Int.
100%-
Fn 2
172.0984
Standard
4o 5.89e3
12.70-16.50
13.0
ES-Fluorerie
2.l7e6
13.01
13.5
1 I ¦
14.0
' 1 '
14.5

15.0
15.5
16.0
lit!
•5.37e8
0% t-Y-f~r-rV|M
13.0	13.5	14.0	14.5
i i i I i i i i
15.0
| [ | | !¦ | f | |
15.
i i i i i i
•O.OOeO
RT
Abs. Int.
-1.19e6
•5.94e5
Rel. Int.
100%-
Fn 2
178.0783
Analyte
4a 2.74e4
12.70-16,50
0%-
Phenantnrene
4.87e9
15.25
16.0
•O.OOeO
RT
rA-
/\

13.0
1—i—t ; i—|—r-
13.5
.A,
l—I 	|—r—1—r"*l—I—I—I t I
14.0
i—i—, \,	i
14.5
i i i" i T '—r-"t-
15.0
1—I—iT^'fl * | 'I
15.5
•5.37e8
O.OOeO
"I ' j'" 'I	I' I—1—|—*—I T - I
16.0	RT
Rel. Int.
100%-
Fn 2
184.0984
Standard
4o 4.92e3
12,70-16.50
ES-Anthracene
3.S5e6
15.37
ES-Phenanthr^ie
3.76e6
15.26
0% | i	¦T" I 'i ' |'"""" i I i ¦»	|	I	 ft	i |" i 		I i |—r-
13,0	13.5
14.0

14,5
15.0
15,5
Abs. Int.
-2.12e6
1,06e6
16.0
-O.OOeO
RT
Rel, Int.
100%
Fn 2
168,9888
QC Check J
12.70-16.50
0%-
' I '
13.0
11 I '
13.5
1 I 1
14.0
' I '
14,5
15.0
' I '
15.5
16.0
Abs. Int.
-4.35e7
-2.17e7
I i i i i O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\m$Ources\P9464_6042_PAH_a0S.utp_re$, saved 01-Aug-2008 13:27 (CM)
AP UltraTrsce-Pm V3.992 User/System: CWCMP4-015 cc: 4416, 2705, 7005. 5679 sec: 048-005
Peak annotation: Areas, Centmids
Revised: 01-Aug-2008 13:26:25 (CM} Printed: 01-Aug-200S 14:15:54 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_006
Instr: AutoSpec-Premier MM6
Rel. Int.
100%'
Fn 2
176.1410
Standard
4o5 32e3
12.00-16.50
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 78
SS-Fluorene
2.81 e6
12.94
Acq: 30-Jul-2008 03:02:34
User: OEM Datafile: 080729V27
Abs. Int.
-1 86e6
-9.29e5
I.OOeO
Rel. Int.
100%T
Fn 2
188.1410
Standard
4a 5.98e3
12.00-16.50
AS-Anthracene
2.69e6
15.32
~l i '11 l ~ " I 'l |"' I T'l 1)11
13.5	14.0
Abs. Int.
-1.78e6
¦8.90e5
•O.OOeO
RT
Rel. Int.	Abs. Int.
100%-,
Fn 2
1 @6.9888
QC Check
12.00-16.50
-2.17e7
0%
O.OOeO
RT
12.0
12.5
13.0
13.5
16.0
14.0
14.5
15.0
15.5
Results: P:\P9400_P9499\P9464_6042 PAHteSOumesW464_6042_PAHj00eMtp_ms. saved 01-Aug-200B 13:27 (CM)	Peak annotation: Areas. Centmids
AP Ultra Trace-Pro V3.992 User/System: CWCMP4-OI5 cc: 5894. 0040 sec: 048-005	Revised: 01-Aug-2008 13:26:49 (CM) Printed: 01-Aug-2008 14:16:05 Page 5 of 9
-------
[
AP Lab ID: P9464_6042_PAH_006	/
Instr: AutoSpec-Premier MM6 /	'
Rel. Int.
Fn 3 100%-
202.0783
Analyte
4o 8.65e5
17.50-22.50 ;
0%-
A,
F uoran
18.13
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Viaf: 78
Pyrene
3.54e9
18,68
19.0
20.0
"i	r	riM
¦¦¦¦r	*	"fr	i	i	r	rm
21.0
Rel. Int.
Fn 3 100%-
208,0984
Standard
4o 8,44e3
17.50-22.50
0%-
6S-Fluoranthene
4,43e6
18,13
Acq: 30-Ju!-2008 03:02:34
User: CEM Datafile: 080729V27
Absr-lnt-
1,07e9-
-5,37e8
-O.OOeO
RT
Abs. Int.
-2,07e6
-1.03e6
""I	t	I	I	V"
22.0
III0*"
Rel. Int.
Fn 3 100%-
205.0883
Standard
4o1.83e4
17.50-22.50
0%-
Rel. Int.
Fn 3 100%.
228.0939
Analyte
40 2.50e5
17.50-22.50
0%-
Rel. Int.
Fn 3 100%1
234.1140
Standard
4o4,07e3
17.50-22.50
0%-
—r
18.0

1—1—I—
19.0
—I—
20,0
¦i i i I i
	'		r	
21.0
i " i i i | r1" T' ¦
I J
22.0
ES-Pyrene
1.4097
18.68
19.0
				 "i	•
20.0

jL
21.0
5.01 e8
21.06
18.0
—I—
19,0
'I 'T"
A
20.0
21.0
BenzfaiAnthracene
21.61
22.0
ES-Benzg|An1hrace
21.61
18.0
\ ' I "T" I
1.24e6
19.36
A.
j T"	T'"»,rK	»"i" 'I - 			
19.0
20,0
21.0
22.0
—«-O.OOeO
RT
Abs. Int.
-5.68e6
¦2.84e6
¦O.OOeO
RT
Abs. tnt.
-1 05e9
•5,23e8
-O.OOeO
RT
Abs. Int.
-2 18e6
1.09e6
¦O.OOeO
RT
Rel. Int.
Fn 3 100%
218.9856
QC Check
17.50-22.50
Abs. Int.
2.32e7
1.16e7
O.OOeO
RT
Results: P:\PS400_P94m\P9464_6042 PAHVesources\P94S4_B042_PAH_008.utp__res, saved 01-Aug-2008 13:27 (CM)
AP UltraTrac#-Pro V3 992 User/System CM/CMP4-015 cc: 1418, 7302. 6724. 4051, 5565 see 048-005
Peak annotation: Areas, Centmids /
Revised: 01-Aug-2608 13:26:32 (CM) Printed: Ot-Asjg-2008 14:18:17 Page 8 of 9 /
-------
AP Lab ID: P9464 6042_PAH_006
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-,
Fn 3
212.1410
Standard
4 o 6,01 e3
18,00-20.00
Rel. Int.
100%-
Fn 3
244.1974
Standard
4o 3.92e3
18.00-20.00 i
18.2
18.4
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 78
JS-Pyrene
4.11e6
18.63
186
18.8
19.0
SS-Terphenyl
2.74e6
1S.02
Acq: 30-Jul-2008 03:02:34
User: CEM Dataflle: 080729V27
Abs. Int.
-2 27e6
0% ] I I I |*i (I" ¦ | I i I I | » )"T""I i i i i |
¦ 1.14ei
¦¦ |	|..=- i|i"n |n"|-{"i! > "V" i "j I II I11"!1 i'-> '"I | I i I "I"'[ 'i "'I "I1" I | ¦ "I1 I1111!11" O.OQeO
19.2	19.4	19 6	19.8	RT
Abs. frit.
1.93e6
18.2
18.4
18.6
( T1*! f f [' i i i i | i i i r
18.8	19.0
"'I T | I I I I |
19.2
i I i i i i I i i i i |1
19.4	19.8
I ' 1 1 1 I ' 1 ' 1
19.8
-9.64e5
ii1' O.OOeO
RT
Rel. Int.	Abs. Int.
100%-i
Fn 3
218.9856
QC Check
18.00-20.00
O.OOeO
RT
16.2
18.4
18,6
18.8
19.0
19.2
19.6
19.4
Results: P. \P9400_P9499W9464_6042 PAHSresourte$\P9464_6042_PAH^006.utp_re$. saved 01-Aug-2008 13:27 (CM)	Peak annotation: Areas, Centroids /
AP U/fra Trace-Pro V3.992 UserfSystem:.CM/CMP4-015 oc: 0346, 0746 see: 04S-005	Revised: 01-Aug-200S 13:19:38 (CMj Printed: 01-Aug-2008 14:16:28 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH_006
Instr: AutoSpec-Premier MM6
Rel. Int.
100%>
Fn 4
252.0939
Analyte
4a 3.22e4
23.50-28.00
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 78
o%-
Benz(b) Fl uoranthene
3.00e9
24.92,
Hy f/
Benzjl Fluoranthene
1.19e8,
?5.0V
' 24.0	" 24.5 '
A-
Benz(e)^Pyrerte /
25.94 / /
' Benz i 1*7 I'ltp-pin |I—T t»T"i I 1 rTl fl-i-1 i I I	t i i I I i I I i
I I T""i I I I I ] I
Rel. Int.
100%-
Fn 4
264.1692
Standard
4o 3.79e3
23.50-28.00
0%-
24.0
24.0
24.5
25.0
25.5
26.0
26.5
ES-Perylene
8.51e6
26.38
27.0
JS-Benz(a)Pyrene
4.37@6
26.06
24.5
'	I	,	
25.0
-i—i—i—|—r-
24,0
ES-Benz(b)Fluorani
1,Q6e7
24.90 ,
/ V L
i i i i i T*
i	>""i f i t i | i
25.5
25.5
26.0
26.5
27.0
	y""»	i	i""
27.5
27.5
Abs. Int.
-4.19e6
•2 09e6
27.5
-O.OOeO
RT
Abs, Int.
-3.90e6
• 1,95e6
¦O.OOeO
RT
Abs. Int.
-2,61e6
1.31e6
-i—i—r-i—'—O.OOeO
RT
Rel. Int.
100%
Fn 4
292.9824
QC Check
23.50-28.00
0%-
24.0
24.5
25.0
I I | I
25.5
	T""1	T	»	
26.0
26 5
27,0
27.5
Abs. Int.
1.76e7
-8.79e6
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464M6042 PAH\fBSOumes\P9464_6Q42_PAHJ)06Mtp_reS. saved 01-Aug-2008 13:27 (CM}
AP UltraTrace-Pro V3 992 User/System CM/CMP4-01S ce: 4196~1G47.~0694. 089T see: 048-005
Peak annotation: Areas, Centmids
Revised: 01-Aug-2008 13:24:15 (CM) Printed: Q1-Aug-2008 14:16:39 Page Bo(9
-------
AP Lab ID: P9464_6042..PAH_006
Instr: AutoSpec-Premier MM6
Rel, Int.
Fn 4 100%
276.0939
Arialyte
4o 1,33e5
29,0-36,0
0%-
Sample ID: Run# II-ACD-M23-2
VSIR expl: pah_db5_Q801 GC: pah_db5-SPLT5 Viai: 78
lnd(l23-cd)Pyrene
7.13e8
31.65
29,0
-Pp**-
30-0
31,0
Rel. Int.
pn4 100%-
282,1140
Standard
4o 5.69e3
29.0-36,0
Q%-
'iii>""mr	i	i""
I l ' 1 —!
29,0
30.0
31.64
33,28
Acq: 30-Jul-2008 03:02:34
User: CEM Datafile: 080729V27
Abs, Int.
1.59e8
-7.95e7
* » * f I 1 f
33.0
34.0
35.0
t j i ; i f«f
31.0
32,0
i i ¦ [ "I i
Rel, Int.
Fn 4 100%-
288,1342
Standard
4o2,73e3
29,0-36.0
0%-
33.0
ES--Benz(ghi)Peryl
7.76e6
33.27
34.0
l l |—r-
29,0
	I
30.0
31,0
~l
33.0
34.0
35,0
Rel. Int.
4 100%-
278,1096
Analyte
4o 5 26e4
29 0-36.0
Rel, Int.
pn4 100%-
284 1297
Standard
40 4.67e3
29.0-36.0
DibenzfahJAntfirace
1.80e8f
31.78/
ES-Oibenz(ah)Ar,ihr
6 72eS
31.81
0%-
29.0
I '' 1 1	'' I
30.0
•O.OOeO
36.0RT
Abs. Int.
1 44e6
• 7.18e5
O.OOeO
¦f'""*		i		j—r^—r—r*
35,0	36.0 RT
¦i-'i—T' v t—» \ — f-n i i
31.0	32.0
~"| ""1 I -T'T [' I* "»"T'
33.0	34.0
Abs, Int.
-1.41e6
¦7 06e5
¦O.OOeO
36,0 RT
Abs, Int.
-2.23e7
1,11e7
O.OOeO
36.0RT
Abs, Int.
-1,19e6
•5.93e5
1 I I I
¦O.OOeO
35.0
36.0 RT
Rel. Int.
Fn 4 100%-
292.9824
QC Check
29.0-36.0
0%-
29,0
30.0
• I • »
31.0
32 0
1 I ¦ ¦ » ' I 1 1 1 1 I 1 ' ' ' I '
33.0	34.0
35,0
Abs. Int.
-1,81e7
-9,06e6
¦O.OOeO
36.0 RT
Results: P:\P9400_P9499\P9464_6042 PAH\resaume$\P9464_6(M2_PAH_006.utp_re$. saved 0)-Aug-2008 13:27 (CM)
AP UltmTrace-Pro V3.992 User/System: CM/CMP4-01S cc 3306, 6772, 4929, 1406, 4S1S see: 048-005
Revised 01-Aug-20Q8 13:26:04 (CM)
Peak annotation: Areas, Centroids
Printed: 01-Aug-2008 14:16:51 Page 9 of 9
-------
Datafile: e: 080730V18
Acquired: 30 Jul 2008 20:35:33
Client ID: Run# II-ACD-M23-2
Lab ID: P9464 6042 PAH 006-SPLS00

Wt/Vol: 1 Train
J Level: 4
ng/Trairr^


ICAL: MM6_PAH_080118_18JAN08
Nominal ES spike: 40 ng
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
Name
f Naphthalene
2 -Methylnaphthalene
yt Acenaphthyl ene
Acenaphthene
-/ Fluorene
•f Phenanthrene
if Anthracene
Fluoranthene
4 Pyrene
Benzo{a)Anthracene
Chrysene
Benzo(b)Fluoranthene
Benzo(k)Fluoranthene
Benzo(e)Pyrene
Benzo(a)Pyrene
Perylene
Indeno(1,2,3-cd)Pyrene
Dibenzo(a,h)Anthracene
Benzo(ghi)Perylene
PAH Ax
2.8
-0.5
Actual
ST
8.56/
9.75 //
11.55/
11.91 /
13.02 '/*
15.25 X
15.38 S
18.13/*
18.68/
21.62/
21.73 /
24 .93
25.04//
25.96 /
26.19 ^
/
31.70 -X
31.80 X
33 .32 /"
QC
ES/SS
3.8
-0.9
Fred
Actual
\h^
¦fijs/
OA*
1 Qbif K. H
1

y
Dif£
Checkcode;
Cone
or
/
RRT
RRT
Sees
Response
Ea
RRF
ng/Train
Noise

DI<
1.0005
0.9996
-0.5
1.49E+09
-
1
09"
444,0OO4f
5.15E+04
54
10000
1.0003
1.0003
1.0002
1.0001
-0.1
-0.1
1.41E+08
2.42E+08
-
1
0
11
86
114,000 "}r SJ30E+Q3
188, 000 4c 4Ke+04
17
70
30000
50000
1.0003
1.0005
+0.1
1.55E+07
-
1
00
20,S00£^f
1.62E+04
74
30000
1.0004
1.0004
0
5.14E+07
-
1.05
/69,100 ^®<«illl_06E+04
54
60000
1.0003
1.0001
-0.2
3.90E+08
-
1.12
189, 000 JC.
4.92E+03
10
10000
1.0003
1.0003
0
5.35E+07
-
1
09
54,400
4.92E+03
21
10000
1.0001
1.0003
+0.2
1.30E+08
-
1
02
82,600 4-
1.20E+04
30
50000
1.0001
1.0004
+0.3
1.01E+08
-
1
03
25,100 +
1.20E+04
14
60000
1.0001
1.0003
+0.3
1.14E+07
-
1
00
18,500
4.10E+03
35
50000
0.9998
1.0005
+0.9
1.92E+07
-
1
11
30,600
4.10E+03
38
60000
1.0002
1.0008
+0.9
1.15E+07
-
0
99
22,900
3 . 842-03
40
00000
1.0003
1.0015
+1.8
7.00E+06
-
0
90
12,000
3.84E+Q3
59
20000
1.0000
1.0005
+0.8
9.27E+06
-
0
93
16,200
3 . 84E+03
61
60000
0.9997
1.0015
+2.8
6.22E+06
-
0
86
15,500
3 -84E+03
93
90000
1.0044
-

-
-
0
90
ND
3.84E+03
70
40000
1.0002
0.0000

2.69E+06
-
0
93
#VALUE!
3.85E+03
fVALUE 1
0.9989
0.0000

5.52E+05
-
0
89
((VALUE !
3.37E+03
#VALUE!(
1.0004
0.0000

3.77E+06
-
0
95
fVALUE!
3.85E+03
# VALUE!
Analytical Perspectives
Page 1 of 2
Printed: 8/5/2008 2:27 PM
-------
Datafile: e: 080730V18

Client ID: Run# II-ACO-M23-2

1
O


Lab ID: P9464_
6042_PAH
_006-SPL500


Stats

PAH Ax
ES/SS


Largest ~ ve RT shift
(sees)

2.8
3.8


Largest -ve RT shift
(sees)

-0.5
-0.9

y


Actual

Pred
Actual
/
Biff
Name

RT

MR?
RRT
Sees
13C6-Naphthalene

8.57

0.8855
0.8844
-0,6
13C6-2-Methylnaphthalene

9.75

1.0063
1.0064
+0,1
13C6-Acenaphthylene

11.55

0.9757
0.9759
+0.1
13 C6-Acenaphthene

11.90

1.0059
1.0056
-0.2
i 3C6 -Fluorer.e

13.02

1.1003
1.1003
0
13 C6-Phenanthrene

15.25

1.2892
1.2888
-0.3
13C6-Anthracene

15.37

1.2995
1.2989
-0.4
13C6-Fluoranthene

18.12

0.9725
0.9724
-0.1
13C3-Pyrene-

18.68

1.0025
1.0022
-0.3
13C6-Be»zo(a)Anthracene

21.61

1.1602
1.1598
-0.4
13C6-Chrysene

21.72

1.1663
1.1657
-0.7
13C6-Benzo(b)Fluoranthene

24.91

0.9557
0.9561
+ 0.6
13C6~Benzcr(k)Fluoranthene

25.01

0.9604
0,9600
-0.6
13C4-Benzo(e)Pyrene

25.95

0.9958
0.9961
+ 0.5
13C4-Benzo(a)Pyrene

26.15

1.0046
1.0040
-0.9
dl2-Perylene

26.37

1.0127
1.0124
-0.5
13C6-Indeno(1,2,3-cd)Pyrene

0.00

1.2144
0.0000

13C6-Dibenzo{ah I Anthracene

0.00

1.2235
0.0000

13C12-Benzo(ghi> Perylene

0.00

1.2772
0.0000

AS—Anthracene

15.32

1.2897
1.2951
+ 3.8
SS-Fluorene

12.95

0.9949
0.9951
+0.2
SS-Terphenyl

19.04

1,0507
1.0505
-0.2
JS-Methyl naphthalene

9.68


_
_
JS~Acenaphthene

11.83

-
-
-
JS-Pyrene

18.63

-
-
-
JS-Ben?.o (al Pyrene

26.05

-
-
-
Analytical Perspectives
Page 2 of 2
ICAL: MM6_PAH_080118_18JAN08
Response
Ra
BXF
/
Recv.
1.23E+05
-
1.51
244
0*""
4.44E+04
-
0.96
139
0
6.O0E+O4
-
1.79
128
0 /
2.985-04
-
1.06
107
0
2.822-04
-
1.11
97
3
7.38E+04
-
1.76
160
ox
3.62E+04
-
1.64
84
6
6.17E+04
-
1.25
130
°/
0 7
1.57E+05
-
1.30
318
2.47E+04
-
1.06
61
4
2.25E+04
-
1.02
58
4
4.08E+04
-
1.21
109
0
5.21E+04
-
1.60
105
0
4.91E+04
-
1.30
122
0
3.72E+04
-
1.39
86
1
2.97E+04
-
1.36
70
5
0.OOE+OO
-
0.81

-
O.OOE+OO
-
1.00

-
0.OOE+OO
-
1.15

-
1.74E+04
-
y
1.44
46
4
3.03E+04
_
0.96 /
112
0
2.02E+04
-
0.54
61
3
3.34E+04
2.62E+04
3.80E+04
1.55E+04
Printed: 8/5/2008 2:27 PM
-------
AP Lab ID; P9464_6042_PAH_006-SPL500
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5J)801 GC: pah_db5-SPLT50Q Vial: 78
Acq: 30-JuI-2008 20:35:33
User: CEM Datafile: 080730V18
Rel, Int.
100%-
Fn 1
130.9920
QC Check
7.02-10.55
0%
7.5
¦-1-1
8.0
I I I I
I I I | I I I I
8.5
I T I !
| I I I I | I I I I | I I I I | f I I I j I
9.0	9.5	10.0
Abs. Int.
-6.17e7
3.08e7
¦OOOeO
10.5 RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
10.59-17.00
r
16.0
Abs. Int.
7,56e7
3,78e7
t i 0. OOeO
17.0RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.01
0%-l—i—i—t—i—|—i—t—i—r"1 |M
18.0
I I I r I I I I I 1 T | I 1 I I ( I I I I | f I I T | T
19.0	20.0	21.0
22.0
Abs. Int.
-4.00e7
-2.00e7
-O.OOeO
23.0 RT
Rel. Int.
100%-
Abs. Int.
-3.2le7
Fn 4
292.9824
QC Check
23.02-35.01"
-1,6167
0%-
'"I	T	I	J	T	1	T,M
24.0
~1 r"
' I '
28.0
t > |	f
34.0
-O.OOeO
RT
26.0
30.0
32.0
Results: P:\P9400_P9499\P9464_6042 PAHte$Oume$\P9464_6042_PAH_Q06-SPLS00.utp_ms, saved 31-Jul-200B 16:03 (CM!
AP UltraTfBce-Pm V3.992 User/System: CM/CMP4-015 see. 736-857
Peak annotation: Areas. Centroids
PKD: n/a Printed 31-Jul-2008 16:45:00 Page 1 of 9
-------
AP Lab ID: P9464_6042_PAH_006-SPL500
Instr; AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT50Q Vial: 78
Rel. Int.
Fn1 100%-
128,0626
Analyte
4o 5.15e4
8.40-10.20
0%-
Rel. Int,
Fn 1 100%-]
134.0827
Standard
4o 1.59e3
8.40-10.20
0%-
Rel, Int.
pn 1 100%-
142.0783
Analyte
4a 5 80e3
8.40-10.20
0%-
Rel. Int.
Fn1 100%-
148.0984
Standard
4ol.02e3
8.40-10.20
0%-
Rel. Int.
Fn 1 100%
152.1410
Standard
4o 9.48e2
8.40-10 20 :
0%-
Naphthalene
I.49e9
8.56
Acq: 30-Ju1-2008 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
-1.06e9
8.6
ES-Naphthalene
1,23e5
8.57
]—i—'—i—i—|—i—i—i—i'| i—i—t—i—|—i—i—i—r—|—i—i—i—r-|—i—i—r-i—]—i—i—I—i—|—i—r—i—i—p—i—i i i—p
8.8	9.0	9,2	9.4	9.6
¦ i ¦
9.8
i ¦ • ¦ ¦ i ¦
10.0
5.31e8
O.OOeO
Tp
8.6
¦ i ¦
8.8
-i—i—r—'—r-
9.0
—|—i—i—i—i—|—i—i—i—i—[¦—i—i—i—i—[—i—i—i—r—|—I—r—r-r—j—r
9.2	9.4	9.6
Hr
¦ i ¦
9.8
2-Methylnaphthalene
i.41eB
9.75
8.6
	I" * ¦ ' ¦ i	
8.8
i i i i i i i i i i i y i r i
9.0
9.2
9.4
9.6
ES-2-Methyi naphtha
4.44e4
9.75
,-rr
8.6
1—|—i i i—i | *
8.8
"l—1 r
9.0
T~r
9.2
9.4
9.6
JS44ethvlnapht}iale
3.34e4
9.68
¦ I '
9.8
1 I 1 ' 1 ' I 1 1 1 1 I 1
8.6	8.8
I ' 1 ' ' I ¦ ' ¦ ¦ 1
9,0
I [• » I I I |
9.2
I I | f t I I | T
9.4
I
9.6
T-P"
9.8
1 1 ' 1 ' 1 I
10.0
1 I ' 1 ' 1 I
10.0
10,0
1 I 1
10,0
RT
Abs. im.
-1 05e5
-5.24e4
-O.OOeO
RT
Abs. Int.
-1.09e8
¦5.44e7
-O.OOeO
RT
Abs. Int.
r4,47e4
2,23e4
-O.OOeO
RT
Abs. Int.
- 3 86e4
¦1.93e4
¦O.OOeO
RT
Rel. Int.
Fn t 100%-
130.9920
QC Check
8.40-10.20
Abs. Int.
-6 17e7
-3 08e7
0%-
I I I I I 1
8.6
8.8
	r	^,,MT		t,m
9.0
9.2
t | I < I I | I I I f | I I '"^""1 'T
94	9.6
9.8
10.0
-rJ-Q.QOeO
RT
Rasults: P:iP940ff_P949SIPS464_6042 PAHVesources\P9464_6042_PAH_006-SPL500.utp_res, saved 31-Jul-2008 16:03 fCMJ	Peak annotation: Areas. Centfoids
AP UttraTrace-Pro V39S2 User/System: CM/CMP4-01S cr: 7614. 4203. 6678. 7752. 3259 see: 736-857	Revised: 31~Jut-2008 16:02:18 (CM) Printed: 31-M-2008 16:45:09 Page 2 of 9
-------
AP Lab ID: P9464_6042_PAH_006-SPL500
Instr; AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt; pah_db5_0801 GC: pah_db5-SPLT500 Vial: 78
Rel. Int.
Fn 2
152.0636
Analyte
4o 2 43e4
11.50-12.30 ;
0%-
Acenaphthyli
2.42e8
11.55
Acq: 30-Jul-2008 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
-1,72e8
11.5	11.6
ES-Acenaphthylene
11.7
I | I I 1 t | T 1 % I
11.8
11,9
8.60e7
O.OOeO
¦¦"I	r	>¦	»	i	j	i1	i	i	t	i1	t	i	»	r	'|	i	i	t	r	|	t	t	t	i	f	i	r	i	i	f	y	r	i	r
12.0	12.1	12.2	12.3RT
Re!. Int.
Fn 2 100%-
158.0827
Standard
4ci1.19e3
11.50-12.30
11.55
Rei. Int.
Fn 2 100%-
154.0783
Analyte
4o 1 62e4
11.50-12.30
0%-
11.5
¦wp
Rel. Int.
Fn2 100%-
160.0984
Standard
4o 1,56e3
11.50-12.30
0%-
11.5
Rel. Int.
Fn 2 100%-
164,1410
Standard
4o9 68e2
11.50-12,30
0%-
r-^
11.5
11.6
1 I 1
11.7
11.8
11.9
Acenaphihene
i.sse7
11,91
12.0
12.1
12.2
I [ I I I I | f I 1 I | t1
11.6	11.7
11.8
11.9
ES-Acenaphthene
2,98e4
11.90
I | I I 1 f | I I I t I1 < I I I |
12.0	12,1
i i | i i i t | i
12,2
' I '
11.6
¦ 1 ' ' i
11,7
¦¦¦»	r	r	'|	r	rw
11.8
11.9
120
12.1
12.2
JS-Acenaphthene
2.62e4
11,03
11.6
11.7
11.8
11.9
T » I T f I
12.0
12.1
12.2
Abs, Int.
-5.28e4
¦2.64 e4
¦O.OOeO
12.3RT
Abs. Int.
-1,06e7
•5.32e6
¦O.OOeO
12.3 RT
Abs. Int.
-3.44e4
1.72e4
•O.OOeO
12.3 RT
Abs. Int.
-2.96e4
1.48e4
¦O.OOeO
12.3RT
Rel. Int.
Fn 2 100%
168,9888
QC Check
11,50-12.30
Abs. Int.
7.37e7
3.68e7
O.OOeO
i 1 ¦ ' ' I ' 1 '
12.2	12.3 RT
Results: P:\P9400_P9499V9464_6042 PAH\resoumes\P9'l64_6042_PAH_006SPL50Q.utp_ms. saved 31-Jul-2008 16:03 (CMJ	Peak annotation: Areas. Centmids
AP UttmTmce-Pro V3.992 User/System: CMCMP4-015 cc: 4173. 6009. B819, 1817, 8809 see: 736-B57	Revised: 31-Jul-2008 16 01:40 (CM) Printed: 31-M-2008 J6;-)5:18 Page 3 of 9
-------
AP Lab ID: P9464_6042_PAH_006-SPL500
Instr: AutoSpec-Premier MM6
Sample ID; Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 78
Rel. Int.
100%-
Fn 2
166.0783
Analyte
4o 1,06e4
12.70-16.50 ]
Fluorene
5.14e7
13.02
0%-

1		—
Acq: 30-Jul-2008 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
-3.33e7
L
Rel. Int.
100%-
Fn 2
172.0964
Standard
4o 1.19e3
12.70-16,50
0%-
13.0
ES-Fluorene
2.82e4
13.02
i |~"i i i	i—f
A-
a\j

13 5
14.0
14.5
15.0
I I I I I I I I I
-1.66e7
15.5
16.0
V f V P | P
13.0
13.5
r i i i | i i > t |
14.0
14,5
I I I I | I t I t j
15.0
Rel. Int.
100%
Fn 2
178.0783
Analyte
4a4 92e3
12.70-16.50 i
Phenanthrsne
3.90ee
15.25
15.5
0%-
tathracene
5.35e7
15.38
' I ' « 1 ' I 1 1 1 1 I ' ' 1 ' 1
13.0	13,5
¦ i ¦
14.0
14,5
1 r i i | i i i
15.0
i
-A-
¦ i «
15.5
Rel. Int.
100%
Fn 2
184.0984
Standard
4a 8.96e2
12.70-16.50
ES-Phenanthrene
7.38e4
15,25
« I I | T
16.0
-O.OOeO
RT
Abs. Int.
-3,53e4
1.76e4
-O.OOeO
RT
Abs. Int.
-2.46e8
1,23e8
i i l i i i i * O.OOeO
16,0	RT
Abs. Int.
5.66e4
2.83e4
Anthracene
3.62e4
15.37
O.OOeO
RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
12.70-16.50
Abs, Int.
7 56e7
3.78e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAtmsoun:es\P9464_6042_PAH_006-SPL500.utp_ms, saved 31-Jul-2008 16:03 (CM)	Peak annotation: Areas, Centroids
AP UltraTmce-Pm V3.992 User/System: CWCMP4-015 cc: 3587, SS34. 4211. 4333 see: 736-857	Revised. 31-Jut-2008 16:02:35 (CM) Printed: 31-M-2008 16:45:27 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_006-SPL500
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 78
Rel, Int.
100%-
Fn 2
176,1410
Standard
4o 1 04e3
12,00-16.50
SS-Fluorene
3.03e4
12.95
Acq: 30-Jul-2008 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
-3.70e4
Rel. Int.
100%
Fn 2
188.1410
Standard
40 1.61e3
12.00-16.50
•1.85e4
t 74e4
15.32
O.OOeO
RT
Abs, Int.
-2 61e4
1.30e4
16.0
-O.OOeO
RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.00-16.50'
0%-
12.0
12.5
13.0
13.5
14.0
14.5
15.0
15.5
16.0
Abs. Int.
-7,56e?
3 78e7
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHVesources\P9464_6042_PAH_006-SPL500.utp_res. saved 31-JU/-2008 16:03 (CM)
AP UltraTmce-Pm V3.992 User/System: CM/CMP4-015 cc: 3658. 8391 see: 736-857
Peak annotation: Areas. Centroids
Revised: 31-Jul-20Q8 16 01.24 (CM) Printed: 31-Jui-2008 16:45:38 Page 5 of 9
-------
AP Lab ID: P9464_6042_PAH_006-SPL
Instr: AutoSpec-Premier MM6
Rel. Int.
Pi^ 3 100%-
202.0783
Arialyte
4o 1.20e4
17.50-22.50
0%-
Rel. Int.
pn g 100%-
208.0984
Standard
4o 4.54e3
17.50-22,50 ;
0%-
Fluorantliene
1.3068
18.13
PL^flC
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah _db5-SPLT500 Vial: 78
Pyrene
I.0le6
16.68
r t i

18.0
ES-Fluoranthene
6.17e4
18.12
18.0
—I—
19.0
19.0
20.0
21.0
Acq: 30-Jul-2008 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
-7.50e7
¦3.75e7
22.0
20.0
21.0
I I t 	1	
22.0
¦T	t	%	t""
-O.OOeO
RT
Abs. Int.
-5.16e4
• 2.58e4
•O.OOeO
RT
Rel. Int.
Fn 3 100%-
205.0883
Standard
4o 2.52e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%
228.0939
Analyte
4o 4.10e3
17.50-22,50 }
0%-
Rel. Int.
Fn 3 100%'
234.1140
Standard
4o 1.50e3
17.50-22.50
0%-
—I—
18.0
18.0
18.0
ES-Pyrene
1,57eS
18.68
19.0
20.0
21.0
22.0
BenzfaJAnthracene
Y\ 4e7,
21.621
1- I	1 t
i r -i
i r i f
JL
19.0
20.0
21.0
22.0
ES-Benz(a)Anthraee
2A7e4
21.61
—[—
19.0
20.0
21.0
—I—
22.0
Abs. Int.
-1.05e5
5.27e4
-O.OOeO
RT
Abs. Int.
-7 06e6
•3 53e6
-O.OOeO
RT
Abs. Int.
-2,42e4
-1.21e4
¦O.OOeO
RT
Rel. Int.
Fn 3 100%
218.9856
QC Check
17.50-22.50
Abs. Int.
4.00e7
2,00e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PA.H\resources\P9464 6042 PAH 006-SPL500.utp res, saved 31-Jul-2008 16:03 (CM)	Peak annotation: Areas. Centroids
AP UttraTmce-Pm V3.992 User/System: CWCMP4-01S cc: 3663, 91S7.~2891, 3208, 3162 see: 736-857	Revised: 31-Jut-2008 16:02:44 (CM) Printed: 31-Jul-2008 16:45:46 Page 6 of 9
-------
AP Lab ID; P9464_6042_PAH_006-SPL500
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-,
Fn 3
212,1410
Standard
4o 2,SSe3
18.00-20.00
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 78
0%-
Rel. Int.
100%-
Fn 3
244.1974
Standard
4o1.21e3
18.00-20.00
Acq: 30-Jul-2008 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
3.85e4
JS-Pvrene
3.80e4
18.63
1 I 1
18.2
r > i r | i i
18.4
18.6
18.8
19.0
SS-Terpheriyl
2.02e4
19.04
19.2
< i i > ¦TTi-r'
t I I I T > I I I 1 t M 1 I I 1 I I
19.'
19.6
0% i i i t | i i i i [ i i
18.2
18.4
i i i i i t i i i i i i i
18.6
18.8
i i i i i i i i i I i i i i I
19.0
' I ' ' ' 1 I ' ' ' ' I '
19.2	19.4
19.6
19.8
1.93e4
¦O.OOeO
RT
Abs. Int.
-2.3464
¦1.17e4
O.OOeO
I i i » i I | i * i i
198	RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
18.00-20.00"
0%-
18.2
I j I I < t | * T
18.4
' T", M"
18.6
18.8	1S.0
19.2
19.4
19.6
19 8
Abs. Int.
-3.96e7
-1.98e7
•O.OOeO
RT
Results: P:\P94W_P9499\P9464_6042 PAHtosoun:es\P9464_6042_PAH_006-SPL500 utp res. saved 31-JUI-2068 16 03 (CM}
AP UltraTmce-Pm V3.992 User/System: CM/CMP4-01S cc: 3357, 3697 sex: 736-857
Peak annotation: Areas, Centmids
Revised: 31-M-2008 16:01 43 (CM} Printed: 3l-Jut-!008 16:45:55 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH_006-SPL500
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 4
252,0939
Analyte
4a 3.84e3
23.50-28.00
Rel. Int.
100%-
Fn 4
258.1140
Standard
4 o 8.29e2
23.50-28.00
Sample ID; Run# II-ACD-M23-2
VSIR expl: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 78
Acq: 30-Jul-2Q08 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
-2 42e6
Benz(b)Fluor8fflhene
I.l5e?
24
Ben"
jFluoranthene
" 00e6
25.04
3.64e6
25.35
I—I—|—I—I—I—!—|
24.0
—t—!—I | ' I' «
25.0	25.5
ES-Benz(b)Fluorant
4.0Se4
24.91
0%-
24.0
24.5
25.0
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o1.23e3
23.50-28.00
0%-
25.5	26.0
ES-Benz(e)Pyrene
2^-Be3nfm'yrene
26.15
26.5
f | I I I I | I 1 I I | I
27.0	27.5
i y i i i
24.0
| I I
24.5
| t I I I | I
25.0
T-T-
I t | I 1 t 1
25.5
I I I | I I I I
26.0
Rel. Int.
100%
Fn 4
264.1692
Standard
4o l.00e3
23.50-28.00
I 1 t | I
26,5
ES-Perylene
i t i i i
27.0
27,5
1.21e6
O.OOeO
Abs, Int.
-3.13e4
-1 56e4
-O.OOeO
RT
Abs. Int.
r2.53e4
1,26e4
26.37
JS-ienzfalPyrerte
1.55e4
26.05
-O.OOeO
RT
Abs. Int.
-2.38e4
1,19e4
O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28.00
0%-
24,0
24.5
25.0
1 I '
25.5
26,0
26,5
27.0
27.5
Results: P:\P9400_PS49SV9464_6042 PAH\msaufcesV>9464_6Q4Z_PAH_0Q6-SPL5OQ.utp_res. saved 31-Jut-2008 18:03 (CM)	Peak annotation: Areas. Centroids
AP UttrnTmce-PrcT V3.S92 User/System: CM/CMP4-015 cc: am, 7838, 8831, 3658 see: 736-857	Revised- 31-Jut-2008 16:02:52 (CM) Printed: 31-M-20W 16:46:04 Page 8 Of 9
-------
AP Lab ID: P9464_6042_PAH_OG6-SPL500
Instr: AutoSpec-Premier MM6
Rel. Int
Fr, 4 100%-
276.0939
Analyte
4o 3.85e3
29,0-36.0
Sample ID: Run# II-ACD-M23-2
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 78
0%-
lnd(123-cd)Pyfene
2.69e6
31.70
r I |I" "I 1
29.0
Benz(^h||Perylene .
33.32 /
Acq: 30-Jul-2008 20:35:33
User: CEM Datafile: 080730V18
Abs. Int.
-5.04eS
1 J I I I I
2 52e5
¦O.OOeO
33.0
34.0
35.0
36.0 RT
Rel. Int.
Fn 4 100% -
282.1140
Standard
4o 1,71e3
29,0-36.0

0%-
29,0
'"1	1	f	r	r	T	T	T	T	T	T,M
30.0
I | I I I I | I I I I | » t I I
31.0	32 0
I I I [ > I > I | I I
33.0
' I 1 '
34.0
' I ''
35.0
"T	T	T	1	1	1	T"
Abs. Int.
-1.70e4
•8.50e3
O.OOeO
36,0 RT
Rel, Irit,
Fn 4 100% ¦
288.1342
Standard
4o8.14e2
29.0-36.0
0%-
29.0
Rel. Int.
Fn4 100%-q
278.1096
Analyte
4o 3.37e3
29.0-36.0
0%
29.0
30.0
30.0
31.0
31.0
32.0
DibenzfahlAnthrice
5.52e5 J
31.80
"I
33.0
32.0
33.0
34.0
34.0
» | t I I I | t
35.0
35.0
Abs. Int,
-1.85e4
9 27e3
O.OOeO
36.0 RT
Abs. Int.
8.31 e4
4.16e4
-O.OOeO
36.0 RT
Rel. Int,
Fn 4 100%-
284,1297
Standard
4o 8.92e2
29 0-36.0
0%-
29.0
30.0
31.0
32.0
33,0
34.0
35,0
Abs, Int.
-I.47e4
•7 33e3
-O.OOeO
36.0RT
Rel, Int.
Fn 4 100%-
292.9824
QC Check
29.0-36.0
0%-
29.0
30.0
t | l l t l | l i l » [—r
31.0	32.0
33.0
Results- P:\P9400_P9499\P94S4_6042 PAH\mst>vmes\P9464_6O42__PAH_OO&-SPL5O0Mtp_ms, saved 31-Jut-2008 16:03 (CM)
AP UitraTrsce-Pro V3 992 User/System: CM/CMP4-015 cc 5589. ^B64.~3257. 3513. 4017 see 736-857
-t—|—f—i—i—i—j-
34.0
35.0
Abs. Int.
-3.20e7
1 60e7
•O.OOeO
36.0 RT
Peak annotation: Areas, Centrums
Revised: 31-Jul-2008 16:00:55 (CM) Printed: 31-Jul-2008 16:46:14 Page 9 of 9
-------
Datafile: e: 080729V28
Acquired: 30 Jut 2008 03:42:01
Client ID: Run# II-ACD-M23-3
Lab ID: P9464 6042 PAH 007
Stats
Largest •ve RT shift (sees)
Largest -ve RT shift (sees)
Name
f Naphthalene
^ 2-Methylnaphthalene
f Acenaphthylene
Acenaphthene
Jp Fluorene
P Phenanthrene
Anthracene
f Fluoranthene
ft Pyrene
Benzo(a)Anthracene
Chrysene
Benzo(b)Fluoranthene
Benzo fk)Fluoranthene
Benzo(e)Pyrene
Benzo(a)Pyrene
Perylene
Indeno{1,2,3-cd)Pyrene
Dibenzo(a,h)Anthracene
Benzo(ghi)Perylene
PAH Ax
1.0
-2.5
Actual
RT
9.76 f
11. 55-^
11.90 /
13.02 *¦**"
15.26 ^
15.38
18.13/
18. 69/"
21.62 /y
21.72 /
24.93-^" f{U
25.02/
25.95 /"
26.16/
26.49 /
31.66 '
31.79 / ,
33.29 /
QC
ES/SS
4.6
-1.1
Pred
RUT
1.0004
1.0003
1.0003
1.0003
1.0003
1.0002
1.0002
1.0002
1.0001
1.0001
1.0001
1.0001
1.0001
1.0001
1.0001
1.0042
1.0002
1.0002
1.0004
f *

or*

.01
Analytical Perspectives
Wt/Vol: 1 Train
J Level: 4 na/Trair

H*
ICAL: MM6 PAH 080118 18JAN08
Nominal ES spike: 40 ng
Checkcode:


Actual
RRT
0.9986
0.9998
1.0000
1.0003
1.0005
0.9998
0002
0001
0002
0001
0001
0008
0004
1.0001
1.0001
1.0039
1.0002
0.9989
1.0003
Dlff
Sees
Cone
-0
-0
-0
0
+ 0
-0
0
-0
+ 0
0
0
+ 1.0
+ 0.5
0
0
-0.5
0
-2.5
-0.2
Response
5 .25E+09
3.07E+09
3.67E+09
Ra
.01E+09
.79E+09
.69E+Q9
.39E+09
.40E+D9
3.23E+09
1.90E+09
2.18E+09
2.54E+09
7.99E+08
1.08E+09
6.17E+08
4.01E+07
5.13E+08
1.57E+08
4.79E+08
RRF iig/Traj,
1.09
1.11
0.86
1.00
1.05
1.12
09
02
03
00
11
99
0.90
0.93
0.86
0.90
0.93
0.89
0.95
49,500
50,500
48,800
16,600
54,100
50,200
25,500
31,900
10,400
20,300
22,900
20,700
6,500
9,350
5,970
473
6,850
2,120
5,890
/
Noise
61E+06
24E+04
26E+06
75E+05
42E+06
42E+04
42E+04
OlE-t-06
01E+06
18E+05
18E+05
07E+04
07E+04
07E+04
07E+04
07E+04
50E+04
82E+04
50E+04
DL
115.00000
1.81000
150.00000
43.10000
126.00000
2.39000
1.51000
49.20000
19.90000
15.60000
16.60000
2.86000
2.88000
3.03000
4.02000
4.73000
11.10000
10.00000
11.30000
*<¦
<

Page 1 of 2
Printed: 8/5/2008 2:26 PM
-------
Datafile: e: 080729V28
Client ID: Run# II-ACD-M23-3
Lab ID: P9464_6042_PAH_007
Largest +ve RT shift f
Largest -ve RT shift (
Same
13C6-Naphthalene
13C6-2-Methylnaphthalene
13C6-Acenaphthylene
13C6 -Acenaphthene
13C6-Fluorene
13C6-Phenanthrene
13C6-Anthracene
13C6-Fluoranthene
13C3-Pyrene
13C6-Benzo(a)Anthracene
13C6-Chrysene
13C6-Benzo(b)Fluoranthene
13C6-Benzo(k)Fluoranthene
13C4-BenzoIe)Pyrene
13C4-Benzo fa)Pyrene
dl2-Perylene
13c6-Indeno(1,2,3-cd)Pyrene
13c6-Dibenzo(ah!Anthracene
13C12-Benzo(gbi)Perylene
AS—Anthracene
SS-Fluorene
SS-Terphenyl
JS-Methyl r.aph thalene
JS-Acenaphthene
JS-Pyrene
JS-Benzo(at Pyrene
S	PAH Ax ES/SS
) 1.0	4.6
I -2.5	-1.1
Actual	Fred
RT	RHT
8.61	0.8857
9.76	1.0063
11.55	0.9757
11.89	1.0057
13.02	1,1002
15.26	1.2890
15.37	1.2995
18.13	0.9724
18.69	1.0025
21.62	1.1602
21.72	1.1656
24.91	0.9557
25.01	0.9597
25.95	0.9956
26.16	1.0040
26.38	1.0124
31.65	1.2143
31.82	1.2217
33.28	1.2766
15.33	1.2897
12.95	0.9949
19.03	1.0506
9.69
11.82
18.64
26.06
Analytical Perspectives
Wt/Vol: 1 Train
ICAL: MM6 PAH 080118 18JAN08
Actual
EST
0.8886
1.0074
0.9771
1.0060
1.1009
1.2908
1.3001
0.9729
1.0027
1.1600
1.1656
0.9557
0.9597
0.9955
1.0037
1.0123
1.2144
1.2210
1.2767 ¦
1.2962
0.9945
1.0497
Diff
Sees
Response
Ra
+1.
+ 0.
+ 1.
+ 0.
+ 0.
+1.
+ 0.4
+ 0.6
+ 0.2
-0.2
0
0
0
-0.2
-0.
-0.
+ 0.
-1.
+ 0.
+4.6
-0.3
-1.0
.90E+06
.19E+06
.51E+06
.43E+06
.96E+06
.34E+06
.44E+06
.18E+06
.20E+07
.76E+06
.42E+06
.94E+06
.09E+07
9.89E+06
9.58E+06
7.51E+06
6.46E+06
6.63E+06
6.87E+06
1.53E+06
2.41E+06
2.34E+06
tWF
1.51
0.96
1.79
1.06
1.11
1.76
1.64
1.25
1.30
1.06
1.02
1.21
1.60
1.30
1.39
1.36
0.81
1.00
1.15
1.44
0.96
0.54
y
/
Recv.
92.8
/
82
76
89
69
74
82
89
248
95
90
98
82
91
82
66
96
79
71
41
129
105
2.78E+06
2.56E+06
3.74E+06
4.16E+06
Page 2 of 2
Printed: 8/5/2008 2:26 PM
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5.0801 GC; pah_db5-SPLT5 Vial: 79
Acq: 30-Jul-2008 03:42:01
User: GEM Datafile: 080729V28
Rel. Int.
100%-
F n 1
130.9920
QC Check
7.02-10.55
0%-
i i *"11	f	t	r	t	j	i	f	r	*	J-
7.5
'—I—¦
a.o
8.5
9.0
9.5
10,0
Abs. Int.
-3.47e7
-1.73e7
¦O.OOeO
10.5 RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
10.59-17.00
0%-
• I '
11.0
12.0
13.0
14.0
I I | 1
15.0
16.0
Abs, Int.
-4,26e7
¦2,13e7
-i—i i O.OOeO
17.0 RT
Rel. int.
100%-
Fn 3
218.9856
QC Check
17.02-23.00'
0%-
i	i1	r
18.0
19.0
20.0
21.0
22.0
Abs. Int.
-2.27e7
1.13e7
-O.OOeO
23,0 RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01
0%-
24.0
26.0
28,0
30.0
32,0
34 0
Results: P:\P9400_P9499\P9464_6042 PAHSmsouKesV>9464_6042_PAH_M7Mtp_res, saved Ot-Aug-2008 13:34 (CM)
AP UttraTrace-Pm 1/3,992 User/System: CM/CMP4-015 see: 361-909
Abs. Int.
1.71e7
•8.55e6
•O.OOeO
RT
Peak annotation: Areas. Centmids
PKO: n/a Pnnted: OI-Aug-2008 14 J 7 03 Paget of 9
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Rel. Int.
Fnl 100%-
128.0626
Analyte
4o 1.61e6
8.40-10.20
Naphthalene
5,26e9
8.60
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah„db5_0801 GC: pah_db5-SPLT5 Vial: 79
Acq: 30-Jul-2008 03:42:01
User: CEM Datafile: 080729V28
Abs
-1.07e9
¦5.37e8
i.OOeO
Rel. Int.
pni 100%-
134.0827
Standard
4a 3.78e3
8.40-10.20
0%-
Rel. Int.
pn 1 100%-
142.0783
Analyte
4a 2.24e4
8.40-10.20
0%-
ES-Naphthalene
3.90e6
8.81

8.6
I I | I	I I I I T 1 1 ""J f 1 I I I 1 I I I I I I
I »" I 1 T ¦ > ¦ « I
9.0	9.2
'7-rr
8.8
9,0
9,4
i ¦ • ¦ * i '
9.6
I l"!			 I « I I I I I I
3.2
Tr
9.4
9.6
¦n—1—I—I—r r
Abs. Int.
-1,32e6
-6.58e5
¦O.OOeO
RT
Abs. Int
rtTOeg)
5.37e8
•O.OOeO
RT
Rel. Int.
Fn 1 100%!
148.0984
Standard
4o 4.59e3
8.40-10.20
0%-
Rel. Int.
-| 100%-
152.1410
Standard
4o 3.84e3
8.40-10.20
0%-
ES-2-Methyl naphtha
2.1 flee
8,76
I I | II	I""
1
8.6
•-n
9.0
		i "i	"i i i ¦
8.8
9,0
	"I ¦ > . i i i
9.2
l—r
9,4
'"I I l 1 *	I I 	 I 1	1 1 I
9.6
JS-MethvHnaphthale
2.78el
0.69
9.8
J "f I I }"	|	 I I I I |
10,0
' I ¦
9,2
* i ¦
9.4
¦ i
9.6
10.0
Abs. Irit,
-1.22e6
6.10e5
-O.OOeO
RT
Abs, Int.
-1.98e6
•9.88e5
•O.OOeO
RT
Rel. Int.
Fn1 100%-
130.9920
QC Check
8,40-10.20 "
0%-
8,6
-r-f-T
8.8
"i"1"!1	r	r""T""T""i""i	i	i 	|	r 	i	i"1 j""T	r"T""T""|" "t1"
9.0	9.2	9,4
9,6
¦ i •
9,8
j—y	t	i	t	y	i""
10,0
Abs, Int.
-3.47e7
1 73e7
¦O.OOeO
RT
Results: P:IP9400_P9499\P9464_6042 PAH\resourves\P9464_6042_PAH_007 utp_res. saved 01-Aug-2008 13:34 (CM)
AP UttmTmce-Pm V3 992 User/System: CM/CMP4-015 cc: 7115. 5805. 4289, 8311, 1692 see: 361-909
Peak annotation: Areas, Centro/ds
Revised: 01-Aug-2008 13:33:22 (CM) Printed: OI-Aug-2006 14:17:15 Page 2 of 9
-------
AP Lab ID: P9464_6042_PAH_007
Irtstr: AutoSpec-Premier MM6
Rel. Int.
pr 2 100%
152.0636
Analyle
4o 2.26e6
11.50-12.30
Sample ID: Run# II-ACD-M23-3
VSIR expl: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 79
Acq: 30-Jul-2008 03:42:01
User: CEM Datafile: 080729V28
11.55
I 1 | I ! I I | I I I f—r| I «
11.7
11.
11.9
I j 4 | 1 I | t 1 * I | I I f f
12.0	12.1
I ] "«T i—i—r-
12.2
O.OOeO
12.3 RT
ES-Acenaphthytefie
Rel. Int.	3-5i
fn 2 100%- 11-55
158.0827
Standard
4o 8.32e3
11,50-12.30
0%-
11.5
r"t i i^i ii i »|i
11.6	11.7
-I—I I1 I V f—I I | | | I
11.8
Rel. Int.
Fn 2 100%-
154.0783
Analyte
4o 6.75e5
11.50-12.30
0%
11.5
I | 1 I I I | I 1 I I | >
11.6	11.7
11.8
Acenaohthene
1
11.90
L
T'" I / [ I I I I | I
12.0
12.1
i i i i I i
¦' I
12.2
Abs. Int.
-1.78e6
•8.90e5
¦O.OOeO
12.3 RT
i > i—i—i i i
Abs. Int.
-6.80e8
•3.40e8
O.OOeO
11.9
12.0
12.1
1 | I I >T | I I ! I
12.2	12.3 RT
Rel. Int.
Fn 2 100%-
160.0984
Standard
4o8,12e3
11 50-12 30
ES-Aoenaphthene
2.43e6
11.89
11.6
Rel. Int.
Fn 2 100%-
164.1410
Standard
4o 6.18e3
11.50-12.30
0%-
I ¦	» T ) ) I I I | I I I I | I" I I 'I |" "I"
11.7	11.8
JS-Acenaphthene
2 56e6
11.82
Abs. Int.
-1.59e6
•7.93e5
O.OOeO
i	j	r	i i * *	|	*	*	f	t	|	'	t	1	i	|	t	r i i | > i i i | i i i » | > i i »
11.9	12.0	12.1	12.2	12.3 RT
11.5
( t > " T I | | | I I | |
11.6	11.7
11.8
i i1" i
11.9
12.0
12.1
I I | 1 I I I | P I I I
12,2
Abs. Int.
-1.67e6
¦8.37e5
¦O.OOeO
12.3RT
Rel. Int.
Fn 2 100%-
168.9888
QC Check -
11,50-12.30"
0%-
I \ I
11.6
—r—*—r-
1 I 1
12.0
-1—!—I—T
T
12.2
1—!—|—T-
11.5
1 i *
11,7
11.8
11.9
12.1
12,3 RT
Results: P:\P9400__P9499\P9464_6042 PAH\resoufces\P9464_6042_PAH_007.utp_res, saved 0UAug-2008 13:34 (CM)
AP Ultra Trace-Pro V3.992 User/System CM/CMP4-015 cc: 9261,5093, 0424. 7008, 5321 see: 361-909
Peak annotation Armas, CentmieSs
Revised: 01-Auq-2008 13:29:26 {CM} Printed: OI-Aug-2008 14:17:26 Page 3 of 9
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 79
Rel. Int.
100%-
Fn 2
166.0783
Analyte
4o 1 42e6
12.70-16.50
0%-
Fluorene
2.7Se9
13.02
Acq: 30-Jul-2008 03:42:01
User: OEM Datafile: 080729V28
Ab&r+rtk
/l.OTeSK
Rel. Jnt.
100%-
Fn 2
172.0984
Standard
4o 6.73e3
12,70-16.50
13.0
ES-Fluorene
1.96e6
13.02
13.5
14.0
I I "I | " I 'I I 1 |	1	1 I
14.5
I | f I I I | I
15.0
•5.37e8
O.OOeO
T | '} I > I | > t I t | t I > 1 [ I I I 1
15.5	16.0	RT
0%	•• f
13,0
TTTTi|*V l 'I I ' |" I
13.5
l" ' |	I *"»"->		
14.0	14.5
Abs. int.
-1,09e6
¦5.46e5
" "j | l'""l I l I l'""l1 I1 'f 	r t ^ ' V ^ T^1' I i j l < i > | l I '11'* O.OOeO
15,0	/ 15.5/	16.0	RT
Rel, Int.
100%n
Fn 2
178.0783
Analyte
40 3,42e4
12.70-16.50
0%-
Phenanthrane
4.69ef
15.26
n
13.0
¦ ¦¦ |	j | | "T' I | I I" t	IB I j
13.5
Tlo
*1—,	I	—, -f! n,i—i,h«|»ii, nijii ^ ¦/

14.5
Rel, Int.
100%
Fn 2
184.0984
Standard
4a 6.43e3
12.70-16.50
0%-
|^n i t	|1 i"" i *7* "I ')	"t I 'f , | i		 i—i | i i—i—i-j-
13.0	13.5	14.0
14.5
15.0
15.5
16.0
AbMnt
rQ_07ff9>
¦5.37e8
™r*i—r i	i'"i i f *r - j -i 1 j w 		i	r'fi t i i
15.0	15.5	16.0
ES-Anthracene
3,44e6
15.37
ES-Phenanttirf
3.34e6
15.26
¦O.OOeO
RT
Abs. Int.
r2.10e6
1.05e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
12.70-16.50
0%-
13,0
13.5
T
14,0
i	r	t	»	i	r1
14.5
15.0
-r-f-T-
15.5
> r i i i i
16.0
Abs. Int.
-4,25e7
•2.12e7
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_007.utp_res, saved 01-Aug-200S 13:34 (CM)
AP UltraTrace-Pro 1/3 992 U$er/Sy$tem; CM/CMP4-01S cc: 4041. 8424, 8308, 3544 see: -361-909
Peak annotation: Areas, Centroids
Revised: Q1~Attg-2QQ8 13:33:35 (CM) Printed: 01-Aug-2Q0B 14:17:37 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 2
176-1410
Standard
4o 5.20e3
12.00-16,50
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Via!: 79
Rel. Int.
100%-i
Fn 2
188.1410
Standard
4o 6.82e3
12.00-16.50-
SS-Fluorene
2.41e6
12.9S
Acq: 30-Jul-2008 03:42:01
User: CEM Datafile: 080729V28
Abs. Int.
-1.65e6

		O.OOeO
fi 0/ f*—~S- ¦	, ¦	¦ ,/^S,
U /0"t—i—i—i—i—|—i—i—r
AS-Anthracene
1.53e6
15,33
K,
¦8.25e5
12.0
t	|	t	i	t	t		t	r	!¦	i	|		¦>	i	\	i	t	i	t	|	t	
12.5	13.0	13.5
14.0
-p-T—i-nr 	i	i	i	i	j	r	r	t	rMy	»	i	i	t	j	i	»	i	i	|	
14,5	15.0	15.5
Abs. Int.
-1.10e6
•5,52e5
•O.OOeO
RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
12.00-16.50"
12.0
Results: P:\P9400_P9499SP9464_6042 PAH\msources\P9464_6042_PAH_007.utp_res, saved 01-Aug-200B 13:34 {CMJ
AP UttraTrace-Pro V3.S92 UseriSystem: CM/CMP4415 fx; 6696. 6229 see: 361-909
flirt
15,5
Abs. Int.
-4.25e7
-2.12e7
-O.OOeO
RT
Peak annotation: Areas, Centroids
Revises!: 01-Aug-2008 13:27:42 fCMJ Printed: 0t-Aug-2008 14:17:48 Page 5 of 9
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Re!, Int.
Pfi 3 100%
202.0783
Analyte
4o1.01e6
17.50-22.50
0%-
Ruoranthene
3.40©9
18.13
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0S01 GC: pah_db5-SPLT5 Vial: 79
Pyrene
3.2389
18.69
.A

Jl
Rel. Int.
Fn 3 100%-
2OB.0984
Standard
4o1.01e4
17.50-22.50
0%-
18.0
ES-Fluoranthene
4.1Be6
18.13
—
19.0
¦A-r^y.
I I I ¦!
20.0
21.0

Acq: 30-Jul-2008 03:42:01
User: CEM Datafile: 080729V28
•5.37e8
22.0
1 I I
18.0
'i"" i	" i -r - r 1
19,0
I l I I | f w i ¦ 11 ¦ -f	 i	I 'I
20.0
21.0
22.0
-O.OOeO
RT
Abs. Int.
-2.04e6
-1.02e6
[ 'i "¦"> i 'i" | i"" i"" i i | t"" i i "i O.OOeO
RT
Rel. tnt
Fn 3 100%
205.08S3
Standard
4o3.10e4
17.50-22.50
0%-
—AW
ES-Pvrene
I.20e7
18.69
Rel. Int.
Fn 3 1°0%-
228.0939
Analyte
4o 3.18e5
17.50-22 50
0%-
Rel. Int.
Fn 3 100%-
234.1140
Standard
4o6.59e3
17.50-22.50
0%-
I » | I
18.0
—I—1
18.0
19.0
7.78e5
20.43
	^\i ii
20.0
I—1—"¦*
21.0
5.20e8
21.07
Benz(a)A cene
•U
i t ¦ r i i i
18.0
	1	-r—
19.0
r20.0
i.
I 1 I
21.62
22.0
21.0
ES-Benz(a)Anthrace
3.76e6
21.62
i i "| '—
19.0
"l r f" i i j
20.0
—I—1
21.0
22.0
Abs. Int.
-5.90e6
•2 95e6
¦	|	1	1	t	T""
22.0
-O.OOeO
RT
Abs. Int.
-1,04e9
5.1968
-O.OOeO
RT
Abs. Int.
-2.06e6
1,03e6
¦O.OOeO
RT
Rel. Int.
Fn 3 100%
218.3856
QC Check
17.50-22.50
18.0
19.0
20.0
21.0
22.0
Abs. Int.
2.26e7
1.13c7
i r i—i O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6042_PAH_007 utp_res. saved 01-Aug-2008 13:34 (CM)
AP UttraTrace-Pro V3.992 User/System: CM/CMP4-01S cc; 5865, 9544, 5082, 7279, 5906 see: 361-909
Peak annotation: Areas, Centmids /
Revised: 01-Aug-2008 13:33:43 (CM) Printed: 01-Aug-2008 14 1B OO Page 6 of 9 /
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
212.1410
Standard
4o 8.27e3
18.00-20.00
Sample ID: Run# II-ACD-M23-3
VSIR exp{; pah_db5_0801 GC: pah_db5-SPLT5 Vial: 79
JS-Pyrene
3.T4eB
18.64
\
Acq: 30-Jul-2008 03:42:01
User: CEM Datafile: 080729V28
Abs. Int.
2.09e6
Rel. Int.
100%-
Fn 3
244.1974
Standard
4o 4.51 e3
18.00-20.00
" f	1 I I | I I I I | I I I I J I
18.4	18.6
18.8
ISM)
SS-Terphenyl
2.34e6
19.03
19.2
T
19.6
1,05e6
19.8
=r-i— O.OOeO
RT
Abs. Int.
-1.65e6
0% I I I i | mii
18.2
i | i i i i | i r ¦ ¦ | r i¦~rT~"]TT~i -i—|—i i r'l | ri'i T~|	| i i i i | i i i i | i i I i j r » i i | i i 7 i f"Tl i i~| i i i i | i fi'i'fn
18.4	18.6	18 8	19.0	19.2	19.4	19.6	19.8
¦8.27e5
O.OOeO
RT
Rel. Int.
100%-,
Fn 3
218.9856
QC Check
18.00-20,00"
Abs. Int.
-2.19e7
-1.10e7
0%-
18.2
' I 1 ' ' ' "l"
18.4
' I '
18.6
t
18.8
-r-j-f-
19.0
19.8
j i t i t O.OOeO
RT
Results: P:\P9400_P9499SP9464_6042 PAH\resaurces\P9464_6042_PAH_007.utp_ms. saved 01-Aug-2008 13:34 (CM}
AP UltraTrace-Pro V3 992 User/System CM/CMP4-01S cc: 5840, 7572 see: 361~909
19.2	19.4	19.6
Peak annotation Areas. CentroKts
Revised: 0)-Aug-2008 13:28:12 (CMj Printed: 0l-Aug-20O8 14:18:13 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4a 5.07e4
23.50-28.00
0%-
¦i T"'r"
24.0
Sample ID: Run# II-ACO-M23-3
VStR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 79
Benz(b)Fluoranttiene
2.54e9
" I.9JK'
24.5
luoranthene
25.5
m,re
25.95
J 26.16
ill
Acq: 30-Jul-2008 03:42:01
User: CEM Datafile: 080729V28
Abs. Int.
-6 11e8
26.0
"I ' ¦ ' '"T ¦
26.5
27.0
27.5
3,05e8
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
258.1140
Standard
4a 3.42e3
23.50-28.00
0%-
» t I I [ I I I I | f
24.0
Rel. Int.
100%-
Fn 4
256.1073
Standard
4o 6.69e3
23.50-28.00
0%-
ES-Benz(b)Fluorant
9.94e6
24.91
Rel. Int.
100%-
Fn 4
264.1692
Standard
4o3 69e3
23.50-28.00
0%-
24.5
25.0
25.5
26.5
27.0
ES-Benz(e)Pyrene
9.B9e5
23js&-Benz(a)Pyrer>e
9.58ei
26.16
11 i ji iji
24.0
24.5
' |" i it | "I I > I | i't i r | i
25.0	25.5
I J1 1 I I 1—f
26.0
27.5
| I "f 1 I ) » I'l T'l'l
26.5
ES-Perylene
7.51e6
26.38
' 1 ' | i % i )"i"r fi i "i"
27.0	27.5
JS-Benz(a)Pyrer>e
4.16e6
26.06
I			I	
24.0
iN,il i i i i | i i i i J1 i" i i" i | i
24 5	25.0
25 5 ' '
26.0
I ' | I"'
26.5
Abs. Int.
-3.93e6
1.97e6
-O.OOeO
RT
Abs. Int.
-3.63e6
1.81e6
-O.OOeO
RT
Abs. Int.
-2,38e6
1.19e6
27.0
27.5
¦O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28.00
0%-
I | i l i l | l l i i—|—r-
24.0	24.5
25,0
25.5
26.0
26.5
27.0
27.5
Abs. Int.
1.63e7
8.13e6
¦O.OOeO
RT
Results: P:\P9400^P9499\P9464_6042 PAHVesources\P9464_6042_PAH_007utp_res saved 01 -Aug-2008 13:34 (CM)
AP Wfra Trace-Pro V3.992 User/System: CWCMP4-015 cc: 8228, 6510, 49S0, 4096 see: 361-909
Peak annotation: Areas, Controids
Revised: 01-Aug-2008 13:33:51 (CM) Printed: 01-Aug-2008 14:18:25 Page 8 of 9 /
-------
AP Lab ID: P9464_6042_PAH_007
Instr: AutoSpec-Premier MM6
Rel. Int.
Pn 4 100%'
276.0939
Arialyte
4o 6.50e4
29.0-36,0
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 79
lnd(123-af)Pyrene
5,13e9
31,66
0%
29.0
¦ , o
30.0

31.0
32.0
Benz(ghi
!	1 I I
Acq: 30-Jul-2008 03:42:01
User: CEM Datafile: 080729V28
Abs. Int.
1,03e8
•5.14e7
33.0
| i i i r | t
35.0
Rel. Int.
4 100%-
282.1140
Standard
4o 5.40e3
29.0-36.0
0%-
ES-!nd{123-cd)Pyre
6,46e6
31.65
I ' » I I
29.0
30.0
"1	1	1	I	I	I
31.0
32.0
T11' | i i i i ( i r "T1 i11 j"111—i—f—i—|—r
33.0	34.0
-1—j—i—l 11" 111 ¦ |—i—i—i—i—|—r-
35,0
Rel. Int.
pn4 100%
288.1342
Standard
4o2.76e3
29.0-36.0
Ret. Int.
pn 4 100%-q
278.1096
Analyte
4o 4.82e4
29.0-36.0
Rel. Int.
pn 4 100%-
284,1297
Standard
4o 4.41e3
29.0-36.0
0%-
33,28

35.0
ES-Dibenz(ah)Anthf
6.63e6
31,82
I I » I
29.0
30.0
I i1i | i i i i |
31.0
32.0
T I I—I | I I "" I 	I | 1 1
33.0
1 I '
34.0
"I" "I 7 1 f t I	1 I
¦O.OOeO
36.0RT
Abs. Int.
1,28e6
•6.42e5
O.OOeO
36.0RT
[ t t I 1
31.0
—'/ ' 1
DihenzfahlAnth
I.57e8
31.79
Abs, Int.
1.23e6
6.15e5
O.OOeO
36.0 RT
Abs. Int.
-2.00e7
1.00e7
O.OOeO
36.0 RT
Abs. Int.
- 1.09e6
5.46e5
O.OOeO
35.0
36.0 RT
Rel. Int.
Fn 4 100%-
292.9824
QC Check
29.0-36.0
Abs. Int.
•1.7te7
-8.55e6
0%-
O.OOeO
29.0
" * "i ¦ r ¦ "i ""T ¦
30.0
31 0
32.0
••"I	t	r	i	i	|	»	»	t	r	|	*	r	i	i	j	t	tm"
33.0	34.0
r r j—i—i—i—i—|—I—i—r-
35.0	36.0RT
Results: P:\P9400_P9499\P9464 6042 PAMfBSOUfuesiP9464 6042_PAH 00?,
-------
AP Lab ID: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: OEM Dalafile. 080729V29
Rel. Int.
100%n
Fn 1
130.9920
QC Check
7.02-10.55
0%-
7.5
8.0
' I ¦
8.5
9.0
9.5
100
Abs. Int.
wvj- 3.67e7
• 1 ,84e7
] 0. OOeO
10.5 RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
10.59-17.00'

0%-
» | I I I I [ I I
11.0
1 I 1
12.0
'	T	
13.0
14.0
15.0
T J t
16.0
Abs. Int.
4.69e7
-2.35e7
>111
O.OOeO
17.0 RT
Rel. int.
100%-
Fn 3
218.9856
QC Check
17.02-23.01'
0%-
18.0
19,0
20.0
21.0
22.0
-I—i—i—i—,—f-O.OOeO
23.0 RT
Abs. Int.
-2.40e7
1,20e7
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35 01'
0%-
24.0
26.0
28.0
30.0
32.0
Abs. Int.
-1,69e7
•8.47e6
34.0
O.OOeO
RT
Results: P\P9400_P9499\P94&4_B042 PAHVesaurces\SB_08072B_PAH_VH.utp_re$. saved 01-Aug-2008 11:40 (CM)
AP UltraTrace-Pro 1/3.992 Userhystem: CM/CMP4-01S see 692-132
Peak annotation: Areas. Centmids /
PKD:n/a Printed: 01-Aug-2008 14:18:49 Paget of 9 /
-------
AP Lab ID: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_08Q1 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: CEM Datafile: 080729V29
Rel. Int.
Fn1 100%-
128.0626
Analyte
4a 1.59e4
8,40-10.20
0%-
¦r~rp
8.6
8.8
¦¦¦¦j	t	!¦	r	i	y	i	i	i	i	|--f—
9.0	9.2
"T—I™1"
9.4
9.6
I | I 1 I I | 1
9.8
'	I	'	
10,0
Abs. Int.
-1,39e6
•6,93e5
O.OOeO
RT
Rel. Int.
1 100%-
134.0827
Standard
4o 1.45e3
8.40-10.20
0%-
| i i rr'j r
8.6
"T~rr
8.8
"T-T-r
9.0
T'-
9.2
Itltllll III )
9.4
9.6
9.8
' I '
10.0

Abs. Int.
-1.43e4
7,13e3
¦O.OOeO
RT
Rel. Int.
Fn 1 100%
142.0783
Analyte
4o 1.45e4
8.40-1020
Abs. Int.
-2.35e5
1,17e5
OOeO
Rel. Int.
Fn1 100%-
148.0984
Standard
4 o 1,04e3
8.40-10.20
0%-
•y""|	yT-y-v-|""7		t	|,	[	|	|,	,		.)	|	|	t	|	t	»	1	t	|	I'	I	t	("„
8.6	8,8	9.0	9,2
T—T--r-
9,4
1 [ T T 1 T | I > t ) | I
9,6	9.8
"1	|	I""
10,0
Abs. Int.
-1.30e4
•6.51e3
•O.OOeO
RT
Rel, Int,
pn i 100%-
152.1410
Standard
4a 1.47e3
8.40-10.20
Abs. Int.
1.56e4
7.82e3
OOeO
Rel. Int.
Fn 1 100%
130.9920
QC Check
8,40-10.20
Abs. Int.
3.67e7
Pl.84e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHtosources\SB_080729_PAH_VHutp_ms, saved 01-Aug-2008 11:40 (CMS
AP Ultra Trace-Pro V3 992 User/System: CM/CMP4-015 cc: 8I71~I537 1138, 8718, 6270 see: 692-132
Peak annotation: Areas, Centmids y
PKD: 01-Aug-2008 11:40:46 Printed: 0l-Aug-2008 14:19:00 Page 2 of 9 /
-------
AP Lab ID: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: CEM Datafile: 080729V29
Rel. Int.
pn 2 100%-
152.0636
Analyte
4o 8.50e3
11.50-12.30
0%-
11.5
I I I I I 1 I I I I I T I I 1 I I I f I I I I r I I I I I I I I I I I 1 ! I I
11.6	11.7	11,8	11.9
12.0
' I ' ' ' 1 I 1 ' ' ' I '
12.1	12.2
Abs, Int.
-5.28e5
•2.64e5
•O.OOeO
12.3 RT
Rel. Int.
Fn2 100%-
158.0827
Standard
4o 1.64e3
11.50-12.30
Rel. Int.
Fn 2 100%!
154.0783
Analyte
4o 1.15e4
11.50-12.30
5 14e4
11.89
i » i i i | i i i i i r » i i | t i i i | i t i i | i i t r | i t i r i i i i i r t i i i i i
Abs. Int.
-1.36e4
6.79e3
OOeO
12.3RT .
Abs. Int.
5.67e4
2.83e4
OOeO
12.3 RT
Rel. Int.
Fn 2 100%
160.0984
Standard
4o 1.78e3
11.50-12.30
Abs. Int.
1.25e4
6.23e3
OOeO
12.3 RT
Rel. Int.
2 100%-
164.1410
Standard
4o 1.57e3
11.50-12.30
0%-
| I I t I 1
11.5
11.6
• i •
11.7
11.8
11.9
12.0
12.1
I 1 T | < I » I | I
12.2
Abs. Int.
-1,20e4
¦5.99e3
•O.OOeO
12.3RT
Rel. Int.
Frl2 100%
168.9888
QC Check
11.50-12.30
0%-*j—i—*—»—*t
11.5
Abs. Int.
57e7
2.29e7
O.OOeO
12.3 RT
Results: P:\P9400_P9499\P9464_6042 PAH^esources\SB_080729_PAH_VKutp_re$. saved 01-Aug-2008 11:40 (CM)
AP Ultra Trace-Pro~ V3.992 User/System CMSCMP4-015 cc: 0171 2064, 8207, 3233 See: 692-132
Peak annotation: Areas. Centmitfs
PKD 0t-Aug-2008 11:40:46 Printed: OI-Aug-2008 14:19:12 Page 3 of 9
-------
AP Lab ID: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_Q801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: CEM Datafile: 080729V29
Rel. Int.
100%-,
Fn 2
166.0783
Analyte
4o 7.21 e3
12.70-16.50 ¦
0%-
3.28e5
5,37e4
13.51
I | I I I I |
13.0
13.5
1 | 1
14.0
' I '
14.5
15.0
' I '
15.5
r i | i i i » j i i—i—*—p
16.0
Abs. Int.
-1.65e5
8.27e4
•O.OOeO
RT
Rel. Int.
100%
Fn 2
172.0984
Standard
4o 1 56e3
12 70-16.50
Rel. Int.
100%
Fn 2
178.0783
Analyte
4o 1.16e4
12.70-16 50
Abs. Int.
-2.42e4
1.21e4
f	f	i	v	t	|	i	i	r	t	|	i	r	r	i		 ¦ O.OOeO
16.0	RT
3.29e6
15.24
4 82eS
Abs. Int,
-1 95e6
9.73e5
0% | "i1 »"p | i k i
14.5
Rel. Int.
100%'
Fn 2
184.0984
Standard
40 1 ,09e3
12.70-16.50
0%——|—i—i i i—j-
13.0
13,5
14.0	14.5
—i—i—i—i—|—i—i—[—i—J—i—[—i—(—|—r-
15.0	15.5
Abs. Int.
-1.45e4
-7.24e3
i—|—i i i i | i i i i ' 0. GOeO
16.0	RT
Rel. Int.
100%-
Fn 2
168,9888
QC Check
12,70-16.50
0%-
"•t	|	1	T	T	T	|	f	T	*	I	J	T"
13.0	13.5
14,0
14.5
15 0
15.5
16,0
Abs. Int,
4.69e7
•2.3587
f ]—r—i—r—i—0 OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHVesources\SB_080729_PAVH utp_res. saved 01-Aug-2008 11:40 (CM)
AP UltraTrace-Pm V3.992 User/System CM/CMP4-015 cc: 5892. 0565. 0719. 2764 see 692-132
Peak annotation: Amas, Centmids
PKD: oi-Aug-2008 11:40:46 Printed: 0l-Aug-2008 14:19:24 Page 4 of 9
-------
AP Lab ID: S8_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: CEM Datafile: 080729V29
Rel. Int.
100%-,
Fn 2
176-1410
Standard
4a 1.60e3
12.00-16.50
/JWmWVw
Abs. int,
r1.53e4
•7.64e3
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
188.1410
Standard
4o 1 67e3
12.00-16.50 ¦
12.0
' I '
12.5
¦¦¦¦I	i	i	i	i	i	r"
13.0
I 1 ' ¦ 1 I ¦
13,5
"I	 ' 1 I '
14.0
14.5
1 I *
15,0
"i—*—j—i—i—r*
15.5
-i—>—i—i—j—r—i—i—i—|—i—r*
16,0
Abs. Int.
-1 54e4
7.7163
O.OOeO
RT
Rel. Int.
100%-
Abs, Int.
-4.69e7
Fn 2 '
168.9888 •
QC Check
12.00-16.50
-2.35e7
0%-
12,0
I I I | 1 I I I | 1 I
12.5	13.0
	f	f	I	f		f	1	1	|	f	f""T	r		T""l	|	f	f,mT	|»»^»»t»»t""Tm,T""|	T""T""1	
13.5	14.0	14.5	15.0
Results: P:\P9400_P9499\P9464_6042 PAH\msources\SB_080729_PAH_VH.utp_m$, sawsi Q1-Aug-2008 11:40 (CM)
AP UltraTrace-Pm ¥3.992 User/System: CM/CMP4-01S cc: 0230, 1511 see: 692-132
O.OOeO
—j—r""T",T""T",y"i	T,,Mi	t	I	r	f	t	rm|	f'T
15.5	16.0	RT
Peak annotation: Areas, Centroids
PKD: Q1-Auq-2008 11:40:46 Printed: 01-Aug-2008 14:19:38 Page 5 of 9
-------
AP Lab 10: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonarie
VS1R expt: pah_db5_08Q1 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: GEM Datafile: 080729V29
Rel. Int.
Fn 3 100%-
202.0783
Analyte
4 o 162e4
17.50-22.50
0%-
—r
18.0
s.ioes
18.34
—I—
19.0
20.0
21.0
	1	1	r-
22.0
Abs. Int.
-1.37e6
•6.84e5
•O.OOeO
RT
Rel. Int.
pn 3 100%'
208.0984
Standard
4o 6.29e3
17.50-22.50
Abs, Int.
3.72e4
1.86e4
OOeO
Rel. Int.
Fn 3 100%-
205.0883
Standard
4a 4.22e3
17.50-22.50
0%-
—I—
18.0
—I	T——!—
19.0
20.0
21.0
22.0
Abs. Int.
- 2 15e4
¦ 1.07e4
•O.OOeO
RT
Rel. Int.
Fn 3 100%-
228.0939
Analyte
4o 1.15e4
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-
234.1140
Standard
4o 1.73e3
17.50-22.50
0%-
18.0
19.0
B.iOeS
21.61
20.0
21.0
22.0
Abs. Int.
-4.88e5
¦2.44e5

—f	1 I t
18.0
-I—I—1—I—
19.0
20.0
lII«|f1VT
21.0
22.0
•O.OOeO
RT
Abs. Int.
• 1,43e4
-7.13e3
•O.OOeO
RT
Rel. Int.
Fn 3 100%
218.9856
QC Check
17.50-22,50
Results: P:\P9400_P9499\P9464_6Q42 PAHVesources\SB_080729_PAH_VH utp__res. saved 01-Aug-20Q8 11:40 (CM)
AP UltraTmee-Pm V3.992 Userkystem: CWCMP4-015 cc: 6182, 2841, 8587. 7592. 5915 see: 692-132
Abs. Int.
2,40e7
1,20e7
O.OOeO
RT
Peak annotation. Areas. Centroltis
PKD: 01-Aug-2008 11:40:46 Printed: 01-Aug-2008 14:19:50 Page S of &
-------
AP Lab ID: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: CEM Datafiie: 080729V29
Rel. Int.
100%-
Fn 3
212.1410
Standard
4a 3.80e3
18,00-20.00
18.2
> i | it i i | i i i i | i i i i j i i i i | i i i i | i i i i |
18.6	18.8	19.0	19.2
Abs. Int.
-1.91e4
-9.55e3
j » i * % ) i i i i | i i i i | i i i i 0. OOeO
19.6	19.8	RT
Rel. Int.
100%-
Fn 3
244.1974
Standard
4a 1.32e3
18.00-20.00
0%-
18,2
Abs. Int.
-1,19e4
-5.96e3
18.4
		|	rMTM.r...	r""g""T	I	I""'l '¦ | f f 1 | ' I'T' f~
18.6
18,8
19.0
19,2
19.4
O.OOeO
i | i i i i ] r i ! i | i i i ^ | i i i i
19.6	19.8	RT
Rel. Int.
100%-
Abs. Int.
- 2.38e7
Fn 3
218.9856 ¦
QC Check
18.00-20,00"
-1,19e7
0%-
I ' ' ' ' I '
18.2
'"I	r""r"rmr"'j""i""T"
18,4
I I I I I I > I
18.6
18.8
I i i i i j i i i i | i i * i | *
19,0	19.2
Results: P:\P940a_P9499\P9464_8042 PAHVesoarces\SB_0BO729__PAH_VH utp res. saved OI-Aug-2008 11:40 (CM)
AP UttraTrace-Pm V3.992 User/System; CM/CMP4-015 cc: 6081. 9420 see: 692-132
19.4
19,6
19,8
-O.OOeO
RT
Peak annotation: Areas, Centrotds
PKD: 01-Aug-20Q8 11:40:46 Printed: 01-Aug-200B 14:20:01 Page 7 ot 9 '
-------
AP Lab ID: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: CEM Datafile: 080729V29
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4o 1.41e4
23.50-28.00
0%-
1.7Se6
24.91
8.11e5
25.93 7.64eS
26.14
I t 1 J > I I T | > I I > | I T I > | T I I I | I f I I | I I 1 I f I I > I | 1 T 1 t | 1 I I I | 1 I I I | f I I I [ I
24.0	24.5	25.0	25.5	26.0	26.5
27.0
j t i i i i ;
27.5
Abs, Int.
-4.68e5
•2.34e5
t . . I-.—0.OOeO
RT
Rel, Int.
100%-
Fn 4
258.1140
Standard
4o1.77e3
23.50-28.00
0%-
24.0
24,5
25.0
25.5
26.0
26.5
27.0
27.5
Abs. Int.
-1.77e4
¦8.87e3
¦ O.OOeO
RT
Rel. Int.
100%-
Fn 4
256,1073
Standard
4a3 27e3
23.50-28.00
0%-
"i	<	t	»	j	t	i1	i	i	|	i	i	i	t	|	t	i	i	r	|	i	r	i	r	|	rmt	i	i	|	i	t	»"
24.0	24.5	25.0
¦"<¦¦"1	TMMf— t—¦»—j—1•»	1	»"M,r	y	r	r	i	i	|	»	<	t	»	j	t	i	r	i		»	%••••
26.0	26.5
25.5
27.0
I ' 1 ' ¦ I '
27.5
I t l 1 »
Abs. Int.
-2.11e4
¦1.05e4
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
264.1692
Standard
4a 2 11e3
23.50-28.00
0%-
24.0
24.5	25.0	25.5	26.0
I [ I I I 1 ) i t I I | I
26.5	27.0
27.5
Abs. Int.
r1.71e4
•8.53e3
I ¦ ¦ ¦ i O.OOeO
RT
Rel. Int.
100%n
Fn 4
292.9824
QC Check
23.50-28.00
0%-
r i i i f i i i i | i i i t 1 i
24.0
24.5
25.0
25.5
26.0
26,5
27.0
> | f T I I |
27.5
Abs. Int.
1 68e7
• 8.40e6
• O.OOeO
RT
Results: P. \P9400_P9499V9464_6042 PAH\resources\SB_080729_PAH_ VH. utp_res. saved 01-Aug-2008 11:40 (CM)
AP Wfra Trace-Pro ¥3.992 Usei/System: CM/CMP4-015 cc: 1W1~0377, 0911, 6025 see: 692-132
Peak annotation: Areas. Centmids
PHD: 01-Aug-2008 11:40:46 Printed: Ot-Aug-2008 14:20:13 Page 8 of 9
-------
AP Lab ID: SB_080729_PAH_VH
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 04:21:32
User: CEM Datafile: 080729V29
Rel, Int.
Fn4 100%-
276-0939
Analyte
4ct 1.78e4
29,0-36.0
0%-
9.70e5
1.05e6
33.25
2 96e5
31.05
29.0
30.0
31.0
32.0
33.0
34.0
1 1 J I J I
35.0
Abs, Int.
-2.56e5
1.28e5
•O.OOeO
36.0 RT
Rel. Int.
pn4 100%-
282.1140
Standard
4o 3.84e3
29.0-36.0
0%-
29.0
I I I I | I I
30.0
g|iiti |i i-i-1-"!1 i i » r | i i r r | i i > » | i
31.0	32.0	33.0
' ' l
' I »
34.0
35.0
Abs. Int.
-2,01e4
¦1.00e4
¦O.OOeO
36.0RT
Rel. Int.
pn 4 100%-
288.1342
Standard
4a1.59e3
29.0-36.0
0%-

29.0
30.0
31.0
32.0
i | i
33.0	34.0
t
35.0
I I I I
Abs, Int.
-1.54e4
>7.69e3
¦O.OOeO
36.0 RT
Rel. int
Fn 4 100*!
278.1096
Anatyte
4 a 1,22e4
29,0-36.0
0%-
i	t	i	t	|	f	r	i	i	|	i"
29.0	30.0
31.0
		'	I	 •
32.0
"T	|	I"
33.0
34.0
* J I ? ? ! | I 1
35.0
Abs. Int.
-8.43e4
¦4.21e4
•O.OOeO
36.0 RT
Rel, Int.
pn 4 100%
284,1297
Standard
4a 2.03e3
29.0-36,0
0%
2.00e4
31.79
1.11«4
32.45

t i i i ] i i i » | > r r t [ i i > i | i i -riii,-|i r i i r j 1 i i
29.0	30.0	31.0	32.0
-i—|—i—i—i—i—p
33.0
34.0
35.0
Abs. Int.
-1.58e4
7 89e3
•O.OOeO
36.0 RT
Rel. Int.
Fn 4 100%-
292.9824
QC Check
29.0-36.0
0%-
29.0
30.0
31.0
32.0
33.0
34.0
35.0
Abs. Int.
-1 69e7
•8 47e6
¦O.OOeO
36.0RT
Results: P:\P9400_P9499\P9464_6042 PAmesoumes\S8_080729_PAH_m.utp_rBS, saved Q1-Aug-2008 11:40 (CM)
AP UltraTmce-Pm V3.992 User/System: CM/CMP4-01S cc: 1962. 8209, 0038, 0060, 8B46 sec: 692-132
Peak annotation: Areas. Centruds
PKD: 01-Aug-2QQ8 11:40:46 Printed: 01-Aug-2008 14:20:26 Page 9 of 9
-------
Datafile: e: 080730V19
Acquired: 30 Jul 2008 21:15:05
J
Client ID: Run# H-ACD-M23-3
Lab ID: P9464 6042 PAH 007-SPL500
Wt/Vol: 1 Train
J Level: 4 ng/Trair^

H°VaL:
MM6PAH 080118_18JAN08
Nominal ES spike: 40 ng
Stats
Largest +ve RT shift (sees)
Largest -ve RT shift (sees)
Name
ft Naphthalene
f 2-Methylnaphthalene
Acenaphthylene
Aeenaphthene
f, Fluorene
& Phenanthrene
¥ Anthracene
Fluoranthene
4 Pyrene
Benzo(a!Anthracene
Chrysene
Benzo(b)Fluoranthene
Benzo(klFluoranthene
Benzo(elPyrene
Benzo(a)Pyrene
Perylene
Indeno(1,2,3-cd)Pyrene
Dibenzo{a,h)Anthracene
Benzo(glii)Perylene
Actual
RT
PAH Ax ES/SS
#VAliUE! 3.7
~VALUE! -1.3
QC
/
8.56 '
9.75
11.55/*
11.91 /
13.03-/
15.25 S
15.37 /
18.13-/
18.69 /
21.62
21.74
24.93 /
25.06 ^
25.96/
26.20 S
26.48 S
31.73/
31.78 /
33.30 '
/
J, {/?& &
(p*~>
f oan
Checkcode:
(}v4_ K» ^


So)
Pred
Actual
Diff

X

J*-f'cone

RET
RRT
Sees
Response
RS RRF
/fag/Train_
Noise
1.0005
0.9996
-0.5
1.42E+09
1
09*
x428,000 4«
7.93E+04
1.0003
1.0001
-0.1
1,66E+08
1
11
-130,000 Jf
6.91E+03
1.0003
1.0001
'0.1
2.33E+08
0
86
<191, OOO^
3.46E+04
1.0003
1.0002
-0,1
1,16E+07
1
00
14,200
1.39E+04
1.0004
1.0004
0
5.44E+07
1
05
63, 800
1.64E+04
1.0003
1.0001
-0.2
3.71E+G8
1
12
.-193, 000 »\r
5.08E+03
1.0003
1.0003
0
4.04E+07
1
09
~ 37,100
5.08E+03
1.0001
1,0002
+ 0.1
1,13E+08
1
02
* 73,300 £0
J25,900 %>
1.55E+04
1.0001
1.0002
+0.1
9.12E+07
1
03
1.55E+04
1.0001
0,9999
-0.3
1,32E+07
1
00
16,200
6.07E+03
0.9998
1,0007
+1.2
2.33E+07
1
11
27,600
6.07E+03
1.0002
1.0007
+ 0.7
1.31E+07
0
99
17,200
3.88E+03
1.0003
1.0015
+1.8
7.84E+06
0
90
11,600
3.88E+03
1.0000
1.0004
+ 0.6
7.18E+06
0
93
10,500
3.88E+03
0.9997
1.0015
+2.8
4.06E+06
0
86
8,530
3.88E+03
1.0044
1.0041
-0.5
2.47E+05
0
90
705
3.88E+03
1.0002
1.0022
#VALHE!
2.66E+06
0
93
#VALUE!
5.11E+03
0.9989
0.0000

5.01E+05
0
89
#VALUE!
3.87E+03
1.0004
1.0013
#VALUE!
2.37E+06
0
95
#VALUE!
5.11E+03
DL
92.30000
17.50000
110.00000
60.80000
84.40000
11.60000
17.30000
44.30000
18.30000
38.80000
44.60000
34.50000
37.50000
48.80000
55.20000
55.60000
#VALUE! "p
#VALUEI \
#VALUE!
ei5
ff"'1
Analytical Perspectives
Page 1 of 2
Printed: 8/5/2008 2:26 PM
-------
Datafile: e: 080730V19
Client ID: Run# II-ACD-M23-3
Lab ID: P9464 6042 PAH 007-SPL500
Wt/Vol: 1 Train
Stats
Largest +ve RT shift (seesI
Largest -ve RT shift (sees!
PAH Ax
#VALUE!
# VALUE!
ES/SS
3.7
-1.3
Name
Actual
RT
Fred
RRT
Actual
RRT
Diff
Sees
13C6-Naphthalene
8.
57
13C6-2-Methylnaphthalene
9
75
13C6-Acer:aphchylene
11
55
13C6-Acenaphthene
11
90
13C6-Fluorene
13
02
13C6-Phenanthrene
15
25
13C6-Anthracene
15
37
13C6-Pluoranthene
18
12
13C3-Pyrene
18
68
13C6-Benza(a)Anthracene
21
62
13 C 6-Chrysene
21
72
13C6-Benzolb)Fluoranthene
24
91
13C6-Benzo(k)Fluoranthene
25
02
13C4~Benzo(e)Pyrene
25
95
13C4-Benzo(a)Pyrene
26
16
dl2-fcryiene
26
38
13C6-Indeno(1,2,3-cd)Pyrene
0.
00
13C6-Dibenzo!ah)Anthracene
0.
00
13C12-Bcnzo(ghi> Perylene
0.
00
AS--An thracene
15
33
SS-Fluorerie
12
95
SS-Terphenyl
19
04
JS-Methylaaphthalene
9.
69
JS-Acenaphthene
11
84
JS-Pyrene
18
64
JS-Benzo(a)Pyrene
26
06
0
8855
0
8846
-0
5
1
0063
1
0066
+0
2
0
9757
0
9758
+0
1
1
0059
1
0058
-0
1
1
1003
1
1001
-0
1
1
2892
1
2086
-0
4
1
2995
1
2987
-0
6
0
9725
0
9726
+0
1
1
0025
1
0025
0

1
1602
1
1604
+ 0
2
1
1663
1
1655
-0
9
0
9557
0
9561
+ 0
6
0
9604
0
9601
-0
5
0
9958
0
9959
+0
2
1
0046
1
0038
-1
3
1
0127
1
0122
-0
8
1
2144
0
0000


1
2235
0
0000


1
2772
0
0000


1
2897
1
2949
+3.
7
0
9949
0
9949
0

1
0507
1
0505
-0.
2
Analytical Perspectives
Page 2 of 2
ICAL: MM6 PAH 080118 18JAN08
Response
Ra
RUT
Recv.
1.22E+05
1
51 v

227
0
4.58E+04
0
96

134
0 ^
5.69E+04
1
79

123
0
3.26E+04
1
06

119
0
3.23E+04
1
11

113
0
6.88S+04
1
76

152
0 x
4.00E+04
1
64

94
9 v
6.051+04
1
25

110
0 ^
1.361+05
1
30

238
0
3.26E+04
1
06

70
1
3.03E+04
1
02

67
9
6.15E+04
1
21

413
0
6.00E+04
1
60

306
0
5.85E+04
1
30

366
0
4.41E+04
1
39

.258
0
3.10E+04
1
36

185
0
O.OOE+OO
0
81


-
0.0QE+00
1
00


-
0-00E+00
1
15


-
1.37E+04
1
44
/
37
0
2.59E+04
0
96
/
83
7
2.44E+04
0
54
/
75
5
3.57E+04
2.58E+04
4.40E+04
6.141+03
Printed: 8/5/2008 2:26 PM
-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr; AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 79
Acq: 30-Jul-2008 21:15:05
User: CEM Datafile: 080730V19
Re). Int.
100%-
Fn 1
130.9920
QC Check
7.02-10.55
0%-
i-1—i—i—i—i—|—i—i—i—i—j—i—i-
7.5	8.0
1-1
8.5
9.0
9.5
10.0
Abs. int.
5.83e7
-2.92e7
O.OOeO
10.5 RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
10.59-17.00
r~
0%-T—"I	1	1	1—
11.0
' I 1
12.0
13.0
14.0
15.0
16.0
Abs. Int.
-7.12e7
•3.56e7
-O.OOeO
17.0 RT
Rel Int.
100%
>"1,	
r~
Fn 3
218.9856
QC Check
17.02-23.00'
0%-
18.0
1 !
19.0
1 f I 1
""I	*	1	|	T
20.0
""I	'I	»	I	I	«	I""
21.0
22.0
Abs. Int.
-3.75e7
¦1.87e7
-O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01'
0%-
' I '
24.0
I 1 I I | » T"
26.0
M,r	i	t	i	rM
28.0
30.0
Results: P:\P9400_P9499\P9464_6042 PAHuvsourceslPS464_6042_PAH_00?-SPL500.utp_res. saved 31-Jul-200B 15:23 {CM)
AP Ufl/BTrace-Pro V3.992 User/System CM/CMP4-01S see: 025-871
' I 1
32.0
34.0
Abs. Int.
-3.05e7
¦1.52e7
•f-O.OOeO
RT
Peak annotation: Areas, Centroids
PKD: n/9 Printed 31-Jut-2009 >6:46:25 Page lot 9
-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr: AutoSpec-Premier MM6
Rel. Int.
pn ¦} 100%-
128.0626
Analyte
4a7 93e4
8.40-10.20
0%-
Naphthalene
1.42e9
8.56
Sample ID: Run# II-ACD-M23-3
VSIR expt: pahdb5_0801 GC: pah_db5-SPLT500 Vial: 79
Acq: 30-Jul-2008 21:15:05
User: CEM Datafile: 080730V19
Abs. Int.
1,06e9
-5.28e8
I 1 1 1 I I
Rel. Int.
Fn1 100%-
134.0827
Standard
4o9,59e2
8.40-10.20
0%-
Rel. Int.
Fn 1 100%-
142.0783
Analyte
4o 6.91e3
8.40-10.20
0%-
Rel. Int.
Fn1 100%-
148.0984
Standard
4o 9.6Qe2
8.40-10.20
0%-
Rel. Int.
Fnt 100%-
152.1410
Standard
4o7.91e2
8,40-10.20
0%-
ES-Naplrtl >ne
1.22e
8.5 /
8.8
9,0
9.2
9.4
9.6
9 8
		f 1
8,6
"¦"rr
8.6
8.6
8.6
8.8
i	r	j""T""T	
9.0
' I ' 1 ' 1 I ' 1 1 ' I '
9.2	9.4
9.6
2-Methylnaphtha!ene
1.6&e"
1 I '
8,8
1 I ' ' 1 1 I ¦ ' 1 ' I '
9.0	9.2
\ I | I 1 I I |
9.4
T—j—"»—r—r i |—j1 -r i i i |
9.6	9.8
ES-2-MeU^tnaphtha
'I 1 1 11 1 '
8.8
"j	i	t	t	!¦	I"1 r
9.0
9.2
9.4
3.82e4
1 I ¦ ¦ ' * I
9.6
JS-Methylnaphthale
3.57e4
9,69
' I '
9.8
1 I 1 1 1 1 I 1
8.8
g'o'
9.2
¦ I '
9,4
9.6
I
9.8
10.0
-O.OOeO
10.2 RT
Abs. Int,
- 9.44e4
-4.72e4
O.OOeO
¦¦r	f	r	i			r
10.0	10.2 RT
Abs. Int.
-1 28e8
¦6.42e7
O.OOeO
| i i i i | i r i
10.0	10.2 RT
Abs. Int.
-4,87e4
-2.43e4
10.0
¦O.OOeO
10.2 RT
Abs. Int.
r3,82e4
-1.91e4
I | I
10.0
O.OOeO
| 1 I » I
10.2 RT
Rel. Int.
Fn 1 100%
130.9920
QC Check
8.40-10.20
I I I I
Abs. Int.
5.83e7
2.92e7
O.OOeO
10.2 RT
Results: P:\P94O0_P9499\P9464_6O42 PAH\resources\P9464_6042_PAH_007-SPL500utp_res. saved 31-Jul-2008 16:23 (CM)	Peak annotation Areas. Centroids
AP UttraTrace-Pro V3.992 User/System: CM/CUP4 015 cc 7347. 5650. 6210, 8314. 4442 see 025-671	Revised: 31-JuI-2008 16.21:48 (CM) Printed: 31-Ju!-2008 16:46:34 Page 2 Of 9
-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr: AutoSpec-Premier MM6
Sample ID; Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 79
Rel. Int.
Fn 2
152.0636
Analyte
4o 3.46e4
11.50-12.30
0%-
Acenaphth^lei
T-1"
11.5
Acq: 30-Jul-2008 21:15:05
User: CEM Datafile: 080730V19
Abs. Int.
1 ,T2e8
•8.58e7
1 I '
11.7
11.8
1 I
11.9
12.0
• i •
12.1
Rel. Irit
Fn2 100%-q
158.0827
Standard
4o 1,30e3
11.50-12.30
0%-
ES-Acenagtittiytene
11.55
1.59e4
11.90
r-1-
11.5
Rel. Int.
Fn 2 100%-
154.0783
Analyte
4a1.39e4
11.50-12.30
0%-
11.5
Rel. Int.
Fn 2 100%-
160.0984
Standard
4o1.44e3
11.50-12.30
0%-
11.5
Rel. Int.
Fn 2 100%-
164.1410
Standard
4cr 8 10e2
11.50-12.30 :
0%-
11.5
¦"I	|	r	*	*	i	j	tm
11.6
I J > 1 I I I I I 1 I I
11.7	11.8
	t	i	[	r	i	t	f	j	r	»	r	r	y	t	r	t	i	|	t1"
11.9	>2.0
Acenaphthene
1 I '
11.6
11.7
11.8
11.91
12.1
119
ES-Acenaphthene
3.26©4
11.90
1 I "
12 0
1 I 1
12.1
12.2
¦"f my 11	r"f'"
12.2
12.2
t""-
•O.OOeO
12.3RT
Abs. Int.
4.83e4
•2.42e4
¦O.OOeO
12.3 RT
Abs, Int.
8,03e6
-4.02e6
¦O.OOeO
12.3 RT
* I ¦"
11.6
¦ I "
11.7
11.8
JS
11.9
Abs. Int.
-3.47e4
1.73e4
O.OOeO
12.0	12.1	12.2	12 3 RT
-Acenaphthene
2.58e4
11.84
i | i i i r | f
11.6
11.7
i | i > i i | i i r t ( i
11.8	11.9
1 ] I I I I | I I I ! | I
12.0	12.1
I I | I I I I | I I I I | I 1 I I
12.2
Abs. Int.
-3.11e4
1.55e4
¦O.OOeO
12.3RT
Rel. Int.
Fn 2 100%:
168.9888
QC Check
11.50-12.30"
Abs. Int.
-7.00e7
-3 50e7
o%-r
11.5
'I 1 ' 1 1 I 1
11.6
i | i i i i | i i i—i—|—»	t	r	t	i	*	r	r	r
11.7	11.8	11.9
12.0
I I | I I > I | I < t I | I I I I ] I
12,1	12.2
-O.OOeO
Results: P:\P9400_P9499\P9464_6042 PAH\msOumeSlP9464_6042_PAH_007SPL500Mtp_res, saved 31-Jul-2008 16:23 (CM)
AP UltraTrace-Pro V3.992 User/System: CM/CMP4-015 cc: 1116, 4414, 9777, 7547, 0171 see: 025-87?
12.3 RT
Peak annotation: Areas, Centmids
Revised: 31-Jul-200S 16:21:50 (CM) Printed: 31-Jui-2008 16:46:44 Page 3 of S

-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_080t GC: pah_db5-SPLT5Q0 Vial: 79
Ret. Int.
100%
Fn 2
166.0783
Artalyte
4o 1,64e4
12.70-16,50 H
Fluorene
5.44e7
13.03
0%-
Acq: 30-Jul-2008 21:15:05
User: CEM Dataflle: 080730V19
Abs. Int.
-3.50e7


Rel. Int.
100%
Fn 2
172.0984
Standard
40 8.42e2
12.70-16.50
Rel. Int.
100%-,
Fn 2
178.0783
Arialyte
4o 5.08e3
12.70-16.50
0%-
Rel. Int.
100%-
Fn 2
184.0984
Standard
40 1 15e3
12.70-16.50
0%-
13.0
ES-Fluorene
3.2364
13.02
135
r|T~i i
14.0	14.5
¦1.75e7
i—i-0.00e0
-T—r—|—i—|—|—r—|—I—I—I—*—|—I—*—I—I—I—I—I—I—I—p-i—1—I—1—|—f—!—i—
15.0	15,5	16,0	RT
T
16.0
Phenanthrene
3,71e8
15.25
X
-i—r—i—r—i—r*
i urthracei
4.Q4e7
15.37
\ A

Abs. Int.
-3.35e4
1.67e4
—|—i—i—i—i—0. OOeO
RT
Abs. Int.
2,30efi
-1.15e8
13,0
13.5
14.0
14,5
15.0
15.5
16.0
ES-Phenanthrene
6.8864
15,25
t | I I I I | I 1
13.0
~i—|—»—i—i—i—|—i—i—i—i—|—i—i—i—i—j—i—i—i—i—j—!—i—i—i—|	r i
13.5	14.0	14.5
¦O.OOeO
RT
Abs. Int.
- 5.13e4
•2.56e4
O.OOeO
I | I I I I | I 1 I I { I I I I | 1 J I I | I I I I | I I I I
15.0	15.5	16.0	RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.70-16.50"
0%-
1 1 1
13.0
' I 1
13.5
14.0
' 1 "11 ¦'
14.5
"T	T	1	V"
15.0
15.5
1 I 1
16.0
Abs. Int.
-7,12e7
3,56e7
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAH\resourxs\P9464_6042_PAH^OO7SPL5D0ulp_res. saved 31-Jul-200B 16:23 (CM)	Peak annotation: Areas. Centmids
AP UttraTrace-PrO V3.992 User/System: CM/CMP4-015 cc: 6606, 9005,1/17, 7149 sec: 025-871	Revised: 31-Jul-200S f6:/6:5S (CM) Printed 31-Jul-2008 16 46:54 Page 4 of 9
-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 79
Rel. Int.
100%-
Fn 2
176.1410
Standard
4o 1.18e3
12.00-16.50
0%-
12.0
SS-Fluorene
2,59e4
12.95
wW*VAy\j
Acq: 30-Jul-2008 21:15:05
User: CEM Datafile: 080730V19
Abs, Int.
-2.83e4
6.05e3
15.26
12.5
13.0
I j
13.5
I I j ! ¦ I 1
14.0
-!	|	I	I	! ' *
14.5
1 ' I 1
15.0
1 I 1 '
15.5
Rel. Int.
100%-
AS-Anthracene
1.37e4
15.33
Fn 2
188.1410
Standard
4a1.33e3
12.00-16.50

120
12.5
| t r i r | r
13.0
| I I 1 I | I I t I | I
13.5
14.0
| 1 f I I | I I 1 I
14.5
' l ' " 1 ' "l	
150
15.5
16,0
160
¦ 1,42e4
-O.OOeO
RT
Abs. Int.
r 1.99e4
•9 93e3
¦O.OOeO
RT
Rel. Int.
100%-
Abs. Int.
-7.12e7
Fn 2
168.9888
QC Check
12.00-16.50
-3.56e7
0%-
12,0
_r
¦ i 1
12.5
13.0
i—i—|—i—r-
1 I 1
13.5
—>—i—i—| i i
14.0
' I 1
14.5
T
15.0
15.5
16.0
-O.OOeO
RT
Results: P:\P9400_P9499V9464_6042 PAtmsources\PS4S4_e042_PAH_0O7-SPLSO0,utp_res, saved 31-M-2008 16:23 (CM)	Pgak annotation: Areas, Centrums
AP UltraTrac&Pro V3 992 User/System: CM/CMP4-015 cc: 7333. 0084 see: 025-871	Revised 31-M-2008 16 21:39 (CMj Printed: 31-Jut-2008 16:47:03 Page 5 of 9
-------
AP Lab ID: P9464_6Q42_PAH_007-SPL500
Instr; AutoSpec-Premier MM6
Rel. Int.
pn3 100%-
202.0783
Analyte
4a 1.55e4
17.50-22-50
0%-
Rel. Int.
3 100%-
208.0984
Standard
40 3.61 e3
17.50-22.50
0%-
Fluoranthene
I.i3e8
18.13
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 79
Pwerie
9.12e7
18.69
A.
18.0
ES-FIuoranthene
6 05(54
18.12
19.0
18.0
-i	'	r-
19.0
Acq: 30-Jul-2Q08 21:15:05
User: CEM Datafile: 080730V19
Abs. Int.
-6.62e7
20.0
20.0
"I 	T	1	1""
21.0
3.31e?
¦ |—i—i—i—i—|—i—i—i—i—f—i—i—r—-i—L-O.OOeO
21.0	22.0	RT
Abs. Int.
-4.91e4
•2.45e4
-i—i | i—i—i—i—*— O.OOeO
22.0	RT
Rel. Int.
Fn 3 100%-
205.0883
Standard
4o2.83e3
17.50-22.50 :
0%-
2.74e5
19.37
ES-Pyrene
1.36e5
18.68
Rel. Int.
Fn 3 100%-
228.0939
Analyte
4a 6.07e3
17.50-22.50
0%-
2.02e5
17.87
6 5Be4
2.53e4 '1 ,8-05'
17.6^
	1	1
18.0
18.0
19.0
19.0
20.0
¦"—i—1—1—1—¦—r
21.0
BenzfalRnthracene
n.32e7,
21.621
4.15e6
21.08
A.
20.0
21.0
Abs. Int.
-1.71e5
-8.57e4
-O.OOeO
RT
Abs. Int.
-8,32e6
¦4.16e6
22.0
0 OOeO
RT
Rel. Int.
Fn 3 100%-
234.1140
Standard
4o 1,36e3
17.50-22.50
0%-
18.0
19.0
20.0
21.0
ES-8enz(a)Anthrace
3 26e4
21.62
22.0
Abs. Int.
-3.10e4
1.55e4
-O.OOeO
RT
Rel, Int.
Fn3 100%-
218.9856
QC Check
17.50-22.50
Results: P:\P9400_P9499\P9464_6042 PAH]resources\P9464_6042_PAH_007-SPL500.utp_res. saved 31-Jul-2008 16 23 (CM)
AP UltraTrace-P/o V3.992 User/System CM/CI4P4-015 cc: 2758, 8302, §702. 8003, SS20 see: 025-871	Revised:
22.0
Abs. Int.
3,75e7
1.87e7
-i—i—i—O.OOeO
RT
Peak annotation: Areas, Centroids
31-JUI-2008 16:21:03 (CM) Printed 31-Jul-2008 16 47'13 Page 6 of 9
-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr: AutoSpec-Premier MM6
Rel. Int.
100%T
Fn 3
212.1410
Standard
4a3.13e3
18.00-20.00
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 79
Rel. Int.
100%
Fn 3
244.1974
Standard
4a 1.13e3
18.00-20.00
JS-Pyrerie
4.4De4
18.64
Acq: 30-Jul-2008 21:15:05
User: CEM Dataflle: 080730V19
Abs. Int.
-4.35e4
2.18e4
I ( i i t | < i r	O.OOeO
Abs. Int.
-2,46e4
SS-Te
2.4
19.04
0%-J-,
1,23e4
O.OOeO
RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
18.Q0-2Q.00"
Q%-
' 1 I 1
18.2
18.4
18.6
1 I I I 1
18.8
' I ' ¦ ' 1 t 1 1 1 1 j 1
19.0	19.2
l i i i i f i i > i I
19.4
19.6
19,8
Abs. Int.
-3.70e7
¦1.85e7
•O.OOeO
RT
Results: PW400_P9499\P9464_6042 PAHtesouKes\P9464_6042_PAH_007-SPLS00.utp_rB5. saved 31-Jul-2008 16:23 (CM)	Peak annotation: Areas. Centmids
AP Ultra Trace-Pro V3 892 User/System CM/CMP4-015 cc 0233. 6268 see: 025-871	Revised: 31-M-2008 16:21:57 (CM} Printed. 31-Jul-2008 76.<7.22 Page 7 of 9
-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
252.0939
Analyte
4o 3.88e3
23.50-28.00
0%-
Rei. Int.
100%-
Fn 4
258.1140
Standard
4o 7,03e2
23,50-28.00
0%-
Rel. Int.
100%-
Fn 4
256,1073
Standard
4o 1,25e3
23.50-28.00
0%-
Rel. Int.
100%-
Fn 4
264.1692
Standard
4o S.88e2
23.50-28.00
0%-
24.0
24.0
24.0
I 1 • 1 ' i 1
24.0
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Via!: 79
BenzfbJFIucranthene
1.31e7 /¦
24.S y
Ben IFIuoranlherie
7,84e6 ,
l 25.06 /
"T'~
24.5
Beni(e)Pyrene
7.l8e6 y
25.96 '
Acq: 30-Jul-2008 21:15:05
User: CEM Datafile: 080730V19
Abs, Int.
-2.61e6
BenzfalPyrene/^
4.06e6
26.20
26.0
TT' I i i i i | • i i r i | i I i i | i
26,5	27.0
1.31e6
27.5
ES-8enz(b)Fluarant
6,iSe4
24,91
24,5
¦ I"1-
25.0
	|	»	r,M,T	r	f-r-i—i—i | i * t i j i i i » | i * i
25.5	26.0
25.95 26 16
265
27.0
27,5
-O.OOeO
RT
Abs. tnt.
-3.48e4
• 1,74e4
•O.OOeO
RT
24.5
•""»	|	1	%	*	I	|	>	I	»	I ) > i i r [ i i i i | i i f i | i
25,0	25.5	26.0
26.5
ES-Perylene
3.1064
26.38
27.0
I \ I | %
27,5
Abs. Int.
-2.95e4
•1.47e4
JS-Benz(a)Pyrene
6.14e3
26.06
™i—i—i—i—i—i—*- O.OOeO
RT
Abs. Int.
-2.78e4
1.39e4
24.5
25.0
i i i i I i i i i I i i i i I i i i i I i i i i I i i i i I
25.5	26.0	26.5
27.0
27,5
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28 00'
0%-
I I I | t
24.0
24.5
25.0
	|	1	J	f	f""|	r"
25,5
26.0
26.5
27.0
""r""r	i			t	T-
27.5
Abs. Int.
- 3 05e7
1.52e7
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHVesources\P9464_6042 PAH 007-SPL500 utp_rvs, saved 31-Jul-2008 16:23 (CM)
AP UltraTrace-Pn} V3 992 User/System: CU/CUP4-015 cc: 3907, 6470, 6463, 0405 see: 025-871
. Peak annotation: Areas, Cenlmids
Revised: 31-Jut-2008 16:22:48 (CM) Printed: 31-M-2008 16:47:32 Page 8 of 9
-------
AP Lab ID: P9464_6042_PAH_007-SPL500
Instr: AutoSpec-Premier MM6
Rel. Int.
Fn 4 100%-
276.0939
Analyte
4o 5.11e3
29.0-36.0
0%-
29.0
30.0
Sample ID: Run# II-ACD-M23-3
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT500 Vial: 79
lnd(l23-cd)Pvrene
2.66e6
31.73
Benz(^hf|Perylene
33.30
I { I 1 f
31.0
1 i 11 11 I
32.0
' I '
33.0
Acq: 30-Jul-2008 21:15:05
User: CEM Datafile: 080730V19
Abs. Int.
-3.46e5
34.0
35.0
1 73eS
•O.OOeO
36.0RT
Rel. Int.
Fn 4 100%.
282.1140
Standard
4cr 1,82e3
29.0-36.0
0%-
29.0
30.0
31.0
32.0
33,0
34.0
35.0
Abs. Int.
-2.23e4
>1.11e4
¦O.OOeO
36.0 RT
Rel. Int.
Fn 4 100%
288.1342
Standard
4o 7 53e2
29.0-36.0
Rel. Int.
Fn 4 100%
278.1096
Analyte
40 3.87e3
29.0-36.0
Dibenzlah Anthra
33.0
34.0
35.0
Abs. Int.
-1.99e4
9,96e3
OOeO
36.0 RT
Abs. Int.
9.10e4
4.55e4
OOeO
36.0 RT
Rel. Int.
Fd 4 100%-
284.1297
Standard
40 8 25e2
29.0-36.0
0%-
29.0
I I I I I I 1 T
30.0
31.0
» [ I I I \ | I I » I—-p"
32.0
33.0
34.0
| 1 f I » | f 1
35.0
flit
Abs. Int.
-1 67e4
8 33e3
O.OOeO
36.0 RT
Rel. Int.
Fn 4 100%
292.9824
QC Check j
29 0-36 0
29.0
Results: P:\P9400_P9499\P9464_6042 PAH\resources\P9464_6O42_PAH_007SPLS00.utp_res. saved 31-Jul-2008 16:23 (CM)
AP UltmTrace-Pm V3.992 Usgr/Sysiem: CM/CMP4-015 cc: 8407, 0769,~S007. 6155, 9152 see: 025-871
T
35.0
Abs. Int.
-3.05e7
1.52e7
-O.OOeO
36.0RT
Peak annotation: Areas. Centroids
Revised: 31-Jut-200B 16:23:14 (CM) Printed: 31-Jul-2008 16 47:41 Page 9 ot 9
-------
AP Lab ID: SB_08073Q_PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User: CEM Datafile. 080730V20
Rel. Int.
100%-
Fn 1
130.9920
QC Check
7.02-10.55
0%-
.I .
7.5
8.0
1 I '
8.5
1 I '
9.0
9.5
10.0
~i—f-O.OOeO
10.5 RT
Rel. Int.
100%-
Fn 2
168.9888
QC Check
10.59-17.00"
0%-^—i—i—i—|—p-
11.0
I ' ' ¦ ¦ I ¦
12.0
I | I I I I | I I I I j
13.0
¦ I '
14.0
15.0
16.0
- O.OOeO
17.0RT
Rel. Int.
100%-
Fn 3
218.9856
QC Check
17.02-23.00"

0%-
I I I I I I t t
18.0
19,0
20.0
21.0
t r i i | i i i
22.0
-O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.02-35.01
0%-

24.0
26.0
28.0
30.0
32.0
34.0
Results: P:\P9400_P9499\P9464_BQ42 PAHVesourcesiSB_080730_PAH_VD.utp_ms. saved 31-Jul-2008 15:11 (CM)
AP UttraTcace-Pro V3.99Z UserfSystem: CM/CMP4-015 see: 085-777
Peak annotation: Areas, Centroids
PKD: n/a Printed: 3l-Jul-2008 >6 47 52 Page 1 of 9
-------
AP Lab ID: SB_080730_PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSfR expl: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User: CEM Datafile: 080730V20
Rel. Int.
pn i 100%-
128.0626
Analyte
4o 1.13e4
8.40-10.20
0%-
'T I '"i" I	| I
, y.		I, ^ i[ 'pi | t I i-j-TT"! I |	I I 1 | i I I ln j T'
8.6	8.8	9.0	9.2	9.4	9.6
»	I1 ¦' ''
9.8
10.0
i' i i i i i
Abs. Int.
-1.71e6
•8.57e5
•O.OOeO
10.2 RT
Re!. Int.
pn -j 100%-
134.0827
Standard
4o1.36e3
8.40-10.20
0%-
'I" '1	T	T	I	I	J	r..T>-j-r
8.6
' I 1 1 1 ¦ ) '
8.8
	T"
9.0
T'-
9.2
9.4
,MJ	T	I	t	t,mJ	r"TM,T""1	|	T	»""T	|""^""T,,,,fMMTMMTMMJ,M
9.6	9.8
10.0
Abs. Int.
1.7164
-8.53e3
O.OOeO
10.2 RT
Rel. Int.
Fn 1 100%
142.0783
Analyte
4a 8.97e3
8.40-10.20
10.0
Abs. Int.
2.51e5
1 26e5
OOeO
10.2 RT
Rel. Int.
Fn1 100%-
148.0984
Standard
4o 1.2363
8.40-10.20
0%-
'"'"1	1"
8.6
8.8
9.0
I I t 1 I
9.2
9,4
Abs. Int.
1.45e4
7.25e3
O.OOeO
¦g	[¦	*	i	i	i	|	i	i	r	i	|	\	»	t	i1	|	t	i	i	I"" j1	i	i ¦¦ "i	»¦¦¦¦ |	r""t	t	r
9.6	9.8	10.0	10,2 RT
Rel. Int.
1 100%
152.1410
Standard
4a 1.37e3
8.40-10.20
0%'
Abs. Int.
1.54e4
7.68e3
i—i—O.OOeO
10.2 RT
Rel. Int.
p„ ! 100%-
130.9920
QC Check
8.40-10.20 "
0%-
' 1 I 1 ' | » I
8.6
' I 1 '
8.8
¦"i	i	i	i	rm
9.0
i | < i i i | i i i * j i
9.2	9.4
Results: P:\P9400_P9499\P9464_6042 PAH\resources\SB_080730_PAH_VDvtp_nes. saved 31-Jut-2008 15:11 (CM)
AP UKraTrace-Pro V3.B92 User/System: CM/CMP4-015 cc: 4886, 552S~ 9933, 2275, 9435 see: 085-777
¦*	|	T,mi	i	i	j	i	r	f	t	i""*-
9,6	9.8
10.0
Abs. Int.
-5,36e7
¦ 2.68e7
¦O.OOeO
10.2 RT
Peak annotation: Areas, CentrokSs
PKD: 31-M-200S 15:10:43 Printed: 31-Jul-200B 16:48:02 Page 2 Of 9
-------
AP Lab ID: SB_080730_PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User: CEM Datafile: 080730V20
Rel. Int.
Fn 2 100%1
152.0636
Analyte
4tj 5.11e3
11.50-12.30
I I I I I »
11.5
' I ' " 1 ' I 1
11.6
11.7
11,
11.9
12.0
y | i
12.1
It | I
12.2
Abs. Int.
-6.01e5
¦3.00e5
¦O.OOeO
12.3 RT
Rel. Int.
Fn 2 100%-
158.0827
Standard
4o1.43e3
11.50-12.30
0%-
m»	t	*	\	i	t	t	i	|	»""
11.5	11.6
I | I I « I | I I I I | I I
11.7	11.8
11.9
"¦¦y	r		r	*	r	r	|	t	t	v	i	|	r	r"
12.0	12.1
12.2
Abs. Int.
-1,59e4
•7,96e3
•O.OOeO
12.3 RT
Rel, Int.
Fn 2 100%-
154,0783
Analyte
4o6,13e3
11,50-12.30
0%-
6.14e4
11.88
r-'-
11.5
11.6
| I I I I | t
11.7
11,8	11.9	12.0
-r-j-r
12.1
Abs. Int.
-4.73e4
2.37e4
O.OOeO
12,2	12.3 RT
Rel. Int.
Fn 2 100%'
160.0984
Standard
4a 1.77e3
11.50-12.30
0%'
r-r-
11.5
' I 1
11.6
11.7
11.8
' I '
11.9
i % j y i i t f i t * i ; ; t i > | i
12.0	12.1
' I "*
12.2
Abs. Int.
-1.46e4
•7.30e3
¦O.OOeO
12.3 RT
Rel. Int.
Fn 2 100%
164.1410
Standard
4a 1 35e3
11.50-12.30
0%-
11.5
11.6
I'Ti	Til—T"—J	T	f	1	T	(	I I 1 1 I | r I 1 I
11.7
11.8
119
12.0
r ¦ 1 '' • i
12.1
12.2
Abs. Int.
-1.56e4
•7.82e3
¦O.OOeO
12.3 RT
Rel. Int.
Fn 2 100%
168.9888
QC Check
11.50-12,30
Abs. Int.
50e7
3.25e7
O.OOeO
12.3 RT
Results: P:\P9400_P9499\P9464_6Q42 PAH\resources\SB_080730_PAH_VO utp_rvs. saved 31-Jul-2008 15:11 (CM)
AP UltmTmce-Pm V3.992 User/System: CM/CMP4-Q1S cc: 438$, S113, 8280,5241. 1501 see: 085-777
Peak annotation: Areas. Centmids
PKD: 31-Jul-2008 15:10:43 Printed: 31-Jut-2008 16:48:11 Page 3 of 9
-------
AP Lab ID: SB. 080730.„PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User: CEM Datafile: 080730V20
Re I. Int.
100%'
Fn 2
166-0783
Analyte
40 4.89e3
12,70-16,50
2.69e5
3.44e4 3,51
12.79 12,
4.20e4
13.51
I ) I
13.5
| I I I I | I
14.0
I I 1 I | 1 I I I | I I I I ( I I
14,5	15,0
15.5
I 1 I | I I T V | I I
16.0
Abs. Int.
-1,69e5
• 8.46e4
¦O.OOeO
RT
Ret. Int.
100%-
Fn 2
172.0984
Standard
4a1.30e3
12.70-16.50
Q%-
13.0
13.5	14,0	14,5
' I '
15.0
	f	|	|	T	f	f	T	\	T	1	1	1" '| 1
15.5	16.0
Abs. Int.
-2.20e4
-1.10e4
•O.OOeO
RT
Rel Int.
100%-
Fn 2
178.0783
Analyte
4cr 5.52e3
12.70-16.50
0%-
13.0
13.5
2.96e6
15.24
14.0
T ' ¦¦
14,5
15.0
4.2Se6
15,36
La
| -ftr, 'i|ii | | | [ | [
15.5
' I '
16.0
j i i i
Abs. Int.
-1.83e6
9.13e5
O.OOeO
RT
Rel. Int.
100%
Fn 2
184.0984
Standard
4o1.19e3
12.70-16.50
t | 1 I 1 I | I I I I ) I 1 I »	f~
15,0	15.5
-i—i—i—i—i—r
16,0
Abs. Int.
1,56e4
7.81e3
-O.OOeO
RT
Rel. Int.
100%
Fn 2
168.9888
QC Check
12.70-16.50'
Abs. Int.
6.65e7
3.33e?
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PAHVBSOuKBS\SB_080730_PAH_VDutp_res. saved 31-Jul-2008 15 11 (CM)
AP UltraTrace-Pro ¥3.992 User/System: CWCMP4-015 cc: 1636. 5(379, 3200, 3189 sec: 085-777
Peak annotation: Areas, Centmids
PKD 31-Jul-2008 15 10:43 Printed: 31-Jul-200S 16:48:20 Page 4 of 9
-------
AP Lab ID: S8_08Q73G_PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User: CEM Datafile: 080730V20
Ret. Int.
100%-
Fn 2
176.1410
Standard
4o 1.15e3
12.00-16.50

Rel. Int.
100%-
Fn 2
188.1410
Standard
4ot.57e3
12.00-16.50
0%-
1 ' I ' 1 ' ¦ I '
13.5
12.0
12.5
13.0
	*	»	i	r	j	i1	»	i	i	j	<	* ¦
14.0
14.5
15.0
' I '
15.5
16.0
Rel. Int.
100%-
Fn 2
168.9888
QC Check
12.00-16.50"
0%-
12,0
I 1 '
1 | I
12.5
13.0
1 I ' 1
13.5
"T""l	!	f	
14.0
14.5
' I '
15.0
T
' • I 1
15.5
16.0
Results: P:tP9400„P9499\P9464_6042 PAMi*souicos\SB_080730_PAH_ VD utp_res. saved 31-Jul-ZOOe 15:11 (CM)
AP tJltraTrace-Pm V3.992 User/System: CM/CMP4-G15 cc: 2771. 4589 see: 085-777
Peak annotation: Areas. Cent/aids
PKD: 31-JUI-200S 15:10:43 Printed 31-Jul-2008 16 48 30 Page 5 of 9
-------
AP Lab ID: SB_080730_PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User. CEM Datafile: 080730V20
Rel. Int.
Fn3 1°0%
202.0783
Analyte
4o 5.47e3
17,50-22.50 1
0%-
1.62e6
3.8?eS
18.34
	i
1.48e6
18.67
I " I"'1 I
18.0
~l—
19.0
T f	I ' I" I' I" | I I 'I'l	¦!	I "I'l I I t ¦ t [ I f ' I
20.0	21.0	22.0
Abs. Int.
-1.0186
¦ 5,04e5
¦O.OOeO
RT
Rel. Int.
Fn 3 100%-]
208.0984
Standard
4o3.82e3
17.50-22.50
0%-
Rel. Int.
Fn 3 100%-,
205.0883
Standard
4o1.94e3
17.50-22.50
0%-
18.0
—(	
19.0
"T 1 '1	1	~1~
20.0
21.0
22.0
Abs. Int.
-3.15e4
•1.56e4

—I—
18.0
19.0
20.0
ivtfiirtjtiivjif
21.0	22.0
•O.OOeO
RT
Abs, Int.
1.68e4
8.42e3
•O.OOeO
RT
Rel. Int.
Fn 3 100%
228.0939
Analyte
4 o 2.29e3
17.50-22.50 }
0%-
i t ;
""I	I	T1"
""I	t	T	I""
18.0
19.0
20.0
1.10e5
21.06
_JL_
21.0
3.5tte
21.61
T" f
22.0
Abs. Int.
-2.52e5
1.26e5
•O.OOeO
RT
Rel. Int.
Fn 3 100%-]
234.1140
Standard
4o 1,40e3
17,50-22.50
Abs. Int.
-1,63e4
8.13e3
OOeO
Rel, Int.
pn 3 100%-
218,9856
QC Check
17,50-22.50
Results P:\P9400_P949W9464_6042 PAHVesources\S8 0B0730_PAH_VDMtp_tes. saved 31-Jul-2008 15:11 (CM)
AP UlSmTmce-Pm V3.992 User/System: CWCMP4-015 cc: 5671, 1984, 2404, 0981, 6596 see: 085-777 .
22.0
Abs. Int.
-3,57e7
1,79e7
-O.OOeO
RT
Peak annotation: Areas, Centmids
PKD: 31-Jut-2006 15:10:43 Printed: 31-JUI-2Q06 16 48:40 Page 6 of 9
-------
AP Lab ID: SB_Q8073Q„PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonarie
VSIR expt: pah_db5_0801 GC; pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User: OEM Datafile: 080730V20
Rel. Int.
100%-
Fn 3
212.1410
Standard
4 o 3.07e3
18,00-20.00
0%-
—I—|—I—r-*—!—| 1 ! ' 1 "f |- I—ll»|?ril|lfl—I | I I f I | I T-TM I "| " T"' F T ' T | f I I I J I ! I—!]'**![
18.2
18.4
18.6
18.8
19.0
19.2
* I i i i i I i i i i I i
19.4	19.6
O.OOeO
Abs. Int.
-1.88e4
•9.39e3
19.8
RT
Rel. Int.
100%-
Fn 3
244.1974 •
Standard
4ct 1.26e3
18.00-20.00 •
0% ¦¦¦'¦¦¦¦¦¦¦¦ 			 , r
18.2
	i			i	r'T1"!	[		|	|		
18.4	18.6	18.8
		|	|		j	tMMr.M|M.M,	
19.0	19.2
llllfilfllll
19.4
19.6
19.8
Abs. Int.
-1,78e4
8.90e3
¦ ] ¦ i ¦ i 0.OOeO
RT
Rel. Int.
100%-
Abs. Int.
-3.5067
Fn 3
218.9856
QC Check
18.00-20.00
¦ 1.75e7
0%-
' I '
18.2
18.4
18.6
18.8
19.0
Results; P:\P940G_P9499\P9464_6O42 PAH\re$Ources\SB_080730_PAH_VD utp_nes, saved 31-M-2008 15:11 {CM}
AP UttraTrace-Pm 1/3.992 User/System: CM/CMP4-01S cc 5364, 3360 see: 085-777
19,2
	'	1		
19.4
1 I '
19.6
19.8
-O.OOeO
RT
Peak annotation: Areas, Centmids
PKD: 31-Jut-2008 15:10:43 Printed: 31-M-2008 16:48:49 Page 7 ot 9
-------
AP Lab ID: SB_080730_PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID: Nonane
VSIR expt: pah_db5_0801 GC: pah_db5-SPLT5 Vial: 2
Acq: 30-Ju1-2008 21:54:36
User: CEM Datafile: 080730V20
Rel, Int.
100%-
Fn 4
252-0939
Analyte
4a 4.08e3
23.50-28.00
0%-
D.uoeS
25.9?
24.0
24.5
25.0
—i—i—j—i—i—i—j—|—i—i—!—i—|—i—r-
25.5
26.0
-i—|—i—i—i—i—|—r-
26.5

27,0
27.5
Abs. Int.
-1 65e5
-8,23e4
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
258.1140
Standard
4o 7.68e2
23.50-28.00
0%-
f I 1 I f I I I 1 I I I f I 1 1 t
24.0
24.5
25.0
25.5
26.0
26.5
27.0
i I i i i r | * i i
27.5
Abs. Int.
-1 44e4
7.20e3
-r-1-O.OOeO
RT
Rel. Int.
100%
Fn 4
256.1073
Standard
4o1.21e3
23.50-28.00

0% I i i i i |
t-i—r-|—i—r-T—r*
24.0
"i—|—i—i—i—i—|—I—<—r—i—| i i—r—I | >—i—i—i—|—i—i—i—r—i—i—r—i—1—|—i—i—<—r—j—r—i—i—r—[—>—i—r—i—|—r—r-
24.5	25.0	25.5	26.0	26.5
27.0
' i <-«-v-nr
27.5
Abs. Int.
1,51e4
¦7.56e3
, ¦ , • O.OOeO
RT
Rel. Int.
100%-
Fn 4
264.1692
Standard
4a 1.23e3
23.50-28.00
0%-
24.0
24.5
25.0
t t i [ r i t | t ^ i r | i i i r | t < r > | i r i i ( t > f i | i
25.5	26.0	26.5	27.0
27.5
Abs. Int.
-1.65e4
•8.23e3
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
292.9824
QC Check
23.50-28,00'
0%-
24.0
24.5
25.0
25.5
26.0
26.5
J 1 I 1 » j 1
27.0
I I t | 1 I 1 I
27.5
Abs. Int.
-2.91e7
I.46e7
.ii- O.OOeO
RT
Results: P:\P9400_P9499SP94S4_6042 PAH\msoureesSSBjOB0730_PAH_VDMtp_res, saved 31-Jul-200a 15:11 (CM)
AP UltmTrace-Pro V3.992 User/System: CMJCMP4-015 cc: 3649, 9138, 2957, 0967 see: 085-777
Peak annotation: Areas, Centroids
PKD: 31-Jui-Z00a 15:10:43 Printed: 31-Jul-200B 16:48:59 Page B Of 9
-------
AP Lab ID: SB_Q8Q73Q_PAH_VD
Instr: AutoSpec-Premier MM6
Sample ID; Nonane
VSIR expt: pah_db5_0801 GC; pah_db5-SPLT5 Vial: 2
Acq: 30-Jul-2008 21:54:36
User: CEM Datafile. 080730V20
Rel. Int.
pn 4 100%—
276.0939
Analyte
4o 2.87e3
29.0-36.0
0%-
8.69e4
5.0184
33.23
31.60
3.7364
31.05
29.0
30.0
31.0
32.0
33.0
I I | I I 1 I | I t I I } t t
35.0
34.0
Abs. Int.
-4.67e4
-2.34e4
•O.OOeO
36.0RT
Re!, Int.
4 100% -
282.1140
Standard
4o 2.35e3
29.0-36,0
0%-

"t	1	1--T-
» I ' > I I I *
29.0
30.0
31.0
mt	i	|	i	i	r	t	|	i	i	i	i	|	i	r	r	r	|	v	r	i	t	j	r	t	r	r"	r--r-
32.0	33.0	34,0
""i	i	t	t	t	t	r	i	i	|	i	r	r	r1"
35.0
Abs, Int.
-1,63e4
8 16e3
I.OOeO
36.0 RT
Rel. Int.
Fn 4 100%-
288.1342
Standard
4o 8.52e2
29.0-36,0
Abs. Int.
1,34e4
6.71 e3
OOeO
36,0 RT
Rel, Int.
pn 4 100%-
278,1096
Analyte
4o 2.38e3
29.0-36,0
0%-
1.4984
31.01

29.0
30.0
' I ' ' ' ' I
31,0
I I I I I 1 "I	f"
32.0
33.0
34,0
Abs, Int.
r2.10e4
105e4
I [ I 1 I i { % I I
35.0
¦O.OOeO
36.0RT
Rel. Int.
Fn4 100%-
284.1297
Standard
4cj 1.20e3
29,0-36.0
0%-

1111
111!
29.0
30,0
31.0
32.0
33.0
34,0
-r-|—r
35,0
I 1 I I I I
Abs. Int.
-1.37e4
¦6.87e3
•O.OOeO
36,0 RT
Rel, Irit,
Fn 4 100%.
292,9824
QC Check
29,0-36.0
—*—i	i	r	|
30.0
Abs. Int.
2.92e7
1.46e7
i i i i 1 0. OOeO
36.0RT
Results: P\P9400_P9499\P9464_6042 PAH\resources\S8_080730_PAH_ VD.utp^res, saved 31-Jul-2008 15:11 (CM)
AP UltraTmce-Pm V3 992 UserfSystem: CWCMP4-015 cc 1955. 674ft 4027. 4704, 2801 see: 085-777
Peak annotation: Areas, Centmids
PKD: 31-M-2008 15:10:43 Printed: 31-M-2008 16 49 OB Page 9 of 9 /
-------
Datafile: 080724V04_EQ
Acquired: 24 Jul 2008 02:52:28
Client ID: MB1_6042_PCB_SDS
Lab ID: MB1 6042 PCB SDS
MB1_6042_PCB^SDS
Name
PCB-77 3 3'4 4'-TeCB
PCB-81 344'5-TeCB
PCB-105 233'44'-PeCB
PCB-114 2344'5-PeCB
PCB-118 23'44'5-PeCB
PCB-173 2'344'5-PeCB
PCB-126 33'44'5-PeCB
PCB-156/157 233'44'5/233144'5'
PCB-167 23 ' 44'55'-HxCB
PCB-!69 33'44'55'-HxCB
PCB-189 233144'55'-HpCB
PCS-209 DeCB
Actual
RT
NocFnd//
NotFnd'
NotFnd^
MotFnd/
30.87 ^
NotFnd /
NotFnd/
NotFnd/
NotFnd/*,
NotFnd/,
NotFnd '
46.62 /
QC
Pred
RRT
1.0006
1.0006
1.0007
1.0007
1.0008
1.0006
1.0005
1.0005
1.0006
1.0004
1.0005
1.0004
ES
PCB-1
9.45 "
0
7047
ES
PCB-3
11.40 '
0
8520
ES
PCB-4
11.62 ~
0
8687
ES
PCB-15 _
16.79 ^
1
2550
ES
PCB-19 /
14.37 '
1
0745
ES
PCB-37 - / 1
22.78 '
1
0878
ES
PCB-54 n y
17.05 ^
0
8144
ES
PCB-77 | J~
Jk 28.92 „
1
3808
ES
PCB-81 I
28.45
1
3585
ES
PCB-104 .
PCB-105 QW
% 21.74'
0
8143
ES
* 31.84'"
1
1919
ES
PCB-114
31.30 '
1
1717
ES
PCB-118
30.85 "
1
1551
ES
PCB-123
30.58
1
1449
ES
PCB-126
34.41 '
1
2881
ES
PCB-15 3
32.41 ^
0
9690
ES
PCB-155
26.52 ^
0
7930
ES
PCB-156/157
36.92 "
1
1035
ES
PCB-167
35.95
1
0747
ES
PCB-169
39.60
1
1838
ES
PCB-170
39.12 ^
0
9006
ES
PCB-180
38.07
0
8765
ES
PCB-188
31.29 *'
0
7207
ES
PCB-189
41.69 "
0
9600
ES
PCB-202
35.76 ^
0
8234
ES
PCB-205
43.83
1
0090
ES
PCB-206
45.27 '
1
0420
ES
PCB-208
41.30 ^
0
9509
ES
PCB- 209
46.60
1
0726
Analytical Perspectives
Wt/Vol: 1
A-level: 20
pg/
PCB_VAB CPSM_080724_PCB_VA
Nominal ES spike: 4000 pg
z
Actual
RRT
1.0004
Diff
Sees
-0.7
1.0005 +0.3
Response
O.OOE+OO
0.00E+00
O.OOE+OO
0.O0E+00
1.06E+05
O.OOE+OO
O.OOE+OO
O.OOE+OO
0.00E+00
0.00E+00
0.00E+00
3.06E+04
Ra
0.58
RRF
To
Checkcode:
1 Noise
yo
DL
1
05/
' 4.18E+03
3.54
1
10
tro
4.18E+03
3.23
0
97
ND
2.60E+03
2.91
0
94 ,
97 /
ND
2.60E+03
2.92
0
10.9
2.60E+03
2.78
0
96
ND
2.60E+03
3 .08
0
98
ND
3.39E+03
3 .44
0
97
ND
2.15E+03
3 .89
0
99
HB
2.15E+03
2.8
0
93 /
ND
2.15E+03
3.18
0
92 y
ND
2.95E+03
3.57
0
91
5. 03
1.32E+03
2.45
0.7066
+1.1
0.8523
+0.2
0.8689
+0.1
1.2550
0
1.0745
0
1.0880
+0.3
0.8143
-0.1
1.3812
+0.7
1.3589
+0.7
0.8138
-0.7
1.1918
-0.2
1.1717
0
1.1550
-0.2
1.1448
-0.2
1.2881
0
0.9689
-0.2
0.7928
-0.3
1.1036
+0.2
1.0748
+0.2
1.1839
+ 0.2
0.9005
-0.2
0.8764
-0.2
0.7205
-0.4
0.9599
-0.3
0.8233
-0.2
1.0091
+ 0.3
1.0422
+ 0.5
0.9509
0
1.0728
+0.6
5.74E+07	3.25
5.91E+07	3.34
4.19E+07	1.60
7.40E+07	1.61
4.06E+07	1.05
6.09E+07	1.07
4.71E+07	0.78
4.87E+07	0.81
4.78E+07	0.82
4.40E+07	1.58
3.86E+07	1.63
3.94E+07	1.57
4.OOE+07	1.59
3.80E+07	1.59
4.32E+07	1.60
3.12E+07	1.26
4.14E+07	1.27
6.77E+07	1.27
3.33E+07	1.26
3.31E+07	1.24
2.63E+07	1.07
2.91E+07	1.06
3.89E+07	1.03
4.08E+07	1.04
3.45E+07	0.89
2.92E-07	0.92
1.89E+07	0.79
2.56E+07	0.79
2.67E+07	1.18

Recv.
0.94 /
92.8
%
0.92 J
97.6
%
0.64
99.4
%
0.99
113
%
0.58
107
%
1.41
110
%
1.12
107
%
1.18
105
%
l.!3 /
107
%
1.27
99.2
%
1.13
97.4
%
1.17
96.4
%
1.17
97.5
%
1.10
98.1
%
1.29 "
95.4
%
1.12
109
%
1.48
110
%
1.23
108
%
1.23
106
%
1.21
107
%
0.90
123
%
1.10
112
%
1.43
107
%
1.53
112
%
1.25
108
%
1.08
114
%
0.73
109
%
0.99 \l
109
%
1.04
109
%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
25%
150%
Page 1 of 5	Printed: 08 06 2008 1:19PM
-------
KB1_6042_PCB_SOS
Nana
SS PCB-28
Actual
RT
19.38 ^
QC
SS
PCB-lll
28.95'"
1
SS
PCB-178
33.83^
1
cs
PCB-28
19.38"
0
cs
PCB-lll
28.95'
1
cs
PCB-178
33.83 X
1
JS
PCB-9
13.38-

as
PCB-52
20.94'

JS
PCB-101
26.71*'

JS
PCB-138
33.45"

JS
PCB-194
43 .44"'

Pred
RUT
0.9259
0838
, 0838
, 0113
Checkcode:
yo

PCB-1
2-MoCB

9.46
1.0011
PCB-2
3-MoCB

11.25
0.9869
PCB-3
4-MoCB

11.41
1.0010
PCB-4
22'-DiCB

NotFnd
1.0012
PCB-10
26-DiCB

NotFnd
1.0146
PCB-9
25-DiCB

NotFnd
1.0011
PCB-7
24-DiCB

NotFnd
1.0119
PCB-6
23'-DiCB

NotFnd
1.0275
PCB-5
23-DiCB

NotFnd
1.0477
PCB-8
24'-DiCB

14.12
1.0560
PCB-14
35-DiCB

NotFnd
0.9258
PCB-11
33'-DiCB

16.27
0.9689
PCB-13/12 34'-/34-
-DiCB
NotFnd
0.9848
PCB-1S
44'-DiCB

NotFnd
1.0009
PCB-19
22'6-TrCB

14.39
1.0011
PCB-30/18 246-/22
•5-TrCB
16.01
1.1129
PCB-17
22 *4-TrCB

16.37
1.1388
PCB-27
23'6-TrCB

NotFnd
1.1517
PCB-24
236-TrCB

NotFnd
1.1599
PCB-16
22'3-TrCB

16.77
1.1664
Analytical Perspectives
Actual
Diff




Checkco de
Y V
REf
Sees
Response
Ra
RRF
Cone
Noise
DL
0.9258
-0.1
6.63E+07
1.06
1.05 /
104 %
30%
135%
1.0837
-0.2
4 .48E+07
1.54
1.19
99.1 %
30%
135%
1.0113
0
2.60E+07
1.09
0.65
102 %
30%
135%
0.9258
-0.1
6.63E+07
1.06
1.48/
114 %
30%
135%
1.0837
-0.2
4.48E+07
1.54
1. 31
97.1 %
30%
135%
1.0113
0
2.60E+07
1.09
0.93
110 %
30%
135%


6.57E+07
1.63






3.93E+07
0.79






3.51E+07
1.58






2.55E+07
1.27






2.38E+07
0.92





Totals
NON-EKPC

EMPC
Dh



Mono-CBS
32.4

32.4
2.84



Di-CBs
302

302
8.2



Tri-CBs
141

158
4.76



Tetra-CB.-
82.6

92.7
3.13



Penta-CB:
43.5

56.5
2.95



Hexa-CBs
23

33.5
2.98



Hepta-CB;
0

0
4.09



Octa-CBs
0

0
3.2



Nona-CBs
0

0
5.01


1.0011
0
1.80E+05
3.00
1.19*/
10.5
8.44E+03
2.58
0.9869
0
1.91E+05
2.71
1.11 ,
11.6
8.44E+03
3.36
1.0012
+0.1
1.82E+05
2.73
1.21 J
10.2
8.44E+03
3.09
-

o.oqe+oo

0.98

1.74E+04
11.2
-

0.00E+00

1.42

1.74E+04
7.68
-

0.00E+00

0.97

1.18E+04
5.39
-

0.0QE+00

0.98

1.18E+04
5.35
-

0.Q0E+00

0.97

1.18E+04
5.4
-

0.00E+0Q

0.92

1.18E+04
5.68
1.0556
-0.3
7.12E+05
SI*
0. 98
39.2
1.18E+04
5.32
-

O.OOE+OO

1.12

1.18E+04
4.66
0.9689
0
4.46E+06
SI *
0. 91
263
1.18E+04
5.71
-

0.00E+00

0.91

1.18E+04
5.72
-

0.00E+00

0.99

1.18E+04
5.26
1.0008
-0.3
5.34E+04
0.89
1.01
5.22
6.60E-03
4.92
1.1140
+1.1
3.50E+05
1.18
1.10
31.4
6.60E+03
4.51
1.1386
-0.2
1.59E+05
0.94
0.96
16.3
6.60E+03
5.15
-

0.00E+00

1.31

6.60E+03
3.79
-

0.00E+00

1.23

6.60E+03
4.03
1.1665
+ 0.1
1.25E+05
1.07
0. 81
15.3
6.60E+03
6.14
Page 2 of 5
Printed: 08 06 2008 1:19 PM
-------
MB1_6042_PCB_SDS
Name
PCB-32 2416-TrCB
PCB-34 2135-TrC3
PCB-23 235-TrCB
PCB-26/29 23'5-/245-TrCB
PCB-25 23'4-TrCB
PCB-31 24'5-TrCB
PCB-28/20 244'—/2 3 3'-TrCB
PCB-21/33 234-/2'34-TrCB
PCB-22 234'-TrCB
PCB-36 3315-TrCB
FCB-39 34'5-TrCB
PCB-38 345-TrCB
PCB-35 33'4-TrCB
PCB-37 344'-TrCB
PCB-54 22'66'-TeCB
PCB-S0/53 22'46-/22'56'TeCB
PCB-45 22'36-TeCB
PCB-51 22'46'-TeCB
PCB-46 22'36'-TeCB
PCB-52 22'55'-TeCB
PCB-73 23'5'6TeCB
PCB-43 22'35-TeCB
PCB-69/49 23'46-/22'45'TeCB
PCB-48 22'45-TeCB
PCB-44/47/65 22'35'-/22'44'-
PCB-59/62/75 233'6-/2346-/24
PCB-42 22'34'-TeCB
FCB-41 22'34-TeCB
PCB-71/40 23'416/221331-TeCB
PCB-64 234"6-TeCB
PCB-72 23'55'-TeCB
PCB-6 8 23'45'-TeCB
PCB-57 233 * 5-TeCB
PCB-58 233'5'-TeCB
PCB-67 23'45-TeCB
PCB-63 234'5-TeCB
PCB-61/70/74/76 2345-/23'4'5
PCB-66 23'44'-TeCB
PCB-55 233'4-TeCB
PCB-56 233'4'-TeCB
FCB-60 2344'-TeCB
PCB-80 33'55'-TeCB
PCB-79 33'45'-TeCB
PCB-78 33'45-TeCB
PCB-104 22'4 66'-PeCB
PCB-96 22'366'-PeCB
PCB-103 22"45"6-PeCB
Analytical Perspectives
Actual	Fred	Actual
RT	QC	RUT	RRT
17.21
1.1973
1.1975
NotFnc
0.8032
-
NotFnd
0.8091
-
NocFnd
0.8210
-
NotFnd
0.8292
-
19 .15
0.8409
0.8408
19.40
0.8525
0.8519
19.61
0.8598
0.8608
19.94
0.8756
0.8755
NotFnd
0.9334
-
NotFnd
0.9468
-
NotFnd
0.9685
-
NotFnd
0.9856
-
NotFnd
1.0008
-
NotFnd
1.0011
-
NotFnd
0.9043
-
NotFnd
0.9307
-
NotFnd
0.9339
-
NotFnd
0.9436
-
20.96
1.0010
1.0010
NotFnd
1.0068
-
NotFnd
1.0108
-
21.37
1.0196
1.0207
NotFnd
1.0323
-
21.82
1.0422
1.0420
NotFnd
1.0547
-
NotFnd
1.0624
-
NotFnd
1.0775
-
22.66
1.0822
1.0823
22.85
1.0913
1.0914
NotFnd
0.8279
-
NotFnd
0.8365
-
NotFnd
0.8489
-
NotFnd
0.8559
-
NotFnd
0.8610
-
NotFnd
0.8687
-
25.01
0.8785
0.8791
25.27
0.8882
0.8883
NotFnd
0.8931
-
NotFnd
0.9080
-
NotFnd
0.9144
-
NotFnd
0.9261
-
NotFnd
0.9711
-
NotFnd
0.9876
-
NotFnd
1.0009
-
NotFnd
1.0153
-
NotFnd
0.8878
-
Page 3 of 5
Di££
Sees
Response
Ra
RRF
+0.2
1.25E+05
1.09
1.38

0.00E+00

1.03

0.Q0E+00

1.00

0.G0E+00

1.04

O.OOE+OO

1.12
-0.1
4.19E+05
1.00
1.06
-0.7
4.69E+05
0.92
1.05
+ 1.2
2.62E+05
¦ 0.87
1.03
-0.1
1.39E+05
1.02
1.01

O.OOE+OO

1.05

O.OOE+OO

1.06

0.00E+00

0.95

0.00E+00

0.95

0.00E+00

0.89

0.00E+00

1.09

O.OOE+OO

0.74

O.OOE+OO

0.57

O.OOE+OO

0.82

0.OOE+OO

0.59
0
1.76E+05
0.90
0.72

0.00E+00

0.93

O.OOE+OO

0.59
+1.4
1.01E+05
¦ 0.64 1
0.83

0.00E+00

0.71
-0.3
2.14E+05
0.86
0.75

0.00E+00

0.94

0.00E+00

0.67

O.OOE+OO

0.56
+0,1
5.48E+04
0.80
0.75
+0.1
6.47E+04
0.77
0.98

O.OOE+OO

1.15

0.00E+00

1.18

0.00E+00

1.09

0.00E+00

1.09

O.OOE+OO

1.18

O.OOE+OO

1.17
+0.9
2.41E+05
0.87
1.12
+0.2
1.17E+05
0.71
1.13

0.00E+00

1.04

0.00E+00

1.07

0.00E+00

1.07

O.OOE+OO

1.20

O.OOE+OO

1.18

0.00E+00

1.02

0.00E+00

1.02

O.OOE+OO

0.88

O.OOE+OO

0.82

Checkcode:
yu
Cone
Noise
DL
8.89
6.60E+03
3.58

6.22E+03
3.97

6.22E+03
4.1

6.22E+03
3.95

6.22E+03
3.67
25.9
6.22E+03
3.87
29.4
6.22E+03
3.92
16.8
6.22E+03
4
9
6.22E+03
4. 06

6.22E+03
3.91

6.22E+03
3.87

6.22E+03
4.31

6.22E+03
4.31

6.22E+03
4.6

2.92E+03
1.9

2.98E+03
3.46

2.98E+03
'4.46

2.98E+03
3.1

2.98E+03
4.29
20.5
2.98E+03
3.54

2.98E+03
2.74

2.98E+03
4.34
10.1
2.98E+03
3.05

2.98E+03
3.61
23.8
2.98E+03
3 .38

2.98E+03
2.7

2.98E+03
3.83

2.98E+03
4.56
6.08
2.98E+03
3.38
5.53
2.98E+03
2.6

4.18E+03
3.1

4.18E+03
3. 04

4.18E+03
3.27

4.18E+03
3 .28

4.18E+03
3.03

4.18E+03
3.04
17.9
4.18E+03
3.18
8.7
4.18E+03
3.17

4.18E+03
3.44

4.18E+03
3.33

4.18E+G3
3.33

4.18E+03
2.97

4.18E+03
3.02

4.18E+03
3.51

2.98E+03
2 .55

2.98E+03
2.96

2.60E+03
3.62
Printed: 08 06 2008 1:19 PM
-------
MB1_6042_PCB_SDS	Actual	Pred
Name	RT	QC	RHT
PCB-94 22'356'-PeCB
NotFnd
0.8948
PCB-95 22 *35*6-PeCB
24.27
0.9087
PC3-100/93 22 144 1 6-/22'356-P
NotFnd
0.9158
FCB-102 22'456*-PeCB
NotFnd
0.9201
PCB-98 22'3'46-PeCB
NotFnd
0.9225
PCB-88 22'346-PeCB
NotFnd
0.9329
PCB-91 22'34'6-PeCB
NotFnd
0.9358
PCB-84 22'33'6-PeCB
NotFnd
0.9429
PCB-89 22'346"-PeCB
NotFnd
0.9579
PCB-121 23'45'6-PeCB
NotFnd
0.9708
PCB-92 22'355'-PeCB
NotFnd
0.9825
PCB-113/90/101 233'5'6-/22'3
26.74
1.0000
PCB-83 22133'5-PeCB
NotFnd
1.0157
PCB-99 22144'5-PcCB
NotFnd
1.0190
PCB-112 233'56-PeCB
NotFnd
1.0228
PCB-108/119/86/97/125/87 233
NotFnd
1.0353
PCB-117 234'56-PeCB
NotFnd
1.0545
PCB-116/85 23456-/22'344'-Pe
NotFnd
1.0575
PCB-110 233'4'6-PeCB
28.39
1.0624
PCB-115 2344'6-PeCB
NotFnd
1.0651
PCB-82 22'33 4-PeCB
NotFnd
1.0725
PCB-111 233"55'-PeCB
NotFnd
1.0846
PCB-120 23'455'-PeCB
NotFnd
1.0990
PCB-107/124 233 ' 4 ' 5-/2 ' 3'455 '
NotFnd
0.9908
PCB-109 233'46-PeCB
NotFnd
0.9973
PCB-106 233'45-PeCB
NotFnd
1.0039
PCB-122 2'33'45-PeCB
NotFnd
1.0100
PCB-127 33'455'-PeCB
NotFnd
1.0390
PC3-155 22'44'66'-HxCB
NotFnd
1.0008
PCB-152 22'3566'-HxCB
NotFnd
1.0070
PCB-150 22'34'66'-HxCB
NotFnd
1.0122
PCB-136 22'33"66'-HxCB
NotFnd
1.0236
PCB-145 22'3466'HxCB
NotFnd
1.0331
PCB-148 22'34'56'-HxCB
NotFnd
1.0805
PCB-1S1/135 22'355'6-/22'33'
NotFnd
1.0997
PCB-154 22*44*5'6-HxCB
NotFnd
1.1070
PCB-144 22'345'6-HxCB
NotFnd
1.1169
PCB-147/149 22'34'56-/22'34'
29.92
1.1281
PCB-134 22'33'56-HxCB
NotFnd
1.1343
PCB-143 22*3456'-HxCB
NotFnd
1.1374
PCB-139/140 22'344'6-/221344'
NotFnd
1.1469
PCB-131 22*33'46-HxCB
NotFnd
1.1532
PCB-142 22'3456-HxCB
NotFnd
1.1582
PCB-132 22'33'46'-HxCB
NotFnd
1.1676
PCB-13 3 22'33'55'-HxCB
NotFnd
1.1832
PCB-165 233'55'6-HxCB
NotFnd
0.9482
PCB-146 22'34'55'-HxCB
NotFnd
0.9543
Analytical Perspectives
Actual
RHT
0.9085
1.0011
1.0626
1.1283
Page 4 of 5
Diff
Sees
-0.3
+1.8
+0.3
+0.4




Checkcode
yu /
Response
Ra
RR¥
Cone
Noise
DL
O.OOE+OO

0.71

2.60E+03
4.16
9.57E+04
ESDI
0.77
13
2.60E+03
3.82
0.00E+00

0.78

2.60E+03
3.8
0.00E+00

0.88

2.60E+03
3.37
0.00E+00

0.69

2.60E+03
4.26
O.OOE+OO

0.66

2-60E+03
4.45
O.OOE+OO

0.84

2.60E+03
3.52
0.00E+00

0.66

2.60E+03
4.49
0.00E+00

0.70

2.60E+03
4.25
0.00E+00

1.02

2.60E+03
2.91
O.OOE+OO

0.74

2.60E+03
4.02
1.50E+05
0.68
0.84
18.7
2.60E+03
3.51
0.00E+00

0.59

2.60E+03
5.05
O.OOE+OO

0.85

2.60E+03
3.49
0.00E+00

0.97

2.60E+03
3.05
0.00E+00

0.85

2.60E+03
3.5
O.OOE+OO

0.94

2.60E+03
3.14
O.OOE+OO

0.83

2.60E+03
3.54
1.23E+05
0.71
0.93
13 .9
2.60E+03
3.17
O.OOE+OO

1.02

2.60E+03
2.89
0.00E+00

0.62

2.60E+03
4.8
0.00E+00

1.00

2.60E+03
2.97
0.00E+00

0.99

2.60E+03
3
0.00E+00

0.96

2.60E+03
3.09
0.00E+00

1.01

2.60E+03
2.94
0.00E+00

0.94

2.60E+03
3.15
0.00E+00

0.86

2.60E+03
3.21
0.00E+00

0.88

2.60E+03
3.18
0.00E+00

1.03

2.29E+03
2. 06
0.00E+00

0.98

2.29E+03
2.15
0.00E+00

0.96

2.29E+03
2.21
0.00E+00

0.92

2.29E+03
2.31
0.00E+00

0.90

2.29E+03
2.35
O.OOE+OO

0-89

2.29E+03
3.51
O.OOE+OO

0.89

2.29E+03
3.52
O.OOE+OO

1.04

2.29E+03
2.99
O.OOE+OO

0.93

2.29E+03
3.35
8.53E+04
1.41
0.93
11.8
2.29E+03
3.36
O.OOE+OO

0.75

2.29E+03
4 .14
O.OOE+OO

0.87

2.29E+03
3.58
O.OOE+OO

0.92

2.29E+03
3.4
O.OOE+OO

0.80

2.29E+03
3.9
O.OOE+OO

0.80

2.29E+03
3.91
O.OOE+OO

0.83

2.29E+03
3.75
O.OOE+OO

0.86

2.29E+03
3-63
O.OOE+OO

1.05

2.29E+03
2.96
O.OOE+OO

0.93

2 .29E+03
3.34

Printed: 08 06 2008 1:19 PM
-------
MB1_6042_PCB_SDS
Name
PCB-161	233145'6-BxCB
PCB-153/168 22 '44'55'-/23'44'
PCB-141	22'34 55'-HxCB
PCB-130	22'33'45'-HxCB
PCB-137	22*344'5-HxCB
PCB-164	233'4'5"6-HxCB
PCB-163/138/129 233'4 • 56-/22•
PCS-160	233'456-HxCB
PCB-158	233 ' 44*" 6-HxCB
PCB-128/166 22'33'44"-/2344'5
PCB-159	233'455'-HxCB
PCB-162	233 * 4'55'-HxCB
PCB-188	22'34'566'-HpCB
PCB-179 22'33'566'-HpCB
PCB-184 22'344'66'-HpCB
PCB-176	22'33'466'-HpCB
PCB-186	22'34566'-HpCB
PCB-178	22'33'55'6-HpCB
PCB-175	22'33'4 5'6-HpCB
PCB-187	22'34'55'6-HpCB
PCB-182	22'344'56'-HpCB
PCB-183	22'344'5'6-HpCB
PCB-185	22'3455"6-HpCB
PCB-174	22'33'456'-HpCB
PC8-177	22'33'4'56-HpCB
PCB-181	22'344'56-HpCB
PCB-171/173 22'33'44'6-/22'3
PCB-172	22'33'455'-HpCB
PCB-192	233'455'6-HpCB
PCB-180/193 22'344'55'-/233'
PCB-191	233'44'5'6-HpCB
PCB-170	22'33'44'5-HpCB
PCB-190	233'44'56-HpCB
PCB-202	22"33'55"66'-OcCB
PCB-201	22'33'45'66'-OcCB
PCB-204	22"344'566'-OcCB
PCB-197	22'33'44'66'-OcCB
PCB-200	22'33'4566'-OcCB
PCB-198/199 22'33'455'6-/22'
PC3-196	22'33'44'56'-OcCB
PCB-203	221344"55'6-OcCB
PCB-195	22133'44156-OeCB
PCB-194	22*33'44'55'-OcCB
PCB-205	233'44'55'6-OcCB
PCB-208	22'33'455'66'-NoCB
PCB-207	22'33'44'566'-NoCB
PCB-206	22'33'44'55'6-NoCB
Analytical Perspectives
Actual	Fred	Actual
S.T	QC	HUT	RUT
NotFnd
0.9577
-
32.43
0.9702
0.9695
NotFnd
0.9745
-
NotFnd
0.9846
-
NotFnd
0.9901
-
NotFnd
0.9930
-
33.48
1.0012
1.0008
NotFnd
1.0049
-
NotFnd
1.0104
-
NotFnd
0.9601
-
NotFnd
0.9829
_
NotFnd
0.9896
-
NotFnd
1.0007
-
NotFnd
1.0097
-
NotFnd
1.0236
-
NotFnd
1.0331
-
NotFnd
1.0453
-
NotFnd
1.0816
-
NotFnd
1.0985
-
NotFnd
1.1057
-
NotFnd
1.1111
-
NotFnd
1.1219
-
NotFnd
1.1246
-
NotFnd
1.1283
-
NotFnd
1.1400
-
NotFnd
1.1505
-
NotFnd
1.1563
-
NotFnd
0.9005
-
NotFnd
0,9061
-
NotFnd
0.9128
-
NotFnd
0.9205
-
NotFnd
0.9386
-
NotFnd
0.9492
-
NotFnd
1.0006
-
NotFnd
1.0220
-
NotFnd
1.0376
-
NotFnd
1.0428
-
NotFnd
1.0454
-
No cFnd
1.1099
-
NotFnd
1.1256
-
NotFnd
1.1302
-
NotFnd
0.9474
-
NotFnd
0.9915
-
NotFnd
1.0004
-
NotFnd
1.0005
-
NotFnd
1.0191
-
NotFnd
1.0004
-
Page 5 of 5
Diff	Checkcode:	yv
Sees Response Ra	RRF Cone	Noise	DL
0.00E+00 	 1.16	2.29E+03	2.69
-1.4 1.02E' 05 BE9 1-24 10.5	2.29E+03	2.51
O.OOE+OO	0.90	2.29E+03	3.48
O.OOE+OO	0.78	2.29E+03	3.98
0.00E+00	0.89	2.29E+03	3.49
0.00E+00	1.14	2.29E+03	2.73
-0.8 8.30E+04 1.23 0.95 11.2	2.29E+03	3.29
0.00E+00	1.09	2.29E+03	2.86
0.00E+00	1.21	2.29E+03	2.59
0.00E+00	0.85	2.15E+03	3.26
0.00E+00	0.95	2.15E+03	2.91
0.00E+00	0.95	2.1SE+03	2.91
O.OOE+OO	1.00	2.84E+03	3
O.OOE+OO	0.87	2.84B+03	3.45
O.OOE+OO	0.84	2.84E+03	3.6
0.008+00	0.90	2.84E+03	3.35
0.00E+00	0.86	2.84E+03	3.49
O.OOE+OO	0.64	2.84E+03	4.69
0.00E+00	0.88	2.58E+03	4.64
0.00E+00	0.90	2.58E+03	4.56
0.00E+00	0.93	2.58E+03	4.39
0.00E+00	0.92	2.58E+03	4.41
0.00E+00	0.85	2.58E+03	4.81
O.OOE+OO	0.86	2.58E+03	4.73
0.00E+00	0.85	2.58E+03	4.81
O.OOE+OO	0.88	2.58E+03	4.65
O.OOE+OO	0.79	2.58E+03	5.16
O.OOE+OO	0.79	2.58E+03	5.15
O.OOE+OO	1.02	2.58E+03	4.01
O.OOE+OO	0.97	2.58E+03	4.23
O.OOE+OO	1.10	2.58E+03	3.72
O.OOE+OO	1.17	2.58E+03	3.73
O.OOE+OO	1.39	2.58E+03	3.15
O.OOE+OO	0.95	2.34E+03	2.99
O.OOE+OO	0.89	2.34E+03	3.17
O.OOE+OO	0.84	2.34E+03	3.37
O.OOE+OO	0.86	2.34E+03	3.27
O.OOE+OO	0.89	2.34E+03	3.19
O.OOE+OO	0.63	2.34E+03	4.5
O.OOE+OO	0.63	2.34E+03	4.47
O.OOE+OO	0.71	2.34E+03	4
O.OOE+OO	0.76	2.20E+03	4.72
O.OOE+OO	0.82	2.20E+03	4.41
O.OOE+OO	1.06	2.20E+03	3.41
O.OOE+OO	1.00	2.50E+03	4.23
O.OOE+OO	1.00	2.50E+03	4.23
O.OOE+OO	1.11	2.50E+03	5.79
Printed: 08 06 2008 1:19 PM
-------
djc CHICKTOSQUMJIiD
AP Lab ID: MB1_6042_PCB_SDS
Instr; AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
Fn 1 100%.
218.9856
QC (non-EQ)
9.03-13.00
0%1, , ,
t I "r 1—I—I—I—I—I—I—I—I—I—I—I—1—|—I—r-T—r—j—i—i—t I I—t—i—11 I	 I—I—i—I—I—I—I—r—I—]—I—I—I—I—I—I—I—I—I—I—r
9.5	10.0	10.5	11.0	11.5	12.0
' I '
12.5
Abs. Int.
-1,06e8
-5.28e7
t , |' O.OOeO
13,0 RT
Re!. Int.
Fn 2 100%-
242.9856
QC (non-EQ)
13.02-17.79
0%-
—I—j—i—i—i—I—j—r-
13.5
—i——i—i1 'i " [—i—i—i—i—]—i—i—i—i—|—i i i—i—|—r-r f "i j
14.0	14.5	15.0
¦ I ¦
15.5
¦ I ¦
16.0
16.5
17.0
Abs. Int.
-6.82e?
-3,41e7
O.OOeO
I ' 11 1 I 11 11 1
17.5	RT
Rel. Int.
Fn 3 100%.
292.9824
QC (non-EQ)
17.81-23.26
0%-
—I—
18.0
—I—
19.0
	1	1	1	T |	1	1	1	!	1~
20.0
Abs. Int.
-?.01e7
¦ 3.51e7
O.OOeO
21.0
* l 1	f |	1	f t i |	[ t i I	j	1	r
22.0	23.0	RT
Rel. Int.
Fn 4 100%.
330.9792
QC (non-EQ)
23.27-34.14
0%-
24.0
	1	1	1	1	r-
26.0
—'	1—
28.0
30.0
—i—1—<—>—'—r
32.0
Abs. Int.
-5,83e7
•2.92e7
•O.OOeO
—r
34.0 RT
Rei. Int.
Fn 5 100%
366.9792
QC (non-EQ)
34.16-41.15
Rel. Int.
Fn 6 100%.
454.9728
QC (non-EQ)
41,17-46.41
Abs. nt
1 _S3e7
D.OOeO
Rel. Int.
Fn 7 100%
454.9728
QC (non-EQ) -
46.42-54.0t
54.0 RT
Results P:\P9400_P9499\P9464_6042 PCB\msourcesWB1_6042_PCB_SDS.utp_ms, saved 24-M-200S 10:57 (BE)
AP UttraTrace-Pro W3.993 User/System: EBEEC2-038 see 026-75?
Peak annotation: Areas, Centmids
PKD: n/a Printed: 05-Aug-200S 08 27 06 Page 1 of 22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
QC CHECK EQUALIZED
PRIOR TO PROCESSING
Sample ID: MB1_6042J3CB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
Fn 1 100*.
218,9856
QC Check
9,03-13.00
0%.
i-r-<
9.5
Abs, Int.
¦ 1.07e8
¦ I 1
10.0
¦ I '
10.5
-i—i—i—i—|—i—i—i—j—r—'—'—i—*—I—i—'—r-
11.0
11.5
1 I ' 1 ' ' I
12.0
-i—]—i—i—i—I—|—i—*—r-
12.5
¦ 5.35e7
¦O.OOeO
13.0 RT
Fn 2
Rel, Int.
100%.
242.9856
QC Check
13.02-17.73
0%.
13,5
-i—j—i i f i—(iii
14,0
—| * |—|—|—j—|—| | |—|—f I I I J
14.5	15.0
' t ¦
15,5
Abs. Int.
-7.00e7
¦ 3.50e7
O.OOeO
—i'f rvi-i-j-rr t fj
16,0	16.5	17,0	17,5	RT
Rel, Int.
Fn 3 100%.
292.9824 :
QC Check :
17.81-23.2S ~
0%-
18.0
I
19.0
I
20.0
21.0	22,0
Abs. Int.
•7.10e7
•3.55e7
—I—,—r-L O.OOeO
23.0	RT
Fn 4
Rel. Int.
100%.
330.8792
QC Check
23.27-34.14
0%.
24.0
1	¦"
1 I \ » f I
26.0
—y——y	f		j—
28.0
—j—
30.0
—(—
32.0
Abs, int.
• S.74e7
-2,87e7
, O.OOeO
34.0 RT
Rel. tnt.
Fn 5 100%.
454.9728
QC Check
34.16-41.15
0%.
I r
35.0
¦¦¦r	t	t	r
36.0
¦ i i i i i i i
37.0
38.0
i | r
39.0
40.0
Abs. Int.
-2.31C7
1.15e7
,-Lo.OOeO
41.0 RT
Rel. Int.
Fn 6 100%.
404.9760
QC Check
41.17-46.41
0%-
1 I 1 | I I
42.0
I i < i i I i i i » j
43.0
I
44.0
45.0
46.0
Abs. Int.
-2.46e7
-1.23e7
-O.OOeO
RT
Rel. Int.
Fn7 100%-
454.9728
QC Check
46.42-54.01
0%.
^ | r
47.0
I ' 1 1 ' I '
48.0
49.0
50.0
51.0
' I 1
52.0
^ I r
53.0
Abs. Int.
.2.38e7
¦ 1.19e7
-O.OOeO
54.0 RT
Results: P:\P94QO_P9499\P9464_6042 PCB\re$Quwe$\MBl_6042_PCB_SDS.utp res. saved 24~Jul-20Q8 10:57 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-038
Peak annotation: Areas, Centroids
PKD: n/a Printed: 05-Aug-20Q8 08:27:07 Page 2 of 22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
100%.
Fn 1
188.0393
MoCB
4a 4 62e3
9.03-13.00
Rel. Int.
100%-
Fn 1
190.0363
MoCB
4o 3.83e3
9.03-13,00
Rel. Int.
100%
Fn 1
200.079S
MoCB Std.
4a 1.40e4
9.03-13.00
Rel. Int.
100%
Fri 1
202.0766
MoCB Std.
4o 5.65e4
9.03-13.00
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Abs, Int.
6.79e4
3.40e4
O.OOeO
Abs. Int.
-2.95e4
1.48e4
O.OOeO
PCB-1
1.35es
PCB-2 PCB-3
1 39e5 1.33e5
11.25 11.41
1 r—i i i i i i
I	»—T	I	J	I	I	I	I
12 5	13.0RT
5.15e4
PCB-1
PCB-3
11.25
4.52e4
4.89e4

I—I—|—I—r—I—I
12.5	13.0RT
4.33e7
Abs. Int
2.09e7
4.55e7
11.40
1,Q5e7
O.OOeO
r	i	i	r	i	i	r	¦»

13,0 RT
Abs. Int
6.38e6
3.19e6
»"" | i*yvT"irj". i r i' |TTrfi ' i i~ i [¦ i	r i i i i t r ir i i i—I"11' i" i" i""ni i1111	i t i r i	i	ir	\	 -0.OOeO
13.0RT
Rel, Int.
100%-
Fn 1
218.9856
QC Check
9,03-13.00
Abs, Int.
-1.07a8
-5.35e7
0%-
9.5
10.0
10.5
' I '
11,0
Results: P \P9400 PS499\P9464_6042 PCB\resources\MB1_6042_PCB_SDS utp_res. saved 24-Jul-2008 10:57 fEE)
AP UttraTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 2975. 0820
~i—i—f—i—i—r—i "i i—?—i—i ¦ t —f—r—?—
-O.OOeO
11.5
12.0
12,5
13.0RT
Peak annotation: Areas, Centroids
Revised: 24-M-2008 10:32:57 fEEJ Printed: OS-Aug-2008 08:27:08 Page 3 oW2
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
/
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
100%-
Fn 1
222.0003
DiCB-1
4a 1.06e4
9.03-13.00
0%-
| "P i' r ff-t
9.5
i' i" i i' ¦ i i | 1 r ; f i ""|	i'	i ini'i f—i 	i			i	i	r i I 'i i i i 		i11 i i" r i1 i1	j in"!	
10.0	10.5	11.0	11,5
12.0
	1	T | l
12.5
Abs. Int.
-6 77e5
•3.38e5
^-O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
223.9974
DiCB-1
4a 2.93e4
9.03-13.00
Rel. Int.
100%
Fn 1
234.0406
DiCB Std.
4o 1.17e4
9.03-13.00
Rel. Int.
100%
Fn 1
236.0376
DiCB Std.
40 8.60e3
9.03-13.00
11.62
11.62
10.0
1 [ I I
12.5
Abs. Int.
-7.67e5
3.B4e5
O.OOeO
13.0RT
Abs. Int.
9.81e6
-4.90e6
O.OOeO
13.0RT
Abs. Int.
6.05e6
3 03e6
O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
218.9856 •
QC Check
9.03-13.00 "
Abs. Int.
-<-1.07e8
-5.35e7
0%-
> I j 1 I 1 f
9.5
I ' ' 1 1 t 1
10.0
10.5
11.0
Results P:\P9400_P9499V94S4_6042 PCBinssources\MB 1_6042_PCB_SDSjjtp_res. saved 24-M-2008 10:57 (EE)
AP UttraTrace-Pro V3.993 User/System EE/EEC2-038 cc~9262. 0694
-I—|—I—!—I—I—|—I—I—I—I—|—I—I—I—I—|—I—I—*—I—|—r-
11,5	12.0	12.5
-O.OOeO
13.0RT
Peak annotation: Areas. CentmkSs
Revised: 24-Jul-2008 10 33:00 (EE) Printed: 0S-Aug-2008 08:27:09 Page 4 o1Jt2
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fri 2
222.0003
DiCB-2
4a 7.20e3
13.07-17.79
Rel. Int.
100%
Fn 2
223.9974
DiCB-2
4o 2.45e4
13.07-17 79
Rel. Int.
100%
Fn 2
234.0406
DiCB Std.
4o 1.58e4
13.07-17.79
Rel. Int.
100%
Fn 2
236.0376
DiCB Std.
4a 1.03e4
13.07-17.79
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
PCB-11
2.72e6
16.27
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04_EQ
Abs. Int.
8.29e5
4.14e5
i 
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 2
255.9613
TrCB-2
4a 2.38e3
13.02-17.79
Rel. Int.
100%
Fn 2
257.9584
TrCB-2
4a 4.22e3
13.02-17.79
Rel. Int.
100%
Fn 2
268.0016 ,
TrCB Std.
4a 5.88e4
13.02-17.79
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
PCB-30/16
uses
16.01
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Abs. Int.
-5.70e4
ES-19
2.08e7
14.37
6.45e6
13.44
3.80e6
17.06
2.85e4
O.OOeO
RT
PCB-17
7.72e4
16.37
PCB-32
B.50e4
17.21
PCB-16
6.4 5e4
16.77
PCB-19
2.52e4
14.39
PCB-30/18
1J1e5
16.01
PCB-17
8,2le4
16.37
PCB-32
5.98e4
17.21
PCB-16
6,04e4
16.77
PCB-19
2.82e4
14.40
0% HiVyvs
0% l l t l | l l irl i ^ l i l'"' i		l" 		f	i >]¦ I i ji" i |""i i ' i" f j r r i f |
13.5	14.0	14.5	15.0
i i i i i
15.5
16.0
16.5
r l A-	'	I				'	'	f ' 1 1
Abs. Int.
-5.59e4
2,80e4
O.OOeO
Abs. Int.
-6.88e6
3 44e6
17.0
17.5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
269.9986
TrCB Std.
4a 5.23e4
13.02-17.79
0%-
8,68e5
13.44
f ¦ ' ' 1 I *
13.5
14.0 '
	| 	i"" i" "j	|'i	I "i" i|—i"i" i "i—	f	"i	i ""I | i f i"""i	|	r i i i ] i i i i -|- I i l i	| i""'
14.5	15.0	15.5	16.0	16.5
') ""i'	i "i i | *i"-i 		i- |"t r i "i	| i""
17.0	17.5
Abs. Int.
-6.51 ©6
-3.26e6
•O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
13.02-17.79
Results: P:\P9400_P9499\P9464_6042 PCBVesource$\MB1_6042_PCB_SDS.utp_ms, saved 24-Jul-2008 10:57 (EE1
AP UttraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 5592. 3606
Abs. Int.
7.00e7
3 50e7
O.OOeO
Peak annotation: Areas, Centroids
Revised: 24-Jul-2Q08 10:54:23 (EE) Printed: OS-Aug-2008 08:27:11 Page 6 oJ/22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Re I. Int.
100%-
Fn 3
255.9613
TrCB-3
4a 2.89e3
17.81-23.26
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
4o3.32e3
17.81-23.26
18.0
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mmi GC: pcbx100_a Vial: 58
PCB-28/20
PC8-31 2.24e5
2.09e5 19.40
Acq; 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Abs. Int.
-6.49e4
PCB-22
5.99e4
19.94

PCB-28/20
PCB-31 2.45e5
2.1065 19.40
19 15 I PCB-21/33
1.53e5
19.61
19.0
PCB-22
6.86 ©4
19.94
20.0
21.0
22.0

SS-28
Rel. Int.
3.41e7
100%-j
19,38
ft
Fn 3 :
ft
268.0016 ¦

TrCBStd.

4o 6.95e4

17.81-23.26 ¦
11
0%-
'i 1 » » i » I i ¦ 'i ¦ t f " 1" I1" 1 /—r-^-
4.78e6
20.79
/\
f 1 ) 1 I * I *' 1
3,25e4
18.0
19.0
20.0
21.0
22.0
VWf O.OOeO
Abs. Int.
-6.83e4
•3.42e4
23.0
—I—>
23.0
O.OOeO
RT
Abs. Int.
-9.35e6
•4.67e6
O.OOeO
RT
Rel. Int.
100%-
Fn 3
269.9986
TrCBStd.
4o 3.24e4
17.81-23.26
0%-
18,0
19,0
20.0
21.0
i | i—i—i I"' |
22.0
23.0
Abs. Int.
-8.87e6
•4.44e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P:\P9400_P9499\P9464_S042 PCB\resources\MB1_6042_PCB_SDS.utp_res. saved 24-Jul-2008 10:57 (EE)
AP UltraTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 7836. 8378
Abs, Int.
7.10e7
3,55e7
O.OOeO
RT
Peak annotation Areas. Centrakte^
Revised. 24-Jul~2008 10:55:00 (EE) Printed: 05-Aug-200S 08:27:12 Page 7 of-^2
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Ju1-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Ret. Int.
100%
Fn 2
289.9224
TeCB-2
4a 1.15e3
13.02-17.79
Abs, Int.
3.59e3
1,80e3
O.OOeO
RT
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o 1.77e3
13.02-17.79
Rel. Int.
100%-
Fn 2
301.9626
TeCBStd.
4a 6.41e3
13,02-17.79
0%-
Rel, Int.
100%-
Fn 2
303.9597
TeCS Std.
4o 3.82e3
13.02-17.79
0%-
' I 11 1 1 i
13.5
1 I 1
13.5
¦ I '
13.5
14.0
ES-54
2,Q7e7
17.05
14.5
' I 1
15.0
' I '
15.5
16.0
16.5
Abs, Int.
-4.71e3
2.35e3
O.OOeO
RT
Abs. Int.
-6.22e6
3,11e6
14.0
1 I '
14,5
15.0
15.5
I | I I t I |
16.0
16.5
ES-54
2.64e7
¦I ' 1 ' ' I
17.0
17.5
. , ¦ , O.OOeO
RT
Abs. Int.
,-7.76e6
-3.88e6
¦ i ¦
17.5
¦O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
13.02-17.79
Results: P:\P94Q0_P9499SP9464_6042 PCBVesource$\MB1_6042_PCB^SDS.vtp_res. saved 24-M-2008 10:57 (EE)
AP UitraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 3489~2408~
P-T—I
Abs. Int.
7.00e7
3.50e7
O.OOeO
RT
Peak annotation: Amas. Centmiitef
Revised: 24-Jui-2008 10:30:54 (EE) Printed: 0S-Aug-2008 08:27:14 Page 8ol&2
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Rel. Irrt,
100%
Fn 3
289-9224
TeCB-3
4 a 1.00e3
17.81-23.26 -
Sample ID: MB1_6Q42_PCB_SDS
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2O08 02:52:28
User: JLJ Datafile: 080724V04 EQ
Abs. Int.
-2.69e4
PCB-52
8.34 e4
PCB-44/47/65
9.91e4
PCB-69/49 21 &2
4.43e4
21.37
PCB-71/RffiB-64
2,43642.8164
22.66 22.85


18.0
19.0
20.0
21.0
22.0
23.0
1 35e4
O.OOeO
RT
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4o 1 98e3
17,81-23.26 ¦
Rel, Int
100%-,
Fn 3
301.9626
TeCB Sid.
4o 5,35e3
17.81-23.26
0%-
18.0
PCB-69/49 PCB-44/47/65
6.87e4	1.15e5
21.37	21.82
PCB-7lfi&BM34
3.05e43.66e4
22.85
19,0
20.0
21.0
JS-52
1.73e7
20.94
22.0
23,0
Abs, Int.
-2.76e4
• 1,38e4
-O.OOeO
RT
Abs. Int.
-4.66e6
•2.33e6
19 0
20.0
21,0
22.0
23.0
-O.OOeO
RT
Rel. Int.
100%-
Fn 3
303.9597
TeCBStd. .
4o 2.93e3
17.81-23.26
0%-
,—I—,
18.0
19.0
| I I I I j I T I I
20.0
21.0
22,0
Abs. Int.
-5.94e6
•2.97e6
—i—t i O.OOeO
23.0	RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P:\P94O0_P9499\P94d4_W42 PCBSm$ourcesW81_6042_PCB_SDSMtp„res, saved 24-Jul-2008 10:57 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 7955, 9826
Abs. Int.
7.10e7
3.55e7
O.OOeO
RT
Peak annotation: Areas. Centrwls
Revised: 24-Jul-200B 10 55 43 (EE) Printed: OS-Aug.2008 08:27:15 Page 9 #22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB 1^6042JPGB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pctox100_a Vial; 58
Rel. Int.
100%
Fn 4
289.9224
TeCB-4
4o 1 91e3
23.27-33.00
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4o 2.2?e3
23.27-33,00
0%-
PCB-61/70/74/76
1.12e5
25.01
rCB-86
4.87e4
25.27
24.0
25.0
PCB-61/70/74/76
1.29eS
25.00
PCB-66
6,86e4
25.27
26.0
27.0
28.0
29.0
30.0
Acq: 24-Jul-2G08 02:52:28
User: JLJ Datafile: 080724V04_EQ
Abs. Int.
3.20e4
1,60e4
o.ooeO
31.0	32.0	RT
Abs. Int.
-2.93e4
> » I1 i " * t I	I I I t I f I I I 1 | I > f t | T
24.0
Rel. Int.
100%-
Fn 4
301.9626
TeCBStd.
4o 3.84e3
23.27-33.00
0%-
24.0
> » I |
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
4oS.11e3
23,27-33.00
0%-
24,0
25.0
26.0
27.0
I » | I
28.0
TT"
ES-81
2,15e7
28.45
25,0
5.64e5
26.33
1111(11 f1! | I !
29,0
ES-77
2.17e7
28.92
j i i—i i j i I—i—r—|—i—i—i—r~
30.0	31.0
i i i I i
32.0
¦1.47e4
26.0
27,0
I 'i—i—i	i i i	¦ i
3,49e5
31.84
28.0
29.0
ES-01 ES-77
2.63a7 _2r?0e7
^28t45 28.92
¦"|"mi	i'""»	rim|"^""i	i—<	|	<	) t f^i 	i	i	i	r11!""
30.0
31.0
32.0
25.0
6,75e5
26.33
~l—'—1 I
26.0
27.0
' I • ' '
28.0
-Q.QOeO
RT
Abs. Int.
-5.28eS
2.64e6
-O.OOeO
RT
Abs. Int.
-6.57e6
3.29e6
29.0
30.0
31.0
32.0
¦O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-33.00
24.0
Result$: P:\P9400_P9499\P94S4_6042 PCB\resoutves\MB1_6042_PC8_SDS.utp_ms, saved 24-Ju!-2008 10:57 (EE)
AP tjltraTrace-Prv V3.993 User/System EE/EEC2-038 cc: 1130. B857
Abs. Int.
5.74e7
2.87e7
O.OOeO
RT
Peak annotation: Areas. CentraA
Rev/sect: 24-Jul-2008 10:58:06 (EE) Printed: 05-Aug-2008 08:27:16 Page 10 of22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
/
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
100%
Fn 3
323,8834
PeCB-3
4a 1.53e3
17.81-23-26
Abs. Int.
- 5 54e3
2.77e3
O.OOeO
Rel. Int.
100%
Fn 3
325.8804
PeCB-3
40 1,44e3
17 81-23 26
20.0
21.0
22.0
23.0
Abs. Int.
-5.05e3
2.53e3
-O.OOeO
RT
Rel. Int.
100%-
Fn 3
337.9207
PeCBStd,
4o 2.22e3
17.81-23.26
0%-
18.0
—I—1
19.0
20.0
1—I—1
21.0
I I I I
» ; i i
22.0
—I—1
23.0
Abs. Int.
-7.03e6
¦3.52e6
O.OOeO
RT
Rel. Int.
100%-
Fn 3
339.9177
PeCBStd.
4c 2.40e3
17.81-23.26
0%-
18,0
19,0
20,0
> I t I | I I I
21,0
Abs. Int.
-4.41 e6
¦2,20e6
'I r i——"J	r"—t—1—?	i	1	1¦ i ¦ i" »- 'j—-r—
22.0	23.0	RT
OOeO
Rel, Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P:\P9400_P9499W$464_6042 PCB\resouKesW!B1_6042_PC8_SDSMtp_res, saved 24-Jub20Q8 10:57 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc:~S140~373S~
22.0
Abs. Int.
7.10e7
3,55e7
-O.OOeO
RT
Peak annotation: Areas, Centrmfts
PKD: 24-Jul-2008 10:18:37 Printed: OS-Aug-2008 08:27:17 Page11*ff22
-------
/
AP Lab ID: MB1_6042„PCB._SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
323.8834
PeCB-4
4o 1,05e3
23.27-34.14
Rel. Int.
100%-
Fri 4
325.8804
PeCB-4
4o 1 55e3
23.27-34.14
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
0%-
Rel. Int.
100%-
Fn 4
337.9207
PeCB Std.
4o 3.74e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
339.9177
PeCB Std.
4a2 14e3
23.27-34.14
0%-
24.0
PCB-95
5.9164
24.27
I I [ I I
24.0
24.0
PCB-113/90/101
6.05e4
Acq: 24-Jul-2008 02.52:28
User: JLJ Datafile: 080724V04 EQ
Abs. Int.
-1.80e4
PCB-110
5.09e4
PCB-95
PCB-118
28.39
4.66e4
3.8864
24.27
30.87
26.0
28.0
30.0
32.0
PCB-113/90/101
8.9te4
26.74
1.53e4
25.20
PCB-110
7,18e4
29.38

PCB-118
S.73e4
30.87
—i	1	1	1	1	r -r
26.0
28.0
JS-101
2 15e7
26.71
—i	1	r-
SS-111
2.72e7
28.95
-i	[—i
30.0
—r
32.0
ES-123
2.33e7
30.58
ES-114 ES-105
2.41e7 2.39e7
31.30 31.84
26.0
28.0
4_i
30.0
32.0
JS-101 /¦
1.3667/
26.ZT
SS-11U
1.M
2C9S
ES-123 /ES-114--
1JTe7 / 1.53*7
3u.S8 31.30 ^ g4
24.0
.—|—i
26.0
LA
LA
28.0
30.0
T-J-
32.0
8.99e3
O.OOeO
34.0 RT
Abs. Int.
-2.97e4
•1.48e4
-i—|——i—i i i—|—*— 0 OOeO
34.0 RT
Abs. Int.
6.78e6
-3.39e6
-{-—O.OOeO
34.0 RT
Abs. Int.
-4.37e6
¦2,19e6
—¦—,—¦ ¦ 	i		O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Results: P\P9400_P9499\P9464_6042 PCB\resources\MB1_6042_PCB_SDSutp_res. saved 24-Jut-2008 10:57 (EE)
AP l/ffra Trace-Pro V3.993 User/System: EE/EEC2-03S cc: 0013, 3159
Abs. Int.
-5 74e7
2.87e7
T—O.OOeO
34.0 RT
Peak annotation: Areas, Centrmds
Revised: 24*Jut-200$ 10:56:39 (EE) Printed: 05-Aug-2008 08:27; 18 Page t2M22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample (D: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-20Q8 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
100%-
Fn 5
323.8834
PeCB-5
4o 1 57e3
34.16-41,15
0%-
2.2Te4
35.77
I I *» I
| I I t t | 1 1**
35.0
1.86e4
36.74
¦ W
1.6784
39.11
36.0
T" | < ¦
37.0
•r" i	
38.0
-r-r-

"T
39.0
40.0
Abs. Int.
-1.81e5
-9 05e4
•O.OOeO
-r-r
41.0 RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4o1.83e3
34.16-41.15
0%-
I ' ' 1 ' I 1
35.0
ES-126
Rel. Int. 2.66e7
100%-
Fn 5
337.9207
PeCB Std.
4o 5.17e3
34.16-41.15
0%-
34.41
L
E&126
Ret. int.
100%- 3441
Fn 5
339.9177
PeCB Std.
4a 4.50e3
34.16-41.15
0%-
35.0
>1)1
35.0
""r""T"""r	^	i	*	i'
36,0
7,84e4
36.73
_
Abs. Int.
-4.89e5
•2.45e5
37,0
8.94e5
36.92
T-T-
36.0
37.0
S.lle5
36.92
38.0
39.0
40.0
O.OOeO
41.0 RT
Abs. Int.
6.22e6
•3.11e6
39.0
i—i—t—t—i—|—i—i—*—i—|—r-*- O.OOeO
40.0	41.0 RT
Abs. Int.
4.03e6
•2.01e6
36.0
37.0
38.0
I I | I
39.0
40.0
I i O.OOeO
41.0 RT
Rel. Int.
- 100%-,
Fn 5
454.9728
QC Check
34.16-41.15
0%-
35.0
36.0
37.0
38.0
39,0
Abs. Int.
-2.31e7
1 15e7
40.0
41.0
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464 6042 PCB\resauix;es\MB1_6042_PCB SDS.utp_res, saved 24-Jul-2008 10:57 (EE)
AP UltraTmce-Pm V3.993 User/System: EEMEC2-038 cc. 3981. JS12~
Peak annotation: Areas. Centmjds
Revised: 24-M-2008 10:31:26 (EE) Printed. 05-Aug-2008 08 2 7:19 Page 13jtf 22
-------
AP Lab ID: MB1_6Q42_PCB_SDS
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 4
359.8415
HxCB-4
4o l .12e3
23.27-34.14
Rel. Int.
100%
Fn 4
361.8385
HxCB-4
4o 1.17e3
23.27-34.14
Rel. Int.
100%-
Fn 4
371.8817
HxCB Std.
4o 2.04e3
23.27-34.14
0%-
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Rel. Int.
100%-
Fn 4
373.8788
HxCB Std.
4o 2.02e3
23.27-34.14
0%-
24.0
ES-1SS
2.32e7
26.52
i i i i—J	r—
26.0
28.0
30.0
ES-155
l.82e
26*52
Acq: 24-Jul-2008 02:52:28
User: JU Datafile: 080724V04_EQ
PCB-153/168
6.98e4	Abs. Int.
32.43 PC B-163/138/129 r1 98e4
9.90e3
O.OOeO
34.0 RT
PCB-147/149
4.99e4
PCB-153/168
4.53e4
PCB-147/149
3.54e4
29.92
PCB-163/138/129
3,?2e4
33.48
ES-153
1.74e7
32.41
JS-138
1.43e7
33.45
32.0
ES-153
W8e7
32.41
Abs. Int.
-2.46e4
1.23e4
O.OOeO
34.0 RT
Abs. Int.
6,07e6
•3,04e6
JS-13B^
1.U67
33.45
•O.OOeO
34.0 RT
Abs. Int.
r4.79e6
-2 40e6
24.0
26,0
28.0
30.0
i | 1*1*1 r |
32,0
¦t—i—0. OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
24.0
26.0
28.0
30.0
Abs. Int.
5.74e7
-2.87e7
O.OOeO
Results: P:SP9400_P94$9\P9484 6042 PCB\resoumes\MB1 6042 PCB_SDS.utp_res, saved 24-M-2008 10:57 (EE)
AP UltraTrace-Pro V3.993 User/System: EEMEC2-038 €0:1X47^176
32,0	34.0 RT
Peak annotation: Areas, Centroidsr
Revised: 24-JM-2008 (0:57 re (EE) Printed: OS-Aug-2008 08:27:21 Page 14 oUS
-------
AP Lab ID: MB1_6042„PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
100%
Fn 5
359.8415
HxCB-5
4o 1,34e3
34.16-41.15
Abs. Int.
-5.34e3
2.67e3
!—r--O.OOeO
41.0 RT
Rel. Int.
100%
Fn 5
361.8385
HxCB-5
4o 8.07e2
34.16-41.15
Rel. Int.
100%
Fn 5
371.8817
HxCB Std.
4a 4,21 e3
34.16-41.15
Rel. Int.
100%-
Fn 5
373.8788
HxCB Std.
4o 3.06e3
34.16-41.15
0%-
ES-1&6/157
5T58e7
36.92
T i i i i | . i i i | i i i , |-
35.0	36.0
37.0
38.0
I r
39.0
39.60
Abs. Int.
-6.29e3
3.14e3
, . , • O.QOaO
41.0 RT
ES-156/157
3,79e7
ES-167
t .86e7
35.95
ES-169
1.84S7
39.60
Abs. Int.
-6.40e6
3.20e6
T-T— O.OOeO
41.0 RT
Abs. Int.
-5.22e6
I [ I
40.0
2 61e6
~i—r—O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
i r i | i i i
35.0
36.0
37.0
38.0
39.0
Results: P:\P9400__P9499\P9464_6042 PCB\msourc0S\MB1_6O42_PCB_SDS.Utp_res, saved 24-Jut-2008 10:57 (EE)
AP UttraTmce-Pro V3.993 User/System: EBEEC2-038 ec: 2831, 6289~
40.0
Abs. Int.
-2.31e7
¦1.15e7
41.0
¦O.OOeO
RT
Peak annotation: Areas. Centroids
Revised: 24-Jul-2008 10:31:3$ (EE) Printed: 0S-Aug-2008 08:27:22 Page 15 002
-------
AP Lab ID: MB1_6042 PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
100%
Fn 4
393,8025
HpCB-4
4a 1,69e3
30.00-34.14
Abs. Int.
-5.81e3
2.91 e3
j-r-.-~Q.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
395.7995
HpCB-4
4a 1.14e3
30.00-34.14
Rel. Irit.
100%-
Fn 4
405.8428
HpCB Std.
4a 2.01 e3
30.00-34.14
0%-
34.0 RT
Rel. Int.
100%-
Fn 4
407.8398
HpCB Std.
4a2.95e3
30.00-34.14
0%-
ES-188
1.97e7
31.29
30.5
1 I '
31.0
' I 1
31.5
' I '
32.0
' ' I
11 I '
32.5
' I '
33.0
1 I 1 ' '
33.5
SS-178
1.36e7
33.83
Abs. Int.
-4,03e3
2.02e3
OOeO
Abs. Int.
-4.78e6
•2.39e6
ES-1S6
L»2e7
^31.29
30.5
J i i r p | i r i—t
31.0
I | I I I I | I I I I | I I » I ]
31.5	32.0
32.5
1—r—r-*-O.OOeO
34.0 RT
Abs. Int.
-4.79e6
SS-178
-2.40e6
t-r-i-O.OOeO
33.0
33.5
34.0 RT
Rel. Int.
100%-
Fn 4 !
330.9792 -
QC Check "
30.00-34.14 -
Abs. Int.
74e7
2.87e7
Results: P:\P9400_P9499\P9464_6042 PCB\resources\MB1_6042_PC8_SD$.utp_ms, saved 24-Jui-2003 10:57 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-038 ce~2672, 7300
O.OOeO
Peak annotation: Areas, Centmifls
Revised: 24-Jut-2008 10:32:12 (EE) Printed: OS-Aug-2008 08:27:23 Page 16 0^22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04_EQ
Rel. Int.
100%
Fn 5
393,8025
HpCB-5
4o 1 76e3
34.16-41.15
Rel. Int.
100%.
Fn 5
395,7995
HpCB-5
4o 8.19e2
34.16-41.15
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std.
4o 4.13e3
34 16-41 15
0%-
35.0
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std..
4a 1.49e3
34.16-41.15

ES-180
V50e7
38.07

36.0
¦"1	|	1	%	%	%	j1	Tm
37.0
¦¦T	*!¦	T" T	t""
38,0
ES-180
1.41e7
3%Mr
39-0
0%—*-1—i—i—|—i—i—i—i—[' "i
35.0
i i j i i i i | i i i i | i
36.0	37.0
38.0
™T	!	p
39.0
"I	1	1	1	1	T~
40.0
41.0 RT
1,14e4
1,28e4
34,61
38.07
Abs, Int.
-7,48e3
3.74e3
O.OOeO
Abs, Int.
-6.11e3
3.05e3
OOeO
41,0 RT
Abs. Int.
-3.25e6
-1.63e6
-O.OOeO
TTo RT
Abs. Int.
-3.23e6
¦ 1,62e6
40.0
I . O.OOeO
41.0 RT
Rel. Int.
100%
Fn 5
454.9728
QC Check
34.16-41,15
0%-
I » I [ I i I
35.0
36.0
{ » I I 1 | I
37.0
38,0
r
I 1 1 f
39.0
40,0
T
Abs, Int.
-2,31e7
•1,15e7
-O.OOeO
"*410 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\MB1_6042_PCB_SDSMtp_re$, saved 24-Jul-2008 10:57 (BB)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-03B cc: 6238, S124
Peak annotation: Areas, Centroids,
PKD: 24-Ju!-2008 10:18:37 Printed: OS-Aug-2008 08:27 24 Page 17 of 22
-------
AP Lab ID; MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb04Q5_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2Q08 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
100%-
Fn 6
393.8025
HpCB-6
4a1.67e3
41.17-46-41
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-4.81e4
¦2.41e4
¦O.OOeO
RT
Rel. Int.
100%
Fn 6
395.7995
HpCB-6
4a1.29e3
41.17-46.41
42.0
43.0
44.0
45.0

ES-189
Rel. Int.
2.08e7
100%-,
41.69
A
Fn 6
A
405.8428 •

HpCB Std, '

4o6.18e3 .

41.17-46.41 •

0%-
J V
5.51e5
43.83
—r~-1
Rel. Int.
100%-
Fn 6
407.8398
HpCBStd.
4o 4.69e3
41.17-46.41
0%-
42.0
ES-189
2.00e
43.0
44.0
1—'—¦—'—¦—I—¦—1—
45.0
I I I
42.0
—I—.—p-
43.0
4.19e5
43.44
Abs. Int.
~3 65e3
1.83e3
1—i—t—i—t— O.OOeO
46.0	RT
Abs. Int.
4.57e6
44.0
I I |
45.0
-2 28e6
-i—i—i—i—[—i—i—i—t— 0. OOeO
46.0	RT
Abs. Int.
-4.34e6
•2.17e6
46.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41"
0%-
42.0
43.0
"1—1—""
44.0
45.0
46.0
Abs. Int.
-2.46e7
1.23e7
¦O.OOeO
RT
Results: P:V>94Q0_P9499\P946
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr; AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Rel. Int.
100%
Fn 5
427.7635
OcCB-5
4ct 9.34e2
34.16-41.15

~r
36.0
Abs. Int.
-4.64e3
2.32e3
O.OOeO
41.0 RT
Rel. Int.
100%
Fn 5
429.7606
OcCB-5
4o 1.41e3
34.16-41.15

ES-202
Rel. Int.
1.63e7
100%-,
35.76
Fn 5


439.8038


OcCB Std. J


4cj 1,20e3


34.16-41.15 '


0%-
1—i—i—i i i—>—'—]—i—i—i—i—i i l
X
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std.
4o1.72e3
34.16-41.15
0%-
35.0
36.0
"T" T T J T T T — V "—
37 0
38.0
39.0
ES-202
A.626J
3676
F I F F | f f 1 1 | I I T T'I —T
35.0	36.0
37.0
1 I [ I I 1 1 | % 1 I t | T
38.0
39.0
Abs. int.
-7,53e3
3.76e3
< , ¦ O.OOeO
41.0 RT
Abs. Int.
-3.91e6
1.96e6
O.OOeO
40.0
t 1 I I | 1
41.0 RT
4.02e5
40.24
"1—'—l*a"1—1—T"
Abs. Int.
-4.35e6
¦2.17e6
•O.OOeO
40.0
¦^T
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15
0%-
35.0
1 I 1 1 ' 1 I ¦
36.0
37.0
38.0
j f I t t | 1 1 1 * J
39.0
Results: P:\P9400_P9499\P9464_6042 PCB\nesources\M81_6042_PC8_SDS utp_rcs. saved 24-Jul-2008 10:57 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 2509, 9684
t
Abs, Int.
-2 31e7
¦1.15e7
,-t—O.OOeO
41.0 RT
40.0
Peak annotation: Areas, Centroh
PKD: 24-Jul-20OB 10:18-37 Printed: 0S-Aug-200a 08 27:26 Page 19
'entroids
19 0*72
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1 _6042_PCB_SDS
VSIR expt: pcb0405_cM-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Ret, Int,
100%
Fn 6
427,7635
OcCB-6
4o 8,90e2
41,17-46.41
Abs. Int.
-3.49e3
-1,74e3
*-O.OOeO
RT
Rel, Int.
100%-
Fn 6
429,7606
OcCB-6
4 o 1,30e3
41,17-46.41
Rel, Int.
100%-
Fn 6
439.8038
OcCBStd.
4a 1.70e3
41.17-46 41
0%-
Rel, Int.
100%-
Fn 6
441.8008
OcCB Std.
4cr1.71e3
41.17-46.41
0% i "t	
1—r_
42,0
JS-194
1.14e7
43.44
ES-205
1.40e7
43.83
43.0
3.77eS
45.27
44.0
45,0
JS-194
1.24a?
ES-205^
1.52C7
43.83
42.0
43.0
3.32e5
45.27
I	-~T	
46.0
Abs, Int.
-6,16e3
-3.08e3
O.OOeO
RT
Abs. Int.
-2.92e6
1.46e6
-O.OOeO
RT
Abs. Int.
-3,10e6
1,55e6
44.0
45.0
46.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41 "
0%-
42.0
43.0
44.0
45.0
46.0
Abs. Int.
r2.46e7
i.23e7
•O.OOeO
RT
Results: P:\P9400_P9499
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 58
1,522/
Acq: 24-Jul-2008 02::
User: JLJ Datafile: 080724V04_EQ
Rel. Int.
100%
Fn 6
461.7245
NoCB
4o 1.18e3
41.17-46.41
44.0
45.0
mT	1	|""
46.0
Abs. Int.
r3.98e3
1,99e3
~r~ O.OOeO
RT
Rel. Int.
100%
Fn 6
463.7216
NoCB
4o 1.32e3
41.17-46.41
ES-208
Rel. Int. i;J3e7
100%-
Fn 6
473.7648
NoCBStd.
4o1.45e3
41.17-46,41 ¦
41.30
0%-
ES-208
Rel. Int. 1.43J
100%- 4i
Fn 6
475,7619 ¦
NoCB Std. '
4a2.01e3
41.17-46,41 ¦
0%-
42.0
43.0
44.0
45.0
es.206
8.35e6
45.27
ES-20
4x27
460
Abs. Int.
-5.77e3
2.88e3
O.OOeO
RT
Abs. Int.
-2.61e6
1.30e6
-O.OOeO
RT
Abs. Int.
-3.35e6
1.67e6
420
43.0
44.0
45.0
46.0
•O.OOeO
RT
Rel. Int.
100%
Fn 6
404.9760
QC Check
41.17-46.41
0%-
1
42,0
43.0
44.0
45.0
Results: P\P9400_P9499*P9464_6042 PC8\resaurces\MB 1_6042_PCB_SDS utp_res. saved 24-Jul-ZOOS 10:57 (EE)
AP Ultra Trace-Pro 1/3.993 User/System: EE/EEC2-038 cc: 4407. 2330
46.0
Abs. Int.
-2.46e7
l.23e7
•O.OOeO
RT
Peak annotation: Areas. Centroiels
PKD: 24-Jut-2008 10: f8:37 Printed: 0$-Aug-200B 08:27 29 Page 21 oJ/22
-------
AP Lab ID: MB1_6042_PCB_SDS
Instr: AutoSpec-Premier MM6
PCB-209
Rel. Int. 2J9f4
100% 4662
Fn 7
497.6826
DeCB
4a 7.72e2
46.42-54.01
Rel. Int.
100%
Fn 7
499.6797
DeCB
4a 5.45e2
46.42-54.01
Rel. Int.
100%
Fn 7
509.7229
DeCB Std.
4o 8.86e2
46.42-54.01
Rel. Int.
100%
Fn 7
511.7199
DeCB Std.
4a 7.35e2
46.42-54.01
Sample ID: MB1_6042_PCB_SDS
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 58
Acq: 24-Jul-2008 02:52:28
User: JLJ Datafile: 080724V04 EQ
Abs. Int.
-6.53e3
3.26e3
O.OOeO
54.0 RT
PCB-209
i.4ie4
E 5-209
1,45e7
46.60
ES-209
1.22e7
46.60
48.0
51.0
52.0
53.0
Abs. Int.
5.97e3
2.99e3
O.OOeO
54.0 RT
Abs. Int.
3 20e6
1.60e6
O.OOeO
54.0 RT
Abs. Int.
2.74e6
1.37e6
-O.OOeO
54.0 RT
Rel. Int.
100%-
Fn 7
454,9728
QC Check
46.42-54.01"
Abs. tnt.
-2.38e7
-1,19e7
0%-
—I—>	t	|	I	%	V	f"
47.0
48.0
I I 1 I J T'l 1 I'l't "T-
49.0
50.0
r-— T"
51.0	520
Results: P:\P9400_P9499\P94S4_S042 PC8Vesources\MB !_6042_PCB_SOS utp_res, saved 24-M-2008 1057 (EE}
APWraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: Bin. 10B7
53.0
-O.OOeO
54.0 RT
Peak annotation: Areas, Centrops
Revised: 24-Jul-200S 10:29:26 (EE) Printed: 05-Aug-2008 08:27:30 Page 22 of 22
-------
Datafile: 080724V05_EQ
Acquired: 24 Jul 2008 03:49:55
Client ID: Run# ACD-M23-FB
Lab ID: P9464 6042 PCB 001
P9464_6042_PCB_001
Name
PCB-77 33'44'-TeCB
PCB-81 344'5-TeCB
PCB-105 233'44'-PeCB
PCB-114 234415-PeCB
PCB-118 23'44'5-PeCB
PCB-123 2-344'5-PeCB
PCB-126 33'44'5-PeCB
PCB-156/157 233 ' 44 ' 5/233 1 44 1 5 '
PCB-167 23'44'55'-HxCB
PCB-169 33'44'55'-HxCB
PCB-189 233"44'55'-HpCB
PCB-209 DeCB
Actual
RT
28.94 f
NotFnd/
31.86 y
NotFnd S
30,88 S
NotFnd/
NotFnd,#'
36,92 /
NotFnd
NotFnd /.
NotFnd /
46.62 X7
QC
Pred
RRT
.0006
.0006
.0007
.0007
0008
0006
0005
0005
0006
.0004
1.0005
1.0004
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PC3-
PCB-
PCB-
PCB-
PCB-
PCB-
PC3-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
1
3
4
15
19
37
54
n
81
104
105
114
118
123
126
153
155
156/157
167
169
170
180
188
189
202
205
206
208
209
9.46 "
11.40*"
11.63^
16.79 -*
14.38
22.78 '
17.05 ''
28.92 ^
28.46''
21.75*"
31.84 "
31.30
30.86
30.59,-
34.41	^
32.42
26.53
36.92 ^
35.96 ^
39.61
39.12 «*-
38.07 /¦
31.30	~
41.70 s
35.77
43.83 ~
45.27 ~
41.31
46.60 ~
0.7047
0.8520
0.8687
1.2550
1.0745
1.0878
0.8144
1.3808
1.3585
0.8143
1.1919
1.1717
1.1551
1.1449
1.2881
0.9690
0.7930
1.1035
1.0747
1.1838
0.9006
0.8765
0.7207
0.9600
0.8234
1.0090
1.0420
0.9509
1.0726
Analytical Perspectives
Wt/Vol: 1 -
A-level: 20

"V
D?l*M°(S
BCS3 6042 PCB VAB CPSW 080724 PCB VA
Nominal ES spike: 4000 pg
Actual
RRT
Diff
Sees
1.0006	0
1.0006	-0.2
1.0007	-0.2
1.0001	-0.9
1.0004 0
Response
2.79E+05
Q.00E+00
3.35E+05
Q.00E+00
9.87E+05
0.00E+00
0.00E+00
1.09E+05
O.OOE+OO
0.OOB+QO
O.OOE+OO
4.00E+04
Ra
0.77
0.63
0.68
1.36
/
RRF
1.05
1.10
0.97
0.94
0.97
0.96
0.98
0.97
0.99
0.93
0.92
0.91
Cone
21.1
HD
33
MD
96.7
ND
ND
11.7
ND
ND
ND
6.02
Checkcode:
Noise
83E+03
B3E+Q3
18E+03
18E+03
18E+03
4.18E+03
4.92E+03
95E+03
95E+03
9SE+03
17E+03
40E+03
-------
P9464_6Q42_FCB_0O1
Name
SS
ss
SS
PCB-28
pcB-m
PCB-178
Actual
HT
19.39 *
28.95 "
33.83 '
QC
Pred
RRT
0.9259
1.0838
1.0113
CS PCB-28
CS PCB-111
CS PCB-178
19.39^
28.95 ^
33.83"
0.9259
1.0838
1.0113
JS
JS
JS
JS
JS
PCB-9
PCB-52
PCB-101
PCB-138
PCB-194
13.38^
20.94^
26.72 ~
33.45 ,
43.44 ^
Checkcode;
cov

PCB-1 2-MoCB
PCB-2 3-MoCB
PCB-3 4-MoCB
PCB-4 221-DiCB
PCB-10 26-DiCB
PCB-9 25-DiCB
PCH-7 24-DiCB
231-DiCB
23-BiCB
24'-DiCB
35-DiCB
33'-DiCB
PCB-6
PCB-5
PCB-8
PCB-14
PCB-11
PCB-13/12
PCB-15 44
PCB-19 22
PCB-30/18
PCB-17 22
PCB-27 23
PCB-24 236-TrCB
PCB-16 22'3-TrCB
34"-/34-DiCB
-DiCB
6-TrCB
246-/22'5-TrCB
4-TrCB
6-TrCB
9.47
11.26
11.42
11.64
HotFnd
13.38
13.54
13.75
14.02
14.13
NotFnd
16.27
16.53
16
14
16
16
16
16
16
81
39
02
37
56
68
77
1.0011
0.9869
.0010
.0012
.0146
.0011
.0119
.0275
.0477
.0560
0.9258
0.9689
0.9848
1.0009
1.0011
1.1129
1.1388
1.1517
1.1599
1.1664
Analytical Perspectives
Actual
Dif f
Checkcode.-
RRT
Sees
Response
Ha
RRF /
Cone
Noise
DL
0.9259
0
6.67E+07
1.07
1.05 *
107 %
30%
135%
1.0837
-0.2
4.76E+07
1.56
1.19
102 %
30%
135%
1.0114
+0.2
2.91E+Q7
1.04
0.65
/
101 %
30%
135%
0.9259
0
6.67E+07
1.07
1.481/
98.7 %
30%
135%
1.0837
-0.2
4.76E+07
1.56
1.31
90 %
30%
13 5%
1.0114
+0.2
2.91E+07
1.04
0.93
96.7 %
30%
135%


7.09E+07
1.61






4.57E+07
0.79






4.02E+07
1.58






3.24E+07
1.29






2.92E+07
0.90





Totals
IJON-EMPC

EMFC
DL



Mono-CBs
319

319
3.12



Di-CBs
2,430

2, 430
8.54



Tri-CBr,
4,020

4,020
5.47



Tetra-CB:
2,160

2, 280
3.29



Penta-CB:
1,130

1,130
4.19



Kexa-CBs
1,680

1, 700
3.61



Hepta-CB:
2,670

2,670
4.24



Octa-CBs
1,300

1,300
2.91



Nona-CBs
125

125 /
4. 95


7
1
0011
0
1.27E+06
2.80
1
19 V
77.2 y/c
. 91E+03
2.86
0
9870
+0.1
1.80E+06
2.92
1
11
118
8.91E+03
3.69
1
0010
0
2.05E+06
2.90
1
21
124
8.91E+03
3.39
1
0012
0
1.68E+06
SI*
0
98
179
1.52E+04
10.7

-

0.00E+00

1
42

1.52E+04
7.37
0
9996
-1.2
2.23E+06
SI*
0
97
132
1.27E+04
6.53
1
0119
0
6.27E+05
SI*
0
98
36.8
1.27E+04
6.49
1
0274
-0.1
2.08E+06
SI*
0
97
123
1.27E+04
6.55
1
0475
-0.2
4.00E+05
SI*
0
92
24.9
1.27E+04
6.89
1
0559
-0.1
9.87E+06
SI*
0
98
576
1.27E+04
6.46

-

O.OOE+OO

1
12

1.27E+04
5.65
0
9689
0
1.59E+07
SI*
0
91
994
1.27E+04
6.92
0
9845
-0.3
1.72E+06
SI*
0
91
108
1.27E+04
6.94
1
0009
0
4.47E+06
SI*
0
99
258
1.27E+04
6.37
1
0011
0
5.27E+05
1.07
1
01
53
6.99E+03
5.3
1
1140
+1.1
6.20E+06
1.04
1
10
572
6.99E+03
4.86
1
1388
0
2.83E+06
1.04
0
96
298
6.99E+03
5.55
1
1516
-0.1
5.00E+05
1.03
1
31
38.8
6.99E+03
4.08
1
1598
-0.1
1.44E+05
0.92
1
23
11.9
6.99E+03
4.33
1
1664
0
2.03E+06
1.02
0
81
255
6.99E+03
6.61
Page 2 of 5
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_PCB_001
Name
PCB-32 24'6-TrCB
PCB-34 2'35-TrCB
PCB-23 235-TrCB
PC3-26/29 23'5-/245-TrCB
PCB-25 23'4-TrCB
PCB-31 24'5-TrCB
PCB-28/20 244'-/233'-TrCB
PCB-21/33 234-/2'34-TrCB
PCB-22 234'-TrCB
PCB-36 33'5-TrCB
PCB-39 34'5-TrCB
PCB-38 345-TrCB
PCB-35 33'4-TrCB
PCB-37 344'-TrCB
PCB-54 22'66'-TeCB
PCB-50/53 22'46-/22'56'TeCB
PCB-45 22'36-TeCB
PCB-51 22'46'-TeCB
PCB-46 22'36'-TeCB
PCB-52 22'55'-TeCB
PCB-73 23'5"6TeCB
PCB-43 22"35-TeCB
PCB-69/49 23'46-/22'45'TeCB
PCB-48 22'45-TeCB
PCB-44/47/65 22 ' 35'-/22 ' 44 '-
PCB-59/62/75 23316-/2346-/24
PCB-42 22'34'-TeCB
PCB-41 22'34-TeCB
PCB-71/40 23'4'6/22'33'-TeCB
PCB-64 234'6-TeCB
PCB-72 23'55'-TeCB
PCB-68 23'45'-TeCB
PCB-57 233'5-TeCB
PCB-58 233'5'-TeCB
PCB-67 23"45-TeCB
PCB-63 234'5-TeCB
PCB-61/70/74/76 2345-/23 ' 4 ' 5
PCB-66 23'44'-TeCB
PCB-55 233'4-TeCB
PCB-56 233'4'-TeCB
FCB-60 2344'-TeCB
PCB-80 33'55'-TeCB
PCB-7 3 33'45'-TeCB
PCB-78 33'45-TeCB
PCB-104 22'466'-PeCB
PCB-96 22'366'-PeCB
FCB-103 22'45'6-PeCB
Analytical Perspectives
Actual	Fred	Actual
RT	QC	RRT	RRT
17.22
1.1973
1.1976
NotFnd
0.8032
-
NotFnd
0.8091
-
18.69
0.8210
0.8203
18.89
0.8292
0.8292
19.16
0.8409
0.8409
19.41
0.8525
0.8520
19.61
0.8598
0.8609
19.95
0.8756
0.8756
NotFnd
0.9334
-
NotFnd
0.9468
-
NotFnd
0.9685
-
22.45
0.9856
0.9856
22.80
1.0008
1.0008
NotFnd
1.0011
-
18.92
0.9043
0.9034
19.50
0.9307
0.9309
19.56
0.9339
0.9340
19.76
0.9436
0.9435
20.97
1.0010
1.0010
NotFnd
1.0068
-
NotFnd
1.0108
-
21.38
1.0196
1.0207
21.62
1.0323
1.0322
21.82
1.0422
1.0417
22.09
1.0547
1.0545
22.25
1.0624
1.0624
22.57
1.0775
1.0776
22.67
1.0822
1.0824
22.85
1.0913
1.0912
NOtFnd
0.8279
-
23.80
0.8365
0.8364
NotFnd
0.8489
-
NotFnd
0.8559
-
24.50
0.8610
0.8610
24.72
0.8687
0.8687
25,01
0.8785
0.8790
25.28
0.8882
0.8883
NotFnd
0.8931
-
25.84
0.9080
0.9080
26.02
0.9144
0.9144
NotFnd
0.9261
-
NotFnd
0.9711
-
NotFnd
0.9876
-
NotFnd
1.0009
-
NotFnd
1.0153
-
NotFnd
0.8878
-
Page 3 of 5
Diff
Sees
Response
Ra
RHJT
+ 0.3
2.46E+06
1.02
1.38

0.OOE+OO

1.03

0,OOE+OO

1.00
-0.8
2.28E+06
1.03
1.04
0
1.04E+06
1.10
1.12
0
1.08E+07
1.02
1.06
-0.6
1.20E+07
1.03
1.05
+ 1.3
7.06E+06
1.04
1.03
0
4.09E+06
1.05
1.01

0.00E+00

1.05

0.00E+00

1.06

0.00E+00

0.95
0
3.28E+05
0.95
0.95
0
2.21E+06
1.02
0.89

0.OOE+OO

1.09
-1.0
4.42E+05
0.76
0.74
+0.2
4.59E+05
I 0.93
0.57
+0.1
3.03E+05
0.68
0.82
-0.1
1.83E+05
mon
0.59
0
3.26E+06
0.78
0.72

0.00E+00

0.93

0.00E+00

0.59
+1.4
2.06E+06
0.74
0.83
-0.1
7.54E+05
0.82
0.71
-0.7
3.73E+06
0.76
0.75
-0.3
3.55E+05
0.87
0.94
0
7.21E+05
0.77
0.67
+0.1
2.89E+05
0.83
0.56
+0.3
1.06E+06
0.79
0.75
-0.1
1.40E+06
0.76
0.98

0.00E+00

1.15
-0.1
2.70E+05

1.18

0.00E+00

1.09

0.OOE+OO

1.09
0
1.41E+05

1.18
0
1.23E+05
0.68
1.17
+0.8
4.59E+06
0.77
1.12
+0.2
2.01E+06
0.76
1.13

0.00E+00

1.04
0
9.36E+05
0.80
1.07
0
5.51E+05
0.79
1.07

0.00E+00

1.20

0.00E+00

1.18

0.OOE+OO

1.02

0.OOE+OO

1.02

0.OOE+OO

0.88

0.00E+00

0.82

Checkcode:
0)V
Cone
Noise
DL
180
6.99E+03
3.85

7.84E+03
4.87

7.84E+03
5.04
149
7.84E+03
4 .85
63.3
7.84E+03
4 .51
691
7.84E+03
4 .74
779
7.84E+03
4 .81
465
7.84E+03
4 .91
274
7.84E+03
4 .99

7.84E+03
4.8

7.84E+03
4.74

7.84E+03
5.29
23.3
7.84E+03
5.28
167
7.84E+03
5.65

3.44E+03
2.35
49
2.73E+03
3.23
65.6
2.73E+03
4.16
30.1
2.73E+03
2.9
25.2
2.73E+03
4
370
2.73E+03
3.3

2.73E+03
2.55

2.73E+03
4.05
201
2.73E+03
2.85
87.2
2.73E+03
3.37
405
2.73E+03
3.16
30.7
2-73E+03
2.52
88.5
2.73E+03
3.57
42.3
2.73E+03
4 .25
115
2.73E+03
3.15
117
2.73E+03
2.43

4.83E+03
3,65
18.8
4.83E+03
3.58

4.83E+03
3.85

4.83E+03
3.86
9.79
4.83E+03
3.57
8.54
4.83E+Q3
3.58
334
4.83E+03
3.74
146
4,83E+03
3.73

4.83E+03
4.05
71.2
4.83E+03
3.92
41.9
4.83E+03
3.92

4.83E+03
3.49

4.83E+03
3.55

4.83E+03
4.13

3.21E+03
2.74

3.21E+03
3.19

4.18E+03
5.41
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_FCB_001
Name
Actual
RT
QC
Fred
rrt
Actual
RRT
FCB-94
22'3561-PeCB
NotFnd
0.8948
-
PCB-95
22'35'6-PeCB
24.27
0.9087
0.9084
PCB-100/93 22'44'6-/221356-P
NotFnd
0.9158
-
PCB-102
22'456'-PeCB
NotFnd
0.9201
-
PCB-98
22 ' 3'46-PeCB
NotFnd
0.9225
-
PCB-88
22'346-PeCB
NotFnd
0.9329
-
PCB-91
22 ' 34'6-PeCB
24.99
0.9358
0.9355
PCB-84
22*33*6-PeCB
25.18
0.9429
0.9426
PCB-89
22*346'-PeCB
NotFnd
0.9579
-
PCB-121
23'45'6-PeCB
NotFnd
0.9708
-
PCB-92
22'355'-PeCB
26. 24
0.9825
0.9822
PCB-113/90/101 233'5'6-/22 ' 3
26.74
1.0000
1.0008
PCB-83
22'33'5-PeCB
NotFnd
1.0157
-
PCB-99
22'44'5-PeCB
27.22
1.0190
1.0187
PCB-112
233'56-PeCB
NotFnd
1.0228
-
PCB-108/119/86/97/125/87 233
27.68
1.0353
1.0362
PCB-117
234'56-PeCB
NotFnd
1.0545
-
PCB-116/85 23456-/22'344•-Pe
28.25
1.0575
1.0573
PCB-110
233'4"6-PeCB
28.38
1.0624
1.0623
PCB-115
2344*6-PeCB
NotFnd
1.0651
-
PCB-82
22'33'4-PeCB
28.65
1.0725
1.0724
PCB-111
233'55'-PeCB
NotFnd
1.0846
-
PCB-120
23'455'-PeCB
NotFnd
1.0990
-
PCB-107/124 233'4'5-/2'3455'
NotFnd
0.9908
-
PCB-109
233'46-PeCB
NotFnd
0.9973
-
PCB-106
233'45-PaCB
NotFnd
1.0039
-
PCB-122
2'33 *45-PeCB
NotFnd
1.0100
-
PCB-127
33'455'-PeCB
NotFnd
1.0390
-
PCB-155
22'44'66'-HxCB
NotFnd
1.0008
-
PCB-152
22'3566'-HxCB
NotFnd
1.0070
-
PCB-150
22•34'66'-HxCB
NotFnd
1.0122
-
PCB-136
22'33'66•-HxCB
27.15
1.0236
1.0237
PCB-145
22'3466'HxCB
NotFnd
1.0331
-
PCB-148
22'34'56'-HxCB
NotFnd
1.0805
-
PCB-151/135 22'355'6-/22'33'
29.16
1.0997
1.0994
PCB-154
22'44'5'6-HxCB
NotFnd
1.1070
-
PCB-144
22'345'6-HxCB
29.63
1.1169
1.1169
PCB-147/149 22'34'56-/22'34'
29.92
1.1281
1.1281
PCB-134
22*33'56-HxCB
NotFnd
1.1343
-
PCB-143
22'3456'-HxCB
NotFnd
1.1374
-
PC3-139/140 22'344'6-/22'344 '
NotFnd
1.1469
-
PCB-131
22'33'46-HxCB
NotFnd
1.1532
-
PCB-142
22 * 3456-HxCB
NotFnd
1.1582
-
PCB-132
22'33'46'-HxCB
30.97
1.1676
1.1677
PCB-133
22*33*55'-HxCB
NotFnd
1.1832
-
PCB-165
233'55*6-HxCB
NotFnd
0.9482
-
PCB-146
22*34*55*-HxCB
31.93
0.9543
0.9543
Analytical Perspectives
Page 4 of 5
Diff





Checkcode:
cov"
Sees
Response
Ha
ERF
Cone
Noise
DL

Q.OOE+OO

0
71

4.18E+03
6.22
-0.4
1.45E+06
0.59
0
77
190
4.18E+03
5.71

O.OOE+OO

0
78

4.18E+03
5.67

O.OOE+OO

0
88

4.18E+03
5.03

0.00E+00

0
69

4.18E+03
6.37

O.OOE+OO

0
66

4.18E+03
6.65
1
o
2. 32E+05
0.70
0
84
28.1
4.18E+03
5.26
-0.5
4.26E+05
0.58
0
66
65.8
4.18E+03
6.72

0.00E+00

0
70

4.18E+03
6.35

O.OOE+OO

1
02

4.18E+03
4.35
LO
o
i
2.63E+0S
0.60
0
74
36.4
4.18E+03
6 .01
+1.3
1.90E+06
0.60
0
84
229
4.18E+03
5.25

0.00E+00

0
59

4.18E+03
7.54
-0.5
6.25E+05
0.59
0
85
75
4.18E+03
5.21

0.00E+00

0
97

4.18E+03
4. 56
+1.5
1.13E+06
0.60
0
85
136
4.18E+03
5.23

O.OOE+OO

0
94

4.18E+03
4.7
CO
o
1
2.11E+05
0.64
0
83
25.6
4.18E+03
5.29
-0.2
1.72E+06
0.62
0
93
188
4.18E+03
4.74

0.00E+00

1
02

4.18E+03
4.31
-0.2
1.54E+05
0.62
0
62
25.4
4.18E+03
7.18

O.OOE+OO

1
00

4.18E+03
4.43

O.OOE+OO

0
99

4.lfiE+03
4 .48

O.OOE+OO

0
96

4.18E+03
4.61

O.OOE+OO

1
01

4.18E+03
4.39

0.00E+00

0
94

4.18E+03
4.71

O.OOE+OO

0
86

4.182+03
4.67

0.00E+00

0
88

4.18E+03
4.83

O.OOE+OO

1
03

2.68E+03
2.46

0.00E+00

0
98

2.68E+03
2.57

O.OOE+OO

0
96

2.68E+03
2.65
+0.2
8.00E+05
1.20
0
92
83.5
2.68E+03
2.76

0.00E+00

0
90

2.68E+03
2.81

0.00E+00

0
89

2.68E+03
3.61
-0.5
1.62E+06
1.25
0
89
214
2.68E+03
3.61

O.OOE+OO

1
04

2.68E+03
3.07
0
1.65E+05
1.11
0
93
20.8
2.68E+03
3.44
0
3.62E+06
1.31
0
93
457
2.68E+03
3,45

O.OOE+OO

0
75

2.68E+03
4.26

0.0 0E+ 00

0
87

2.68E+03
3.68

O.OOE+OO

0
92

2.68E+03
3.49

O.OOE+OO

0
80

2,68E+03
4.01

O.OOE+OO

0
80

2.68E+03
4.02
+0.2
1.01E+06
1.33
0
83
142
2.68E+03
3.85

O.OOE+OO

0
86

2.68E+03
3.73

0.00E+00

1
05

2.68E+03
3.04
0
4.84E+05
1.23
0
93
60. 9
2.68E+03
3.44
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_FCB_001
Name
PCB-
PCB-
FCB-
PCB-
PCB-
PCB*
PCH-
•PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PC3-
PCB-
?C3-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
•161 233 '45' 6-HxCB
153/168 22 ' 44'55"-/231441
¦141 22 ' 3455 ' -HxCB
130 22'33'45'-HxCB
137 22'344'5-HxCB
164 233'4'5'6-HxCB
163/138/129 23314'56-/22'
160 233'4 56-HxCB
158	233'44'6-HxCB
128/166 22'33'44'-/2344 ' 5
159	233'455'-HxCB
162 233'4'55'-HxCB
188
179
184
176
186
178
175
187
182
183
185
174 22•33"456'-HpCB
177	22"33"4156-HpCB
181 22"344'56-HpCB
171/173 22"33'4416-/22 ' 3
172 22'33'455'-HpCB
192 233'455"6-HpCB
180/193 221344'55'-/233 '
191 233'44'5'6-HpCB
22'33'44'5-HpCB
233'44'56-HpCB
22'33'55'66'-OcCB
22'33'45'66'-OcCB
22'344'566'-OcCB
22'33'44'66'-OcCB
22'33'4566'-OcCB
22
34'566'
-HpCB
22
33'566'
-HpCB
22
344'66'
-HpCB
22
33 '466'
-HpCB
22
34566'-
HpCB
22
33'55'6
-HpCB
22
33'45'6
-HpCB
22
34'55'6
-HpCB
22
344'56'
-HpCB
22
344'5 ' 6
-HpCB
22
3455'6-
HpCB
170
190
202
201
204
¦197
200
198/199 22'331455'6-/22'
196 22'33'44'56'-OcCB
203	22'344'55"6-OcCB
195 22'33'44'56-OcCB
194 22*33'44'55'-OcCB
205	233 '44'55'6-~OcCB
208 22'33'455'66'-NoCB
207 22133"44 * 5661-NoCB
206	22'33'44'55'6-NoCB
Actual

Prod
Actual
RT
QC
ROT
RM?
NotFnd

0.9577
-
32.44

0.9702
0,9695
32.60

0.9745
0.9745
NotFnd

0.9846
-
NotFnd

0.9901
-
33.22

0.9930
0.9929
33.48

1.0012
1.0008
NotFnd

1.0049
-
33.81

1.0104
1.0105
NotFnd

0.9601
-
35.32

0.9829
0.9823
NotFnd

0.9896
-
NotFnd

1.0007
-
31.60

1.0097
1.0097
NotFnd

1.0236
-
32.33

1.0331
1.0331
NotFnd

1.0453
-
33.85

1.0816
1.0816
NotFnd

1.0985
-
34.61

1.1057
1.1059
NotFnd

1.1111
-
35.12

1.1219
1.1222
35.21

1.1246
1.1249
35-32

1.1283
1.1284
35.68

1.1400
1.1400
NotFnd

1.1505
-
36.20

1.1563
1.1568
37.55

0.9005
0.9004
NotFnd

0.9061
-
38.09

0.9128
0.9134
NotFnd.

0.9205
-
39.14

0.9386
0.9386
39.58

0.9492
0.9491
35.79

1.0006
1.0006
36.55

1.0220
1.0220
NotFnd

1.0376
-
NotFnd

1.0428
-
37.39

1.0454
1.0455
39.72

1.1099
1.1106
40.27

1.1256
1.1258
40.43

1.1302
1.1303
41.53

0.9474
0.9474
43 .46

0.9915
0.9915
NotFnd

1.0004
-
41.33

1.0005
1.0005
42.10

1.0191
1.0192
45.29

1.0004
1.0004
Analytical Perspectives
Page 5 of 5
Sees
Response
Ra
RRF
Cone
Noise
DL

0.00E+00

1
16

2.68E+03
2.76
-1.4
2.55E+06
1.28
1
24
241
2.68E+03
2.58
0
8.18E+05
1.27
0
90
107
2.68E+03
3.58

O.OOE+OO

0
78

2.68E+03
4.09

O.OOE+OO

0
89

2.68E+03
3.59
-0.2
2.31E+05
1 1.01
1
14
23.7
2.68E+03
2.81
-0.8
2.42E+06
1.21
0
95
300
2.68E+03
3.38

0.00E+00

1
09

2.68E+03
2.94
+0.2
2.33E+05
1.15
1
21
22.7
2.68E+03
2.66

0.00E+00

0
85

2.95E+03
3.95
-1.3
1.58E+05
1.18
0
95
17,9
2.95E+03
3.52

0.OOE+OO

0
95

2.95E+03
3.53

O.OOE+OO

1
00

2.82E+03
2.57
0
2.18E+06
1.01
0
87
225
2.82E+03
2.95

O.OOE+OO

0
84

2.82E+03
3.08
0
5.18E+05
1.05
0
90
52
2.82E+03
2.86

O.OOE+OO

0
86

2.82E+03
2.98
0
6.02E+05
1.03
0.
64
84.7
2.82E+03
4.01

0.00E+00

0.
88

3.36E+03
5.16
+0.4
3.48E+06
1.05
0
90
474
3.36E+03
5.08

O.OOE+OO

0
93

3.36E+03
4 .88
+ 0.6
1.14E+06
1.03
0
92
150
3.36E+03
4 .91
+0.6
4.23E+05
1.13
0
85
60.7
3.36E+03
5.35
+0.2
3.43E+06
1.03
0
86
483
3.36E+03
5.26
0
1.32E+06
1.04
0
85
190
3.36E+03
5.36

O.OOE+OO

0
88

3,36E+03
5.17
+ 1.1
4.55E+05
1.18
0
79
70
3.36E+03
5.74
-0.2
2.97E+05
1.04
0
79
45.6
3.36E+03
5.74

0.OOE+OO

1
02

3.36E+03
4.46
+ 1.4
4.92E+06
1.02
0
97
621
3.36E+03
4.71

O.OOE+OO

1
10

3.36E+03
4.15
0
1.51E+06
1.02
1
17
173
3.36E+03
4 .46
-0.2
3.84E+05
0.99
1
39
37.1
3.36E+03
3.76
0
5.61E+0S
0.84
0
95
64.2
2.23E+03
2.56
0
3.93E+05
0.94
0
89
47.8
2.23E+03
2.72

O.OOE+OO

0
84

2.23E+03
2.88

O.OOE+OO

0
86

2.23E+03
2.79
+0.2
5.02E+05
0.86
0
89
61.3
2.23E+03
2.73
+ 1.7
2.31E+06
0.89
0
63
398
2.23E+03
3.85
+0.5
8.99E+05
0.83
0
63
154
2.23E+03
3.83
+0.2
1.24E+06
0.87
0
71
190
2.23E+03
3.42
0
6.36E+05
0.94
0
76
110
2.21E+Q3
4.52
0
1.74E+06
0.93
0
82
280
2.21E+03
4.22

O.OOE+OO

1
06

2.21E+03
3.26
0
1.46E+05
0.81
1
00
20.9
2.91E+03
4.53
+ 0.3
1.02E+05
0.75
1
00
14.6
2.91E+03
4 . 53
0
5.13E+05
0.79
1
11
89.9
2.91E+03
5.37
Printed: 08 06 2008 1:20 PM
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID; Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05_EQ
Rel. Int.
Fn 1 100%-,,
218,9856
QC (non-EQ)
9,03-13.00
0%-
I | I I T
as
10.0
I j I I I I
10.5
' I ¦
11.0
I t I I j I t I t j I
12.0
i [ i
12.5
Abs, tnt
,-1,04b8
.5.19e7
¦ O.OOeO
13,0 RT
Rel. Int.
Fn 2 100%.
242.9856
QC (non-EQ) .
13.02-17.79
0%.
13.5
1 I 1
14.0
~r"I—rT"
14.5
-i—r-i—i—|—!—i i i | i i—i i | i i i i—j—i i f i—| i i » i—g i i i i j i i—i—i | i i—>—i—|—i-
15.0	15.5	16.0	16.5	17,0
Abs, Int.
-6 49e7
¦ 3,2Se?
O.OOeO
¦T" I r	t I r j
17.5	RT
Rel. Int.
Fn 3 100%-j,
292.9824
QC (non-EQ)
17.81-23,26
0%.
—I—'—1—1—*—r
18.0
19.0
—I—
20.0
i i i | t »
21.0
i * i |
22.0
23.0
Abs, Int.
-6.56e7
-3.28e7
-O.OOeO
RT
Rel. Int.
Fn4 100%
330.9792
QC (non-EQ)
23.27-34,14
0%.
—.	.—I—
24.0
i i I i i r i I
26.0
I
28.0
I
30.0
I i i i i
32.0
Abs. Int,
-5.57e7
,2,79e7
.O.OOeO
—r
34.0 RT
Rel. Int.
Fn 5 100%.
366.9792
QC (non-EQ)
34.16-41.15
0%.
35.0
"1—'—1—'—'—I—r
36.0
—i—i—|—r-
*—j—r—i—i—*—|—i—i—i—r
38.0
39.0
—i—i—!—!—r~
Abs. Int.
-1,20o?
¦6,02e6
-O.OOeO
*-r
41,0 RT
Fn6
Rel. Int.
100%.
454.9728
QC (non-EQ)
41.17-46.41
0%-
42.0
-i	1	p-
I
43.0
44.0
I
45.0
—I—*	'	
46.0
Abs. Int.
-1,87e7
-9.37B6
¦O.OOeO
RT
Fn 7
Rel, Int.
100%.
454.9728
QC (non-EQ)
46.42-54.01
47.0
48.0
I ' 1 1 ' I '
49,0
-1 ] r
50,0
"¦I r
51.0
Results: P:\P9400_P9499\P9464jS042 PCBte$ouree$V39464_6042_PCB_Q0lMtp_a;s, saved 24-Jui-2008 11:13 (E£j
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 see: 5 f 3-856
1 I r
52.0
t f I | I f
53.0
Abs. Int.
-2.28e7
-1.14e7
• O.OOeO
54,0 RT
Peak annotation: Areas. Centroids
PKD: n/a Printed: 05-Aug-2008 08:27:32 Page 1 of 22
-------
QC CHECK EQUALIZED
PRiOXTO?S3C3SIKO
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-JuI-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Fn 1
Rel. Int.
100%.
218.9856
QC Check
9.03-13.00
0%.
i—]—i—i—i—i—|—i—i—i—r—|—r-
9.5	10.0
' I 1
10.5
' I '
11.0
' I '
11.5
' I •
12.0
-j—i—r—i—n—[—i—!—r—f—j—f—i—i—r
12.5
Abs. Int.
-1.05e8
¦ 5.26a7
-O.OOeO
13.0 RT
Rel. Int.
Fn 2 100%-
242.9856
QC Check
13.02-17.79
0%.
T—I—1	I	P	I	T—T~
' I "
13.S
14.0
14.5
15.0
15.5
16.0
16.5
¦ I ¦
17.0
Abs. Irtl.
•6.7487
•3.37e7
17.5
RT
Fn 3
Rel. Int.
100%.
292.9824
QC Check
17.81-23.26
0%.
1 | 1 T V
18.0
—|	1	1	1	1	1	1	1	1	1	]	1	1	1	i	1	1	r-
19.0	20.0
	(	.	r-
21.0
~"1	1	r	(	1	1	
22.0
23.0
Abs. Int.
-6.86e7
¦ 3,43e7
¦ O.OOeO
RT
Fn 4
Rel. Int.
100%-
330.9792
QC Check
23.27-34.14
0%.
24.0
26.0
—I—
28.0
1	1	'	1	'	1—
30.0
—I—
32.0
Abs. Int.
.5.8067
-2.90e7
¦O.OOeO
34,0 RT
Rel. Int.
Fn 5 100%.
454.9728
QC Check
34.16-41.15
0%.
T-T-T
35.0
I T f I I I I | 1
36.0
37,0
~i—|—i—i—i—i—|—i—i—i—i—|—r-
38.0
1 I 1 1
39.0
•	1	'
40.0
Abs. Int.
-2,43e7
¦ 1.2207
""i	r	y	r	t	t	t	i""
41.0 RT
Rel. Int
Fn 6 100%-
404.9760
QC Check
41.17-46.41
Q%-
—I—
42,0
I
43.0
| T I I I
44,0
I i i
45.0
—I	
46.0
Abs. Int.
-2,44e7
-1 -22e7
-O.OOeO
RT
Fn 7
Rel. fnt.
100%-
454.9728
QC Check
46.42-54.01
0%-
T p 1	1 I I |
47.0
i | i i
48.0
T	|' "T ' »	I	f	|	!	1	f—1	J' 1	T Ml F'"
49.0	50.0
T'T T""f T *| ' I f
51.0
1 1 '
$2.0
' \ *
53.0
• 2.34e7
H.17e7
.O.OOeO
54.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_001.utp_res, saved 24~Juf-2008 11:13 (EE}
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-Q38
Peak annotation: Areas, Gerntroids
PKD: n/a Printed: 05~Aug~2008 08:27:33 Page 2 of 22
-------
AP Lab ID: P9464_6042JPGB_001
Instr: AutoSpee-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 59
Rel, Int.
100%-
Fn 1
188.0393
MoCB
4a 5.l8e3
9.03-13.00
0%-
Rel. Int.
100%-
Fn 1
190.0363
MoCB
4o3.72e3
9.03-13.00
0%-
PCB-1
9.37e5

tZu? ) V 1
PCBJ
I.34e6	ii 49
II.26
10.37
i '< 'f i-r r-i-
10.0
-f=t-

.5	10.0
10.5
4.02e4
11.64
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05_EQ
Abs. Int.
5.79e5
•2.89e5
'' I"1'
12.0
i i r-r—i ¦
12.5
„„„ ,, PCB-3
PCB-2 S.26eS
4 61 e5 11.42
11.26
¦O.OOeO
13.0RT
f | 'f:>arr^nj-inpnp	-jr-;	j , i i i |
10,5	11.0	11.5
12.0	12.5	13.0RT
Abs. Int.
-2.14e5
1.07e5
Rel. Int.
100%-
Fn 1
200.0795
MoCB Std.
4a 1,50e4 ¦
9.03-13.00
0%-Lr
Rel. Int.
100%-
Fn 1
202.0766
MoCB Std, ,
4o 5.50e4
9.03-13.00
0%-
10.0
4.19e7
11.40
i—' t ?¦ i r i i | i r i I I ! i t i | i r t r I i !— i i i f i i i i i i i i i i r i i i i i i i
10.5
11.0
11.5
12.0
12.5
ES-K
1.3*67
9.46
f.fT t1
f.ojc 1
•jj,ooO
1{0OD
I OD
ES^
I.30e7
II.41
9.5
I V o H /
&2-8 % ^
Ob
10.0
10.5
n-4~r-
Abs. Int.
-1.99e7
¦9.96e6
¦O.OOeO
13.0RT
~T— t— [ mi" i~*"| P't i
11.0	11.5
rmiTi t rrf r
12.0
fi^rT i * i i t ' ' » '
Abs. (nt.
-6.37e6
•3.19e6
¦O.OOeO
12,5
13.0RT
Rel. Int.
100%
Fn 1
218.9856
QC Check
9,03-13.00
0%-^r
Results: P:\P9400_P94S9\P9464_6042 PCB\resources\P94S4_6042_PCB_001.utp_ms. saved 24-M-2008 11:13 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc 3177, 8785
Abs. Int.
05e8
5.26e7
O.OOeO
12.5	13.0RT
Peak annotation: Areas, Centroids/
Revised: 24-M-2008 11:02:33 (EE) Printed: 05-Aug-2008 08:27:34 Page 3 oUn
-------
AP Lab ID: P9464_6042 _PCB_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb040i_cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Ret. Int.
100%-
Fn 1
222.0003
DiCB-1
4o 9.25e3
9.03-13,00
0%-
"l-'i-i- » i | i¦ i i i | i i "i1	i" ¦[¦ i i i i f i i—i" P1)111 i "i""!' 'i ]• I111 i1 in i | i i i r-| «i-i -r i"|¦ t
9.5	10.0 *	10.5	11.0	11.5
"f^
'II | » f '9 ¦ f ¦ I I" f
12.0	12.5
Abs. Int.
-6.10e5
¦3.05e5
-O.OOeO
13.0 RT
Rel. Int
100%
Fn 1
223.9974
DiCB-1
40 3.31e4
9.03-13.00
Rel. Int
100%-
Fn 1
234,0406
DiCB Std.
4o 1.33e4
9.03-13.00
0%-
PCB-4
7.13e5
11.64
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std.
40 7.86e3
9.03-13.00
0%-
Abs. Int,
-6.61e5
3.31e5
t—i—i—i—|—r—i—r—i—l—r—r—i—i—r—r™i—r-™|—i—i—?—r—j—i—r—1—*—f— O.OOeO
115	12.0	12,5	13 0RT
ES-4
2.34e7
11.63
' I ' ' ' ' I '
9,5
10.0
I 1 ' 1 ' l '
10.5
lilt
11.0
I I I I i
9.5
1 I I—I I I I | I I I I | *
10,0
-i—i—I—i—i—i—i—j—i—r-
11.63
12.0
10.5
11.0
11.5
1 J 1 1 * •
12,0
I I » I I
Abs. Int.
-8.85e6
•4,43e6
O.OOeO
I | I I I I | 1 I I
12.5	13.0RT
Abs. Int.
-5.56e6
•2,78e6
¦O.OOeO
12.5
13.0RT
Rel. Int.
100%-,
Fn 1
218.9856
QC Check
9.03-13.00 .
Abs. Int.
05e8
5,26e7
Results: P:\P9400_P9499\P9464_6042 PCB\resaurcesSP9464_6Q42_PCB_001.utp ms. same1 24-M-200S 11:13 (EE)
AP UltmTrace-Prn V.3.993 User/System: EE/EEC2-038 cc: 8278, 9828
O.OOeO
13.0RT
Peak annotation: Areas. Centruids
Revised; 24-Jut-2QQB 11:02:3? (EE) Printed: Q$-Aug-2Q08 08:27:35 Page W?
-------
AP Lab ID: P9464_6042_PCB. 001
Instr: AutoSpec-Premier MM6
Ref, Int.
100%-
Fn 2
222 0003
DiCB-2
4o 7.74e3
13.07-17.79
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 59
0%-
¦+=*-
PCB-9__-, ,, PCB-e
1 36e6PCB"7 1.27e6
13 38 3.82e5 13.75
13.5** "
13.5
PCB-o
6.01e6
14.13
14.0
!¦ |
14.5



PCB-11




9.67e6




16.27
ft





PCB-13/12



\
1 .osee



\
16.53


i • ¦ 1 * ( * ¦
¦ *r,,v
^	
15.0
15 5
16,0

16.5
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05_EQ
Abs. Int.
-2.90e6
PCB-1 S
2.72e6
16.81
17.0
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4o 2.71 e4
13.07-17.79
0%-
PCB-8
3.9866
14.13
13.75 1 63e
14.0
PCB-9	PCB.6
VH£pPCB-7	9.86e5	PCB-SI
3,18e§	"""" 	1
13.54
T
13.5
1—i—i i i—r-r-
PCB-11
6.21 e6
PCB-15
1.86e6
PCB-13/12 16.81
6.92e5
16.53
14.0
14,5	15.0	15.5
-1—[—i—i—i—i—|—r~
16.0
16.5
i
17.0
Rel. Int.
100%-
Fn 2
234.0406
DiCB Std.
4o 2.06e4
13.07-17,79
0%-
JS-9
4,38e7
13.38
ft
MX
j i i i i i
13.5
' I ' "
14.0
14.5

• I ¦
15.0
I I I I | \
15.5
I | I > i | j
16.0
' T '
16.5
4.3Qe7
16.79
17.0
Rel. Int.
100%-
Fn 2
236,0376
DiCB Std.
4o8,75e3
13,07-17.79
0%-
JS-9y
2.71 #7
!3
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxIOO .a Vial:
59
Acq: 24-JuI-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Re I. Int.
100%-
Fn 2
255.9613
TrCB-2
4o 2.86e3
13.02-17.79
0%-
13.5
PCB-19
2.72eS
14.39
tAt
PCB-17
1.44e6
16,37
PCB-16
1.02e6
14.0
14.5
15.0
A PCB-27 16/7
Ay a
PGB-32
1,24e6
17.22
15.5
16.5
17.0
1 ' 1 I 1
17.5
Abs. Int.
-9.96e5
4.98e5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
257.9584
TrCB-2
4 a 4.13e3
13.02-17,79
0%-
	I	
13,5
PCB-19
2.54e5
14.38
1 I ' 1 11 1
14.0	14.5
| t » I I | I I
15.0
1 I ' 1 1 1 I
15,5
PCB-17
1.39e6	PC8-16
16,37
A PCB-27 16.77
24%5 f\
rr i
16.0

PCB-32
1.22e6
17.22
16.5
r | i *i i i | f
17.0
P* ¦ • ¦ | i i i i |
17.5
Abs. Int.
-9.42e5
•4.71e5
-O.OOeO
RT
Rel. Int.
100%-
Fn 2
268.0016
TrCBStd,
4o 4.52e4
13.02-17.79
0%-
6.38e6
13.44
3.63eB
17.07
Rel. Int.
100%
Fn 2
269.9986
TrCB Std
4a 6.19e4 .
13.02-17,79
0%-
"» 1 »"> "I	»	| Tl^jn	i|i u'jinpiMf' t , I~n l I "inj j n	>fi V	|| ) ! |' I T I' i ["II rfjl 1 I*
13.5	14 0	14.5	15 0	15.5	16,0
ES-19
A
9.73e5
13.45
1 I ' ' ' 1 I 'r
16.5
T
,,, A.-
Abs. Int.
-6.72e6
•3.36e6
17.0
8.06«5
17.04
13.5
14.0
14.5
' I I' I I I I | ! 1 I I | I I I I ) I I ! I | I « I
15.0	15.5	16.0
16 5
17.0
		i i p") 0.OOeO
17.5	RT
Abs. Int.
6.40e6
-3.20e6
17.5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.02-17.791
Abs. Int.
-6.74e7
-3.37e7
0%-
13.5
"T""!""!""!	r-
14.0
' I 1 ' ' ' I
14.5
1 ) 1 ' ' '
15.0
-i—|—i—i—r-i—|—i—!—i—i—f—i—p—i—i—|—i—r ¦ r t	^—i—i—i r |—i—i—r-T—|—r-
15.5	16,0	16.5	17.0
Results: P:\P9400_P9499\P9464_B042 PCB\msouKes\P9464_6042_PCB_001.ulp_res, saved 24-Jul-2008 11:13 (EE)
AP UttraTrace-Pm V3.993 User/System: EE/EEC2-038 cc; 9643, 5018
17.5
-O.OOeO
RT
Peak annotation: Areas, Centroids
Revised: 24-Jul-200S 11:04:05 (EE) Printed: 05-Aug-2008 08:27 37 Page 6 oyt
-------
X
AP Lab ID: P9464_6042_PCB_G01
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
255.9613
TrCB-3
4o 3.51e3
17.81-23.26
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 59
0%-
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
4o 4.33e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
268.0016
TrCB Std.
4o 4.90e4
17.81-23.26
0%-
1—I—'
18.0
18.0
«PCB-28/20
PCIfl 6.11e6
5.47e6 19 41
19.16 a'4
PCB-26/29
1.16e6PCB-25
18.89 5.48e5
19.09
/\
T
A
PCB-26/29
1-12e6pcB-25
18.69 4 9765
A 1^9
PCB-21/33
3.59eB
PCB-28/20
rCB-31
5.94e6
5.37e6
19.16
PCB-21/33
3.46ee
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05_EQ
Abs. Int.
-1.66e6
PCB-22
2.O9e0
19.95
PCB-35
1.60eS
22.45
1—1
20.0
PCB-22
2.00e6
19.95
i—,—,
21.0
22.0
T
PC8-37
1.11e6
22.80
23.0
20.0
21.0
22.0
SS-28
3.44e7
19.39
18.0
19.0
t" | i
20.0
PCB-35
1,68e5
22.45
—r-^i	
PCB-37
1.08e6
22.80
A
23.0

ES-37

3.04e7

22.78
A
4.91e6

20.79
/ \

						 —J.	..L,
-8.30e5
-O.OOeO
RT
Abs. Int.
-1,63e6
¦8.14e5
-O.OOeO
RT
Abs. Int.
-9.49e6
-4.75e6
21.0
22.0
23.0
-H-O.OOeO
RT
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
4a 4.53e4
17.81-23.26
0%-
18.0 '
1—I—1
19,0
20.0
21.0
22.0
ES-37
2.87e7
gyrs
23.0
Abs. Int.
-8.78e6
-4.39e6
¦O.OOeO
RT
Rei. Int.
100%
Fn 3
292.9824
QC Check
17,81-23.26
Results: P:\P9400_P9499\P94S4_S042 PCB\ra$Qurce$\P9464_6O42_PC8_00lMtp_re$. saved 24-Jul-2008 11:13 (EE)
AP UltmTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 1603. 8209
Abs. Int.
-6.86e?
3,43e7
O.OOeO
RT
Peak annotation: Areas, CentmkK
Revised: 24-Jul-2008 11:05:03 (EE) Printed: 05-Aug-2008 08 27:38 Page Tp22
-------
AP Lab ID; P9464_6042_PCB_0G1
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ DatafHe: 080724V05 EQ
Rel. Int.
100%
Fri 2
289.9224
TeCB-2
4o 1.32e3
13.02-17.79
Abs. Int.
-5 31e3
2.66e3
T—OOOeO
RT
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o2.12e3
13.02-17.79
Rel. Int.
100%
Fn 2
301.9626
TeCB Std.
4o 6.91 e3
13.02-17.79
Rel. Inl,
100%-
Fn 2
303.9597
TeCB Std.
4o4.19e3
13,02-17,79
0%-
Abs, Int.
-7.78e3
3.89e3
O.OOeO
ES-54
t.gse?
Abs. Int
5.91 e6
17.05
2.95e6
i i i i i ; i i t i I * O.OOeO
17.5	RT
ES-54"
17,05
I I I I t I I I 1 I I f I I I I
13.5
14.0
14.5
15.0
15.5
I	I
16.0
16.5
-i—i i i —i—rl—i—[~~
17,0
Abs. Int.
-7.19e6
¦3.59e6
T— O.OOeO
17.5	RT
Rel. Int.
100%-i
Fn 2
242.9856 •
QC Check
13.02-17.79"
Abs. Int.
-6.74e7
-3.37e7
0%-
i | I I I
13.5
| 1 I I « | » I I I |
14.0
14.5
15,0
15.5
Results: P:\P9400_P9499\P9464_B042 PCB\resources\P9464_6042_PCB_00lMtp_ms, saved 24-Jul-2Cl08 11:13 (EE)
AP UltraTrace-Pro V3 993 User/System: EE/EEC2-038 cc: 5056, 5343
16.0
16.5
1 I '
17.0
i i i | O.OOeO
17.5	RT
Peak annotation: Areas, Centimes
PKD: 24~Jul-2008 10:57:32 Printed: 0S-Aug-2008 08:27:40 Page 8ff >2
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Rel Int.
100%-
Fn 3
289.9224
TeCB-3
40 1 30e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4o 1.43e3
17.81-23.26
0%-
18.0
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 59
PCB-44M7/65
1.61©6
21.82
PCB-50/53
1,90e5
18.92
/\
PCB-45
2.40eS PCB-46
19.50 1 0085
19.76

19.0
20.0
PC B-50/53
2.5265
18.92
A
18.0
19.0
PCB-45
2.58e5 PCB-46
19,49 1 0385
19.76
¦ I ¦
20.0

PCB-52
1.43e6
20.97
PCB-69/49
8.77e5
21.38
PC8-48
3.40e5
21.62
PCB-52
1.83e6
PCB-44M7/65
2.12e6
21.82
PCB-69/49
1.18S6
21.38
PC8-48
4.14e5
21.62
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Abs, Int.
-3.95e5
PCB-59/62/75
1.6565 .
A
6.05e5
22.65
PCB-41
1.31e
22.57,
23.0
PC 8-64
?.98e5
22.86
PCB-59/62/75
1.90e5
22.08 /\
A^4-X-
PCB-41
¦1.97e5
-O.OOeO
RT
Abs. Int.
-4.92e5
2.46e5
21.0
22,0
23.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
301.9626
TeCBStd.
40 6.51e3
17 81-23.26
0%-
Rel. Int.
100%-
Fn 3
303.9597
TeCBStd.
4o 3.58e3
17.81-23.26
0%-
18,0
19.0
20.0
21XK
JS-5B
22.0
23.0
i I I f
18.0
19.0
20.0
21.0
22.0
Abs. Int.
-5.41e6
2.70e6
-O.OOeO
RT
Abs. Int.
-6.70e6
-3.35e6
O.OOeO
23.0	RT
Rel. Int.
100%
Fn 3
292 9824
QC Check
17.81-23.26
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_001vtp_res, saved 24-Jut-2Q08 11:13 (EE)
AP t/teaTrace-Pro 1/3 993 User/System: EE/EEC2-038 cc: 5705, 2795
Abs. Int.
6,86e7
3.43e7
O.OOeO
RT
Revised: 24-M-2008 11:06:21 (EE)
Peak annotation: Areas, Centrpitfs
Printed: 05-Aug-2Q08 08:27:41 Page 9fit 22
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_c!1-10_mm6 GC: pcbx100_a Vial:
59
Rel. Int.
100%-
Fn 4
289,9224
TeCB-4
4o1.80e3
23,27-33,00
0%-
Rel, Int.
100%-
Fn 4
291.9194
TeCB-4
4a 3.03e3
23.27-33.00
0%-
Rel. Int.
100%-
Fn 4
301,9626
TeCBStd.
4o5.19e3
23 27-33,00
PCB-61/70/74/76
2.00e6
25.01
PCB-68
t.t8e5
23.80
. .A. ,
PCB-67
7.63e4
24,50
24,0
PCB-66
B.BSeo
25,28
PCB-56
4,16e5
25.84
/
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05_EQ
Abs, Int.
3,95e5
-1.97e5
PC8-77
1.2leS
28.94
25.0
26.0
27.0
28.0
-^r
29.0
30.0
	-	r' ' lf	1
31.0
1 'I I I » > I™
32.0
PCB-61/70/74/78
2.59e6
25,01
PCB-68
1.79e5
23,00
A
PCB-67
7.95e4
24.49
24.0
i
j J
25.0
PCB-86
1.14e6
25.28
PCB-77
1.58e5
28.94
26,0
27.0
28.0
T
ES-B1
2,20e7
28.46
A-
-O.OOeO
RT
Abs. Int.
>4.61 e5
•2.41e5
29,0
ES-77
2.24e7
28.92
300
i n" i j i t i t j i i i ") "j i—i—t*t—*— 0.GOeO
31.0	32.0	RT
Abs. Int.
5.44e6
¦2.72a6
11
0% i | i i i i | i i i i ) i i i i ( F'" i '"i" "i	) i i i i | i i P"i ) i i t i | i i ) i j t i i i ) i i i 'i i n p	ft i i )
24.0	25.0	26.0	27,0	28.0	29.0
30.0
31,0
32.0
Rel. Int.
100%.
Fn 4
303.9597
TeCB Std.
4o5.11e3
23.27-33.00 -
0%-
ES-81 fS-71
2.70e7
28.48 26.92
7,19e5
26.34
I I | '1 1111 !"|	, j C 1 ' I i | I i I | | 1 | | 1 | | 1	| 1 1" I I | I I I I j
24.0	¦ 25.0	26.0	27.0
I
28,0
11 •1 		r-'				"
29.0
30.0
31.0
I '
32.0
-O.OOeO
RT
Abs. Int.
-6,55e6
•3.27e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn4 :
330.9792 •
QC Check
23.27-33.00 .
Abs. Int.
-5.80e7
-2.90e7
0%-
24,0	25,0
26.0
27.0
| I T I I j1 I
28.0
T I I { ( I I
29.0
30.0
31.0
32.0
-O.OOeO
RT
Results: P:\P9400_P9499W9464_6042 PC8\resaurcesSP9464_6042_PCB_00lMtp_ms, saved 24-M-200B 11:13 (EE)
AP UttmTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 3559, 5603
Peak annotation: Areas, Centmietf*
Revised: 24-M-2008 11:07:13 (EE) Printed: QS-Aug-2008 08:27:42 Page 10 of i
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Via!: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05_EQ
Rel. Int.
100%
Fn 3
323.8834
PeCB-3
4 a 1.41e3
17.81-23.26
Abs. Int.
-6.87e3
3.44e3
O.OOeO
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
4o1.81e3
17.81-23.26
0%-
18.0
19.0
20.0
21.0
22,0
Abs. Int.
-2.01 e4
¦1,01e4
r—r—O.OOeO
23,0 RT
Rel. Int.
100%-
Fn 3
337.9207
PeCB Std.
40 2.91e3
17.81-23.26
0%-
	[¦	!
18.0
19.0
—i—r
-¦—¦—i—1
20,0
21.0
22.0
23,0
Abs. Int.
-7.06e6
¦3.53e6
-O.OOeO
RT
Rel. Int.
100%-
Fn 3
339.9177
PeCB Std.
4a 3 97e3
17.81-23,26
0%-
18.0
19,0 '
20.0
I I | f I I I J
21.0
22.0
Abs. Int.
-4,68e6
-2.34e6
-j—i—r— O.OOeO
23.0	RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P:\P9400_P9499\P9464_e042 PCBSresources\P94S4_S042_PCB_001.utp_ms, saved 24-Jul-20oe 11:13 (EE)
AP Ultra Tmce-Pm V3.993 User/System EE/EEC2-038 CC: 2879, 3592
23.0
Abs, Int.
6.86e7
3.43e7
-O.OOeO
RT
Peak annotation: Are as. Centrojtfs
Revised: 24-M-200B 11:07:17 (EE) Printed: 0S-Aug-2008 06:27:43 Page 11 o( 22
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_d1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Rel. Int.
100%-
Fn 4
323.8834
PeCB-4
4o 2.30e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
325.8804
PeCB-4
4o 1.88e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
337.9207
PeCBStd.
4 a 3.75e3
23.27-34 14
0%-
Re!. Int.
100%-
Fn 4
339.9177
PeCB Std
4o 3.16e3
23.27-34.14
0%-
PCB-95
5.39eS
24.27
PCB-113/90/101
7.13e5
26.74
PCB-91
9,59e4
24.99
-OA.
PCB-92
9 85e4
26.24
A.
PCB-110
6 S7eS
28.38
/
P2t
27.22
08/119/86/97/
4.2385
27.68 PCB-11
8.:
28.
.22(1
2)
PfeB-82
5.88e4
26.65
w A i, I,
24.0
26.0
28.0
30.0
PCB-118
4.00e5
i
/
PCB-105
1.29eS
31J

¦*/^1
32.0
PCB-95
9.07©5
24.27
PCB-113/90/101
1.19e6
26.74
¦—I—»-
24.0
24,0
i—|—.
24,0
PCB-110
1.07e6
28.38
PCB-91
1.36e5
24.99 A
A 71
PCW9108/119/86/97/
3.94e5 7.05e5
PCB-92 I 27-22 27.68 pcB-11
1.65eS	(1 ft 1.28d
26 25	I t*\ 28.2
(\, }\	21	LA	A
S&B-82
[9.4964
28.65
At-
26.0
PCB-118

5.87e5

30.88

ft
PCB-105

2.0Se5
I
31,86
V		T"--1

28.0
30,0
JS-101
2.46e7
26.72
SS-111
2,9067
28.95
ES-123
2.41e7
30.59 ,
ES-114
2.65e7
31.30
32.0
ES-105
2.57e7
31.84
26.0
28.0
30.0
JS-iaV
tS6e7
26.72
SS-11V
1 .&6eT
2T
1.53e7
32.0
ES-m es-105--
3f84
31.30
Lai
26.0
28.0
30.0
32,0
Abs. Int.
-1.77e5
¦8.84e4
I 'i" i^i 	r"	|	 0.00e0
34.0 RT
Abs. Int.
2.97e5
1,48e5
-r—O.OOeO
34.0 RT
Abs, Int.
-7.15e6
-3.58e6
-O.OOeO
34.0 RT
Abs. Int.
4.62e6
-2.31e6
¦O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
330.9792
QC Check
23,27-34.14'
0%-
1—I—1
24.0
26,0
28.0
30.0
1—r_
32,0
Abs. Int.
-5.80e7
-2.90e7
¦O.OOeO
34.0 RT
Results: P:\P94Q0_P9499\P9464_6042 PCB\msOtIKes\P9464_6042_PCB_0OlMtp_ms, saved 24-Jul-2008 11:13 (EE)
AP UliraTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 8163, 522$
Peak annotation: Areas, Cenbpius
Revised: 24-Juf-200B 11:09:57 (EE) Printed: 0S-Aug-2008 08:27:44 Page J2W 22
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID; Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Ref. Int.
100%-
Fn 5
323.8834
PeCB-5
4o 2.52e3
34.16-41.15
0%-
35.0
J I T" < 1 | I 'I I > | >
36.0

37.0
38.0
^ l r
39.0
"I *~
40.0
Abs. Int.
r5.70e5
¦2.85e5
¦ i ¦ | ¦ O.OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4o 2.40e3
34.16-41.15
0%-
Rel. Int.
100%-
Fn 5
337.9207
PeCB Std.
4o6.17e3
34.16-41.15
0%-
Rel. Int.
100%-
Fn 5
339.9177
PeCBStd.
4o 5.84e3
34.16-41.15
0%-
ES-126
2.83e7
34.41
35.0
¦"i	i	|	r	r	t "'i'—I t
36.0
i | i	> |
1 1 1 ' j 1 I 1 f I
37.0	38.0
' I «
39.0
40.0
J, \»1 i i <
ES-m
1.7*87
34.41
35.0
36.0
8.73e5
36.92
37.0
38.0
I > I I I I
35.0
¦	'I ¦
36.0
3.14eS
36.96
37.0
38.0
t t I I | 1
39.0
40.0
39.0
40.0
Abs. Int.
r-1.71ei
•8.55e5
¦O.OOeO
41.0 RT
Abs. Int.
6.53e6
• 3.26e6
e | i 1 0. OOeO
41.0 RT
Abs. Int.
r4 18e6
2,09e6
¦O.OOeO
41.0 RT
Rel, Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15'
0%-
35.0
"T—r
'T	T	T	f'"'
36.0
' I 1
37.0
38.0
Results P:\P9400_P9499\P94S4 6042 PC8Vssouices\P9464 6042_PCB_001.utp res. saved 24-Jul-2008 11:13 (EE)
AP VttmTrace-Pm VI993 User/System: EESEC2-038 cc: 2677. 0398
39.0
40.0
Abs. Int.
r2.43e7
¦1.22e7
41.0
¦O.OOeO
RT
Peak annotation: Areas Centroids
Revised: 24~Jut-2008 11:09:59 (EE} Printed OS-Aug-2008 08:27:45 Page 13 of 27
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
359,8415
HxCB-4
4 a 1,45e3
23.27-34,14
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl 1 -1 Q_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
0%-
PCB-147/149
2.05e6
29.92
PCi-136
4.36e5
27.15
Rel. Int.
100%-
Ffl 4
361.8385
HxCB-4
4cr 1,22e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
371.8817
HxCBStd.
4 a 1,64e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
373.8788
HxCBStd.
4o 2.38e3
23.27-34.14
0%-
1—I—'
24.0
A
PCB-151/135
8 96eS
29.16
PC B-144
8.68e4
29,63
PCB-132
5.73eS
30.97
PCB-163/138/129
1.33e6
33.48
26.0
PCB-153/168
1.43e6
32.44
:B-141
PCB-146
PCB-16
2.67e5
i2,6Q
1,28eS
31,93
33,22
Abs. Int.
-4.93e5
2.46e5
•O.OOeO
28.0
30.0
PCB-147/149
1.57e6
29.92
32.0
34.0 RT
PCB-13S
3.64e5
27.15
A
PCB-151/135
7.19eS
29.16
PCB-144
7.83e4
29,63
—p*_,
PCB-153me PCB-163/138/129
\i2.e.B	1 10e6
32.44	334g
PCB-132
4,33e5
30.97
6 62e4
%,10
24.0
26.0
28.0
A
PCB-146
2.18e5
31.92
1.SZ	ft
a	Ua
30.0
"T
32.0
?B-141
60e5 PCB-16^
'2.60 1 27e5
33.22
-A J
ES-155
2.33e7
26.53
ES-153
1.B8e7
32.42

24.0
26.0
28.0
30.0
32.0
ES-15
ES-153
1.53b7
32(42
24.0
26.0
28.0
30.0
32.0
T"
JS-138
1.83e7
33.45
JS-136
1.41a?'
33T35
11
Abs, Int.
-3.99e5
-2.00e5
^"T
34.0
-O.OOeO
RT
Abs, Int.
-5.90eS
•2.95e6
¦O.OOeO
34.0 RT
Abs. Int.
-4,65e6
2 32e6
•O.OOeO
34 0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Results: P:\P9400_P9499\P9464_6042 PCBVesoufCesV9464_6043_PCB_001.ulp_res, saved 24-M-2008 11:13 (EE)
AP UltraTrace-Pfo V3.993 User/System: EE/EEC2-038 cc: 8124. 0465
Abs, Int.
5 80e7
2.90e7
O.OOeO
34.0 RT
Peak annotation: Areas. Centmids
Revised: 24-M-2008 11:10:49 {EE} Printed: 05-Aug-2008 08:27:47 Page 14/M 22
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 5
359.8415
HxCB-5
4o 1.39e3
34,16-41.15
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb040^_cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:4i:55
User: JLJ Datafile: 080724V05 EQ
Abs, Int.
-2.78e4
PCB-159
8.53e4
35.32
PCB-156/15?
36.92
1.3964
'-A--—ftp	^ * | * | -j	j
00e0
41.0 RT
Rel. int.
100%
Fn 5
361.8385
HxCB-5
4o1.56e3
34.16-41.15
Rel. Int.
100%
Fn 5
371.8817
HxCB Std.
4a 6.50e3
34.16-41.15
Rel. Int.
100%
Fn 5
373.8788
HxCB Std.
4a 4.80e3
34.16-41.15
0%
PCB-159
7.23e4
35.32
Abs, Int.
-2.22e4
1.1164
O.OOeO
Abs. Int.
-7,27e6
3.64e6
PCB-156/157
4.62s4
36.92

41.0 RT
4.28e7
36.92
ES-167
2.06e7
35.96
ES-168
2.03e7
39.61
36.92
S-169
1.59e7
39.61
O.OOeO
Abs. Int.
-5.82e6
2 91e6
O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
f 1 1 |
35.0
36.0
| l l l i—[—r
37.0
'"f	T	t	t	T	J	T	T	r	T	I"'
38.0
39.0
Results: P:\P9400_P9499\P9464_6042 PCB)msouwesSP9464_6042_PCB_OOlMtp_res, saved 24-Jui-2008 11:13 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-03S cc 4823. 2120
40,0
-r_T-
Abs. Int.
-2.43e7
•1.22e7
—j—r-4-- 0. OOeO
41,0 RT
Peak annotation: Areas. Centmjd£
Revised: 24-Jut-2008 11:11:09 (EE) Printed: 0S-Aug-200B 03 2 7 48 Page 1Sjff22
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
393.8025
HpCB-4
4o 1 59e3
30.00-34.14
0%-
Rel. Int.
100%
Fn 4
395.7995
HpCB-4
4o1.23e3
30.00-34.14
0%-
Rel. Int.
100%-
Fn 4
405.8428
HpCB Std.
4ct 1.92e3
30.00-34.14
0%-
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 59
PCB-179
1.09e6
31.60
30.5
' I ¦ 1 | ' I"1"1' ,nrT
31.0	31.5
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Abs. Int.
-3.03e5
PCB-176
2.65e5
32 33
PCB-17B
3.06eS
33.85
V i f r-i i—tt r i T"
32.0
T-r-
32.5
¦1.52e5
33.0
-i—|—i—i—i—r—|—r-~i—i—i—|—i—i—i—i—
PCB-179
1.08e6
31.60
PCB-176
2.53e5
32.33
305
"I—I I I | 1 I I t | 1
30.5
Rel. Int.
100%-
Fn 4
407,8398
HpCB Std.
4a 3,45e3
30.00-34.14
Q%-
I < i ! I r t
30.5
31.0
31.5
32.0
32.5
33.0
ES-188
2.26e7
31.30
I I I I I I I I
1 I I > t I i I I
31.0
31.5
32.0
32.5
1 I '
33.0
ES-188/
2 160?
31*30
33.5
33 5
33 5
r r O.OQeO
34.0 RT
Abs, Int.
r2.83e5
PCB-178
29665
33.86
A
I I *> f 1
¦1.41e5
•O.OOeO
34,0 RT
$$-178
1 49e?
33.83
Abs. Int.
-5.61e6
•2.80e6
I I I I ! I I1 I I I TI I I I I I I
31.0
31.5
| ! !	1	T	1	TTTT|TTV1"|ll«r|
-l-'T" I	1	1	J	I	1	1 T I I	" I I I I
SS-178
1.42e7
O.OOeO
34.0 RT
Abs. Int.
5.41 e6
•2.71e6
¦O.OOeO
32.0
32.5
33,0
33,5
34.0 RT
Rel. Int,
100%
Fn 4
330.9792
QC Check
30.00-34.14
30.5
Abs. Int.
80e?
2.90e7
31.0
31.5
32.0
32.5
33.0
33.5
O.OOeO
34.0 RT
Results: P:\P94Q0_P9499\P94G4_6042 PCB\resourcesSP9464_6042_PCB_001.utp_ms, saved 24-Jul-2008 11:13 (EE)
APUttmTmce-Pro V3.993 User/System: EE/EEC2-03B cc; 1727. 7817
Peak annotation: Areas, Centmips'
Revised: 24-Jul-2008 11:11:19 (EE) Printed: 05-Aug-2008 08:27:49 Page 16 gt22
-------
AP Lab ID: P9464_6042_PCB_001
Instr; AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial:
Acq: 24-Jul-2008 03:49:55
User: JU Datafile: 080724V05 EQ
Rel. Int.
PCB-187
100%-j
1.79e6
Fn 5 :
34.61
A
393.8025 ¦
ft
HpGB-5

40 2.28e3

34.16-41.15 ;

0%-
, ,-JA	
PCB-174
i.74ee
PCB-177
PCB-183
6.7365
5.80e5
35.68
35.12
PCB-171/173
2.46e5
36.20
. ,A, .
35.0
36.0
37.0
PCB-172
t.5leS
37.55
¦ n .
PCB-170
7.65e5
39.14
PCB-190
1.91e5
39.58
S\ ~
39.0
40.0
Abs, Int.
-5.22e5
2,61e5
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4a 1 08e3
34.16-41.15
0%-
PCB-174
1.69e6
35.32
i O" I"
PCB-187
i.70efl
PCB-177
PCB-183
6.5ue5
5,62e5
PCB-171/173
35.12
2.08e5
35.0
~i—i—i—p
36.0
T r
37.0
PCB-172
1,46e5
37.55
—i——r-
PCB-170
7.48e5
39.14
38.0
39.0
PCB-190
1.93e5
39.58
f	^	I	' f	i
40,0
Abs. Int.
-5.34e5
2.67e5
~i—i—i—i—]—r*~ O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std.
4a 3.78e3
34.16-41.15
0%-
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std.
4o 2.80e3
34.16-41.15
0%-
' ' ' I 1
35.0
ES-170
1.51e7
39.12
'	35.0
"v—1	-f	t	t	t	i",Mt	t—i—>	j	«	i	i	i	J	i	r	r	r	^	i	*i	r	r	|mi
36.0	37.0	38.0
ES-rn^
tkseT
38.07
\
""I	I		f*'"T	T	|	1	T	T	I	I	t	t	»	I	I""1
39.0	40.0
¦ ! '
36.0
' I "
37.0
ES-170
1.46b7
Abs. Int.
-3.81e6
¦ 1.90e6
•O.OOeO
T—p
41.0 RT
Abs. Int.
-3.54e6
-1.77e6
O.OOeO
38.0
39.0
| I I I I | I I T I | I I I I j
40.0	41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15'
0%-
35.0
• I '
36.0
37.0
38.0
1 I '
39.0
Abs, Int.
-2.43e7
l.22e7
40.0
41.0
¦O.OOeO
RT
Results: P'\P9400_P9499'\P9464_6042 PC8\resourcesSP946042_PC8_001.utp__res, saved 24-Jui-20Q8 11:13 (EE)
AP UtlraTrace-Pro V3 993 Userhystem: EE/EEC2-038 cc 7809 3201
Peak annotation: Areas, Centroi
Revised: 24-M-2008 11:12:19 (EE) Printed: 0S-Aug-2008 08:27.50 Page 17 ot/22
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_rnm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05_EQ
Rel. Int.
100%-
Fn 6
393,8025
HpCB-6
4 o 2.20e3
41.17-46-41
0%-
42.0

43.0
/Wwy^.
44.0
Abs, Int.
-3 79e4
1.90e4
Rel. Int.
100%-
Fn 6
395,7995
HpCB-6
4a 9.68e2
41.17-46.41
0%-
Rel. Int.
100%.
Fn 6
405.8428
HpCBStd.
4 o 6,59e3
41.17-46,41
0%-
Rel. Int.
100%-
Fn 6
407.8398
HpCB Std.
4o 5.00e3
41.17-46.41
0%-
42.0
ES-189
2.26e7
41.70
42.0
ES-189
2.180?
^*70
43.0
5.07e5
43.44

Abs. Int.
-1 04e4
5.20e3
44.0
43.0
44.0
4.89e5
43.84
45.0
45.0
46.0
46.0
^-O.OOeO
RT
Abs. Int.
-5.01e6
•2.51e6
-O.OOeO
RT
Abs, Int.
-4.72e6
•2.36e6
42.0
43.0
44.0
45.0
46.0
-O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41'
0%-
42.0
T—r-r
mi	l	Tm
43.0
44.0
45.0
Results: P:\P9400_P9499\P9464_S042 PCB\resources\P9454_6042_PCB_001.utp_rzs. saved 24-Jul-2008 11:13 (EE)
AP UltmTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 3740, 2790
46.0
Abs. Int.
-2,44e7
¦ 1,22e7
¦O.OOeO
RT
Peak annotation: Areas. Centnxdss
Revised: 24-Jul-2008 11:12:21 (EE) Printed: OS-Aug-2008 08:27:51 Page 18 0122
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 5
427.7635
OcC8-5
4o 1.25e3
34.16-41.15
0%-
i i r i * i f •
Rel. Int.
100%-
Fn 5
429.7606
OcCB-5
4a 9.78e2
34.16-41.15
0%-
35.0'
1 1 1 1
35.0
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Data file: 080724V05 EQ
PCB-202
2.57e5
35.79
JL.
pcB-201
1.91e5
36.55
A
PCB-200
2.32e5
37.39
36.0
37.0
38.0
PCB-202
3.04e5
35.78
l*| 1 "f 1 1
36.0
PCB-201
2.02e5
36.55
A
37T0
PCB-200
2.70e5
37.39
PCB-198/199
1.09e6
39.72
PCB-196
4.07eS
40.27
390
40.0
PCB-19BM 99
1.22e6
39.72
T T'		f		T	T"
38.0
	T""t	|	f
39.0
111	i1111			'"J*1 1
40.0
PCB-196
4.92e5
Abs. Int.
-2.62e5
•1.31e5
•O.OOeO
T
41.0 RT
Abs. Int.
-2.72e5
1.36e5
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
439.8038
OcCB Std.
4o 1.55e3
34.16-41.15
0%-
i i r | » » i r | r
35.0
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std.
4o 2.55e3
34.16-41.15
0%-
' I | I I I T |
36.0
t—1—1—I—1—1—r—1—1—1—1—r-
ES-202
1.93eZ^
i5.tr
IS
35.0
36.0
37,0
38.0
39.0
37.0
38.0
39.0
40.0
4,4Be5
40.25
I fT», |
40.0
Abs. Int.
-4.41 e6
2.21e6
O.OOeO
1 ' 1 1 1 1
41.0 RT
Abs. Int.
-4.63e6
•2.31e6
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
""t	1	r	1	1	1	> 11
35.0
36.0
37,0
| " * f "f-f 1 I "t—T"
38.0
1 1 1
39.0
Results: P:\P9400_P9499\PB464_6042 PCB)m$aurte$\P9464_W42_PCB_001.utp_ms. saved 24-Jut-2008 11:13 (EE)
AP UltraTmce-Pm V3.993 User/System: EE/EEC2-038 cc 5996, 4434
40.0
Abs, Int.
-2.43e7
• 1,22e7
-O.OOeO
41.0 RT
Peak annotation: Areas. Centrokis
Revised: 24-M-2008 11:12:46 (EE) Printed 05-Aug-2008 08 27:52 Page 19 &22
-------
AP Lab ID; P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 6
427.7635
OcCB-6
4o 7.55e2
41.17-46.41
0%-
Rel. Int.
100%-
Fn 6
429.7606
OcCB-6
4o 1,46e3
41.17-46.41
Rel. frit.
100%-
Fn 6
439.8038
OcCBStd.
4o 1.54e3
41.17-46.41
0%-
PCB-195
3.08e5
41.53
Rel, Int.
100%-
Fn 6
441.8008
OcCB Std.
4o2 24e3
41.17-46.41
0%-
0%-s—
i—p
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial; 59
PCB-1S4
8 38e5
43.46
42.0
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
Abs. Int.
- 1.76e5
-f^V-
42.0
42.0
43.0
44.0
9.62e3
45.28
45.0


PCB-194


8.97e5


43.46
A
PCB-195


3.2865.


41.53
A
-i—i—r—i—i- -1" i • i ¦ i
[
1.53e4
45.28
,i , «rqj-k> ,
43.0
44.0
45,0
JS-194
1.38e7
43.44
43.0
ES-205
1.45e7
43.83
44.0
1	1	
45.0
3.26e5
45.28
|
JS-194
1.5307
ES-2D5
1J8e7
45.83
42.0
43.0
i [ 'i i '
46.0
I * * "
46.0
46.0
-8.82e4
-O.OOeO
RT
Abs. Int.
-1.92e5
¦9.58e4
-O.OOeO
RT
Abs, tnt.
-3.07e6
1.53e6
¦O.OOeO
RT
Abs. Int.
-3 30e6
•1.65e6
44.0
45.0
46.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46,41"
0%-
42.0
43.0
,—,—
44.0
45.0
Results: P:\P9400_P9499\P9464_6042 PCB\re$aurws\P9464_6042_PCB_001.utp_res, saved 24-JM-2008 11:13 (EE)
AP UltmTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 2763. 9768
46.0
Abs. Int.
r2.44e7
-1.22e7
¦O.OOeO
RT
Peak annotation: Areas, Centmidps
Revised: 24-Jut-2008 11:13:09 (EE) Printed: OS-Aug-2008 08 27 53 Page 20 0^2
-------
PCB-208
6.54a4
41.33
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-,
Fn 6
461,7245
NoCB
4a 1 ,09e3
41.17-46.41
Rel. Int.
100%-
Fn 6
463.7216
NoCB
4a 1 82e3
41.17-46.41
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405.cl1-10_mm6 GC: pcbx100_a Vial: 59
Acq: 24-Jul-2008 03:49:55
User: JLJ Datafile: 080724V05 EQ
0%.
PCB-208
8.09e4
41,33
Fn B
473.7648
NoCB Std.
4o 1.93e3
41.J7-48.41
0%-
100%-
Fn 6
475,7619
NoCB Std.
4a 1 49e3
41.17-46.41
0%-
41.31

ES-208
Rel. Int. ^f467
100%-, 4131
ES-208
Rel. Irit.
PCB-206
2,27e5
45.29
PCB-207
4,38e4
42.10
42.0
43.0
"¦A*	

44.0
-f—r

—
45,0
PCB-206
2.86e5
45,29
PCB-207
5.84 ©4
42.08
A
42.0
		
43.0
iVf	i-Tji fnf -art 	j		i
44.0
45.0
42.0
43.0
1—¦—1—«—'—I—'—•"
44.0
ES-208
6.9566
45,0
ES-208
1.16e7
J/S.27
1—I—'—
42 0
-j	.	1	1	1	j	1
43.0
"1—'—'—'—1—i—p"
44.0
46,0
Abs. Int.
-4.68e4
¦2.34e4
-O.OOeO
RT
Abs. Int,
-7 28e4
3,64e4
7-0 OOeO
RT
Abs. Int.
r2.86e6
-1,43e6
1—i—i—i—f—0 0060
46.0	RT
Abs. Int.
-3.63e6
-1.81e6
45.0
46.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41"
0%-
-i—i—|—i-
42.0
43.0
1—I—""
44.0
45.0
Results: P:\P9400_P9499'
-------
AP Lab ID: P9464_6042_PCB_001
Instr: AutoSpec-Premier MM6
PCB-209
Rel. Int. 2 |ee4
100%-, 662
Fn 7
497.6826
DeCB
4o 5.09e2
46.42-54,01
Q%-
Sample ID: Run# ACD-M23-FB
VSIR expt: pcb0405_cl1-t0_mm6 GC: pcbx100_a Via): 59
47.0
PCB-209
Rel. Int. Vg4e4
100%-| 46 62
Fn 7
499.6797
DeCB
4cr 8.89e2
46.42-54.01
ES-209
Rel. Int. i-|8e?
100%-i 46,60
Fn 7
509.7229
DeCB Std.
4o 9.94e2
46.42-54.01
ES-20
Rel. Int. 1
100%
Fn 7
511.7199
DeCB Std.
4a 8.06e2
46.42-54.01
47.0
Acq: 24-Jul-2O08 03:49:55
User: JU Datafile: 080724V05_EQ
Abs. Int.
9.36e3
¦4 68e3
48.0
49.0
| > t I I | I
50.0
f |	1 I I I | 1 1 1 I | I
51.0	52,0
O.OOeO
I I | I 1 I 1 | I I l I
53,0	54,0 RT
Abs. Int.
-5.40e3
2.70e3
O.OOeO
mT	T	|	1"
48.0
' I 11 11 I
49.0
1 J I I t 1
50.0
51.0
'I 1 1
52.0
53.0
47.0
48.0
49.0
50.0
I | I I 1 I | I I I I | I I I I | I
51.0	52.0
54,0 RT
Abs. Int.
-3.53e6
1.77e6
i i r-. t O.OOeO
54.0 RT
Abs. Int.
2.95e6
1,47e6
¦O.OOeO
53.0
54.0 RT
Rel. Int.
100%-
Fn 7
454.9728
QC Check
46.42-54.01 ¦
Abs, Int.
-2 34e7
-1.17e7
0%-
47.0
48-0
49.0
50.0
Results: P:\P9400_P9499W9464_6042 PCBMesources\P9464_6042_PCB_a01.u!p_tes, saved 24-Jut-2008 11:13 (EE)
AP Ultra Trgce-Pm V3.993 Userftystem: EE/EEC2-038 cc: 6871, 3303
51.0	52.0
I I I I » 1 I
I | 1 I
53.0
j i i i i O.OOeO
54.0 RT
Peak annotation: Areas, Centroids
Revised: 24^Jul-20Q8 11:02:09 (EE) Printed: 0S-Aug-200B 08:27:56 Page 22 oP22
-------
Datafile: 080724V06_EQ
Acquired: 24 Jul 2008 04:47:22
Client ID: Run# I-ACD-M23-1 y/
Lab ID: P9464 6042 PCB 002
Wt/Vol: 1 - -TVkioI
A-level: 20 pg y
		
n°cl
CS3_6042_PCB_VAB CPSM 080724 PCB VA
Nominal ES spike: 4000 pg
F9464_6042_PCB_002
Name
PCB-77 33144'-TeCB
PCB-SI 344'S-TeCB
PCB-105 233'44'-PeCB
PCB-114 2344'5-PeCB
PCB-118 23'44'5-PeCB
PCB-123 2'344'5-PeCB
PCB-126 33"44"5-PeCB
PCB-156/157 233'44'5/233'44'51
PCB-167 231441551-HxCB
PCB-169 33'44'55'-HxCB
FCB-189 233'44'55'-HpCB
PCB-209 DeCB
Actual
RT
28
96
28
49 /
31
87 S
31
34 /
30
90 f
30
62 /
34
44 S
36
94 /*
35
99 /
39
62 /
41
72 /
46
62 /
QC
Fred
Actual
Diff


'gjCS:
RRT
RRT
Seca
Response
Ra
RRF
1.0006
1.0006
0
5.07E-07
0.77
1.05
1.0006
1.0006
0
8.94E+06
0.77
1.10
1.0007
1.0007
0
9.45E+06
0.64
0.97
1.0007
1.0006
-0.2
1.78E+06
0.62
0.94
1.0008
1.0007
-0.2
1.42E+07
0.62
0.97
1.0006
1.0008
+ 0.4
1.64E+06
0.59
0.96
1.0005
1.0005
0
1.34E+07
0.60
0.98
1.0005
1.0002
-0.7
7.21E+06
1.27
0.97
1.0006
1.0006
0
2.43E+06
1.21
0.99
1.0004
1.0003
-0.2
1.73E+06
1.33
0.93
1.0005
1.0004
-0.3
2.62E+06
1.05
0.92
1.0004
1.0004
0
1.07E+06
1.20
0.91
J
Cone
A
4,350
749
Checkcode -•
Noise
8.76E+03
8. 7SE+03
050rftQf 1.12E+Q4
207
1,570
195
1,410
951
318
251
331
214
1.12E+04
1,12E+04
1.12E+04
5.Q0E+03
6.47E+03
6.47E+03
6,47E+03
3.95E+03
1.35E+03
vo y
DL
7,67
7.48
12.8
13.6
13
13.8
5.67
12.9
9.13
10.2
5.57
3.11
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
PCB
PCB-
PCB
PC3
PCB-
PCB'
PCB-
PCB'
PCB'
PCB-
PCB-
PCB
PCB
PCB-
PCB'
PCB'
PCB-
PCB-
PCB
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
•1
•3
-4
-15
-19
-37
-54
-77
-81
-104
•105
-114
-118
-123
-126
-153
-155
•156/157
-167
-169
-170
¦180
•188
-189
¦202
•205
¦206
-208
¦209
9.48 •

11.43
s
*>
11.68

16.83 s
14.40'
22.80
s
17.09
*
28.94
s
28.47
/
21.76
J
31.85
*¦*
31.32
s
30.87
s
30.60

34.42
S
32.43

26.54
*¦
36.93

35.96

39.61
-
39.13
/
38.08
~
31.31

41.70
35.77
~
s
43.84
«*
45.27

41.31
**
46.60
**





/
Reev.


0.7047
0.7069
+1.3
5.15E+07
3.28
0.94 v
92.7 %
25%
150%
0.8520
0.8523
+ 0.2
5.35E+07
3 .21
0.92
98.4 %
25%
150%
0.8687
0.8715
+2.0
3.97E+07
1.61
0.64
105 %
25%
150%
1.2550
1.2550
0
5.69E+07
1.59
0.99
97.2 %
25%
150%
1.0745
1.0742
-0.3
3.30E+07
1.07
0.58
97.3 %
25%
150%
1.0878
1.0878
0
4.96E+07
1.06
1.41
99.7 %
25%
150%
0.8144
0.8154
+1.0
3.59E+07
0.79
1.12
90.7 %
25%
150%
1.3808
1.3808
0
4.46E+07
0.80
1.18
107 %
25%
150%
1.3585
1.3584
-0.2
4.33E+07
0.80
1.13
108 %
25%
150%
0.8143
0.8141
-0.3
3.58E+07
1.58
1.27
86.2 %
25%
150%
1.1919
1.1915
-0.8
3.74E+07
1. 60
1.13
101 %
25%
150%
1.1717
1.1714
-0.6
3.65E+07
1.60
1.17
95.4 %
25%
150%
1.1551
1.1548
-0.6
3.72E+07
1.60
1.17
96.7 %
25%
150%
1.1449
1.1446
-0.6
3.49E+07
1.63
1.10
96.3 %
25%
150%
1.2881
1.2876
-1.0
3.91E+07
1.60
1.29
92 %
25%
150%
0.9690
0.9690
0
2.96E+07
1.27
1.12
95.2 %
25%
150%
0.7930
0.7930
0
3.69E+07
1.29
1.48
90 %
25%
150%
1.1035
1.1034
-0.2
6.27E+07
1.27
1 .23
91.8 %
25%
150%
1.0747
1.0747
0
3.11E+07
1.27
1.23
91 %
25%
150%
1.1838
1.1836
-0.5
2.96E+07
1.25
1.21
87.9 %
25%
150%
0.9006
0.9006
0
2.33E+07
1.06
0.90
116 %
25%
150%
0.8765
0.8764
-0.2
2.72E+07
1.03
1 .10
112 %
25%
150%
0.7207
0.7207
0
3.74E+07
1.04
1.43
94.3 %
25%
150%
0.9600
0.9599
-0.3
3.43E+07
1.05
1.53
101 %
25%
150%
0.8234
0.8234
0
3.18E+07
0.88
1.25
91.5 %
25%
150%
1.0090
1.0090
0
2.40E+07
0.92
1.08
100 %
25%
150%
1.0420
1.0421
+ 0.3
1.59E+07
0.78
0.73
97.5 %
25%
150%
0.9509
0.9509
0
2.21E+07
0.81
0.99
101 %
25%
150%
1.0726
1.0727
+ 0.3
2.19E+07
1.19
1.04
95.3 %
25%
150%
Analytical Perspectives
Page 1 of 5
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_PCB_002
Name
SS PCB-28
SS PCB-111
SS PCB-178
Actual
RT
19.40*"
28.97'
33.85 '
QC
Fred
RUT
0.9259
1.0838
1.0113
CS PCB-28
CS PCB-111
CS PCB-178
19.40 V
28.97 '
33.85 /
0.9259
1.0838
1.0113
JS	PCB-9
JS	PCB-52
JS	PCB-1D1
JS	PCB-13 8
JS	PCS-194
13.41^
20.96 '
26.73 "*
33.47 ^
43.44 "
Checkcoae
-^v
PCB-1 2-MoCB
9.49
1.0011
PCB-2 3-MoCB
11.28
0 .9869
PCB-3 4-MOCB
11.44
1.0010
PCB-4 22'-DiCB
11.70
1.0012
PCB-10 26-DiCB
11.84
1.0146
PCB-9 25-DiCB
13.42
1.0011
PCB-7 24-DiCB
13 .56
1.0119
FCB-6 23'-DiCB
13 .77
1.0275
PCB-5 23-DiCB
14.04
1.0477
PCB-8 24'-DiCB
14 .15
1.0560
PCB-14 35-DiCB
15.57
0.9258
PCB-11 33'-DiCB
16.30
0.9689
PCB-13/12 34'-/34-DiCB
16.58
0.9848
PCB-15 44'-DiCB
16.84
1.0009
PCB-19 22'6-TrCB
14.42
1.0011
PCB-30/18 246-/22'5-TrCB
16.04
1.1129
PCB-17 22'4-TrCB
16.40
1.1388
PCB-27 23'6-TrCB
16.59
1.1517
PCB-24 236-TrCB
16.70
1.1599
PCB-16 22'3-TrCB
16.80
1.1664
Analytical Perspectives
Actual
RHT
0.9258
1.0836
1.0114
0.9258
1.0836
1.0114
Diff
Sees
-0.1
-0 . 3
+0.2
-0.1
-0.3
+0.2
Response
5.34E+07
4.30E+07
2 -63E+07
5.34E+07
4.30E+07
2.63E+07
Ra
1.05
1.58
1.07
1.05
1.58
1.07
RRF
1.05
1.19
0.65
1.48
1.31
0.93
J
Cone
102 %
104 %
108 %
102 %
99.7 %
102 %
Checkcode .-
Noise
30%
3 0%
30%
30%
30%
30%
vu
DL
135%
135%
135%
135%
135%
135%

5.89E+07
3 .53E+07
3.28E+07
2.78E+07
2.22E+07
1.62
0.80
1.57
1.24
0.90
Totals
Mono-CBs
Di-CBs
Tri-CBs
Tetra-CB;
Penta-CB:
Hexa-CBs
Hepta-CB;
Octa-CBs
Nona-CBs
1.0012	+0.1
0.9871 +0.1
1.0010	0
1.0013	+0.1
1.0134 -0.9
1.0009 -0.2
1.0117 -0.2
1.0274 -0.1
1.0474 -0.3
1.0555 -0.4
0.9256 -0.2
0.9688 -0.1
0.9853 +0.5
1.0009 0
1.0011	0
1.1140	+1.1
1.1389	+0.1
1.1518	+0.1
1.1600	+0.1
1.1665	+0.1
NON-EMPC
148,000
86,300
48,500
38,100
17,300
23,400
63,800
52,000
6,250
3.37E+08	3.12
1.08E+09	3.09
8.65E+08	3.08
1.33E+07	SI*
7.05E+06	SI*
2.96E+07	SI*
5.77E+07	SI*
6.40E+07	SI*
6.74E+07	SI*
6.97E+07	SI*
5.97E+07	SI*
1.29E+08	SI*
5.86E+08	SI*
6.33E+07	SI*
3.08E+06	0.99
2.51E+07	1.03
1.26E+07	1.02
4.79E+06	1.02
4.39E+06	1.02
1.14E+07	1.04
EMFC
DL
148
000
5. 65
86
300
11.9
48
500
7.31
38
100
5.22
17
800
10.3
23
400
8. 62
63
800
7.03
52
000
5.21
6
250
7.17
1.19 v/
22,000
1.11
72,600
1.21
53,500
0.98
1,370
1.42
499
0.97
2,150
0.98
4,160
0.97
4,650
0.92
5,150
CO
O-I
o
5, D00
1.12
3,750
0.91
9,950
0.91
45,100
0.99
4,480
1.01
370
1.10
2, 770
0.96
1,590
1.31
444
1.23
433
0.81
1, 710
1.47E+04	5.38
1.47E+04	6.45
1.47E+04	5.92
1.53E+04 16
1.53E+04 11
1.27E+04	8.01
1.27E+04	7.96
1.27E+04	8.03
1.27E+04	8.45
1.27E+04	7.92
1.27E+04	6.93
1.27E+04	8.49
1.27E+04	8.51
1.27E+04	7.82
7.06E+03	6.64
7.06E+03	6.09
7.06E+03	6.96
7.06E+03	5.12
7.06E+03	5.43
7.06E+03	8.29
Page 2 of 5
Printed: 08 06 2008 1:20 PM
-------
t>9464_60#2_PCB_002
Nam©
PCB-32 24'6-TrCB
PCB-34 2'35-TrCB
PCB-23 235-TrCB
PCB-26/29 23'5-/245-TrCB
PCB-25 23'4-TrCB
PCB-31 2415-TrCB
PCB-28/20 244'-/233'-TrCB
PCB-21/33 234-/2'34-TrCB
PCB-22 234'-TrCB
PCB-36 33'5-TrCB
PCB-39 34'5-TrCB
PCB-38 345-TrCB
PCB-35 33'4-TrCB
PCB-37 344'-TrCB
PCB-54 22'66'-TeCB
PCB-50/53 22'46-/22156 "TeCB
PCB-45 22'36-TeCB
PCB-51 22"46'-TeCB
PCB-46 22"36"-TeCB
PCS-52 22'55'-TeCB
PCB-73 2315'6TeCB
PCB-43 22'35-TeCB
PCB-69/49 23'46-/22'45'TeCB
PCB-48 22145-TeCB
PCB-44/47/65 22'35'-/221 44'-
PCB-59/62/75 233'6-/2346-/24
PCB-42 22'34'-TeCB
PCB-41 22'34-TeCB
PCB-71/40 23'4'6/22'33'-TeCB
PCB•64 234'6-TeCB
PCB-72 23'55'-TeCB
PCB-68 23'45'-TeCB
PCB-57 233'5-TeCB
PCB-58 233'5'-TeCB
PCB-67 23'45-TeCB
PCB-63 234'5-TeCB
PCB-61/70/74/76 2345-/23'4'5
PCB-66 23'44'-TeCB
PCB-55 233'4-TeCB
PCB-56 233'4'-TeCB
PCB-60 2344'-TeCB
PCB-80 33'55'-TeCB
PCB-79 33'45'-TeCB
PCB-78 33'45-TeCB
PCB-104 22'466'-PeCB
PCB-96 22'366'-PeCB
PCB-103 22145'6-PeCB
Actual	Fred	Actual
RT	QC	RHT	RRT
17.24
1
1973
1.1975
18.31
0
8032
0.8033
18.45
0
8091
0.8091
18.71
0
8210
0.8208
18.90
0
8292
0.8291
19.17
0
8409
0.8409
19.43
0
8525
0.8523
19.61
0
8598
0.8603
19.96
0
8756
0.8755
21.28
0
9334
0.9335
21.59
0
9468
0.9469
22.08
0
9685
0.9686
22.47
0
9856
0.9856
22.82
1
0008
1.0008
17.11
1
0011
1.0013
18.94
0
9043
0.9036
19.51
0
9307
0.9306
19.57
0
9339
0.9339
19.77
0
9436
0.9434
20.98
1
0010
1.0010
21.10
1
0068
1.0066
21.18
1
0108
1.0107
21.39
1
0196
1.0206
21.63
1
0323
1.0323
21.85
1
0422
1.0427
22.10
1
0547
1.0545
22.27
1
0624
1.0624
22.58
1
0775
1.0773
22.68
1
0822
1.0821
22.87
1
0913
1.0912
23.57
0
8279
0.8280
23.82
0
8365
0.8365
24.17
0
8489
0.8490
24.37
0
8559
0.8560
24.52
0
8610
0.8610
24.74
0
8687
0.8688
25.02
0
8785
0.8789
25.29
0
8882
0.8884
25.43
0
8931
0.8932
25.85
0
9080
0.9080
26.03
0
9144
0.9144
26,37
0
9261
0.9261
27.65
0
9711
0.9711
28.12
0
9876
0.9875
21.78
1
0009
1.0008
22.10
1
0153
1.0153
23.72
0
8878
0.8873
Analytical Perspectives
Page 3 of 5
Dif£
Checkcode:

Sees
Response
Ra
RRF
Cose

Noise
DL
+0.2
1.07E+07
1.02
1.38
941
7
06E+03
4.83
+0.1
5.80E+06
1.03
1.03
453
9
04E+03
6.88
0
7.85E+06
1.03
1.00
633
9
04E+03
7.11
-0.2
2.84E+07
1.03
1.04
2,210
9
04E+03
6.85
-0.1
1.99E+07
1.04
1.12
1,430
9
04E+03
6.36
0
3.50E+07
1.02
1.06
2, 660
9
04E+03
6.69
-0.2
6.44E+07
1.03
1.05
4, 960
9
04E+03
6,79
+0.6
6.01E+07
1,03
1.03
4,720
9
Q4E+03
6.93
-0.1
2.64E+07
1.02
1.01
2,100
9
04E+03
7.04
+0.1
1.77E+07
1.05
1.05
1,360
9
04E+03
6.78
+0.1
1.45E+07
1.04
1.06
1,110
9
04E+03
6.7
+0.1
3.28E+07
1,06
0.95
2,780
9
04E+03
7.46
0
9.83E+07
1.02
0.95
8,310
9
04E+03
7.46
0
8.34E+07
1.03
0.89
7, 540
9
04E+03
7.97
+0.2
1.75E+05
0.77
1.09
17.9
3
64E+03
3.26
-0.8
2.54E+06
0.79
0.74
319
2
97E+03
3.81
-0.1
2.531+06
0,77
0.57
410
2
97E+Q3
4.9
0
2.05E+07
0,77
0.82
2,310
2
97E+03
3.42
-0.2
9.99E+05
0.82
0.59
156
2
97E+03
4.72
0
1.42E+07
0.77
0.72
1, 830
2
97E+03
3.9
-0.3
4.49E+05
0.81
0.93
44 .6
2
97E+03
3.01
-0.1
1.33E+06
0,77
0.59
210
2
97E+03
4.77
+1.3
1.00E+07
0.77
0.83
1,110
2
97E+03
3.36
0
3.64E+06
0.81
0.71
477
2
97E+03
3.97
+0.7
5.80E+07
0.77
0.75
7,120
2
97E+03
3.72
-0.3
5.47E+06
0.78
0.94
536
2
97E+03
2.97
o-
4.39E+06
0.77
0.67
610
2
97E+03
4.21
-0.3
2.20E+06
0.79
0.56
364
2
97E+03
5.01
-0.1
7.65E+06
0,77
0.75
938
2
97E+03
3.72
-0.1
6.95E+06
0.79
0.98
657
2
97E+03
2.86
+0.1
2.41E+06
0.80
1.15
193
8
76E+03
7.17
0
4.01E+07
0.77
1.18
3,160
8
76E+03
7.03
+0.1
4.66E+06
0.79
1.09
394
8
76E+03
7.56
+0.1
3.18E+06
0.76
1.09
269
8
76E+03
7.58
0
7.90E+06
0.76
1.18
619
8
76E+03
7.01
+0.1
4.22E+06
0,76
1.17
332
8
76E+03
7.04
+0.6
4.18E+07
0,77
1.12
3,440
8
76E+03
7.36
+0.3
2.28E+07
0.76
1.13
1, 870
8
76E+03
7.33
+0.2
6.87E+06
0.77
1.04
612
8
76E+03
7.97
0
2.28E+07
0,77
1.07
1, 960
8
76E+03
7.7
0
7.89E+06
0.75
1.07
679
8
76E+03
7.7
0
1.71E+06
0.76
1.20
131
8
76E+03
6.86
0
1.60E+07
0,77
1.18
1,250
8
76E+03
6.98
-0.2
1.05E+07
0.82
1.02
956
8
76E+03
8.11
-0.1
1.45E+05
0.59
1.02
15.9
2
78E+03
2.85
0
4.73E+05
0,58
0.88
60. 2
2
78E+03
3.31
-0.7
2.99E+05
0.66
0.82
41.9
1
12E+04
16.2
Printed; 08 06 2008 1:20 PM
-------
P9464_6O42_PCB_0Q2
Actual

Fred
Actual
Name
RT
QC
RRT
RRT
PCB-94 22'356'-PeCB
23.91

0.8948
0.8944
PCB-95 22'35'6-PeCB
24.29

0.9087
0.9085
PCB-100/93 22'4416-/2213S6-P
24.48

0.9158
0.9157
PCB-102 22'456'-PeCB
24.59

0.9201
0.9198
PCB-98 22'3'46-PeCB
NotFnd

0.9225
-
PCB-88 22'346-PeCB
24.93

0.9329
0.9326
PCB-91 22'34'6-PeCB
25.01

0.9358
0.9356
PCB-84 22'33'6-PeCB
25.20

0.9429
0.9427
PCB-89 22'346'-PeCB
NotFnd

0.9579
-
PCB-121 23'45'6-PeCB
NotFnd

0.9708
-
PCB-92 22'355'-PeCB
26 .26

0.9825
0.9822
PCB-113/90/101 233'5'6-/22'3
26.75

1.0000
1.0008
PCB-83 22'33'5-PeCB
27 .13

1.0157
1.0147
PCB-99 22'44'5-PeCB
27.23

1.0190
1.0187
PCB-112 233'56-PeCB
27.33

1.0228
1.0225
PCB-108/119/86/97/125/87 233
27.68

1.0353
1.0355
PCB-117 234'56-PeCB
28.19

1.0545
1.0544
PCB-I16/85 23456-/22-344'-Pe
28.26

1.0575
1.0571
PCB-110 233'4'6-PeCB
28.40

1.0624
1.0624
PCB-115 2344'6-PeCB
MotFnd

1.0651
-
PC'B-82 22 ' 33 ' 4-PeCB
28.67

1.0725
1.0722
PCB-111 233'55'-PeCB
28.99

1.0846
1.0844
PCB-120 23'455'-PeCB
29.37

1.0990
1.0987
PCB-107/124 233'4'5-/2'3455'
30.32

0.9908
0.9908
PCB-109 233'4 6-PeCB
30.52

0.9973
0.9976
PCB-106 233'45-PeCB
30.72

1.0039
1.0040
PCB-122 2'33'45-PeCB
31.18

1.0100
1.0100
PCB-127 33'455'-PeCB
33.10

1.0390
1.0390
PCB-15S 22'44'66 *-HxCB
26.56

1.0008
1.0008
PCB-152 22'3566'-HxCB
26.73

1,0070
1.0070
PCB-150 22'34'66'-HxCB
26.87

1.0122
1.0124
PCB-136 22'33'66'-HxCB
27.17

1.0236
1.0236
PCB-145 22'3466'HxCB
27.41

1.0331
1.0330
PCB-148 22'34'56'-HxCB
28.68

1.0805
1.0806
PCB-151/13S 22'355'6-/22 * 33'
29.18

1.0997
1.0994
PCB-154 22'44'5'6-HxCB
29.38

1.1070
1.1072
PCB-144 22'345'6-HxCB
29.64

1.1169
1.1169
PCB-147/149 22'34'56-/22'34'
29.94

1.1281
1.1280
PCB-134 22'33'56-HxCB
30.11

1.1343
1.1347
PCB-143 22*3456'-HxCB
NotFnd

1.1374
-
PCB-139/140 22'344'6-/22'344'
30.43

1.1469
1.1468
PCB-131 22'33'46-HxCB
30.61
o
1.1532
1.1533
PCB-142 22'3456-HxCB
NotFnd

1.1582
-
PCB-132 22'33'46'-HxCB
30.99

1.1676
1.1676
PCB-133 22'33'55'-HxCB
31.40

1.1832
1.1832
PCB-165 233'55'6-HxCB
NotFnd

0.9482
-
PGB-146 22'34'55'-HxCB
31.94

0.9543
0.9544
Analytical Perspectives
Page 4 of 5
Di££
Checkcode:
X
Sacs
Response
Ra
RRF
Cone
Noise
DL
-0.6
2.12E+05
I 0.75
0
71
34.2
1.12E+04
18.6
-0.3
1.34E+07
0.64
0
77
1,980
1.12E+04
17.1
-0.1
5.98E+05
0.59
0
78
88
1.12E+04
17
-0.4
6.32E+05
I 0.82
0
88
82.4
1.12E+04
15.1

0.00E+0Q

0
69

1.12E+04
19.1
-0.4
2.74E+05
0.56
0
66
47.1
1.12E+04
19.9
-0.3
1.96E+06
0.63
0
84
268
1.12E+04
15.8
-0.3
2.71E+06
0.62
0
66
471
1.12E+Q4
20.1

D.OOE+OO

0
70

1.12E+04
19

O.QOE+OO

1
02

1.12E+04
13
-0.5
2.65E+06
0.62
0
74
413
1.12E+04
18
+1.3
1.93E+07
0.63
0
84
2,620
1.12E+04
15.7
-1.6
1.64E+06
I 0.49
0
59
320
1.12E+04
22.6
-0.5
4.71E+06
0.59
0
85
636
1.12E+04
15.6
-0.5
5.96E+05
0.69
0
97
70. 3
1.12E+04
13.7
+0.3
1.17E+07
0.60
0
85
1,580
1.12E+04
15.7
-0.2
7.66E+05
0.57
0
94
93.2
1.12E+04
14.1
-0.7
2.25E+06
0.62
0
83
308
1.12E+04
15.9
0
1.51E+07
0.61
0
93
1, 860
1.12E+04
14 .2

O.00E+00

1
02

1.12E+04
12.9
-0.5
2-05E+06
0.63
0
62
382
1.12E+04
21.5
-0.3
8.63E+05
0.63
1
00
99.1
1.12E+04
13.3
-0.5
1.41E+06
0.60
0
99
164
1.12E+04
13.4
0
2.63E+06
0.63
0
96
314
1.12E+04
13.8
+0.5
5.28E+06
0.62
1
01
600
1.12E+04
13.1
+0.2
1.79E+06
0.62
0
94
218
1.12E+04
14.1
0
2.64E+06
0.63
0
86
337
1.12E+04
15
0
1.89E+06
0.60
0
.88
229
1.12E+04
14
0
1.10E+05

1
.03
11.6
2.30E+03
2.27
0
1.75E+0S
1.28
0
.98
19.3
2.30E+03
2.38
+0.3
4.01E+05
1.13
0
.96
45.4
2.30E+03
2.45
0
5.49E+06
1.27
0
.92
649
2.30E+03
2.55
-0.2
1.65E+05
1.41
0
.90
19.8
2.30E+03
2.6
+0.2
2.34E+05
1.37
0
.89
35.6
2.30E+03
3.69
-0.5
1.24E+07
1.25
0
.89
1,890
2.30E+03
3.69
+0.4
5.31E+05
1.26
1
.04
68.7
2.30E+03
3.14
0
1.92E+06
1.24
0
93
279
2.30E+03
3.52
-0.2
2.68E+07
1.26
0
93
3, 890
2.30E+03
3.53
+0.7
1.25E+06
1.31
0
75
224
2.30E+03
4.35

O.OOE+OO

0
87

2.30E+03
3.76
-0.2
8.85E+05
1.18
0
92
130
2.30E+03
3.57
+0.2
6.17E+05
1.29
0
80
104
2.30E+03
4.1

O.OOE+OO

0
80

2.30E+03
4.11
0
6.99E+06
1.30
0
83
1,130
2.30E+03
3.94
0
5.15E+05
1.23
0
86
80.8
2.30E+03
3.81

0-00E+00

1
05

2.30E+03
3.11
+0.2
5.16E+06
1.23
0
93
746
2.30E+03
3.51
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_FCB_0Q2
Actual

Pred
Actual
Name

RT
<2C
RSI

RRT
PCB-161
233'45'6-KxCB
NotFnd

0.9577

-
PCB-153/168 22 ' 44'55'-/23'44'
32.45

0.9702
0
9696
PCB-141
22'3455'-HxCB
32.61

0.9745
0
9746
PCB-130
22'33"45'-HxCB
32.96

0.9846
0
9848
PCB-137
22'344'5-HxCB
33.13

0.9901
0
9900
PCB-164
233'4"5'6-HxCB
33 .23

0.9930
0
9930
PCB-1G3/138/129 233'4 ' 56-/22'
33.49

1.0012
1
0008
PCB-160
233'456-HxCB
NotFnd

1.0049

-
PCB-158
233'44'6-HxCB
33.82

1.0104
1
0106
PCB-128/166 22'33'44 ' -/2344 1 5
34.53

0.9601
0
9602
PC8-159
233'455'-HxCB
35.33

0.9829
0
9824
PCB-162
233'4'55'-HxCB
35.59

0.9896
0
9896
PCB-188
22'34'566'-HpCB
31.33

1.0007
1
0007
PCB-179
22'33'566'-HpCB
31.61

1.0097
1
0097
FOB-184
22'344'66'-HpCB
32.05

1.0236
1
0236
PCB-176
22'33'466'-HpCB
32.34

1.0331
1
0330
PCB-186
22'34566'-HpCB
32.73

1.0453
1
0453
PCB-178
22'33'55'6-HpCB
33 .87

1.0816
1
0816
PCB-175
22'33'45'6-HpCB
34.39

1.0985
1
0984
PCB-187
22'34'55'6-HpCB
34.62

1.1057
1
1057
PCB-182
22'344'56"-HpCB
NotFnd

1.1111

_
PCB-183
22'344'5'6-HpCB
35.13

1.1219
1
1219
PCB-185
22'3455'6-HpCB
35.21

1.1246
1
1246
PCB-174
22*33'456'-HpCB
35.33

1.1283
1
1283
PCB-177
22'33'4'56-HpCB
35.69

1.1400
1
1399
PCB-181
22'344"56-HpCB
NotFnd

1.1505

-
PCB-171/173 22'33'44'6-/22'3
36.21

1.1563
1
1566
PCB-172
22'33'455'-HpCB
37.55

0.9005
0
9005
PCB-192
233'455'6-HpCB
NotFnd

0.9061

-
PCB-180/193 22'344"55"-/233 "
38.09

0.9128
0
9135
PCB-191
233'44'5'6-KpCB
38.39

0.9205
0
9204
PCB-170
22'33'44'5-HpCB
39.14

0.9386
0
9386
PCB-190
233'44'56-HpCB
39.58

0.9492
0
9491
PCB-202
22'33'55'66'-OcCB
35.80

1.0006
1
0006
PCB-201
22'33 *45'661-OcCB
36.56

1.0220
1
0220
PCB-204
22'344'566'-OcCB
NotFnd

1.0376

-
PCB-197
22'33'44'66'-OcCB
37.31

1.0428
1
0429
PCB-200
22'33'4566'-OcCB
37.40

1.0454
1
0455
PCB-198/199 22'33'455"6-/22"
39.73

1.1099
1
1105
PGB-196
22'33'44'56'-OcCB
40.27

1.1256
1
1256
PCB-203
22'344'55'6-OcCB
40.43

1.1302
1
1302
PCB-19S
22'33 ' 44'56-OcCB
41.53

0.9474
0
9474
PCB-194
22'33'44'55*-OcCB
43.46

0.9915
0
9915
PCB-20S
233'44'55'6-OcCB
43.85

1.0004
1
0004
PCB-208
22'33'455'66"-NoCB
41.33

1.0005
1
0005
PCB-207
22'33'44'566'-NoCB
42 .10

1.0191
1
0191
PCB-206
22'33'44'55'6-NoCB
45.29

1.0004
1
0004
Analytical Perspectives
Page 5 of 5
Diff





Checkcode .*

Sees
Response
Ra
RRF
Cone
Hoi so
DL

0.00E+00

1
16

2.30E+03
2.83
-1.2
3.83E+07
1.26
1
24
4,160
2.30E+03
2.64
+0.2
8.59E+06
1.20
0
90
1,290
2.30E+03
3.66
+0.4
1.63E+06
1.26
0
78
280
2.30E+03
4.18
-0.2
7.71E+05
1.27
0
89
116
2.30E+03
3. 67
0
3.60E+06
1.22
1
14
425
2.30E+03
2. 87
-0.8
3.42E+07
1.25
0
95
4,860
2.30E+03
3.45

0.00E+0O

1
09

2.30E+03
3
+ 0.4
5.68E+06
1.26
1
21
636
2.30E+03
2.72
+ 0.2
2.12E+06
1.08
0
85
321
6.47E+03
10.6
-1.1
2.55E+06
1.24
0
95
345
6.47E+03
9.45
0
1.09E+06
1.13
0
95
148
6.47E+03
9.47
0
2. 49E+05
1.06
1
00
26.6
2.44E+03
2.64
0
1.35E+07
1.05
0
87
1,650
2.44E+03
3.03
0
3.46E+05
1.12
0
84
44.3
2.44E+03
3.17
-0.2
4.47E+06
1.04
0
90
533
2.44E+03
2.94
0
9.61E+04
1.11
0
86
11.9
2.44E+03
3.07
0
7.41E+06
1.07
0
64
1, 230
2.44E+03
4.12
-0.2
1.60E+06
1.07
0
88
266
5.06E+03
9.43
0
5.73E+07
1.03
0
90
9, 390
5.06E+03
9.27

0.Q0E+00

0
93

5.06E+03
8.92
0
2.04E+07
1.04
0
92
3,230
5.06E+03
8.98
0
5.37E-06
1.09
0
85
928
5.06E+03
9.77
0
4.78E+07
1.04
0
86
8,130
5.06E+03
9.61
-0.2
2.29E+07
1.04
0
85
3,970
5.06E+03
9.78

0.00E+00

0
88

5.06E+03
9.45
+0.7
9.29E+06
1.03
0
79
1,720
5.06E+03
10.5
0
7.83E+06
1.07
0
79
1,450
5.06E+03
10.5

0.00E+00

1
02

5.06E+03
8.15
+1.6
1.50E+08
1.04
0
97
22,900
5.06E+03
8.6
-0.2
2.65E+06
1.07
1
10
355
5.06E+03
7.57
0
4.13E+07
1.05
1
17
6, 040
5.06E+Q3
8.62
-0.2
1.27E+07
1.05
1
39
1,570
5.06E+03
7.29
0
1.02E+07
0-91
0
95
1,3 50
1.93E+03
2.68
0
8.38E+06
0.88
0
89
1,180
1.93E+03
2.85

0.00E+0O

0
04

1.93E+03
3.03
+0.2
2.79E+06
0.86
0
86
407
1.93E+03
2.93
+0.2
1.04E+07
0.89
0
89
1,490
1.93E+03
2.87
+1.4
7.56E+07
0.89
0
63
15,100
1.93E+03
4.04
0
3 .15E+07
0.90
0
63
6,280
1.93E+03
4.02
0
4.46E+07
0.89
0
71
7,960
1.93E+03
3.6
0
2.18E+07
0.91
0
76
4,740
4.06E+03
10.7
0
6.36E+07
0,91
0
82
12,900
4.06E+03
10
0
3.39E+06
0. 94
1
06
532
4.06E+03
7.74
0
5.54E+06
0.79
1
00
1,010
3.17E+03
6.24
0
4.31E+06
0.79
1
00
783
3.17E+03
6.23
0
1.97E+07
0.78
1
11
4,460
3.17E+03
8.11
Printed: 08 06 2008 1:20 PM
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1	^	Acq: 24-Jul-2008 04:47:22
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60	User: JLJ Datafile: 080724V06_EQ
QC<
Rel. Int.
Fn 1 100%
218.9856
QC (non-EQ)
9.03-13.00
Rel. Int.
Fn 2 100%
242.985$
QC (non-EQ)
13.02-17.79
Abs. nt
-9.51e7
4.75e7
O.OOeO
13.0 RT
Abs. nt
5.56e7
I | » I ! I J
17.5	RT
Rel. (nt
Fn 3 100%.
292.9824
QC (non-EQ) .
17.81-23.26
0%.
18.0
I
19.0
20.0
—I—
21.0
—I—
22.0
23.0
Abs. Int.
5.82e7
.2.91 e7
-O.OOeO
RT
Rel. Int.
Fn 4 100%.
330.9792
QC (non-EQ)
23,27-34.14
0%-
	1—.	1—
24.0
I I I I
—I	
26.0
-J	.	I	1	1	]	
28.0
—p-
30,0
•r	i	i	i	r	'	
—I—
32.0
itii
Abs. Int.
-5.30e7
12,65e7
-O.OOeO
34.0 RT
Rel. Int
Fn 5 100%.
366.9792
QC (non-EQ)
34.16-41.15
0%.
T	f	T	T	r	T	
35,0
1 I 1
36.0
1 I r
37.0
i i i i i i i t
38,0
39.0
1 1 I ¦
40.0
-T-^0.
Abs. Int
-1.11e7
•5.57e6
I.OOeO
41.0 RT
Rel. Int.
Fn 6 100%.
454.9728
QC (non-EQ)
41.17-46.41
0%.
I
43.0
I
44.0
I
45.0
46.0
Abs. Int
-1,79e7
	,	(L. O.OOeO
RT
Rel. Int.
Fn 7 100%-,
454.9728
QC (non-EQ) -
46.42-54.01
0%-
-i—i—i—|—r
47.0
—I	1	1	1	1	1	1	1	I	1—
48.0
49.0
so.o'
1 I '
51.0
52.0
1 I 1
53.0
Abs. Int.
-2 18e7
1.09«7
	1	¦ ¦ ' ¦
¦ O.OOeO
54.0 RT
Results: P:\P9400_P9499\P9464_6Q42 PCB\m$ourcesiP9464_6042_PCB_002.utp_ms, saved 24^ful-2008 11:27 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-03B see: 415-382
Peak annotation: Areas. Centmids
PKD n/a Printed: 0S-Aug-2008 08:27:58 Page 1 of 22
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1	EQUALIZED Acq: 24-JuI-2008 04:47:22
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a VialP&d0R TO PROCESSES©: JLJ Datafile: 080724V06_EQ
Rel. Int.
Fn 1 100%-
218,9856
QC Check
9.03-13.00
0%-
-i—i—|—i—i i i—p
9.5
-i—i—i—|—r
10.0
1—r—|—r
10.S
-v-
~ r
11.0
• I ¦
11.5
12.0
¦ t •
12.5
Abs. Int.
-1.02e8
IS. 12b?
¦O.OOeO
13.0 RT
Rel. Int.
Fn 2 100%.
242.9856
QC Check
13.02-17.79
0%.
I ' ' ' ' I i ¦ ¦ ' I ' ' 1 ' I ' ' ' ¦ I
13.5	14.0
14.5
' I '
15.0
• I '
15.5
¦ I '
16.0
16.5
17,0
• I '
17.5
Abs. Int.
-S.12e7
»2.56©7
-O.OOeO
RT
Fn 3
Rel. Int.
100%.
282.9824
QC Check
17.81-23.26
0%.
—I—
18,0
19.0
20.0
21.0
22.0
23.0
Abs. Int.
-5.3287
• 2.66e7
¦ O.OOeO
RT
Fn 4
Rel. Int.
100%.
330.9792
QC Check
23.27-34.14
0%.
—I—
24.0
26.0
28.0
—f	1	1	T	1	T— 11111111
	1	
30.0
—(	,	
32.0
Abs. Int.
-4.88e7
-2.44e7
¦ O.OOeO
34.0 RT
Re), Int.
Fn 5 100%.
454.9728
QC Check
34.16-41.15
0%-X,—,—,—|—,—,—r-
35.0
36.0
^yyy»|f»ii|i
37.0
38.0
39.0
y f f
40.0
Abs. Int.
2.00e7
.39cO
-O.OOeO
41.0 RT
Rel. Int.
Fn 6 100%.
404.9760
QC Check
41.17-46.41
0%.
42.0
I
43.0
I
44.0
I
45.0
	1—
46.0
Abs, Int.
-1.90e7
9.50e6
-O.OOeO
RT
Rel. Int.
Fn 7 100%.
454.9728
QC Check
46.42-54.01
0%.
¦T_rT
47.0
48.0
49.0
SO.O
1 I r
51,0
-i—i—i—i—i—i—I—i—i—'—r
52.0
r
53.0
Abs. Int.
-1.89s7
9 44e6
t-0 OOeO
54.0 RT
Results: P:\P9400_P9499P9464j6042 PCB\KSOUK»S\P9464_6O42_PCB_00Zutp_ws. saved 24^ul-2008 11:27 (BE)
AP UltraTmce-Pm V3.993 User/System: EE/EEC2-C38
Peak annotation: Areas. Centroids
PKD: n/a Printed: 05-Aug-2008 08:27:59 Page 2 of 22
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 1
188.0393
MoCB
4o778e3
9.03-13.00
0%-
Rel. Int.
100%-
Fn 1
190.0363
MoCB
4o6.96e3
9.03-13.00
0%-
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
PCB-2
8,15e8
11.28
PCB-1
2 S5e8
9.49
9.5
I I | I T I I | I
10.0
I I I I | I I I I J I 1 I I | I I I I
10.5	11.0
10,0
10.5
PCB-3
6.53e8
11.44
PCB-2
11.28
PCB-3
2.12e8
11.44
Acq: 24-Ju!-2008 04:47:22
User: JLJ Datafile: 080724VQ6 EQ
Abs. Int.
-3.31e8
11.5
i ¦ 1 ¦ ¦ i ¦
12.0
I 1 1 ' 1 l '
12 5
11.0
11.5
12.0
T
-i—j—r-
12.5
•1.65e8
¦O.OOeO
13.0RT
Abs. Int.
1.07e8
¦5.36e7
•O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
200.0795
MoCB Std.
4a1.78e4
9.03-13.00
0%-
Rel. Int.
100%-
Fn 1
202.0766
MoCB Std.
4a 8.56e4
9.03-13.00
0%-
10.0
10.5
11.0
11.5
12,0
12.5
ES-3
l,2?e7
yAz
10,34
9.5
10.0
10.5
I ! ( I I I ! | I ! I I | I ! ! I [ I I ! I | ! 1 I 1 | I < I I |	T~
11.0	11.5	12.0	12.5
Abs. Int.
-1,75e7
8.77e6
-O.OOeO
13.0RT
Abs. Int.
5.63e6
•2.82e6
¦O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
218.9856
QC Check
9.03-13.00
Abs. Int.
-1 02e8
5.12e7
O.OOeO
Results: P:\P9400_P94SSSP9464_6042 PCB\msouncesSP94B4_SO42_PCB_0O2.utp_ms, saved 24-Jut-2008 11:27 (EE)
AP UttraTmce-Pm V3.S93 User/System: E&EEC2-038 cc: 3726. 8291
13.0RT
Peak annotation: Areas, CentrotdS
Revised: 24-Jut-20M 11:16:57 (EE) Printed: OS-Aug-2008 08:28:00 Page 3 d22
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 1
222,0003
DiCB-1
4o 9.33e3
9.03-13,00
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbxl 00_a Vial: 60
o%.
Rel. Int.
100%-
Fn 1
223.9974
DiCB-1
4o 2.90e4
9.03-13.00
0%-
PCB-4
8,12e6
11.70
PC 8-10
4.30e6
11,84
9.5
i r
9.5
10.0
"T-*-
-i—i—i—|—i—i—i—i—!—i—i—i—i—|—i—r-*-i—i—'—i—r-^f—i—I—i—i—i—i—i—i—i—r
Acq: 24-Ju1-2008 04:47:22
User: JLJ Dataflle: 080724V06_EQ
Abs, Int.
2,44e6
, „ 1.7386
1.06e6 12,71
12,54
10.0
10.5
11.0
11.5
12,0
A
'I	r""'i	f	i—r—r-
•1.22e6
PCB-4
5,36e6
11.7°PCB-10
2,78e6
11.84
T I	1 T 1 1 I |
10.5
11.0
11.5
12.0
12.5
2,0leS
12.71
12.5
¦O.OOeO
13.0RT
Abs. Int.
1.70e6
8.49e5
O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
234.0406
DiCBStd.
4 a 1,34e4
9.03-13.00
0%-
1—(-T
9.5
10.0
-r—p-i—i t i—|—i—i i i | i i i i { t i i i | r f r r ^ i i i t | r i i i |
10.5	11.0	11.5	12.0
Abs. Int.
-6.03e6
-3.01e6
¦O.OOeO
12.5
13.0RT
Rel. Int.
100%-
Fn 1
236.0376
DiCBStd.
4o 6.43e3
9,03-13.00
0%-Lr
I—r
9,5
' I '
10,0
10.5
11.0
	r	'I	I'" 1	1 r——t—r
11.5
f | > T I f
12.0
Abs. Int.
-3.98e6
•1.99e6
O.OOeO
i r | > t f > } i > i
12.5	13.0RT
Rel. Int.
100%
Fn 1
218.9856
QC Check
9.03-13.00
0%-Lt-
Results: P:\P9400_P9499V9464_6042 PCBVesaurce$\P94e
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
222.0003
DiCB-2
4o 7,75e3
13,07-17.79
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl 1-10_mm6 GC: pcbx100_a Vial:
60
0%-
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4o2,55e4
13,07-17.79
0%.
PCB-13/12
3.57ei
16.58
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: Q80724V06 EQ
Abs. Int.
-8.83e7
PCB-9
I.80e7
13.42
PCB-6
3.90e7
13,77
PCB-5
4.10e7
14.04

13,5
14,0
14,5
¦ i '
15,0
PGB-14
3,64e7
15.57
PC8-11
7,88e7
16.30
15.5
PCB-15
3,86e7
16.84
A , , ¦
16.0
16,5
PCB-13/12
2.3ie8
16.58
17.0
POR 8
fCB-9 2,e0e7
1.25e7	13 77
1^,A. A.
13.5
PCB-5
2.70e7
14.04
,/NA
14,0
14.5
-i—i !""i—r—i—i—p-r—r-r-
15.0
PCB-14
2.41e7
15.S7
15,5
1 I '
16.0
PCB-11
5.12e7
16.30
PCB-15
2,5le7
16,84
hCw
17.5
16.5
17.0
-4.42e7
	i		|	
17.5
-j—O.OOeO
RT
Abs. Int.
-5.70e7
•2.85e7
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
234.0406
DiCB Std.
4o1.91e4
13.07-17.79
0%-
Rel. Int.
100%-
Fn 2
236.0376
DiCB Std,
4a 8,95e3
13.07-17,79
0%-
I I I I I" I I I l~l I I ) I I | I	I | I I -V I | I I I 1 |
13,5	14.0	14.5
JS-9 /
2.25e7/
1r
/ 11* i	1111
13.5
15,0
15,5
~i—f—t—i—i—i—|—i—i—i—i—| i i t i f i i l i—|—r—r—r r"j 11 t | i
16.0	16.5	17.0	17,5
ES-15"
2. Ure7
^C83
14.0
1 | I I—I 11 I j "T"
14.5	15.0
15.5
16.0
16,5
Abs, Int.
-1,27e7
-6.37e6
-O.OOeO
RT
Abs. Int.
-8.00e6
¦4.00e6
17.0
17.5
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.07-17,79'
0%-
13.5
14.0
I 1 1 1 ' 1 1
14.5
1 ' 1 I ¦
15.0
' I 1
15,5
16.0
16.5
17.0
Abs. Int.
-5.12e7
•2.56e7
"1—1—I—i—I—|—I—l—r—r—I 0 OOeO
17.5	RT
Results: P:\P9400_P9499SP9464_6042 PCB\resources\P9464_6042_PCB_002.utp^ms. saved 24-Jul-200a 11:27 (EE)
AP UltraTrace-Pro V3.S93 User/System: EE/EEC2-038 cc 6621. 9093
Peak annotation: Areas, Centroitis
PKD 24-JUI-2008 11:13:21 Printed: 0S-Aug-2008 08:28:02 Page %®22
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int
100%
Fn 2
255 9613
TrCB-2
4o 3.60e3
13.02-17.79
0%-
Rel. Int.
100%-
Fn 2
257.9584
TrCB-2
4o 3.46e3
13.02-17.79
0%-
1 | I I I
13.5
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
PCB-19
1.53e6
14.42
14.0
| I I I I [ I I ! I | I I 1 I |
14.5	15,0
PCB-30/18

1.2787

16.04
A

A
PCB-17
i
6.37e6

16.40
A'
Acq: 24-Jul-2008 04:47:22
User: JU Datafile: 080724V06_EQ
Abs. Int.
-3 77e6
PCB-16
soueo
2,42e6
16.59
PCB-32
5.4168
17.24
15.5
16.0
PCB-30/10
1,24e7
16.04
17.0
1 I ¦
17.5
PC8-19
1,5Se6
14.42
PC8-17	D_Q
e.27ee	PCI-18
An	O.Doeb
A PCB-27 16.80
/\ 2,37e6
I \ 16.59
PCB-32
5.33e6
17.24
I | « I I
13.5
I I f I | 1 I
14,0

J I I I f | I I I I j f t I I f
14.5	15,0
¦ i } » j i i		fmi
15.5	16.0
16,5
¦1.89e6
-O.OOeO
RT
Abs. Int.
-3.68e6
1,84e6
17,0
17.5
¦O.OOeO
RT
Rel. Int.
100%
Fn 2
268.0016
TrCB Std.
4o6.71e4
13.02-17.79 i
0%-
Rel. Int.
100%-
Fn 2
269.9986
TrCB Std.
4o 4,73e4
13.02-17.79
0%-
4.26e6
13.46
A
i i1 r i < < r | it i i "[¦' 111
13.5	14.0
"j 1 "1 I 		
14.5
ES-19 ^
1.59 e]T
14.$-
15,0
-p-pr-i r 1 | i' 1 "
15.5
160
""I" 1 1		 1 1 ""? I"" |" 1 » 1 "I 1 'I "
13.5	14.0

16.5
2.2886
17.08
/\
17.0
14.5
15.0
15.5
16.0
16.5
17.0
Abs, Int.
-5.54 e6
2.77e6
,"i	O.OOeO
17.5	RT
Abs. Int.
5.28e6
¦2.64e6
17.5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.02-17.79 J
Abs. Int.
r5.12e7
2.56e7
O.OOeO
Results: P^P9400_P9499\P9464_6042 PCBSmsourcesV3S4S4_S042_PCB_002.utp_ms. saved 24-M-2008 11:27 (EE)
AP UttmTmce-Pnf ¥3.993 User/System: EE/EEC2-CI38 cc: 5757. 7973
Peak annotation: Areas, Centrvids
Revised: 24-M-2008 11:19:16 (EE) Printed: OS-Aug-2008 08:28:03 Page 6 of^e
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
255.9613
TfC8-3
4o 3.67e3
17.81-23.26
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_d1-10_mm6 GC: pcbx100_a Vial: 60
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06_EQ
0%-
Rel. Int.
100%-
Fn 3
257,9584
TrCB-3
4o 5.36e3
17.81-23.26
Q%-
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
4o 3.76e4
17.81-23.26
0%-
18.0
PCB-34
2,95e6
18.31 ^
, OA,
PCB-26»ftB-25
VJWi.0le7
18-71 18.90
PCB-28/20
3-27>pt8-21/33
19-43 3.05e7
PCB-37
4.23e7
22.82
PC 8-31
1.7767
19.17
A, A
PCB-22
1,33e7
19,96
A
PCB-36
9.05e6
21,28
A
PCB-38
7.41e6
21.59
f\
i i
20.0
21.0

PCB-38
1.69e7
22.08
22.0
PCB-35
4.9767
18.0
PCB-34
2.85e6
18.31 „
pC%26ffl%B.25
VfW9-77®6
18.?1 18.90
A A
PCB-28/20
3.17e7
PCB-31 1943
1.73e7
19.17
19.0
PCB-22
1.30e7
19.98
JL
20.0
21.0
PCB-36
8.66e6
21.28
-A,
PCB-39
7.14e6
21.59
A

PCB-35

4.86e7

22.47
A
PCB-38

1.60e7
1
22.08
A

22.0

SS-28
Rel. Int.
2.74e7
100%-
19.40
Fn 3 i


268.0016 •


TrCB Std. J


4o 4.76e4


17.81-23.26 •


0%-

A
18.0
19.0
SS^
2.9tfe7
19.40
	'
20.0
2.60e6
20.01
vCX,
21.0
22.0
18.0
19.0
20.0
¦—|—,
21,0
PCB-37
4,1 Oe?
22.82
23.0
ES-37 /
2.4" "
22
Abs. Int.
r 1,28e7
6.39e6
-O.OOeO
RT
Abs. Int.
-1,26e7
•6.28e6
-O.OOeO
RT
Abs. Int.
-7.64e6
•3.82e6
i •r i 		i1 		 J O.OOeO
23.0 RT
Abs. Int.
222§ff	r7.26e6
•3.63e6
22,0
»* i—i i i "S | i—»—*- 0.OOeO
23.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17,81-23.26
20.0
Results: P:\P9400_P9499\P9464_6042 PCB\resourtes\P9464_6O42_PCB_002.utp_reS. saved 24-Jut-2008 11:27 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 9757, 6839
21.0
Abs. Int.
5.32e7
2 66e7
-O.OOeO
RT
Peak annotation: Areas, Centroids.
Revised: 24-Jul-200B 11:19:35 (EES Printed: 05-Aug-2008 08:28:04 Page ?oP2z
22.0
23.0
-------
AP Lab ID: P9464_6042_PCS_002
Instr: AutoSpec-Premier MM6
Rel Int.
100%
Fn 2
289.9224
TeCB-2
4o 1,60e3
13.02-17,79
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o 2,05e3
13,02-17.79
Rel. Int.
100%
Fn 2
301,9626
TeCB Std.
4o 6.84e3
13,02-17.79
Rel. Int.
100%-
Fn 2
303.9597
TeCB Std.
4o4.35e3
13.02-17.79
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxi 00_a Vial: 60
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06 EQ
Abs. Int.
-2.29e4
1.1584
O.OOeO
RT
Abs. Int.
-3 21e4
1.60©4
PCB-54
7,65e4
PCB-54
,—O.OOeO
RT
ES-54
1,58e7
Abs. Int
4.52e6
17,09
2,26e6
O.OOeO
Abs. Int
5,74e6
17.09
2,87e6
O.OOeO
Ret, Int,
100%.
Fn 2
242.9856
OC Check
13,02-17.79'
Abs. Int.
-2.56e7
O.OOeO
fill
Results: P:\PS400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_002 utp_res. saved 24-Jul-2008 11:27 (EE)
AP UttraTrace-Pro V3.S93 User/System EE/EEC2-038 cc: 4363. 9968
Peak annotation: Areas, Centroigs
Revised: 24-Jul-2008 11:19:45 (EE) Printed: 05-Aug-2008 08:28:06 Page 8jsf22
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AuloSpec-Premier MM6
Rel. Int.
100%-
Fn 3
289,9224
TeCB-3
4o 1 ,96e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4o1.01e3
17.81-23,26
0%-
18.0
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
PCB-44/47/65
2.52e7
21,85
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06 EQ
Abs. Int.
-5.91 e6
PCB-50/53
1.12e6
18.94
¦ rs
19.0
PCB-51
8,93e6
19.57
PCB-52
6,19e6 PCB-69/49	,	,
20.98 „„ 4.37bB PCB-48 /	fCB-59/62/75
VIK?/21.39 1 6386 /	\ 2.40e6
21.63 }	\ 22.10
A
5,8065
21.18
PCB-64
PCB-41 3,0066
9.71e5 22 87
22-^y\ /\
20.0
21.0
22.0
PCB-44/47/65
3.28e7
2185
23,0
18.0
PCB-50/53
1,42e6
18.94
i		r
19.0
PCB-51
1,16e7
19.57
20.0
PCB-52
8.02e6 PCB-69/49
20.98 n/^n 5,66e6 PCB-48
21.18^/\
A
r
21.0

2,01 ee
21,63
PCB-59/62/75
3 07e6
22.10
PCB-64
PCB-41 3.89e6
1,2386 22.87
/\
22.0
~j	!
23.0
•2,95e6
-O.OOeO
RT
Abs. Int.
~7.77e6
•3,6986
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
301.9626
TeCB Std.
4o 5.25e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
303.9597
TeCB Std.
4o 3.98e3
17.81-23.26
0%-
18.0
19.0
20.0
21.0
22.0
23.0
18.0
' 19 0 '
20.0
21 0
.—|—i—r-
22.0
Abs, Int.
-4.20e6
•2.10e6
-O.OOeO
RT
Abs, Int.
-5,17e6
2.58e6
I i—r-- O.OOeO
23.0	RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17,81-23.26
Results: P:\P9400_P9499\P9464_6042 PCB\m$Ources\P9464_6042_PCB_002.utp_res, saved 24-Jul-2008 11:27 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 8440, 1084
23,0
Abs, Irrt,
5.32e7
2,6607
-O.OOeO
RT
Peak annotation: Areas, CentmMs-
Revised: 24-M-2008 11:20:23 (EE) Printed: 0S-Aug-2008 08 28 07 Page 9^f22
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
289.9224
TeCB-4
4o 4.33e3
23.27-33.00
0%-
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4o4,43e3
23,27-33.00
0%-
Rel. Int.
100%-
Fn 4
301.9626
TeCB Std.
4o4 44e3
23.27-33.00
0%-
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
4a 5.10e3
23.27-33.00
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10 mm6 GC: pcbx100_a/Vial: 60
PC8-77 /
PCB-68
1,74e7
23.82
PCB-72
1,07eS
23.57
WW
PCB-61/70/74/76
1.82e7
25.02
PCB-sfalS7
2 0Se6 24 52
24.17 a
\ .
~r
24.0
T
PCB-56
9.89e6
25.85
C8-60
|9,#CB-80
.6 03 7 39e5 6.66e5l 00e6
\ A 26.37 26.78 27.10
/
2.21e7
28.96
PCB-79
6.95e6
27.65
25.0
26.0
T
" f I "
27.0
6.25e;
27.9:
28.0
PCB-81
3.89e6
28.49
e5A *
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06_EQ
Abs. Irit.
- 5.40e6
PCB-68
2.27e7
23.82
29.0
PCB-77
2 86e7
28.95
30.0
I | t I I I | I 1 I I | I I I I
31.0	32.0
PCB-72
1.34e6
23.57
PCB-61/70/74f76
2.37«7
25.02
. ,f>CB-67
l-57d dHpi
PCB-5/4 dgog
2 60e6 24 51
24.17 A
,	A
24.0
PCB-56
1.29e7
25.B5
CB-60
S0efl>cB-80
6-039.7185
26.37
> r/>i i
PCB-79
9,03e6
27,65
PC|-7|pcB-81
oPi% 5.06e6
28*12 28.49
A A
' i t I—i'| i—r
1 I '
24.0
0% i i | * i i i | i
24.0
25.0
26.0
27.0
"28.0
'1 i\
r
29.0
ES-81 ES-77
1.93e7 1.98e7
28.47 28.94
' I '
30.0
31.0	32.0
5.34e5
26,35
25.0
26,0
27.0
28,0
29.0
ES-81 E&T7
2.40c7 2me 1
2*47 "*28.94
30,0
¦"* I '
31.0
T~—I—]—i—
32.0
25.0
26.0
—j 1 t I I | t 1 1 1
27.0
-X-. J. k
28.0
f 1 | p 1 » f j 1 f ? t j r
29.0	30.0
31.0
32.0
-2.70e6
1 0.00e0
RT
Abs. Int.
7,08e6
¦3.54e6
¦r—i— O.OOeO
RT
Abs, Int.
4.85e6
•2.42e6
-O.OOeO
RT
Abs, Int.
-5.85eB
•2.92e6
•O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-33.00
Results: P\P9400_P9499\P9464_6042 PCB
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
323.8834
PeCB-3
4o 1.46e3
17.81-23.26
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx10Q_a Vial: 60
PCB-96
1.74e5
22.10
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06_EQ
Abs. Int.
-4.50e4
•2.25e4
0% " "V	f
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
4o 1,32e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
337.9207
PeCB Std.
4o2.15e3
17.81-23.26
0%-
Rel, Int.
100%-
Fn 3
339.9177
PeCB Std.
4o 1,72e3
17.81-23.26
0%-
18.0
hi I ii rjnr/1^.		|	JV,**	
19.0
20.0
21.0
rCB-104
5.41e4
21.78
22.0
23.0
18.0
i ¦ y ¦ *•&' "T¦"
—I—1
18.0
I | I
18.0
f I' f T
19.0
r
"^i" "i ¦
19.0
20.0
f '"i
21.0
PCB-104
9.0964
21.79
PCB-96
2.99e5

22.0
ES-104
2.19e7
21.76
n
I	|	1	t	T'"
19.0
20.0
21.0
—*—i—|—i—r-
22.0
ES-104
1.3867
,2176
ft
20.0
21.0
22.0
23.0
23.0
1,3264
23.07
-O.OOeO
RT
Abs. Int.
-8.43e4
4.22e4
-O.OOeO
RT
Abs. Int.
-5.86e6
¦2.93e6
-O.OOeO
RT
Abs. Int.
-3.74e6
•1.87e6
, , i O.OOeO
23.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P:\P9400_P9499\P9464_6042 PCB\reSOumeS\P9464_6042_PCB_002.utp_res, saved 24-Jui-2Q08 11:27 (EE)
AP UttmTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 0095. 4575
Abs. Int.
5.32e7
2.66e7
O.OOeO
RT
Peak annotation: Areas, Centmids
PKD: 24-M-2008 > 1:13:21 Printed: 05-Aug-2008 08:28:09 Page 11 
-------
AP Lab (D: P9464 J042_PCB_Q02
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_c!1-10_mm6 GC: pcbx100._a Vial:


60
Rel. Int.
100%-
Fn 4
323.8834
PeCB-4
4a 7.70e3
23.27-34.14
Rel. Int.
100%-
Fn 4
325.8804
PeCB-4
4o 3.52e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
337,9207
PeCB Std.
4o2.25e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
339.9177
PeCB Std.
4o 3.90e3
23.27-34.14
0%-
PCB-95
PCB-113/90/101
7.44e6
26.75
/
PCB-110
5 72e6
28.40
PCB-118
5.40e6
30.90
*-f** Acq: 24-Jul-2008 04:47:22
User: JLJ Datafil,e:_Q30724V06 EQ

PCB-105
3.69ee
31.87
8,25e5
PCB-108/119/86/97/
4.37e6
27.68
PCB-83 « PCB-11
Wi h
PCB-92
1.0166
26.26
PCB-82
PCB-122
PCB-127
PCB-114
PCB-120
PC 3-10Q/93CB-88
42265 9.78e4 „
7.9265
6ft11e5
6.82e5
7.09e5
S.30e5
2 62e5
2J7e5
33.10
29.37
32.45
28.94
33.50
fef.
07es

PCB-95
81466
24.29
PCB-113/90/101
1.18e7
26.75
PCI
r-|	1
24.0
5-1OO/80CB-88
76eS 1.76eS .
*11 »:»A
PCB-92
1.64e6
26.26
PCB-110
9.41e6
28.40
PCB-116
8.76e6
30.89

¦—r
26.0
A
PCB-108/119/86/97/
7.33e8
T PCB-11
w$ /H «
PCB-1 OS
5.76e6
31,87
3CB-82
11.26e6
, 28.66
-A,
PCB-120
B.79e5
29.37
1 6 ¦
4.29e5
29.94
pcb-1 2:
1jp3e6
0.62
28.0
300
PCB-114
1.1Qe6
31.34
r» i*
PCB-127
1.18e6, .. r
33.10
A 33.50
-£i-	.<"¦ ,	
JS-101
2.01e7
26.73
SS-111
2.64e7
28.97
ES-123
2.iee7
30.60
ES-114
2.25e7
31.32
32.0
ES-105
2,30e7
31.85
T
24.0
1 l—1
26.0
28.0
JS-10t^
1.280?
26.73
^ 1 ^
SS-111
i.67«r
29^97
\ ./ \
11
30.0
32.0
K1« ES-11>^ES-105
StJs /1.41«7 1.44#?"
1 ^ 31 32 31.85
80.60
24.0
26.0
28.0
1—r~
30.0

32.0
OOeO
Abs. Int.
-2 62e6
1.31e6
Ho
-O.OOeO
RT
Abs. Int.
-657e6
¦3.28e6
™i—g	 i—1	 i—r-—j—«-0.00e0
34.0 RT
Abs. Int.
-4,10e6
-2,05e6
-|—O.OOeO
34,0 RT
Rel. tnt.
100%
Fn 4
330.9792
QC Check
23.27-34.14
0%
Results: P:\P94Q0_P9499\P9464_6042 PCB\maounxs\P9464_6042_PCB_OQ2.utp_res, saved 24-Jul-2008 11:27 (EE)
AP UttraTmce-Pro V3 993 User/System: EE/EEC2-03S cc: 0603, 3754
Abs. Int.
4,B8e7
-2,44e7
O.OOeO
RT
Pealr annotation: Areas. Centmids
Revised: 24-M-2008 11:23:45 (EE) Printed: OS-Aug-2006 00:28:10 Page 12yt22
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 5
323.8834
PeC8-5
4a 2,34e3
34.16-41.15
0%-
PCB-126
5,Q5e6
34.44
2.95e5
2.i2e5
35.33
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcfa0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
35.0
36.0
T
2.9Se5
36.75
i	i
6.i2ee
8,E3e5
37.0
38.0
3.76e5
39.14
¦ .
Acq: 24-Jui-2008 04:47:22
User: JLJ Datafile: 080724V06 EQ
Abs. Int.
-1 52e6
39.0
40.0
•7.58e5
, ¦ O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4o 2.65e3
34.16-41.15
0%-
" l "
35.0
i r i i
360
7.53eS
36.75
¦ ¦
37.0
1.66e7
38.01
38.0
5 29e5
39,13
I
Abs. Int.
-3.70e6
-1.85e6
39.0
-j—i—i—i—i—|—i—i—i—i—j—i—r—i—i—|—t—*— O.OOeO
40,0	41.0 RT
Rel. Int.
100%-
Fn 5
337.9207
PeCB Std.
4o 3.96e3
34,16-41.15
0%-
Rel. Int.
100%-
Fn 5
339.9177
PeCB Std.
4o 5.07e3
34,16-41 15
0%-
ES-126
1.50 ei^
3&A2
35.0
35.0
36.0
8.11©5
36.94
i ¦«-—'| f
37,0
38.0
36.0
37.0
39.0
40.0
38.0
39.0
40.0
Abs, Int.
-5.56e6
•2.78e6
-O.OOeO
41.0 RT
Abs. Int.
-3 58e6
¦ 1,79s6
¦O.OOeO
41,0 RT
Rel, Int.
100%-
Fn 5
454,9728
QC Check
34.16-41.16"
0%-
35.0

36.0
| f I f
37.0
38.0
Results: P:\P9400_P9499V9464_6042 PCB\msoune$iP9464_e042_PCB_002,utp_ms. saved 24-M-200B 11:27 (EE)
AP Ultra Trsce-Pro V3.993 User/System: EE/EEC2-038 ccr 3077, 27$0
39.0
40.0
Abs. Int.
r2.00e7
-9.99e6
41.0
¦O.OOeO
RT
Peak annotation: Areas, Centroids
Revised: 24-M-2008 11:16:44 (EE) Printed: 0S-Aug-2008 08:28:12 Page 13 qT22
-------
AP Lab ID: P9464_6042_PCBJ302
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4o1.27e3
23.27-34.14
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06 EQ
0%-
PCB-153/168
2.13e7
32.4S
Ret. Int.
100%-
Fn 4
361.8385
HxCB-4
4o1.03e3
23,27-34.14
0%-
Rel, fnt.
100%-
Fn 4
371,8817
HxCB Std.
4o 2.00e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
373,8788
HxCB Std.
4o 1.41 e3
23,27-34.14 -
0%-
,! ,
24.0
PCB-136
3.07e€
27,17
A
PCB-161/135
6,92e6
29.18 PCB-14,
1,07e6
29.64
A
Q9e5
PCB-132
3.95e6
30.99
A
PC B-146
2.85e6
31.14
Ffcl
26,0
28,0
30,0
A~
PCB-163/138/129
1.90e7
33.49
:B-141
68e6
,2.61
32.0

PCB-16'
1.97e6
33,23
11
u
Abs, Int.
-5.16e6
2 58e6
OOOeO
34.0 RT
PCB-153/168
324es7 PCB-163/138/129
1.52e7
33,49
PCB-136
2.41 e6
27,17
A
24.0
PCB-151/135
6,52e6
29.18 PCB-14'
8.58e5
29.64
1 A ¦
A
26.0
28.0
CB-134
PCB-132
3 03e6
30.99
_A_
PCB-146
2,3le6
31,94
30,0
A
fCB-141
91e6
¦2.61 PCB-137
3.3965
¦¦r	"v	"t
it
32.0
-°r

Abs, Int.
-4.03e6
¦2.01 e6
•O.OOeO
ES-155
2,08e7
26,54
ES-153
1,66e7
32,43
JS-138
1.54e7
33.47
34.0 RT
Abs. Int.
5.54e6
•2.77e6
24.0
26,0
'—I—r_
28.0
I 1 I
I I ¦ I I
30.0
32,0
—[—O.OOeO
34,0 RT
ES-155,
1.62£r
2#
JS-138 /
l.24ej^
33,jf
Abs, Int.
-4.31 e6
•2.16e6
f l T"1 f i • * -
24,0
I I I I
26.0
¦O.OOeO
28,0
30,0
32,0
34,0 RT
Rel. Int.
100%
Fn 4
330,9792
QC Check
23.27-34.14
24.0
26.0
28.0
30.0
32,0
Results: P *P94O0_P9499\P9464_6O42 PCBVesowx:es\P9464_6042_PCB_002 utp_i*s. saved 24-Ju!-2008 11:27 (EE)
AP UttraTram-Pm V3.993 User/System: EE/BEC2-038 cc 3920, 6741	~
Abs. Irit.
4,88e7
2.44e7
T—O.OOeO
34.0 RT
Peak annotation: Areas, CentrokSs
Revised: 24-M-200B 11:25:09 (BE) Printed: 05-Ai/g-2008 06:26:13 Page 14 ofp^
-------
AP Lab ID: P9464 6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 5
359,8415
HxCB-5
4o 3,43e3
34,16-41,15
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial:
60
0%-
PCB-156/157
4,04e6
36.94
/
Acq: 24-JuI-2008 04:47:22
User: JLJ Datafile: 080724V06 EQ
Abs. Int.
-7.42e5
PCB-128/166
1.10e6
34,53
PC B-159
1.41e6
PCB-167
1.33e6
3S.33PCB-162 3599
' 5.80e5
35,59
iY\
PCB-169
9,9De5
39.62
¦TV
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4o 3.04e3
34.16-41.15
0%-
PCB-128/16B
1.02e6
34.54
35.0	36.0
PCB-159	PCB-167
I.i4e6	1.10e6
35.33PCB-162	35.99
5.12eS
35.59
I ""1	1	1-4—I	!	f—I T"
37.0
PCB-156/157
3.17e6
36.94
¦fV
38.0
, t ,/V.,, rZV\	,. /
39.0	40.0

35.0
,A\r i
PCB-169
7.4165
39.62
-*> .
36.0
Rel. Int.
100%-
Fn 5
371.8817
HxCB Std.
Aa 4.34e3
34,16-41.15
0%-
37.0
ES-156/157
3.50e7
36.93

38.0
A 39.62
/V
' 		 'p '' ' [ '
39 0	40.0

""1	1	1	1""
35.0
Rel. Int.
100%-
Fn 5
373.8788
HxCB Std.
4o 3.97e3
34 16-41.15 ¦
0%-
i i i i r r i
35.0
36.0
i i
3J.0
, , , , i , i i i i
38.0
39.0
1 1 i • ¦
ES-ier
1.3?fe?
36.97
A
2.76e7
36.93


ES-169
1.31e7
39
J
36.0
i—I i—j
37.0
38.0
39.0

40.0
I I [ »
40.0
-3.71e5
O.OOeO
I I I |
41.0 RT
Abs. Int.
-6.27e5
¦3.14e5
¦ I i' O.OOeO
41.0 RT
Abs. Int.
-5.81e6
-2.91e6
-r-1-O.OOeO
41.0 RT
Abs. Int.
-4.67e6
-2.34e6
™i—r-*~ O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15
0%-
35,0
I | I I I 1
36.0
	I	|	I	»	f	*	|	*	!	*	*	|	1	t	
37.0	38.0
39,0
Abs. Int.
-2.00e7
•9.99e6
t-L-O.OOeO
mf	*	*	T	T	|	f	I	T	T	J	1	*	*	Tm
40.0	41 0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_ PCB_002. utp_res. saved 24-JUI-2008 11:27 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 2106, 5678
Peak annotation: Areas. Centroid^
Revised: 24-Jul-2008 11:25:35 {EE} Printed: 05-Aug-2008 08:28:14 Page 15
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 4
393,8025
HpCB-4
4o 1.29e3
30.00-34.14
0%-
Rel. Int.
100%-
Fn 4
395.7995
HpCB-4
40 1.15e3
30.00-34.14
0%-
305
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
31.0
30.5
1 I '
31.0
I w
PCB-179
6,89e6
PCB-179
6.59e6
PCB-184
1.83e5
32.05
PCB-176
2.29e6
32.34
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06_EQ
Abs. Int.
1,65e6
•8.27e5
32.0
32,5
33.0
PCB-176
2.19e6
32.34
31.5
PCB-184
i.63eS
32.05
i i i	i i |
32.0
I | I
32.5
I—| 1 i
33.5
33.0
< I '
33,5
PCB-178
3.83e6
33.87
PCB-178
3.58e6
-O.OOeO
RT
Abs. Int.
-1.56e6
•7.81e5
34.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 4
405.8428
HpCB Std.
4o 3.13e3
30.00-34.14
0%-
30.5
' I '
31.0
31.5
32.0
32.5
-r—i—i » i | i i i i | i i r t | i
33.0	33.5
SS-178
1.36e7
33.85
-|*-i—!—r
Abs. Int.
-4.70e6
2.35e6
¦O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
407.8398
HpCB Std.
4o 1.30e3
30.00-34.14
0%-
| f I
30.5
"1—|-I—I—1—I f| I—I *1 I—[—I—I—I—I—|—T—l—!—I—|	1—I—!—I—|	1—I—I—I—|—I	1—P"
31,0	31.5	32.0	32.5
SS-178
Abs. Int.
-4,53e6
¦2.27e6
33.0
33.5
34.0
-O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
30.00-34.14
Abs. Int.
4.87e7
2.44e7
I i i * O.OOeO
34.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resovnXS\P9464_6042_PCB_002 utp_res. saved 24-Jut-2008 11:27 (EE)
AP UltmTmce-Pm V3.993 User/System: EE/EEC2-038 ce: 5515. 0933
Peak annotation: Areas. Centnjidt
Revised: 2*-Jul-2008 11:25:52 (EE) Printed: 0S-Aug-2008 08:28:15 Page 16 or/2
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm€ GC: pcbx100_a Vial
60
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06 EQ
Rel. Int.
100%-
Fn 5
393.8025
HpCB-5
4g 3.09e3
34.16-41.15
Q%-
PCB-187
2.91 e7
34.62
PCB-183
1.04e7
35.13
35.0
PCB-177
1.17«7
35.69
A
PCB-171/173
4.71e6
36.21
' I 1
36.0
37.0
PCB-172
4.0Se6
37.55
¦ o •
PCB-170
2.1167
39.14
JL
PCB-190
6.51 e6
39.58
/> -p>-
38.0
39.0
40.0
Abs, Int.
-1.66e7
•8.32e6
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4cr 1.97e3
34.16-41.15
0%-
PCB-187
2.82e7
34.62
T7
PCB-183
35.13
35.0
PCB-177
1.12e7 PCB-171/173
35.69	4.58e6
36.21
. 
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Re! Int.
100%-
Fn 6
393.8025
HpCB-6
4o2 29e3
41.17-46.41
0%-
PCB- 89
i.34ee
41.72
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb04O5_cI1-1O_mm6 GC: pcbx100_a Vial: 60
I I t i
42.0
43.0
Acq: 24-Jul-2QG8 04:47:22
User: JLJ Datafile: 080724V06_EQ
Abs. Int.
3.87e5
•1.93e5
	f->	
yy
44.0
45.0
I I t — I	I 'I
46.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
395.7995
HpCB-6
4
-------
AP Lab ID: P9464 6042„PCB„002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 5
427.7635
OcCB-5
4o 8.28e2
34.16-41.15
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
0%-
Acq: 24-Ju 1-2008 04:47:22
User: JLJ Datafile: 080724V06 JEQ
Abs. Int.
-8.06e6
PCB-202
4.84e6
35.80
A
Rel. Int.
100%-
Fn 5
429.7606
OcCB-5
4o1.10e3
34.16-41.15
0%-
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std.
4o 2.14e3
34.16-41.15
0%-
35.0
36.0
PCB-201
3.93e6
36.56
-A-
37.0
PCB-197
1.30e6
37-^\
38.0
39.0
35.0
PCB-202
5.34e6
35.00
. .A,
PCB-201
4.45e6
36.56
35.0
35.0
36.0
-A-
PCB-197
1.50e6
37.0
38.0
till
39.0
PCB-198/199
3.5667
PCB-190
1.49e7
40.27
PCB-198/199
3.99e7
PCB-196
1.66e7
40.27

ES-202
Rel. Int.
1,49e7
100%-
35.77
Fn 5


439.8038 ¦


OcCB Std. '


4o 1.36e3 "


34.16-41.15 ¦
f

0%-

I
I 1 1
36.0
1 I 1
37.0
' I •
38.0
39.0
40.0
1 tn?
is
36.0
1 1 I '
37.0
38.0
39.0
40.0
-4.03e6
O.OOeO
'¦ '	t	
41.0 RT
Abs. Int.
-8.84e6
•4.42e6
41.0
-O.OOeO
RT
Abs. Int.
-3.57e6
• 1.79e6
•O.OOeO
41.0 RT
Abs. Int.
-3 86e6
• 1,93e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
'"I	I	|	*'
35.0
36.0
37.0
' I r
38.0
Results: P:\P9400_P9499\P9464_6042 PCBVesaurce$\P9464_6042_PC8_002.utp_nes, saved 24-Jut-2W8 11:27 (EE)
AP UttraTrace-Piv V3.993 User/System: EE/EEC2-03S cc 2734. 4066
39.0
40.0
Abs. Int.
-2,00e?
¦9.99e6
41.0
¦O.OOeO
RT
Peak annotation: Areas. Centroids^
Revised: 24-M-2006 11:27:27 (EE) Printed: OS-Aug-2006 08:28:18 Page 19 otH2
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 6
427,7635
OcCB-6
4o 2.10e3
41.17-46.41
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 60
o%-
Rel. Int.
100%-
Fn 6
429.7606
OcCB-6
40 1.97e3
41.17-46.41
0%-
Rel. Int.
100%-
Fn 6
439.8038
OcCB Std.
4o2.08e3
41.17-46.41
0%-
Rel. Int.
100%-
Fn 6
441.8008
OcCB Std.
4o1.71e3
41.17-46.41
0%-
PCB-195
1.03e7
41.53
42.0
43.0
PCB-194
3,Q3e7
4346
Acq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06_EQ
Abs, Int.
-6.27e6
PCB-205
1.65e6
43.85
,	
1—
44.0
1—I—
45.0
¦3,13e6
46.0
PCB-194

3.34e7

43.46
A
PCB-195

1.14e7

41.53
K
/1
-i—/-O.OOeO
RT
Abs. Int.
7.10e6
3 55e6
PCB-205
1.74e6
43.85
i	i
42.0
43.0
44.0
45.0
JS-194
i.ose7
43.44
ES-205
1.15«7
43.84
'—I—
42.0
43.0
JS-194
43.84
i | i i i 0. OQeO
46.0	RT
Abs, Int.
2.38e6
•1.19e6
45.0
n—1—1—1—1—I—1
46.0
-O.OOeO
RT
Abs. Int.
-2.72e6
1 36e6
42.0
43.0
44.0
45.0
46,0
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41
0%-
42.0
43.0
44.0
45.0
46 0
Abs. Int.
r 1 90e7
•9.50e6
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resouiXXS\P9464_6042_PCB_002utp_nes. saved 24-Jul-2008 11:27 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc. 5116, 7710
Peak annotation: Areas. Centroipe
Revised: 24~Jul-2008 11:18:39 (EE) Printed: 0S-Aug-2008 08:28:20 Page 20 ofi2
-------
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 6
461.7245
NoCB
4o 7.94e2
41.17-46.41
Sample ID: Run# I-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
0%-
PCB-208
2,44e6
41.33
A-
Rel. Int.
100%-
Fn 6
463,7216
NoCB
4o 2.38e3
41.17-46.41
0%-
PCB-208
3.10e6
41.33
A-
ES-208
Rel. Int. 9:8566
100%- 41 J1
Fn 6
473.7648 •
NoCB Std.
4a 1,84e3 .
41,17-46.41 -j
0%-
ES-208
Rel. Int.
100%-, 
-------
46 62
AP Lab ID: P9464_6042_PCB_002
Instr: AutoSpec-Premier MM6
PCB-2Q9
Rel, Int. 5J2e5
100%-
Fn 7
497,6826
DeCS
4o 8.11e2
46,42-54.01
Sample ID: Run# I-ACD-M23-1
VSIR expt; pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 60
0%-
Aeq: 24-Jul-2008 04:47:22
User: JLJ Datafile: 080724V06 EQ
Abs. Int.
-1.36eS
47.0
48.0
"I-"-
I I T f I I'll
49,0
50.0
—T—I—I—|—1—T—I—1	|—I—I" I I " j—I—I "" I "T "" | I t 1	E |" 'I
51,0	52.0
•6.78e4
53.0
PCB-209
Rel. Int. 4J7„e5
100%-
Fn 7
499.6797
DeCB
4o 5.39e2
46.42-54.01
46.62
0%-
' I '
47.0
ES-209
Rel. Int. ijae?
100%
46.60
Fn 7
509,7229
DeCB Std.
4o 9.00e2
46.42-54.01
Fn 7
511.7199
DeCB Std.
4o 8,27e2
46,42-54.01
47.0
ES-209
Rel. Int.
100%
47.0
48.0
49,0
50.0
51.0
52.0
480
49.0
50.0
51 0
52.0
48.0
49.0
' I '
50.0
51.0
52.0
53.0
53.0
53.0
( i < t * f 0.0080
54,0 RT
Abs. Int.
I.!2e5
5.61e4
* ¦' '	I"
-O.OOeO
54.0 RT
Abs. Int.
2,59e6
1 30e6
-O.OOeO
54.0 RT
Abs. Int.
2.20e6
•1,10e6
¦O.OOeO
54.0 RT
Rel, Int.
100%
Fn 7
454.9728
QC Check
46.42-54.01
47.0
Abs. Int.
-1,89e7
9,44e6
48.0
49.0
50.0
Results P:\P9400_P9499\P9464_6042 PC8SresouwesV94S4_S042_PCB_002.utp_ms. saved 24-Jul-2008 11:27 (£E)
AP Ultra Trace-Pro 1/3.993 User/System EE/EEC2-Q 38 cc: 7645. 3209
I t i i—>—J—i—r-i—i—f-O.OOeO
51.0	52,0	53.0	54.0 RT
Peak annotation: Areas. Centrxxsts
Revised: 24-Jul-200B 11:18:07 (EE) Printed: OS-Aug-2008 08:28:22 Page 22yf22
-------
Datafile: 080724V07_EQ
Acquired: 24 Jul 2008 05:44:48
Client ID: Run# I-ACD-M23-2
Lab ID: P9464 6042 PCB 003
P9464_6042_PC8_003
Name
PCB-77 33'44'-TeCB
PCB-81 344'5-TeCB
PCB-105 233'44'-PeCB
FCB-114 2344'5-PeCB
PCB-118 23'44'5-PeCB
PCB-123 2'344'5-PeCB
PCB-126 33'44'5-PeCB
PCB-156/157 233'44 * 5/23 3'44'5 *
PCB-167 23"44"55"-HxCB
PCB-169 33'44'55"-HxCB
PCB-189 233 * 44155'-HpCB
PCB-209 DeCB
Actual
RT
28.96/"/
28-49 '
31.88 /
31.34 X
30.90 S
30.62
34.45 /
36. 95/
35.99 S
39 .64 //
41.73-
46.63.
QC
Prod
RRT
1.0006
1.0006
1.0007
1.0007
1.0008
0006
0005
0005
0006
0004
0005
0004
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
PCB-
PCB-
PCB-
PCB-
PCB
PCB
PCB-
PCB
PCB
PCB
PCB
PC3
PCB
PCB
PCB
PCB-
PCB
PCB-
PCB
PCB-
PCB
PCB-
PCB-
PCB
PCB-
PCB-
PCB-
PCB-
PCB-
-1
¦3
-4
-15
-19
-37
-54
-77
-81
-104
¦105
¦114
¦118
-123
¦126
-153
-155
¦156/157
¦167
-169
¦170
¦180
•188
-189
¦202
-205
•206
-208
¦209
9.47 -
0.7047
11.42 x
0.8520
11.66 "
0.8687
16.82'
1.2550
14.39 -
1.0745
22.80 -
1.0878
17.08 '
0.8144
28.94 '
1.3808
28.47 -
1.3585
21,76."
0.8143
31.86-'
1.1919
31.32-"
1.1717
30.88 ,
1.1551
30.60^
1.1449
34.43 ^
1.2881
32 .43 *•
0.9690
26.54 '
0.7930
36.93 -
1.1035
35.97 ,,
1.0747
39.62 -
1.1038
39.13 ""
0.9006
38.09 "
0.8765
31.31 "
0.7207
41.71 *•
0.9600
35.78 "
0.8234
43.84 '
1.0090
45.28 "
1.0420
41.32 "
0.9509
46.61 -
1.0726
Analytical Perspectives
Wt/Vol: 1 -	U B6S3_6042_PCB_VAB CPSIVi_080724_PCB_VA
A-level: 20 pg	'	" "	Nominal ES spike: 4000 pg
Actual
Diff




Ckeckcode•
X*
RJRT
Sees
Response
Ra
L*S -^
RRF ,
Cone
Noise
DL
1.0006
0
1.70E+07
0.76
1.05
1,490
7.58E+03
7.07
1.0006
0
2.71E+06
0.76
1.10
232
7.58E+03
6.88
1.0007
0
4.45E+06
0.61
0.97
470
6.70E+03
7.32
1.0006
-0.2
7.26E+05
0.56
0.94
83.9
6.70E+03
8.15
1.0007
-0.2
5.46E+06
0.60
0.97
615
6.70E+03
7.84
1.0006
0
9.47E+05
0 .59
0.96
110
6.70E+03
8,29
1.0005
0
6.09E+06
0.60
0.98
629
5.86E+03
6.54
1.0003
-0.4
3.38E+06
1.28
0.97
444
3.79E+03
7.23
1.0006
0
1.12E+06
1,30
0.99
148
3.79E+03
5.34
1.0005
+0.2
9.00E+05
1.28
0.93
132
3.79E+03
6.1
1.0004
-0.3
1.15E+06
1.02
0.92
142
3.48E+03
4.78
1.0004
0
7.00E+05
1.13
0.91
/
132
1.77E+03
3 .66




/
Recv.


0.7066
+1.1
4.42E+07
3.21
0.94 V
88.2 %
25%
150%
0.8524
+0.3
4.71E+07
3 .21
0.92
95.8 %
25%
150%
0.8706
+1.3
3.36E+07
1.55
0.64
98.4 %
25%
150%
1.2551
+0.1
5.47E+07
1.60
0.99
103 %
25%
150%
1.0743
-0.2
3.14E+07
1.06
0.58
103 %
25%
150%
1.0879
+0.1
4.74E+07
1.06
1.41
102 %
25%
150%
0.8150
+0.6
3.42E+07
0.77
1.12
92 %
25%
150%
1.3809
+0.2
4.35E+07
0.82
1.18
111 %
25%
150%
1.3586
+0.2
4.23E+07
0.80
1.13
113 %
25%
150%
0.8141
-0.3
3.50E+07
1.59
1.27
88.3 %
25%
150%
1.1918
-0.2
3.92E+07
1.57
1.13
111 %
25%
150%
1.1717
0
3.67E+07
1.57
1. 17
101 %
25%
150%
1.1550
-0.2
3.66E+07
1.59
1.17
99.9 %
25%
150%
1.1449
0
3.57E+07
1.61
1.10
103 %
25%
150%
1.2879
-0.4
3.97E+07
1.60
1.29
98.2 %
25%
150%
0.9690
0
2.98E+07
1.29
1.12
96.6 %
25%
150%
0.7929
-0.2
3.61E+07
1.26
1.48
88.9 %
25%
150%
1.1034
-0.2
6.29E+07
1.25
1.23
93 %
25%
150%
1.0747
0
3.08E+07
1.26
1.23
90.9 %
25%
150%
1.1836
-0.5
2.93E+07
1.25
1.21
88 .1 %
25%
150%
0.9005
-0.2
2.32E+07
1.03
0.90
111 %
25%
150%
0.8764
-0.2
2.77E+07 ¦
1.08
1.10
109 %
25%
150%
0.7206
-0.2
3.80E+07
1.06
1.43
96.9 %
25%
150%
0.9599
-0.3
3.53E+07
1.06
1.53
99.1 %
25%
150%
0.8234
0
3.20E+07
0.91
1.25
93 %
25%
150%
1.0090
0
2.48E+07
0.92
1.08
99 %
25%
150%
1.0421
+0.3
1.67E+07
0.78
0.73
97.9 %
25%
150%
0.9509
0
2.28E+07
0.78
0.99
99.5 %
25%
150%
1.0727
+ 0.3
2.33E+07
1.18
1.04
97.2 %
25%
150%
Page 1 of 5
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_PCB_003
Name
SS PCB-28
SS PCB-111
SS PCB-178
Actual
RT
19.40 "*
28.97 «•
33.85*""
QC
Pred
RRT
0.9259
1.0838
1.0113
CS PCB-28
CS PCB-111
CS PCB-178
19.40-
28.97"
33.85'
0.9259
1.0838
1.0113
JS	PCB-9
JS	PCB-52
JS	PCB-101
JS	PCB-138
JS	PCB-194
13.40-"
20.96 ^
26.73 ^
33.47 ^
43.45 ^
ChecJtcode:
IF

PCB-1 2-MoCB
9.48
1.0011
PCB-2 3-MoCB
11.27
0.9869
PCB-3 4-MoCB
11.43
1.0010
PCB-4 22'-DiCB
11.68
1.0012
PCB-10 26-DiCB
11.83
1.0146
PCB-9 25-DiCB
13.41
1.0011
PCB-7 24-DiCB
13.56
1.0119
PCB-6 23'-DiCB
13.77
1.0275
PCB-5 23-DiCB
14.03
1.0477
PCB-8 24'-DiCB
14.14
1.0560
PCB-14 35-DiCB
15.56
0.9258
PCB-11 33'-DiCB
16.29
0.9689
PCB-13/12 34'-/34-DiCB
16.57
0.9848
PCB-15 44'-DiCB
16.83
1.0009
PCB-19 2 2'6-TrCB
14.41
1.0011
PCB-30/18 246-/22'5-TrCB
16.03
1.1129
PCB-17 22'4-TrCB
16.39
1.1388
PCB-27 23'6-TrCB
16.58
1.1517
PCB-24 236-TrCB
16.69
1.1599
PCB-16 2 2'3-TrCB
16.79
1.1664
Analytical Perspectives
Actual
Dif f
Checkcode:
RUT
Sees
Response
Ra
RRF
/
Cone
Noise
0.9258
-0.1
5.04E+07
1.05
1.05
\/
101 %
30%
1.0838
0
4 .34E+07
1.62
1.19

102 %
30%
1.0113
0
2.69E+07
1.05
0.65
J
109 %
30%
0.9258
-0.1
5.04E+07
1.05
1.48
J
103 %
30%
1.0838
0
4.34E+07
1.62
1.31

106 %
30%
1.0113
0
2.69E+07
1.05
0.93

105 %
30%
X*
DL
135%
135%
135%
135%
135%
135%
5.32E+07
3.31E+07
3.13E+07
2.75E+07
2.32E+07
1.62
0.80
1.59
1.30
0.91
Totals
Mono-CBS
Di-CBs
Tri-CBs
Tetra-CB;
Penta-CB;
Hexa-CBs
Hepta-CB;
OcCa-CBs
Nona-CBs
1.0011
0
0.9870
+ 0.1
1.0010
0
1.0013
+0.1
1.0137
IX?
O
I
1.0007
-0.3
1.0118
1
o
1.0274
-0.1
1.0475
-0.2
1.0556
-0.3
0.9255
O
i
0.9687
-0.2
0.9851
+0.3
1.0009
0
1.0010
-0.1
1.1139
+1.0
1.1387
-0.1
1.1518
+0.1
1.1597
-0.2
1.1664
0
NON-EMFC
20,700
19,400
17,400
15,900
6,230
4, 040
2,280
1,260
467
3.39E+07	3.08
1.30E+08	3.09
1.16E+08	3.09
4.57E+06	SI*
1.24E+06	SI*
6.65E+06	SI*
1.94E+07	SI*
1.20E+07	SI*
9.34E+06	SI*
1.91E+07	SI*
1.76E+07	SI*
4.72E+07	SI*
9.20E+07	SI*
1.93E+07	SI*
1.78E+06	1.01
1.18E+07	1.04
5.99E+06	1.06
1.81E+06	1.00
1.02E+06	1.04
4.23E+06	1.04
EMFC
01/
20,700
5.17
19,400
9.65
17,400
7.2
16,200
5.41
6,490
6.92
4,050
5.36
2,300
4,63
1,260
3.91
467
y
7.45
1.19%/
2, 570
1.11
9,930
1.21
8,190
0.98
555
1.42
104
0.97
502
0.98
1,460
0.97
905
0.92
744
0.98
1, 420
1.12
1,150
0.91
3,770
0.91
7,380
0.99
1,420
1.01
225
1.10
1,370
0.96
793
1.31
176
1.23
105
0. 81
667
1.18E+04	4.81
1.18E+04	6.01
1.18E+04	5.52
1.17E+04	12.1
1.17E+04	8.35
1.11E+04	7.35
1.11E+04	7.3
1.11E+04	7.37
1.11E+04	7.75
1.11E+04	7.26
1.11E+04	6.36
1.11E+04	7.79
1.11E+04	7.8
1.11E+04	7.17
6.29E+03	6.09
6.29E+03	5.58
6.29E+03	6.37
6.29E+03	4.69
6.29E+03	4.98
6.29E+03	7.6
Page 2 of 5
Printed: 08 06 2008 1 ;20 PM
-------
P9464_6042_PCB_003
Actual

Prod
Name

RT
QC
RJRT
PCB-32
24'6-TrCB
17,24

1.1973
PCB-34
2'35-TrCB
18.31

0.8032
PCB-23
235-TrCB
18.44

0.8091
PC3-26/29 23"5-/245-TrCB
18.71

0.8210
PCB-25
23'4-TrCB
18.90

0.8292
PCB-31
24'5-TrCB
19.17

0.8409
PCB-28/20 244 *-/233'-TrCB
19.43

0.8525
PCH-21/33 234-/2'34-TrCB
19.62

0.8598
PCB-22
234'-TrCB
19.96

0.8756
PCB-36
33'5-TrCB
21.28

0.9334
PCB-3 9
34'5-TrCB
21.59

0.9468
PCB-38
345-TrCB
22.08

0.9685
PCB-35
33'4-TrCB
22.47

0.9856
PCB-37
344'-TrCB
22 .82

1.0008
PCB-54
22'66--TeCB
17.10

1.0011
PCB-50/53 22"46-/22'56"TeCB
18.93

0.9043
PCB-45
22"36-TeCB
19.50

0.9307
PCB-51
22'46'-TeCB
19.57

0.9339
PCB-46
22'36'-TeCB
19.77

0.9436
PCB-52
22'55'-TeCB
20.98

1.0010
PCB-73
23'5'6TeCB
NotFnd

1.0068
PCB-43
22'3 5-TeCB
21.18

1.0108
PCB-69/49 23'46-/22'45'TeCB
21.39

1.0196
PCB-48
22"45-TeCB
21.63

1.0323
PCB-44/47/65 22'35'-/22 ' 44 ' -
21.85

1.0422
PCB-59/62/75 233'6-/2346-/24
22.10

1.0547
PCB-42
22'34"-TeCB
22.27

1.0624
PCB-41
22"34-TeCB
22.58

1.0775
PCB-71/40 23'4'6/22'33'-TeCB
22.68

1.0822
PCB-64
234¦6-TeCB
22.87

1.0913
PCB-72
23"55'-TeCB
23.57

0.8279
PCB-68
23'45'-TeCB
23.82

0.8365
PCB-57
233'5-TeCB
24.17

0.8489
PCB-58
233'5'-TeCB
24.37

0.8559
PCB-67
23'45-TeCB
24.51

0.8610
PCB-63
234•5-TeCB
24 .74

0.8687
PCB-61/70/74/76 2345-/23'4'5
25.03

0.8785
PCB-66
23'44'-TeCB
25.29

0.8882
PCB-55
233'4-TeCB
25.43

0.8931
PCB-56
2 33'4'-TeCB
25.85

0.9080
PCB-60
2344'-TeCB
26.04

0.9144
PCB-80
33'55'-TeCB
26 .37

0.9261
PCB-79
33'45'-TeCB
27.65

0.9711
PCB-7 8
33'45-TeCB
28.11

0.9876
PCB-104
22'466'-PeCB
21.78

1.0009
PCB-96
22'366'-PeCB
22.09

1.0153
PCB-103
22'45'6-PeCB
NotFnd

0.8878
Analytical Perspectives
Actual
Diff




Checkcode:
X"
RRT
Sees
Response
Ra
RKF
Cone
Noise
DL
1.1974
+ 0.1
6.59E+06
1.01
1.38
606
6.29E+03
4.43
0.8032
0
1.64E+06
1.02
1.03
134
8.94E+03
7.17
0.8090
-0.1
2.02E+06
0.99
J—1
o
o
170
8.94E+03
7.41
0.8206
-0.4
8.78E+06
1.01
1.04
713
8.94E+03
7.14
0.8291
-0.1
6.57E+06
1.03
1.12
495
8.94E+03
6.63
0.8408
-0.1
1.72E+07
1.04
1.06
1,370
S.94E+03
6.98
0.8521
-0.5
2.91E+07
1.03
1.05
2,350
8.94E+03
7.08
0.8604
+0.7
1.70E+07
1.04
1.03
1,400
8.94E+03
7.22
0.8755
-0.1
1.06E+07
1.02
1.01
886
8.94E+03
7.33
0.9335
+0.1
6.20E+06
1.02
1.05
498
8.94E+03
7.06
0.9469
+0.1
5.47E+06
1.04
1.06
435
8.94E+03
6.98
0.9685
0
6.25E+06
1.08
0.95
554
8.94E+03
7.78
0.9856
0
2.42E+07
1.02
0.95
2,140
8.94E+03
7.77
1.0008
0
2.46E+07
1.04
0.89
2,320
8.94E+03
8.31
1.0011
0
9.22E+04
0.89
1.09
9.93
3.17E+03
3 .05
0.9035
-0.9
1.55E+06
0.78
0. 74
200
3.64E+03
4.96
0.9306
-0.1
1.45E+06
0.79
0.57
241
3.64E+03
6.39
0.9338
-0.1
6.76E+06
0.77
CO
o
780
3.64E+03
4.45
0.9435
-0.1
5.87E+05
0.75
0.59
93 .5
3.64E+03
6.15
1.0010
0
7.94E+06
0.77
0.72
1, 040
3.64E+03
5.08
-

0.00E+00

0. 93

3.64E+03
3.92
1.0106
-0.3
5.33E+05
0.79
0. 59
85.9
3 .64E+03
6.22
1.0208
+1.5
6.14E+06
0.76
0. 83
697
3.64E+03
4.38
1.0323
0
1.98E+06
0.78
0.71
265
3.64E+03
5.17
1.0426
+0.5
2.64E+07
0.78
0.75
3,320
3.64E+03
4 .85
1.0546
-0.1
2.15E+06
0.77
0.94
216
3.64E+03
3.87
1.0626
+0.3
2.52E+06
0.78
0.67
358
3.64E+03
5.49
1.0776
+0.1
1.07E+06
0.79
0.56
182
3.64E+03
6.53
1.0823
+0.1
3.97E+06
0.77
0.75
498
3.64E+03
4.84
1.0913
0
4.38E+06
0.78
0.98
424
3.64E+03
3 .73
0.8279
0
8.94E+05
0.71
1.15
73.4
7.58E+03
6.6
0.8365
0
1.25E+07
0.78
1.18
1,000
7.58E+03
6.47
0.8489
0
1.40E+06
0.76
1.09
121
7.58E+03
6.96
0.8558
-0.1
1.18E+06
0.75
1.09
103
7.58E+03
6.97
0.8610
0
2.44E+06
0.83
1.18
196
7.58E+03
6.45
0.8689
+ 0.3
1.56E+06
0.75
1.17
126
7.58E+03
6.48
0.8790
+0.8
1.78E+07
0.77
1.12
1, 500
7.58E+03
6.77
0.8884
+ 0.3
1.08E+07
0.76
1.13
906
7 .58E+03
6.74
0.8932
+0.2
2.01E+06
0.71
1.04
183
7.58E+03
7.33
0.9080
0
7.S7E+06
0.77
1.07
693
7.58E+03
7.08
0.9144
0
3.35E+06
0.78
1.07
295
7.58E+03
7.09
0.9262
+0.2
1.10E+06
0 . 83
1.20
86.2
7.58E+03
6.32
0.9712
+0.2
5.90E+06
0.78
1.18
471
7.58E+03
6.42
0.9874
-0.3
3.01E+06
mm
1.02
279
7.58E+03
7.47
1.0011
+0.3
6.29E+04

1.02
7.07
3.24E+03
3.4
1.0152
-0.1
2.02E+05
0.55
0.88
26.4
3.24E+03
3 .95
-

0.00E+00

0.82

6.70E+03
9.75
Page 3 of 5
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_PCB_003	Actual	Pred
Name	rt	QC	RRT
PCB-94 22'356'-PeCB
NotFrid
0.8948
PCB-95 22'35"6-PeCB
24.29
0.9087
PCB-100/93 22144'6-/22'356-?
24.48
0.9158
PCB-102 22'456'-PeCB
24.60
0.9201
PCB-98 22'3'46-PeCB
NotFnd
0.9225
PCB-88 221346-PeCB
24.93
0.9329
PCB-91 22"34"6-FeCB
25.01
0.9358
PCB-84 22'33'6-PeCB
25.20
0.9429
PCB-8S 22'346'-PeCB
25.60
0.9579
PCB-121 23'45'6-PeCB
25.95
0.9708
PCB-92 22'355'-PeCB
26.26
0.9825
PC3-113/90/101 233'5'6-/22'3
26.75
1.0000
PCB-83 22'33'5-PeCB
27.12
1.0157
PCB-99 22*44'5-PeCB
27.24
1.0190
PCB-112 233"56-PeCB
NotFnd
1.0228
PCB-108/119786/97/125/87 233
27.67
1.0353
PCB-117 234'56-PeCB
28.18
1.0545
PCB-116/85 23456-/22-344'-Pe
28.26
1.0575
PCB-110 233'4'6-PeCB
28.40
1.0624
PCB-115 2344'6-PeCB
28.48
1.0651
PCB-82 22'33'4-PeCB
28.67
1.0725
PCB-111 233'55'-PeCB
28.99
1.0846
PCB-120 23'455'-PeCB
29.38
1.0990
PCB-107/124 233'415-/2 * 3455'
30.32
0.9908
PCB-109 233'46-PeCB
30.53
0.9973
PCB-106 233145-PeCB
30.72
1.0039
PCB-122 2'33'45-PeCB
31.18
1.0100
PCB-127 33'455'-PeCB
33.10
1.0390
PCB-155 22'44'66'-HxCB
NotFnd
1.0008
PCB-1S2 22'3566'-HxCB
26.73
1.0070
PCB-150 22'34'66'-HxCB
26.87
1.0122
PCB-136 22'33'66'-HxCB
27.17
1.0236
PCB-145 22'3466'HxCB
27 .42
1.0331
PCB-148 22'34'56'-HxCB
28.68
1.0805
PCB-151/135 22135516-/22'33 '
29.19
1.0997
PCB-154 22'44'5'6-HxCB
29.38
1.1070
FCB-144 22'345'6-HxCB
29.65
1.1169
PCB-147/14 9 22134'56-/22'34'
29.94
1.1281
PCB-134 22'33'56-HxCB
30.11
1.1343
PCB-143 22'3456'-HxCB
NotFnd
1.1374
PCB-139/140 22'344'6-/22'344'
30.44
1.1469
PCB-131 22'33'46-HxCB
30.61
1.1532
PCB-142 22'3456-HxCB
NotFnd
1.1582
PCB-132 22'33'46'-HxCB
30.99
1.1676
PCB-133 22¦33'55'-HxCB
31.40
1.1832
PCB-165 233'55'6-HxCB
NotFnd
0.9482
PCB-146 22'34'55'-HxCB
31.94
0.9543
Analytical Perspectives
Actual Diff
RRT
Sees
Response
Ra
RRW
-


O.OOE+OO

0.71
0.9085
-0
3
3.352+06
0.69
0.77
0.9157
-0
1
2.78E+05
0.66
. 0.78
0.9203
+0
3
3.48E+05
¦ 0.73
0.88
-


O.OOE+OO

0.69
0.9326
-0
4
9.11E+04

0.66
0.9357
-0
2
9.18E+05
0.61
0.84
0.9427
-0
3
1.O8E+06
0.63
0.66
0.9578
-0
2
1.74E+05
0.61
0.70
0.9707
-0
2
1.03E+05
¦ 0.52
1.02
0.9823
-0
3
7.43E+05
0.62
0.74
1.0007
+1
1
4.72E+Q6
0.61
0.84
1.0146
-1
8
6.60E+05
¦ 0.49
0.59
1.0189
-0
2
2.17E+06
0. 67
0.85
-


0.00E+00

0.97
1.0352
-0
2
5.32E+06
0.56
0.85
1.0542
-0
5
2.74E+05
0.61
0.94
1.0572
-0
5
1.17E+06
0.64
0.83
1.0624
0

5.16E+06
0.61
0.93
1.0656
+0
9
1.82E+05

1.02
1.0724
-0
2
9.09E+05
0.63
0.62
1.0846
0

3.36E+05
¦ 0.51
1.00
1.0990
0

6.22E+05
0.60
0.99
0.9908
0

1.05E+06
0.61
0.96
0.9974
+0.
2
2.03E+06
0.61
1.01
1.0039
0

6.44E+05
0.61
0.94
1.0100
0

9.78E+05
0.64
0.86
1.0391
+0.
2
9.32E+05
0.63
0.88
-


0.00E+00

1.03
1.0071
+0.
2
8.91E+04
¦ 1.51
0.98
1.0123
+0.
2
2.40E+05
1.26
0.96
1.0237
+0.
2
8.18E+05
1.16
0.92
1.0330
-0.
2
1.21E+05
1.08
0.90
1.0804
-0-
2
1.33E+05
1.07
0.89
1.0997
0

1.44E+06
1.32
0.89
1.1070
0

2.68E+05
1.11
1.04
1.1170
+0
2
3.46E+05
1.31
0.93
1.1281
0

2.95E+06
1.27
0.93
1.1344
+0
2
3.21E+05
1.29
0.75
-


0.00E+00

0.87
1.1468
-0
2
5.47E+05
1.30
0.92
1.1534
+0
4
3.65E+05
1.26
0.80
-


O.OOE+OO

0.80
1.1677
+0
2
1.39E+06
1.23
0.83
1.1833
+0
2
1.56E+05
1.26
0.86
-


0.00E+00

1.05
0.9S43
0

8.76E+05
1.23
0.93
Page 4 of 5

Checkcode:
/
Cone
Noise
DL

6.70E+03
11.2
486
6.70E+03
10.3
40
6.70E+03
10.2
44.4
6.70E+03
9.07

6,7 0E+03
11.5
15.4
6.70E+03
12
122
6.70E+03
9.48
183
6.70E+03
12.1
28.1
6.70E+03
11.4
11.3
6.70E+03
7.83
113
6.70E+03
10.8
628
6.70E+03
9.45
126
6.70E+03
13.6
287
6.70E+03
9.39

6.70E+03
8.21
705
6,70E+03
9.42
32 .6
6.70E+03
8.46
157
6.70E+03
9.54
620
6.70E+03
8.54
19.9
6.70E+03
7.77
165
6.70E+03
12.9
37.7
6.70E+03
7.99
70. 7
6.70E+03
8.08
123
6.70E+03
8.31
226
6.70E+03
7.9
76.9
6.70E+03
8.49
124
6.70E+03
8.96
108
6.70E+03
8.01

2.52E+03
2.77
10
2.52E+03
2.89
27.8
2.52E+03
2.98
99
2.52E+03
3.11
14.9
2.52E+03
3.16
20.1
2.52E+03
3.92
218
2.52E+03
3. 92
34 .4
2,52E+03
3.33
49 .8
2.52E+03
3.74
427
2.52E+03
3.75
57 .2
2.52E+03
4.62

2.52E+03
3.99
80.1
2.52E+03
3.79
61.2
2.52E+03
4.35

2.52E+03
4.36
224
2.52E+03
4.18
24.4
2.52E+03
4.05

2.52E+03
3.3
126
2.52E+03
3 .73
Printed: 08 06 2008 1:20 PM
-------
P9464_6042_PCB_003
Actual

Pred
Actual
Name
RT
QC
RRT
RRT
PCB-161 233'45'6-HxCB
NotFnd

0.9577
-
PCB-153/168 22'44'55'-/23'44'
32.46

0.9702
0.9697
PCB-141 22'3455'-HxCB
32.62

0.9745
0.9745
PCB-130 22'33'45'-HxCB
32.96

0.9846
0.9848
PCB-137 221344'5-HxCB
33.14

0.9901
0.9900
PCB-164 233'4'5'6-HxCB
33.24

0.9930
0.9930
PCB-163/138/129 233'4'56-/22'
33.50

1.0012
1.0009
PCB-160 233'456-HxCB
PCB-158 233"44"6-HxCB
PCB-128/166 22'331441-/2344 ' 5
PCB-159 233'455 *-HxCB
PCB-162 233'4'55'-HxCB
PCB-188 22"341566'-HpCB
PCB-179 22'33'566'-HpCB
PCB-184 22'344'66'-HpCB
PCB-176 22'33'466'-HpCB
PCB-186 22'34566'-HpCB
PCB-178 22'33'55'6-HpCB
PCB-175 22'33'45'6-HpCB
PCB-187 22'34'55•6-HpCB
PCB-182 22'344"56'-HpCB
PCB-183 22'344'5'6-HpCB
PCS-185 22'3455'6-HpCB
PCB-174 22'33'456'-HpCB
PCB-177 22'33'4156-HpCB
PCB-181 22'344'56-HpCB
PCB-171/173 22'33'44'6-/22 ' 3
PCB-172 22'33'455'-HpCB
PCB-192 233'455'6-HpCB
PCB-180/193 22'344'55'-/233 '
PCB-191 233'44'516-HpCB
22133'4415-HpCB
233'44'56-HpCS
22'33'55'66'-OcCB
22'33'45'66'-OcCB
22'344'566'-OcCB
22'33'44*66•-OcCB
22'33*4566"-OcCB
PCB-198/199 22'33'455'6-/22'
PCB-196 22'33'44'56'-OcCB
22'344'55'6-OcCB
22'33'44'56-OcCB
22'33 '44 '55'-OCCB
233'44'55'6-OcCB
22'33'455'66 '-NoCB
22133'44'566'-NoCB
22'33'44155"6-NoCB
PCB-170
PCB-190
PCB-202
PCB-201
PCB-204
PCB-197
PC3-200
PCB-203
PCB-195
PCB-194
FCB-205
PCB-208
PC8-207
PCB-206
NotFnd
33.82
34.55
35.35
35.60
31.34
31.62
32.05
32.35
32.74
33.87
34.40
34.63
34.79
35.13
35.23
35.33
35.70
NotFnd
36.22
37.56
NotFnd
38.09
38.40
39.15
39.59
35.80
36.56
37.13
37.32
37.41
39.73
40.28
40.44
41. 54
43.47
43.87
41.34
42.11
45.30
1.0049
1.0104
0.9601
0.9829
0.9896
1.0007
1.0097
1.0236
1.0331
1.0453
1.0816
1.0985
.1057
.1111
.1219
.1246
.1283
.1400
.1505
.1563
0.9005
0.9061
0.9128
0.9205
0.9386
0.9492
1.0006
1.0220
1.0376
1.0428
1.0454
1.1099
1.1256
1.1302
0.9474
0.9915
1.0004
1.0005
1.0191
1.0004
1.0105
0.9604
0.9829
0.9896
1.0007
1.0096
1.0235
1.0330
1.0455
1.0816
1.0984
1.1058
1.1111
1.1219
1.1249
1.1283
1.1399
1.1566
0.9005
0.9133
0.9206
0.9387
0.9492
1.0005
1.0219
1.0377
1.0429
1.0454
1.1103
1.1256
1.1301
0.9473
0.9916
1.0005
1.0005
1.0191
1.0004
Analytical Perspectives
Page 5 of 5
Diff




Checkcode:
W
Sees
Response
Ra
RRF
Cone
Noise
DL

O.OOE+OO

1.16

2.52E+03
3
-1.0
3.16E+06
1.23
1.24
342
2.52E+03
2.8
0
7.34E+05
1.19
0.90
110
2.52E+03
3.88
+0.4
6.55E+05
1.32
0.78
112
2.52E+03
4 .44
-0.2
5.29E+05
1.33
0.89
79.5
2.52E+03
3.9
0
8.64E+05
1.38
1.14
102
2.52E+03
3.05
-0.6
4.55E+06
1.24
0.95
644
2.52E+03
3 .67

0.00E+00

1.09

2.52E+03
3.19
+0.2
1.82E+06
1.32
1.21
203
2.52E+03
2.89
+0.6
8.42E+05
1.24
0.85
129
3,79E+03
6.2
0
3-61E+Q5
1.12
0.95
49.3
3.79E+03
5.53
0
5.95E+05
1.18
0.95
81.4
3.79E+03
5.54
0
2.08E+05
0.98
1.00
21.8
3.01E+03
3.07
-0.2
9.26E+05
1.05
0.87
112
3.01E+03
3.52
-0.2
2.97E+05
1.01
0.84
37.4
3.01E+03
3.68
-0.2
8.55E+05
1.02
0.90
99.9
3 .01E+03
3.42
+0.4
1.02E+05
1.12
0.86
12.4
3 .01E+03
3 .56
0
3.72E+05
1.08
0. 64
60.9
3.01E+03
4.79
-0.2
3.84E+05
1.03
0.88
62 .9
2.81E+03
5.05
+0.2
1.37E+06
1.06
0. 90
221
2.81E+03
4.96
0
2 .67E+05
1.11
0. 93
41.4
2.81E+03
4.77
0
9.48E+05
0.95
0.92
148
2.81E+03
4.8
+0.6
1.44E+05

0.85
24 .4
2.81E+03
5.23
0
1.17E+06
1.07
0. 86
195
2.81E+03
5.14
-0.2
7.17E+05
1.04
0.85
122
2.81E+03
5.23

O.OOE+OO

0. 88

2.81E+03
5.06
+0.7
1.15E+06
1.10
0.79
210
2.81E+03
5.61
0
4.47E+05
1.02
0.79
81.4
2.81E+03
5.61

0.00E+00

1.02

2.81E+03
4.36
+1.1
2.24E+06
1.06
0.97
335
2.81E+03
4.6
+0.2
7.08E+05
1.04
1.10
93.1
2.81E+03
4.05
+0.2
1.28E+06
1.11
1,17
189
2.81E+03
4.8
0
7.67E+05
1.12
1.39
95.1
2.81E+03
4.05
-0.2
3.25E+05
0.93
0.95
42.9
2.64E+03
3.62
-0.2
8.25E+05
0.84
0.89
116
2.64E+03
3.84
+0.2
2.14E+05
0.90
0.84
31.9
2.64E+03
4.08
+0.2
8.38E+05
0.91
0.86
121
2.64E+03
3.96
0
6.37E+05
0.91
0. 89
89.9
2.64E+03
3. 87
+1.0
9.71E+05
0.95
0.63
193
2.64E+03
5.45
0
1.28E+06
0.82
0. 63
253
2. 64E+03
5.42
-0.2
5.71E+05
1.00
0.71
101
2.64E+03
4.85
-0.2
5.25E+05
0.88
0. 76
110
2. 28E+03
5. 81
+0.3
7.40E+05
0.91
0.82
146
2.28E+03
5.43
+0.3
3.82E+05
0.93
1.06
58
2.28E+03
4.19
0
5.87E+05
0.80
1.00
103
3 .44E+03
6.35
0
1.09E+06
0.76
1.00
191
3.44E+03
6.35
0
7.99E+05
0.85
1.11
173
3.44E+03
8.55
Printed: 08 06 2008 1:20 PM
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
QC CHECK UNEQUMHIB)
Sample ID: Run# I-ACD-M23-2	Acq: 24-Jul-2008 05:44:48
VSIR expt: pcb0405_c!1-10_mm6 GC: pcbx100_a Vial: 61	User: JLJ Datafile: 080724V07_EQ
Rel. Int.
Fn 1 100%
218.9856
QC ^non-EQ)
9.03-13.00
ReL Int.
Fn 2 100%-,
242.98S6
QC (non-EQ)
13,02*17.79
Abs. Int
9.2Se7
4.62S7
O.OOeO
13,0 RT
Abs, In!
5.45e7
2,7267
O.OOeO
|—t—i—i—i—|—(—i—p—r-|—i—i—(—p—|
ReL Int.
Fn 3 100%.
292.9824
QC (non-EQ)
17,81-23.26
0%.
I
18.0
—I—
19.0

I
20.0
I I t I I I I E I I I I ! E r I I
21.0	22.0
23.0
Abs. Int.
-5.74eT
•2.87e7
¦O.OOeO
RT
Rel. Int.
Fn 4 100%-,
330.9792
QC (non-EQ) :
23.27-34.14
0%.
I t I T I V
24.0
	I	i	i	i	
26.0
~v-
v~"
28.0
30.0
32.0
Abs. Int.
-5.08e7
• 2.54e7
¦ O.OOeO
34.0 RT
Rel. Int.
Fn 5 100%.
366.9792
QC (non-EQ) .
34.16-41.15
0%.
' I '
35.0
-\y~-
36.0
37.0
' I ' ' '
38.0
I ¦ 1 ' ' I 1
39.0
T—i-1
40.0
Abs. Int.
-1.06o7
-5.30e6
-O.OOeO
41.0 RT
Rel. Int.
Fn 6 100%.
454.9726
QC (non-EQ)
41.17-46.41
0%.
42.0
I I t
—I—
43.0
—]	1	1	1	1	1	1	1—r-
44.0
I
45.0
-i	1	1—
46.0
Abs. Int.
-1.70e7
-8.49e6
f 0. OOeO
RT
Rel. Int.
Fn 7 100%.
454.9728
QC (non-EQ)
46.42-54.01
0%-
-1—I—I—|—r
47,0
I » I | I I f » |
48.0
i | i i i i | i i i i i1 i > i
49.0	50,0
51.0
52.0
Results: P:\P9400_P949B\P9464_6042 PCB\msotneeslP9464_6042__PGB_QQ3Mtp__r&$, saved 24-Juf-2008 13:49 (EE)
AP UttraTrace-Pm V3.993 User/System EEJEEC2-038 see: 070-785
	I""'
53.0
Abs. Int.
-2.07e7
¦ 1.04e7
-0.0080
54.0 RT
Peak annotation: Areas. Centroids
PKD: n/a Printed: 05-Atig-200B 08:28:24 Page 1 of 22
-------
AP Lab ID: P9464_6042_PCB_003
Instr AutoSpec-Premier MM6
QC CHECK EQUALIZED
Sample ID: Run# l-ACD-M23-2 PRIOR TO PROCESSING
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx1Q0_a Vial: 61
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07_EQ
Fn 1
Rel. Int.
100%.
218.9856
QC Check
9.03-13.00
0%.
T"'
9.5
10.0
10.5
11.0
' I 1
11.5
12.0
1 I r
12.5
Abs. Int.
-9.41e7
¦4.70e7
¦ O.OOeO
13.0 RT
Fn 2
Rel. Int.
100%.
242.9856
QC Check
13.02-17.79
0%-
—J—i—i—l—i—| l l—I—r—]—i—i—i i | i—i t i—p
13.5	14.0
14.5
1S.0
' I '
15.5
16.0
16.5
17.0
17.5
Abs. Int.
-5.41e7
•2.70e7
•O.OOeO
RT
Rel. Int.
Fn 3 100%.
292.9824
QC Check
17.81-23.26
0%.
18.0
19.0
I i i i i I i i i~
20.0
21.0
	1	1	1	,	>—1~
22.0
Abs. Int.
• 5 62e7
• 2.81e7
—,—|—,—r-t. O.OOeO
23.0	RT
Rel. Int.
Fn 4 100%-
330.9792 ;
QC Check
23.27-34.14 ~-
0%.
24.0
->—r
26.0
I
28.0
30.0
32.0
Abs. Int.
•5.25e7
-2.62e7
•O.OOeO
34.0 RT
Rel. Int.
Fn 5 100%.
454.9726
QC Check
34.16-41.15
0%.
i—|—i—i—i—i—f—
35.0
36.0
1 I ' ' ' ' I
37.0
38.0
39.0
40.0
Abs. Int.
-2.31e7
¦ 1.16e7
¦,—|—r-I-OOOeO
41.0 RT
Rel. Int.
Fn 6 100%.
404,9760
QC Check
41.17-46.41
0%-
->	'	'	1—
42.0
T	'	'—'—'—I—>~
43.0
I I I
44.0
| i r r t |
45.0
i i |
46.0
Abs. Int.
-2 05e7
• 1.02e7
-O.OOeO
RT
Rel. Int.
Fn 7 100%-
454,9728
QC Check
46.42-54.01
0%-
1 I 1 1 1 1 I
47.0
| r
48.0
1 1 1 '
T~"~T r
49.0
fiii*
50.0
51.0	52,0
' I '
53.0
Abs. Int.
-2.05e7
¦ 1.03e7
• O.OOeO
54.0 RT
Results: P:\P940Q_P9499\P9464_6042 PCBSresources\P9464_6042_PCB_003.utp_res, saved 24-Jut-2Q08 13:49 (EE)
AP UftraTrsce-Pm i/3.993 User/System: EE/EEC2-Q38
Peak annotation: Areas. Centmids
PKD: n/a Printed: 05-Aug~2008 08:28:25 Page 2 of 22
-------
AP Lab ID: P9464 J042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int,
100%-
Fn 1
188.0393
MoCB
4o 6.29e3
9.03-13,00
0%-
Rel. Int.
100%-
Fn 1
190.0363
MoCB
4o 5.50e3
9.03-13.00
0%-
PCB-1
2.5Se7
9.48
9.5
PCB-1
8 30e6
9.48
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
PCB-2
98167 pcB-3
11-27 8,79e7
11.43
10.0
10.5
V I | I 1 t I | I 1
11,0
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07_EQ
Abs, Int.
3.93e7
1.97e7
12.0
PCB-2
31172877 PCB"3
112.85e7
11.43
T
10.0
,Mi	i	i	\	i	i	i	r-
10.5
I ¦ ' * ¦ I • ¦ •
11.0
11.5
"¦¦r	r	r	t	|	r1
12.0
12.5
12.5
-O.OOeO
13.0RT
Abs. Int
1.29e?
•6,44e6
-O.OOeO
13.0 RT
Rel. Int
100%-
Fn 1
200.0795
MoCBStd, .
4a 1.27e4
9.03-13.00
0%-
Rel. Int.
100%.
Fn 1
202.0766
MoCB Std,
4o 6.26e4
9.03-13.00
ES-3
3.59e7
11.42
I t [ t I I f I | I -T	%	1	|	|	|	V" f |	1-
9-5	10.0
10,5
11,0
I i	t *" [ i i i"" i j i i i » | »
11.5	12.0
6.10eS
10.32
2.50e5
11.15
10.0
1 1 1 1 I |
10.5
2.96e5
11.62
12.5
11,0
—t	1	J I 1 "I I | ! I I I | I I T f | *
11,5	12.0
12.5
Abs. Int.
-1.57e7
¦7,84e6
-i—|—i—i—i—i—0 .OOeO
13.0RT
Abs, Int.
-5.17e6
•2.58e6
-O.OOeO
13.0RT
Rel. Int.
100%-,
Fn 1
218.9856
QC Check
9.03-13.00
12.5
Abs. Int.
-9.41e7
4.70e7
O.OOeO
13.0RT
Results: P:\P9400_P9499\P9464_6042 PCB \nesairrcesIP9464_6042_PC8_003. utp_res, saved 24-M-2008 13:49 (££}
AP Ultra Trace-Pro V3.S93 User/System: EE/EEC2-038 cc: 3532. 9048
Paak annotation: Areas. Centroiste-
Revised: 24-M-2008 13:37:34 (EES Printed: 05-Aug-2008 08:28:26 Page 3 oUS
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Prernier MM6
Rel. Int.
100%
Fn 1
222.0003
DiCB-1
4a 7.16e3
9.03-13.00
Rel. Int.
100%
Fn 1
223.9974
DiCB-1
4o2 78e4
9,03-13.00
Rel. Int.
100%-
Fn 1
234.0406
DiCB Std.
4o 1 03e4
9.03-13.00
0%-
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb04Q5_cl1-10_mm6 GC: pcbx100_a Vial: 61
PCB-4
2-7Se6
11.68
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
Abs. Int.
-9.24e5
PCB-10
7.54eS
11.83
PCB-4
i.96ee
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std.
40 1 00e4
9.03-13,00
0%-
Rsl. Int.
100%-T-
Fn 1
218.9856
QC Check
9.03-13.00 ¦
ES-4
2.04e7
11,66
-4.62e5
O.OOeO
13.0RT
Abs. Int.
6.68e5
3.34e5
O.OOeO
J3.0RT
Abs. Int.
5 99e6
3.00e6
I | I I
9.5
11 I ¦
10.0
10.5
—|—l—l—l—l—J—l1 1 c i—i—|—r—f—i , j—(—i—i—r-j—r-
11.0	11.5	12.0
ES-4
i i i i i i i i i i i i i i i *
12.5
13
—i—|—i—r-
9.5
10.0
10.5
11.0
1 I '
11.5
12,0
12,5
-O.OOeO
ORT
Abs. Int.
-3.90e6
•1.95e6

—r—i—i—i—j— 0. OOeO
13.0RT
Abs. Int.
		r9-41e7
-4.70e7
0%-
"T
»	j	y	r1"
9.5
"™1—'—i—i—i—|—i—»—i—i—|—i—i—i—'—j—i i i—i—j—r-
10.0	10.5
11.0
T
-I—f—I—I—1-1—|—I—I—I—I—|—r—I—I I |—I I I—i—|—r
11.5	12.0	12.5
Results: P:\P9400_P9499\P9464_6042 PC8\resources^P9464_6042_PCB_003.utp_res, saved 24-Jut~2008 13:49 (EE)
AP UltmTmce-Pm V3 993 User/System: EE/EEC2-038 cc: 0493, 0298
i i i i i 0. OOeO
13.0RT
Peak annotation: Areas, Centrotds
Revised: 24-Jul-2008 13 37 56 (EE} Printed: 05-Aug-200e 08 2d 27 Page 4 qf72
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Ret. Int.
100%-
Fn 2
222.0003
DiCB-2
4o 6.74e3
13.07-17.79
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl 1 -10_rnm6 GC: pcbx100_a Vial: 61
0%-
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4o 2 54e4
13.07-17.79
0%-
PCB-13/12
5.61e7
16.57
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
Abs. Int.
-1.22e7
PCB-9
I\02e6 a
\3.64 A

13.5





PCB-11 A
2-87e7 \
16a9 /


PCB-5
5.69e6/\
,aA ,


PCB-14
1.08e7
15.56

lii
PCB-15
1.17e7
16.83

¦ i ' i
14.0
14.5
15.0
15.5
16.0
16.5
17.0
i • ' • ' i «
17,5
PCB-11
I,86e7
16.29
PCB-13M2
3.68e7
16.56
PCB-9
3.09e6
13.40 /%56®5
PCB-5
3.74e6
14.03
PCB-14
7.12e6
15.56
13.5
14.0
'' I
14.5
15.0
15.5
i | i
16.0
PCB-15
7.77e6
16.83
¦6,08e6
-O.OOeO
RT
Abs. Int.
-8.09e6
-4.04e6
i i i l i i
t
17.5
i i i i I
• O.OOeO
RT
Rel. Int.
100%-
Fn 2
234.0406
OiCB Std.
4o 1,85e4
13.07-17.79
0%-
14.0
¦ i ¦
14,5
15.0
15.5
16.0
16.5
17.0
17.5
Abs. Int.
-1.15e7
5.77e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
236.0376
DiCB Std.
4o 7.36e3
13 07-17 79
0%-
14.0
ESytS
zMm
16,82
14.5
15.0
15.5
16.0
16,5
17,0
Abs. Int.
-7.17e6
•3.58e6
O.OOeO
• i • ¦ ¦ ¦ I
17.5	RT
Rel, Int.
100%
Fn 2
242.9856
QC Check
13.07-17.79
Abs. Int.
5 41e7
2.70e7
O.OOeO
Results: P:V»}400_P9499\P9464_6G42 PC8\resources\P9464_6042_PCB_003 utp res. saved 24-M-2008 13:49 (EE}
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 0921. 8546
16.0	16.5 ''''''' '17' Q	17.5	RT
Peak annotation: Areas, Centmios
Revised: 24-Jut-20Q8 13:38:39 (EE) Printed: OS-Aug-2008 06:28 29 Page S4t 22
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 2
255-9613
TrCB-2
4o3 05e3
13,02-17.79
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 61
0%.
PCB-19
8.95e5
14.41
OX
13.5
14.0
T—'—t—i—i—|—i—i—rn—|—r-
14.5	15.0
15.5
Rel. Int.
100%-
Fn 2
257.9584
TrCB-2
4a 3.24e3
13.02-17.79
Q%-
1 1 ' 1 ' I '
13.5
PCB-19
8.84eS
14.41
14.0
r1-
14.5
15.0
M"i	i		r-
15.5
PCB-30/18
6,0166
16.03
PCB-17
3.08E6
16.39
PCB-30/18
5.79e6
18.03
PCB-17
2.91 e6
16,38
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
Abs. Int.
r 1 86e6
PCB-16
2,15e6
PCB-27 16.79
9,Q6e5
18.58
16.5
PCB-16
PCB-27 ™7#
9 04e5 6 S
16.58
17.0
	'	I	'	
17.5
PCB-32
3.27ee
16.5
1 I I I I T 'l [
17.0
17.5
Rel. Int.
100%-
Fn 2
268.0016
TrCB Std.
4o 4.99e4
13.02-17.79
0%-
ES-19
1.6ie7
14.39
5.82e6
13.46
3.94eS
17.08
A,
Rel. Int.
100%-
Fn 2
269.9986
TrCB Std,
4ct 5.87e4
13.02-17.79
0%-
ES^IS
1«3e7
14.39
6.61eS
13.45
13.5
7,i0e5
17.08
14.0
	I i i i i	)	i i "i I |	
14.5
15.0
i I i i i
15.5
9.30e5
-O.OOeO
RT
Abs. Int.
-I81e6
¦9.03e5
iij ii^r i ijn , t , | . , i i |			 v'! ¦; |' r'i i i-0^1 ri	i	| 				| i 		i" t* i	jni i i i j '"i 	j'"(	>¦ t 'f[ 'f f yp [''i i \r r	jO1 ii r 1 'i i1 i i
13-5	14.0	>4.5	15.0	15.5	16.0	16.5	17.0	17.5
-O.OOeO
RT
Abs. Int.
-5 33e6
2.66e6
I 1 I I 1" I |I "I	I »	T			 ¦ I ¦ I I" "I	|	f> I	["""|	I I I I | 'I	
16.0	16.5	17.0	17.5
-OOOeO
RT
Abs. Int.
-5,20e6
2.60e6
O.OOeO
RT
Rel. Int.
100%-
Fn 2 :
242.9856 -
QC Check "
13.02-17.791
Abs. Int.
-5.41 e7
-2 70e7
0%-
13.5
| 1 r i	r'"f	rm
14.0
1 | l
14.5
' I ' 1 1 1 I ' 1 ' ' I
15.0
' I ' ' ' 1 I
15.5
Results: P:\P9400_P9499\P9464_6042 PC8Vesouiv0s\P9464_6O42_PCB_SQ3,utp_ms, saved 24-Jut-200& 13:49 (EE)
AP UltraTrace-Pru V3.993 User/System EE&EC2-C38 cc: 0261, 2066
16,0
' I ¦
16.5
O.OOeO
17.0
17.5	RT
Peak annotatbn: Areas. Cenirolds
Revised: 24~Jul-2008 13:39:03 (EE) Printed: QS-Aug-2008 08:28:30 Page 6ofJj!i2
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%.
Fn 3
255.9613
TrCB-3
4o 3 74e3
17.81-23.26
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
0%-
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
4o 5.20e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
268.0016
TrCB Std.
4o 4.89e4
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
40 3.52e4
17.81-23.26
G%-
18.0
.1
18.0
18,0
18.0
PCB-34
8.31e5
18.31
PCB-26/2».r ,5
18.71
18.90

AA
19.0
PCB-34
8.13e5
18.31
¦^v
PCB-2&ICB-25
4.36663.2486
18.71 18.90
A A
19.0
19 0
PCB-28/20
1.48e7
19.43
PGB-31
8,79e6
PCB-21/33
19.17
8.68e6
PCB-28/20
1.4467
18.43
PCB-31
6.44e6
PCB-21/33
35e6
19.62
2 59e7
19.40
PCB-35 PCB-37
1 22e7 1.2567
22.47 22.82
PCB-22
5.37C6
18.86
A.,,
PCB-36
3.12e6
21.28
A
PCB-39
2.80e6
21.59
A
PCB-38
3.25e6
22.08
^ A
20.0
I		 ' ,T"
21.0
i ¦ i '
22.0
23.0
PCB-22
6.25e6
19.96
PCB-36
3.07e6
21.28
PCB-39
2.68e6
21.59
PCB-38
3.00e6
22.08
20.0
I—I—.
21.0
	1 A I	r^-
T—.	j*
22.0
6.96e5
19.80
T ¦ i 1 >'1 ' i i <1
20.0
4.43e6
20.81
/\
i|»
21.0
22.0
19.0
SS-28
2,45e7
PCB-37
\20g 1.21e7
22.47 22.82
23.0
Abs. Int.
-3.82e6
¦1.91e6
-O.OOeO
RT
Abs. Int.
-3 84e6
1 92e6
-O.OOeO
RT
Abs. Int.
-7.54e6
• 3.77e6
S"^| ¦ > ¦»O.OOeO
23.0 RT
Abs. Int.
6 81e6
•3.41e6
20.0
21.0
22 0
23.0
-O.OOeO
RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P\P9400_P9499\P9464_6042 PC8Vesourc9s\P9464_6042_PCB_003Mtp_n>s, saved 24-Jul-2008 13:49 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 2102, 0239
21.0
22.0
23.0
Abs. Int.
-5 62e?
2.81e7
-O.OOeO
RT
Peak annotation: Areas, Centroids
Revised: 24-Ju)-2008 13:40:05 (BE) Printed: 0S-Aug-2008 08:28:31 Page 7 00.2
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int.
¦ 100%-
Fn 2
289.9224
TeCB-2
4o 1.27e3
13.02-17.79
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx10G_a Vial: 61
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07_EQ
Abs. Int.
- 1.57e4
•7.87e3

PC8-54
4.34e4
13.5
14.0
14.5
15.0
15,5
16.0
16.5
17.0
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o 1,90e3
13.02-17.79
Rel. Int.
100%
Fn 2
301.9626
TeCB Std.
40 6.22e3
13.02-17.79
Rel. Int.
100%-
Fn 2
303.9597
TeCB Std.
4o 4.27e3
13.02-17.79
17.5
-O.OOeO
RT
Abs. Int.
-IJ1e4
-9 57e3
T—O.OOeO
RT
Abs. Int.
-4.15e6
PCB-54
4.88e4
ES-54
1.49e7
17.08
ES-54
2.08e6
O.OOeO
Abs. Int.
-5 62e6
2.81 e6
O.OOeO
Rel. Int.
100%
Fn 2
242 9856
QC Check
13.02-17.79
Abs. Int.
-5.41e7
-2.70e7
O.OOeO
Results: P:\P9400_P9499\P94B4_6042 PCBVesources\P9464_6042_PCB_003.utp_res. saved 24-Jul-2008 13:49 (EE)
AP UltraTmce-Pro V3.993 User/System: EE/EEC2-038 cc. 7848, 2837
16.0	16.5	17.0	17.5	,,,
Peak annotation: Areas, Centmjds
Revised: 24-Jut-2008 13:40:15 (EE) Printed 05-Aug-2008 06 28 32 Page 8gf22
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 3
289-9224
TeCB-3
4o1.37e3
17.81-23.26
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_c! 1-10_mm6 GC: pcbx100_a Vial: 61
0%-
Rel. Int.
100%-
Fn 3
291,9194
TeCB-3
4o2.27e3
17 81-23.26
0%-
PCB-44M7/65
I.l6e7
21.85
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafiie: 080724V07_EQ
Abs. Int.
-2.59e6
PCB-50/53
6.81 e5
18.93
PCB-45
6.41e '
19.£
18.0
19.0
i

PCB-52

3.46eB

20.98
PCB-46
A
2.51e5
/ \
19.77
/ V
i *"» t | . i . i
r » « » i i '
20.0
21.0
PCB-69M9
21 39 PCB-48
8.69e5
21,63
53,?7
4.73e5 2Z/f7
22JA A
220
PCB-44/47/65
1.48e7
21.85
23,0
PCB-50/53
8,73e5
18.94
, r*,
18.0
19.0
PCB-46
3.36e5
19.77
PCB-52
4.48e6
20.98
PCB-69/49
3,49e6 _
21 39 PCB-48
1.11e6
21.63
£. 1
A
PC8-64
as?
, Mrs A
20.0
21.0
22.0
1—1
23.0
¦1.30e6
-O.OOeO
RT
Abs. Int.
-3.31e6
1.65e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
301.9626
TeCB Std,
4a 5.73e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
303.9597
TeCB Std
4a 3 85e3
17.81-23,26
0%-
18,0
19.0
20.0
1—I—'
18,0
19.0
22.0
23.0
Abs. Int.
-3.89e6
1 95e6
-O.OOeO
RT
Abs. Int.
-4.95e6
•2.48e6
20.0
21.0
22.0
-i—j—i—i—-OOOeO
23.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P:\P9400_P9499\P9464_6042 PCB\resoun:es\P9464_6042_PC8_003Mtp_ms, saved 24-Jut-2008 13:49 (EE)
AP UllraTrace-Pm V3.993 user/System: EE&EC2-03B cc: 8552. 3660
Abs, Int.
5.62e7
2,81e7
i i i I-" t¦¦ | t i i i [ i i " O.OOeO
22.0	23.0	RT
Pea* annotation: Areas, Centmms
Revised: 24-Jul-200B 13:41:10 (EE} Printed: 05-Aug-2008 08:28:33 Page 9/1/22
-------
AP Lab ID: P9464_6042_PCBJ)03
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-j
PCB-68
5.48e6
Fn 4
23.82
289.9224 •


TeCB-4


4a 2.62e3 .


23.27-33.00 •
PC8-72
3.71e5|
6

23.57 /
£
U-
o%J
I,	,-a-,4
PC B-61/70/74/76
7.72eB
25.03
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx10Q_a Vial: 61
/
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4a 4.96e3
23.27-33.00
0%-
24.0
PCB-68
6.99e6
23.82
PCB-56
3,43e6
25.85
"C8-60
47fM^CB-B0
¦6'044.96e5
26.37
./> . .
PCB-77
7.33e6
28.96
PCB-79
2278656 PC-I^CB-ai
is # 1 17e€
2811 28.49

Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
Abs. Int.
-1,73e6
26.0
27.0
— ¦ • 40.
A i\.
28.0
-8.67eS
PCB-72
5.24e5
23.57
PCB-61/70/74/76
1.0le7
25.03
29.0
PCB-77
9.67e6
28.96
30.0
31.0
32.0
PCB-56
4,43e6
~r
PCB-5®7
7.95e5 74 «
24.17 n '
M\ A
24.0
Rel. Int.
100%-
Fn4
301.9626
TeCB Std.
4o 5.22e3
23.27-33.00
0%-
24.0
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
4o 2.76e3
23.27-33.00
0%-
24,0
B-60
88e&>cB-80
¦°i036.01e5
A ,y,.
PCB-79
3,32e6
27.65
26 0
~~rT~r_
27.0
PCB-78PCB-81
1,69e6 1.5406
28.12 28 49
X4-
-O.OOeO
RT
Abs. Int.
-2.32e6
-1.16e6
28.0
ES-81
1.88e7
28.47
A
' ' l^~
29.0
ES-77
1.9607
28.94
30,0
25.0
26.0
27.0
' I '
28.0
JwJ
i i i i i i t i i i i i i i i—|-i—i—i—r-*-O.OOeO
31,0	32.0	RT
Abs. Int.
4,61e6
2.31e6
l *» ¦ i i > i i i
29.0
' I '
30.0
T
31.0
32.0
25.0
26.0
6 07e5
26.35
T
27.0
28.0
ES-81
235e7
fS.47
IX
esjt"
2.4087
28.94
•O.OOeO
RT
Abs. Int.
r5.71e6
¦2,85e6
29,0
30.0
T | ¦ ' ' |
31.0
32,0
-O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23 27-33 00
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_003.utp_ms, saved 24-Jut-200a 13:49 (EE)
AP UltraTmce-Pm ¥3.993 User/System E&EEC2-038 cc: 9590. 0458
T-r-p
32.0
Abs, Int.
5.25e7
-2.62e7
[)
-------
AP Lab ID: P9464_6042_PC8_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%
Fn 3
323.8834
PeCB-3
4o 2 06e3
17.81-23.26
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
4c 1.19e3
17.81-23.26
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
PCB-96
7.20e4
22.09
PCB-104
3.16e4
21.78
PC 8-96
1.3065
22.10
PCB-104
3.88e4
21.78
Acq: 24-Jul-2008 05:44:48
User JLJ Datafile: 080724V07_EQ
Abs. Int.
-2.36e4
1.18e4
O.OOeO
RT
Abs. Int.
-4.20e4
22.0
¦2.10e4
, 0.OOeO
23.0 RT
Rel. Int.
100%-
Fn 3
337.9207
PeCB Std.
4o2.01e3
17.81-2326
Q%-
18.0
19.0
-i	1—i—r-
i	,	1	1	r-
20.0
T * | f I I f |
21.0
22.0
23.0
Abs. Int.
-5.74e6
•2.87e6
•O.OOeO
RT
Rel. Int.
100%-,
Fn 3
339.9177
PeCB Std. j
4c 3.68e3
17.81-23.26
0%-
18.0
19.0
1—r->—1—'—I—1
20.0
21.0
22.0
23.0
Abs. Int.
-3.66e6
183e6
O.OOeO
RT
Rel. Int.
100%-
Fn 3	:
292.9824 -
QC Check '
17.81-23.261
20.0
Results: P:\P94O0_P9499\P9464_6O42 PCB\resources\P9464_6042_PCB_003.up_ms, saved 24-JuI~2008 73.49 (EE)
AP Ultra Trace-Pro V3.9S3 User/System: EE/EEC2-038 cc: 8654. 2813
21.0
22.0
23.0
Abs. Int.
62e7
-2.81e7
-O.OOeO
RT
Peak annotation: Areas, Centroi&r
Revised: 24-JUI-200S 13:42 33 (EE) Printed: 05-Aug-200B 08:28:35 Page 11 otfi2
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int.
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
Fn 4
pcB-gs
1.37o6
323.8834
24.29
PeCB-4
A
4o 3.78e3
1L
23.27-34 14 •
PffiB-100/SPCB-88
i11e5 4,62e4

/ 24.48 24.98
0%-
I-,- , , —>-
32.0
1 98e6
100/^CB-88
°7.®5 5,63g4
14.48 „
24.0
24.0
24.0
PCB-89
I.08e5
25.60
PCB 110
PCB-113/90/101	3 1966
2.93e6	28 40
26,75 PCB-108/119/86/97/
3 40e6
PCB-99 27.67
1 30e6
PCB-92 PCp
4.S9eS	g 11
26.26	27.1
PCB-118
3.41 e6
30.90
-b-J-
i.
26.0
PCB-11
1.71
28
PCB-82
715 56e5
28.67
_A
PCB-120
3 88e5
29.38
A
28.0
PCB-12
PCB-114
4.64e5
PCB-105
2,77e6
31.88
A
I—T—.—r-
32.0
js-101
1 92e7
26.73
SS-111
2.68e7
28.97
ES-123
2.20e7
30.60
ES-114
2.24e7
31.32
ES-105
2 3Se7
31.86
26.0
28.0
|*l 1 I t | 1 1 ' I
30.0
v-4
6Se7
SS-
28.97
26.0
JS-10
28.0
I | ! I I
30.0
ES-123 ES-11>-- ¦) 53air
1.3M7 / SAW 31 flg
3CT60 ' 31.32 .
UU
i—,
32.0
PCB-127
3.59e5
33.10
k
T
PCB-127
5.73e5
33.10
A-
f	t i t t |'
32.0
ES-105^
Abs. Int.
-5,10e5
2 55e5
¦ O.OOeO
34.0 RT
Abs. Int.
-8.12e5
¦4.06e5
•O.OOeO
34,0 RT
Abs. Int.
6.57e6
¦3.29e6
O.OOeO
t ' T 1' |
34.0 RT
Abs. Int.
-4.28e6
¦2.1406
O.OOeO
-I	f J""" *	? ~
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23 27-34 14
24.0
26.0
28.0
30.0
32.0
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_003 utp_res. saved 24-Jul-2008 13:49 (EE)
AP IMraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 2210, 1525
Abs. Int.
5 25e7
2.62e7
f—¦-O.OOeO
34.0 RT
Peak annotation: Areas, Centmids
Revised: 24-jul-20oe 13:44:58 (EES Printed: 0S-Avg-2008 08:28:37 Page 12 of42
-------
AP Lab 10: P9464 6042 PCB003
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
Rei. Int.
100%-,
Fn 5
323.8834
PeCB-5
4o 2.90e3
34.16-41.15
0%-
PCB-126
2.29e6
34.45
-A-
' I 1
35.0

36.0
37.0
-i—|—i—i—i—i—|——i—i—|—i—r-
39.0
40.0
Abs. Int.
-4.71e6
2 36e6
[ i i i i j ¦ i O.OOeP
41.0 RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4o 2.96e3
34.16-41.15
0%-
Rel. Int.
100%-
Fn 5
337.9207
PeCBStd.
4o8.18e3
34.16-41.15
0%-
PCB-126
3.80e6
34.45

ES-126
2.44e7
34.43
A
' i V i
ES-128
Rel. Int.
100%-, V*2
Fn 5
339.8177
PeCBStd.
4o 4 76e3
34,16-41.15
0%-
35.0
35.0
35.0
I | T t t I
36.0

37.0
7.88e5
36.95

38.0
39,0
40.0
1 "1 '
36,0
37.0
38.0
390
40.0
'	T	¦	
36.0
-I—J—r
37.0
38.0
39.0
3.35e5
38.62
I		
40,0
Abs, Int.
-1.09e7
•5.45e6
I i i ¦ i [ i O.OOeO
41.0 RT
Abs. Int.
-5.66e6
-2.83e6
rJ-O.OOeO
41.0 RT
Abs. Int.
-3.64e6
¦1.82e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454,9728
QC Check
34.16-41.15'
Q%-
t t r r
'"1	1	1	Tm
35.0
36.0
' t '
37.0
38.0
39,0
Results: P:\P9400_P9499\P94S4_6042 PC8esauFces\P9464_6042_PCB_003.utp_m$. Saved 24-Jul-2008 13:49 (EE)
AP UltmTmce-Pm V3.993 User/System: EEJEEC2-038 cc: 1204, 9759
40.0
Abs. Int.
-2.31e7
1.16e7
41.0
•O.OOeO
RT
Peak annotation: Areas, Centroitter
Revised: 24-Jut-2006 13:45:08 (EE) Printed: 05-Aug-2008 08:28:38 Page 13 of/2
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel Int.
100%-
Fn 4
359.8415
HxCB-4
4o 1.38e3
23.27-34.14
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07_EQ
0%-
Rel. Int.
100%
Fn 4
361.6385
HxCB-4
40 1.14e3
23.27-34.14
0%-
Rel. Int.
100%-
Fn 4
371.8817
HxCBStd.
4a 1,57e3
23,27-34.14
0%-
Rel. Int.
100%-
Fn 4
373.8788
HxCB Std.
4o 2.04e3
23.27-34.14
0%-
PCB-147/149
1.65e6
29.94
PCB-136
p£B*lf24270175
5.97e4
26 73
te* a
ft. A
PCB-151/135
8.22e5 prB-14
PCf-1« 29 19 7^'
ys? A.29-65
24.0
26,0
28.0
PCB-132
7.6665
3.134PCB-13130-"
81 e5 2.0385

30.0
PCB-147/149
1.30eS
29.94
T
PCB-146
two tit 4,83e5
PCB-133 34 04
8.7264 J n
31.40 \
, C. .i r., I y\.
PC B-153068
1.74e6
32,46
B-141
PCB-137
3.02e5
PC B-163/138/120
2.52e6
33.50

Abs. Int.
-5 31e5
¦2.66e5
-O.OOeO
32.0
34 0 RT
PCB-136
3.78eS
PCB-152 27.17
3.96e4
26.7^
A
PCB-151/135
PCB-148 6292fa5
A J2llf

PCB-153/168
1.42e6
32.45
PCB-163/138/129
2,04e6
33.50
PCB-132
6.24e5
30 99
:B-134PCB-131 ¦ pro ««
40e5 1.61e5 J\ P6C|^3
,0.11
,30.61
Aa
31.40
24.0
26.0
28.0
30.0
PCB-146
3.93e5
31.94
F 'I;1!1 PCB-137
H34e5 22765
2.61 -ii'P

32.0
Abs. Int.
-4.09e5
¦2.04e5
ES-1S5
2.01e7
26.54
24.0
26.0
28.0
30.0
_l—,—(—,—,—^
32.0
ES-153
1.68e7
32.43
T-4-i
JS-138
1.55e7
33.47
-U-
- O.OOeO
RT
Abs. Int.
-4,94e6
•2.47e6
-T—O.OOeO
34.0 RT
ES-155
1.60e7
>154
ES-153
1.30e7^-
LA
JS-138 ,
1.20eZ^
3.*7
24.0
26.0
28.0
r | 1
30.0
1—I—1
32.0
Abs. Int.
-4.00e6
¦2,00e6
-O.OOeO
1—r
34 0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23,27-34.14
Results: P:\P9400__P9499\P9464_6042 PCB\Fesources\P9464_S042_PC8_003.utp_ms, saved 24.Jul-2008 13:49 (EE)
AP UltraTrace-Pro V3.993 Userhystem: EE/EEC2-038 cc: 0143, 7919
Abs. Int.
5.25e7
2,62e7
i O.OOeO
34.0 RT
Peak annotation: Areas. Centiptds
Revised: 24-Jtil-2008 13:47:00 (EES Printed: OS-Aug-2008 08:28:39 Page 1/6(22
-------
AP Lab ID; P9464,6042_PCB„003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fri 5
359.8415
HxCB-5
4o2.18e3
34.16-41.15
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
0%-
PCB-156/15?
uoes
36.95
PCB-128/166
4.67e5
34.55
PCB-162
" 2265
PCB-15|lf05
1.91e5 ,
A.
PCB-167
6,34e5
35.09
J
35.35
A
4.69e4
38.11
35.0
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4o 1 61e3
34.16-41.15
0%-
PCB-128/166
3.75e5
34.55
PCB-162
PCB-1S§-73e5
1 70ep5 60
35.38
36.0
PCB-167
4.89e5
35.99
Rel, Int.
100%-
Fn 5
371.8817
HxCBStd.
404 26e3
34.16-41,15
0%-
Rel. Int.
100%-
Fn 5
373.8788
HxCB Std.
4o 6.80e3
34.16-41.15
0%-
' V*r
350

A*.

36.0
PCB-156/157
1.49e6
36.95
38.0
39.0
2 53e4
39.14
PCB-169
5,04e5
39.64
Acq: 24-Ju1-2008 05:44:48
User: JLJ Datafile: 080724V07_EQ
Abs. Int.
r 3.55e5
• 1,77e5
40.0
37.0
ES-156/157
3.49e?
36.93
'T'"r l*">
3.47e4
36.10
38.0
2.9764
39.15
—!"=>!—r
PCB-169
3.95e5
39.63
A
39,0
40.0
ES-167
1 72e7
35.97
T [ r
35.0
"* I r-
35.0
36.0
ES-156/157
"1 '
38.0
' i *
39.0
~i—p—i—r~*i—i—|—i—i—i—r—|—r-
40.0
ES-169
1.30e7
1 i O.OOeO
41.0 RT
Abs, Int.
2.69e5
-1,34e5
O.OOeO
"r ¦ ' ¦ ¦ 'i
41.0 RT
Abs. Int.
-601e6
¦3.01 e6
¦. i ¦' O.OOeO
41.0 RT
Abs. Int.
r4,61e6
38.0
39.0
-2.31e6
	i1 't' j—i' * 't—r—|—i—t—t—i—|—r-1— O.OOeO
40.0	41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15'
0%-
35.0
36.0
' I 1
37.0
38,0
39.0
40.0
Abs. Int.
-2.31e7
-I.l6e7
1—r—O.OOeO
41.0 RT
Results: P:\P9400_P9499IP94B4_6042 PCBtesources\P9464_6042_PCB_003 utp_res. saved 24-Jul-2008 13 49 (EE)
AP UltraTmce-Pm V3.993 User/System: E&EEC2-03B cc 0123. 0289
Peak annotation: Areas, Centmids^
Revised: 24-Jul-2008 13:47:18 (EE) Printed: 05-Aug-2008 08:28:40 Page 15^2
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb04Q5_cl1-1Q_mm6 GC: pcbx100_a Vial: 61
Acq: 24-Jul-2O08 05:44:48
User: JLJ Datafile: 080724V07 EQ
Rel. Int.
100%-
Fn 4
393.8025
HpCB-4
4o 2.06e3
30.00-34.14
0%-
Rel. Int.
100%-
Fn 4
395,7995
HpCB-4
4o 9.51e2
30.00-34.14
30.5	31.0

31.5
PC B-188
1.05e5
31.33
PCB-176
4.31e5
PC8-184
1.50e5
32.05
PCB-176
4.23e5
32.35
PC B-184
1.48e5
32.05
PCB-186
5.38e4
32.74
32.5
33.0
0% i i n"t11 'i i i I jj l *1 i f t I* * I 1 f pi » V f | A I—I T pfTl llrj l—iVprtp	p ! 7
A 		 ,. , 	 			 ,.rrt	pf.T.TVp-fl O.OOeO
PCB-186
4,80e4
32.73
mjL.
PCB-178
1.93e5
33.87
¦,I '|" r"">' I ' I |"T I I 1
33.5	34.0
PCB-178
1.79e5
33.87
Abs. Int.
-1.31e5
¦6.57e4
-O.OOeO
RT
Abs. Int.
-1,14e5
5.68e4
30.5
31 0
31.5
32 0
32.5
33.0
33.5
34 0 RT
Rel. Int.
100%
Fn 4
405.8428
HpCBStd. J
40 3.07e3
30.00-34.14
0%-
¦¦¦>	¦!	i	i1	i	t	i	i	»	|	i	t	1	i	}¦	i	»	r	i	|	i ¦
30.5	31.0
SS-178
1.38e7
33.85
—i i 1 )—r—i—t—i—r-
-r—i—i—i—|—i—r—"i—»—i—i—i—i—i—!—r*
31.5
32.0
32.5
33.0
I V I I | I V I I
33.5
Abs. Int.
-5.04e6
•2.52e6
¦O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
407.8398
Hpcestd. •
40 2.58e3 -
30.00-34.14
ES-188
1.84e£<
31 v"
0%-
-i—i—i—i—i—i—i-i—i—i—i—i—i—i—f—i—f—i—i—I—i—i—i—i--!—f—r
-I—I—!—I I I I—1 ( I—I—*—I—I—i I I I P
SS-178
33.85
30.5
31.0
31,5
32,0
32.5
33 0
Abs. Int.
-4.51e6
•2,25e6
O.OOeO
33,5	34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
30.00-34.14
Abs. Int.
5.24e7
2 62e7
) i . O.OOeO
34.0 RT
Results: P:\P9400_P9499\P9464_6042 PCBVescurces\P9464_6042_PCB_003.tzfp_res, saved 24-Jul-2008 13:49 (££j
AP UllraTrace-Pro' V3.993 User/System: EE/EEC2-038 cc: 9509, 0005
Peak annotation: Areas, Centrods
Revised: 24-Jut-2008 13:47:49 (EE) Printed: 05-Aug-2008 08:28:41 Page 16 4! 22
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 61
Rel. Int.
100%-
Fn 5
393.8025
HpCB-5
4o 1 47e3
34.16-41.15
0%-
PCB-180/193
PCB-187
7,04e5
34.63
PCB-171/173
6.04«5
36.22
PCB-183
4.61e5
35
PCB-177
3.66e5
35.70
PCB-175
CB-182
1.40e5
34.79
1,95eS
34.40
PC B-172
2.2565
37.56
4.96e4
37.80
Q- ¦
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4o 1 33e3
34.16-41,15
0%-
PCB-187
6.67e5
34.63
35.0
PCB-183
4.87e5
35.13
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std.
40 3.94e3
34.16-41.15
0%-
PCB-175
CB-182
,27e5
34.79
1.89e5
34,40
36.0
PCB-171/173
5.49e5
PCB-177 3621
3.51e5
35.70
37.0
a:
1.15e6
38.09
PCB-181
3.61e5
38,40
38.0
PCB-180/193
1.09e6
38.09
PCB-170
6,76e5
33.15
PCB-190
4.05e5
39.59
Acq: 24-JuI-2Q08 05:44:48
User: JLJ Datafrle: 080724V07_EQ
Abs. Int.
-2.26e5
3.95e4
40,27
- T'^	 -f
36.0
37.0
PC B-172
2 22e5
37.56
A.

PCB-191
3.47e5
38.40
39.0
PCB-170
6.09e5
39.15
40.0
PCB-190
3.62e5
39.59
38.0
ES-180
1.44e7
38.09
35.0
36.0
37.0

39.0
3.0884
40.28
,'A*
40.0
38.0
ES-170
I.i8e7
39.13
imf	r	i	i	i	|	i"
40.0
-1.13e5
O.OOeO
11 I '
41.0 RT
Abs. Int.
-2.13e5
-1.06e5
-O.OOeO
41,0 RT
Abs. Int.
-3.29e6
¦ 1.64e6
• O.OOeO
"TTo RT
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std..
4o 3.00e3
34,16-41.15
0%-
-170 /
4 elX
ES-170
I.i4e7^
39, '
35.0
36,0
37.0
38.0
39.0
40.0
Abs. Int.
-2.91e6
¦ 1,45e6
41.0
-O.OOeO
RT
Rel, Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
35.0
36.0
37.0
38.0
• I '
39.0
' I 1
40.0
Abs, Int.
-2.31e7
¦I.l6e7
-O.OOeO
t
41.0 RT
Results: P:\P9400_P9499iP9464_6042 PC8\re$Ovme$\P9464_8042_PCB_003.ittp_re$. saved 24-Jul-2008 13:4S (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc; 8235, 2880
Peak annotation: Areas. Centmps
Revise#: 24-Jul-2008 13 48:57 (EE} Printed: 0S-Aug-2008 OS 28 42 Page 17 o?22
-------
AP Lab ID: P9464_6042_PCB_Q03
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 61

PCB-189
Rel. Int.
5.81eS
100%-,
41.73
t
Fn 6
A
393.8025 ¦

HpCB-6

4o 1.94e3 .

41.17-46.41 ¦
11
0%-
r 1 -t1"	i '"l1 ¦' i—Is-
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
Abs. Int.
-1.42e5
¦7.10e4
Rel. Int.
100%-
Fn 6
395.7995
HpCB-6
4o 1 54e3
41.17-46.41
0%-
PCB-188
5.72e5
41.73
1.22e4
41.53
43.0
2,03e4
43j47
¦ II|| ¦ ^
44.0
tm •
45.0

46.0
43.0
1.3864
43.46
1 I 1
44.0
-O.OOeO
RT
Abs. Int.
-1.46e5
¦7.28e4

ES-189
Rel. Int.
1.82e7
100%-
41.71
A
Fn 6
A
405.8428

HpCBStd.

4o 6 55e3 .

41.17-46.41 ¦

0%-
. 		/ A
i 	i	-I 	''i-	r ¦ "| i ¦ 			 i i "i " •/ O.OOeO
45.0	46.0	RT
Abs. Int.
4.07e6
-2.03e6
4.28eS
43.85
42.0
43,0
44.0
45.0
""—I—1
46 0
¦O.OOeO
RT

ES-189



Rel. Int.
1.7W
4ffi
' A


Abs. Int.
100%-j


-3.80e6
Fn 6
A


*
407.8398 ¦



¦
HpCBStd. :



-1.90e6
40 8.97e3 .



41.17-46.41 ¦
\
3.30e5
4.0leS
¦
0%-
	/. \	
43.45
43.85
-O.OOeO
42.0
43.0
44.0
45.0
46.0
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41"
0%-
42.0
43.0
44.0
Results: P:\P9400_P9499\P9464_6042 PCSVesovrtes\P9464_6042_PCB_003.utp_res. saved 24^Jul-2008 13:49 fEE}
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 8031. 4307
45.0
Revised: 24-Jut-2008 13:34:51 (EE)
46.0
Abs. Int.
r2.05e7
¦1.02e7
¦O.OOeO
RT
Peak annotation: Areas. Centroitis
Printed: OS-Aug-2008 06:28:44 Page l&pr22
-------
AP Lab ID; P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 5
427.7635
OcCB-5
4a 7.43e2
34.16-41.15
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
0%-
PCB-202
1.57e5
35.80
X
PCB-201
3.77e5
36.56
i'fj i i 9 1 i [ i if t 1 f i' n i t »"f ¦"» *
35.0	36.0	37.0
PCB-197
3.99e5
PC8-20
I.0le5
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07 EQ
Abs. Int.
-1.33e5
I" I"1! V » 1*1'^* I I |"
38.0
39,0
Rel. Int.
100%-
Fn 5
429.7606
OcCB-5
4a 1.90e3
34.16-41.15

PCB-202
1.68e5
35.80
Rel, Int.
100%-
Fn 5
441.8008
OcCB Std.
4a 1 87e3
34,16-41.15 ¦
0%-
I	¦
35.0
A
i | i i I
36.0
PCB-197
PCB-201
4.4Qe5
37.32
36.57
PCB-2
1.13e5
37.13
'i ¦ i—'i"y—r—»—i—i—i"1 "i" —i—j ¦ t
38.0	39.0
PC B-196
5.75e5
PCB-19B/199
40.28
4.73e5
CB-203
2.86e5
40.44
PCS-196
7.03eS
40.27
40.44
-6 63e4
PCB-198/109
4.99e5
39.73
'i*| O.OOeO
41.0 RT
Abs. Int.
1.63e5
8.14e4
t" i "»—|——r"»r -y r 4—* f—f | ¦ r' O.OOeO
40.0

ES-202
Rel. Int.
1.52e7
100%-,
35.78
A
Fn 5 :

439,8038 ¦

OcCB Std. "

4a 2.52e3 "

34.16-41,15 ;
[
0%-

35.0
36.0
¦¦¦¦j	i	i	i	i	|	i	r	r	r	|	t	t	»	t	j	t	t	t	i	j	i	i	i	i	y	tmi
37.0	38.0	39.0
40,0
ES-202
1,68e7.
35^6
35.0
36.0
I I I | I 1 I 1 | I
37.0
¦T"-| ¦ t—t—r—t ¦ p
38.0
41.0 RT
	X	1	t	%	|	1		%	|	I	I	I	I	|f	>'
Abs. Int.
-3.67e6
1,84e6
¦O.OOeO
41,0 RT
39.0
40.0
Abs. Int.
-4.08e6
•2.04e6
i—i-*-O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
35.0
I 1 1 1 • t •
36.0
37,0
38.0
» » | 1 < 1 I j
39.0
Abs, Int.
-2.31e7
1.16e7
40.0
	O.OOeO
41.0 RT
Results: P:\PS400_P9499\P9464_6042 PC8SmsouKesSP9464_6042_PCB_003.utp_ms, saved 24-M-2008 13:49 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 2382 0946
Peak annotation: Areas, Centrpfds
Revised: 24-Ju/-2008 13:49:18 (EE) Printed: 05-Aug-2008 08:28:45 Page 19 fit 22
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Rel. Int.
100%-
Fn 6
427,7635
OcCB-6
4o 1 22e3
41,17-46.41
0%-

rCB-195
2.45e5
41.54
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
PCB-194
3.53e5
43.47
A
42.0
43.0
Acq: 24-Jul-2008 05:44:48
User: JLJ Datafile: 080724V07_EQ
Abs. Int.
7.83e4
6.49e3
45.27
44.0
	P-	I"11 f1
45.0

•3 92e4
i.OOeO
Rel. Int.
100%-
Fn 6
429.7606
OcCB-6
4o1.06e3
41.17-46.41
0%-
Rel. Int.
100%-
Fn 6
439.8038
OcCBStd.
4a 2.28e3
41.17-46.41
0%-
Rel. Int.
100%-
Fn 6
441.8008
OcCBStd.
4o 3 28e3
41.17-46.41
Q%-
PCB-195
2.79e5
42.0

PCB-205
1.96e5
43.86
42.0
43.0
44.0
) "^r
1.88e4
45.31
-i—|—r^-r^rVY
45.0
JS-194
1.11e7
43.45
1—I—
42.0
43.0
46.0
44,0
45.0
46.0
ES-205
1.29b?
43J5
Abs. Int.
-7.90e4
3.95e4
-O.OOeO
RT
Abs. Int.
-2.47e6
-1.23e6
¦O.OOeO
RT
Abs. Int.
-2.76e6
1 38e6
43.0
44.0
45.0
46.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41'
0%-
42.0
43.0
44.0
45.0
T
'—I—1
46.0
Abs. Int.
-2.05e7
1.02e7
•O.OOeO
RT
Results: P:SP9400_P9499\P9464_B042 PC8Sresources
-------
AP Lab ID: P9464_6042_PCBJ)03
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 61
Acq: 24-Jul-2008 05:44:48
User: JLJ Oatafile: 080724V07 EQ
Rel. Int.
100%-
Fn 6
461.7245
NoCB
4o 1.33e3
41.17-48.41
0%-
PCB-20
2,60e5
41 34
42.0
1—
43.0
I	'	
I 111 P—|	1	j I I
44.0
45.0
PCB-206
3.60e5
45.30
Abs. Int.
-1.21e5
•6.04e4
i	|	 	r		 "•'/ O.OOeO
46.0	RT
Rel. Int.
100%-
Fn 6
463.7216
NoCB
4cr 2.11e3
41.17-46.41 •
0%-
Rel. Int.
100%-
Fn 6
473.7648
NoCB Std.
4a 2,00e3
41.17-46.41
PCB-2Q8
3.27e5
41.34
ES-208
9.98e6
41.32

42.0
43.0

-r—f—
44.0
'"I	T
45.0
PCB-206
4.31e5
45.30
ES-206
7,33e6
45.28
46.0
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-1.39e5
•6.94e4
-O.OOeO
RT
Abs. Int.
-2.38e6
•1.19e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
475.7619 •
NoCB Std.
4o2.13e3
41.17-46.41 ¦
41.32
ES-206
9,35er"
0M
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-2.94e6
¦1.47e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41'
0%-
42.0
43.0
44.0
45.0
46.0
Abs. Int.
r2.05e7
-1.02e7
¦O.OOeO
RT
Results: P:\P9400_P9499W9464_6042 PCB\resources\P9464_6042_PC8_003utp_ms. saved 24-Jul-2008 13:49 (EE)
AP Ultra Trace-Pro V3.993 User/System EE/EEC2-038 cc: 9289. 1732
Peak annotation: Areas, Centroids
Revised: 24-M-2008 13:35:37 (EE) Printed: OS-Aug-2008 08:28:4? Page 21 o¥22
-------
AP Lab ID: P9464_6042_PCB_003
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-2
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 61
PCB-20S
Rel. Int.
100%
46.63
Fn 7
497.6826
DeCB
4o 6.93e2
46.42-54.01
0%-
Acq: 24-Jul-2008 05:44:48
User. JLJ Datafile: 080724V07 EQ
Ate. Int.
-8.72e4
•4.36e4
l', i"»• i [ i (	r "t	|"" i 'i "i i | i i i1 i "| 'f1 r1"? i1 | it i i | i i
47.0
PCB-209
Rel. Int. 3.-29e5
100%-
Fn 7
499.6797
DeCB
4o 1.08e3
46.42-5401
0%-
46,63
X
47.0
Rel. Int.
100%-
Fn 7
509.7229
DeCB Std.
4o6.76e2
46.42-54.01
0%-
ES-209
1-26e7
46.61

47.0
Rel. Int.
100%
Fn 7
511.7199
DeCB Std.
4o 1.16e3
46.42-54.01
0%-
ES-20J
msSS
4K61
XX
47.0
48.0
49.0
50.0
"I I I i ) r I' I I"I"* I' "i	f"I—r-
51,0	52.0
53.0
i '> | "i' i "i ''"'i' y i"
48.0
f-n~
I T I	'Hr'-j'"-! • J '| | fn-pun, | n 11 | [»! | ¦ T " | |
49.0	50.0	51.0
52.0
53.0
48.0
49,0
50.0
51.0
52.0
¦¦¦¦I	i	|	r	*	i	i	|	I1"
53.0
48.0
49.0
50.0
51.0
52.0
1111(1
53.0
-O.OOeO
54.0 RT
Abs. Int.
7.64e4
¦3.82e4
-O.OOeO
54.0 RT
Abs, Int.
2.8Se6
-1.44e6
-O.OOeO
54.0 RT
Abs. Int.
2.33e6
1.l?e6
•O.OOeO
54.0 RT
Rel, Int.
100%-
Fn 7
454.9728
QC Check
46.42-54.01
Abs. Int.
-2,05e7
-1,03e7
0%-
'"1	r	T	T	f	I	T	T"1
,MJ	I	f	T	f	|	t"
48.0
49.0
' I '
50.0
¦¦¦'*	\	*	j	i	i	r	t	J	r	i	t,m
51.0
52.0
-O.OOeO
47.0
53.0
54.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resaur
-------
AP Lab ID: SBS_080724_PCB_VS
fristr; AutoSpec-Premier MM6
Sample 10: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2Q08 06:42:15
User: JLJ Datafile: 080724V08_EQ
Fn 1
Rel. Int.
100%.
218.8856
QC {non-EQ)
9,03-13.00
0%.
' I *
9.5
10.0
10.5
' I '
11.0
11.5
12.0
' 1 *
12.5
Abs. Int.
-9.47c?
-4.73e7
-O.OOeO
13.0 RT
Fn 2
Rel, Int.
100%-,
242.9856
QC (non-EQ) ,
13.02-17.79
0%.
13.S
' I "
14.0
1 I '
14.5
15.0
15.5
16.0
16.5
17.0
17.5
Abs. Int.
-6.0087
• 3.00e?
•O.OOeO
RT
Fn 3
Rel. Int.
100%.
292.8824
QC (non-EQ) .
17.81-23,26
0%.
—I—
18.0
-i	.—i	1	,					1—|—
19.0
-1	.	¦	>	.	1	r-
20.0
21.0	22.0
Abs. Int.
-6.07e7
• 3.03e?
O.OOeO
-i—i—i—[—r-
23.0	RT
Rel. Int.
Fn 4 100%-
330.9792
QC (non-EQ)
23.27-34,14
0%-
—I—
24,0
iiiiiiii
26.0
—I—
28.0
->—1	1—
30.0
i i i i i i
	1—
32.0
—I—'	*~
Abs. Int.
-5,10e7
•2.55e7
¦O.OOeO
34,0 RT
Fn S
Rel, Int.
100%.
366.9792
QC (non-EQ)
34.16-41.15
0%-l, , . 	,	
Abs. Int.
-1.09e?
-5.47o6
' I '
35.0
' I ' ' ' ' I
36.0
37.0
I i i i i I i i i i I i i
38.0
	I	'
39.0
O.OOeO
—I—l—l—p-1—I—i—r—|—i—r—r—*—j-
40,0	41.0 RT
Rel. Int.
Fn 6 100%.
454.9728
QC (non-EQ)
41.17-46.41
0%-
-i—j—i—i—i—>—p
42.0
—I—
43.0
—I—
44.0
'j1 1 ¦!	*	!	*	1	1	1	1	1	p
45.0
—I—
46.0
Abs. Int.
-1,67e7
-8 33e6
-O.OOeO
RT
Rel, Int.
Fn 7 100%
454.9728
QC (non-EQ)
46.42-54.01
Abs. nt
2,05e7
1,03e7
O.OOeO
54.0 RT
Results: P:\P9400_P9499V9464_6042 PCBVesources\SBS_080724_PCB_VBvtp_res. saved 24-M-2008 13:49 (EE!
AP UllraTrace-Pm V3.993 User/System: EE/EEC2-038 see: 620-6fi
Peak annotation: Areas, Centroids
PKD n/a Printed: O^Aug-2008 08:28 50 Page 1 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1	^	Acq: 24-Jul-2008 06:'42:15
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_#W?¥rOPRm'§SSS User: JLJ Oatafile: 080724V08_EQ
Ret. Int.
Fn 1 100%-
218.9855 ;
QC Check J
9.03-13.00 -
0%-
-i—|—i--i—i—r—|—p—r-
9.5
10.0
10.5
11.0
11.S
12.0
12.5
Abs. Int.
-9 60e7
-4.60e7
.O.OOeO
13.0 RT
Fn 2
Ret. Int.
100%-
242.9856
QC Check
13.02-17,79
0%-
I I I—r—|—I—I t I—|—!—i—I v | I—TT-
13.5	14.0
14.5
15.0
1S.5
18.0
' I ¦
16,5
Abs. Ini.
-6.02e7
• 3.01e7
17,0
17.5
•O.OOeO
RT
Fn 3
Rel. Int.
100%.
292.9824
QC Check
17.81-23.26
0%.
—I—
18.0
19.0
20.0
21.0
—I—
22.0
23.0
Abs. Int.
-5.96e7
-2.98e7
¦ O.OOeO
RT
Fn 4
Rel. Int
100%-
330.9732
QC Check
23.27-34.14
0%.
24,0
26.0
28.0
30.0
—I—
32,0
Abs. Int
-5.02e7
• 2.51e7
.O.OOeO
34.0 RT
Rel. Int.
Fn 5 100%-
4M.9728
QC Check
34.16-41.15
0%-
* I r
35.0
"1—'—'—'—'—I—r
36.0
37.0
1 I 1
38.0
-t—t—|—r-
' "1 '
39.0
"T—'—'—'—'—I—r
40.0
—|—i—r-
Abs. Int.
1.97e7
9.84 e6
O.OOeO
41.0 RT
Rel. Int.
Frt6 100%-
404.9760
QC Check
41.17-46.41
0%.
—!	1	1	r-
42,0
—i—<—•—>—>—r
43.0
i i I i i	1	1 j i	1	1 i—J—
44.0	45.0
—I—
46.0
Abs. Int.
-2.11e?
H.OSe?
¦f- O.OOeO
RT
Rel. Int,
Fn 7 100%.
454.9728
QC Check
46.42-54,01
0%-
47.0
I 1 1 ' ' I ' ' '
48.0
' I 1
49.0
-i—*—j—i—i—i—i—|—r-
50.0
' I ' ¦
51.0
I ' ' ' ' I '
52.0
53.0
Abs. Int.
-2.04e7
-1,02e7
•O.OOeO
54.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB[resources^SBS_080724_PCB_VB.u!p_res. saved Z4-Jul-2008 13:4S (EE)
AP UltraTmce-Pm 1/3.993 User/System: EE/EEC2-038
Peak annotation: Areas. Centmids
PKD: nta Printed: 0S-Aug-2OO8 08:28:5 f Page 2 of 22
-------
AP Lab ID; SBS_08G724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%
Fn 1
188.0393
MoCB
4o 3.50e3
9.03-13.00
1.3964
11.26
Abs, Int.
-1,26e4
6 28e3
O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
190.0363
MoC8
4 a 2.72e3
9.03-13.00
Abs. Int.
-6.86e3
3.43e3
O.OOeO
13.0 RT
Rel. Int.
100%
Fn 1
200,0795
MoCB Std,
4o1.23e4
9.03-13,00
Abs. Int.
-2,80e4
1.4084
O.OOeO
13.0 RT
Rel. Int.
100%
Fn 1
202.0766
MoCB Std.
4cj 4.34e4
9.03-13.00
Abs, Int.
-1,35e5
6.74e4
O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
218.9866
QC Check
9.03-13.00
Abs. Int.
-9.60e7
4.80e7
O.OOeO
13.0RT
Results: P:\P9400_P9499\P9464_6042 PCB\resourcBs\SBS_080724_PCB_VB utp_res, saved 24-Jut-2008 13:49 (EE)
AP UttraTmce-Pm V3.993 UserfSyStom: EEJEEC2-038 cc: 6638. 6760
Peak annotation: Areas. Centroids
PKD: 24-Jul-2008 13:49:37 Printed: OS-Aug-2008 08:28:52 Page 3 of 22
-------
AP Lab ID: SBS_08Q724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Dataflle: 080724V08_EQ
Rel, Int.
100%
Fn 1
222.0003
DiCB-1
4 o 6.95e3
9.03-13.00
Abs. Int.
-1.?5e4
-8.74e3
O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
223.9974
OiCB-1
4o 2.65e4
9,03-13.00
Abs. Int.
-8.23e4
4,11e4
O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
234.0406
DiCB Std.
4o 1.08e4
9.03-13.00
I I t I I t 1
Abs. Int.
3.03e4
1,52e4
l i i—i—i—|—i——i—f- O.OOeO
12.5	13.0 RT
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std.
4 o 9.02e3
9.03-13 00
0%-
T~I~r
9.5
10.0
10.5
11.0
¦ i ¦
11.5
t % [ t I I t | I
12.0
' I 1
12.5
Abs. Int.
-1,94e4
9 71e3
•O.OOeO
13.0 RT
Rel. Int.
100%-
Fn 1
218.9856
QC Check
9,03-13.00 "
Abs. Int.
-9 60e7
-4.80e7
0%-
r-T-r
9.5
lllVflfllllTfl
f [ T I I T | I T f I | I
12.5
-O.OOeO
10.0
10.5
11.0
11.5
12,0
13.0RT
Results: P*P9400_P9499\P9464_6042 PCBSmsources\SBS_Q80724_PCB_VB.utp_ms, saved 24-Ju>-2008 13:49 (EE)
AP UltmTrace-Pro V3M3 User/System: EEJBEC2-038 cc: 8045, 1746
Peak annotation: Areas, Centmids
PKD: 24-Jul-2008 13:49:37 Printed: OS-Aug-2008 08:28:54 Page 4 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Oatafile: 080724V08 EQ
Rel. Int.
100%
Fn 2
222.0003
DiCB-2
4 o 5.87e3
13.07-17.79
Abs. Int.
-1.07e4
5.37e3
O.OOeO
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4a 2.02e4
13.07-17.79
0% », ¦ ¦
13.5
I 1 1 1 1 I 1
14.0
ir|riii|iiir|iiir|ii—r—!—|—i i
14.5	15.0
' I ¦
15.5
16.0
i i | » i i i [ r
16.5
¦"t	r"vimi	f	
17.0
Abs. Int.
r 7.25e4

17.5
•3.63e4
-j—O.OOeO
RT
Rel. Int.
100%
Fn 2
234.0406
DiCB Std.
4a1.37e4
13.07-17.79
| I I I I
13.5
I | % » I I f I I I T | t I 1 I | I » I » | » I I I } 1—I t I | I I I I | > I I
14.0	14.5	15.0	15.5	16.0
Y"V"i	»¦	rm
17.5
Abs. Int.
-4.67e4
2.34e4
-O.OOeO
RT
Rel. Int.
100%
Fn 2
236.0376
DiCB Std.
4o 6 72e3
13.07-17.79
Abs. Int.
-2.10e4
1,05e4
O.OOeO
Rel. Int.
100%
Fn 2
242.9856
QC Check
13.07-17.79
Results: P \PV400_P9499\P9464_604? PCBtresaunxs\SBS_080724_PCB_ VB utp_nas. saved 24-Jul-2008 13:49 (EE)
AP UttrsTrdce-Pro V3.993 User/System: EE/EEC2-038 cc: 6996, 0096
Abs, Int.
6 02e7
3.01 e7
O.OOeO
Peak annotation: Areas. Centroids
PKD: 24-Jut-20Q8 13.49:37 Printed: OS-Aug-2008 08 28 55 Page S of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AuloSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%
Fn 2
255.9613
TrCB-2
4a 2,22e3
13.02-17.79
Abs. Int.
-5.25e3
2.63e3
r—O.OOeO
RT
Rel. Int.
100%
Fn 2
257.9584
TrCB-2
4o2 46e3
13 02-17.79
Abs. Int.
-6.16e3
3 08e3
O.OOeO
RT
Rel. Int.
100%
Fn 2
268,0016
TrCB Std.
4o 4.82e4
13.02-17.79
1.39e6
13.44
Abs. Int.
-4,70e5
2.35e5
6.70e5
17.06
O.OOeO
Rel. Int.
100%
Fn 2
269.9986
TrCB Std.
4o 4,37e4
13.02-17.79
Abs. Int.
-8.31e4
4.16e4
i ? i i * ] O.OOeO
17.5	RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.02-17.79 ~
Abs. Int.
02e7
3.01e7
i—i t t i | O.OOeO
17.5	RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\SBS_080724_PC8_V8.utp_res. saved 24-Jut-2008 13:49 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 6084, 2191
Peak annotation: Areas. Centroids
PKD: 24-Jul-2008 13:49:37 Printed: OS-Aug-2008 08:28:56 Page B of 22
-------
AP Lab ID: SBS_080724_PCBJ/B
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%
Fn 3
255.9613
TrCB-3
4o 2 43e3
17.81-23.26
Rel. Int.
100%-
Fn 3
257,9584
TrCB-3
4o 3.24e3
17.81-23.26
Abs. Int.
-4,82e4
24le4
t.94e5
21.26
r3-O.OOeO
1.9565
Abs. Int
5.16e4
18.0
19.0
200
21.0
22,0
23.0
2.58e4
O.OOeO
RT
Rel. Int.
100%
Fn 3
268.0016
TrCB Std.
4a 3.88e4
17.81-23.26
1.08e6
20.78
A
Abs. Int.
-2.36e5
1.18e5
O.OOeO
RT
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
4o 3.94e4
17.81-23.26
18,0
19.0
20.0
21.0
22.0
Abs. Int.
-9.26e5
¦4,63e5
-O.OOeO
23,0	RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26 J
20,0
Results: P:\P9400__P9499V9464_6042 PCB\resounoes\SBS_OB0724_PCB_ VB utp_res. saved 24-Jul-200S 13:49 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 21S6, 9512
21 0
22.0
Abs, Int.
96e7
2,98e7
-I—.—r—O.OOeO
23.0	RT
Peak annotation: Areas, Centroids
PKD: 24-M-2008 13:49:37 Printed: Q5-Aug-2008 08:28:57 Page 7 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_d1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%
Fn 2
289.9224
TeCB-2
4o 1.24e3
13.02-17.79
Abs. Int.
-4.52e3
2.26e3
OOeO
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o 2.04e3
13.02-17.79
Abs. Int.
-5.17e3
2.59e3
O.OOeO
RT
Rel. Int.
100%
Fn 2
301.9626
TeCB Std.
4a 6,26e3
13.02-17.79
Abs, Int.
r1 ,94e4
9.70e3
I-*-0.0060
RT
Rel. Int.
100%
Fn 2
303.9597
TeCB Std.
4o 3.90e3
13.02-17 79
Abs. Int.
1.12e4
5.61 e3
O.OOeO
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.02-17.79
Abs. Int.
-6.02e7
-3.01 e7
0%-
| I > I I | I I
13.5
14.0
14.5
15.0
15,5
I | t I I I J I I I ! | I T I I | I I
16.0	16.5
Results: P:\P9400_P9499W9464_6042 PCB
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%-
Fn 3
289.9224
TeCB-3
4o1.22e3
17.81-23.26
0%-
18.0
I g I I I
19.0
Abs. Int.
-3.29e3
•1.65e3
t-J-O.OOeO
I I I I f I I I I ! I 1 I I I I ! I I I ; I ! I ! I f V V I | ! I ( I |
20.0	21.0	22.0	23.0 RT
Rel. Int.
100%
Fn 3
291.9194
TeCB-3
4o 1.36e3
17.81-23.26
'—¦—r
22.0
Abs. int.
-6.04e3
3.02e3
—.—r—O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 3
301.9626
TeCBStd.
4o 3.89e3
17.81-23.26
Abs. Int.
-3.59e4
1.79e4
O.OOeO
RT
Rel. Int.
100%
Fn 3
303.9597
TeCBStd,
40 3.03e3
17.81-23.26
0%
Abs. Int.
-7.54e3
3,77e3
^j—r—i—i—|—r—i—¦— O.OOeO
23.0	RT
Rel. Int.
100%-
Fn 3
292.9824
QC Check '
17.81-23.26 .
Abs. Int.
-5.96e7
-2.98e7
0%-
18.0
19.0
» » '| I 		I	T	I""
20.0
"T	T	T,M
21.0
22.0
23.0
Results: P:\P9400_P9499\P9464_6042 PCB\resourxxs\SBS_080724_PCB_VB utp res. saved 24-Jut-200B 13:49 (EE)
AP Ultra Trace-Pro V3 993 User/System: EE/EEC2-038 cc: 1903, 7146
-O.OOeO
RT
Peak annotation: Areas. Centmids
PKD 24-JU/-2009 13:49:37 Printed: 05-Aug-2008 08:28:59 Page 9 at 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%- M9eS
289.922AT-
TeCB-4l°1'"'
4o 1.05e3
23.27-33.00
1,40e5
27 ®3 ,1.3le5
23.55
!	J
Abs. Int.
-4.33e4
2.16e4
O.OOeO
RT
Rel, Int.
100%-, 2 ,
Fn 4
291.9194
TeCB-4
4o 2.89e3
23.27-33.00
I.67e5
1.52e5
27.63
28.10


Abs. Int.
-5.27e4
2.63e4
O.OOeO
RT
Rel. Int.
100% -
Fn 4
301.9626
TeCB Std.
4o 4.56e3
23.27-33.00

1.77e4
* \ ll


30.88
i 1 1 11 f 1 '
¦	'	I	'	?	•	'	!	'	*	'	»	?	«	»	r~r I i i 1
faj
1 1
1 1 » I 1 1 i ? ! iii llllVI
iiiiiiiititiitiliTiit t-i	i		i	r"ir,,T",r"T,,'r"T,,,T""'r 'l l i""l|a< 7 < "yHTTfTT f'!¦> '
24.0
25.0
26.0
27.0
28.0
29.0
30.0
31.0
32.0
Abs. Int.
1,84e4
9.19e3
O.OOeO
RT
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
4o 2.09e3
23,27-33.00
0%-
24.0
II1I
-------
AP Lab ID: S8S_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cI1-10_mm6 GC:pcbx10Q_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%-
Fn 3
323.8834
PeCB-3
4o 1.22e3
17.81-23.26
8.64e4
22.07
m

Abs. Int.
r2.82e4
-1.41e4
O.OOeO
RT
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
4o 1 .80e3
17 81-23.26
0%-La^r
1.44e5
Abs. Int.
-3.88e4
•1.94e4
20.0
21.0
22.0
—i	j	1	r——r—	f	1—¦-O.OOeO
230	RT
Rel. Int.
100%
Fn 3
337.9207
PeCB Std,
4a 2.49e3
17.81-23.26
Abs. Int.
-1,45e4
7.25e3
1.38e4
21.39
OOeO
Rel. Int.
100%-
Fn 3
339.9177
PeCB Std.
4a 2.07e3
17.81-23.26
0%-
i4^#
T
18.0
19.0

20.0
21.0
22,0
Abs. Int.
-1.13e4
•5.65e3
23.0
•O.OOeO
RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Abs. Int.
5.96e7
2 98e?
O.OOeO
RT
Results: P:\P9400_P9499\P94S4_S042 PCB\resouices\SBS_080724_PCB_VB.utpi_ms, saved 24-Jul-2008 13:49 (EE)
AP UltraTrace-Pm V3 993 User/System: EE/EEC2-03B cc: 6662, 6292
Peak annotation: Areas. Centroids
PKD: 24-Jul-2008 13:49:37 Printed: 05-Aug-2008 08 29.0r Page 11 at 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: S1L 7-27-1
VSIR expt. pcb0405_ _cl1-10_mm6 GC: pcbx10Q_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JU Dataffle: 080724V08_EQ
Rel. Int.
100%
Fn 4
323.8834
PeCB-4
4o 1.25e3
23.27-34.14
6.31 e4
SH3CE
^ 6 86e4
25.58
fSJSTS-
*V:- ..y
| I 1 >
24.0
26.0
28.0
~ ^ ,7J0e4 8,6,164
^-1

"\_Li2.	''
30.0
32,0
Abs. Int.
-2,34e4
¦1.17e4
i.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
325.8804
PeCB-4
4o l.61e3
23.27-34.14
24.0
< ai^c. i,3Ses
i .4oes> 30 71
1.12e5
24.83
1.05e5
25.5
Abs. Int.
-3.96e4
1,98e4
O.OOeO
26.0
28.0
30,0
32.0
34.0 RT
Rel. Int.
100%-
Fn 4
337.9207
PeCBStd.
4o 2.76e3
23.27-34.14
0%-

I 1 V I
24.0
'"I	I	I	
26.0
*t	1 J " ¦" "T ¦ T »
28.0
30.0
32,0
Abs. Int.
-1,54e4
7.72e3
¦O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
339.9177
PeCBStd.
4o 2.07e3
23.27-34.14
0%-
24.0

26,0
Abs. Int.
-1.18e4
5.89e3
O.OOeO
28.0
30,0
32.0
34,0 RT
Rel. Int.
100%
Fn 4
330.9792
GC Check
23.27-34.14
Results: P:\P9400_P9499\P9464_6042 PCBW$auwesiSBS_080724_PCB_VB.utp_m$, saved 24-JM-20Q8 13:49 (EE)
AP UltmTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 7122, 8288
Abs. Int.
5.02e7
2 51e7
j—-O.OOeO
34.0 RT
Peak annotation: Areas, Centroids
PKD: 24~Jut-2008 13:49:36 Printed: OS-Aug-2008 08:29:03 Page 12 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl 1-10_mm6 GC: pcbx100_a Viat: 2
Acq: 24~Jul-2008 06:42:15
User: JU Datafile: 080724V08_EQ
Ret, Int.
100%-
Fn 5
323,8834
PeCB-5
4o 1.51e3
34,16-41.15
0%-
35.0

36.0
37.0
38.0
39.0
40.0
Mm/*:
Abs, Int.
-1,02e4
¦5,10e3
•O.OOeO
41,0 RT
Rel. Int.
100%
Fn 5
325,8804
PeCB-5
4o 2.27e3
34.16-41.15
Abs. Int.
7.35e3
3.67e3
OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
337.9207
PeCB Std,
4a2.02e3
34.16-41.15
Rel. Int.
100%
Fn 5
339.9177
PeCB Std.
4o 1,68e3
34.16-41.15
41.0 RT


Abs. Int.
-1.22e4
6 12e3
OOeO
Abs. Int.
1.61e4
8.06e3
OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15'
0%-
I | 1
35.0
36.0
1 I I I > »
37.0
38.0
39.0
40.0
Abs. Int.
-1,9?e7
9.84e6
-T-T— O.OOeO
41.0 RT
Results: P:\P9400_P9499\P9484_6042 PCBVasaurce$\SBS_080724_PCB_VB.utp_m$, saved 24-M-20Q8 13:49 (EE)
AP UltmTmce-Pm ¥3.993 User/System: E&EEC2-038 cc: 9699, 7839
Pea* annotation: Areas. CentmUs
PUD: 24-Jul-2008 13:49:36 Printed: OS-Aug-2008 08:29:04 Page 13 Of 22
-------
AP Lab ID: SBS_Q80724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: S!L 7-27-1
VSIR expt: pcb0405_d1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Dataflle: 080724V08 EQ
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4o 1 00e3
23.27-34.14
24,0
1.35e5
26.71
,CVT:/
rK-
26.0
A
28.0
30.0
32.0
Abs. Int.
r3.86e4
¦ 1,93e4
_ Q Q00O
34.0 RT
Rel. Int.
100%
Fn 4
361,8385
HxCB-4
4o 9.50e2
23,27-34.14
1.05e5
26.71
Abs. Int.
-3,31e4
1.66e4
O.OOeO
24.0
26.0
28.0
30.0
32.0
34.0 RT
Rel, Int.
100%-
Fn 4
371.8817
HxCBStd.
4o 1.91e3
23.27-34.14
3.2264
30.29
1.25e<
30.09
Abs. Int.
-2,09e4
1.04e4
.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
373.8788
HxCBStd,
4o 2.23e3
23.27-34,14
0%-*—i—i—i—i—i—i—i—i—i—j—i i—i—i—i—i—
T
24.0
-I	i	r-
26.0
28,0
1—I—1
30,0
32.0

Abs, Int.
-1.95e4
•974e3
¦O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Results: P:\P9400_P9499\P9464_6042 PCB\resources\SBS_080724_PCB_VB utp_res. saved 24-Jut-2008 13:49 (EE)
AP UtlraTrace-Pm V3.993 User/System: EE/EEC2-Q38 cc: 7882. 2706
Abs, Int.
5.02e7
2.51e7
— O.OOeO
34.0 RT
Peak annotation; Areas. Centroids
PKD: 24-M-2008 13:49:37 Printed: Q5-Aug-200& 08:29:05 Page 14 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIRexpt: pcb0405_cl1-10_mrn6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%
Fn 5
359.8415
HxCB-5
40 1.11©3
34,16-41.15
Rel. Int.
100%
Fn 5
361.8385
HxCB-5
4o 1,07e3
34.16-41.15
U5e5
34.51
B.9»e4
34.51
Abs. Int.
- 3 13e4
1.56e4
i ' ' ' ' r
39.0
pta_0.00e0
41.0 RT
Abs. Int.
-2.57e4
1,28e4
T^-O.OOeO
41.0 RT
Rel. int.
100%
Fn 5
371.8817
HxCB Std,
4o 2.46e3
34.16-41.15
1.2364
40.91
Abs. Int.
-1 S3e4
-7.64e3
O.OOeO
41.0 RT
Rel. Int.
100%
Fn 5
373.8788
HxCB Std.
4a 2.21 e3
34 16-41.15
2.03e4
40.42
2,19e4
39.39
1.68e
38.93
Abs. Int.
-1,92e4
9.60e3
O.OOeO
38.0
39.0
40.0
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34,16-41.15'
0%-
'"T	T	T	
35.0
36.0
37,0
38.0
11 I '
39,0
Abs. Int.
-1,97e7
¦9.84e6
40.0
-O.OOeO
41.0 RT
Results: P:\P9400_P9499\P9464_6042 PC8\msoumes'
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: peb04Q5_c!1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-JUI-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel, Int.
100%
Fn 4
393.8025
HpCB-4
4cr 1.57e3
30.00-34.14
1.Q2e5
32.04
Abs. Int.
-2,51e4
1.26e4
¦ ¦ | > -1 O.OOeO
34.0 RT
Rel, Int.
100%-
Fn 4
395.7995
HpGB-4
4o 1,07e3
30.00-34.14
9.83©4
32.04
Abs. Int.
-2,93e4
1 46e4
I ¦ i • O.OOeO
34.0 RT
Rel. int.
100%-
Fn 4
405.8428
HpCB Std.
4o2,16e3
30.00-34.14
0%-
1.03e4
30,72

30.5
31.0
31.5
32,0
Abs. Int.
-2.15e4
1,08e4
O.OOeO
34.0 RT
Rel. Int.
100%-,
Fn 4
407.8398
HpCB Std.
4o 2.60e3
30.00-34.14
Rel. Int.
100%
Fn4
330.9792
QC Check
30.00-34.14
30.5
31.0
31,5
32,0
32.5
33.0
Abs. Int.
-1.41e4
7.04e3
OOeO
33.5
34.0 RT
Abs. tnt.
t-5.02e7
-2.51e7
O.OOeO
Results: P:\P9400_P9499SP9464_6042 PCBVvsources\SBS_080724_PCB_ VButp_res saved 24-JUI-2008 13:49 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 1045, 8992
Peak annotation: Areas. Cenlmids
PKD: 24-M-2008 13:49:37 Printed: Q5-Aug-2008 08:29:07 Page 16 of 22
-------
AP Lab ID; SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SiL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx10Q_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JU Datafile: 080724V08_EQ
Rel. Int.
100%-
Fn 5 ]
393.8025 •
HpCB-5
4o 1,64e3 -
34.16-41.15 -
Rel. Int.
100%
Fn 5
395,7995
HpCB-5
4a 8.94e2
34.16-41.15
vooe5
34,77

9.0264
34.78

Abs. Int.
-2.58e4
1.29e4
I itti i i j1 t* O.OOeO
41.0 RT
Abs. frit.
-2,22e4
0%-Mv
37.0
1.11e4
i—0. OOeO
41.0 RT
Rel. Int.
100%
Fn5
405.8428
HpCB-5 Std.j
4a 2.27e3
34.16-41.15
Rel. Int.
100%
Fn 5
407.8398
HpCB-5 Std
4o2 80e3
34.16-41,15
Abs. Int.
-1,75e4
8,73e3
OOeO
1,50e4
37.23
Abs. Int.
1.15e4
5.76e3
O.OOeO
35.0
36.0
37.0
38.0
39.0
40.0
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
"I	1	1 ! I
I | I I f
35.0
* * * i
36.0
37.0
38,0
39.0
40.0
Abs. Int.
-1,97e7
•9 84e6
41.0
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCBVesourcestSBS_080724_PC8_ VB res. saved 24-Jul-2008 13:49 (EE)
AP imraTmce-PrcT V3.993 User/System: EE&EC2-038 cc: 8317. 9650
Peak annotation: Areas Centroids
PKD: 24-Jut-2008 13:49:37 Pnnled OS-Aug-2008 08:29 08 Page 17 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%-
Fn 6
393.8025
HpCB-6
4o 1 .26e3
41.17-46.41
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-3.0Se4
¦1.53e4
•O.OOeO
RT
Rel. Int.
100%
Fn 6
395.7995
HpCB-6
4ct 1.08e3
41.17-46.41
Abs. Int.
-4.84e3
2 42e3
O.OOeO
RT
Rel. Int.
100%-
Fn 6
405,8428
HpCBStd. J
4o 4.25e3
41.17-46.41
42.0
43.0
44.0
45.0
J1 o.OOeO
Abs. Int.
-5.21e4
2.60e4
46.0
Rel. Int.
100%-
Fn 6
407,8398
HpCB Std.
4o4,11e3
41,17-46.41
2.53e4
41.74
Abs. Int.
-I.93e4
9.65e3
OOeO
Rel. Int.
100%-,
Fn 6
404.9760
QC Check
41.17-46.41
Q%-
,MT	T	|	T	I""
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-2.11e7
• 1,05e7
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_S042 PCB\resources\SBS_OB0724_PCB_ VB ulp res, saved 24-Jul-ZOOS 13:49 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 6296, 1085
Peak annotation: Areas, Centroids
PKO 24-Jul-2008 13:43:36 Printed: 0S-Aug-2008 06 29:10 Page 18 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-20Q8 06:42:15
User: JLJ Datafile: 080724V08_EQ
Re). Int.
100%
Fn 5
427.7635
OcCB-5
4o1.01e3
34.16-41.15
Rel. Int.
100%
Fn 5
429.7606
OcCB-5
40 1.1Se3
34,16-41.15
Abs. Int.
-2 62e4
1.31e4
O.OOeO
I.QSeS
37.11
1.04e5
Abs. Int.
-2,93e4
1 47e4
	O.OOeO
41.0 RT
Rel. Int.
100%
Fn 5
439.8038
OcCB Std,
4o 1.16e3
34.16-41.15 H

—r——r——
35.0
36.0
37.0
i i y t t » »
38.0	39.0

Abs. Int.
-1.12e4
•5.59e3
l.OOeO
40.0
41.0 RT
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std.
4a 1 22e3
34.16-41,15
0%-
35.0
" | I I I I | I ! ! 1 | 1 I I 1 | I 8 I 1 | * I I I | I
36 0	37.0	38.0
-j—i—i—i—i—|—i—r-
39.0
Abs. Int.
-9.77e3
4.89e3
OOeO
40.0
410 RT
Rel. Int.
100%-
Fn 5
454,9728
QC Check
34.16-41.15 J
0%-
f f % [ I f
35 0
' ' I
36.0
37.0
' ' I ' * ' ' I 1
38.0
39.0
—r—r—i—|—r-
' I '
40.0
Abs. Int.
-1.97e7
•9.84e6
¦O.OOeO
41.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\SBS_080724_PCB_\/8.utp_res,-save(1 24-M-2008 13:49 (EE)
AP UltmTmce-Pro ^3.993 User/System EE/BEC2-038 cc: 1721. 7424
Peak annotation: Areas, Centroids
PKD: 24-Juf-20Q8 13:49:37 Printed 05-Aug 2008 08:29:11 Page 19 of 22
-------
AP Lab ID: SBS_08Q724_PCB_VB
Instr; AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel, Int.
100%
Fn 6
427.7635
OeCB-6
4o 1.03e3
41.17-46.41
Abs. Int.
-3.03e3
1.52e3
O.OOeO
Rel. Int.
100%
Fn 6
429.7606
OcCB-6
40 1.14e3
41.17-46.41
Abs. Int.
-4.64e3
2.32e3
O.OOeO
RT
Rel. Int.
100%
Fn 6
439.8038
OcCB Std.
4o1.91e3
41.17-46.41
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-9.63e3
-4.82e3
f-O.OOeO
RT
Rel. Int.
100%
Fn 6
441.8008
OcCB Std
4o 2.08e3
41.17-46.41 ¦
1.09e4
42.64

42.0
43.0
44.0
45.0
46.0
Abs. Int.
-2.39e4
1.20e4
O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41,17-46.41'
Q%-
42.0
43.0
44.0
45.0
Results: P:\P9400_P9499\P9464_6042 PCBVesources\SBS_080724 PCB V8 utp_res. saved 24-Jut-2008 13:49 (EE)
AP UitmTrace-Pm V3.993 User/System: E&EEC2-038 cc: 0213, 0690
46.0
Abs. Int.
i-2.11e7
l.05e7
•O.OOeO
RT
Peak annotation: Areas. Centroids
PKD: 24-Jul-200B 13:49:37 Printed: OS-Aug-2008 08 29 12 Page 20 of 22
-------
AP Lab ID: SBS_080724_PCB_VB
Instr; AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cI1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel, Int.
100%-
Fn 6
461,7245
NoCB
4a 9.54e2
41.17-46.41
0%-
42.0
43.0
44.0
1—I—
45.0
46.0
Abs. Int.
-4.21 e3
¦2.10e3
¦O.OOeO
RT
Rel. Int.
100%
Fn 6
463.7216
NoCB
4o 1.74e3
41.17-46.41
42.0
43.0
44,0
45.0
46.0
Abs. Int.
-4.91e3
2.45e3
O.OOeO
RT
Rel. Int.
100%'
Fn 6
473.7648
NoCBStd.
4o 1.83e3
41.17-46 41
Abs. Int.
-7.67e3
3.83e3
OOeO
Rel. Int.
100%-
Fn 6
475.7619
NoCB Std.
4a 1 24e3
41.17-46.41
0%-
I I I
42.0
I I I
43.0
I T I
44,0
45.0
-1—'—<-
46.0
Abs. Int.
-6.94e3
•3.47e3
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41 "
Abs, Int.
-2.11e7
•1 Q5e7
0%-
42.0
1—I—1
43.0
—t	1 -I-
44,0
T—T—T"
""F	f	r"
	*	*	
45,0
46.0
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\msources\S8S_D80?24_PCB_V8.utp_Hl$, saved 24-Jut-20O8 13:49 (EE)
AP UHraTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 5611. 4070
Peak annotation: Areas. Centmids
PKD: 24-M-2008 13:49:37 Printed: 05-Aug-2O08 08:29:14 Page 21 of 22
-------
AP Lab ID: SBS_080724_PCi_VB
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIRexpt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 06:42:15
User: JLJ Datafile: 080724V08 EQ
Rel. Int.
100%
Fn 7
497.6826
DeCB
4o 7.07e2
46.42-54,01
47.0
4B.0
49.0
50.0
51.0
52,0
53.0
Abs, Int.
2.81 e3
1,40e3
O.OOeO
54.0 RT
Rel. Int.
100%
Fn 7
499.6797
DeCB
4a 9.39e2
46.42-54.01
49.0
50.0
51.0
Abs. Int.
-3.51e3
l.75e3
-O.OOeO
54.0 RT
Rel, Int.
100%
Fn 7
509.7229
DeCB Std.
4o 6 58e2
46.42-54.01
Abs. Int.
-3.34e3
1.67e3
O.OOeO
54.0 RT
Rel. Int.
100%
Fn 7
511.7199
DeCB SW.
4o 5.22e2
46.42-54.01
I 1 1 1 1 I
47.0
48,0
49,0
50.0
51.0
52.0
53.0
Abs. Int.
-3.25e3
1 63e3
O.OOeO
54.0 RT
Rel. Int.
100%
Fn 7
454.9728
QC Check
46.42-54,01
50.0
Abs. Int.
-2.04e7
1.02e7
O.OOeO
54.0 RT
Results: P:)P9400_P9499\P9464_6042 PCB\fesources\SBS_Q80724_PCB_\/B.utp_res, saved 24-Ju(-2008 13:49 (EE)
AP UltraTrace-Pm V3.993 User/System: E6CEC2-038 cc: 0024, 7191
Peak annotation: Areas, Centmitis
PKD: 24-Jul-2008 13:49:3? Printed: OS-Aug-2008 08:29; J5 Page 22 of 22
-------
Datafile: 080801 R19.EQ
Acquired: 01 Aug 2008 22:32:34
Client ID: Run# I-ACD-M23-3 i/	Wt/Voi: 1
Lab ID: P9464_6042_PCB_004RJ-D10 A-level: 20 pg

6042 PCB_RCD CPSM 060801 PCB RB
Nominal ES spike: 4000 pg
P9464_6042_PCB_004RJ-D10
Name
PCB-77 33'44'-TeCB
PCB-ai 344'5-TeCB
PCB-105 233"44'-PeCB
PCB-114 2344'5-PeCS
PCB-118 23'44'5-PeCB
PCB-123 2'344'5-PeCB
PCB-12S 33'44'5-PeCB
PCB-156/157 233'44'5/233'44'
PCB-167 23'44'55'-HxCB
PC3-169 33'44'55"-HxCB
PCB-189 233'441551-HpCB
PCB-209 DeCB
ES
ES
PCB-
PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES
ES
ES
PCB-
PCB-
PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
ES
ES
PCB-
PCB-
ES	PCB-
ES	PCB
ES	PCB-
ES	PCB-
ES	PCB-
ES	PCB-
¦1
3
4
¦15
19
37
¦54
¦77
81
104
105
114
118
123
126
153
155
156/157
167
169
170
180
188
189
202
205
206
208
209
Actual
RT
31.79/
31-32 /
34.77/
34.23X
33.77X
33.49 /
37.37/
39.90/
38.94
42.62
44.74/
49.72
~
11.25 -
13.44 '
13.68 ""
19.25 ^
16.66-
25.48"
19.53'
31.77 ~
31.30 *
24.43 ~
34.74
34.20
33.75.
33.47 X
37.35
35.33	«-
29.35 ^
39.89 -
38,92 ~
42.60
41.06 ^
42.11 ~
34.20 ^
44.72	^
38.73	—
46.88 ^
48.34
44.34 "
49.70 ""
QC
/
Pred
RUT
Actual
RRT
Di££
Sees
Response
Ra
^CJ>3
RRF
Cone
Checkcode .-
Noise
DL
1.0006
1.0006
0
4.72E+07
0
77
0
98 .
03
10,300
1.07E+04
23.8
1.0006
1.0006
0
6.85E+06
0
75
1
1, 570
1.07E+04
24.1
1.0007
1.0007
0
1.03E+07
0
61
0
90
2,720
9.15E+03
25.8
1.0007
1.0006
-0.2
1.70E+06
0
64
0
90
439
9.15E+03
24.2
1.0007
1.0007
0
1.21E+07
0
62
0
90 /
3,090
9.15E+03
24
1.0007
1.0007
0
2.02E+06
0
59
0
91
546
9.15E+03
26.4
1.0005
1.0005
0
1.67E+07
0
62
0
90
4,230
5.66E+03
15.7
1.0005
1.0003
-0.5
8.61E+06
1
29
0
97
2,530
3.97E+Q3
15.6
1.0006
1.0005
-0.2
2.81E+06
1
24
0
99
811
3.97E+Q3
11.3
1.0005
1.0005
0
2.48E+06
1
28
0
93 /
772
3.97E+03
12.9
1.0004
1.0004
0
2.43E+06
1
01
0
84 »
836
3.61E+03
13.1
1.0004
1.0004
0
2.25E+06
1
13
0
91
919
2.18E+03
10
ate
0.7213
0.7216
+ 0.2
2.03E+07
3.06
1.06 J
1.00
-B0.9 25%
150%
0.8616
0.8616
0
2.04E+07
3.35
86.3 %
25%
150%
0.8771
0.8774
+0.2
1.56E+07
1.55
0.77
84.8 %
25%
150%
1.2330
1.2341
+ 1.3
2.30E+07
1.56
0.94
103 %
25%
150%
1.0684
1.0685
+0.1
1.43E+07
1.05
0.67
90.7 %
25%
150%
1.0809
1.0810
+ 0.2
1.87E+07
1.06
0.99
103 %
25%
150%
0.8279
0.8284
+0.6
1.54E+07
0.80
1.00
84.1 %
25%
150%
1.3474
1.3478
+0.8
1.85E+07
0.79
0.88
115 %
25%
150%
1.3274
1.3277
+0.6
1.68E+07
0.82
0.84
110 %
25%
150%
0.8277
0.8274
-0.4
1.63E+07
1.56
1.28
82.1 %
25%
150%
1.1769
1.1770
+0.2
1.68E+07
1.55
1-19/
1.17
91.5 %
25%
150%
1.1587
1.1587
0
1.72E+07
1.58
94.6 %
25%
150%
1.1432
1.1432
0
1.74E+07
1.59
1.23
91.3 %
25%
150%
1.1338
1.1338
0
1.63E+07
1.55
1.13
93.5 %
25%
150%
1.2652
1.2653
+0.2
1.75E+07
1.64
1.20
94.2 %
25%
150%
0.9711
0.9711
0
1.48E+07
1.31
1.15
96.2 %
25%
150%
0.8067
0.8066
-0.2
1.84E+07
1.27
1.47
93.4 %
25%
150%
1.0964
1.0964
0
2.82E+07
1.23
1.31
80.3 %
25%
150%
1.0696
1.0696
0
1.40E+07
1.19
1.25
84.2 %
25%
150%
1.1709
1.1709
0
1.39E+07
1.28
1.33
78.3 %
25%
150%
0.8833
0.8832
-0.2
1.26E+07
1.11
1.13
105 %
25%
150%
0.9060
0.9060
0
1.03E+07
1.06
0.91
107 %
25%
150%
0.7359
0.7358
-0.2
1.50E+07
1.07
1.18
94.9 %
25%
150%
0.9621
0.9621
0
1.39E+07
1.01
1.30
101 %
25%
150%
0.8332
0.8331
-0.2
1.32E+07
0.90
1.20
82.7 %
25%
150%
1.0086
1.0086
0
1.16E+07
0.90
1.11
98.2 %
25%
150%
1.0400
1.0400
0
8.07E+06
0.80
0.79 /
96.2 %
25%
150%
0.9539
0.9538
-0.3
1.1QE+Q7
0.79
1.07 y
96.7 %
25%
150%
1.0692
1.0692
0
1.08E+07
1.20
1.06
96.1 %
25%
150%
Analytical Perspectives
Page 1 of 5
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_004RJ-D10
Name
SS PCB-28
SS PCB-111
SS PCB-178
CS
CS
CS
PCB-28
PCB-111
PCB-178
Actual
RT
21.97 .
31.80 '
3-6.76

QC
Pred
RRT
0.9320
1.0774
1.0105
21.97
31.80
36.76
0.9320
1.0774
1.0105
JS	PCS-9
JS	PCB-52
JS	PCB-101
JS	PC8-138
JS	PCB-194
15.60^
23.57''
29. 52"
36.38'
46.49^
Checkcode:
HP

PCB-1 2-MoCB
11.27
1.0011
PCB-2 3-MoCB
13.27
0.9879
PGB-3 4-MoCB
13.45
1.0010
PCB-4 22'-DiCB
13.70
1.0011
PCB-10 26-DiCB
13.87
1.0138
PCB-9 25-DiCB
15.61
1.0010
PCB-7 24-DiCB
15.77
1.0113
PCB-6 23'-DiCB
15.99
1.0254
PGB-5 23-DiCB
16.28
1.0441
PCB-8 24'-DiCB
16.40
1.0516
PCB-14 35-DiCB
17.92
0.9319
FCB-U 3 3'-DiCB
18.69
0.9715
PCB-13/12 341-/34-DiCB
18.99
0.9863
PCB-15 44'-DiCB
19.26
1.0008
PCB-19 22"6-TrCB
16.68
1.0011
PCS-30/18 246-/22'5-TrCB
18.41
1.1044
PCB-17 22'4-TrCB
18.80
1.1279
PCB-27 23'6-TrCB
19.00
1.1393
PCB-24 236-TrCB
19.12
1.1471
PCB-16 22'3-TrCB
19.22
1.1527
Analytical Perspectives
Actual
RRT
0.9319
1.0774
1.0105
0.9319
1.0774
1.0105
Dif £
Sees
-0.1
0
0
Response
1.96E+07
1.96E+07
9.73E+06
1.96E+07
1.96E+07
9.73E+06
Ra
1.07
1.57
1.07
1.07
1.57
1.07
RRF
i.07y
1.18
0.66
1.05
1.33
0.78
/
Cone
98.4 %
102 %
97.9 %
102 %
95.4 %
93 %
Checkcode:
Noise
30%
30%
30%
30%
30%
30%
mP '
DL
135%
135%
135%
135%
135%
135%
2.37E+07
1.83E+07
1.55E+07
1.34E+07
1.06E+07
1.59
0.78
1.57
1.30
0.89
Totals
NQN-EMPC
EKPC
DL
Mono-CBs
155
000
155,000
9.32
Di-CBs
111
000
111,000
18.9
Tri-CBs
71
600
71,600
16.7
Tetra-CB:
80
800
82,900
17.1
Penta-CB:
29
700
30,700
20.3
Hexa-CBs
18
600
18,800
11.3
Hepta-CB:
31
500
31,600
13.1
Octa-CBs
25
100
25,100
9.07
Nona-CBs
4, 580
4,580
3,6.8
1.0011
0
1.01E+08
3.08
1
09-^
18,400^
Jg.87E+03
8.3
0.9879
0
3.94E+08
3.10
1
01
76,400
7.87E+03
11.2
1.0010
0
3.37E+08
3.11
1
09 ^
60,300
7.87E+03
10.3
1.0011
0
5.70E+06
SI*
0
98
1,490
8.74E+03
16.7
1.0136
-0.2
2.50E+06
SI*
1
55
413
8.74E+03
10.6
1.0009
-0.1
1.08E+07
SI*
0
94
1, 990
1.06E+04
20.4
1.0113
0
4.17E+07
SI*
0
90
8, 020
1.06E+04
21.3
1,0254
0
3.06E+07
SI*
0
89
5, 940
1.06E+04
21.5
1.0441
0
3 .62E+07
SI*
0
87
7,190
1.06E+04
22
1.0516
0
2.37E+07
SI*
0
91
4,510
1.06E+04
21
0.9313
-0.6
3.45E+07
SI*
1
02
5,880
1.06E+04
18.9
0.9711
-0.4
6 .00E+Q7
SI*
0
87
12,000
1.06E+04
22.2
0.9868
+ 0.6
2.86E+08
SI*
0
85
58,600
1.06E+04
22.7
1.0008
0
2.65E+07
SI*
0
92
5, 020
1.06E+04
21
1.0011
0
1.40E+06
1.04
0
91
427
4.96E+03
13 .2
1.1051
+ 0.8
8.97E+06
1.05
1
03
2, 420
4.96E+03
11.7
1.1283
+ 0.5
6.78E+06
1,08
0
89
2,130
4.96E+03
13.5
1.1400
+ 0.8
2.67E+06
1.08
1
22
608
4.96E+03
9. 82
1.1476
+0.6
2.01E+06
1.01
1
20
465
4.96E+03
10
1.1533
+0.7
6.82E+06
1.05
0
69
2,760
4.96E+03
17.5
Page 2 of 5
Printed: 08 06 2008 1.22 PM
-------
P9464_6042_PC8_004RJ-D10
Name
Actual
RT
QC
Fred
RRT
Actual
RRT
PCB-32
24'6-TrCB
19.70
1.1809
1.1822
PCB-34
2'35-TrCB
20,83
0.8174
0.8173
PCB-23
235-TrCB
20.97
0.8231
0.8229
PCB-26/29 23'5-/245-TrCB
21.25
0.8341
0.8338
PCB-25
23'4-TrCB
21.44
0.8417
0.8415
PC8-31
24'5-TrCB
21.72
0.8525
0.8523
PCB-28/20 244'-/233'-TrCB
22.00
0.8634
0.8632
PCB-21/33 234-/2'34-TrCB
22.19
0.8703
0.8706
PCB-22
234'-TrCB
22.55
0.8848
0.8847
PCB-36
33'5-TrCB
23.92
0.9386
0.9385
PCB-39
34•5-TrCB
24.23
0.9510
0.9509
PCB-38
345-TrCB
24.75
0.9715
0.9714
PCB-35
33'4-TrCB
25.15
0.9868
0.9868
PCB-37
344'-TrCB
25.50
1.0007
, 1.0007
PCB-54
22'66'-TeCB
19.55
1.0010
1.0011
PCB-S0/S3 22'46-/22'56'TeCB
21.48
0.9119
0.9112
PCB-45
22'36-TeCB
NotFnd
0.9362
-
PCB-51
22'46"-TeCB
22 .14
0.9393
0.9393
PCB-46
22'36'-TeCB
22.35
0.9481
0.9479
PCB-52
22'55'-TeCB
23 .60
1.0010
1.0010
PCB-73
23'5'6TeCB
23.73
1.0065
1.0065
PCB-43
22'35-TeCB
23.81
1.0103
1.0102
PCB-69/49 23'46-/22'45'TeCB
24.03
1.0185
1.0192
PCB-48
22'45-TeCB
24.29
1.0303
1.0303
PCB-44/47/65 22'35'-/22'44 ' -
24.52
1.0393
1.0400
PCB-59/62/75 233'6-/2346-/24
24.77
1.0510
1.0506
PCB-42
22'34*-TeCB
24.94
1.0578
1.0578
PCB-41
22'34-TeCB
25.27
1.0717
1.0718
PCB-71/40 23'4'6/22*33'-TeCB
25.36
1.0758
1.0759
PCB-64
234'6-TeCB
25.56
1.0841
1.0842
PCB-72
23'55'-TeCB
26.28
0.8397
0.8396
PCB-68
23'45'-TeCB
26. 53
0.8478
0.8477
PCB-57
233'5-TeCB
26.90
0.8595
0.8594
PCB-58
233'5'-TeCB
27.10
0.8659
0.8657
PCB-67
23'45-TeCB
27.25
0.8709
0.8708
PCB-63
234'5-TeCB
27.48
0.8780
0.8780
PCB-61/70/74/76 2345-/23'4'5
27.78
0.8872
0.8874
PCB-66
23'44'-TeCB
28.05
0.8961
0.8962
PCB-55
233'4-TeCB
28.19
0.9007
0.9006
PCB-56
233'4'-TeCB
28.62
0.9145
0.9144
PCB-60
2344'-TeCB
28.81
0.9206
0.9205
PCB-80
33'55'-TeCB
29.15
0.9314
0.9313
PCB-79
33'43'-TeCB
30.46
0.9732
0.9731
PCB-78
33'45-TeCB
30.93
0.9886
0.9882
PCB-104
22'466'-PeCB
24.45
1.0009
1.0009
PCB-96
22'366'-PeCB
24.76
1.0136
1.0137
PCB-103
22'45'6-PeCB
26.45
0.8961
0.8960
Analytical Perspectives
Page 3 of 5
Diff




Checkcode.*
Hp •
Sees
Response
Ra
RRF
Cone
Noise
DL
+1.5
5.91E+06
1.06
1.28
1,280
4.96E+03
9.39
-0.1
4.04E+06
1.02
1.13
770
8.74E+03
17.3
-0.3
4.12E+06
1.04
1.06
834
8.74E+03
18.3
-0.4
1.60E+07
1.03
1.13
3,030
8.74E+03
17.2
-0.3
1.32E+07
1.04
1.25
2,270
8.74E+03
15.6
-0.3
1.63E+07
1.05
1.16
3,030
8.74E+03
16.8
-0.3
3.96E+07
1.03
1.13
7, 500
8.74E+03
17.2
+ 0-4
3.88E+07
1.04
1.10
7, 540
8.74E+03
17.6
-0.1
1.56E+07
1.03
1.09
3,060
8.74E+03
17.8
-0.1
1.17E+07
1.12
1.14
2,200
8.74E+03
17
-0.1
8.61E+06
1.05
1.12
1,650
8.74E+03
17.4
-0.1
1.92E+07
1.08
1.04
3,970
8.74E+03
18.7
0
6.44E+07
1.03
1.04
13,300
8.74E+03
18.8
0
5.52E+07
1.04
0.96
12,400
8.74E+03
20.3
+0.1
1.57E+05
0.83
1.18
34.5
3.G1E+03
7.39
-0.9
1.67E+06
0.74
0.93
428
5.97E+03
15

0.OOE+OO

0.71

5.97E+03
19.5
0
4.49E+07
0.78
1.00
10,600
5.97E+03
13.9
-0.3
7.76E+05
0.73
0.73
251
5.97E+03
18.9
0
6.16E+06
0.77
0.91
1,610
5.97E+03
15.3
0
4.50E+05
0.72
1.17
91.6
5.97E+03
11.9
-0.1
1.09E+06
0.75
0.71
365
5.97E+03
19.5
+1.0
7.60E+06
0.76
1.05
1,720
5.97E+03
13.2
0
2.59E+06
0.75
0.86
716
5.97E+03
16.2
+1.0
5.70E+07
0.77
0.92
14,700
5.97E+03
15
-0.6
5.16E+06
0.75
1.19
1,040
5.97E+03
11.7
0
3.54E+06
0.79
0.80
1,050
5.97E+03
17.3
+ 0.2
2.11E+06
0.80
0.73
685
5.97E+03
19
+0.2
7.0OE+O6
0-79
0.93
1,780
5.97E+03
14.9
+ 0.2
4.60E+06
0.78
1.24
885
5.97E+03
11.2
-0.2
1.71E+06
0.76
1.05
388
1.07E+04
23.8
-0.2
4.20E+07
0.77
1.09
9,150
1.07E+04
22.8
-0.2
3.72E+06
0.78
1.01
871
1.07E+04
24.5
-0.3
2.91E+06
0.75
0.99
695
1.07E+04
25.1
-0.2
6.16E+06
0.78
1.09
1,350
1.07E+04
22.9
0
2.95E+06
0.76
1.07
655
1.07E+04
23.2
+0.3
2.48E+07
0.77
1.02
5,770
1.07E+04
24.4
+ 0.2
1.61E+07
0.76
1.03
3,710
1.07E+04
24.2
-0.2
5.52E+06
0.78
0.94
1,400
1.07E+04
26.5
-0.2
1.95E+07
0.77
1.01
4, 590
1.07E+04
24.6
-0.2
5.16E+06
0.78
1.00
1,230
1.07E+04
24.9
-0.2
1.60E+06
0.77
1.08
352
1.07E+04
23.1
-0.2
1.33E+07
0.75
1.13
2,790
1.07E+04
22
-0.7
0
+ 0.1
-0.2
8.3 5E+06 |
0.93
[ 0.94
2, 120
34.9
92.6
86.6
1.07E+04
2.53E+03
2.53E+03
9.15E+03
26.6
5.87
6.92
31.4
1.50E+05
0.64
1.06
3.37E+05 |
0.74
| 0.89
2.69E+05
0.63
0.76
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_004RJ-D10
Name
Actual
RT
QC
Pred
RRT
Actual
RUT
PCB-94 22'3 56'-PeCB
26,63
0.9024
0.9022
PCB-95 22"35"6-PeCB
27.01
0.9151
0.9151
PCB-100/93 22'4416-/221356-P
27,22
0.9224
0.9220
PCB-102 22'456'-PeCB
27.33
0.9262
0.9260
PC3-98 22 ' 3 '46-PeCB
27.40
0.9284
0.9281
PCB-88 22'346-PeCB
27.68
0.9385
0.9379
PCB-91 22'34'6-PeCB
27.76
0.9407
0.9404
PCB-84 22'33'6-PeCB
27.95
0.9469
0.9468
PCB-89 22'346'-PeCB
28,36
0.9610
0.9608
PCB-121 23'45'6-PeCB
28.72
0.9730
0.9728
PCB-92 22'355'-PeCB
29-03
0.9837
0.9836
PCB-113/90/101 233'5* 6-/22'3
29.53
0.9999
1.0005
PCB-83 22'33'5-PeCB
29.94
1.0143
1.0143
PCB-99 22'44'5-PeCB
30.05
1.0176
1.0178
PCB-112 233156-PeCB
30.14
1.0211
1.0212
PCB-108/119/86/97/125/87 233
30.48
1.0328
1.0326
PCB-117 234'56-FeCB
KotFnd
1.0506
-
PCB-116/85 23456-/22'344'-Pe
31.07
1.0536
1.0525
PCB-110 233*4'6-PeCB
31.23
1.0577
1.0580
PCB-llf) 2344'6-PeCB
NotFnd
1.0605
-
PCB-82 22'33'4-PeCB
31. 50
1.0671
1.0671
PCB-111 233"55'-PeCB
31.83
1.0782
1.0782
PCB-120 23'455'-PeCB
32.22
1.0915
1.0915
PCB-107/124 233'415-/2'3455"
33.18
0.9913
0.9914
PCB-109 233'46-PeCB
33.39
0.9976
0.9977
PCB-106 233145-PeCB
33.60
1.0039
1.0038
PCB-122 2'33'45-PeCB
34.06
1.0093
1.0092
PCB-127 33'455'-PeCB
36.01
1.0363
1.0363
PCB-155 22'44'66'-HxCB
29.37
1.0007
1.0008
PCB-152 22'3566'-HxCB
29,53
1.0060
1.0061
PCB-150 22'34'66'-HxCB
29. 67
1.0109
1.0111
PCB-136 22'33'66'-HxCB
29.97
1.0210
1.0211
PC3-145 22'3466'HxCB
30.24
1.0302
1.0303
PCB-148 22'34'56'-HxCB
31.51
1.0738
1.0738
PCB-151/135 22'355'6-/22'33'
32.03
1.0913
1.0913
PCB-154 22'44"5'6-HxCB
32.24
1.0985
1.0985
PCB-144 22'345'6-HxCB
32.50
1.1073
1.1074
PCB-147/149 22'34'56-/22'34'
32.80
1.1175
1.1175
PCB-134 22'33'56-HxCB
32.97
1.1234
1.1236
PCB-143 22'3456'-HxCB
33.06
1.1262
1.1264
PCB-)3 9/14 0 22'344'6-/22'344•
33.31
1.1351
1.1351
PCB-131 22'33'46-HxCB
33.48
1.1408
1.1410
PCB-142 22'3456-HxCB
33.62
1.1456
1.1456
PCB-132 22'33'46'-HxCB
33.86
1.1537
1.1538
PCB-133 22'33'55'-HxCB
34.28
1.1679
1.1680
PCB-165 233'55*6-HxCB
34.62
0.9514
0.9515
PCB-146 22'34'55'-HxCB
34.83
0.9573
0.9573
Analytical Perspectives
Page 4 of 5
Diff





Checkcocie:
MP
Sacs
Response
Ra
RRF
Cone
Noise
DL
1
o
t/J
2.09E+05
0.70
0
65
76.5
9.15E+03
36,6
0
3.02E+06
0.68
0
71
1,040
9.15E+03
33.8
-0.7
8,96E+05
0.67
0
74
297
9.15E+03
32.3
-0.3
4.28E+05
0.66
0
74
143
9.15E+03
32.6
-0.5
2.93E+05
0.67
0
64
112
9.15E+03
37.2
-1.0
2.73E+05
0.53
0
72
93.2
9.15E+03
33.3
-0.5
2.47E+06
0,59
0
66
920
9.15E+03
36.3
-0.2
1.23E+06
0.65
0
60
502
9.15E+03
39.8
-0.3
3.58E+05
0.64
0
64
137
9.15E+03
37.2
-0.3
3.83E+05
0.63
0
95
98.7
9.15E+03
25.1
-0.2
9.91E+05
0.64
0
69
353
9.15E+03
34.7
+1.1
6.65E+06
0.61
0
79
2,060
9.15E+Q3
30.2
0
1.63E+06 |

0
53
754
9.152+03
45.1
+0.4
3.59E+06
0.63
0
80
1.100
9,15E+03
29.8
+0,2
6,35E+05 |
0.51
0
93
167
9.15E+03
25.6
-0.4
8.53E+06
0.58
0
79
2,640
9.15E+03
30.2

O.OOE+OQ

0
87

9.15E+03
27.4
-2.1
2.32E+06
0.58
0
78
726
9.15E+03
30.5
+0.6
0.55E+06
0,61
0
89
2, 370
9.15E+03
27

O.OOE+OO

0
96

9.15E+03
25.1
0
1.85E+06
0.60
0
56
809
9.15E+03
42 .6
0
1.01E+06
0.60
0
95
263
9.15E+03
25.3
0
1.71E+06
0.64
0
96
436
9.15E+03
24.9
+0.2
2.92E+06
0.59
0
93
772
9.15E+03
25.8
+0.2
6.19E+06
0.62
0
99
1, 540
9.15E+03
24.2
-0.2
2.05E+06
0.65
0
91
557
9.15E+03
26.5
-0.2
3.20E+06
0.62
0
84
888
9.15E+03
26
0
2.23E+06
0.60
0
88
603
9.1SE+03
26.5
+0.2
1.47E+05
1.28
1
04
30-7
2.52E+03
5.24
+0.2
2.12E+05
1.23
0
98
47
2.52E+03
5.55
+0.4
4.51E+05
1.25
0
94
104
2,52E+03
5.77
+0.2
1.21E+06
1.28
0
92
285
2.52E+03
5.89
+0.2
2.64E+05 |
1.47
0
92
62.5
2.52E+03
5.92
0
3.48E+05
1.10
0
90
105
2.52E+03
7.52
0
2.56E+06
1.24
0
91
763
2 .522+03
7.44
0
5.76E+05
1.21
1
05
148
2.52E+03
6.41
+0.2
6.59E+05
1.37
0
94
189
2.52E+03
7.16
0
5.11E+06
1.27
0
94
1,460
2.52E+03
7 .13
+0.4
6.13E+05
1.24
0
79
211
2.52E+03
8. 58
+0.4
2.53E+05
1.12
0
83
82.2
2.52E+03
8.1
0
1.33E+06
1.31
0
92
392
2.52E+03
7.35
+0.4
6.99E+05
1.20
0
78
242
2.52E+03
8. 64
0
2.OOE+05 |
1.00
0
80
67.9
2.52E+03
8.47
+0.2
2.18E+06
1.24
0
83
712
2.52E+03
8.15
+0.2
3.97E+05
1.17
0
86
125
2.52E+03
7. 85
+0.2
3.56E+05 |
1.01
1
09
87.9
2.52E+03
6.16
0
1.91E+06
1.18
0
98
529
2.52E+03
6 . 89
Printed: 08 06 2008 1:22 PM
-------
P9464_6042„FCB_004RJ-D10
Actual

Fred
Actual
Name

RT
QC
HRT
RRT
PCB-161
233 *45"6-HxCB
34.95

0.9605
0.9606
PCB-153/168 22'441551-/23'44"
35.36

0.9722
0.9717
PCB-141
22'3455'-HxCB
35.51

0.9761
0.9761
PCB-130
22'33'45'-HxCB
35.86

0.9855
0.9857
PCB-137
22'344'5-HxCB
36.05

0.9910
0.9909
PCB-164
233'4'5'6-HxCB
36.14

0.9933
0.9933
PCB-163/138/129 233'4'56-/22'
36.41

1.0011
1.0009
PCS-160
233'456-HxCB
36. 56

1.0048
1.0047
PCB-158
233'44'6-HxCB
36.74

1.0098
1.0098
PC3-128/166 22 ' 33 ' 44"-/2344'5
37.47

0.9629
0.9630
PCB-159
233'455'-HxCB
38.29

0.9840
0.9839
PCB-162
233'4'55'-HxCB
38.53

0.9902
0.9901
PCB-188
221341566'-HpCB
34.23

1.0006
1.0006
PCB-179
22'331566'-HpCB
34.50

1.0087
1.0087
PCB-184
22'344'66'-HpCB
34.96

1.0222
1.0222
PCB-176
22'33'466'-HpCB
35.25

1.0306
1.0306
FCB-186
22'34566'-HpCB
35.65

1.0421
1.0422
PCB-178
22'33'55'6-HpCB
36.78

1.0754
1.0754
PCB-175
22 ' 33'45'6-HpCB
37.33

1.0913
1.0913
PCB-187
22'34'55'6-HpCB
37.56

1.0979
1.0980
PCB-182
22"344'56'-HpCB
37.73

1.1031
1.1031
PCB-183
22"344'5'6-HpCB
38.08

1.1132
1.1132
PCB-185
22'3455'6-HpCB
38.16

1.1155
1.1156
PCB-174
22'33'456'-HpCB
38.27

1.1187
1.1188
PCB-177
2213314'56-HpCB
38.64

1.1296
1.1296
PGB-181
221344'56-HpCB
38.98

1.1397
1.1397
PCB-171/173 22 *33 *44'6-/22'3
39.17

1.1450
1.1452
PCB-172
22'3 3'455'-HpCB
40.52

0.9061
0.9061
PCB-192
233'455'6-HpCB
40.76

0.9116
0.9115
PCB-180/193 22'344'55'-/233'
41.07

0.9178
0.9184
PCB-191
233'44'5'6-HpCB
41.37

0.9251
0.9250
PCB-170
22-33-44'5-HpCB
42.13

0.9421
0.9421
PCB-190
233'44'56-HpCB
42 .58

0.9522
0.9522
PCB-202
22'33'55'66'-OcCB
38.75

1.0006
1.0006
PCB-201
22'33'45'66'-OcCB
39.53

1.0207
1.0208
PCB-204
22-344'566'-OcCB
40.10

1.0356
1.0356
PCB-197
22*33 *44'66'-OcCB
40.30

1.0406
1.0406
PCB-200
22*33'4566'-OcCB
40,38

1.0427
1.0428
PCB-198/199 221331455'6-/22'
42.72

1.1027
1.1032
PCB-196
22'33'44*56'-OcCB
43.28

1.1175
1.1176
PCB-203
22'344155'6-OcCB
43.45

1.1218
1.1219
PCB-195
32'33'44'56-OcCB
44. 56

0.9504
0.9504
PCB-194
22'33'44'55'-OcCB
46.51

0.9919
0.9919
PCS-2OS
233*44*55'6-OcCB
46 .90

1.0004
1.0004
PCB-208
22'33'455'66*-NoCB
44 .36

1.0005
1.0005
PCB-207
22'33'44'566--NoCB
45.15

1.0182
1.0182
PCB-206
22'33'44'55'6-NoCB
48.36

1.0004
1.0004
Analytical Perspectives
Page 5 of 5
Diff
Checkcode:

Sees
Response
Ra
RBF
Cone
Noise
DL
+0.2
6.26E+05
1.42
1.17
144
2.52E+03
5.74
-1.1
7.08E+06
1.21
1.24
1,540
2.52E+03
5.44
0
1.69E+06
1.22
0.86
528
2.52E+03
7.79
+0.4
1.37E+06
1.28
0.80
465
2.52E+03
8.45
-0.2
1.04E+06
1.21
0.94
299
2.52E+03
7.13
0
2.08E+06
1.30
1.16
487
2.52E+03
5.82
-0,4
1.07E+07
1.24
0.95
3,020
2.52E+03
7.05
-0.2
5.22E+05
1.09
1.08
130
2.52E+03
6.22
0
5.16E+06
1.24
1.31
1,070
2.52E+03
5.16
+ 0.2
1.63E+06
1.27
0.82
568
3.97E+03
13.6
-0.2
1.14E+06
1.22
0.95
343
3.97E+03
11.7
-0.2
1.54E+06
1.22
0.97
454
3.97E+03
11.5
0
3.44E+05
1.03
1.05
87.4
2.30E+03
6.02
0
2.26E+06
1.05
0.94
641
2.30E+03
6.74
0
5.57E+05
1.10
0.93
159
2.30E+03
6.8
0
1.65E+06
1.01
0.98
449
2.30E+03
6.46
+ 0.2
1.88E+05
1.17
0.94
53.5
2.30E+03
6.76
0
1.38E+06
1.04
0.69
533
2.30E+03
9.18
0
1.01E+06
1.00
1.05
372
4.12E+03
16.1
+ 0.2
9.09E+06
1. 07
1.08
3,270
4.12E+03
15.7
0
4.87E+05
1.03
1.14
165
4.12E+03
14.8
0
4.67E+06
1.07
1.18
1, 540
4.12E+03
14 .4
+ 0.2
9.59E+05
0.99
1.00
372
4.12E+03
16.9
+ 0.2
9.68E+06
1.04
0.98
3, 840
4.12E+03
17.2
0
4.53E+06
1.01
0.96
1,840
4.12E+03
17.7
0
3.55E+05
1.04
1.05
132
4.12E+03
16.2
+0.5
3.27E+06
1.01
0.95
1,340
4.12E+03
17,9
0
2.22E+06
1.06
0.99
873
4.12E+03
17.1
-0.2
2.21E+05
¦ 0.84 I
1.23
70
4.12E+03
13.8
+ 1.5
3.08E+07
1.04
1.21
9,920
4.12E+03
14
-0.2
2.08E+06
1.04
1.38
584
4.12E+03
12.2
0
9.41E+06
1. 07
0.94
3,180
4.12E+03
14.8
0
4.S9E+06
1.07
1.12
1,300
4.12E+03
12.4
0
2.03E+06
0. 87
1.03
594
2.02E+03
6.13
+0.2
2.68E+06
0.90
0.99
818
2.02E+03
6.38
0
4.46E+05
0.93
0.94
144
2.02E+03
6.75
0
1.52E+06
1.02
1.06
434
2.02E+03
5.95
+0.2
2.71E+06
0.84
0.90
916
2.02E+03
7.07
+1.3
1.65E+07
0.89
0.69
7,280
2.02E+03
9.23
+0.3
7.45E+06
0.91
0.72
3, 120
2.02E+03
8.74
+0.3
8.54E+06
0.88
0.79
3, 290
2.02E+03
8.05
0
4.71E+06
0.92
0.66
2,460
3.16E+03
17 .7
0
1.16E+07
0.89
0.73
5, 500
3.16E+03
16
0
1.59E+06
0. 87
0.97
562
3.16E+03
12
0
2.23E+06
0. 77
0.95
853
8.20E+03
32 .4
0
3.44E+06
0.79
0.96
1,300
8.20E+03
32
0
5.12E+06
0.77
1.05
2,430
8.20E+03
41.2
Printed: 08 06 2008 1 ;22 PM
-------
AP Lab ID; P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID; Run# I-AGD-M23-3
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
CQBMraBQU.
Acq: 01-Aug-2008 22:32:34
User: CJL Dalafile: 080801R19 EQ
Rel, Int.
Fn 1 100%.
218.9856
QC (non-EQ)
10.43-15.00
0%
i—|—i—i—i—i—|—i—i—i—i—j—r—i i i—[—i—i—i	'» - [ r
10.5	11.0	11.5
12.0
1 I 1
12.5
13.0
13.5
14.0
14.5
| i
Abs. Int.
-?.04«7
.3.528?
-O.QQeO
15.0 RT
Rel. Int.
Fn 2 100%.
242.9656
QC (non-EQ)
15.02-20.50
0%-
-i	j	1	r-
—I	1	1	1	1	1	i	>	.	.	1	
16.0	17.0
18.0
—I—
19.0
	1 r !	1	r-
20.0
Abs. Int.
-2.52e?
• 1.2607
•O.OOeO
RT
Ret. Int.
Fn 3 100%-
292.9824 f
QC {non-EQ)
20.52-26.00
0%.
21.0
22.0
I
23.0
-i	* "i f	r~~
24.0
-i—i—i—r-
25.0
Abs. Int.
-2.86S7
• 1.4367
-O.OOeO
26.0 RT
Rel. Int.
Fn 4 100%
330.9792
QC (non-EQ) •
26.03-37.11
0%-
I
28.0
30.0
i i i i i i
32.0
34.0
-i	i—i	[—i	r-
36.0
Abs. Int.
-3.2287
• 1.6le?
-O.OOeO
RT
Rel. Int.
Fn 5 100%
366.9792
QC (non-EQ)
37.13-44.01
0%.
38.0
—i—t—I—'—|—i—i—i—r-
39.0
I t—r—|—!—T—T	1	1	1 I I 1 | I
40.0	41.0
42.0
"i—p—r—f—i—r-
43.0
Abs. Int.
-5,44e6
-2,72a6
O.OOeO
44.0 RT
Rel. Int.
Fn$ 100%
454.9728
QC (non-EQ) -
44.02-49.21
0%.
-|	1	1	1	1	1	1 i i
45.0
i i i i I
46.0
47.0
—I—
48.0
I i I C « I
49.0
Abs. Int.
-9.10e6
• O.OOeO
RT
Rel. Int.
Fn 7 100%
454.9728
QC (non-EQ) j
49.22-53.00
0%.
i—[—i—i—!—i—|—i—i—i—i—|—r
49.5	50.0
" I 1
50.5
t I I I I I T I I > I
51.0
51.5
j < i i i | % i t i
52.0
52.5
Abs, Int.
-9.37e6
4.69e6
O.OOeO
53.0 RT
Results: P:\P9400_P9499\Pd464_6042 PCB\msoun;esSP94S4_e042_PCB_0Q4RJ-D1O.utp_res, saved Q5-Aug-2008 09:19 (EE)
AP UitmTrace-Pm VI993 User/Sysfem: EE/EEC2-038 see: 452-427
Peak annotation: Areas. Centroids
PKD: n/a Printed: 0$-Aug-2Q08 09:21:48 Page 1 of 22
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
QC CHECK EQUALIZED
PRIOR TO PROCESSING
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GO: pcbx90_a Vial: 9
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19 EQ
Rel. int.
Fn 1 100%-
218,9856
QC Check
10,43-15.00
Q%-
11.0
11.5
T""
12.0
-i-l-r
12.5
13.0
"I—I—|—I—I—!—I—1~
13.5
14,D
T—|—T—T-
14.5
Abs. Int.
-7.31e7
• 3.65e7
•O.OOeO
15.0 RT
Rel. Int.
Fn 2 100%.
242.9856
QC Check
15.02-20.50
0%.
—i—i—r-
t	1	1	1	1	1	1	1 i i i i | i	r-
16.0	17.0
—I—
18.0
"1	
—I—
19.0
-i—i ] i i i—i—
20.0
Abs. Int.
-2.4787
1.2307
•O-OObO
RT
Rel. Int
Fn 3 100%.
292.9824
QC Check
20.52-26.00
0%.
21,0
22.0
23.0
24.0
I
25.0
Abs. Int.
-2.7407
-1,37e7
•O.OOeO
26,0 RT
Rel. Int.
Fn 4 100%.
330,9792
QC Check
26.03-37.11
0%.
—I—
28.0
1
30.0
32.0
I
34.0
—I—
36.0
Abs. Int.
- 3.25e7
11,62e7
O.OOeO
RT
Rel. Int
Fn 5 100%.
454.9728
QC Check
37.13-44.01
0%.
' I '
38.0
1 I '
39.0
40.0
41.0
*I '
42.0
43,0
Abs. Int.
r8.S8e6
-4.29e6
¦O.OOeO
44.0 RT
Rel. Int.
Fn 6 100%.
404.9760
QC Check
44.02-49.21
0%-
—I—
45.0
46.0
47.0
F
48.0
I
49.0
Abs. Int.
-8.64ei
• 4.32e6
• O.OOeO
RT
Rel. Int.
Fn 7 100%-
454.9728 ^
QC Check
49.22-53.00 "
0%-
T r
49.5
50.0
50.5
51.0
51.5
i—i—i—i—|—i—i—j—i—|—i—i—i—i—j—i—i—i—i—j—i—r-
S2.0	52.5
Abs. Int,
-8.72e6
•4.36e6
•O.OOeO
53.0 RT
Results: P:\PB4Q0_P949SW464_6042 PCBtesoumes\P9464_6042_PCB_D04RJ-D10.utp_res, saved 0S-Aug-2008 09:19 (EE)
AP UttraTmce-Pm V3.993 User/System: EEfeEC2038
Peak annotation: Areas, Centroids
PKD: n/a Printed: 05-Aug-200B 09:21:50 Page 2 of 22
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cp-10 GC: pcbx90_a Vial: 9
Rel. Int.
100%-
Fn 1
188.0393
MoCB
4a 3.48e3
10-43-15.00
0%-
1 | f
10.5
Rel. Int.
100%-
Fn 1
190,0363
MoCB
4a4 39e3
10,43-15.00
0%-
10.5
Rel, Int.
100%-
Fn 1
200.0795
MoCB Std,
4o 5.02e3
10.43-15.00
Q%-
10.5
Rel, Int.
100%-
Fn 1
202.0766
MoCB Std. .
4o 3,54e4
10,43-15.00
0%-
/».o
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 1
222.0003
DiCB-1
4o 5.33e3
10.43-15.00
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
0%-
PCB-4
3.4886
13.70
PCB-10
1,52e6
13,87
1 I ' 1 1 ' I
10.5
Rel, Int.
100%-
Fn 1
223.9974
DiCB-1
4o 9,97e3
10.43-15.00
0%-%
10.5
i | i i i i | i i i i | i * i i |
11.0	11.5
12,0
i—j—r-
12.5
13.0
13.5
PCB-4
2,22e6
13.70
PCB-10
9,6965
13.87
Acq: 01 -Aug-2008 22:32:34
User: CJL Datafile: 080801 R19_EQ
Abs. Int.
1.17e6
imr	y	r	r""T	i	y"*'""*	i	i	|	i	r	»	t "j
11.0	11.5
1 I I I I 1 I t
12.0
12.5
13.0
' 13.5 '
> i j r i » i |
14.0
• I '
14.5
.A, .A.
-5.83e5
1 I ¦
14.5
•O.OOeO
15.0RT
Abs, Int.
-7 64e5
3.82e5
O.OOeO
15.0RT
Rel. Int.
100%-
Fn 1
234.0406
OiCBStd.
4c 9.72e3
10.43-15.00
0% T ) I I I I" |	
10,5
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std
40 4,57e3
10.43-15.00
0%-^-r
10.5
11.0
11.0
11.5
12.0
12,5
13.0
13.5
-r-x-r-
14,0
ES-4
6.12e§-
¦ I '
11.5
12.0
12.5
13.0
13.5
¦ I '
14.0
¦¦ I '
14.5
I ¦"
14.5
Abs. Int.
-3.24e6
1 62e6
-O.OOeO
15,0 RT
Abs. Int.
2.04e6
• 1,02e6
•O.OOeO
15.0RT
15.0RT
Results: P:\P9400_P9499\P9464_6042 PCBVesourcesSP9464_6Q42_PCB J)04RJ-D10.ulp_res. sawed 0S-Aug-2008 09:19 (EE)	Peak annotation: Areas, Centrojps
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 6772. 5341	Revised: 04-Aug-2008 10:53:52 (EE) Printed: 05-Aug-2008 09:21:52 Page 4j/22
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Re! Int.
100%-
Fn 2
222.0003
DiCB-2
4o 6.43e3
15.07-20.50
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 9
0%-
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4a 2.37e4
15.07-20.50
0%-
Rel. Int.
100%-
Fn 2
234.0406
DiCBStd.
4ct 1,02e4
15.07-20.50
0%-
Rel. Int.
100%-
Fn 2
236.0376
DiCB Std.
4o 6.26e3
15.07-20.50
0%-
PCB-13/12
1.7«e8
18.99
PCB-6	PCB-5
PCB-9 1.87e7 2.20e7
6.59e6 A 15.99	16.28
A A A/\
16.0
17.0
PCB-14
2.10e7
17.92
18.0
PCB-tl
3.66e7
18.69
A
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801 R19_EQ
Abs. Int.
3.63e7
1.81e?
PCB-9
4.65e6
15.61
PCB-6
1.24e7
15.99
JS-9
1.46e7
15.60
.A	A
PCB-5
1.48e7
16.28
. A/\
16.0
!	I	'
17.0
PCB-14
1.42e7
17.92
18.0
PCB-13/12
1.16e8
18.90
PCB-11
2.44e7
18.69
PCB-15
1.62e7
19.26
w.
20.0
PCB-15
1.05e7
19.26
/\ ,
19.0
T	1	1	
20.0
16.0
17.0
18.0
19.0
20.0
JS-9
9.17e6
15.61
e6 /
6JK
ES-15
16.0
17.0
18.0
-O.OOeO
RT
Abs. Int.
-2.43e7
1 22e7
-O.OOeO
RT
Abs. Int.
-4.38e6
•2.19e6
-O.OOeO
RT
Abs. Int.
-2.84eS
1 42e6
19.0
20.0
¦O.OOeO
RT
Rel. Int.
100%-^
Fn 2
242.9856
QC Check
15.07-20.50
Abs. Int.
-2.47e7
:-1 23e7
O.OOeO
RT
Results: P:
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 2
255.9613
TrCB-2
4o 2.26e3
15.02-20,50
0%-
Rel. Int.
100%-
Fn 2
257,9584
TrCB-2
4o 2,69e3
15,02-20.50
0%-
16.0
16.0 '
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
PCB-30/18
4.59e6
18.41
PCB-17
3,52e6
18.80
PCB-19
7.12e5
16.68
A
17.0
18.0
PC8-16
3.5086
PC6-27
1.3966
19.00
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801 R19_EQ
Abs. Int.
r1.19e6
PCB-32
3.04e6
19.70
20.0
PCB-30/18
4,38e6
18.41
PCB-16
3.32e6
19.22
PCB-19
6.84e5
16.68
17.0
18.0
PCB-17
3.26e6
PCB-27
1.28e6
18.99
PCB-32
2.87e6
19.70
¦5.94e5
-O.OOeO
RT
Abs. Int.
-1.15e6
¦5.77e5
19.0
20.0
O.OOeO
RT
Rel. Int.
4.13e7
100%-,
15.58
Fn 2 :


268.0016 •


TrCB Std. -


4o 2.95e4 •


15.02-20.50 ;


0%-
, , . T- / ,
\
Rel. Int.
100%-
Fn 2
269,9986
TrCB Std.
4o 1.26e4
15.02-20.50
0%-
ES-19
7.34eB
16.6"
16.0
•	¦ i—[-
17.0
1—I—1
18,0
¦	1	r	r-
19.0
t *1 t I
I | ' I
20.0
T-1
16.0
ES-19
2.66e6
18.39
1—1—1
17.0
18,0
19.0

20.0
Abs. Int.
-1.20e7
•6.02e6
O.OOeO
RT
Abs. Int.
r1.99e6
¦9.93e5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
242,9856
QC Check
15 02-20.50
0%-
16,0
!	1	"
17,0
18,0
19,0
20.0
Abs. Int.
-2.47e7
-1.23e7
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6O42 PCBVesources\P94&4_6042_PCB_004RJ-DlOutp_re$. saved 05-Aug-2008 09:19 (EE)	Peak annotation: Areas, Centmids-
AP UltmTrace-Pro V3.993 User/System: EE/EEC2-03B cc: 6006, 4958	Revised: 04-Aug-200S 10:54:17 {EE} Printed: 05-Aug-20Q8 09:21:54 Page 6 q?22
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 3
255.9613
TrCB-3
4o 4.59e3
20,52-26.00
Sample ID; Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19 EQ
0%'
Rel. Int.
100%-
Fn 3
257,9584
TrCB-3
4o4.15e3
20.52-26.00
0%-
PCB-35
3.2Be?
25.15
PCB-34
2.04e6
20.83
PCB-26/tS,B-25
8.12e6^73e6
21.25 21.44
PCB-31
8.38e6
21.72
PCB-28/20
2.02«CB-21/33
22.00 1.98e7
22.19
21.0
21.25 •£'.«w A
/\ a, .A.
PCB-34
201e6
20.83
PCB-26/KB-25
7.87e66-45e6
21.25 21.44
21.0

22.0
PCB-28/20
1,95«:B-21/33
22.00 t.90e7
PCB-31 A 22.16
7.97e6
21.72
PCB-22
7.93e6
22.55
-A-
POB-36
6.19e6
23.92
PCB-39
4.40e6
24.23
2.09e6
24.55
PCB-38
9.96e6
24.75
A
23.0
24.0
25 3
PCB-22
7.71e6
22.55
-A-
PCS-36 pro ia
23J2
,
-A.
22.0
23,0
24,0

PCB-38
9.26e6
24.75
A
2.82e7
25.50
PCB-35
3.17e7
PCB-37
2.70e7
25,50
Abs. Int.
-8,0366
¦4,01e6
-O.OOeO
26.0 RT
Abs. Int.
7.72e6
3.86e6
25,0
-O.OOeO
26,0 RT
Rel. Int.
100%-
Fn 3
268.0016
TrCBStd.
4o 2,90e4
20.52-26.00
0%-M-
Rel. Int.
100%
Fn 3
269.9986
TrCB Std.
4ct 1,60e4
20.52-26.00 ¦
0%-
i | i
21.0
i i	r
—I	>"
21.0
22.0
SS-28
9.4466
21.97
22.0
,	,	h-,	
23.0
-r-r
-1—f—=,
24.0
25,0
23.0
24.0
25.0
Abs. Int.
-4.35e6
-2.17e6
-f-O.OOeO
26.0 RT


ES-37
9.0486
Abs. Int.
-2.34e6
2.27e6
23.24

n
-1,17e6
-O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
20.52-26.00
21.0
22.0
23.0
24,0
25.0
Abs. Int.
2,7467
-1,37e7
O.OOeO
26.0 RT
Results: P \P9400_P9499\P9464_6042 PC8Vesourves\P9464_6042_PC8_004RJ-D10utp_W3. saved 0S-Aug-2008 09:19 (EE)
AP UttraTrace-Pro V3993 User/System: EBEEC2-038 cc: 9570, 2935
Peak annotation: Amas, Cenj
Revised: OI-Aug-2008 10:57:35 (EE) Printed: 05-Aug-2008 09:21:55 Page
Cenjtoids
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 2
289.9224
TeCB-2
4o 1.30e3
15.02-20.50
Rel. Int.
100%-
Fn 2
291.9194
TeCB-2
4o1.71e3
15,02-20.50
Rel, Int.
100%-
Fn 2
301.9626
TeCB Std,
4o 2.19e3
15.02-20,50
0%-
Rel, Int.
100%-
Fn 2
303.9597
TeCB Std.
4o 1.71e3
15 02-20.50
0%-
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19 EQ
PCB-54
7.15e4
Abs. Irit
1.67e4
19.55
8.33e3
O.OOeO
RT
PCB-54
B,58e4
Abs. Int
2.30e4
19.55
1.15e4
i"~i i "—. I i*T i—r-^O.OOeO
16.0
ES-54
6 84e6
19.53
17.0
18.0
19.0
---eS-54
a si
B.54e6
19,53
16.0
17.0
18.0
20.0
Abs, Int.
-1.53e6
•7.65e5
-O.OOeO
RT
Abs. Int.
-1.90e6
9 52e5
19.0
20.0
-O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
15,02-20.50'
0%-
'"f	T	
"T	r	1	T'"
16.0
17,0
18.0
19.0
R»$ults: P:\P9400_P9499\P9464_6042 PCB\m$ources\P9464_6042_PC8_004RJ-DWMtp_ms, saved 0S-Aug-2OO8 09:19 (EE)
AP UttraTrace-Pro V3.993 User/System EEJEEC2-038 cc: 8546, 7026
1 I 1
20,0
Abs. Int.
-2,47e7
¦1.2387
¦O.OOeO
RT
Peak annotation: Areas. Centmidf-
Revised: 04-Aug-2008 10:57:51 (££} Printed: QS-Aug-2008 09:21:SB Page a 
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 3
289.9224
TeCB-3
4a 1.59e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4o 4,38e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
301.9626
TeCB Std.
4o1.96e3
20.52-26,00
0%-
Rel. Int.
100%-
Fn 3
303.9597
TeCB Std.
4o1.79e3
20.52-26.00
0%-
21.0
PCB-50/53
7.08e5
21.48
I I -~~f 1
21.0
PCB-50/53
9.S2e5
21.48
' '
21.0
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
21.0
PC8-51

1,96e7

22.14
A


PCB-52
1 1
2.67e6
/ \
23.60
/, I , , , , ¦ ,

PCB-44M7/65
2.48e?
24.52
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19 EQ
Abs. Int.
-5.62e6
PCB-69M8
3.27e6 PCB-48
24,03 1.11e6
/\ 24^9
	Mil			I
3CB-59/82/75
2.21e6
24.77
22,0
23.0
24.0
25.0
prR,. PCB-64
9 37e5 2 01 e6
f CJ	re
25JP\ ^
PCB-51

2.53e7

22.14
A


PCB-52
/
3.49e6
/ \
23.60
J, \	
/\
PCB-44M7/B5
3,23e7
24.52
PCB-69/49,„n
4.33e6 PCB-48
24.02 1.48e6
24.29
-6
JS-52
8.02e6
23.57
22.0
23.0
24.0
25.0
22.0
23.0
•2.8166
-O.OOeO
26.0 RT
Abs. Int.
7.30e6
3.65e6
-O.OOeO
26.0 RT
Abs. Int.
2,01e6
•1.00e6
¦O.OOeO
26.0 RT
Abs. Int.
-2.59e6
•1.29e6
¦O.OOeO
24.0
25.0
26.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
20.52-26 00
Results: P:\P9400_P9499\P9464_6042 PCB\msoumes\P9464_6042^PCB_004RJ-010.utp_ms, saved 05-4ug-2008 09:19 (EE)
AP UttraTrace-Pro V3.993 User/System:EE/EEC2-038 cc: 1832, 9650
25.0
Abs. Int.
2.74e7
l.37e?
O.OOeO
26.0 RT
Peak annotation: Areas, Centmids
Revised: 04-Aug-2008 10:58:18 (EE) Printed: OS-Aug-2008 09:21:58 Page 9 ol^2
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19_EQ
Rel. Int.
100%
Fn 4
289.9224
TeCB-4
4o 5.21e3
26.03-32.99
Rel, Int.
100%-
Fn 4
291.9194
TeCB-4
4a 5.52e3
26.03-32.99
PCB-68
1.83e7
26.53
PCB-72
7.39e5
26.28
PCB-S7
1.63e6
26.90
/X
PCB-67
2.70e6
27.25
PCB-61/7O/7R0B-66
1,08e7 6.97e6
27.78 28.05
27.0
28.0
0%-
PCB-72
9.68e5
26.28
		 ¦ -
PCB-67
2.09e6
26.90
PCB-67
3.46e6
27.25
	A		
PCB-61/70/
1.40S7
27.78
28.05
PCB-56
8.53e6
28.62
[ PCB-60
[ 2.26e6 PCB-80
28.81 697e5
29.15
29.0
PCB-56
1.10e7
28.62
PCB-60
2.90e6
28.81
A,	
PCB-77
2 06e7
31.79
A
PCB-79
5.70e6
30.46
P,CJtI£ PCB-81
4^80e,8 2.93e6
30.93 31 32
30.0
A	30;?3 31.32
i\. , .a
31.0
32.0
PCB-77
2.66e7
31.79
27.0
28.0
PCB-80
9.02e5
29.15
Oi i
PCB-79
7.57e6
30.46
29,0
PCB-78 PCB-81
4; §86® 3.91e6
31.31
A
30.94
30.0
-A
31.0
¦¦¦V	V	f	I	
32.0
Rel, Int.
100%-
Fn 4
301.9626
TeCBStd,
4o 510e3
26.03-32.99
0%-
ES-81
7.57e6
31.30
ES-77
8.19e6
31.77
2.14e5
29.15
i r-	
27.0
28.0
29.0
30.0
31.0
32.0
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
4a 2 45e3
26.03-32.99
0%-
ES-81 ,
9 26e6-*"^
ES-77
1.04eT^
31.77
27.0
28.0
29.0
30.0
31.0
32.0
Abs. Int.
-4.91e6
¦2.46e6
•O.GOeO
RT
Abs. Int.
-6,38e6
3.19e6
-0,00e0
RT
Abs. Int.
-2.02e6
¦1.01e6
-O.OOeO
RT
Abs. Int.
-2.45e6
•1.23e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
26,03-32.99
I > | I f
29.0
3
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 3
323.8834
PeCB-3
4o 1.21e3
20.52-26.00
Sample ID: Run# I-ACD-M23-3
VSIR expt; pcb0306_cl1-10 GC: pcbx90_a Vial: 9
Re!. Int.
100%-
Fn 3
325.8804
PeCB-3
4o 1.32e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
337.9207
PeCB Std.
4o 1.01e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
339.9177
PeCB Std,
4o 1.26e3
20.52-26.00
0%-
21.0
22.0
23.0
24.0
21.0
	ji*i		 ^
22.0
23.0
¦ f •*••'? I"" n I
24.0
21.0
22.0
23.0
24.0
FCB-96
1.54e5
24.76
PC8-104
5.86e4
24.45
PCB-96
2,08e5
24.76
PCB-1Q4
9.12e4
24.45
ES-104
9.93e6
24.43
Acq: 01 -Aug-2008 22:32:34
User: CJL Datafile: 080801 R19_EQ
Abs. Int.
-3.74e4
25.0
ES-104
6.36e6^
2^43
1.87e4
-O.OOeO
26.0 RT
Abs, Int.
5.30e4
•2.65e4
f£S, f irjfnr-y-a., r. f
25.0
- -ft	
25,0
¦O.OOeO
26.0 RT
Abs. Int.
-2,49e6
¦1.25e6
-O.OOeO
26.0 RT
Abs. Int.
-1.60e6
¦7.98e5
21.0
22.0
23.0
24.0
25.0
-O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
20.52-26.00
21,0
22.0
23,0
Abs. Int.
2.74e7
1.37e7
O.OOeO
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_S042_PCB_004RJ-D10 utp_res. saved 0S-Aug-2008 09:19 (EE)
AP UltraTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 3205, 4656
24.0	25.0	26.0 RT
Peak annotation: Areas, Centmitis
Revised: 04-Aug-200S 10:59:28 (EE) Printed: 05-Aug-200B 09:22:00 Pag# llsdf 22
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 4
323.8834
PeCB-4
4o3.43e3
26.03-37.11
Sample ID: Run# I-ACD-M23-3
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
/
Q%-
Rel. Int.
100%-
Fn4
325.8804
PeCB-4
4o 5,72e3
26.03-37.11
0%-
Rel. Int.
Rel. Int.
100%-
Fn 4
339.9177
PeCB Std.
4o1.89e3
26.03-37,11
0%-
PCB-95
1.2306	PCS-84
27.01 pCB-98 4B5e5>CB-89
A 1.t8eS 95 1.40e5
28,36
28.0
PCB-92
3.89e5
29.03
PCB-110
PCB-113/90/1OTCB-108/119/86/97/3^22e6
2.53e6	3.15e6 31 23
29.53	30.48
PC 6-83 A PCB-11
, 62§3Jf K ^
PCB-118
4.64e6
33.77
I8XJB-82
6.93e5
31.50
iL_
£
PCB-120
6J63@5
32.22
30.0
32.0
PCB-95
27??PCB-98 7^|3"|^>CB-89
j?z5 as?
-r-t	r
4-
28.0
PC8-92
6 02e5
29.03
>, 0 ,
PCB-110
PCB-113/90/1 (flCB-108/119/86/97/5.3366
412e6	5.38e6 31.23
29.53	30.48
PCB-83 t\ PCB-11
' 25a6 A 1,47c
29.W I 31.0
8SB-82
1.16C6
31.50
¦A
PCB-120
1.04e6
32.22
A
30.0
T
32.0
PCB-105
3.91 e6
34.77
PCB-10
PCB-114
6.64e5
PCB-118
7.48e6
PCB-105
33.77
6.40e6
34.77
PCB-10
PCB-114
1,Q3e6
Acq: 01-Aug-2008 22:32:34
Jfser: CJL Datafile: 080801R19_EQ
Abs. Int.
-1 12e6
100%-,
JS-101
9.45e6
Fn 4 !
29.52
337.9207 ¦


PeCB Std. '


4o 1,86e3 "


26,03-37.11 -


0%-
I
V-
SS-111
1.19e7
31.80
34.0
fS-123 f|se7 fS-105
9.8^6 34.20 ^
*1	T"
28.0
30 0
3,l2e5
28.60
i i i i
i i i i
M
320
SS-111
7 63ea-
3.12*
31.6?
,	fit
T"—[' | ^ I ^ I	r*—
34,0
ES-123 ESJ-t< ES-JW
6.3?e6 ^-6>«Be6 6&1e6
^33u47 34.20 *34.74
^-i
II
PCB-127
8.3665
30.01
A
36.0
PCB-127
1.39e8
36.00
36.0
36.0
1 > I I
28.0
30.0
32.0
34,0
i—I—1
36.0
•5.62e5
-O.OOeO
RT
Abs, Int.
-1.86e6
•9.28e5
-O.OOeO
RT
Abs. Int.
- 2 94e6
1.47e6
-O.OOeO
RT
Abs. Int.
-1.92e6
•9.61e5
-O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
26.03-37.11
Abs. Int.
-3.2Se7
1.6267
O.OOeO
28.0
30.0
32.0
34.0
Results: P:\P9400_P9499\P94$4_6042 PC8VesourcesSP94S4 6042_PCB_004RJ-D10.utp_res, saved Q5-Aug-2008 09:19 (EE)
AP Ultra Trace-Pro I'3.993 User/System: ESEEC2-038 cc. 9229. 0J02
36.0
Peak annotation: Areas. Centmids
Revised: 04-Aug-2008 11:01:32 (EE) Printed: 05-Aug-2008 09:22:01
Page i2oy2
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
PCB-126
Rel. Int. SAiee
100%-
37.37
Fn 5
323,8834
PeCB-5
4o 2.14e3
37.13-44.01
0%-
Rel. Int.
100%
Fn 5
325.8804
PeCB-S
4o 3.53e3
37.13-44.01 -
0%-
PCB-126
1.03e7
37.37
ft
38.0
38,0
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
[ I I I 1 | t
39,0

40.0
I i i i r |
41.0
' 1 I
42.0
Acq: 01-Aug-2008 22:32:34
User: CJL Dataflle: 080801 R19_EQ
Abs. Int.
r 1.58e6
43.0
I | I ! I T
390
1 *1 *1 T | »
40.0
| > t i r ]
41.0
I | O"! f T | > T f I j	T
42.0	43.0
-7.9165
-O.OOeO
44.0 RT
Abs. Int.
2.51 e6
-l.25e6
—j—*—i—i—i—| - O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
337.9207
PeCBStd,
4o 3.96e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
339.9177
PeCBStd.
4o2.75e3
37.13-44.01
0%-
ES- i
6.6: .
37.
38.0
j I I ' I I | I
38.0
39.0
3.58e5
39.90
i "T-" |
2.45e5
42.61
40.0
41.0
39.0
2.52e5
39.39
~l—'—1—r
' I '¦ •'
40.0
I ' ' 1 ' I 1
41.0
42.0
42.0
43.0
Abs. Int.
-2.48e6
• 1.24e6
¦O.OOeO
44.0 RT
Abs. Int.
-1,60e6
•7.98e5
O.OOeO
I | r—"7	i—t—f	r	»——r*—r'
43.0	44.0 RT
Rel, Int.
100%-
Fn 5
454.9728
QC Check
37 13-44.01"
0%-
38.0
39.0
1 I 1 - J 1 T T
40.0
1111
41.0
42.0
Abs. Int.
-8.58e6
•4.29e6
¦O.OOeO
43.0	44.0 RT
Results: P\P9400_P9499\P9464_6042 PCB\resources'P9464_6042_PCa_004RJ-D10utp_res. saved OS-Aug-2008 09:19 (EE)	Peak annotation: Areas, CentmidS
AP UltmTmce-Pm V3.993 User/System: EEJEEC2-038 cc: 8226, 1058	Revised: 04-Aug-2008 11:01:38 (EE) Printed: 05-Aug-2OO8 09:22:02 Page 13 of22
-------
AP Lab ID: P9464_6042_PCB_0Q4RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 4
359,8415
HxCB-4
40 1.34e3
27,99-37.11
0%-
28.0
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4o1.18e3
27.99-37.11
0%-
28.0
Rel. Int.
100%-
Fn 4
371,8817
HxCB Std
4o 1 25e3
27,99-37,11
0%-
28.0
29.0
29.0
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19 EQ
PCB-163/138/129
5.90e8
36.41
II
PCB-147/149
2.86e6
32.80
PCB-150 PCB-145
2.50e5 1 73eS
29 67 A 30.24
l	i / f i Pi i
PCfl-148
1.83eS
31.51
PCB-151/135
1,42e6 PCB-144
32.03 3,B1e5
32.50
A
30.0
31.0
i
¦ i ¦
32.0

A
PCB-132
„_PCB-139n40 1 21 e6
33,86 PCB-13aCB-1
09e5 333i	. 2 1485 1 98e5
32,97	J\ 34 28 34.62
1 i '
33.0
PCB-147/149
2.25e6
32.80
34.0
PCB-153/168
3,87e6
PCB-158
2.85e8
|;ifCB-130
27eS 7.69e5
35.86
Abs. Int.
-1,27e6
•6,36e5
PCB-163/138/129
47Se6
36.41
PCEMSO PCB-145
2J0®5 1.17e5
2B£7 A 30.24
, rs> • '}¦>
30.0
PCB-151/135
PCB-148 \j,4ne6 PCB-144
1 B6e5 32.03 2 78e5
3V52 A 3250
i i ft i ¦ » A
31.0
T
32.0
-
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-llltima MM3
Rel, Int.
100%-,
Fn 5
359.8415
HxCB-5
4o 2.27e3
37,13-44.01
0%-
PCB-128/166
9.09e5
37.47

RCB-167
1,5666
3894
63l°2f 38 53 A
,A. A-,
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
PCB-156/157 |
4.84e6 /
5 07e5
41.08
-A
Rel, Int.
100%-
Fn 5
361,8385
HxCB-5
40 1.69e3
37.13-44.01
0%-
PCB-128/166
7,17e5
37.47
7k
Rel. Int.
100%-
Fn 5
371.8817
HxCB Std.
4o 2.46e3
37.13-44.01
0%-
-r-T-
Rel. Int.
100%-
Fn 5
373,8788
HxCB Std.
40 3.08e3
37.13-44.01
0%-
38.0
39,0
PCB-167
1,25e6
38,94
Acq: 01-Aug-2Q08 22:32:34
User: CJL Datafile: 0808Q1R19_EQ
Abs. Int.
9.33e5
PCB-169
1.39e6
42.62
40.0
PCB-156/157
3 77e6
39.90
41.0
2.58e5
42.14
42.0
43,0
5^15e5 3g 53
38.29 a
A. A-..
4.57e5
41.08
PCB-169
1.09e6
42.62
1.98e5
42.14
1-^
38.0
38.0
39.0
40.0
ES-156/157
1.56e7
39.89
41,0
42.0
43.0

39.0
ES-167 -
6.40e6^
38.9?
40.0
ES-156/157
1,26e7
39.f"
41.0
420
""T	|	1"
43.0
38.0
39.0
ES-189
6.10e6
¦4.67e5
¦O.OOeO
44,0 RT
Abs. Int.
7.45e5
•3.73e5
¦ O.OOeO
44.0 RT
Abs, Int.
-2.91e6
1,45e6
-f- O.OOeO
44.0 RT
Abs. Int.
2.28e6
•1.14e6
O.OOeO
40.0
41.0
42.0
43.0
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01'
0%-
I ! I |
38.0
-r
1 I 1
39.0
1 I 1
40.0
T
41.0
~T
42.0
T
Abs. Int.
r8.58e6
-4 29e6
•O.OOeO
43.0	44.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\msoumi$\P9464_6042_PCB_004RJ-D10.utf)_m$, saved O5-Aug-2O08 09:19 (EE)	Peak annotation: Areas, Centmids
AP UltraTmce-Pm V3.993 User/System: EEJEEC2-038 cc: 0763, 9026	~	Revised 04-Aug-2008 11:09:55 (EE) Printed: 05-Aug-2008 09:22:04 Page 15 oj/Z2
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel Int.
100%-
Fn 4
393-8025
HpCB-4
4a 1,46e3
30.01-37.11
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 9
0%-
Rel. Int.
100%-
Fn 4
395.7995
HpCB-4
4cr 8.41e2
30.01-37.11
0%-
Ret, Int.
100%-
Fn 4
405.8428
HpCB SW.
4o 2 00e3
30.01-37.11
0%-
Rel. Int.
100%-
Fn 4
407,8398
HpCB Std.
4 o 1,47e3
30,01-37.11
0%-
-i—i—i—r"
PCB-179
i.ise6
PC B-188
1.74eS
34.23
PCB-176
8,29e5
35.25
PCB-186
1.01e5
35,65
Acq: 01-Aug-2008 22:32:34
User: CJL Dataflle: 080801 R19_EQ
Abs. Int.
-2.81 e5
PCB-184
2.9le5
34.96
31.0
' I '
31.0
I f 1 I
till
31.0
31.0
32.0
32.0
32.0
33,0
34.0
35.0
36.0
PCB-179
I.l0e6
34.50
PCB-176
8,17e5
35,25
PC B-188
1,69e5
34.23
PCB-184
2.65e5
34.96
24.23	A
A)\ , ,A
PCB-186
8.65e4
35.65
-r-A-,
33,0
34.0
35.0
ES-188
7.75e6
34.20
33.0
34.0
35.0
ES-188
7.24e6^'
34>1
'"T	1	1	1""
'"T	1	1	I""
32.0
33.0
34.0
35.0
36,0
36.0
PC8-178
?.Q3e5
36.78
¦1.40e5
36.0
-p-f-O.OOeO
37.0 RT
PCB-178
6 76e5
36.78
Abs. Int.
-2.58e5
1.29e5
¦ 		 O.OOeO
37.0 RT
SS-178
5,03e6
36,76
Abs. Int.
-1.88e6
¦ 9.40e5
~i—^-O.OOeO
37.0 RT
SS-,178
36.76
Abs, Int.
-1.75e6
•8,77e5
I—f- O.OOeO
37,0 RT
Rel. Int.
100%-
Fn 4
330.9792
QC Check
30.01-37.11'
34.0
Abs. Int.
-3.24e7
1 62e7
~i—r-O.OOeO
37.0 RT
Results: P:\P9400_P9499\P9464_6042 PCBVesoun:es\P9464_6042_PCB_004RJ-D10 utp_res, saved 05-Aug-2008 09 19 (EE)	Peak annotation: Areas, Centrpids
AP Ultra Trace-Pro V3 993 User/System: EE/EEC2-038 cc: 1328. 9437	Revised: 04-Aug-2008 11:09:59 (EE/ Printed 0S-Aug-2008 09 22 05 Page 1$f£22
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%'
Fn 5
393.8025
HpCB-5
4a 2.63e3
37.13-44.01
0%-
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_c)1-10 GC: pcbx90_a Vial:
PCB-180/193
1.57e7
41.07
A
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4g 1,50e3
37,13-44.01 ¦
0%-
PCB-187
4,69e6
37.56
PCB-175
5,03e5
37.33
I fSy—
PCB-133
2.4266
38.08
PCB-177
2.27e6
38.64
PCB-17V173
1.6Se6
39.17
A .
380
H.O
PCB-172
1.14e6
40.52
40.0
i
1
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19EQ
Abs. Int.
-3.47e6
PCB-191
1.O0e6
41.37
PCB-170
4.85e6
42.13
41.0
PC8-18Q/193
1.51e7
41,07
I
PCB-187
4,4Qe6
PCB-17!7'56
5.03e5
37.33
•Pt
75 ft
>A
I—^—r—
PCB-183
2.25e6
38.08
PCB-177
2.25e6
38.64
PCB-171/173
1.63e6
39.17
38.0
-1—r
39.0
PCB-172
1.08e6
40.52
¦ ,
PCB-191
1.02e6
41.37
—A.
42.0
PCB-170
4.55e6
42.13
PCB-190
2.37e6
42.58
i	i j t
43.0
40.0
41.0
i
JX.
PCB-190
2.22e6
42.58
42.0
43.0
'"I '
1.74e6
¦ O.OOeO
44.0 RT
Abs. Int.
-3.33e6
1.67e6
¦O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std.
4o3.76e3
37,13-44.01
0%-
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std..
4o2.41e3
37.13-44,01
0%-
—(~—i—i—r—¦i—|—i—r~~*t—i—j—i—i"" i i—j—i—i—
38.0	39.0
>1 i—i—i—j—I—*—i—i—r—'—'—i—r~
40.0
41.0
ES-170
5.97e6^
4r
42.0
43.0
Abs. Int.
-1 56e6
•7.81e5
-O.OOeO
44.0 RT
Abs. Int.
1,43e6
• 7.13e5
! I I | I ! I I | I I
38.0
39,0
I I I I
¦O.OOeO
40,0
41.0
42.0
43.0
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01
0%-
38.0
39.0
40.0
41.0
42.0
43.0
Abs. Int.
-8.58e6
•4.29e6
•O.OOeO
44.0 RT
Resute: P:\P9400_P9499\P9464_6042 PCBVe$ouwes\P9464_6042_PCB_004RJ-D10.utpjes, saved OS-Aug-2008 09:19 (EE)
AP UttraTrace-Pm V3.993 User/System: EE/EEC2-G38 cc: 1622, 0242
Peak annotation: Areas, Centroids
Revised: 04-Aug-2008 11:11:04 (BE) Printed: 05-Aug-2008 09:22:07 Page 17 &Q2
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# I-AGD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9

PCB-189
Rel. Int.
100%-,
1 22e6
44.74
n
Fn 6 :
A
393.8025 •
U
HpCB-6

4o 2.05e3 .

44.02-49.21 -
/ \
0%-
		 A/ n
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801 R19_EQ
Abs, Int.
-2.88e5
t I 1
45.0
'—I—'
46.0
t i 1"
A
i t
47.0
48.0

PCB-189
Rel. Int.
100%-]
1.21e6
44.74
k
Fn 6
A
395.7995

HpCB-6

4o 1.57e3 •

44.02-49.21 •
/
0%-
/v/ V
A
45.0
46.0
47.0
Rel. Int.
100%-,
ES-189
7.ooes
44,72
A
Fn 6
405.8428 -
HpCBStd, J
40 4.57e3 ¦
44.02-49,21 ¦
j
0%-
	-	L \
45.0
46.0
-T
1.99e5
46.89
—r	1	1 "T*—[—
47,0
45.0
46.0
47.0
i—j—i—i—f
48.0
-I	,	1	1
48.0
48.0
1—I—
49.0
49.0
49.0
¦ 1,44e5
-O.OOeO
RT
Abs. Int.
-2 95e5
1,47e5
i—,—i—
49.0
-O.OOeO
RT
Abs. Int.
r 1 66e6
•8.31e5
¦O.OOeO
RT

ES-189jr



Rel. Int.
6.94eT


Abs. Int.
100%-,
44
-------
AP Lab ID: P9464_6042_PCB_004RJ-D 10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 5
427.7635
OcCB-5
4o 1.11 e3
37.13-44.01
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Viai: 9
0%-
Rel. Int.
100%-
Fn 5
429.7606
OcCB-5
4a 9.07e2
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
439.8038
OcCB Std
4a 1.35e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std. .
4o 1.88e3
37.13-44.01
0%-
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19 EQ
Abs. Int.
-1 76e6
PCB-202
9.43e5
38.75
-A-
38.0
1 l r
39.0
PCB-201
1,27e6
39.53
PCB-200
2 15e5 40a38
4QJ0 /-f\
40.0
41.0
42.0
38.0
PCB-202
1.08e6
38.75
. A , , .
39.0
ES-202
6.25e6
38.73
PCB-201
1.41e6
39.53
-rA,
PCB-200
PCB-2041j47^
2.3165 40 38
40.10 /V\
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 9
Fn 6
427.7635
OcCB-6
4o1.39e3
44.02-49,21
0%-
Rei. Int.
100%
Fn 6
439.8038
OcCB Std.
4o 2.42e3
44.02-49.21 ¦
0%-
PCB-195
2,26e6
44,56
45.0
i r j i i
46.0
PCB-194
5 47e6
Acq: 01-Aug-200B 22:32:34
User: CJL Datafile: 080801R19 EQ
Abs. Int.
-1,24e6
PC B-205
7.38e5
46.90
/\
47.0
-i—.—.—|—'
48.0
49.0


PCB-194

Rel. Int.

6.16e6

100%-i

46,50

Fn 6 :

A

429.7606
PCB-195


OcCB-6
2.45e6


4a1.77e3
44.56
A

PCB-205
44.02-49.21
A
\
6.48e5
/ \
/ \
46.00
0%~
'"1" T . .'**T- T* 1 » 1 1 1 ¦¦ 1 1 1 1
_—,—,—,—,—,—,—,—J	,, i—
			
45.0
46.0
47.0
48.0
49.0
ES-205
5.49e6
46.88
45.0
""I	I	I	J	%	V"
46.0
	r~
•6.21e5
-O.OOeO
RT
Abs. Int.
-1.42e6
•7.10e5
48.0
1.17e5
48.35
| i t i i | r
49.0
-O.OOeO
RT
Abs. Int.
-1 28e6
¦6.40e5
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
441.8008
OcCB Std.
4o1.63e3
44.02-49.21
0%-
45.0
1.56e5
46.35
	1""*!	
46.0
47.0
48.0
Abs. Int.
-1.39e6
-6.95e5
•O.OOeO
49.0 RT
Rel. Int.
100%'
Fn 6
404.9760
QC Check
44.02-49.21
0%-
45.0
!	1	
46.0
47.0
48.0
Results: P:)P9400_P9499\PS464_6042 PCB\msauncesV:'9464_S042_PCB_004RJ-D10.utp_ms, save4 05-Aug-2008 09:19 (EE)
AP UtiraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 7096, 4091
49.0
Abs. Int.
-8.64e6
•4.32e6
¦O.OOeO
RT
Peak annotation: Areas, Centroktp
Revised: 04-Aug-2008 11:11:35 (EE) Printed: 0S-Aug-2008 09:22:10 Page 201
entroiiM
Oo02
-------
AP Lab ID: P9464_6042_PCB_004RJ-D1Q
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 6
461.7245
NoCB
4o 2.69e3
44.02-49,21
0%-
Rel. Int.
100%-
Fn 6
463.7216
NoCB
4o 5.51e3
44.02-49.21
0%-
PCB-208
9,7365
44.36
PCB-208
1.26e6
44.36
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801R19 EQ
PCB-207
1,51e6
45.15
45.0
PCB-206
2.23e6
48.36
45.0
ll!|iriT|flT
46.0
47.0
48.0

PCB-206

2.89e6

48.36
PCB-207
A
1.93e6
t
45.15
A
A
46.0
Abs. Int.
r5.27e5
-2,63e5
,—,—,—J-O.OOeO
49.0 RT
Abs. Int.
-6.90eS
-3.45e5
47.0
48.0
,—,—.—t- O.OOeO
49.0 RT
Rel. Int.
100%-
Fn 6
473.7648
NoCBStd.
4a 141e3
44.02-49.21
0%-
Rel. I nt.
100%-
Fn 6
475.7619
NoCB Std.
40 1.67e3
44.02-49.21
0%-
¦¦¦¦I	r	t	
45.0
ES-208
B.17e6
">—«—I—1
45.0
46.0
46.0
47.0
47.0
48.0
ES-206^
4.49«B
4ff34
	!	1	1	1	1	1 * i	r—|—
48.0
49.0
Abs. Int.
-1.18e6
¦5.90e5
-O.OOeO
RT
Abs. Int.
-1.42e6
•7.12e5
O.OOeO
-i—*—i—|—i—
490 RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
44.02-49.21'
0%-
45.0
46.0
47.0
Results: P:\P9400_P949S\P9464_6042 PCBVesources\P946
-------
AP Lab ID: P9464_6042_PCB_004RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 7
497,6826
DeCB
4o 8.13e2
49.22-53.00 •
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 9
0%-
PCB-209
1.19eB
Acq: 01-Aug-2008 22:32:34
User: CJL Datafile: 080801 R19_EQ
Abs. Int.
-2.74e5
49.5
50.0
50.5
51.0
51.5
52.0
Rel. Int.
100%-
Fn 7
499.6797
DeCB
4o 1.37e3
49.22-53.00
0%-
PCB-209
1.uSe6
49.72
Rel. Int.
100%-
Fn 7
509.7229
DeCB Std.
4o 1.13e3
49.22-53.00
0%-
Rel. Int.
100%-
Fn 7
511.7199
DeCB Std.
4o8.18e2
49.22-53.00
0%-
49.5
I i* i i r | i' i "i' i | > i i i ") 1 i i i i | i i t i f > t i i y t¦ i i i | i
50,0	50.5	51.0	51.5
lilt
52.0
ES-209
5.8Se6
49.70
49.5
50.0
50.5
51.0
51.5
52.0
ES-209
49.5
50.0
50.5
51.0
51.5
¦1.37e5
52.5
-O.OOeO
53.0 RT
Abs. Int.
2.39e5
¦1.20e5
O.OOeO
¦ t |,mr	t	r	»	y	r	t	t"
52.5	53.0 RT
Abs. Int.
-1.31e6
•6.56e5
52.5
-O.OOeO
53.0 RT
Abs. Int.
1.08e6
¦5.40e5
52,0
52.5
-O.OOeO
53.0 RT
Rel. Int.
100%-
Fn 7
454.9728
QC Check
49.22-53.00"
0%-
I | I
49.5
I J I I
50.0
T
T
50.5	5l'.0	51.5
Results: P:\P9400_P9499\P9464_W42 PC8\resources\P9464_6042_PCB_004RJ-D10.utp_res. saved 0S-Aug-2008 09:19 (EE)
AP UltraTmce-Pm V3-993 User/System: EEMEC2-038 cc: 7084, 8435
T
—i—i—|—i—i—r-
52.0
1 I 1
52.5
Abs. Int.
-8.72e6
4.36e6
¦O.OOeO
53.0 RT
Peak annotation: Areas, Centroid/
Revised: 04-Aug-2008 10:53:16 (EE) Printed: OS-Aug-2008 09 22 12 Page 22 ol$
-------
AP Lab ID; P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cJ1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Rel. Int.
Fn 1 100%
218,9856
QC (non-EQ) j
9.03-13.00
Abs, tnt
8.1367
0% V i—i—t—|—i—i—i—i—|—i " i i i ^
9.5
t—|—i—i—i—i—|—i—i—i—i—|—i—(—i—i—|—i—!—i—r—|—i—i—!—i—|—i—i—i—i—j—i—i—i—i—j—i—i—i—i—|—t—i—i—i—|—i—r~
10.0	10.5	11.0	11.5	12.0
' ! '
12.5
—i—i—j—i—i—r-
4.06e?
O.OOeO
13.0 RT
Rel. Int.
Fn 2 100%
242.9856
QC (non-EQ)
13.02-17.79
Rel. Int.
Fn 3 100%
292.9824
QC (non-EQ)
17.81-23.26
Abs. Int.
4.13e7
2.Q7e7
i « i O.OQsu
i111 * i11 •11

Abs. lilt
4.07e7
-2,03e7
O.OOeO
16.0
19.0
20.0
21.0
22.0
23.0
Rel. Int.
Fn 4 100%.
330.9792
QC (non-EQ)
23.27-34.14
0%.
[Ill
24.0
"1—¦—'—f—«—I—
26.0
—I—
28.0
30.0
32.0
Abs. int.
-3.98e?
>1.99e7
•O.OOeO
34.0 RT
ReL int.
Fn 5 100%
366.9792
QC (non-EQ)
34.16-41.15
Abs. Int
7.65e6
3.8366
L O.OOeO
41.0 RT
Rel. Int.
Fn 6 100%-
454.9728
QC (non-EQ)
41.17-46.41
0%.
42.0
i i i i
43.0
44,0
	1—
45.0
—I—
46.0
Abs. Int.
-1,33e7
-6.66e6
-O.OOeO
RT
Rel. Int
Fn 7 100%
454.9728
QC (non-EQ"
46.42-54.01
i l i i
47.0
nI r
48.0
-1	1—f	1	!	I	1	?	f—f	f	T	J—
49.0
1 I 	
50.0
i i i i i i i
51.0
52,0
-i—i—i—i—|—i—r-
53.0
Abs. Int.
-1.64e7
8.20e6
¦ O.OOeO
54.0 RT
Results: P:\P9400_P9499\P94B4_6Q42 PC8te$
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Rel. Int.
Fn 1 100%.
218.9856
QC Check
9.03-13.00
Q%-
-V*—
' r ¦	¦	
9.5
1 I I V ( I I I 1
10.0
I I I I I I I I I I I I I
10.S	11.0
11.5
12.0
12.5
Abs. Int.
-9.68e7
-4.84e7
• Q.OOeO
13.0 RT
Rel. Int.
Fn 2 100%-j
242.9856
QC Check
13.02-17.79
0%-
' ' 1 I 1 ' i""
13.5
14.0
' I '
14.5
15.0
* I '
15.5
T""
16.0
16.5
17.0
I i i i i | i i i—r-
17.5
Abs. Int.
-«.86e7
¦ 2.4367
¦O.OObO
RT
Fn 3
Rel. Int.
100%.
292.9824
QC Check
17.81-23.26
0%-
18.0
19.0
->—r
—i—1—*~
20.0
"I—r_
21.0
T J J * I	1	1	1~
22.0
—I—1—r
23.0
Abs. Int.
-4.49e7
¦ 2.25o7
¦ O.OOeO
RT
Rel. Int.
Fn 4 100%-
330.9792 •
QC Check
23.27-34.14 "
0%.
-i	1	r-
24.0
26.0
28.0
-f	1	r-
i i	r	1	
30.0
—
32.0
Abs. Int.
-4.68e7
¦2.3467
•O.OOeO
—r
34.0 RT
Rel. Int
Fn 5 100%.
454.9728
QC Check
34.16-41.15
0%.
35.0
1 I '
36,0
1 I '
37.0
38.0
39.0
' I '
40.0
Abs, InL
-2.03e7
•1.01«7
¦ O.OOeO
41.0 RT
Rel. Int.
Fn 6 100%.
404.9780
QC Check
41.17-46.41
0%.
Rel. Int.
Fn 7 100%
454.9728
QC Check
46.42-54.01
Abs. Int
1,70e7
8.50e6
O.OOeO
54.0 RT
Results: P:\PS400 P9499\P9464 6042 PCB\resaurces\P9464 6042 PCB 004.utp res. saved 05-Avg-2Q08 08:24 (EE)
AP UltraTmce-Pro V3.993 User/System: EEMEC2-038
Peak annotation: Areas, Centroids
PKD: n/a Printed: 05-Aug-2008 08:31:05 Page 2 ot 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-JuI-2008 11:40:03
User: JLJ Datafile: 080724V13_EQ
Rel. Int.
100%-
Fn 1
188.0393
MoCB
4o 8.57e3
9.03-13.00
0%-
3.64e8
9.56
A
I * | " I *f I I J
9.5
1.54e9
11.30
1.34e9
11.46
-i—i—t—f—i—i—I—r
10.0
10.5
11.0
11.5
r-^
12.0
I 1 I I
) | I
12.5
Abs. Int.
-6.45e8
•3.23e8
-O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
190.0363
MoCB
4o 5.80e3
9.03-1300
1.19e8
9.56
0%-*1—I—I—I—|	1—I	!—I—| ' I 'l	!	1—j-
9,5
4.96e8
11i?° 4.3468
" 11.46
10.0
10.5
11.0
11.5	12.0
12.5
Abs. Int.
-2,09e8
1.05e8
-H-0.00e0
13.0RT
Rel. Int.
100%-
Fn 1
200.0795
MoCBSM. .
4a 1.41e4
9.03-13.00
0%-
5.8B©7
9.55
¦¦¦¦>	r	t	r		i	i	1	f	rM»i	%	tmi
10.0
10.5
11.0
7.68e7
1,45
•••I	n	*	i	>	i	»	i	''	'	*	»'	I	'	i	'	'	'I	'	'	
11.5
12.0
12.5
t t I I
Abs. Int.
-3.34e?
¦ 1.67e7
¦O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
202.0766
MoCBStd, .
40 8.71e4
9.03-13.00
0%-

2.17e7
9.55
6.23e5
10.38	
9.5
f | i r r1 i [ i i i i | t i i
10.0	10.5
-i j—i-
11.0
r | i Pi i | i
11.5
120
Abs. Int.
-1.05e7
•5.24e6
O.OOeO
j | i i r i 'j i i 11 i | t T" t
12.5	13.0RT
Rel. int.
100%
Fn 1
218.9856
QC Check
9.03-13.00
Abs. Int.
-9.68e7
4.84e7
i ¦ O.OOeO
13.0RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_004.utp_re$, saved 05-Aug-2008 08:24 (EE)
AP UltraTmee-Pm" V3.993 User/System: EEJEEC2-038 cc: 8995, 4314
Peak annotation: Areas, Centnoids
PKD: OS-Aug-2008 08:24:08 Printed: 05-Aug-2008 08 31:06 Page 3 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JU Datafile: 080724V13_EQ
Rel Int.
100%-
Fn 1
222,0003
DiCB-1
4o 7.34e3
9.03-13.00
0%-
I I I | I I I I [ 1 I t
9.5
! I I [ T 1 1 I
10.0
10.5
6.82e6
11.86
E I t I f I I 1 I 111 f I I I I 1 I I 1
11.0
11.5
12.0
3.4186
2.34e6 12.72
12.55 A
A A
Abs, Int.
-5.14e6
•2.57e6
•O.OOeO
12.5
13.0RT
Rel. Int.
100%-
Fn 1
223.9974
DiCB-1
40 3.26e4
9.03-13.00
3.59e5
9.19
2 45e5 3.56e5
10.38 10.54
¦T	T	|	T	T	I	T	]	1	1	T	1	|	1	1	T	f—|-T
9.5	10,0
njHlTpr
10,5
• I '
11.0
~i—|—t i i
11.5
1.02e7
4.69e6
-p-i—r—l—i—p—i—i—r-
12.0
3.55e6
2.40e6 12-72
12,55
' I •
12.5
Abs. Int.
-3.36e6
1 68e6
•O.OOeO
13.0 RT
Rel. Int.
100%-
Fn 1
234.0406
DiCBStd.
4a 1.46e4
9.03-13.00
0%-
9,5
10.0
10.5
11.0
11.5
12.0
12.5
Abs. Int.
- i.31e7
¦6.54e6
-O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
236.0376
DiCBStd. .
4a 9.64e3
9.03-13.00
0%-
9.5
| I I I I | I t I T | I I -t'T~ | >
10.0	10.5
11,0
11.5	12.0
r j f i
12.5
Abs. Int.
-8.18e6
•4.09e6
-O.OOeO
13.0RT
Rel. Int.
100%.
Fn 1
218.9856
QC Check
9.03-13.00
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PC8_004 ulp_res, samel OS-Aug-2008 08 24 (EE)
AP UttraTmc*-Pto V3.993 User/System: EE/EEC2-038 cc: 4831, 9565
Abs. Int.
-9.68e7
4,84e7
O.OOeO
13.0RT
Peak annotation: Areas, Cantnoids
PKD: 05-Aug-2008 06:24:09 Printed: OS-Aug-2008 08:31:0? Page 4 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13_EQ
Rel. Int.
100%-
Fn 2
222.0003
DiCB-2
4a 9.65e3
13.07-17.79
0%-
3.83e7
13.41
r4V
1	1.3268
13 77 14.04
A,,Aa
1 I t J I 1 "i 1 j' I f" I 1' J I' I 7 i—p-
13.5	14.0
14.5
I.29e8
15.57
15.0
15.5
16.0
1 .OSes
16.61
2.22e8
16.31
2.67e7
-i—it i '| i—<—i—i' |
16.5
17.0

Abs. Int.
-1.85eB
•9.23e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
402 97e4
13.07-17.79
0%-
¦n—n—| 'i" i i
2.61e7
13,41
- »
Abs, Int.
-2 74e7
1.37e7
17.5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
236.0376
DiCB Std,
4o9.77#3
13,07-17,79
0%-
4.88e7
13.40
13,5
I37e:
16.8
14.0
14.5
15.0
15.5
16.0
16.5
17.0
17.5
Abs. Int.
-1 68e7
-8 39e6
I O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
13.07-17.79
Abs. Int.
-4.86e7
2.43e7
4
O.OOeO
Results: P:\P9400_P9499\P94B4_B042 PCB\resoumes\P9464_6042_PCB_0Q4.utp_res, saved 05-Aug-2008 08:24 (EE}
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 3331, 5308
Peak annotation: Areas, Centmids
PKO: 05-Aug-2Q0$ 08:24:09 Printed: OS-Aug-2006 08:31:08 Page S of 22
-------
AP Lab ID: P9464_6Q42_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11(40:03
User: JLJ Datafile: 080724V13_EQ
Rel. Int
100%-
Fn 2
255.9613
TrCB-2
4a 3.42e3
13.02-17.79
0%-
13.5
4.00e6
14.41
1,94e7
16.84
14.0
14.5
15.0
15.5
i i i r j i i * i i | i
16.0
1.9967
16.41
7.84e6
16.61
16.5
17.5
Abs. Int.
-6.23e6
3.11e6
•0.00 eO
RT
Ret. Irit.
100%-
Fn 2
257.9584
TrCB-2
4a 4.33e3
13.02-17.79
0%-
—T—|—v—f—f—v—|—I—	
13.5	14.0
3.98e6
14.41
t1
rT_
14.5
15.0
—i—j—i—r-
15.5
2.45e7
1.96e7
18.83
1.95e7
7.5Be6
16.61
1.65e7
17.38
J.
Abs. Int.
-5.99e6
¦2.99e6
17.5
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
268.0016
TrCB Std.
4a 6.13e4
13.02-17.79
0%-
4.33e6
13.45
2.75e6
17.08
rr
13.5
'[	I¦ T'I I ) I 'I I I" | I
14.0	14.5
1-1 f '1" f I "I
15.0
I i i i i I i r i i
15.5
	f" '	
16.0
16.5
' I"1
17.0
Abs. Int.
-1.13e7
5.66e6
17.5
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
269.9986
TrCB Std.
4a 4,66e4
13.02-17.79
0%-

13.5
'"'"I
14.0
1 '• 1 ' ' T
14.5
15,0
I | I I I I | I I I I
15.5
16.0
i i i i | f r i i |
16.5
17.0
17.5
Abs. Int.
-1.11e7
•S.57e6
-(—O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.02-17.79
0%-
13.5
14.0
14.5
15.0
15.5
16.0
	¦ I 1 ' ' ' I
16.5
"I 1
17.0
-r-T-r-
17.5
Abs. Int.
-4.86e7
•2.43e?
-p—O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PC8\resources\P9464_6042_PCB_004.utp_ms, saved 05-Aug-2008 08:24 (EE)
AP UltraTmce-Pm 1/3.993 User/System: EEJEEC2-038 cc: 7616, 1336
Peak annotation: Areas, Centralis
PKD: QS-Aug-2008 08:24:09 Printed: O5-Aug-20O8 08:31:09 Page 6 of 22
-------
AP Lab ID: P9464_6042_PCB_004
tristr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Ju1-2008 11:40:03
User: JLJ Datafile; 080724V13 EQ
Rel. Int.
100%-
Fn 3
255.9613
TrCB-3
4o 4.43e3
17.81-23.26
0%-
18,0
118e7
18.32
/T\
4.69e73,81e7
18.72 18.91
4.65e7
19.17

AAA
19.0
1.1668
19.44
4,55e7
19.96
-A.
2.69e7
5.99e6A 21.59
2147A /\
5.89e7
22.00
1.l9e7
21.89
20.0
21.0
i
A
22.0
23.0
Abs. Int.
-5.09e7
•2.5567
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
4a 6.08e3
1781-23.26
0%-
I.t5e7
18.32
18.0

4.54e73.71e7
18.72 18.90
AAA
19.0
1.13e8
4.41e7
19.96
-A
i i i
3.3167
21.28
A
2.56e7
21.59
A
5.49e?
22,08
20.0
21,0
~r
** i
22.0
1.93eB
1.62e8
23.0
Abs. Int.
-4J5e7
•2 48e?
•O.OOeO
RT
Rel, Int.
100%-
Fn 3
268.0016
TrCB Std.
4
-------
AP Lab ID: P9464_6042_PCB_004
Iristr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq; 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Rel. Int.
100%-
Fn 2
289.9224
TeCB-2
4o 1.65e3
13.02-17.79
0%-
13.5
14.0
9.63e3
16.00
i.05e4
16.62
y y j"ii)
14,5
15,0
15.5
16.0
T
165
3.80e5
17.22
| I I' T l | I I W>j"l
17.0
17.5
Abs. Int.
-7.71e4
3 85e4
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
291.9194
TeCB-2
4o 2.53e3
13.02-17,79
13.5

14.0
14.5
15.0
15.5
5,08e5
17.5
Abs. Int.
-8.19e4
-4.10e4
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Rel. Int.
100%-
Fn 2
301.9626
TeCBStd.
4o 7.96e3
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14.0
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-6.6186
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Rel. Int.
100%-
Fn 2
303.9597
TeCBStd.
40 3.37e3
13.02-17.79
0%-
13.5
S.22e7
17.20
14.0
14.5
15.0
15.5
16.0
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17.0
17.5
Abs. Int.
-8.31e6
¦4,16e6
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Rel. Int.
100%-
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242.9856
QC Check
13.02-17.79"
0%-
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13.5
14.0
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14.5
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16.0
,MT""1		r,m
16,5
17.0
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17.5
Abs. Int.
-4 86e7
¦2.43e7
•O.OOeO
RT
Results: P:\P9400_PB499V9464_6042 PC8\re5OUwes\P9464_6042_PCB_004Mtp_nes, saved Q5-Aug>2008 08:24 (EE}
AP UltrsTrace-Pro I/3.993 UserfSystem: EE/EEC2-038 cc: 6792. 3647
Peak annotation: Areas. Centmids
PKD: QS-Aug-2008 08:24:09 Printed; 0S-Aug-2008 08:31:11 Page 8 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13_EQ
Rel. Int.
100%-
Fn 3
289 9224
TeCB-3
4o 3.52e3
17.81-23.26
0%-
Rel. Int.
100%-
Fn 3
291,9194
TeCB-3
4o 3.36e3
17.81-2326
0%-
3.76e6
18.94
18.0
19.0
! | I 1 I I | 1
20.0
1,38e7	1.70e7
20 98	21.38 5.§9e6
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21.0

18.0
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18.94
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1.2968
19.0
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1.78e7
20.98
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T
21.0
2.19e7
21.38 7.65e6
/\ 21.63
|\ |
1,26e8
21.85
1,64e8
21.85
1.49e7
22,10
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23.0
5.93e6
1.34e7
22.87
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22.0
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23.0
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-3,02e7
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Abs, Int.
-3.90e7
1,95e7
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RT
Rel. Int.
100%-
Fn 3
301.9626
TeCBStd.
4a 5.43e3
17.81-23.26
0%-
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18.0
t | f I I
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20.0
21.0
22.0
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-1,00e7
5.02e6
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Rel. Int.
100%-
Fn 3
303.9597
TeCB Std,
4
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# 1-ACD-M23-3
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User JLJ Datafile: 080724V13_EQ
Rel. Int.
100%-
Fn 4
289.9224
TeCB-4
4o 9.53e3
23-27-33-00
0%-
1,23e8
23-81
4 89e8
23.57
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1.74e7
24.17 n
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24.0
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25.85
25.02
24.52
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A 26.38
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26.0
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26.99
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1,36e8
28.97
3.87e7
27,66
2.00e7
28.50
27.0
4.99e6,
28.0
29.0
30.0
31.0
32.0
Abs. Int.
-3.25e7
1.62e7
•O.OOeO
RT
Rel, Int.
1.5968
100%-,
23.81
Fn 4 :


291.9194 ¦


TeCB-4


4o 1,33e4 .


23.27-33.00 ¦
6.46e6



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4-
1.75eB
26.97
5 13e7
27«66 3A3?J 2 60e7
28A12 28.50
A

25.0
26.0
27.0
28.0
29.0
30.0
31,0
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32.0
Abs. Int.
-4.21e7
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Rel. Int.
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301.9626
TeCB Std.
40 7.36e3 .
23.27-33.00 ¦
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-1.23e7
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Rel. Int.
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303.9597
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40 5.75e3
23.27-33 00
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-1.58e7
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330.9792 ¦
QC Check
23.27-33.00
Abs. Int.
-4,68e7
-2 34e7
0%-
I T I > | % » T I [ T I
25.0
30.0
I ( > i i O.OOeO
RT
24.0
26.0
27.0
28.0
29-0
31.0
32.0
Resu/fs; P.V94O0_P9<»99tf:,9464_6(M2 PCBSmsaurces\P9464_6042_PCB_004.utp_res. saved 05-Aug-2008 OS:24 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 0135, 028S
Peak annotation: Areas. Centmids
PKD: 05-Aug-2Q08 08:24:09 Printed: OS-Aug-2008 08:31:14 Page 10 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample 10: Run# I-ACD-M23-3
VSIR expt: pcb0405_cI1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Rel. Int.
100%-
Fn 3
323.8834
PeCB-3
4a 1,86e3
17.81-23.26
0%-
18.0
1 i 1
19.0
' 20.0
r ¦ r- f i^-T1 —t"¦ - r1 -11 -
21.0
7 28e5
22.09
3.20e5
21.78

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-1.7685
8.81 e4
23.0
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RT
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100%-,

1.16eB
22.09
/)


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-3.03e5
Fn 3 :
325.8804 ¦
PeCB-3
4a 2.00e3 "
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5.ises
21.78
A
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19.0
20.0
21.0
22.0
23.0
RT
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100%-
Fn 3
337.9207
PeCBStd.
4a 2.78e3
17.81-23.26
0%-
18.0
19.0
20.0
21.0
22.0
23.0
Abs. Int.
r-1.41 e7
¦7.06e6
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RT
Rel. Int.
100%-
Fn 3
339.9177
PeCB Std.
4a 2.29e3
17.81-23.26
0%-
18.0
19.0
20 0
21,0
22.0
Abs. Int.
-9.04e6
¦4.52e6
-O.OOeO
23.0 RT
Rel, Int.
100%-
Fn 3
292.9824
QC Check
17.81-23.26
18.0
19.0
20.0
21.0
Results: P:)P9400_P9499\P9464_6042 PCB^esourcesf94S4_6042_PCB_004.utp_res. saved 0S-Aug-2008 08:24 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 8231, 3811
Abs. Int.
4.49e?
2.25e7
-O.OOeO
RT
Peak annotation Areas. Centroids
PKD: 0S-Aug-200B 08:24:09 Printed: QS-Aug-2008 08:31:15 Page 11 of 22
-------
AP Lab ID: P9464_6042_PGB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13_EQ
Rel, Int.
100%.
Fn 4
323,8834
PeCB-4
4o 1,94e4
23.27-34.14
0%-
2,74e7
2.46e7
31.89
1 92e7
28.41
1.45e7
14267
30.54
1.52e7
27.65
26.76
7.10e6
31.20
7.48e6
24.28
6.53e
5.40e6
33.13
4,49e6
5.68e
3.85e6
3.i8e6„„ „
A25 22 8.50e5
JX A 25.60
2.3766
29.39
5.26e5
6.28es
23.72
26.26
Abs. Int.
-6.44e6
3.22e6
O.OOeO
24.0
26.0
28.0
30.0
32.0
34,0 RT
Rel. Int.
100%-
Fn 4
325.8804
PeCB-4
4a 1 03e4
23.27-34.14
1.11e7
24.29	4 71e6
9.19e5 A25 22l.35e6
24 66 7\ a 25 60
24.0
3. 2e7
2.38e7
2.46e7
27.BS
7.25e6
9.37e
6.28e6
3.89ee
28.67
29.39
4.4?e7
30.91
2.37e7
30.33
H6e7
31.20
iV
26.0
28.0
30.0
3.98e7
31,89
32.0
8.88e6
33.13
	A
Abs. Int.
-1.06e?
-5.32e6
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34.0 RT
Rel. Int.
100%-
Fn 4
337.9207
PeCB Std.
4o4.51e3
23.27-34,14
0%-
24.0
5.20e7
26.75
6,90e7
28,98
1,14i
28.8(5
5.85e7
30.61
6.16e7
31.33
M\ J\
6.24e7
31.87
26,0
28.0
30.0
32.0
Abs. Int.
-1J2e7
•8.09e6
-•—i—[—1O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
339.9177
PeCB Std.
4o 3.72e3
23.27-34,14
0%-
24.0
2.22e6
25.84
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26.0
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26,75
4,39e7
28.98
2.59 if
28.
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167.7 3-92e7
30 61 . 31f
3.94e7
31.87
28.0
30.0
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32.0
Abs. Int.
-1.07e7
5.36e6
•O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Results: P:\P9400_P9499\P9464_6042 PCBtesaunxs\P9464_6042_PCB_004.utp_ms, saved OMug-2008 08:24 (EE)
AP UiimTrace-Pro V3.99J User/System: EE/EEC2-038 cc: 2087. 0518
Abs. Int.
-4.68e7
2.34e7
O.OOeO
34.0 RT
Peak annotation: Areas. Centroids
PKD: 0S-Aug-2008 08:24:09 Printed: OS-Aug-2008 08:31:18 Page 12 of 22
-------
AP Lab ID; P9464_6042_PCB_004
Instr. AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13.EQ
Rel. Int.
100%-
Fn 5
323.8834
PeCB-5
4a 3.76e3
34.16-41.15
0%-
35.0
I I | I I *
36.0
1.28e6
36.77
—i^=>—i
r_r"T'
37.0
ioie6
39.15
38.0
39.0
40.0
Abs. Int.
r94te6
•4.71e6
•O.OOeO
41.0 RT
Rel, Int.
6.45e7
100%-]
34,46
Fn 5


325.8804 ¦


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4o 7.42e3 -


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i-
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36.76
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36.0
37.0
6,81e7
38.02
IX
2.11e6
39,15
38.0
39.0
40.0
Abs. Int.
-1.57e7
-7.85e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
337.9207
PeCB Std.
4o 1.36e4
34.16-41.15
0%-
35.0
T-r
36.0
37.0
38.0
39,0
40.0
Abs. Int.
-1.53e7
•7.65e6
"1—r-*~ O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
339.9177
PeCB Std.
4a 6.90e3
34.16-41.15
0%-
35.0
36.0
37.0
38,0
39.0
40.0
Abs. Int.
r9,70e6
•4.85e6
-O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454,9728
GC Check
34 16-41 15 J
0%-
' I '
35.0
1 1 | » t t
36.0
37.0
38.0
Results: P:\P9400_P9499\P9464_$042 PCB\resoumes\P9464_6042_PCB_004.utp_ms, saved 05-Aug-2008 08:24 (EE)
AP UttraTrace-Pro V3 993 User/System: EE/EEC2-038 cc: 6915. 5240
-f—J—i—r-
39.0
40.0
I I 1 | 1
Abs. Int.
-2.03e7
-1.01e7
~l—O.OOeO
41,0 RT
Peak annotation: Areas, Centroitis
PKD: 05-Aug-2008 08:24:09 Printed: 05-Aug-2008 08:31:17 Page 13 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13_EQ
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4o1.83e3
23.27-34.14
0%-
1.38e6 e.98e5
26.89 A 27.42
I.59e7
29.95
7.35e6
7.70e6 „ _ I	„ „ _ 31.00
1.06e6 29 20 2.18e6H64e6 "5e6 i 1 34e6
/f°A62 A 31«
^ (A

24.0
26.0
28.0
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3.36e7
2.2267
32.47
31.95
32.0
Abs. Int.
-7,20e6
•3.60e6
¦O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4o 1 35e3
23.27-34.14
0%-
1.12e6 7.42b5
26 89 A 27.42
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24.0
26.0
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1.72e6
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1.78e7
32.47
2.72e7
33.52
4.86e6
z.Saae
31.95
32.0
Abs. Int.
-5.67e6
•2.83e6
-O.OOeO
34.0 RT
Rel. Int.
100%-
Fr» 4
371.8817
HxCBStd.
4o 2.78e3
23.27-34.14
0%-
Rel. int.
100%-
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373.8788
HxCB Std.
4o 2.61 e3
23.27-34.14 ¦
0%-
t	J	I""
24.0
5.43e7
26.54
26.0
4.31 e7
26.55
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30.0
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24.0
26.0
28.0
30.0
1—I—1
32.0
4.6267
4.32e7
32.45
33.49
3.61 e7
3.36e7
33.49
Abs. Int.
~1.27e7
•6.34e6
•O.OOeO
34.0 RT
Abs. Int.
r1.02e7
•5.12e6
-j—O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Abs. Int.
4.68e7
2.34e7
O.OOeO
34.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\msauKe$\P9464_6042_PCB_0Q4:utp_res, saved OS-Aug-2008 0B:24 (EE!
AP UltraTrace-Pro V3.993 User/System EEJEEC2-038 cc 2437. 9710
Peak annotation: Areas, Centroids
PKD: 05-Aug-2008 08:24:09 Printed: 05-Aug-2Q08 08:31:18 Page 14 of 22
-------
AP Lab ID: P9464_6042_PCB_004
instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405„cl 1-10_mm6 GC: pcbx100_a Vial:
62
Acq: 24-Jul-2Q0S 11:40:03
User: JLJ Datafile: 080724V13 EQ
Rel. Int.
100%-
Fn 5
359-8415
HxCB-5
40 6.11e3
34.16-41.15
0%-
6.44e6
34.56
i ¦ 	*	
t—J—r~r
35.0
, ™ ,5,4766
3.90e6 35.61
35.36 A
A IV
f i I t 'T*' i—r
9.80e6
36.00
3.04e6
3S112
36.0
37.0
38.0
39.0
1.56e6
39.18
?.60e6
39,64
Abs. Int.
-5 56e6
-2.78e6
(92b5
.75
i t I—i—|—i—r-"T—r~"i—i i i
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40.0
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41.0 RT
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4a 4.44e3
34.16-41.15
0%-
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34.S6
/V
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4,63e6
3.36e6 35 61
35 35 A
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7.83e6
36.00
35.0
36.0
2.33e6
38.12
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37.0
38.0
1,24e6
39.18
5.83e6
39.84
Abs. Int.
-4.48e6
2.24e6
O.OOeO
39.0
40.0
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41.0 RT
Rel. Int.
100%-
Fn 5
371,8817
HxCBStd.
4o 5.85e3
34.16-41,15
0%-
35.0
4,88e7
35.98
36.0
37.0
38.0
39.0
40.0
Abs. Int.
-1.73e7
•8.67e6
, . O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
373.8788
HxCBStd.
4o 6.25e3
34.16-41.15
0%-
35.0
36,0
37.0
38.0
39.0
40.0
I I I I
Abs. Int.
-1.35e7
•6.77e6
¦O.OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15
Abs. Int.
-2.03e7
-1.01 e7
0%-
35.0
36.0
37.0
38.0
39.0
40.0
—I—r-*— 0 .OOeO
41.0 RT
Results: P:\P9400_P949S\P9464_6042 PCB\rBSOurces\P9464_6042_PCB_004utp_res. saved OS-Aug-2008 08:24 (EE)
AP UltfaTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 51 OB, 0899
Peak annotation: Areas, Centmids
PKD: OS-Aug-2008 06:24:09 Printed: OS-Aug-2008 08:31:20 Page 15 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13_EQ
Rel. Int.
100%-
Fn 4
393.8025
HpCB-4
4a 1.94e3
30.00-34,14
0%-
30.5
31.0
7.54e6
31.63
i.i see
31.34
1.76e6
32.06
32.0
5.74e6
32.36
6.28e5
32.74
4.77e6
Abs. Int.
-1.93e6
•9.63e5
33.0
33.5
[ii- O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
395.7995
HpCB-4
40 1,58e3
30.00-34.14
0%-
30.5
1.08e6
31.34
7.28e6
31.63
31.0
31.5
1.70e6
32.07
5.35e6
32.36
6.04e5
32.74
32.0
32.5
33.0
33.5
4.63e6
33.88
Abs. Int.
-1.75e6
¦8.76e5
34.0
¦O.OOeO
RT
Rel. Int.
5.27e7



100%-,
31.32
A



Fn 4 !
A


3.68e7
405,8428 ¦



33.86
A
HpCBStd, "



A
4o 3.52e3 .



/ \
30,00-34,14 ;
/ \


/ \
0%-

T-^T-r-^-r-T-r-T	'		I	i	t	>	'	[			»	t	
I ' 1 ' 1 1 ' 1 ' 1 l-'-'-v ' I 	»	

Abs. Int.
-1.26e7
¦6.29e6
¦O.OOeO
30.5
31.0
31.5
32.0
32.5
33.0
33.5
34.0 RT
Rel. Int.
100%-,
Fn 4
407.8398
HpCBStd. J
4o 3.12e3 ¦
30.00-34.14
0%-
30.5
31.0
5.08B7
31,32
31.5
32.0
32.5
33.0
33.5
3.48e7
33.86
Abs. Int.
-1 23e7
¦6.13e6
34.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
330.9792
QC Check
30.00-34.14'
0%-
30,5
31.0
31,5
32.0
32,5
' l""!1	1	T	T'"
33.0
m,t	r	r	%	r	t	r	i	v"
33.5
Abs. Int.
-4.68e7
•2,34e7
34.0
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\msowtes\PS464_6042_PCB_004.utp_res, saved Q5-Aug-2008 08:24 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 7138. 0745
Peak annotation: Areas, Centroids
PKD: 05-Aug-20Q8 08:24:09 Printed: OS-Aug-2008 08:31:21 Page IS of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr; AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbxl00_a Vial: 62
Acq: 24-Jul-20Q8 11:40:03
User: JLJ Datafile: 080724V13_EQ
Rel. Int.
100%-
Fn 5
393.8025
HpCB-5
4a 4.45e3
34.16-41.15
0%-
2.96S7
34.64
2.80e6
34.41
1.00e7 A
fl\
35.0
I.40e7
35.71
1.0567
36.23
36.0
t
37.0
i i i i
7.05e6
37.57
./"v .
T
6.19e6
38.40
3.l1e7
39.18
i.3ie7
39.00
/V-
38.0
39.0
40,0
Abs. Int.
-2.05e7
1.02e7
¦O.OOeO
41 0 RT
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4a4 27e3
34.16-41.15 ¦
0%-
2.85e7
34.64
2.78e6
34.41
¦ .
h	B.94e6 A 1.38e7
\	35.14 \ 35.71
A , pill A
1.0187
36.23
35.0
36.0
37.0
6.60e6
37.57
6.14e6
38.40
. .
3.01 e7
39.16
38.0
i
1.27e7
39.60
A -
39.0
40.0
Abs. Int.
-1.97e7
•9.83e6
•O.OOeO
*41~0 RT
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 SW.
4a6 05e3
34.16-41.15
0%-
35.0
36.0
37.0
38.0
r f*"t	V I	I	I'""
39.0
Abs. Int.
-9.26e6
4.63e6
O.OOeO
T"-| -r i t l | I I I I 'J
40.0	41.0 RT
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std.
4a 4.61e3
34.16-41.15
0%-
35.0
36.0
37,0
38.0
39,0
"t"" i—|—i—i—i—i—|—"—i—r—i—f-
40.0
Abs. Int.
-8.92e6
¦4.46e6
¦O.OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
35.0
36.0
37.0
M,r	r	»	r"
38.0
39.0
40.0
Abs. Int.
-2.03e7
¦1.01e7
-p-r—O.OOeO
41.0 RT
Results: P:\P9400_P9499\P94S4_6Q42 PCB\resounxs\P9464_6042_PCB_004.up_ms, saved 05-Aug-200a 00:24 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 9204. 7487
Peak annotation; Areas. Centmkls
PKD: 05-Aug-2008 08:24:09 Printed: 05-Aug-2008 0&31:22 Page 17 of 22
-------
AP Lab ID: P9464_6042_PCB_0Q4
Instr; AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jui-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Ret, Int.
100%-
Fn 6
393,8025
HpCB-6
4o 3,72e3
41,17-46.41
0%-
8.62e5
41.54

9.1 see
41.73
42.0
I,85e6
43.48
43,0
44,0
45.0
3.Q2e5
45.31
46.0
AbS- Int.
-2.09e6
¦ 1,04e6
O.OOeO
RT
Rel. Int.
100%
Fn 6
395.7995
HpCB-6
4o 3.15e3
41.17-46.41 H
0%-
8.53e5
41.54
¦t—» ~ »—	r i—'t ^ i—p
8.98e6
41.73
42.0
| 1 1 1 I | I
43.0
I.9ie6
43.48
-JS-,
I	| | "l | I
44.0
"1—1—1—1—'—I—
45.0
46.0
Abs. Int.
-2,03e6
•1.02e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
405.8428
HpCBStd,
4o 1.04e4
41.17-46.41
0%-Lr
4.80e7
41.72
42.0
43.0
* f	I I I1"" I | I I I
44.0
1—I—r_
45.0
46.0
Abs. Int.
r 1.08e7
•5.41e6
¦O.OOeO
RT
Rel. Int.
100%-,
4.65e7
41.72
ft
Fn 6
407.8398 -
HpCBStd. '
4o6.64e3
41,17-46.41 ¦

0%-
	A V
42.0
43.0
1 I—1
44.0
45.0
46.0
Abs. Int.
-1.06e7
-5.31e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46,41
0%-
42,0
—,—|—i
43.0
44.0
1—
45.0
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PC8_004.utp_res. saved OS-Aug-2008 08:24 (EE)
AP UltraTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 0035, 1593
46.0
Abs. Int.
-1 67e7
8.36e6
¦O.OOeO
RT
Peak annotation: Areas. Centroids
PKD: 05-Aug-2008 08:24 09 Printed: OS-Aug-2008 08:31:23 Page 18 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Re!. Int.
100%-
Fn 5
427.7635
OcCB-5
4o1.57e3
34.16-41.15
0%-
I I 1 I
35.0
5.81e6
35.81
A
i
36.0
i—i—*—r
7.82e6
36.58
tA-t-
I.l2e6
37.13
8.28e6
37.41
37.0
38-0
1 1 I 1
39.0
4.24e7
39.74
2.24e7
111766
39.84
40.55
40.0
Abs. Int.
-9 55e6
•4.77e6
41.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 5
429,7606
OcCB-5
4a 1.99e3
34,16-41.15
0%-
35.0
6.38e6
35.81
A.
36.0
8.73e6
36.58
1,29e6
I.00e7
37.41
° A
37.13/A
37.0
38.0
39.0
4.93e7
39.74
2.55e?
40.28
40.0
Abs. Int.
-1,09e7
5.47e6
41.0
¦ O.OOeO
RT
Rel. Int.
100%-
Fn 5
439.8038
OcCBStd.
4o 2.17e3
34.16-41.15
0%-
35.0
36,0
37.0
38.o"
39.0
"i	i'	»—i"*"*! i | I
40.0
Abs. Int.
-9.89e6
¦4,95e6
-y-r—O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std.
4a 1,80e3
34.16-41.15
0%-
35.0
4.70e7
35.79
36.0
37.0
38.0
39.0
40.0
Abs. Int.
r1.09e7
•5.45e6
I i O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
Till
35,0
36.0
''	I	
37.0
38,0
11(11
39,0
Abs, Int.
-2.03e7
-1.01e7
~i—t—i—i—i—i—i—i—*—i—|—r~*~ O.OOeO
40.0	41.0 RT
Results: P:\P9400_P9499IP9464_S042 PCBtesources\P9464_6042_PCB_Q04.utp_ms, saved 05-Aug-2008 08:24 (EE)
AP UltraTrace-Pm ^3,993 User/System: EE/EEC2-038 cc: 7S0S, 3401
Peak annotation: Areas, Centmids
PKD 05-Aug-2008 08:24:09 Printed: 0S-Aug-2008 08:31:24 Page 19 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID; Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Rel. Int.
100%-
Fn 6
427.7635
OcCB-6
4 o 2.36e3
41.17-46.41
0%-
1.47e7
41.54
42.0
43.0
3.53e7
43.48
4.88e6
43,86
8.93e5
45.30
44.0
45.0
46.0
Abs. Int.
-?.39e6
3 69e6
•O.OOeO
RT
Rel. Int.
100%-
Fri 6
429.7606
OcCB-6
4o 2.42e3
41.17-46.41
0%-
1.62e7
41.54
42.0
3.93e7
5.27e6
43.86
-/V
9.85e5
45.30
43.0
44.0
45.0
46.0
Abs, int.
-8.10e6
•4.05e6
¦O.OOeO
RT
Rel. int.
100%-
Fn 6
439.8038
OcCB Std.
4o 2.64e3
41.17-46.41
0%-
42,0
2,84e7
43,45
43,0
3,18e7
43.85
1B1e6
413.55
45.0
r i I
46.0
Abs. Int.
-6.71e6
•3.36e6
-O.OOeO
RT
Rel. Int.
100%-
Fn 6
441,8008
OcCB Std.
4o 3.59e3
41.17-46.41
0%-
42.0
3.62e7
3.29e7	43.B5
43.46
43.0
45.0
46.0
Abs. Int.
r7.59e6
3.79e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41'
0%-
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-1.67e7
•8.36e6
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_G042_PCB_004.utp_m$, saved 05-Aug-2008 08:24 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-Q38 cc: 9329, 3545
Peak annotation: Areas. Centroids
PKO: 0S-Aug-2008 08:24:09 Printed: OS-Aug-2008 08:31:25 Page 20 of 22
-------
AP Lab ID: P9464J»042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Data file: Q80724V13_EQ
Rel. Int.
100%-
Fn 6
461.7245
NoCB
4o 1 68e3
41.17-46.41 ¦
0%-

8.56 e6

42.11
5.8386
A
41.34
A

42.0
43.0
r | y i i i |
44.0
45,0
1,33e7
45.30
46.0
Abs. Int.
(-3.0366
1.51e6
¦O.OOeO
RT
Rel. Int.
100%-
Fri 6
463.7216
NoCB
4o 2.42e3
41.17-46.41
0%-

1.71e7

45.30
A
1.09e7
A
42,11
a
42.0
430
44.0
45.0
46.0
Abs. Int.
r3.85e6
1.92e6
¦O.OOeO
RT
Rel. Int. 2 77e7
100%-
Fn 6
473.7648
NoCB Std.
4o 3 29e3
41.17-46.41
0%-
41.32
42.0
43,0
44.0
I I 1 t
45.0
46.0
Abs. Int.
-6.40e6
3.20e6
O.OOeO
RT
Rel. Int.
100%-
Fn 6
475.7619
NoCB Std.
4o 3.73e3
41.17-46.41
0%-
41.32
42.0
I ) I I I I |
430
i i I i i i—i—| i
44.0
-i	1	1	r-
45.0
2.58e7
45.28
46.0
Abs. Int.
-7.91e6
•3.95e6
O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41,17 -46.41
0%-
42.0
43.0
44.0
45,0
Results: P:\P94Q0_P9499VB464_6042 PCB(resources\P9464^E042_PC9_004 ulp_res. saved 05-Aug-2008 08:24 (EE)
AP UttraTrace-Pro V3 993 User/System: EE/EEC2-038 cc: 722J. 0632
46,0
Abs. Int.
-1,67e7
8 36e6
¦O.OOeO
RT
Peak annotation: Areas. Cenlmids
PKD: 05-Aug-2OO8 08:24:09 Printed: OS-Aug-2008 08.31 26 Page 21 of 22
-------
AP Lab ID: P9464_6042_PCB_004
Instr: AutoSpec-Premier MM6
Sample ID: Run# I-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 62
Acq: 24-Jul-2008 11:40:03
User: JLJ Datafile: 080724V13 EQ
Rel. Int. «««*
100%n 46i63
Fn 7
497.6826
DeCB
4o 8.08e2
46.42-54.01
i r i i
47.0
48.0
49.0
50.0
51.0
52.0
53.0
Abs, Int.
-1.53e6
-7.63e5
I I j I I
-O.OOeO
54.0 RT
Rel. Int. S-ReB
100%-,
46.63
Fn 7
499.6797
DeCB
4ct 1.15e3
46,42-54.01
0%-
I'1 '*
47.0
I I i » |
48.0
49.0
50.0
I | K f
51 0
' I '
52.0
53.0
-i—j—*—r--i—i—f-O.OOeO
54.0 RT
Abs. Int.
-1,31e6
¦6.57e5
46.61
Rel. Int. 3 33?/
100%-
Fn 7
509.7229
DeCBStd. J
4
-------
Datafile: 080801 R20_EQ
Acquired: 01 Aug 2008 23:27:29
Client ID: Run# II-ACD-M23-1 v/	Wt/Vol: 1 -
Lab ID: P9464_6042_PCB_005RJ-D10 A-level: 20 pg

BCS3 6042 PCB ROD CPSM 080801 PCS RB
Nominal ES spike: 4000 pg
Pred
Actual
Diff




Checkcode
p®
RRT
RRT
Sees
Response
Ra
KRF (
Cone

Hoise
DL
1.0006
1.0006
0
3.69E+08
0.77
0.98^
45, 700
4
68E+04
57.9
1.0006
1.0005
-0.2
4.66E+07
0.78
1.03
6,350
4
68E+04
65
1.0007
1.0006
-0.2
1.82E+08
0.62
0.90
28,000
2
04E+05
327
1.0007
1.0006
-0.2
1.86E+07
0.62
0.90
2,920
2
04E+05
326
1.0007
1.0007
0
2.70E+08
0.62
0.90
40,100
2
04E+05
314
1.0007
1.0007
0
2.19E+07
0.57
0.91
3,540
2
04E+05
338
1.0005
1.0005
0
1.19E+08
0.62
0.90
18,000
2
52E+05
405
1.0005
1.0003
-0.5
5.96E+07
1.23
0.97
10,200
5
40E+04
135
1.0006
1.0005
-0.2
2.03E+07
1,25
0.99
3,410
5
40E+04
93.3
1.0005
0.9999
-1.5
5.31E+Q7
1.25
0.93
9, 400
5
40E+04
103
1.0004
1.0005
+0.3
1.16E+07
1.00
0.84
2,230
1
51E+04
31.8
1.0004
1.0004
0
1.42E+07
1.18
0.91
/
3,300
1
27E+03
3.16





J
Recv.



0.7213
0.7220
+0.5
3.72E+07
3.10
1.06
99.3 %

25%
150%
0.8616
0.8635
+ 1.5
3-82E+07
3.06
1.00
108 %

25%
150%
0.8771
0.8876
+ 8.8
1.41E+07
1.58
0.77
51.4 %

25%
150%
1.2330
1.2331
+ 0.1
3-73E+07
1. 59
0 .94
112 %

25%
150%
1.0684
1.0680
-0.4
2.39E+07
1.04
0.67
101 %

25%
150%
1.0809
1.0806
-0.5
3 -01E+07
1.07
0.99
107 %

25%
150%
0.8279
0.8307
+3.3
2.64E+07
0.82
1.00
93.1 %

25%
150%
1.3474
1.3466
-1.5
3.28E+07
0.81
0.88
131 %

25%
150%
1.3274
1.3266
-1.5
2.84E+07
0.79
0.84
119 %

25%
150%
0.8277
0.8278
+0.1
2.74E+07
1.59
1.28
85.1 %

25%
150%
1.1769
1.1764
-1.0
2.89E+07
1.57
1.19
96.6 %

25%
150%
1.1587
1.1583
-0.0
2.84E+07
1.54
1.17
96.3 %

25%
150%
1.1432
1.1428
-0.8
2.98E+07
1.55
1.23
96.4 %

25%
150%
1.1338
1.1334
-0.8
2.73E+07
1.55
1.13
96.4 %

25%
150%
1.2652
1.2647
-1.1
2.93E+07
1.61
1.20
97.2 %

25%
150%
0.9711
0.9711
0
2.47E+07
1.28
1.15
96.7 %

25%
150%
0.8067
0.8069
+0.4
3.11E+07
1.24
1.47
95.3 %

25%
150%
1.0964
1.0964
0
4.81E+07
1.29
1.31
82.7 %

25%
150%
1.0696
1,0696
0
2,41E+07
1.29
1.25
87.3 %

25%
150%
1.1709
1.1709
0
2.44E+07
1.25
1.33
82.9 %

25%
150%
0.8833
0.8834
+0.2
3.33E+07
1.05
1.13
157 %

25%
150%
0.9060
0,9058
-0.5
1 -90E+07
1.09
0.91
111 %

25%
150%
0.7359
0.7357
-0.4
2.59E+07
1.07
1.18
99 %

25%
150%
0.9621
0.9619
-0.5
2.49E+07
1.03
1.30
102 %

25%
150%
0.8332
0.8329
-0.7
2.27E+07
0.93
1.20
85.6 %

25%
150%
1.0086
1.0084
-0.6
2.17E+07
0.90
1.11
103 %

25%
150%
1.0400
1.0400
0
1.64E+07
0.78
0.79
110 %

25%
150%
0.9539
0.9536
-0.8
2.02E+07
0.80
1.07
99.5 %

25%
150%
1.0692
1.0690
-0.6
1.91E+07
1.20
1.06
95.6 %

25%
150%
7
P9464_6042_PCB_005RJ-D10
Name
PCB-77 3 3 ' 4 4 1-TeCB
PCB-81 344'5-TeCB
PCB-105 233'44'-PeCB
PCB-114 2344'5-PeCB
PCB-118 23'44'5-PeCB
PCB-123 2' 344'5-PeCB
PCB-126 33'44'5-PeCB
PCB-156/157 233'44'5/233'44'
PCB-167 23'44'55'-HxCB
PCB-169 33'44'55'-HxCB
PCB-189 233"44'55'-HpCB
PCB-209 DeCB
Actual
RT

31,82'
31.35 /
34.79-/
34.25/'"*
33.80/
33.52
V
37.40 y"
39.93/"
38.96/
42.63/-
44.77 /
49.75 /
ES
PCB-1


11.31 -
ES
PCB-3


13.53 "
ES
PCB-4


13.90 "
ES
PCB-15


19.32
ES
PCB-19


16.73 <
ES
PCB-37
f
)
25. 52s-
ES
PCB-54
/ f
/
19.62-"
ES
PCB-77
I X

31.80 *-
ES
PCB-81

«•—
31.33 ^
ES
PCB-104
/
a

24.46
ES
PCB-105
Qb A"
34.77 -
ES
PCB-114
1
34.23 ^
ES
PCB-118

33.77 *"
ES
PCB-123


33.49 "
ES
PCB-126


37.38 *"
ES
PCB-153


35.36 '
ES
PCB-155


29.38 *"
ES
PCB-156/157


39.92 '
ES
PCB-167


38.94 ¦"
ES
PCB-169


42.63 ^
ES
PGB-170


41.10
ES
PCB-180


42.14 ^
ES
PCB-188


34.23 ""
ES
PCB-189


44.75 <-
ES
PCB-202


38.75
ES
PCB-205


46.91 ""
ES
PCB-206


48.38 ^
ES
FCB-208


44.36
ES
PCB-209


49.73
ac
Analytical Perspectives
Page 1 of 5
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_005RJ-D10
Name
SS PCB-28
SS PCB-111
SS PCB-178
Actual
m
22,01 -
31.83 "
36,79 *
QC
Pred
ERT
0.9320
1.0774
1.0105
CS PCB-28
CS PCB-111
CS PCB-178
22.01
31.83
36.79•
0.9320
1.0774
1.0105
JS	PCB-9
JS	PCB-52
JS	PCB-101
JS	PCB-138
JS	PCB-194
15.66"
23.62''
29.55 ^
36.41 -
46.52 ^
Checkcode:
ptu

FCB-1
2-MoCB

11,32
1.0011
PCB-2
3-MoCB

13.36
0.9879
PCB-3
4-MoCB

13.54
1.0010
PCS-4
22'-DiCB

13 .91
1.0011
PCS-10
26-DiCB

NotFnd
1.0138
PCB-9 :
25-DiCB

15.68
1.0010
PCB-7
24-DiCB

15.83
1.0113
PCB-6
23'-DiCB

16.06
1.0254
PCB-5
23-DiCB

16.35
1.0441
PCB-8
24'-DiCB

16.47
1.0516
PCB-14
35-DiCB

17.98
0.9319
PCB-11
33'-DiCB

18.76
0.9715
PCB-13/12 34"-/34-
-DiCB
19.05
0.9863
PCB-15
44 *-DiCB

19.33
1.0008
PCB-19
22'6-TrCB

16.75
1.0011
PCB-30/18 246-/22
'5-TrCB
18.48
1.1044
PCB-17
22'4-TrCB

18.87
1.1279
PCB-27
23 ' 6-TrCB_

19.05
1.1393
PCB-24
236-TrCB

19.19
1.1471
PCB-16
22'3 -TrCB

19.20
1.1527
Analytical Perspectives
Actual
Diff




Checkcode:
pm
RRT
Sees
Response
Ra
RRF ,
Cone
Noise
DL
0.9321
+0.1
3.37E+07
1.05
1.07*
105 %
30%
135%
1.0771
-0.6
3.63E+07
1.54
1.18
113 %
30%
135%
1.0104
-0.2
1.80E+07
1.11
0.66
105 %
30%
135%
0.9321
+0.1
3.37E+07
1.05
J
1.05
113 %
30%
135%
1.0771
-0.6
3,63E+07
1.54
1.33
109 %
30%
135%
1.0104
-0.2
1.80E+07
1.11
0.78
104 %
30%
135%


3.54E+07
1. 59






2.84E+07
0.77






2.51E+07
1. 55






2.22E+07
1.27






1.89E+07
0. 91





Totals
NON-EMFC

EMPC
DL



Mono-CBs
245,000

245,000
14.2



Di-CBs
278,000

278,000
26.6



Tri-CBs
489,000

489,000
22.4



Tetra-CB;
623,000

630,000
28,8



Penta-CB;
307,000

445,000
286



Hexa-CBs
147,000

148,000
83.8



Hepta-CB:
57,800

57,800
105



Octa-CBs
26,200

27,600
12.5



Nona-CBs
9,050

9,050 j
/ n


1.0011
0
3.66E+08
3.13
1.09 V
36,200
1.44E+04
10
0.9875
-0.3
1.15E+09
3.09
1.01
119,000
1.44E+04
20
1.0011
+0.1
9.35E+08
3.12
1.09
89,600
1.44E+04
18.4
1.0006
-0.4
2.06E+07
SI*
0.98
5,950
7.38E+03
9.69
-

O.OOE+OO

1.55

7.38E+03
6.13
1.0010
0
3 -95E+07
SI*
0.94
4,490
3.45E+04
42.3
1.0108
-0.5
7.37E+07
SI*
0.90
8,740
3.45E+04
44.1
1.0251
-0.3
9.15E+07
SI*
0.89
11,000
3.45E+04
44.6
1.0439
-0.2
1.44E+08
SI*
0,87
17,700
3.45E+04
45.6
1.0511
-0.5
1.79E+08
SI*
0.91
20,900
3.45E+04
43.6
0.9310
-1.0
1.81E+08
SI*
1.02
19,000
3.45E+04
39.2
0.9710
-0.6
2.86E+08
SI*
0.87
35,400
3.45E+04
46.1
0.9864
+0.1
1.02E+09
SI*
0.85
129,000
3.45E+04
47
1.0009
+0.1
2.22E+08
SI*
0.92
26,000
3.45E+04
43.5
1.0010
-0.1
1.52E+07
1.03
0.91
2,780
7.01E+03
11.1
1.1046
+0.2
1.96E+08
1.03
1.03
31,800
7.01E+03
9.81
1.1277
-0.2
8.99E+07
1.03
0.89
16,900
7.01E+03
11.4
1.1389
-0.5
2.22E+07
1.03
1.22
3,030
7.01E+03
8.27
1.1468
-0.3
1.3 8E+07
1.03
1.20
1,920
7.01E+03
8.42
1.1525
-0.2
8:96E+07
1.04
0.69
21,800
7,01E+03
14 .7
Page 2 of 5
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_005R»T-D10
Name
Actual
RT
QC
Pr«d
RRT
Actual
RUT
PCB-32
24'6-TrCB
19.79
1
1809
1.1828
PCB-34
2'35-TrCB
20. 87
0
8174
0.8178
PCB-23
235-TrCB
21.02
0
8231
0.8235
PCB-26/29 23"5-/245-TrCB
21.29
0
8341
0.8341
PCB-25
23'4-TrCB
21.49
0
8417
0.8420
PCB-31
24'5-TrCB
21.76
0
8525
0.8528
PCB-28/20 244'-/233'-TrCB
22.03
0
8634
0.8634
PCB-21/33 234-/2'34-TrCB
22.23
0
8703
0.8712
PCB-22
234'-TrCB
22.59
0
8848
0.8852
PCB-36
33'5-TrCB
23.96
0
9386
0.9388
PCB-39
34 ' 5-TrCB
24.28
0
9510
0.9512
PCB-38
345-TrCB
24.79
0
9715
0.9716
PCB-35
33'4-TrCB
25.18
0
9868
0.9869
PCB-37
344¦-TrCB
25.54
1
0007
1.0007
PCB-54
22'66'-TeCB
19.64
1
0010
1.0012
PC3-30/53 22'46-/22'56'TeCB
21.52
0
9119
0.9112
PCB-45
22'36-TeCB
22.11
0
9362
0.9364
PCB-51
22 46'-TeCB
22.19
0
9393
0.9395
PCB-46
22'36'-TeCB
22.39
0
9481
0.9481
PCS-52
22'55'-TeCB
23.64
1
0010
1.0010
PCB-73
23'5'6TeCB
NotFnd
1
0065
-
PCB-43
22'35-TeCB
23.85
1
0103
1.0099
PCB-69/49 23'46-/22'45'TeCB
24.07
1
0185
1.0192
PCB-48
22145-TeCB
24.33
1
0303
1.0301
PCB-44/47/65 22'35'-/22'44'-
24.52
1
0393
1.0382
PCB-59/62/75 233'6-/2346-/24
24.80
1
0510
1.0503
PCB-42
22'34'-TeCB
24.98
1
0578
1.0577
PCB-41
22"34-TeCB
25.30
1
0717
1.0713
PCB-71/40 23'4'6/22'33'-TeCB
25.40
1
0758
1.0754
PCB-64
234¦6-TeCB
25.60
1
0841
1.0839
PCB-72
23'55"-TeCB
26.32
0
8397
0.8400
PCB-68
23'45'-TeCB
26.57
0
8478
0.8481
PCB-57
23315-TeCB
26.94
0
8595
0.8598
PCB-58
233'5'-TeCB
27,13
0
8659
0.8661
PCB-67
23 *45-TeCB
27.29
0
8709
0.8711
PCB-63
234'5-TeCB
27.52
0
8780
0.8783
PCB-61/70/74/76 2345-/23 '4 • 5
27.81
0
8872
0.8878
PCB-66
23'44'-TeCB
28.09
0
8961
0.8965
PCB-55
233'4-TeCB
28.23
0
9007
0.9010
PCB-56
233'4'-TeCB
28.65
0
9145
0.9146
PCB-60
2344•-TeCB
28.84
0
9206
0.9207
PCB-8D
33'55'-TeCB
29.18
0
9314
0.9314
PCB-79
33'45'-TeCB
30.50
0
9732
0.9734
PCB-78
33"45-TeCB
30.96
0
9886
0.9882
PCB-104
221466'-PeCB
24.48
1
0009
1.0009
PCB-96
221366"-PeCB
24.80
1
0136
1.0136
PCB-103
2 2 1 4 5"6-PeCB
26.48
0
8961
0.8961
Analytical Perspectives
Page 3 of 5
Dif f
Checkcode:
pBI _
Sacs
Response
Ra
RRF
Cone
Noise
DL
+2.3
9.94E+07
1.03
1.28
13,000
7.01E+03
7.9
+ 0.5
1.43E+07
1.02
1.13
1,680
2.53E+04
28.7
+ 0.5
3.07E+07
1.04
1.06
3,840
2.53E+04
30.5
0
1.57E+08
1.05
1.13
18,400
2.53E+04
28.6
+ 0.4
8.33E+07
1.05
1.25
8,870
2.53E+04
25. 9
+ 0.4
5.04E+08
1. 04
1.16
57,800
2.53E+04
27.9
0
6.50E+08
1.05
1.13
76,200
2.53E+04
28.5
+ 1.2
4.72E+08
1.05
1.10
56,700
2.53E+04
29.3
+ 0.5
2.72E+08
1.04
1.09
33,000
2.53E+04
29.5
+ 0.3
4.76E+07
1.07
1.14
5,530
2.53E+G4
28.3
+0.3
4.33E+07
1.05
1.12
5,150
2.53E+04
28.9
+ 0.1
1.64E+08
1.07
1.04
21,000
2.53E+04
31 .1
+0.2
2.89S+08
1.05
1.04
37,000
2.53E-04
31.2
0
5,25E+08
1.05
0.96
72,700
2.53E+04
33.7
+0.2
1.03E+06
0.77
1.18
131
3.66E+03
5.18
-0.9
4.00E+07
0.76
0.93
6,080
5.14E+03
7.97
+ 0.3
4.16E+07
0.77
0.71
8,210
5.14E+03
10.3
+ 0,3
1.59E+07
0.77
1.00
2,230
5.14E+03
7 .36
0
1.77E+07
0.76
0.73
3,400
5.14E+03
10.1
0
2.76E+08
0.76
0.91
42,700
5.14E+03
8,12

O.OOE+OO

1.17

5.14E+03
6.32
-0.6
1.74E+07
0. 77
0.71
3,440
5.14E+03
10.4
+ 1.0
2.18E+Q8
0.77
1.05
29, 300
5.14E+03
7.04
-0.3
8.29E+07
0.77
0.86
13,600
5.14E+03
8.6
-1.6
3.38E+08
0.77
0.92
51,600
5.14E+03
8
-1.0
6.05E+07
0.77
1.19
7,200
5.14E+03
6.23
-0.1
1.01E+08
0.77
0.80
17,800
5.14E+03
9.21
-0.6
4.85E+07
0.77
0.73
9,320
5.14E+03
10.1
-0.6
1.88E+08
0.76
0.93
28,400
5.14E+03
7.92
-0.3
2.07E+08
0.77
1.24
23,500
5.14E+03
5.98
+0.5
9.59E+06
0.77
1.05
1,290
4.68E+04
64.3
+0.5
1.92E+07
0.77
1.09
2,480
4.68E+04
61.7
+0.5
2.05E+07
0.77
1.01
2,840
4.68E+04
66.3
+0.3
1.65E+07
0.85
0.99
2,340
4.68E+04
67.7
+0.3
5.14E+07
0.77
1.09
6, 650
4.68E+04
61.8
+0.5
3.64E+07
0.76
1.07
4,780
4.68E+04
62.7
+1.0
9.55E+08
0.77
1.02
132,000
4.68E+04
65.9
+ 0.7
5.52E+08
0.78
1.03
75,400
4.68E+04
65.2
+0.5
4.30E+07
0.78
0.94
6, 460
4 .68E+04
71.7
+ 0.2
3.53E+08
0.78
1.01
49,100
4.68E+04
66,5
+0.2
1.98E+08
0. 77
1.00
28,000
4,68E+04
67.4
0
1.31E+07
0.77
1.08
1,710
4.68E+04
62.3
+ 0.4
8.94E+07
0.78
1.13
11,100
4 .68E+04
59.4
-0.7
4.99E+07
I 0.94 I
0.94
7,490
4.68E+04
71.7
0
6.35E+05
0.53
1.06
87.7
2.63E+03
3.59
0
4.72E+06
0.62
0.89
770
2.63E+03
4.23
0
2.92E+06
0.60
0.76
560
2.G4E+05
402
Printed; OS 06 2008 1:22 PM
-------
PS464_6042_PCB_005RJ-D10
Actual

Pred
Name
HT
QC
BRf
PCB-94 22'356'-PeCB
26.67

0.9024
PCB-95 22'35'6-PeCB
27.05

0,9151
PCB-100/93 22'44'6-/22'356-P
27.25

0.9224
PCB-102 22'456'-PeCB
27.37

0.9262
PCB-98 2213'46-PeCB
NotFnd

0.9284
PCB-88 22'346-PeCB
NotFnd

0.9385
PCB-91 22'34'6-PeCB
27.79

0.9407
PCB-84 22'33'6-PeCB
27.99

0.9469
PCB-89 22'346'-PeCB
28.40

0.9610
PCB-121 23'45'6-PeCB
NotFnd

0.9730
PCB-92 22'355'-PeCB
29.07

0.9837
PCB-113/90/101 233'5'6-/22'3
29.58

0.9999
PCB-83 22'33'5-PeCB
29.96

1.0143
PCB-99 22'44'5-PeCB
30.07

1.0176
PCB-112 233'56-PeCB
30.18

1.0211
PCB-108/119/86/97/125/87 233
30.51

1.0328
PCB-117 234'56-PeCB
31.04

1.0506
PCB-116/85 23456-/22'344"-Pe
31.12

1.0536
PCB-110 233'4'6-PeCB
31.25

1.0577
PCB-115 2344'6-PeCB
NotFnd

1.0605
PCB-82 22'33'4-PeCB
31.53

1.0671
•PCB-111 233'55'-PeCB
31.85

1.0782
PCB-120 23-455'-PeCB
32.25

1.0915
PCB-107/124 233 *4'5-/2'345S'
33.21

0.9913
PCB-109 233'46-PeCB
33.41

0.9976
PCB-106 233'45-PeCB
33.60

1.0039
PCB-122 2'33'45-PeCB
34.09

1.0093
PC3-127 33'455*-PeCB
36.03

1.0363
PCB-155 22'44'66'-HxCB
29.39

1.0007
PCB-152 22'3566'-HxCB
29.56

1.0060
PCB-150 22'34'66'-HxCB
29.70

1.0109
PCB-136 22'33'66'-HxCB
30.00

1.0210
PCB-145 22'3466'HxCB
30.27

1.0302
PCB-148 22*34'56'-HxCB
31.54

1.0738
PCB-151/135 22 ' 355'6-/22'33'
32.05

1.0913
PCB-154 22 *44'5'6-HxCB
32.27

1.0985
PCB-144 22*345'6-HxCB
32.52

1.1073
PCB-147/149 22 ' 34 ' 56-/22 * 34 *
32.82

1.1175
PCB-134 22'33'56-HxCB
33.00

1.1234
PCB-143 22'3456'-HxCB
33.08

1.1262
PCB-139/140 22'344'6-/22'344'
33.34

1.1351
PCB-131 22'33'46 HxCB
33.51

1.1408
PC3-142 22'3456-HxCB
33.65

1.1456
PCB-132 22'33'46'-HxCB
33.89

1.1537
PCB-133 22'33'55'-HxCB
34.30

1.1679
PCB-165 233'55'6-HxCB
34.67

0.9514
PCB-146 22'34'55'-HxCB
34 .85

0.9573
Analytical Perspectives
Actual Diff
RET
Sees
Response
Ra
RRF
0.9023
-0
2
2.16E+06
0.60
0
65
0.9152
+0
2
1.28E+08
0.63
0
71
0.9222
-0
3
5.06E+06
0.63
0
74
0.9263
+0
2
1.21E+07
0.64
0
74
-


0.OOE+OO

0
64
-


O.OOE+OO

0
72
0.9405
-0
3
3.51E+07
0.61
0
66
0.9470
+0
2
5.20E+07
0.61
0
60
0.9609
-0
2
6.16E-06
0.61
0
64
-


0.00E+00

0
95
0.9835
-0
3
3 . 22E • 07
0.60
0
69
1.0008
+1
6
2.37E+08
0.60
0
79
1.0139
-0
7
1.02E+08
ekei
0
53
1.0176
0

1.04E+08
0.62
0
80
1.0213
4-0
4
3.04E+06
0.60
0
93
1.0324
-0
7
5.77E+08

0
79
1.0502
-0
7
7.82E+06
0.61
0
87
1.0529
-1
3
5.60E+07
0.63
0
78
1.0575
-0
4
2.77E+08
0.63
0
89
-


0.OOE+OO

0
96
1.0667
-0
8
4.65E+07
0.61
0
56
1.0778
-0
8
6.03E+06
0.59
0
95
1.0912
-0
6
9.59E+06
0.60
0
96
0.9914
+0
2
2.58E+07
0.60
0
93
0.9976
0

4.85E+07
0.62
0
99
1.0032
-1
4
2.27E+07
MEM
0
91
1.0092
-0
2
2.46E+07
0.62
0
84
1.0364
+0
2
1.92E+07
0.58
0
88
1.0006
-0
2
7.93E+05
MEM
1
04
1.0061
+0
2
1.11E+06
1.37
0
98
1.0110
+0
2
3,28E+06
1.14
0
94
1.0212
+0
4
2.86E+07
1.22
0
92
1.0302
0

1.16E+06
1.17
0
92
1.0737
-0
2
2.06E+06
1.09
0
90
1.0910
-0
6
4.66E+07
1.23
0
91
1.0983
-0
4
6.98E+Q6
1.22
1
05
1.1071
-0
4
1.20E+07
1.24
0
94
1.1172
-0
6
1.09E+08
1.23
0
94
1.1232
-0
4
8.57E+06
1.22
0
79
1.1260
-0
4
1.55E+06
1.31
0
83
1.1347
-0
8
9.59E+06
1.29
0
92
1.1406
-0
4
5.58E+06
1.31
0
78
1.1453
-0
6
7.96E+05
1.28
0
80
1.1534
-0
6
4.68E+07
1.28
0
83
1.1676
-0
6
3.98E+06
1.26
0
86
0.9523
+1
9
3.71E+Q6
1.36
1
09
0.9572
-0
2
3.39E+07
1.28
0
98
Page 4 of 5

Checkcode:
ptB
Cone
Noise
DL
485
2.04E+05
469
26,400
2.04E+05
432
1, 000
2.04E+05
414
2, 420
2.04E+05
417

2.04E+05
476

2.04E+05
426
7, 810
2 .04E+05
465
12,700
2.04E+05
510
1,400
2.04E+05
476

2.04E+05
321
6,850
2.04E+05
444
43,800
2.04E+05
387
28,200
2.04E+05
578
19,000
2.04E+05
381
477
2.04E+05
328
107,000
2.04E+05
386
1,310
2.04E+05
351
10,500
2.04E+05
391
45,900
2.04E+05
346

2.04E+05
321
12,100
2.04E+05
545
932
2.04E+05
323
1,460
2.04E+05
319
4,090
2.04E+05
331
7,200
2.04E+05
310
3, 680
2.04E+05
339
4,130
2.04E+05
350
3, 040
2.04E+05
335
98.1
3.00E+03
3.72
146
3.00E+Q3
3.94
448
3.00E+03
4.1
3,980
3.00E+03
4.18
162
3.OOE+03
4.2
373
3.00E+03
5.54
8,340
3.0QE+O3
5.48
1,080
3.00E+03
4.72
2,070
3.00E+03
5.27
18,800
3.00E+03
5.25
1,770
3.00E+03
6.32
302
3.OOE+03
5.97
1,700
3.00E+03
5.41
1,160
3.00E+03
6.36
162
3.00E+03
6.24
9,190
3.OOE+03
6
752
3.OOE+03
5. 78
550
3.OOE+03
4.54
5, 620
3.OOE+03
5.07
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_005RJ-D10
Name
PCB-161 233'45'6-HxCB
PCB-153/168 22 ' 44'55'-/23'44'
PCB-141 22'3455'-HxCB
PCB-130 22'33'45'-HxCB
PCB-137 22'344'5-HxCB
PCB-164 233*4'5'6-HxCB
PC8-163/138/129 233'4 * 56-/22'
PCB-160 233'456-HxCB
PCB-158 233'44'6-HxCB
PCB-128/166 22133'44'-/2344 ' 5
PCB-159 233'455'-HxCB
PCB-162 233'4'55'-HxCB
PCB-188 22'34'566'-HpCB
PCB-179 22"33'566'-HpCB
PCB-184 22*344'66'-HpCB
PCB-176 22'33'466'-HpCB
PCB-186 22'34566'-HpCB
PCB-178 22 * 33•5516-HpCB
PCB-175 22'33"45'6-HpCB
PCB-187 22'34'55'6-HpCB
PCB-182 22'344'56'-HpCB
PCB-183 22 *344'5"6-HpCB
PCB-185 22'3455'6-HpCB
PCB-174 22'33'456'-HpCB
PCB-177 22"33'4'56-HpCB
PCB-181 221344'56-HpCB
PCB-171/173 22'33'44'6-/22'3
PCB-172 22'33'455'-HpCB
PCB-192 233'455'6-HpCB
PCB-180/193 22 * 344'55'-/233'
PCB-191 233'4 4'5'6-HpCB
PCB-170 22'33'44'5-HpCB
PCB-190 233'44'56-BpCB
PCB-202 22'33'55'66'-OcCB
PCB-201 22'33'45'66'-OcCB
PCB-204 22'344'566'-OcCB
PCB-197 22'33'44'66'-OcCB
PCB-200 22'33'4566'-OcCB
PCB-198/199 22'33'455*6-/22'
PCB-196 22'33'44'56'-OcCB
PCB-203 22'344'55'6-OcCB
PCB-195 22'33'44'56-OcCB
PCB-194 22'33'44'55'-OcCB
PCB-205 233'44'55*6-OcCB
PCB-208 221331455'66'-NoCB
PCB-207 22'33'44'566'-NoCB
PCB-206 22'33'44'55'6-NoCB
Analytical Perspectives
Actual

Pred
Actual
RT
QC
RRT
RUT
34.97

0.9605
0.9606
35.38

0.9722
0.9718
35.53

0.9761
0.9760
NotFnd

0.9855
-
NotFnd

0.9910
-
36.16

0.9933
0.9933
36.43

1.0011
1.0007
NotFnd

1.0048
-
36.77

1.0098
1.0099
37.50

0.9629
0.9630
38.32

0.9840
0.9840
38.56

0.9902
0.9901
NotFnd

1.0006
-
34.53

1.0087
1.0087
34.99

1.0222
1.0222
35.27

1.0306
1.0304
NotFnd

1.0421
-
36.81

1.0754
1.0754
37.35

1.0913
1.0913
37.58

1.0979
1.0979
37.76

1.1031
1.1031
38.10

1.1132
1.1132
38.20

1.1155
1.1160
38.29

1.1187
1.1187
38.66

1.1296
1.1295
39.01

1.1397
1.1396
39.20

1.1450
1.1452
40.56

0.9061
0.9064
NotFnd

0.9116
-
41.11

0.9178
0.9186
41.40

0.9251
0.9251
42.17

0.9421
0.9422
42.61

0.9522
0.9522
38.78

1.0006
1.0008
39.54

1.0207
1.0205
40.13

1.0356
1.0356
40.32

1.0406
1.0405
40.40

1.0427
1.0427
42.75

1.1027
1.1032
43 .31

1.1175
1.1175
43 .47

1.1218
1.1218
44 .58

0.9504
0.9503
46.54

0.9919
0.9921
46.93

1.0004
1.0004
44.38

1.0005
1.0005
45.17

1.0182
1.0182
48.40

1.0004
1.0003
Page 5 of 5
Diff




Checkcotle .-
pw
Sees
Response
Ra
RRF
Cone
Noise
DL
+0.2
2.28E+06
1.26
1.17
316
3.00E+03
4.23
-0.8
1.48E+08
1.28
1.24
19,400
3.OOE+03
4
-0.2
3.07E+07
1.44
0.86
5,750
3.00E+03
5.74

0.00E+00

0.80

3.OOE+03
6,22

0.00E+00

0.94

3.OOE+03
5,25
0
1.85E+07
1.38
1.16
2, 590
3.OOE+03
4.29
-0.9
1.63E+08
1.29
0.95
27,700
3.00E+03
5.19

0.00E+00

1.08

3.00E+03
4.58
+0.2
3.94E+07
1.24
1.31
4,900
3.00E+03
3.8
+0.2
2 .382 + 07
1.22
0.82
4,830
5.40E+04
113
0
5.18E+06
1.26
0.95
904
5.40E+04
96.9
-0.2
8.93E+06
1.25
0.97
1,530
5.40E+04
95.1

O.OOE+OO

1.05

2.90E+03
4.23
0
1.64E+07
1.04
0.94
2,690
2.90E+03
4.73
0
2.12E+06
0.95
0.93
350
2.90E+03
4 .77
-0.4
1.04E+07
1.08
0.98
1,640
2.90E+03
4.54

0.00E+00

0.94

2.90E+03
4.75
0
6.82E+06
1.04
0.69
1, 530
2.90E+03
6.44
0
5.17E+06
1.04
1.05
1,040
8.77E+04
186
0
3.64E+07
1.04
1.08
7, 100
8.77E+04
181
0
2.70E+06
1.04
1.14
496
8.77E+04
171
0
2.77E+07
1.03
1.18
4,950
8.77E+04
166
+ 1.1
3.89E+06
1.02
1.00
817
8.77E+04
195
0
2.32E+07
1.05
0.98
4,980
8.77E+04
199
-0.2
1.32E+07
1.04
0.96
2,920
8.77E+04
205
-0.2
1,96E+06
1.09
1.05
395
8.77E+04
187
+0.5
1.41E+07
1.04
0.95
3,130
8.77E+04
207
+ 0.7
8.98E+06
1.02
0.99
1,910
8.77E+04
198

O.OOE+OO

1.23

8.77E+04
159
+ 2.0
8.56E+07
1.03
1.21
14,900
8.77E+04
162
0
7.58E+06
1.08
1.38
1,150
8.77E+04
142
+ 0.3
3.18E+07
1.03
0.94
4,070
8.77E+04
94.9
0
1.35E+07
1.02
1.12
1,440
8.77E+04
79.5
+ 0.5
8.41E+06
KB9
1.03
1,440
7.31E+03
13 .4
-0.5
8.85E+06
0.81
0.99
1,570
7.31E+03
14
0
9.52E+05
0.92
0.94
179
7.31E+03
14 .8
-0.2
3.45E+06
0.90
1.06
573
7.31E+03
13
0
5.00E+06
0. 91
0.90
985
7.31E+03
15.5
+ 1.3
2.93E+07
0.90
0.69
7, 530
7.31E+03
20.2
0
1.51E+07
0. 90
0.72
3,690
7.31E+03
19 .1
0
2.02E+07
0. 91
0.79
4, 520
7.31E+03
17.6
-0.3
6.12E+06
0. 90
0.66
1,710
5.82E+03
17
+ 0.6
1.87E+07
0.90
0.73
4,720
5.82E+03
15.4
0
3.74E+06
0. 89
0.97
710
5.82E+03
11.5
0
9,98E+06
0.78
0.95
2,090
7.50E+03
16.5
0
7.76E+06
0.78
0.96
1,610
7.50E+03
16 .3
-0.3
2.28E+07
0.78
1.05
5,340
7.50E+03
17.5
Printed; 08 06 2008 1:22 PM
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-1	Acq: 01-Aug-2008 23:27:29
VSIRexpt: pcb0306_c!1-10 GC: pebx90_a V^pgHECJKUNEQUAIfiSSSfcjl Datafile: 080801 R20.EQ
Rel, Int.
Fn 1 100%.
218.9856
QC (non-EQ)
10.43-15.00
Rel. Int.
Fn 2 100%
242.9656
QC (non-EQ)
15.02-20.50
Rel. Int.
Fn 3 100%
292.9824
QC (non-EQ)
20.52-26,00
Rel. Int
Fn 4 100%.
330,9792
QC (non-EQ) .
26.03-37,11
Rel. Int.
Fn 5 100%
366,9792
QC (non-EQ)
37.13-44.01
Abs, Int.
5.8867
2.84e7
O.OOeO
15,0 RT
Abs. nt
1.0787
-9.37e6
O.OOeO
Abs. nt
2.1 Ie7
1.0687
O.OOeO
I	1
26.0 RT
Abs. nt
2.61e7
1.31e7
O.OOeO
Abs, Int
4,05e6
2.03e6
O.OOeO
44.0 RT
Rel. Int.
Fn6 100%.
454.9728
QC (non-EQ)
44.02-49,21
0%-
45.0
46.0
	1	1	r-
47.0
—I—
48.0
-1	1	!—
Abs, Int.
,-7.37e6
-3.68e6
—I—
49,0
¦ O.OOeO
RT
Rel. Int.
Fn 7 100%.
454.9728
QC (non-EQ)
49.22-53.00
0%.
-|—i—i—i—i—|—i—i—i—i—|—
49.5
"¦ I r
50.0
50.5
1 I '
51.0
I 1 1 ' ' I 1
51.5
—|—! I 1—i—I—r—r—i—'—j—I—l—r-—i—|—r—1—r-—i—]—'—I T I	O.OOeO
52,0	52.5	53,0 RT
Abs. Int.
-8.55e6
¦ 4.28e6
Results: P:\P9400_P94BS)P9464_6042 PCB)resaurce$\P9464_6042_PCB_005RJ-010.utp_res. saved Q5-Aug-2008 09:19 (EE)
AP UitraTrace-Pm V3 993 User/System: EE/EEC2-038 see: 743-639
Peak annotation: Areas, Centroids
PKD: n/a Printed: 05-Aug-2008 09:22:14 Page 1 of 22
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
QC CHECK EQUALIZED
Sample ID: Run# II-ACD-M23-1 PRIOR TO FSOCTOTBG Acq: 01-Aug-2008 23:27:29
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10	User: CJL Datafile: 080801 R20_EQ
Rel. Int
Fn 1 100%.
218.9856
QC Check
10.43-15,00
0%-
r

I	|	T	I	1	1	't—jT-
10 5	11,0
) ) i i i r [ i
11.5
I 1 ' * ' I >
12.0
t » i I i
12.5
13.0
		T	|	„	f	,,	r,.„i	r,„T„ f .y.	y
13.5	14.0
* r ¦
14.5
Abs, Int.
-B.B2e7
-3.41e7
•O.OOeO
15,0 RT
Rel. Int.
Fn 2 100%.
242.9856 :T
QC Check
15.02-20.50
0%.
16.0
"T	1	1	|f—i	r-
	1	
17.0
I
18.0
19.0
	,—,—,—,—,—,—
20.0
Abs. Int.
-1.74a7
¦ 8.70e6
¦ O.OOeO
RT
Rel. Int.
Fn 3 100%-
292.9824
QC Check
20.52-26.00
0%.
21.0
22.0
I
23.0
1—'	'—'	'—I—
24.0
25.0
Abs. Int.
¦ 1.95e7
19 76e6
¦ O.OOeO
26.0 RT
Rel. Int.
Fn 4 100%.
330.9792
QC Check
26.03-37.11
0%.
¦"I	»	i	r	»"
-1	
28.0
Abs, Int.
•2.64e7
30.0
if — i i ii ii i iii	riiifiTV
•1.32e7
32.0
34.0
36.0
¦ O.OOeO
RT
Re!. Int
Fn 5 100%.
454.9728
QC Check
37.13-44.01
Abs. Int
B43eS
4.21e6
O.OOeO
Rel. Int.
Fn 6 100%.
404.9760
QC Check
44.02-49.21
0%-
Abs, Int.
_7.76e6
-3.88e6
48.0
46.0
47.0
	1—
48.0
I I I
49.0
RT
Rel. Int
Fn 7 100%.
454.9728
GC Check
49.22-53.00
0%-
I i i i i I i
49.5
i I i i i i I i
50.0
I ^
50.5
S1.0
i | i i r i i i i i i ] t i i \ t
51.5	52-0
Abs. Int.
-7.20e6
• 3.60e6
O.OOeO
f ! 1 1 ' ' I' * ' '
52.5	53.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resource$SP9464_6042_PCB__00SRJ~D 10 utp__res, saved 0&-Aug-2008 09:19 {EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-Q38
Peak annotation: Areas, Centmids
PKD: rt/a Printed: 0S~Aug~2Q08 09:22:15 Page 2 of 22
-------
AP Lab ID: P9464_6Q42_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 1
188.0393
MoCB
4o 8,32e3
10,43-15.00
Rel. Int.
100%
Fn 1
190.0363
MoCB
4o 6.05e3
10.43-15.00
Re!. Int.
100%
Fn 1
200.0795
MoCB Std.
4o 1.17e4
10.43-15.00
Rel. Int.
100%.
Fn 1
202.0766
MoCB Std.
4a 7.90e4
10.43-15 00
Sample ID: Run# II-ACD-M23-1
VSIR expt; pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801 R20_EQ
Abs. Int.
-2.18e8
1,09e8
O.OOeO
15.0RT
Abs. Int.
7,03e7
3.51e7
O.OOeO
PCB-2
3.66e8
13.36
PCB-3
7.08e8
13.54
PCB-1
2.77e8
11.32
PCB-2
2.81e8
13.36
PCB-3
PCB-1
2.27e8
8,87e7
13.54
1 ,32
15.0 RT
2.81e7
ES-3
2,87e7
13.53
15.0RT
r41e6
13.52
27e6
14.49
3.11e6
10.59
1.62e6
13.77
i.ioee
12.30
2.16e6
13.26

14.0
14.5
Abs. Int.
r9.99e6
5.00e6
O.OOeO
Abs. Int.
-3 49e6
1.75e6
OOeO
15.0RT
Rel. Int.
100%-
Fn 1
218.9856
OC Check
10.43-15.00
0%-
T~r
T
		i	i	>	|""T	r1"
11.0
10.5	11.0	11.5	12.0	12.5	13.0
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_005RJ-D10 utp res, saved OS-Aug-2008 09:19 (EE)
AP UltraTraee-Pm V3.993 User/System: EE/EEC2-038 cc: 0142, 8912
~r
I f | i
12.0
' I 1
12.5
T
-n—i—rr-
13.5
14.0
14.5
Abs. Int.
-6 82e7
•3.41e7
•O.OOeO
15.0RT
Peak annotation: -Areas, Centroid&s
Revised: 04-Aug-2008 11:27:00 {EE} Printed: 05-Aug-2008 09:22:16 Page 3 ob&2
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 1
222.0003
DiCB-1
4o 4.50e3
10.43-15.00
Sample ID: Run# II-ACD-M23-1
VSIRexpt: pcb0306_c!1-10 GC: pcbx90_a Vial: 10
0%-
10.5
Rel. Int.
100%-
Fn 1
223.9974
DiCB-1
4o 1.07e4
10.43-15.00
0%-
10.5
Rel. Int.
100%-
Fn 1
234.0406
DiCB Sid.
4a 1.01e4
10.43-15.00
0%-
PCB-4
1.26e7
13.91
11.0
' 1 '
11.5
12.0
12,5
13.0
13.5
Acq: O1-AU0-2OQ8 23:27:29
User: CJL Datafile: 080801R20 EQ
Abs. Int.
-7.47e6
3.73e6
¦O.OOeO
14.0
PCB-4
8.37e6
13.91
11.0
1 I 1
11.5
f—i mf r-
12.0	12.5
13.0
-f'TT't J'T t t
13,5
ES-4
8.66e6
13.90
f—I—I—I i I | I—r—i—i"1 ) I—i i I	I 1' t ""1—I—j—r-
10.5	11.0	11.5
12.0
12.5
13.0
13,5
4.26e6
13,79
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std.
4o 3.47e3
10 43-15 00
14.0
ES-4
S.47ar
i&sn
2.73eS
13.79
0%-r-r-
10.5
] l l l i I l 1 l l [ l 1 l l I l r i i I
11.0	11.5
—I—p-T-Tj-T		r""T""T""l		1	1	1	j	%	r""T	y"y""1"mT""r""r""|	1	T	1	1	f	t	r		V""f"
12,0	12.5	13.0	13.5	14.0
14.5	15.0RT
Abs. Int.
4.69e6
•2.34e6
i I i i i »^p>	i /?*•» - O.OOeO
14.5	15.0RT
14.5
Abs, Int.
-5.04e6
•2.52e6
¦O.OOeO
15.0 RT
14.5
-j—*—i i i—f-O.OOeO
15.0 RT
Abs. Int.
-3.11e6
1.56e6
Rel. Int.
100%
Fn 1
218,9856
QC Check '
10,43-15.00
0%-
	| I ' !—I—I—|—'—'—!—1—|—|—I—|—| | j | |—| | 1 I
10.5	11.0	11.5
-i—i—i—i—i—i—i—|—r-
-t—i—i—r-t—i—i—i—i—I—r-i—i—i—j—i—i—i—i—|—i—i—i—i—
12.0
12.5
13.0
13.5
14.0
14.5
Abs. Int.
-6.82e7
¦3.41 e7
¦O.OOeO
15.0 RT
Results: P:\P9400_P9499\P94S4_S042 PCB'ire$Oume$\P9464_6042_PCB_005RJ-D10.utp_res, saved 0S~Aug-20Q8 09:19 (EE)	Peak annotation: Areas, Centrokfs
AP UltmTmce-Pro~V3.993 User/System: EBEEC2-038 CC 0444. 1501	Revised: 04-Aug-2008 13:43:28 {EE) Printed: 05-Aug-2008 09:22:17 Page 4 g?22
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 2
222.0003
DiCB-2
4o 2.10e4
15.07-20.50
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
0%-
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4o 2.37e4
15.07-20.50
0%-
Rel. Int.
100%-
Fn 2
234.0408
DiCBStd,
4o 1.20e4
15.07-20.50
0%-
Rel. Int.
100%.
Fn 2
236.0376
DiCB Std.
4o 6.05e3
15.07-20.50
0%-
PCB-9
2,41e7
15.88 „
, /•> {\,
PCB-6 ^^^7
5.58e7 16 35
16.06
A-
T
16.0
m.
17.0
PCB-9
1.60e7
15.68 »
X /\
PCB-6
3.65e7
16.06
PCB-5
5.79e7
16.35
M-
16.0
17,0
JS-9
2.18e7
15.66
PCB-14
1.10e8
17.98
_A_
PCB-11
1,75e8
18.76
18.0
PCB-14
7.3Qe7
17.98
JX,
18.0
PCB-13/12
6.Z1e8
19.05
PCB-15
1.35e8
PCB-13/12
4.06e8
19.05
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
Abs Int.
-1.38e8
PCB-11
1.15e8
18.76
PCB-15
8.80e7
19.33
19.0
ES-15
2.29e7
19.32
¦¦T	r	t	r"
16.0
17.0
—I—1
18,0
-•—1—r
JS-&S
1.3^7
Jfim
16,0
17.0
-i	1	r-
18.0
-|	r-
20,0
20.0
-6.90e7
-O.OOeO
RT
Abs. Int.
-8.98e7
•4 49e7
i i [ i r > 1 ( i i i t | i i i "i
19.0	20,0
-O.OOeO
RT
Abs. Int.
-7.30e6
•3.65e6
-O.OOeO
RT
Abs. Int.
-4.63e6
•2.32e6
19.0
20.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
15.07-20.50"
0%-
16.0
17.0
18.0
19.0
Results: P:\P9400_P9499\P9464_6042 PCBVesoun:es'iP9464_e042_PCB_Q05RJ-D10,utp_re$, saved 05-4ug-2008 00; f 9 (EE)
AP UltraTrace-Pm~ 1/3.993 User/System: EE/EEC2-038 cc: 4544. 2495
Abs. Int.
-1.74e7
-8.70e6
•O.OOeO
RT
20.0
Peak annotation: Areas, Centropg'
Revised: 04-Aug-2008 11:30:25 (EE) Printed: 0$-Aug-2008 09:22:18 Page 5pf?2
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 2
255.9613
TrCB-2
4a 3.30e3
15.02-20.50
0%-
Rel. Int.
100%-
Fn 2
257.9584
TrCB-2
4a 3.71e3
15.02-20.50
0%-
Sample ID: Run# II-ACD-M23-1
VSiR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
PCB-30/18
9.97e7
18.48
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801 R20_EQ
Abs. Int.
2 82e7
PCB-17
4.57e7
18.87
PCB-19
7.67e6
16.75
PGB-16
4.56e7
19.28
16.0
16.0
17.0
18,0
PCB-27
1.12S7
19.05
19.0
PCB-30/18
9.68e7
18.48
PCB-17
4.43e7
18.87
PCB-19
7.48e6
16.75
_4\_
PCB-16
4.4Qe7
A „„„ 19.28
\ PCB-27 A
1 1.1" "

,10e7 \
19.05 I \
17.0
18.0
-A-
PCB-32
5.03e7
19.79
20.0
PCB-32
4.90e7
19.79
19.0
20.0
¦1.41e7
-O.OOeO
RT
Abs. Int.
-2,74e7
1,37e?
•O.OOeO
RT
Rel. Int.
100%-,
2.28e7
15.62
Fn 2 !
268.0016 ¦
TrCB Std. "

ES-19
1.22e7
16.73
4a 3.01 e4 .

A
15.02-20.50 ¦


0%-

Rel. Int.
100%-
Fn 2
269.9986
TrCBStd.
401 27e4
15,02-20.50
0%-
2.85e6
15,62
A
16.0
16.0
17.0
18.0
ESJS
1 >7e7
~16.73
17.0
18.0
19.0
{ < i
19.0
1.37e6
19.42
-^V
20.0
20.0
Abs. Int.
r6.54e6
-3.27e6
-O.OOeO
RT
Abs. Int.
-3.45e6
173e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
15.02-20.50"
0%-
16.0
17.0
1—1—1
18.0
19.0
Results: P:\P9400_P9499\P9464_6042 PCB\msoufces\P9464_S042_PCB_005RJ-D10,utp_ms, saved 0S-Aug-2008 09:13 (EE)
AP UltraTrace-Pm 1/3.993 User/System: EE/EEC2-G38 cc: 8597. 7446
AbS. Int.
-1.74e?
•8.70e6
¦O.OOeO
RT
20.0
Peak annotation: Areas, Centmkfs-
Revised 04-Aug-2008 11:30:49 (EE) Printed: 05-Aug-2008 09:22:15 Page 6oT72
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 3
255,9613
TrCB-3
4a 1.61e4
20.52-26.00
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
o%-
Rel. Int.
100%-
Fn 3
257J584
TrCB-3
4a 9.21e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
268.0016
TrCB Std.
4a 2.61 e4
20.52-26.00
0%-
PCB-28/20
3.33e8
22.03
I PCB-21/33
2.41 eB
22.23
Rel, Int.
100%
Fn 3
269.9986
TrCB Std. j
4a 1.51e4
20.52-26.00
0%-
80567^6-25
PCB-23 21 29 4.26e7
1.57e7	21.49
2102 A A
21.0
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
Abs. Int.
-8.29e7
PCB-22
1,39e8
22.59
PCB-36 PCB-39
2.46e7 2 22e7
23.96 24.28
23.0

PCB-38
8.48e7
24.79
JL
PCB-35
1.48e8
25.18
PCB-37
2.08e8
25.54
•4.15e7
24.0
25.0
PCB-28Q0
3.17e8
22.03
\ PCB-21/33
2.31 e8
22.23
PCB-
PCB-23
1.50e7 „ zi
-L2k02 A A
21.0
7 67It^B-25
?1 ?4 4.07e7
21.49
PCB-37
2.57e8
25.54
PCB-22
1.33e8
22.59
23.0
PCB-36 PCB-39
2 30e7 2 11e7
23,96 24.27
PCB-38
7.91 e7
24,79
A
PCB-35
1.41e8
25.18
-O.OOeO
26.0 RT
Abs, Int.
7.86e?
3 93e7
24.0
25.0
SS-28
1.7367
22.01
i i i i i
21.0
I i i i I ' |—V t ~r-
22.0
SS-2&/
1.64^7
2T01

ES-37

1.56e7

25.52
A
7.60e6
ft
23.27
A

-O.OOeO
26.0 RT
Abs. Int.
4.77e6
2.38e6
23.0
24.0
250
ES-37
1.46e7
25.52
21.0
22.0
9.08e5
23.27
¦ O.OOeO
26.0 RT
Abs, Int.
-4,48e6
2.24e6
¦O.OOeO
23.0
24.0
25.0
26.0 RT
Rel. Int.
100%-
Fn 3
292.9824
QC Check
20.52-26.00'
0%-
Abs. Int.
-1.95e7
9.76e6
¦O.OOeO
21.0
22.0
23.0
24.0
25,0
26.0 RT
flesute: P:\P94GQ_P9499)P9464_6042 PCB\resources\P9464_6042_PCB_005RJ-D10.utp_res, saved 05-Aug-2008 09:19 (EE)
AP UltraTrace-Pro V3.993 L/serrtJysfem EE/EE.C2-03B cc 2387. 0318
Peak annotation: Areas. CentmtSs
Revised: 04-Aug-2008 11:31:37 (EE) Printed: OS-Aug-2008 09:22:20 Page 7<6f 22
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 2
289.9224
TeCB-2
4o t ,48e3
15.02-20.50
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 10
o%-
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
Abs. Int.
-1.13eS
•5.67e4
Rel, Int.
100%-
Fn 2
291.9194
TeCB-2
4o2 18e3
15.02-20.50
0%-
Rel. Int.
100%-
Fn 2
301.9626
TeCB Std.
4 o 1,93e3
15.02-20.50
0%-
<' I" ¦[ " r i' t i 1 i
16.0
y i i " i—r-
17.0
' "T* ¦—r"
18.0
2.92e4
18.51
¦-K3- <
"•—' " I ^
19.0
PCB-54
4.47eb
19.64
20.0
6.44e4
15.93
16.0
1 I 1
17.0
T '| ' I
,	1—1
18.0
r—{==,
19.0

PCB-54
5.82e5
19,64
20.0
ES-54
1.19e7
19.62
16.0
I I | f I
17.0
18.0
19.0
-O.OOeO
RT
Abs. Int.
-1.35e5
•6.77e4
•O.OOeO
RT
Abs. Int.
-2 68e6
¦1.34e6
20.0
, , O.OOeO
RT
Rel. Int.
100%-
Fn 2
303.9597
TeCB Std.
4o 2.26e3
15.02-20.50
0%-
fill!
16.0
I 1	1 1 *
17.0
18.0
19.0
19.62
20.0
-*—i—i—f- 0. OOeO
RT
Abs. Int.
-3 21e6
•1.61e6
Rel. Int.
100%-
Fn 2
242.9856
QC Check
15.02-20.50'
0%-
16.0
1—I—1
17.0
i—|—i
18.0
19.0
Results: P:\P9400 P9498\P9464_6042 PC8\resaurce$\P9464_6042 PCS 00SRJ-D10.utp_ms, saved 05-Aug-2008 09:19 (EE)
AP UltraTrace-Pm V3.993 User/System: ££EEC2-<338 cc: 7800, 14B9
~r
r | 1
20.0
Abs. Int.
-1.74e7
8.70e6
¦O.OOeO
RT
Peak annotation: Amas. Centmjels
Revised: Q4-Aug-2Q08 11:18:20 (EE) Printed: 05-Aug-2008 09:22:21 Page 8 of 22
-------
AP Lab ID: P9464_6042_PCB _005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel, Int.
100%-
Fn 3
289,9224
TeCB-3
4a 1.99e3
20.52-26.00
Sample ID; Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801 R20_EQ
o%-
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4ct 3.16e3
20.52-26.00
0%-
Rel. Int,
100%-,
Fn 3
301.9626
TeCB Std.
4o 3.10e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
303,9597
TeCB Std.
4o2.74e3
20.52-26.00
0%-
PCB-50/53
1,73e7
21.52
A
21.0
T"
PCB-45
1 80e7 PCB-46
22.11 7.67e6
/\ 22.39
. ¦/, ¦,
PCB-52
1.20e8
23.64 PCB-69M9
9.47e7
24.07
PCB-43
7.56e8
23.85
—A_
PCB-44/47/65
1.47e8
24.52
PCB-64
PCB-71/4%g0e?
8.14e7 25.60
21.0
1—I—
21.0
"T	T	T	T	f	I
21.0
22.0
23.0
PCB-48
3.8167
PCB-59/62/75
2.63e7
24.80
2.10e
PCB-50/53
2.27e7
21.52
A
PCB-45
2,36e7	PCB-46
22.11	1,00e7
/V	22^9
24.0
PCB-52
1.56e8	PCB-44/47/65
23.64 PCB-69/49 1.91e8
1.24e8	24,52
24.07
PCB-43
9.82 e6
23.85
	
25,0
PCB-64
PCB-71M617e8
1,06e8 55.60
22.0
""I	'I	I	I""
22.0
23.0
PCB-48
4.68e7
PCB-59/62/75
3.43e7
24.0
25.0
JS-52
1.24e7
23.62
23.0
JS-52-^
tide?
23.62
24.0
25.0
22.0
'"p1—">	—¦>"*'"*¦ rM*	i
23.0
24.0
""T	r	i	r	I	i
25.0
Abs. Int.
r3.09e7
-1,55e7
-O.OOeO
26.0 RT
Abs. Int.
4.03e7
2 02e7
¦O.OOeO
26.0 RT
Abs, Int,
-3.26e6
1.63e6
-O.OOeO
26.0 RT
Abs. Int.
4.22e6
2.11e6
•O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
292.9B24
QC Check
20.52-26.00"
0%-
21.0
1—'—r_
22.0
23.0
24.0
25.0
Abs. Int.
-1,95e7
•9 76e6
¦O.OOeO
26,0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\msources\P9464_6042_PCB_00SRJ-D10.utp_res, saved 05-Aug-2008 09:19 {EE}	Peak annotation: Areas. CentroipS
AP UttmTmce-Pro V3.993 User/System: E&EEC2-038 cc: 7486. 3355 ~	Revised: 04-Aug-2Q08 11:32:05 (EE) Printed: 05-Aug-2Q08 09:22:23 Page 9p?72
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 4
289.9224
TeCB-4
4o2 35e4
26.03-32.99
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb03Q6_c!1-10 GC: pcbx90_a Viai; 10
0%'
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4o 2.33e4
26.03-32.99
0%-
Rel. Int.
100%-
Fn 4
301.9626
TeCB Std.
4a 3.52e3
26.03-32.99
0%-
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
4o 7.31e3
26.03-32.99
0%-
PCB-61/70/74/76
447fle,8pCB-66
27.81 2.41e8
28.09
PCB-68
8,34e6
26.57
I | JT**|i |
ppp c7 PCB-67
r"Ks!3Sf j 2q07
8.92e6
^ 26J4 _ A ^
27.0
PCB-56
1.5468
28.65
CB-55
Acq: 01-Aug-2008 23:27:29
User: CJL Datafite: 080801R20 EQ
Abs. Int.
-6.97e7
PCB-79
3.93e?
30.50
.A,
PCB-78
2.63e7
30.96
30,0
PCB-81
2.04e?
31.35
A-
rCB-77
1,61e8
31.82
31,0
32,0
PCB-61/70/74/76
5.38e8pcB-66
27.81 a.iies
28.09
PCB-68 PCB-57
1.09e7 1.1587
26.57 26.93
PCB-67
2.90e7
27.29
1.98e8
28.65
F CB-55
PCB-77
2.08e8
31 82
27.0
28.0
29.0
I | 1
30.0
PCB-79
5.01e7
30.49
A
T
PCB-78
2.8067
30.97
/x
T
31.0
PCB-81
2.62©7
31.35
r-A-
3.63e5
29.16
I—***—r
27.0
28.0
29.0
30.0
31.0
ES-77
1.47e7
31,80
1.2567
31.33
27,0
¦ I «
28.0
29.0
30.0
ES-81
32.0
ES-jW^
i.B^e7
31.80
1 I 1
32.0
•3.49e7
-O.OOeO
RT
Abs. Int.
-8.94e7
4.47e7
-O.OOeO
RT
Abs. Int.
-3.68e6
¦1 84e6
-O.OOeO
RT
Abs. Int.
r4 60e6
•2.30e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
26.03-32.99
Abs. Int.
-2,64e7
1.32e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resourr:es\P9464_60
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx9Q_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
Rel. Int.
100%-
Fn 3
323.8834
PeCB-3
4o 1.02e3
20.52-26.00
0%-
21.0
PC 8-104
2.20e5
24.48
/V
22.0
230
24.0
T"
25.0
Abs. Int.
r4-58e5
•2.29e5
¦O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
4o1.61e3
20.52-26.00
0%-
21.0
22.0
-i	1	r-

A
PCB-104
4.15e5
24.49
,/SfN
23.0
24.0
—
25.0
JX
Abs. Int.
r7.69e5
•3.85s5
A
¦O.OOeO
26.0 RT
Rel, Int.
100%-
Fn 3
337.9207
PeCB Std.
40 1.57e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
339,9177
PeCB Std.
4o 1,45e3
20.52-26.00
0%-
i ¦ | i i j i i [ r i i t | t i t i | i i i i | ii t i i ) i i t i | i » i i
21 0		22.0	23.0	24.0
T 1 I
21.0
22.0
23.0
I I t I | I I I
24.0
250
ES-104/
tose?
2C46
25,0
Abs. Int.
-4.27e6
•2.13e6
-O.OOeO
26.0 RT
Abs. Int.
2.71e6
• 1,35e6
¦O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
20.52-26.00
23.0
Results: P:\P9400_P9499\P9464_6042 PCB\msources\P94B4_W42_PCB_OO5RJ-D10Mtp_re$, saved OS-Aag-2008 09:19 (EE)
AP UltmTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 2989, 6248
24.0
Abs. Int.
-1,95e7
9.76e6
O.OOeO
26.0 RT
Peak annotation: Areas, Centroidg,
Revised: 04-Atig-206B 11:33:34 (EE) Printed: 05-Aug-2008 09 22:25 Page 11
Centroidgs-
11at42
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 4
323.8834
PeCB-4
4ct 6.86e4
26.03-37 11
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_c!1-10 GC: pcbx90_ a Vial: 10
Acq: 01 -Aug-2008 23:27:29
User: CJL Datafile: 080801 R20_EQ
0%-
Rel, Int.
100%-
Fn 4
325.8804
PeCB-4
4o 1 36e5
26.03-37.11
0%-
Rel. Int.
100%-
Fn 4
337.9207
PeCB Std.
4o 5.05e3
26.03-37.11
0%-
PCB-108/119/86/97/
2.21e8
30.51

PCB-9S
4.92e7
2705
PCB-113/90/101
8.89e7
29.58
PCB-91
1.33e7
27.79a
	/\ /\
PC8-92
1.21e7
29.07
28.0

24e7,
9.77/
-4.
n
PCB-110
1.07e8
31.25
		 , JPCB-82
PCB-1 tfk76e7
2 95eS i 31,53
31Wl,A, ,
PCB-12
7.96e6
. KJ3:
PCB-118
1.Q4e8
/
/PCB-105
/ 6.96e7
34.79
30.0
PCB-108/119/86/97/
4.64e8
30.50
32.0
PCB-95
7.85e7
27.05
A
PCB-91
2.18e7
27.79.
. A A
PCB-113/90/101
1,48e8
	 29.58
PCB-92 ft,, ,
2.01 e7 /t7le7
29.07 if9Jy\/\
28.0
-1^
30.0
PCB-110
1.70e8
31.25
PCB-1 lteftB-82
3.44602.8887
31.1£1 31.53
A
T
34.0
PCB-118
1.66e8
33.80
PCB-114
7.13e6
34.25
" r- i
PCB-127
7.08e6
36.03
I	|
36.0
PCB-123
1.39e7
32.0
SS-111
2.20e7
31.83
PCB-114
1.15e7
34.25
i*"> i
PCB-105
1.12e8
34.79
34.0
PCB-127
1.22e7
36.03
	' r	¦	
36.0
JS-101
1.53e7
29.55
ES-123
1.66e7
33.49
ES-114
1.72e7
34.23
-T	1	r-
28.0
30.0
Rel. Int.
100%-
Fn 4
339,9177
PeCB Std.
4o3.51e3
26.03-37.11
0%-
JS-10V
9.84eo
prsb
28.0
6.66@5
^ 28^63
7.92e5
30.20
.	1
30.0
32 0
SS-111-
1.430T
3*33
8.99( S
31.7)
aT > .
/ \ ,
ES-105
1.77e7
34.77
1
32.0
i r i
34.0
ES-123 ^ ES-114 ES4t)5
1 OlfiT / 1 >2e7 H2e7
33.49 34.23 34.77
J {I \, u, J
I—I—1
36.0
Abs. Int.
-4.20e7
2.10e7
¦O.OOeO
RT
*"1
Abs. Int.
-8.76e7
•4.38e7
-O.OOeO
RT
Abs. Int.
-5.42e6
•2.71e6
34.0
,—,—,
36.0
-O.OOeO
RT
Abs. Int.
-3.51e6
1.75e6
O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
26.03-37.11
28.0
30.0
32.0
Abs. Int.
-2.64e7
1.32e7
O.OOeO
Results: P:\P9400_P9499\P9464_604Z PCBtesources\P9464_6042_PCB_00SRJ-D10Mtp_res. ssved OS-Aug-2008 09:19 (EE)
AP UltraTrace-Pm V3.993 User/System; ESE/EEC2-038 cc: 2551. 7652
36.0
Peak annotation: Areas, Centrwds
Revised: 04-Aug-2008 11:36:01 (EE) Printed: 0S-Aug-20Q8 08:22:26 Page 12/122
-------
AP Lab ID; P9464_6042_PCB_005RJ-D10
Instr; AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJl Datafile: 080801R20 EQ
Rel. Int.
100%-
Fn 5
323.8834
PeCB-5
4o1.63e5
37.13-44,01
0%-
i | r i
38.0
r [ i
39.0

>111
40.0
I I I *| I 'I I I | I I 1
41,0
42.0
430
Abs. Int.
-2.95e9
¦ 1,47e9
-O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4cj 8.89e4
37 13-44.01
0%-
ES-126
Rel. Int. 1-S0e7
100%-
Fn 5
337.9207
PeCB Std.
4a 6.30e3 ¦
37.13-44.01
37.38
38.0

39,0
40.0
41.0
-i—|—
42.0
7.30e6
41.09
0%-*—r—f——i—]—i—i—i—i—[—i—i—i—r—]—i—i—*—i—f—i—i	i y*i—t—i—i—i—j—t—i—i—i—y—r^"i—i—i—|—»—i—i—r—|—r
Rel. Int. lf2e7
100%-, 37;38
38.0
39.0
Fn 5
339,9177
PeCB Std.
4o6 42e3
37.13-44.01
0%-
-i—r^i-
38.0
I I " | I
39,0
40.0
41.0
42.0
4.84e6
41.09
4.02e5
39.92
f=T—r
40.0
l I—i—(—j—I—*—i—!—|—r—1—i—r-
41.0	42.0
43.0
43.0
43.0
Abs. Int.
-2.95e9
1.47e9
-O.OOeO
44.0 RT
Abs. Int.
4.25e6
2.12e6
¦O.OOeO
44.0 RT
Abs. Int.
-2,64e6
¦1.32e6
•O.OOeO
44,0 RT
Rel, Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01'
r
40.0	41.0
Results: P:\P9400_P9499\P9464_6042 PCB\resaurces\P9464_6042_PCB_005RJ-D10,utp_m&, saved 05-Aug-2008 09:19 (EE)
AP UllraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 3469, 0827
Abs. Int.
-8.43e6
4,21 e6
O.OOeO
44.0 RT
Peak annotation Areas, Centrpkls
Revised: 04-Aug-2008 11:36:05 (EE) Printed: 05-Aug-2008 09:22:27 Page iy% 22
-------
AP Lab ID: P9464_6042_PCB _Q05RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4o 1.74e3
27.99-37.11
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_d1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
0%-
280
Rel. Int.
100%-
Fn 4
361,8385
HxCB-4
4o 1.25e3
27.99-37.11
0%-
28.0
Rel. Int.
100%-
Fn 4
371.8817
HxCBSM.
4o 1 85e3
27.99-37.11
0%-
28.0
Rel. Int.
100%-
Fn 4
373.8788
HxCB Std.
4a2.51e3
27.99-37.11
0%-
28.0
PCB-147/149
6.03e7
32.82
PCB-163/138/129
9.18e7
36.43
PCB-136
1.57e7
30.00
A
29.0
30.0
PCB-151/135
2.57e7 PC B-144
32.05 6,6666
32.52
, , A .
A
PCB-132
2.63e7
JBflSS-139/140 33k89 pen 111
[71e6 5.41e6 A p2cf2^3
>3.00 33,34	\
31.0
32.0
i

-A-
33.0
34.0
i
PCB-163/168
9.29e7
PCB-156
2.18e7
36.77
PCB-146
B- 41
1.90e7
B-164
1L81e7
34.85
Abs. Int.
•1.94e7
-9,68e6
¦O.OOeO
37.0 RT
PCB-147/149
4.91e7
32.82
PCB-153/168
6.49e7
35.38
PCB-163/138/129
7.13e7
36.43
PCB-136
1.29e7
30.00
A-.
PCB-151/135
2 08e7 pcB-144
32.05 Usee
32.52
29.0
30,0

A

PCB-132
2.05e?
;Bfl8*-139/140 33k89 pm 111
A If
31.0
32.0
33,0
PCB-146
1.48e7
34,85
T
34.0
-J-T-
A
t	I V
35.0
'CB-141
B-164
1 26e7
PCB-158
1.76e7
36.77
ib,.
Abs. Int.
-1.59e7
•7 97e6
-O.OOeO
370 RT
ES-155
1.72e7
29,38
ES-153
1.3967
35.36
29.0
""i	j	r	r-T"
30.0
""|			t	r	t	|"'"t	r	i—T'-j-frri	
31.0	32.0	33.0
	("""C""T""r""T""t""
34.0
Abs. Int.
-4.30e6
•2,15e6
O.OOeO
35.0
¦ T- y rr r f | i t"ii|
36.0	37.0 RT
ES-1S
1 3867
138
ES-153^
i.o aSr
3S3B
JS-13S-^
9.7866
36.41
MX
29.0
I ' 1 ' ' I '
30,0
-j—i—i—i—i—|—i—n—!—f" i i—j—i—|—f—!—r-
31.0	32,0
-!—i—r-i—|—n—!—i—fl—i—i—i—i—|—i—ri—*—p
33.0	34.0
i f i i i i
Abs. Int.
- 3.49e6
• 1,74e6
35.0
36.0
-j-f-O.OOeO
37.0 RT
Rel. Int.
100%-
Fn 4
330,9792
QC Check
27.99-37.11'
28.0	29.0	30.0	31.0	32.0	33.0
Results: P:\P9400_P9499\P9464_G042 PC8\re$aunxs\P9464_6O42_PC8_0OSRJ-D1O.utp_ms, saved OS-Aug-2008 09:19 (EE)
AP UltmTrace-Pm V3.993 User/System: EEJEEC2-038 cc: (286. 8392
34.0
| 1 T I T |
35 0
Abs. Int.
-2.64e7
1 32e7
O.OOeO
36,0	37.0 RT
Peak annotation: Areas, Centmids
Revised: 04-Aug-2008 13:22:57 (EE) Printed: OMug-2008 09:22:28 Page If of 22
-------
AP Lab ID: P9464_6042_PCB J305RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%'
Fn 5
359.8415
HxCB-5
4a 2.89e4
37.13-44.01
PCB-128/166
1.31e7
37.50a
38.0
PCB-iSPB-162
2.88e6*f6g6
/\ 38,32 38,5(3
< > *P-i
Sample ID; Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
PCB-167
1.13e7
38.96
39.0
)
RGB-156/157
3.29e7
39.93
Acq: Q1-Aug-20Q8 23:27:29
User: CJL Datafile: 080801R20_EQ
Abs. Int.
r2.02e7
PCB-169
2.95e7
42.63
A\ M
40.0
41.0
42.0
43.0
1.01e7
O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4o 2.51e4
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
371.8817
HxCB Std.
40 4.34e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
373.8788
HxCB Std.
4o 4.67e3
37.13-44.01
0%-
PCB-128/166
1.07e7
37.50a
. /y\
38.0
PCB-lifB.1|2
2.29e63-98e6
38.32 38 56
¦A ¦"¦7 ,
PCB-167
0.01 e6
38.96
PCB-156/157
2.67e7
39.93
PCB-169
2.35e7
42.62
A
38.0
38.0
39.0
39.0
38.94
39.0
40.0
ES-156/157
2.7te7
39.92
41.0
ir,,TIM l—f
42,0
/A /V\ I
r^-1—l 1 I		 l—> r i—I—l—i—i-4-!—r-V-
43,0
1.95e6
41.10
40.0
ES-156/157
2.10e7
39

41.0
42.0
43.0
T-r-
ES-169
1.08eK
4*63
1.80e6
4T10
40.0
41.0
42.0
43.0
Abs. Int.
-1.72e7
8 61e6
O.OOeO
44.0 RT
Abs. Int.
-4.68e6
•2 34e6
O.OOeO
44.0 RT
Abs. Int.
-3.75e6
•1.8fle6
•O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01'
0%-
i i f	i i1 | t i r « i r i
38.0	39.0
T
40.0
"T
~r
41.0
Results: P:)P9400_P9499\P9464_6042 PCB\msourees\P9464_6042_PCB_005RJ-D10.Utp_ms, saved Q5-Aug-2008 09:19 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 9078, 2839
42.0
43.0
Abs. Int.
-8.43e6
¦4.21e6
-i—i—(— O.OOeO
44.0 RT
Peak annotation: Areas, Centroids
Revised: 04-Aug-2008 13:23:25 (EE) Printed: OS-Aug.2008 09:22:29 Page 150^22
-------
AP Lab ID: P9464_6042_PCB 005RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
Ret, Int.
100%-
Fn 4
393-8025
HpCB-4
4a 1.49e3
30,01-37.11
0%-
31.0
32.0
33.0
PCB-17S
8 36e6
34.53
PCB-176
5.41 e6
PCB-18435'27
1.03e6
34.99
i
I
35,0
"" t—i—[—i—r-
36.0
PCB-178
3.47e6
36.81
A
Abs. Int.
-3.72e6
• 1 86e6
O.OOeO
I i i" r"N—f
37.0 RT
Rel. Int.
100%-
Fn4
395.7995
HpCB-4
4o 1,41e3
30.01-37 11
0%-
Rel. Int.
100%-
Fn 4
405.8428
HpCB Std.
4o215e3
30.01-37.11
0%-
Rel. Int.
100%-
Fn 4
407.8398
HpCB Std.
4a 1 67e3
30.01-37.11
0%-
I 1 f f
31,0
3l'.0
31,0
> I ! | I I
320
33.0
34.0
PCB-17!
8.05e6
34.53
PCB-176
PCB-18^22,^
1.09e6 fV
34.99 /V\
—i i i' A r	
35.0
ES-188
1.34e7
34.23
T-r^r-
32.0
6.15e5
33.57
	1^-r
32,0
33.0
34.0
35.0
ES-1B8
1.25e7,
3A.&
6.98e5
33.57
33.0
34,0
35,0
36.0
36,0
36.0
PCB-178
3.35e6
36.81
A
Abs, Int.
-6.75e6
3.37e6
¦O.OOeO
37.0 RT
SS-178
9.45e6
Abs. Int.
-3.37e6
1.69e6
¦O.OOeO
37.0 RT
SS-178^
asies
1679
"T"
Abs. Int.
-3.17e6
¦ 1,59e6
i.OOeO
37.0 RT
Rel. Int.
100%-
Fn 4
330.9792
QC Check
30.01-37.11"
Abs. Int.
-2.64e7
-1 32e7
0%-
31.0	32.0
t
33.0	34,0
Results: P:\P9400_P94Q9\P9464_6042 PCB\resources\P9464_6O42_PCB_005RJ-D10 utp_re$. saved 0S-Aug-2008 09:19 (EE)
AP UltraTmce-Pm V3.993 User/System: EE/EEC2-038 cc 4090. 3084
t t |—i—i—f—i—|—i i i—i—|—i—i—i—i—|—i—i—» " r	|—0. OOeO
35.0	36.0	37.0 RT
Peak annotation: Areas, Centroids^
Revised: 04-Aug-2008 13:23:45 (EE} Printed: OS-Aug-2008 09:22 30 Page 16 of22
T
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 5
393,8025
HpCB-5
4o 3,99e4
37,13-44.01
0%-
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_ci1-10 GC: pebx90_a Vial: 10
PCB-180/193
4.34e7
41.11
Acq. 01-Aug-2008 23:27:29
User: CJL Datafiie: 080801R20 EQ
Abs, Int.
-1,27e7
PCB-187
1.86e7
37.58
PCB-175
2.63e6
37.35
i <"¦>
PC B-183
1.40e7
38.10
AA.
PCB-177
B.75e6
38.66
Rel. Int.
100%-
Fn 5
395,7995
HpCB-5
4o4 78e4
37,13-44.01
0%-
Rel. Irtt.
100%-
Fn 5
405.8428
HpCB-5 Std,
4o 5.33e3
37.13-44.01
0%-
38.0
PCB-171/173
7.19e6
30.20
39.0
PCB-172
4.53e6
40.56
40.0

PCB-191
3.93e6
41.40
. ,
PCB-170
1.62e7
42.17
PCB-190
6,80e6
42.61
A _
41.0
PCB-180/193
4.22e7
41.11
42.0
43,0
PCB-187
1.7987 PCB-183
37.58	1.36e7
PCB-175 rPCB-182 38.10
2.54«6 I \ 1 32e6
37,35 / \ 37 76
-i—O / Ai"l—r
*38.0
JO. IU
/VA
• ¦ T l ' l
PCB-177
6.48e6
38.66
r—/-V—r-
PCB-171/173
6,90e6
39,20
39.0
PCB-172
4.44e6
40.56
40.0

PCB-191
3 65e6
41.40
^ .
PCB-170
1.56e7
42.16
41.0
ES-170
1,70e7
41.10
I
42.0
PCB-190
6,67e6
42.61
43.0
5.78e5
39.43
¦ -r».
38.0
39.0
40.0
J
41.0
42.0
43.0
¦6.33e6
•O.OOeO
44.0 RT
Abs. Int.
-1.27e7
-6.34e6
-O.OOeO
44.0 RT
Abs. Int.
5.03e6
¦2.52e6
-O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
407,8398
HpCB-5 Std..
4o 4.35e3
37.13-44.01
0%-
I | I
38,0
39.0
40.0
41.0
42.0
43.0
Abs. Int.
-4.65e6
•2.33e6
¦O.OOeO
44.0 RT
Rel. Int.
100%
Fn 5
454,9728
QC Check
37.13-44.01
Abs. Int.
-8.43e6
4 21e6
O.OOeO
38.0
39.0
40.0
41.0
42.0
43.0
44.0 RT
Results: P:\P9400_P949S\P9464_S042 PCB\resources\P9464_6042_PCB_005RJ-D10.utp res. saved 05-Aug-200S 09:19 (EE)
AP UltraTrace-Pm V3 993 User/System: EE£EC2-038 cc: 6340, 1473
Peak annotation: Areas, Cenfrotds
Revised: 04-Aug-2008 13:25:55 (EE) Printed: 05-Aug-200B 09:22:31 Page 17 of 22
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-UItima MM3
Sample ID; Run# II-ACD-M23-1
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801 R20_EQ
Rel. Int.
100%-,
5,79e6
Fn 6
44.77
A
393.8025 •
A
Hpce-6 :

4o 8 96e3 .

44 02-49.21 -
J \
0%-

45.0
—!	1	1	r-
	j—f
46.0
t	1	rJ" f	r
47.0
—r	(	1	1	r-
48.0
49.0
Abs. Int.
-1.61e6
-8.03e5
-O.OOeO
RT
Rel. Int.
100%-
Fn 6
395.7995
HpCB-6
4o6.18e3
44,02-49.21
0%-
PCB-189
5.7866
-i	!¦""> |	r—r
46.0
Abs, Int.
-1.54e6
•7.68e5
47.0
48,0
49,0
•O.OOeO
RT
Rel, Int.
100%-
Fn 6
405.8428
HpCBStd.
4o 6.64e3
44,02-49.21
0%-
45.0
45.0
5,55e6
46.73
46.0
47.0
3.26e7
48.30
48.0
46.0
47.0
48.0
49.0
49.0
Abs. Int.
-5.87e6
¦2.93e6
¦O.OOeO
RT

ES-188



Rel. Int.
1,2267
4?,75
* A


Abs. Int.
100%-,


-2.82e6
Fn 6
A

i.i6e7
4B.30

407.8398 ¦


A

HpCBStd. J


/
-1.41e6
4a 7.4le3


/
44.02-49.21 ¦
/
2,19©6
/

i \
46,75
/
-
0%-
\	
	,			,	T~ I 	»=-l	1	1	,	1	1	
	/, \	
-O.OOeO
RT
Rel, Int.
100%-
Fn 6
404.9760
QC Check
44 02-49.21"
0%-
45.0
46.0
47.0
48.0
-1—'—I—
49.0
Abs. Int.
-7.76e6
•3.88e6
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resaurces\P9464_6042_PCB_Q05RJ-D10.utp^_re$, saved Q5-Aug-20Q8 09:19 (EE)	Peak annotation: Areas, Centroids
AP UttcaTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 0139. 1742	Revised: 04-Aug-2008 13:25 57 (EE! Printed: 05-Aug-2008 09:22:32 PageUp of 22
-------
AP Lab ID: P9464_6042_PCB_005FU-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 5
427.7635
OcCB-5
4a 3.23e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
429.7606
OcCB-5
4o 4.08e3
37.13-44.01
0%-
Rel, Int.
100%-
Fn 5
439.8038
OcCi Std.
4o 1.21 e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
441.6008
OcCB Std,
4o 1.68e3
37.13-44.01
0%-
38,0
38,0
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
PC 0-108/198
1,39e7
42,75
PCB-202
3.96e6
38.78
PCB-201
3,95e6
39,54
f\ /\
t » |¦ i pi f r v

PCB-200
PCB-aO^JSe6
4.56e5 40-40
40.13 /V\
-4=t

PCB-196
7,1 See
43.31
39,0
40.0
41,0
42.0
43.0
i——r-
PCB-198/189
1.54e7
42,75
PCB-202
S.83e6
38.79
PCB-201
4,90e6
39,54
PCB-196
7.99e6
43.31
¦A.A. .a
PCB-200
PCB^D^2-®2?®
4.96e5
40.13 /V\
-f=V-
,.
-------
AP Lab ID; P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801 R20_EQ
Rel. Irit.
100%-
Fn 6
427.7635
OcCB-6
4o 2.70e3
44.02-49,21
0%
PCB-195
2.89e6
44.58
45.0
46.0
PCB-205
1.77e6
46.93
-A-
5.89e6
48.41
47.0
48.0
Abs. Int.
-2 08e6
• 1.04e6
OOOeO
I [ I f
49.0 RT
Rel. Int.
100%-
Fn 6
429.7606
OcCB-6
4a3.11e3
44.02-49.21
0%-
Rel. tnt.
100%-
Fn 6
439.8038
OcCB Std
4o 2.95e3
44.02-49.21
0%-
Rel. Int.
100%-
Fn 6
441.8008
OcCB Std.
4o 3.16e3
44.02-49 21
0%-
PCB-195
3,23@6
44.58
45.0
46.0
PCB-205
1.98e6
46,93
7 08e5
48.41
47.0
48,0
45.0
46.0
45.0
46.0
ES-205
1.03e7
JS-194
8.97e6
JS-194
46.91
48,0
49.0
490
Abs. Int.
-2.24e6
1.12e6
-O.OOeO
RT
Abs. Int.
r2.46e6
1.23e6
-O.OOeO
RT
Abs. Int.
-2.72e6
-1,36e6
47.0
48.0
49.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
44.02-49.21"
0%-
45.0
46.0
47.0
48.0
1—r_
49.0
Abs. Int.
-7.76e6
•3.88e6
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\msouices\P9464i_6042_PCB_005RJ-D10.utp_ms. saved 05-Aug-2008 09:19 (EE)
AP UmTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 2207. 4767
Peak annotation: Areas, Certiroids
Revised: OA-Aug-2008 13:31:54 (EE) Printed: 05-Aug-20CB 09:22:35 Page 20pf22
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 6
461.7245
NoCB
4o 2.76e3
44.02-49.21
0%-
Rel. Int.
100%-
Fn 6
463.7216
NoCB
4o 4.74e3
44.02-49.21
0%-
Rel. Int.
100%-
Fni
473.7648
NoCBStd.
4o 1.65e3
44.02-49.21
0%-
Rel. Int.
100%-
Fn 6
475.7619
NoCBStd.
4o 1,98e3
44.02-49.21
0%-
PCB-208
4.38e6
44.38
PCB-2D8
5.61 e$
44.38
ES-208
8.94e6
44.36
ES-20fr-^
/«,36
Sample ID: Run# II-ACD-M23-1
VSIRexpt: pcb0306_c!1-10 GO: pcbx90_a Vial: 10


PCB-206


1.00e7


48.40
A
PCB-207


3.40e6

J
45.17
A 	

	A
45.0
46.0
45.0
46.0
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
Abs. Int.
-2.33e6
47.0
48.0
49.0

PCB-206

1.2867

48.40
A
PCB-207

4.37e6

45.17
A
47,0
48.0
P » » |
49.0
ES-206
7.15e6
48.38
45.0
46.0
47.0
""f	>	|	»	
48.0
45.0
->—r
	1	.	r-
46.0
ES-206
9.2 lea
•1.16e6
-O.OOeO
RT
Abs. Int.
-2.99e6
• 1,50e6
1—1—¦"
49.0
-O.OOeO
RT
Abs. Int.
-2.14e6
1.07e6
-O.OOeO
RT
Abs. Int.
-2.60e6
¦ 1,30e8
47.0
48.0
49.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
44.02-49.21'
0%-
45,0
I 1 I I
46,0
47.0
48.0
"I	
1	1	
49.0
Abs, Int.
-7.76e6
•3.88e6
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6(M2_PCB_005RJ-D10 utp_res. saved OS-Aug-2008 09:19 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc 8820. 5552
Peak annotation: Areas, Centmips
Revised: 04-Aug-2008 13:32:05 (EES Printed: QS-Aug-2008 09:22:36 Page 21gfz2
-------
AP Lab ID: P9464_6042_PCB_005RJ-D10
Instr: AutoSpec-Ultima MM3

PCB-209
Rel. Int.
7.72e6
100%^
49.75
Fn 7 !
A
497.6826 ¦
M '
DeCB
/
4o 7.49e2 "
/
49.22-53.00 ¦
/ \
0%-
1 ' ¦ ' ¦ I ¦ ¦ ¦/ I
Rel, Int.
100%
Fn?
509.7229
DeCB Std
4o 8.13e2 .
49.22-53 00 ¦
0%-
Rel. Int.
100%-
Fn7
511.7199
OeCB Std.
4c 6 65e2
49 22-53.00
0%-
49.5

PCB-209
Rel. fnt.
6.52e6
100%-j
49,75
A
Fn 7 :
A
499.6797 -

DeCB :

4a 5.19e2 .

49.22-53,00 ;
/ \
0%-

49.5
¦ I '
49.5
ES-209
1.04e7
49.73
50.0
50.0
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 10
Acq: 01-Aug-2008 23:27:29
User: CJL Datafile: 080801R20 EQ
Abs. Int.
-1,75e6
2.4Se5
50.40
! 1 I I I I I r-m
50.5
51.0
1 I '
51.5
52.0
3.25eS
50.40
T I 1 '
50.5
"i	[¦	r	i	t	t	j	r
51.0
51.5
> I | I 1 I I |
52.0
50.0
I » | 	 » I "I	|	I1		I	I""
50.5
51.0
51,5
52,0
ES-209 „
8.68e§^-'
4j£lV
49.5
50.0
~f-r-
' I ' 1
50.5
I-r"
51.0
51.5
52.0
t [—i—r—i1 »¦
52.5
8.76e5
-r*—i—i—i—
52.5
52.5
52.5
¦O.OOeO
53.0 RT
Abs. Int.
1,45e6
•7.27e5
¦O.OOeO
53.0 RT
Abs. Int.
2 41e6
1,20e6
-O.OOeO
53.0 RT
Abs. Int.
2,00e6
9.98e5
¦O.OOeO
53.0 RT
Rel. Int.
100%
Fn 7
454.9728
QC Check
49.22-53.00'
Q%-
49,5
50.0
50.5
51.0
51,5
Results: P:\P9400_P9499\P9464_6042 PCB\K$Ources\P9464_6Q42_PCB_005RJ-D1Q.utp_m$, saved OS-Aug-2008 09:19 (EE)
AP UltraTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 7988, 1174
52.0
""I	T	T	f	V"
52.5
Abs. Int.
-7.20e6
¦ 3.60e6
¦O.OOeO
53.0 RT
Peak annotation: Areas, Cmtmids
Revised: 04-Aug-2QQ8 11:24:47 (EE) Printed: OS-Aug-2008 09:22:37 Page 22 off 2
-------
AP Lab ID: P9464_6042_PCBJ)05
Instr: AutoSpec-Premier MM6
Sample ID; Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14_EQ
Rel. Int.
Fn 1 100%.
218.9856
QC {non-EQ;
9.03-13.00
Rel. Int.
Fn 2 100%
242.9856
QC (non-EQ)
13.02-17.79
Rel, Int
Fn 3 100%.
292.9824
QC (non-EQ)
17.81-23.26
Abs. Ira.
7.08e7
13.54e7
E-O.OOeO
13.0 RT
Abs. Int
3.52e7
1.76e7
Abs. Int.
^3.65e7
-1.82e?
O.OOeO
Rel. Int.
Fn 4 100%
330,9792
QC (non-EQ) j
23.27-34.14
0%.
24.0
26.0
—t	!	1	J	1	
28.0
I
30.0
-i—i—i—r
32.0
Abs. Int.
-3.90e7
1.1.95e?
O.OOeO
—1—r
34.0 RT
Rel. Int.
Fn 5 100%
366.9792
QC (non-EQ)
34.16-41.15
Abs. Int
—7.Q8e6
-3.54e6
L-O.OOeO
35,0
36.0
Rel. Int.
Fn 6 100%-
454.9728 j
QC (non-EQ) :
41,17-46.41
Q%~
—I—
42.0
43.0
	1—
44.0
45.0
—,—
46.0
Abs. Int.
-1 22e7
•6.11e6
•O.OOeO
RT
Rel, Int.
Fn 7 100%-
454.9728
QC (non-EQ) ,
46.42-54.01
54.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\msoua:esV>9464_6Q42_PCB_00S.utp_re$. saved 0S-Aug-2008 08:24 (EE)
AP UltmTmce-Pro V3 9B3 User/System: EE/EEC2-038 see: 973-180
Peak annotation: Areas. Centroids
PKD: n/a Printed: 0S-Aug-2O0d 08:31:30 Paget of 22
-------
AP Lab ID: P9464_6042_PCB_005
instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_clt-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14 EQ
Rel, Irit,
Fn 1 100%.
218,9856
QC Check
9,03-13.00
0%-

-i—i—i—I—i—i—i—i—I—i—i—r-
9,5
—t—i—i—f—l—i—I—r—
10,0
10,5
-i—i—i—|—i—i—i—i—|—j—i—'—i—j-
11,0
-i—|—i—!—r-
11,5
12,0
"I—I—I—I—|—I—I—I—I—|—r
12.5
Abs. Int.
-8.04©7
4,02e7
-i—,—»-O.OOeO
13.0 RT
Rel. Int.
Fn 2 100%-
242.9856 j
QC Check
13.02-17.79
0%-1-r
-i—i—i—i—i—r-
13.5
T
14.0
¦ I '
14.5
15.0
15.5
16.0
' I '
16.5
-i—i—|—rr-
17.0
Abs, Int.
-2,99e?
1.5067
17.5
¦ O.OOeO
RT
Fn 3
Rel. Int.
100%.
292.9824
QC Check
17.81-23,26
0%-
—I—
18.0
19.0
20,0
21.0
22,0
Abs. Int.
-2.96e7
• 1.48e7
—|—,—r-*- 0. OOeO
23.0	RT
Fn4
Rel. Int.
100%.
330.9792
QC Check
23.27-34.14
0%-
—I—
24,0
1 I I
—I—
32.0
Abs. Int
-3.2487
. 1.62e7
-O.OOeO
—r
34.0 RT
26.0
28,0
30.0
Rel. Int.
Fn S 100%.
454.9728
QC Check
34.16-41,15
0%.
-»—i—i—j—i—i—i—r-
35,0
36.0
37.0
38.0
—i—i—i—i—i—i—i—i—i—r—i—i—|—r
39,0
r
40.0
• 1 1
41.0
Abs. Int.
-1.630?
.8 13e6
¦ O.OOeO
RT
Rel, Int.
Fn 6 100%.
404,9760
QC Check
41.17-46.41
0%.
T	1	1	1	1	1	!	1 |	
42.0
—j	1	1	1	1	j	1	r-
43.0
44.0
~i	j	r~
45,0
46.0
Abs, Int,
-1,16e7
-5,80e6
. -O.OOeO
RT
Rel. Int.
Fn 7 100%-
454,9728
QC Check
46.42-54.01
0%.
~i—i—i—r—i—v i
47.0
¦t—|—i—i—i—i—|—i—i—»—i—|—i—i—i—»—|—r-
48,0	49.0
-t—i—i—i—|—r"
50.0
51.0
' I '
52.0
r" i 't—|—r~i—i—r-
53.0
Abs. Int.
-1.1967
.5 93e6
¦ O.OOeO
54.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9461_6042_PC8_005 utp_res. saved OS-Aug~2008 08:24 (EE)
AP UttraTmce-Pm V3.993 User/System: EE/EEC2-03B
Peak annotation: Areas, Centmids
PKD: n/a Printed: QS-Aug-2008 08:31:31 Page 2 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxl 00_a Vial; 63
Acq; 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14 EQ
Rel. Int.
100%-
Fn 1
188.0393
MoCB
4o 9.61 e3
9.03-13.00
0%-
1.24e9
,03e8
11.51 4.33e8
11.64
10.0
10.5
11.0
11.5
12,0
12.5
Abs. Int.
-1.94e8
• 9.71e7
-O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
190.0363
MoCB
40 7.13e3
9,03-13.00
0%-
i 20e8
¦ I '
10,0
10.5
i i i | i r i i |
11.0
4.05e8
3le8
11.51 i.40eS
11.65
Abs. Int.
-6.30e7
• 3.15e7
11.5
12.0
12 5
-O.OOeO
13.0 RT
Rel. Int.
100%-,
3.67e7
9.54
Fn 1
200.0795 ¦
MoCB Std. J
4o 2.04e4
9.03-13.00 ;
i
0%-

"¦¦r	i	f	r	
9.5
10.0
10.5
11.0
1.56e7
11.50
4.55e6
11.5
T—j-¦r l l | t f f t
12.0
Abs. Int.
-1.31e7
-6.54e6
t i I i i i i I O.OOeO
12.5	13.0 RT
Rel. Int.
100%
Fn 1
202,0766
MoCB Std.
4ct 9.86e4
9.03-13.00
I.i0e7
4.53e6
11.49
2.5Zee
12.41
7.84e5
11.90
4 63e5 1.2166
H.ojca	10,47
7.42e5
12.82
4.27e5
11.27
Abs. Int.
-4 28e6
2.14e6
O.OOeO
13.0RT
Rel. tnt.
100%-
Fn 1
218.9856
QC Check
9.03-13.00
0%-
¦ i ¦
9.5
10.0
10.5
11.0
• i ¦
11.5
120
Results: P:\P9400 P9499W9464_6042 PCBSm$Ource$\P9464 6042 PCB OOS.utp res. saved 05-Aug-2008 08:24 (EE)
AP UttraTrace-Pm V3.993 User/System: EBEEC2-038 cc: 7f08, 9401
'* T"1,
12.5
> 1 I
Abs. Int.
-8.04e7
•4.0267
i i i O.OOeO
13.0RT
Peak annotation: Areas, Centmids
PKD: 0S-Aug-2008 08:24:18 Printed: OS-Aug-2008 08:31:32 Page 3 of 22
-------
AP Lab ID: P9464_6042_PCB_005
instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Viai: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14..EQ
Rel. Int.
100%-
Fn 1
222.0003
DiCB-1
4o 7.65e3
9.03-13.00
0%-
I.77e6
II.77
9.5	10.0	10.5
11.0
-I	1—I	1	P"
48e6
2.05
Si
1.04e6 1.61e6
12.64 12.81
"fT" t i'» t | »^i » i [—r
11.5
12.0
¦ 1 11'	
12.5
Abs. Int.
-1.49e7
• 7.47e6
•O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
223.9974
DiCB-1
4o 3.24e4 .
9.03-13.00
0%-
» I t 1 | I 1 1 I | I I t I t I I I j 1
9,5	10.0
""1	ymy-iH.—y	J	|f|||||j|
10,5	11.0
I,76e6
II,80
74e6
12,04
-j—I—I—t lllin| t ''I " f
JiA
i—r i t—i—i—I—i—i
11.5
12.0
1 i *
12.5
1.13e6
12.64 12.81
.. fT-,	i" i
Abs. Int.
-9 98e6
¦4.99e6
•O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
234,0406
DiCB Std.
40 1,52e4 .
9.03-13.00
0%-
I.09e6"l-?%,e
II.71	1186
r r i r | r i I i | i
9.5
i | i r i i | i t i
10.0
• i •
10.5
I I
t | I 1
11.0
TT"
' I '
11,5
12.0
12.5
Abs. Int.
-1.09e7
¦5.46e6
-O.OOeO
13.0 RT
Rel. Int.
100%
Fn 1
236.0376
DiCB Std.
4a 6 75e3
9.03-13.00
0%-*"l—I—I—I—J—!	1—I	1—|—I—1—I	1—J—!	1—I I |
9.5	10.0
1 I • ' 1 ' I 1 i 1 1 I
10.5
11.0	11.5
12.0
12.5
Abs. Int.
-7.15e6
¦3,57e6
•O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
218.9856
QC Check
9.03-13.00 '

10.0
10.5
Results: P:\P9400_P9499\P9464JB042 PCBVe$OurcesV9464_6O42_PCB_00S.utp_res. saved OS-Aug-2003 00:24 (EE)
AP UltraTrace-Pro 1/3.993 Usef/Systern EE/EEC2-03B cc: 4133. 4928
Abs. Int.
-8.04e7
4,02e7
O.OOeO
13.0RT
Peak annotation: Areas. Centroids
PKD: 0S-Aug-2008 08:24:18 Printed: 0S-Aug-2008 08:31:33 Page 4 of 22
-------
AP Lab ID: P9464_6042_PGB_0Q5
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14EQ
Rel. Int.
100%-
Fn 2
222.0003
DiCB-2
4a 1 50e4
13.07-17.79
0%-
3.28e7
13.50
y; a, , a
H2e8
7.39e7 14.12
13.8S
13.5
14.0
m.
1,57e8
15.63
14 5
15.0
-i—i | r i
15.5
2.3988
16.37
"T t | t I 1 I | f I I "I |
16.0	16.5
16.64
1,74e8
16.93
¦rOv,
17.0
Abs, Int.
-1.89e8
•9.43e7
j i i i j | i i i i | 0. OOeO
17.5	RT
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4a 2.25e4
13 07-17.79
0%-
2.18e7
13.50
/\ /\
< t-1 i < iN
7.32e7
4,B8e7 14.12
13.85
aA
¦ i i*» i*i
i -t j >-t "r-r-i m i h | f m i | i'i iti pi i f i | i i i i | i i i i | i < i i |
13-5	14.0	14.5	15.0
1.02e8
18.62
-A_
15.5
16.0
1.13e8
16.93
16.5
17.0
Abs. Int.
-1,23e8
¦6.13e7
O.QOeP
17.5	RT
Ret. Int.
100%-
Fn 2
234.0406
DiCB Std.
4a1.42e4
13.07-17.79
0%-
2.91e7
13.48
Jl
• ' I 1
13.5
3.06e7
16.91
-1	J i % I "P* | 1 I I I | 1
14.0	14.5
15.0
'l ' 11 1 I 11 11 I '
15.5	16.0
—i—pi—i—i—i—j-
16.5
17.0
17.5
Abs. Int.
-1.07e7
•5.34e6
O.OOeO
RT
Rel. Int.
100%
Fn 2
236.0376
DiCB Std. J
4o 1 37e4 .
13.07-17.79
0%-
1,81e7
13.48
(l
I I I | I I I 'I |
13.5
1.92e7
16.91
I i i i i I i i i y I
14.0
f | 1 1 i I \ I I I I | « I
14,5	15.0
15.5	16.0
I | »
16.5
17,0
Abs. Int.
-6.74e6
¦3.37e6
17.5
¦ O.OOeO
RT
Rel. Int.
100%'
Fn 2
242.9856
00 Check
13.07-17.79 J
Abs. Int.
-2.99e7
1,50e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCBbemurce$\P9464_6042_PCB_005.utp_ms, saved 05-Aug-2008 08:24 (EE)
AP UltraTrace-Pm V3.993 User/System EE/EEC2-038 cc 5013, 2121
Peak annotation: Areas. Centmitts
PKO OS-Aug-2008 08:24:18 Printed: 0S-Aug-2008 00:31:34 Page 5 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Inslr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Via!: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14_EQ
Rel. Int.
100%-
Fn 2
255.9613
TrCB-2
4
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Ju1-2008 12:37:31
User: JLJ Datafile: 080724V14_EQ
Re I. Int.
100%-
Fn 3
255.9613
TrCB-3
4ct 5.73e3
17.81-23,26
0%'
9.63e7 ,
18 75 5,17e7
1.93e7 A 18.94
18.49
—j—i—i—i 111 ir |11
18.0
A
A A
4.09ei
18.46
3.Q9e8
3.0168
19.65
1.66e8
20.00
19.0
20.0
i—|—i
21.0
3.16e7 2 60e7
21.32 21.82
1.08e8
22,11
A-
22.0
23 0
Abs. Int.
-1.07e8
•5.35e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
4o 5.42e3
17.81-23.26
0%-
18,0
9,3467„
18 75 5.04e7
1.90e7 A 18 94
18,49 /X
_£2x_
A 18.94
^v
3.96eS
19.46
2.99e8
2.92e8
19.65
162e8
20.00
19.0
20.0
,—i—<
21.0
3 06e7 2.73e7
21.32 21.62
T
i.04e8
22,11
_A_
22.0
3.27e8
22.85
1.88e8
23.0
Abs. Int.
-1,03e8
5.16e7
• O.OOeO
RT
Rel. Int.
100%-
Fn 3
268.0016
TrCB Std.
4o4.11e4
17.81-23.26
0%-
"y	'|	i""
18.0
"»		f		» t	-1*"-> — i i" |	"t—T"
19.0	20,0
l.82e6
20.83
	*i^i	
21.0
-1	1 I '!
22.0
23.0
Abs. Int.
-6.59e6
• 3.30e6
¦O.OOeO
RT
Rel. lr»t.
100%-
Fn 3
269.9986
TrCB Std.
4o 3.49e4
17 81-2326
Rel. Int
100%
Fn 3
292.9824
QC Check
17.81-23.261
18.0
2.23e7
19.44
i	r"*r	i^-'l—-1—nr-
19.0
¦—I—¦—•—'—•—I—'—r"
20.0
r1 1' ' i i » > | i »
21.0
22.0
—r-
Results: P:\P9400_P9499\P9464_6042 PCBVesources\P9464_6042_PCB_005Mtp_res. saved OS-Aug-2008 08:24 (EE)
AP UltraTmce-Pro W.993 User/System; EE/EEC2-038 cc: 1169, 1161
2,1067
22.83
Abs. Int.
-6,14e6
3.07e6
-O.OOeO
RT
Abs. Int.
2.96e7
1,48e7
O.OOeO
RT
Peak annotation Areas, Centmids
PKD OS-Aug-2008 08:24:18 Printed: 05-Aug-2008 08:31:36 Page 7 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-AGD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14 EQ
Rel, Int.
100%-
Fn2
289,9224
TeCB-2
4 o 1,65e3
13.02-17.79
0%-
Rel, Int.
100%
Fn 2
291.9194
TeCB-2
40 2.55e3
13.02-17.79 i
2.36e4
16.66
¦•"I	i |	ifti "1111" 'I"11-I i ~f pm ¦) PrTrryfr 		r i » i f
13.5
14.0
ITtf l*1T ' 'I ^ ' t '| 1 			 j 'f'
14.5	15.0	15.5
16.0
16.5
17,0
0%-
1.66e4
13.69
* fr-i 'rf ¦»
t "| "r*
13.5
-»~f
14.0
4 fi|ff pi f | ^-1, pn|ri| ij ri| i^nfi | | rfnt ; | | r|r t i
14.5	15-0	15.5
t |111 r *i i1 | i r^nr • n ? j1"1!111 <11 | ri
16.0	16.5	17.0
17.24
17.24
Abs. Int.
-1 09e5
•5.46e4
-O.OOeO
RT
Abs. Int.
-1.4285
-7.10e4
17.5
¦O.OOeO
RT
Rel, Int.
100%-
Fn 2
301.9626
TeCB Std.
4o 7.49e3
13,02-17.79
0%-
1.42e7
17.22
13.5
I1 1 I 1 \ I I I I ¦ I J I
14.0	14.5
15,0
•"1	1	1	|'""l	1	f	I	|	I""«	I	I	|	I""l	
15.5	16.0
'• 1 1 I 1
16.5
	[""¦»	1	1	1	)"
17.0
Abs. Int.
-2,28e6
•1.14e6
O.OOeO
17.5	RT
Rel. Int.
100%-
Fn 2
303.9597
TeCB Std.
4o 3 25e3
13.02-17.79
0%-
13.5
I [ I
14.0
I | I I I ¦ ( 9 I f I | ! I ! I | ¦ ! 1 I f I
14.5	15.0	15.5
¦	I	i	r
16.0	16.5
1,88e7
17.22
Abs. Int.
-3.17e6
-1,58e6
—i—i rt i i | i1" i—i i | i i i—i—|—*-- 0.OOeO
17,0	17.5	RT
Rel. Int.
100%-
Fn 2	I
242.9856 ¦
QC Check '
13.02-17.79
Abs. Int.
-2.99e7
-1.5067
0% i ¦ ¦ .
13.5
14.0
' I 1 1 '
14.5
mV "ft 1~»— 'i-f-'f
15.0
15.5
Results: P:\P9400_P9499\PS464_6042 PCB\resources\P9464_6O
-------
AP Lab ID; P9464_6042_PCB_005
Instr. AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_c!1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Ju1-2008 12:37:31
User: JLJ Datafile: 080724V14_EQ
Rel. Int.
100%-
Fn 3
289,9224
TeCB-3
40 1,47e3
17.81-23.26
0%-
18.0
1.81e7
1B.98
.yy.
19.0
2.14e7
19.51 8.44e6
19.81
¦iV

8.36e6
21.21
¦ ,
20.0
21.0
22.0
22 71 22 90
1.6288
21.86
1 .ones
3.93e7
21.60
z.3ie
2.85e7
22.13
23.0
Abs. Int.
-3.44e7
•1.72e7
¦O.OOeO
RT
Rel, Int.
100%-
Fn 3
291.9194
TeCB-3
4 a 1,86e3
17.81-23.26
0%-
1—I—1
18.0
2.33e7
18.98
A.
19.0
2.7 5e7
19.54 1.10e7
19.81
-CW
4V,
!.29e8
21.42
1.08e7
21.21
1 I6e81,j;0e8
20.0
21.0
22.0
22.90
2.Q8eo
5.D5e7
21.B6
2 98e
3.68e7
22.13
23.0
Abs. Int.
-4.46e7
•2,23e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
301.9626
TeCBStd.
4o 5.60e3
17.81-23.26
0%-
1—I—1
18.0
19.0
20.0
21.0
22.0
23.0
Abs. Int.
-3.29e6
• 1.65e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
303.9597
TeCB Std.
4o 3.05e3
17.81-23.26
0%-
18.0
19.0
20.0
21.0
22.0
23.0
Abs, Int.
-4.31e6
2.15e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
19.0
Abs. Int.
-2.96e7
1.48e7
O.OOeO
RT
Results: P:\P9400_P9499W9464 6042 PCB\msaurcesSP9464 6042 PCB_005.ulp_res, saved OS-Aug-2008 08:24 (EE)
AP Ultra Trace-Pro V3.993 UserfSyslem: EE/EEC2-038 cc: 4738, 5830
Peak annotation: Areas, Centmids
PKD: OS-Aug-2008 08:24:18 Printed: 05-Aug-2008 08:31:39 Page 9 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxl00_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14 EQ
Rel Int.
100%.
Fn 4
289.9224
TeCB-4
4o2.95e4
23.27-33.00
0%-
1.17e71.24e7
23.85 24.20
' I ^
24.0
2.99e7
24.55
r» /V i1
4.29e8
25.0
66e7
, i 5.47
.y).
2 12eB
25.88
26.06
2,Q7e8
28.98
26.0
27.0
527°687 3-58e7 2.97e7
28.13 28.51
¦ /	, |	i
28.0
Abs. Int.
-9.14e7
¦4.57e7
O.OOeO
29.0
30.0
I ¦ 1 1 ¦ I ¦ ' ' 1 I ' 1	I 1 1 i '
31.0	32.0	RT
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4o2.00e4
23.27-33 00
0%-
1 50e71.60e73,f5A7
23,85 24.20 ** 33
5.63e8
25.05
2.74e8
25.88
24.0

315167
6.71e7
27.68
-i—i
2,67e8
28.98
27,0
3.76e7 3,81e7
28.14 28.51
I i i *f\ i
28.0
29.0
30,0
Abs. Int.
-1.17e8
¦5.87e7
|*IIIJT»II|ITTI] 111 I ] I 1 » I— 0 OOeO
31 0	32.0	RT
Rel. Int.
100%-
Fn 4
301,9626
TeCBStd.
4a 5.40e3
23.27-33,00
0%-
24.0
S.46e5
26.40
1.78e7 *Ul(te7
28 50 28.96
.¦ Ie5
~i .06
f "
25,0
26.0
i i i t i i < i
] i i—iii)
27,0
28.0
r*r-
29,0
30.0
»¦ | * f ri | » i ? t | i
31,0	32.0
Abs, Int.
-4 48e6
•2.24e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std
4a 5.65e3
23.27-33.00
0%-
I I 1 1 I
24.0
25,0
26.0
5.88e5
26.38
i i-> ) i
2 19e7 229e7
28.50 28.97


27.0
28.0
29.0
1 I 1
30.0
¦ l '
31.0
»"' i i i i i '» | i—r-r-
32.0
Abs, Int.
-5.58e6
2.79e6
•O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-33.00
28,0
29.0
30.0
I ' •
31.0
Abs. Int.
-3,24e7
1 62e7
-O.OOeO
RT
Results: P:\P9400_Pgt99\P9464_6042 PCB\resources\P9464_6042_PCB_005. utp_res, saved 05-Aug-2008 08:24 (EE)
AP UttraTrace-Pm V3.993 User/System: EE/EEC2-038 cc 6015. 8076
Peak annotation: Areas, Centmids
PKO: 0S-Aug-2008 08:24:18 Printed: OS-Aug-2008 08:31:40 Page 10 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405._cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafiie: 080724V14_EQ
Ret. Int.
100%-
Fn 3
323,8834
PeCB-3
4o 1,75e3
17,81-23.26
0%-
—I—1
18.0
I I 1

2.1 Ie6

22.13
Ii
2.46e5

21.81
/ \
/\
/ \
19,0
20.0
21.0
22.0
'I 1
23.0
Abs. Int.
-S.36e5
¦2.68e5
•O.OOeO
RT
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
4o 1,82e3
17.81-23.26
0%-




3.3286
22,13
h


9,6504
20,16
5,58e5
1.89e5 21,03
2K7 A
1.57e6 I
21.54 1
\ 3.97e5 I 1
)[ Xv / \
, , , , . ,
18.0
19.0
20.0
21,0
22,0
I.72e5
22.36
-A-t

Abs. Int.
-8,54e5
¦4.27e5
23.0
O.OOeO
RT
Rel, Int.
100%-
Fn 3
337.9207
PeCBStd.
4o 3.0Se3
17.81-23,26
0%-
,—I—,
18.0
	I	|	I1	'I	«	I""
19.0
20.0
21.0
22.0
i * r f | i
23.0
Abs. Int.
-4.82e6
•2.41e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
339.9177
PeCB Std
4o 3.53e3
17.81-23.26
0%-i—i—p
18.0
i i r f | i
19.0
I I I
t f 1 T
—f	1 I
20.0
21.0
22.0
Abs. Int.
-3.09e6
•1.54e6
-j—i—r—O.OOeO
23,0 RT
Rel, Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6M2_PCB_00S.utp_m$, saved 05-Aug-2008 03 24 (,EE)
AP UttmTrace-Pm V3.995 User/Syslem EE/EEC2-038 ec; 8488, 4567
Abs. Int.
96e?
1.48e7
O.OOeO
RT
22.0	23.0
Peak annotation: Areas. Centroids
PKD: C5-Aug-2Q08 08 24:18 Printed: 05-Aug-2008 08:31:41 Page 11 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JU Datafile: 080724V14 EQ
Rel. Int.
100%-
Fn 4
323.8834
PeCB-4
4o 7.67e3
23.27-34.14
5.B6e7
24.32
24,0
1.60e7
25.04
2.68eS
27.66
1.28e8
28.43
1 Me 8
26.79
..B6e7
27.78 3.13
2.15e7
1.49e7
28 28 28,68
28.29
1.21e7
30.35.
1.25e8

30.92
8.7087
A
31.90
j 1.04e7
A
\ 31.21
\
~V > -T-O—

26.0
28.0
30.0
32.0
9.1186
33.13
j —*—r—i—f-
Abs. Int.
-5.12e7
¦2,56e7
•O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
325.8804
PeCB-4
4o 4.66e3
23,27-34.14
0%-
9.59e7
24.32
JL
24.0
2.62e7
25.04
. p O
5.69e8
27.65
1.74e8
26.79
2.44e7
26.29
W™ 5,08^,3 4767
'- 28.2? \ 28.69
2.02e8
30,92
26.0
28,0
30.0
1.92e7
1.75e7
30.35
1,40e8
31,90
—1
32.0
1.55e7
33.14
Abs. Int.
-1.11e8
•5.54e7
i t O.OOeO
34,0 RT
Rel. Int.
100%-
Fn 4
337.9207
PeCBStd.
4a 5.38e3
23,27-34.14
Q%-
1,78e7
26.77
6.57e5
27.40
2.49e7
29.00
5.32i
28.
I	|	1	»	t	"I""
24.0
2.06e7 23i4!,7 2.15e7
30.63 ,
26.0
28.0
30,0
A
31.88
Abs. Int.
-5 96e6
2J8e6
-t—|-		i i—i—r—|—O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
339.9177
PeCBStd.
4o 5.23e3
23.27-34.14
0%-
24,0
8,40e5
25.86
i—<£s~T-
1.15e7
26.77
1.13e6
27.40
/v
1.59e7
29.00
1.28fq
28
1.31«7 1,35e7 1.35e7
30 63 31.35 31.88
26.0
28.0
I I | I
30.0
U
Abs. Int.
-3,74e6
•1.87e6
•O.OOeO
i—i-
34.0 RT
Rel. Int.
100%
Fn 4
330,9792
QC Check
23.27-34.14
Abs. Int.
3.24e7
1.62e7
7	'	r—-i	1 ' 0. Q0#0
34.0 RT
Results: P:\P9400_P9499\P9464_6042 PC8^esoumes\P9464_6042_PCB_005Mtp_nes, saved 0S-Aug-200B 08:24 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 4520. 3017
Peak annotation: Areas. Centmids
PKD OS-Aug-2008 08:24:18 Printed: 05-Aug-2008 08:31:42 Page 12 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr; AutoSpee-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User. JLJ Datafile: 080724V14_EQ
Rel. Int.
100%-
Fn 5
323,8834
PeCB-5
4o8.02e4
34.18-41,15
0%-
35,0
1,11e9
36.78
.
9.07a?
5.85e8
39,17
36.0
37.0
38.0
39.0
40.0
T
Abs. Int.
-2.88e9
¦ 1,44e9
l.OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
325,8804
PeCB-5
4o1.31e5
34 16-41.15
0%-
35.0
-i—l—i—i—r
36.o'
2.58e9
36.78
iiii
37.0
7.69B9
4,02e8 39^
38,76
i — iOr » | r r* i i
38.0
IsTo
' I '
40.0
Abs. Int.
-2.88e9
1.44e9
i i r i i I i * 0.00e0
41.0 RT
Rel. Int.
100%-]
2 28e?
34.45


Abs. Int.
-5.23e6
Fn 5 :
337.9207 •
PeCB Std, J
4a 1,06e4 .
34 16-41 15 ¦



1.13e7
38.14
A
-2.62e6
Q%-
, .
\	


-O.OOeO
35.0
36.0
37.0
38.0
39.0
40.0
41.0 RT
Rel, Int.
100%-
Fn 5
339.9177
PeCB Std.
4o 1.01e4
34.16-41.15
0%-
1.44e7
34.45
1*^1
35.0
2.45e
38, f
360
I 1	1 I "I
37.0
38.0
39,0
* l ' ' ' ' I
40.0
Abs. Int.
-3 32e6
1,66e6
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454,9728
QC Check
34.16-41.15'
0%-
35.0
36.0
37.0
38.0
390
40.0
Abs. Int.
-1.63e7
•8.l3e6
-O.OOeO
r
41.0 RT
Results: P.\P9400_P9499\P9464_6042 PCBtesovrces\P9464_6042_PCB_005utp_res. saved OS-Aug-2008 08:24 (EE)
AP UttraTraee-Pm V3.993 User/System: EE/EEC2-038 cc: 4191. 5214
Peak annotation: Areas, Centroids
PKD: 05-Aug-2008 03:24:18 Printed: 05-Aug-2008 08 31 43 Page 13 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpee-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-JuI-20Q8 12:37:31
User: JLJ Datafile: 080724V14 EQ
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4o 2.28e3
23 27-34 14
0%-
24.0
26.0
1,64e7
27.20
. A .
6.82e7
29.96
i|	3.01 e7
2.94e7	31,01
29.21 7,34e6 M.53e6 3 62e6
A „ 29/7 j>.H jolf

A.
1.02e8
32.48
2.18e7
31 96 9-1246
^32,
33.02
1.14eB
33.52
De7
JB.13
1125#7
3.27
28.0
30.0
32.0
Abs, Int.
-2.89e7
• 1,45e7
¦O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4o 2.06e3
23.27-34.14
0%-
TT~—7	1 1
24,0
I I I
f | I ~ I *
26.0
1.39e7
27.20
rik-
2.32e7
28.0
29 21 6 04e6 iaoeS 3.12e6
A Al14 30.64
| '• ^ f» Al' |V>	
2.41 e7
31.01
A
8.32e7
32.47
1.12e8
33.02
9.06e7
33.52
1.75e7
115867
2.64
31.96
Abs. Int.
-2.23e7
•1,12e7
• O.OOeO
30.0
32.0
34.0 RT
Rel. Int.
100%-
Fn 4
371.8817
HxCB Std.
4 o 2,34e3
23.27-34.14
0%-
1.88e7
26.57
"T		|	r;--..y.-.'«Y	n	j	|	r,.
24,0 '
26.0
	»'		1	|	I
28.0
|lfll|fll
30.0
1.59e7
32.45
32.0
1.46e7
33.49
Abs. Int.
-4,45e6
•2.22e6
•O.OOeO
1—r
340 RT
Rel, Int.
100%-
Fn 4
373.8788
HxCB Std.
4o 3.01 e3
23.27-34.14 ¦
0%-
I 1 1 | I I V
24.0
1.49e7
26.67
-|	!	1	1	1	1 I I ' I "
26.0
28.0
30.0
1,22e7
32.45
32.0
Abs. Int.
-3.46e6
•1.73e6
¦O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14 .
24,0
26.0
28.0
30.0
Results: P:\P9400__P9499\P9464_6042 PCB\m$OunceS\P9464_6042_PCB_00$.utp_ms, saved 05-Aug 2008 08:24 (EE)
AP UltraTrace-Pro V3 993 User/System EE/EEC2-038 cc: 0141. 13S6
32.0
Abs, Int.
-3.24e7
1,62e7
T—- O.OOeO
34.0 RT
Peak annotation: Areas, Centnoids
PKD: 05-Aug-2008 08:24:18 Printed: 05-Aug-2QQB 08:31:45 Page 14 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14JEQ
Rel. Int.
100%-
Fn 5
359.8415
HxC8-5
4o2.63e4
34.16-41.15
0%-
1,60e7
34.57/
1.15e7
35.19
/\
7.01 e6
35.63
35.0
T
1,40e7
36.02
/V
4,26e7
36.97
A.
36.0
37.0
1.01e7 8.53e6
37.74 38.15
, T~i	 f i -rTT	
38.0
39,0
Aif?l 41267
39„24 39.63
/V\ ,(Y)
40.0
1,65e8
40.47
40.39
Abs, Int.
-3.37e7
1.68e7
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4o 2.05e4
34.16-41.15
0%-
1.29e7
34.57/
34.57A
-fidX
9 26e6
35.19
35.0
5.06e6
35.62
1.12e7
36.02
/\
3 52e7
36.97
A.
7.71e6 6.13e6
37.74 38.15
2.75e7
39.63
36.0
37.0
38.0

I—r
39.0
40.0
1.19e8
40.47
Abs, Int.
-2.46e7
1.23e7
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
371.8817
HxCBStd.
4o 1.02e4
34.16-41.15
0%-
35.0
2.85e6
38.14
36.0
37.0
38.0
39.0
1.7467
39.65
40.0
"¦¦r	y	y	v
Abs, int.
-6.13e6
•3.07e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
373.8788
HxCB Std
4o 7.69e3
34.16-41.15
0%-
35,0
2 83e7
36.96
36.0
37.0
2.56e6
38.14
38.0
39.0
40.0
Abs. Int.
-4.81e6
•2,40e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34,16-41.15
0%-
35.0
36,0
37,0
38.0
' I '
39.0
40.0
Abs. Int.
-1.63e7
8.13e6
		 O.OOeO
41.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resounxs\P9464_6042_PC8_00S.utp_fes. saved 05-Aug-2008 08:24 (EE)
AP Ulta Tmce-Pm V3.993 User/System: EE/EEC2-038 ce: 3912, 2518
Peak annotation: Areas, Cenlmids
PKD: 05-Aug-2008 08:24:18 Printed: 0S-Aug-2008 08:31:46 Pago IS of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_ct1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14_EQ
Rel. Int.
100%-
Fn 4
393.8025
HpCB-4
4o1.91e3
30.00-34.14
0%-
Rel. Int.
100%-
Fn 4
395.7995
HpCB-4
4a 1.55e3
30.00-34,14
0%-
7.74e5
30.61
3.09e5
30.93
8.6Be6
31.32
1.11e7
31.64
30.5
31.0
31.5
1.4Se6
30.61
I.78e7
31.32
i t i | Pi r i | I	I I' t | i \ 		I |i i
30.5	31.0	31.5
1.92e7
4,00efi
32.28
1,44ee
4.33e7
31.81
1.0567
31.64
33.0
8.47e6
-l—| -ll^t—r~|—r-H—i ¦ i |	
32.0	32.5
33.5
33,0
33.5
4.63e6
33.89
34,0
4.51e6
33.89
Abs. Int.
-4.25e6
2 13e6
, ¦ ,
-O.OOeO
RT
Abs. Int.
-1 ,02e7
5.08e6
34.0
¦O.OOeO
RT
Rel, Int.
100%-
Fn 4
405.8428
HpCB Std,
4o 1.80e3
30.00-34.14
0%-
1.03e6
30.69
~i—i—I—r—[—T—I—I—I—]—r—I	|—1—t—i- t ¦ |—r-
30.5	31.0
1.79e7
I f I %	I*""l	|	1""
31,5
—»-T i—r f » j »—» I » | I—i—P—P—J—1—i i '—J—r-
32 0	32.5	33.0
I 1 I 1 | » I
33.5
1.3ue7
33.87
Abs. Int.
-4.46e6
¦2,23e6
-O.OOeO
RT
Rel. Int.
100%-
Fri 4
407.8398
HpCB Std,
4o 3.58e3
30.00-34.14 •
0%-
I 1
30,5
1,38e6
30.69
1.76e7
31,33
1 J I I I I f I I I" I | I I 1 I | I I I I | I
31.0	31.5	32.0

32,5
33.0
t | % 1 » T |
33.5
1.23e7
33.87
34.0
Abs. Int.
-4.34e6
•2.17e6
•O.OOeO
RT
Rel. Int
100%-f
Fn 4
330.9792
QC Check
30.00-34.14
Results: P:\P94Q0__P9499SP9464_6042 PCBSresouFCB$'J3S464_6042_PC8_00$.utp_ms. saved 0S-Aug-2008 08:24 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 0272, 8170
Abs. Int.
-3.24e7
1.62e7
|--T" t *	—T	F—I	1 1 I I I | ! I O.OOeO
33.0	33.5	34.0 RT
Peak annotation: Areas. Centroids
PKD: 05-Aug-2008 08:24:18 Printed: 0S-Aug-2008 08:31:47 Paga 16 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# H-ACD-M23-1
VSIR expi: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 08Q724V14 EQ
Rel. Int.
100%-
Fn 5
393.8025
HpCB-5
4o 1.20e4
34,16-41.15 •
0%-
2.53e7
34.65
2.98e6
34.42
1.43e7
35.16
35.0
/WV
8.34©6
35,72
/\
8.99e6
36.24
5.4?e6
37.61
5.42e7
38.17
36,0
' 1 '
37.0

4.4406
38.43
38.0

31.0
2.12e?
39.18 a.17e6
39.62
4X-
A
T
40.0
Abs. Int.
-1,94e7
•9.68e6
¦O.OOeO
-r-f-
41.0 RT
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4a 1 23e4
34.16-41.15
0%-
2.40e7
34.65
2.86 e6
34.42
1,38e7
35.16
A	35.16
T., , /VA
7.95e6
35.72
.
8.67e6
36.24
tA,
35 0
36.0
5.32e6
37.61
5.24e7
38.17
37.0
38.0
4.00e6
38.43
vt i i ¦f*1
2.07e7
39. IS 8.10e6
39.62
-*x-
A
39.0
»f="i—|-S-
40.0
Abs. Int.
-1.94e7
•9.68e6
¦O.OOeO
"TTo RT
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std.
4o 6.11e3
34.16-41.15
0%-
35.0
36.0
37.0
2.21 e7
38.16
-r-T
38.0
	X
1.25e7
39.16
"1	1	*	>¦*"»	
39.0
" I » » 1 1 I
40.0
Abs. Int.
-7.59e6
•3.80e6
« % | i O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std..
4a 6.78e3
34.16-41.15
0%-
35.0
2.07e7
38.16
1.22e7
39.16
36.0
37.0
38,0
39.0
40.0
Abs. Int.
-7,08e6
3.54e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15'
0%-
35.0
36.0
37.0
-r—T-r
38.0
39.0
Results: P:\P9400__P9499\P9464_6042 PC8\msourcesSP9464_6042_PC8_005.utp_ms, saved 05-Aug-2008 08:24 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 5411, 3703
40.0
Abs. Int.
-1 63e7
8 13e6
41.0
•O.OOeO
RT
Pea* annotation: Areas, Centmids
PKD: 05-Aug-2008 03:24:18 Printed: 05-Aug-2008 08:31:48 Page 17 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14JEQ
Rel. Int.
100%-
Fn 6
393.8025
HpCB-6
4ct 8.46e3
41,17-46,41
1.02e6
41.34
e.36e6
42.0
3,9Qe5
42.79
43.0
3-81
4.44e6 , „ 43 g;
41 %7 2.7966
44.4Z 435?	X*
3.24e6
44.42
5.40e5
45.37
5.63e6
45.88
Abs. Int.
46 15 -2.66e6
1,33e6
44.0
45.0
46.0
O.OOeO
RT
Rel. Int.
100%-
Fn 6
395.7995
HpCB-6
4ct 9.99e3
41.17-46.41
9.03e5
41.33
8.68e6
2.97e5
42.18
4.11e5
42.79
4 24e6 , - 43.88
43.33 3;?5,e,6
3.20e6
44.40
1J81Abs. Int.
2.57e6
¦1.28e6

42.0
43.0
44.0
45.0
5.46e6
45.88
460
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
405.8428
HpCB Std.
4o8.17e3
41.17-46.41
0%-
1I 1
42.0
-i—i—i—|—i—i—i—i y
43.0
3.19e6
43.68
I I "*"1	 |	1 	 I	T"
44.0
"i—i—i—i—|—
45.0
i.i oe<
46.0
Abs. Int.
-3.90e6
1.95e6
-O.OOeO
RT
Rel. Int.
100%-
Fn 6
407.8396
HpCB Std.
4o 1.13e4
41.17-46.41
0%-
1.7067
42.0
43.0
1,24e6
43.68
	i	f^S ¦ ¦
4.31e6
45.31
44.0
45.0
46,0
Abs. Int.
-3.82e6
1 91e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41
0%-
42.0
'—I—
43.0
""r	i	r1"
44.0
45.0
Results: P:\P9400_P9499\P9464_6042 PCBte$ouKes\P9464_6042_PCB_005.utp_ms. saved Q5-Avg~200B 08:24 (EE)
AP UttraTrace-Pm V3 993 User/System: EE/EEC2-03S cc: 9933, 7803
46.0
Abs. Int.
-1.16e7
•5.80e6
•O.OOeO
RT
Peak annotation: Amas, Centmids
PKD: OS-Aug-2008 08:24:18 Printed: 05-Aug-2008 08 31:49 Page 18 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb040S_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14 JEQ
Rel. Int.
100%-
Fn 5
427.7635
OeCB-5
4a 3 62e3
34.16-41.15
0%-
?.72e5
34,35
2.63e5
^ 34
35,0
3.67e6
35.83

2.23e6
36.3:"
6.45e6
36.62

4.66eS
37.15
i r-v
3.38 e6
37.42
36.0
2.23e6
38.17
1.50e7
39,76
ft
37.0
38,0
I
39,0
9.51e6
40.30
40.0
Abs. Int.
-3.24e6
•1.62e6
•O.OOeO
r
41.0 RT
Rel. Int.
- 100%'
Fn 5
429.7606
OcCB-5
4o 3.85e3
34.16-41,15
1,27e8
34,34
-4X
2.40e6
34,92
|
35.0
6 9166
B.23e6
35.85
3.84e6
3.15e6
37.42
36.83
5.43e5
37.14


1.69e7


39.76
ft
1,88e6

II
38.18
,


I.08e7
40.30
Abs, Int.
-3.68e6
•1.84e6
•O.OOeO
36.0
37.0
38.0
39,0
40.0
41.0 RT
Rel, Int.
100%-
Fn 5
439.8038
OcCB Std.
4 o 3.48e3
34,16-41.15
0%-
3.42e6
34.69
JL
1.53e6
35,18
./> .
35.0
360
37.0
1.57e6
38.15
38.0
39.0
40.0
—i—|—i—i—i—r—j—*-*- O.OOeO
Abs. Int.
-3.30e6
1 65e6
41.0 RT
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std.
4o 3.52e3
34.16-41.15
0%-
5.37e6
34.69
2,56e6
35.19
1.66e7
35.80
A
LX
35.0
36.0
37.0
i.6ie6
38.15
38.0
39.0
40.0
Abs. Int.
-3.84e6
¦ 1.92e6
¦O.OOeO
41.0 RT
Rel. Int.
100%'
Fn 5
454.9728
QC Check
34.16-41.15'
0%'
35.0
36.0
¦	I	*"
37.0
38.0
39.0
Results: P:\P9400_P9499\P9464_6042 PCB\msaurtes\P$464_6042_PCB_00S.utp_re$, saved OS-Aug-2008 08:24 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 2468, 1225
40.0
'"1	T	T	T""
Abs. Int.
-1.63e7
8 13e6
41.0
•O.OOeO
RT
Peak annotation: Areas, Cenlmids
PKD: 0$-Aug-2008 08:24:18 Printed: 05-Aug-200B 08:31:50 Page 19 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Ron# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14_EQ
Rel. Int.
100%-,
Fn 6
427.7635
OcCB-6
4cr 2.95e3
41.17-46-41
0%-
4.01 eB
41.56
42.0
1.1667
43.52
2.18e6
43.89
JS,
5.31e5
45^7
43.0
44.0
45.0
46.0
Abs. Int.
-2.30e6
¦1.15e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
429.7606
OcCB-6
4o 3.07e3
41.17-46.41
0%-
4.44e6
41.56
42.0
43.0
1.28e7
43.52
2.36B6
43.89
-A.
6.2le5
45.37
/V
44.0
45.0
46.0
Abs. Int.
r2.55e6
1.28e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
439.8038
OcCB Std.
4o 3.89e3
41,17-46.41
0%-
42.0
1,23e7
43.87
I.i2e7
43.50
43.0
44.0
45.0
» 1 I | 1
46.0
Abs. Int.
-2.64e6
•1.32e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
441.8008
OcCB Std.
4o 5.02e3
41.17-46.41
0%-
42.0
1.34e7
43.87
1,22e7
43.50
1.27eS
4S.36
43.0
44.0
45.0
Abs. Int.
-2.85e6
• 1,43e6
T	1 f I | » I » P
46.0
¦O.OOeO
RT
Rel. Int.
100%
Fn 6
404.9760
QC Check
41.17-46.41
0%-
1—r-
42.0
I I I
43.0
44.0
45.0
I | T » I
46,0
Abs. Int.
-1.16e7
•5.80e6
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_005 utp_res. saved 0S-Aug-2008 08:24 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 7859, 6798
Peak annotation: Ames, Centroids
PKD: 05-Aug-2008 08:24:18 Printed: OS-Aug-2008 08:31:51 Page 20 of 22
-------
AP Lab ID: P9464_6042_PCB_005
tnstr: AutoSpec-Premier MM6
Sample ID; Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial; 63
Acq: 24-Jul-2008 12f37:31
User: JLJ Datafile: 080724V14_EQ
Rel. Int.
100%-
Fn 6
461.7245
NoCB
4a1.76e3
41.17-46.41
0%-
5.24e6
41.36
-A-
4.00e6
42.13
rA-
42.0
43.0
"'¥	t	!	|
44.0
1.4267
45.36
45.0
i		|
1—i—
46.0
Abs. Int.
-4.72e6
•2,36e6
¦O.OOeO
RT
Rel. Int.
100%-,
Fn 6
463.7216
NoCB
40 1,84e3
41.17-46.41
0%-
6,71 e6
41.38
S.16e6
42,13
42.0
I > > I
Till
43,0
44,0
45.0
46.0
Abs. Int.
-6.24e6
¦3.12e6
-i—(-O.OOeO
RT
Rel. Int.
100%-
Fn 6
473.7648
NoCB Std.
4a 2 84e3
41.17-46.41
0%-
42.0
8.53e6
45.35
43.0
T—¦"
r	>*¦
44.0
45.0
46.0
Abs. Int.
-3.78e6
1,89e6
4- O.OOeO
RT
Rel. Int.
100%-
Fn 6
475.7619
NoCB Std.
4o 1 83e3
41.17-46.41
0%-
1—I—'—•-
42.0
1.16e7
45,36
J_X-
43.0
44.0
45.0
46.0
Abs. Int.
- 5.03e6
¦2.51e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41,17-46,41'
0%-J-r
42,0
43.0
44.0
45.0
46.0
Abs. Int.
-1.16e7
¦ 5.80e6
•O.OOeO
RT
Results: P:SP9400_P9499\P9464_6042 PCB\resourcesW9464_6042_PCB_005.utp_res, saved 05-Aug-2008 08:24 (EE)
AP UltraTmce-Pm W.993 User/System: EE/EEC2-038 cc f550. 5898
Peak annotation: Areas. Centmids
PKD: OMug-2008 08:24:18 Printed: O^Aug-2008 08:31 S3 Page 21 of 22
-------
AP Lab ID: P9464_6042_PCB_005
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-1
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 63
Acq: 24-Jul-2008 12:37:31
User: JLJ Datafile: 080724V14 EQ
Rel. Int. 9JSe6
100%-
Fn 7
497.6826
DeCB
4o 1.82e3
46.42-54 01
0%-
46.66
3.59e5
47.25
. r~> ¦¦
47 0
48.0
49.0
50.0
51.0
-r—> 1 i i t [ > » i i | i i r i { »
52.0	53.0
Abs. Int.
-2.10e6
• 1.05e6
-f-O.OOeO
54.0 RT
Rel. Int,
100%-
Fn 7
499.6797
DeCB
4o 1.29e3
46.42-54.01
0%.
7.94e6
46,66
S.ISeS
47.25
470
48.0
49.0
50.0
51.0
52.0
53.0
Abs. Int.
-1.80e6
-9.01 e5
-O.OOeO
54.0 RT
Rel. Int.
100%-
Fn 7
509,7229
DeCB Std.
4o 1,84e3
46,42-5401
0%-
1,27e7
46.64
A
LX
47.0
48.0
¦H"
49.0
50.0
1.49e6
^ 50^6^
51.0
52.0
53.0
Abs. Int.
-2.88e6
¦ 1.44e6
-O.OOeO
54.0 RT
Rel. Int.
100%-
Fn 7
511.7199
DeCB Std.
4o 3.34e3
46.42-54.01
0%
3.38e5
47,18
47.0
48.0
49.0
50.0
1 I3e6
50.47
51.0
52.0
53.0
Abs. Int.
-2.40e6
•1.20e6
•O.OOeO
54.0 RT
54.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resaurces\P9464_6042_PCB_005,utp_ms. saved OS-Aug-2008 08:24 (EE)
AP UttraTrace-Pm V3.993 UserTsyslem: EE/EEC2-038 cc: $869, 7937
Peak annotation: Areas. Centmkts
PKD: 05-Aug-2008 08:24:18 Printed: OS-Aug-2008 08:31:54 Page 22 of 22
-------
Datafile: Q80802R01_EQ
Acquired; 02 Aug 2008 00:22:22
Client ID: Run# II-ACD-M23-2
Lab ID: P9464 6042 PCB 006RJ-D10
Wt/Vol: 1 -
A-level: 20 pg
V *
-IN

BCS3 6042 PCB RCD CPSM 080801 PCB RB
—i —			 " ¦ P	—	~		
Nominal ES spike: 4000 pg
P9464_6042_PCB_006RJ-D10
Name
PCB-77 3 3'4 4'-TeCB
PCB-81 34415-TeCB
PCB-105 233'44'-PeCB
PCB-114 2344'5-PeCB
PCB-110 23'44'5~PeCB
PCB-123 2'344'5-PeCB
PCB-126 33'44"5-PeCB
PGB-156/157 233'44 * 5/233'44'5'
FGB-167 231441551-HxCB
PCB-169 33'44'55'-HxCB
PCB-189 233'44'55'-HpCB
PCB-209 DeCB
Actual
KT
31.82"^
31.34 /
34.79/
34.25/.
33.79
33
37
39
38
42
44
49
/
52 ^
39/
92^"
96 /
63 /
77 / /
74
QC
Prod
HRT
1
0006
1
0006
1
0007
1
0007
1
0007
1
0007
1
0005
1
0005
1
0006
1
0005
1
0004
1
0004
Actual
RHT
1.0005
1.0005
1.0006
1.0005
0007
0010
0005
0002
0006
0001
0004
0004
Diff

Checkcode;

Sees
Response
Ra
RRF /
Cone
Noise
DL
-0.2
1.94S+08
0.78
%J
0.98
55,300
4.021+04
119
CM
O
1
3.48E+07
0.77
1.03
11,100
4.02E+04
138
-0.2
2.29E+08 •
0.63
0.90
79,400
2.18E+05
785
I
O
2.19E+07
0.58
0.90
7,610
2.18E+05
782
0
5.15E+Q8
0.62
0.90
173,000
2,18E+05
727
KD
O
+
1.60E+07
0.59
0.91
5,850
2.18E+05
819
0
8.06E+07
0.63
0.90
27,400
1.66E+05
586
-0.7
1.04E+08
1.23
0.97
40,200
3.75E+04
208
0
3.20E+07
1.26
0.99
12,600
3.75E+04
151
-1.0
2.54E+07
1.24
0.93
l/o, 500CA&*3 .75E+04
168
0
8.74E+06
1.02
0.84
3,920
1.32E+04
62.6
0
5.75E+06
1.15
0.91
3, 040
1.39E+03
8.19
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PC3-
PCB-
£>GB-
PCB-
PCB-
PCB-
FCB-
PCB-
PCB-
PCB-
PCB-
PCB-
PCB-
-1
-3
-4
-15
-19
-37
¦54
-77
-81
¦104
•105
¦114
¦118
¦123
¦126
•153
•155
¦156/157
•167
¦169
170
180
188
189
202
205
206
208
209
11
29
~
13
49
~
13
86

19
30
*
16
72
**
25
52 ^
19
60^
31
80
s
31
33
s
24
46

34
77

34
23
~
33
77
-
33
49
¦S
37
37
~
35
35
~
29-
37

39
91

38
94

42
62

41
08
«*
42
13

34
23
S
44
75
S
38
75
S-
46
91
S
48
37
S
44
36
s
49
72







/
Recv.


0.7213
0
7210
-0.2
1.85E+07
3.04
1.06
114 %
25%
150%
0.8616
0
8620
+0.3
1.84E+07
I 2.49
1.00
120 %
25%
150%
0.8771
0
8852
+6.7
6.25E+06
1.55
0.77
52.4 %
25%
150%
1.2330
1
2331
+0.1
1.67E+07
1.60
0.94
115 %
25%
150%
1.0684
1
0682
-0.2
1.09E+07
1.06
0.67
106 %
25%
150%
1.0809
1
0807
-0.3
1.37E+07
1.08
0.99
115 %
25%
150%
0.8279
0
8300
+2.5
1.18E+07
0.77
1.00
97.9 %
25%
150%
1.3474
1
3467
-1.3
1.43E+07
0.81
0.88
134 %
25%
150%
1.3274
1
3266
-1.5
1.21E+07
0.79
0.84
120 %
25%
150%
0.8277
0
8279
+0.3
1.25E+07
1.64
1.28
93 %
25%
150%
1.1769
1
1766
-0.6
1.28E+07
1.53
1.19
102 %
25%
150%
1.1587
1
1584
-0.6
1.28E+07
1.52
1.17
104 %
25%
150%
1.1432
1
1429
-0.6
1.321+07
1.57
1.23
102 %
25%
150%
1.1338
1
1334
-0.8
1.21E+07
1.56
1.13
102 %
25%
150%
1.2652
1
2648
-0.9
1.30E+07
1.60
1.20
103 %
25%
150%
0.9711
0
9711
0
1.11E+07
1.26
1.15
106 %
25%
150%
0.8067
0
8069
+0.4
1.39E+07
1.35
1.47
105 %
25%
150%
1.0964
1
0963
-0.2
2.13E+07
1.26
1.31
89.7 %
25%
150%
1.0696
1
0695
-0.2
1,03E+07
1.27
1.25
91.8 %
25%
150%
1.1709
1
.1708
-0.3
1.05E+07
1.25
1.33
87.2 %
25%
150%
0.8833
0
.8832
-0.2
1.09E+07
1.07
1.13
135 %
25%
150%
0.9060
0
9060
0
8.12E+06
1.06
0.91
125 %
25%
150%
0.7359
0
7359
0
1.18E+07
1.04
1.18
110 %
25%
150%
0.9621
0
9621
0
1.07E+07
1.04
1.30
115 %
25%
150%
0.8332
0
8331
-0.2
1.03E+07
0.92
1.20
95 %
25%
150%
1.0086
1
0086
0
8.91E+Q6
0.93
1.11
112 %
25%
150%
1.0400
1
0400
0
6.45E+06
0.80
0.79
114 %
25%
150%
0.9539
0
9538
-0.3
8.70E+06
0.81
1.07
113 %
25%
150%
1.0692
1
0691
-0.3
8.33E+06
1.21
1.06
110 %
25%
150%
Analytical Perspectives
Page 1 of 5
Printed: 08 06 2008 1:22 PM
-------
F9464_6042_PCB_006RJ-D10
Name
SS PCB-28
SS PCB-111
SS PCB-178
Actual
ET
22-01 x
31.83 ~
36.78
QC
Pred
RET
0.9320
1.0774
1.0105
CS PCB-28
CS PCB-111
CS PCB-178
22.01,
31.83.
36.78 '
0.9320
1.0774
1.0105
JS	PCB-9
JS	FCB-52
JS	PCB-101
JS	PCB-138
JS	PCB-194
15.65/—
23.61-'
29.55 *"
36.41
46.51-'

PCB-l 2-MoCB
PCS-2 3-MoCB
PCB-3 4-MoCB
PCB-4 22'-DiCB
PCB-10 26-DiCB
PCB-9 25-DiCB
PCB-7 24-DiCB
PCB-6 23'-DiCB
PCB-5 23-DiCB
PCB-8 24'-DiCB
PCB-14 35-DiCB
PCB-11 33'-DiCB
PCB-13/12 34'-/34-DiCB
PCB-15 44'-DiCB
PCB-19 22•6-TiCB
PCB-30/18 246-/22'5-TrCB
PCB-17 22'4-TrCB
PCB-27 2316-TrCB
PCB-24 236-TrCB
PCB-l6 22'3-TrCB
11.30
13.33
13.51
13.86
13.98
15.67
15.82
16.05
16.35
16.46
17.97
18.75
19.04
19.32
16.74
l'B.47
18.86
19.05
19.17
19 .27
1.0011
0.9879
1.0010
1.0011
1.0138
1.0010
1.0113
1.0254
1.0441
1.0516
0.9319
0.9715
0.9863
1.0008
1.0011
1.1044
1.1279
1.1393
1.1471
1.1527
Analytical Perspectives
Actual
RRT
0.9321
1.0772
1.0104
0.9321
1.0772
1.0104
Diff
Sees
+0.1
-0.4
+0.1
-0.4
-0.2
Response
1.55E+07
1.54E+07
7.75E+06
1.55E+Q7
1.54E+07
7.75E+06
Ra
1.05
1.55
1.02
1.05
1.55
1.02
EKF ^
1.07
1.18
0.66
1.05
1.33
0.78
J
Cose
107	%
108	%
99.1 %
123 %
110 %
109	%
Checkcode:
Noise
30%
30%
30%
30%
3 0%
30%
ecu
DL
135%
135%
135%
135%
135%
135%


1.54E+07
1.60






1.20E+07
0.80






1.05E+07
1.57






9.05E+06
1.26






7.16E+06
0.89





Totals
NON-EMPC

EMPC
DL



Mono-CBs
878,000

878,000
28.2



Di-CBs
462,000

462,000
39.3



Tri-CBs
448,000

448,000
51.2



Tetra-CB;
553,000

567,000
63.1



Penta-CB;
1,260,000
1
290,000
636



Hexa-CBs
912,000

912,000
141



Hepta-CB:
228,000

228,000
131



Octa-CBs
63,200

63,200
31



Nona-CBs
8,980

8,980
43.5
/


1.0011
0
8.18E+08
3.13
1.09 \J
163,000
1.67E+04
21.9
0.9878
-0.1
1.92E+09
3.09
1.01
414,000
1.67E+04
37.4
1.0011
+ 0.1
1.52E+09
3.10
1.09
301,000
1.67E+04
34.5
1.0005
-0.5
1.41E+07
SI *
0.98
9,200
9.25E+03
33.5
1.0086
-4.4
1.24E+07
SI*
1.55
5,130
9.25E+03
21.2
1.0010
0
5.07E+07
si •
0.94
12,800
1.64E+04
43.9
1.0108
-0.5
6.69E+07
SI*
0.90
17,700
1.64E+04
45.8
1.0252
-0.2
8.77E+07
SI*
0. 89
23.400
1.64E+04
46.3
1.0442
+ 0.1
1.11E+08
SI*
0.87
30, 400
1.64E+04
47.4
1.0515
-0-1
1.02E+08
SI*
0. 91
26,600
1.64E+04
45.3
0.9312
-0.8
1.02E+08
SI*
1.02
24,100
1.64E+04
40.7
0.9713
-0-2
2.57E+08
SI*
0.87
70,900
1.64E+04
47 . 8
0.9864
+0.1
7.30E+08
SI*
0.85
206,000
1.64E+Q4
48.8
1.0009
+0.1
1.37E+0S
SI*
0.92
35,700
1.64E+04
45.2
1.0010
-0.1
6.65E+06
1.04
0.91
2, 680
5.60E+03
18.7
1.1046
+ 0.2
6.47E+07
1.02
1.03
23,000
5.60E+03
16.5
1.1277
-0.2
3.19E+07
1.01
0.89
13,200
5.60E+03
19.2
1.1390
-0.3
1.04E+07
1.03
1.22
3,120
5.60E+03
13.9
1.1466
-0.6
1.07E+07
1.05
1.20
3, 270
5.60E+03
14.1
1.1523
-0.5
3.OOE+07
1.05
0.69
16,000
5.60E+03
24.7
Page 2 of 5
Printed: 08 06 2008 1:22 PM
-------
P94 64_S042_PC1_0 06IW - D10
Name
Actual
RT
QC
Fred
RRT
PCB-32
24'6-TrCB
19
.77
1
.1009
PCB-34
2'35-TrCB
20
.87
0
8174
PCB-23
235-TrCB
21
.01
0
8231
PC3-2G/29 23'5-/245-TrCB
21
29
0
8341
PCB-25
23'4-TrCB
21
49
0
8417
PCB-31
24•5-TrCB
21
76
0
8525
PCB-28/20 244'-/233'-TrCB
22
04
0
8634
PCB-21/33 234-/2'34-TrCB
22
22
0
8703
PCB-22
234'-TrCB
22
59
0
8848
PCB-36
3315-TrCB
23
96
0
9386
PCB-39
34'5-TrCB
24
27
0
9510
PCB-38
345-TrCB
24
79
0
9715
PCB-35
33'4-TrCB
25
18
0
9868
PCB-37
344'-TrCB
25
54
1
0007
PCB-54
22166¦-TeCB
19
62
1
0010
PCB-50/53 22'46-/22'56'TeCB
21
52
0
9119
PCB-45
22136-TeCB
22
11
0
9362
PCB-51
22'46'-TeCB
22
19
0
9393
PCB-46
22136'-TeCB
22
39
0
9481
PCB-52
22'55'-TeCB
23
64
1
0010
PCB-73
23¦5'6TeCB
23
77
1
0065
PCB-43
22135-TeCB
23
85
1
0103
PCB-69/49 23'46-/22'45'TeCB
24
07
1
0185
PCB-48
22'45-TeCB
24
33
1
0303
PCB-44/47/65 22¦35'-/22'44¦-
24
52
1
0393
PCB-59/62/75 233'6-/2346-/24
24
80
1
0510
PCB-42
22'34'-TeCB
24
98
1
0578
PCB-41
22'34-TeCB
25
30
' 1
0717
PCB-71/40 23'4'6/22'33'-TeCB
25
40
1
0758
PCB-64
234'6-TeCB
25
60
1
0841
PCB-72
23'55'-TeCB
26
32
0
8397
PCB-68
23'45'-TeCB
26
57
0
8478
PCB-57
233'S-TeCB
26
93
0
8595
PCB-58
233"5'-TeCB
27
13
0
8659
PCB-67
23'45-TeCB
27
29
0
8709
PCB-63
23415-TeCB
27
51
0
8780
PCB-61/70/74/76 2345-/23'4'5
27
80
0
8872
PCB-66
23'44'-TeCB
28
08
0
8961
PCB-55
233'4-TeCB
28
22
0
9007
PCB-56
233'41-TeCB
28
65
0
9145
PCB-6D
2344'-TeCB
28
84
0
9206
PCB-8Q
33'55'-TeCB
29
18
0
9314
PGB-79
33'45'-TeCB
30
49
0
9732
PCB-78
33'45-TeCB
30
96
0
9886
PCB-104
22'466'-PeCB
Not
Fnd
1
0009
PCB-96
22'366'-PeCB
24
80
1
0136
PCB-103
22'45'6-PeCB
26
48
0
8961
Analytical Perspectives
Actual Diff

RRT
Sees
Response
Ra
RRT
1
.1822
+ 1.5
2
72E+Q7
1.05
1.28
0
.8177
+0.4
1
32E+07
1.04
1.13
0
.8234
+0.4
2
58E+07
1.04
1.06
0
.8342
+ 0.1
8
90E+07
1.04
1.13
0
8419
+0.3
4
62E+07
1.05
1.25
0
8528
+ 0.4
1
16E+08
1.04
1.16
0
8635
+ 0.1
1
88E+08
1.04
1.13
0
8709
+ 0.8
1
72E+08
1.05
1.10
0
8851
+0.4
7
76E+07
1.06
1.09
0
9388
+0.3
4
54E+07
1.07
1.14
0
9511
+0.1
3
76E+07
1.06
1.12
0
9716
+0.1
1
13E+08
1.05
1.04
0
9868
0
2
31E+08
1.05
1.04
1
0007
0
2
37E+08
1.03
0.96
1
0012
+0.2
5
63E+05
0.75
1.18
0
9112
-0.9
1
49E+07
0.77
0.93
0
9364
+0.3
1
44E+07
0.78
0.71
0
9395
+0.3
6
69E+06
0.76
1.00
0
9480
-0.1
5
61E+06
0.77
0.73
1
0010
0
1
78E+08
0.77
0.91
1
0066
+0.1
1
49E+06
0.77
1.17
1
0102
-0.1
6
55E+06
0.77
0.71
1
0192
+1.0
7
34E+07
0.77
1 .05
1
0302
-0.1
2
40E+07
0.76
0.86
1
0382
-1.6
1
22E+08
0.77
0.92
1
0503
-1.0
2
85E+07
0.76
1.19
1
0577
-0.1
2
65E+07
0.76
0.80
1
0714
-0.5
1
37E+07
0.75
0.73
1
0755
-0.5
5
25E+07
0.77
0.93
1
0839
-0.3
5
65E+07
0.76
1.24
0
8401
+0.6
8
08E+06
0.79
1.05
0
8481
+0.5
1
41E+07
0.77
1.09
0
8597
+0.3
1
62E+07
0.75
1.01
0
8662
+0.5
1
24E+07
0.78
0.99
0
8711
+0.3
3
53E+07
0.77
1.09
0
8783
+0.5
1
57E+07
0.79
1.07
0
8875
+0.5
3
43E+08
0.78
1.02
0
8964
+0.5
1
31E+08
0.78
1.03
0
9008
+0.2
2
74E+07
0.78
0.94
0
9146
+0.2
1
11E+08
0.78
1. 01
0
9206
0
4
21E+07
0.78
1.00
0
9315
+ 0.2
8
44E+06
0.77
1,08
0
9732
0
6
81E+07
0.78
1.13
0
9882
-0.7
4
09E+07
B8IHI
0.94

-

0
00E+00

1.06
1
0136
0
4
32E+06
0.61
0.89
0
8962
+ 0.2
2
67E+06
0.54
0.76
Page 3 of 5

Checkcode:
ecu^
Cone

Noise
DL
7,800
5
60E+03
13.3
3,440
2
74E+04
71.3
7,120
2
74E+04
75.7
23,000
2
74E+04
70.9
10,800
2
74E+04
64.3
29,300
2
74E+04
69.3
48,300
2
74E+04
70.8
45,500
2
74E+04
72.7
20,700
2
74E+04
73.3
11,600
2
74E+04
70.2
9, 840
2
74E+04
71.9
31,700
2
74E+04
77 .3
65,100
2
74E+04
77.5
72,300
2
74E+04
83.7
162
3
58E+03
10.7
5,310
6
24E+03
23.9
6,670
6
24E+03
31
2,200
6
24E+03
22
2, 520
6
24E+03
30.1
64,600
6
24E+03
24.3
420
6
24E+03
18.9
3,040
6
24E+03
31.1
23,100
6
24E+03
21.1
9,200
6
24E+03
25.7
43,500
6
24E+03
23.9
7,930
6
24E+03
18.7
10,900
6
24E+03
27.6
6,150
6
24E+03
30.2
18,600
6
24E+03
23.7
15,100
6
24E+Q3
17.9
2,550
4
02E+04
136
4,270
4
02E+04
131
5,280
4
02E+04
140
4, 130
4
02E+04
143
10,700
4
02E+04
131
4,830
4
02E+04
133
111,000
4
02E+04
140
42,000
4
02E+04
138
9,650
4
02E+04
152
36,300
4
02E+04
141
13,900
4
02E+04
143
2,580
4
02E+04
132
19,900
4
02E+04
126
14,400
4
02E+04
152

3
95E+04
119
1,540
3
95E+04
140
1,160
2
18E+05
971
Printed: 08 06 2008 1:22 PM
-------
P3464_6042_PCB_006RJ-D10
Actual

Pred
Actual
Name
ET
QC
RRT
RRT
PCB-94 22'356'-PeCB
26.66

0.9024
0.9024
PCB-95 22'35'6-PeCB
27.04

0.9151
0.9152
PCB-100/93 22'44'6-/22'356-P
27.25

0.9224
0.9223
PCB-102 22'456--PeCB
27.37

0.9262
0.9263
PCB-98 22'3'46-PeCB
NO I rllll

0.9284
-
PCB-88 22'346-PeCB
NotFnd

0.9385
-
PCB-91 22'34'6-PeCB
27.79

0.9407
0.9405
PCB-84 22'33'6-PeCB
27.98

0.9469
0.9469
PCB-89 22'346'-PeCB
28.40

0.9610
0.9611
PCB-121 2 3'4 5'6 -PeCB
NotFnd

0.9730
-
PCS-92 22'355'-PeCB
29 .06

0.9837
0.9836
PCB-113/90/101 233'5'6~/22'3
29.57

0.9999
1.0008
PCB-B3 22'33'5-PeCB
29.96

1.0143
1.0141
PCB-99 22'44'5-PeCB
30.07

1.0176
1.0176
PCB-112 233'56-PeCB
NotFnd

1.0211
-
PCB-108/119786/97/125/87 233
30.53

1.0328
1.0331
PCB-117 234'56-PeCB
31.03

1:0506
1.0503
PCB-116/85 23456-/22'344'-Pe
31.11

1.0536
1.0530
PCB-110 233'4'6-PeCB
31.25

1.0577
1.0576
PCB-115 2344'6-PeCB
NotFnd

1.0605
-
PCB-82 22'33'4-PeCB
31.52

1.0671
1.0668
PCB-111 233'551-PeCB
31.85

1.0782
1.0779
PCB-120 23'455'-PeCB
32.25

1.0915
1.0913
PCB-107/124 233'4'5-/2'3455'
33.21

0.9913
0.9915
PCB-109 233'46-PeCB
33.41

0.9976
0.9977
PCB-106 23 3'45-PeCB
33.62

1.0039
1.0038
PCB-122 2'33'45-PeCB
34. 08

1.0093
1.0092
PCB-127 33'455'-PeCB
36. 03

1.0363
1.0364
PCB-155 22'44"66"-HxCB
NotFnd

1.0007
-
PCB-152 22'3566'-HxCB
29. 55

1.0060
1.0060
PCB-150 22'34'66'-HxCB
29.70

1.0109
1.0110
PCB-136 22'33*66'-HxCB
29.99

1.0210
1.0211
PCB-145 22'3466'HxCB
NotFnd

1.0302
-
PCB-148 22'34'56'-HxCB
31.55

1.0738
1.0741
PCB-151/135 22'355'6-/22"33"
32.05

1.0913
1.0910
PCB-154 22'44'5'6-HxCB
32.26

1.0985
1.0983
PCB-144 22'345'6-HxCB
32.52

1.1073
1.1071
PCB-147/149 22'34'56-/22*34"
32.82

1.1175
1.1172
PCB-134 22'33'56-HxCB
32.99

1.1234
1.1231
PCB-143 22'3456'-HxCB
33.09

1.1262
1.1265
PCB-i39/140 22'344'6-/22'344'
33.33

1.1351
1.1348
PCB-131 22'33'46-HxCB
33.51

1.1408
1.1406
PCB-142 22'3456-HxCB
NotFnd

1.1456
-
PCB-132 22'33'46'-HxCB
33.88

1.1537
1.1535
PCB-133 22'33'55'-HxCB
34.30

1.1679
1.1677
PCB-165 233'55'6-HxCB
34.66

0.9514
Q.9520
PCB-146 22'34'55'-HxCB
34.85

0.9573
0.9573
Analytical Perspectives
Page 4 of 5
Diff





Checkcode:
£Q> '
Sees
Response
Ra
RET
Cone
Noise
DL
0
2 .01E+06
0. 56
0
65
1, 020
2.18E+05
1,130
+ 0.2
2.55E+08
0.62
0
71
119,000
2.18E+05
1,050
-0.2
3.60E+06
0.65
0
74
1,610
2.18E+05
1,000
+ 0.2
1.04E+07
0.63
0
74
4,670
2.18E+05
1, 010

0.00E+00

0
64

2.18E+05
1,150

0.00E+00

0
72

2.18E+05
1,030
-0.3
3 .93E+07
0.61
0
66
19,800
2.18E+05
1,120
0
7.88E+07
0.62
0
60
43,400
2.18E+05
1,230
+ 0.2
3 .82E+06
0.60
0
64
1, 970
2.18E+05
1,150

0.00E+00

0
95

2.18E+05
777
-0.2
6.24E+07
0.62
0
69
30,000
2.18E+05
1, 070
+1.6
4.22E+08
0.62
0
79
176,000
2.18E+05
935
-0.4
4.37E+07

0
53
27,300
2.18E+05
1,400
0
1.4 0E+08
0.60
0
80
57,600
2.18E+05
921

0.00E+00

0
93

2.18E+05
793
+0.5
4.63E+08
0.55
0
79
193,000
2.18E+05
933
-0.6
9.44E+06
0.58
0
87
3,580
2.18E+05
849
-1.1
5,68E+07
0.61
0
78
24,000
2.18E+05
945
-0.2
5.57E+08
0.61
0
89
208,000
2.18E+05
837

0.00E+00

0
96

2.18E+05
776
-0.6
4.51E+07
0.61
0
56
26,600
2.18E+05
1,320
-0.6
4.89E+06
0.61
0
95
1, 710
2.18E+05
782
-0.4
7.56E+06
0.56
0
96
2, 610
2.18E+05
772
+0.4
3.21E+07
0.61
0
93
11,500
2.18E+05
799
+0.2
5.46E+07
0.62
0
99
18, 300
2.18E+05
750
-0.2
1.34E+07
0.57
0
91
4, 910
2.18E+05
819
-0.2
2.91E+07
0.61
0
84
10,800
2.18E+05
838
+0.2
1.60E+07
0.58
0
88
5,720
2.18E+05
805

O.OOE+OO

1
04

1.23E+04
35
0
1.65E+06
1.39
0
98
484
1.23E+04
37 .1
+0.2
2.22E+06
1.34
0
94
676
1.23E+04
38.6
+0.2
7.28E+07
1.23
0
92
22,600
1.23E+04
39.4

0.OOE+OO

0
92

1.23E+04
39.6
+0.6
2.31E+06
1.33
0
90
933
1.23E+04
51.8
-0.6
1.19E+08
1.27
0
91
47, 600
1.23E+04
51.3
-0.4
5.89E+06
1.30
1
05
2, 030
1.23E+04
44 .2
-0.4
2.23E+07
1.22
0
94
8, 560
1.23E+04
49.3
-0.6
3.29E+08
1.23
0
94
126,000
1.23E+04
49.1
-0.6
2. 67E + 07
1.26
0
79
12,300
1.23E+04
59.1
+0.6
3,18E+06
1.30
0
83
1, 380
1.23E+04
55.8
-0.6
1.42E+07
1.29
0
92
5, 620
1.23E+04
50.7
-0.4
1.05E+07
1.34
0
78
4, 880
1.23E+04
59 .6

0.OOE+OO

0
80

1.23E+04
58.4
-0.4
1.69E+08
1.28
0
83
73,900
1.23E+Q4
56 .2
-0.4
7 . 60E+06
1.30
0
86
3, 200
1.23E+04
54.1
+1.2
2.06E+06
1.28
1
09
680
1.23E+04
42.5
0
7.43E+07
1.29
0
98
27,500
1.23E+04
47.5
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_006RJ-D10
Actual

Fred
Name


RI
CC
RRT
PCB-161
233'45'6-HxCB
34.97

0.9605
PCB-153/168
22 '44'55'-/23'44'
35.37

0.9722
PCB-141
22'3455'-HxCB
35.53

0.9761
PCB-130
22'33'45'-HxCB
NotFnd

0.9855
PCB-137
22'344'5-HxCB
36.06

0.9910
PCB-164
233'
4'5'6-HxCB
36.16

Q.9933
PCB-163/138/129 233'4•56-/22 '
36.43

1.0011
PCB-160
233'
456-HxCB
NotFnd

1.0048
PCB-15B
233'44"6-HxCB
36.76

1.0098
PCB-128/166
22'33'44'-/2344 ' 5
37.50

0.9629
PCB-159
233'455'-HxCB
38.31

0.9840
PCB-162
233
'4*55*-HxCB
38.55

0.9902
PCB-188
22
34'566'-HpCB
NotFnd

1.0006
PCB-179
22
33'566'-HpCB
34 ,52

1.0087
PCB-184
22
344*66*-HpCB
34.99

1.0222
PCB-176
22
33*466'-HpCB
35.27

1.0306
PCB-186
22
34566'-HpCB
NotFnd

1.0421
PCB-178
22
33'55'6-HpCB
36.81

1.0754
PCB-175
22
33'45'6-HpCB
37.35

1.0913
PCB-187
22
34'55'6-HpCB
37.58

1.0979
PCB-182
22
344'56'-HpCB
37.75

1.1031
PCB-183
22
34415'6-HpCB
38.10

1.1132
PCB-185
22
3455'6-HpCB
38.19

1.1155
PCB-174
22
33*456'-HpCB
38.29

1.1187
FCB-177
22
33'4'56-HpCB
38.66

1.1296
PCB-181
22
344'56-HpCB
39.00

1.1397
PCB-171/173
22'33'44'6-/22 ' 3
39.19

1.1450
PCB-172
22'33'4551-HpCB
40.55

0.9061
PCB-192
233'455'6-HpCB
NotFnd

0.9116
PCB-180/193
22'344'55'-/233 '
41.09

0.9178
PCB-191
233
•44*5'6-HpCB
41.39

0.9251
PCB-170
22
33144'5-HpCB
42 .15

0.9421
PCB-190
233
'44'56-HpCB
42 .60

0.9522
PCB-202
22'33'55'66'-CcC3
38.77

1.0006
PCB-201
22133'45'66'-OcCB
39.54

1,0207
PCB-204
22'
344'566'-OcCB
40.12

1.0356
PCB-197
22'33'44'66'-OcCB
40.31

1.0406
pca-200
22'
33'4566'-OcCB
40.40

1.0427
PCB-198/199
22'33'455'6-/22'
42.74

1.1027
PCB-196
22'33'44'56'-OcCB
43.30

1.1175
PCB-203
22' 344 ' 55' 6-OeCB
43.47

1.1218
PCB-195
22'
33'44'56-OcCB
44.58

0.9504
PCB-194
22*33'44'55'-OcCB
46.53

0.9919
PCB-205
233
•44'55'6-OcCB
46.92

1.0004
PCB-208
22"33'455'66'-NoCB
44.38

1.0005
FCB-207
22'
33'44'566'-NoCB
45.17

1.0182
PCB-206
22'
33'44'5516-NoCB
48.38

1,0004
Analytical Perspectives
Actual Diff
RRT
Sees
Response
Ra
0.9605
0
1.55E+06
1.37
0.9717
-1.1
4.50E+08
1.27
0.9761
0
9.45E+07
1.24
-

0.00E+00

0.9905
-1.1
6.77E+07
1.38
0.9933
0
4.66E+07
1.30
1.0007
-0.9
5.94E+08
1.28
-

0.00E+00

1.0098
0
9.20E+07
1.28
0.9631
+0.4
8.99E+07
1.22
0.9838
-0.5
5.43E+06
1.31
D.9901
-0.2
7.55E+06
1.25
-

0.00E+00

1.0087
0
2.78E+07
1.06
1.0222
0
9.44E+05
1.01
1.0305
-0.2
1.28E+07
1.03
-

0.OOE+OO

1.0754
0
1.08E+07
1.07
1.0912
-0.2
4.88E+06
0.99
1.0979
0
6.18E+07
1.03
1.1031
0
1.40E+06
1.03
1.1131
-0.2
4.25E+Q7
1.03
1.1158
+0.7
5.29E+06
1.03
1.1186
-0.2
5.45E+07
1.03
1.1295
-0.2
2.88E+07
1.03
1.1395
-0.5
1.90E+06
1.05
1.1451
+0.2
2.18E+07
1.03
0.9062
+0.2
1.32E+07
1.03
-

O.OOE+OO

0.9184
+1.5
1.44E+08
1.03
0.9251
0
6.82E+06
1.05
0.9421
0
6.16E+07
1.03
0.9522
0
1.83E+07
1.02
1.0007
+0.2
7.45E+06
0.79
1.0206
-0.2
6.84E+06
0.78
1.0355
-0.2
4.00E+05
0.91
1.0403
-0.7
2.05E+06
0.90
1.0426
-0.2
5.29E+06
0.92
1.1031
+1.0
3.21E+07
0.91
1.1175
0
1.54E+07
0.92
1.1218
0
1.82E+07
0.92
0.9504
0
7.85E+06
0.93
0.9920
+0.3
1.98E+07
0.91
1.0004
0
2.94E+06
0.93
1.0005
0
3.98E+06
0.77
1.0182
0
3.06E+06
0.78
1.0004
0
9.42E+06
0.77


Checkcoie .-
m
RRF
Cone
Noise
DL /
1.17
478
1.23E+04
39.6
1.24
132,000
1.23E+04
37.5
0.86
39,600
1.23E+04
53.7
0.80

1.23E+04
58.2
0.94
25,900
1.23E+04
49.2
1.16
14,600
1.23E+04
40.1
0.95
225,000
1.23E+04
48.6
1. 08

1.23E+04
42.9
1.31
25,500
1.23E+04
35.6
0. 82
42,500
3.75E+04
183
0.95
2, 210
3.75E+04
157
0. 97
3,010
3.75E+04
154
1.05

4.94E+03
15.9
0.94
10,100
4.94E+03
17.8
0.93
344
4.94E+03
18
0.98
4,430
4.94E+03
17.1
0.94

4.94E+03
17.9
0.69
5,330
4.94E+03
24.3
1.05
2,290
4.43E+04
217
1.08
28,200
4.43E+04
211
1.14
602
4.43E+04
199
1.18
17,800
4.43E+04
194
1.00
2, 600
4 .43E+04
227
0.98
27,400
4.43E+04
232
0.96
14,800
4-43E+04
238
1.05
896
4.43E+04
218
0.95
11,400
4.43E+04
241
0.99
6, 600
4. 43E+04
230
1.23

4.43E+04
186
1.21
58,900
4.43E+04
189
1.38
2,430
4.43E+04
165
0.94
24,100
4.43E+04
188
1.12
5, 990
4.43E+04
158
1.03
2, 810
6.28E+03
24.8
0.99
2,690
6.28E+03
25.8
0. 94
166
6.28E+03
27.3
1.06
751
6.28E+03
24.1
0.90
2, 300
6.28E+03
28.6
0.69
18,300
6.28E+03
37.4
0.72
8,280
6.28E+03
35.4
0.79
9,020
6.28E+03
32.6
0.66
5. 330
7.77E+03
54.7
0.73
12,200
7.77E+03
49.6
0.97
1,360
7.77E+03
37.2
0.95
1, 930
7.51E+03
38.9
0.96
1,470
7.51E+03
38.4
1.05
5,590
7.51E+03
48
Page 5 of 5
Printed; Oa 06 2008 1:22 PM
-------
AP Lab ID: P9464_6042_PCB _006R J-D10
Instr: AutoSpec-UItima MM3
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11

Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
Rel. Int.
Fn 1 100%.
218,9856
QC (non-EQ)
10.43-15. DQ
Rel. Int.
Fn 2 100%
242.9856
QC (non-EQ)
1S.02-20.50
Abs. nt
5,63e7
2.82e7
,—r-p—i—i—r—|—i—i—i—i—|—i—i—i—i—|—i—i—i—i—|—i—i—i—i—|—i—i—i—i—j—i—i—p—i—|—i—i—i—i—f-Q.OOeO
13.0	13.5	14.0	14.5	15.0 RT
Abs. nt
-1,83e7
-9.1686
O.OOeO
Rel, Int.
Fn 3 100%.
292.9824
QC (non-EQ)
20.52-26.00
0%-
-i	1	r-
21.0
—I—
22.0
-1	1	T~
23,0
24.0
25.0
Abs. Int.
2.06e7
• 1.03e7
• O.OOeO
26.0 RT
Rel. Int.
Fn 4 100%.
330.9792
QC (non-EQ)
26.03-37.11
Rel. Int.
Fn 5 100%
386.9792
QC (non-EQ)
37.13-44.01
Rel. (nt
FnS 100%
454.9728
QC (non-EQ)
44.02-49.21
Abs. nt
2.47©7
1.24e7
O.OOeO
Abs. Int.
3.80eS
1.90e6
O.OOeO
44.0 RT
Abs. rrt
6.72e6
— 3.36e6
— 0.0060
Rel. Int.
Fn 7 100%.
454.9728
QC (non-EQ)
49.22-53.00
0%.
' I ' '
49.5
50.0
50.5
j I I I I | I I
51.0
-r—y—r
51.5
Abs. Int.
-8,08e6
-4.04e6
'O.OOeO
52.0
52.5
53.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resouix;es\P9464_6042_PCB_006RJ-D10.utp ms, saved 05-Aug-200S 09:19 (EE)
AP UltraTrace-Pm I'3.993 User/System: EE/EEC2-03B see 097-297
Peak annotation: Areas, Centroids
PKD: n/a Printed: 05-Aug-2008 09:22:39 Page 1 of 22
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AuloSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-2 0° CHECK EQUALIZED Acq: 02-Aug-2008 00:22:22
VSIR expt: pcb03G6_c!1-10 GC: pcbx90_a Vial:WORTOF®aJCasaE®er: CJL Datafile: 080B02R01_EQ
Rel. Int.
Fn 1 100%.
218.9856
QC Check
10.43-15,00
0%.
10.5
-V*-
¦vr
t i i—i f i—r"
11.0
1 I '
11.5
' ' t 1 ' ' ' I
12.0
' I '
12.5
-r-i—j—i—fi—i—|-t—n—i—| I i
13.0
T"-
13.5
14.0
14.5
Abs. Int.
r-6.01e7
13.00e7
¦O.OOeO
15.0 RT
Rel. Int.
Fn 2 100%.
242.9856
QC Check
15.02-20.50
0%-
16.0
17.0
i * [ i i
18.0
—I—
19.0
—I—'—r"
20.0
Abs. tnt.
-1.63e?
• 8.13e6
¦O.OOsO
RT
Rel. Int.
Fn 3 100%.
292.9824
QC Cheek
20.52-26.00
0%.
21.0
I
22.0
—I—
23.0
24.0
25.0
Abs. Int.
• 1.91e7
9.54e6
O.OOeO
26.0 RT
Rel. Int.
Fn 4 100%.
330.9792
QC Check
26.03-37.11
0%.
28.0
30.0
i i t
32.0
34.0
36.0
Abs. Int.
¦2.53e7
¦ 1.26e7
•O.OOeO
RT
Rel. Int.
Fn 5 100%.
454.9728
QC Check
37.13-44.01
0%.
I—r
38.0
1—|—r—i—i—i—|—i—i—r—-l—|—till
40.0	41.0
42.0
' I ¦
43.0
Abs. Int.
-7.57e6
¦ 3.79e6
¦O.OOeO
44.0 RT
Rel. Int.
Fn 6 100%.
404.9760
QC Check
44.02-49.21
0%.
45.0
46.0
47.0
48.0

I
49.0
Abs. Int.
6 31e6
3.15e6
O.OOeO
RT
Rel. Int
Fn 7 100%.
454.9728
QC Cneck
49.22-53.00
0%.
1 I r
49.5
50.0
50.5
1 ' I '
51.0
¦i	f	i	i	t	%	f	r	v"
51.5
¦"T	*	r	T'"
52.0
52.5
Results: P:\P9400_P9499\P9464_6042 PC8\resoufVes\P9464_6Q42_PCB_006RJ-D 10. utp_res. saved OS-Aug-2008 09:19 (EE)
AP UltraTrsce-Pro V3.993 User/System: EE/EEC2-038
Abs. int.
-€.45e€
¦ 3.23e6
• O.OOeO
53.0 RT
Peak annotation: Areas. Centrotds
PKD: n/a Printed: QS-Aug-2008 09:22:40 Page 2 of 22
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Re I. Int.
100%-
Fn 1
188.0393
MoCB
4a 1 05e4
10.43-15,00
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
0% "i J i
10.5
Rel. Int.
100%-
Fn 1
190.0363
MoCB
4a6.22e3
10.43-15.00
0%-r-y-
10.5
Rel. Int.
100%-
Fn 1
200.0795
MoCB Std,
4a 9.89e3
10.43-15.00
0%-Jt-
10.5
Rel. Int.
100%-
Fn 1
202.0766
MoCB Std.
4a 5.77e4
10.43-15.00
0%-
10.5
11.0
¦ i ¦
11.5
12.0
I I I I	1 t f I f I 'T' ' j *
12.5
PCB-2
1,45e9
13.33
PCB-3
1.15e9
13.51
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
Abs. Int.
-4.21e8
-I—l-t t f \ 1 I f"M | * l"
13.0	13.5
•2.11e8
O.OOeO
i—i—t i y i t > i } i i i i [ i i i i | r i i
14.0	14.5	15.0 RT
PCB-1
I.98eB
II.30
11.0
11.5
12.0
12.5
13.0
PCB-2
4 69e8
13,33
PCB-3
3.70e8
13.51
14,0
14.5
ES-1
I.39e7
II.29
1
ES-3
1.39e7
13.49
i Oi
L
11.0
"¦I	j	»	i	r	r	
11.5	12.0
' I 1 ' ¦ 1 Tr"
12.5
es-y
4.5866
1*29
' I <
11.0
11.5
12.0
1 | T 1 I I | I 1 I I [ I
12.5	13.0
t | I
13.5
14.0
14.5
Abs. Int.
-1.38e8
6.90e7
O.OOeO
15.0RT
Abs. Int.
r5 29e6
-2.64e6
O.OOeO
¦¦¦?•¦¦["-t	i ¦»• -t - ¦t—f* rmmymr,mTm,j	r"|""T""T""T""ir""i|	t-i	i	f"f	i			t
13.0	13.5	14,0	14.5	15.0RT
13.49
Abs. Int.
-1.91e6
•9 56e5
•O.OOeO
15.0 RT
Rel. Int.
100%'
Fn 1
218.9856
QC Check
10.43-15.00'
0%-
		 i ¦
i—|—i—i—i—p—j—r—r—r—*—|—'r-
10.5	11.0
¦ i ¦
11.5
—T—I—*—|—I " T	
12.0
12.5	13.0

13.5
T
14.0
T
14.5
T
Abs. Int.
-6.01e7
•3.00e7
•O.OOeO
15.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\re$ources\P9464_6042_PCB_006RJ-D10Mtp_n>s. saved 0$-Aug-2008 09:19 {EE)	Peak annotation: Areas. Centmps
AP UllraTrace-Pro V3 993 User/System: EE/EEC2-038 cc: 4422 0494	Revised: 04-Aug-2008 13:40 01 (EE) Printed: 05-Aug-200B 09 22:41 Page 3pT22
-------
AP Lab ID; P9464_6042_PCB_006RJ-D1Q
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 1
222.0003
DiCB-1
4o 5.64e3
10,43-15.00
0%-
10.5
11.0
Rel. Int.
100%-
Fn 1
223.9974
DiCB-1
4a 9 41e3
10.43-15.00
0%-
»' | I'
10.5
< r i I i i i » i i
11.0
Rel. Int.
100%-
Fn 1
234.0406
DiCBStd.
4o 8.65e3
10.43-15.00
0%-
Sample ID: Run# H-ACD-M23-2
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
PCB-4
8.60 e6
13.86
11.5
12.0
—1—T J T—I I I | I I I I | I I I I | r ! 1 V ] ! ! !
12,5	13.0	13.5
PCB-10
7.58e6
13.98
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01_EQ
Abs. Int.
4.0le6
4.22e5
14.74
T- I 1 | I 1 I I J I
14.0	14.5

•2.01 e6
¦Q.QQeO
PCB-4
6.24e6
13.86
PCB-10
5.02e6
13.98
1 I 1 " 1 <	I
11.5
I | I I ¦ i T f I I ( I J I 'I I i j I I I 	|11)1111)1
12.0	12.5	13 0	13.5
15.0RT
Abs. Int.
2.67e6
1.34eS
4.39e5
14.74
Tr-
14.5

•O.OOeO
ES-4
3.79e6
13.88
h
15.0RT
Abs. Int.
1 92e6
•9 62e5
rr"
10.5
i I i ""i1	i	
t_T_r
11.0
i t	i" t	i'
i '"I	i | i11—t i | v i i i |—i¦ ri'i—|—i—i i i^i'i""1
11.5	12.0	12.5
13.0
'¦ ""I	
13,5
O.OOeO
14.0
"'T	i r j	i" "i	i j	| i i t i
14,5	15.0 RT
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std.
4o 4,68e3
10.43-15.00
0%-t-r
10,5
~I—1—1—r*-!—t	T""
11.0
—I—|—I—I—I—!—j	I—|—!—I—J—r"
11.5	12.0
12.5
13.0
13,5
¦*' I 1
14.0
1 I 1
14,5
Abs. Int.
-1.22e6
•6.08e5
-O.OOeO
15.0RT
Rel. Int.
100%-
Fn 1
218,9856
QC Check
1043-1500"
0%-
'•'1 1	
10,5

' r 1
11.0
11.5
I i i y i 1
12,0
1 I •
12.5
130
11 I '
13.5
I | 1 I I » | > 1 I
14.0
' ' ( '
14,5
T
Abs. Int.
-6.01e7
3.00e7
¦ O.OOeO
15.0RT
Results: P:\P9400_P9499SP94M_6042 PC8\resources\P94S4_5042_PCB_006RJ-D 10. ulp res, saved Q5-Aug-20Q8 09:19 (EE)
AP UttmTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 5484. 2018
Peak annotation: Areas, Centrmjs
Revised: M-Aug-2008 13:50:08 (EE) Printed: OS-Aug-2008 09:22:42 Page 4 y?22
-------
AP Lab ID: P9464_6042_PCB_OG6RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 2
222,0003
DiCB-2
4o 9.98e3
15.07-20.50
Sample ID: Run# H-ACD-M23-2
VSIR expt: pcb0306_cI1-10 GC: pcbx90_a Vial: 11
0%-
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4ct 2.70e4
15.07-20.50
0%-
Rel. Int.
100%-
Fn 2
234.0406
DiCBStd.
4o 1,36e4
15.07-20.50
0%-
Rel. Int.
100%-
Fn 2
236.0376
DiCB Std.
4a 5.33e3
15.07-20.50
0%-
PCB-13/12
4.45e6
19.04
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01_EQ
Abs. Int.
9.05e7
PCB-9
3.09e7
15.67
PCB-6 PCB-5
5.34e7 iV?l
16.05 1635
1/x a 7\ A/\
16.0
1—I—1
17.0

PCB-11

1.56eB
PCB-14
18.75
6.24e7
A
17.97
\
A
. A
18.0
PCB-15
8.34e7
19.32
19.0
PCB-13/12
2.93e8
19.04
PCB-6
3.52e7
16.05
PCB-9
2.08e7
1S 67 ^ A
¦A A, /\
16.0
JS 9
9.46e6
15.65
PCB-5
4.32e7
16.34
-AA-
17.0
PCB-14
4.11e7
17.97
-A-
PCB-11
1.02e8
PCB-15
5.51e7
19.32
.A.
18,0
19.0
1—I—1
160
17.0
I
18.0
ES-15
1.03e7
19.30
19.0
JS-9 y
5J2e§/
1536
M
4.21 e5
18.73
,	
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Uttima MM3
Rel. Int.
100%
Fn 2
255.9613
TrCB-2
4o 3,09e3
15.02-20.50
0%-
Rel. Int.
100%-
Fn 2
257.9584
TrCB-2
4a2.51e3
15.02-20.50
0%-
16.0
Sample ID; Run# II-ACD-M23-2
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 11
PC 8-19
3.40e6
16.74
—I	1
17.0
PCB-19
3.25eB
16.74
rA-
i i i
18.0
PCB-30/18
3.27e7
18.47
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
Abs. Int.
-8.72e6
PCB-17
PCB-16
1.6Qe7
,53e7
PCB-27
5.29e6
19.05
19.0
20,0
PCB-30/18
3.20e7
18.47
16.0
17.0
'—I—'
18.0
PCB-17
1.5967
PCB-16
1.4Be7
19.27
PCB-27
5.12e6
19.04
•4.36e6
19.0
20,0
¦O.OOeO
RT
Abs. Int.
-8.62e6
4.31 e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
268.0016
TrCBStd.
4o2.16e4
15.02-20.50
0%-
Rel. Int.
100%-
Fn 2
269.9986
TrCBStd.
4a 1,44e4
15.02-20.50 -I
0%-

ES-19
5 62e6
16.72
1.75e6
15.61
A
—|—«-
16.0
17.0
180
19.0
ES-19
5.28a
16.0
—I—'
17.0
-|—i—r-
1—I—1
18.0
I I I
19.0
1.02e6
19.42
20.0
Abs. Int.
-4.30e6
•2.15e6
-O.OOeO
RT
Abs. Int.
-1.58e6
¦7,91 e5
20,0
¦O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
15.02-20 50
0%
16.0
17.0
18.0
19.0
¦"T	1	t	f"
20,0
Abs. Int.
-1.6367
6.13e6
•O.OOeO
RT
Results: P\P9400_P9499\P9464_6042 PCBVesouKeslP9464_6042_PCB_006RJ-D10utp_res. saved OS-Aug-2008 09:19 (EE}	Peak annotation: Areas, Centroxis
AP U/traTrace-Pro V3.993 User/System: EE/EEC2-Q38 cc: 3756. 6348	Revised: 04-Aug-2008 13:51:01 (EE) Printed: 05-Aug-2008 09:22:44 Page Bgf22
-------
AP Lab ID: P9464_6042._PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
Rel. Int.
100%-
Fn 3
255.9613
TrCB-3
4o 1.82e4
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
4o9,19e3
20,52-26.00
0%-
PCB-34
6.77e6
20.87
21-29 ifW
PCB-28/20
9.57e7
PCB-31 22^WCB-21/33
c q9q7 a a./ye/
2176 II 22.22
PCB-35 PCB-37
118e8 ',2tte8
25.18 25.64
¦x
21.0
A
PCB-22
3.99e7
22.59
PCB-34
6.48e6
2°j7/\
P%>2P%6-25
PCB-31
5,71 e7
21,76
22.0
PCB-28/20
9,19e7
22.0BCB-21/33
8.41 e7
22.22
23.0
1 I I f
3,52e6
23J4
PCB-36
2-34e7
23.86
-A
PCB-39
1.94e7
24.27
PCB-38
5,78e7
24,0
25.0
21.0
PCB-22
3.77e7
22.59
3 61e6
23.64
PCB-36
2.20e7
23.96


PCB-35


1.13e8


25.18

PCB-38
A

5,48e7
/

24.79

PCB-39
A

1.8267
\

24.27
/ \

	A		
/ V
, / A.
PCB-37
1.17e8
25.54
22.0
23,0
24,0
25,0
> * 1 1 | »
Abs, Int.
-3,08e7
¦ 1,54e7
¦O.OOeO
26.0 RT
Abs. Int.
2.98e7
1,49e7
•O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
268.0016
TrCBStd.
4o 2.74e4
20,52-26.00
0% "~p" I "1 I | 		" l	1 i "l'	f"tf i^ V
21.0	22.0
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
4cr 2.24e4
20.52-26.00
0%-
21.0
SS-28
i—|" t-'I"""1)"1	t"	f i1 '<	i" i | i 'f r i
23.0	24.0
ES-37
7.12e6
25.52
11 1	T1 f T I I' i" I" f' l""r | 1 '
25.0
Abs, Int.
-2.10e6
¦ 1,05e6



ES-37
8.5986
7,84e5
23.27


- i\
-r—t-O.OOeO
26,0 RT
Abs. Int.
2.04e6
•1.02e6
22.0
23.0
24,0
25.0
-O.OOeO
26.0 RT
Rel, Int.
100%-
Fn 3
292,9824
QC Check '
20.52-26.00"
0%-
21.0
22.0
23,0
Abs. Int.
-1.91e7
-9.54e6
i i 5 f » i—j-—i—(—i i j i i i i | i i i i j i i ¦¦11 i1" 0 .OOeO
24.0	25.0	26.0 RT
Results: P:\P9400_P9499W9464_6042 PCB\resourcesSP9464_6042_PCB_DQ6RJ-D10Mtp_res, saved 05-Aug-2008 09:19 (EE)	Peak annotation: Areas, Centroid/'
AP UltraTmce-Pm 1/3.993 User/System: EE/EEC2-038 cc 9033, 2548	Revised: 04-Aug-2006 13:51:50 (EE) Printed: 05-Aug-2008 09:22:45 Page 7 aUb
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 2
289.9224
TeCB-2
4o1.53e3
15.02-20.50
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
0%-
Rel. Int.
100%-
Fn 2
291.9194
TeCB-2
4o 2 05e3
15 02-20.50
Rel. Int.
100%-
Fn 2
301.962S
TeCB Std.
40 2.01e3
15.02-20.50
0%-
Rel. Int.
100%-
Fn 2
303.9597
TeCB Std.
4o 2.62e3
15.02-20.50
0%-
—p-i
16.0
-|	iji np ,,
17.0
| ^	I	I	 "? "f	f		'T1 		 i
18,0
2.23e4
15.92

16.0
16,0
16.0
17.0

	-
18.0
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
Abs. Int.
-6.33e4
3,16e4
¦^=-O.OOeO
,	1	,	r-
17.0
18.0
17.0
I I I | f I I
18.0
Abs. Int.
-7.53e4
3.77e4
PGB-54
2.41e5
19.62
-¦ rfl 1 - I ¦ *1 . ¦ r
PCB-54
3.22e6
ES-54
5 13e6
9.60
B.63e6
19.60
OOeO
Abs. Int.
-1.23e6
6.15e5
-O.OOeO
RT
Abs. Int.
1.55e6
7,73e5
O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
15.02-20.50'
0%-
T
T
T
-1	7	t	1""
16.0	17.0	18.0
Results: P:\P9400_P9499\P9464_6042 PCBVesource$\P9464_6042_PCB_0Q6RJ-D10.utp_res, saved OS-Aug-2008 09:19 (EE)
AP UlIoTrace-Pro V3.993 User/System EE/EEC2-038 cc: 8402, 5166
¦¦¦r	x	|	i	r	i	i""
19.0
20.0
Abs. Int.
-1 63e7
8,13e6
¦O.OOeO
RT
Peak annotation: Areas, Centmids
Revised: 04-Aug-200B 13:46:03 (EE) Printed: 0S-Aug-2008 09:22:46 Page B ^22
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 3
289.9224
TeCB-3
4cr 2.36e3
20.52-26.00
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 11
0%.
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4a 3.88e3
20.52-26,00
0%-
PCB-44/47/65
5.30e?
24.52
PCB-50/53
e.soee
21.52
<~v.
PCB-45
6.32ee
22.11
PCB-46
2.43e6
22.38
21.0
22,0
23.0
PCB-50/53
8.43e6
21.52
Qv.
PCB-46
PCB-45
84°^p	3.18e6
>vl	22 39
>	-
21.0
22.0

23.0
PCB-52
7.75e7
23.64
PCB-69/49
3.1967
24.07
PCB-4B
PCB-43
1.03e7
2.85e6
24.33
PCB-52
1.01e8
23.64
PCB-69/49
4.1 Se7
24.07
PCB-48
1.36e7
24.33
A
3.70e6
23.85
Acq: 02-Aug-2008 00:22:22
User: GJl Datafile: 0808Q2R01_EQ
Abs. Int.
r1.99e7
PCB-59/62SEB-42
1.23e7l.l4e7
24.80 24.98
yv /\,
PCB-64
2.45e7
PCB-41 25 60
W\ A
25.0
PCB-44/47/65
6.89e7
24.52
PCB-59/6BES-42
I.62e71.51e7
24.80 24.98
. /\/\
PCB-64
3.20e7
PCB-41 25a60
7.79e9
25.3(1
A
¦9.95e6
-O.OOeO
26.0 RT
Abs. Int.
2.56e7
1.28e7
24.0
25.0
-O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
301.9626
TeCBStd.
40 3.55e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
303.9597
TeCB Std
40 3.27e3
20.52-26.00
0%-
21.0
22.0
23.0
24.0
25.0
JS-52U-
6,67«6
2T61
21.0
22.0
23.0
24.0
25,0
Abs. Int.
-1.41e6
¦7,04e5
-O.OOeO
26.0 RT
Abs. Int.
1.75e6
¦8.74e5
-O.OOeO
26,0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
20.52-26.00
23.0
Results: P:\P9400_P9499\P94S4_S042 PCBlresaurce$\P9464_6042_PCB_006RJ-D10.utp_ms, saved 05-Aug-2008 09:19 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 9862, 9847
Abs. Int.
-1.91 e7
9.54e6
O.OOeO
26.0 RT
Peak annotation: Areas, CenlroicIs
Reviseef: 04-Aug-200B 13:58:58 (EE) Printed: OS-Aug-2008 09:22:47 Page
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 11
Rei. int.
100%-
Fn 4
289,9224
TeCB-4
4o 2,23e4
26,03-32.99
0%-
Rel. Int.
100%-
Fn 4
291,9194
TeCB-4
4o 1,79e4
26,03-32.99
0%-
Rel. Int.
100%
Fn 4
301.9626
TeCB Std.
4o 5.80e3
26.03-32,99
0%-
Rel, Int.
100%-
Frj 4
303.9597
TeCB Std.
40 6 37e3
26.03-32.99
0%-
PCB-61/70/74/76
1,50e8
27.80
PCB-66
5.74e7
28,08
PCB-72*CB-68
3.S6e66.14e6
28.32 26.57
—i—r-
PCB-67
1.54e7
27,29
-Pf'rvA. ¦
PCB-57
6.95e6
26.93
27.0
C8-55
20e7
22
PCB-5B
4.88e7
28.65
*CB-60
1.84e7
28,84
¦A.
PCB-80
3 66e6
29.18
28.0
PCB-61F10/74/76
1.93e8
27.80

PCB-79
2.98e7
30,49
,a>
PCB-78
2.18e7
30.96
, A.
PCB-81
1.52e7
31.34
,-A
Acq: 02-Aug-2008 00:22:22
User: CJl/ Datafile: 080802R01_EQ
Abs. Int.
-2.72e7
¦1,36e7
29,0
30.0
31.0
PCB-77
8.49e7
31,82
PCB-66
7.36e7
28.08
PCB-7?CB-68	PCB-57 %|f
4 52e67.97e6	9,29e6	27 29
26 32 26.57 26.93	A
i 11 M i	^ j	|	|
27,0
CB-55
PCB-56
6.25e7
28 65
PCB-80
, 2,37e7
28.84
¦A
28,0
PCB-80
4.78©6
29.18
	i O" i
PCB-79
3.83e7
30.49
PCB-78
2.30e7
30.97

A	30.97
[/ I	|	|
PCB-81
1,96e7
31,34
i^fS
29.0
30.0
31.0

PCB-77
1,09e8
31.82
im¥	t	r	T"
32.0
ES-81
5.36e6
31.33
ES-77
6.40e6
31.80
27.0
28.0
29.0
30.0
31.0
32.0
ES-81
6,77eff
J&33
ES-77y
7B7M
3 mo
-i—i—r—i—r~
27,0
28.0
29.0
-i—•- 0.00e0
RT
Abs, Int.
-3 49e7
1.75e7
¦t			O.OOeO
RT
Abs. Int.
-1.54e6
¦7.71e5
¦O.OOeO
RT
Abs. Int.
-1.93e6
-9.63e5
30.0
31.0
32.0
•O.OOeO
RT
Rel. Int.
100%'
Fn 4
330.9792
QC Check
26.03-32.99.
Results: P:\P9400_P9499\P9464_6042 PCB\n>sourzes\P9464_6042_PCB_0O6RJ-D 10 utp_res. saved Ob-Aug-2008 09:19 (EE)
AP UltraTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 8970, SOTS
32.0
Abs. Int.
2,53e7
1.26e7
-O.OOeO
RT
Peak annotation: Areas, Cemmj&i
Revised: 04-Aug-2008 14:01:13 (EE) Printed: OS-Aug-200S 09:22:48 Page 10 of 22
-------
AP Lab tD: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int,
100%
Fn 3
323.6834
PeCB-3
4o t ,48e4
20.52-26.00
Rel. Int.
100%
Fn 3
325.8804
PeCB-3
4o 2.47e4
20.52-26.00
Rel. Int.
100%-
Fn 3
337.9207
PeCB Std
4o 4.04e3
20.52-26.00
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
Abs. Int.
-4 07e5
PCB-96
1.64e6
PC8-96
2.68ei
24.80
0%-
ES-104
7.78e6
24.48
"'I	I	I	
21.0
22.0
23.0
24.0
25.0
Rel. Int.
100%
Fn 3
339.9177
PeCB Std.
4o 4.16e3
20.52-26.00 \
0%-
i—|—i
21.0
2.03e5
O.OOeO
26.0 RT
Abs. Int.
6.76e5
3.38e5
O.OOeO
26.0 RT
Abs. Int.
1.96e6
9.80e5
-O.OOeO
26.0 RT
Abs. Int.
1.20e6
•6.01e5
¦O.OOeO
22.0
23.0
24.0
25.0
26.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
20.52-26.00
Results: P:\P9400_P9499\P9464_6042 PCB\reSQUKe$\P9464_6042_PCB_006RJ*D10.utp_Fe$, saved 05-Aug-2008 09:19 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 8478, 665f
Abs. Int.
-1.91e7
9.54e6
O.OOeO
26.0 RT
Peak annotation: Areas, Centroids
Revised: 04-Aug-2008 14:01:29 (EE} Printed: OS-Aug-2008 09:22:50 Page 11 ofZT
-------
AP Lab ID: P9464_6042_PC B_006RJ-010
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 4
323,8834
PeCB-4
40 7 15e4
26,03-37.11
Sample ID: Run# II-ACD-M23-2
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
/
Acq: G2-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
o%-
Rel. Int.
100%-
Fn 4
325,8804
PeCB-4
4o 1.47e5
26.03-37,11
0%-
Rel. Int.
100%-
Fn 4
337,9207
PeCB Std.
4a 5.23e3
26.03-37.11
0%-
Rel. Int.
100%-
Fn 4
339.9177
PeCB Std.
4 o 9.59e3
26.03-37.11
0%-
PCB-95
9.7987
PCB-113/90/101
1.62e8
29 57
PCB-108/119/86/97/
1.64e8
30.53
PCB-110
2.11e8
31.25
PCB-118
1,98e8
33.79
PCB-91
1.49e7
27.79
A A
28.0
PCB-92
2.39e7
29,06
PCB-83
PCB-11
3.4866
/
PCB-82
1.70e7
31.52
A

PCB-12!
5.97e6
BS1
y
/
PCB-105
8.82e7
34.79
PCB-114
8.02e6
34.25
30.0
32.0
PCB-95
1.57e8
27.04
PCB-113/90/101
2.61e8
29.57 pcB-108/119/88/97/
2.98e8
30.52
PCB-110
3.48e8
31.25
PCB-91
2.45e7
27.79,

PCB-92
3.86e7
29.06
28.0
¦A—^
PCB-83
3.70 "
29.90
1 I 1
34.0
PCB-118
3.17e8
33.79
PCB-127
5.92e66.33e6
38.03 36.44
	f		'	
36.0
PCB-11 ?
5.96el
31 ""
30.0
PCB-82
2.8167
31,52
ivA	,
-O"
PCB-12:
1.01e7
PCB-105
1.40e8
34.79
PCB-114
1.39e7
34.25
	
JS-101
6,41e6
29.55
32.0
SS-111
9 37e6
3183
2^41>S
34,0
PCB-127
1.01e7
36.03
-i—p—i—f*-
36.0
ES-123
7.36e6
33.49
ES-114
7.70e6
34.23
ES-105
7.7488
34.77
m
J.
Abs. Int.
r-4 86e7
¦2.42e7
-y—O.OOeO
RT
Abs, Int.
-8.03e7
•4.02e7
-O.OOeO
RT
Abs. Int.
-2.17e6
1,Q9e6
28.0
30.0
32.0
JS-101
4.09ej
29
SS-111
6.03BST
3113
1.75e5
28.62
4.08e5
30.20
28.0
30.0
1—r_
3.86< :5
31.6 5
A>
34.0
4Me6 5.0%ir 5,0Se6
33,49
34.23 34,76
i i f 1 r ' ' i I O.OOeO
36.0	RT
Abs. Int.
1.39e6
¦6.97e5
32.0
34.0
i j			t i i--( 0 .OOeO
36.0	RT
Rel. Int.
100%-
Fn4
330.9792
QC Check
26.03-37.11'
Abs. Int.
-2.53e7
1.26e7
O.OOeO
30.0
Results: P:\P9400_P9499W94&4_6042 PCB\re$OUKes\P9464_6042_PCB^JX>BRJ-D10.utp_ms, saved 0S-Aug-2008 09:19 (EE)	Peak annotation: Amas, Centmidp
AP UltraTrace-Pro V3 993 User/System EE/EEC2-038 cc: 0444, 8128	Revised: 04-Aug-200S 14:04:19 (EE) Printed: 0S-Aug-2008 09:22:51 Page 1Jj^22
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90„a Vial: 11
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01_EQ
Rel. Int.
100%-
Fn 5
323,6834
PeCB-5
4o 6.20e4
37.13-44.01
0%-
» I t J1 I""
38,0
I I I I
39.0

40.0
i ' |—r—i—r-
41,0
i i j i i i
	t	i' 11	i	
42.0
43,0
Abs. Int.
-4.67e8
•2.33e8
) ( i 0, OOeO
44,0 RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4c 1 04e5
37.13-44.01
0%-
37.37
ES-126
Rel, Int. |§1e6
100%-
FnS
337.9207
PeCBStd.
4a 8,53e3
37 13-44.01
0%-
38.0
t "4 f * I	T-	ffm
38,0
ES-12j
Rel. Int. 5 90
100%-,
Fn 5
339.9177
PeCB SM,
4o 1.10e4
37.13-44.01
0%-
37.37
I I I I
r\ ,
i i "Hi i~ i »
38.0
39.0
40,0
	t	*	|	*	I"'1
41.0
A-
42,0
43.0
39.0
40.0
41,0
42.0
'[ f-i—i F' |—r
43.0
""¦""I" '
39.0
-f—i—11 -~r^—i—i—i	-i	)	i	
40,0

41,0
?-*¦—* **i ' I '
42.0
¦iT "j f-1 I I r *|"	•'
43.0
Abs, Int.
-1.11e8
¦5,54e8
¦O.OOeO
44,0 RT
Abs. Int.
1.9486
9,69e5
-i	r	r	1""
O.OOeO
T
44.0 RT
Abs. Int.
r1.19e6
-5.95e5
¦O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44,01"
0%-
-i—i—!—r
i-1-
38.0	390	40.0	41.0
Results: P:\P9400_P9499\P9464_6042 PCB\resouKesSP9464_6042_PCB^006RJ-D10Mtp_m$, saved 05-Aug-2008 09:19 (EE)
AP Ultra Trace-Pm V3 993 User/System: EE/EEC2-Q3B cc: 1392, 3116
T
42.0
43.0
Abs. Int.
-7.57e6
¦3.79e6
I.OOeO
44.0 RT
Peak annotation: Areas. Centroidf
Revised: 04-Aug-2008 14:04:30 (EE) Printed: 0S-Aug-2008 09:22:52 Page 13 al£2
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4o 7.19e3
27.99-37.11
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Via!: 11
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
0%-
28.0
PC B-136
4.01e7
29.99
A
29.0
30.0
31.0
PCB-147/149
1.81e8
32.82
PCB-151/135	^
6.68e7 PCB-144 PCB-134
32.05 1 23e7 I f4Se7
32.52 I P2.99
PCB-153/168
2S2e8
35.37
PCB-163/138/129
3.34e8
36.43
PCB-132
9.49e7
33.88

PCB-146
4.18e7
34.85
Plie?1 PCB-137
iS S3 3'93e7
32.0
33.0
34.0

PCB-158
5,16e7
36.76

Abs. Int.
-7.586?
•3.79e7
35.0
36.0
37.0
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4a 5.10e3
27.99-37.11
0%-
28.0
1 I '
29.0
PCB-136
3.27e7
29.99
. .A..
PCB-151/135
5.2Se7 PCB-144
32.05 1.00e7
A
30.0
31.0
32.0
PCB-147/149
1.47eo
B-134
PCB-153/168
1.99e8
35.37
PCB-163/138/129
2 61e8
36.43
PCB-132
7.39e7
33.88
PCB-146
3.25e7
34.85
34.0
¦A
35.0
•< ;b-141
,21e7
15.53
SL
PCB-137
2.85e7
56.06
T
36.0
Rel. Int.
100%-
Fn 4
371.8817
HxCB Sid.
4o 2.80e3
27.99-37.11
0%-
ES-155
8.01e6
29.37
28.0
29.0
u
ES-153
6.16e6
35.35
JS-138
5.0466
36.41
PCB-158
4.03e7
36.76
Un
•OOOeO
RT
Abs. Int.
-5.96e7
-2.98e7
¦ O.OOeO
37.0 RT
Abs. Int.
r 1.94e6
•9.72e5
30.0
4-O.OOeO
31.0
32.0
33.0
34.0
35.0
36.0
i • ¦ ' ¦ i
37.0 RT
Rel. Int.
100%-
Fn 4
373.8788
HxCB Std,
4o 3 53e3
27.99-37.11
ES-155
5.93e6
29.3r
0%-
28.0
		1"'
29,0
30.0
31.0
32.0
33.0
34 0
' 1 •
35.0
JS-138
4.opeT
36^41
Abs. Int.
-1.41e6
7.05e5
O.OOeO
36.0	37.0 RT
Rel. Int,
100%
Fn 4
330,9792
OC Cheek
27.99-37.11
Abs. Int.
2.50e7
I.25e7
T-f-O.OOeO
37.0 RT
Results: P:\P9400_P9499\P9464_6042 PCBkBSOurces\P9464_6042_PCB_006RJ-D10,utp_ms. saved 05-Aug-2008 09:19 (EE)
AP UltraTnace-Pm V3 993 User/System EE/EEC2-038 cc: 7076, 5631
Peak annotation: Areas. Centmps
Revised: 04-Aug-2008 14:07:15 (EE) Printed: 05-Aug-2008 09:22:53 Page 14 QT22
-------
AP Lab ID: P9464_6042_FCB_Q06RJ-D10
Instr: AutoSpec-Ultima MM3
PCB-128/166
Rel. Int. 4J3e7
100%- 37 50
Fn 5
359.8415 •
HxCB-5
4o 2.12e4 .
37.13-44.01 •
Sample ID; Run# II-ACD-M23-2	. A O
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11 <-"fVA

Acq: 02-Aug-2008 00:22:22
User CJL Datafile: 080802R01 EQ
0%-
PCB-156/157
S.72e7
39.92
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4o 1,64e4
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
371.8817
HxCBStd.
4g 1 ,Q6e4
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
373.8788
HxCBStd.
4o 1,06e4
37,13-44.01
0%-
PCB-128/166
4.05e7
37.50
38,0
3.08e6^f°|f
38,31 38a65
PCB-1B7
1.78e7
38,98
1,40e*+-1.1 Bw?"?-
,0^

38.0
2.35e63_3fe6
38.31 3y6
.......
39,0
, , i i i , i
40.0

PC B-156/157

4.64e7

39,92
A
PC B-167
ft
1.42e7

38.96
A...

39.0
... .
,,,,,,,
40.0
41.0
,/V\
43.0
PCB-169
1,13e7
42.63
-i—i-
41.0
' I	r
42.0
43.0
ES-156/157
1.19e7
39-61
38.0
¦-*—p—i—i—r-
39,0
38.0
ES-16Z
38 04
40.0
ES-156/157^
9.41eS^
39*01
i f r i i i |
41.0
' I 1	' ' ' I"
42.0
43.0
39.0
40,0
-I i t **y
41,0
2.83e5
41.04
11"11
T 1 ' I I
ES-16
43S2
Abs. Int.
-1.15e7
•5.74e6
-O.OOeO
44,0 RT
Abs. Int.
-9.59e6
•4.80e6
•O.OOeO
42.0
43.0
—I—|—T—t—
44.0 RT
Abs. Int.
-2.09e6
¦1.04e6
¦O.OOeO
44.0 RT
Abs. Int.
-1,70e6
¦8.51e5
¦O.OOeO
44.0 RT
Rel. Int.
100%'
Fn 5
454.9728
QC Check
37.13-44.01
0%-
| r
38.0
39,0
40.0
41.0
42.0
Results: P:\P9400_P9499\P9464_6042 PCB\msoumes\P9464_B042_PCB_006RJ-DW.utp_res, saved OS-Aug-2008 09:19 (EE)
AP UltraTrace-Pro V3 993 User/System: EE/EEC2-038 cc 4966. 2743
43.0
Abs. Int.
-7.57e6
•3.79e6
¦O.OOeO
44.0 RT
Peak annotation: Areas, Cenlroids
Revised: Ot-Aug-2008 14:07:47 (EE) Printed: 0S-Aug-200B 09:22:54 Page IS of/5
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. int.
100%
Fn 4
393.8025
HpCB-4
4o 2.57e3
30.01-37.11
0%-
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
PCB-179
1.43e7
34,52
31.0
32.0
33,0
	' I	
34.0
A.
PCB-176
6.49e6
35.27
PCB-184 A
4 75e5 I \
34J9 /J V
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01_EQ
Abs. Int.
-3.53e6
PCB-178
5,B0e6
36.81
35.0
< < * i t i —i i r | i t
36.0
1.76e6
•O.OOeO
37.0 RT
Rel. Int.
100%-
Fn 4
395.7995
HpCB-4
4o 2.37e3
30.01-37,11
0%-
Rel. Int.
100%-
Fn 4
405.8428
HpCB Std.
4o 2.79e3
30.01-37,11
0%-
Rel. Int.
100%-
Fn 4
407.8398
HpCB Std.
4o 2,20e3
30 01-37.11
0%-
31 0
32.0
33.0
31.0
32.0
33.0
31.0
320
33.0
PCB-179
1,35e7
PCB-176
6.30e6
35,27
PCB-184
4.6985
34.99
ES-188
o.Oueb
34.23
36.0
36.0
PCB-178
S.24e8
36.81
Abs. Int.
-3.65e6
¦1.82e6
O.OOeO
T' r • ¦ r
37.0 RT
SS-178
3.91 e6
36.78
Abs. Int.
-1.51e6
7.53e5
¦O.OOeO
37.0 RT
SS-178
3.84e6
36.78
Abs. Int.
-1.46e6
¦7,31e5
36,0
™i—i—t——[ O.OOeO
37.0 RT
Rel. Int
100%-
Fn 4
330.9792
QC Check
30.01-37.11"
Abs. Int.
-2.50e?
-1,25e7
0%-
t i i r [
i i [ i i i
31.0
—[¦	y	t	t	t—|	i	»,m
32.0
33.0
""»	F	»	f	T	T	T"
34.0
i—I—t—i—r	r	
35.0
Results; P:\P9400_P9499\P9464_6042 PCB\resaurees\P9464_6042_PCB_006RJ-D10.utfl_ms. saved 05-Aug-2008 09:19 (EE)
AP UltraTrace-Pro V3.993 User/System: EBEEC2-03S cc: 0384. 6663
• I '
36.0
<-0,00e0
37.0 RT
Peak annotation: Ames, Centrpids
Revised: 04-Aug-2008 14:10:43 (EE) Printed: OS-Aug-2008 09:22:55 Page J6>w 22
-------
AP Lab 10: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 5
393.8025
HpCB-5
4o 2.17e4
37.13-44.01
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
PCB-180/193
7.33e7
41.09
0%-
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4o 2.26e4
37.13-44.01
0%-
PCB-187
3.1467
PCB-183
37.58
2.16e7
PCB-175
2.42e6
37.35
PCB-170
PCB-177
1.46e7
38,66
PCB-171/173
1.1107
39.19
t A
39.0
40.0
PCB-172
6.73e6
40.55
, {S ,
PCB-191
3.50e6
41.39
. Q
41.0
PCB-180/193
7.11e7
41.09
I
3.12e7

42.15

A
PCB-190
\
9.26 e6
/ \
42.60

A
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01_EQ
Abs. Int.
1.60e7
•8.02e6
42.0
43.0
PCB-167
3.04e7
37.58
PCB-175
2,4Be6
37.35
PCB-183
2,09e7
PCB-177
1.42e7
38.66
PCB-171/173
1.07e7
39.19
A
PCB-170
3.04e7
42.15
38.0
39.0
40.0
PCB-172
6.52e6
40.55
-A-
PCB-191
3.32e6
41.39
	 i.^\. 		
PCB-190
9,04 e6
42.60
A
•O.OOeO
44.0 RT
Abs. Int.
-1.57e?
•7.85e6
42.0
43.0
-O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std.
4a 6.83e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std..
4o4.92e3
37.13-44.01
0%-
38.0
39.0
1.68e5
^39.43
' I
40.0
Abs. Int.
-1.30e6
-6,49e5
•O.OOeO
38.0
42.0
43.0
ES-170
5.26e6
ES-18
39.0
40.0
41.0
42.0
I ¦ 1 ' ' I
43.0
44.0 RT
Abs. Int.
-1.21e6
-6,03e5
-f-O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01"
0%-
Abs. Int.
-7.57e6
¦3.79e6
38,0
39.0
40.0
41.0
42.0
43.0
-f-O.OOeO
44.0 RT
Results: P:\P940Q_P9499\P9464_6042 PCB\resources\P9464_6Q42_PCB_006RJ-D 10.utp_res, saved 05-Aug-2008 09:19 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 5599, 7610
Peak annotation: Areas. Centroj&sf
Revised: 04-Aug-2008 14:12:22 (EE) Printed: 05-Aug-2008 09:22:56 Page 170122
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 6
393.8025
HpCB-6
4o 7,11e3
44.02-49.21
Sample ID: Run# II-ACD-M23-2
VSIRexpt: pcb0306_cl1-10 GC: pcbx?0_a Vial: 11
Rel. Int.
100%-
Fn 6
405.8428
HpCBStd.
4o 8.95e3
44.02-4921
0%-
PC B-189
4.42e6
44.77
45.0
46.0
47.0
PCB-189
Rel. Int.
4.32e6
100%-,
44.76
/I
Fn 6
A
395.7995 ¦

HpCB-6 J

4o 6.08e3 ¦

44.02-49.21 ;
J
0%-

1.40e5
44.38
	1
Rel. Int.
100%-
Fn 6
407.8398
HpCBStd.
4o 7 57e3
44.02-49.21
0%-
—
45.0
ES-189
5.45e6
44.75
ES-«9
I I I
46.0
47.0
46.0
6.17e5
46.75
47.0
1.78eS i.3SeS
46.71 46.91
Acq: 02-Aug-2008 00:22:22
User: CJL Dataftle: 080802R01 EQ
Abs. Int.
-1 05e6
48.0
48.0
3,29e6
48.24
49.0
A
49.0
•5.26e5
-O.OOeO
RT
Abs. Int.
-1.01e6
•5.04e5
i i i ~i
48.0
49.0
-O.OOeO
RT
Abs, Int.
-1.29e6
6,47e5
t—f-O.OOeO
RT
Abs. int.
-!24e6
6.19e5
1.22e6
4Q4
45.0
46.0
47.0
48.0
1—1—
49.0
4- O.OOeO
RT
Rel, Int.
100%-
Fn 6
404,9760
QC Check
44.02-49 21"
Abs. Int.
-6.31 e6
-3.15e6
0%-
I I I
45.0
46.0
47,0
48,0
49.0
-O.OOeO
RT
Results: P:\P940Q_P9499\P9464_S042 PCB\msoumes\P9464_6042_PCB_006RJ-D10.utp_n$, saved 05-Aug-2008 09:19 (EE)	Peak annotation: Areas, Centrvids
APUltraTrace-Pm V3.993 User/System:EE/BEC2-038 cc: 7367, 0423	"	Revised: 04-Aug-2008 14:12:24 (EE) Printed. 05-Aug-2008 09 22 57 Page 1Bpf72
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 5
427.7635
OcCB-5
4o 2.92e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
429.7606
OcCB-5
4o3.36e3
37.13-44.01
0%-
38,0
-r=?-
T—r
38,0
Sample ID; Run# II-ACD-M23-2
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
Acq: 02-Aug-2008 00:22:22
User: CJL Data file: 080802R01_EQ
PCB-198/199
1,53e?
42.74
PCB-202
3.28e6
38,77
-A*
PCB-201
3.01 e6
39.54
PCB-197
9.72eS
PCB-196
7.38e6
43,30
39.0
40.0
41,0
42.0
43.0
PCB-198/199
1,68e?
42.74
PCB-202
4.16e6
38,78
PCB-201
3.83e6
39.54

, /?.
PC8-197
1.08e6
4^\
PCB-196
8.0186
43.30
39.0
40.0
41.0
42.0
43.0
Abs. Int.
r3.57e6
1.79e6
•O.OOeO
44.0 RT
Abs, Int.
4.04e6
•2.02e6
-O.OOeO
44,0 RT
Rel. Int.
100%-
Fn 5
439,8038
OcCBStd,
4o 1.90e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std
4o 2.12e3
37.13-44.01
0%-
3.16eS 2.39e5
37.52	38.12
38,0
3.97e5 3.45e5
37.82 38.12
/x	^
T | > t I i | I I 1 I |" 1 I t I | 1 I I I ) I I I
40.0	41.0	42.0
ESu _
5.5oe6
38.75
38.0
39.0
40.0
43.0
¦ I1"'
41,0
1.34e5
43.29
—r~l—r
42.0
43.0
Abs. Int.
-1.18e6
•5.88e5
•O.OOeO
44.0 RT
Abs. Int.
-1 24e6
•6.21e5
-O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01"
0%-
T
T
T
41.0
38.0	39.0	40.0
Results: P. \P9400_P9499\P9464_6042 PCBVesources\P9464_6042_PCB_006RJ-Ol0.iitp_nes. saved 05-Aug-2008 09:19 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-038 cc 0)69. 9660
> | T I
42.0
1 I I | I 1
43.0
-t—r
Abs. Int.
-7.57e6
-3.79e6
-f-O.OOeO
44.0 RT
Peak annotation: Areas. Centmtds/
Revised: 04-Aug-2008 14:13:04 (EE! Printed: 0S-Aug-2008 09:22:59 Page 19 oUS
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Frt 6
427,7635
OcCB-6
40 3 69e3
44.02-49.21
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC; pcbx90_a Vial: 11
0%-
Rel. Int.
100%-
Fri 6
429.7606
OcCB-6
4o4.07e3
44.02-49.21
0%-
PCB-194
9.4466
46.53
PCB-195
3.77e6
44.58
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01_EQ
Abs. Int.
-2.12e6
45.0
46.0
PCB-205
1,42e6
46.92
^A-
2.93e5
48.39
47,0
i | t i——r~
48,0
-i	1	1	r-
PCB-195
4,07e6
PCB-194
1.04e7
45.0
46,0
-i	1	1	r-
-1—I—I—
48.0
3,26e5
48,39
i	|	1	1	r-
49.0
¦1.06e6
•O.OOeO
49.0 RT
Abs. Int.
2.35e6
•1.17e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
439.8038
OcCB Sid.
4n 3.34e3
44.02-49.21
0%-
45.0
46.0
JS-194
3.38e6
48.51
-t	t*	t		r	r	r	t1"
47.0
Abs. Int.
-1.04e6
•5.1805
48.0
i i 0. OOeO
49.0 RT
Rel. Int.
100%-
Fn 6
441.8008
OcCB Std.
4a 3.09e3
44.02-49.21
0%-
—i	1	1	r-
JS-J-34
46.51
45.0
46,0
47.0
48.0
49.0
Abs. Int.
-1,08e6
¦ 5.38e5
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
GC Check
44.02-49.21"
0%-
45.0
46.0
47,0
48.0
49.0
Abs. Int.
-6.31e6
¦3.15e6
•O.OOeO
RT
Results P:)P9400^P9499
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-UItima MM3
Rel. Int.
100%
Fn 6
461.7245
NoCB
4ct 2.39e3
44.02-49.21
0%-
Rel. Int.
100%-
Fn 6
463.7216
NoCB
4a 5.11e3
44.02-49.21
0%-
PCB-208
1,7366
PCB-208
2.25e6
44.38
PCB-207
1.34e6
45.17
45,0
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01_EQ
PCB-206
4.08e6
48,38
46,0
47.0
48.0
r~r
45.0


PCB-206


5,33e6


48.38
A
PCB-207


1.72e6


45.16
A

	A
-i—i—|—i
4S.0
Abs, Int.
-9.56e5
¦4.78e5
-O.OOeO
RT
Abs. Int.
-1.22e6
¦6.11e5
46.0
47,0
48.0
49.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
473.7648
NoCB Std.
4o1.69e3
44,02-49.21
0%-
Rel. Int.
100%-
Fn 6
475.7619
NoCB Std,
4o1.93e3
44.02-49,21
0%-
ES-208
4.80e6
45.0
45.0
l.94e5
48.84
"¦¦r	r	r	v	y	
46.0
47.0	48.0
-t	1 l n i	1——r-
ES-206
46.0
47.0
48.0
i	1 1 |	r-
2.10e5
48.84
Abs, Int.
-9.16e5
•4.58e5
¦O.OOeO
49.0 RT
r | i
49.0
Abs. Int.
-1.12e6
•5.60e5
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
44.02-49.21'
0%-
T
T
1—I—
45.0	46.0	47.0
Results: P:\P9400_P9499\P9464_6042 PCB\resourcesV9464_6042_PCB_006RJ-D 10 ulp_res, saved OS-Aug-2008 09:19 (EE)
AP USra Trace-Pro V3S93 User/System: EECEC2-038 cc: 1334, 7922
48.0
'—I—
49.0
Abs. Int.
-6.31e6
¦3.15e6
-O.OOeO
RT
Peak annotation: Areas, CentroUs
Revised: 04-Aug-2008 13:48:32 (EE) Printed: 0S-Aug-2008 09:23:01 Page 2yrfl22
-------
AP Lab ID: P9464_6042_PCB_006RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 7
497.6826
DeCB
4o 6.90e2
49.22-53.00
0%-
Sample ID: Run# I1-ACD-M23-2
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 11
49.5
PCB-209
3.0?e6
48.74
7.29e4
50.39
T-1-
1 I r
50.5
51.0
« | 1 f 1 t |
51.5
52.0
Rel, Int.
100%n

PCB-209
2 68e6
49.74
A
Fn 7 ;
499.6797 ¦
DeCB
4o 6.97e2 .
49.22-53.00 •

J\
0%-


1.38e5
50,39
Acq: 02-Aug-2008 00:22:22
User: CJL Datafile: 080802R01 EQ
Abs. Int.
-7.33e5
52.5
49.5
50.0
T** [It
50.5
| I I I 1 [ I
51,0
' I '
51.5
•••%	r	|	r"
52.0
52.5
T
3.67e5
-O.OOeO
53.0 RT
Abs. Int.
6.19e5
•3.09e5
•O.OOeO
53.0 RT
Rel. Int.
100%-,
Fn 7
509.7229
DeCB Std.
40 7.02e2
49.22-53.00
0%-
Rel. Int.
100%-
Fn 7
511.7199
DeCB Std.
4a 1 03e3
49.22-53.00
0%-
"¦i	j	r	f^r
49.5
49.5
50.0
liny	|llMBymi
50.5
51 0
51.5
i.3ie5
50.30
50.0
50.5
51.0
51.5
52.0
52,0
	i -1 i i | i i i i i ¦ O.OOeO
52.5
52.5
Abs, Int.
-1,02e6
5,11e5
53.0 RT
Abs. Int.
-8.37e5
•4.18e5
¦O.OOeO
53,0 RT
Rei. Int.
100%-
Fn 7
454.9728
QC Check :
49.22-53.00
0%-
t r | t i
49.5
—T—'«	1	|	T"
50.0
"T	*	i	|	r	r	rm
50.5
"• I	¦"
51.0
51.5
» | 1 I
52.0
-i—|—
T" I ' ' ' ' |
52.5
Abs, Int.
-6.45e6
•3.23e6
• O.OOeO
53.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6Q42_PCB_006RJ-D10Mtp_res, saved QS-Aug-2008 09:19 (EE)	Peak annotation: Areas, Centa'tfs
AP UltraTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 0385, 8431	~	Revised: 04-Aug-2008 13:49:30 (EE) Printed: 05-Aug-2OOB 09 23:02 Page 22vtp&'
-------
AP Lab ID; P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID; Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Oatafile: 080724V15_EQ
Rel. Int.
Fn 1 100%.
210.9856
QC (non-EQ)
9.03-13.00
Rel, Int.
Fn 2 100%
242.9856
QC (non-EQ
13.02-17.79'
Rel. Int.
Fn 3 100%.
292,9824
QC (non-EQ)
17.81-23.26
Rel. lot
Fn 4 100%.
330.9792
QC (non-EQ)
23.27-34.14
Rel. Int.
Fn 5 100%.
366.9792
QC (non-EQ)
34.16-41.15
Rel. Int.
Fn 6 100%
454.9728
QC (non-EQ)
41.17-46.41
Rel. Int.
Fn 7 100%-
454.9728
QC (non-EQ)
46.42-54.01
Abs. Int.
5.7387
L2.86e7
OOeO
10.5	
13.0 RT
Abs. Int
2,51e7
1,25e7
O.OOeO
Abs. Irit
2.73e7
-1.36e7
r	i	|	t	i	r	r	j	r	t	0.0080
Abs, Int
3.03e7
1.51e7
O,G0eu
34.0 RT
Abs. 3nt
5.25e6
-2.62e6
QOOeO
Abs. Int
9.53e6
4.76e6
-O.OOeO
Abs. int
1.29e7
B.46e6
O.OOeO
54.0 RT
Results: P:\P9400_P9499\P9464_E042 PCBtesaurces\P9464_6042_PCB_006.utp_rt>$, saved OS-Auq-2008 08:25 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-03B see 417-467
Peak annotation: Areas, Centmids
PKD: n/a Printed' OS-Aug-2008 08:31:56 Page 1 of 22
-------
AP Lab ID: P9464_6G42_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
Fn 1 100%.
218.8856
QC Check
a.03-13.00
0%Jt
-ir-
—i—i—j—i—i—!—i—|—i—i—!—i—]—i—r-
9.5
-i—I—i—i—i—r-
10.0
10.5
—!—i—i—|—i—i—!—r-
11.0
' I 	'	'	'	
11.5
12.0
• I '
12.5
Abs. Int.
-6.22e7
13.11e7
¦O.OOeO
13.0 RT
Rel. Int.
Fn 2 100%-
242.9856
QC Check
13.02-17.79
-wvyv-
' i i i i | i i i i | i i i i—|—r-
13.5
14.0
		 I ' i 1 ' I ' ' 1 ' I ' 1
14.5	15.0
-i—j—<—i—n—| i i—p—i—]—i i i—i—[—r-
15.5	16.0
16.5
1 I 1
17.0
—yw
1 I 1
17.5
Abs. Int.
-2.55e7
.1,2767
-O.OOeO
RT
Fn 3
Rel. Int.
100%-
292.9824
QC Check
17.81-23.26
0%.
18,0
19.0
20.0
-i	1	!	1	f	1	r-
21.0
22.0
I
23.0
Abs. Int.
-3.57e7
-1.78e7
¦O.OOeO
RT
Rel. Int
Fn 4 100%.
330.9792
QC Check
23,27-34.14
0%-i-r
24.0
—I—
26.0
-i—i	1—
28.0
t i—i i
30,0
—I—
32.0
1—r_
Abs, Int.
-5.88a7
¦2.9487
34.0
¦ O.OOeO
RT
Rel, Irrt.
Fn 5 100%
454.9728
QC Check
34.16-41.15
0%
Ads. int
2.93e?
1.47e7
O.OOeO
36.0
Rel. Int.
Fn 6 100%.
404.9760
QC Check
41.17-46.41
0%.
42.0
I
43.0
44.0
45.0
	1	<	<	r-
46.0
Abs. Int.
-2.16e7
1,08e7
¦O.OOeO
RT
Rel. Int.
Fn 7 100%
454.9728
QC Check
46.42-54.01
0%.
Abs. int
2.27e7
1.13e7
O.OOeO
54.0 RT
Results: P:\P940Q_P9499\P9464_6W2 PCB^esources\P9464_§042_PCB_m}6.utp_ms, saved QS-Aug-2Q08 08:25 (EE)
AP UltraTmce-Pro V3 993 User/System: E&EEC2-038
Peak annotation: Areas, Controids
PKD: n/3 Printed: 05-Aug-200808:31:57 Page 2 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2QG8 13:34:57
User: JLJ Datafile: 080724V15 EQ
Rel. Int.
100%-
Fn 1
188.0393
MoCB
4o 1.61e4
9,03-13.00
0%-
7.15e8
2.48e9 2.07e9
11-57 '11.75
I.73e9
II.45
8.7968
11.88
10.0
10.5	11.0
Abs. Int.
r3.70e8
1.85e8
O.OOeO
i | r r t r | t i i
12.5	13.0RT
Rel. Int.
100%-
Fn 1
190.0363
MoCB
4o 1.38e4
9.03-13.00
0%-
Rel. Int.
100%-
Fn 1
200.0795
MoCBStd. .
4o 2.69e4
9.03-13.00
0%-
9.89e5
9.18
-A
i r i> "f >fi
2.33ee
1.73e7
8,57e8 i.Q7e9
11.57 11.72
5.66e8
11.45
2.86ei
11.88
•\—f—I—I	1—|—|	1—|	1	1—|	1—I—|	1 1 T
10.0	10.5
11.0
—I—r"
11.5

|	'r11"!	T""iiM^	i	i	i	r	
10.0
10.5
¦ i ¦
11.0
11.5
12.5
3.24e5
12.39
12.5
Abs. Int.
-1.20e8
¦6.02e7
•O.OOeO
13.0RT
3.21e5
12.84
Abs. Int.
-4.86e6
•2.43e6
•O.OOeO
13.0 RT
Rel. Int.
100%
Fn 1
202.0766
MoCB Std.
4a 1,36e5
9.03-13.00
4.18e6
3.45e6
12,57
3.79e6 	 2®°8e|
13.0RT
Abs. Int.
-2.41eS
-1 21e6
OOeO
Rel. Int.
100%-,
Fn 1
218.9856
QC Check
9.03-13.00
0%-
9.5
10.0
1 ' I >
10.5
11.0
I I ' 1 ' ' I '
11.5
I ' ' ' ' I 1
12.0
1 I '
12.5
Abs. Int.
-6.22e7
3.11e7
¦O.OOeO
13.0 RT
-Results: P:\P9400_P94M\P9464_6042 PC8\nesovnxs\P9464_6042_PCB_{m,Mp_re$, saved 05-Aug-2008 08:25 (BE)
AP Ultra Trace-Pro V3M3 Use/System: EE/EEC2-038 cc: 5457, 8768
Peak annotation: Areas, Centmids
PKD: QS-Aug-2008 00:25:16 Printed: 0S-Aug-20W 08:31:58 Page 3 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxl 00_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafiie: 080724V15_EQ
Re I. Int.
100%-
Fn 1
222.0003
DiCB-1
4a 8.04e3
9.03-13.00
0%-
i r i i | i i i i | i t i i | i i f i | i i
9.5	10.0
i I t I I r j « r ! I | I I 1 p | I I I I ) I
10.5	11.0	11.5
1.95e6
12.14 ,
-j—; i i i ¦)["., "r ¦ v~r-
12.0
12.5
Abs. Int.
-2.80e7
¦1.40e7
•O.OOeO
13.0RT
Rel. Int.
100%n
Fn 1
223.9974
OiCB-1
40 3.06e4
9.03-13.00
0%-*-i—i—i—i—]—i—i—i—i—j—i—i—i—i—]—i—e—r—i—|—r-
9.5	10.0
2.B1e7
12,24
10.5
11,0
11,5
12.0
-i—i—|—i—>—i—i-p
12.5
Abs. Int.
-1.77e7
¦8.86e6
¦O.OOeO
13.0RT
Rel, Int.
100%-
Fn 1
234,0406
Dice Std.
4 o 1.67e4
9.03-13.00
0%-
1 68e6
12.06
i t | i i i e | i i i i | i ! i i | i i t i I i i i i f t i » t | » i i t | i i > > |
9.5	10.0	10.5	11.0
i i ( 'i 111 i	i	
11.5
12.0
T
12.5
T	t	»	1	1	1	1	1	i1"
Abs. Int.
-1.88e7
¦9.3886
¦O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std.
4o 1.16e4
9,03-13.00
0%-
I 1 T I | 1 ¦ I I | I I ! T j !
9.5	10.0
1 »¦ 'p-i t I ( T f l l | l l l l | T
10.5	11.0
5.99e5 7,29e5
11.95 12,12
11.5
12.0
' I '
12.5
Abs. Int.
-1.22e7
¦6.11e6
¦O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
218.9856
QC Check
9,03-13.00 J
Abs, Int.
-6 22e7
3.11e7
O.OOeO
13.0RT
Results: P:\P9400_P9499W94S4_6042 PCB\resourcesm464_e042_PCB_006.utp_res, saved OMug-2008 08:25 (EE}
AP UltraTmce-Pro V3 993 User/System: EE/EECZ-038 cc: 8351 6156
Peak annotation: Areas, Centroids
PKD: 05-Aug-200S 08:25:18 Printed: OS-Aug-2008 08:31:59 Page 4 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mmB GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
100%.
Fn 2
222,0003
DiCB-2
4a 3.93e4
13.07-17.79
0%-
, .,a0 2,S2e8
14J1 1430
1—I ' » "i—I I I
13.5
1.35e8
13.66
¦X\ "fN, i r i *
14.0
2 73e8
15.77
-rr-
14.5
-i—'—r-|—r—
15.0
15.5
i I i i i i I i t rr i I i r r" i I i
16,0	16.5
USea
16.79
6.35eo
16.53
1.03e8
17.0
Abs. Int.
r3.17e8
1 59e8
¦ I '
17.5
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
223,9974
DiCB-2
4o 4 88e4
13.07-17.79
0%-
8.74e7
i	«"*»—|	r	r""i	r	|	r
13.5
, ,T„D 1.63e3
1.37eB 14.30
1366	14.0*1
Afs.
14.0
1.79e8
15.77
1.28e9
16.79
14.5
15.0
15.5
16.0
4.11e8
16.53
7.52e7
7.02
16.5
17.0
1 I '
17.5
Abs. Int.
-2.06e8
1.03e8
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
234,0406
DiCB Std.
4a 1,82e4
13.07-17.79
0%-
4,01e7
13.65
h
i i [—i—r—r~i—| i 1 i \ |
13.5
1 33e7
17.01
-r—|—I—I I I—I—I I	I""i—]—1—I—r I—
14.0	14.5
15.0
i | f"i	> i |—'—i—>—'—j—i—i i i—|—i—i i i | i
15.5	16.0
Abs. Int.
-1.40e7
-7.01e6
—i—|—r—i i i 1 t 11 j > I i r	| i—i—r~i—[ i i—i—i—p*- O.OOeO
16.5	17.0	17.5	RT
Rel. Int.
2.49e7
100%-,
13.65
Fn 2


236,0376 -


DiCB Std. '


4a 1,98e4 .


13,07-17.79 ¦


0%-

I
13.5
8.35e6
17.00,
14.0
14.5
15.0
15.5
16.0
T»-
16.5
17.0
• i ¦
17.5
Abs. Int.
r9.23e6
¦4.61e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
13.07-17.79
Abs. Int.
-2.55e7
1.2767
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCBVesaurces\P9464_6Q42_PCB_006.utp_m$, saved 05.Aug-20Q8 08:25 (EE)
AP UltraTrace-Pm V3.993 User/System: EBEEC2-038 cc: 3623, 3727
Peak annotation: Areas, Centroids
PKD: 05-Aug-2008 08:25 18 Printed: OS-Aug-2008 08:32:00 Page 5 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15 EQ
Rel. Irit.
100%-
Fri 2
255.9613
TrCB-2
4o 5.60e3
13.02-17.79
Rel. Int.
100%-
Fn 2
257.9584
TrCB-2
4o 5.33e3
13.02-17.79
0%-
4.89e7
17.59
0%-^—I—>—I—|—r"
1.3167
14.65
'»' ' I	I	I" "T r 1 I 1" I' I Tl—J ! I I I | I f ! I f r r ! r f r I l I f T I I I | < ! I V | I I 1 f | I ! 1 ff j I
13.5	14.0	14.5	15.0	15.5	16.0
I I t T [ I 1 t I |
17.5	RT
I ' ' ' ' I '
13.5
¦ i • 1 ¦ ¦ i
14,0
1.30e7
14.65
i 1 T 1 ^ i 1 ¦ 1 1 i 1 ¦ 1 1 i ¦ 1 1 ' r
14.5
15.0
15.5
1.31C8
16.26
6,19e7
16.62
3.42e7
1.94e7 1705
16.79
1.27e8
18.26
o.08©7
16.62
4.77e7
17.59
3.29e7
1.91e7 JH'05
16.79
Abs. Int.
-2.52e7
•1.26e7
O.OOeO
Abs, Int.
-2.49e7
1.25e7
16.0
¦O.OOeO
RT
Rel. Int.
100%-
Fri 2
268,0016
TrCBStd.
4o 6.50e4
13.02-17.79
0%-
—r~i—f
13.5
2.65e6
13.62
ftl|ii»y|Ttit>1
14.0	14,5
2.0067
14.64
15.0
mj mi iii | i i
15.5
| I I " ff I "r| I 'I I "I1" I""!1
16.0
1.73e6
17.23
16.5
1 «[ i i i i | i i ru |
17.0
Abs, Int.
-6.07e6
¦3.03e6
17.5
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RT
Rel. Int.
100%-
Fn 2
269,9986
TrCB Std.
4o 3.94e4
13.02-17.79
0%-
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13.5
I.90e7
14,64
i i i'i '[ i i i t '| n i i11 pi	f	i	I"11 i t i | i i i i ¦ [ "r "i	i	i | i i i i )¦ i i "v i ft	rvTf
14.0	14.5	15.0	15.5	16.0
16.5
Abs, Int.
-5,9466
¦2.97e6
f i 1 i I i i r i' r I1'"1» | i1 I "f i ¦' O.OOeO
17.0	17.5	RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.02-17,79"
0%-
-i—I—i i i i i
13.5
i i i i i j i i
14.0
1 I 1
14.5
• I '
15.0
15.5
16.0
16,5
* t ¦
17.0

¦ i ¦
17 5
Abs. Int.
-2.5567
• 1,27e7
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCBVesources\P9464_6042_PCB_006 titp_res. saved 05-Aug-2008 08:25 (EE)
AP U/fra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 7089, 0455
Peak annotation: Areas.. Centmids
PKD: 05-Aug-2Q08 03:25:18 Printed: 0S-Aug-2008 08 32. 02 Page 6 of 22
-------
AP Lab ID: P9464_6042_PCB_Q06
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15„EQ
Rel. Int.
100%-
Fn 3
255-9613
TrCB-3
4o 1,76e4
17.81-23.26
0%-
3.41e7
18.49
/V
2.37e8
13.89
A
18.0
1.2360
19.08
/X
4,96e8
19.60
3 1868
4.60e8
19.77
19.0
i—p
20,0
2.07e8
20.12
A.
1.27e8
21.45
/V
3.10e8
22.24
21.0
1.05e8
21.75 2.60e7
/\ 22.07
22.0
5.09e8
22.96
6.6068
23.0
Abs, Int.
-1,65e8
8.24e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
40 1.35e4
17.81-23,26
0%-
1—I—1
18.0
3.34e7
18.49
T
'/x
2.29e8
18.89
1.20e8
19.08

4.46e8
19.77
19.0
4,80e8
19.60
3.09e8
19.35
2,02e8
20.12
A
1.27e8
21,45
3 10e8
22.24
1,01e8
21.75
/V
20.0
21.0
—I—1
22.0
6.48e8
22.97
6.47s8
22.62
Abs. Int.
-1.60e8
•8.01e7
1—**—i—¦— 0. OOeO
23.0 RT
Rel. Int.
100%-
Fri 3
268.0016
TrCBStd.
4o8.01e4
17.81-23.26
0%-
18.0
19.0
2.62e6
20.91
20.0
21.0
i | i
22.0
4,25e7
22.95
Abs. Int.
-1,24e7
•6.21e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
4o 4.25e4
17.81-23.26
0%-
—I—1
18.0
19.0
4,33e7
19.57
i i i
4.0487
22.95
Abs. Int.
- 1.18e7
•5.91e6
20.0
21.0
22.0
i ¦ i""—^—O.OOeO
23.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23,26
Abs. Int.
-3.57e7
1.78e7
O.OOeO
RT
Results. P:\P9400_P9499\P9464^6042 PC8tesouives\P9464_6042_PC8_006 ulp_res, saved 05-Aug-20QB 08:25 (EE)
AP UttraTrace-Pro V3.993 User/System: EEJEEC2-038 cc 8737. 7122
Peak annotation: Areas, Centroids
PKD: 05-Aug-2008 08:25 18 Printed: 0S-Aug-2008 08:32:03 Page 7 of 22
-------
AP Lab ID: P9464_6Q42_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15 EQ
Rel. Int.
100%
Fn 2
289.9224
TeCB-2
4o 3.13e3
13.02-17.79
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o 4.39e3
13.02-17.79
Abs. Int.
r 1.26e5
6.28e4
fJ-0.00e0
RT
3.65e5
17.45
1.64C4 2,0264
16.56 16.77

r ¦ i
7,39e5
17.43
3.07e4
13.86
rfYV
Abs. Int.
-1.67e5
-8.33e4
13.5
OOeO
Rel. Int.
100%-
Fn 2
301.9626
TeCB Std.
4a 8.35e3
13.02-17 79
0%-
Rel. Int.
100%-
Fn 2
303.9597
TeCB Std.
4o 5,36e3
13.02-17,79
0%-
9.33e6
17.42
13.S
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14.0
14.5
1 I "
15.0
-i—i i | i—i—r-r-
15.5
16.0
16.5	17.0
13.5
14.0
14.5
15.0
15.5
16.0
16.5
	'	I
17.0
1.2667
17.42
Abs. Int.
-2.38e6
1.19e6
-O.OOeO
RT
Abs. Int.
-2.99e6
-1,49e6
111 i—i—i—O.OOeO
17.5	RT
-f-
' ( '
16.0
" t "
17.0
i i ¦ | O.OOeO
17,5	RT
13.5
14-0
14,5
15-0
15,5
16.5
Re$ult$: P:\P94O0_P9499\P9464_6Q42 PC8\resources\P9464jS042_PCB_Q06.utp_ms, saved Q5-Aug-2008 08:25 fEE}
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-Q38 cc: 2725. 2191
Peak annotation: Areas. CenOwds
PKD: OS-Aug-2008 08:25:18 Printed: 0b-Aug-2008 08:32:04 Page 8 Of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JU Datafile: 080724V15_EQ
Re!. Int.
100%-
Fn 3
289.9224
TeCB-3
4c 4.29e3
17.81-23.26
0%-
18.0
2.9867
19.11
1—r-1
19.0
2 89e7	_
19_93
3.5760
21.14
1.4868
1.55e7
21.33
4.91e7
21.79
i
5.81e7
22.25
20.0
21.0
22.0
/v/\,
1,Q3e8
2.37 e7i
Abs. Int.
-7.81e7
•3,90e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4o 4.98e3
17.81-23.26
0%-
-i—|—i
18.0
3.83e7
19.11
3.75e7 ,c ,
19^ 1993
19.0
r i	i i i i
4.6QeH
21.14
1.8968
1.97e7
21.33
6.29e7
21.79
OX
21.98
7.53e7
22.25
20.0
21.0
22,0
A	A
1.32e8
23.02
3.11es
23.0
Abs. Int.
-1.01eB
•5.05e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
301.9626
TeCBStd,
4o 8,45e3
17.81-23.26
0%-
18.0
2.35e7
21.12
¦ *~ I 1 | I I I I | I I I I
19.0
riff
20.0
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21.0
| I	1 I I ' | I
22.0
23.0
Abs. Int.
-5.36e6
¦2.68e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
303.9597
TeCBStd.
4o 6.41e3
17.81-23.26
0%—I	1	1	I	!	T-
! I I I I I
18.0
19.0
20.0
3.0267
21.12
21.0
I I | I I I I |
22.0
Abs. Irit.
-6.77e6
-3.38e6
-O.OOeO
23,0	RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17,81-23.26
Abs. Int.
-3.57e7
1.78e7
O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\msaumes\P9464_6042_PC8_006.utp_res, saved G5-Aug-20O8 08:25 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 0693, 3134
Peak annotation: Areas, Centroids
PKD: 0S-Aug-2008 08:25:18 Printed: QS-Aug-2008 08:32:05 Page 9 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
100%-
Fn 4
289.9224
TeCB-4
4o 2.63e4
23.27-33.00
0%-
1.27eB
2 96e7 6.12e7 24,65
23.73 24.31
~T
rQ.o
24.31 ft
i	V
1.20e9
25.15
4.64e8
25.44
7.15e8
29.00
4.08e8
25.97
63e8
!8«15 3.26e7 4.94e72.g2e7
f\ 26j0 26JQ 27.23
2.3Se8
27,77 1 5968 14568
28.22 28.61

25.0
26.0
A
27.0
fyf
28.0
^rV-i -i i I
29.0
30,0
310
32.0
Abs. Int.
-2 00e8
9.99e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4cr 3.13e4
23.27-33.00
0%-
1,B4e8
3.89e7	24,65
23 73 24,31
T
¦r-i sy
24.0
24,31 A
1,50e9
25.15
5 95e8
25.44
8.87e8
29.07
5.26e8
25.97
:.11e8
B.15 .
Xi? I fVD 4.2667 5.23e7
JAA 26 60 26 89
27 78 2,06e8! 92e8
"1,24 28.60
25.0
i r i "T y i i | t ! r
26.0	27.0
A 28,24
/ k, A
28,0
-A
I
29.0
30.0
31.0
320
Abs. Int.
-2.54e8
1.27e8
O.OOeO
RT
Rel. Int.
100%-
Fn 4
301.9626
TeCBStd.
4o 1 94e4
23 27-33.00
0%-
4 83e7
29.06
2e6
M-15
i i I i r t ( | r i i r I r
24.0
25.0
	»'""l	|'""l	I	I"
26.0

riMi	tr"*		»¦¦¦¦*		t"IMi	f" i	jMMi	t"iMi	
27.0	28.0
29,0
30.0
' I '
31.0
—i—?—i—r—i—i—i—i—i i
32.0
Abs. Int.
-1.19e?
-5.97e6
¦O.OOeO
RT
Rel, Int
100%-
Fn 4
303.9597
TeCB Std.
4cr1.03e4
23.27-33.00
0%-
| i i i i | r r i
24.0
6,32e7
6 02e7 29;06
28,59
25.0
26.0
27,0
28.0
\ i i I i"i i i I i i i i I—i—i—i—i i i i i
29.0
30.0
31.0
Abs. Int.
-1.47e7
¦7.37e6
O.OOeO
¦ I ¦ 1 ¦ ' I ' 1 '
32.0	RT
Rel. Int.
100%-k-
Fn 4
330.9792
QG Check
23,27-33.00"
Abs. Int.
_r5.88e7
-2.94e7
0%-U
1 I I I I
i i I i i i i I -r-r-r-
i I » i i i | i i i i | i i > i | i
i i i t i—i j i \ i i 0 .OOeO
24.0
25,0
26.0
27,0
28.0
29.0
30.0
31.0
32.0
RT
Results. P:\P94G0_P9499\P9464^6042 PC8\f'e5.OUfXX'^lP9464_6042_PCB_006 (ltp_n?s. saved OS-Aug-2008 08:25 (BE)
AP UltmTmce-Pro V3.993 User/System: E&EEC2-038 oc: 9138.2878
Peak annotation: Areas. Centmi&s
PKD: 0S-Aug-2008 08:25: )8 Printed: 05-Aug-2008 08:32:06 Page 10 of 22
-------
AP Lab ID; P9464_6042_PCB_0Q6
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_c!1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Re I, Int.
100%-
Fn 3
323.8834
PeCB-3
4o 8.60e3
17.81-23.26
0%-
18.0
19,0
20.0
21.0
6.90eS
21,94
22.0
23.0
Abs. Int.
-1.67e6
¦8,33e5
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
40 1,44e4
17.81-23.26
0%-
18.0
19.0
3.94e5
20.35
4.62e5
20.91 2"kJ6
		 		
20.0
21.0


1-22e7


22.24
A
2.77e6


21.67
1.21e6
\
/\
21.04
./ V
1,33eS
3.2985 22.66
22.48 /X
i-"> / V
22,0
1—I—1
23,0
Abs. Int.
-2.70e6
1.35e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
337.9207
PeCB Std.
4o 5.91e3
1781-23.26
0%-
18.0
19.0
20.0
3,74e7
21.92
21.0
22.0
23.0
Abs, Int.
-8.14e6
•4,07e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
339.9177
PeCB Std.
4o 7 74e3
17.81-23.26
0%-
18.0
19.0
20,0
21.0
22.0
23,0
Abs. Int.
-5 08e6
¦2.54e6
¦O.OOeO
RT
Rel. Int.
100%'
Fn 3
292.9824
QC Check
17.81-23.26'
0%-
18.0
19.0
20,0
21,0
22.0
Results: P:\P940Q_P9499\P94e4_6042 PCB\m$oume$\P9464_6042_PCB_006.utp_re$, saved 0$-Aug-20QB 08:25 (EE)
AP UltraTrace-Pro V3 993 User/System EE/EEC2-038 cc 2435, 0366
23,0
Abs, Int.
-3,57e7
•1.78e7
•O.OOeO
RT
Peak annotation: Areas, Centmids
PKD 0S-Aug-2008 08:25:78 Printed: 05-Aug-200B 08:32:07 Page 11 of 22
-------
AP Lab ID:
P9464 6042 PCB
Instr: AutoSpec-Premier MM6
Rel. Int.

100%-,

Fn 4 :

323.8834 •
7.31e8
PeCB-4
24.43
4o 3.50e4 .
ft
23.27-34,14 ;

0%-
	/A,
1.12e8
25.14a
, a A
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
1.82e8
26.38
A
24.0
26.0
I.60e9
2B.52
I.i9e9
26.80
8.30eB
27.76

,28.78
LA
1.47e9
31.01
A
9.5Se7
. ^A44^ V31J0
6,07e7
0
Aeq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Abs. Int.
-2.88e8
6.83e8
31.98
4.73e7
33.23
28.0
30.0
32.0
1.44e8
-I— O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4

325.8804 •
1.18e9
PeCB-4
24.43
4o l.47e4
ft
23 27-34.14 ;

0%-
A
24.0
1.81e8
25.14 a
. a/\
1.93e9
26.89
2.96e8
26.38
. A ,
2.60el
28.51
7.04 e8
27.36
Si
26.0
J9e7
¥
l.7les
27,76
J j. 2.91
5?5e/ 28.3 >
M.
2.21 e8
28.78
V-A-r
2.37e9
31.01
28.0
1—r~
30.0
1.S4CB
30-44.
9.83e7
\J31.30
1.10S9
31.98

32.0
7.51e7
33.23
I			
Abs. Int.
-4.71 e8
2.36e8
•O.OOeO
1—r
34.0 RT
Rel. Int.
100%-
Fn 4
337.9207
PeCBStd.
4a 9.50e3
23 27-34.14
0%-
1—I—1
24.0
4.53e7
26.87
6.53e7
29.08
2 31 if.
28.nel
5 60e7
30.71
A
5.87e7
31.44
26.0
28.0
30.0
I , /. \
5.86e7
31.96
32.0
Abs. Int.
-1,40e7
•7.02e6
O.OOeO
->—¦—r
34.0 RT
Rel. Int.
100%-
Fn 4
339.9177
PeCBStd.
4o 1.16e4
23.27-34.14
0%-
i—|—i
24.0
I.09e6
25.95
» """I I
26.0
3.03e6
27.49
.	i..
4.33e7
29.08
2,27i 6
28.S5
-r-4-4
3,6le7
3.59e7
31.44
3.70e7
31.96
I .	J.
Abs. Int.
-9.10e6
•4.55e6
28.0
30.0
32.0
f i "i—r—j—*- 0. OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
24.0
26.0
28.0
30.0
32.0
Abs. Int.
-5.88e7
2.94e?
r—O.OOeO
34.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB'vesources\P9464_6Q42_PC8_006.utp_ms, saved 0S-Aug-20O8 08:25 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 8279. 8922
Peak annotation: Areas, Centroids
PKD: 05-Aug-2008 08:25:18 Printed: 05-Aug-2008 08:32:08 Page 12 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VS1R expt: pcb0405_c!1-10_jnm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15 EQ
Rel. Int.
100%-
Fn 5
323,8834
PeCB-5
4o 2,33e5
34,16-41,15
0%-
35-0
9,31e8
36.86
r-A
1.74e10
38,15
4,S0eB
39,24
36.0
37.0
38.0
39.0
40.0
Abs, Int.
-3.17e9
•1.58e9
O.OOeO
~4l!o RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4o 1 66e5
34.16-41.15
0%-
35.0
-1-r
2.1 ie9
36.86
36.0
I '
37.0
" I " 1 1 " I 1
38.0
i | i—i T"i—|—r
39.0
1.03e9
39.24
-<=Vi
40,0
Abs. Int.
-3.94e9
1 97e9
-O.OOeO
T
41.0 RT
Rel. Int.
100%-
Fn 5
337.9207
PeCBStd.
4o 4.03e4
34.16-41.15
0%-
35,0
36.0
37J
7.17e6
38.16
38,0
39.0
40.0
Abs. Int.
-1.33e7
6.64e6
•O.OOeO
41.0 RT
Rel, Int.
100%-
Fn 5
339.9177
PeCBStd.
4o 3.83e4
34,16-41.15
0%-
1.2386
34 J1
35.0
36.0
' 1	1
37.0
5.24e6
38.16
. ./X .
38.0
39.0
40.0
Abs. Int.
-8.64e6
¦4.32e6
O.OOeO
i ' ' ' ' I
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
35.0
36.0
37.0
38.0
39.0
40.0
41.0
Abs. Int.
-2.93e7
•1.47e7
¦O.OOeO
RT
Results: P:\P940Q_P9499\P9464^6042 PCBVesources\P9464_6042_PCB_00S.utp_res, saved 05-Aug-2008 08:25 (EE)
AP Ultmlrsce-Pro V3.993 User/System: EE/EEC2-038 cc: 5854, 9962
Peak annotation: Areas, Centmi&s
PKD: 05-Aug-2008 08 25:18 Printed: 05-Aug-2008 06:32:10 Page 13 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GO: pcbx100_a Vial; 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4o 5 97e3
23.27-34.14
0%-
24.0
26.0
2.67e8
27.29
A
4.70e8
29.29 8.65e7 |1l14e8
29.75 I $0 23
-A.
6.68e8
31.09
28.0
30.0
3.03e8
32.04
, A.
1.77e9
Abs. Int.
33f° r4.66e8
32.0
5.85e8
'33.10
-/W
UL
-2.33e8
¦O.OOeO
34.0 RT
Rel. Int.
100%-,
Fn 4
361.8385
HxCB-4
4a 7.52e3
23.27-34,14
0%-
24.0
26.0
2,i4e8
27.29
28.0
1.04e8
30.05
3.76eB
23.29 6.96e7 Jfl00e7
/\ 2975 /10.23
5.32e8
31.09
2.4le8
32.04
A
l.4ies
32.56
1-i? fir? Abs. Int.
33.60 -3.77e8
1,89e8
00e84-35e8
2 72 33.10
32.0
fix*
UV
•O.OOeO
34.0 RT
Rei. Int.
100%-
Fn 4
371.8817
HxCBStd,
4o 5.67e3
23.27-34.14
0%-
5.1487
26.66
	1 'm-f	1	y	f	|"	T	T	T
24.0	26.0
I
i i i | i i i —r | i i i i [ i
28.0	30.0
—r
4.34e7
32,54
32.0
Abs, Int.
3.82e? r9.77e6
33.58
•4.88e6
•O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
373.8788
HxCB Std
4o 1.12e4
23.27-34.14
0%-
24.0
4.09e7
26.66
3.12e5
28.75
"T—^	1
26.0
28.0
30.0
3.54e7
32.54
A
I
32,0
3.00e7
33.58
Abs. Int.
-7.80e6
•3.90e6
-j-—O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Abs. Int.
5 88e7
2.94e7
i	 O.OOeO
34.0 RT
Results: P:\P9400_P9499\PS4G4_6042 PCB\resources\P94$4_6042_PCB_006.utp_re$. saved 05-Aug-2008 08:25 (EE)
AP UitraTrace-Pro V3 993 User/System: EE/EEC2-038 cc 3126. 1717
Peak annotation: Areas, Centroids
PKD: 05-Aug-200B 08:25:18 Printed: 05~Aug-2Q0B 08:32:1? Page 14 of 22
-------
AP Lab ID: P9464_6042_PC8_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100„a Viai: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel Int.
100%-
Fn 5
359.8415
HxCB-5
40 7.54e4
34,16-41.15
0%-
4.10e8
35.0
2.73e7
35.27
- -
1.43e8
36.10
3.40e?
35^70
2.47e7
37.81
9.98e7 1,1**
39.31 39/1
36.0
37.0
38.0
39,0
40.0
Abs. Int.
-8.81e7
4,41e7
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4o 7.70e4
34.16-41,15
0%-
3,32e8
34.65
1.15eB
36.10
35.0

1.96e7 1.8Se7
37.81 38.22
7.37e7 93|%7
39.31	*
36.0
—|	11 11 r I	|	I ! "I 1 j I
37.0	38.0
39.0
40,0
Abs. Int.
r7.0Be7
¦3,54e7
•O.OOeO
t-T-
41.0 RT
Rel. Int.
100%-
Fn 5
371.8811
HxCB Std,
4o2.50e4
34.16-41.15
0%-
I I I I
I j I I I I | I I 1 ""T
35.0	36.0
37.0
—i—| "r*
38,0
39.0
I iiiii ¦¦¦¦>	> >	|	r
40.0
Abs. Int.
-1.71e7
• 8.54e6
i t i i i l i 0 .OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
373.8788
HxCB Std.
4o 3.91 e4
34.16-41.15
0%-
I I I f I I
35.0
3.02e7
36.08
1.99e6
38.17
36.0
37.0
38.0
39.0
40.0
Abs. Int.
-1.36e7
¦6.79e6
0 OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15'
0%-
I I I I
lilt
35.0
36.0
37.0
' I '
38.0
39.0
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_006.utp_nes. saved OS-Aug-2O0S 08:25 (EE)
AP UttraTrace-Pro V3.993 User/System: EBEEC2-038 cc: 08SS. 3788
40.0
Abs. Int.
-2.93e7
¦1.47e7
-j—i-*-O.OOeO
41.0 RT
Peak annotation: Areas. Centroids
PKD: 0S-Aug-2008 08:25:18 Printed: 05-Aug-200B 08:32:12 Page 15 at 22
-------
AP Lab ID; P9464_6042_PCB_006
Instr; AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VS1R expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Ju1-20Q8 13:34:57
User: JU Datafile: 080724V15_EQ
Rel. Int.
100%
Fn 4
393,8025
HpCB-4
4a 4.58e3
30.00-34.14
l.He8
6.04e7
31.89
6.47e7
32.43
4,5567
33.97
2,46e7
3.85eb
32.15
30.5
Abs, Int.
2.55e7
1.28e7
O.OOeO
RT
Rel. Int.
100%-
Fri 4
395,7995
HpCB-4
4o 3.54e3
30.00-34.14
0%-
T—J—f
30.5
5.02e6
30,70
-r~r~T-
4,55e7
31.41
1.30e8
1,06e8 31.89
31.72
'"i1	(""¦ i i i i {
31.0
3.40e7
33.97
2.68S7
4.71e6
32.15
Abs. Int.
-2.73e7
1,37e7
, > , ¦ O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
405.8428
HpCB Std,
4o 8,96e3
30.00-34.14
0%-
4.95e7
31.42
-t—|—i—i—i—! r" l—i—i—|—i—i—!—i—|—r-S—t—i—f—i—i—i—i—|—i—i—r—i—j—r-
30.5	31 0	31.5	32.0
3.52e7
Abs. Int.
-1.17e7
5.83e6
¦ O.OOeO
32.5
33.0
33,5
34.0 RT
Rel. Int.
100%-
Fn 4
407.8398
HpCB Std.
4a 8.28e3
30.00-34.14
0%-
I I I I J1 » I I I ( I I
30.5

4.73e7


31.42
fr.


A
3.31e7


33.95
A
1.54e8
\
l\
30.78
J V

31.0
31.5
32.0
32.5
33.0
33.5
Abs. Int.
-1.11e7
•5.55e6
¦O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
30.00-34.14
Abs. Int.
-5.88e7
2.94e7
I—i i | i i O.OOeO
34,0 RT
msu/ts: P:\P9400_P9499\P9464 6042 PC8\ne$oumes\P9464_6042_PC8 006.utp_ms. saved OS-Aug-2008 08:25 (EE)
AP UllraTrace Pro V3 993 User/System EEfcEC2-038 cc 1663, 1061
Peak annotation: Areas, Centmids
PHD: QS-Aug-2008 08:25:18 Printed: OS-Aug-2008 08:32:13 Page IS of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Viai: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
100%-
Fn 5
393,8025
HpCB-5
4cr 8.15e4
34.16-41.15
0%-
2.76e8
34.72
i.9ie7
34.49
1.22e8	. »
1*% a 1.1568
J ¦ A 35.79
AA.
JX.
8.81 e7
36.31
-4X
'I |—r"S—i—i—p—I—r—i 11 |—i—r^-i—T—[—i—!—i—i—|—¦—i—
35.0	36.0	37.0
5.64e7
37.67
2.38e7
38.50
2.47e8
39.25
38.0
39-0
40.0
Abs. Int.
-1,40e8
7.00e7
¦O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4a 6.83e4
34.16-41.15
0%-
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std.
4o2.13e4
34,16-41.15
0%-
2.6
34.72
1.87e7
34.49
1.17e8
35.23
' I •
35.0
35.23 A
A.A
1.11e8
35.79
	.A.	
8.43e7
36.31
uv
36.0
r ) i r r i
37.0
5.51e7
37.67
iiiijTTir|rtiijTYir
35.0	36.0
5.92e8
2,2767
38.50
4.79e7
38.19
2.36e8
39.25
35
7.20e7
39.69
/\
39.0
37.0
38.0
39.0
40.0
40,0
Abs. Int.
-1.36e8
¦6 82e7
•O.OOeO
Vo RT
Abs. Int.
1.25e7
6 25e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std._
4o 3.18e4
34.16-41.15
0%-
35.0
4.44e7
38.19
36.0
37.0
38.0
39.0
40.0
Abs. Int.
-1.21e7
•6.06e6
¦O.OOeO
TTo RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15
0%-
35.0
36.0
37.0
i i [ r
38.0
39.0
Results: P:\P9400_P9499\P9464_6042 PCSVesources\P9464_6042_PCB_006.u!p_res, saved 05-Aug-2008 08:25 (EE)
AP UitraTrace-Pro V3.993 User/System: EE/EEC2-038 CC: 9658. 0349
40.0
Abs. Int.
-2.93e7
•1.47e7
41.0
¦ O.OOeO
RT
Peak annotation: Areas, Centroids
PKD: 05-Aug-2008 08:25:18 Printed: Q5-Aug-2008 08:32:14 Page 17 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100._a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15..EQ
Rel. Int.
100%-
Fn 6
393.8025
HpCB-6
4g 3.97e4
41.17-46,41
0%-
6.15e5l;01ee
41.31^41-50
4.17e7
41.83
2j?7e6
42.0
1.14e7
44.04
8.22e6 9.50e84 ggeB
43.39 43.62 43j
7.71 e6
44.46
43.0
44,0
"*»—f
1,58e6
45.40
1.12e7
45.94
2 4087
46.22
45.0
i	i f i 1 j1
46.0
Abs. Int.
-8.53e6
•4.26e6
¦O.OOeO
RT
Rel. Int.
100%-
Fri 6
395.7995
HpCB-6
4o 3,55e4
41,17-46.41
0%-
4,12e7
41,83
l.3lee S82e5
41,41 41,03
8.10e6
44.05
1.02e7 8.91e6B77e6
43.38 43.62
7.5le6
44.47
2.58e7
1,09e7
45.94
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-8.39e6
•4.20e6
¦O.OOeO
RT
Rel. Int.
4 99e7
100%-,
41.82
A
Fn 6
A
405.8428 ¦

HpCB Std. :

4cr3.13e4

41.17-46.41 ;
j \
0%-

1.88e6
43.73
"T —f — f '
42.0
43.0
44.0
1.22e7
45.28
45.0
"1—r"
i—|—
46.0
Abs. Int.
-9.84e6
•4.92e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 6
407.8398
HpCB Std.
4c 5.27e4
41.17-46.41
0%-
41.81
42.0
1.11e8
43.73
4.89eB
45.28
.
43.0
44.0
45.0
I | I
46.0
Abs. Int.
-9.92e6
¦4,96e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41'
0%-
42.0
43,0
44.0
-i—|—i
45.0
Results: P:\P9400_P94mP9464_6042 PCBbr)SOurce$W464_6042_PCB_006 utp res. saved 0S-Aug-2008 08:25 (EE)
AP UiiraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 3018. 8804
46.0
Abs. Int.
-2,16e7
¦1.08e7
•O.OOeO
RT
Peak annotation: Areas, Centrotfs
PKD: 05-Aug-2008 08:25:18 Printed: 05-Aug-200B 08:32:15 Page 18 of 22
-------
AP Lab ID: P9464_6042_PCB_Q06
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405. cI1-10_mm6 GC: pcbx100_a Viaf: 64
Acq: 24-Jtil-2Q08 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
100%-
Fn 5
427.7635
OcCB-5
4a 1 76e4
34.16-41.15
0%-
5.02e6
34.46
5.27e6
35.01
35.0
2.25e7
35.90
36.0

2.67e7
8,28e6 3e-eS
36.40
7.63e6
3^\
37,0
38.0
39.0
1.00e8

39.83
n

ft
5.99e7
A
40.37 A
M
40.0
Abs. Int.
-2,04e?
• 1 02e7
-i—[ i 0. OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
429.7606
OcCB-5
4a 1,33e4
34.16-41.15
0%-
1.2467
34.46
t——p"T—i—r
r"?>
3.81e7 2.05e73||f
T
35.0
35.92
M
36.4I
1.1567 8,68e8
36.91	37.: "
36.0
I | 1 V
37.0
uucu
21
I ^1 I I1" I
38.0
39.0
' '~! '
40.0
40.37
Abs. Int.
r2.31e7
-1.16e7
i » ' ' > i
¦ O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
439.8038
OcCBStd.
4a 9.39e3
34.16-41.15
0%-
8.38e6
34.77
4.27e6
A	35.27
A. ,, a
35.0
9.1 Ie5
40.35
37.0
38.0
39.0
I 11 11 I '
40.0
Abs. Int.
-9.06e6
•4.53e6
O.OOeO
	r	r	r	i	
41.0 RT
Rel. Int.
100%-
Fn 5
441.8008
OcCB Std.
4a 1.20e4
34.16-41.15
0%-
1,28e7
34.77
.A.
r-1
35.0
6.33e6
35.26
i	i
-i—i—*t—r-
36.0
-i—|—i—i—i—i—|—i—i—i—r
37.0
38.0
39.0
40.0
Abs. Int.
-9 59e6
•4.80e6
, ¦ O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15
0%-
35,0
36.0
' I '
37,0
¦ I 1
38.0
I I I | I
39.0
40.0
Abs. Int.
-2.93e7
-1.47e7
I i O.OOeO
41.0 RT
Results: P:\P9400^P9499\P9464_6042 PCB\re$OurCe$\P9464_6042_PCB_006.utp^res, saved 05-Aug-2008 08:25 (EE)
AP UltraTrace-Pm VI993 User/System: EE/EEC2-038 cc: 2268. 1825
¦ Peak annotation: Areas. Cenlmids
PKD: 05-Aug-2Q08 08:25:1 fi Printed: OS-Aug-2008 08:32:17 Page 19 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpee-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mmB GC: pcbxl 00_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Dataflle: 080724V15_EQ
Rel, Int.
100%-
Fn 6
427.7635
OcCB-6
4o 1 ,Q3e4
41.17-46.41
0%-
3.31e7
41.63
42.0
43.0
8,41e7
43.58
1.20e7
43.96
44,0
45,0
46.0
Abs, Int.
-1,58e7
7.91e6
-i—#-O.OOeO
RT
Rel, Int.
100%-
Fn 6
429.7606
OcCB-6
4g1.30e4
41.17-46.41
0%-
3.65e7
41.63
42.0
43,0
9.20e7
43.58
1.29e7
43.96
44.0
45.0
46.0
Abs. Int.
-1.75e7
-8.77eS
O.OOeO
RT
Rel. Int.
100%-
Fn 6
439.8038
OcCB Std.
4a 1.52e4
41.17-46.41
0%-
42.0
3 37e7
2.t0e7
43.56
43.0
44.0
-•—1—r
45,0
46.0
Abs. Int.
-6.84e6
• 3.42e6
¦O.OOeO
RT
Rel, Int.
100%-
Fn 6
441,8008
OcCB Std.
4o 1,62e4
41,17-46.41
0%-
42.0
I i |
I | I I I » |
43.0
3.67e7
43.94
3.19e7
43,56
—i	1	r-
45.0
Abs. Int.
-7.58e6
•3.79e6
46.0
¦O.OOeO
RT
Rel, Int.
100%-j
Fn 6	f
404.5760
QC Check
41.17-46.41 .
Abs. Int.
_r-2,16e7
-1.0Be7
0%-
1—I—
42.0
43.0
44.0
45.0
46,0
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resourxxs\P9'S64_6042_PCB_006utp_res. saved 05-Aug-2008 08 25 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-038 cc 9973, 5377
Peak annotation: Areas, Centmkls
PKD 05-Aug-2008 08:25:18 Pnnted 05-Aug-200B 08:32:18 Page 20 of 22
-------
AP Lab ID; P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expt: pcb0405_cl1-10_mmB GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
100%-
Fn 6
461,7245
NoCB
4o6.47e3
41.17-46.41
0%-
1.40e7
41.43
1.0367
42.20
42.0
43.0
44.0
45.0
3,34e7
45.40
Abs. Int.
-7.47e6
•3.73e6
->—|—i—,—,—c-O.OOeO
46.0	RT
Rel. Int.
100%-
Fn 6
463.7216
NoCB
4a 7.03e3
41.17-46.41
0%-
1.3Se7
42.20
42.0
43.0
44.0
1—I—1—¦"
45.0
4.24e7
45.40
46.0
Abs. Int.
-9.55e6
•4,78e6
i * 0. OOeO
RT
Rel. Int.
100%-
Fn 6
473.7648
NoCBStd.
4 o 1,20e4
41.17-46.41
0%-
2.9367
41.41
42.0
"'I	¦»¦	'f		
43.0
1—r"
44.0
45.0
2.26e7
45.38
1,33e6
45.88
46.0
Abs. Int.
-6.16e6
¦3.08e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
475.7619
NoCB Std.
4a 7.91e3
41.17-46.41
0%-
3.67e7
41.41
42.0
43.0
44.0
45.0
I.2le6
45.87
46.0
Abs. Int.
r8.03e6
•4.02e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41
0%-
42.0
43.0
44.0
Results: P:\P9400_P9499\P9464_6042 PGBSre$ource$\P9464_6042_PCB_006.utp_ms, saved 05-Aug-2008 08:25 (EE)
AP UltraTrace-Pro V3 993 User/System: EE/EEC2-038 ce: 9275, 1636
45.0
46,0
Abs. Int.
-2.16e7
-1.08e7
¦O.OOeO
RT
Peak annotation: Areas. Centroids
PKD: 05-Aug-200B 08:25:18 Printed: 0S-Aug-2008 08:32:19 Page 21 of 22
-------
AP Lab ID: P9464_6042_PCB_006
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-2
VSIR expl: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 64
Acq: 24-Jul-2008 13:34:57
User: JLJ Datafile: 080724V15_EQ
Rel. Int.
100%-
Fn 7
497,6826
OeCB
4o 5 39e3
46,42-54.01
0%-
2,38e7
46.72
A
1.1Se6
47.32
47,0
48.0
49.0
50.0
! | I 1 I I j I I I I | I
51.0	52.0
) I I I I j I
53.0
Abs. Int.
-5.28e6
•2.64e6
•O.QOeO
54.0 RT
Rel, Int. 2 03e7
100%- 46*72
Fn 7
499.6797
DeCB
4o 5,05e3
46.42-54.01
0%-
I.77e6
47.32
i
»' » f * [ i i"» t |
47.0
48.0
49.0
50,0
I	'
51.0
* I ¦ ' ' 1 I
52.0
53.0
Abs. Int.
-4.56e6
2.28eS
•O.OOeO
54.0 RT
Rel. Int. 3:«e7
100%-, 46,70
Fn 7
509.7229
DeCBStd. J
4o 5.90e3 ~
46.42-54.01
0%-
9.83eS
47.24
¦¦¦¦I	1	r	|	rmi
47.0
48.0
49.0
7,16e6
50.52
f""i	i	r"
50.0
51.0
¦ i ' 1 1 1 i 1
52.0
53.0
Abs. Int.
-7.79e6
•3.89e6
¦O.OOeO
54,0 RT
Rel. Int. 2 99e7
100%- 4670
Fn 7
511.7199
DeCBStd.
40 7.74e3
46.42-54.01
0%-
1.48e6
47.24
¦ ,
47.0
-|	I	1—1—T	1 I 1 ( I J
48.0
5.36e6
50.52
-^rV
49.0
50.0
51.0
52.0
53.0
Abs. Int.
-6.50e6
•3.25e6
¦O.OOeO
54.0 RT
Rel. Int.
100%
Fn 7
454.9728
QC Check
46,42-54,01
47.0
48.0
49.0
I1 I I I I j I I I I |
50.0	51.0
52.0
Abs. Int.
-2.27e7
1,13e7
i—i—i—i—i—|—i—i—i—i—O.OOeO
53.0	54.0 RT
Results: P:\P94OO^P9<99\P9464_6042 PCBSng$auKe$\P94$4_6Q42_PCB_006.utp_res, saved 05-Aug-20Q8 08:25 (BE)
AP UttraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 7152, 7985
Peak annotation: Am as, Centmids
PKD: 05-Aug-2008 08:25:18 Printed: OS-Aug-2008 08:32:20 Page 22 Of 22
-------
Datafile: 080802R02_EQ
Acquired: 02 Aug 2008 01:17:17
Client ID: Run# II-ACD-M23-3 sj	Wt/Vol; 1
Lab ID: P9464_6042_PCB_007RJ-D10 A-level: 20 pg
PCB RCD CPSM 080801 PCB RB
Nominal ES spike: 4000 pg
F9464_6042_J>CB_007RJ-D10
Name
PCB-77 33'44'-TeCB
PCB-81 344'5-TeCB
PCB-105 233'44'-PeCB
PCB-114 2344"5-PeCB
PCB-118 23'44'5-PeCB
PCB-123 2'344'5-PeCB
PCB-126 33'44'5-PeCB
PCB-156/I57 233'44'5/233'44'5'
PCB-167 23'44"55"-HxCB
PCB-169 33'44'55'-HxCB
PCB-189 233'44'55*-HpCB
PCB-209 DeCB
Actual
RT
31.82^
31.35 /
34. 80/'"
34.26/
33.80 '
33.52 /
37.40/
39.94/.
38.97 ' ,
42.65 S
44.78 /
49.75 /
QC
Pred
Actual
Diff




Checkcode:
0t
RRT
RRT
Sees
Response
Ra
RRF /
Cone
Noise
DL
1.0006
1.0005
-0.2
3.35E+08
0.78
0
98y
122,000
5.05E+04
202
1.0006
1.0006
0
6.35E+07
0.78
1
03
25,600
5.Q5E+04
221
1.0007
1.0007
0
1.39E+08
0.62
0
90
63,600
8.10E+04
402
1.0007
1.0007
0
2.09E+07
0.60
0
90
9,510
8.10E+04
384
1.0007
1.0007
0
1.92E+08
0.61
0
90
83,700
8,10E+04
376
1.0007
1.0007
0
1.85E+07
0.60
0
91
8,420
8 .10E+04
394
1.0005
1.0005
0
1.96E+08
0.62
0
90
86,000
7.61E»04
359
1.0005
1.0003
-0.5
1.06E+08
1.22
0
97
51,700
1.50E+04
106
1.0006
1.0006
0
2.85E+07
1.28
0
99
14,300
l.SQE+04
78.4
1.0005
1.0005
0
3.52E+07
1.25
0
93
17,700
1.50E+04
81
1.0004
1.0004
0
2.78E+07
1.01
0
84
14,700
8.88E+03
47.9
1.0004
1.0004
0
8.40E+06
1.12
0
91
5,220
1.74E+03
12.1








/
Recv.


ES
PCB-1
11.28 *-
0.7213
0.7208
-0.3
1.50E+07
2.97
1.06
110 %
25%
150%
ES
PCB-3
13.47 '
0.8616
0.8614
-0.2
1.58E+07
2.69
1.00
123 %
25%
150%
ES
PCB-4
13.76
0.8771
0.8800
+2.4
1.01E+07
1.59
0.77
101 %
25%
150%
ES
PCB-15
19.29^
1.2330
1.2329
-0.1
1.25E+07
1.65
0.94
102 %
25%
150%
ES
PCB-19
16.71
1.0684
1.0681
-0.3
8.64E+06
1.14
0.67
100 %
25%
150%
ES
PCB-37
25.52
1.0809
1.0807
-0.3
1.03E+07
1.10
0.99
108 %
25%
150%
ES
PCB-54
19.57
0.8279
0.8286
+0.8
8.70E+06
0. 83
1.00
90.6 %
25%
150%
ES
PCB-77
31.81 -
1.3474
1.3469
-1.0
1.12E+07
0.81
0.88
131 %
25%
150%
ES
PCB-81
31.33 ^
1.3274
1.3268
-1.1
9.59E+06
0.80
0.84
119 %
25%
150%
ES
PCB-104
24.46 ^
0.8277
0.8278
+0.1
9.55E+06
1. 57
1.28
85.6 %
25%
150%
ES
PCB-105
34.77 -
1.1769
1.1767
-0.4
9.67E+06
1. 61
1.19
93.4 %
25%
150%
ES
PCB-114
34.24 ^
1.1587
1.1585
-0.4
9.77E+06
1. 54
1.17
95.8 %
25%
150%
ES
PCB-118
33.78v
1.1432
1.1430
-0.4
1.02E+07
1.56
1.23
95 %
25%
150%
ES
PCB-123
33.50 ^
1.1338
1.1336
-0.4
9.67E+06
1.48
1.13
98.7 %
25%
150%
ES
PCB-126
37.38
1.2652
1.2650
-0.4
1.01E+07
1.56
1.20
96.8 %
25%
150%
ES
PCB-153
35.36^
0.9711
0.9711
0
8.99E+06
1.23
1.15
99.3 %
25%
150%
ES
PCB-155
29.38 ^
0.8067
0.8069
+0-4
1.06E+07
1.27
1.47
91-8 %
25%
150%
ES
PCB-156/157
39.92
1.0964
1.0963
-0.2
1.69E+07
1.23
1.31
82 %
25%
150%
ES
PCB-167
38.95 ^
1.0696
1,0696
0
8.09E+06
1.30
1.2S
82.5 %
25%
150%
ES
PCB-169
42.64 "
1.1709
1.1708
-0.3
8.60E+06
1.27
1.33
82.5 %
25%
150%
ES
PCB-170
41.09 '
0.8833
0.8833
0
7.95E+06
1.04
1.13
103 %
25%
150%
ES
PCB-180
42.14 "
0.9060
0.9060
0
6,36E+06
1.06
0.91
102 %
25%
150%
ES
PCB-188
34.23 '
0.7359
0.7359
0
9.27E+06
1.07
1.18
99.8 %
25%
150%
ES
PCB-189
44.76
0.9621
0.9621
0
9.08E+06
1.05
1.30
103 %
25%
150%
ES
PCB-202
38.76 ^
0.8332
0.8331
-0.2
8.26E+06
0.96
1.20
87.8 *
25%
150%
ES
PCB-205
46.92 "
1.0086
1.0085
-0.3
7.75E+06
0.90
1.11
102 %
25%
150%
ES
PCB-206
48.38 "
1.0400
1,0399
-0.3
5.31E+06
0.81
0.79
98.6 %
25%
150%
ES
PCB-208
44.37
0.9539
0.9538
-0.3
7.27E+06
0.77
1.07
99.2 %
25%
150%
ES
PCB-209
49.73 ^
1.0692
1.0691
-0.3
7.10E+06
1.1S
1.06
98.5 %
25%
150%
Analytical Perspectives
Page 1 of 5
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_007RJ-D10
Name
SS FCB-28
SS PCB-111
SS PCB-178
CS PCB-28
CS PCB-111
CS PCB-178
Actual
RT
22.01 *
31.er'
36. 79'""
QC
Pred
RRT
0.9320
1.0774
1.0105
22. 01/*
31.84/*
36,79^
0.9320
1.0774
1.0105
JS	PCB-9
JS	PCB-52
JS	PCB-101
JS	PCB-138
JS	PCB-194
15.64
23 .62"'"
29.55 '
36.41 ~
46.52
Checkcode:
0i

PCB-1 2-MoCB
11.29
1.0011
PCB-2 3-MoCB
13 .31
0.9879
PCB-3 4-MoCB
13.49
1.0010
PCB-4 22'-DiCB
13 .78
1.0011
PCB-10 26-DiCB
NotFnd
1.0138
PCB-9 25-DiCB
15.66
1.0010
PCB-7 24-DiCB
15.81
1.0113
PCB-6 23'-DiCB
16.03
1.0254
PCB-5 23-DiCB
16.33
1.0441
PCB-8 24'-DiCB
16.44
1.0516
PCB-14 35-DiCB
17.97
0.9319
PCS-11 33'-DiCB
18.74
0.9715
PCB-13/12 34'-/34-DiCB
19.03
0.9863
PCB-15 44'-DiCB
19 .30
1.0008
PCB-19 22'6-TrCB
16.72
1.0011
PCB-30/18 246-/22'S-TrCB
18.46
1.1044
PCB-17 22'4-TrCB
18.85
1.1279
PCB-27 23'6-TrCB
19.03
1.1393
PCB-24 236-TrCB
19.17
1.1471
PCB-16 22'3-TrCB
19.26
1.1527
Analytical Perspectives
Actual
Diff





Checkcode;
01
RUT
Sees
Response
Ra
RRF
, Cone
Noise
DL
0.9320
0
1.19E+0?
1.10
1.
07 V
109 %
30%
135%
1.0772
-0.4
1.21E+07
1.55
1.
18
106 %
30%
135%
1.0104
-0.2
6.32E+06
1.06
0.
66 /
103 %
30%
135%
0.9320
0
1.19E+07
1.10
1.
J
05
118 %
30%
13 5%
1.0772
-0.4
1.21E+07
1.55
1.
33
105 %
30%
135%
1.0104
-0.2
6.32E+06
1.06
0.
78
103 %
30%
135%


1.29E+07
1.62







9.61E+06
0.78







8.69E+06
1.55







7,87E+06
1.27







6.82E+06
0.87






Totals
NON-EMPC

EMPC
DL



Mono-CBs
1,380,000
1
380
000
27.9



Di-CBs
583,000

583
000
47.2



Tri-CBs
606,000

606
000
74.3



TeCra-CB:
685,000

685
000
98.1



Penta-CB:
734,000

734
000
327



Hexa-CBs
383,000

383
000
72.7



Hepta-CB:
122,000

122
000
59.9



Octa-CBs
44,500

44
500
39.6



Nona-CBs
13,600

13
600
, 54


1.0011
0
1.09E+09
3.10
1
09 IJ
267,000
1.59E+04
24.2
0.9878
-0.1
2.74E+09
3,10
1
01
687,000
1.59E+04
34.3
1.0010
0
1.85E+09
3.09
1
09
427,000
1.59E+04
31.6
1.0009
-0.2
2.78E+07
SI*
0
98
11,300
7.43E+03
22
-

O.OOE+OO

1
55

7.43E+03
13.9
1.0010
0
6.34E+07
SI*
0
94
21,600
2.14E+04
70.4
1.0109
-0.4
6.90E+07
SI*
0
90
24,500
2.14E+04
73.5
1.0249
-0.5
9.79E+07
SI*
0
89
35.100
2.14E+04
74.2
1.0437
-0.4
9.94E+07
SI*
0
87
36,500
2.14E+04
76
1.0511
-0.5
9.83E+07
SI*
0
91
34,500
2.14E+04
72.6
0.9316
-0.3
9.21E+07
SI*
1
02
29,100
2.14E+04
65.3
0.9717
+ 0.2
1.76E+08
SI*
0
87
65,300
2.14E+04
76.7
0.9868
+ 0.6
7.57E+08
SI*
0
85
286,000
2.14E+04
78.3
1.0009
+ 0.1
1.10E+08
SI*
0
92
38,600
2.14E+04
72. 5
1.0009
-0.2
6.38E+06
1.04
0
91
3,240
5.20E+03
23.4
1.1049
+ 0.6
5.11E+07
1.03
1
03
22,900
5.20E+03
20.7
1.1282
+ 0.3
2.87E+07
1.04
0
89
14,900
5.20E+03
24
1.1392
-0.1
1.01E+07
1.01
1
22
3,830
5.20E+03
17.4
1.1471
0
1.36E+07
1.04
1
20
5,250
5.20E+03
17.8
1.1526
-0.1
2.71E+07
1.02
0
69
18,200
5.20E+03
31
Page 2 of 5
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PC8_007RJ-D10
Actual

Pred
Actual
Nam*

RT
QC

RRT

RUT
FCB-32
24 * 6-TrCB
19
.74

1
1809
1
.1812
PCB-34
2¦35-TrCB
20
.87

0
8174
0
8176
PCB-23
235-TrCB
21
01

0
8231
0
8233
FCB-26/29 23'5-/245-TrCB
21
29

0
8341
0
8342
PCB-25
23•4-TrCB
21
48

0
8417
0
8418
PCB-31
24'5-TrCB
21
76

0
8525
0
8527
PCB-28/20 244'-/233'-TrCB
22
04

0
8634
0
8634
PCB-21/33 234-/2'34-TrCB
22
22

0
8703
0
8706
PCB-22
234'-TrCB
22
59

0
8848
0
8849
PCB-3 6
33'5-TrCB
23
96

0
9386
0
9387
PCB-39
3415-TrCB
24
27

0
9510
0
9510
PCB-38
345-TrCB
24
79

0
9715
0
9715
PCB-35
3314-TrCB
25
18

0
9868
0
9868
PCB-37
344'-TrCB
25
54

1
0007
1
0007
PCB-54
22'66'-TeCB
19
59

1
0010
1
0012
PCB-50/53 22'46-/22'56'TeCB
21
52

0
9119
0
9112
PCB-45
22'36-TeCB
22
11

0
9362
0
9363
PCB-51
22'46'-TeCB
22
18

0
9393
0
9394
PCB-46
22'36'-TeCB
22
39

0
.9481
0
9479
PCB-52
22'55'-TeCB
23
64

1
.0010
1
0010
PCB-73
23'5"6TeCB
23
77

1
0065
1
0065
PCB-43
22'35-TeCB
23
86

1
0103
1
0102
FCB-69/49 23'46-/22*45'TeCB
24
07

1
0185
1
0192
PCB-48
22'4 5-TeCB
24
33

1
0303
1
0301
PCB-44/47/65 22135'-/22 ' 44 ' -
24
52

1
0393
1
0382
PCB-59/62/75 233"6-/2346-/24
24
80

1
0510
1
0503
PCB-42
22'34•-TeCB
24
98

1
0578
1
0576
PCB-41
22'34-TeCB
25
30

1
0717
1
0714
PCB-71/40 23'4'6/22'33'-TeCB
25
40

1
0758
1
0754
FCB-64
234'6-TeCB
25
60

1
0841
1
0840
PCB-72
23'55'-TeCB
26
32

0
8397
0
8400
PCB-68
23'45'-TeCB
26
57

0
8478
0
8481
PCB-57
233'5-TeCB
26
94

0
8595
0
8597
PCB-58
233'5'-TeCB
27
14

0
8659
0
8661
PCB-67
23'4b-TeCB
27
29

0
8709
0
8711
PCB-63
234'5-TeCB
27
52

0
8780
0
8782
PCB-fil/70/74/76 234S-/23'4'5
27
80

0
8872
0
8873
PCB-66
23'44'-TeCB
28
08

0
8961
0
8963
PCB-55
233"4-TeCB
28
22

0
9007
0
9008
PCB-56
233'4'-TeCB
28
66

0
9145
0
9146
PCB-60
2344'-TeCB
28
85

0
9206
0
9206
PCB-80
33'55'-TeCB
29
18

0
9314
0
9315
PCB-79
33'451-TeCB
30
49

0
9732
0
9732
PCB-78
33-45-TeCB
30
97

0
9886
0
9884
PCB-104
22'466'-PeCB
24
49

1
0009
1
0011
PCB-96
22'366'-PeCB
24
80

1
0136
1
0137
PCB-103
22'45'6-PeCB
26
49

0
8961
0
8962
Analytical Perspectives
Page 3 of 5
Diff




Checkcode .-
01
Sees
Response
Sa
REF
Cone
Noise
DL
+0.4
2.35E+07
1.05
1.28
8,500
5.20E+03
16.7
+ 0.3
1.35E+07
1.05
1.13
4,650
3.06E+04
107
+0.3
3.37E+07
1.06
1.06
12,300
3.06E+04
113
+0.1
8.85E+07
1.03
1.13
30,400
3.06E+04
106
+0.1
4.45E+07
1.04
1.25
13,800
3.06E+04
96.1
+ 0.3
8.23E+07
1.05
1.16
27,600
3.06E+04
104
0
1.70E+08
1.05
1.13
58,400
3.06E+04
106
+ 0.4
1.75E+08
1.04
1.10
61,600
3.06E+04
109
+0.1
7.44E+07
1.06
1.09
26,400
3.06E+04
110
+ 0.1
4,00E+Q7
1.07
1.14
13,600
3.06E+04
105
0
3.64E+07
1.05
1.12
12,700
3.06E+04
107
0
1.59E+08
1.06
1.04
59,500
3.06E+04
115
0
2.67E+08
1.04
1.04
100,000
3.06E+04
116
0
2.65E+08
1.04
0.96
108,000
3.06E+04
125
+0.2
3.67E+05
0.78
1.18
142
3.55E+03
13
-0.9
9.14E+06
0.78
0.93
4,110
5.55E+03
27.1
+0.1
9.57E+06
0.77
0.71
5,590
5.55E+03
35.2
+0.1
3.08E+06
0.77
1.00
1, 280
5.55E+03
25.1
-0.3
3.87E+06
0.74
0.73
2,200
5.55E+03
34.2
0
9.23E+07
0.77
0.91
42,300
5.55E+03
27.6
0
1.63E+06
0.76
1.17
583
5.55E+03
21.5
-0.1
6.99E+06
0.75
0.71
4,100
5.55E+03
35.3
+1.0
4.71E+07
0.78
1.05
18,700
5.55E+03
24
-0.3
1.73E+07
0.76
0.86
8, 420
5.55E+03
29.3
-1.6
7.67E+07
0.77
0.92
34,600
5.55E+03
27.2
-1.0
2.96E+07
0.77
1.19
10,400
5.55E+03
21.2
-0.3
2.50E+07
0.77
0.80
13,000
5.55E+03
31.3
-0.5
1.44E+07
0.77
0.73
8,170
5.55E+03
34 .3
-0.6
4.48E+07
0.77
0.93
20,000
5.55E+03
26.9
-0.2
3.75E+07
0.77
1.24
12,600
5.55E+03
20.4
+0.5
7.63E+06
0.78
1.05
3,040
5,05E+04
219
+0.5
1.07E+07
0.77
1.09
4, 090
5.05E+04
210
+0.3
2.27E+07
0.75
1.01
9,330
5.05E+04
225
+0.3
1.67E+07
0.78
0.99
7,020
5.05E+04
230
+0.3
3.82E+07
0.77
1.09
14,700
5.05E+04
210
+0.3
2.05E+07
0.79
1.07
7,960
5.05E+04
213
+ 0.2
2.54E+08
0.77
1.02
104,000
5.05E+04
224
+ 0.3
1.09E+08
0.78
1.03
44,300
5.05E+04
222
+0.2
4.22E+07
0.77
0.94
18,800
5.05E+04
244
+ 0.2
1.31E+08
0.78
1.01
53,900
5.05E+04
226
0
4.30E+07
0.78
1.00
18,000
5.05E+04
229
+0.2
5.99E+06
0.80
1 ,08
2, 310
5.05E+04
212
0
8.30E+07
0.78
1.13
30,600
5.05E+04
202
-0.4
7.48E+07
0.87
0.94
33,300
5.05E+04
244
+0.3
3.78E+05
0.58
1.06
150
1.22E+04
46.2
+0.1
1.86E+06
0.59
0.89
870
1.22E+04
56.9
+0.2
1.35E+06
0.61
0.76
733
8.10E+04
469
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_007RJ-D10
Actual

Pred
Actual
Name
ET
QC
RRT
RRT
PCB-94 22'356'-PeCB
26.67

0.9024
0.9025
PCB-95 22'35'6-PeCB
27.05

0.9151
0.9152
PCB-100/93 22-44'6-/22'356-P
27.26

0.9224
0.9223
PCB-102 22'4561-PeCB
27.37

0.9262
0.9260
PCB-98 22'3'46-PeCB
27.44

0.9284
0.9205
PCB-88 22'346-PeCB
NotFnd

0.9385
-
PCB-91 22'34'6-PeCB
27.79

0.9407
0.9403
PCB-84 22'33'6-PeCB
27.98

0.9469
0.9469
PCB-89 22'346'-PeCB
28.40

0.9610
0.9610
PGB-121 23'45'6-PeCB
28.76

0.9730
0.9730
PCB-92 22'355'-PeCB
29.07

0.9837
0.9836
PCB-113/90/101 233 ' 5 ' 6-/22 ' 3
29.57

0.9999
1.0007
PCB-83 22'33•5-PeCB
29.97

1.0143
1.0143
PCB-99 22'44"5-PeCB
30.08

1.0176
1.0178
PCB-112 233'56-PeCB
30.18

1.0211
1.0213
PCB-108/119/86/97/125/87 233
30.53

1.0328
1.0331
PCB-117 234'56-PeCB
31.05

1.0506
1.0505
PCB-116/85 23456-/22'344'-Pe
31.12

1.0536
1.0531
PCB-110 233'4'6-PeCB
31.25

1.0577
1.0575
PCB-115 2344'6-PeCB
31.34

1.0605
1.0604
PCB-82 22'33'4-PeCB
31.53

1.0671
1.0669
PCB-111 233'55'-PeCB
31.86

1.0782
1.0780
PCB-120 23'455'-PeCB
32 .25

1.0915
1.0914
PCB-107/124 233'4'5-/2'3455'
33 .21

0.9913
0.9914
PCB-109 233'46-PeCB
33 .42

0.9976
0.9977
PCB-106 233'45-PeCB
33 .63

1.0039
1.0038
PC3-122 2'33'4 5-PeCB
34 .09

1.0093
1.0092
PCB-127 33'455'-PeCB
36.04

1.0363
1.0363
FCB-155 22'44'66'-HxCB
NotFnd

1.0007
-
PCS-152 22'3566'-HxCB
29.56

1.0060
1.0060
PCB-150 22'34'66'-HxCB
29 .70

1.0109
1.0109
PCB-136 22'33'66'-HxCB
30.00

1.0210
1.0210
PCB-145 22'3466'HxCB
30.27

1.0302
1.0301
PCB-148 22'34'56'-HxCB
31.55

1.0730
1.0738
PCB-1S1/135 22'355'6-/22'33'
32 .06

1.0913
1.0911
PCB-154 22'44'5'6-HxCB
32.27

1.0985
1.0983
PCS-144 22 ' 345 ' 6-ltxCB
32 .53

1.1073
1.1071
PCB-147/149 22'34'56-/22'34'
32.83

1.1175
1.1172
PCB-134 22'33'56-HxCB
33.00

1.1234
1.1232
PCB-143 22'3456'-HxCB
33.09

1.1262
1.1261
PCB-139/140 22'344'6-/22'344'
33. 34

1.1351
1.1348
PCB-131 22'33'46-HxCB
33.54

1.1408
1.1415
PCB-142 22'3456-HxCB
NotFnd

1.1456
-
PCB-132 22'33'46'-HxCB
33. 89

1.1537
1.1535
PCB-133 22'33'55'-HxCB
34. 31

1.1679
1.1677
PCB-165 233'55'6-HxCB
34.65

0.9514
0.9515
PC5 146 22'34'55'-HxCB
34. 86

0.9573
0.9573
Analytical Perspectives
Page 4 of 5
Diff




Checkcode:
01
Sees
Response
Ra
RRF
Cone
Noise
DIt
+ 0.2
1.21E+06
0.57
0.65
766
8.10E+04
548
+0.2
7.54E+07
0.62
0.71
44,000
8.10E+04
505
-0.2
2.93E+06
0.65
0.74
1, 630
8.10E+04
483
-0.3
3.99E+06
0.66
0.74
2, 240
8.10E+04
487
+ 0.2
1.39E+06
0.70
0.64
890
8.10E+04
556

0.00E+00

0.72

8.10E+04
498
-0.7
1.68E+07
0.62
0.66
10,600
8.10E+04
543
0
2.69E+07
0.63
0.60
18,500
8.10E+04
595
0
2.19E+06
0.60
0.64
1, 410
8.10E+04
556
0
1.36E+06
0.65
0.95
590
8.10E+04
375
-0.2
1.91E+07
0.60
0.69
11,500
8.10E+04
519
+ 1.4
1.26E+08
0.62
0.79
65,900
8.10E+04
452
0
2.06E+07
0.57
0. 53
16,100
8.10E+04
675
+ 0.4
5.20E+07
0.62
0.80
26,700
8.10E+04
445
+ 0.4
3.54E+06
0.63
0. 93
1, 570
8.10E+04
383
+ 0.5
1.35E~08
0.61
0.79
70,500
8.10E+04
451
-0.2
6.76E+06
0.61
0 ^ 87
3, 210
8.10E+04
410
-0.9
2.82E+07
0.61
0.78
14,900
8.10E+04
457
-0.4
1.67E+08
0.62
0. 89
77,900
8.10E+04
404
-0.2
9.20E+06
0.61
0.96
3, 980
8.10E+04
375
-0.4
3-53E+07
0.62
0. 56
26,000
8.10E+04
637
-0.4
7.05E+06
0.60
0.95
3, 080
8.10E+04
378
-0.2
1.05E+07
0.59
0.96
4, 520
8.10E+04
373
+0.2
2.75E+07
0.62
0.93
12,300
8.10E+04
386
+0.2
5.54E+07
0.61
0. 99
23.200
8.10E+04
362
-0.2
2.22E+07
0.59
0.91
10,100
8.10E+04
396
-0.2
3.72E+07
0.60
0.84
18,100
8.10E+04
413
0
2.23E+07
0.59
0.80
10,500
8.10E+04
413

0.00E+00

1.04

7.03E+03
25.3
0
7.82E+05
1.28
0.98
301
7.03E+03
26.8
0
1.18E+06
1.12
0. 94
472
7.03E+03
27.8
0
1.57E+07
1.23
0.92
6, 400
7.03E+03
28.4
-0.2
9.94E+05
1.17
0.92
407
7.03E+03
28.6
0
1 -52E+06
1,11
0.90
756
7.03E+03
35.9
-0.4
2.67E+07
1.25
0. 91
13,100
7.03E+03
35.5
-0.4
2.78E+06
1.25
1.05
1,180
7.03E+03
30.6
-0.4
5,95E+06
1.23
0. 94
2, 810
7.03E+03
34.1
-0.6
6.98E+07
1.24
0. 94
32,900
7.03E+03
34
-0.4
8.29E+06
1.23
0.79
4, 690
7.03E+03
40.9
-0.2
1.79E+06
1.24
0. 83
959
7.03E+03
38.6
-0.6
7,50E+06
1.27
0. 92
3, 640
7.03E+03
35.1
+1.4
8.34E+06
1.21
0.78
4, 760
7.03E+03
41.2

0.00E+00

0. 80

7.03E+03
40.4
-0.4
3.70E+07
1.23
0. 83
19,900
7.03E+03
38.9
-0.4
4.14E+06
1.25
0.86
2,150
7.03E+03
37.4
+0.2
2 .58E+06
1.25
1.09
1, 050
7.03E+03
29.4
0
2.13E+07
1.29
0. 98
9, 700
7.03E+03
32. 9
Printed: 08 06 2008 1:22 PM
-------
P9464_6042_PCB_007RJ-D10
Name
Actual
RT
QC
Fred
RRT
Actual
RRT
PCB-161
233'45'6-HxCB
34,98
0.9605
0.9605
PCB-153/168 22"44"55'-/23"44'
35.38
0.9722
0.9717
PCB-141
22'3455'-HxCB
35. 54
0.9761
0.9761
PCB-130
22'33'45"-HxCB
35.89
0.9855
0.9857
PCB-137
22'344'5-HxCB
36.08
0.9910
0.9909
PCB-164
233*4<5'6-HxCB
36.17
0.9933
0.9932
PCB-163/138/129 233•4•56-/22'
36.45
1.0011
1.0009
PCB-160
233'456-HxCB
36. 59
1.0048
1.0049
PCB-158
233'44'6-HxCfl
36.77
1.0098
1.0098
PCB-128/166 22•33'44'-/2344 ' 5
37. 51
0.9629
0.9630
PCB-159
233'455'-HxCB
38,33
0.9840
0.9840
PCB-162
233'4'55'-HxCB
38, 56
0.9902
0.9902
PCB-188
22'34'556'-HpCB
34.25
1.0006
1.0003
PCB-179
22'33'566'-HpCB
34.53
1.0087
1.0087
PCB-184
22'344'66'-HpCB
34.99
1.0222
1.0222
PCB-176
22'33'466'-HpCB
35.28
1.0306
1.0306
PCB-186
22'34566'-HpCB
35.67
1.0421
1.0421
PCB-178
22'33'55'6-HpCB
36. 81
1.0754
1.0754
FCB-175
22 ' 33 ' 45'6-HpCB
37.36
1.0913
1.0913
PCB-187
22'34'55'6-HpCB
37. 59
1.0979
1.0979
PCB-182
22*344'56'-HpCB
37.76
1.1031
1.1031
PCB-183
22 ' 344'5'G-KpCB
38.11
1.1132
1.1132
PCB-185
22'3455'6-HpCB
38.21
1.1155
1.1160
PCB-174
22'33'456'-HpCB
38. 30
1.1187
1.1187
PCB-177
22'33'4'56-HpCB
38.67
1.1296
1.1295
PCB-181
22'344'56-HpCB
39.02
1.1397
1.1397
PCB-171/173 22'33'44'6-/22 ' 3
39.20
1.1450
1.1450
PCB-172
22'33'455'-HpCB
40. 55
0.9061
0.9061
PCB-192
233'455'6-HpCB
40.80
0.9116
0.9116
PCB-180/193 22'344'55'-/233 '
41.10
0.9178
0.9182
PCB-191
233'44'5'6-HpCB
41.40
0.9251
0.9251
PCB-170
2 2'3 3'4 4'5-HpCB
42.17
0.9421
0.9421
PCB-190
233'44'56-HpCB
42.61
0.9522
0.9521
PCB-202
22'33"55"66"-OcCB
38.78
1.0006
1.0006
PCB-201
22'33'45'66'-OcCB
39.56
1.0207
1.0207
PCB-204
22'344'566'-OcCB
40.13
1.0356
1.0356
PCB-197
22'33'44*66'-OcCB
40.33
1.0406
1.0406
PCB-200
22•33'4566'-OcCB
40.41
1.0427
1.0427
PCB-198/199 221331455'6-/221
42.75
1.1027
1,1030
PCB-196
22*33*44'56'-OcCB
43.31
1.1175
1.1175
PCB-203
22'344'55'6-OcCB
43.48
1.1218
1.1218
PCB-195
22*33'44'56-OCCB
44.59
0.9504
0.9504
PCB-194
22'33 *44 *55'-OcCB
46.54
0.9919
0.9919
PCB-205
23 3'44'55'6-OcCB
46 .93
1.0004
1.0004
PCB-208
22*33 *455'66'-NoCB
44 .39
1.0005
1.0005
PCB-207
22'33•44¦566 *-NoCB
45.17
1.0182
1.0181
PCB-206
22'33 *44'55 * 6-NoCB
48.40
1.0004
1.0004
Analytical Perspectives
Page 5 of 5
Diff




Checkcode:
8i '
Sees
Response
Ra
RRF
Cone
Noise
DL
0
3.43E+06
1.21
1.17
1, 300
7.03E+03
27.4
-1.1
9.42E+07
1. 22
1.24
33,800
7.03E+03
25.9
0
2.05E+07
1.25
0.86
10,600
7.03E+03
37.2
+ 0.4
1.89E+07
1.28
0.80
10,500
7.03E+03
40.3
1
o
NJ
1.40E+07
1.28
0.94
6, 620
7.03E+03
34
-0.2
1.88E+07
1.26
1.16
7, 240
7.03E+03
27.8
-0.4
1.65E+08
1.24
0,95
76,800
7.03E+03
33.6
+0.2
3.52E+06
1.39
1.08
1,450
7.03E+03
29 .7
0
4.25E+07
1.23
1.31
14,500
7.03E+03
24 .6
+ 0.2
3.09E+07
1.25
0. 82
18,700
1.50E+04
95.1
0
7.80E+06
1.25
0.95
4, 060
1.50E+04
81.7
0
1.63E+07
1.25
0.97
8, 330
1.50E+04
80.2
-0.6
8.90E+05
0.91
1.05
365
4.27E+03
18.8
0
6.4 5E+06
1.06
0. 94
2, 960
4.27E+03
21
0
1.16E+06
1.04
0.93
537
4.27E+03
21.2
0
4.62E+06
1.03
0.98
2, 040
4.27E+03
20.1
0
5,44E+05
0.95
0.94
251
4.27E+03
21
0
3.70E+06
1.00
0. 69
2, 310
4.27E+03
28.6
0
3.76E+06
1.05
1. 05
2, 250
1.32E+04
83.7
0
1.40E+07
1.06
1.08
8,170
1.32E+04
81.4
0
1.56E+06
1.05
1.14
861
1.32E+04
76.9
0
1.10E+07
1.03
1.18
5, 880
1.32E+04
74.8
+1.1
1.52E+06
1.03
1.00
957
1.32E+04
87,7
0
1.28E+07
1.04
0. 98
8, 220
1.32E+04
89.7
-0.2
8.55E+06
1.04
0.96
5, 630
1.32E+04
92
0
1.96E+06
1.00
1. 05
1,180
1.32E+04
84.1
0
1.23E+07
1.03
0.95
8,160
1.32E+04
92 .9
0
1.03E+07
1.01
0.99
6, 550
1.32E+04
89
0
1.88E+06
1.02
1.23
964
1.32E+04
71.7
+1.0
4.08E+07
1.02
1.21
21,300
1.32E+04
72.8
0
1.16E+07
1.03
1.38
5,280
1.32E+04
63.7
0
2.68E+07
1.04
0.94
14,400
1.32E+04
76.1
-0.3
1.95E+07
1.01
1.12
8,750
1.32E+04
63.8
0
2.42E+06
0.91
1.03
1,130
6.29E+03
30.7
0
3-54E+06
0.86
0.99
1,730
6.29E+03
32
0
9.31E+05
0. 84
0.94
481
6.29E+03
33.9
0
2.48E+06
0.85
1.06
1,130
6.29E+03
29.8
0
2.88E+06
0. 87
0.90
1,560
6.29E+03
35.4
+0.8
1.43E+07
0.92
0.69
10,100
6.29E+03
46.3
0
8.60E+06
0.95
0.72
5,760
6.29E+03
43.8
0
7.18E+06
0. 92
0.79
4,420
6.29E+03
40.4
0
5,95E+06
0.91
0.66
4,650
8.30E+03
71.3
0
1.23E+07
0.90
0.73
8,680
8.3 0E+03
64.6
0
9.04E+06
0.90
0.97
4, 800
8.30E+03
48.4
0
4.42E+06
0.77
0.95
2, 570
7.98E+03
48.1
-0.3
5.29E+06
0.78
0.96
3, 040
7.98E+03
47.6
0
1,12E+07
0.76
1.05
8, 040
7.98E+03
59.9
Printed: 08 06 2008 1:22 PM
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID; Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
/
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02.EQ
Rel. Int.
Fn 1 100%
218.9856
QC (non-EQ)
10.43-15,00
Rel, Int.
Fn 2 100*.
242.9856
QC (non-EQ1
15.02-20.50'
Abs. nl
5.51e7
2.76S7
OOeO
15,0 RT
Abs. nt
1.8367
~9.13e6
OuoO
Rel, Int.
Fn 3 100%-
292.9824 |
QC (non-EQ) -
20.52-26.00 "
0%-
-r—r—t——r
| i i 1 i' t | l-'i '"V" i" |	r i'—? i | l l l l | j l % t | t
21,0	22,0	23,0
—|—
24.0
-i	1	1	1	r-
25.0
Abs. Int.
_2.05e7
¦ 1.03e7
• O.OOeO
26.0 RT
Rel, Int.
Fn 4 100%.
330.9792
QC (non-EQ)
28.03-37.11
0%.
28,0
30.0
32,0
34,0
36.0
-i—f
Abs. Int.
-2.42e7
• 1.21e7
¦O.OOeO
RT
Rel. Int.
Fn 6 100%.
366,9792
QC (non-EQ) .
37.13-44.01
0%-
-f—i—i—i—|—i—r-
38.0
-I	1	!	1	J	1
39.0
I ' 1 ' ' I ' '
40.0
' I
41.0
i i—j—i—r-
T"'
42.0
• t '
43.0
Abs. Int.
-3,64e8
. 1.82e6
•O.OOeO
44.0 RT
Rel, Int.
Fn 6 100%
454,9728
QC (non-EQ) J
44.02-49.21
0%.
-1	1 l	1	1	p	]	1	1	!	1 |	1	1	1	1	1	1	1	1	r	j
45,0	46.0
-T	1	1	1	1	1	r-
47.0
Abs. Int.
-6,40e6
49.0
-O.OOeO
RT
Rel. Int.
Fn 7 100%.
454.9728
QC (non-EQ)
49.22-53.00
0%.
~i—|—i—i—i—i—|—i—i—i—i—|—i—i—i—i—|—r—i—i—i—|—i—r 11
50.5
49.5
50.0
-I—I—J—r
51.0
—i—i—i—i—i—r-
i i i i
51.5
52,0
52,5
Ab$, Int.
-7.70e6
¦ 3.85e6
¦ O.OOeO
53.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\rBSOUKes\P9464_6042_PC8_O07RJ-D1OMtp_m$, saved OS-Aug-2008 09:19 (EE)
AP Ultra Tmce-PnT V3.993 User/System: EEJEEC2-Q3S see: 520-716
Peak annotation: Areas, Centroids
PKD n/a Printed: OS-Aug-2008 09:23:04 Page 1 of 22
-------
AP Lab ID: P9464_6042_PCB..007RJ-D10
Instr: AutoSpec-Ultima MM3
QC CHECK EQUALIZED
Sample ID: Run# II-ACD-M23-3 PRIOR TO PROCESSING	Acq: 02-Aug-2008 0f:17:17
VSIR expt: pcb0306_cI1-1Q GC: pcbx90_a Vial: 12	User: CJL Datafile: 0808Q2RG2_EQ
Rel. Int.
Fn 1 100%-
218.9856
QC Check
10,43-15,00
0%.
i j i j i
10.S
¦t-
—i—i—(—r-
11,0
11.5
-r"rr
12.0
12.5
—i—|—t-
13.0
"T—I—|—I—t—I—I—T-
13.5
' I '
14.0
¦ I ¦
14,5
Abs Irit.
-5.9107
¦ 2.95e7
¦O.OOeO
15.0 RT
Rel. Int.
Fn 2 100%
242.9856
QC Check
15.02-20.50
16.0
—I	'—<~
17.0
18.0
~i	1	1	1	r	1	1	'	1	1	1	1	1	1	1	1 i	1	r-
Abs. Int.
-1.50e?
• 7 52e6
19.0
20.0
• O.OOeO
RT
Rel. Int.
Fn 3 100%-
232.9824
QC Check
20.52-26.00
0%-i-,	r-
21,0
""	1—r"
22.0
—I—
23.0
Abs. Int.
• 1.76e7
	1	i	1	f	r—-j	1	1	1	1	j	r—i	1	1	j	r—r—r-
24.0	25,0
¦ 8,82e6
¦ O.OOeO
26.0 RT
Rel. Int
Fn 4 100%.
330.9792
QC Check
26.03-37.11
0%.
—(—
28.0
30.0
"•—I—""
~i	j	1	r-
32.0
-i—i—i—|—
34.0
36.0
Abs. Int.
-2.38e7
¦ 1.19e7
• O.OOeO
RT
Rel. Int.
Fn 5 100%-
454,9728
QC Check
37.13-44.01
0%-
1—i—i—i—*—p—i—i—|—f i v—r-
38.0
39.0
• I ¦
40.0
¦"T	i	i	t	i	r	i	r"
41.0
1 I r
42.0
1 I r
43.0
Abs. Int
7.05e6
-3.53e6
-O.OOeO
44.0 RT
Rel. Int
Fn 6 100%-
404.9760
QC Check
44.02-49.21
Abs, Int
6.28e6
3.14eS
O.OOeO
Rel. Int
Fn 7 100%.
454.9728
QC Check
49.22-53.00
0%.
49.5
Abs. Int.
-6.79eS
L3.39e6
t—| r
50.0
I i i i i | i i—i t ¦¦ | ¦
50,6
1 1 1 • ' ' I
51.0
' i '
51.5
i y i i %
52.0
i i f I >
•O.OOeO
52.5
53.0 RT
Results: P:\P9400_P9499V9464___6042 PCBtescurves\P9464_6042_PCB_00TRJ-D10 utp_res. saved 05-Aug-2008 09:19 (EE)
AP UttraTrace-Pm V3.993 User/System: EE/EEC2-038
Peak annotation: Areas, CentroitSs
PKD n/a Printed: 05-Aug-2Q08 09:23:05 Page 2 of 22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 1
188,0393
MoCB
4o 8.98e3
10.43-15,00
0%-
Sample ID: Run# II-ACD-M23-3
VSIRexpt: pcb0306 _cl1-10 GC: pcbx90_a Vial: 12
PCB-2
2.07e9
13.31
PCB-1
8.24e8
11.29
PCB-3
1,40e9
13,49
10.5
1 1 ' 1
11.0
1 I 1
11,5
12.0
12,5
13.0
Rel. Int.
100%
Fn 1
190.0363
MoCB
4o6.88e3 .
10.43-15.00
0%-
PCB-1
2.66eB
11.29
I | I I I f | I I 1 I | 1
10.5	11.0
Rel. Int.
100%-
Fn 1
200.0795
MoCBStd. ,
4o 8,46e3
10,43-15.00
0%-
10.5
I j I 1 I 1 j I I I I J I
11.5	12.0
I | I I I I
12.5
13,0
PCB-2
6.67eB
PCB-3
4.51C8
13.49
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02_EQ
Abs. Int.
-6.64e8
14.0
14.0
ES-1
I.12e7
II,28
ES-3
I.i5e?
13.47
11.0
11.5
12.0
12.5
13.0
13.5
14.0
14,5
14,5
•3.32e8
•O.OOeO
15.0 RT
Abs. Int.
2.11e8
1.06e8
•O.OOeO
15.0RT
14.5
i i i | r ) i i 0 .OOeO
1S.0RT
Abs. Int.
-4 52e6
2.26e6
Rel. Int.
100%
Fn 1
202.0766
MoCBStd, J
4o 5.51e4
10.43-15.00
0%-
10.5
3.78ee
11,Z8
ES-3/
4.2$m
1X47
,41e5
13.87
I 1 I I I I
11,0
1 I I 1 • 1 I 1
11.5
12.0
( I I I I | I I I I |
12.5
13.0
13,5
i ' f—| i i—i—i—|—n—r i
14.0
—j—i—r-j—r-
14.5
¦ | i i i i O.OOeO
15.0RT
Abs. Int.
-1.65e6
¦8.25e5
Rel. Int.
100%
Fn 1
218.9856
QC Check
10.43-15.00
0%-
10.5

11.0
	1	T""|	1	I—|—I—
11.5	12.0
Abs. Int.
-5.91e7
•2.95e7
O.OOeO
12.5
	1	1 J I T I I |	1 I 1 \	1	I	I r . I' ¦¦ 1	1 | I I 1 I
13.0	13.5	14.0	14.5	15.0RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB_007RJ-D10 u(p_res. saved 05-Aug-2008 09:19 (EE)
AP UltraTraee-Pro V3.993 User/System: EE/EEC2-038 cc: 4443, 8175
Peak annotation: Areas. Centmidg'
Revised: 04-Aug-2008 14:20:47 (EE) Printed: OS-Aug-2008 09 23:06 Page 3 o?22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 1
222.0003
DiCB-1
4o 4.53e3
10.43-15.00
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 12
0% I | I—1—I—I—|—I—!—I—1 | 11 'I—I ¦ I
10.5
11.0
Rel. Int.
100%-
Fn 1
223.9974
DiCB-1
4o 1.53e4
10.43-15.00
0%-
¦ » r" 'I	i	r	f"
10.5
Rel. Int.
100%-
Fn 1
234.0406
DiCBStd.
4c 1,05e4
10.43-15.00
0%-
t-'-
10.5
Rel. Int.
1Q0%-
Fn 1
236,0376
DiCB Std,
4a 4.53e3
10.43-15.00
0%-
10.5
11.0
• i ¦
11.0
11.0
11.5	12.0
PCB-4
1.89e7
13.78
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02_EQ
Abs. Int.
-5.70e6
12.5
13.0
13.5
i t » I t i i—i ] i i i
14.0	14.5
2.85e6
¦FT--O.OOeO
15.0RT
PCB-4
1.10e7
13.78
11.5
12,0
12.5
13.0
" ' ' 1	'<<•'!<
13.5
11.5
12.0
12.5
13.0
6.18e6
13.76
3.90e5
14.72
|—i—i—i—i—|—i—i—i i ¦( <—t
14.0	14.5
i r-f i iO
Abs. Int.
-3,76e6
•1.88e6
-O.OOeO
15.0RT
13,5
14.0
"'1	1	1	J	I""
14,5
Abs. Int.
-2.13e6
-1.06e6
-O.OOeO
15.0 RT
Abs, Int.
1.33e6
•6.63e5
11.5
12,0
-i—|—i—i—i—i—|—!—i—r—r—|—!—i i i—|—l l i—i i—i T i—j—r-i—r-i—)—i—r-r-
12.5	13.0	13.5	14.0
• T *'
14.5
•O.OOeO
15.0RT
Rel. Int.
100%-
Fn 1
218.9856
QC Check
10.43-15.00'
11.5	12.0	12.5	13.0
Results: P:\P9400__P9499\P9464__6042 PC8Vesources\P9464_6042_PCB_007RJ-DW utp_ms. saved OS-Aug-2008 09:19 (EE)
AP UftraTrace-Pro V3.993 User/System: EE/EEC2-038 ce: 0919.1332
Abs. Int.
-5.91e7
2 95e7
O.OOeO
15.0 RT
Peak annotation: Areas. Centroids
Revised: 04-Aug-2008 14:28:11 (EE) Printed: 05-Aug-2008 09:23:07 Page 4 oj/22
-------
AP Lab ID; P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 2
222.0003
DiCB-2
4a 1.30e4
15.07-20.50
Sample ID: Run# II-ACD-M23-3
VSIRexpt: pcb0306_clt-10 GC: pcbx90_a Vial: 12
0%-
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
40 3.34e4
15.07-20.50
0%-
Rel. Int.
100%n
Fn 2
234.0408
DiCB Std.
4o 1.16e4
15.07-20.50
0%-
Rel, int.
100%-
Fn 2
236.0376
DiCB Std.
4o5,54e3
15.07-20.50
0%-
PCB-9
3.87e7
15.66
/\ A
PCB-6
5.96e7
16.03
4V-
16.0
PCB-5
6.06e7
16.33
AA
PC8-14
5.61e7
17.97
PCB-11
1.07e8
18.74
PGB-15
6.72e7
19.30
17.0
18.0
PCB-9
2.5Be7
16.66
pcb-s
3.95e7
16.03
PCB-5
3.98e7
16.32
A, , M
16.0
17.0
PCB-14
3.74e7
17.97
18.0
PCS-13/12
4.61ea
19.03
PCB-13/12
3.03ei
19.03
PCB-15
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 2
255.9613
TrCB-2
4o 2.79e3
15.02-20.50
0%-
Rel, Int.
100%-
Fn 2
257.9584
TrCB-2
4o 2.41 e3
15.02-20.50
0%-
16.0
Sample ID: Run# II-ACD-M23-3
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
PCB-30/18
2.59e7
18.46
PCB-19
3.26e6
16.72
A
Acq: 02-Aug-2008 01:17:17
User: CJL Dataftte: 080802R02 EQ
Abs. Int.
-7.03e6
1—I—'
17,0
18.0
PCB-17
PCB-16
1.4667
1.37e7
16.85
PCB-27
I I S.09e6
19.03
PCB-32
I.20e7
19.74
20.0
PCB-30/18
2.52e7
18.4$
j	|	i	1——r-
16.0
PCB-19
3.1266
16,72
A
1—i—1
17,0
—I—1
18,0
PCB-17
1,4le7 PCB-16
18.85	1 34e7
19.26
P
-•—r
PCB-32
1.15e7
19.74
3.52e6
-O.OOeO
RT
Abs. Int.
-6,63e6
¦ 3.32e6
20,0
¦O.OOeO
RT
Rel, Int.
100%-
Fn 2
268,0016
TrCBStd.
4o 2.63e4
15.02-20,50
0%-
Rel. Int.
100%-
Fn 2
269,9986
TrCB Std,
4cr 1,43e4
15.02-20.50
0%-
ES-19
4.60e6
16.71
16.0
i*~ r-r- ¦
17.0
-7—*—r-
i—|	1—i i
18.0
1—I—1
19.0
1,47e7
19.43
~r	1	r——I	1 i
20.0
ES-ia^
4J14€B
TE.71
i	i
16.0
LX
i i	i I'" T
17.0
18.0
T
1.7766
19.43
i—i
Abs, Int.
-8.10e6
•4.05e6
-O.OOeO
RT
Abs. Int.
-1.16e6
¦5,81e5
19.0
20.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
15.02-20.50"
0%-
16.0
17.0
18.0
—I—1
19.0
Abs. Int.
-1.50e7
-7.52e6
¦O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\re$ources\P9464^6Q42_PCB_007RJ-D10.utp_re$, saved 05-Aug-2008 09:19 (EE)
AP UllraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 4227, 6145
20.0
Peak annotation: Areas. Centmitpr
Revised: 04-Aug-2008 14:32:55 (EE) Printed: 05-Aug-2008 09:23:09 Page 6 <31/22
-------
AP Lab ID: P9464_6042JPCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 3
255.9613
TrCB-3
4o1.92e4
20,52-26.00
Sample ID: Run# II-AGD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Acq: 02-Aug-2008 01:17:17
0%-
Rel. Int.
100%-
Fn 3
257.9584
TrCB-3
4a 1.14e4
20.52-26,00
0%-
PCB-34

21.29
20.87 /%
¦ O A,
2.27e7
21.48
PCB-31
4.21 e7
21.76
PCB-28/20
8,70e7
22.04
21.0
PCB-22
3.82e7
22.59
A
22.0
23.0
PCB-34
6.58@6
20J7
21.0
PCB-28/20
8.32e7
22.03
PCB-31
4.02e7
21.76
21.48
PCB-22
3.61e7
22.59
A
PCB-36
2,06e7
23,96


User: CJl


PCB-35
1.36e8
25.18

PCB-38
8.1887
24,79
A
ji
PCB-39
I,86e7
24.27
A
A
w
PCB-37
1,35e8
25,54
24.0
25.0
PCB-38
7,7167
24.79
PCB-36
1.03e7
23.96
PCB-39
1.77e7
24.27
22.0
23.0
A . A
PCB-35
PCB-37
1.31e8
1.30e8
Abs. Int.
r3.49e?
¦1.74e7
¦O.OOeO
26.0 RT
Abs. Int.
r3.31e7
-1.65e7
¦O.OOeO
24.0
25,0
26.0 RT
Rel. Int.
100%-
Fn 3
268.0016
TrCB Std.
40 2.50e4
20.52-26.00
0%-
Rel, Int.
100%-,
Fn 3
269,9986
TrCB Std,
4o 2.45e4
20.52-26,00
0%-
SS-28
6,25e6
22.01
ES-37
S.39e6
25.52
i ^ ? fi | r — r -1 ¦ i ^ y t " r i i |
21.0
21.0
i | f * i i | i i
23,0
24.0
" I i i '|—f-~"T i—f
25.0
n	i""	» —y
22.0
I '¦"i i r •'i |
23.0
1.43e6
23.27
T I I ' ]	f t	-•)' f
24.0
ES-37
4.9186
Abs. Int.
-2.96e6
1.48e6
i i i f O.OOeO
26.0 RT
Abs. Int.
1.45e6
¦7.27e5
-O.OOeO
25.0
26.0 RT
Rel. Int.
100%-
Fn 3
292.9824
QC Check
20.52-26.00"
0%-
21.0
22.0
23,0
24.0
25.0
Results: P:\P9400_P9499\P9464_6042 PCBSre$ources\P9464_6042_PCB_0Q7RJ-D10,utp_ms, saved 0S-Aug-2008 09:19 (EE)
AP UttraTraze-Pro V3 993 User/System: EE/EEC2-038 cc 3967, 2801
Abs, Int.
-1.76e7
¦8.82e6
¦O.OOeO
26.0 RT
Peak annotation: Areas, Cenlrp/ds
Revised: 04-Aug-200B 14:33:45 (EE) Printed: 05-Aug-2008 09:23:10 Page 122
-------
AP Lab ID; P9464_6042_PCBJ307RJ-D10
Instr: AutoSpec-Ultima MM3
Rel, Int.
100%
Fn 2
289.9224
TeCB-2
4o 1 ,25e3
15.02-20-50
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o2.30e3
15.02-20.50
Rel. Int.
100%
Fn 2
301.9626
TeCB Std.
4o 2.45e3
15.02-20.50
Rel. Int.
100%-
Fn 2
303.9597
TeCB Std.
4o 2 36e3
15.02-20.50
0%-
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC; pcbx90_a Vial: 12
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02_EQ
Abs. Int.
4.62e4
PCB-54
1,60e5
19.59
2.84e4
18.45
l'~~-7	 .	- - | iiiiflq, mirm)

PCB-54
2.06e5
19.59

ES-54
3.94eS
19.57

-4*76e6
19.57
2.3164
_ o.OOeO
Abs. Int.
-5.65e4
2.83e4
O.OOeO
RT
Abs. Int.
-1.04e6
5.22e5
O.OOeO
RT
Abs. Int.
-1.25ei
•6.24e5
I j I I I I | I I
16.0
17,0
18.0
19.0
20.0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
15.02-20.50'
0%-
16.0
17.0
18.0
19.0 '
Results: P:\P9400_P9499\P9464_6042 PCB^msouirxs\P9464_6042_PC8_007RJ-D10.utp_ms. saved 0S-Aug-2008 09:19 (EE)
AP UltraTrace-Pro V3.993 User/System EE/EEC2-038 cc: 6069. 1215
Abs. Int.
-1.50e7
7.52e6
O.OOeO
RT
20.0
Pea* annotation: Areas, Centroids
Revised: (M-Aug-2608 14:33:52 (EE) Printed: 0S-Aug-2008 09.23:11 Page 8 q(*22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID: Run# II-ACD-M23-3
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Acq: 02-Aug-2Q08 01:17:17
User: CJL Datafile: 080802R02_EQ
Rel. Int.
100%-
Fn 3
289-9224
TeCB-3
4cr2.59e3
20.52-26.00
0%-
PCB-50/53
4.00e6
21.52
.
42]6,f ?65ef
PCB-69/49
2,06e7
24.07
PCB-43
3.00e6
23.86
PCB-44/47/65
3.33e7
24.52
PCB-59/62/75
1.2967
24.00
PCB-48
7.49e6
24.33
21.0
22.0
23.0
24.0
25.60
Abs. Int.
-1.02e7
5.12e6
-O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4o 2.96e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
301.9626
TeCB Std.
4o 2.76e3
20.52-26.00
0%-
Rel. Int.
100%-
Fn 3
303.9597
TeCB Std.
4a4.03e3
20.52-26,00
0%-
21.0
PCB-50/53
5.14e6
21.52
PCB-45 prR^ift
5.41 e6
oo 11 2.2366
22.39
t >-^ - |
22.0
PCB-44/47/65
PCB-S9/49 4^3®7
2 S5e7	24-52
24.07
A PCB-48
9.85e6
24.33
23.0
24.0
PCB-59/62/75
1.67e7
24.80
y A A
PC2B-|mB-64
^rsz.i2e7
?-4u 25.60
25.0
8.12e
JS-52
4.22e6
23.62
A
21.0
22.0
23.0
24.0
25.0
JS-52,*
5 39e6
Abs. Int.
-1.32e7
•6.59e6
¦O.OOeO
26.0 RT
Abs. Int.
-1.10e6
5.49e5
-O.OOeO
26.0 RT
Abs. Int.
-1,46e6
r7.28e5
21.0
22.0
23.0
24.0
25.0
-O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
292.9824
QC Check
20.52-26,00"
0%-
21.0
22.0
23.0
24.0
1—I—1
25.0
Abs. Int.
-1,76e7
•8.82e6
-O.OOeO
26.0 RT
Results: P:\PS400_P9499\P9464_6042 PCB\resource5\P9464_6042_PC6__007RJ-D 10utp_res, Saved 05-Aug-2008 09:19 (EE)
AP UllraTrace-Pro V3.993 User/System EE/EEC2-038 cc 9? 89. 8534
Peak annotation: Areas, CentirMy
Revised' 04-Aug-2008 14:34:48 (EE) Printed: 0S-Aug-200S 09:23:12 Page 9^22
-------
X
AP Lab ID: P9464_6042_PCB_007RJ-D1G
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fri4
289.9224
TeCB-4
4a 1.99e4
26.03-32.99
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC; pcbx90_a Vial: 12
/ Acq: 02-Aug-2008 01:17:17
Usei/CJL Dalafile: 080802R02_EQ
0%-
PCB-6W0/74/76
I.11e8 i
27.80
PCB-77
1.46e8
31.82
PCB-72»CB-68
3.33e64,65e6
26.32 26.57
t i—j-*2*—r
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4o 3.05e4
26.03-32.99
0%-
Rel. Int.
ioo%-
Fn 4
303.9597
TeCBStd.
4o 8.30e3
26.03-32.99
0%-
PCB-57
9.75e6
26.94
' A""
27.0
PCB-66
4.78e7
28.08
rCB-67
1.67e7
27.2a
PCB-56
5.72e7
28.
'CB-60
1.88e7
28.85
UU
PCB-79
3.62e7
30.49
PCB-78 PCB-81
3-49e7 2.79e7
30.97 31,35
prn cT PCB-67
PCB-68 p.c°£4 2.16e7
28.0
PCB-61/70/74/76
1,43©8 ppD ce
27.80 PC|66
28.08
29.0
' I 1
30.0
A. .A., A
31.0
32.0
PCB-77
1.89e8
31.82
6.05e6
26,57
¦r*' i | O
1.30e7 tyj nr*
26.94 11
t"
27.0
PCB-56
7.36e7
28.6|CB_g0
, 2.42e7
28.84
PCB-79
4.67e?
30.49
PCB-78 PCB-81
3 39e7 3.56e7
30.97 31.35
A-

28,0
29.0
30.0
r
31.0
T	f	r..~.T-...T..-T—
32.0
Rel. Int.


ES-81
100%-,


4.25e6
Fn 4 ;


31.33
301.9626 ¦


A
TeCBStd. '



4a 5.63e3 -



26 03-32.99 ;
1.42e5

[
0%-
29.18
' '—'—'—i—i—¦—¦—¦—i—i—i—i—i—i—i—i" 'i'	i—i—i—i—i i i " i i 	[• i—i - i-" i- i i i •• i i i—

i i r i < \ N
ES-77
4,98e6
31.81
A
/ I
Abs. Int.
r3.50e7
-1.75e7
-O.OOeO
RT
Abs. Int.
-4.54e7
-2.27e7
-O.OOeO
RT
Abs. Int.
-1.14e6
¦ 5.68e5
27.0
28.0
29,0
30.0
r—i—i | i ' i—r—^—r i i—V—|—i—"!—i—i—j—i ¦ i ¦ i r 0 OGcO
31.0	32.0	RT
RT
ES-77
6 18e6	Abs Int.
Vf1	r 1,60e6
¦ 7,99e5
27,0
28.0
29.0
30.0
31.0
32.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
330.9792 ¦
QC Check '
26.03-32.99 .
Abs. Int.
j-2.38e7
-1.19e7
0%-
T
27.0
I I | I
28.0
[ 1 >"!""!'""F	J	f	f	f""
29.0
t 1 1 1 ' I '
30.0
'I		I'" I — "1 " I —| 1 "T * " I
31,0
T	J	T	T""
32.0
-O.OOeO
RT
Results: P\P9400_P9499\P9464_6042 PCB\resoumes
-------
AP Lab ID: P9464_6042_PGB_007RJ-D10
Instr; AutoSpee-Ultima MM3
Rel. Int.
100%
Fn 3
323,8834
PeCB-3
4a 5.14e3
20.52-26,00
Rel. Int.
100%
Fn 3
325,8804
PeCB-3
4o 7.02e3
20.52-26,00
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx9Q_a Vial: 12
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02_EQ
Abs. Int.
-1.76e5
PCB-96
6.93e5
PCB-104
1.39e5
24.49
PCB-96
I.l6e6
24.80
PCB-104
2,38eS
24.49
S,65e4
25.23
1,04eS
25.82
21.0
22.0
23.0
24.0
25,0
8,81 e4
OOeO
26,0 RT
Abs. Int.
2.88e5
1 44e5
O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
337.9207
PeCBStd.
4o 2,41e3
20.52-26.00
0%-
¦"t	t	i	i	|	i	i	«	¦!	|	i	i	y	t	I" ""t"
22.0
21.0
23.0
»	I	'I	
24.0
25.0
Abs, Int.
-1,46e6
7.32e5
•O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
339.9177
PeCB Std.
4o 3 20e3
20.52-26.00
0%-
I I I 1 | I I
21.0
22.0
23.0
24.0
1—T~
25.0
I I I 1
Abs. Int.
-9.54e5
•4.77e5
¦O.OOeO
26,0 RT
Rel. Int.
100%-
Fn 3
292.9824
QC Check
20.52-26.00'
21.0	22.0	23.0
Results: P:\P9400_P9499\P9464_6042 PCB)n)SOUwes\P9464_6042_PCB_007RJ-D10.utp_m$, saved OS-Aug-2008 09:19 (EE}
AP UltmTrace-Pm 1/3.993 User/System; EE/EEC2-038 cc: 9426, 4997
24.0
25.0
Abs, Int.
-1 76e7
8.82e6
O.OOeO
26.0 RT
Peak annotation: Areas, Canttmtef'
Revised: 04-Aug 2008 14:40:03 (EE} Printed: 05-Aug-2008 09:23 14 Page 1 \ oftLZ
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
PCB-91
6,45e6
27.79a
•jy
Sample ID: Run# II-ACD-M23-3
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Fn 4

323.8834
PCB-95
PeCB-4
2.87©7
4o 2.69e4 "
27.05
A
26.03-37,11 -
l\
0%-
, , . . \.
Rel. Int.
100%-
Fn 4
325.8804
PeCB-4
4a 5.41e4
26.03-37.11
0%-
Rel. Int.
100%-
Fn 4
337.9207
PeCB Std.
4a 5.89e3
26.03-37.11
0%-
Rel. Int.
28.0
PCB-92
7.19e6
29.07
PCB-113/90/101
4.82e7
nq c]7
PCB-108/119/86/97/
5.12e7
30 53
PCB-83
7.46) "
29.'
PCB-110
6.40e7
31.25
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02 EQ
/
30.0
PCB-118
7.25@7
33.80
PCB-105
5.32e7
34.80
PCB-82
1.35e7
31.53
PCB-122
PCB-114
7.85e6
RT
PCB-127
8.32e6
36.04
PCB-11
2.56e(
31.
PCB-120
3.89e6
32.25
A
-PCB-95
4.67e7
27.05
PCB-91
1.04e7
27.79a
A/l
28.0
PCB-92
1,20e7
29.07
r—-j^-i—
PGB-113/80/101
7.80e7
29.57 PCB-108/119/86/97/
8.42e7
30.53
PCB-83
PCB-110
I.03e8
31.25
PCB-118
1.19e8
33.80
PCB-11?
4,20el
31J—
30.0
PCB-82
2.17e7
31.53
iVL
PCB-120
6.61e6
32.25
i A ,
PCB-12:
.A
PCB-105
8.54e7
34.00
PCB-114
1.31e7
04.26
JS-101
5.28e6
29.55
32.0
SS-111
7.33e6
31.84

PCB-127
1.40e7
38.04
34 0

36.0
'"I"	I	J	I	T""
28.0
30.0
100%-,
JS-101
Fn 4 ;
3.41e6
339.9177 ¦
29 55,
PeCB Std, '
1

4a 5.80e3 .


26.03-37 11 ¦
f

0%-

«-
¦	1 i—1—1—<—1—r
32.0
SS-111
4.73e6 ..
31.
T
ES-123
5.77e6
33.50
ES-114
5.92e6
34.24
ES-105
5,97e6
34.77
34.0
i	1—r—r-
36.0
J
34 fA 3.70e6
34.77
28.0
30.0
-n—
32.0
	
j' *» * r* 1 f"
34.0
r—t—,
36.0
Abs. Int.
-1.76e7
8.78e6
OOeO
RT
Abs. Int.
-2.8967
• 1,44e7
-O.OOeO
RT
Abs. Int.
-1.8586
¦9,23e5
-O.OOeO
RT
Abs, Int.
-1.17e6
¦5.85e5
¦O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
26.03-37.11
Results: P:\P9400_P9499\P9464_6042 PCB\msoumes\P9464_6042_PCB_007RJ*010Mp_re$, saved 05-Aug-2008 09:19 (EE)
AP UttraTmce-Pro ¥3.993 User/System EE/EEC2-03S cc: 7141, 3441
Abs. Int.
2.38e7
1.19e7
O.OOeO
RT
Peak annotation: Areas. CentrpkJs
Revised: 04-Aug-2008 14 42 S3 (EE) Printed: 05-Aug-200S 09 23 16 Page 12 W 22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpee-Ultima MM3
PCB-126
Rel. Int. 7 52e?
100%-, 37'40
Fn 5
323.8834
PeCB-5
4o 2.93e4
37.13-44,01
Sample ID: Run# II-AGD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
0%-
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4o 4.68e4
37.13-44.01
0%.
PCB-126
1.21e8
Rel. Int.
100%-
Fn 5
337.9207
PeCB Std,
4cr6.83e3
37.13-44.01
0%-
ES-126
6.15e6
37,38
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02_EQ
Abs. Int.
-1.82e7
-9.08e6
Rel. Int.
100%-
Fn 5
339.9177
PeCB Std,
4c 9.01e3
37.13-44.01
ES-126
3.95e6
37.38
0%-
I I f ¦'T¦
, A .
38.0
39,0
40.0
I | I I '
41.0
¦"1
42.0
' I 1—1 1
38,0
I » I—I [ t t 1 1 |
39.0

40.0
j I I I I '	1
41.0
r^
42.0
43.0
43.0
O.OOeO
-i—.—i—i—•—r
44.0 RT
Abs. Int.
-2.98e7
¦1.49e7
¦O.OOeO
44.0 RT
I- f > T I'" I
38.0
—f—[—1—r—r-
39,0
40,0
41.0
42,0
Abs, Int,
-1,44e6
• 7 18e5
! —"i ¦ r • i i i i—|—¦—i—i'i 0 .OOeO
43,0	44,0 RT
Abs. Int.
9 78e5
-**1—"i i	i1"
38.0
39.0
T^l	f—I	1	1	J-
40,0
I |
41.0
42,0
1,72e5 2.98e5
42.65 42.91
	,y——y
43,0
4.89e5
-i—i—i ¦[ j O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37,13-44.01'
0%-
Abs. Int.
-7.05e6
3.53e6
¦O.OOeO
' ' I ' ' ' ' I ' 1 ' 1 I 1 1 1 1 I » '» ' ' I ¦ ' 1 ' 1 ' ¦ ' ' | 1 ¦ ' ' | '	¦ ¦ ' ) > t ¦ ¦ | ' ' ¦ ¦ | '	' '«
38.0 39.0 40.0 41.0	42.0 43.0	44.0 RT
Results: P\P9400_P9499\P9464_6042 PCBVesources\P94f>4_6042_PCB_007RJ-D WMtp_KS, saved 05-Aug~2008 09:19 (EE)	Peak annotation: Areas. Centro&£^~
AP UltmTmce-Pro V3.S93 User/System: EE/EEC2-03B cc: 1093, 0351	Revised: 04-Aug-2008 14:43:01 (EE)	Printed: 0$-Aug-2008 09:23:17 Page 13 9 22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Re!, Int.
100%-
Fn 4
359.8415
HxCB-4
4cr 3.80e3
27.99-37.11
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Acq: Q2-Aug-2008 01:17:17
User: CJL Datafile: 080802R02_EQ
0%-
PCB-147/149
3.86e7
32.83
PCB-153/168
5.18e7
35.38
PCB-163/138/129
8.12e7
36.45
28.0
29.0
PC B-136
8.67eS
30.00
, .A, ,
30.0
PCB-151/135 ...
1 48e7 rCB-144
32 06 3.28e6
	a. 32-53 '
31.0
32.0

PC B-132
2.04e7
;B-B>BB-139/140 33 89 pcB-133
57e6 4 20e6 A 2 30e6
P OO 33,34	\ 34.31
33.0
PCB-146
1.20e7
34.88
34.0

:b-i«cb-i3o
yte7 10Se7
|5.54 35,89
A./A
PCB-158
2.3567
Abs. Int.
-1,84e7
9.22e6
•O.OOeO
35.0
36.0
37.0 RT
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4o 3.23e3
27.99-37.11
0%-
28.0
PCB-147/149
3.12e7
32.83
PCB-136
7.03e6
30.00
29.0
30.0
pcfMl93kgu4
3>°6 lllf *
31 0
32.0
¦p,
PCB-132
(	1.66e7
139/140 33 89 pCB-133
I72e6 3 30e6 A 1.84e6
^3^0 33^4 ^ j\ 34.31
33.0
nr*-
34.0
PCB-153/168
4.2367
35.38
PCB-146
P*14f*C8-130
9.32e€
lie? 8,27e6
34.86
5.54 35 HQ
PCB-163/138/129
7.37e7
36,45
A
PCB-158
V91e?
pClB-^77
l»Se.
36.59j
J	1
35,0
. .A/A i
36.0
T
Rel. Int.
100%-
Fn 4
371.8817
HxCBStd.
4a 5.00e3
27.99-37.11
0%-
ES-155
5.94e6
29.38
a
ES-153
4.97e6
35.36
28.0
29.0
30.0
-i—|—i i I—i | i—i—I i r i—i i i j i" i i I | t i—i—i j 			 "i |—i—i i i |—i	i )
31.0	32.0	33.0	34.0
IS
35.0
Rel. Int.
100%-
Fn 4
373.8788
HxCB Std.
4o3.56e3
27 99-37.11
ES-155
4.fSe6
.38
0%-
4JS(
35.36
3<®e6
36.41
28.0
29,0
30.0
31.0
32.0
33.0
34.0
35,0
36,0
Abs. int.
-1.50e?
•7 49e6
•O.OOeO
37.0 RT
Abs. Int.
-1.50e6
¦7.49e5
O.OOeO
' I	* ' 'I ¦ 1 1 i
36.0	37.0 RT
Abs. int.
-1.18e6
•5.92e5
¦[ f*O.OOeO
37.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
27.99-37.11
Abs. Int.
-2.38e?
1.19e7
28.0
Results: P:\P9400_P9499\P9464_6Q42 PCB\resovrce$\P9464_6042_PCB_007RJ-D10 utp_res, saved 05-Aug-2008 09:19 (EE)
AP UltraTmce-Pm 1/3.993 User/System: EE/EEC2-038 cc: 3580, 6404
I O.OOeO
37.0 RT
34.0	35,0
Peak anno)			... .
Revised: 04-Aug-2008 15:11:34 (EE) Printed: 0S-Aug-2008 09:23:16 Page 14^(22
36.0
Peak annotation: Areas, Centmpr
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-)
Fn 5
359.8415
HxCS-5
4 a 9,85e3
37.13-44.01
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
0%-
PCB-156/157
5.82e7
39.94
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02 EQ
Abs. Int.
-1.11e7
PCB-128/166
1.72e7
37.51
PCB-162
PCB-15®.08e6
4.3466 38.56
38.33
. /\
PC B-167
1.60e7
38.97
PCB-169
1,9Se7
42.65
38.0
-A-
Rel. Int.
100%
Fn 5
361.8385
HxCB-5
40 5.10e3
37.13-44.01 ¦
0%-
Rel. Int.
Rel. Int.
100%-
Fn 5
373.8788
HxCB Std. .
4cr 7.20e3
37.13-44.01
0%-
PCB-128/166
1.37e7
37.51
38.0
PCB-162
PCB-15ff,24e6
3.46e6 38.56
38.32 A
39.0
PCB-167
1.25e7
38.97
40.0
PCB-156/157
4.77e7
39.94
41.0
42.0
43.0
PCB-169
1,56e7
42.65
39.0
100%-
ES-167
Fn 5
4.58e6
371.8817
38.95
HxCB Std.
A
4o 7.61e3 .

37.13-44.01 ¦
\
0%-

40.0
ES-156/157
9.33e6
39.92
41.0
42.0
43.0
38.0
39.0
¦ '' ' r ' ''
40.0
ES-156/157-
TJOefj
11 i ¦ i—<—i | t i i i |
41.0
42.0
43.0
ES-169,
3.Z9e8
^42763
38.0
39.0
40.0
41.0
-r->-
42.0
43.0
5 56e6
-f-0.00e0
44.0 RT
Abs. Int.
8.84e6
•4.42e6
-O.OOeO
44.0 RT
Abs. Int.
1.61e6
•8.04e5
•O.OOeO
44.0 RT
Abs. Int.
-1.35e6
•6.75e5
-i—f-O.OOeO
44.0 RT
Rel. Int.
100%
Fn 5
454.9728
QC Check
37.13-44.01
0%-
T
~r
38.0	39.0	40.0	41.0
Results. P:\P9400_P9499\P9464_6042 PCB\msouites\P9464_6042_PCB_007RJ-D10.utp_res. saved 0S-Aug-2008 09:19 (EE)
AP UHraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 7931. 8987
1 ' I '
42,0
43.0
Abs. Int.
-7.05e6
3.53e6
¦O.OOeO
44.0 RT
Peak annotation: Areas, CentroMg"
Revised 04-Aug-200S 13:12:04 (EE) Printed: OS-Aug-2008 09:23:19 Page I5pt22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel, Int.
100%
Fn 4
393.8025
HpCB-4
4a 1.80e3
30.01-37.11
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cJ1-10 GC: pcbx90_a Vial: 12
Acq: 02-Aug-2008 01:17:17
User: CJL Dataflle: 080802R02_EQ
0%-
PCB-179
3.32e6
34.S3
Rel. Int.
100%-
Fn 4
395.7995
HpCB-4
4o 2.47e3
30.01-37.11
0%.
Rel. Int.
100%-
Fn 4
405.8428
HpCB Std.
4o 3.03e3
30.01-37.11
0%-
Rel. Int.
100%-
Fn 4
407.8398
HpCB Std.
40 1,95e3
30.01-37.11
0%-
31.0
32,0
33.0
PCB-188
4.23e5
34.25
. A .
PCB-176
2.35e6
35.28
PCB-176
1.85e6
38.81
PCB-184
5.9265
2 13e5 34.99
Q4.70 A
, ¦ / A.
PCB-186
2,66e5
35.67
, /> ,
Abs. Int.
-7 79e5
•3.90e5
34,0
35.0
36.0
31.0
32.0
33.0
PCB-188
4.66eS
34.24
,
PCB-179
3,13e6
34.53
PCB-176
2.27e6
PCB-184
5.67e5
34.99
34.70
O.OOeO
37.0 RT
Abs. Int.
7.35e5
3 68e5
PCB-186
2.7fle5
35.67
34.0
35.0
36.0
PCB-178
1.85e6
O.OOeO
' I '
31.0
ES-188
4.78e6
34.23
fl
II
""I	|"	I	I	I	I	|	1	1	»'	>	'J	I	'I'	'I	'I	I	I	'1	1	'I	|	»"*"l	I*"
32.0	33.0	34.0
ES-188
4.48e6
34.2'
i 1 i—i—|—i—i—r—r—|—r-
35.0
Abs. Int.
-1,12e6
¦5.60e5
360
-i—{—¦—r i *i"" | 0. OOeO
37.0 RT
I I I I
Till
31.0
32.0
33.0
-r_r-'
34.0
SS -wr-T
3,Q7e6
36.79
Abs. Int.
1.18e6
•5.92e5
¦O.OOeO
35.0
36.0
37.0 RT
Rel. Int.
100%-
Fn 4
330.9792 ¦
QC Check
30.01-37.11"
Abs. Int.
-2.38e7
-1.1987
0%-
) I I I I | I i i I
31.0
t—I i | i i |	i	t	f	r	j	r	r	t	t	f"
32.0	33.0
34.0
,MT	t	I	i	!	i	i	|	f	i	f	f	j	r	r	t m,,r ¦¦ j i
35.0	36.0
-O.OOeO
37,0 RT
Results: P:\P9400_P9499\P9464_6042 PCB^resourcesV9464_6042_PCB_007RJ-DW.utp_/es, saved 05-Aug-2008 09:19 (EE)
AP UltmTmce-Pm ¥3.993 User/System: EE/EEC2-03S cc: 8599, 9401
Peak annotation: Areas, Centmids>
Revised: 04-Aug-2008 15:12:16 (EE) Printed: 05-Aug-2008 09:23:20 Page 16j
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 5
393-8025
HpCB-5
4ofl.19e3
37.13-44,01
0%-
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Acq: 02-Aug-2008 01:17:17
User: CJL Oatafile: 080802R02_EQ
PCB-18Q/193
2.06e7
41.10
PCB-187
PCB-183
37.59	5.58e6
PCB-175 ^	33,11
1 i PCB-182
. 3/\ I
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4o 5.00e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
405-8428
HpCB-5 Std.
4o 5.65e3
37.13-44.01
0%-
38,0
,,, PCB-171/173
PP&1!7 6.23e6
4,37e6	39 20
38.67 PCB-181 /
9.60e5 ,
39.02 ,
A
PCB-187
6.81e6
37.59
37 36 / \7.64e5
/> f\*!™.
PCB-183
S.41e8
38.11
* j|
39.0
PCB-171/173
PCB-177 6.04e6
4.18e6	39.20
38,67 PCB-181/
9.B3e5 ,
39.01
¦ >
A
PCB-191
5.88 e6
41.40
40.0
JO.Of
A
PCB-172
5.1166
40«5^CB-192
8.3Q#5
40.80
. . ,
38,0
39.0
40.0
PCB-180/193
2.02e7
PCB-181
5.70ei
41.40
PCB-170
1.37e7
42,17
PCB-190
9.78e6
42,61
42.0
43.0
41.0
ES-170
4.05e6
41.09
PCB-170
1.31e7
PCB-190
42.16
9.70e6
42.81
42.0
43,0
ES-180
3.27e6
42.14
Abs. Int.
-3.99e6
1.99e6
¦O.OOeO
44.0 RT
Abs. Int.
3.85e6
• 1,93e6
-O.OOeO
44.0 RT
Abs. Int.
9.43e5
•4.72e5
38.0
1—[¦ I"
39.0

T"r
40.0
O.OOeO
41.0
i ¦ f —i' t * i * )—i' i ¦ > 'i y t I* r r | i i t i
42.0	43.0	44.0 RT
Rel. Int.
100%-,
Fn 5
407.8398
HpCB-5 Std..
4o 5.14e3
37.13-44 01
0%-
38.0
39.0
40.0
41.0
ES-160
43.0
Abs. Int.
-9.71e5
•4.85e5
¦O.OOeO
44.0 RT
Rel. Int.
100%
Fn 5
454.9728
QC Check
37.13-44.01'
0%-
38.0
39.0
M,i	i	p	r	|	r
40.0
41.0
42,0
43.0
Abs. Int.
-7.05e6
•3,53e6
O.OOeO
44,0 RT
Results P:\P9400_P9499\P9464 6042 PC8\resoucces\P9464_6042_PC8_007RJ-010utp_res, saved 05-Auq-2006 09:19 (EE)
AP Ultra Trace-Pro V3 993 User/System: EEMEC2-038 cc: 6269, 8246
Peak annotation: Areas, Cent/ptds
Revised 04-Aug-2008 15:13:55 (EE) Printed: 05-Aug-2008 09:23:21 Page 17/&22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Int.
100%
Fn 6
393.8025
HpCB-6
40 5.47e3
44.02-49-21
0%-
Rel. Int.
100%-
Fn 6
395.7995
HpCB-6
4a 3.41e3
44.02-49.21
0%-
PCB-189
1.4007
44.78
rCB-189
1.38e7
44.78
45.0

ES-189
Rel. Int.
4.66e6
100%-,
44.76
n
Fn 6

405.8428 ¦

HpCBStd, '

4a 1.01e4

44.02-49.21 ¦
\
0%-

Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02 EQ
Abs. Int.
-3.27e6
46.0
47.0
I I | I I
48.0
46.0

47.0
48.0
Rel. Int.
100%-
Fn 6
407.8398
HpGBStd. .
4a 9.92e3
44.02-49.21
0%-
_|__r
.4266
44,76
45.0
46.0
¦ i i i 'p i i ¦ i *r** [
47.0
¦f	t t
48.0
f "p * 1 I	1	J	1	1	1	1 I '"I | t I I 	 1 		 P ""	f n	I ¦«!|
45.0	46.0	47.0
	J—1—r=
48.0
1,64e6
49.0
-O.OOeO
RT
Abs. Int.
-3.20e6
-1.60e6
49.0
-O.OOeO
RT
Abs. Int.
-1.14e6
5.71e5
i ln [ "i O.OOeO
49.0 RT
Abs. Int.
1,06e6
•5.31e5
49,0
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
44.02-49.21'
0%-
I I f f
45.0
T	1	1	'—¦	1—
46.0
r r i
47.0
48,0
49.0
Abs. Int.
-6.28e6
-3,14e6
¦O.OOeO
RT
Results: P:\P9400_P9499\P94B4_6042 PCB\resouKes\P9464_6Q42_PC8_007RJ-D10.utp_res, saved 05-Aug-2008 09:19 (EE)	Peak annotation: Areas. Centmidsy
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 0246, 3138	Revised. 04-Aug-2008 15:13 58 (EE) Printed: OS-Aug-2008 09:23:22 Page 18 <£22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rei. Int.
100%
Fri 5
427.7835
OcCB-5
40 2 89e3
37.13-44.01
0%-
Rei. int.
100%-
Fn 5
429.7606
OcCB-5
4o 3.39e3
37.13-44.01
0%-
38.0
38.0
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02 EQ
PGB-198/199
S.86e6
42.75
PCB-2Q2
1.15e6
38.78
PCB-201
1.64e6
39.56
JL
PCB-200
PCB-2041^4^
4.24eS
40.13 aA
39.0
40.0
41.0
¦I— |	T | 1*1 1*1 | t
42.0	43.0
PCB-198/199
7.48e6
42.75
PC B-196
4,1Se6
43.31
PC B-202
1.27e6
38.78
PCB-201
1.90eS
39.56
PCB-200
	1,54e6
PCB-204 40 41
5 07e5 ^ a
40.13 N\
39.0
40.0
41.0
'"I ,,,n
42.0
PCB-196
4.41e6
43.31
43,0
Abs, int.
-1 42e6
•7.11e5
¦O.OOeO
44.0 RT
Abs. Int.
-1.59e6
•7.94e5
¦O.OOeO
44.0 RT
Rei. Int.
100%-
Fn 5
439,8038
OcCB Std.
4o 2.18e3
37.13-44.01
0%-
"i	i	r	f	
Rei. Int.
100%-
Fn 5
441.8008
OcCB Std.
4a 3 80e3
37.13-44.01
0%-
38.0
38.0
•'	r •'
39.0
40.0
41.0
42.0
ESiM2
442e6
<36.76
1,02eS
43.29
"*»	t—t	r-
39,0
40.0
41.0
42,0
43.0
I,l7e5
43_29
43.0
Abs, Int.
-9.71 eS
¦4.85e5
-O.OOeO
44.0 RT
Abs, Int.
1,07e6
•5.37e5
-O.OOeO
44.0 RT
Rei. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01
0%-
T
T"
' I ' '
38.0	39.0	40.0	41.0
Results: P:\P9400_P9499\P9464_6042 PC8\resovrces\P9464_6042_PCB_007RJ-D 10.utp_rvs. saved 05-Aug-2008 09:19 (EE)
AP Ultra Trace-Pm V3 993 User/System EE/EEC2-038 cc 0321. 6306
T
I I	t
42.0
43,0
Abs. Int.
-7.05e6
¦3.53e6
¦O.OOeO
44.0 RT
Peak annotation: Areas. Centmjtfs
Revised: 04-Aug-2008 15:26:14(EE) Printed: 0S-Aug-2Q08 09:23:23 Page 19 pt22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr; AutoSpec-Ultima MM3
Rel. Int.
100%-
Fn 6
427,7635
OcCB-6
4o 3.38e3
44.02-49.21
0%-
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Rel. Int.
100%-
Fn 6
429.7606
OcCB-6
4o 4.92e3
44.02-49.21
0%-
Rel. Int.
100%-
Fn 6
439.8038
OcCBStd.
4o 5.48e3
44.02-49.21
0%-
Rel. Int.
100%-
Fn 6
441.8008
OcCB Std.
4o 4.78e3
44 02-4921
0%-
PCB-195
2 S4ee
44.59
PCB-194

5.80e6

46.54
PCB-205
A
4.27e6

46.93
A
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02 EQ
Abs. Int.
-1.35e6
3.96e5
48.41
-6.74e5
45.0
46.0
PCB-195
3,1 le6
44.59
PCB-194
6.46e6
47.0
PCB-205
4.77e6
46,93
48.0
49.0
3.89e5
48.40
45.0
46.0
JS-194
3.17e6
46.52
47.0
ES-205
3.66e6
46.92
48.0
i
49.0
45.0
1 I
46.0
JS-194
ZM&T
4^52
47.0
ES-205j*
4.09er
46 <82
1—I—1
48.0
1.16e5
48.38
8.89e4
48.38
45,0
46.0
47.0
i ¦ [—*
48.0
-O.OOeO
RT
Abs. Int.
-1.51e6
¦7,54e5
-OOOeO
RT
Abs, Int.
-8.35e5
4.17e5
i i—| I "i 0, OOeO
49.0 RT
Abs. Int.
9.73e5
•4.87e5
49.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
44,02-49.21'
0%-
45.0
460
47.0
48.0
Results: P:\P9400_P9499\P9464_6042 PCB\wsoun;es
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Rel. Irtt.
100%-
Frt 6
461,7245
NoCB
4o 3.32e3
44.02-49,21
0%-
Sample ID: Run# II-ACD-M23-3
VS1R expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 12
Rel. Int.
100%-
Fn 6
463.7216
NoCB
4o 4.67e3
44.02-49.21
0%-
Rel, Int.
100%-
Fn 6
473.7648
IMoCBStd.
4o 2.85e3
44.02-49.21
0%-


PCB-206


4.83e6


48.40
A

PCB-207
A
PCB-208
2,31e6

1.92e6
45.17

44,39
A
A
A
PCB-208
2.50e6
44.39
ES-208
3.16e6
44.37
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02 EQ
Abs. Int.
-1.13e6
45.0
46.0
47.0
48,0
PC B-207
2.98e6
45,17
45.0
46.0
47.0
48,0
PCB-206
6,33e6
48.39
ES-206
2.38e6
48.38
45,0
1—r"
48.0
47.0
48.0

ES-20S-
Rel. Int.
4.1166
100%-,
44<37
A
Fn 6
A
475.7619 ¦

NoCB Std.

4o 2.77e3 .

44.02-49.21 ;

0%-
/ I
45.0
-i—|—
46.0
47.0
ES-208
49.0
49,0
49.0
¦5.63e5
-O.OOeO
RT
Abs. Int.
-1 ,50e6
• 7,48e5
-O.OOeO
RT
Abs. Int.
-7.63e5
•3.81 e5
-O.OOeO
RT
Abs. Int.
-9.09e5
4 54e5
48.0
49,0
•O.OOeO
RT
Rel. Int.
100%
Fn 6
404.9760
QC Check
44.02-49.21
0%-
45.0
46.0
47.0
48.0
49.0
Abs. Int.
-6.28e6
¦3.14e6
¦O.OOeO
RT
Results: P:\P9400_P9499W9464 S042 PCBSresoun:es\P9464_6042_PCB 007RJ.D10.utp_ms, saved 05-Aug-20Q8 09:19 (EE)
AP UttraTrace-Pm V3.993 User/System: E&EEC2-03B cc: 8761, 5269
Peak annotation: Areas, Centroids
Revised: 04-Aug-2008 15:26:41 (EE) Printed: OS-Aug-2008 09:23:25 Page 21 of/22
-------
AP Lab ID: P9464_6042_PCB_007RJ-D10
Instr: AutoSpec-Ultima MM3
Sample ID; Run# II-ACD-M23-3
VSIR expt: pcb0306_cl1-10 GC; pcbx90_a Vial: 12
Acq: 02-Aug-2008 01:17:17
User: CJL Datafile: 080802R02_EQ
Rel. Int.
100%-
Fn 7
497,6826
DeCB
4o 9.77e2
49,22-53.00
0%-
49.5
^ l r
50.5
51.0
51,5
52.0
52.5
Abs. Int.
r9J6e5
¦4.93e5
-O.OOeO
53.0 RT
Rel. Int.
100%-
Fn 7
499,6797
DeCB
4a 7,59e2
49.22-53,00
0%-
49.5
¦"i	|	»	r	r	i	j	i	r	i	i	i"" i	r	r	t	j	r
50.0	50.5
51.0
¦¦¦¦t	|	f	x	»	i	[	i	t	i	i	[¦	i	t	t	i	I	r	i	t	i	|	r,M
51,5	52.0	52.5
l1 '	
Abs. Int.
-8,75e5
¦4.37e5
-O.OOeO
53.0 RT
Rel. Int.
100%-
Fn 7
509.7229
DeCBStd.
4o8 83e2
49,22-53.00
0%-
49.5
50.0
50.5
51.0
51.5
52.0
¦ I '
52.5
Abs. Int.
-8.52e5
•4.26e5
¦O.OOeO
53.0 RT
Rel. Int.
100%-
Fn 7
511,7199
DeCBStd.
4a 6.89e2
49.22-53.00
0%-
49.5
50.0
50.5
51.0
51.5
52,0
52.5
Abs. Int.
-7,50e5
•3.75e5
-O.OOeO
53,0 RT
Rel. Int.
100%-
Fn 7
454.9728
QC Check
49.22-53,00'
0%-
' ' ' I 1
49.5
•••\	r	»	j	i	i	r	»	|""
50.0
50.5
51.0
1 ) '
51.5
52,0
T
52,5
*	T	T	f	T	1	T"
Abs. Int.
-6,79e6
•3.39e6
-O.OOeO
53.0 RT
Results: P:\P94O0_P9499SP94G4__6O42 PC8Resources\P94S4_S042_PCB_007RJ-D 10.utp_res, saved 0S-Aug-2008 09:19 (EE)	Peak annotation: Areas, Centroips
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 8386, 3244	Revised QI-Aug-2008 14 19 23 (EE) Printed: 05-Aug-2008 09:23:26 Page 22j/f22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-UItima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel. Int.
Fn 1 100%-
218.9856
QC (non-EQ)
10.43-15.00
0%.

T-T"
10.5
-i—|—i—r-
11.0
' I '
11,5
12.0
' I '
12.5
13.0
1 I 1
13.5
mT | |
14,0
"T—I | I
14.S
Abs. Int.
-6,86e7
• 3.43e7
-O.OOeO
15.0 RT
Fn 2
Rel. Int.
100%.
242.9856
QC (non-EQ)
15.02-20.50
0%-
I
16.0
I
17.0
18.0
19.0
20.0
Abs, Int.
-2.4987
. 1.24e7
¦ O.OOeO
RT
Fn 3
Rel. Int.
100%.
292.9824
QC (non-EQ)
20.52-26.00
0%.
21.0
22.0
23.0
24,0
25.0
Abs. Int.
-2.76e7
¦ 1.38e7
¦O.OOeO
2B.0 RT
Rel. Int.
Fn 4 100%-
330.9792
QC (non-EQ)
26.03-37.11
0%.
—r~
28.0
i i I i i i i I i i i i I
30.0
i i I i i i i I i i i i j
32.0	34.0
"T—'—'—1—1—I—
36.0
Abs. Int.
-2.92e7
1.46e7
O.OOeO
RT
Rel. Int.
Fn 5 100%.
366.9792
QC (non-EQ)
37.13-44.01
0%.
"I	1	1	1	1	1	1	1	1	1	1	»	1	1	T	1	1	1	—*
38.0	39.0
1 I '
40.0
41.0
i—|—(—i—*—f—j—t—i—t—i—|—r
42.0	43.0
Abs. Int
r-4.59e6
2.30e6
•O.OOeO
44.0 RT
Rel. Int.
Fn 6 100%.
454.9728
QC (non-EQ)
44.02-49.21
0%-
—1—
45.0
1
46.0
47.0
I
48.0
49.0
Abs. Int.
-7.28e6
• 3.64e6
¦O.OOeO
RT
Rel. Int.
Fn 7 100%.
454.9728
QC (non-EQ)
49.22-53.00
0%-
' I 1
49.5
1 I '
50.0
~i—|—i—r"
50.5
51.0
51.5
52.0
' I 1
52.5
¦T
Abs. Int.
-8.23e6
-4.11e6
-O.OOeO
53.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\resotirces\SBS_080802_PCB_RA.utp_res, saved OS-Aug-2008 09.20 (EE)
APUltraTrace-Pro V3 9S3 User/System: EE/EEC2-038 sec; 081-3)7
Peak annotation: Areas, Centroids
PKD: n/a Printed: 0$-Aug-2008 09:23:28 Paget of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
QC CHECK EQUALIZED
Sample ID: SIL7-27-1	?RIOR TO PROCESSING Acq: 02-Aug-2008 02:12:10
VSIR expt; pcb0306_c!1-10 GC: pcbx90_a Vial: 3	User: CJL Datafile: 080802R03_EQ
Fn 1
Rel. Int.
100%.
218,9856
QC Check
10.43-15.00
0%.
1 I ' '
10.5
i « i )—i—i—r-
11.0
-I-r-
T"r
12.5
—]—j—t—r—I—|—r-i—r-T
14.0	14.5
I ' ¦ ' 1 I
Abs. Int.
-6.92e7
¦ 3.468?
¦O.OOeO
' I '
11.5
12.0
13.0
13.5
15.0 RT
Rel. Int.
Fn 2 100%.
242.9856
QC Check
15.02-20.50
0%-
16.0
17.0
18.0
19.0
Abs. Int.
-2.46e7
-1.23e7
O.OOeO
—t—i—|—i—i—i—i—
20.0	RT
Fn 3
Rel. Int.
100%.
292.9824
QC Check
20.52-26.00
0%-
I
21.0
22.0
23.0
I
24.0
25.0
Abs. Int.
-2,6Se7
1.32e7
O.OOeO
26.0 RT
Fn4
Rel. Int.
100%.
330.9792
QC Check
26.03-37.11
i i	r—-i	1	r-
I
28.0
—|	i	i	r	i	|	i	I	p	I	|	r-
30.0
—I—1—r_
32.0
i | t i i i j i i
34.0
Abs. Int.
-2.82e?
• 1.4187
O.OOeO
—,—.—.—i—i—r
36.0	RT
Rel. Int.
Fn 5 100%-,
454.9728
QC Check
37.13-44.01
0%.
38.0
I I I I I
39.0
1 I 1
40.0
i—j—r
41.0
42.0
I ' ' 1 ' I 1
43.0
Abs. Int.
.29e6
•4.14e6
¦ O.OOeO
44.0 RT
Rel. Int.
Fn 6 100%.
404.9760
QC Check
44.02-49.21
0%-

—i	1—|—
45.0
46.0
47.0
48,0
—j—
49.0
Abs. Int.
8.69e6
.4 35e6
—f-O.OOeO
RT
Rel, Int.
Fn 7 100%
454.9728
QC Check
49.22-53.00
0%
Abs, Int.
B.74e6
4.37e6
O.OOeO
53.0 RT
Results; P:\P9400_P9499WS464_6042 PC8Sre$aume$mS_0SW02_PCB_RA.ulp_ms, sawed 05-Aug-2008 03:20 (EE)
AP UltraTrace-Pm V3.993 User/System: EBEEC2-03B
Peak annotation: Areas, Centmids
PKD: n/a Printed: 05-Aug-200B 09:23:29 Page 2 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIRexpt: pcb030B_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-20Q8 02:12:10
User: CJL Datafile: 080802R03_EQ
Rel, Int.
100%
Fn 1
188.0393
MoCB
4o 3 06e3
10.43-15-00
, 2.02e5
1.66eS 13.46
3.11e4
11.26
Abs. Int.
-5,68e4
2.84e4
O.OOeO
15.0RT
Rel. Int.
100%
Fn 1
190.0363
MoCB
4o 3.50e3
10.43-15.00

Abs. Int.
-2 37e4
1.19e4
OOeO
15.0 RT
Ret. Int.
100%
Fn 1
200.0795
MoCB Std.
4o5 51e3
10.43-15.00
T -ft ¦¦ i ¦¦¦ *	|MMT	i	s	¦!	y	<	»	t	t	|	»	i	t	i	|	i		i	t	¦j""
13,5	14.0	14.5
Abs. Int.
-1.01e4
5.04e3
O.OOeO
15.0 RT
Rel. Int.
100%-
Fn 1
202.07S6
MoCB Std.
4cr2.44e4
10.43-15.00
0% 	i' ''III—I—I—r—*—1—I—r—I—I—I—I—I—I—I—I—i I I I I—I I 1
10.5	11.0	11.5
12.0
i ¦ ¦ • ¦ i • • • ¦ i ¦ • ¦ ¦ i • ¦ ¦ ¦ i
12.5	13.0
13.5
i ¦ • • ¦ i •
14.0
14,5
-f—i—i—i—i—-0.0060
Abs. Int.
-1,46e5
¦ 7.30e4
15.0 RT
Rel. Int.
100%-
Fn 1
218.9856
QC Check J
10.43-15.00
0%-r-r
10.5
Abs. Int.
92e7
3.46e7
I ... i 0 .OOeO
15.0RT
Results: P:\P9400_P9499\P9461_6042 PCB\resoupcesSSBS_0SO8O?_PCB_RA utp_ms. saved O^Aug-2008 09:20 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-03B cc: 6079, 9768
Peak annotation: Areas, Centrolds
PKD: 04-Aug-2008 15:26:49 Printed: 05-Aug-2008 09:23:30 Page 3 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Dataffle: 080802R03 EQ
Rei, Int.
100%
Fn 1
222.0003
DiCB-1
4o4,16e3 -l
10.43-15.00
0%
Abs. Int.
-1.03e4
5.16e3
l f i i i I O.OOeO
15.0 RT
Rel. Int.
100%
Fn 1
223.9974
DiCB-1
4o 1,34e4
10.43-15.00
Rel. Int.
100%
Fn 1
234.0406
DiCB Std,
4o 1.01e4 .
10.43-15.00
Rel. Int.
100%
Fn 1
236.0376
DiCB Std.
4a 5.63e3
10.43-15.00
Rel. Int.
100%-
Fn 1
218.9856
QC Check
10.43-15.00

0%-K
I 1 1 11 I
10.5
11.0
I 11 1 1 I >
11.5
12.0
' I 1
12.5
	j	r""t	r
13.0
i | i i i i i i
13.5
"T,,M|	t	r	r	r-
14.0
14.5
Abs. (nt,
-2.90e4
1.45e4
-O.OOeO
15.0RT
Abs. Int.
r3.91e4
1.96e4
. ! ¦ i i i i i i ¦ i O.OOeO
14.5	15 0RT
Abs. Int.
-9.02e3
4.51e3
O.OOeO
15.0 RT
Abs. Int.
6.92e7
•3.46e7
¦O.OOeO
14.5
15.0 RT
Results: P:\P9400_P9499\P9464_6042 PC8\resoun:es\S8S_0808Q2_PCB_RA ulp_res. saved 05-Aug-2008 09:20 (EE)
AP UHmTrace-Pm V3.993 User/System: EE/EEC2-038 cc. 59 U. 4862
Peak annotation: Areas. Cantroids
PKD: 04-Aug-2008 15:26:49 Printed: 0S-Aug-2008 09 23 32 Page 4 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Inslr: AutoSpec-UItima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-20G8 02:12:10
User: CJL Datafiie: 080802R03_EQ
Rel. Int.
100%
Fn 2
222.0003
DiCB-2
4o 9.48e3
15.07-20.50
2.15e5
18,9?
Jill
18.0
19.0
20.0
Abs. Int.
-3.51e4
1.76e4
-O.OOeO
RT
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4a 2.26e4
15.07-20.50
0%-
,MT	F	J	?	T	J	t	|	I
16.0
17.0
18,0
19.0
Abs. Int.
-7.09e4
•3.55e4
20.0
-O.OOeO
RT
Rel. Int.
100%
Fn 2
234.0406
DiCB Std.
4o 1.36e4
15.07-20.50
Abs. Int.
-5.33e4
2.67e4
19.0
—i—.—,—.—i—i—.—f O.OOeO
20.0	RT
Rel. Int.
100%
Fn 2
236,0376
DiCB Std.
4o 6.20e3
15,07-20.50
16.0
17.0
18.0
19.0
20.0
Abs. Int.
-1.03e4
5,15e3
i—i—i—(-O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
15.07-20.50
18.0
19.0
20.0
Abs. Int.
2.46e7
1.23e7
-O.OOeO
RT
Results: P:\P94QQ__P9499\P9464 6042 PCB\resources\SBS_080802 PCS RA.ulp_res, saved 05-Aug-20QS 09:20 (EE!
AP UttraTmce-Pm V3.993 User/System: £&E£C2-038 cc: 3394. 1485
Peak annotation: Areas. Centroids
PKD: Q4-Aug-2008 15:26:49 Printed: OMug-2008 09:23:33 Page 5 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel. Int.
100%
Fn 2
255.9613
TrCB-2
4o 2,14e3
15.02-20.50
Abs. Int.
-5.28e3
2 64e3
O.OOeO
RT
Re!. Int.
100%
Fn 2
257.9584
TrCB-2
4o 2.85e3
15.02-20.50
Rel. Int.
100%
Fn 2
268.0016
TrCB Std.
4o 2.26e4
15.02-20.50
Rel. Int.
100%
Fn 2
269.9986
TrCB Std.
4o l.39e4
15.02-20 50
1.95e6
15.57
9.96e5
19.38
2.10e5
15.57
t—i—¦—r
19.0
Abs, Int.
-3.94e3
1.97e3
O.OOeO
RT
Abs. Int.
-4.98e5
2.49e5
O.OOeO
RT
Abs. Int.
-7.18e4
3,59e4
-O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
15.02-20.50
Abs. int.
-2.46e7
1.23e7
O.OOeO
RT
Results: P:\P9400_P9499V9464_6042 PC8be$ouKes\SBS_080802_PCB_RA.ulp_ms, saved 05-Aug-2008 09:20 (EE)
AP UltmTrace-Pm V3.993 User/System: EE/EEC2-03& cc: 3788, 3404
Peak annotation: Areas, Centroids
PKD: 04-Aug-2008 15:26:49 Printed: OS-Aug-2008 09:23:34 Page 6 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile 080802R03_EQ
Rel, Int.
100%
Fn 3
255.9613
TrCB-3
4o 3.73e3
20.52-26.00
3.1465
23.91
l.OeeS
25.49
. . 8.06e4
4.8064	25 14
24.75
Abs. Int.
-7 16e4
3.58e4
O.OOeO
21,0
22.0
23,0
24.0
25.0
26.0 RT
Rel. Int.
100%
Fn 3
257.9584
TrCB-3
4o2.86e3
20.52-26.00
Rel. Int.
100%>
Fn 3
268.0016
TrCBStd,
4a 2.97e4
20.52-26.00
3.61 e5
1.1265
7.84e4
25.50
4.57e4
24.76
3.3564
25.13
21.99
7.Q9e5
23.24
Abs. Int.
-7.50e4
3.75e4
O.OOeO
26.0 RT
Abs. Int.
-1,97e5
9.83e4
O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
40 1.64e4
20.52-26.00
0%-
21,0
22.0
23.0
24.0
25.0
Abs. Int.
-1.63e5
¦8.14e4
O.OOeO
26.0 RT
Rel, Int.
100%
Fn 3
292.9824
QC Check
20.52-26.00
21.0
22.0
Abs. Int.
<-2.65e7
1,32e7
O.OOeO
23.0
24.0
25.0
26.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\zesauives\SBS_080802_PCB_RA utp_res. saved OS-Aug-2008 09:20 (£E)
APUttraTrace-Pro V3 993 User/System: EE/EEC2-038 cc 6700, 4476
Peak annotation: Areas. Centra ids
PKD: 04-Aug-2008 15:26:49 Printed: 05-Aug-2008 09:23:35 Page 7 Of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC; pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel, Int.
100%
Fn 2
289.9224
TeCB-2
4ot.40e3
15.02-20.50
Abs. Int.
-3.05e3
1.52e3
OOeO
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4a 2.09e3
15.02-20.50
16.0
17,0
18,0
19,0
20.0
Abs. Int.
-5.25e3
•2.63e3
¦O.OOeO
RT
Rel. Int.
100%
Fn 2
301.9626
TeCB Std.
4o 3.07e3
15.02-20.50
Abs. Int.
-6.62e3
3.31e3
i	1	.	r—H	r—f 0.0060
20.0	RT
Rel. Int.
100%
Fn 2
303.9597
TeCB Std.
40 3.60e3
15.02-20.50
Abs. Int.
-1.06e4
5.29e3
O.OOeO
RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
15.02-20.50
16.0
17.0
18.0
Results: P:\P9400_P949W9464J6042 PCB\m$auKes\SBS 080S02_PCB_RA.utp res, saved 05-Aug-2008 09:20 (EE)
AP UltmTmce-Pm V3.993 User/System: EEJEEC2-038 cc: 9305, 7936
Abs. Int.
,46e7
1,23e7
O.OOeO
19 0	20.0	RT
Peak annotation: Areas, Centroids
PKO: 04-Aug-20Q8 15:26:49 Printed; 0$~Aug~2Q08 09:23:36 Page 6 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cI1-t0 GC: pcbx90_a Viai: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel. Int.
100%
Fn 3
289.9224
TeCB-3
4a 1,50e3
20.52-26.00
Abs. Int.
-3 51e3
1,75e3
i ¦ i—i—[-O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
291.9194
TeCB-3
4a 2.73e3
20.52-26.00
Abs. Int.
-7.93e3
3.97e3
O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
301.9626
TeCB Std.
4o1.88e3
20.52-26,00
Abs. Int.
-6.80e3
3 40e3
O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
303.9597
TeCB Std.
4a 6.12e3
20.52-26.00
Abs. Int.
-1.34e4
6.69e3
O.OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
292.9824
QC Check
20.52-26.00 .
Abs. Int.
-2.65e7
1.32e7
O.OOeO
22.0
23.0
24.0
25.0
26.0 RT
Results: P:\P9400_P9499\P9464_S042 PCB\re$ource$\SBS_08B802_PC8_RA.utp_m$, saved OS-Aug-2008 09:20 (EE)
AP UttmTrace-Pro~V3.993 User/System: EE/EEC2-038 cs~6380, 6888
Peak annotation: Amas, Centmids
PKD: 04-Aug-2008 15:26:49 Printed: 05-Aug-200B 09:23:37 Page 9 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: S1L7-27-1
VSIR expt: pcb03(J6_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User CJL Datafile: 080802R03 EQ
Rfkio) 2.44e5
100%—| 26.28
Fn 4
289.92M
TeCB-fc^,!
4a 2.6?e3'
26.03-32,99
Rel. Int.
100%
Fn 4
291.9194
TeCB-4
4a4 60e3
26.03-32.99
2.43e5 - ,
30.45 2 27e5
30.94
Abs, Int.
-5.56e4
2.78e4
O.OOeO
RT
irMT^iTv
7.6Qe4
31.78
4,22e4
27.74
2.61 e4
28.61
2.66e4
31.31

3.4765
3.3365
30.48
2,97eS
26.27
30.94
1.0365
31.79
Abs. Int.
-7.98e4
3.99e4
OOeO
Rel, Int.
100%
Fn 4
301.9626
TeCB Std.
4o4.13e3
26.03-32.99
28.0
31.0
32.0
Abs. Int.
-1.35e4
6.73e3
-O.OOeO
RT
Rel. Int.
100%
Fn 4
303.9597
TeCB Std.
4a 6.80e3
26.03-32.99
0%
31.0
32.0
Abs. Int.
-2.02e4
1.01e4
-O.OOeO
RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
26,03-32.99
Results: P\P9400_P9499\P9464_6042 PCBVesources\SBS_080802_PCB RA.utp ms, saved OS-Aug-2008 09:20 (EE)
AP UliraTmce-Pm V3.993 User/System EE/EEC2-038 cc: 6725. 6282
Abs. Int.
«-2.82e7
1.41e7
O.OOeO
RT
Peak annotation: Areas Centroids
PKD: 04-Aug-200B 15:26 49 Printed: OS-Aug-2008 09:23:38 Page JO of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Dataftle: 080802R03 EQ
Rel. Int.
100%-
Fn 3
323.8834
PeCB-3
4ct 1.98e3
20.52-26.00

Abs. Int.
-4.54e4
•2.27e4
0 OOeO
26.0 RT
Rel. Int.
100%-
Fn 3
325,8804
PeCB-3
4o 3.53e3
20.52-26.00
21.0
22.0
23.0
24.0
3,27e5
24.75
25.0
Abs. Int.
-7.25e4
•3.63e4
-O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
337.9207
PeCB Std.
4a 3.94e3
20.52-26.00
24.0
Abs. Int.
-1.15e4
5.77e3
-O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
339.9177
PeCB Std.
4o 4.95e3
20.52-26.00
24.0
Abs. Int.
r 1.3264
-6.59e3
-O.OOeO
26.0 RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
20 52-26.00
Abs. Int.
-2.65e7
1.32e7
O.OOeO
26.0 RT
Results: P:\P9400_P9499\P9484_6042 PCBVesources\SBS_0808Q2_PCB_RA.utp_res, saved 05-Aug-2008 09:20 (EE)
AP Ultra Trace-Pro V3.993 User/System EE/EEC2-038 cc 3556. 1909
Peak annotation: Areas. Cenfroids
PKD: 04-Aug-2QQ8 15:26:49 Printed: 05-Aug-200S 09:23:39 Page 11 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
instr: AutoSpec-Ultima MM3
Sample 10: SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel. Int.
100%-
Fn 4
323,8834
PeCB-4
4ct 2,05e3 -
26,03-37.11 ¦
27 AO-*'— -—-28;36
1.83e5
X? ; ^! -3V7>.38e5
	I -33.59,
Abs. Int.
r4.37e4
2.18e4
1.21eS
30.46
4.73e4
34.76
00e0
Rel. Int.
100%
Fn 4
325,8804
PeCB-4
4o 4.27e3
26.03-37.11
2.96e52,fe5
M it 33.59
3,44e5
30.47
1.84e5
28.36
1.82e5
27.39
WJL!
Abs, Int.
r6.34e4
3.17e4
OOeO
30,0
32.0
34.0
36,0
Rel. Int.
100%.
Fn 4
337,9207
PeCB Std.
4o 5.13e3
26.03-37 11
28.0
30.0
32.0
34.0
36.0
Abs. Int.
-3.68e4
1.84e4
O.OOeO
RT
Rel. Int.
100%
Fn 4
339,9177
PeCB Std.
40 5.37e3
26,03-37.11 H
8.80e4 ,
32.87 2.65e4
1.64eS
36.02
Abs. Int.
-4.29e4
2.14e4
O.OOeO
30.0
32.0
34.0
36.0
Rel. Int.
100%
Fn 4
330.9792
QC Check
26.03-37.11
Abs. Int.
-2.82e7
1.41e7
O.OOeO
Results: P:\P940Q_P9499\P9464_6042 PCBVesources\S8S_080802_PCB_RAvtp_res, saved 0S-Aug-2008 09:20 (EE)
AP UttmTmce-Pro V3.SS3 User/System: EEMEC2-038 cc: 7409, 4667
Peak annotation; Areas, C&ntroids
PKD: 04-Aug-2QQ8 15:26:49 Printed: 0$-Aug-2008 09:23:40 Page 12 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cJ1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Oatafile: 080802R03_EQ
Rel. Int.
100%-
Fn 5
323.8834
PeCB-5
4o 4.23e3
37.13-44.01
0%-
Rel. Int.
100%-
Fn 5
325.8804
PbCB-5
4o4 15e3
37.13-44.01
0%-
1.09eS
40.99
6,58e4
30.07
f-r-
*1—1—p-i»
38.0
¦ i r i n t
	
2,67eS
39.70
-A.
38.0
39.0
i-pi '-t i * ^
40.0
¦T	t'm"1	|	I	I	T	t			i|i

39.0
40.0
	I""
2 22e6
41.00
9.65e4
42.12
_f\

42.0
43,0
1 7n"°'°*'	
41.0
9.77e4 2|1.®5
41 73 42->3
^av.1.T^TV
42.0
> ! 1 I* i i f|'i i i*"r* |
43.0
Abs. Int.
-2.08e5
1.04e5
¦O.OOeO
44.0 RT
Abs. Int.
-4.49e5
•2.24e5
•O.OOeO
44.0 RT
Rel. Int.
100%
Fn 5
337.9207
PeCB Std.
4o 1.16e4
37,13-44.01
Rel. Int.
100%.
Fn 5
339.9177
PeCB Std.
4o 1,45e4
37.13-44.01
5.28e4
38.00
9.51e5
42.92
5,51e4
37.31
1.9665
41.08
1,13e5
37.9
Abs. Int.
-1.05e5
5,23e4
O.OOeO
44.0 RT
40.0
Abs. Int.
-1.20e5
6.01 e4
-O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01
0%-
¦¦r	»	i	r	t	i"
38.0
39.0
40.0
41.0
42.0
43.0
Abs. Int.
-8.29e6
•4,14e6
¦O.OOeO
44.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\m$Ources\SBS_080B02_PCB_RA.utp_ms, Saved 05-Aug-200B 09:20 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc 0915. 2209
Peak annotation: Areas, Centroids
PKD: 04-Aug-2008 15:26:49 Printed: OS-Aug-2008 09:23:41 Page 13 of 22
-------
AP Lab ID: SBS_0808Q2_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SI 17-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-20Q8 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel. Int.
100%
Fn 4
359.8415
HxCB-4
4o 2.41 e3
27.99-37.11
3.0le5
-f'lff'n.
3.91e4
36.40


36.0
Abs. Int.
-7.08e4
-3.54e4
O.OOeO
37 0 RT
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4cr 1,54e3
27.99-37.11
0%	t
28.0	29.0
2.51 e5
29.51
30.0

31.0
32.0
2.94e4
36.39
Abs. Int.
-6.22e4
-3.11e4
33.0
¦» fir.|iif\	-0.
l.OOeO
34.0
35.0
36.0
37,0 RT
Rel. Int.
100%
Fn 4
371.8817
HxCB Std. '
4o4 74e3 "
27.99-37.11
0%
28.0
Rel, Int.
100%
Fn 4
373.8788
HxCB Std.
40 5.31e3
27.99-37.11
1.05e5
32.80
3.24e4
33.26
3.48e4
1.49e5
33.19
6.17e4
32.81
30.0
31.0
32.0
I | I I I I | I I I 1 | » I I I | 1 I
34.0	35.0	36.0
Abs. Int.
-3.57e4
1.78e4
•j-4- O.OOeO
37.0 RT
Abs. Int.
r-4.17e4
-2.09e4
-O.OOeO
37.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
27.99-37.11
i | i r i i j i
34.0
Abs. Int.
-2.81e7
1.41e7
Results: P:\P9400_P9499\P9464_8042 PCB\re$ources\SBS_080802_PC8_RA.utp_teS. saved 05-Aug-2008 09:20 (EE)
AP UltraTrace-Pm V3.993 User/System EE/EEC2-038 cc: 9927. 3632
i i i i—i i i—p-f-O.OOeO
37.0 RT
Peak annotation: Areas. Centroids
PKD: 04-Atig-2008 15:26:49 Printed: 05-Aug-2008 09:23:42 Page 14 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aus-2008 02:12:10
User: CJL Datafile: 080802R03_EQ
Rel. Int.
100%-
Fn 5
359.8415
HxCB-5 ;
4o 2 66e3
37.13-44.01 •
2.59e5
37.46
spffi
3.38e4
39.87
Abs. Int.
-6 38e4
3.19e4
O.OOeO
42.0
43.0
44,0 RT
Rel. Int.
100%-
Fn 5
361.8385
HxCB-5
4a 1 60e3
37.13-44.01
0%-
2.21 ©5
37.46

2.24e4
39.88
I	n 1.111	j .—^ ^	—
38.0
8.85e3
42,66
39.0
40.0
41.0
Abs. Int.
-5.23e4
¦2.62e4
•O.OOeO
44.0 RT
Rel. Int.
100%
Fn 5
3718817
HxCB Std.
40 8.47e3
37.13-44.01
Rel. Int.
100%
Fn 5
373.8788
HxCB Std.
4o 1.17e4
37.13-44.01
1.7305
42.97
Abs. Int.
-3.19e4
1.59e4
O.OOeO
44.0 RT
1.3265
5.99e4
43.01
2.43e4
O.OOeO
44.0 RT
Abs. Int.
-4.86e4
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01 "
0%-
38.0
-r-r
39.0
40.0
-'	I 1 1 1 ' I
41.0
,MT	T	I	|	T	T	1	1	]	r	t	1	r	J	T	7	T	T	J""
42.0	43.0
Results. P:\P9400_P9499\P9464_6042 PCB\msources\$BS_080802_PCB_RAutp_res. saved 0S-Aug-200B 09:20 (EE)
AP UltraTrace-Pru V3.993 User/System: EE/EEC2-038 cc: 1496. 7645
Abs. Int.
-8.29e6
•4.14e6
-i—f-O.OOeO
44.0 RT
Peak annotation: Areas, Centroids
PKD: 04-Aug-2008 15:26:49 Printed: 05-Aug-2008 09:23:43 Page 15 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID; SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel, Int.
100%-
Fn 4
393.8025
HpCB-4 J
4a 1,44e3
30,01-37.11 ¦
Rel. Int.
100%
Fn 4
395.7995
HpCB-4
4o1.57e3
30.01-37.11
Rel. Int.
100%
Fn 4
405.8428
HpCB Std.
4a 3.84e3
30.01-37.11
2.2365
Abs. Int.
-5.82e4
-2.91 e4
m^i		O.QOeQ
pn>	pf ~u ¦
p	, t
37.0 RT
i.Bies
34.96

37.0 RT
1.6464
34.66
1,21e4
34.18
37.0 RT
Abs. Int.
-4.16e4
2 08e4
O.OOeO
Abs. Int.
-1.30e4
6.51e3
4-O.OOeO
Rel. Int.
100%
Fn 4
407,8398
HpCB Std.
4a 2.97e3
30.01-37.11
1.49e4
33.16
1.26e4
37,0 RT
Abs. Int.
-1 43e4
7.17e3
O.OOeO
Rel. Int.
100%-
Fn 4
330.9792
QC Check
30.01-37.11"
0%-
31.0
i i I r i i i
32.0
33.0
T-1-
34.0
35.0
Results: P:\P9400_P94S9\P9464_6042 PCB\resources\SBS_0B0802 PCB_RA.utp_ms, saved 0$-Aug-2008 09:20 (EE)
AP UltraTrace-Pro V3.993 User/System EE/EEC2-038 cc 7386, 8245
36.0
i
Abs. Int.
2.81 e7
¦1.41e7
^-O.OOeO
37.0 RT
Peak annotation: Aneas, Centroids
PKD: Q4-Aug-2008 15:26:49 Printed: 05-Aug-200B 09 23:45 Page 16 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03_EQ
Rel. Int.
100%-
Fn 5
393.8025
HpCB-5
4a 3.59e3
37.13-44.01
2.04e5
37.74
38.0
39.0
40.0
41,0
42.0
43.0
Abs. Int.
-5.38e4
•2.69e4
-O.OOeO
44.0 RT
Rel. Irit.
100%
Fn 5
395.7995
HpCB-5
4o2.59e3
37.13-44.01 •

2.05e5
37,73
Abs. Int.
-5.66e4
2.83e4
•O.OOeO
44.0 RT
Rel. Int.
100%
Fn 5
405.8428
HpCB-5 Std
4a 6.29e3
37.13-44.01 -i
i r f | r i
38.0
Abs. Int.
-1.69e4
8.47e3
O.OOeO
44.0 RT
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std.
4a8.67e3
37.13-44.01
Abs. Int.
-2.73e4
l.36e4
44.0 RT
t—i—i—! - O.OOeO
Rel. Int.
100%-
Fn 5
454.9728
QC Check
37.13-44.01'
0%-
38.0
39.0
40.0
¦"T	%	|	T	T	I""
41.0
42.0
Results: P:\P9400_P9499\P9464_6042 PCB\msaurces\SBS_080802_PCB_RA.utp_re$, saved OS-Aug-2008 09:20 (EE)
AP UltraTrace-Pm V3.993 User/System EE/EEC2-036 cc: 6072. 0534
43.0
Abs. Int.
-8.29e6
4.14e6
-f-O.OOeO
44,0 RT
Peak annotation: Areas, Centmids
PKD 04-Aug-2008 15:26:49 Printed: 05-Aug-20QB 09:23:46 Page 17 of 22
-------
AP Lab ID; SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VS1R expt: pcb0306_c!1-10 GC: pcbx90_a Vial; 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel, Int.
100%-
Fri 6
393.8025
HpCB-6
4o3.51e3
44,02-49.21
45.0
46.0
47.0
48,0
49.0
Abs. Int.
-4,74e4
•2.37e4
¦O.OOeO
RT
Rel. Int.
100%n
Fn 6
395.7995
HpCB-6
4a 3.24e3
44.02-49,21
Abs. Int.
-7.65e3
3,82e3
O.OOeO
Rei, Int.
100%
Fn 6
405,8428
HpCB Std.
4o 9.83e3
44,02-49.21
Abs. Int.
-3.53e4
1 _77e4
1—(—i—i—«—i—|—i—i—i—i—|—i O.OOeO
48.0	49.0 RT
Rel. Int.
100%
Fn 6
407.8398
HpCB Std.
4cr 1 23e4
44.02-49.21
6.63e4
47.87
Abs. Int.
-7.20e4
3.60e4
O.OOeO
RT
Rel, Int.
100%-
Fn 6
404.9760
QC Check
44 02-4921
0%-
"I—1—
45,0
46.0
47,0
'"I	T	r	f	T	J	I	V"
48.0
Results: P:\PB400_P94m\P9464_6042 PCB\rs$Ouree$\SBS_OS08O2_PCB_RAMip^res, saved 0S-Aug-2008 09:20 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 9264, 0334
49.0
Abs. Int.
8.69e6
¦4.35e6
¦O.OOeO
RT
Peak annotation: Areas, Centroids
PKD: 04-Aug-2008 15:26:49 Printed: 05-Aug-2008 09:23:4? Page 18 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial; 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel. Int,
100%
Fn 5
427.7635
OeCB-5
4
-------
AP Lab ID: SBS_080802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt: pcb0306_c!1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2Q08 02:12:10
User: CJL Datafile: 080802R03 EQ
Rel. Int
100%
Fn 6
427,7635
OcCB-6
4o 3.63e3
44.02-49,21
45.0
46.0
47,0
48,0
49,0
Abs. Int.
-1.28e4
6.41 e3
O.OOeO
RT
Rel. Int.
100%
Fn 6
429,7606
OcCB-6
4o3 25e3
44.02-49.21
Abs. Int.
-8 92e3
-4.46e3
O.OOeO
RT
Rel. Int.
100%-,
Fn 6
439.8038
OcCB Std.
4a 6.16e3
44.02-49
Abs. Int,
r1.21e4
6.04e3
OOeO
46.0
47.0
48.0
49.0
Rel, Int.
100%
Fn 6
441,8008
OcCB Std.
4a 6 92e3
44.02-49.21
47.0
Abs. Int.
r 1.73e4
8.67e3
-O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
44.02-49.21"
0%-
45.0
46.0
47.0
48.0
Rssults: P:\PS4Q0_P9499\P94S4_e042 PCBVesource$)SB$J)80802_PC8_RA.utp_ms. saved 05-Aug-2008 09:20 (EE)
AP U/fra Trace-Pro V3.993 User/Sysfem EE/EEC2-038 cc~0?11,3362
49.0
Abs. Int,
-8.69e6
-4.35e6
¦O.OOeO
RT
Peak annotation: Areas. Centroids
PKD: 04-Aug-200S 15:26:49 Printed: OS-Aug-2008 09:23:49 Page 20 of 22
-------
AP Lab ID; SBS_08Q802_PCB_RA
Instr: AutoSpec-Ultima MM3
Sample ID; SIL7-27-1
VSIRexpt: pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03 EQ
Rei. Int.
100%
Fn 6
461.7245
NoCB
40 3.85e3
44.02-49.21
Rel. Int.
100%
Fn 6
463.7216
NoCB
4 a 6.29e3
44.02-49.21
Rel. Int.
100%-
Fn 6
473.7648
NoCB Std.
4a 2 17e3
44 02-49.21 H
45.0
46.0
47.0
48.0
49.0
Abs. Int.
-8.76e3
4,38e3
O.OOeO
RT
Abs. Int.
-1.57e4
7 86e3
i—,—i-O.OOeO
49,0 RT
Abs. Int
9.90e3
l.81e4
47.57
4 95e3
O.OOeO
49.0 RT
Rel. Int.
100%-
Fn 6
475.7619
NoCB Std.
4o 3.44e3
44.02-49.21
Rel. Int,
100%-
Fn 6
404.9760
QC Check
44,02-49.21"
0%-
45.0
47.0
46 0
47.0
Results: P:\P94W_P9499V9464_6042 PCB*esourceS\SBS_080B02_PC8_RA utp_res, saved 05-Aug-2008 09 20 (EE)
AP UttmTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 6921. 6662
48.0
48.0
49.0
49.0
Abs. Int.
-7.79e3
3 90e3
-O.OOeO
RT
Abs. Int.
-8 69e6
-4.35e6
-O.OOeO
RT
Peak annotation: Areas, CentroMs
PKD: 04-Aug-2W8 15:26:49 Printed: 05-Aug-2008 09:23:50 Page 21 of 22
-------
AP Lab ID: SBS_080802_PCB_RA
Instr; AutoSpec-Ultima MM3
Sample ID: SIL7-27-1
VSIR expt. pcb0306_cl1-10 GC: pcbx90_a Vial: 3
Acq: 02-Aug-2008 02:12:10
User: CJL Datafile: 080802R03_EQ
Rel. Int.
100%-
Fn 7
497.6826
DeCB
4c 9.77e2
49.22-53.00
Rel, Int.
100%
Fn 7
499,6797
DeCB
4o 1.06e3
4f.22-53.00
3.73e4
49.73
1.1864
2.25e4
49.72
Abs. Int.
-7.85e3
3.93e3
O.OOeO
53,0 RT
Abs, Int.
1.01e4
5,04e3
-4* O.OOeO
53.0 RT
Rel. Int.
100%
Fn 7
509.7229
DeCB Std.
4a9 90e2
49.22-53,00
Abs, Int.
-6,77e3
3.38e3
O.OOeO
53.0 RT
Rel. Int.
100%-
Fn 7
511.7199
DeCB Std.
4a 8.64e2
49.22-53.00
50.0
50.5
51.0
51.5
52.0
52.5
Abs. Int.
-4 51e3
2.25e3
-O.OOeO
53.0 RT
Rel, Int
100%-,
Fn 7
454,9728
QC Check
49.22-53.00
0%-
49.5
50.0
50.5
51.0
51.5
"" I"
52.0
! | f
52.5
¦ | ¦ ¦ i i O.OOeO
53,0 RT
Abs. Int.
-8.74e6
¦4,37e6
Results: P:\P9400_P9499\P9464_6042 PCBVesources\SBS_080802_PCB_RA utp_res. saved QS-Aug-20QB 09:20 (EE)
AP UltraTracc-Pm V3 993 User/System: EE/EEC2-038 cc: 2444, 1495
Peak annotation: Areas, Centmitts
PKD: 04-Aug*2008 15:26:49 Printed: OS-Aug-2008 09:23:51 Page 22 of 22
-------
AP Lab 10: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC:pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel. Int.
Fn 1 100%
218.9856
QC (non-EQ)
9.03-13.00
Rel. Int.
Fn 2 100%
242.9856
QC (non-EQ)
13.02-17.79
Rel. int.
Fn 3 100%
292.9824
QC (non-EQ)
17.81-23,26
Rel. Int.
Fn 4 100%.
330,9792
QC (non-EQ)
23.27-34.14
Rel. Int.
Fn 5 100%
366.9792
QC (non-EQ)
34.16-41.15
Rel. Int.
Fn 6 100%
454.9728
QC (non-EQ;
41.17-46.41
Rel. Int.
Fn 7 100%
4S4.9728
QC (norvEQ) j
46,42-54.01
Abs. Int
4.93e7
2.46e?
OOeu
	
13,0 RT
Abs. Int
2,3Se7
1.19e7
QOeO
Abs. Int
2.54e7
1.27e7
OOeO
Abs. Int
2.79*7
-1.39*7
OOeO
34,0 RT
Abs. m
4.26e6
2.14e6
Abs. Int
7.90e6
3 95e6
Abs. Int
1.12«7
5.61 e6
54,0 RT
Results: P:\P9400__P9499\P9464__6042 PCB\resources\P9464__6042__PCB__007.utp__res, saved OS-Aug-2008 08:25 (EE)
AP UltmTmce-Pm V3.993 User/System: EE/EEC2-038 see; 292-050
Peak annotation: Areas. Centroids
PKD: n/a Printed: Q5-Aug-200B 08:32:23 Page 1 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10„mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2O08 14:32:30
User: JLJ Datafile: 080724V16 EQ
Rel. Int.
Fn 1 100%.
218.9856
QC Check
9.03-13.00

—'—p—[—-t—i—i—r-
9.5
10.0
ill'
10.S
11.0
11.5
~i—i—i—|—i—r~
12.0
11 I '
12.5
Abs. tnt.
-5.13e7
¦2.57e7
-O.OOeO
13.0 RT
Rel. Int.
Fn 2 100%.
242.9856
QC Check
13.02-17.79
0%.
13.S
• I '
14.0
14.5
15.0
15.5
' I '
16.0
i i i—|—r
16.5
17.0
• f
17.5
Abs. tnt,
-1,68e7
•8.39e6
¦O.OOeO
RT
Rel. Int
Fn 3 100%-
292.9824
QC Cheek
17.81-23.26
0%-
—I—
18.0
19.0
—I—
20.0
—I—
21.0
22.0
—I—
23.0
Abs. Int.
-1.90e7
19.48eS
-O.OOeO
RT
Rel. Int.
Fn 4 100%-
330.9792
QC Check
23.27-34,14
0%.
Abs. Int
2.85B7
1.42e7
O.OOeO
34.0 RT
Rel, Int.
Fn S 100%-,
454.9728 :
QC Check :
34.16-41.15 :
0%-
35.0
t-t-t
36.0
1 I '
37.0
1 I '
38.0
7 I '
39.0
40.0
Abs. Int.
f-1.36s7
-6.79eS
41,0
-O.OOeO
RT
Rel. Int.
Fn 6 100%-
404.9760 ;
QC Check j
41.17-46.41 ;
0%-
42.0
I
43.0
44.0
45.0
46.0
Abs. Int.
,-1.12e7
-5.60e6
-O.OOeO
RT
Rel. int.
Fn 7 100%-
454.9728
QC Check
46.42-54.01
0%J
Abs. mt
-1.2567
6.24e6
O.OOeO
54.0 RT
Results P:\P9400_P9499\P9464_6042 PCB\resources\P9464_6042_PCB OOT.utp res, saved G5-Aug-200a 08:25 (EE)
AP UttmTmce-Pm V3.993 User/System EE&EC2-038
Peak annotation: Areas, Cenlroids
PKD: n/a Printed: 05-Aug-2008 08:32:24 Page 2 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID; Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16 EQ
Rel. Int.
100%-
Fn 1
188,0393
MoCB
4o 1,85e4
9.03-13.00
Q%-
1.58e9
9.61
9.5
3.57e9
11.43
I { I I I I
10.0
10.5
11.0
8.13eS
11. S8
I.ubea
II.74
-i—i—|—i—i—i—r-
11.5
12.0
12.5
Abs. Int.
-8.18e8
-4.09e8
•O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
180.0363
MoCB
4o 1.13e4
9.03-13.00
0%-
4.64e8
9.61
I,16e9
II.43
~|	1 I ' f 1 'I | 1 ! 'I I f I I I I | I
9.5	10.0
10.5
11.0
11.58
3.82e8
11.75
11.5
12.0
Abs. Int.
-2.66e8
-1.33e8
O.OOeO
I | I I i I | I I I I | I I I »
12.5	13.0RT
Rel. Int.
100%-
Fn 1
200.0795
MoCBStd. .
4o 1 ,89e4
9.03-13,00
0%-
l ^ i l i—i—r-
2-02e7
I.39e7
II.57
7.94e6
11.75
10.0
5.74e
—1 '	!	1—|	1—I—I	1—|	1—I	1	!—|	1	1—1—1—{—I	1 I 1 'J I I'll |
10,5	11,0	11,5
3.55e5
12.80
1—I—I—r—i—i—i" i f "i—i—i—i—i ""i1 I1
Abs. Int.
-5 64e6
2.82e6
¦O.OOeO
12.0
12,5
13.0RT
Rel. Int.
100%
Fn 1
202.0766
MoCB Std,
40 1.24e5
9,03-13.00
Z,37e6
11.54 1.24e6
1.70
1,74e6
12,04
1.79e6
12.51
8.16e5
10.52
Abs, Int.
-2.23e6
-1.11 e6
O.OOeO
13 0RT
Rel. Int.
100%.
Fn 1
218.9856
QC Check
9.03-13.00 '
' ' I
12.5
Abs. Int.
-5.13e7
2.57e7
O.OOeO
13.0RT
Results: P;\P9400_PS4mSP$464 6042 PCB\resources\P9464_6042_PCB_007Mtp res, saved 05-Aug-2008 08:25 (E£)
AP UttmTrace-Pm V3.S93 User/System: EEEEC2-038 cc: 3400, 0006
Peak annotation: Areas, Centmitis
PKD: OS-Aug-20oa 08:25.25 Printed: 0S-Aug-2008 08:32:25 Page 3 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1 -10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2O08 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel. Int.
100%-
Fn 1
222.0003
DiCB-1
4a 8.99e3
9.03-13.00
0%-
9.5
1 arioR 2,75e6
i.aueo 11 qr
11.78 11'9b'
~I	1	!	1	1	T—l	1	1	1	1	1	1	n	!	!	1	1	1	1	1	1	1	1	!"
I	1	I I" I	1	1	1	1	1	1 " j
10,0
10,5
11,0
11,5
12.0
12.5
Abs. Int.
-2.33e7
¦1.16e7
¦O.OOeO
13.0 RT
Rel, Int.
100%-
Fn 1
223.9974
DiCB-1
4o 2.72e4
9.03-13.00
0%-
,M|	r	r	t	t	I	?	r	i	t	j	i	i	r	i	|	fm
9.5	10.0
¦ 1 *
10.5
3,54e7
12.09

11.0
'"1	1	|	I	T	T	
11,5
12.0
12.5
-rt-
Abs, Int.
-1.54e7
•7.69e6
•O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
234.0406
DiCBStd. :
4a 1,53e4
9.03-13.00
0%-
9.5
10.0
10.5
11.0
11.5
1.36e7
12.05
_ 2.46e6
5.55e5 11 go
11.75	"
12.0
12.5
Abs. Int.
-8.05e6
•4.02e6
¦O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
236.0376
DiCB Std
4o 1,08e4
9.03-13.00
0%-
i—i—i—i—i—?—I—i—r
I '
9.5
8,69e6
12.05
-j—i—i—i—i—j—i—i—i—p—|—i—'—i—i—|—i—i—i—i—|—i—i—i—j—|—i—i i t |—i—i—i—i	| (	
10.0	10,5	11.0	11.5
5,90e5 11 ga
11.77
12.0
' I '
12.5
Abs. Int.
-5.14e6
•2.57e6
•O.OOeO
13.0RT
Rel. Int.
100%-
Fri 1
218.9856
QC Check
9.03-13.00 '
	
0%-
9.5
10.0
I | I I I
10.5
» I I I J I > 1
11.0
11.5
¦ r ¦
12.0
12.5
Abs. Int.
-5.13e7
•2.57e7
¦O.OOeO
13.0RT
Results: P:\P9400_P9499\P9484_6042 PCB\resources\P9«64_6042_PCB_007 ulp_res. saved 0S-Aug-2008 08:25 (EES
AP UltmTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 6577. 518?
Peak annotation: Areas. Centmids
PKD: Q5-Aug-2008 08:25 25 Printed: OS-Aug-2008 08 32:26 Page 4 of 22
-------
AP Lab ID: P9464_6Q42_PCB_0G7
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cJ1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel. Int.
100%-
Fn 2
222,0003
DiCB-2
4o 1.84e4
13.07-17.79
0%-
Rel. Int.
100%-
Fn 2
223.9974
DiCB-2
4o 2.01 e4
13.07-17.79
0%-
1 51e8 2 2le8 213e8
13.65 13.98 14.24

2,28e8
15.78
-T-'I'T t I I J I T I 1" |
13.5
15.0
15.5
i j > i i i | t i i
16.0
9.84e7
13.65
13.5

1 4Se8 1 39e8
13.97 14.24
14.0
14 5
15.0
1,50e8
15.78
—I—|—I—I—I	I—I—|—r-
15.5	16.0
i.88ea
16.79
4.10e8
16.54
2.55e8
17.06
1,22e9
18.79
2.6708
16.54
1.65efi
17.05

16.5
17.0
17,5
Abs, Int.
- 3 7068
-1.88e8
I | I I I"
17,5
I.OOeO
RT
Abs. Int.
-2.43e8
¦1,21 e8
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
234.0406
DiCB Std.
4 a 1.46e4
13,07-17.79
0%-
3.08e7
17,04
f t i i i i i i | »f
14.0
I 1 1 1 ' I 1
14.5
15.0
15.5
1 I 1 1 1 1 I ' 1 T ' I 1
16.0	16,5
17.0
17.5
Abs. Int.
-1,04e7
¦ 5.20e6
O.OOeO
RT
Rel. Int.
100%-
Fn 2
236,0376
OiCB Std,
4a 1,57e4
13.07-17.79
0%-
13.5
1.9567
17.04
i I i i i i I i	i"" i i	| i i i i |
14.0	14.5
15.0
15.5
16,0
I ! t | I—I—I—!—I—I I I | '
16.5
T
17,0
17.5
Abs. Int.
-6.52e6
¦3.26e6
-r— O.OOeO
RT
Rel, Int.
100%-
Fn 2
242.9856
QC Check
13.07-17.79'
0%-
13.5
14.0
1 I 1
14.5
T1-
15.0
I « I | I I t t | I
15.5
I | I I I I J *
16.0
» I 1 I f T
16.5
1 1 •
17.0
t j T H 1
17.5
Abs, Int.
-1.68e7
•8.39e6
-l—O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCB\resouives\P9464_6042_PC8_007utp_res, saved 05-Aug-2008 08:25 (EE)
AP UllraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 2439. 8060
Peak annotation: Areas, Cenlroids
PKD: 05-Aug-2003 08:25:25 Printed: OS-Aug-2008 08:32:27 Page 5 of 22
-------
AP Lab ID: P9464_6042_PCBJ)07
Instr: AutoSpec-Premier MM6
Sample ID; Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxl00_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16 EQ
Rel, Int.
100%-
Fn 2
255,9613
TrCB-2
4o 3.66e3
13.02-17.79
0%-
Rel. Int.
100%-
Fn 2
257.9584
TrCB-2
4O 4 54e3
13.02-17.79
0%-
13.5
• I ¦"
13.5
14.0
1 i7e?
14.64
14.5
' I T'
15.0
1 I '
15.5
I | 1
14.0
H5e7
14.64
14.5
15.0
15,5
9.66e7
5.44e7
16.99
1.80e7
16.79
9.4097
5.12e7
4,1987
5.26e7
16.99
1,7667
16,79
Abs. Int.
-1.70e7
•8.49e6
-O.OOeO
RT
Abs. Int.
-1.64e7
•8.22e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 2
268.0016
TrCB Std.
4a 3.85e4
13.02-17.79
0%-
1.50e6
13.62
*
'I' rlI r \ I 1 f I	"Irtp'i' r|h
13.5	14.0
1.42e7
14.62
14.5

i.i3es
17.25
15.0
15.5
16.0
16,5	17.0	17.5
Abs, Int.
-2 59e6
1.29e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
269.9986
TrCB Std.
4o3.80e4
1302-17.79
0% ''I f" i | ? 'f"f t i "i"? | ¦ i ¦ f' 		|iim |i ni|iiwp , -1 r ? ^ i—i i ifr i 'i i" i~i i r r,f '* i ¦ ti	|	i1"11! n	i	pi	r f r1)	i "*1 f i pi i
13.5	14.0	14.5	15.0	15.5	16.0
Abs. Int.
-2 35e6
¦1.18e6
¦I ""'i'""! iinii11 i | i|"|-I i r i'T c iTi ~[in)' O.OOeO
16.5	17.0	17.5	RT
Rel. Int.
100%
Fn 2
242.9856
QC Check
13.02-17.79
Results: P:\P9400_P9499\P9464_6042 PCB\nesources\P9464_6042_PCB_007 utp_res, saved 05-Aug-2008 08:25 (EE)
AP UltraTmce-Pm V3.993 User/System EE/EEC2-038 cc: 1038, 9095
| I I I I j
17.0
Abs, Int.
-1,68e7
8.39e6
I O.OOeO
RT
Peak annotation: Areas, Centwids
PKD: 0S-Aug-2008 08:25:25 Printed: 05-Aug-2008 08:32:28 Page 6 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expl: pcb0405_d1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16.EQ
Rel. Int.
100%
Fn 3
255,9613
TrCB-3
4cj 1,83e4
17.81-23.26
Rel. Int.
100%-
Fn 3
257,9584
TrCB-3
4g 1,41e4
17.81-23.26
Abs. Int.
-1.18e8
5.91 e7
O.OOeO
RT
5.74e8
5.6668
22.99
3.34e8
3.42e8
22.26
19.61
1,70e8
1.7760
19.36
1.52e8
18.90
9.17e7
o.47e7 7.68e7
21.47 21.77
20.14
2.5167
19.09
A
A . /v
5.61e8
5.53e8
22.99
3.2368
19.61
3 29e8
22.26
1,84e8
19.36
1,7168
18.90
1,48e8
20.14
8.92e7
B,15e7 7.36e7
21.47 21.77
2.48e7
1B.49
Abs. Int.
-I.16e8
5 81e7
OOeO
Rel. Int.
100%
Fri 3
268,0016
TrCB Std.
4o 3.91 e4
17,81-23,26 i
0%-
I ' J1 " I 1
18.0
-i	1	r-
19.0
2.62e7
19,58
™!		 f	I
20,0
1.10e6
20.93
i <-*1
21.0
!¦ p ' 1	" I' I
22.0
2.41e7
22.97
*T—	T"
23,0
Abs. Int.
-6.27e6
-3.13e6
O.OOeO
RT
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std.
4o 2.21e4
17.81-23.26
0%-
18.0
—i—i—i—r-
1—""
19.0
-i—i—f—t r '¦ f -
200
21.0
r	1	1	1	1	1 	H
22.0
2.2587
22,97
Abs, Int.
-5.82e6
•2 91e6
!	*	O.OOeO
23.0	RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Abs. Int.
-1.90e7
9 48e6
O.OOeO
RT
Results: P:\P9400^P9499\P9464^6042 PCB^$SOurces\P9464_6042_PC8_007 utp_re$, saved 0S~Aug~2008 08:25 (EE)
AP UttmTrace-Pro V3.993 User/System: EE/EEC2-03B cc: 7882, 6479
Peak annotation: Areas, Centroids
PKD: OS-Aug-2008 08:25 25 Printed: OS-Aug-2008 08:32:29 Page 7 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405. cl1-10_mm6 GC: pcbx100„a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel, Int.
100%-
Fn 2
289-9224
TeCB-2
40 3.14e3
13.02-17.79
0%-

13.5
14.0
14.5
*i"T	| iTt-i | ffi i	|
15.0
15.5
16.0
16.5
17.0
2.97e5
17.36
2.19eB
17.3f
4.96e4
16.80
17.5
Abs. Int.
-9.18e4
4.59e4
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
291.9194
TeCB-2
4o 2.43e3
13.02-17.79
0%-
13.5
14,0
wiini!!! w| ) m iit| '|" j	|	i
14.5
15.0
15,5
16.0
2.61 e4
16,79
16.5
Abs. Int.
-1.14e5
•5.72e4
¦O.OOeO
RT
Rel. Int.
100%-
Fn 2
301.9626
TeCBStd.
4o 5 63e3
13.02-17.79 -
0%-
| i i—i—l—[ill—i—|—i—i i i—|—r-
13.5	14.0
I"' "' ¦ 1 | i ' » ¦ |
14.5
15.0
15.5
16.0
T
¦ I 1 1
16.5
—r~]—r-t—r
17.0
1.3Be7
7.33
Abs. Int.
-1.93e6
9.63e5
, i , i i , O.OOeO
17.5	RT
Rel. Int.
100%
Fn 2
303.9597
TeCB Std.
4o 3.28e3
13.02-17.79
0%-
III I | 4 I f I | I
13.5
' * I ¦
14.0
	'	I '' '
14.5
i	j	f	i—i—i—]—r-i—i—r—|—i i i—i—p
15.0	15.5
16.0
| V I I 1 | T f t I |
16.5
17.0
1.74e7
17.33
17.5
Abs. Int.
-2.35e6
1.17e6
-r— O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856
QC Check
13.02-17.79
0%-
13.5
14.0
14,5
15.0
15.5
' I 1
16.0
¦ I '
16.5
17.0
Abs. Int.
-1.68e7
-8.39e6
I i i i—r-|—i—i—f—i—O.OOeO
17.5	RT
Results: P\P9400_P9499\P9464 6042 PCBVesources\P9464_6042_PCB_007 utp_res. saved OS-Aug-2008 08:25 (EE}
AP UltraTrace-Pm V3.993 User/System: EEMEC2-038 cc: 3237, 4410
Peak annotation: Areas. Centralis
PKD: 05-Aug-2008 08:25:25 Printed: 05-Aug-2008 08:32:31 Page 8 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405._cl1 -10_mm6 GC: pcbx100..a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16 EQ
Rel, Int.
100%-
Fn 3
289.9224
TeCB-3
40 2.45e3
17.81-23,26
Q%-
1—I—1
18.0
1,40e7
19.12

5.88e6
19,94
1.19eB
22.00
19.0
->=*r
20.0
21.0
I.4le8
6.96e7
21.57
4.44e7
2.66e7
22.26
21.80
1.23e7
21.35
22.0
6.55e7
22 84 4_6ie7
2,41ef\ 23.04
22.74
23.0
Abs. Int.
-3.05e7
¦1.53e7
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
291.9194
TeCB-3
4o 2.74e3
17.81-23.26
0%-
18.0
1.79e7
19.12
19.0
2 31e7
10.69 7 5,e6
/v 19.94
1		 i>—f="|—i
20.0
1.8268
1.55ei
22.00
9.01e7
21,57
5.73e7
3.4987
21,80
1.59e7
21,35
5.50e7
22;84 567e7
23.04
Abs. Int.
-3.94e7
-1.97e7
21.0
22.0
23,0
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
301.9626
TeCBStd.
4o 4.80e3
17.81-23,26
0%-
18.0
19.0
20.0
21.0
22,0
23.0
Abs. Int.
-3.17e6
• 1.58e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
303.9597
TeCBStd,
4cr4,34e3
17,81-23,26
0%-
1—I—1
18.0
19.0
-i	1	r-
20.0
21.0
22.0
I i »
23.0
Abs. Int.
-4.1 Qe6
•2.05e6
-O.OOeO
RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
18.0
Results: P:\P9400_P9499\P9464_6042 PCB\m$oun;es\P9464_e042_PCB_007.utp_ms saved 05-Aug-2008 08:25 (EE)
AP UltmTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 7271, 4564
Abs. Int.
1.90e7
9,48e6
O.OOeO
RT
Peak annotation: Areas, Centroids
PKD: Q5-Aug-20Q8 08:25:25 Printed: OS-Aug-2008 08:32:32 Page 9 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_c!1 -10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16JEQ
Rel. Int.
100%-
Fn 4
289.9224
TeCB-4
4o 1.70e4
23-27-33.00
0%-
, 9.08e7
2.56e75x°B«7 24.69
24 00 24 35
-ft
24.0


25.0
3.1Be8
26.00
&83e7 /l.OBeS
125.60 I fee. 19
2.94e7
27.14
26.0
27.0
22?|l8 12f2fljf|
J\ |TA, i a
n
29,0
| i i i i | i—r-
30,0
31.0
32.0
Abs. Int.
-1.58e8
•7.91e7
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
291.9194
TeCB-4
4o2.19e4
23.27-33.00
0%'
3 32e77^e7 2476e9B
23.99
24.0
£**.33 A
TV,

I'' ¦ ' '"I
25.0
4.08e8
26.00
V13e8 JOSeS
/25.59 / 126.16
ik , y.vN.,
9J7e8
29.10
2578!i8 2.26e8 2.04e8
27.81 28.27 28.M
,A,.A,,A,
26.0
27.0
28.0
290
30,0
31.0
32,0
Abs. Int.
-2.04e8
1.02e8
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
301.9626
TeCB Std.
4o 1.48e4
23.27-33.00
0%-
24.0
2.58e7
2,45e7 29.09
28.62
25.0
26.0
i Y*1 t i T* | r
27.0

—j—i—i ii (I i	j i r""l i j
28.0	29.0
30.0
I 1 ' 1 ' I 1 ' ' '"I
31.0
-nr-
32.0
Abs. Int.
-5.21e6
•2.60e6
I ¦! fi i O.OOeO
RT
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
4o 7.54e3
23.27-33.00
0%-
24.0
25,0
3.18e7
3 Q5e7 29.09
28.62
A
' I I1 I 1 I I
26.0
27.0
28.0
29.0
¦ i ¦
30.0
31,0
1 r ¦
32,0
Abs. Int.
-6,24e6
•3.12e6
¦O.OOeO
RT
Rel. Int.
100%
Fn 4
330,9792
QC Check
23,27-33.00
Results: P:\P9400_P9499'P9464_6042 PCBVesources\P9464_§042_PCB_007Mtp_res, saved 0S-Aug-2008 08:25 (EE)
AP UtlraTrace-Pro V3.993 User/System: EE&EC2-038 cc: 7291. 5460
Abs, (nt,
-2 85e7
1,42e7
O.OOeO
RT
Peek annotation: Areas, Centroids
PKD: 0S-Aug-2008 08 25 25 Printed: 05-Aug-20Q8 08 32:33 Page 10 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbxl 00_a Vial; 65
Acq: 24-JuI-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel. Int.
100%-
Fn 3
323-8834
PeCB-3
4 cj 4.28e3
17.81-23.26
0%-
i—|—.
18.0
19.0
	!' 	i—"J—i	1 r ""'"P
20.0
-i—i—(—i
21.0
2.84e8
22.26
5.03e5
21.96

22.0
Abs. Int.
-5.25e5
•2.62e5
i	1 <*' O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 3
325.8804
PeCB-3
4o 5.51e3
17.81-23.26
20.0
21.0
22.0
0% i1 		
18.0
-|	r-
8.24e5
21.96
1	1	—f-
19.0
""I 	i	i i i
"i	i"" i	"i
4.iie6

22.26
ft


3.50e5
/ \
22.68
J V .

Abs. Int.
-8.5085
•4.25e5
i—,—i—f^-O.OOeQ
23.0 RT
Rel. Int.
100%-
Fn 3
337.9207
PeCB Std.
4o2,90e3
17 81-23 26
0%-
1—I—1
18.0
19.0
20,0
21.0
—r
23.0
Abs. Int.
-4.45e6
¦2.2386
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
339.9177
PeCBStd.
4a 4.29e3
17.81-23.26
0%-
-1	"I	1	I
18.0
IJ(!I!J!II(JII(!J
19 0	20.0
« 1 I
21.0
22.0
23.0
Abs. Int.
r2.71e6
¦1.36e6
¦O.OOeO
RT
Rel. Int.
100%-
Fn 3
292.9824
QC Check
17.81-23.26"
0%-
—r~
18.0
I I 1
19.0
20.0
21.0
22.0
23.0
Abs. Int.
-1.90e7
•9,48e6
¦O.OOeO
RT
Results: P:\P9400_P9499SP9464_6042 PCBSre$oun;e$\P9464_6042_PCB_Q07Mtp_res. saved 05-Aug-200S 08:25 (EE)
AP UttraTrace-Pro V3.993 User/System EE/EEC2-038 cc 7324, 6056
Peak annotation: Areas, Centmkts
PKO: 05~Aug~2008 08:25:25 Printed: Q5-Aug-2Q08 08:32:34 Page 11 of 22
-------
AP Lab ID: P9464_6042_PCB_Q07
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-JuI-2008 14:32:30
User: JU Datafile: 080724V16_EQ
Rel. Int.
100%
Fn 4
323.8834
PeCB-4
4o 1.16e4
23.27-34.14
3 38eS
3.26e8
2.65e8
32,02
2.27e8
26.92
IBOea
27.80
1.42e8
24.45
6.636 7 6_S2_e7
6.32e7
31.33
5.11e7
30.48
3.59e7 I | 2.97
26 42 I I 27
4.21e7
33.27
A
j 28.81
1 11p73'ee7
24.77 2^\
1.34e7
29.53
26.0
Abs. Int.
-6.90e7
3.45e7
O.OOeO
28.0
34.0 RT
Rel. Int.
100%
Fn 4
325.8804
PeCB-4
4a 7.24e3
23.27-34,14
5.S0e8
31.05
5,30e8
28.54
4-2fle8
32.02
3.85e8
2.73e8
27.80
2.28e8
24.45
1,Q7eo
1,04e8
8.36e7
30.48
6.9367
33.27
A
5.87e7
31,33
a rfl„7 5.15©f
1.5267 ocis
24.76 /j/\
3.16e7
29.53
26.42
Abs. Int.
•1.12e8
5,58e7
O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
337.9207
PeCBStd.
4a 8.00e3
23.27-34.14
0%-
i i	r~
24.0
2.49e7
26.90
3.43e7
29.12
'I | I I *
26.0
28.0
—4
, 2.9S©7
2.80e7 3i 47
30.75
30.0
| " 1	1 1	r-
32.0
Abs, Int.
-6.47e6
¦3,24e6
¦ , I • O.OOeO
34 0 RT
Rel. Int.
100%-
Fn 4
339.9177
PeCBStd.
4a 8.94e3
23.27-34.14
0%-
1.59e7
26.90
2.14e?
29.12
7.08 ;5
29.01
24.0
I—1
26.0
1.81e7 Vi^r
30 75 31-4?
A
lis
28.0
30.0
Abs. Int.
-4,30e6
•2.15e6
¦O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
24.0
26.0
28.0
30.0
Abs. Int.
-2.85e7
1,42e7
1—1—1—1 i j—¦- 0. OOeO
34.0 RT
Results: P.\P9400_P9499V>9464_6042 PCB^resourcos\P9464_e042_PCB_007 utp_r»s, saved 05-Aug-2C08 08:25 (EE)
AP UltraTrace-Pro V3 993 User/System: EE/EEC2-038 cc: 9949, 5402
Peak annotation: Areas. Centmids
PKD: 05-Aug-2008 08 25 25 Printed: 05-Aug-2008 08:32:35 Page 12 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial; 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel, Int.
100%-
Fn 5
323.8834
PeCB-5
4o 7.92e4
34.16-41.15
0%-
4.07e8
34.60
i i 1 —i—r
35.0
2.96e7
36.91
,
36.0
37.0
3,02eo
38.17
9.E6e6
1.38e7
39.29
1 33e7
40.08
38.0
39.0
40,0
Abs. Int.
-7.91e7
¦3.96e7
i—— O.OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
325,8804
PeCB-5
4c1.32eS
34.16-41,15
0%-
6.57e8
34.60
35.0
I 1
36.0
6.94e7
36.91
_-4V-
37.0
38.0
I '
39.0
3.27e7
39.20
—i	i—I—(—r-
40.0
Abs, Int.
-1,40e8
•6.98e7
•O.OOeO
41.0 RT
Rel. Int.
3.51e7
100%-]
34.58
*
Fn 5
A
337.9207 •

PeCB Std. "

4o 2,08e4 .

34.16-41,15 ;

0%-
, , . I .V.
35.0
| r
36.0
Abs. Int.
-7.02e6
¦3.51e6
37.0
38.0
39.0
i i i—i—j—i—i—i—i—i m i 0.0060
40.0	41.0 RT
Rel. Int.
100%-
Fn 5
339.9177
PeCB Std.
4c2 77e4
34 16-41 15
0%-
2.26e7
34,58
35.0
36.0
37.0
38.0
' I 1
39.0
	>	i r i
40.0
Abs. Int.
-4.44e6
•2.22e6
~i~* O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15
0%-
35.0
36.0
37.0
' I "
38.0
1 ' i 1
39.0
40,0
Abs, Int.
-1 36e7
•6.79e6
41.0
¦O.OOeO
RT
Results: P:\P9400_P9499\PS464_6042 PCB\nesoumm\P9464_6042_PCB_0a7.utp_ms, saved OS-Aug-2008 08 25 (EE)
AP UUraTraca-Pro V3 993 User/System: EE/EEC2-03B cc 3297. 8516
Peak annotation: Areas, Centroids
PKD: OS-Aug-2008 08:25:25 Printed: 05-Aug-2008 08:32:3? Page 13 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: D80724V16 EQ
Rel. Int.
100%-
Fn 4
359.8415
HxCB-4
4a3 90e3
23.27-34.14
0%-
24.0
26.0
3.7Se7
27.32
-A-


2.39e8
1.75e8
30.09
«	9.69e7
6 82e7 i	31.13 5.38e7
29.33 1.55e7|4|0e7	2LI 4eJ A 1,06e7 32.08
29.79	30,77 \ 31 55 A
28.0
30.0
32.0
13J? 3.06e7
1;1%8 Abs. Int.
33 65 r7.44e7
¦3,72e7
-O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4a 2.97e3
23,27-34.14
Q%-
r-Ti—'
24.0
¦"i	r	r	
2.98e7
27.32
-A-
1.40e8
30f	7.7367
S 44®7 l\	31.13
29 33 1.24e7 |08e7	1.45e7 A 8 72e6
29.79 Ao,27	30.75 \ 31 55
/V

4.33e7
32,08
3.43e8
33.65
26.0
28.0
30.0
1.90e8
32.80
2.43e?
32.0
Abs. Int.
-5,99e7
-2.99e7
34.0
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
371.8817
HxCB Std.
4a6.11e3
23.27-34.14
0%-
1 '
24,0
i—i—i i
2,62e7
26.0
28.0
30.0
32.0
2.00e7
33,62
Abs. Int.
-4.84e6
¦2.42e6
i—j-"-O.OOeO
34.0 RT
Rel. Int.
100%-
Fn4
373.8788
HxCB Std.
4a 7 05e3
23.27-34.14
0%-
24.0
2.09e7
26.69
i-4
26.0
28.0
I	f '1
30,0
32.0
Abs. Int.
i.59e7 r3,61e6
33.62
¦ 1,80e6
V. ' O.OOeO
~T
34.0 RT
Rel. Int.
100%-
Fn 4
330.9792
QC Check
23.27*34.14'
Abs. Int.
2.85e7
1 42e7
O.OOeO
34.0 RT
Results: P:\P94Q0_P9499W9464_6042 PCB\resources\P9464_6Q42_PCB_0D7 utp_res. saved 0S-Aug-2008 08:25 (EE!
AP Ultra! race-Pm ¥3.993 User/System: EE/EEC2-038 cc: 5121, 2008
Peak annotation: Areas, Centroids
PKD: 05-Aug-2Q08 08:25:25 Printed: 05-Aug-2008 08:32:38 Page 14 of 22
-------
I
AP Lab ID; P9464_6042_PCB_0Q7
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC; pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V1 S_EQ
Rel. int.
100%-
Fn 5
359.8415
HxCB-5
4o 4.54e4
34.16-41,15
0%-
9.4267
34.69
35.0
8.55e7
518e7 36.15
2 47e7 35 75
35.51 A
. / V
OQ. 1SJ
		
3.3468
37.10
1.Q4eB
39.79
1	pS	1 ' |
36.0
37.0
38.0
39.0
40.0
Abs. Int.
-5,64e7
-2.82e7
O.OOeO
I			 I
41.0 RT
Rel. Int.
100%-
Fri 5
361.8385
HxCB-5
4o 2.68e4
34.16-41,15
0%-
7.55e7
34.69
A-
35.0
6.72e7
4.16e7 36.15
1.99e7 35.75 A
35.51 A j \
I'—r-4—I J i
2.68e8
37.10
36.0
8.2987
39.79
37.0
I 1 1 1 *~l 1
38,0
39.0
40.0
Abs. Int.
-4,53e7
¦2.27e7
¦ O.OOeO
~41~0 RT
Rel. Int.
100%-
Fn 5
371.8817
HxCBStd.
40 2.06e4
34.16-41.15
0%-
' I '
35.0
5.46e7
37.09
i ['< i f 1 | tti ir| 1 r-i > [ > t
36.0
37.0
¦* T 		 I
38.0
"I	|	1		1""
39.0
40,0
Abs. Int.
r8.59e6
•4.29e6
-O.OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
373,8788
HxCB Std.
4a 2.16e4
34.16-41.15
0%-
35.0
36.0
37.0
38.0
39.0
| * I { f
40.0
Abs. Int.
-7.19e6
3.60e6
¦O.OOeO
41.0 RT
Rel, Int.
100%
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
35.0
36.0
t—J—r
37.0
38.0
39.0
40.0
41.0
Abs. Int.
r-1.36e?
-6.79e6
•O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PCBVesourZ0S\P9464 S042_PCB_007.utp ms: saved 05-Aug-2008 08:25 (EE)
AP UltmTmce-Pm V3.993 User/System: EEMEC2-038 cc: 2722. 9750
Peak annotation: Areas, Centmids
PKD: 05-Aug-2QQ8 08:25:25 Printed: 05-Aug-2008 08 32:39 Page 15 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cI1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel. Int.
100%
Fn 4
393.8025
HpCB-4
4a2 68e3
30.00-34.14
Rel. Int.
100%
Fn 4
395.7995
HpCB-4
4o 1.94e3
30.00-34.14
Abs. Int.
-3.41e6
1.7le6
OOeO
1.7Qe7
31.75
1.1767
32.48
2.9666
1,30e6 32.19
31.93
2.46e6
1.44e6
32.87
31.46
30,5	31.0
34.0 RT
1.60e7
31.75
1.1907
32.48
3,01e6 2.91e6
31,93 32.19
2.74e6
31.46
1.30e6
32.87
-»—i—i—i—f
31,0
-i—pr
31,5
Abs. Int.
3.17e6
1.58e6
OOeO
Rel. Int.
100%-
Fn 4
405.8428
HpCBStd.
4a 6,41 e3
30,00-34.14
0%-
30,5
31,0
2.38e7
31.45
32.0	32,5
' I	¦
33.0
33,5
1,38e7
33.99
Abs. Int.
-4,92e6
• 2.46e6
¦O.OOeO
RT
Rel, Int.
100%-
Fn 4
407.8390
HpCBStd.
4a 6.02e3
30.00-34.14
0%-
30.5
2.41e7
31.45
{11)1
31.0
31.5
32.0
	!—I I I | I I I I | I I f T | I 1 ' 0 -OOeO
32.5
33.0
33.5
1.6067
Abs. Int.
-4.83e6
¦2.41 e6
34.0 RT
Rel. Int.
100%-
Fn 4
330.9792
QC Check
30.00-34.14
Abs. Int.
-2.85e7
-1,42e7
0%-
- O.OOeO
RT
30.5
31.0
1 1 1 I '
31,5
32.0
32.5
33.0
33.5
34.0
Results: P:\P9400_P9499\P9464_6042 PCS Ire S0urces\P9464_6042_PCB_007 utp_res. saved 05-Aug-2008 08:25 (EE)
AP UttraTrace-Pro V3.993 User/System: EE/EEC2-Q38 cc; 9799, 6919
Peak annotation: Areas, Cenfroids
PKD: 0$-Aug-2008 08:25:25 Printed: 0S-Aug-2008 08:32 40 Page 16 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel, Int.
100%-
Fn 5
393.8025
HpCB-5
4o 1.98e4
34,16-41.15
0%-
3 93e7
34.7?
1,94e7
35.27
9.72e6
34.54
3.49e7
2 34e7	36 36
35.84	,
4.92e6f
36.17/
A
35.0
| f r* I I |
36.0
» | i i i i | r i
37,0
1,08e8
38.24
3.08e7
2.7367
38,54
5.03e6
37.95
5.00e7
39.73
107e8
39 87
38.0
39.0
40.0
Abs, Int.
-1.83e7
9.17e6
-O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
395,7995
HpCB-5
4o 2,29e4
34,16-41.15
0%-
3.80e7
34.77
J.79e6 i u nK-R
+iA SZA / R.Jaeo
/ %4J3
¦4V
1,89e7
35.27
35.0
2.28e7
35.84
3.35e7
36.35
4.80e6
36.17
—
1.04e8
38.24
36.0
37.0
2.99e7
2,66e7
38.54
5,i7ee
37.95
4.81e7
39,73
38.0
39,0
7.23e7
39.30
2156e6
30.85
40.0
Abs. Int.
-1.78e7
•8.90e6
•O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
405,8428
HpCB-5 Std.
4o 1,93e4
34,16-41,15
0%-
I ' 1 1 ' I ' • 1 1 l'
35.0	36,0
-i—j—i—i—i i |—i—i—i—i | r 'i'1 tH' "|—i—i—i i | i 1 i i > |—i—i" "i" 'i	|	i	i	i	'—|—i—r—i—i ¦ f f
Abs. Int.
-4.42e6
•2.21e6
• O.OOeO
37.0
38.0
39.0
40.0
41.0 RT
Rel. Int.
100%-
Fn 5
407.8398
HpCB-5 Std.
4o 1.76e4
34.16-41.15
0%-
35.0
l—|
36.0
« I I I I i | I
37.0
2.0867
38.23
—r1—i—i »v f
38.0
. ! • • •
39.0
-r—|—r—
40.0
Abs. Int.
r4.11e6
•2.06e6
i ( ¦< i i i ¦ f O.OOeO
41,0 RT
Rel. Int.
100%-
Fri 5
454.9728
QC Check
34,16-41.15
0%-
35.0
36.0
37.0
38.0
I ' 1
i i i i i
T
39,0
-i—i—i—r—i—i—i—i—r-
T
40.0
Abs. Int.
-1.36e7
¦6.79e6
j » 0 .OOeO
410 RT
Results: P:\P9400_P9499\P9464_6042 PCB\m$OUKes\P9464_6042_PCB_007.utp_m$. Saved OS-Aug-2008 08:25 (EE)
AP UltraTrace-Prv V3.993 User/System: EE/EEC2-038 cc 2582. 7527
Peak annotation: Amas, Centmists
PKD: 05-Aug-2008 08:25:25 Printed: 05-Aug-200B OS:32 41 Page 17 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl 1-10_mm6 GC: pcbx100_a Viaf: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16 EQ
Ret. Int.
8.83e7
100%-
41.68
A
Fn 6
A
393.8025

HpCB-6 :

4o 1.11e4 .

41.17-46.41 ;
/ \
0%-
	i \
42.0
2.34e6
42.46
'T
43.0
44.0
45.0
-l	1	r-
46.0
Abs. int.
-1.71e7
•8.57e6
¦O.OOeO
RT
Rel. Int.
100%-j
8.47e7
41.88
A
Fn 6 :
395.7995 ¦
HpCB-6 J
4o 9.87e3
41.17-46.41
ft
0%-

42.0
2 22e6
42.47
——r-
43.0
-1—r
i	1	,	r-
44.0
| i i i i | i	1	r~
45.0
46.0
Abs. Int.
-1,66e7
•8.29e6
¦O.OOeO
RT
Rel. Int.
100%-j
2.79e7
41.86





Abs. Int.
-5.62e6
Fn 6 :
405.8428
HpCBStd. J
4o4 31e4
41.17-46.41 ;
. A





-2.81e6
0%-

m|	<	i	'	>	>	<	i	-T"		
	r—"f—l	



-O.OOeO
42.0
43.0
44.0
45,0
46.0
RT
Rel. Int.
100%-n

2-60e7
41.86
A
Fn 6
407.8398 •
HpCBStd, '
4a 4.07e4 .
41.17-46.41 ¦

I
0%-
T..J. ,|

42.0
=1—'—r-
43.Q
'¦"I 	r i—i i ^
44.0
1 1—
45.0
46.0
Abs. Int.
-5.13e6
•2.57e6
RT
Rei. int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41
0%-
42.0
43.0
44.0
45.0
¦—I—
46.0
Abs. Int.
-1,12e?
•5.60e6
•O.OOeO
RT
Results: P:)P9400_P9499\P9464_6042 PC8Vvsoumes\P9464_6042_PCB_007.Utp_res, saved 05-Aug-2008 08:25 (EE)
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 8613, 1259
Peak annotation: Areas, Cenlmids
PKD. 05-Aug-2008 08:25:25 Printed: 05-Aug-200S 08:32:43 Page 18 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16 EQ
Rel Int.
100%-
Fn 5
427.7635
OcCB-5
4o 6.33e3
34.16-41.15
0%-
35.0
6.26e6
35.94
A
36.0
9.47e6
36.70
37.0

3.17e7


39.87
2.21 e?

A

h
40.41
A
8M&S

A A
37.54


1 96e6 rA
/
n
37.26 /; \
/ \
/ V \
r> I \ \ 	
	/. .v.,
, ,/, i A
38.0
39.0
40.0
Abs. Int.
-5.61e6
•2.80e6
.-L0.00e0
41.0 RT
Rei. Int.
100%-
Fn 5
429.7606
OcCB-5
4a 7.14e3
34.16-41.15
0%-
I I | 1
35.0
7.31e6
35.94
.A.
36.0
I.l0e7
36.70
1.04e7
37.54
2.22e6
37.26
-r—|—i tO ¦
3.57e7
39.86
37.0
38.0
I I j I I
39.0
[ii
) I" i i
40.0
2.5367
40.41
Abs. Int.
-6.34e6
•3.17e6
O.OOeO
' t I | I
41.0 RT
Rel. Int.
2.33e7
100%-,
35.92
*
Fn 5 !
A
439.8038 ¦

OcCB Std. -

40 5 57e3 .

34.16-41.15 ¦

Q%-
	\
35.0
36.0
37.0
"1	i	i	i	i	|	i	r	r	r	|	t	i	i "M|—»	t	r
38.0	39.0
5,65e5
40.40
40.0
Abs. Int.
-4.58e6
•2.29e6
-O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
441.8008
OcCBStd.
4o 1,43e4
34.16-41.15
0%-
35.0
I | >11
36,0
37.0
38.0
39,0
5,78e5
40.40
> > y i i i —i" | i
40.0
Abs. Int.
-4.84e6
•2.42e6
O.OOeO
I | 1
41.0 RT
Rel. Int.
100%
Fn 5
454.9728
QC Check
34.16-41.15
38.0
Abs. Int.
1,36e7
6.79e6
O.OOeO
RT
Results: P:\P9400_P9499V9464_6042 PCB\resoumes\P9464_6042_PCB_OO7Mtp_m$, saved OS-Aug-2008 08:25 (EE)
AP UltraTrace-Pm V3 993 User/System: EE/EEC2-038 cc: 7722. 6383
39.0	40.0
PKD: o^Aug-2008 08:25:25 Printed: OS-Aug-2008 08:32:44 Page 19 of 22
41.0
Peak annotation: Areas, Cenlroids
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16_EQ
Rel. Int.
100%-
Fn 6
427.7635
OcCB-6
4 o 1.10e4
41.17-46.41
0%-



3.20e7
43.62

I,64e7
41.88
A


i
2.33e7
44.01
l\

. 		
42.0
, . , i i I i i
43.0
¦ i i i " •
44.0
1 1	1 I
45.0
1 43e6
45.44
Abs. Int.
-6.28e6
•3.14e6
i i—| " i	'i—i—f— 0 .GOeO
46.0	RT
Rel. Int.

3.48e7
100%-,

43,62
A
Fn 6 ;

A
429,7606 ¦
1,80e7

OcCB-6 J
41.68

4o 9.81 e3 ~
A

41.17-46,41 ¦
A
\
0%-

J V
42.0
43.0
2-39e7
44.00
i.BQee
48.10
44.0
45.0
1.46e6
45.44
—^ 1—
Abs. Int.
-6.89e6
¦ 3.44e6
i i i | i i i 0. OOeO
46.0	RT
Rel. Int.
100%-
Fn 6
439.8038
OcCBStd,
4o 1.51e4
41.17-46.41
0%-
42.0
i	I.8le7
1.62e7	43 gg
43.60
43.0
I1 f 1 I " V
45.0
2.00e5
45.43
~i—rfr- [—i	1	1	1	|	r-
46,0
Abs. Int.
-3.39e6
¦1.70e6
—J-O.OOeO
RT
Rel. Int.
100%-
Fn 6
441.8008
OcCBStd.
4o 1,56e4
41,17-46.41
0%-
42.0
i „ , 2.00e7
1.82e7	43.99
43.60
43.0
45.0
"¦—r
Abs. Int.
-3.91 e6
¦1.95e6
i i i—i—t- O.OOeO
46.0	RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41.17-46.41'
0%-
42.0
43,0
44.0
45.0
Results: P:\P9400_P9499\P9464_6042 PCB\resource$\P9464_6042_PCB_QQ7.utp_m$, saved OS-Aug-lOOB 08:25 (EE)
AP UltraTrace-Pm V3.993 User/System: EEMEC2-03S cc: 2433, 4810
46,0
Abs. Int.
-I.12e7
•5.60e6
¦O.OOeO
RT
Peak annotation: Areas, Centmids
PKD: 05-Aug-200S 08:25:25 Printed: 0S-Aug-2008 08:32:45 Page 20 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16 EQ
Ret. Int.
100%-
Fri 6
461.7245
NoCB
4a 4 56e3
41.17-46.41
0%-
2.39e7
45.44
42.0
43.0
I I |
44.0
45.0
46.0
Abs. Int.
-4.80e6
•2 40e6
•O.OOeO
RT
Rel. Int.
100%-
Fn 6
463,7216
NoCB
40 6.44e3
41.17-46,41
0%-
42,0
I I I | I
43.0
-i	1	1	r-
2.98e7
45.44
Abs. Int.
-6.19e6
•3.09e6
44.0
-i—|—i—i—i*i	i i—i—|—i—i—i—f-0.OOeO
45.0	46,0	RT
Rel. Int.
100%-
Fn 6
473.7648
NoCB Std.
4a 1 31e4
41.17-46.41
0%-
1.59e7
41.45
42.0
43.0
I ¦[ !¦ ' I ' I ¦ I | ¦ T*
44,0
1.08e7
45.42
i	r—p—p—ir i pi
45.0
'—I—
46.0
Abs. Int.
-3.46e6
•1 73e6
•O.OOeO
RT
Rei. int.
100%-
Fn 6
475.7619
NoCB Std,
4o6,32e3
41.17-46.41
0%-
2.00e7
41.45
42.0
43,0
44.0
I I I |
45.0
1.45e7
45.42
46.0
Abs, Int.
-4.34e6
¦2,17e6
¦O.OOeO
RT
Rel, Int.
100%-
Fn 6
404,9760
QC Check
41.17-46.41"
0%-
42,0
'-T—1
43.0
44.0
45.0
46.0
Results: P:\P9400_P9499\P9464_6Q42 PCBSmsotimes\P9464_6042_PCB__007.utp_ms, saved OS-Aug-2008 OB 25 (EE)
AP UltmTrace-Pm V3.993 User/System: EE/E£C2-03B ce: 2319, 1338
Abs. Int.
-1.12e7
5.60e6
+-0,00e0
RT
Peak annotation: Areas, Cent/aids
PKD: OS-Aug-2008 08:25:25 Printed: 05-Aug-2008 OB:32:46 Page 21 of 22
-------
AP Lab ID: P9464_6042_PCB_007
Instr: AutoSpec-Premier MM6
Sample ID: Run# II-ACD-M23-3
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 65
Acq: 24-Jul-2008 14:32:30
User: JLJ Datafile: 080724V16 EQ
Rel. Int.
100%-
Fn 7
497.6826
DeCB
4o 3.47e3
46.42-54.01
0%-
*f f * I I I I I
47.0
I I 1 I
48.0
I I | I I 1 I J f I I I | I ! I I | I I I I
49,0	50,0
I I | I I	1 I
51,0
! I I T I I
52.0
53.0
Abs. Int.
-4.76ei
•2.38e6
•O.OOeO
54,0 RT
Rel. Int.
100%-
Fn 7
499.6797
DeCB
40 3.87e3
46.42-54.01
0%-
47.0
48,0
49.0
50,0
51,0
'"T	|	1	T	
52.0
I ' ' ' ' I 1
53.0
Abs. Int.
-4.05e6
-2.03e€
¦O.OOeO
54.0 RT
Rel. Int.
100%-
Fn 7
509.7229
DeCB Std.
4o3.93e3
46.42-54.01
0%-
1.92e7
46.74
/ V
47.0
6.83e5
50.56
48.0
49,0
50.0
51.0
52.0
53.0
Abs. Int.
-3.80e6
t-1,90e6
•O.OOeO
54.0 RT
Rel, Int.
100%-
Fn 7
511.7199
DeCB Std.
4o 5.06e3
46.42-54.01
0%-
1 i | i i r i |
47.0
5.34e5
50.58
48.0
-r~r
49.0
50.0
51.0
52.0
—i—r—[—i—i—i—i—|—r—i—i—i—p
53.0
Abs, Int.
-3.28e6
1,64e6
•O.OOeO
54.0 RT
Rel. Int.
100%
Fn 7
454.9728
GC Check
46,42-54.01
Abs. Int.
-1.25e7
6.24e6
O.OOeO
54.0 RT
Results: P-\P940O_P9499\P9«64_6O42 PC8\resources\P94M_W42_PCB_007Mtp_re$, saved OS-Aug-2008 08:25 (EE)
AP UttraTmce-Pm 1/3 993 User/System: EE/EEC2-038 cc: 5124, 3869
Peak annotation: Areas, Cant/aids
PKD: 0S-Aug-2008 08:25:25 Printed: OS-Aug-2008 08:32:47 Page 22 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxIOO a Vial: 2
Acq: 24-Ju 1-2008 15:30:01
User: JLJ Datafiie: 080724V17_EQ
Fn 1
Rel, Int.
100%.
218.9856
QC (non-EQ)
9.03-13.00
0%.
¦ I '
9.5
1 1 1
10.0
10.5
11.0
11.5
T-r
12.0
1 I '
12.5
Abs Int.
-7.80e7
. 3 9Qe7
¦ O.OOeO
13.0 RT
Fn 2
Rel. Int.
100%.
242.9856
QC (non-EQ)
13.02-17.79
0%.
—|—i—i—i—i | i—i—i—i—|—i—i t .—|—i—i—i i |—r—r—i—i—|—r—i—r i |
13.5	14.0	14.5
' I 1
15.0
t—|—i—r-i—i | i—r-i—i | i—r—i—i—|—i—I—i—i—]—i i i—i—p
15.5	16.0	16.5
-i—j—<—i—i—r-]—i—i—r-i—|—r-
17.0	17,5
Abs. Int.
-4.45e?
•2.23e7
-O.OOeO
RT
Fn 3
Rel. Int.
100%-
292.9824
QC (non-EQ) :
17.81-23.26 :
0%-
18.0
"¦¦r	i	t	T"
19.0
—j—
22.0
23.0
Abs. Int.
-4.43e7
-2.2le7
-O.OOeO
RT
Rei. Int.
Fn 4 100%-
330.9792
QC (non-EQ)
23.27-34.14
0%-
-r"—i	[	1 t i
24.0
—I—
28.0
28.0
i * i i
30.0
32.0
~i	1 |—'—i—
~r
Abs. Int.
-4.32e7
2.16e7
O.OOeO
34.0 RT
Rel. Int.
Fn 5 100%.
366.9792
QC (non-EQ)
34.16-41.15
0% 1,
35.0
—i—|—.—.—i—i—|—i—i—r-
36.0
» I '
37.0
-i—|—i—i—i—i—|—i—i—i—i—|—.—.—i—i—|—r
36,0	39.0
Abs. Int,
-B.22eB
¦4.11e6
O.OOeO
f	|	t	r	t	t	|	t	t	t	»	y
40.0	41.0 RT
Rel. Int.
Fn 6 100%-
454.9728
QC (non-EQ)
41.17-46.41
0%-
"i	1—*r~
T—'—•"
-i	1	r-
42.0
43.0
44.0
45.0
-r	r	1	1	»	1	r*
46.0
Abs. tnt
-1,26e7
¦ 6.28e6
¦O.OOeO
RT
Rel. Int.
Fn 7 100%
454.9728
QC (non-EQ) j
46.42-54,01
0%.
I ¦ ' 1 1 I ' 1 1 ¦ 1
47.0
48.0
49.0
50.0
51.0
t i i i I i t i i I i i i i I
52.0
Abs. Int.
-1,42e7
¦ 7.08e6
O.OOeO
53.0
—i—r—i—r-i
54.0 RT
Results: P:\P9400_P9499\P9464_6042 PCB\m$ovnx$\SBS_080724_PCB_VD.utp_ms, saved 05-Aug-2008 08:25 (EE)
AP UllraTrace-Pro V3.993 User/System: EB/EEC2-038 see: 512-728
Peak annotation: Areas, Centroids
PKD: n/a Printed: 0S-Aug-2008 08:32:49 Page 1 or 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial; 2
Acq: 24-Jul-2008 15:30:01
User: JU Datafile: 080724V17 EQ
Rel. Int.
Fn1 100%.
218.9856
QC Check
9.03-13.00
0%-^i—i—i—t—|—i—i—i—i—|—i—i—t—
9.5
10.0
—I	!—|	1	1—I	1—I	1	r~
10.5
11.0
—I—1—i—1	1—|—|—|—T—!	1—1	!—I	1	[—I—I	1—I—|	1	1—I	<	|—r
11.5	12.0	12.5
Abs. Int
-7.88e7
„3,94e?
¦ O.OOeO
13.0 RT
Rel. Int.
Fn 2 100%-
242.9856 f
QC Check
13.02-17.79 1
0%.
T—I I I—I 1 I I I I I I—I i I I I t
13.5
' I ¦
14.0
14.5
' I '
15.0
1 I 1
15.5
16.0
i i i i I i i i—r-
16.5
t*"
17.0
i i i i i i
Abs. Int.
-4.49e7
-2.24e?
17.5
RT
Fn 3
Rel, Int.
100%.
292.9824
QC Check
17.81-23.26
0%-
18.0
I
19.0
20.0
21.0
—I—
22.0
Abs. Int.
-4.40e7
-2.20e7
¦O.OOeO
23.0
RT
Rel. Int.
Fn 4 100%
330.9792
QC Check
23.27-34.14
Abs. nt
4.23e7
-2.11e7
o.ooeo
Rel. Int.
Fn 5 100%.
454.9728
QC Check
34.16-41.15
0%-
-i—i—|—t—i—i—r-
35.0
38,0
37.0
T"
38,0
7	f	1 |
—I—i—I—r~
39,0
40.0
41.0
Rel. Int.
Fn 6 100%.
404.9760
QC Cheek
41.17-46.41
0%.
Abs. Int.
-1,61e7
-8,05e6
42,0
43.0
—I—
44.0
	1	
45.0
46.0
• O.OOeO
RT
Rel. Int.
Fn 7 100%
454.9728
QC Check
46.42-54.01
S4.0 RT
Results; P:\P9400_P9499\P9464_6042 PCB\msoun:e$\SBS_<®0724_PCB_VD.utp_nis, saved 0S-Aug-2Q08 08:25 (EE)
AP UitmTrace-Pm V3.993 User/System: EE/EEC2-038
Peak annotation: Amas, CentrokSs
PKD: nla Printed: 0S-Aug-2OO8 08 32:5t Page 2 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jut-2008 15:30:01
User: JLJ Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 1
188.0393
MoCB
4a 3.27e3
9.03-13.00
Rel. Int.
100%
Fn 1
190.0363
MoCB
4a 2.81 e3
9.03-13.00
1.1 ses
11.26
1.9le4
9.45
3,11e4
4.76e4
Abs. Int.
-4.35e4
2.17e4
O.OOeO
13.0RT
Abs. Int.
1.94e4
9.70e3
O.OOeO
13.0 RT
Rel. Int.
100%
Fn 1
200.07S5
MoCB Std.
4a 1 24e4
9.03-13.00
Ate. Int.
-1.75e4
76e3
O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
202,0766
MoCB Std.
4a 5.53e4
9.03-13.00
I 1 11 1 I	
10.0	10.S
Abs. Int.
-2.47e5
1.24eS
i i ¦ i O.OOeO
13.0 RT
Rel. Int.
100%
Fn 1
218.9856
QC Check
9.03-13.00
Abs. Int.
7.88e7
3.94e7
O.OOeO
13.0RT
Results: P:\P9400_P9499\P9464_6042 PCB\resources\SBS_080?24_PCB_ VD.utp_res. saveef OSAug-2008 08:25 (EE)
AP UltraTrace-Pm V3 993 User/System: EE/EEC2-038 cc: 4180, 7994
Peak annotation: Areas, Centmids
PKD: 05-Aug-2008 08:25:31 Printed: 0S-Aug-2008 08 32 52 Page 3 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl 1 -10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Dataftle: 080724V17_EQ
Rel. Int.
100%
Fr» 1
222.0003
DiCB-1
4o 7.22e3
9-03-13.00
Abs. Int.
-1.66e4
8.31e3
r i i i i i r i ( | i i r i | r t i i | i i i i —U.0u6U
13.0RT
Rel. Int.
100%
Fn 1
223.9974
DiCB-1
4 o 1,94e4
9.03-13.00
Abs. Int.
-6.72e4
3 36e4
O.OOeO
13.0RT
Rel. Int.
100%
Fn 1
234.0406
DiCB Std.
4o 1.28e4
9.03-13.00
Abs. Int.
- 3.33e4
1,67e4
O.OOeO
13.0 RT
Rel. Int.
100%
Fn 1
236.0376
DiCB Std.
4a 1 03e4
9.03-13.00
t i—| 1 r 1 i t 'i --i i i i | i i i i | r i i i | i i i r ,_i ¦ i ¦» i i j i
11.0	11.5	12.0	12.5
Abs. Int.
-2.29e4
1.14e4
O.OOeO
13.0RT
Rel. Int.
100%-
Fn 1
218.9856
QC Check
9.03-13.00
Results: P:\P9400_P9499\P9464_6042 PCB\resoun:es\SBS_080724_PCB_ VD utp_res. saved 0S-Aug-2008 08:25 (EE}
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc~2353. 0919
Abs. Int.
88e7
3 94e7
O.OOeO
13.0RT
Peak annotation: Areas. Centroids
¦ PKD: 05-Aug-2008 08:25:31 Printed: OS-Aug-2008 08:32:53 Page 4 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V 17_EQ
Rel. Int.
100%
Fn 2
222.0003
DiCB-2
4o 6.78e3
13.07-17.79
1.03eS
16,55
i i i i—|—i—i
14.0
0%-w;
16.0
Abs. Int.
-2.38e4
1.19e4
-O.OOeO
RT
Rel. Int.
100%
Fn 2
223.9974
DiCB-2
4o 1.52e4
13.07-17.79
Abs. Int.
7.48e4
-3.74e4
r— O.OOeO
RT
Rel. Int.
100%-
Fn 2
234.0406
DiCB Std.
4a 1,57e4
13.07-17.79
Abs, Int.
-3.88e4
1,94e4
O.OOeO
Rel. Int.
100%
Fn 2
236.0376
DiCB Std.
4cr1.41e4
13.07-17.79
Abs. Int.
r2.99e4
1.50e4
I I I
-r-H- O.OOeO
Rel, Int.
100%-
Fn 2
242.9856
QC Check '
13.07-17.79
Abs. Int.
-4.49e7
-2.24e7
0%-
I I I I I I 1 I
! | I I I I | I I 1 1
14.0
-O.OOeO
RT
13,5
» | i i r i | i i \ i | i i i » i1 <
14.5	15.0
t T t I t I I I I I f
15.5
16.0
16.5
t t J t I t t
17.0
I I I | I
17.5
Results: P\P9400_P9499\P9464_6042 PCB\resouKes\SBS_08C724_PCB_VD utp_res, saved 0S-Aug-2008 08:25 (EE)
AP UltraTrace-Pm V3.993 User/System EE/EEC2-038 cc: 4930, 7909
Peak annotation: Amas, Centrokts
PKD: 0S-Aug-2008 08:25:31 Printed: 0S-Aug-2008 08 32:54 Page 5 of 22
-------
AP Lab ID; SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC:pcbx100_a Vial; 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 2
255.9613
TrCB-2
4o 2.87e3
13,02-17,79
' i ¦ i | ¦ i i ( j i r i i | i r i i j f i
14,5	15.0	15.5
Abs. Int.
-7,69e3
3.85e3
I—O.OOeO
RT
Rel, Int.
100%
Fn 2
257.9584
TrCB-2
4o 2.76e3
13.02-17.79
Rel. Int.
100%
Fn 2
268.0016
TrCB Sid.
40 5.78e4
13.02-17,79
Rel. Int
100%
Fn 2
269.9986
TrCB Std.
4o 3.45e4
13.02-17.79
Abs. Int,
-6,29e3
3 15e3
O.OOeO
RT
Abs. Int.
-9.52e5
4.76e5
2.73e6
13.45
3.83e5
13.44
T—O.OOeO
RT
Abs. Int.
-1.66e5
8.29e4
O.OOeO
Rel. Int.
100%-
Fn 2	:
242,9856 ¦
QC Check "
13.02-17.79"
Abs. Int
-4,49e7
-2,24e7
0%-
	r.,
13.5
1 I 1
14.0
14.5
15.0
15.5
Results: P:\P94M_P3499\P9464_W42 PCBtesources\S8S_080724_PCB_ VD utp_res, saved OS-Aug-2008 08:25 (EE)
AP UltraTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 4832, 4677
~l—i i t i | "i i ) * '|—i—i—i—¦ | i—i—i—i—|—i—i i i—|—i—i i t—|—i i i—r-j—i—i—i i | 0.OOeO
16.0	16.5	17,0	17.5	RT
Psak annotation: Areas, Centroids
PKD 05-Aug-2008 08:25:31 Printed: 05-Aug-200B 08 32:55 Page 6 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: S1L 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbxl 00_a Vial; 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 3
255.9613
TrCB-3
40 3.14e3
17.81-23.26
1 99e5
5.35@4
22.82
3.88e4
18.0
19.0
20.0
21.0
22 0
23.0
Abs. Int.
-6,05e4
3.0364
O.OOeO
RT
Rel. Int.
100%
Fn 3
257.9584
TrCB-3
4a 3.39e3
17.81-23.26
Rel. Int.
100%
Fn 3
268.0016
TrCB Std.
4 o 4.20e4
17.81-23.26
i.Ble5
21.27
3.38e4
2.10e6
20.80
Abs. Int.
~5.49e4
2.74e4
O.OOeO
RT
Abs. Int.
-5.09e5
2.5465
I i , ¦ O.OOeO
23.0 RT
Rel. Int.
100%-
Fn 3
269.9986
TrCB Std,
40 3.98e4
17.81-23.26
20.0
3.12S5
20.79

21.0
22.0
23.0
Abs. Int.
-6.74e5
3.37e5
¦O.OOeO
RT
Rel. Int.
100%
Fn 3
292.9824
GC Check
17.81-23.26
18,0
19.0
20.0
21.0
22.0
23.0
Abs. Int.
4,40e7
2.20e7
O.OOeO
RT
Results: P:\P9400_P9499V9464_6042 PC8\m$oufce$\S8S_080724_PCB_VD.utp_ms. saved 05-Aug-2008 08:25 (EE)
AP UltmTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 6920, 6122
Peak annotation: Areas, C&ntmids
PKD: 0S-Aog-2008 08:25:31 Printed: 0&Aug-2008 08:32:56 Page 7 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JU Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 2
289.9224
TeCB-2
4o 1.89e3
13.02-17.79
I | I 1
15.5
16,0
Abs. Int.
-5,07e3
2,54e3
i i » i i l i i—i—i—|—i i i i—j—¦- 0. OOeO
17.0	17.5	RT
Rel. Int.
100%
Fn 2
291.9194
TeCB-2
4o 2,80e3
13.02-17.79
Abs. Int.
-5,48e3
2.74e3
l-^O.OOeO
RT
Rel. Int.
100%-
Fn 2
301.9626
TeCB Std.
4o 5.50e3
13.02-17.79
Abs. Int.
-3 03e4
1,5164
OOeO
16.0
16.5
Rel. Int.
100%
Fn 2
303.9597
TeCB Std.
4o4.62e3
13,02-17.79
I I I I ( I I I I I I
Abs. Int.
-1.50e4
7.48e3
O.OOeO
RT
Rel. Int.
100%-
Fn 2
242.9856 ¦
QC Check
13.02-17.79"
Abs. Int.
-4.49e7
-2.24e7
0%-
I ( I I I I | I I 1 t | I 1 I			
13.5	14.0	14.5
15.0
15.5	16,0	16,5
O.OOeO
I I | I I » I | I I J » | f I I I
17.0	17,5 ' RT
/Jesuits: P:\P9400_P9499\P9464 6042 PC8V>esources\SBS_080724 PCB_VD utp_res, saved OS-Aug-ZOOB 08:25 (EE)
AP Ultra Trace-Pro V3.993 User/System: EEMEC2-038 cc: 6226. 1339
Peak annotation; Areas, Centmitis
PKD 05-Avg-2Q08 08:25:31 Printed; 05-Aug-200B 00:32:57 Page 0 of 22
-------
AP Lab ID; SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC; pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JU Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 3
289.9224
TeCB-3
4o 1,85e3
17 81-23.26
Abs. Int.
-5.94e3
2.97e3
O.OOeO
RT
Rel, Int.
100%
Fn 3
291,9194
TeCB-3
4a 1.91 e3
17,81-23.26
20,0
Abs. Int.
-4.62e3
2,31e3
O.OOeO
RT
Rel. Int.
100%-
Fn 3
301.9626
TeCB Std.
4a 5.85e3
17,81-23.26
Abs. Int.
-1.81e4
9,05e3
20.0
21,0
22,0
—l	1	1	1	1	1	0,0060
23.0	RT
Rel. Int.
100%-
Fn 3
303.9597
TeCB Std.
4o 3.46e3
17.81-23,26
20.0
21,0
22,0
23,0
Abs. Int.
-1.14e4
5.69e3
-O.OOeO
RT
Rel. Int.
100%
Fn 3
292.9824
QC Check
17.81-23.26
Abs. Int.
-4.40e7
2.20e7
—i—i—!—i—i—r~*~ O.OOeO
23.0	RT
Results; P:\P9400_P9499\P9464 6042 PCBVesauives\SBS_080724 PCB_VD ulp_res, saved OS-Aug-2008 08:25 (EE)
AP Ultra Trace-Pro V3.993 User/Sysiem: E&EEC2-03B cc: 9530, 6258
Peak annotation: Areas. Centmkis
PKD: OS-Aug-2008 08:25:31 Printed¦ 05-Aug-2008 08:32:59 Page 9 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: S!L 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Via!; 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17_EQ
Rel. Int. 1,|8e5
100%-
Fn 4
289,9224
TeCB-4
4o 2,36e3
23,27-33.00 1
23.57
1.81e5 16605
27.65 28,11

24.0
i f | i § i r[T'i r r*
25,0	26.0
4.61e4
28.95

Abs. Int.
-5,86e4
•2.93e4
29.0
30.0
31.0
32.0
¦Q.OOeO
RT
Rel. Int. 2 08e5
100%-
Fn 4
291.9194
T ©C B~4
4o 3.22e3
23.27-33.00
23.56
2.16e5
27.64
1.76e5
26.11

Ww-
4,47e4
28.95
24.0
25.0
26.0
27,0
280
l * ' ' ' I
29.0
30.0
r...|....1....,...|.....r..T....|..„,	|„„r.„t„ , i | ; | > > |
31.0	32,0
Abs. Int.
-5 26e4
¦2.63e4
•O.OOeO
RT
Rel. Int.
100%-
Fn 4
301.9626
TeCBStd,
4 o 3.98e3
23,27-33.00
Abs. Int.
-1.77e4
8.87e3
OOeO
Rel. Int.
100%-
Fn 4
303.9597
TeCB Std.
40 4.74e3
23.27-33.00
2.54e4
30.82
2.5064
4.40e4
0.02
1.7964
29.06
Abs. Int.
-2.21 e4
1,11e4
OOeO
Rel, Int.
100%-
Fn 4
330.9792
QC Check
23.27-33.00"
Abs. Int.
-4.23e7
-2.11e7
0%-
9|TVtV|V
30.0
	' I ' ' ¦ ' 1 ' ' ' ' I 1
31.0	32.0
-O.OOeO
RT
	'	I	'	'	'	'	I	
24.0
25.0
I	f
26.0
i i i | i i i i—| i i i i | i—r-
27.0	28,0
I 1 1 1 1 I ¦
29.0
Results: P:\P9400_P9499\P9464_6042 PCB\resources\SBS_080724_PCB_VD.utp_res, saved 05-Aug-2008 08:25 (EE)
AP Ultra Trace-Pro V3.993 User/System: EE/EEC2-038 cc: 1782, 6840
Peak annotation: Areas. Centroids
PKD: Q5-Aug-2Q08 03:25:31 Printed: 0S-Aug-2008 08:33:00 Page 10 of 22
-------
AP Lab ID; SBS_08Q724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID; SIL 7-27-1
VSIR expt: pcb0405_cI1-1Q_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 3
323,8634
PeCB-3
4o 2,93e3
1781-23 26
Rel, Int.
100%
Fn 3
325.8804
PeCB-3
4o 4,18e3
17,81-23.26
Abs. Int.
-3.13e4
1.56e4
O.OQeO
RT
1.1065
22.09
1.3765
22,08
Abs, Int.
-4.29e4
2.15e4
O.OOeO
Rel. Int.
100%
Fn 3
337,9207
PeCB Std.
4o 5.39e3
17.81-23,26
4.0964
22.16
2.73e4
2.58e4
21.26
Abs, Int.
-3,13e4
1.57e4
O.OOeO
RT
Rel. Int.
100%
Fn 3
339.9177
PeCB Std.
40 8.79e3
17.81-23.26
Abs. Int.
-2,92e4
1.46e4
O.OOeO
Rel, Int.
100%
Fn 3
292.9824
OC Check
17.81-23.26
19.0
20.0
21.0
22.0
23.0
Abs. Int.
4.40e7
2.20S7
-O.OOeO
RT
Results: P:\P9400_P9499\P9464___6042 PC8\re$ources\SBS_080724_PC8_VD utp_res. samd OZAug-2008 08:25 (EE)
AP UttraTrace-Pm V3.993 User/System: EE/EEC2-038 cc. 4217. 7181
Peak annotation: Areas. Cenimids
PKD: 05-Aug-2008 08:25:31 Printed: 05-Aug-2008 08:33:01 Page 11 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Dataftle: 080724V17_EQ
Rel. Int.
100%
Fn 4
323-8834
PeCB-4
4o 3.05e3
23.27-34.14
1.02e5
9 R1 30.72
7.12e4
6.49e4
25.60
24.65
Abs. Int.
r2.74e4
1.37e4
OOeO
34.0 RT
Rel. Int.
100%
Fn 4
325.8804
PeCB-4
4cr4.17e3
23.27-34.14
Rel. Int.
100%-
Fn 4
337.9207
PeCB Std.
40 7.29e3
23.27-34.14
0%.
1.58e5
30.31
34.0 RT
1.67e5
1,23e5
24.65
9.35e4
2.74e4
27.61

2.04e5
32.12
6.72e4
4 42e4 28.66
28.30
4,38e4
29
4.30e4
Abs. Int.
-4.66e4
2.33e4
OOeO
Abs. Int.
-7.61e4
3.81e4
¦,—,—,—,—i—r—O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
339.9177
PeCB Std.
4a 9.04e3
23.27-34.14
1,70e5
32.0
1 I4e5
29.57
Abs. Int.
-8.19e4
4.10e4
O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Results: P:\P9400_P9499\P9464_6042 PCB\resources\SBS_08O724_PCB_VO.utp_m$. saved OS-Aug-2008 08:25 (EE)
AP UltraTmce-Pro V3.993 User/System EE/EEC2-038 cc 0250. 2161
30.0
Abs. Int.
-4.23e7
2.11e7
-p— O.OOeO
34.0 RT
Peak annotation: Areas, Centroids
PKD 0S-Aug-2008 08 25 31 Printed: 0S-Aug-2008 08:33:02 Page 12 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Ju1-2008 15:30:01
User: JLJ Datafile: 080724V17_EQ
Rel. Int.
100%
Fn 5
323.8834
PeCB-5
4a 3,63e3
34.16-41.15
1.57e5
35.0
Abs. Int.
-3.63e4
1 81e4
O.OOeO
36.0
37.0
38.0
39.0
40.0
41.0 RT
Rel. Int.
100%-
Fn 5
325.8804
PeCB-5
4o6.17e3
34.16-41.15
3-00e4
36.76
3 65e4
34.44
r
40.0
Abs. Int.
-9.27e4
4.63e4
*1-O.OOeO
41.0 RT
Rel. Int.
100%
Fn 5
337.9207
PeCB Std.
4o 1.40e4
34.16-41.15
Abs. Int.
r7.83e4
3.91e4
^—i—i—i i i—i—*—i—|—r—i—*i—i—|-1 *"• O.OOeO
40.0	41.0 RT
Rel. int.
100%
Fn 5
339.9177
PeCB Std.
4cr1.36e4
34.16-41.15
Abs. Int.
-9.25e4
4,62e4
jr—O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15'
0%-
I I | 1 1 I I } <
35.0
~r—t—|—i r i i | i i i i | i i
36.0
I > > >
Abs. Int.
-1.75e7
•8.77e6
37,0
38.0
39.0
40.0
-i—i—|—i—i—i—r—|—r-*~ 0 OOeO
41,0 RT
Results: P:\PS400_P9499\P9464_6042 PCB\re$ources\SBS_08Q724_PCB_VD.utp_re$, saved OS-Aug-2008 08:25 (EE)
AP UltmTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 6569, 9267
Peak annotation: Areas: Centroxls
PKD: 05-Aug-2008 08:25:31 Printed: 05-Aug-2008 08:33:03 Page 13 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Oatafile: 080724V17_EQ
Rel. Int.
100%-
Fn 4
359.8415
HxGB-4
4a 2,71e3
23,27-34.14
1.50e5
26.72
Abs. Int.
-4.17e4
2.09e4
1—— Q.QQeO
34.0 RT
Rel. Int.
100%-
Fn 4
361.8385
HxCB-4
4o 1.80e3
23.27-34.14 -
0%-
1.34e5
26.72

24.0
26.0
28.0
30.0
32~0
Abs, int.
-3.59e4
-1.80e4
¦O.OOeO
34.0 RT
Rel. Int.
100%-
Fn 4
371.8817
HxCBStd.
4o 7.62e3
23.27-34.14
0%-

24.0
26.0
1.1 leS
32.25
7.26e4
30.77
01 e4
Abs. Int.
6.24e4
3.12e4
OOeO
34.0 RT
Rel. Int.
100%
Fn 4
373.8788
HxCB Std,
4o 7,09e3
23.27-34.14
4.S5e
32

Abs. Int.
-1,26e5
6.28e4
i—T—O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
23.27-34.14
Abs. Int.
-4.23e7
2.He7
O.OOeO
34.0 RT
Results: P:\P9400_P9499\P9464_B042 PCBiresaurces\SBS_080724_PCB_i/D.utp_ms. saved 05-Aug-2008 08:25 (EE)
AP UtlmTmce-Pro V3.993 User/System: EE/EEC2-038 cc: 6814. 6863
Peak annotation: Areas. Certtroids
PKD: 0^-Aug-2008 08:25:31 Printed: 05-Aug-2008 08:33:05 Page 14 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jyl-2008 15:30:01
User: JLJ Datafile: 080724V17_EQ
Rel, Int.
100%
Fn 5
359.8415
HxCB-5
4o 3.31e3
34.16-41.15
1.46e5
34.52
38.0
•t ' t f 1 t I I J I I I I [ I I I I | \ I » »
39.0	40.0
Abs. Int.
-3.81e4
1.91 e4
' I' i 0.00@0
41.0 RT
Rel. Int.
100%
Fn 5
361.8385
HxCB-5
4o 3.43e3
34.16-41.15
Rel. Int.
100%
Fn 5
371.8817
HxCB Std
4o 1.78e4
34.16-41.15
Rel. Int.
100%
Fn 5
373.8788
HxCB Std.
4o 1.83e4
34,16-41,15
1.1765
34,52
1.3565
1 79e5
l.5Se5
34.0
39.09
Abs. Int.
-2 98e4
1,49e4
O.OOeO
41.0 RT
Abs. Int.
5,27e4
264e4
i—ji—f1—i—i—|—i—i—i—i—|—0. OOeO
40.0	41.0 RT
Abs. Int.
6.32e4
3.16e4
35,0
36.0
37,0
38.0
39.0
40,0
i * | i 0. OOeO
41,0 RT
Rel, Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
~l—iiit
350
~i—I—i—i—r-
360
37.0
38.0
-1—i—i—j—i—*—r-
39.0
40.0
Abs. Int.
-1,75e7
•8.77e6
I i O.OOeO
41.0 RT
Results: P:\P940O_P9499\P9464_6O42 PCBtesoume$\SBS_080724_PCB_VD.vtp_res. saved Q5-Aug-2008 08.25 (EE)
AP Ultra Trace-Pro V3.993 User/System: EEJEEC2-038 cc: 5346. 4879
Peak annotation: Areas, Cenlroids
PKD: 05-Aug-200B 08:25:31 Printed: 0S-Aug-2008 08:33:06 Page f 5 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID; SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 4
393.8025
HpCB-4
4o 1.57e3
30.00-34.14
Rel. Int.
100%
Fn 4
395.7995
HpCB-4
4o 1 46e3
30 00-34.14
Rel. Int.
100%
Fn 4
405.8428
HpCB Std.
4o 5.55e3
30.00-34.14
34.0 RT
1.36e5
32.04
1.29e5
32.05
4,?le4
32.35
Abs. Int.
-4 51e4
2.25e4
Q.QOeO
Abs. Int.
-3 89e4
1 J4e4
. , . , • 0 OOeO
34.0 RT
Abs, Int.
-4.17e4
2.08e4
O.OOeO
34.0 RT
Rel. Int.
100%
Fn 4
407.8398
HpCB Std.
4o 6.64e3
30.00-34.14
9,32e4
32.12
2.69e4
32
6.39@4
30.25
Abs. Int.
-6.40e4
3.20e4
-j—i—t—{—i—|—I—i—i—i—j—*—i— 0. OOeO
33.5	34.0 RT
Rel. Int.
100%
Fn 4
330.9792
QC Check
30.00-34.14
34.0
Abs. Int.
4,22e7
-2.He7
-O.OOeO
RT
Results: P:\P9400_P9499\P9464_6042 PC8Vesoura>5XSBS_080724_PCB_VD.Mp_ms. saved 05-Aug-2008 08:25 (EE)
APUltraTmce-Pm V3.993 User/System: E&BEC2-038 cc: 1950, 5944
Peak annotation: Areas, CentmkSs
PKD: 0S-Aug-2008 08:25:31 Printed: 05-Aug-2008 08:33:07 Page « of 22
-------
AP Lab ID: SBS_Q80724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_d1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile. 080724V17 EQ
Rel, Int.
100%
Fn 5
393.8025
HpCB-5
4a 2.62e3
34.16-41.15
1,22e5
34.79

Abs. Int.
-3.17e4
1,58e4
!* t O.OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
395.7995
HpCB-5
4o 2.46e3
34.16-41,15
0%-X^
i.iieS
34.79
35.0
36.0
37,0
38.0
39.0
40,0
Abs. Int.
-2.54e4
1.27e4
t—fs'^-O.OOeO
41,0 RT
Rel. Int.
100%-
Fn 5
405.8428
HpCB-5 Std,
40 1.34e4
34.16-41 15
5.82e4
38.35
Abs. Int.
-4.37e4
2,18e4
|—n—i—i—i—j—i—i—i—i—|—i 0. OOeO
40.0	41,0 RT
Rel. Int.
100%
Fn 5
407.8398
HpCB-5 Std
4o 1,43e4
34.16-41.15
1.1465
9.26e4
38.1
6Jt4e4
.38
0 /q-*-i—i——j
41.0 RT
Abs. Int.
7.24e4
3 62e4
O.OOeO
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15
0%-
[ I	I	1	1	|	TT"
35.0
'"1	|	T	T	T	T	I	
36.0
37.0
38,0
39,0
Results: P:\P9400_PQ499\P9464_6042 PCB\msoumes\SBS_080724_PCB_VOutp_res, saved 05.4ug.200S 08:25 (EE)
AP UltraTrace-Pm V3.993 User/System: EE/EEC2-038 cc: 8688. 0112
' I 1
40.0
' • I >
Abs. Int.
-1.75e7
¦8.77e6
41,0
¦O.OOeO
RT
Peak annotation: Areas, Centroids
PKD: OS-Aug-2008 08:25:31 Printed: 0S-Aug-2008 08:33:08 Page 17 of 22
-------
AP Lab ID; SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17_EQ
Rel. int.
100%-
Fn 6
393,8025
HpCB-6
4o 2.77e3
41.17-46.41
0%-A-
Abs, Int.
-6.13e4
¦ 3 06e4
O.OOeO
RT
Rel. Int.
100%'
Fn 6
395.7995
HpCB-6
4a 2.36e3
41.17-46.41
Abs. Int.
r 1.12e4
5 62e3
O.OOeO
RT
Rel, Int.
100%
Fn 6
405.8428
HpCB Std.
4cr 1.96e4
41.17-46.41
0% 				
Abs. Int.
-1.03e5
5.13e4
t—-J-O.OOeO
RT
Rel. Int.
100%
Fn 6
407.8398
HpCB Std.
4o 1,97e4
41.17-46.41
2.00e5
46.00
Abs. Int.
-1,50e5
- 7.50e4
O.OOeO
RT
Rel. Int.
100%-
Fn 6
404 9760
QC Check
41.17-46,41"
0%-
42.0
43.0
44.0
-i—i—i—r
45,0
r i i
46,0
Abs, Int.
-1.61 e7
•8.05e6
•O.OOeO
RT
Results P:\P9400_P9499\P9464_6042 PCBSmsouicesS8S_080724_PCB_VD,utp_res, saved 05-Aug-2008 08:25 (EE!
AP UltraTrace-Pro V3.993 User/System: EE/EEC2-038 cc: 8099, 7219
Peak annotation: Areas, Centro'uSs
PHD: 05-Aug-200B 08:25:31 Printed: OS-Aug-2008 08:33:10 Page 18 of 22
-------
AP Lab ID: SBS_08Q724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17_EQ
Rel. Int.
100%
Fn 5
427.7635
OcCB-5
4o 2.98e3
34.16-41.15
1.14e5
37.12
Abs. Int.
-3 41e4
1.70e4
O.OOeO
35.0
36.0
37,0
38.0
39.0
40,0
Rel. Int.
100%-
Fn 5
429.7606
OcGB-5
4o2.75e3
34.16-41.15
0%-
35.0
36.0
1.32e5
37.12
37,0
38.0
f I f f | I I I I
39.0
40.0
	1	1'" 1MM
Abs. Int.
-4.00e4
•2.00e4
41.0
¦O.OOeO
RT
Rel, Int.
100%-
Fn 5
439.8038
OcCB Std.
4o 8.99e3
34.16-41,15
Rel. Int.
100%
Fn 5
441.8008
OcCB Std.
4o 1.13e4
34.16-41.15
6 62e4
41.0 RT
4.40e4
35,04
8.2284
Abs. Int.
3 12e4
1.56e4
O.OOeO
Abs. Int.
-4.48e4
-2.24e4
I 1 i i i j i 0. OOeO
41.0 RT
Rel. Int.
100%-
Fn 5
454.9728
QC Check
34.16-41.15"
0%-
"¦	I	r
35.0
-i—i—i—j—i—r-
' I '
36.0
37.0
38.0
39.0
ResultsI P \P9400_P9499\P9464_6042 PCBVesources\SBS_080724_PCB_VD utp_rvs. saved 05-Avg-2008 08:25 (EE)
AP UttmTmce-Pm V3.993 User/System: EE/EEC2-038 cc: 8563, 4353
-i—]—i—i—i—
40.0
Abs. Int.
-1,75e7
8.77e6
41.0
-O.OOeO
RT
Peak annotation: Areas, Centmids
PKD: 05-Aug-2008 08:25:31 Printed: 05-Aug-2008 08:33:11 Page 19 of 22
-------
AP Lab ID; SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIRexpt: pcb0405_cl1-10_mm6 GC: pcbx100_a Viai: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 6
427.7635
OcCB-6
40 3.10e3
41.17-46.41
Abs, Int.
-1.17e4
5 86e3
O.OOeO
RT
Rel. Int.
100%
Fn 6
429,7606
OcCB-6
4a 2.91 e3
41.17-46.41
44.0
Abs. Int.
-7.29e3
3.65e3
-O.OOeO
RT
Rel. Int.
100%-,
Fn 6
439.8038
OcCB Std.
40 1,04e4
41.17-46.41 H
42.0
43.0
44.0
45.0
46.0
Abs. Int.
r3.18e4
1.59e4
O.OOeO
RT
Rel. Int.
100%-
Fn 6
441.8008
OcCB Std. .
4o 1.62e4
41.17-46.41
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-4.08e4
2.04e4
O.OOeO
RT
Rel. Int.
100°/cr
Fn 6
404.9760
QC Check
41,17-46.41"
0%-
42.0
43.0
44.0
45.0
Results: P:\P9400_P9499\P9464_6042 PCB*esauwes\SBS_080724_PCB_VD.utp_ms. saved 05-Aug-2OO8 08:25 (EES
AP Ultra Twee-Pro V3 993 UsarTsystem- EE/EEC2-038 cc 7890,3149
46.0
Abs. Int.
-1.61e7
8.05e6
•O.OOeO
RT
Peak annotation Areas, Centroids
PKD: 0S-Aug-2008 08:25:31 Printed: OS-Aug-2008 08:33:12 Page 20 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15530:01
User: JLJ Datafile: 080724V17 EQ
Rel. Int.
100%
Fn 6
461.7245
NoCB
4o 2.61e3
41.17-46.41
Abs. Int.
-5 79e3
2.9Ge3
O.OOeO
RT
Rel. Int.
100%
Fn 6
463.7216
NoCB
4o3.19e3
41,17-46.41
45.0
Abs. Int.
-8.57e3
4 28e3
-O.OOeO
RT
Rel. Int.
100%
Fn 6
473.7648
NoCB Sid.
4o 8.34e3
41.17-46.41
42.0
43.0
44.0
45.0
46.0
Abs. Int.
-2.98e4
1.49e4
O.OOeO
RT
Rel. Int.
100%
Fn 6
475,7619
NoCB Std.
4cr6.40e3
41.17-46.41
Abs. Int.
-2.43e4
1.21e4
O.OOeO
RT
Rel. Int.
100%-
Fn 6
404.9760
QC Check
41,17-46.41
0%-
42,0
43.0
44.0
45.0
I t I
46.0
Abs Int.
-1.61e7
8 05e6
• -O.OOeO
RT
Results: P:\P94Q0_P9499\P9464_6042 PCB\resoumesSSBS_080724_PC8_VD.utp_ms, saved 05~Aug-2008 08:25 (EE)
AP UttraTrace-Pm V3.993 User/System: EEJEEC2-038 cc: 8526, 7090
Peak annotation: Areas Centroids
PKD: 05-Aug-2006 08:25:31 Printed: 0$-Atig-2QM 08:33:13 Page 21 of 22
-------
AP Lab ID: SBS_080724_PCB_VD
Instr: AutoSpec-Premier MM6
Sample ID: SIL 7-27-1
VSIR expt: pcb0405_cl1-10_mm6 GC: pcbx100_a Vial: 2
Acq: 24-Jul-2008 15:30:01
User: JLJ Dataflle: 080724V17 EQ
Ret, Int
100%
Frt 7
497.6826
DeCB
4o 3.33e3
46.42-54.01
Abs. Int.
-1,20e4
6.02e3
O.OOeO
54.0 RT
Rel. Int.
100%
Fn 7
499,6797
DeCB
4 o 3.71e3
46.42-54.01
I 1 1 1 ' I
49.0
Abs. Int.
-8.46e3
4.23e3
i—i—|—i—i—i—!—O.OOeO
54.0 RT
Rel. Int.
100%
Fn 7
509.7229
DeCB Std.
4a 3.56e3
46.42-54.01
Abs. Int.
-1,10e4
5 52e3
OOeO
54.0 RT
Rel. Int.
100%-
Fn 7
511.7199
DeCB Std. J
4a 3 49e3
46.42-54.01
Abs. Int.
-1.28e4
6.41 e3
i—i—i—i—|—i—t*t—i—|—i—i—i—i—f-O.OOeO
53.0	54.0 RT
Rel. Int.
100%-
Fn 7
454.9728
QC Check
46.42-54.01 "J
Abs. Int.
-1.6767
-8.36e6
0%-
~~i—r	i	|	i"
47.0
¦i	r	r	|	r	r	r	r	»	i •
i | i i i >
49,0
-O.OOeO
"T I 1 1	1	1—!	T~~
48.0
50.0
T , "1"'	' ""l	,,n
51.0
' I '
52.0
53.0
54.0 RT
Results: P:\P9400_P9499)P9464_G042 PCB\resources\SBS_080724_PCB_VD.utp_res, saved OS-Aug-2008 08:25 (EE)
AP UttmTrace-Pm V3.993 User/System: EE/EEC2-03S cc: 0098. 9705
Peak annotation: Areas, Cenlroids
PHD: 05-Aug-200B 08:25:31 Printed: 05-Aug-2008 08:33:14 Page 22 of 22
-------
—flu ftfflwQt
OPUSquan on MM1
26-JUL-2008 11:18
checkcode: 3f532
: 3(53

1613/8290 Sample Sumnnary
Analytical Perspectives
Client ID:
Lab ID:
0_6042_MB001
HB1 6042 DF SDS
Filename: 08Q723P2
GC column ID: db-5
[Form; DF]
Vial: 32
Sample text; MB1_6042_DF_SDS 0_6042_MB001
Typ
Name
Resp
RA


RT
''"RRF
Ax
2,3,7,8-TCDD
*
¦it
n
NOtF»/
1.09
Ax
1,2,3,7,8-PeCDD
*
-*
n
NotFs/
1.00
Ax
1,2,3,4,7,8-HxCDD
*
*
ri
MotF>v/r
1.10
Ax
1,2,3,6,7,5-HxCDD
#
*
n
NotF»^*
1.00
Ax
1,2,3,7,8,9-HxCDD

*
n
NotF>M""
1.03
Ax
1,2,3,4,6,7,8-HpCDD
¦k
*
n
NotF^
0.98
Ax
OCDD
*
~
n
NotFV'
1.08
Ax2
OCDD-a
*
*
n
NOtF»
0.07
Ax
2,3,7,8-TCDP
*
¦k
n
NOtF»/
1.17
Ax
1,2,3,7,8-PeCDF
*
~
n
NOtF>y"
1.02
Ax
2,3,4,7,8-PeCDF
*
*
n
NOtP»/
1.09
Ax
1,2,3,4,7,8-HxCDF
*
*
n
NotF®/
1.20
Ax
1,2,3,6,7,8-HxCDF
*
#
n
NotFis/
1.13
Ax
2,3,4,6,7,8-KxCDF
*
*
n
NotF»/,
1.17
Ax
1,2,3,7,8,9-HxCDF
*
*
n
NotF®'
1.12
Ax
1,2,3,4,6,7,8-HpCDF
*
~
n
NotFa^*
1.43
Ax
1,2,3,4,7,8,9-HpCDF
*
*
n
NotFV'
1.35
Ax
OCDF
-*
*
n
N'OtF» /
0.94
Ax2
OCDF-a
*
*•
n
NotF»
0.05
ES
13C-2,3,7,8-TCDD
3.39e+07
0.83
y
27
07
0.96
ES
13C-1,2,3,7,8-PeCDD
2.88e+07
1.61
y
32
42
0.84
ES
13C-1.2,3,4,7,8-HxCDD
2.47e+07
1.31
y
36
38
0.91
ES
13C-1,2,3,6,7,8-HxCDD
2.74e+07
1.25
y
36
45
1.01
ES
13C-1.2,3,7,8,9-HxCDD
2.67e+07
1.31
y
37
04
0.98
ES
13C-1,2,3,4,6,7,8-HpCDD
2.31e+07
1.06
y
40
16
0.91
ES
13C-OCDD
3.23e+07
0.88
y
43
50
0.68
ES
13C-2,3,7,8-TCDF
5.17e+07
0.80
y
26
11
0.93
ES
13C-1,2,3,7,8-PeCDF
4.77e+07
1.58
y
31
12
0.86
ES
13C-2,3,4,7,8-PcCDF
4.98e+07
1.55
y
32
20
0. 88
ES
13C-1,2,3,4,7,8-HxCDF
3.34e« 07
0.53
y
35
40
1.25
ES
13C-1,2,3,6,7,8-HxCDF
4.04e+07
0. S3
y
35
49
1.46
ES
13C-2,3,4,6,7,8 HxCDF
3.79e+07
0.55
y
36
28
1.36
ES
13C-1,2,3,7,8,9-HxCDF
3.05e+07
0.52
y
37
27
1.28
ES
13C-1,2,3,4,6,7,8-HpCDF
2.54e+07
0.45
y
39
05
1.04
ES
13C-1,2,3,4,7,8,9 HpCDF
2.lle+07
0.45
y
40
51
0.85
ES
13C-OCDF
4.83e+07
0.89
y
44
05
1.01
CS
37C1-2,3,7,8-TCDD
1.52e+07


27
08
1.09
CS
13C-1,2,3,4,7-PeCDD
3.06e+07
1.63
y
32
10
0.89
CS
13C-1,2,3,4,6 PeCDF
5.13e+07
1.58
y
30
39
0.93
CS
13C-1,2,3,4,6,9-HxCDF
3.76e+07
0.53
y
36
07
1.39
CS
13C-1,2,3,4,6,8,9-HpCDF
2.49a+07
0.44
y
39
35
0.99
NA
n/a
~
*
n
NotF»
1.36
JS/RT
13C-1,2,3,4 TCDD
3.72e+0?
0.83
y
26
25
_
JS
13C-1,2,3,4-TCDF
5.92e+07
0.78
y
24
44
-
JS/RT
13C-1,2,3,4,6,7-HxCDD
1.37e+07
1.28
y
36
57
-
S: 3
Cal:
tds: JS (split adj.): 4000
'3,
Acq: 23 JUL-p#'21^3?
-.12
Wt/Vol: l.OpO
CS/SS; 1600 ES: 4000
Cone
J
J
3810
3690
3960
3950
4010
3720
6910
3760
3750
3830
3900
4050
4070
3500
3570
3630
6980
1500
3680
3710
3950
3670
139
140
60.8
Noise Fac
1820
870
1275
1275
1275
1665
2107
3651
1231
1845
1845
1402
1402
1402
1402
1545
1545
2885
3178
2398
2490
1788
1788
1788
2435
2707
1801
10642
10642
5681
5681
5681
5681
6244
6244
2043
2490
10642
5681
6244
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2. S
2.5
2403 2.5
2398
1801
2296
2.5
2.5
2.5
DL
3.77 f
2.92
3.66
3.68
4.22
5.90
10.8
297
Rec,
1.61
3.59
3 .15
1.77
1.62
I.72
2.38
2.17
3.18
II.6
235
/
5.42
/95
3
6.40
92
2
6.01
98
9
5.42
98
9
5. 63
100
8.22
93
1
12.1
86
3
2.83
94
1
18.1
93
8
17.7
95
8
13 .9
97
5
12 .0
101
12 .8
102
13 .7
87
5
18.4
89
3
22 .5
90
7
6.19
87
2
3.09
93
7
6.04
92
1
16.6
92
8
12.5
98
8
19.3
91
8
5.41
X
alvst:
-------
OPUSquan
on MM1 26-JUL-2008 11
: 18


checkcode: 3532 y
/




SS
37C1-2,3,7,8-TCDD
1
52e+07


27:08
1.14 ^
1S70


3.10
98.4
SS
13C-1,2,3,4,7 FeCDD
3
Q6e+07
1.63
y
32:10
1.06
4000
2490
2.5
7.91
100.0
SS
13C-l,2,3,4,6-PeCDF
5
13e+07
1.58
y
30:39
1.09
3960
10642
2.5
19.5
98.9 /
SS
13C-1,2,3,4,6,9-HxCDF
3
76e+Q7
0.53
y
36:07
0.95
3900
5681
2.5
7.78
97.6
SS
130-1,2,3,4,6,8,9-HpCDF
2
49e+07
0.44
y
39:35
0.95
4110
6244
2.5
13 .2
103
SBS
2,4,6,8-TCDF
*

*
a
NotF»
1.17
*
1231
2.5
1,61
-
Ay
1,3,6,8-TCDD
*

*
n
NotF»
1.09
-it
1820
2.5
3.77
_
Ay
1,2,3,9-TCDD
*


n
NotF»
1.09
•*
1820
2.5
3.77
-
Ay
1,2,8,9-TCDD
*

*
n
NotF»
1.09
*
1820
2.5
3.77
-
Ay
1,2,4,7,9-PeCDD
*

~
n
NotF»
1.00
•*
870
2.5
2.92
-
Ay
1,2,3,8, 9-PeCDD
*

•*
n
NotF»
1.00
*
870
2.5
2.92
-
Ay
1,2,4,6,7,9-HxCDD
*

-k
IX
NotF»
1.04
*
1275
2.5
3.85
-
Ay
1,2,3,4,6,7,9-HpCDD
*-

*
n
NotF»
0.98
*
1665
2.5
5.90
-
Ay
1,3,6,8-TCDF
*

*
n
NotF»
1.17
*
1231
2.5
1.61
-
Ay
2,3,4,8-TCDF
*

¦k
n
NotF»
1.17
*
1231
2.5
1.61
-
Ay
1,2,8, 9-TCDF
*

~
n
NotF» j
1.17
*
1231
2.5
1.61
-
Ay
1,3,4,6,8-PeCDF
*

*
n
NotF»^
1.17
*
2111
2.5
2.77
-
Ay
1,2,3,8,9-PeCDF
*

*
n
NOtF»
1.05
Jr
1845
2.5
3.36
-
Ay
1,2,3,4,6,8-HxCDF
*

*
n
NotF»
1.15
*
1402
2.5
1.84
-
Tot
Total Tetra-Dioxins
*

*-
n
NotF»
1.09
*
1820
2.5
3.77

Tot
Total Penta-Dioxins
-k

*
n
NotF»
1.00
*
870
2.5
2.92
-
Tot
Total Hexa-Dioxins
*

*
n
NotF»
1.04
*
1275
2.5
3.85
-
Tot
Total Hepta-Dioxins
*

*
ri
NotF»
0.98
*
1665
2.5
5.90
-
Tot
Total Tetra-Furans
*

*
n
NotF»
1.17
*
1231
2.5
1.61
_
Tot
Total Penta-Furans
*

*
n
NotF»
1.05
*
1845
2.5
3.36
-
Tot
Total Hexa-Furans
it

*
n
NotF»
1.15
*
1402
2.5
1.84
_
Tot
Total Hepta-Furans
*

*
n
NotF»
1.40
*
1545
2.5
2.61
-
Tot
TCDD EMPC
*

*
n
NotF»
1.09
*
1820
2.5
3.77
_
Tot
FeCDD EMPC
*

*
n
HOtF»
1.00
*
870
2.5
2.92
-
Tot
HxCDD EMPC
~

•*
n
NotF»
1.04
~
1275
2.5
3.85
-
Tot
HpCDD EMPC
*

*
n
NotF»
0.98
*
1665
2.5
5.90
_
Tot
TCDF EMPC
*

*
n
NotF»
1.17
*
1231
2.5
1.61
-
Tot
PeCDF EMPC
~

*
n
NotF»
1.05
*
1845
2.5
3 .36
-
Tot
HxCDF EMPC
*

*
n
NotF»
1.15
*
1402
2.5
1.84

Tot
HpCBF EMPC
*

*
n
NotF»
1.40
*
1545
2.5
2.61

AS
130-1,3,6,8-TCDD
3.
42e+07
0.82
y
23 :11
0.98
3760
2398
2.5
5.29
94.0 f
AS
13C-1,3,6,8-TCDF
6.
07e+07
0.79
y
20:58
1.09
3780
1801
2.5
2.42
94.4
DPE
HxCDPE
*



NotF»
_
.


.
_
DPE
HpCDPE
*



NotF»
-
*


-
-
DPE
OCDPE
*



NotF»
-
is


_
_
DPE
NCDPE
*



NotF»
-
*


_
-
DPE
DCDPE
~



NotF»
-
*


-
-
LMC
Fnl check mass
*



NotF»
„
*




LMC
Fn2 check mass
*



NotF»
_
*



_
LMC
Fn3 check mass
*



NotF»
-
*


_
_
LMC
Fn4 check mass
*



NotF»
-
*


_
_
LMC
Fn5 check mass
Jr



NotF»

*




-------
OPUSquan on MM1
26-JUL-2008 11:21
Totals Results
Analytical Perspectives
(Form: TOT
Totals class: TCDD EMPC
Pile Name: 080723P2 Sample #: 3
Function: 1 Run #: 3
Sample text: MB1_6042_DF_SDS 0_6042_MB001
Checkcode: 3532
Acquired: 23-JUL-08 21:39:12
Processed: 24-JUL-08 13:38:52
Total Cone.:
Unnamed Cone.: *
Homolog count: 0
ml Resp mod. m2 Eesp mod, RA
RT
Resp Adj_Resp S/N
Cone. Name
NotF»
Totals Results
Analytical Perspectives
[Form: TOT
Totals Class: PeCDD EMPC
File Name: 080723P2 Sample #: 3
Function: 2 Run #: 3
Sample text: MB1_6042_DF_SDS 0_6042_MB001
Checkcode: 3532
Acquired: 23-JUL-08 21:39:12
Processed: 24-JUL-08 13:38:52
Total Cone.: *
Unnamed Cone.:
Homolog count: 0
ml Resp mod. m2 Resp mod. RA
RT
Resp Adj_Resp S/N
Cone. Name
File Name: 080723P2 Sample #: 3
Sample text: MB1_6Q42_DF_SDS 0_6042_MB001
Acquired: 23-JUL-08 21:39:12
Processed: 24-JUL-08 13:38:52
Total Cone.:
Unnamed Cone - :
Homolog count: 0
RT
ml Resp mod. m2 Resp mod. RA
Resp Adj_Resp S/N
Cone. Name
NotF»
Totals Results
Analytical Perspectives
Totals class: HpCDD EMPC
File Name: 080723P2 Sample #: 3
Checkcode: 3532
Sample text: MB1 ,6042_DF_SDS 0_6042_MB001
Acquired: 23-JUL-08 21:39:12
Processed: 24-JUL-08 13:38:52
Total Cone,:
Unnamed Cone.:
Homolog count: 0
ml Resp mod. m2 Resp mod. RA
RT
Resp Adj_Resp S/N
Cone. Name
NotF»
Totals Results
Analytical Perspectives
Form: TOT]
Totals class: TCDF EMPC
File Name: 08Q723P2 Sample #: 3
Function: 1 Run #: 3
Sample text: MB1_6042_DF_SDS 0_6042_MB001
Checkcode: 3532
Acquired: 23-JUL-08 21:39:12
Processed: 24-JUL 08 13:38:52
Total Cone.:
Unnamed Cone.:
Homolog count: 0
-------
OPUSquan on MM1 26-JUL-2008 11:21
RT ml Resp mod. m2 Resp mod. RA	Resp Adj. Resp S/N	Cone. Name
NotF»	*11	* n * n	*	» *	n	*
Totals Results	Analytical Perspectives	[Form; TOT]
Totals class: PeCDF EMFC	Function: 2 Run #: 3	Checkcode: 3532
File Name: 080723P2 Sample #: 3	Sample text: MB1_6042_DF_SDS 0_6042_MB001
Acquired: 23-JUL-08 21:39:12 Processed: 24^JUL^08 13:38:52
Total Cone.: *	Unnamed Cone.: *	Homolog count: 0
ET ml Resp mod. m2 Resp mod. RA	Resp Adj_Resp S/N	Cone. Name
NotF»	*n	* n * n	*	* *	n	*
Totals Results	Analytical Perspectives	[Form: TOT]
Totals class: HxCDF EMPC	Function: 3 Run #: 3	Checkcode: 3532
File Name: 080723P2 Sample #: 3	Sample text: HB1_6042_DF_SDS 0_6042_MB001
Acquired: 23-JUL-08 21:39:12 Processed: 24-JUL-08 13:38:52
Total Cone.: *	Unnamed Cone.: *	Homolog count: 0
RT ml Resp mod. m2 Resp mod. RA	Resp Adj_Resp S/N	Cone. Name
NotF»	* n	* n * n	*	* *	n	*
Totals Results	Analytical Perspectives	[Form: TOT]
Totals class: HpCDF EMPC	Function: 4 Run #: 3	Checkcode: 3532
File Name: 080723P2 Sample #: 3	Sample text: MB1_6042_DF_SDS Q_6Q42_MBQ01
Acquired: 23-JUL-08 21:39:12 Processed: 24-JOL-08 13:38:52
Total Cone.: *	Unnamed Cone.: *	Homolog count: 0
RT ml Resp mod. m2 Resp mod. RA	Resp Adj_Resp S/N	Cone. Name
NotF»	*n	* n	* n	*	* *	n	*
-------
File: U80T2TP2 Acq: 23-JUL-200B 21:/9:12 GC EI+ Voltage SIR Autospec-U11 imaE
Sample# 3 Text: MB1_6042_DF_SDS 0_6042_MB001 Vial# 32 File Text: AP DB5
316.9824 S: 3 PKD(5,5,3,100.00%,750,0,0.00%, F,F) F.xpt: DF_CL4-8
25:14,
27:44
25:43 26:23
24:00
28:06 28:45 29:20_2
21:00	22:00	23:00
366.9792 S:3 F:2 PKD<5,5,3,100.00%,750.0,0.00%,F,F>
24:00
Expt: DF_CL4
25:00
26: 00
27:00
28:00
29:00
t2 ¦ 233*20
32 • 14* n 32:31 32:43 33: 00 " t 33:30
„„ 31:20
31:12 r 3
30:19 30:36 30:46
33:4
31:43 .31:56
30:00 30:11 f
29:41
Time
30:00	31:00
380.9760 S:3 F:3 PKD(5,5,3,100.00%,750,0,0.00%,F,F) Expt: DF_CL4
32:00
33:00
34:00 Time
1004 34:09 34 :19
01
34:40 34:5535:06 35:18
35:37
35:58
i 36:07
36:38	„	37:37
36:28 1 36:48 37:00 37:17	n 37:47
38:11 38:25 7,
35:00	36:00
430.9728 S:3 F:4 PKD(5r5,3,100.00%, 750.0,0.00%, F,F) Expt: DF„CL4-
37:00
38:00
Time
38:42
39:02 39:13 39:23
39:46
40:06 ,,
I 40:13
40:30 40:40
41 • 1 5
40:55 41:07 r 41:22 41:34
41:49
1004,
38:36 38:48 39:00 39:12 39:24 39J36 39148 40i00 40^12 40^24 40136 40lit
454.9728 S:3 F:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-
T	1—I	1—P	1—I—J—I—I—I—1—I—|—f—!	!	!	r—p l"f'l—1" 1 "I'
41:00 41:12 41:24 41:36 41:48 42:00
Time
1001, 42:08
80i
42:31
42:47
142:51
43 ¦ 49
41 ¦ 2^ 43:36	-i 43:55
44:30 44:40
43:04 43:1
44:55. _4
42:4
42?lV ' '42:24' *42536
43:00
43:12 43:24 43:36 43:48 44:00 44:12 44:24 44:36 44:48
45:00 Time
-------
File; 080723P2 Acq: 23 -JUL-2 U08 21 = 39:12 GC EI+ Voltage SIR Autospec-U"11imaE
Sample# 3 Text: MB1_6042JDF_SDS 0_6042_MB001 Vial# 32 Pile Text: AP DB5
319.8965 S; 3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 367
24:45
1004
5. 2E3
-4.1E3
24:3
22:49 23 :|23 23:44 24:19
3.1E3
20:44 21:00 21:20 22:02
2.1E3
f 21:44
0:15
2»:0
1.0E3
21:00	22:00	23:00	24:00
321.8936 S:3 BSUB(10000,15,-3.0) Expt: DF_CL4-B Noise: 393
25:00
26:00
27:00
28:00
29:00
26:26
lOOi
4.5E3
27:07
3.6E3
23:13
23:35	24:43 25:16
3: 23 I 23 j 43	24:3(7	fe5:25 25:50
2 , 7E3
20:15
1.8E3
9.0E2
28:00
Time
21:00	22:00	23:00	24i00
327.8850 S:3 BSUB(10000,15,-3.0} Expt: BF_CL4-8 Noise: 544
25:00
26:00
27:00
29: 00
Time
100%
27:
A1, 5
08
2E7
3. 6E6
80i


L2.9E6
60i


12.2E6
40i


Ll.4E6
20i
..
L7.2E5
21:00	22:00	23:00	24:00
331,9368 S:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise; 728
25:00
100%,
80.
60.
40.
20.
23:11
A1.54E7

00
7:06
A1.J&9E7 A1.54E7
28:00
29:00
Time
.3.8E6
.3 , 1E6
.2.3E6
.1.5E6
.7.7E5
21:00	22:00	23 = 00	24=00
333.9339 S:3 BSUBUOOOO,15,-3.0) Expt: DP_CL4-8 Noise: 566
25:00
26:00
27:00
28:00
29:00
1001
80i
60i
40i
20 j
21:00
22:00
23:11
A1.88E7
-t—f ¦ t-
23:00
24:00
25:00
26: 00

27:06
4 . 6E6
A1.85E7
I
E.3.7E6

£.2. 8E6

L1.9E6
11
E.9.3E5
27:00
28 : DO
29:00
Time
-------
/
File: 080723P2—Acq: 23-JUL-2008 21:39:12 GC EI+ Voltage SIR Avifospec-UltimaE"
Sample# 3 Text: MB1_6042_DF_SDS 0_6042_MB001 Vial# 32 File Text: AP DBS
355.8S46 S:3 F:2 BSUB(10000,15,-3.0) Expt: DF_CL4 8 Noise: 401
100!*
80.
60.
40.
20.
29:36
r
30: 00
30:39
30,
31:12
32:53
33:2^ 33:37 ^3:46
33:54
32:18
30:26
32:36
.3.2E3
. 2 . 6 S3
.1.9E3
.1. 3E3
.6.4E2
30:00	31:00
357,8517 S:3 F:2 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 372
32:00
33:00
33:18
33, 33:37 33:46
30:00	31:00
367.8949 S:3 F:2 BSOB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 536
100%
80.
60.
40.
20.
32:00
33 :00
		i——~—-|	1	1	1—i	1	1	1	1	1	i
30:00	31:00
369.8919 S:3 F:2 BSOB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 486
100%
80.
60.
40.
20.
32:10
A1.90E7
32:41
A1.78E7
34:00 Time
A . 6E3
3 .7E3
2 .7E3
1. 8E3
9 . 2E2
1:00 Time
5.3E6
4 .2E6
3.2E6
2 . 1E6
1. 1E6
33! 00
32:00
34
30:00	31:00
366.9792 S:3 F:2 PKD(5,5,3,100.00%,7 50.0,0.00%,F,F) Expt: DF_CL4-8
1	'	1	
32 :00
32:10
A1.16E7
32:41
A1.10E7
100%
30:19
30:46
31:20
33: 00
<3 3 * 2 ^3
32:31 32:43 33:00 ' i 33:30
00 Time
.3 , 3E6
2 . 7E6
2 .0E6
1.3E6
6.7E5
34:00 Time
33:48
2.3E6
30:36
31:12
31 : 56
29:41 30:00
1.8E6
1.4E6
9.2E5
4.6E5
30:00
31:00
32: 00
33:00
1: 00 Time
-------
File: 080723P2 Acq: 23-JUL-2008 21:39712 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 3 Text: MB1_6042_DF_SDS 0_6042_MB001 Vial# 32 File Text: AP DBS
389.8156 S:3 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 456
5.3E3
35:49
4 . 2E3
36:09
36:39
34:30
25
37:25
3.2E3
35:01
34:47 n
38:07
35:10 35:26 35
34:16
38:22
2.1E3
1.1E3
37: 00
38:00
35:00	36:00
391.8127 S: 3 F:3 BSUB (10000, IS,-3 . 0) Expt: DF CL4-8 Noise: 442
34:32
34:14	A 34:38
35: 00
401.8559 S : 3 F: 3 BSUB(10000,15,-3.0) Expt: DF_CL4
100^
80.
60.
40.
20j
Time
36:40
3.9E3
3.1E3
36:57 37;07 ,n
H I 37:20
37 :47
35:49
2.4E3
38:18
8:28
1
1. 6E3
7.8E2
36:00
Noise: 545
37:00
36:45
A1.52E7 37:03
A1.51E7
38: 00
Time
.4.3E6
.3.4E6
.2 . 6E6
.1.7E6
.8.6E5
35:00
403.8530 S : 3 F: 3 BSUB(10000,15,-3.0) Expt: DF_CL4-8
100%
80.
60.
40.
20.
36:00
Noise: 614
37:00
36:45
A1.22E7 37:03
A1.16E7
38:00
Time
35:00	36:00
380.9760 S:3 F;3 PKD (5,5,3,100.00%,7S0.0,0.00%, F, F) Expt: DF_CL4-
35:58
.3 . 5E6
l2.8E6
L2.1E6
i,1.4E6
L6.9E5
100»-j 34:09 34:19
80j
34:40 34:5535:06 35:1
37:00
36:38	37:37
36-28 "l 36:48 37:00 37:17	"1 37:47
38:00
Time
36:07
35:37
38:25
7
4E6

i_5
9E6

l4
4E6

L2
9E6

Li
5E6
35:00
36:00
37:00
38:00
Time
-------
/
File: 0B0723P2 Acq: 23-JUL-2008 21:39:12 GC EI+ VolXa >
38:48 39:00
39:12 39:24* 39:36 39 i 48 40100 40il2
3 F:4 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
40:06
2
9E6
12
3E6
Li
7E6
Li
1E6
L5
7E5
38:36
430.9728 S:
1 1 I ' 1 J 1 11 1
40:24 40:36
40:48
41:00
55 41
41:12 41:24
41:15
°7 r 41:22
91:36
41:34
41:48 42:00 Time
100S
39:02 39:13 39:23
40:30 40
41:49
39:46
4.3E6
3 . 4E6
2.6E6
1.7E6
8, 6E5
38:36
3 8:48 " 39:00
39Sl2' ' '39I24' ' 39 ' 36' ' 39 : 48 ' Wldo' ' 4
-------
File; 080723P2Acq: 23-JUL-2008 21:39:12 GC EI+ Voltage~SIR SUtospec-UitimaE
Sample# 3 Text: MB1_6042_PF_SDS 0_6042_MB001 Vial# 32 File Text: AP DBS
457,7377 S:3 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 461
43:50
44 :36
42:12 42:24 42:36 42:48 43:00
459.7348 S:3 F:S BSUB(10000,15,-3.0> Expt: DF_CL4
43:12 43:24
Noise: 519
43:36 43:48 44:00 44:12 44:24 44:36 44:48
43 :53
.3 . 7E3
2.9E3
2 . 2E3
1, 5E3
7.4E2
45:00 Time
100%
3.8E3
3 . 0E3
44:11
44:53
44:57
44:37
42:18
2 . 3E3
1 .5E3
¦1.6E2
43:12
42:12 42:24 42:36
469.7780 S:3 F:5 BSUB(10000,15,-3.0)
iooa
80i
60i
40i
20i
42748
Expt:
43 !36' ' '43S48 44:00
44:12 44:24 44:36 44:48
45: (
Noise:
42:12 42:24 42:36 42:48 43:00 43:12
471.7750 S:3 F:5 BSUB(10000,15,-3 . 0) Expt: DF_CL4-8 Noise: 703
100%
80-
60.
40.
20.
t—r—f—?—r-
43:24
		
43 :36
43:50
A1.51E7
i
"T"
I
~T~
Time
3 . 2E6
.2 . 6E6
1.9E6
1.3E6
6 . 4E5
43:48 44:00 44:12 44:24 44:36 44:48
43 :50
'45!00 Time
3.6E6
12.8E6
2 ,1E6
1. 4E6
7 . 1E5
	' I ' '
44:12
42:12 42:24 42:36 42:48 43:00 43:12 43:24
454.9728 S:3 F:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
~r
~T
43:36 43:48
44:00
t—1111—r p-f—j* t •t
44:24 44:36
44:48 45:00 Time
42:47 r„
1 42:51
43:49
43 :55
43:36
44:30 44:40
42:31
44:55
43 : 04
43 :1
43:25
4.0E6
l3.2E6
2.4E6
1.6E6
8.0E5
42:12 42:24 42:36 42:48 43:00 43:12 43:24 43:36 43:48 44:00 44:12 44:24 44:36
44:48
:0Q Time
-------
/
File: 080723P2 Acq':"23-JUL-2OOB 21:39:12 GC^TVoTtagTe SIR Autospec-UltimaE
sample# 3 Text: MB1_6042_DF_SDS 0_6042_MB001 Vial# 3.2 File Text: AP DBS
303.9016 S:3 BSUB(10000,15,-3,0) Expt: DF_CL4~8 Noise: 379
3.1E3
27:51
25:17	26:06	26J57
34 ,25-48 At	217 : 03
t r it 'II 26:30 Ji I 2i7:19
29:19
24:19
,n _ 21:01 21:42 22:01
20:35 I 21:20 1 , .h2:l
22:44	23:43
23:14 23:3
56 28:25 28:56
2.4E3
1.6E3
7, 9E2
21:00	22:00	23:00	24:00
305.8987 S:3 BSUB(10000,15,-3.0) Expt: DF CL4-8 Noise: 381
25:00
26:00
27:00
28:00
29:00
24:44
100%
4.1EJ
26:05
28:18
27:44 ( 28:54 29*13
24 1 ->h:19
3.2E3
23:53
22:25
W&5 ^ 21: 04
1 20
J ? ¦ HI
3.00. 23:33 34:00 24:32
0V 1 ' 1 I '24:17
2.4E3
1.6E3
Time
21:00	22:00	23i00	24^00
315.9419 S:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 825
25:00
100&
80i
60.
40.
20.
20:58
A2.68E7
24:45
A2.60B7
26:00
26:11
A2.29E7
27:00
28:00
29:00
Time
21:00 ' ' 22! 00 ' ' ' 23! 00 ' ' ' 24! 00
317.9389 S : 3 BSUB(10000,15,-3 . 0) Expt: DF_CL4-8 Noise: 885
5
4E6
l4
3E6
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3E6
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Li
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25:00
lOOi,
80.
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20.
20:59
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24:44
A3.32E7
26:00
26:11
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27:00
28:00
29:00
Time
.6. 8E6
.5.5E6
.4. 1E6
.2.7H6
1.4E6
21:00	22:00	23:00	24:00
375.8364 S:3 3SUBQ0000.15, -3.0) Expt: DF_CL4-8 Noise: 457
25:00
26:00
27:00
28:00
29:00
Time
20:10
[20.24 20:39 21-12 21:40
' r r ,21:1
22:34 P50
122:4
25:16
29:10
26:57
3 . 7E3
b	23:56
23:00 23:42
r
^¦¦13 26:26
27:09
28:53
27:51
3.0E3
22:20
06
27:33
2.2E3
1.5E3
7.4E2
21:00
22:00
23:00
24:00
25:00
26:00
27:00
28:00
29:00
Time
-------
File: 0B0723P2 Acq: 23-JUL-2008 21:39:12 GC EX+ Voltage SIR Autospec-UltimaE
Sample# 3 Text: MB1_6042 DF _SDS 0_6042_MB001 Vial# 32 File Text: AP DB5
339.8597 S:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 432
20:10
lOOi r
90j
80.
70.
60.
50.
40.
30.
20.
10.
20:22
21: 04
20:39
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23:51
23:34 24:00
29:25
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29:02
25:20
28:05 28:39
22:45
25:49
A, 25:0C
24:44 r
24:48
26:25
21: 58
21: 39
23:13
25:00
27 ! 00
28 !00
4.3E3
3.9E3
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2.6E3
2.2E3
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1.3E3
8.7E2
4.3E2
21:00	22:00	23:00	24:00
341.8568 S:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 429
21:27
26:00
29:00
Time
4.1E3
24:17
27:42
3.7E3
24:37
23:51
22:43
25:49
29:13
3.3E3
20:23
28:56
28:39
26:17
21:63 22:02 H2;50 23:23
r
2.9E3
20 = 15	21:05
604 60:2
50
2p_:42 25:16
25:27
7:50
26:2
r
26:0
27:25
2.5E3
22:25
21:1
7 : 04
28:1
26:139
26
2.0E3
1.6E3
1.2E3
8.2E2
4.1E2
21:00	22:00	23:00	24:00
316.9824 S : 3 PKD(5, 5, 3. 100.00%,750.0,0. 00%, F, F) Expt: DF_Ct.4-8
25:00
26:00
27:00
28:00
29:00
Time
100%
90 j
8 0 J
70.
60.
5QJ
40.
30.
20.
10.
20:16 20:43 21:10	21:55 22:21 23:04 23:39
oc 1 a	27:44
24 : 00 24; 34 ' ,-.25:27 25:43 i. 26:50 27:17
21 : 00
22 I 00
23' 00
25 • 00
.2. 3E6
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.1.8E6
.1.6E6
.1. 4E6
.1-1E6
.9 . 1ES
.6 -8E5
.4 . 6E5
2 . 3ES
24:00
26:00
27:00
28:00
29:00
Time
-------
File: 080723P2 Acq: 23-JUL-2008 21:39:12 GC EI+ Voltage SIR Autospec-UitimaE
Sample# 3 Text: MB1_6042._DF_SDS 0_6042..MB001 Vial# 32 File Text: AP DBS
339.8597 S:3 F:2 3SUB(10000,15.-3.0) Expt: DF_CL4-8 Noise: 333
3.0E3
33:16
32:21
29:41
12.4E3
27 _33 : 4X 33.59
1.8E3
1.2E3
6. 0E2
30:00
341.8568 S:3 F:2 BSUB(10000,15
-3.0)
31:00
Expt: DF_CL4-8 Noise: 379
32:00
33:00
30:00	31:00
351.9000 S : 3 F-. 2 BSUB (10000,15,-3.0) Expt: DF_CL4-8 Noise: 3141
32:00
33:00
30:39
A3.14E7
31:11
A2.92E7
32:20
A3.03E7
: 00 Time
3.5E3
2.8E3
2.1E3
1.4E3
6.9E2
34:00 Time
.8.4E6
-6 -7E6
15.0E6
l3.4E6
Ll.7E6
30:00	31:00
353.8970 S:3 F:2 BSUB(10000,15,-3.0) Expt: DF^CL4-8 Noise: 2259
32' 00
33:00
1004
80i
60.
40.
20.
30:39
A1.99E7
31:11
A1.85E7
32:20
A1,95E7
34:00 Time
3.4E6
L4.3E6
13.2E6
.2.1E6
11.1E6
30:00	31:00
409.7974 S:3 F:2 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 444
32! 00
33:00
34:00 Time
100%
32:31
¦3.6E3
3:22
31:18
30:46
29:36
r
2.7E3
33:4
1.8E3
9.1E2
30:00
31:00
32:00
33:00
; 00 Time
-------
File: 080775T2 Acqr™23™JuTT7OT8~^TnTTr5 iST'SIt Voltage SIR Autospcc-UltimaE
Sample# 3 Text: MB1	6042„_DF_SDS 0_6042_MB0Q1 Vial# 32 File Text: AP DB5
373.8207 S:3 F:3 3SUB(1G000,15,-3.01 Expt: DF_CL4-8 Noise: 415
35:41
3-6E3
36:03 36:13 36:30
34: 05
r
2.9E3
37:27 :
2.2E3
1.4E3
7 . 2E2
35:00
375.8178 5:3 F: 3 BSUBU0000. 15, -3 . 0) Expt: DF_CL4
36:00
Noise: 401
37 :00
38:00
Time
100!
3.2E3
35:50
2.6E3
35:27
34:17 34:30
1.9E3
1.3E3
6. 4E2
35:00	36:00
383.8639 S:3 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1324
35:40 35:48 35-07	36:28
100%,	A1.16E7A1.39E?	30E7 A1.34E7
80.
60.
40j
20.
37:00
38:00
Time
35:00	36100
385.8610 S:3 F:3 SSU8110000,15,-3.0) Expt: DF_CL4 8 Noise: 1887
35 r 40	*3 • ft 7
^	A2.18E7 a2.|4E7 ^2-46E7 A2.45E7
80|
60J
4oJ
2oJ
37:27
A1.04E7
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0E6
.3
2E6
.2
4E6
_1
6E6
_8
0E5
37 :00
38:00
Time
36:28
37:27
A2.01E7
7 . 7E6
6 . 2E6
4.6E6
.3 . 1E6
1.5E6
35:00	36:00
445.7555 S:3 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 487
37:00
38:00

4.2E3
34:17
3 . 3E3
6:45 36:53	37:19
34:02
r
2 . 5E3
37:39 ft ^7;57 3g
37:27
1.7E3
8.4E2
35:00
36:00
37:00
38:00
Time
-------
/
File: 080723F2 Acq: 23-JUL-2008 21:39:12 GC EI+ Voltage SIR Aut ospec-UltmaE"
Sample# 3 Text: MB1_6Q42_DF_SDS 0„6042_MB001 Vial# 32 File Text: AP DBS
407.7618 S:3 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 403
3.4E3
100&
40:32
40:52
0:56
39:08
39:1
41:57 L2.7E3
1
2.0E3
41:22
41:40 4l:48
1.3E3
6 . 7E2
38:36* ' 38 : 48 ' 3 9! 00* ' *39 ! 12* ' '39:24' ' '39:36' ' 39! 4*8* ' 401 00 40^12 40^24 40^36 40 S 48 41:00 41:'l2
41:24 41:36 41:48 42:00 Time
409.7788 S:3 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4^B Noise: 443
lOOSj
80.
60.
40.
20.
40:29
40:41
38:JP338f." 38:55
r
38:36 3B «i8' 397oO"jslL 39 ! 24 3 9:36' «fT 40 1 00 ' 40:12 To'^V ' YoiseT"'' 4 0 I 4 8 4l!oo'
417.8253 S: 3 F:4 BSUB (10000,15,-3.0) Expt: DF_CI,4 8 Noise: 1595
39:05
100%,	A7.88E6
80j
60.
40.
20.
00
Time
3
8E3
:..3
0E3
12
3E3
Ll
5E3
l7
6E2
00
Time
2
2E6
Li
8E6
Li
3B6
L9
0E5
L4
5E5
00
Time
5
0E6
L4
0E6
L3
0E6
L2
0E6
Li
0E6
00
Time
4
9E3
L3
9E3
12
9E3
L2
0E3
r9
8E2
00
Time
i M ' i
41:12
| 1 i 1 1 1 1 1 i 1 i-t-'-i-r 1
41:24 41:36 41:48
39:35
A7.61E6
40:51
A6.55E6
| I ' 1 ' I 1 I 1	' ' I > 1 » ' 1 I ' 1 I 1 I I ' 1 r t 1 I I		I	f	;	T....r	I I ) I 1 ! » I t !	r-r.y	)	,	T	j- i . J t
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40-00 40:12 40:24 40:36 40:48 41:00
419.8220 S: 3 F:4 BSUBjlOOOO, 15,-3 . 0} Expt: DF^CL,4-8 Noise: 2486
39:05
100t,	A1.75E7
80.
60j
40i
20.
-}—r~r—f—r
41:12
t—*—i—j—i—i—i—r—i—r r i""" i -i—i—i—i i r t
41:24 41:36 41:48 42
39:34
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38: 36 38:48 39100 39^12 39:24 39:36 39^48 4o!o0* ' *40 S12* ' '40:24' ' '4o!3V ' *4*0 ! 48 ' *4x1 00*
40:51
A1.46E7
479,7165 S:3 F:4 BSUB(10000,15,-3,0) Expt: DF_CL4-8 Noise: 460
1001,
80.
60.
40,
20.
40:19
38:44
38:49
41:12 41:24 41:36 41:48 42
41:57
"I
40:35
39:35
40: 56
40:46 fl 41
41:23
41:48
17 ( \ *
41:41
i ' ' ' I
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:
-------
/
File; 080723P2 Acq: 23-JUL-2008 21:39:12 GC EI+ Voltage SIR	Autospee-UltimaE
Sample# 3 Text: MB1_6042_DF_SDS 0_6042_MB001 Viali 32 File Text: AP DBS
441.7428 S:3 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 460
100!
4.5E3
44:58 E.3.6E3
44:0
42:25
"I 42:30
.2 . 7E3
1. 8E3
43 :47
42:03 42:1;
43:31
43 :12
20.
9.0E2
42:12 42:24 42:36 42:48
443.7398 S;3 F:5 BSUB{10000,15,-3.0) Expt:
43: 00
DF_CL4-
43:36
43:48
45:00 Time
43 :12
Noise: 402
43:24
44:12
44: 24
42:12 42:24 42:36
453.7830 S:3 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-
42:48
43:00
43:12
Noise: 586
43:24
43:36
43:48
44:24
44:36
44:48
45:00 Time
44:00
44:12
44:05
A2.2 8E7
100%,
60.;
40i
9E6
9E6
6E5
20j
42:12
455.7801 S:3 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-
45:00 Time
42:24
42:36
42:48
43:00
43:12
Noise: 548
43:24
43:48
44:00
44:12
44:24
44:36
44:4:
44:05
42:12 42:24
513.6775 S:3 F:5 BSUB(10000,15,-3.01 Expt
10 OS.	42:29	42:44
42 :36
45:00 Time
42 :4B
43:00 43:12
DF_CL4-8 Noise: 514
43 :36
43:48
44 : 00
44:12
44:36
44:48
44:57
42:12
42:24
45:00 Time
42:48
43 :36
43:00
43:12
43:24
43 :48
44:00
44 :12
44:24
44:36
44:48
-------
-pf\
OPUSquan on MM1
26-JUL-2008 11:18
checkcode: 3862

161 3/8290 Sanple Summary
Client ID:
Lab ID:
Sample text:
Typ
Run# ACD-M23-FB
P9464_6042_001
P9464_6042_001 Run#
Name
Analytical Perspectives
Filename: 080723P2
column ID: db-5
Air Train
GC
ACD-M23-FB
Resp
s
Cal
Stds
RA
Ax
2,3,7,8-TCDD
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3.91e+04
0.81
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1.76e+05
0.95
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Ax2
OCDD-a
*
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Ax
2,3,7,8-TCDF
9.57e+Q4
0.68
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Ax
2,3,4,7,8-PeCDF
1.67e+05
1.42
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1,2,3,4,7,8 HxCDF
2.65e+04
0.87
n
Ax
1,2,3,6,7,8 HxCDF
1.94e+04
0.88
n
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6.39e+04
1.11
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5.07e+04
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*
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Ax
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7.76e+04
0.72
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13C-2,3,7,8-TCDD
2.94e+07
0.81
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2.53e+Q7
1.63
y
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13C-1,2,3,4,7,8 KxCDD
2.23e+07
1.27
y
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13C-1,2,3,6,7,8-KxCDD
2.43e+07
1.27
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2.45e+07
1.30
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2.Q3e+07
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2.83e+07
0.88
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4.46e+07
0.79
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13C-1,2,3,7,8-PeCDF
4.16e+07
1.56
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3.67e+07
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3.35e+07
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2.67e+07
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13C-1,2,3,4,6,7,8-HpCDF
2.31e+07
0.45
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13C-1,2,3,4,7,8,9-HpCDP
1.88e+07
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y
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4.26e+07
0.90
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cs
37C1-2,3,7,8-TCDD
1.35e+07


cs
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2.83e+07
1.64
y
cs
13C-1,2,3,4,6-PeCDF
4.55e+07
1.57
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cs
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3.47e+07
0.52
y
cs
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2.27e+07
0.44
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NA
n/a
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n
JS/RT
13C-1,2,3,4-TCDD
3.42e+07
0.82
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5.44e+Q7
0.79
y
JS/RT
13C-1,2,3,4,6,7-HxCDD
" 1.23e+07
1.28
y

[Form: DF]
Vial: 33
Acq: 23-JUL-
02
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39
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27
32
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39
0.05
0.96
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0.91
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2.5
13.4
89.0
7221
2.5
13.1
91.5
6500
2.5
17.1
98.8
6500
2.5
14 .7
103
6500
2.5
15.8
100
6500
2.5
16.8
85.4
2490
2.5
7.92
90.6
2490
2.5
9.67
89.7
3810
2.5
12 .4
85.6


4.22
90.2
1560
2.5
4.13
92.7
7221
2.5
12.4
89.6
6500
2.5
15.4
102
2490
2.5
8.31
93.4
968
2.5
2.35
*
2989
2.5
_

2742
2.5
-
_
2062
2.5
"

/
-------
OFUSquan
on MM1 26-JUL-2008 11
18


checkcode: 3862
/




SS
37C1-2,3,7,8-TCDD
1.35e+07


27
08
1.14
/ 1600


4.45
100
SS
13C -1,2,3,4,7-PeCDD
2.83e+07
1.64
y
32
11
1.06 y
' 4220
1560
2.5
5.60
105 /
SS
13C-1,2,3,4,6-PeCDF
4.55e+07
1.57
y
30
39
1.09 \/
4030
7221
2.5
15.4
101 /
SS
13C 1,2,3.4.6,9-HxCDF
3.47e+07
0.52
y
36
07
0.95
3960
6500
2.5
10.4
99.0
SS
13C-1,2,3,4,6,8,9-HpCDF
2.27e+07
0.44
y
39
35
0.95
4130
2490
2.5
5.53
103
SBS
2,4,6,8-TCDF
*
*
n
NotF»
1.17
*
1762
2.5
2.74
-
Ay
1,3,6,8-TCDD
*
*
n
NOtF»
1.09
*
1728
2.5
4.11
-
Ay
1,2,3,9-TCDD
*
ir
n
NotF»
1.09
*
1728
2.5
4.11
-
Ay
1,2,8,9-TCDD
*
#
n
NOtP»
1.09
*
1728
2.5
4.11
-
Ay
1,2,4,7,9-PeCDD
*
*
n
NotF»
1.00
*
1319
2.5
5.01
-
Ay
1,2,3,8,9-PeCDD
*
#
n
NotF»
1,00
*
1319
2.5
5.01
-
Ay
1,2,4,6,7,9-HxCDD
*
*
ri
NotF»
1.04
*
2004
2.5
6.69
-
Ay
1,2,3,4,6,7,9-HpCDD
4.93e+04
0.99
y
39
25
0.98
9.85
2826
2.5
10.8
-
Ay
1,3,6,8-TCDF
*
~
n
NotF»
1.17
*
1762
2.5
2.74
-
Ay
2,3,4,8-TCDF
5.45e+04
0.74
y
26
04
1.17
4.19
1762
2.5
2.74
-
Ay
1,2,8,9-TCDF
*
•dr
n
NotF» j
1.17
#
1762
2.5
2.74
-
Ay
1,3,4,6,8-PeCDF
•*
*
n
NotFw/
1.17
*
2749
2.5
4.28
-
Ay
1,2,3,8,9-PeCDF
*
*
n
NotF»
1.05
*
4630
2.5
9.80
-
Ay
1,2,3,4,6,8-HxCDF
*
*
n
NotF»
1.15
*
2542
2.5
3.93
-
TOt
Total Tetra-Dioxins
*
*
n
NOtF»
1.09
*
1728
2.5
4 .11
-
Tot
Total Penta-Dioxins
*
*
n
NOtF»
1.00

1319
2.5
5 .01
-
Tot
Total Hexa-Dioxins
*
*
n
NotF»
1.04
*
2004
2.5
6.69
-
Tot
Total Hepta-Dioxins
4 -93e+04
0.99
y
39
25
0.98
9.85
2826
2.5
10.8
-
TOt
Total Tetra-Furans
3.33e+05
0.84
y
23
10
1.17
25.6
1762
2.5
2 .74
-
Tot
Total Penta-Furans
3.19G+05
1.65
y
29
55
1.05
27.6
4630
2.5
9.80
-
Tot
Total Hoxa-Furans
1.32e+05
1.06
y
34
29
1.15
14.0
2542
2.5
3 .93
-
TOt
Total Hepta-Furans
1.2Ge+05
1.02
y
39
06
1.40
15.6
1612
2.5
2 .95
-
Tot
TCDD EMPC
*
*
n
NotF»
1.09
¦k
1728
2.5
4 .11
_
TOt
PeCDD EMPC
*
¦*
n
NOtF»
1.00
*
1319
2.5
5.01
-
TOt
HxCDD EMPC
*
*
n
NotF»
1.04
*
2004
2.5
6.69
-
TOt
HpCDD EMPC
8.84e+04
0.99
y
39
25
0.98
17.7
2826
2.5
10.8
-
Tot
TCDF EMPC
4,40e+05
0.84
y
23
10
1.17
33,8
1762
2.5
2.74
-
Tot
PeCDF EMPC
3.67e+05
1.65
y
29
55
1.05
31.8
4630
2.5
9.80
-
Tot
HxCDF EMPC
2.10e+05
1.06
y
34
29
1.15
22.3
2542
2.5
3.93
-
Tot
HpCDF EMPC
1,20a+05
1.02
y
39
06
1.40
15.6
1612
2.5
2.95

AS
13C-1,3,6,8-TCDD
3.31e+07
0.81
y
23
11
0.98
3950
2989
2.5
7.21
98.8 /
AS
13C-1,3,6,8-TCDF
5.86e+07
0.79
y
20
59
1.09
3970
2742
2.5
4 .04
99.2
DPE
HxCDFE
~


NOtF»
-
*


-
-
DPE
HpCDPE
*


NotF»
-
*


-
-
DPE
OCDPE
*


NotF»
-
4


-
-
DPE
NCDPE
*


NotF»
-
*


-
-
DPE
DCDPE
*


NotF»
-
*


-
-
LMC
Fnl check mass
*


NotF»
_
*


-
-
LMC
Fn2 check mass
*


NotF»
-
*


-
-
LMC
Fn3 check mass
*


Not. F»
-
*


-
-
LMC
Fn4 check mass
*


NotF»
-
*


-
-
LMC
Fn5 check mass



NotF»






-------
OFUSquan on MM1 26-JUL-2008 11:20
Totals Results	Analytical Perspectives	{Form: TOT]
Totals class: TCDD EMPC	Function; 1 Run #: 4	Checkcode
File Name: 080723P2 Sample #: 4	Sample text: P9464_6042_001 Run# ACD-M23-FB Air Train
acquired: 23-JUL-08 22:30:02	Processed: 24-JUL-08 13:38:53
Total Cone.: *	Unnamed Cone.: *	Homolog count: 0
: 385®
in /
RT ml Resp mod. m2 Resp mod. RA	Resp Adj_Resp S/N	Cone. Name
NatF»	*n	* n	* n	*	* *	n	*
Totals Results	Analytical Perspectives	[Form; TOT]
Totals class: PeCDD EMPC	Function: 2 Run #: 4	Checkcode: 3862
File Name: 080723P2 Sample #: 4	Sample text; P9464_6042_001 Run# ACD-M23-FB Air Train	y?
Acquired: 23-JUL-08 22:30:02 Processed: 24-JUL-08 13:38:53
Total Cone.: *	Unnamed Cone.: *	Homolog count: 0
RT ml Resp mod. m2 Resp mod. RA	Resp Adj_Resp S/N	Cone. Name
NotF»	* n	* n * n	*	* *	n	~
Totals Results	Analytical Perspectives	[Form: TOT]
Totals class: HxCDD EMPC	Function: 3 Run #: 4	Checkcode; 3862
File Name; 080723P2 Sample #; 4	Sample text; P9464_6042_001 Run# ACD-M23-FB Air Train
Acquired: 23-JUL-08 22:30:02 Processed: 24-JUL-08 13:38:53
Total Cone.: *	Unnamed Cone.: *	Homolog count: 0
RT ml Resp mod. m2 Resp mod. RA	Resp Adj_Resp S/N	Cone. Name
NotF»	~ n	* n * n	~	* *	n	*
Totals Results	Analytical Perspectives	[Form: TOT]
Totals class: HpCDD EMPC	Function: 4 Run #: 4	Checkcode: 3862
File Name: 080723P2 Sample #: 4	Sample text: P9464_6042_001 Run# ACD M23--F3 Air Train
Acquired: 23-JUL-08 22:30:02 Processed: 24-JUL-08 13:38:53
Total Cone.: 17.666	Unnamed Cone.: *	Homolog count: 2
/
Resp Adj_Resp S/N
RT ml Resp mod. m2 Resp mod. RA
0.99 y*4 .926e+04 4.926e+04
39:2&. 2.453e+04 y
40:16, 1.993e+04 y
Totals Results
2-472e+04 y
2.450e+O4 y 0.81 4.443e+04 3.910e+04
Analytical*TPerspectives
2.87e+00 y
1.98e+00 n
[Form: TOT]
Totals class: TCDF EMPC
File Name: 080723P2 Sample #;
Cone. Name
9.85 1,2,3,4,6,7,9-HpCDD
7.82 1;2,3,4,6,7,8-HpCDD
Function: 1 Run #: 4	Checkcode: 3862
sample text: F9464_6042_001 Run# ACD-M23-FB Air Train
Acquired: 23-JUL-08 22:30:02 Processed; 24-JUL-08 13:38:53
-------
OPUSquan on MM1
26-JUL-2008 11:20
Total Cone.: 33.809
Unnamed Cone.: 22.268
Homolog count: 7
RT
ml Resp
mod.
m2 Resp
mod. RA
Resp
Adj_Resp
S/N

Cone.
Name

23:1ft,
2.376e+04
y
2
831e+04
y
0.84
y-5.207e+04
5.207e+04
2.63e+00
y
4.00


23:57
1.674e+04
y
2
124e+04
y
0.79
y-3.798e+04
3 .7SSe+04
3.10e+00
y
2.92


24 :4?
4 .253e+04
y
4
3 59e+04
y
0.98
8.612e+04
7.716e+04
3.53e+00
y
5.93


25:1*
2.263e+04
y
1
667e+04
y
1.36
<&3.930e+04
2.951e+04
2.02e+00
n
2.27


26:04^
2.311e+04
y
3
142e+04
y
0.74
y" 5.453e+04
5.453e+04
3.47e+00
y
4.19
2,3,4ft
i-TCDF
26: l>v
3.879e+04
y
5
691e+04
y
0.68 f 9.570e+04
9.570e+04
6.84e+00
y
7.35
2,3,7,?
•TCDF
26:35-'
4.259e+04
n
5
055e+04
n
0.84
•f 9.313e+04
9.313e+04
6.23e+00
y
7.15


Totals
Results


Analytical
Perspectives
[Form: TOT]



Totals class: PeCDF empc
File Name: O0O723P2 Sample #:
Function:
Sample text:
2 Run ft: 4
F9464 6042 001
Run# ACD-M23
Checkcode: 3862
-FB Air Train
/
Acquired: 23-JUL~08 22:30:02 Processed: 24-JUL-08 13:38:53
Total Cone.: 31.825
Unnamed Cone.: 17.793
Homolog count: 4
HT
ml Resp mod. m2 Resp mod. EA
Resp Adj_Resp S/N
2.731e+04 y
6•640e+04 n
2.888e+04 y
9.772e+04 n
Totals Results
29
55
30
05*
32
1 i*
32
2V
1.658e+04 y 1.65 yi 4.389e+04 4,389e+04
4.229e+04 y 1.57 1.08?e+05 1.087e+05
3.024e+04 y 0.96§>5.911e+04 4.751e+04
6.898e+04 y 1.42 y-1.667e+0S 1.667e+05
Analytical Perspectives
1.01e+00 n
1.42e+00 n
1.72e+00 n
3.94e+00 y
[Form: TOT)
Totals class: HxCDF EMPC
File Name; 080723P2 Sample #: 4
Acquired: 23-JUL-08 22:30:02
Total Cone.: 22.266
Function; 3 Run #: 4
Cone. Name
3.90
9.67
4.22
14.0 2,3,4,7,
-PeCDF
Checkcode: 3862
Sample text: P9464_6042_001 Run# ACD-M23-FB Air Train
Processed: 24-JUL-08 13:38:53
Unnamed Cone.: 10.953
Homolog count: 6
34
35
35
35
35
36
RT
28k
08
3?
4&1
. s>
48
2$.
.516e+04
.602e+03
.272e+03
,469e+04
•075e+04
.364e+04
Totals Results
1. m2 Resp mod. RA Resp
Adj_Resp
S/N

Cone.
Name

3.309e+04 y
1.06 ir"6.825e+04
6.825e+04
2.28e+00
n
7.44


1.105e+04 y
0.87 0 2.065e+04
1.734e+04
1.38e+00
n
1.89


9.576e+03 y
0.86 W 1.785e+04
1,494e+04
9.95e-01
n
1.63


1.694e+04 y
0.87 ft 3.163e+04
2.654e+04
1.70e+00
n
2.92
1,2,3,4,7,!
3-HxCDF
1.220e+04 y
0.88 ® 2.295e+04
1.943e+04
1.15e+00
n
1.87
1,2,3,6,7,!
3-HxCDF
3.023e+04 y
1.11 .388e+04
6.388e+04
3.21e+00
y
6.53
2,3,4,6,7,!
HxCDF
Analytical Perspectives
[Form: TOT)



Totals class: HpGDF EMPC
File Name: 080723P2 Sample #: 4
Function: 4 Run #: 4	Checkcode: 3862
Sample text: P9464_6042_Q01 Run# ACD-M23-FB Air Train
Acquired: 23-JUL-08 22:30:02 Processed: 24-JUL-08 13:38:S3
Total Cone.: 15.561	Unnamed Cone.: 9.440	Homolog count: 2
RT
ml Resp mod. m2 Resp mod. RA
Resp Adj_Resp S/N
39 :06-- 2 . 563e• 04 y
39:354. 3 .701e+04 y
2 . 505c» 04 y 1.02 y»,5 .067e+04 5.O67e+04 3 . 60e+ 00 y
3.200e+04 y 1.16 y"6.901e+04 6.901e+04 7. 00e+00 y
Cone. Name
6-12 1,2,3,4,6,7,8-HpCDF
9.44
-------
File; 080723P2 Acq: 23-JUL-2008 22:30:02 GC EI+ Voltage SIR Autospec UltimaE
Sample# 4 Text: P9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 Pile Text: AP DBS
316.9824 S:4 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt; DF_CL4-8
24:56
iD.ni 28:16	29:27
26:01
24:21
21:02 |=1:16
22 ^ 23:06
21:00
22:00
23:00
24:00
366.9792 S:4 F:2 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
30:45
100^29:38 29;48 r9:5^ 30:12 J0^23 30:37 r 31:01_
80ir
31:18
31:40
25:00
31:58
26:00	27:00
32 -iq 32:31 12-4R
28:00
33:1^
29:00
33:42
Time
33:52
2.3E6
1.9E6
1.4E6
9.4ES
4.7E5
30:00	31:00
380.9760 S: 4 F:3 PKD{ 5, 5, 3 ,100.00%, 750 . 0, 0 . 00%, F, F) Expt: DF...CL4-8
32 :00
33: 00
37 • 45
36:56 37:15 37:29 n 37:53
: 00 Time
38:11 38:2^
36:09 T 36=33
35:25
34:47 35:02 35-13 35:33 35:45
34:1534:26
35:00
9728 S:4 F:4 PKD(5,5,3,100.00%,750.0, 0.00%>F, F)
36:00
Expt: DF_CL4-8
37:00
38:00
39:32
38:35 38:52
39:05
40:57 41:06 41:15
39:40 39:49
41:28 41:37
=i 38:58
39:23
40:42
4.5E6
40:0
38:43
41:55
3 -6E6
2 .7E6
1.8E6
9.0E5
Time
430
454
38 !36' ' '38:48 39:00 39:12 39:24 39136 39:48 40:00 40:12
.9728 S: 4 F:5 PKD (5, 5, 3 ,100 . 00%, 750 . 0, 0. 00%, F, F) Expt: DF.CL4-8
42:57
40:24 40:36

43:12
43 :31
40:48
43:59
41:00 41:12 41:24
44:29
41: 36
44:34 44
41:48 4 2:00 Time
44 : 51
42:12
42:24
42:36
42:48
43:00
43:12
43:24
43:36
43:48
44:00
44:12
44:24
44:36
4 . 1E6
i3 . 3E6
2.5E6
1. 6E6
8.2E5
44:48 45:00 Time
-------
File; 080723P2 Acq; 23-JUL 21)08 22:30:02 GC EI+ Voltacje~~3IS Autospec-UltimaE
Sample# 4 Text: P9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 File Text; AP DB5
319.8965 S;4 BSUB110000,15,-3.0) Expt: DP_CL4-8 Noise; 416
23:13
24:44
4 . 3K3
26:27
26:11
3 . 4E3
23:36
23:55
24:50
2.6E3
24; 32
25:24
4:05
25:09
1, 7E3
8.6E2
20:58
21:106	„
20:33 k 1 2l=-2
21:00 1 ' ' 22]00 ' ' ' 23T0O	24:00	25=00	26=00	27 = 00	28:00	29:00
321.8936 S;4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 409
Time
27:07
6.8B3
23:13
*5. 5E3
4.1E3
22:44
20:24
2 . 7E3
27:37
:2» ii 28:07
29:04
28 ;,40
1.4E3
21:00	22:00	23=00	24:00
327.8850 S;4 BSUB(10000,15,-3.0) Expt: DF CL4-8 Noise: 548
25:00
-I	1	! 	(—
26:00
27:00
27:09
28:00
29:00
Time
lOOi
hi.
?SE7
_3
1E6
80^


l2
5E6
60.



_1
9E6
40i



_1
3E6
20.
_	 	 /
I
.6
3E5
21:00	22:00	23:00	24:00
331.9368 S: 4 BSUBQOOOO, 15, -3 .0) Expt: DF_CL4-8 Noise: 879
25:00
26:00
27:00
28 ; 00
29:00
Time
1003,
80.
60.
40i
20.
23:10
A1.48E7
26:25
A1.54E7 27:07
A1.31E7
21:00	' 22:00	23:00	24 = 00
333.9339 S:4 BSUB(10000,15,-3.0) Expt: DF„CL4-8 Noise: 709
23:00
.3 . 5E6
.2 . 8E6
.2 .1E6
1.4E6
.7.0E5
25:00
26:00
1004,
80.
60.
40i
20.
23:10
A1.83E7
26:25
A1.88E7
27:00
27:07
A1.63E7
281 00
29:00
Time
.4 , 2E6
3.4E6
2.5E6
1.7E6
8.5E5
21:00
22 ; 00
23:00
24:00
25:00
26:00
27:00
28:00
29; 00
Time
-------
File: 080723P2 Acq: 23-JUL-2UQ8 22:30:02 GC EI+ Voltage SIR Autospec UltiriaS
Sample# 4 Text: P9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 File Text: AF DB5
355.8546 S:4 F:2 BSUBf10000,15,-3.0) Expt: DF_CL4-8 Noise: 391
32:21
3 . 8E3
30:05
_3.1E3
29:42
32:43
33 :04
33:54
1.5E3
7 , 7E2
30:00	31:00
357.8517 S:4 F:2 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 344
32:00
33:00
: 00 Time
32:22
3 , 2E3
32:33
31:4
2.6E3
31:16
30:07
29:38
1.9E3
1.3E3
6.4E2
367.8949 S:4
100%,
80.
60.
40.
20.
30:00
F:2 BSUB(10000,15,-3.0)
Expt:
31:00
DF_CL4-B Noise: 484
32:00
33:00
32:11
A1.76E7
32:41
A1.57E7
34:00 Time
5.0E6
4.0E6
3.0E6
2.0E6
1.0E6
30:00	31:00
369.8919 S:4 F:2 BSUB(10000,15,-3 . 0) Expt: n? CL4-8 Noise: 521
100%
8oi
60j
4o|
204
32:00
33:00
34
32:11
A1.07E7
32:41
A9.61E6
366.9792 S:4
100^29:38 29
80.
60.
30:00	31:00
F:2 FKD{5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF„CL4-8
r>occ;	3 0 j 4 5
48 r 30:12 30:23 30:37 r 31:01
31:18
31:40
32:00
31:58
32:19 32:31 32:46
33:00
33:10
00 Time
.3.126
2.5E6
1. 8e6
1.2E6
6. 1E5
34:00 Time1
33:20
33:52
2 .3E6
1.9E6
1.4E6
9.4E5
L4.7E5
30:00
31:00
32:00
33:00
34:00 Time
-------
File: Q80723P2 Acq: 2J-JUL-2008 22:30:02 GC EI+ Voltage SIR Autospee-UltimaE
Sample# 4 Text: P9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 File Text: AP DBS
389,8156 S;4 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-fi Noise; 396
35:53
35:39 at *
"I 35:4
100&
4.0E3
36:24
34:58
3.2E3
36:46
37:13
37:27
2.4E3
37:4
37:53
38 : lb
06 psin -1
34:03
r
34:40
34:22
1. 6E3
8. 0E2
37:00
35:00	36:00
391.8127 S:4 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 434
38:00
35:00
401.8559 S: 4 F:3 BSUB (10000,15, -3 . 0) Expt: D? CL«i
100%,
80.
60j
40.
20j
36:00
Noise: 965
37:00
38:00
36i|L 37:03
A1.36E7
A1.38E7
35:00
403.8530 S:4 F:3 BSUB(10000,15,-3.0! Expt: DF_CL4-
1001
80i
60
40
20,
36:00
Noise: 696
37:00
37:03
A1.07E7
38:00
36:45
A1.07E7
Time
100%
35:55
3.3E3
36:08
35:09
34:5535.01
36:47 36:59 ^7:0B	37:36
37113
34:30
2.6E3
38:07
8:15
34:13 34:23
4:0
2.0E3
1.3E3
6.5E2
Time
3.9E6
l3.1E6
2.4E6
E.1.6E6
7 . 9E5
Time
.3.1E6
.2.5E6
Ll.8E6
L1.2E6
. 1E5
35:00	36:00
380.9760 S:4 F:3 PKD<5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
37:00
38:00
Time
34:15 34:26
35' 25
34:47 35:02 35:13 ' ~l 35:33 35:45
36:09 36:2t 36:33
37-45	38-
36:56 37:15 37-29 ' n 37:53 38:11
35:00
36:00
37:00
38:00
Time
-------
/
File: 080723P2 Acq: 23-JUL-2008 22:30:02 GC EI +	Voltage SIR Autospec-UltimaE
Sample# 4 Text: F9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 Pile Text: AP DBS
423.7767 S:4 F:4 BSUBU0000, 15, -3.0) Expt: DF_CL4-8 Noise: 374
39:25
A2.4SE4
40:16
100%
80i
60.
, h
20.

38:36 38:48 39:00 39:12
425.7737 S:4 F:4 BSUB(10000,15,-3
7 . 2E3
5 . 7E3
4 . 3E3
2 . 9E3
1.4E3
39:24 39:36 39:46 40:00
,0) Expt: DF_CL4-8 Noise: 376
39:25
40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48
:00 Time
8 . 4E3
6.7E3
45E4
5.0E3
3.3E3
1.7E3
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12
435.8169 S:4 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1143	—
40:15
100^	A1.Q5E7
80.
60.
40j
20.
40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
i	T'""t—I—*—i—r—i—i	T""i—i—% i t I ?—r-r—i-f-t—i—ir'T"-y"*	i—; 'riTf-i"*''
39:00 39:12 39:24 39:36 39:48 40:00
T
~r
2.8E6
2.3E6
1.7E6
1.1E6
5.7E5
38:36 38:48
437.8140 S:4 F:4 BSUB(10000,lb,-3.0) Expt: DF_CL4
Noise: 773
40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
40:15
42:00 Time
100%
2.7E6
2.2E6
1.6E6
1 .1E6
5.4E5
48 41:00
40:36
41:12
41:24 41:36
41:28 41:37
41:48
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12
430.9728 S:4 F:4 PKB(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
40:24
39:32
38:35
8:52
39:05
40:57 41
39:40 39:49
40:42
06 41:15
39:23
4 . 5E6
1 38:58 r
40:0
41:55
r 38:4
3.6E6
2.7E6
1.8E6
9 , 0E5
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48
00 Time
-------
File: 080723P2 Acq: 23-JUL-2008 22:30:02 GC EI+ Voltage SIR Autospec-Ultir.aE
Sample# 4 Text: P9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 File Text: AP DBS
457.737? S:4 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 449
43: 51
100*	A8.59E4
80.
60.
40i
20.
' 42 ! 12 ' ' ^7: 24 "	'^T^'| q'q '
459.7348 S:4 F:5 BSUB(10000,lb,-3.0) Expt: DF_CL4 8
1004
80i
60 i
40i
20 i
i—i—r~~t—r—i—r—t—i	t	i—r—i—r—i—r~t
43:48 44:00 44:12
i—I—|—r-
44:24
1.7E4
Ll.4E4
L1.0E4
6.8E3
13.4E3
43:12 43:24
Noise: 406
43:36
44:36
44:46
' ' i	1 * > | ' ' ¦ , • l	
42:12 42:24 42:36
469.7780 S:4 F:5 BSUBI10000,15,-3.
1001,
80.
60i
40.
20.
45:00 Time
43:51
2.6E4
A9.04E4
2. 1E4
1.6E4
1.0E4
5.2E3
43:48
44:00
44:12
44:24
44:36
44:48
43:50
A1.32E7
42:48 43:00
0) Expt: DF_CL4-8
43:12 43:24
Noise: 416
43:36
1 I | ¦ . "" f " t |—I—I—I—i—I—f—!—I—I—I—I—j—I—I—I—I—r—i—I—I—t—i—I—|—I—r—r—r-r—I—I—I—I—I—I—[—I—I—i r i—i—i—i—i—i—i i i T	I		, I I . I I
42:12 42:24 42:36 42:48 43:00 43:12 43:24 43:36 43:48 44:00 44:12 44^24
471.7750 S:4 F:5 BSUBtlOOOO,15,-3.0} Expt: DF_CL4-8 Noise: 782
100%
80.
60_
40.
20.
45:00 Time
2
7E6
L2
2E6
Ll
6E6
Ll
1E6
Ls
5E5
44:36
44:48
43:50
43:48
44:00
43:59
"" f | 1 1 1 ' 1 I 1 1
44:12 44:24
44 : 29
45:00 Time
3.0E6
2.4E6
1.8E6
Ll. 2E6
6.1E5
454.9728
,42:05
42:12 42:24 42:36 42:48 43:00
S:4 F:5 FKD(5,5,3,100.00%,750.0,0.00%,F,F)
42:57
43:12 43:24
Expt: DF_CL4-8
43:36
44:36
44 : 34
44:48
45:00 Time
42:31
42:52
43:12
43:31
44:51
42:12
42:24
42:36
42:48
43:00
43:12
43:24
43:36
43:48
44:00
44 ; 12
44:24
44:36
44 :48
: 00 Time
-------
File; 080723P2 Acq: ZX-JUL 200S 2 2:30:02 GC El-f Voltage SIR A'.itospec-U1 cimaE
Sample# 4 Text: P9464„6042_001 Run# ACD-M23-FB Air Traill Vial# 33 File Text: AP DBS
303.3016 S:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 381
26:35
100*
A4.26E4
9.5E3
7.6E3
24:42
A4.25E4
25:16
A2.26E4
5.7E3
23:09
A2.38E4
23:57
A1.67E4
3.8E3
1.9E3
21:00
22:00
23:00
24:00
25:00
26:00
27:00
28:00
29:00
305.8987 S:4 BSUB(10000,15,-3.0) Expt: DF CL4-8 Noise: 413
26:13
A5.69E4
1.2E4
11.0E4
24:41
A4.36E4
23:57
A2.12B4
23:12
A2.83E4
7.5E3
A3. 1<
25:16
A1.67E4
5.0E3
2. 5E3

21:00	22:00	23:00	24:00
315.9419 S:4 BSUB(10000,15,-3.0) Expt: DF_CL4~8 Noise: 766
20:59
100%,	A2.J9E7
80.
60.
40.
20.
25:00.
26:00
27:00
24:44
A2.40E7
I
26:12
A1.97E7
28:00
Time
29:00
Time
0E6
0E6
0E6
0E6
0E6
Time
21:00
317.9389 S:4 BSUB(10000,15,
20:59
1001,	A3.J6E7
80.
60i
40.
20.
22:00	23:00	24:00
- 3 - 0 > Expt: DF_CL4-8 Noise: 893
25:00
26:00
27:00
24:44
A3.Q4E7
28:00
29:00
26:12
..6.4E6
A2.50E7
t
n
E.S.1E6

L3.8E6

t2.6E6
1 l
L1.3E6
21:00	22:00	23:00
375.8364 S:4 BSUB(10000,15, 3.0) Expt: DF _CL4•8 Noise: 490
'1	1	V"
24:00
25:00
26:00
27 :00
28:00
29:00
Time
21:14
23:13
28:01
24:25 J4;44
22:07 22:24
21:29 , "122 • felO 22 :|50
7 ' '
27:34,7
21: 02
25;11 __ 25:58 ^6:15 26:55
2.t;05 28:28
25:26
29:17
.4 . 9E3
.3 . 9E3
.2. 9E3
2 . 0E3
.9 . 8E2
21:00
22:00
23:00
24:00
25:00
26:00 ' ' ' 27! 00*
28:00
29:00
Time
-------
File: 080723F2 Acq: 23-JITL-2008 22:30:02 GC EI+ Voltage SIR Autospee-UltimaE
Sample# 4 Text: P9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 File Text: AP DBS
339.8597 S:4 BSUB(10000,15,-3.0> Expt: DF..CL4-8 Noise: 459
100%
28:19
4.5E3
27:58
4.1E3
26:37
3 . 6H3
21:39
27:05
24: OB
24:53 •)« -,1
24.4c 25:23
3 . 2E3
2:13 22:38 23:06 23:28
29:29
1
20:32 o
7:17
26:23
21:25
28:43
2 .7E3
25:58
21:50
1:10
41 23
29 : 21
2.3E3
29:02 n
1.8E3
1.4E3
9.1E2
4.5E2
21:00	22:00	23)00	24)00
341.8568 S:4 BSUB(10000,15, 3.0) Expt: DF_CL4-8 Noise: 456
21:10
25:00
26:00
27:00
28:00
29:00
Time
100S
22:37
1E3
7E3
2E3
8E3
2.3E3
1.8E3
1.4E3
9.2E2
4.6E2
21:50
24:58
27:30
22:51
23:13 23:28	24:1
20:13
28:17
27:09 uL 4,
25:23 L_	26:37 27:-' ,Z" ' iZ
n 85:37 26:02
29:19
21:30
20:53
3:34
22:07
24:2
29 : 03
24:46
4:
25:68 26 I 3
6:12
25:1
8:17
21:00	22:00	23100	24100
316.9824 S:4 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
25:00
26:00
27:00
28:00
29:00
Time
100%
90.
80.
70.
60.
50.
40.
30.
2 0.
10.
20:21
21-16	01.49	24:21 24:40
21:02 r I: 21:01	23:06 .23:40	n
24,56 26 = 01 26:24
27:06 27:34 28:01 r8:" 28:52 29:2l
21:00
I	1 t
22; 00	23T0O ' ' ' 24!00 ' ' ' Siloo ' ' ' 26!00 ' ' ' 27 loo ' ' ' 28 = 00 ' ' ' 29100
2.3E6
2.1E6
1.9E6
1.6E6
1.4B6
1.2E6
9.3E5
7.0E5
4.7E5
2.3E5
Time
-------
File; Q80723P2 Acq: 23-JUL-2Q08 22:30:02 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 4 Text: P9464_6042_001 Run# ACD-M23-FB Mr Train Vial# 33 File Text: AP DBS
'339.859? S:1 F:2 BSUBI10000,15. 3.0) Expt: DF_CL4-8 Noise: 359
7
32:22
A9.77E4
32:13
A2.89E
29:55 30:05
A2 . 7 3F.4 A6.64E4
341.8568
30:00	31:00
: 4 F:2 BSUB110000,15,-3 . 0) Expt: DF_CL4 8 Noise: 412
32:00
33:00
351.9000 S
IOOSl
80i
60.
40j
20.
30:00
;4 F:2 BSUB(10000,15
31:00
-3.0) Expt: DF_CL4-8
30:38
A2.78E7
32:00
33:00
Noise: 2342
31:11
A2.54E7
32:21
A2.70E7
34:00 Time
32:21
1.9E4
1.5E4
1.1E4
7.4E3
3.7E3
34:00 Time
.7.6E6
.6 . 0E6
.4.5E6
.3.0E6
.1. 5E6
353.8970 S
lOOt,
80.
60.
40.
20.
30:00
: 4 F:2 BSUB(10000,15,
-3.0) Expt:
30:38
A1.77E7
31:00
DF CL4-8
32' 00
33:00
Noise: 1454
31:11
A1.62E7
i	i—
32:21
A1.67E7
34
00 Time
7E6
8E6
8E6
9E6
4E5
30:00	31:00
409.7974 S:4 F:2 BSUB(10000,15,-3,0) Expt: DF_CL4
32: 00
33:00
Noise: 382

34:00 Time
33 : 54
4.1E3
3.3E3
32:35
33:2
2.5E3
1.7E3
32:4
S.3E2
30:00
31:00
32:00
33:00
t:00 Time
-------
/
File: 08
Sample#
373.820?
1001
BOi
60,
40.
20.
0723P2 Acq: 23-JUL-2008 22:30:02 GC EI+ Voltage SIR Autospee-UltimaE
4 Text: P9464_6042_001 Run# ACD-M23-FB Air Train Vial# 33 File Text: AP DBS
S:4 P:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 397
34:29	,
A3.52E4	/	/
3S:<3/1	36:28 /
A1.47E4	A3.36EW
35:08
A9.60E3
35
1.08E4
35:33
1.0E4
8, 2e3
6.1E3
4.1E3
2.0E3
35:00"
375.8178 S:4 F:3 BSUB(10000,15,-3.0)
Expt: DF_CL4-8
- — 36:00
Noise: 472
37:00
38:00
35:00	36:00
383.8639 S:4 F:3 BSUB(10000,15,-3.0) Expt: DF„CL4-8 Noise: 1379
35:48 36:07
lOOi	A1.28E7 A1.J.9E7
80.
60.
40
20j
37:00
38:00
36:28
A1.16E7
37:27
A9.48E6
Time
36:29
100%
9.1E3
34:28
A3.31E4
7.3E3
35:40
A1.69E4
35:08
A1.10E4
35:50
A1.22E4
r
5.4E3
3.6E3
1.8E3
Time
.3.5E6
.2 . 8E6
.2 . 1E6
,1. 4E6
.7 .0E5
35:00	36:00
385.8610 S: 4 F:3 BSUBU0O00.15,-3 .0) Expt: DF_CL4-8 Noise: 2802
35:40 35:48 36:07
100%	A1.98E7 A2.J9E7 A2.?8F.7
80.
60i
40.
20.
37:00
le'Too"
36:28
A2.19E7
37:26
A1.73E7
Time
.6 . 7E6
.5.3E6
.4 . 0E6
.2 . 7E6
.1.3E6
35:00	36:00
445.7555 S:4 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 471
37:00
38:00
Time
1001
36:11
35:10 35:20
34:23
34
3
r
34:03
r "4:1
38:21
09 18:25
35:00
36:00
37:00
38:00
Time
-------
/
File: 08Q723P2 Acq; 23-OUL-20Q8 22:30-02 GC~^j> Voltage"SIS Autospec-UltimaE
Sample# 4 Text: P9464_6042_001 Runs ACD-M23 FB Air Train Vial# 33 File Text: AP DBS
407.7818 S:4 F:4 BSUB[10000,15,-3.0) Expt: DF_CL4-8 Noise: 360
39:36
loot	A3.70E4
39:05
A2,56E4
IF: 36' ' '38!48* ' '391 do" '39112' ' 39124 ' 39136 ' 39! 4a' ' *40' do" ' 40! 12* ' '40:24' ' '4o!36' ' '40:48' ' 41:00 ' 4l!l2 ' '41:24' ' '41:36'
409.7788 S:4 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 385
39:35
1D0S,	A3.20E4

.1.4E4
.1.1E4
.8.2E3
5.5E3
.2 .7E3
T
41:48 42:00 Time
1.2E4
9.5E3
39:05
l7.1E3
A2.50E4
4.7E3
2.4E3
38:36' ' '313! 48' ' 39: do' ' 39 ' 12* ' *39 ! 24' ' *39 ! 36 ' '39148' ' 40 : 00 ' 40 '12' ' 40:24 ' 4b!36 40:48 41:00 41' 12 41:24 41:36
417.8253 S.4 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1057
39 :05
100%	A7.J.3E6
8o|
60 j
4o|
2oj
41:48 42:00 Time
39:34
A6.97E6
40:50
A5.70E6
' 1 1 1 ' 1 1 ' ' ' ' I ' 1 ' ' ~| 1 1 	1	 11 I 1 1 		 | ' 1 1 i" 1 1 i i i i i 1 1 , 1 1 i 1 1 1 r 1 1 1 1 1 1 1 t 1 , 1 1 		 1 1 1 1 1 1 1 1 1 -
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36
419.8220 S:4 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 2502
1E6
7E6
3E6
4E5
2E5
100^
80.
60.
40.
20.
39:05
A1.60E7
39:34
Al.58E7
40:50
A1.31E7
41:48 42:00 Time
4.8E6
f_3. 8E6
2.9E6
_1.9E6
9.5E5
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36
479.7165 S:4 P:4 BSUB(10000,15,-3.0[ Expt: DF_CL4-8 Noise: 416
100%
41:48 42:00 Time
. . 38:54
;38:33 38:48 r
41:27
41: 50
39 :5
39 : 52
41:10 41:1
40:52
T 40:59 41:05
1:59
0:46
38:36 38:48 *39 ! do' ' '39:12' ' 39 !	' 39:48' ' '4o!do' ' *40 512* ' *40! 24' ' 40 ! 36" ' *40 ! 48* ' 41! 00 ' 41512* ' 41^24 " 4ll36
.3 . 8E3
.3 . 1E3
.2 . 3E3
.1 .SE3
.7 .7E2
I I 1 i ' ' >
~r
41:48 42:00 Time;
-------
/
File: 080723P2 Acq: 23-JUL-2008 22:30:02 GC EI+ Voltage SIR Autospec-UitimaE
Sample# 4 Text: P9464_6042_001 Runt ACD-M23-FB Air Train Vial# 33 File Text; M> DBS
441.7428 S:4 F:5 BSUBU0000, IS, -3.0) Expt; DF_CL4-8 Noise: 387
44:06
8 . 2E3
6.6E3
4 . 9E3
3.3E3
1.6E3
42:12 42:24 42:36
443.7398 S:4 F:5 BSUB(10000,15,-3.
42:48 43:00
0) Expt: DF_CL4-8
43:36 43:48 44:00 44:12
44:06
44:24
44:36 44:48
42:12 42:24 42:36 42:48 43:00 43:12 43:24
453.7830 S:4 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 441
1001,
80,
60i
40.
20J
43 :36
43:48
44:00
44:12
44:24
44:36 44:48
' 42! 12 ' ' ' 4*2 ! 24 ' ' ' 42 ! 36 ' 42 ! 48 ' ' ' 43 ! 00 ' ' ' 43 ! 12 ' ' ' 43 I 24 '
455.7801 S:4 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 701
1001,
80.
60.
40.
20.
, | | | | i—, i
43:36 43:48 44:00 44:12
44:04
A2.02E7
45:00 Time
1.3E4
1.0E4
7 . 5E3
5.0E3
2.5E3
45:00 Time
,4 . 2E6
.3 . 4E6
2 . 5E6
1.7E6
B.4E5
44:24
44:36 44:48
44:04
A2.24E7
	1—1	1	1	1	1	1	!	!	1 1 j 11 llnl I	1	1	1	1	1	I	1	T	1	f	1	1	1	!	1	1—1	1	!	1	!	j	T	1	1	I I l I I I I I—1	1	1	1	1	1	1	1	1	1	1	!	T—T	1	1	1	1~
42:12 42:24 42:36 42:48 43:00 43:12 43:24 43:36 43:48 44:00 44:12
513.6775 S:4 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 463
45:
00 Time
A .7E6
3.8E6
2.8E6
1.9E6
9.4E5
44:24
44:36 44:48
45:00 Time
4.0E3
35
1 44:40
3.2E3
2.4E3
1.6E3
"7.9E2
-1—r t ? i i 1—i—i—i—i—t—f—>—i—i—r—i—j—i—i—i—i—r—|—j—p—!—t—i—|—r—i—t—r—i—i—i—i—i—i—i—i—s—i—t—i—i—t—t—t—t—i—i—i—i—i—r~
42 i12 42:24 42:36 42:48 43:00 43:12 43:24 43:36 43:48 44:00 44:12
44:24
44:36 44:4£
:00 Time
-------
	7^~
checkcode: 5i08
—71^1 fl*f At^os?
OPUSguan on MM1
26-JUL-2008 11:18

1613/8290 Sample Summary
Analytical Perspectives
Client
Lab ID;
Sample
Typ
Ax
ID: Run# I-ACD-M23-1
P9464_6042_002 *	GC
text; P9464_6042_002 Run# I-ACD-M23
/
Filename: 080723P2 S
column ID: db-5	Cal
1 Air Train	_ Stds
to
Ax2
Ax
AX
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax2
ES
ES
ES
ES
ES
ES
ES
ES
Name Resp
Ax
1,2
3,7
Ax
1,2,3
4,7
Ax
1,2,3
6,7
Ax
1,2,3
7,8
Ax
1,2,3,4
6,7
1,2
1.2
2.3
1,2
,2,3
,2,3
2,3,7,8-TCDD
8-PeCDD
8-HxCDD
8-HxCDD
9-HxCDD
8-HpCDD
OCDD
OCDD-a
2,3,7,8-TCDF
7,8-FeCDF
7,8-PeCDF
7, 8-HxCDF
7,8-HxCDF
7,	8-HxCDF
8,	9-HxCDF
7,	8-HpCDF
8,	9-HpCDF
OCDF
OODF-a
130-
130-1,2
13C-1,2,3,4,7
130-1,2,3,6,7
130-1,2,3,7,8
130-1,2,3,4,6,7
ES
130-1,2
3,7
ES
130-2,3
4,7
ES
130-1,2,3
4,7
ES
13C-1,2,3
6,7
ES
13C-2,3,4
6,7
ES
13C-1,2,3
7,8
ES
130-1,2,3,4
6,7
ES
13C 1,2,3,4
7,8
130-2,3,7,8-TCDF
8-PeCDF
8-PeCDF
8-HxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8-HpCDF
9-HpCDP
ES	13C-0CDF
OS	3701-2,3,7,8-TCDD
OS	13C 1,2,3,4,7 PeCDD
CS	130-1,2,3,4,6-PeCDF
OS	liC 1,2,3,4,6,9 HxCDF
CS	13C-1,2,3,4,6,8,9-HpCDF
NA	n/a
JS/RT	130-1,2,3,4-TCDD
JS	130-1,2,3,4-TCDF
JS/RT 13C-1,2,3,4,6,7-HxODD
2,3,7,8-TCDD
,3,7,8-PeCDD
,4,7,8-HxCBD
,6,7,8-HxCDD
,7,8,9-HxCDD
8-HpCDD
13C-OCDD
40e+Q6
08e+07
17e+06
95e+06
05e+06
37e+07
89e+06
29e+0S
71e+07
63e+07
86e+07
80e+07
20e+07
21©+ 07
14e+06
39e+07
36e+06
59e+06
Q9e+05
26e+07
77e+07
21e+07
67e+07
60e+07
14e+07
39e+07
63e+07
16e+07
41e+07
55e+07
47e+07
04e+07
15e+07
46e+07
90e+D7
64e+07
86e+07
87e+07
23e+07
82e+07
25e+07
4.57e+07
7.31e+07
1.76e+07
RA
77
65
19
26
21
06
92
11
0.80
y
1.57
y
1.58
y
1.27
y
1.25
y
1.27
y
1.25
y
1.03
y
1.02
y
0.87
y
2.02
n
0.81
y
1.59
y
1.30
y
1.27
y
1.29
y
1.07
y
0.86
y
0.80
y
1.60
y
1.58
y
0.53
y
0.52
y
0.53
y
0.54
y
0.44
y
0.44
y
0.91
y
1.64
y
1.57
y
0.53
Y
0.46
y
*
n
0.83
y
0.80
y
1.27
y
RT
•.08^/1.
¦.4?Y 1
27
32
36
36.
37:04^/1
40:16- .
43:51-^1
43:50 0
39/ 1
46/, 1
Y/1
/ r
26:13'
31:12'
32
35
35
36
37
39
40
/
44
44
27
32
36
36
37
40
43
7aY
40/
49/
28*^
2W
06*"
53/
05/
05
1.17
1.02
1.09
1.20
1.13
06
41
38
45
04
15
50
26:11
31:11
32:20
35:39
35:48
36:28
37:26
39:05
40:50
44:05
27
32
30
36
39
08
10
38
07
34
17
12
43
35
94
05
96
84
91
01
98
91
J
25
46
36
28
04
85
01
09
89
93
1.39
0.99
NotF» 1.36
26:25
24:44
(Form: DF]
5 Vial: 34
JS (split adj.): 4000
(
Acq: 23- JUL-0p"*53:20:50
Wt/Vol: 1.000 ^ 		
CS/SS: 1600 ES/ 4000
J
J
36:57
Cone.
635
1140
587
647
652
1770
992
876
4510
2950
4510
2060
2060
2180
616
2740
445
462
494
3900
3930
3990
4110
4190
3920
7280
3910
3920
3990
4130
4260
4200
3700
3780
3860
7450
1490
3800
3660
3930
3720
170
173
78.3
/
Noise Fac
1659
1645
2062
2062
2062
2428
1542
2049
1718
6502
6502
4152
4152
4152
4152
2745
2745
2928
2008
2044
3310
2469
2469
2469
3222
2334
6798
10958
10958
13842
13842
13842
13842
11522
11522
3630
3310
10958
13842
11522
2044
6798
1417
2.5
2.5
2.5
2.5
2.5
2.5
1860 2.5
2.5
2.5
2.5
DL
.76
.01
55
63
84
12.
5.82
122
1.81
10.1
8.42
/"
02
66
87
33
73
10
36
105
3.66
6.75
6.30
5.68
5.89
8.25
7.94
15.6
15.3
25.7
22.1
23.6
25.3
25.8
31.5
8.35
3.78
6.36
14.4
23.2
27.1
3.18
Rec

/
97.5
98.2
99.8
103
105
98.1
91.0
97.8
98.1
99.9
103
107
105
92.4
94
96
93
93
94
91
98
93
/
/
0 Jtaalys
Date
-------
OPUSquan
on MM1
26-JUL-2008 11
18


checkcode: 5908
/





SS
37C1
-2,3,7,8-TCDD
1.86e+07


27
08
1.14
/ 1530


3.84
95.4

SS
13C-1,
2,3,4,7-PeCDD
3.87e+07
1,64
y
32
10
1.06 ,
/ 3870
3310
2.5
7.65
96 - 7
/
SS
13C-1,
2,3,4,6-PeCDF
6.23e+07
1,57
y
30
38
1.09 ~
3730
10958
2.5
16.1
93-2
/
SS
13C-1,2,
3,4,6,9-HxCDF
4.82e+07
0.53
y
36
07
0.95
3690
13842
2.5
14.5
92.3

SS
13C-1,2,3,
4,6,8,9-HpCDF
3.25e+07
0.46
y
39
34
0.95
3930
11522
2.5
17.2
98.3

SBS

2,4,6,8-TCDF
3.71e+07
0.78
y
22
12
1.17
1920
1718
2.5
1.81
-

Ay

1,3,6,8-TCDD
2.72e+07
0.79
y
23
12
1.09
2340
1659
2.5
2.76
_

Ay

1,2,3,9-TCDD
5.38e+06
0.78
y
26
58
1.09
462
1659
2.5
2.76
-

Ay

1,2,8,9-TCDD
3.86e+06
0.75
y
28
09
1.09
332
1659
2.5
2.76
-

Ay
1,
2,4,7,9-PeCDD
2.44e+07
1.58
y
30
07
1.00
2580
1645
2.5
4.01
-

Ay
1,
2,3,8,9-PeCDD
7.78e+06
1.58
y
33
09
1,00
822
1645
2.5
4.01
-

Ay
1,2,
4,6,7,9-HxCDD
8.74e+06
1.26
y
34
56
1.04
960
2062
2.5
4.67
-

Ay
1,2,3,
4,6,7,9-HpCDD
1.24e+07
1.04
y
39
25
0.98
1610
2428
2.5
6.12
-

Ay

1,3,6,8-TCDF
6,14e+07
0.78
y
21
:00
1.17
3170
1718
2.5
1.81
	

Ay

2,3,4,8-TCDF
5.88e+D7
0.75
y
26
06
1.17
3040
1718
2.5
1.81
-

Ay

1,2,8,9-TCDF
1.05e+07
0.83
y
28
19 /
1.17
541
1718
2.5
1.81
-

Ay
1,
3,4,6,8-PeCDF
5.38e+07
1.73
y
28
:1T
1.17
2780
1666
2.5
1.76
-

Ay
1,
2,3,8,9 PeCDF
6.79e+06
1.54
y
33
27
1.05
410
6502
2.5
9.24
_

Ay
1,2,
3,4,6,8-HxCDF
1.98e+07
1.27
y
34
.16
1.15
1430
4152
2.5
4.15
-

Tot
Total
Tetra Dioxins
1.75e+08
0.79
y
23
12
1.09
15000
1659
2.5
2.76


Tot
Total
Penta-Dioxins
1.20e+08
1.58
y
30
07
1.00
12700
1645
2.5
4.01
-

Tot
Total
liexa- Dioxins
7.05e+07
1.26
y
34
56
1.04
7750
2062
2.5
4 .67
-

Tot
Total
Hepta-Dioxins
2.61e+07
1.04
y
39
25
0.98
3380
2428
2.5
6.12
-

Tot
Total
Tetra-Furans
1.98e+09
0.78
y
21
00
1.17
103000
1718
2.5
1.81
_

Tot
Total
Penta-Furans
7.06e+08
1.56
y
29
53
1.05
42600
6502
2.5
9.24
-

Tot
Total Hexa-Furans
2.65e+08
1.27
y
34
16
1.15
18900
4152
2.5
4.15
-

Tot
Total
Hepta-Furans
5.54e+07
1.03
y
39
06
1.40
4720
2745
2.5
3.34
-

Tot

TCDD EMPC
1.75e+08
0.79
y
23
12
1.09
15000
1659
2.5
2.76
_

Tot

PeCDD EMPC
1.20e+08
1.58
y
30
07
1.00
12700
1645
2.5
4 .01
_

Tot

HxCDD EMPC
7,05e+07
1.26
y
34
56
1.04
7750
2062
2.5
4.67


Tot

HpCDD EMPC
2.61e+07
1.04
y
39
25
0.98
3380
2428
2.5
6.12


Tot

TCDF EMPC
1.98e+09
0.78
y
21
00
1.17
103000
1718
2.5
1.81
-

Tot

PeCDF EMPC
7.06e+08
1.56
y
29
53
1.05
42600
6502
2.5
9.24
-

Tot

HxCDF EMPC
2-65e+08
1.27
y
34
16
1.15
18900
4152
2.5
4.15
_

Tot

HpCDF EMPC
5.54e+07
1.03
y
39
06
1.40
4720
2745
2.5
3.34
-

AS
13C
-1,3,6,8-TCDD
4.32e+Q7
0.81
y
23
10
0.98
3860
2044
2.5
3.58
96.5

AS
13C
-1,3,6,8-TCDF
7.26e+07
0.79
y
20
58
1,09
3660
6798
2.5
7.68
91.5

DPE

HxCDPE
*


NotF»

*


_
_

DPE

HpCDPE
*


NotF»
-
it



-

DPE

OCDPE
*


NotF»
-
*


	
-

DPE

NCDPE
¦k


NotF»
-
*


_


DPE

DCDPE
*


NotF»
-
H


-


LMC
Fnl check mass
.


NotF»
_
*





LMC
Fn2 check mass
*"


NotF»
-
*


_
_

LMC
Fn3 check mass
*


NotF»
-
~


-
_

LMC
Fn4 check mass
it


NotF»
-
*


_


LMC
Fn5 check mass
*


NotF»







-------
OPUSquan on MM1
26
-JUL-2008
11
20








Totals
Results


Analytical Perspectives
[Form: TOT]



Totals
class: TCDD
EMPC


Function: 1 Run
#:
5


Checkcode: 59m
File
Name: 080723P2
Samgle
#
5 Sample text: PS464..6042 002 Run#
i
-ACD-M23-1
Air Tra»

Acquired: 23-JUL
-08 23:20:50 Processed; 24-JUL-08 13
:3f
: 55




Total
Cone.: 15030


Unnamed Cone
: 11263.663
Homolog
count: 17

RT

ml Resp
mod.
m2 Resp
mod. RA
Resp
Adj^Resp
S/N


Cone.
Name
23

1
.202e+07
n
1
522e> 07
n
0.79 2
.724e+07
2.724e+07
1
72e+03
y

2340
1,3,6,8-TCDD
23
35
5
.294e+06
n
6
743e+06
n
0.79 y 1
.204e+07
1.204e+07
7
74e+02
y

1030

24
of
2
.712e+06
n
3
326e+06
n
0.82 y 6
037e+06
6.037e+06
3
96e+02
y

518

24
55,
3
.483e+05
n
4
329e+05
n
0.80 # 1
812e+05
7.812e+05
5
68e+01
y

67.1

25
10
1
-080e+07
n
1
359e+07
n
0.79 y 2
439e+07
2.439e+07
1
41e+03
y

2090

25
2?
8
.194e+Q6
n
1
046e+07
n
0.78 f 1
866e+07
1.866e+07
1
34e+03
y

1600

25
3|
3
•624e+06
n
4
581e+06
n
0.79 5^ 8
205e+06
8.205e+06
5
94e+02
y

704

25
51
1
.763e+06
n
2
194e+06
n
0.80 y 3
957e+06
3.957e+06
3
04e+02
y

340

26
o3
4
.488e+06
n
5
747e+06
n
0.78 f 1
024e+07
1.024e+07
8
33e+02
y

878

26
25,
3
.142e+06
n
3
942e+06
n
0.80 y.7
084e+06
7.084e+06
4
91e+02
y

608

26
33
2
.083e+06
n
2
71Qe+06
n
0.77 £4
793e+06
4.793e+06
3
71e+02
y

411

26
49>
8
,380e+06
n
1
069e+07
ii
0.78 y 1
907e+07
1.907e+07
9
83e+02
y

1640

26
5ft
2
.362e+06
n
3
016e+06
n
0.78 f 5
378e+06
5.378e+06
4
20e+02
y

462
1,2,3,9-TCDD
27
0^
3
.220e+Q6
n
4
176e+06
n
0.77 f 7
396e+06
7.396e+06
6
01e+02
y

635
2,3,7,8-TCDD
27
2&
5
.425e+06
n
7
017e+06
n
0.77 f 1
244e+07
1.244e+07
1
08e+03
y

1070

27
3?
1
.561e+06
n
1
980e+0S
n
0.79 £ 3
541e+06
3.541e+06
2
78e+02
y

304

28
OS-
1
.653e+06
n
2
211e+06
n
o.75 yj
864e+06
3.864e+06
3
20e+02
y

332
1,2,8,9-TCDD
Totals
Results


Analytical Perspectives
[Form: TOT]



Totals
class: PeCDD EMPC


Function: 2 Run
#:
5


Checkcode: 5908 /
File
Name: 080723P2
Sample
#
5 Sample text: P9464_604S
_002 Run#
i-
-ACD-M23-1
Air Tra»

Acquired: 23 JUL
-08 23:20:50 Processed: 2t
-JUL-08 13
:3£
: 55




Total
Coric.: 12673


Unnamed Cone
: 8125.533

Homolog
count: 10


RT

ml Resp
mod.
m2 Resp
mod. RA
Resp
Adj_Resp
S/N


Cone.
Name
30
QZ
1
498e+07
n
9
466e+06
n
1.58 v 2
444e+07
2.444e+07
1.
12e+03
y

2580
1,2,4,7,9-PeCDD
30
40
2
353e+06
n
1
436e+06
n
1.64 y 3
789e+06
3,789e+06
2.
48e+02
y

400

31
1?
1
049e» 07
n
6
507e+06
n
1.61 p 1
700e+07
1.700e+07
1.
09e+03
y

1800

31
2?
5
947e+06
n
3
755e+06
n
1.58 & 9
702e+06
9,702e+06
6.
28e+02
y

1030

31
33>
7
664e+06
n
4
775e+06
n
1.61 V 1
244e+07
1.244e+07
8.
45e+02
y

1310

31
4SL
9
965e+06
n
6
285e+06
n
1.59 y 1
625e+07
1,625e+07
6.
93ei02
y

1720

32
12
6
967e+06
ii
4
335e+06
n
1.61 y 1
130e+07
1.130e+07
6.
89e+Q2
y

1190

32
4?
6
73 5e+06
n
4
079e+06
n
1.65 ? 1
081e+07
1.081e+07
7
28e+02
y

1140
l,2,3,7,a-PeCDD
32
48*
3
863e+06
n
2
557e+06
n
1.51 Y, 6
419e+06
6.419e+06
4.
10e+02
y

673

33
09*"
4
764e+06
n
3
017e+06
n
1.58 v 7
7 81e+06
7.781e+06
5.
22e+02
y

822
1,2,3,8,9-PeCDD
Totals
Results


Analytical Perspectives
(Form: TOTJ



Totals class: HxCDD EMFC


Function: 3 Run
# :
5


Checkcode: 5908
File
Name: 080723P2

Sample
#
5 Sample text: P9464 6042
_002 Run#
i-
ACD-M23-1
Air Tra»

Acquired: 22
-JUL-
08 23:20:50 Processed: 24
-JUL-08 13
: 38
: 55




Total Cone.: 7751.
3


Unnamed Cone.
: 4905.684

Homolog
count: 8

-------
OPUSquan on MM1
26
-J0L-2OO8
11
20









RT

ml Resp
mod.
m2 Resp mod.
RA
Resp
Ad j ..Resp
S/N

Cone.
Name
34
54,
4
.875e+06
n
3
.860e+06
y
1
,26 r
>8.735e+06
8.735e+06
5
,45e+02
y
960
1,2,4,6,7,9-HxCDD
35
35
7
.553e+06
n
6
103e+06
n
1
-24 v
1.366e+07
1.366e+07
8
68e+02
y
1500

35
5?
1
.190e+07
n
9
440e+06
n
1
.26 y
2.134e+07
2.134e+07
1
00e+03
y
2350

36
o2
1
.377e+0fi
n
1
182e+06
n
1
16 ^ 2.559e+06
2.559e+06
1
-33e+02
y
281

36
35»
2
.814e+06
n
2
355e+06
y
1
.19 f 5.169e+06
5.169e+06
3
24e+02
y
587
1,2,3,4,7,8-HxCDD
36
46i
3
,318e+06
n
2
628e+06
y
1
.26 £
5.945e+06
5.945e+06
3
62e+02
y
647
1,2,3,6,7,8-HxCDD
36
58,
3
¦904e+06
n
3
172e+06
n
1
.23 %
7.075e+06
7.075e+06
4
13e+02
y
778

37
04-
3
.312e+06
n
2
.739e+06
y
1
.21 y, 6 . 051e+06
6.051e+06
3
,43e+02
y
652
1,2,3,7,8,9-HxCDD
o
rr
Results


Analytical Perspectives
(Form: TOT]


Totals
llass: HpCDD EMPC



Function: 4 Run
# :
5

Checkcode: 5908 /
File
Name: 080723P2
Sample
#
5

Sanple text: P9464_6042_002 Run# I
-ACD-M23-1 Air Tra» '

Acquired: 23-JUL
-08 23:20:50
Processed: 24-JUL-08 13
: 3
3:55



Total
Zone.: 3381
.4



Unnamed Cone
: *

Homolog
count: 2


RT

ml Resp mod.
m2 Resp mod.
RA
Resp
Adj_Resp
S/N

Cone.
Name
39
25
6
340e+06
n
6
095e+06
n
1
04 -f
1.243e+07
1.243e+07
6
74e+02
y
1610
1,2,3,4,6,7,9 HpCDD
40
15-
7
041e+06
n
6
653e+06
xi
1
06 *
1.369e+07
1.369e+07
7
13e+02
y
1770
1,2,3,4,6,7,8-HpCDD
Totalis
Results


Analytical Perspectives
[Form: TOT]

Totals
-•lass: TCDF
EMPC



Function: 1 Run
# :
5

Checkcode: 5908 j
File
Name: 080723F2
Sanple
#:
5

Sample text: P9464_6042_0Q2 Run# I-
-ACD-M23-1 Air Tra» '

Acquired: 23-JUL
-08 23:20:50
Processed: 24-JUL-08 13
:38:55



Total Cone.: 102640



Unnamed Cone
: 89455.802
Homolog
count: 25

RT

ml Resp
mod.
m2 Resp
mod.
RA
Resp
Adj_Resp
S/N

Cone.
Name
21
CUL
2
691e+07
n
3
446e+07
y
0
78 *
6.137e+07
6.137e+07
3
90e+03
y
3170
1,3,6,8-TCDF
21
33
1
956e+07
a
2
485e+07
n
0
79 v
4,440e+07
4.440e+07
2
79e+03
y
2300

22
12**
1
628e+07
n
2
085e+07
y
0
78 y
3.713e+07
3.713e+07
2
13e+03
y
1920
2,4,6,8-TCDF
22
44-
1
314e+08
ri
1
672e+08
n
0
79 n
2.986e+08
2.986e+08
1
08e+04
y
15400

23
04
2
035e+07
n
2
622e+07
n
0
78 y
4.657e+07
4.657e+07
2
93e+03
y
2410

23
12"
5
577e+07
n
7
100e+07
n
0
79 ?
1.268e+08
1.268e+08
6
12e+03
y
6560

23
25
6
50Qe+Q5
n
7
824e+05
n
0
83 y
1.432e+06
1.432e+06
8
97e+01
y
74.1

23
38->
2
735e+07
n
3
503e+07
n
0
78 \
6.238e+07
6.238e+07
3
92e+03
y
3230

23
4^
2
175e+07
ri
2
757e+07
n
0
79 jr
4.932e+07
4.932e+07
3
10e+03
y
2550

23
58
3
202e+07
n
4
070e+07
n
0
79 y
7.272e+07
7.272e+07
4
61e+03
y
3760

24
21,
2
749e+07
n
3
522e+07
n
0
78
6.271e+07
6.271e+07
3
90e+03
y
3240

24
30
3
770e+07
n
4
824e+07
n
0
78 y
8.594e+07
8.594e+07
5
71e+03
y
4440

24
4(7*
4
443e+07
n
5
738e+07
n
0
77 y
1.018e+08
1.018e+08
7
22e+03
y
5260

24
46
7
498e+07
n
9
466e+07
n
0
79 y
1.696e+08
1.696e+08
8
80e+03
y
8770

25
1^
5
903e+07
n
7
503e+07
n
0
79 y
1.341e+08
1.341e+08
7
59e+03
y
6930

25
3X
3
529e+07
n
4
S09e+07
TL
0
78 y
8.037e+07
8.037e+07
5
82e+03
y
4160

25
45
3
385e+07
n
4
277e+07
11
0
79 y
7.662e+07
7.662e+07
4
87e+03
y
3960

25
Sfr
3
647e+07
n
4
468e+07
n
0
82 y
8.115e+07
8.115e+07
5
62e+03
y
4200

26
06>
2
519e+07
ri
3
3 65e+07
y
0
75 f
5.883e+07
5.883e+07
4
22e+03
y
3040
2,3,4,8-TCDF
26
13.
3
866e+07
n
4
846e+07
y
0
80 y
8.712e+07
8.712e+07
5
34e+03
y
4510
2,3,7,8-TCDF
26
3S.
9
161e+07
n
1
162e+08
a
0
79 ¥
2.078e+08
2,078e+08
1
50e+04
y
10700

26
5*
6
627e+06
n
8.
083e+06
n
0
82 jt
1.471e+07
1.471e+07
9
73e+02
y
761

2?
08-
5
242e+06
n
6.
461e+06
n
0
81 £
1.170e+07
1.170e+Q7
8
29e+02
y
605

-------
QPUSquan on MM1
26-JUL-2008 11:20
27:2? 5.005e+05 n
28:IS- 4.735e+06 n
Totals Results
5.896e+05 n 0.85 f1.090e+06 1.090e+06 6.09e+01 y	56.4
5.735e+06 y 0.83 x, 1,047e+07 1.047e+07 7.16e+02 y	541
Analytical Perspectives	[Form; TOT]
1,2,8,9-TCDF
Totals class: PeCDF EMPC
File Name; 080723P2 Sample ft; S
Acquired: 23-JUL-0B 23:20:50
Total Cone.: 42554
Function: 2 Run #: 5	Checkcode: 5908
Sample text: P9464_6042_002 Run# I-ACD-K23-1 Air Tra»
Processed: 24^jul-08 13:38:55
Unnamed Cone. : 34687.384	Homolog count: 16

RT
ml Resp
mod. mZ Resp
mod. RA

Resp
Adj_Resp
S/N

Cone.
Name
29
52.
6.502e+07
n
4.159e+07
y
1.56
ft
1.066e+08
1
066e+Q8
1.19e+03
y
6430


30
03
8.062e+07
n
5.147e+07
n
1,57
X
1.321e.08
1
3 21e» 08
1.43e+03
y
7970


30
09s
1.761e+07
n
1.108e+07
n
1.59
y
2-869e+07
2
869e+07
5.15e+02
y
1730


30
15-
8.850e+06
n
5.525e+06
n
1.60 ?
1.438e+07
1
438e+07
2.15e+Q2
y
868


30
30
1.232e+07
n
7.764e+06
n
1.59
X
2.009e+07
2
009e+07
2.36e+02
y
1210


30
3f
1.129e+07
n
6.564e+06
n
1.72
y
1.785e+07
1
785e+07
3.06e+02
y
1080


30
46.
4.317e+07
n
2.813e+07
n
1.53
f
7.130e+07
7
130e+Q7
7.76e+02
y
4300


30
59
1.002e+07
n
6.421e+06
n
1.56
&
1.645e+Q7
1
645e+07
2.68e+02
y
993


31
18-
2.828e+07
n
1.806e+07
y
1.57
y
4.634e+07
4
634e+07
7.4le+02
y
2950
1,2,
3,7,8-PeCDF
31
2a
4.500e+07
n
2.851e+07
n
1.58
y
7.351e+07
7
351e+07
7.71e+02
y
4440


31
39
4.710e+06
n
2.990e+06
n
1.58
f>
7.700e+06
7
700e+06
1.15e+02
y
465


32
OS
6.600e+06
n
4.238e+06
n
1.56
X.
1.084e+07
1
084e+07
1.87e+02
y
654


32
1»
4.268e+07
n
2.730e+07
n
1.56
x.
6.998e+07
6
998c 07
1.12e+03
y
4220


32
21
4.816e+Q7
n
3.040e+07
y
1.58
X
7.856e+07
7
856e+07
1.10e+03
y
4510
2,3,
4,7,8-PeCDF
32
41-
3 .204e+06
n
1.988e+06
n
1.61
It
5.193e+06
5
193e+06
8.21e+01
y
313


33
23
4.123e+06
n
2.670e+06
y
1.54
V
6,793e+06
6
793e+06
1.16e+02
y
410
1-2,
3,8,9-PeCDF
Totals
Results

Analytical
Perspectives

[Form: TOT]



Totals class: HxCDF EMPC
Pile Name: 080723P2 Sample
Function:
Sample text:
3 Run I: 5
P9464_6042_002 Run# I-ACD-
Checkcode: 5908
M23-1 Air Tra»
/
Acquired: 23-JUL-08 23:20:50 Processed: 24-JUL-08 13:38:55
Total Cone.: 18883	Unnamed Cone.: 10534.242	Homolog count: 13

RT
ml Resp
mod. m2 Resp
mod. RA
Resp
Adj_Resp
S/N

Cone.
Name
34
XL
1. l09e+07
n
8.725e+06
y
1.27
1.982e+07
1.982e+07
6.17e+02
y
1430
1,2,
3,4,6,8-HxCDF
34
28
4 .147e > 07
n
3.307e+07
n
1.25
y 7.454e+07
7.454e+07
2.29e+03
y
5380


34
42"
4 .687e+06
n
3.828e+06
n
1.22
y"8.515e+06
8.515e+06
2.41e+02
y
615


34
54"
6.573e+06
n
5.215e+06
n
1.26
* 1.179e+07
1.179e+07
3.56e+02
y
851


35
08
2.463e+06
n
2.0Q4e+06
n
1.23
X 4,467e+06
4.467e+06
1.37e+02
y
323


35
33
1.459e+07
n
1.161e+07
n
1.26
y 2.620e+07
2.620e+07
8.54e+02
y
1890


35
4»
1.570e+07
n
1.235e+07
y
1.27
y 2.805e+07
2.805e+07
8 -70e+02
y
2060
1,2,
3,4,7,8-HxCDF
35
4a
1.773e+07
n
1.423e+07
y
1.25
f 3.197e+07
3.197e+07
9.70e+02
y
2060
1,2,
3,6,7,8-HxCDF
35
58
3.132e+06
n
2.448e+06
n
1.28
^ 5.581e+06
5.581e+06
1.50e+02
y
403


36
0?
3.460e+06
n
2.749e+06
n
1.26
1? 6.210e+06
6.210e+06
1.86e+02
y
448


36
IS
4.843e+06
n
3.771e+06
n
1.28
1 8.614e+06
8.614e+06
2.55e+02
y
622


36
28-
1.796e+07
n
1.417e+07
y
1.27
y 3 .212e+07
3.212e+07
1.00e+03
y
2180
2,3,
4,6,7,8-HxCDF
37
29-
3.965e+06
n
3.173e+06
y
1.25
Y, 7,137e+06
7.137e+06
1.58e+02
y
616
1,2,
3.7,8,9-HxCDF
Totals
Results

Analytical
Perspectives
(Form: TOT J



Totals class: HpCDF EMPC
File Name: 080723P2 Sample #:
Function: 4 Run #: 5	Checkcode: 5908
Sample text: P9464_6042_002 Run# I-ACD-M23-1 Air Tra»
-------
OPUSquan on MM1 26-JUL-2008 11:20
Acquired: 23-JUL-08 23:20:50 Processed: 24-JUL-08 13:38:55
Total Cone.: 4723.1	Unnamed Cone.: 1542.526	Homolog count: 4

RT
ml Resp mod. m2 Resp mod. RA Resp
Adj_Resp
S/N

Cone.
Name
39
0*
1.722e+07 n
1.668e+07 y 1.03 x,3.391e+Q?
3.39ie+07
1.75e+03
y
2740
1,2,3,4,6,7,8-KpCDF
39
25,
4.874e+06 n
4.730e+06 n 1.03 s,9.604e+06
9.604e+06
4,96e+02
y
865

39
35"»
3,804e+06 n
3.712e+06 n 1.02 y,7.515e+06
7.51Se+06
3.82e+02
y
677

40
51-
2.199e> 06 n
2.162e+06 y 1.02 y~4.361e+QS
4. 3Gle+06
1.99e+02
y
445
1,2,3,4,7,8,9-HpCDF
-------
iFile: 0B0723P2 Acq':' 2S-JUL-2008 23:20:50 GC EI+ voltage Sir Autospec-ULtimaE
:Sample# 5 Text: P9464_6042_002 Run# I-ACD-M23-1 Mr Train Vial# 34 Pile Text; AP DBS
316.9824 S:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt; DF_CL4 8
100%,	20:45 „r
25:48 26:21 26:50 27:2Z 27:40
25:00
22: 4S
23:38
28:35
21:00	22:00	23:00	24:00
366.9792 S:5 F:2 PKD(5,5,3,100.00%,750,0,0.00%,F,F) Expt: DF_CL4-8
25:00
29:00
Time
26:00
27:00
28:00
32:56
32:31
31:22
1 33:03 33:18 33:30
33:51
100%
29:47 30:04
* 31:29
32:41
31:51
30:45 31:00
32:14
30:25
9:40 r
30:00	31:00
380,9760 S;5 F;3 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
32:00
34:53 35:09 35:24 35:40
10°*	343:1821 34:34_
80i
60.
40,
20.
36:1t 36:20
36 ; 39
33:00
I7 „ ftp
36:55 r	37:20 37:38
34:00 Time
37:57 ,c
T 3£
5E6
0E6
5E6
0E6
5E6
Time
4E6
5E6
7E6
8E6
8E5
35:00	36:00
430.9728 S:5 F:4 PKDi5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
100%,
80.
60.
40.
20.
39-02 39;22 _„ 	
38:56 r 39:15 ~l 39:27
39:47
~i 39:54
40:10 40:18
37:00
„ „ 41:08
40:32 40:43 40:53
41:16
41:
38:00
41:35
41:47 41:57_4,
.3.
1—1—i—!—n—j—1—r~i—i—1—I—1—1—1—1—p—I—1—i—p—1—1—I—1—1—1—1—i—I—1—i—1—?—i—I—i—1—1—i—1—I—1—f—1—i—t—I—1—\—1—1—1—j—i—1—1—1—1—I—1—1—1—1—1—r—1—i—1—i—1—j—1—1—1—\—1—1—1—i—1—p—1—
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:
-i—I—I—I—I—I—1—r
24 41:36
41:48 42:00 Time
454,9728 S:5 F;5 PKD(5,5,3,100,00%,750,0,0.00%»F,F) Expt: DF_CL4
100%. 42:11 42:19 42:27	42:44
80. ' "	' """
43:ll3:2T 43:32
43 : 56 . . __
n44:00
„„ „„ 44:27
44:20 r 44:37
44:53
42112 42 !24' ' ' 4*2 1 3*6 " ' ' 42 ' 48 ' ' ' 43 ! 00 ' ' ' 43 ! 12 ' ' ' 43 ' 24 * ' * 43 ! 36 ' ' ' 43 ! 48 ' ' ' 44 ! 00 ' ' ' 44:12 44^24
44:36
44:48 45:00 Time
-------
File: 0B0723P2 Acq: 23-JUL-2OO0 23:20
Sample# 5 Text: P9464_6042_002 Run# I-
319.8965 S:S BSOBI10000,15,-3.0) Expt:
ioos,
80,
60.
40.
20.
21:00	22:00
321.8936 S:5 BSUBQOOOO,15,-3.0) Expt:
1004,
80.
60,
40.
20.:
35 GC EI+ Voltage SIR Auto spec -UJ.tiir.aE
ACD-M23-1 Mr Traiii Vial# 34 File Text: AP DB5
DFCL4-8 Noise: 602
25: 09
A1.08E7
23 :12
26:01
23:35
A4.49E6
24:03
A5.29E6
A2.71E6
24: 55
A3 .48
26.50 / 27:28
A8 38E6/A5.43E6
27 :08
26:33 I
A2.08E«
23:00	24:00
DF_CL4-8 Noise: 482
23:12
A1.S2E7
24:04
A3.33E6
25:00
23:35
hb.74E6
A
25:09
A1.36E7
26:00
26:01
A5.75E6
27:00
28:09
A1.65E6
28100
24: 55
A4.33B5
_—, /—,
26:50
A1.07E7
27:08
26:33
A2.71E-
27:28
A7.02E6
28:09
A2.21E6
iV
28! 00
29:00
.2.356
L1.9E6
Ll. 4E6
l9 , 4E5
. 7E5
2 . 8E6
2 . 3E6
1.7E6
1.1E6
5.7E5
21:00
327.8850 S:5 BSUB(10000,15,
100%,
80.
60.
40.
20.
22: 00
-3.0) Expt:
23:00	24:00
DF_CL4-B Noise: 537
25:00
26:00
27:00
27:08
A1.86E7
26-00
I
27:00
27:06
A1.91E7
29:00
Time
4 .4E6
3 -5E6
2.6E6
1. 8E6
8.8E5
21:00	22:00
331.9368 S:5 BSUB(10000,15,-3.0) Expt:
23:00	24:00
D?_CL4~8 Noise: 765
25:00
28:00
23:10
A1.93E7
26:25
A2.08E7
"¦	'	TTT
29:00
Time
9E6
9E6
9E6
9E6
7E5
Time
21:00
333.9339 S:5 BSUBU0000,15,
10QS,
80,
60.
40,
22:00
-3.0) Expt:
23:00	24:00
DF_CL4-8 Noise: 595
23:10
A2.38E7
25:00
26:00
27:00
28:00
26:25 27:06
.4yE 1 ^2 35E7
" (
29:00
.5.8E6
L4.7E6
L3.5E6
.2.3E6
Ll.2E6
21:00
22:00
23:00
24:00
25:00
26:00
27 :00
28:00
29:00
Time
-------
File: 080723P2
Sample# 5 Text;
355.8546 S:5 F; \
100^
80,
60.
40.
20.
Acq: 23-JUL-2DDS 23:20:50 GC EI+ Voltage SIR Autospac-UltimaE
F9464_6042_002 Run# I-ACD-M23 1 Mr Train Vial# 34 File Text:
BSUB (10000,15,-3.0) Expt: DF..CL4-8 Noise; 1098
31-32
A7.66E6 31:48
A9.97E6
HP DB5
30:07
30:40
A2.35E6
32:12
A6.97E6
32:42
A6.74E6
2:47
. 86E6
33:09
A4.76E6
357,8517 S:5
100S,
80.
60j
40.
20.
30:00
F:2 BSUB(10000,15,
30:08
A9.47E6
-3.0) Expt:
30:40
A1.44E6
31:00
DF_CI,4- 8 Noise:
31:14
A6.51E6
32:00
33:00
1324
31:32
A4.77E6 3i;48
A6.2BE6
32:12
A4.34E6
32:42
A4.08E6
33:09
A3.02E6
. 56E6
_2
9E6
L2
3E6
Ll
7E6
.1
2E6
_5
8E5
34:00 Time
.1.8E6
l1.5E6
.1.1E6
L.7.4E5
13.7E5
30:00	31:00
367.8949 S:5 F:2 BSUBQOOOO,15,-3.0) Expt: DF_CL4-8 Noise: 793
100^
80.
60.
40i
20.
32:00
33:00
32:10
A2.41E7
32:41
A2.32E7
34:00 Time
.6. 8E6
.5.4E6
4.1E6
.2.7E6
1.4E6
30:00	31:00
369.8919 S:5 F:2 BSUB(10000,15,-3.0) Expt: BF_CL4-8 Noise: 499
1001
80i
60i
40i
20i
32:00
33:00
34:00 Time
32:10
32:41

A1.46E7
A1.45E7
4.1E6
A
A
i3.3E6


SFG


L1.6E6
/I
11
L8.2E5
30:00	31:00
366.9792 S:5 F:2 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-
32:00
33 ; 00
32:56
34:00 Time
33:03 33:18 33:30
32:31
4 31:29
1001
m 29:47 30:04
33:51
32:41
2.3E6
31:51
1.8E6
1.4E6
9.1E5
4.5E5
30:00
31: 00
32:00
33 :00
34:00 Time
-------
File: 080723P2 Acq: 23-JUL-2008 23:20:50 GC EI+ Voltage SIR AuLospec-UlcimaS
Sample# 5 Text: P9464_6042_002 Run# I-ACD-M23-1 Air Train Vial# 34 File Text; AP DB5
389.8156 S:5 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1144
looi,
80.
60.
40
20.
34:56
A4.88E6
35:00
391.8127 S:5 F:3 BSUB(10000,15,-3.0>
35:54
35:35
A7.55E6
36:01
38E6
36:58
A3.T2E6 A3.90E6
T
/
Expt: DF_CL4-8
1004
80.
60
40.
20.
36:00
Noise: 1240
35:53
35:35 A9.44E6
A6.10E6
34:55
A3.86E6
6:01
. 18E6
37*! 00
36:45 36:58
A2.63E6 A3.17E6
38:00
"T	a|"
37 :00
.2.6E6
.2 . 1E6
Ll.6E6
.1.1E6
.5. 3E5
Time
-2.1E6
Ll.7E6
Ll.2E6
L8.3E5
.4.1E5
35:00
401.8559 S:5 F:3 BSUB(10000,15,-3.01
100%,
80.
60.
40.
20j
Expt: DF_CL4-8
36:00
Noise; 1597
38:00
35:00
403.8530 S:5 F:3 BSUB(10000 ,15 , -3.0)
100%,
80.
60.
40.
20.
Expt: DF_CL4-8
36:00
Noise: 960
36:45
37:03
A2.02E7
37 :00
36:45 37-03
A1.61E7 A1.57E7
38:00
37 :00
37:02
Time
_5.?E6
L4.6E6
.3.4ES
.2.3EG
Ll-1E6
Time
_4.4E6
L3.5E6
L2.6E6
Ll.8E6
L8.8E5
380.9760 S:5 F:3 PKDIS,5
34:26
35: 00
3,100.00%,750.0,0.00%,F.F)
Expt:
36:00
DF_CL4-8
36:10
38:00
37 • 57
: 38	38:05
Time
38:30
37:20 37
36:55
7.5E6
6.0E6
4.5E6
3.0E6
1.5E6
35:00
36:00
37 :00
38:00
Time
-------
File; 080723P2Acq: 23-JUL-2008 23:20:50 GC EI+ Voltage SIR Autospec UltimaE
Sample# 5 Text: P9464_6042_002 Run# I-ACD-M23 1 Air Train Vial# 34 File Text: Ag^DB5
423.7767 S:5 F:4 BSUB (10000,15,-3 . 0) Expt: DF.. CL4-8 Noise: 912
39:24	40:16
100%	A6.34E6	A7.J4E6
80^
60i
40i
20j
38*48' ' 39 ! 00 ' 39112 39 = 24 39:36 39i48
\£>^J ^2J3££>X~L-
o-yz
-r	^
38:36
425.773? S:5 F:4 BSUB(10000,15,-3.0) Expt: DF CL4-8 Noise: 726
1001,
80.
60,
40,
20.
40:00 40:12 40:24 40:36
40:48
41:00 41:12 41:24 41:36
1.8E6
1.4E6
1.1E6
7.2E5
3.6E5
41:48 42:00 Time
39:25
A6.09E6
40:16
A6.65E6
1
7E6
.1
4E6
Li
0E6
L6
9E5
r3
5E5
48 39:00 39:12 39:24 39i36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00
38:36 38
435.8169 S:5 F
100^
80,
60^
40.
20.
4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1611
40:15
A1.B2E7
—r f i t i | i < i t r-j	r	i—i j ! "I" I i—i—i—i—|—r~i—i—r~t—|—t—i—r—f—i—p—i—i	t	—i—» fi~J I i I I—r-r—?—r-r—t—r""r""r"*r	t	)	i	¦ "v im r"'i"1 > i 'i—i—i—i—s—i—i—i—r-i—i—i—i" r i—i—i—
48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 4li48 42i00
:4 BSUB(10000,15, 3.0) Expt: DF_CL4-8 Noise: 1139
40:14
Time
2E6
416
5E6
7E6
4E5
Time
1E6
3E6
5E6
6E6
2E5
Time
38:36 38
437.8140 S:5 F
100S,
80.
60.
40.
20.
A1.52E7
38:36 38
430.9728 S:5 F
100^ 38:39
80. "
48 39:00 39:12 39^24 39i36 39^48 40^00 40^12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42^00
4 FKD(5, 5,3,100.00%,750,0,0.00%,F,F) Expt: DF..CL4-
38:56 r9:02 39?&2t 39:27
39:47
"1 39:54
4°a040i18 40j32 40:43 40^53 41:0^ 41:16 41:2^ 41:35 41:47 41:57
38T3i'~nr~*38T48*~r~'39 ' 0o' ' 39:12' ' 39! M ' 39:36' ' *39 5 48' ' Vo!do' ' 4b!l2' ' Yo!24' ' 40 hV ' 40 J 48* ' Yl!oO ' 4ill2 ' Vl:24 41136 41148 42i00 Time
-------
/
File: 080T2"Xp2 Scq: 2-i - JUL- 2006 23:20: 50 EI i Voltage Sir Autospec-Ul t imaB
Sample# 5 Text: F9464_6042_Q02 Run# I-ACD-M23-1 Mr Train Vial# 34 File Text: AP DBS
457.7377 S:5 F:5 BSUB(10000,IS,-3.0) Expt: DFCL4-8 Noise: 416
43:51
100%	A2.§3E6
80.
60.
40.
20.
42:12
459.7348 S:5 F:
100%,
80.
60.
40.
20.
42:24 42:36 42:48 43:00
BSUB(10000,15,-3.0} Expt: DF_CL4-
43:12 43:24
Noise: 501
i—i—i—i—r-
43:36
6.0E5
4.8E5
3.6E5
2. 4ES
1.2E5
43:48
43:51
A3.06E6
44:00
44:12
44:24
44:36
44:48
45:00 Time
-j—i—i—i—I—I—T
42:12
i i l i '
42:24
t ! j I I
44:12
_6
7E5
_5
4E5
_4
0E5
_2
7E5
_1
3E5
42:36 42:48
469.7780 S:5 F:5 BSUB(10000,15,-3.0) Expt;
100%
80.
60.
40.
20J
43:00
DF CL4-8
43:12 43:24
Hoise: 591
43:36
43:48
44:00
44:24 44:36
' 44!48'
'42:12" ' '42! 24' ' ' 42 ! 3*6 * ' '42 UV ' ' 43 ! 00 '
471.7750 S: 5 F : 5 BSUB ^ 1000 0,15, -3.0) Expt: DF__CL4 -
1001,
80,
60.
40
20,
43:12 43:24
Noise: 528
j—1—j—i—1—r~t—1—I—r—
43:36 43:48
43:50
A2.03E7
45:00 Time
4.2E6
i3-4E6
2 .5E6
1.7E6
8.5E5
44:00
44:12
44
1—'—f—{—f—f—]—r—i
:24 44:36
—<	T	1	1	1	J i J [ t i l
42:12 42:24
-1—1—j—1—¦
42:36
43:50
A2.36E7
"i—t—1——i—*—1—rr
44:48 45:00 Time
_4.9E6
l3.9E6
.2.9E6
-.1. 9E6
.9.7R5
42:48
43:00
43:12
43:24
43:36
43:26
43:17 1 43:32
454.9728 S:5 F:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
100% 42:11 42:19 40:27	42:44 42:58
80. '	^
60.
40.
20.
43:48 44:00
43: 56
•1 44:00
44:12
44
~—1—1—1—1—1—1—r-
:24 44:36
1—I—1—1—1—¦—•—r—r
44:48 45:00 Time
44:20
44:27
T 44:37
44:53
,4 , 1E6
l3,3E6
2.5E6
1.7E6
8.3E5
1 1 I J '
43:00
'43•36
42:12
42:24
42:36
42:48
43:12
43:24
43:48
44:00
' 44!12'
44:24 44:36
44:48
45:00 Time
-------
FiTe:080723F2Acq: 23-JUL-200B 73T20:5n GC EI+ Voltage SIR Autospec UltimaE
Sample# 5 Text: ?9464_6042 002 Run# I-ACD-M23-1 Mr Traill Vial# 34 File Text: AP DBS
303.9016 S:5 BSUB(10000,15,-3.0) Expt: DF^CL4-8 Noise: 3182
2.0E7
22:47
1.6E7
A1.31E8
25:15
A5.90E7 2g
r	A3.
24:46
A7.50E7
24:2
A2..7
1.2E7
23:12
AS.58E7
23:58
A3.20E7
B7E7
21:00
a2 69E7 21:33
A2.byE/
22:12
A1.63E7
A
26:51
4.1B6
28:20
A4.73E6
6.63E6
21:00	22:00
305.8987 S:5 BSUB(10000,15, 3.0) Expt
23:00	24:00
DF_CL4-8 Noise: 3859
25:00
26:00
27:00
28:00
29:00
315.9419 S:5
21:00
BSUB110000,15
22:00	23:00
-3.0) Expt: DF_CL4-8
Noise:
24:00
963
25:00
100S
20:58
A3.21E7
80_
ft
60_

40_

20i
fx

21:00
26:00
26:12
A2.95E7
27:00
28:00
29:00
Time
2.6E7
22:47
A1.67E8
2.1E7
24:46
A9.47E7
24:2
A3
r
25:15
A7.50E7
r
1. 6E7
23:12
26:12
A4,85E7
23:5
A?,10E7
21:00	,,
A3 45F.7 ^-1:3 J
A2.48E7
1.0E7
A4.07E7
22:12
A2.09E7
A
26:51
8.08E6
5.2E6
28:20
A5.74E6
Time
6.6E6
l5.2E6
3.9E6
2 .6E6
1.3E6
22:00
317.9389 S:5 BSUB<10000,15,-3.0) Expt
20:58
23:00	24:00
DF_CL4-8 Noise: 908
25:00
26:00
27:00
28:00
i	1	r~
29:00
21:00
22:00
23:00
24:00
25:00
26:00
27:00
28:00
29:00
Time
26:12
A3.68E7
100%
i '1 1
22:00
21:00	22:00	23:00	24:00
375.8364 S:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 481
25:00
26:00
27:00
28:00
29 : 00
26:20
9.1E3
7 . 3E3
28:10
5.4E3
21:14
1 21 :,0
22:06
r 22:35
3 -6E3
20:27
1.8E3
Time
Time
-------
File: 080723P2 Acq: 23-JUL-2008 23:20:50 GC EI+ Voltage SIR Autospec-Ult imaE
Sample# 5 Text: P9464_6042_002 Rub# I-ACD-M23-1 Mr Train Viall 34 File Text: AP DBS
339.8597 S:5 BSUB(10000,15,-3.0) PKDI5,5,3,0.10%,750.0,0.00%,F,F) Expt: DF_CL4-8 Noise: 433
1004,
90.
80.
70.
60j
50.
40.
30.
20.
10.
28:17
6.9E6
2S6
5E6
8E6
1E6
4E6
8E6
1E6
4E6
9E5
A3.41E7
29:00
28:17
A1.97E7
21:00
341.8568 S:5 BSUB(10000,15,
100*
90 J
8 0-1
7oJ
60|
50|
4 °1
3oJ
20|
loj
22:00	23:00	24:00
-3.0) Expt: DF_CL4-8 Noise: 531
25! 00
-t——»—--t	1	r"
2S:00
27:00
Time
21:00	22:00	23:00	24:00
316.9824 S:5 PKD(5,5.3,100.00%.750.0,0.00%,F,F) Expt: DF_CL4-8
25:00
26:00
27:00
29:00
Time
100* 20:09
23: 52
25:00 25:48 26:21 26:50 27;27 27:40
28:35
29 : 2Q_2 . 3E6
12.0E6
L1.8E6
2i:44 23:00
20:30 20:45
21:00
22:00
23:00
24:00
25:00
26:00
27:00
28:00
29:00
Time
-------
File: 080723P2 Acq: 23-JUL-20Q8 23:20:50 GC EI + Voltage SIR Aut ospec - U11 itnaE
Sample# S Text: F9464_6042_002 Run# T-ACD-M23-1 Air Train Vial# 34 File Text: AP DBS
339.859? S:5 F:2 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 9490
30:03
30:00
341.8568 S:5 F:2 BSUB(10000,15,-3.0)
29:54 Af:M
A4.16E7
32:21
A4227l7A4'82E7
29:54
lOOt
A6.50E7
31:12
A2.83E7 A4.50E7
30:45
A4.32E7
7 6E7
30:3
A1.13E7
30:59
A1.00B7
32:05
0 : IS
31:39
A6.60S
4.71ES
32:41
A3.20E6
		
33:27
A4.12E6
	
31:00
Expt: DF_CL4-8
32:00
33:00
Noise: 5004
32:13
A2 .73E7
31:12 31:29
A1.81E7 A2.85E7
30:44
A2.81E7
. 11E7
30:3
A6.57E6
30:59
A6.42E6
32 :05
31:39
2.99E6
A4.24E
32:41
A1.99E6
33:27
A2.67E6
,
351.9000 S:5
1001,
80.
60j
40
20,
30:00
F:2 BSUB(10000,15. -3.0)
31:00
Expt: DF_CL4-8
32:00
33:00
Noise: 2838
30:38
A3.81E7
31:11
A3.79E7
353.8970 S:5
100%,
80.
60.
40.
20.
30:00
F:2 BSUB(10000,15,-3.01
31:00
Expt: DF_CL4 - 8
32:00
33 :00
Noise: 2386
30:38
A2.42E7
31:11
A2.36E7
32:20
&2.49E7
30:00	31:00
409.7974 S:5 F:2 BSUB(10000,15, -3.0) Expt: DF_CL4-8 Noise: 530
32:00
33! 00
100%,
80.
60.
40.
20j
31:00
31:15
29:37
r
29:56 30:09
30:42
30:30 . H%30:50.
32:15 32:25
1.5E7
1.2E7
L0.8E6
5.9E6
12.9E6
34:00 Time
.9.3E6
L7.5E6
L5.6E6
L3 .7E6
11.9E6
34:00 Time
32:20
1.1E7
A3.93E7
A
L8.9E6

L6.7E6

L4 ,4E6
is. . ¦
L2.2E6
34:00 Time
. 256
. 8E6
. 3E6
. 9E6
,4E6
30:00
31:00
33:32 "I 33:51
33 :20
31
33:04
32:00
33:00
34:00 Time
3.9E4
3.1E4
2.3E4
,1.6E4
7 . 8E3
1:00 Time
-------
/
File: 080723P2 Acq: 23-JUL-2Q08 23:20:50 GC EI+ Voltage SIR AutOSpec-UltimaE
Sample# 5 Text: P9464_6042_002 Run# X ACD-M23-1 Air Train Vial# 34 File Text: AP DB5
373,8207
BSUBS10000,15, -
34:28
A4.15E7
Expt: DF_CL4-
Noise: 5569
/
35:40
36:28
35:49
A1.57E7
A1.80E7
A1.77E7
34:16
A1.11E7
34:54
A6.57E6
A.
35:08
A2.46E6
r
36:15
37:29
A3.96E6
35:59
84E6
35: 00
375.8178 S:S F:3 BSUB(10000,15,-3.0)
34:28
100*	A3.31E7
80 J;
60.":
40i
20i
36:00
Expt: DF_CL4-8 Noise: 7496
37:00
38: 00
34 :15
A8.73E6
A
34:43	•S4
3.83E6 A|«22E6
	A	A.,
35:40 35.49
M-23E7 A«4H7
35:08
A2.00E6
r
	;	
36:28
A1.42E7
36:15
A3.77E6
35:59
A2.45E6
36:00
Noise
35:48
36:28
36:07
A1.67E7
A1.88E7
A1.74E7
36:00
4336
Time
9 . 5E6
.7 . 6E6
5.7E6
3 . 8E6
.1.9E6
35:00
383.8639 S:5 F:3 BSUB(10000,15,-3.0)
100*
80.
60.
40.
20.
37:00
38:00
Expt: DF_CL4-8
38S.8610 S:5 F
100%
60i
60i
40i
20i
35:00
3 BSUB(10000,15,-3.0)
3?! 00
37:26
A1.45E7
38:00
Expt: DF_CL4
Noise:
35:40 35:48
A2.97E7 A3 . J9E7
~l
36:07	36:28
A3.15E7 A3.31E7
37:26
A2.70E7
Time
.5.2E6
l4 . 2E6
l3 .1E6
i.2-1E6
Ll-0E6
Time
.1. 0E7
8 . 0E6
6.0E6
4 . 0E6
2 . 0E6
35:00	36;00
445.7555 S:5 F:3 BSUBI10000,15,-3.01 Expt: DF_CL4-8 Noise: 533
35:46
37 loo
38:00
35:00
36:00
37:00
38:00
Time
1001
2.0E4
1.6E4
36:40
43
1.2E4
35:37
8.1E3
35
35:22 r
34:1Z 34:27
4.0E3
Time
-------
/
File: Q8Q723P2 Acq: 23-JUL-2008 23:20:50 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 5 Text: P9464_6042_002 Run# I-ACD-M23-1 Air Train Vial# 34 File Text: AP DBS
407.7818 S:5 F:4 BSUBUOOOO,15,-3 . 0) Expt: DF_CL4-8 Noise: 1277
39:06
100%
80i
60
40.
20,
/
39:25 39:35
A4.87E6 A3,80E6
A A
40:51
A2.20E6
I i1 i i i 1 I ' 1 1 r ' I ' ' ' ' ' I '	1	
39:24 39:36 39:48 40:00 40:12
0) Expt: DF_CL4 8 Noise: 1239
39:25 39:35
A4.73E6 A3.71E6
S.1E6
4 . 1E6
3 . 0E6
2 . 0E6
.1.0E6
38:36 38:48 39i00 39:12
409.7788 S:5 F:4 BSUB(10000,15,-3
39:05
100%	A1.67E7
80i
60.
40.
20.:
40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
4 ,8E6
3 . 9E6
2 . 9E6
1.9E6
9.6E5
40:51
A2.16E6
40 ' 24 ' 40 bY
40:48 41:00 41:12
38:36
417.8253 S;
1001
80j
60.
40j
20.
38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12
5 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1628
39:34
A1.02E7
38:36
419.8220 S:
100%,
80.
60.
40.
20.
39:04
38!48 ' 39:00 39512
5 F : 4 BSUBUOOOO, lb, -3
39:04
A2.40E7
40:50
A8.89E6
41:24 41:36 41:48 42:00 Time
3.1E6
2. 5E6
1.9E6
.1.3E6
6.3E5
39:24 39:36 39:48 40:00 40:12
0) Expt; DF_CL4-8 Noise: 3409
40:24 40:36
40:48 4i;00 41:12
38:36
479.7165 S
38:48 39:00 39:12
5 F: 4 BSUB(10000,15,-3
39:34
A2.23E7
39:24 39:36 39:48 40:00
0) Expt: DF_CL4-8 Noise: 466
40:50
A2.01E7
41: 24* ' 41'36 ' 41! 48* ' 42 J 00 Time
.7.0E6
.5.6E6
.4.2E6
.2 . 8E6
Ll.4E6
-rrn-f—t—r*r
40:12 40:24 40:36 40:48 41:00 41:12 41:24
41!36 ' 41!48 425 00 Time
40: 08
8.7E3
6.9E3
5.2E3
3 . 5E3
1.7E3
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24
4li36 41'4fi' ' 42 loo Time
-------
/
File; 080723P2 Acq: 23-JUL-2008 23:20:50 GC EI + Voltage SIR AutOSpec-UltimaE
Sample# 5 Text: P9464_6042_002 Run# I-ACD-M23-1 Air Train Vial* 34 File Text: AP DBS
441.7428 S:S F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 464
100%
BOi
60j
40^
20i
I	!	1	1	1—
43:48
44 :05
r i i~i i
44:24
3 . 5E5
2.8E5
2, 1E5
1.4E5
7.0E4
443.7398
1001.
80 J
60.
40.
20j
42:12 42:24 42:36 42:48 43:00
S:5 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8
43:12
Noise;
43:24
479
-i—i—1—i—p—
43:36
I- 
-------
	
¥-m

OPUSquan on MM1
26-JUL-2008 11:19
checkcode:
1613/8290 Sample Summary
Client ID:
Lafo ID;
Sample text:
Typ
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax2
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax2
ES
ES
ES
ES
ES
ES
ES
CS
CS
CS
CS
CS
NA
JS/RT
JS
JS/RT
Run# I-ACD-M23-2
P9464_6042_003
P9464_6042_003 Run#
Name
2,3,7,8-TCDD
1,2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2.3.6.7.8-HxCDD
1.2.3.7.8.9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
OCDD-a
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2.3.4.6.7.8-HxCDF
1.2.3.7.8.9-HxCDF
1.2.3.4.6.7.8-HpCDF
1.2.3.4.7.8.9-HpCDF
OCDF
OCDF-a
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
13C-1,2,3,6,7,8-HxCDD
13C-1,2,3,7,8,9-HxGDD
13C-1,2,3,4,6,7,8-HpCDD
13C-OCDD
8-PeCDF
8-PeCDF
8-HxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8-HpCDF
9-HpCDF
13C-OCDF
ES
13C-2,3

ES
13C-1
2,3
7
ES
13C-2
3,4
7
ES
13C-1,2
3,4
7
ES
13C-1,2
3,6
7
ES
13C-2,3
4,6
7
ES
13C-1,2
3,7
8
ES
13C-1,2,3
4,6
7
ES
13C-1,2,3
4,7
8
ES



37C1-2,3,7,8-TCDD
13C-1,2,3.
13C-1,2,3.
13C-1,2,3,4.
13C-1,2,3,4,6.
6,9
7-PeCDD
6-PeCDF
HxCDF
9-HpCDF
n/a
Analytical Perspectives
Filename: 080723P2
GC column ID: db 5
I-ACD-M23-2 Air Train
Cal
tds
13C-1,2,3,4-TCDD
13C-1,2,3,4-TCDF
13C-1,2,3,4,6,7-HxCDD
Resp
4.07e+06
9.88e+06
6.13e+06
8.36e+06
8.34e+06
4.38e+Q7
1.09e+08
6.63e+06
88e+07
43e+07
88e+07
91e+07
30e+07
89e+07
76e+06
35e+07
64e+06
97e+06
88e+05
38e+07
92e+07
59et07
90e+07
88e+07
50e+07
74e+Q7
19e+07
85e+07
94e+07
63 ©+07
32e+07
99e+07
33e+07
75e+07
35e+07
Ble+07
1.44e+07
2.94e+07
4.89e+0?
3.76e+07
2.59e+07
3.61e+07
5.84e+07
1.41e+07
RA
0,80
1.58
1,28
1.24
1.24
1.05
0.91
2.55
0.76
1.56
1.59
1
27
24
28
26
03
04
89
10 n
0.79 y
1.56 y
1.59 y
0.53 y
0.53 y
0.52 y
0.53 y
0.44 y
0.45 y
0.89 y
1.66 y
1.56 y
0.53 y
0.45 y
0.83 y
0.79 y
1.25 y
27
32
36
36
37
40
43
43
27
32
30
36
39
RT
OS'/ 1.09
42' 1.00
39/ 1.10
46/ 1.00
04 / 1.03
16/* 0.98
51/ 1.08
50 0.07
13/^1.17
12x 1.0
2l/ 1.09'
40/* 1,20
49/" 1.13
29-^ 1.17
29' 1.12
OS""" 1.43
5]/\ 1.35
06/ 0.94
RRF
27:06
0.96
0.84
0.98
0.91
0.68
08
10
38
06
34
NotF»
0.93
0.86
0.881
1.25
1.46
1.36
1.
1.04
0.85
1.01
1.09
0.89
0.93
1.39
0.99
1.36
26
24
36
24
44
56
[Form; DF]
6 Vial: 35
JS (split adj.): 4000
Acq: 24-JUL-0|^00:ll:35
Wt/Vol: 1.000
CS/SS: 1600 ESj^OOO
J
Cone.
440
1350
863
1150
1120
7110
21400
20700
2570
1960
3640
1760
1880
2470
727
3400
709
1390
1390
3920
3850
4020
4060
4180
3890
7750
1460
3650
3580
3820
3700
135
139
62.8
Noise Fac
2095
1390
1778
1778
1778
3115
2316
2442
1666
6268
6268
5518
5518
5518
5518
2597
2597
2174
3201
3124
5200
3008
3008
3008
4398
2912
3113
11817
11817
11200
11200
11200
11200
11046
11046
2178
5200
11817
11200
11046
3124
3113
1972
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2552 2.5
2.5
2.5
2.5
DL
.50
.19 /
.74
Rec
5.26
10.1
9.96
166
2.18 j
11.5 /
10.5
6.23
6.02
6.48
8.76
3.36
4.59
7.87
212
7.07
97.9
13.4
96.2
9.61
100
8.66
101
8.99
105
14 .1
97.4
12.4
96.9
4.95
95.6
20.3
96 .6
19.8
96.2
26.1
103
22.4
105
24.0
104
25.6
92.5
31.0
93.6
37.8
97.8
6.27
96.3
5.26
91.1
12.6
91.2
18.7
89.6
23.5
95.6
32.5
92.4
5.46
*
/
/
1
AnalysfO'
Bat<
-------
OPUSquan
on MM. 26-JUL-2008 11
: 19



checkcode: 0198
/





ss
37C1-2,3,7,8-TCDD
1.44e+07



27
08
1.14
/ 1490


5.46
93.1

ss
13G-1,2,3,4,7-PeCDD
2 -94e+07
1
.66
y
32
10
1.06 J
' 3790
5200
2.5
14.8
94.8
y
ss
13C-1,2,3,4,6-PeCDF
4.89e+07
1
56
y
30
38
1.09
3710
11817
2.5
20.3
92.7
/
ss
13C-1,2,3,4,6,9-HxCDF
3. 76e+07
0
53
y
36
06
0.95
3650
11200
2.5
14.5
91.2

ss
13C-1,2,3,4,6,8,9 HpCDF
2.59e+07
0
45
y
39
34
0.95
3950
11046
2.5
21.4
98.7

SBS
2,4,6,8-TCDF
2,32e+07
0
78
y
22
12
1.17
1530
1666
2.5
2.18
-

Ay
1,3,6,8-TCDD
2.48e+07
0
79
y
23
12
1.09
2680
2095
2.5
4.50
_

Ay
1,2,3,9-TCDD
2.97e+06
0
78
y
26
57
1.09
321
2095
2.5
4.50
_

Ay
1,2,8,9-TCDD
2.13e+06
0
83
y
28
09
1.09
230
2095
2.5
4.50
-

Ay
1,2,4,7,9-PeCDD
2.69e+07
1
58
y
30
07
1.00
3670
1390
2.5
4.19
-

Ay
1,2,3,8,9-PeCDD
6.51e+06
1
58
y
33
09
1.00
888
1390
2.5
4.19
-

Ay
1,2,4,6,7,9-HxCDD
1.62e+07
1
25
y
34
56
1.04
2220
1778
2.5
4.96
	

Ay
1,2,3,4,6,7,9-HpCDD
5.03e+07
1
04
y
39
24
0.98
8180
3115
2.5
10.1
-

Ay
1,3,6,8-TCDF
2.77e+07
0
78
y
21
00
1,17
1830
1666
2.5
2.18
-

Ay
2,3,4,8-TCDF
2.49e+07
0
84
y
26
05
1.17
1650
1666
2.5
2.18
-

Ay
1,2,8,9-TCDF
5.67e+06
0
79
y
28
19 ~
1.17
375
1666
2.5
2.18
_

Ay
1,3,4,6,8-PeCDF
2.94e+07
1
71
y
28
16^
1.17
1940
3082
2.5
4.03
-

Ay
1,2,3,8,9-PeCDF
4.69e+06
1
59
y
33
27
1.05
363
6268
2.5
11.0
-

Ay
1,2,3,4,6,8-HxCDF
1.53e+07
1
26
y
34
16
1.15
1390
5518
2.5
6.78


Tot
Total Tetra-Dioxins
1,24e+08
0
79
y
23
12
1.09
13400
2095
2.5
4.50
_

Tot
Total Penta-Dioxins
1.17e+08
1
58
y
30
07
1.00
16000
1390
2.5
4.19
_

Tot
Total Hexa-Dioxiris
1.01s+08
1
25
y
34
56
1.04
13900
1778
2.5
4.96
-

Tot
Total Hepta-Dioxins
9.4 0e+07
1
04
y
39
24
0.98
15300
3115
2.5
10.1


Tot
Total Tetra-Furans
8.41e+08
0
78
y
21
00
1.17
55600
1666
2.5
2.18
-

Tot
Total Penta-Furans
4.03e+08
1
58
y
29
53
1.05
31200
6268
2.5
11.0
_

Tot
Total Hexa-Furans
2.03e+08
1
26
y
34
16
1.15
18200
5518
2.5
6.78
-

Tot
Total Hepta-Furaxis
6.18e+07
1
03
y
39
05
1.40
6660
2597
2.5
3.91
-

Tot
TCDD EMPC
1.24e+08
0
79
Y
23
12
1.09
13400
2095
2.5
4 .50
_

Tot
PeCDD EMPC
1.l?e+08
1
58
y
30
07
1.00
16000
1390
2.5
4.19
-

Tot
HxCDD EMPC
1.01e+08
1
25
y
34
56
1.04
13900
1778
2.5
4.96
-

Tot
HpCDD EMPC
9.40e+07
1
04
y
39
24
0.98
15300
3115
2,5
10.1
_

Tot
TCDF EMPC
8.42e+08
0
78
y
21
00
1.17
55700
1666
2.5
2.18
-

Tot
PeCDF EMPC
4.G3e+08
1
58
y
29
53
1.05
31200
6268
2.5
11.0
	

Tot
HxCDF EMPC
2,03e+08
1
26
y
34
16
1.15
18200
5518
2.5
6.78
-

Tot
HpCDF EMPC
6.18e+07
1
03
y
39
05
1.40
6660
2597
2.5
3 .91
-

AS
13C-1,3,6,8-TCDD
3.40e+07
0
83
y
23
10
0.98
3850
3124
2.5
6.91
96.2 ^

AS
13C-1,3,6,8-TCDF
5.77e+07
0
80
y
20
58
1.09
3640
3113
2.5
4.23
90.9

DPE
HxCDPE
*



NotF»
_
*





DPE
HpCDPE
-£•



NotF»

*


-
_

DPE
OCDPE
*



NotF»
-
*


-
-

DPE
NCDPE
*



NotF»
-
¦k


-
_

DPE
DCDPE
*



NotF»
"
*


-
_

LMC
Fnl check mass
*



NotF»
_
*





LMC
Fri2 check mass
*



NotF»
-
*


_
_

LMC
Fn3 check mass
*



NotF»
-
*


_
_

LMC
Fri4 check mass
~



NotF»
-
*


-


LMC
FrtS check mass
*



NotF»







-------
OPUSquan on MM1
26-
JUL 2008 11
20







Totals
Results


Analytical Perspectives
[Form: TOT]



Totals class: TCDD
EMPC


Function: 1 Run i
h 6


Checkcode: 0498
File
Name: 080723P2
Sartple
#
6
Sample text: P9464_6042_003 Run#
i
-ACD-M23-2
Air Tra»/

Acquired: 24-JUL
-08 00:11:35
Processed: 2'
-JUL-08 13
38:56




Total Cone.: 13394



Unnamed Cone.
: 9720.S41
Homolog
count: 17


RT
ml Resp
tnod.
m2 Resp
mod.
RA Resp
Adj_Resp
S/N


Cone.
Name
23
1^
1.097e+07
n
1
382e+07
n
0
79 y, 2.480e+07
2.480e+07
1.26e+03
y

2680
1,3,6,8-TCDD
23
35
4.544e+06
n
5
722e+06
n
0
79 ^ 1.027e+0?
1.027e+07
5.35e+02
y

1110

24
04*
2,031e+06
n
2
616e+Q6
n
0
78 y 4.647e+06
4.647e+Q6
2.56e+0'2
y

503

24
54i
2.138e+05
n
2
767e+05
n
0
77 J 4.905ct 05
4.905e+05
2.98e+01
y

53.0

25
10.
6.813e+06
n
8
479e+06
a
0
80 r> 1.529e+07
1.529e+07
7.25e+02
y

1650

25
22
6.402e+06
n
8
245e+06
n
0
78 y 1.465e+07
1.46Se+07
8.20e+02
y

1580

25
35
2.624e+06
n
3
310e+06
n
0
79 y 5.934e+06
5.934e+06
3.40e+02
y

642

25
sf
l.llle+06
n
1
426e+06
n
0
78 ? 2.537e+06
2.537e+06
1.58e+02
y

274

26
03.
3.310e+06
n
4
158e+06
n
0
80 y 7.467e+06
7,467e+06
4.49e+02
y

808

26
24
1.876e+06
n
2
397e+06
n
0
78 % 4.274e+06
4.274e+06
2.29e+02
y

462

26
3T
1.142e+06
n
1
426e+06
n
0
80 ^ 2.569e+06
2.569a+06
1.57e+02
y

278

26
43,
5.609e+06
n
7
087e+06
n
0
79 y 1.270e+07
1.270e+07
5.36e+02
y

1370

26
57
1.304e+06
n
1
661e+06
n
0
78 y 2.965e+06
2.965e+06
1.89e+02
y

321
1,2,3,9-TCDD
27
OS1
1.808e+06
n
2
265e+06
n
0
80^ 4. 072e+06
A.072e+06
2 -54e+02
y

440
2,3,7,8-TCDD
27
28"
3.156e+06
n
3
910e+06
n
0
81>; 7.065e+06
7.065e+06
4.46e+02
y

764

27
3T
9.233e+05
n
1
071e+Q6
n
0
86 y 1.994e+06
1.994e+06
1.18et 02
y

216

28
oa
9.647e+05
n
1
166e+06
n
0
83 it2.131c»06
2.131e+06
1.44e+02
y

230
1,2,8,9-TCDD
Totals
Results


Analytical Perspectives
[Form: TOT]



Totals class: PeCDD EMPC


Function: 2 Run i
: 6


Checkcode: 0198 /
Pile
Name: 080723P2
Sample
i
6
Sample text: F9464_6042_003 Run#
i-
-ACD-M23-2
Air Tra»

Acquired: 24-JUL
-08 00:11:35
Processed: 24
-JUL-08 13
38:56




Total Cone,: 15989



Unnamed Cone
: 10086.527 Homolog
count: 10


RT
ml Resp
mod.
m2 Resp
mod.
RA Resp
Adj_Resp
S/N


Cone.
Name
30
cm
1.647e+07
n
1
040e+07
n
1
58 "ji 2 . 688e+07
2.688e+07
1.42e+03
y

3670
1,2,4,7,9-PeCDD
30
4%
2.304e+06
n
1
.431e+06
n
1
61 x 3 .735e+06
3.735e+06
2.94e+02
y

510

31
14
1.l86e+07
n
7
539e+06
n
1
57 y 1. 940e+07
1.940e+Q7
1.54e+03
y

2650

31
20
5.891e+06
n
3
.673e+06
n
1
60 y 9.564e+06
9.564e+06
7.47e+02
y

1300

31
32.
8.OlOe+06
n
4
.930e+06
n
1
62 r l-294e+07
1.2 9 4e+ 07
9.69e+02
y

1770

31
49,
8.620e+06
n
5
392e+06
n
1
60 y 1.401e+07
1.401e+07
7.31e+02
y

1910

32
12
5.519e+06
n
3
466e+06
n
1
59 x, 8 • 985e+06
8.985e+06
7.12e+02
y

1230

32
42""
6.047e+06
n
3
829e+06
n
1
58 ^ 9.876e+06
9.87 6e+ 06
8.15e+02
y

1350
1,2,3,7,8-PeCDD
32
48^
3.275e+06
n
2
014e+06
n
1
63 ^ 5.288e+06
5.288e+06
4,Q2e+02
y

722

33
09^
3.989e+06
n
2
521e+06
n
1
58 jk 6 . 510e+06
6.510e+06
4.77e+02
y

888
1,2,3,8,9-PeCDD
Totals
Results


Analytical Perspectives
[Form: TOT]



Totals class: HxCDD EMPC


Function: 3 Run i
: 6


Checkcode: 0198
File
Name: 080723P2

Sample
#
6
Sample text: P9464_6042_003 Run#
i-
-ACD-M23-2
Air Tra»

Acquired: 24-JUL
-08 00:11:35
Processed: 24
-JUL-08 13
38:56




Total Cone.: 13897




Unnamed Cone.
: 8537.818
Homolog
count: 8

-------
OPUSquan on MM1
26
-JTJL-2008
11
20










RT
ml Resp
mod. m2 Resp mod.
RA
Resp
Adj_Resp
S/N


Conc.
Name
34

9 -Q01e+06
n
7.179e+06
y
1
.25
y1,618e+07
1
618e+07
1.17e+03
y

2220
1,2,4,6,7,9-HxCDD
35
35
9.854e+06
n
7.865e+06
n
1
.25
v 1.772e+07
1
772e+07
1.29e+03
y

2440

35
53"
1.811e+07
n
1.453e+07
il
1
.25
y 3.264e+07
3
264e+07
1.81e+03
y

4490

36
02*
1.937e+06
n
1.556e+06
n
1
.24
y 3.492e+06
3
492e+06
2.06e+02
y

480

36
3i
3.437e+06
n
2.694e+06
y
1
.28
¥ 6.131e+06
6
131e+06
4.56e+02
y

863
1,2,3,4,7,8-HxCDD
3fi
46,
4.623e+06
n
3.739e+06
y
1
.24
•f 8.362e+06
8
362e+06
6.24e+02
y

1150
1,2,3,6,7,8-HxCDD
36
57*
4.524e+06
n
3.715e+06
n
1
.22
f 8.239e+06
8
239e+06
5.8 9e+ 02
y

1130

37
04-
4.615e+06
n
3.722e+06
y
1
.24
y' 8.338e+06
8
338e+06
5.58e+02
y

1120
1,2,3,7,8,9-HxCDD
Totals
Results

Analytical
Perspectives

[Form: TOT]



Totals class: HpCDD EMPC



Function
4 Run
#: 6


Checkcode: 0198
File
Name: 080723P2 Sample
#
6

Sample text
P9464_6042_003 Run#
i-
ACD M23-2 Air Tra»

Acquired: 24-JUL-08 00:11:35
Processed: 24-JUL-08 13
: 38:56




Total Cone.: 1528
9


Unnamed Cone

*
Homolog
count: 2


RT
ml Resp mod. rti2 Resp mod.
HA
Resp
Adj Resp
S/N


Cone.
Name
39
2f
2.567e+07
n
2.462e+07
in
1
04
5» 5.029e+07
5
029e+07
2.22e+03
y

8180
1,2,3,4,6,7,9-HpCDD
40
IS—
2.246e+07
n
2.130e+07
n
1
05
y»4.376e+07
4
376e+07
l.80e+03
y

7110
1,2,3,4,6,7,8-HpCDD
Totals
Results

Analytical
Perspectives

[Form: TOT]



Totals class: TCDF
EMPC



Function
1 Run
#: 6


Checkcode: 0198 /
File
Name: 080723P2 Sainple
#
6

Sample text
F9464_6042_003 Run#
i-
-ACD-M23-2 Air Tra» /

Acquired: 24-JUL-08 00:11:35
Processed: 24-JUL-08 13
:38:56




Total Cone.: 55663


Unnamed Cone

47709.514 Homolog
count: 26

RT
ml Resp
mod. m2 Resp
mod.
RA
Resp
Adj_Resp
S/N


Cone.
Name
21
m
1.217e+07
n
1.551e+07
y
0
78
j 2.768e+07
2
768e+07
1.87e+03
y

1830
1,3,6,8-TCDF
21

8.147e+06
n
1.033e+07
n
0
79
y 1.847e+07
1
847e+07
1.16e+03
y

1220

22
12
1.013e+07
n
1.304e+07
y
0
78
y 2.317e+07
2
317e+07
1.37e+03
y

1530
2,4,6,8-TCDF
22
44*
4.789e+07
n
6.082e+07
n
0
79-y 1.087e+08
1
087e+08
3.97e+03
y

7190

23
04
7.835e+06
n
1,008e+07
n
0
78
y 1.791e+07
1
791e+07
1.18e+03
y

1180

23
12»
2.161e+07
n
2.746e+07
n
0
79
"y 4.907e+07
4
907e+07
2.49e+03
y

3250

23
25
4.343e+05
ri
5.17Se+05
n
0
84
yi 9.519e+05
9
519e+05
4.88e+01
y

63.0

23
if
1.188e+07
n
1.475e+07
n
0
81
y 2.664e+07
2
664e+07
1.75e+03
y

1760

23
46,
7.571e+06
n
9.896e+06
n
0
77
f 1.747e+07
1
74 7e+07
1.14e+03
y

1160

23
5?
1.1lls+07
n
1.427e+07
n
0
78
^ 2.538e+07
2
538e+07
1.69e+03
y

1680

24
2f>
1.104e+07
n
1.396e+07
n
0
79
y 2.500e+07
2
500e+07
1.56e+03
y

1650

24
3d
1 -899e+07
n
2.428e+07
n
0
78
y 4.327e+07
4
327e+07
2.98e+03
y

2860

24
40
2 .470e+07
n
3.169e+07
n
0
78
y 5.63 8e•C7
5
638e+07
3,78e+03
y

3730

24
4 *f
2.796e+07
n
3.540e+07
n
0
79
V 6.336e+07
6
336e+07
3.91e+03
y

4190

25
15-,
2.031ei07
n
2.517e+07
n
0
81
y 4.548e+07
4
548e+07
3.15e+03
y

3010

25
21
2.700e+06
n
4.023e+06
n
0
67
Y 6¦723e+06
6
723e+06
5.46e+02
y

445

25
33»
1.416e+07
n
1.773e+07
n
0
80
y 3.189e+07
3
189e+07
2.34e+03
y

2110

25
4».
1.5246+07
n
1-932e+07
n
0
79
y 3.456e+07
3
456e+07
2.24e+03
y

2290

25
58
1,754e+07
n
2,237e+07
n
0
78
y 3.991e+07
3
991e+07
2,93e+Q3
y

2640

26
0?
1.142e+07
n
1.352e+07
y
0
84
9 2.493e+07
2
493e+07
1.99e+03
y

1650
2,3,4,8-TCDF
26
15*
1.676e+07
n
2.204e+07
y
0
76
+ 3.881e+07
3
881e+07
2.94e+03
y

2570
2,3,7,8-TCDF
26
38*
4.273e+07
n
5.383e+07
n
0
79
y 9.655e+07
9
655e+07
7.22e» 33
y

6390

26
5V.
3.293e+06
n
4.080e+06
ii
0
81
y 7.373e+06
7
373e+06
4.76e+02
y

488

-------
OPUSquan on MM1
26-JUL-2008 11:20
0.81'^'5.766e+06 5.766e+06
1-04 im£.298e+05 4.592e+05
27:08^ 2.581e+06 n
27:23, 2.703e+05 n
28:19_ 2.493e+06 n
Totals Results
3.185e+06 n 0.81 *5" 5.766e+06 5.766e+06	4.00e+02 y	381
2.594e+05 n 1.04 im£.298e+05 4.592e+05	3.08e+01 y	30.4
3.174e+06 y 0.79 /5.667e+06 5.667e+06	3.78e+02 y	375 1,
Analytical Perspectives	[Form: TOT]
2,8,9-TCDF
Totals class: PeCDF EMPC
File Name; 080723P2 Sample #:
Function: 2 Run #: 6	Checkcode: 0198
Sample text: P94646042303 Run# I-ACD-M23-2 Air Tra»
X
Acquired: 24-JUL-08 00:11:35 Processed: 24-JUL-08 13:38:56
Total Cone.: 31188	Unnamed Cone.: 25226.244	Homolog count: 16

RT

ml Resp
mod.
m2 Resp
mod. RA


Resp
Adj_Resp
S/N

Cone.
29
5J.
3
384e+07
n
2
141e+07
y
1.58
4*5
525e+07
5
525e+07
6
57e+02
y
4280
30
02
3
946e+07
n
2
408e+07
n
1.64
y
6
354e+07
6
354e+07
7
07e+02
y
4930
30
09"
8
589e+06
n
6
359e+06
n
1.35
*¦*
y
1
495e+07
1
495e+07
2
85e+02
y
1160
30
15-,
5
204e+06
n
3
342e+06
n
1.56
»
8
546e+06
8
546e+06
1
31e+02
y
663
30
30
8
051e+06
n
5
043e+06
n
1.60
y
1
309e+07
1
309e+07
1
65e+02
y
1020
30
39-
5
482e+06
n
3
498e+06
n
1.57
7
8
979e+06
8
979e+06
1
61e+02
y
696
30
46
2
970e+Q7
n
1
867e+07
n
1.59
y?
4
837e+07
4
837e+07
5
75e+Q2
y
3750
30
59""
5
621e+06
n
3
661e+06
n
1.54
&
9
282e+06
9
282e+Q6
1
57e+02
y
720
31
13,
1
482e+07
n
9
470e+06
y
1.56
y
2
429e+07
2
429e+07
3
88e+02
y
1960
31
29
2
431e+07
n
1
560e+07
n
1.56

3
991e+07
3
991e+Q7
4
57e+02
y
3090
31
39*
3
061e+06
n
1
907e+06
n
1.61
*
4
968e+06
4
968e+06
7
73e+01
y
385
32
OS"
4
717e+06
n
2
897e+06
n
1.63
x.
7
614e+06
7
614e+06
1
29e+02
y
590
32
13'
2
885e+07
n
1
847e+07
n
1.56
y.
4
732e+07
4
732e+07
7
88e+02
y
3670
32
21>
2
995e+07
n
1
883e+07
y
1.59
X,
4
879e+07
4
879e+07
7
35e+02
y
3640
32
4ll
2
183e+06
n
1
377e+06
n
1.59
X.
3
560e+06
3
560e+06
5
70e+01
¥
276
33
21,
2
879e+06
n
1
809e+Q6
y
1.59
W 4
688e+06
4
688e+06
8
17e+01
y
363
Totals Results


Analytical
Perspectives

[Form: TOT]

Totals class: HxCDF EMPC
File Name: 080723P2 Sample #:
Function:
Sample text:
3 Run #: 6
P9464_6042_003 Run# I-ACD-
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,8,9-PeCDF
Checkcode: 0198
M23-2 Air Tra»
/
Acquired: 24-JUL-08 00:11:35 Processed: 24-JUL-08 13:38:56
Total Cone.: 18210
Unnamed Cone.; 9973.801
Homolog count: 13

RT
ml Resp
mod. m2 Resp
mod. RA

Resp
Adj _Resp
S/N

Cone.
Name

34

8.563e+Q6
n
6.771e+06
y
1.26
fl
533e+Q7
1
533e+07
3.65ei02
y
1390
1,2,3,4,
6,8-HxCDF
34
28
2.801e+07
n
2.214e+07
n
1.27
X.5
015e+07
5
015e+07
1.17e+03
y
4560


34
42
3.946e+06
n
3.2S9e+06
n
1.21
7
204e+06
7
204e+06
1.52e+02
y
554


34
sr
5.926e+06
n
4.635e+06
n
1.28
y i
056e+07
1
056e+07
2.43e+02
y
959


35
°S.
2. 627e+06
n
2.017e+Q6
n
1.30
It 4
644e+06
4
644e+06
1.04e+02
y
422


35
33
1.102e+07
n
8.862e+06
n
1.24
* 1
988e+07
1
988e+07
4,85e+02
y
1810


35
40.
1.070e+Q7
n
8.398e+06
y
1.27
¥ 1
910e+07
1
910e+07
4.50e+02
y
1760
1,2,3,4,
7,8-HxCDF
35
49
1.27 6e+07
n
1.027e+07
y
1.24
X 2
3 0 3s+07
2
303e+07
5.35e+02
y
1880
1,2,3,6,7,8-HxCDF
35
55"
2.670e+06
n
2,084e+06
n
1.28
X. 4
753e+06
4
753e+06
1.07e+02
y
432


36
01,
3,085e+06
n
2.393e+06
n
1.29
X 5
478e+06
5
478e+06
1.29e+02
y
497


36
15
4.003e+06
n
3.140e+06
n
1.27
*7
143e+06
7
143e+06
1.64e+02
y
649


36
29"
1.621e+07
n
1.270e+07
y
1.28
y 2
891e+07
2
891e+07
6.81e+02
y
2470
2,3,4,6,
7,8-BxCDF
37
29^
3.767e+Q6
n
2.995e+Q6
y
1.26
& 6
762e+06
6
762e+06
1.12e+02
y
727
1,2,3,7,
8,9-KxCDF
Totals
Results

Analytical
Perspectives

[Form: TOT]



Totals Class: HpCDF EMPC
File Name: 080723P2 Sample it:
Function: 4 Run #: 6	Checkcode: 0198
Sample text: P9464_6042_003 Run# I-ACD-M23-2 Air Tra»
-------
OPUSquan on MM1 26-JUL-2Q08 11:20
Acquired: 24-JUL-08 00:11:35 Processed: 24-JUL-08 13:38:56
Total Cone.: 6659.2	Unnamed Cone.: 2548.248	Homolog count: 4
RT
ml Resp mod. m2 Resp
mod. RA Resp
Adj_Resp
S/N

Cone.
Name
39:05s
1.697e+07 n
1.6S0e+07
y
I - 03 3 .348e+07
3.348e+07
1.85e+03
y
3400
1,2,3,4,6,7,8-HpCDF
39:2*^
5,859e+06 n
5.639e+Q6
n
1.04 y 1.150e+07
1.150e+07
6.39e+02
y
1290
39:35j
5.696e+06 n
5.494e+06
n
1.04 / 1,119e+07
1.119e+07
6.06e+02
y
1260

40:51
2.880e+06 n
2.760e+06
y
1.04 Y 5.640G+06
S.640e+06
2.89e+02
y
709
1,2,3,4,7,8,9-HpCDF
-------
File: 080723P2 Acq: 24-iUL-2008 00:11/:35 GC El+ Voltage SIR Autospec-UltimaE	
Sample# 6 Text: F9464_6042_003 Bun# 1-ACD-M23-2 Air Train Vial# 35 File Text: AP DBS
316.9824 S:6 PKD(5,5,3,100.00%,750.0,0,00%,F,F) Expt: DF_CL4-8
,	23-19	25:44
100% 20:15 20:51 21:31 22:03 22:46 T 23:40	24:29 25:06
80.
60.
40.
20.
27:22
28:31
29:24
25 : 00
31:53 32:07
26' 00
27 I 00
32:47
28'00 ' ' ' 29!00
33:19 33:39
3E6
Be6
4E6
2E5
6E5
Time
2E6
8E6
3E6
9E5
5E5
Time
21:00	22:00	23:00	24:00
366.9792 S:6 F:2 PKD{5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
?9 • 44
3 00%, ' n 29
80
60
40,
20
30:14 ,A
52 30:03 1 30=24
30:46
31:06 3i:18 31:31
32:26
32' 00
30:00	31:00
380.9760 S:6 F:3 FKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF CL4-
34:56
:23	34:44 H 35:03
36:19 __ 36:33
35:22 35:35 35:50 36:04 ~1 36 : 27 r
37:20
37:00	"
37:51
34
38:09 38:2^
35:00	36:00
430.9728 S:6 F:4 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4 8
to . an
37:00
38:00
Time
h Q . 1 *i
"3 ft . A1


41:11
41:24

a~> • nn
38:36 38
454.9728 S:6 F
42 : 11
48 39:00 39il2 39l24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00
Time
S FKD(5,5,3,100.00%,750.0,0.00%,F,Expt: DF.CL4-8
42:35
42:56 43:04
43:28
43.42 43;4g 43:59 44:09
42:24
* a in	44:44 45:00
44^30 44:37	-,_4
42:12
42:24
42:36 42:48
43:00
43:12
43:24 43:36
43:48
44:00
44:12
44:24
44:36
44:48
1E6
3E6
5E6
6E6
2E5
45:00 Time
-------
File: 080723P2 Acq: 24-^rUL-2008 00:11
Sample# 6 Text: F9464_6042_003 Run# I-
319.8965 S:6 BSUB{10000,15,-3.0) Expt
35 GC EI+ Voltage SIR Auto spec-UltiinaE
-ACD-M23-2 Air Train Vial# 35 File Text: AP DBS
DF_CL4-8 Noise: 710
23 :12
A1.10E7
23:35
A4 .54E6
25:22
A6.40E6
24:04
A2.03E6
T
25:00
26:01
A3.31E6
"A A
26 : 50
A5.61E6
26:3jA
"A#/Ua
28
16E6
7:36 28:09
23E5 A9.65E5
A
2 9.1 00
.2.1E6
:1.7E6
L1.3E6
.8.4E5
i.4 .2E5
21:00
321.8936 S:6 BSUB(10000,15,
1001,
80.
60.:
40.
20j
22:00
-3.0) Expt:
23:00	24:00
DF_CW-8 Noise: 502
23:12
A1.38E7
26:00
27:00
28:00
23:35
A5.72E6
24:04
A2.62E6
25:22
A8.24E6
26:02 A7609E6	27:28
A4.16E6 "a	A3.91E6
25:5W 26:34/1	&7:37 28:09
1.43(5(5 Al • 43EJ5 \ . A OT _ Q7E6 M .^17 E6

28! 00
Time
2.7E6
,2 . 1E6
1.6E6
.1. 1E6
5.3E5
21:00
327.8850 S:6 BSUB(10000,15,
100%
80i
60i
40i
20i
22: 00
-3.0) Expt:
23:00	24:00
DF_CL4-8 Noise: 566
25: 00
26: 00
27:00
27: 08
A1.44E7
25! 00*
26* 00
27:00
29 00
Time
_3. 4E6
12 .7E6
L2,0E6
Ll.4E6
L6.8E5
21:00
331.9368 S: 6 BSUBU0000,15,
100i,
80.
60.
40.
20.
22:00	23:00	24:00
-3.0) Expt: DF_CL4-8 Noise: 846
23:10
A1.54E7
28:00	29:00
26:25
A1.64E7
Time
27
: 06
_3.8E6
AJl .
53 E7

A
-3.3E6


_2.3E6


_1.5E6
-4

_7.7E5
21:00
333.9339 S:6 BSUB(10000.15,
1001,
80.
60.
40.
20.
22:00	23:00	24:00
-3.0) Expt: DF_CL4-8 Noise: 720
23: 10
A1.86E7
25:00
26! 00
27:00
,26i^. 27:06
A1.97E7 A1.85E7
28:00
29: 00
27 :00
2b!oo' ' ' ' 29 ¦' 00
Time
.4.6E6
13.7E6
L2.8E6
Ll.0E6
19.2E5
21:00
22: 00
23:00
24:00
25:00
26:00
Time
-------
File: Q8Q723P2 ACQ: 24-JUL-
Sample# 6 Text: P9464_6042
355.8546 S:6 F:2 BSUB<10000
1004,
80,
60.
40.
20.
30:07
Al.65E7
•2008 00:11:35 GC EI+ Voltage SIR Autospec UltimaE
.003 RunJ I-ACD-M23-2 Air Train Vial# 35 File Text: AP DB5
*15,-3.0) Expt: DF_CL4-8 Noise: 1442
31:14
A1.J9E7
30:40
A2.30E6
A.
31:32
A8.01E6 31-47
A8.62E6
32:11
A5.S2E6
32:42
A6.05E6
2:47
27E6
33 :09
A3.99E6
.3.5E6
l2.8E6
L2.1E6
i.1. 4E6
.6.9E5
357,8517 S:6 F
100&
80i
60.
40.
20.
30:00
2 BSUB(10000
31:00
15,-3.0) Expt: DF_CL4-8 Noise: 1160
32:00
33:00
30:07
A1.04E7
31:14
hi.54E6
30:40
A1.43E6
A
31:33
A4 .93E6 -a ¦) .An
A5.39E6
32:11
A3.47E6
32:42
A3.83E6
. 01E6
33:09
A2.52E6
33: 00
34:00 Time
. 1E6
.1.7E6
.1.3E6
.8.6E5
.4.3E5
30: 00
367.8949 S:6 F:2 BSUB(10000
100i,
80.
60.
40.
20.
31:00
15,-3.0) Expt: DF_CL4-8 Noise: 660
32:00
32 :10
Al.83E7
32 : 41
34:00 Time
,_5 . 4E6
4 . 3E6
3 . 2E6
2.2E6
1.1E6
30:00	31:00
369.8919 S:6 F:2 BSUBflOOOO.15, -3 .0) Expt: DF_CL4-8 Noise: 1124
1001
80i
60i
40i
20.:
32:00
33:00
32:10
A1.10E7
366.9792
100%, 29:
80.
60.
40.
20.
30:00	31:00
S:6 F:2 PKD(5,5,3,100.00%,750.0, 0.00%, F, F)
44	30:14
n 29:52 30:03
30:24
30:46
Expt: DF_CL4
31:06 31:18 31:31
32 J 00
31:53 32:07 32:26
32:41
33 :00
32:47
33:19
33:39
30:00
31 :00
32:00
33:00
34
34;
00 Time
.3.326
.2 . 6E6
i.2 . 0E6
Ll.3E6
10.6E5
00 Time
2 . 2Eb
1.8E6
1.3E6
B.9Et>
4 . 5E5
34:00 Time
-------
File: 080723P2 Acq: 24-JUL-2008 00:11:35 GC""E1+ Voltage SIR Autospec-Ultiir.aE
Sample# 6 Text: P9464_6042_003 Run# I-ACD-M23-2 Air Train Vial# 35 File Text: AP DBS
389.8156 S: 6 F:3 BSUBjlOOOO,15,-3.0) Expt: DF_CL4-8 Noise: 1865
35: 53
100%	A1.81E7
35:35
A9.85E6 J |	^
46
A4.62E6
6:00
. 94E6
80.
60.
40.
20.
34:55
A9.00E6
/ ^
/36:<
/
36:57
A4.53E6
4
0E6
13
2E6
L2
4E6
Ll
6E6
18
0E5
35:00	36:00
391,8127 S:6 F:3 BSUB(10000,lb,-3.0 I Expt: DF_CL4-8 Noise: 1134
35:53
100%,	A1.45E7
80j	34:56	A7S86ES
hi 1RBfi	A/.8bEb
60j
40.
20.
6:00
56E6
37:00
,,	36:57
36=46 A3.7 2K6
A3.74E6 p
38:00
Time
3.2E6
2.6E6
ll.9E6
1.3E6
6.5E5
35:00
401.8559 S:6 F:3 BSU3(10000,15, 3.0) Expt: DF_CL4-8
1001,
80.
60.
40.
20j
36:00
Noise: 768
37:00
36:45 -
ai	J / : U J
& A1,6!E7
38:00
Time
4.6E6
3.7E6
12.8E6
1.9E6
9.3E5
35:00	36:00
403.8530 S:6 F:3 BSDB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 954
100*
80.
60.
40.
20.
37:00
35:00	36:00
380.9760 S:6 F:3 PKD(5,5,3,100.00%,750,0,0.00%, F,F) Expt: DF_CL4-8
36:45
37:03
A1.27E7
100* 34:1I 34
80.
60.
40.
20.
34:56
: 23	34:44 "135:03
„„ _	_ 36:19 ,, 36:33
35:22 35:35 35:50 36:04 ~t 36:27 r
37:00
37:00
38:00
38:00
: 51 3 £
Time
3.6E6
2.9E6
2.2E6
1.5E6
7.3E5
Time
35:00
,7,4E6
.5 , 9E6
,4 , 4E6
2.9E6
1.556
36:00
37:00
38:00
Time
-------
/
File: 080723P2 Acq: 24-JUL-2QD8 00:11:35 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 6 Text: P9464 6042 .003 Run# I-ACD-M23-2 Air Train Vial# 35 File Text: AP DBS
423.776? S:6 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1829
39:24
1004	A2.57E?	4Q;16
A2.25E7
38:36
425.7737 S:
100%
80i
60,
40.
20.
38:48 39:00 39:12
6 F:4 BSUBjlOOOO,15,-3
"T^
T"
39:24 39:36 39:48 40:00 40:12
.0) Expt: DF_CL4-8 Noise: 2068
39:24
A2.46E7	4Q:16
A2.13E7
40:24 40:36 40:48
41! 00*
» ' I 1 I
41:12
.7 , 3E6
.5.9E6
4.4E6
2.9E6
1.5E6
41:24 41:36 41:48 42:00 Time
39:12
6
9E6
5
5E6
4
216
2
8E6
1
4E6
40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:46
38:36
435.8169 S:
1004
80.
60j
40.
20.
1 i I 1 1 1 1 1 i 1 »
38:48 39:00
6 F:4 BSUB(10000,15
39:24 39:36 39=48 40:00 40:12
-3.0) Expt: DF_CL4-8 Noise: 1292
40:15
A1-28B7
38:36 38:48 39:00 39:12
437.8140 S:6 F:4 BSUB(10000,15. 3.0}
'	1 '
39:24
42:00 Time
-3.4E6
L2.7E6
i.2 . 0E6
L1.3E6
.6.7E5
39:36 39:48 40:00 40:12
Expt: DF_CI,4 8 Noise: 1277
40:15
A1.22E7
40:24
Willi
40:36
40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
3.1E6
100S
2.5E6
11.8E6
1.2E6
6.1E5
41:24 41:36
41:48
42:00
38:36
430.9728 S
38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24
6 F:4 PKD(5,5,3,100.00%,750,0,0.00%, F,F) Expt: DF CL4-8
39:40
38 49 " v — 1Q.11 TQ .¦jn	< M H .
40:36
40:48
41:00
41:12
41:11
41:24
4 2 : 00
40:22
41:47
41:24 41:36
41:48
39:00
39:12
39:24
39:36
39:48
40:00
40:12
40:24
40:36
40:48
41:00
41:12
Time
38:36 38:4
Time
-------
/
File: 080723P2 Acq: 24-JUL-20O8 00:11:35 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 6 Text; P9464_6 042_003 Run# I ACD M23 -2 Air Train Vial# 35 File Text
457.737? S:6 F:5 BSUB(10000,15,-3.0) Exp I: DF_CL4-8 Noise: 306
AP DB5
/






100%


43:50
A5.16E7
/





1.1E7
80i



/





L9.1E6
60 i









L6.9E6
40i









l4 , 6E6
20i









i2.3E6

'42!12
1 42 :24 ' ' ' 42 ! 36 ' ' 42 Us ' ' ' 43 I 00 ' ' 43 :12 ' ' ' 43 ' 24 ' ' 43 1 36
43 ! 4*8 '
'44! 00 '
44:12
' 44!24'
' 44 ! 3*6 '
' 44!48
45:
00 Time
459.
7348 S:6 F:5
BStrotlOOOO,15,-3.0) PKD(5,5,3,0.10%,750.0,0.00%,F,F) Expt; DF_
.CL4-8 Noise; 389






100%


43:50
A5.70E7






1.3E7
80i









L1.0E7
60i









L?.6E6
40i









LS.1E6
20:









12.5E6

'42!12'
1 1 j 1 1 ¦ r 1 1 j i 1 1 1 . | 1 1 1 ( 1 | 1 . 1 . 1 | 1 1 1 i 1 | 1 1 1 1 1 | i 1 1
42:24 42:36 42:48 43:00 43:12 43:24 43:36
i"-! 1 1 1 1
43:48
'«! 00*
1 1 1 | ! 1 1
44:12
I , , .
44:24
' 44!36'
' 44!48
'45!
00 Time
469.
7780 S:6 F:5
BSUB(10000,15,-3.0) Expt: DF_CL4 8 Noise: 653








100%


43:50
A1.76E7






3.8E6
80i









L3.1E6
6 0J









L2.3E6
40i









_1.5E6
20i









„7.6E5

'42!12'
' 4*2 1 2*4 ' ' ' 42 ! 36 ' ' ' 42 ! 48 ' ' ' 43 ! 00 ' 1 ' 43 ! 12 ' ' ' 43 i 24 ' ' ' 43 ! 36 '
43! 4*8*
'44! 0*0*
' 4*4 ! 12 '
' 4*4 i 2*4 '
' 44!36'
' 4 *4! 4 8
' 45!
00 Time
471.
7750 S:6 F:5
BSUB(10000,15,-3.0) Expt; DF_CL4-8 Noise: 735








loot


43:50
A1-98E7






.4.3E6
BOj









:.3 .4E6
60i









L2.6E6
40j









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20i









L8.6E5

'42¦12'
' 42 ! 24 ' ' ' 42 ! 36 ' ' 42 S 48 ' ' 43 ! 00 ' ' * 43 ! 12 ' ' ' 43 ! 24 * ' *43 136 '
43:48'
......
44:00
44:12
' 4*4 ! 2*4 *
' 44!36'
44:48
45!
00 Time
454.
9728 S;6 F:5
PKD(5,5,3,100.00%,750.0,0.00%,F,F> Expt: DF_CL4-8








100S.
80i
42:11
43-45
42:24. „ 	 . 42:56 43:04 43:28 ' 1
43:49
43:59	j

44
30 44:37
44:44
r
45:00
~Xi
_4.1E6
-3.3E6
60j









_2.5E6
40.









_1.6E6
20i









.8.2E5

'42!12'
' 42 24 ' ' ' 42 ! 36 ' ' * 4*2 ? 4*8 ' ' ' 4*3 ! 0*0 ' ' ' 4*3 ! 1*2 ' ' ' 43 * 2*4 * ' ' 4*3 ¦ 3*6 '
'43:48"
'44:00'
' 44! 1*2 '
' 4*4 ! 2*4 '
'44!36'
' 44 48 '
45:
00 Time
-------
File: 080723P2 Acq: 24-JUL-2O08 00:11:35 GC EI+ Voltage SIR AutOSpec-UltimaE
Sample# 6 Text: P9464_6042_003 Run# I-ACD-M23-2 Mr Train Vial# 35 File Text: AP DBS
303.9016 S:6 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 2203
loos,
80.
60.
40.
20.
21:00
A1.22E7 21:34
A8.15E6
A
22:12
A1JHE7
2i;00	22l00	23:00	24:00
305.8987 S:6 BSUB[10000,IS,-3.0 I Expt: DF_CL4- 8 Noise: 2733
26:36
M.27E7
22:46
24:46
25:15
25: 58
A4.79E7
80E7
A2.03E7
16E7
23:57
A1.11E7
27:08
26:51 A2.58E6
M3 . 29E6 r
28:19
A2.49E6
25:00
26:00
27:00
28:00
1Q0S,
80.
60.
40.
20.
26:36
A5.38E7
21:00
A1.55E7 21:34
22:46
A6.08E7 23:12
A2.75E7
22:12
04 f-
A
A1.03E7 A1.30E7
J\	A.
21:00
315.9419 S : 6 BSUBdOOOO, 15,
MA
22:00	23:00	24:00
-3.0) Expt: DF_CL4-8 Noise: 789
24:46
25:15
A3.54E/
A2.52E7
26:12
23 :57
A2.20E7
A1.43E7
25: 00
100a
80i
60J
40i
20i
20:58
A2.56E7
24:44
A2.59E7
26:00
26:11
A2.29E7
27:08
26:51 A3.18E6
,4 .08E6 r
27:00
28:19
A3.17E6
28:00
29:00
29:00
.9.6E6
7.7E6
.5. 8E6
.3 . 8E6
1.9E6
Time
1.2E7
9.6E6
7.2E6
4.8E6
2 . 4E6
Time
5.4E6
4.3E6
3.2E6
2 -2E6
1.1E6
21:00	22:00	23:00	24:00
317.9389 S: 6 BSUBdOOOO, 15, -3 . 0) Expt: DF_CL4-8 Noise: 1017
iota
eoJ
60.
40j
20.
25: 00
26: 00
27-00
28:00
20:58
A3.21E7
24:44
A3.26E7
i	1	1	1	r-
24: 00
26:11
A2.89E7
27:00
28:00
26:00
28:07
26:15
26:37
27: 37
26:56
29:00
Time
.6.8E6
L&.4E6
_4. 1E6
.2 . 7E6
.1.4E6
7 . 9E3
H6.3E3
4.7E3
3 -1E3
1.6E3
21:00	22:00	23:00
375.8364 S: 6 BSUBdOOOO, 15,-3 . 0) Expt: DF_CL4-8 Noise: 492
100*
80.
60.
40.
20.
25: 00
r°:fo:35 2U1\ 21 32 22:09
22:58
23:26 24:06 24:31
25:31 25:59
24:57 25:2
29:00
29:28
5 28:45 29:10

21:00
22:00
23:00
24:00
25:00
26:00
27:00
28:00
29:00
Time
-------
File: 080723P2 Acq: 24-JUL-2008 00:11:35 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 6 Text: P9464_6042_003 Run# I ACD-M23-2 Air Train Vial# 35 Pile Text: AP DBS
339,859? S : 6 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 503
28:16
A1.86E7
1004
9E6
5E6
1E6
70.
7E6
4E6
50.
0E6
40.
6E6
30.
20.
2E6
8E5
9E5
10.
Time
21:00	22:00
341.9568 S:6 BSUB<10000,15,-3.0) Expt: DF_CL4-8 Noise: 501
23: 00
24: 00
25:00
26:00
27:00
28: 00
29:00
28:16
A1.08E7
1001
2.3E6
2.0E6
1.8E6
80.
70.
1.6E6
60.
1. 4E6
50.
1.1E6
40.
9.1E5
6.8E5
30.
20.
10.
21:00	22:00	23:00	24:00
316.9824 S:6 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
27:00
28:00
29:00
Time
26:00
29: 24
28:31
28:11 1
27:22
.6:59 1
25:44
27 :44
28:46
1005
90.
2.3E6
*12 .1E6
22:46 23:06 23:40
22:03
24: 29
20:15
20:51
-1 22:18
21:31
80.
70.
60.
50.
Ll,4E6
LI .2E6
40.
30.
.9.2E5
20.
L4 . 6E5
10.
L2 .3E5
21:00
22:00
23:00
24:00
25:00
26:00
27:00
28:00
29:00
Time
-------
File: 080723P2 Acq; 24-JUL-
Sample# 6 Text: F9464_6042_
339.8597 S:6 F:2 BSUB(10000,
29:54 30:03
A3.38E7 A3.95E7
1
2008 00:11:35 GC EI+ voltage SIR	Autospec'-UltifiiE	
.003 Run It I-ACD-M23-2 Air Train Vial# 35 File Text: AP
15,-3.0) Expt: DF_CL4-8 Noise: 3976
.J 31:29
31-12 A2.43E7
A1.48E7
DBS
0:08
A81.58E6
30:29 a
A8.05E6 r
31:39
06E6
30:00
341.8568 S:6 F:2 BSUB(10000,15,-3.0)
31:00
Expt: DF CL4 8
32:05
32 :41
A4.72E
A2.18E6
32:00
33:00
33:26
A2.88E6
, /N
Noise: 3113
lOOi
80i
60i
40 j
20i
29:54 30:03
A2.14E7 A2.41E7
30:44
A1.87E7
0:08
30
30:29 a
A5.04E6 r
AS.36E6
„„	31:29
31:12 A1.56E7
A9.47E6
31:39
1.91E6
32:05
32:41
A2.90E
A1.38E6
33:26
A1.81E6
, /N
34
7 .8E6
16.3E6
4 . 7E6
3.1E6
1.6E6
00 Time
4
9E6
.4
0E6
.3
0E6
L.2
0E6
l9
9E5
351.9000 S:6 F
100%,
80
60.
40.
20.
30:00
2 BSUB(10000,15,-3
30:38
A2.98E7
31:00
Expt: DF_CL4-
32:00
33:00
Noise: 2628
31:10
A2.95E7
32:20
34
00 Time
, 8E6
.7.Eft
5.3E6
l3.5E6
L1.8E6
353.8970 S:6
100SL
80i
60i
40-
20.
30:00
F:2 BSUB(10000,15,
-3.0)
31:00
Expt: DF_CL.4-8
32:00
33:00
Noise: 1890
30:38
A1.91E7
31:10
A1.89E7
32:20
34:00 Time
.5.4E6
l4 . 3E6
L.3 .3E6
l2 .2E6
L1.1E6
409.7974 S:6
30:00
P:2 BSUB(10000,15,
-3.0) Expt:
31:00
DF CL4-B
31:00
32:00
33:00
Noise: 528
31:16
32:16
n 32:25
33:16 ,, 33:45 33
.nc a 33:JU H
32:00
32:40 32:54
31:1
31:25
32:00
30:00
31:00
33:00
34:00 Time
2 . 7E4
2.2E4
1.6E4
1, 1E4
5.4E3
:00 Time
-------
File: 080723P2 Acq: 24-JUL-2008 '0D7I 1715 GcTjTTvHTtaga SIR Auto spec-UltiroaE
Sample# 6 Text: P9464_6042_003 Run# I-ACD-M23-2 Air Train Vial# 35 File Text; AF DBS
373.8207 S:6 F:3 BSUB(10000,15,-3.0) Bxpt: DF_CL4-8 Noise: 5462
34:28
A2.80E7
100*
BO,
60j
40,
20.
34:16
34:42
34:54
Ad.56E6
AS.93E6
35:33
A1.10E7
/ib-.J)
hi. 2887
35:08
A2.63E6
r
/~V
35:58
A2.67E6
36:15
A4.00E6
/\/\
/
37:29
A3.77E6
. 2E6
-6.6E6
l4.9E6
.3.3E6
.1.6E6
375.8178 S
34:28
A2.21E7
34:15
34:42
A6.77E6
3.26E6
35:00
F:3 BSUB(10000,15,-3.0)
Expt: DF_CL4-8
36:00
Noise: 4841
37:00
38:00
35:33
35:48
36:28
A1.27E7
34-.S4 35:08
A4.63E6 A2.02E6
A A , A ,
A8.86E6 A1-03E7
35:58
A2.08E6
36 :15
A3.14E6
>v/\
37 : 29
A3.00E6
Tine
6
5E6
l5
2E6
l3
9E6
-2
6E6
Li
3E6
35:00
383.8639 S:6 F:3 BSUB(10000,15,-3.0)
100%,
80,
60,
40.
20,
36: 00
Expt: DF_CL4-8 Noise: 2249
35:48
A1-50E7 36:07
A1.30E7
37:00
38:00
36:28
A1.37E7
37:26
A1.15E7
Time
.4.3E6
i3.4E6
.2.6E6
-1.7E6
.8.6E5
35: 00
385.8610 S:6 F:3 BSUB(10000,15,-3.0)
100*
80.
60.
40.
20.
Expt: DF_CL4-8
36:00
Noise: 2411
35:48
37: 00
38:00
36:28
36:07
A2.63E7
A2.46E7
37:26
A2.18E7
Time
.8.1E6
.6.5E6
l4 . 8E6
.3 . 2E6
.1.6E6
35: 00
445,7555 S:6 F:3 BSUB(10000,15,-3.0)
100*
80,
60.
40.
20.
Expt: DF_CL4-8
36:00
Noise: 620
35:48
37:00
36 : 57
38:00
35:00
36:00
37:00
38:00
Time
37:35
37:21
8:04
38:21
1 .1E4
8 . 4E3
6. 3E3
4 -2E3
2.1E3
Time
-------
/
File: 080723P2 Acq: 24-JUL-2008 00:11:35 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 6 Text: ?9464_6042_003 Run# I-ACD-M23-2 Air Train Vial# 35 File Text: AP DBS
407.7818 S:
1001
80j
60i
40i
20 i
P:4 BSUB(10000, 15,
39:05
A1.70E7
-3.0) Expt: DF_CL4-8 Noise; 1329
39:24
A5.B6E6
39:35
A5.70E6
r
/
40:51
A2.88E6
.4.9E6
.4.0E6
i.3 . QE6
L2.0E6
.9.9E5
40:36 40:48 41:00 41:12 41:24
| ' I 1 1 1 1 1 I 1 1
41:36 41:48
38:36
409.7788 S:
100%
80i
6°i
40i
20i
38:48 39 : 00 39112
6 F:4 BSUB(10000,15,-3
39:05
A1.65E7
39:24 39:36 39:48 40:00 40:12 40:24
0) Expt: DF_CL4-8 Noise: 964
38:36
417.8253 S
100*
80.
60.
40.
20.
39:24
AS.64E6
39: 3S
A5.49E6
r
42:00 Time
A . 8E6
i.3 . 8E6
.2 . 9E6
.1. 9E6
.9.6E5
38:48 39:00 39:12
6 F:4 BSUB(10000.15,-3
39:04
A8.35E6
39:24 39:36 39:48 40i00
.0) Expt: DF_CL4-8 Noise: 1692
39:34
AS.
40:12 40:24
38:36 38:48 39:00 39:12
419.8220 S:6 F:4 BSUB(10000,15,-3.0)
39: 04
100%,	A1.J1E7
BOi
60i
40i
20i
> '	I'"'
39:24
40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
-2.4E6
il. 9E6
L1.4E6
.9.5F.5
L4.7E5
39:00
39:36 39:48 40:00
Expt: DF_CL4-8 Noise: 2647
39: 34
A1.78E7
' 1 I ' 	I		
40:12 40:24
40:50
A7.26E6
40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
.5-5E6
.4 -4E6
:3. 3E6
.2.2E6
L1.1E6
39:12 39 i 24 39:36 39:48 40:00 40ll2
479.7165 S:6 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 479
40:50
A1.63E7
I , i ¦ i r^|-i • i
40:48 41:00
-j—r—i-1—i—i—|—i—r*
38:36 38:48
1 ' "T 1
39:24
40:24 40:36
40:22
100i
41:21
40:16
39:30
41:58
1
41 : 4 2
38:44
41:12 41:24 41:36 41:48 42:00 Time
9.6E3
i7 , 7E3
. 8E3
l3.8E3
1.9E3
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40i48 41^00 41112
41:24 41:36 41:48
00 Time
-------
/
8.8E5
.7 . 0E5
A4.21E6
lOOt
80-
60 J
40.:
20i
S.3E5
3 . 5E5
1.8E5
44:36
44:48
45:00 Time
43:12
43:24
43 :36
43:48
44 :00
44:12
42:12 42:24 42:36 42:48
443.7398 S:6 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 475
43:00
44:05
A4.76E6
1.0E6
8.1E5
1005
80.
6.1E5
,4. 0E5
40.
.2.0E5
20.
44:48
45:00 Time
44:36
43:36
44:00
44:12
44:24
42:12 42:24 42:36
453.7830 5:6 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 361
42:48
43:00
43:12
43:24
44:04
A2.6QE7
5.2E6
4 .2E6
1005
80.
3 . 1E6
2 . 1E6
60.
40.
1.0E6
20.
45:00 Time
44:12
44 :24
44:36
44:48
42:12 42:24 42:36
455.7801 S:6 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 332
42:48
43:00
43:12
43:24
43:36
43:48
44:00
44:04
A2.91E7
100!
80.
60.
.3.6E6
.2.4E6
40.
1.2E6
20.
45:00 Time
43 :48
44:00
44:12
44:24
44:36
44:48
42:12 42:24 42:36
513.6775 S:6 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-S Noise: 394
43:00
43:12
43 :24
43:36
42:08
45:00 Time
44:00
44:12
44:4
42:24
42:36
42:48
43:00
43:12
43:24
43:36
43:48
42:12
-------
4/ -fk-
-ft
OPUSquan on KMl
26-JUL-2008 11:19
checkcode: 04,
1613/8290 Sample Summary
Client ID: Run# I-ACD-M23-3
Lab ID:	P9464_6042„004
Sample text: P9464_6042_004 Run#
Analytical Perspectives
Typ
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax2
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax2
2,3,7
1,2,3,7
2,3,4,7
2.3.6.7
2.3.7.8
3,4,6,7
Maine
8-TCDD
8 -PeCDD
8-HxCDD
8-HxCDD
9-HxCDD
8-HpCDD
OCDD
OCDD-a
2,3,7,8-TCDF
1,2,3,7,8-PeCDF
2,3,4,7,8-PeCDF
1,2,3,4,7,8-HxCDF
1,2,3,6,7,8-HxCDF
2.3.4.6.7.8-HxCDF
1.2.3.7.8.9-HxCDF
1,2,3,4,6,7,8 HpCDF
1,2,3,4,7,8,9-HpCDF
OCDF
OCDF-a
ES
13C-
ES
13C-1,2
ES
13C-1,2,3
ES
13C-1,2,3
ES
13C-1,2,3
ES
13C-1.2,3,4
ES

2,3,7,
3,7,8
4,7,8
6.7
7.8
-TCDD
8-PeCDD
8-HxCDD
8-HxCDD
9-HxCDD
ES
13C-2,3,
ES
13C-1,2,3,7
ES
13C-2,3,4,7
ES
13C 1.2,3,4.7
ES
13C-1.2,3,6,7
ES
13C-2,3,4,6,7
ES
130-1,2,3,7,8
ES
13C-1,2,3,4,6,7
ES
13C-1,2,3,4,7,8
ES

CS
37C1-2,3,
CS
13C-1,2,3,4
CS
13C-1,2,3,4
CS
13C-1,2,3,4,6
CS
13C-1,2,3,4,6,8
NA

JS/RT
13C-1,2,
JS
13C-1.2,
JS/RT
13C-1,2,3,4,6
6,7,8-HpCDD
13C-0CDD
7,8-TCDF
8-PeCDF
8 PeCDF
8-HxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8-HpCDF
9-HpCDF
13C-OCDF
7-PeCDD
9-HxCDF
n/a
3,4-TCDD
3,4-TCDF
,7-HxCDD
GC
I-ACD-M23
Resp
2.84e+0?
5.05e+07
2.85e+07
3.78e+07
3.64e+07
1,26e+08
6.58e+Q7
4.16e+06
3.12e+08
1.76e+08
3.52e+08
1.35e+08
1.56e+08
2.04e+08
4.83e+07
2 . 3 0©+ 08
3.76e+07
4.43e+07
2.65e+06
5.40e+07
4,94e+07
4.29e+07
4.81e+07
4.79e+07
4.52e» 07
6.04e+07
8.52e+ 07
8.05e+07
8.16e+07
6.15e+07
7.21e+07
6.$4e+07
5.44e+07
4.74e+07
3.93e+07
8.88e+07
2.37e+07
4.95e+07
8.04e+07
6.35e+07
4.48e+07
5.74e+07
9.31e+07
2.35e+07
Filename:
column ID:
3 Air Train
080723P2
db-S
RA
0.79
1.63
1.23
0.78
1.57
1.06
0.88
2.26
0.81
1.62
1.29
1.29
1.31
1.04
0.88
80
58
57
54
0.54
0.54
0.53
0.45
1.62 y
1.56 y
0.54 y
0.45 y
32:43
36:4 Oir
37:05
1.17
1.02
27:07
32:42
36:39
36:46
37:05
40:16
43 : 51
26:12
31:12
32:21
35:40
35:49
0.96
0.84
0.91
1.01
0.98
0.91
0.68
J
36
37
39
40
29
27
06
51
44:06
27:09
32:11
0.86
0.88
30
36
39
39
08
35
1.09
0.89
0.93
1.39
0.99
n NotF» 1.36
0.83 y
0.79 y
1.27 y
26:25
24:45
36:58
[Form; DF)
7 Vial: 36
JS (split adj.): 4000
Cone.
1920
4080
2420
3130
2940
11400
8060
8050
12600
8540
15900
7330
7650
10500
3180
13600
2830
4270
4670
3940
4090
3990
4040
4170
4220
7490
3940
4030
3990
4160
4200
4140
3620
3870
3920
7440
1510
3870
3700
3880
3840
214
221
105
.fo2
Acq: 24-JUL-£fl- 01)02:23
Wt/Vol; 1.000	—"
CS/SS: 1600 ES: 400

Noise
Fac
DL
Rec



/
2214
2.5
2 ,92
2977
2.5
5.56
-
2682
2.5
4.34
_
2682
2.5
4.59
-
2682
2.5
4.84
-
2085
2.5
3.74
-
2259
2.5
6.33
-
1714
2.5
75.9
/
2843
2.5
2.30
-
3775
2.5
4.41
-
3775
2.5
3.91
-
4865
2.5
3.48
-
4865
2.5
3.29
_
4865
2.5
3.44
-
4865
2.5
4 .73
-
1870
2.5
1.38
-
1870
2.5
2.09
-
1720
2.5
3.87
-
2329
2.5
95.9
-
2561
2.5
3.82
98.4
2978
2.5
5.05
102
3969
2.5
7.47
99.7
3969
2.5
6.73
101
3969
2.5
6.99
104
4183
2.5
7.90
105
2511
2.5
6.31
93 .6
2658
2.5
2,65
98.6
9427
2.5
10.2
101
9427
2.5
9.93
99.7
9930
2.5
13.6
104
9930
2.5
11.7
105
9930
2.5
12.5
103
9930
2.5
13 .4
90.5
4970
2.5
8.21
96.7
4970
2.5
10.0
98.0
2724
2.5
4.62
93.0


3.42
94.5
2978
2.5
4.76
96.7
9427
2.5
9.35
92.5
9930
2.5
12.3
96.9
4970
2.5
8.61
95.9
1530
2.5
1.93
*
2561
2.5

_
2658
2.5
-
-
1858
2.5
-
-
J
Analyst :£
Date
-------

OPUSquan
on MMl 26-JUL-2008 11
19


checkcode: 0477






ss
37C1-2,3.7,8-TCDD
2,37e+07


27
09
1.14
/ 1540


3.32
96
0
ss
13C-1,2,3,4,7-PeCDD
4.95e+07
1.62
y
32
11
1.06
/ 3780
2978
2.5
5.26
94
5 X
ss
13C-1,2,3,4,6-PeCDF
8 - 040+07
1.56
y
30
39
1.09-/
3680
9427
2.5
10 .3
91
9 X
ss
13C-1,2,3,4,6,9 HxCDF
6.35e+07
0.54
y
36
08
0.95
3700
9930
2.5
7.99
92
4
ss
13C-1,2,3,4,6,8,9-HpCDF
4.4 8e+07
0.45
y
39
35
0.95
3970
4970
2.5
5.52
99
2
SBS
2,4,6,8-TCDF
1.48e+08
0.78
y
22
14
1.17
5970
69650
2.5
56.3

-
Ay
1,3,6,8-TCDD
1.88e+08
0.79
y
23
13
1.09
12700
2214
2.5
2.92

_
Ay
1,2,3,9-TCDD
1.81e+Q7
0.80
y
26
59
1.09
1220
2214
2.5
2.92

-
Ay
1,2,8,9-TCDD
1,27e+07
0,77
y
28
10
1.09
860
2214
2.5
2.92

_
Ay
1,2,4,7,9-PeCDD
1.42e+08
1. 59
y
30
08
1.00
11400
2977
2.5
5 .56

-
Ay
1,2,3,8,9-PeCDD
3.17e+07
1.53
y
33
10
1.00
2560
2977 ¦
2.5
5.56

_
Ay
1,2,4,6,7,9-HxCDD
4 -69e+07
1.24
y
34
57
1.04
3880
2682
2.5
4.59

-
Ay
1,2,3,4,6,7,9 HpODD
9.9Qe+07
1.06
y
39
25
0.98
8910
2085
2.5
3.74

.
Ay
1,3,6,8-TCDF
1.98e+08
0.78
y
21
01
1.17
7970
2843
2.5
2.30

-
Ay
2, 3,4,8-TCDF
1.98e+08
0.78
y
26
07
1.17
7960
2843
2.5
2.30

-
Ay
1,2,8,9-TCDF
4.22e+07
0.78
y
28
20 /
1.17
1700
2843
2.5
2.30

-
Ay
1,3,4,6,8-PeCDF
2.20e+08
1.71
y
28
17
1.17
8870
2940
2.5
2.38

~
Ay
1,2,3,8,9-PeCDF
3.43e+07
1.58
y
33
28
1.05
1610
3775
2.5
4.15

-
Ay
1,2,3,4,6,8-HxCDF
l.lle+08
1.25
y
34
17
1.15
6050
4865
2.5
3.68

-
Tot
Total Tetra-Dioxins
8.13e+08
0.79
y
23
13
1.09
55000
2214
2.5
2.92


Tot
Total Penta-Dioxins
6,54e+08
1.59
y
30
08
1.00
52800
2977
2.5
5.56


Tot
Total Hexa-Dioxins
5.13e+08
1.24
y
34
57
1.04
42500
2682
2.5
4.59


Tot
Total Hepta-Dioxins
2.25e+Q8
1.06
y
39
25
0.98
20300
2085
2.5
3.74

-
Tot
Total Tetra-Furans
6.83e+09
0.78
y
21
01
1.17
275000
2843
2.5
2.30

-
Tot
Total Penta Furans
3.02e+09
1.56
y
29
54
1.05
141000
3775
2.5
4.15

_
Tot
Total Hexa-Furans
l,46e+09
1.25
y
34
17
1.15
78400
4865
2.5
3.68

-
Tot
Total Kepta-Furans
4.24e+08
1.03
y
39
07
1.40
26800
1870
2.5
1.69

-
Tot
TCDD EMPC
8.13e+08
0.79
y
23
13
1.09
55000
2214
2.5
2.92

_
Tot
PeCDD EMPC
6,54e+08
1.59
y
30
08
1.00
52800
2977
2.5
5.56

-
Tot
HxCDD EMPC
5.13e+08
1.24
y
34
57
1.04
42500
2682
2.5
4.59

_
Tot
HpCDD EMPC
2.25e+08
1.06
y
39
25
0.98
20300
2085
2.5
3.74

_
Tot
TCDF EMPC
6.B3e+09
0.78
y
21
01
1.17
275000
2843
2.5
2.30

_
Tot
PeCDF EMPC
3.02e+09
1.56
y
29
54
1.05
141000
3775
2.5
4.15

_
Tot
HxCDF EMPC
1.46e+09
1.25
y
34
17
1.15
78400
4865
2.5
3.68

-
Tot
HpCDF EMPC
4.24e+08
1.03
y
39
07
1.40
26800
1870
2.5
1.69

' /
AS
13C-1,3,6,8-TCDD
5.37e+07
0.82
y
23
11
0.98
3820
2561
2.5
3.73
95
6 /
AS
13C 1,3,6,8 TCDF
8.82e+07
0.79
y
20
59
1.09
3490
2658
2.5
2.27
87
3
DPE
HxCDPE
*


NotF»
_
*


_

-
DPE
HpCDPE
*


NotF»
-
#


-

_
DPE
OCDPE
*


NotF»
-
*


-

-
DPE
NCDPE
*


NotF»
-
*


-

_
DPE
DCDPE
*


NotF»
-
*


-

_
LMG
Fnl check mass
~


NotF»
_
*


_

_
LMC
Fn2 check mass
*


NotF»
-
*


-

-
LMC
Pn3 check mass
*


NotFw
-
*


-

-
LMC
Fn4 check mass
*


NotF»
-
*


-

_
LMC
Fn5 check mass
*


NOtF»

A





-------
OPUSquan on MM1
26-
JUL-2008
11
20






Totals
Results


Analytical Perspectives
(Form: TOT]



Totals class: TCDD
EMPC

Function: 1 Run
#: 7


Checkcode: 047/
File
Name; 080723P2
Sample
#
7 Sample text: P9464_6042_004 Run#
i
-ACD-M23-3
Air Tra» /

Acquired: 24-JUL
-08 01:02:23 Processed: 2'
-JUL-08 13
: 38:57




Total Cone.: 55002


Unnamed Cone
: 38273.56
8 Homolog
count: 17

RT
ml Resp
mod.
x2 Resp
mod. RA Resp
Adj_?.esp
S/N


Cone.
Name
23
K
8.274e+Q7
n
1
052e+08
n
0.79 m, 1 • 879e+08
1.879e+08
9.13e+03
y

12700
1,3,6,8-TCDD
23
37
3.605e+07
n
4
584e+07
n
0.79 ^ 8.189e+07
8.189e+07
4-03e+03
y

5540

24
0?
9.924e+06
n
1
287e+07
n
0.77 x, 2.280e+07
2.2 80e+07
1.18e+03
y

1540

24
5f?
9.989e+Q5
n
1
318e+06
n
0.76 y 2.317e+06
2.317e+06
1.32e+02
y

157

25
11.
3 . 83 8e > 07
n
4
884e+07
n
0.79 f 8.722e+07
8.722e+07
3.80e+03
y

5900

25
23
3.890e+07
n
4
903e+07
n
0.79 7 8.793e+07
8.793e+07
4.81e+03
y

5950

25
36*
1.467e+07
n
1
898e+07
n
0.77 5! 3 .365e+07
3.365e+07
1.81e+03
y

2280

25
52
6.4 09e+06
n
8
115e+06
n
0.79 if, 1. 452c107
1.452e+07
7.91e+02
y

983

26
02
1.736e+07
n
2
227e+07
n
0.78 34 3 .963e+07
3.963e+07
2,20e+03
y

2680

26
2$
1.773e+07
n
2
276e+07
n
0.78 x 4 - 049c107
4.049e+07
1.99e+03
y

2740

26
34
7.876e+06
n
9
922e+06
n
0.79 y 1.780e+07
1.780e+07
1.02e+03
y

1200

26
58
3.454e+07
n
4
386e+07
n
0.79 f 7.841e+07
7.841e+07
3.14e+03
y

5310

26
58.
8.014e+06
n
1
008e+07
n
0.80 y 1.809e+07
1.809e+07
l.OSe+03
y

1220
1,2,3,9-TCDD
27
09
1.251e+07
n
1
592e+07
n
0.79 j) 2 . 843e+07
2.843e+07
1.64e+03
y

1920
2,3,7,8-TCDD
27
29"
2.Q46e+07
n
2
609e+07
n
0.78 « 4,655c.07
4.655e+07
2.8le+03
y

3150

27
38>
5. 433e+06
n
6
813e+06
n
0.80 7 1.225e+07
1.225e+07
7.20e+02
y

829

20
19
5.540e+06
n
7
174e+06
n
0.77 £ 1.271e+07
1.271e+Q7
7.93e+02
y

860
1,2,8,9-TCDD
Totals
Results


Analytical Perspectives
[Form: TOT]


/
Totals class: PeCDD empc

Function: 2 Run
#: 7


Checkcode: 0477
File
Name: 080723P2
Sample
#
7 Sample text: P9464_6042 004 Run#
i
-ACD-M23-3
Air Tra»

Acquired: 24-JUL
-08 01:02:23 Processed: 2<
-JUL-08 13
: 38:57




Total Cone.; 52762



Unnamed Cone
: 34683.262 Homolog
Count: 10

RT
ml Resp
mod.
m2 Resp
mod. RA Resp
Adj_Resp
S/N


Cone.
Name
30
oa,
8.701e+07
n
5
4 88e+07
n
1.59 * 1.419e+08
1.419e+08
3.55e+03
y

11400
1,2,4,7,9-PeCDD
30
41
8.908e+06
n
5
601e+06
n
1.59 y 1.451e+07
1.451e+07
5.11e+02
y

1170

31
if
8.133e+07
n
5
081e+07
n
1.60 y 1.321e+08
1.321e+08
4.66e+03
y

10700

31
2 T
2.471e+Q7
n
1
575e+07
n
1.57 7 4 .046e+07
4.046e+07
1.53e+03
y

3260

31
33*
5.725e+07
n
3
6iie+07
n
1.59 yi 9 . 336e>07
9.336e+07
3,32e+03
y

7530

31
SO,
3.900e+07
n
2
483e+07
n
1.57 m 6.383e+07
6.383e+07
1.59e+03
y

5150

32
13
3.580e+07
n
2
260e+07
ri
1.58 y, 5 - 840e+07
5.840e+07
2.09e+03
y

4710

32
43""
3.130e+07
n
1
921e+07
n
1.63 it 5 . C51c> 07
5.051e+07
1.86e+03
y

4080
1,2,3,7,8-PeCDD
32
49'
1.600e+07
n
1
117e+07
n
1.43 y 2.716e+07
2.716e+07
9.84e+02
y

2190

33
10*
1.916e+07
n
1
250e+Q7
n
1.53 y3.167e+07
3.167e+07
l.i3e+03
y

2560
1,2,3,8,9-PeCDD
Totals
Results


Analytical Perspectives
(Form: TOT]



Totals class: HxCDD EMPC

Function: 3 Run
#: 7


Checkcode: 0477
File
Name: 080723P2

Sample
*
7 Sample text: P9464_6042_004 Run#
i-
-ACD-M23-3
Air Tra»

Acquired: 2'
-JUL-
-08 01:02:23 Processed: 24
-JUL-08 13
:38:57




Total Cone.: 42454



Unnamed Cone.
: 30079.725 Homolog
count: 8

-------
OPUSquail oil MM1
26-
JUL-2008
11
20











RT ml Resp
mod. m2 Resp mod.
RA

Resp
Adj_Resp
S/N


Conc.
Name
34
5"i, 2. S98e+07
n
2.091e+07
y
1
24
as
4.689e+07
4
689e+07
2.24e+03
y

3880
1,2,4,6,7,9-HxCDD
35
36 l,056e+08
n
8.499e+07
a
1
24
i
1.906e+08
1
.906e+08
9.41e+03
y

15800

35
5 5 . C97e+07
n
4.8060+07
n
1
06
TL
9.902e+07
9
.902e+07
6.47e+03
y

8910
1,2,3,4,6,7,9-HpCDD
40
17- 6.465e+07
n
6.156e+07
n
1
05
y* 1,262e+08
1
,262e+08
7.73e+03
y

11400'
1,2,3,4,6,7,8-HpCDD
Totals Results

Analytical
Perspectives

[Form: TOT]



Totals class: TCDF
EMPC




Function
1 Run
#: 7


Checkcode: 0477
File Name: 080723P5
Sairple
#
7


Sample text
P9464_6042_004 Run#
i-
-ACD-M23-3
Air Tra»

Acquired: 24-JUL 08 01:02:23
Processed: 2<
-JUL-08 13
:38: 57




Total Cone.: 274780


Unnamed Cone
:
238609.8
66 Homolog
count: 25

RT ml Resp
mod. m2 Resp
mod.
RA

Resp
Adj_Rcsp
S/N


Cone,
Name
21
05«, 8. 693e+07
n
l.llle+08
y
0
78
U.
1,980e+08
1
980e+08
7.59e+03
y

7970
1,3,6,8-TCDF
21
34 6.400e+07
n
8. 160e+07
n
0
78
%
1.456e+08
1
456e+08
5.40e+03
y

5860

22
14 6.492e+07
n
8. 335e+07
n
0
78
Y
1.483e+08
1
483e+08
2.16e+02
y

5970
2,4,6,8-TCDF
22
45"* 4.099e+08
n
5.2276+08
n
0
78
7
9.325e+08
9
325e+08
2.04e+O4
y

37500

23
OS, 6.436e+07
n
8.322e+07
n
0
77
¥>
1.476e+08
1
476e+08
5.46c 103
y

5940

23
13 1.765e+08
ri
2.244e+08
n
0
79
y
4.009e+08
4
009e+08
1.226+04
y

16100

23
26, 1.767e+06
n
2.476e+06
n
0
71
9
4.243e+06
4
243e+06
1.46e+Q2
y

171

23
39 9, 308e+07
n
1.189e+08
n
0
78
7
2.120e+08
2
120c~08
8.33e+03
y

8530

23
47-» 7.049e+07
n
9.031e-07
n
0
78
y,
1.608e+08
1
608e+08
6.25e+03
y

6470

23
58 9.948e+07
n
1,272e+08
n
0
78
y
2.267e+08
2
267e+08
8.96e+03
y

9120

24
22"* 8.995e+07
n
1.155e+08
n
0
78
?
2.055e+08
2
055e+08
7.65e+03
y

8270

24
31^ 1.562e+08
n
1.957e+08
n
0
80

3.520e+08
3
520e+08
1,45e+04
y

14200

24
41 1.703e+08
n
2.224e+08
n
0
77
y
3.927e+08
3
927e+08
1.65e+04
y

15800

24
4» 2.320e+Q8
n
2.939e+08
n
0
79
y
5,259e+08
5
259e+08
1.67e+04
y

21200

25
1^ 1.569e+08
n
1.999e+08
n
0
78
f
3.568e+08
3
568e+08
1,47e+04
y

14400

25
23 2.317e+07
n
2.890e+07
n
0
80
V
5.207e+07
5
207e+07
2.38e+03
y

2100

25
3 4* 1. 097e+08
n
1.386e+08
n
0
79
y
2.482e+08
2
482e+08
l.lle+04
y

9990

25
46, 1.313e+08
n
1.674e+08
n
0
78
?
2.987e+08
2
987e+08
1.12e+04
y

12000

25
59 1.378e+G8
n
1.765e+08
n
0
78
V
3.143e+08
3
143e+08
1.41e+04
y

12700

26
0^ 8.677e+07
n
l.llle+08
y
0
78
u
1.978e+08
1
978e+08
9.25e+03
y

7960
2,3,4,8-TCDF
26
1? 1.373e+08
n
1.750e+08
y
0
78
K
3.123e+08
3
123e+08
1.38e+04
y

12600
2,3,7,8-TCDF
26
3"? 3.763e+08
n
4.769e+08
n
0
79
X
8.533e+08
8
533e+08
3.67e+04
y

34300

26
5*2- 2 .460e+07
n
3.188e+07
n
0
77

5.648e+07
5
648e+07
2.51e+03
y

2270

-------
OFUSquan on MM1
26-JUL-2008 11:20
27: 0#* 1.834e+07 n
28:2ft, 1.854e+07 n
Totals Results
2,368e+07 n 0.77 y. 4.203e+07 4.203e+07 1.95e+03 y	1690
2.364e+07 y 0.78 y 4.217e+07 4.217e+07 1.83e+03 y	1700 1,2,
Analytical Perspectives	[Form: TOT]
,9-TCDF
Totals class: PeCDF EHPC
File Name; 080723P2 Sample #: 7
Acquired: 24-JUL-08 01:02:23
Total Cone.: 140960
Function: 2 Run ff: 7	Checkcode: 0477
Sample text; P9464_6042_004 Run# I-ACD-M23-3 Air Tra»
Processed: 24-JUL-08 13:38:57
Unnamed Cone.: 114940.S29 Homolog count: 16

RT
ml Resp
mod. m2 Resp
mod. RA


Resp
Adj_Resp
S/N

Cone.
Name
29
54
2.615e+08
n
1.671e+08
y
1.56

4
286e+08
4.286e+08
8
79e+03
y
20100

30
04
2.942e+08
n
1.854e+08
n
1.59

4
796e+08
4.796e+08
9
78e+03
y
22500

30
if
7.01Oe+O7
n
4.908e+07
n
1.59

1
272e+08
1,272e+08
3
53e+03
y
5950

30
1&
3.959e+07
n
2.484e+07
n
1.59
X.
6
443 e+07
6.443e+07
1
65e+03
y
3020

30
3i,
6.157e+07
n
3.918e+07
n
1.57
y
1
007e+08
1.007e+08
2
06e+03
y
4720

30
40
4.274e+07
n
2.744e+07
n
1.56

7
018e+07
7.01Be+07
2
10e+03
y
3290

30
4>*
2.110e+08
n
1.342e+08
n
1.57
y
3
452e+08
3,452e+08
7
07e+03
y
16200

31
0%
3,919e+07
n
2.500e+07
n
1.57
?
6
419e+07
6.419e+07
1
75e+03
y
3010

31
13
1.072e+08
n
6.836e+07
y
1.57
x
1
755e+08
1.755e+08
4
88e+03
y
8540
1,2,3,7,8-PeCDF
31
3ft
1.778e+08
n
1.135e+08
n
1.57
y
2
913e+08
2.913e+08
5
38e+03
y
13600

31
40
2.363e+07
n
1.512e+07
n
1.56
y
3
875e+07
3.875e+07
1
06e+03
y
1810

32
0?
3.175e+07
n
2.029e+07
n
1.57
V.
5
2Q4e+07
5.204e+07
1
58e+03
y
2440

32
If
2.248e+08
n
1.433e+08
n
1.57
u
3
682e+08
3.682e+08
1
06e+04
y
17200

32
22*
2.153e+08
n
1.365e+08
y
1. 58
¥
3
518e+08
3.518e+08
8
85e+03
y
15900
2,3,4,7,8-PeCDF
32
42*
i.451e+07
n
1.027e+07
n
1.41
>
2
478e+07
2.478e+07
7
00e+02
y
1160

33
2S"
2.103e+07
n
1.328e+07
y
1. 58
Y
3
431e+07
3 .431e+07
1
01e+03
y
1610
1,2,3,8,9-PeCDF
Totals
Results

Analytical
Perspectives
[Form: TOT]


Totals class: HxCDF EMFC
File Name: 080723P2 Sample #: "5
Acquired: 24-JUL-08 01:02:23
Total Cone.: 78445
Function: 3 Run
Checkcode: 0477
Sample text: P9464_6042_004 Run# I-ACD-M23-3 Air Tra»
Processed: 24-JUL-08 13:38:57
Unnamed Cone.: 43717.896	Homolog count: 13

RT
ml Resp
mod. m2 Resp
mod. RA
Resp
Adj_Resp
S/N

Cone.
Name

34
11,
6,lSle+07
n
4.934e+07
y
1.25
yil .108e+08
1.108e+08
3.05e+03
y
6050
1,2,3,4,
6,8-HxCDF
34
29
2.009e+08
n
1.592e+08
n
1.26
y 3.600e+08
3.600e+08
9.46e+03
y
19600


34
41*
2.950e+07
n
2.380e+07
n
1.24
f 5.329e+07
5.329e+07
1.34e+03
y
2910


34
55,
4.413e+07
n
3.497e+07
n
1.26
7.909e+07
7.909e»07
2.07e+03
y
4310


35
09
1.709e+O7
n
1.355e+07
n
1.26
y 3.063e+07
3.063e+07
8.08e+02
y
1670


35
3-f
8.320e+07
n
6.630e+07
n
1.26
"? 1.495e+08
1.495e+08
3.95e+Q3
y
8150


35

7.533e+07
n
5.937e+07
y
1.27
y 1.347e+08
1-347e+08
3.62e+03
y
7330
1,2,3,4,
7,8-HxCDF
35
5u
8.657e+07
n
6.988e+07
y
1.24
y 1.564e+08
1-564e+08
3.95e+03
y
7650
1,2,3,6,
7,8-HxCDF
35
S%
2.086e+07
n
1.673e+07
n
1.25
3.759e+07
3.7596+07
9.24e+02
Y
2050


36
08
2.173e+07
n
1,753e+07
n
1.24
M 3.926e+G7
3.926e+07
1.06e+03
y
2140


36
19
2.870 e+07
n
2.341e+07
n
1.23
^ 5.2l0e+07
5.210e+07
1,37e+03
y
2840


36
29
1.130e+08
n
9.109e+07
y
1.24
X 2.041e+08
2.041e+08
5.30e+03
y
10500
2,3,4,6,
7,8-HxCDF
37
3 IT
2 .698e+07
n
2.128e+G7
y
1.27
v 4.826e+07
4.826e+07
8.95e+02
y
3180
1,2,3,7,
8,9-HxCDF
Totals Results

Analytical
Perspectives
[Form: TOT]



Totals class: HpCDF EMPC
File Name: 080723P2 Sanple #: 7
Function: 4 Run #: 7
Sample text: P9464_6042_004 Run! I-
Checkcode: 0477
ACD-M23 3 Air Tra»
J
-------
OFUSquan on MM1 26-JUL-2008 11:20
Acquired: 24-JUL-08 01:02:23 Processed: 24-JUL 08 13:38:57
Total Cone.; 26751	Unnamed Cone.: 10362.285	Homolog count: 4

RT
ml Resp mod. m2 Rasp mod. HA Resp
Adj_Resp
S/N

Cone.
Name
39
02s
1.166e+08 n
1.133e+08 y
1.03 "? 2.299e+08
2.299c > 08
1-72e+04
y
13600
1.2,3,4.6,7,8-HpCDF
39
25*
4.453e+07 n
4.313e+07 n
1.03 if 8.767e+07
8.7 67©+ 07
6.82e+03
y
5790

39
35.
3.479e+Q7 n
3.432e+07 n
1.01 >6.911e+Q7
6.911e+Q7
4.87e+03
y
4570

40
52,
1.938e+07 n
1.825e+07 y
1.06 *3.763e+07
3.763e+07
2.57e+03
y
2830
1,2,3,4,7,8,9-HpCDF
-------
File: 080723P2—Acq: 24-JUL-200B 01:07:23—6c EI+ voltage SIR Autospec-uItxniaE
Sample# 7 Text: P9464_6042_004 Run# I-ACD-M23-3 Air Train Vial# 36 Pile Text: AP DBS
316.9824 S:7 PKD(5,5,3,100.00%,750.0,0.00%, F, F! Expt: DF CL4-8
24:59
127:1t 27:225?:5° 28:l|:3° 28:46 29.10
24:02
100%
21:16 21:37
1 25:51 26:16 26:41
23:23
24:16
20:02
20:35
28:00
29: 00
21:00	22: 00	23:00	24:00
366.9792 S:7 F:2 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4
1	J	1	1 I
25:00
26:00
27:00
„ n, 30:09
29:48 30:01 p
30:35
31:02
31:33
32:00 32:19 32:31 r 2 3 2°: 4 9 3?i05 33:2n ..33:32. 3ii45,
31:20
30:00	31:00
380.9760 S:7 F:3 PKD (5,5, 3,100.00%,750.0,0.00%, F, F) Expt: DF_CL4-8
34:29
100%, 34:12
80 J
"I 34:35
34:52
32:00
¦,F) Expt: DF_CL4- 8
35:08 r5:3\8:28 35:42 35:57 36:11 36:23
36:47
~1 36:57
33:00
37:21 37:38 37:52 38:10 38:23
: 00 Time
7 ,0E6
L5.6E6
4 . 2E6
2.8E6
1.4E6
35500	36:00
430.9728 5:7 F:4 PKDf5,5,3,100.00%,750.0,0.00%,F, F) Expt: DF_CL4~8
38:52
37 :00
100%,
39:00
39:07
39:45
39:29 39:38 r 39:57
40:10 40:19, 40:32 40:43
40:59 4i:12
38: 00
,, 41:42 41:58
41:25 41:35 r	1
Time
38:37
38:36 38:48 39S00 39ll2 39124 39:36 39i48 40i00 40 = 12 40:24 40:36 ' '40:48' 41' do' '	' 41 ? 2 4 ' 41 be' ' 41! 48 42 = 00 Time
454.9728 S:7 F:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4~8

45 ¦ 28


43:41
44:01
44 : 24
n	a-, 45:00
44:37 44:47 ^ -1,
42 :12
42:24
42:36
42:48
43:00
43!12' ' 43124
43 :36
43 :48
44:00
44:12
44: 24
44:36 44:48
:00 Time
-------
File: 0BU723P2 Acq: 24-JUL-
Sample# 7 Text: P9464_6042„
319.8965 S:7 SSUB(10000,15, •
100%
80 j
6 0-|
40|
20 j
¦2008 01:02:23 5C~EI+ Voltage SIR Autospec-UltimaE
.004 Run# I-ACD-M23-3 Air Train Vial# 36 File Text: AP DBS
¦3.0) Expt: DF_CL4-8 Noise: 1231
23:13
A8.27E7
23:37
A3.61E7
24:05
A9.92E6
rA^
25:23
A3.89E7

26:51
A3.45E7
26:34
B7EI
/21:
/A2.0
30
05E7
7:38 28:10
43E6 A5.54E6
/>
.1.6E7
L1.3E7
L9.6B6
16 -4E6
13.2E6
.2.0E7
LX.6E7
L1.2E7
l8,1E6
.4.0E6
21:00
321.8936 S:7 BSUB(10000,15,
1001,
80i
60i
40i
20i
22 : 00
-3,0) Expt:
23:00	24:00
DF_CL4-8 Noise: 947
23 :13
A1.0SE8
: 00
27:00
28:00
23:37
A4.58E7
24:05
A1.29E7
25:23
90E7
26:02
A2.23E7
^ A
26:50
A4.39E7
26:34 .
92E6
26 : 00
27 : 00
27:29
A2.61E7
7:38 28:10
81E6 A7.17E6
^	j
29:00
29 : 00
21: 00
327.8850 S:7 BSUB(10000,15,
1001
80i
60.
40.
20.
22 :00
-3.0) Expt:
23:00	24:00
DF CL4-8 Noise: 632
25:00
28 : 00
27:08
A2.37E7
23:14
A7.64ES

29:00*
Time
.5.5E6
.4.4E6
3.3E6
.2 . 2E6
1.1E6
21:00
331.9368 S:7 BSUB(10000,15,
100%,
80.
60.
40-
20,
22:00	23:00
-3.0) Expt: DF_CL4 8
24:00
Noise: 850
25:00
26:00
27 :00
28:00
23 :11
A2.42E7
26:25 27:07
A2.60E7 A2.41E7
Time
.5.9E6
.4.7E6
.3.5E6
L2.4E6
Ll.2E6
21:00
333.9339 S:7 BSUB(10000,15,
100S
80J
60i
40i
20i
21 !00
22:00	23:00
-3.0) Expt: DF_CL4-8
24:00
Noise: 724
25:00
26:00
27:00
28:00
22:00
23:11
A2.96E7
26:25 27:07
A3.14E7 A2.99E7
23 :00
*24 ! 00*
25 lot)
*26! 00
27:00
28:00
29:00
29:00
Time
.7.0E6
.5,6E6
.4.2E6
-.2 . 8E6
Ll .4E6
Time
-------
02:23 G^rir?-voltage SIR Autospec-UltimaE
I ACD-M23-3 Air Train Vial# 36 File Text: AP DBS
Expt: DF_CL4-8 Noise: 2185
31:16
A8.13E7
File: 080723P2 Acq: 24-JUL-2008 01
Sample# 7 Text: P9464_6042...004 Bun#
355.8546 S:7 F:2 BSUB(10000,15,-3.0)
100%
80i
60i
40i
20_:
30:08
A8.70E7
31:33
A5.72E7
30:41
A8.91E6
A2.47
31:49
A3.90E7
32
A3.
= 12
58E7
32:43
A3.13E7
33:10
A1.92E7
2.2E7
1.8E7
1.3E7
8 . 8E6
4.4E6
34:00 Time
1.4E7
.1. 1E7
8.3E6
5.516
2.8E6
357.8517 S:7 F
100&
80i
60i
40.
20.
30:00
2 BSUB(10000,15,
31:00
-3.0) Expt: DF..CL4-8 Noise: 1788
31:15
32:00
33:00
30:08
A5.49E7
31:33
A3.61E7
30:41
A5.60E6
31:49
A2.48E7
32
A2
: 12
26E7
32:42
A1.92E7
33 :10
A1.25E7
30:00
367.8949 S:7 F:2 BSUBU0000,15,
1004,
80.
60j
40.
20^
-3.0) Expt:
31: 00
DF_CL4-8
32:00
33:00
Noise: 991
32:42
A3.05E7
33:00
34:00 Time
_8.7E6
7.0E6
5.2E6
3.5E6
1.7E6
30:00
369.B919 S:7 F:2 BSUB(10000,15,-3.0)
lQQS,
80.
60.
40.
20.
31: 00
Expt: DP_CL4-8 Noise: 1166
32: 00
32 :11
A1.89E7
32:42
34:00 Time
.5.4E6
l4 . 3E6
L.3.2E6
-2.1E6
1I.IE6
30:00	31:00
366.9792 S:7 F:2 PKD(5,5,3,100.00%.750.0,0.00%,F,F) Expt: DF_CL4-8
32 :00
33: 00
,n ni 30:09
29:48 30:01 r,
30:35
31:02 31:20 31i33
32:00 32:19 32i31 '<2 32%9
34:00 Time
33:05
33:32 33=«8
100%
30:00
31 :00
32 :00
33: 00
34:00 Time
-------
File: Q80723P2 Acq: 24-JUL-2008 01:02:23 GC EI+ Voltage SIR Autospec UltimaK
Sample# 7 Text: P9464_6042_004 Run# I-ACD-M23-3 Mr Train Vial# 36 File Text: AP DBS
389.8156 S:7 F:3 BSUB(10000.15. -3.0) Expt; DF_CL4-B Noise: 2395
35:36
1001,
80.
60.
40,
20.
A1.06E8
3S: 55
A7.06E7
34:56
A2.60E7
A6.54E6
/ '
36:46
A2.09E7
/
36:59
Al.83E7
/yy
3S!00	36:00	37I0O
391.8127 s:7 F:3 BSUB(10000,15,-3.0) PKD(5,5,3,0.10%,750.0,0.00%,F,Fl Expt; DF_CL4-B Noise: 1552
35:36
1001,	A8.50E7
80i
60i
40i
20i
38:00
.3. 1E7
.2.5E7
.1.9E7
.1.3E7
.6.3E6
34: 56
A2.09E7
35:54
A5.72E7
a : 02
A6.31E6
36:46 37-05
A1.68E7 Al.59E7
/\A /y\
38:00
Time
.2.5E7
.2. 0E7
.1. 5E7
.1. 0E7
.5.1E6
35:00	36:00
401.8559 S:7 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 683
100*
80.
60.
40 j
20
37:00
37.04
A2.72E7 a2.72E7
Time
.7 . 5E6
.6 . 0E6
.4.5E6
.3. 0E6
.1.5E6
35:00
403.8530 S:7 F:3 BSUB(10000,15,-3.0!
1004
SO.
60.
40j
20.
36:00
Expt; DF_CL4-8 Noise: 1781
36:46
37:00
37:04
A2.07E7
38:00
Time
_5.9E6
L4 . 7E6
L3.5E6
L2.3E6
.1.2E6
35:00	36:00
380,9760 S:7 F:3 PKD (5,5,3,100.00%,750.0,0.00%, F, F) Expt: DF_CL4-
34:29 	 _ . _	no 35:.
37:00
38:00
Time
38:10 38:23
36:47
37:38 37:52
37 :21
36: 57
35:08
35:57
36:11 36:23
7 . 0E6
5.6E6
4.2E6
2 . 8E6
1,4E6
35:00
36:00
37:00
38:00
Time
-------
File: ffff072~3p2 Acq: 24-JUL-2008 01:02:23 GC EI+ Voltage SIR Autospec-011imaE
Sample# 7 Text: P9464_6042_004 Run# I-ACD-M23-3 Air Train Vial# 36 File Text: AP DBS
423.7767 S:7 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 2847	/
40:17 /
100%,	39:25	A6.-J6E7
80,1	A5'10E?
60.
40.:
20.
1 - 7E?
1.4E7
1. QE7
,6 . 8E6
.3.4E6
3a! 36' ' 38:48 ' 39 ' 00 ' 39 ! 12* ' 39 : 24* ' 39 lie' ' 39148' * m'oo' ' 4*0 112 ' 40! 24 ' 40 ? 3s' ' 40 ' 48* ' 41! 00 41': 12 41^24 41136 41:48 42:'00 Time
425.7737 S:7 F:4 BSUB(10000,15,-3.0} Expt: DF_CL4 8 Noise: 1439
100S,
80.
60.
40.
20j
39:25
A4.81E7
40:17
A6.16E7
T
T
.1.6E7
1. 3e7
9.7E6
.6.5E6
.3.2E6
38:36
435.8169 S
100%,
80.
60.
40.
20j
38148 3 9:00 39^12 39I24 ' 39! 36 ' 39 J 48 40! 00 40!l2 40^24 4o! 36 40U8 41100 41:12 41:24 41;36 41:48
:7 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1202
40:16
A2.31E7
42:00 Time
5 . 9E6
4.7E6
3.6E6
2.4E6
1.2E6
T ! f | ! I
40^24 40:36
40 lis' ' Yl!o0 ' '41:12' ' 41524*
41:36 41:48
38:36
437.B140 S
100%
80.
60.
40.
20.
ill		 | i ' i i i | i ¦ i i -1 i | i ¦ ' ' i i ' i ' i ' i i i ' ' i i i i i '
38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12
7 F:4 BSUB[10000,15,-3.0) Expt: DF_CL4-8 Noise: 1268
40:15
A2.21E7
42:00 Time
.5.7E6
l4 . 5E6
l3 .4E6
12.3E6
-1.1E6
38:36
430.9728 S
100%
80.
60.
40.
20.
38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24
7 F:4 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
« i I 1 ' 1 1 1 1 ' •
40:36 40:48
T
41:00 41:12 41:24 41:36 41:48 42:00 Time;
38;52 39;Q0 39:07
39:45
39:29 39:38 r 39:57
40:10 40:19. 40:32 40:43
40:59 41:12 41:25 41:35
41:42 41
r
58
~1 _4 . 2E6
3.4E6
2.5E6
1.7E6
8.5E5
t
Vol 36'
40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time

38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24
-------
Kile: 080723P2 Scql 24-JUL 2008 01:02:23 GC EI+ Voltage SIR Autospec-UitimaE
Sample# 7 Text: P9464_6042_004 Run# 1-ACD-M23-3 Air Traill Vial# 36 File Text: AP DBS
457.7377 S:7 F: 5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 928
43:52
100%,	A3.J.1E7
80,
60.
40.
20.
44:12
I I | ! I 1
44:24
44 ! 36'
6.5E6
5.2E6
3.9E6
2.6E6
1.3E6
42:12 42:24 42:36
459.7348 S:7 F:5 BSUB(10000,15,-3
1001
80i
60i
40i
20i
-1	1	1	1	1	1—1	1	1	J—I	1—1	1 I |—1 I 1—1 I | I T
42:48 43:00 43:12 43:24
.0) Expt: DF CL4-8 Noise: 432
43:36
43:48
' 44 ! 0*0 '
43:52
A3.48E7
44:48
45:00 Time
.7 .3E6
-5.8E6
14.4E6
l2.9E6
.1.5E6
42:12 42:24 42:36 42:48 43:00
469.7780 S:7 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-
100%,
BO.
60.
40.
20.
43:12 43:24
Noise: 534
'43!36 '
43:48
44:00
44:12
i i—i i i
44:24
44:36
42:12 42:24 42:36 42:48 43:00
471.7750 S:7 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-
100ft,
80.
60.
40.
20.
43:12 43:24
Noise: 354
43:36
43 :51
43 :48
44 :00
—i—J—s—r-
44:12

44:24
> ' I ' 1
44 :36
43:50
A3,22E7
44:48
1 44!48'
42:12 42-24 42:36 42:48 "43!00 43:12 43 ! 24 43:36 43:48
454.9728 S:7 F:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
44:00
44:12
45:00 Time
5.8E6
4 . 7E6
3.5E6
2 .3E6
.1.2E6
45:00 Time
. 6E6
_5. 2E6
.3.9E6
_2 . 6E6
-1.3E6
Txme
1004, 42:10
80_
42:23
42:28
44:48
44:36
44:24
45:00
44:24
44:37
43:31 43:41
44:01
44:47
43:16
42:55 43:04
42:40
2.4E6
1.6E6
7 . 9E5
44:48
44 :36
Time
44:12
44:24
43:36
43 :48
44:00
43 :24
42:12
42:24
42:36
42:48
43:00
43:12
-------
File: 080723P2 Acq: 24-JUL-2008 01:02:23 GC EI« Voltage SIR Aucospec-UltimaE
Sample# 7 Text: P9464_6D42_004 Run# I-ACD-M23-3 Air Train Vial# 36 File Text: AP DBS
303.9016 S:7 BSUBI1000G,15,-3.0) PKD(5,5,3,0.10%,750.0,0.00%,F,F) Expt: DF_CL4
Noise: 6883
26:37
A3.7618
80J
22:48
A4.10E8
25:16
A1.57E8
25:59.
hi.33
.5.0E7
_3 . 4E7
Li .7E7
60j
40i
24:47
A2.32E8
23:14
A1.76E8
21:01
A8.69E7
21:34
A6.40E7
27:09
A1.83E7
20.
MA
Time
25:00
26:00
27:00
28:00
29:00
21:00
305.8987 S; 7 BSUBilOOOO,15,-3.0
22:00
23:00
Expt: DF_CL4-8
24:00
Noise: 11589
26:37
A4.77E8
1.0E8
.8.4E7
L6 .3E7
i4 .2E7
:„2 . 1E7
1001
22:48
A5.23E8
25:16
A2.00E8
25: 59
A1.77E8
60.
40,
24:47
A2.94E8
23 :14
A2.24E8
23:59
A1.27E8
21:00
A1.11E8
21:34
A8.16E7
27:09
A2.37E7
22:14
A8.33E7
20.
28:21
A2.36E7
	-		t	
MA
26:00
28:00
29:00
Time
27:00
21:00
315.9419 S:7 8SUB<10000,15,^3.0
22:00
23:00
Expt: DF_CL4-8
24:00
Noise: 1038
25:00
24:45
A4.10E7
26:12
A3.78E7
21:00
A3.89E7
6E6
9E6
1005
80.
2E6
4E6
7E6
60.
40.
26:00
28:00
29:00
Time
21:00
317.9389 S:7 BSUB(10000,15,-3.0
22:00
23:00
Expt: DF_CL4-8
24:00
Noise: 1306
25:00
27:00
24:45
A5.21E7
26:12
A4.74E7
20:59
A4.93E7
1.1E7
100%
80i
60i
40j
20i
16 . 4E6
i4 . 3E6
-.2 . 1E6
23:00
Expt: DF_GL4-8 Noise: 521
24:00
25:00
26:00
27:00
28:00
29 : 00
21:00
375.8364 S:7 BSUB(10000,15,-3.0
22:00
Time
26:21
1001
80.
-.2 . 1E4
.1.4E4
-7.0E3
26:01
40.
20.
6:39
27:56 28:11 28:35
22: 53
23:35
9:25
25: 39
¦4627:09 27:40
20:30 20:58
28:5'
22:15
23:59
Time
23 :00
24:00
25:00
26:00
27:00
28:00
29:00
21:00
22:00
-------
/
File: 080723P2 Acq: 24-JOL-2008 01:02:23 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 7 Text: P9464_6042. 004 Run# I-ACD-M23 3 Air Train Vial# 36 File Text: AP DBS
339.8597 S:7 3SUB{10000,15,- 3.0) Expt: DF_CL4 8 Noise: 566
100%
9oJ
so|
7°J
6o|
5o|
40|
3oJ
20 J
ioJ
21!00 ' ' ' 22100 ' ' ' 23!00 ' ' ' 24!00 ' ' ' 25100 ' ' ' 26:00
341.8568 S:7 BSUB(10000,15,-3.0) PKD(5,5,3,0.10%,750.0,0.00%,F,F) Expt: DF_CL4-8 Noise: 509
100S
90J
80 J
70i
eoi
50i
40i
30i
2oj
loj
28:17
A1.39E8
27:00
28:00
28
A8.
29:00
17
3E7
21:00	22:00	23:00	24:00
316.9824 S:7 PKD(5,5,3,100.00%,750.0,0.00%, F,F) Expt: DF_CL4-8
*25: 00
26:00
100i.
90i
80.
70.
60.
50.
40.
30.
20.
10.
__ „ ,	, „„ 24-02 , 24:59 .,25:36 25:51 26:22
21:16	22-15 « u	23:23	n 24:16	i 25:14 1
20:02 20:35 21:091 .21:37 n 2hf4 .^23: 05.
27:00
27 ai
26-iR T 27
28:00
27:50
T 28:
29:00
L:3° 28:46 29-.10
21:00
22:00
23:00
"24T0O"
25! 00
'.2.
Li.
.1.
Li.
.8.
Ls.
9E?
6E7
3E7
0E7
8E7
5E7
2E7
8E6
9E6
9E6
Time
26:00
27:00
28:00
29:00
Time
3E6
0E6
. 8E6
6E6
4E6
. 1E6
. 1E5
. 8E5
. 6ES
. 3E5
Time
-------
File':	B8Q723P2 Acq: 24-JUL-2008 01:02:23 (St 'EI+ Voltage SIR Autospec-UltimaZ
Sample# 7 Text: P9464_6042_0Q4 Run#
339.8597 S:7 F:2 BSUB110000,15,-3.0)
I-ACD-M23 3 Air Train Vial# 36
Expt: DF_CL4-8 Noise; 30077
File Text: AP DBS
32;|4„ 32:22
A2.?5E8A2.i5E8
r
30: 04
/
29 : 55
100&
A2.94E8
A2 . 61E8
30:45
A2.11E8
31:30
A1.78E
31:13
A1.07EB
A7L 81E7
30
A4.27
31:00
32:06
A3.17E
33 :28
A2.1057
31:40
32:42
A1.45E7
A3.92E7
30:00
341.8568 S:7 F:2 BSUB(10000,15,-3.0)
29:55 30:04
A1.67E8 A1.85E8
n
Expt:
31: 00
DF CL4-8
32:00
33:00
Noise: 15045
32:22
A1.37E8
30:45
A1.34E8
31:30
A1.13E8
31:13
A6.84E7
0:10
A4\. 91E7
31:00
A2.50E7
z\
32:06
31:40
32:42
A1.03E7
33:28
A1.33E7
	
30:00
351.9000 S:7 F:2 BSUB[10000,15,
100%,
80.
60.
40.
20j
-3.0) Expt:
30:39
A4.90E7
31:00
DF_CL4-8 Noise: 2712
31:12
A4.93E7
32 :00
33 : 00
32:21
A4.98E7
30:00
353.8970 S:7 F:2 BSUB<10000,15,
lOOi
80i
60.
40.
20.
.0) Expt:
30:39
A3.14E7
31:00
DF_CL4-8
32:00
33:00
Noise: 3063
31:12
A3.12E7
32:21
A3.17£7
409
30:00
.7974 S:7 F:2 BSUB(10000,15,
-3.0)
31: 00
Expt: DF_CL4-8
31:01
30:44
32 :00
33:00
Noise: 819
31:18
30 :12
31: 33
31:51 32:03
32:1T 32:25.
6.2E7
5.0E7
3.7E7
2.5E7
1.2E7
: 00 Time
4.0E7
3.2E7
2.4E7
1.6E7
.8.0E6
34:00 Time
.1.4E7
.1.1E7
L8.4E6
LS.6E6
.2.8E6
34:00 Time
.8.9E6
-.7 . 1E6
.5, 3E6
l3.6E6
.1. 8E6
34:00 Time
13-21 33:29
jj.zj. r	33:47
1.8E5
1.4E5
1.1E5
7 . 1E4
3 . 5E4
30:00
31:00
32:00
33:00
34 :00 Time
-------
File:080723P2 Acq: 24-JUL-2tR)8 01:02:23 GC EI+ Voltage SIR Autospec-U1tlmaE
Sample# 7 Text: F9464_6042_004 Run# I-ACD-M23-3 Air Train Vial# 36 File Text: AP DB5
373.8207 S:7 F:3 BSUB(10000,15,-3.0) Expt; DF_CL4-8 Noise: 27322
34:29
100%,	A2.01E8
Al.13
35:34
35:50
34:16
AH.66E7
A6.15E7
35:09
A1.71E7
r
36:16
95E7
41E7
36:00
37:30
A2.70E7
87E7
09E7
35:00
375.8178 S:7 F:3 BSUB(10000,15,-3,0)
34 :29
100^	A1.59E8
80.
60.
40.
20.
36:00
Expt: DF_CL4-8 Noise: 22147
37:00
38:00
34:16
34:43
A4.93E7
2.3BE7
34: 55
A3.50E7
-VV
35:09
A1.35E7
r
	_
35:34 35:49
A6.63E7 A6.99E7
36* 00
\A1 67E7 A2-3«7
36:29
A9.11E7
37! 00
Time
4.6E7
3.7E7
2.8E7
1.8E7
9.2E6
35: 00
383.8639 S:7 F:3 BSUB(10000,15,-3.0)
1001,
80,
60j
40.
20,
Expt: DF_CL4-8
36: 00
Noise: 4054
35:49
A2.51E7 36:08
A2.22E7
38:00
36:29
A2.32E7
37:27
A1.88E7
3 B: 00
Time
6
9E6
5
6E6
4
2E6
2
8E6
1
4E6
385.8610 S:7
35:00
F:3 BSUB(10000,15,-3.0)
Expt: DF_CL4-8
36 :00
Noise: 4461
35:49
A4.7QE7 36:08
A4.14E7
37:00
36:29
A4.32E7
37:27
A3.56E7
35:00	36:00
445.7555 S:7 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 714
35:48
37 :00
38:00
35:00
36:00
37:00
38:00
Time
1.3E7
1.0E7
7 . 9E6
5.2E6
2 . 6E6
Time
6.8E4
100S
5.5E4
36:40
4 . 1E4
35:36
36:55
2 . 7E4
37:38
1.4E4
34:04
r 34
8:08 38:20
14 34:29 34:43
35:07
35:2
Time
-------
/
File: 080723P2 Acq: 24-JUL-2008 01:02:23 GC EI + Voltage SIR Autospec-UltimaE
Sample# 7 Text: P9464_6042_004 Run# I-ACD-M23-3 Air Train Vial# 36 File Text: AP DBS
407.7818 S;7 F:4 BSUB(10000,15,-3.0) PKD(5,5.3,0.10%,750.0.0.00%,F,F) Expt: DF_CL4-8 Noise: 4220
39:07
A1.17E8
1004
soi
60 jj
40i
2 0_:
39:25 39:36
A4.45E7 A3.48E7
r
/
39:48
40:52
A1.94E7
,_3 . 4E7
2.7E7
2.0E7
1.4E7
6.8E6
40:48 41:00
TZ
38:36
409.7788 S
100%
80i
60i
40i
20."
38:48 39:00 39:12
:7 F:4 BSUB(10000,15,-3
39:07
A1.13E8
39:24 39:36
0) Expt: DF_CL4-8
39:25 39:36
A4.31E7 A3.43E7
r
' i I ' 11 1 ' I 11 1 11 l 1 11 11 l 1 '
40:00 40:12 40:24 40:36
Noise: 2794
40:52
Al.82E7
41:12 41:24 41:36 41:48 42:00 -Time
-3.2E7
i.2. 6E7
.1 . 9E7
Ll.3E7
i_6. 4E6
40:48 41:00
41' 36* ' 41:48' ' 42 : 00 Time
_4.3E6
i3.4E6
12.6E6
.1.7E6
L8.5E5
38:36
417.8253 S
100^
80.
60.
40.
20.
38:48 39:00 39:12 39:24
T
39:36
39:48 40:00 40:12 40:24 40:36
41:12 41:24
7 F:4 BSUB(10000,15,-3.0)
39:05
A1.46E7
Expt: BF_GL4-8 Noise: 3416
38:36
419.8220 S
lOOi
80 j
60.
40.
20.
38:48 39:00 39:12
7 F:4 BSUB(10000,15, -3 .
39:05
A3.28E7
38:36
479.7165 S
39:35
A1.38E7
39:24
39:36
39:35
A3.10E7
r'T iMf	i	rMs	t	riMj	i	r
39:48 40:00
'40! 12' ' 40! 24 40:36
40:51
A1.20E7
40:48 41:00
41:12' ' 4l! 24 ' Vl! 36* ' *41: 48 42 : 00 Time
Expt: DF_CL4 8 Noise: 4796
38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24
7 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4 8 Noise: 618
40:50
A2.73E7
9
4E6
L?
5E6
Ls
6E6
L3
7E6
Li
9E6
T
40:36 40:48 41:00 41:12 41:24
Y) ' 36 41 : 4h' ' 42:00 Time
40:24
4 . 7E4
3 . 7E4
40:08 40:15
2 . 8E4
1 -9E4
40:34
39:33 39:40
9.4E3
41:43
41 :36
38:34
r
41: 54
39^0639:16
38:47
38:36
38 : 48 39:00' ' '39:12" ' 39! 24 39^36 39 i 48 40 J 00 40i 12 40^24
40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
-------
/
File: 080723P2	Acq:	24-JUL-2008 01:02:23 GC EI+ Voltage SIR AutOspec-UltimaE
Sample# 7 Text: P9464_6042_004 Run# I-ACD-M23-3 Air Train Vial# 36 File Text: AP DBS
441.7428 S:7 F:5 BSU3(10000,25,-3.0) Expt: DF_CL4-8 Noise: 370
100%,
80.
60.
40.
20.
42:12 42:24
443.7398 S:7 F:S BSUB(10000,IS
100i
80i
60,
40.
20.
1 1 r
42:36
1 1 I '
42:48
-3.0}
43:00
Expt: DF_CL4-
43:12 43:24
Noise: 453
i—i—I—i—1
43 :36
43:48
44:06
44:00
44:12
44:24
	'	"'""I 1 1
44: 36
44:48
42:12 42:24 42:36 42:48
453.7830 S:7 F:5 BSUB(10000,IS,-3.0) Expt:
100*
80.
60j
40.
20.
43:00
DF CL4-
43:12 43:24
Noise: 561
i 1 I 1 '
43:36
' 43:48'
44:06
44^00 "44:12
44:06
A4.22E7
' 1 I 1 1 1
44:24
J I I 1 '
44:36
44:48
42:12 42:24 42:36
455.7801 S:7 F:5 BSUB(10000,15,-2
42:48
.0) PKD(5,
43:00 43:12 43:24
,3,0.10%,750.0,0,00%,F,F)
43:36 43:48 44 ¦ 00 44 ! 12
Expt: DF_CL4-8 Noise: 519
44:06
A4.66E7
44:24
44:36
44:48
4 .2E6
3.4E6
2.5E6
1.7E6
8.SES
45:00 Time
.4.7E6
.3 ,7E6
.2.8E6
.1.9E6
.9.3E5
45:00 Time
8 -6E6
6.9E6
5. 2E6
_3.5E6
1 -7E6
45:00 Time
45:00 Time
44:24
44:36
44 ; 4
43:48 44:00 44:12
43:36
42:24 42:36 42:48 43:00 43:12
7 F:5 BSUB(10000,IS,-3.0) Expt: DF_CL4-8 Noise
43:24
385
42:12
513.6775
44:26
6.5E3
1001
44:14
44:1
-5.2E3
3.9E3
42:52
42•08	42:30
42:13 42:22 * 42:39
2.6E3
1.3E3
44:24
44:36
44 :4
43:48 44:00 44:12
43:12
43:24
43:36
42:48
43:00
42:24
42 :36
42 :12
-------
,Z.

OPUSquan on MM1
26-JUL-2008 11:19
checkcode: 0780

1613/8290 Sample Summary
Analytical Perspectives
(Form: DF]
Client ID:
Lab ID:
Sanple text:
Typ
Ax
AX
Ax
Ax
Ax
Ax	1
Ax
Ax 2
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax	1
Ax	1
Ax
Ax 2
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
cs
cs
cs
cs
cs
NA
Run# I1-ACD-M23-1
P9464_6042_005
P9464_6042_005 Run#
Name
2,3,7,8-TCDD
2,3,7,8-PeCDD
3,4,7,8-HxCDD
HxCDD
HxCDD
1.2.3.6.7
1.2.3.7.8
, 2,3,4,6,7,8-HpCDD
OCDD
OCDD-a
2,3,7,8-TCDF
1,2,3,7
2,3,4,7
1,2,3,4,7
1,2,3,6,7
2.3.4.6.7
1.2.3.7.8
2.3.4.6.7
2.3.4.7.8
8-PeCDF
8-PeCDF
8-KxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8-HpCDF
9-HpCDF
OCDF
OCDF-a
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
13C-1,2,3,6,7,8-HxCDD
13C-1,2,3,7,8,9-HxCDD
13C-1,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,
13C-1,2,3,7
13C-2,3,4,7
13C-1,2,3,4,7
13C-1,2,3,6,7
13C-2,3,4,6,7
13C-1,2,3,7,8
13C-1,2,3,4,6,7
13C-1,2,3,4,7,8
,8-TCDF
8-PeCDF
8-PeCDF
8-HxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8-HpCDF
9-HpCDF
13C-OCDF
37C1-2,3,7,8-TCDD
13C-1,2,3,4,7-PeCDD
13C-1,2,3,4,6-PeCDF
13C-1,2,3,4,6,9-HxCDF
13C-1,2,3,4,6,8,9-HpCDF
n/a
GC
II-ACD-M23
Resp
6.96e+07
1.37e+08
6.52e+07
9.56e+07
9.54e+Q7
4.69e+08
1.48e+09
9.16e+07
5.38e+08
4.64e+08
7.31e+D8
3.30e+08
3.86e+08
3.74e+08
9.88e+Q7
4.48e+08
7.39e+07
1.Q8e+08
6.54e+06
3.42e+07
3.090+07
2.76e+07
3.22e+07
3.15e+07
2.87e+Q7
Filename: 080723P2
column ID: db-5
¦1 Air Train
Vial: 37	Acq: 24 -JUL-OS
Wt/Vol: 1.000
4000 CS/SS: 1600
(split adj.)
5.34e+07
5.14e+07
5.23e+07
3.97e+07
4.61e+07
4.19e+07
3.51e+07
3.05e+07
2.52e+07
5.96e+07
1.59e+07
3.24e+07
5.16e+07
4.37e+07
2.91e+07
RA
0,79
1.57
1.27
1.23
1.25
1.04
0.90
2.55
0.76
1.57
1.58
1.25
1.26
1.27
1.28
1.04
1.01
0.89
2.65
: 09 1.09
43^ 1.00
1.43
A .35
0.94
0.05
0.83 y
1.64 y
1.28	y
1.29	y
1.25 y
1.05 y
4.44e+07 0.88 y 43:52 0.68
0.81
1.59
1.58
0.53
0.53
0.53
0.53
0.45
0.45
0.93
26:13
31:12
32:21
35:41
35:49
36:29
37:27
39:05
40:51
44:06
1.64	y
1.58 y
0.54	y
0.45 y
27
32
30
36
39
09
11
39
08
35
1.09
0.89
0.93
1.39
0.99
Cone.
8590
11800
11700
66300
246000
241000
34500
35400
51500
27800
29600
30500
10100
41000
8660
15500
17200
3860
3980
3700
3890
3950
3860
7930
3690
3850
3820
3870
3860
3760
3370
3590
3620
7200
1570
3920
3550
3840
3590
Noise Fac
4213
3521
3234
3234
3234
7588
2584
2896
4323
24664
24664
13274
13274
13274
13274
8275
8275
5141
2424
3336
8547
6130
6130
6130
4118
4183
3722
11760
11760
12740
12740
12740
12740
6116
6116
6340
8547
11760
12740
6116
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
* n NotF» 1.36
6874 2.5
DL
8.61
10.3
7.98
8.16
9.32
20.3
9.51
168
5.54
44. 8
40.2
15.3
14.3
14.8
20.2
9.39
13.8
16.5
143
7 .52
21. 9
15.9
14.3
14 .9
10.7
14.5
5.84
19.9
19. 5
24.0
20.7
22.1
23.6
13.9
17.0
14.8
9.03
20.7
18.4
21.7
14.6
11.9
/
/
/
01:53^1£
ES; 4000
(7 q_JL«C—
96.6
99.4
92.6
97.2
98.7
96.6
99.2
/
92
96
95
96
96
94
84
89
90
89
98
96
89
/
/
Date
Analyst?
JS/RT	13C-1,2,3,4-TCDD 3.70e+07 0.82 y 26
JS	13C-1,2,3,4-TCDF 6.23e+07 0.79 y 24
JS/RT	13C-1,2,3,4,6,7-HxCDD 1.63e+07 1.34 y 36
26
45
58
138
148
72.7
3336
3722
3222
2.5
2.5
2.5
-------
OPUSquan
on MM1 26-JUL-2008 11
:19


checkcode: 0780
/





SS
37C1-2,3,7,8-TCDD
1.59e+07


27
09
1.14
/ 1630


8.96
102

SS
13C-1,2,3,4,7-PeCDD
3.24e+07
1.64
y
32
11
1.06 y
3950
8547
2.5
23.7
98.7
y
SS
13C-1,2,3,4,6-PeCDF
5.16e+07
1.58
y
30
39
1.09
3690
11760
2.5
20.1
92.3
/
SS
13C-1,2,3,4,6,9-HxCDF
4.37e > 07
0.54
y
36
08
0.95
3980
12740
2.5
16.3
99.5

SS 13C-1,2,3,4,6,8,9-HpCDF
2.91e+07
0.45
y
39
35
0.95
4000
6116
2.5
10.4
99.9

SBS
2,4,6,8-TCDP
3,24e+08
0.78
y
22
14
1.17
20800
4323
2.5
5.54
-

Ay
1,3,6,8-TCDD
2.00e+08
0.79
y
23
13
1.09
21400
4213
2.5
8.61
_

Ay
1,2,3,9-TCDD
4.21e+07
0,79
y
26
59
1.09
4510
4213
2.5
8.61
-

Ay
1,2,8,9-TCDD
3.60e+07
0.78
y
28
10
1.09
3850
4213
2.5
8.61
-

Ay
1,2,4,7,9-PeCDD
2.97e+08
1.59
y
30
08
1.00
38300
3521
2.5
10.3
-

Ay
1,2,3,8,9-PeCDD
9.77e+07
1.60
y
33
10
1.00
12600
3521
2.5
10.3
-

Ay
1,2,4,6,7,9-HxCDD
1.38e+08
1.24
y
34
57
1.04
17400
3234
2.5
8.50
-

Ay
1,2,3,4,6,7,9-HpCDD
3.84e+08
1.05
y
39
26
0.98
54300
7588
2.5
20.3
-

Ay
1,3,6,8-TCDF
3.94e+08
0.79
y
21
00
1.17
25300
4323
2.5
5.54
-

Ay
2,3,4, 8-TCDF
3.43e+08
0.84
y
26
07
1.17
22000
4323
2.5
5.54
-

Ay
1,2,8, 9-TCDF
7.86e+07
0.77
y
28
20 y
1.17
5050
4323
2.5
5.54
-

Ay
1,3,4,6,8-PeCDF
5.46e+08
1.73
y
28
18'
1.17
35100
3473
2.5
4.45
-

Ay
1,2,3,8,9-PeCDF
7.28e+Q7
1.58
y
33
28
1.05
5330
24664
2.5
42.4
-

Ay
1,2,3,4,6,8-HxCDF
2.37e+08
1.25
y
34
17
1.15
20200
13274
2.5
15.9
-

TOt
Total Tetra-Dioxins
1.50e+09
0.79
y
23
13
1.09
161000
4213
2.5
8.61
_

Tot
Total Penta-Dioxiixs
1.42e+09
1.59
y
30
08
1.00
183000
3521
2.5
10.3
-

Tot
Total Hexa-Dioxins
1.08e+09
1.24
y
34
57
1.04
136000
3234
2.5
8.50
-

TOt
Total Hepta-Dioxins
8,53e+08
1.05
y
39
26
0.98
121000
7588
2.5
20.3
_

Tot
Total Tetra-Furans
1,32e+10
0.79
y
21
00
1.17
846000
4323
2.5
5.54
-

Tot
Total Penta-Furans
6.75e+09
1.58
y
29
54
1.05
494000
24664
2.5
42.4
-

Tot
Total Hexa-Furans
3.08e+09
1.25
y
34
17
1.15
259000
13274
2.5
15.9
-

Tot
Total Kepta-Furans
8.02e+08
1.04
y
39
07
1.40
78400
8275
2.5
11.3
-

Tot
TCDD EMPC
1.50e+09
0.79
y
23
13
1.09
161000
4213
2.5
8.61


Tot
PeCDD EMPC
1.42e+09
1.59
y
30
08
1.00
183000
3521
2.5
10.3
-

Tot
HxCDD EMPC
1.08e+09
1.24
y
34
57
1.04
136000
3234
2.5
8.50
-

TOt
HpCDD EMPC
8,53e+08
1.0S
y
39
26
0.98
121000
7588
2.5
20.3
-

Tot
TCDF EMPC
1.32e+10
0.79
y
21
00
1.17
846000
4323
2.5
5.54
-

Tot
PeCDF EMPC
6.75e+09
1.58
y
29
54
1.05
494000
24664
2.5
42.4
_

Tot
HxCDF EMPC
3.08e+09
1.25
y
34
17
1.15
259000
13274
2.5
15.9
-

Tot
HpCDF EMPC
8.02e+08
1.04
y
39
07
1.40
78400
8275
2.5
11.3
-
/
AS
13C-1,3,6,8-TCDD
3.46e+07
0.81
y
23
11
0.98
3830
3336
2.5
7.34
95.6

AS
13C-1,3,6,8-TCB?
5.71e+07
0.80
y
20
59
1.09
3380
3722
2.5
5.00
84.4

DPE
HxCDPE
3.26e+07


26
19

*





DPE
HpCDPE
3.04e+06


33
50
-
*


-
-

DPE
OCDPE
*


NotF»
-
*


-
-

DPE
NCDPE
#


NotF»
-
*


-
-

DPE
DCDPE
*•


NotF»
-
*


-
-

LMC
Fnl check mass
#


NotF»

*



_

LMC
Pr>2 check mass
*


NOtF»
-
*


-
-

LMC
Fn3 check mass
#


NotF»
-
*


-
-

LMC
Fn4 check mass
*


NotF»
-
*


-
-

LMC
Fn5 check mass
*


NotF»

*





-------
OPUSquan on MMl
26-JUL-2008 11:20
Totals Results
Analytical Perspectives
[Form: TOT]
Totals class: TCDD EMPC
File Name: 080723P2 Sample #: 8
Acquired: 24-JUL-08 01:53:12
Total Cone.: 160770
Function: 1 Run #: 8	Checkcode: Of80
Sample text: P9464_6042_0Q5 Run# 11 ACD-M23-1 Air Tr»
Processed: 24-JUL-08 13:38:58
Unnamed Cone,: 123587,522 Homolog count: 17

RT
ml Resp
mod. m2 Resp
mod.
RA

Resp
Adj_Resp
S/N

Cone.
Name
23

8.799e+07
n
1 .H7e+Q8
n
0
79
%
1.997e+08
1.997e+08
5,19e+03
y
21400
1,3,6,8-TCDD
23
37
4.559e+07
n
5.817e+07
n
0
78
y
1.038e+08
1.038e+08
2.64e+03
y
11100

24
of
2.485e+07
n
3 .173e+07
n
0
78
y
5.659e+07
5.659e+07
1.53e+03
y
6060

24
50*
2.760e+06
n
3 .587e+06
n
0
77
y
6.347e+06
6.347e+06
1,82e+02
y
679

25
11,
8.382e+07
n
1.071e+08
n
0
78

1.909e+Q8
1.9Q9e+Q8
4-47e+03
y
20400

25
24
7,913e+07
a
1,008e+08
n
0
78
*
1.799e+08
1.799e+08
5.14e+03
y
19300

25
3&
3.519e+07
n
4.494e+07
n
0
78
y
8.012e« 07
8.012e+07
2.3 6e+03
y
8580

25
51
1.503e+07
n
1-9378+07
n
0
78
7
3.439e+07
3.439e+07
1.08e+03
y
3680

26
of
4,310e+07
n
5.486e+07
n
0
79
T
9.795e+07
9.795e+07
2.87e+03
y
10500

26
26)
2-493e+07
n
3.184e+07
n
0
78
¥.
5.677e+07
5.677a+07
1.49e+03
y
6080

26
34,
1,647e+07
n
2.104e+07
n
0
78

3.75le+07
3.751e+07
1.13e+03
y
4020

26
5Q,
7,233e+07
n
9,217e+07
n
0
78
y
1.645e+08
1.645e+08
3.40e+03
y
17600

26
59,
1.860e+07
n
2.350e+07
n
0
79
y
4.210e+07
4.210e+07
1.29e+03
y
4510
1,2,3,9-TCDD
27
09
3.068e+07
n
3.892e+07
n
0
79
I
6.960e+07
6 -960e+07
2.14e+03
y
7450
2,3,7,8-TCDD
27
3
-------
OPUSquan on MM1
26
-JUL-2008
11
20









RT
ml Resp
mod. m2 Resp mod. MA

Resp
Adj_Resp
S/N

Cone.
Name
34
52,
7.658e+Q7
n
6.168e+07
y
1.24
4* 1
383e+QB
1
383e+08
5.52e+03
y
17400
1,2,4,6,7.9-KxCDD
35
37»
1.215e+08
n
9.746e+07
n
1.25
y 2
190e+08
2
¦190e+08
8.59e+03
y
27600

35
54
1.879e+08
n
1.522e+08
n
1.23
X 3
401e+08
3
401e+08
1.02e+04
y
42900

36
03'
2.180e+07
n
1,782e+07
n
1.22
y 3
961e+07
3
961e+07
1.35e+03
y
4990

36
4(3
3.653e+07
n
2.866e+07
y
1.27 f 6
519e+07
6
519e+07
2.68e+03
y
8590
1,2,3,4,7,8-HxCDD
36
n
5.265e+07
n
4.293e+Q7
y
1.23 f 9
5596407
9
559e+D7
3.7Qe+03
y
11800
1,2,3,6,7,8-HxCDD
36
50i
4.898e+07
n
3.986e+07
n
1.23 /a
884e+07
8
884e+07
3.60e+03
y
11200

37
oy
5.306e+07
n
4,235e+07
y
1.25
y 9
541e+07
9
541e+07
3.16e+03
y
11700
1,2,3,7,8,9-HxCDD
Totals
Results

Analytical
Perspectives

[Form: TOT]


Totals Class: HpCDD EMPC



Function
4 Run
#: 8

Checkcode: 0780
File
Name: 080723P2 Sample
#.
8
Sample text
P9464_6042_005 Run#
II-ACD-M23-
¦1 Air Tr»

Acquired: 24-JUL-08 01:53:12
Processed: 24-JUL-08 13
: 3 8:58



Total Cone.: 120610

Unnamed Cone
:
*
Homolog count: 2


RT
ml Resp mod. m2 Resp
mod. ha

Resp
Adj_Resp
S/N

Conc.
Name
39
26.
1.961e+08
n
1.875e+08
n
1.05
^3
836e+08
3
836e+08
7.19e+03
y
54300
1,2,3,4,6,7,9-HpCDD
40
17
2.395e+08
n
2.294e+08
n
1.04
i>-4
690e+08
4
690e+08
8.01e+03
y
66300
1,2,3,4,6,7,8-HpCDD
Totals
Results

Analytical
Perspectives

[Form: TOT]


Totals class: TCDF
EMPG



Function
1 Run
ft: 8

Checkcode: 0780 ,
File
Name: 080723P2 Sample
#:
8
Sample text
P9464_6042_005 Run#
II-ACD-M23-
-1 Air Tr» /

Acquired: 24-JUL-08 01:53:12
Processed: 24
-JUL-08 13
: 38:58


/
Total Cone.: 846290

Unnamed Cone

738522.073 Homolog count: 26

RT
ml Resp
mod. m2 Resp
mod. RA

Resp
Adj_Resp
S/N

Conc.
Name
21
0ft,
1.733e+08
n
2.204e+08
y
0.79
* 3
937e+08
3
937e+08
9.93e+03
y
25300
1,3,6,8-TCDF
21
34,
1.225e+08
n
1.555e+08
n
0.79
y 2
780e+08
2
780e+08
6.74e+03
y
17900

22
14
1.423e+08
n
1.818e+08
y
0.78
7 3
241e+08
3
241e+08
7.S4e+Q3
y
20800
2,4,6,8-TCDF
22
4?
8.l82e+08
n
1.042e+09
n
0.79
X 1
860e+09
1
860e+09
2.69e+04
y
120000

23
05,
1.237e+08
y
1.581e+08
y
0.78
y 2
818e+08
2
818e+08
7.02e+03
y
18100

23
13
3.512e+08
y
4. 450e+08
y
0-79

962e+08
7
962e+08
1.56e+04
y
51200

23
29
9.866e+06
y
1,324e+07
y
0.75
y 2
311e+07
2
311e+07
4.76e+02
y
1490

23
39*
1.897e+08
y
2.338e+08
y
0.81
7 4
235e+08
4
235e+08
1.07e+04
y
27200

23
48
1.315e+08
y
1.739e+08
y
0.76
y» 3
054e+08
3
054e+08
7.78e+03
y
19600

23
58*
2.022e+08
y
2,575e+Q8
y
0.79
v 4
597e+08
4
597e+08
1.16a+04
y
29500

24
22
1.728e+08
y
2.207e+08
y
0.78
y 3
935e+08
3
935e+08
9.55e+03
y
25300

24
31
2.766e+08
y
3.509e+08
y
0.79
? 6
274e+08
6
274e+08
1.73e+04
y
40300

24
AT
2.875e+08
y
3 -698e+08
y
0.78
% 6
573e+Q8
6
573e+08
1.86e+04
y
42200

24
48"*
5.147e+08
y
6.498e+08
y
0.79
y 1
165e+09
1
165e+09
2.41e+04
y
74800

25
17
3.772e+QB
n
4-792e+08
n
0.79
y 8
564e+08
8
564e+08
1.98e+Q4
y
55000

25
33S
2.286e+08
n
2.923e+08
n
0.78
y 5
209e+08
5
209e+08
1.49e+04
y
33500

25
46*
2.524e+08
n
3.1986+08
n
0.79
If 5
722e+08
5
722e+08
1.4fie+04
y
36800

25

2.434e+08
y
3.102e+08
y
0.78
y 5
536e+08
5
536e+08
1.60e+04
y
35600

26

1.562e+08
n
1.866e+Q8
y
0.84
y 3
428e+08
3
428e+08
1.07e+04
y
22000
2,3,4,8-TCDF
26

2.315e+08
y
3.061e+08
y
0.76
M 5
376e+08
5
376e+08
1.57e+04
y
34500
2,3,7,8-TCDF
26
3?
6.561e+08
n
8.411e+08
ri
0.78
K 1
497e+09
1
497e+09
4.40e+04
y
96200

26
53,
4,826e+07
y
6.197e+07
y
0.78
¥ 1
102e+08
1
102e+08
2.75e+03
y
7080

27
03».
3.977e+07
n
5.093e+07
n
0.78
% 9
070e+07
9
070e+07
2.61e+03
y
5830

-------
GPUSquan on MMl 26-JUL 2008 11:20
27:2#i 4.S53e+06 n
27-.39" 3.647e+06 n
28:20^ 3 .428e+Q7 n
Totals Results
5.884e+06 n 0.77 ;pl.044e+07 1.044e+07
4.563e+06 y 0,80 y 8.210e+06 8.210e+06
4 ,427e+07 y 0.77 Jr 7.855e+07 7.855e»07
Analytical Perspectives
2.52e+02 y
2.27c 102 y
2.17e+03 y
(Form: TOT]
671
528
5050 1,2,8,9-TCDF
Totals class: PeCDF EMPC
File Name: 080723P2 Sample #: 8
Acquired: 24-JUL-08 01:53:12
Total Cone.: 493640
Function: 2 Run #: 8	Chackcode: 0780
Sample text: P9464_6042_005 Run# II-ACD-M23-1 Air Tr»
Processed: 24-JUL-08 13:38:58
Unnamed Cone.: 401490.337 Homolog count: 16

RT
ml Resp
mod. m2 Resp
mod. RA
Resp
Adj_Resp
S/N

Cone.
Name
29
5!
6.250e+08
n
3.958e+08
y
1.58 k
1.021e+09
1.021e+09
3 .03e+03
y
74700

30
04*
7.715e+08
n
4.890e+08
n
1.58 y
1,260e+09
1.260e+09
3 .72e+03
y
92200

30
icr
1.703e+08
n
1.Q19e+08
n
1.67 y
2.722e+08
2.722e•08
1.27e+03
y
19900

30
16->
7.174e+07
n
4.951e+07
n
1.45 y
1.212e+08
1.212e+08
4.70e+02
y
8870

30
31
1,091e+08
n
6.892e+07
n
1.58 9
1.780e+08
1.780e+08
5.43e+02
y
13000

30
40"
1.064e+08
n
6.813e+07
n
1.56 v
1.746e+08
1.746e+Q8
7.39e+02
y
12800

30
47
4.088e+08
n
2.570e+08
n
1.59 y
6.658e+08
6.658e+08
1,94e+03
y
48700

31
or
9.167e+07
n
5.831e+07
n
1.57 y
1.500e+08
1.500e+08
6.32e+02
y
11000

31
1»
2.836e+08
n
1,808e+08
y
1.57 #
4.644e+08
4.644e+08
2.00e+03
y
35400
1,2,3,7,8-PeCDF
31
34
4.355e+08
n
2.752e+08
n
1,58 y
7.107e+08
7.107e+Q8
1.94e+03
y
52000

31
41
4.805e+07
n
3.052e+07
n
1.57 y
7.857e+07
7.857e+07
3.lle+02
y
5750

32
Off
5.973e+0?
n
3.804e+07
n
1,57 f
9.777e+07
9.777e+Q7
4.39e+02
y
7150

32
14"
4.254e+08
n
2.693e+08
n
1.58 y
6.947e+08
6 .947e+08
2.92e+03
y
50800

32
22-
4.4 76c~08
n
2.830e+08
y
1.58 y
7.307e+08
7.3Q7e+08
2.90e+03
y
51500
2,3,4,7,8-PeCDF
32
42*
3.809e+07
n
2.390e+07
n
1.59 f
6.199e+07
6.199e+07
2.55e+02
y
4540

33
28"
4-460e+07
n
2.824S+07
y
1,58 /
7.284e+07
7.284S+07
3.24e+02
y
5330
1,2,3,8,9-PeCDF
Totals
Results

Analytical Perspectives
(Form: TOT]


Totals class: HxCDF EMPC
File Name: 080723P2 Sample
Function: 3 Run #: 8
Sample text: P9464_6042_005 Run# II-
Checkcode: 0780
ACD-M23 1 Air Tr»
/
Acquired: 24-JUL-08 01:53:12 Processed; 24-JUL, 08 13:38:58
Total Cone.: 259020	Unnamed Cone.: 140815.738 Homolog count: 13

RT
ml Resp
mod. ui2 Resp
mod. RA

Resp
Adjjtesp
S/N

Cone.
Name

34
11,
1.317e+O0
n
1.057e+08
y
1.25-%
2.37 4e+ 08
2.374e+08
2.31e+03
y
20200
1,2,3,4,6,
8-HxCDF
34
29
4.518e+08
n
3.617e+08
n
1.25
y
8.135e+08
8.135e+08
8.20e+03
y
69300


34
43*
5.185e+07
n
4.109e+07
n
1.26
y
9.294e+Q7
9.294e+07
8.13e+02
y
7920


34
59
7.134e+07
n
5.639e+07
n
1.27
*
1.277e-08
1.277e+08
1.18e+03
y
10900


35
09,
3.365e+07
n
2.616e+07
n
1.29
x
5.982e+07
5.982e+07
5.82e+02
y
5100


35

1.723e+08
n
1.380e+08
n
1.25
t)
y
3.103e+08
3.103e+08
3.08e+03
y
26400


35
41*
1.832e+08
n
1.465e+08
y
1.25
y
3.297e+08
3.297e+08
3.25e+03
y
27800
1,2,3,4,7,
8-HxCDF
35
50.
2.152e+08
n
1.711e+08
y
1.26
X
3.863e+08
3.863e+08
3.61e+03
y
29600
1,2,3,6,7,
8-HxCDF
36
0CK
3.819e+07
n
2.987e+07
n
1.28
y
6.8Q7e+07
6.807e+07
5.93e+02
y
5800


36
0*.
4.432et07
n
3.434e+07
n
1.29
J
7.866e+07
7.866e+07
7.98e+02
y
6700


36
16.
5.676e+07
n
4.458e+07
n
1.27

1.013e+08
1.013e+08
1.00e+03
y
8640


36
29»
2.096e+08
n
1.645e+08
y
1.27
f
3.740e+08
3.740e+08
3.53e+03
y
30500
2,3,4,6,7,
8-HxCDF
37
30«-
5.539e+07
n
4.342e+07
y
1.28

9.881e+07
9.881e+07
7.05e+02
y
10100
1,2,3,7,8,
9-HxCDF
Totals
Results

Analytical
Perspectives
[Form: TOT]



Totals class: HpCDF EHPC
File Name: 080723P2 Sample #:
Function:
Sample text:
4 Run #: 8	Checkcode: 0780
P9464 6042 005 Run# II-ACD-M23-1 Air Tr»
-------
OPUSquan on MMl 26-JUL-2008 11:20
Acquired: 24-JUL-08 01:53:12 Processed: 24-JUL-Q8 13:38:58
Total Cone.: 78446	Unnamed Cone.: 28797.3S8	Homolog count: 4
RT
ml Resp mod. m2 Resp mod. RA

Resp
Adj_Resp
S/N

Cone.
Name
39:0ft,
2.278e+08 n
2.201e+08 y
1.04
5»
4.480e+08
4.480e+08
8.15e+03
y
41000
1,2,3,4,6.7,8-HpCDF
39:2§.
7.379e+07 n
7.139e+07 n
1.03
y>
1.452e+08
1.452e+Q8
2.64e+03
y
14900

39:36,
6.926e+07 n
6.584e+07 n
1.05
/
1.351e+08
1.351c > 08
2.23e+03
y
13900

40:5^,
3.713e+Q7 n
3.675ei07 y
1.01
r
7.388e+07
7.388ei07
1.18e+03
y
8660
1,2,3,4,7,8,9-HpCDF
-------
File: 08072 JP2*~~Scql 5T3-JUL-2008 01:03:12 GC EI+ Voltage SIR Auto spec -U11 lmaE
Sample# 8 Text: P9464 6042_00S Runt II-ACD-M23-1 Mr Train Vial# 37 File Text: AP DBS
316.9824 S:8 PKD(5.5,3,100.00%,7S0.0,0.00%,F,F) Expt: DF_CL4-8
100%,
23:57
24 :58
27 :24
28:45 29:10
28:07
20:17
21:00	22:00	23:00	24:00
366.9792 S:8 F:2 PKD<5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4
30:58
25:00
26:00
27 :00
28:00
29:00
Time
1001,
3°:08 30:25
30:47
31:36 31:52
32:16 __ _ , 32:32 AQ
- 32:24 r 32:49
33.16 33:29 33:41 33:53
29:39 29:50 30:02
30:00	31:00
380.9760 S:8 F:3 PKD(5,5,3,100.00%.750.0,0.00%,F,FI Expt: DF_CL4-8
32: 00
33:00
Time
1001,	34:30
34:47
i:07 35:18
36:00
37:18
37:56 38:13, 38:23
36:57
37 :26
35:00	36:00
430.9728 S:8 F:4 PKD( 5,5,3,100 - 00%,750.0,0.00%, F, F> Expt: DF_CL4~8
37:00
38: 00
100^38:36 „3fi.47_
80j
60.
40j
20.
39:05 39:16
39 :37
41:17
39:53 40:06 «0:17 40:27 40:39 49i|1 41:02	t41:21
41:43 41:53
-i-,-,—. i | i * " i i | " i
41:12 41:24 41:36
Time
1E6
2E6
4E6
6E6
.1E5
38:36 38:48 39:00 39:12 39:24 39:36
39:48
454.9728 S:8 F:5 FKD( 5, 5» 3 .100 . 00%, 750 . 0, 0. 00%, F, F) Expt: DF_CM 8
4b! 00' ' *40 ' 12' ' 40:24' ' 40136' ' 40 UY ' 41! Qo'
100% 42:09
80
60,
40.
20.
42:2^ 42:29
42:4^2:51
43 :05
43:16
,,.43:49
43:45r dl-Sfi
44:18
"I 44:25 44:33 44:43
41:48 42:00 Time
45:00
8E6
1E6
3E6
5E6
6E5
42:12
42:24
42:36
42:48
43:00
43:12
43'24'
' 43:36'
'43!48'
44:00
44:12
44:24
44:36
44:48
45:00 Time
-------
File: 080723P2Acq: 24-JUL
Sample# 8 Text; P9464_6042.
319.8965 S:8 BSUB(10000,15, ¦
-2008 01:bJ:
.005 Run# II
•3.0) Expt:
Tl GC EI+ Voltage SIR Autospec-UltimaE
ACD-M23-1 Air Train Vial# 3? File Text: AP DBS
DF_CL4-8 Noise: 26SS
21: 00
327.88S0 S:8 3SUBI10000,15 ,
100S,
80.
60.
40j
20.
22 :00
-3.0) Expt:
23:00	24:00
DF CL4-8 Noise: 1312
25:00
26:00
27:00
27:08
A1 . 59F.7
28:00
29:00
23:14
A9.08E5
——r
25:23
A8.38E5
26:03
A4.35E5
-I		r
26:00
26:50 I 27:30
A6.97E51 \A5¦33E5
28:54
A5.96E5
-i		r-
29:00
1.7E7
1.4E7
1.0E7
9E6
3.5E6
23:14
25:23
27:30
A5-.06E7
26: 51
A7.23E7
27:0
26:26 / \A3 , 0vE7
A2-49E7	A 07:38
1.36E7
26:03
A4.31E7
56E7
24:05
A2.49E7
28:10
Al.58E7
25:5
24:56
A2.76
28:00
29:00
24:00
25:00
26:00
27:00
22:00
0) Expt
23:00
DF CL4-M NOise
23:14
21:00
321.8936 S:8 BSUB(10000,15
1273
25:23
2.2E7
27:30
1.8E7
26:51
A9.22E7
27: 09
26:25 MA3.89E7
A3.18E7 M A 1P73I7 A2.02E?
A6.44E7
26:02
23:37
A5.82E7
1.3E7
A5.49E7
24: 05
A3.17E7
r
8.8E6
28:10
25:5
4.4E6
24:56
A3 .59 0*6
Time
3.8E6
3.0E6
2.3E6
1.5E6
7 . 5E5
21:00
331.9368 S:8 BSUB(10000,15,
100%,
80.
60.
40.
20.
22:00	23:00	24:00
-3.0) Expt: DF_CL4-B Noise: 1100
23:11
Al.55E7
25:00
26:26
A1.67E7
27:00
27 :07
Al.55E7
28:00
Time
3.8E6
3.0E6
2.3E6
1.5E6
7 -5E5
21:00
333.9339 S:8 BSUB(10000,15,
100%,
80.
60.
40.
20.
22:00	23:00
-3.0) Expt: DF_CL4-8 Noise:
24: 00
1124
25:00
26:00
27:00
27:07
28:00
29:00
23:11
A1.91E7
26:26
A2.03E7 A1.87E7
Time
4.7E6
3.8E6
2.8E6
1.9E6
9.4E5
21:00
22:00
23:00
24! 00
25:00
26:00
27:00
28:00
29:00
Time
-------
9. f.5.31 -e 3* /ZccDp* kZ?
File; 080723P2—Acq: 24-JUL-2008 01:53:12—GC EI+ Voltage SIR Autospec-UItimaE
Sample# 8 Text: P9464„6042_005 Run# II-ACD-M23-1 Air Train Vial# 37 File Text: AP DB5
355.8546 S:8 F:2 3SUB (10000 ,15,-3 . 0) Expt: DF_CL4-8 Noise: 3959
100*
80.
60.
40.
20.
30:09
Al.B3E8
30:41
A2.61E7
31:33
A9.43E7 31:49
A1.14E8
32 :12
A6.71E7
32:43
A8.34E7
32:49
67E7
1 *z. Expt: DF_CL4-8
32:00
33:00
34:00 Time
32:32 22:49
32:16
30:58
33-16 33:29 33:41 33:53
2. 2E6
30:08 30-25
"I 32:24
30:47
31:36
31: 52
31:20
29:50 30:02f
29:39
1.7E6
1.3E6
9 . 3E5
30:00
31:00
32:00
33:00
34:00 Time
-------
File: 080723W Acq: 24-JUL-2008 01:53:12 GC EI+ Voltage SIR AutOSpec-UltlmaS
Sample# 8 Text: F9464_6042_005 Runi TI-ACD-M23-1 Air Train Vial# 37 File Text: AP DBS
389.8156 S:8 F:3 BSUB(10000,15,-3.01 Expt: DFCL4-8 Noise: 4833
35:55
100%.	35: 37 A1.$8E8
„„1	A1.21E8
O U-
60.
40.
20.
34:56
A7.66E7
AB.18E7
/eh46 ^,	/
S.27E7 36:59 /
"1 A4 .90E7
.4.1E7
l3 . 3E7
.2.5E7
.1.7E7
.8.3E6
35:00	36:00
391.8127 S:8 F:3 BSUBf10000,15,-3.0i Expt: DF_CL4-8 Noise: 4013
35: 55
1001,	35:37 A1.52E8
803	A9-75E7
60i
40.
20.
34:56
A6 .17 E7
6:02
. 78E7
37:00
ifi ar 36:59
36:46 A3.99E7
A4.29E7 r
38:00
Time
3.3E7
.2.6E7
.2.0E7
1.3E7
.6. 6E6
401.8559
100%,
80.
60.
40.
20.
35:00	36:00
S:8 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1834
37:00
36:46
Al.§1E7 37:04
A1.75E7
38:00
Tune
5.0E6
4.0E6
3.0E6
2.0E6
1.0E6
35:00
403.8530 S:8 F:3 BSUB<10000,15,-3.0)
100k
80i
60.
40.
20.
Expt: DF_CL4-8
36:00
Noise: 2096
37: 00
36:46
A1.40E7 37;04
A1.40E?
38:00
Time
.4 . 0E6
.3 -2E6
.2 . 4E6
.1 .6e6
.8. 0E5
35:00
380.9760 S:8 F:3 PKD(5,5,3,100.00%,750.0,0.00%, F, F)
34:23
36:00
Expt: DF_CL4-
37 :00
38:00
38; 13
Time
37:56
38:23
36:00
36:57
37:26
5.7E6
1.4E6
35:00
36:00
37:00
38:00
Time
-------
File: 080723P2 Acq: 24-JUL-2008 01:53:12 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 8 Text: P9464_6042_005 Run# II-ACD M23-1 Air Train Vial# 37 File Text: AP DBS
423.7767 S:8 F:4 3SU3(10000,15, 3.0) PKD(5,5,3,0,10%,750.0,0.00%, F, F) Expt: DF CL4-8 Noise: 16889
,, /
100^	A1 96E8	A2'-40E8
80.
60.
40.
20.
i j j i i i i i > i | i j i i i i t i
40:24 40:36 40:48 41:00
Noise: 12695

6 . 4E7
S.1E7
3 . 8E7
2 . 6E?
1.3E7
I 1 1 I 1
38:36
38:48 39:00 39;12 39i24 39^36 39:48 40:00 40:12
425.7737 S:8 F:4 BSUBUOOOO, 15,-3 . 0) PKD«5,5»3,0.10%,750.0,0,00%,F,F) Expt: DF_CL4-8
40:17
i,
100s
soJ
60i
40i
20i
39:26
A1.87E8
41:36 41:48 42:00 Time
_6.1E7
4 . 9E7
3 . 7E7
2.4E7
1.2E7
38:36
435.8169 S
100%
80i
60i
40i
20i
38:48
39:00 39:12 39^24 39:36 39:48 40:00 40:12
F:4 BSUB(10000,15, 3.0) Expt: DF_CL4- 8 Noise: 1638
40:16
A1.47E7
40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42100 Time
38:36
437.8140 S:
lOOi
80i
60.
40.
20.
~T~
-r
4.0E6
3-2E6
2.4E6
.1.6E6
.7 , 9E5
38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12
3 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1898
40:16
A1.40E7
40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:4?
38:36
430,9728 S:
42:00 Time
.3.8E6
13.1E6
.2.3E6
Ll. 5E6
L7.6E5
38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12
5 F:4 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
40:24
' i I i "
40:36
40:48 41:00
' ¦ i 1 1 1 1 r'	
41:12 41:24
41:36 41:48 42:00 Time.
39:53
40:06
40:27 40:39 40:51 41:02
41:17
n41:21
41:43 41:53
38:47
39:16
nn
39:36
40:00
40:12
40:24
40:36
40:4
39:12
39:24
39:48
39:00
38:36 38:48
41:00 41:12 41:24 41:36 41:48
4.1E6
3.2E6
2.4E6
1.6E6
8.1E5
!: 00 Time
-------
/
Acq: 24-JUL-2008 01: 53 :12 ~~GC EI+ Voltage SIR Aut o spec-U11imaE
Sample# 8 Text: P9464_6042_005 Run# II-ACD-M23-1 Air Train Vial# 37 File Text: AP DBS
457.7377 S:8 F:5 BSUB(10000,15,-3.0) PKD{5,5r3,0.10%,750,0,0.00%,F,F) Expt: DF_CL4-8 Noise:
43 :S2
10 OS,	A6.&7E8
80.
60.
40.
20.
845
—I—I—'—|—'—i—I—'	1	[	'—1—1—I—I—|—1	1	1—1	1	1	1 I—I—I—I—|—>-1	'	'—| ' > 1 "| • '
42:12 42:24 42:36 42:48 43:00 43:12 43:24
459.7348 S:8 F:5 BSUB(10000,15,-3.0) PKD(5,5,3,0.10%,750.0,0.00%, F, F)
1001,
80.
60.
40.
20.
43:36 43:48 44:
Expt: DF_CL4-8 Noise:
43:52
A7.79E8
00
715
-I—1—|—I	1	1	1	!	["
44:12 44:
24
44:36
43:48
43 : 51
44:48
'44!48'
1.5E8
1.2E8
9.1E7
6.0E7
3 . 0E7
45:00 Time
-1.7E8
L1.4E8
Ll.0E8
.6 . 8E7
.3.4E7
42 :12 ' 42 ! 24 ' 42 I 36 42! 48 43 ! 00 43 112 -43:24
469.7780 S:8 F: 5 BSUB (10000,15,-3.0) Expt: DF_CI,4 8 Noise: 1358
1001,
80.
60.
40.
20.
43:36
44:12
44:24 44:36
45:00 Time
_4.4E6
3 . 5E6
l2.6E6
1.8E6
8.8E5
42:12 42:24 42:36 42:48 43:00 43:12 43:24
471.7750 S:8 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 933
lOOSs,
80.
60.
40.
20.
' 43\36'
43:48
44:00
44:12
44:24 44:36
43:51
A2-37E7
44:48
45:00 Time
.5.0E6
.4 . 0E6
13.0E6
,2.0E6
.1.0E6
45:00 Time
42:12 42:24 42:36 42:48 43:00 43:12 43:24
S:8 F:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
43:36
43:48
44:12
44:18
24 44:36
44:48
454.9728
~ 43 : 49
43:45 r 43:56
45:00
42:46 ..
-i 42:51
42 : 24
=1 42:29
:25 44:33 44
43:05
43:16
2.3E6
42:12
42:24
42:36
42:48
43:00
43:12
43 :24
43:36
43:48
44:00
44:12
44:36
44:48
Time
-------
File: 080723P2 Acq: 24-JUL-20Q8 01:53:12 GC EI+ Voltage SIR Autospec UitunaE
Sample# 8 Text: P9464_6042_005 Runl II-ACD-M23-1 Air Train Vial# 37 File Text: AP DB5
303.9016 S:8 BSU3(10000,15,-3.0) Expt: DF_CL4-8 Noise: 27682
21:00
315,9419 S:8 BSUB(10000,15,-
22:00
3.0) Expt:
23: 00
DF_CL4-8 Noise:
24:00
1601
25:00
100*
80.
60.
40.
20.
20:59
A2.53E7
24:45
A2.75E7
26:00
26 :13
A2.38E7
27:00
28:00
29:00
1.5E8
1.2E8
9E7
6.0E7
3.0E7
26:37
A6.56E8
22:48
A8.18E8
23:14
A3.51E8
24:47
25:16
AS.15E8
A3.77E8
26:1
A2.3Jffi8
24 :23
23:59
21:01 ... ...
A1 7 1F.8 ^ J-: J 4
A1.
22:14
A1.42E8
A
A2.02E8
26:53
28:21
A3-43E7

29: 00
27 :00
28:00
26: 00
23:00
DF CL4-8
24:00
25 : 00
21: 00
BSUBf10000, 15
22 : 00
3.0) Expt
33247
Noise
305.8987
26:37
1.9E8
A8.41E8
1.5E8
22:48
A1.04E9
23:14
A4.45E8
24:47
25:16
A4.79E8 25:59
r	A3.10E8
r
1.1E8
A6.50E8
24:23
7. 6E7
23:59
A2.58E8
21:01
A2^°E8 A1 56E8
22:14
A1.82E8
3.8E7
26:53
6^20E7
28:21
A4.43E7
Time
Time
.5.4E6
.4. 3E6
.3.3E6
.2.2E6
.1.1E6
21:00	22:00	23:00	24:00
j317 . 9389 S : 8 BSUB (10000,15,-3 .0) Expt: DF_CL4-8 Noise: 1737
100%
80j
60..
40 i
20i
25:00
26:00
27:00
28:00
29:00
20: 59
A3.18E7
A


24:45
A3.48E7
1
26:13
A2.95E7
1



-i	1	|	"		'	'	'	r "I	>	'	
21:00 22:00
:8 BSUBI10000,15,-3.0) Expt:
23! 00
DF_CL4-8 Noise:
24:00
697
25:00
26:00
27 5 00
28: 00
29 ! 00
Time
.6.9E6
.5.5E6
L4.1E6
1.2 .7E6
Ll.4E6
375.8364
100%
80.
60.
40.
20.
26:21
A3.51E6
28:10
A2.91E7
*29 : 00
Time
5.2E6
4.2E6
3.1E6
2.1E6
.1.0B6
21:00
22:00
23:00
24:00
25:00
26:00
27:00
28:00
Time
-------
File: 080723P2 Acq:'24-JUL-2008 01:53:12 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 8 Text: P9464_6042_005 Run# II-ACD-M23-1 Air Train Vial# 37 File Text: AP DB5
339.8597 S:8 BSUB(10000,15,-3.0) PRD(5,5,3,0.10%,750.0,0.00%,F,F) Expt: DF_CL4-8 Noise: 1090
100%
9o|
8oJ
70 j
60 J
503
4oJ
3o|
2oJ
loj
28:18 j
A3.46E8
29:25
A7.95E6
~l
			
.7 . 3E7
.6.6E7
.5.9E7
L5,1E7
_4 . 4E7
i_3. 7E7
.2 . 9E7
L2.2E7
LI. 5E7
.7 .3EG
21:00	22:00	23:00	24:00	25:00
341.8568 5:8 BSUB(10000,15, 3.0) PKD{5,5,3,0.10%,750.0,0.00%,F,F) Expt: DF_CL4-
loot
9o|
8oJ
701
6o|
5o|
40|
3 o|
2oj
ioj
26:00
Noise: 940
27 :00
28:00
28:18
A2.00E8
29:00
Time
4.2E7
3.8E7
3.4E7
3.0E7
2.5E7
2.1E7
1,7E7
1 .3E7
8.5E6
4.2E6
'»'	f	'I'"
—r—r	i—t	r~
""i	i	r-
21:00	22:00	23:00	24:00
316.9824 S:8 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
2S: 00
26:00
27:00
28:00
100%
90i
80.
7 0.
60.
50.
40.
30.
20.
10.

20:17 20:53 21:40 21;58 22.26 23 : 08 23 : 3^ ' " 242;41J[118 2i'^\	26:00 26:25
29:00
45 29:10
Time
27:24
27:02 •"1 27
41 28:07
21:00
22:00
23:00
24! 00
25:00
26 ! 00
2.2E6
1.9E6
1.7E6
1.5E6
1. 3E6
1 . 1E6
8.6E5
6.5E5
4 . 3E5
2.2E5
27:00
28:00
29:00
Time
-------
File; 080723P2 Acq; 24-JUL-2008 01:53:12 GC THT" Voltage SIR Autospec-UltiiraE	
Sample# 8 Text: P9464_6042_005 Run* II ACD-M23-1 Air Train Vial# 37 Pile Text:
339.8597 S:8 F:2 BSUB(10000,IS,-3.01 Expt: DF_CL4-8 Noise: 78668
30:04
29:56
30:46
M.09E8
A6.25E8
70E8
30:4
A1.06E8
17E7
31:00
A9.17E7
31:30
A4.35E8
A2.84E8
31:41
4.81E7
AP DB5
„ .. 32:22
A4.4BE8
A4 .25£8 r
32:06
32:42
A5.97E
A3.81E7
33:28
A4.46E7
.1.4E8
.1.2EB
.8.6E7
.S.8E7
.2 , 9E7
30:00
341.8568 S:8 F:2 BSUB(10000,15,-3,0) Expt
oo 30:04
29:56 j, a oqro
31:00
DF_CL4-8 Noise: 45720
32:00
33:00
30:00
351.9000 S : 8 F:2 BSUBUOOOO, 15,
1001,
80.
60j
40.
20,
Expt;
30:39
A3.16E7
31:00
DF CL4-8 Noise: 3364
32:00
33:00
31:12
A3.16E7
32 loo
32:21
34:00 Time
32:22
32:14 A2.83E
A2.69E8 r
. 2E7
100S
A3.96E8
7.3E7
31:13 31:30
A1.81E8 A2.75E8
30:46
5.5E7
A2.57E8
10
02E8
0:16
. 95E7
3.7E7
30:4
A6.81
31: 00
A5.83E7
32:06
A3.80E
33:28
A2.82E7
zx
31:41
32:42
A2.39E7
1.8E7
05E7
34:00 Time
.8.9E6
L7.1E6
.5.3E6
L3.5E6
L1.8E6
30:00
353.8970 S:8 F:2 BSUB(10000,15,
100S,
80.
60.
40.
20.
30:39
A2.00E7
31:00
Expt: DP_CL4-8 Noise:
31:12
A1.98E7
33:00
3849
32:21
A2.02E7
34:00 Time
.5. 7E6
a.me
,3 . 4E6
.2.3E6
.1.1E6
30:00
409.7974 S:8 F:2 BSOB(10000,15,
100%,
80.
60j
40.
20,
-3.0) Expt:
31:00
DF_CL4 8
32:00
33:00
Noise: 1257
A
30:00
31:00
32:00
33:00

33:50
A3.04E6
34:00 Time
8.7E5
6.9ES
5.2E5
3.5E5
1.7ES
34:00 Time
-------
File: 080723P2 Acq: 24-JUL-iMff
Sample# 8 Text: P9464_6042_005
373,8207 S:8 F:3 BSU8(10000,15,
34:29
1001,	A4
80.
60.
40.
20.
01:53:12 GC EI+ Voltage SIR Autospec-UltimaE
Run#
3.0)
II-ACD-M23 1 Air Train
Expt; DF_CL4-8 Noise:
Vial#
92341
37 File Text; AP DB5
A1.32E8
. 18E7
35:41/
A1.83E? A2.15E8
/
36:29
A2.10E8
/
34:55
A7^13E7
35:09
A3.37E7
r
Q- 	
¦ 00 36:16
P,H7 A5.68E7
B2EVv /V,
1.3E8
1.1E8
8.1E7
5 . 4E7
2 . 7E7
35:00
375,8178 S:8 F:3 SSU3(10000,15,-3.0)
34:29
A3.62E8
Expt: DF_CL4 - 8
36:00
Noise: 89328
37:00
383 .
100%,
80.
60.
40.
20.
35:00
8639 S:8 F:3 BSUB(10000,15,-3.0)
36: 00
6107
35-41 35:49 36:08
A1.38E7A1.60E7 A1.53E7
37 :00
Expt: DF_CL4-8 Noise:
385.8610 S:f
100%,
80.
60.
40 4
20.
35:00
F: 3 BSUBdOOOD, 15,-3.0)
36:28
A1.45E7
37:27
A1.22E7
Expt: DF_CL4-8
35:41 35:49
A2.59E7 A3.00B7
1
36:00
Noise: 2894
36:
A2. j
37:00
36:28
A2.74E7
35:00	36:00
445.7555 S:8 F:3 BSUB{10000,15,-3 . 0) Expt: DF_CL4-8 Noise: 1408
37: 00
37:27
A2.29E7
38:00
38:00
38:00
38:00
Time
1, IE
B.7E7
6.SE7
35:41
A1.46E8 ai 7^e8
36:29
A1.64E8
34:16
A1.06E8
34:43
35:09
A2.62E7
r
34:55
A5.64E7
/\
36:16
37:30
A4.34E7
2.2E7
36:00
. 11E7
A2.99E7 A4-i6E7
Time
4
5E6
l3
6E6
r2
7E6
Li
8E6
L8
9E5
Time
.8. 5E6
.6. 8E6
.5.1E6
.3.4E6
.1.7E6
Time
35:48
1.8E5
100%
1 .5E5
1.1ES
35:35
36:58
7 . 3E4
37:37
3.6E4
7i56 38:09 38:19
34:29 34:55 TS-m
r 34:42 "I	35:14
34:08
34:21
35:00
36:00
37:00
38:00
Time
-------
/
File: 080723P2 Acq; 24-JUL-2008 01:53:1:2 GC EI+ Voltage SIR Autospec-UItimaE
Samples 8 Text: P9464 6042_005 Run# II-ACD-M23-1 Air Train Vial# 37 File Text:
407.7818 S:8 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 35932
AP DBS

6.9E7
80i
5.5E7
. 1E7
60j
39:26
A7.38E7
12.7E7
40.
ll.4E7
20j
41:00 41:12 41:24 41:36 41:48 42:00 Time
39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:4
38:36
38:36 38:48 39:00 39112
409.7788 S:8 F:4 BSUB(10000,15,-3
39:06
lOOSs,	A2.J0E8
80.
60.
40.
20.
39:24 39:36 39=48 40:00 40:12 40i24 40:36 40:48 41:00
.0) PKD(5,5,3,0.10%,750.0,0.00%,F,F) Expt: DF_CL4-8 Noise: 9752
39-26 39:36
A7.14E7 R6.58E7
1 ' I 1 ' ' 1 1 I ' J 1 ' 1 i ^
38:36 38:48 39:00 39:12
417.8253 S:8 F:4 BSUB(10000,15.-3.0)
39:05
100%,	A9.49E6
80.
60.
40,
20
38:36 38:48 39=00 39=12
419.8220 S:8 F:4 BSUB(10000,15,-3.0)
39:05
1001,	A2.10E7
80i
60j
40j
20i
40:52
A3.67E7
t~
6.BE7
5.4E7
4.1E7
2 .7E7
1.4E7
39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
Expt
39:35
A8.98E6
DF CL4-8 Noise: 3871
39:24
40: 51
A7.89E6
39:36 39
Expt: DF_CL4-8
39:35
A2.01E7
48 40:00
Noise: 4293
2 . 8E6
2 .2E6
1.7E6
L1.1E6
5 . 6E5
40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
40:51
Al.73E7
_6, 2E6
i4 . 9E6
L3.7E6
L2.5E6
11.2E6
38:36 38:48 39:00 39;12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00
479.7165 S:8 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 2276
lOOi,
80.
60.
4 0.
20J
39:32 39:40
40:23
41:12 41:24 41:36 41;48 42:00 Time
8.1E5
6.5E5
.4 . 9E5
3.3E5
1 . 6E5
41j23 4jU|jL 41:42
38! 36	48 ' *39 ! oo' ' '39:12' ' '39S24' 39'36 ' 39! 48 40 1 00 * '40:12'4o!24 40 = 36 40 = 48 41:00
41:12 41:24 41:36 41:48 42;00 Time
-------
/
File; 080723P2 IcqT~2T^JTOr2OTB~!jlTr5T7n GC EI- Voltage SIR Aut o spec-Ui timaE
sample# 8 Text: P9464_6042_00S Run# II-ACD-M23-1 Air Train Vial# 37 File Text: AP DB5
441.7428 S:8 F:5 3SUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 3234
100*
80,
60.
40.
20.
44:06
A5. J.0E7
' ' | ' i i ' i I i 	
43:36 43:48
Expt: DF_CL4-8
44:24
T | 1 I
44:36
.1.1E7
L8.6E6
.6.4E6
.4.3E6
i.2.1E6
' ' ' | ' ' ' ' ' | 1 ' ' ' ' I 1	'	
42:12 42:24 42:36
443.7398 S:8 F:5 BSUB(10000,IS,-3
1001,
80.
60.
40.
20.
42:48
0) FKD(5,5
43:00 43:12 43:24
«3,0.10%,750.0,0.00%,F,F)
44:00 44:12
Noise: 1022
44:06
A5.71E7
42 :12 42!24 42 = 36 42 E 48 43:00
453.7830 S:8 F:5 BSUB(10000 ,15 , -3.01 Expt: DF_CL4-8
-i—i—j—
100SS,
80.
60.
40.
20.
43:12
Noise:
43:24
1118
' ' I 1 1
43:36
i—!—r—T—r
43:48
44:00
44:12
1 1 I ' '
44:24
44:36
44:06
A2.86E7
	44:24
44:48
44:48
45:00 Time
1.2E7
9 .726
.7 . 3E6
.4 . 8E6
.2 .4E6
45:00 Time
_6
2E6
:. 4
9E6
L3
7E6
_2
5E6
Ll
2E6
—?	r—i—i
42:24
•11 r*1"
42:36
42 :12
455.7801 S:8 F:5 BSUBI10000, 15
100S
80i
60i
40i
20j
42:48 43:00 43:12 43:24
3.0) Expt: DF_CL4-8 Noise: 1604
1 1 I ' '
43 :36
43:48
44 :00
44:12
44:36
44:06
A3.09E7
44:48
45:00 Time
.6.7E6
.5.3E6
14.0E6
.2 . 7E6
.1.3E6
44:24 44:36 44:48 45:00 Time
42:12 42:24 42:36
513.6775 S:8 F:5 BSUB(10000,15,-3
42:48
.0) Expt:
43:00
DF CL4-8
•13 :12
Noise:
43:24
759
43:36
' 43 I 48 '
;00' ' '44:12
44 :10
100%.
44:37
44:47 44:59
1
42:12
42:24
42:36
42:48
43:00
43:12
43:24
43:36
43 :48
44:12
44:24
2.8E4
t-2. 3E4
1.7E4
1.1E4
5.6E3
44:36 44:48 45:00 Time
-------
OPUSquan on MM 26-JUL-2008 11:19
checkcode

"7?r?o'/A4^0Si
1613/8290 Sanple Summary
Analytical Perspectives
Client
Lab ID:
Sample
Typ
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax2
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax
Ax2
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
ES
cs
cs
cs
cs
cs
NA
JS/RT
JS
JS/RT
ID:
/
Run# II-ACD M23-2
P9464_6042_006 ^	GC
text: P9464_6042	006 Run# II-ACD-M23-2 Air Train
Name
2,3,7,8-TCDD
1.2,3,7,8-PeCDD
1,2,3,4,7,8-HxCDD
1.2.3.6.7.8-HxCDD
1.2.3.7.8.9-HxCDD
1,2,3,4,6,7,8-HpCDD
OCDD
OCDD-a
1
2
1,2
1.2
2.3
1,2
1,2,3
1,2,3
4,7
6,7
6.7
7.8
6.7
7.8
13C-2,3,7,8-TCDD
13C-1.2
13C-1,2,3
13C-1
13C-1
13C-1,2
,2,3,
13C-2,3,7,8-TCDF
13C-1,2
13C-2
12C-1.2
13C-1,2
13C-2,3
13C-1,2
13C-1,2,3
13C-1,2,3
8-PeCDF
8-PeCDF
8-HxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8-HpCDF
9-HpCDF
13C-OCDF
37C1-2,3,7,8-TCDD
13C-1,
13C-1i
13G-1,2,
13C-1,2,3,
2,3,4,7 PeCDD
2,3,4,6 PeCDF
3,4,6,9-HxCDF
4,6,8,9 -KpCDF
n/a
Resp
2,3,7,8 TCDF
3,7,8-PeCDF
4,7,8-PeCDF
8-HxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8-HpCDF
9-HpCDF
OCDF
OCDF-a
89e+07
53e+Q8
73e+07
20e+08
14e+08
1.07e+09
3.77e+09
2.35e+08
7.65c t 08
5.44e+08
8.48e+08
3.65e+08
3.98e+08
3.79e+08
9.13e+07
4.66e+08
6.52e+07
1.18e+08
7.00e+06
3, 7,8-PeCDD
4,7,8-HxCDD
6,7, 8-HxCDD
2, 3, 7, 8,9-HxCDD
3,4,6,7,8-HpCDD
13C-OCDD
13C-1,2,3,4-TCDD
13C-1,2,3,4-TCDF
13C-1,2,3,4,6,7 -HxCDD
4.58e+07
4.19e+07
3.74e+07
4.35e+07
4.32e+07
4.03e+07
6.34e+07
7,03e+07
6.79o+07
6.90e+07
5.43e+07
6,24e+07
5.62e+07
4.88e+07
4.26e+07
3.50e+07
8 -46e+07
2.01e+07
4.38e+07
6.61e+07
5.58e+07
3.91e+07
4.70e+07
7,73e+07
2.12e+Q7
Filename: 080723P2 S
column ID: db-5	Cal
Stds
3
RA
0,79
1.58
1.23
1.24
1.26
1.05
0. 89
2.49
0.79
1.58
1.58
1.25
1.24
1.22
.27
.03
.05
.89
.42
0.83
1.62
1.27
1.29
1.33
1.04
0.68
0.81
1.56
1.58
0.53
0.55
0.54
0.53
0 .44
0 .44
0.92
1.46
1.55
0.S4
0.46
RT
27:09
32
36
36
37
40
43
43
26
31
32
35
35
36
37
39
40
44
44
../i
43/ 1
40^" 1
47/ 1
05 V 1
17-^,0
53 * 1
53 0
13'^/1
l/, 1
23/ 1
42^ 1
50^ 1
29^" 1
30^ 1
07/ 1
52 y1
07 f 0
07 0
27:07
32
36
36
37
40
43
42
39
46
05
16
52
RRF
09
00
10
00
03
98
08
07
17
02'
09
20
13
17
12
43
35
94
05
96 1
84
91
01
98
91
0.83 y
0.80 y
1.30 y
NotF»
26:26
24:45
36:58
1.36
[Form: DF]
9 Vial: 38
JS (split adj.): 4000
Cone.
0.85
44:06
0.93
0.99
7100
14500
7520
11000
10300
108000
439000
434000
37300
31400
45200
22500
22500
23000
6700
30500
5520
11900
'13000
4080
4240
3870
4060
4180
4180
8750
3920
4090
4060
4090
4040
3900
3610
3870
3880
7890
1570
4180
3660
3780
3720
175
183
94 .2
Noise Fac
Acq: 24 JUL Q«
Wt/Vol: 1.000
CS/SS: 1600
DL
/
02:44^)5
3454
6502
3337
3337
3337
9962
6021
8120
3847
9695
9695
17386
17386
17386
17386
9498
9498
14516
2951
5792
61409
24904
24904
24904
5937
8016
9831
14080
14080
8775
8775
8775
8775
15166
1S166
10079
61409
14080
8775
15166
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2,
2.
2.
2.
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
2.5
3536 2.5
ES:^flOO
Rec
5.37

-
15.0

-
6.39

-
6.75

-
6.97

-
19.7

-
17.7

-
377
/
_

3 .76
-
13 .8

-
11.9

-
14.6

-
14.0

-
14.5

-
19.9

-
7.60

-
12.2

-
33.7

-
126

-
10.3

102
124

106
54.8

96.8
49.4

101
51.3

105
13.1

105
23.5

109
12.1

98.0
18.7

102
18.3

102
14.1

102
12.1

101
12.9

97.4
13.8

90.3
29.3

96.8
35.8

96.9
20.0

98.6
10.3

98.0
117

105
17.2

91.6
12.7

94.6
30.7

93.1
5.21

*
/
5792
9831
16768
2.5
2.5
-------
OPUSquan on MM1
26-JUL-2008 11:19
checkcode: 1069
ss
37C1-2,3,7,8-TCDD
2.01e+07


27
09
1.14
/ 1540


9.87
96.1
ss
13C
-1,2,3,4,7-PeCDD
4.38e+07
1.46
Y
32
11
1.06
/ 3940
61409
2.5
134
98.6
ss
13C
-1,2,3,4,6 PeCDF
6.61e+07
1.55
y
30
39
1.09 ^
' 3580
14080
2.5
18.9
89.5
ss
13C-1
2,3,4,6,9-HxCDF
5.58e+07
0.54
y
36
08
0.95
3750
8775
2.5
8.40
93.7
ss
13C-1,2
3,4,6,8,9 HpCDF
3.91e+07
0.46
y
39
36
0.95
3850
15166
2.5
18.2
96.2
SBS

2,4,6,8-TCDF
5.94e+08
0.78
y
22
14
1.17
29000
3847
2.5
3.76
-
Ay

1,3,6,8-TCDD
1.51e+08
0.79
y
23
13
1.09
12000
3454
2.5
5.37
_
Ay

1,2,3,9-TCDD
6.63e+07
0.79
y
26
59
1.09
5290
3454
2.5
5.37
-
Ay

1,2,8,9-TCDD
4.95e+07
0.78
y
28
10
1.09
3950
3454
2.5
5.37
_
Ay

1,2,4,7,9-PeCDD
2.94e+08
1.58
y
30
08
1.00
28000
6502
2.5
15.0
_
Ay

1,2,3,8,9-PeCDD
1.08e+08
1.57
y
33
10
1.00
10200
6502
2.5
15.0
-
Ay
1
2,4,6,7,9 HxCDD
2.16e+08
1.25
y
34
57
1.04
20000
3337
2.5
6.70
_
Ay
1,2
3,4,6,7,9-HpCDD
8.74e+08
1.05
y
39
25
0.98
88100
9962
2.5
19.7
-
Ay

1,3,6,8-TCDF
5.12e+0S
0.79
y
21
00
1.17
25000
3847
2.5
3.76
-
ay

2,3,4,8-TCDF
6.04e+08
0.79
y
26
07
1.17
29500
3847
2.5
3.76
-
Ay

1,2,8,9-TCDP
1.03e+08
0.79
y
28
20 ~1.17
5040
3847
2.5
3.76
_
Ay

1,3,4,6,8-PeCDF
7.34e+08
1.71
y
28
18^ 1.17
35800
2941
2.5
2.87
-
Ay

1,2,3,8,9 PeCDF
8.22e+07
1.59
y
33
28
1.05
4550
9695
2.5
12.8
-
Ay
1
2,3,4,6,8-HxCDF
2.79e+08
1.26
y
34
17
1.15
17400
17386
2.5
15.6
-
Tot
Total Tetra-Dioxins
1.87e+09
0. 79
y
23
13
1.09
149000
3454
2.5
5.37
_
Tot
Total Penta-Dioxins
1.57e+09
1. 58
y
30
08
1.00
150000
6502
2.5
15.0
-
Tot
Total Hexa-Dioxins
1.40e+09
1.25
y
34
57
1.04
129000
3337
2.5
6.70
-
Tot
Total Hepta-Dioxins
1.94e+09
1.05
y
39
25
0.98
196000
9962
2.5
19.7

Tot
Total Tetra-Furans
1.94e+10
0.79
y
21
00
1.17
945000
3847
2.5
3 .76
-
Tot
Total Penta-Purans
8.28e+09
1.57
y
29
55
1.05
458000
9695
2.5
12.8
-
Tot
Total Hexa-Furans
3.31e+Q9
1.26
y
34
17
1.15
204000
17386
2.5
15.6
-
Tot
Total Hepta-Furans
8.02e+08
1.03
y
39
07
1.40
56000
9498
2.5
9.61
-
Tot

TCDD EMPC
1.87e+09
0.79
y
23
13
1.09
149000
3454
2.5
5.37
_
Tot

PeCDD EMPC
1.57e+09
1.58
y
30
08
1.00
150000
6502
2.5
15.0
_
Tot

HxCDD EMPC
1.40e+09
1.25
Y
34
57
1.04
129000
3337
2.5
6.70
-
Tot

HpCDD EMPC
1,94e+09
1.05
Y
39
25
0.98
196000
9962
2.5
19.7
_
Tot

TCDF EMPC
1.94e+10
0.79
y
21
00
1.17
945000
3847
2.5
3.76

Tot

PeCDF EMPC
8.28e+09
1.57
y
29
55
1.05
458000
9695
2.5
12.8
-
Tot

HxCDF EMPC
3.31e+09
1.26
y
34
17
1.15
204000
17386
2.5
15.6
_
Tot

HpCDF EMPC
8.02e+08
1.03
y
39
07
1.40
56000
9498
2.5
9.61
-
AS
13C-1,3,6,8-TCDD
4,43e+07
0.82
y
23
11
0.98
3860
5792
2.5
10.0
96.4
AS
13C-1.3,6,8-TCDF
7.35e+07
0.80
y
20:
59
1.09
3500
9831
2.5
10.3
87.6
DPE

HxCDPE
1.24e+07


28:
10

*


_
_
DPE

HpCDPE
2,47e+06


33:
51
-
*


_
-
DPE

OCDPE
*


NotF»
-
*


-
-
DPE

NCBPE
*


NotF»
-
*


-
-
DPE

DCDPE
*


NotF»
-
*


_
_
LMC

Fnl check, mass
*


NotF»

¦k


_
_
LMC

Fn2 check mass
*


NotF»
-
-k


_
_
LMC

Fn3 check mass
*


NotF»
-
*


-
_
LMC

Fn4 check mass
*


NOtF»
-
*


_

LMC

Fn5 check mass
4


NotF»
-
¦k


-
_

-------
OFUSquan on MMl
26-JUL-2008 11:20
Totals Results
Tocals class: TCDD EMPC
File Name: 080723P2 Sample #
Analytical Perspectives	[Form: TOT]
Function: 1 Run #: 9	Checkcode: 10&9
Sample text: P9464_6042_006 Run# II-ACD-M23-2 Air Tr» /
Acquired; 24-JUL-08 02:44:05
Total Cone.: 149060
Processed: 24-JUL-08 13:38:59
Unnamed Cone.: 120686.087 Homolog count: 17

RT
ml Resp
mod. m2 Resp
mod.
RA
Resp
Adj_Resp
S/N

Cone.
Name
23
13.
6.654e+07
n
8.413e+07
y
0
79 y
1.507e+08
1
507e+08
4.74e+03
y
12000
1,3,
6,8-TCDD
23
3Z|
4.109e+07
n
5.216e+07
n
0
79 y
9.325e+07
9
325e+07
2.88e+03
y
7450


24
05
3.662e+07
n
4.649e+07
n
0
79 ?
8.310e+07
8
310e+07
2.72e+03
y
6640


24
5(T
5.375e+06
n
6.788e+06
n
0
79 y
1.216e+07
1
216e+07
4.06e+02
y
971


25
lh
1.221e+08
n
1.554e+08
n
0
79 n
2.775e+08
2
775e+08
7.76e+03
y
22200


25
23
8.998e+Q7
n
1.13964-08
n
0
79 x
2.039e+08
2
039e+08
7.06e+03
y
16300


25
36
4,579e+07
n
5.813e+07
n
0
79 y
1.039e+08
1
039e+08
3.64e+03
y
8300


25
s2
2.257e+07
n
2.875e+07
n
0
79 J
5.132e+07
5
132e+07
1.89e+03
y
4100


26
03Is
5.294e+07
n
6.756e+07
n
0
78
1.205e+08
1
205e+08
4.31e+03
y
9620


26
26>
3.834e+07
n
4.901e+07
n
0
78 y
8.736e+07
8
736e+07
2.86e+03
y
6980


26
3^
2.693e+07
n
3.390e+07
n
0
79 v
6.083e+07
6
083e+07
2.28e+03
y
4860


26
50
9.364e+07
n
1.190e+08
n
0
79 y
2.126e+08
2
126e+08
5.18e+03
y
17000


26
5?
2.928e+07
n
3.700e+07
Y
0
79 5
6.62 8c 107
6
628e+07
2 -52e~03
y
5290
1,2,
3,9-TCDD
27
09
3.913a+07
n
4.976e+07
y
0
79 J>
8.889e+07
8
889e+07
3.36e+03
y
7100
2,3,
7,8-TCDD
27
301
7.055e+07
n
8.854e+07
n
0
80
1.591e+08
1
591e+08
6.41e+03
y
12700


27
3|
1.992e+07
n
2.589e+07
n
0
77 x
4.581e+07
4
581e+07
1.77e+03
y
3660


28
16-
2.175e+07
n
2.774e+07
y
0
78 y
4.949e+07
4
949e+07
1,94e+03
y
3950
1,2,
8,9-TCDD
Totals
Results

Analytical Perspectives

[Form: TOT]



Totals class: PeCDD EMPC
File Name: 080723P2 Sample #:
Function:
Sample text:
2 Run #: 9
P9464_6042_006 Run# II
Checkcode: 1069
-ACD-M23-2 Air Tr»
/
Acquired: 24-JUL-08 02:44:05 Processed: 24-JUL-08 13:38:59
Total Cone.: 149640
Unnamed Cone,: 96866.454
Homolog count: 10

RT
ml Resp
mod. m2 Resp
mod. RA

Resp
Adj_Resp
S/N

Cone.
Name
30
OS,
1.800e+08
n
1.141e+08
y
1.58 v
2
941e+08
2.941e+08
3.38e+03
Y
28000
1,2,4,7,9-PeCDD
30

4.066e+07
n
2.574e+07
n
1.58 y
6
641e+07
6.641e+07
1.06e+03
y
6320

31
16
1.140e+08
n
7.180e+07
n
1.59 y
1
858e+08
1,858e+08
3.05e+03
y
17700

31
2T
8.496e+07
n
5.355e+07
n
1.59 y
1
385e+08
1.385e+08
2.36e+03
y
13200

31
3-h
9.374e+07
n
5.883e+07
n
1.59 f
1
526e+08
1.526e+08
2.42e+03
y
14500

31
50
1.510e+08
n
9.537e+07
n
1.58 f
2
463e+08
2 .463e+08
2.68e+03
y
23400

32
13
8.215e+07
n
5.137e+07
n
1.60 f
1
335e+08
1.335e+08
2.15e+03
y
12700

32
43'
9.361e+07
n
5.917e+07
y
1.58 y
1
528e+08
1.528e+08
2.63e+03
y
14500
1,2,3,7.8 PeCDD
32
49"
5.831e+07
n
3.644e+07
n
1.60 9
9
476e+07
9 ,476e+07
1.55e+03
y
9020

33
ioT
6.571e+07
n
4.189e+07
y
1.57 y
1
076e+08
1.076e+08
1.72e+03
y
10200
1,2,3,8,9-PeCDD
Totals
Results

Analytical Perspectives
[Form: TOT]


Totals class: HxCDD EMPC
File Name: 080723P2 Sample I: 9
Acquired: 24-JUL-08 02:44:05
Total Cone.: 129340
Function: 3 Run #: 9
Checkcode: 1069
Sample text: P9464_6042_006 Run# II-ACD M23-2 Air Tr»
Processed: 24-JUL-08 13:38:59
Unnamed Cone.: 80484.185	Homolog count: 8
-------
OPUSquar
on MM1
26-
-JUL-2008
LI
20










RT
ml Resp
mod. m2 Resp
mod.
RA

Resp
Adj_Resp
S/N

Cone.
Name
34

1.201e+08
n
9.61le+07
y
1
25

2.162e+08
2
162e+08
8.23e+03
y
20000
1,2,4,6,7,9-HxCDD
35
3t
1.378e+08
n
1.109e+08
n
1
24
y
2.487e+08
2
.487e+08
9.32e+03
y
23100

35
H
2. 489e+08
n
2.014e+08
n
1
24
"y
4.503e+08
4
•503e+08
1.32e+04
y
41700

36
03
3.2S7e+07
n
2.655e+07
n
1
23
y
5.912e+07
5
. 912e+07
1.95e+03
y
5480

36
40
4.262e+07
n
3.473e+07
y
1
23
7
7.735e+07
7
735e+07
3.15e+03
y
7520
1,2,3,4,7,8-HxCDD
36
it
6.675e+07
n
5.371e+07
y
1
24
y
1.205e+Q8
1
,205e+08
4.31e+Q3
y
11000
1,2,3,6,7,8-HxCDD
36
58
6.095e+07
n
4.930e+07
n
1
24
f 1.103e+Q8
1
.103e+08
4.01e+03
y
10200

37
05"
6.374e+07
n
5.058e+07
y
1
26
f 1.143e+08
1
•143e+08
4.05e+03
y
10300
1,2, 3,7,8,9-HxCDD
Totals
Results

Analytical
Perspectives

[Form: TOT]


Totals class: HpCDD EMPC




Function
4 Run
»: 9

Checkcode: 1069 /
File
Name: 080723P2 Sample
#
9


Sample text
P9464_6042_006 Run#
II-ACD-M23-
-2 Air Tr»

Acquired; 24-JUL-08 02:44:05
Processed: 24
-JUL-08 13
: 38:59



Total Cone.: 195620


Unnamed Cone

*
Homolog count: 2


RT
ml Resp mod. m2 Resp mod.
RA

Resp
Adj_Resp
S/N

Conc.
Name
39
2S.
4.480e+08
n
4.257e+08
n
1
05 f8.737e+08
S
. 737e+08
1.28e+04
y
88100
1,2,3,4,6,7,9-HpCDD
40
11
5.471e+08
n
5.193e+08
n
1
05
1 - Q66e+09
1
066e+09
1.39e+04
y
108000
1,2,3,4,6,7,8-HpCDD
Totals
Results

Analytical
Perspectives

[Form: TOT)


Totals class: TCDF
EMPC




Function
1 Run
i: 9

Checkcode: 1069 /
File
Name: 080723P2 Sample
#
9


Sample text
P9464_6042_006 Run#
II-ACD-M23-
-2 Air Tr» '

Acquired: 24-JUL-08 02:44:05
Processed: 24
-JUL-08 13
: 38:59



Total Cone.: 945110


Unnamed Cone

819361.102 Homolog count: 26

RT
ml Resp
mod. m2 Resp
mod.
RA

Resp
Adj_Resp
S/N

Conc.
Name
21
0«s
2.254e+08
n
2.869e+08
y
0
79
*
5.123e+08
5
123e+08
1.46e+04
y
25000
1,3,6,8-TCDF
21
34
1.972e+08
n
2.505e+08
n
0
79
*
4.477e+08
4
477e+08
1.23e+04
y
21800

22
lT
2.609e+Q8
n
3.332e+08
y
0
78
y
5.94le~08
5
941e+08
1.56e+04
y
29000
2,4,6,8-TCDF
22
45,
1.160e+09
n
1.473e+09
n
0
79
J
2.633e+09
2
633e+09
3.83e+04
y
128000

23
05
1.869e+08
y
2.400e+Q8
y
0
78
X
4,269e+08
4
269e+08
1.20e+04
y
20800

23
1?
5.214e+08
y
6.615e+08
y
0
79

1.183e+09
1
183e+09
2.66e+04
y
57700

23
26
1.398e+07
y
1.771e+07
y
0
79
¥.
3.170e+07
3
170e+07
7.44e+02
y
1550

23
35*
2.919e+08
y
3.602e+Q8
y
0
81
x
6.522e+08
6
522e+08
1.87e+04
y
31800

23
41,
2.289e+08
y
3.036e+08
y
0
75
y
5.325e+08
5
325e-08
1.51e+04
y
26000

23
59
2.934e+08
y
3.709e+08
y
0
79
y
6.643e+08
6
64 3 e+ 08
1.80e+04
y
32400

24
22*
2.378e+08
y
3.027e+08
y
0
79
?
&.40Se+08
5
4O5e+08
1.47e+04
y
26400

24
31
4.036e+08
y
5.119e+08
y
0
79
>
9.1556+08
9
155e+08
2.64e+04
y
44600

24
41*
4.215e+08
y
5.423e+08
y
0
78
y
9.638e+08
9
638e+08
3.20e+04
y
47000

24
48.
8.013e+08
y
1.014e+09
y
0
79
*
1.816e+09
1
816e+09
4.22e+Q4
y
88500

25

5.416e+08
n
6.896e+08
n
0
79
X
1.231e+09
1
231e+09
3.19e+04
y
60000

25
3?
3.568e+08
n
4.530e+O8
n
0
79
y
8.099e+08
8
099e+08
2.59e+04
y
39500

25
it
3.594e+08
n
4.577e+08
n
0
79
9
8.171e+08
8
171e+08
2.42e+04
y
39800

25
5%.
3.580e+08
y
4.576e+08
y
0
78
y
8.156e+08
8
156e+08
2.61e+04
y
39800

26
01
2.661e+08
y
3.383e+08
y
0
79
y
6.045e+08
6
045e+08
1.99e+04
y
29500
2,3,4,8-TCDF
26
13
3.376e+08
y
4.270e+08
y
0
79
V
7.645e+08
7
645e+08
2.50e+04
y
37300
2,3,7,8-TCDF
26
ff
8.831e+08
n
1.127e+09
n
0
78

2.010e+09
2
010e+09
6.56e+04
y
98000

26
5?
6.774e+07
y
8.645e+07
y
0
78
¥
1.542e+08
1
542e+08
4.28e+03
y
7520

27
0§_
5.775e+07
n
7.370e+Q7
n
0
78
*
1.315e+08
1
315e+08
4.19e+03
y
6410

-------
OPUSquan on MM1
26-
JUL-2008 11
20







27

7.498e+06
n
9.776e+06
n
0.77 j,
1.727e+07
1.727e+07
4.58e+02
y
842

27
40,
4.270e+06
n
4 . 9S7e+06
y
0.86
3f
9.237e+06
9,237e+06
3.21e+02
y
450

28
20-
4.567e+07
n
5.777e+07
y
0.79

1.034e+08
1.034e+08
3.22e+03
y
5040
1,2,8,9-TGDF
Totals
Results

Analytical
Perspectives
(Form: TOT]


Totals class: PeCDF EMPC



Function: 2 Run
t ¦¦ 9

Checkcode: 1069
File
Name: 080723P2
Sairple
#
9

Sample text: P9464_6042_006 Run#
II-ACD-M23-
2 Air Tr»

Acquired: 24-JUL-08 02:44:05
Processed: 2<
-JUL-08 13
:3 8:59



Total Cone.: 458300

Unnamed Cone.
: 377135.360 Homolog count: 16

RT
ml Resp
mod. m2 Resp
mod. RA

Resp
Adj_Resp
S/N

Conc.
Name
29
W
7.854e+08
n
4.993e+08
y
1.57
V,
1.285e+09
1.285e+09
9.89e+03
y
71200

30
04.
8.868e+08
n
5.631e+08
n
1.57
y
1.450e+09
1.450e*09
1.08e+04
y
80300

30
10
2.200e+08
n
1.377e+08
n
1.60 J
3.577e+08
3.577e+08
4.20e+03
y
19800

30
ir
7.841e+07
n
4.891e+07
n
1.60
if
1.273e+O0
1.273e+08
1.14e+03
y
7060

30
3J,
1.217e+08
n
7.685e+07
n
1.58
y
1.985e+08
1.985e+08
1.57e+03
y
11000

30
40
1.490e+08
ri
9.501e+07
ti
1.57
V
2.440e+08
2.440e+08
2.68e+03
y
13500

30
4T
S.487e+08
n
3.443e+08
n
1.59
y
8.930e+08
8.930e+08
6.57e+03
y
49500

31
00
1,356e+08
n
8.677e+07
n
1.56
7
2.223e+08
2.223c 108
2.42e+03
y
12300

31
1?
3.334e+08
n
2.llle+08
y
1.58
V
5¦445e+08
5.445e+08
5.74e+03
y
31400
1,2,3,7,8-PeCDF
31
3#>
5.717e+08
n
3.616e+08
n
1.58
%
9.333e+08
9.333e+Q8
6.76e+03
y
51700

31
&
5.383e+07
n
3.42le+07
n
1.57
y
8.804e+07
8.B04e+07
8.Q6e+02
y
4880

32
06
7.490e+07
n
4.625e+07
n
1.62 ¥
1.211e+08
1.211e+08
1.34e+03
y
6710

32
1 «•
4.915e+08
n
3.147e+08
n
1.56
¦Y
8.062e+08
8,062e+08
8.57e+03
y
44700

32
2f
5.192e+08
n
3.286e 108
y
1.58
r
8.478e+08
8.478e+08
8.080+03
y
45200
2,3,4,7,8-PeCDF
32
4?
4.876e+07
n
3.088e+07
n
1.58
Y
7.964e+07
7.964e+07
8.03e+02
y
4410

33
2 g
5.041e+07
n
3.177e+07
y
1.59
y
8.217e+Q7
8.217e+07
9.37e+02
y
4550
1,2,3,8,9-PeCDF
Totals
Results

Analytical
Perspectives
[Form: TOT]


Totals class; HxCDF EMPC



Function: 3 Run
~ : 9

Checkcode: 1069 '
File
Name: 080723P2
Sample
#
9

Sanple text: P9464_6042_006 Run#
II-ACD-M23-
2 Air Tr»

Acquired: 24-JUL-08 02:44:05
Processed: 2«
-JUL-08 13
38:59



Total Cone.: 204490

Unnamed Cone
: 112344.263 Homolog count: 13

RT
ml Resp
mod. iri2 Resp
mod. RA

Resp
Adj_Resp
S/N

Conc.
Name
34
IX
1.552e+08
n
1.233e+08
y
1.26
51
2.785e+08
2.785e+08
2 .01e+03
y
17400
1,2,3,4,6,8-HxCDF
34
29
5.085e+08
n
4.056e+08
n
1.25
y
9.141e+08
9.141e+08
6.58e+03
y
57200

34
4?
5.148e+07
n
4.159e+07
n
1.24
y
9.307e+07
9.307e+07
5.51e+02
y
5820

34
54
6.965e+07
n
5.62Qe+07
n
1.24
»
1.258e+08
1.258e+08
8.72e+02
y
7870

35
09
4.300e+07
n
3.509e+07
n
1.23
y
7.809e+07
7.809e+07
5.67e+02
y
4890

35
34>
2.006e+08
n
1.618e+08
n
1.24
?
3.623e+08
3.623e+08
2.69e+03
y
22700

35
42
2,024e+08
n
1.624e+08
y
1.25
X
3.649e+08
3.649e+08
2.58e+03
y
22500
1,2,3,4,7,8-HxCDF
35
5?
2.205e+08
n
1,774e+08
y
1.24
y
3.979e+08
3.979e+08
2.84e+03
y
22500
1,2,3,6,7,8-HxCDF
35
5»
3.326e+07
n
2.727e+07
ii
1.22
y
6.053e+07
6.053e+07
4.04e+02
y
3790

36
08
3.940e+07
n
3.223e+07
n
1.22
t
7.163e+07
7.163e+07
5.04e+02
y
4480

36
1*5
4.947e+07
n
4.029e+07
n
1.23
y
8.976e+07
8.976e+07
6.29e+02
y
5620

36
2|
2.080e+08
n
1.706e-f-08
y
1.22
f
3.787e+08
3.787e+08
2.87e+03
y
23000
2,3,4,6,7,8-HxCDF
37
3g
5.102e+07
n
4.028e+07
y
1.27
f
9.130e+07
9.130e+07
4.95e+02
y
6700
1,2,3,7,8,9-HxCDF
Totals
Results

Analytical
Perspectives
[Form: TOT]


Totals class: HpCDF
EMPC



Function: 4 Run
t: 9

Checkcode: 1069
File
Name: 080723P2
Sample
#
9

Sample text: P9464_6042_006 Run#
II-ACD-M23-
2 Air Tr»
-------
I
OPUSquan on MM1 26-JUI.-2008 11;20
Acquired: 24-JUL-08 02:44:05 Processed: 24-JUL-08 13:38:59
Total Cone.; 56038	Unnamed Cone.: 19970.893	Homolog count: 4

RT
ml Resp mod. m2 Resp mod. RA
Resp
Adj_Resp
S/N

Cone.
Name
39

2.367e+Q8 n 2,295e+08 y 1.03
4 .662e+08
4.6620*08
7.04e+03
y
30500
1,2,3,4,6,7,8-HpGDF
39

5.661e+07 n 5.450e+07 n 1.04
if 1. llle+08
1. llle+08
1.67e+03
y
8210

39
3%
8.059e+07 n 7 . 873e-07 n 1.02
¥ 1.593e+08
1.S93e+08
2.26e+03
y
11800

40
sz
3,349e+07 n 3.174e+07 y 1.05
%,6.523e+07
6.523e+07
8.10e+02
y
5520
1,2,3,4,7,8,9 HpCDF
-------
File: 080T23P2 Acq: 24-JUL-2008 02742Y05 GC EI+ Voltage SIR Autospec-UltimaE
Sample! 9 Text: P9464_6042_006 Run# II-ACD-M23-2 Air Train Viali 38 Pile Text: AP DBS
316.9824 S:9 PXD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
100%r°: 02 20:35 21:11 21:47 P'°h-.28 P "'H: 07 23 : 32 24:04 24:28 24:55 25:30 ,25:59 26?fi5l 27:12 r?'26 28: 00 28:30 29:03
21:00	22:00	23:00	24:00
366.9792 S:9 F:2 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
30: 06
30:45
31:34
25:00
31:50
26:00	27:00
"<9 . Q _ _
28:00
29:00
33 : 46
Time

31:40
33:30
380.9760 S:9 F
34:15
30:00	31:00
3 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4
32:00
33:00
34:00 Time
34 :37
35:0t 35:13 35:27
35:50
36:10 36:26 r6:3336:48 37:00 37:12 37:28 37i4Jl37:55
38:14
35:00	36:00
430.9728 S : 9 F:4 PKD (5, 5, 3 ,100 . 00%, 750. 0, 0.00%, F, F) Expt: DF..CL4-
37:00
38:00
Time
39:08
39:40
41:23
41:49
39:46 39:56
39:00
40:50
39:20
38:36 38
454.9728 S:9 F
48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00
5 PKD(5,5,3,100,00%,750.0,0.00%,F,F) Expt: DF_CL4-8
Time
100%
80-
60.
40.
20.
42:09
42:29	.w.
1 42:36
42:56
42:50 r 
-------
File: 080723P2 Acq: 24-JUL
Sample# 9 Text: P9464_6042,
319.8965 S:9 BSUB(10000,15,
-2008 02:44:05 GC EI+ Voltage SIR Autospec-UltimaE
.006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text; AP DBS
*3.0) Expt: DF_CW-8 Noise: 3286
25:10
23:14
A6.65E7
23:37
A4.11E7
21:00
321.8936 S:9 BSUB(10000,15,
lOOfe
80J
60.
40.
20.
21:00
327.8850 S:9 BSUB(10000,15, •
100%,
80.
60.
4Gj
20.
22:00	23:00
-3.0) Expt: DF_CL4-8 Noise:
23:14
A8.41E7
23:37
A5.22E7
22:00
3.0) Expt:
23:00
DF_CL4-8
24:00
Noise: 1521
A1.22E8
26:03
A5.29E7
25:5
24:56
A5.38
-
26:00
25:00
24:00
2605
25:10
A1.55E8
26: 03
A6.76E7
24:05
A4.65E7
25:5
24:56
Ab . 79EI6
27:30
26:51	06E7
A9.36E7
26:35 I 1*3 . 9i
69EV
27 :00
28:10
A2.17E7
A
28:00
29:00
27 :30
26:50 A8.85E7
Al.19E8
26:35I(A4.98E7
39EP
25:00
26:00
28:10
A2.77E7
A
27:00
27:09
A2 . 01E7
28:00
29:00
23:14
A6.95E5
—r
25:23
A8.58E5
-•—
26:00
26:51
A9.61E
T
i 27:30
\A8.22E5
29:00
2.1E7
1.7E7
1.3E7
8 , 5E6
4 . 2e6
Time
2.7E7
2.1E7
1.6E7
1.1E7
5.4E6
Time
4
8E6
L3
9E6
12
9E6
Ll
9E6
.9
7E5
21:00
331.9368 S-.9 BSUB(10000,15,
1001,
80.
60.
40.
20.
22:00
-3.0) Expt:
23:00	24:00
DF CL4-8 Noise: 1273
25100
23:11
A1.99E7
26:26
A2.13E7
27:00
27:07
A2.Q7E7
28:00
i
J±
Time
.4.8E6
.3.9E6
.2. 9E6
1.9E6
.9. 7E5
6.0E6
4.BE6
3.6E6
2.4E6
1 . 2E6
21:00
333.9339 S:9 BSUB(10000,15,
100%,
80.
60.
40.
20.
22160	23:GO	24:00
-3.0) Expt: DF_CL4-8 Noise; 1340
23:11
A2.44B7
25:00
26:00
26:26
A2.57E7
->—r
27 :00
27:07
A2.51E7
28:00
29:00
21:00
22 :00
23:00
24; 00
'25! 00
26:00
27:00
28:00
29:00
Time
-------
Sample# 9
355.8S46 S
10 os,
80.
60.
40
20.
Voltage SIR Au t o spec-U11 imaE
Text: P9464_6042_006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text: AP DBS
9 F: 2 BSUBUOOOO. 15, 3.0) Expt: DF..CL4-8 Noise: 6223
30:09	„„
At	31:16
*	A1.14E8	31:49
32*13
A8.22E7
30:41
A4.07E7
.A.
A9.37E7
32:43
A9.36E7
2:48
. 83 E7
3o!qO	 31:00	32; 00	33
357.8517 S:9 F:2 BSUB(10000,15,-3.0 I PKD[5,5,3,0.10%,750.0,0.00%,F,F) Expt: DF_CL4-8 Noise: 3338
30:09
A1.14E8
33:10
A6 .57E7
100%
803
soj
40i
20i
31:49
31:33 jo 54E7
AS.88E7 Ay"5
30:41
A2.57E7
A
32:13
A5.14E7
32:43
A5.92E7
: 00
33:10
A4.19E7
3.5E7
i_2, BE?
L2.1E7
Ll. 4E7
i.7 . 0E6
34:00 Time
2.2E7
1.8E7
i . 3E7
8.8E6
4 . 4E6
30:00	31:00
367.8949 S:9 F:2 BSUB(10000,15,-3 . 0) Expt: DF_CL4-8 Noise: 2468
32:00
33 :00
34:00 Time
00 Time
32:11
A2.6QE7
32:42
A2.59E7
100%
33:00
32:00
30:00
9 F:2 BSUB(10000,15
31:00
DF CM-8
Noise: 7103
369.8919 S
32:11
Al.78B7
32:42
4.5E6
A1.60E7
1001
2.7E6
1.8E6
9.0E5
34:00
33:00
32:00
30:00	31:00
9 F:2 PKD(5,5,3,100.00%,750.0¦0.00%,F, F)
Expt: DF CL4-8
366.9792 S
29
33:4b
33:30 "I 33:52
31:50
r 32:03
3i ?24 n 31:40
32:49
30:06 3q;12 30:24 J0^^30:5
32:32
32:59
2 . 1E6
32:19
100%
31:05
1.7E6
1.3E6
8 . 3E5
30:00
31:00
32:00
33:00
34:00 Time
-------
File"-ffffD72"3p2 Acq: 24-JUL-2008 02:44:0b GC EI + Voltage SIR AutOspec-UltunaE
Sample# 9 Text: P9464_6042_006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text: AP DBS
389.8156 S:9 F:3 BSUB(10000,15,-3.0| Expc: DF_CL4-8 Noise: 8565
35:54
1001,	A2.49E8
35:36
34:57
A1.20E8
A1.38E8
35:00
391.8127 S:9 F:3 BSUB(10000,15,-3.0)
Sxpt: DF_CL4-
100%,
80.
60.
40.
20.
36:00
Noise: 4853
35:54
A2.Q1E8
34:57
A9.61E7
35:36
A1.11E
6:02
-66E7
35:00	36:00
401.8559 S:9 F:3 BSUBUOOOO,15, -3.0) Expt: DF_CL4 8 Noise: 3982
100%
80i
60i
40J;
20i
35:00	36:00
403.8530 S:9 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4 8 Noise: 6129
1001,
80.
60.
40.
20.
35:00
380.9760 S:9 F:3 PKD(5,5¦3,100.00%,750,0,0.00%,F,F)

36:47 37:05
A6.67E7 A6.37E7
37:00
36:47 37:05
A5.37E7 A5.D6E7
37:00
36:46 37:04
A2. 45E7 A2.46E7
37 :00
37:04
A1.86E7
36:46
A1,90E7
37 :00
38:00
38:00
38:00
38:00
S.4E7
4.3E7
3.2E7
.2 .2E7
.1. 1E7
Time
.4 . 4E7
.3. 5E7
2.6E7
.1. 8E7
.8 . 8E6
Time
.6, 4E6
.5.1E6
.3 . 8E6
.2.5E6
.1. 3E6
Time
.4.9E6
.4.0E6
.3.0E6
.2.0E6
.9.9E5
Time
-------
/
File: QB0723F2 Acq: 24-JUL"-2008 02:44:05 GC El+ Voltage SIR Autospec-UltimaE
Sample# 9 Text: P9464_6042_006 Run# II ACD-M23-2 Air train Vial# 38 File Text: AP DB5
423.7767 S:9 F:4 BSUB{10000,15,-3.0) PKD15,5,3.0.10%,7 50.0,0.00% , F, F) Expt: DF_CL4-8 Noise: 31982
40:17
100%,	»	a	A5.47E8
80.
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38:36
425.7737 S:
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38:48 39:00 39:12
5 F:4 BSU3(10000, 15,-3
39:24
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39:36 39:48 40:00 40^12 40:24 40 i 3 6 40:48 41500 41: 12
5,3,0.10%,750.0,0.00%,F,F) Expt: DF..CL4-8 Noise: 31162
40:17
A5.19E8
41:24 41:36 41:4S 42:00 Time
38148 39:00 39:12 39:24 39:36 39 • 48 40^00 40S12
9 F:4 BSUB(10000,15,-3.01 Expt: DF_CL4 8 Noise: 3312
40:16
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1
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L.5
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40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
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: 9 F: 4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 3327
40:16
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40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:00 Time
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39:24 39:36
39:48
430.9728 S:9 F:4 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
39:40
40:00 40:12 40:24 40:36 40:48 41:00 41:12
. . . . 39:0H - -

40:50
41: 23
41:17 r '
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40:24
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41:24 41:36 41:48 42:00 Time
-------
File: 0B0723P2 Acq: 24-JUL-2Q08 02:44:05 GC EI+ Voltage SIR Autaspec-ljltimaE
Sample# 9 Text: P9464_6042_006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text: AP DBS
457.7377 S:9 F:5 BSUB(10000,15,-3.0) PKD(5,5,3,0.10%,750.0,0.00%,F,FJ Expt: DF_CL4-8 Noise
43:53
100S,	A1.78E9
80,
60.
40,
20,
775
42:12 42:24 42:36
459.7348 5:9 F:5 BSUB(10000,15,-3
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42:48 43:00 43:12 43:24
0) FKD{5,5,3,0.10%,750.0,0.00%,P,P)
43:36 43:48 44:00
Expt: DF_CL4-8 Noise: 881
43:53
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44:12 44:24
'44!36 '
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42:12 42:24 42:36 42:48 43:00
469.7780 S:9 F:5 BSUB<10000,15,-3.0) Expt: DF_CL4-8
100%
80i
60i
40i
20i
43:12
Noise:
43:24
3056
43:36
43 :48
44:00
44:12
44:24
44 :36
44:48
' 4*2 ! 12 ' " ' 4*2 • 24 ' ' ' 42 ! 36 " ' ' 42 1 4*8 * ' ' 43 ! 00 "
471.7750 S:9 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4-
100%
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7.1E7
45:00 Tiae
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12.4E8
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45:00 Time
-5.5E6
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l3. 3E6
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Noise: 2771
44:24
44:36 44:48
43:52
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43:36 43:48 44:00 44:12
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44:24 44:36 44:48
45:00 Time
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2.6E6
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42:12 42:24 42:36 42:48 43:00 43:12 43:24
454.9728 S:9 F:5 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
100%, 42:09
80.
45:00 Time
42:56
r	43:07
42:29
44:34 44:42 44:51
43:19
3.8E6
44:01 44:10
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1.5E6
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42:12
42 ' 24 ' ' ' 4*2 : 36
42"T48T—'	4J-l2
43:24 43:36
43:48 44:00
44:12
44:24 44:36
44:48
45:00 Time
-------
File: 08D723P2 Acq: 24-JUL-2008 02:44:05 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 9 Text: P9464_6042_006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text: AP DBS
303.9016 S:9 BSUB{10000,15,-3.0) Expt: DF_CL4-8 Noise: 37004
100%
80i
60 i
40i
20i
26
A8.
21:01 21-34
A2.2SE8 ftl,97E8
A, , A,
22:48
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22: 14
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24-47
23:13	A8.01E8
A5.21E8	24:31
r	23:59 A4.04
A2.93E8

25:1b
25: 59
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37
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26:53
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28:21
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29 !00
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1 ,SE8
1. 2E8
8.0E7
4.0E7
21:00	22:00	23:00	24:00
305.8987 S:9 BSUB(10000,15,-3,0} Expt: DF CL4-B Noise: 47376
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25:00
26:00
27:00
100*
80
60.
40.
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22:48
A1.47E9 23:13
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8.65E7
28:00
28:21
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Time
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L2.QE8
Ll.5E8
L1.0E8
L5.1E7
21!00	22:00	23:00	24-00
315.9419 S:9 BSUB(10000,15,-3.0) Expt: DF_CL4- 8 Noise: 1779
25:00
100*
80.
60.
40.
20.
20:59
A3.27E7
21:00	22:00	23:00	24:00
317.9389 S:9 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 2894
24:45
A3.43E7
i-U
26:00
26:13
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27:00
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25: 00
100*
80.
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26:00
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27: 00
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28:00
28:00
28:00
29:00
291 00
Time
7.0E6
5.6E6
4 . 2E6
2.8E6
1. 4E6
Time
8 . 9E6
7 . 1E6
5.3E6
3 . 6E6
1.8E6
21:00	22:00	23:00	24:00
375.8364 S:9 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 1250
100*
80
60
40.
20.
25:00

28:11
A1.24E7
29:00
Time
2 . 2E6
1,8E6
1.3E6
8 , 9E5
4.4E5
21:00
221 00
23:00
24:00
25:00
26:00
27:00
29:00
Time
-------
File: 080723P2 Acq: 24-JUL-2008 02:44:05 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 9 Text: P9464_6042_006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text: AP DB5
339.8597 S:9 BSUBflOOOO,15.-3.0) PKD(5,5,3,0.10%,750.0,0.00%,F,F) Bxpt: DF_CL4-8 Noise: 1353
100%
9o|
80|
7o|
60|
5o|
4o|
3oj
2oJ
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/
28:18
A4.63E8
21:00	22:00	23:00	24:00
341.8568 S:9 BSUB(10000,15,-3.0) PKD(5.5,3,0.10%.750.0,0.00%,F,F)
1001
90 J
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70|
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25:00
Expt: DF_CL4 -
26
Noise
00
1436
27 ! 00
11^
28:00
28:18
A2.71E8
29: 24
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29:00
Time
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21:00	22:00	23:00	24:00
316.9824 S:9 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
25:00
26! 00*
100S.20:02
xuu^_ 20:35
90.
80.
70.
60.
50 j
40.
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21:47 22:022:2g 22:4|:07 23;3, ,4. 04 24 : 28 24 : 55 25:30 |S:S9
27 I 00
26:51 ,7.-1, 27:
*31	
-------
14:05 GC EX+ Voltage SIR Antospec-uitimaE
II-ACD-K23-2 hit Train Vial# 38 File Text: AP DBS
Expt: DF_CL4-8 Noise: 167725

'File; U80723P2 Acq: 24-JUL-2008 02:
Sample#
339.8597
F9464_6042_006 Run#
BSUB(10000,15,-3.0)
30:05
A8.87E8

: 22
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31:31
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30:46
AS. 49E8
31:13
A3.33E8
10
20E8
32 :42
A4.88E7
31:40
84E7
5.38E7
33:27
A5.04E7
1.7E8
1.3E8
9.9E7
6.6E7
3.3E7
30:00
341.8568 S:9 F:2 BSUB(10000,15
30:05
lOOi	A5.63E8
80i
60.
40i
20.
-3.0)
31:00
Expt: DF_CL4-
32:00
33:00
Noise: 98370
30:46
A3.44E8
: 10
38E8
0:16
. 89E7
31:31
31:13 A3.62E8
A2.11E8
32-14 32:22
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31:00 A
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31:40
3.42E7
32:06
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32:42
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34:00 Time
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30:00
351.9000 S:9 F:2 BSUBf10000,15,
100*
80.
60.
40.
20.
3.01 Expt:
31:00
DF CL4-
32:00
33:00
34:00 Time
8 Noise: 3947
30:39
A4.01E7
31:11
A4.14E7
32:21

A4.23E7
1.2E7
A
fc.9. 5E6

L7.1E6

E.4. 8E6
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30:00	31:00
353.8970 Si 9 F:2 BSUB110000,15,-3.0) Expt: DF_CL4-8 Noise: 5237
100*
80.
60,
40.
20.
32-00
33: 00
30:39
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31:11
A2.65E7
32:21
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34:00 Time
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6 . QE6
4 . 5E6
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	r
34:00 Time
30:00
31:00
32:00
33:00
409.7974 S:9 F:2 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 3296
100*
80i
60
40
20
30:00
31:00
32:00
33:00
33:51
6 . 7E5
5.4E5
1.3E5
34:00 Time
-------
File: 080723P2 Acq: 24-JUL-Z00fl 02:44:05 GC EI+ Voltage SIR Autospec-UltimaS
Sample# 9 Text: P9464_6042_006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text: AP DBS
373.8207 S:9 F:3 BSUB(10000,15,-3.0) Expt: DF_CL4-B Noise: 125008
34:29
100%	AS.09E8
35:34
A2.01E8 A2.20E8
08E8
34:17
A1.55E8
34:44
5.15E7
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35:09
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r
34:55
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36:16
37:30
A5.10E7
35:59
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35:00	36:00
375.8178 S: 9 P:3 BSUSUQ0QO, 15, -3 . 0) Expt: DF^CL4-8 Noise: 103024
34:29
100|	A4.P6E8
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37:00
38:00
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9.2E7
6.9E7
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2.3E7
35:00
383.8639 S:9 F:3 BSUB(10000,15, -3.0)
Expt: DF_CL4-8
36:00
Noise: 7419
37:00
38:00
35:00	36:00
445.7555 S:9 F:3 BSUB(10000,15,-3 . 0} Expt: DF_CL4-8 Noise: 1533
37:00
38:00
Time
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4.7E6
3 . 6E6
2 . 4E6
1.2E6
35:49
A2.21E7
36:08
36:29
A1.95E7
A1.98E7
37:27
A1.70E7
38: 00
36:00
Noise: 3734
37:00
35:00
385.8610 S:9 F:3 BSUB(10000,15,-3.0)
DF CL4
35:49
36:08
36:29
100%
A3.63E7
A3.64E7
37 : 27
A3.18E7
8.9E6
6.7E6
4.4E6
2.2E6
Time
Time
35:48
.1.1E5
100%
35:36
8.9E4
36:59
6.6E4
4 . 4E4
37:08
37:36
38:08
2.2E4
34 :18
38: 24
34:10
35:02
35:00
36:00
37:00
38:00
Time
-------
/
File: 080723P2 Acq: 24-JUL-2006 02:44:05 GC EI+ voltage SIR Autospee-uitimaE
Sample# 9 Text: F9464_6042_006 Run# II-ACD-M23-2 Air Train Vial# 38 File Text: A? DBS
407,7818 S:9 F:4 BSUB(10QOO,15,-3.0) Expt: DF_CL4-S Noise: 30311
39:06
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80.
60.
40.
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39:36
39:25
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/
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38:36
409.7788 S
100&,
80.
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38:48 39:00 39:12 39:24 39:36 3 9 ! 4 8 '40:00 4 0 512 40:24 *4 0 I 3 6 ' 40: 48 41:00 41 i 12 41: 24 41:36
9 F:4 BSU3(10000,15.-3.0) PKD(5,5,3,0.10%»750.0,0.00%,F,F) Expt: DF_CL4-8 Noise: 12294
39:06
A2.29E8
39:36
A7.87E7
40:52
A3.17E7
41:48 42:00 Time
-6.7E7
l5.4E7
14.0E7
'¦Jl .7E7
-1.3E7
' I ' '
41:00
41:12 41:24 41:36 41:48 42:00 Time
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7 . 8E5
38:36
417.8253 S
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40.
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3 8148 ' 39:00 39:12 39!24 39]36 39i48 40i00 40:12
:9 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise; 6341
39:05
A1.31E7	39:35
A1.23E7
40:24 40:36 40:48
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40:00 40:12 40:24
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40:51
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39:12
38:36 38:48 39:00
419.8220 S: 9 F:4 BSUB (10000,15,-3.0)
39:05
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80,
60 j
40i
20.
i I 1
39:24
39:36
Expt: DF_CL4
39:35
A2.68E7
' ¦ [ 1 i
39:48
41:00 41:12 41:24 41:36 41:48 42:00 Time
•8 Noise: 5935
40:51
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LS. 2E6
l3 . 5E6
Ll.7E6
. 	' i ' | ' 1
41:00 41:12
38:36 38:48 39^00 39il2 39:24 39:36 39:48 40:00 40:12
479.7165 S:9 F:4 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 2384
100J
80.
60-
40_
20l
40:24 40:36 40:48
41:24 41:36 41:48
38:45
39:09
39:3339:41
40•24 40:32
r	40:52 41:14	.
40:46 nJO : 41:08T 41:,
41:32
42:00 Time
_5.7E5
4. 5E5
3 . 4E5
2 . 3ES
1.1E5
41:49
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48
41:12 41:24 41:36 41:48 42:00 Time
-------
/
File: 080723P2 Acq: 24-JTUL-2008 02:94:05 GC EI+ Voltage SIR Autospec-ultimaE
Sample# 9 Text: P9464_6042_006 Run# II-ACD M23-2 Air Train Vial# 38 Pile Text: AP DB5
441.7428 $:9 F:5 BSUB(10000,15,-3.0) Expt: DF_CL4~8 Noise: 6774
100%
80i
60j
40i
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'42]12 ' '42 ! 24' ' ' 42¦36
443.7398 S:9 F:5 BSUB(10000,15
100%,
80.
60.
40.
20,
42:48 43:00 43:12 43:24
3.0) PKDI5,5,3,0.10%,750.0,0.00%,F,F)
44:07
43136 43:48 44100 44:12 44:24
Expt: DF_CL4-8 Noise: 1331
44:07
A6.24E7
44:36
44:48
I	1 ¦ 1 I I T I	1
43:48 44:00
.1.2E7
9.6ES
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.4 ,8e6
2 . 4E6
45:00 Time
1.3E7
l1.1E7
7.9E6
5 . 3E6
2.6E6
42:12 42:24
453.7830 S:9 P:5 BSUB(10000,15
100%
80i
60i
40i
20i
r-n—t—r—t—t—»—i—|—i—
42:36 42:48
3.0)
43:00
Expt: DF_CX4-
43:12 43:24
Noise; 2866
' 43!36'
44:12
44:24
44:36
44:48
42:12 42:24 42:36 42:48
455.7801 S:9 F: 5 BSUBUOOOO, 15,-3 . 0> Expt:
100%,
80.
60.
40.
20.
43:00
DF_CL4-8
43:12 43:24
Noise: 2789
43:36
43:48 44:00
44:06
A4.04E7
44:12
44:24 44:36
44:48
42:12 42:24 42:36 42:48 43:00
513.6775 S : 9 F:5 BSUBUOOOO, 15,-3 . 0) Expt: DF_CL4-8
43:12
Noise:
43:24
1189
'43¦36'
44:06
M.41E7
rn
43:48 44:00 44:12 44:24 44:36
44:10
44 : 48
45:00 Time
8.4E6
6 . 7E6
5.0E6
3 . 4E6
1-7E6
45:00 Time
-9.2E6
i7 . 4E6
-5.5E6
.3 . 7E6
:1,8E6
44:30
44:48
44:59
1
42:12
42 : 24
42:36
42:48
43 :00
43:12
43:24
43:36
43 :48
44:00
44:12
44:24
44:36
44:48
45:00 Time
3.3E4
2.6E4
2.0E4
1. 3E4
6.SE3
4 5:00 Time
-------

o«V Avy %
OPUSquan on MMl
26-JUL-2008 11:19
checkc ode: 13s 0
1613/8290 Sample Summary
Client ID: Run# II-ACD M23-3
Lab ID:	P9464_6042_007
Sample text: P9464_6042_007 Run#
Name
7,8-TCDD
8-PeCDD
8-HxCDD
8-HxCDD
9-HxCDD
8-HpCDD
OCDD
OCDD-a
8-PeCDP
8 PeCDF
8 HxCDK
8-HxCDF
8-HXCDF
9-HxCDP
8-HpCDF
9-	HpCDF
OCDF
OCDF-a
Analytical Perspectives
Typ

Ax
2,3,
Ax
1,2,3,7
Ax
1,2,3,4,7
Ax
1,2,3,6,7
Ax
1,2,3,7,8
Ax
1,2,3,4,6,7
Ax

Ax2

Ax
2,3,
Ax
1,2,3,7
Ax
2,3,4,7
Ax
1,2,3,4,7
Ax
1,2,3,6,7
Ax
2,3,4,6,7
Ax
1,2,3,7,8
Ax
1,2,3,4,6,7
Ax
1,2,3,4,7,8
Ax

Ax2

ES
13C-2,3,
ES
13C-1,2,3,7
ES
13C-1,2,3,4,7
ES
13C-1,2,3,6,7
ES
13C-1,2,3,7,8
ES
13C-1,2,3,4,6,7
ES

ES
13C-2,3,
ES
13C-1,2,3,7
ES
13C-2,3,4,7
ES
13C-1,2,3,4,7
ES
13C-1,2.3,6,7
ES
13C-2,3,4,6,7
ES
13C~1,2,3,7,8
ES
13C-1,2,3,4,6,7
ES
13C-1,2,3,4,7,8
ES

cs
37C1-2,3,
CS
13C-1,2,3,4
CS
13C-1.2,3,4
CS
13C-1,2,3,4,6
CS
13C-1,2,3,4,6,8
NA

JS/RT
13C-1.2,:
JS
13C-1.2,:
JS/RT
13C-1,2,3,4,6
13C-OCDD
7,8-PeCDF
8-PeCDF
8-HxCDF
8-HxCDF
8-HxCDF
9-HxCDF
8 HpCDF
9-HpCDF
13C-OCDF
7-PeCDD
6-PeCDF
9-HxCDF
9-HpCDF
n/a
3,4-TCBD
GC
II-ACD-M23
Resp
1.50e+08
3.63e+08
2.21e+08
3,38e+08
2.76e+08
1.34e+09
1.23e+09
7,61e+07
1,29e+09
1.32e+09
2,24e+09
1.28e+09
1.32e+09
1.40e+09
3.58e+08
2.07e+09
2.47e+08
3.36e+08
2.09e+Q7
4,06e+07
3.87e+07
3.44e+07
3.91e+07
3.87e+07
3.60e+07
5.32e+07
Filename: 080723P2 S
column ID; db-5	Cal
¦3 Air Train firC. Stds
.37e+07
.18e+07
,19e+07
. 95a + 07
,60e+07
, 13e+07
.54e+07
-89e+07
,29e+07
.55e+07
1.83e+07
3.94e+07
5.98e+07
4.92e+07
3.64e+07
4.23e+07
7.01e+07
1.9Se-07
RA
80
57
23
24
23
05
0.
1.
1.
1.
1,
1.
0.89
2.51
0.79
1.57
.58
.25
.26
.25
1.
1.
1.
1.
1.25
0.81
1.58
1.29
1.26
1.32
1.07
0.86
0.78
1.57
1.56
0.55
0.54
0.55
0.55
0.45
0.44
0.91
1.03 n
1.57 y
0.54 y
0.46 y
0.82 y
0.80 y
1.28 y
RT FtRF /
1. f *
10
[Form: DF)
1
Vial: 39
/
Acq: 24-JUL-08^03:34:58
WC/Vol: 1.00CT
JS (split adj.): 4000 CS/SS: 1600
27:09 ' 1 .09y
32:43/ 1.00
36:4 0' 1.10
36:47/ 1.00
37:05'' 1.03
40:17/ 0.98
43:53/ 1.08 1
43:52 0.07 /I
rJ,J
14/ 1.02
23/ 1.09
41-^" 1.20
s 
-------
OFUSquan
on MM1
26-JUL-2008 11
:19


checkcode: 1340
/






SS
37C1
-2,3,7,8-TCDD
1
83e+07


27
09
1.14
/ 1580


8.94
98
5

SS
13C-1,
2,3,4,7-PeCDD
3
94e+07
1.03
n
32
11
1.06,/
3830
186818
2.5
429
95
8

SS
13C-1,
2,3,4,6-PeCDF
5
98e+07
1.57
y
30
40
1.09
3560
33908
2.5
48.6
89
1
/
SS
13C-1,2,
3,4,6,9-HxCDF
4
92e+07
0.54
y
36
08
0.95
3690
12784
2.5
13.4
92
1

SS
13C-1,2,3,
4,6,8,9-HpCDF
3
64e+07
0.46
y
39
36
0.95
3920
30348
2.5
41.9
98
0

SBS

2,4,6,8-TCDF
8
07e+08
0.79
y
22
14
1.17
43500
4567
2.5
4.84

-

Ay

1,3,6,8-TCDD
2
68e+08
0.79
y
23
13
1.09
24100
5216
2.5
8.99



Ay

1,2,3,9-TCDD
1
45e+08
0.79
y
26
59
1.09
13100
5216
2.5
8.99

-

Ay

1,2,8,9-TCDD
1
09e+08
0.79
y
28
10
1.09
9840
5216
2.5
8.99

-

Ay
1,
2,4,7,9-PeCDD
7
48e+08
1.58
y
30
09
1.00
76900
9407
2.5
22.8

-

Ay
1,
2,3,8,9-PeCDD
2
7le+08
1.62
y
33
11
1.00
27800
9407
2.5
22 .8

-

Ay
1,2,
4,6,7,9-HxCDD
5
27e+08
1.23
y
34
57
1.04
54000
6474
2.5
13.9

-

Ay
1,2,3,
4,6,7,9-HpCDD
1
34e+09
1.05
y
39
25
0.98
152000
12768
2.5
28.4

-

Ay

1,3,6,8-TCDF
8
30e+08
0.78
y
21
02
1.17
44700
4567
2.5
4.84

-

Ay

2,3,4,8-TCDF
1
28e+09
0.79
y
26
07
1.17
69000
4567
2.5
4.84

-

Ay
•
1,2,8,9-TCDF
2
17a+08
0.78
y
28
21 /
1.17
11700
4567
2.5
4.84

-

Ay
1,
3,4,6,8-PeCDF
1
73e+09
1.71
y
28
18r
1.17
93100
7314
2.5
7.76

-

Ay
1,
2,3,8,9-PeCDF
2
25e+08
1.58
y
33
27
1.05
13800
18340
2.5
26.6

-

Ay
1,2,
3,4,6,8-HxCDF
9
95e+08
1.25
y
34
16
1.15
68300
25339
2.5
25.0

-

Tot
Total
Tetra-Dioxins
3
73e+09
0.79
y
23
13
1.09
336000
5216
2.5
8.99

_

Tot
Total
Penta-Dioxins
4
04e+09
1.58
y
30
09
1.00
415000
9407
2.5
22.8

-

Tot
Total
Hexa-Dioxins
4
04 e~09
1.23
y
34
57
1.04
414000
6474
2.5
13.9

-

Tot
Total
Hepta-Dioxins
2
69e+09
1.05
y
39
25
0.98
303000
12768
2.5
28.4

-

Tot
Total
Tetra-Furans
3
85e+10
0.78
y
21
02
1.17
2080000
4567
2.5
4.84

-

Tot
Total
Penta Furans
2
20e+10
1.57
y
29
55
1.05
1350000
18340
2.5
26.6

-

Tot
Total Hexa-Furans
1
14e+10
1.25
Y
34
16
1.15
778000
25339
2.5
25.0

-

Tot
Total
Hepta-Furans
3
23e+09
1.03
y
39
07
1.40
244000
18284
2.5
19.6

-

Tot

TCDD EMPC
3
73e+09
0.79
y
23
13
1.09
336000
5216
2.5
8.99

_

Tot

PeCDD EMPC
4
04e+09
1.58
y
30
09
1.00
415000
9407
2.5
22.8

-

Tot

HxCDD EMPC
4
04e+09
1.23
y
34
57
1.04
414000
6474
2.5
13.9

-

Tot

HpCDD EMPC
2
69e+09
1.05
y
39
25
0.98
303000
12768
2.5
28.4

_

Tot

TCDF EMPC
3
86e+10
0.78
y
21
02
1.17
2080000
4567
2.5
4.84

-

Tot

PeCDF EMPC
2
20e+10
1.57
y
29
55
1.05
1350000
18340
2.5
26.6

-

Tot

HxCDF EMPC
1
14e+10
1.25
y
34
16
1.15
778000
25339
2.5
25.0

-

Tot

HpCDF EMPC
3
2 3 e+ 0 9
1.03
y
39
07
1.40
244000
18284
2.5
19.6

-

AS
13C
-1,3,6,8-TCDD
4
04e+07
0.82
y
23
11
0.98
3910
4971
2.5
9.38
97
6
/
AS
13C
-1,3,6,8-TCDF
6
67e+07
0.79
y
21
00
1.09
3510
8628
2.5
10.5
87
7

DPE

HxCDPE
*-



NotF»
-
*


_

_

DPE

HpCDPE
*



NotF»
-
*


-

-

DPE

OCDPE
*



NotF»
-
*


-

-

DPE

NCDPE
*



NotF»
-
*•


-

-

DPE

DCDPE
*



NotF»
-
it


-

-

LMC
Fnl check mass
*



No tF»

*






LMC
Fn2 check mass
*



NotF»
-
*


-

-

LMC
Fri3 check mass
*



NotF»
-
*


-

-

LMC
Fn4 check mass
*



NotF»
-
•*


-

-

LMC
FnS check mass
*



NOtF»

*






-------
OPUSquan on MM1
26
CO
o
o
CM
1
11
20







Totals
Results


Analytical
Perspectives
[Form: TOT]



Totals class: TCDD
EMPC


Function: 1 Run
#: 10


Ch.ec kcode: 134©
File
Name: 080723P2
Sanple
i
10
Sanple text: P9464_6042_007 Run#
13
-ACD-M23
-3 Air Tr»

Acquired: 24-JUL
-08 03:34:58
Processed: 24-JUL-Q8 13
: 39:00




Total Cone.: 335990


Unnamed Cone
: 275358.962 Homolog
count: 17

RT
ml Resp
mod.
m2 Resp
mod. Rft
Resp
Adj_Resp
S/N


Cone,
Name
23

1.182e+08
n
1
498e+08
y
0.79
^ 2.680e+08
2.680e+08
5.63e+03
y

24100
1,3,6,8-TCDD
23
37
7.677e+07
n
9
787e+07
n
0.78
jr l.746e+08
1,746c-!-08
3.49e+03
y

15700

24
OS"
7.50Se+07
n
9
483e+07
n
0.79
y 1.699e+08
1.699et 08
3.64e+03
y

15300

24
5 St
1.079e+07
n
1
387e+07
n
0.78
y 2.465e+07
2, 4S5e+07
6.03e+02
y

2220

25
12
2.640e+08
n
3
365e+08
n
0.78
^ 6.Q06e+08
6.006e+08
1.06e+04
y

54100

25
24*
1.624e+08
n
2
053e+08
n
0.79
y 3.677e+08
3.677e+08
8.56e+03
y

33100

25
36,
9.287e+07
n
1
175e+08
n
0.79
y. 2.104e+08
2.104e+08
5.04e+03
y

18900

25
52
4.444e+07
ii
5
662e+07
n
0.78
y 1.011e+08
1.011e+08
2.33e+03
y

9100

26
03
1,045e+08
n
1
319e+08
n
0.79
y 2.365e+08
2.365e+08
5.76e+03
y

21300

26
20-
8.538e+07
n
1
058e+08
n
0.81
y 1.912e+08
1.912e+08
4.15e+03
y

17200

26
35,
5,987e+07
n
7
728e+07
n
0.77
Y. 1.371e+08
1.371e+08
3.16e+03
y

12400

26
50
1.923e+08
n
2
43 Be~08
n
0.79
X 4.361e+08
4.361e+08
7.04e+03
y

39300

26
59
6.433e+07
n
8
116e+07
y
0.79
y 1.455e+08
1.4556+08
3.91e+Q3
y

13100
1,2,3,9-TCDD
27
0?
6.666e+07
n
8
379e+07
Y
0.80
£ 1.504e+08
1.504e+08
3.69e+03
y

13500
2,3,7,8-TCDD
27
29"
1.379e+08
n
1
74 2©+ 08
n
0.79
y 3.121e+08
3.121e+08
7.90e+03
y

28100

27
38*
4.268e+07
n
5
282e+07
n
0.81
9.549e+07
9.549e+07
2.26e+03
y

8600

28
10*
4.813e+07
n
6
109e+07
y
0.79
y 1.092e+08
1.092e+08
2.83e+03
y

9840
1,2,8,9-TCDD
Totals
Results


analytical
Perspectives
(Form: TOT]



Totals class: PeCDD EHPC


Function: 2 Run
# : 10


Checkcode: 1340 /
File
Name: 080723P2
Sample
#
10
Sample text: P9464_6042_007 Run#
II
-ACD-M23-
3 Air Tr» ^

Acquired: 24-JUL-
-08 03:34:58 Processed: 2<
-JUL-08 13
: 39:00




Total Cone.: 415230


Unnamed Cone.
: 273141.613 Homolog
count: 10

RT
ml Resp
mod.
m2 Resp
mod. RA
Resp
Adj_Resp
S/N


Cone.
Name
30
00,
4.583e+08
n
2
895e+08
y
1.58
S» 7 . 4 7 7 e» 0 8
7.477e+08
5.94e+03
y

76900
1,2,4,7,9-PeCDD
30
*2.
1.103e+08
n
6
959e+Q7
zi
1.59
y. 1.799e+08
1.799e+08
1.91e+03
y

18500

31
16
2.928e+08
n
1
846e+08
n
1.59
4.773e+08
4.773e+08
5.49e+03
y

49100

31
2§
1.928e+08
n
1
216e+08
n
1.59
y 3.144e+08
3.144e+Q8
3.92e+03
y

32300

31
3*
2,261e+08
n
1
427e+08
ti
1.58
y* 3.688e+08
3.688e+08
4.22e+03
y

37900

31
50
4.026ei08
n
2
530e+08
n
1.59
y 6.556e+08
6.556e+08
4.74e+03
y

67400

32
13.
2.451a+08
n
1
530e+08
n
1.60
f 3.381e+08
3.981e+08
4.33e+03
y

40900

32
43»
2.218e+08
n
1
413e+08
y
1.57
3.631e+08
3.63le+08
4.39e+03
y

37300
1,2,3,7,8-PeCDD
32

1.617e+08
n
1
002e+08
n
1.61
Y 2.619e+08
2.619e+08
3.05e+03
y

26900

33
IT
1.673e+Q8
n
1
034e+08
y
1.62
y. 2.707e+08
2.7Q7e+08
3.01e+03
y

27800
1,2,3,8,9-PeCDD
Totals
Results


Analytical
Perspectives
[Form: TOT]



Totals class: HxCDD
EMPC


Function: 3 Run
ft: 10


Checkcode: 1340
File
Name: 080723P2

Sample
#:
10
Sample text: P9464_6042_007 Run#
II
-ACB-M23-
3 ftir Tr»

Acquired: 24
-JUL-
08 03:34
:58 Processed: 24
-JUL-08 13
:3 9:00




Total Cone.: 414250


Unnamed Cone.
: 274781.776 Homolog
count: 8

-------
OPUSquan oil MM1
26
-JUL-2008
11
: 20










RT
ml Resp
mod. m2 Resp mod.
RA

Resp
Adj_Resp
S/N


Cone.
Name
34
5S
2.907e+08
n
2.366e+08
y
1
.23
* 5
273e+08
5.273e+08
1.04e+04
y

54000
1,2,4,6,7,9-HxCDD
35
37
5.266e+08
n
4.252e+08
n
1
24
Y 9
518e+08
9.518e+08
1.87e+04
y

97500

35
5?
6.498e+08
n
5.257e+Q8
n
1
24
V 1
176e+Q9
1.176e+09
1.80e+04
y

120000

36
oy
1.065e+08
n
8.660e+07
n
1
23
V 1
931e+08
1. 931e+08
3.57e+03
y

19800

36
4 2
0Sle+09
2.051e+09
5.12e+04
y

110000

25

7.702e+08
y
9.822e+08
y
0
78 V 1
752e+09
1,752e+09
4.76e+04
y

94400

26
07*
5.648e+08
n
7.171e+08
y
0
79
1
282e+09
1,282e+09
3.66e+04
y

69000
2,3,4,8-TCDF
26
ia,
5.719e+08
y
7.209e+08
y
0
79
y i
293e» 09
1 - 293c'09
3.53e+04
y

69600
2,3,7,8-TCDF
26
H
1.727e+09
n
2.182e+09
n
0
79 > 3
910e+09
3.910e+09
1.03e+05
y

211000

26
53-
1.401e+08
y
1.810e+08
y
0
77
* 3
212e+08
3.212e+08
7.38e+Q3
y

17300

27
09-
1.282e+08
n
1.656e+08
n
0
77
¥• 2
937e+08
2.937e+08
7.57e+03
y

15800

27
24,
1.862e+07
n
2.845e+07
n
0
65
^4
707e+07
4.707e+07
9.87e+02
y

2530

-------
OPUSquan
on MM1
26-
-JtfL-2008
11:
20









27
•,49*
1
.061e+07
y
1.924e+07
y
0.55<{J? 2.985e+07 2.439e+07
7
7 6e+02
y

1310

28
7 V
9
.518e+07
n
1.215e+08
y
0.78
y,2
,167e+08
2.167e+08
5
61e+03
y

11700
1,2,8,9-TCDF
Totals Results

Analytical
Perspectives
[Form: TOT]



Totals
Class: PeCDF EMFC



Function: 2 Run
#:
10


Checker ode; 1340
File Name; Q80723P2 Sample
#;
10
Sample text: P9464_6042_007 Run#
ii
-ACD-M23-
-3 Air Tr» '

Acquired; 24-JUL-Q8 03:34:58
Processed: 24-JUL-Q8 13
:39;00




Total
Cone.; 1350000

Unnamed Cone
: 1118941.
636 Homolog
cour.r : 16

RT

ml Resp
mod. m2 Resp
mod. RA

Resp
Adj_Resp
S/N


Cone.
Name
29
55.
2
057e+09
n
1.312e+09
y
1 .57 -y 3
3 69e+09
3.369e+09
1
50e+04
y

207000

30
04*
2
172e+09
y
1.380e+09
y
1.57
J 3
552e+09
3.552e+09
1
39e+Q4
y

218000

30
11
5
416e+08
y
3.400e+08
y
1.59
y 8
816e+08
8.816e+08
5
50e+03
y

54100

30
17**
1
739e+08
y
1.087e+08
y
1.60 -f 2
826e+08
2.826e+Q8
1
43e+03
y

17300

30
3U
2
902e+08
y
1.847e+Q8
y
1.57 *4
749e+08
4,749e+08
2
09e+03
y

29100

30
40
4
930e+08
y
3.170e+08
y
1.56
y 8
101e+08
8.101e+08
5
19e+03
y

49700

30
4T>
1
559e+09
y
9.839e+08
y
1.58
?2
543e+09
2.543e+09
9
70e+03
y

156000

31

4
139e+08
n
2.626e+08
n
1.58
It 6
765e+08
6.765e+08
3
86e+03
y

41500

31
14
8
085e+08
n
5.141e+08
y
1.57
y 1
323e+09
1.323e+09
7
23e+03
y

83900
1,2,3,7,8-PeCDF
31
30*
1
512e+09
n
9.555e+08
n
1.58
y 2
468e+09
2.468e+09
9
44e+03
y

151000

31
4k
1
271e+08
y
8.033e+07
y
1.58
y 2
07 4e+ 08
2.074e+08
1
01e+03
y

12700

32
06.
1
699e+08
y
1.086e+08
y
1.56
y. 2
785e+08
2.785e+08
1
51e+03
y

17100

32
14
1
472e+09
ii
9.360e+08
n
1.57
It 2
408e+09
2.408e+09
1
36e+04
y

148000

32
23"
1
373e+09
y
8.686c 08
y
1.58
X 2
242e+09
2.242e+09
1
13e+04
y

133000
2,3,4,7,8 PeCDF
32
42n
1
717e+08
y
1.098e+08
y
1.56
y 2
815e+08
2.815e+08
1
54e+03
y

17300

33
27"
1
379e+08
ii
8.731e+07
y
1.58
y 2
252e+0B
2.252e+08
1
37e+03
y

13800
1,2,3,8,9-PeCDF
Totals Results

Analytical
Perspectives
[Form: TOT]



Totals
3lass: HxCDF EMPC



Function: 3 Run
#:
10


Checkcode: 1340 /
File Name: 080723P2
Sample
#:
10
Sample text: P9464_6042
_007 Run#
ii
-ACD-M23-
3 Air Tr»

Acquired: 24-JUL-08 03:34:5
8 Processed: 2<-
-JUL-08 13
:3S
: 00




Total Cone.; 777770

Unnamed Cone
: 418374.987
Homolog
count: 13

RT

ml Resp
mod. m2 Resp
mod. RA

Resp
Adj_Resp
S/N


Cone.
Name
34
10
5
529e+08
n
4.419e+08
y
1.25-y 9
948e+08
9.948e+08
5.
16e+03
y

68300
1,2,3,4,6,8-HxCDF
34
23
1
680e+09
n
1.338e+09
n
1.26
3
018e+09
3.018e+09
1
49e+Q4
y

207000

34
43
1
369e+08
y
1.093e+08
y
1.25
X 2
462e+08
2.462e+08
1
17e+03
y

16900

34
5?
2
353e+08
y
1.879e+08
n
1.25
y 4
231e+08
4.231e+08
1
95e+03
y

29000

35
09,
9
752e+07
y
7.723e+07
y
1.26
yi
748e+08
1.748e+08
8
90e+02
y

12000

35
34
8
270e+08
y
6.6Q7e+08
y
1.25
y i
488e+09
1.488e+09
7
69e+03
y

102000

35
4r
7
126e+08
y
5.682e+08
y
1.25
y. i
281e+09
1.281e+09
6
07e+03
y

86600
1,2,3,4,7,8-HxCDF
35
59
7
3 3 Oe t 08
y
5.83 5e+08
y
1.26
36.1
316e+09
1.316e+09
6
55e+03
y

82900
1,2,3,6,7,8-HxCDF
35
5a.
1
.127e+0B
n
8.926e+07
y
1.26
X 2
020e+08
2.020e+08
9
08e+02
y

13900

36
08
1
¦497e+08
y
1.190e+08
y
1.26
¥-2
687e+08
2.687e+08
1
33e+03
y

18400

36
16
1
536e+08
y
1-218e+08
y
1.26
x~2
754e« 08
2.754e+08
1
38e+03
y

18900

36
25
7
.7610+08
n
6.227e+08
y
1.25
Yl
399e+09
1.399e+09
7
00e+03
y

93300
2,3,4,6,7,B-HxCDF
37
38
1
.993e+08
n
1.592e+08
y
1,25
f 3
585e+08
3.585e+08
1
38e+03
y

28300
1,2,3,7,8,9-HxCDF
Totals Results

Analytical
Perspectives
[Form: TOT]



Totals class; HpCDF
EMPC



Function; 4 Run
#:
10


Checkcode: 1340
File Name: 080723P2
Sample
#:
10
Sample text; P9464_6042
_007 Run#
ii
-&CD-M23-
3 Air Tr»
-------
OPUSquan on MM1 26-JUL-20Q8 11:20
Acquired: 24-JUL-08 03:34:58 Processed: 24-JUL-08 13:39:00
Total Cone.: 243540	Unnamed Cone.: 73022.580	Homolog count: 4
RT	ml Resp mod. m2 Resp m
39:01*	1. Q50e+09 n 1.017e+09 y
39:2?	2.374e+08 n 2.317e+08 n
39:3?	2.253e+08 n 2.211e+08 n
40:5?	1.265e+08 n 1.210e+08 y
:. RA	Resp Adj_Resp S/n
1.03 j/ 2 . 067e+09	2 . 067e+09	1.59e+04
1.02 x 4.691e+Q8	4.691e+08	3.39e+03
1.02 4.464e+08	4.464e+08	3.36e+03
1.05 ^5. 2.4?5e+08	2.475e+08	1.74e+03
Cone, Name
y	148000 1,2,3,4,6,7,8 HpCDF
y 37400
y 35600
y	22200 1,2,3,4,7,8,9-KpCDF
-------
ST
File: 080723P2 Acq: 24-JUL-200B 03:3^:58 GC EI+ Voltage Sl3™ AutospGC-Ultirr.aE
Sample# 10 Text: P9464_6042_007 Run# II-ACD-M23-3 Air Train Vial# 39 File Text
316.9824 S:10 PKD(S,5,3,100.00%,750.0,0.00%,F,F) Exptj OF_CL4
; AP DBS
25:41 26:05
29:29
20:09
28:11
26:42
22:59
100&
21:00	22:00	23:00	24:00
366.9792 S:10 F:2 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
25:00
26:00
27 :00
28:00
i Ana 29:33
iuu^r 59-49
80.
60.
40,
20.
30:16 30:29 30:39 30:58 31:09 rVi^fi 31:39 31:53 32:1n 32:19 32:3^ 32;44
33:00;1"1 33:19
29:00
33:58
33:36 33:50 T 2 .
Time
30:00	31:00
380.9760 S:10 F:3 PKD{S,5.3.100.00%.750.0,0.00%,F,F) Expt: DF_CL4-
32:00
34:27	„„
34:15 "> 34:37
35:5936:10 r6=19 36:37 36;
33 ; 00
37:07 37:20r?:26 37:45
34:00 Time
38:19
38:02
100%
35:13 35:25 35:39
34:53
38:00
35:00	36:00
430.9728 S;10 F:4 PKD (5,5,3,100.00%,750.0,0,00%,F,F) Expt: DF_CL4
37:00
41:32
41:01
41:27 r 41:40
40:44
41:56
39:41
40:08 40:19 40:28
lOOfi
38:58
38:45
39:10
39:27
Time
38:36 38:48 39:00 39:12 39:24 39:36 39:48 40:00 40:12 40:24 40:36 40:48 41;00 41:12 41:24 41:36 41:48 42:00
454.9728 S:10 F:5 PKD{5,5,3, 100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
Time
100% 42:10 42^17
80J
60.
40.
20.
42:33
42:12
42:24
42:36
42:48
T3! 00'
' 43 12 '
43:24
43:36
43:48
'44!00'
'44112 *
44:24
i—i | 1 r
44:36
'44Ue' ' 45:00
7E6
0E6
2E6
. 5E6
5E5
Time
-------
File: 080723P2 Acq: 24-JUL-
Saaplet 10 Text: P9464_6042
319.8965 S:10 BSUB(10000,15,
2008 03:34:58 GC EI+ Voltage SIR Autospec-UltimaE
_007 Run8 II ACD-M23-3 Air Train Vial# 39 File Text: AP DBS
-3,0) Expt: DF_CL4-8 Noise: 6469
25:10
27:30
26:51 A1.38E8
A1.92E8
26:03
A1.05E8
23:14
A1.18E8
24:05
A7,50E7
7:38
. 27E7
24: 56
Al.OBi
2
21:00
321-8936 S:10 BSUB(10000,15,
1001,
80.
60.
40.
20.
22:00
-3.0) PKD(5,
23:00	24:00
5,3,0.10%,750.0,0.00%,F,F)
24:05
A9.48E7
23:14
A1.50E8
25:00
Expt: DF_CL4-8
25:10
A3.37E8
24:56
A1.39
26:00
Noise: 5504
27:00
28: 00
26:51
A2.44E8
26:03
A1.32E8
8.11E7
~j -jn 28:10
28E7 A6'11E7
A
29:00
4.3E7
3.4E7
2.6E7
1.7E7
8. 6E6
Time
5. 5E7
4.4E7
3.3E7
2.2E7
.1.1E7
21:00
327.8850 S:10 BSUB(10000,15,
100&,
80.
60.
40.
20.
22:00
-3.0) Expt:
23:00	24 I 00
DF CL4-8 Noise: 1725
25:00
26:00
27:00
28: 00
23:13
Al.11E6
I O". .
24:05
A7.42E5
25:10
A2.S7E6
26:03
A1.07E6
26:00
26:51
Al.
27:09
27:30
A1.44E6
29:00
29:00
Time
4
3E6
i.3
4E6
12
6E6
Li
7E6
Is
5E5
21:00
331.9368 S:10 BSUB(10000.15,
lOOi
80 J
60j
403
2qJ
22:00	23:00	24:00
-3.0) Expt: DF_CL4-8 Noise: 1599
23:12
A1.82E7
25:00
26:26
A1.90E7
27:00
27 :07
A1.82E7
28:00
"I	1	1	1	1	T-
28:00
Time
1.SE6
I.6E6
!. 7E6
L.8E6
>.0E5
21:00	22:00	23:00	24:00
333.9339 S:10 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 2045
25:00
26:00
27:00
1001,
80.
60j:
40"
20.
23:12
A2.22E7
26:26 27:07
A2.32E7 A2.24E7
29:00
Time
5
4E6
14
3E6
i.3
2E6
12
1E6
Li
1E6
21:00
22 ¦ 00
23:00
24:00
25:00
26:00
27 :00
28:00
29 ;00
Time
-------
File: 080723P2 Acq: 24-JUL-2008 03:34:58 GC BI+ Voltage SIR Aucospec-ultimaE
Sample# 10 Text: P9464_6042_007 Run# II-ACD-M23-3 Air Train Vial# 39 Pile Text: AP DBS
355.8546 S: 10 F:2 BSUB(10000,15,-3.0) PKD(5,5,3,0.10%,750.0, 0.00%, F, F) Expt: DF_CL4-8 Noise:
11651
30:09
31:16
A4,58E8
A2.93E8
31:49
31:34 A4.03E8
A2.26E8
32:44
A2.22E8
: 49
62E8
32 :13
A2.45E8
33:10
A1.67E8
30:41
A1.10E8
30:00
357.8517 S:10 F:2 BSUB(10000,15
30:09
A2.89E8
DF CL4
Expt:
Noise:
31:16
5.6E7
100S
A1.85E8
31:49
32 :44
A1.41E8
: 49
. 00E8
32:13
31:34
A2.53E8
4.5E7
A1.53E8
A1.43E8
33:10
A1.03E8
3 -4E7
30:41
A6.96E7
2.2E7
1.1E7
30:00	31:00
367.8949 S:10 F:2 BSUB(10000,15,-3.0) Expt: DF_CL4-B Noise: 3031
100%,
80.
60.
40.
20J
32:00
32 :11
A2.39E7
32:42
A2.37E7
8.7E7
7.0E7
S.2E7
3.5E7
1.7E7
34:00 Time
34:00 Time
.6. 5E6
:5.2E6
.3 . 9E6
:2 . 6E6
.1.3E6
30:00	31:00
369.8919 S: 10 F:2 BSUBdOOOO, 15 , -3 . 0) Expt; DF_CL4-B Noise: 24551
32:00
33:00
30:00	31:00
366.9792 S:10 F:2 PKD(5,5,3,100.00%,750.0,0.00%,F,F) Expt: DF_CL4-8
32 :11
32:42
A2.33E7
A1.50E7
32:00
34:00 Time
4 . 3E6
3 . 5E6
2 . 6E6
Ll.7E6
, 6E5
34 :00
Time
1005^
80.
60.
40.
20.
29 : 33
r 29:49
30:16 30:29 30:39 30:58 31:09	31:39 31:53
32:15j 32:19
32:36
~! 32:44 33:
33:19 33:36
33:58
33:50 n
_2
0E6
_1
6E6
.1
2E6
_S
0E5
.4
0E5
30:00
31:00
32:00
33:00
34:00 Time
-------
File: 080723P2 XeqT~24-JUL-2008 03:11751 GC F.T+ Voltage SIR Autospec-UltimaE
Sample# 10 Text: P9464_6042_007 Run# IT ACD M23-3 Air Train Vial# 39 File Text: AP DB5
389.8156 S:10 F:3 BSOB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 11237
35:37 35:55
100S,
SO.
60.
40.
20.
A5.27E8 A6.50E8
34:57
A2.91E8
36:02
. 06E8
v/n /,,,
/
A1 .«7EB
~1
36:58
A1.99E8
35:00	36:00	37:00
391.8127 S:10 F:3 BSUBtlOOOO,15,-3.0) PKD{5,5,3,0.10%,750.0,0.00%,P,P) Expt: DF_CL4-8 Noise: 9931
35:37 35:55
lOOt	A4.J5E8 A5.26E8
80.
60.
40.
20.
34:57
A2.37E8
6:02
66E7
36:47
A1.51E8
37:05
U-24E8
35:00
36:00
37:00
401.8559 S:10 F:3 BSUB(10000,15,-3.0! Expt: DF_CL4•8 Noise: 3941
100%
80.
60.
40.
20.
36:39
Al.
37:04
38:00
38:00
.1-5E8
.1.2E8
.9.1E7
.6.1E7
.3 . 0E7
Time
1.2E8
9.7E7
.7 . 3E7
.4 . 8E7
.2.4E7
Time
5
8E6
4
6E6
3
5E6
2
3E6
1
2E6
35:00	36:00
403.8530 S:10 F:3 BSUB(10000,15,-3 , 0) Expt: DF_CL4-8 Noise: 15855
lOOi
80i
60.
40
20.
37:00
36:39
Al
35:00	36:00
380.9760 S: 10 F:3 PKDI5,5,3,100.00%,750.0,0.00%,F, F) Expt: DF_CL4-8
100& 34;15 :2T _34j37 34:53 35:13 35:25 35:39 35:59 36x10 ?6''}9 3_6i37 __3 6i
80.
60.
40.
20j
37:00
38:00
37:04
Al.67E7
37:07 37:20 p7 ! 26
Time
.4.6E6
.3 .7E6
.2. 7E6
.1. 8E6
.9 . 1E5
38:00
37:45 38:02 38:19
Time
6 ,7E6
5.4E6
4.0E6
2 . 7E6
1.3E6
35:00
36:00
37: 00
38:00
Time
-------
File; 080723P2 Acq: 24-JUL-2008 03:34:58 GC EI+ Voltage SIR Autospec-UltimaE
Sample# 10 Text: P9464_6042_007 Run# II-ACD-M23-3 Air Train Vial# 39 File Text
423.7767 S:10 F:4 BSUB{10000,15,-3.0! FKD(5,5,3,0.10%,750.0,0.00%,F
39:25
100%,	A6.89E8
AP DB5
P) Expt: DF..CL4 8 Noise; 12816
80.
60s
40.
20.
40:17
ft6.89E
"i1 i ' ! J ¦ ! i	j 1 1 ! '
39:24 39:36 39:48 40:00 40:12
0) PKB(5,5,3,0.10%,750.0,0.00%,F,F
39:25	H
A6.54E8	l0:17„
A6.55E8
40:24
40:36
DP CL4
2.
0E8
Li.
6E8
Li.
2E8
L7.
9E7
l4.
0E7
00
Time
1
9E8
Li.
5E8
Li.
1E8
L7
6E7
l3
8E7
00
Time
4
9E6
l3
9E6
L2
9H6
Li
956
L9
7E5
00
Time
4
6E6
13
7E6
i2
8E6
Ll
9E6
:.9
3E5
00
Time
4
0E6
L3
2E6
i2
4E6
Ll
6E6
i.8
1E5
00
Time
38:36 38:48 39:00 39:12
425.7737 S.-10 F:4 BSUB(10000,15, -3
1004
80i
60i
40i
20i
40:48
Noise:
41:00
11066
41:12 41:24 41:36 41;46
39:36
"T""T""i—r—i—i—r-r	i'"
38:36 38:48
39:00 39:12 39:24
435.8169 S:10 F:4 BSUB(10000,15,-3.0) Expt:
100%
80i
60.
40.
20.
39:48 40:00 40:12
DF_CL4-8 Noise: 5324
40:16
A1.87E7
40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48 42:
38:36 38:48 39:00 39:12
437.8140 S:10 F:4 BSUB(10000,15,-3,
1008
80J
60i
40i
20i
-r
39:24 39:36 39:48 40:00 40:12
0) Expt: DF_CL4-8 Noise: 5397
40:16
A1.74E7
I i i|TT
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' ' I	' ' ' i i I 1 1
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48 40:00 40S12
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40:36 40:48
40:44
41:00
41:01
41:12 41:24 41:36 41:48
41-12
41:27 r 41:40
41:56
39:36
38:36 38:48 39:00 39:12 39:24
39:48 40:00 40:12 40:24 40:36 40:48 41:00 41:12 41:24 41:36 41:48
-------
File; 08Q723P2—Acq: 24-JUL-200B 03 :'34 :'58" GC EI+ Voltage SIR Autospcc-UltimaE
Sample# 10 Text: P9464_6042_00? Run# II-ACD-M23-3 Air Train Vial# 39
457.7377 S:10 F:5 BSUB(10000,15,-3.0) PKD<5,5,3,0.10%,750,0,0,00%,F,F)
100%,
80.
60.
40.
20.
Pile Text; AP DBS
Expt: DF_CL4-8 Noise: 1413
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43:36 43:48 44:00 44:12
Expt: DF_CL4-8 Noise: 935
43:52
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44:24
44:36
44:48
1 I 1 1
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Noise:
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5 BSUB<10000,15,-3.0) Expt;
43:00
DF_CL4-8
43:24
3945
43:48
44:00
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43:51
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43:36
43:48
44:00
44:36
Time
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43:07
43:47
100%
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44:48
45:00 Time
-------
File: 080723P2 Acq; 24-JUL-2008 03:34:58 GC EI+ Voltage SIR Autospec-UitimaE
Sample# 10 Text: P9464_6042_007 Run# II-ACD-M23-3 Air Train Viali 39 File Text: AP DBS
303.9016 S:10 BSUB(10000,15,-3.0) Expt: DF_CL4-8 Noise: 79065
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r 23:48
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24:00
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24:00
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23: 00
DF CL4-8
24 : 00
Noise: 2585
25:00
27 : 00
28: 00
28:11
Time
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4.2E4
26:08 26:22
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20:26
21:00
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23:00
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25:00
26:00
27:00
28:00
29:00
Time
-------
File: 080723P2 Acq: 24-JUL-2008 03:34:58 GC EI+ Voltage SIR AutOSpec-UltimaE
Sample# 10 Text: P9464_6042_007 Run# II-ACD-M23-3 Air Train Vial# 39 File Text: AP DBS
339.8597 S:1Q BSUB<10000,15,-3.01 PKD{5,5,3,0,10%,750.0,0.00%, F, Fl Expt: DF_CL4-8 Noise: 1708
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25:41 26:05
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25:00
26:00
21:00
22:00
23:00
24:00
-------
File: 080723P2 Ac?fr~Z3'-jm7-''2OTff
Sample# 10 Text; P9464_6042_007
339.8597 S:10 F:2 BSUB<10000,15,
29:56
100%	A2.06E9
80,
60.
40.
20.
113734758GC EI+ Voltage SIRAutospee-UltimaE
Run# II-ACD-M23-3 Mr Train Vial# 39 File Text: AP DBS
-3.0) Expt: DF_CL4-8 Noisg: 360506
30:46
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42E8
30:4
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32:00
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32: 00
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32 : 00
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30:40
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31:12
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32:22
A2.42E7
30:00
409.7974 S:10 F:2 BSUB(10000,15,
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-3.0) Expt: DF_CL4-
32 :00
3 3 : 00
Noise: 3004
34:00 Time
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6.7E4
5. JE4
33:24
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33:46
30:06
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29:36
r
1. 3E4
32 :00
30:00
31:00
33: 00
1: 00 Time
-------
File: 080723P2 Acq: 24--JUL-2008 03:34:58 GC EI+ Voltage SIR
Sample# 10 Text: P9464_6042_007 Run# II-ACD-M23-3 Air Train
373.8207 S:10 F:3 BSUB(10000,15,
34:29
A1.68E9
-3.0) Expt: DF_CL4-8 Noise;
Autospec-uicinal
vial# 39 File Text: AP DBS
374654
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36:00
Noise: 360614
37:00
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36:00
Noise: 21163
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37:00
38:00
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1
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35:00
15,-3.0)
36:29
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Expt: DF_CL4-8
36:00
Noise: 10284
35:41 35:49
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37:00
38:00
36:08
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Expt: DF_CL4-8
36:00
Noise: 1096
37:00
38:00
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3.8E8
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35:47
1.8E4
1.4E4
9.2E3
4 . 6E3
35:00
36:00
37:00
38:00
Time
-------
/
File: 080723P2 Acqr^'-m'-SOTTTO^^SB GC EI+ Voltage SIR Autospec
Sample* 10 Text: P9464_6042_007 Run# II-ACD-M23-3 Air Train Vial# 39
407.7818 S: 10 F: 4 BSUBUO0OO, 15, -3 . 0) Expt: DF_CL4~8 Noise: 54136
39: 07
10 OS,	A1.Q5E9
80.
- tJl C i infiE
File Text: AP DBS
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38:36
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39:36
39-26 A2.21E8
A2.32E8 r
40:24 40:36 40:48 41:00
Expt: DF_CL4-8 Noise: 18742
3.0E8
2.4E8
1.8E8
1.2E8
6.0E7
38:36 38:48 39:00 39112
417.8253 S.-10 F:4 BSUB(10000,1 5. 3
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40:00 40:12
Noise: 19180
40:52
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41:12 41:24 41:36 41:48 42:00 Time
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39:35
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40:24 40:36 40:48 41:00
38:36 ' '38:48' ' 39:00 39112
479.7165 S: 10 F:4 BSUBdOOOO, 15,-3
40:51
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00 Time
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39:24 39136 39:48 40:00 40:12
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40:24 40:36 40:48 41:00
41:12 41:24 41:36 41:48 42:00 Time
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41:12 41:24 41:36 41:48 42:00 Time
-------
/
file:' '080723p2 Acq: 24-OUL-2OT8"
03:34:58 GC EI+ Voltage SIR
Autospec
-Ultj-maE





Sample* 10 Text; P9464_6042_007
441.7428 S: 10 F:S BSUBdOOOO,15,
Run# II-ACD-M23-3 Air Train
-3.0) PKD(5,5,3,0.10%,750.0,0.
Vialf 39
00%,F,F)
File Text: AP DBS
Expt: DF_CL4~8 Noise: 1228
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44:36 44:48
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Expt: DF.
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-3.0) Expt: DF_CL4-8 Noise:
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-3.0) Expt: DF_CL4-8 Noise:
757






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40_
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45:
00 Time
-------
Client/Plant Maine; ARCADIS / RTl
Anal) it: . R^l_
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Sample Man i\ & Components:
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Rl- \ // UM>7 [>	Fngc (
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Date of Anal) , j)T l4} OS	
Anatvte(s); PM I0imen»i, _
and fronts rinses
particulate catch only. The total catch reported for each run is a
sura of the filter and rinse catches. The acetone blank catch has
been subtracted out of sample rinse catches in proportion with their
; vo i irmoH ,
Surnniiii v of Instrumentation:
balance
Analytical Detection Limits): 0.5 nigs
Miscellaneous C.'mttroenls Regarding Sample Vrtalssis: ( Note unusual catch weiszltK inlei tcreiKVs. odd
sample behavior, mid Mops iaken to confirm unusual results. Also nulc any deviations ironi sun h laid analytical
procedures. together uirli justification and possible aiiect on results. Specif) samples when applicable.)
No Hi  .Iv. M< u . ! 5 -Lu'	p, , i,r. ,	.
See Data Sheets for individual sample descriptions.
Confirmation of Data Review;
ri
OA Officer Nipaaiuie
\ I. Bruce Nenei , Lab QA Uitker >
Date
-------
PARTICULATE SAMPLING LABORA fORY RESUL TS_ {V*)}A>
.7/f '/	1 ' ^ ^
Method. 201A	Filename: ARCADIB
i c r» r(v i [/ / t vW.	1 j / (F	FHt r if(ni i	w "V,* MtA •
3,7470
0.11S9
Date
| Inn
Date
©
 @
ml)
hlNSr s^h^\E\VT 7
Fi!h>! Catch, my
Rinse Catch, mg.
Chink hi^iouf mq
Not Rinse Catch, mg
Hi TFRABl £ PARTICULATE, mg.
n>rtnk h'L'ih'i
f'u.ii At m>t
Id, 2 vu rn«/
Resitltm, mg.
Volume, mA
<~}; nil
Cone.. mg/mg
Uppf.
Imit, rttg/mg
Legend;
1445
«,4 9
1 1
0,0
t t
56.0
Visual Incpactforr
21.8
Rurt IP
L^wnr
Texture:
f Oi'j'yn iV3!fct
Relative Comp:
i<} Stack Fitter
t LAl *
STAIN
NONE
VLiV
NqzzIb Rins&
BLACK
HLM
Mi&cclumtrftus Notes & Comments
TWO FILTERS WERE SUPPLIED
IMF. FILTER CA1CH IS A RGSUL T OF THE ADDITION OF THE TWO CATCHES.
Pr-mi'V* Date.
29-Jul-Ofl
Priming Tims
01 3! PM
-------
PART1C	\MPUNG LABORATORY RESULTS
Run !slufn*'pr
08071$
ARCABtS
File Pathway:
1836S
18757
THW
, i ir,
w
Front
1466
(< - 10 uo)
ISO #
/(iff
Dab
07/23
07/28
Trllf T/Vf
Rifi I	'LtT i'V"
ml)
rtiter CtUrJh my
4? 7
NA



Rinse Catch, mg.
16
8J



Blank Residue, mg.
0,0
QJ



Net Rinsf Cztch mq





Fit TERABLE PARTICULATE, mg.
46. f
as









L1H'lk LVi' "j />' '44''
Visual inspection
	i



Final wt., m$. 3J540B
,v"* ^
M si f r «c
Ff/ter W.nse

A/fJ *« f\l
1-h- \\t fihj 1 v •nJO

BLACK
SA'iJkV^


K'ci./tfor mq a.J
r.^vmrnv
STAIN
H/.W


¦voiwj iw
foreign Matter
NONE
/vow;:


iVkS-'fy -W/'m/

WVut?
if a;


rhs





I'fVHvl"?)ff mi/'fNiy ^ Mi"Ci <}.'
Miscellaneous Not^s & Comments'



Legenj- tq. = rmo1 Wt-yht





-------
PARTICUIA TE SAMPLING LABOR A TORY RESUL TS (PM10)
F	
Plant Name: RTI / USEPA
D
Page- 3 of 7
Fi
Fife Pathway: C:\JC
'A > OW* }*>
Run Number
Hilar Container #
Sample I/O. Hunt H..11 hii.s.. t	Nozzle & Cic/nii, r!,n~c #
1418	1448
	1 ^VucA
Date I (in*	Date
ft/CP	BNL	3 Mil	" ' \P3?0
fffl"	BNL	© jSfr/W	p r ?«	~ 3W
Filter Catch, mg.	24.4	NA
Rinse my	1.8	9 J
Riant; Residue unj	0.1	i) I
Nvt Rinse Catch, n' Rmsf
Rut, /i.'
In Star l< F'ltbr

BLACK
BLACK
tUAt 1
Te\rcrp

	
GRANULE LU
Ft,t**i\jn Akrfit't
n< >we
w ;/v£
NONE
¦
MEDHJU
(t_M'
MtPIUM
Miscellaneous Notes & Comments:
Priming Date:
Printing Tims:
01-31 PM
-------
PARTICULQ'f c SAMPLING LABORATORY REl
Plant Name: R TI / USEPA
Hill I,iff
Filter C
IV' w	6<>
'* • > IV .J	Tf- I'f-V
•-'i /h/J ^ i kJ 1(¦ v\ T g.	i i /,
		«-//.;»Wrw. #	AKrfc K > vch'i" riu^e#
IJ. i'	M®
Ir ~ 1 h/)	( ! R;; ; j
Date I frii'f	Dale
Tare W?„ g,
f- w r,4lii
07/28
( 4U
a
m/j
Fitter Catch mg.
R11 si h h i f\
Blank Residue, mg,
Nft Rinse Catch, mg
HL reRABLC PARTICULATE, mg.
29.5
0 1
!.t
30. e
Bhiok lip ,k> i i
Final wt, mg.
Tare wt,, mg,
Residue, mg,
Volume, mi.
Drip jiy mo>ml
Cone., mg/mg
i if ix>r Lin id my ma
m
16,3
0,1
16.2
16.2
Visual inspection'
~


Ht.m uj
In Vrtuv Filter
Hit"' H,n\f
Nouh i-ini^e
r..,ofo r
^ri\

BLACK
h--y{ute
o7 AIN
HlM
hit M
r >/{ mn

NONt
NONE
RJ-tlfbt-'
MtLLUUM

MIDUM
Miscellaneous Notes 4, Comments-
Legend;
ia'i ~ fd'ai it/eight
t - i1 ihor
R -¦ Rinse
Printing Date;
29-Jui-QS
Printing l"imr
01:31 PV
-------
PAR71CUI A TrSA MPLING LABOR A TORY RESUL TS	fPM10)

Mslh<
" V. ' ,M	K? \Lt i MJ *
!M'c
(< = 10 tig)
07 >_	|jf>»
0,0-14,;
NO
Filename: ARCADIS
" ' r a ^ I	Page 5 of 7	File Pathway CM".' >ni»f
Sample I. D, p,,. it I trill w	H \lu-:h & i;> <:/m #
Vi">	9'T
	( 't'lllljl
Date | Inlt	Date
07,73
07/26
(
RIN^c SAW) £ IVL, g.
Ffltu Catci, mg
14,5
NA
Ri'n-i' mg
1.2
I ft
Blrtiih Rf-Sfjuf, ttttj
0.1
0.1
Not Rimt' Catch, mg.
if
1.7
Fit. TeRABLE PA RTICULA TE, mg.
15.6
1.7
8 >(>,V
I	t"f»~
"0 f >r (
J 00
Visual Inspection:
In Nat
t-thvi h,nt,e
Noirte Rmfp
BLACK
~>T4/W
NONt
MrOIUM
JK< m'N
FILM
NONE
LOW
tponw
IVOME
Mi*cet!dnno(»s> Wovos & Comments:
Lsgsnd;
jht
Printing Date:
2S-Juf-0B
Printing Tims;
-------
PARTfCULA TE SAMPLING LABORATORY RESUl TS (PM'nTi
Plant Name: RTt / USEPA
Method. 2Q1A
Dste Received: OT/i 5/08
PageSof 7
i1
RPA #
Filename,
File Pathway: C.	»»o.
Run Number
Filter Container #
Date
imt
Date

I ML 4}
f (WiA
07/29 ©
a HOT!

BNL
3.6410
07/28 (§
3.6071
hii-z. tot CI
( lil
v P404
( 50 ml}
C<507f!
RiNI-E bAMPLk WT„ g.



n ny> i
Filtm Cau h mg.

1.5

m
Z'iKh nhi

0.5

0,1
tmi

0.1

0.1
Nst Binse Ctilch, mg.

0.4

0.0
FILTERABLE PARTICULATE, mg.

1,9

0.0
f'lrtrlk
h:r.'ti uf, ni>)	i r>40!.
Tdte •*'! //kj	-I
'x\v Kit if* ni< j	i ;i
Volume ',i>	k(ii;
L\P-.T,- ifu/m!	7Hh.O
no/ma
l/p. c/ bp'h mj'mQ	f i v> if -a t	MfeceHatii*oU8> Moles & Comments:
" ^dh (Nc<.r>u"p	i 'toi'Vmj
Visual inwcth'm
	
Ri.n 'I'
»' S'J( I. filtzr

wHirr-
Fdrf/lii
N/;\
Fim.mil htjltei
NONE

i >nv
NoZ7l>? RihSi!
WHITE
GRANUt ATED
NONE
LUW
Leg&nd
\1.31 PM
-------
IEAGENT BLANKLA80RATORYRESUL TS
Paga	7 of 7	File Pathway
Run Number
Container #
litil
Tare Wt„ g.
SAMPLE WT„ g.
07/28 i
07/25 l
(
-------
Ainilytlcai Narniiv e
[Client/Plant Name: MU' M MS ' R11
A«>:thsi: BNL
Analysis Method: LP\ Method 202
Ri- A A- OMJ.'r
Date Rec'd in tab; I ** "K
Date of Analysis- u7q(HIK
Analvte(s); (."uin.icnsible Pa
I ufl
Sample Maim & t onifiomintv
Summary of Sample 1'ivp:
The H-,0 imp.in.qer saxnt
r.i. £
hloride rinses were then ev
II	, i " " 1 h 1 « L I ul|- I a - J
o n s e c ti t .1 v e w e i g h t s a g r e e cl w
i~ r . 4 « !r c-n , t j s !
ime t h 0_y wsrs r^suspsridsri. i
night
id dai 1 s
' IfK":
: i.C C
) T
svery six nours until
ant pressure) until dry at which
] „ 1 c% i( . >}« r • , J - ' i I I I u , .-11! t'l' i 1 1 'lib
ipo rated
irvness aaaj
Summary of Instrumentation:
Analytical Detection t.smiths:	0.5 mgs
1} Hi ' i* r -^r i ,u[ n w n 1 v »> ,<	i J,	ently,
adj usted for NH^Cl arid (NB^)^SO^ rosct ion products.
2) See Data Sheets for individual sample descriptions,
Conurnialiun of Data Review:
n
»		 		..	l<	¦	¦-			¦¦
QA ' 'ittcc. si;:i;.inui
• i i Hpkv Niik.'I . Lab QA Officer}
-------
PARiiCULA l£ SAMPLING i APOH«rOfy VRFSJL fS {ft*A A*
H _ r i h* , - fc s	i I i	fahSiil/ /5
jD^? < N /	ft * tt	Hit- I a! I ,	• l« *1 V \\K aL i\l>,
Run Number	RW	R2-ACD-PM2.5-1
writ-	U4C>	_	7339
Date I {nit	Date	Dal&
(g 1 Hff 6	07 " @ , Pii.
i u ' i	C ' Hl 1 ' ~'h 1
ml) 	J.B-.M7 f HtK) ml) 	 3 ^L_
	 -i i.21	"pom,-
1-nH	1574
BNL (,"»	< / " .f 'M	ii'iC
BNL g . - .)'>	i § .	0.', • ®
( SO ml) 	 ,< f mfl 	60~t'	( M ml)
o n j_	(i i« •?
Organic Fraction Catch mg
Z7
1.2
14
M&thySene Chloride Blank Residue, mg.
0.3
0.1
0.J
Oiq**.nc *-r««*f!on Cdu. h m \
2.4
10
t '1
Inorganic Fmclion Catch, mg.
94,3
9f.l 1
24 7
Water Blank R&sidu®, tng

1.9
1.3
in >rg,snic rrartK j? f.stcb, mg

27,3
_%*» •?
NH4 + Water Residue, mg. ($04 catch x 0.354}

7.33
a 56
Ammonium Chhridv Residue, mg.

-Mi-
-N/A-
£ tl istesi tno^yafiH fra< tn n rjm { mg.

p.oo
t9.fi
TOTAL PARTICULATE, >sig.
86.5
21.0
21.1
Miscellaneous Notes & Comments'
Vi±,ii*st InspcUlQ-i of H'JO
Run tD
p i ac n ptvrn R
Visual 'rspcctf*>n nf bh Cf? _	j
Run tD	R1-ACP-PM2.5-1	R1-ACD-PM
uciiar
1T¦.iv.vir..rI¦	til fi.fl	r-n m
F > M* tei	Nu !L	NoNL
h > ' ^ ^	h i	irw
Printing Date:
3£Wui~0S
-------
rV R-riCUi A IE SAMPUNG LABORATORY RESULTS (EPA MEI HOD iO<')
i' V, tU / 7i «/ r1	fit-H *
-\u ./¦[..!¦ ,;¦¦¦	r	¦¦ v
f* *>! ' ) » » i	Page 2 of 3	Pile Pathway: v. *¦ ,l r «. lV I
Run Number	R2-ACD-PM2.5-2	R2-ACD-PM2.5-3
7eV<» M y
^AMPi.r ivr u
3,3950
3.5946
J r>' c'j
7,028/
ml)
17169
17171
¦>
mi)
5 [i??7
J h 'Ob
 ' t»oo
aoofo
4,0	0 5
fi.WtWt '* f ' /. R wi',?' mo	0,2	02	0.!
Organic fr^rtrort C£*(oh. mcj	3.8	0 8	0.9
Inorganic Fraction Catch, mg.	28.7	34,6	2.1
WdW Biank Residue. mg	1.5	1,8	13
Inoiganir Fr.-K.tion Caich, rng	_T _	^^	11
Nh' i IVaiti Nc^'d e vq f&^r, tc * 'i	1	1 «*	i3«\&
>\rrmO.J>F/n] Crihiuit* tfiQ.	ft. 1	N'A-
AdiiiSted Innr^i.fr fraction Crtrch, mg.	2<	79 $	0 *
TOTAL PARTICULATE, mg.
25.5
Vtsujl lifSyQcOut of r,20
30.2
1.6
r,' Ac L \ j-J
BLACK
FILM
NONE
MEDIUM
i tp.d L'i.rik
WHITE
FILM
Nt 'Nt
i.,». J W V
Vtsujr "smpet
> t*g i fUsitrt
t Oil r
Pmnlifig.DaiK-
-------
\NK LABORA TORY RESULTS (Version 04.28.92)
Page	3 of 3	(ay:
|B»anV
><¦ I! t,f I i h	I ':/¦ i'.?
ni,' j.'i»	Date-
SO ml)
-------
Client Name:
File Pathway:
Analyst:
Sulfate (Method 202I5P1 Analytical Data Sheet
ARCAD1S, fnc,
C"JOBS\T ^C\f liS-Uc 12<>663
130122
20.0
.<0.0
1920S9 19^932 3V402S
195650
All
40.0 ^
259120 261080 2o0i)U;
260072
40.0
RN007160
M2Q2-S04
07/29/2008
%
Deviation
from
Actual
0.12%
-0.11°B
-o w;
0.20%
»0.0Sui
uarjAJ_.000__ ___ _ Slope;. 6503 . Y-Int: 186
Field Samples in. 	D1H20
LoD
2*
S.V-fPLF
ro__
MELD BLANK
T
Inj, I
MM..
135SS
Inj. 2
AREA
AVERAGE
AREA
DILUTIC*
FACTOR
SAMPLE
VOLUME
„ JPiJf
13091
13338
50
Sulfatr
Catci!
-2>«fts).
0.101
M202
C orrectiuii
K:\dor.
0.033
Rl-01
Rl-02
12-01
12-02
R2-03
57997
49809
23793
36850
23795
5S982
51930
25841
40169
22821
1 IN-HOUSE AUDIT REPORT «*"
IN-HOUSE
Inj. 1
199170
58490
50860
24817
38510
23303
Average
AlCJ_
197791
0.84%
2,07%
4 13d o
4.31%
2 09%
SO
50
50
50
50
50
50
50
22.4
IfJ
9.47
14.7
5.®

Ejected
Calculated

%
Sulfate
Sulfate
Percent
Dex,
	»«1 ,.
(ppm)
Dili.
0.70%.
30.0
1
1
Ij
1.30%
S,4i
7,-S
3.56
5.54
5.5-1
Printing Date
3P-JU1-2Q08
Printing Time
D9:Q1 AM
-------
7n i i	j T jr> rhr-'T-at.jyfi „•( 1.
Ij 1 tii-ni ,	t, * r.u L-h, u.c
Gain 0,2 |iS/om	20 pi laj Vol
File	c;\e;\hroiP"chi ui^nuM)" i Ou\
Merhod	>'\exhr<*>«",J-irfliod<\M> f "id
Ssitupii-ID	V) iTM -i
\cq*
Hai
ml 3/
PEP-X100 15 0x4.lmm
1 ot 1
A Results
Peak Name	Ret Time	Ar^ci
Sulfate	6.02	199179
c:\ezchroin\ohroin\ni0071o0 001 - Channel A
M
i
1
1
l
v
0
1
t
s
Peak Name
M
i
1
1
i
v
0
1
t
s
10	15
Minutes
-------
Gain 0,2 ]iS/ca 20 p.1 Inj Vo
j-ile	* c •^/e'lFont'dtioiri ^ I*!-'
Meiiwfl <. \e>4
Xar.tpfe ^fipPiVi:
At.pi>vr| Jul 2\, 2>1'.tS I? 40 -15
nel A Results
Peak Name	Ret Time
Sulfate	6,02
c:\ezchrom\chrom\161078.014 - Channel A
25,	— 				
Peak Name
6	5	15	20
Minutes
-------
it. i .te-.i ! J-ix Jii-.-mit<:„.»{ u M.j/ •- . Col«j. i.: -frtt it.ra PRP-X10Q 150x4.1
LI ti" : 1nil ^'T"P f -T ,	T	l " 5 ml' u. i a
Gain 0.2 ]iS/cm 20 'jil Inj Vol	Temp 40 C
I-ilc	* c \e;tSirj!mch.tuti-RJ(!>0"i
Method	/cl.ron i\rr u Uwi^So 1.rKi
Sample ID . Fl> «
Acquired Jul 2.3 2008 o{):38,'S9
Channel A Penults
Peak Name	Ret Time	Area
Sulfate	6.02
c-\ezchroin\cliiom\Rii007Jo0.002 - Channel A
M
i
1
1
i
v
0
1
t
s
Peak Name
M
i
1
1
i
v
0
1
t
s
10	15
Minutes
-------
instrument: ion Uxiromatoi
Eluent: 4.5 rnM KHP pH 6
Gain 0,2 pS/citi 20 p. 1 1
File	' r''.ejchronrciir^niVr0 "¦
; c:\ezchrom\methods\so<
;> mipU IP i Ft * t
"vC^.tr.nt Jiii ^ Zong 13;3*)
i PRP-X100 150x4,1mm
1 ot 1
Channel A Results
t">-a,c N«:jne.	Ret Time	Ai c a
Sulf .~,f r	6.03
c:\ezcliroiti\chrom\ni007160.008 - Channel A
25-
M
i
i
1
i
v
0
1
t
s
15-
10
Peak Name
f

10	15
> finafe'j
20
•25
20
15
10
25
M
i
1
1
i
v
0
1
t
s
-------
u.-t rn v nt : lcu lhr>. u u oorctph (t
Eluent; 4 . 5 itlM KHP pH 6» 0	I
Gain 0*2 ]iS/cm 20 |il Inj Vol
i >ic	' c \t' >ciifom\ch!c iAI-MM* M1 <'i
.V< tlicd • i,' f.	s ir»ci
j..iinpk G") Rt-tH:
Aa)uueu 11J w\ :.OOS ii.52 55
n PKF-X100 150x4. litim
Page I of 1
Channel A Results
F.-M1' Name	Ret L j iaj	r
-------
f'lle	c .ci'Cfr) ^rri,ch-t)in\R.)(ht "K<
MeihoJ	c V/i,	So 1 >nei
SfnifiieJT?	i\!-03«!
Acquitui	Jul ]fl08Hr»1"V
xriel A P^si.iIts
Peak Name	Ret Time
5ul-Vai-	6. 0 1
c:\ezchi-Qiii\ohrotn\Rn007l 60.004 - Channel A
25
Peak Name
20
M
i
1
1
i
v
0
1
t
s
15-
10-
->
J
5	10	15
Minutes
20
-------
Uj- ! . ¦	. 1> i Cii i ,i ;L; • .[ h
taf'i	I r >- 'J
1; a -1 o, ;	u s / ¦tr	i> 111 rj j *' i
-	t V^cht<>\n\clirc,m'ics s< ; n»'s
Sample IT-	Rl-oj a
A^iarcd *	Jul 2>\ IfttS l y j I, I s
Channel A Results
P^ak Hani-?	r fjmc
Sulfate	6.03
c:\ezehroni\chroni *RnOO 7J oO.00> - Channel A.
2Sr
Peat Name
M
i
1
1
i
v
0
1
t
s
m
I
Al
10
15
20
-------
1 '1 '• Lr :iii ^Tlt I iul. i li I", I j 1 C ul apu 1 , "¦!'
Eluent: 4,5 niM KHP pH 6.0 Flow
Gain, 0.2 pS/cm 20 ]il inj Vol
Fie	: c.v «?t h.oiu\claonj\inCAi"i to io
iVfdliod	t in,
K(iri IP . R2-0"2 a
Acquired J»;i 2v, 2'h>^ 1 >
Ha.i	>>0 150x4.1mm Page 1 °X 1
mis
Channel A Results
I 'JctX. N oil I >-	Ret 1 XTU*r:
Sulfate	6.02
e:\ezchroiriWirom\rnOO7160.006 - Channel A
25-r-
Peak Name
20-
-20
M
i
1
1
i
v
0
1
t
s
I
*
45
-10
1
1
i
v
0
1
t
s
10	15
Minutes
20

-------
Ins u ^ uUtu«11 it ( *~i t_ <. n ur ^ i n 1 r i	Pp " iUll i; ^ t ii l 1 h r xx 3?R.*P""/C10Q ISO' i jT ' ^ ^ ^ i 1)
-7 ! u - •. : i,1 ;ih Tii' t-J* ! .	I> I u i> -_ t : I ^ ,)',,/!> n	"	*"
Gain 0,2 pS/cm 20 pi Jnj Vol	Temp 40 C
File : c:\e2shrom\chrorn\Rn007160.007
Meiised i e>iluoj»i\tr i nv<
^JimpielD 1ulfst©	5 , 98
c:\e/.chroin\chrom\RnOO 7160.007 - Channel A
-20
Minutes;
7S
V
-------
File
\Lltl' «t
ID
AujU'icd
at; ion Caxoitta to graph (C
1. 5 ittM KHP pH 6,0	3?
|lp	I'U |. i i-.;i 'hj
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* " STANDARD LP80RAT0#?I£S,INC.
i, ¥: U T1 f 1 C A T E o F & N A I. Y'S J S
1 ;." ¦. ."¦¦"¦ '¦
-¦: - ' • - ' .'¦¦•« -i' c" : . i ::¦	:
		NOT V.AUP JF ALTERED	
-------
ARCADIS GERAGHDY & MILLER
4915 PROSPECTUS DRIVE
DURHAM, NC. 27713
STANDARD LABORATORIES INC
NORTHERN DIVISION
P.0. BOX 214
CRESSON, PA 16630
(814) 886-7400
3SWI5 STRNMRD LflBOfMTOftJES,INC
DATE: 8- 6-2008
SAMPLE NO. 969971
SAMPLE ID: WOOD #3 <6/25/08) ASH FROM
INCINERATOR
OPERATING CO.: ARCADIS GERAGHDY MILLER
SAMPLED BY: CUSTOMER PROVIDED
MINE:
LOCATION:	DURHAM, N. C.
DATE SAMPLED:
WEATHER:
GROSS WEIGHT:
6/25/08
DATE RECEIVED: 7/25/08
OTHER ID:	P.O. #RB64141 / E-MAIL GENE.STEPHENSON0ARCADIS-US. COM
CERTIFICATE OF ANALYSIS
MOISTURE
VOLATILE
FIXED CARBON
ASH
SULFUR
CARBON
HYDROGEN
NITROGEN
OXYGEN
BTU/LB
MAF BTU/LB
LBS OF S02 PER MILLION BTU
LBS OF SULFUR PER MILLION BTU
ASTM METHOD
AS RECEIVED
D2961 D3302 D3173
27. 48%
D3175M
59. 57%
D3172
11. 27%
D3174
1. 68%
D4239 METHOD B
0. 08%
D3178 D5373
34. 87%
D3178 D5373
4. 14%
D3179 D5373
0. 14%
D3176
31. 61%
D5865
6520
0. 123
DRY BASIS
82. 15%
15. 53%
2. 32%
0. 11%
48. 08%
5. 71%
0. 20%
43, 58%
8990
9204
0. 24
Page 1 of 1
335
occS y°^°Iection th,s document HAS
BEEN PRINTED ON CONTROLLED PAPER STOCK.
	NOT VALID IF ALTERED.
APPROVED BY
APPROVED BY
BLACK SEAL ANALYSIS
-------
A K " A' ¦ I: fit-' k AH i] V S MILL F. k
4-i"- -• c.	..V f;; ;	; V't
hc.
r A NPARD LA MOfc A TOR T F ¦ IMG,
N/!RT K ER N L= I v J' ¦ T nN
H. o. vi'y
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f~ 1. \ • Sr-it- ¦ 7 4tV.:
STANDARD LABORATORIES,INC.
i'ATE :	.1 •
B A MPLS" N'"1.
lAMPi.K I f." : r i. ASH :¦ AMF>L
IN: T N ;-r A r;R
A F'lr
0:-'t.'KAT ! !Jo CO. i ARi AM S i ^'KAriH^Y
SAM Pl.t.; BY:	R	j r-v:-
M I N V •.
: !'.'C'aT ION :	[ ¦[ If, j-j A M, N . C.
M i i.l.FR
r-ATK : - A M f -.!-! ¦:
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!-ki )sv- wr-: :
A T ' * K ¦' ?¦;!. V L L:	s •
11' t€ n':	!^- »R.r«B41 4: L-MA F L GENE. riT R'K- HENSON «A RlJ A D 7 S COH
	 CERTIFICATE QF ANALYSIS
A?'-'T" HETHUP	AS ftE'-KIVKh	r,'F<-*	4 J v.,
MXh?. ;-akr.in lJj27;>	-3.4©::	0
ASH ^	'• 1 K1. 49;:	-U, ,AV
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'	1. V.	.j . 1 J|
MTU ' 1.H	[V,;;,
MAI- r-T'.i'i p-
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LH-:" SUl.KuR f;fvR M IL.L l !.iN B'ru
4®
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i of 1
APPROVED BY ^
APPROVED BY
:,:i™ vow™jlicfWN "ui oscmiSfrWM~~
if tK mkm» ON	RAPO* 'iTOCK.
	-		:	 HOf VAUP g-ALTeweg;
BLACK SEAL ANALYSIS
-------
ARCADIS GERAGHDY & MILLER
4915 PROSPECTUS DRIVE
DURHAM, NC. 27713
STANDARD LABORATORIES INC.
NORTHERN DIVISION
P. 0. BOX 214
CRESSON, PA 16630
<814) 886-7400
STANDARD LABORATORIES,INC.
DATE: 7-30-2008
SAMPLE NO. 969970
SAMPLE ID: WOOD ASH (6/25/08) ASH FROM
INCINERATOR
OPERATING CO.:ARCADIS GERAGHDY MILLER
SAMPLED BYs CUSTOMER PROVIDED-
MINE:
LOCATION:	DURHAM, N. C.
DATE SAMPLED:
WEATHER:
GROSS WEIGHT:
6/25/08
DATE RECEIVED: 7/25/08
OTHER ID:
P.O. #RB64141 / E-MAIL GENE.STEPHENSON0ARCADIS-US.COM
CERTIFICATE OF AHALYSIS
MOISTURE
VOLATILE
FIXED CARBON
ASH
SULFUR
CARBON
HYDROGEN
NITROGEN
OXYGEN
BTU/LB
MAF BTU/LB
LBS OF S02 PER MILLION BTU
LBS OF SULFUR PER MILLION BTU
D2961 D3302 D3173
D3175M
D3172
D3174
D4239 METHOD B
D3178 D5373
D3178 D5373
D3179 D5373
D3176
D5865
AS RECEIVED
2.00%
5. 92%
58. 19%
33. 89%
0. 09%
61. 36%
0. 98%
0.	36%
1.	32%
9159
0.098
DRY BASIS
6. 04%
59. 38%
34. 58%
0. 09%
62.61%
1.00%
0.	36%
1.	36%
9345
14285
0. 19
Page 1 of 1
72
THIS DOCUMENT HAS
BEEN PRINTED ON CONTROLLED PAPER STOCK
	 NOT VALID IF ALTERED.
APPROVED B
APPROVED B
BLACK SEAL ANALYSIS
-------
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
Job Number: 680-38294-1
Job Description: Parris Rd. Landfill - TCLP
For:
ARCADIS U.S., Inc.
4915 Prospectus Drive
Suite F
Durham, NC 27713
Attention: Mr. Gene Stephenson
Terry Hornsby
Project Manager I
terry.hornsby@testamericainc.com
07/21/2008
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or
available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be
reproduced, except in full, without the written approval of the laboratory. All questions regarding this report should be
directed to the TestAmerica Project Manager who signed this report.
TestAmerica Laboratories, Inc.
TestAmerica Savannah 5102 LaRoche Avenue, Savannah, GA 31404
Tel (912) 354-7858 Fax (912) 352-0165 www.testamericainc.com
Page 1 of 4 0
-------
Job Narrative $
680-J38294-1 $
Receipt
All samples were received in good condition within temperature requirements. #
GC/MS VOA
Method 8260B: The following sample was prepared outside of preparation holding time: Wood Ash 6/25 (680-38294-1). #
No other analytical or quality issues were noted. #
GC/MS Semi VOA
No analytical or quality issues were noted. #
GC Semi VOA
No analytical or quality issues were noted. #
Metals
No analytical or quality issues were noted. #
General Chemistry
Method 1030: The followings sample did not ignite: C/D Ash Sample 6/26/08 (680-38294-2), C/D Ash Sample 6/27/08 (680-38294-3), and
Wood Ash 6/25 (680-38294-1); therefore, an ignitability value could not be obtained. The result has been reported as "No Burn" (NB). #
Method 9045C: The following sample was received with greater than 50% of holding time expired: C/D Ash Sample 6/27/08
(680-38294-3), C/D Ash Sample 6/26/08 (680-38294-2), and Wood Ash 6/25 (680-38294-1). As such, the laboratory had insufficient time
remaining to perform the analysis within holding time. #
No other analytical or quality issues were noted. #
VOA Prep
Method 1311: The following sample was received with greater than 50% of holding time expired: Wood Ash 6/25 (680-38294-1). As such,
the laboratory had insufficient time remaining to perform the preparation within holding time. #
No other analytical or quality issues were noted. #
Page 2 of 4 0
-------
METHOD SUMMARY
Client: ARCADIS U.S., Inc.
£escN£tion_
Lab Location
Method
Job Number: 680-38294-1
_Pre£aration_Metho^^^^^^^_
Matrix Solid
Volatile Organic Compounds by GC/MS	TAL SAV
Toxicity Characteristic Leaching Procedure (ZHE)	TAL SAV
Purge and Trap on Leachates	TAL SAV
Semivolatile Compounds by Gas Chromatography/Mass	TAL SAV
Spectrometry (GC/MS)
Toxicity Characteristic Leaching Procedure	TAL SAV
Continuous Liquid-Liquid Extraction	TAL SAV
Organochlorine Pesticides & Polychlorinated Biphenyls by	TAL SAV
Gas Chromatography
Toxicity Characteristic Leaching Procedure	TAL SAV
Continuous Liquid-Liquid Extraction	TAL SAV
Chlorinated Herbicides by GC	TAL SAV
Toxicity Characteristic Leaching Procedure	TAL SAV
Chlorinated Herbicides by GC - Aqueous Prep	TAL SAV
Inductively Coupled Plasma - Atomic Emission Spectrometry	TAL SAV
Toxicity Characteristic Leaching Procedure	TAL SAV
Acid Digestion of Aqueous Samples and Extracts for	TAL SAV
Mercury in Liquid Waste (Manual Cold Vapor Technique)	TAL SAV
Toxicity Characteristic Leaching Procedure	TAL SAV
Mercury in Liquid Waste (Manual Cold Vapor	TAL SAV
Ignitability of Solids	TAL SAV
Reactive Cyanide Analysis using method 9014	TAL SAV
Cyanide, Reactive (SW7.3.3)	TAL SAV
Titrimetric Procedure for Acid-Soluble and Acid-Insoluble	TAL SAV
Sulfides
Sulfide, Reactive (SW7.3.4)	TAL SAV
Soil and Waste pH	TAL SAV
SW846 8260B
SW846 8270C
SW846 1311
SW846 5030B
SW846 1311
SW846 3520C
SW846 8081A 8082
SW846 8151A
SW846 6010B
SW846 7470A
SW846 1030
SW846 9014
SW846 9034
SW846 9045C
SW846 1311
SW846 3520C
SW846 1311
SW846 8151A
SW846 1311
SW846 301 OA
SW846 1311
SW846 7470A
SW846 7.3.3
SW846 7.3.4
Lab References:
TAL SAV = TestAmerica Savannah
Method References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its
Updates. $
TestAmerica Savannah'
Page 3 of 4 0
-------
SAMPLE SUMMARY'
Client: ARCADIS U.S., Inc.	Job Number: 680-38294-1
Lab Sample ID
Client Sample ID
Client Matrix
Date/Time
Sampled
Date/Time
Received
680-38294-1
680-38294-2
680-38294-3
Wood Ash 6/25	Solid
C/D Ash Sample 6/26/08	Solid
C/D Ash Sample 6/27/08	Solid
06/25/2008 0000
06/26/2008 0000
06/27/2008 0000
07/07/2008 1015
07/07/2008 1015
07/07/2008 1015
TestAmerica Savannah
Page 4 of 4 0
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Client Sample ID:
Lab Sample ID:
Client Matrix:
Wood Ash 6/25)
680-38294-1
Solid
Job Number: 680-38294-1 (
Date Sampled:
Date Received:
06/25/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
8260B
5030B
20
07/16/2008 1616
07/16/2008 1616 (
07/10/2008 1618 (
8260B Volatile Organic Compounds by GC/MS-TCLP )
Analysis Batch: 680-111808
Leachate Batch: 680-111267
Instrument ID: GC/MS Volatiles - O C2 (
Lab File ID:	o3878.d (
Initial Weight/Volume:	5 mL(
Final Weight/Volume:	5 mL(
Analyte
DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Benzene
<0.020
H
0.020 (
Carbon tetrachloride
<0.020
H
0.020 (
Chlorobenzene
<0.020
H
0.020 (
Chloroform
<0.020
H
0.020 (
1,2-Dichloroethane
<0.020
H
0.020 (
1,1-Dichloroethene
<0.020
H
0.020 (
2-Butanone (MEK)
<0.20
H
0.20 (
Tetrachloroethene
<0.020
H
0.020 (
Trichloroethene
<0.020
H
0.020 (
Vinyl chloride
<0.020
H
0.020 (
Surrogate
%Rec

Acceptance Limits (
4-Bromofluorobenzene
107

75-120 (
Dibromofluoromethane
105

75-121 (
Toluene-d8 (Surr)
98

75-120 (
Test America Savannah
Page 5 of 4 0
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/26/08 )
680-38294-2
Solid
Job Number: 680-38294-1 (
Date Sampled:
Date Received:
06/26/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
8260B
5030B
20
07/16/2008 1645
07/16/2008 1645 (
07/10/2008 1618 (
8260B Volatile Organic Compounds by GC/MS-TCLP )
Analysis Batch: 680-111808
Leachate Batch: 680-111267
Instrument ID: GC/MS Volatiles - O C2 (
Lab File ID:	o3880.d (
Initial Weight/Volume:	5 mL(
Final Weight/Volume:	5 mL(
Analyte
DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Benzene
<0.020

0.020 (
Carbon tetrachloride
<0.020

0.020 (
Chlorobenzene
<0.020

0.020 (
Chloroform
<0.020

0.020 (
1,2-Dichloroethane
<0.020

0.020 (
1,1-Dichloroethene
<0.020

0.020 (
2-Butanone (MEK)
<0.20

0.20 (
Tetrachloroethene
<0.020

0.020 (
Trichloroethene
<0.020

0.020 (
Vinyl chloride
<0.020

0.020 (
Surrogate
%Rec

Acceptance Limits (
4-Bromofluorobenzene
110

75- 120(
Dibromofluoromethane
106

75-121 (
Toluene-d8 (Surr)
101

75- 120(
Test America Savannah
Page 6 of 4 0
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/27/08 )
680-38294-3
Solid
Job Number: 680-38294-1 (
Date Sampled:
Date Received:
06/27/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
8260B
5030B
20
07/16/2008 1714
07/16/2008 1714 (
07/10/2008 1618 (
8260B Volatile Organic Compounds by GC/MS-TCLP )
Analysis Batch: 680-111808
Leachate Batch: 680-111267
Instrument ID: GC/MS Volatiles - O C2 (
Lab File ID:	o3882.d (
Initial Weight/Volume:	5 mL(
Final Weight/Volume:	5 mL(
Analyte
DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Benzene
<0.020

0.020 (
Carbon tetrachloride
<0.020

0.020 (
Chlorobenzene
<0.020

0.020 (
Chloroform
<0.020

0.020 (
1,2-Dichloroethane
<0.020

0.020 (
1,1-Dichloroethene
<0.020

0.020 (
2-Butanone (MEK)
<0.20

0.20 (
Tetrachloroethene
<0.020

0.020 (
Trichloroethene
<0.020

0.020 (
Vinyl chloride
<0.020

0.020 (
Surrogate
%Rec

Acceptance Limits (
4-Bromofluorobenzene
108

75- 120(
Dibromofluoromethane
103

75-121 (
Toluene-d8 (Surr)
99

75- 120(
Test America Savannah
Page 7 of 4 0
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Client Sample ID:
Lab Sample ID:
Client Matrix:
Wood Ash 6/25)
680-38294-1
Solid
Job Number: 680-38294-1 (
Date Sampled:
Date Received:
06/25/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS)-TCLP)
8270C	Analysis Batch: 680-111563	Instrument ID: GC/MS SemiVolatiles - G (
3520C
1.0
07/12/2008 2301
07/09/2008 1404
07/07/2008 1400 (
Prep Batch: 680-110963
Leachate Batch: 680-110821
Lab File ID:	g3227.d (
Initial Weight/Volume:	200 mL(
Final Weight/Volume:	1 mL(
Injection Volume:	1.0 uL(
Analyte
DryWt Corrected: N Result (mg/L) Qualifier
RL (
1,4-Dichlorobenzene
<0.050
0.050 (
2,4-Dinitrotoluene
<0.050
0.050 (
Hexachloroethane
<0.050
0.050 (
Hexachlorobenzene
<0.050
0.050 (
Hexachlorobutadiene
<0.050
0.050 (
Methyl Phenols,Total
<0.10
0.10(
Nitrobenzene
<0.050
0.050 (
Pentachlorophenol
<0.25
0.25 (
Pyridine
<0.25
0.25 (
2,4,5-T richlorophenol
<0.050
0.050 (
2,4,6-T richlorophenol
<0.050
0.050 (
Surrogate
%Rec
Acceptance Limits (
2,4,6-T ribromophenol
64
40- 139(
2-Fluorobiphenyl
59
50- 113(
2-Fluorophenol
50
36- 110(
Nitrobenzene-d5
65
45- 112(
Phenol-d5
54
38- 116(
Terphenyl-d14
74
10-121(
Test America Savannah
Page 8 of 4 0
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/26/08 )
680-38294-2
Solid
Job Number: 680-38294-1 (
Date Sampled:
Date Received:
06/26/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS)-TCLP)
8270C	Analysis Batch: 680-111563	Instrument ID: GC/MS SemiVolatiles - G (
3520C
1.0
07/12/2008 2323
07/09/2008 1404
07/07/2008 1400 (
Prep Batch: 680-110963
Leachate Batch: 680-110821
Lab File ID:	g3228.d (
Initial Weight/Volume:	200 mL(
Final Weight/Volume:	1 mL(
Injection Volume:	1.0 uL(
Analyte
DryWt Corrected: N Result (mg/L) Qualifier
RL (
1,4-Dichlorobenzene
<0.050
0.050 (
2,4-Dinitrotoluene
<0.050
0.050 (
Hexachloroethane
<0.050
0.050 (
Hexachlorobenzene
<0.050
0.050 (
Hexachlorobutadiene
<0.050
0.050 (
Methyl Phenols,Total
<0.10
0.10(
Nitrobenzene
<0.050
0.050 (
Pentachlorophenol
<0.25
0.25 (
Pyridine
<0.25
0.25 (
2,4,5-T richlorophenol
<0.050
0.050 (
2,4,6-T richlorophenol
<0.050
0.050 (
Surrogate
%Rec
Acceptance Limits (
2,4,6-T ribromophenol
67
40- 139(
2-Fluorobiphenyl
67
50- 113(
2-Fluorophenol
63
36- 110(
Nitrobenzene-d5
66
45- 112(
Phenol-d5
67
38- 116(
Terphenyl-d14
75
10-121(
Test America Savannah
Page 9 of 4 0
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/27/08 )
680-38294-3
Solid
Job Number: 680-38294-1 (
Date Sampled:
Date Received:
06/27/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
8270C Semivolatile Compounds by Gas Chromatography/Mass Spectrometry (GC/MS)-TCLP)
8270C	Analysis Batch: 680-111563	Instrument ID: GC/MS SemiVolatiles - G (
3520C
1.0
07/12/2008 2345
07/09/2008 1404
07/07/2008 1400 (
Prep Batch: 680-110963
Leachate Batch: 680-110821
Lab File ID:	g3229.d (
Initial Weight/Volume:	200 mL(
Final Weight/Volume:	1 mL(
Injection Volume:	1.0 uL(
Analyte
DryWt Corrected: N Result (mg/L) Qualifier
RL (
1,4-Dichlorobenzene
<0.050
0.050 (
2,4-Dinitrotoluene
<0.050
0.050 (
Hexachloroethane
<0.050
0.050 (
Hexachlorobenzene
<0.050
0.050 (
Hexachlorobutadiene
<0.050
0.050 (
Methyl Phenols,Total
<0.10
0.10(
Nitrobenzene
<0.050
0.050 (
Pentachlorophenol
<0.25
0.25 (
Pyridine
<0.25
0.25 (
2,4,5-T richlorophenol
<0.050
0.050 (
2,4,6-T richlorophenol
<0.050
0.050 (
Surrogate
%Rec
Acceptance Limits (
2,4,6-T ribromophenol
81
40- 139(
2-Fluorobiphenyl
69
50- 113(
2-Fluorophenol
67
36- 110(
Nitrobenzene-d5
73
45- 112(
Phenol-d5
73
38- 116(
Terphenyl-d14
91
10-121(
Test America Savannah
Page 10 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1 (
Client Sample ID:
Lab Sample ID:
Client Matrix:
Wood Ash 6/25)
680-38294-1
Solid
Date Sampled:
Date Received:
06/25/2008 0000 (
07/07/2008 1015 (
8081A_8082 Organochlorine Pesticides & Polychlorinated Biphenyls by Gas Chromatography-TCLP)
8081A_8082	Analysis Batch: 680-111410	Instrument ID: GC SemiVolatiles - M (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
3520C
1.0
07/11/2008 2021
07/08/2008 1342
07/07/2008 1400
Prep Batch: 680-110858
Leachate Batch: 680-110821
Lab File ID:	mg11031.d(
Initial Weight/Volume:	20 mL(
Final Weight/Volume:	10 mL(
Injection Volume:	1.0 uL(
Column ID:	PRIMARY (
Analyte
DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Chlordane (technical)
<0.025

0.025 (
Endrin
<0.0050

0.0050 (
gamma-BHC (Lindane)
<0.0025

0.0025 (
Methoxychlor
<0.025

0.025 (
Heptachlor
<0.0025

0.0025 (
Heptachlor epoxide
<0.0025

0.0025 (
Toxaphene
<0.25

0.25 (
Surrogate
%Rec

Acceptance Limits (
Tetrachloro-m-xylene
56

35- 120(
DCB Decachlorobiphenyl
78

14 - 115 (
TestAmerica Savannah
Page 11 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1 (
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/26/08 )
680-38294-2
Solid
Date Sampled:
Date Received:
06/26/2008 0000 (
07/07/2008 1015 (
8081A_8082 Organochlorine Pesticides & Polychlorinated Biphenyls by Gas Chromatography-TCLP)
8081A_8082	Analysis Batch: 680-111410	Instrument ID: GC SemiVolatiles - M (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
3520C
1.0
07/11/2008 2040
07/08/2008 1342
07/07/2008 1400
Prep Batch: 680-110858
Leachate Batch: 680-110821
Lab File ID:	mg11032.d(
Initial Weight/Volume:	20 mL(
Final Weight/Volume:	10 mL(
Injection Volume:	1.0 uL(
Column ID:	PRIMARY (
Analyte
DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Chlordane (technical)
<0.025

0.025 (
Endrin
<0.0050

0.0050 (
gamma-BHC (Lindane)
<0.0025

0.0025 (
Methoxychlor
<0.025

0.025 (
Heptachlor
<0.0025

0.0025 (
Heptachlor epoxide
<0.0025

0.0025 (
Toxaphene
<0.25

0.25 (
Surrogate
%Rec

Acceptance Limits (
Tetrachloro-m-xylene
62

35- 120(
DCB Decachlorobiphenyl
83

14 - 115 (
TestAmerica Savannah
Page 12 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1 (
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/27/08 )
680-38294-3
Solid
Date Sampled:
Date Received:
06/27/2008 0000 (
07/07/2008 1015 (
8081A_8082 Organochlorine Pesticides & Polychlorinated Biphenyls by Gas Chromatography-TCLP)
8081A_8082	Analysis Batch: 680-111410	Instrument ID: GC SemiVolatiles - M (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
3520C
1.0
07/11/2008 2100
07/08/2008 1342
07/07/2008 1400
Prep Batch: 680-110858
Leachate Batch: 680-110821
Lab File ID:	mg11033.d(
Initial Weight/Volume:	20 mL(
Final Weight/Volume:	10 mL(
Injection Volume:	1.0 uL(
Column ID:	PRIMARY (
Analyte
DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Chlordane (technical)
<0.025

0.025 (
Endrin
<0.0050

0.0050 (
gamma-BHC (Lindane)
<0.0025

0.0025 (
Methoxychlor
<0.025

0.025 (
Heptachlor
<0.0025

0.0025 (
Heptachlor epoxide
<0.0025

0.0025 (
Toxaphene
<0.25

0.25 (
Surrogate
%Rec

Acceptance Limits (
Tetrachloro-m-xylene
54

35- 120(
DCB Decachlorobiphenyl
81

14 - 115 (
TestAmerica Savannah
Page 13 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1 (
Client Sample ID:
Lab Sample ID:
Client Matrix:
Wood Ash 6/25)
680-38294-1
Solid
Date Sampled:
Date Received:
06/25/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Analyte
8151A
8151A
1.0
07/11/2008 0144
07/08/2008 0822
07/07/2008 1400
8151A Chlorinated Herbicides by GC-TCLP )
Analysis Batch: 680-111302
Prep Batch: 680-110848
Leachate Batch: 680-110821
DryWt Corrected: N Result (mg/L)
Instrument ID: GC SemiVolatiles - S (
Lab File ID:	sf10045.d(
Initial Weight/Volume:	10 mL(
Final Weight/Volume:	10 mL(
Injection Volume:	1 uL(
Column ID:	PRIMARY (
Qualifier	RL (
2,4-D
Silvex (2,4,5-TP)
Surrogate
DCAA
<0.050
<0.050
%Rec
101
0.050 (
0.050 (
Acceptance Limits (
61 -120(
TestAmerica Savannah
Page 14 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1 (
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/26/08 )
680-38294-2
Solid
Date Sampled:
Date Received:
06/26/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Analyte
8151A
8151A
1.0
07/11/2008 0202
07/08/2008 0822
07/07/2008 1400
8151A Chlorinated Herbicides by GC-TCLP )
Analysis Batch: 680-111302
Prep Batch: 680-110848
Leachate Batch: 680-110821
DryWt Corrected: N Result (mg/L)
Instrument ID: GC SemiVolatiles - S (
Lab File ID:	sf10046.d(
Initial Weight/Volume:	10 mL(
Final Weight/Volume:	10 mL(
Injection Volume:	1 uL(
Column ID:	PRIMARY (
Qualifier	RL (
2,4-D
Silvex (2,4,5-TP)
Surrogate
DCAA
<0.050
<0.050
%Rec
83
0.050 (
0.050 (
Acceptance Limits (
61 -120(
TestAmerica Savannah	Page 15 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1 (
Client Sample ID:
Lab Sample ID:
Client Matrix:
C/D Ash Sample 6/27/08 )
680-38294-3
Solid
Date Sampled:
Date Received:
06/27/2008 0000 (
07/07/2008 1015 (
Method:
Preparation:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Analyte
8151A
8151A
1.0
07/11/2008 0221
07/08/2008 0822
07/07/2008 1400
8151A Chlorinated Herbicides by GC-TCLP )
Analysis Batch: 680-111302
Prep Batch: 680-110848
Leachate Batch: 680-110821
DryWt Corrected: N Result (mg/L)
Instrument ID: GC SemiVolatiles - S (
Lab File ID:	sf10047.d(
Initial Weight/Volume:	10 mL(
Final Weight/Volume:	10 mL(
Injection Volume:	1 uL(
Column ID:	PRIMARY (
Qualifier	RL (
2,4-D
Silvex (2,4,5-TP)
Surrogate
DCAA
<0.050
<0.050
%Rec
93
0.050 (
0.050 (
Acceptance Limits (
61 -120(
TestAmerica Savannah	Page 16 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.	Job Number: 680-38294-1 (
Client Sample ID:
Wood Ash 6/25)


Lab Sample ID:
680-38294-1
Date Sampled:
06/25/2008 0000 (
Client Matrix:
Solid

Date Received:
07/07/2008 1015 (


6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-TCLP)

Method:
601 OB
Analysis Batch: 680-111168
Instrument ID:
ICP/AES - D (
Preparation:
301 OA
Prep Batch: 680-110926
Lab File ID:
N/A (
Dilution:
1.0
Leachate Batch: 680-110821
Initial Weight/Volume:
5 mL (
Date Analyzed:
07/09/2008
2013
Final Weight/Volume:
50 mL (
Date Prepared:
07/08/2008
1634 (


Date Leached:
07/07/2008
1400 (


Analyte

DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Arsenic

0.22

0.20 (
Barium

<1.0

1.0(
Cadmium

<0.10

0.10(
Chromium

<0.20

0.20 (
Lead

<0.20

0.20 (
Selenium

<0.50

0.50 (
Silver

<0.10

0.10 f


7470A Mercury in Liquid Waste (Manual Cold Vapor Technique)-TCLP )

Method:
7470A
Analysis Batch: 680-111492
Instrument ID:
LEEMAN1(
Preparation:
7470A
Prep Batch: 680-111299
Lab File ID:
N/A (
Dilution:
1.0
Leachate Batch: 680-110821
Initial Weight/Volume:
0.50 mL(
Date Analyzed:
07/14/2008
1430
Final Weight/Volume:
50 mL (
Date Prepared:
07/11/2008
1333 (


Date Leached:
07/07/2008
1400 (


Analyte

DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Mercury

<0.020

0.020 (
TestAmerica Savannah	Page 17 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.	Job Number: 680-38294-1 (
Client Sample ID:
C/D Ash Sample 6/26/08 )


Lab Sample ID:
680-38294-2
Date Sampled:
06/26/2008 0000 (
Client Matrix:
Solid

Date Received:
07/07/2008 1015 (


6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-TCLP)

Method:
601 OB
Analysis Batch: 680-111168
Instrument ID:
ICP/AES - D (
Preparation:
301 OA
Prep Batch: 680-110926
Lab File ID:
N/A (
Dilution:
1.0
Leachate Batch: 680-110821
Initial Weight/Volume:
5 mL (
Date Analyzed:
07/09/2008
2018
Final Weight/Volume:
50 mL (
Date Prepared:
07/08/2008
1634 (


Date Leached:
07/07/2008
1400 (


Analyte

DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Arsenic

<0.20

0.20 (
Barium

<1.0

1.0(
Cadmium

<0.10

0.10(
Chromium

<0.20

0.20 (
Lead

<0.20

0.20 (
Selenium

<0.50

0.50 (
Silver

<0.10

0.10 f


7470A Mercury in Liquid Waste (Manual Cold Vapor Technique)-TCLP )

Method:
7470A
Analysis Batch: 680-111492
Instrument ID:
LEEMAN1(
Preparation:
7470A
Prep Batch: 680-111299
Lab File ID:
N/A (
Dilution:
1.0
Leachate Batch: 680-110821
Initial Weight/Volume:
0.50 mL(
Date Analyzed:
07/14/2008
1432
Final Weight/Volume:
50 mL (
Date Prepared:
07/11/2008
1333 (


Date Leached:
07/07/2008
1400 (


Analyte

DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Mercury

<0.020

0.020 (
TestAmerica Savannah	Page 18 of 40
-------
Analytical Data)
Client: ARCADIS U.S., Inc.	Job Number: 680-38294-1 (
Client Sample ID:
C/D Ash Sample 6/27/08 )


Lab Sample ID:
680-38294-3
Date Sampled:
06/27/2008 0000 (
Client Matrix:
Solid

Date Received:
07/07/2008 1015 (


6010B Inductively Coupled Plasma - Atomic Emission Spectrometry-TCLP)

Method:
601 OB
Analysis Batch: 680-111168
Instrument ID:
ICP/AES - D (
Preparation:
301 OA
Prep Batch: 680-110926
Lab File ID:
N/A (
Dilution:
1.0
Leachate Batch: 680-110821
Initial Weight/Volume:
5 mL (
Date Analyzed:
07/09/2008
2023
Final Weight/Volume:
50 mL (
Date Prepared:
07/08/2008
1634 (


Date Leached:
07/07/2008
1400 (


Analyte

DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Arsenic

0.30

0.20 (
Barium

<1.0

1.0(
Cadmium

<0.10

0.10(
Chromium

<0.20

0.20 (
Lead

<0.20

0.20 (
Selenium

<0.50

0.50 (
Silver

<0.10

0.10 f


7470A Mercury in Liquid Waste (Manual Cold Vapor Technique)-TCLP )

Method:
7470A
Analysis Batch: 680-111492
Instrument ID:
LEEMAN1(
Preparation:
7470A
Prep Batch: 680-111299
Lab File ID:
N/A (
Dilution:
1.0
Leachate Batch: 680-110821
Initial Weight/Volume:
0.50 mL(
Date Analyzed:
07/14/2008
1435
Final Weight/Volume:
50 mL (
Date Prepared:
07/11/2008
1333 (


Date Leached:
07/07/2008
1400 (


Analyte

DryWt Corrected: N Result (mg/L)
Qualifier
RL (
Mercury

<0.020

0.020 (
TestAmerica Savannah	Page 19 of 40
-------
Client: ARCADIS U.S., Inc.
Analytical Data)
Job Number: 680-38294-1 (


General Chemistry)



Client Sample ID:
Wood Ash 6/25)





Lab Sample ID:
680-38294-1



Date Sampled:
06/25/2008 0000 (
Client Matrix:
Solid



Date Received:
07/07/2008 1015 (
Analyte
Result
Qual Units



Dil Method (
Ignitability
NB
mm/sec



1.0 1030 (

Anly Batch: 680-111879
Date Analyzed
07/17/2008
1830

DryWt Corrected: N (
pH
10.1
H SU



1.0 9045C (

Anly Batch: 680-111347
Date Analyzed
07/11/2008
1136

DryWt Corrected: N (
Analyte
Result
Qual Units


RL
Dil Method (
Cyanide, Reactive (
<100
mg/Kg


100
1.0 9014 (

Anly Batch: 680-111045
Date Analyzed
07/08/2008
1321

DryWt Corrected: N (

Prep Batch: 680-111044
Date Prepared:
07/08/2008
0700 (


Sulfide, Reactive (
<50
mg/Kg


50
1.0 9034 (

Anly Batch: 680-111047
Date Analyzed
07/09/2008
1329

DryWt Corrected: N (

Prep Batch: 680-111046
Date Prepared:
07/08/2008
0700 (


Client Sample ID:)
C/D Ash Sample 6/26/08 )





Lab Sample ID: (
680-38294-2



Date Sampled:
06/26/2008 0000 (
Client Matrix: (
Solid



Date Received:
07/07/2008 1015 (
Analyte (
Result
Qual Units



Dil Method (
Ignitability
NB
mm/sec



1.0 1030

Anly Batch: 680-111879
Date Analyzed
07/17/2008
1830

DryWt Corrected: N
pH
12.2
H SU



1.0 9045C

Anly Batch: 680-111347
Date Analyzed
07/11/2008
1136

DryWt Corrected: N
Analyte
Result
Qual Units


RL
Dil Method
Cyanide, Reactive
<100
mg/Kg


100
1.0 9014

Anly Batch: 680-111045
Date Analyzed
07/08/2008
1321

DryWt Corrected: N

Prep Batch: 680-111044
Date Prepared:
07/08/2008
0700


Sulfide, Reactive
<50
mg/Kg


50
1.0 9034

Anly Batch: 680-111047
Date Analyzed
07/09/2008
1329

DryWt Corrected: N

Prep Batch: 680-111046
Date Prepared:
07/08/2008
0700


Test America Savannah
Page 2 0 of 4 0
-------
Client: ARCADIS U.S., Inc.
Analytical Data
Job Number: 680-38294-1


General Chemistry



Client Sample ID:
C/D Ash Sample 6/27/08





Lab Sample ID:
680-38294-3



Date Sampled:
06/27/2008 0000
Client Matrix:
Solid



Date Received:
07/07/2008 1015
Analyte
Result
Qual Units



Dil Method
Ignitability
NB
mm/sec



1.0 1030

Anly Batch: 680-111879
Date Analyzed
07/17/2008
1830

DryWt Corrected: N
pH
12.5
H SU



1.0 9045C

Anly Batch: 680-111347
Date Analyzed
07/11/2008
1136

DryWt Corrected: N
Analyte
Result
Qual Units


RL
Dil Method
Cyanide, Reactive
<100
mg/Kg


100
1.0 9014

Anly Batch: 680-111045
Date Analyzed
07/08/2008
1321

DryWt Corrected: N

Prep Batch: 680-111044
Date Prepared:
07/08/2008
0700


Sulfide, Reactive
<50
mg/Kg


50
1.0 9034

Anly Batch: 680-111047
Date Analyzed
07/09/2008
1329

DryWt Corrected: N

Prep Batch: 680-111046
Date Prepared:
07/08/2008
0700


TestAmerica Savannah	Page 21 of 4 0
-------
DATA REPORTING QUALIFIERS $
Client: ARCADIS U.S., Inc.	Job Number: 680-38294-1
Lab Section
Qualifier
Description
GC/MS VOA
Sample was prepped or analyzed beyond the specified
holding time
General Chemistry
Sample was prepped or analyzed beyond the specified
holding time
TestAmerica Savannah $
Page 22 of 40
-------
Quality Control Results (
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Method Blank-Batch: 680-111734
Method: 8260B
Preparation: 5030B
Lab Sample ID: MB 680-111734/9
Client Matrix:	Water
Dilution:	1.0
Date Analyzed:	07/16/2008 1504
Date Prepared:	07/16/2008 1504
Analysis Batch: 680-111734
Prep Batch: N/A
Units: mg/L
Instrument ID: GC/MS Volatiles ¦
Lab File ID: oq861.d
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
RL
Benzene
<0.0010

0.0010
Carbon tetrachloride
<0.0010

0.0010
Chlorobenzene
<0.0010

0.0010
Chloroform
<0.0010

0.0010
1,2-Dichloroethane
<0.0010

0.0010
1,1-Dichloroethene
<0.0010

0.0010
2-Butanone (MEK)
<0.010

0.010
Tetrachloroethene
<0.0010

0.0010
Trichloroethene
<0.0010

0.0010
Vinyl chloride
<0.0010

0.0010
Surrogate
% Rec
Acceptance Limits

4-Bromofluorobenzene
109
75- 120$

Dibromofluoromethane
116
75-121 $

Toluene-d8 (Surr)
98
75- 120$

Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 23 of 40
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
TCLP SPLPE Leachate Blank - Batch: 680-111734
Method: 8260B
Preparation: 5030B
Lab Sample ID: LB 680-111734/1
Client Matrix: Water
Dilution:
20
Date Analyzed: 07/16/2008 1533
Date Prepared: 07/16/2008 1533
Analysis Batch: 680-111734
Prep Batch: N/A
Units: mg/L
Instrument ID: GC/MS Volatiles ¦
Lab File ID: o3875.d
Initial Weight/Volume: 5 mL
Final Weight/Volume: 5 mL
Analyte
Result
Qual
RL
Benzene
<0.020

0.020
Carbon tetrachloride
<0.020

0.020
Chlorobenzene
<0.020

0.020
Chloroform
<0.020

0.020
1,2-Dichloroethane
<0.020

0.020
1,1-Dichloroethene
<0.020

0.020
2-Butanone (MEK)
<0.20

0.20
Tetrachloroethene
<0.020

0.020
Trichloroethene
<0.020

0.020
Vinyl chloride
<0.020

0.020
Surrogate
% Rec
Acceptance Limits

4-Bromofluorobenzene
109
75- 120$

Dibromofluoromethane
111
75-121 $

Toluene-d8 (Surr)
98
75- 120$

Calculations are performed before rounding to avoid round-off errors in
TestAmerica Savannah	Page
calculated results. $
24 of 40
-------
Quality Control Results (
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-111734
Method: 8260B (
Preparation: 5030B (
LCS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 680-111734/7
Water
1.0
07/16/2008 1302
07/16/2008 1302$
Analysis Batch: 680-111734
Prep Batch: N/A
Units: mg/L
Instrument ID: GC/MS Volatiles - O $
Lab File ID: oq853.d $
Initial Weight/Volume: 5 mL$
Final Weight/Volume: 5 mL$
LCSD Lab Sample ID: LCSD 680-111734/8
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
07/16/2008 1331
07/16/2008 1331 $
Analysis Batch: 680-111734
Prep Batch: N/A
Units: mg/L
Instrument ID: GC/MS Volatiles ¦
Lab File ID: oq855.d $
Initial Weight/Volume: 5 mL$
Final Weight/Volume: 5 mL$
% Rec. $
Analyte
LCS

LCSD
Limit
RPD
RPD Limit LCS Qual LCSD Qual $
Benzene
99

99
77-119
1
30$
Carbon tetrachloride
93

90
71 - 135
3
30$
Chlorobenzene
101

104
85-116
2
30$
Chloroform
108

106
82-120
1
30$
1,2-Dichloroethane
76

76
66-132
0
30$
1,1-Dichloroethene
110

109
62-141
1
30$
2-Butanone (MEK)
104

105
33-157
2
30$
Tetrachloroethene
107

108
76-126
1
30$
Trichloroethene
95

95
84-115
1
30$
Vinyl chloride
101

101
59-144
0
50$
Surrogate

LCS % Rec
LCSD % Rec
Acceptance Limits $
4-Bromofluorobenzene

103

104

75- 120$
Dibromofluoromethane

109

113

75-121 $
Toluene-d8 (Surr)

99

99

75- 120$
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 25 of 40
-------



Quality Control Results
Client: ARCADIS U.S., Inc.


Job Number: 680-38294-1
Method Blank-Batch: 680-111808


Method: 8260B



Preparation: 5030B
Lab Sample ID: MB 680-111808/5
Analysis Batch: 680-111808

Instrument ID: GC/MS Volatiles - O C2
Client Matrix: Water
Prep Batch: N/A

Lab File ID: oq862.d
Dilution: 1.0
Units: mg/L

Initial Weight/Volume: 5 mL
Date Analyzed: 07/16/2008 1518


Final Weight/Volume: 5 mL
Date Prepared: 07/16/2008 1518



Analyte
Result
Qual
RL
Benzene
<0.0010

0.0010
Carbon tetrachloride
<0.0010

0.0010
Chlorobenzene
<0.0010

0.0010
Chloroform
<0.0010

0.0010
1,2-Dichloroethane
<0.0010

0.0010
1,1-Dichloroethene
<0.0010

0.0010
2-Butanone (MEK)
<0.010

0.010
Tetrachloroethene
<0.0010

0.0010
Trichloroethene
<0.0010

0.0010
Vinyl chloride
<0.0010

0.0010
Surrogate
% Rec

Acceptance Limits
4-Bromofluorobenzene
104

75- 120$
Dibromofluoromethane
114

75-121 $
Toluene-d8 (Surr)
98

75- 120$
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 2 6 of 4 0
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Quality Control Results (
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Lab Control Spike/
Lab Control Spike Duplicate Recovery Report - Batch: 680-111808
Method: 8260B (
Preparation: 5030B (
LCS Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 680-111808/6
Water
1.0
07/16/2008 1317
07/16/2008 1317$
Analysis Batch: 680-111808
Prep Batch: N/A
Units: mg/L
Instrument ID: GC/MS Volatiles - O C2 $
Lab File ID: oq854.d $
Initial Weight/Volume: 5 mL$
Final Weight/Volume: 5 mL$
LCSD Lab Sample ID: LCSD 680-111808/7
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
07/16/2008 1346
07/16/2008 1346$
Analysis Batch: 680-111808
Prep Batch: N/A
Units: mg/L
Instrument ID: GC/MS Volatiles - O C2 $
Lab File ID: oq856.d $
Initial Weight/Volume: 5 mL$
Final Weight/Volume: 5 mL$
% Rec. $
Analyte
LCS

LCSD
Limit
RPD
RPD Limit LCS Qual LCSD Qual $
Benzene
103

100
77-119
3
30$
Carbon tetrachloride
105

100
71 - 135
5
30$
Chlorobenzene
99

102
85-116
3
30$
Chloroform
103

101
82-120
2
30$
1,2-Dichloroethane
82

76
66-132
7
30$
1,1-Dichloroethene
102

102
62-141
0
30$
2-Butanone (MEK)
106

101
33-157
5
30$
Tetrachloroethene
103

108
76-126
4
30$
Trichloroethene
98

97
84-115
1
30$
Vinyl chloride
95

95
59-144
0
50$
Surrogate

LCS % Rec
LCSD % Rec
Acceptance Limits $
4-Bromofluorobenzene
Dibromofluoromethane
Toluene-d8 (Surr)

104
105
101

105
107
99

75- 120$
75-121 $
75- 120$
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 27 of 40
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Method Blank-Batch: 680-110963
Method: 8270C
Preparation: 3520C
Lab Sample ID:	MB 680-110963/14-A
Client Matrix:	Water
Dilution:	1.0
Date Analyzed:	07/12/2008 1729
Date Prepared:	07/09/2008 1404
Analysis Batch: 680-111563
Prep Batch: 680-110963
Units: mg/L
Instrument ID: GC/MS SemiVolatiles -
Lab File ID: g3212.d
Initial Weight/Volume: 1000 mL
Final Weight/Volume: 1 mL
Injection Volume:	1.0 uL
Analyte	Result	Qual	RL
1,4-Dichlorobenzene
<0.010

0.010
2,4-Dinitrotoluene
<0.010

0.010
Hexachloroethane
<0.010

0.010
Hexachlorobenzene
<0.010

0.010
Hexachlorobutadiene
<0.010

0.010
Methyl Phenols,Total
<0.020

0.020
Nitrobenzene
<0.010

0.010
Pentachlorophenol
<0.050

0.050
Pyridine
<0.050

0.050
2,4,5-T richlorophenol
<0.010

0.010
2,4,6-T richlorophenol
<0.010

0.010
Surrogate
% Rec
Acceptance Limits

2,4,6-T ribromophenol
58
40-139

2-Fluorobiphenyl
65
50-113

2-Fluorophenol
60
36-110

Nitrobenzene-d5
61
45-112

Phenol-d5
62
38-116

Terphenyl-d14
67
10-121

Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 2 8 of 4 0
-------
Quality Control Results (
Client: ARCADIS U.S., Inc.	Job Number: 680-38294-1 $
TCLP SPLPE Leachate Blank - Batch: 680-110963	Method: 8270C
Preparation: 3520C




TCLP

Lab Sample ID: LB 680-110821/16-E
Analysis Batch: 680-111563

Instrument ID: GC/MS SemiVolatiles - G
Client Matrix: Solid

Prep Batch: 680-110963

Lab File ID: g3214.d

Dilution: 1.0

Units: mg/L

Initial Weight/Volume:
200 mL
Date Analyzed: 07/12/2008
1813


Final Weight/Volume:
1 mL
Date Prepared: 07/09/2008
1404


Injection Volume:
1.0 uL
Date Leached: 07/07/2008
1400
Leachate Batch: 680-110821



Analyte

Result
Qual

RL
1,4-Dichlorobenzene

<0.050


0.050
2,4-Dinitrotoluene

<0.050


0.050
Hexachloroethane

<0.050


0.050
Hexachlorobenzene

<0.050


0.050
Hexachlorobutadiene

<0.050


0.050
Methyl Phenols,Total

<0.10


0.10
Nitrobenzene

<0.050


0.050
Pentachlorophenol

<0.25


0.25
Pyridine

<0.25


0.25
2,4,5-T richlorophenol

<0.050


0.050
2,4,6-T richlorophenol

<0.050


0.050
Surrogate

% Rec

Acceptance Limits

2,4,6-T ribromophenol

63

40-139

2-Fluorobiphenyl

66

50-113

2-Fluorophenol

62

36-110

Nitrobenzene-d5

65

45-112

Phenol-d5

62

38-116

Terphenyl-d14

73

10-121

Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 2 9 of 4 0
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Lab Control Spike - Batch: 680-110963
Method: 8270C
Preparation: 3520C
Lab Sample ID:	LCS 680-110963/15-A
Client Matrix:	Water
Dilution:	1.0
Date Analyzed:	07/12/2008 1751
Date Prepared:	07/09/2008 1404
Analysis Batch: 680-111563
Prep Batch: 680-110963
Units: mg/L
Instrument ID: GC/MS SemiVolatiles -
Lab File ID: g3213.d
Initial Weight/Volume: 1000 mL
Final Weight/Volume: 1 mL
Injection Volume:	1.0 uL
Analyte
Spike Amount

Result
% Rec.
Limit
Qual
1,4-Dichlorobenzene
0.100

0.0569
57
38-110

2,4-Dinitrotoluene
0.100

0.0730
73
49-128

Hexachloroethane
0.100

0.0607
61
33-110

Hexachlorobenzene
0.100

0.0687
69
48-119

Hexachlorobutadiene
0.100

0.0629
63
40-110

Nitrobenzene
0.100

0.0626
63
46-110

Pentachlorophenol
0.100

0.0617
62
37-132

Pyridine
0.100

<0.050
43
10-110

2,4,5-T richlorophenol
0.100

0.0744
74
47-122

2,4,6-T richlorophenol
0.100

0.0716
72
46-120

Surrogate
% Rec

Acceptance Limits

2,4,6-T ribromophenol

69


40-139

2-Fluorobiphenyl

69


50-113

2-Fluorophenol

56


36-110

Nitrobenzene-d5

65


45-112

Phenol-d5

64


38-116

Terphenyl-d14

68


10-121

Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 30 of 4 0
-------
Quality Control Results (
Client: ARCADIS U.S., Inc.


Job Number: 680-38294-1
TCLP SPLPE Leachate Blank - Batch:
680-110858

Method: 8081A_8082



Preparation: 3520C



TCLP
Lab Sample ID: LB 680-110821/16-D
Analysis Batch: 680-111410

Instrument ID: GC SemiVolatiles - M
Client Matrix: Solid
Prep Batch: 680-110858

Lab File ID: mg11022.d
Dilution: 1.0
Units: mg/L

Initial Weight/Volume: 20 mL
Date Analyzed: 07/11/2008 1726


Final Weight/Volume: 10 mL
Date Prepared: 07/08/2008 1342


Injection Volume: 1.0 uL
Date Leached: 07/07/2008 1400
Leachate Batch: 680-110821

Column ID: PRIMARY
Analyte
Result
Qual
RL
Chlordane (technical)
<0.025

0.025
Endrin
<0.0050

0.0050
gamma-BHC (Lindane)
<0.0025

0.0025
Methoxychlor
<0.025

0.025
Heptachlor
<0.0025

0.0025
Heptachlor epoxide
<0.0025

0.0025
Toxaphene
<0.25

0.25
Surrogate
% Rec

Acceptance Limits
Tetrachloro-m-xylene
63

35-120
DCB Decachlorobiphenyl
78

14-115
Method Blank-Batch: 680-110858


Method: 8081A_8082



Preparation: 3520C
Lab Sample ID: MB 680-110858/18-A
Analysis Batch: 680-111410

Instrument ID: GC SemiVolatiles - M
Client Matrix: Water
Prep Batch: 680-110858

Lab File ID: mg11023.d
Dilution: 1.0
Units: mg/L

Initial Weight/Volume: 1000 mL
Date Analyzed: 07/11/2008 1746


Final Weight/Volume: 10 mL
Date Prepared: 07/08/2008 1342


Injection Volume: 1.0 uL



Column ID: PRIMARY
Analyte
Result
Qual
RL
Chlordane (technical)
<0.00050

0.00050
Endrin
<0.00010

0.00010
gamma-BHC (Lindane)
<0.000050

0.000050
Methoxychlor
<0.00050

0.00050
Heptachlor
<0.000050

0.000050
Heptachlor epoxide
<0.000050

0.000050
Toxaphene
<0.0050

0.0050
Surrogate
% Rec

Acceptance Limits
Tetrachloro-m-xylene
55

35-120
DCB Decachlorobiphenyl
66

14-115
Calculations are performed before rounding to avoid round-off errors in calculated results.
TestAmerica Savannah	Page 31 of 4 0
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Lab Control Spike - Batch: 680-110858
Method: 8081A_8082
Preparation: 3520C
Lab Sample ID:
Client Matrix:
Dilution:
LCS 680-110858/19-A
Water
1.0
Date Analyzed: 07/11/2008 1805
Date Prepared: 07/08/2008 1342
Analysis Batch: 680-111410
Prep Batch: 680-110858
Units: mg/L
Instrument ID: GC SemiVolatiles - M
Lab File ID: mg11024.d
Initial Weight/Volume: 1000 mL
Final Weight/Volume: 10 mL
Injection Volume:	1.0 uL
Column ID:	PRIMARY
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
Endrin
0.000203
0.000177
87

38-144
gamma-BHC (Lindane)
0.000100
0.0000818
82

31 - 118
Methoxychlor
0.000201
<0.00050
78

10-243
Heptachlor
0.000100
0.0000824
82

30-133
Heptachlor epoxide
0.000100
0.0000791
79

34-126
Surrogate

% Rec

Acceptance Limits
T etrachloro-m-xylene

68

35-
120
DCB Decachlorobiphenyl

41

14-
115
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 32 of 40
-------
Quality Control Results (
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
TCLP SPLPE Leachate Blank - Batch: 680-110848
Lab Sample ID: LB 680-110821/16-B
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Solid
1.0
07/10/2008 2334
07/08/2008 0822
07/07/2008 1400
Analysis Batch: 680-111302
Prep Batch: 680-110848
Units: mg/L
Leachate Batch: 680-110821
Method: 8151A
Preparation: 8151A
TCLP
Instrument ID: GC SemiVolatiles -
Lab File ID: sf10038.d
Initial Weight/Volume: 10 mL
Final Weight/Volume: 10 mL
Injection Volume:	1 uL
Column ID:	PRIMARY
Analyte
2,4-D
Silvex (2,4,5-TP)
Surrogate
Result
<0.050
<0.050
% Rec
Qual
DCAA
106
Acceptance Limits
61 -120
RL
0.050
0.050
Method Blank-Batch: 680-110848
Method: 8151A
Preparation: 8151A
Lab Sample ID: MB 680-110848/15-A
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Water
1.0
07/10/2008 2352
07/08/2008 0822
Analysis Batch: 680-111302
Prep Batch: 680-110848
Units: mg/L
Instrument ID: GC SemiVolatiles - S
Lab File ID: sf10039.d
Initial Weight/Volume: 1000 mL
Final Weight/Volume: 10 mL
Injection Volume:	1 uL
Column ID:	PRIMARY
Analyte
Result
Qual
RL
2,4-D
Silvex (2,4,5-TP)
Surrogate
DCAA
<0.00050
<0.00050
% Rec
104
0.00050
0.00050
Acceptance Limits
61 -120
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 33 of 40
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Lab Control Spike - Batch: 680-110848
Method: 8151A
Preparation: 8151A
Lab Sample ID:
Client Matrix:
Dilution:
LCS 680-110848/16-A
Water
1.0
Date Analyzed: 07/11/2008 0011
Date Prepared: 07/08/2008 0822
Analysis Batch: 680-111302
Prep Batch: 680-110848
Units: mg/L
Instrument ID: GC SemiVolatiles -
Lab File ID: sf10040.d
Initial Weight/Volume: 1000 mL
Final Weight/Volume: 10 mL
Injection Volume:	1 uL
Column ID:	PRIMARY
Analyte
2,4-D
Silvex (2,4,5-TP)
Surrogate
DCAA
Spike Amount
0.00200
0.00200
Result
0.00226
0.00175
% Rec
108
% Rec.	Limit
113	61-127
87	55-110
Acceptance Limits
61 -120
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 34 of 4 0
-------
Quality Control Results
Client: ARCADIS U.S., Inc.	Job Number: 680-38294-1
TCLP SPLPE Leachate Blank - Batch: 680-110926
Lab Sample ID: LB 680-110821/16-C
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Solid
1.0
07/09/2008 1857
07/08/2008 1634
07/07/2008 1400
Analysis Batch: 680-111168
Prep Batch: 680-110926
Units: mg/L
Leachate Batch: 680-110821
Method: 6010B
Preparation: 301 OA
TCLP
Instrument ID: ICP/AES - D
Lab File ID: N/A
Initial Weight/Volume: 5 mL
Final Weight/Volume: 50 mL
Analyte
Result Qual
RL
Arsenic
<0.20
0.20
Barium
<1.0
1.0
Cadmium
<0.10
0.10
Chromium
<0.20
0.20
Lead
<0.20
0.20
Selenium
<0.50
0.50
Silver
<0.10
0.10
Lab Control Spike - Batch: 680-110926
Method: 6010B
Preparation: 301 OA
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 680-110926/15-A
Water
1.0
07/09/2008 1902
07/08/2008 1634
Analysis Batch: 680-111168
Prep Batch: 680-110926
Units: mg/L
Instrument ID: ICP/AES - D
Lab File ID: N/A
Initial Weight/Volume: 5 mL
Final Weight/Volume: 50 mL
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
Arsenic
20.0
19.7
98
75- 125$

Barium
20.0
21.7
108
75- 125$

Cadmium
0.500
0.511
102
75- 125$

Chromium
2.00
2.00
100
75- 125$

Lead
5.00
5.03
101
75- 125$

Selenium
20.0
20.4
102
75- 125$

Silver
0.500
0.512
102
75- 125$

Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 35 of 40
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
TCLP SPLPE Leachate Blank - Batch: 680-111299
Lab Sample ID: LB 680-110821/16-G
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
Date Leached:
Solid
1.0
07/14/2008 1424
07/11/2008 1333
07/07/2008 1400
Analysis Batch: 680-111492
Prep Batch: 680-111299
Units: mg/L
Leachate Batch: 680-110821
Method: 7470A
Preparation: 7470A
TCLP
Instrument ID: LEEMAN1
Lab File ID: N/A
Initial Weight/Volume: 0.50 mL
Final Weight/Volume: 50 mL
Analyte
Mercury
Result
<0.020
Qual
RL
0.020
Lab Control Spike - Batch: 680-111299
Method: 7470A
Preparation: 7470A
Lab Sample ID:
Client Matrix:
Dilution:
Date Analyzed:
Date Prepared:
LCS 680-111299/5-A
Water
1.0
07/14/2008 1427
07/11/2008 1333
Analysis Batch: 680-111492
Prep Batch: 680-111299
Units: mg/L
Instrument ID: LEEMAN1
Lab File ID: N/A
Initial Weight/Volume: 0.50 mL
Final Weight/Volume: 50 mL
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
Mercury
0.250
0.269
108
80-120
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 36 of 4 0
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Method Blank-Batch: 680-111044
Method: 9014
Preparation: 7.3.3
Lab Sample ID:	MB 680-111044/1-A
Client Matrix:	Solid
Dilution:	1.0
Date Analyzed:	07/08/2008 1321
Date Prepared:	07/08/2008 0700
Analysis Batch: 680-111045
Prep Batch: 680-111044
Units: mg/Kg
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial Weight/Volume: 10.00 g
Final Weight/Volume: 250 mL
Analyte
Cyanide, Reactive
Result
<100
Qual
RL
100
Lab Control Spike - Batch: 680-111044
Method: 9014
Preparation: 7.3.3
Lab Sample ID:	LCS 680-111044/2-A
Client Matrix:	Solid
Dilution:	1.0
Date Analyzed:	07/08/2008 1321
Date Prepared:	07/08/2008 0700
Analysis Batch: 680-111045
Prep Batch: 680-111044
Units: mg/Kg
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial Weight/Volume: 10.00 g
Final Weight/Volume: 250 mL
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
Cyanide, Reactive
238
<100
18
10-120
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 37 of 40
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Method Blank-Batch: 680-111046
Method: 9034
Preparation: 7.3.4
Lab Sample ID:	MB 680-111046/1-A
Client Matrix:	Solid
Dilution:	1.0
Date Analyzed:	07/09/2008 1329
Date Prepared:	07/08/2008 0700
Analysis Batch: 680-111047
Prep Batch: 680-111046
Units: mg/Kg
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial Weight/Volume: 10.00 g
Final Weight/Volume: 250 mL
Analyte
Sulfide, Reactive
Result
<50
Qual
RL
50
Lab Control Spike - Batch: 680-111046
Method: 9034
Preparation: 7.3.4
Lab Sample ID:	LCS 680-111046/2-A
Client Matrix:	Solid
Dilution:	1.0
Date Analyzed:	07/09/2008 1329
Date Prepared:	07/08/2008 0700
Analysis Batch: 680-111047
Prep Batch: 680-111046
Units: mg/Kg
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial Weight/Volume: 10.00 g
Final Weight/Volume: 250 mL
Analyte
Spike Amount
Result
% Rec.
Limit
Qual
Sulfide, Reactive
2450
1760
72
40-120
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 38 of 4 0
-------
Quality Control Results
Client: ARCADIS U.S., Inc.
Job Number: 680-38294-1
Lab Control Spike - Batch: 680-111347
Method: 9045C
Preparation: N/A
Lab Sample ID:	LCS 680-111347/1
Client Matrix:	Solid
Dilution:	1.0
Date Analyzed:	07/11/2008 1136
Date Prepared:	N/A
Analysis Batch: 680-111347
Prep Batch: N/A
Units: SU
Instrument ID: No Equipment Assigned
Lab File ID: N/A
Initial Weight/Volume: 20.00 g
Final Weight/Volume: 20.00 mL
Analyte
pH
Spike Amount
7.00
Result
6.990
% Rec.
100
Limit
63- 158$
Qual
Calculations are performed before rounding to avoid round-off errors in calculated results. $
TestAmerica Savannah	Page 3 9 of 4 0
-------
Arcadis
4915 Prospectus Drive
Durham, NC 27713
(919) 544-4535
(see jar lid)
C/D Ash Sample 6/26/08 [ 06/26/08
(see jar lid)	 06/26/08
Date
Collected
06/25/08
06/25/08
C/D Ash Sample 6/27/08
(see side label)
ash from wood burnir
ash from C&D burning
06/27/08
ash from C&D burnir:
Samples collected by:
(signature)
Samples relinquished by:
(signature)
Samples received by:
(signature)
|"C Co f"
CHAIN OF CUSTODY RECORD
Project Description.
Arcadis charge #:
Responsible Arcadis Part
[Gene Stephenson
Gene Stephenson
Gene Stephenson
Number of
Containers
Analyses Required
see attached quote & P.O.
see attached quote & P.O.
see attached quote & P.O.
Page	1_	 of	1_
Date shipped:
yy**
Date:

os — /4»:«

m w£c.
23*c
o
ij-i
O
o
a)
t7)
a5
&
U* Vis"*
-------
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
nan'
nel c
NELAP Accredited NJ #NC003
919 510-0228 Telephone
919 510-0141 Fax
Web Site: www.rtp-labs.com
August 19, 2008
Arcadis
4915 Prospectus Drive, Suite F
Durham, NC 27713
Attn: Gene Stephenson
PROJECT: Purchase Order #RB63948 (VOCs) #RB64119 (SVOCs); "New Orleans Tests"
RTP Labs Project #: 08-139 (VOCs) and 08-166 (SVOCs)
Enclosed with this letter is the report on the chemical analyses for the samples received July 11 and 16, 2008 for
a normal turnaround. Nine Summa canisters were received on July 11 and seven sets of EPA Method 0010
sample fractions (XAD-2 cartridge, filter, impinger contents) were received on July 16. All samples were
received in good condition with a chain-of-custody forms completed. The Summa canister samples were
analyzed for 60 VOCs by EPA Method TO-15 GC/MS. In addition, a library search was performed for unknown
volatile organic compounds (Tentatively Identified Compounds) using the EPA/NIST 129,000 mass spectral
database. The EPA Method 0010 sample fractions were combined, extracted and analyzed by EPA Method 8270
for Semivolatiles with an EPA/NIST library search for unknown SVOCs.
Please note that ND means not detected at the reporting limits expressed.
Sincerely,
Alston Sykes, Principal Chemist
Attachments: VOCs; SVOCs Reports; COC forms.
Arcadis08-139_166.doc/als	Page 1 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-01.sms	Acquisition Date: 7/30/2008 22:44
Comment: Arcadis/New Orleans C&D #2 June 25
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
0.61
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
31.48
ppbv
0.5
75-01-4
Vinyl chloride
5.98
ppbv
0.5
106-99-0
1,3-Butadiene
36.68
ppbv
0.5
74-83-9
Bromomethane
4.50
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
Not Found
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
10.09
ppbv
0.5
75-15-0
Carbon disulfide
12.45
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
Below MDL
ppbv
0.5
67-64-1
Acetone
74.56
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
1.28
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
Not Found
ppbv
0.5
141-78-6
Ethyl Acetate
3.74
ppbv
0.5
109-99-9
Tetrahydrofuran
0.66
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
17.42
ppbv
0.5
142-82-5
Heptane
0.82
ppbv
0.5
71-43-2
Benzene
161.23
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
0.39
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
0.48
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
23.67
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
0.41
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
Below MDL
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethylbenzene
3.20
ppbv
0.5
108-90-7
Chlorobenzene
1.02
ppbv
0.5
1330-20-7
m/p-Xylene
5.20
ppbv
0.5
95-47-6
o-Xylene
2.02
ppbv
0.5
100-42-5
Styrene
14.45
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
1.71
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
1.65
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
2.01
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 2 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-01.sms	Acquisition Date: 7/30/2008 22:44
Comment: Arcadis/New Orleans C&D #2 June 25
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
96-15-1
1-Butanamine, 2-methyl-
9.02
21.09
ppbv
74-97-5
Methane, bromochloro-
16.2
16.13
ppbv
598-58-3
Methyl nitrate
17.1
18.09
ppbv
624-92-0
Disulfide, dimethyl
20.2
31.09
ppbv
544-25-2
1,3,5-Cycloheptatriene
20.5
63.26
ppbv
None
3-(4-Hydroxy-3-methoxyphenyl)-2-isothioc
20.7
25.94
ppbv
40136-65-0
Methyl isopropyl disulphide
23.5
16.08
ppbv
98-01-1
Furfural
23.6
52.11
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.8
34.31
ppbv
535-77-3
Benzene, 1 -methyl-3-(1 -methylethyl)-
25.2
28.05
ppbv
33868-50-7
Ethanone, 2-(benzoyloxy)-1 -phenyl-
25.5
82.31
ppbv
7423-69-0
1-Hexene, 3,5-dimethyl-
25.7
24.79
ppbv
766-97-2
Benzene, 1-ethynyl-4-methyl-
26.0
17.61
ppbv
1197-01-9
Benzenemethanol, a,a,4-trimethyl-
26.2
49.91
ppbv
29812-79-1
Hydroxylamine, O-decyl-
26.7
17.93
ppbv
2890-67-7
Cyclohexanemethyl propanoate
26.8
19.16
ppbv
102-31-8
Benzeneethanamine, a,3,4-trimethyl-
26.9
19.11
ppbv
30718-58-2
N-Benzoyl-2,2-difluoro-3,3-bis(trifluoro
27.0
19.11
ppbv
91-20-3
Naphthalene
28.3
101.50
ppbv
122-03-2
Benzaldehyde, 4-(1-methylethyl)-
29.5
19.39
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:13	Page 1 of 1	CLP TIC	08-139-01 .sms
Arcadis08-139_166.doc/als
Page 3 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-02.sms	Acquisition Date: 7/30/2008 23:28
Comment: Arcadis/New Orleans Wood Burn #1
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
Not Found
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
Not Found
ppbv
0.5
75-01-4
Vinyl chloride
Not Found
ppbv
0.5
106-99-0
1,3-Butadiene
Not Found
ppbv
0.5
74-83-9
Bromomethane
Not Found
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
Not Found
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
5.04
ppbv
0.5
75-15-0
Carbon disulfide
Not Found
ppbv
0.5
67-63-0
Isopropyl alcohol
Below MDL
ppbv
0.5
75-09-2
Methylene chloride
8.11
ppbv
0.5
67-64-1
Acetone
37.91
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
Not Found
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
Not Found
ppbv
0.5
141-78-6
Ethyl Acetate
Not Found
ppbv
0.5
109-99-9
Tetrahydrofuran
Not Found
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
Not Found
ppbv
0.5
142-82-5
Heptane
Not Found
ppbv
0.5
71-43-2
Benzene
26.95
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
0.75
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
0.72
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
1.81
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
0.78
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
0.75
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethyl benzene
0.38
ppbv
0.5
108-90-7
Chlorobenzene
Not Found
ppbv
0.5
1330-20-7
m/p-Xylene
0.80
ppbv
0.5
95-47-6
o-Xylene
0.45
ppbv
0.5
100-42-5
Styrene
0.86
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
Not Found
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
0.54
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
Not Found
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 4 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-02.sms	Acquisition Date: 7/30/2008 23:28
Comment: Arcadis/New Orleans Wood Burn #1
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
74-97-5
Methane, bromochloro-
16.2
20.68
ppbv
16979-20-7
4-Methylbenzylidene-4-methylaniline
20.7
47.45
ppbv
190-81-8
Tribenzo[b,n,pqr]perylene
23.0
17.18
ppbv
110871-41-
2,5-Dichloro-N-(1,1-dimethyl-2-phenyleth
23.3
26.60
ppbv
103805-86-
Racemosol
23.8
24.59
ppbv
63689-57-6
Carbamic acid, (trifluoromethyl)-, 1,1-d
24.8
16.67
ppbv
75991-61-6
2,7-Octadiene-1,6-diol, 2,6-dimethyl-, (
25.0
8.84
ppbv
51324-18-6
Benzenecarboximidothioic acid, N-(3-phen
25.2
8.33
ppbv
30718-58-2
N-Benzoyl-2,2-difluoro-3,3-bis(trifluoro
25.5
48.94
ppbv
7423-69-0
1-Hexene, 3,5-dimethyl-
25.7
45.39
ppbv
None
1,3-Dimethyl-5-[3-(2-methoxycarbonyl-2-a
25.9
19.20
ppbv
33406-07-4
6H-1,2,5-Oxadiazine-6-thione, 4,5-dihydr
26.2
18.48
ppbv
63922-51-0
3,4-Heptadien-2-one, 3,5-dicyclopentyl-6
26.4
8.60
ppbv
29833-69-0
1-Pentadecene, 2-methyl-
26.7
18.07
ppbv
22104-79-6
2-Nonen-1-ol
26.8
11.24
ppbv
72218-58-7
3-Methylheptyl acetate
26.9
17.21
ppbv
532-27-4
Acetophenone, 2-chloro-
27.0
16.81
ppbv
82360-14-3
2,2-Dimethyl-propyl 2,2-dimethyl-propane
27.8
11.89
ppbv
None
4-Propionyloxytridecane
28.0
19.23
ppbv
91-20-3
Naphthalene
28.3
95.53
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:13	Page 1 of 1	CLP TIC	08-139-02.sms
Arcadis08-139_166.doc/als
Page 5 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-03.sms	Acquisition Date: 7/31/2008 0:16
Comment: Arcadis/New Orleans C&D #1 June 25
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
Not Found
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
Not Found
ppbv
0.5
75-01-4
Vinyl chloride
Not Found
ppbv
0.5
106-99-0
1,3-Butadiene
Not Found
ppbv
0.5
74-83-9
Bromomethane
Not Found
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
Not Found
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
10.17
ppbv
0.5
75-15-0
Carbon disulfide
15.29
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
25.78
ppbv
0.5
67-64-1
Acetone
32.62
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
Not Found
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
Not Found
ppbv
0.5
141-78-6
Ethyl Acetate
Not Found
ppbv
0.5
109-99-9
Tetrahydrofuran
Not Found
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
Not Found
ppbv
0.5
142-82-5
Heptane
Not Found
ppbv
0.5
71-43-2
Benzene
12.66
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
Not Found
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
Not Found
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
2.79
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
0.60
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
0.67
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethylbenzene
0.60
ppbv
0.5
108-90-7
Chlorobenzene
Not Found
ppbv
0.5
1330-20-7
m/p-Xylene
2.66
ppbv
0.5
95-47-6
o-Xylene
1.00
ppbv
0.5
100-42-5
Styrene
Not Found
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
0.76
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
1.12
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
Not Found
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 6 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-03.sms	Acquisition Date: 7/31/2008 0:16
Comment: Arcadis/New Orleans C&D #1 June 25
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
293765-87-
Dibenzo[cd,g]indazole-3-sulfonic acid, 2
8.87
300.52
ppbv
74-97-5
Methane, bromochloro-
16.2
44.29
ppbv
648-36-2
Hexane, 3,3,4,4-tetrafluoro-
17.2
7.74
ppbv
544-25-2
1,3,5-Cycloheptatriene
20.6
9.68
ppbv
98-36-2
2-Chloroaniline-5-sulfonic acid
20.7
50.93
ppbv
469-61-4
1 H-3a,7-Methanoazulene, 2,3,4,7,8,8a-hex
22.0
10.00
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.8
70.81
ppbv
79-92-5
Camphene
23.9
10.99
ppbv
111-71-7
Heptanal
24.0
11.69
ppbv
106260-21-
trans-2,3-Bis(2,4,5-trimethyl-3-thienyl)
24.8
12.14
ppbv
24310-39-2
4(1 H)-Quinolone, 2,3-dihydro-6-methoxy-2
24.8
11.90
ppbv
99-87-6
Benzene, 1 -methyl-4-(1 -methylethyl)-
25.2
59.68
ppbv
2243-35-8
Ethanone, 2-(acetyloxy)-1 -phenyl-
25.5
48.88
ppbv
7423-69-0
1-Hexene, 3,5-dimethyl-
25.7
25.03
ppbv
None
1,3-Dimethyl-5-[3-(2-methoxycarbonyl-2-a
26.0
13.29
ppbv
459-73-4
Glycine, ethyl ester
26.2
18.10
ppbv
51973-28-5
1 H-lmidazol-1-yloxy, 4-(dibromomethyl)-2
26.7
6.79
ppbv
88153-47-3
5,6-Dimethoxy-7,3',4'-trihydroxyflavone
26.8
12.62
ppbv
3588-18-9
5,7-Octadien-4-one, 2,6-dimethyl-, (Z)-
28.2
13.56
ppbv
91-20-3
Naphthalene
28.3
100.08
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:14	Page 1 of 1	CLP TIC	08-139-03.sms
Arcadis08-139_166.doc/als
Page 7 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-04.sms	Acquisition Date: 7/31/2008 1:03
Comment: Arcadis/New Orleans Wood #2
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
Not Found
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
23.65
ppbv
0.5
75-01-4
Vinyl chloride
Not Found
ppbv
0.5
106-99-0
1,3-Butadiene
4.76
ppbv
0.5
74-83-9
Bromomethane
Not Found
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
0.39
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
55.41
ppbv
0.5
75-15-0
Carbon disulfide
65.46
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
2.46
ppbv
0.5
67-64-1
Acetone
53.12
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
Not Found
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
Not Found
ppbv
0.5
141-78-6
Ethyl Acetate
Not Found
ppbv
0.5
109-99-9
Tetrahydrofuran
Not Found
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
Not Found
ppbv
0.5
142-82-5
Heptane
10.59
ppbv
0.5
71-43-2
Benzene
670.34
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
Not Found
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
Not Found
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
46.65
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
Below MDL
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
Not Found
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethyl benzene
2.40
ppbv
0.5
108-90-7
Chlorobenzene
1.73
ppbv
0.5
1330-20-7
m/p-Xylene
3.83
ppbv
0.5
95-47-6
o-Xylene
1.32
ppbv
0.5
100-42-5
Styrene
11.29
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
Not Found
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
0.27
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
0.53
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
Not Found
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 8 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-04.sms	Acquisition Date: 7/31/2008 1:03
Comment: Arcadis/New Orleans Wood #2
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
96-15-1
1-Butanamine, 2-methyl-
9.00
10.76
ppbv
74-97-5
Methane, bromochloro-
16.2
21.28
ppbv
124-38-9
Carbon dioxide
17.0
44.16
ppbv
544-25-2
1,3,5-Cycloheptatriene
20.5
107.16
ppbv
14920-92-4
Phenyl-pentamethyl-disiloxane
20.7
61.81
ppbv
536-74-3
Phenylethyne
23.2
21.72
ppbv
6415-58-3
1,2-Diphenyl-3-chlorocarbonyl-cycloprope
23.5
12.35
ppbv
98-01-1
Furfural
23.6
15.07
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.8
94.57
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.8
13.84
ppbv
2918-13-0
1 -Hepten-3-one
24.0
12.64
ppbv
4796-68-3
7-Benzoyloxybicyclo[2.2.1 ]hepta-2,5-dien
25.5
199.05
ppbv
None
1,3-Dimethyl-5-[3-(2-methoxycarbonyl-2-a
25.9
13.44
ppbv
100-47-0
Benzonitrile
26.2
34.67
ppbv
None
Propanoic acid, 3-chloro-, 4-formylpheny
26.7
26.52
ppbv
2890-67-7
Cyclohexanemethyl propanoate
26.8
16.14
ppbv
104-87-0
Benzaldehyde, 4-methyl-
26.9
14.03
ppbv
55153-12-3
Ethanone, 2-(formyloxy)-1 -phenyl-
27.0
40.31
ppbv
88-75-5
Phenol, 2-nitro-
28.0
76.53
ppbv
91-20-3
Naphthalene
28.3
345.95
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:27	Page 1 of 1	CLP TIC	08-139-04.sms
Arcadis08-139_166.doc/als
Page 9 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-05.sms	Acquisition Date: 7/31/2008 1:50
Comment: Arcadis/New Orleans C&D #6 June 26
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
0.48
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
47.55
ppbv
0.5
75-01-4
Vinyl chloride
11.27
ppbv
0.5
106-99-0
1,3-Butadiene
50.01
ppbv
0.5
74-83-9
Bromomethane
2.57
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
0.20
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
34.47
ppbv
0.5
75-15-0
Carbon disulfide
37.66
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
Below MDL
ppbv
0.5
67-64-1
Acetone
31.32
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
Not Found
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
0.51
ppbv
0.5
141-78-6
Ethyl Acetate
3.56
ppbv
0.5
109-99-9
Tetrahydrofuran
0.58
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
13.47
ppbv
0.5
142-82-5
Heptane
Not Found
ppbv
0.5
71-43-2
Benzene
86.26
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
0.48
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
Not Found
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
18.64
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
Not Found
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
Not Found
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethylbenzene
2.07
ppbv
0.5
108-90-7
Chlorobenzene
1.16
ppbv
0.5
1330-20-7
m/p-Xylene
3.30
ppbv
0.5
95-47-6
o-Xylene
1.51
ppbv
0.5
100-42-5
Styrene
9.50
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
Not Found
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
0.72
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
6.02
ppbv
0.5
95-50-1
1,2-dichlorobenzene
0.67
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 10 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-05.sms	Acquisition Date: 7/31/2008 1:50
Comment: Arcadis/New Orleans C&D #6 June 26
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
107-01-7
2-Butene
8.95
13.66
ppbv
None
dl-3,4-Dehydroproline methyl ester
11.3
23.65
ppbv
534-22-5
Furan, 2-methyl-
15.1
20.09
ppbv
542-88-1
Methane, oxybis[chloro-
16.2
8.76
ppbv
124-38-9
Carbon dioxide
17.1
12.55
ppbv
544-25-2
1,3,5-Cycloheptatriene
20.5
42.25
ppbv
56784-17-9
6-Nonenamide, N-[[3-methoxy-4-[(trimethy
20.7
15.04
ppbv
98-01-1
Furfural
23.6
63.35
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.8
32.67
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.9
13.93
ppbv
1120-73-6
2-Cyclopenten-1-one, 2-methyl-
24.7
8.96
ppbv
123-05-7
Hexanal, 2-ethyl-
24.8
19.79
ppbv
33868-50-7
Ethanone, 2-(benzoyloxy)-1 -phenyl-
25.5
52.94
ppbv
104-76-7
1-Hexanol, 2-ethyl-
25.7
85.84
ppbv
None
1,3-Dimethyl-5-[3-(2-methoxycarbonyl-2-a
25.9
10.35
ppbv
7190-99-0
Bis-S-triazolo[4,3-b,3',4'-f]pyridazine,
26.2
20.20
ppbv
2890-67-7
Cyclohexanemethyl propanoate
26.8
9.92
ppbv
27257-15-4
1 H-Pyrrolo[2,3-b]pyridine, 1-methyl-
26.9
10.52
ppbv
54797-44-3
Benzoic acid, 4-methyl-, 2-oxo-2-phenyle
27.0
9.66
ppbv
91-20-3
Naphthalene
28.3
26.77
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:27	Page 1 of 1	CLP TIC	08-139-05.sms
Arcadis08-139_166.doc/als
Page 11 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-06.sms	Acquisition Date: 7/31/2008 2:36
Comment: Arcadis/New Orleans C&D #5 June 26
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
Not Found
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
190.45
ppbv
0.5
75-01-4
Vinyl chloride
55.07
ppbv
0.5
106-99-0
1,3-Butadiene
209.71
ppbv
0.5
74-83-9
Bromomethane
5.19
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
Not Found
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
2.81
ppbv
0.5
75-15-0
Carbon disulfide
Not Found
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
9.51
ppbv
0.5
67-64-1
Acetone
78.52
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
1.61
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
0.37
ppbv
0.5
141-78-6
Ethyl Acetate
11.58
ppbv
0.5
109-99-9
Tetrahydrofuran
3.07
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
0.64
ppbv
0.5
78-93-3
2-Butanone
42.26
ppbv
0.5
142-82-5
Heptane
Not Found
ppbv
0.5
71-43-2
Benzene
443.04
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
Not Found
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
Not Found
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
91.93
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
Not Found
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
Not Found
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethylbenzene
12.19
ppbv
0.5
108-90-7
Chlorobenzene
6.50
ppbv
0.5
1330-20-7
m/p-Xylene
18.80
ppbv
0.5
95-47-6
o-Xylene
7.01
ppbv
0.5
100-42-5
Styrene
116.28
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
4.56
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
3.08
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
52.60
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 12 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-06.sms	Acquisition Date: 7/31/2008 2:36
Comment: Arcadis/New Orleans C&D #5 June 26
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
107-01-7
2-Butene
8.95
53.37
ppbv
None
dl-3,4-Dehydroproline methyl ester
11.3
46.61
ppbv
534-22-5
Furan, 2-methyl-
15.1
35.71
ppbv
74-97-5
Methane, bromochloro-
16.2
32.99
ppbv
544-25-2
1,3,5-Cycloheptatriene
20.5
168.51
ppbv
21578-58-5
1 H-Benzimidazol-2-amine, N-phenyl-
20.7
66.10
ppbv
38310-48-4
Tricyclo[3.2.1,0(2,4)]octane, 8-methylen
23.5
51.40
ppbv
98-01-1
Furfural
23.6
132.46
ppbv
47145-46-0
3,4-Dihydroisoquinolin-7-ol, 1 -[4-hydrox
23.8
70.45
ppbv
79-92-5
Camphene
23.9
47.27
ppbv
598-23-2
1-Butyne, 3-methyl-
24.7
30.23
ppbv
5989-54-8
Cyclohexene, 1 -methyl-4-(1 -methylethenyl
25.0
64.89
ppbv
99-87-6
Benzene, 1 -methyl-4-(1 -methylethyl)-
25.2
32.79
ppbv
33868-50-7
Ethanone, 2-(benzoyloxy)-1 -phenyl-
25.5
169.53
ppbv
673-32-5
Benzene, 1-propynyl-
26.0
114.58
ppbv
105151-36-
3-Pyridinecarbonitrile, 2-nitro-
26.2
46.91
ppbv
43230-93-9
D:A-Friedooleanane-1,3-dione, 2-acetyl-7
26.7
30.83
ppbv
620-23-5
Benzaldehyde, 3-methyl-
26.9
47.93
ppbv
54797-44-3
Benzoic acid, 4-methyl-, 2-oxo-2-phenyle
27.0
40.38
ppbv
91-20-3
Naphthalene
28.3
140.73
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:28	Page 1 of 1	CLP TIC	08-139-06.sms
Arcadis08-139_166.doc/als
Page 13 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-07.sms	Acquisition Date: 7/31/2008 3:21
Comment: Arcadis/New Orleans C&D #3 June 26
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
Not Found
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
Not Found
ppbv
0.5
75-01-4
Vinyl chloride
16.98
ppbv
0.5
106-99-0
1,3-Butadiene
159.24
ppbv
0.5
74-83-9
Bromomethane
Not Found
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
Not Found
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
Not Found
ppbv
0.5
75-15-0
Carbon disulfide
Not Found
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
1.19
ppbv
0.5
67-64-1
Acetone
294.91
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
0.98
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
1.11
ppbv
0.5
141-78-6
Ethyl Acetate
Not Found
ppbv
0.5
109-99-9
Tetrahydrofuran
1.02
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
Not Found
ppbv
0.5
142-82-5
Heptane
8.57
ppbv
0.5
71-43-2
Benzene
497.59
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
Not Found
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
Not Found
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
78.09
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
0.80
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
2.59
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethylbenzene
5.03
ppbv
0.5
108-90-7
Chlorobenzene
3.26
ppbv
0.5
1330-20-7
m/p-Xylene
7.05
ppbv
0.5
95-47-6
o-Xylene
2.86
ppbv
0.5
100-42-5
Styrene
6.65
ppbv
0.5
75-25-2
Tribromomethane
0.47
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
Not Found
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
Not Found
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
Not Found
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 14 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-07.sms	Acquisition Date: 7/31/2008 3:21
Comment: Arcadis/New Orleans C&D #3 June 26
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
115-07-1
Propene
8.43
59.97
ppbv
96-15-1
1-Butanamine, 2-methyl-
9.02
113.72
ppbv
10230-68-9
1 -Nitro-2-propanone
9.80
44.02
ppbv
591-95-7
1,2-Pentadiene
11.1
29.77
ppbv
110-00-9
Furan
11.4
49.82
ppbv
3518-65-8
Chloromethanesulfonyl chloride
13.0
26.98
ppbv
74-97-5
Methane, bromochloro-
16.2
100.06
ppbv
624-92-0
Disulfide, dimethyl
20.3
49.42
ppbv
544-25-2
1,3,5-Cycloheptatriene
20.5
244.19
ppbv
98-36-2
2-Chloroaniline-5-sulfonic acid
20.7
50.72
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.8
31.51
ppbv
111-71-7
Heptanal
24.0
35.49
ppbv
5961-33-1
Azetidine, 3-methyl-3-phenyl-
24.7
37.95
ppbv
40727-07-9
1,3,4-Oxadiazolium, 5-mercapto-2-methyl-
25.5
106.50
ppbv
104-76-7
1-Hexanol, 2-ethyl-
25.7
28.47
ppbv
100-47-0
Benzonitrile
26.2
76.01
ppbv
1474-52-8
17a-Estradiol diacetate
26.4
41.48
ppbv
37902-13-9
Benzene, 1,3-bis(4-phenyl-1,3-butadiynyl
26.7
33.75
ppbv
2890-67-7
Cyclohexanemethyl propanoate
26.8
76.40
ppbv
91-20-3
Naphthalene
28.3
231.82
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:28	Page 1 of 1	CLP TIC	08-139-07.sms
Arcadis08-139_166.doc/als
Page 15 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-08a.sms	Acquisition Date: 7/31/2008 10:51
Comment: Arcadis/New Orleans C&D #4 June 26
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
Not Found
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
Not Found
ppbv
0.5
75-01-4
Vinyl chloride
11.59
ppbv
0.5
106-99-0
1,3-Butadiene
88.74
ppbv
0.5
74-83-9
Bromomethane
Not Found
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Below MDL
ppbv
0.5
75-35-4
1,1-dichloroethene
Not Found
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
Not Found
ppbv
0.5
75-15-0
Carbon disulfide
Not Found
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
33.07
ppbv
0.5
67-64-1
Acetone
274.38
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
0.72
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
0.44
ppbv
0.5
141-78-6
Ethyl Acetate
5.32
ppbv
0.5
109-99-9
Tetrahydrofuran
1.76
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
Not Found
ppbv
0.5
142-82-5
Heptane
2.14
ppbv
0.5
71-43-2
Benzene
177.06
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
9.48
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
0.37
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
31.21
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
Not Found
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
Not Found
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethylbenzene
4.92
ppbv
0.5
108-90-7
Chlorobenzene
1.51
ppbv
0.5
1330-20-7
m/p-Xylene
6.03
ppbv
0.5
95-47-6
o-Xylene
2.50
ppbv
0.5
100-42-5
Styrene
30.52
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
Not Found
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
1.33
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
Not Found
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 16 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
tTlxai
NELAP Accredited NJ #NC003
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-08a.sms	Acquisition Date: 7/31/2008 10:51
Comment: Arcadis/New Orleans C&D #4 June 26
CAS NO.
COMPOUND NAME
Retention Time
Estimated Concentration, Units
115-07-1
Propene
8.49
18.91
ppbv
106-99-0
1,3-Butadiene
9.25
24.72
ppbv
37294-05-6
Azadirachtin, 3-O-deacetyl-
16.3
13.13
ppbv
71-36-3
1-Butanol
18.8
11.87
ppbv
544-25-2
1,3,5-Cycloheptatriene
20.6
61.59
ppbv
21578-58-5
1 H-Benzimidazol-2-amine, N-phenyl-
20.7
462.29
ppbv
1714-14-3
9,10-Anthracenedione, 1-phenyl-
23.8
222.99
ppbv
66407-26-9
Cyclopenta[c]pyran-1,3-dione, 4,4a,5,6-t
25.0
14.61
ppbv
30718-58-2
N-Benzoyl-2,2-difluoro-3,3-bis(trifluoro
25.5
107.37
ppbv
7423-69-0
1-Hexene, 3,5-dimethyl-
25.7
31.47
ppbv
None
1,3-Dimethyl-5-[3-(2-methoxycarbonyl-2-a
25.9
28.83
ppbv
76100-13-5
Propanedinitrile, 2-(5-phenylthio-2-thie
26.0
18.14
ppbv
108-95-2
Phenol
26.2
489.02
ppbv
2890-67-7
Cyclohexanemethyl propanoate
26.8
43.16
ppbv
71840-29-4
Phenol, 2,2'-methylenebis-, dibenzoate
27.0
16.58
ppbv
None
4-Hydroxy-7-(p-methyl-phenacyl)-xanthopt
27.2
20.63
ppbv
87069-33-8
Sarcocapnidine
27.2
13.64
ppbv
42215-29-2
4(1 H)-Pyridinone, 1,2,6-t ri m et hy I-3,5-d i
27.4
13.49
ppbv
1474-52-8
17a-Estradiol diacetate
28.0
31.36
ppbv
275-51-4
Azulene
28.3
184.43
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:29	Page 1 of 1	CLP TIC	08-139-08a.sms
Arcadis08-139_166.doc/als
Page 17 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-09.sms	Acquisition Date: 7/30/2008 22:01
Comment: Arcadis/New Orleans Blank, Can 12163.
CAS NO.
COMPOUND
CONCENTRATION
UNITS
Reporting
75-71-8
Dichlorodifluoromethane (Freon 12)
Not Found
ppbv
0.5
76-14-2
1,2-Chloro-1,1,2,2-Tetrafluoroethane
Not Found
ppbv
0.5
74-87-3
Chloromethane
Not Found
ppbv
0.5
75-01-4
Vinyl chloride
Not Found
ppbv
0.5
106-99-0
1,3-Butadiene
Not Found
ppbv
0.5
74-83-9
Bromomethane
Not Found
ppbv
0.5
75-00-3
Chloroethane
Not Found
ppbv
0.5
75-69-4
Trichloromonofluoromethane
Not Found
ppbv
0.5
75-35-4
1,1-dichloroethene
Not Found
ppbv
0.5
76-13-1
1,1,2-trichloro-1,2,2-trifluoroethane
Not Found
ppbv
0.5
64-17-5
Ethanol
Not Found
ppbv
0.5
75-15-0
Carbon disulfide
Not Found
ppbv
0.5
67-63-0
Isopropyl alcohol
Not Found
ppbv
0.5
75-09-2
Methylene chloride
7.30
ppbv
0.5
67-64-1
Acetone
6.61
ppbv
0.5
156-60-5
t-1,2-dichloroethene
Not Found
ppbv
0.5
11-05-3
Hexane
Not Found
ppbv
0.5
1634-04-4
Methyl-t-butyl ether (MTBE)
Not Found
ppbv
0.5
75-34-3
1,1-Dichloroethane
Not Found
ppbv
0.5
108-05-4
Vinyl acetate
Not Found
ppbv
0.5
156-59-2
cis-1,2-dichloroethene
Not Found
ppbv
0.5
110-82-7
Cyclohexane
Not Found
ppbv
0.5
67-66-3
Chloroform
Not Found
ppbv
0.5
141-78-6
Ethyl Acetate
Not Found
ppbv
0.5
109-99-9
Tetrahydrofuran
Not Found
ppbv
0.5
71-55-6
1,1,1-trichloroethane
Not Found
ppbv
0.5
56-23-5
Carbon Tetrachloride
Not Found
ppbv
0.5
78-93-3
2-Butanone
Not Found
ppbv
0.5
142-82-5
Heptane
Not Found
ppbv
0.5
71-43-2
Benzene
Not Found
ppbv
0.5
107-06-2
1,2-dichloroethane
Not Found
ppbv
0.5
79-01-6
Trichloroethylene
Not Found
ppbv
0.5
78-87-5
1,2-dichloropropane
Not Found
ppbv
0.5
75-27-4
Bromodichloromethane
Not Found
ppbv
0.5
123-91-1
1,4-dioxane
Not Found
ppbv
0.5
10061-01-5
cis-1,3-dichloropropene
Not Found
ppbv
0.5
108-88-3
Toluene
Not Found
ppbv
0.5
108-10-1
4-Methyl-2-pentanone (MIBK)
Not Found
ppbv
0.5
1006-02-6
t-1,3-dichloropropene
Not Found
ppbv
0.5
127-18-4
Tetrachloroethylene
Below MDL
ppbv
0.5
79-00-5
1,1,2-trichloroethane
Not Found
ppbv
0.5
124-48-1
Dibromochloromethane
Not Found
ppbv
0.5
106-93-4
1,2-dibromoethane
Not Found
ppbv
0.5
591-78-6
2-Hexanone
Not Found
ppbv
0.5
100-41-4
Ethylbenzene
Not Found
ppbv
0.5
108-90-7
Chlorobenzene
Not Found
ppbv
0.5
1330-20-7
m/p-Xylene
Not Found
ppbv
0.5
95-47-6
o-Xylene
Not Found
ppbv
0.5
100-42-5
Styrene
Not Found
ppbv
0.5
75-25-2
Tribromomethane
Not Found
ppbv
0.5
79-34-5
1,1,2,2-tetrachloroethane
Not Found
ppbv
0.5
622-96-8
1 -ethyl-4-methylbenzene
Not Found
ppbv
0.5
108-67-8
1,3,5-trimethylbenzene
Not Found
ppbv
0.5
95-63-6
1,2,4-trimethylbenzene
Not Found
ppbv
0.5
541-73-1
1,3-dichlorobenzene
Not Found
ppbv
0.5
106-46-7
1,4-dichlorobenzene
Not Found
ppbv
0.5
100-44-7
Benzyl chloride
Not Found
ppbv
0.5
95-50-1
1,2-dichlorobenzene
Not Found
ppbv
0.5
87-68-3
1,1,2,3,4,4-hexachloro-1,3-butadiene
Not Found
ppbv
0.5
120-82-1
1,2,4-trichlorobenzene
Not Found
ppbv
0.5
Arcadis08-139_166.doc/als
Page 18 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
TENTATIVELY IDENTIFIED COMPOUNDS
EPA Method TO-15 GC/MS VOLATILE ORGANICS ANALYSIS REPORT
Data File: c:\varianws\wsdatafiles\voc072908\08-139-09.sms	Acquisition Date: 7/30/2008 22:01
Comment: Arcadis/New Orleans Blank, Can 12163.
CAS NO.	COMPOUND NAME
115-11-7	1 -Propene, 2-methyl-
96-15-1	1-Butanamine, 2-methyl-
Retention Time Estimated Concentration, Units
9.28
9.45
0.82
0.86
ppbv
ppbv
(IS) is BFB Internal Standard and (SS) are Surrogate Standards that are added to each sample.
8/12/2008 12:29	Page 1 of 1	CLP TIC
08-139-09.sms
Arcadis08-139_166.doc/als
Page 19 of 68
-------
w
©
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* £
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Research Triangle Park Laboratories, Inc
7201 ACC Blvd., Suite 104
Raleigh, North Carolina 27617
Phone: 919-510-0228 Fax: 919-510-0141
Web Site: www.rtp-labs.com

\W ACCo*,
Chain of Custody Record
NELAP Accredited NJ #NC003
ISO 17025
Client (BiHiag):
fi/lCAQii
Send Report To Attention:
¦tfj/f	fac r* jr
City

Stale
#/<-
Zip Code
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Contract/Purchase Order No.:
^lfr'0(A/6
Project Name:
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Comments:
Sample ID No. & Description

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QC Requirements: Screen ~ Standard D
EPA Levei IV for Compliance Q
Requires approved OAFF sent to lab 	
Received By:
File: chain RTP.doc/als revision 5/20/2008
An
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-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Methods 8270 Semivolatiles by GC/MS


Data File Name:
08166-01.D


Data File Path:
C:\MSDChem\1\DATA\01_04_
_08\

Operator:
amg


Date Acquired:
8/6/2008 8:51


Acq. Method File:
8270C_2.M


Misc Info:
08-166-01 Run#l M0010-01



1uL; 5mLMeCI2


Vial Number:
1


Instrument Name:
GCMS#3 HP6890_5973


Sample Multiplier:
5




Unit
#
Compound Name
Amount Total/Sa
1)
Pyridine
ND
ug
2)
N-Nitrosodimethylamine
ND
ug
3)
Phenol
ND
ug
4)
Aniline
ND
ug
5)
s-Dichloroethyl ether
ND
ug
6)
2-Chlorophenol
ND
ug
7)
1,3-Dichlorobenzene
ND
ug
8)
1,4-Dichlorobenzene
ND
ug
9)
Benzyl Alcohol
108.46
ug
10)
1,2-Dichlorobenzene
ND
ug
11)
2-Methylphenol
ND
ug
12)
Bis(2-chloroisopropyl)ether
ND
ug
13)
3 & 4-Methylphenol
ND
ug
14)
N-nitroso-di-n-propylamine
ND
ug
15)
Hexachloroethane
ND
ug
16)
Nitrobenzene
ND
ug
17)
Isophorone
ND
ug
18)
2-Nitrophenol
ND
ug
19)
2,4-Dimethylphenol
ND
ug
20)
Bis(2-chloroethoxy)methane
ND
ug
21)
2,4-Dichlorophenol
85.41
ug
22)
1,2,4-Trichlorobenzene
ND
ug
23)
Naphthalene
93.63
ug
24)
p-Chloroaniline
ND
ug
25)
Hexachloro-1,3-butadiene
ND
ug
26)
4-Chloro-3-methylphenol
ND
ug
27)
2-Methylnaphthalene
54.92
ug
28)
1 -Methylnaphthalene
13.63
ug
29)
Hexachlorocyclopentadiene
ND
ug
30)
2,4,6-Trichlorophenol
ND
ug
31)
2,4,5-Trichlorophenol
4.69
ug
Arcadis08-139_166.doc/als
Page 21 of 68
-------
Jh Triangle Pf
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
rk LaTborattories, I:
mc.
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
32)
2-Chloronaphthalene
ND
ug
33)
2-Nitroaniline
ND
ug
34)
1,4-Dinitrobenzene
ND
ug
35)
Dimethyl phthalate
5.99
ug
36)
1,3-Dinitrobezene
ND
ug
37)
Acenaphthylene
6.89
ug
38)
2,6-Dinitrotoluene
6.00
ug
39)
1,2-Dinitrobenzene
ND
ug
40)
3-Nitroaniline
ND
ug
41)
Acenaphthene
1.23
ug
42)
2,4-Dinitrophenol
ND
ug
43)
4-Nitrophenol
ND
ug
44)
Dibenzofuran
9.22
ug
45)
2,4-Dinitrotoluene
ND
ug
46)
2,3,4,6-Tetrachlorophenol
ND
ug
47)
2,3,5,6-Tetrachlorophenol
ND
ug
48)
Diethylphthalate
8.25
ug
49)
4-Chlorophenyl phenyl ether
ND
ug
50)
Fluorene
ND
ug
51)
4-Nitroaniline
ND
ug
52)
4,6-Dinitro-2-methylphenol
ND
ug
53)
Diphenylamine
ND
ug
54)
Azobenzene
ND
ug
55)
4-Bromophenyl phenyl ether
ND
ug
56)
Hexachlorobenzene
ND
ug
57)
Pentachlorophenol
ND
ug
58)
Phenanthrene
18.52
ug
59)
Anthracene
20.44
ug
60)
Carbazole
ND
ug
61)
Di-n-butyl phthalate
75.87
ug
62)
Fluoranthene
5.72
ug
63)
Pyrene
4.51
ug
64)
Benzyl butyl phthalate
ND
ug
65)
Bis(2-ethylhexyl)adipate
ND
ug
66)
Benz[a]anthracene
ND
ug
67)
Chrysene
ND
ug
68)
Bis(2-ethylhexyl) phthalate
56.55
ug
69)
Di-n-octyl phthalate
84.41
ug
70)
Benzo[b]fluoranthene
ND
ug
71)
Benzo[k]fluoranthene
ND
ug
72)
Benzo[a]pyrene
ND
ug
73)
lndeno[1,2,3-cd]pyrene
ND
ug
74)
Dibenz[a,h]anthracene
ND
ug
75)
Benzo[ghi]perylene
ND
ug
Arcadis08-139_166.doc/als
Page 22 of 68
-------
Researcli Triangle Park Laboratories, Inc.	/|
7201 ACCBlvd., Suite 104 *""	I|Tm¥ oVn
Raleigh, NC 27617 ¦	** ' A
• I^aI	NELAP Accredited NJ#NC003
919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
C:\MSDChem\l\DATA\01_04_08\
08166-01.D
6 Aug 20 08 8:51 am
amg
08-166-01 Run#I M0010-01
luL; 5mL MeC12
1 Sample Multiplier: 5
Quant Method : C:\MSDCHEM\1\METHODS\8270C_2.M
Quant Title : 8270C SVOCs
TIC Library : C:\DATABASE\NIST12 9K.L
TIC Integration Parameters: rteint.p
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 1 2-Furancarboxaldehyde, 5-ni... Concentration Rank 6
R.T. EstConc	Area	Relative to ISTD	R.T.
2.84 5457.40 ug 10914800
External
Standard
o
o
o
Hit# of 2 Tentative ID
MW
MolForm
CAS#
Qual
1	2-Furancarboxaldehyde, 5-nitro- ... 141 C5H3N04	000698-63-5 2
2	(CH3)2CHCH20N0	103 C4H9N02	000542-56-3 1
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 2 Dimethyl-t-butylphosphonite	Concentration Rank 7
R.T. EstConc	Area	Relative to ISTD	R.T.
2 . 9E
3 3164.45 ug
6328910
External
Standard
o
o
o
Hit#
of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Dimethyl-t-butylphosphonite	150 C6H1502P	032045-17-3 2
2	Silane, chloro(chloromethyl)dime... 142 C3H8C12Si	001719-57-9 1
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 3 N-(l-Butyl-2-benzimidazolyl... Concentration Rank 3
R.T. EstConc	Area	Relative to ISTD	R.T.
3.19 31021.90 ug	62043800 External Standard	0.00
Hit# of 2 Tentative ID	MW MolForm	CAS#	Qual
1	N-(l-Butyl-2-benzimidazolyl)-4-n... 374 C17H18N404S 000000-00-0 9
2	4,4'-Diisothiocyanatostilbene-2,... 454 C16H10N2O6S4 053005-05-3 9
Arcadis08-139_166.doc/als
Page 23 of 68
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Researcli Triangle Park Laboratories, Inc.	/|
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Raleigh, NC 27617 ¦	** ' A
• I^aI	NELAP Accredited NJ#NC003
919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 4 3-Furaldehyde $$ 3-Furancar... Concentration Rank 8
R.T. EstConc	Area	Relative to ISTD	R.T.
3.32 2670.51 ug
5341030
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	3-Furaldehyde $$ 3-Furancarboxal... 96 C5H402	000498-60-2 91
2	Furfural	96 C5H402	000098-01-1 91
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 5 Ethylbenzene $$ Benzene, et... Concentration Rank 4
R.T. EstConc	Area	Relative to ISTD	R.T.
3.49 19300.60 ug	38601100 External Standard	0.00
Hit# of 2 Tentative ID	MW MolForm	CAS#	Qual
1	Ethylbenzene $$ Benzene, ethyl- ... 106 C8H10	000100-41-4 91
2	1,3-Cyclopentadiene, 5-(1-methyl... 106 C8H10	002175-91-9 80
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 6 Benzene,	1,3-dimethyl-	Concentration Rank 5
R.T. EstConc	Area	Relative to ISTD	R.T.
3.54 18671.30 ug	37342600 External Standard	0.00
Hit# of 2 Tentative	ID	MW MolForm	CAS#	Qual
1	Benzene, 1,3-dimethyl-	106 C8H10	000108-38-3 90
2	Benzene, 1,3-dimethyl-	106 C8H10	000108-38-3 90
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 7 Cyclopentane, l-methyl-2-pr... Concentration Rank 16
R.T. EstConc	Area	Relative to ISTD	R.T.
3.64 328.60 ug
657194
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Cyclopentane, l-methyl-2-propyl- 126 C9H18	003728-57-2 81
2	Cyclopropane, 1,1,2,3-tetramethyl- 98 C7H14	074752-93-5 46
Arcadis08-139_166.doc/als
Page 24 of 68
-------
Researcli Triangle Park Laboratories, Inc.
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tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Peak Number 8 Styrene $$ Benzene, ethenyl... Concentration Rank 11
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.70 746.35 ug
1492700
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Styrene $$ Benzene, ethenyl- $$ ... 104 C8H8
2	Styrene	104 C8H8
000100-42-5 86
000100-42-5 70
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 9 2H-Pyran-2-one, 6-ethyltetr... Concentration Rank 1
R.T. EstConc	Area	Relative to ISTD	R.T.
3.84 270412.00 ug	540824000 External Standard	0.00
Hit# of 2 Tentative ID	MW MolForm	CAS#	Qual
1	2H-Pyran-2-one, 6-ethyltetrahydr... 128 C7H1202
2	3-Hexene, (Z)-	84 C6H12
003301-90-4 52
007642-09-3 46
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 10 Oxazole, 2-ethyl-4,5-dihydro- Concentration Rank 2
R.T. EstConc	Area
3.86 40093.70 ug	80187400
Hit# of 2 Tentative ID
Relative to ISTD
External Standard
MW MolForm
R.T .
0.00
CAS#	Qual
1	Oxazole, 2-ethyl-4,5-dihydro-
2	3-Furanmethanol
99 C5H9NO
98 C5H602
010431-98-8 52
004412-91-3 27
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 11 Benzaldehyde	Concentration Rank 9
R.T .
EstConc
Area
Relative to ISTD
R.T .
4.22 1978.
8 6 ug
3957720
External
Standard
0.00
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde
2	Benzaldehyde
106 C7H60
106 C7H60
000100-52-7 97
000100-52-7 97
Arcadis08-139_166.doc/als
Page 25 of 68
-------
Researcli Triangle Park Laboratories, Inc.	/|
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Raleigh, NC 27617 ¦	** ' A
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919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 12 2H-l-Benzopyran-5-carboxyli...	Concentration Rank 14
R.T. EstConc Area Relative	to ISTD R.T.
4.27 398.56 ug
797119
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	2H-l-Benzopyran-5-carboxylic aci... 206 C11H10O4	120714-40-1 12
2	Benzenemethanamine, N,.alpha.-di... 135 C9H13N	032512-24-6 9
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 13 Phenol $$ Baker's P and S L... Concentration Rank 13
R.T. EstConc	Area	Relative to ISTD	R.T.
4.45 412.00 ug 824009
External
Standard
o
o
o
Hit# of 2 Tentative ID
MW
MolForm
CAS#
Qual
1	Phenol $$ Baker's P and S Liquid... 94 C6H60	000108-95-2 90
2	Phenol	94 C6H60	000108-95-2 76
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 14 Cyclotetrasiloxane, octamet... Concentration Rank 10
R.T. EstConc	Area	Relative to ISTD	R.T.
4 . 4E
3 1334.
81 ug
2669620
External
Standard
o
o
o
Hit#
of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Cyclotetrasiloxane, octamethyl-	296 C8H2404Si4	000556-67-2 52
2	Cyclotetrasiloxane, octamethyl- ... 296 C8H2404Si4	000556-67-2 50
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 15 Acetophenone	Concentration Rank 12
R.T. EstConc	Area	Relative to ISTD	R.T.
4.98 567.92 ug
1135840
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Acetophenone	120 C8H80	000098-86-2 72
2	Acetophenone	120 C8H80	000098-86-2 72
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Arcadis08-139_166.doc/als
Page 26 of 68
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Researcli Triangle Park Laboratories, Inc.
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919 510-0228 Telephone
919 510-0141 Fax
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tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Peak Number 16 Caffeine
R . T . EstConc
Area
Concentration Rank 15
Relative to ISTD	R.T.
9.12 343.34 ug 686673
External
Standard
o
o
o
Hit# of 2 Tentative ID
MW
MolForm
CAS#
1	Caffeine
2	Caffeine $$ lH-Purine-2,6-dione,..
194 C8H10N4O2
194 C8H10N4O2
Qual
000058-08-2 70
000058-08-2 70
Peak Number 17 2 (1H)-Phenanthrenone, 3,4,4... Concentration Rank 17
R.T .
EstConc
Area
Relative to ISTD
R.T .
9.37 322.55 ug
645104
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	2 (1H)-Phenanthrenone, 3,4,4a, 9, 1.. . 272 C18H2402
2	Phenanthrene, 7-ethenyl-1,2,3,4,... 272 C20H32
055255-51-1 60
055255-56-6 60
Peak Number 18 Benzoic acid, 2,4,6-tris (1, .. . Concentration Rank 18
R.T .
EstConc
Area
Relative to ISTD
R.T .
10.21 320.01 ug
640022
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzoic acid, 2,4,6-tris(1,1-dim..
2	1,1 ' : 4',1' '-Terphenyl, 4-nitro-
290 C19H30O2
275 C18H13N02
066415-27-8 43
010355-53-0 42
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 19 1,2-Benzenedicarboxylic aci... Concentration Rank 21
R.T. EstConc	Area	Relative to ISTD	R.T.
11.83 220.45 ug
440908
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1,2-Benzenedicarboxylic acid, mo..
2	1,2-Benzenedicarboxylic acid, bi..
222 C12H1404
250 C14H1804
000131-70-4 72
000605-45-8 59
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 20 Di-n-octyl phthalate	Concentration Rank 20
Arcadis08-139_166.doc/als
Page 27 of 68
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tTlxai
NELAP Accredited NJ #NC003
R.T. EstConc
Area
Relative to ISTD
R.T .
13 .84 268.26 ug
536524
External Standard
o
o
o
Hit# of 2 Tentative
ID
MW Mo1Form
CAS#
Qual
1	Di-n-octyl phthalate
2	1,2-Benzenedicarboxylic acid, de..
390 C24H3804
418 C26H4204
000117-84-0 37
000119-07-3 37
-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 21 1,2-Benzenedicarboxylic aci . . . Concentration Rank 19
R.T .
EstConc
Area
Relative to ISTD
R.T .
14.43 2!
3 0.21 ug
560429
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1,2-Benzenedicarboxylic acid, di..
2	1,2-Benzenedicarboxylic acid, he..
362 C22H3404
376 C23H3604
003648-21-3 64
088216-58-4 64
Arcadis08-139_166.doc/als
Page 28 of 68
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Researcli Triangle Park Laboratories,
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Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
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nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Methods 8270 Semivolatiles by GC/MS
Data File Name:
Data File Path:
Operator:
Date Acquired:
Acq. Method File:
Misc Info:
Vial Number:
Instrument Name:
Sample Multiplier:
# Compound Name
1)	Pyridine
2)	N-Nitrosodimethylamine
3)	Phenol
4)	Aniline
5)	s-Dichloroethyl ether
6)	2-Chlorophenol
7)	1,3-Dichlorobenzene
8)	1,4-Dichlorobenzene
9)	Benzyl Alcohol
10)	1,2-Dichlorobenzene
11)	2-Methylphenol
12)	Bis(2-chloroisopropyl)ether
13)	3 & 4-Methylphenol
14)	N-nitroso-di-n-propylamine
15)	Hexachloroethane
16)	Nitrobenzene
17)	Isophorone
18)	2-Nitrophenol
19)	2,4-Dimethylphenol
20)	Bis(2-chloroethoxy)methane
21)	2,4-Dichlorophenol
22)	1,2,4-Trichlorobenzene
23)	Naphthalene
24)	p-Chloroaniline
25)	Hexachloro-1,3-butadiene
26)	4-Chloro-3-methylphenol
27)	2-Methylnaphthalene
28)	1-Methylnaphthalene
29)	Hexachlorocyclopentadiene
30)	2,4,6-Trichlorophenol
08166-02.D
C:\MSDChem\1\DATA\01_04_08\
amg
8/6/2008 9:54
8270C_2.M
08-166-02 Run#l M0010-02
1uL; 5mLMeCI2
1
GCMS#3
HP6890_5973
5
Units
Amount Total/Sample
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
3.24
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
67.61
ug
ND
ug
ND
ug
ND
ug
32.28
ug
8.23
ug
ND
ug
ND
ug
Arcadis08-139_166.doc/als
Page 29 of 68
-------
Jh Triangle Pf
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
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919 510-0141 Fax
rk LaTborattories, I:
mc.
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
31)
2,4,5-T richlorophenol
ND
ug
32)
2-Chloronaphthalene
ND
ug
33)
2-Nitroaniline
ND
ug
34)
1,4-Dinitrobenzene
ND
ug
35)
Dimethyl phthalate
ND
ug
36)
1,3-Dinitrobezene
ND
ug
37)
Acenaphthylene
4.95
ug
38)
2,6-Dinitrotoluene
ND
ug
39)
1,2-Dinitrobenzene
ND
ug
40)
3-Nitroaniline
ND
ug
41)
Acenaphthene
ND
ug
42)
2,4-Dinitrophenol
ND
ug
43)
4-Nitrophenol
ND
ug
44)
Dibenzofuran
5.31
ug
45)
2,4-Dinitrotoluene
ND
ug
46)
2,3,4,6-Tetrachlorophenol
ND
ug
47)
2,3,5,6-Tetrachlorophenol
ND
ug
48)
Diethylphthalate
ND
ug
49)
4-Chlorophenyl phenyl ether
ND
ug
50)
Fluorene
1.25
ug
51)
4-Nitroaniline
3.24
ug
52)
4,6-Dinitro-2-methylphenol
ND
ug
53)
Diphenylamine
ND
ug
54)
Azobenzene
ND
ug
55)
4-Bromophenyl phenyl ether
ND
ug
56)
Hexachlorobenzene
ND
ug
57)
Pentachlorophenol
ND
ug
58)
Phenanthrene
17.01
ug
59)
Anthracene
19.96
ug
60)
Carbazole
1.01
ug
61)
Di-n-butyl phthalate
12.38
ug
62)
Fluoranthene
ND
ug
63)
Pyrene
ND
ug
64)
Benzyl butyl phthalate
ND
ug
65)
Bis(2-ethylhexyl)adipate
ND
ug
66)
Benz[a]anthracene
ND
ug
67)
Chrysene
ND
ug
68)
Bis(2-ethylhexyl) phthalate
15.45
ug
69)
Di-n-octyl phthalate
ND
ug
70)
Benzo[b]fluoranthene
ND
ug
71)
Benzo[k]fluoranthene
ND
ug
72)
Benzo[a]pyrene
ND
ug
73)
lndeno[1,2,3-cd]pyrene
ND
ug
74)
Dibenz[a,h]anthracene
ND
ug
75)
Benzo[ghi]perylene
ND
ug
Arcadis08-139_166.doc/als
Page 30 of 68
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Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
C:\MSDChem\l\DATA\01_04_08\
08166-02.D
6 Aug 20 08 9:54 am
amg
08-166-02 Run#I M0010-02
luL; 5mL MeC12
1 Sample Multiplier: 5
Quant Method : C:\MSDCHEM\1\METHODS\8270C_2.M
Quant Title : 8270C SVOCs
TIC Library : C:\DATABASE\NIST12 9K.L
TIC Integration Parameters: rteint.p
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 1 Furfural $$ 2-Furancarboxal... Concentration Rank 7
R.T. EstConc	Area	Relative to ISTD	R.T.
2.99 125.14 ug
250269
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Furfural $$ 2-Furancarboxaldehyd... 96 C5H402	000098-01-1 83
2	2H-Pyran-2-one $$ .alpha.-Pyrone... 96 C5H402	000504-31-4 78
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 2 Benzene, 1,2-dimethyl-	Concentration Rank 4
R.T. EstConc	Area	Relative to ISTD	R.T.
3.19 290.26 ug
580528
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzene, 1,2-dimethyl-	106 C8H10	000095-47-6 14
2	Ethylbenzene $$ Benzene, ethyl- ... 106 C8H10	000100-41-4 11
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 3 Benzene, 1,3-dimethyl-	Concentration Rank 3
R.T. EstConc	Area	Relative to ISTD	R.T.
3.26 295.54 ug
591087
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzene, 1,3-dimethyl-	106 C8H10	000108-38-3 86
2	Benzene, 1,3-dimethyl-	106 C8H10	000108-38-3 50
Arcadis08-139_166.doc/als
Page 31 of 68
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Web Site: www.rtp-labs.com
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 4 1,3,5,7-Cyclooctatetraene	Concentration Rank 13
R.T. EstConc	Area	Relative to ISTD	R.T.
CO
81.
8 2 ug
163646
External
Standard
o
o
o
Hit# of
2
Tentative
ID
MW
MolForm
CAS#
Qual
1	1,3,5,7-Cyclooctatetraene	104 C8H8	000629-20-9 90
2	Styrene	104 C8H8	000100-42-5 87
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 5 Ethyl 2-[3-(2,4-difluorophe... Concentration Rank 1
R.T. EstConc	Area	Relative to ISTD	R.T.
3.67 36216.10 ug	72432100 External Standard	0.00
Hit# of 2 Tentative ID	MW MolForm	CAS#	Qual
1	Ethyl 2-[3-(2,4-difluorophenyl)u.. . 326 C12H11F5N203 000000-00-0 38
2	Quinoline	129 C9H7N	000091-22-5 38
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 6 1-Nonene $$ n-Non-l-ene $$ ... Concentration Rank 17
R.T. EstConc	Area	Relative to ISTD	R.T.
3 .74
67.00 ug
133992
External
Standard
0.00
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1-Nonene $$ n-Non-l-ene $$ 1-C9H... 126 C9H18	000124-11-8 52
2	cis-2-Nonene	126 C9H18	006434-77-1 49
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 7 D-Limonene $$ Cyclohexene, ... Concentration Rank 15
R.T. EstConc	Area	Relative to ISTD	R.T.
3 .87
7 9.54 ug
159073
External
Standard
0.00
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	D-Limonene $$ Cyclohexene, 1-met... 136 C10H16	005989-27-5 32
2	Cyclohexene, l-methyl-5-(1-methy... 136 C10H16	013898-73-2 23
Arcadis08-139_166.doc/als
Page 32 of 68
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NELAP Accredited NJ #NC003
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Peak Number 8 Benzaldehyde
R.T. EstConc	Area
Concentration Rank 10
Relative to ISTD	R.T.
4 .17
91.14 ug
182281
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde
2	Benzaldehyde
106 C7H60
106 C7H60
000100-52-7 95
000100-52-7 94
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 9 Benzofuran	Concentration Rank 2
R.T .
EstConc
Area
Relative to ISTD
R.T .
4.44 470.93 ug
941869
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzofuran
2	Benzofuran
118 C8H60
118 C8H60
000271-89-6 46
000271-89-6 37
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 10 Carbamothioic acid, [[(3-me... Concentration Rank 16
R.T .
EstConc
Area
Relative to ISTD
R.T .
5 . 02
71.21 ug
142417
External
Standard
0.00
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Carbamothioic acid, [[(3-methylb... 266 C12H14N203S
2	4,5-Dihydro-4-(2-nitrobenzyliden... 308 C17H12N204
074793-43-4 14
000000-00-0 12
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 11 Bicyclo[2.2.1]heptan-2-ol, ... Concentration Rank 8
R.T .
EstConc
Area
Relative to ISTD
R.T .
5.17 110.07 ug
220144
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Bicyclo[2.2.1]heptan-2-ol, 2-(l-.
2	cis-Chlordane $$ 4,7-Methano-lH-.
178 C12H180
406 C10H6C18
107082-01-9 25
005103-71-9 17
Arcadis08-139_166.doc/als
Page 33 of 68
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919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 12 Cyclopentasiloxane, decamet...	Concentration Rank 11
R.T. EstConc Area Relative	to ISTD R.T.
5.51
8 8.08 ug
176169
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Cyclopentasiloxane, decamethyl-	370 C10H3005Si5 000541-02-6 72
2	Phenethylamine, N-methyl-.beta.,... 399 C18H37N03Si3 010538-85-9 43
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 13 Benzaldehyde, ethenyl- $$ V... Concentration Rank 14
R.T. EstConc	Area	Relative to ISTD	R.T.
5 .99
80.17 ug
160330
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde, ethenyl- $$ Vinylb... 132 C9H80	043145-54-6 37
2	Cinnamaldehyde, (E)-	132 C9H80	014371-10-9 14
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 14 2-Propenoyl chloride $$ Acr... Concentration Rank 18
R.T. EstConc	Area	Relative to ISTD	R.T.
6.21
56 .
8 4 ug
113682
External
Standard
o
o
o
Hit# of
2
Tentative
ID
MW
MolForm
CAS#
Qual
1	2-Propenoyl chloride $$ Acryloyl... 90 C3H3C10	000814-68-6 32
2	5-Nitro-2-furaldoxime $$ 2-Furan... 156 C5H4N204	000555-15-7 27
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 15 3-Ethylenimino-acrylonitrile Concentration Rank 20
R.T. EstConc	Area	Relative to ISTD	R.T.
7 . 43
55 .
85 ug
111706
External
Standard
o
o
o
Hit# of
2
Tentative
ID
MW
MolForm
CAS#
Qual
1	3-Ethylenimino-acrylonitrile	94 C5H6N2	000000-00-0 36
2	Acetic acid, 1-cyano-l-(1-cyclop... 193 C10H11NO3	000000-00-0 34
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Arcadis08-139_166.doc/als
Page 34 of 68
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• I^aI	NELAP Accredited NJ#NC003
919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
Peak Number 16 Imidazo[4,5-e]-1,4-diazepin...	Concentration Rank 9
R.T. EstConc	Area	Relative to ISTD	R.T.
8.93 102.52 ug
205046
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Imidazo[4,5-e]-1,4-diazepin-8-on... 180 C8H12N40	000000-00-0 49
2	3-Pyridinecarboxylic acid, trime... 195 C9H13N02Si	025436-37-7 47
Peak Number 17 1,3-Dicyclohexyl-2-(4-oxo-p... Concentration Rank 19
R.T. EstConc	Area	Relative to ISTD	R.T.
CO
CO
i
5 6.59 ug
113177
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1,3-Dicyclohexyl-2-(4-oxo-pentan... 322 C18H30N2O3	000000-00-0 25
2	Spiro[1,3-dioxolane-2,11 (21H)-na.. . 226 C13H2203	073284-93-2 25
Peak Number 18 Nickel, cyclopentadienyl-(d... Concentration Rank 6
R.T. EstConc	Area	Relative to ISTD	R.T.
9.37 185.76 ug
371517
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Nickel, cyclopentadienyl-(dimeth... 257 C14H17NNi	000000-00-0 53
2	Naphthalene, decahydro-1,1,4a-tr... 272 C20H32	005957-33-5 45
Peak Number 19 Indoxazene, 3-ethyl-	Concentration Rank 12
R.T. EstConc	Area	Relative to ISTD	R.T.
9 .70
8 6.23 ug
172455
External
Standard
0.00
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Indoxazene, 3-ethyl-	147 C9H9NO	000000-00-0 27
2	1H-1,5-Benzodiazepine, 2,3,4,5-t... 148 C9H12N2	006516-89-8 27
Peak Number 20 Naphtho[2,1-f]quinolin-2(1H... Concentration Rank 5
Arcadis08-139_166.doc/als
Page 35 of 68
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tTlxai
NELAP Accredited NJ #NC003
R . T . EstConc
Area
Relative to ISTD
R.T .
10 .21 260.21 ug
520411
External Standard
o
o
o
Hit# of 2 Tentative
ID
MW Mo1Form
CAS#
Qual
1	Naphtho[2,1-f]quinolin-2(1H)-one... 275 C18H29NO
2	lH-Naphtho[2,1-b]pyran, 3-etheny... 290 C20H34O
021171-75-5 38
000596-84-9 32
Arcadis08-139_166.doc/als
Page 36 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Methods 8270 Semivolatiles by GC/MS
Data File Name:
Data File Path:
Operator:
Date Acquired:
Acq. Method File:
Misc Info:
Vial Number:
Instrument Name:
Sample Multiplier:
# Compound Name
1)	Pyridine
2)	N-Nitrosodimethylamine
3)	Phenol
4)	Aniline
5)	s-Dichloroethyl ether
6)	2-Chlorophenol
7)	1,3-Dichlorobenzene
8)	1,4-Dichlorobenzene
9)	Benzyl Alcohol
10)	1,2-Dichlorobenzene
11)	2-Methylphenol
12)	Bis(2-chloroisopropyl)ether
13)	3 & 4-Methylphenol
14)	N-nitroso-di-n-propylamine
15)	Hexachloroethane
16)	Nitrobenzene
17)	Isophorone
18)	2-Nitrophenol
19)	2,4-Dimethylphenol
20)	Bis(2-chloroethoxy)methane
21)	2,4-Dichlorophenol
22)	1,2,4-Trichlorobenzene
23)	Naphthalene
24)	p-Chloroaniline
25)	Hexachloro-1,3-butadiene
26)	4-Chloro-3-methylphenol
27)	2-Methylnaphthalene
28)	1-Methylnaphthalene
29)	Hexachlorocyclopentadiene
30)	2,4,6-Trichlorophenol
08166-03.D
C:\MSDChem\1\DATA\01_04_08\
amg
8/6/2008 10:50
8270C_2.M
08-166-03 Run#l M0010-03
1uL; 5mLMeCI2
1
GCMS#3
HP6890_5973
5
Units
Amount Total/Sample
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
67.59
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
88.99
ug
ND
ug
ND
ug
ND
ug
1.09
ug
449.76
ug
ND
ug
ND
ug
ND
ug
53.01
ug
12.43
ug
ND
ug
ND
ug
Arcadis08-139_166.doc/als
Page 37 of 68
-------
Jh Triangle Pf
7201 ACC Blvd., Suite 104
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919 510-0141 Fax
rk LaTborattories, I:
mc.
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NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
31)
2,4,5-T richlorophenol
ND
ug
32)
2-Chloronaphthalene
1.09
ug
33)
2-Nitroaniline
3.74
ug
34)
1,4-Dinitrobenzene
ND
ug
35)
Dimethyl phthalate
ND
ug
36)
1,3-Dinitrobezene
9.49
ug
37)
Acenaphthylene
14.75
ug
38)
2,6-Dinitrotoluene
ND
ug
39)
1,2-Dinitrobenzene
ND
ug
40)
3-Nitroaniline
ND
ug
41)
Acenaphthene
ND
ug
42)
2,4-Dinitrophenol
ND
ug
43)
4-Nitrophenol
ND
ug
44)
Dibenzofuran
27.05
ug
45)
2,4-Dinitrotoluene
ND
ug
46)
2,3,4,6-Tetrachlorophenol
ND
ug
47)
2,3,5,6-Tetrachlorophenol
ND
ug
48)
Diethylphthalate
9.77
ug
49)
4-Chlorophenyl phenyl ether
ND
ug
50)
Fluorene
4.28
ug
51)
4-Nitroaniline
ND
ug
52)
4,6-Dinitro-2-methylphenol
ND
ug
53)
Diphenylamine
ND
ug
54)
Azobenzene
ND
ug
55)
4-Bromophenyl phenyl ether
ND
ug
56)
Hexachlorobenzene
ND
ug
57)
Pentachlorophenol
ND
ug
58)
Phenanthrene
77.50
ug
59)
Anthracene
85.55
ug
60)
Carbazole
ND
ug
61)
Di-n-butyl phthalate
12.88
ug
62)
Fluoranthene
40.61
ug
63)
Pyrene
32.82
ug
64)
Benzyl butyl phthalate
ND
ug
65)
Bis(2-ethylhexyl)adipate
ND
ug
66)
Benz[a]anthracene
ND
ug
67)
Chrysene
ND
ug
68)
Bis(2-ethylhexyl) phthalate
17.67
ug
69)
Di-n-octyl phthalate
ND
ug
70)
Benzo[b]fluoranthene
ND
ug
71)
Benzo[k]fluoranthene
ND
ug
72)
Benzo[a]pyrene
ND
ug
73)
lndeno[1,2,3-cd]pyrene
ND
ug
74)
Dibenz[a,h]anthracene
ND
ug
75)
Benzo[ghi]perylene
ND
ug
Arcadis08-139_166.doc/als
Page 38 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
C:\MSDChem\l\DATA\01_04_08\
08166-03.D
6 Aug 2008 10:50 am
amg
08-166-03 Run#I M0010-03
luL; 5mL MeC12
1 Sample Multiplier: 5
Quant Method : C:\MSDCHEM\1\METHODS\8270C_2.M
Quant Title : 8270C SVOCs
TIC Library : C:\DATABASE\NIST12 9K.L
TIC Integration Parameters: rteint.p
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 1 Octane, 2-methyl-	Concentration Rank 8
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.19 160.97 ug
321946
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Octane, 2-methyl-
2	Octane, 3-ethyl-2,7-dimethyl-
128 C9H20
170 C12H26
003221-61-2 53
062183-55-5 50
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 2 5-Hexen-3-one	Concentration Rank 7
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.26 175.37 ug
350739
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	5-Hexen-3-one
2	Oxirane, (chloromethyl)
98 C6H10O
92 C3H5C10
024253-30-3 25
000106-89-8 12
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Concentration Rank 1
Relative to ISTD	R.T.
Peak Number 3 3-Hexene, (Z)-
R.T. EstConc	Area
3.66 285948.00 ug	571896000 External Standard
Hit# of 2 Tentative ID	MW MolForm
0 .00
CAS#	Qual
1	3-Hexene, (Z)-	84 C6H12
2	Cyclopropane, 1,2-dimethyl-, tra... 70 C5H10
007642-09-3 46
002402-06-4 43
Arcadis08-139_166.doc/als
Page 39 of 68
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Researcli Triangle Park Laboratories, Inc.	/|
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919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
Peak Number 4 Benzaldehyde	Concentration Rank 4
R.T. EstConc	Area	Relative to ISTD	R.T.
4.19 261.06 ug
522119
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde	106 C7H60	000100-52-7 78
2	Benzaldehyde	106 C7H60	000100-52-7 49
Peak Number 5 Cyclotetrasiloxane, octamet... Concentration Rank 2
R.T. EstConc	Area	Relative to ISTD	R.T.
4.43 396.62 ug
793234
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Cyclotetrasiloxane, octamethyl-	296 C8H2404Si4	000556-67-2 41
2	Cyclotetrasiloxane, octamethyl- ... 296 C8H2404Si4	000556-67-2 38
Peak Number 6 Chloroacetic acid,	1-methyl... Concentration Rank 6
R.T. EstConc Area Relative to ISTD	R.T.
4.99 205.82 ug	411647	External Standard	0.00
Hit# of 2 Tentative ID	MW MolForm	CAS#	Qual
1	Chloroacetic acid, 1-methyl ester 136 C5H9C102	000000-00-0 32
2	Ethyl 2-(2-chloroacetamido)-3,3,... 305 C10H15C1F3NO4 000000-00-0 32
Peak Number 7 Cyclopentasiloxane, decamet... Concentration Rank 12
R.T. EstConc	Area	Relative to ISTD	R.T.
5.51 101.
8 6 ug
203729
External
Standard
o
o
o
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Cyclopentasiloxane, decamethyl-	370 C10H3005Si5 000541-02-6 83
2	Cyclopentasiloxane, decamethyl-	370 C10H30Q5Si5 000541-02-6 50
Arcadis08-139_166.doc/als
Page 40 of 68
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Researcli Triangle Park Laboratories, Inc.	/|
7201 ACCBlvd., Suite 104 *""	I|Tm¥ oVn
Raleigh, NC 27617 ¦	** ' A
• I^aI	NELAP Accredited NJ#NC003
919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 8 Cyclobutaneoctol $$ Octahyd...	Concentration Rank 3
R.T. EstConc Area Relative	to ISTD R.T.
6.00 306.54 ug
613084
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Cyclobutaneoctol $$ Octahydroxyc... 184 C4H808	020389-20-2 32
2	Glycyl-dl-alanine $$ Glycyl-dl-a... 146 C5H10N2O3	000926-77-2 9
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 9 1-Butanol, 3-methyl-, nitrate Concentration Rank 10
R.T. EstConc	Area	Relative to ISTD	R.T.
6.09 140.91 ug
281816
External Standard
O 1
O 1
O 1

Hit# of 2 Tentative
ID
MW MolForm
CAS#
Qual
1 1-Butanol, 3-methyl-,
nitrate
133 C5H11N03
000543-87-3
25
2 2-Pentanol, nitrate $$
n-C3H7CH(
. . . 133 C5H11N03
021981-48-6
9
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk

Peak Number 10 1-Butanol
, 3-methyl
-, nitra... Concentration Rank 5

R.T. EstConc
Area
Relative to ISTD
R.T .

6.20 232.25 ug
464496
External Standard
o
o
o

Hit# of 2 Tentative
ID
MW MolForm
CAS#
Qual
1	1-Butanol, 3-methyl-, nitrate $$... 133 C5H11N03	000543-87-3 43
2	1-Propanol, 2,2-dimethyl-, nitra... 133 C5H11N03	000926-42-1 40
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 11 Benzocycloheptatriene	Concentration Rank 14
R.T. EstConc	Area	Relative to ISTD	R.T.
6.53
93.53 ug
187057
External
Standard
0.00
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzocycloheptatriene	142 C11H10	000264-09-5 72
2	Naphthalene, 2-methyl-	142 C11H10	000091-57-6 64
Arcadis08-139_166.doc/als
Page 41 of 68
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Web Site: www.rtp-labs.com
Peak Number 12 Acetic acid, chloro-	Concentration Rank 15
R.T .
EstConc
Area
Relative to ISTD
R.T .
6.91 88.
8 0 ug
177602
External
Standard
o
o
o
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Acetic acid, chloro-
2	Acetic acid, chloro-
94 C2H3C102
94 C2H3C102
000079-11-8 38
000079-11-8 38

Peak Number 13 Acenaphthenone
R.T. EstConc	Area
Concentration Rank 11
Relative to ISTD	R.T.
8.33 102.
87 ug
205742
External
Standard
0.00
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Acenaphthenone	168 C12H80
2	Benzenaldehyde, 2-fluoro-5-hydroxy- 140 C7H5F02
000000-00-0 90
000000-00-0 58
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 14 9H-Fluoren-9-one
R.T. EstConc	Area
Concentration Rank 9
Relative to ISTD	R.T.
8.69 144.29 ug
288576
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	9H-Fluoren-9-one
2	9H-Fluoren-9-one
180 C13H80
180 C13H80
000486-25-9 83
000486-25-9 80
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 15 Phenol, 4-(2-thienylmethyl)- Concentration Rank 13
R.T .
EstConc
Area
Relative to ISTD
R.T .
9 . 43
93 . 8
8 ug
187761
External
Standard
o
o
o
Hit# of
2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Phenol, 4-(2-thienylmethyl)-
2	5-[3-Chlorophenyl]tetraazole
190 C11H10OS
180 C7H5C1N4
091680-55-6 35
041421-28-7 30
Arcadis08-139_166.doc/als
Page 42 of 68
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Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Methods 8270 Semivolatiles by GC/MS
Data File Name:
Data File Path:
Operator:
Date Acquired:
Acq. Method File:
Misc Info:
Vial Number:
Instrument Name:
Sample Multiplier:
# Compound Name
1)	Pyridine
2)	N-Nitrosodimethylamine
3)	Phenol
4)	Aniline
5)	s-Dichloroethyl ether
6)	2-Chlorophenol
7)	1,3-Dichlorobenzene
8)	1,4-Dichlorobenzene
9)	Benzyl Alcohol
10)	1,2-Dichlorobenzene
11)	2-Methylphenol
12)	Bis(2-chloroisopropyl)ether
13)	3 & 4-Methylphenol
14)	N-nitroso-di-n-propylamine
15)	Hexachloroethane
16)	Nitrobenzene
17)	Isophorone
18)	2-Nitrophenol
19)	2,4-Dimethylphenol
20)	Bis(2-chloroethoxy)methane
21)	2,4-Dichlorophenol
22)	1,2,4-Trichlorobenzene
23)	Naphthalene
24)	p-Chloroaniline
25)	Hexachloro-1,3-butadiene
26)	4-Chloro-3-methylphenol
27)	2-Methylnaphthalene
28)	1-Methylnaphthalene
29)	Hexachlorocyclopentadiene
30)	2,4,6-Trichlorophenol
08166-04.D
C:\MSDChem\1\DATA\01_04_08\
amg
8/6/2008 11:55
8270C_2.M
08-166-04 run#ll M0010-01
1uL; 5mLMeCI2
1
GCMS#3
HP6890_5973
5
Units
Amount Total/Sample
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
127.03
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
61.00
ug
ND
ug
ND
ug
58.13
ug
ND
ug
78.48
ug
18.39
ug
ND
ug
ND
ug
ND
ug
425.32
ug
ND
ug
ND
ug
ND
ug
86.29
ug
32.91
ug
ND
ug
ND
ug
Arcadis08-139_166.doc/als
Page 43 of 68
-------
Jh Triangle Pf
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
rk LaTborattories, I:
mc.
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
31)
2,4,5-T richlorophenol
ND
ug
32)
2-Chloronaphthalene
ND
ug
33)
2-Nitroaniline
ND
ug
34)
1,4-Dinitrobenzene
ND
ug
35)
Dimethyl phthalate
ND
ug
36)
1,3-Dinitrobezene
56.22
ug
37)
Acenaphthylene
71.11
ug
38)
2,6-Dinitrotoluene
ND
ug
39)
1,2-Dinitrobenzene
ND
ug
40)
3-Nitroaniline
ND
ug
41)
Acenaphthene
ND
ug
42)
2,4-Dinitrophenol
ND
ug
43)
4-Nitrophenol
ND
ug
44)
Dibenzofuran
43.35
ug
45)
2,4-Dinitrotoluene
ND
ug
46)
2,3,4,6-Tetrachlorophenol
ND
ug
47)
2,3,5,6-Tetrachlorophenol
ND
ug
48)
Diethylphthalate
ND
ug
49)
4-Chlorophenyl phenyl ether
ND
ug
50)
Fluorene
13.49
ug
51)
4-Nitroaniline
ND
ug
52)
4,6-Dinitro-2-methylphenol
ND
ug
53)
Diphenylamine
ND
ug
54)
Azobenzene
ND
ug
55)
4-Bromophenyl phenyl ether
ND
ug
56)
Hexachlorobenzene
ND
ug
57)
Pentachlorophenol
ND
ug
58)
Phenanthrene
117.39
ug
59)
Anthracene
129.57
ug
60)
Carbazole
1.80
ug
61)
Di-n-butyl phthalate
26.75
ug
62)
Fluoranthene
53.09
ug
63)
Pyrene
48.16
ug
64)
Benzyl butyl phthalate
6.53
ug
65)
Bis(2-ethylhexyl)adipate
ND
ug
66)
Benz[a]anthracene
ND
ug
67)
Chrysene
ND
ug
68)
Bis(2-ethylhexyl) phthalate
50.16
ug
69)
Di-n-octyl phthalate
ND
ug
70)
Benzo[b]fluoranthene
ND
ug
71)
Benzo[k]fluoranthene
ND
ug
72)
Benzo[a]pyrene
ND
ug
73)
lndeno[1,2,3-cd]pyrene
ND
ug
74)
Dibenz[a,h]anthracene
ND
ug
75)
Benzo[ghi]perylene
ND
ug
Arcadis08-139_166.doc/als
Page 44 of 68
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Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
C:\MSDChem\l\DATA\01_04_08\
08166-04.D
6 Aug 2008 11:55 am
amg
08-166-04 run#II M0010-01
luL; 5mL MeC12
1 Sample Multiplier: 5
Quant Method : C:\MSDCHEM\1\METHODS\8270C_2.M
Quant Title : 8270C SVOCs
TIC Library : C:\DATABASE\NIST12 9K.L
TIC Integration Parameters: rteint.p
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 1 1-Pyrrolidinecarbonitrile $... Concentration Rank 12
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.47 1!
3 2.54 ug
365087
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1-Pyrrolidinecarbonitrile $$ N-C... 96 C5H8N2
2	4-Cyclopentene-l,3-dione	96 C5H402
001530-88-7 43
000930-60-9 38
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 2 Nonane	Concentration Rank 1
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.54 2E
3 2 9.43 ug
5658860
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Nonane
2	Nonane
128 C9H20
128 C9H20
000111-84-2 83
000111-84-2 83
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 3 Benzaldehyde
R.T. EstConc	Area
Concentration Rank 3
Relative to ISTD	R.T.
4 .14 478.45 ug
956907
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde
2	Benzaldehyde
106 C7H60
106 C7H60
000100-52-7 95
000100-52-7 94
Arcadis08-139_166.doc/als
Page 45 of 68
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Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 4 4-Methyl-2-oxo-(1H)-pyrimidine Concentration Rank 10
R.T. EstConc	Area	Relative to ISTD	R.T.
4.30 200.78
ug
401565
External
Standard
o
o
o
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	4-Methyl-2-oxo-(1H)-pyrimidine
2	1-Propyne, 3-bromo-
110 C5H6N20
118 C3H3Br
015231-48-8 87
000106-96-7 64
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 5 Benzaldehyde, 2-hydroxy- $$... Concentration Rank 2
R.T .
EstConc
Area
Relative to ISTD
R.T .
4 . 7E
i 663.25 ug
1326500
External
Standard
0.00
Hit#
of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde, 2-hydroxy- $$ Sali... 122 C7H602
2	Benzaldehyde, 2-hydroxy-	122 C7H602
000090-02-8 46
000090-02-8 38
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 6 1,3,5,7-Cyclooctatetraene	Concentration Rank 4
R.T .
EstConc
Area
Relative to ISTD
R.T .
5.96 475.56 ug
951125
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1,3,5,7-Cyclooctatetraene
2	1,3,5,7-Cyclooctatetraene
104 C8H8
104 C8H8
000629-20-9 94
000629-20-9 93
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 7 Benzoic acid, 2-nitro-	Concentration Rank 7
R.T .
EstConc
Area
Relative to ISTD
R.T .
6.71 323.58 ug
647170
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzoic acid, 2-nitro-
2	Benzoic acid, 2-nitro- $$ Benzoi..
167 C7H5N04
167 C7H5N04
000552-16-9 72
000552-16-9 59
Arcadis08-139_166.doc/als
Page 46 of 68
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Raleigh, NC 27617
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919 510-0141 Fax
nel c
tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Peak Number 8 7-Quinolinol	Concentration Rank 8
R.T .
EstConc
Area
Relative to ISTD
R.T .
6.75 265.02 ug
530034
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	7-Quinolinol
2	lH-Pyrrolo[2,3-b]pyridine, 2-eth..
145	C9H7NO
146	C9H10N2
000580-20-1 38
023612-49-9 38
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 9 Naphthalene, 2-ethenyl-	Concentration Rank 6
R.T. EstConc	Area	Relative to ISTD	R.T.
6.87 425.42 ug
850837
External Standard
O 1
O 1
O 1
Hit# of 2 Tentative
ID
MW MolForm
CAS# Qual
1 Naphthalene, 2-ethenyl
-
154 C12H10
000827-54-3 93
2 Biphenyl

154 C12H10
000092-52-4 90
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 10 Vanillin

Concentration Rank 5
R.T. EstConc
Area
Relative to ISTD
R.T .
7.02 460.69 ug
921388
External Standard
0.00
Hit# of 2 Tentative
ID
MW MolForm
CAS# Qual
1	Vanillin	152 C8H803
2	Vanillin $$ Benzaldehyde, 4-hydr... 152 C8H803
000121-33-5 76
000121-33-5 76
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 11 Acenaphthenone	Concentration Rank 9
R.T .
EstConc
Area
Relative to ISTD
R.T .
8 .29 245.76 ug
491526
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Acenaphthenone
2	1H-Inden-1-one, 4,7-difluoro-2,3..
168 C12H80
168 C9H6F20
000000-00-0 76
130408-16-1 53
Arcadis08-139_166.doc/als
Page 47 of 68
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Raleigh, NC 27617
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919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Peak Number 12 9H-Fluoren-9-one	Concentration Rank 11
R.T .
EstConc
Area
Relative to ISTD
R.T .
8.66 198.80 ug	397593
Hit# of 2 Tentative ID
External Standard
MW Mo1Form
0 .00
CAS#
Qual
1	9H-Fluoren-9-one
2	9H-Fluoren-9-one
180 C13H80
180 C13H80
000486-25-9 91
000486-25-9 83
Arcadis08-139_166.doc/als
Page 48 of 68
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Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Methods 8270 Semivolatiles by GC/MS
Data File Name:
Data File Path:
Operator:
Date Acquired:
Acq. Method File:
Misc Info:
Vial Number:
Instrument Name:
Sample Multiplier:
# Compound Name
1)	Pyridine
2)	N-Nitrosodimethylamine
3)	Phenol
4)	Aniline
5)	s-Dichloroethyl ether
6)	2-Chlorophenol
7)	1,3-Dichlorobenzene
8)	1,4-Dichlorobenzene
9)	Benzyl Alcohol
10)	1,2-Dichlorobenzene
11)	2-Methylphenol
12)	Bis(2-chloroisopropyl)ether
13)	3 & 4-Methylphenol
14)	N-nitroso-di-n-propylamine
15)	Hexachloroethane
16)	Nitrobenzene
17)	Isophorone
18)	2-Nitrophenol
19)	2,4-Dimethylphenol
20)	Bis(2-chloroethoxy)methane
21)	2,4-Dichlorophenol
22)	1,2,4-Trichlorobenzene
23)	Naphthalene
24)	p-Chloroaniline
25)	Hexachloro-1,3-butadiene
26)	4-Chloro-3-methylphenol
27)	2-Methylnaphthalene
28)	1-Methylnaphthalene
29)	Hexachlorocyclopentadiene
30)	2,4,6-Trichlorophenol
08166-05.D
C:\MSDChem\1\DATA\01_04_08\
amg
8/6/2008 12:36
8270C_2.M
08-166-05 Run #ll M0010-02
1uL; 5mLMeCI2
1
GCMS#3
HP6890_5973
5
Units
Amount Total/Sample
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
237.32
ug
11.12
ug
10.49
ug
135.45
ug
ND
ug
227.86
ug
ND
ug
392.71
ug
ND
ug
ND
ug
709.04
ug
ND
ug
113.17
ug
93.52
ug
68.45
ug
118.87
ug
ND
ug
1073.46
ug
ND
ug
ND
ug
ND
ug
164.99
ug
ND
ug
ND
ug
ND
ug
Arcadis08-139_166.doc/als
Page 49 of 68
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Jh Triangle Pf
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
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919 510-0141 Fax
rk LaTborattories, I:
mc.
nel c
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Web Site: www.rtp-labs.com
31)
2,4,5-T richlorophenol
ND
ug
32)
2-Chloronaphthalene
ND
ug
33)
2-Nitroaniline
87.87
ug
34)
1,4-Dinitrobenzene
ND
ug
35)
Dimethyl phthalate
7.07
ug
36)
1,3-Dinitrobezene
142.91
ug
37)
Acenaphthylene
173.04
ug
38)
2,6-Dinitrotoluene
ND
ug
39)
1,2-Dinitrobenzene
ND
ug
40)
3-Nitroaniline
ND
ug
41)
Acenaphthene
15.94
ug
42)
2,4-Dinitrophenol
ND
ug
43)
4-Nitrophenol
194.64
ug
44)
Dibenzofuran
122.99
ug
45)
2,4-Dinitrotoluene
ND
ug
46)
2,3,4,6-Tetrachlorophenol
ND
ug
47)
2,3,5,6-Tetrachlorophenol
ND
ug
48)
Diethylphthalate
6.90
ug
49)
4-Chlorophenyl phenyl ether
ND
ug
50)
Fluorene
55.01
ug
51)
4-Nitroaniline
ND
ug
52)
4,6-Dinitro-2-methylphenol
ND
ug
53)
Diphenylamine
ND
ug
54)
Azobenzene
4.62
ug
55)
4-Bromophenyl phenyl ether
ND
ug
56)
Hexachlorobenzene
ND
ug
57)
Pentachlorophenol
ND
ug
58)
Phenanthrene
342.50
ug
59)
Anthracene
325.18
ug
60)
Carbazole
7.21
ug
61)
Di-n-butyl phthalate
ND
ug
62)
Fluoranthene
102.71
ug
63)
Pyrene
88.46
ug
64)
Benzyl butyl phthalate
ND
ug
65)
Bis(2-ethylhexyl)adipate
ND
ug
66)
Benz[a]anthracene
26.40
ug
67)
Chrysene
98.35
ug
68)
Bis(2-ethylhexyl) phthalate
860.81
ug
69)
Di-n-octyl phthalate
ND
ug
70)
Benzo[b]fluoranthene
ND
ug
71)
Benzo[k]fluoranthene
ND
ug
72)
Benzo[a]pyrene
ND
ug
73)
lndeno[1,2,3-cd]pyrene
ND
ug
74)
Dibenz[a,h]anthracene
2.06
ug
75)
Benzo[ghi]perylene
ND
ug
Arcadis08-139_166.doc/als
Page 50 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
C:\MSDChem\l\DATA\01_04_08\
08166-05.D
6 Aug 2008 12:36 pm
amg
08-166-05 Run #11 M0010-02
luL; 5mL MeC12
1 Sample Multiplier: 5
Quant Method : C:\MSDCHEM\1\METHODS\8270C_2.M
Quant Title : 8270C SVOCs
TIC Library : C:\DATABASE\NIST12 9K.L
TIC Integration Parameters: rteint.p
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 1 Furfural $$ 2-Furancarboxal... Concentration Rank 2
R.T. EstConc	Area	Relative to ISTD
2.93 11199.00 ug	22398000 External Standard
Hit# of 2 Tentative ID	MW MolForm
R.T .
0.00
CAS#	Qual
1	Furfural $$ 2-Furancarboxaldehyd... 96 C5H402
2	Furfural	96 C5H402
000098-01-1 96
000098-01-1 95
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 2 Ethylbenzene	Concentration Rank 11
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.17 1167.67 ug
2335340
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Ethylbenzene
2	Ethylbenzene
106 C8H10
106 C8H10
000100-41-4 70
000100-41-4 70
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 3 Benzene, 1,2-dimethyl-	Concentration Rank 10
R.T. EstConc	Area	Relative to ISTD	R.T.
3.26 1213.
8 6 ug
2427730
External
Standard
o
o
o
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzene, 1,2-dimethyl-
2	p-Xylene
106 C8H10
106 C8H10
000095-47-6 95
000106-42-3 95
Arcadis08-139_166.doc/als
Page 51 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
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nel c
tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 4 1,3,5,7-Cyclooctatetraene	Concentration Rank 4
R.T. EstConc	Area	Relative to ISTD	R.T.
3.49 5341.14 ug 10682300
External
Standard
o
o
o
Hit# of 2 Tentative ID
MW
MolForm
CAS#
Qual
1	1,3,5,7-Cyclooctatetraene
2	Styrene
104 C8H8
104 C8H8
000629-20-9 97
000100-42-5 97
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 5 2H-Pyran-2-one, 6-ethyltetr... Concentration Rank 1
R.T. EstConc	Area	Relative to ISTD
3.68 324111.00 ug	648222000 External Standard
Hit# of 2 Tentative ID	MW MolForm
R.T .
0 .00
CAS#	Qual
1	2H-Pyran-2-one, 6-ethyltetrahydr... 128 C7H1202
2	Cyclopropane, l-ethyl-2-methyl-,... 84 C6H12
003301-90-4 52
019781-68-1 47
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 6 Bicyclo[3.1.1]hept-2-ene, 2... Concentration Rank 6
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.87 23!
3 9.31 ug
4778620
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Bicyclo[3.1.1]hept-2-ene, 2,6,6-... 136 C10H16
2	(1R)-2,6,6-Trimethylbicyclo[3.1.... 136 C10H16
002437-95-8 97
007785-70-8 96
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 7 Benzaldehyde
R.T. EstConc	Area
Concentration Rank 3
Relative to ISTD	R.T.
4.12 6968.62 ug 13937200
External
Standard
o
o
o
Hit# of 2 Tentative ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde
2	Benzaldehyde
106 C7H60
106 C7H60
000100-52-7 96
000100-52-7 96
Arcadis08-139_166.doc/als
Page 52 of 68
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Researcli Triangle Park Laboratories, Inc.	/|
7201 ACCBlvd., Suite 104 *""	I|Tm¥ oVn
Raleigh, NC 27617 ¦	** ' A
• I^aI	NELAP Accredited NJ#NC003
919 510-0228 Telephone | Id V*
919 510-0141 Fax	Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 8 1-Propyne, 3-bromo-	Concentration Rank 5
R.T. EstConc Area Relative	to ISTD R.T.
4.29 2963.05 ug
5926100
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1-Propyne, 3-bromo-	118 C3H3Br	000106-96-7 53
2	2,5-Furandione, 3-methyl- $$ Cit... 112 C5H403	000616-02-4 47
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 9 1,5-Cyclooctadiene, 1,5-dim... Concentration Rank 7
R.T. EstConc	Area	Relative to ISTD	R.T.
4.65 1670.40 ug
3340800
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1,5-Cyclooctadiene, 1,5-dimethyl- 136 C10H16	003760-14-3 90
2	D-Limonene	136 C10H16	005989-27-5 86
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 10 Propanedinitrile, methylene- Concentration Rank 8
R.T. EstConc	Area	Relative to ISTD	R.T.
5.96 1302.
8 2 ug
2605640
External
Standard
0.00
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Propanedinitrile, methylene-	78 C4H2N2	000922-64-5 64
2	2,4-Hexadiyne	78 C6H6	002809-69-0 52
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 11 Naphthalene, 1-methyl-	Concentration Rank 12
R.T. EstConc	Area	Relative to ISTD	R.T.
6.50 1149.62 ug
2299230
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Naphthalene, 1-methyl-	142 C11H10	000090-12-0 94
2	1,4-Methanonaphthalene, 1,4-dihy... 142 C11H10	004453-90-1 91
Arcadis08-139_166.doc/als
Page 53 of 68
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Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
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nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Peak Number 12 Biphenyl	Concentration Rank 9
R.T .
EstConc
Area
Relative to ISTD
R.T .
6.87 1275.69 ug	2551380 External Standard
Hit# of 2 Tentative ID	MW MolForm
0 .00
CAS#
Qual
1	Biphenyl	154 C12H10
2	Biphenyl $$ 1,1'-Biphenyl $$ Bib... 154 C12H10
000092-52-4 94
000092-52-4 87
Arcadis08-139_166.doc/als
Page 54 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Methods 8270 Semivolatiles by GC/MS
Data File Name:
Data File Path:
Operator:
Date Acquired:
Acq. Method File:
Misc Info:
Vial Number:
Instrument Name:
Sample Multiplier:
# Compound Name
1)	Pyridine
2)	N-Nitrosodimethylamine
3)	Phenol
4)	Aniline
5)	s-Dichloroethyl ether
6)	2-Chlorophenol
7)	1,3-Dichlorobenzene
8)	1,4-Dichlorobenzene
9)	Benzyl Alcohol
10)	1,2-Dichlorobenzene
11)	2-Methylphenol
12)	Bis(2-chloroisopropyl)ether
13)	3 & 4-Methylphenol
14)	N-nitroso-di-n-propylamine
15)	Hexachloroethane
16)	Nitrobenzene
17)	Isophorone
18)	2-Nitrophenol
19)	2,4-Dimethylphenol
20)	Bis(2-chloroethoxy)methane
21)	2,4-Dichlorophenol
22)	1,2,4-Trichlorobenzene
23)	Naphthalene
24)	p-Chloroaniline
25)	Hexachloro-1,3-butadiene
26)	4-Chloro-3-methylphenol
27)	2-Methylnaphthalene
28)	1-Methylnaphthalene
29)	Hexachlorocyclopentadiene
30)	2,4,6-Trichlorophenol
08166-06.D
C:\MSDChem\1\DATA\01_04_08\
amg
8/6/2008 13:16
8270C_2.M
08-166-06 Run#ll M0010-03
1uL; 5mLMeCI2
1
GCMS#3
HP6890_5973
5
Units
Amount Total/Sample
ND
ug
ND
ug
ND
ug
74.76
ug
ND
ug
208.23
ug
14.46
ug
13.65
ug
123.31
ug
12.18
ug
178.24
ug
ND
ug
262.51
ug
ND
ug
ND
ug
461.40
ug
ND
ug
136.36
ug
81.88
ug
ND
ug
130.29
ug
5.74
ug
803.27
ug
ND
ug
ND
ug
83.18
ug
152.73
ug
ND
ug
ND
ug
ND
ug
Arcadis08-139_166.doc/als
Page 55 of 68
-------
Jh Triangle Pf
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
rk LaTborattories, I:
mc.
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
31)
2,4,5-T richlorophenol
ND
ug
32)
2-Chloronaphthalene
4.24
ug
33)
2-Nitroaniline
ND
ug
34)
1,4-Dinitrobenzene
ND
ug
35)
Dimethyl phthalate
ND
ug
36)
1,3-Dinitrobezene
86.53
ug
37)
Acenaphthylene
109.09
ug
38)
2,6-Dinitrotoluene
ND
ug
39)
1,2-Dinitrobenzene
ND
ug
40)
3-Nitroaniline
ND
ug
41)
Acenaphthene
ND
ug
42)
2,4-Dinitrophenol
ND
ug
43)
4-Nitrophenol
161.43
ug
44)
Dibenzofuran
77.43
ug
45)
2,4-Dinitrotoluene
11.85
ug
46)
2,3,4,6-Tetrachlorophenol
25.54
ug
47)
2,3,5,6-Tetrachlorophenol
19.64
ug
48)
Diethylphthalate
ND
ug
49)
4-Chlorophenyl phenyl ether
ND
ug
50)
Fluorene
31.84
ug
51)
4-Nitroaniline
ND
ug
52)
4,6-Dinitro-2-methylphenol
11.97
ug
53)
Diphenylamine
ND
ug
54)
Azobenzene
ND
ug
55)
4-Bromophenyl phenyl ether
ND
ug
56)
Hexachlorobenzene
ND
ug
57)
Pentachlorophenol
ND
ug
58)
Phenanthrene
178.77
ug
59)
Anthracene
185.19
ug
60)
Carbazole
ND
ug
61)
Di-n-butyl phthalate
15.09
ug
62)
Fluoranthene
48.11
ug
63)
Pyrene
39.54
ug
64)
Benzyl butyl phthalate
ND
ug
65)
Bis(2-ethylhexyl)adipate
ND
ug
66)
Benz[a]anthracene
15.65
ug
67)
Chrysene
75.72
ug
68)
Bis(2-ethylhexyl) phthalate
82.65
ug
69)
Di-n-octyl phthalate
4.09
ug
70)
Benzo[b]fluoranthene
ND
ug
71)
Benzo[k]fluoranthene
ND
ug
72)
Benzo[a]pyrene
ND
ug
73)
lndeno[1,2,3-cd]pyrene
ND
ug
74)
Dibenz[a,h]anthracene
ND
ug
75)
Benzo[ghi]perylene
ND
ug
Arcadis08-139_166.doc/als
Page 56 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
C:\MSDChem\l\DATA\01_04_08\
0	8166-0 6.D
6 Aug 20 08 1:16 pm
amg
08-166-06 Run#II M0010-03
luL; 5mL MeC12
1	Sample Multiplier: 5
Quant Method : C:\MSDCHEM\1\METHODS\8270C_2.M
Quant Title : 8270C SVOCs
TIC Library : C:\DATABASE\NIST12 9K.L
TIC Integration Parameters: rteint.p
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 1 Furfural	Concentration Rank 2
R.T .
EstConc
Area
Relative to ISTD
R.T .
2.93 8749.51 ug 17499000
External
Standard
o
o
o
Hit# of 2 Tentative ID
MW
MolForm
CAS#
Qual
1	Furfural	96 C5H402
2	Furfural $$ 2-Furancarboxaldehyd... 96 C5H402
000098-01-1 95
000098-01-1 94
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 2 Ethylbenzene $$ Benzene, et... Concentration Rank 11
R.T .
EstConc
Area
Relative to ISTD
R.T .
3 .If
3 1002.11 ug
2004230
External
Standard
o
o
o
Hit#
of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Ethylbenzene $$ Benzene, ethyl- ... 106 C8H10
2	Ethylbenzene	106 C8H10
000100-41-4 95
000100-41-4 91
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 3 Benzene, 1,2-dimethyl-	Concentration Rank 5
R.T. EstConc	Area	Relative to ISTD	R.T.
3.27 18!
3 6.09 ug
3772180
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzene, 1,2-dimethyl-
2	p-Xylene
106 C8H10
106 C8H10
000095-47-6 93
000106-42-3 93
Arcadis08-139_166.doc/als
Page 57 of 68
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Researcli Triangle Park Laboratories,
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lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 4 4(3H)-Pyrimidinone $$ 4 (3H) .. . Concentration Rank 8
R.T. EstConc	Area	Relative to ISTD	R.T.
3.42 1325.90 ug
2651800
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	4(3H)-Pyrimidinone $$ 4(3H)-Pyri... 96 C4H4N20
2	2H-Pyran-2-one	96 C5H402
051953-17-4 47
000504-31-4 47
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 5 1,3,5,7-Cyclooctatetraene	Concentration Rank 3
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.49 4239.32 ug
8478630
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1,3,5,7-Cyclooctatetraene
2	Styrene
104 C8H8
104 C8H8
000629-20-9 96
000100-42-5 96
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 6 Cyclopropane, 1,2-dimethyl-... Concentration Rank 1
R.T. EstConc	Area	Relative to ISTD	R.T.
3.67 292168.00 ug	584336000 External Standard	0.00
Hit# of 2 Tentative ID	MW MolForm	CAS#
1	Cyclopropane, 1,2-dimethyl-, tra... 70 C5H10
2	Cyclopropane, 1,2-dimethyl-, cis... 70 C5H10
Qual
002402-06-4 43
000930-18-7 43
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 7 2-Propyn-l-ol
R.T. EstConc	Area
Concentration Rank 10
Relative to ISTD	R.T.
3.76 1094.71 ug
2189430
External
Standard
0.00
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	2-Propyn-l-ol
2	Butanimidamide, N-(l-chloro-2-me..
56 C3H40
238 C10H2 0C12N2
000107-19-7 25
040645-73-6 25
Arcadis08-139_166.doc/als
Page 58 of 68
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Researcli Triangle Park Laboratories, Inc.
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tTlxai
NELAP Accredited NJ #NC003
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Peak Number 8 (1R)-2,6,6-Trimethylbicyclo... Concentration Rank 6
R.T. EstConc	Area	Relative to ISTD	R.T.
3.87 15!
3 7.38
ug
3174770
External
Standard
o
o
o
Hit# of
2
Tentative
ID
MW
MolForm
CAS#
Qual
1	(1R)-2,6,6-Trimethylbicyclo[3.1.... 136 C10H16
2	Bicyclo[3.1.1]hept-2-ene, 2,6,6-... 136 C10H16
007785-70-8 96
002437-95-8 91
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 9 Benzaldehyde
R.T. EstConc	Area
Concentration Rank 4
Relative to ISTD	R.T.
4.12 2E
i73.30 ug
5746610
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Benzaldehyde
2	Benzaldehyde
106 C7H60
106 C7H60
000100-52-7 97
000100-52-7 95
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 10 Oxirane, ethenyl- $$ 1-Bute... Concentration Rank 7
R.T .
EstConc
Area
Relative to ISTD
R.T .
4.29 1409.
8 3 ug
2819660
External
Standard
0.00
Hit# of 2
Tentative
ID
MW
MolForm
CAS#
Qual
1	Oxirane, ethenyl- $$ 1-Butene, 3... 70 C4H60
2	2,5-Furandione, 3-methyl- $$ Cit... 112 C5H403
000930-22-3 50
000616-02-4 47
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 11 Naphthalene, 2-methyl-	Concentration Rank 12
R.T .
EstConc
Area
Relative to ISTD
R.T .
6.50 E
3 2 3.75 ug
1647500
External
Standard
0.00
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Naphthalene, 2-methyl-
2	Naphthalene, 2-methyl-
142 C11H10
142 C11H10
000091-57-6 96
000091-57-6 93
Arcadis08-139_166.doc/als
Page 59 of 68
-------
nel c
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
.. a	NELAP Accredited NJ #NC003
919 510-0228 Telephone
919 510-0141 Fax	Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 12 Benzaldehyde, 3-hydroxy-4-m... Concentration Rank 9
R.T. EstConc	Area	Relative to ISTD	R.T.
7.01 1190.51 ug	2381030 External Standard	0.00
Hit# of 2 Tentative ID	MW MolForm	CAS#	Qual
1	Benzaldehyde, 3-hydroxy-4-methoxy- 152 C8H803	000621-59-0 91
2	Vanillin	152 C8H803	000121-33-5 87
Arcadis08-139_166.doc/als
Page 60 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
EPA Methods 8270 Semivolatiles by GC/MS
Data File Name:
Data File Path:
Operator:
Date Acquired:
Acq. Method File:
Misc Info:
Vial Number:
Instrument Name:
Sample Multiplier:
# Compound Name
1)	Pyridine
2)	N-Nitrosodimethylamine
3)	Phenol
4)	Aniline
5)	s-Dichloroethyl ether
6)	2-Chlorophenol
7)	1,3-Dichlorobenzene
8)	1,4-Dichlorobenzene
9)	Benzyl Alcohol
10)	1,2-Dichlorobenzene
11)	2-Methylphenol
12)	Bis(2-chloroisopropyl)ether
13)	3 & 4-Methylphenol
14)	N-nitroso-di-n-propylamine
15)	Hexachloroethane
16)	Nitrobenzene
17)	Isophorone
18)	2-Nitrophenol
19)	2,4-Dimethylphenol
20)	Bis(2-chloroethoxy)methane
21)	2,4-Dichlorophenol
22)	1,2,4-Trichlorobenzene
23)	Naphthalene
24)	p-Chloroaniline
25)	Hexachloro-1,3-butadiene
26)	4-Chloro-3-methylphenol
27)	2-Methylnaphthalene
28)	1-Methylnaphthalene
29)	Hexachlorocyclopentadiene
30)	2,4,6-Trichlorophenol
08166-07.D
C:\MSDChem\1\DATA\01_04_08\
amg
8/5/2008 15:22
8270C_2.M
08-166-07
1uL; Run M0010- FB
1
GCMS#3
HP6890_5973
5
Units
Amount Total/Sample
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
1.11
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
ND
ug
Arcadis08-139_166.doc/als
Page 61 of 68
-------
Jh Triangle Pf
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
rk LaTborattories, I:
mc.
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
31)
2,4,5-T richlorophenol
ND
ug
32)
2-Chloronaphthalene
ND
ug
33)
2-Nitroaniline
ND
ug
34)
1,4-Dinitrobenzene
ND
ug
35)
Dimethyl phthalate
ND
ug
36)
1,3-Dinitrobezene
ND
ug
37)
Acenaphthylene
ND
ug
38)
2,6-Dinitrotoluene
ND
ug
39)
1,2-Dinitrobenzene
ND
ug
40)
3-Nitroaniline
ND
ug
41)
Acenaphthene
ND
ug
42)
2,4-Dinitrophenol
ND
ug
43)
4-Nitrophenol
ND
ug
44)
Dibenzofuran
ND
ug
45)
2,4-Dinitrotoluene
ND
ug
46)
2,3,4,6-Tetrachlorophenol
ND
ug
47)
2,3,5,6-Tetrachlorophenol
ND
ug
48)
Diethylphthalate
ND
ug
49)
4-Chlorophenyl phenyl ether
ND
ug
50)
Fluorene
ND
ug
51)
4-Nitroaniline
ND
ug
52)
4,6-Dinitro-2-methylphenol
ND
ug
53)
Diphenylamine
ND
ug
54)
Azobenzene
ND
ug
55)
4-Bromophenyl phenyl ether
ND
ug
56)
Hexachlorobenzene
ND
ug
57)
Pentachlorophenol
ND
ug
58)
Phenanthrene
ND
ug
59)
Anthracene
ND
ug
60)
Carbazole
ND
ug
61)
Di-n-butyl phthalate
4.88
ug
62)
Fluoranthene
ND
ug
63)
Pyrene
ND
ug
64)
Benzyl butyl phthalate
ND
ug
65)
Bis(2-ethylhexyl)adipate
ND
ug
66)
Benz[a]anthracene
ND
ug
67)
Chrysene
ND
ug
68)
Bis(2-ethylhexyl) phthalate
2.84
ug
69)
Di-n-octyl phthalate
ND
ug
70)
Benzo[b]fluoranthene
ND
ug
71)
Benzo[k]fluoranthene
ND
ug
72)
Benzo[a]pyrene
ND
ug
73)
lndeno[1,2,3-cd]pyrene
ND
ug
74)
Dibenz[a,h]anthracene
ND
ug
75)
Benzo[ghi]perylene
ND
ug
Arcadis08-139_166.doc/als
Page 62 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
tTlxai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
Library Search Compound Report
Data Path
Data File
Acq On
Operator
Sample
Misc
ALS Vial
C:\MSDChem\l\DATA\01_04_08\
08166-07.D
5 Aug 20 08 3:22 pm
amg
08-166-07
luL; Run M0010- FB
1 Sample Multiplier: 5
Quant Method : C:\MSDCHEM\1\METHODS\8270C_2.M
Quant Title : 8270C SVOCs
TIC Library : C:\DATABASE\NIST12 9K.L
TIC Integration Parameters: rteint.p
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 1 1-Propanamine	Concentration Rank 3
R.T .
EstConc
Area
Relative to ISTD
R.T .
3.01 276.67 ug
553333
External
Standard
o
o
o
Hit# of 2 Tentative
ID
MW
MolForm
CAS#
Qual
1	1-Propanamine
2	2-Pentanone, 4-hydroxy-4-methyl-
59 C3H9N
116 C6H1202
000107-10-8 43
000123-42-2 42
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 2 Octane, 4-methyl-	Concentration Rank 6
R.T .
EstConc
Area
Relative to ISTD
R.T .
3 .19
52.94 ug
105875
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Octane, 4-methyl-
2	Octane, 2-methyl-
128 C9H20
128 C9H20
002216-34-4 10
003221-61-2 10
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 3 Heptane, 3-ethyl-2-methyl- ... Concentration Rank 4
R.T. EstConc	Area	Relative to ISTD	R.T.
3.26
72.26 ug
144527
External
Standard
o
o
o
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Heptane, 3-ethyl-2-methyl- $$ 2-... 142 C10H22
2	Undecane, 6-methyl- $$ 6-Methylu... 170 C12H26
014676-29-0 50
017302-33-9 43
Arcadis08-139_166.doc/als
Page 63 of 68
-------
Researcli Triangle Park Laboratories,
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
lUTI Co
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
¦k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k-k
Peak Number 4 1-Hexene
R.T. EstConc	Area
3.60 156107.00 ug	312214000
Hit# of 2 Tentative ID
Concentration Rank 1
Relative to ISTD	R.T.
External Standard	0.00
MW MolForm	CAS#	Qual
1	1-Hexene
2	3-Hexene, (Z)-
84 C6H12
84 C6H12
000592-41-6 47
007642-09-3 46
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 5 2-Pyrrolidinone, 1-methyl- ... Concentration Rank 2
R.T. EstConc	Area	Relative to ISTD
3.63 43968.00 ug	87936100 External Standard
Hit# of 2 Tentative ID	MW MolForm
R.T .
0.00
CAS#	Qual
1	2-Pyrrolidinone, 1-methyl- $$ M-... 99 C5H9NO
2	Oxazole, 2-ethyl-4,5-dihydro- $$... 99 C5H9NO
000872-50-4 35
010431-98-8 32
kkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkkk
Peak Number 6 Cyclopentasiloxane, decamet... Concentration Rank 5
R.T .
EstConc
Area
Relative to ISTD
R.T .
5 . 51
57.62 ug
115230
External
Standard
0.00
Hit# of
2 Tentative
ID
MW
MolForm
CAS#
Qual
1	Cyclopentasiloxane, decamethyl-
2	Benzeneacetic acid, .alpha.,4-bi..
370 C10H3005Si5
326 C15H2604Si2
000541-02-6 72
055334-40-2 43
Arcadis08-139_166.doc/als
Page 64 of 68
-------
Jh Triangle Park Laboratories, I:
mc.
7201 ACCBlvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
Web Site: www.rtp-labs.com
[Tla-ai
NELAP Accredited NJ #NC003
I I !
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-------
Jh Triangle Park Laboratories, I:
mc.
7201 ACCBlvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
I
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Page 66 of 68
-------
Jh Triangle Park Laboratories, I:
mc.
7201 ACCBlvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax
nel c
[Tla-ai
NELAP Accredited NJ #NC003
Web Site: www.rtp-labs.com
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Page 67 of 68
-------
Researcli Triangle Park Laboratories, Inc.
7201 ACC Blvd., Suite 104
Raleigh, NC 27617
919 510-0228 Telephone
919 510-0141 Fax	Web Site: www.rtp-labs.com
nel c
NELAP Accredited NJ #NC003
Arcadis08-139_166.doc/als
Page 68 of 68
-------
Appendix D: Supporting Documents
: | Audit CheckJist.pdf
_) Audit report Sampling for the Air Curtain Destructor Performance Test.pdf
| WPS measurements2.pdf
D-1
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June^2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST 1
Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments
Y 1 N
NA
I. Project management/QA management

Is the final, approved QAPP available to field personnel? Is
the addendum dated June 20, 2008 attached?
Have field personnel read the QAPP?
Are ail pertinent SOPs and/or standard tests methods
available to field personnel?
Have field personnel read all pertinent SOPs and/or standard
tests methods?
s/
s/



QiAff IK> ~TfLA 'Uc*~ "ft
MtfMOOS M RFU5 MAt-Wf*—
iU
rJJ
II. Overall sampling design

Has a velocity profile across the Air Curtain Destructor
(ACD) been confirmed to match preliminary results (QAPP
Figure 5)?
Has the flow through the sampling scoop been matched to
the ACD outlet flow in order to achieve near-isokinetic
sampling conditions?
Is the sampling scoop located along the midpoint of ACD
wall opposite of the plenum?



B1
¥iu€4-pj S£r Ar
6r~ P"-'~
*73 tft c tJ
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"	^ 3
June 14,2008	ft&l *** _ iAJi
y	r
r$mc]
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Are extractive sampling ports in the sampling duct located at
minimum of 8 duct diameters apart from one another?
Are isokinetic conditions being maintained inside the
sampling duct? Specify how this is known.
Are all flow/velocity measurements and deviations from
isokinetic conditions (if any) being fully documented?
Is the ACD bed temperature tracked and recorded using both
thermocouples and infrared pyrometry?
Do the independent temperature measurements
(thermocouple vs. IR pyrometry) agree?
Has the site layout been photographed and/or documented?
III. General field QA/QC, field documentation, and data handli
Compliance

1

N
/^
w

QAPP Reference
B2.7
ng
Are Chain of Custody (CoC) documents present for all
samples?
Axe CoC forms being filled out completely, legibly,
correctly, and with indelible ink?
Are signatures and dates present on all CoC forms?
Are all field records including notebooks being completed
/
B3
Comments
i O.n
dy ftrf
Vtn..	f'B
it-	S
N**r t/fA.' PitjP
r* j uti pus -pkan>\
*EKc-> "T/»KJ£"U
S aj'sT"
$tjtfff-G (ji-Jnt,	r»
DATA

co^fcerPjj /fj >
ISA/ACD Source Sampling
Page 2 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
i
r,
fC c ^
3T £
Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments
Y
N
NA

completely, legibly, and with indelible ink?
Are any and all error corrections being made with a single
line, initials and date (no obliterations)?
Are balances calibrated?
Is the calibration of balances checked regularly?
-	Specify acceptable tolerance.
Are balances used in a temperature- and humidity-controlled
environment?
Is volumetric glassware calibrated/certified, as appropriate?
Are all reagents used traceable and of sufficient quality to
meet project objectives (i.e. minimal backgrounds and
interferences)?
Are field blanks generated to assess amount of contamination
introduced during sample handling?
-	Specify for which methods/sample types.
Are extractive sampling trains leak-checked before and after
each sampling event?
-	Is this documented?
Are flow rates through extractive sampling trains verified
1
s
J
y
/
M

A7, Table 1.
B5
B6
B6
FtuJ uj/Ofi "* C
u *# 7nor 4
t* externt> .
ft" 2-3 ^ /VUS", Ml°
l£ak >W'
5p r.?(rMti
fk& "flST Fn> j situ
des&wgo	j7> &puf.*jj-s
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14, 2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST

Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments


Y
N
NA




before and after each sampling event?
Is this documented?







Are Continuous Emissions Monitors (CEMs) calibrated
before and after sampling runs?
Specify acceptable tolerance.
Is this documented?
y


B7
C A,t~ t Gfo
CMC eft


Has the performance of the Environics 4000 gas mixer been
verified as described in Method 205?
-	Is this documented?
-	Specify CEM and gases used for performance
verification.
./


A7, Table 1.
T>*1T H
n wSf D
'L
r?

Are all electronic data handled in such a way so as to
minimize data loss, i.e. nightly back-ups?
vX




1
H

Are all time-keeping devices synchronized so that sampling
start/stop times are accurate?
v/


B10



Has the Project Engineer performed the duties of the Data
Manager? That is, have they reviewed all field sampling
data, CoCs, notebooks, etc.?





i
IV. Sample labeling, packaging, and shipping (Sample Handling and CoC) j

Are metals samples and diox i ns/furans/PCBs/S VOC samples
maintained and shipped on ice at 4°C (or less)?
- Indicate how other sample types are shipped.
~


B3, Table 3

TSA/ACD Source Sampling
rfc'-L r"'"*
tJ-JT
Page 4 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST I
Djc€
Ft ZA,*Apu€ •
V. Continuous emission monitoring for C02,02, NO„ CO, SO2, and THC

Are appropriate sampling methods being followed? That is,
are instruments being operated in accordance with:
EPA Method 3A for C02/02?
Specify instrument make/model, measurement
principle, and calibration range.
EPA Method 7E for NO,?
Specify instrument make/model, measurement
principle, and calibration range.
EPA Method 10 for CO?
/
/
~


B2.1
B2.2
B2.3
B2.4
B2.5
B2.6
ftd ~7&S
c m «• > >C 0
*'¦ C*.

TSA/ACD Source Sampling
Page 5 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECIINICA]
L SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments
Y
N
NA

-	Specify instrument make/model, measurement
principle, and calibration range.
EPA Method 6C for S02?
-	Specify instrument make/model, measurement
principle, and calibration range.
EPA Method 25A for THC?
-	Specify instrument make/model, measurement
principle, and calibration range.
Are performance criteria being met for all of these CEMs? If
not, explain remedial action(s) undertaken. Also describe
how instrument performance is verified for each criterion.
-	Calibration error < ± 2%
-	Sampling system bias < ± 5%
-	Zero and calibration drift < ± 2%
-	Data completeness > 90%.
Are sampling system components in contact with the sample
gas constructed of 316 stainless steel or Teflon?
Is the appropriate collection and conditioning inlet system,
consisting of a heated probe and particulate filter, moisture
removal trap, and out-of-stack secondary particulate filter,
used for the C02/02, NO,. CO, and S02 instruments?
Is the sample gas going to the THC instrument heated to
\ V 
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICA
Requirements Based on Procedures Established in QAPP
SYSTEMS AUDIT CHECKLIST
Compliance | QAPP Reference
N
NA
Comments
250-300°F and filter with glass fiber filters so that certain
compounds comprising total hydrocarbons do not condense
from the sample stream?
Are multipoint calibration curves prepared for each of the
CEMs?
Are all calibration gases used certified and traceable?
-	Indicate concentrations.
For N'Ox, has the converter efficiency been
established/tested?
-	Indicate measured efficiency.
Has the performance of the electronic data acquisition
system for the CEMs been verified?
-	Indicate checks performed.
~




3 ft
C ufi-Jft f i
i/t
Y
sft
cczHlf
,,,	CcT'31
; t/iVcn
C<- itfl'l'1
83.1
fa.o&lo O-x, 1	1
1%*% oL ( 8.^3 C°~l~
bits
C*t> Z*S'>
Cc i o3 Hlf\ A\^
PAtft	f
VI. Extractive sampling
I
iffiWAS" TESTES, *5^n M
OAs
o<
Methods 1A & 2C	/
Is extractive sampling occurring > 8 duct diameters
downstream and > 10 duct diameters upstream from flow
disturbances?
Do at least 8 duct diameters separate extractive sampling
probes?
B2.8
B2.9
B2.10
B2.ll
B2.12
B2.13
B2.14
B2.15
B2.16
tA
up y
fif
TSA/ACD Source Sampling
\.//iy <>->. err-. U
,'T it*-.
<; '% Difc.

^93% '*>ijr cMfc< °
srs, oc -c, G«Page 7 of 18
/^TT«0 /ULfFC^
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Are velocity measurements conducted at least 8 duct
diameters downstream from any extractive sampling?
Have at least 8 velocity traverses be conducted to
characterize the duct velocity?
-	If not, indicate how many.
Is such velocity characterization done for every test?
Is so, are results in general consistent across tests?
Is a standard pitot tube used?
-	If not, specify what type is used.
Is pitot tube calibrated?
-	Specify when calibration expires.
Is pitot tube coefficient 0.99?
-	Specify if otherwise.
Is a calibrated manometer used to measure pressure drop
across pitot tube?
-	What is the calibration date.
Method 4 (moisture)
QAPP indicates that sample moisture is determined as part of
sampling for Methods 5/202, 29, and 23. Is moisture
determined for each of these methods during each and every
Compliance
/

N
NA
QAPP Reference
B2.17
B2.18
B2.19
A
CcH&r
^ *v
/*9

Comments
fo vtt
H
a.<4 ot
* »
i.r
L"
fjo TTbvw.
r, To Si DC
f/Ui»

tijjM
ryfg
l/i£q
4 V» A*-1"7
tj Z/i /ZXiSl
c 
|D*r£j
<5*

TSA/ACD Source Sampling
Page 8 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
sample collection event?
- Specify frequency if otherwise.
Is moisture determined gravimetrically?
Is moisture determined volumetrically?
Is the sample temperature at the outlet of the final impinger
in the sampling train maintained at < 20°C?
Is probe ahead of condenser maintained at > 120°C so as to
avoid condensation?
Method 5/202 (Filterable and Condensable PM)
Are all procedures and QA protocols as specified and
outlined in Methods 5 and 202 being followed?
Is isokinetic sampling being conducted?
Are filters dried to a constant mass before use (i.e. < 0.5 mg
difference change from previous weighing)?
Is this gravimetric analysis performed on-site?
Is low-residue acetone used to ensure artifact minimization?
For filterable PM, is the PM in the probe captured along with
that collected on the filter?
Compliance
/
/I
1
v/
v/
l/
N

\
NA
QAPP Reference
Comments
(IV.


cgfl*' 1VU.T	f 0f
.4A rn^	^ /r'
ca<~- D/c^ y'ifo®
FilTZU A I*
><¦"*>
fiAJO
fjvT E •*-
"p.' T*	L>
I
TSA/ACD Source Sampling	Page 9 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST

Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments


Y
N
NA



For condensable PM, is the correct sampling train consisting
of 3 water-filled impingers and one silica gel-filled impinger
used?
v/



imfitMSH* ItJ

Is low-residue methylene chloride being used?
~





Are water and methylene chloride blanks collected?
- Specify frequency.




ooe of
C 6 f&k* a%C71 J4 *

Is a contingency plan in place to perform N2 purging for SO2
removal or NH4OH addition for sulfate correction if S02 is
observed in the gas stream using the CEMs?






Asbestos





(
What type of sampling is being performed to capture
asbestos:
- Sampling onto polycarbonate filters with dilution?
Sampling onto pHycallTDTOtt^Uers without dilution?
s^-^Sampling into distilled water impinggra?
Is a modified Method 5 sampling train used for asbestos
sampling?
If filter sampling is being performed, specify:
-filter size (47 or 83 mm)
-pore size (0.4 um)
/



Mii*12* *
-£0X0 a.
A%tT]ph ^ 4J O?0,1. 9/zi/tn	1-b»xv
0L'^rl
TSA/ACD Source Sampling	o:	Page 10 of 18
OU>q^
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
-sampling flow rate (15 slpm)
Method 26 (Acid gases)
Are all procedures and QA protocols as specified and
outlined in Method 26 being followed?
Is sampling occurring isokinetically?
Is the correct sampling train being used? Sampling train
should include: filter, empty impinger, 2 impingers
containing 0.1 N H2S04, 2 impingers containing NaOH, one
impinger containing silica gel; all impingers submerged in
ice bath.
Is filter recovered and analyzed? Explain rationale if not.
Are blanks of the sulfuric acid and sodium hydroxide
solutions being generated and analyzed?
- Specify frequency.
Is the correct amount of sodium thiosulfate added to the
NaOH impinger solution? (0.7 mg per ppm*dscm)
Have the vacuum gauges, rotometers, thermocouples, and
dry gas meter been calibrated?
Have any through-the-probe matrix spikes been performed?
Compliance
./I
I
J
1

N

NA
QAPP Reference
Comments
1 
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
N NA
QAPP Reference
Comments
If yes, were the results acceptable?
If not, are any planned?
Have any through-the-probe zero checks been performed?
If yes, were the results acceptable?
If not, are any planned?
Method 23 (Dioxins/Furans, PCBs. PAHs, and SVOC)
Are all procedures and QA protocols as specified and
outlined in Method 23 being followed?
Is isokinetic sampling occurring?
Is the correct sampling train being used? Sampling train
should include: filter, XAD-2 trap, empty impinger, 2
impingcrs containing water, an empty impinger, and one
impinger containing silica gel; all impingers submerged in
ice bath.
Is the use of sealing grease avoided on the sampling train?
Is the gas cooled to 20°C before passage through XAD-2
trap?
Are the filters and XAD-2 resin precleaned before use (for
/
/
~






«*,. yV0* '
Fl* u **1?
fitJ-	T&Ht* 6
IN FL4 cff f
fjo	of
ih ftV'aD
m	of "7*'-if fA
etir -TB'M* y? cf
mT"*
mtes fZjsstu-
TSA/ACD Source Sampling
Xftb n-Afr
fAlZ
€ r* \6 Sfl i
Page 12 of 18
c. ?:*>
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
instance, by Soxhlet extraction)?
Are reagents used in the field blank-checked? At what
frequency?
Is a train blank generated?
-	Specify frequency.
Have any through-the-probe matrix spikes been performed?
If yes, were the results acceptable?
If not, are any planned?
Have any through-the-probe zero checks been performed?
-	If yes, were the results acceptable?
If not, are any planned?
Method 29 (Metals')
Are all procedures and QA protocols as specified and
outlined in Method 29 being followed?
Is sampling occurring isokinetically?
Is the correct sampling train being used? Sampling train
should include: filter, XAD-2 trap, empty impinger, 2
Compliance
y
i
y
~
N
rJ
NA
QAPP Reference
Comments
I
/0 OfM fl.fiViStub

frtb aw
E"_p
2- ilm. em.pr^ ~TA
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14, 2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments
Y
N
NA

impingers containing 5% HNOy 10% H20), an empty
impinger, two impingers containing 4% KMnOv'l 0% H2SO4,
one impinger containing silica gel; all impingers submerged
in ice bath.
Are all reagents of sufficient quality (sufficiently low
background concentrations of target analytes) so as to meet
project objectives?
Is venting of the acidic potassium permanganate solution
permitted so as to avoid buildup of pressure?
Is sufficient care taken during the preparation and handling
of the impinger sampling train so as to minimize and
eliminate contamination?
Are reagents used in the field blank-checked? At what
frequency?
Is a train blank generated?
-	Specify frequency.
Have any through-the-probe matrix spikes been performed?
-	If yes, were the results acceptable?
If not, are any planned?
Have any through-the-probe zero checks been performed?
y
r
/
/
jO
rJ


" mx-TA'\s
fW ur ti6folA
VWHA-ft PL
f pit* Mt rw
1 ret' mWUkP
C W € **..
TSA/ACD Source Sampling
Page 14 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments
Y
N
NA

-	If yes, were the results acceptable?
If not, are any planned?
Modified EPA Method 0040 (VOCs)
Are all procedures and QA protocols as specified and
outlined in Method 0040 being followed? (with the exception
that samples are being collected in stainless steel canisters
instead of Tedlar bags)
Is sampling occurring isokinetically? ^
If not, specify sampler flow rate.
Is the sampling apparatus capable of removing moisture and
other condensable components of the gas stream before
collection in the sampling vessel?
Are all chemicals and reagents of a quality sufficient so as to
minimize interferences and background signals so that
project objectives can be achieved?
Is a train blank generated?
Specify frequency.
Have any through-the-probe matrix spikes been performed?
-	If yes, were the results acceptable?
yt

A

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TSA/ACD Source Sampling
Page 15 of 13
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
If not, are any planned?
Have any through-the-probe zero checks been performed?
- If yes, were the results acceptable?
If not, are any planned?
Modified CARB Method 501 (PM particle sizing)
Specify cut sizes for Anderson PM10 cascade impactor.
Specify collection media in cascade impactor.
Modified EPA Method 201A fPMlO)
Specify flow through cyclone that results in only sampling
PM2,s.
Ash sampling
Are samples collected from several different areas of the
AC'D and composited?
- If yes, how is this documented?
Have ash samples been collected (or will they be collected)
for each type of debris to be combusted: vegetative, clean
Compliance
N
k)
N*
NA
QAPP Reference
Comments
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-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICA1
L SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comments
Y
N
NA

construction and demolition (C&D), and asbestos-containing
C&D)?
Are sampling implements and containers kept clean and free
of contaminants?
Method 9 (Visible Emissions)
Are the viewing guidelines as outline in Method 9 being
followed?
Is the smoke reader a certified observer?
-Indicate name of smoke reader.
Is the certification documented?
Is the opacity documented in any other way (i.e.
photography)?
l/



€6**- i^36*rt37
yUfos — 11/13/
3i6jTAv. f

I




VII. Other non-critical measurements

Is the bulk composition of the debris destroyed in the ACD
in the various tests being tracked and recorded (its collection
location, water content, gross weight, gross makeup)?
- Is this documented?



B9 3

TSA/ACD Source Sampling
Page 17 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Source sampling in support of Air Curtain
Destructor Performance Test"
June 14,2008
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
N NA
QAPP Reference
Comments
Arc the local meteorological conditions (temperature,
relative humidity, wind speed and direction) being
recorded/captured?
Are local measurements of PM and asbestos concentrations
being captured/recorded?
Are particle size distribution measurements being made
using the Wide-Range Particle Spectrometer?
/
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QA checklist prepared by: Ian C. MacGregor, Battelle
Under contract to Neptune, Inc. for the US EPA, ORD/NRMRL
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TSA/ACD Source Sampling	Page 18 of 18
-------
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-------
AUDfT JO J ( 10 DEC. 2jCO^J
December 17, 2009
MEMORANDUM
SUBJECT: Technical Systems Audit (TSA) of source measurement activities for "Air Curtain
Destructor Performance Test"
This work was performed under Contract EP-C-08-007, Task Order 30, Work
Order 1.
FROM: Kenneth Cowen
Principal Research Scientist, Battclle. Environmental Assessment and Exposure
TO:	Paul Groff
Director of Quality Assurance, USEPA/ORD/NRMRL/APPCD
Attached is the final report from the Technical Systems Audit, completed on December 10, 2009,
Dr. Kenneth Cowen, with Battelle, performed the audit as a subcontractor to Neptune and
Company, Inc. The completed audit checklist is included with this document as Attachment 1.
Thank you for the opportunity to perform this audit.
-------
CONTENTS
INTRODUCTION	1
SUMMARY	1
AUDIT RESULTS	2
Attachment 1: Completed Audit Checklist
-------
INTRODUCTION
On December 10, 2009. a technical systems audit (TSA) was performed at the
EPA's Open Burn Test Facility located in the EPA's Research Center in Research
Triangle Park, NC, during the performance test of a pilot-scale air curtain burner (ACB).
The purpose of the performance testing was to assess if the pilot-scale ACB could
effectively convert regulated asbestos containing materials (RACM) to forsterite or other
non-asbestos materials during combustion. To assess the performance, samples of
gaseous and particulate emissions from the pilot-scale ACB were collected using
standard source sampling techniques. The samples were collected from inside an eight
inch diameter exhaust duct that led from the burn hut chamber to the facility
baghouse/HEPA filter. A large volume induced-draft blower was used to draw the
sample from the burn hut through the baghouse and HEPA filter. Sampling train probes
were inserted into the duct, and the sampling trains had tliexr own pumps to withdraw the
sample from the duct.
The audit was performed by Dr. Kenneth Cowen, of Battelle Memorial Institute,
under subcontract to Neptune and Company, Inc. Present for the audit were Dr. Paul
Lemieux of EPA, Dr. Johannes Lee, Ms. Libby Nessley, Mr. Steve Terll, Mr. Daniel
Janek, Mr. John Nash, and Mr. Justin Ashely all from ARCADIS. This audit addressed
measurement of key target analytes from the source and included the real-time
measurement of carbon dioxide (C02) and carbon monoxide (CO), as well as the
collection of integrated samples for filterable/condensable particulate matter (PM)
(Method 5/202,), asbestos (CARB Method 427), volatile organic compounds (VOCs)
(Method 0040), semi-volatile organic particles (SVOCs) (Method 0010). All
measurements included in this audit were performed by ARCADIS and were performed
according to the QAPP entitled "Pilot-Scale Air Curtain Burner Performance Test" dated
November, 2009, with modifications as documented on December 4, 2009. A checklist
was prepared for this technical system audit using the above mentioned QAPP.
SUMMARY
The one day audit was performed at the EPA's Open Burn Test Facility and
included observations of test preparation and sampling activities by Dr. Cowen, as well
as the recovery of a single sampling train. Time constraints and the physical separation
of locations for sampling and train recovery activities prevented observation of the
recovery of all sampling trains. Some minor delays in testing were experienced during
test start up as the result of leaks in sampling train apparatus and subsequent corrective
action. Consequently, the ignition of the combustible feed materials was initiated at
approximately 11:10 a.m., with the onset of the introduction of RACM feed materials to
the ACB at 11:40 a.m. Preweighed samples of combustible feed material and RACM
feed material were introduced to the ACB at ten minute intervals throughout the sample
collection periods. Sample collection activities were initiated at 12:20 p.m. for the
Method 5/202 and Method 0010 sampling trains. The Method 0010 sampling continued
for 2 hours, whereas the Method 5/202 sampling continued for only 1 hour. After
completion of the sampling the trains were recovered and sampling was initiated for
1
-------
CARB Method 427, Method 0040, and a modified Method 5 sampling train. Upon
completion of the sampling activities, preweighed combustible feed material (wood with
no RACM) was introduced to the ACB at ten minute intervals for an additional two hours
to promote the complete conversion of the RACM present in the ACB to non-hazardous
forms (based on results from earlier muffle furnace tests performed at RTI).
AUDIT RESULTS
FINDINGS
I.	General field QA/QC, field documentation, and data handling
Is sampling planning to commence 5 minutes before the onset of the ACMfeed and
stop 30 minutes after the feed has stopped? Are procedures in place to adjust
sampling time and/or sample gas withdrawal rate, or swapping of the filter housing
if there is plugging/blinding of the filter?
Finding; The timing of sample collection varied from the prescribed times given in
the QAPP. The QAPP calls for sampling to commence 5 minutes prior to the onset
of ACM feed for both Method 0010 and Method 427, and 30 minutes after the onset
of ACM feed for Method 5/202 and Method 0040. During testing, sampling for both
Method 0010 and Method 5/202 was initiated approximately 40 minutes after the first
ACM feed and sampling for Method 427, Method 0040, and the modified Method 5
train for asbestos commenced at least three hours after the onset of ACM feed.
Are balances calibrated?
Is the calibration of balances checked regularly? Specify acceptable tolerance.
Are balances used in a temperature- and humidity-controlled environment?
Finding; The balance used to measure weights for the combustion feed material and
the impingers (EPA Metrology Laboratory number 03269) was out of calibration.
The most recent calibration date for the balance was 4/7/08. The balance is kept in an
environment that is not temperature and humidity controlled. Further, there was no
evidence that calibration checks had been performed using certified weights.
II.	Extractive sampling
CARB Method 427
Does filter plugging/binding occur during sample collection?
What corrective actions are performed and how are they documented?
Finding; As implemented, the CARB method used for the collection of asbestos
samples was not able to maintain isokinetic sampling conditions. During testing,
plugging of the filter appeared to occur almost instantaneously upon initiation of
sampling. The pressure drop across the filter was too great to achieve isokineticity,
thus potentially biasing the sampling. To ensure that a representative asbestos sample
2
-------
was collected, the test crew conducted additional sampling using a modified Method
5 train without filtration to capture the asbestos fibers directly in the impinger liquid.
Recommend an amendment to the QAPP be performed to accurately document this
additional or modification to the testing procedures.
OBSEVATIONS
I.	Project Management/QA Management
Have field personnel read the QAPP?
Observation: No documentation was available in the field to demonstrate that the
source sampling personnel had read the signed QAPP. Mr. Johannes Lee explained
that the ARC AD IS staff had all read the QAPP and had discussed roles and
responsibilities multiple times. The test personnel had ready access to and did seem to
be aware of the QAPP requirements as well as with the sampling method
requirements.
II.	Overall Sampling Design
Have the bum hut preparation procedures been followed prior to initiation of
testing?
Observation: Prior to testing, ash/debris were observed on the floor of the burn hut
although the walls seemed clean. During testing, it was apparent that a large number
of sparks and other combustion debris were emitted from the Air Curtain Burner
(ACB). This observation reinforces the need to perform the post-test cleanup
procedures, including the collection of debris and particulate materials on the floor of
the burn hut. Since the floor of the burn hut is a somewhat porous cement surface, it
is recommended that aluminum foil, or other readily cleanable surface is placed over
the bare concrete to facilitate the cleaning process.
Are 20 minute running averages being calculated to be able to determine when
steady-state conditions have been reached (bed temperatures unchanged over 3
charge cycles)? If not, what is being done to determine when steady state
conditions have been met?
Observation: Steady-state conditions were determined based on the results of the
scoping tests as the bed temperature varied considerably over the course of a single
charge. Bed temperatures were maintained above 700° for much of the testing period.
III.	General field QA/QC, field documentation, and data handling
Are all field records including notebooks being completed completely, legibly, and
with indelible ink?
3
-------
Are any and all error corrections being made with a single line, initials and date
(no obliterations) ?
Observation: Entries on sample collection forms and other documentation were
legible and written in indelible ink. However, corrections to entries were
occasionally partially obliterated, and frequently not initialed and dated (see for
example the data sheet for ACB-VT-PM-01). Additionally, some data were recorded
on loose pieces of paper rather than on dedicated forms or in bound record books (for
example, the data from the pre-test traverse).
IV.	Sample labeling, packaging, and shipping (Sample Handling and CoC)
Is the sample labeling format as described in QAPP Section B3 being followed?
Observation: The sample labeling scheme deviated somewhat from the scheme
described in the QAPP. The revised scheme was developed to minimize redundancy
but should be documented.
V.	Extractive sampling
Method 1A & 2C
Is pitot tube calibrated?
Observation: The sampling crew indicated that the pitot tube had been calibrated by
the EPA Metrology Laboratory, but no documentation of the calibration was
available. Also, apparently the pitot tube was identified only by an inscription (T3)
faintly written in marker. A unique identification number should probably be etched
on the pitot tube to avoid misidentification. Also calibration records should be kept
on site to ensure proper documentation.
Wood and ACM Burning Weight Loss
Is the weight of the ACB recorded during the test?
Observation: Because of the weight of the ACB, no scales with sufficient sensitivity
were available to measure weight loss during testing.
4
-------
ATTACHMENT 1
COMPLETED AUDIT CHECKLIST
-------
Baireiie
\.
The Business of Iimavntioit

December 17, 2009
Mr. Paul Groff
U.S. Environmental Protection Agency
Mail Drop E343-03
4930 Old Page Road
Research Triangle Park, NC 27709
Dear Mr. Groff:
RE: Technical Systems Audit, Contract EP-C-08-007, Task Order 30, Work Order 1
On December 10, 2009, an assessment of the performance test of a pilot-scale air curtain burner
(ACB) at the EPA's Open Bum Test Facility located in the EPA's Research Center in Research
Triangle Park, NC was conducted by Battelle, under subcontract to Neptune and Company, Inc.
Please find the final results of this assessment based on input provided by the US EPA presented
below. If you have any questions or comments, please do not hesitate to contact me at 614-424-
5795 or Milenbergz@battelle.org or Dr. Kenneth Cowen at 614-424-5547 or
eowenk@.battelle.org. Thank you.
Sincerely,

ZacharyJiVillenberg^
Quality Assurance Officer
Battel le Columbus
zjw/cg
Enclosures
cc
Paul Lemieux, U.S. EPA
Lauren Drees, U.S. EPA
Dave Gratson, Neptune and Comp., Inc.
605 King Avenue Columbus, Ohio 43?0K>693 800 201 2011 solutions@battelle.org www.battelle.ofg
-------
ILLI) IECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10, 2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKI JST~
Requirements Based on Procedures Established in QAPP
Compliance
I. Project managcnient/QA management
Is the final, approved QAPP available to testing personnel?
Have testing personnel read the QAPP?
Are all pertinent SOPs and/or standard tests methods
available to testing personnel?
Have testing personnel read all pertinent SOPs and/or
standard tests methods?
II, Overall sampling design
N NA
rfc?r c../tf i
TSA/ACl) Source Sampling
Snvt;
V.
T:M 	
Tc'lU^
A/4 J V
Q\l'l' Reference
Have the combustible and feed materials been prepared as
described?
1


B 1.1.2-4
Have the feed charges been prepared and stored as
described?
1


131.1.5
Is the make-up air controlled to maintain a slightly negative
pressure relative to ambient? How is this measured?
\i


Bl.2.1
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!



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Comments
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Page 1 of 18

-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10, 2009
' FIELD AC IIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Kstablished in QAPP
Is the ash collection tray installed in the burn hut?
Have the walls of the burn hut been lined with A1 foil?
Is the air being introduced via a bank of 107 drilled round
openings, 0.116 inches in diameter into a 3 inch thick-wall?
Is the air flowrate being measured by a rotameter and is it
adjustable by a flow control valve?
Has the flow rate been set to around 40 scfm and supplied by
a pressure blower? •
Were scoping tests performed to verify the optimum charge
size? What did the results of those tests indicate?
Prior to any testing, have the following procedures been
followed:
•	Was a clean vacuum filter and hose used to remove
loose PM from internal surfaces of the burn hut?
•	Was a mop or wetted cloth used to wipe down the
aluminum foil surfaces?
Has the wipe down procedure been repeated between
bumcj#?
Have the burn hut preparation procedures been followed
after completion of testing?
•	Was Al foil removed and stored in appropriate
Compliance
1
1
1
N

NA
/J 4
QAPP Reference
B 1.12.2
B 1.2.3
Bl.2.5
B1.3
B1.3.1
B1.3.2.2
ft
Comments
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TSA/ACD Source Sampling
Page 2 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
AC-TIV1T1ES TECHNICAL SYSTEMS^AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
drums?
•	Was a clean vacuum filter and hose used to remove
loose I'M from internal surfaces of the burn hut?
•	Was vacuum cleaner catch collected and placed in
labeled jar?
Are 20 minute running averages being calculated to be able
to determine when steady-state conditions have been reached
(bed temperatures unchanged over 3 charge cycles)? If not,
what is being clone to determine when steady state conditions
have been met.
Sample Collection Period
Is sampling planning to commence 5 minutes before the
onset of the ACM feed and stop 30 minutes after the feed has
slopped? Are procedures in place to adjust sampling time
and/or sample gas withdrawal rate , or swapping of the filter
housing if there is plugging/blinding of the filter?
Was a scoping test performed to determine the appropriate
sample collection rates and duration?
Is a Health and Safety Plan (HASP) in place that specifies
the appropriate PPE requirements during the GARB Method
427 train operation to reduce potential contact to asbestos?
Compliance
NA


QAPP Reference
KJ
B1.3,2.4
B2.6.
Comments

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-------
HELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10, 2009
FIELD ACTIVITIES TECHNICA1
. SYSTEMS AUDIT CHECKLIST


Requirements Based on Procedures Established In QAPP
Compliance
QAPP Reference !
Comments



Y
N
NA



III, General field QA/QC, field documentation, and data handling


Are Chain of Custody (CoC) documents present for all
samples?
Are CoC forms being filled out completely, legibly,
correctly, and with indelible ink?


NA
B3
Ot-fi 7 t-A "•?> t'ilitA
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Are signatures and dates present on all CoC forms?
Are all testing records including notebooks being completed
completely, legibly, and with indelible ink?
/

NA

O-c c 1 S"< i <"-a-os'/o '.rrS/£>p
uteres

Are any and all error corrections being made with a single
line, initials and date (no obliterations)?
Are balances calibrated?
Is the calibration of balances checked regularly?
- Specify acceptable tolerance.

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A7, Table 1.
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environment?
Is volumetric glassware calibrated/certified, as appropriate?




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Are all reagents used traceable and of sufficient quality to
meet project objectives (i.e. minimal backgrounds and
V
1





TSA/ACD Source Sampling	Page 4 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10, 2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECK LIS I
Requirements Based on Procedures Established in QAPP
interferences)?
Are field blanks generated to assess amount of contamination
introduced during sample handling?
-	Specify for which methods/sample types.
Arc extractive sampling trains leak-checked before and after
each sampling event?
-	Is this documented?
Are flow rates through extractive sampling trains verified
before and after each sampling event?
Is this documented?
Are Continuous Emissions Monitors (CEMs) calibrated
before and after sampling runs?
-	S pecify "acceptable tolerance.
Is this documented?
Are all electronic data handled in such a way so as to
minimize data loss, i.e. nightly back-ups?
Are all time-keeping devices synchronized so that sampling
start/stop times are accurate?
Has the Project Engineer performed the duties of the Data
Manager? That is, have they reviewed all sampling data,
CoCs, notebooks, etc.?
Compliance
1
y
1
!
1
N
NA
M A
wA
QAPP Reference
B5
B6
B6
B7
BIO
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-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
Deeember 10, 2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
N
NA
QAPP Reference
IV. Sample labeling, packaging, and shipping (Sample Handling and CoC)
Are samples stored on-site either before use or after
sampling is complete and before being shipped?
- Specify length of time.
Are all samples handled in a manner so as to avoid
introduction of contamination?
Is the sample labeling format as described in QAPP Section
B3 being followed?
Are any trip blank filters, impinger liquids, XAD-2
cartridges, etc, generated?
If yes, specify.


B20, Table 4
V. Continuous emission monitoring for C02, 02, N'()„ CO, S()2, and THC
Are appropriate sampling methods being followed? That is,
are instruments being operated in accordance with:
EPA Method 3A for C02/02?
Specify instrument make/model, measurement
principle, and calibration range,
EPA Method 10 for CO?
Specify instrument make/model, measurement
^ principle, and calibration range.	
i
Comments
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TSA/ACD Source Sampling
Page 6 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST-
Requirements Based on Procedures Established in QAPP
EPA Method 25A for THC?
Specify instrument make/model, measurement
principle, and calibration range.
Are performance criteria being met for all of these CEMs? If
not, explain remedial action(s) undertaken. Also describe
how instrument performance is verified for each criterion.
-	Calibration error < ± 2%
Sampling system bias < * 5%
-	Zero and calibration drift < ± 3%
Data completeness > 90%.
Are sampling system components in contact with the sample
gas constructed of 316 stainless steel or Teflon?
Is the appropriate collection and conditioning inlet system,
consisting of a heated probe and particulate filter, moisture
removal trap, and out-of-staek secondary particulate filter,
used for the CO2/O2, CO, and THC instruments'?
Is the sample gas going to the THC instrument heated to
250~300°F and filtered with glass fiber filters so that certain
compounds comprising total hydrocarbons do not condense
from the sample stream?
Are multipoint calibration curves prepared for each of the
CI Ms?
Compliance
v InTna
v/
/
QAPP Reference
B2.2.3
A7, Table 1
Comments
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TSA/ACD Source Sampling
Page 7 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10, 2009
"FIELD ACTIVITIES TECHN1CALSYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Are all calibration gases used certified and traceable?
-	Indicate concentrations.
Has the performance of the electronic data acquisition
system for the CEMs been verified?
-	Indicate checks performed.
VI. Extractive sampling
Methods LA & 2C
Is extractive sampling conducted 5 ft downstream of the
Burn Hut exhaust duct?
Are the extractive sampling probes located 8 equivalent
diameters upstream of the velocity sampling ports?
Is velocity characterization done for every test?
Is so, are results in general consistent across tests?
Is a standard pitot tube used?
If not, specify what type is used.
Is pitot tube calibrated?
- Specify when calibration expires.
"r'3
Compliance
r
NA
QAPP Reference
1
y

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TSA/ACD Source Sampling
Page 8 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AI 1)11 CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
 Reference
Comments

Y
N
NA



Is pitot tube coefficient 0,99?
Specify if otherwise.






Js a calibrated manometer used to measure pressure drop
across pitot tube?
What is the calibration date.




fbtssoiul CAv
aBox.,

Method 4 (moisture)



B2.4


QAPP indicates that sample moisture is determined as part of
sampling for Methods 5/202, and M0010. Is moisture
determined for each of these methods during each and every
sample collection event?
- Specify frequency if otherwise.
7





Is moisture determined gravimetrically?
Is moisture determined volumetrically?
y
i
K>




Is the sample temperature at the outlet of the final impinger
in the sampling train maintained at < 20°C?
. j
Vj
/



SI * J fofl"
J A ~ 5 ¦' PtVj*-' At £Y 2,

Is probe ahead of condenser maintained at > 120°C so as to
avoid condensation?
1





Method 5/202 (Filterable and Condensable PM )



B2.5


Are all procedures and QA protocols as specified and






m-'-f
TSA/ACD Source Sampling
Page 9 of 18
-------
HELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
FIELD AClWlTIESTECHN1CALSYSTEMS AIT)IT CHECKLIST
Requirements Based on Procedures Established in QAPP
outlined in Methods 5 and 202 being followed?
Is isokinetic sampling being conducted?
Are filters dried to a constant mass before use (i.e. < 0.5 mg
difference change from previous weighing)?
?M oof'CHlo triL.Pt.pS
Is this gravimetric analysis performed on-site? /wyr-:
Is low-residue acetone used to ensure artifact minimization?
For filterable PM, is the I'M in the probe cap/iired along' with
that collected on the filter?
For condensable PM, is the correct sampling train consisting
of 3 water-Filled impingers and one silica gel-filled impinger
used?
Is low-residue methylene chloride being used?
Are water and methylene chloride blanks collected?
Specify frequency.
Is a contingency plan in place to perform N2 purging for SO.,
removal or N114011 addition for sulfate correction if S()2 is
observed in the gas stream using the CEMs?
ComjjHance i QAPP Kiference
N
NA
£

H
\T-
aJ


Comments
UJ1M< /tofflslV Bo/
a*j 1/4/0 5 MITMO
j o u- a >„>*) % _	_—	_	
O.-Lfa i .£>,
UiKlCr.fi Tt> Mgf t.JJ |J
C4t_
fit-TSM se*r r» -i
piU>B£ €	7L*r-i
rtwr
2
0 30 0^
fit.
I#(„€ 6At\bQ	L-ar"
~&ec ~5/€/o"i /x, fc-/f
nws "pi,4^Cfc. 0-,rr
cau
~ff-0g4 2SS
satis*
-re "" 5WH,
TSA/ACD Source Sampling
Page 10 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
A*'

4 o ^'
^ ¦"
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
-7*"
Requirements Based on Procedures Established in QAPF
Compliance
CARB Method 427 (Asbestos)
Is sampling being conducted using 0.4 mm pore size
polycarbonate filter media?
Is the face velocity maintained in the range of 4-25 cm/sec?
How is this documented?
Is the exhaust gas temperature maintained below 150 C?
If dilution/cooling is necessary how is this documented?
Does sample collection begin 5 minutes prior to ACM feed,
and extend 30 minutes after completion of ACM feed?
Does filter plugging/binding occur during sample collection?
What corrective actions are performed and how are
they documented?
EPA Method OOlOfPAHs)
Are all procedures and QA protocols as specified and
outlined in Method 10 being followed?
Is isokinetic sampling occurring?
1
N

NA
MA
QAPP Reference
B2.6
B2.7
""Of		' -ext&V:
-fm fMii '-Air X>*At a*****
fiGiZ*. rs -To*	r"° 4'
/ so fct n < 5* *» f* "4 •
/
Comments

m.u, "3d uir4 73 cMfK>A,t M
[*¦*
"itmfuhic Timfs	Tt>
Puct" jtsvr**cn'*is
I «4 ft A tfib A, I J •
r.fc.T£lU	 -^-cnati.
<-• "J
:r< c •
7
its to* '
¦** *

iw«rrI-

TSA/ACD Source Sampling
Page 11 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Is the correct sampling train being used? Sampling train
should include: filter, XAD-2 trap, empty impinger, 2
impingers containing water, an empty impinger, and one
impinger containing silica gel; all impingers submerged in
ice bath.
Is the use of sealing grease avoided on the sampling train?
Is the gas cooled to 20°C before passage through XAD-2
trap?
Are the filters and XAD-2 resin precleaned before use (for
instance, by Soxhlet extraction)?
Are reagents used in the field blank-checked? At what
frequency?
Is a train blank generated?
Specify frequency.
Have any through-the-probe matrix spikes been performed?
If yes, were the results acceptable?
If not, are any planned?
Have any through-the-probe zero checks been performed?
If yes, were the results acceptable?
Compliance

N
fvt
tJ
/J
kj
NA
QAPP Reference
f	t ?-'*CJ *,rj *
fti Aoo 4 It CO* o c
Comments

'"f¥,

TSA/ACD Source Sampling
Page 12 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
FILLI) ACTIVITIES TECHN1CA
Requirements Based on Procedures Established in QAFP
If not, are any planned?
Modified EPA Method 0040 (VOCs)
Are all procedures and QA protocols as specified and
outlined in Method 0040 being followed? (-with the oKeepluyi
iitstrad-oi^sdtertegs)-
Is sampling occurring isokinetically?
-	If not, specify sampler flow rate.
Is the sampling apparatus capable of removing moisture and
other condensable components of the gas stream before
collection in the sampling vessel?
Are all chemicals and reagents of a quality sufficient so as to
minimize interferences and background signals so that
project objectives can be achieved?
Is a train blank generated?
Specify frequency,
1 lave any through-the-probe matrix spikes been performed?
-	If yes, were the results acceptable?
If not, are any planned?
SYSTEMS AUDIT"CHECKLIST
Compliance

N
lO
rj
NA
Vi
KJ
/J
QAPP Reference
B2.8
Comments
MtTtfi. v £t . r *~t .
ijo KtrJ'€*'-> C A**:
T)na^o-X TW* t"
<3 aj<(*¦ *» ^ ?£>v* O

TSA/ACD Source Sampling
Page 13 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10,2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Have any through-the-probe zero checks been performed?
If yes, were the results acceptable?
If not, are any planned?
ACB Bed Temperature
Is the ACB bed temperature using K-type thermocouples?
How are the measurements being recorded?
Is the optional infrared pyrometry being performed?
How are the measurements being recorded?
Wood and ACM Feed Rate
Are the weights of the feed material being recorded in the
test log book?
Wood and ACM Burning Weight Loss
Is the weight of the ACB recorded during the test?
Ash sampling
Is the ash residue from the AC'D collected after each test run?
If yes, how is this documented?
Compliance
nJ
V
N
NA
QAPP Reference
B2.9
li2.10
B2.ll
B2.1.4
Comments
SH i	t	M f.A
%C&HTiatoi (;4ct4 5 iiifi t-f

v/fiMM of
4ftflffl *"•¦>
$•£4.Lit ajoT
Mf.At'-'M	L,nfS.
CMjU&tPSQ f
	CfJg/tM ijtJir,	2/U*Jr <¦ At**}
-4
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test"
December 10, 2009
__—
FIELD ACTIVITIES TECHNICA1
U SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
QAPP Reference
Comment

Y
N
NA

Are sampling implements and containers kept clean and free
of contaminants?
Grab Samples
Arc samples of wood fuel, vinyl tiles, and transite siding
being randomly selected and pieces being stored in labeled
jars?
Burn Hut Wipe Samples
Has a 1 ft x 1 ft square been marked off under the exhaust
vent been marked off on the A1 foil for obtaining wipe
samples?
Are wipe samples beinu collected? Has one been collected
in the same 1 ft x 1 ft square after completion of each bum?
Has one wipe sample been collected after completion of all
ACM tests after the Al foil has been removed and vacuum
cleaned?



B2.1, B2.1.1,
B2.1.2, B2.1.3
B2.1.5
to" £ 5 7" <> * / Jp_
OixJSt/jra I'M "fkt
A Ffff* C*»(. ri
TSA/ACD Source Sampling
Page 15 of 18
-------
FIELD TECHNICAL SYSTEMS AUDIT - "Pilot-Scale Air Curtain Burner Performance Test''
December 10,2009
FIELD ACTIVITIES TECHNICAL SYSTEMS AUDIT CHECKLIST
Requirements Based on Procedures Established in QAPP
Compliance
N
NA
QAPP Reference
Comments
VII. Other non-critical measurements
Are the local meteorological conditions (temperature,
relative humidity, wind speed and direction) being
recorded/captured?
Are local measurements of PM and asbestos concentrations
being captured/recorded?
B9
A'fA*- "i-M-jsi kl^ST
QA checklist prepared by: Ken Cowen, Battelle
Under contract to Neptune, Inc. for the US EPA, ORD/NRMRL
TSA/ACD Source Sampling
Page 16 of 18
-------
1. Scope and Application
The purpose of this method is to provide a procedure for obtaining real-time particle
size distributions (PSDs) using the Model 1000XP Wide-Range Particle Spectrometer
(WPS) (Figure 1). The WPS is a general purpose, high-resolution aerosol spectrometer
that combines the principles of differential mobility analysis, condensation particle
counting and laser light scattering to measure the diameter and number concentration of
aerosol particles in the 0.01 to 10 • m (10-nm to 10,000-nm) particle diameter range.
AEROSOL
IONIZER
LASER PARTICLE
SPECTROMETER
o
DIFFERENTIAL
MOBILITY
ANALYZER
PUMP FILTER
PARTICLE COUNTER
Figure 1. WPS Instrument Schematic.
2. Summary of Method.
The Model 1000XP WPS is a general purpose, high-resolution aerosol spectrometer
that combines the principles of differential mobility analysis, condensation particle
counting and laser light scattering to measure the diameter and number concentration of
aerosol particles in the 10-nm to 10,000-nm particle diameter range. The differential
mobility analyzer (DMA) and the condensation particle counter (CPC) can measure
aerosol size distributions in the 10-nm to 500-nm particle diameter range in up to 96
channels. This technique will be referred to as Differential Mobility Spectroscopy
(DMS). The laser particle spectrometer (LPS) can measure aerosol size distributions in
the 350-nm to 10,000-nm particle diameter range using 24 additional channels.
Therefore, the WPS covers three orders of magnitude in particle diameter by combining
two particle sizing techniques in a single, energy efficient aerosol spectrometer.
3. Instrument Calibration.
-------
The Model 1000XP WPS has been calibrated at the factory to provide National
Institute of Standards and Technology (NIST)-traceable particle sizing by using
Polystyrene Latex (PSL) spheres of 100.7-nm and 269-nm (i.e. SRM 1963 and SRM
1691) from the NIST, for the DMA-CPC sizing mode. The LPS has also been calibrated
with NIST-traceable PSL spheres of 1.36 • m, 0.701 • m, 0.499 • m and 0.404 • m.
4.	Instrument Size and Power Requirements.
The DMA, the CPC and the LPS are compact devices allowing the entire system to
be placed within a small, lightweight enclosure (318 mm H x 521 mm D x 432mm W).
The Model 1000XP WPS Configuration A has a total weight of 25 kg (21 kg for
Configuration B) and requires only 135 W (100 W for Configuration B) of power during
steady state operation.
5.	Standard Operation
The operation of the Model 1000XP WPS is fully computerized. The computer
software is run on the Microsoft Windows XP operating system and is designed
specifically for the Model 1000XP WPS. Under the automated operation mode, the
computer software assumes full control of the system operation, including regulation of
flow rates, control of the CPC, DMA and LPS operating parameters, monitoring of sensor
outputs, acquisition of all system operating parameters, execution of measurement cycles
according to the loaded recipe, and data output storage. In automatic operation, the
overall sequence is as follows:
1.	Launch the program. A program selection screen is automatically launched by
powering up the WPS. It can also be started by double clicking the MSP1000XP icon on
the Desktop or from the Windows Start menu.
2.	Allow the instrument to stabilize. Wait for the required warm-up time (about 15
minutes) and check the status of the main operating parameters on the Monitor Screen.
3.	Set up the instrument by choosing or creating a measurement "recipe "file. A
recipe file contains all the parameters needed to perform a single sample or a series of
samples. This information is used by the system to set important parameters and to select
operating procedures.
4.	Start the measurement cycle. The instrument is made ready to perform a
measurement cycle by clicking the Start button. When loading a recipe wait until the
upper green box on the Setup Screen shows the message READY. A STANDBY
message indicates that the instrument is not ready for making measurements.
5.	Look at the measured size distribution in real time. During a measurement cycle it
is possible to look at the size distribution measurement in real time. Click the Graph Icon
on the right hand side of the Setup Screen. The X and Y axes can be selected after a
measurement has been performed as described below by clicking the right button of the
mouse.
6.	Transfer/export the data files to a remote computer. Once a measurement cycle
has been completed the recorded data files can be transferred to a remote computer by
connecting the WPS serial port (RS232) to a remote computer serial port using the null-
-------
modem cable and by clicking the Remote Control Icon followed by the Null Modem
selection.
7. End the program.
6.	Sample Collection
This instrument will be used to conduct non-critical, real-time PSD measurement to
investigate combustion emissions using the Air Curtain Burner (ACB), subject to changes
in process parameters such as input material. For the testing of the burn operation, the
WPS probe was inserted into the 6-inch NPT stainless steel sample duct at a location co-
located with one of the other samples (i.e., Port 1 through 5) and was connected to the
WPS through a short length (1.22m) of Tygon® tubing to minimize wall losses.
7.	Sample Results
WPS measurements were taken during the vegetative and construction debris field
tests using the ACB. Background samples were taken upwind from the ACB and
represent the average results of 21 sample runs (Figure 2). The WPS configuration for
these sample runs are as follows: (1) wide scanning mode to obtain PSD information
ranging from 0.01 to 10 micrometers and, (2) an instrument sample time of 96 seconds
followed by a 30 second wait before starting another sample run.
The curve-fitting algorithms in the WPS software (lognormal distribution
assumption) revealed the following PSD characteristics: geometric mean particle
diameter (dgm) = 0.049 • m, geometric standard deviation (• g) = 2.6. The average
number and mass concentrations (density assumed to be 1 g/cm3) for these samples was
5.5 X 104 particles/cm3 and 3.1 X 102 • g/m3, respectively. As will be seen, these
concentrations were several orders of magnitude lower than the particles formed when
burning vegetative and construction debris from the ACB.
-------
C:\Program Files\WPSCommander\Data\20080S260705.SWS
5.0e+3 --
4.0e+3
S, 3.0e+3 -¦
2.0e+3 --
1 ,0e+3
O.Oe+O
10""
H1
10"1
Particle diameter (pm)
10u
10'
Data Statistics





Number
Length
Surface
Mass
Mode (fttn)
3.978e-2
1.411e-1
AASAe-1
9.487e+0
Mean (|im)
7.124e-2
1.597e-1
9.342e-1
5.483e+0
Std. Dev. (|im)
7.941 e-2
3.517e-1
2.061 e+0
3.11Ge+0
G. Mean ([tin)
4.997e-2
1.029e-1
2.862e-1
3.224e+0
GSD
2.271 e+0
2.387e+0
3.675e+0
3.944e+0
Tot. Y Value
5.519e+4
3.932e+3
1.973e+3
3.072e+2
Fitting Parameters



Number
Peak #1
Peak#2
Peak#3
Peak#4
G. Mean (|im)
4.852e-2
O.e+O
O.e+O
O.e+O
GSD
2.599e+0
O.e+O
O.e+O
O.e+O
Tot. Area
3.943e+3
O.e+O
O.e+O
O.e+O
Rel. FWHM
2.755e+0
O.e+O
O.e+O
O.e+O
Peak Value
3.791 e+3
O.e+O
O.e+O
O.e+O
R2
9.87e-1



Figure 2. Background particle size distribution results (average of 21 samples taken
on June 26 from 0705-0749).
-------
Measurements taken during the operation of the ACB are illustrated by the following
figures. Figure 3 shows the average results of 120 runs during the vegetative debris burns
while Figure 4 shows the average results of 43 sample runs for the construction &
demolition (C&D) debris burns. The WPS configuration for these sample runs were the
same as that used during the background measurements.
For the vegetative burns (Figure 3), there appears to be three distinct modes.
Although the entire mode is not visible, a nucleation mode appears to show the right-
hand side of the PSD. The peak of the nucleation mode was not apparent because it was
outside the operational range for the DMS (i.e., < 0.01 • m). An accumulation mode is
also apparent. The curve-fitting algorithms in the WPS software (lognormal distribution
assumption) revealed the following PSD characteristics: dgm = 0.08 • m, • g = 1.73. The
left-hand side of another, more coarse mode is also visible. Unfortunately, the bulk of the
PSD for this mode appears to be located at a point corresponding to the overlap range of
the two instruments (i.e., upper particle size limit for the DMS and lower limit for the
LPS). As such, particle measurement was not optimal. The average number and mass
concentrations (density assumed to be 1 g/cm3) for these samples was 4.8 X 107
particles/cm3 and 3.9 X 105 • g/m3, respectively.
For the C&D debris burns (Figure 4), there also appears to be several modes in the PSD.
As was evident in the vegetative burn, the right-hand side of the nucleation mode and the
left-hand side of a coarse mode was visible although the peaks of each mode were not
apparent for the reasons previously described. Interestingly, the presence of two distinct
modes corresponding to the accumulation mode (i.e., particles formed primarily through
coagulation processes). The curve-fitting algorithms in the WPS software (lognormal
distribution assumption) revealed the following PSD characteristics for the first mode:
dgm = 0.054 • m, • g = 1.47. The characteristics of the second mode were as follows: dgm =
0,14 • m, • g = 1.32. Whether this is a real phenomena or an instrument artifact is a
subject of current debate. The average number and mass concentrations (density
assumed to be 1 g/cm3) for these samples was 4.8 X 107 particles/cm3 and 1.5 X 105
• g/m3, respectively.
Another purpose of the WPS measurements was to evaluate the temporal changes
of the PSD. Time-stamped video of the ACB operation will be provided by Region 6 that
will allow a comparison of the instrument readings to activities taking place during the
field tests (e.g., material addition). Receipt of this video will allow a more thorough
analysis of the PSD during the ACB field tests.
-------
C:\Prograrn Files\WPSComrriander\Data\200806250732.SWS
5.0e+6 -
4.0e+6
S, 3.0e+6 -¦
2.0e+6
1 Oe+6
O.Oe+O
10"1
Particle diameter (pm)
Data Statistics





Number
Length
Surface
Mass
Mode (fttn)
A.ASAe-l
AA8Ae-1
AASAe-1
4.484e-1
Mean (|im)
1.5 3 7 e-1
2.772e-1
3.631 e-1
5.13e-1
Std. Dev. (|im)
1 378e-1
1,5^3e-1
2.333e-1
7.202e-1
G. Mean ([tin)
9.649e-2
2.232e-1
3.26e-1
¦1.059e-1
GSD
2.863e+0
2.126e+0
1.636e+0
1.685e+0
Tot. Y Value
4.758e+7
7.313e+6
S.3S9e+S
3.855e+5
Fitting Parameters



Number
Peak #1
Peak#2
Peak#3
Peak#4
G. Mean (|im)
8.095e-2
O.e+O
O.e+O
O.e+O
GSD
1,73e+0
O.e+O
O.e+O
O.e+O
Tot. Area
2.115e+6
O.e+O
O.e+O
O.e+O
Rel. FWHM
1,383e+0
O.e+O
O.e+O
O.e+O
Peak Value
3.543e+6
O.e+O
O.e+O
O.e+O
R2
9.053e-1



Figure 3. Particle size distribution results for the vegetative debris burns (average of
120 samples taken on June 25 from 0732-1150).
-------
C:\Prograrn Files\WPSCommander\Data\20080E251622.SWS
5.0e+6 --
4.0e+6
O
g, 3.0e+6 --
Q_
Q.
ZJ)
o
—I
| 2.0e+6 --
"C
1,0e+6 --
0.0e+0
Tni

10^
10"1
Particle diameter (pm)
10"
101
Data Statistics





Number
Length
Surface
Mass
Mode (fttn)
5.386e-2
AA8Ae-1
^.^8^e-1
4A84e--\
Mean (|im)
1.018e-1
1.91 9e-1
3.1 e-1
4.009e-1
Std. Dev. (|im)
9.579e-2
1.506e-1
1.678e-1
3.083e-1
G. Mean ([im)
7.579e-2
1.398e-1
2.5546-1
3.603e-1
GSD
2.082e+0
2.26e+0
2.007e+0
1.61 Se+0
Tot. Y Value
4.832e+7
¦1.91 7e+G
2.9G5e+E
1.532e+5
Fitting Parameters



Number
Peak #1
Peak#2
Peak#3
Peak #4
G. Mean (|im)
5 Me-2
1 36e-1
O.e+O
O.e+O
GSD
1.467e+0
1,323e+0
O.e+O
O.e+O
Tot. Area
2.067e+6
9.888e+5
O.e+O
O.e+O
Rel. FWHM
9.332e-1
6.702e-1
O.e+O
O.e+O
Peak Value
4.955e+6
3.249e+6
O.e+O
O.e+O
R2
9.93Be-1



Figure 4. Particle size distribution results for the C&D debris burns (average of 43
samples taken on June 25 from 1622-1754).
-------
vvEPA
United States
Environmental Protection
Agency
PRESORTED STANDARD
POSTAGE & FEES PAID
EPA
PERMIT NO. G-35
Office of Research and Development (8101R)
Washington, DC 20460
Official Business
Penalty for Private Use
$300
-------

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