m m ^tosr<* Environmental Monitoring and Support Laboratory Las Vegas Third Quarter — July, August, September 1976 ------- THIRD QUARTER REPORT OF THE ENVIRONMENTAL MONITORING AND SUFPORT LABORATORY LAS VEGAS July through September 1976 U.S. ENVIRONMENTAL PROTECTION AGENCY OFFICE OF RESEARCH AND DEVELOPMENT ENVIRONMENTAL MONITORING AND SUPPORT LABORATORY LAS VEGAS, NEVADA 89114 ------- CONTENTS Page EVENTS OF GENERAL INTEREST 1 BIOLOGICAL MONITORING 3 MONITORING SYSTEMS DEVELOPMENT 5 EQUIPMENT AND TECHNIQUES DEVELOPMENT 6 MONITORING 11 QUALITY ASSURANCE 15 TECHNICAL SUPPORT 17 SCIENTIFIC AND TECHNICAL REPORTS 20 OFFICE OF RADIATION PROGRAMS-LAS VEGAS FACILITY 22 ------- EVENTS OF GENERAL INTEREST On September 12, Dr. Delbert S. Barth, Director of the Envi- ronmental Monitoring and Support Laboratory-Las Vegas since 1972, was named Deputy Assistant Administrator of the Office of Health and Ecological Effects, Office of Research and Development, at EPA Headquarters in Washington, D.C. Appointed as Acting Di rector of the Laboratory, effective August 1, was Mr. George B. Morgan, Di rector of the Laboratory's Monitoring Systems Research and Development Division. Dr. Richard E. Stanley, Deputy Di rector of the Division, was named that Division's Acting Director. On July 31, Mr. John R. McBride, Acting Laboratory Di rector at the time and long-time Deputy Di rector of the Laboratory, re- tired from a 35-year Federal career to become a private consultant in environmental protection and nuclear safety. In one of his last official duties, Mr. McBride awarded the EPA's Bronze Medal to 11 off-site radiological monitoring person- nel of the Laboratory's Monitoring Operations Division. The award was presented in recognition of continued outstanding performance in carrying out a radiological safety program in the pub1ic areas around the Nevada Test Site and other sites of underground nuclear testing. Dr. Stuart Black, Senior Scientific Advisor at the Laboratory, was detailed to the Off ice of Health and Ecological Effects at EPA Headquarters for a 1-month term effective July 21. Dr. Bruce Wiersma of the Laboratory's Pollutant Pathways Branch, Monitoring Systems Research and Development Division, is the EPA Project Officer on a joint Poland/United States research program being conducted with the Environmental Pollution Abatement Center, Katowice, Poland. The program is to study the interact ions of gaseous air pollutants and trace elements and their associated impact on plant uptake and soil contamination. Dr. Wiersma was in Katowice September 10 through 19 accompanied by Dr. Clyde Frank of the University of Iowa. Dr. Frank, Professor of Analytical Chemistry at the Institute of Agricultural and Environmental Medi- cine , assisted Dr. Wiersma as a consultant on analytical chemistry. Messrs. Noel Lance and John Franklin of the General Accounting Office, Los Angeles District, conducted a month-long study at the Laboratory beginning July 21, They reviewed the Laboratory's radiation research and field studies in terms of the regulatory 1 ------- and standard-setting functions of the EPA. They also made an over- all survey of programs at the Laboratory. PROFESSIONAL MEETINGS The Monitoring Siting Workshop, sponsored jointly by the Of- fice of Monitoring and Technical Support of the EPA's Office of Research and Development and the EPA's Office of Air Quality Plan- ning and Standards, was held at the Laboratory July 12 through 16. The aim was to review present and future criteria for the siting of monitoring stations to meet specific objectives of the Clean Air Act and to prepare a written report setting forth the general consensus of the participating group. Attendees included repre- sentatives of EPA's operational, regulatory, research, and Regional monitoring programs, State and local monitoring agencies, univer- sities, and industry. On September 19 through 22, Mr. Morgan and Dr. S. Harvey Me If i, Director of the Remote Sensing Division, and Mr. John Eckert, Chief of the Division's Remote Monitoring Methods Branch, attended the National Bureau of Standards Eighth Materials Research Symposium in Gaithersburg, Maryland. Mr. Morgan and Mr. Eckert presented papers there. OTHER MEETINGS Mr. Walter E. Petrie, Director of the Laboratory's Program Management and Support Staff, attended the Annual Planning and Management Conference in New Orleans, Louisiana, on July 14 through 16. On July 7 and 8, eight members of the Environmental Measure- ments Advisory Committee met with Mr. Morgan, then Director of the Monitoring Systems Research and Development Division, and members of his staff. The committee was briefed on Laboratory operations, including Laboratory instrumentation and its functions, during a tour of the facilities. The committee was especially interested in documents prepared on EPA problems which the Division had di- rectly helped to solve. They were interested in the Division's approach to solving those problems and in how the Division inter- acts with EPA Regional offices and other Laboratories. The Electric Utilities Working Sector Group and the Advanced Fossil Fuels Sector Group of the EPA Office of Energy, Minerals, and Industry held a joint meeting at the Laboratory on August 24 and 25. Dr. John Santolucito, Acting Deputy Director of the Monitoring Systems Research and Development Division, briefed the visitors on the relationship of biological research to the Divi- sion's efforts in developing integrated monitoring systems. The group was especially interested in Laboratory research on devel- oping biological indicators of pollutant exposure and the animal investigations at the experimental farm the Laboratory operates on the Nevada Test Site. 2 ------- BIOLOGICAL MONITORING CURIUM A study of the biological transport of curium in dairy cows was conducted at the Nevada Test Site farm. Preliminary results indicate that the total curium excreted in the urine and feces was approximately 9 percent of the administered dose compared to 4.5 percent for plutonium in a similar study. In both of these studies, the experimental animals were administered acute intra- venous citrate-buffered doses of either curium or plutonium. As expected, the urinary excretion of curium was much greater than that for plutonium. The percent of the curium dose secreted in the milk was slightly less than 2, but was over 6.0 percent greater than the percentage of the plutonium dose secreted in the milk in an earlier study. A basically similar excretion and secretion pat- tern was noted in experiments using dairy goats that had received doses of either curium or plutonium. LEAD AND CADMIUM The transport of toxic trace elements in geothermal effluents requires the design of experiments to study the transport of such materials in biological systems. Lead and cadmium have been se- lected as two cations for preliminary experimentation. This study was designed to develop surgical and analytical methods to quan- titate the absorption, excretion, and placental transfer of lead and cadmium in rats. Fifteen pregnant rats were exposed to lead in drinking water. Of these, 11 gave birth to 75 young, some of which were sacrificed to determine their total lead content. The remaining young either remained with their mothers or were placed with foster mothers, i.e., young from lead-ingesting mothers were placed with mothers not receiving lead, and young from mothers not receiving lead were placed with lead-ingesting mothers. Upon wean- ing, some of these young were sacrificed and others will continue to receive lead in their drinking water. Samples of blood and hair are being collected periodically. Analytical methods are being tested to arrive at the best procedure for determining the lead content of these samples. Surgical techniques for cannulating the bile ducts of juvenile rats are being developed. MERCURY Recent findings from a continuing study of mercury in soil systems confirmed that the transformation process of ionic mercury 3 ------- lo methy1 mercury is primarily caused by abiotic factors. By using a series of special separatory techniques and gas chromatography, the principal methyl at ing factor was identified as being contained in the fulvic acid fraction of the soil system. Recent findings from a continuing study of the transformation of elemental mercury into methylmercury by plant systems indicate that pea plants, after exposure in chambers to elemental mercury, developed significant quantities of methylmercury in their tissues, It was also determined that the transport of mercury from plants exposed via the leaves resulted in mercury residues being detected in the roots of plants; this indicates that the plant system is capable of transporting mercury both from the leaves to the roots as well as from the roots to the leaves. ANIMAL INVESTIGATION During the spring, summer, and fall, a large herd of mule deer resides at the higher elevations of the Nevada Test Site. This herd migrates to unknown areas during the winter. The whereabouts of these mule deer is of interest to both the U.S. Energy Research and Development Administration and the State of Nevada Department of Fish and Game on the remote possibility that some of these deer may contain elevated radionuclide concentrations and may be har- vested by hunters. However, this interest is of a precautionary nature since the results of a continuing long-term study have not shown any significant radionuclide concentrations in the edible tissues of mule deer collected from the NTS herd. During this quarter, 11 mule deer were captured and outfitted with collars containing radio transmitters with the ability to transmit for about 1 year. The movement of the deer is periodically monitored to determine their migration patterns. As yet, none of these deer have left the NTS and roost have remained within the locality of their capture. 4 ------- MONITORING SYSTEMS DEVELOPMENT A study of a plutonium-uranium oxide fuel fabrication facil- ity in Pennsylvania was recently completed. In this study, the chemical and physical characteristics and quantity of the radio- nuclide emissions were determined. A report on the results of the study is being prepared. The Laboratory coordinated an EPA contract research project concerning the quantification of trace metal pathways on a region- a1 scale. From this study, Mr. Cliff Davidson of the California Institute of Technology prepared a report, "The Deposition of Trace Metal-Containing Particles in the Los Angeles Area." Mr. Davidson was awarded the first Lincoln T. Work Award for this work by the Fine Particle Society in recognition of his "outstanding independent research in the fie1d of fine particle behavior." In a study designed to assess available water monitoring data in the Western Uni ted States and establish baseline con- ditions, evaluate the impact of present. energy development and predict the impact of proposed developments on water quality, a "primary" water quality network from existing monitoring stations has been identified. The network consists of long-term, data-rich stations located through an inventory of STORET, the United States Geological Survey, and other data sources. Available data from the network are being analyzed to determine baseline conditions, present trends, and deficiencies in the sampling network. The major water basins to be surveyed in this study are the upper and lower Colorado and the upper Missouri regions. After lengthy as- sessment and man ipulat ion of data, along with augmentation of primary network stations where necessary, basin-by-basin water quality status reports will be prepared. 5 ------- EQUIPMENT AND TECHNIQUES DEVELOPMENT ANALYTICAL TECHNIQUES Development of a method to determine iron-55 in various types of environmental samples continued. By optimizing a liquid scin- tillation counting technique and improving an existing separation scheme, a minimum detectable concentration of approximately 500 picocuries of iron-55 per gram of iron in the sample can now be obtained. The minimum detectable concentration of iron-55 in en- vironmental samples will thus depend on the amount of stable iron in the samples. In an effort to improve the yield determination for thorium analyses, thorium-234 is being evaluated as a tracer spike. The tracer yield is determined by measuring the beta activity of the thorium-234. This is accomplished prior to the alpha spectral analysis of the other thorium isotopes of interest. Interference by progeny beta emissions and the short half-life of thorium-234 are the most serious obstacles at this point in the development. At the request of Dr. John Moran of the EPA's Office of Monitoring and Technical Support, the applicability of the gas chroma tog rapli microwave emission spectrometer for identifying vaporous metal species in environmental samples was determined. Using the spectrometer system to analyze for compounds of platium, antimony,' arsenic, and lead in environmental samples was of par- ticular interest. Analytical techniques were developed for making optimal trace metal determinations for the compounds of interest. A method was developed and modifications were made to the in- strument to make possible reliable and sensitive platinum compound determinations. This capability will be needed for platinum com- pound pathways study. The Laboratory has acquired a new instrument that can simul- taneously analyze a liquid sample for two different elements in about 5 minutes. The instrument, called a plasma emission spectro- meter, sprays the liquid sample into very hot ionized argon gas (plasma) which causes the sample to break down into elements. In the 8,000° K heat, the elements emit light. The wavelength, or color, of the light emitted is characteristic of the element. The light is broken into the spectral wave length using a diffraction grating. A given wavelength of light always appears at the same location on the spectrum. Photomult iplier tubes, which detect light and convert it to electricity, are placed at the 23 locations 6 ------- along the spectrum where light will be produced when any of the 23 elements being sought is present. A computer can identify the element from the photomultiplier tube it excites and can measure its concentration from the intensity of the light. Actually, each element emits several wavelengths of light. In designing the in- strument one wavelength that would be unlikely to be produced to any great extent by other elements in the samples was chosen 1 or each element. The small interferences that do exist are taken in- to account in a computer program before the results are printed out. DATA INTERPRETATION The contract for a computer-based gamma data acquisition and formatting system was awarded to Nuclear Data Corporation in August. Delivery will be made within 120 days. The system is expected to provide a high degree of reliability in data ac- quisition and handling. Downtime is expected to be minimal be- cause most of the crucial components are interchangeable and can be bypassed if a component fails. For example, all three com- puters used in the system are identical and may be switched in seconds if failure of any one computer occurs. The system will benefit the entire counting laboratory operation by streamlining data acquisition, handling, transmission, and reduction. In addition, this system will be interfaced with the U.S. Energy Research and Development Administration's CDC 6400 computer lo- cated in Las Vegas thus facilitating data transmission and read- out . In the project to develop environmental keys for interpreting aerial photographs, all available photo-interpretation keys are being surveyed and cataloged by the Laboratory. Accomplishments during this quarter include final selection of prints and format for the Harbor Key, field verification of target landfills in Maine using applicable keys, and the preliminary use of landfill keys on operational programs involving enforcement actions in Region I. Efforts were also made to correlate sulfur dioxide emissions with vegetation stress in an Arkansas project. A helicopter-borne team collected water samples and made relevant measurements in and on Lake Mead on July 9, August 4 and 5, and August 23 and 24 for the Trophic Classification of Lakes Utilizing Contact and LANDSAT Data Study. On July 9 and August 24 the National Aeronautics and Space Administration flew an Ames Research Center aircraft over the lake to collect coin- cident data with a rapid scanning spectrometer and the NASA Johnson Space Center provided an overflight on August 5 to col- lect photography using two aerial mapping cameras. The data collected from these flights will be compared with data from the LANDSAT-1 experimental satellite in a continuing study to investigate the feasibility of using LANDSAT multispectral scanner data in conjunction with contact water data in lake water quality classification work. 7 ------- REMOTE MONITORING TECHNIQUES Federal Aviation Administration Dynamic Flight Tests were completed in the project to test and demonstrate the concept of operating a photographic pod with multisensor capabilities on a light aircraft. Update of engineering drawings according to FAA specifications as requested by the FAA was also initiated and is 80 percent completed. Initial flight tests were made with mini- pan cameras loaded to evaluate the pod. Aerial infrared scanner survey techniques are being developed to quantitatively determine ground temperatures which are dis- played on isothermal contour maps. To date, telemetry receiver and droppable temperature sondes have been installed in aircraft and test flights are being planned to check out operating methods and performance, A dye laser f1uorosensor, installed in a Huey helicopter, is being used to collect data on chlorophyll a and turbidity on Lake Mead. Though not confirmed with ground truth data, systematic changes in the chlorophyll fluorescence signal are consistent with known conditions in the Lake. Flights are planned to produce a calibrated contour map of surface chlorophyll concentrations in the Las Vegas Bay region of the Lake. Plans are also in progress to evaluate new laser dyes to excite specific targets for tracing, such as controlled dye releases and blue-green algal blooms. Phase 1 of the project to quantitatively determine turbidity through the use of aerial multispectral techniques was completed. This included (1) taking water samples and collecting spectrometer data near the water surface to measure sediment concentration and (2) collecting spectral water samples arid spectral data at various altitudes. The results of ground measurements were then compared to the results of aerial measurements to develop techniques for correcting atmospheric absorption and scattering that cannot be accounted for with data collected at the water surface. A basic relationship that needs to be verified is that volume spectral reflectance measured remotely can be related to sediment concen- tration in water bodies and obtain the resultant correlation co- efficients. A data system for this project, using a rapid scan- ning spectrometer, will be installed and field-tested during the next quarter. The Laboratory is also investigating the feasibility of using an airborne system to image non-visible gases such as sulfur dioxide, carbon monoxide, carbon dioxide and water vapor. Remote aerial thermal measurements were used to image what is believed to be sulfur dioxide emitted from a copper smelter exhaust stack. However, extensive ground truth data are needed to support the conclusions reached to date. Preliminary indications suggest a potential use of the technique for rapid determination of non- visible gases in areas requiring supplemental investigation. 8 ------- In the design of the Airborne Infrared Earth-Reflected Dif- ferential Absorption system for mapping gaseous pollutants and tracers, a laboratory laser and cells for checking candidate tracers were set up and tested. An ozone system is now being tested and sample returns suitable for measurement of atmospheric ozone have been obtained. Ground tests and preliminary flight tests of the ozone device should be completed during the next quarter. A method is being developed to use aerial photographs to measure the opacity of stack plumes in terms of Clean Air Act requirements. To date several plant stacks have been photographed and reference points established to validate statistical inter- pretation methods. In developing the Two-wavelength Downlooking Airborne L1DAR System for further characterizing power plant plumes, optical/ mechanical portions of the design were completed. The assembly includes a telescope using a mirror in a Newtonian configuration, a laser assembly, and two photomul tip 1iers to separate the two frequencies. The assembly, to be constructed by a contractor, will be completed by January 1977. In the electronics portion of the design, a systems chart has been produced detailing the electronics subsystem which will transform the signals to a real- time two-color display, record the data, and provide overall control to the device. The device, when ready for testing, will be automated to the point of giving maintenance warnings and will be used not only in characterizing urban effluent plumes but also in preparing detailed maps of the plumes. In the development of a monitoring method for determining the impact of mining operations on the environment, manual photo- interpretation of eight existing and proposed mining sites has been completed. In this project, color and color infrared imagery are used. Current effort in the study to apply fluorescence spectros- copy in detecting sub-visual vegetation stress induced by atmos- pheric pollutants is applied to resolving problems in measuring the fluorescence spectra of leaf samples. No significant changes have been observed in the fluorescence spectra of stressed leaf samples with respect to controls when exposed to sulfur dioxide and ozone. However, changes in the amplitude in the fluorescence emission of stressed leaf samples have been observed. Studies are continuing with a view to correlating these changes with pollutant type and concentration and with duration of exposure. An H-34 helicopter with associated air quality and avionics equipment was overhauled in preparation for the Anaconda, Montana, Smelter Study, scheduled to begin October 1. In addition, two helicopter-transportable sulfur dioxide (SO2) monitoring systems were constructed and a mathematical program was developed to 9 ------- determine the correct concentration input to the various air qual- ity instruments from their known responses and transfer function. The purpose of the project is to measure plume rise, horizontal and vertical dispersion coefficients and center 1ine concentrations of the plume from the copper smelter at Anaconda, and to obtain ground level S0Z concentrations averaged over 3-hour and 24-hour periods during those times when the plume is at or near the sur- face of elevated terrain in the vicinity of the smelter. The data collected will be used by Region VIII to validate the EPA Valley Mode 1. 10 ------- MONITORING AIR In the Aircraft Emissions Impact Monitoring Study, collection and processing of air quality data at Williams Air Force Base, Arizona, begun June 1, continued through this quarter. The aim is to test the ability of existing air quality simulation models to estimate the air quality impact of airport emissions. This five-station air quality monitoring study is being conducted by Laboratory personnel in cooperation with the U.S. Air Force Civil Engineering Center and the Argonne National Laboratory. During July and August the summer field portion of aerial data collection for the Regional Air Pollution Study (RAPS) was completed in St. Louis, Missouri. The helicopters flew over 200 mission hours and obtained data for a number of investigators. Preparations are now underway for the final RAPS Intensive Field Study Period which is scheduled for October 25 through November 19. On completion of the mission, the Laboratory's St. Louis operations base will be vacated and work will begin on the final report for the entire RAPS helicopter data collection operation from 1974 through 1976. The Western Energy Resource Development Area Study, a program to evaluate the present and future air quality impact of energy- related development in the western United States, was begun with the performance of an initial inventory of present and proposed energy-related air quality emissions sources, meterological ob- servation stations and air quality monitoring stations in the project area. The 28 stations of the Ute Research Laboratory air quality network in Utah have been placed into full operation and the Laboratory's Air Quality Monitoring B-26 aircraft began wide-area monitoring flights in central Utah to develop optimum flight paths for future monitoring. Contracts have been made with the Ute Laboratory and with the University of California at Davis for analyses of air quality samples. WATER In the Atchafalaya Basin Study, intensive sampling of selec- ted water qualify management units (Pat's Bay, Henderson Lake, and Buffalo Cove) was conducted on a monthly basis using small boats. This program of sampling key management units will 11 ------- continue on a monthly basis, and synoptic water quality sampling of the Basin from a helicopter is scheduled for the next quarter. In August, a helicopter team collected samples from 116 sampling sites established through the Basin to provide synopt ic water quality data. Additionally, samples were collected in the major inlets (Old River, Red River, and Atchafalaya River) and outlets (Wax Lake and the Atchafalaya River at Morgan City) of the Basin. Water samples were sent to the Las Vegas Laboratory for nutrient analysis and samples for adenosine triphosphate and organic car- bon determinations were analyzed in Baton Rouge. Productivity estimates were made in the management units. Pesticide samples were collected at four sites in the Henderson Lake area and will be analyzed for pesticides levels at the EPA facility at the National Space Technology Laboratory in Bay St. Louis, Mississippi. Draft reports for individual lakes sampled as part of the National Eutrophication Survey (NES) are in review or in the printing process for lakes in Alabama, Louisiana, Arkansas, Missouri, Oklahoma, Idaho and Tennessee. In the Phytoplankton Identification and Enumeration Study, counts and species lists for about 220 samples were per formed during the quarter. Also, quality cont. rol procedures were established to provide increased confidence in the estimates produced, and State phytoplankton species lists, complete with diversity and pollution indices, were released to Alabama and Delaware for review. These and subsequent State algae distribution wi11 be finalized as NES Working Papers. RADIATION As part of the Long-Term Hydrological Monitoring Program to monitor underground waters for potential movement of radioactivity from underground nuclear explosions, quarterly water samples were collected from 20 locations in the Project Dribble site area, near Hat t iesburg, Mississippi. Semiannual water sample collections were made at 25 locations on and around the Nevada Test Site (NTS), and monthly samples from 11 locations in Nevada were taken. As part of the program of moni toring conducted by the U.S. Geological Survey at the Project Faultless site, 12 water samples were col- lected at the site by Laboratory personnel. Projects Dribble and Faultless involved underground nuclear detonations in the 1960's for seismic detection (Dribble) and calibration (Faultless) purposes. Analysis of plutonium data f rom so i1 samples collected around the NTS indicated the need for additional samples to fill in gaps of data or to extend the area of coverage to adequately determine the distribution pattern of plutonium-239 in the NTS environs. Off-site monitoring personnel from the Laboratory col- lected an additional 150 samples from locations in Nevada and California. These soil samples are being prepared for analysis. 12 ------- Also, meteorology data and a series of high-volume air samples, both particulate and size-fractionated, were collected at three locations off the NTS during periods of rel a tively high winds. The samples were collected in areas where plutonium-239 in soil is above average for the area to determine if plutonium-239 de- posited as fallout is resuspended by the wind. A variety of fruit and vegetable samples were collected from 11 locations around the NTS as a follow-on to a similar program conducted during 1974. These samples will be analyzed for pluton ium-238, plutonium-239, and iron-55 to complete the in for- mat ion on radionuclides in locally grown foods. A specially modified atmospheric tritium sampler used in the Noble Gas and Trit ium Network was assembled, tested, and installed in Area 5 of the NTS to moni tor for tritium as tritiated water and tritiated hydrogen which might be released from a new tritium- waste storage area. The sampler uses compressed hydrogen gas as the carrier for tritiated hydrogen, replacing the electrolysis cell using antique water, and is designed for battery operation rather than line power. Using two types of recording exposure rate systems and ther- moluminescent dosimeters (TLD) in a typical field environment, a special radiation dosimetry study was begun to compare measurements of external gamma exposure rates and integrated exposures. The TLD are exposed for varying lengths of time in overlapping periods to determine the effect of length of exposure and environmental temperatures on the fade of the accumulated dose signal. In conjunction with the Off-site Human Surveillance Program which the Laboratory has conducted since 1966. whole-body counts were made on 21 persons (9 families) resident in areas near the NTS. As in the past, medical examinations of these persons re- veals a generally healthy population. The Laboratory 1s whole- body counting facility is used to measure body burdens of radioactive contamination in such off-site residents who may have been exposed to radioactivity from NTS nuclear test ing act i vities. Medical and other health physics support was provided for a large-animal radionuclide metabolism study at the experimental farm on the NTS and for a small-animal study at the Las Vegas Laboratory. The annual survey of milk cows in Nevada and Utah was com- pleted. The data were compiled into a directory published in September. Addit ionally, a special census was conducted near the NTS at the request of the U.S. Energy Research and Develop- ment Administration's Nevada Operations Office to determine human population distribution and length of residence of each person. Th is census information is col 1ected to enable response to po- tential accidental radioact ive releases from NTS nuclear testing 13 ------- activities and to measure population radiation exposures in the event of such a release. Updated maps of the Goldfield, Tonopah, Alamo, and Pahranagat Valley, Nevada, areas were prepared from aerial photographs taken by the Laboratory. These maps provide accurate information on populated locations and access routes for travel during ot'f-site (radiation release) monitoring activities around the NTS. Interim procedures were developed so that surveillance net- work data can be formatted to allow statistical analyses using the University of California Biomedical Statistical Program P-series. 14 ------- QUALITY ASSURANCE The Laboratory has implemented the FAMULUS system developed by the U.S. Forest Service for storing and retrieving information. This system allows records to be searched in a manner very similar to that required for searching a library card catalog. During this quarter, the FAMULUS computer system was successfully tested on the Laboratory's computer system. The amount and type of qual- ity assurance data to be placed in the system have been determined and the current year's data are being entered. Historic data will be entered next, starting with recent years and working backwards to the start of the program. New study data will be entered as it becomes available. Early in 1977, the FAMULUS system will be made available through the INTERCOM time-sharing computer execu- tive control system. Information searches may then be performed using cathode ray scope remote computer terminal. The use of this terminal will facilitate searches to the point where responses can be made to telephone requests for information while the caller is still on the line. INTERCOMPARISON STUDIES Reports were issued to participants in the Environmental Radioactivity Laboratory Intercomparison Studies Program for 12 different cross-check analyses: April - food; May - milk, radium-226 in water, and gross alpha and gross beta in water; June - tritium in urine, tritium in water, gamma in water, air filter, and krypton-85 in air; July - milk, radium-226 in water, and gross alpha and gross beta in water. The types of cross- check analyses and the number of participating laboratories dur- ing this quarter are shown in the following table. Type of Cross-check Air Filter Gamma in water Gross alpha and gross beta in water Milk Radium-226 in water Tritium in urine Tritium in water Food Krypton-85 in air July 65 62 31 August 65 70 25 September 55 54 57 15 15 ------- The laboratories participating in these programs include in- ternational, Federal, State, university, county, nuclear facilities and contractor laboratories. CALIBRATED SAMPLE DISTRIBUTION During this quarter, 186 calibrated samples, including 17 dif- ferent radionuclides, were distributed to user laboratories. BIOLOGICAL REFERENCE MATERIALS Arrangements are being completed for two projects designed to provide plant and animal tissues containing environmental and elevated levels of a combination of in vivo incorporated pol- lutants. The dried tissues will be used as reference material for methods standardization and equivalency determinations, in- strument calibrations, cross-check programs, and laboratory per- formance evaluations. Because the pollutants are incorporated into the reference materials in vivo, any matrix effects influ- encing analytical results of actual biological tissue samples will be minimized. In one of these projects, waterhyaeinths will be grown in hydroponics solution containing known amounts of added pollutants such as mercury, lead, arsenic, zinc, and cadmium. In the other project, young goats will be used for the in vivo incor- poration of the same pollutants into animal tissue, and a variety of tissues will be processed. 16 ------- TECHNICAL SUPPORT REGION I The following projects were conducted in Massachusetts: 1. Eight map sheets along with selected photographs were furnished locating stack emission sources in Worcester; 2. An aerial inventory was made of non-point sources in the Manchung Pond and West and Quinsigamond Rivers areas; 3. Leachate drainage from Tyngsboro landfill were identi- fied for ground sampling, for possible non-filing of point-source discharge into the Merritt River, and possible violation of land- fill operation permit; and 4. Imagery and analysis of color photographs and thermal infrared imagery were transmitted to the State Attorney General for use in court action on a landfill in Middleton. In Maine: 1. Annotated photographs and map sheets were delivered to the State Department of Environmental Protect ion providing data collected on 22 landfill sites in Windham, Gorham and Falmouth Counties for leachate and landfill practices; 2. Growth or non-growth of algae in 27 ponds and lakes was determined; and 3. Annotated mosaics of Royal and Stroud Water Rivers de- lineating potential sources of sedimentation were prepared for the Soi1 Conservation Service. REGION IV Eight map sheets with overlays of land use in Guilford County, North Carolina, were prepared and subsequently used by the U.S. Geological Survey. Eight map sheets with overlays de- picting population density by housing types were also furnished. The Florida I sothermal Survey of thermal discharge plumes from four power plants was completed. The results of a survey of duckweed in Alabama rivers were also provided to the Region. 17 ------- REGION V A reconnaissance of oil fields and refineries was begun in Southern 111 inois to determine condi t ions of tanks, dikes and containment. REGION VI Vegetation stress analysis and drainage areas affected by ethylene dibrornide plants were depicted on overlays to mosaics of the El Dorado-Magnolia and Marysvilie, Arkansas, areas. Im- agery analysis was provided as a basis for sampling and obtain- ing ground truth. REGION VI I An emission source inventory of Kansas City, Kansas, was made. The data provided include overlays keyed to map sheets and an analysis report. REGION VI I I A vegetation stress visibility project was completed with delivery of color and color infrared aerial imagery of 13 se- lected air pollution sites. The imagery intended to show synopt ic visibility, vegetation condi tions, and 1imi ted atmospheric dis- persion , An alluvial valley strip mine analysis was completed with delivery of color and color infrared imagery to determine the percentage of western strip mines that lie in alluvial valleys. Partial delivery was made of color and color infrared imagery of 90 strip mines located in Region VIII States. Forty of these mines were covered using data from aerial imagery archives. A partial delivery was also made of color and color infrared photographs showing Jackson and Jackson Lake, Wyoming, to locate and classify sediment loading in 170 miles of streams in the area. A water quali ty field survey was conducted in the San Juan River Basin to help assess the impact of present and proposed energy resources development in the Four Corners area and Lake Powell area. The data have been entered into the STORET system and are undergoing review and analysis. An additional sampling survey is planned for October. REGION IX Written data and annotated color photographs were delivered to ascertain the current status of operations at a Nevada copper 18 ------- mine and smelter. REGION X A survey was made of oil storage facilities in the area of Pocatello, Idaho, and Seattle, Washington, to determine condi- tions of site and equipment for compliance with Federal regula- tions . The third phase of a land use survey of the Yakima River Valley was begun to depict silviculture activities, harvest practices and agricultural activities. OFFICE OF WATER AND HAZARDOUS MATERIALS An aerial survey was made of a chemical plant in Memphis, Tennessee, and analysis and imagery were delivered for enforce- ment use. Three overflights were made to col1ect color photography of an oil spill in the St. Lawrence-Thousand Island area. Deliveries included 400 color photos, selected en largements, and an analysis map. OFFICE OF SOLID WASTES Color, color infrared and thermal infrared imagery was col- 1ected for a non-point source inventory of the Camden and Gloucester County , New .Jersey , and New Castle County , Delaware , areas. Map sheet overlays were prepared from these data. OFFICE OF NOISE CONTROL The Laboratory participated in a feasibility study to re- fine the EPA Community Noise Model which is based on population density of a residential neighborhood. The aim was to test the concept that the density of noise in cities is directly propor- tional to population density. The Laboratory interpreted photo- graphy from sites in each of several selected major cities to explore ways to improve the model using features that can be obtained primarily from aerial photography. 19 ------- SCIENTIFIC AND TECHNICAL REPORTS EPA PUBLICATIONS During this quarter, five project reports were published. They are: "Proceedings of the first workshop on sampling geothermal ef- fluents," a compilation of papers presented at a workshop held at the Las Vegas Laboratory in October 1975 (EPA-600/9-76-001). "Biotransformation and chemical form of mercury in plants" by D. D. Gay (EPA-600/3-76-082), "Monitoring groundwater quality: Monitoring methodology" by D. K. Todd, R. M. Tinlin, K, D. Schmidt, and L. G. Everett of the General Electric-TEMPO Center for Advanced Studies, prepared under the direction of project officer G. B. Morgan (EPA-600/4-76-026). This is the third volume in a series of five manuals on groundwater monitoring. "Monitoring groundwater quality; Illustrative examples" by R, M. Tinlin, editor, of the General Electric-TEMPO Center for Advanced Studies, prepared under the direction of project officer G. B, Morgan (EPA-600/4-76-036). This is the fourth in the series of five groundwater monitoring manuals. "Procedure for evaluating operations of ambient air monitoring networks" by R. W, Schnider and E. S. Shapiro of URS Research Com- pany, under the direction of project officer E. A. Schuck (EPA-600/4-76-043). REPORTS OF ERDA-REIMBURSABLE WORK One report of work performed under the Laboratory's memorandum of understanding with the U.S. Energy Research and Development Ad- ministration (E1DA) was published. This was: "Agronomic practices of the Nevada Test Site experimental dairy farm during 1971, 1972, and 1973" by E. M. Daley (EMSL-LV-539-5>. PAPERS PRESENTED OR PUBLISHED Two papers from the Laboratory were published in scientific journals during the quarter. These are: 20 ------- "Lead: In search of the facts," by R. R. Kinnison. Environ- mental Science and Technology 10(7):644. "Analysis of atmospheric particulates for trace elements by optical emission spectrometry," by D. R. Scott, W. A. Loseke, L. E. Holboke, and R. J. Thompson. Applied Spectroscopy 30(4):392. A paper by L. R. Shuyler, D. A. CI ark, J. Barth, and D. D. Smith on "Excretion of salts by feedlot cattle in response to vari- ations in concentrations of sodium chloride added to their ration" has been published by the American Society of Agricultural Engineers in the Proceedings of the Third International Symposium on Live- stock Wastes 1975. The proceedings document is entitled "Managing Livestock Wastes" and is available as ASAE Publication PROC-275, Another paper has been accepted for publication in Health Physics. It is by A. A. Mullen, E. W. Bretthauer, and R. E. Stan- ley and is entitled "Absorption, distribution, and milk secretion of radionuclides by the dairy cow. V: Radiotungsten." Mrs. A. A. Mullen presented a paper on "Transport of intra- venously administered plutonium to milk and tissues in dairy goats" at the combined Radiation Research Society/Health Physics Society meeting held in San Francisco June 27 through July 2. At the Eighth Materials Research Symposium sponsored by the National Bureau of Standards in Gaithersburg, Maryland, September 19 through 22, Mr. George B. Morgan presented a paper entitled "Ambient air quality monitoring" and Mr. John A. Eckert presented one co-authored by D. Bundy and J. Peacock on "Development of a two-frequency downward-looking airborne LIDAR system." 21 ------- OFFICE OF RADIATION PROGRAMS-LAS VEGAS FACILITY (ORP-LVF) URANIUM MINING AND MILLING Radon Evaluations. Mr. David Bernhardt participated in a contin- uing field study at the Vitro site, Salt Lake City, Utah, to as- sess the magnitude of radon-222 releases from uranium mill tailings piles and the parameters which affect releases of radon. On September 28 and 29, he attended a meeting at the U.S. Energy Research and Development Administration Headquarters, Germantown, Maryland, concerning the radon monitoring and health effects eval- uations for Vitro and other inactive mill sites. He described the pertinent ORP programs and presented data which indicate elevated radon concentrations (tenths of picocuries per 1 iter) out to about 2 miles (3.2 kilometers). The data composited information from several studies and modeling efforts. There was a general con- currence at the meeting to include evaluations of this type in the Phase II report. Navajo Assistance. Messrs, Joseph Hans and William Moore trav- eled to Shiprock, New Mexico, on August 9, to conduct surveys and attend a meeting at the inactive uranium mill site. Final surveys were conducted in a section of the ore-storage yard, and an area which had been decontaminated to acceptable levels was marked off to receive clean fill. They held discuss ions with Navajo Engineering and Construction Authority (NECA) staff concerning the decontamination activit ies and the chain of command to be initiated after the departure of the NECA Training Director, Mr. Chris East in. Messrs. Hans and Wi11iam Fort traveled to Shiprock on September 20 through 24 to teach two Navajo Environmental Pro- tection Commission technicians how to survey the salvage steel from the mill building in order to meet the radiation require- ments provided by the New Mexico Environmental Improvement Agency. In addition, several meetings with NECA and IHS staffs were held, and radiation surveys were conducted in the ore- storage yard area. A current major part of the NECA decontam- ination program is the dismantling and removal of the old mill building. Radon sampling was again postponed because of incle- ment weather. Active Mill Study. All active uranium mills were reviewed to select potential candidates for environmental studies. Several 22 ------- candidates have been selected based on pre-determined criteria. Messrs. Richard Douglas and Fort traveled to the selected sites in Washington, Wyoming, and Texas to further evaluate and rank them according to accessibility, available power, interfering sources, topography, etc. Drs. Leonard Link and Michael Momeni from Argonne National Laboratory visited the ORP-LVF on September 15 to discuss their plans for a study at an operat ing uranium mill and to exchange information regarding our proposed study. Uranium Mine. A field study in the vicinity of the Jackpile uranium mine, near Paguate/Laguna, New Mexico, was completed on June 30. ENVIRONMENTAL PLUTONIUM Mr. Bernhardt and Mr. Raymond Johnson, Headquarters Environ- mental Analysis Division, met with Rocky Flats and other agency personne1 in Denver, Colorado, to plan a joint soi1 samp 1ing eval- uation project. This project includes evaluation and comparison of the proposed EPA, Rocky Flats, Colorado Department of Health, Jefferson County, and, possibly, Savannah River soil sampling techniques, NATURAL RADIOACTIVITY GUIDANCE On August 31 Messrs. Mike Christie and Gary Booth, Radiation Control Section, Department of Health and Welfare, Idaho, and Mr. Edward Cowan, Region X, EPA visited ORP-LVF to discuss re- sults of the Idaho phosphate study. The need for future work, especially in Soda Springs, Idaho, was also discussed. RADIOACTIVE WASTE MANAGEMENT On July 14, Mr, DonaId Hendricks accompanied Dr. Brion Sasaki of the U.S. Office of Management and Budget and Mr. Tom Castor of the U.S. Mining Enforcement and Safety Administration on a tour of the Anaconda open pit and underground uranium mines on the Laguna Pueblo Reservation, They also toured the Anaconda Bluewater uranium mill. Other mill tailings piles in the area were also viewed. On July 15, Messrs. Bruce Mann and Fort ac- companied Dr. Sasaki on a tour of the Beatty, Nevada, commercial low-level waste burial site. Mr. Mann and Dr. Robert Kaufmann met with personnel of the Headquarters Office of Radiation Programs July 28 through 30 to discuss program plans in radioactive waste management. The plan for development of Federal criteria for radioactive waste 23 ------- management and ways in which ORP-LVF staff could assist in this development were discussed, Comments were prepared on the draft paper, "Radiological Measurements at the Maxey Flats Radioactive Waste Burial Site," and forwarded to the Cincinnati, Ohio, Radiochemistry and Nuclear Engineering Branch of the ORP Eastern Environmental Radiation Faci1ity. Dr. Kaufmann began a special 2-month temporary assignment to ORP Headquarters. He will assist in the development of en- vironmental radiation protection criteria for radioactive waste management. On September 17, Mr. Mike O'Connell held discussions with Dr. Jim Duguid and other staff members of the Environmental Sciences Division, Oak Ridge National Laboratory (ORNL). The topics reviewed concerned previous low-level waste management studies at ORNL and future efforts in the area of site engineer- ing practices. These discussions were in conjunction with a recently awarded ORP contract. He also gave a seminar to the Environmental Sciences Division, ORNL, on the commercial low- level facilities including inventory projections. On September 18, he gave a presentation on the same subject at the joint meeting of the East Tennessee and Blue Grass Chapters of the Health Physics Society. On September 21 and 22, he participated in the National Conference of Radiation Control Program Directors, Inc., Radio- active Waste Task Force meeting in Bethesda, Maryland, at the request of the Task Force Chairman, Mr. Beyward Shealy. Technical evaluations have been completed on two proposals received for the low-level radioactive waste burial site engineer- ing management study. Final negotiations are now being conducted with the contractors. ENVIRONMENTAL IMPACT STATEMENTS (EIS) The ORP-LVF managed the review of the EIS for the Idaho National Engineering Laboratory. Comments of the EIS were solicited from a number of EPA programs, edited and incorporated into a single set of comments which were sent to ORP Headquarters. The draft EIS, "Navajo-Exxon Uranium Development," has been reviewed for radiological aspects and comments forwarded to EPA Region VI. EMERGENCY RESPONSE PLANNING Mr. Thomas Sell participated as an instructor in the Federal interagency workshop, "Radiological Emergency Response Planning 24 ------- in Support of Fixed Nuclear Facilities," from September 13 through 17. The report, "Rationale for Developing Protect ive Act ion Guides and Recommended Protective Action Guides for Organ Doses for Airborne Releases Due to Accidents at Light Water Reactors," was completed and sent to the Protective Action Planning Branch, Environmental Analysis Division, Off ice of Radiation Programs. PUBLICATIONS The following Technical Notes were distributed: "Review of State Licenses for Disposal of Low-Level Radio- active Waste by Shallow Land Burial," ORP/LV-76-3. "Report of Ambient Outdoor Radon and Indoor Radon Progeny Concentrat.ions During November 1975 at Selected Locations in the Grants Mineral Belt, New Mexico," ORP/LV-76-4. "Environmental and Safety Aspects of Alternative Nuclear Power Technologies - Fusion Power Systems," ORP/LV-76-7. A paper, "Effects of Uranium Mining and Milling on Ground Water in the Grants Mineral Belt, New Mexico," was published in the journal, Ground Water. 25 ------- ENVIRONMENTAL MONITORING AND SUPPORT LARORATORY P.O. BOX 15027 944 EAST HARMON AVENUE LAS VEGAS. NEVAOA 89114 TEL |702) 736-2969 FTS 595-2969 DIRECTOR G B MORGAN. ACTG DEPUTY DIRECTOR (VACAN TENANT ORGANIZATIONS PERSONNEL OFFICE LAS VEGAS A SANDOVAL JR LAS VEGAS ACCOUNTING OFFICE LA OEMERS REGION IX LAS VEGAS UNIT R CUMMINS REGIONAL SERVICES STAFF R E JAQUISH OFFICE OF RADIATION PROGRAMS. LAS VEGAS FACILITY 0 W HENDRICKS MONITORING SYSTEMS flESIGN ANO ANALYSIS STAFF E SCHUCK HEALTH AND SAFETY STAFF OR M E KAYE INFORMATION SERVICES STAFF G S DOUGLAS BRANCHES: GENERAL SERVICES M CARPENTER COMPUTER SERVICES G ALLISON FACILITIES ANO ENGINEERING SERVICES R COULTER OFFICE Of PROGRAM MANAGEMENT AND SUPPORT WE PETRIE BRANCHES: REMOTE SENSING OPERATIONS R HOLMES REMOTE MONITORING METHODS J ECKERT ENVIRONMENTAL PHOTOGRAPHIC INTERPRETATION COMPLEX V WEBB REMOTE SENSING DIVISION DR SH MELFI BRANCHES: METHODS DEVELOPMENT ANO ANALYTICAL SUPPORT E BRETTHAUER QUALITY ASSURANCE A JARVIS POLLUTANT PATHWAYS DR G WIERSMA EXPOSURE/DOSE ASSESSMENT DR G POTTER FARM ANO ANIMAL INVESTIGATION DR D SMITH MONITORING SYSTEMS RESEARCH AND DEVELOPMENT OIVfSfON DR R E STANLEY ACTG BRANCHES: WATER AND LAND QUALITY V. LAMBOU AIR QUALITY R EVANS ENVIRONMENTAL RADIATION C COSTA AIRCRAFT OPERATIONS C DROPP MONITORING OPERATIONS DIVISION OT WRUSLE ------- U.S. ENVIRONMENTAL PROTECTION AGENCY ENVIRONMENTAL MONITORING AND SUPPORT LABORATORY P.O. BOX IS027 LAS VEGAS. NEWDA 89m OFFICIAL BUttNESS PENALTY FOR PfMWTE USE, $300 m POSTAGE AND FEES RWD U.S. ENVIRONMENTAL PROTECTION AGENCV EPA-335 nwr class man. ------- |