United States Office of Air Quality EPA-454/R-00-035b
Environmental Protection Planning and Standards September 2001
Agency Research Triangle Park, NC 27711
AIR
A EPA
Final Report - Volume II of II
Testing of a 4-Stroke Diesel Cycle
Oil-fired Reciprocating Internal
Combustion Engine to Determine
the Effectiveness of an Oxidation
Reduction Catalyst System for
Reduction of Hazardous Air
Pollutant Emissions
-------
FINAL REPORT
TESTING OF A 4-STROKE DIESEL CYCLE OIL-FIRED
RECIPROCATING INTERNAL COMBUSTION
ENGINE TO DETERMINE THE EFFECTIVENESS OF AN
OXIDATION CATALYST SYSTEM FOR REDUCTION
OF HAZARDOUS AIR POLLUTANT EMISSIONS
VOLUME II OF II
Prepared for:
Terry Harrison (MD-19)
Work Assignment Manager
SMTO, EMC, EMAD, OAQPS
U.S. Environmental Protection Agency
Research Triangle Park, NC 27711
September 2001
Submitted by:
PACIFIC ENVIRONMENTAL SERVICES, INC.
5001 S. Miami Blvd., Suite 300
Research Triangle Park, NC 27709-2077
(919)941-0333 FAX (919) 941-0234
-------
DISCLAIMER
Pacific Environmental Services, Inc. (PES) prepared this document under EPA
Contract No. 68-D-01-003, Work Assignment No, 1-04. PES reviewed this document in
accordance with its internal quality assurance procedures and approved it for distribution.
The contents of this document do not necessarily reflect the views and policies of the U.S.
EPA. Mention of trade names does not constitute endorsement by the EPA or PES.
-------
TABLE OF CONTENTS
VOLUME I
Page
1,0 INTRODUCTION 1-1
2.0 SUMMARY OF RESULTS 2-1
2.1 EMISSIONS TEST LOG 2-1
2.2 ENGINE PARAMETERS AND 2-3
2.3 FTIRS AND GEMS MEASUREMENTS 2-3
2.4 GCMS MEASUREMENTS 2-6
2.5 POLYNUCLEAR AROMATIC HYDROCARBON (PAH)
MEASUREMENTS 2-9
2.6 DESTRUCTION OF ORGANIC COMPOUNDS BY THE CATALYST 2-11
2.7 PARTICULATE MATTER MEASUREMENTS 2-15
2.8 FUEL OIL ANALYSIS 2.15
3.0 SOURCE DESCRIPTION AND OPERATION 3-1
3.1 ENGINE DESCRIPTION 3-1
3.2 ENGINE OPERATION DURING TESTING 3-4
4.0 SAMPLING LOCATIONS 4-1
5.0 SAMPLING AND ANALYSIS METHODS 5-1
5.1 LOCATION OF MEASUREMENT SITES AND SAMPLE/VELOCITY
TRAVERSE POINTS 5-1
5.2 DETERMINATION OF STACK GAS VOLUMETRIC FLOW RATE... 5-3
5.3 DETERMINATION OF STACK GAS OXYGEN AND CARBON
DIOXIDE CONTENT 5-4
5.4 DETERMINATION OF STACK GAS MOISTURE CONTENT 5-4
5.5 DETERMINATION OF NITROGEN OXIDES 5-6
5.6 DETERMINATION OF CARBON MONOXIDE 5-6
5.7 DETERMINATION OF TOTAL HYDROCARBONS 5-7
5.8 DETERMINATION OF METHANE AND NON-METHANE
HYDROCARBONS 5-7
ii
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TABLE OF CONTENTS (Concluded)
Page
5.9 DETERMINATION OF GASEOUS ORGANIC HAP
USING FTIRS 5-8
5.10 DETERMINATION OF ORGANIC HAPS BY DIRECT
INTERFACE GCMS 5-9
5.11 DETERMINATION OF POLYCYCLIC AROMATIC
HYDROCARBONS BY CARB 429 5-12
5.12 DETERMINATION OF PARTICULATE MATER 5-14
5.13 DETERMINATION OF FUEL OIL COMPOSITION 5-14
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES
AND RESULTS 6-1
6.1 FTIRS QA/QC PROCEDURES 6-1
6.2 CEMS QA/QC PROCEDURES 6-5
6.3 GCMS QA/QC PROCEDURES 6-12
6.4 CARB 429 QA/QC PROCEDURES 6-19
6.5 DATA QUALITY ASSESSMENT 6-29
APPENDIX A SUBCONTRACTOR TEST REPORT - COLORADO STATE
UNIVERSITY ENGINES AND ENERGY CONVERSION
LABORATORY. "EMISSIONS TESTING OF CONTROL DEVICES
FOR RECIPROCATING INTERNAL COMBUSTION ENGINES IN
SUPPORT OF REGULATORY DEVELOPMENT BY THE U.S.
ENVIRONMENTAL PROTECTION AGENCY (EPA) PHASE 3:
FOUR-STROKE. DIESEL INTERNAL COMBUSTION ENGINES"
APPENDIX B SUBCONTRACTOR TEST REPORT - EMISSION MONITORING,
INC. "RESULTS OF DIRECT INTERFACE GCMS TESTING
CONDUCTED ON A 2-STROKE LEAN BURN ENGINE"
VOLUME II
APPENDIX C SUBCONTRACTOR TEST REPORT - EASTERN RESEARCH
GROUP, INC. "CARB METHOD 429: SAMPLE ANALYSIS"
APPENDIX D CARB METHOD 429 FIELD DATA
iii
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LIST OF XABLES
Page
Table 2.1 Emissions Test Log 2-2
Table 2.2 Summary of Engine and Exhaust Gas Parameters 2-4
Table 2.3 Stack Concentrations of Detected FTIRS and CEMS Compounds 2-5
Table 2.4 Stack Concentrations of Detected GCMS Compounds 2-7
Table 2.5 Summary of Stack Gas and Sampling Parameters C'ARB 429
Catalyst Inlet and Outlet 2-10
Table 2.6 Emission Rates of Detected PAHS at Catalyst Inlet . 2-12
Table 2.7 Emission Rates of Detected PAHS at Catalyst Outlet 2-17
Table 2.8 Mass Flow Scenarios 2-13
Table 2.9 Removal Efficiencies of Detected Organic Compounds 2-15
Table 2.10 Method ISO 8178-1 Particulate Matter Mass Flow Data 2-16
Table 2.11 Summary of Fuel Oil Analysis 2-17
Table 3.1 Engine and Catalyst Specifications Caterpillar 3508 EUI (4-stroke,
diesel cycle, oil-fired) 3-2
Table 3.2 Summary of Nominal Engine Parameters 3-3
Table 3.3 Target Engine Operating Conditions During Testing 3-5
Table 3.4 Summary of Engine Parameters - Caterpillar 3508 EUI 3-6
Table 3.5 Summary of Engine Parameters During Baseline Runs 3-7
Table 5.1 Summary of Sampling and Analysis Methods 5-2
Table 5.2 FTIRS Analyzer Specifications 5-8
Table 5.3 Summary of Fuel Oil Analysis Methods 5-15
Table 6.1 Detection Limits of FTIRS and CEMS Compounds 6-6
Table 6,2 Types and Frequencies of CEMS Analyzer Calibrations 6-8
Table 6.3 Summary of Fuel Factor Values 6-11
Table 6.4 Summary of CEMS Analytical Detection Limits 6-12
Table 6.5 Summary of GCMS Continuing Calibrations 6-14
Table 6.6 GCMS Analyte Spike Recoveries 6-15
Table 6.7 Detection Limits of GCMS Compounds at Catalyst Inlet 6-17
Table 6.8 Detection Limits of GCMS Compounds at Catalyst Outlet 6-18
Table 6.8 CARB 429 Sample Train - Summary of Temperature Sensor
Calibration Data 6-20
Table 6.10 CARB 429 Sample Train Summary of Pitot Tube Calibration Data ..... 6-21
Table 6.11 CARB 429 Sample Train Summary of Dry Gas Meter and Orifice
Calibration Data 6-22
iv
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LIST OF TABLES (Concluded)
Page
Table 6.12 Summary of CARB 429 Blank Results 6-25
Table 6.13 Summary of CARB 429 Surrogate Recoveries 6-26
Table 6.14 Detection Limits of PAH Compounds at Catalyst Inlet 6-27
Table 6.15 Detection Limits of PAH Compounds at Catalyst Outlet ............. 6-28
Table 6.16 Summary of Engine and Method Performance 6-31
LIST OF FIGURES
Page
Figure 1.1 Test Program Organization and Major Lines of Communication 1-3
Figure 4.1 Inlet Sample Port Locations for Velocity, CARB 429, FTIRS, CEMS,
and GCMS Sampling 4-2
Figure 4.2 Inlet Traverse Point Locations for Velocity and CARB 429 Sampling .... 4-3
Figure 4.3 Outlet Sample Port Locations for Velocity, CARB 429, FTIRS, CEMS,
and GCMS Sampling 4-4
Figure 4.4 Outlet Traverse Point Locations for Velocity and CARB 429 Sampling . . 4-5
Figure 5.1 Schematic Diagram of EECL FTIRS/CEMS Sampling and
Analysis System 5-6
Figure 5.2 Schematic of GCMS Sampling and Analysis System 5-11
Figure 5.3 Schematic Diagram of CARB 429 PAH Sampling Train 5-13
v
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APPENDIX B
SUBCONTRACTOR TEST REPORT - EMISSION MONITORING, INC.
"RESULTS OF DIRECT INTERFACE GCMS TESTING CONDUCTED
ON A 4-STROKE DIESEL ENGINE"
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DIRECT INTERFACE GCMS TESTING CONDUCTED ON
A CATERPILLER DIESEL-FIRED ENGINE
February 7,2000
Prepared For:
John Chehaske
Dennis Falgout
Pacific Environmental Services Inc.
560 Herndon Parkway, Suite 200
Herndon, VA 20170-5240
Prepared By:
Laura L. Kinner Ph. D.
James W. Peeler
Emission Monitoring, Inc.
8901 Glen wood Avenue
Raleigh, NC 27612
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DISCLAIMER
This report presents the results of direct interface GCMS emissions testing conducted on a diesel engine
located at the Colorado State University Engines and Energy Conversion Laboratory. This document is a
companion document to a comprehensive report prepared by Pacific Environmental Services that describes
the test program in its entirety.
Results contained in this report are presented in concentration units of parts per million (ppm) on a dry
basis. Calculation of mass emissions rates was not performed.
This document was prepared by Emission Monitoring Incorporated (EMI) under Pacific Environmental
Services Incorporated (PES) Subcontract NO, 68-D-98-004-EMI and EPA Contract NO. 68-D-98-004. It
has undergone the internal QA policies of EMI. The contents do not necessarily reflect the views and
policies of the EPA, and/or mention of trade names does not constitute endorsement by the EPA or by EMI.
1
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1.0 INTRODUCTION and BACKGROUND
The United States Environmental Protection Agency (U.S. EPA) and the Industrial Coordinated
Combustion Rulemaking (ICCR) emissions test work group requested the use of a portable gas
chromatograph-mass spectrometer (GCMS) based analyzer and its associated extractive sampling system to
identify and quantify volatile organic hazardous air pollutants at the inlet and outlet of catalysts installed on
various natural gas-fired, and diesel-fired engines. The direct interface GCMS instrumentation was
requested because it provides on-site analysis of stack gas constituents at very low concentration levels
without the use and problems associated with adsorbents. Data gathered from this testing effort will be
used in support of developing a maximum achievable control technology (MACT) standard for the source
category that includes reciprocating internal combustion engines.
Pacific Environmental Services (PES) subcontracted Emission Monitoring Incorporated (EMI) to perform
direct interface GCMS testing on a Caterpillar 3508 diesel-fired engine located at the Colorado State
Engines and Energy Conversion Laboratory (ECCL). Testing on this particular engine represented the
third in a series of tests that were conducted at the ECCL.
The primary objective of GCMS testing was to characterize and quantify nine specific volatile organic
hazardous air pollutants (benzene, toluene, o,m,p-xylenes, styrene, ethyl benzene, 1,3-butadiene, and
hexane) in samples acquired at the inlet and outlet of an oxidation catalyst in order to determine the
potential removal efficiency. The oxidation catalyst was installed in the exhaust duct of the diesel engine.
Simultaneous concentration data from the catalyst inlet and the outlet were acquired using two separate
direct interface GCMS measurement systems.
Each measurement system was operated in accordance with EPA Alternate Method - 017. On-site data
analysis immediately following sample acquisition was performed to determine whether the method QA
criteria were achieved, and to inform the PES Project Manager of the concentration levels observed in the
engine exhaust. Representatives from the EPA were also on-site to observe the testing, the method QA/QC
activities, and the data analysis.
Engine operating parameters were changed from baseline conditions, and the effects of these changes were
determined for the nine test specific target analytes at the inlet and outlet of the catalyst. The engine test
matrix consisted of 10 test points that included changes in engine speed, torque, ignition timing, and air
manifold temperature.
This report is a companion document to a detailed report prepared by PES that describes the test program in
its entirety, and includes mass emission rates for all die program target analytes including those measured
by the GCMS measurement systems.
2
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2.0 SUMMARY OF GCMS MEASUREMENT RESULTS
The sampling and analysis procedures used during this testing program followed those detailed in EPA
Alternate Method 17 and the quality assurance criteria of the method were achieved. Additional quality
assurance procedures consisting primarily of analyte spiking at various concentrations were also performed.
Very low levels of benzene and toluene were measured at the catalyst inlet sampling location. Very low
levels of benzene (sometimes greater than the inlet location) were measured at the catalyst outlet sampling
location. Toluene was below the measurement system detection limit at the outlet sampling location. None
of the other target analytes were detected at either the catalyst inlet or outlet sampling locations.
Problems were encountered with the large quantity, small particle size, and adsorptive nature of the diesel
soot that was present at both the inlet and outlet sampling locations. The soot adsorbed a portion of the
target analytes that were detected, (i.e., benzene and toluene) as documented by analyte spiking procedures.
Special precautions were taken including modification of the sampling equipment and modification of
sampling procedures to minimize the effects of the soot on the measurement results. (See detailed
discussion in Section 5.1) In spite of these efforts to minimize collecting particulate matter, concentration
results for benzene and toluene are consistently biased low. The extent of the bias is relatively insignificant
considering the very low level of benzene and toluene present at the catalyst inlet and outlet sampling
locations.
Analyte spiking procedures were conducted as the test program schedule allowed to document and to verify
the extent of adsorption by soot. Analyte spikes were performed at 1 ppm levels on the first test day (8/31)
consistent with previous practices for performing such spikes. Recoveries were lower than expected. It
could not be determined if the apparent biases were exaggerated because the spiked concentration was
significantly greater than the emissions concentrations and perturbation of the soot/benzene equilibrium
was suspected. It should also be noted that the duration of the test day, and the corresponding sample
volume for the GCMS systems, were greatly extended due to numerous delays in the test program while
waiting for engine stabilization and delays due to problems with other sampling methods.
On the second test day, all of the sampling system filters were replaced and even greater efforts were made
to minimize collection of soot on the sampling system filters. Also, analyte spikes were performed at
approximately 100 ppb levels which was far more challenging (i.e., requires use of a different calibration
standard with its associated uncertainty, and also reduces the acceptable tolerance by a factor of 10 from
300 ppb to only 30 ppb). Although much more challenging, the lower spike concentrations are also much
more representative of actual effluent concentrations. For the second day, spike recoveries were within
acceptable tolerances for the first nine hours of testing. The recoveries were then observed to decrease due
to the soot adsorption phenomena for the spikes conducted after the last test run of the day was completed.
On the third test day, the sampling system filters were again replaced and efforts to avoid collection of
particulate were again optimized. Following the completion of the single test run on the third day, analyte
spikes were performed at 100 ppb, 200 ppb, and 1 ppm to further quantify the adsorption phenomena.
The results presented here have not been corrected to account for adsorption of analytes by the diesel soot.
However, percent recovery calculations for the benzene and toluene analyte spikes are included in Table
2.3 and Table 6.2. A discussion of the factors that affect the representativeness of the analyte spike results
for use in correcting the measurement results is presented in Section 6.2.
Table 2-1 presents a detailed test log including calibration, QA/QC, and corrective actions token during the
course of the test.
3
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Table 2-1 Diesel Engine GCMS Test Log
Run # - Event
Date
Time
Comments
Calibrations
8-29-99
08:45-20:00
Calibration of mass flow meters relative to primary
standard. Fundamental analyzer calibrations (four-
point). QA/QC audits. Catalyst inlet and outlet
measurement svstem calibration checks. CEneine not
operating. No opportunity to evaluate effluent
conditions, soot levels, or to conduct analyte spikes.)
Set-up
8-30-99
07:45-16:45
Complete measurement system set-up and checks of
inlet GCMS ion pump. (Engine not operating. No
opportunity to evaluate effluent conditions, soot levels,
or to conduct analyte spikes.)
Pre-Run
8-31-99
06:00-10:45
Measurement system QA/QC activities and
preliminary catalyst inlet/outlet sampling.
Run 1
10:46-11:21
End Run 1 analyte spikes at 1 ppm. Spike recoveries
40%/30% of exp. value for benzene/toluene.
Run 14
13:57-14:32
End Run 14 analyte spikes at 1 ppm. Spike recoveries
consistently 40%/30% of exp, value for
benzene/toluene.
Benzene/toluene detected in zero checks at 20 ppb.
Run 13
16:58-17:32
None
Run 10
18:58-19:33
End Run 10 analyte spikes at 1 ppm. Spike recoveries
40%/3G% of exp. value for benzene/toluene.
Benzene/toluene detected in zero checks at 20 ppb.
Run 9
22:42-23:26
Clean and secure measurement systems
QA/QC
Activities
9-1-99
06:00-10:45
Changed sampling system filters at beginning of day -
2 in series at inlet and one at outlet. Very high loading
of diesel soot on all filters at both locations.
Measurement system QA/QC activities
Run 4
11:15-11:49
Started sampling ambient air between runs to avoid
collecting soot.
Run 11
15:16-15:50
Analyte spikes at 100 ppb within accepted values.
Run 12
16:36-17:10
Spike for benzene pre/post catalyst acceptable, toluene
recovery 26%/48%.
Run 2
19:11-19:45
Spiking recoveries 50%-60% at inlet, changing
effluent concentrations at outlet make it difficult to
calculate analyte spike recoveries accurately.
Clean and secure measurement systems
QA/QC
Activities
9-2-99
06:00-09:30
Changed sampling system filters at beginning of day -
2 in series at inlet and one at outlet. High loading of
diesel soot on all filters at both locations.
Measurement system QA/QC activities
Run 3
10:04-10:38
Analyte spikes at 100 ppb, 200 ppb and 1 ppm
2.1.1 Catalyst Inlet Results
Benzene and toluene were the only compounds detected in the diesel exhaust at concentration levels
ranging from 0,03 ppm to 0.14 ppin. These levels are near, or below the lowest level calibration point of
100 ppb.
Table 2-2 presents the concentration results in parts per million on a dry basis (2% moisture) for each
sample acquisition, and for individual run averages. All data are reported using two significant figures
only.
4
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Table 2-2 Diesel Emission Test Results - Target Analytes Only
1
MW
Run - Preliminary
Run 1 - Baseline Condition
Run 14
Run 13
"OLD" HAPSITE
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
RUN/SAMPLE ID
DinPrel
DinPre2
DinPre3
Dinrla
Dinrlb
Dinrlc
Dinrld
Avg.
Dinrl4a
Dinrl4b
Dinrl4c
Dinrl4d
Avg.
dinl3a
dinl3b
dinl3c
dinl3d
Avg.
Date
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
Time
8:46
8:58
9:22
10:46
10:58
11:10
11:21
13:57
14:09
14:21
14:32
16:58
17:09
17:21
17:32
Compound
PPm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1,3-Butadiene
54
Hexane
86
Benzene
78
0.04
0.05
0.030
0.03
0.04
0.04
0.05
0.040
0.03
0.04
0.04
0.05
0.04
0.03
0.03
0.04
0.03
0.03
Toluene
92
0.13
0.14
0.140
0.14
0.14
0.15
0.14
0.143
0.13
0.14
0.14
0.14
0.14
0.14
0.14
0.14
0.14
0.14
Ethyl Benzene
106
m/p-Xylene
106
Styrene
104
o-Xylene
106
"NEW HAPSITE"
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
RUN/SAMPLE ID
DoutPrel
DoutPre2
DoutPre3
DoutrlA
Doutrlb
Doutrlc
Doutrld
Avg.
Doutrl4a
Doutrl4b
Doutrl4c
Doutl4d
Avg.
Avg.
Date
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
Time
8:58
9:10
9:22
10:46
10:58
11:10
11:21
13:57
14:09
14:21
14:32
16:58
17:09
17:21
17:32
Compound
1,3-Butadiene
64
Hexane
86
Benzene
78
0.02
0.03
0.030
0.03
0.03
0.04
0.04
0.035
0.02
0.04
0.02
0.04
0.03
0.06
0.05
0.08
0.08
0.07
Toluene
92
Ethyl Benzene
106
m/p-Xylene
106
Styrene
104
o-Xylene
106
Blanks indicate non detect values
Catalyst Efficiency for Toluene*
Run#
Pre
1
14
13
Removal Percent
89%
89%
89%
89%
* Dl of 15 ppbusedfo
r outlet concentration, represents worst case scenario.
Benzene removal not calculated III!
-------
Table 2-2 (cont) Diesel Emission Test Results - Target Analytes Only
MW
Run 10
Run 9
Run 4
Run 11
"OLD" HAPSITE
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
RUN/SAMPLE ID
DinrlOa
DinrlOb
DinrlOc
DinrlOd
Avg.
Dinr9a
Dim9b
Dinr9c
Dinr9d
Avg.
Dinr4a
Dinr4b
Dinr4c
Dinr4d
Avg.
Dinrlla
Dinrl lb
Dinrl lc
DinrlId
Avg.
Date
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
Time
18:58
19:09
19:22
19:33
22:42
22:53
23:05
23:16
11:15
11:26
11:38
11:49
15:16
15:27
15:39
15:50
Compound
ppra
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1,3-Butadicne
54
Hexane
86
Benzene
78
0.03
0.05
0.03
0.030
0.035
0.02
0.03
0.05
0.03
0.033
0.08
0.09
0.1
0.09
0.09
0.06
0.05
0.06
0.04
0.05
Toluene
92
0.14
0.14
0.15
0.140
0.143
0.13
0.13
0.13
0.13
0.130
0.13
0.14
0.14
0.13
0.14
0.14
0.14
0.14
0.14
0.14
Ethyl Benzene
106
m/p-Xylene
106
Styrene
104
o-Xylene
106
"NEW HAPSITE"
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
RUN/SAMPLE ID
DoutrlOa
DoutrlOb
DoutrlOc
DoutrlOd
Avg.
Doutr9a
Doutr9b
Doutr9c
Doutr9d
Avg.
Doutr4a
Doutr4b
Doutr4c
Doutr4d
Avg.
Doutrlla
Doutrl lb
Doutrl lc
Doutrl Id
Avg.
Date
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
31-Aug
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
Time
18:58
19:09
19:22
19:33
22:42
22:53
23:05
23:16
11:15
11:26
11:38
11:49
15:16
15:27
15:39
15:50
Compound
ppm
ppm
ppm |
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1,3-Butadiene
64
Hexane
86
Benzene
78
0.06
0.06
0.09
0.110
0.080
0.11
0.12
0.15
0.16
0.135
0.08
0.13
0.15
0.13
0.12
0.01
0.02
0.03
0.05
0.03
Toluene
92
Ethyl Benzene
106
m/p-Xylene
106
Styrene
104
o-Xylene
106
Blanks indicate non detect values
Catalyst Efficiency
or To
uene*
Run#
10
9
4
Removal Percent
89%
88%
89%
* D1 of 15 ppb used
"or outlet concen
trarion, represents worst case scenario.
Benzene removal not calculated | [ ! !
-------
Table 2-2 (cont.) Diesel Emission Test Results - Target Analytes Only
MW
Run 12
Run 2
Run 3
"OLD" HAPSITE
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
Inlet
RUN/SAMPLE ID
Dinrl2a
Dinrl2b
Dinrl2c
Dinrl2d
Avg.
Dinr2a
Dinr2b
Dinr2c
Dinr2d
Avg,
Dinr3a
Dinr3b
Dinr3c
Dinr3d
Avg.
Date
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
2-Sep
2-Sep
2-Sep
2-Sep
Time
16:36
16:48
16:59
17:10
19:11
19:22
19:33
19:45
10:04
10:15
10:27
10:38
Compound
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1,3-Butadiene
54
Hexane
86
Benzene
78
0.06
0.06
0.06
0.05
0.058
0.05
0.05
0.05
0.05
0.050
0.14
0.1
0.13
0.11
0.120
Toluene
92
0.14
0.14
0.14
0.14
0.140
0.13
0.11
0.13
0.13
0.125
0.04
0.03
0.03
0.03
0.033
Ethyl Benzene
106
m/p-Xylene
106
Styrene
104
o-Xylene
106
"NEW HAPSITE"
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
Outlet
RUN/SAMPLE ID
Doutrl2a
Doutrl2b
Doutrl2c
Doutrl2d
Avg.
Doutr2a
Doutr2b
Doutr2c
Doutr2d
Avg.
Doutr3a
Doutr3b
Doutr3c
Doutr3d
Avg.
Date
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
1-Sep
2-Sep
2-Sep
2-Sep
2-Sep
Time
16:36
16:48
16:59
17:10
19:11
19:22
19:33
19:45
10:04
10:15
10:27
10:38
Compound
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
1,3-Butadiene
64
86
Hexane
Benzene
78
No Data
0.07
0.09
0.13
0.097
0.08
0.11
0.15
0.21
0.138
0.12
0.12
0.16
0.19
0.148
Toluene
92
Ethyl Benzene
106
m/p-Xylene
106
Styrene
104
o-Xylene
106
Blanks indicate non detect values
Catalyst Efficiency for Toluene*
Run#
12
2
3
Removal Percent
89%
88%
54%
* D1 of 15 ppb used for outlet concentration, represents worst case scenario.
Benzene removal not calculated
-------
Table 2-3 Run Averages and Corresponding Analyte Spike Recoveries
Catalyst Inlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery - 1 ppm
+/- ppm
Corrected Range - ppm
8/31/99
Low
Benzene
1
0.04
39%
0.06
0.10
Toluene
1
0.14
28%
0.07
0.21
Benzene
14
0.04
42%
0.06
0.10
Toluene
14
0.14
30%
0.07
0.21
Benzene
13
0.03
42%
0.06
0.09
Toluene
13
0.14
30%
0.07
0.21
Benzene
10
0.04
42%
0.06
0.09
Toluene
10
0.14
29%
0.07
0.21
Benzene
9
0.03
42%
0.06
0.09
Toluene
9
0.13
29%
0.07
0.20
Catalyst Outlet
Compounds
Run#
Run Average
Spike Recovery -1 ppm
+/- ppm
Corrected Range - ppm
8/31/99
Low
Benzene
1
0.04
88%
0.01
0.05
Toluene*
1
nd
60%
Benzene
13
0.03
88%
0.01
0.04
Toluene
13
nd
60%
Benzene
14
0.07
88%
0.01
0.08
Toluene
14
nd
60%
Benzene
10
0.08
88%
0.01
0.09
Toluene
10
nd
60%
Benzene
9
0.14
88%
0.01
0.15
Toluene
9
nd
60%
* Toluene could be 21 ppb and be undetected at the 60% recovery level
-------
Table 2-3 (cont.) Run Averages and Corresponding Analyte Spike Recoveries
Catalyst Inlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery - 100 ppb
+/- ppm
Corrected Range - ppm
9/1/99
Low
Benzene
4
0.09
81%
0.02
0.11
Toluene
4
0.14
74%
0.03
0.16
Benzene
11
0.05
83%
0.02
0.07
Toluene
11
0.14
26%
0.07
0.21
Benzene
12
0.06
83%
0.02
0.07
Toluene
12
0.14
26%
0.07
0.21
Benzene
2
0.05
57%
0.04
0.09
Toluene
2
0.13
69%
0.03
0.16
Catalyst Outlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery - 100 ppb
+/- ppm
Corrected Range - ppm
High
Benzene
4
0.12
104%
-0.004
0.12
Toluene*
4
nd
58%
Benzene
11
0.03
107%
-0.007
0.02
Toluene
11
nd
48%
Low
Benzene
2
0.14
89%
0.011
0.15
Toluene
2
nd
48%
* Toluene could be 22 ppb and be undetected at the 50 percent recovery level
-------
Table 2-3 (cont.) Run Averages and Corresponding Analyte Spike Recoveries
Catalyst Inlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery -100 ppb
+/- ppm
Corrected Range - pp
9/2/99
Low
Benzene
3
0.12
71%
0.03
0.15
Toluene
3
0.03
54%
0.05
0.08
Catalyst Inlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery - 200 ppb
.
Benzene
3
0.12
76%
0.02
0.14
Toluene
3
0.03
61%
0.04
0.07
Catalyst Inlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery - lppm
Benzene
3
0.12
71%
0.03
0.15
Toluene
3
0.03
67%
0.03
0.07
Catalyst Outlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery -100 ppb
+/- ppm
Corrected Range - pp
9/2/99
High
Benzene
3
0.15
117%
-0.02
0.13
Toluene*
3
nd
58%
Catalyst Outlet
Compounds Detected
Run #
Run Average - ppm
Spike Recovery - 200 ppb
Benzene
3
0.15
126%
-0.03
0.12
Toluene
3
nd
48%
Catalyst Outlet
Compounds Detected
Run#
Run Average - ppm
Spike Recovery - 1 ppm
Benzene
3
0.15
120%
-0.02
0.13
Toluene
3
nd
48%
* Toluene could be 22 ppb and be undetected at the 50 percent recovery level
-------
2.1.2 Catalyst Outlet Results
Benzene was the only compound detected at the catalyst outlet at concentration levels ranging from 0.03
ppm to 0.15 ppm. These concentration levels are near, or below the lowest level calibration point of 100
ppb.
Table 2-2 presents the concentration results in parts per million on a dry basis (-2% moisture) for each
sample acquisition, and for individual run averages. All data are reported using two significant figures
only.
3.0 PROCESS DESCRIPTION
The PES report contains a detailed description of the process.
4.0 SAMPLING LOCATIONS
Sampling was conducted at the inlet and outlet of an oxidation catalyst. The PES report contains a detailed
description of each sampling location.
5.0 SAMPLING AND ANALYTICAL PROCEDURES
The sampling and analytical procedures used during this testing program followed those detailed in EPA
Alternate Method 17. The instrument was calibrated on-site using a 10 ppm manufacturer's certified
compressed gas mixture consisting of nine target analytes (benzene, toluene, o,m,p-xylenes, styrene, ethyl
benzene, 1,3-butadiene, and hexane) in nitrogen balance. Calibrations were conducted at 10 ppm, 3 ppm, 1
ppm and 100 ppb in order to provide enough calibration points for all of the target analytes. "Die 10 ppm
standard was diluted with VOC free nitrogen using and EMI calibration gas manifold with three mass flow
meters. The mass flow meters were calibrated in the field on the day of use by comparing to a digital
bubble meter with a NIST traceable calibration. Also, an independent 1 ppm standard was used to verify
the calibration validity and calibration gas dilution technique as required by the method.
5.1 Sampling Procedures
Effluent gas samples were withdrawn at a constant flow rate (l.S-LPMd,,,) from a single point located
approximately at the midpoint of the exhaust pipe. It is estimated that the gas residence time through the
sampling system at this flow rate is less than 1 minute. The response time required to equilibrate a step
change in sample concentration is approximately 6 minutes. During this test program, the catalyst inlet and
outlet GCMS measurement systems collected effluent simultaneously from each location for a period not
less than 10 minutes before acquisition by the GCMS instrumentation. A total o f four 10-minute samples
were acquired from each location to comprise a test run.
Each sampling system consisted of a heated probe, heated 0.3 micron quartz fiber filters, heated-head
sample pump, heated Teflon sampling line to transport the gas to the control units. The control units
include flow measurement and flow control capabilities and Peltier cooled condensers with continuous
condensate removal to dry the gas to a level acceptable for introduction to each instrument. For these tests,
all of the sample gases were directed through the condensers (the condenser bypass was not used) and the
condensers were operated at 36-39F. This resulted is a sample moisture content of less than 2%. The
control units also include provisions to ensure that the sample gas at the GCMS inlet probe is at
atmospheric pressure so that the quantify of internal standards co-injected with the sample is unaffected.
A generalized schematic of the GCMS measurement system is depicted in Figure 5-1.
5
-------
H ealed Probe 2 J0°F
Sample Gas
(1.5 lpm eonstar*
idt sampling
Bypass Control? tin,
"30" " ^
ff
Sampl# Lint H iitid to 3QCTF
CtficrOiOftGtt
Probe Box Hinted to 25D*F
ExcewStmjtfe Atmojpbmcv tti
: MusFlow Meter -i
s
tukssFlow Meter
m
C ondenser
Flaw.CoiSid
* y aJfiSL
C ondwise* B yp«s
FlowConlxd
X—r--
Ftow
Meter
I"1 ' 1-j Filter I*-**'
Flcur
Mtter
-j Filter (—^
Connection Line
'P'O cctain duringOC-MS
sample acquisition
GC-MS
Analyzer
Condenser System
otxlensete Drain
Control Bo* Hosted to. !2S°F
(or at!es9l3°F above mtuietion
temperature of ram pie gas)
Figure 5-1. Direct Interface GCMS Measurement System
6
-------
Several equipment modifications were made for this test. High soot loading was expected at the inlet
sampling location. Therefore, two 0.3-micron quartz fiber filters were installed in series in the pre-catalyst
sampling system to prevent breakthrough of the particulate matter and subsequent coating of the internal
surfaces of the measurement system. A single 0.3-micron quartz fiber filter was used in the outlet sampling
system. A short length of unhealed stainless steel tubing was installed at the inlet sampling location to cool
the exhaust stream from 11 OOF to about 300-400F. A three-way valve with an atmospheric vent was
installed at the catalyst pre-catalyst sampling probe because of the elevated static pressure at this sampling
location and concerns that this could adversely affect system calibration checks. The three-way valve
proved to be very useful because it also allowed sampling of ambient air between test runs during the
extended periods required to achieve stable engine operation and during other test delays. Finally, a
cooling system comprised of a fan and metal foil flexible duct was used to convey relatively cool ambient
air from the floor of the engine room to the electronic control sections of the inlet and outlet sampling
system probe boxes. This prevented overheating of electronics and pump motors due to the elevated
ambient temperatures and infrared radiation at the sampling locations during the tests.
There were numerous delays associated with achieving stable engine operation, problems with the
automated particulate sampling equipment, problems with the PAH sampling equipment, safety concerns
for the PAH sampling personnel due to the elevated NOx concentrations, and delays due to other factors.
These problems were mostly unavoidable because the engine was not operated during the preceding two
days due to budget and personnel constraints. Therefore, there was little opportunity to resolve these
problems before the test actually started. These problems had an indirect effect on the GCMS measurement
results even though the two measurement systems operated with very few problems for the entire test. The
direct interface GCMS systems are adjusted to maintain constant rate sampling. Thus, the amount of
particulate (in this case soot) that accumulates on the filters is directly proportional to the amount of time
that sampling is performed. On the first day of the test (8/31), EMI personnel arrived on-site at 6 am to
begin daily QA/QC activities as had been previously agreed with the other test personnel. The first GCMS
effluent samples were acquired at 8:30 am. The first test run began sometime later. The last sample was
completed at about midnight. During most of this 18 hour period, it was generally believed that testing
would begin "soon" so the GCMS systems continued sampling so that they would be ready without delay
when testing was resumed. Five 40-minute test runs were completed on the first day.
On the second test day (9/1), EMI personnel removed and inspected all of the particulate filters (filters in
the probe box and control unit) in both measurement systems. All of the probe box filters, including both
of the two filters in series for the inlet sampling location, were observed to have substantial amounts of
black sooty material coating all inlet side surfaces. Considering the state of the filters, it seemed amazing
that the low spike recoveries were as good as they had been on the first day. All of the probe box filters
were replaced. The backup filters in the control boxes located before and after the condensers were
inspected and were discolored only slightly. These filters were reinstalled. System calibrations were
performed to verify that the performance of the measurement systems was acceptable.
A new sampling strategy was adopted for the second day of the test. The three-way valve on the catalyst
inlet sampling system was manually positioned so that ambient samples were acquired at all times except
immediately (10 minutes) before a sample run was almost certain to begin, and during the course of actual
test runs and performance of analyte spikes. Similarly, the catalyst outlet sampling system was purged with
an excess flow of zero gas (nitrogen) through the system calibration port (upstream of the particulate filter)
except immediately before sample runs, and during the course of actual test runs and performance of
analyte spikes. These procedures were used to minimize particulate build up on the particulate filters.
A malfunction of the outlet sampling system occurred shortly before Run 11. An electrical short circuit in
the probe box resulted from water spilled when loading ice in a nearby manual sampling train. Repairs
were affected with the assistance of CSIJ personnel and the test was resumed.
On third day, all of the probe box filters were again replaced prior to the QA/QC calibration checks and the
sampling systems were again operated to minimize collection of particulate matter. Only one test condition
remained to be conducted on the third test day. A series of analyte spikes were performed at various
concentrations after the test run was completed.
7
-------
5.2 GCMS Operation
The mass spectrometer was operated using a non-evaporative getter (NEG) pump to maintain the requisite
high internal vacuum needed to generate mass spectra. A grab sample was acquired by co-mixing effluent
sample gas with an internal standard mixture (in a constant ratio of 10:1) in the GC sampling loop for 1
minute before injection into the GCMS, The internal standards used are 1,3,5-trifluoromethylbenzene
(TR1S) and bromopentafluorobenzene (BPFB). These compounds are not usually found in industrial
processes and are used to tune the mass spectrometer, to assess the stability and performance of the GCMS
on each sample run, and to determine adherence to the method QA/QC.
The GC and all of the instrument internal components were operated isothermally at 60°C to separate and
detect the target analytes. The mass spectrometer was operated in a limited full scan mode (45-125 amu).
This limited scan range was sufficient to acquire the full mass spectrum for each target analyte while
maximizing the instrument sensitivity.
5.3 Analytical Procedures
The procedures detailed in Alternate Method 17 were followed for this testing program, A copy of this
method is available from the EPA website.
Establishing a valid calibration curve requires a 20 percent relative standard deviation (%RSD) for each
individual analyte over the calibration range. Calibration was performed on-site by conducting two
successive GCMS runs at each of four concentration levels; 10 ppm, 3 ppm, 1 ppm and 100 ppb. Section
10 of the method details the calculation procedures used to determine the %RSD for each of the analytes.
Four calibration points were used instead of the three specified by the method in order to obtain a wider
dynamic calibration range, particularly for 1,3-butadiene and hexane (whose detection limits are higher
than the other target analytes). A separate 1 ppm mixture of these same target analytes was used to verify
that the calibration curve was valid and could be used to quantify all measurement system checks,
instrument QA and effluent samples.
Tables 5-1 and 5-2 present the target analytes, the results from the initial calibration in terms of %RSD, and
the test specific estimated detection limits for each GCMS measurement system. The detection limit was
estimated using the following procedure. Each target analyte's quantification ion was examined at the 100
ppb calibration level (the lowest calibration point). The signal to noise (S/N) ratio of each quantification
ion at this level was used to determine the concentration equivalent to a S/N ratio of 10:1. For example, if
the S/N ratio of benzene (ion 78) at the 100 ppb level was 200:1, then the estimated detection limit
(assuming a linear relationship with concentration) would correspond to 5 ppb at a S/N of 10:1.
Copies of the initial instrument calibration raw data sheets and calibration audits are presented in Appendix
A. The calibration gases and internal standards used for this testing were certified to within 5% analytical
accuracy by Spectra Gas, and by Scott Specialty Gases. Copies of the manufacturer certificates of
analyses are included in Appendix B.
6.0 QUALITY ASSURANCE/QUALITY CONTROL PROCEDURES
Each day the GCMS measurement system was tuned according to the criteria identified in the method.
Achieving the criteria for a valid mass spectral tune and achieving the internal standard relative mass
abundances during each GCMS run (see Tables 3 and 4 of Alt -17) verify the continuing instrument
performance and ensure that the QA/QC of the method can be achieved. Achieving the criteria for a valid
tune also allows searches of the NIST Mass Spectral library and verification of compounds that are not
contained in the instrument specific calibration.
6.1 Daily Calibration Check Procedures
Daily system calibrations were conducted to check both the validity of the initial instrument calibration and
the effectiveness of the sampling system to transport the target analytes to the instrumentation. Daily
system calibration checks were conducted at 1 ppm using the blended mixture of test program analytes.
8
-------
Table 5-1. ICCR - Initial Calibration and Calibration Audit Results
Pre-Test
"NEW" HAPSITE
Outlet
Estimated
"NEW" HAPSITE
Detection Limit
Compound
Initial Calibration %RSD
Critieria
Audit Results
Expected Value-ppm
% Difference
Criteria @ lppm Level
PPB
Compound
1,3-Butadiene
5.1
20%
0.86
1.03
-16.50%
within 20% of expected value
100
1,3-Butadiene
Hexane
4.2
20%
0.91
1.03
-11.65%
within 20% of expected value
50
Hexane
Benzene
1.8
20%
1.01
1.04
-2.88%
within 20% of expected value
15
Benzene
Toluene
1.3
20%
0.94
1.04
-9.62%
within 20% of expected value
15
Toluene
Ethyl Benzene
2.5
20%
0.96
1.04
-7.69%
within 20% of expected value
15
Ethyl Benzene
m/p-Xylene
2.3
20%
1.97
2.06
-4.37%
within 20% of expected value
30
m/p-Xylene
Styrene
2.7
20%
0.96
1.04
-7.69%
within 20% of expected value
50
Styrene
o-Xylene
6.7
20%
0.89
1.03
-13.59%
within 20% of expected value
30
o-Xylene
"OLD HAPSITE"
Inlet
"OLD HAPSITE"
Compound
Initial Calibration %RSD
Critieria
Audit Results
Expected Value-ppm
% Difference
Criteria @ lppm Level
PPB
Compound
1,3-Butadiene
6.5
20%
1.07
1.03
3.88%
within 20% of expected value
500
1,3-Butadiene
Hexane
4.9
20%
0.92
1.03
-10.68%
within 20% of expected value
150
Hexane
Benzene
3.1
20%
1.02
1.04
-1.92%
within 20% of expected value
15
Benzene
Toluene
6.3
20%
0.95
1.04
-8.65%
within 20% of expected value
15
Toluene
Ethyl Benzene
5.9
20%
0.96
1.04
-7.69%
within 20% of expected value
15
Ethyl Benzene
m/p-Xylene
5.7
20%
1.91
2.06
-7.28%
within 20% of expected value
30
m/p-Xylene
Styrene
6.5
20%
1.06
1.04
1.92%
within 20% of expected value
200
Styrene
o-Xylene
. 7.7
20%
0.91
1.03
-11.65%
within 20% of expected value
30
o-Xylene
-------
For system calibrations, the gas standard was directed through the entire sampling system (including the
filter). The certified standard used for this procedure was independent from that used to generate the initial
calibration. All target analytes met the method system calibration criteria of 20% except for toluene on 9-1
(it was 24%).
Immediately following the system continuing calibration, nitrogen was allowed to flow through both
measurement systems and a system blank was acquired. No analytes were detected in any of the system
blank analyses.
Tables 6-1 presents the results from the system continuing calibration checks.
6.2 Additional QA Procedures - Analyte Spiking
Periodic analyte spiking was conducted at 1 ppm on 8-3,100 ppb on 9-1, and at multiple concentration
levels on 9-2-99 in order to determine the extent of the soot adsorption for benzene and toluene. Hie
analyte spike was delivered at a ratio of exactly 1 part of spike gas to 9 parts of effluent as measured by
calibrated mass flowmeters. The analyte spike mixture was injected into the sampling system immediately
upstream of the particulate filters in both measurement systems so that the combined effect of the effluent
matrix and the diesel soot could be evaluated.
From the analyte spiking procedures conducted on 8-31, it was observed that the soot adsorbed about 60%
of these compounds at the 1 ppm concentration level. The adsorption was fairly consistent with time at this
spike level.
Because the 1 ppm analyte spike concentration represented a factor of about 10 greater than the effluent
concentration of benzene and toluene, analyte spikes at 100 ppb were conducted on 9-1 to document more
fully the extent of the adsorption at applicable concentration levels. Filter changes at the beginning of the
day combined with sampling ambient air between runs minimized the adsorption of the benzene and
toluene as demonstrated by acceptable recoveries at the 100 ppb level after the first few runs. At the end of
the day; however, soot build up again reduced the analyte spike recoveries to the levels observed the
previous day.
Analyte spiking performed on 9-2 was conducted at multiple concentration levels. Recoveries for benzene
were within the acceptable 30% tolerance. Toluene recoveries ranged from 50-60% of the expected values.
Table 2-3 presents the individual run averages along with the corresponding analyte spike recoveries.
Table 6-2 presents the results for the analyte spiking procedures conducted during this test program.
There is a temptation to correct actual measurement data based on the results of analyte spikes. Such
corrections may in some cases decrease the accuracy of the data. The following factors should be
considered:
1. Calculation of analyte spike recoveries may be adversely affected due to actual changes in the
underlying native concentrations for compounds present during the spiking procedure. In these tests,
our recovery calculations assume that the benzene concentration preceding the spike is the same as the
native benzene concentration during the spike. However, the benzene concentration was observed to
vary significantly among the four samples analyzed for certain test runs.
2. The analyte spike procedure involves use of additional equipment that is not part of the method and
thus inclusion of some additional errors. Calculation of spike recoveries includes measurement errors
associated with the sample flow system (rotameter or mass flow meter which is normally used only for
assuring constant rate sampling) and the mass flow meter used to monitor the spike rate. Both
measurements contribute some additional uncertainty due to their accuracy and precision. The sample
flow meter is also susceptible to changes in composition and molecular weight of the sample gas.
3. The 1 ppm analyte spikes were significantly greater than the sample concentrations and thus may
affect the dynamic equilibrium between the benzene and soot in the exhaust stream.
4. The 100 ppb analyte spikes involve the use of a second calibration standard relative to the calibration
standard used for the fundamental multi-point calibration thus introducing another source of
9
-------
Table 6-1 - Diesel System Continuing Calibration Check Results
"OLD" HAPSITE
Inlet
31-Aug
% Diff
1-Sep
% Diff
2-Sep
%Diff
Exp. Vals
Compound
PPm
ppm
Exp.
ppm
1,3-Butadiene
1.13
9.71%
1.00
-2.91%
1.00
-2.91%
1.03
Hexane
1.02
-0.97%
0.95
-7.77%
1.00
-2.91%
1.03
Benzene
0.88
-15.38%
0.94
-9.62%
1.00
-3.85%
1.04
Toluene
0.81
-19.80%
0.77
-23.76%
1.01
0.00%
1.01
Ethyl Benzene
0.91
-12.50%
1.01
-2.88%
1.01
-2.88%
1.04
m/p-Xylene
1.86
-9.71%
1.93
-6.31%
2.00
-2.91%
2.06
Styrene
1.02
-1.92%
0.83
-20.19%
1.00
-3.85%
1.04
o-Xylene
0.91
-11.65%
1.01
-1.94%
1.00
-2.91%
1.03
"NEW HAPSITE"
Outlet
31-Aug
% Diff
1-Sep
%Diff
2-Sep
%Diff
Exp. Vals
Compound
ppm
ppm
ppm
ppm
1,3-Butadiene
1.00
-2.91%
1.09
5.83%
1.01
-1.94%
1.03
Hexane
1.01
-1.94%
1.01
-1.94%
1.01
-1.94%
1.03
Benzene
1.01
-2.88%
1.03
-0.96%
1.01
-2.88%
1.04
Toluene
1.00
-3.85%
1.09
4.81%
1.00
-3.85%
1.04
Ethyl Benzene
1.01
-2.88%
1.10
5.77%
1.01
-2.88%
1.04
m/p-Xylene
2.02
-1.94%
2.14
3.88%
2.03
-1.46%
2.06
Styrene
1.00
-3.85%
1.07
2.88%
1.00
-3.85%
1.04
o-Xylene
1.00
-2.91%
1.03
0.00%
1.00
-2.91%
1.03
-------
Table 6-L Amlyte Spticktc ResaMa
Iff- S-31-99
INLET
DlnASl
31-Aug
11:38
DlnASl
31-Aug
11:48
DlnAS3
31-Aug
19:55
DinAS4
31-Aug
20:05
DfciASS
31-Aug
20:45
¦OLD HAPSITir
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Tag Value
Reemtn'
Tag Value
ppra
ppm
ppm
Recovery
Tag Value
ppm
Recovery
Tag Value
ppra
Recovery
Tag Value
Recovery
Ccmiwund
1,3-Butadiene
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
Hexane
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.)
0.00
1.01
0%
10.1
0.00
1.01
0%
Benzene
10.1
0.040
1.05
0.39
37%
10.1
0.040
1.05
0.42
40%
10.1
0.035
1.04
0.43
41%
10.1
0.035
1.04
0.45
43%
10.1
0.035
1.04
0.44
42%
Toluene
10.0
0.143
1.13
i.oi
0.29
26%
10.0
0.143
1.13
0.34
30%
10.0
0.143
1.13
0.33
29%
10.0
0.143
1.13
0.34
30%
10.0
0.143
1.13
0.33
29%
Ethvl Benzene
10.1
0.00
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
mfoOCylene
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
Stvrene
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
o-Xvleoe
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
OUTLET
DwtASt
31-Aug
20:16
D*utAS2
31-Aug
20:35
IWAS3
31-Aug
20:35
•NEW* HAPSITE
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Tap Value
ppm
Recovery
Tag Value
_PPi"
PP"
Recovery
Tag Value
ppm
Recover}'
Ciapwlrf
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
Hcxsne
10.1
0.00
1.01
0%
10.1
0.00
1.01
L03
0%
10.1
0.00
1.01
0%
Benzene
10.1
0.110
t.ll
0.90
81%
10.1
0.110
111
93%
10.1
0.110
1.11
099
89%
Toluene
10.0
0.00
1.00
0.52
52%
10.0
0.00
1.00
0.63
63%
10.0
0.00
1.00
0.65
65%
Etbvl Benzene
to. 1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
mfe-Xvlene
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
10.1
0.00
1.01
0%
SUTene
10.1
0.00
1.01
0%
101
0.00
1.01
0%
10 1
0.00
1.01
0%
o-Xvkne
10.0
0.00
i.00
0%
10.0
0.00
1.00
0%
10.0
0.00
1.00
0%
Avertic Recovery at 1
Idd
Benzene
41%
29%
Toluene
OHtM
Benzene
88%
Toluene
60%
-------
Table 6-2. (cant.) Analyte Spiking Results- continued
100 pnb spikes 9-1-99
INLET
DinR4AS
l-Sep
12:21
DinR12AS
l-Sep
17:5*
DinRlAS
l-Sep
18:49
DinR2AS2
l-Sep
20:08
"OLD HAPSITE"
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Tas V»hw
Recovery
Tag Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
ppm
Recovery
Compound
1,3-Butadieae
1.03
000
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
Hexane
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
Benzene
104
0.090
0.19
0.15
<1%
1.04
0.05S
0.16
0.13
83%
1.04
0.050
0.15
0.08
54%
1.04
0.050
0.15
0.09
60%
Toluene
1.04
0.140
0.23
0.17
74%
1.04
0.140
0.23
0.06
26%
1.04
0.125
0.22
0.15
69%
1.04
0.125
0.22
0.15
69%
Ethvl Benzene
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
m/p-Xvlene
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
Styrene
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
1.04
0,00
0.10
0%
1.04
0.00
0.10
0%
o-Xvlene
1.03
0.00
o.to
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
- -
OUTLET
DaatlMAS
I-Sep
12:10
DoutUAS
l-Sep
16:15
DoutUAS
1 -Sep
17:47
DoutRlAS
l-Sep
20:34
"NEW" HAPSITE
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Nath-e
Expected
Observed
%
Tat Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
Recovery
Tax Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
ppm
Recovery
CnhwimI
1,3-Butadiene
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0 10
0%
Hexane
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
Benzene
1.04
0120
0.21
0.22
104%
1.04
0.050
0.15
0.16
107%
1.04
0.097
0.19
0 17
19%
1.04
0.210
029
0.36
123%
Toluene
1.04
0.00
0.10
0.06
51%
1.04
0.00
0.10
0.05
4S%
1.04
0.00
o.to
0.05
48%
1.04
0.00
0.10
0.05
48%
Ethvl Benzene
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
1.04
0 00
0.10
0%
1.04
0.00
0.10
0%
m/p-X%1ene
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
Stvrene
104
0.00
0.10
0%
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
o-Xvlene
1.03
000
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
Ave. Recovery at 100 ppb
Inlet
Benzene
70%
Toluene
60%
- —
Outlet
Benzene
100%
Toluene
51%
-------
Table 6-2. Analyte Spiking Results
Various Spike Levels 9-2-99
100 ppb spike sample
200ppb spike sample
1 ppm spike sample
INLET
Dinr3asl
2-Sep
Dinr3as2
2-Sep
Dinr3as3
2-Sep
"OLD HAPSITE"
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Tag Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
ppm
Recovery
Compound
1,3-Butadiene
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
10.0
0.00
1.00
0%
Hexane
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
10.1
0.00
1.01
0%
Benzene
1.04
0.120
0.21
0.15
71%
1.04
0.120
0.32
0.24
76%
10.1
0.120
1.12
0.79
71%
Toluene
1.01
0.033
0.13
0.07
54%
1.01
0.033
0.23
0.15
65%
10.0
0.033
1.03
0.69
67%
Ethyl Benzene
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
10.1
0.00
1.01
0%
m/p-Xylene
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
10.1
0.00
1.01
0%
Styrene
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
10.1
0.00
1.01
0%
o-Xylene
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
10.0
0.00
1.00
0%
100 ppb spike sample
200ppb spike sample
1 ppm spike sample
OUTLET
"NEW" HAPSITE
Dotr3asl
2-Sep
Dotr3as2
2-Sep
Dotr3as3
2-Sep
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Certified
Native
Expected
Observed
%
Tag Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
ppm
Recovery
Tag Value
ppm
ppm
ppm
Recovery
Compound
1,3-Butadiene
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
10.0
0.00
r~ i.oo
0%
Hexane
1.03
0.00
0.10
0%
1.03
0.00
0.10
0%
10.1
0.00
1.01
0%
Benzene
1.04
0.148
0.24
0.30
126%
1.04
0.148
0.34
0.40
117%
10.1
0.148
1.14
1.37
120%
Toluene
1.01
0.00
0.10
0.06
59%
1.01
0.00
0.20
0.14
69%
10.0
0.00
1.00
0.83
83%
Ethyl Benzene
1.04
0.00
0.10
0%
1.04
0.00
0.10
0%
10.1
0.00
1.01
0%
m/p-Xylene
2.06
0.00
0.21
0%
2.06
0.00
0.21
0%
10.1
0.00
1.01
0%
Styrene
1.04
0.00
0.10
010
0%
1.04
0.00
0.10
L 0%
10.1
0.00
1.01
0%
o-Xylene
1.03
0.00
0%
1.03
0.00
0.10
0%
10.0
0.00
1.00
0%
-------
uncertainty. (Note that the tolerance allowed for audit of the calibration curve using the 1 ppm gas is
20%.)
5. Both the unspiked and the spiked concentration measurements are influenced by noise or imprecision
associated with the mass spectrometer measurements particularly at very low concentration levels.
(Note that the tolerance for the daily continuing calibration checks is 20% and that replicate injections
are performed to minimize the effects of noise in construction the fundamental calibration curve.
6. The limitations of the analyte spiking procedure require that the normal acceptable tolerance be 70% to
130% recovery relative to the expected concentration resulting from a 1 ppm spike. The spike
criterion is less restrictive than the +20% tolerance for the continuing calibration checks because it
reflects the limitations stated above. The spike criterion applied to a 100 ppb spike becomes very
restrictive! (i.e., 30 ppb for a 1 ppm spike versus 300 ppb for a 1 ppm spike)
7.0 OBSERVATIONS AND DISCUSSION
The main observations from this test program for the nine GCMS target analytes are as follows.
• Concentration levels of benzene and toluene were, on average, near the lowest level GCMS calibration
point of 100 ppb. No other GCMS target analytes (or any other volatile organic compounds detectable
by the GCMS) were detected in the diesel fired engine exhaust.
• Benzene and toluene were detected at the catalyst inlet and toluene only was detected at the catalyst
outlet. Based on past experience with liquid fuels, it was expected that combusting diesel fuel would
produce higher concentration levels of benzene and toluene than those detected during this testing
program. The low concentration levels observed during this test program are likely due to the very
high combustion and exhaust temperatures for this engine type. These high temperatures minimize the
formation of volatile organic products of incomplete combustion.
• The catalyst demonstrated no observable removal for benzene; however, apparent toluene removal
approximated 85% in almost every run. One probable explanation is that toluene and lighter weight
polynuclear aromatic hydrocarbons (i.e. naphthalene) adsorbed onto the soot convert to benzene across
the catalyst by desorption. In any case, toluene concentrations at the inlet location were so low that
the 85% removal of the catalyst corresponds to only about 100 ppb.
• It was very difficult to transport effectively the low concentration levels of the GCMS target analytes
to the instrumentation because of the adsorptive nature of the finely divided diesel soot. The soot is
likely comprised of highly organized groups of aromatic rings thus making it a perfect adsorbent for
organic aromatic compounds (such as the test program target analytes). Similar soot-like materials,
such as activated carbons, are frequently used in laboratory applications as adsorbents and in
chromatographic cleanup applications.
• The soot demonstrated a greater affinity for toluene as opposed to benzene as shown by the analyte
spike recoveries. This was true for all concentration levels of analyte spikes.
• The particulate soot loading at the outlet location was observed to be less than that at the inlet location,
suggesting that the soot is either burned or filtered by the catalyst. Another probable explanation for
the lack of benzene removal by the catalyst is that benzene may be formed as a product of incomplete
combustion from the burning soot.
• Most surely, there is a dynamic adsorption/desorption equilibrium between benzene and toluene (and
other aromatics), and the planar adsorptive groups on the finely divided soot in the high temperature
combustion environment. This equilibrium probably changes slightly as engine-operating parameters
change, along with the surface temperature of the catalyst.
10
-------
APPENDIX C
SUBCONTRACTOR TEST REPORT - EASTERN RESEARCH GROUP, INC.
"CARB METHOD 429: SAMPLE ANALYSIS"
-------
APPENDIX €
SUBCONTRACTOR TEST REPORT
EASTERN RESEARCH GROUP, INC.
"CARB METHOD 429: SAMPLE ANALYSIS"
-------
CARB Method 429: Sample Analysis
Contract #68-D7-0069-WA213-ERG
Prepared for:
Dennis Falgout
Pacific Environmental Services, Inc.
560 Herndon Parkway, Suite 200
Herndon, VA 22070
Prepared by:
Joan Bursey
Eastern Research Group, Inc.
P. O. Box 2010
Morrisville, NC 27560
December 1999
-------
feERG
fASTf&N RfScARCH QROUf
INC.
ATTACHMENT 1
P.O. Box 2010
Morrisvilie, NC 27560
Ph. (919) 468-7800
NARRATIVE
Site: Colorado State University • Engines and Energy Conversion Laboratory
Prepared for; Pacific Environmental Services
ERG Project No, 0070-02-002, Contract No. 68-D7-0008
Description of Procedures for Method CARB 429 and Observations
Sample Collection Dates: August 31,1999; September 1,1999; September 2,1999
Sample Preparation
Filters/XAD-2®
Procedure—The filters and XAD-2® were placed into soxhlets and extracted for approximately
18 hours with methylene chloride. Surrogate compounds were added to the soxhlets to verify
method recoveries. Also, the XAD-2® was spiked with recovery standards prior to sampling.
Observations—The filters were fairly clean and free of particulates: the XAD-2® had some
yellow discoloration. After pouring methylene chloride through the XAD-2*. some of the color
came off. but even after 18 hours of extractions, some of the XAD-218 retained the yellow color
and was eventually discarded.
Front Half, Back Half, and Impinger Rinses
Procedure—All three rinses were combined, then poured into a two liter separatory funnel.
Water was added to aid removal of the acetone from the sample and then extracted with
methylene chloride. The samples were then passed through a bed of sodium sulfate to remove
any residual water that might have been present. This fraction was eventually combined with the
Glp*:\0122\attach1 .wpd
occdocs
-------
rest of the other fractions for concentration except for the two knockout traps designated for
separate extraction on the Chain of Custody forms.
Observations—Due the amount of acetone in the rinses, when water was added to partition the
acetone from the methylene chloride / hexane in the rinse samples, an azeotrope was formed.
This reaction was not noticed until the samples were combined with the remaining fractions
(XAD-2<®/filter/reagent blanks). To avoid loss of analyte, water was repeatedly added to the
samples until the azeotrope did not form. Then the samples were extracted three times with
methylene chloride, passed through sodium sulfate and concentrated to final volume.
Impinger Contents/Knockout Traps
Procedure—The impinger contents were poured into individual separatory funnels for extraction.
Into each separatory funnei approximately 200 mL of HPLC grade methylene chloride was
added. The samples were shaken for approximately 3 minutes and then allowed to separate.
After separation, the bottom methylene chloride layer was drained into a clean, pre-rinsed beaker.
This procedure was then repealed two more times. The final extract was then set aside to be later
combined with the other fractions.
Observations—No observations out of the ordinary were noted.
Reagent Blanks
Procedure—Forty grams of clean XAD-2® (the same batch was used in the field test) with a clean
filter were extracted by soxhiet extraction Solvents used in the test were combined and
concentrated to 1 mL with the XAD-2®/filter extract.
All Samples
Procedure—After all components of the sample had been extracted, they were combined into a
1000 mL Kuderna-Danish flask. The samples were concentrated until approximately 10-15 mL
of solvent remained. The last 10-15 mL of solvent was evaporated using a nitrogen blowdown
apparatus. The samples were adjusted to a final volume of 1 mL with methylene chloride.
Sample Analysis Usirte Gas Chramatoeraphv/Mass Spectrometry
Combined Sample Extract Analysis by GC/MS
Procedure—All the sample extracts were analyzed by the California Air Resources Board
Method 429 (Determination of Polycyclic Aromatic Hydrocarbon (PAH) Emissions from
Stationary Sources) using a Hewlett Packard 5989B Mass Spectrometer operating in the selected
ion mode (SIM).
Glp\K:\Ql22\attach1.wpd 2
0CC30C3
-------
Observations-—No problems were encountered with the analysis of the sample extracts, although
there were problems with the DFTPP tune on October 15, 1999. The 441 ion failed the
40 - 110 percent relative percent abundance criterion, but the 12 hour continuing calibration
check was successful. Also. dl()-anthracene deteriorated in the stock standard supplied by
Cambridge Isotopes. This deterioration resulted in a one-point calibration for d1(l-anthracene in
the initial calibration (PES3), Surrogate recoveries were excellent in the method blank, but
recoveries for some compounds were poor (d|,-benzo(a)pyrene. dHI-anthracene), Oxidation by the
source effluent may also have contributed to the low recoveries of the surrogates in the field
samples. Clean-up procedures to remove the hydrocarbons present in the sample extracts could
enhance the method's ability to recover specific PNAs.
Compound concentrations were corrected for surrogate recoveries when surrogate recoveries
were below 100 percent. Target compounds were also flagged if they were detected below the
practical quantitation limit (PQL) with a "U". The PQL is as follows:
Compound
Total ne
Naphthalene
100
Acenaphthylene
100
Acenaphthene
100
Fluorene
100
Phenanthrene
100
Anthracene
100
Fluoranthene
100
Pyrene
100
Benzo(a)anthracene
100
Chrysene
100
Benzol bifluoranthene
100
Benzo(k )fluoranthene
100
Benzo(a)pyrene
100
lndeno{ l.2,3-cd)pyrene
100
Dibenzl u.h)anthracene
100
Benzo(g,h,i)perylene
100
MDL Study
In addition to the PQL. a method detection limit (MDL) study was performed.
Procedure—XAD-2® was placed into ten soxhlets and extracted 18 hours following 40 CFR
Part 136B. The target analvtes were spiked for a 99.9% confidence level. The concentration
selected was determined from the previous set of conditions for CARB 429. Between the first
set of samples and the current set, analytical conditions were improved to increase instrument
Glp\K,*\0l22\attacht,wfxi 3
OCC30 id
-------
sensitivity observations. Because of the increased instrument sensitivity, the concentration of the
spikes was in the top half of the calibration curve. The MDL results are as follows;
Compound Total ng
Naphthalene 670
Acenaphthylene 850
Aeenaphthene 760
Fluorene 760
Phenanthrene 700
Anthracene 920
Fluoranthene 620
Pyrene 610
Benzo( a)anthracene 670
Chrysene 720
Benzo(b)fluoranthene 940
Benzo(k)fluoranthene 1,000
Benzo(a)pyrene 1,040
Indeno( 1,2,3-cd)pyrene 750
Dibenz(a,h)anthracene 770
Benzo(g.h.i )perylene 640
Glp\K:\0122\attach1 .wpd
4
OCCJQil
-------
PES - PAH Samples
8/31/99 - 9/2/99
Field ID
Sample ID
Data File
Date Analyzed:
Compounds
Naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
lndeno{1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h ijperylene
METHOD BLANK
ENG1673
10/16/99
C-429-RB-XAD
REAGENT BLANK
ENG1674
10/16/99
C-429-I-FB
INLET FIELD BLANK
ENG167S
10/16/99
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
Cone, (ng/sample)
w/ Surr. correction
847
1,081
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
Compounds
\aphthalene-d8
Acenaphthylene-d8
Acenaphthane-d10
Fluorene-d10
Phenanthrene-d10
Anthracene-d10
Fluoranthene-d10
Pyrene-d10
BenzD(a)anthracene-d12
Chrysene-d12
Benzo( b)fluoranthene-d12
Benzojk)fluoranthene-d12
Benzo(a)pyrene-d12
lndeno(1,2,3-cd)pyrene-d12
Dibenz(a,h)arsthracene-d14
Senzo(g,h,i)perylene-d12
68
119
100
140
101
105
135
103
124
123
116
119
119
111
Surrogate Recoveries
% Recovery
57
110
93
135
90
92
128
91
112
116
100
85
96
93
21
23
56
65
75
155
76
70
45
71
79
71
0
44
49
48
Compounds
2-Methlynaphthalene-d10
p-Terphenyl-d14
NS
NS
Recovery Standard
% Recovery
78
80
33
71
ND = Not Detected
NS = Not spiked
U = Detected below the method detection limit
DL = Diluted Value
1 of 4
1411 •-
•J'kM Lfi*
SUMMARY2.XLS
-------
PES - PAH Samples
8/31/90 - 9/2/99
Field ID
Sample ID
Data File
Date Analyzed:
C-429-O-FB
OUTLET FIELD BLANK
ENG1676
10/16/99
C-429-1-K0-1
KNOCK OUT
ENG1677
10/16/99
C-429-I-KO-2
KNOCK OUT
ENG1678
10/16/99
Compounds
Naphthalene
Acenaphthylene
Acersaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracene
Chrysene
Benzo(b)fIuoranthene
Benzc(k)fluoranthene
Benzo(a)pyrene
lndeno(1,2,3-cd)pyrene
Dibenz(a.h)anthracene
Benzo(g,h,i)perylene
Cone, (ng/sample)
w/ Surr. correction
965 <100
<100 <100
<100 <100
<100 <100
29 <100
69 <100
<100 <100
<100 <100
<100 <100
<100 <100
<100 <100
<100 <100
<100 <100
<100 <100
<100 <100
<100 <100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
<100
Surrogate Recoveries
% Recovery
Compounds
Naphthalene-d8 39 NS NS
Aeenaphthylene-d8 57 NS NS
Aeenaphthene-d10 73 NS NS
Fluorene-d10 78 NS NS
Phenanthrene-d1C 81 NS NS
Anthracene-d10 82 NS NS
Fluoranthene-d10 84 NS NS
Pyrene-d10 84 NS NS
Benzo(a)anthracene-d12 130 NS NS
Chrysene-d12 82 NS NS
Benzo(b)fluoranthene-d12 113 NS NS
Benzo(k)fluoranthene-d12 137 NS NS
Benzo(a)pyrene-d12 106 NS NS
lndeno( 1,2,3-cd)py rene-d12 96 NS NS
Dibenz(a,h)anthracene-d14 103 NS NS
Benzc(g,h,i)perylene-d12 86 NS NS
Compounds
2-Methlynaphthalene-d10
p-Terphenyl-d14
71
Recovery Standard
% Recovery
NS
NS
NS
NS
ND = Not Detected
NS = Not spiked
U = Detected below the method detection limit
DL = Diluted Value
2 of 4
',
-------
PES - PAH Samples
8/31/99 - 9/2/99
Field ID C-429-1-1 C-429-0-1 CB-429-I-2 C-429-G-2
Sample ID INLET 1 OUTLET 1 INLET 2 OUTLET 2
Data File ENG1679/1692 ENG16S0 ENG1681/1893 ENG1682
Date Analyzed: 10/16/99 10/16/99 10/16/99 10/16/99
Cone, (rig/sample)
w/ Surr. correction
Compounds
Naphthalene
97,651
DL
9,164
160,869
DL
8,121
Acenaphthylene
7,129
DL
318
U 15,102
DL
<100
Aeenaphthene
<100
<100
<100
<100
Fluorene
22,648
DL
<100
31,766
DL
154
Phenanthrene
31,163
DL
672
52,683
DL
436
Anthracene
<100
<100
4,720
<100
Fluoranthene
1,922
<100
11,858
DL
<100
Pyrene
7,520
DL
<100
18,559
DL
<100
Benzo(a)anthracene
<100
<100
779
<100
Chrysene
751
<100
2,074
<100
Benzo(b)fluoranthene
188
<100
1,169
<100
Berizo(k)fluoranthene
77
U
<100
325
<100
Benzo(a)pyrene
<100
<100
<100
<100
lndeno(1,2,3-cd;pyene
<100
<100
<100
<100
Dibenz(a, h)anthracene
<100
<100
<100
<100
Benzo(g,h.i)perylene
<100
<100
<100
<100
Surrogate Recoveries
% Recovery
Compounds
Naphthalene-d8
67
51
42
52
Acenaphthylene-d8
93
11
49
10
Acenaphthene-d10
66
92
8
80
Fluorene-d10
103
93
69
95
Phenanthrene-d10
92
81
56
83
Arrthracene-d10
80
ND
79
14
Fluorartthene-d10
101
83
74
85
Pyrene-diO
102
66
76
75
Benzo(a)anthracerie-d12
100
44
80
93
Chrysene-d12
63
78
47
78
Benzo{b)fluoranthene-d12
78
98
60
96
Benzo(k)fluoranthene-d12
82
91
64
97
Benzo(a)pyrene-d12
49
ND
52
ND
lndeno(1,2,3-cd)pyrene-d12
84
62
75
76
Dibenz(a,h)anthracene-d14
78
63
72
77
Benzo(g,h,i)perylene-d12
67
55
57
59
Recovery Standard
% Recovery
Compounds
2-Methlynaphthalene-d10 42 72 25 72
p-Terphenyl-d14 75 67 46 66
ND = Not Detected
NS = Not spiked
U = Detected below the method detection limit
DL = Diluted Value 3 of 4 SUMMARY2.XLS
l/i, i, j-U i_ -x
-------
PES - PAH Samples
8/31/89 - 9/2/99
Field ID
Sample ID
Data File
Date Analyzed:
Compounds
Naphthalene
Acenaphthylene
Acenaphthene
Fluorene
Phenanthrene
Anthracene
Fluoranthene
Pyrene
Benzo(a)anthracerie
Chrysene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo{a)pyrene
lndeno(1,2,3-cd)pyrene
Dibenz(a,h)anthracene
Benzo(g,h,i)perylene
C-429-I-3 C-429-0-3
INLET 3 OUTLET 3
ENG1683/1694 ENG1684
10/16/99 10/16/99
Cone, (ng/sample)
w I Surr. correction
224,365
DL
6,617
20,748
DL
1,567
<100
<100
32,744
DL
71
69,574
DL
153
<100
<100
14,867
DL
52
20,863
DL
<100.
682
<100
1,954
<100
997
<100
240
<100
<100
<100
<100
<100
<100
<100
<100
<100
Surrogate Recoveries
% Recovery
Compounds
Napnthalene-d8 63 40
Acenaphthylene-d8 53 8
Acenaphthene-d1Q ND 86
Fluorene-dlQ 106 89
Phenanthrene-d10 72 79
Anthracene-d10 89 12
Fluoranthene-d10 95 78
Pyrene-d10 99 67
Benzo(a)anthracene-d12 102 68
Chrysene-d12 60 66
Banzc(b)fluoranthene-d12 73 66
Benzo(k)fluoranthene-d12 74 64
Benzo{a)pyrene-d12 37 ND
lndeno(1,2,3-cd)pyrene-d12 80 43
Dibenz(a,h)anthracene-d14 78 46
Benzo(g,h,i)perylene-d12 57 30
Compounds
2-Methlynaphthalene-d10
p-Terphenyl-d14
37
58
Recovery Standard
% Recovery
64
64
ND = Not Detected
NS = Not spiked
U = Detected below the method detection limit
DL = Diluted Value
4 of 4
oe
SUMMARY2.XLS
-------
ERG PPK Sample Prep Traveler
Project Name:
PES
Analysis Type:
MS
Analyst;
Mitchell Howell
Date released:
9/17/99
ERG Sample iD
Date
Sampled
Date
Extracted
Surrogate
ID Amt
Concen-
tration
Date
Final Vol. &
Solvent
Method Blank
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
REAGENT BLANK
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
PES INLET-FB
9/1/99
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
PES OUTLET-FB
9/1/99
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
PES INLET-1
8/31/99
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
PES OUTLET-1
8/31/99
9/13/99
PES-JEM
041499-01
1ml
9/17/99
Hex
1mL
PES INLET-2
9/1/99
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
PES OUTLET-2
9/1/99
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
PES INLET-3
9/2/99
9/13/99
PES-JEM
041499-01
1mL
9/17/99
Hex
1mL
PES OUTLET-3
9/2/99
9/13/99
PES-JEM
041499-01
1mL
9/17/99
hex
1mL
KNOCKOUT 1
9/2/99
9/15/99
9/17/99
MeCI2
1mL
KNOCKOUT 2
9/2/99
9/15/99
9/17/99
MeCI2
1mL
OCt -ij<
-------
ERG PPK Sample Prep Traveler
Project Name:
Analysis Type:
Analyst:
Date released:
PES
MS
Mitchell Howell
9/17/99
ERG Sample ID
Date
Sampled
Date
Extracted
Surrogate
ID Amt
Concen-
tration
Date
Final Vol. &
Solvent
Method Blank
9/13/99
PES-JEM
041499-01
0.5ml
9/17/99
Hex
1mL
REAGENT BLANK
9/13/99
PES-JEM
041499-01
0,5mL
9/17/99
Hex
1ml
PES INLET-FB
9/1/99
9/13/99
PES-JEM
041499-01
0.5mL
9/17/99
Hex
1mL
PES OUTLET-FB
9/1/99
9/13/99
PES-JEM
041499-01
0.5mL
9/17/99
Hex
1mL
PES INLET-1
8/31/99
9/13/99
PES-JEM
041499-01
0.5mL
9/17/99
Hex
1mL
PES OUTLET-1
8/31/99
9/13/99
PES-JEM
041499-01
0.5mL
9/17/99
Hex
1mL
PES INLET-2
9/1/99
9/13/99
PES-JEM
041499-01
0.5mt
9/17/99
Hex
1mL
PES OUTLET-2
9/1/99
9/13/99
PES-JEM
041499-01
0.5mL
9/17/99
Hex
1mL
PES INLET-3
9/2/99
9/13/99
PES-JEM
041499-01
0.5ml
9/17/99
Hex
1mL
PES OUTLET-3
9/2/99
9/13/99
PES-JEM
041499-01
0.5mL
9/17/99
hex
1mL
KNOCKOUT 1
9/2/99
9/15/99
9/17/99
MeCI2
1mL
KNOCKOUT 2
9/2/99
9/15/99
9/17/99
MeCI2
1mL
Ot €
-------
nn r—i i—i
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
I533.000
Project Name
US EPA RICE Caterpillar 3508 EUI
Analysis Requested
Samplers:
D.D. Holzschuh, Maret, Urban
CM
Remarks
Date
Time
Field Sample ID
Sample Description
00
a:
<
o
8/31/99
19:35
C-429-I-1-F
Filter ^
V
Inlet Run No. 1
8/31/99
19:35
C-429-I-1-FH
Front Half Rinse''
V
Inlet Run No. 1
8/31/99
19:35
C-429-1-1 -XAD
XAD Module "
V
Inlet Run No. 1
8/31/99
19:35
C-429-1-1 -BH
Back Half Rinse'
V
Inlet Run No. 1
8/31/99
19:35
C-429-1-1-IC
Impinger Contents '
V
Inlet Run No. 1
8/31/99
19:35
C-429-1-1-IR
Impinger Rinse '
V
Inlet Run No. 1
8/31/99
18:30
C-429-0-1-F
Filter ,
V
Outlet Run No. 1
8/31/99
18:30
C-429-0-1 -FH
Front Half Rinse '
V
Outlet Run No. 1
8/31/99
18:30
C-429-0-1 -XAD
XAD Module -
V
Outlet Run No. 1
8/31/99
18:30
C-429-0-1-BH
Back Half Rinse -
V
Outlet Run No. 1
8/31/99
18:30
C-429-0-1-IC
Impinger Contents -
V
Outlet Run No. 1
8/31/99
18:30
C-429-0-1-IR
Impinger Rinse "
V
Outlet Run No. 1
9/1/99
12:00
C-429-RB-F
Filter Blank ,
V
Reagent Blank
9/1/99
12:00
C-429-RB-XAD
XAD Blank ^
V
Reagent Blank
9/1/99
12:00
C-429-RB-DI
Dl Water Blank -
yf
Reagent Blank
9/1/99
12:00
C-429-RB-A
Acetone Blank -
V
Reagent Blank
9/1/99
12:00
C-429-RB-H
Hexane Blank '
V
Reagent Blank
9/1/99
12:00
C-429-RB-M
MeCI2 Blank -
V
Reagent Blank
9/1/99
14:00
C-429-0-FB-F
Filter
y/
Outlet Field Blank
9/1/99
14:00
C-429-0-FB-FH
Front Half Rinse
V
Outlet Field Blank
9/1/99
14:00
C-429-0-FB-XAD
XAD Module-
V
Outlet Field Blank
9/1/99
14:00
C-429-O-FB-BH
Back Half Rinse
yf
Outlet Field Blank
9/1/99
14:00
C-429-0-FB-IC
Impinger Contents ^
V
Outlet Field Blank
9/1/99
14:00
C-429-0-FB-IR
mpinger Rinse "
V
Outlet Field Blank
9/1/99
18:55
C-429-I-2-F
Filter r
V
Inlet Run No. 2
9/1/99
18:55
C-429-I-2-FH
Front Half Rinse -
V
Inlet Run No. 2
Page 1 of 3
-------
nUEUj{^D
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX: (919) 941-0234
Chain of Custody Record
Project Num
1533.000
Project Name
US EPA RICE Caterpillar 3508 EUI
Analysis Requested
Remarks
Samplers:
D O. Holzschuh, Maret, Urban
CARB 429
Date
Time
Field Sample ID
Sample Description
9/1/99
18:55
C-429-I-2-XAD
XAD Module
V
Inlet Run No. 2
9/1/99
18:55
C-429-I-2-BH
Back Half Rinse
V
Inlet Run No. 2
9/1/99
18:55
C-429-I-2-IC
Impinger Contents
V
Inlet Run No. 2
9/1/99
18:55
C-429-I-2-IR
Impinger Rinse*/
V
Inlet Run No. 2
9/1/99
8:38
C-429-0-2-F
Filter ^
V
Outlet Run No. 2
9/1/99
18:38
C-429-0-1-FH
Front Half Rinse c/
V
Outlet Run No. 2
9/1/99
18:38
C-429-0-2-XAD
XAD Module ^
yf
Outlet Run No. 2
9/1/99
18:38
C-429-0-2-BH
Back Half Rinsev/
V
Outlet Run No. 2
9/1/99
18:38
C-429-0-2-IC
Impinger Contents^
yf
Outlet Run No. 2
9/1/99
18:38
C-429-0-2-IR
Impinger Rinsed
V
Outlet Run No. 2
9/2/99
9:30
C-429-I-3-F
Filter^
V
Inlet Run No. 3
9/2/99
9:30
C-429-I-3-FH
Front Half Rinse ^
V
Inlet Run No. 3
9/2/99
9:30
C-429-I-3-XAD
XAD Module —
yf
Inlet Run No. 3
9/2/99
9:30
C-429-I-3-BH
Back Half Rinse
V
Inlet Run No. 3
9/2/99
9:30
C-429-I-KO-1
Knock-out Impinger Bottle 1 of 2
V
ANALYZE SEPARATELY
9/2/99
9:30
C-429-I-KO-2
Knock-out Impinger Bottle 2 of 2
yf
ANALYZE SEPARATELY
9/2/99
9:30
C-429-I-3-IC
Impinger Contents^
yf
Inlet Run No. 3
9/2/99
9:30
C-429-I-3-IR
Impinger Rinse
yf
Inlet Run No. 3
9/2/99
9:52
C-429-0-3-F
Filter
yf
Outlet Run No. 3
9/2/99
9:52
C-429-0-3-FH
Front Half Rinse^
yf
Outlet Run No. 3
9/2/99
9:52
C-429-0-3-XAD
XAD Module ^
yf
Outlet Run No, 3
9/2/99
9:52
C-429-0-BH
Back Half Rinse '
yl
Outlet Run No. 3
9/2/99
9:52
C-429-0-3-IC
Impinger Contents ¦"
yf
Outlet Run No. 3
9/2/99
9:52
C-429-0-3-IR
Impinger Rinse ^
y/
Outlet Run No. 3
9/2/99
14:00
C-429-I-FB-F
Filter
V
Inlet Field Blank
9/2/99
14:00
C-429-I-FB-FH
Front Half Rinse ^
yf
Inlet Field Blank
Page 2 of 3
-------
O PACIFIC ENVIRONMENTAL SERVICES, INC.
Central Park West
5001 South Miami Boulevard, P.O. Box 12077
Research Triangle Park, North Carolina 27709-2077
(919)941-0333 FAX. (919) 941-0234
Chain of Custody Record
Project Num
I533.000
Project Name
US EPA RICE Caterpillar 3508 EUI
Analysis Requested
Remarks
Samplers:
D.D. Holzschuh, Maret, Urban
CARB 429
Date
Time
Field Sample ID
Sample Description
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
Relinquished by: (Signature)
Date/Time
Received by: (Signature)
^V^^^^^f(^^iatur e)
Date/Time
m
I7CO
Received for lab bvL. (SigpAure) ., >
\xov
REMARKS
Q
Page 3 of 3
-------
SEQUENCE.LOG
Simulate Run Sequence Mon Nov 01 16:31:16 1999
Instrument Name: HP 5989B
Sequence File: C:\HPCHEM\1\SEQUENCE\1014.S
Comment:
Operator:
Data Path: C:\HPCHEM\l\DATA\
Method Path: C:\HPCHEM\l\METHODS\
Line Type Vial DataFile Method Sample Name
1} DFTPP 1 EN61653 TUNING 8270C,QA/QC,1Q14DFT
PP,
2) Calibration 2 ENG1654 PES3
CARB429,ICALO.1
3) Calibration 3 ENG1655 PES3
CARB429,ICALO.25
4) Calibration 4 ENG1656 PES3
CARB429,ICALO.5
5) Calibration 5 ENG1S57 PES3
CARB429,ICAL1.0
S) Calibration 6 ENG1658 PES3
CARB429,ICAL2.0
7) Calibration 7 ENG1659 PES3
CARB429,ICAL3.0
Bytes Needed: 302271
Sequence Verification
Space on drive C: 344588288
Done!
Page 1
occjtwa
-------
SEQUENCE.LOG
Simulate Run Sequence Fri Oct 15 11:37:19 1999
Instrument Name
Sequence File
Comment
Operator
Data Path
Method Path
Line Type
HP 5989B
C:\HPCHEM\l\SEQUENCE\l015.S
C:\HPCHEM\l\DATA\
C:\HPCHEM\1\METH0DS\
Vial DataFile Method Sample Name
PP,
1} DFTPP
2) Calibration
3} Calibration
1 ENG1660 TUNING 8270C,QA/QC,1014DFT
2 ENG1661 PES3
3 ENG16621-//'PES3
CARB4 2 9,MDLBLK
CARB4 2 9,MDL1
4} Calibration 4 ENG1663 ^ PES3
5) Calibration
6) Calibration
5 ENG16 64 PES3
/
6 ENG1665 ^ PES3
CARB4 2 9,MDL2
CARB429,MDL3
CARB429,MDL4
7) Calibration 7 ENG1666 PES3
CARB429,MDL5
8) Calibration
8 ENG1667 PES3
CARB42 9,MDL6
9) Calibration
9 ENG1S68 PES3
CARB4 2 9,MDL7
10) Calibration 10 ENG1669 PES3
CARB429,MDL8
11) Calibration 11 ENG1670 PES3
CARB42 9,MDL9
PP,
12) DFTPP
13) DailyCal
14! Sample
15)' Sample
1 ENG1671 TUNING 8270C,QA/QC,1014DFT
12 ENG1672 PES3
13 ENG1673 PES3
14 ENG1674 PES3
CARB429,CCAL1.0,
CARB429,M.B
CARB429,REAGENT BLK
Page 1
IjvT <-¦)
V 4* Xj jr *J> w ij
-------
SEQUENCE.LOG
16) Sample
BLANK
17) Sample
D BLANK
18 5 Sample
OCKOUT
19) Sample
OCKOUT
20) Sample
15 ENG1675 PES3
16 ENG1676 PES3
17 ENG1677 PES3
18 ENG1678 PES3
19 ENG167 9 PES3
21) Sample
22) Sample
23) Sample
24) Sample
20 ENG1680 PES3
21 ENG1681 PES3
22 ENG1682 PES3
23 ENG1683 PES3
25) Sample
24 ENG1684 PES3
Bytes Needed: 1154542 Space on. drive C
Sequence Verification Done!
CARB429,INLET FIELD
CARB429,OUTLET FIEL
CARB4 2 9,OUTLET 1 KN
CARB42 9,OUTLET 2 KN
CARB429,INLET 1
CARB42 9,OUTLET 1
CARB429,INLET 2
CARB42 9,OUTLET 2
CARB429, INLET 3
CARB4 2 9,OUTLET 3
395837440
Page 2
Oil' -C-'I
-------
SEQUENCE.LOG
Simulate Run Sequence Mon Nov 01 16:24:29 1999
Instrument Name: HP 5989B
Sequence File: C:\HPCHEM\1\SEQUENCE\1019.S
Comment:
Operator:
Data Path: C:\HPCHEM\1\DATA\
Method Path: C:\HPCHEM\l\METHODS\
Line Type
Vial DataFile Method
Sample Name
1
2
3
4
5
6
7
, 20|iL/lQOO|iL,
8} Sample 8
, 20^L/1000^iL,
9) Sample 9
,20^L/1000mL,
Bytes Needed: 402271
Sequence Verification
1)
DFTPP
pp,
2)
DailyCal
.0,
3)
DailyCal
25
4)
DailyCal
5,
5)
DailyCal
.0
6)
DailyCal
. 0,
7)
Sample
ENG1685 TUNING
ENG1687 PES3
ENG1688 PES3
ENG1689 PES3
ENG1690 PES3
ENG1S91 PIS3
ENG1692 PES3
ENG1693 PES3
ENG1694 PES3
Space on drive C:
Done!
8270C,QA/QC, 1014DFT
CARB42 9,QA/QC,CCAL1
CARB429,QA/QC,CCAL.
CARB42 9,QA/QC,CCAL.
(3ARB429 , QA/QC, CCAL2
CARB429,QA/QC,CCAL3
CARB429,INLET1 1:50
CARB429,INLET2 1:50
CARB42 9,INLET3 1:50
344653824
Page 1
-------
Pre-spike solution:
PES-JEM-032299-01
PES Stocks
Manufacturer Lot# Initial Raw Solution Final
Cone Amount Volume Cone
(jig/mL) (g) (mL) (|jg/mL)
p-Terphenyl-d14 Chem Service
214-144A
2000
5
2000
2-Methylnaphthalene-d10 Aid rich
02415BQ
0.01013
5
2026
Pre-spike solution:
Initial
Initial
Final
Final
PES-JEM-032299-02 *
Cone
Volume
Volume
Cone
((ig/mL)
(mL)
(mL)
(H9'mL)
p-Terphenyl-d14
2000
1
50
40.0
2-Methylnaphthalerie-d10
2026
1
50
40.5
* Dilution made from PES-JEM-032299-02
Manufacturer
Lot#
Initial
Initial
Final
Final
Cone
Volume
Volume
Cone
(|jg/mL)
(mL)
(mL)
(MQ/mL)
~-labelled
PES-JEM-041499-01
Acenaphthalene-d10
CIL
IG-248
100
1
25
4
Acenaphthylene-d8
CIL
IG-248
100
1
25
4
Anthracene-d10
CIL
IG-248
100
1
25
4
Benz[a]anthracerie-d12
CIL
IG-248
100
1
25
4
Benzo{b]fluoranthene-d12
CIL
IG-248
100
1
25
4
Benzof kjfluora nthene-d12
CIL
IG-248
100
1
25
4
Benz0[ghi]perylene-d12
CIL
IG-248
100
1
25
4
Benzo[a]pyrene-d12
CIL
IG-248
100
1
25
4
Chrysene-d12
CIL
IG-248
100
1
25
4
Dibenz[ah}anthracene-d14
CIL
IG-248
100
1
25
4
Fluoranthene-d10
CIL
IG-248
100
1
25
4
Fluorene-d1Q
CIL
IG-248
100
1
25
4
I n deno[ 123-cd]pryene-d 12
CIL
IG-248
100
1
25
4
Naphthalene-d8
CIL
IG-248
100
1
25
4
Phenanthrene-d10
CIL
IG-248
100
1
25
4
Pyrene-d10
CIL
IG-248
100
1
25
4
Manufacturer
Lot#
Initial
Initial
Raw
Solution
Cone
Volume
Amount
Volume
(pg/mL)
(mL)
(9)
(mL) i
Internal Standard
PES-JEM-051199-01
2,2-Difluorobiphenyl
AecuStandard
A7120073
2,002
0.25
1
Methylene Chloride Lot # -
B & J BS575
Final
Cone
(ng/mL)
500,5
Page 1
0CC3033
-------
PES Stocks (2)
Manufacturer
Lot#
Initial
Cone
(pg/mL)
Raw
Amount
(g)
Solution
Volume
(mL)
Final
Cone
(jig/mL)
Pre-spike solution;
PES-JEM-032299-01
p-Terphenyl-d14
2-MethylnaphthaJene-d 10
Chem Service
Aldrioh
214-144A
02415BQ
2000
0.01013
5
5
2000
2026
Pre-spike solution:
PES-JEM-082399-01 *
Initial
Cone
(MQ/mL)
Initial
Volume
(mL)
Final
Volume
(mL)
Final
Cone
(|ig/mL)
p-Terphenyl-d14
2-Methylnaphthalene-d10
2000
2026
0,1
0,1
50
50
4.0
4.1
* Dilution made from PES-JEM-032299-Q1
0CCJ034
Page 1
-------
PES: STANDARDS PREPARATION
PES-MAH-«51299-t2
PES-MAH-051299-03
PES-MAH-051299-04
FES-MAH-051299-05
Stock Com.
Amoaat
Flml
StdCMC.
Aaawt
Flul
StdCoac.
Amwt
Raal
Std Coac.
Amoaat
Flaal
Std Coac.
Ckeaictl Name
(m/"l)
Spilwd (mL)
VoHmm(mL)
W»L)
Spiked (mL)
VoImm (mL)
Spiked (mL)
VoIum (mL)
Spiked (mL)
Volaaw (mL)
WmL)
Naphthalene-d8
100.0
0.05
1.0
03
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Naphthalene
2004.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
2 -Methy naphthalene-d 10
2026.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.1
Acenaphthylene-d8
100.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Acenaphthylene
2008.4
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Acenaphthene-dl0
100.0
0.05 -
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Acenaphthene
2008.1
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Fhiorene-dlO
100.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
FIuotww
2009.4
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Phenanthrene-dl 0
100.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Phenanthrene
2014.1
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Anthracene-dlO
100.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Anthracene
2010.5
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Fluoranthene-dl 0
100.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Fluoranthene
2008.4
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Pyrene-dl 0
100.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Pyrene
2005.8
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
p-Terphenyl-dl 4
2000.0
0.05
1.0
0.5
0.10
1.0
1.0
0.25
1.0
2.5
0.50
1.00
5.0
Benzo(a)anthracene-
-------
PES: STANDARDS PREPARATION
PES-MAH-051299-06
PES-MAH-051299-01
PES-MAH-051899-01
Stock Caac.
Aaomt
Flaal
Sid Come.
Aaomt
Fiul
StdCoac.
Anont
Fiaal
Std Coac.
ChcMical Na««
Spiked (mL)
Votam (mL)
(m/mL)
Spiked (mL)
Velam (»L)
Spiked (mL)
VehiaM -Terphenyl-dl 4
2000.0
0.70
1.0
7.0
0.025
5.0
10.0
0.0075
1.0
15.0
Benzo(a)anthracene-d 12
100.0
0.70
1.0
7.0
0.50
5.0
10.0
0.15
1.0
15.0
Benzo(a)anthracenc
2010.6
0.70
1.0
7.0
0.025
5.0
10.1
0.0075
1.0
15.1
Chrysene-dl 2
100.0
0.70
1.0
7.0
0.50
5.0
10.0
0.15
1.0
15.0
Chrysene
2009.2
0.70
1.0
7.0
0.025
5.0
10.0
0.0075
1.0
15.1
Benzo(b)fluoranthene-
-------
VENDERS
Cambridge Isotope Laboratories (Labeled PNAs)
Lot * IG-248
lOOpg/mL
AccuStandard (Native PNAs)
A7120073
2000pg/mL
Working Stock (PNAs)
50uL Accustandard X 2000ua/mL
= 100(jg/mL
1000|jL Methylene Chloride |
I
f.-
O
o
o
-------
Sheetl
pes-mah-101499-01 [ |
p«s-mah-101399-03 | J
pes-mah-101399-02 | |
Amount spiked Final Volume
Std. Cone
Amount spiked Final Volume
Std. Cone
Amount spiked Final Volume
Std. Com;
compound
Stock pg/mL
ML
ML
pg/mL
ML
ML
pg/mL
ML
ML
MB/rtL'.
Naphthalene
100
1.0
1000
0.10
2.S
1000
0.25
5.0
1000
0.54?
Acenaphthylene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.5C™
Acenaphthene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0 5Q"
Fluorene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.5Q*-.
Phenanthrene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.5tb
Anthracene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50H"
Fluoranthene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50C
Pyrene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(a)anthracene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Chrysene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(b)fluoranthene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(k)fluoranthene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(a)pyrene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
lndeno(1,2,3-cd) pyrene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Dibenz(a,h)anthracene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(g,h,i)perytene
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Naphthalene-d8
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Acenaphthylene-d8
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Acenaphthene-d 10
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Fhjorene-dlO
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Phenanthrene-dIO
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Anthracene-d10
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Fluoranthene-d 10
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Pyrene-d10
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(a)anthracene-d12
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Chrysene-d12
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(b)fluoranthene-d 12
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(k)fluoranthene-d12
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(a)pyrene-d 12
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
lndeno(1,2,3-cd)pyrene-d 12
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Dibenz(a,h)anthracene-d14
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Benzo(g ,h, i)perylene-d12
100
1.0
1000
0.10
2.5
1000
0.25
5.0
1000
0.50
Page 1
-------
Sheetl
pes-mah-101499-02 | |
pes-mah-101499-03 | |
pes-mah-101499-01 | |
Amount spiked Final Volume
Std. Cone
Amount spiked Final Volume
Std. Cone
Amount spiked Final Volume
Std. Cone
ml
ml
pg/mL
H-
ML
Mg/mL
ml
ML
Mg/mL
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
10.0
1000
1.00
20.0
1000
2.00
30.0
1000
3.00
en
co
o
-------
Cambridge Isotope Laboratories, Inc.
jo Frontage Road, Andover, MA 01810-5413 usa
ph: 800.3z2.n74 (USA) PH: 978.749.8000
fAx: 978.749.1768 url: http://www.isotopc.com
Technical Data Sheet
Compound:
PAH Cocktail for CARB Method 429
containing approximately 100 ± 10pg/mL
of each of the following:
Acenaphthene (D-jo. 98%)
C12D10
Acenaphthylene (Dg, 98%)
C12D8
Anthracene (D-jq. 98%)
C14D10
Benz[a]anthracene (D-12.98%)
C18D12
Benzo{b]fluoranthene (D12.98%)
C20D12
Benzofkjfluoranthene (D^, 98%)
c20°12
Benzojghijperylene (D12.98%)
C22D12
Benzo[a]pyrene (D-|2,98%)
C20D12
Chrysene (D12.98%)
C18D12
Dibenz[ah]anthracene (D14,97%)
C22D14
Fluoranthene (Dio> 98%)
Cl6D10
Fluorene (D-jo, 98%)
C13D10
lndeno[123-cd]pyrene (Df2< 98%)
C22D12
Naphthalene (Dg, 98%)
C10D8
Phenanthrene (D-jq. 98%)
C14D10
Pyrene (D-jg, 98%)
c16°10
Catalog Number:
ES-2528
Lot Number:
IG-248
Chemical Purity:
98%+
Amount:
1 milliliter
Solvent:
Benzene (Dg, 99.6%)
Date Prepared: 3/98
OCCOOiO
-------
ABSOLUTE STANDARDS, INC • 44 Rossotto Drive • Hamden, CT • 06514 • (800)-368-1131
ISO 9001 Quality System Registered.
DLS ANSI-RAB Accredited.
CERTIFIED WEIGHT REPORT: Uncertainty < +,-0.5% Stated Values.
Part Number: 10017
Lot Number:
Description:
Expiration Date:
Nominal Concentration (pg/mL):
Weight(s) shown below were combined and diluted to:
092398
CLP Semi-Volatiles - PAH Mix
16 Components
092403 Solvents): Lot #
Methylene Chloride M03A01
2000 Benzene G06634
500
mL.
(50%)
(50%)
Formulated By:
l/^f- X _
f~ ' 092398
Vincent K. Criscio, Jr.
DATE
Reviewed By:
^ 092398
Pedro L. Rentas
DATE
Compound
RM#
MSDS Information
Nominal Purity Max. Target Actual -Actual (Solvent Safety Info. On Attached pg.)
Lot Number Cone (pg/ml_) (%) Weight(g) Welght(g) Cone (pg/mL) CAS# OSHA PEL (TWA) LDSO
o
O
1. Acenaphthene 1 01619AX 2000 99 1.01010 1.00403 2008.1 00083-32-9 n/a n*-r«t noomg/ng
2. Acenaphthylene
3
HKY-27456-24
2000
99
1.01010
1.00421
2008.4
00208-96-8
N/A
N/A
3. Anthracene
13
04806HX
2000
99
1.01010
1.00527
2010.5
00120-12-7
0.2mgfrn3 (8H>
Ipr-mut 430mgfeg
4. Benzo(a)anthracene
28
31331-13
2000
99
1.01010
1.00531
2010.6
00056-55-3
N/A
N/A
5. Benzo(a)pyrene
30
060691
2000
98
1.02041
1.00632
2012.6
00050-32-8
0.2m^m3 (8H)
¦cu-ral 50mgfcg
6. Benzo(b)fluoranthene
31
CAP-27981-50
2000
99
1.01010
1.00372
2007.4
00205-99-2
N/A
N/A
7. Benzo(k)fluoranthene
33
30893-34
2000
99
1.01010
1.00253
2005.1
00207-08-9
N/A
ori-rat 2820mg/kg
8. Benzo(g,h,i)perylene
32
31331-40
2000
99
1.01010
1.00367
2007.3
00191-24-2
N/A
N/A
9. Chrvsene
91
RAC-29697-23
2000
99
1.01010
1.00458
2009.2
00218-01-9
0.2mg/m3
N/A
10. Dibenzo(a,h)anthracene
112
29494-83
2000
99
1.01010
1.00255
2005.1
00053-70-3
0.2mg/m3
N/A
11. Fluoranthene
183
AJO-22599-72
2000
99
1.01010
1.00419
2008.4
00206-44-0
N/A
orl-ral 2000mg/kg
12. Fluorene
184
ECH-29240-49
2000
99
1.01010
1.00471
2009.4
00086-73-7
N/A
tpr-mus 2 g/kg
13. lndeno(1,2,3-cd)pyrene
202
29494-93
2000
99
1.01010
1.00328
2006.6
00193-39-5
N/A
N/A
14. Naphthalene
222
04813DW
2000
99
1.01010
1.00202
2004.0
00091-20-3
10 ppm (50mg/m3/8H)
orl-rat 400mg/kg
15. Phenanthrene
248
03410PV
2000
98
1.02041
1.00703
2014.1
00085-01-8
0.2mg/m3/BH
orl-mus 700ntg/kg
16. Pyrene
259
123196
2000
99
1.01010
1.00292
2005.8
00129-00-0
0.2mg/m3/8H
ori-fat 2700m^kg
17.
18.
19.
20.
'Actual concentrations assume purities 98% or greater are equal to 100%.
P#10017 L#092398 Revision No.: 0, Date Issued: 070194
-------
ABSOLUTE STANDARDS,Inc. • 44 Rossotto Drive • Hamden, CT • 06514 • (800)-368-1131 ISO 9001 Quality System Registered
DLS ANSI-RAB Accredited
in
-------
AccuStandard Inc.
CERTIFICATE OF ANALYSIS
125 Market Street
New Havtn, CT 06513
USA
Ph: 203-786-5290
Fax: 203-786-5287
E-mail: usaeaccustandard.com
CATALOG NO. M-625-07-10X
DESCRIPTION: Calibration Standard
LOT: A7120073
SOLVENT: CH2CI2
EXPIRATION: On-going Stability
Program
Component
2,2'-Difluorobiphenyl
CAS * Purity %
(GC/MS)
388-82-9 100
Gravimetric
Concentration1
(jig/mL)
2002
Analyte
Concentration3
(ng/mL)
2002
1. AI weights are traceable through National Institute c!
Standards & Technology, Test No. 822/^4480
2. Anafyta Concentration * Purity * Gravtmrtric Concentration
0C0304;
CflrMadbf.,
kJT) ss
Vc. I jrfryLVL
This product was manufactured to meet the quality system requirements of ISO 9001
QH-ORG/INO-001
Rev. 9/98
-------
DFTPP
Data File
Acq On
Sample
Misc
Method
Title
C:\HPCHEM\l\DATA\ENGl653.D
14 Oct 99 7:09 pm
8270C,QA/QC,1014DFTPP,
C;\HPCHEM\l\MBTHODS\APG_PE.M
SW-846 Method 8270C
Vial: 1
Operator:
Inst : HP 5989B
Multiplr: 1.00
Abundance
400000
200000
TT€T~EwGlb53.D
0
J
—i—i—i—[—i—i—i—i—|—i—i—i—i—i—i—p—s—i—|—i—i—i—i—|—i—i—i—5—|—f—i—i—i I i—i—i—i—|—r
Time--> 9.00 9.50 lOlOO 10:50 11100 11150 12l00
Abundance
10000
5000
Average of 10.676 to 10.716 min.: ENG1653.D (-)
198
51 77 127
110
m/ z-
1—1— "T" v"f,il 1" "[' "f ' I "t "I" 'r ¦ f—I ~T "1- - 1* 'I'*n "' 1" I •**!—i—1—r*r f*T*"|—1—rTT—1—|—I—|—r*-|—
50 100 160 200 250 300 350 400
167
lj iiiWinji.— iJ^Hii * * jj* *i.>|
255
442
224
j 1 .fai.ii.iat'
275
u,—JL—_L.
323*4 365 423
Peak Apex is scan: 224
Target
Rel. to
Lower
Upper
Rel,
Raw
Result
Mass
Mass
Limit%
Limit %
Abn%
Abn
Pass/Fail
51
198
30
80
47 .5
5929
PASS
68
69
0
2
0.0
0
PASS
69
198
0
100
37 .5
4680
PASS
70
69
0
2
0.0
0
PASS
127
198
25
75
47 .9
5980
PASS
197
198
0
1
0.0
0
PASS
198
198
100
100
100.0
12474
PASS
199
198
5
9
6.6
827
PASS
275
198
10
30
24 .1
3012
PASS
365
198
1
100
1.9
239
PASS
441
443
0
100
81. 6
903
PASS
442
198
40
110
53 .7
6693
PASS
443
442
15
24
16.5
1106
PASS
ENG1653.D APG PE.M
Mon Oct 18 13:47:19 1999 HP 59891
OCCjOuD
-------
DFTPP
Data- File
Acq On
Sample
Misc
Method
Title
C:\HPCHEM\l\DATA\ENG1660.D
15 Oct 99 12:17 pm
8270C,QA/QC,1014DFTPP,
C:\HPCHEM\l\METHODS\APG_PE.M
SW-846 Method 8270C
Vial 1
Operator:
Inst : HP 5989B
Multiplr: 1,00
Abundance
400000
200000
TIC: ma 1660.£>
0
Time-->
Abundance
5000
¦ i , i i 11 1 ,
J
1—i—|—(—i—i—r-
-1 ! 1 1 1 1 ! -J ! ! 1 1 1 1 E 1 r
9.00 9.50 10.00 10.50 11.00 11.50 12.00
Average of 10.674 to 10.715 min.: ENG1660.D (-;
198
m/z-
3354 365
uu
100
150
200
> | t ' [ 1,ar i 1 j—j—ih i ' ?—| ' \ '-t' t- i—j—i—r*-
250 300 350 400
Peak Apex is scan-. 224
Target
Rel. to
Lower
Upper
Rel.
Raw
Result
Mass
Mass
Limit%
Limit%
Abn%
Abn
Pass/Fail
51
198
30
80
61.2
5052
PASS
68
69
0
2
0.0
0
PASS
69
198
0
100
60.0
4953
PASS
70
69
0
2
0.0
0
PASS
127
198
25
75
54.3
4483
PASS
197
198
0
1
0.0
0
PASS
198
198
100
100
100.0
8259
PASS
199
198
5
9
6.3
517
PASS
275
198
10
30
22 .3
1838
PASS
365
198
1
100
2.1
171
PASS
441
443
0
100
80 .8
506
PASS
442
198
40
110
44 .7
3688
PASS
443
442
15
24
17 .0
626
PASS
ENG1660.D APG_PE.M Mon Oct 18 14:01:50 1999 HP 5989B f-Jh
0CC39S1 1$
-------
DFTPP
Data File
Acq On
Sample
Misc
Method
Title
C:\HPCHEM\1\DATA\ENG1671.D
15 Oct 99 11:39 pm
827OC,QA/QC,1014DFTPP,
C:\HPCHEM\1\METHODS\8270C_1.M
SW-846 Method 8270C
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Abundance
300000
TIC7ENGT671. D
200000
100000
Time-->
SBu
20000 -
ioooo :
"1 [ "i 'i " i T i i—i—i—i—i—i—i—i—i—I—i—i—i—i—i—i—i—i—i—|—i—i—i—i—I—i—i—i—i—I—r
9.00 9.50 10100 10 ISO 11.00 11.50 12.00
Scan 225 (10.653 min) : EtfGl671.D (-)
198
51 77
127
m/z-
r 1" ¦
50
110
li|,„ 1,-11! ,1" *| 1.^ |il. »l, . ,J>y , I-. , , , 1 , . , , ,1
100 150 200 250 300 350 400
167
A
255
Jl
224
ii. 1,
275
442
33334 365
423
Peak Apex is scan: 224
Target
Rel. to
Lower
Upper
Rel.
Raw
Result
Mass
Mass
Limit%
Limit%
Abn%
Abn
Pass/Fail
51
198
30
80
67.9
19560
PASS
68
69
0
2
0 .0
0
PASS
69
198
0
100
50.3
14477
PASS
70
69
0
2
1.4
209
PASS
127
198
25
75
64.9
18677
PASS
197
198
0
1
0.0
0
PASS
198
198
100
100
100.0
28786
PASS
199
198
5
9
5.7
1653
PASS
275
198
10
30
17.0
4901
PASS
365
198
1
100
1.1
324
PASS
441
443
0
100
78 .4
674
442
198
40
110
18.3
5262
CfAIL*^
443
442
15
24
16.3
860
PASS
/
ENG1671.D 8270C_1.M Mon Nov 01 16:13:18 1999 HP 5989B ~JL
0CC30u£
-------
DFTPP
Data File
Acq On
Sample
Misc
Method
Title
C:\HPCHEM\l\DATA\ENG1685.D
19 Oct 99 2:26 pm
8270C,QA/QC,1014DFTPP,
: C;\HPCHEM\1\METHODS\APG_PE.M
: SW-846 Method 8270C
Vial: l
Operator
Inst
Multiplr
ST
HP 5989B
1.00
TIC: ENG1685.D
Abun
15
100000
50000
Time-->
Abundance
6000
4000
2000
0
r =s—r—n e > r—t—i 1 1—j—i—\—i—i—i—\ 1—i—i—j—i 1—i 1—j—i—i—7—i—i 11 \ ¦ 11{
9.00 9.50 10.00 10.50 11.00 11.50 12;00
Average of 10.S50 to 10.612 thin.: EHGlSSS.D (-)
198
51
77
127
110
167
442
255
224
J.
275
32834 365
423
m/z-
50
i'T f i'V '\ "f—i' "1 "t 'i'"t—1 " | Bii 1 1 — i1 1 ¦ 1—1—;' i • 1—I ¦ i 'T 1—1—r—1—r^r-
100 ISO 200 250 300 350 400
Peak Apex is scan: 219
Target
Mass
Rel. to
Mass
Lower
Limit%
Upper
Limit %
Rel.
Abn%
Raw
Abn
Result
Pass/Fail
ENG1685.D APG PE.M
51
198
30
80
78.6
5337
PASS
68
69
0
2
0.0
0
PASS
69
198
0
100
64.1
4349
PASS
70
69
0
2
0.0
0
PASS
127
198
25
75
53 .1
3604
PASS
197
198
0
1
0.0
0
PASS
198
198
100
100
100 .0
6789
PASS
199
198
5
9
6.5
441
PASS
275
198
10
30
24.5
1662
PASS
365
198
1
100
2.6
177
PASS
441
443
0
100
81.5
782
PASS
442
198
40
110
65.8
4465
PASS
443
442
15
24
21.5
959
PASS
Tue Oct 19 14:52:10 1999
HP 5989B
0CC7J;
-------
429SUM.XLS
Method Detection Study CARB Method 429
PNAs by QC/MS/SIM
Concentration
pg/mL
pg/mL
pg/mL
pg/mL
pg/mL
pg/mL
pg/mL
pg/mL
pg/mL
MEAN
Compounds
MDL1
MDL2
MDL3
MDL4
MOL6
MDL7
MDL8
MDL9
SD
pg/mL
T-FACTOR
MOL
%RSD
% RECOVERY
Naphthalene
1.15
1.43
1.23
1.23
1.72
1.51
0.93
1.27
0.2248
1.31
2.998
0.67
17
65
Acenaphthylene
1.25
1.51
1.18
1.20
1.98
1.68
1.09
1.48
0.2820
1.42
2.998
0.85
20
71
Acenaphthene
1.26
1.45
1.15
1.27
1.89
1.59
1.04
1.47
0.2539
1.39
2.998
0.76
18
70
Fluorene
1.32
1.48
1.25
1.27
1.95
1.75
1.16
1.46
0.2533
1.46
2.998
0.76
17
73
Phenanthrene
1.43
1.48
1.33
1.34
1.96
1.80
1.23
1.45
0.2334
1.50
2.998
0.70
16
75
Anthracene
1.72
1.78
1.49
1.56
2.39
2.08
1.39
1.71
0.3063
1.76
2.998
0.92
17
88
Fluoranthene
1.52
1.50
1.43
1.40
1.95
1.78
1.29
1.40
0.2079
1.53
2.998
0.62
14
77
Pyrene
1.50
1.47
1.42
1.39
1.92
1.74
1.26
1.37
0.2030
1.51
2.998
0.61
13
76
Benzo(a)anthracene
1.89
1.81
1.81
1.62
2.10
1.83
1.36
1.48
0.2221
1.74
2.998
0.67
13
87
Chrysene
1.91
1.66
1.75
1.48
1.94
1.73
1.24
1.33
0.2416
1.63
2.998
0.72
15
82
Benzo(b)fluoranthene
1.73
1.64
1.74
2.00
2.31
1.70
1.26
1.34
0.3142
1.71
2.998
0.94
18
86
Benzo(k)fluoranthene
2.01
1.85
1.91
2.33
2.34
1.84
1.34
1.46
0.3348
1.88
2.998
1.00
18
94
Benzo(a)pyrene
1.86
1.67
1.78
2.02
2.43
1.75
1.23
1.37
0.3486
1.76
2.998
1.04
20
88
lndeno(1,2,3-cd)pyrene
1.88
1.58
1.66
1.81
2.16
1.97
1.37
1.46
0.2497
1.74
2.998
0.75
14
87
Dibenz(a,h)anthracene
1.94
1.64
1.72
1.87
2 21
2.06
1.45
1.46
0.2567
1.79
2.998
0.77
14
90
Benzo(g,h,i)perylene
1.75
1.50
1.62
1.69
2.00
1.86
1.32
1.41
0.2140
1.64
2.998
0.64
13
82
O
O
O
o
J
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1662.D
15 Oct 99 1:47 pm
CARB429,MDL1
Oct 18 14:51 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HFCHEM\1\METH0DS\PES3 .M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1}
2,2-Difluorobiphenyl
19 .99
190
689030
5.00
ng/uL
0.00
lystem Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00
ng/uL
0.00%
4)
2-Methlynaphthalene-dl0
19.36
152
328600
2 .43
ng/uL
60.72%
5)
Acenaphthylene-d8
0.00
160
0
0.00
ng/uL
0.00%
7)
Acenaphthene-dl0
0.00
164
0
0.00
ng/uL
0.00%
9)
Fluorene-dlO
0.00
176
0
0.00
ng/uL
0.00%
11)
Phenanthrene-dl0
0.00
188
0
0.00
ng/uL
0.00%
13)
Anthracene-dlO
0.00
188
0
0.00
ng/uL
0.00%
15)
Fluoranthene-dlO
0 .00
212
0
0 .00
ng/uL
0.00%
17)
Pyrene-dlO
0 .00
212
0
0.00
ng/uL
0.00%
19)
p-Terpheny1-dl4
29 .62
244
364974
2 .72
ng/uL
67.96%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00
ng/uL
0.00%
22)
Chrysene-dl2
0.00
240
0
0.00
ng/uL
0.00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
0
0.00
ng/uL
0.00%
26)
lenzo(k)fluoranthene-dl2
0.00
264
0
0.00
ng/uL
0.00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00
ng/uL
0 .00%
30)
Indeno(1,2,3-cd)pyrene-dl2
0 .00
288
0
0.00
ng/uL
0.00%
32)
Dibenz(a,h)anthracene-dl4
0.00
292
0
0.00
ng/uL
0.00%
34)
Benzo(g,h,i)perylene-dl2
0 .00
288
0
0.00
ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17 .73
128
509961
1.15
ng/uL
99
6)
Acenaphthylene
21.66
152
187688
1.25
ng/uL
100
8)
Acenaphthene(CCC)
22.11
154
164650
1.26
ng / uL
97
10)
Pluorene
23 .38
166
179615
1.32
ng/uL
98
12)
Phenanthrene
25.73
178
295951
1.43
ng/uL
98
14)
Anthracene
25.86
178
217959
1.72
ng/uL
98
16)
Fluoranthene(CCC)
28.72
202
303338
1.52
ng/uL
96
18)
Pyrene
29 .33
202
333614
1.50
ng/uL
96
21)
Benzo(a)anthracene
33 .45
228
194422
1.89
ng/uL
100
23)
Chrysene(CCC)
33 .60
228
283696
1.91
ng/uL
93
25)
Benzo(b)fluoranthene
39.51
252
181234
1.73
ng/uL
100
27)
Benzo(k)fluoranthene
39.65
252
155676
2.01
ng/uL
97
29)
Benzo(a)pyrene(CCC)
41.77
252
94438
1.86
ng/uL
96
31)
Indeno(1,2,3-cd)pyrene
52.80
276
96645
1.88
ng/uL
74
33)
Dibenz(a,h)anthracene
52.83
278
85581
1.94
ng/uL
66
35)
Benzo(g, h, i)perylene
55 .83
276
98017
1.75
ng/uL#
62
(#) = qualifier out of range (m) » manual integration
ENG1662.D PES3.M Mon Oct 18 14:52:14 1999 HP 5989
t)CG30:!t?
e 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1662,D
15 Oct 99 1:47 pm
CARB429,MDL1
Method
Title
Last Update
Response via
Oct 18 14:51 1999
: C:\HFCHEM\1\METHQDS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Abundance
450000
400000
350000
300000
250000
200000
150000 .
100000
50000
TIC: ENG1662.D
0
45
19S
10
1$
12 16
23
21
29
32
35
iA
Time-->
1 1—
20
i—i—i—,—|—|—|—j—:—i—j—j—i—ft—j—i—i—r—i—]—r—r—i—i—t—i—i—i—\—[—i—i—i—r—j—\—
100 25.00 30.00 35.00 40.00 45.00 50.00 55.00
ENG1662.D PES3.M
Mon Oct 18 14:52:21 1999
HP 5989B Page 2
0CC-395S
-------
TIC: ENG1662.D
Abundance
200000
100000
Time-->16.50 17:00 17.50 18.00 18150
abundance Ion. 13g.0Q (135.70 to 136.70) : SNG
Ion 68.00 (67.70 to 68.70): ENG16
4000
2000
#2
Naphthalene-d8
Concern 0.00 ng/uL
Expected RT: 17.69 min
Lab File: ING1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 136
Exp Ratio
100
15.3
0.0
0.0
—i—t—t—i—i—i—i—rn—i—i—i—f—i—j—i—i—i—r—i—i—i—j—r
Time-->16150 17100 17.50 18.00 18150
TIC: ENG1662.D
200000
Time - - >
100000
17160
17 .80
200000
100000
Time-->
ENG1&62.D—PES3M
#3
Naphthalene(CCC)
Concen: 1.15 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.01 min
Lab File: ENG1662,D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 128 Resp*. 509961
Ion Ratio Lower Upper
128
100
127
12 .7
0.0
63.0
0
0.0
0.0
0.0
0
0,0
0.0
0.0
Abundance Ion 128.00 (127.70 to 128.70): ENG
lion 127.00 (126.70 to 127.70): ENG
17.73
17160 17.80
Mon Oct 18 14:52:24 1999'
HP 5
- Page 3
;7
-------
|Aburi3ance
150000
100000
50000
TIC: IMG1662.D
A
19.40
Time--> 19130
Abundance Ion 152,00 (151.70 to 152.70)
200000
150000
100000
50000
19.36
Time-
19.30
19 .40
Abundance
150000 -
100000
50000
T 1 1 1 I 1 T"
22100 22.50
2000
1000
0
—j—,—j—i—j—,—,—?—i—i— i t"""i—!—|—i—i—i—i—|—i—r
Time--> 20150 21.00 21.50 22.00 22.50
ENGlbfeZ.D FES3.M
#4
2-Methlynaphthalene-dlO
Coneen: 2.43 ng/uL
RT: 19.36 rain Scan# 759
Delta R.T. -0.01 min
Lab File: SNG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:152 Resp: 328600
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: 2NG1662.D
Time--> 20150 21.00 21.50
AbundanceIon 160.00 (159.70 to 160.70) : ENG
#5
Acenaphthy1ene-d8
Concen: 0.00 ng/uL
Expected RT: 21.63 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 160
Exp Ratio
100
0.0
0.0
0.0
Mon Oct 18 14:52:27 199?
HP 5989B Page 4
00C3053
-------
Abundance
100000
Time-->
TIC: BNG16627TT
50000
0
1 i ] 5 J 1 1 \ i
21.50 21.60
21.70
—"—1 | i i i (
21.80
Abundance Ion 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
100000 21.66
50000
Time-
-! 1 t 1 1 r
21.50 21.60 21.70 21180
#6
Acenaphthylene
Concen: 1.25 ng/uL
ET: 21.66 min Scan# 1302
Delta R.T. -0.01 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:152
Ion Ratio
152 100
153 13 . 0
0 0.0
0 0.0
Resp: 187688
Lower Upper
6.6 19.6
0.0 0 .0
0.0 0.0
Abundance
150000
100000
Time-->
¦a i_ m ' ' ' m ' j j i Ji/i / J m at "Pt'Jl" ^ n'V \
Abundance Ion 164.00 (163.70 to 164.70)
50000
TIC: ENG1662.D
1——i—i—f—i—r—i—i—i—i—|—i—«—i—!—|—i—i—m-
21.00 21.50 22.00 22.50 23:00
2000
1000
Time-
21.00 21.50 22.00 22.50 23.00
#7
Acenapht Jiene - dl 0
Concen: 0.00 ng/uL
Expected RT: 22.04 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:
Ion
164
Exp Ratio
100
0.0
0.0
0.0
0003059
ENG1662 .D—PES3 .M
Mon Oct 18 14:52:30 1999
HP 5989B
Page 5
-------
Abundance
150000
100000
50000
Time-
TTC7ENGT&627D
22 .00
22 .10
1—1 r*
22.20
Abundancelon 154.00
Ion 153.00
80000
60000
40000
20000
{153.70 to 154.70):
(152.70 to 153.70) :
22 .11
Time-->
22.00 22.10
22 120
#8
Acenaphthene(CCC)
Concen: 1.26 ng/uL
RT; 22.11 min Scan# 1370
Delta E.T. -0.01 min
Lab Pile: ENG1662.D
Acq: 15 Oct 99 1:47 pxtl
Tgt Ion:154 Resp: 164650
Ion Ratio Lower Upper
154
100
153
95 .4
49.1
147.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
Time-
TlC: ENG1662.D
22.50 23100
23 .50 24.00
1000
0
Time-
~1 f [ 1 7 ? 1 1 ! ! 1 T T~T 1 1 1 1 1 1
22 50 2300 23 50 24 00
£* . mJ W <£•»¦?• W W lb • +J v (B ¦ y U
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 176
Exp Ratio
100
0.0
0.0
0.0
Abundance Ion 17 6.00 (175.70 to 176.70): 3NG
2000
ENG1662.D—FES3.M
0CC39c9
Mori Oct 18 14:52:33 xyyy
HP 5989B
Page 6
-------
Abundance
150000
100000 :
50000
Time-
TlCTENGTbbTTD
n—i—!—|—i—i—i—i—till
23!20 23.30 23,40 23:50
Abundance Ion 166.00 (155.70 to 166.70): ENS
100000
]Ion 165.00 (164.70 to 165.70)
23 .38
50000
—1—tt—1—r—?—\—1—*—1—i—r—1—1—j—1—\—v't —r-
lrime--> 23.20 23.30 23.40 23.50
1000
t—1—1 ""i |—1—r
Time-->24:50 25.00
ENGit>62.D—PEsrnr
25.50
¦ ' I 1 1 1 T 1 1
26100 26.50
#10
Fluorerie
Concert; 1.32 ng/uL
RT; 23.38 min Scan# 1561
Delta R.T. -0.00 min
Lab File: SNG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:166 Resp: 179615
Ion
166
165
0
0
Ratio
100
89.2
0.0
0.0
Lower Upper
45.7
0.0
0.0
137 .0
0.0
0.0
TIC: ENG1662.D
150000
100000
50000
T I I r~-l 1 1 1 ? 1 1 1 ! 1 E 1 1 1 f 1 ! !—r
Time--> 24:50 25l00 25.50 26.00 26150
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
3000
2000
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1662.D
Acq-. 15 Oct 99 1:47 pm
Tgt Ion: 188
Ion Ixp Ratio
100
24.5
0.0
0.0
OCODOcl
Mon Oct 18 14:52:38 1999
HP 5989B
Page 7
-------
Abundance
150000
100000
50000
Time-->25.60
TTC: ENG1662.D
25.70
25180
¦ ——— ¦ we' m*' 1 mil i [¦ ¦¦ ¦ mttmmmm—1
Abundance Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 {175.70 to 176,70); ENG
25.73
150000
100000
50000
Time-->25.60
25 .70
25.80
#12
Phenanthrene
Concen: 1.43 ng/uL
ET: 25.73 min Scan# 1919
Delta R.T. -0.01 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion;178 Resp: 295951
Ion Ratio Lower Upper
178
100
176
19 .5
10.2
30.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000 .
100000
TIC: SNG1SS2.D
50000
0
u
L
Time-
n—i—i—i—i—i—«—i—i—i—s—i—j—|—i—i—i—j—\—i—i—i—r
25!00 25.50 26.00 26.50
Abundance Ion 188.00 (187.70 to 188.70): ENG
JIon 94.00 {93.70 to 94.70): ENG16
3000
2000
1000
0
Time-->
-1—r r 1 i
25.00 25.50 26.00 26.50
ENG1662.D—PES3.M
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 26.6
0 0.0
0 0.0
3
>—j r-*.
z'Z
Mon Oct 18 14:52:42 1999
HP 5989B
Page 8
-------
TIC; ENG1662.D
150000
100000
50000
150000
100000
50000
Time-->25 1 70
25.86
#14
Anthracene
Concen: 1.72 ng/uL
RT: 25.86 min Scan# 1939
Delta R.T. -0.01 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:178 Resp: 217959
Ion Ratio Lower Upper
Time-->25.70 25.80 25.90 26.00
Abundance Ion 178.00 (177.70 to 178.70): IMG
Ion 176.00 (175.70 to 176.70): ENG
178
100
176
18.8
10.0
29.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
25^80
25.90
26100
Abundance
200000
100000
TIC: ENG16S2
Time--> 27.50 28100 28150 29100 29 150
Abundance Ion 212.00 {211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
20000 -
10000
I
Time
ENG1662 . D PES3 . M
i—I—I—l—f—|—i—l—r
> 27.50 28.00 28150
29 15cT
29100
Mon Oct 18 14:52:45 1999'
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 27.3
0 0.0
0 0.0
OC03933
HP 5989B
Page 9
-------
TTC: EMG1SS2.d
150000 .
100000
50000
Time--> 28.50 28.60 28.70 28.80 28.90
AbundanceIon 202.00 (201.70 to 202.70); SMG
jlon 101.00 (100.70 to 101.70); ENG
150000 -i 28.72
100000
50000
T 1 1 ! 1 1 ] 1 ! 1 1 1 ! 1 1 1 j 1 1 ! ! 1 1 T
Time-- > 28.50 28 1 60 28.70 28.80 28.90
#16
Fluoranthene(CCC)
Coneen: 1.52 ng/uL
RT: 28.72 min Scan# 2377
Delta R.T. -0.01 min
Lab Pile: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:202
Ion Ratio
202 100
101 25.9
0 0.0
0 0.0
Resp: 303338
Lower Upper
12,1 36.1
0.0 0.0
0.0 0.0
TIC: ENG1662.D
200000
100000
I > I f | I | i I |—'—i—i—i——i—i—i—i——i—i—i—r
28 50 29.00 29.50 30.00
Time
Abundance Ion 212.00 (211.70 to 212.70)
Ion 106.00 (105.70 to 106.70)
20000
10000
1 ! ! 1 1 1 r—1 1 1 1 ! 1 1 1 ! 1—! 1 1 1 !
28150 29.00 29.50 30.00
Time
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab Pile: SNG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 212
Exp Ratio
100
31.6
0.0
0.0
0C030I
ENG1662.D—PES3 .M
Mon Oct 18 14:52:48 1999
HP 5989B
Page 10
-------
Abundance
200000
100000
TIC: ENG1662.D
Time--> 29.20 29.40
Abundance Ion 202.00 (201.70 to 202.70): 1NG
Ion 101.00 (100.70 to 101.70): ENG
29 33
150000
100000
50000
0
Time-
29.20
29.40
Abundance
200000
100000
TIC: BNG1662.E)
Time-->
i 1 r
29.40
r 1 1 r 1 1 "i"'
29:60
Abundance Ion 244
Ion 122
150000 .
100000
00
00
29 . 80
(243.70 to 244.70}:
(121.70 to 122 .70) :
29.62
1U
ENG
#18
Pyrene
Concen: 1.50 ng/uL
RT: 29.33 Ttlin Scan# 2468
Delta R.T. -0 .00 rain
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:202 Resp: 333614
Ion Ratio Lower Upper
202 100
101 29.6 13.9 41.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
50000
0
Time--»
ENG1662.D
#19
p-Terphenyl-dl4
Concen: 2.72 ng/uL
RT: 29.62 min Scan# 2511
Delta R.T. -0.00 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:244 Resp: 364974
Ion Ratio Lower Upper
244
100
122
32.9
14.6
43 .7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC39S5
29.40 29.60 29.80
"PE53TH Mon Oct 18 14 :52 : 51 1999'
HP 5989B
Page 11
-------
Abundance
100000 -
Time-->
50000
q . £^(ji6o2 0
T f
32 ; 50
33 .00
' ' i
33 .50
n—I—i—i—i—r
34.00
Jir1 111 lp"™' *. A K A A ) n w JK m A " t ¦¦ ji i'A p» A V ijwwf J4
Abundance Ion 240.00 (239.70 to 240.70) : ENG
Ion 120.00 (119.70 to 120.70): ENG
6000 J
4000
2000
rime-->
-i—r—i—j—i—i—i—i—|—i—i—!—i—|—i—r—!—i——j—i—r——i—r~
32.50 33.00 33.50 34.00
#20
Benzo(a)anthracene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.36 min
Lab Pile: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.9
0 0.0
0 0.0
Tier ENG1&62TD
100000
50000 .
-j ! r-
33 140
T E ! 1 1 1 r-
33.50 33160
Time--> 33.30
— k—*-* / vs m m—*T7\—ZTZZ—* * A—py«\ \
Abundance Ion 228.00 (227.70 to 228.70)
00000HIon 114_ oo (113.70 to 114.70)
50000
Time - - >
—!—,—
33 .30
-i r
33 140
1—i—I—i—i—i—i—|—i—
33150 33.60
#21
Benzo(a)anthracene
Concen: 1.89 ng/uL
RT: 33.45 rain Scan# 3087
Delta R.T. -0.01 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:228 Resp: 194422
Ion Ratio Lower Upper
228 100
114 25.4 12.8 38.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
"EH
ENG
0CC3Q5S
ENG1662.D—PES3 .M
Mon OCt 18 14:52:54 1999
HP 5989B
Page 12
-------
Abundance
100000
50000
TIC: EUG1662.D
Time--> 32T501 '"iYTcJQ1 r33T501 TSToO^ '"m! 50
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33 . 50 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 240
Exp Ratio
100
27.3
0.0
0.0
Abundance Ion 240.00 (239.70 to 240.70): ENG
* f —s a A / <« 1 ft m a 4. 1 « » a i riitrt
Ion 120.00 (119.70 to 120.70): ENG
6000 *
4000
2000
0
Time--> 32.50
_r_r_T_1_T
33 . 00
"1 J J 1 1 ? 1 I J 1 1 1 1 1 1
33.50 34.00 34.50
Abundance
100000
TIC: ENG1662. D
50000
0
Time-->
Abu
i \ i1" \ \ ? 1 1 \ 1 r
33:40 33160
#23
Chrysene(CCC)
Concen: 1.91 ng/uL
RT: 33.60 min Scan# 3109
Delta R.T. -0.01 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:228 Resp: 283696
Ion Ratio Lower Upper
elon 228 .00
Ion 114.00
50000
0
33 180
—————————
(227.70 to 228.70):ENG
(113.70 to 114.70): ENG
33.60
228
100
114
25 .7
11.2
33.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
S>"»
Time-->
ENG1662.D
33 .40
FEB3 .M
33.60 33.80
Mon Oct 18 14:52:58 1999'
HP 5989B
Page 13
-------
TIC: ENG1662.D
40000
20000
Time--> 38150 39100 39^50 40!00
SrC 3 f'JL.^ * /* A TTTK W7S E7ZZ *¦>/"! W A \ fl-kf/H
Abundance loll 264.00 (263.70 to 264.70) : ENG
Ion 132.00 (131.70 to 132.70): ENG
6000
4000
2000
Time-
-i—i—i—|—i—i—f—?—|—j—r—i—i" r " f ' i—5—i—i—i—e—i—r-
38 150 39.00 39.50 40100
40000
30000
20000
10000
0
Ion 126.00 (125.70 to 126.70): ENG
39.51
Time--> 39.40 39.50 39.60
ENG1662 .D FE5T7TC
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 69.4
0 0.0
0 0.0
TIC: ENG1662.D
40000
20000
~r—i—i—|—r—i—i—i ] 1—i 1—f—|—i—j—i—i—r
Time--> 39.40 39.50 39.60
AbundanceIon 252.00 (251.70 CO 252.70): ENG
#25
Benzo(b)fluoranthene
Concen: 1.73 ng/uL
RT: 39.51 min Scan# 4017
Delta R.T. -0.01 min
Lab Pile: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:252 Resp: 181234
Ion Ratio Lower Upper
252
100
126
27.7
14.0
41.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Mon QCt 18 14:53:01 1999
HP 5989B
Page 14
-------
40000
20000
0
TIC;
ENG1662. D
a
i I [ I i i I | i l
40.00 40.50
Time--> 38.50 39.00 39.50
Abundance Ion 264.00 (263.70 to 264.70) : ENG
;ion 132.00 (131.70 to 132.70); ENG
6000 -
4000
2000
fTime- - > 38 ! 50' 39 100 "39 ! 50" Yolo'o" 40 J 50'
#26
Senzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.53 rain
Lab File: ENG1662.D
Acq: 15 Oct 99 1;47 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 35.8
0 0.0
0 0.0
TIC:
ENG1662
.D
40000 -
20000 .
0 .
,
Time-->
t t I t i t I I 1 1 !
39.40 39.60
39.80
Abundance ion 252.00 (251.70 to
252.70) =
IMG"
Ion 126.00 (125.70 to
126.70) :
ENG
40000
39 .65
30000
20000
10000
0
Time-->
39.40 39.60
' l ' '
39.80
#27
Benzo(k)fluoranthene
Concen: 2.01 ng/uL
RT: 39.65 min Scan# 4039
Delta R.T. -0.01 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:252 Reap: 155676
Ion Ratio Lower Upper
252
100
126
29.0
13 .9
41.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG1 b b 2 .D—PESTTM
0C039S3
Hon"Oct 18 14:53:04 1999
HP 5989B
Page 15
-------
Abundance
30000
20000
10000
0
TIC: MG1662.D
1—[—I—I—r
41100
t i r
41,50
t—i—i—i—|—i—r
42100 42.50
Time--> 40.50
Abundance Ion 264.00 (263.70 to 2S4.70
lion 132.00
]g{J£r"
(131.70 to 132.70): ENG
6000
4000
2000
T 1 f 1 I I | I I I 1 1 ! 5 ! 1 ! ! 1 ! ! 1 1 1 T
Time - - > 40.50 41. 00 41.50 42 . 00 42 .50
yDundance
30000
20000
10000
0
TIC: ENG1662.D
-1 1 1— } r r"
41.60
-1 1 1 1 1 1 1 1 1 r~
41.80 42.00
Time - - >
«¦ l_-_ T WW"* TTJS. / B 4 TTS ZT7Z Pf7\-T
Abundance Ion 252.uu (251.70 to 252.70}
20000 :
15000
10000:
5000 :
0
Ion 126.00
:i25.70 to 126.70;
41.77
Time-
T 1 ! 1 1 ! \
41.60
'i—1 ! 1 r—-1 1 1 1 r
41180 42.00
#28
Benzo(a)pyrene-dl2
Concen; 0.00 ng/uL
Expected RT: 41.61 min
Lab File; ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 37.8
0 0.0
0 0.0
#29
Benz o(a}pyrene(CCC)
Concen: 1.86 ng/uL
RT: 41.77 min Scan# 4364
Delta R.T. -0.02 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:252 Resp: 94438
Ion Ratio Lower Upper
252
100
126
29 .0
15 .7
46.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
liur
ENG
0003070
ENG1662.D PES3.M
Mon OCt 18 14:53:07 1999
HP 5989B
Page 16
-------
Abundance
30000
20000
10000
TIC: 2NGlfa62.D
-i 1 1 1 ! j r
52,00
-1 1 1-
53 .00
r~54;oo
Time-->
Abundance Ion 288.00 (287.70 to 288.70): ENG
2000 -
1000
Time-->
~1 J 1 1 1 r*T 1 >'"• * '1 '-r [ ! 1 r
52.00 53 .00 54.00
#30
Indeno(l, 2, 3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 52.54 min
Lab File: ING1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Abundance
TIC: EMG1662.D
30000 -
20000 :
10000 -
0 .
Time - ->
52.40 52.60 52.80 53.00 53.20
Abundancelon 276.05 (275.75 to 276 . 75) : ENG
Ion 138.00 (137.70 to 138.70): ENG
52 .80
10000 .
A
5000 _
0 -
Time-->
52.40 52.60 52.80 53.00 53.20
#*JT
TT "it "*•
Indeno(1,2,3-cd)pyrene
Concern 1.88 ng/uL
RT: 52.80 min Scan# 6074
Delta R.T. -0.02 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:276.05 Resp: 96645
Ion Ratio Lower upper
276
100
138
40.2
30 .1
90.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG1662.D—PES3.M
Mon UCt 18 14:53:11 1999
HP 5989B
Page 17
-------
Abundance
30000
20000
TIC: ENG1662.D
10000
Tirae - ->
Abundance Ion 292.00 (291.70 to 292.70): ENG
2000
1000
0
Time-
52;00
53 .00
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 52,50 min
Lab File: ING1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 292
Ion Exp Ratio
292 100
0 0.0
0 0.0
0 0.0
Abundance
TIC: ENG1662.D
30000 :
A
20000:
J V
10000:
0 '
Time--> 52.40 52,60 52.80 53.00 53.20
Abundance Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): 1NG
52.83
10000 -
A
5000 J
0 -
Time-->52.40 52.60 52.80 53.00 53.20
#33
Dibenz(a,h)anthracene
Concen: 1.94 ng/uL
RT: 52.83 min Scan# 6080
Delta R.T. -0.04 min
Lab File: 1NG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion:278 Resp: 85581
Ion Ratio Lower Upper
278 100
139 29.3 26.9 80.5
0 0.0 0.0 0.0
0 0,0 0.0 0.0
0CC3972
HP 5989B
Page 18
-------
Abundance
15000
TIC: SNG16S2.D
10000
5000
0
Time--> 55!00 56.00
Abundance Ion 258.00 (257.70 to 288.70): ENG
2000
1000
0
Time-->
—,—|—
55.00
56.00
5000
"1 1 r
55.40
-1—I—1—r
55 .60
i—I—1—1—1—1—I—1—r
55.80 56.00
Time - ->
Abundance Ion 276.00 (275.70 to 276.70}
Ion 138.00 (137.70 to 138.70)
55.83
10000 .
5000
T 1—!—!—r
56.20
1—I—1—i—1—i—J—I—!—I—!—J—I—I—I—!—]—I—I I 1—|—?—I—r~
Time--> 55.40 55.60 55.80 56.00 56.20
ENG1662.D—PES3.M
#34
Benzo(g,h,i)perylene-dl2
Concen: 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1:47 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
TIC: ENGlb€2.D
15000
10000
#35
Benzo(g,hfi)perylene
Concen: 1.75 ng/uL
RT: 55.83 min Scan# 6669
Delta R.T. -0.01 min
Lab File: ENG1662.D
Acq: 15 Oct 99 1 :47 pttl
Tgt Ion:276 Resp: 98017
Ion Ratio Lower Upper
276
100
138
0.0
6.5
2 6 . 0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
2NG
0C03073
Mon Oct 18 14:53:17 1999
HP 5989B
Pacjp 19
<¦» V> mtm mf
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DATA\ENGl663.D
15 Oct 99 2:54 pm
CARB429,MDL2
Oct 18 14:59 1999
Vial: 4
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES 3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Internal Standards
1) 2, 2-Difluorobiphenyl
System Monitoring Compounds
R.T. Qlon
20.00 190
Response Cone Units Dev(Min)
685634 5.00 ng/uL 0.00
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00 ng/uL
0.00%
4}
2-Methlynaphthalene-dlO
19.36
152
345606
2.57 ng/uL
64.17%
5)
Acenaphthylene-d8
21.49
160
18664
0.16 ng/uL
3 .92%
7)
Acenaphthene-dl0
22.04
164
9716
0.08 ng/uL
2.08%
9)
Fluorene-dlO
0.00
176
0
0.00 ng/uL
0.00%
11)
Phenanthrene-dl0
0.00
188
0
0.00 ng/uL
0.00%
13)
Anthracene-dlO
0.00
188
0
0.00 ng/uL
0.00%
15)
Fluoranthene-dl0
0.00
212
0
0.00 ng/uL
0.00%
17)
Pyrene-dlO
0.00
212
0
0.00 ng/uL
0 .00%
19)
p-Terphenyl-dl4
29.62
244
348868
2.61 ng/uL
65.28%
20)
Benzo(a)anthracene-dl2
0 .00
240
0
0.00 ng/uL
0.00%
22)
Chrysene-dl2
0.00
240
0
0.00 ng/uL
0.00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0 .00%
26)
Benzo(k)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0,00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00 ng/uL
0.00%
30)
Indeno(1,2,3-cd)pyrene-dl2
0.00
288
0
0.00 ng/uL
0.00%
32)
Dibenz(a,h)anthracene-dl4
0.00
292
0
0.00 ng/uL
0 .00%
34)
Benzo(g,h,i)perylene-dl2
0.00
288
0
0.00 ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.74
128
630969
1.43 ng/uL
99
6)
Acenaphthylene
21.66
152
225948
1.51 ng/uL
100
8)
Acenaphthene(CCC)
22 .11
154
189332
1.45 ng/uL
98
10)
Fluorene
23.38
166
201097
1.48 ng/uL
97
12)
Phenanthrene
25.74
178
304747
1.48 ng/uL
99
14)
Anthracene
25 .86
178
224322
1.78 ng/uL
98
16)
Fluoranthene{CCC)
28 .72
202
297782
1.50 ng/uL
96
18)
Pyrene
29.33
202
325377
1.47 ng/uL
96
21)
Benzo(a)anthracene
33 .45
228
185810
1.81 ng/uL
100
23)
Chrysene(CCC)
33 .60
228
244561
1.66 ng/uL
97
25)
Benzo(b)fluoranthene
39.50
252
170709
1.64 ng/uL
99
27)
Benzo(k)fluoranthene
39.65
252
142803
1.85 ng/uL
96
29)
Benzo(a)pyrene(CCC)
41.78
252
84616
1.67 ng/uL
97
31)
Indeno(1,2,3-cd)pyrene
52.79
276
80642
1.58 ng/uL#
49
33)
Dibenz(a,h)anthracene
52 .83
278
72296
1.64 ng/uL
69
35)
Benzo(g,h#i)perylene
55.82
276
83636
1.50 ng/uL#
51
(#} - qualifier out of range (m) = manual integration
ENG1663.D PES3.M Mon Oct 18 14:59:57 1999 HP 5989B
I **
Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1663.D
15 Oct 99 2:54 pm
CARB429,MDL2
Oct 18 14:59 1999
Vial
Operator
Inst
Multiplr
4
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3,M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Abundance
500000
450000
400000
350000
300000
250000
200000
150000 -
100000
TIC: EHG1663.D
50000
0
Time-
4s
tJ
5'5 3
19S
10 1 • ;
8 12
16
is
23
21
-Jl
29
31
±
35
-T—I—I—| r—(—I—I—[—!—!—»—I—I—I—\—I—T—j—r—I—!—i—I—I—i—r—r—\—i—i—i—i—!—i—i—i—i—i—r—
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0CC3075
ENG1663.D PES3.M
Mon Oct 18 15:00:05 1999
HP 5989B
Page 2
-------
Abundance
300000
200000
100000
® —i—i—i—i—|—r
fTime- -> 16 ,50 17 . 00
TTCl ENG1663 JJ
17:50 18.00
I I i '"1 T "T"
18.50
Abundance Ion 136.00 (135.70 to 136.70} : ENG
Ion 68.00 (67.70 to 68.70); ENG16
4000
2000-
frime--> 16 ! 50' 17 I 00 17 ! 5o' 18 1 00' 18 ! 50
Abundance
300000.
200000
100000
TIC: ENG1SS3.D
Time-->
17.60
17 .80
(AbundanceIon 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70); ENG
17.74
300000 J
200000 :
100000
Time-->
17! 60
17.80
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT; 17,69 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion;
Ion
136
68
0
0
136
Exp Ratio
100
15.3
0.0
0.0
#3
Naphthalene(CCC)
Concen: 1.43 ng/uL
RT: 17.74 min Scan# 259
Delta R.T. -0.00 min
Lab File: SNG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:128 Resp: 630969
Ion
128
127
0
0
Ratio
100
12.8
0.0
0.0
Lower Upper
0.0
0.0
0.0
63.0
0.0
0.0
ENG1663.D PES3.M
0CC397S
Mori' Oct 18 15 : 00 ; US) 1999
HP 5989B
Page 3
-------
Abundance
150000
100000
50000
Time-->19.20
TICTWSlMTTB
19.30
i 1 ! s 1 1 1 r
19.40 19.50
r35
a fori IS2 66—fl'Sl 70 to 152 70) • ENG
w Wi 1 JL-J 19 ;20 19.30 19.40 19.50
$4
2-Methlynaphthalene-dl0
Concen; 2.57 ng/uL
RT: 19.36 min Scan# 759
Delta R.T. -0.01 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:152 Resp: 345606
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0,0
TIC: ENGlbfoJ .!>
80000
60000
40000
20000
Time-->
i t [ 1 r
21.40
i ! r~ r*
21.50
*r*~—i 1 r~
21. 60
Abundance Ion 160.00 (159 .70 to 160.70): ENG
2000
1000
0
21.49
Time--> 21.40
ENGlSSirD FES3 I'M
21.50 21.60
Mon Oct 18 15:00:12 1999'
#5
Acenaphthylene-d8
Concen: 0.16 ng/uL
RT: 21.49 min Scan# 1277
Delta R.T. -0.14 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion;160 Resp: 18664
Ion Ratio Lower Upper
160
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC JOT-7
HP 5989B
Page 4
-------
Abundance
TIC: 1NG1663.D
100000 -
50000 -
I
1
0 .
Time-->
I i ; j ! i i i i i
21. 50 21.60
21.70 21.80
AbundanceIon 152.00 (151
.70 to 152.70): ENG
Ion 153.00 (152
.70 to 153.70): ENG
21.66
100000
50000
n
U -
Time-->
21.50 21.60
21.70 21.80
#6
Acenaphthylene
Concen: 1.51 ng/uL
RT: 21,66 min Scan# 1302
Delta R.T. -0.00 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:152 Resp: 225948
Ion Ratio Lower Upper
152
100
153
13 .0
6.6
19.6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
TIC: ENG1S53.D
50000
0
Time--> 22.00 22,05
Abundance Ion 164.00 (163.70 to 164.70)
22.10
W
2000
1000
22.04
Time-
ENG1&63 .D—PESTTW"
22 .00
22.05
22 .10
#7
Acenaphthene-dl0
Concen: 0.08 ng/uL
RT: 22.04 min Scan# 1359
Delta R.T. -0.00 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:164 Resp: 9716
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0CC3078
"Flon Oct 18 15:00:15 1999
HP 5989B
Page 5
-------
TIC; ENG1663.D
150000
100000
Time-
50000
—j—,—r
22.00
22.10
-i—j—i—r
22.20
Abundance Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
lOOOOOj 22.11
50000
Time-->
22.00
22 .10
22 .20
#8
Acenaphthene(CCC)
Concert; 1.45 ng/uL
RT: 22.11 min Scan# 1370
Delta R.T. -0.01 min
Lab File; ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:154 Resp: 189332
Ion Ratio Lower Upper
154
100
3. ^3
96 .3
49 .1
147 .1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
?rT7Tl—PWH —Ys
X X Li * iZilNlv? IDDJ • i-»
150000
100000
50000
i—i—i—I—i—i—|—i—i—i—i—i—i—i—i—i—|—I—!—r
22.50 23.00 23.50 24.00
Time-->
BP ¦ » I 1 ¦ II ————<¦ 11 11 —I—
Abundance Ion 176.00 {175.70 to 176.70): ENG
2000
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File; ENG1663.D
Acq; 15 Oct 99 2:54 pm
Tgt Ion: 176
Ion Exp Ratio
176 100
0 0.0
0 0.0
0 0.0
1000
0
0CG3979
n—i—i—i—|—i—i—i—i—j—i—!—i—i—|—? i1 -"i—i—|—r—i—i—r
Time --> 22.50 23.00 23.50 24.00
ENG1563.D PES3 .M
Mon Oct IB 15:00:19 1999
HP 5989B
Page 6
-------
S5
TIC: ENG1663.D
150000
100000
50000
0
iTTT j _ i /¦ /" A A /i /g—pjt*—jj—-—H /*"/"—If K \
AbundanceIon 16 6.00 (165.70 to 166.70):
Ion 165.00 (164.70 to 165.70)
23 .38
US"
BUG
100000
50000
0
Time-->
-f ! 1 r
23 .20
"1 k 1 I 1 " f 1
23 .40
23 .60
#10
Fluorene
Concen: 1.48 ng/uL
RT; 23.38 min Scan# 1561
Delta R.T. -0.01 min
Lab File; ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:166 Resp: 201097
Ion Ratio Lower Upper
166
100
165
88.9
45.7
137.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000:
TIC: SNG1663.D
0
U
L
Time--> 24.50 25.00
< ' I ' 1
25.50
26.00 26.50
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
3000 '
2000
1000
0
#11
Phenant hrene-d10
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 24.5
0 0.0
0 0.0
0CC393Q
tilt
"7 "I"—ft
Time--> 24.50 25.00 25.50 26.00 26.50
ENG1663.D—PES3.M
Mon Oct IB 15:00:22 1999
HP 5989B
Page 7
-------
Abundance
150000
100000
50000
Time--> 25I?0
TIC: ENG1663.D
25170
1 1 | 1 r
25.80
!¦! urn «——I—————I—MI—mmmmmmmmmmmmmmmmmmmmmmmm mi i i u ¦ yy ———————
Abundance Ion 178.00 (177.70 to 178.70); SNG
150000
100000
50000
Ion 176.00 {175.70 to 176.70); ENG
25.74
{Time-
¦> 25.60
25.70
25.80
Abundance
150000
100000
50000
Time-->
TIC: ENG1663.D
L
T—1—I—I—i—I—I—I—I—I ! I—I—I—I—I—!—I—I—|—!—I—1—r
25 !00 25.50 26.00 26*50
188.00
1UGT
Abundance Ion 188.00 (187.70 to 188.70) :
Ion 94.00 (93.70 to 94.70): ENG16
3000
2000
1000
Time-->
"~1 1 1 T
25.00 25.50 26.00 26.50
#12
Phenanthrene
Concen: 1.48 ng/uL
RT: 25.74 min Scan# 1919
Delta R.T. -0.00 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:178 Resp: 304747
Ion
178
176
0
0
Ratio
100
19.6
0.0
0.0
Lower Upper
10 .2
0.0
0.0
30 .4
0.0
0.0
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 26.6
0 0.0
0 0.0
ENGT6F3TD PES3 .M
OC03O61
Mon Oct 18 lb:00:2fc> 1999
HP 5989B
Page 8
-------
Abundance
150000
100000
A
TIC: ENG1663.D
50000
Time--> 25.70 25.80 25.90 26.00
Abundance Ion 178.00 (177.70 to 178.70)
150000
100000
50000
0 .
25170
Ion 176.00 (175.70 to 176.70):
ENG
ENG
25 .86
i—i—i—i—|—i—i—i—i-
25.80 25190 26100
Abundance
200000
100000
TIC: ENG1663.D
10000 .
i—I—f—i—\—j—i—I—i—i—i—i—r~
fTime--> 27.50 28,00 28:50
29100 29.50
#14
Anthracene
Concen: 1.78 ng/uL
ET: 25.86 min Scan# 1938
Delta R.T. -0.01 min
Lab Pile: ENG1663.D
Acq: 15 Oct 99 2:54 pra
Tgt Ion:178 Resp:
Ion Ratio Lower
224322
Upper
178
100
176
19 .2
10.0
29.9
0
0 . 0
0.0
0.0
0
0.0
0.0
0.0
i—i—I—i—i—[—i—i—i—i—j—i—I—I—i—j—i—r*—i—i—t—!—i—t—r
Time--> 27 150 28.00 28150 29100 29.50
Abundance I on 212.00 (211.70 to 212.70) : ENG
Ion 106,00 (105.70 to 106.70): ENG
20000 .
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 27.3
0 0.0
0 0.0
0CC3962
ENG1663.D—PES3 .M
Mon QCt IB 15:00:29 1999
HP 5989B
Page 9
-------
Abundance
150000
100000
50000
Time-
TIC: EMG1663.D
28.60
28 . 80
Sundance Ion 202.00 {201.70 to 202.70): IMG
Ion 101.00 (100.70 to 101.70): ENG
150000
100000
50000
28.72
T
lme - - >
28 ! 60
28.80
Abundance
200000
100000
TIC; ENGl££37IJ
Time-->
0
i r ! r-
-i—i—i—f r !—i—i—j—f—i—i—t—|—f—
28.50 29100 29150 30100
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
20000
10000
0
Time-->
n—!—!—r—r~i—!—»—i—!—i—i—i—j—j—i—r—i—i—r—t—i—\—r~
28.50 29.00 29.50 30100
#16
Fluoranthene(CCC)
Concen: 1.50 ng/uL
RT: 28.72 min Scan# 2377
Delta R. T. -o.Ol min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:202 Resp: 297782
Ion Ratio
202 100
101 25.9
0 0.0
0 0.0
Lower Upper
12 .1
0.0
0.0
36 .1
0.0
0.0
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 rain
Lab File; ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 31.6
0 0.0
0 0.0
ENGl fa 6 3 . D PEST7WT
OCC 3933
Mon Oct 18 "T5T00:33 1999
HP 5989B
Page 10
-------
Abundance
200000 -
100000 -
TIC: EMG1663.D
0
#18
Pyrene
Concen: 1.47 ng/uL
RT: 29.33 min Scan# 2468
Delta R.T. -0.01 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pra
Tgt Ion:202 Resp: 325377
Ion Ratio Lower Upper
Time--> 29.20 29.40 29.60
«T 3 jp- '' A A ' /nA-i"—*¦> K' " X -J"* /K ^ ft AT wvtw -
Abundance Ion 202.00 (201.70 to 202.701 : ENG
Ion 101.00 (100.70 to 101.70): ENG
150000 J 29.33
100000
202
100
101
29.5
13.9
41.5
0
0.0
0.0
0.0
0
0.0
0.0
0 .0
50000
Time-
—1 1 e r
29.20
29.40
—j— -p— , ' f
29.60
AEun3anc¥"
200000
100000
v -*—i—r-i—i—I—i—|—f—i—I—E—i—i—rT—i—r—t—r—i—i—f—i—i—r*
Time--> 29.40 29150 29.60 29.70 29.80
TIC: ENG1663.D
K.
#19
p-Terphenyl-dl4
Concen: 2.61 ng/uL
RT: 29.62 min Scan# 2511
Delta R.T. -0.00 min
Lab File: SNG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:244 Resp.- 348868
Lower Upper
14.6 43.7
0.0 0.0
0.0 0.0
Ion
244
122
0
0
Ratxo
100
32 . 5
0.0
0.0
1111 m m i II ^ i ¦— i m i i Q ¦ m K ° i n « lwmwwpi—rw—w
Abundance Ion 244.00 (243.70 to 244.70)
Ion 122.00
(121.70 to 122.70)
29.62
~mr
ENG
150000
100000
50000
0
0CG39
- .1
£~sl
—i—i—i—i—i—[—i—,—i—¦—J—i—i—i—i—.—i—i—i—i—|—i—r
iTime- - > 29.40 29.50 29.60 29.70 29.80
ENG1S63 .D—PES3 .M
TfolTUct 18 lb : 00 :36 1999
HP 5989B
Page 11
-------
[Abundance
80000
TIC; SNG1663.D
Time-
soooo
40000
20000
t f—'
33.00
32 .50
i—i—r—i—r~r™
33:50 34:00
Abundance Ion 240.00 (239.70 to 240.70): ENG
e000 1Ion 120.00 (119.70 to 120.70); ENG
4000
2000
0
1—i—s—r
Time-->
32.50 33.00
—"i—r~
33 .50
34.00-
¦ — — . « rr...
AbundanceTIC; ENG1663.D
80000
60000
40000
20000 J
n
V -^T 1 p—1 1 1 1 1 1 1 1 1 1 1 ! 1 1 r
fTime--> 33:30 33:40 33! 50 33160
3— „ — AAg A A )
ENGt^FT".Tr~
#20
Benzo(a)anthracene-d!2
Concent 0.00 ng/uL
Expected RT: 33.36 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 240
Exp Ratio
100
27.9
0.0
0.0
#21
Benzo(a)anthracene
Concen: 1.81 ng/uL
RT: 33.45 min Scan# 3086
Delta R.T. -0.01 rain
Lab Pile: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt ion:228 Resp: 185810
Ion Ratio Lower Upper
228 100
114 25.6 12.8 38.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TMT
Ion 114.00 (113.70 to 114.70) : ENG
33.45
0CCJ9S3
33:30 33:40 33-50 33.60
PES3.M Men Oct 18 15:00:39 1999'
HP 5989B
Page 12
-------
^Abundance
80000
TIC: ENG1663.D
Time- - > 32150 33.00 33.50 34100 34.50
60000
40000
20000
Abundance Ion 240.00 (239.70 to 240.70): ENG
jlon 120.00 (119,70 to 120.70): ENG
6000
1
4000
2000
0
n—i—i—r~
~i—i—f—r~
Time--> 32.50 33.00 33.50 34.00 34.50
Abundance
80000
60000
40000
20000
TIC: 2NG1663.D
0
80000
60000
40000
20000
Time-->
33 .40
33 .60
i r—i 1 r
33.80
#22
Chrysene-dl2
Coneen: 0.00 ng/uL
Expected RT: 33.50 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.3
0 0.0
0 0.0
#23
Chrysene(CCC)
Concen: 1.66 ng/uL
RT: 33.60 min Scan# 3110
Delta R.T. -0.01 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:228 Resp: 244561
Time--> 33.40 33.60 33.80
Abundancelon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
33 .60
Ion
228
114
0
0
Ratio
100
23 .8
0.0
0.0
Lower Upper
11.2
0.0
0.0
33.5
0.0
0.0
0CC105S
ENG1663 .D—PEF3TRT
Mon Oct IB 15:00:43 1999
HP 5989B
Page 13
-------
ENG1663.D
40000
20000
Time - - > 3830 39100 39150 40100
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132,70): ENG
6000 '
4000
2000
Time-
i—t—i—i—i—i—i—r—i—»—i—i—j—!—i—i—i—I—f—r
38.50 39.00 39.50 40.00
40000
20000
-i—i—*—r
20000
10000
Time-->39.30
ENGlbbJ.D—PEST7H
r_39 140
~1 1 1 P"
39160
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pro
Tgt Ion: 264
Ion Exp Ratio
264 100
132 69.4
0 0.0
0 0.0
TIC: ENG1663.D
#25
Benzo(b)fluoranthene
Concen: 1,64 ng/uL
RT: 39.50 mm Scan# 4016
Delta R.T. -0.02 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:252 Resp: 170709
Ion Ratio Lower Upper
Time-->39130 39.40 39-50 39.60
Abundance Ion 252.00 (251.70 to 252.70}: ENG
Ion 126.00 (125.70 to 126.70): ENG
40000 J 39.50
30000
252
100
126
27 .1
14.0
41.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0003937
39150
Mon Oct IB 15:00:46 1999'
HP 5989B
Page 14
-------
(Abundance
40000
TIC: ENG1663.D
20000
Time--> 38 . 50 39!00
*1—!—I—i—|—i—i—|—¦ i r r r - r r
39.50 40 100 40150
Abundance Ion 264.00 (263.70 to 264.70): ENG
(Ion 132.00 {131.70 to 132.70): ENG
6000
4000
2000
-1 1 1 1 1 j I 1 1 ! [ » 1 T*T { 1 ! ! 1 1 f }
fTime--> 38.50 39.00 39.50 40.00 40.50
20000
Time-->
39.40
39.60
39.80
#26
Benzo (k) fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.53 min
Lab Pile: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 264
Ion
264
132
0
0
Exp Ratio
100
35.8
0 .0
0.0
TIC: ENG16637D
40000
Abundance Ion 252.00 (251.70 to 252.70): StfG
Ion 126.00 (125.70 to 126.70): ENG
40000
30000
20000 -
10000
0
39.65
Time-
—I ! 1 1 1 r r r—i s 1 1 1 r
39:40 39.60 39.80
ENG1663 .D PESTTW"
#27
Benzo(k)fluoranthene
Concen: 1.85 ng/uL
RT: 39.65 min Scan# 4039
Delta R.T. -0.01 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:252 Resp: 142803
Ratio
100
29 .8
0.0
0.0
Lower Upper
13 .9
0.0
0.0
41.5
0.0
0.0
0CC3963
"HorTUct 18 15:00:50 1999
HP 5989B
Page 15
-------
Abundance
30000
20000
10000
0
|Time--> 40:50 41:00 41150 42100 42150
TIC; ENG1663.D
tTXZ—JS ~ 1" ¦*> /» A 7T75 / A PfTf—rrzz—*1 tE A PI A \ f*WI
Abundance Ion 264.00 (263.70 to 264.70) : ENG
Ion 132.00 (131.70 to 132 . 70) r
6000 J
4000
2000
0
Time--> 40.50 41.00
i " i—|—r "i ¦
41150
t—i—i—i—i—j—i—j—i—i—r~
42.00 42.50
Abundance
30000
20000
Time-->
TIC: ENG1663.D
10000
0
""T ¦ t r~
41.60
41,80
42.00
#28
Benzo(a)pyrene~dl2
Concen: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: 1NG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 264
Ion
264
132
0
Exp Ratio
100
37.8
0.0
0.0
Abundance Ion 252.00 (251.70 to 252.70): ENG
20000
15000
10000
5000
¦Ion 126.00 (125.70 to 126.70): ENG
41.78
Time-
"I—t r -i 1 r~
41.60
1 1 \ \ 1 ! ! r
41.80 42.00
#29
Benzo(a)pyrene(CCC)
Concen: 1.67 ng/uL
RT: 41.78 min Scan# 4365
Delta R.T. -0.01 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:252 Resp:
84616
Ion
252
126
0
0
Ratio
100
29.4
0.0
0.0
Lower Upper
15.7
0.0
0.0
46.9
0.0
0.0
398Q
ENG 16 6 3 .D PE5T7M"
Mon Oct 18 15:00:53 1999
HP 5989B
Page 16
-------
Abundance
30000
20000:
10000
0
TIC: ENG1663.D
i s 1 1 ! 1 r-
52.00
~i 1 1 1 1 1 1 r
53:00 54.00
Time - - >
Abundance Ion 288.00 (257.70 to 288.70): fitJG
2000 .
1000
0
Time - - >
1- "'T 1 1 !—[ 1 1 \ 1 1 1 ! r
52:00 53100 54.00
#30
Indeno(1,2,3-cd)pyrene~dl2
Concen: 0.00 ng/uL
Expected RT: 52.54 min
Lab File: ENG16 63.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:
Ion
288
0
0
0
288
Exp Ratio
100
0.0
0.0
0.0
Abundance
30000
20000
10000
0
TIC: ENG1663.D
1 1 J 1 T"
Time--> 52.40 52
Abundance Ion 276.05
Ion 138.00
10000.
5000
—i—i—i—r~
SO 52
—I—r
80
53.00 53
275.75 to 276.75)
[137.70 to 138.70)
52 .79
20
0
#31
Indeno(1,2,3-cd)pyrene
Concen: 1.58 ng/uL
RT: 52.79 min Scan# 6073
Delta R.T. -0.03 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:276.05 Resp: 80642
Ion Ratio Lower Upper
276
100
138
21.3
30.1
90 .2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG
Time--> 5 2 ! 4 0 52 ieo' 5*2 ! 8*0 53!q0 *53 i 20
ENGTFOTD PES3 .M Mon Oct 18 15:00:57 1999'
0003030
HP 5989B
Page 17
-------
Abundance
30000
20000
10000
0
Time--561 00 52.00 53.00
AbundanceIon 292.00 (291.70 to 252.70}: ENG
2000
1000
0 .
00
-i 1 1 r
52.00
53 .00
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 52.50 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 292
Ion
292
0
0
Exp Ratio
100
0.0
0.0
0.0
Abundance
TIC: SNG16S3.B
30000 J
A
20000:
J v
10000 .
0
Time--> 52.40 52.60 52.80 53.00 53.20
Abundance Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
10000 .
52 .83
5000 -
0 -
| ! 1 t : J 1 ] T 1 J 1 1 t i | 1 1 t 1 j t (
Time--> 52.40 52.60 52.80 53.00 53.20
#33
Dibenz(a,h)anthracene
Concen: 1.64 ng/uL
RT: 52.83 min Scan# 6081
Delta R.T. -0.03 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion:278 Resp: 72296
Ion Ratio Lower Upper
278
100
139
31.7
26.9
80.5
0
0.0
0.0
0.0
0
0.0
0.0
0 . 0
0003931
HP 5989B
Page 18
-------
Abundance
15000
10000
5000
Time-
TIC: 1NG1663.D
55.00
56.00
Abundance Ion 288.00 (287.70 to 288.70): 8NG
2000
1000 -
0 .
Time-
55.00
56.00
Abundance
15000
10000
TIC; ENG1663.D
Time
5000 J
55.40
55.60
55.80 56.00 56.20
Abundance Ion 27 6.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
10000 55.82
5000
#34
Benzo(g,h, i)perylene-dl2
Concen: 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1663.D
Acq: 15 Oct 99 2:54 pm
Tgt Ion: 288
Exp Ratio
100
0.0
0.0
0.0
0
#35
Benzo(gf h,i)perylene
Concen: 1.50 ng/uL
T"*m r- t— a J _ XL y* y* /¦* r
RT: 55.82 mm Scan# 6666
Delta R.T, -0.03 rain
Lab Pile: ENG1663.D
Acq; 15 Oct 99 2:54 pm
Tgt Ion:276 Resp: 83636
Ion
276
138
0
0
Ratio
100
37 .2
0.0
0.0
Lower Upper
0.0
0.0
26.0#
0.0
0.0
frime-->
ENG1&63.D
i—!—I—I—I—i—I—|—I—r
56.00 56.20
55.40 55.60 55,80
PES3.M Kon Oct IB IS:01:04 1999
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acq Oil
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG16 6 4 . D
15 Oct 99 4:00 ptr.
CARB4 2 9,MDL3
Oct 18 15:08 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Method : C:\HPCHEM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:50:18 1999
Response via : Multiple Level Calibration
Internal Standards E.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
20.00
190
613246
5.00
ng/uL
0.00
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00
ng/uL
0.00%
4)
2-Methlynaphthalene-dl0
19.36
152
261977
2.18
ng/uL
54.39%
5)
Acenaphthylene-d8
0.00
160
0
0.00
ng/uL
0.00%
7)
Acenaphthene-dlO
0.00
164
0
0.00
ng/uL
0.00%
9)
Fluorene-dlO
0.00
176
0
0 .00
ng/uL
0 .00%
11}
Phenanthrene-dl0
0.00
188
0
0.00
ng/uL
0.00%
135
Anthracene-dlO
0.00
188
0
0.00
ng/uL
0.00%
15)
Fluoranthene-dl0
0.00
212
0
0.00
ng/uL
0.00%
17)
Pyrene-dlO
0.00
212
0
0.00
ng/uL
0.00%
19)
p-Terpheny1-dl4
29.62
244
318138
2.66
ng/uL
66.56%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00
ng/uL
0.00%
22)
Chrysene-dl2
0.00
240
0
0.00
ng/uL
0.00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
.0
0.00
ng/uL
0.00%
26)
Benzo(k)fluoranthene-dl2
0.00
264
0
0 .00
ng/uL
0.00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00
ng/uL
0.00%
30)
Indeno(1,2,3-cd)pyrene-dl2
0 .00
288
0
0.00
ng/uL
0.00%
32)
Dibenz(a,h)anthracene-dl4
0 .00
292
0
0,00
ng/uL¦
0.00%
34)
Benzo(g, h,i)perylene-dl2
0.00
288
0
0.00
ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.73
128
487229
1.23
ng/uL
99
6)
Acenaphthylene
21.66
152
157482
1.18
ng/uL
100
8)
Acenaphthene(CCC)
22.11
154
134663
1.15
ng/uL
97
10)
Fluorene
23.38
166
151559
1.25
ng/uL
98
12)
Phenanthrene
25.73
178
243276
1.33
ng/uL
99
14)
Anthracene
25.86
178
167866
1.49
ng/uL
98
16)
Fluoranthene(CCC)
28.72
202
255052
1.43
ng/uL
97
18)
Pyrene
29.33
202
281602
1.42
ng/uL
96
21)
Benzo(a)anthracene
33 .45
228
166108
1.81
ng/uL
100
23)
Chrysene(CCC)
33 .60
228
230775
1.75
ng/uL
97
25)
Benzo(b)fluoranthene
39.50
252
162169
1.74
ng/uL
99
27)
Benzo(k)fluoranthene
39 .65
252
132083
1.91
ng/uL
94
29)
Benzo(a)pyrene(CCC)
41.78
252
80493
1.78
ng/uL
95
31)
Indeno(1,2,3-cd)pyrene
52.81
276
75825
1.66
ng/uL
74
33)
Dibenz(a,h)anthracene
52.84
278
67526
1.72
ng/uL#
25
35)
Benzo(g,h(i)perylene
55.80
276
80682
1.62
ng/uLm
36
OCC 00:33
{#) ¦ qualifier out of range (m) « manual integration
ENG1664.D PES3.M Mon Oct 18 15:09:37 1999 HP 5989B Page 1
-------
Quantitation Report
C:\HPCHEM\l\DATA\ENG1664.D
15 Oct 99 4:00 pm
CARB4 2 9,MDL3
Data File
Acq On
Sample
Misc
Quant Time: Oct 18 15:08 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHIM\l\METHODS\PES3,M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
SBundance
450000
400000
350000
300000
250000
200000
150000 .
100000
TIC: ENG1664.D
50000
4s
10
19S
ia
12 16
23
21
-Jl
29
31
35
li
T—! 1 r 11 i " 1 1 1 J ! ! 1 1 1 1 1 1 1 1 i 1 1 1 J 1 1 1 1 1 ! 1 1 1 1 \ T—1 5 { r—
Time--> 20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0C 01034
ENG1664.D PES3.M
Mon Oct 18 15:09:43 1999
HP 5989J3
Page 2
-------
TIC: ENG1664.D
200000
100000
Time-->16.50
"i—i—i—i—i—r
17:00 17.50
i—i—|—i—I ii |
18.00 18.50
AbundanceIon 136.00 (135.70 to 136.70}: ENG
Ion 68.00 (67.70 to 68.70): ENG16
4000
2000
i ii—i—r—r—i—r—i—i—t—i—i—!—i—i—s—i—i—r—\—i—i—r
frime--> 16:50 17.00 17.50 18.00 18.50
#2
Naphthalene-d8
Concen.- 0.00 ng/uL
Expected RT; 17.69 min
Lab File: ENG1664,D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 136
Ion
136
68
0
0
Exp Ratio
100
15 .3
0.0
0.0
Abundance
200000 .
100000
Time-
TIC; ENG1664.D
17.60
i j ! 1 r
17 180
Abundance Ion 128.00 (127.70 to 128.70)
Ion 127.00 (126.70 to 127.70)
17.73
200000
~SUG"
ENG
100000
Time-->
17.60
17 .80
#3
Naphthalene(CCC)
Concen: 1.23 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:128 Resp: 487229
Ion Ratio Lower Upper
128 100
127 12.7 0.0 63.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG16S4.D FES3.M
0CC3995
/"VJtlC M'fH M pm m fm mm fm>
Mon Oct 18 15:09:471999
HP 5989B
Page 3
-------
Abundance
100000
TIC: ENG1654.D
50000
I 1 T- T
19.40
Time - - >
19.30
19 .50
Abundance Ion 152.00 (151.70 to 152.70): ENG
150000
100000 .
50000
19.36
Time-
#4
2-Methlynaphthalene-dlO
Concen: 2.18 ng/uL
RT: 19.36 min Scan# 759
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:152 Resp: 261977
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0 . 0
0
0.0
0.0
0.0
19:30
19.40
19.50
WDundance"
100000
"TIC: ENG1664.D
50000
0
21! 50 22 ! 00 '22: s'o'
Time--> 20.50 21.00
Abundance Ion 160.00 (159.70 to 160.70) : ENG
2000
1000
0 .
> 20:50' 21 loo
Time
ENG1664 .13—PES3.M
-t—1—j—j—r
21.50
—i—r—r—1—1—r-i—1—!—r
22:00 22:50
#5
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT: 21.63 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 160
Ion Exp Ratio
160 100
0 0.0
0 0.0
0 0.0
occjoes
Mon Oct 18 lb:09:50 1999
HP 5989B
Page 4
-------
Abundance
TIC: ENG16S4.D
n
80000 :
\
60000 :
40000:
20000:
i *
) V
o:
rime-->
1 1 I 1 1 1 1 : i 1 1 —j 1 I , I I , |
21.50 21.60 21.70 2l!80
Abundance
Ion 152.00 (151.70 to 152.701: ENG
Ion 153.00 (152.70 to 153.70): ENG
21.66
A
50000 -
\
Jy\_
U -
Time-->
21.50 21.60 21.70 21.80
#6
Acenaphthylene
Concen: 1.18 ng/uL
RT: 21.66 mill Scan# 1303
Delta R.T. -0.00 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:152 Resp: 157482
Ion Ratio Lower Upper
152
100
153
13 .0
6.6
19 .6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1664. D
100000
50000
-1—i—|—!—i—i—i "f" i t i—i—I—i—i—j—r—i—i—i—r
21100 21.50 22.00 22.50 23100
rime-~>
Abundance Ion 164.00 (163.70 to 164.70): ENG
2000
1000
0
Time-->
1 | ' r
21.00
~i—i—|—i—r~
21.50
22 .00
"*i—i—!—i—r
22.50
i i r
23.00
#7
Acenaphthene-dlO
Concen: 0.00 ng/uL
Expected RT: 22.04 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 164
Exp Ratio
100
0.0
0.0
0.0
ENG1664.D FEST7W"
0CG3997
"Hon Oct 18 15:09:53 1999
HP 5989B
Page 5
-------
TIC: ENG1664.D
100000
50000
t—i—!—i—r—i—i—i "t |—i—i—s—r—-1—i—i—r—i—r
Time - - > 21190 22.00 22llO 22120 22.30
Abundance Ion 154.00 (152.70 to 154.70): HNG"
Hon 153.00 (152.70 to 153.70): ENG
22 .11
80000
60000
40000
20000
1—i—«—!—i—i—r—!—r—f—i—i—i—r~~\—I—s—f—f—r—j i
Time--> 21.90 22.00 22.10 22120 22130
Abundance
150000
100000
50000
*-? ! 1 1 1 1 1 ! ! 1 1 1 1 1 1 1 1 1 ! 1 ! E 1 T*
22l50 23.00 23.50 24.00
Time-->
Abundance Ion 176.00 (175.70 to 176,
2000
1000 -
Time-
*1—1—!—I—!—!—I—j 1" ' ) i—I—I—*—r*
22.50 23.00 23.50
ti—j—i—j—!—r~
24.00
#8
Acenaphthene(CCC)
Concen: 1.15 ng/uL
RT: 22.11 min Scan# 1371
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:154 Resp: 134663
Ion
154
153
0
0
Ratio
100
101.3
0.0
0.0
Lower Upper
49.1
0.0
0.0
147 .1
0.0
0.0
TIC: ENGl6pr.D
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 176
Ion Exp Ratio
100
0.0
0.0
0.0
HKT
000)993
ENG1664 .D—PEH3TPT
Mon Oct 18 lb : 09:56 1999
HP 5989B
Page 6
-------
Abundance
150000
100000
TIC: ENG1664.D
50000
23140 ' ' 23.60
Abundance Ion 166.00 (165.70 to 166.70); ENG
lion 165.00 {164.70 to 165.70): ENG
23.38
80000
60000 :
40000:
20000
Time-->
#10
Fluorene
Concen: l.25 ng/uL
RT: 23.38 min Scan# 1562
Delta R.T. -0.01 min
Lab File; ENG1664.D
Acq; 15 Oct 99 4:00 ptn
Tgt Ion:166 Resp: 151559
Ion Ratio Lower Upper
166
100
165
89.2
45.7
137.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
®uii3ance
150000
100000
TIC: ENG1664.D"
50000
0
u
Time--> 24150 25.00 25.50 26.00
Abundance Ion 188.00 (187.70 to 188.70): fiNG
Ion 94.00 (93.70 to 94.70): ENG16
r—i—[—i—r~
25.50
I—i—i—i—i—r
26150
3000
2000
1000
¦*wr
—i—!—i—i—(—i—i—i—i—i—i—i—i—i—t—r—i—\—!—|—r—i—r
iTime - -> 24 150 25.00 25.50 26 .00 26.50
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 24.5
0 0.0
0 0.0
0CC3Q23
HF 59B9B
Page 7
-------
Abundance
150000
100000
50000 J
TIC: EMG1664.D
25.60
25.70
25.80
Time
Abundance Ion 178.00 (177.70 to 175.70): fiMG
150000 HIon 176,00 (175.70 to 176.70)
25.73
100000 -
50000
Tirae--> 25!60
25.70
25.80
#12
Phenanthrene
Concen: 1.33 ng/uL
RT: 25.73 min Scan# 1920
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:178 Resp: 243276
Ion Ratio Lower Upper
178
100
176
19 .6
10.2
30.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
TT 0 » «IEi-!^rC!!y «L ^ ^ «D
t—i—i—i—i—j—r
26.00 26150
\ f
Time--> 25 100 25150
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
3000 "
2000
1000
0
Time-->
T ! J ! 1 f 1 1 1 1 1 ( 1 1 1 1 1 1 ! 1 1 V
25.00 25.50 26.00 26.50
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 188
Exp Ratio
100
26.6
0.0
0.0
ENG1664.D PES3 .M
0CC91Q0
Mon Oct 18 15:10:03 1999
HP 5989B
Page 8
-------
Abundance
150000 J
TIC: ENGl6b4.D
100000 -
50000 .
25180
Time--> 25.70
Abundance Ion 178.00 (177.70 to 178.70): SMG
25.90
26.00
Time--> 25.70
25.80
25.90
26.00
#14
Anthracene
Coneen: 1.49 ng/uL
RT: 25.86 min Scan# 1940
Delta R.T. -0,01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:178 Resp: 167866
Ion Ratio Lower Upper
178
100
176
19.1
10.0
29.9
0
0,0
0.0
0.0
0
0.0
0.0
0.0
rsr-« <¦ ¦" — jm 4 / ji i m. -
AbundanceTIC: ENG1664.D
200000
150000
100000
50000
|Time--> 27 iso 28 1 do' 28 I 50' 29 I 00 29! SO
10000
5000
0
1—i—i—i—i—!—i—r-n—i—r—i—i—i—I—p-i—i—i—i—i—i—i—i—r
Time-->27150 28.00 28.50 29.00 29.50
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1664.D
Acq-. 15 Oct 99 4:00 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 27.3
0 0.0
0 0.0
Abundance Ion 212.00 (211.70 to 212.70): 2NG
I°n 106.00 (105.70 to 106.70): 1NG
ZUvUU
15000
OGCJiOi
ENG1664.D—PES3.M
Mon Oct 18 15:10:06 1999
HP 5989B
Page 9
-------
Abundance
TIC: ENG1664.D
150000 -
A
100000 J
1
50000 J
j\
0 -
Time-->
28.60 28.80
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
28.72
100000 -
ft
50000 _
/ A I
A
n
U -
Time-->
28.60 28180
#16
Fluoranthene(CCC)
Concen: 1.43 ng/uL
RT: 28 . 72 min scan# 2378
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt IOil: 202 Resp: 2550S2
Ion Ratio Lower Upper
202
100
101
25.6
12.1
36.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
150000
100000 4
50000
0
Time-->
TIC: ENG1664.D
L
t—i—|—i 'i 1111 t j i—i i i—|—i—i—r—i—j—i—f—i—r
28.50 29.00 29.50 30.00
10000
5000
0
I
Time-->
1 1 1 \ ] 1 1 1 1 [ 1 1 ! ! 1 1 F 1 1 ! 1 1 ! f
28.50 29100 29.50 30.00
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab File; ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 212
Exp Ratio
100
31.6
0.0
0.0
Abundance Ion 212.00 (211.70 to 212.70): ENG
.*«««« lion 106.00 (105.70 to 106 .70) : ENG
20000
15000 :
0CC3102
ENGT¥6^
PES3 .M
Mon Oct 18 15:10:09 1999
HP 5989B
Page 10
-------
Abundance
200000
150000
100000 :
50000
0
TIC: ENG1664.D
~i—~f 1 1 1 1 r
29.40
50000
Time-
—r 1 1 1 1 r~
29'.20
29140
Abundance
200000 :
150000 :
Time-->
100000
50000
29.40
29.60
29.80
#18
Pyrene
Concen: 1.42 ng/uL
RT: 29.33 min Scan# 2469
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:202 Resp: 281602
Time--> 29.20
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 {100.70 to 101.70): ENG
29.33
100000
Ion
202
101
0
0
Ratio
100
29 . 5
0 . 0
0.0
Lower Upper
13 .9
0.0
0.0
41.5
0.0
0.0
TIC: ENG1664.D
Abundance Ion 244.00 (243.70 to 244.70): ENG
150000
100000
50000
0
lion 122.00 (121.70 to 122.703: ENG
29.62
Time-->
ENG1664,D PES3.M
#19
p-Terphenyl-dl4
Concen: 2.66 ng/uL
RT: 29.62 min Scan# 2512
Delta R.T. -0.00 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:244 Resp: 318138
Ion Ratio Lower Upper
244
100
122
32 .6
14.6
43 .7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC31C3
Man Oct 18 15:10:12 1999
HP 5989B
Page 11
-------
Abundance
80000
60000
40000
20000
TIC: SUG1664.D
0
~i—!—i—|—i—i
Time--> 32.50 33100
Abundance Ion 240.00 (239.70 to 240.70); ENG
6000 JIon 120.00 (119.70 to 120.70): ENG
I—r—|—i—i—r~i—j—\—i
33.50 34.00
4000
2000
0
Time-
H 1 1 \ 1
32.50
i—i—|—i—i—i—i—|—i—i—i—!—?¦"" i" i—t—r~
33.00 33.50 34.00
#20
Benzo(a)anthracene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.36 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 240
Ion Esqp Ratio
240 100
120 27.9
0 0.0
0 0.0
Abundance
TIC: ENG1664.D
80000 :
A
60000 :
A / \
40000 :
V \ / \
20000:
J V_y V
0
Time-->
33.30 33.40 33 . 50 33 .60
[Abundance Ion 228 . 00 (227 .70 to 228.70): ENG
80000 -
Ion 114.00 (113.70 to 114.70): ENG
60000
33.45 / \
40000
A / \
20000 :
/ \ A
0 -
Time - - >
i • | * i j » j i j i i j i i i rf'i j
33.30 33.40 33.50 33.60
#21
Benzo(a)anthracene
Concen: 1.81 ng/uL
RT: 33.45 min Scan# 3087
Delta R.T. -0.01 min
Lab Pile: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:228 Resp: 166108
Lower Upper
12 . 8 38 .2
0.0 0.0
0 .0 0.0
Ion
228
114
0
Ratio
100
25.6
0.0
0.0
ENG1664.D—PES3 .M
oeoie-i
Mon Oct 18 15:10:1b 1999
HP 5989B
Page 12
-------
Abundance TIC: SNG1664.D
80000
60000
40000
20000
0 i | s ii i j i i k t j * T I r-,-| i t ? i | i r~
Time--> 32.50 33.00 33.50 34.00 34.50
Abundance Ion 240.00 (239.70 to 240.70); ENG
"V. /
6000
4000
2000
Ion 120.00 (119.70 to 120.70): ENG
Time-
'! ' """r
•> 32.50
33.00 33.50 34.00 34.50
Abundance
80000
60000
40000
20000
0
TIC; ENG1664.D
Time--> 33.40 33.60 33.80
Abundance Ion 228.00 (227.70 to 228.70); ENG
80000 -i
60000
40000
20000
Ion 114.00 (113.70 to 114.70): ENG
33 .60
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.50 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.3
0 0.0
0 0.0
#23
Chrysene(CCC)
Concen: 1.75 ng/uL
RT: 33.60 min Scan# 3111
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:228 Resp: '230775
Ion Ratio Lower Upper
228
100
114
23.8
11.2
33.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
^05
33 *40
33 ;60
33;80
Time - ->
HP 5989B
Page 13
-------
TIC: ENG1664.D
40000
20000
"i—i—i—i—i—r
38.50
~i—|—i—i—i—r
39.00 39150
t—r
40100
Time-->
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70) : ENG
6000.
4000
2000
0
Time-->
38.50 39.00 39.50 40.00
Abundance
40000 -
20000
TIC: ENG1S64.D
0
fTime- -;39.30 39.40 39.50 39160
Abundance Ion "252.00 (251.70 to 252.70)
40000 JlQn 126.00
30000:
20000
10000
(125.70 to 126.70)
39 .50
#24
Benzo(b) fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion-. 264
Ion Exp Ratio
264 100
132 69.4
0 0.0
0 0.0
#25
lenzo(b)fluoranthene
Concen: 1.74 ng/uL
RT: 39.50 rain Scan# 4017
Delta R.T. -0.02 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:252 Resp: 162169
Ion Ratio Lower Upper
252
100
126
27 .4
14.0
41.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
~mr
ENG
oce
t—i—i—!—[—i—r
^9.30 39.40
Time
ENG1664 . D—PES3TRT
\ I i—i—r—t—r 1 1 i i—r
39.50 39.60
Mon Oct 18 15:10:22 1999"
HP 5989B
Page 14
-------
Abundance
40000
TIC: ENG1SS4.D
20000
0
Time--> 38.50 39.00 39.50 40.00 40.50
Abundance Ion 264.00 (263.70 to 264.70) : ENG
|Ion 132.00 (131.70 to 132.70): ENG
6000
4000
2000
Time--> 38.50
-?—I—|—r—r-
39.00
i—i—1—i—I—i—i—!—i—r—i—i—i—!—i
39150 40 !00 40.50
#26
Benzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.53 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 264
Ion
264
132
0
0
Exp Ratio
100
35.8
0.0
0.0
TIC:ENG1664:D
40000 -
20000
#27
Benzo(k)fluoranthene
Concen: 1.91 ng/uL
RT: 39.65 rain Scan# 4040
Delta R.T. -0,01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:252 Resp: 132083
-i—i—i—i—|—i—i—f—r—r—!—i—i—i—|—i—i—i—i—j—i—\—i—i—r~
Time-->39140 39.50 39.60 39170 39180
Abundance Ion 252.00 (251.70 to 252.70): ENG
4 00 00 1^*®^ 126.00 (125.70 to 126.7 0) : ENG
Ratio
100
30.8
0.0
0.0
Lower Upper
13 .9
0.0
0.0
41.5
0.0
0.0
30000
20000
10000
39.65
Time-->39.40 39.50 39.60
39170
~i—i—r
39180
ENG1664.D—PES3TFT
0CC
Mon Oct 18 15:10:25 1999
HP 5989B
i
Page 15
-------
abundance
30000
20000
TIC: ENG1664.D
10000
0
~i—r—i—r—p~i—i—*—i—!—rr—i—i—i—i—i—i—i—s—f—i—r™
Time--> 40150 41.00 41.50 42.00 42.50
Abundance Ion 264.00 {263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
6000
4000 .
2000
0
Time-->
¦' i 1 «'
40.50
5 | | | | | | j | f
41.00 41.50
1 ' ! ' I '¦ '
42.00 42.50
#28
Benzo(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 37.8
0 0.0
0 0.0
abundance
30000
20000
10000
TIC: BNG1664.D
Time-
I i \ | [' 1"" 1
41.60
41.80
i 't' 1 | v i r
42 loo
#29
Benzo(a)pyrene(CCC)
Concen: 1.78 ng/uL
RT: 41.78 min Scan# 4366
Delta R.T. -0.01 min
Lab Pile: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:252 Resp: 80493
Ion
252
126
0
0
Ratio
100
28.3
0.0
0.0
Lower Upper
15.7
0.0
0.0
46.9
0.0
0.0
8S^lw^M"^^H""aVaaaaaaaaaaaaaaaaaaaaaaaaaaaaaaMVVaMM^^
Abundance Ion 252.00 (251.70 to 252.70}: ENG
20000 Hion 126.00
15000
(125.70 to 126.70)
41.78
10000
5000
41.60
41.80
42.00
0CC3iC3
ENG1664.D—PES3.M
Mon Oct 18 15 :10 : 29" 1'999
HP 5989B
Page 16
-------
Abundance
30000
20000 -
10000
TIC: ENG1664.D
-i r
Time--> 52100 53100
Abundance ion 288.00 (287.70 to 2&8.170): ENG
54 .00
2000
1000
52 ;oo
Time
53 ;oo
54.00
#30
Xndeno(1,2,3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 52.54 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:
Ion
288
0
0
0
288
Exp Ratio
100
0.0
0.0
0.0
Abundance
tic: ENG1664.D
30000.
A
20000 -
J
10000 .
0 _
Time-->
1 1 1 1 ! 1 j ! 1 » 1 ] < 1 1 ! | 1 1 1 I | 1 1
52.40 52.60 52.80 53.00 53.20
Abundance Ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
10000 .
52 .81
5000 -
0 -
Time-->
i | 1 I i t | 1 1 f 1 | ! 1 1 1 | I 1 1 1 | 1 1
52.40 52.60 52.80 53.00 53.20
ENGTS¥1TD—PES'3 . M
#31
Indeno(1,2,3-cd)pyrene
Concen: 1.66 ng/uL
RT: 52.81 min Scan# 6077
Delta R.T. -0.01 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:276.05 Resp: 75825
Ion
276
138
0
0
Ratio
100
40 .5
0.0
0.0
Lower Upper
30.1
0.0
0.0
90.2
0.0
0,0
1109
MOn OCt 18 15:10:32 1999
HP 5989B
Page 17
-------
TIC: 1MG1664.D
Abundance
30000 J
20000 -
10000 -
Time--s61.00
Abundance Ion 292.00 (291.70 to 292.70): ENG
52.00
53 .00
2000 -
1000 -
Time--d51 00
52.00
53.00
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 52.50 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion: 292
Ion Exp Ratio
292 100
0 0.0
0 0.0
0 0.0
Abundance
30000
20000
10000
Time-->52.40
TIC: ENG1554.D
-i—i—i—i—i—r
52:60 52.80
T—?—| 3—I I—1—J !—r
53.00 53.20
AbundanceIon 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
52 .84
10000
5000
Time-->52 140
! 1 1 1 1 1 r~—r
52.60 52.80
~i—i—I—i—i—i—r—I—i—r
53:00 53.20
ENGlb64.D PES3.M
#33
Dibenz(a,h)anthracene
Concen: 1.72 ng/uL
RT: 52.84 min Scan# 6084
Delta R.T. -0.02 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:278 Resp: 67526
Ion
278
139
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
26.9
0.0
0.0
80.5#
0.0
0.0
OCOllO
Mon Oct IB 15:10:35 199?
HP 5989B
Page 18
-------
TIC: ENG1664.D
Abundance
15000 -
10000 .
5000 -
56,00
Time-->
Abundance Ion 288.00 (287.70 to 288.70): ENG"
55 . 00
2000 J
1000 -
Time-->
55.00
56.00
#34
Benzo(g,h,i)perylene-dl2
Concern 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1664.D
Acq: 15 Oct 99 4;00 pra
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Abundance
TIC: ENG16S4.D
15000 J
A
/ \
10000 .
J V
5000 J
0 -
Time - ->
55.50 56.00
Abundance Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
10000 -
55 .80
5000 „
A
0 .
Time-->
i i \ i i \ 1 ' ^ »
55.50 56.00
#35
Benzo(g,h,i)perylene
Coneen: 1.62 ng/uL m
RT: 55.80 min Scan# 6664
Delta R.T. -0.04 min
Lab File; ENG1664.D
Acq: 15 Oct 99 4:00 pm
Tgt Ion:276 Resp: 80682
Ion Ratio Lower Upper
276
100
138
52 .2
6,5
26.0#
0
0,0
0.0
0.0
0
0.0
0.0
0.0
ENG16M.D—PE5T7FT
OCCJili
Mon Oct IB 15:10:40 1999
HP 5989B
Page 19
-------
Quantitation Report
C:\HPCHEM\l\DATA\ENG1665.D
15 Oct 99 5:06 pm
CARB429,MDL4
Data File
Acq On
Sample
Misc :
Quant Time: Oct 18 15:13 1999
Vial: 6
Operator:
Inst • HP 5989B
Multiplr: 1.00
Method : C:\HPCHEM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:50:18 1999
Response via : Multiple Level Calibration
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
20.00
190
635311
5.00 ng/uL
0.00
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00 ng/uL
0 .00%
4)
2-Methlynaphthalene-dl0
19.36
152
258178
2.07 ng/uL
51.74%
5)
Acenaphthylene-d8
0.00
160
0
0.00 ng/uL
0.00%
7)
Acenaphthene-dlO
0.00
164
0
0.00 ng/uL
0.00%
9)
Fluorene-dlQ
0.00
176
0
0.00 ng/uL
0.00%
11)
Phenanthrene-dlO
0.00
188
0
0.00 ng/uL
0.00%
13)
Anthracene-dlO
0.00
188
0
0.00 ng/uL
0.00%
15)
Fluoranthene-dlO
0.00
212
0
0.00 ng/uL
0.00%
17)
Pyrene-dlO
0.00
212
0
0.00 ng/uL
0.00%
19)
p-Terpheny1-dl4
29.62
244
320255
2.59 ng/uL
64.68%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00 ng/uL
0.00%
22)
Chrysene-dl2
0.00
240
0
0.00 ng/uL
0.00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0.00%
26)
Benzo(k)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0.00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00 ng/uL
0.00%
30)
Indeno(1,2,3-cd)pyrene-dl2
0.00
288
0
0.00 ng/uL
0.00%
32)
Dibenz(a,h)anthracene-dl4
0.00
292
0
0.00 ng/uL
0.00%
34)
Benzo(g,h,i)perylene-dl2
0.00
288
0
0.00 ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.73
128
503125
1.23 ng/uL
99
6)
Acenaphthylene
21.65
152
165855
1.20 ng/uL
100
8)
Acenaphthene(CCC)
22.11
154
153072
1.27 ng/uL
95
10)
Fluorene
23 .38
166
159165
1.27 ng/uL
98
12)
Phenanthrene
25 .73
178
254640
1,34 ng/uL
99
14)
Anthracene
25.86
178
181984
1.56 ng/uL
98
16)
Fluoranthene(CCC)
28.72
202
258097
1.40 ng/uL
97
18)
Pyrene
29.33
202
285608
1.39 ng/uL
97
21)
Benzo(a)anthracene
33 .45
228
154000
1.62 ng/uL
98
23)
Chrysene(CCC)
33.60
228
202222
1.48 ng/uL
95
25)
Benzo(b)fluoranthene
39.50
252
193580
2.00 ng/uL
99
27)
Benzo(k)fluoranthene
39.65
252
166256
2.33 ng/uL
95
29)
Benzo(a)pyrene(CCC)
41.78
252
94797
2.02 ng/uL
97
31)
Indeno(1,2,3-cd)pyrene
52.79
276
85553
1.81 ng/uL
74
33)
Dibenz(a,h)anthracene
52.82
278
76191
1.87 ng/uL#
47
35)
Benzo(g,h,i)perylene
55.80
276
87299
1.69 ng/uLm
58
000)112
(#) « qualifier out of range (m) = manual Integration
ENG1665.D PES3.M Mon Oct 18 15:15:04 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Mise
Quant Time
C:\HPCHEM\l\DATA\ENGl665.D
15 Oct 99 5:06 pm
CARB429,MDL4
Oct 18 15:13 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1. 00
Method : C:\HPCHBM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:50:18 1999
Response via : Multiple Level Calibration
TIC: ENGlbbB.D
Abundance
450000 .
400000 -
350000 .
300000 .
19S
250000 -
in
200000
12 16
10
4S
150000
23
21
100000
29
3 J
50000 -
35
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0CC3313
ENG1665.D PES3.M
Mon Oct 18 15:15:11 1999
HP 5989B
Page
-------
Abundance
200000
100000 j
TIC; ENGl665.t>
0
Jl
Time-->16:50 17100 17!SO' 18100
Abundance Ion 135.00 (135,70 to 136.70
} | I I "M I
18.50
4000
2000
0
Ion 68.00 (67.70 to 68.70): SNG16
t—i—t—i—I—r—i—i—i—I—i—i—i—i—]—i—i—i—I—I—i—r
frime - -> 16:50 17,00 17.50 18.00 18.50
Abundance
200000
100000
TIC: ENG1665.D
100000
Time--> 17.60
ENG1665.D PES3.M
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 17.69 min
Lab Pile: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 136
Ion Exp Ratio
136 100
68 15.3
0 0.0
0 0.0
$3
Naphthalene(CCC)
Concen: 1.23 ng/uL
RT: 17.73 rain Scan# 258
Delta R.T. -0.01 min
Lab File: ENG1665,D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:128 Resp: 503125
Time --> 17160 17180
IWaundanceIon 128.00 (127.70 to 128.70) : IMG
jlon 127.00 (126.70 to 127,70): ENG
17.73
200000
Ion
Ratio
Lower
Upper
128
100
127
12,7
0.0
63.0
0
0.0
0.0
0.0
0
0,0
0.0
0.0
OCC0114
17.80 T
Mon Oct 18 15:15:15 1999
HP 5989B
Page 3
-------
Abundance
100000
TIC: ENG1665.D
Txme-->
19.30
19.40
50000
AbundanceIon 152.00 (151.70 to 152.70): ENG
150000
19.36
100000
50000
[Time-
19.30
19.40
2000
1000
1—I—i—i—i—|—i—i—i—i—|—i—i—i—i—|—i—i—i—i—|—i—r
fTime--> 20.50 21.00 21.50 22 loo 22.50
#4
2-Methlynaphthalene-dlO
Concern 2.07 ng/uL
RT: 19.36 min Scan# 758
Delta R.T. -0.01 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:152 Resp:
Ion Ratio Lower
152 100
0 0.0 0.0
0 0.0 0.0
0 0,0 0.0
258178
Upper
0.0
0.0
0.0
TIC: ENG1665.D
100000 -
50000
t-~i—j—?—r—i—i—i—i—f—i—!—i—?—|—r—i—!—j—|—!—r
Time--> 20150 21.00 21.50 22100 22.50
SWinSan^o Tori—1 ffrt—PY7S TTXT5—TH—Frt—TfTIT—*7(\\ .—SW-
AXjunQallCc JL OH IbU . UU \ 1D j . / U lu low . / U / . liiNvjr
#5
Acenaphthy1ene-d8
Concen: 0.00 ng/uL
Expected RT; 21.S3 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion; 160
Exp Ratio
100
0.0
0.0
0.0
OCOOH5
ENGlbbb ,JU FESTTFT
Mon uct IB IS:ib:i» iyyy
HP 5989B
Page 4
-------
Abundance
100000
Time-->
50000
TIC: ENGlfabb. D
; i—!—|—f—r
21.50
21.60
2i:70 21180
Abundance Ion 152.00 (151.70 to 152.70): ENG
100000 jlon 153.00 (152.70 to 153.70): ENG
21.65
50000 .
0
Tirae-->
21.50 21.60 21.70 21.80
#6
Acenaphthylene
Concen: 1.20 ng/uL
RT: 21.65 min Scan# 1301
Delta R.T. -0.01 rain
Lab File: ENG1665.D
Acq: 15 Oct 9 9 5:06 pm
Tgt Ion:152
Ion Ratio
152 100
153 13 .1
0 0.0
0 0.0
Resp: 165855
Lower Upper
6.6 19.6
0.0 0.0
0.0 0.0
100000
TIC: ENG1665.D
50000
—?—j—1—f—i—1—1 1—1—T" |—i—1—1—!—I—r
rime--> 21.00 21.50 22.00 22.50 23100
AbundanceIon 164.00 (163.70 to 164.70): ENG
2000
1000
Time-
1—1 ¦ r--t—r—1—j—!—1—r—1—j—r—1—1—r—f—1 1 1 1 \ 1—r r~
21.00 21.50 22.00 22.50 23.00
Acenaphthene-dlO
Concen -. 0.00 ng/uL
Expected RT: 22.04 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:' 164
Exp Ratio
100
0.0
0.0
0.0
ENG1665.D PES3.PT
0C0011S
"Hon Oct 18 15:15:21 1999
HP 5989B
Page 5
-------
TIC: ENG1665.D
mmm%e
100000
50000
Time-
• > 21T90' 22:00
22.10 22.20
~1 I—I—J—r-
22130
AbundanceIon 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.705: ENG
80000
60000
40000
20000
0
22 .11
Time--> 21.90
"I 1 1 1 I 1 1 1 1 1
22.00 22:i0
i 1 i r
22 .20
22:30
Abundance
150000
100000
50000
-i—p—i 1 1—r~|—1—r" 'i —|—1—1—f—!—*|—r~n—1—r
22:50 23.00 23.50 24.00
2000
1000 -
"i—1—1—r
Time--> 22.50 23.00 23.50 24.00
ENG1665 .D—PE'S'3 . M
#8
Acenaphthene(CCC)
Concen: 1.27 ng/uL
RT*. 22.11 min Scan# 1369
Delta R.T. -0.01 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:154 Resp: 153072
Ion
154
153
0
0
Ratio
100
93 .3
0.0
0.0
Lower Upper
49.1
0.0
0.0
147 .1
0.0
0.0
TTC1ENG1665.D
:
Time-->
Abundance Ion 17S.00 (175.70 to 176.70): ENG
#9
Fluorene-dlO
Concern 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 176
Ion Exp Ratio
100
0.0
0.0
0.0
0CC1I17
Mon Oct 18 15:15:24 1999
HP 5989B
Page 6
-------
TIC: ENG1665.D
Abundance
150000
100000
50000
23.30
23.40
23.50
Time-->
Abl^gggelon 166.00 (165.70 to 166.70): ENG
lion 165.00 (164.70 to 165.70): ENG
23 .38
50000
Time--> 23.20
H ! j ! ! 1 1 1 T*
23 .30 23.40
-1—!—r
23150
#10
Fluorene
Concen: 1.27 ng/uL
RT; 23.38 min Scan# 1560
Delta R.T. -0.00 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:166 Resp: 159165
Ion Ratio Lower Upper
166
100
165
89.1
45.7
137.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
TIC: ENG1S65.D
Time - - > 24150' '2*5 I 00 " 25 1 50 ' '26 ! 00 26 150
Abundance Ion 188.00 (187.70 to 188.70)
j L.
3000
2000
1000
Ion 94.00 (93.70 to 94.70)
: 2MG
ENG16
Time--> 24.50
ENG1665.D PES3.M
i i [ i r
25.00
25.50
i i i r
26.00
i i | i r-
26.50
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG16 6 5 . D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 24.5
0 0.0
0 0.0
Mon uct 18 lb:ib:27 iyyy
0CC73A3
HP 5989B
Page 7
-------
sundance
150000
100000
50000
TIC: ENG1665.D
Time--> 25.60 25.70 25.80
AbundanceIon 178.00 (177.70 to 178.70): ENG
150000
100000
50000 -
0
Ion 176.00 (175.70 to 176.70): ENG
25.73
Time--> 25.60
Abundance
150000
iooooo :
50000 J
25.70
25 - 80
t—i—i—*—[—i—I—i—i—i—i—i—i—!—|—r—i—i—i—|—!—i—i—i—r-
25.00 25.50 26.00 26.50
Time-->
Abundance Ion 188.00 (187.70 to 188.70)
3000
2000
1000
0
Ion 94.00 (93.70 to 94.70)
: ENG
ENG16
Time-->
ENG1665.D PES3. M
t-—i—t—!—j—i—i—i—i—j—i—i—i—r~~i—r-~i—i—i | i i—i—r~
25.00 25.50 26.00 26.50
#12
Phenanthrene
Concen: 1.34 ng/uL
RT: 25.73 min Scan# 1917
Delta R.T. -0.01 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:178 Resp: 254640
Ion Ratio Lower Upper
178
100
176
19 .6
10.2
30 .4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1665.D
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 188
Ion Exp Ratio
100
26.6
0.0
0.0
0C0)113
Mon Oct IB 15:15:30 1999
HP 5989B
Page 8
-------
(Abundance
150000
100000
Time*
50000
TIC; ENGlfabbTD
25T70
25.80
25 .90
26.00
Abundance Ion 178.00 (177.70 to 178.70): SNG
150000 Jlon 176.00 (175.70 to 176.70): ENG
100000
50000
Time-
25 .86
25 .70
-1 1 1 1 r
25.80
25 .90
26.00
abundance TIC: ENG1665.D
200000
150000
100000
50000
0 — r ( 1 I » I I I I I j ! 1 | I j f J I I J I J 5 r
[Time - - > 27 l50 28.00 28.50 29.00 29.50
SundanceIon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
20000
15000
10000
5000
*~i—!—1—1—I—1—i—1—r
Time--> 27150' 28! 00 28 1 ScT^S ! 00 29150
#14
Anthracene
Concen: 1.56 ng/uL
RT: 25.86 min Scan# 1937
Delta R.T. -0.01 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:178 Resp: 181984
Ion
178
176
0
0
Rat io
100
19.1
0.0
0.0
Lower Upper
10.0 29.9
0.0 0.0
0.0 0.0
ENGTFF5TD PES3. M
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion; 212
Exp Ratio
100
27.3
0.0
0.0
0C00120
"Win "Or F ttj—...__ —-ppni
I IWilp W Vw hat Jtm U JU t -mf • mjf X
HP 5989B
Page 9
-------
Abundance
150000
100000
50000
0
Time-->
TIC: ENG1665.D
28.60
28.80
Abundance Ion 202.00 (201.70 to 202.70)
lion 101.00 (100.70 to 101.70)
28.72
100000 -
50000 -
w
ENG
0
Time-->
#16
Fluoranthene(CCC)
Concen: 1.40 ng/uL
RT: 28.72 min Scan# 2375
Delta R.T. -0.01 min
Lab File: SNG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:202 Resp: 258097
Ion Ratio Lower Upper
202
100
101
25 .6
12 .1
36.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1665.D
200000
150000
100000
50000
Time-->
-i—I—|—! 1 1 1—T r-~l 1 f 1 1 1 ! 1 ! 1 1 ? !—r~
28 .50 29.00 29.50 30.00
Time - ->
I " i i' ' l—I—i—J—!—|—f—r—i—i—j—i—!—i—i—|—i—f—i—r*
28.50 29.00 29.50 30.00
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion; 212
Exp Ratio
100
31.6
0.0
0 »0
(AbundanceIon 212.00 (211.70 to 212.70) : ENG
|Ion 106.00 (105.70 to 106.70): ENG
20000
15000
10000
5000
0
ENG1665.D—PES3.M
0C031
O-l
Hon OCt 18 15:15:36 1999
HP 5989B
Page 10
-------
Abundance
200000
150000
100000
50000
TIC: ENGlbbb.D
29.20
29.40
AbundanceIon 202.00 (201.70 to 202.70): ENG
150000
100000
50000
Ion 101.00 (100.70 to 101.70): ENG
29.33
0
Time-->
~r 1 j—'T- 1 1 1 1 r
29.20 29.40
#18
Pyrene
Concern: 1.39 ng/uL
RT: 29.33 min Scan# 2466
Delta R.T. -0.01 min
Lab Pile: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:202 Resp: 285608
Ion Ratio Lower Upper
202
100
101
29.0
13 .9
41.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
abundance
200000
150000
100000
50000
Time-
TIC: ENG1665.D
#19
p-Terphenyl-dl4
Concen; 2.59 ng/uL
RT: 29.62 min Scan# 2509
Delta R.T. -0.00 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:244 Resp: 320255
—i—'
29.40
2 9 i 6 0
i 1 j r
29.80
Ratio
100
32.1
0.0
0.0
Lower Upper
14.6
0.0
0.0
43.7
0.0
0.0
AbundanceIon 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122 .70) : ENG
150000 J 29.62
100000
50000
Time-
29 .40
29.60
29.80
ENG1665.D PES3.M
0CC0122
Mon Oct 18 15:15:39 1999
HP 5989B
Page 11
-------
Abundance
80000
TIC: ENGI665.D
60000
40000
20000
Time--> * 32150 33100 33150 34100
Abundance Ion 240.00 (235.70 to 240.70): SNG
Ion 120.00 (119.70 to 120.70): ENG
33100 33150
4000
2000
[Time-
-i—r*"!—p""1—r
32.50
! 1 1 1 1 ! ! j 1 1
33.00 33.50
34 1 00
#20
Benzo(a)anthracene-dl2
Concen; 0.00 ng/uL
Expected RT: 33.36 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 240
Exp Ratio
100
27 .9
0.0
0.0
[Abundance
80000 :
TIC: ENG1665.D
60000 .
A / \
40000:
\
20000:
J VA
o:
Time-->
33.30 33.40 33.50
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
60000 -
33.45 f\
40000
A 1*
20000
0 -
Time-->
\ } 1 1 i i i I t 1 i i I 1 ! i 1 f
33.30 33140 33.50
#21
Benzo(a)anthracene
Concen: 1.62 ng/uL
RT: 33.45 min Scan# 3084
Delta R.T. -0.01 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:228 Resp: 154000
Ion Ratio Lower Upper
228
100
114
26.6
12.8
38.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC3123
HP 5989B
Page 12
-------
Abundance
80000
Time-
TlC: ENGlfabS.D
60000
40000
20000
-i—r—s—!—|—i—r
¦> 32:50 33.00
'"I 1 '
33 .50
34.00 34.50
Abundance Ion 240.00 (239.70 to 240.70): ENG
oUUUiion 120.00 (119.70 to 120.70): ENG
4000
2000
0
! I I 1
i—i—I—r
Time--> 32.50 33100 33150 34100 34150
Abundance
80000 .
60000
40000
20000
0
TIC: ENG1SS5.D
n 1 r r r
33.40
1 ! ! J ! 1 1 1 V
33.60 33.80
Txme-->
Abundancelon 228.00 (227.70 to 228.70)
Ion 114.00 (113.70 to 114.70)
33.60
60000
40000
20000
Time-->
33 .40
i i f T
33.60
33 .80
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.50 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pro
Tgt Ion: 240
Exp Ratio
100
27.3
0.0
0.0
#23
Chrysene(CCC)
Concen: 1.48 ng/uli
RT: 33.60 min Scan# 3107
Delta R.T. -0.01 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion;228 Resp: 202222
Ion Ratio
228 100
24.5
Lower Upper
114
0
0
0.0
0.0
11.2
0.0
0.0
33.5
0.0
0.0
"iwr
ENG
0003124
ENGTfebbID—FES3TW
Moii Oct ia ib :ib :4b iyyy
HP 5989B
Page 13
-------
[Abundance
60000
40000
20000
TIC: ENG1665.D
t—r—t—I—i—i—s—r—r—i—i i i i—i—i—!—i—i i r i—i—i
38.50 39.00 39.50 40.00
Time-->
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
6000
4000
2000
Time-
1—i—r "" j'—r—i
38 .50
39.00 39.50
~1 1 1 ! 1 1 1
40.00
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:
Ion
264
132
0
0
264
Exp Ratio
100
69.4
0.0
0.0
Abundance
TIC: ENG1665.
D
60000 .
40000 -
20000 -
0
Time--> 39.30 39.40 39.50 39.60
Abundance Ion 252.00 (251.70 to 252.70) : ENG
Ion 126.00 (125.70 to 126.70): ENG
39.50
40000 -
20000 -
0 -
| 1 i i I [ I I t I [ 1 1 1 ! t I ! ! 1 | 1
Time--> 39.30 39.40 39.50 39.60
#25
Benzo(b)fluoranthene
Concen: 2.00 ng/uL
RT: 39.50 min Scan# 4014
Delta R.T. -0.02 min
Lab Fil©: ENG166 5.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:252 Resp: 193580
Ion Ratio Lower Upper
252
100
126
28.3
14.0
41.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG1665.D PES3.M
\ Yt Of
Mon Oct 18 15:15:4y 1999
HP 5989B
Page 14
-------
Abundance
60000
40000 j
TIC: ENG1665.D
20000
t—i—i—r—|—i—i—i—i—j—[—i—i—i—j—i—i—i—r
Time--> 38150 39.00 39.50 40.00 40)50
Abundance Ion 264.00 (253.70 to 264.705: ENG
Ion 132.00 (131.70 to 132.70): ENG
6000
4000
2000 J
—|—i—i—i—i—]—i—i—i—r—i—i—i—i—i—|—i—i—i—i—|—i—r
frime - -> 38.50 39.00 39 .50 40100 40)50
#26
Benzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.53 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 35.8
0 0.0
0 0.0
Abundance
TIC
: ENGlfabS
.D
60000 .
40000 .
20000 -
0 ,
Time-->
39!
40 39.60
39! 80
AbundanceIon
252.00 (251.70 to
252.70):
Ion
126.00 (125.70 to
126.70) :
ENG
40000 -
39.65
20000 -
0 .
Time-->
1
39.
40 39.60
i | i i
39.80
i
#27
Benzo(k)fluoranthene
Concen: 2.33 ng/uL
RT: 39.65 min Scan# 4036
Delta R.T. -0.02 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:252 Resp: 166256
Ion
252
126
0
0
Ratio
100
30.3
0.0
0.0
Lower Upper
13 .9
0.0
0.0
41.5
0.0
0 .0
occurs
HP 5989B
Page 15
-------
Sundance
30000
20000 -
10000
i—|—i—i—i—i—[—i—i—i—i—|—i—i—i—i—|—i—'—r~i—I—i—i—r~
fTime--> 40.50 41.00 41.50 42.00 42.50
TIC: ENGlSbS,D
Abundance Ion 264.00 (263.70 to 254.70): ENG
Ion 132.00 (131.70 to 132.70) : ENG
6000
4000
2000
!' t—r—T—I 1 1 ! 1 1 1 r-T 1 f I I I I ! I I 1
fTime--> 40150 41100 4ll50 42100 42:50
Abundance
30000
20000
10000 J
TIC; ENG1665.D
Time — > 41.60 41.80 42.00
Abundance Ion 252.00 (251.70 to 252.70):
Ion 126.00 (125.70 to 126.70):
41.78
20000
15000
10000
5000
Time-->
ENGlbfebID—PES3.M
1 41160
#28
Benzo(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 264
Exp Ratio
100
37.8
0.0
0.0
#29
Benzo(a)pyrene(CCC)
Concen: 2.02 ng/uL
RT: 41.78 min Scan# 4363
Delta R.T. -0.01 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:252 Resp: 94797
Ion Ratio Lower Upper
252
100
126
29.6
15.7
46.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG
OCOOi*
4i;eo~1" 42.00
won uct la ib:ib:bb xyyy
HP 5989B
*17
1
Page 16
-------
TIC; EfJGl6 6 5.D
¦¦ 1 " '""
Abundance
30000 J
20000 -
10000 -
Time-->
abundance Ion 288.00 (287.70 to 288.70): ENG
52 .00
53.00
54 .00
2000 _
1000 -
Time-->
52.00
53 .00
54.00
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0,00 ng/uL
Expected RT: 52.54 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 2 88
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Abundance
TIC: ENG1SS5.D
30000 :
A
20000;
J V
10000 J
0 .
Time - - >
52.40 52.60 52.80 53.00 53.20
Abundance Ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
52 .79
10000 -
A
5000 -
0 .
i
Time-->
52.40 52.60 52.80 53.00 53.20
#31
Indeno(1,2,3-cd)pyrene
Concen: 1.81 ng/uL
RT: 52.79 min Scan# 6072
Delta R.T. -0.03 min
Lab File: SNG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:276.05 Resp:
85553
Ion
276
138
0
0
Ratio
100
40.1
0.0
0.0
Lower Upper
30.1
0.0
0.0
90.2
0.0
0.0
0C03123
HP 59891
Page 17
-------
Abundance
30000
20000
10000
0
Time-->
mwy\ -i cc g—f\
TIC: ENGlooS.D
52,00
53 .00
Abundance Ion 292.00 (251.70 to 292.70): ENG
2000 -
1000
t*" 1 r-
n i 1 r
Time-->
52.00
53 .00
Abundance
30000
20000
10000
Time--> 52.40
T i 1 i III i i j i i t r j 1 1 ! ! r
52.60 52.80 53.00 53.20
J"
5000
0
:irae--> 52.40
ENG1665.D PES3.M
#32
Dibenz (a, h) anthracene-dl4
Concent 0.00 ng/uL
Expected RT: 52.50 min
Lab File; ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 292
Ion
292
0
0
0
Exp Ratio
100
0.0
0.0
0.0
TIC: ENGlb65 .D
#33
Dibenz(a,h)anthracene
Concen: 1.87 ng/uL
RT: 52.82 min Scan# 6077
Delta R.T. -0.04 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:278 Resp: 76191
Ion Ratio Lower Upper
278 100
139 16.1 26.9 80.5#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
[AbundanceIon 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
10000 52.82
0CC1S
i i | ? t 5—j [ 1 t"" i "p i \—i r—"t rT—r"
52.60 52.80 53100 53.20 |
Mon OCt 18 15:16:02 1999
HP 5989B
*>3
Page 18
-------
TIC: ENGlSSb.D
Abundance
15000
10000 -
5000 -
Time - - >
Abundance Ion 288.00 (2S7.70 to 288.70): ENS
55.00
56.00
2000
1000 -
Time - - >
55.00
56.00
#34
Benzo(g,h,i)perylene-dl2
Concen: 0.00 ng/uL
Expected RT: 55.52 min
Lab Pile: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Abundance
15000 :
10000
5000
0
Time-->
TIC:ENGlbbbTD
i " """ i r
55.50
561 00'
Abundance ton 275'. 00 (273'. 70 to 276.70)
Ion 138.00 (137.70 to 138.70): ENG
10000 55.80
5000
Time-->
55.50
56;00
ENG1665.D—PES3 ,M
#35
Benzo(g,ta,i)perylene
Concen: 1.69 ng/uL m
RT; 55.80 min Scan# 6660
Delta R.T. -0.04 min
Lab File: ENG1665.D
Acq: 15 Oct 99 5:06 pm
Tgt Ion:276 Resp: 87299
Ion Ratio Lower Upper
276 100
138 51.6 6.5 26.0#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0C03120
Mon Oct 18 15:16:05 1999
HP 59891
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\ENG16 6 7.D
15 Oct 99 7:19 pm
CARB4 2 9,MDL6
Oct 18 15:17 1999
: C:\HPCHEM\1\METHODS\PES 3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
8
HP 5989B
1. 00
Internal Standards
R.T.
Qlon
Response
Cone Units Dev(Min)
l)
2,2-Difluorobiphenyl
20.00
190
503421
5.00 ng/uL
0.00
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00 ng/uL
0 .00%
4)
2-Methlynaphthalene-dlO
19.37
152
295310
2.99 ng/uL
74.68%
5)
Acenaphthylene-d8
0.00
160
0
0 .00 ng/uL
0.00%
7)
Acenaphthene-dl0
0.00
164
0
0.00 ng/uL
0.00%
9)
Fluorene-dlO
0.00
176
0
0.00 ng/uL
0.00%
11)
DhananhVirtfuiOi-Hl H
Jet XicilCUii IbiXIJL >S»X JLG! U X w
0.00
188
0
0.00 ng/uL
0.00%
13)
Anthracene¦dl0
0.00
188
0
0.00 ng/uL
0.00%
15)
Fluoranthene-dlO
0.00
212
0
0.00 ng/uL
0.00%
17)
Pyrene-dlO
0.00
212
0
0.00 ng/uL
0.00%
19)
p-Terpheny1-d14
29.62
244
338007
3.45 ng/uL
86.14%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00 ng/uL
0.00%
22)
Chrysene-dl2
0.00
240
0
0.00 ng/uL
0.00%
24)
Benzo(b)fluoranthene~dl2
0.00
264
0
0.00 ng/uL
0.00%
26)
Benzo(k)fluoranthene-dl2
0 .00
264
0
0 .00 ng/uL
0.00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00 ng/uL
0 .00%
30)
Indeno(1,2,3-cd)pyrene-dl2
0.00
288
0
0.00 ng/uL
0 .00%
32)
Dibenz(a, h)anthracene-dl4
0.00
292
0
0.00 ng/uL
0.00%
34)
Benzo(g,h,i)perylene-dl2
0.00
288
0
0.00 ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.73
128
557050
1.72 ng/uL
99
6)
Acenaphthylene
21.66
152
216905
1.98 ng/uL
100
8)
Acenaphthene(CCC)
22.11
154
181280
1.89 ng/uL
98
10)
Fluorene
23.38
166
193864
1.95 ng/uL
97
12)
Phenanthrene
25 .73
178
295132
1.96 ng/uL
99
14)
Anthracene
' 25.86
178
220582
2.39 ng/uL
98
16)
Fluoranthene(CCC)
28.72
202
285183
1.95 ng/uL
97
18)
Pyrene
29.33
202
312226
1.92 ng/uL
97
21)
Benzo(a)anthracene
33.45
228
157849
2 .10 ng/uL
98
23)
Chrysene(CCC)
33.60
228
209970
1.94 ng/uL
96
25)
Benzo(b)fluoranthene
39 .50
252
176392
2 .31 ng/uL
99
27)
Benzo(k)fluoranthene
39.65
252
132255
2.34 ng/uL
93
29)
Benzo(a)pyrene(CCC)
41.77
252
90478
2 .43 ng/uL
96
31)
Indeno(1,2,3-cd)pyrene
52.78
276
81084
2.16 ng/uL
72
33)
Dibenz(a,h)anthracene
52 .83
278
71332
2.21 ng/uL
67
35)
Benzo(g,h,i)perylene
55.79
276
81932
2.00 ng/uL#
54
OC03I31
(#5 = qualifier out of range (m) = manual integration
ENG1667.D PES3.M Mon Oct 18 15:19:48 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File ; C:\HPCHEM\l\DATA\ENG1667.D
Acq On : 15 Oct 99 7:19 pm
Sample ; CARB429,MDL6
Misc :
Quant Time: Oct 18 15:17 1999
Vial
Operator
Inst
Multiplr
8
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Abundance
350000
300000
250000
200000
150000
100000
50000
0
-
4s
u
TIC: ENG1667.D
19S
~ 1$
8 12
16
14
—lLt
25
27
29
U
32
35
Time - - >
' I '1 1 'I 1 ! T 1 I ' » ' » ? » i i i [ >iii| l 1 1 1 ] 1 1 I I j |
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0C03I32
ENG1667,D PES3.M
Mon Oct 18 15:19:54 1999
HP 5989B Page 2
-------
Abundance
TIC: ENG1667.D
300000
200000.
100000
0 -
. . A
I
—I—l > 1 ? 1 '!" 1 1 1"" 1 f "T"
Time-->16^50 17.00 17,50 18.00 18.50
abundance Ion 136.00 (135.70 to 136.70}: ENS
Ion 68.00 (67.70 to 68.70): ENG16
4000
2000
—i—i—i—i—i—i—i—i—i—r—i—i—i—i—i—i—i—i—i—r—i—s—i—r~
Time- - > 16 1 5 0 17.00 17.50 18.00 18.50
Abundance
300000
200000 j
100000 -
TIC: ENG1667.0
Time--> 17.60 17:80
Abundance Ion 128.00 (127.70 to 128.70)
300000
200000
100000
0
]Ion 127.00 (126.70 to 127.70)
17.73
Time - - >
ENG1667.D PES3.M
i 1 1 j r
17160
"j 1 1 1 1-
17.80
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 17.69 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 136
Ion
136
68
0
0
Exp Ratio
100
15.3
0.0
0.0
#3
Naphthalene(CCC)
Concen: 1.72 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.01 min
Lab Pile: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:128 Resp: 557050
Ion Ratio Lower Upper
T
"Emr
ENG
128
100
127
12,6
0.0
63.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
OCCJi
Mon Oct 18 15:19:58 1999
HP 5989B
Page 3
-------
Abundance
150000
100000
TIC: ENG1667.D
50000
Time--> 19.30 19140
Abundance Ion 152.00 (151.70 to 132.75}: ENG
150000
100000
50000
19.37
Tirae-
Aburidahce
150000
100000
50000
f—i—i—j—[—\—i—i—f—|—i—i—»—J—j—j—r
Time--> 20150 21.00 21.50 22.00 22150
AbundanceIon 160.00 (159.70 to 160.70): ENG
2000
1000
jri
,ime--> 20150 21100
ENG1667.D—PSS3.M
-1—!—i—r-
#4
2-Methlynaphthalene-dlO
Concen: 2.99 ng/uL
RT: 19.37 min Scan# 759
Delta R.T. -0.00 min
Lab File; ENG1667.D
Acq: 15 Oct 99 7:19 pra
Tgt Ion:152 Resp: 295310
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
I , ——i 1
19130
19.40
TIC: ENG1667.D
21.50 22.00 22150
Mon Oct IB lb:2U;Ul 1999
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT; 21.63 min
Lab File; 1NG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 160
Ion Exp Ratio
100
0.0
0.0
0.0
0CCji24
HP S989B
Page 4
-------
jSbundance
100000
50000
Time-
TItmUGl66?.D
r—1—i—I r i r
21,60
I 1 1 1
21.50
21.70 21.80
[AbundanceIon 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
21.66
100000
50000 .
i—i—i—i—|—r—i—i—i—i—r—i—i—|—i—i—i—i—j—r—i
Time--> 21.50 21.60 21.70 21,80
Abundance
150000
100000
50000
-?—i—i—I—|—I—r—t-
21:00 21:50 22:00 '22!50* 23loo'
2000
1000
Time-
1 I 1 r
21.00
1—!—|—1—«—1—r—\—!—»—\—1—i—1—1—e—1—j—1—r
21.50 22.00 22 150 23.00
#6
Acenaphthyiene
Concent 1.98 ng/uL
RT; 21,66 min Scan# 1302
Delta R.T. -0.01 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion-. 152 Resp: 216905
Lower Upper
Ion
152
153
0
0
Ratxo
100
13 .1
0.0
0.0
6.6
0.0
0.0
19.6
0.0
0.0
TIC: ENG1667.D
Time-->
Abundance Ion 164.00 (163.70 to 164.70): ENG
#7
Acenaphthene-dlO
Concen: 0.00 ng/uL
Expected RT; 22.04 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 164
Ion Exp Ratio
100
0.0
0.0
0.0
ENG1667.D PES3.M
« 35
TTorTTTct 18 15:20:04 lyyy
HP 5989B
Page 5
-------
Abundance
150000
100000
50000
0
Time-->
TIC: ENGlbbV. D
-i 1 1 1 r
22.00
, , j , p.
22 :10 22.20
AbundanceIon 154.00 (1§3.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70) : ENG
22 .11
100000 .
50000
i 1 j s ! 1 1 1 1 r—i r r—nr—r—~i—-r
Time--> 22.00 22.10 22.20
#8
Acenaphthene(CCC)
Concen: 1.89 ng/uL
RT: 22.11 min Scan# 1370
Delta R.T. -0.01 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:154 Resp: 181280
Ion Ratio Lower Upper
154 100
153 96.1 49.1 147.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
/ n T)
150000
100000
Time-
50000
T 1 1—J ['" > I I ! [" I'" 1 I 1' I ' ) I
22.50 23.00 23.50 24i00
r ¦ i m ii- hi ii hi Ijpy—
Abundance Ion 176.00 (175.70 to 176.70): ENG
2000
1000
Time-->
_i—r~T—r-
22.50 23.00 23.50
1 1 [ 1 1 1 1 1-
24 .00
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 176
Exp Ratio
100
0.0
0.0
0.0
occoias
ENG1667.D P1S3.M
"Mon Oct 18 15:20:07 1999
HP 5989B
Page €
-------
TIC: ENG1667,D
150000
100000
Time-
50000
i—I—i—i—r—i—r~
23.20 23:30
t—r~
23140
H 1 1 I ! 1—r-
23.50
Abundance Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
_ „ 23.38
100000
50000
0 }
Time-->
1 r—i [ r-'T I 1 1 1 J*—-!—I p-l J—! 1—\—!—f
23.20 23.30 23.40 23.50
SB
undance
150000
100000
50000
T ! ! 1 1 f 1 1 ! 1 1 5 1 1 r—1 1 1 * f 1 1—r
(Time--> 24150 25.00 25.50 26.00 26.50
Abundance Ion
3000
2000
1000
188.00 (187.70 to 186.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
Time--> 24.50
-1—I—} I I—I—!—1 ! ! !—'—1—I—r—T—I—r—'1—1—T
25100 25.50 26.00 26150
#10
Pluorene
Concen: 1.95 ng/uL
RT: 23.38 min Scan# 1561
Delta R.T. -0.00 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:166 Resp: 193864
Ion Ratio
166 100
165 88.9
0 0.0
0 0.0
Lower Upper
45.7
0.0
0.0
137.0
0.0
0.0
TIC: EHG1667.D
#11
Phenanthrene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1667 .D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 188
Exp Ratio
100
24 . 5
0.0
0.0
ENG1667.D PES3.M
0C05137
Mon Oct 18 15:20:10 1999
HP 5989B
Page 7
-------
Abundance
150000
100000 :
50000
Time-
TIC: ENG1667.D
-i ] r~
25.60
25.70
25.80
Sundance ion 178.oo (177.70 to 178.70): eng
Ion 176.00 (175.70 to 176.70): ENG
25 73
150000 J
100000
50000
1 [ I 1 1 1 T 1 1 ! 1 1 1 ! 1 1 !
fTime--> 25.60 25.70 25.80
#12
Phenanthrene
Concen: 1.96 ng/uL
RT: 25.73 min Scan# 1918
Delta R.T. -0.01 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 178 Resp-. 295132
Ion Ratio Lower Upper
178
100
176
19 .7
10 .2
30.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: EnGISS".D
150000
100000
50000
Time
-7 1 1 1 1 1 1 1 1 1 1 1 1 1 1"
25;00 25150 26.00 26.50
3000
2000
1000 -
Time-->
ENG1667.D
t—i—i—i—r—i—i—i—i—|—i—r
25.00 25.50
PES3.M
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab Pile: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 188
Exp Ratio
100
26 .6
0.0
0.0
(AbundanceIon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
j ( 1 J J * f J 1 1 p
26.00 26.50
Mon OCt 18 15:20:14 1999
0CG3i23
HP 5989B
Page 8
-------
Abundance
150000 :
100000
50000
Time--> 25.70
TIC: EMGlbb"7D
25.80
25.90
26.00
—4 p»fl—JPTT"! 7'«i" f'*f—wA ' "—+TB—*9A 1 WVf/q
abundance IOIl 178.00 {177.70 to 178.70); ENG
Jlon 176.00 (175.70 to 176.70); ENG
150000
100000
50000
25.86
Time--> 25.70
25.80
25.90
26.00
#14
Anthracene
Concen: 2.39 ng/uL
RT: 25 . 86 min Scan# 1938
Delta R.T. -0.01 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:178 Resp: 220582
Ion Ratio Lower Upper
178
100
176
19.1
10.0
29.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
150000
100000 .
50000
—i—!—i—!—|—i—i—!—i—|—i—s—r—f—e—i—r—i—i—[—i—i—!—r
tTime--> 27 i50 28.00 28.50 29.00 29.50
TIC: ENG1667.D
0
Time- - > 27 i 50 28 I 00' '2JB ! 50' 29 ! do' '29 150*
#15
Fluoranthene-dl0
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 212
Exp Ratio
100
27.3
0.0
0.0
Abundance Ion 212.00 (211.70 to 212.70): ENG
•Ion 106.00 (105.70 to 106.70): ENG
20000.
15000
10000
5000
0CC3139
ENGTW7TD—PES3.M
Mon Oct 18 15:20:17 1999
HP 5989B
Page 9
-------
Abundance
150000
100000 -
50000
TIC; ENGlbb".D
Time-
28.60
28,80
Abundance Ion 202.00 (201.70 to 202.70); 2NG
150000
100000
50000
Ion 101.00 (100.70 to 101.70): ENG
28 .72
Time - - >
28.60
28.80
#16
Fluoranthene(CCC)
Concen: 1.95 ng/uL
RT; 28.72 min Scan# 2377
Delta R.T. -0.00 ttiin
Lab File: ENG1667.D
Acq; 15 Oct 99 7:19 pm
Tgt ion:202 Resp: 285183
Ion Ratio Lower Upper
202
100
101
25 .5
12.1
36.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENC1667.D
200000
150000
100000
50000
i—\—i—i—f—{—i—i—i—f—i—i—i—i—|—i—i—i—i—r—!—I—r—r-
Time- - > 28.50 29.00 29.50 30.00
Abundance Ion 212.00 (211.70 to 212.70) ; BNG
Ion 106.00 (105.70 to 106.70): BNG
20000
15000 :
10000
5000
0
Time-->
T 1 , p—| 1 , 1 , j , 1 , 1 1 1 , , , 1 , 1 r
28.50 29.00 29.50 30.00
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 212
Exp Ratio
100
31.6
0.0
0.0
1KGXF67TD—PES 3 .M
Mon Oct 18 15:20:20 1999
QCG JMD
HP 5989B Page 10
-------
Abundance
200000
150000
100000
50000 4
TIC: ENG1667.D
Time-->
i t ¦¦¦¦¦ r"
29.20
29.40
"i r r~
AbundanceIon 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
29 .33
150000
100000
50000
0
Time-->
~i 1 r 1 1 \ ! 1 r— r-—i-
29120 29.40
#18
Pyrene
Concen: 1.92 ng/uL
RT: 29.33 rain Scan# 2467
Delta R.T. -0.01 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:202
Ion Ratio
202 100
101 29.3
0 0.0
0 0.0
Resp: 312226
Lower Upper
13.9 41.5
0.0 0.0
0.0 0.0
TIC: ENG1667.D
Abundance
200000
150000
100000
50000
#19
p-Terphenyl-dl4
Concen: 3.45 ng/uL
RT: 29.62 min Scan# 2511
Delta R.T. -0.00 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:244 Resp: 338007
Ion Ratio Lower Upper
—1—r
29 .40
i 1 r
29.60
-i i i p
29'80
Time-->
Abundance Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
29.62
150000
100000
244
100
122
32.7
14.6
43 .7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
50000 J
Time--> 29.40
ENG1667.D PES3.M
0C03141
29! 60 "" 29180
Mon Oct IB lb : 20 :23 1999"
HP 5989B
Page 11
-------
(Abundance
80000
60000
40000
20000
0
TIC: ENG1667.D
i—i—I—i—i—i—i—j—i—i—i—r-
33.50 34.00
i—r—i—jiii—i—|—i—
[Time--? 32.50 33 100
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
4000
2000
Time-
Abundance"
80000
60000
40000:
20000
i—i—j—i—i—i—i—[—i—i—r "'T—|—1—i—i—!—| i i"""i—r
32.50 33.00 33.50 34100
TIC: ENG1667.D
n—j—i—t—r—i—I—r—i—i—i—|—r—i—i—i—i—i—
rime--> 33.30 33.40 33.50 33.60
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70)
60000
33.45
40000
20000
ENG.
-i 1 1 1 1 1 1 1 1 r
33130 33.40 33.50 33160
lori Oct
#20
Benzo(a)anthracene-dl2
Concern 0.00 ng/uL
Expected RT: 33.36 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 240
Ion
240
120
0
0
Exp Ratio
100
27 .9
0.0
0.0
#21
Benzo(a)anthracene
Concen: 2.10 ng/uL
RT: 33.45 min Scan# 3086
Delta R.T. -0.01 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:228 Resp: 157849
Ion Ratio Lower Upper
228
100
114
26.4
12 .8
38.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
OCC0112
HP 5989B
Page 12
-------
Abundance
80000
60000
40000
20000
0
Time--> 32150 33.00 33150 34100 34.50
Abundance Ion 240.00 (239.70 to 240.70): ENO
Ion 120.00 (119.70 to 120.70): ENG
TIC; ENGlbfa?.D
4000
2000 .
Time--> 32 150 ' 33 ! 00' 33 ! S0 '34 ! 00' 3*4 ! 50'
#22
Chrysene-dl2
Coneen: 0.00 ng/uL
Expected RT; 33.50 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.3
0 0.0
0 0.0
Abundance
l
80000
60000:
40000
20000:
TIC: ENG1667.D
Time-->
-i 1 p j i r~
33.40
33 .60
-i 1 1 1 ! r
33.80
[AbundanceIon 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70)
33.60
60000
40000
20000
0
#23
Chrysene(CCC)
Concen: 1.94 ng/uL
ET: 33.60 min Scan# 3109
Delta R.T. -0.01 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:228 Resp: 209970
Ion Ratio Lower Upper
228 100
114 24.0 11.2 33 .5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0003113
Time-
-1 1 T
33140
~i 1 1 1 1 1 1 \ 1 r
33.60 33.80
ENG1667 . D—FE5T7H"
Mon Oct 18 15:20:30 1999
tl"D CQDQP
Jtl J» D mf O mr £3
Page 13
-------
Abundance
40000
TTCT~~£NG 15 o 7 . D
20000
0
r i—i—r~
-t—i—i—r
Time- - > 38150 39!00 39.50 40.00
Abundance Ion 254.00 (253.70 to 264.70): ENG
Ion. 132 .00 - (131 .70 to 132 .70) : ENG
6000
4000
2000 .
Time-
-i—i 1 'i ;—r—i—i—!—|—r-1—i—i—|—i—i—i—i—r—i—i—i—r
38.50 39.00 39.50 40.00
20000
Time-->39.30
¦¦¦¦ ¦ —¦—— »—¦——¦» ¦ i i «"»i i
Abundance Ion 252.00
Ion 126.00
40000
30000
20000
10000
Time-->39.30
ENG1667.D—FE53TW
—|—,—
39.40
—i—|—]—|—|—t—|—|—r
39.50 39160
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 69.4
0 0.0
0 0.0
TIC: ENG1MT7B
40000
!—i—i 1—r
39.50
I ! I I
39.60
39.40
#25
Benzo(b)fluoranthene
Concen: 2.31 ng/uL
RT: 39.50 min Scan# 4016
Delta R.T. -0.01 min
Lab Pile: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion-.252 Resp: 176392
Ion Ratio Lower Upper
252
100
126
27.3
14.0
41.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
i » » j mj\ A'\" ' ' PVM1
(251.70 to 252 . 70) : ENG
(125.70 to 126.70): ENG
39.50
0C051M
"Ron Oct 18 lb:20:JJ 199?
HP 5989B
Page 14
-------
TIC: EUG1667.D
Abundance
40000 -
20000
Time--> 38.50 39.00 39.50 40.00 40.50
"a tT"—K/i 1 -m a / m j* i" ¦ m'm. ' "X1.-. *S y* A *f7ST '
Abundance Ion 264.00 (263.70 to 264.70}:
6000 -|i0n 132.00 {131.70 to 132.70):
4000
2000
#26
Benzo(k)fluoranthene-dl2
Concern 0.00 ng/uL
Expected RT: 39.53 min
Lab File: ENGl667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 35.8
0 0.0
0 0.0
n—|—i—i—i—i—|—i—i—i—i—I—i—i—i—i—|—i—i—i—i—|—i—r
frime- - > 38.50 39.00 39.50 40.00 40.50
TIC: ENGlbb".D
40000
20000
Time - - > 39.40
I ' 1 r-
39.60
39.80
Abundance Ion 252.00
Ion 126.00
40000
30000
20000
10000
fTime--> 39.40
ENGl667.D PES3.M
39.60
39.80
#27
Benzo (k) fluoranthene
Concen: 2.34 ng/uL
RT: 39.65 min Scan# 4038
Delta R.T. -0.02 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:252 Resp: 132255
(251.70 to 252.70): EMG
(125.70 to 126.70): 1NG
Mon Oct 18 15:20:36 1999
Ratio
100
31.2
0.0
0.0
Lower Upper
13.9
0.0
0.0
41.5
0.0
0.0
000111
'W* J3 •JLw a
HP 5989B
•jfciJ
Page 15
-------
[Abundance
I
30000
20000
10000 J
Time--> 40.50 41.00 41.50 42.00 42.50
TIC: ENG16677D
Abundance Ion 264.00 {263.70 to 264.70); ENG
6000Jlon 132.00 (131.70 to 132.70): ENG
4000
2000
i—i—i—i—i—i—]—i—i—i—i—i—i—i—i—i—|—i—rn—f—r—i—i—r~
frime--> 40.50 4l!00 41.50 42.00 42.50
#28
Benzo(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 41.'61 min
Lab File; ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 37.8
0 0.0
0 0.0
Abundance
30000
20000
10000
Time-
TIC: ENGlbfa".D
#29
Benzo(a)pyrene(CCC)
Concen: 2.43 ng/uL
RT: 41.77 min Scan# 4364
Delta R.T. -0.02 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:252 Resp: 90478
41.40
4i: 60 4i:so 42:00
Ratio
100
29.1
0.0
0.0
Lower Upper
15.7
0.0
0.0
46.9
0.0
0.0
Abundance Ion 252.00 (251.70 to 252.70): ENG
20000
15000
lion 126 .00
(125.70 to 126.70); ENG
41.77
10000
5000
Titne-->
]—1—1—r—n—|—i—r—1—r 1 "j i i 1 1 1 > 1 1
41140 4i;60 41.80 42.00
ENGlfafeV .D—PES 3 .M
Mon Oct IB 15:20:40 1999
OCCOiiS
HP 5989B
Page 16
-------
Abundance
30000
20000
10000
TIC; EMG1667.D
52 .00
i 1 f—t 1 1 1 ! 1 1 r
53,00 54.00
Time-->
Abundance Ion 288.00 (287.70 to 288.70): ENG
2000
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 52.54 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion: 288
Exp Ratio
100
0.0
0.0
0.0
1000 -
i 1 s r
52.00
54.00
53 .00
Abundance
TIC: SMG1667.D
30000.
A
20000 -
J V
10000 -
0 .
Time-->
*52 ! 4o' *52 ! 60 52 1 SO *53 ! do' 53 ! 20*
Abundance Ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
10000 -
52.78
5000 -
0 .
j
Time-->
52.40 52.60 52.80 53.00 53.20
#31
Indeno(1,2,3-cd)pyrene
Concen: 2.16 ng/uL
RT: 52.78 min Scan# 6072
Delta R.T. -0.04 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:276.05 Resp: 81084
Ion Ratio Lower Upper
ENG1667 . D—FE5T7W
276
100
138
39.0
30.1
90.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0C0M17
Mon Oct 18 15:20:43 1999
HP 5989B
Page 17
-------
Abundance
30000
20000 .
TIC: ENG1667.D
10000
0
Time--> 52.00 53.00
AbundanceIon 292.00 (291.70 to 292.70]
"115"
2000 -
1000
Time-
52.00
53.00
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 52.50 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:
Ion
292
0
0
0
292
Exp Ratio
100
0.0
0.0
0,0
Abundance
TIC: EHG1667.D
30000 -
A
20000 .
J V
10000 -
0 '
Time--> 52!40 52 i 60 ' '52 180 53!00' 53 . 20
Abundance Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 {138.70 to 139.70): ENG
10000 _
52.83
5000 .
0 .
J 1 1 1 < j t ! 1 ! I 1 I ) I | I I I t j 1 I
Time-~> 52.40 52.60 52.80 53.00 53.20
#33
Dibenz(a, h)anthracene
Concen: 2.21 ng/uL
RT: 52.83 min Scan# 6080
Delta R.T. -0.04 min
Lab Pile: ENG1667 .D
Acq: 15 Oct 99 7:19 pm
Tgt Ion:278 Resp: 71332
Ion Ratio Lower Upper
278
100
139
30.1
26.9
80.5
0
0.0
0.0
0,0
0
0.0
0.0
0.0
AAA '.'S .1 T)
0CC JM3
HP 5989B
Page 18
-------
TIC: ENG1667.D
Abundance
15000
10000
5000 -
56.00
Time-->
Abundance Ion 288.00 (287.70 to 288.70): ING
2000 -
1000
55.00
56.00
#34
Benzo(g,h,i)perylene-dl2
Concen: 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1667.D
Acq: 15 Oct 99 7:19 pra
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
Abundance
TIC: ENG1667,D
15000 -
A
10000 J
V. J V
5000 -
0 -
Time-->
t i 1 i 1 t i > t ! i ! i t i I i 1 j 1 t I ' i ! i )
55.40 55.60 55180 56 .00 56.20
Abundance Ion 276.00 (275.70 to 276 .70) : ENG
Ion 138.00 (137.70 to 138.70): ENG
10000 .
55.79
5000 -
./V
0 -
Time-->
i r i [ r ! i i j iii i { I 111] r J 1 1 J ! 1 1
55.40 55.60 55.80 56.00 56.20
#35
Benzo (g, h, Dperylene
Concen: 2.00 ng/uL
RT: 55.79 min Scan# 6660
Delta R.T. -0.05 min
Lab File: 1NG1667.D
Acq: 15 Oct 99 7:19 pm
Tgt
Ion
276
138
0
0
Ion:276
Ratio
100
35,6
0.0
0.0
Resp:
Lower
0.0
0.0
81932
Upper
26.0#
0.0
0.0
31/
Mon Oct 18 15T2^jT5o—ijygg'
HP 5989B
Page 19
-------
Quantitation Report
C:\HPCHEM\1\DATA\ENG1S 6 8.D
15 Oct 99 8:25 pm
CARB429,MDL7
Data File
Acq On
Sample
Misc :
Quant Time: Oct 18 15:22 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Method : C:\HPCHEM\1\METHODS\PES3.M
Title :
Last Update : Man Oct 18 14:50:18 1999
Response via : Multiple Level Calibration
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.99
190
473975
5.00 ng/uL
i o
i o
1 o
System Monitoring Compounds
%Recovery
2}
Naphthalene-d8
0.00
136
0
0.00 ng/uL
0.00%
4)
2-Methlynaphthalene-dlO
19.36
152
243011
2.61 ng/uL
65.27%
5)
Acenaphthy1ene-d8
0.00
160
0
0.00 ng/uL
0.00%
7)
Acenaphthene-dlO
0.00
164
0
0.00 ng/uL
0.00%
9)
Fluorene-dlO
0.00
176
0
0.00 ng/uL
0 .00%
11)
Phenanthrene-d10
0.00
188
0
0.00 ng/uL
0.00%
13)
Anthracene-dlO
0.00
188
0
0.00 ng/uL
0.00%
15)
Fluoranthene-dlO
0.00
212
0
0.00 ng/uL
0.00%
17)
Pyrene-dlO
0.00
212
0
0.00 ng/uL
0.00%
19)
p-Terphenyl-dl4
29.61
244
287965
3.12 ng/uL
77.95%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00 ng/uL
0.00%
22)
Chrysene-dl2
0.00
240
0
0.00 ng/uL
0.00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0.00%
26)
Benzo(k)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0 .00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00 ng/uL
0 .00%
30)
Indeno(l,2, 3-cd)pyrene-dl2
0.00
288
0
0.00 ng/uL
0.00%
32)
Dibenz(a,h)anthracene-dl4
0.00
292
0
0.00 ng/uL
0.00%
34)
Benzo(g,h,i)perylene-dl2
0.00
288
0
0.00 ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.73
128
460954
1.51 ng/uL
99
6)
Acenaphthylene
21.66
152
173673
1.68 ng/uL
100
8)
Acenaphthene(CCC)
22.11
154
143698
1.59 ng/uL
96
10)
Fluorene
23 .37
166
163874
1.75 ng/uL
98
12)
Phenanthrene
25.73
178
255000
1.80 ng/uL
99
14)
Anthracene
25 .86
178
180574
2.08 ng/uL
99
16)
Fluoranthene(CCC)
28.72
202
244659
1.78 ng/uL
98
18)
Pyrene
29.32
202
266662
1.74 ng/uL
97
21)
Benzo(a)anthracene
33 .44
228
129460
1.83 ng/uL
98
23)
Chrysene(CCC)
33.59
228
176809
1.73 ng/uL
96
25)
Benzo(b)fluoranthene
39.49
252
122382
1.70 ng/uL
99
27)
Benzo(k)fluoranthene
39.64
252
98308
1.84 ng/uL
92
29)
Benzo(a)pyrene(CCC)
41.77
252
61164
1.75 ng/uL
99
31)
Indeno(1,2,3-cd)pyrene
52.76
276
69372
1.97 ng/uL#
21
33)
Dibenz(a,h)anthracene
52.80
278
62572
2.06 ng/uL
68
35)
Benzo(g,h,i)perylene
55.78
276
71688
1.86 ng/uL#
62
0600150
(#) - qualifier out of range (m) = manual integration
ENG1668.D PES3.M Mon Oct 18 15:24:14 1999 HP 5989B Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc :
Quant Time: Oct 18 15:22
C;\HPCHEM\1\DATA\BNG1668.D
15 Oct 99 8:25 pm
CARB4 2 9,MDL7
1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\M1TH0DS\P1S3.M
Mon Oct.18 14:50:18 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
TIC: ENG1668.D
Abundance
350000 h
300000 -
250000 -
19S
200000 -
111
10 12
16
150000 -
4s
100000 .
23
21
50000 -
29
35
TJ
Time-->
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
OCCjiui
ENG1668.D PBS3.M Mon Oct 18 15:24:20 1999 HP 5989B
Page 2
-------
TIC: EfTG165S .D
200000
100000 -
A
Time-
• >16150'
"i—r—i—r—i—f—i—i—i—|—t—i i ""I
17100 17.50 18.00 18150.
iAbundan.ceIon 13S.00 (135.70 to 136.70) : ENG
Ion 68.00 (67.70 to 68.70): ENG16
4000 -
2000
i 1 i—i—i—|—ri—i—i—r—i—i—i—i—r—i—i—i—i—1—i—i—i—r
fTime-->16l50 17.00 17.50 18.00 18.50
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 17.69 rain
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 136
Ion
136
68
0
0
Exp Ratio
100
15 .3
0.0
0.0
Abundance
200000
100000
TIC: ENG1668.D
rime - - >
n ! 1 1 1 r
17 .60
17 .80
T
Abundance Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
17.73
200000
100000
0
Time-->
-i—i—i—f
17.60
17180
#3
Naphthalene(CCC)
Concen: 1.51 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.01 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:128 Resp; 460954
Ion
128
127
0
0
ENG1668.D—FEST7M"
Mon Oct lb lb:24:24 lyyy
Ratio
100
12 .6
0.0
0.0
Lower Upper
0.0
0.0
0.0
63.0
0.0
0.0
0C0M.52
HP 5989B
Page 3
-------
Abundance
100000
50000
TIC: SNG1668.D
Time--> 19.30 19140
Ab^g^g^gelon 152.00 (151.70 to 152.70)
"EHS"
100000
50000
19 .36
_r r—7"- j-
Time-
19 .30
19.40
TIC: ENG16W1T)
100000
50000
0
Time--> 20. 50' 21'00 211 50' 22 100 22 150
Abundance Ion ISO.00 (159.70 to 160.70)
2000
EH5"
1000
i | i t i i j i i—i ""i i i i i i r—r i "¦ r" i r T"t
Time--> 20.50 21.00 21.50 22.00 22.50
#4
2-Methlynaphthalene-dlO
Concen: 2.61 ng/uL
RT: 19.36 min Scan# 758
Delta R.T. -0.01 min
Lab Pile; ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:152 Resp: 243011
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT: 21.63 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 160
Ion ixp Ratio
100
0.0
0.0
0.0
0003153
HP 5989B
Page 4
-------
Abundance
100000
TIC: ENG1668.D
50000
Time-
21150 21,60 2i;70
2i:80
100000
Ion 153.00
50000
0
Time-->
1—1—i—i—1—i—1 ( 1—|—!—1—r-
21.50 2i:60 21.70 21.80
#6
Acenaphthylene
Concen: 1.68 ng/uL
RT: 21.66 tnin Scan# 1302
Delta R.T. -0.01 rain
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pra
Tgt Ion:152 Resp: 173673
Ion
152
153
0
0
Abundance Ion 152.00 (151.70 to 152.70): 2m
; 152.70 to 153.70): 2NG
21.66
Ratio
100
13 .0
0.0
0.0
Lower Upper
6.6
0.0
0.0
19 .6
0.0
0.0
ENG1668.D
100000
50000
*1—i—1—i—i—1—1—j—1—1—i—1—|—1—1—1—1—r~*T"
Tirne--> 21.00 21.50 22.00 22.50 23:00
Abundance Ion 164.00 (163.70 to 164.70]
#7
Acenaphthene-dlO
Concen: 0.00 ng/uL
Expected RT: 22.04 rain
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 164
Exp Ratio
100
0.0
0.0
0.0
IMT
2000
1000
0
-'Ww^
Time-->
! 1 1 1 ! I 1 1 f 1"" 1 1 1 1' ¦ I 1 1 ! 1—1 ! 1 1 r
21.00 21.50 22.00 22.50 23.00
ENGT5OT7D—PES 3 .M
won uct is ib:24:iu iyyy
000)154
HP 5989B
Page
-------
1NG1668
100000
Time-->
50000
22.00
22.10
22 .20
Abundance Ion 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152 .70 to 153 .70) : ENG
80000: 22.11
60000
40000
20000
Time-->
22 .00
22:i0
22.20
Abundance
150000
100000
50000
T-H 1 1 ! P
22.50
T T I 1 1 ! J 1 \ 11 < J| 1 J ! I 1 T
23 .00 23.50 24!00
Time - - >
Abundance Ion 176.00 (175.70 to 176.70)
2000
1000 .
Tirae-
22 .50
23 .50 24.00
#8
Aeenaphthene(CCC)
Concen: 1.59 ng/uL
RT: 22.11 min Scan# 1370
Delta R.T, -0.01 min
Lab File: ENG1668.D
Acq; 15 Oct 99 8:25 pm
Tgt Ion:154 Resp: 143698
Ion
154
153
0
Ratio
100
101.5
0.0
0.0
Lower Upper
49.1
0.0
0.0
147.1
0.0
0.0
TIC: ENG1668.D
#9
Fluorene-dlO
Concen; 0.00 ng/uL
Expected RT; 23.31 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 176
Exp Ratio
100
0.0
0.0
0.0
"EH5"
0C03I55
ENSlbbB.D—FE5XTTT
1 I ! 1 1
23^00
Mon Oct IB 15:24:33 1999'
HP 5989B
Page 6
-------
Abundance
150000
100000
50000
i—i—j—j—i—i—i—i—i—|—i—|—i—r~—i—r—t—t—| i -'i—i—r-
Time--> 23.20 23.30 23.40 23.50
Abundance Ion lSS.OO U65.70 to 155.70): EMG"
TIC: EN61668.D
100000
Ion 165.00 (164.70 to 165.70): ENG
23.37
50000
Time-
I 1 1—t J 1 ! 1—I J 1 1 1 1—t 1 ! 1 1 1 1—r-
23.20 23.30 23.40 23.50
#10
Fluorene
Concen: 1.75 ng/uL
RT: 23.37 min Scan# 1560
Delta R.T. -0.01 min
Lab File: SNG1668.D
Acq: 15 Oct 99 8:25 pra
Tgt Ion:166 Resp: 163874
Ion Ratio Lower Upper
166 100
165 89.1 45.7 137.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000
100000
50000
Time - - > 24 .50
TIC: ENG1668.D
25:oo"
25.50 26.00 26.50
3000
2000
1000
Time-
—f—i—i—1—j—1—r~
>24150 25.00
!—i—j—1—r
25.50
26.00 26.50
#11
Phenanthrene-dl0
Concen-. 0 .00 ng/uL
Expected RT: 25.69 min
Lab File:
Acq: 15 Oct
Tgt Ion-. 188
ENG1668.D
99 8:25 pm
Exp Ratio
100
24.5
0.0
0.0
Abundance Ion 188.00 (137.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
OCOiSS
ENGlfc&B.D—FES3.M
Mon Oct 18 15:24:37 1999
HP 5989B
Page 7
-------
Abundance
150000
100000
50000
TTCTT1MG1668 .D
0
Time--> 25.60 25:70 25180
Abundance Ion 178.00 (177.70 to 178.70); IMG
150000
100000
Ion 176.00 (175 .70 to 176.70): ENG
25.73
50000
25 70
Time--> 25.60
25.80
#12
Phenanthrene
Concen; 1.80 ng/uL
RT: 25.73 min Scan# 1918
Delta R.T. -0.01 min
Lab Pile; ENG1668 .D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:178 Resp: 255000
Ion Ratio Lower Upper
178
100
176
19.7
10.2
30.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
TIC: ENG1668.D
i—i—i—I—|—i—I—i—I—I—i—i—i—i—I—i—i—i—i—|—i—r
25.00 25.50 26.00 26.50
Time-->
Abundance Ion 188.00 (187.70 to 188.70)
3000
2000
iooo :
0
Ion 94.00 (93.70 to 94.70)
'p' i.
rime-->
T—I—?—I—[—!—1 1—I—I—I—\—I—I—I—I—I—l 1—\—l—l—r
25.00 25.50 26.00 26.50
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab Pile: ING1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 26.6
0 0.0
0 0.0
: IMG
ENG16
ENG1668.D PES3.M
Mon Oct 18 15:24:40 1999
0C03157
HP 5989B
Page 8
-------
TIC: ENGl€68.D
Maundance
150000 _
100000 -
50000 _
25.80
Time-->25.70
Abundance Ion 178.00 (177.70 to 178.70): ENG
150000jlon 176.00 (175.70 to 176.70): ENG
26!00
25.86
100000 .
50000 -
Time-->25.70
25.80
25 .90
26.00
#14
Anthracene
Concen: 2.08 ng/uL
RT: 25.86 min Scan# 1938
Delta R.T. -0.01 min
Lab File: SNG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion;178 Resp; 180574
Ion Ratio Lower Upper
178 100
176 19.3 10.0 29.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
TIC: 1MG1668.D
200000:
|
150000 .
100000 -
50000 .
A 1
I .
U
I
0 1
Time-->27.50 28.00 28.50
29.00
29 .50
Abundance Ion 212.00 {211.70 to 212
.70)
: ENG
20000 :
Ion 106.00 (105.70 to 106
.70)
ENG
15000 .
10000 -
5000 -
.
0 -
1
Time--> 27 i 50 28 !oV 28150
r r* t t i
29.00
1 j 1 1 i !
29 .50
#15
Fluoranthene-dl0
Concsn: 0.00 ng/uL
Expected RT; 28.68 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 27.3
0 0.0
0 0.0
0003153
HP 5989B
Page 9
-------
EE
TIC: ENG1668.D
100000
50000
0
Time-->
28.60
-i 1 j ! r*
28.80
Abundance Ion 202700 (2"OT770 to 202.70): ENG
jlon 101.00 (100.70 to 101.70) : ENG
28.72
100000
50000 -
0
Time-->
~l ! 1 j 1 1 T
28.60
28.80
#16
Fluoranthene(CCC)
Goneen: 1.78 ng/uL
RT; 28.72 min Scan# 2376
Delta R.T. -0.01 min
Lab File: ENG16 68.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:202 Resp: 244659
Ion Ratio Lower Upper
202
100
101
25.1
12 .1
36.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
150000
100000
50000
0
Time-
TIC: ENG1668.D
-i—i—i—!—|—i i" " i \ | i t i t ¦ i1 r 1 i—i 11 " "j1 1) [ ;—r-
28.50 29.00 29.50 30.00
Abundance Ion 212.00 (211.70 to 212.70); ENG
20000 lion 106.00 (105.70 to 106.70): ENG
15000
10000
5000
0
Time-->
'2*8 1 50* 29 10*0 29 i 50 30 I 00
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 212
Exp Ratio
100
31.6
0.0
0.0
0003159
HP 5989B
Page 10
-------
(Abundance
200000
150000:
100000
50000
TIC: ENGl€SS.D
0
n 1 1 r
29.20
29.40
Abundance Ion 202.00 (201.70 to 202.70):
Ion 101.00 (100.70 to 101.70):
29 .32
100000
~mr
ENG
50000
0
Time-->
29.40
#18
Pyrene
Concen: 1.74 ng/uL
RT: 29.32 rain Scan# 2467
Delta R.T. -0.01 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:202 Resp: 266662
Ion Ratio Lower Upper
202
100
101
29.0
13 .9
41.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
150000
100000
50000
TIC: ENG1668.D
0
Time-->
29 .40
Abundance Ion 244.00
150000 4Ion 122.00
100000
50000
29.60
(243.70 to 244.70)
I 1 r-
29.80
#19
p-Terphenyl-dl4
Concen: 3.12 ng/uL
RT: 29.61 min Scan# 2510
Delta R.T. -0.01 min
Lab Pile: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:244 Resp: 287965
Ion Ratio Lower Upper
244
100
122
32 .5
14.6
43 .7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
(121.70 to 122
29 . 61
70!
IMS"
ENG
0
Time-->
ENQ1668.D
0GC3160
—I 1 ! 1 1
29140 29160 29180
PES3 .M Mon Oct 18 15:24:49 1999'
HP 5989B
Page 11
-------
TIC; ENG1668.D
60000
40000
20000
Txme-
32.50
33 iocT
33.50 34.00
Abundance Ion 240.00 (239.70 to 240.70): IMC
Ion 120.00 (119.70 to 120.70): ENG
4000
2000
Time-
32.50 33.00 33.50 34.00
Abundance
60000
40000
20000
Time--> 33.30
33 .40
33 .50
20000
0
Time-->
ENG166B.D
—|—p.
33 .50
#20
Benzo (a) anthracene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.36 min
Lab File; ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion; 240
Ion
240
120
0
0
Exp Ratio
100
27.9
0.0
0.0
TIC: ENG1668.D
#21
Benzo{a)anthracene
Concen: 1.83 ng/uL
RT: 33.44 min Scan# 3085
Delta R.T. -0.02 min
Lab File; ENG1668.D
Acq; 15 Oct 99 8:25 pm
Tgt Ion:228 Resp: 129460
Ratio
100
26.6
0.0
0.0
Lower Upper
12.8
0.0
0.0
38.2
0.0
0.0
Abundance Ion 228.00 (227.70 to 228.70); ENG
60000 JIon 114-00 (113.70 to 114.70! : ENG
40000
33.30 33.40
PES3.M Mon Oct IB 15:24:53 1999
0CG3161
HP 5989B
Page 12
-------
ABun9ance
60000
40000
20000
TIC: ENGT6F870
-i—p—1—!—!—I—|—I—r
¦> 32.50 33 .00
-i—j—i—!—i—r—I—i—i—ft—|—t~
33.50 34.00 34.50
Time-
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70) : ENG
4000
2000
L
ime-
_j , j , y—, f ( —p-.-.,. . .y , , j—
•> 32150 33.00 33.50 34.00
34.50
Abundance
60000 :
40000
20000 4
TIC: ENG1668.D
0
—I 1 1 1 ! 1 1 ! ! 1 1 1 1 r
33.40 33.60 33.80
60000
40000
20000 .
0
~i 1 ? i 1 i 1 11 1 r " i"
Time--> 33.40 33 160
ENGXW8TD—roSTTH
—j—,—r
33.80
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.50 min
Lab Pile: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 240
Exp Ratio
100
27 .3
0.0
0.0
#23
Chrysene(CCC)
Concen: 1.73 ng/uL
RT: 33.59 min Scan# 3108
Delta R.T. -0.02 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion-.228 Resp: 176809
Ion Ratio Lower Upper
Time-->
Abundance Ion 228.00 (227.70 to 228.70): filJG
228
100
114
24.1
11.2
33.5
0
0,0
0.0
0.0
0
0.0
0.0
0.0
Ion 114.00 (113.70 to 114.70): ENG
33 .59
oeooi
»-2
Mon Oct 18 15:24:56 1999
HP 5989B
Page 13
-------
[Abundance
40000
30000
20000 .
10000 -
Time-->
0
TTC7ENG16 6 8.D
I 1 1 1 1 1 1 1 1 1 5 1 1 J 1 1 ! ! 1 1 1 1 T"
38.50 39.00 39.50 40.00
(AbundanceIon 264.00 (263.70 to 264.70); IMG
Ion 132.00 (131.70 to 132.70): ENG
4000
2000
Time-->
i—i—i—[—i—i—i—i—i—r—i—i—l—r—i—i—i—i—|—i—i—it
38.50 39.00 39.50 40.00
Abundance
40000
TIC; ENG1668.D
30000
20000
10000
0
Time--> 39 I 30 39140
Abundance Ion 252.00
39.50 39 . SO
(251.70 to 252.70]
#24
Benzo(b)£luoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab File: ENG1668.D
Acq; 15 Oct 99 8:25 pm
Tgt Ion; 264
Ion Exp Ratio
264 100
132 69.4
0 0.0
0 0.0
#25
Benzo(b)fluoranthene
Concen: 1.70 ng/uL
RT: 39.49 min Scan# 4014
Delta R.T. -0.03 min
Lab File; ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion;252 Resp: 122382
Ion Ratio Lower Upper
252
100
126
28.1
14.0
41.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
30000
20000
10000
0
Ion 126 .00
(125 .70 to 126.70)
39.49
ENG
ENG
0C03163
Time--> 39.30
ENGXS¥S7U—PES 3 .M
1 1 1 1 ! 1 j 1 1 1 1 1 1
39!40 39.50 39160
Mon Oct IB 15:24:59 1999'
HP 5989B
Page 14
-------
Abundance
40000
30000:
20000
10000
0 1 , , , 1 1 1 1 1 1 1 ! 1 1 j 1 1 1 1 1 1 'I
Time--> 38150 39l00 39.50 40.00 40.50
TIG: MG1668.D
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70) : ENG
4000
2000
0
"i—r—r—r—i—j ? i——j i m—i—r—i—!—\—r—r—i—j—r-
frime--> 38.50 39.00 39.50 40.00 40.50
#26
Benzo(k)fluoranthene-dl2
Coneen: 0.00 ng/uL
Expected RT: 39.53 min
Lab Pile: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion
Ion
264
132
0
0
: 264
Exp Ratio
100
35 .8
0.0
0.0
Abundance
TIC • 5NG!L€€S
.D
40000 :
30000 -
20000:
10000 -
o:
Time- -s39
¦ •
.40
39.50
39.60 39.
70 39.80
AbundanceIon
252.00
(251.70 CO
252.70) : ENG
30000 _
Ion
126.00
(125.70 to
126.70): ENG
39.64
20000_
10000 -
0 -
Time-->39
.40
39 .50
! 1 1 1 1 . 1 |
39.60 39.
* l t ! !" i i l
70 39.80
#27
Benzo(k)fluoranthene
Concen: 1.84 ng/uL
RT: 39.64 min Scan# 4037
Delta R.T. -0.03 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion-.252 Resp: 98308
Ion Ratio Lower Upper
252
100
126
31.8
13.9
41.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG1668.D PEHJTW
0C031tl
Mon Oct 18 15:25:02 1999
HP 59891
Page 15
-------
Abundance
20000
10000 .
TIC: ENG1668.D
Time- - > 4ol50' 4X100 41!50 42 loo 42150
WDundanceIon 264.00 (263.70 to 264.70): ENG
6000 ^ion 132.00 (131.70 to 132.70): ENG
4000
2000
--J 1 ' 1 1 j 1 r ! 1 j~~! 1 I 1 1 1 ! 1 1 J 1 I 1
Time--> 40.50 41.00 41.50 42.00 42.50
#28
Benzo (a) pyrene-d.12
Concen: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 37.8
0 0.0
0 0.0
TIC: ENGlbb8.D
Abundance
20000
10000
-i 1 | 1 r
41.60
r—1 1 1 j 1 r
41180 42.00
15000
10000
5000
Time-->
ENG16 6 8 . D
#29
Benzo(a)pyrene(CCC)
Concen: 1.75 ng/uL
RT: 41.77 min Scan# 4363
Delta R.T. -0.02 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:252 Resp: 61164
Txme-->
AbundanceI on 252.00 (251.70 to 252.70): ENG
Ion
Ratio
Lower
Upper
252
100
126
31.5
15.7
46.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
jlon 126.00 (125.70 to 126.70): ENG
41.77
41.60 41.80 42.00
TES3.M Hon Oct 18 15:25:06 1939"
0CC31
HP 5989B
Page 16
-------
TIC: ENGTfabB,D
20000
10000
Time*
52 .00
53 .00
54.00
Abundance Ion 288.00 (287.70 to 288.70): ENG
2000
1000
[Time - - >
10000
1—i 11 1 i—1—1—1—'—5—'—'—I—r—r™P"1—'—!—'—i—'—
Time--> 52.40 52160 52180 53 100
AbundanceIon 276.05(275.75 to 276.75): ENG
10000
Ion 138.00 (137.70 to 138.70)
52.76
ENG
5000
Time-
"1—I—I—!—!—I—f—!—!—!—!—!—|—r—1—I—I—I—r—1
52.40 52.60 52.80 53.00
#30
Indeno(1,2,3-cd)pyrene-dl2
Concern 0.00 ng/uL
Expected RT: 52.54 min
Lab File; ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion; 288
Exp Ratio
100
0.0
0.0
0.0
TICz ENG1668.D
20000
#31
Indeno{1,2,3-cd)pyrene
Concen: 1.97 ng/uL
RT: 52.76 min Scan# 6068
Delta R.T. -0.06 min
Lab File; ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:27 6.05 Resp:
69372
Ion Ratio Lower Upper
100
0.0
0.0
0.0
30.1
0.0
0.0
90.2#
0.0
0.0
oooJigs
1NG1668.D—PES3.M
Mon Oct 18 15 :~25 : 09 1999
HP 5989B
Page 17
-------
fares'
20000
10000
TIU7~EN<3l668.D
Time--3B1100 52100 53.00
Abundance Ion 2$2.0C (291.70 to 292.70): ENG"
2000
1000
0 ,
Time- - jBI
00
52.00
! r-
53 .00
#32
Dibenz(a,h)anthracene~dl4
Concen: 0.00 ng/uL
Expected RT: 52.50 min
Lab File: ENG1668.D
Acq; 15 Oct 99 8:25 pm
Tgt Ion
Ion
292
0
0
0
292
Exp Ratio
100
0 .0
0.0
0.0
Abu50TOge
TIC: ENGlbbB .D
20000 .
y\_
10000 .
0 J
Time-->
52.40 52.60 52.80 53.00 53
120
Abundance Ion 278.00 (277.70 to 278.70):
ENG
10000 -
Ion 139.00 (138.70 to 139.70):
ENG
52.80
5000 .
0 .
Time-->
52140 52.60 52,80 53.00 53
.20
#33
Dibenz(a,h)anthracene
Concen: 2.06 ng/uL
RT: 52.80 min Scan# 6075
Delta R.T. -0.06 min
Lab Pile: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:278 Resp: 62572
Lower Upper
26.9 80.5
0.0 0.0
0.0 0.0
Ion
278
139
0
0
Ratio
100
31.0
0.0
0.0
ENG1&68 .D—PES 3 .M
0CCML67
Hon Oct 18 15:25:12 1999
HP 5989B
Page 18
-------
fTime--> 55.00 56.00
Abundance Ion 288.00 (287.70 to 288 .705
3undan.ce
15000
10000
TIC: ENG1668.D
5000
2000
1000
Time-
,—r
55.00
56.00
Abundance
15000
10000 .
5000 .
i—j—i—t—i—?—j—i—i—i—i—]—i—r—i—[—|—i—i—j—i—|—i—r
55.40 55160 55180 56.00 56120
Abundance Ion 276.00 (275.70 to 276.70):
#34
Benzo(g,h,i}perylene-dl2
Concen: 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:. 288
Ion
288
0
0
0
Exp Ratio
100
0.0
0.0
0.0
ENG
TIC: ENGlbba.D
#35
Benzo{g,h,i)perylene
Concen: 1.86 ng/uL
RT: 55.78 min Scan# 6658
Delta R.T. -0.06 min
Lab File: ENG1668.D
Acq: 15 Oct 99 8:25 pm
Tgt Ion:276 ReBp: 71688
Ion Ratio Lower Upper
276
100
138
0.0
6.5
26.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
10000 Jlon 138.00
EMT
(137.70 to 138.70): ENG
55 .78
5000 -
i—I—I—i—!—i—i—1—r—I—i—f—j—i—i—i—I—I—I—I—j—i—i—I—r
Time--> 55.40 55.60 55.80 56.00 56.20
ENGlfebB .D—PES3 .M Mon Oct IB 15:25:16 1999'
0C03163
HP 5989B
Page 19
-------
Quantitation Report
C:\HPCHEM\1\D ATA\ENG166 9.D
15 Oct 99 9:32 pm
CARB4 2 9,MDL8
Data Pile
Acq On
Sample
Misc
Quant Time: Oct 18 15:26 1999
Vial
Operator
Inst
Multiplr
10
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.99
190
621512
5.00 ng/uL
1 H
1 o
l o
iystem Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00 ng/uL
0.00%
4)
2-Methlynaphthalene-dlO
19.36
152
203621
1.67 ng/uL
41.71%
5)
Acenaphthylene-d8
0.00
160
0
0.00 ng/uL
0.00%
7)
Acenaphthene-dl0
0.00
164
0
0.00 ng/uL
0.00%
9)
Fluorene-dlO
0.00
176
0
0.00 ng/uL
0.00%
11)
Phenanthrene-dl0
0.00
188
0
0.00 ng/uL
0.00%
13)
Anthracene-dl0
0.00
188
0
0.00 ng/uL
0.00*
15)
Fluoranthene-dlO
0.00
212
0
0.00 ng/uL
0.00%
17)
Pyrene-dlQ
0.00
212
0
0.00 ng/uL
0.00%
19)
p-Terphenyl-dl4
29.61
244
269694
2.23 ng/uL
55.67%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00 ng/uL
0.00%
22)
Chrysene-dl2
0.00
240
0
0.00 ng/uL
0.00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0.00%
26)
Benzo(k)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0.00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00 ng/uL
0.00%
30)
Indeno(1,2,3-cd)pyrene-dl2
0.00
288
0
0.00 ng/uL
0.00%
32)
Dibenz(a, h)anthracene-dl4
0.00
292
0
0.00 ng/uL
0.00%
34)
Benzo(g,h,i)perylene-dl2
0.00
288
0
0.00 ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.73
128
372670
0.93 ng/uL
99
6)
Acenaphthylene
21.65
152
147592
1.09 ng/uL
100
8)
Acenaphthene(CCC)
22.11
154
123091
1.04 ng/uL
97
10)
Fluorene
23 .37
166
142529
1.16 ng/uL
98
12)
Phenanthrene
25.73
178
228418
1.23 ng/uL
99
14)
Anthracene
25 .86
178
158001
1.39 ng/uL
99
16)
Fluoranthene(CCC)
28.72
202
231784
1.29 ng/uL
98
18)
Pyrene
29.33
202
252203
1.26 ng/uL
98
21)
Benzo(a)anthracene
33 .44
228
126131
1.36 ng/uL
98
23)
Chrysene(CCC)
33.59
228
165455
1.24 ng/uL
96
25)
Benzo(b)fluoranthene
39 .49
252
118835
1.26 ng/uL
99
27)
Benzo(k)fluoranthene
39.64
252
93449
1.34 ng/uL
94
29)
Benzo(a)pyrene(CCC)
41.76
252
56358
1.23 ng/uL
97
31)
Indeno(1,2,3-cd)pyrene
52 .76
276
63632
1.37 ng/uL#
52
33)
Dibenz(a,h)anthracene
52.81
278
57638
1.45 ng/uL#
44
35)
Benzo(g,h,i)perylene
55.79
276
66836
1.32 ng/uL#
62
OCCjIcS
(#) = qualifier out of range (m) = manual integration
ENG1669.D PSS3.M Mon Oct 18 15:28:09 1999 HP 5989B
Page l
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\1NG1669.D
Acq On ; 15 Oct 99 9:32 pm
Sample : CARB429,MDL8
Misc :
Quant Time; Oct 18 15:26 1999
Vial: 10
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METH0DS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
TIC: 1NG16S9.B
450000
400000
350000
300000
250000
200000
10 12
150000
100000 .
50000
Time-->
"i i—i—|—i—i—i—i—|—i—; i i1 r i"1 i1—j—i—I—s—i—i i r i—i—i—r~-1—i—»—it—i—i—i—i—r
20.00 25.00 30.00 35100 40.00 45.00 50.00 55100
000)170
ENG1669.D PES3.M Mon Oct 18 15:28:16 1999 HP 5989B
Page 2
-------
Abundance
200000
150000
100000
50000
T 1 1 F
Time-->16150 17100
17.50
AbundanceIon 13S.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG16
4000
TIC!: ENG1669.D
Ti8: oo
1—i—|—!—i—r-
18.50
2000
-i—i—i—i—|—"—i—i—i—|—i—i—?—i—| i I i i | i r—r~r
Time-->16150 17.00 17.50 18.00 18.50
Abundance
200000
150000
100000
50000 J
—!—r
17.60
1 r
17.70
,——,—,—r
17.80
200000
150000
100000
50000
17.73
Time-->
1NG1669.D
17.60
FES'3.M
#2
Naphthalene-d8
Ccncen: 0.00 ng/uL
Expected RT: 17.69 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 136
Ion Exp Ratio
136 100
68 15.3
0 0.0
0 0.0
TIC: ENG1669.D
#3
Naphthalene(CCC)
Concen: 0.93 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.01 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:128 Resp: 372670
Ion Ratio Lower Upper
Time-->
Abundance Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70)
128
100
127
12.7
0.0
63 .0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
000 ji
M' J*
fx
11,70 17:80 ' I
Mon Oct 18 15:28:20 1999
HP 5989B
Page 3
-------
TTC7
Abundance
100000 H
50000 -
Time--> 19.30 19.40
Abundance Ion 152.00 (151,70 to 152.705; IMG
19.36
100000 -
50000 -
Time-->
19.30
19.40
#4
2-Methlynaphthalene-dlO
Concen: 1.67 ng/uL
RT; 19.36 min Scan# 757
Delta R.T, -0.01 min
Lab File: ENG1669.D
Acq; 15 Oct 99 9:32 pm
Tgt Ion:152 Resp: 203621
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
100000
—i—!—i—?—i—t—i—r—i—I—i—i—i—I—i—i—i—(—r—i—i—\—r-
Time--> 20.50 21.00 21.50 22.00 22.50
TIC; BNG1SS9.D
50000
2000
1000
_1 j , p.
~i—*—i
rime--> 20.50 21.00 21.50 22.00 22.50
#5
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT; 21.63 min
Lab File; ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion; 160
Exp Ratio
100
0.0
0.0
0.0
Abundance Ion 160.00 (159.70 to 160.70): EMS
ENG1669.D—PES3.M
Mon Oct 18 15:28:23 1999
HP 5989B
Page 4
-------
Abundance
80000
60000
40000
20000
Time-->
TIC; ENG1669.D
11 «'
-1—I—I—r
21.50 21.60 21.70 21.80
Abundance Ion 152.00 (151.70 to 152.70): ENG
<• f- -1 A A
Ion 153.00
80000:
60000 :
40000
20000
0
Prime-->
[152.70 to 153.70} ; ENG
21.65
]—i—I—i—!—|—i—i—i—i—j—r—T—i—i—|—i—i—r-
21.50 21160 21.70 21.80
#6
Acenaphthylene
Concen: 1.09 ng/uL
RT: 21.65 min Scan# 1301
Delta R.T. -0.01 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:152-Reap: 147592
Ion Ratio Lower Upper
152
100
153
12.9
6.6
19.6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENGlbbS.D
100000
50000
1—!—I—I—I—I—I—I—I—!—!—I—I—I—I—I—I—I—I—I—r
Time--> 21.00 21.50 22.00 22.50 23100
Abundance Ion 154.00 (163.70 to 164.70]
HT
2000
1000
f\
Time-
i—i—j—i—(—i—i—j—s—!—i—i—r—i—i—i—i—|—i—i—i—i—j—i—r-
21.00 21.50 22.00 22150 23.00
ENGT6"69"'T5—PES3 M'
•af
-------
TIC: ENG1669.D
100000
50000
T" T ¦" !—T [ I I—i—r 1 1 1 1 1 1 I 1 ! r
Time--=21.90 22.00 22.10 22.20
IOIl 154.00 (153.70 to 154.70):
Ion 153 .00 (152 .70 to 153.70)
22.11
1U0~
ENG
60000
40000
20000
0
i 1 ! 1—»—I 1 1 r [i 1 1—i—[—I—i r—i—r-
fTime--21.90 22.00 22.10 22.20
#8
Acenaphthene(CCC)
Concen: 1.04 ng/uL
RT: 22.11 min Scan# 1369
Delta R.T. -0.01 min
Lab File: ENG1669.D
Acq; 15 Oct 99 9:32 pm
Tgt Ion: 154 Resp-. 123091
Ion Ratio Lower Upper
154
100
153
101.4
49.1
147.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENGlbb9,D
100000
50000
Time-->
Abundance Ion 17S.00 (175.70 to 176.70): ENG
2000 ^
22 .50
T—I—I—I—|—T
23 .00
23.50 24.00
1000
Time-
i—i—|—i—i—i—i—|—i—i—i—i—|—i—!—i—i—]—r—r
22.50 23.00 23.50 24.00
T
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 176
Exp Ratio
100
0.0
0.0
0.0
ENG1669.D—PES3.M
Mon Oct 18 15:28:29 1999
0C03i?4
HP 5989B
Page 6
-------
abundance
100000
50000
TIC: ENG1669.TT
40000
20000
Time-
-i—i—i—I—i—r
23120
-1—r—1—1—I—1 1 1—r
23130 23140 23,50
50000
1—1—r 1 "i"
25.50
26:00^26:50
Time-->24.50 25,00
Abundance Ion 188.00 (187.70 to 188.70
#10
Fluorene
Concen: 1,16 ng/uL
ET: 23.3 7 min Scan# 1560
Delta E.T. -0.01 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:166 Resp: 142529
Ion Ratio Lower Upper
Time - - > 23.20 23.30 23 U0 23 !5o'
Abundance Ton 166.00 (165.70 to 166.70): ENG
lion 165.00 (164.70 to 165.70;
80000 J 23.37
60000:
166
100
165
89 .0
45.7
137.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1669.D
100000
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 188
Exp Ratio
100
24.5
0.0
0.0
3000
2000
1000
Ion 94.00 (93.70 to 94.70]
: ENG
ENG16
time- - > 24 .To 2*5 ! 00 25 ! 5 0 ' ' 2 6 1 00 ' 26l50'
ENG16 6 9 . D PES3. M
Man Oct 18 15:28:32 1999
HP 5989B
Page 7
-------
Abundance
100000
TIC: ING1669.D
50000
0
0
Time--> 25.60
Time--> 25.60 25.70 25 . 80
or ya -mm—Pf-*——4'
AbundanceIon 188.00
lion 94.00
3000 J
2000
1000
0
25.00 25.50 26.00 26.50
(18?.70 to 188.70):
(93.70 to 94.70): SNG16
Time-->
ENG1669.D—PES3.M
1—!—i—1—i—i—1 i t—1—r—1—(—1—1—1—!—1—1—1—1—i—r
25.00 25.50 26.00 26150
#13
Anthracene-dlO
Concen: 0.00 ng/uL
ExTJfCt" pfi RT * 0 ^ fl O mi n
•""¦I 9** Xw» 1m# *hM> hf • w* >& <*
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 26.6
0 0.0
0 0.0
Mon Oct 18 15:28:35 1999
0C0317S
HP 5989B
Page 8
-------
^Abundance
100000
50000
TIC: ENG166S.D
Time--> 25.70 25.80 25.90
AbundanceIon 178.00 (177.70 to 178.70
26.00
Ion 176.00
100000
50000 -
Time--> 25.70
#14
Anthracene
Concen: 1.39 ng/uL
RT: 25.86 min Scan# 1938
Delta R.T. -0.01 min
Lab Pile: ENG1669.D
Acq: 15 Oct 99 9;32 pm
Tgt Ion:178 Resp: 158001
Ion Ratio Lower Upper
178
100
176
19.3
10.0
29.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
i : IMG
175.70 to 176.70}: ENG
25.86
25.80
25.90
26.00
ENG1669.D
150000
100000
50000
Time - - > 27 '.50 28100 28150 29.00 29 : 50
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
15000:
"*29100
ioooo :
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
; 212
Exp Ratio
100
27.3
0.0
0.0
Tgt Ion
5000
"**1—l—I 1 1—1—I—I—1—J—I 1 1 1 [ 1 1 1 I—I—I—f 1 1"
kTime--> 27 15 0 28.00 28 150 29.00 29*50
0CC3177
Mon Oct IB 15:28:38 1999
uo CQQQO
rif jjojd
Page 9
-------
TIC: ENG166S.D
100000
50000 -
Time-
28.60
28.80
(AbundanceIon 202.00 (201.70 to 202.705
Ion 101.00 (100.70 to 101.70)
28.72
iooooo 1
50000
0
Time-->
28.60
28 1 80
#16
Fluoranthene(CCC)
Concen: 1.29 ng/uL
RT: 28.72 min Scan# 2377
Delta R.T. -0.01 min
Lab File; ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:202 Resp: 231784
Ion Ratio Lower Upper
202
100
101
25 .0
12 .1
36.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
150000
100000
50000
TIC: EMG1SS9.D
0
Time-->
~i—f—i—r—i—i—t—t—|—i—i—i—i—r—i—t—i—!—f—i—r~r
28.50 29:00 29150 30.00
[AbundanceIon 212.00 (211.70 to 212.70)
Ion 106.00 (105.70 to 106.70)
15000
10000
5000
Time - - >
28.50 29.00 29.50 30.00
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 212
Ion Exp Ratio
212 100
106 31.6
0 0.0
0 0.0
ENGlfcfcy.D—PES3.M
0CC 31;s
Hon Oct 18 15:28:42 1999
HP 5989B
Page 10
-------
Abundance
150000
100000
50000 .
TIC: ENG1669.D
0
Time--> 29120 29130 29140 29.50
Abundance Ion 202.00 (201.70 to 202.70): ENG
Jlon 101.00
(100.70 to 101.70)
29.33
100000
50000
0
Time-->
_! 1 r 1 | I
29.20
29.30
i—!—i—f—i—i—|—r~
29.40 29.50
50000
i—i—i—i—|—i—i—i—?—|—r
fTime-->29140 29.50 29.60
t—i—[—i—i—i—r
29.70
#18
Pyrene
Concen: 1.26 ng/uL
RT; 29.33 min Scan# 2467
Delta R.T. -0.01 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt ion:202 Resp: 252203
Ion Ratio Lower Upper
202
100
101
28.7
13.9
41.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1GG9.D
150000
100000
#19
p-Terphenyl-dl4
Concen: 2.23 ng/uL
RT: 29.61 min Scan# 2510
Delta R.T. -0.01 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:244 Resp: 269694
Ion
Ratio
Lower
Upper
244
100
122
32,1
14.6
43 .7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance Ion 244.00 (243.70 to 244.70): ENG
Ion 122 .00 {121.70 to 122 .70) : ENG
29.61
100000
50000
0
~i—i—'—r~
Time-->29.40
ENG1669.D PES3.M
29.50 29.60 29 ! 70
Won Oct 18 15:28:44 1999'
0CG3179
HP 59891
Page 11
-------
TIC; 2NG1669.D
60000 -
40000 -
Time-->
Abundance Ion 240.00 (235.70 to 240.70): ENG
Jlon 120.00 (119.70 to 120.70): ENG
32.50 33.00 33.50 34.00
4000 -
2000 -
32.50 33.00 33.50 34.00
#20
Benzo(a)anthracene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.36 min
Lab Pile: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.9
0 0.0
0 0.0
Abundance
TTuiENG1669.D
60000
40000
20000
t f 1 1 1 1 1 1 1 1 1 1 1 1 r~
fTime - -> 33.30 33.40 33.50 33 .60
#21
Benzo(a)anthracene
Concen: 1.36 ng/uL
RT: 33.44 min Scan# 3085
Delta R.T. -0.02 min
Lab Pile: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:228 Resp: 126131
Ion Ratio Lower Upper
228
100
114
26.3
12.8
38 .2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
l..1 1 —¦ ¦ ——— — m i — m ¦ n—- ¦ MM —HT ¦ I ¦¦ II ¦ ¦!
AbundanceIon 228.00(227.70 to 228.70): ENG
60000 -|lQn 114.00 (113.70 to 114.70): ENG
40000
20000 .
0
33.44
Time--> 33.30
ENG1669.D PES3 .M
33 .40
33.50 33.60
HonHOct la 15:28:48 1992
0CC3160
HP 5989B
p^g0 12
-------
Abundance
60000
40000
20000
Time--> 32,50 33.00 33.50 34.00 34.50
TIC; ENG1669.D
2000
Time - ->
1—|—I f ! 1—| 1—I
32.50 33.00
33 ;50
1 1 1 1 1 1 1 1 1 1
34.00 34.50
Abundance
60000
40000:
20000
Time - ¦
33.40
33 . 60
33 .80
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.50 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 240
Exp Ratio
100
27.3
0.0
0.0
[AbundanceIon 240.00 (239.70 to 240,70): ENG
Ion 120.00 (119.70 to 120.70): ENG
4000 H
TIC: ENG1&69.D
#23
Chrysene(CCC)
Concen: 1.24 ng/uL
RT: 33.59 min Scan# 3108
Delta R.T. -0.02 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:228 Resp: 165455
Ratio
100
24.0
0.0
0.0
Lower Upper
11.2
0.0
0.0
33.5
0.0
0.0
Abundance Ion 228.00 (227.70 to 228.70): IMG
60000
40000
20000
Ion 114.00 (113.70 to 114.70): ENG
33.59
Time--> 33.40 33.60 33.80
ENG1669 ,D—PES3.M Mon Oct 18 15:28:51 1999'
OCCOldl
HP 5989B
Page 13
-------
Abundance
40000
30000
20000
TIC: ENG1669.D
10000
0
Tittle--> 38.50 39.00 39.50 40.00
Abundance Ion 264.00 {263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
4000
2000
0
Time-->
i—i—|—i—r
38 .50
39.00 39.50
t—i—I—i—i—i—r
40.00
abundance
40000:
30000
20000
10000
0
TIC: ENG1669.D
Time--> 39.30 39.40
Abundance Ion 252.00
39 .50 39.60
251.70 to 252.70]
#24
Benzo(to)fluoranthene-dl2
Concen: 0.00 ng/'uL
Expected RT: 39.35 tnin
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 264
Ion
264
132
0
0
Exp Ratio
100
69.4
0.0
0.0
#25
Benzo(b)fluoranthene
Concen: 1.26 ng/uL
RT: 39.49 min Scan# 4014
Delta R.T. -0.03 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:252 Resp: 118835
Ratio
100
28.4
0.0
0.0
Lower Upper
14
0
0
0
0.0
41.8
0.0
0.0
30000
20000
10000
0
Ion 126.00
(125.70 to 126.70)
39.49
r
ENG
0CC0162
Time--> 39.30
39.40
—h—|—i—i—i—!—[—r—i—i—r-
39.50 39.60
ENG1669 .D—PES 3 .M
Mon Oct 18 15:28:54 1999
HP 5989B
Page 14
-------
TIC: ENG1S69.D
Abundance
40000 J
30000 .
20000:
ioooo :
Abundance Ion 264.00 (263,70 to 264.70') : ENG
•lion 132 . 00 (131.70 to 132 . 70) : ENG
4000 -
2000 -
#26
lenzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.53 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pra
Tgt Ion: 264
Ion Exp Ratio
264 100
132 35.8
0 0.0
0 0.0
Abundance
TIC: ENG1669
.D
40000:
30000:
20000:
ioooo:
o:
Time-->
39.40 39.60
. i i .
39180
Abundance Ion 252.00 (251.70 to
252 .70) :
ENG
30000:
Ion 126.00 (125.70 to
126.70) :
ENG
/ \ 39.64
20000 ,
/ \ A
ioooo:
0 J
Time-->
39.40 39.60
39.80
ENGX5W7D—PES 3 .M"
#27
Benzo(k)fluoranthene
Concern 1.34 ng/uL
RT: 39.64 min Scan# 4037
Delta R.T. -0.03 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion;252 Resp
Ion
252
126
0
0
Ratio
100
30.9
0.0
0.0
Lower
13 .9
0.0
0.0
93449
Upper
41.5
0.0
0.0
0CC3163
Mori "Oct 18 15 : 28 : 57 1999
HP 5989B
Page 15
-------
mm-m BWH ccq—ft
ill: aJNulbb? .u
Abundance
20000
10000
1 1 1 1—l 1—|—1—I—I—l—|—I—l—I—I—|—I—I—I—I—|—l—I—r-
Time--> 40.50 41.00 41.50 42.00 42.50
[AbundanceIon 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131. 70 to 132.70) : ENG
4000
2000
h—j—i—r*
Time--> 40.50 41.00 41.50 42.00 42.50
15000 .j
10000
5000
0
Time-
-i—| 1 r
•> 41.40
1 1 1 1 1 ! 1 1 1 1 1 1 1—
41.60 41.80 42.00
1 I I
#28
Benzo(a)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 264
Ion
264
132
0
0
Exp Ratio
100
37.8
0.0
0.0
TIC: ENG1669.D
20000
10000
#29
Benzo(a)pyrene(CCC)
Concen: 1.23 ng/uL
RT: 41.76 min Scan# 4362
Delta R.T. -0.03 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:252 Resp:
56358
T 1 1 1—f 1 1 1 1 1 1 1 ! ! 1 1 1 1 r-
Time--> 41.40 41.60 41.80 42.00
Abundance ion 252.00 (251.70 to 252.70): ENG
Ratio
100
29 . 6
0.0
0.0
Lower Upper
15.7
0.0
0.0
46.9
0.0
0.0
Ion 126.00 (125.70 to 126.70): ENG
41.76
000164
ENG1669.D PES3.M
Mon Oct IB lb:29:01 199"?
HP 5989B
Page 16
-------
TTC7
Abundance
20000 .
10000
54.00
Time-->
AbundanceIon 288.00 (287.70 to 288.70): IMG
52.00
53 .00
2000 -
1000 -
54.00
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 52.54 mill
Lab File: ENG1669.D
Acq; 15 Oct 99 9:32 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
TIC: ENG1669.D
20000
10000
52.40
r—r
52;80
I—I—I
53 ;oo
52.60
#31
Indeno(1,2,3-cd)pyrene
Concen: 1.37 ng/uL
RT: 52.76 min Scan# 6067
Delta R.T. -0.06 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion;276.05 Resp;
63632
Ratio
100
23,6
0.0
0.0
Lower Upper
30 .1
0.0
0.0
90 .2#
0.0
0 ;0
Abundance Ion 27 6.05 (275.75 to 276.^57:
10000.Jon 13800 (137 . 70 to 138.70): ENG
52.76
5000
0
Time- ->
i—i—i—i—i—i—i—i—i—i—i—i——i—i—i—i—r~~i—r
52.40 52.60 52.80 53.00
ENG1669.D—PES3.M
0C031
"Men Oct 18 15:29:04 1999
tlt5 CQQQt3
£14f Z? 0 Of
Page 17
-------
TIC: ENG1669.D
Abundance
20000 -
10000 -
53.00
Time--»
'JS m 7T7K / A A ^ WK—*T7Z—AAA W7T\
AbundanceIon 252.00 (291.70 to 292.70): Eng
52.00
2000 -
1000 -
52.00
53.00
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 52.50 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 292
Ion Exp Ratio
292 100 .
0 0.0
0 0.0
0 0.0
Abundance
TIC: ENG1669.D
20000 .
A
10000 J
0 _
I ! t 1 5 I t i » 1 I i I I 1 1 ! 1 4 ! 1 J
Time--> 52.40 52.60 52.80 53.00
Abundance Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
52 .81
5000 ,
0 .
Time--> 52.40 52.60 52180 53.00
#33 '
Dibenz(a,h)anthracene
Concen: 1.45 ng/uL
RT: 52.81 min Scan# 6076
Delta R.T. -0.06 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:278 Resp:
Ion
278
139
0
0
Ratio
100
13 .7
0.0
0.0
Lower
26.9
0.0
0.0
OCC'i
57638
Upper
80.5#
0.0
0.0
>*Vi
wlJ
Up 598 9B
Page 18
-------
Abundance
TIC: EMG1669.C
10000
5000
-I 1 "T
~1 "~~1 T"
Time--> 55.00 56.00
Abundance Ion 288.00 (287.70 to 288.70): IMG
2000
1000 -
Time*
55.00
56100
#34
Benzo(g,h,i)perylene-dl2
Concern 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
TIC: ENG1S69.D
10000
5000
i—i—i—i—\—i—i—i—i—|—i—i—r—i—i—i—r
Time--> 55140 55.60 55.80 56100 56.20
Abu^ggelon 276.00 (275.70 to 27S.70): SNG
Ion 138.00 (137.70 to 138.70)
55.79
5000
Time-->
ENGlbfcy . D—FESTTM
T 1 J ! 1 1-"! [ 1 1 ! ! J ! T
55.40 55.60 55.80
1 1 ! 1 1 1 1 1 1
56.00 56.20
#35
Benzo (g, h, i) perylene
Concen: 1.32 ng/uL
RT: 55.79 rain Scan#. 6659
Delta R.T. -0.05 min
Lab File: ENG1669.D
Acq: 15 Oct 99 9:32 pm
Tgt Ion:276 Resp: 66836
Ion Ratio Lower Upper
276
100
138
0.0
6.5
26.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
1NG
OCOiS?
Mon Oct 18 15:29:10 1999
HP 5989B
Page 19
-------
Quantitation Report
Data Pile
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1670.D
15 Oct 99 10:38 pm
CARB429,MDL9
Oct 18 15:30 1999
Vial
Operator
Inst
Multiplr
11
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Hon Oct 18 14:50:18 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.99
190
573937
5.00 ng/uL
-0.01
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00 ng/uL
0.00%
4)
2-Methlynaphthalene-dlO
19.36
152
253497
2.25 ng/uL
56.23%
5)
Acenaphthylene-d8
0.00
160
0
0.00 ng/uL
0.00%
7)
Acenaphthene-dl0
0.00
164
0
0.00 ng/uL
0.00%
9)
Fluorene-dlO
0.00
176
0
0.00 ng/uL
0.00%
11)
Phenanthrene-dl0
0.00
188
0
0.00 ng/uL
0.00%
13)
Anthracene-dlO
0.00
188
0
0.00 ng/uL
0.00%
15)
Fluoranthene-dl0
0 .00
212
0
0.00 ng/uL
0.00%
17)
Pyrene-dlO
0.00
212
0
0.00 ng/uL
0.00%
19)
p-Terphenyl-dl4
29.61
244
269938
2.41 ng/uL
60.34%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00 ng/uL
0.00%
22)
Chrysene-dl2
0 .00
240
0
0.00 ng/uL
0.00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0.00%
26)
Benzo(k)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0.00%
28)
Benzo(a)pyrene-d!2¦
0.00
264
0
0.00 ng/uL
0 .00%
30)
Indeno(l, 2, 3-cd)pyrene-dl2
0.00
288
0
0.00 ng/uL
0.00%
32)
Dibenz(a, h)anthracene-dl4
0.00
292
0
0.00 ng/uL
0.00%
34)
Benzo (g,h,i)perylene-dl2
0.00
288
o ;
0.00 ng/uL
0.00%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17 .73
128
467993
1.27 ng/uL
99
6)
Acenaphthylene
21.65
152
185189
1.48 ng/uL
100
8)
Acenaphthene(CCC)
22.11
154
160679
1.47 ng/uL
96
10)
Fluorene
23 .37
166
166197
1.46 ng/uL
98
12)
Phenanthrene
25.73
178
249495
1.45 ng/uL
99
14)
Anthracene
25.85
178
179868
1.71 ng/uL
98
16)
Fluoranthene(CCC)
28 .72
202
232703
1.40 ng/uL
99
18)
Pyrene
29 .33
202
254468
1.37 ng/uL
99
21)
Benzo(a)anthracene
33.43
228
127240
1.48 ng/uL
99
23)
Chrysene(CCC)
33.59
228
164506
1.33 ng/uL
97
25)
Benzo(b)fluoranthene
39.48
252
116816
1.34 ng/uL
99
27)
Benzo(k)fluoranthene
39.63
252
94353
1.46 ng/uL
93
29)
Benzo(a)pyrene(CCC)
41.75
252
58241
1.37 ng/uL
98
31)
Indeno(1,2,3-cd)pyrene
52.76
276
62394
1.46 ng/uL
74
33)
Dibenz(a,h)anthracene
52.80
278
53855
1.46 ng/uL#
50
35)
Benzo(g,h,i)perylene
55.77
276
65904
1.41 ng/uL#
51
oceoifis
(#) = qualifier out of range (m) = manual integration
ENG1670.D PES3.M Mon Oct 18 15:36:21 1999 HP 5989B Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\ENG1670.D
Acq On : 15 Oct 99 10:38 pm
Sample : CARB429,MDL9
Misc :
Quant Time: Oct 18 15:30 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METH0DS\PES 3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial: 11
Operator:
Inst
HP 5989B
Multiplr: 1,00
Abundance
400000
350000
300000 .
250000 .
200000 .
150000
100000
50000
0
Time - - >
T X C • 16 / 0 • JU
4s
19S
10
12 11!
16
23
21
29
31
1
35
~lA
i—rr—[—i—i—i—?—|—i—i—?—i—|—i—i—i—i—i—i—t—i—i—i i 'i i"" \—|—i—it—i—p—i—i—i—i—i—t—r~
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0C03169
ENG1670,D P1S3.M
Mon Oct 18 15:36:30 1999
HP 5989B
Page 2
-------
Abundance
200000
100000
"TTC1 ENGTSTOTET
0
L
Time- -> 16.50 n.OO 17.50 18.00
I I ' I I
18l50
AbundaoqeIon 135.00 (135.70 to 136.70): BNG
lion 68.00 (67.70 to 68.70): ENG16
4000
2000
0
*""1—i—i—i—i—[—i—i—f—i—|—i—i—i—r—|—i—i—r~i—|—i—r*
[Time--> 16.50 17.00 17.50 18.00 18.50
Tirae-
->—i—f
17 I 60
17.80
100000 -
Time*
17 .60
17.80
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 17.69 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 13 6
Ion
136
68
0
0
Exp Ratio
100
15 .3
0.0
0.0
Abundance
mrnz——T%
JL JL Vw* * Ciliv JL u < U « Lr
200000
100000
#3
Naphthalene(CCC)
Concen: 1.27 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.01 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:128 Resp: 467993
Ion Ratio Lower Upper
128 100
12.6 0.0 63.0
0.0 0,0 0.0
0.0 0.0 0.0
—i *va—Trx / m 9% m—T7S—4. _—* a—pi jr-r frvf/s
ADUIiaance Ion. 128,UU (14,7 *70 to 128.70/: ENG
Ion 127.00 {126.70 to 127.70) : ENG
17 .73
200000
ENG1670.D PES3.M
ocoieo
Mon oct ia 15:36:34 iyyy
HP 5989B
Page 3
-------
Abundance
100000
TIC: ENG167U.D
50000
Time-->
T*"—i j—'—i i —'*—] 1 ! r~
19.30 19.40
4XUIC3 -»
abundance Ion 152.00 (151.70 to 152.70): ENG
150000 j
100000
50000
19.36
Time- - >
#4
2-Methlynaphthalene-dlO
Concen: 2.25 ng/uL
RT: 19.36 min Scan# 757
Delta R.T. -o.oi min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:152 Resp: 253497
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
TIC * 1R1X^57Q ¦ D
50000
—j—j—,—,—j—p—1—i i | t—r—i—i—|—i—r—i—i—i—i—i—r
Time - -> 20.50 21.00 21.50 22.00 22150
2000
1000
Time--> 20.50 21.00
_T J , y-
21.50
i—r—i—i—i—!—i—|—i—r
22.00 22.50
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT: 21.63 min
Lab File: ING1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 160
Ion Exp Ratio
100
0.0
0.0
0.0
Abundance Ion 150.00 (159.70 to 150.70): ENG
0CG31S
\sjl.
ENG1670 .D PES3.M
Mon Oct 18 15:36:36 1999
HP 5989B
Page 4
-------
Abundance
100000
Time-
TIC: ENG1670.D
I J 1
21.50
50000
21160
1 . p—1 , p-
21.70 21i 80
[AbundanceIon 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
100000 21.65
50000
0
Time-->
21,50
I 1 J 1 ! 1 1 ] ! 1 1"
21.60 21.70 21!80
#6
Acenaphthylene
Concen: 1.48 ng/uL
RT: 21.65 min Scan# 1301
Delta R.T. -0.01 min
Lab Pile: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:152 Resp: 185189
Ratio
100
12.9
0.0
0.0
Lower Upper
6.6 19.6
0.0 0.0
0.0 0.0
Abundance
150000
100000
50000
0
TIC: ENG1670.D
i—i—|—i—i—i—i—|—i—t—i—i—|—i—!—i—i—i—'—r
21.50 22.00 22.50 23.00
T* i TYjf***. 21 00
Abundance Ion 164.00 (163.70 to 164.70) : 2UG
2000
1000
0
(S
Time-->
1 I I r
21.00
~i t " i \ r~
21.50
22.00
t—T—[—s—i—r—i—|—i—r
22 .50 23l00
#7
Acenaphthene-dl0
Concen: 0.00 ng/uL
Expected RT: 22.04 min
Lab File: SNG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 164
Ion Exp Ratio
100
0.0
0.0
0.0
0CO122
ENGX6T0TD FE53TRT
Mon Oct 18 15:36:39 1999
HP 5989B
Page 5
-------
.Abundance
150000
100000
50000
Time--> 21.90
TIC; ENG1670.D
22100 ' 22!10 22:20
Abundance Ion 154.00 (153.70 to 154.70): eng
Ion 153.00 (152.70 to 153.70): ENG
80000 :
60000
40000
20000:
22 .11
T " '1 ! 1 T ! 1 1 ? 1 1 1 1 1 1 | !' I 1 ; [ I
frime --> 2i:90 22:00 22.10 22120
#8
Acenaphthene(CCC)
Concen: 1.47 ng/uL
RT: 22.11 min Scan# 1369
Delta R.T. -0.01 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:154 Resp: 160679
Ion Ratio Lower Upper
154 100
153 94.3 49.1 147.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000
100000
50000
TIC: ENGlbvo.D
T 1 1 I 1 ! f I ! 1 1 1 1 ! 1 ! ! r—T 1 1 ! 1 1 f~
Time--> 22.50 23.00 23.50 24.00
lUDunaancelon 176.00 (175.70 to 176.70): ENG
2000 .
1000
0
Time-->
22.50 23.00 23.50 24.00
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 176
Exp Ratio
100
0.0
0.0
0.0
ENGlb7U.D FES3.M
0CCM33
Mon Oct 18 15:36:41 1999
HP 5989B
Page 6
-------
Abundance
150000
100000
50000
Tirae-->
Abundance Ion 166.00 (165.70 to 166.70): ENG
TIC: ENG1670.D
23 .20
23130 23140
i—I—I—r
23 150
100000
JIon 165.00 (164.70 to 165.70)
23 .37
50000
Time-
n—r—i—i—i—i—i—|—!—i—i—i—j—t—i—i—i—|—i—i—i—r-
23.20 23.30 23.40 23.50
#10
Fluorene
Cancen: 1.46 ng/uL
RT: 23,37 win Scan# 1560
Delta R.T. -0.01 min
Lab Pile: 2NG1670.D
Acq; 15 Oct 99 10:38 pm
Tgt Ion:166 Resp: 166197
Ion Ratio Lower Upper
166
100
165
89.2
45.7
137.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
Time-
TIC: enG1o7u.D
¦ > 24 1 50
25.00 25.50 26.00 26.50
1000
—j f-
Time--> 24150
! 1 [—?—I—1—s 1—I—r
25 .00 25.50
_l 1 j ,
26 .00
1 1 [ 1 1 T
26.50
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 188
Exp Ratio
100
24.5
0.0
0.0
[AbundanceIon 188,00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94 .70) : ENG16
3000
2000
ENG1670 .D PES3 .M
OCC019
Mon Oct 18 15:36:44 1999
HP S989B
Page 7
-------
Abundance
150000
100000
I I I !—¦ ——1—W
TIC; 1NG1670.D
50000
Time--> 25.60 25170 25!80
AbuDdaoselon 178.00 {177.70 to 178.70): 2MG
Ion 176.00 (175.70 to 176.70): ENG
25.73
100000
50000
Time--> 25.60
2 5.70
25.80
Abundance
150000
100000 -
TIC: ENG1670.D
50000
u
L
Time--> 25:00 25 : 50 26i00 26.50
AbundanceIon 188.00 (187.70 to 188.70): 1NG
Ion 94.00 (93.70 to 94.70): ENG16
3000 '
1000
i—i—i—i—|—?—i—i—i—|—i—i—i—f—r—i—i—i—r™-|—i—i—i—p*
Time--> 25.00 25.50 26.00 26.50
#12
Phenanthrene
Concen: 1.45 ng/uL
RT: 25.73 min Scan# 1919
Delta R.T. -0.01 min
Lab File: SNG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:178 ReBp: 249495
2000
Ion
178
176
0
0
Ratio
100
19.8
0.0
0.0
Lower Upper
10.2
0,0
0.0
30.4
0.0
0.0
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 188
Ion Exp Ratio
188 100
94 26.6
0 0.0
0 0.0
ENG167U.D—PESi.M
Mon Oct IB 15:36:47 1999
HP 5989B
Page 8
-------
TIC: ENG1670.D
100000
50000 -
Time--> 25.70
25180 25.90
eIon 178.00 {177.70 to 178,70): ENG
lion 176.00 (175.70 to 176.70): ENG
26.00
25.85
100000 -
50000 .
Time—> 25.70
25.80
25.90
26.00
#14
Anthracene
Coneen: 1.71 ng/uL
RT: 25.85 min Scan# 1938
Delta R.T. -0.01 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:178 Reap: 179868
Ion Ratio Lower Upper
178
100
176
19 .1
10.0
29.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
—I—I—i—i—|—I—I—I—I—j—I—(—I—I—|—i—i—I—I—|—\—r
fTime--> 27 ! 50 28.00 28.50 29.00 29.50
TIC: ENG1670.D
Abundance Ion 212.00
Ion 106.00
15000
10000
5000
—j 1 1 , . , , , , 1 , , , , . , 5 j , j 1 , , r
fTime- - > 27 150 28.00 28.50 29.00 29.50
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 212
Exp Ratio
100
27.3
0.0
0.0
{211.70 to 212.70) : IMS
(105.70 to 106.70): ENG
0CC31S
O
ENG1670.D PES3 .M
15:36:49 1999
HI 5989B
Page 9
-------
Abundance
TIC: ENG1S70-D
100000 -
\
50000 -
j{
0 -
Time-->
28.60 28.80
(AbundanceIon 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
28.72
100000 .
A
50000 -
A
j/\
y -
Time - - >
28.60 28.80
#16
Fluoranthene(CCC)
Concern l.40 ng/uL
RT: 28.72 min Scan# 2376
Delta R.T. -0.01 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pra
Tgt Ion:202 Resp: 232703
Ion Ratio Lower Upper
202
100
101
24 .6
12.1
36.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
TIC: ENG1670.D
0
Time-->
i—i—i—i—j—i—i—!—i—| i i \—r—!—r~i—r~i—j—r~r
28.50 29.00 29.50 30.00
T
¦VTL 3 f H K Pi A' *f A L. m HI m M \ ilHTjH
AbundanceIon 212.00(211.70 to 212.70):ENG
Ion 106.00 (105.70 to 106.70): ENG
15000 :
10000
5000
0
Time - ->
n—I—?—i—t—1 ! !—|—I—I—!—I—| J—I—I !—|—I—S—1—r
28.50 29.00 29.50 30.00
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 212
Exp Ratio
100
31.6
0.0
0.0
ENG1670.D—PESTTTT
0003107
m p- my* mm- m.
Mon Oct1815:36:531999
HP 5989B
Page 10
-------
Abundance
150000
100000
50000
TIC: ENG1S70.D
Time-->
29.20
29.40
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70) : ENG
29.33
100000
50000
:ime-
29.20
29.40
#18
Pyrene
Concen: 1.37 ng/uL
RT: 29.33 min Scan# 2467
Delta R.T. -0.01 min
Lab File: ENG1670.D
Acq; 15 Oct 99 10:38 pm
Tgt Ion:202 Resp: 254468
Ion Ratio Lower Upper
202 100
101 28.3 13.9 41.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1670.D
150000
100000
#19
p-Terptienyl-dl4
Concen: 2.41 ng/uL
RT: 29.61 min Scan# 2510
Delta R.T. -0.01 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:244 Resp: 269938
50000 .
Time-
,—,—, f—.—,—,—, r
29.40 29.50 29160
29 J 70 29 180
Ratio
100
32.2
0.0
0.0
Lower Upper
14.6
0.0
0.0
43.7
0.0
0.0
Abundance Ion 244.00 (243.70 to 244.70): ENG
|Ion 122 .00 (121.70 to 122.70) : ENG
29.61
100000
50000 _
Time--> 29.40 29.50
29:60
' 1 i
29 .70
29.80
ENG1670.D—PES3 .M
0003133
Mon Oct 18 15:36 :56 1999'
HP 59891
Page 11
-------
TIC: ENG1670.D
60000
40000
20000
Time-->
"i—i—i—I—i—i—i—i—I—i—i—i—i—i—i—<—i—i—|—i—i—i—r
32,50 33.00 33.50 34100
Abundance Ion 240.00 (239.70 to 240.70): BNG
Ion 120.00 (119.70 to 120 .70) : ENG
4000
2000
Time-
i—i—i—|—i—f—i—i—i—i—i—i—i—|—i—*—i—i—|—i r i"' i1
32.50 33.00 33 .50 34100
60000H
40000
20000
i ! r i 1 1—i r—i 1 1 1 { ! 1—i—r
TVi mp- - 31 10 13 40 13 50
J> X lllC J J • V J J i « W a}*} * af u
#20
Benzo(a)anthracene-dl2
Coneen: 0.00 ng/uL
Expected RT: 33.36 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.9
0 0.0
0 0.0
Abundance
60000.
TIC: SNG1670.D
40000 .
\ \
20000 I
J
0 .
Time-->
33130
33140 33.50
EHG"
Ion 114.00 (113.70 to 114.70) : ENG
33.43
#21
Benzo(a)anthracene
Concen: 1.48 ng/uL
RT: 33.43 min Scan# 3084
Delta R.T. -0.03 min
Lab File: ENG167G.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:228 Resp: 127240
Ion Ratio Lower Upper
228 100
114 26.1 12.8 38.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0C031S3
ENGlfeVO.D—PESJ.M
Mon Oct 18 15:36:58 1999
HP 5989B
Page 12
-------
Abundance
60000
40000
20000
TIC: ENG1670.D
32150
-r—i—i—r—i—i—p—i—i—i—i—|—i—i—i-
33.00 33.50 34 ! 00 34!50
Time- ->
abundanceIon 240.00 (239.70 to 240.70):
Ion 120.00 (119.70 to 120.70): ENG
4000
2000
0
Time-
1 1—! 1 1 I I 1—I I I [ i—T
32.50 33.00 33.50
i—rp"'i' i—i—r—i—r
34.00 34.50
20000
Time--> 33.40 33:60 33i80
AbundanceIon 228.00 (227.70 to 228 .70)
60000
lion 114.00 {113.70 to 114.70)
33.59
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.50 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion;
Ion
240
120 ¦
0
0
240
Exp Ratio
100
27.3
0.0
0.0
TIC: ENG1670.D
60000
40000
#23
Chrysene(CCC)
Concen: 1.33 ng/uL
RT: 33.59 min Scan# 3108
Delta R.T. -0.02 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:228 Resp: . 164506
Ion Ratio Lower Upper
100
23.9 11.2 33.5
0.0 0.0 0.0
0.0 0.0 0.0
40000
20000
I 1 1
33.80
Time
33 .40
33 .60
ENGTSTOTD PES3.M
Won Oct IB 15:37:01 1995
HP 5989B
Page 13
-------
Abundance
40000
TIC: ENGievu.D
30000
20000
10000
Time--> 38150 39.00 39150 40 100
AbundanceIon 264.00 (263,70 to 264.70): ENG
ion 132.00 (131.70 to 132.70): ENG
4000 -
2000 -
Time-
-I ! 5 1 1 1 1 1 1 1 1 1—I r—1 1 'M I f -' I \ > i
38.50 39.00 39.50 40.00
#24
Benzo(b)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab File*. ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 264
Exp Ratio
100
69 .4
0.0
0.0
Abundance
TIC: ENG1670.D
40000 :
30000 -
20000:
ioooo :
n
*" J r I \ I 1 1 1 1 i i i >
Time--> 39.30 39.40 39.50
39 1 60
Abundance Ion 252.00 (251.70 to 252.70): ENG
30000 .
Ion 126.00 (125.70 to 126.70) : ENG
39.48
20000 -
10000
0
rime--> 39!30 '39140' 39150'
i ! i i i i
39 .60
#25
Benzo(b)fluoranthene
Concen: 1.34 ng/uL
ET: 39.48 min Scan# 4013
Delta R.T. -0.04 min
Lab Pile: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:252 Resp: 116816
ENG167U.D PE53TW
Ion
252
126
0
0
Ratio
100
28.5
0.0
0.0
Lower Upper
14 .0
0.0
0.0
41.8
0.0
0.0
OCG-J201
Mon Oct 18 15:37:07 lyyy
HP 5989B
Page 14
-------
Abundance
40000
30000
20000
10000
TIC: ENGlbvO.D
Time--> 38.50 39)00 39:50* '40100 Vol^O*
Abundance Ion 264.00 (263.70 to 264.70): ENS
Ion 132.00 (131.70 to 132 .70) : ENG
4000 -
2000-
*1 J P r i r~
Time--> 38.50 39.00 39.50 40.00 40.50
#26
Benzo(k)fluoranthene-dl2
Concen; 0.00 ng/uL
Expected RT; 39.53 min
Lab Pile: 1NG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 264
Ion Exp Ratio
264 100
132 35.8
0 0.0
0 0.0
Abundance
TIC: SNS1S70
.D
40000.
30000 :
20000:
ioooo :
0 -
Time-->
39! 40' ' ' 39! 60
1 ' I 1
39; 80
Abundance Ion 252.00 (251.70 to
252.70):
emg
30000 .
Ion 126.00 (125.70 to
126.70) :
ENG
A 39.63
20000
10000 .
0 -
Time - - >
1 ! i i > | i i
39.40 39.60
, i j i
39.80
#27
Benzo(k)fluoranthene
Concen: 1.46 ng/uL
RT: 39.63 min Scan# 4036
Delta R.T. -0.03 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:252 Resp: 94353
Ion
252
126
0
0
Ratio
100
31.5
0.0
0.0
Lower Upper
13.9
0.0
0.0
41.5
0.0
0.0
0CC32C2
HP 5989B
Page 15
-------
TIC; enGi€70. D
20000
10000
-j—i "T" "i—i—|—i—r
40.50 41.00
r—i—i—i—i—i—i—r
42100 42150
Time-
ftbundanceIon 264.00 (263.70 to 254.70): ENG
Ion 132 .00 (131.70 to 132.70) : ENG
4000
2000
0
Time-
—|—i—i—i—i—|—r—i—i—i—|—i—i—i—i—i—i—i—i—i—j—j—r
•> 40.50 41.00 41.50 42.00 42.50
#28
Benzo (a) pyrene-d.12
Concen: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 264
Exp Ratio
100
37.8
0.0
0.0
Abundance
20000
Time--> 41.40
TIC: 2MG1S70.D
10000
0
41.60
41.80
42100
Abundance Ion 252.00 (251.70 to 252.70): ENG
15000 Jlon 126.00 (125.70 to 126.70): ENG
41.75
10000
5000
i 1 1 1 1 1 1 1 1—i 1 1 1 f 1 ] 1 1 r
|Time--> 41.40 41.60 41.80 42.00
#29
Benzo(a)pyrene(CCC)
Concen: 1.37 ng/uL
RT: 41.75 min Scan# 4361
Delta R.T. -0.04 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:252 Resp:
Ion
252
126
0
0
Ratio
100
30.1
0.0
0.0
58241
Lower Upper
15.7
0.0
0.0
HP 5989B
46.9
0.0
0.0
o
! J
Page 16
-------
Abundance
20000
10000 .
TIC: ENG1670.D
Time--> 52.00 53.00 54.00
aHnnan<-c>Tri'n—3TFH—iTTi—~-<->" Oflfl—*ft\ \ .—IMF
aDunaance jlqji aoo . uu \zo / » /u wu zoo. / u / .
2000
1000
Time-->
" ? 1 ! ! 1 ! 1 1 1 1 1 1 ! 1 [ 1 r-
52.00 53.00 54.00
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 52.54 min
Lab Pile; ENG1670, D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
abundance
TIC: ENG1670.D
20000.
/\_
10000 ^
0 .
Time-->
52.40 52.60 52.80 53.00
Abundance Ion 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
52 .76
5000 _
0 -
/
Time-->
52.40 52.60 52.80 53.00
#31
Indeno(1,2,3-cd)pyrene
Concen: 1.46 ng/uL
RT: 52.76 min Scan# 6067
Delta R.T. -0.06 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:276.05 Resp: €2394
Ion Ratio Lower Upper
276
138
100
40.4
0.0
0.0
30.1
0.0
0.0
90.2
0.0
0.0
0CG3204
ENGT670.D PES3TM
Mon Oct 18 15:J7:1b ±319
HP 5989B
Page 17
-------
Abundance
20000
TIC: EMG1670.D
10000
0
Time--> 52.00 53:00
Abundance Ion 292.00 (291.70 to 292.70): ENG
2000 .
1000
0
Time-->
Abundance
20000
52.00
53 loo
TIC: ENG1670.D
10000
0
T
Time- -> 52 .40
Abundance t on 2*78
t—r-"i—i i
52.60
"< i | «
52.80
1 ] T
53.00
8000 -
6000
4000
2000
00 (277.70 to 278.70):
Ion 139.00 (138.70 to 139.70):
52 .80
1—r
Time--> 52 .40
ENGT6T0TD PES3 .M
i
#32
Dibenz(a,h)anthracene-dl4
Concern 0.00 ng/uL
Expected RT: 52.50 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 292
Ion Exp Ratio
292 100
0 0.0
0 0.0
0 0.0
#33
Dibenz(a,h)anthracene
Concen: 1.46 ng/uL
RT: 52.80 min Scan# 6075
Delta R.T. -0.06 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:278 Resp: 53855
Ion Ratio Lower Upper
278
100
139
17 .6
26.9
80.5#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
"EMT
ENG
ocem:
—i—[—!—i—i—i—r—i—i—tt—|—i—
52.60 52.80 53.00
Mon Oct 18 15:37:19 1999'
HP 5989B
Page 18
-------
TIC: ENGlbvO,D
lOOOO -
5000
Titus ~ - >
Abundance Ion 268.00 (287.70 to 288.70): ENG
56 .00
55.00
2000 -
1000 -
Time-->
55.00
56.00
#34
Benzo(g»h,i)perylene-dl2
Concen: 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
(Abundance
TIC: SMG1670.B
~l
10000
5000
#35
Benzo(g,h,i)perylene
Concen: 1.41 ng/uL
RT: 55.77 min Scan# 6655
Delta R.T. -0.07 min
Lab File: ENG1670.D
Acq: 15 Oct 99 10:38 pm
Tgt Ion:276 Resp: 65904
Ion Ratio Lower Upper
i | i i i r-1 r—
55.40 55.60
Time-->
AbundanceIon 276.00
Ion 138.00
t—i—|—i—r
55.80
56.00 56.20
(275.70 to 276.70)
{137.70 to 138.70)
55.77
ISlMvjr
ENG
5000
276
100
138
37.2
6.5
26. 0#
0
0.0
0.0
0,0
0
0.0
0.0
0.0
000200
:ime-->
Sw/ him i«i' ¦ whu i" far-
NG1670.D PES3.M
n—|—i—i—? i | t i—i—i—j—r—i—till—i—i—i—i—i—r
55.40 55.60 55.80 56.00 56.20
Man Oct 18 15:37:23 199?
HP 59891
Page 19
-------
Response Factor Report HP 5989B
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES 3.M
Mon Oct 18 14:41:01 1999
Initial Calibration
Calibration Files
.1 =ENG1654.D
1 =ENG1657.D
Compound
25 =ENG1655.D
i =ENG1658.D
,1 .25
.5
=ENG1656.D
=ENGl659.D
Avg
%RSD
2,2-Difluorobiphenyl
s Naphtha1ene-d8 3,
Naphthalene(CCC) 4.
s 2-Methlynaphthalene
s Ac enaphthy1ene-d8 0.
Acenaphthylene 1,
s Acenaphthene-dl0 0.
Acenaphthene(CCC) 1,
s Fluorene-dlO 0.
Fluorene 1,
s Phenanthrene-dlO 1,
Phenanthrene 1.
s Anthracene-dlO
Anthracene 0,
s Fluoranthene-dlO 1.
Fluoranthene(CCC) 1
s Pyrene-dlO 1
Pyrene l
S p-Terphenyl-dl4
s Benzo(a)anthracene- 0
Benzo(a)anthracene 0
s Chrysene-dl2 0
Chrysene(CCC) 0
s Benzo(b)fluoranthen 0
Benzo(b)fluoranthen 0
s Benzo(k)fluoranthen 0
Benzo(k)fluoranthen 0
s Benzo(a)pyrene-dl2 0
Benzo(a)pyrene(CCC) 0
s Indeno(1,2,3-cd)pyr 0
Indeno(l,2,3-cd)pyr 0
s Dibenz(a,h)anthrace 0
Dibenz(a,h)anthrace 0
s Benzo(g,h,i)perylen 0
Benzo(g,h,i)perylen 0
624
076
877
063
943
093
979
159
379
710
798
104
535
139
675
364
657
708
967
395
,657
378
, 448
.238
.291
.247
.319
.146
.249
.253
.362
3 .259
3 .825
1.157
0.771
0.995
0.860
0.997
0.850
1.046
1.173
1.560
0.732
0.956
1.371
1.059
1.540
0.327
0.610
0.637
0 .961
0 .397
0.616
0.370
0,428
0.203
0 .277
0.205
0.267
0.132
0.229
0.237
0.322
3 .202
3 .410
1.108
0.844
0.991
0.855
0.912
0.878
0.962
1.323
1.519
0.787
1.120
1.402
1.251
576
036
402
664
0.827
1.036
0,501
0.698
0 .482
0.511
0.248
0.347
0.298
0.339
0.166
0 .298
0.312
0.384
¦ISTD--
2.714
3 .014
0 .888
0 .849
1.052
0.776
0.934
0.822
0.936
1.152
1.456
0 ,575
0.990
1.114
1.453
1.270
1.626
0.948
0.491
0.718
0,833
1.062
0.493
0.729
0.481
0.544
0.252
0.355
0 .298
0.367
0 .172
0 .294
0.308
0.402
2,178
2 .579
0.874
0.911
1.173
0.858
0.881
0. 770
0.911
1.075
1.381
1.066
1.126
1.458
1.292
1.627
0.970
0.530
0.857
0,891
1.170
0.575
0 .865
0.599
0,668
0.302
0.429
0.332
0 .413
0 .219
0 .382
0 .354
0 .448
1
1
1
1.991 2
2.418 3
0.882 0
0.958 0
1.266 1
0.808 0
0.888 0
0.742 0
0.915 0
1.031 1
1.355 1
0
1,132 0
1,095 1
1.477
1- * 2 ,3
1.634
0.943 0
0.582 0
0.975 0
0.938 0
1.258 1
0.622 0
0.995 0
0.693 0
0.776 0
0.352 0
0.516 0
0.386 0
0.530 0
0.249 0
0.473 0
0.410 0
0.522 0
.828
.220
.982
.868
,090
,850
.951
.840
.988
.189
.497
.575
,917
.086
.450
.212
.613
.974
.449
.747
.806
.076
.497
.760
. 500
.563
.266
.369
.295
.372
.181
.321
.312
.407
22 .88
20.75
14.15
7.38
9.96
6.65
8.54
10 .05
9 .82
11.51
8.73
0.00
18,18
5.95
3 .97
7 .62
2.96
4.37
22.34
18.85
14.02
10.92
18.50
18.82
25.16
24.00
19 .96
24 .34
21.48
24.53
24.90
28.47
20.45
17.26
oce ~)3
(#) = Out of Range
PES3 .M
Mon Oct 18 14:43:53 1999
HP 5989B
-------
Quantitation Report
C:\HPCHEM\1\DATA\ENG1654.D
14 Oct 99 7:32 pm
CARB429,ICALO.1
Data File
Acq On
Sample
Misc :
Quant Time: Oct 18 14:27 1999
Vial: 2
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method
Last Update
Response via
C:\HPCHEM\1\METH0DS\PES3.M
Mon Oct 18 14:27:39 1999
Multiple Level Calibration
Internal Standards
R.T, Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
20 .01
190
957920
5 .00
ng/uL
-0.02
lystem Monitoring Compounds
%Recovery
2)
Naphthalene-d8
17.70
136
69428
0.18
ng/uL
4.39%
4}
2-Methlynaphthalene-dlO
0.00
152
0
0.00
ng/uL
0.00%
5}
Ac enaphthylene-d8
21.64
160
16793
0.10
ng/uL
2.42%
7)
Ac enapht hene-d10
22 .05
164
18065
0.11
ng/uL
2.84%
9)
Fluorene-dlO
23 .32
176
18757
0.12
ng/uL
2.99%
11)
Phenanthrene-dl0
25.69
188
26429
0.12
ng/uL
3.01%
13)
Anthracene-dlO
25,82
188
1379
0.03
ng/uL
0.72%
15)
Fluoranthene-dl0
28.69
212
21155
0.10
ng/uL
2 .48%
17)
Pyrene-dlO
29.30
212
21828
0.09
ng/uL
2.29%
19)
p-Terpheny1-d14
0.00
244
0
0.00
ng/uL
0.00%
20)
Benzo(a)anthracene-dl2
33.38
240
6978
0.08
ng/uL
1.95%
22)
Chrysene-dl2
33 .51
240
13570
0.09
ng/uL
2.29%
24)
Benzo(b)fluoranthene-dl2
39.37
264
7560
0 .10
ng/uL
2 .42%
26)
Benzo(k)fluoranthene-di2
39 .53
264
7245
0.08
ng/uL
2,05%
28)
Benzo{a)pyrene-dl2
41.64
264
4551
0.10
ng/uL
2 .55%
30)
Indeno(1,2,3-cd)pyrene-dl2
52.58
288
4732
0.09
ng/uL
2 .23%
32)
Dibenz(a,h)anthracene-dl4
52 .53
292
2793
0.08
ng/uL
2 .04%
34)
Benzo(g, h, i)perylene-dl2
55 .54
288
4853
0.10
ng/uL
2.41%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.75
128
78092
0.17
ng/uL
98
6)
Acenaphthylene
21. 67
152
20361
0.10
ng/uL#
60
8)
Acenaphthene(CCC)
22.13
154
20938
0.12
ng/uLm
91
10)
Fluorene
23.39
166
22198
0.12
ng/uL
80
12)
Phenanthrene
25.75
178
32768
0.12
ng/uL
100
14)
Anthracene
25.88
178
15282
0.09
ng/uL#
60
16)
Fluoranthene(CCC)
28.73
202
29410
0.11
ng/uL
92
18)
Pyrene
29 .34
202
32094
0 .11
ng/uL
98
21)
Benzo(a)anthracene
33 .47
228
12592
0 .09
ng/uL#
50
23)
Chrysene(CCC)
33 .62
228
18534
0.10
ng/uL#
59
25)
Benzo(b)fluoranthene
39.53
252
12588
0.10
ng/uL#
48
27)
Benzo(k)fluoranthene
39.68
252
8581
0.09
ng/uL#
49
29)
Benzo(a)pyrene(CCC)
41.80
252
5581
0.09
ng/uL#
4 8
31)
Indeno(1,2,3-cd)pyrene
52.86
276
6106
0.10
ng/uLm
0
33)
Dibenz(a, h)anthracene
52 .92
278
4772
0.09
ng/uLm
0
35)
Benzo(g,h,i)perylene
55.88
276
6942
0.11
oee
ng/uLm
•~tj ;7 7 n
-i 4 ' . ft
s:.. -£
0
(#) = qualifier out of range (m) - manual integration
-KM.,.,, U„ — ^
-------
Quantitation Report
Data Pile
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DATA\ENG1654.D
14 Oct 99 7:32 pm
CARB42 9,ICALO.1
Oct 18 14:27 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Men Oct 18 14:27:39 1999
Multiple Level Calibration
Vial;
Operator;
Inst ;
HP 5989B
Multiplr: 1.00
TIC: EMG1S54.D
Abundance
650000
600000
550000
500000
450000
400000
350000
300000
250000
200000
150000
100000
50000
0
Time-->
2^3
J
0 ll
S 1*
381
31S
i i—f—i—i—-i—|—i—i—?—r—( f i—r i i—r—t—!—e—j—I—s—i—r—I—i—r~~i—r—i—i—i—i—i—i r ¦
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55100
OCOiio
ENG1654.D PES3.M
Mon Oct 18 14:28:08 1999
HP 5989B
Page 2
-------
(Abundance
40000 ^
20000
TIC: ENG1654.D
0 ¦, | i—,—i i- | i
Time--> 17.50 17.60
Abundance Ion 136.00
40000 lIon 68-00
30000
n—i—{—\—i—i—i—i—i—!—i—r
17.70 17.80
135.70 to 136.70}: ENG
67.70 to 68.70); ENG16
17.70
20000
10000
0
i—?—r -i "i—i—it—i—i—i—i—f r i—i—r—r-~i—\—r
frime - - > 17.50 17.60 17.70 17.80
Time--si 7.50
Abundance Ion 128.00
Ion 127.00
40000
30000
20000
10000
17.60 17.70 17.80 17190
Time--517.50
ENG1654 .D PES3.M
' 1 f"
17.60
#2
Naphthalene-d8
Concen: 0.18 ng/uL
RT: 17.70 min Scan# 253
Delta R.T, -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt ion:136 Resp: 69428
Ion Ratio Lower Upper
136
100
68
12 .9
3.9
11.5#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1654.D
40000
20000
#3
Naphthalene(CCC)
Concen: 0.17 ng/uL
RT: 17.75 min Scan# 260
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:128 Resp: 78092
Ion Ratio Lower Upper
128
100
127
13 .1
0.0
62.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
;i27.70 to 128.70): ENG
{126.70 to 127.70): ENG
17.75
"T—I—I—I—I—I—I—I—I—I—P—r
17.70 17.80 17.90
Mon Oct 18 14:28:12 lyyy'
OCC
HP 5989B
Page 3
-------
Abundance
20000 -
—T—!—I—I—]—I—I—I—!—j—I—I—»—I—|—I—i—1—I—!—I—1—r-
Time--> 20150 21.00 21.50 22.00 22.50
TIC: ENG16S4.D
10000
AbundanceIon 152.00 (151.70 to 152.70): eng
10000
5000
t—f—i—i—i—i—r~i—i—|—i—i—i—r~*i—r—i—r—i—]—i—r~i—r
frime--> 20:50 21.00 21.50 22.00 22.50
Abundance
15000
10000
5000
TIC: ENG1654.D
Time--> 21!50
—I—i—r-
21.60
—i 1 1 1 1 1 r
21.70
Abundance Ion 160.
10000
5000
utr
21.64
160.705 : ENG
Time--> 21.50
ENG1654.D PES3 ,M
#4
2-Methlynaphthalene-dl0
Concen: 0.00 ng/uL
Expected RT: 21.68 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
#5
Acenaphthylene-d8
Concen; 0.10 ng/uL
RT: 21.64 min Scan# 1299
Delta R.T. -0.02 min
Lab Pile: ENG1654.D
Acq:
14 Oct
99 7
:32 pm
Tgt
Ion:160
Resp:
16793
Ion
Ratio
Lower
Upper
160
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
oeev:
21.60 21.70
"Mon Oct IB "14: 28:15 199"?
HP 5989B
Page 4
-------
iAbundance
I
j
! 15000
10000 J
5000
fTime - -> 21150 2l!eb 21! 70 21.80
TIC: ENGlb54.D
Abundance Ion 152,00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
21.67
10000
5000
, , , , , , f f—| j j 1 1 j p-
fTime--> 21150 21.60 21.70 21.80
j I i l I | i i —r—— I ? r -- f— f I 1 1-
Time - - > 21.95 22.00 22.05 22.10
#6
Acenaphthylene
Concen: 0.10 ng/uL
ET: 21.67 min Scan# 1304
Delta R.T. -0.01 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:152 Resp: 20361
Ion Ratio Lower Upper
152
100
153
0.0
8.7
25 .9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC- BNGlb54.D
20000
10000
Abundance Ion 164.00 (163.70 to 164.70): ENG
10000
5000
22.05
Time--> 21195
ENGlbb4 .L) PESTTH"
n—.—j_,—r
22.00
#7
Acenaphthene-dl0
Concen: 0.11 ng/uL m
RT: 22.05 min Scan# 1361
Delta R.T. -0.01 min
Lab File: SNG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:164 Resp: 18065
Ion Ratio Lower Upper
164
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ocoo
—t—|—,—,—,—,—p—5—j—; | ¦¦ -i—r
22 .05 22.10
Mon Oct 18 14:28:18 1999'
HP 5989B
Page 5
-------
TIC: ENG1654.D
Abundance
20000
10000
Time
>22.00
22.05
22 .10
22 .15
22.20
Abundance Ion
15000 -ilon 153.00
10000
to 154.10): SNG
(152.70 to 153.70): SNG
22.13
5000
"1 1 1 J 1 F 1 1 1 j 1 1 ! 1 1 1 1 1 1 1 1
Time-->2 2!00 22.05 22 .10 22.15 22 .20
#8
Acenaphthene{CCC)
Concen: 0.12 ng/uL m
RT: 22.13 min Scan# 1372
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:154 Resp: 20938
Ion Ratio Lower Upper
154
100
153
103 .6
45 .5
136 .3
0
0.0
0.0
0.0
0
0.0
o.o
0.0
Abundance
20000
TIC: ENG1654.D
10000
0
T
Time--> 23.20 23.30 23.40
Abundance Ion 17 6.00 (175.70 to 176.70): ENG
23 .32
10000
5000 .
#9
Pluorene-dlO
Concen: 0.12 ng/uL
RT: 23.32 rain Scan# 1552
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:176 Resp: 18757
Ion Ratio Lower Upper
176
100
0
0.0
0.0
0.0
0
0.0
0-0
0.0
0
0.0
0.0
0.0
Of
0
Time--> 23.20 23.30 23.40
ENGT6BT7I3 PES3 . M Mon Oct 18 14:28:21 lW
HP 5989B
Page 6
-------
TIC: ENGTF547D
20000
10000
1 i ! T"
Time--> 23:20 23130 23:40 23:50
Abundance Ion 166,00 (165,70 to 166.70): ENG
15000 HIon 165.00 (164.70 to 165.70): ENG
23 .39
10000 j
5000
0
Time--> 23:20 23:30 23:40 23:50
#10
Fluorene
Concen: 0.12 ng/uL
RT: 23.39 min Scan# 1563
Delta R.T. -0.01 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:166 Resp:
Ion Ratio Lower
22198
Upper
166
100
165
93 .5
38.3
114.7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
[Abundance
30000
20000
TIC: ENG1654.D
10000
0
fTime--> 25.60 25:70 25.80
Abundance Ion 188.00 (187.70 to 188.70): ENG
lion 94.00 (93.70 to 94.70): ENG16
15000 25.69
10000
5000
#11
Phenanthrene-dl0
Concen: 0.12 ng/uL
RT: 25.69 min Scan# 1913
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:188 Resp: 26429
Ion Ratio Lower Upper
188 100
94 21.9 5.8 17.2#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCOi
Time--> 25.60
ENG163"4 7D PE537M
25.70 25:80
Mon Oct" 18 14:28:24 1999'
HP 5989B
Page 7
-------
Abundance
30000
20000 -
Time - - >
TIC: ENG1654.D
10000
0
25.65 25.70 25.75 25.80 25.85
Abundance Ion 178.00 (177.70 to 178.70): EN<3
Ion 176.00 (175.70 to 176.70): ENG
20000 ' 25.75
15000
10000
5000
T 1 1 1 1 1 r—I 1 1 1 1 1 [ I 1 1 1 J 1 I ! ! 1 1 T"
Time--> 25.65 25.70 25.75 25.80 25.85
#12
Phenanthrene
Concen: 0.12 ng/uL
RT: 25.75 min Scan# 1921
Delta R.T. -0.02 min
Lab Pile: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:178 Resp: 32768
Ion Ratio Lower Upper
178
100
176
20.6
10 .3
30.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1654.D
30000 -i
20000 J
\
10000 .
v V
0 '
! ii i t 1 t 1 1 1 1 1 I
Time--> 25.75 25.80 25.85
Abundance Ion 188.00 (187.70 to 188.70): ElJG
3000 .
Ion 94.00 (93.70 to 94 .70) : ENG16
25.82
2000
1000
0 .
• j • i ' ' | ' i i i | f i i i j
Time--> 25.75 25.80 25.85
SNG1654.D FE5T7W
#13
Anthracene-dlO
Concen.- 0.03 ng/uL m
RT: 25.82 min Scan# 1933
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq:
14 Oct
99 7
: 32 pm
Tgt
Ion:188
Resp:
1379
Ion
Ratio
Lower
Upper
188
100
94
89.2
6.6
19 .6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CCJ-2ti
MOn OCt 18 14:26:27 iy99
HP 5989B
Page 8
-------
Abundance
" 30000
20000 .
10000
Time-
TIC: EMG1654.D
25.80
1 r
25.90
Time
15000
10000
5000
#14
Anthracene
Concen: 0.09 ng/uL
RT: 25.88 min Scan# 1941
Delta R.T. -0.02 min
Lab File; ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:178 Resp: 15282
Ion Ratio Lower Upper
178
100
176
0.0
8.9
26.5#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance ion 178.00 1177.70 to 178.70}: ENG
Ion 176.00 (175.70 to 176.70): ENG
20000 1
25.88
25.80
25 .90
Abundance"
20000
10000
0
TIC: ENG1654.D
Time--> 28.50 28.60 28.70 28.80
Abundance Ion 212.00 (211.70 to 212.70)
#15
Fluoranthene-dlO
Concen: 0.10 ng/uL
RT: 28.69 min Scan# 2372
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:212 Resp: 21155
Ion Ratio Lower Upper
212
100
106
26.8
8.0
23 .8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Ion 106.00
(105.70 to 106.70):
28.69
-mr
ENG
10000 -
5000
oecj^*
AI /C
0 J
Time-~> 28.50
ENGT5517B—PES 3 .M
!——r—1 1 1 ! (—i—\ f—I 1 1—i—
28.60 28.70 28.80
Mon 0ct 18 i4:28:30 1999'
HP 5989B
Page 9
-------
Abundance
20000
Tj'C:—EKGKS4 I'D"
10000
~l—I—r
28.80
T
5000
#16
Fluoranthene(CCC)
Concen: 0.11 ng/uL
RT: 28.73 rain Scan# 2379
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tine--> 28.60
Abundance Ion 202.00 (201.70 to 202.70): EMG
Ion 101.00 (100.70 to 101.70): ENG
15000 . 28.73
10000
Tgt Ion:202 Resp-.
ion Ratio Lower
202 100
101 23.2 9.9
0 0.0 0.0
0 0.0 0.0
29410
Upper
29.6
0.0
0.0
Time-
28.60
~ ~
28.80
Abundance
TIC: ENG1654
.D
30000 .
20000 J
10000 -
0
Time-->
S I t 1 r < | T
29.20 29.30
1 1 r i ¦"
29.40
Abundance Ion
212.00 (211,70 to
212.70):
ENG
Ion
106.00 (105.70 to
106.70):
ENG
29 .30
10000 .
5000-
0 .
Time-->
29.20 29.30
iii
29.40
#17
Pyrene-dlO
Concen: 0.09 ng/uL
RT: 29.30 min Scan# 2463
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion-.212 Resp: 21828
Ion Ratio Lower Upper
212 100
106 31.9 8.6 25.6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENGX55¥7D PES3.M
OCCj-i-33
Mon Oct 18 14:28:33 1999
HP 5989B
Page 10
-------
Abundance
TIC: ENU1654.D
30000 .
/\A
20000 J
J v.
10000 J
0 -
Time- - >
29.20 29.30 29.40 29.50
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
29.34
15000
10000
A
5000
/A
j ^
0 -
Time~->
I i i i i ( k 111 1 'i i i i 1 i i k s i i r i
29.20 29.30 29.40 29.50
#18
Pyrene
Concen: 0.11 ng/uL
RT: 29,34 min Scan# 2470
Delta R.T. -0.02 min
Lab File: ENG1654.D
Acq; 14 Oct 99 7:32 pm
Tgt Ion:202 Resp: 32094
Ion Ratio Lower Upper
202
100
101
27 .5
14.3
42.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
30000
20000 -
10000
t—I—i—I 1—I—I 1—I—|—I—l—i—I—|—i—5 1 * i—I—r
Time- -> 28!50 29.00 29.50 30.00 30.50
Abundance ion 244.00 (243 .70 to 244.70)
TIC: ENG1654.D
3000 lion 122.00 (121.70 to 122.70)
2000
1000 -
1H5T
ENG
k
i • r
ime--> 28.50
i—1—I—I—r
29 .00
i—*i—|—i—i—i—i—I—r—i—r—i—|—i—i—i—i
29.50 30.00 30.50
#19
p-Terphenyl-dl4
Concen*. 0.00 ng/uL
Expected RT: 29.65 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion: 244
Ion Exp Ratio
100
13 .2
0.0
0.0
ENG1654 ID—PEST'l'M'
OCC->2€4
Tfon Oct 18 14:28:36 1999
HP 5989B
Page 11
-------
Abundance
20000
15000
10000 :
5000
Time-
TIC: ENGlb54.D
33 .30
33.40
5000
0
33.38
[Time-
33.30
i I i r
33 .40
Abundance
20000 j
Time-->33 .30
33 .40
33 .50
33 160
#20
Benzo(a)anthracene-dl2
Concen: 0.08 ng/uL
RT: 33.38 min Scan# 3075
Delta R.T. -0.03 min
Lab Pile: SNG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:240 Resp:
Ion Ratio Lower
240 100
0.0
0.0
0.0
7.3
0.0
0.0
6978
Upper
21.8#
0.0
0.0
Abundance Ion 240.00 (239.70 to 240.70): ENG
r IOUUO ^lQn 120.00 {119.70 to 120.70): ENG
TIC: EnG1&54.D
15000
10000
5000
Abundance Ion 228.00 (227.70 to 228.705: ENG
Ion 114.00 (113.70 to 114.70): ENG
8000
6000
4000
2000
0
33 .47
Time--> 33 ITS"
33.40
33.50
~t 1 j 1 r
33160
ENGUS4.D fEHJ.M
#21
Benzo(a)anthracene
Concen: 0.09 ng/uL
RT: 33.47 min Scan# 3089
Delta R.T. -0.03 min
Lab File: BNG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:228 Resp: 12592
Ion
228
114
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
12.8
0.0
0.0
38.2#
0.0
0.0
0CC.3*£;
Mon Oct IB 14:28:39 1999
HP 5989B
Page 12
-------
Abundance
20000
15000
10000
Time-
5000
TIC: ENG1654.D
33 .40
^33:50
33.60
Abundance Ion 240.00 (239.70 to 240.70): SMG
10UUU-lQn 120.00 (119.70 to 120.70): ENG
5000
33.51
Time-
—i 1 1 r-
33 .40
33 i 50 ' ' 33 ! 60
Abundance
20000
15000
10000
5000
Time--> 33:40' '33!50' ' 33 160
1 E f f » 1
33170 33.80
#22
Chrysene-dl2
Concen: 0.09 ng/uL
RT: 33.51 min Scan# 3096
Delta R.T. -0.03 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:240 Resp: 13570
Ion Ratio Lower Upper
240
100
120
0.0
6.4
19.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1654.D
#23
Chrysene(CCC)
Concen: 0.10 ng/uL
RT: 33.62 min Scan# 3112
Delta R.T. -0.03 min
Lab Pile: ENG1654 .D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:228 Resp;
Ratio
100
0.0
0.0
0.0
Lower
9.1
0.0
0.0
18534
Upper
27.1#
0.0
0.0
Abundance Ion 228.00 (227.70 to 226.705: 2N<3
Ion 114.00 (113.70 to 114.70): ENG
33.62
8000
6000
4000
2000 :
0
Time-~> 33.40
ENG1654.D—PES3.M
33.50 33.60 33.70 33.80
Mon Oct 18 141ZB :42 1999
0CC
' r»
o
HP 5989B
Page 13
-------
jftbimdance
20000
15000
10000.
5000
TIC: 2NG1654.D
Time-->39 .20
39.30
—i , r t r-
39:40
—T 1 1 r
39*50
AbundanceIon 264.00 (263.70 to 264.70): ENG
"Ion 132.00 (131.70 to 132,70): ENG
5000
39.37
#24
Benzo(b)fluoranthene-dl2
Concen: 0.10 ng/uL m
RT: 39.37 min Scan# 3996
Delta R.T. -0.05 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:264 Resp:
Ion Ratio Lower
264 100
132 206.8 8.0
0 0.0 0.0
0 0.0 0.0
7560
Upper
23 .9#
0.0
0.0
0 .
\ 1 1 1 1 1 1 ! 1 r—| 1 1 r- . ,
[Time--539 ^ 20 39.30 39.40 39.50
Abundance
20000
TIC: ENG1S54.D
15000
10000
5000
0
Time-->
39 .40
¦~i 1 1 r
39.50
39.60
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
8000 J 39.53
2000
0
"1HG*
ENG
6000 :
4000
#25
Benzo(b)fluoranthene
Concen: 0.10 ng/uL
RT: 39.53 min Scan# 4020
Delta R.T. -0.06 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:252 Resp:
Ion Ratio Lower
252 100
126
0
0.0
0.0
0.0
13.4
0.0
0.0
12588
Upper
40.1#
0.0
0.0
Time-->
39 .40
-i 1 r'-T-
39.50
39.60
ENG1654 .D—PESJ.'M'
Mon Oct 18 14:28:45 1999
HP 5989B
'it7
Page 14
-------
Abundance
20000
15000
10000
5000
TIC: ENG1654.D
—!—i—(—r—T—i—i—i—i—rr'i—r—<—i—i—i—i—i—i—i—i—r
fTime- - >39.30 39140 39.50 39160 39170
Abundance Ion 264.50 (263.70 to 264.70): ENG
UU Ion 132.00 (131.70 to 132.70): ENG
5000
39.53
0 ,
time-->39.30 39.40 39.50 39 160
39l7tir
#26
Benzo(k)fluoranthene-dl2
Concen: 0.08 ng/uL
RT: 39.53 min Scan# 4021
Delta R.T. -0.06 rain
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:264 Resp:
Ion Ratio Lower
7245
Upper
264
100
132
0.0
8.5
25 .3#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Dundance
20000
15000
10000
5000
TIC: ENG1654.D
Time--> 39150 39160 39170 39180
Abundance Ion 252.00 (251.70 to 252.70): SNG
Ion 126.00 (125.70 to 126.70): ENG
8000
6000
4000
2000
39.68
#27
Benzo(k)fluoranthene
Concen: 0.09 ng/uL
RT: 39.68 rain Scan# 4044
Delta R.T. -0.04 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion;252 Resp: 8581
Ion Ratio Lower Upper
252
100
126
0.0
13 .0
38.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
n—1—1—1—1—i—r_
Time--> 39.50 39.60
P——-1 ? , 1 l | 1 V1 ! "T
39170 39180
ENG1654 ,D PE5T7FT
"Mid
Mon Oct 18 14:28:48 1999
HP 5989B
Page 15
-------
Abundance
20000
15000
TIC: ENG1S54.D
10000
5000
—!—I I |—r—I—i—I—|~~T—\—i—r—j—i—i—i—i—]—r—I—r—
Time-->41140 41.50 41.60 41.70 41.80
|M _ ipmnnnnnnniwn—nimnnmii i 1 ¦M—
Abundance Ion 264.00 (263.70 to 264.70): 1NG
Ion 132.00 (131.70 to 132.70); EPG
5000
0
41.64
Time-->41.40
T—T—|—I—|
41.50
41.60
i~T~r 1 1
41.70
41.80
\TXCj *—SrlG X 6 54—y
Abundance
20000
15000
10000
5000
n
w —l——i i \—i | i—i—i—f—i—i—i—!—j—j—\—i—r
Time--> 41.60 41.70 41.80 41190
Abundance Ion 252.00 (251.70 to 252.70)
Ion 126.00 (125.70 to 126.70)
41.80
6000
4000
2000
TJFTS"
ENG
Time*
l > 1
41.60
1 , , p-
41.70
, 1 , , , , , , j y.
41.80 41.90
ENG1654.D—PESi.M
Mon Oct 18 14:28:51 1999
Benzo(a)pyrene-dl2
Concen: 0.10 ng/uL m
RT: 41.64 min Scan# 4343
Delta R.T. -0.05 min
Tjah
File:
ENG1654.D
Acq:
14 Oct
99 7:32 pm
Tgt
Ion:264
Resp; 4551
Ion
Ratio
Lower Upper
264
100
132
263 .8
8.7 25.9#
0
0.0
0.0 0.0
0
0.0
0.0 0.0
#29
Benzo(a)pyrene(CCC)
Concen: 0.09 ng/uL
RT: 41.80 min Scan# 4368
Delta R.T. -0.07 min
Lab
Pile:
ENG1654
,D
Acq:
14 Oct
99 7:
32 pm
Tgt
Ion:252
Resp:
5581
Ion
Ratio
Lower
Upper
252
100
126
0.0
13 .4
40.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC K-" 3
HP 5989B Page 16
-------
Abundance
20000
15000
10000
5000:
"'TIC; BUS16S4.D
ou
"I 1 F
Time--> 52120 ' 52 140' 52:60 52180
1—r—i—r—r~
Abundancelon 288.00 (287.70 to 288.70): 1NG
3000 ^
52.58
2000
1000
"i—i—t—i—i—!—!—!—!—r—i—r—|—I—i—j—i—j—i—!—i—r~
Time--> 52.20 52.40 52.60 52.80
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen; 0.09 ng/uL m
RT: 52.58 min Scan# 6035
Delta R.T. -0.08 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pttl
Tgt Ion:288 Resp: 4732
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
10000
TIC: ENG1654.D
5000
0
—i i }—|—?—r-
Time-->52 140 52.60
1—1 i 1 1
52180
t \ \ ( i—i "t j—r—
53.00 53 .20
Abundance Ion 276.05 (275-75 to 276.75): ENG
3000
2000
1000 -
Ion 138.00 (137.70 to 138.70) : ENG
52 .86
Time-->52 .40
—' 1
52 .60
i—i—|—i—r~i—i—i—!—I—i—r—i—i—i—r
52.80 53.00 53.20
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.10 ng/uL m
RT: 52.86 min Scan# 6086
Delta R.T. -0.09 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:276.05 Resp:
6106
Ion
276
138
0
ENG1654.D—PES3.M
Mon uct ia i4:2b:b4 iyyy
Ratio
100
88.4
0.0
0.0
Lower Upper
22 .8
0.0
0.0
68.2#
0.0
0.0
HP 5989B
Page 17
-------
Abundance
20000
15000
10000
TIC: ENG1654.D
5 000
52.40
52 .60
52 .80
Time-->
Abundance Ion 292.00 (291.70 to 292.70): ENG
52.53
2000
1000
Time-->
• i' * 1 1 1 » ! 1 j r 1 ! r—i 1 r
52.40 52.60 52.80
#32
Dibenz {a, h.) anthracene-dl4
Concen: 0.08 ng/uL m
RT: 52.53 min Scan# 6024
Delta R.T. -0.10 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:292 Resp: 2793
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1654.D
10000 .
5000 -
0
Time - ->
52
j i i r i | i I i i | ! i i • |
.60 52.80 53.00 53.
20
AbundanceIon
278.00 (277.70 to 278.70)
: ENG
3000 .
Ion
139.00 (138.70 to 139.70}
: ENG
52 .92
2000
1000
0 .
Time- - >
52
.60 52180 53100 53.
20
#33
Dibenz(a,h)anthracene
Concen: 0.09 ng/uL m
RT*. 52.92 min Scan# 6097
Delta R.T. -0.07 min
Lab File: SNG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:278 Resp: 4772
Ion Ratio Lower Upper
278
100
139
92 .0
13.7
41.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
PES'3'.M
OeC) lys
HP 5989B
Page 18
-------
Abundance
TIC: ENG1654.D
i
10000 -
1
i
I
5000 -
0 .
Time-->
55.20 55:40 55.60 55180
Abundance Ion 288.00 (287.70 to 288.70): ENG
3000
55 .54
#34
Benzo(g,h, i)perylene-dl2
Concen: 0.10 ng/uL m
RT: 55.54 min Scan# 6598
Delta R.T. -0.12 min
Lab File; ENG1654.D
Acq; 14 Oct 99 7:32 pm
Tgt Ion:288 Resp: 4853
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
1000
0 -
i—, j i1 i 1 r—| 1 1 1 1 1 1 1 ! 1 1 1 1 r
Time--> 55.20 55.40 55.60 55.80
Abundance
6000
TIC: ENG1654.D
4000
2000
0
-i—|—i—i—r
Time-
55.60 55.80 56.00 56.20
Abundance Ion 215.00 (275.70 to 276.705: 2NG
Ion 138.00 (137.70 to 138.70): ENG
55.88
3000
2000 -
1000 -
Time-
—! j , r—\ 1 j 1—i r 1 1 3 1 1 1 1 1—
55:60 55:80 56.00 56.20
ENG1654.D—PES3.M
Mon Oct IB 14:2y:U0 1999
#35
Benzo(g,h,i)perylene
Concen: 0.11 ng/uL m
RT: 55.88 min Scan# 6681
Delta R.T. -0.11 min
Lab File: ENG1654.D
Acq: 14 Oct 99 7:32 pm
Tgt Ion:2 76 Resp: 6942
Ion Ratio Lower Upper
276
100
138
87.4 15.9
63.4#
0
0.0 0.0
0.0
0
0.0 0.0
0.0
OCCji/2
HP 5989B
Page
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG16 5 5.D
14 Oct 99 8:39 pm
CARB429,ICALO.25
Oct 18 14:22 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Mon Oct 18 14:20:26 1999
Single Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
20.01 190 926005 5.00 ng/uL -0.02
%Recovery
1) 2, 2-Difluorobiphenyl
System Monitoring Compounds
2)
Naphthalene-d8
17.70
136
15088 0
0.22 ng/uL
5.62%
4)
2-Methlynaphthalene-dlO
19.38
152
53577
0 .27 ng/uL
0 • 68%
5)
Ac enaphthylene-d8
21.64
160
35676
0.22 ng/uL
5 .49%
7)
Ac enaphthene-dl0
22 .05
164
3 9833
0.23 ng/uL
5.70%
9)
Fluorene-dlO
23 .32
176
39373
0.22 ng/uL
5.43%
11}
Phenanthrene-dl0
25 .69
188
54310
0.21 ng/uL
5.31%
13)
Ant hracene-dl0
25.83
188
4224
0.32 ng/uL
7.92%
15)
Fluoranthene-dlO
28 .69
212
44261
0.22 ng/uL
5.41%
17)
Pyrene-dlO
29.29
212
49031
0.23 ng/uL
5 .81%
19)
p-Terphenyl-dl4
29.62
244
275261
0.00 ng/uL
0.00%
20)
Benzo(a)anthracene-di2
33.37
240
15130
0.22 ng/uL
5.61%
22)
Chrysene-dl2
33 .51
240
29503
0.22 ng/uL
5.62%
24)
Benzo(b)fluoranthene-dl2
39.36
264
18374
0.25 ng/uL
6.29%
26)
Benzo(k)fluoranthene-dl2
39.53
264
17146
0.24 ng/uL
6.12%
28)
Benzo(a)pyrene-dl2
41.62
264
9381
0.21 ng/uL
5.33%
30)
Indeno(l,2»3-cd)pyrene-dl2
52.55
288
9509
0.21 ng/uL
5.20%
32)
Dibenz(a,h)anthracene-dl4
52 .50
292
6105
0.23 ng/uL
5.65%
34)
Benzo(g,h,i)perylene-dl2
55 .54
288
10967
0.23 ng/uL
5.84%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.74
128
177118
0 .23
ng/uL
99
6)
Acenaphthylene
21.66
152
46069
0.23
ng/uL
90
8)
Acenaphthene(CCC)
22 .13
154
46178
0.23
ng/uLm
99
10)
Fluorene
23.38
166
48453
0.23
ng/uL
80
12)
Phenanthrene
25.74
178
72223
0.23
ng/uL
100
14)
Anthracene
25 .87
178
33891
0 .23
ng/uL
95
16)
Fluoranthene(CCC)
28.74
202
63489
0 .22
ng/uL
91
18)
Pyrene
29.34
202
71285
0.23
ng/uL
97
21)
Benzo(a)anthracene
33 .47
228
28230
0.23
ng/uL
98
23)
Chrysene(CCC)
33 .62
228
44499
0.25
ng/uL
94
25)
Benzo(b)fluoranthene
39.53
252
28518
0.23
ng/uL
97
27)
Benzo(k)fluoranthene
39 .67
252
19821
0.24 ng/uL
92
29)
Benzo(a)pyrene(CCC)
41.80
252
12830
0.24
ng/uLm
48
31)
Indeno(1,2,3-cd)pyrene
52 .81
276
12345
0 .21
ng/uLm
31
33)
Dibenz(a,h)anthracene
52 .88
278
10598
0.23
ng/uLm
48
35)
Benzo(g,h,i)perylene
55 .88
276
14908
0.22 ng/uLm
36
0CC).i.'3
(#) » qualifier out of range (m) = manual integration
ENG1655.D PSS3.M Mon Oct 18 14:23:18 1999 HP 5989B
Page l
Va
-------
Quantitation Report
Data File :
Acq On
Sample
lMf i SC
Quant Time;
C:\HPCHEM\l\DATA\ENG1655.D
14 Oct 99 8:39 pm
CARB429,ICALO.25
Oct 18 14:22 1999
Vial:
Operator:
Inst :
Multiplr:
HP 5989B
1.00
Method : C:\HPCHEM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:20:26 1999
Response via : Single Level Calibration
TIC: ENGlbbb.D
600000 :
550000 -
500000 ;
450000 :
400000:
350000 :
300000:
250000
200000:
150000
2S
100000
8 10 .12
£b9S *14
l|s
lis vV
Id 15
4s
229:
50000
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55 .00
ENG1655.D PES3.M
Mon Oct 18 14:23:26 1999
HP 5989B
Page 2
-------
'A5un3ance~
'—ENG1 (5 5 5—U~
100000 -
A
50000 -
{
0 -
Tirae-->
17.60 17.80
Abundance Ion 136.00 (135.70 to 136.70): ENG
80000 ;
Ion 68.00 (67.70 to 68.70): ENG16
17.70
60000 :
A
40000:
\
20000 -
11
0 -
y\V
Time-->
17.60 17.80
#2
Naphthalene -d.8
Cone en 0.22 ng/uL
RT: 17.70 min Scan# 253
Delta R.T, -0.02 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:136 Resp: 150880
Ion Ratio Lower Upper
136
100
68
13 .5
3.9
11.5#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
100000
TIC: ENG1655.D
50000
Time--> 17.60 17.80
Abundance Ion 128.00 (127.70 to 128.70)
100000 jlon 127.00
1MT
(126.70 to 127.70): ENG
17 .74
50000
#3
Naphthalene(CCC)
Concen: 0.23 ng/uL
RT: 17.74 min Scan# 260
Delta R.T. -0.02 min
Lab File: ENG165S.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:128 Resp: 177118
Ion Ratio Lower Upper
128 100
127 13.0 0.0 62.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ocems
I 1 T"
7ime - -> 17.60 17 180
ENGX631T7D FEST7M Ron Oct 18 14:23:30 1999'
HP 5989B
Page 3
-------
p
lindane e
TIC: ENGlSSS.D
20000
10000
Time--> 19.30 19.40 19.50
Abundance Ion 152.00 (151.70 to 152.70): ENG
30000
20000
10000
19,38
#4
2 -Me thiynaphthalene-dl0
Concen: 0.27 ng/uL ra
RT: 19.38 min Scan# 763
Delta R.T. -2.31 min
Lab Pile: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:152 Resp: 53577
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time-
19 .30
19 .40
19.50
SEundance
30000 .
20000 .
10000
1 1 j—j j (fill 1 1 j 1 1 \ 1 1 r-
Time--> 21.50 21.60 21.70 21.80
TIC: ENG1655.D
Abundance Ion 160.00 (159.70 to 160.70): ENG
20000 :
15000
ioooo 4
5000
0
21.64
Time-->
isrMy^SBiErKir"T^"""' opu'i—par
CivlviJii v • U Jtr «3 » FrS
1 1 1 1 1 1 1 1 r-
21.50 21.60
#5
Acenaphthylene-d8
Concen: 0.22 ng/uL
RT: 21.64 min Scan# 1300
Delta R.T, -0.02 min
Lab File: ENG1655.D
Acq; 14 Oct 99 8:39 pm
Tgt Ion:160 Resp: 35676
Ion Ratio Lower Upper
160
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
2i;70 21:80
Mon Oct la 14:23:32 1999
OCC } J
HP 5989B
Page 4
-------
Abundance
TIC: ENG1655.D
30000 J
A
20000 -
j
10000 -
j V
/
0 .
Time-->
• t 1 ' ? 1 < I' 1 1 ) i » i ( j t I i I j 1 i | 1 " | 1
21 . 50 21.60 21.70 21.80
Abundance Ion 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153 .70) : ENG
21.66
20000 .
A
10000 I
JA^
0 -
/
Time-->
i i i i i i i t i j j t « i j i i i « | * i i i i i
21.50 21.60 21.70 21.80
#6
Acenaphthylene
Conceri; 0 .23 ng/uL
RT: 21.66 min Scan# 1304
Delta R.T. -0.02 mill
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:152 Resp: 46069
Ion Ratio Lower Upper
152 100
153 12.7 8.7 25.9
0 0.0 0.0 0.0
0 0.0 0.0 0 . 0
gee—ft
X J. ; Ciivux ~ Jn I J
Abundance
40000
20000
i 1 1 1 1 1 1 1 1 1 1 r--1 ] 1 i I"
22.00 22.05 22.10
Time-->
Abundance Ion 164.00 (163.70 to 164.70) : ENG
22.05
20000
10000
Time - ->
ENG1655 .D—FBS37W
—t—r
22.00
i \ r
22 .05 22.10
Mon Oct 18 14:23:35 1999'
#7
Ac©naphth.ene-dlQ
Concen: 0.23 ng/uL m
RT: 22.05 min Scan# 1361
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:164 Resp: 39833
Ion Ratio Lower Upper
164
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CCji77
HP 5989B
Page 5
-------
TIC: BHG1655.D
Abundance
40000
20000 -
Time-->
-1 1 1 ,
22.05
-i—t—r
22.10
22.15 22.20
Abundance Ion 154.00 (153.10 to 154.70]
30000 Jlon 153
20000
(152.70 to 153.70): 1NG
.13
10000 J
0
Time-->
-?—i—i—r
22.05 22.10 22.15 22.20
Abundance
40000
Time-->
TIC: SNG1655.D
20000
0
23 .20
23 .30
23 .40
23 .32
20000
10000
Time-
23 .20
23.40
#8
Acenaphthene(CCC)
Concen: 0.23 ng/uL ra
RT: 22.13 min Scan# 1373
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:154 Resp: 46178
Ion Ratio Lower Upper
154 100
153 100.8 45.5 136.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#9
Fluorene-dlO
Concen: 0.22 ng/uL
RT: 23.32 min Scan# 1553
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion: 176 Resp*. 39373
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 176.00 (175.70 to 175.70): ENG
OCCrm
ENGT6"55".B PES3 .M
n 1 1 1 i
23.30
Man Oct IB 14:23:38 1999
HP 5989B
Page 6
-------
Abundance
40000 -
TIC: 8MG16S5.D
20000
30000
20000
10000
0
Time--^3:20
-t < j j j 1 s j * 1 \ j 1: » r
23.30 23.40 23.50
#10
Fluorene
Concen: 0.23 ng/uL
RT: 23.38 rain Scan# 1563
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:166 Resp: 48453
Ion Ratio Lower Upper
Time-- >23 ; 20 23130 23140 "3 150
Abundance Ion 166.00 (165.70 to 166.70): ENG
166
100
165
93.8
38.3
114.7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Ion 165.00 (164.70 to 165.70): ENG
23.38
Abundance
TIC: ENG1655.D
40000 .
A A
20000 -
J\J \ y
0 -
Time - ->
25 ! 60
25.70 25180
Abundance Ion
188.00
(187.70 to 188.70): ENG
Ion
94.00
(93.70 to 94.70): ENG16
30000 .
25.69
20000 I
A
10000 -
i\V
0:
Time-->
25160
25.70 25180
#11
Phenanthrene-dl0
Concen: 0.21 ng/uL
RT: 25.69 min Scan# 1913
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:188 Resp;
Ion
188
94
0
0
Ratio
100
22 .8
0.0
0.0
Lower
5.8
0.0
0.0
54310
Upper
17.2#
0.0
0.0
SNG1655.D—PES3.M
OOCti?
- » »• I
Mon Oct 18 14:23:41 1999
HP 5989B
3
Page 7
-------
Abundance
40000 .
TIC: EMG1655.D
20000
0
#12
Phenanthrene
Concen: 0.23 ng/uL
RT: 25.74 min Scan# 1921
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq; 14 Oct 99 8:39 pm
Tgt Ion:178 Resp: 72223
Ion Ratio Lower Upper
i—?—I—r—*t—i—i—j—i—i—i—i—|—i—i—i—i—|—i—r
25.65 25170 25.75 25.80
Time - - >
Abundance ion 178.00 (177.70 to 178.70)
Ion 176.00 £175.70 to 176.70)
40000 25 .74
30000 ;
20000
10000 J
178
100
176
20.3
10.3
30.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0 -
'mr
ENG
Time--»
25.65
""25:70
25 .75
—|—1—\—i—r
25.80
Abundance
40000
mwft:—pvrm gee—TV
XIU: Eiriu>ADDS , JJ
20000
_i 1 1 1 1 1 r—| 1 r-
25.85 25.90
1 1—1—1—|—1—
Time--> 25 175 25.80
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70); ENG16
25.83
3000
2000
1000
Je
#13
Anthracene-dlO
Concern 0.32 ng/uL m
RT: 25.83 min Scan# 1934
Delta R.T. -0.02 min
Lab Pile: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:188 Resp: 4224
Ion Ratio Lower Upper
188 100
94 77.7 6.6 19.6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
oeoiao
:ime-->
¦¦¦> jtH/—n'wr "J
ENG1655.D
25 .75
PES3 .M
25180 25.85 25.90
—Mon 0ct lg 14 : 23 : 44 1999'
HP 5989B
Page 8
-------
Abundance
40000
"TIC: ENG16557D
20000
Time-->25.70 25:80 25190 26100
Abundance Ion 178.00 (177.70 to 178.70): ENG
lion 176.00 (175.70 to 176.70): ENG
#14
Anthracene
Concen: 0.23 nq/uL
RT: 25.87 min Scan# 1941
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq; 14 Oct 99 8:39 pm
Tgt Ion:178 ReBp: 33891
Ion Ratio Lower Upper
178 100
176 19.7 8.9 26.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
40000
30000 :
20000
10000
0
25.87
Time-->25.70
25.80
25 .90
26.00
Abundance
40000
30000
20000
10000
Time-
TTTT—*1 £ E E—Ts
X X «• £iiNv7 X O Id O ¦
"T i \ t—I—I—I—| S1 T" T f T T ! I 1 r~T 1 m 1 1—r
28.50 28.60 28170 28180 28.90
ENG16 5 5.D—PES3.M
OCCjisi
Mon Oct IB 14:23:4V 19^9
HP 5989B
Page 9
-------
Abundance
40000
30000
20000
TIC- BHG1655.D'
A
10000
o
Time- -> 28.60 28180
Abundance Ion 202.00 (201.70 to 202.70): ENG
lion 101.00 (100.70 to 101.70);
30000 J 28.74
20000
10000
0
Time-->
28.60
28.80
#16
Fluoranthene(CCC)
Concen: 0.22 ng/uL
RT: 28.74 min Scan# 2380
Delta R.T. -0.02 rain
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:202 Resp: 63489
Ion Ratio Lower Upper
202 100
101 24.0 9.9 29.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
TIC: ENG1655.D
40000 -
r\
20000 -
1
0 -
Time-->
s I f : i t | f i ! i | t i t t i t | i i 1
29.10 29.20 29.30 29140
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
29.29
20000 -
A
10000 -
A
0 -
Time - - >
1 | 1 > t t j t > 1 1 | 1 t 1 I I t 1 T 1 I
29.10 29.20 29.30 29.40
#17
Pyrene-dlO
Concen: 0.23 ng/uL
RT: 29.29 min Scan# 2463
Delta R.T. -0 .03 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:212 Resp: 49031
Ion Ratio Lower Upper
212
100
106
29.7
8.6
25.6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG1655.D—PES3.M
H___— - . -- ^
V«» v JL O «l» T5 » v JL *7 5" ip?
HP 5989B
Page 10
-------
(Abundance
1
j
60000
40000
20000
Tirae-->29;i0 29.20 29.30 29140 29150
Abundance Ion 202.00 (201.70 to 202.70); ENG
(100.70 to 101.70); ENG
29.34
30000
20000
10000
TIC: ENGlbbb.D
Ion 101
Time--> 29110 29120 29.30 29 140 29150
SBundance
150000
100000
50000
Time--> 29.40
Abundance Ion 244.00
Ion 122.00
100000 .
50000
TIC: ENG1655.D
29.60
29.80
to 244 .70) :
#18
Pyrene
Concen: 0.23 ng/uL
RT: 29.34 min Scan# 2471
Delta R.T. -0.02 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:202 Resp: 71285
Ion Ratio Lower Upper
202
100
101
26.9
14 .3
42 .8
0
0 . 0
0.0
0.0
0
0.0
0.0
0.0
#19
p-Terphenyl-dl4
Concen: 0.00 ng/uL
RT: 29.62 min Scan# 2513
Delta R.T. -0.03 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:244 Resp: 275261
Ion Ratio Lower Upper
244
100
122
28.9
6.7
19 .9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
7U
121.70 to 122
29.62
70)
1HG"
ENG
0
1—r
29.40
Time-->
ENGIfcSB.D—PES3.M
n 1 r
29.60
29.80
Mon Oct 18 14:23:53 1999'
HP 5989B
Page 11
-------
fS
undance
TIC: ENG1655.D
20000
10000
i—r
rime--> 33.30
AbundanceIon 240,00
Ion 120.00
10000 .
5000
33 .40
239.70 to 240.70): EMG
119.70 to 120.70):
Time-->
33 .30
33 .40
#20
Benzo(a)anthracene-dl2
Concen: 0.22 ng/uL
RT: 33.37 min Scan# 3075
Delta R.T. -0.03 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:240 Resp: 15130
Ion Ratio Lower Upper
240
100
120
0.0
7.3
21.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: EMGlfaSS.D
20000 -
_/x/\A
10000,
0 .!
Time - ->
33.30 33.40 33.50 33.60
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70) : ENG
15000 -
A
10000
33.47 / \
5000
0 -
Time - - >
33.30 33.40 33.50 33.60
#21
Benzo(a)anthracene
Concen: 0.23 ng/uL
RT: 33.47 min Scan# 3090
Delta R.T. -0.03 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:228 Resp;
28230
Ion
Ratio
Lower
Upper
228
100
114
26.3
12.8
38.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENGT&55 . D PES3 .M
Mon Oct IB 14:23:56 1999
0
0C)1'51
HP 5989B
Page 12
-------
tttt:—pkvi g e e—n
tiU llWVai.ODD . U
'Abundance
20000 -
10000
i—I i |—i—i—i—i—|—i—i—i—i—I—i—i—r
> 33:30 33.40 33.50 33.60 33170
Time
Abundance Ion 240.00 (229.70 to 240.75): IMG
Ion 120.00 (119.70 to 120.70): ENG
33.51
10000 1
5000
E
lme-
0
¦» 33.30 33.40
33;50' ' 33160' 33!70
Abundance
20000
TIC; 2NG16S5.D
#22
Chrysene-dl2
Concen: 0.22 ng/uL
RT: 33.51 min Scan# 3096
Delta R.T. -0.03 min
Lab File; ENG165 5.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:240 Resp:
Ion Ratio Lower
29503
Uoner
JrJr
240
100
120
32 .5
6.4
19.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
10000
Time--> 33i40 33 160 33l80
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70); ENG
15000 J 33.62
10000
5000
0
#23
Chrysene(CCC)
Concen: 0.25 ng/uL
RT: 33.62 min Scan# 3113
Delta R.T. -0.03 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:228 Resp:
Ion Ratio Lower
228 100
114 20.8
44499
Upper
9,1 27.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0CC)lf;
Time-->
ENG16 5 5 . D FES3 . M
1 ' 1 r~
33 .40
1 1 1 1 r
33160
33 180
Mon Oct is 14;23: by iyyy
HP 5989B
Page 13
-------
TIC! ENGl 6 5 5 . D
20000 -
10000 .
Time--> 39.20 39.30
Abundance Ion 264,00 (263.70 to 254.70): ENG
10000 HIon 132.00 (131.70 to 132.70): ENG
39.40
39.50
39.36
5000
39.30
39.50
Time--> 39.20
#24
Benzo(b)fluoranthene-dl2
Concern; 0.25 ng/uL m
RT: 39.36 min Scan# 3995
Delta R.T. -0,06 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:264
Ion Ratio
264 100
132 148.4
0 0.0
0 0.0
Resp; 18374
Lower Upper
8.0 23.9#
0.0 0.0
0.0 0.0
TIC: ENG1655,D
Abundance
20000
10000
Time--> 39140 39 i50 39160
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
39.53
10000
5000
0
#25
Benzo(b)fluoranthene
Concen: 0.23 ng/uL
RT: 39.53 min Scan# 4021
Delta R.T. -0.06 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:252 Resp: 28518
Ion Ratio Lower Upper
252
100
126
28.0
13 .4
40.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time--> 39.40
ENGXF55TD FE53TM
39.50 39.60
Mon Oct IB 14 : 24 : U1 1999'
oecj
HP 5989B
¦a »«r.r
sZO
Page 14
-------
TIC: EMG16SS.D
20000
10000 .
39.60
3 9 .40
Time-->
Abundance Ion 2 64.00 (263.70 to 264.70): BNG
10000Jlon 132.00 (131.70 to 132.70): ENG
39.S3
5000 -
39.60
Time-->
39 .40
#26
Benzo(k)fluoranthene-dl2
Concen: 0.24 ng/uL
RT: 39.53 min Scan# 4022
Delta R.T. -0.06 rain
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt ion:264 Resp: 17146
Ion Ratio Lower Upper
264 100
132 0.0 8.5 25.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
30000 -j
TIC: ENG1655.D
20000 -
10000 -
o '
Time--> 39 150 ' ' 39 160 ' ' 39!70 ' ' 39180
Abundance Ion 252.00 (251.70 to 252 .70) : ENG
Ion 126.00 (125.70 to 126.70) : ENG
10000 _
39.67
5000 -
0 .
t j ! 1 i ! 1 1 i 1 1 | ! ! t 1 1 ! 1 I
Time--> 39.50 39.60 39.70 39.80
#27
Benzo(k)fluoranthene
Concen: 0.24 ng/uL
RT: 39.67 min Scan# 4043
Delta R.T. -0.06 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:252 Resp
Ion
252
126
0
0
Ratio
100
30.1
0.0
0.0
Lower
13.0
0.0
0.0
19821
Upper
38.8
0.0
0.0
oee
CHe 7
HP 5989B
Page 15
-------
Abundance TIC; ENG1655.D
20000
15000
10000
5000
0 1 , , 1 1 , , 1 , j 1 1 1 1 1 r
Time--> 41.60 41.70 41.80 41.90
Abundance
Abundance
TIC; ENG1655.D
20000 -
15000 -
10000
5000
0
Time-->
111 1 i 1 ; 1 ! I 1 1 1 1
41.40 41.60 41.80
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
5000 -
41.62
0.
Time-->
41.40 41.60 41.80
#28
Benzo(a)pyrene-dl2
Concen: 0.21 ng/uL
RT: 41.62 min Scan# 4342
Delta R.T. -0.06 min
Lab File; ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:264 Resp: 9381
Ion Ratio Lower Upper
264
100
132
0.0
8.7
25.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#29
Benzo(a)pyrene(CCC)
Concen: 0.24 ng/uL m
RT: 41.80 min Scan# 4369
Delta R.T. -0.07 min
Lab Pile: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:252 Resp:
Lower
13 .4
0.0
0.0
Ion
252
126
0
0
Ratio
100
70.8
0.0
0.0
12830
Upper
40.1#
0.0
0.0
8000
6000
4000
2000
0
Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70); ENG
41.80
OCOi-i,
—I , 1 , p— ! , , 1 1' I |
Time--> 41.60 41.70 41.80 41.90
ENG1655 .13—PES3.M
Mon Oct 18 14:24:07 1999
HP 5989B
Page 16
-------
TIC: ENGlbbb.D
15000
10000
5000
, , , 1 1 f 1 1 ] 1 1 1 1 1 1 1 r
time --> 52.20 52.40 52.60 52.80
Abundance Ion 288.00 (287.70 to 288.705: EMG
3000
2000
1000
52.55
t r—t 1 1 [ 1 r
[Time --> 52.20 52.40
t \ r 1 r
52 I 60 52.80
Abundance
15000
10000
TIC: ENG1655.D
5000
0
Time-->
i t—t—]—i 1—i—i—| r—r
52.60 52180
Abund^nge
3000
2000
1000
0
53:00
Ion 276.05 (275.75 to 275.75): EMG
Ion 138.00 (137.70 to 138.70): ENG
52.81
Time-->
ENG1655 . D PES 3 .M
r~-n—i—i—f r ! 5 i—r—r—
52.60 52.80
#30
Indeno (1, 2, 3-cd) pyren.e-dl2
Concen: 0.21 ng/uL m
RT: 52.55 min Scan# 6029
Delta R.T. -0.12 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:288 Resp: 9509
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.21 ng/uL m
RT: 52.81 min Scan# 6078
Delta R.T. -0.14 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:276.05 Resp: 12345
Ion Ratio Lower Upper
276
100
138
80.3
22.8
68.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
I -T T' I T
53 iOO
Mon Oct 18 14:24:10 1999
0CCJI5S
HP 5989B
Page 17
-------
TIC: ENG1655.D
15000
10000
5000
Time--> 52.20 52.40 52160 52180
Abundance Ion 292.00 (291.70 to 292.70)
3000
2000
1000
Time-->
52.50
)—i—i | i—i—i—i—|—!—i—i—r
52.20 52.40 52160
T ! 1 1 j 1
52.80
#32
Dibenz (a, h) anthracene-cll4
Concen*. 0.23 ng/uL m
RT: 52.50 min Scan# 6021
Delta R.T. -0.13 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:292 Resp:
Ion
292
0
0
0
Ratio
100
0.0
0.0
0.0
Lower
0.0
0.0
0.0
6105
Upper
0.0
, 0.0
0.0
ENG
Abundance
TIC: ENG1655.D
15000 .
10000 l
5000 I
0 J
Time - ->
52160 52,80 53.00 53.20
Abundance Ion 278.00 (277.70 to 278.70) : ENG
Ion 139.00 (138.70 to 139.70): ENG
52 .88
3000 :
2000
1000
0
Time-->
52.60 52180 53.00 53 .20
#33
Dibenz(a, h)anthracene
Concen: 0.23 ng/uL m
RT: 52.88 min Scan# 6091
Delta R.T. -0.11 min
Lab Pile: ENG1655.D
Acq: 14 Oct 99 8:39 pm
Tgt Ion:278 Resp;
Ion
278
139
0
0
Ratio
100
80 .5
0.0
0.0
Lower
13 .7
0.0
0.0
10598
Upper
41.0#
0.0
0.0
ENG1655.D PBS3. M
0CC)I«y
Mon Oct IB 14:24:13 1999
HP 5989B
Page 18
-------
(Abundance
10000
TIC: MG16S5.D
Time-->
AbundanceIon 288.00 (287.70 to 288.70): ENG
5000
55.20 55.40 55.60 55.80
55.54
3000
2000
1000
t—i—i—|—r—r
Time--> 55:20 55140 55.60 55180
#34
Benzo(g,h,i)perylene-dl2
Concen: 0.23 ng/uL m
RT; 55.54 min Scan# 6599
Delta R.T. -0.12 min
Lab File: ENG1655.D
Acq: 14 Oct 99 8:39 prn
Tgt Ion:288 Resp: 10967
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
8000
Time-
TTC:ENGlbbb.D
6000
4000
2000
#35
Benzo{g,h,i)perylene
Concen: 0.22 ng/uL m
RT: 55.88 min Scan# 6683
Delta R.T. -0.11 rain
T ah To. WHITM CCC r\
•JCUJ E? J— X t» * JL, w O <3 » 4#
Acq: 14 Oct 99 8:39 pm
Tgt Ion:276 Resp: 14908
1 r l ! [ ""1 1 T F r ! ! 1 ! 1—TT 1 > 1 T 1 \ \ (
55.60 55.80 56.00 56120
Ratio
100
77 .5
0.0
0.0
Lower Upper
15 .9
0.0
0.0
63 .4#
0.0
0,0
Abundance Ion 276.00 (275.70 to 276.70)
4000
3000
2000
1000
Ion 138.00 (137.70 to 138.70): ENG
55.88
Time-
-1—i—1—1—!—1—1—i—!—r—1—i—i—1—r—1—\—i—5—I—1—\—r-
55.60 55.80 56.00 56.20
ENG1655.D—PES3.M
oecj2
Won UCt IB 14:24:17 1999
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DATA\ENGl656.D
14 Oct 99 9:45 pm
CARB429,ICAL0.5
Oct 18 14:31 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1. 00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES 3.M
Won Oct 18 14:32:45 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
20 .01
190
864870
5.00
ng/uL
-0.02
ystem Monitoring Compounds
%Recovery
2)
Naphthalene~d8
17 ,70
136
276924
0.47
ng/uL
11.63%
4)
2-Methlynaphthalene-dlO
19.37
152
95858
0.54
ng/uL
1.35%
5)
Acenaphthylene-d8
21.63
160
72984
0.51
ng/uL
12.81%
7)
Acenaphthene-dl0
22 .05
164
73929
0.47
ng/uL
11.85%
9)
Fluorene-dlO
23 .31
176
75938
0.48
ng/uL
12.00%
11)
Phenanthrene-dl0
25,69
188
114440
0.52
ng/uL
12.96%
13)
Anthracene-dlO
25.82
188
5367
0.38
ng/uL
9.51%
15)
Fluoranthene-dl0
28.68
212
96895
0 .54
ng/uL
13.60%
17)
Pyrene-dlO
29.29
212
108156
0.57
ng/uL
14.22%
19)
p-Terphenyl-dl4
29.62
244
89569
0.09
ng/uL
0.22%
20)
Benzo(a)anthracene-dl2
33.37
240
34743
0 .58
ng/uL
14.53%
22)
Chrysene-dl2
33.50
240
71499
0.61
ng/uL
15.36%
24)
Benzo(b)fluoranthene-dl2
39.36
264
43295
0.63
ng/uL
15.81%
265
Benzo(k)fluoranthene-dl2
39.53
264
41648
0.64
ng/uL
16.08%
28)
Benzo(a)pyrene-dl2
41.62
264
21445
0.56
ng/uL
14.08%
30)
Indeno(1,2,3-cd)pyrene-dl2
52 .55
288
25798
0.66
ng/uL
16.48%
32)
Dibenz(a, h)anthracene-dl4
52 .51
292
14321
0.60
ng/uL
14.91%
34)
Benzo(g,h,i)perylene-dl2
55 .52
288
27022
0.64
ng/uL
15.94%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17 .74
128
294902
0.43
ng/uL
99
6)
Acenaphthylene
21.66
152
85734
0.48
ng/uL
90
8)
Acenaphthene(CCC)
22.12
154
78877
0 .44
ng/uLm
97
10)
Fluorene
23 .38
166
83240
0 .44
ng/uL
80
12)
Phenanthrene
25.75
178
131387
0.46
ng/uL
99
14)
Anthracene
25.87
178
68087
0 .51
ng/uL
94
16)
Fluoranthene(CCC)
28.73
202
121290
0 .48
ng/uL
90
18)
Pyrene
29.34
202
136344
0 .49
ng/uL
99
21)
Benzo(a)anthracene
33 .46
228
57401
0 .52
ng/uL
100
23)
Chrysene(CCC)
33 .61
228
89579
0.54
ng/uL
90
25)
Benzo(b)fluoranthene
39.51
252
60384
0.55
ng/uL
98
27)
Benzo(k)fluoranthene
39.66
252
44176
0.58
ng/uL
91
29)
Benzo(a)pyrene(CCC)
41.80
252
29999
0 .61
ng/uL
93
31)
Indeno(1,2,3-cd)pyrene
52.83
276
29311
0.58
ng/uL
100
33)
Dibenz(a,h)anthracene
52,86
278
25767
0.62
ng/uL#
48
35)
Benzo(g,h,i)perylene
55.85
276
33201
0.56
ng/uLm
96
0CC3
(#) = qualifier out of range (m) = manual integration
ENG1656,D PES3.M Mon Oct 18 14:33:16 1999 HP 5989B
Page
V.
'c
-------
Quantitation Report
C:\HPCHEM\1\DATA\ENG1656.D
14 Oct 99 9:45 pm
CARB429,ICALO.5
Data File
Acq On
Sample
Misc
Quant Time: Oct 18 14:31 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METH0DS\PES3.M
Mon Oct 18 14:32:45 1999
Multiple Level Calibration
Vial: 4
Operator:
Inst : HP 5989B
Multiplr: 1.00
TIC: ENG1656.D
550000 :
500000:
450000 :
400000:
350000
300000
250000
200000
2s
150000
8 10 .12, 18
3flS9£
c 15s
9tis 9|s ^j4
100000
20s
50000
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
Time - - >
OCOI93
ENG1€56.D PES3.M
Mon Oct 18 14:33:24 1999
HP 5989B
Page
-------
Abundance
150000
100000
50000
TICi ENG1656.D
Time-
1 m — ¦¦¦¦!! rj|' "Ml MII'll r"' 1 I ¦ —1 ¦ ¦
Abundance Ion 136.00 (135.70 to 136.70)
~i 1 r-
17.60
17.80
150000 Jlon
100000
50000
68.00 (67.70 to 68.70): ENG16
17 .70
0
Time-->
#2
Naphthalene-d8
Concen: 0.47 ng/uL
RT: 17.70 min Scan# 253
Delta R.T. -0.02 min
Lab File: ENG1656.D
Acq.- 14 Oct 99 9:45 pm
Tgt Ion:136
Ion Ratio
136 100
68 14.2
0 0.0
0 0.0
Resp: 276924
Lower Upper
•J Q 11 C#
*mr * *r m *mf 7}
0.0 0.0
0.0 0.0
Abundance
150000
100000
50000
Time-
TlC: ENGlbbb.D
j f
•> 17.50
"i—|—i—i—\—i—!—*—i—i—5—|—!—r—?—r—?—i—i—1—r-
17160 17.70 17.80 17.90
Abundance Ion 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70)
150000 1 17.74
100000
50000
Time-->17.50 17.60
ENGlfcbfc.D PESJ.M
-J , j fj f j j 1 1
17:70 17.80 17.90
#3
Naphthalene(CCC5
Concen: 0.43 ng/uL
RT: 17.74 min Scan# 260
Delta R.T. -0.02 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:128 Resp: 294902
Ion Ratio Lower Upper
128
100
127
12 .9
0.0
62.5
0
0.0
0.0
0.0
0
0,0
0.0
0.0
Mon Oct 18 14 : 33 fZS" 1999
0CG31
HP 5989B
Page 3
-------
Abundance
40000
TIC; ENG1S56.D
30000
20000
10000
0
Time--> 19,30 19.40
Abundance Ion 152.00 (151.70 to 152.70): EMG
19.37
40000
20000 -
0
$4
2-Methlynaphthalene-dlO
Concen: 0.54 ng/uL ra
RT: 19.37 min Scan# 762
Delta R.T. -2.31 min
Lab File; ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion;152 Resp: 95858
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time-
19 .30
19.40
Abundance
40000
,—i—i—>—J—J—r—i—i—j—i—i—i—i—|—i—?—j—>—I—i—f -r
Time-->21:40 21.50 21.60 21.70 21.80
TIC; ENG1656.D
20000
0
Abundance Ion 160.00 (159.70 to 160.70}; ENG
40000
21.63
30000 :
20000
10000
Time-->21.40
ENG1656.D P1S3.M
2i:sT
2i:eo
1 1 1 1 ! 1 T
21.70 21.80
#5
Acenaphthy1ene-d8
Concen: 0.51 ng/uL
RT: 21.63 min Scan# 1299
Delta R.T. -0.02 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:160 Resp: 72984
Ion Ratio Lower Upper
160 100
0 0,0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC)
Hon Oct 18 T4 ; 33:31 1999
HP 5989B
tj
Page 4
-------
Abundance
40000
ircrmwo"
20000
0
Time--> 21.40 21.60
Abundance Ion 152.00
Ion 153.00
i | ! 1 r
21.80
40000
20000 -
0 -_/~
21.40
n—^—r
21.60
21.80
Abundance
80000
60000
40000
20000
0
TIC: ING15S6.D
T
Time--> 22100 22105 22.10
Abundance Ion 164.00 (163.70 to 164.70): ENG
#6
Acenaphthylene
Concen: 0.48 ng/uL
RT: 21.66 min Scan# 1303
Delta R.T. -0.02 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:152 Resp: 85734
Ion Ratio Lower Upper
1 wj
100
153
13 .0
8.7
25.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
(151.70 to 152.70): ENG
(152.70 to 153.70): ENG
21.66
40000
30000
20000
10000
Time-->
22 .05
#7
Acenapht tiene - dl 0
Concen: 0.47 ng/uL m
RT: 22.05 min Scan# 1360
Delta R.T. -0.02 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion*. 164 Resp:
Ion Ratio Lower
164 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
73929
Upper
0.0
0.0
0.0
r*"
22 .00
l 1 1 1 1 1 1 1 1 1 r
22 .05 22.10
ENG1656.D—FHSTTTT
Man"Oct 18 14:33:34 1999
OCOSt'u
HP 5989B
Page 5
-------
TIC: ENG165 6.D
80000
60000
40000
20000 .
Time
Abundance
40000
20000
—,—r
22 105
"7 ' 1 ! 1 v i 1—j 1 1 r—i 1 r*
22.10 22.15 22.20
Ion 154.00 (153.70 to 154.70): EMG
Ion 153.00 (152.70 to 153.70): 1NG
22 .12
Time-
~i—i—[—i—i—i~—t—r
22.05 22.10
t—i \—r
#8
Acenaphthene(CCC)
Concen: 0.44 ng/uL m
RT: 22.12 min Scan# 1371
Delta R.T. -0.03 min
Lab Pile: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:154 Resp: 78877
Ion Ratio Lower Upper
154 100
153 105.3 45.5 136.3
0 0.0 0.0 0.0
0 0.0 0.0 0,0
22.15 22.20 I
Abundance
80000
60000
40000
TIC: ENG1656.D
20000
fTime--> 23.20 23.30 23 !40
Abundance Ion 176.00 (175.70 to 176.70): ENG
23.31
40000
20000
0
Time-
i I 1 E ! r-
23 .20
—,—j—,—r
23 .30
~l—I—r
23 .40
ENG1656,D PES3.M
#9
Fluorene-dlO
Concen: 0.48 ng/uL
RT: 23.31 min Scan# 1551
Delta R.T. -0.03 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:176 Resp: 75938
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
ocoiev
Man Oct 18 14:33:36 1999
HP 59891
Page 6
-------
Abundance
60000 -
60000
40000
20000
0
TIC: ENGlSSS.D
Time--> 23:30 23.40 23150
Abundance Ion 156.00 (165.70 to 166.70): ENG
lion 165.00 (154.70 to 165.70); ENG
23.38
40000
20000
0
#10
Fluorene
Concen: 0.44 ng/uL
RT; 23.38 min Scan# 1562
Delta R.T. -0.02 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:166 Resp: 83240
Ion Ratio Lower Upper
166 100
165 93.6 38.3 114.7
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time-->
23 .30
23 .40
23 .50
Abundance
80000
60000 J
40000
20000
TIC: ENG1656.D
Time--> 25.60 25.70 25.80
Abundance Ion 188.00 (187.70 to 188.70): ENG
1Ion 94.00 (93.70 to 94.70): ENG16
60000 25'69
40000
20000
Time-->
ENGX¥5¥7D—PES 3 .M
1—1—r
25.60
25170
25.80
#11
Phenanthrene-dlO
Concen: 0.52 ng/uL
RT: 25.69 min Scan# 1912
Delta R.T. -0.03 min
Lab File: ENG1656,D
Acq:
14 Oct
99 9
: 45 pm
Tgt
Ion:188
Resp:
114440
Ion
Ratio
Lower
Upper
188
100
94
23 .7
5.8
17.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
OCCJii-y
Mon Oct 18 14:33:39 1999
HP 5989B
Page 1
-------
Abundance
80000
60000
40000 -
20000
0
Time-->
Abundance Ion 178.00 (177.70 to 178.70): ENG
| 80000iIon 176.00 (175.70 to 176.70): ENG
iJLC: CjINvjXdDO . U
25 .70
i 1 ' r
25 .80
25. 75
60000
40000
20000
0
Tirae--»
25.70
25! SO'
Abundance
80000
60000
40000
20000
TIC: ENG165S.D
Time--> 25.70
=ncr -zrr t —ttst"
Abundance Ion 188.00
25.80 25.90
(187.70 to 188.70)
#12
Phenanthrene
Concen: 0.46 ng/uL
RT: 25.75 min Scan# 1921
Delta R.T. -0.02 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pin
Tgt Ion:178 Resp: 131387
Ion Ratio Lower Upper
178 100
176 20.1 10.3 30.8
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#13
Anthracene-dlO
Concen *. 0.38 ng/uL
RT: 25.82 min Scan# 1933
Delta R.T. -0.03 min
Lab Pile: ENG1656.D
Acq:
14 Oct
99 9
: 45 pm
Tgt
Ion:188
Resp:
5367
Ion
Ratio
Lower
Upper
188
100
94
0.0
6.6
19.6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
60000 :
40000
20000 .
0
Ion 94.00 (93.70 to 94.70)
EMT"
ENG 16
25.82
OCCJK'j
Time-->
7D—PKS3.M
1 , j j j 1 1 1 1 f-
25.70 25.80
—r—| , 1 1 r~
25 .90
ENG1656
MOn OCt 18 14:33:42 199y
HP 5989B
Page 8
-------
TIC: Ef75l656.D
jAJbundance
80000
60000
40000
20000
Time
25 .80
T 1 1 1 1 1 T J-
25.90 26;00
Abundance Ion 178,00 (177.70 to 178.70): ENG
80000 HIon 176.00 (175.70 to 176.70): ENG
60000
40000
20000
25 .87
Time-
25 1 80 25190
26 ! 00
20000
Time- - >28140
28.60
28.80
#14
Anthracene
Concen: 0.51 ng/uL
RT: 25.87 min Scan# 1940
Delta R.T. -0.03 min
Lab Pile: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:178 Resp: 68087
Ion Ratio Lower Upper
178 100
176 20.1 8.9 26.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1656.D
60000
40000
#15
Fluoranthene-dl0
Concen: 0.54 ng/uL
RT: 28.68 min Scan# 2371
Delta R.T. -0.03 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:212 Resp:
Ion Ratio Lower
212 100
106
0
0
27.5
0.0
0.0
8.0
0.0
0.0
96895
Upper
23 .8#
0.0
0.0
Abundance Ion 212.00 (211.70 to 212.70): ENG
lion 106.00 (105.70 to 106.70): ENG
28.68
40000
20000
0
Time - - 52 8 .4 0
28.60
28.80
ENGTS5F7B—FES3TFT
Mon Oct 18 14:33:45 1999
0C£)300
HP 5989B
Page 9
-------
(Abundance
60000
40000
TIC: ENG16S6 I'D"
20000
Time--528140 IjsTecT^ 28180 29100
in in mi 1 ¦ - ¦*" *" '**' " ¦ 1 — . M ¦ — , . — , — nm
Abundance Ion 202.00 (201.70 to 2152.70): ENG
60000Jlon 101.00 (100.70 to 101.70): ENG
28.73
40000 -
20000
0
Time--=28.40
28.60
-1 1 1 r
28.80
~1—!—r"
29:00
#16
Fluoranthene(CCC)
Coneen: 0.48 ng/uL
RT: 28.73 min Scan# 2379
Delta R.T. -0.02 rain
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:202 Resp: 121290
Ion Ratio Lower Upper
202
100
101
24.2
9.9
29.6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
80000
60000
40000
20000
Time-
TIC: ENG165 6.D
0
>29 I 00
29.20 29.40
_ ¦ ¦ ¦ 1 " h ¦! 'w h. -h 1 > h . j"****nar*w*******T****^^ ¦ 1 ________ _
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70) : ENG
29.29
40000
20000
0
#17
Pyrene-dlO
Concen: 0.57 ng/uL
RT: 29.29 min Scan# 2462
Delta R.T. -0.03 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:212 Resp: 108156
Ion Ratio Lower Upper
212
100
106
31.8
8.6
25 .6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
OCOsci
lTime-->29 .00
ENGX&5¥7B—PES3 .M
29.20 29.40
Mon Oct IB 14:3J :4B 1999'
HP 5989B
Page 10
-------
Abundance
80000:
60000
TIC: ENG1656.E)
40000
20000 4
0
Time--> 29,20
Abundancelon 202.00
ilon 101.00
60000
40000
20000
29.40
(201.70 to 202.70)
(100,70 to 101.70)
29 .34
"IMS"
ENG
#18
Pyrene
Concen: 0.49 ng/uL
RT; 29.34 min Scan# 2469
Delta R.T. -0.03 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:202 Resp: 136344
Ion Ratio Lower Upper
202
100
101
27.8
14.3
42 . 8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
bi
lme-
29.20
29 .40
Abundance
TIC: BNG1656«D
60000 -
A
40000:
/ \
20000 -
1 V.
0 -
Time-->
t i i i j r i i i | i i i ) i i i i i i i i
29.50 29.60 29.70 29.80
Abundance ion 244.00 (243.70 to 244.70) : ENG
Ion 122.00 (121.70 to 122.70): ENG
29 .62
40000
A
20000
H
0 -
Time - - >
i i i i i I r r t | t i r r |,M r - i i t r i" i
29.50 29.60 29.70 29.80
ENG1556 .D FESTTCT
#19
p - Te rpiieny 1 - d 14
Concen; 0.09 ng/uL
RT: 29.62 min Scan# 2512
Delta R.T. -0.03 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:244 Resp: 89569
Ion Ratio Lower Upper
244 100
122 28.7 6.7 19.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0CC
Hon" Oct" 18 14 T3I151 1999'
HP 5989B
Page 11
-------
Abundance
40000
30000
20000
10000
0
m*f/-*,—tJKfr"1! £Ct£—FT
X Xv«. * CilMvjJ. u ~J D - U
"1 1 1 T"
"i i r~
"T I 1 1
Time--> 33.30 33.40 33.50
Abundance Ion 240.00 (239.70 to 240.70): ENG
ilon 120.00 (119.70 to 120.70): ENG
20000
10000
33.37
Time-
"i 1 r
33 .30
—,—|—r
33 .40
#20
Benzo(a)anthracene-dl2
Coneen: 0.58 ng/uL
RT: 33.37 rain Scan# 3074
Delta R.T. -0.03 rain
Lab File: ENG16S6.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:240 Resp: 34743
Ion Ratio Lower Upper
240
100
120
29.3
7.3
21.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
33 .50
TIC: ENGl&bfe.D
40000:
30000:
20000:
10000 -
0
Time - - > 3 3 ! 30 ' ' 33 !40 ' ' 33 ! 50 ' ' 33160
Abundance Ion 228.00 (227.70 to 228 . 70) : ENG
30000 -
Ion 114.00 (113.70 to 114.70): ENG
20000
33 .46 / \
10000
.
0 J
Time--> 33.30 33.40 33.50 33.60
#21
Benzo(a)anthracene
Concen: 0.52 ng/uL
RT: 33.46 min Scan# 3088
Delta R.T. -0.04 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:228 Resp: 57401
Ion Ratio Lower Upper
228
100
114
25.5
12 .8
38 .2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
oee
t j
HP 5989B
Page 12
-------
[Abundance"
TIC: ENG1656.D
1
40000 .
/ \ A
30000 .
\ \
20000 .
J\! \j V
10000
o
Time-->
33.40 33 .60
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
33 .50
20000 _
A
10000 -
A /\
J V/
0
Time-->
r 1 1 i I 1 ! i 1 1 r i i 1
33;40 33.60
Abundance
40000
30000
20000
10000
TIC: ENG1656.D
0
#22
Chrysene-dl2
Concen: 0.61 ng/uL
RT: 33.50 min Scan# 3094
Delta R.T. -0.04 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:240 Resp: 71499
Ion Ratio Lower Upper
240 100
120 26.4 6.4 19.0#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Tirae--> 33.40 33.60 33.80
AbundanceI on 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
33 .61
#23
Chrysene(CCC)
Concen: 0.54 ng/uL
RT: 33.61 min Scan# 3111
Delta R.T. -0.04 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:228 Resp: 89579
Ion Ratio Lower Upper
228 100
114 22.2 9.1 27 .1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
30000 .
20000
10000
0CC)'je4
Time - - >
-1 1—1 1 F t
33 .40
ENG1656.D—PES3.M
i i 1 1 1 1 1 r—
33.60 33.80
Mon Oct IB 14:33:57 iyyy'
HP 5989B
Page 13
-------
(Abundance
! 40000
i
i
I 30000
20000
TIC: BUG1656.D
Time--> 39!20 ' 39!30 39140 ' ' 39!50 '
Abundance Ion 264.00 (263.70 to 264.70) : ENG
Ion 132.00 (131.70 to 132.70): ENG
39.36
ioooo 1
10000
0
5000
0
Time-->
39.20
39.30
39 .40
39.50
#24
Benzo(b)fluoranthene-dl2
Concen: 0.63 ng/uL
RT: 39.36 min Scan# 3994
Delta R.T. -0.06 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:264 Resp: 43295
Ion Ratio Lower Upper
264
100
132
91.6
8.0
23.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENGlbbb.D
40000 :
30000 -
20000:
ioooo:
o:
Time-->
39.40 39.50 39.60
Abundance Ion 252.00 (251.70 to 252.70) : ENG
j
Ion 126.00 (125.70 to 126.70): ENG
i
39 .51
j 15000:
S
! ioooo:
/ V/A
j
i 5000:
o:
|Time-->
39.40 39.50 39.60
#25
Benzo{b)fluoranthene
Concen: 0.55 ng/uL
RT: 39.51 min Scan# 4018
Delta R.T. -0.07 min
Lab File: SNG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:252 Resp: 60384
Ion Ratio Lower Upper
252
100
126
27.5
13.4
40.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
OCCjS&j
HP 5989B
Page 14
-------
Abundance
TIC: SNG1656.D
40000 :
A
30000.
/\ / \/\
20000 -
y Vy ^ \^_
10000
0 -
Time-->
39.40 39.60
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
10000 -
39.53
5000 -
j w
0
Time-->
39140 39160
#26
Benzo(k)fluoranthene- dl2
Concern 0.64 ng/uL
RT: 39.53 min Scan# 4020
Delta R.T. -0.06 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:264 Resp: 41548
Ion Ratio Lower Upper
264
100
132
31.3
8.5
25.3#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Sundance
TIC: ENG1656.D
40000 :
30000:
20000 .
.
10000
0
Time-->
» * I i j < 1 t t f { i t i j i i r r j r f r > f
39.50 39.60 39.70 39.80
Abundance Ion 252.00 (251.70 to 252.70) : ENG
Ion 126.00 (125.70 to 126.70): ENG
15000 -
/\ 39.66
10000 -
/ vx\
5000
0
Time-->
39.50 39.60 39.70 39.80
#27
Benzo (k.) f luoranthene
Concen: 0.58 ng/uL
RT; 39.66 min Scan# 4041
Delta R.T. -0.06 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:252 Resp: 44176
Lower Upper
13.0 38.8
0.0 0.0
0.0 0.0
Ion
252
126
0
0
Ratio
100
30.2
0.0
0.0
ENG1656.D—FESJ7W
Mbn Oct 18 14:34:03 1999
HP 5989B
0CO5CS
Page 15
-------
Abundance
- «Tp 1 S C C "Pi
11L: hlMtjlobb .L)
20000
— '
10000
0 _
Time-->
i i | . i i . | i
41.40 41.60
1 1 I '
41.80
Abundance Ion 264.00 (263.70 to
264.70) :
SNG
10000 -
Ion 132.00 (131.70 to
132.70) :
ENG
41.62
5000 ^
0.
Time-->
41.40 41.60
41! 80
#28
Benzo(a)pyrene-dl2
Concen: 0.56 ng/uL
RT: 41.62 min Scan# 4340
Delta R.T. -0.07 rain
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pra
Tgt Ioil: 2 64 Resp :
Ion Ratio Lower
21445
Upper
264
100
132
42 .4
8.7
25 .9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
20000
TIC: ENG1656.D
10000
0
#29
Benzo(a)pyrene(CCC)
Concen: 0.61 ng/uL
RT: 41.80 min Scan# 4368
Delta R.T. -0.07 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:252 Resp:
Ion Ratio Lower
29999
Upper
Time--> 41.60 41.80 42.00
Abundance Ion 252.00 (251.70 to 252.70): ENG
JIon 126.00 (125.70 to 126.70) : ENG
252
100
126
30 .2
13 .4
40.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
10000
5000
0
41.80
ocose?
Time--> 41.60
ENGlbbb,D PES3.M
41.80 42.00
Mon Oct 18 14:34:06 1999'
HP 5989B
Page 16
-------
TTC7~~SSRir55F7D"
15000:
10000:
5000:
Time--> 52.20 52.40 52.60 52.80
Abundance Ion 288.00 (287.70 to 288.70): ENG
52 .55
4000
2000 -
52.60 52.80
52 .20
52 .40
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0.66 ng/uL ra
RT: 52.55 min Scan# 6028
Delta R.T. -0.12 rain
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:288 Resp: 25798
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
15000
10000 J
5000
TIC: ENG1656.D
Time-
Abun>
-i r i p
52.60
elon 276.05
Ion 138.00
~~i—-i—¦'-T— ? r~
52.80
' 53l00
4000
2000
0
[275.75 to 276.75): ENG
[137.70 to 138.70}: ENG
52.83
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.58 ng/uL
RT: 52.83 min Scan# 6080
Delta R.T. -0.13 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:276.05 Resp: 29311
Ion Ratio
276 100
138 45.4
Lower Upper
0
0
0.0
0.0
22.8
0.0
0.0
68.2
0.0
0.0
Time-->
52.60
52.80
53.00
0C05503
Mon Oct IB 14:34:09 I9¥9
HP 5989B
Page 17
-------
TIC: SNG1656.D
15000
10000
5000
0
!"" i 1 ! 1 f j r 1 r-
52.40 52160
Time--> 52,20
Abundance Ion 292.00 (291.70 to 292.70!: ENG
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.60 ng/uL m
RT: 52.51 rain Scan# 6021
Delta R.T. -0.12 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:292 Resp: 14321
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
4000
3000
2000
1000 _j
0
52.51
Time - - > 52 .20
52! 40
52.60
TIC: ENG1656.D
15000
10000
5000
Time--> 52.60 52.80 53100
'TW7S 7T7K impfPf w A W7TT
AbundanceIon 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
52 .86
i f f
53 . 20
2000
#33
Dibenz(a,h)anthracene
Concen: 0.62 ng/uL
RT: 52.86 min Scan# 6086
Delta R.T. -0.13 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:278 Resp:
Ion Ratio Lower
278 100
4000
139
0
0
0.0
0.0
0.0
13 .7
0.0
0.0
25767
Upper
41.0#
0,0
0.0
lme-
52.60
i i—|—i—
52.80
—i—|—i—i—i—i—]—i—r
53 .00 53.20
ENGi¥5"6'.D—PES3 .M
Mon Oct 18 14:34:12 1999
HP 5989B
Page 18
-------
TIC: ENG1656.D
Abundance
10000 -
5000 .
55.20 55140 55,60 55.80
Time - - >
Abundance Ion 288.Oo (287.70 to 288.70): ENG
55 .52
4000 -
2000
55.20 55.40 55.60 55.80
Time-->
#34
Benzo(g,h,i)perylene-dl2
Concen: 0.64 ng/uL m
ET: 55.52 min Scan# 6592
Delta R.T. -0.14 min
Lab File: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:288 Resp: 27022
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
10000
5000
TIC: ENGlbbb.D
—(—j—(—j—|—,—,—,—,—.—,—,—,—i—|—r~*~t—i—r~i—i—r
Time-->55.40 55.60 55.50 56.00 56120
Abundance Ion 276.00 (275 .70 to 276.70) :
6000
4000
2000
Ion 138.00
(137.70 to 138.70)
55.85
—1 T
Time-->55140
55.60
n—i—f—i 1
55.80
I—|—j—,—,—|—,—|—i—j—r
56.00 56.20
#35
Benzo(g,h,i)perylene
Concen: 0.56 ng/uL ra
RT.- 55.85 min Scan# 6675
Delta R.T. -0.14 min
Lab Pile: ENG1656.D
Acq: 14 Oct 99 9:45 pm
Tgt Ion:276 Resp: 33201
Ion Ratio Lower Upper
100
65.8 15.9 63.4#
0.0 0.0 0.0
0.0 0.0 0.0
0CC3510
ENG1656.D PES3.M
Mon Oct IB 14*34*15 19'yg
* • W afc w W lar aE a mtf TB « <¦&» mJf mtm nr mS
HP 5989B
Page 19
-------
Quantitation Report
Data Pile
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1657.D
14 Oct 99 10:51 pm
CARB42 9,ICAL1.0
Oct 18 14:19 1999
Vial: 5
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Mon Oct 18 14:35:44 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response
20.00 190 773278
Cone Units Dev(Min)
1) 2,2 -Difluorobiphenyl
System Monitoring Compounds
5.00 ng/uL -0.02
%Recovery
2)
Naphthalene-d8
17 .69
136
419748
0.81
ng/uL
20.18%
4)
2-Methlynaphthalene-dl0
19.37
152
137264
0.87
ng/uL
2.18%
5)
Acenaphthy1ene-d8
21.63
160
131372
1.02
ng/uL
25 .58%
7)
Acenaphthene-dl0
22 .04
164
120082
0.88
ng/uL
21.91%
9)
Fluorene-dlO
23 .31
176
127099
0.91
ng/uL
22.77%
11)
Phenanthrene-dl0
25.69
188
178228
0 .89
ng/uL
22.30%
13)
Anthracene-dl0
25.82
188
88990
7.66
ng/uL
191.58%
15)
Fluoranthene-dlO
28.68
212
172338
1.05
ng/uL
26.28%
17)
Pyrene-dlO
29.29
212
196382
1.10
ng/uL
27.61%
19)
p-Terphenyl-dl4
29.62
244
146620
0.27
ng/uL
0 .68%
20)
Benzo(a)anthracene-dl2
33.36
240
75930
1.35
ng/uL
33.70%
22)
Chrysene-dl2
33 .50
240
128881
1.15
ng/uL
28.77%
24)
Benzo(b)fluoranthene-dl2
39.35
264
76295
1.15
ng/uL
28.64%
26)
Benzo(k)fluoranthene-dl2
39.53
264
74433
1.17
ng/uL
29.35%
28)
Benzo(a)pyrene-dl2
41.61
264
38956
1.10
ng/uL
27.45%
30)
Indeno(1,2,3-cd)pyrene-dl2
*5 . *3
288
46159
1.19
ng/uL
29 . 82%
32)
Dibenz(a,h)anthracene-dl4
52 .50
292
26577
1.16
ng/uL
29.08%
34)
Benzo(g,h,i)perylene-dl2
55 .52
288
47584
1.15
ng/uL
28.75%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.74
128
466075
0.80
ng/uL
99
6)
Acenaphthylene
21.66
152
162706
1.04
ng/uL
90
8)
Acenaphthene(CCC)
22.12
154
144388
0,93
ng/uL
92
10)
Fluorene
23 .38
166
144783
0.89
ng/uL
83
12)
Phenanthrene
25 .74
178
225139
0.91
ng/uL
99
14)
Anthracene
25.87
178
153060
1.28
ng/uL
95
16)
Fluoranthene(CCC)
28.73
202
224744
1.01
ng/uL
91
18)
Pyrene
29 .34
202
251416
1.02
ng/uL
98
21)
Benzo(a)anthracene
33 .46
228
110992
1.12
ng/uL
100
23)
Chrysene(CCC)
33 .61
228
164217
1.07
ng/uL
90
25)
Benzo(b)fluoranthene
39.51
252
112667
1.11
ng/uL
98
27)
Benzo(k)fluoranthene
39.66
252
84073
1.18
ng/uL
97
29)
Benzo(a)pyrene(CCC)
41.78
252
54832
1.16
ng/uL
91
31)
Indeno(l,2,3-cd)pyrene
52.83
276
56716
1.19
ng/uLm
46
33)
Dibenz(a,h)anthracene
52.87
278
45474
1.14
ng/uLm
73
35)
Benzo(g,h,i)perylene
55.84
276
62100
1.13
ng/uL 62
0C€)5ii
(#) = qualifier out of range (m) « manual integration
ENG165 7.D PES3.M Mon Oct 18 14:36:43 1999 HP 5989B
Page 1J
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1657.D
14 Oct 99 10:51 pm
CARB429,ICAL1.0
Oct 18 14:19 1999
Vial: 5
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method : C:\HPCHEM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:35:44 1999
Response via : Multiple Level Calibration
TIC: ENG1657.D
Abundance
550000 j
500000 -
450000
400000 -
350000
300000
2s
250000
200000
18
16
17s
l4{?S
8 10 12
150000
11
4s
100000
50000
3li
Time-->
20,00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0CC35I2
ENG1657.D PES3.M
Mon Oct 18 14:36:51 1999
HP 5989B
Page 2
-------
Abundance
200000 H
100000
TIC: ENG1657.D
0
200000
150000
100000
50000
0
17.69
Time - -> 17 .40
1 r
17; 60
17.80
Abundance
200000
100000
TIC: ENG1S57.D
0
ITime-
-i J r
17 I 60
#2
Naphthalene-da
Concen: 0.81 ng/uL
RT: 17.69 min Scan# 252
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:136 Resp: 419748
Ion Ratio Lower Upper
—!——1 f—1 1 t I 1 1 r—T 1 I 1
Time - -> 17 140 17 160 17 180
Abundance ion 13 6 . 0 0 (135.70 to 136.70): ENG
' -:Ion 68.00 (67.70 to 68.70): ENG 16
136
100
68
15.3
3.9
11.5#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#3
Naphthalene(CCC)
Concen: 0.80 ng/uL
RT: 17.74 min Scan# 260
Delta R.T. -0.02 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:128 Resp: 466075
17 180
AbundanceIon 128.00 (127.70 to 128.705: ENG
Ion 127.00 (126.70 to 127.70): ENG
17.74
200000
i ^3 ri
128
127
0
0
Ratio
100
13.0
0.0
0 ¦ 0
Lower Upper
0.0
0.0
0.0
62 .5
0.0
0.0
100000
0
OCC0513
[Time- - > 17.60 17180
ENG1657.D PES3.M Mon Oct 18 14:36:54 1999
HP 5989B
Page 3
-------
Abundance
TIC: ENG1657.D
60000 -
A
40000.
/ \
20000.
J v
0 „
Time - - >
19.30 19:40
Abundance Ion 152.00 (151.70 to 1S2.70): ENG
80000 :
19 .37
60000 :
A
40000 -
/ \
20000 -
/ \
0 -
J v
Time-->
19.30 19.40
$4
2 - Methlynaphthalene - ell 0
Concen: 0.87 ng/uL m
RT: 19 . 37 mill Scan# 761
Delta R.T. -2.31 rain
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:152 Resp: 137264
Ion Ratio Lower Upper
£r iEr
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 ,0.0 0.0 0.0
abundance
100000
Time-->
50000
TIC: ENG1S5?.D
#5
Acenaphthylene-d8
Concen: 1.02 ng/uL
RT: 21.63 rain Scan# 1298
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:160 Resp: 131372
\ i | i < i i
21.40 21150
21.60
1 t ''
21.70
i—!—i—i—i—i—r~
21.80
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundance Ion 160.00 (159.70 to 160.70): ENG
21.63
60000
40000
20000
Time-->
i i i—| i I I I | i I I—i—e—i—i—r-T . ,
21.40 21.50 21.60 21.70 21.80
ENGT6T5T7D—PES3 . M
iL"3C
Won Oct lb 14:Jb:57 1999
HP 5989B
Page 4
-------
iMnmdance
i 100000 -I
TIC: ENG1657.D
50000
0
Time--> 21140 21160 21.80
abundance Ion 152.00 (151.70 to 152.70)
Ion 153.00 (152.70 to 153.70)
21.66
50000
0
T
Time--> 21.40
21.60
21.80
100000
50000
TIC: ENG1657.D
Time--> 22.00 22.05 22110
Abundance Ion 164.00 (163.70 to 1S4.70)
#6
Acenaphthylene
Concen: 1.04 ng/uL
RT: 21.66 min Scan# 1303
Delta R.T. -0.02 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pra
Tgt Ion:152 Resp: 162706
Ion
152
153
0
0
Ratio
100
13 .0
0.0
0.0
Lower Upper
8.7
0.0
0.0
25.9
0.0
0.0
"SMT
ENG
#7
Ac enapht hene-d10
Concen: 0.88 ng/uL ra
RT: 22.04 min Scan# 1359
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:164 Resp: 120082
Ion Ratio Lower Upper
164 100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HRT
60000
40000
20000
b
22.04
ime-->
22.00
1 ( r—T I 1 1 1 T"
22105 22110
0CCJ515
HP 5989B Page 5
-------
TTCT EWG1657.D
Time - ->
100000 -
50000
0
-1 1 1 1 1 ' 1 1 T 1 1 1 i ] f i r-
22.00 22.10 22.20
AbundanceIon 154.00 (153.70 to 154,70): ENG
Ion 153.00 (152.70 to 153.70): ENG
22.12
80000
60000
40000
20000 :
0
rime-->
i ! i ! 1 1 1 1 r 1 1 r™"—i 1 e 1 r r-
22.00 22!10 22120
#8
Acenaphthene(CCC)
Concen: 0.93 ng/uL
RT: 22.12 min Scan# 1371
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:154 Resp: 144388
Ion Ratio Lower Upper
154
100
153
98 .0
45.5
136 .3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1657.D
100000
50000
T 1 1 1 ] 1 1 1 1 1 ) 1 1 1 1 1 1 3 !—r
fTime-->23 .10 23.20 23 .30 23.40
Abundance Ion 176.00 (175.70 to 176.70): ENG
80000
23 .31
60000 :
40000:
20000
i i 1 ? [ 1 p 1 r 1 ? 1 1—i j !—t—
Time--523 .10 23.20 23.30 23.40
ENGT55T7D PES3 .M
#9
Fluorene-dlO
Concen: 0.91 ng/uL
RT: 23.31 min Scan# 1551
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:176 Resp: 127099
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Mon Oct 18 14:37:03 1999
0CC3516
HP 5989B Page 6
-------
100000
50000
TIC: EUG1SS7.D
#10
PlUO!T6I16
Concen: 0.89 ng/uL
RT: 23.38 min Scan# 1562
Delta R.T. -0.02 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
I ' "| )—\ !' i—(—i—i—i—i I 1 I i—f—r
23130 23! 40 23150
Time--> 23 120
Abundance Ion 166.00 (165.70 to 166.70) ENG
lion 165.00 (164.70 to 165.70}: ENG
Tgt Ion:166 Resp: 144783
Lower Upper
38.3 114.7
0.0 0.0
0.0 0.0
Ion
166
165
0
0
Ratio
100
91.3
0.0
0.0
80000
60000
40000
20000
0
23 .38
Time--> 23.20 23.30
—i i i—r
23 140
23150
Abundance
100000
TIC: ENG1657.D
50000
0
Time--> 25 160 25l70 25180
AbundanceIon 188.00 (187.70 to 188.705
100000 -
ENG"
94.00 (93.70 to 94.70): ENG16
25.69
50000
#11
Phenanthrene-dl0
Concen: 0.89 ng/uL
RT: 25.69 min Scan# 1912
Delta R.T. -0.03 min
T ** V n J i TTiMy"* i /"P" »i
LED Fixe: ENG1657, D
Acq:
14 Oct
99 10
: 51 pm
Tgt
Ion:188
Resp:
178228
Ion
Ratio
Lower
Upper
188
100
94
24 .5
5.8
17.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time--> 25.60
ENG1657.D—PES3 .M
25.70 25.80
Mon uct 18 14:37:06 1999
0CC35L7
HP 5989B Page 7
-------
TIC: ENG165 7TD
100000 -
50000
50000 -
0
Time-
t—i—t—!—r
25.65
25.70 25.75
!—!—!—I—I—r
25.80
Abundance
100000 _
TIC: ENG1657.D
50000
0
t 1 r
25 I 60
Tirae-->
Abundance Ion 188.00
#12
Phenanthrene
Concen: 0.91 ng/uL
RT: 25.74 min Scan# 1920
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:178 Resp: 225139
Ion Ratio Lower Upper
Time --> 25.65 25 !70 25.75 25.80
AbundanceIon 1?8.00 (117. 7d to 178.70):
'Ion 176.00 (175.70 to 176.70): ENG
25.74
100000
178
100
176
20 .2
10.3
30 .8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
25.80 26.00
187.70 to 108.705 : IMG
100000JIon 94.00 (93.70 to 94.70): ENG16
50000
0
Time-->
—
ofWaXOO i . U
25 .60
"PES3TW
25.82
25.80 26 : 00
Mon Oct 18 14:37:09 199"$
#13
Anthracene-dlO
Concen: 7.66 ng/uL
RT: 25.82 min Scan# 1933
Delta R.T. -0.03 min
Lab Pile: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:188 Resp: 88990
Ion Ratio Lower Upper
188
100
94
26.6
6.6
19.6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CCJ513
HP 5989B
Page 8
-------
Abundance
100000
TIC: ENG1657.D
50000
100000
50000
fTime--^5
Abundance
100000
50000
25.87
25.80
25.90
26.00
TIC: ENG1657.D
#14
Anthracene
Concen: 1.28 ng/uL
RT: 25.87 min Scan# 1940
Delta R.T. -0.03 min
Lab Pile: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:178 Resp: 153060
Ion Ratio Lower Upper
Time--=25.70 25.80 25190 26100
Abundance Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 {175.70 to 176.70): ENG
178
100
176
19 .9
8.9
26 .5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#15
Fluoranthene-dlO
Concen: 1.05 ng/uL
RT; 28.68 min Scan# 2371
Delta R.T. -0.03 min
Lab Pile: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:212 Resp: 172338
0
Time-->28140 28160 28180
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
80000 28.68
60000
40000
20000
0
Ion
212
106
0
0
Ratio
100
27.3
0.0
0.0
Lower Upper
8.0
0.0
0.0
23 .8#
0.0
0.0
Time--s28 .40
ENGl'657 ,D—PES3 . M
000513
28160 28180
Mon Oct 18 14:37:12 1999
HP 5989B
Page 9
-------
Abundance
100000
50000
TIC: fiHGl6S7.D
Time--> 28.60 28:80
'Abundancefon 202.00 (201.70 to 202.70)
lion 101.00 (100.70 to 101.70)
28.73
100000
50000
1U
ENG
Time-
28.60
28.80
#16
Fluoranthene(CCC)
Concen; 1.01 ng/uL
RT: 28.73 min Scan# 2378
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion-.202 Resp: 224744
Ion Ratio Lower Upper
202 100
101 24.0 9.9 29.6
0 0.0 0.0 0.0
0 0,0 0.0 0.0
Abundance
150000
100000
50000
Time
KB
TIC: SNG1657.D
29.00 29.20 29.40
elon 212.00" (211.70 to 212.70) : BUG
Ion 106.00 (105.70 to 106.70); ENG
29 .29
50000 .j
\
#17
Fyrene-dlO
Concen: 1.10 ng/uL
RT: 29.29 min Scan# 2462
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:212 Resp: 196382
Ion Ratio Lower Upper
212
100
106
31.6
8.6
25.6#
0
0.0
0.0
0.0
0
0,0
0.0
0.0
0CC3520
Time-->
ENG1657.D
29.00
PES3.M
29.20
29 .40
Mon Oct 18 14:37:15 1999
HP 5989B
Page 10
-------
Abundance
150000
100000
Time - - >
TIC: 2NC?i6s57 ,D
50000
0
1 — "t I I 1 T~
29.20
-1 —! 1 p i 1 r
29.40 29.60
Abundance Ion 202.00 (201.70 to 202.70): BUG
Ion 101.00 (100.70 to 101.70): ENG
29.34
100000
50000 .
Time-
-i 1 1 1 ! j 1 f 1 1 1 j r
29.20 29.40 29.60
#18
Pyrene
Concen: 1.02 ng/uL
RT: 29.34 min Scan# 2469
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 ptn
Tgt Ion:202 Resp: 251416
Ion Ratio Lower Upper
202
100
101
27 .6
14 .3
42.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
Time--> 29140 29160 29180
AJDund^nceIon 244.00 (243.70 to 244.70) ; ENG
Hon 122.00 (121.70 to 122.70) : ENG
29 .62
60000
40000
20000
Time-
29 .40
29.60
29 1 80
#19
p-Terphenyl-dl4
Concen: 0.27 ng/uL
RT; 29.62 min Scan# 2512
Delta R.T. -0.03 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:244 Resp: 146620
Ion
244
122
0
0
ENGT657.D PES3.M
Mon Oct IB 14:37:18 1999
Ratio
100
29.1
0.0
0.0
Lower Upper
6.7
0.0
0.0
19.9#
0.0
0.0
0CC3521
HP 5989B
Page 11
-------
TIC:ENG16S7.D
GOOOO
40000
20000
Time -->33 20 33130 33.40 33150
AbundanceIori 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
40000
30000
20000
10000
0
33.36
#20
Benzo(a)anthracene-dl2
Concen: 1.35 ng/uL
RT: 33.36 min Scan# 3 073
Delta R.T. -0.04 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:240 Resp: 75930
Ion Ratio Lower Upper
240
100
120
27 .9
7.3
21.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
—I , , , 1 , , , jj f-
Time-->33 120 33.30 33.40
33.50
Abundance
60000
iriyr*.—ffivi —rr
11^, J llWviJ.C 3 / « LJ
40000
20000
Time--> 33130 33140 33.50 33160
Abundance Ion 22S.00 (227.70 to 228.70): ENG
lion 114.00 (113.70 to 114.70); ENG
40000
20000
0
33.46
Time-->
ENG1657.D"
I 1 J 1 1 ' 1 ] * 1 1 1 I » 1 J 1 1 ! 1 1 S
33.30 33.40 33.50 33.60
PES3.M Mon Oct 18 14:37:21 1999'
#21
Benzo(a)anthracene
Concen: 1.12 ng/uL
RT: 33.46 min Scan# 3088
Delta R.T. -0.04 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:228 Resp: 110992
Ion Ratio Lower Upper
228
100
114
25 .4
12.8
38 .2
0
0 . 0
0.0
0.0
0
0.0
0.0
0.0
0CO52,
HP 5989B
t
Page 12
-------
Abundance
60000 :
40000
20000 _
(
Time-->
TIC: EHGI65T7T>
33 .40
33! 60
40000
30000
33.50
20000
33 .40
J3 . 60
33 .80
#22
Chrysene-dl2
Concen: 1.IS ng/uL
RT: 33.50 min Scan# 3094
Delta R.T. -0.04 rain
Lab File; ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:240 Resp: 128881
Ion Ratio Lower Upper
240 100
120 27.3 6.4 19.0#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
20000
10000
33.60
Time
33 .40
TIC: ENG1657,D
Abundance
60000
40000
#23
Chryaene(CCC)
Concen: 1.07 ng/uL
RT: 33.61 min Scan# 3111
Delta R.T. -0.04 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:228 Resp: 164217
Time-->
AbundanceXon 228.00 (227.70 to 228. 70): ENG
Ion 114.00 (113.70 to 114.70): ENG
33.61
40000 .
20000
Ratio
100
22 .3
0.0
0.0
Lower Upper
9.1
0.0
0.0
27.1
0.0
0.0
Time-
0CC3523
33.40
33.60
33 .80
ENG1657.D—PES3.M
—Oct" 18'—1."4 » 37'»2'^[—X999
HP 5989B
Page 13
-------
Abundance
' 60000
40000
"TUT: ENG1657 .D
20000 .
Time--> 39.20 39.30
Abundance Ion 264.00
—! j , 1 j , f , r
39140 39.50
20000
15000
10000
5000
Ion 132.00
263.70 to 264.70) : ENG
131.70 to 132.70): ENG
39.35
Time-
39.20
39i30
1—1—I—1—r
39 .40
—j—,—r
39:50
#24
Benzo(b)fluoranthene-dl2
Concern 1.15 ng/uL
RT: 39.35 min Scan# 3993
Delta R.T. -0.07 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion: 264 Resp*. 76295
Ion Ratio Lower Upper
264
100
132
69 .4
8.0
23 .9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENGlbS?,D
|
60000 -
40000
20000 -
0 J
Time-->39
¦ 1
.30
1 ' 1 1
39 .40
1 1 I j 1 » 1 S | ? 1 \ 1
39.50 39.60 39
| '
.70
Abundance Ion
252.00
(251.70 to 252.70):
i m
30000 -
Ion
126.00
(125.70 to 126.70):
ENG
39 .51
20000 .
10000 J
0 J
Time-->39
1 '
.30
' 1 1 '
39.40
'39 1 50 ' '39!60 ' ' 39
i 70
#25
Benzo(b)fluoranthene
Coneen: 1.11 ng/uL
RT.- 39.51 min Scan# 4018
Delta R.T. -0.07 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:252 Resp: 112667
Ion Ratio
252 100
126 27.8
Lower Upper
0
0
0.0
0.0
13.4
0.0
0.0
40.1
0.0
0.0
0CC3524
HP 5989B
Page 14
-------
(Abundance
' 60000 .
40000
TIC: ENG16S7.D
20000
Time - - >3 9 ! 20 39!40 39.60 39.80
AbundanceIon 244.00 (263.70 to 264.70): SNG
20000 jIOn 132-00 (131.70 to 132.70) : ENG
#26
Benzo(k)fluoranthene-dl2
Concen; 1.17 ng/uL
RT: 39.53 min Scan# 4020
Delta R.T. -0.07 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:264 Resp: 74433
• Ion Ratio Lower Upper
264 100
132 35.8 8.5 25.3#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
15000
10000
5000
39.53
Time- -339.20
39.40
*7 1 1 \ 1 1 ! ! r
39.60 39.80
Abundance
TIC: EMG1S57.D
60000 .
A
40000 J
/ \ A
20000 .
J V
0
Time - ->
39 1
40 ' 39!60 ' 39 ! 80
Abundance Ion
252.00 (251.70 to 252.70):
ENG
30000:
Ion
126 .00 (125 .70 to 126.70):
ENG
l \ 39.66
20000 -
10000 -
! o
Time-->
r
39.
40 ' 39.60 ' 39 i 80
#27
Benzo(k)fluoranthene
Concen: 1.18 ng/uL
RT: 39.66 min Scan# 4041
Delta R.T. -0.07 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:252 Resp: 84073
Ion Ratio Lower Upper
252
100
126
27.6
13.0
38.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CO5
HP 5989B
.»< i
Page 15
-------
Abundance
TIC: ENGlfa57.D
20000 -
10000 -
0
Time - ->
41.40 41.60 41.80
Abundance Ion 264.00 (263.70 to 264.70): ENG
10000 -
Ion 132.00 (131.70 to 132.70): ENG
5000.
f\_
0
Tirae-->
i - j I 1 1 k k r r i i i j 1 1 !
41.40 41.60 41.80
#28
Benzo(a)pyrene-di2
Concen: 1.10 ng/uL
RT: 41.61 min Scan# 4339
Delta R.T. -0.08 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:264 Resp; 38956
Ion Ratio Lower Upper
264
100
132
37.8
8.7
25.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1657.D
20000
10000
1—1—'
41.60
i 1 1 1 r-
411 80 42.00
Time - ->
Abundancelon 252.00 (251.70 to 252.70):
"2HS"
15000
10000
5000
Ion 126.00 (125.70 to 126.70) : ENG
41.78
#29
Benzo(a)pyrene(CCC)
Concen: 1.16 ng/uL
RT: 41.78 min Scan# 4366
Delta R.T. -0.08 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:252 Resp: 54832
Lower Upper
13.4 40.1
0.0 0.0
0.0 0.0
Ratio
100
31.2
0.0
0.0
Time--> 41.60 41.80 42!00
ENG1657 .D PEST7M Man Oct IS 14:37:33 1999'
000;:}5 2'Q
HP 5989B
Page 16
-------
TIC: ENG1657.D
20000
10000
Time-
III "1 1 T"f 1 I ¦ V" I I ¦ T"
52.20 52140 52.60 52.80
Abundance Ion 288.00 (287.70 to 288.70)
8000
52.54
6000
4000
2000
Time-
~i—!—|—i—j—i—i—|—f—i—i—i—[ I i—i—i—p-~?—i—i—r
52.20 52.40 52.60 52.80
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 1.19 ng/uL m
RT: 52.54 min Scan# 6026
Delta R.T. -0.13 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:288 Resp: 46159
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1657.D
20000
10000
1 i 1
52 .40
-t—r—r -T' i—T—I—|—?—I—I l |—r~1—T
52.60 52.80 53.00 53^20
Time-->
Abundance Ion 275.05 (275.75 to 276.75) : SNG
Ion 138.00 (137.70 to 138.70): ENG
8000 J 52.83
6000 J
4000
2000
0
Time - - >
ENGX5F77I3—FEHTTW
52.40 52.60 52.80
53:oo 53:20
#31
Indeno(1,2,3-cd)pyrene
Concen: 1.19 ng/uL m
RT: 52.83 min Scan# 6080
Delta R.T. -0.13 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:276.05 Resp:
56716
Ion
276
138
0
0
Ratio
100
60 .1
0.0
0.0
Lower Upper
22.8
0.0
0.0
68 .2
0.0
0.0
0CC3527
won UCt 18 14:377Xr~T9¥S
HP 5989B
Page 17
-------
tVTf*.—CfW"rT^C?7—TS
lit; tt.Nvj.Lb 3 / . U
20000
10000 -
-i 1—' r 'T—~r
Time--> 52 120 52.40 ' 52!60 52ls0
4000
2000 .
Time--> 52.20
52 .40
1 1 1 r-
52. 60
52.80
52160 52180 53l00
Time-->
Abundance Ion 278.00 (277.70 to 278.70)
#32
Dibenz (a, h) anthracene-dl4
Concent 1.16 ng/uL m
RT: 52.50 min Scan# 6018
Delta R.T. -0.14 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:292 Resp: 26577
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
AbundanceIon 292.00 (291.70 to 292.70}: SMG
52.50
TIC: ENG1657.D
20000
10000
8000
6000
4000
2000
0
Ion 139.00 (138.70 to 139.70): ENG
52.87
Time-->
ENG1657.D—PES3 .M
—i \ 1 r"
52.60
! 1 < 1 1 r—| 1 1 1 r-
52.80 53 I 00
#33
Dibenz(a,h)anthracene
Concen 1.14 ng/uL m
RT: 52.87 min Scan# 6088
Delta R.T. -0.12 min
Lab Pile: ENG1657 .D
Acq; 14 Oct 99 10:51 pm
Tgt Ion:278 Resp:
Ion
278
139
0
0
Ratio
100
53.6
0.0
0,0
Lower
13 .7
0.0
0.0
45474
Upper
41.0#
0.0
0.0
0CC3528
Hon Oct 18 14:37:40 1999
HP 5989B
Page 18
-------
TIC: ENG1657.D
10000 .
5000 -
55.20 55.40 55.60 55.80
Time - - >
Abundance Ion 288.00 (287.70 to 288.70): ENG
55 .52
Time-->
55.20 55.40 55.60 55.80
#34
Benzo(g,h,i)perylene-dl2
Concen; 1.15 ng/uL
RT: 55.52 min Scan# 6593
Delta R.T. -0.14 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion-. 288 Resp: 47584
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: SMG1657-D
10000
5000
Time-
55.50
56.00
Abundance Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
80004 55.84
2000
6000
4000
Time-
55.50
56100
ENGTF5T7T3—PES3 ,M
#35
Benzo(g,h,i)perylene
Concen: 1,13 ng/uL
RT: 55.84 min Scan# 6672
Delta R.T. -0.15 min
Lab File: ENG1657.D
Acq: 14 Oct 99 10:51 pm
Tgt Ion:276 Resp: 62100
Ion
276
138
0
0
Ratio
100
16 .2
0.0
0.0
Lower Upper
15.9
0.0
0.0
Man Oct IB 14:37:43 1999
HP 5989B
63.4
0.0
0.0
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Mise
Quant Time
C : \HPCHEM\1\DATA\ENG1S58.D
14 Oct 99 11:57 pm
CARB429, ICAL2 .0
Oct 18 14:38 1999
Vial:
Operator
Inst
Multiplr
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M -
Man Oct 18 14:38:36 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1) 2,2-Difluorobiphenyl
System Monitoring Compounds
20.00 190
846782 5.00 ng/uL -0.02
%Recovery
2)
Naphthalene-d8
17.69
136
737807
1.36
ng/uL
34 .04%
4)
2-Methlynaphthalene-dlO
19.37
152
296054
1.71
ng/uL
4.26%
5)
Acenaphthylene-d8
21.63
160
308604
2 .18
ng/uL
54.55%
7)
Acenaphthene-dl0
22.04
164
290749
2.00
ng/uL
49 .99%
9)
Fluorene-dlO
23.31
176
260738
1.74
ng/uL
43.62%
11)
Phenanthrene-dl0
25.69
188
364242
1.71
ng/uL
42 .77%
13)
Anthracene-dl0
25.82
188
44478
1.31
ng/uL
32.80%
15)
Fluoranthene-dlO
28.68
212
381369
2.10
ng/uL
^3
17)
Pyrene-dlO
29.28
212
437465
2.19
ng/uL
54.74%
19)
p-Terphenyl-dl4
29.62
244
328595
0.73
ng/uL
1.84%
20)
Benzo(a)anthracene-di2
33 .37
240
179496
2 .68
ng/uL
66.92%
22)
Chrysene-dl2
33.50
240
301783
2 .37
ng/uL
59.29%
24)
Benzo(b)fluoranthene-dl2
39.36
264
194840
2:58
ng/uL
64.44%
26)
Benzo(k)fluoranthene-dl2
39.53
264
202774
2 .80
ng/uL
69.96%
28)
Benzo(a)pyrene-dl2
41.62
264
102307
2.57
ng/uL
64.26%
30)
Indeno(1,2,3-cd)pyrene-dl2
52 .53
288
112385
2.53
ng/uL
63.25%
32)
Dibenz (a, h) anthracene - dl4
52.50
292
74317
2 .85
ng/uL
71.34%
34)
Benzo(g,h, i)perylene-dl2
55.53
288
119908
2.55
ng/uL
63.77%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17,74
128
873423
1.44
ng/uLm
99
6)
Acenaphthy1ene
21,66
152
397332
2.29
ng/uL
91
8)
Acenaphthene(CCC)
22 .12
154
298290
1.79
ng/uL
90
10)
Fluorene
23 .38
166
308620
1.78
ng/uL
84
12)
Phenanthrene
25 .74
178
467682
1.77
ng/uL
99
14)
Anthracene
25 .87
178
360916
2 .58
ng/uL
96
16)
Fluoranthene(CCC)
28 .73
202
493814
2.02
ng/uL
90
18)
Pyrene
29 .34
202
551052
2.03
ng/uL
98
21)
Benzo(a)anthracene
33 .46
228
290368
2.59
ng/uL
100
23)
Chrysene(CCC)
33 .61
228
396463
2.33
ng/uL
90
25)
Benzo(b)fluoranthene
39.52
252
293012
2 .56
ng/uL
98
27)
Benzo(k)fluoranthene
39 .67
252
226427
2 .77
ng/uL
93
29)
Benzo(a)pyrene(CCC)
41.79
252
145295
2.70
ng/uL
96
31)
Indeno(1,2,3-cd)pyrene
52.81
276
139977
2.56
ng/uLm
31
33)
Dibenz(a,h)anthracene
52 . 87
278
129249
2.85
ng/uL
94
35)
Benzo(g, h, i)perylene
55 .85
276
151588
2.44
ng/uL
68
(#) = qualifier out of range (m) = manual integration
ENG1658.D PES3.M Mon Oct 18 14:39:03 1999 HP 5989B
•QCC-J530--
Page 1
/
-------
Quantitation Report
vial; 6
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method : c:\HPCHEM\1\METHODS\PES 3.M
Title :
Last Update : Mon Oct 18 14:38:36 1999
Response via : Multiple Level Calibration
Data File : C:\HPCHEM\1\DATA\ENG1658.D
Acq On : 14 Oct 99 11:57 pm
camnlo • fARB429 ICAL2 0
DuillUxw « ^jnJVi ^ f 4. i u
Misc
Quant Time: Oct 18 14:38 1999
TIC: ENG1658.D
Abundance"
600000 -J
550000 -
500000 :
450000 :
400000:
18
8 10 ~
12 16
350000
300000
250000
200000
4S
150000
2(
100000
50000:
A
Time - - >
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0CC3521
ENG1658.D PES3.M
Mon Oct 18 14:39:12 1999
HP 5989B
Page 2
-------
TTC: ENGlbSSTD"
(Abundance
400000
300000
200000
100000 -
Time-->17.40 17:60 17,80
Abundance Ion 136.50 (135.70 to 136.70}
400000 lion 68.00
300000
(67.70 to 68.70}
17.69
T7W1 C
200000
100000
0
?ime-->17 .40
17 . 60
17.80
Abundance
400000
300000
200000
100000
Time-->
Abundance Ion 128.00
Ion 127.00
400000
200000
1 f i r !—t 1 ! j ' 1 rT—i 1 r—*i 1 i i i
17:60 17:70 17.80 17.90
(127.70 to 128.70]
(126.70 to 127.70]
17 .74
IBS"
ENG
0
Time--> 17.60
EI>jgi 6 5 8 . D PBS 3 . M
#2
Naphthalene-d8
Concen: 1.36 ng/uL
RT: 17.69 min Scan# 252
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:136 Resp: 737807
Ion Ratio Lower Upper
136 100
68 16.3 3.9 11.5#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: EMGlbSS.D
17.70 17.80 17.90
Mon Oct 18 14:3y:16 1999
#3
Naphthalene(CCC)
Concen: 1,44 ng/uL m
RT: 17.74 rain Scan# 260
Delta R.T. -0.02 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:128 Resp: 873423
Ion Ratio Lower Upper
128
100
127
13 .3
0.0
62.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC5532
HP 5989B Page 3
-------
Abundance
150000
100000
Time-->
50000
TIC; ENG16S8.D
19.30
19.40
19.50
[abundanceIon 152.00 (151.70 to 152.70}: ENG
19 .37
150000
100000
50000
Time-~>
19.30
19.40
19.50
#4
2-Methlynaphthalene-dlO
Concen: 1.71 ng/uL m
RT: 19.37 min Scan# 761
Delta R.T. -2.31 min
Lab File: ENG1658.D
Acq; 14 Oct 99 11:57 pm
Tgt Ion:152 Resp: 296054
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
150000
100000
50000
TIC: SNG1658.D
#5
Acenaphtby1ene-d8
Concen; 2.18 ng/uL
RT: 21.63 min Scan# 1298
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:160 Resp: 308604
Ion Ratio Lower Upper
Time--> 21140 21.60 21180
Abundance Ion 160.00 (159.70 to 160.70): IMG
160
100
0
0.0
0.0
0.0
0
0.0
0 . 0
0.0
0
0.0
0.0
0.0
150000
100000
50000
21.63
Time--> 21140
ENG1658.D—P1SJTH"
21.60 21.80
Mon Oct T8 14:39:iy 1999'
HP 5989B
Page 4
-------
'Abundance
t 200000
150000
100000
50000
TIC";
ENG1658.D
f]
0
Time--> 21140 21160 ' ' 21180
Abundance Ion 152.00 (lSl.70 to 152.70): fiNG
ilon 153.00 (152.70 to 153.70): ENG
21.66
2000Q0
150000
100000
50000
0
Time--> 21.40
"i 1 r- 1 r~—i 1 1 r
211 60 21.80
100000
i 1 !—j—! \—i—I—I—I 1—i—1—|—r—i—?—I—r—I—r—r
Time--> 21.90 22.00 22.10 22.20
Abundance Ion 164.00
150000
100000
50000
(163.70 to 164.70) :
22 .04
0
lTime-->
ENG1658.D
~1—r"~i—r—t—
21.90
22 .00
—t , , , 1 , f-—f
22 .10 22.20
#6
Acenaphthylene
Concen: 2.29 ng/uL
RT: 21.66 min Scan# 1303
Delta R.T. -0.02 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:152 Resp: 397332
Ion Ratio Lower Upper
152 100
153 13.1 8.7 25.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENGlb 5 8.D
200000
#7
Acenaphthene-dlO
Concen: 2.00 ng/uL
RT: 22.04 min Scan# 1359
Delta R.T. -0.03 min
Lab Pile: ENG1658.D
Acq; 14 Oct 99 11:57 pm
Tgt Ion:164 Resp: 290749
Ion Ratio Lower Upper
164
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
IKS"
PES3.M
"Won Oct 18 14:39:23 1999
0CC3534
HP 5989B Page 5
-------
TIC: ENG1658.D
200000 .
100000
0
-1 1 1 ] 1——i r- i i ! 1 1 1 1 1 1 1 1 r
Time--> 22.00 22.10 22.20
Abundance Ion 154.05 (153.70 to 154.70): ENG
'Ion 153.00 (152.70 to 153.70): ENG
22.12
150000
100000
50000 .
Time-->
22.00
22.10
22 .20
psiiK
200000
100000
TIC: ENG1658.D
Time--> 23.20 23:30 23:40
AbundanceIon 176.00(175.70 to 176.70): ENG
150000
2 3 • 3 X
1 1 ! t
23 .30
100000
50000
#8
Acenaphthene(CCC)
Concen: 1.79 ng/uL
RT: 22.12 min Scan# 1371
Delta R.T. -0.03 rain
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:154 Resp: 298290
Ion Ratio Lower Upper
154
100
153
99.9
45.5
136.3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#9
Fluorene-dlO
Concen: 1.74 ng/uL
RT: 23.31 min Scan# 1551
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:176 Resp: 260738
Lower Upper
0,0 0.0
0.0 0.0
0.0 0.0
Ion
176
0
0
0
Ratio
100
0.0
0.0
0.0
Time--> 23.20 23.30 23.40
ENG1658 ,D—PES3 . M Mon Oct IB 14:39:26 1999*
0CC353S
UTS CODQC rj-ay-r^* C
**». «}«? oJd xr di^S o
-------
TIC: ENG1&58
.D
1
200000 J
100000 -
a 1
n
J v V
Time-->
—I r—r~ i—'t i 1 1 i f T r r —r
23.20 23.30 23.40
f - , r
23,50
' ' 1
Abundance
150000
Ion 166.00 (165.70 to
Ion 165.00 (164.70 to
23 .38
A
166.70):
165.70) :
ENG
ENG
100000
n
50000 .
0 .
J V
Time-->
1 j i ' ' * | 1 ' 1 1 j ' !
23.20 23.30 23.40
till
23 .50
#10
Fluorene
Concert: 1.78 ng/uL
RT: 23.38 rain Scan# 1562
Delta R.T. -0.02 min
Lab File; ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:166 Resp: 308620
Ion Ratio Lower Upper
166 100
165 90.4 38.3 114.7
0 0.0 0.0 0.0
0 0,0 0.0 0.0
TIC: ENG1658.D
Abundance
200000
100000
Time- - > IsTio 25170 25 180
ABundancelon 188.00 {187.70 to 188.705
200000
150000
100000
50000
0
94.00
mr
(93.70 to 94.70): ENG16
25.69
Time--> 25.60
ENG1658.D PES3.M
#11
Phenanthrene- dl 0
Concen .• l. 71 ng/uL
RT: 25.69 rain Scan# 1912
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:188 Resp: 364242
Ion Ratio Lower Upper
188
100
94
25.5
5 .8
17 .2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC0536
25170 25180
"MoETOct 18 14:39:29 1999'
HP 5989B
Page 7
-------
j&bundance
200000
100000
TIC: ENG16S8.D
Time—> 25.70 25.80
AbundanceIon 178.00 (177.70 to 178,70): SNG
Ion 176.00 (175.70 to 176.70): ENG
25.74
200000
100000
Time-
25 .70
25 .80
Abundance
200000
100000
0
TIC: ENG1658.D
#12
Phenanthrene
Concen: 1.77 ng/uL
RT: 25.74 min Scan# 1920
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:178 Resp: 467682
Ion Ratio Lower Upper
178
100
176
20.2
10 . 3
30.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#13
Anthracene-dlO
Concen: 1.31 ng/uL
RT: 25.82 min Scan# 1933
Delta R.T. -0.03 min
Lab File: ENG1658.D
Time-->25.60 25 170 25180 25190 26100
Abundance Ion 18 8.00 (187.70 to 188.*70): ENG
200000 Jlon 94.00 (93.70 to 94.70): ENG16
Acq;
14 Oct
99 11:
: 57 pm
Tgt
Ion.-188
Resp:
44478
Ion
Ratio
Lower
Upper
188
100
94
26.7
6.6
19 .6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
150000
100000
50000
Time-->25.60
ENG1658.D—PKSJ.M
25.82
1—r
25170
25.80 25190 26100
Mon Oct 18 14:39:33 1999'
0CC3537
HP 5989B
i
Page 8
-------
(Abundance
200000 .
100000
TTUr~IMST£5S7D~
Time-->25.70 25:80 25.90 26.00
Abundance Ion 178.00 (177.70 to 175.70): BNG
Ion 176.00 (175.70 to 176.70): ENG
#14
Anthracene
Concern 2.58 ng/uL
RT: 25.87 min Scan# 1940
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:178 Resp: 3 60916
Ion Ratio Lower Upper
178 100
176 19.4 8.9 26.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
200000 -
100000
25.87
Time-
\ I
>25170
25 .80
~t 1 j 1 ! 1 j 1 ? r
25.90 26.00
Abundance
200000
100000
0
TIC: ENG1658.D
Time-->28:40 28!60 28:80
Abundance Ion 212.00 (211.70 to 212.10) : 2MG
200000 -|ion 106.00
150000
100000
50000
(105.70 to 106.70): ENG
28 .68
#15
Fluoranthene-dlO
Concen: 2.10 ng/uL
RT: 28.68 min Scan# 2371
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:212 Resp; 381369
Ion Ratio Lower Upper
212
100
106
27.6
8.0
23.8#
0
0.0
0,0
0.0
0
0.0
0.0
0.0
Time-->28.40
ENG1658.D PES3.M
28.60 28.80
Mon Oct 18 14:39:36 1999'
HP 5989B
m
Page 9
-------
(Abundance
200000
100000
"TIC; ENG1658.D
Time--> 28.60 28,80
Abundance Ion 202,00 (201.70 to 202.70)
Ion 101,00 (100.70 to 101.70):
28.73
TMT
ENG
200000
100000
0 -
Time-->
28.60
n i j ¦—r"
28.80
—r
Abundance
300000
200000
100000 -
TIC: ENG1S58.D
0
J
#16
Fluoranthene(CCC)
Concen: 2.02 ng/uL
RT: 28.73 rain Scan# 2378
Delta R.T. -0.03 min
Lab Pile: ENG1658.D
Acq: 14 Oct 99 11:57 pra
Tgt Ion:202 Resp: 493814
Ion Ratio Lower Upper
202 100
101 24.4 9.9 29.6
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#17
Pyrene-dlO
Concen: 2,19 ng/uL
RT: 29.28 min Scan# 2461
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:212 Resp: 437465
Ion Ratio Lower Upper
Time--> 29 100 29T20 29140
Abundance Ion 212.00 (211.70 to 212.70): ENG
Won 106.00 (105.70 to 106.70) : ENG
200000 J 29.28
150000
212
100
106
31,0
8.6
25. 6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
100000
50000 :
0
Time--> 29.00
ENGXF5"8TD—PES3 .M
' 1 1 ' 1 \ { \
29.20 29.40
Mon Oct 18 14:39:39 1999'
5 m
Page 10
HP 5989B
-------
pffiuMarice
i 300000 4
200000
100000
Time-->
TIC: ENG1658.D
29.20
29.40
29.60
100000 4
Time-
29.20
k
29.40
29160
Abundance
300000
200000
100000
TIC: 1NG1658.E)
Time--> 29.40
Abundance Ion 2 44.0 0
Hon 122.00
150000 -
iooooo 4
$18
Pyrene
Coneen: 2.03 ng/uL
RT: 29,34 min Scan# 2469
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:202 Resp: 551052
Ion Ratio Lower Upper
202 100
27.2 14.3 42.8
0.0 0.0 0.0
0.0 0.0 0.0
[abundanceIon 202.00 (201.70 to 202.70): BUG
lion 101.00 (100.70 to 101.70): ENG
29.34
200000
#19
p-Terphenyl-dl4
Concen: 0.73 ng/uL
RT: 29.62 min Scan# 2511
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:244 Resp: 328595
29.60 29.80
(243.70 to 244.70); ENG
(121.70 to 122.70): ENG
29.62
Ion
Ratio
Lower
Upper
244
100
122
29.5
6.7
19.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
50000
0
Time--> 29.40
ENGlbbB .D—PEST.M
29.60 29 .80
Mon Oct 18 14:39:43 TW9"
0003520
HP 5989B Page 11
-------
Abundance
150000 -i
100000
50000 ,
TIC; ENG1658.D
50000
0
33.37
Time-->
Abundance
150000
100000
50000
—_
33.30
1 1 , 1 1 1 r-
33.40 33.50
TIC: ENG16S8.D
Time- - > 33130 33i40 33150 33160
Abundance Ion 228.00 (227.70 to 228.70): ENG
lion 114.00 (113.70 to 114.70): ENG
i—i—|—i—i—r~
33.40 33 150
#20
Benzo(a)anthracene-dl2
Concen: 2.68 ng/uL
RT: 33.37 min Scan# 3074
Delta R.T. -0.03 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:240 Resp: 179496
Ion Ratio Lower Upper
"T ! 1 ( -] f ] 1 1 1 1 1 1 1 1 1
Time--> 33.30 33.40 33.50
II ¦ ¦ ** * J. A 7C7S 1 H""! WTK zrr M i Pi t
Abundance Ion 240.00 i2Jy,70 to 240.70): ENG
100000 J Ion 120.00 (119.70 to 120.70): ENG
240
100
120
28 .9
7.3
21.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
100000
50000
0
33.46
Time--> 33.30
ENG1658.D PES3.M
#21
Benzo(a)anthracene
Concen: 2.59 ng/uL
RT: 33.46 min Scan# 3088
Delta R.T. -0.04 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:228 Resp: 290368
Ion Ratio Lower Upper
228
100
114
25.2
12.8
38.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
33.40 33.50 33.60
Won Oct IB 14:39:46 199*
HP 5989B
Page 12
-------
Abundance
150000
100000 .
50000
100000
50000
Time - ->
33.40
33160
Abundance
150000 J
100000
TIC: ENG1658.D
50000
0
Time--> 33.40 33.60 33180
Abundance Ion 228.00 (227.70 to 228.TU): ENG
jlon 114.00 (113.70 to 114.70): ENG
#22
Chrysene-dl2
Concen: 2.37 ng/uL
RT: 33.50 min Scan# 3094
Delta R.T. -0.04 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:240 Resp: 301783
Ion Ratio Lower Upper
Time--> 33 140 33 160
AbundanceIon 240.00 (239.70 to 240.70): SNG
240
100
120
27 .0
6.4
19.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Ion 120.00 (119.70 to 120.70): ENG
33 .50
#23
Chrysene(CCC)
Concen: 2.33 ng/uL
RT: 33.61 min Scan# 3111
Delta R.T. -0.04 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:228 Resp: 396463
Ion Ratio Lower Upper
228
100
114
22 .5
9.1
27.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
33.61
100000
50000
Time--> 33T40
ENG1658 .D—PES! .M
33 .60
t 1 r "i 1 r-
33.80
Mon Oct IB 14:39:49 iy99
HP 5989B
J03542
Page 13
-------
TIC: ENG1658,D
100000
50000
Time-
39.20 39.30 39.40
39 .50
Abundance Ion 264.00 (263.7d to 264.70):
Ion 132.00 (131.70 to 132.70) :
39.36
40000
20000
Time-
-i r—r—f—i—J—i 1 1—
39.20 39.30
—i—i—i—r
39 .40
—i—i—\—r
39150
#24
Benzo(b)fluoranthene-dl2
Concen: 2.58 ng/uL
RT: 39.36 rain Scan# 3994
Delta R.T. -0.06 min
Lab File; ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:264 Resp: 194840
Ion Ratio Lower Upper
264 100
132 47.2 8.0 23.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
100000
TIC: ENGISW7D"
50000
0
#25
Benzo(b)fluoranthene
Concen: 2.56 ng/uL
RT: 39.52 min Scan# 4019
Delta R.T. -0.06 min
Lab File; ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:252 Resp: 293012
Ion Ratio Lower tipper
Time--> 39140 39150 39160 39170
Abundance I on 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
39.52
60000
40000
252
100
126
27.6
13 .4
40.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
20000
0
0CC5513
~r—r—i—I—i—1—1—1—I—1—1—r
Time--> 39.40 39.50
ENGI658TD—PES3 .M
—I 1 1 1 1 f 1
39160 39170
Mon Oct 18 14:39:52 1999
HP 5989S
Page 14
-------
Abundance
TIC: ENG1658.D
100000 -
A
50000 -
f\J VA
0 .
Time-->39
! 20
39.40 39.60 39 .80
AbundanceIon
264.00 (263.70 to 264.70): ENG
Ion
132.00 (131.70 to 132.70): ENG
39.53
40000 _
20000 .
0 _
Time - ->39
1 20
S !' I E i ~ 1 1 | ' 1 * " f f 1 " I " 1 1
39.40 39.60 39.80
#26
Benzo(k)fluoranthene-dl2
Concen: 2.80 ng/uL
RT: 39.53 mill Scan# 4020
Delta R.T. -0,06 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:264 Resp: 202774
Ion Ratio Lower Upper
264
100
132
34 .4
8.5
25.3#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1658,D
100000
50000
"9:40
-I ! \—"T
39160 39180
Time
Abundance Ion 252.00 (251.70 to 252.70): 1NG
Ion 126.00 (125.70 to 126.70}: ENG
60000
40000
20000 J
—i p—1 f 1 r
T ime39.40 39.60
1NG1658.D—PES3TR
~| ! 1 !—
39:80
#27
Benzo (k)fluoranthene
Concen: 2.77 ng/uL
RT: 39.67 min Scan# 4041
Delta R.T. -0.06 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:252 Resp;
Ion
252
126
0
0
Ratio
100
29.3
0.0
0.0
Lower
13.0
0.0
0.0
226427
Upper
38.8
0.0
0.0
0CC3544
Hon Oct IB 14:39:bS 1999
HP 5989B
Page 15
-------
Abundance
TIC: SMG1658.D
A
40000 .
A A
30000 :
20000 -
J V
10000 -
0
Time - - >
—f "J \ f j I 1 I 1 J 1 i r 1 j « * 1 « j
41.40 41.60 41.80
Abundance Ion 264.00 1263.70 to 264. '/uj : kng
Ion 132.00 (131.70 to 132.70): ENG
20000 :
41.62
A
15000 -
A
10000 -
5000 -
J v
0 -
Time - ->
41.40 41.60 41.80
#28
Benzo (a) pyrene-dl2
Concern 2.57 ng/uL
RT: 41.62 mill Scan# 4340
Delta R.T. -0.07 min
Lab File; ENG1658.D
Acq; 14 Oct 99 11:57 pm
Tgt Ion:264 Resp: 102307
Ion Ratio Lower Upper
264
100
132
36.7
8.7
25 .9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1658.D
Abundance
40000
30000
20000
10000
-i 1 1 1 1 f 1 r
41.60 41.80 42100
T ! i
Time-->
_ "a zn j."z. g ^ a a—/a f i—wt%—¦1 jit***—w"X"\
Abundance Ion 2 52.00 (251.70 to 252.70} : ENG
Ion 126.00 (125.70 to 126.70): 1NG
30000. 41.79
20000
10000
0
1 ! s 1 r-
Time--> 41.60
ENG165B.D—PES3.M
—j— 1 1 1 1 1 1 1 r
41.80 42.00
#29
Benzo(a)pyrene(CCC)
Concen: 2.70 ng/uL
RT: 41.79 min Scan# 4367
Delta R.T, -0.08 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:252 Resp: 145295
Ion Ratio Lower Upper
252
100
126
28 .9
13 .4
40.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Mon Oct 18 14:39:58 199~9
0CCJ545
HP 5989B Page 16
-------
TIC: ENG1658.D
Abundance
40000 -
30000 :
20000 :
52.60
52.80
52.40
Time--> 52.20
Abundance Ion 288.00 (287.70 to 288.70): ENG
15000 .
52.53
10000 -
5000 -
52.60
52.80
Time--> 52.20
52 .40
#30
Indeno(1,2,3-cd) pyrene-dl2
Concen-. 2.53 ng/uL m
RT: 52.53 min Scan# 6025
Delta R.T. -0.14 min
Lab File: 1NG1658.D
Acq: 14 Oct 99 11:57 ptn
Tgt Ion:288 Resp: 112385
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: EMG1S58.D
40000
30000
20000
10000 :
#31
Indeno(1,2, 3-cd)pyrene
Concen: 2.56 ng/uL m
RT: 52.81 min Scan# 6076
Delta R.T. -0.15 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:276.05 Resp: 139977
Ion Ratio Lower Upper
Time--> 52 140 52160 52:80 53 100
Abundance Ion 276.OS (27S.7S to 276.75)
Ion 138.00 {137.70 to 138.70)
52 .81
15000
—r_r_
52; 80
i I I i
10000
276
100
138
50.1
22.8
68 .2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
emg
ENG
5000
0
Time-~> 52.40
ENG165B :D FEST7FT
—,—|—,—r-
52.80
I [ ! T
53 .00
52 :eo
Mon Oct IB 14:40:01 1999'
0C03546
HP 5989B
TO
Page 17
-------
Abundance
TIC: 2MG16S8.D
40000 .
j
30000 .
r\
20000:
10000
o
Time-->
52.20 52.40 52.60 52.80
Abundance Ion 292.00 (291.70 to 292.70): ENG
10000 -
52.50
5000
J V.
0
/
Tirae-->
52!20 ' ' 52 !40 ' ' 52160 ' ' 52^80
#32
Dibenz(a,h)anthracene-dl4
Concen: 2.85 ng/uL m
RT: 52.50 min Scan# 6019
Delta R.T. -0.13 min
Lab File; ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion;292 Resp: 74317
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENGlfeSa.D
40000
A
30000
f\ / \
20000
J \J \
10000
0
Time--> 52.40 52.60 52.80 53.00 53.20
Abundance Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
52.87
15000 _
A
10000 -
/ \
5000 .
1 0 -
Time--> 52 .40 52 ieo 52 Iso' 53 I 00 *53 ! 20'
ENG1658.D PEBT7M
#33
Dibenz(a,h)anthracene
Concen: 2.85 ng/uL
RT: 52.87 min Scan# 6088
Delta R.T. -0.12 min
Lab File: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:278 Resp: 129249
Ion Ratio
278 100
139 30.5
0 0.0
0 0.0
Lower Upper
13 .7
0.0
0.0
41.0
0.0
0.0
Won Oct 18 14:40:04 1999
0CC3547
HP 5989B Page 18
-------
TIC: SNG16S8.D
20000
10000
t—r~n—i—|—r—?—i—j—r—i—s—t—!—i—i—i—i—i—i—i—i—i—i—r~r
55.20 55:40 55.60 55.80
Time-->
Abundance Ion 288.00 {287.70 to 288.70)
15000
10000
5000
55 .53
Time-
55.20 55.40 55.60 55.80
#34
Benzo
I ¦• » > » i i i
55.50 55.00
i r
Abundance Ion
275.00 (275.70 to 276.70):
ENG
Ion
138.00 (137.70 to 138.70):
ENG
55.85
15000 -
10000
5000
6
Time - - >
55.50 56.00
1 ' ¦" I '
#35
Benzo(g,h,i)perylene
Concen: 2.44 ng/uL
RT: 55.85 min Scan# 6673
Delta R.T. -0.15 min
Lab Pile: ENG1658.D
Acq: 14 Oct 99 11:57 pm
Tgt Ion:276 Resp: 151588
Ion Ratio Lower Upper
276
100
138
19 . 8
15.9
63 .4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HP 5989B
il
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\KPCHEM\l\DATA\ENG1659.D
15 Oct 99 1:04 am
CARB429,ICAL3.0
Oct 18 14:40 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\METH0DS\PES 3.M
Mon Oct 18 14:41:01 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2, 2-Difluorobiphenyl
20.00
190
804445
5.00
ng/uL
¦ i
O l
O I
to 1
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
17.69
136
961211
1.99
ng/uL
49.86%
4)
2-Methlynaphthalene-dlO
19.37
152
425723
2.51
ng/uL
6 .27%
5)
Acenaphthylene-d8
21.63
160
462602
3 .38
ng/uL
84.54%
7)
Acenaphthene-dlO
22.04
164
390213
2 .82
ng/uL
70.62%
9)
Fluorene-dlO
23 .31
176
358343
2 .59
ng/uL
64.76%
11)
Phenanthrene-dl0
25.69
188
497786
2.53
ng/uL
63.36%
13)
Anthracene-dlO
25.82
188
70455
2.35
ng/uL
58.73%
15)
Fluoranthene-dlO
28 .68
212
528426
3.03
ng/uL
75 .74%
17)
Pyrene-dlO
29.28
212
610431
3 .16
ng/uL
78.91%
19)
p-Terpheny1-dl4
29.62
244
455289
1.27
ng/uL
3 .18%
20)
Benzo(a)anthracene-dl2
33 .36
240
280945
4 .13
ng/uL
103.27%
22)
Chrysene-dl2
33.50
240
452669
3,61
ng/uL
90.26%
24)
Benzo(b)fluoranthene-dl2
39.35
264
300241
3 , 95
ng/uL
98.82%
26)
Benzo(k)fluoranthene-dl2
39.53
264
334446
4.50
ng/uL
112.49%
28)
Benzo(a)pyrene-dl2
41.61
264
169936
4.25
ng/uL
106.30%
30)
Indeno(1,2,3-cd)pyrene-dl2
52.54
288
186359
4.19
ng/uL
104.85%
32)
Dibenz(a, h)anthracene-dl4
52 .51
292
120334
4,48
ng/uL
112.04%
34)
Benzo(g,h,i)perylene-dl2
55.52
288
197707
4.20
ng/uL
104.90%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.74
128
1166954
2 .15
ng/uLm
99
6)
Acenaphthylene
21.66
152
611152
3 .60
ng/uL
91
8)
Acenaphthene(CCC)
22 .12
154
428744
2 .77
ng/uL
92
10)
Fluorene
23 .38
166
441655
2 .74
ng/uL
85
12)
Phenanthrene
25.74
178
653934
2.66
ng/uL
99
14)
Anthracene
25.87
178
546534
3 .88
ng/uL
96
16)
Fluoranthene(CCC)
28.73
202
712995
3 .07
ng/uL
89
18)
Pyrene
29 .34
202
788880
3 .05
ng/uL
98
21)
Benzo(a)anthracene
33 .46
228
470835
4.17
ng/uL
99
23)
Chrysene(CCC)
33 .61
228
607292
3 .63
ng/uL
90
25)
Benzo(b)fluoranthene
39 .52
252
480122
4.19
ng/uL
99
27)
Benzo(k)fluoranthene
39.67
252
374667
4.48
ng/uL
91
29)
Benzo(a)pyrene(CCC)
41.79
252
248990
4.56
ng/uL
97
31)
Indeno(1,2,3-cd)pyrene
52.82
276
255763
4 .66
ng/uL
94
33)
Dibenz(a,h)anthracene
52.85
278
228310
4.89
ng/uL
94
35)
Benzo(g, h, i)perylene
55.84
276
251908
4.08
ng/uL
95
0CC3519
(#) = qualifier out of range (m) = manual integration
ENG1659.D PES3.M Mon Oct 18 14:42:05 1999 HP 5989B
Page 1 /
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1659.D
15 Oct 99 1:04 am
CARB429,ICAL3.0
Oct 18 14:40 1999
Method
Title
Last Update
Response via
C:\HPCH1M\1\METH0DS\PES3.M
Mon Oct 18 14:41:01 1999
Multiple Level Calibration
Vial: 7
Operator:
Inst : HP 5989B
Multiplr: 1.00
TIC: ENG16S9.D
Abundance
750000 :
700000 :
650000 :
600000
550000
18
16
500000
10
450000
12
1; s UU9S
350000:
c
4S
250000 :
150000:
29
28s
100000
M— ^ u"
f — T T—f—r—i—i—I 1—!—I—I—I 1—I 1—r—I—i—t—I—I—!—i—t—f—I—j—i—i—!—I—I—I—r—1 1—j 1—
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0CCj5c0
ENG1659.D PES3.M Mon Oct 18 14:42:13 1999 HP 5989B Page 2
-------
Abundance
600000 -
400000
200000
TIC; ENG1659.D
0
200000
0
Time--> 17 .40
17 .60
~i e t r r r
17180
Abundance
600000
400000
200000 .
0
TIC: EMG1659.D
#2
Naphthalene-d8
Concen: 1.99 ng/uL
RT: 17.69 min Scan# 252
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:136 Resp: 961211
Ion Ratio Lower Upper
Time--> 17 140 17.60 17.80
Abundance Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG16
17.69
400000
136
100
68
16.8
3.9
11.5#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#3
Naphthalene(CCC)
Concen: 2.15 ng/uL m
RT: 17.74 min Scan# 259
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion: 128 Resp-.
Ion Ratio Lower
128 100
h—i—|—l—t—i—r—i—i—i—i—i—r—i—t—i—i—p-r—j—i—r
Time-->17.50 17.60 17.70 17.80 17.90
Abundance Ion 126.00 (127.70 to 128.70): ENG
lion 127.00 (126.70 to 127.70): ENG
600000 J 17.74
400000
127
0
0
13 .6
0.0
0.0
0.0
0.0
0.0
1166954
Upper
62.5
0.0
0.0
200000
-i i ! s | i i i i—|—i—r— i " r"-"r" i—i—i——i -t ¦t 17
Time-->17:50 17,60 17.70 17.80 17190
0CC3551
ENGIbSy.D t»ES3.M
Mon Oct 18 14:42:17 1999
HP 5989B
Page 3
-------
Abundance
200000
150000
X00000
50000
TIC: EWG1659.D
19 .30
19.40
19 .50
T ime - - >
Abundance Ion 152.00 (151.70 to 152.70): EWG
19 .37
200000
100000
Time*
Abundance
300000
200000
100000
0
19 .30
19140
19 1 50
TIC: BUG1659.D
Time--> 21140 21.60 21180
AbundanceIon 160.00 (159.70 to 160.70]
21.63
200000
100000
Time--> 21.40
EM2T55W7D—FE5T7H
#4
2-Methlynaphthalene-dlO
Concen: 2.51 ng/uL m
RT: 19.37 min Scan# 760
Delta R.T. -2.31 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:152 Reap: 425723
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#5
Acenaphthy1ene-d8
Concen: 3.38 ng/uL
RT: 21.63 min Scan# 1298
Delta R.T. -0.03 min
Lab Pile: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:160 Resp: 462602
Ion Ratio Lower Upper
160 100
0 0.0 0.0 . 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
OCC0552
21.60 21.80
Man Oct IB 14:42:20 1999'
HP 5989B
Page 4
-------
[Abundance
i
i
I 300000:
200000
100000
Time-
TIC: ENG1659.D
21.40
21,60
1 | 1 t
21.80
Abundance Ion 152.00 {151.70 to 152.70); ENG
Ion 153.00 (152.70 to 153.70); ENG
21.66
300000
200000 J
100000
Time--> 21,40
21.60
7 1 j r
1 1 r~
21.80
Abundance
400000
300000
200000
100000
0
Time-->
1—|—r
21.90
22.00
22.1cT 22.20
Abundance Ion 164.00 (163.70 to 164.70): 2NG
200000
150000
100000 4
50000 J
22.04
Time-
2ll90 22:00
—I 1 f-—| f—-1 r—
22.10 22;20
#6
Acenaphthylene
Concen: 3.60 ng/uL
RT: 21.66 min Scan# 1303
Delta R.T. -0.02 min
Lab File: ENG1659.D
Acq; 15 Oct 99 1:04 am
Tgt Ion:152 Resp: 611152
Ion Ratio Lower Upper
152 100
153 13.3 8.7 25.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TTC7 ENG1659.D
ENG1659.D—PES3.M
#7
Acenaphthene-dlO
Concen: 2.82 ng/uL
RT: 22.04 min Scan# 1359
Delta R.T. -0.02 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:164 Resp: 390213
Ion Ratio
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Lower Upper
0CC3553
Mon Oct 18 1*7*2:23 1999
HP 5989B
Page 5
-------
pE
400000 J
300000
200000
100000
TIC: 2NG1655.D
0
Time-
¦¦—i—r
22 .00
r——j 1 r
22.20
Abundance Ion 154 00
Ion 153.00
200000
100000 -
(153.*>0 to 154.70}
(152.70 to 153.70)
22 .12
"BUG"
ENG
#8
Acenaphthene(CCC)
Concen: 2.77 ng/uL
RT: 22.12 min Scan# 1371
Delta R.T. -0.02 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:154 Resp: 428744
Ion Ratio Lower Upper
154 100
153 98.1 45.5 136.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time-
22 .00
22.20
Abundance
400000
TIC: ENG1659.D
h
300000
200000 .
100000 .
.Time-->23 .10 '23 120
i 1 r r—! F \ r—t t
23.30 23.40
Abundance Ion 176.00 (175.70 to 176.70): ENG
200000
150000
100000
50000
23 .31
#9
Fluorene-dlO
Concen; 2.59 ng/uL
RT: 23.31 min Scan# 1551
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:176 Resp: 358343
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
| ¦ "'i i ' !—r—i—i—> j—i—r—-r—i—|—i i 'i t
Time-->23.10 23.20 23.30 23.40
ENG1659.D—PES3.M
Mon Oct 18 14:42:26 1999
00C35
f-?
HP 5989B
Page 6
-------
EMJlbSy
Abundance
400000
300000
200000
100000
i—i—i—i—|—i—i i i (
Txttie - -> 23.20 23.30 23.40 23.50
Abundance ton 166.00 (165.70 to 166.70):
lion 165.00
(164.70 to 165.70}
23.38
200000
100000
Time*
-T—I—!—1—i—i—r—I—r—r—I—I—r—i—I—i—1—i—r~i—I—i—i—r~r
23.20 23.30 23.40 23.50 23160
Time-->
Abundance Ion 188.00
Hon 94.00
200000
, , 1 , 1 , , r
25.60 2 5.70 25:80
#10
Fluorene
Concen: 2.74 ng/uL
RT: 23.38 min Scan# 1561
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
441655
Upper
Tgt Ion;166 Resp:
Ion Ratio Lower
100
89.4 38.3
0.0 0.0
0.0 0.0
114 .7
0.0
0.0
TIC: ENG1S59.D
300000
200000
100000
100000
0
(187.70 to 188.70): ENG
(93.70 to 94.70): ENG16
25.69
Tirae-->
ENGT61T97B PES3 .M
25.60 25.70 25.80
Mon uct 18 14:42:29 1999'
#11
Phenanthrene- dl 0
Concen: 2.53 ng/uL
RT: 25.69 min Scan# 1912
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:188 Resp: 497786
Ion Ratio Lower Upper
188
100
94
26.1
5.8
17 .2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
OCC 35
HP 5989B Page 7
-------
300000
200000
100000
TIC: £NG165§.D
Time-->
Abundance Ion 178
300000:
200000
100000
25.70 25.80
00 (177.70 to 178.10): ENG
Ion 176.00 (175.70 to 176.70): ENG
25.74
Time-
~25 170
25 1 80
#12
Phenanthrene
Concen: 2.66 ng/uL
RT: 25.74 min Scan# 1920
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:178 Resp: 653934
Ion Ratio Lower Upper
178 100
176 20.0 10.3 30.8
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: SNG1659.D
300000
200000
100000
n—i—i—i—i—i—i—t—!—r—i—i—i—i—| 11 r
Time--> 25160 25170 25.80 25190 26100
Abundance Ion 188.00 C187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
200000 .
100000
0
T—l 1—i—
25.60
Time-->
ENG1659.D—FEB1TW
25.82
-i—i—|—i—r
25180
"1—I—f—!—1—I—I—t—I 1—I—r-
25.90 26100
25 .70
Mon~UcE IB 14:42:J2 1999
#13
Anthracene-dlO
Concen: 2.35 ng/uL
RT: 25.82 min Scan# 1933
Delta R.T. -0.03 min
Lab Pile: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:188 Resp: 70455
Ion Ratio Lower Upper
188
100
94
27 .1
6.6
19.6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HP 5989B
0GC3556
Page 8
-------
^60866
"TIC: ENG165 9.D
300000
200000
100000
I 1 I II \ ! 1 1 1 T"
25180 25.90 26100
Time--> 25.70
Abundance Ion 178.00 (177.70 to 178.705; Sm
Ion 176.00 (175.70 to 176.70): ENG
300000
200000
100000
ime--> 25 170
25.87
-j 1 1 1 r~—i 1 ! i—m—r~
25180 25.90 26.00
#14
Anthracene
Concen: 3.88 ng/uL
RT: 25.87 rain Scan# 1940
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:178 Resp: 546534
Ion Ratio Lower Upper
178
100
176
19.4
8.9
26.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
400000
300000
200000
100000
TIC: ENG1659.D
Time-->28.40 28.60 28180
Abundance Ion 212.00 (211.70 to 212.70): ENG
lion 106.00 (105.70 to 106.70): ENG
28 .68
200000
100000
0
#15
Fluoranthene-dlO
Concen: 3.03 ng/uL
RT: 28.68 min Scan# 2371
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:212 Resp: 528426
Ion Ratio Lower Upper
212 100
106 28.0 8.0 23.8#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time-->28. 40
ENG1659,D FES3.M
28.60 28180
Mon Oct IB 14:42:35 1999'
HP 5989B
0CC3557
Page
-------
Abundance
400000
300000
200000
100000
¦? s ! \ j 1 r—n 1 1 1 r"
fTime--52S!40 28.60 28.80
my* ,—zTCO n
jL JL L. • mIHvji JL u 3 -7 • L#
#16
Fluoranthene(CCC)
Concen: 3.07 ng/uL
RT: 28.73 rain Scan# 2378
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:202 Resp: 712995
Ion Ratio Lower Upper
29 100
202
100
101
24.6
9.9
29.6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
28.73
300000
200000
100000
Time--;28 140 28l60 28 ! 80 29'. 00
Abundance
400000
300000
200000
100000
TIC: EMG1659.D
i ' i ' i r
#17
Pyrene-dlO
Concern 3,16 ng/uL
RT: 29.28 min Scan# 2461
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:212 Resp: 610431
Ion Ratio
212 100
106 31.2
Lower Upper
Time --> 29.00 29120 29140
Abundance Ion 212.00 (211.70 to 212.70): ENG
0
0
0.0
0.0
8.6
0.0
0.0
25 .6#
0.0
0.0
300000
200000
Ion 106.00 (105.70 to 106.70): ENG
29 .28
100000 .
~i 1 r—t 1 r—! i I i 1 1 s 1 r
fTime--> 29.00 29.20 29.40
ENGT6W7D PES3 .M
Mon uct 18 14:42:38 1999
HP 5989B
3558
Page 10
-------
Abundance
400000
300000
200000
100000
TIC: ENG165 9.D
0
Time --> 29.20 29.40 29.60
abundance Ion 202.00 (201.70 to 202.70): EMS
400000 -Jion 101.00
300000
(100.70 to 101.70)
29 .34
ENG
200000
100000
Time-
29 .20
#18
Pyrene
Concen: 3.05 ng/uL
RT: 29.34 min Scan# 2469
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion*.202 Resp: 788880
Ion Ratio Lower Upper
202
100
101
27 .5
14 .3
42.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
29.40
29.60
Abundance
400000
300000
200000
100000
TIC: ENG1659.D
0
Time - - >
29 .40
29.60 29.80
Abundance Ion 244.00 (243.70 to 244.70) : ENG
lion 122.00 (121.70 to 122.70): ENG
200000 29.62
150000
#19
p-Terphenyl-dl4
Concen: 1.27 ng/uL
RT: 29.62 min Scan# 2511
Delta R.T. -0.03 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:244 Resp: 455289
Ion Ratio Lower Upper
244 100
122 30.0 6.7 19.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
100000
50000
Time--> 29.40
ENGT63TTTD—FES3 .M
29.60 29.80
Man Oct 18 14:42:41 1999'
HP 5989B
3559
Page 11
-------
Abundance
TIC: ENG1659.D |
200000 :
I \
150000 :
/ \
100000:
A / \
50000 J
J \J ^
n
^
Time--> 33.20 33.30 33.40 33.50
Abundance Ion 240.00 (239.70 to 240.70): ENG
150000 -
Ion 120.00 {119.70 to 120.70): ENG
100000
33.36 / \
50000
U -
n "
Time--> 33.20 33.30 33.40 33.50
Abundance TtC: ENG1659.D
200000
150000
100000
50000
0 -i—,—i [ ¦ i—j—i—i—,—i—j • r -i—r—<—j—i—i—i—i—j—i—i—i—r-
Time--> 33.30 33.40 33.50 33.60
Abundance Ion 228.00 (227.70 to 228.70); ENG
200000 jIon H4.00 (113.70 to 114.70): ENG
33 .46
150000
100000
50000 J
Time--> 33.30
ENG1659.D—PES3.M
33140T
i—?¦ »f 't—|—j—i—>—r-
33:50 33.60
#20
Benzo(a) anthracene-dl2
Concen: 4.13 ng/uL
RT: 33.36 min Scan# 3073
Delta R.T. -0.04 min
Lab File: ENG1659.D
Acq; 15 Oct 99 1:04 am
Tgt Ion:240 Resp: 280945
Ion Ratio
240 100
120 29.6
Lower Upper
0
0
0.0
0.0
7.3
0.0
0.0
21.8#
0.0
0.0
#21
Benzo(a)anthracene
Concen: 4.17 ng/uL
RT: 33.46 min Scan# 3088
Delta R.T. -0.04 min
Lab Pile: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:228 Resp: 470835
Ion Ratio Lower Upper
228
100
114
25.1
12.8
38.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Mon Oct 18 I¥:42:44 1999
oecjSto
HP 5989B Page 12
-------
Abundance
200000
150000
100000
50000
0
Time - - ;33 .20
TIC: 1HG1659.D
33.40
t 1 1 1 r-
33.60
Abundance Ion 240.00 T2T9". 70 to 240.70): ENG
150000
100000
50000 -
Ion 120.00 (119.70 to 120.70) ENG
33.50
Time--^33
33.60
33 .40
#22
Chrysene-dl2
Concen: 3.61 ng/uL
RT: 33.50 rain Scan# 3094
Delta R.T. -0.04 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:240 Resp: 452669
Ion Ratio Lower Upper
240
100
120
27.0
6.4
19.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
TIC: ENG1659.D
Time-
150000
100000
50000
#23
Chrysene(CCC)
Concen: 3.63 ng/uL
RT: 33.61 min Scan# 3111
Delta R.T. -0.04 min
Lab File: ENG1659.D*
Acq.- 15 Oct 99 1:04 am
Tgt Ion:228 Resp: 607292
33.40
33 . 60
, j i
33.80
Ion
228
114
0
0
Ratio
100
22 .3
0.0
0.0
Lower Upper
9.1
0.0
0.0
27.1
0.0
0.0
Abundance Ion 2 2 8.00
200000
150000
100000
50000
Time - - >
227.70 to 228.70)
Ion 114.00 {113.70 to 114.70)
33.61
mr
ENG
"1— 1 1 1 1 1 \ t 1 1 1 1 r-
33.40 33.60 33.80
OCC35£i
ENG1659.D PES3.M
Mon Oct 18 14T42T471999
HP 5989B
Page 13
-------
[Abundance
200000
150000
100000
50000
"TIC: ENG1659.D
0
Time - - > 39120 39130 39150
Abundance Ion 264.00 {263.70 to 264.70): ENG
¦lion 132.00
60000
40000
20000
(131.70 to 132.70)
39.35
J-
Time-
1—r—|—i—¦; - f i—j—*—v f i—| -f t r- ] "i" r "i
39120 39.30 39140 39.50
ENG
#24
Benzo(b)fluoranthene-dl2
Concen: 3.95 ng/uL m
RT: 39.35 rain Scan# 3993
Delta R.T. -0.07 min
Lab File: SNG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:264 Resp: 300241
Ion Ratio Lower Upper
264
100
132
40.9
8.0
23.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
150000
100000 -I
50000
T—I—!—i—|—I—1—f—?—{—J—?—n—I—i—n—5—!—r*
fTime -->39130 39140 39.50 39.60 39170
TIC: ENG1659,D
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
100000 J 39.52
50000
0 _
-i—r
Time-->3 913 0
1 ¦' i 1 11
39.40
~ T'" ' -T ! J 1 ! 1 1
39.60 39.70
ENGTfc59 .D—PES 3 .M
39.50
Hif'iJrT—' jf-JlL" m rm m 'm - ¦ rf '-1111111 n" ¦ w w
Mon Oct 1814:42:bOl999
#25
Benzo(b)fluoranthene
Concent 4,19 ng/uL
RT: 39.52 min Scan# 4019
Delta R.T. -0.06 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:252 Resp: 480122
Ion Ratio Lower Upper
252
100
126
27 .1
13 .4
40.1
0
0 . 0
0.0
0.0
0
0.0
0.0
0.0
0CC35*°
HP 5989B
Page 14
-------
(Abundance
I 200000
150000
100000
50000
ENG1659.D
Time--^39 • 20 39.40
AbundanceIon 264.00 (263.70
39.60 39.80
to 264.70)
60000
40000
20000
Ion 132.00
(131.70 to 132.70)
39 .53
tt,ime--s39 - 20
39.40
39.60
39.80
Sundance
200000
150000
100000
50000
Time-->39.40
TIC: ENG15ET97D
#26
Benzo(k)fluoranthene-dl2
Concen: 4.50 ng/uL
RT: 39.53 min Scan# 4020
Delta R.T. -0.06 rain
Lab
File:
ENG1659.D
Acq:
15 Oct
99 1:04 am
Tgt
Ion:264
Resp: 334446
Ion
Ratio
Lower Upper
264
100
132
34 .1
8.5 25.3#
0
0.0
0.0 0.0
0
0.0
0.0 0.0
EMT
ENG
39.60 39.80
Abundancelon 252.00 (251.70 to 252.70): ENG
Jlon 126.00 (125.70 to 126.70): ENG
100000 .
50000
#27
Benzo(k)fluoranthene
Concen: 4.48 ng/uL
RT: 39.67 min Scan#' 4042
Delta R.T. -0.06 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:252 Resp: 374667
Ion Ratio
252 100
126 30.2
Lower Upper
0
0.0
0.0
13.0
0.0
0.0
38.8
0.0
0.0
Time-->39.40
39.60
39.80
0CC35t3
HP 5989B Page
-------
Abundance
60000
40000
20000 :
TIC: ENG1659.D
0
i—!—i—r—i—i—i—i—!—i—i—i—!—'—
41.40 41160 41.80
10000
"I f !
Time--> 41120 41140
41160
"i" \ 1 "i—r~
41180
#28
Benzo(a)pyrene-dl2
Concen: 4.25 ng/uL
RT: 41.61 rain Scan# 4339
Delta R.T. -0.08 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:264 Resp: 169936
Ion Ratio Lower Upper
Tints > 41.20
Abundance Ion 254.00 (263.70 to 254.70): SNG
lion 132.00 (131.70 to 132.70): ENG
41.61
30000
20000
264
100
132
34 .4
8.7
25.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
60000
TIC: 2NG1659.D
40000
20000
n—i—i—i—i—j—r
41.60
Time --> 41160 41.80 42100
Abundance Ion 252.00 (251.70 to 252.70) :
Ion 126.00 {125.70 to 126.70):
41.79
40000
T2HCT
ENG
20000
0
Time-
-i—i—>—r
41.60
T
ENGiF5'S~. D—PES3 .M
41.80 42.00
Mon Oct IB 14:42:56 1999'
#29
Benzo(a)pyrene(CCC)
Concen: 4.56 ng/uL
RT: 41.79 min Scan# 4367
Delta R.T. -0.08 min
Lab Pile: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:252 Resp: 248990
Ion
252
12 6
0
0
Ratio
100
28.4
0.0
0.0
Lower Upper
13 .4
0.0
0.0
HP 5989B
40.1
0.0
0.0
¦. $
Page 16
-------
(Abundance
60000
40000
20000
TIC: ENG1S59.D
Tittle--> 52.20 52 i 40 52 160
Abundance Ion 288.00 (287.70 to 288.70)
—|—,—
52180
20000
10000
52,54
fTime--> 52 ! 20
—|—p.
52 .40
52160
52.80
Abundance
TIC: ENG1659.D
60000
40000
20000
0
Time-
#30
Indeno(1,2,3-cd)pyrene-dl2
Coneen: 4.19 ng/uL m
RT: 52.54 min Scan# 6026
Delta R.T. -0.13 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:288 Resp: 186359
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#31
Indeno(1,2,3-cd)pyrene
Coneen: 4.66 ng/uL
RT: 52.82 min Scan# 6078
Delta R.T. -0.14 min
Lab Pile: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:276.05 Resp: 255763
Ion Ratio Lower Upper
52.50 53100
(AbundanceIon 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70): ENG
52 .82
276
100
138
41.4
22.8
68 .2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
30000
20000
10000 -
Time--> 52.50
ENGlfoby.D FE5T7M
53100
Mon Oct 18 14:42:59 1999'
HP 5989B
5~ !*"*
Page 17
-------
Abundance
60000
40000
20000
TIC: £NGl659.D
0
Time- -> 52:20 52 ! 4Q~ 52:60
Abundance Ion 292.00 (291.70 to 292.705 : ENG
52.51
15000
10000
5000 :
I 1—! 1 1 \ 1 S 1 [ f r
Time--> 52:20 52:40 52.60
#32
Dibenz(a,h)anthracene-dl4
Concent 4.48 ng/uL m
RT: 52.51 min Scan# 6020
Delta R.T. -0.12 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:292 Resp: 120334
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
TIC: ENG1659
,D
60000 -
40000 -
20000:
0 .
Time - - >
1 1 ' 1 • 1
52.50 53.
00
1 r
Abundance Ion
278.00 (277 .70 to
278.70);
EMG
30000 ^
Ion
139.00 (138.70 to
139.70):
ENG
52.85
20000
10000 -
0 „
!
Time-->
52.50 53.
00
ENGlfc59.D PES3.M
#33
Dibenz(a,h)anthracene
Concen: 4.89 ng/uL
RT: 52.85 min Scan# 6085
Delta R.T. -0.14 min
Lab Pile: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:278 Resp:
Ion
278
139
0
0
Ratio
100
30.2
0.0
0.0
Lower
13 .7
0.0
0.0
228310
Upper
41.0
0.0
0.0
at)
won Oct 18 14:43:02 1999
HP 5989B
* f1
m
Page 18
-------
TIC: ENG1659.D
30000
20000 -
10000
56.00
55.50
Time--> 55.00
Abundance Ion 288.00 (287.70 to 288.70): ENG
55 .52
20000
15000
10000 :
5000 J
55.50
56.00
#34
Benzo(g,h,i)perylene-dl2
Concen: 4.20 ng/uL
RT: 55.52 min Scan# 6593
Delta R.T. -0.14 min
Lab Pile: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion:288 Resp: 197707
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0 .0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1659.D
30000
20000
10000
Time
55 .50
56.00
#35
Benzo(g,h,i)perylene
Concen: 4.08 ng/uL
RT: 55.84 min Scan# 6672
Delta R.T. -0.15 min
Lab File: ENG1659.D
Acq: 15 Oct 99 1:04 am
Tgt Ion*.276 Resp: 251908
Ratio
100
36 .6
0.0
0.0
Lower Upper
15.9
0.0
0.0
Abundance Ion 276.00 (275.70 to 276.70): ENG
30000 -|lon 138.00 (137.70 to 138.70): ENG
55.84
20000
63 .4
0.0
0.0
10000
Time-->
ENG1659.D
i 1 j r
55 .50
PES3—M
0CC3567
56 .00
Mon^Oct 18 14:43:0b 1999
HP 5989B
s- I
Page 19
-------
Method
Title
Last Update
Response via
Response Factor Report HP 5989B
C:\HPCHEM\i\METHODS\PES2\M
Wed Oct 20 10:34:06 1999
Initial Calibration
Calibration Files
.25 =SNG1688.D .5 =ENG1689.D
1 =ENG1687.D 2 =«ENG169G.D 3 =ENG1691.D
Compound .25 .5 1 2 3 Avg %RSD
1)
2)
s
3)
4)
s
5)
s
6)
7)
s
8)
9)
s
10)
11)
s
12)
13)
s
14)
15)
s
16)
17)
s
18)
19)
s
20)
s
21)
22)
s
23)
24)
s
25)
26)
s
27)
28)
s
29)
30)
s
31)
32)
s
33)
34)
s
35)
2, 2-Difluorobiphenyl ISTD
Naphthalene-d8 1.942 1.941 1.712 1.444 1.350 1.678 16.38
Naphthalene(CCC) 2.192 1.824 1.668 1.428 1.393 1.701 19.19
2-Methlynaphthalene 0,920 0.922 0.765 0.747 0.736 0.818 11.57
Acenaphthylene-d8 0,800 0.935 1.102 0.955 1.134 0.985 13.74
Acenaphthylene 0.988 1.006 1.175 1.037 1.263 1.094 10.96
Acenaphthene-dl0 0.797 0.869 0.828 0.745 0.729 0.794 7.30
Acenaphthene(CCC) 0.889 0.830 0.821 0.737 0.743 0.804 7.99
Fluorene-dlO 0.899 0.971 0.946 0.835 0.816 0.894 7.56
Fluorene 1,030 0.948 0.955 0.847 0.855 0.927 8.24
Phenanthrene-dl0 1.232 1.372 1.283 1.133 1.113 1.226 8.73
Phenanthrene 1.476 1.334 1.369 1.224 1.237 1.328 7.77
Anthracene-dlO 0.757 0.757 *• 0.00
Anthracene 0.758 0.754 1.114 0.965 1.062 0.931 18.06
Fluoranthene-dlO 0.793 0.857 1,028 0.894 0,943 0.903 9.81
Fluoranthene(CCC) 1.035 1.001 1.172 1.017 1.157 1.077 7.57
Pyrene-dlO 0.769 0.850 1.051 0.941 1.008 0.924 12.43
Pyrene 1.087 1.000 1.238 1.069 1.165 1.112 8.26
p-Terpheny1-dl4 0.749 0.845 0.759 0.815 0.792 5.77
Benzo(a)anthracene- 0.218 0.228 0.408 0.313 0.392 0.312 28.51
Benzo(a)anthracene 0.371 0.347 0.546 0.453 0.581 0.460 22.45
Chrysene-dl2 0.378 0.419 0.578 0.502 0.588 0.493 18.98
Chrysene(CCC) 0.535 0.470 0.681 0.587 0.706 0.596 16.61
Benzo(b)fluoranthen 0.223 0.236 0.315 0.277 0.336 0.277 17.61
Benzo(b)fluoranthen 0.311 0.305 0.423 0.370 0.475 0.377 19.39
Benzo(k)fluoranthen 0.218 0.211 0.300 0.270 0.340 0.268 20.53
Benzo(k)fluoranthen 0.262 0.218 0.310 0.269 0.352 0.282 18 .12
Benzo(a)pyrene-dl2 0.110 0.114 0.150 0.127 0.160 0.132 16.75
Benzo(a)pyrene(CCC) 0.180 0.143 0.203 0.163 0.213 0.180 15 . 85
Indeno{1,2,3-cd)pyr 0.163 0.130 0.143 0.175 0.153 13.19
Indeno(1, 2,3 -cd)pyr 0.201 0.164 0.195 0.171 0.202 0.187 9.43
Dibenz(a,h)anthrace 0.104 0.081 0.088 0.105 0.095 12.63
Dibenz(a,h)anthrace 0.162 0.131 0.159 0.142 0.172 0.153 10.74
Benzo(g,h,i)perylen 0.146 0.138 0.161 0.147 0.161 0.151 6.80
Benzo(g,h,i)perylen 0.184 0.172 0.212 0.178 0.203 0.190 8.96
0CC3568
(#) = Out of Range /
PES3.M Wed Oct 20 10:37:50 1999 HP 5989B Page 1J'
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DATA\ENG1688.D
19 Oct 99 3:58 pm
CARB429,QA/QC,CCAL.2 5
Oct 20 10:31 1999
Vial: 3
Operator:
Inst ; HP 5989B
Multiplr: 1.00
Method : C:\HPCHEM\1\METH0DS\PES4.M
Title :
Last Update : Wed Oct 20 11:38:44 1999
Response via ; Multiple Level Calibration
Internal Standards R.T, Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.90
190
424924
5 .00
ng/uL
0.00
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
17.59
136
41263
0.19
ng/uL
4 .78%
4)
2-Methlynaphthalene-dlO
19,27
152
19536
0.25
ng/uL
6 .17%
5)
Acenaphthylene-d8
21.53
160
17005
0.22
ng/uL
5.45%
7)
Acenaphthene-dlO
21.94
164
16926
0.24
ng/uL
5.93%
9)
Fluorene-dlO
23.21
176
19103
0.26
ng/uL
6.44%
11)
Phenanthrene-dlO
25.58
188
26169
0 .25
ng/uL
6.31%
13)
Anthracene-dl0
25.72
188
1797
0.03
ng/uL
0.70%
15)
Fluoranthene-dl0
28.58
212
16858
0.19
ng/uL
4.80%
17)
Pyrene-dlO
29.17
212
16345
0.17
ng/uL
4.30%
19)
p-Terphenyl-dl4
29.51
244
18556
0.24
ng/uL
6.09%
20)
Benzo(a)anthracene-dl2
33 .20
240
4625
0.14
ng/uL
3.41%
22)
Chrysene-dl2
33 .33
240
8036
0.14
ng/uL
3.38%
24)
Benzo(b)fluoranthene-dl2
39.10
264
4733
0.13
ng/uL
3.33%
26)
Benzo(k)fluoranthene-dl2
39.26
264
4627
0.13
ng/uL
3.28%
28)
Benzo(a)pyrene-dl2
41.32
264
2330
0.12
ng/uL
3 .12%
30)
Indeno(1,2,3-cd)pyrene-dl2
52.09
288
3457
0.14
ng/uL
3.49%
32)
Dibenz(a,h)anthracene-dl4
52.04
292
2202
0.15
ng/uL
3.69%
34)
Benzo(g,h,i)perylene-dl2
55.02
288
3101
0 .14
ng/uL
3.60%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.64
128
46564
0 .20
ng/uL
100
6)
Acenaphthylene
21.56
152
20984
0.23
ng/uLm
65
8)
Acenaphthene(CCC)
22.02
154
18897
0.24
ng/uL
97
10)
Fluorene
23 .28
166
21888
0.26
ng/uL
100
12)
Phenanthrene
25.64
178
31357
0.25
ng/uL
99
14)
Anthracene
25.76
178
16113
0.21
ng/uL#
58
16)
Fluoranthene(CCC)
28.62
202
21997
0.19
ng/uL#
69
18)
Pyrene
29 .22
202
23090
0.19
ng/uL#
65
21)
Benzo(a)anthracene
33,29
228
7891
0.14
ng/uL#
71
23)
Chrysene(CCC)
33.44
228
11363
0.15
ng/uL#
73
25)
Benzo(b)fluoranthene
39.26
252
6602
0.12
ng/uL#
70
27)
Benzo(k)fluoranthene
39.39
252
5558
0.14
ng/uLm
0
29)
Benzo{a)pyrene(CCC)
41.50
252
3824
0.15
ng/uLm
0
31)
Indeno(1,2,3-cd)pyrene
52 .34
276
4267
0 .17
ng/uLm
0
33)
Dibenz(a, h)anthracene
52.42
278
3436
0.16
ng/uLm
0
35)
Benzo(g,h,i)perylene
55.32
276
3902
0.14
ng/uLm
0
0CC3569
(#) = qualifier out of range (m) » manual integration
ENG1688.D PES4.M Wed Oct 20 11:41:40 1999 HP 5989B Page 1
-------
Quantitation Report
C:\HPCHEM\l\DATA\ENGl6 8 8.D
19 Oct 99 3:58 pm
CARB429,QA/QC,CCAL.2 5
Data File
Acq On
Sample
Misc
Quant Time: Oct 20 10:31 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PSS4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Vial: 3
Operator;
Inst : HP 5989B
Multiplr: 1.00
TIC: ENG1638.D
Abundance
280000 :
260000 :
240000 ;
220000 J
160000 :
80000 :
8 10
14
4S
31S
20 . 00 25.00 30.00 35.00 40 . 00 45.00 50.00 55 . 00
0CC35?0
ENG1688.D PES4.M Wed Oct 20 11:41:49 1999 HP 5989B Page
-------
Abundance
30000.
20000
10000
TIC: SNG1688.D
Time-
17.59
20000
10000
0
Time-~>
\ J 1 1 ! r-
17.40
Abundance
30000 :
20000
10000
~t—i—i—|—i—i—i—!—j—%—i—r~
17150 17.60 17.70
TIC: ENG1688.D
#2
Naphthalene -d.8
Concen: 0.19 ng/uL
RT: 17.59 min Scan# 236
Delta R.T, -0.00 min
Lab File: SNG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:136 Resp: 41263
Ion Ratio Lower Upper
~t—t—|—*—i—\ i j—i—r-i—r—|—i—i—i—i—|—r—i—i—i—i—i—
17,40 17.50 17.60 17170
AbundanceIon 136.00 (135.70 to 136.70): ENG
\Ion 68.00 (67.70 to 68.70): ENG16
136
100
68
0.0
4.5
13 . 4#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time--> 17 150 ' 1716*0 ' 17170 17180
Jl ¦>—. 4^/1 FTK N —pj-w—tt"———m A'\ ffriT/T
Abundance Ion 128.00 (127.70 to 128.70); ENG
Ion 127.00 (126.70 to 127 .70) : ENG
17.64
20000 -
10000
#3
Naphthalene(CCC)
Concen: 0.20 ng/uL
RT: 17.64 rain Scan# 244
Delta R.T. 0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:128 Resp: 46564
Ion Ratio Lower Upper
128
100
127
12.5
0.0
62.6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
Time-->
17 .50
17.60^17170 17180
ENG1688:B FES¥7W~
Wed Oct 20 11:41:53 1999
HP 5989B Page 3
-------
(Abundance
i
10000
TIC: ENGlSSS.D
5000
-1 1 ! J 1' 1 1 ! 1 1 1 1 1 1 f 1 ! FT
Time--> 19:15 19.20 19.25 19.30 19.35
Abundance Ion 152.00 (151.70 to 152.70): ENG
$4
2-Methlynaphthalene-dlO
Concen: 0.25 ng/uL
RT: 19.27 min Scan# 766
Delta R.T. 0.00 rain
Lab Pile: 1NG1688.D
Acq; 19 Oct 99 3:58 pm
Tgt Ion:152 Resp: 19536
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0 . 0
0.0
0.0
0
0.0
0.0
0.0
19.27
10000
5000
—f—t—r~™r—'—|1 "i i—n—i—r—j—i—?—i—j "i t i—i—r~n—!—r t,m
fTime - - > 19.15 19.20 19.25 19.30 19.35
Abundance
15000 :
TIC; ENG1688.D
10000 -
5000
0
Time - -> 21.40 21.50 21.60
Abundanceion 160.00 (159.70 to 160.70)
HRJ
10000
5000
21.53
Time--> 21.40
1NG1688.D—PE54.M
#5
Acenaphthylene-d8
Concen: 0.22 ng/uL
RT: 21.53 rain Scan# 1260
Delta R.T. 0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:160 Resp: 17005
Ion Ratio Lower Upper
160
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
21.50 21.60
Wed Oct 20 11: 41; bfe 1999'
"9
4 At
HP 5989B
Page 4
-------
TIC: ENG1688.D
15000 _
10000 -
5000 -
Abundance Ion 152.00 (151.70 to 152.70): ENG
jloil 153.00 (152.70 to 153.70): ENG
21.56
10000 -
5000 .
Time --> 21.45 21.50 21.55 21.60 21.65
#6
Acenaphthylene
Concen: 0.23 ng/uL m
RT: 21.56 min Scan# 1265
Delta R.T. 0.01 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:152 Resp: 20984
Ion Ratio Lower Upper
152
100
153
28.9
7.4
22 .0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
20000
TIC: ENG1688.D
10000
0
21.94
10000
5000
0 .
Time-->21185 1 ' 21i 9 0
#7
Acenaphthene-dlO
Concen: 0.24 ng/uL
RT: 21.94 min Scan# 1321
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:164 Resp: 16926
Ion Ratio Lower Upper
Time-->21.80 21.90 22.00
Abundance Ion 164.00 (163 .70 to 164.70): ENG
164
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
¦~i 1 j i——r f r
22 .00
HP 5989B
Page 5
-------
Abundance
20000
10000
0
TIC: 6NG1688.D
Time--> 21.90
Abundance Ion 154.00
lion 153,00
10000 -
22.00 22.10
(153.70 to 154.70) :
(152.70 to 153 .70) :
22.02
5000
#8
Acenaphthene(CCC)
Concen: 0.24 ng/uL
RT: 22.02 miri Scan# 1333
Delta R.T. 0.01 min
Lab Pile: ENG1688.D
Acq: 19 Oct 99 3:58 pra
Tgt Ion:154 Resp: 18897
Ion Ratio Lower Upper
154
100
153
107.2
52 .3
156.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
"Erar
ENG
Time-
Abundance
21.90
22 .00
22 .10
TIG: SMG1688.D
20000
10000
Time - -> 23!l0_I" 23! 20 23 130
Abundance Ion 176.00 (175.70 to 176.70): ENG
#9
Fluorene-dlO
Concen: 0.26 ng/uL
RT: 23.21 min Scan# 1513
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:176 Resp: 19103
Ion Ratio Lower Upper
176 100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
23 .21
10000
5000
0
Time - ->
ENGTFSTSTB—PES4.M
"t ! 1 1 1 1 1 1 1 ! 1 1 t r
23 .10 23120 23.30
Wed Oct 20 11:42:02 1999
0CC3573
HP 5989B
Page 6
-------
Abundance
20000
~TTC: SNG168S.D
10000
0
Tims — — > 23.20 23.30 23.40
Abundance Ion lSS.00 (165.70 to 166.70)7"
#10
Fluorene
Concen: 0.26 ng/uL
RT: 23.28 min Scan# 1524
Delta R.T. 0.01 min
Lab File; ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:166 Resp: 21888
Ion Ratio Lower Upper
166 100
165 91.6 45.8 137.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
IMS"
15000
10000
5000
|Ion 165.00 (164.70 to 165.70): ENG
23.28
k
ime-
—I , r "i"1"
23 1 20
23 .30
-I 1 1 1 1 F"
23.40
Abundance
20000
TIC: ENG1688.D
10000
0
#11
Phenanthrene-dl0
Concen: 0.25 ng/uL
RT: 25.58 min Scan# 1873
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion;188 Resp:
26169
Ion Ratio Lower Upper
Time--> 25150 25160 25170
Abundance Ion 188.00 (187,70 to 188.70): ENG
188
100
94
0.0
5 .5
16 . 4#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Hon 94.00
15000
10000
5000
0
(93.70 to 94.70)
25.58
ENG 16
0CC35
j «-
1—i—i—|—i—i—i—i—|—i—i—i—i—j—i—
Time--> 25.50 25.60 25.70
ENGlfo88. D PES4 .M Wed Oct 20 11: 42 : 05 1999'
HP 5989B
Page 7
-------
Abundance
20000
TIC: EMG1688.D
10000
0
Time-
1 1 I ! '
25.55 25,60 25,65 25.70
[AbundanceIon 178.00 (177.70 to 178.70): IMG
Ion 176.00 (175.70 to 176.70): ENG
25 .64
20000
15000:
10000
5000
Time-->
Abundance
15000:
10000
5000
0
' ' I '
25.55
25.60
' ' I I 1 ' "T"T
25.65 25.70
TIC: ENGTF8T7D
Time- ->
Abundance Ion 188
#12
Phenanthrene
Concen: 0.25 ng/uL
RT: 25.64 min Scan# 1882
Delta R.T. 0.01 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:178 Resp: 31357
Ion Ratio Lower Upper
178
100
176
20.0
9.8
29.3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#13
Anthracene-dlO
Concen: 0.03 ng/uL m
RT: 25.72 min Scan# 1894
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:188 Resp: 1797
Ion Ratio Lower Upper
25.70 25.75
00 (187.70 to 188 .70) : ENG
188
100
94
82 .3
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.Q
0.0
3000
2000
1000
0
Ion 94.00
(93.70 to
25.72
94.70): ENG16
Time-->
ENG1688.D
PES4.M
25.70 25 .75
Wed Oct 20 11:42:08 1999'
HP 5989B
Page 8
-------
TIC: ENG1688.D
Abundance
20000
10000 -
Time-->
AbundanceIon 178.00 (177.76 to 178.70): BUG
Ion 176.00 (175.70 to 176.70): ENG
25 I 70
25 .80
15000 J
25.76
10000 :/
5000:
25 .70
Time-->
25.80
#14
Anthracene
Concen: 0.21 ng/uL
RT: 25.76 min Scan# 1901
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:178 Resp: 16113
Ion Ratio Lower Upper
178
100
176
0.0
9.5
28.4#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
20000 j
TIC: BnG1S88
.D
15000 :
ioooo :
5000:
O
Time--> 28140
i i i . . I i
28.50 28.60
i i i l i
28.70
( t
Abundance Ion
2l2
.00 (211.70 to
ENG
10000 .
Ion
106
.00 (105.70 to
28.58
106,70):
ENG
5000 .
IX
0 ..
Time--> 28 .40
28!50 28160
28.70
ENGT688.ET FE547W
#15
Fluoranthene-dlO
Concen: 0.19 ng/uL
RT: 28.58 min Scan# 2332
Delta R.T,
0.01 min
Lab
File:
ENG1688
,D
Acq:
19 Oct
99 3:
58 pm
Tgt
Ion:212
Resp:
16858
Ion
Ratio
Lower
Upper
212
100
106
0.0
6.4
19.1#
0
0.Q
0.0
0.0
0
0.0
0.0
0.0
OCC-3578
Wed Oct 2U 11:42:11 1999
HP 5989B
Page 9
-------
Abundance
20000
15000
10000:
5000
TIC: ENG1&88.D
0
Time-
, , , , , . , , , 1 j , j ( j ] 1 r
28.50 28.60 28.70 28.80
- — Klin ¦ JL II I »| ¦ II JL I»I ¦ rn ¦ ¦ t mm- ¦ ¦
Abundance Ion 202.00 (201.70 to 202 .70):
Ion 101.00 (100.70 to 101.70):
28 .62
10000
ENG
5000
0
Time - - >
~1 1 ! ! 1 1 S 1 1 j 1 i 1 1 ! 1 1 1 1 | T r
28.50 28.60 28.70 28.80
#16
Fluoranthene(CCC)
Concen: 0.19 ng/uL
RT: 28.62'min Scan# 2339
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:202
Ion Ratio
202 100
101 0.0
0 0.0
0 0.0
Resp: 21997
Lower Upper
6.0 17.9#
0.0 0.0
0.0 0.0
Abundance
20000
15000
10000
5000
TIC: 2NG1S88.D
Time-->29100 29110 2 9!20 29130
Abundance Ion 212.00 (211.70 to 212.70); ENG
10000
Ion 106.00 (105.70 to 106.70): ENG
29.17
5000
#17
Pyrene-dlO
Concen: 0.17 ng/uL
RT: 29.17 min Scan# 2420
Delta R.T. 0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pro
Tgt Ion:212 Resp: 16345
Ion Ratio Lower Upper
212
100
106
0.0
7.4
22.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC
Time- ->29.00
RNGIG 8 S ""D |y|
29.10 29120 29130
Wed 0ct 2{) i1:42;14 iy9y
HP 5989B
Page 10
-------
Abundance
TIC: ENG1688.D
20000 :
Am
15000 -
/ V
/ \_ y
ioooo :
5000:
o :
Time--> 29.00 29110 29.20 29.30 29140
Abundance Ion 202.00 (201.75 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
29.22
10000 -
A
5000 .
J ^
0 .
Time - - > 29 1 do' 29! 10 ' 2 9 I 2 0" 29 13*0* *29 14*0
#18
Pyrene
Concern 0.19 ng/uL
RT: 29.22 min Scan# 2428
Delta R.T. 0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:202 Resp: 23090
Ion Ratio Lower Upper
202
100
101
0.0
7.1
21.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1688.D
20000 :
/ \
15000 :
10000:
5000
0
Time-->
29.40
. 0
If)
" CN
29.60
1 i
Abundance Ion
244.00
541 7A Fn
\ im "X wl • / V W
244.70) :
WG
Ion
122.00
(121.70 to
122 .70) :
ENG
29 .51
10000 -
5000 -
0 -
Time-->
29 .40
¦ 1 1 1 1 ' ¦
29 .50
1 1 1 1
29160
' 1
#19
p-Terphenyl-dl4
Concen: 0.24 ng/uL
RT: 29.51 min Scan# 2471
Delta R.T. 0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:244 Resp: 18556
Ion Ratio Lower Upper
244
100
122
0.0
6.8
20.3#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HP 5989B
Page 11
-------
Abundance
TIC: ENG1688.D
10000 .
5000 -
0
Time-->
33
. 10 33 .15 33.20 33 .25 33.30
Abundance Ion
240.00 (239.70 to 240.70): ENG
Ion
120.00 (119.70 to 120.70): ENG
4000 -
33.20 /
2000 -
0
Time-->
S * 5
33
.10 33 .15 33.20 33.25 33 .30
#20
Benzo(a)anthracene-dl2
Ccncen: 0.14 ng/uL m
RT: 33.20 min Scan# 3025
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:240 Resp: 4625
Ion Ratio Lower Upper
240
100
120
95.7
6.0
17.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: lNGlb88.O
10000 -
5000
#21
Benzo(a)anthracene
Concen: 0.14 ng/uL
RT: 33.29 min Scan# 3039
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:228 Resp: 7891
Ion Ratio Lower Upper
33 .30 ^r 33 :40
Time--> 33.20
Abundance Ion 228.00 (227.70 to 228.70): ENG
6000 Jlon 114.00 (113.70 to 114.70): ENG
228
100
114
0.0
5.6
16.7#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
4000
2000
0
33 .29
0CC3579
Time--> 33.20 33.30 33.40
ENG1688 .D PES4.M Wed Oct JO 11: CZTOTTW?
HP 5989B
Page 12
-------
Abundance
TIC: EHG1688.D
10000 -
5000 -
0 -
Time - - >
i ! [ ( t i [ | ! s i j j ' f j ' i s i
33.20 33.30 33.40
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70) : ENG
33.33
4000 -
r/X-y\—
2000 -
0 .
Time - - >
"I r i i i % t i i i i i j ? i i 1 1 !' 1"
33 .20 33.30 33.40
#22
Chrysene-dl2
Concen: 0,14 ng/uL
RT: 33.33 min Scan# 3045
Delta R.T. -0.00 min
Lab File: 1NG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:240 Resp: 8036
Ion Ratio Lower Upper
240 100
120 0.0 6.1 18.2#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
10000 -
TIC: 2UG1688.D
5000
0
#23
Chrysene(CCC)
Concen: 0.15 ng/uL
RT: 33.44 min Scan# 3062
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:228 Resp: 11363
Ion Ratio Lower Upper
—i—i—5—3—p—r
Time--> 33120 33.30
1—i—|—i—r
33 .40
33.50 33 .60
Abundance Ion 228.00 (227.70 to 228.70):
228
100
114
0.0
5.1
15.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
nrr
6000
4000
2000
Ion 114.00 (113.70 to 114.70): ENG
33 .44
0C03560
Time--?
SNG168B.D
33
PES4.M
~"t I i V "| ' l—r
20 33.30
33
j 1—I 1 1—
.40 33
—i—j—j—r~~i—»—?—g t
50 33.60
Wed Oct 20 11:42:23 1999
HP 5989B
Page 13
-------
"mT/** i——rr
i 1L * JZjlMVjr 1DOO . U
10000
5000 .
39 .00
39.10
Time-->
Abundance Ion 264.00 (262.10 to 264.705: BUG
JIon 132 .00 (131.70 to 132.70) : ENG
3000:
2000
1000 .
39.00
39.10
39.20
Time-->
#24
Benzo(b)fluoranthene-dl2
Concen: 0.13 ng/uL m
RT; 39.10 rain Scan# 3932
Delta R.T. _ 0.00 min
Lab File: ' ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:264 Resp; 4733
Ion Ratio Lower Upper
264
100
132
104.8
6.6
19.6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance ^ TIC: ENG1688.D
10000 -
5000
0
time-->39110
39.20
39.30
39 .40
Abundance Ion 252.00 (251.70 to 252.70}
Ion 126.00 (125.70 to 126.70)
39.26
4000
IMS"
ENG
2000
#2,5
Benzo(b)fluoranthene
Concen: 0.12 ng/uL
RT: 39.26 min Scan# 3957
Delta R.T, 0.01 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:252 Resp: €602
Ion Ratio Lower Upper
252 100
126 0,0 5.9 17.5#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
oeosei
HP 5989B Page 14
-------
Abundance
TIC: ENGlb88.D
10000 -
5000
0
i | i » i i | » i i I j f i i i j « r'•••
Time--> 39,10 39.20 39.30 39.40
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
3000 :
2000 :
1000 .
0 -
Time~~>
39.10 39.20 39.30 39.40
#26
Benzo(k)fluoranthene-dl2
Coneen: 0.13 ng/uL m
RT: 39.26 rain Scan# 3957
Delta R.T, 0.00 min
Lab File: ING1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:264 Resp: 4627
Ion Ratio Lower Upper
264
100
132
109.5
6.8
20.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
10000
TIC: ENG1688.D
5000
0
#27
Bemzo(k)fluoranthene
Concen; 0.14 ng/uL m
RT: 39.39 min Scan# 3977
Delta R.T. -0.01 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:252 Resp: 5558
Ion Ratio Lower Upper
Time - - >3 9 . 20 39.30 39.40 39.50
Abundance Ton 252.00 (251.70 to 252.70): ENG
¦lion 126.00 (125.70 to 126.70): ENG
252
100
126
62 .3
6 .4
19.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
4000
39.39
2000
0
o39
1 T*
20
Time-
ENGlbBB.D—PKS4.M
1 1 T"
39 .30
~T~~—i j ! j r-
39.40 39 I 50
Wed Oct 20 IT!42;29 iy99
HP 5989B
Page 15
-------
Abundance
10000
TIC: ENG1688. D
5000
Time--s4lil0 41.20 ' 411 30 '41140* ' 41! 50 '
Abundance Ion 264.00 (263.70 to 264.70) : ENG
ilon 132.00 (131.70 to 132.70): ENG
i—i—i—r
3000
2000
1000
0
41.32
~i—i ! 1 1 r~
Time--^11.10 41.20 41.30 41.40 41.50
#28
Benzo(a)pyrene-dl2
Concen: 0.12 ng/uL m
RT: 41.32 min Scan# 4272
Delta R.T. 0.01 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion-.264 Resp: 2330
Ion Ratio Lower Upper
264
100
132
124.9
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
10000
TIC: ENG1688.D
5000
0
T
Time--> 41.30 41.40 41.50 41.60
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
4000J 41.50
3000
2000
1000
'—i—r—i—\—i—i—j—f—i—i—i—i—s—¦—i—r—r—t—r
Time--> 41.30 41.40 41.50 41.60
ENG168B.D—P1S4.M
#29
Benzo(a)pyrene(CCC)
Concen: 0.15 ng/uL m
RT: 41.50 min Scan# 4299
Delta R.T. -0.00 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:252 Resp: 3824
Ion Ratio Lower Upper
252
100
126
66.4
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Wed Oct 20 11:42:33 I¥¥9
0003583
HP 5989B Page 16
-------
Abundance
TTC7 EMG1688.D
10000
5000
Time--> SlTTsO
Abundance Ion 288.00 (287.70 to 288.70}: ENG
52.00
52 .20
2000
1000
52.09
0
Time - - > 51.80
52100
52.20
abundance
10000
5000
TIC: ENG1688.D
0
—,—| i \—e f—r—i—r
52100 52.20
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0.14 ng/uL m
RT: 52.09 min Scan# 5962
Delta R.T. 0.02 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion-.288 Resp: 3457
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.17 ng/uL m
RT: 52.34 min Scan# 6009
Delta R.T. 0.00 min
Lab Pile: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:276.05 Reap;
4267
! J ! ! 1 1 1 ! 1 S T
52.40 52.60
Time-->
Abundance Ion 276.05 (275.75 to 276.75): ENG
3000 lion 138.00 (137.70 to 138.70): ENG
52.34
Ion
276
138
0
0
Ratio
100
88 . 2
0.0
0.0
Lower Upper
0.1
0.0
0.0
0.1#
0.0
0.0
2000
1000
Time-->
ENG16 88.D
52.00
"FESITM"
~i—1—i—1—t—1—1—[—t—1—r
52,20 52.40 52.60
Wed Oct 20 11:42:36 1999'
0CC35e4
HI? 5989B
Page 17
-------
(Abundance
TIC: ENG1688.D
10000
5000
0
Time --> ' 51180 52 iOO 52120
5T" 3 V A A A A H"""? H tk 4 *1 A i. IT" —A A PI WtiJa
Abundance Ion 292.00 (291.70 to 292.70}: ENG
2000
1000
0
52 .04
Time-->
—i—i—r-
51.80
—I * , 1 ( 1 r 1 1 r
52 . 00 52.20
jAbundance
TIC: ENG1688.D
10000
5000
Time--> 52120 52140 52160
I—war*—wwiainui ¦ « « pwMywwwwwwwww pgwjMWflMS—
Abundancelon 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
52 .42
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.15 ng/uL m
RT: 52.04 min Scan# 5952
Delta R.T, 0.01 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:292 Resp: 2202
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#33
Dibenz(a, h)anthracene
Concen: 0.16 ng/uL m
RT: 52.42 min Scan# 6023
Delta R.T. 0.03 min
2000
1000
Lab
File:
ENG1688
.D
Acq:
19 Oct
99 3 :
58 pm
Tgt
Ion:278
Resp:
3436
Ion
Ratio
Lower
Upper
278
100
139
88.7
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time-->
ENG1&88.D
52 .20
PES4.M
52T40 52!60
Wed Oct 20 11:42:39 1999'
0CG3565
HP 5989B Page 18
-------
Abundance
6000
4000
2000
"TIC: ENG15SS.D
Time - - > ' 54! 80 55^00
Abundance Ion 288.00 (287.70 to 288,70)
-I—1—I—f~
55 .20
2000
1000
0
55.02
Time-->
~i 1 1 1 \—
54.80
—i | r—t-
55.00
—1 ! 1 r"
55.20
Abundance
6000
4000
2000
TIC: ENG1688.D
1 1 { f 1) 1 r t t r - r—i 1 " r "i r I
Time--> 55.00 55120 55140 55.60
Abundc
#34
Benzo(g,h,i)perylene-dl2
Coneen: 0.14 ng/uL m
RT: 55.02 min Scan# 6567
Delta R.T. 0.03 min
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt Ion:288 Resp: 3101
Ion Ratio Lower Upper
238 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
eIon 276.00 (275.70 to 275.70): ENG
Ion 138.00 (137.70 to 138.70):
55.32
2000
1000
#35
Benzo(g,h# i)perylene
Concen: 0.14 ng/uL m
RT: 55.32 min Scan# 6640
Delta R.T. -0.01 rain
Lab File: ENG1688.D
Acq: 19 Oct 99 3:58 pm
Tgt!Ion:276 Resp: 3902
Ion Ratio Lower Upper
276
100
138
88.5
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
Time--> 55.00
ENGi fc 8 8.D—PES4.M
—t 1 i r r—! 1 ! 1 1 1 1 r—
55.20 55.40 55.60
Wed Oct 20 11:42:42 1999'
0CC35;
HP 5989B Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHSM\l\DATA\ENG1689.D
19 Oct 99 5:04 pm
CARB429,QA/QC,CCAL.5,
Oct 20 10:33 1999
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Method
Title
Last Update
Response via
C:\HPCHEM\1\M1TH0DS\PES4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19,90
190
504769
5.00 ng/uL
0.00
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
17.59
136
97957
0 .47 ng/uL
11.78%
4)
2-Methlynaphthalene-dlO
19.27
152
46540
0.52 ng/uL
13.03%
5)
Acenaphthylene-d8
21.53
160
47217
0.50 ng/uL
12.55%
7)
Acenaphthene-dlO
21.94
164
43858
0.54 ng/uL
13 .46%
9}
Fluorene-dlQ
23.21
176
49014
0.56 ng/uL
14.11%
11)
Phenanthrene-dl0
25.58
188
69236
0.57 ng/uL
14.28%
13)
Anthracene-dlO
25 .72
188.
3374
0.04 ng/uL
1.10%
15)
Fluoranthene-dlO
28.58
212
43260
0.43 ng/uL
10.86%
17)
Pyrene-dlO
29.18
212
42896
0.40 ng/uL
10 .07%
19)
p-Terphenyl-dl4
29.51
244
37789
0.42 ng/uL
10.45%
20)
Benzo(a)anthracene-dl2
33 .20
240
11511
0.30 ng/uL
7 .41%
22)
Chrysene-dl2
33 .33
240
21157
0.33 ng/uL
8.13%
24)
Benzo(b)fluoranthene-dl2
39.09
264
11916
0.30 ng/uL
7.61%
26)
Benzo(k)fluoranthene-dl2
39.27
264
10631
0.27 ng/uL
6.71%
28)
Benzo(a)pyrene-dl2
41.31
264
5736
0.29 ng/uL
7.20%
30)
Indeno{1,2,3-cd)pyrene-dl2
52 .06
288
6567
0.22 ng/uL
5.57%
32)
Dibenz(a, h)anthracene-dl4
52.03
292
4083
0.23 ng/uL
5.76%
34)
Benzo(g,h,i)perylene-dl2
55.01
288
6957
0.29 ng/uL
7 .33%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17 .64
128
92063
0.41 ng/uL
99
6)
Acenaphthylene
21.56
152
50774
0.46 ng/uLm
84
8)
Acenaphthene(CCC)
22 .02
154
41872
0.49 ng/uL
99
10)
Fluorene
23 .28
166
47861
0.50 ng/uL
99
12)
Phenanthrene
25.64
178
67356
0.48 ng/uL
100
14)
Anthracene
25.76
178
38037
0.40 ng/uL
98
16)
Fluoranthene(CCC)
28.62
202
50539
0.41 ng/uL
97
18)
Pyrene
29.22
202
50466
0.38 ng/uL
99
21)
Benzo(a)anthracene
33 .29
228
17523
0.29 ng/uL#
71
23)
Chrysene(CCC)
33 .44
228
23724
0.29 ng/uL#
73
25)
Benzo(b)fluoranthene
39.26
252
15407
0.27 ng/uL#
70
27)
Benzo(k)fluoranthene
39.40
252
11003
0.26 ng/uL#
68
29)
Benzo(a)pyrene(CCC)
41.50
252
7214
0.25 ng/uL#
100
31)
Indeno(1,2,3-cd)pyrene
52.35
276
8301
0.29 ng/uLm
0
33)
Dibenz(a,h)anthracene
52.38
278
6619
0.27 ng/uLm
0
35)
Benzo (g,h, Dperylene
55.34
276
8683
0.29 ng/uLm
0
(#) = qualifier out of range (m) = manual integration
ENG1689.D PES4.M Wed Oct 20 11:43:18 1999 HP 5989B
.O.CC35a7..
Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DATA\ENG1689.D
19 Oct 99 5:04 pm
CARB42 9,QA/QC,CCAL.5,
Method
Title
Last Update
Response via
Oct 20 10:33 1999
: C:\HPCHEM\l\METHODS\PES4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Vial
Operator
Ins t
Multiplr
HP 5989B
1.00
Abundance
350000
TIC: ENG1689.D
300000 -
250000 .
200000 -
150000 -
100000 -
50000 -
4s
331
i;is
335
20.00 25.00 30.00 35.00 40100 45.00 50.00 55100
0CC3563
ENG16 8 9.D PES4.M
Wed Oct 20 11:43:26 1999
HP 5989B
Page 2
-------
Abundance
60000
40000
TIC: EMG1689.D
20000
0
-1 1 1 T"
[Time--317 .40
17.50
17.60
17 . 70
PSEuodancelon 136.00 (135.70 to 135.70): ENG
Ion 68.00 {67.70 to 68.70): ENG16
17.59
40000
20000
m 1 1 1 ! 1 1 1 1 1 1 1 1 1 j e 1 r
frime--sl7140 17.50 17.60 17.70
#2
Naphthalene-d8
Concen: 0.47 ng/uL
ET: 17.59 .min Scan# 236
Delta R.T. -0.00 min
Lab Pile: ENG1689.D
Acq: 19 Oct 99 5:04 pra
Tgt Ion:136 Resp: 97957
Ion Ratio Lower Upper
136
100
68
9.5
4.5
13.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
60000
40000
TIC: ENG1689.D
20000
#3
Naphthalene(CCC)
Concen: 0.41 ng/uL
RT: 17.64 min Scan# 244
Delta R.T. 0.01 min
Lab File : ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:128 Resp: 92063
Ion Ratio Lower Upper
Time--> 17.50 17.60 17.70 17
AbundanceIon 128.00 (127.70 to 128.70):
lion 127 .00
(126.70 to 127.70)
17 .64
80
ENG
128
100
127
12.8
0.0
62.6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
40000 -
20000
i i r~
T-—r
Time--> 17! 50
ENG16B9.D PES4.M
—, —r— r i—~j p-—r—t—- s—j j 1
17.60 17.70 17.80
Wed Oct 20 11:43:30 1999'
0003563
HP 59891 Page 3
-------
TIC: ENG1689.D
20000
10000
Time-->
"i f 1 r~
19:20
t 1 1 r
19130
Abundance Ion 152.00 (151.70 to 152.70); 1NG
30000
19.27
20000
10000
0
Time-
n 1 1 r
19.20
n 1 r
19.30
Abundance
30000
20000
10000
Time - - >
-T 5 ! 1 1 1 1 S J ! 1 ! 1 j 1 1 * E I ! 1 T*
21.45 21.50 21.55 21.60
Abundance Ion 160.00 (159.70 to 160.70): ENG
^ 30000h
21.53
20000
10000
Time-
I 7 X 1-
21.45 21.50 21.55 21.60
2-Methlynaphthalene-dl0
Concen: 0.52 ng/uL
ET: 19.27 min Scan# 766
Delta R.T, 0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:152 Resp: 46540
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1689.D
#5
Acenaphthylene-d8
Concen: 0.50 ng/uL m
RT: 21.53 min Scan# 1260
Delta R.T. -0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:160 Resp: 47217
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENGT689 ,'D—PES4TM
Wed Oct 20 11:43:33 1999
HP 5989B
Page 4
-------
Abundance
TIC: ENG1689.D
30000 -
f\
20000:
/ \
10000 _
J v.
o.
Time-->
21.
45 21.50 21.55 21.60 21.
65
Abundance Ion
152.00 (151.70 to 152.70)
: EMG
30000 ^
Ion
153.00 (152.70 to 153.70)
: ENG
21.56
20000 -
A
10000 -
0 _
Time-->
! 1
21.
45 21.50 21.55 21.60 21.
65
#6
Acenaphthylene
Coneen: 0.46 ng/uL m
RT: 21.56 min Scan# 1265
Delta R.T. 0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:152 Resp: 50774
Ion Ratio Lower Upper
152
100
153
20 .0
7.4
22 .0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1S89.D
40000 -
20000
Time
21.80
21.90
22100
22 .10
#7
Ac enapii t hene ~ dl 0
Concen: 0.54 ng/uL
RT: 21.94 min Scan# 1321
Delta R.T. -0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:164 Resp: 43858
Ion Ratio Lower Upper
100
0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 164.0 0 (163.70 to 164.70) : ENG
20000
10000
21.94
Time-
21.80
21.90
22.00
22 .10
ENGlfeay .D PES4 .M
Wed OCt 20 11:43:36 1999
0CG35
HP 5989B
Page 5
-------
TIC: ENG1689.D
40000
20000
Time--> 21.90
22.00
"T 1 r r-
22.10
(AbundanceIon 154.00 {153.10 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
22 ,02
20000
10000
Time-
21.90
22.00
22.10
#8
Aeenaphttiene (CCC)
Concen: 0.49 ng/uL
RT: 22.02 min Scan# 1333
Delta R.T. 0.01 min
Lab Pile: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:154 Resp: 41872
Ion Ratio Lower Upper
154
100
153
105.4
52 .3
156 .8
0
0.0
0 .0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1689.D
40000 -
\
20000.
N1
0 .
Time-->
• i ! | * i < » i i i i > | i i i i
23 .10 2 3 120 23 .30
Abundance Ion 176.00 (175.70 to 176,70): ENG
30000 :
23.21
20000
A
10000
J V
0 -
Time-->
i * > i ' > * • j i ) t i ! i * f
23110 23.20 23.30
#9
Fluorene-dlO
Concen: 0.56 ng/uL
RT: 23.21 min Scan# 1513
Delta R.T. -0.00 min
Lab Pile: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:176 Resp: 49014
Ion Ratio Lower Upper
176
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0003§mq
HP 5989B
Page 6
-------
TIC: ENG1689.D
40000
20000 -
Time - ¦
23.10
-i—i—i—i—i—!—-i—I' • r" '"I—r^T—i—~i—i—n—r
23.20 23.30 23.40
AbnnrianrP Ton 155 00 Tl55 70 to 155 701 • BUS"
rUJ Ulill rl llu Q x Uii X W y t V W \ JLm W nmf * * V W W X V W < f V / « £li'l\7
lion 165.00 (164.70 to 165.70): ENG
23.28
30000
20000 .
10000
0
i—i—\—\—r—!—r—i—i—j—i—!—i—f—|—t—i—T'1 i
'Time - - > 23:i0 23.20 23130 23.40
#10
Fluorene
Concen: 0.50 ng/uL
ET: 23.28 min Scan# 1524
Delta R.T. 0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:166 Resp: 47861
Ion Ratio Lower Upper
166 100
165 92.2 45.8 137.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
TIC: ENG1689.D
40000 -
A A
20000 -
/ IJ
0 -
Time-->25
140 25.50 25160 25.70
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG 16
40000:
25.58
30000 :
A
20000
/1
10000 -
0 -
Time-->25.40 25150 25160 25170
#11
Phenanthrene-dlO
Concen*. 0 . 57 ng/uL
RT: 25.58 min Scan# 1874
Delta R.T. 0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:188 Resp: 69236
Ion Ratio Lower Upper
188
100
94
10 .8
5.5
16 .4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC3533
Wed Oct 20 11:43:43 1999
HP 5989B
Page 7
-------
Abundance
40000
20000 -
TIC: ENG1689.D
0
Time - - >
"3—I—I » 111'[—r
25,55 25.60 25,65 25.70 25.75
Abundancelon 178.00 (177.70 to 178.70); 2NG
40000.
30000
20000
10000
Ion 176.00 (175.70 to 176.70): ENG
25.64
0
Time-->
1—i—I—i—i—r—!—i—r—i—i—r—j—:—t—i—j—i—t—i—i—i—t—i—t
25.55 25.60 25.65 25.70 25.75
#12
Phenanthrene
Conceii: 0.48 ng/uL
RT: 25.64 min Scan# 1883
Delta R.T. 0.01 min
Lab Pile: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion*.178 Resp: 67356
Ion Ratio Lower Upper
178
100
176
19.6
9.8
29.3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
30000
20000
TIC: ENG1689.D
#13
Anthracene-dlO
Concen: 0.04 ng/uL m
RT: 25.72 min Scan# 1895
Delta R.T. 0.00 min
10000
"i—i—r—r—i—i—r—i—r—i—i—r—i—r—i—i—i—r~~|—i 1 i "i—f—r—r~T~
Time--> 25.68 25.70 25.72 25.74 25 .76
Abundance Ion 188.00 (187.70 to 188.70): ENG
4000
3000
2000
1000
Ion 94.00 (93.70 to 94.70): ENG16
25.72
Time--> 25.68
ENG1689.B FE5ITM
t—i—[—r—i—r~i—j i !—i—i—r f¦ "i—i—V'"]—r—r
25.70 25.72 25.74 25.76
Lab
File:
ENG1689.D
Acq:
19 Oct
99 5 : 04 pm
Tgt
Ion:188
Resp*. 3374
Ion
Ratio
Lower Upper
188
100
94
64 .4
0.1 0.1#
0
0.0
0.0 0.0
0
0.0
0.0 0.0
oce
^ A.
Wed Oct 20 II:4J :4b 1999
HP 5989B
Page 8
-------
Abundance
TIC: ING1S89.D
40000 .
\ A
20000 .
0
Time--> 25!60 ' 25I70 ' 25!80 ' ' 25i90
Abundance Ion 178.00 (177.70 to 178.70) : 2NG
40000
Ion 176.00 (175.70 to 176.70): ENG
30000
A
/ \ 25.76
20000
/ \ A
10000
0 .
1 I 1 1 1 i 1 i i t » | s | |
Time--> 25.60 25,70 25.80 25.90
#14
Anthracene
Concen: 0.40 ng/uL
RT: 25,76 min Scan# 1902
Delta R.T. 0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:178 Resp: 38037
Ion Ratio Lower Upper
178 100
176 19.7 9.5 28.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
30000
20000 J
10000
0
Time-->
TIC: ENG1689.D
n—i—i—|—i—!—i—i—|—j—j—j—j—|—f—i—i—r
28.40 28.50 28.60 28.70
#15
Fluoranthene-dlO
Concen: 0.43 ng/uL
RT: 28.58 min Scan# 2333
Delta R.T. 0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:212 Reap: 43260
Ion Ratio Lower Upper
100
12.3 6.4 19.1
0.0 0.0 0.0
0.0 . 0.0 0,0
[AbundanceIon 212.00 (211.70 to 212.70)
Ion 106.00 (105.70 to 106.70)
28.58
20000 4
10000
ENG
ENS
Time - - >
I !—"1 1 1-
28.40
28.50
I 1 ] 1 T"
28.60
28.70
ENG1689.D—PES4.M
Wed Oct 20 11:43:49 199?
HP 5989B
Page 9
-------
Abundance
30000
20000
10000
0
Time - - >
TIC: BUG16M.D
28 .40
28.60
28,80
Abundance Ton 202.00 (201.70 to 202.70): ENCT
Ion 101.00 (100.70 to 101.70); ENG
28.62
20000
10000
Time-
28! 40
28160
28.80
#16
Fluoranthene(CCC)
Coneen: 0.41 ng/uL
RT: 28.62 min Scan# 2340
Delta R.T. 0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:202 Resp: 50539
Ion Ratio Lower Upper
202
100
101
10.8
6.0
17.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
30000
20000
10000
TIC: ENG16 8 9 . D
#17
Pyrene-dlO
Concen: 0.40 ng/uL
RT: 29.18 min Scan# 2422
Delta R.T. 0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:212 Resp;
29:00^29:10
Time - - >
Abundance Ion 212.00
^I on 106.00
20000 -
10000
1—1—j—!—r
29.20
29:30
(211.70 to 212.70):
(105.70 to 106.70)
29.18
ENG
Time - ->
ENG1689.D
1 1 1 f f 1 1 1 1—
29.00 29.10
PES4. M
—1 j , j 1 1 j , 1 , r p
29.20 29.30
Wed Oct 20 11:43:52 1999'
42896
Ion Ratio Lower Upper
212
100
106
13 .8
7.4
22.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HP 5989B
vQ
Page 10
-------
TIC: ENG1&897D
Abundance
30000
20000
10000
Time--> 29:00 29:io' 29120 29140
#18
Pyrene
Concen: 0.38 ng/uL
RT: 29.22 min Scan# 2429
Delta R.T, 0,00 min
Lab File: ENG1689.D
Acq; 19 Oct 99 5:04 pm
Tgt Ion:202 Resp: 50466
Ion Ratio Lower Upper
202 100
101 13.7 7,1 21.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
29.22
20000
10000
0
Time*
¦> 29:00
? ! 1 ! 1 ! ? I 1 ! 1 1 1 ill! 1 1—1 r
29.10 29.20 29.30 29.40
Abundance
30000 :
20000
10000
Time-
TTCTTnKm^89TD
'—1—r
29130
1—1—1—r~
29:40 29:50 29:60
1 1 1 r ')' 1
29 ! 70
#19
p-Terphenyl-dl4
Concen: 0.42 ng/uL
RT: 29.51 min Scan# 2472
Delta R.T. 0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:244 Resp: 37789
Ion Ratio Lower Upper
244 100
122 13.6 6.8 20.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
20000 "I 29.51
15000
10000
5000
T—|—1—i-"i—1—]—1—1—r—1—|—f—r
Time--> 29.30 29.40 29.50
29:60
1—!—I—t—!—r
29.70
ENGT689.D PES4.M
0CC35S7
Wed Oct 2U ll:4i:b5 1999
HP 59891
Page 11
-------
TIC: ENG1689.D
Abundance
15000 .
10000
5000
33,20
33.30
Time-->
Abundance Ion 240.00 (23$.70 to 240.70): EMG
10000Jjon 120 .00. {119.70 to 120.70) ; ENG
33.10
33 .20
5000 -
33 110
33 .20
33 .30
#20
Benzo(a)anthracene-dl2
Concen: 0.30 ng/uL
RT: 33.20 min Scan# 3026
Delta R.T. -0.00 min
Lab File: ENG1689.D
Acq*. 19 Oct 99 5:04 pm
Tgt Ion:240 Resp: 11511
Ion Ratio Lower Upper
240
100
120
0.0
6.0
17.9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1689.D
15000:
/ \ /\
ioooo :
5000:
0 -
Time-->
1 1 1 1 1 » 4 1 1 t * * 1 1 j I i 1
33.20 33.30 33.40
AbundanceIon 228.00 {227.70 to 228.70): ENG
10000 .
Ion 114.00 {113.70 to 114.70): ENG
33.29 / \
5000 .
0 .
Time-->
33.20 33.30 33.40
#21
Benzo(a)anthracene
Concen: 0.29 ng/uL
RT: 33.29 min Scan# 3040
Delta R.T, -0.00 min
Lab File: ENG1689.D
Acq; 19 Oct 99 5:04 pm
Tgt Ion:228 Resp: 17523
Ion Ratio Lower Upper
228
100
114
0.0
5.6
16.7#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CCK,:
HP 5989B
Page 12
-------
Abundance
15Q00
10000 :
5000
TIC; 2NG1689.D
i 1 1 1—i—i—]—r
33.20 33,30
,—r—p
33 .40
Time-->
HB-IMMaHHa_lMavanHIIMa_IMrtMMIH|VnHpIViBMMMMMMTVS-«--nlVaVIHHIlaMaMaMVaVlVllaaWaVl1
Abundaneelon 240.00 (239.70 to 240.70]
"EKT
10000
5000
0
Ion 120.00 (119.70 to 120.705; ENG
33 .33
Time-->
33 .20
TIC: ENG1689.D
#22
Chrysene-dl2
Concen; 0.33 ng/uL
RT: 33.33 min Scan# 3046
Delta R.T. -0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:240 Resp: 21157
Ion Ratio Lower Upper
240 100
120 0.0 6.1 18.2#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
15000 :
10000
5000
J 1 1 j , f , , j . , , , j . p-
rime--> 33.30 33.40 33.50 33.60
Abundance Ion 228.00 (227,70 to 228.70): ENG
10000
Ion 114
(113.70 to 114.70)
33 .44
ENG
5000
Time--> 33130
ENG1S89.D—PES4.M
#23
Chrysene(CCC)
Concen: 0.29 ng/uL
RT: 33.44 min Scan# 3063
Delta R.T. -0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:228 Resp: 23724
Ion Ratio Lower Upper
228
100
114
0.0
5.1
15 .2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
"i r-
33 .40
1—i—i—i—i—i—i—i—i—[ i
33.50 33.60
Wed Oct 20 11:44:01 1999
0003539
HP 5989B Page 13
-------
Abundance
15000
TIC: ENG1689.D
10000
5000
0
Time--> 38190 39!00 ' ' 39 110 ' 39 ! 20
Abundance Ion 264.00 (263.70 to 264.70}
Ion 132.00 (131.70 to 132.70)
39.09
4000 '
2000
0
1 ! 1 1 1 r ( 1 5 5 r { J ? ? 1 { f \ r
Time--> 38.90 39.00 39.10 39.20
#24
Benzo(b)fluoranthene-dl2
Coneen: 0.3 0 ng/uL
RT; 39.09 rain Scan# 3931
Delta R.T. -o.oi min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:264 Reap:
Ion Ratio Lower
11916
Upper
264
100
132
0.0
6.6
19.6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
H5~
ENG
Abundance
Tic: 1NG1689.D
15000 -
10000 :
5000 .
0 -
Time - - >
? "| 1 1 1 ? 1 i » i 1 1 1 f 1 t I ' t
39.10 39.20 39.30 39.40
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
39.26
6000 .
4000 :
.
2000:
0 -
Time-->
1 1 < 1 I 1 1 1 ' t 1 1 f i 1 t I 1 1
39.10 39.20 39.30 39 .40
#25
Benzo(b)fluoranthene
Concen: 0.27 ng/uL
RT: 39.26 min Scan# 3956
Lab
File:
ENG1689
.D
Acq;
19 Oct
99 5:
04 pm
Tgt
Ion:252
Resp:
15407
Ion
Ratio
Lower
Upper
252
100
126
0.0
5.9
17.5#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
BNG1689ID PES4.M
00C3S00
Wed Oct 20 11:44:05 1999
HP 5989B
Page 14
-------
Abundance
15000 _
10000
5000
1—t—i—i—i—I—i—i—i—r
fTime--> 39.10 39.20
TIC: ENG1689.D
39.30
39.40
- - ————— ¦! mm ¦ ¦ »"¦' m m—mm- . -m m -|—
AbundanceIon 264.00 (263.70 to 264.70]
Ion 132.00 (131.70 to 132.70]
39.27
4000 .
2000
0
w
ENG
[Time-
—!—I ! ! 1 * 1 5 1 J 1 1 !
39.10 39.20 39.30
*1 1 J IT
39.40
Abundance
15000
10000
5000
0
TIC: SMG1689.D
Time- -s39 :20 ' 39!30 39140 39150
AbundanceIon 252.00 (251.70 to 252.70): ENG
lion 126.00 (125.70 to 126.70): ENG
#26
Benzo(k)fluoranthene-dl2
Concen: 0.27 ng/uL
RT: 39.27 rain Scan# 3958
Delta R.T. 0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:264 Resp:
Ion Ratio Lower
100
0.0 6.8
0.0 0.0
0,0 0.0
10631
Upper
20.2#
0.0
0.0
6000:
4000
2000
Time-->39.20
BNG16B9.D—PES4.M
39.40
39.30
\ I
39140
1—1—I—r
39.50
#27
Benzo(k)fluoranthene
Concen: 0.26 ng/uL
RT: 39.40 min Scan# 3978
Delta R.T. -0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:252 Reap: 11003
Ion
252
126
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
6.4
0.0
0.0
19.0#
0.0
0.0
Wed Oct 20 11:44:08 1999
OCC0SC1
HP 59891 Page 15
-------
iAbundahce
10000
TIC: KWG1689.D
5000
0
Time--> 41.20
Abundance Ion 264.00
41.40
(263.70 to 264.70)
i i linl
(131.70 to 132.70}
3000
Abundance
10000
TIC: SNG1689.D
5000
0
Time-->
Abundance Ion 252.00
jlon 126.00
4000 -
2000
2000
1000
41.20
41.40
#28
Benzo(a)pyrene-dl2
Concen: 0.29 ng/uL
RT: 41,31 min Scan# 4270
Delta R.T. -0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:264 Resp: 5736
Ion Ratio Lower Upper
264
100
132
0.0
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#29
Benzo(a)pyrene CCCC)
Concen: 0.25 ng/uL
RT: 41.50 min Scan# 4299
Delta R.T. 0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:252 Resp: 7214
Ion Ratio Lower Upper
T—I—I—j—I—J—I—!—I !—I—1—I—J !—1 !—1—I' I ! 1 1' j—r—1—r
41.30 41.40 41.50 41.60 41.70
(251.70 to 252.70): ENG
(125.70 to 126.70): ENG
41.50
252
100
126
0.0
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time--> 41.30
ENG16B9.D—PES4.M
i ! ! i i i j i r
41.60 41.70
0CC36i'2
41.40 41.50
Wed Oct 20 11:44:11 T59$
HP 5989B
Page 16
-------
Abundance
TIC: ENG1689TET
10000
5000
Time-
-I 1 1 1—
51.80
52 .00
—i r—r—
52120
Abundance Ion 288.00 (28?.70 to 288.70!
3000
2000
1000
52 .06
Time-
l I 1 ! 1 l 1 (
51.80 52.00
1 1 1 ! 1 r
52 .20
abundance
TIC: ENG1S89.D
10000
5000
Time-->
52.00 52.20
, j ^ 1—
52.40
' 1 1 1~
52.60
[AbundanceIon 276.05 (275.75 to 276.75): ENG
Ion 138.00 (137.70 to 138.70); 1NG
3000 J 52.35
2000
1000
0
Time-->
ENG1689.D "
1—i—|—j—i—r—1—1—i—
52 .00 52.20
~1—1 1
52 .60
#30
Indeno(1(2,3-cd)pyrene-dl2
Concen: 0.22 ng/uL
RT: 52.06 ttiin Scan# 5956
Delta R.T. -0.02 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pra
Tgt Ion:288 Resp: 6567
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#31
Indeno(1,2,3-cd)pyxene
Concen: 0.29 ng/uL m
RT: 52.35 min Scan# 6010
Delta R.T. 0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:276.05 Resp: 8301
Ion Ratio Lower Upper
276
138
0
0
100
78.2
0.0
0.0
0.1
0.0
0.0
0.1#
0.0
0.0
PES4.M
52 .40
Wed Oct 20 11:44:14 1999'
0CC3SC3
HP 5989B
Page 17
-------
Abundance
TIC: ENGl68"9TD"
10000
5000
0
Time - ->
—t j ! ?—"T" i 1 1 1 s r—| r v
51.80 52.00 52.20
Abundance Ion 292.00 (291.70 to 292.70]
300*
52.03
2000
~mr
1000
0 -
Time-
"1 J 1 j 1 1 ! 1 ! ! 1 ! 1 1 1—
51.80 52.00 52.20
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.23 ng/uL m
RT: 52.03 min Scan# 5950
Delta R.T. -0.01 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:292 Resp: 4083
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
10000
TIC: ENG1689.D
5000
0
T
Time - - ^2.00 52:20 52140 52160
Abundance Ion 278.00 (277.70 to 278.70): ENG
Jlon 139.00 (138.70 to 139.70): ENG
3000 J 52 .38
2000
1000
0
#33
Dibenz(a,h)anthracene
Concen: 0.27 ng/uL m
RT: 52.38 min Scan# 6017
Delta R.T. 0.00 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:278 Resp;
6619
Ion
278
139
0
0
Ratio
100
80 .6
0.0
0.0
Lower Upper
0.1
0.0
0.0
0.1#
0.0
0.0
oecjgc-i
Time--252.00
52.20
_1
52 140
-i 1 1 1 1 1 r
52 .60
ENGT689 .D—FE54TM
Wed Oct 20 11:44:17 1999
HP 5989B
Page 18
-------
Abundance
TIC: 2MG1689
,D
6000 .
4000 .
2000 -
0 J
Time-->54
f 1
.60
i i i 11 1 1 l 1 j S J J
54.80 55.00
55 ,20
Abundance Ion
288.00 (287.70 to
288.70): ENG
3000 -
55 .01
2000 -
1000 -
0 -
fTime-->54
I , ,
i 60
54.80 55.00
55 :20 1
Abundance
6000
4000
2000
0
TIC: 1HG1689.D
#34'
Benzo(g,h,i) perylene-dl2
Concen: 0.29 ng/uL m
RT; 55.01 min Scan# 6564
Delta R.T. 0.02 min
Lab File: ENG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:288 Resp: 6957
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time--> 55.00 55.20 55.40 55.60
Abundance Ion 276.00 (275.70 to 276.70): ENG
Ion 138 . 00 (137 . 70 to 138.70) : ENG
3000 55.34
2000
1000
0
Time--> 55.00
ENGTSF9TB PES4 . M
1 1 1 J—
55-20
i—t—|—i—i—!—r
55 1 60
#35
Benzo(g,h,i)perylene
Concen: 0.29 ng/uL m
RT: 55.34 min Scan# 6644
Delta R.T. 0.00 min
Lab File: SNG1689.D
Acq: 19 Oct 99 5:04 pm
Tgt Ion:276 Resp:
Ion
276
138
0
0
Ratio
100
77.5
0.0
0.0
Lower
0.1
0.0
0.0
8683
Upper
0.1#
0.0
0.0
¦j't'
55 .40
Wed Oct 20 11:44:21 1999'
HP 5989B
Page
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
Method
Title
Last Update
Response via
C:\HPCHEM\1\DATA\ENG1687.D
19 Oct 99 2:54 pm
CARB429,QA/QC,CCAL1.0,
Oct 20 10:28 1999
C:\HPCHEM\1\METHODS\PES4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
Internal Standards
l) 2,2-Difluorobiphenyl
R.T. Qlon Response
19.90 190 490120
Cone Units Dev(Min)
5.00 ng/uL 0.00
System Monitoring Compounds
2) Naphthalene-d8 17.58 136 167824 0.63
4) 2-Methlynaphthalene-dl0 19.26 152 74954 0.80
5) Acenaphthylene-d8 21.53 160 108010 1.26
7) Acenaphthene-dlO 21.94 164 81187 1.00
9) Fluorene-dlO 23.21 176 92770 l.n
11) Phenanthrene-dlO 25.58 188 125759 1.07
13) Anthracene-dlO 25.72 188 74233 1.32
15) Fluoranthene-dlO 28.57 212 100763 0.98
17) Pyrene-dlO 29.17 212 102986 0.91
19) p-Terphenyl-dl4 29.51 244 82810 0.92
20) Benzo(a)anthracene-dl2 33.20 240 40021 0.99
22) Chrysene-dl2 33.34 240 56682 0.78
24) Benzo(b)fluoranthene-dl2 39.10 264 30909 0.70
26) Benzo(k)fluoranthene-dl2 39.27 264 29419 0 .67
28) Benzo(a)pyrene-dl2 41.32 264 14711 0.63
30) Indeno(1,2,3-cd)pyrene-dl2 0.00 288 0 0.00
32) Dibenz(a,h)anthracene-dl4 0.00 292 0 0.00
34) Benzo(g,h,i)perylene-dl2 55.01 288 15768 0.58
tRecovery
ng/uL 15.82%
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
ng/uL
19.99%
31.46%
24.91%
27.80%
26.76%
32.90%
24.54%
22.76%
22.92%
24.70%
19.51%
17.62%
16.83%
15.86%
0.00%
0.00%
14.48%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.63
128
163547
0.55
ng/uL
100
6)
Acenaphthylene
21.55
152
115217
1.10
ng/uLm
89
8)
Acenaphthene(CCC)
22.02
154
80522
0.89
ng/uL
100
10)
Fluorene
23.27
166
93565
0.98
ng/uL
100
12)
Phenanthrene
25 .63
178
134220
0.93
ng/uL
100
14)
Anthracene
25.76
178
109156
1.24
ng/uL
100
16)
Fluoranthene(CCC)
28.62
202
114912
0.85
ng/uL
96
18)
Pyrene
29 .22
202
121350
0.81
ng/uL
97
21)
Benzo(a)anthracene
33.29
228
53478
0.80
ng/uL
97
23)
Chrysene(CCC)
33 .44
228
66788
0.70
ng/uL
98
25)
Benzo(b)fluoranthene
39.25
252
41455
0.62
ng/uL
96
27)
Benzo(k)fluoranthene
39.40
252
30419
0.63
ng/uL#
68
29)
Benzo(a)pyrene(CCC)
41.49
252
19863
0.62
ng/uL#
100
31)
Indeno(1,2,3-cd)pyrene
52 .35
276
19122
0.59
ng/uLm
100
33)
Dibenz(a, h)anthracene
52 .39
278
15615
0.57
ng/uL#
100
35)
Benzo (g,h, Dperylene
55.33
276
20775
0.59
ng/uL#
100
0CCDSC6
(#) a qualifier out of range (m) » manual integration
•ENG1687.D PES4.M Wed Oct 20 11:40:09 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File ;
Acq On :
Sample :
Misc ;
Quant Time:
C:\HPCHEM\l\DATA\ENG1687.D
19 Oct 99 2:54 pm
CARB429,QA/QC,CCAL1.0,
Oct 20 10:28 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES4. M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Vial: 2
Operator:
Inst : HP 5989B
Multiplr: 1,00
Abundance
TIC: ENG1687.D
300000
250000
200000
150000 ,
100000
50000
Time-->
"T"- ;—i—i—r—i—r—i—i—j—s—i—j—i—i—i—i—i—i—I—r—i—r—p—r—n—r—»—r
00 25100 30.00 35.00 40.00 45.00 50.00
OCCjgC'7
ENG1687.D PES4.M Wed Oct 20 11:40:17 1999 HP 5989B
Page 2
-------
Abundance
100000 H
TIC: ENG1687 .D
50000
Time- - > 17.40
17 .50
17.60
17.70
Abundance Ion 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG16
17 .58
50000
1 I ? F I 1-] 1 1 1 1 E 1 1 1 1 1 1
[Time--> 17.40 17.50 17.60 17.70
#2
Naphthalene-d8
Concen: 0.63 ng/uL
RT: 17.58 min Scan# 235
Delta R.T. -0.01 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:136 Resp: 167824
Ion Ratio Lower Upper
136 100
68 10.0 4.5 13.4
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
100000
50000
Time- - >
m
TIC: ENGlb 87.D
#3
Naphthalene(CCC)
Concen: 0.55 ng/uL
RT: 17.63 min Scan# 243
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:128 Resp: 163547
! * 1 1 r
17 '40 17160
17 180
Ratio
100
12.7
0.0
0.0
Lower Upper
0.0
0.0
0.0
62.6
0.0
0.0
Ion 129.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70): ENG
17.63
50000
0
Time--> 17.40
»*T/^lT'2rn"T—r\ •ntycy"^ tot—
mJN\7 JL D O / a la# i> JCillkd <¦ *
17.60 17.80
Wed Oct 20 11:40:20 1999'
0CC3SC3
HP 5969B Page 3
-------
Abu:
TIC: ENGl68r.fi
30000
20000
10000
0
Time--> 19.20 19.30 19.40
Abundance Ion 152.00 (lSl. 70 to 152 .70) : ENG
40000
30000
20000
10000
0
19.26
[Time-
19.20
19 .30
19.40
20000
Time-->
AbundanceIon 160.00
60000
40000
1—r—I—i—i 1—i—*—i—I—t—i—i r
21.40 21.50 21.60 21.70
20000 J
0
i 1 1 1 ! I p r 1 1 1 1 1 1 1 1 1 1 1 1—
Time--> 21.40 21.50 21,60 21.70
ENGT6¥T7D PES1TM
$4
2-Me thlynaphthalene-dl0
Cone en: 0.80 ng/'uL
RT: 19.26 min Scan# 765
Delta R.T. -0.00 min
Lab File; ENG1687.D
Acq; 19 Oct 99 2:54 pm
Tgt Ion:152 Resp:
Ion Ratio Lower
74954
Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG1687.D
60000 -
40000
#5
Acenaphthylene-d8
Concern 1.26 ng/uL
RT: 21.53 min Scan# 1260
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion;160 Resp: 108010
Ion Ratio Lower Upper
100
0.0 0.0 0.0
0.0 0.0 0.0
0.0 0.0 0.0
[159.70 to 160.70): ENG
21.53
!Jean3c^~2TrTTT¥Tn^ZX~IFW
00C3SC9
HP 5989B Page 4
-------
toundance
60000:
40000
20000
TIC: ENG1687.D
^ -1—I—I—i—n—i—|—i—i—i—i—|—i—r—\—!—|—i—r ....
Time--> 21.45 21150 21,55 21.60
Abundance Ion 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
60000
40000
20000
21.55
Time--> 21.45 21.50 21.55 21.60
Abundance
80000
60000
40000
TIC: ENG1687.D
20000
#6
Acenaphthylene
Concen: 1.10 ng/uL m
RT: 21.55 min Scan# 1264
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion: 152 Resp :
Ion Ratio Lower
152 100
153 15.9 7.4
0 0.0 0.0
0 0.0 0.0
115217
Upper
22 .0
0.0
0.0
#7
Ac enapht h.ene - d 10
Concen: 1.00 ng/uL
RT: 21.94 min Scan# 1321
Delta R.T. -0.00 min
Lab File: SNG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:164 Resp:
81187
Ion
164
0
0
0
Ratio
100
0.0
0.0
0.0
Lower Upper
0.0
0.0
0.0
0.0
0.0
0.0
Abundance Ion 164.00 (1&3.70 to 164.70}
21.94
40000 -
20000
~EM3~
0
Time-
21180
21.90
22 .00
ENG1687.D PES4.M
Wed OCt 20 11:40:26 1999
0CC 3510
HP 5989B Page 5
-------
Abundance
80000
60000
40000
20000
Time--> 21190
Abundance Ion 154.00
lion 153.00
40000 -
20000 -
TIC: ENG1687.D
0
22.00 22110
(153.70 to 154.70)
(152.70 to 153.70)
22.02
~mr
ENG
#8
Acenaphthene(CCC)
Concen: 0.89 ng/uL
RT: 22.02 min Scan# 1333
Delta R.T. 0.01 min
Lab
File:
ENG1687
.D
Acq:
19 Oct
99 2:
54 pm
Tgt
Ion:154
Resp:
80522
Ion
Ratio
Lower
Upper
154
100
153
104.9
52 .3
156.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time-->
_i 1 r-
21190
22 .00
22.10
TIC: 2NG1687.D
80000
60000
40000
20000
Time-->
AEu
-f 1 ! 1 1 1 1 r
23110 23.20 23130
elon 176.00 (175.70 to 175.70): ENG
23.21
40000
20000
0
Time--> 23.10
ENG16H7.D PKS4.M
#9
Fluorene-dlO
Concen: 1.11 ng/uL
RT: 23.21 min Scan# 1513
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:176 Resp: 92770
Ion Ratio Lower Upper
100
0.0 0.0 0.0
0.0 0.0 0.0
0.0 0.0 0.0
23 .20 23.30
Wed Oct 20 11:40:28 1999'
OCCjSI
HP 5989B
Page 6
-------
Abundance
80000
60000
40000
20000
#10
Fluorene
Concert*. 0.98 ng/uL
RT; 23.27 rain Scan# 1523
Delta R.T. -0.00 rain
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:166 Resp; 93565
Ion Ratio Lower Upper
Time--> 23.20 23.30 23140
Abundance Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (164.70 to 165.70): ENG
23.27
40000
20000
0
Time-
—l—¦"
23 .20
23 .30
n 1 1 j r*
23:40
166
100
165
91.4
45.8
137.3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
80000
60000
40000
20000
Time--> 25:50 25.60 25:70
Abundance Ion 188.00 (187.70 to 188.70): EMG
Ion 94.00 {93.70 to 94.70): ENG16
25.58
TIC: ENG1637.D
#11
Phenanthrene-dlO
Concen: 1.07 ng/uL
RT: 25.58 min Scan# 1874
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:188 Resp: 125759
Ion Ratio Lower Upper
188 100
94
12.1
5.5
16.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
60000
40000
20000
0
Time - ->
ENG1687.D—PES4.M
25 I 50
25.60 25.70
wea uct 2U ii:4U:3i lyy^
HP 5989B
Page 7
-------
Abundance
80000
Time
Abundance Ion 173.00 (177.70 to 175.70): ENG
TIC: ENG1687.D
60000
40000
20000
25155 25! 60 25165 25170
80000 -lion 176.00
60000
(175.70 to 176.70!
25.63
ENG
40000
20000
Time - ->
r—1—r—1—1—i—1 ¦ *1 r j i—t—1—1—j—!—1—1—i—I—i—i—r~1—; 1
25.55 25.60 25.65 25.70
#12
Phenanthrene
Coneen: 0.93 ng/uL
RT: 25.63 min Scan# 1882
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:178 Resp: 134220
Ion Ratio Lower Upper
178
100
176
19.5
9.8
29.3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
80000
60000 h
40000
20000
TIC: SNG1687.D
60000
40000 :
20000
25 .72
Time — >
ENG1687.D—P1S4.M
#13
Anthracene-dlO
Concen: 1.32 ng/uL
RT: 25.72 min Scan# 1895
Delta R.T. 0.00 min
Time --> 25,60 25.80
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
Lab
Pile;
ENG1687.D
Acq:
19 Oct
99 2:54 pm
Tgt
Ion:188
Resp: 74233
Ion
Ratio
Lower Upper
188
100
94
13 .8
0.1 0.1#
0
0.0
0.0 0.0
0
0.0
0.0 0.0
25160 25180
Wed Oct 20 11:40:34 iy99
HP 5989B
Page 8
-------
TIC: ENG1S87.D
80000 J
60000 -
40000:
20000 -
25170
Time--> 25.60
Sundance Ion 178.00 (177.70 to 178.70): ENG
80000J Ion 176.00 (175.70 to 176.70): ENG
25.80
25.90
25.76
60000:
40000 :
20000
Time--> 25.60
25.70
25180
25190
#14
Anthracene
Concen: 1.24 ng/uL
RT: 25.76 min Scan# 1902
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:178 Resp: 109156
Ion Ratio Lower Upper
178
100
176
18 .7
9.5
28.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
60000
40000
20000
Time-
TIC: ENG1687.D
#15
Pluoranthene- dl 0
Concen: 0.98 ng/uL
RT: 28.57 min Scan# 2332
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:212 Resp: 100763
"i—| i—i—r—s r—i—t—r—i—r ¦•¦t
28.40 28.50 28! 60
T 1 1 f T"
28.70
[abundanceIon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
28.57
40000
20000
Time-
! ' «
28.40 28.50 28.60 28.70
ENG1S87.D—PES4.M
Ratio
100
14.6
0.0
0.0
Lower Upper
6.4
0.0
0.0
19.1
0.0
0.0
Wed Oct 20 11:40:37 1999
0CC3514
HP 5989B Page 9
-------
Abundance
60000
40000
20000
0
Titne-
TIC: ENG1687.D
28 .40
28.60
T !
28 .80
Abundance Ion 202.00 (201.70 to 202.70): INS
lion 101.00 (100.70 to 101.70); ENG
60000 - 28.62
40000
20000
Time--> 28.40
28.60
28.80
Abundance
60000
40000
20000 J
i—!—i i |—i—i—i i ?—?—i—i i | !—i—i—r~
29:00 29.10 29:20 29.30
Time-->
Abundance Ion 212.00 (211.70 to 212.70)
Ion 106.00 {105.70 to 106.70)
29.17
40000
#16
Fluoranthene(CCC)
Concen: 0.85 ng/uL
RT; 28.62 min Scan# 2340
Delta R.T. 0.00 min
Lab File; ENG1687.D
Acq: 19 Oct 99 2;54 pm
Tgt Ion:202 Resp:
Ion Ratio Lower
202 100
101 13.5 6.0
0 0.0 0.0
0 0.0 0.0
114912
Upper
17.9
0.0
0.0
.—ENG 1,6 § 7—13
#17
Pyrene-cSlO
Concen: 0.91 ng/uL
RT: 29.17 min Scan# 2421
Delta R.T. -0.00 min
Lab Pile: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion;212 Resp; 102986
Ion Ratio Lower Upper
212
100
106
17.3
7.4
22 .0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
isHcr
ENG
20000
0
Time-->
ENG16S7.D PES4.M
—? ]—1 !—I J [—I—I—I f J i i I i 1 f I I—r
29.00 29.10 29.20 29:30
wea uct 20 ii;40:3'y iyy?
0C03S15
HP 5989B Page 10
-------
Abundance
60000
TIC: ENG1687.D
40000
20000
0
Time--> 29.00 29.20 29.40
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 <100.70 to 101.70): ENG
29.22
60000
40000
20000
Time--> 29.00
29 20
29.40
#18
Pyrene
Coneen: 0.81 ng/uL
RT: 29.22 ruin Scan# 2429
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:202 Resp: 121350
Ion Ratio Lower Upper
202 100
101 15.5 7.1 21.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
60000
40000 '
TIC: ENG16 8 7.D
20000
n—i—?—r
n—i—i—r-
-j—!—i—r
Time-
29.30 29.40 29.50 29.60 29.70
{AbundanceIon 244.00 (243.70 to 244.70): SNG
Ion 122.00 (121.70 to 122 . 70) : ENG
29 .51
40000
20000 -j
#19
p-Terphenyl-dl4
Concen: 0.92 ng/uL
RT: 29.51 min Scan# 2472
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:244 Reap:
Ion Ratio Lower
244 100
122
0
0
14 .9
0.0
0.0
6.8
0.0
0.0
82810
Upper
20.3
0.0
0.0
0
n—!—r—i—i—f—e—r~~i—i—j—|—i i i i 1 | f i 1 i—i t [—r-
Time--> 29.30 29.40 29.50 29.60 29.70
ENG16B7.D—PES4.M Med Oct 20 11:40:42 1999'
00C3S16
HP 5989B Page 11
-------
Abundance
TIC: ENG1687
.D
1
300*0 0 -
\
20000 -
10000 -
0 J
Time-->
33.10 33.20
1 i '
33.30
Abundance Ion
240.00 (239.70 to
240
.70) :
2MG
20000 -
Ion
120.00 (119.70 to
120
.70) :
ENG
15000
33 .20
10000
5000
0 .
Time-->
33.10 33.20
1 i '
33 130
#20
Benzo(a) anthracene-dl2
Concen: 0.99 ng/uL
RT; 33.20 min Scan# 3026
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:240 Resp; 40021
Ion Ratio Lower Upper
240
100
120
13 .8
6.0
17 .9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1687
.D
30000 -
20000 J
10000 -
0.
Time-->
33
I » 1 1 1 ; 1 I 1 1 1 1 <
.10 33.20 33,30
33 140 33
o
in
Abundance Ion
228.00 (227.70 to
228.705 :
ENG
Ion
114.00 (113.70 to
114.70) :
ENG
20000 -
33 .29
10000 .
A
0 .
—
Time-->
33
.10 33.20 33.30
i | i t t i
33.40 33
¦| i
.50
#21
Benzo(a)anthracene
Concen- 0.80 ng/uL
RT: 33.29 min Scan# 3040
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
ENG1687JD—PES4.M
Tgt Ion:228 Resp:
Ion Ratio Lower
228 100
114 12.1 5.6
0 0.0 0.0
0 0.0 0.0
occ
53478
Upper
16 .7
0.0
0.0
Wed Oct 20 11:40:151999
HP 5989B
SI 7
Page 12
-------
Abundance
30000 -
20000
10000
TIC: ENG1687.D
i—r
33 110
33120 33130 33 140" '33 150
Time-'
Abundancelon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
20000 -
15000
10000
5000
33 .34
ci
'[ ; | 1 1 1 1 1 1 1 ! 1 \ 1 1 1 1 !—\ 1 f—r—T 1 T
ime--» 33110 33120 33.30 33140 33150
Abundance
30000
20000
10000
TIC: ENG1687.D
Time--> 33.20
Abundance Ion 228,00
Ion 114.00
20000
#22
Chrysene-dl2
Concen: 0.78 ng/uL
RT: 33.34 min Scan# 3047
Delta R.T. 0.01 tuin
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:240 Resp: 56682
Ion Ratio Lower Upper
240
100
120
13 .1
6.1
18 .2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#23
Chrysene(CCC)
Concen: 0.70 ng/uL
RT: 33.44 min Scan# 3063
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:228 Resp: 66788
Ion Ratio Lower Upper
33140 33160
(227.70 to 228.70): ENG
228
100
114
11.0
5.1
15.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
(113.70 to 114.70)
33 .44
ENG
10000 .
0
Time--> 33 120
ENG16 8 7.D PES4.M
33140 33!60
Wed Oct 20 11:40:48 1999'
0CC3S13
HP 5989B Page 13
-------
Abundance
TIC: ENG1687
.D
20000 .
10000 -
/
0 _
Time--^38
.90 '
39
i i . i i ¦ | i .
.00 39.10
i 1 , i i t 1
39.20
Abundance Ion
264 .
00 (263.70 to
254,70): ENG"'
Ion
132.
00 (131.70 to
132 .70) : ENG
39.10
5000 .
/ \
0
/
Time--=38
.90
39
.00 39.10
39.20
#24
Benzo(b)fluoranthene-dl2
Concen: 0.70 ng/uL
RT: 39.10 min Scan# 3933
Delta R.T. 0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:264 Resp: 30909
Ion Ratio Lower Upper
264
100
132
0.0
6.6
19.6#
0
0.0
0.0
0.0
0
0.0
0,0
0.0
Abundance
TIC: ENG1687.D
20000 -
A
10000 .
0
Time-->
1 1 1 1 1 5 1 | J t t 1 1 i 1 I 1 j t ' i
39.10 39.20 39.30 39.40
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126,70): ENG
39 .25
10000 .
A ~
5000 .
y_Av
0
Time-->
39.10 * * 39120 ' ' 39!30 * ' 39!40 '
#25
Benzo(b)fluoranthene
Concen: 0.62 ng/uL
RT: 39.25 min Scan# 3956
Delta R.T. -0.00 min
Lab File: ING1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:252 Resp: 41455
Ion Ratio Lower Upper
252
100
126
13 .1
5.9
17,5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CC35I9
HP 5 98 9B
Page 14
-------
Abundance
TIC: SNGiea?
.D
20000 -
10000 .
0 *
Time--> 39!00 39 ! 20
39 .40
J i
Abundance Ion 1264.00 (263.70 to
264.70):
ENG
Ion 132.00 (131.70 to
132.70):
ENG
39.27
5000 .
0 .
1
Time--> 39.00 39.20
39.40
#26
Benzo (k) f luoranthene-dl2
Concen: 0.67 ng/uL
RT; 39.27 min Scan# 3958
Delta R. T. 0,00 min
Lab
File:
ENG1687
.D
Acq:
19 Oct
99 2:
54 pm
Tgt
Ion:264
Resp:
29419
Ion
Ratio
Lower
Upper
264
100
132
0.0
6.8
20.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
20000
TIC: ENG1687.D
10000
#27
Benzo(k)fluoranthene
Concen: 0,63 ng/uL
RT: 39.40 min Scan# 3979
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:252
Ion Ratio
Resp:
Lower
30419
Upper
-I—I ""l" l ""| |
Time --> 39,20 39130 39,40
Abundance Ion 252
10000
5000
0
mr
Ion 126 .00
39.50
»HPJ HTM1 i_ _ I* ¦ m W A 1
(251„7 0 tO 252 , 70)
(125.70 to 126.70)
39.40
' ' | 1 1
39.60
MS"
ENG
252
100
126
0.0
6.4
19.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0CG3S20
Time-->
ENG16 87.D PE5¥7W
—i—r—r—i—i—i—f—i—'—i—i—|—r—T—i—i—r—\—i—i—i—\—i—r
39.20 39.30 39.40 39.50 39.60
Wed QCt 2TT 11:40:54 1999
HP 5989B
Page 15
-------
jAbundance
TIC; ENG1687.D
10000
5000 -
2000
Time-
41.20
41,40
#28
Benzo(a)pyrene-dl2
Concen: 0.63 ng/uL
RT: 41.32 rain Scan# 4273
Delta R.T. 0.01 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pra
Tgt Ion:264 Resp:
Ion Ratio Lower
14711
Upper
n
V ^ , j 1 , 1 1 1 1 , j , i J "i j 1
Time--> 41.20 41.40
AbundanceIon 264.00 (263.70 to 264.70); ENG
JIon 132.00 (131.70 to 132.70): ENG
41.32
4000
264
100
132
0.0
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC: ENG1687.D
10000 -
5000 -
0 '
Time--> 41.20 41.40 41.60
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126 .70) : ENG
41.49
6000 :
/A
4000 I
J v_
2000 .
0 -
Time--> 41.20 41.40 41.60
#29
Benzo(a)pyrene(CCC)
Concen: 0.62 ng/uL
RT: 41.49 min Scan# 4299
Delta R.T. -0.00 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:252 Resp: 19863
Ion Ratio Lower Upper
252
100
126
0.0
0.1
0,1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HP 5989B
0CC3521
Page 16
-------
Abundance
15000 -
10000
5000
> lj I l' i I > T I J ' •I J
[rime - -> 51.00 52 . 00 53 .00
TIC: ENGlbB?.D
Abundance Ion 288.00 (287,70 to 288.70); ENG
4000
3000
2000
1000
Time-
51.00
T > 1 1-
52.00
—i——i—i—j-
53.00
Abundance
15000
10000 -
5000
0
TIC: ENG1687.D
4000
3000
2000
1000
Ion 138.00 (137.70 to 138.70)
52.35
~1 1—I—I !—f—I—!—i-—1 s I t— I I I ( !
(Time--> 52.00 52.20 52.40 52 .60
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT; 52.07 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion: 288
Ion
288
0
0
0
Exp Ratio
100
0.0
0.0
0.0
#31
Indeno <1,2,3-cd)pyrene
Concen: 0.59 ng/uL m
RT: 52.35 min Scan# 5979
Delta R.T. 0.01 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:276.05 Resp: 19122
Ion Ratio Lower Upper
Time--> 52.00 52.20 52.40 52.60
Abundance Ion 276.05 (275.75 to 276.75): ENG
276
138
0
0
100
63 .8
0.0
0.0
0.1
0.0
0.0
0.1#
0.0
0.0-
ING
ENG1687.D—PES4 .M
Wed Oct 20 11:40:59 1999
0CC3S22
HP 5989B Page 17
-------
Abundance
15000
TIC: ING1S87.D
xoooo
5000
Time--> 51.00 52.00 53.00
AbundanceIon 292.00 (291.70 to 292.70): IMG
3000
2000
1000
0
Time-->
51.00
~i 1 1 r-
52.00
53 .00
TIC: ENG1687.D
Abundance
15000
10000
5000
0
Time--> 52! 20 52!40 ' 52!60
Abundance Ion 278.00 (277.70 to 273.70): ENG
lion 139.00 {138.70 to 139.70)
4000i 52.39
3000 J
2000
1000
0
C I I | I
Time - - > 52.20
SNGX¥ST7D—PES4.M
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.00 ng/uL
Expected RT: 52.03 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion: 292
Ion Exp Ratio
292 100
0 0.0
0 0.0
0 0.0
#33
Dibenz(a, h)anthracene
Concen: 0.57 ng/uL
RT: 52.39 min Scan# 5987
Delta R.T. 0.01 min
Lab
File:
ENG1687.D
Acq:
19 Oct
99 2:54 pm
Tgt
Ion:278
Resp: 15615
Ion
Ratio
Lower Upper
278
100
139
0.0
0.1 0.1#
0
0.0
0.0 0.0
0
0.0
0.0 0.0
—, , r—| 1 1 r—1 1 ! 1 T-
52.40 52.60
Wed Oct 20 11:41:02 1999'
0CC3S23
HP 5989B Page 18
-------
Sundance
TIC: ENG1687.D
10000 -
5000 .
0
I '
Time--> 54.60
54.80 55.00 55.20
Abundance Ion
288.00 (287.70 to 288.70): ENG
4000 :
55.01
3000 :
2000:
iooo :
o.
j T
Time-->54 160
• » « i i i i i i i i i i j i \ i * i t
54.80 55.00 55.20
#34
Benzo(g,h,i)perylene-dl2
Concen: 0,58 ng/uL m
RT: 55.01 min Scan# 6474
Delta R.T. 0.02 min
Lab File: ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:288 Resp: 15768
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1S87.D
10000
5000
#35
Benzo(g,h,i)perylene
Concen; 0.59 ng/uL
RT: 55.33 min Scan# 6551
Delta R.T. -0.00 min
Lab File; ENG1687.D
Acq: 19 Oct 99 2:54 pm
Tgt Ion:276 Resp: 20775
Ion Ratio Lower Upper
Time
"i—i—r—i—i—!—r—I—r
55 .00 55.20
55 i 40 55160
276
100
138
0.0
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
[AbundanceIon 27S.00 (275.70 to 275.70): ENG
Ion 138.00 (137.70 to 138.70): ING
55.33
4000
2000
Time-->
ENG1687.D PES4.M
—i—J—\—|—|—|—|—|—|—|—,—|—|—i"-—n—I—|—i—i—i—r
55.00 55.20 55.40 55.60
_ wed Oct 20 11:41:05 1999'
HP 5989B
Page 19
-------
Quantitation Report
Data File : C:\HPCHEM\l\DATA\ENG1690.D
Acq On : 19 Oct 99 6:11 pm
Sample ; CARB429,QA/QC,CCAL2.0
Misc :
Quant Time: Oct 20 10:25 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Vial
Operator
Ins t
Multiplr
HP 5989B
1.00
Internal Standards
R.T, Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.90
190
515960
5.00 ng/uL
I o
1 HI
1
1 O
1
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
17.59
136
298094
1.02 ng/uL
25.54%
4)
2-Methlynaphthalene-dlO
19.27
152
154126
1.52 ng/uL
38.03%
5)
Acenaphthylene-d8
21.53
160
197126
2.20 ng/uL
55.00%
7)
Acenaphthene-dl0
21,94
164
153740
1.75 ng/uL
43.81%
9)
Fluorene-dlO
23 .21
176
172386
1.99 ng/uL
49.7 0%
11)
Phenanthrene-dl0
25.58
188
233776
1.91 ng/uL
47.63%
13)
Anthracene-dlO
25.72
188
29512
0.50 ng/uL
12.43%
15)
Fluoranthene-dl0
28 .57
212
184587
1.65 ng/uL
41.18%
17}
Pyrene-dlO
29 .17
212
194173
1.55 ng/uL
38.80%
19}
p-Terphenyl-dl4
29 .51
244
156688
1.56 ng/uL
38.96%
20)
Benzo(a)anthracene-dl2
33 .20
240
64699
1.40 ng/uL
34.89%
22)
Chrysene-dl2
33.33
240
103617
1.25 ng/uL
31.16%
24)
Benzo(b)fluoranthene-dl2
39.10
264
57177
1.11 ng/uL
27.87%
26)
Benzo(k)fluoranthene-dl2
39.26
264
55770
1.08 ng/uL
27.00%
285
Benzo(a)pyrene-dl2
41.32
264
26190
0.96 ng/uL
23.88%
30)
Indeno(1,2,3-cd)pyrene-dl2
52 .07
288
29440
0.97 ng/uL
24.22%
325
Dibenz(a, h)anthracene-dl4
52.03
292
18218
0.98 ng/uL
24.43%
34)
Benzo(g,h,i)perylene~dl2
54.99
288
30302
0.94 ng/uL
23.51%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.63
128
2 94659
0 . 89 ng/uL
99
6}
Acenaphthylene
21.55
152
214081
1.90 ng/uLm
95
8)
Acenaphthene(CCC)
22»01
154
152079
1.55 ng/uL
93
10)
Pluorene
23.27
166
174887
1.71 ng/uL
100
12)
Phenanthrene
25 .63
178
252667
1.64 ng/uL
98
14)
Anthracene
25.76
178
199194
2.10 ng/uL
98
16)
Fluoranthene(CCC)
28.62
202
209882
1.40 ng/uL#
75
18)
Pyrene
29.22
202
220692
1.33 ng/uL
74
21)
Benzo(a)anthracene
33.29
228
93423
1.21 ng/uL#
72
23)
Chrysene(CCC)
33 .44
228
121062
1.09 ng/uL#
75
25)
Benzo(b)fluoranthene
39.26
252
76353
0.97 ng/uL#
69
27)
Benzo(k)fluoranthene
39.41
252
55495
0.96 ng/uL#
71
29)
Benzo(a)pyrene(CCC)
41.50
252
33569
0.88 ng/uL#
43
31)
Indeno(1,2,3-cd)pyrene
52.34
276
35272
0.92 ng/uL#
21
33)
Pk«« Wan ** / si Vi § a y\ V* w> a aw tsx
u xosnz \ ct f n) cin
52.38
278
29302
0.89 ng/uL#
25
35)
Benzo(g,h,i)perylene
55.33
276
36752
0.88 ng/uL#
62
0CG3S2;
(#) = qualifier out of range (m) = manual integration
ENG1690.D PES4.M Wed Oct 20 11:44:48 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\SNG16 9 0.D
19 Oct 99 6:11 pm
CARB42 9,QA/QC,CCAL2.0
Oct 20 10:25 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METH0DS\PES4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Vial: 5
Operator:
Inst : HP 5989B
Multiplr: 1.00
Abundance
350000
300000
250000
200000
150000 -
100000
50000
0
Time-->
3
2s
4s
10
6
5s
12
m
17 s
iass
TIC: EMS1S90.D
20
-J
3iS
31&
i—r~i—i—i—r~i—|—i—'—i—i—i—i—i—i—!—|—i—i—i—i—I—i—i—r™-i—i—i—f—i—i—r—?—i—i—i—i—i—r
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
ENG1690.D PES4.M Wed Oct 20 11:44:57 1999 HP 5989B Page 2
-------
Abundance
150000 .
100000
50000
0
rime-->
TIC: BNG1690.D
17.40
17,60
-i j j r
17.80
150000
100000
17.59
17.40
17 .60
17.80
#2
Naphthalene-d8
Concern l.02 ng/uL
RT: 17.59 min Scan# 236
Delta R.T. -0.10 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:136 Resp: 298094
Ion Ratio Lower Upper
136 100
68 8.9 7.7 23.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
arc 3 fZLTZ A ¦> jm A A I i "1 W PI A TTZZ yyy 'W"H'
AbundanceIon 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.70): ENG 16
50000
Time
17 ;40
17; 60
17180
TIC: ENG1690.D
150000
100000
50000
#3
Naphthalene(CCC)
Concen: 0.89 ng/uL
RT: 17.63 min Scan# 243
Delta R.T. -0.11 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:128 Resp: 294659
Ion Ratio Lower Upper
128 100
127 12.6 0.0 63.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 128 .00 (127.70 to 128 .70) : ENG
.Ion 127.00 (126.70 to 127.70): ENG
150000 17.63
100000
50000
0
Time - ->
17 .40
17 .60
17.80
ENG1690.D—PES4.M
Wed Oct 20 11:45:00 1999
HP 5989B
00C3S27
Page 3
-------
TIC: £NGl690.U
60000:
40000:
20000:
19 .30
19 .40
19.20
Time--> 19.10
¦ ..-r.....--J...— JJ— m ipnr ^ ^ pr-w , ' W "g A W A 1 WVI/N
Abundance Ion 152.00 (151.70 to 152.70) : 1NG
19.27
80000
60000
40000
Time--> 19.10 • 19 .20
19.40
#4
2-Methlynaphthalene-dlO
Concen: 1.52 ng/uL
RT: 19.27 min Scan# 765
Delta R.T. -0.10 min
Lab File: ENG169 0.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:152 Resp: 154126
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
100000
TIC: SNG1690.D
50000
0
Time - - > VlU's' 21150 21155
Abundance Ion 160.00 (159.70 to 160.70}
21! 6o'
#5
Acenaphthylene-dS
Concen: 2.20 ng/uL m
RT: 21.53 min Scan# 1260
Delta R.T. -0.10 min
Lab File: ENG16 90.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:160 Resp: 197126
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
100000
50000
21.53
0
Time-
21.45 21.50
I ' < ' < i ''
21.55 21.60
ENG1690 .0 PE54" 1M
Wed. Oct—213—11 «. —X999
0CC3523
HP 5989B Page 4
-------
Abundance
100000
TIC: EMG1S90.D
Time--> 21.50
abundance Ion 152.00 (151.70 to 152.70)
50000
1 1 1-
21.60
Ion 153.00
(152.70 to 153.70)
21.55
100000
50000
0
Time-->
21.50
#6
Acenaphthylene
Concern 1.90 ng/uL ra
RT: 21.55 min Scan# 1264
Delta R.T. -0.11 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:152 Resp: 214081
Ion Ratio Lower Upper
ENG
152
100
153
14.6
6.6
19 .6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
21160
Abundance
150000
100000
50000 ^
TIC: 2NG1690.D
0
"r *"""i 1 r
T
Time-->21.70 21.80
Abundance Ion 164.00
21.90 22100 22.10
(163.70 to 164.70)
21.94
"ENG"
50000
-1—I 1 1—I—1 1 l—1—I—i—1—1—1—r—1—iiii—1 1
7ime- - >21! 70 21! 80 21. 90 22 ! 00 22 .10
#7
Acenaphthene-dlO
Concen; 1.75 ng/uL
RT; 21.94 min Scan# 1321
Delta R.T. -0.10 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:164 Resp: 153740
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0CC3S29
ENG1690.D—PE34.M
Wed Oct 20 11:45:07 1999
HP 5989B
Page 5
-------
(Abundance
150000
100000 J
50000
TIC: EMG1690.D
0
i ! i i
Time - - > 21.90
Abundancelon 154.00
Ion 153.00
22:00
22.10
(153.70 to 154.70)s 2NG
(152.70 to 153 .70) : ENG
22 .01
50000 .
0
Time - ->
1—1—*]—1 1—i—1—|—1—1 ! 1—|—1 ! 1—r~
21.90 22.00 22ll0
#8
Acenaphthene(CCC)
Concen: 1.55 ng/uL
RT: 22.01 min Scan# 1332
Delta R.T. -0.11 min
Lab File-. ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:154 Resp: 152079
Ion Ratio Lower Upper
154 100
153 104.5 49.1 147.1
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
150000
100000
50000
EKGlb90.D
Time-->
Abundance Ion 176.00
100000 -
1—i—t—!—1—i—1—|—f—!—r- r"-"]—1—1—1—i—j—1—i—r—t—1—?—1—r~
23.00 23.10 23.20 23.30 23.40
#9
Fluorene-dlO
Concen: 1.99 ng/uL
RT: 23.21 min Scan# 1513
Delta R.T. >0.10 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:176 Resp: 172386
Ion Ratio Lower Upper
176
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
!175.70 to 176.70)
23 .21
50000
Time - -> 23 :00 23 .10 23:20 *23 !30
ENG1F90 .D' PES4 .M
23 .40
Wed Oct 20 11:45:10 1999'
HP 5989B
OOC3S3Q
Page 6
-------
TIC: ENG1690.D
Abundance
150000 .
100000 -
50000 -
Time--? 23,10
Abundance Ion 166.00 (165.70 to 166.70): ENG
100000 JIon 165.00 (164.70 to 165.70): ENG
23 .20
23 .30
23 .40
50000 -
23.20
Time--> 23.10
23.30
#10
Fluorene
Concern 1.71 ng/uL
RT; 23.27 min Scan# 1523
Delta R.T. -0.11 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:166 Resp: 174887
Ion Ratio Lower Upper
166
100
165
91.5
45.7
137.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
TIC: ENG1690.D
0
Titne--> 25.50 25.60 25.70
Abundance Ion 188.00 (187.70 to 188.70):
#11
Phenanthrene-dl0
Concen: 1.91 ng/uL
RT: 25.58 min Scan# 1873
Delta R.T. -0.11 min
T.saVi 17i 1 o# DMdi £"QA tn
i-iclJJ 0, JL X C « CiJDtvjr JL O wf \J * U
Acq: 19 Oct 99 6:11 pm
Tgt Ion:188 Resp: 233776
Ion Ratio Lower Upper
188
100
94
10 .9
12.3
36.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Ion 94.00
(93.70 to 94.70)
25.58
EMT
ENG16
100000
50000
Time-
ENGtwcr
n 1 1 1 r
25.50
TS PES4.M
—i 1 1 r
25 .70
wed Oct 20 iyyy
-i | 1 r-
25.60
0CG3S31
HP 5989B Page 7
-------
Abundance
150000
100000
50000
Time - - >
TIC: ENG1690.D
i i—j—i—f—< ' j—t "i ?—j—r—i—i—r—i—i—i—~i—i—r
25.55 25.60 25.65 25.70
Abundance Ion 178.00 (177.70 to 178.70); ENG
150000
100000
50000
¦lion 176.00 (175.70 to 176.70): ENG
25.63
Time-
] ! 1 1—I—|—1 i 1 1 ! 1 1 ! r 1 1
25.55 25.60 25.65 25.70
#12
Phenanthrene
Concen: 1.64 ng/uL
RT: 25.63 min Scan# 1881
Delta R.T. -0.11 min
Lab File; SNG1690.D
Acq; 19 Oct 99 6:11 pm
Tgt Ion:178 Resp: 252667
Ion Ratio Lower Upper
178
100
176
19 .5
10.2
30.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
TIC: ENG1690.D
50000
r "i t i—f—!—!—i—i—j—i—i—i—r~—j—t—!—r r i—r—r-
Time--> 25150 25.60 25.70 25.80 25190
Abundance Ion 188.00 (187.70 to 188.70): ENG
Hon 94.00 (93.70 to 94 . 70) : ENG16
#13
Anthracene-dlO
Concen: 0.50 ng/uL
RT: 25.72 min Scan# 1894
Delta R.T. -0.11 min
Lab File: 1NG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:188 Resp: 29512
Ion Ratio Lower Upper
188
100
94
0.0
13 .4
40.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
100000
50000
Time-
•> 25150
25.72
25.60
ENG1690,D—PES4.M
, S J 1 1 J 1 1 1 1 1 ! 1
25.70 25.80 25.90
Wed Oct 20 11:45:16 1999
HP 5989B
£22
Page 8
-------
Abundance
150000
100000
"TIC7 ENG1690.D
50000
25. 76
100000 -
50000
0
Time - - >
25.70
25.80
Time--> 28.40
Abundance Ion 212.00
100000Jlon 106.00
• 1 i
28.50
f—i—i—S !—I—I—f—I ! (—r
28 160 28.70
#14
Anthracene
Concen: 2.10 ng/uL
RT: 25.76 min Scan# 1901
Delta R.T. -0.10 min
Lab File; ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion: 178 Resp*. 199194
Ion Ratio Lower Upper
Time--> 25170 25.80
Abundance ion 178.00 (177.70 to 178.70): ENG
150000 -|Ion 176.00 (175.70 to 176.70); ENG
178
100
176
18.9
10.0
29.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1690.D
100000
50000
#1 e
TT •> w
Fluoranthene-dlO
Concen: 1.65 ng/uL
RT: 28.57 min Scan# 2331
Delta R.T. -0.11 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:212 Resp: 184587
Ion Ratio
212 100
106 12 .7
Lower Upper
0
0
0.0
0.0
13.7
0.0
0.0
41.0#
0.0
0.0
(211.70 to 212.70): ENG
(105.70 to 106.70): ENG
28.57
50000
0
frime - ->
ENGTF9TJ7D PES4 .M
i—!——|—!—5—i—!—|—!—r—i—r
28.40 28.50 28160
28 .70
Wia^T3cr^nrTTT45:19 1999
HP 5989B
Page 9
-------
Abundance
100000 .
TIC: ENG169C.D
50000
-i 1 1 1 1 * 1 1 1 r
28.60 28.80
Time --> 28.40
Abundance Ion 202.00 (201.70 to 202.70): ING
100000
50000
Ion 101.00 (100.70 to 101.70): ING
28.62
Tirae-->
28.40
28.60
28,80
#16
Pluoranthene(CCC)
Concen: 1.40 ng/uL
RT: 28.62 rain Scan# 2339
Delta R.T. -0.10 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:202 Resp: 209882
Ion Ratio Lower Upper
202
100
101
11.9
12 .1
36.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1690.D
100000
50000
29.00
29.20
29.40
Time
#17
Pyrene-dlO
Concen: 1.55 ng/uL
RT: 29.17 min Scan# 2420
Delta R.T. -0.12 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:212 Resp: 194173
Lower Upper
Ratio
100
14.6
0.0
0.0
15.9
0.0
0.0
47.5#
0.0
0.0
AbundanceIon 212.00 {211.70 to 212.70): ING
100000 106.00
(105.70 to 106
29.17
70): ENG
50000
0
Time - - >
29.00
-i 1 1 r
29.20
i » r
29.40
ENG1690 .13—PES4 .M
"ireanjcr-w-irrfBTirTiw
WO CQQQn
mr d y ojo
Page 10
-------
Abundance
~TICr"ERG1690 ,D
Time-->
100000
50000
A
V 1
J
( r
29100
-i ! r~
29 .20
29.40
ten s— m —aai a A m a i- —py a ¦! Plltf/"! '
Abundance Ion 202.00 (201.70 to 202,70): ENG
Ion 101.00 (100.70 to 101.70): ENG
100000 29.22
50000
0 >
Time--> 29.00
! I T" J I
29:20
29.40
#18
Pyrene
Concen: 1.33 ng/uL
RT: 29.22 min Scan# 2428
Delta R.T. -0.11 min
Lab File: ENG1S90.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:202
Ion Ratio
202 100
101 14.1
0 0.0
0 0.0
Resp: 220692
Lower Upper
13.9 41.5
0.0 0.0
0.0 0.0
Abundance
100000
TXCT~ER(3llW7U"
50000
J
0
? \ •• 1—1—1—!—|—1—i—1—1——1—>—1—r~~t—1—r—r~~|—r—r~
Time--> 29.30 29.40 29:50 29.60 29.70
Abundance Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122.70): ENG
29 .51
8 0 0 0 0 ~
60000
40000:
20000
—, , , , j 1 , , , 1 1 , , 1 1 j 1 , 1 1 1 r
fTime- - > 29.30 29.40 29:50 29.60 29.70
#19
p-Terpheny1-dl4
Concen: 1.56 ng/uL
RT: 29.51 min Scan# 2471
Delta R.T. -0.11 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:244 Resp: 156688
Ion Ratio Lower Upper
244
100
122
13 .5
14.6
43.7#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG16 9 0 . D PES4.M~"
Wed Oct 20 11:45:34 1999
HP 5989B
0CC3S34
Page 11
-------
TTC: 2MG1690.D
Abundance
40000 -
20000 .
Time-->
Abundance Ion 240.00 (235.70 to 240.70): ENG
jlon 120.00 (119.70 to 120.70): ENG
33 .10
33.20
33.30
30000:
33.20
20000:
ioooo :
Time-->
33 .10
33.20
33 .30
#20
Benzo(a)anthracene-dl2
Concen: 1.40 ng/uL
RT; 33.20 min Scan# 3025
Delta R.T. -0.16 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:240 Resp: 64699
Ion Ratio Lower Upper
240 100
120 11.9 14.0 41.9#
0 0.0 0.0 0,0
0 0,0 0.0 0.0
Abundance
40000
TIC: EUG1690.D
20000 .
#21
lenzo(a)anthracene
Concen: 1,21 ng/uL
RT: 33.29 min Scan# 3039
Delta R.T. -0,17 min
Lab File: 690 .D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:228 Resp: 93423
Ion Ratio Lower Upper
-i 1 r~—r* i ! 1 1 1 i -i 1 1 1 1 1
Time--> 33.20 33.30 33.40
Abundancelon 228.00 {227.70 to 228.70): ENG
]Ion 114.00 (113.70 to 114.70): ENG
40000
228
100
114
11.1
12 .8
38. 2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
33.29
30000 J
20000
10000
Time - ->
ENGlfeyU .D—P1S4.M
—! 1 F
33 120
33.30 33.40
Wed Oct 2U 11:45:37 1999'
HP 5989B
3555
Page 12
-------
Abundance
TIC: EHG1690.D
40000 .
[\ j\
20000 .
,_J\J \j
0 -
Time - - >
1 '"j ! i l l 1 I 1 i 1 1 < I
33I20 33.40
Abundancelon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
33 .33
30000 -
A
20000
A 1 \
10000
0.
Time-->
33.20 33.40
#22
Chrysene~dl2
Concen: 1.25 ng/uL
RT: 33.33 min Scan# 3045
Delta R.T, -0.17 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:240 Resp: 103617
Ion Ratio Lower Upper
240
100
120
12.1
13 .7
41.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: EMGlSyO.D
40000
20000
#23
Chrysene(CCC)
Concen: 1.09 ng/uL
RT: 33.44 min Scan# 3062
Delta R.T. -0.17 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pra
Tgt Ion:228 Resp: 121062
Time
T 1 1 1 1 1 ] i 1 1 1 1 1 1 r
33.20 33.40 33.60
Ratio
100
10.1
0.0
0.0
Lower Upper
11.2
0.0
0.0
33 . 5#
0.0
0.0
Abundancelon 228.00 (227.70 to 228.70): ENG
lion 114.00 (113.70 to 114.70): ENG
40000 J 33.44
30000
20000
10000
Time-
,
33.20
| f-
33 .40
—1 1 1 1 r-
33 .60
ENG1690. D PES4.M
0CC3S35
Wed Oct 20 11:45:39 1993
HP 5989B
Page 13
-------
TTC-. ENG16 90 .D
30000
20000
10000
Time - - > 38.90
*t—i—j—s—r
39.00
' F <
39.10
39.20
Abundance I on 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
39.10
15000
10000 j
5000
Time-
t ' '
38.90
—i—[—\—i—j—i—j—j—i—i—i—j—r*~i—i—i—p—r-
39.00 39.10 39.20
#24
Benzo(b)fluoranthene-dl2
Concen: 1.11 ng/uL
RT: 39.10 min Scan# 3931
Delta R.T. -0.25 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:264 Resp: 57177
Ion Ratio Lower Upper
264
100
132
13.0
34.8
104.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
wp. ENG169Q o
30000
20000
10000
#25
Benzo(b)fluoranthene
Concen: 0.97 ng/uL
RT: 39.26 min Scan# 3955
Delta R.T. -0.26 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:252 Resp: 76353
Ion Ratio Lower Upper
"i—r
39:10
1—1—1—t—j—1—r—r
39.20 39.30 39.40
rxme-->
Abundance Ion 252.00 (TBI.70 to 252.707
252
100
126
11.6
14 . 0
41.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
"SWT
20000
15000 J
10000
5000
0
Ion 126.00 (125.70 to 126.70): ENG
39.26
1 j 1 , r
39.10
Time-->
ENG1690.D—PES4.M
39.20 39.30 39.40
Wed Oct 20 11:45:42 1999'
0003S37
HP 5989S Page 14
-------
Abundance
30000
TIC: ENGlSyu.u
20000
10000 -
Time-
n 1 r
39.00
39:20
39.40
t 1 1 r
Abundance Ion 264.00 (263.70 to 264.70): ENG
15000
10000
5000
Ion 132,00
131.70 to 132.70): ENG
39.26
#26
Benzo(k) f luoranthene-d.12
Concen: 1.08 ng/uL
RT: 39.26 min Scan# 3956
Delta R.T. -0.26 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:264 Resp: 55770
Ion Ratio Lower Upper
264
100
132
13 .4
18.0
53.8#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TTC: ENG1690.D
30000
20000
10000
39 .20
1 1 r
39.60
39.40
#27
Benzo(k)fluoranthene
Concen: 0.96 ng/uL
RT: 3 9.41 min Scan# 3978
Delta R.T. -0.26 min
Lab File: ENG1690.D
Acq*. 19 Oct 99 6:11 pm
Tgt Ion:252 Resp: 55495
Ratio
100
12 .6
0.0
0.0
Lower Upper
13.9
0.0
0.0
41.5#
0.0
0.0
Abundance Ion 252.00 (251.70 to 252.70) : ENG
20000
15000
10000
5000
JIon 126.00 (125.70 to 126.70): ENG
0
Time-->
ENGXSWTD—PES4 . M
39 .41
39 .20
39 .40
39.60
Wed Oct 2U 11:45:45 1999
HP 5989B
00G3S33
Page 15
-------
abundance"
15000
TIC: EMG1690.D
Time-->
Abundance Ion 264.00 (263.70 to 264.70): ENG
10000
5000
'l I 1 1 1 1
41.20
-i 1 r-
41.40
ilon 132.00 (131.70 to 132.70!
41.32
6000
4000
2000
0
Time-->
41.20
41.40
#28
Benzo(a)pyrene-dl2
Concen: 0.96 ng/uL
RT: 41.32 min Scan# 4270
Delta R.T. -0.30 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pra
Tgt Ion:264
Ion Ratio
264 100
132 0.0
0 0.0
0 0.0
Resp: 26190
Lower Upper
19.0 56.8#
0.0 0.0
0.0 0.0
Abundance
15000
10000
5000
0
Time-->
TIC: EMG1690.D
41.40
1 1 1 1 r
41! 60
#29
Benzo(a)pyrene(CCC)
Concen: 0.88 ng/uL
RT: 41.50 min Scan# 4298
Delta R.T. -0.29 min
Lab file: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:252 Resp: 33569
Ion Ratio Lower Upper
252 100
0.0 15.7 46.9#
0.0 0.0 0.0
0.0 0.0 0.0
Abundance Ion 252.00 (251.70 to 252 . 70) : ENG"
10000
5000
Ion 126.00 (125.70 to 126.70)
41.50
rime-->
ENG'l690 ,D PSS4 .M
41.40
41.60
Wed Oct 20 11:45:48 1999
HP 5989B
0CG3S39
Page 16
-------
SEu
TIC: ENG1690.D
15000
10000
5000
0
i—i—i—J—i—i—i—i—|—i—i—i—i—|—i—r—i—i—|—i—
51.80 52.00 52.20 52.40
Time-->
AbundanceIon 288.00 (287.70 to 288.70)
6000
4000
"INS"
2000
52.07
Time - - >
51180 52100 52120 52.40
#30
Indeno(1,2,3-cd)pyrene-dl2
Concent 0.97 ng/uL m
RT: 52.07 min Scan# 5958
Delta R.T. -0.46 rain
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:288 Resp: 29440
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1690.D
15000
10000
5000
~i—i—i—i—r~i—i—i—i—|—r~i—f—i—|—f—i—i—i—r~
52100 52.20 52.40 52.60
6000
4000
2000
¦Ion 138.00 (137.70 to 138.70):
52 .34
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.92 ng/uL
RT: 52.34 min Scan# 6008
Delta R.T. -0.48 min
Lab Pile: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion;276.05 Reap: 35272
Ion Ratio Lower Upper
Time-->
Abundance Ion 276.05 (275.75 to 276.75): ENG
276
100
138
0.0
30.1
90.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG
0
Time--> 52.00
ENG1690.D PES4.M
1 ! | [ f | 1 1 1 I ] T"
52.40 52160
52.20
Wed Oct 2U 11:45:51 1999
0CC3S'i9
HP 5989B
Page 17
-------
TtC: 2NG1650.D
15000:
10000:
5000:
52.20
52.00
51.80
Time
j I M < * ¦ 1 ¦ ¦ ¦ ¦ 1—¦ f~ H ¦ II
Abundance Ion 292.00 (291.70 to 292.70) : ENG
52.03
4000 J
2000
Time-->
51.80
52.00
52 .20
#32
Dibenz(a,h)anthracene-dl4
Concen: 0.98 ng/uL
RT: 52.03 min Scan# 5950
Delta R.T. -0.47 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion *.292 Resp : 18218
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC; EMG1690.D
15000
10000
5000
t 1 r*—r j 1 1 ? r 1 1 r-
[Time - ->52 1 00 52120 52140
#33
Dibenz(a, h)anthracene
Concen: 0.89 ng/uL
RT: 52.38 min Scan# 6016
Delta R.T. -0.48 min
Lab File: ENG16 90.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:278 Resp:
Ion Ratio Lower
278 100
52:60^
139
0
0
0.0
0.0
0.0
26.9
0.0
0.0
29302
Upper
80.5#
0.0
0.0
Abundance Ion 278.00
6000
4000
2000
Ion 139.00
(277.70 to 278.70): ENG
(138.70 to 139.70): ENG
52.38
Time-->52.00
C5 nfi
d <
-------
Abundance
10000 -I
5000
TIC: ENG1690.D
Time--> 54160' 54180 55100 55120 55140
[AbundanceIon 288.00 (287.70 to 288.70): SNG
54180 55 !00
' t
55 ,20
4000
2000
0 -
54.99
'T ' 5 " T ' ¦ J T—1 J—T—| f ! 1 ! 1 T 1 1 T—J 1 ! ! I 1 J ! J
54.60 54.80 55.00 55120 55140
Abundance
10000
TIC: EHG1690.D
5000
0
r—t—I—[—r
55120
1—1—j—1—1—I—i—1—1—1—r-
55.40 55.60
Time--> 55.00
Abundancelon 276.00 (275.70 to 276.70): EMS
ilon 138.00 (137.70 to 138.70): 1NG
55.33
6000
4000
2000
I i " j
ENGlfeyU . D—PEB4 . M
1—1—1—|—1—1—1—1—1—1—1—1—1—
55.00 55120 55140 55160
#34
Benzo (g, h., i) perylene-dl2
Concen: 0.94 ng/uL m
RT: 54.99 min Scan# 6559
Delta R.T. -0.53 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:288 Resp: 30302
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#35
Benzo(g,h,i)perylene
Concen: 0.88 ng/uL
RT: 55.33 min Scan# 6642
Delta R.T. -0.51 min
Lab File: ENG1690.D
Acq: 19 Oct 99 6:11 pm
Tgt Ion:276 Resp: 36752
Ion Ratio Lower Upper
276
100
138
0.0
6.5
26.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
wed Oct 20 11:45:57 1999
HP 5989B
0CC3S42
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DATA\ENG1691.D
19 Oct 99 7;17 pm
CARB42 9,QA/QC,CCAL3.0,
Oct 20 10:35 1999
Vial: 6
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.90
190
578313
5.00 ng/uL
1
1
O I
I
O 1
O I
System Monitoring Compounds
%Recovery
2}
Naphthalene-d8
17.59
136
468379
2.24 ng/uL
56.05%
4)
2-Methlynaphthalene-dl0
19.27
152
255239
2.61 ng/uL
65.13%
5)
Acenaphthy1ene-d8
21.53
160
393522
3.58 ng/uL
89 .51%
7)
Acenaphthene-dlO
21.94
164
252961
2.70 ng/uL
67.55%
9)
Pluorene-dlO
23 .21
176
283145
2.79 ng/uL
69.64%
11)
Phenanthrene-dl0
25.58
188
386326
2.76 ng/uL
69.01%
13)
Anthracene-dl0
25.72
188
57325
0.65 ng/uL
16.36%
15)
Fluoranthene-dl0
28.57
212
327231
3.03 ng/uL
75.77%
17)
Pyrene-dlO
29.17
212
349606
3.10 ng/uL
77.50%
19)
p-Terphenyl-dl4
29.51
244
282710
2.97 ng/uL
74.16%
20)
Benzo(a)anthracene-dl2
33.20
240
136040
3.36 ng/uL
84.03%
22)
Chrysene-dl2
33.34
240
204082
3.13 ng/uL
78.34%
24)
Benzo(b)£luoranthene-dl2
39 .11
264
116525
3.01 ng/uL
75.26%
26)
Benzo(k)fluoranthene-dl2
39 .27
264
118125
3.02 ng/uL
75 .47%
28)
Benzo(a)pyrene-dl2
41.33
264
55413
2.81 ng/uL
70.26%
30)
Indeno(1,2,3-cd)pyrene-dl2
52.08
288
60779
2.03 ng/uL
50.82%
32)
Dibenz(a,h)anthracene-dl4
52 .06
292
36595
1.99 ng/uL
49.86%
34)
Benzo(g,h,i)perylene-dl2
55.02
288
55970
2.42 ng/uL
60.42%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17 .63
128
483417
2.19 ng/uL
99
6)
Acenapht hy1ene
21.55
152
438223
3.46 ng/uL
93
8)
Acenaphthene(CCC)
22 .01
154
257705
2.67 ng/uL
99
10)
Fluorene
23 .27
166
296712
2.73 ng/uL
100
12)
Phenanthrene
25.63
178
429316
2 .75 ng/uL
100
14)
Anthracene
25 .76
178
368455
3.37 ng/uL
100
16)
Fluoranthene(CCC)
28 .62
202
401427
3.04 ng/uL
99
18)
Pyrene
29.22
202
404244
2 .90 ng/uL
99
21)
Benzo(a)anthracene
33 .30
228
201587
3.24 ng/uL
100
23)
Chrysene(CCC)
33 .45
228
245120
3 .00 ng/uL
100
25)
Benzo(b)fluoranthene
39.26
252
164906
2 .97 ng/uL
99
27)
Benzo(k)fluoranthene
39.41
252
122311
2.88 ng/uL
98
29)
Benzo(a)pyrene(CCC)
41.50
252
73824
2.65 ng/uL#
100
31)
Indeno(1,2,3-cd)pyrene
52.36
276
69968
2.40 ng/uLm
100
33)
Dibenz(a,h)anthracene
52.41
278
59745
2 .42 ng/uL#
100
35)
Benzo(g,h,i)perylene
55.34
276
70427
2.40 ng/uL#
100
(#} = qualifier out of range (m) = manual integration
ENG1691.D PES4.M Wed Oct 20 11:46:26 1999 HP 5989B
D0.Ca§43._
Page l
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DA7A\ENG1691.D
19 Oct 99 7:17 pm
CARB42 9,QA/QC,CCAL3.0,
Oct 20 10:35 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\PES 4.M
Wed Oct 20 11:38:44 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
HP 5989B
1.00
TIC: ENGlb9l.D
Abundance
400000
350000
300000
250000
200000
150000
100000
50000
_A-_
LI
Time-->
1! —T" J !" ' I —¦T"~ | r I '"™""I ! ITT ! I 111 ["""1"' 1 I i T ! 1 l T "j p i i i i i "1 ' I I i \
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
ENG1691.D PES4.M
Wed Oct 20 11:46:35 1999
0003544
HP 5989B Page 2
-------
TIC: BMG1691.D
200000
100000
Time-
17140
T ] 1 T-
17 160
17.80
Abundance Ion 136.00 (135.70 to 136.70): IMG
Ion 68.00 (67.70 to 68.70): ENG16
17 .59
200000 4
100000
Time-->
-T , . j p-
17.40
~i 1 r
17.60
17.80
Abundance
200000
100000
TIC: ENG1691.D
Time--> 17140 11'.50
I IJIIIMIIIIMIII« 17.40 17.50 17.60 17170 17180
0003845
ENG169I.D PES4 .M
Wed Oct 20 11:46:39 1999
HP 5989B
Page 3
-------
Abundance
100000
50000
TIC: EHG1691.D
0
-J 1 1 1 ! 1 1 ! I 1 1 1 1 ! ! 1—
Time--> 19.20 19,30 19.40
Abundance Ion 152.00 (iSi.70 to 152.70): ENG
150000
19.27
100000
50000
19.20
19 .30
19.40
Time-->
414
2-Methlynaphthalene-dlO
Concen: 2.61 ng/uL
RT: 19.27 min Scan# 765
Delta R.T. 0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:152 Resp: 255239
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
100000
TIC: ENG1691.D
i—|—i—r—i—i—*t—i—i—i—i—I—i—r—i—r -"t—v i—r1 * |—i—i—ft
Time-- > 21.30 21.40 21.50 21.60 21.70
150000
100000
50000
21.53
Time-
1 1 f 1 j j 1 \ , 1 . 1 1 1 ? 1 , 1 1 1 r , j r-
21.30 21.40 21.50 21.60 21170
#5
Acenaphthylene-d8
Concen: 3.58 ng/uL
RT: 21.53 min Scan# 1260
Delta R.T. 0.00 min
Lab File; ENG1691.D
Acq*. 19 Oct 99 7:17 pm
Tgt Ion:160 Resp: 393522
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 160.00 (159.70 to 160.70): ENG
200000
00036-46
ENGT¥9T7D FES4.M
"Wed Oct 20 11:46:42 1999
HP 5989B
Page 4
-------
P&
undance
TIC: EMGT691.D"
200000
100000
I 1 f—| 5 1 ! 1 J 1 1 5 ! 1 1 ! 1 1 | r—I 5 1
Time--> 21.40 21.50 21.60 21.70
Ton 1S2 flQ—(1§1 70 to "T5"2 IMG
HUUiiUClilvV JkUi* • V V V < I W WW JL,mi <£m *¦ / M / « ClJ.'IVJ
jlon 153.00 (152.70 to 153.70); ENG
200000
150000
100000
50000
0
21.55
Time-
#6
Acenaphthylene
Coneen: 3.46 ng/uL
RT: 21.55 min Scan# 1264
Delta R.T. 0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:152 Resp: 438223
Ion Ratio Lower Upper
152
100
153
11.8
7.4
22.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
"i—i—i—!—j—i—i—i—!—|—i—i—r
2i:40 21.50 21.60 21:70
TIC: ENG1691.D
200000
100000
n—i—i—r
21.80
-1—i—1—1—r*
21.90
1—1—5—[—i—r—r
22:00 22.10
Time-->
Abundance Ion 164.00 (163.70 to 164.70)
150000
100000
50000
21.94
0
Time-->
ENG1691.D
I I I I I 1 f ] s- I ! 1 t I 'l J ) J 1
21.80 2i:90 22:00 22.10
PES4.M
#7
Acenaphthene- dl 0
Concen: 2.70 ng/uL
RT: 21.94 min Scan# 1321
Delta R.T. -0.00 min
Lab Pile: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:164 Resp: 252961
Ion Ratio Lower Upper
164 100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Wed Oct 20 11:46:45 1999
HP 5989B
000)547
Page 5
-------
TIC: 6UG16S1.D
200000 -
100000 -
¦ ——— ' ¦ — — —
Abundance Ion 154.00 (153.70 to 154.70) : ENG
Ion 153.00 (152.70 to 153.70): ENG
22 ,01
150000 -
100000 .
50000
#8
Acenaphthene(CCC)
Concen: 2.67 ng/uL
RT: 22.01 min Scan# 1332
Delta R.T. -0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:154 Resp: 257705
Ion Ratio Lower Upper
154
100
153
103 .6
52 .3
156.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1691.D
200000
100000 -
#9
Fluorene-d.10
Concen: 2.79 ng/uL
RT: 23.21 min Scan# 1513
Delta R.T. -0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:176 Reap: 283145
Ion Ratio Lower Upper
176 100
-i—i—f—i—i—r-i—i—i—i—i—i—j—i—i—i—r—|—i—r—?—i—[—i—i—r
Time--> 23.00 23.10 23.20 23.30 23.40
AbundanceIon 176.00 (175.70 to 176.70): ENG
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
23.21
150000:
100000
50000
t—i—j—t~~t—?—r~j—t—r~r—i—|—t——|—i—t—[—i—j—i—i—r~
Time--> 23.00 23.10 23.20 23.30 23.40
0003533
-------
TIC: ENG16 91. D
Abundance
200000
100000
-j 1 1 1—-i 1 1 1 1 1 1 ? ! r
Time--> 23)10 23.20 23.30 23)40
Abundance Ion 165.00 (165.70 to 166.70): SNG
]Ion 165.00 (164.70 to 165.70): ENG
23.27
150000 1
100000
50000 J
o
1 ! 1 ! 1 ! r—i ! e r—t 1 1 1 r~~l r
frime--> 23)10 23.20 23.30 23.40
#10
Pluorene
Concern 2.73 ng/uL
RT: 23.27 min Scan# 1523
Delta R.T. -0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:166 Resp: 296712
Ion Ratio Lower Upper
166 100
165 91.3 45.8 137.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1691.D
200000
100000
#11
Phenanthrene- dl 0
Concen: 2.76 ng/uL
RT: 25.58 rain Scan# 1874
Delta R.T. -0.00 rain
Lab Pile: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:188 Resp: 386326
Ion Ratio Lower Upper
Time--> 25.50
Abundance Ion I8d . 0o
Ion 94.00
200000
150000
25 .60
25.70
188
100
94
11.1
5.5
16.4
0
0.0
0.0
0.0
0
0.0
0.0
0.0
100000
50000
0
(187.70 to 188.70): ENG
(93.70 to 94.70): ENG16
25 .58
¦ T "¦ P'"" V—~"f" 1 1 1 1 1 I 1 1 ! 1 1 r
Time--> 25.50 25.60 25.70
SNGT691.D FES4 )FT Wed Oct 20 11:46:51 1999'
0C035I9
HP 5989B
Page 7
-------
TIC: StfSiSdl.D
200000
t—r-~i—!—|—!—i—i—i—j—i—i—i—i—i—i—i—i—r—|—I—1—e—r
frime--> 25.55 25.60 25.65 25.70
100000
Abundance Ion 178.00 (177.70 to 178.70)
Ion 176.00 (175.70 to 176.70)
25.63
200000 j
100000
ENG
ENG
Time-->
~1 ! 1 J 1 ! 1 1 5 !—I 1 1 1 1 j "1 1 ! 1 1 1 ! 1 T
25.55 25:60 25.65 25.70
Abundance Ion 188.00 (187.70 to 188.70)
Ion 94.00 (93.70 to 94.70): ENG16
200000 :
150000
100000
50000 - __ __
25 .72
i—r—r—r-
Time—> 25.50 25.60 25.70 25.80 25,90
ENGT53JT7D PES4.M
#12
Phenanthrene
Concern 2.75 ng/uL
RT: 25.63 min Scan# 1882
Delta R.T. -0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:178 Reap: 429316
Ion Ratio Lower Upper
178 100
176 19.5 9.8 29.3
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1691.D
200000
100000 -
#13
Anthracene-dlO
Coneen: 0.65 ng/uL
RT: 25.72 min Scan# 1895
Delta R.T. -0.00 min
Lab File: ENG1691.D
-T i 1 ? 1 1 ! 1 1 1 ! ! 1 ( 1 1 1 T
fTime--> 25150 25160 25.70 25.80 25.90
"SMT
Acq:
19 Oct
99 7:17 pm
Tgt
Ion:188
Resp: 57325
Ion
Ratio
Lower Upper
188
100
94
11.5
0.1 0.1#
0
0.0
0.0 0.0
0
0.0
0.0 0.0
Wed Oct 20 11:46:55 1999
0003550
HP 5989B Page 8
-------
TIC: ENG1691.D
200000
100000
I 1 1 r
25.90
1 '
25.80
25.70
Time - - > 25 . 60
m •• • i Wft T*T7K i'"4 m m ptk 3T~r—A *1 fl PIA I WVT/1*
Abundance Ion. 178.00 [177 . 70 to 178 .70) : ENG
Ion 176.00 (175.70 to 176.70): ENG
200000
100000
25 .76
Time--> 25 .60
i I i r
25.70
1 1 ! ! J r
25!80 25.90
#14
Anthracene
Concen: 3.37 ng/uL
RT: 25.76 min Scan# 1902
Delta R.T. -0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:178
Ion Ratio
178 100
176 18.7
0 0.0
0 0.0
Resp: 368455
Lower Upper
9.5 28.4
0.0 0.0
0.0 0.0
Abundance
200000
150000
100000
50000
"TIC: ENG1691.D
0
#15
Fluoranthene-dlO
Concen: 3.03 ng/uL
RT: 28.57 min Scan# 2332
Delta R.T. 0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:212 Resp: 327231
Ion Ratio Lower Upper
Time--> 28.40
Abundance Ion 212.00
]Ion 106.00
150000 -
100000
28.60 28,
(211.70 to 212.70):
(105.70 to 106.70)
28.57
80
ENG
1NG
212
100
106
12.8
6.4
19.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
50000
0
Time--> 28.40
& NG^LS5X—D—
28.60
28 . 80
Wed Oct 20 11:46:58 1999
OC03S51
HP 5989B • Page 9
-------
Abundance
200000:
150000
100000 .
50000:
(
Time-->
TIC: ENS1691.D
28.40
28.60
28.80
=TTT 3 ' m- _\j ar-yc-ag TTK 1 '«TA ¦« WK . «-¦¦¦ > If A V /"I
Abundance Ion 202.00 (201.70 to 202.70}: ENG
.Ion 101.00 (100.70 to 101.70): ENG
200000 -1 28.62
150000
100000
50000
0
Time - ->
28.40
28.60
28 .80
Abundance
200000
150000
100000
50000:
Ticnro3i69i.D
Time--> 29.00
AbundanceIon 212.00
Ion 106.00
150000 .
100000
29.20 29.40
(211.70 to 212.70):
(105.70 to 106.70)
29.17
#16
Fluoranthene(CCC)
Concen: 3.04 ng/uL
RT: 28.62 min Scan# 2340
Delta R.T, -0.00 min
Lab File; ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:202 Resp:
Ion Ratio Lower
100
11.5 6.0
0.0 0.0
0.0 0.0
401427
Upper
17 .9
0.0
0.0
#17
Pyrene-dlO
Concen: 3.10 ng/uL
RT: 29.17 min Scan# 2421
Delta R.T. -0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:212 Resp:
Ion Ratio Lower
100
349606
Upper
212
106
0
15
0
0
,2
,0
.0
7.4
0.0
0.0
22
0
swr
ING
50000
0
Time-->
" T ] T [ I
29.00
I ' | I 1111 'I
29.20
I " I ""T"
29.40
ENGTF5T7D PE5TTTT"
Wed Oct 20 11:47:01 1999
0C03S52
HP 5989B Page 10
-------
Abundance
200000 :
150000
100000
50000
0
Time - - >
TTC~- ENG16 91. D
29:00
29.20
T 1 1 f
29:40
Abundance Ion 202.00 (201.70 to 202.70)
Ion 101.00 (100.70 to 101.70)
29.22
"""
1NG
200000
150000
100000
50000
Time--> 29.00
29.40
#18
Pyrene
Concern; 2.90 ng/uL
RT; 29.22 min Scan# 2429
Delta R.T. -0.00 min
Lab Pile: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:202 Resp: 404244
Ion Ratio Lower Upper
202
100
101
14.4
7.1
21.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
150000
100000
50000
TIC: 2MG1691.D
#19
p-Terphenyl-dl4
Concen: 2.97 ng/uL
RT: 29.51 min Scan# 2472
Delta R.T. -0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:244 Resp: 282710
Ion Ratio Lower Upper
™i 1 1 1 r-
29.60
Time--> 29.40
Abundance Ion 244.00 (243.70 to 244.70)
244
100
122
13 .6
6.8
20 .3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
150000
100000
50000
0
Ion 122.00 (121.70 to 122.70): ENG
29.51
Time-->
ENG1fc y1.D—PES4.M
r
29.40
29! 60
wea act 2U 11-.47:04 1999'
HP 5989B
>0^53
Page 11
-------
1NG1691. D
80000
60000
40000
20000
Time •
33.10
33.20
33 .30
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
60000 -
sk
•
33.20 / \
40000 -
A / \
20000 -
0 -
Time - - >
33.10 33.20 33.30
Sundance
80000
60000
40000
20000
0
TIC: ENG1691.D
—' } ! i 1 1 1 1 1 1 f J 1 1 1 1 1 1 1 1 ! 1 1
33.10 33.20 33.30 33.40 33.50
Time - ->
0^,,^p^——MI 11 1 11 11 I I
Abundance Ion 228.00 (227.70 to 228.70)
#20
Benzo(a)anthracene-dl2
Concen: 3.36 ng/uL
RT: 33.20 rain Scan# 3026
Delta R.T. -0.00 min
Lab File*. SNG1691 .D
Acq: 19 Oct 99 7;17 pra
Tgt Ion:240 Resp: 136040
Ion Ratio Lower Upper
240
100
120
11.9
6.0
17 .9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
80000
60000
40000
20000
Ion 114.00 (113.70 to 114.70): ENG
33.30
Time--> 33!l0
ENGlfeyi.D—PES4.M
#21
Benzo(a)anthracene
Concen: 3.24 ng/uL
RT: 33.30 min Scan# 3041
Delta R.T. 0.01 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:228 Resp: 201587
Ion Ratio Lower Upper
228 100
114 11.0 5.6 16.7
0 0.0 0.0 0.0
0 0.0 0,0 0.0
T ! [ 1 1 1 1 1 1 1 1 1 J ! 1 ! 1 r !
33.20 33.30 33.40 33.50
wea oct 20 ii:47:uv iyyy
HP 5989B
0003554
Page 12
-------
'Abundance
80000 J
60000
40000
20000
0
Time-->
TIC: fiHGl69l.D
, ! r
33.20
1 1 T"
33 .40
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
33.34
60000
40000
20000
Time-->
Abundance
33120
33 .40
TIC: ENG1691.D
80000:
60000
40000
20000
[Time-
I 1
33 120
33.40
33 .60
#22
Chrysene-dl2
Concen: 3.13 ng/uL
RT: 33.34 min Scan# 3047
Delta R.T. 0.01 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:240 Resp: 204082
Ion Ratio Lower Upper
100
11.4 6.1 18.2
0.0 0.0 0.0
0.0 0.0 0.0
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
80000 J 33.45
60000
40000
20000
0
Time - - > 33.20
ENGTF9T7D PES4.M
#23
Chrysene(CCC)
Concen: 3.00 ng/uL
RT: 33.45 min Scan# 3064
Delta R.T. 0.01 min
Lab Pile: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:228 Resp: 245120
Ion Ratio Lower Upper
228 100
114 10.1 5.1 15.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
33 !40
33 .60
Wed OCt 20 11:47:10 1999
HP 5989B
!">S55
Page 13
-------
Abundance
60000 :
40000 -
20000
TIC: SNG1691.D
-j—j—n—i—i—I—i—I—i-!—! 11 \—i—r—j—r—t—f—i—i—r~
Time--> 38.90 39.00 39 ilO 39.20
Abundance Ion 264.00 (263.70 to 264.70): ENG
30000 -jion 132.00 (131.70 to 132.70): ENG
39 .11
20000
10000
J—-7 r r I J T~" ! 1—H
Time--> 38190 39.00 39.10
~1 1 1 1 J 1 r~
39.20
Abundance
60000
40000
20000
TIC: ENG1S91.D
#24
Benzo(b)fluoranthene-dl2
Concen: 3.01 ng/uL
RT: 39.11 min Scan# 3934
Delta R.T. 0.01 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:264 Resp:
Ion Ratio Lower
116525
Upper
264
100
132
13 .2
6.6
19.6
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#25
Benzo(b)fluoranthene
Concen: 2.97 ng/uL
RT: 39.26 min Scan# 3958
Delta R.T. 0.01 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:252 Resp: 164906
Ion Ratio Lower Upper
Time--> 39110 39120 39 i 30 39 !40
Abundance Ion 252.00 (251.70 to 252.70): ENG
252
100
126
11.9
5.9
17 .5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
40000
30000
20000
10000
Ion 126.00 (125.70 to 126.70): ENG
39.26
I 1 j 1 1 1 1 j 1 ! 1 1 1 1 I 1 I" I I 1 1 I I
[Time - - > 39.10 39.20 39.30 39.40
ENGTF9TTTJ—PE54.M Wed Oct 20 11:47:13 1999'
0003856
HP 5989B Page 14
-------
Abundance
60000
40000
20000
Time--> 39.00
Tic: fiHGl69l.D
39120
39 140
Abundance Ion 264.00 (263.70 to 264 . 70) : ENG
30000
20000
10000
Ion 132.00 (131.70 to 132.70); ENG
39.27
"I——¦? i—"—r~
Time- - > 39 .00
39.20
39.40
#26
Benzo(k) f luoranthene-dl2
Concen: 3.02 ng/uL
RT: 39.27 min Scan# 3959
Delta R.T. 0.01 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:264 Resp: 118125
Ion Ratio Lower Upper
264 100
132 13.2 6.8 20.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
60000
40000
20000
L JL D ? 39120
Abundance Ion 252 . 00
40000 "lIon 126 •00
30000
20000
10000
39140 39160
(251.70 to 252 .70): ENG
(125.70 to 126.70):
39.41
#27
Benzo (k) f luoranthene
Concen: 2.88 ng/uL
RT: 39.41 min Scan# 3980
Delta R.T. 0.00 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:252 Resp: 122311
Ion Ratio Lower Upper
252 100
126 13.3 6.4 19.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time-->
ENG1691.D
39.20 39.40 39.60
PES4.M Wed Oct 20 11:47:16 1999'
0e035f
HP 5989B
Page 15
-------
Abundance
TIC: BUG1691.D
20000 -
aA
10000 -
0 -
Time-->
! 1 !' " \ I " I 'i i t I 1 1 f i i |
41.20 41.40
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
41.33
10000 -
A
5000 -
/A
^^
0
Time - - >
1 i i 1 1 1 : t i ; i 1 i i 1
41.20 41.40
#28
Benzo(a)pyrene-dl2
Concen: 2.81 ng/uL
RT: 41.33 rain Scan# 4274
Delta R.T. 0.01 rain
Lab
File:
ENG1691
.D
Acq:
19 Oct
99 7 :
17 pm
Tgt
Ion:264
Resp:
55413
Ion
Ratio
Lower
Upper
264
100
132
14.2
0.1
0.1#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
I MU I m !¦ I I I ¦! II I II I I II
Abundance
20000
TIC: ENG1691.D
10000
0
41.40
Time-->41.20
Abundance Ion 252.00
¦lion 126.00
15000.
10000
41.60
(251.70 to 252.70); ENG
{125.70 to 126.70): ENG
41.50
#29
Benzo(a)pyrene(CCC)
Concen: 2.65 ng/uL
RT: 41.50 min Scan# 4301
Delta R.T. 0.01 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:252 Resp: 73824
Ion Ratio Lower Upper
252 100
126 12.4 0.1 0.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
5000
0CC5S53
Time-->41.20
ENG16 91.D—PES4.M
41140 41160
Wed Oct 20 11:47:20 1999'
HP 5989B
Page 16
-------
TIC: ENG1691.D
20000
10000
1 ! 1 ? I 1 1 1 1 j 1 ! 1 ! ! 1 1 1 1 J IT ! f
Time - -:61 60 51.80 52.00 52.20 52.40
in.,, — , ¦¦Tnr" T" JiK" WW"—tw w . bljljl ¦ i i milmju"
Abundance Ion 288.00 (287.70 to 288.70): ENG
10000 h
52 .08
#30
Indeno(l,2,3~cd)pyrene-dl2
Concen: 2.03 ng/uL
RT: 52.08 min Scan# 5961
Delta R.T. 0.01 min
Lab Pile: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion;288 Resp:
Ion Ratio Lower
60779
Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
5000
—j—,—,—|—,—,—j—,—j—r—,—,—,—.—T—^\ i" ; j i l
frime- -s51160 51.80 52100 52120 52140
Abundance
20000
TIC: EHSX691.D
10000 .
#31
Indeno(1,2,3-cd)pyrene
Concen: 2.40 ng/uL m
RT-. 52.36 min Scan# 6014
Delta R.T. 0.02 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:276.05 Resp: 69968
Ion Ratio Lower Upper
Time-
t—r~i—i—p~i—i—*—i—j—i—i—r
52100 52120 52.40 52.60
276
138
0
0
100
36 .9
0.0
0.0
0.1
0.0
0.0
0.1#
0.0
0.0
abundance Ion 276.OS (275.75 to 276.75): ENG
10000 lion 138 .00 (137.70 to 138 .70) : ENG
52 .36
5000 -
Time-
i—i—i—i—i—e
52.00
-i—r—|—i—i—i—i—|—j—i—i—f—r—i—i—?—r
52.20 52140 52160
ENG1691 ZD PES4 .
0003859
Wed Oct 20 11:47:23 1999
HP 5989B
Page 17
-------
: ENG1691,D
Abundance
20000 -
10000 -
Time--^1.60 51,80 52.00 52.20 52.40
snrr—1—jji "-•¦'•¦*«» a *—*-* / m jk a—wr*—ht—k'tk—wai w-kT/r
AbundanceIon 292.00 (291.70 to 292 .70) : ENG
52 .06
6000 -
4000 .
2000
Time--;£1 60 51.80 52.00 52.20 52.40
#32
Dibenz (a,h) anthracene-dl4
Concen: 1.99 ng/uL
RT; 52.06 rain Scan# 5957
Delta R.T. 0.03 min
Lab File: SNG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:292 Resp: 36595
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
20000
TIC: ENG1591.D
10000
#33
Dibenz (a, h) anthracene
Concen: 2.42 ng/uL
RT: 52.41 min Scan# 6022
Delta R.T. 0.02 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:278 Resp: 59745
~i—I—i—r
-i—i—!—r
i—i—i—r*
Time--> 52.00 52.20 52 .40 52.60 52 . 80
Abundance Ion 278.00 (277.70 to 278.70): ENG
-|Ion 139 oo (130.70 to 139 .70) : ENG
52 .41
5000
Ion
278
139
0
0
0
Time--> 52.00 52.20 52.40
i—!—r—t—i—r'T" i—i—r
52.60 52.80
ENG1691.D—PES4.M
wed Oct 20 11:47:26 1999
Rat xo
100
0.0
0.0
0.0
Lower Upper
0.1
0.0
0.0
0.1#
0.0
0.0
OCOjfStO
HP 5989B
Page 18
-------
TIC; ENGlfeyl.D
10000
5000
Time--> 54.60
~i 1 1 1 1 i r
54.80 55.00
55:20 "SSUO
Abundance Ion 288.00 (287.70 to 288.70): ENG
8000
6000
4000
2000
55.02
0
-1—1—t—r
Time--> 54.60
1—1—I—1—I—1—I—f—\—I—I—I—5—\—I—I—
54:80 55.00 55.20 55.40
Abundance
10000
TIC; ENG16S1.D
5000 _
Time--> 55:00 55:20 55:40 55:60
Abundance Ion 276.00 (275.70 to 276.70)
10000
#34
Benzo(g, h,i)perylene-dl2
Concen; 2.42 ng/uL
RT; 55.02 min Scan# 6568
Delta R.T, 0.03 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:288 Resp: 55970
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#35
Benzo(g,h,i)perylene
Concen: 2.40 ng/uL
RT: 55.34 min Scan# 6647
Delta R.T. 0.01 min
Lab File: ENG1691.D
Acq: 19 Oct 99 7:17 pm
Tgt Ion:276 Resp: 70427
Ion Ratio Lower Upper
276 100
138 0.0 0.1 0.1#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG
5000
Time-
ENG1691.D—PES4.M
(137.70 to 138
55.34
Ion 138
55.00 55.20 55:40 55.60
0GC3S*!
Wed Oct 20 11; 47": 29 IB93
HP 5989B
Page 19
-------
Evaluate Continuing Calibration Report
Data File
Acq On
Sample
Misc
C:\HPCHEM\1\DATA\ENG1672.D
16 Oct 99 12:08 am
CARB429,CCAL1.0,
Method
Title
Last Update
Response via
Min. RRP
Max. RRP Dev
Vial:
Operator:
Inst :
Multiplr:
12
HP 5989B
1.00
C;\HPCHEM\1\METH0DS\PES3.M
Mon Oct 18 16:44:02 1999
Multiple Level Calibration
0.000 Min. Rel. Area : 1%
30% Max. Rel. Area : 500%
ll-r^
Max. R.T. Dev O.SOmin
Compound
AvgRF
CCRF
%Dev Area%
Dev (mi]
1
2,2-Difluorobiphenyl
1.000
1.000
0.0
50
0.00
2
s
Naphthaiene-d8
2.828
2 ,490
12.0
46
0.00
3
Naphthalene(CCC)
3 .220
2.635
18.2*^
44
0.00
4
8
2-Methlynaphthalene-dlO
0 .982
0.984
-0.2
56
0.00
5
S
Acenaphthylene-d8
0.868
0 .949
-9.3
56
0 .00
6
Acenaphthylene
1.090
1.167
-7.1
56
0.00
7
s
Acenaphthene-dl0
0 .850
0.992
-16.6
64
0.00
8
Acenaphthene(CCC)
0.951
1.020
-7.3^
55
0.00
9
s
Fluorene-dlO
0.840
0.909
-8.2
55
0.00
10
Fluorene
0.988
1.010
-2.2
54
0.00
11
s
Phenanthrene-dl0
1.189
1.256
-5.6
55
0,00
12
Phenanthrene
1.497
1.503
-0.4
52
0.00
13
s
Anthracene-dlO
0 .575
0 .635
-10.4
55
0.00
14
Anthracene
0.917
1.099
-19 .'8
56
0.00
15
s
Fluorant hene-dl0
1.086
1.136
-4.6
51
0.00
16
Fluoranthene(CCC)
1.450
1.440
0 . 7U-"
50
0.00
17
s
Pyrene-dlO
1.212
1.263
-4.2
50
0.00
18
Pyrene
1.613
1.627
-0.9
50
0.00
19
s
p-Terphenyl-dl4
0 .974
0 .956
1.9
51
0.00
20
s
Benzo(a)anthracene-dl2
0 .449
0 .471
-4.8
48
0 .00
21
Benzo(a)anthracene
0.747
0.718
3.8
50
0.00
22
s
Chrysene~dl2
0.806
0.813
-0.9 ^
49
0.00
23
Chrysene(CCC)
1.076
1.023
4.9
48
0.00
24
s
Benzo(b)fluoranthene-dl2
0.497
0.489
1.6
50
0 .00
25
Benzo(b)fluoranthene
0.760
0.720
5.3
50
0.00
26
s
Benzo(k)fluoranthene-dl2
0.500
0.471
5.8
49
0.00
27
Benzo(k)fluoranthene
0.563
0.503
10 .6
46
0.00
28
s
Benzo(a)pyrene-dl2
0 .266
0.228
14.3
45
0.00
29
Benzo(a)pyrene(CCC)
0 .369
0.328
11.2W^ 46
0 .00
30
s
Indeno(1,2,3-cd)pyrene-dl2
0 .295
0.251
14 .7
42
0 .00
31
Indeno(1,2,3-cd)pyrene
0.372
0.319
14 .3
44
0.00
32
s
Dibenz(a, h)anthracene-dl4
0.181
0.158
12 .4
46
0.00
33
Dibenz(a,h)anthracene
0.321
0.295
8.0
50
0 .00
34
s
Benzo(g,h,i)perylene-dl2
0.312
0 .291
6.9
47
0.00
35
Benzo(g,h,i)perylene
0 .407
0.366
10 .1
46
0.00
1
0C(
W24
.cf
(#) = Out of Range
ENG1672.D PES3.M
SPCC's out = 0 CCC's out = 0
Mon Oct 18 16:45:28 1999 HP 5989B
Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\l\DATA\ENG1672.D
16 Oct 99 12:08 am
CARB429,CCAL1.0,
Oct 18 16:42 1999
Vial
Operator
Inst
Multiplr
12
HP 5 9 8 933
1.00
Method : C:\HPCHEM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:50:18 1999
Response via : Multiple Level Calibration
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-D i fluorobipheny1
19.99
190
387818
5.00 ng/uL
i i
O 1
O i
U> 1
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
17.68
136
193105
0.88 ng/uL
22.01%
4}
2-Methlynaphthalene-dlO
19 .36
152
76312
0.90 ng/uL
2.26%
5)
Aeenaphthylene-d8
21.62
160
73604
1.09 ng/uL
27.32%
7)
Acenaphthene-dlO
22 .03
164
76920
1.17 ng/uL
29.16%
9)
Fluorene-dlO
23 .30
176
70529
1.08 ng/uL
27.05%
11)
Phenanthrene-dl0
25.67
188
97404
1.06 ng/uL
26.40%
13)
Anthracene-dlO
25.81
188
49277
1.10 ng/uL
27.60%
15)
Fluoranthene-dl0
28.67
212
88130
1.05 ng/uL
26.16%
17)
Pyrene-dlO
29 .28
212
97998
1.04 ng/uL
26.05%
19)
p-Terphenyl-dl4
29.61
244
74154
0.98 ng/uL
2.45%
20)
Benzo{a)anthracene-dl2
33 .35
240
36533
1.05 ng/uL
26.21%
22)
Chrysene-dl2
33.48
240
63057
1.01 ng/uL
25.22%
24)
Benzo(b)fluoranthene-dl2
39.33
264
37926
0.98 ng/uL
24.59%
26)
Benzo(k)fluorant hene-dl2
39 .50
264
36562
0.94 ng/uL
23.55%
28)
Benzo(a)pyrene-dl2
41.58
264
17653
0.86 ng/uL
21.42%
30)
Indeno(1,2,3-cd)pyrene-di2
52 .47
288
19476
0.85 ng/uL
21.32%
32)
Dibenz(a,h)anthracene-dl4
52.45
292
12268
0.88 ng/uL
21.89%
34)
Benzo(g,h,i)perylene-dl2
55 .44
288
22547
0.93 ng/uL
23.27%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17.73
128
204385
0.82 ng/uL
99
6)
Acenaphthylene
21.65
152
90552
1.07 ng/uL
90
8)
Acenaphthene(CCC)
22.11
154
79147
1.07 ng/uL
99
10)
Fluorene
23 .37
166
78339
1.02 ng/uL
84
12)
Phenanthrene
25 .73
178
116614
1.00 ng/uL
99
14)
Anthracene
25.86
178
85222
1.20 ng/uL
97
16)
Fluoranthene(CCC)
28.72
202
111678
0.99 ng/uL
90
18)
Pyrene
29.32
202
126215
1.01 ng/uL
98
21)
Benzo(a)anthracene
33.44
228
55707
0.96 ng/uL
100
23)
Chrysene(CCC)
33.59
228
79345
0.95 ng/uL
90
25)
Benzo(b)Cluoranthene
39.49
252
55823
0.95 ng/uL
97
27)
Benzo(k)fluoranthene
39.64
252
38991
0.89 ng/uL
92
29)
Benzo(a)pyrene(CCC)
41.76
252
25411
0.89 ng/uL
95
31)
Indeno(1,2,3-cd)pyrene
52.76
276
24759
0.86 ng/uL#
31
33)
Dibenz(a, h)anthracene
52.80
278
22878
0.92 ng/uL#
48
35)
Benzo(g,h,i)perylene
55 .78
276
28362
0.90 ng/uL#
36
0003725
(#) » qualifier out of range (m) ¦ manual integration
ENG1672.D PES3.M Mon Oct 18 16:42:44 1999 HP 5989B Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C;\HPCHEM\1\DATA\ENG1672,D
16 Oct 99 12:08 am
CARB429,CCAL1.0,
Oct 18 16:42 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\MSTHODS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
12
HP 5989B
1.00
Abundance"
280000
260000.
240000.
220000 -
200000 .
180000.
160000,
140000
120000
100000
80000
60000
40000
20000
0
Time-->
2 s
8 " 12
lis
18
4s
Si
i
3"
1
w isjr
9S
2*§
2%%
-t 1 ! 1 1 1 1 1 r 1 ! 1—r
3ll
A-
T 1 1 ! 1 J * 1 r 1 1 ! 1 1 1 1 ! 1 1 1 T*
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0CCJ726
ENG1672.D PES3.M
Mon Oct 18 16:42:52 1999
HP 5989B Page 2
-------
TIC: KNG1672.D
100000
50000
Time-
-1 ! 1—]—f—I—I—I—I—1—E—!—S—|—T—! 1—1—|—!—I 1—l—n—f~
17.50 17.60 17.70 17.80
ir-H^Him III ¦!!! I ¦! II ¦ —— ——————————
Abundance Ion 136.00 (135.70 to 136.70) : ENG
Ion 68.00 (67.70 to 68.70): ENG16
100000 17.68
50000
0
Time--»
i—i—|—i—i—r—i—i—i—i—i—i—i—i—i—i—i—|—i—r
17.50 17.60 17.70 17.80
#2
Naphthalene-<18
Coneen: 0.88 ng/uL
RT: 17.68 min Scan# 250
Delta R.T, -0.04 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:136
Ion Ratio
136 100
68 15.9
0 0.0
0 0.0
Resp: 193105
Lower Upper
3.9 11.5#
0.0 0,0
0.0 0.0
Abundance
100000
TIC: SNG1672.D
50000
0
Time--> 17:60 1?!70 ' 17180 17.90
Abundance Ion 123.00 (127.70 to 128.70)
Ion 127.00 (126.70 to 127.70)
17 .73
100000
mi
ENG
50000
0
Time-->
ENG 16 72 .D—FES3 .M
—! [ 1 1 " "I'
17:60
-f—i—?—!—f—"i i—i—i—I- r-
17170 17 ! 80 17 ! 90
#3
Naphthalene(CCC)
Concen: 0.82 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.03 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:128 Resp: 204385
Ion Ratio Lower Upper
128
100
127
12 .8
0.0
62 .5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0003757
Hon Oct 18 lfc:42;56 1999
HP 5989B
Page 3
-------
Abundance
30000
20000
10000
1 1 j , 1 , , 1 1 , , ,
Time - - > 19 i 20 19.30 19.40
TIC: ENG1672.D
0
Abundance Ion 152.00 (151.70 to 152.70): ENG
40000
30000
20000
10000
19.36
j j 1 r—3 1 1 1 1 j 1 1 1 1 11 1,1 \
(Time--> 19120 19.30 19.40
#4
2-Meth.lynaph.thalene-dlO
Concen: 0.90 ng/uL m
RT: 19.36 min Scan# 756
Delta R.T. -2.32 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:152 Resp: 76312
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
60000
40000
20000
Time-
TIC: ENG1672.D
21.40
21.60
21.80
Abundance Ion ISO.00 (155.70 to 160.70): fiHG
40000
30000
20000
10000
0
21.62
Time--> 21.40
21.60
21.80
ENGT6T2TB—PES3.M
#5
Acenaphthy1ene-d8
Concen: 1.09 ng/uL
RT: 21.62 min Scan# 1296
Delta R.T. -0.03 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:160 Resp:
Ion
160
0
0
0
Ratio
100
0.0
0.0
0.0
Lower
0.0
0.0
0.0
Mon Oct 18 16:42:59 1999
73604
Upper
0.0
0.0
0.0
0003728
HP 5989B
Page 4
-------
Abundance
60000
40000
TIC: BNG1672.D
20000
Time--> 2l!40 2ll50 2ll60 21! 70~2ll 80'
Abundance Ion 152.00 (151.70 to 152.70):
Ion 153.00 (152.70 to 153.70):
21.65
40000
20000
#6
Acenaphthylene
Concen: 1.07 ng/uL
RT: 21.65 min Scan# 1300
Delta R.T. -0.03 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:152 Resp: 90552
Ion Ratio Lower Upper
152
100
153
12 .8
8.7
25 .9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
fTirae--> 21.40 21.50 21.60 21.70 21.80
Abundance
80000 -i
60000
TIC: ENG1S72.D
40000
20000
0
Time-
#7
Acenaphthene-dlO
Concen: 1.17 ng/uL m
RT: 22.03 min Scan# 1357
Delta R.T. -0.03 min
Lab File: ENG1672.D
Acq*. 16 Oct 99 12:08 am
Tgt Ion:164 Resp: 76920
Ion Ratio Lower Upper
164 100
22.00 22.05 22.10
II——W ^|W—f—¦?»» M ¦¦¦!—... m »
Abundance Ion 164.00 (163.70 to 164.70): ENG
40000
22.03
30000
20000
10000 J
Time - ->
ENG1572.D—PES3.M
"¦—I—r
22 .00
1——i r——i 1 1 .—
22 i 05 22.10
Mon Oct 18 16:43:01 1999'
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HP 5989B
3753
Page 5
-------
Abundance
TIC: SUGl$?2
.D
80000 -i
A
60000 -
\
40000 -
A / \
20000 :
J J V
0 J
Time-->
! » » » ) I j f 1
22.00 22.10
1 1 i
22.20
1 I
Abundance Ion 154.00 (153.70 to
154.70) :
ENG
Ion 153.00 (152.70 to
153 .70) :
ENG
40000:
22.11
30000
A
20000 -
/ \
10000 -
0
) V
Time - - >
1 ! 1 ] 1 ¦"!— "1— I—1 1
22.00 22.10
i i 1 | t
22 .20
T- T
#8
Acenaphthene(CCC)
Concen: 1.07 ng/uL
RT: 22.11 min Scan# 1368
Delta R.T. -0.04 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt ion:154 Resp: 79147
Ion Ratio Lower Upper
154
100
153
92 .0
45 .5
136 .3
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
80000
TIC: ENG1672.D
60000
40000
20000
Time - - >
^~23 120
i " i 1 1 r—! r—i—t—1 1—T-
23.30 23.40
#9
Fluorene-dlO
Concen: 1.08 ng/uL
RT: 23.30 min Scan# 1548
Delta R.T. -0.04 min
Lab File: 1NG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:176 Resp: 70529
Ion Ratio Lower Upper
100
0.0 0.0 0.0
0.0 0.0 0.0
0.0 0.0 0.0
Abundance Ion 176.00 (175.70 to 176.70): ENG
40000
30000
20000
10000
23 .30
o
Time-->
"-? ! 1 1 1 ! 1 1 1 [ ! 1 ! 1 1 1 T"~"T T"
23 .20 23.30 23.40
ENGT6T2TD PES3 .M
Mon Oct 18 16:43:04 1999
0003730
HP 5989B
Page 6
-------
Abundance
80000
60000
40000
20000
Time-
TIC: ENG167 2 . D
-1 1 1 1 r—] 1—
¦> 23.20 23130
23 .40
I r-~1 1 1 1
23 .50
(AbundanceIon 165.00 (165.70 to 166.70):
Ion 165.00 (164.70 to 165.70):
23.37
40000 "
20000
TSJ5"
ENG
23.20
23 .30
23 .40
23 .50
#10
Pluorene
Concen: l.02 ng/uL
RT: 23.37 min Scan# 1559
Delta R.T. -0.03 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:166 Resp: 78339
Ion Ratio Lower Upper
166 100
165 90.0 38.3 114.7
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
60000
40000
20000
TIC: ENG1672.D
Time--> 25.60 25.70 25.80
Abundance Ion 188.00 (187.70 to 188.70): ENG
60000-Ion
40000 j
94.00 (93.70 to 94.70]
25 .67
ENG 16
#11
Phenanthrene-dlO
Concen: 1.06 ng/uL
RT: 25.67 min Scan# 1909
Delta R.T. -0.04 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:188 Resp: 97404
Ion Ratio Lower Upper
188
100
94
22 .7
5.8
17.2#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
20000
*3
Time - ->
ENGI672.D
25.60 25.70 25.80
PES3 M Mon Oct 18 16 • 13 -07 1999'
J» «¦? < 11 I iWii V w V X W * TR * v f ^
HP 5989B
Page 7
-------
Abundance
TIC: SNG1672.D
60000
40000
20000
"T—i—I—s—j—i—i—i—r-
Tirae--> 25.65 25170 25175
AbundanceIon 178.00 {171.70 to 178.70): IMG
lion 176.00 {175.70 to 176.70): ENG
25.73
60000
1 1 I 1 1
25.80
40000
20000
Time-->
1—>—I—I—|—f—i—i—i—t—5—i—!—i—]—I—i—i—\—<—i—r
25.65 25.70 25.75 25180
Abundance
60000 :
40000
20000
TIC: ENG1672.D
n
~i—I—I—r
#12
Phenanthrene
Concen: 1.00 ng/uL
RT; 25.73 min Scan# 1918
Delta R.T. -0.03 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:178 Resp:
Ion Ratio Lower
116614
Upper
178
100
176
19.9
10.3
30 .8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Time-->25.60 25.70 25180 25 ! 90
Abundance Ion 188.00 (187.70 to 188.70): ENG
60000 -|Ion 94.00 (93.70 to 94.70): ENG16
40000
20000
#13
Anthracene-dlO
Concent 1.10 ng/uL
RT: 25.81 min Scan# 1930
Delta R.T. -0.04 min
Lab File: ENG1672.D
Acq:
16 Oct
99 12
: 08 am
Tgt
Ion:188
Resp:
49277
Ion
Ratio
Lower
Upper
188
100
94
25.2
6.6
19.6#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
25.81
0003722
—r j j Ti (—,—j—i—j1" i—j—r—i—i—!—r—i—i—r
fTime- -> 25160 25.70 25.80 25.90
ENG1672.D—PES3.M~
'Hon 0ct~18"16 :43 :10' 199'9
HP 5989B
Pd^€ 8
-------
TIC; BNG1672.D
60000
40000
20000
Time--> 25.70
25.80
25.90
26.00
Abundancelon 178.00 (177.70 to 178,70): ENG
Ion 176.00 {175.70 to 176.70): ENG
60000
40000
20000 -
25.86
mb < •"! r rf A
Txme--> 25.70
-i 1 1 r
25.80
-i 1 1 r
25.90
"r ""i ! r
26.00
#14
Anthracene
Concen: 1.20 ng/uL
RT: 25.86 min Scan# 1937
Delta R.T. ~0.04 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:178 Resp: 85222
Ion Ratio Lower Upper
178
100
176
19.1
8.9
26.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
60000 :
40000
20000
rime-
TIC: ENG16 7 2,D
28.50
~i—i—f—r—r—!—|—i—i—i—I—!—i—r-
28160 28.70 28.80
#15
Fluo rant hene-d10
Concen: 1.05 ng/uL
RT: 28.67 rain Scan# 2369
Delta R.T. -0.03 min
Lab Pile: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:212 Resp: 88130
Ion Ratio Lower Upper
212 100
106 27.0 8.0 23.8#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 212.00 (211.70 to 212.70): ENG'
Ion 106.00 (105.70 to 106.70): ENG
28 .67
40000
20000
Time-
28 .50
111 7 t "I r—! J f 1 J 1 t " I,"-l I i -"rif
28.60 28.70 28.80
ENG1572.D—PESJ.M
OCGj'?
Mon Oct 18 16:43:13 1999
HP 5989B
Page 9
-------
\bundance
60000 .
40000
20000
Time*
TiC: ENG1672.D
>28150' 28:60
28.70 28.80
-1 1 r
28.90
Abundance Ion 202.00 (201.70 to 202.70): ENG
lion 101.00 {100.70 to 101.70): ENG
28.72
60000
40000
20000
"i—s—i—i—i—!—r-~i—r—i—r-~i—i—i—t—i—i—i—i—r—i—r
fTime-->28! 50 28160 28.70 28.80 28.90
#16
Fluoranthene(CCC)
Concen: 0.99 ng/uL
RT; 28.72 min Scan# 2376
Delta R.T. -0.03 min
Lab File-. ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion: 202 Resp*. 111678
Ion Ratio Lower Upper
100
24.5 9.9 29.6
0.0 0.0 0.0
0.0 0.0 0.0
Abundance
TIC: ENG1672
.D
80000 :
60000 -
40000:
20000:
o:
Time-->29
('¦' t
.00
29.20
29 ! 40*
i t
Abundance Ion
212.00 (211.70 to
212 .70) :
ENG
Ion
106.00 (105.70 to
106.70):
ENG
29.28
40000 -
A
20000 -
0 -
Time-->29
.00
29.20
iii
29.40
PES3.M
#17
Pyrene-dlO
Concen: 1.04 ng/uL
RT: 29.28 min Scan# 2459
Delta R.T. -0.04 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:212 Resp: 97998
Ion Ratio Lower Upper
212 100
106 31.7 8.6 25.6#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0000755
HP 5989B
Page 10
-------
Abundance
80000
60000
40000
20000
Time-
ENG1672„D
r
29 ,20
1 1 J 1"" i"
29 .40
[AbundanceIon 202.00 (201.70 to 202.70): ENS"
Ion 101.00 (100.70 to 101.70) : ENG
60000 J 29.32
40000
20000 -
Time-->
29120
29140
#18
Pyrene
Concern 1.01 ng/uL
RT: 29.32 rain Scan# 2466
Delta R.T. -0.04 min
Lab File: ENG1672.D
Acq; 16 Oct 99 12:08 am
Tgt Ion:202 Resp: 126215
Ion Ratio Lower Upper
202
100
101
27.5
14 .3
42 .8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
60000
40000
20000
TIC: ENG1672.D
Time-
1 1 1 1 1 ! 1 ! 1 1 I ? 1 ! 1 r 1~
29.50 29.60 29.70
Abundance Ion 244.00 (243.70 to 244.70)
40000
30000
20000
10000
Ion 122.00 (121.70 to 122.70)
29.61
T
"ENG"
ENG
#19
p-Terphenyl-dl4
Coneen: 0.98 ng/uL
RT: 29.61 min Scan# 2509
Delta R.T. -0.04 min
Lab Pile: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:244 Resp: 74154
Ion Ratio Lower Upper
244 100
122 30.5 6.7 19.9#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Time-->
ENG1672.D
29.50 29.60 29.70
PES3.M Mon OCt 18 16:43:19 1999
HP 5989B
4s *\
Page 11
-------
Abu:
30000
20000
10000
0
Time-->
TIC: ENG1672.D
~i 1 r
33 .30
33 .40
-i 1 1 r
Abundance Ion 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
20000
10000 .
33 .35
rime-->
1 s 1 1 * r "T"—-n— x
33.30 33,40
#20
Benzo(a)anthracene-dl2
Concen: 1.05 ng/uL
RT: 33.35 min Scan# 3070
Delta R.T. -0.05 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:240
Ion Ratio
240 100
120 29.0
0 0.0
0 0.0
Resp: 36533
Lower Upper
7.3 21.8#
0.0 0.0
0.0 0.0
TIC: ENG1672
30000 -
20000:
ioooo :
0
Time-->
l \
33
.30 33.40 33
.50 33.60
Abundance Ion
228.00 (227.70 to
228.70): ENG
30000 -
Ion
114.00 (113.70 to
114.70): ENG
20000
33.44
10000
0 -
Time-->
33
.30 33.40 33
.50 33.60
#21
Benzo(a)anthracene
Concen: 0.96 ng/uL
RT: 33.44 min Scan# 3084
Delta R.T. -0.06 min
Lab File: ENG1672,D
Acq: 16 Oct 99 12:08 am
Tgt Ion:228 Resp: 55707
Ion Ratio Lower Upper
228
100
114
25.5
12.3
38.2
0
0.0
0.0
0.0
0
0.0
0.0
0.0
PES3.M
0003721
HP 5989B
©
Page 12
-------
TIC: ENG1672.D
30000
20000
10000
Time-
33,40
33 .60
"name'
30000
20000
10000
TIC: ENG1672.D
Time-->
AbundanceIon 228.00
i—i—i—|—i—i—i—r—j—i—i—r ~!—r
33!40 33.50 33.60
i—r-
33
33.70
(227.70 co 228.70):
#22
Chrysene-dl2
Concent 1.01 ng/uL
RT: 33.48 min Scan# 3090
Delta R.T. -0.06 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:240 Resp: 63057
Ion Ratio Lower Upper
Time--> 33!40 33 160
AbundanceIon 240.00 (239.70 to 240.70): ENG
Ion 120.00 (119.70 to 120.70): ENG
33 .48
20000 J
10000 -
240
100
120
24.8
6.4
19.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#23
Chrysene(CCC)
Coneen: 0.95 ng/uL
RT: 33.59 min Scan# 3107
Delta R.T. -0.06 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:228 Resp: 79345
Ion Ratio Lower Upper
80
~EKfO~
228
100
114
22.3
9.1
27 .1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
30000
20000
10000
Ion 114.00
(113.70 to 114
33 .59
70): ENG
I \ | ! ? i ! j I \
Time- -> 33.40 33.50
ENGX5T2TD—PES3.M
-!—t—! i r i" ?-{ \—i—m—I t'-t
33160 33.70 33.80
Mon Oct 18 16:43:25 1999
HP 5989B
J*1"# "¦»
iff!
Page 13
-------
Abundance
30000
20000
10000
TIC: BNG1672.D
#24
Benzo(b)fluoranthene-dl2
Coneen: 0.98 ng/uL m
RT: 39.33 min Scan# 3988
Delta R.T. -0.X0 min
Lab File-. ENG1672 .D
Acq: 16 Oct 99 12:08 am
Tgt Ion:264 Resp*.
Ion Ratio Lower
37926
Upper
-i ] 1 —;r —i s 1 i r—r—r—i 1 1—r-
39.20 39.30 39140
Time-->
Abundance Ion 264.00 (262.70 to 254.70); ENG
lion 132.00 (131.70 to 132.70): ENG
10000 _| 39.33
5000
264
100
132
68 .4
8.0
23 .9#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
f t ]
Time-
39 .20
39.30
39 .40
TIC: SNG1672.D
Abundance
30000
20000
10000
T t 1 \ | 1' '"I 1 J \ I I 1
Time--> 39.30 39140 39.50 39.60
Abundance Ion 2 52.00 (251.70 to 252.70): ENG
lion 126.00 (125.70 to 126.70): ENG
15000
10000
5000
39 .49
#25
Benzo(b)fluoranthene
Concen: 0.95 ng/uL
RT: 39.49 min Scan# 4013
Delta R.T. -0,10 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:252 Resp: 55823
ion Ratio Lower Upper
252
100
126
28 .1
13 .4
40.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
^38
Time-->
ENG1672 7D
39130 39140 3915" 39160
PES'3""1"M Mon Oct'18 16:43:28 1999'
HP 5989B
Page 14
-------
TIC: ENG1672.D
30000
20000
10000 J
Time-->39.20
39.40
39.60
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
39.50
10000
5000 -
Time-->39.20
39.40
39.60
#26
Benzo(k)fluoranthene-dl2
Concen: 0.94 ng/uL
RT: 39.50 rain Scan# 4015
Delta R.T. -0.09 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:264
Ion Ratio
264 100
132 31.9
0 0.0
0 0.0
Resp: 36562
Lower Upper
8.5 25.3#
0.0 0.0
0.0 0.0
Abundance
30000
20000 :
10000
TIC: ENG1672.D
#27
Benzo(k)fluoranthene
Concen: 0.89 ng/uL
RT: 39.64 min Scan# 4036
Delta R.T. -0.09 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:252 Resp: 38991
Ion Ratio Lower Upper
"T~—| 1 i—* ?—| \ 1 i 1 1—p 1—! ! r—i r
39!50 39.60 39.70 39.80
Time-* — >
Abundance Ion 252.00 (251.70 to 252.70); ENG
Ion 126.00 (125.70 to 126.70): ENG
252
100
29.9
13 .0
38 .8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
15000
10000
5000
39.64
Time-->
ENG1672.D—PES3.M
t J—r—|—i—i—j—r—|—i—t i 1 r 1 r r 1 r"-i i ¦ "-j ¦ i 1 "i
39.50 39.60 39.70 39.80
0C03739
Hon Oct 18 16:43:30 1999
HP 5989B
Page 15
-------
Abundance
15000
10000:
5000
Time-->
TIC: ENG1672.D
41.40
41.60
41.80
Abundance Ion 264.00 (263.70 to 264.70): 2NG
00 "'Ion 132.00 (131.70 to 132.70); ENG
41.58
4000 -
2000
Time-
41.40
i 1 i r ¦—i ! t r
41.60 41.80
#28
Benzo(a)pyrene-dl2
Concen: 0.86 ng/uL
RT; 41.58 min Scan# 4333
Delta R.T. -0.11 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:264
Ion Ratio
264 100
132 34.3
0 0.0
0 0.0
Resp: 17653
Lower Upper
8.7 25.9#
0.0 0.0
0.0 0.0
Abundance
15000
10000
5000
t— r 1 | r 1 1 1 1 1 1 1 t ! ! r
Tirne--> 41.60 41.80 42.00
mr
TIC: ENG1672.D
#29
Benzo(a)pyrene(CCC)
Concen: 0.89 ng/uL
RT: 41.76 min Scan# 4361
Delta R.T. -0.11 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:252 Resp: 25411
Ion Ratio Lower upper
252
100
126
29 .3
13 .4
40.1
0
0.0
0.0
0.0
0
0.0
0.0
0.0
AbundanceIon 252.00 (251.70 to 252.70)
8000
6000
4000
2000
Ion 126.00
: 125.70 to 126.70) : 1NG
41.76
Time-->
—T P ! ! T"
41.60
—i j 1 1 1 1 j j r
41.80 42.00
ocomo
Mon Oct 18 16:43:33 1999
HP 5 9 8 9 B
Page 16
-------
TIC: ENGlfi72.t>
15000:
10000:
5000:
Time--> 52.20 52,40
Abundance Ion 288.00 (287.70 to 288.70): ENG
52 .60
52.47
4000 _
2000 -
Time--> 52.20
52,40
52160
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 0.85 ng/uL m
RT: 52.47 rain Scan# 6013
Delta R.T. -0.19 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:288 Resp: 19476
Ion Ratio Lower Upper
288 100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0,0
0.0
Abundance
15000
10000
5000
TIC: ENG1672.D
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.86 ng/uL
RT: 52.76 min Scan# 6066
Delta R.T. -0.19 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion*.276.05 Resp:
24759
Ion Ratxo Lower Upper
Time--> 52140 ' ' 52.60 52 180
Abundance Ion 276.05 {275.75 to 276.75): ENG
_T J j p.
53.00
276
138
0
0
100
0.0
0.0
0.0
22 .8
0.0
0.0
68.2#
0.0
0.0
4000
2000
0
Ion 138.00 (137.70 to 138.70}
52 .76
ENG
0C03741
— wmm
Time~~> 52.40
52.60
52.80
53 .00
ENGT5T27B FES3.M
"Mon Oct 18 16:43736 199?
HP 5989B
Page 17
-------
Abundance
15000
Time - - >
TIC: ENGlb72. D
10000 -
5000
52 .20
"i i [ j 1 1 1 j r—i < - "T"
52.40 52.60
Abundance Ion 292.00 (291.70 to 292.70): ENG
4000
3000
2000
52.45
52 .40
52.60
Time--> 52.20
1000 :
#32
Dibenz (a, h) anthracene-d!4
Concen: 0.88 ng/uL m
RT: 52.45 min Scan# 6008
Delta R.T. -0.18 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:292 Resp: 12268
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
5000
0 —|—,—|—|—|—|—|—,—|—,—i—i—,—i—|—i—i—i—j-
frime-->52.40 52;60 52180 53.00
TIC: ENG1672.D
15000
10000
#33
Dibenz (a, li) anthracene
Concen: 0.92 ng/uL
RT: 52.80 min Scan# 6073
Delta R.T. -0.19 min
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:278 Resp: 22878
Ion Ratio Lower Upper
278
100
139
0.0
13.7
41.0#
0
0.0
0.0
0.0
0
0.0
0.0
0.0
[AbundanceIon 278.00 (277.70 to 278.70)
Ion 139.00 (138.70 to 139.70)
52.80
4000
2000
0-
¦BSRT
ENG
Time-->52.40
•IS-JSTCpSi!
52.60
52 1 80
—r—|—f—f—t t
53.00
Ju Kjfi
Mon Oct 18 16:43:39 1999
HP 5989B
Page 18
-------
TIC: ENG1S72.D
Abundance
10000 ^
5000 -
AbundanceIon 288.00 (287.70 to 288.75): ENG
55 .44
4000 -
2000 .
#34
Benzo(g,h,i)perylene-dl2
Concen: 0.93 ng/uL m
RT: 55.44 min Scan# 6572
Delta R.T. -0,22 itiin
Lab File: ENG1672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:288 Resp: 22547
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1672,D
5000
#35
Benzo(g,h,i)perylene
Concen: 0.90 ng/uL
RT: 55.78 min Scan# 6656
Delta R.T. -0.21 min
Lab Pile: ENGl672.D
Acq: 16 Oct 99 12:08 am
Tgt Ion:276 Resp:
28362
Time--> 55.40 55.60 55.80
56.00
Ratio
100
0.0
0.0
0.0
Lower Upper
15.9
0.0
0.0
63 .4#
0.0
0.0
Abundance Ion 276.00 (275.70 to 276.70): ENG
lion 138.00 (137.70 to 138.70): ENG
55 . 78
4000
2000
—I—i —i—r~-|—i—i—i i—( i 11 r i i i
Time--> 55.40 55.60 55.80 56.00
ENGX5T2TD—FESXTPT
x-O
"Mon Oct IS 16:43:43 1999
HP 5989B
Page 19
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\HPCHEM\1\DATA\ENG1673.D
16 Oct 99 1:14 am
CARB429,M.B
Oct 19 10:03 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METH0DS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
fio
Vial: 13
Operator:
Inst
Multiplr: 1.00
if'*
HP 5989B
Internal Standards
jR T
Qlon
Response
Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.99
190
372353
5
.00
ng/uL
1
1
0 1
0 >
0 1
System Monitoring Compounds
%Recovery
l2)
Naphthalene-d8
17.68
136
575974
2
.73
ng/uL
68.37%
T4)
2-Methlynaphthalene-dlO
0.00
152
0
0
00
ng/uL
0.00%
5)
Acenaphthylene-d8
21.62
160
307663
4
76
ng/uL
118.95%
7)
Ac enaphthene-dl0
22.03
164
252185
3
98
ng/uL
99.57%
9)
Fluorene-dlO
23.30
176
245523
3
92
ng/uL
98.09%
11)
Phenanthrene-dl0
25.67
188
336622
3
80
ng/uL
95.03%
13}
Anthracene-dlO
25.81
188
240052
5
60
ng/uL
140.05%
15)
Fluoranthene-dl0
28.67
212
326965
4
04
ng/uL
101.08%
,}7)
Fyrene-dlO
29 .28
212
378335
4
19
ng/uL
104 .75%
fl9)
p-Terphenyl-dl4
0.00
244
0
0
00
ng/uL
0.00%
20)
Benzo(a)anthracene-dl2
33 .34
240
182117
5
44
ng/uL
136.08%
22)
Chrysene-d12
33 .49
240
247188
4
12
ng/uL
102.99%
24)
Benzo(b)fluoranthene-dl2
39.33
264
183547
4
.96
ng/uL
123.95%
26)
Benzo(k)fluoranthene-dl2
¦ 39.50
264
183565
4
.93
ng/uL
123.13%
28)
Benzo(a)pyrene-dl2
41.58
264
92019
4
.65
ng/uL
116.27%
30)
Indeno(1,2,3-cd)pyrene-dl2
52 .50
288
104793
4
.78
ng/uL
119.45%
32)
Dibenz(a,h)anthracene-dl4
52.46
292
63958
4
.75
ng/uL
118.87%
34)
Benzo(g,h,i)perylene-dl2
55.46
288
102826
4
.42
ng/uL
110.52%
Target Compounds
Qvalue
3}
Naphthalene(CCC)
0.00
128
Not
Detected
6)
Acenaphthylene
0.00
152
Not
Detected
8)
Acenaphthene(CCC)
0.00
154
Not
Detected
10)
Fluorene
0 .00
166
Not
Detected
12)
Phenanthrene
0.00
178
Not
Detected
14)
Anthracene
0.00
178
Not
Detected
16)
Fluoranthene(CCC)
0 .00
202
Not
Detected
18)
Pyrene
0.00
202
Not
Detected
21)
Benzo(a)anthracene
0.00
228
Not
Detected
23)
Chrysene(CCC)
0 .00
228
Not
Detected
25)
Benzo(b)fluoranthene
0.00
252
Not
Detected
27)
Benzo(k)fluoranthene
0.00
252
Not
Detected
29)
Benzo(a)pyrene(CCC)
0.00
252
Not
Detected
31)
Indeno{1,2,3-cd)pyrene
0,00
276
Not
Detected
33)
Dibenz(a,h)anthracene
0.00
278
Not
Detected
35)
Benzo(g,h,i)perylene
0 .00
276
Not
Detected
OOOlOtki)
(#) = qualifier out of range (m) = manual integration
ENG1673.D PES3.M Tue Oct 19 10:04:36 1999 HP 5989B
Page l
-------
Quantitation Report
C:\HPCHEM\l\DATA\ENG1673.D
16 Oct 99 1:14 am
CARB429,M.B
Data File
Acq On
Sample
Misc
Quant Time; Oct 19 10:03 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METH0DS\PES 3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial: 13
Operator:
Inst : HP S989B
Multiplr; 1.00
Abundance
350000
300000
250000
200000
150000 .
100000
50000
TIC: ENG1673.D
lis
5s Us
17s
15$
*'s
9s
22S
20s
-JL
28s
30s
34s
-nL_
Time-->
-1 r 1 j ! ! 1 1 ] J i 1 1 j 1 1 1 1 1 1 1 r—! [ -1 E 1 1 1 ! 1 1 1 J ! 1 J 1 j ! T
20.00 25.00 30100 35.00 40.00 45.00 50.00 55.00
ENG1673.D PES3.M
Tue Oct 19 10:04:42 1999
000.1066
HP 5989B Page 2
-------
[Abundance
300000 "
200000
100000
Tirae-
TIC: ENG1673.D
17.40
17.60
17.80
Abundance Ion 136.00 (135.70 to 136.70): ENG
300000
Ion 68.00
(67.70 to 68.70)
17.68
ENG 16
A
200000 -
100000
0 -
Time--> 17.40 17160
-i [ ; 1 1 r
17.80
Abundance
300000
200000
100000
Time-
Abun
2000 -
1000
A.
#2
Naphthalene-d8
Concen: 2.73 ng/uL
RT; 17.68 min Scan# 250
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq; 16 Oct 99 1:14 am
Tgt Ion:136 Resp: 575974
Ion Ratio Lower Upper
136 100
68 16.4 7.7 23.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1673.D
•516:50 *1*7 100 *17 150 IS i OO" 18! 50
eIon 128.00 (127.70 to 128.70): ENG
Ion 127.00 (126.70 to 127.70)
#3
Naphthalene(CCC)
Concen: 0.00 ng/uL
Expected RT: 17.74 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 128
Exp Ratio
100
13 .0
0.0
0.0
Time--2I6.50 17.00 17.50 18.00 18.50
ENGT5TJ7D—PKSJ.M Tue Oct 19 10:04:46 1999'
0G0.L067
HP 5989B Page 3
-------
Abundance
200000
150000
100000
50000
TIC: ENG1673.D
0
T" -I — j I I
Time--> 18^50 19^00 19 !50 20100
Abundance Ton 152.00 (151.70 to 152.70): ENG
2000 ^
1000
0
i" i "i i—i "I 'i i
Time-->
18.50 19100 19.50 20.00
abundance
150000
100000
50000 .
0
TIC: BNG1673 .D
150000
100000
50000
21.62
Time-
U"1 1 1 I
21.40
21,60
21180
#4
2-Methlynaphthalene-dlO
Concen: 0.00 ng/uL
Expected RT: 19.37 rain
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
Time-~> 21.40 21.60 21.80
Abundance Ion 160.00 (i5$.?0 to 160.70): ENG
#5
Acenaphthylene-d8
Concen: 4.76 ng/uL
RT: 21.62 min Scan# 1297
Delta R.T. -0.01 rain
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:160 Resp: 307663
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG1673.D—PES3.M
•rue oct ly io:U4:4y iyyy
OCO.LOSS
HP 5989B Page 4
-------
Abundance
150000
100000
50000
0
TIC: ENG1673.D
1 i"! 1
21:00
'11" •
21:50
t—1—r—t—1—1—r~H—!—i—1—r
22.00 22:50
Time--> 20.50
Abundance Ion 152.00 (151.70 to 152.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
2000
1000
0
-1—1—j—r
Time--> 20.50 21.00 21.50" 22.00 22.50
TIC: BNG1673.D
Abundance
100000 .
50000
0
Time-->
Abundance Ion 164.00 {163.70 to 164.70)
2i:95 22:00 22,05 22.10
100000
50000
22.03
r—1—!—1—pn—t—s—II"1?"1 1—; 1 v- 1—t r 'i1 1 » • 1—1—1—r
Time--> 2i:95 22.00 22.05 22110
ENG1673 .D—FES3TM
#6
Acenaphthylene
Concen: 0.00 ng/uL
Expected RT: 21.66 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 152
Ion Exp Ratio
152 100
153 13.0
0 0.0
0 0.0
#7
Acenaphthene-dl0
Concern 3.98 ng/uL
RT: 22.03 rain Scan# 1359
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:164 Resp: 252185
Ion Ratio Lower Upper
164 100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
>01359
HP 5989B
Page 5
-------
Abundance
150000
100000
50000
0
TIC: ENG1673.D
L
i t
1—i—i—i—i—t—i—i—i—i—•—»—i—i—i—I—i—i—i—i—i—i—r*
Time--> 21.00 21.50 22.00 22.50 23.00
Abundance Ion 154.00 (153.70 to 154.70): ENG
3000 jlon 153.00 (152.70 to 153.70): ING
2000
1000
Time-
21.00 21.50
22 !00
22.50
-j—i I r
23 .00
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 22.12 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 154
Ion Exp Ratio
154 100
153 98.0
0 0.0
0 0.0
TTcTEBmeTJTD
100000
50000
#9
Fluorene-dlO
Concen: 3.92 ng/uL
RT: 23.30 min Scan# 1551
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:176 Resp: 245523
Ion Ratio Lower Upper
176 100
~i—5 ! 1 1 1 1 1 1 J ! 1 J r—! 1 1—r
Time--> 23110 23.20 23.30 23.40 23150
abundance 1 on 176.00 (l?5.?0 to 176.70): 2NS
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
23 .30
100000
50000
T-~i—f—t—r
23.10
Time-->
ENG1573.D—PES3.M
1—1—1—1—r
23.20
t—s—|—r r -1—1—I—j "i- r ¦ t |—r-r-
23.30 23140 23150
*% K
Tue Oct 19 10:04:55 1999
HP 5989B
j 'if
Page 6
-------
TIC: ENG1S73.D
100000
50000
Time - - >
i—i—!—f—j—i i »—r—j—i—r~n
22!50 23100 23.50 24.00
Abundance I011 1S6.OO (155.70 to 166.70): EKfG
3000"Ion 165.00 (164.70 to 165.70): ENG
2000
1000 .
Time-
i—1—|—t—1—r—1—1—1—i—1—r—|—1—i—1—1—1—1—r
22.50 23.00 23150 24.00
Abundance
200000
150000
100000
50000
0
TIC: ENG1S73.D
—i j j r
25.60
n 1 1 1 ? 1 1 1 r-
25.70 25.80
rime-->
ENG'l673 .D—PKS3.M
"H 1 ! 1 '| t ? r I 1 T
25:60 25.70 25.80
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 23.38 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion*. 166
Ion Exp Ratio
166 100
165 91.3
0 0.0
0 0.0
#11'
Phenanthrene-dl0
Concen: 3.80 ng/uL
RT: 25.67 min Scan# 1910
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion*. 188 Resp: 336622
Ion Ratio Lower Upper
Time-
AbundanceIon 188.00 (187.70 to 188.75): ENS
"Ion 94.00 (93.70 to 94.70): ENG16
25.67
150000
100000
50000
0
188
100
94
23.4
12 .3
36.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
m 14v?i
-
Tue Oct 19 10:04:58 1999
HP 5989B
Page 7
-------
Abundance
200000 J
150000
100000
50000
i—*—i—i—j—i—i—i—i—j—i—i—i—i—|—i—s—i—i—p-r
rime--524.50 25.00 25.50 26.00 26.50
TIC: ENG1673.D
Abundance Ion 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
3000 J
2000
1000
j i—i—*—r~-i—|—i—i—\—i—i—r-~!—i—i—r—i—i—i—i—j—i—i—r
[Time-->24.50 25.00 25150 26.00 26.50
Abundance
200000
150000
100000
50000
t 1 1 r
Time--> 25.60
25.80
26.00
150000:
100000
50000
25.81
Time-->
25.60
25l80
26.00
#12
Phenanthrene
Concen: 0.00 ng/uL
Expected RT: 25.74 min
Lab Pile; ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.2
0 0.0
0 0.0
TIC: EMG1673.D
#13
Anthracene-dlO
Concen: 5.60 ng/uL
RT: 25.81 min Scan# 1931
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:188 Resp: 240052
Ion Ratio
188 100
94 26.2
0 0.0
0 0.0
Lower Upper
13 .4
0.0
0.0
40.0
0.0
0.0
AbundanceIon 188.00 (187.70 to 186.70): iWG
"Ion 94.00 (93.70 to 94.70): ENG16
ENG1673.D—PES3.M
000.1072
Tue Oct 19 10:05:01 1999
HP 5989B
Page 8
-------
Abundance
200000
150000
100000
50000
0
Time-->
TIC: ENG1673.D
25 .00
-i—r
25 i 50 26 I 00
26.50
Abundance Ion 178.00 1177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
3000 '
2000
1000
~i—i—i—r
~T—i 1—r~
-! ! 1 T"
Time-
25.00 25.50 26.00 26.50
Abundance
200000
Time-
28.40
28 .60
28.80
#14
Anthracene
Coneen: 0.00 ng/uL
Expected RT: 25.87 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 178
Ion Exp Ratio
178 100
176 19.9
0 0.0
0 0.0
TIC: ENG1673-D
150000
100000
50000
#15
Fluoranthene-dlO
Concen: 4.04 ng/uL
RT: 28.67 min Scan# 2370
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:212 Resp: 326965
Ion
212
106
0
0
Ratio
10 0
27.4
0.0
0.0
Lower Upper
13.7
0.0
0.0
41.0
0.0
0.0
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
28 . 67
150000
! 100000
50000
0
r . !.'u i 'U
Time-~>
ENG1673.D
28.40
PSS3 . M
28.60 28.80
Tue Oct 19 10:05:05 1999"
HP 5989B
Page 9
-------
Abundance
200000
150000
100000
50000
TIC: ENG1673.D
L
Time-->27:50 28 .oo' *28 1 SO' 29 100
Abundance Ion 202,00 (201.70 to 202.70)
29: sro~r"
4000
3000
2000
1000
0
Ion 101.00 {100.70 to 101.70)
Time-
¦>27l5o' 28 1 0 0
28,50 29.00
"i—i—|—j—r
29 .50
"^T
ENG
#16
Fluoranthene(CCC)
Concen-. 0.00 ng/uL
Expected RT: 28.73 min
Lab File:
Acq: 16 Oct
ENG1673.D
99 1:14 am
Tgt Ion;
Ion
202
101
0
0
202
Exp Ratio
100
24.0
0.0
0.0
Abundanc e
•4
200000 4
150000
100000
50000
TIC: fiNGl6?3.£>
0
Time - - >
29100
29! 20
29140
Abundance Ion 2l2.00 (211.70 to 2l2.70)
200000
150000
100000
50000
lion 106.00 (105.70 to 106.70)
29.28
-mr
SNG
Time-->
ENG1673.D
29.00
PES' 3 . M
29.20 29140
Tue Oct 19 10:05:08 1999'
#17
Pyrene-dlO
Concen: 4.19 ng/uL
RT: 29.28 rain Scan# 2461
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:212 Resp*. 378335
Ion Ratio Lower Upper
212 100
106 30.9 15.9 47.5
0 0.0 0.0 0.0
0 0.0 0.0 0.0
000.137'
HP 5989B
Page 10
-------
Abundance
200000
150000:
TIC: EMG1S73.D
50000
100000
-r1 T"f ! f 1 f 1 f 1 ! !—1 1 I I 1 ! 1 3 1 r-T-
28.50 29.00 29.50 30100
Abundance Ion 202.0o (201.70 to 202.70)-. ENG
4000 JIon 101•00 t100-70 to 101.70): ENG
3000
2000
1000
[Ti
irae-
28.50 29.00 29.50 30.00
Sundance
200000:
150000
100000
50000
0
TIC: ENG1673.D
L
Time --> 28 150
Abundance Ion 244 .00
1 'i ! 1
29.00
29 . 50
yQ"1
30 .00
T5¥
-t—i—|—i—i—r-
30.50
2000
1000
0
Time--> 28.50 29.00
I i r-
29.50
3 0.00 3 0.50
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 29.34 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.6
0 0.0
0 0.0
#19
p-Terphenvl-dl4
Concen: 0.00 ng/uL
Expected RT: 29.62 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 244
Ion
244
122
0
0
Exp Ratio
100
29.1
0.0
0.0
"ISO"
(243.70 to 244.70)
3000 JIon 122.00 (121.70 to 122.70): ENG
,*% r
ENGl b 7 3 . D—PKisi .M
i*ue uct iy iO:Ob:ii'lyyy
HP 5989B
¦ *- O » 'tj}
Page 11
-------
Sundance
100000
0
time - - > 33:20
50000
EMG1673.D
-1 [ r
33.30
33 .40
Abundance Ion 240.00 (239.70 to 240.70]
Ion 120.00 (119.70 to 120.70]
80000
60000
40000
20000 -
HT
ENG
33.34
Time--> 33.20
33.30
33 .40
Abundance
100000
TIC: SNS1673.D
50000
0
-1—|—1—i—r—r
-1—1—1—1—1—r
Time-->
32 . 50 33.00 33 . 50 34.00
AbundanceIon 228.00 (227.70 to 228.70)
lion 114.00 (113.70 to 114.70)
10000
#20
Benzo(a)anthracene-dl2
Concen: 5.44 ng/uL
RT: 33.34 min Scan# 3071
Delta R.T. -0.02 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:240 Resp: 182117
Ion Ratio Lower Upper
240 100
120 29.8 14.0 41.9
0 0.0 0.0 0.0
0 0.0 0.0 0.0
5000
0
ENG
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 33.46 rain
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.4
0 0.0
0 0.0
Time - - >
"1—1—1—r
ft r,
-------
Abundance
100000
Time - - >3 3 .20
TIC: ENG1673.D
50000
0
t ] <~
33 .40
33 .60
Abundance Ion 240.00 (239.70 to 240.70): ENG
80000
60000
40000 .
20000
lOll 120.00 (119.70 to 120.70): ENG
33 .49
Time-->33.20
Abundance
100000 -i
33 .40
33 160
TIC: SJGlim.D
50000
0
5000
0
#22
Chrysene-dl2
Coneen: 4.12 ng/uL
RT: 33.49 min Scan# 3093
Delta R.T. -0.01 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:240 Resp: 247188
Ion Ratio
240 100
120 24.9
0 0.0
0 0.0
Lower Upper
13.7
0.0
0.0
41.0
0.0
0.0
~T—I—1 1 r~l ! I 1 1 1 !~—f 1 ! I 1 f ! T^T T
Time-->32150 33!00 33150 34.00 34150
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
10000
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.61 min
Lab Pile: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 228
Ion Exp Ratio
228 100
114 22.3
0 0.0
0 0.0
—i—i—i—i—f—i—i—i—s—{—i—i—I i i—ill —|—i—i—j—r
Time- ->3215.0 33.00 33.50 34.00 34.50
ENG l h 7 3 . U FEST7RT
Tue OCt 19 10:05:17 1333
HP 5989B
i c-
Page 13
-------
Abundance
60000
Tic: ENG1S73.D
40000
20000
39.20
39 .30
39.40
Time-
AbundanceIon 264.00 (253.70 to 264.70): EIKT
lion 132.00 (131.70 to 132.70): ENG
40000
30000
20000
10000
Time-->
39 .33
39.20 39.30
39.40
#24
Benzo(b)fluoranthene-dl2
Concen: 4.96 ng/uL m
RT: 39.33 min Scan# 3990
Delta R.T. -0.03 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:264
Ion Ratio
264 100
132 41.0
0 0.0
0 0.0
Resp: 183547
Lower Upper
Xrir^
34.8 104.2
0.0 0.0
0.0 0.0
Abundance
60000
TIC: ENG1673.D
40000
20000
40.00
38.50
iii
39.50
39.00
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.52 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 252
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
3000
2000
1000
0
-s ' t > \ i' "ii
> *l i' * ' *' ''»
"'' 1 1 1 '1
Time - - >
38.50 39.00 39.50 40.00
BNG1673-D PES3.M
Tue Oct 19 10:05:21 1999
Exp Ratio
100
27.8
0.0
0.0
000.1073
HP 5989B
Page 14
-------
Abundance
60000
40000
TIC: ENG1673.D
20000
Time--> 39.20 39.40 39:60
abundance Ion 264.00 (263.70 to 264.70)
Ion 132.00 (131.70 to 132.70}
40000 1 39.50
39.00 39.50 40.00 40.50
#26
Benzo(k)fluoranthene-dl2
Concen: 4.93 ng/uL
RT: 39.50 min Scan# 4017
Delta R.T. -0.03 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:264 Resp: 183565
Ion Ratio Lower Upper
264
100
132
34 .2
18 .0
53 .8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
EMT
ENG
30000
20000
10000
[ 1
39.40
3 9.60
>39.20
TIC: ENG1673.D
Abundance
60000
40000
20000
Time - ->
Abundance Ion 252.00 (251.70 to 252.70): £N<3
Ion 126.00 (125.70 to 126.70): ENG
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.67 min
Lab Pile: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 252
Exp Ratio
100
27 . 6
0.0
0.0
3000:
2000
1000
Time-~>
ENG1673.D
i 1 1 1 1 1 I 1 T I " I I I I I I
39.00 39.50 40.00
"FE53TW
40.50
Tue Oct 19 10:05:24 1999
HP 5989B
L's; t v» 4'
Page 15
-------
Abundance
30000
20000 .
10000
Time-
T1C: 1MG1673.D
-> 4i;2o~r
41.40
41.60 41.80
AbundanceIon 264.00 (263.70 to 264.70): ENG
20000
15000
10000
5000
lion 132.00 (131.70 to 132.70): ENG
41.58
I 1—i—j—i—|—i—i—i—i—j—i—i—i—r—?—t—r—e—r*
ime--> 41.20 41.40 41.60 41.80
Abundance
30000 .
20000
TIC; 8WG1S73.D
10000
0
Time--> 41100 42100 r 43100
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
3000
2000
1000
Time - - >
ENGX5TJTTT
T
-i j r-
43.00
#28
Benzo(a)pyrene-dl2
Concen: 4.65 ng/uL
RT: 41.58 min Scan# 4335
Delta R.T. -0.03 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:264 Resp: 92019
Ion
264
132
0
0
Ratio
100
32 .7
0.0
0.0
Lower Upper
19.0
0.0
0.0
56.8
0.0
0.0
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 41.79 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 252
Ion
252
126
0
0
Exp Ratio
100
31.2
0.0
0.0
PESJ .M
41.00 42.00
Tue Oct 19 10:05:27 1999
HP 5989B
?01330
Page 16
-------
TIC: ENGlb?3.0
30000 .
20000 .
10000 -
Time--> 52.20 52.40 52.60
Abundance I on 288.00 (287.70 to 288.70): ENG
52 .80
15000 -
52 .50
10000 -
5000 -
52.40
Time--> 52.20
52.80
#30
Indent) (1,2, 3 -cd) pyrene-di2
Coneen: 4.78 ng/uL m
RT: 52.50 min Scan# 6019
Delta R.T. -0.04 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:288 Resp: 104793
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
30000
20000
10000
0
Time-->
Abundance Ion 27 S.05
Ion 138.00
2000
1000
TIC: EUG1673.D
-i 1 1 1 ( i I ! ' 1 ? *! r i [ i r
52.00 53.00 54.00
#31
Indeno{1,2,3-cd)pyxene
Concen: 0.00 ng/uL
Expected RT: 52.82 min
Lab File: . ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 276.05
Exp Ratio
100
60 .1
0 . 0
0.0
1275.75 to 275.75): ENS
[137.70 to 138.70)
Time-
52.00
53 .00
—j 1 , f-
54 .00
ENG1673.D—PES3.M
Tue Oct 19 10:05:30 1999
HP 5989B
"*v
Page 17
-------
X JLV~ « Q / J> » U
Abundance
10000 -
Time--> 52:20
AbundanceIon 252.00 (2&1.70 to 252.70): fiNG
52 .40
52.60
52.46
10000
5000 .
52 140
52 .60
Time--> 52.20
#32
Dibenz(a, h)anthracene-dl4
Concen: 4.75 ng/uL m
RT: 52.46 min Scan# 6012
Delta R.T. -0.04 min
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion-.292 Resp: 63958
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
30000
20000
10000
Time - - >
TIC: ENG1673.D
52.00
53.00
54.00
2000
1000
Time - ->
52.00
53.00
54.00
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 52.87 min
TFile : ENG1673 . D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 278
Ion Exp Ratio
100
53.6
0.0
0.0
(AbundanceIon 278.00 (211 .It to 278.70): ENG
Ion 139.00 (138.70 to 139.70):
ooaia-
• ^ -ul «¦'"
w.jJ
ENGlfcVj.D—PES3.M
Tue Oct 19 10:05:34 1999
HP 5989B
Page 18
-------
TIC: EMG1673.B
Abundance
15000 -
10000 .
5000 -
55:20
Time - - >
Abundance Ion 288.00 (287.70 to 288.70): ENG
55.40
55.60
55.80
55.46
Time-->
55.20
55 .40
55 .60
55.80
#34
Benzo(g,h, i)perylene-dl2
Concen: 4.42 ng/uL m
RT: 55.46 min Scan# 6580
Delta R.T. -0.06 rain
Lab File: ENG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion:288 Resp: 102826
Ion Ratio Lower Upper
288 10 0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
15000
10000 .
5000
0
Time-->
TIC: ENGlb73.D
#35
Benzo(g,h, i)perylene
Concen: 0.00 ng/uL
Expected RT: 55.84 min
Lab File: 1NG1673.D
Acq: 16 Oct 99 1:14 am
Tgt Ion: 276
Exp Ratio
100
16 .2
55.00
56:00
57.00
(AbundanceIon 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70):
2000
1000
Time--> 55.00
ENGT5777D PES3 .M
56.00
57.00
'me Oct iy 10:05:37 1999
WD CQQQD
n±r D^o;o
If-' -0 ;o
Page 19
-------
ENG1674.XLS
Quantitation Report Summary
Data File
ENG1674,0
Date Analyzed:
10/1 ms
Sample ID
CARB429,REAGENT BLK
Method ID
PES3
Operator
Instrument
HP 5989B
Compounds
Area
Cone.
PQL*
Cone.
Cone, (rig/sample)
Diluted result
(ng/iiL)
(ng/pl)
(ng/sample)
w/ Surr, correction
ng/sample
Naphthalene(CCC)
142621
0.479
0.1
479
847
0
Aeenaphthylene
0
0.000
0.1
0
0
0
Acertapbthene(CCC)
0
0 000
0,1
0
0
0
Fluorene
0
0.000
0.1
0
0
0
Phenanthrene
0
0,000
0.1
0
0
0
Anthracene
0
0,000
0.1
0
0
0
Fl uoranthene(CCC)
0
0.000
0.1
0
0
0
Pyrerte
0
0.000
0.1
0
0
0
Benzo(a)anthracene
0
0,000
0.1
0
0
0
Chryserie(CCC)
0
0.000
0,1
0
0
0
Benzo(b)fluoranthene
0
0.000
0.1
0
0
0
Benzo(k)fl uora ntherse
0
0.000
0.1
b
0
0
Benzo(a)pyrene{CCC)
0.
0.000
0.1
0
0
0
lndeno(1,2,3-cd)pyrene
0
0.000
0.1
0
0
0
3ibenz(a,h)anthraeene
0
0.000
0.1
0
0
0
Benzo(g,hj)perytene
0
0.000
0.1
0
0
.0
* PGL - practical quantitation limit
Surrogate Recoveries
Compound
Cone, (ngf
ML)
% Recovery
Naphthalene-dS
2.26
57
Acena phthy Iene-d8
4.42
110
Acena phthene-d 10
3.73
93
Fluorene-dtO
3.96
99
Phenanthrene-d10
3.72
93
Anthracene-dIO
5.41
135
Fluoranthene-d10
3.61
90
Pyrene-d10
3.67
92
Benzo(a)anthracene-d 12
5.14
128
Chrysene-d12
3.66
91
Benzo(b)fluorarithene-d 12
4.50
112
Benzo{k)fluoranthene-d12
4.64
116
Benzo(a)pyrene-d12
3.99
100
lndeno(1,2,3-cd)pyrerie-d12
3.41
85
Dihenz(a,h)anthracene-d14
3.84
96
Benzo(g,h,i)perylene-d12
3.70
93
Recovery Standard
Compound
Concentration (ngfyL)
% Recovery
j
2-Methlynaphthalene-d 10
1.56
1
77.99
p-TerphenyW14
j_1.S9
79,59
/
1
Compiled by
Renewed by
Reviewed by
I 1 1
000.5.054
-------
Quantitation Report
C:\KPCHEM\l\DATA\ENG1674.D
16 Oct 99 2:20 am
CARB429,REAGENT BLK
Data File
Acq On
Sample
Misc :
Quant Time; Oct 19 10:08 1999
Vial
Operator
Inst
Multiplr
14
HP 5989B
1.00
Method
Title
Last Update
Response via
C;\HPCHEM\l\METH0DS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1) 2,2-Difluorobiphenyl
System Monitoring Compounds
2) Naphthalene-d8
4) 2-Methlynaphthalene-dlO
5) Aeenaphthylene-d8
7) Acenaphthene-dlO
9) Fluorene-dlO
11) Phenanthrene-dlO
13) Anthracene-dlO
15) Fluoranthene-dl0
17) Pyrene-dlO
19) p-Terphenyl-dl4
20) Benzo(a)anthracene-dl2
22) Chrysene-dl2
24) Benzo(b)fluoranthene-dl2
26) Benzo(k)fluoranthene-dl2
28) Benzo(a)pyrene-dl2
30) Indenod, 2, 3-cd) pyrene-dl2
32) Dibenz(a,h)anthracene-dl4
34) Benzo(g,h,i)perylene-dl2
Target Compounds
19.99 190
17.68
19.36
21.62
22.04
23.30
25.67
25.81
28.67
29.28
29.61
33 .34
33.48
39.33
39.50
41.58
52 .48
52 .46
55 .45
136
152
160
164
176
188
188
212
212
244
240
240
264
264
264
288
292
288
462789 5.00 ng/uL -0.01
%Reeovery
591578 2.26 ng/uL 56.50%
141745 1.56 ng/uL 38.99%
355085 4.42 ng/uL 110.45%
293304 3.73 ng/uL 93.18%
307973 3.96 ng/uL 99.00%
408970 3.72 ng/uL 92.89%
288123 5.41 ng/uL 135.25%
363005 3.61 ng/uL 90.29%
411373 3.67 ng/uL 91.64%
143550 1.59 ng/uL 39.80%
213652 5.14 ng/uL 128.44%
272680 3.66 ng/uL 91.41%
206833 4.50 ng/uL 112.38%
214832 4.64 ng/uL 115.94%
98042 3.99 ng/uL 99.67%
92870 3.41 ng/uL 85.17%
64166 3.84 ng/uL 95.95%
106986 3.70 ng/uL 92.52%
Qvalue
100
3)
Naphthalene(CCC)
17.72
128 142621
0.48 ng/uL
6)
Acenaphthylene
0.00
152
Not
Detected
8)
Acenaphthene(CCC)
0.00
154
Not
Detected
10)
Fluorene
0.00
166
Not
Detected
12)
Phenanthrene
0.00
178
Not
Detected
14)
Anthracene
0.00
178
Not
Detected
16)
Fluoranthene(CCC)
0.00
202
Not
Detected
18)
Pyrene
0.00
202
Not
Detected
21)
Benzo(a)anthracene
0.00
228
Not
•Detected
23)
Chrysene(CCC)
0.00
228
Not
Detected
25)
Benzo(b)fluoranthene
0.00
252
Not
Detected
27)
Benzo(k)fluoranthene
0.00
252
Not
Detected
29)
Benzo(a)pyrene(CCC)
0.00
252
Not
Detected
31)
Indeno(1,2,3-cd)pyrene
0.00
276
Not
Detected
33)
Dibenz(a,h)anthracene
0.00
278
Not
Detected
35)
Benzo(g,h,i)perylene
0.00
276
Not
Detected
(#) = qualifier out of range (m) = manual integration
ENG1674.D FES3.M Tue Oct 19 10:09:15 1999 HP 5989B
iMCLlOikj-.
Page 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C: \HPCHEM\l\DATA\ENG1674 .D
16 Oct 99 2:20 am
CARB4 2 9,REAGENT BLK
Oct 19 10:08 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial: 14
Operator:
Inst : HP 5989B
Multiplr: 1.00
^§8908®
TIC: ENG1674.D
300000
250000
200000
150000
100000
50000
4s
Us 17s
15! >
1 is
5s
7s
9s
9S 22s
20s
28s
3fif
34s
> 1 I 1 | > 1 '"I I1 | I 1 I" ' I ' 1 1 ] 1 "T 1 I1 1 ] 1 P T 1 1 ? ! 1 1 1 f 1 1 I [ \ \ i I 1 T"
fTime--> 20.00 25.00 30.00 35.00 40.00 45.00 50 !00 55.00
1NG1674.D PES3.M Tue Oct 19 10:09:22 1999.
000.1055
HP 5989B Page 2
-------
TIC: HWG1674.D
200000
iooooo _
Time-
17.40
17.60
17.80
Abundance Ion 136.00 (135.70 to 136.70): EHG
Ion 68.00 (67.70 to 68.70): ENG16
17.68
200000
100000
Time-
17 .40
17.60
17.80
#2
Naphthalene-d8
Concen: 2.26 ng/uL
RT: 17.68 min Scan# 250
Delta R.T. -0.01 rain
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:136 Resp: 591578
Ion Ratio Lower Upper
136 100
68
17.9
7.7
23 . 0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
200000
100000
TIC: BNG1674.D
0
Time--> 17160 17170 17180
Abundance Ion 126.00 (127.70 to 126.70): BUG
Ion 127.00 (126.70 to 127.70): ENG
17 .72
60000
40000
20000
0
1—I—,—
17.60
Time - - >
ENG1674.D PES3.M
#3
Naphthalene(CCC)
Concen: 0.48 ng/uL
RT: 17.72 min Scan# 257
Delta R.T. -0,02 min
Lab Pile: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:128 Resp: 142621
Ion Ratio Lower Upper
128
100
127
12 .9
0.0
63.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
n 1 i 1 1 > • i <~
17.70 17.80
"rue uct iy 10: oy : 25 lyyy
HP 5989B
WH037
Page 3
-------
TIC: ENG1574.D
Abundance
60000 J
40000 -
20000 .
Time-'->19 .20
19.30
Abundance Ion 152.00 (151.70 to 152 .70); ENG
19.40
19.36
60000 :
40000 ^
20000:
Time-->19.20
19.30
19 .40
#4
2-Methlynaphthalene-dlO
Concern 1.56 ng/uL
RT: 19.36 min Scan# 756
Delta R.T. -0.01 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:152 Resp: 141745
Ion Ratio Lower Upper
152 100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
150000
100000
Time-
50000 -
TIC: ENG1674.D
21.40
21.60
21.80
[AbundanceIon 160.00 (159.70 to 160.70): ENG
21.62
150000:
100000
50000
0
Time-->
21.40
21.60
21.80
#5
Acenaphthylene-d8
Concen: 4.42 ng/uL
RT: 21.62 min Scan# 1296
Delta R.T. -0.01 min
Lab File: SNG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:160 Resp:
Ion Ratio Lower
160 100
0 0.0 0.0
0 0.0 0.0
0 0.0 0.0
ENG1674.D—PES3.M
Tue Oct 19 10:09:28 1999
HP 5989B
355085
Upper
0.0
0.0
0.0
"1053
Page 4
-------
(Abundance
150000:
100000
50000
1 I 1 11 T I '"I"" I I I I I—! 1 1' {—I—I—j—I—r
Time--> 20.50 21.00 21.50 22.00 22.50
TIC: ENG1674.D
Abundance ion 152.50 (151.70 to 152.70): fiNG
Ion 153.00 (152.70 to 153.70): ENG
3000
2000
1000 .
Time--> 20.50 21.00 21.50 22.00 22.50
Abundance
100000
TIC: ENG1674.D
50000
0
150000
100000
50000
22.04
Time~~>
ENGT674 .D—PES3 .M
1"I i J ! 1 1 1 ! 1 1 1 ! 1 1 1 1—
21.90 22.00 22.10 22 .20
#6
Acenaphthylene
Concern 0.00 ng/uL
Expected RT: 21.66 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:
Ion
152
Exp Ratio
100
13 .0
0.0
0.0
#7
Acenaphthene-dl0
Concen: 3.73 ng/uL
RT: 22.04 min Scan# 1358
Delta R.T. -0.01 min
Lab File; .ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:164 Resp: 293304
Ion Ratio Lower Upper
_! j , , j , p- r 1 , j—j , 1 j—-
Time--> 21.90 22.00 22.10 22120
Abundance Ion 164.00 (163.70 to 164.70): ENG
164
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Tus—Oct—X9—IQ" »09 gij
HP 5989B
- '.'jgy
Page 5
-------
Abundance
150000
100000
50000
Time--> 21 lo'o" 211 SO* 22 ! oo' *22 1 50* 23! 00
TIC: ENG1674.D
AbundanceIon 154.00 (153,70 to 154.70]
j loll 153.00 (152.70 to 153.70!
] '
3000 j
W
SNG
2000
1000
J
0
u_
—i—i—i—r—i—i—i—i—i—|—i—i—i—r~|—i—i—i—i—t—i—i
Time--> 21.00 21.50 22.00 22.50 23.00
#8
ft.cenaphth.ene (CCC)
Concen: 0.00 ng/uL
Expected RT: 22.12 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 154
Ion Exp Ratio
154 100
153 98.0
0 0.0
0 0.0
abundance
100000
50000
TIC: EMG1674.D
Tirae-
23.10 23.20 23.30 23.40 23.50
Abundance ton 176.00 (175.70 to 176.70): ENG
150000
100000
50000
23 .30
0
Time-->
"t r i—j i i ' i ~"i | i t i i | r i i—i—|—t—i—r—i—i—i—r
23 .10 23.20 23.30 23.40 23150
ENG1674 .D—FES3.M"
Fluorene-dlO
Concen: 3.96 ng/uL
RT: 23.30 min Scan# 1549
Delta R.T. -0.01 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:176 Resp: 307973
Ion Ratio Lower Upper
176 100
0 0.0 0.0 0.0
0 0.0 0,0 0.0
0 0.0 0.0 0.0
Tue Oct iy 10:09:34 1999
Ge.1090
HP 5989B Page 6
-------
Abundance
100000
50000
t+Tf* -—'cia ' ft
X X v • / TE • jL>>
Time--> 22i50 23:00 23 I 50* 24:00
Abundance Ion 166.00 (165.70 to 166.70): ENG
Ion 165.00 (154.70 to 165.70): ENG
3000
2000
1000
0
Time-->
^—1—I—1—1—I—1—I—I—I—I—!—I—i—I—1—f—I—I—r
22.50 23.00 23.50 24.00
TIC: BWG1674.D
#10
Fluorene
Concen; 0.00 ng/uL
Expected RT: 23.38 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 166
Ion Exp Ratio
166 100
165 91.3
0 0.0
0 0.0
Abundance
200000
150000
100000
50000
n
v - .. , | 1 5 1 , 1 , , 1 r—1 ¦ -1 ¦¦ 1 j 1 r
Time-->25.50 25.60 25.70 25.80
Abundance Ion lSS.00 (137.70 to 168.70): ENG
Ion 94.00 {93.70 to 94.70): ENG16
2000004 25.67
150000
100000
50000
#11
Phenanthrene-dl0
Concen: 3.72 ng/uL
RT: 25.67 min Scan# 1909
Delta R.T. -0.01 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:188 Resp: 408970
Ion Ratio Lower Upper
188
100
94
26 .8
12 .3
36.8
0
0 .0
0.0
0.0
0
0.0
0.0
0.0
—1 , , , , j 1 1 j | i 1 : 1 1 1 r
Time-->25:50 25.60 25.70 25180
ENGlb /4 .D PES 3 .M
'me Oct 19 10:0ST3T~TW9
HP 5989B
OOClOfc
Page 7
-------
Abundance
200000
150000
100000
50000
0
¦¦¦¦ i in. _lm V-i m " TEy""*"
TICi ENtjl674 »D
J
L
• » i 1 1
25.50
—I ! 1 1 1 1 1 1
26100 26150
Time-->24 . 50 25.00
Abundance Ion 178.00 (177.70 to 178.70):
Ion 176.00 {175.70 to 176.70) :
3000
2000
1000
0
n—i—i—r
rrime--s24.50 25.00 25.50 26.00 26.50
abundance
200000
150000
100000
50000 J
1 r 1 1 [ i"
25160 25180 26100
Abundance Ion 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
200000
150000
100000
50000
o _
Time--> 25160
SNG1674.D—PES3 .M
25.81
#12
Phenanthrene
Concen: 0.00 ng/uL
Expected RT: 25.74 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion;
X on
178
176
0
0
178
Exp Ratio
100
20 .2
0.0
0.0
TTel ENGlb 7 4.D
#13
Anthracene-dl0
Concen: 5.41 ng/uL
RT: 25.81 min Scan# 1930
Delta R.T. -0.01 min
Lab Pile: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:188 Resp; 288123
Ion Ratio Lower Upper
188
100
94
29.5
13.4
40.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
25.80 26.00
Tue Oct 19 10:09:41 1999
HP 5989B
• *KrO
Page 8
-------
TIC: ENG1674.D
Abundance
200000
150000
100000
50000
Tirae--> 25100 25l5o' '26!00 '26150'
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 25.87 min
Lab File; ENG1674.D
Acq; 16 Oct 99 2:20 am
Tgt Ion-. 178
Exp Ratio
100
19 .9
0.0
0.0
Abundance Ion 178.00 (177.70 to 178.70): MQ
Jlon 176.00 (175.70 to 176.70): 1NG
3000
2000
1000
Time-
-i—i—]—i—i
25.00
25.50 26.00
—i | j i—i—r~
26150
Abundance
200000
150000
100000
50000
0
TIC; ING1674.D
Time-~> 28.40
28160
28 .80
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
28 .67
150000 '
100000
50000
#15
Fluoranthene-dl0
Concen: 3.61 ng/uL
RT: 28.67 min Scan# 2368
Delta R.T. -0.01 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:212 Resp: 363005
Ion Ratio
212 100
106 28.7
0 0.0
0 0.0
Lower Upper
13 .7
0.0
0.0
41.0
0.0
0.0
Time--> 28140
28.60
28180
ENGT6T4 . D—PES3 .M
Tue Oct 19 10:09:44 1999
HP 5989B
v».
Page 9
-------
Abundance
200000 :
150000 :
100000
TIC: ENG1674.D
50000:
~1 1 J 1 1111' '\ !!"¦"¦"!' 1 I mJ T I I ! ¦'" ] 1 l LIL Li' ! 1111 T
Time-->27:50 28.00 28:50 29100 29.50
Abundance Ion 202.00 1201.70 to 202.70): ENG
]Ion 101.00 (100.70 to 101.70): ENG
4000 .
3000:
2000
1000
0
h—i—i—I—r
Time-->27 . 50 28.00 28150
i—i—|—r-H—i—i—i—\—r
29.00 29.50
Abundance
200000
150000 4
100000
50000
0
>29
TIC: ENG1574.D
Time-->29 100 29.20
Abundance Ion 212.00
29 .40
(211.70 to 212.70):
200000_iIon 106.00
150000
100000
{105.70 to 106.70)
29.28
50000
0
Time-->29.00
ENG1674.D PES3.M
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 28.73 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 202
Exp Ratio
100
24.0
0.0
0.0
#17
Pyrene-dlO
Concen: 3.67 ng/uL
RT: 29.28 min Scan# 2459
Delta R.T. -0.01 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:212 Resp: 411373
Ion Ratio Lower Upper*
212
100
106
32 .8
15 .9
47 .5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
UKT
ENG
-------
Abundance
200000
150000
100000
50000
0
Time - - >
TIC: ENG1674.D
1 ! 1 1 IT ! I I 5—"TT 1 1 ! ! 1 J 7—1 ! T"
28.50 29100 29;50 30100
1 ¦ ¦ %1 JLI Jl J. I ¦ ¦
MaundanceIon 202.00
Ion 101.00
4000 '
3000
2000
1000
/ A A-1 PI A ' A • m, JkM. m A juiia.*,
(201.70 to 202,70); SNG
(100.70 to 101.70): ENG
prime-->
~i—t—i—|—r~
i—i—!—r~
r r r t
28.50 29.00 29.50 30.00
100000
50000
Time
29 .40
29.60
29.80
20000
29.40
Txme-->
29.60
29.80
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 29.34 tnin
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.6
0 0.0
0 0.0
Abundance
Xw * £NGx574,0
200000
150000
#19
p-Terphenyl-dl4
Concen: 1.59 ng/uL
RT: 29.61 rnin Scan# 2509
Delta R.T. -0.01 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:244 Resp: 143550
Rat xo
100
32 .0
0 .0
0.0
Lower Upper
14.6
0.0
0.0
43 .7
0.0
0.0
Abundance Ion 244.00 (243 . 70 to 244.70) : IMS
Ion 122.00 (121.70 to 122.70): ENG
29.61
60000
40000
ENG1674.D—PESJ.M
Tue Oct iy 10:09:50 19$¥
HP 5989B
000.1035
Page 11
-------
Abundance
100000
TIC: ENG1S74.D
50000
Time--> 33^20 ' ' 33130
-T 1 ! 1 1 r
33 i40
^AbundanceIon 240.00 (239.70 to 240.70) : ENG
Ion 120.00 (119.70 to 120.70): ENG
80000
60000
40000
20000 J
0
33 .34
|rime--> 33.20
t 1 ! 4 1 ! I 1 1 I
33.30 33.40
#20
Benzo (a) anthracene-d.12
Concern 5.14 ng/uL
RT: 33.34 min Scan# 3069
Delta R.T. -0.02 min
La.t> File i HMGrl674,0
Acq: 16 Oct 99 2:20 am
Tgt Ion:240
Ion Ratio
240 100
120 30.2
0 0.0
0 0.0
Resp: 213652
Lower Upper
14.0 41.9
0.0 0.0
0.0 0.0
TIC: ENG1674.D
100000
50000
Time
32.50 33:00 33.50 34.00
2000
Time-->
ENGU74.D
32 .50
PES3 .M
T !—I—r
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 33.46 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:
Ion
Abundance Ion 228.00 (227.70 to 228.70): ENG
Ion 114.00 (113.70 to 114.70): ENG
4000 _j
228
Exp Ratio
100
25.4
0.0
0.0
33.00 33.50 34.00
Tue Oct 19 10:09:53 1999'
HP 5989B
Page 12
-------
Abundance
100000
TIC: ENG1674.D
50000
Time-->33.20 33.40 33.60
Sundance Ion 240.00 {239.70 to 240.70):
Ion 120.00 (119.70 to 120.70):
33 .48
80000
60000
40000 -
20000
nr
ENG
0
Time-->33 .20
Sundance
100000
33 .40
33 .60
50000
1 I I 1 ! I 1 1 1 J ( 1 1 ! ! ! T
Time-->32.50 33:00 33.50 34.00 34.50
Sundance Ion 228.00
4000
2000
0
Ion 114.00
#22
Chrysene-dl2
Concen: 3.66 ng/uL
RT: 33.48 min Scan# 3090
Delta R.T. -0 .02 min
Lab Fxle: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:240 Resp: 272680
Ion Ratio Lower Upper
240
100
120
27 .6
13 .7
41.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG1fo 7 4.D
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.61 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 228
Exp Ratio
100
2
0.0
0.0
227.70 to 228.70): ENG
113.70 to 114.70): ENG
i—s—s—I—1—t—i—i—r—1—e—1—r—1—1—f—1—1—I—*—1—1—r
Time-->32 i50 33.00 33.50 34.00 34.50
ENGlb 7 4.D PESTTH"
Tue Oct 19 10:09:57 1999
HP 5989B
000.1036
Page 13
-------
Abundance
TIC: ENG1674.D
60000:
a r
40000:
\ /
20000:
y Vy
0 -
Time-->
i i f i j i * i i «i i t j t *
39.20 39.30 39140
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
39.33 ^
40000
f\ /
20000
l\ L*
0 -
Titne-->
-i 1 t"" * j—i r,M v"" i —p" 'i' * i r"-n—|—? —¦ iiu ¦ |
39.20 39.30 39.40
#24
Eenzo(b)fluoranthene-dl2
Concen: 4.50 ng/uL m
RT: 39.33 min Scan# 3988
Delta R.T. -0.03 min
Lab File: ENG1674.D
Acq; 16 Oct 99 2:20 am
Tgt Ion:264
Ion Ratio
264 100
132 41.2
0 0.0
0 0.0
Resp: 206833
Lower Upper
34.8 104.2
0.0 0.0
0.0 0.0
Abundance
60000
40000 -
20000
TIC: ENG1674.D
~r—r—i—i—f—i—i—s—r I r—r~*i—r—I—i—r-
38150 39.00 39.50 40.00
Time-->
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126 .70) : ENG
3000
2000
1000
0
Time-->
1 1 ! 1 ! ! I 1 1 f 1 1 1 1 1 1 1 ] 1—"T
38.50 39.00 39.50 40.00
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.52 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 252
Exp Ratio
100
27.8
0.0
0.0
ENG1674.D PES3 I'M
Tuin3crT^-TD7i^r7mr-iw?
HP 5989B
ooeios?
Page 14
-------
Abundance
60000
40000
20000
TIC: ENGl6?4.D
Time - - > 3 9 12 0 39.40 39160
Abundance 1on 264.00 (263.70 to 264.70):
Hon 132,00 (131.70 to 132.70):
39.50
40000 "
20000
MS"
ENG
Time-->39.20
39.40
39.60
#26
Benzo(k)£luoranthene-dl2
Concen: 4.64 ng/uL
RT: 39.50 min Scan# 4014
Delta R.T. -0.03 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:264 Resp: 214832
Ion Ratio Lower Upper
264
100
132
35 .5
18 .0
53 .8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
TIC:
A
EMG1674.D
60000 ;
^ l!
40000 :
}j!
20000:
ill
1
/
V
0 -
Time-->
i i i i i i i
39.00
1 ' 1
39 ~
t i i i [ i < ; t j i i i i
50 40.00 40.50
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70): ENG
3000 :
~~
2000:
iooo :
o:
Time-->
1 ! ! 1 J 1 T
39 .00
—1—'—r
39.
—,—,—,—j—,—,—_—j—i :¦ t"
50 40.00 40.50
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.67 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 • 27.6
0 0.0
0 0.0
ENGTF74TD FEST7W
Tue Oct 19 10:10:03 1999
HP 5989B
ft •¦ftos
Page 15
-------
Abundance
TIC: EMG1674
.D
30000 J
20000 -
10000 .
0
Time--> 4l!20 '
41.40 41.60
41.80
Abundance Ion 264
.00 (263.70 to
264.70):
ENG
20000 .
Ion 132
,00 (131.70 to
41.58
132 .70) :
ENG
15000 ,
10000 -
5000 -
0 .
Tirae--> 41120
41140 41.60
CO
H
#28
Benz o{a)pyrene-dl2
Concen: 3.99 ng/uL
RT: 41.58 min Scan# 4333
Delta R.T. -0.03 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt IOIl: 264 Resp: 98042
Ion Ratio Lower Upper
264 100
132 33.3 19.0 56.8
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance
TIC: ENG1674
.D
30000:
20000:
11
10000 .
0 I
Time - - >
41! 00
42 .00
> 1 1 i 1
43 .00
AbundanceIon
252.00
(251.70 to
252.705 : ENG
Ion
126.00
(125.70 to
126.70): ENG
4000-
A
3000
"tV—
2000
1000 -
0 -
Time-->
' 41.00
42! 00
i f i J <
43 .00
#29
Benzo(a)pyrene CCCC)
Concen: 0.00 ng/uL
Expected RT: 41.79 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 31.2
0 0.0
0 0.0
HP 5989B
0001959
Page 16
-------
Abundance
TIC: 2NG1674.d
30000 -
20000 J
/ v
10000 .
0 -
Time - - >
52!20 52.40 52.60
Abundance ion 288.00 (287.70 to 288.70): ENG
15000 _
52 .48
10000
/\
5000
J \
0 .
/
Titne-->
1 I ! I 1 1 | 1 1 1 1 I 1 1 • 1 |
52.20 52.40 52.60
#30
Indeno{1,2,3-cd)pyrene-dl2
Concen: 3.41 ng/uL to
ET: 52.48 mill Scan# 6014
Delta R.T. -0.06 min
Lab Pile; ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:288 Resp: 92870
Ion Ratio Lower Upper
288 100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1674.D
30000
20000
10000
Time
52 00
53.00
54.00
2000
1000
0
I , ,
Time - - >
ENG1674 .D—PES3.M
52 !00
53.00
54.00
#31
Indeno(1,2,3 -ed)pyrene
Concen: 0.00 ng/uL
Expected RT: 52.82 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 276.05
Exp Ratio
100
60 .1
0.0
0.0
IkbundanceIon 275.05 (275.75 to 276.75)
lion 138.00 (137.70 to 138.70): ENG
Tue Oct 19 10:10:11 1999
HP 5989E
UI0-0
Page 17
-------
TIC: ENG1674.D
Sundance
30000 J
20000 .
10000
52 .40
52 .60
> 52 20
Abundance Ion 252.00 (251.70 to 252.70): ENG
52.46
10000 -
5000 j
52 .40
52.60
Time— > 52.20
#32
Dibenz(a,h)anthracene-dl4
Concen: 3.84 ng/uL m
RT: 52.46 min Scan# 6010
Delta R.T. -0.04 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:292 Resp: 64166
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
30000
20000
TIC: MGl€74.D
10000
0
Tirae-
-i r
52 .00
53 .00
54 .00
[AbundanceIon 278.00 (277.70 to 278.70) :
lion 139.00 (138.70 to 139.70); ENG
2000 J
1000 -
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 52.87 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 278
Ion
278
139
0
0
Exp Ratio
100
53 .6
0.0
0.0
' ¦
Time--> 52.00 53.00 54.00
ENG1674.D PES3.M Tue Oct 19 10:10:14 1999'
HP 5989B
Page 18
-------
Abundance
15000
10000
5000 J
0
TIC: ENG1S74.D
1—! 1 T"
Tim© — > 55.00 55.20 55.40 55.60 55.80
AbundanceIon 266.00 (287.70 to 286.70): ENG
55.45
10000
5000
! f ! , , 1 1 1 , , 1 j 1 1 1 ( 1 r 1 r
[Time--> 55.00 55.20 55.40 55.60 55.80
5Bun3ance
15000
10000
5000
0
TIC: ENG1S74.D
A
_1 | , r
Time--> 55.00 56.00 57.00
Abundance Ion 276.00 (275.70 to 276.70): ENG
Ion 138.00 (137.70 to 138.70): ENG
2000
1000
0
Time--> 55.00
ENG1674 .D—P'ESITM
-I 1 1 1
57 100
#34
Benzo (g, h, i)perylene-dl2
Concen: 3.70 ng/uL m
RT: 55.45 min Scan# 6575
Delta R.T. -0.07 min
Lab Pile: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion:288 Resp: 106986
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
#35
Benzo(g,h,i)perylene
Concen -. 0.00 ng/uL
Expected RT: 55.84 min
Lab File: ENG1674.D
Acq: 16 Oct 99 2:20 am
Tgt Ion: 276
Ion Exp Ratio
276 100
138 16.2
0 0.0
0 0.0
J?, _
56.00
Tue Oct 19 10:10:18 1999
HP 5989B
00G
Page 19
-------
ENG1S75.XLS
Quantitation Report Summary
Data File
ENG1675.D
Date Analyzed:
10/16/99
Sample ID
CARB429,INLET FIELD BLANK
Method ID
PES3
Operator
Instrument
HP 5989B
Compounds
Area
Cone.
PQL*
Conc.
Cone, (ng/sample)
Diluted result
(ng/|iL)
(ng/ML)
(ng/samp(e)
w/ Suit, correction
ng/sample
Naphthalene(CCC)
70994
0.226
0,1
226
1081
0
Acenaphthylene
0
0.000
0.1
0
0
0
Acenaphthene(CCC)
0
0.000
0,1
0
0
0
Fluorene
0
0.000
0,1
0
0
0
Phenanthrene
0
0.000
0.1
0
0
0
Anthracene
0
0.000
0.1
0
0
0
:iuoranthene(CCC)
0
0.000
0.1
0
0
0
syrene
0
0.000
0.1
0
0
0
Benzo(a)anthracene
0
0.000
0.1
0
0
0
Chrysene(CCC)
0
0.000
0.1
0
0
0
3enzo(b)fiuoranthene
0
0.000
0.1
0
0
0
Ben2o(k)fluorarrthene
0
0,000
0.1
0
0
0
Benzo(a)pyrene(CCC)
0
0.000
0.1
0
#DIV/0!
#DIV«!
lndeno{1,2,3-cd)pyrene
0
0.000
0.1
0
0
0
Dibenz(a,h)anthraoene
0
0.000
0.1
0
0
0
3enzo(g h,:)perylene
0
0.000
0.1
0
0
0
* PQL - practical quantitation
limit
Surrogate Recoveries
Compound
Cone. (ng/|iL|
% Recovery
Naphthalene-d8
0,84
21
Acenaphihylene-d8
0,91
23
Acenaphthene-d10
2,25
56
I
Fluorene-d10
2.60
65
Phenanthrene-d 10
3.00
75
Anthracene-d10
6.19
155
Fluoranthene-d10
3.03
76
Pyrene-d10
2,80
70
Benzo(a)anthracene-d12
1.81
45
Chryserie-d12
2.85
71
Ber\zo(b)fluoranthene-d12
3.16
79
Benzo(k)fl jorarrthene-d 12
2.82
71
Benzo(a)pyrene-d12
0.00
0
lnderio(1,2,3-od)pyrene-d12
1.78
44
D»cenz(a,h)anthracene-d 14
1.97
49
Benzo(g ,h,i)pery[ene-d 12
1.93
48
Recovery Standard
Compound
Concentration (ng/yL)
% Recovery
2-Methlynaphthalene»d10
0.65
33
p-Terphenyl-d14
1.39
70
vO-
Compiled by:
Reviewed by:
- —"7*""—¦
~it— ¦ »
Reviewed by:
I I
000.1103
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
Method
Title
Last Update
Response via
C; \HPCHEM\l\DATA\ENG1675 .D
16 Oct 99 3:26 am
CARB429,INLET FIELD BLANK
Oct 19 10:12 1999
C:\HPCHEM\l\METH0DS\PES3.M
"Vial
Operator
Inst
Multiplr
15
HP 5989B
1,00
Tue Nov 23 19:47:37 1999
Multiple Level Calibration
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1} 2,2-Difluorobiphenyl
System Monitoring Compounds
2} Naphthalene-d8
4) 2-Methlynaph.thalene-dlO
5) Acenaphthylene-d8
7) Ac enaphthene - d 10
9) Fluorene-dlO
11) Phenanthrene-dlO
13) Anthracene-dlO
15) Fluoranthene-dlO
17) Pyrene-dlO
19) p-Terphenyl-dl4
20) Benzo(a)anthracene-dl2
22) Chrysene-dl2
24) Benzo
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
C:\KPCHEM\1\DATA\ENG1675,D
16 Oct 99 3:26 am
CARB42 9,INLET FIELD BLANK
Oct 19 10:12 1999
Method
Title
Last Update
Response via
C:\HPCHEM\l\METHODS\PES3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial: 15
Operator:
Inst : HP 5989B
Multiplr: 1.00
undance
350000
TIC: ENGlfc/b.D
300000
250000
200000
150000
100000
50000
2s
lis
17S
15s
9s
4S
7 S
5s-
9S
22s
1/
2C
s
1. 1 kit L.
[Time-
3QS
34S
l I 51 I T V T f~
•> '20 loo' 25 ! o'o ' '30 loo' ' 35 ! 00 ' ' 40 ! 00 ' 45.00 50100 55 100
ENG1675.D PES3.M Tue Oct 19 10:13:20 1999
0CQ11^
HP 5989B Page 2
-------
Abundance
150000 -I
100000
TIC: ENG1675.D
50000
0
68.00 (67.70 to 68.70): ENG16
17 .68
100000
50000
Time-
17.50
17 .60
17.70
^17:80
#2
Naphthalene-d8
Concen: 0,84 ng/uL
RT: 17.68 min Scan# 250
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion*. 136 Resp : 230645
Ion Ratio Lower Upper
-r—i—i—i—i—i—i—i—i—r—|—i—i—r~T—j—i—?—i—r
Time--> 17.50 17:60 17170 17180
Abundance Ion 13 6.00 (135.70 to 136.70): ENG
lion ca nn 1 cn ¦""">* - c'1
136
100
68
26.9
7.7
23.0#
0
0.0
0.0
0 . 0
0
0.0
0.0
0.0
Abundance
150000
100000
50000
Time--> 17.60
TIC: ENG1675.D
17 .70
17.80
20000
10000 J
#3
Naphthalene(CCC)
Concen: 0.23 ng/uL
RT: 17.73 min Scan# 258
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:128 Resp: 70994
Ion Ratio Lower Upper
128 100
127 13.0 0.0 63.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
Abundance Ion 128.00 E127.70 to 128.70): ENG
:ion 127.00 (126.70 to 127.70): ENG
40000 J 17.73
30000:
ime--> 17.60
17 .70
17.80
mm
ENG'lfcVh .D—FE5T7W
'me Oct 19 1U : 13 : 23 1999
HP 5989B
Page 3
-------
Sundance
30000
20000 _
10000
TIC: ENGlb'S.D
Time-
[ I j r™"T ¦(—!—| 1 1 I I 1 I ! I I j (—1—1—| 1 ; 1—r-
19.25 19.30 19.35 19.40 19.45
Abundance Ion 152.00 (151.70 to 152.70): ENG
40000
30000
20000 -j
10000 j
19.36
0
Time-
19.25 19.30
n—i—]—i—r
19.35
T I "T I—I—T—I—[—) r
19.40 19.45
Abundance
40000
30000
20000
10000
Time-->
TIC: ENG1675.D
0
21.50 21.60 21.70 21.80
21.62
40000
20000
IMS"
Time-
n—i—n—i—|—i—i—i—j—j—i—r
21.50 21.60
—i—i r—i—t—i—j 1—
21.70 21.80
#4
2-Methlynaphthalene-dl0
Concen: 0.65 ng/uL
RT: 19.36 min Scan# 756
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 152 Resp-. 62369
Ion Ratio Lower Upper
152 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#5
Ac enapht hy1ene-d8
Concen: 0.91 ng/uL
RT: 21.62 min Scan# 1296
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:160 Resp: 77157
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
ENG1'675 .D PES3 .M
Tue Oct 19 10:13:26 1999
HP 5989B
06Q • i
Page 4
-------
Abundance
80000 .
60000
40000
20000
0
20
3000
2000
1000
0
TIC: ENG1675.D
, 50' 2 X i 00'
T r-~] !—1 f 1 1 1 I ! I | I 1—T"
21.50 22.00 22150
Time-->
AbundanceIon 152.00 (151. 70 to 152 .'7 0")' : ENG
Ion 153.00 (152.70 to 153.70): ENG
u\
Ua.
Time- - > 20.50 21.00 21.50 22.00 22.50
TIC: MG1675.D
Sundance
80000
60000
40000
20000
Time21190 2 2 : 0 0 22!10
Abundanceton 164.00 (163.70 to 164.70)
22 .03
50000
r """1 F i \ 1 1 1 ¦ \ - | ¦ T1
Time- - > 2i:90 22.00 22.10
#6
Acenaphthylene
Concent 0.00 ng/uL
Expected RT; 21.66 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 152
Ion
152
153
0
0
Exp Ratio
100
13 .0
0.0
0.0
#7
Acenaphthene-dlO
Concen: 2.25 ng/uL
RT: 22.03 min Scan# 1357
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:164 Resp: 186310
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0,0 0.0 0.0
njM3
ENG1675.D PES3.M
-Tue~Ocl~T^rOTTTF2F~T¥W
HP 59S9B
Page 5
-------
kburidan.ee
100000
50000
TIC: ENGlbVS.D
Time - - > 21100 21 i 50' 22! do' 22! 50" 23 i do'
AbundanceIon 154.00 (153.70 to 154.70): ENG
Ion 153.00 (152.70 to 153.70): ENG
3000
2000
1000
1 ¦ - j"— r —r i i 1 1 i 1 1 | 1 1 1 1—]—1—1—1—I—I—1 T"
Time--> 21.00 21.50 22.00 22.50 23.00
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 22.12 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 154
Ion Exp Ratio
154 100
153 98.0
0 0.0
0 0.0
TIC: EHG1675.&
Abundance
100000 .
50000 -
Titne--> 23.20 23.30
Abundance Ion l?6.00 (175.70 to 176.70): ENG
23 .40
23 .30
100000 -
50000 _
Time-->
ENGlfcVb.D PEST7FT
23 .20
23.30 23.40
Tue Oct 19 10:13:32 1999
#9
Fluorene-dlO
Concen: 2.60 ng/uL
RT: 23.30 min Scan# 1549
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:176 Resp: 212910
Ion Ratio Lower Upper
176
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
HP 5989B Page 6
-------
TIC: EWG167S .t)
100000
50000 -
Time--> 22.50 23.00 23.50 24.00
SundanceIon 166.00 (165.10 to 166.70): fiMG
lion 165,00 (164.70 to 165.70): ENG
4000 J
2000 .
#10
Fluorene
Coneen: 0.00 ng/uL
Expected RT: 23.38 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 166
Ion Exp Ratio
166 100
165 91.3
0 0.0
0 0.0
Abundance
200000
150000
100000 J
50000
TIC: ENG1675.D
#11
Fiienant hr ene - dl 0
Concen: 3.00 ng/uL
RT: 25.67 min Scan# 1909
Delta R.T. -0.01 min
Lab Fxle: ENG1675.D
Acq:' 16 Oct 99 3:26 am
Tgt Ion:188 Resp: 347472
Ion Ratio Lower Upper
188 100
rime-->25 : 50 25:60 25 ! 70 25 . 80^
Abundance Ion I'SS.00 (187.70 to 188.70): ENG
Jlon 94.00 (93.70 to 94.70): ENG16
25.67
150000
100000
94
27 .2
12 .3
36.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
50000
Time-->25.50 25160 25 I 70 25 i 80
~Tue Oct 19 10:13:35 1999'
ENG1675.D—PES3.M
" y;
f k H • **
HP 5989B
-5 .
-------
Abundance
TIC: ENG1675.D
200000 :
150000:
100000 .
50000:
J
o:
Time-->24
.50 25!00
f " 1
25:50
1 t 1 1 1 ' 1 - 1 1 I
26.00 26.50
Abundance Ion 178.00 (177.70 to 178.70): ENG
1
Ion 176.00 (175.70 to 176.70): ENG
4000:
1
3000:
2000
1000
0
Time- - s24
'| i i I r r jr i
150 25100
' 1 '
25.50
' 1 ¦ 1 ¦ 1 1 ¦ 1 1 1 > 1
26.00 26.50
$2.2
Phenanthrene
Concen: 0.00 ng/uL
Expected RT: 25.74 min
Lab Pile: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ioil: 178
Ion Exp Ratio
178 100
176 20.2
• 0 0.0
0 0.0
Abundance
200000
150000
100000
50000
TIC: EHG1675.D
0
—i 1 1 r-
25.80
Time-->25 * 50 25.60 25.70
SundanceIon 188.00 (187.70 to 188.70): ENG
Ion 94.00 (93.70 to 94.70): ENG16
25.67
150000
100000
50000
0
Time-->25150 25:60
ENGXHT5—D—^
#13
Anthracene~dl0
Concen: 6.19 ng/uL
RT: 25.67 min Scan# 1909
Delta R.T. -0.15 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:188 Resp: 347472
Ion Ratio Lower Upper
188
100
94
27.2
13 .4
40 .0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
25 170 25!80
Tue Oct 19 10:13:39 1999
HP 5989B
Page 8
-------
Abundance
200000:
150000
100000
50000
TIC: ENG1675.D
1 1 1 1 ! 1 1 1 1 1 J 1 1 1 I ] 1 1—T"
Time--> 25.00 25.50 26.00 26.50
AbundanceIon 178.00 (177.70 to 178.70}: ENG
Ion 176.00 (175.70 to 176.70}: ENG
4000 ^
3000
2000 J
1000
0
Time-->
—i—I—i—'—!—i—|—i—i—r—T—|—i—i—f—i—|—i—
25.00 25.50 26.00 26.50
Abundance
200000
150000
Time - ->
"i—:—[ \ I—i—r—I—i—r—i—i—i—!—i—i—i—i—i—i—\—i—1—r
28.50 28.60 28.70 28.80
50000
0 .
Time--> 28150 28! 60 28170 28180
ENG1675.D—PES3 .M Tue Oct 19 10:13:42 1999'
#14
Anthracene
Concen: 0.00 ng/uL
Expected RT: 25.87 min
Lab Pile: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 178
Exp Ratio
100
19.9
0.0
0.0
TIC:ENG1575.D
100000
50000
#15
Pluoranthene-dl0
Concen: 3.03 ng/uL
RT: 28.67 min Scan# 2368
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3;26 am
Tgt Ion:212 Resp: 320885
Ion Ratio Lower Upper
212
100
106
30 .2
13 .7
41.0
0
0.0
0.0
0.0
0
0.0
0 . 0
0.0
jkbundancelon 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70): ENG
150000" 28"67
100000
HP 5989B
Page 9
-------
Abundance
200000 j
150000
100000
50000
1 1 1 1 5 1 I ! 1 ! TT 1 j 1 1 1 ! J ! 1 J T"
Time-->27.50 28.00 28.50 29.00 29.50
TIC: EMG1S75.D
Abundance Ion 202.00 (201.70 to 202.70): fiNG
60000 -flon 101.00 (100.70 to 101.70): ENG
40000
20000
~i—i—i—f—?—r~i—i—j—|—i—i—i—i—r—i—i—j—i—r—!—r—r~
Time-->27!50 28.00 28.50 29.00 29.50
Abundance
200000
150000
100000
50000 J
TIC: EMG1S75.D
Time--> 29.00
Abundance Ion
Ion 106.00
150000
100000
50000
Time - - > 29.00
ENG 1675 ;D—PES3 .M"
29.20 29.40
{211.70 to 212.70}
(105.70 to 106.70)
29 .28
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 28.73 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion;
Ion
202
101
0
0
202
Exp Ratio
100
24.0
0.0
0.0
#17
Pyrene-dlO
Concen: 2.80 ng/uL
RT: 29.28 min Scan# 2459
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:212 Resp: 330665
Ion Ratio Lower Upper
212
100
106
34 m 3
15 .9
47 .5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
ENG
000.!?;
29.20 29,40
¦rue uct iy iu: ij:4b iyyy
HP 5989B
¦LJL'iJ
Page 10
-------
Abundance
200000
TIC: ENG1675.D
150000
100000
50000
Time - - > *28 ! 50' 29 I do" '29 !so' '3o!o'o' ' -
Abundance Ion 202.00 (201.70 to 202.70): EtfG
60000 Jion 101.00 (100.70 to 101.70): ENG
40000
20000 -
0
J-
Time-->
T 3 ! 1 ' I' '"I 1 1 1 5 1 1 1 1 ! 1 J 1 1 J V
28.50 29.00 29.50 30.00
Abundance
100000
TIC: 2MG1575.D
50000 .
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 29.34 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:
Ion
202
Exp Ratio
100
27.6
0.0
0.0
#19
p-Terphenyl-dl4
Concen: 1.39 ng/uL
RT: 29.61 min Scan# 2509
Delta R.T. -0.01 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:244 Resp*. 132451
Ion Ratio Lower Upper
Time--> 29:40 29.60 29,80
AbundanceIon 244.00 (243.70 to 244.70): EMS
Hon 122.00 (121.70 to 122.70): ENG
29.61
60000 J
40000
244
100
122
33.0
14.6
43 .7
0
0.0
0.0
0.0
0
0.0
0.0
0.0
20000
0
"T
Time--> 29.40
ENG1675.D PES3.M
r
29.60 29.80
Tue Oct 19 10 ":"I3 : 4"S' "19 '9 9'
HP 5989B
Page 11
-------
80000:
60000:
20000 4
33 :30
33 140
Time-->33.20
60000 :
40000:
33 .34
20000 -
33 130
33 .40
Time-->33.20
#20
Benzo(a)anthracene-dl2
Concen: 1.81 ng/uL
RT: 33.34 min Scan# 3069
Delta R.T. -0.02 min
Lab File: SNG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:240
Ion Ratio
240 100
120 30.1
0 0.0
0 0.0
Resp: 79150
Lower Upper
14.0 41.9
0.0 0.0
0.0 0.0
Abundance
80000
60000
40000
20000
TIC: ENG1675.D
Tine--> 32 ! 50 33 . 00 33 .50 34.00
Abundance Ion 228.00 (227.70 to 228.70): EMS
lion 114 .00 (113 .70 to 114.70) : SNG
20000 ,
10000 H
r—i—i—j—r*n—i—r ¦ r r"- i—i—i' 1 "i i—i—s—i—r—i—i—i—r
Time--> 32.50 33.00 33.50 34.00
#21
Benzo(a)anthracene
Concen; 0.00 ng/uL
Expected RT: 33.46 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 228
Ion Ixp Ratio
228 100
114 25.4
0 0.0
0 0.0
ENG1675 . D—PES3TFT
|||^ .i i i iij. ^"*^1
HP 5989B
000.1115
Page 12
-------
Abundance
80000
60000
40000
20000
TIC: ENG1675 .D
Abuo.dg.OCe Ion 240.00 (239.70 to 240.10) •. ENG
Ion 120.00 (119.70 to 120.70): ENG
33.48
eoooo:
40000
20000
Time - - > 33.20
33.40
33.60
#22
Clirysene-dl2
Concen: 2.85 ng/uL
RT: 33.48 min Scan# .3090
Delta R.T. -0.02 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion;240
Ion Ratio
240 100
120 28.1
0 0.0
0 0.0
Resp: 224121
Lower Upper
13.7 41.0
0.0 0.0
0.0 0.0
[Abundance
80000
60000
40000
20000
0
TIC: ENGlb/S.D
' i1 1
33 .00
Time-->32.50
AbundanceIon £26.00
Ion 114.00
20000
10000
r—\—| i i i "v | i—i—i—i—|—s—r
33.50 34 I 00 34 I 50
[227.70 to 228.70): fiMG
[113.70 to 114.70): ENG
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.61 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 228
Ion Exp Ratio
228 100
114 22.3
0 0.0
0 0.0
—L.
""i"" ) i—i—i—i' i "i'' i—[—r—i—r-"T—|—i—i—i—i—|—i—r
frime-->32150 33.00 33.50 34.00 34.50
ENG1675.D—PES3.M
'i'ue Oct 19 10:13:55 1999
HP 5989B
O
Page 13
-------
Abundance
TIC: UJG1675.D
40000 -
A . A
20000 .
J \J
0 -
Time - - >
L i 1 j i t t 1 f 1 1 1 i 1 I i f 1 j 1
39.20 39.30 39.40
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
39 . 33
30000
AN a
20000
/ \ A
10000
AAA
0 .
——r
Time-->
"f ' r I 1 S i 1 J [ ! 1 1 1 ]' ! ! ! 'i j 1'"
39.20 39.30 39.40
#24
Benzo(b)fluoranthene~dl2
Concen; 3.16 ng/uL m
RT; 39.33 min Scan# 3988
Delta E.T. -0.03 min
Lab File: ENG1675.D
Acq: IS Oct 99 3:26 am
Tgt Ion:264 Resp: 153020
Ion Ratio Lower Upper
264 100
132 44.6 34.8 104.2
0 0.0 0.0 0.0
0 0.0 0.0 0.0
TIC: ENG1675.D
40000
20000
38:50
39:o'o' '39!50 40:00
Time-
ESundaocelon 252.00 (251.70 to 252.70}: ENG
Ion 126.00 (125.70 to 126.70): ENG
3000
2000
1000:
0
Time-->
1—T p—r | ] ! r—!—T 1 T ] S ! ! J j ? T
38.50 39.00 39.50 40.00
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.52 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 252
Exp Ratio
100
27.8
0.0
0.0
ENG1675.D—PES3,M
Tue Oct 19 10:13:58 1999
HP 5989B
1 rs. ~ r. .
Page 14
-------
Abundance
TIC: EHG1675.D
40000
20000
Tittle -->39.20
39.40
T [ 1 [ 1 r~
39160
Abundance Ion 264.00 {263.70 to 264.70): MS
JIon 132.00 (131.70 to 132.70): ENG
30000
20000
10000 .
39.50
It.
ime-->39.20
39.40
39.60
Time-
Woun
-r—r—i—|—r-
39.00
t—|—\—i—i—i—t—r—i—i—1~
39150 40.00 40.50
elon 252.00 (251.70 to 252.70): MQ
Ion 126.00 (125.70 to 126.70): ENG
3000
2000
1000
0
Time-->
ENG'l 6 7 5 . D
"T—i—i—r—!—r
39 .00
PES3.M
I I-
#26
Benzo(k)fluoranthene-dl2
Concen: 2.82 ng/uL
RT: 39.50 min Scan# 4015
Delta R.T. -0.03 min
Lab Pile: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:264 Resp: 137768
Ion
264
132
0
0
Ratio
100
35.9
0.0
0.0
Lower Upper
18.0
0.0
0.0
53.8
0.0
0.0
TIC: fiNGl67S.D
40000
20000
#27
Benzo
HP 5989B
Page 15
-------
Abundance
TIC: ENG1675.'D
15000 :
10000:
5000 .
Abundance ion 264.00 (263.70 to 264.70): ENG
Jlon 132.00 (131.70 to 132.70): ENG
4000 -
2000
Time--> 40.50 41.00 41.50 42.00 42.50
#28
Benzo (a) pyrene-dl2
Conceii: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 264
Ion Exp Ratio
264 100
132 37.8
0 0.0
0 0.0
Abundance
15000
10000
5000 J
TIC: BMG1675.D
Time--> 41.00 42.00 43.00
Abundance I on 252.00 (251.70 to 252.70): Sll56
Ion 126.00 (125.70 to 126 .70) : ENG
5000 .
0 .
Time*
41. 00
-t 1 1 r
42.00
43.00
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 41.79 min
Lab File: SNG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 31.2
0 0.0
0 0.0
ENG1675 .D—PES'XTM""
¦l'ue Oct iy 10:14:0b iyyy
HP 5989B
s *¦ • 1 ^
Page IS
-------
[Abundance TIC: ENG1S75.D
20000:
15000
10000
5000
0
Time--> 52!20 52140 52 I€0 '
Abundance Ion 288.00 (287.70 to 288.70): ENG
52 .47
Tirae-
8000
6000
4000
2000
52:20
52 .40
52160
Abundance
20000
15000
10000
5000 4
0
TIC: EMG1675.D
n 1 1 1 r
rime--> 52100 53.00 54 100
Abundance Ion 276.05 (275.75 to 276.75): ENG
jlon 138.00 (137.70 to 138.70): ENG
2000
1000
Time--> 52 100
ENGTF75TD—FEST7R
i 1 r-
54.00
#30
Indeno(1,2,3-cd)pyrene-dl2
Concen: 1.78 ng/uL m
RT: 52.47 min Scan# 6013
Delta R.T. -0.06 min
Lab Pile: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion*.288 Resp: 51041
Ion Ratio Lower Upper
288
100
0
0 . 0
0.0
0.0
0
0 . 0
0.0
0.0
0
0.0
0.0
0.0
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 52.82 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 60.1
0 0.0
0 0.0
53 .00
Tue Oct 19 10:14:UB 1999
51120
HP 59891
Page 17
-------
Abundance
20000
TIC: ENGl675.D
15000
ioooo :
5000
52 .60
"T—1 r
52 .20
T—-r
52 140
Time-->
Abundance Ion 292.00 (291.70 to 292.70): ENG
6000:
4000:
2000
52.45
rime-
52 .20
52 .40
52.60
TIC: 2NGl6?5.E>
2000
1000
E
xme-->
52 .00
53 .00
54.00
#32
Dibenz{a,h)anthracene-dl4
Concen: 1.97 ng/uL m
RT: 52.45 rain Scan# 6008
Delta R.T. -0.05 min
Lab File; ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt lOO:292 Resp: 34773
Ion Ratio Lower Upper
292
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
20000
15000
10000
5000 '
Time--> 52.00 53.00 54.00
AbundanceIon 278.00 (277.70 to 278.70): ENG
#33
Dibenz (a, h)anthracene
Concen: 0.00 ng/uL
Expected RT: 52.87 min
Lab File: 3NG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 278
Ion Exp Ratio
278 100
139 53.6
0 0.0
0 0.0
Ion 139.00 (138.70 to 139.70): 1NG
ENGl675.D—PES3 ,M
Tue Oct 19 10:14:11 1999
0Ge.'iii
HP 5989B Page 18
-------
Abundance
TIC: ENG1675.D
10000 -
l/\
5000 J
o .
1 t t 1 i 1 1 ! t 1 j I i i j s I J t j i i i i
rime--> 55.00 55.20 55.40 55.60 55.80
Abundancelon 288.00 (287.70 to 288.70): ENG
8000 :
55.46
6000:
A
4000:
/ \
2000:
y
0 -
1 1 ! ! ? ! | 1 1 1 1 11 S 1 i l l 1 i j 1 ! 1 ;
Time--> 55.00 55.20 55.40 55.60 55.80
#34
Benzo(g,h,i)perylene-dl2
Concen: 1.93 ng/uL
RT: 55.46 min Scan# 6577
Delta R.T. -0.06 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion:288 Resp: 58818
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
10000
5000
TIC: 1NG1675.D
0
Time-->
Abundance
55.00
-i 1 r
56.00
57.00
2000
1000
ton 27S.00 (275.70 to 276.10): ENS
Ion 138.00 (137.70 to 138.70): ENG
#35
Benzo(g,h,i}perylene
Concen*. 0.00 ng/uL
Expected RT: 55.84 min
Lab File: ENG1675.D
Acq: 16 Oct 99 3:26 am
Tgt Ion: 276
Ion Exp Ratio
276 100
138 16.2
0 0.0
0 0.0
Time--> 55.00
ENG'1675 .D—PESTTW
-i 1 1 r
56.00
57.00
'me Oct 19 10:14:1b 1999
HP 5989B
HVd.::#
Page 19
-------
ENG1676.XLS
Quantitation Report Summary
Data File
ENG1676.D
Date Analyzed:
10/16/991
Sample ID
CARB429.0UTLE
r FIELD BLANK
Method ID
PES3
Operator
Instrument
HP 5989B
Compounds
Area
Cone.
PQL*
Cone.
Cone, (ng/sample)
Diluted result
(ng/pL)
(ng/pL)
{ng/sample)
w/ Surr. correction
ng/sample
Naphthalene(CCC)
116176
0.378
0.1
37S
965
0
Acenaphthylena
0
0.000
0.1
0
0
0
Acenaphthene(CCC)
0
0.000
0.1
0
0
0
Fluorene
0
0,000
0,1
0
0
0
Phenanthrene
3336
0.023
0.1
23
29
0
Anthracene
4961
0.057
0.1
57
69
0
Fluoranthene(CCC)
0
0.000
0.1
0
0
0
Pyrene
0
0.000
0.1
0
0
0
Benzo(a)anthracene
0
0.000
0.1
0
0
0
Chrysene(CCC)
0
o.ooo
0.1
0
0
0
Benzo(b)fluorar.thene
0
0,000
0.1
0
0
0
Benzoik)fluoranthene
0
0.000
0.1
0
0
0
Benzo(a)pyrenefCCC)
0
0.000
0.1
0
0
0
lndeno(1,2,3-cd)pyrene
0
0.000
0.1
0
0
0
Dibenz(a,h)arrthracene
0
0.000
0.1
0
0
0
Benzo(g ,h,i)perylene
0
0.000
0.1 I 0
0
0
I
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Cone, (ngf
|iL)
% Recovery
Naphthalene-d8
1.56
39
Aeenaphthylene-d8
2.30
57
Acena phthene-d 10
2.94
73
Fluorene-d10
3.14
78
Phenanthrene-d10
3.23
81
Anthracene-d10
3.29
82
Fluoranthene-d10
3.36
84
Pyrene-d10
3,37
84
Benzo(a)anthracene-d 12
5,18
130
Chrysene-d12
3,28
82
Benzo(b}(luoranthene-d 12
4,52
113
Benzo(k)fluoranthene-d 12
5.49
137
Benzo7 / // / / .
Reviewed by:
,r /
Reviewed by:
I I I
000.1133
-------
Quantitation Report
Data File : C:\HPCHEM\1\DATA\ENG1676.D
Acq On : 16 Oct 99 4:32 am
Sample : CARB429,OUTLET FIELD BLANK
Misc :
Quant Time: Oct 19 10:17 1999
Method : C:\HPCHEM\l\METH0DS\PES3.M
Title :
Last Update : Tue Nov 23 19:47:37 1999
Response via : Multiple Level Calibration
Internal Standards R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.98
190
477763
5.00 ng/uL -0.02
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
17 . 67
136
422760
1.56 ng/uL 39.11%
4)
2-Methlynaphthalene-dlO
19-35
152
109804
1.17 ng/uL 58.52%
5)
Acenaphthylene-d8
21.62
160
190448
2.30 ng/uL 57.38%
7)
Acenaphthene-dl0
22 . 03
164
238717
2.94 ng/uL 73.46%
9)
Fluorene-dlO
23.30
176
251982
3.14 ng/uL 78.46%
11)
Phenanthrene-dl0
25.68
188
366811
3.23 ng/uL 80.71%
13)
Anthracene-dlO
25 .81
188
180743
3.29 ng/uL 82.18%
15)
Fluoranthene-dlO
28 .67
212
349073
3.36 ng/uL 84.10%
17)
Pyrene-dlO
29 .28
212
390512
3.37 ng/uL 84.27%
19)
p-Terphenyl-dl4
29 .61
244
132885
1.43 ng/uL 71.37%
20)
Benzo(a)anthracene-dl2
33 .34
240
222503
5.18 ng/uL 129.57%
22)
Chrysene-dl2
33 .49
240
252397
3.28 ng/uL 81.96%
24)
Benzo(b)fluoranthene-dl2
39.33
264
214905
4.52 ng/uL 113.11%
26)
Benzo(k)fluoranthene-dl2
39.49
264
262471
5.49 ng/uL 137.21%
28)
Benzo(a)pyrene-dl2
41.58
264
107922
4.25 ng/uL 106.28%
30)
Indeno(1,2,3-cd)pyrene-dl2
52.47
288
107908
3.83 ng/uL 95.86%
32)
Dibenz(a,h)anthracene-dl4
52 .44
292
71366
4.13 ng/uL 103.37%
34)
Benzo(g,h,i)perylene-dl2
55 .47
288
102234
3.43 ng/uL 85.64%
Target Compounds
Qvalue
3)
Naphthalene(CCC)
17 .72
128
116176
0.38 ng/uL 100
S)
Acenaphthy1ene
0 .00
152
Not Detected
8)
Acenaphthene(CCC)
0.00
154
Not Detected
10)
Fluorene
0.00
166
Not Detected
12)
Phenanthrene
25 .58
178
3336
0.02 ng/uLm 56
14)
Anthracene
25.73
178
4961
0.06 ng/uLra 0
16)
Fluoranthene(CCC)
0 .00
202
Not Detected
18)
Pyrene
0.00
202
Not Detected
21)
Benzo(a)anthracene
0.00
228
Not Detected
23)
Chrysene(CCC)
0.00
228
Not Detected
25)
Benzo(b)fluoranthene
0.00
252
Not Detected
27)
Benzo(k)fluoranthene
0.00
252
Not Detected
29)
Benzo(a)pyrene(CCC)
0.00
252
Not Detected
31)
Indeno(1,2,3-cd)pyrene
0 .00
276
Not Detected
33)
Dibenz(a,h)anthracene
0.00
278
Not Detected
355
Benzo(g,h,i)perylene
0.00
276
Not Detected
(#5 = qualifier out of range (m) = manual integration
ENG1676.D PES3.M Tue Nov 23 19:55:37 1999 HP 5989B
Vial: 16
Operator:
Inst : HP 5989B
Multiplr: 1,00
OOP 1
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
Method
Title
Last Update
Response via
C:\HPCHEM\l\DATA\ENG1676.D
16 Oct 99 4:32 am
CARB429,OUTLET FIELD BLANK
Oct 19 10:17 1999
: C:\HPCHEM\l\METHODS\PES3.M
Hon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
16
HP 5989B
1.00
TreniGHTF^"
300000
280000 :
260000" 2s
17S
lis
240000 ;
220000 :
180000 :
160000 J
9s
Us
7S
9S
22s
20s
5s
26s
24s
80000 :
60000 :
28s
34s
20000 :
20100 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0003155
ENG1676.D PES3.M
Tue Oct 19 10:18:30 1999
HP 5989B
Page 2
-------
Abundance
200000
150000 :
100000:
50000
'TIC: BMG1676.D
0
Time--> 17.40
17 .60
j r-
17.80
Abundance
200000
150000
100000
50000:
TIC: ENG1676.D
Time--> 17;60 17.70 17180
Sundance Ion 128.00 (127 .70 to 128 .70) :
#2
Naphthalene-d8
Concen: 1.56 ng/uL
RT: 17.67 min Scan# 248
Delta R.T, -0.03 min
Lab File: ENG1676.D
Acq; 16 Oct 99 4:32 am
Tgt Ion:136 Resp: 422760
Ion Ratio Lower Upper
0
Time--> 17140 17160 17180
Abundance ton 135.00 (135.70 to 13(5.70) : EWG
Ion 68.00 (67.70 to 68.70): ENG16
200000 H 17.67
150000
100000
50000
3. ^5
100
68
20.2
7.7
23.0
0
0.0
0 . 0
0.0
0
0.0
0.0
0.0
Ion 127.00
60000 :
40000
20000
(126.70 to 127.70)
17.72
115"
ENG
#3
Naphthalene(CCC5
Concen: 0.38 ng/uL
RT: 17.72 min Scan# 256
Delta R.T. -0.02 min
Lab File: ENG1676 .D
Acq; 16 Oct 99 4:32 am
Tgt Ion:128 Resp: 116176
Ion Ratio Lower Upper
128 100
127 13.1 0.0 63.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 -•
000.11;;
. Vj >
[Time- - > 17 160
ENGI676. D—PES3.M
17 .70 17.80
Tue Oct 19 10 :18 : 33 1999'
HP 5989B
Page 3
-------
TIC: ENG157S.D
40000 .
20000
Time-->
Abundance Ion 152.00
60000 ,
19,30
19.40
(151.70 to 152.70): ENG
19.35
40000
20000 -
19.30
19.40
#4
2 -Methlynaphthalene-dlO
Concen: 1.17 ng/uL
RT: 19.35 min Scan# 754
Delta R.T. -0.02 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:IS2 Resp: 109804
Ion Ratio Lower Upper
152
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
80000
60000 4
40000
20000
TIC: EMG1676.D
Time-
21.40
i " i 1 r~
21.60
21.80
#5
Acenaphthylene-d8
Concen: 2.30 ng/uL
RT: 21.62 min Scan# 1295
Delta R.T. -0.01 min
Lab Pile: SNG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:160 Resp: 190448
Ion Ratio Lower Upper
160 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
AbundanceIon 160.00 (155.70 to 160.70}: ENG
100000
21.62
50000
m" \
Time-->
ENG1676.D
i—r
21.40
PES3.M
21.60 21180
Tue Oct 19 10:18:36 1999'
HP 5989B
Page 4
-------
Abundance
100000
50000
0
TIC: 1HG167S.D
Time - - > 20:s'o' *21! Oo" 2ll50 22 ioo' 2i2 i 5 0'
Abundance Ion 152.00 (l5l.70 to 152,70): ENG
Ion 153,00 (152.70 to 153.70): ENG
4000
3000:
2000
1000
0
—t—i—f—i—|—i—!—i—i—j—i—r—i—i | i i—!—i | »—r
Time-->20l50 21.00 21.50 22.00 22.50
Abundance
100000
TIC: ENG1676.D
50000
0
100000
50000
22.03
Time-->
ENG1676.D
21.90
FES3 . M"
#6
Acenaphthylene
Concen: 0.00 ng/uL
Expected RT: 21.66 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 152
Exp Ratio
100
13 .0
0.0
0.0
Time--> 21190 22.00 22.10
Abundance Ion 164.00 (l63 . 70 to 164 .70) : ENG
#7
Acenaphthene-dl0
Concen: 2.94 ng/uL
RT: 22.03 min Scan# 1356
Delta R.T. -0.01 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:164 Resp: 238717
Ion Ratio Lower Upper
164 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
oc
22.00 22110
Tue Oct inu:iB:39 iyyy'
HP 5989B
Page 5
-------
Abundance
100000 -
50000
TIC: ENG1S75.D
Time--> 21 lo'o' 21! 50' 22 ! 00' 22 ! 50 23 ! 00'
Abundanc e I on 154.00 (153.70 to 154 . 70) : ENG
4000
3000
2000
1000
0
loll 153.00 (152,70 to 153.70): ENG
[Time-
T" ¦ r i i [ t i { I j I I I I | I ( i i ^ 1 I
•> 21.00 21.50 22,00 22.50 23.00
Abundance
100000
50000
TIC: fiNGl€76.D
0
—i—j—i—!—i—(—j—t—i—\—r
23.30 23.40
Time--> 23.10 23.20
Abundance Ion 176.00 (175.70 to 176.70)
"W
23 .30
100000
50000
0
'"" I ' 1
23.10
Time - - >
ENG1676.D PES3.M
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 22.12 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 154
Ion Exp Ratio
154 100
153 98.0
0 0.0
0 0.0
#9
Fluorene-dlO
Concen: 3.14 ng/uL
RT: 23.30 min Scan# 1547
Delta R.T. -0.01 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:176 Resp: 251982
Ion Ratio Lower Upper
176
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
^ \rQ
23;20 23 130 23.40
Tue Oct 19 10 : IB : 43 1"599"
HP 5989B
Page 6
-------
TIC: ENG1676.D
100000 -
50000 .
rime--> 22.50 23.00 23.50 24.00
Abundance Ion 166.00 (165.70 to 166.70); 1NG
Jlon 165.00 (164.70 to 165.70): ENG
3000:
2000:
iooo :
Time - - >
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 23.38 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 166
Ion Exp Ratio
166 100
165 91.3
0 0.0
0 0.0
[Abundance
200000
150000
100000
50000
TIC: BNG1676.I3
#11
Piienan thr ene - dl 0
Concen: 3.23 ng/uL
RT: 25.68 min Scan# 1908
Delta R.T. -0.01 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 188 Resp-. 366811
Ion Ratio Lower Upper
! 1
25:80
Time--> 25.50 25.60 25.70
Abundance Ion 188.00 (187.70 to l§8.70) : ElJG
188
100
94
27.4
12 .3
36.8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
200000 Jlon 94.00
150000
(93.70 to 94.70): ENG16
25.68
100000
50000
Time
ENG16 7 6 . D
0 ¦ , , , ,
> 25150 25160 ' 25170 ' 25 180
PES3 .M Tue Oct 19 10:18:46 19T3
jf* ^ -Z-
HP 5989B
Page 7
-------
abundance
TIC: ENG1676.D
200000:
f
150000:
.
100000
50000
J
0 _
Time--> 25150 ' ' 25!55 ' ' 25160 ' ' 25.65
Abundancelon 178.00 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
25.58
4000
#12
Phenanthrene
Concen: 0.02 ng/uL m
RT: 25.58 min Scan# 1894
Delta R.T. -0.16 min
Lab File: ENG1676.D
Acq: IS Oct 99 4:32 am
Tgt Ion:178 Resp: 3336
Ion Ratio Lower Upper
178 100
176 59.7 10.2 30.4#
0 0.0 0.0 0.0
0 0.0 0.0 0.0
2000
1 r—i 1 r [ 1 1 ; 1 'i i i" i ? 1 1 1—
frime--> 25.50 25.55 25.60 25.65
Abundance
200000
TIC: ENG1676.D
150000
100000
50000
#13
Anthracene-dlO
Concen -. 3.29 ng/uL
RT: 25.81 min Scan# 1929
Delta R.T. -0.01 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:188 Resp: 180743
Ion Ratio Lower Upper
Time--> 25:60 25180 26.00
AbundanceIon 188.00 (187.70 to 188.70): EUG
188
100
94
29.6
13 .4
40.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
200000
150000
100000
50000
94.00 (93.70 to 94.70): ENG16
Time-->
ENGT5T6TD"
25.81
008.113!
25.60
25180 26.00
Tub Oct 19 10 : IB :49 1999'
HP 5989B
Page 8
-------
TIC:ENG1676.D
200000 :
150000
100000
50000
Time - ->25.65
25.70
25 .75
25 .80
Abundance Ion 178.00
6000 -,ion 176 .00
4000
;i77.70 to 178.70}: ENG
; 175.70 to 176.70} : ENG
25 .73
2000
0
Time-->25.65
25.70
25.75
25 .80
#14
Anthracene
Concen: 0.06 ng/uL m
RT: 25.73 min Scan# 1917
Delta R.T, -0.14 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:178 Resp:
Ion
178
176
0
0
Ratio
100
59.5
0.0
0.0
4961
Lower Upper
10.0
0.0
0.0
29.9#
0.0
0.0
Abundance
200000
150000
100000
50000 J
TIC: EMG167S.D
Time-
"i—r~n—r
28.50 28.60 28.70 28.80
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 {105.70 to 106.70}: ENG
28.67
150000
100000
50000
Time*
#15
Flu oranthene-dl0
Concen: 3.36 ng/uL
RT: 28.67 min Scan# 2367
Delta R.T. -0.01 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:212 Resp: 349073
Ion
212
106
0
0
Ratio
100
31.9
0.0
0.0
Lower Upper
13 .7
0.0
0.0
41.0
0.0
0.0
28150 28.60 28.70 28.80
ENGT5T67D—PES 3"". M"
A
Tue Oct 19 10:18:51 1999
HP 5989B
Page 9
-------
Abundance
200000 :
150000 :
100000
50000
o X
TIC: ENG1S76.D
Time-->27.50 28100 28.50 29.00 29.50
AbundanceIon 202.00 (201,70 to 202.70); ENG
-lion 101.00 (100.70 to 101.70): ENG
20000
10000
Time-->27 : 50 28 J do' '28 1 so' 29 I 00' 29^50
Abundance
200000
150000
100000
50000 .
TIC: ENG1676 . D
Time-->29.00
29.20 29.40
Abundance Ion 212.06 (211.70 to 2l2.?05: 2UG
I 200000 lion 106.00 (105.70 to 106.70): ENG
#16
Fluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 28.73 min
Lab Pile: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 202
Ion Exp Ratio
202 100
101 24.0
0 0.0
0 0.0
29 .28
150000
100000 J
50000
#17
Pyrene-dlO
Concen: 3.37 ng/uL
RT: 29.28 min Scan# 2458
Delta R.T. -0.01 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:212 Resp: 390512
Ion Ratio Lower Upper
212
100
106
35.2
15 .9
47.5
0
0.0
0.0
0.0
0
0.0
0.0
0.0
¦ Time-->29.00
ENG1676.D PES3.M
29.20 29.40
Tue Oct 19 10:18:55 1999'
HP 5989B
«.ii33
Page 10
-------
Abundance
200000
150000
100000
50000
Time-
TlC: ENGlbVb.D
¦| | 1' »'
28 ,50
1 »'
29 .00
-i—i—|—i—I—i—i—|—i—i—i—r
29.50 30.00
abundance Ion 202.00 (201.16 to 202.70) : 1US
jlon 101.00 (100.70 to 101.70): ENG
20000
10000
Time-
28.50 29.00
"i—r-i—i—m—j—|—i—r
29 . 50 30100
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 29.34 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.6
0 0.0
0 0.0
Abundance
100000
50000
TIC: ENG1676.D
#19
p-Terphenyl-dl4
Concen: 1.43 ng/uL
RT: 29.61 min Scan# 2508
Delta R.T. -0.01 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:244 Resp: 132885
Time--> 29.40 29.50
-i—r~
29 1 60
29.80
Ratio
100
33 .5
0.0
0 . 0
Lower Upper
14.6 43.7
0.0 0.0
0.0 0.0
Abundance Ion 244 .'00
Ion 122.00
60000:
40000 .
(243.70 to 244.70):
(121.70 to 122.70):
29.61
ENG
20000
0 4*
-I 1 1 1 1 1 ! 1 1 E !—I 1 1 1 1 1 1 1 J 1
Time --> 29140 29.50 29160 29170 29.80
ENG1676.D—FES3.M
Tue Oct 19 10:18:58 1999
HP 5989B
Page 11
-------
Abundance
100000
TIC: EMG1676.D
50000
33:40
Time--> 33 120 33,30
Abundance Ion 240.00 (239.70 to 240.70}: ENG
80000
60000
40000
20000
0
Ion 120.00 (119.70 to 120.70); ENG
33.34
Time--> 33.20
33 130
33 .40
Abundance
100000
50000
! i I 1 1 | ! t ! ! 1 . i ! 1 1 1 ! I I
32150 33.00 33.50 34100
#20
Benzo(a)anthracene-dl2
Concen: 5.18 ng/uL
RT: 33.34 min Scan# 3068
Delta R.T. -0.02 min
Lab File: ENG1676.D
Acq: 16'Oct 99 4:32 am
Tgt Ion:240 Resp: 222503
Ion Ratio Lower Upper
240
100
120
31.3
14.0
41.9
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1676.D
Time - - >
Abundance Ion 228.00 (227.70 to 228.70): ENG
60000
40000
20000
0
Ion 114.00 (113.70 to 114.70)
Time-->
ENGlfeVb.D
T 1 ! 1 ! 1 ! 1 ! !—
32150 33.00
¦FES3TM"
i—!—t—i—r~i—r—i—i—i—r"f"
33.50 34.00
'me Uct iy 10:19:01 iyyy
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 33.46 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 228
Exp Ratio
100
25.4
0.0
0.0
00
0 -z;
HP 5989B
Page 12
-------
Abundance
100000 J
Time-->
50000
TIC: ENG167 6.D
33 .40
33 .60
Abundance Ion 240.00 (239.70 to 240.70): ENG
80000
60000
40000
20000
Ion 120.00 (119.70 to 120.70): ENG
33 .49
Time-->
"T I >
33 .40
33.60
Abundance
100000
TIC: ENG1676.D
50000
—?—f—i—i—p-1—i——i—5—i
33.50 34.00 34.50
Time-->32!50 33 I 00
Abundance Ion 228.00 (257.70 to 228.70)
60000
#22
Ch.rysene-dl2
Concen: 3.28 ng/uL
R.T: 33.49 min Scan# 3090
Delta R.T. -0.01 rain
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:240 Resp: 252397
Ion Ratio
240 100
120 27.8
0 0.0
0 0.0
Lower Upper
13 .7
0.0
0.0
41.0
0.0
0.0
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.61 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 228
Ion Exp Ratio
228 100
114 22.3
0 0.0
0 0.0
40000
20000
Time-->32.50
ENGXF75TD—PES3 .M
Ion 114.00 113.70 to 114.70): ENG
000.1136
33 lo'o" 33:50 34:00 34:50
Tue Oct iy 10:iy:04 1999
HP 5989B
Page
-------
Tic: ENG1676.D
80000
60000 -
40000:
20000 -
39120
39 .30
Time-->
Abundance I on 264,06 (263.70 to 264.70): ENG
60000 -:Ion 132.00 (131.70 to 132.70); ENG
39140
39 .33
40000 -
20000 -
39 .20
39.30
39.40
#24
Benzo (b) £luoranthene-dl2
Concen; 4.52 ng/uL m
RT: 39.33 mill Scan# 3987
Delta R.T. -0,03 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:264
Ion Ratio
264 100
132 41.5
0 0.0
0 0.0
Resp: 214905
Lower Upper
34.8 104.2
0.0 0.0
0.0 0.0
Abundance
80000
60000
Time-
40000
20000
TIC: ENGl676.fi
#25
Benzo(b)fluoranthene
Concen; 0.00 ng/uL
Expected RT: 39.52 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:
Ion
38.50 39.00 39.50 40.00
252
Exp Ratio
100
27.8
0.0
0.0
Abundance Ion 252.00 (251.76 to 252.70): 1NG
4000jIon !26.00 (125.70 to 126.70)
3000:
2000
1000
o:
ENG
A.i.m'»i*
Time-
t—!—I—i—r—!—s—|—i—i—i—i—I—i—i—i—r
38.50 39.00 39.50 40100
T TiI
ENG1676.D PESJ.M
*. :
.JL4
e
•iue uct iy iu;iy;U7 lyyy
HP 5989B
Page 14
-------
Abundance
80000
60000:
rime--239 -20
40000
20000
Tic: ENG1676.D
39 .40
39.60
AbundanceIon 264.00 (263.70 to 264.70): ENG
60000 -lion 132,00 (131.70 to 132.70): ENG
39.49
40000
Time
1 1 1
39.40
20000
39.60
#26
Benzo(k)fluoranthene-dl2
Concen: 5.49 ng/uL
RT; 39.49 min Scan# 4013
Delta R.T. -0.03 min
Lab Pile: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:264
Ion Ratio
264 100
132 37.1
0 0.0
0 0.0
Resp: 262471
Lower Upper
18.0 53.8
0.0 0.0
0,0 0.0
Abundance
80000
60000
40000
TIC: 1MG157S.D
20000
0
Time-->
39 .00
r ' i 1 '
39.50
40.00 40.50
[AbundanceIon 252.00 {251.70 to 252.70): ENG
4000 JI°n 126.00 (125.70 to 126,70): ENG
3000
2000
iooo :
Time-->
ENG16"76;TJ~
! !—I—1—I—I—1—!—I—I—t—J 1 !—1 1 1 1 1 1—1—T—r~
39,00 39.50 40.00 40.50
TTJST7M
#27
Benzo(k)fluoranthene
Concen-, 0.00 ng/uL
Expected RT: 39.67 min
Lab Pile: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 27.6
0 0.0
0 0.0
00
Tub Oct 19—1 0 • 19 ¦ XX 19 9 9
HP 5989B
r. '¦>
Page 15
-------
Abundance
•L X « hit ^ 7
.£)
30000:
20000 J
10000:
0:
Time--> 41.20
S 1 1 J t >. t ! ] 1 1
41.40 41.60
1 ! [till
41.80
Abundance Ion
264.00 (263.70 to
264.70): ENG
Ion
132.00 (131.70 to
132.70): ENG
20000
41.58
15000
10000
5000
0 .
Time--> 41.20
41.40 41.60
1 1 1 1 I i I
41.80
#28
Benzo(a)pyrene-dl2
Concen: 4.25 ng/uL
RT; 41.58 min Scan# 4332
Delta R.T. -0.03 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion;264 Resp: 107922
Ion Ratio Lower Upper
264
100
132
33 .5
19.0
56 .8
0
0.0
0.0
0.0
0
0.0
0.0
0.0
TIC: ENG1676.D
30000 -
20000
10000
41.00
42.00
43.00
Time
jAbundanceTorT~252.00 (251.70 to 252.70): ENG
lion 126.00 (125.70 to 126.70): ENG
4000
2000
0
-» r
Time--> 41.00 42.00 43.00
ENG1676.D—PES3.M Tue Oct 19 10:19:14 lyytf
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 41.79 min
T¦ 3?lle : ENG 1676 , D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 252
Exp Ratio
100
31.2
0.0
0.0
lC| ? ^
HP S989B
P3.30 16
-------
Abundance
30000 J
20000
10000
0
Time-->
Abundance Ion 288.00 (287.70 to 288 .70) : ElJG
TIC: ENG1S76.D
52 .20
52.40
52 .60
15000
10000
5000
52.47
Time-
1 1 1
52 .20
52 .40
1 52!60
(Abundance
30000
20000
10000 -
Time-->
't i i j 1 f 1 j f 1 1 1 r \ 1 n
52.00 53.00 54.00
#30
Indeno(l,2,3-cd)pyrene-dl2
Concen: 3.83 ng/uL m
RT: 52.47 min Scan# 6012
Delta R.T. -0.06 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:288 Resp: 107908
Ion Ratio Lower Upper
288 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
flC: BMG1676.D
#31
Indeno(1,2,3-cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 52.82 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 276.05
Exp Ratio
100
60.1
0.0
0.0
m jjm ' ijmwwjli MJL- JIM UM, ml. 1 ' ft f WSmfWFlTm "" WHT-
Abundance Ion 276.05 (275.75 Eo 276.75) : ENG
Ion 138.00 (137.70 to 138.70): ENG
2000
1000
000.51,10
Time-
ENG1676 .D PES3 .M
52.00
53.00
—j—,—r
54.00
Tue Oct 19 10:19:17 1999
HP 5989B
Page 17
-------
TIC: ING1&7S.D
30000 .
20000
10000
Time-
52 .20
52 .40
52 .60
Abundance Ion 2 92.00 (291,70 to 292.70)
52.44
10000
5000
US"
Time-
52 .20
52.40
i 1 r
52.60
p
undance
30000
20000
TIC: ENG1676.D
10000
0
Time--> 52:00 53.00 54100
Abundance Ion 278.00 (277.70 to 278.70): ENG
Ion 139.00 (138.70 to 139.70): ENG
2000
1000
0
Time-
52:00
53.00
54:00
#32
Dibenz(a,h)anthracene-dl4
Concen: 4.13 ng/uL m
RT: 52.44 min Scan# 6006
Delta R.T. -0.06 min
Lab File: ENG1676.D
Acq: 16 Oct 99 . 4:32 am
Tgt Ion:292 Resp: 71366
Ion Ratio Lower Upper
292 100
0 0.0 0.0 0.0
0 0.0 0.0 0.0
0 0.0 0.0 0.0
#33
Dibenz(a,h)anthracene
Concen: 0.00 ng/uL
Expected RT: 52.87 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion: 278
Ion
278
139
0
0
Exp Ratio
100
53 .6
0.0
0.0
ENG1676.D PES3.M
Tue Oct 19 10:19:21 1999
0ce.li.ii
HP 5989B Page 18
-------
TD
10000 J
5000
Time--> 55.00 55.20 55.40 55.60 55.80
Abundance ion 288.00 (267.70 to 288.70); fiUG
55.47
10000
5000 -
Time—>55.00 55.20 55.40 55.60 55.80
#34
Benzo(g,h, i)perylene-dl2
Concen: 3.43 ng/uL m
RT: 55.47 min Scan# 6578
Delta R.T. -0.05 min
Lab File: ENG1676.D
Acq: 16 Oct 99 4:32 am
Tgt Ion:288 Resp: 102234
Ion Ratio Lower Upper
288
100
0
0.0
0.0
0.0
0
0.0
0.0
0.0
0
0.0
0.0
0.0
Abundance
15000
TIC: ENG1676.D
10000
5000-
Time-
55.00
56.00
57.00
#35
Benzo{g,h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 55.84 min
Lab Pile: ENG1676.D
Acq; 16 Oct 99 4:32 am
Tgt Ion: 276
Ion Exp Ratio
276 100
138 16.2
0 0.0
0 0.0
tTCT— a _ a Wj J* A A j PI A 4, ^ A""*! /* I ' flVfyN
Abundance Ion 276.00 (275.70 to 276.70) : ENG
Ion 138.00 (137.70 to 138.70) : ENG
2000 -=
1000
000.1142
Time--> 55.00
ENGTF7F7U—PES 3 .M
56.00
57 1 00
Tue Oct 19 10:19:24 1999
HP 5989B
Page 19
-------
ENG1676.XLS
Quantitation Report Summary
Data File
ENG1677.D
Date Analyzed:
10/16/99!
Sample ID
CARB429,OUTLET 1 KNOCKOUT
Method ID
PES3
Operator
Instrument
HP 5989B
Compounds
Area
Cone.
PQL*
Cone,
Cone, {ng/sample)
Diluted result
(ng/|j|.)
(ng/pL)
{ng/sample)
w/ Surr, correction
ng/sample
Naphthaiene(CCC)
0
0.000
0.1
0
0
0
Acenaphthylene
0
0.000
01
0
0
0
Acenaphthene(CCC)
0
0.000
0.1
0
0
0
Fiuorene
0
0.000
0.1
0
0
0
Phenanthrene
0
0.000
0.1
0
0
0
Anthracene
0
0.000
0.1
0
0
0
Fiuoranthene(CCC)
0
0.000
0.1
0
0
0
Fyrene
0
0.000
0.1
0
0
0
Benzo(a)anthracene
0
0.000
0.1
0
0
0
Chrysene(CCC)
0
0.000
0.1
0
0
0
Senzo(b)fiuoranthene
0
0.000
0.1
0
0
0
Benzo(k)fiuorartthene
0
0.000
0.1
0
0
0
Benzo(a)pyrene(CCC)
0
0.000
0.1
0
0
0
lndeno(1,2,3-cd}pyrene
0
0.000
0.1
0
0
0
Dibsnz(a,h)anthraeene
0
0.000
0.1
0
0
0
Benzo(g.h,i)perylene
0
0.000
0.1
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Cone. (ng/yL)
% Recovery
Naphthaiene-dS
0.00
0
Acenaphthylene-d8
0.00
0
Acenaphthene-d 10
0.00
0
Fluorene-d10
0.00
0
Phenanthrene-d 10
0.00
0
Anthracene-d10
0.00
0
Fluoranthene-d10
0.00
0
Pyrene-d10
0,00
0
Benzo(a)anthracene-d12
0.00
0
Chrysene-d12
0.00
0
Benzo(b}iuoranthene-d 12
0.00
0
Benzo(k)fluoranthene-d12
0.00
0
Benzo(a)pyrene-dl2
0.00
0
lndeno(1,2,3-cd)pyrene-d12
0,00
0
Dibenz(a,h)anthracene-dl4
0.00
0
Benzo(g,h,i)peryiene-d 12
0.00
0
Recovery Standard
Compound
Concentration (ng/|iL)
% Recovery
2-Meth!ynaphthalene-d10
0.00
0
p-Terphenyl-d14
0.00
0
/
/¦
r
Compiled by:
'T*7
Reviewed by:
* /
Reviewed by:
I I
oee.itis
-------
Quantitation Report
Data File
Acq On
Sample
Misc
Quant Time
Method
Title
Last- Update
Response via
C:\HP CHEM\1\DATA\ENG1677.D
16 Oct 99 5:39 am
CARB429,OUTLET 1 KNOCKOUT
Oct 19 10:20 1999
: C:\HPCHEM\l\METHODS\PES3.M
: Mon Oct 18 14:50:18 1999
Multiple Level Calibration
Vial
Operator
Inst
Multiplr
17
HP 5989B
1.00
Internal Standards
R.T. Qlon Response Cone Units Dev(Min)
1)
2,2-Difluorobiphenyl
19.99
190
362637
5.00 ng/uL
0
.00
System Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0.00
136
0
0.00 ng/uL
0
00%
4)
2-Methlynaphthalene-dl0
0.00
152
0
0.00 ng/uL
0
00%
5)
Aeenaphthylene-d8
0.00
160
0
0.00 ng/uL
0
00%
7}
Acena.phthene-dl0
0 .00
164
0
0.00 ng/uL
0
00%
9)
Pluorene-dlO
0 .00
176
0
0.00 ng/uL
0
00%
11)
Phenanthrene-dl0
0 .00
188
0
0.00 ng/uL
0
00%
13)
Anthracene-dl0
0.00
188
0
0.00 ng/uL
0
00%
15)
Fluoranthene-dl0
0.00
212
0
0,00 ng/uL
0
00%
17)
Pyrene-dio
0.00
212
0
0.00 ng/uL
0
00%
19)
p-Terphenyl-dl4
0.00
244
0
0.00 ng/uL
0
00%
20)
Benzo(a)anthracene-dl2
0.00
240
0
0.00 ng/uL
0
00%
22)
Chrysene-dl2
0.00
240
0
0.00 ng/uL
0
00%
24)
Benzo(b)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0
00%
26)
Benzo(k)fluoranthene-dl2
0.00
264
0
0.00 ng/uL
0
00%
28)
Benzo(a)pyrene-dl2
0.00
264
0
0.00 ng/uL
0
00%
30)
Indeno(l,2,3-cd)pyrene-dl2
0.00
288
0
0.00 ng/uL
0
00%
32)
Dibenz(a,h)anthracene-dl4
0 .00
292
0
0.00 ng/uL
0
00%
34)
Benzo(g,h,i)perylene-dl2
0.00
288
0
0.00 ng/uL
0
00%
rarget Compounds
Qvalue
3)
Naphthalene(CCC)
0.00
128
Not Detected
6)
Acenaphthylene
0.00
152
Not Detected
8)
Acenaphthene(CCC)
0.00
154
Not Detected
10)
Fluorene
0.00
166
Not Detected
12)
Phenanthrene
0.00
178
Not Detected
14)
Anthracene
0.00
178
Not Detected
16)
Fluoranthene(CCC)
0.00
202
Not Detected
18)
Pyrene
0.00
202
Not Detected
21)
Benzo(a)anthracene
0.00
228
Not Detected
23)
Chrysene(CCC)
0.00
228
Not Detected
25)
.Benzo(b).fluoranthene
0.00
252
Not Detected
27)
Benzo(k)fluoranthene
0 .00
252
Not Detected
29)
Benzo(a)pyrene(CCC)
0.00
252
Not Detected
31)
Indeno(1,2,3-cd)pyrene
0 .00
276
Not Detected
33)
Ti 4 Vvoi"! f si V* \ zst*i f™ Vi y*a
+*/ inijSXXZi \ (A f IX/
0 .00
278
Not Detected
35)
Benzo(g,h,i)perylene
0.00
276
Not Detected
ooe.ii
s.
X
{#) = qualifier out of range (m5 = manual integration
ENG1677.D P1S3.M Tue Oct 19 10:20:39 1999 HP 5989B
Page 1J
-------
Quantitation Report
C:\HPCHEM\1\DATA\ENG1677.D
16 Oct 99 5:39 am
CARB42 9,OUTLET 1 KNOCKOUT
Data File
Acq On
Sample
Misc :
Quant Time: Oct 19 10:20 1999
Method
Title
Last Update
Response via
C:\HPCHEM\1\METHODS\ PE S 3.M
Mon Oct 18 14:50:18 1999
Multiple Level Calibration
vial: 17
Operator:
Inst : HP 5989B
Multiplr: 1.00
Abundance
260000
240000 J
220000
200000
180000
160000
140000
120000
100000 -1
80000
60000
40000
20000
0
Time - - >
TIC: ENG1677.D
i J i i I ! I | ! I I- JIM ! 1111 "T I "" T"" 7 1 j 1 J I I ] ! ! I ! J ! I 1 1 "7 { I
20 100 25.00 30.00 35100 40100 45.00 50100 55100
OCG.ti-iS
ENG1677.D PES3.M Tue Oct 19 10:20:44 1999 HP 5989B Page 2
-------
Abundance
TIC: - ENG1S77.D
1
10000 -
5000 -
0 _
Time-->is!50' 17!00 iVIso' 18.00
mm\ i j i r i \
18.50
l&bundancelon 136.00 (135.70 to 136.70): ENG
Ion 68.00 (67.70 to 68.
70): ENG16
4000 .
!
2000 -
0 -
Time--> 16 150 *17 1 OO* 17!50* isloo
r i I "'{ i r i
18.50
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 17.69 min
Lab File: ENG1677.D
Acq*. 16 Oct 99 5:39 am
Tgt Ion: 136
Ion Exp Ratio
136 100
68 15.3
0 0.0
0 0.0
Abundance
10000
TIC: SHG1S77.B
5000
0
—i—I—1 J—!—J—1 r—I—I—i—j—I—r t 1 1—t—?—I—1—i—I—I—
fTime- ->I6! 50 17.00 17.50 18.00 18.50
Abundance Ion 128.00 (127.70 to 128.70): SNG
4000 -!Ion 127.00 (126.70 to 127.70): ENG
X
3000
2000
1000
0
t—r—i—!—|—i—i—r—i—i—i—!—i—i—r 1 t —i i j i—r
Time- - si6.50 17.00 17.50 18.00 18.50
ENG1677.D—PES3.M
#3
Naphthalene(CCC)
Concen.- 0.00 ng/uL
Expected RT: 17.74 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 128
Ion Exp Ratio
128 100
127 13.0
0 0.0
0 0.0
Tue Oct 19 10:20:48 1999
HP 5989B
Page 3
-------
Abundance
200000
150000
100000 4
50000
Time-
TIC: BNG1677.D
1 V" T 1
is.so' lblo'o' 19150 20:00
Abundance Ion 152 .00 (151.70 to 152.70): ENG
2000
1000
Time-->
i—j—3—r—j—i—i—i—f—r—i—i—i—i—\—i—i—i—r~
18150 19.00 19:50 20100
Abundance
6000
4000 J
2000
I I | I f
Time--> 20l50' '2l! 00* 2l!50 22100 22150
TIC: ENG1677.D
Abundance Ion 160.00 (159.70 to 160.70): ENG
2000
1000 -
0
Time--> 20150 21.00 21.50 22.00 22.50
#4
2-Methlynaphthalene-dl0
Concen; 0.00 ng/uL
Expected RT: 19.37 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 152
Ion Exp Ratio
152 100
0 0.0
0 0.0
0 0.0
ENG1677.D—PES3.M
#5
Aeenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT: 21.63 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 160
Ion Exp Ratio
160 100
0 0.0
0 0.0
0 0.0
TpQ-0—Oct—j-g— ¦. 20-52—1.999
HI 5989B
Page 4
-------
Abundance
6000
4000 J
2000:
Time--> 20.50 21.00 21150
TIC: ENG1677.D
i—r
22 : 00
22 .50
kbundancelon 152.00
Ion 153.00
2000
1000 -
0
(151.70 to 152.70)
(152.70 to 153.70)
Time--> 20.50 21.00 21.50 22.00 22.50
#6
Acenaphthylene
Concert: 0.00 ng/uL
Expected RT: 21.66 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 152
Ion Exp Ratio
152 100
153 13.0
0 0.0
0 0.0
Abundance
6000
4000
2000
Time--> 21:00 21150 22100 22150 23100
Abundance Ion 164.00 {163.70 to 164.70): 2MG
2000
TIC: ENGlb77.D
#7
Acenaphthene-dl0
Concen: 0.00 ng/uL
Expected RT: 22.04 min
Lab Pile: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 164
Exp Ratio
100
0.0
0.0
0.0
1000
21.50
21.00
22.50
23.00
22.00
oeo
J", %
jL-'iC
-------
Abundance
6000
4000
2000
! ! i—»—j—[—i—?—!—i—|—i—r—i i i—i—r—i—!—i 1 "i '!—r
Time--> 21.00 21150 22.00 22.50 23.00
TIC: EMG1577.D
'AbundanceIon 154.00 (152.70 to 154.10) -. fiNG
Ion 153.00 (152.70 to 153.70) : ENG
2000
1000
0 ,
frime--> 21 loo' 211.50' 22loO 22150 23100
Msundance
8000
6000
4000
2000
0
"TIC: ENG1677.D
T
n—\—i—i—i—r
2000 -
1000
Time-->
22.50 23.00 23.50 24.00
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 22.12 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 154
Ion Exp Ratio
154 100
153 98.0
0 0.0
0 0.0
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 176
Ion Exp Ratio
100
rime--> 22.50 23.00 23.50 24.00
AbundanceIon 17S.00 (175.70 to 175.70): EMG
176
0
0
0
0.0
0.0
0.0
ENG16 7 7.D PES3.M
Tue Oct 19 10:20:59 1999
HP 5989B
n 4"% •** jr ** "s
Page 6
-------
Abundance
8000
TIC: ENG1677.D
6000
4000
2000
0
Time--> 22.50 23.00 23.50 24.00
Abundance Ion 166.00 (165.70 to 166.70): ENG
JIon 165.00 (164.70 to 165.70): ENG
4000
2000
[Time - - >
1 1—I [—i S—1—S—t—I—r
22.50 23.00
23 .50
i i | i i
24.00
-i—!—i—i—j—r—i—i—i—^—i—i—i—r
Time--> 24 i 50 25.00 25.50 26 1 00 26150
Abun
.'xme--> 24.50
ENG'1677 ,D FEST7M
25100 25 150 26.00 26150
Tue Oct iy iu:21:u3 lyyy
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 23.38 min
Lab File: ENG16 7 7 . D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 166
Ion Exp Ratio
166 100
165 91.3
0 0.0
0 0.0
TIC: MG1677.D
10000
5000 _
#11
Phenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 188
Exp Ratio
100
24.5
0.0
0.0
danceion 188.00 (187.70 to 188.705: ENG
4000 -.Jon 94.00 (93.70 to 94.70): ENG16
3000
2000
1000
HP 5989B
s -5-ia
Page 7
-------
Abundance
10000 .
5000
TIC: ENG1677.D
Time--^4.50 25.00 25.50 26.00 26.50
SJbundanc e I on 17 8 .0 0 (177.70 to 178.70): ENG
Ion 176.00 (175.70 to 176.70): ENG
4000
3000
2000
1000
i—i—i—r—j—i—!—i : j—i—i—i—r~~r—i—i—t—r—|—? t1 i
Time-->24 .50 25 . 00 25 .50 26 . 00 26 . 50
#12
Phenanthrene
Concen: 0.00 ng/uL
Expected RT: 25.74 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.2
0 0.0
0 0.0
Abundance
10000
5000
J. X V • filNlw JL O ft* imJ
0
n—r—i—r
-T f \ 1 ! ! ! T
rime-
25.00 25.50 26.00 26150
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 188
Ion Exp Ratio
188 100
94 26.6
0 0.0
0 0.0
Abundance Ion 188.00 (187.70 to 188.70): BUG
4000 -ilon 94.00 (93.70 to 94.70): ENG16
3000
2000
1000
Time-
T 1 "™'l "f—| 1—'f""T "!"—I { "1 I ' I "T""l ' T ]• f I !
25.00 25.50 26.00 26.50
ENG'1677 .1)—PES3TRT
000.1151
Tue Oct 19 10:21:Ufa 1999
HP 5989B
Page 8
-------
Abundance
10000
5000
TIC: ENG1677.D
~i—i—j—i—i—i—i—|—i—r~—;—i—|—r—r
25.00 25.50 26.00 26150
i r i
Time- - >
IMnainceTorri778TCrD_lTr777(J~toT^lT7Frr^S^
lion 176.00 (175.70 to 176.70): ENG
Time-->
4000
3000
2000
1000
25100 25150 26 lo'o' ' 26! 5*0 '
TIC: EUG1S77.D"
Abundance
20000
15000
10000 -
5000
0 -w-j—,—,—,—|—|—|—.—,—,—j—i—,—;—,—j—i—i—i—i—|—i—I—i—r
Time--> 27.50 28.00 28.50 29.00 29.50
212.00 (211.70 to 212.70): ENG
! Ion
5000
"Ion 106.00 (105.70 to 106.70): ENG
-
L-1 1 1 1 1 1 1 ! 1
t i i • i i r"'"T 7 r-'-r t—t -r—r
Time--> 27.50 28.00 28.50
ENGlfeVV ,D—PEST7W
#14
Anthracene
Concen; 0.00 ng/uL
Expected RT: 25.87 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 178
Exp Ratio
100
19.9
0.0
0.0
#15
Fluoranthene-dlO
Concen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 212
Ion Exp Ratio
212 .100
106 27.3
0 0.0
0 0.0
29.00 29.50
'rue Oct 19 10:21:10 1999'
000.1152
HP 5989B
Page 9
-------
A23UHC3.cl.IlG6
20000
Time-->27.50 28,00 28.50 29.00 29.50
TIC: BNGl677.tr
5000
0
15000:
10000
~i—i—I—r-
Abundancelon 202.00 (201.70 to 202.70); BNG
Ion 101.00 (100.70 to 101.70): ENG
3000 J
2000:
1000
Time-->27 i50 28100 28 150 29100 29 i50
rime - - >
\ " »' "T '1 « ! T—) I I' V" ! I 'I '"I 5 ' ]' I ! 1 "T I "
28.50 29.00 29.50 30.00
Abundance Ion 212.00 (211.70 to 212.70)
nIOn 106.00 (105.70 to 106.70)
5000
0
V
Time-->
"1 ! !—[—r
28.50
n—s—|—i—r
29 ; 00
J S I 1
29 .50
1—i—r
30:00
#16
Pluoranthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 28.73 tnin
Lab File; ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 202
Ion
202
101
0
0
Ratio
100
24.0
0.0
0 . 0
TIC:ENG1677.D
20000
15000 _
10000
5000 .
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 rrtin
Lab File: ENG1677.D
Acq.- 16 Oct 99 5:39 am
Tgt Ion: 212
Exp Ratio
100
31.6
0.0
0.0
HMT
ENG
ENGXfe77.D—PES3.M
- ¦
Tue Oct 19 10:21:13 199?
HP 5989B
Page 10
-------
Abundance
20000 :
15000
10000
5000
0
TIC: ENG1677.D
n—i—!—i—|—i—i—i—i—]—i—!—i—e—r—i—i—t i ;—i—i—i—r
28.50 29.00 29.50 30.00
Time-->
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
3000 j
2000
1000
Time-
1 1 i ; >
28 .50
i—t—]—i—r-
29.00
29.50
i—!—[—i—i—r
30.00
TIC: ENG1677.D
20000
15000
10000
5000 4
0
2000
0
#18
Pyrene
Concent 0.00 ng/uL
Expected RT: 29.34 rain
Lab Pile: ENG1677.D
Acq: IS Oct 99 5:39 am
Tgt Ion: 202
Ion Exp Ratio
202 100
101 27.6
0 0.0
0 0.0
1119
p-Terphenyl-dl4
Concen: 0.00 ng/uL
Expected RT: 29.62 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 244
¦—i—i—i—i—i—i—r—r—i——r—i—i—i—|—e—r~*T—t—i—r—t—i—
Time--> 28150 29100 29.50 30.00 30.50
Abundance Ion 244.00 (243 .70 to 244 . 70")": MG
Ion 122.00 (121.70 to 122.70): ENS
4000
Ion
244
122
0
0
Exp Ratio
100
29 .1
0.0
0.0
-t—i—i—i—i—i—i—i—i—i—i—s—t—!—r—|—i—r—i—\—|—i—s—r
Time--> 28.50 29.00 29*50 30100 30.50
ENG1677 .D—PES3 ,M Tue Oct 19 10:21:17 1999
000 s
HP 5989B
Page 11
-------
Sundance
20000
TIC: ENG1677.D
15000
10000
5000
I I 1 j ! 1 1 1 1 ! ! I ! 1 1 I | 1 I T"TTT1 "M
32.50 33.00 33.50 34.00
rirae-->
abundance ion 240.00 (239.70 to 245.76): IMG
8000Jlon 120.00 {119.70 to 120.70)
6000
4000
2000
Time - ->
1 I j ! I
32 .50
~i i r t r i j | ? i—!—)—|—i—i
33.00 33.50 34.00
Abundance
20000
Time--> 32:5C' 3 310 0 3 3 1 50' 34!00
Abundance Ion 228.50 (227.70 to 228.75)
ENG
Ion 114.00 (113.70 to 114.70): ENG
4000:
3000
Time
T~T—I—I—I—I—I—I—r
32:50 33:00 33:50 34.00
#20
Benzo(a)anthracene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.36 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.9
0 0.0
0 0.0
ENG1677.D
15000
10000
5000
2000
1000
ENG1677.D PES3.M
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 33.46 min
Lab Pile: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 228
Ion Exp Ratio
228 100
114 25.4
0 0.0
0 0.0
000.1155
Tue Oct 19 10:21:20 1999
HP 5989B
Page 12
-------
Abundance
20000
15000
10000
5000
TIC: ENG1677.D
0
n—r—i—r
—i—i—r~
Tirne--> 32.50 33.00 33.50 34.00 34.50
Abundance Ion 240,00 (239.70 to 240.70 ) : ENG
8000 JIon 120.00 (119.70 to 120.70): ENG
6000
4000
2000
Time — > 32.50 33.00 33.50 34.00 34.50
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.50 min
Lab File; ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.3
0 0.0
0 0.0
SJsundance
20000
15000:
10000
5000:
o
f/H" • fT"
11^, JCiiNvjXO / / .JU
#23
Chrysene(CCC)
Concen: 0.00 ng/uL
Expected RT: 33.61 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 228
i . : 11 "j 1 "I I I I | J !' I I J —r' —i —< 11—i
Time-->32 i50 33.00 33.50 34.00 34.50
Abundance Ion 226.00 (227.70 to 228,70}: ENG
Ion 114.00 (113.70 to 114.70) : ENG
4000
2000
Ion
228
114
0
0
Exp Ratio
100
22.3
0.0
0.0
0*1 *" /"
JLOt)
Time-->32:50 33100 33:50' *34100' 34:50
ENG1677 . D PES'3~.M
Tue'Oct 19 10:21:24 1999
HP 5989B
Page 13
-------
Abundance
10000
Time-->
TIC: ENG1677.D
5000
-i—I—i—r
-i—i—i—r
38.50 39.00 39.50 40.00
Abundance Ion 264.00 <263.70 to 2S4.70): EMS
jlon 132.00 (131.70 to 132.70): ENG
4000
2000
0
Time-
l !—{—!—f ! 1 1—1 1 1—1 [ 1 1—I—I 1 1 1—i-
38.50 39.00 39.50 40.00
Abundance
10000
TIC: EUS1677.t>
5000
-?—I—j—i—i—i—i—I—!—f—i—1—j—i—r—!—!—j—i—r—i—\—j—i—
rime--> 38.50 39.00 39.50 40.00
Abundance Ion 252.00 (251.70 to 252.70) : ENG
Ion 126.00 (125.70 to 126.70): ENG
4000 1
3000
2000 j
1000
Time-
-j j | , j j 1 1 1 1 1 1 [ 1 r
38.50 39.00 39.50
1 1 """[ I 1 T"
40.00
#24
Benzo (b) fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.35 min
Lab Pile: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 264
Ion
264
132
0
0
Exp Ratio
100
69.4
0.0
0.0
#25
Benzo(b)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.52 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 252
Ion Exp Ratio
100
252
126
0
0
27.8
0.0
0.0
~ J~. T*?
? i.v.y §
ENGl6 7 7.D PES3.M
"Tu¥13ct~T9—nrr2XTZT_T^9¥
HP 5989B
Page 14
-------
Abundance
10000
TIC: ENG1677.D
5000
0
-i—r—i—r
I J" ' 1 * I
Time--> 38^50 39 !00 39:50 40.00 40.50
AbundanceIon 264.00 (263.70 to 264.70): ENG
lion 132 .00 (131.70 to 132.70): ENG
4000
2000
| !- i T-r-j-i" -r
Time--> 38.50 39.00
39 .50
t—i—r—n—r
40.00
40 .50
[Abundance
TIC: EWG1S77.D
10000
5000 .
t—r—i—r—t—r—j—t—i—>—>—I—m—|—i—I—1—r—\—s—i—\—r~
fTime--> 39.00 39.50 40.00 40.50
IMS"
¦ m i i.i. i ai,.„m i i — " » x_ M ' ' M, J¦ - i-V M '* . J III J, ill » I ¦
Abundance Ion 252.00 (251.70 to 252.70}
Ion 126.00 (125.70 to 126.70}
4000 :
3000 :
2000
1000
ENG
Time-
1 ! 1 ! 1 ! ! 1 f 1 1 1 1 1 J 1 T ? 1—ft—r
39.00 39.50 40.00 40.50
#26
Benzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.53 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 264
Ion Exp Ratio
264 100
132 35.8
0 0.0
0 0.0
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.67 min
Lab Pile: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 -27.6
0 0.0
0 0.0
ENGI677.D PES3.M
\J
Tue Oct19 10:21:31 1999
HP 5989B
Page 15
-------
Abundance
15000
10000
•—EM51 £ 77—D~
5000
0
n—i—i—i—i—i—[—i-1—i—i—| i i—i—i—[—i—i—i—s—|—i—i—r—
Time--> 40,50 41.00 41.50 42.00 42.50
Abundance Ion 264.00 (263.70 to 264.70): ENG
lion 132.00 (131.70 to 132.70): ENG
#28
Benzo(a)pyrene-dl2
Concen.- 0.00 ng/uL
Expected RT: 41.61 min
Lab Pile: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 264
Ion Exp Ratio
264 100
132 37.8
0 0.0
0 0.0
4000
2000
i ! I 1 1 1 ! J ! J ! 1 1 1 1 1 I 1 ! 1 1 T
frirae--> 40.50 41.00 41.50 42.00 42.50
Abundance
15000
TIC: ENG1677.D
10000
5000
0
Time-->
Abun-
41.00 42100 43:00
eIon 252.00 (251.70 to 252.70): ENG
'Ion 126.00 (125.70 to 126.70): ENG
4000
2000
0
Time--»
41.00
42.00
43 .00
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 41.79 min
Lab File: 2NG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 31.2
0 0.0
0 0.0
ENGifc'77 .D—PES3.M
000.11
• a
Tue Oct 19 10:21:34 199^
HP 5989B
Page
-------
Abundance
Titne-->
TIC: ENG1577.D
10000
5000 .
0
S
52.00
t I (
53 .00
—P_ f j r
54.00
AbundanceIon 2 88 . 00 (287.70 to 288.70) : ENG
2000
1000
Time-
52.00
53 .00
54.00
Abundance
TIC:'SNSlS??.b
10000
5000
0
Time--> 52100 53:00
Sbundancp Ion 575 0"5—(275 75 to 276 75} • ENG
rMM< UililLlUilLl C X U*X M / O » W W \ ¦£» f •mf • t «i» W> W M / W • ' mJ / » ClilVJ
Ion 138.00 (137.70 to 138.70): ENG
, | r j
54.00
2000
1000
0
Time-->
*wW*ww. «f«f
—,—,—r
52 .00
i 1 r —i 1 t r
53.00
54100
#30
Indeno(1,2, 3-cd)pyrene-dl2
Concen: 0.00 ng/uL
Expected RT: 52.54 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 288
Ion Exp Ratio
288 100
0 0.0
0 0.0
0 0.0
#31
indeno(l,2,3-cd)pyrene
Concen: 0.00 ng/uL
Expected RT: 52.82 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 276.05
Ion Exp Ratio
276 100
138 60.1
0 0.0
0 0.0
ENG1677 .D—PES3 .M
oo&'i-a
Tue Oct 19 10:21:38 19??
HP 5989B
Page 17
-------
Abundance
10000
5000
TIC: EWG1677.D
r
Time-
52.00
i ' i r
53.00
Sundance Ion 252.00 (251.70 to 252.70)
2000
1000
0
Time-->
52 .00
53.00
Abundance
TIC: 6MG1677.D
r~
10000
5000
0
rime - - >
-T ] ! 1 1 I 1 ? ! ! ! I T
52.00 53:00 54100
[Abundance Ion 278.00 (277.70 to 278.70): ENG
3000 -lion 139.00 (138.70 to 139.70): 1NG
2000
1000
Time-
52 . 00
-i 1 r
53.00
1 1 | I
54.00
#32
Dibenz(a,h)anthracene-dl4
Concen: O.OO ng/uL
Expected RT: 52.50 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 292
Ion Exp Ratio
292 100
0 0.0
0 0.0
0 0.0
ENGlfeVV.D PKS3.M
#33
Dibenz (a,h) anthracene
Concen: 0.00 ng/uL
Expected RT: 52.87 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt ion: 278
Ion Exp Ratio
278 100
139 53.6
0 0.0
0 0.0
p.
%S. i
Tue Oct 19 10:21:41 1999
HP 5989B
Page 18
-------
Abundance
Time-->
TIC: ENG1677.D
10000
5000
0
55.00
56.00
abundance Ion 268.00 (267.70 to 288.70): ENG
2000 -
1000
Time-
55.00
56.00
Abundance
TIC: ENG1677.D
10000
5000
Time-->
55.00
56.00
57.00
Abundance Ion 276.00 (275.70 to 276.70): ENG
Jlon 138.00 (137.70 to 138.70): ENG
2000
1000
0
Time-->
55.00
—I—r
56.00
57.00
#34
Benzo (g,h, i}perylene-dl2
Concen: 0.00 ng/uL
Expected RT: 55.52 min
Lab File: ENG1677.D
Acq: 16 Oct 99 5:39 am
Tgt Ion: 288
Ion Ixp Ratio
288 100
0 0.0
0 0.0
0 0.0
ENG1677 .D—PES3 .'M
#35
Benzo(g, h,i)perylene
Concen: 0.00 ng/uL
Expected RT: 55.84 min
Lab File: ENG1677.D
Acq; 16 Oct 99 5:39 am
Tgt Ion: 276
Ion Exp Ratio
100
276
138
16.2
0.0
0.0
Tue Oct 19 10:21:45 19yy
HP 5989B
Page 19
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ENG1678.XLS
Quantitation Report Summary
Data File
ENG1678
Date Analyzed:
10/16/39
Sample ID
CARB429,OUTLET 1 KNOCKOUT
Method ID
PES3
Operator
Instrument
HP 59890
Compounds
Area
Cone,
PQL*
Cone.
Cone, {ng/sample)
Diluted result
(ng/ML)
(ngw
(ng/sampie)
w/ Surr. correction
ng/sample
Naphthalene(CCC)
0
0.000
0.1
0
0
0
Acena phthylene
0
0.000
0.1
0
0
0
Acena phthene(C CC)
0
0.000
0.1
0
0
0
Fluorene
0
0.000
0.1
0
0
0
Phenanthrene
0
0.000
0.1
0
0
0
Anthracene
0
0.000
0.1
0
0
0
Fluoranthene (C CC)
0
0.000
0.1
0
0
0
3yrene
0
0.000
0.1
0
0
0
Benzo(a)anthracene
0
0.000
0.1
0
0
0
Chrysene(CCC)
0
0.000
0.1
0
0
0
Benzo(b)fluoranthene
0
0.000
0.1
0
0
0
Benzo(k)fl uoranthene
0
o.ooo
0.1
0
0
0
Benzo(a)pyrene(CCC)
0
0.000
0.1
0
0
0
lndeno{1,2,3-ed)pyrene
0
0.000
0.1
0
0
0
Dibenz(a,h)anthracene
0
0.000
0.1
0
0
0
Benzo(g,b,i)peryiene
0
0.000
0.1
0
0
0
* PQL - practical quantitation limit
Surrogate Recoveries
Compound
Cone. (ng/pL)
% Recovery
Naphthaiene-d8
0.00
0
Acena phthylene-dB
0,00
0
Acenaphthene-d10
0,00
0
Ftuorene-d10
0.00
0
^henanthrene-dlO
0.00
0
Anthracene-d10
0.00
0
Fluoranthene-d10
0.00
0
Pyrene-d10
0.00
0
Benzo(a)arrthracene-d12
0.00
0
Chrysene-d12
0.00
0
Benzo(b)fluoranthene-d12
0.00
0
Benzo(k)fl uoranthene-d 12
0.00
0
Benzo(a)pyrene-d12
0.00
0
lndeno{1,2,3-cd)pyre ne-d 12
0.00
0
Dibenz(a,h)anthracene-d14
0.00
0
Benzo(g,h,i)perylene-d12
0.00
0
Recovery Standard
Compound
Concentration (ng/pL)
% Recovery
2-Methlynaphthaiene-d10
0.00
0
p-Terphenyi-d14
0.00
0
~
~y
Compiled by:
.9^
Reviewed by:
/
Reviewed by:
I I I
OOCijjcS
-------
Quantitation Report
Data File :
Acq On ;
Sample ;
Misc :
Quant Time:
C:\HPCHEM\1\DATA\ENG1678 .D
16 Oct 99 6:45 am
CARB429.OUTLET 2 KNOCKOUT
Oct 19 10:22 1999
Vial: 18
Operator:
Inst : HP 5989B
Multiplr: 1.00
Method : C:\HPCHEM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:50:18 1999
Response via : Multiple Level Calibration
Internal Standards R.T. Qlon Response Cone Units Eev(Min)
1)
2,2-Difluorobiphenyl
19.
99
190
381838
5.00
ng/uL
-0
.01
ystem Monitoring Compounds
%Recovery
2)
Naphthalene-d8
0
00
136
0
0.00
ng/uL
0
00%
4)
2-Methlynaphthalene-dlO
0
00
152
0
0.00
ng/uL
0
00%
5)
Acenaphthylene-d8
0
00
160
0
0 .00
ng/uL
0
00%
7)
Acenaphthene-dlO
0
00
164
0
0.00
ng/uL
0
00%
9)
Fluorene-dlO
0
00
176
0
0.00
ng/uL
0
00%
11)
Phenanthrene-dlO
0
00
188
0
0.00
ng/uL
0
00%
13)
Anthracene-dlO
0
00
188
0
0.00
ng/uL
0
00%
15)
Fluoranthene-dlO
0
00
212
0
0 .00
ng/uL
0
00%
17)
Pyrene-dlO
0
00
212
0
0.00
ng/uL
0
00%
19)
p-Terphenyl-dl4
0
00
244
0
0.00
ng/uL
0
00%
20)
Benzo(a)anthracene-dl2
0
00
240
0
0.00
ng/uL
0
00%
22)
Chrysene-dl2
0
00
240
0
0.00
ng/uL
0
00%
24)
Benzo(b)fluoranthene-dl2
0
00
264
0
0.00
ng/uL
0
00%
26)
Benzo(k)fluoranthene-dl2
0
00
264
0
0.00
ng/uL
0
00%
28)
Benzo(a)pyrene-dl2
0
00
264
0
0.00
ng/uL
0
00%
30)
Indeno(1,2, 3 - cd)pyrene-dl2
0
00
'288
0
0.00
ng/uL
0
.00%
32)
Dibenz(a,hi anthracene-dl4
0
00
292
0
0,00
ng/uL
0
.00%
34)
Benzo(g,h,i)perylene-dl2
0
00
288
0
0.00
ng/uL
0
.00%
Target Compounds
3} Naphthalene(CCC) 0.00
6} Acenaphthylene 0,00
8 5 Acenaphthene(CCC) 0.00
10) Fluorene 0.00
12) Phenanthrene 0.00
14) Anthracene 0.00
16) Fluoranthene(CCC) 0.00
18) Pyrene 0.00
21) Benzo(a)anthracene 0.00
23) Chrysene(CCC) 0.00
25) Benzo(b)fluoranthene 0.00
27) Benzo(k)fluoranthene 0.00
29) Benzo(a)pyrene(CCC) 0.00
31) Indeno(1,2, 3-cd)pyrene 0.00
33) Dibenz(a,h}anthracene 0.00
35) Benzo(g,h,i)perylene 0.00
Qvalue
128 Not Detected
152 Not Detected
154 Not Detected
166 Not Detected
178 Not Detected
178 Not Detected
202 Not Detected
202 Not Detected
228 Not Detected
228 Not Detected
252 Not Detected
252 Not Detected
252 Not Detected
276 Not Detected
278 Not Detected
276 Not Detected
OOOiii'j!
(#) « qualifier out of range (m) = manual integration
ENG1678 D PES3 M Tue Oct 19 10-23-17 1999 HP 5989B
¦ li * VJJb» W < U • •/ mm Jtmi U mJ ¦ 1 i X UtW Vxr Vrf w X Jtm W ¦ JU ¦/ rnHf mir ImXC wj W
Page 1
-------
Quantitation Report
Data File : C:\HPCHEM\l\DATA\ENGl678.D
Acq On : 16 Oct 99 6:45 am
sample : CARB429,OUTLET 2 KNOCKOUT
Misc :
Quant Time: Oct 19 10:22 1999
Method : C:\HPCHEM\l\METHODS\PES3.M
Title :
Last Update : Mon Oct 18 14:50:18 1999
Response via : Multiple Level Calibration
TIC: ENG1678.D
Abundance
220000 j
200000
180000 -
160000 J
140000 -
120000
iooooo :
soooo;
60000 j
40000 .
20000 j
20.00 25.00 30.00 35.00 40.00 45.00 50.00 55.00
0CQJS6S
1NG1678.D PES3.M Tue Oct 19 10:23:22 1999 HP 5989B Page 2
Vial: 18
Operator:
Inst : HP 5989B
Multiplr: 1.00
-------
Abundance
TIC: ENG1678.D
20000:
15000 :
10000:
yW
I - —. — A n
5000:
|
0:
f
Time-->16
j » » 1 ; 1 > i 1 • > » 1 l ! 1 J i 1 ; j 1 1 1 i
.50 17.00 17.50 18.00 18.50
Abundance Ion 136.00 (135.70 to 136.70); ENG
Ion 68.00 (67.70 to 68.70): ENG 16
15000 .
10000 -
5000 .
A/J
"T\
1 . A. *1
0 .
1
Time-->16.50 17.00 17.50 18.00 18.50
#2
Naphthalene-d8
Concen: 0.00 ng/uL
Expected RT: 17,69 min
Lab Pile: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 136
Ion Exp Ratio
136 100
68 15.3
0 0.0
0 0.0
Abundance
20000
15000
TIC: ENG1678.D
ioooo :aJ
5000
-A.
0
1 I * J
2 000 J
1000
, wAws-
Time-
I 1—I 1—1 1 f 1 ! I I I 1 I , j l I [—1 ! r—T
¦>16.50 17.00 17.50 18.00 18.50
#3
Naphthalene(CCC)
Concen: 0.00 ng/uL
Expected RT: 17.74 min
Lab File; ENG1678.D
Acq: 16 Oct.99 6:45 am
Tgt Ion: 128
rime--516.50 17100 17:50 18.00 18.50
Abundance Ion 128.00 (127.70 to 128.70): ENG
4000Jlon 127.00 (126.70 to 127.70}: ENG
3000
Ion
128
127
0
0
Exp Ratio
100
13.0
0.0
0.0
ENG1678.D PBS3.M
0GS.II66
Tue Oct iy iu :2i:27 lyyy
HP 5989B
Page 3
-------
Abundance
150000
100000
50000
Time-
TIC: ENG1678.D
1 I 1 '
18.50
n [ 1 ! r 1 j T I 1 ! 1 1 I T
19:00 19.50 20.00
Abundance Ion 152.00 (151.70 to 152.70): ENG
2000
1000
Time-
i \—i—r—i—i—i—i—| i i—•—*—|—e—i—rr—|—i—r
18.50 19.00 19.50 20.00
KBundance
6000
4000
2000
0 J,
TIC: ENG1678.D
•t—!—i—r~~i—i—i—s—t—1—j—i—r—r~~i—r—i—t—t——i i
Time--> 20150 21.00 21.50 22.00 22.50
AbundanceIon 160.00 (159.70 to 160.70)
2000 -
1000 -
0
Time--> 20.50 21.00 21.50 22.00 22.50
2-Methlynaphthalene-dlO
Concen: 0.00 ng/uL
Expected RT: 19.37 min
Lab File: SNG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 152
Exp Ratio
100
0.0
0.0
0.0
ENG167B.D—FE53TM"
#5
Acenaphthylene-d8
Concen: 0.00 ng/uL
Expected RT: 21.63 min
Lab Pile: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 160
Ion Exp Ratio
160 100
0 0.0
0 0.0
0 0.0
000.li.67
Tue Oct 19 10 :2T7TU~~T9"EJ9
HE 5989B
Page
-------
Abundance
6000
4000
2000
TIC: ENG1S78.D
rime--> 20.50 21.00 21.50 22i00 22.50
Abundance Ion 152.00 (lSi.70 to 152.76): BUG
Ion 153.00 (152.70 to 153.70); ENG
2000
1000
0
—i—|—i—i—?—i—i—i—i—r
Time--> 20.50 21.00 21.50 22.00 22 .50
Abundance
6000
4000
2000
1 1
I "I—I—r—1—I—1—I—I—J—I—|—?—J—I !—|—I—r
Time--> 21100 21.50 22.00 22.50 23.00
TIC: ENG1678.D
2000
1000
Time--> 21.00 21.50 22.00 22.50 23.00
#6
Acenaphthylene
Concen: 0.00 ng/uL
Expected RT: 21.66 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion*. 152
Ion Exp Ratio
152 100
153 13.0
0 0.0
0 0.0
#7
Acenaphthene-dl0
Concen: 0.00 ng/uL
Expected RT: 22.04 min
Lab Pile: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 164
Ion Exp Ratio
164 100
0 0.0
0 0.0
0 0.0
Abundance Ion 1S4.00 (163.70 to 154.70): BNG
0CC.H68
ENG1678.D PES3.M'
Ke Oct 19 10:23:33 1999
HP 5989B
Page 5
-------
Abundance
TIC: ENG1678.D
6000 -
4000 -
2000:
0 j
Time--> 21.00 21.50 22.
00 22.50 23.
00
Abundance Ion 154
.00 (153
.70 to 154.70)
: ENG
Ion 153
. 00 (152
.70 to 153.70)
: ENG
lm A..-
2000-
1000
0 .
J. , ..J -r r .. r I , ,r ...T, .
Time--> 21.00 21.50 22
do' '22 i50' '23
T 1 1
00
#8
Acenaphthene(CCC)
Concen: 0.00 ng/uL
Expected RT: 22.12 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion.: 154
Ion Exp Ratio
154 100
153 98.0
0 0.0
0 0.0
Abundance
TIC: EWG1678.D
6000
4000
2000
Time-
'22;50' *23 1 o'o' *23 150* '24:00*
2000
1000
Time-->
1—r—T !—I—I—I 1—! 1 1 1 { 1 [ 1 1 [ { J 3—r
22.50 23.00 23.50 24.00
#9
Fluorene-dlO
Concen: 0.00 ng/uL
Expected RT: 23.31 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 176
Ion
176
0
0
0
Abundance Ion 17 6.00 (175.70 to 176.70): ENG
ENG1678.D PES3.M
Tue Oct 19 10:23:37 1999
Exp Ratio
100
0.0
0.0
0.0
00
ii.
IIP 5989B
Pag'e 6
-------
Abundance
Time-->
TIC: ENG167S.D
6000
4000
2000
0
-i—?—i—r
22.50 23.00 23.50 24.00
ZT- -w ^ . m m m j. jt ) 4 mm mm. i ^ ju » M HA t T-tSklW
Abundance Ion 166.00 (165-70 to 166.70): ENG
3000
lion 165.00 (164.70 to 165.70)
2000 .
1000
Time-
22.50 23.00 23.50 24100
Abundance
10000
5000
-i—i—t—i—i—i—i—i—i—r
25.00 25.50
Time--> 24.50
Abundance Ion 188.00 (187.70 to 188.70)
i—I—I—i—[—i—i—r
26!00 26.50
3000J Ion 94.00 (93.70 to 94.70): ENG16
2000
1000
Time- -> 24 50
-!—i—i—i—i—i—r—\—i—|—i—i—i—i—|—i—i—r
25100 25.50 26.00 26.50
#10
Fluorene
Concen: 0.00 ng/uL
Expected RT: 23.38 min
Lab Pile; ENG1678.D
Acq; 16 Oct 99 6:45 am
Tgt Ion: 166
Ion Exp Ratio
166 100
165 91.3
0 0.0
0 0.0
TIC; ENG1678.D
#11
Fhenanthrene-dl0
Concen: 0.00 ng/uL
Expected RT: 25.69 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 188
Exp Ratio
100
24.5
0.0
0.0
1U"
ENGlfcVB .D—FES3TM"
Tue Oct 19 10:23:40 1999
HP 5989B
V>f)
w u
Page 7
-------
TIC: ENG1678.D
10000
5000
n—i—\—i—i—i—!—i—i—i—i—?—i—i—j—i—r-~i—i—j—i—i—r
(Time--524.50 25.00 25.50 26.00 26.50
Abundancelon 178.00 (177.70 to 178.70} : ENG
lion 176.00 (175.70 to 176.70); ENG
3000
2000
1000
rime--s24.50 25100 25.50 26100 26.50
AburiSance
10000
TTC7~lBGIF7F7Tr
5000
0
I—
rime-->
Sundance I
25 . 00 25.50
168.00
26.00
MBpani
!tu
26.50
1MT
3000
2000
1000
0
MM—¦
on 188.00 (187.70 to 188.70}:
Ion 94.00 (93.70 to 94.70): ENG16
Time-->
T—j—|—j—j—i—i—j—; ! t—I—I—1 I I 1 I I i ?" T" '|
25.00 25.50 26.00 26.50
#12
Phenanthrene
Concen: 0.00 ng/uL
Expected RT: 25.74 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 178
Ion Exp Ratio
178 100
176 20.2
0 0.0
0 0.0
#13
Anthracene-dlO
Concen: 0.00 ng/uL
Expected RT: 25.82 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 188
Ion
188
94
0
Exp Ratio
100
26.6
0.0
0.0
f*- ~ r
¦ , ¦r.
• {J_
ENGIF70—PES 3 .M
Tue Oct 19 10:23:44 1999
HP 5989B
Page 8
-------
TIC: ENG1S78.D
10000 .
5000 -
25.00 25.50 26.00 26.50
Time-->
Abundance Ion 17 8.0 0 (177.70 to 178.70): ENG
lion 176.00 (175.70 to 176.70): ENG
3000:
2000:
iooo :
25.00 25.50 26.00 26.50
#14
Anthracene
Coneen: 0.00 ng/uL
Expected RT: 25.87 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 178
Ion Exp Ratio
178 100
176 19.9
0 0.0
0 0.0
TIC: ENG1678.D
15000
10000
5000 -
t—i—i—i—[—"ft—i i"1 "i—i—!—i—i—r—!—\—i—i—i—r~i—i—r
Time--> 27.50 28.00 28.50 29.00 29.50
#15
Fluoranthene-dlO
Cohcen: 0.00 ng/uL
Expected RT: 28.68 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 212
Exp Ratio
100
27 .3
0.0
0.0
(Abundanceion 2i2,00 (211.70 to 2l2.?0): fiWG
Ion 106.00 (105.70 to 106.70): ENG
4000
2000
Je.ii72
Time - -> 27 .50
ENG'1678 .D—PES3 .M
28.00 28.50
1 1 I '
29 . 00
i—I j ,—j—r
29 .50
i*ue uct is iu:2J:47 iyy¥
HP 5989B
Page 9
-------
abundance TIC: ENG1678.D
15000 4
10000 -
5000 J
Time-->27
I—i—l—!—i—|—I—i—i—I—|—i—I—i—i——i—I—I—i—|—I—i—I—r-
.50 28.00 28.50 29.00 29.50
AbundanceIon 202.00 {201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
3000 -
2000:
1000 -
o:
Time-->27
j i i i i j "t -i ¦¦ r" i | i ""T r~ r-y—r t i i-'t-t" 'r' i "t ¦¦
.50 28.00 28.50 29.00 29150
#16
Fluoranthene(CCC)
Concen: 0,00 ng/uL
Expected RT: 28.73 min
Lab Pile: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 202
Ion Exp Ratio
202 100
101 24.0
0 0.0
0 0.0
Abundance
15000
10000 J
TIC: ENG1678.D
5000 j
0
t—i—i—i—|—i—i—i—i—|—i—i—i—(—I—i—i—i—i—|—i—i—r
28.50 29.00 29.50 30.00
Time-->
Abundance Ion 212.00 (211.70 to 212.70): ENG
Ion 106.00 (105.70 to 106.70); ENG
4000
2000-
Time-->
28.50
29.50 30.00
#17
Pyrene-dlO
Concen: 0.00 ng/uL
Expected RT: 29.29 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 212
Ion
212
106
0
Exp Ratio
100
31.6
0.0
0.0
ENG1678.D—PEH3.M
-i—I—j—I—r
29.00
Tue OCt 19 10:23:51 1999
•e.ii-73
HP 5989B
Page 10
-------
Abundance
15000
10000
5000 J
TIC: EMG1678.D
"i—i—i—i—i—r—!—n—r—i—[—-i—i i i
28150 29.00 29.50 30.00
Time-->
Abundance Ion 202.00 (201.70 to 202.70): ENG
Ion 101.00 (100.70 to 101.70): ENG
3000
2000
1000
t—i—i—[—i—I—i—!—j—I—i—i—i—|—r—1—r—i—t—i—i—r*
Time--> 28.50 29.00 29.50 30.00
#18
Pyrene
Concen: 0.00 ng/uL
Expected RT: 29.34 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion; 202
Ion Exp Ratio
202 100
101 27.6
0 0.0
0 0.0
S5un3Snce
15000
10000
5000
1 { 1 j j , f J J S ! 1 1 J 1—r*
Time--> 28150 29100 29.50 30.00 30.50
TIC: ENG167&.D
1000
Time-
i I 1 '
• > 28.50
J i—i—r" ) i—t—i—»—i—?—i—i—r—-1—i—i—r-
29100 29.50 30100 30150
#19
p-Terphenyl-dl4
Concen: 0.00 ng/uL
Expected RT: 29.62 min
Lab File: ENG167 8.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 244
Exp Ratio
100
29.1
0.0
0.0
Abundance Ion 244.00 (243.70 to 244.70): ENG
Ion 122.00 (121.70 to 122 .70) : ENG
3000
2000
ENGTF7BTD—PES3 1M
A " <¦
; J
Tue Oct ry 10:23:54 1999
HP 5989B
c ^
Page 11
-------
TIC: ENG1678.D
Abundance
15000 J
10000 -
5000
32.50 33,00 33.50 34100
Time - ->
Abundance Ion 240.00 (239.70 to 240.70): ENG
6000Jion 120.00 (119.70 to 120.70): ENG
4000
2000 -
32.50 33100 33150 34.00
#20
Benzo(a)anthracene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.36 min
Lab File: ENG1678.D
Acq; 16 Oct 99 6:45 am
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.9
0 0.0
0 0.0
[Abundance
15000
10000
5000
0
Time-->
TIC: ENG1678.D
32.50 33.00 33.50 34.00
#21
Benzo(a)anthracene
Concen: 0.00 ng/uL
Expected RT: 33.46 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 228
Exp Ratio
100
25 .4
0.0
0.0
Abundance Ion 226.00 (227.70 to 228.70): S
4000Jion 114.00 (113.70 to 114.70): ENG
3000
2000
1000
Time-->
n—f—J—I—I—«—i—i—i—l—i—i 1,1 r i—i—f—T
32150 33.00 33.50 34100
ENG1678.D—PES3.M
00
v. kjl fo
Tue Oct 19 10:23:57 1999
HP 5989B
Page 12
-------
Abundance
15000
10000
5000
TIC: SMG1678.D
0
Time--> 32.50 33.00 33.50 34.00 34.50
Abundance Ion 240.00 (239.70 to 240.70); ENG
6000Jlon 120.00 (119.70 to 120.70): ENG
4000
2000
0
Time--> 32.50
-! T 1 1 1
33; 00
33.50 34.00 34.50
Abundance
15000
10000
5000
*1 1 s ! 1 T "t" '"1—I—i—J—T—! r—J ! s 1 1 1 1 1—t
Time-->32.50 33.00 33.50 34.00 34.50
Abundance Ion 228.00 (227.70 to 228.70)
1MJ"
Ion 114.00 (113.70 to 114.70)
4000
t—i—i—I—j—I—i—I—i—I—i—i—i—i—|—i—i—i—i—j—i—r
fTime--»32150 33.00 33.50 34.00 34.50
#22
Chrysene-dl2
Concen: 0.00 ng/uL
Expected RT: 33.50 rain
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 240
Ion Exp Ratio
240 100
120 27.3
0 0 . 0
0 0.0
TIC: ENG1678.D
3000
2000
1000
ENG1678.0 FEST7W
#23
Chrysene(CGC)
Concen-. 0.00 ng/uL
Expected RT: 33.61 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 228
Ion Exp Ratio
228 100
114 22.3
0 0.0
0 0 . 0
V V. -.J. i t)
•me uct iy io:24:oi lyyy
HP 5989B
Page 13
-------
Abundance
TIC: ENG1678.D
Time-->
10000 .
5000
0
~t—i—i—r~
~i—i—i—r~
-t—i—i—r
38.50 39:00 39.50 40!00
|AbundanceIon 264.00 (263.70 to 264.70): ENG
loil 132.00 (131.70 to 132.70): ENG
4000 "
2000
Time-
1—I—I—|—I—I—!—!—|—I—I—I—r
38.50 39.00 39:50 40:00
Abundance
10000
TIC: ENGl6 7 S . D
5000
1—I—I—I—I—I—1—|—1—' "1—1—j—I—I—I—I
38.50 39.00 39.50 40100
1 1 1
2000
1000:
0
T
Time-->
Abundance Ion 252.00 (251.70 to 252.70): ENG
Ion 126.00 (125.70 to 126.70); ENG
3000:
Time-->
1—r-|—1—1—1—1—1—I—i—1—1—1—1—i—i—1—|—i—rii"ri|iii|i"f""
38.50 39.00 39.50 40.00
#24
Benzo(b)fluoranthene-dl2
Concent 0.00 ng/uL
Expected RT: 39.35 min
Lab File: 1NG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 264
Ion Exp Ratio
264 100
132 69.4
0 0.0
0 0.0
#25
Benzo(b)fluoranthene
Concern 0.00 ng/uL
Expected RT: 39.52 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 27.8
0 0.0
0 0.0
ENGl678.D—PESJ-M
Tue Oct 19 10:24:04 1999
HP 5989B
jjPS Z 4".
Page 14
-------
Abundance
TIC: ENG1678.D
10000
5000
0
-I I 1 1 1
39.00
T f 1 1 1 1 1 1 1 1 1 S 1 1 T~
39 .50 40.00 40 150
Time--> 38.50
Abundance Ion 264.00 (263.70 to 264.70): ENG
Ion 132.00 (131.70 to 132.70): ENG
4000 _
#26
Benzo(k)fluoranthene-dl2
Concen: 0.00 ng/uL
Expected RT: 39.53 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 264
Ion Exp Ratio
264 100
132 35.8
0 0.0
0 0.0
2000
0
Time--> 38.50 39.00
i—i—|—r—r
39.50
40.00
T—i—|—|—r
40.50
Sundance
10000
TIC: SNG1S78.D
5000
Time - ->
39.00 39150 40.00 40.50
W
2000
1000
Abundance Ion 252,00 (251.70 to 252.70): ENG
-lion 126.00 (125.70 to 126.70):
3000:
rime-->
-i—r—i—i—i—i r |—i—rr~
T""J""i ?'"f""
39.00 39.50 40.00 40.50
#27
Benzo(k)fluoranthene
Concen: 0.00 ng/uL
Expected RT: 39.67 min
Lab File: ENG1678.D
Acq; 16 Oct 99 6:45 am
Tgt Ion: 252
Ion
252
126
0
0
Exp Ratio
100
27.6
0.0
0.0
000 ;
ENGXET8TD PES3 .M
"Tue Oct 19 10:24:08 1999
HP 5989B
Page 15
-------
Abundance
TIC: ENG1578.D
10000
5000
0
Time - -> 4ol5o' 4l!o'o' 41! 50 42 ! 00 42150
Abundance Ion 264.00 (263.70 to 264.70): MG
Ion 132.00 {131.70 to 132.70): SNG
#28
Benzo(a)pyrene~dl2
Concen: 0.00 ng/uL
Expected RT: 41.61 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 264
Ion Exp Ratio
264 100
132 37.8
0 0.0
0 0.0
4000
2000
rime--> 40.50 41.00 41.50 42.00 42.50
Abundance
TIC: ENG1678
.D
10000 -
5000 J
0 _
Time-->
i i
41.00 42.00
43 .00
AbundanceIon
252.00 (251.70 to
252.70): SMG
Ion
126.00 (125.70 to
126.70): ENG
4000 J
/ i
pi—* i,A« ilwV>w«w«>^
i 1 i i 1 i i i
41.00 42.00
1 1 1 1 1
43.00
#29
Benzo(a)pyrene(CCC)
Concen: 0.00 ng/uL
Expected RT: 41.79 min
Lab File: ENG1678.D
Acq: 16 Oct 99 6:45 am
Tgt Ion: 252
Ion Exp Ratio
252 100
126 31.2
0 0.0
0 0.0
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