Ventilation Air Methane (VAM) Utilization Technologies December 2010 Why is VAM Mitigation Important? Methane, the principal component of natural gas, is often present in deep coal seams and is a safety hazard to miners because it is explosive in con- centrations ranging from 5 to 15 percent in air. Therefore, gassy underground coal mines employ large-scale ventilation systems. These systems dilute methane released into the mine workings as coal is extracted and remove the gas from the mine, thereby maintaining safe working conditions. In-mine methane concentrations must be maintained well below the lower explo- sive limit, so ventilation air exhausts carry only very dilute concentrations of methane (typically less than 1 percent and often less than 0.5 percent). However, because flow rates are so high, ventilation air methane (VAM) constitutes the largest source of methane emissions at most mines. VAM exhausts not only waste a clean energy resource but also contribute signifi- cantly to global greenhouse gas emissions. Methane has a global warming potential 23 times that of carbon dioxide, so successfully deploying technologies to convert VAM into useful forms of energy (such as electricity and heat) can result in very substantial greenhouse gas emission reductions. Ventilation exhaust (evase) (Photo courtesy of H. Lee Schuitz) Utilization Technologies: VAM as Supplemental Fuel Internal Combustion Engines/Turbines/Boilers: Some technologies for beneficial- ly using the energy content of ventilation air exhausts are currently available, while others are in the development and demonstration phase. One existing approach is quite straightforward and entails using VAM as combustion air, thereby supplying ancillary fuel to internal combustion (IC) engines, turbines, or industrial and utility boilers. Such VAM use in IC engines running on drained coal mine methane has been well demonstrated. The Appin Colliery in New South Wales, Australia implemented a project employing 54 VAM/coal mine methane driven internal combustion engines to power generators that produced 55.6 MW of electricity for the mine. Although Available and Developing Options for VAM Utilization • VAM used as a supplemental fuel (i.e., combustion air) Internal combustion engines - Turbines - Utility or industrial boilers - Hybrid rotary kiln/gas turbine • VAM used as the principal fuel - Flow-reversal oxidizers, with or without energy recovery » Thermal » Catalytic - Gas turbines—microturbines (e.g., 30 kW) and full sized turbines (>0.5 MW) Appin power plant (Photo courtesy of EDL) using ventilation exhaust as combustion air in large utility or industrial boilers has been demonstrated on a pilot scale at the Vales Point Power Station in Australia, this option is limited by the need to site the facility near the mine. In contrast, IC engines and turbines are readily deployable at remote locations. In addition, EESTech Inc. acquired the rights to an innovative rotary EPA Coalbed Methane Outreach Program Technical Options Series www.epa.gov/cmop 1 ------- Ventilation Air Methane (VAM) Utilization Technologies kiln system that burns waste coal with ventilation air methane or drained coal mine methane. In this application, VAM again is a supplemental fuel. The mixed fuel is combusted in the kiln, and the exhaust gases pass through a specially designed air-to-air heat exchanger. The heated clean air then powers a turbine to produce electricity. The waste coal feed can be adjusted in response to variations in VAM flow or concentration, allowing for a constant energy feed to the turbine for electricity generation. By combusting waste coal and VAM, this technology offers the ability to mitigate methane emissions while also reducing acid runoff from (and spontaneous combustion of) waste coal piles. The technology was developed jointly by Australia's Commonwealth Scientific and Industrial Research Organisation (CSIRO) and Liquatech Turbine Company Pty., and a 1.2 MW pilot plant was constructed at CSIRO's Queensland Centre for Advanced Technologies. EESTech is standardizing designs for 10 MW and 30 MW systems and is actively commercializing the technology in China and India. Because it avoids the water requirements of steam-cycle power generation, the hybrid coal and gas turbine is appropri- ate for remote locations where waste coal and methane are available but water is scarce. Utilization Technologies: VAM as Primary Fuel Flow-reversal Oxidizers: Both thermal and catalytic systems are commercially available and capable of oxidizing VAM. When VAM enters an oxidizer, the gas encounters a bed of heat exchange material that has been preheated to the oxi- dation temperature of methane (1000° C). The VAM oxidizes and releases heat, which in turn maintains the temperature of the heat transfer material at or above 1000° C, thereby sustaining the auto-oxidation process without requiring addi- tional fuel input. Valves and dampers repeatedly reverse the flow of incoming VAM to keep the hot zone in the center of the oxidizer. Catalytic and thermal systems both operate on this principal, although catalysts allow the reaction to occur at lower temperatures. When VAM concentrations are high enough, thermal oxidizers can provide excess heat energy for uses such as electricity generation. This end-use is currently being employed at the West Cliff Colliery in New South Wales, Australia. The West Cliff Ventilation Air Methane Project (WestVAMP) is the world's first commercial-scale VAM-to-power project. Building upon earlier demonstrations of VAM oxidation and steam genera- tion in the UK and Australia, WestVAMP started operation in September 2007 and is producing 6 MW of power for use by the mine. It employs a thermal flow-reversal oxidizer, the VOCSIDIZER™, manufactured by MEGTEC Systems. Another project deploying the VOCSIDIZER™ is in the planning stages at the Datong coal mine in China's Chongqing municipality. This will be the largest VAM oxidation project in the world to mitigate methane emissions and generate thermal energy. Hybrid waste coalNAM rotary kiln (Photo courtesy of Com Energy) WestVAMP (Photo courtesy of MEGTEC) EPA Coalbed Methane Outreach Program Technical Options Series www.epa.gov/cmop 2 ------- Ventilation Air Methane (VAM) Utilization Technologies Biothermica, a Canadian air pollution control equipment supplier, offers a VAM oxidizer called the VAMOX™. A VAMQX™ unit has been deployed in a successful demonstration program at the Jim Walters Resources mine in Brookwood, Alabama since March 2009. The project is the first to operate at an active underground coal mine in the United States. Lean-fuel Gas Turbines: CSIRO developed a lean-fuel gas turbine, the VAMCAT, that employs a catalytic combustor to run on VAM concentrations in the 1 percent range. In most field applications, this technology will require the availability of supplemental fuel (e.g., drained coal mine methane) that can be blended in to increase the methane concentration entering the turbine to approximately 1 percent methane. Three other oxidizer manufacturers have recently entered the VAM market. Gulf Coast Environmental Systems, LLC provides a thermal flow-reversal oxidizer, the CH4 RTO (regenerative thermal oxidizer), that uses a shipping container as the oxidizer shell, thereby reducing manufacturing costs. China's Shengdong Group is offering a VAM oxidizer that has been field tested for energy recovery (i.e., steam produc- tion) at two Chinese mines (Bingchang mine in Shanxi province and Pingmei mine in Henan province). Diirr Environmental and Energy Systems manufactures both tra- ditional oxidizers and the Ecopure® RL rotary RTO, which avoids the use of poppet valves and dampers by employing a single rotary valve to control the flow-reversal process. Finally, Canada's CANMET Energy and Technology Centre developed a prototype catalytic VAM oxidizer called the CH4MIN. VAMOX7" Project (Photo courtesy of Biothermica) Flex-Microturbine1M (Photo courtesy of Flexenergy) In cooperation with Capstone Turbines, FlexEnergy of- fers a lean-fuel microturbine (Flex-Microturbine™) that is capable of using methane concentrations as low as 1.5 percent for its principal fuel. The system accepts fuel at atmospheric pressure and, by employing cata- lytic combustion, is able to operate with very low NGX emissions (below 0.1 ppm). The units can generate up to 30 kW of electrical power each and, in proof-of-con- cept testing, were shown to achieve nearly full power running on fuels equivalent to <2 percent methane. A FlexEnergy turbine has been installed at the DCOR oilfield near Santa Barbara, California, to consume oilfield gas at concentrations ranging from 1.5 to 4.2 percent, and another is running on coal process waste gas at the Western Research Institute in Laramie, Wyoming. Although no VAM field testing has been performed to date, the system would be applicable to settings where blending gas is available in quantities adequate to raise methane concentrations in the mine exhaust up to the operating concentration of 1.5 percent. VAMCAT schematic (Image courtesy of CSIRO) EPA Coalbed Methane Outreach Program Technical Options Series www.epa.gov/cmop 3 ------- Ventilation Air Methane (VAM) Utilization Technologies For More Information... To obtain more information about emerging VAM mitigation technologies, contact; Biothermica Technologies Inc. 426, rue Sherbrooke Est Montreal, Quebec H2L1J6 Nicolas Duplessis, Director of Development Phone: (514) 488-3881 E-mail: nicolas.duplessis@biother~ mica.com http://www.biothermica.com/technolo- gies/en/air_vamox.html CANMET 1615 Lionel-Boulet Boulevard P.O. Box 4800 Varennes, Quebec, Canada J3X 1S6 Jacques Grau, Business Development Officer Phone: (450) 652-5177 E-mail: jacques.grou@nrcan.gc.ca http://canmetenergy-canmetenergie. nrcan-rncan.gc.ca Commonwealth Scientific and Industrial Research Organisation PO Box 883 Kenmore, Queensland, Australia 4069 Dr. Su Shi, Project Leader Phone: 61-7-3327 4679 E-mail: shi.su@csiro.au http://www.csiro.au Diirr 40600 Plymouth Road Plymouth, Ml 48170-4297 Jim Stone, National Service Manager Phone: (630) 443-0636 E-mail: james.stone@durrusa.com http://www.durr.com/en EESTech Ground Floor, Engineering House 447 Upper Edward Street Brisbane, Queensland, Australia 4000 Ian Hutcheson, CFO Phone: 61-7-3832-9883 E-mail: ihutcheson@eestechinc.com http://www.eestechinc.com/index. php?page=16 FlexEnergy 22922 Tiagua Mission Viejo, CA 92692 Edan Prabhu, President Phone: (949) 380-4899 E-mail: EDANPRABHU@COX.NET http ://w ww.f I exen e rgy. co m Gulf Coast Environmental Systems, LLC 18150 Interstate 45 North Willis, TX 77318 Mark Owen, VAM Manager Phone: (949) 783-0464 E-Mail: mowen@gcesystems.com http://www.gcesystems.com MEGTEC Systems Theros Svenssons Gata 10 SE-417 55 Gothenburg, Sweden 41755 Richard Mattus, Business Manager Phone: 46 (0)31 65 78 19 E-mail: rmattus@megtec.se http://www.megtec.com Contact EPA's Coalbed Methane Outreach Program for more information about this and other profitable uses for coal mine methane: Coalbed Methane Outreach Program Dr. Jayne Somers U.S. Environmental Protection Agency Phone: (202) 343-9896 Washington, DC E-mail: somers.jayne@epa.gov Website http://www.epa.gov/coalbed The mention of products or services in this case study does not constitute an endorsement by EPA. 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