EPA/600/R-17/389 | September 2017
www.epq.qov/hoinelarid-securitv-research
United States
Environmental Protection
Agency

Sample Collection Information
Document for Chemicals,
Radiochemicals and Biotoxins
Companion to Selected Analytical Methods for
Environmental Remediation and Recovery
(SAM) 2017
Office of Research and Development
Homeland Security Research Program

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Sample Collection Information
Document for Chemicals,
Radiochemicals and Biotoxins
Companion to Selected Analytical Methods for
Environmental Remediation and Recovery
(SAM) 2017
by
Romy Campisano, Kathy Hall, Stuart Willison
Threat and Consequence Division
Matthew Magnuson
Water Infrastructure Protection Division
National Homeland Security Research Center
Cincinnati, OH 45268
John Griggs
National Analytical Radiation Environmental Laboratory
Office of Air and Radiation Office of Radiation and Indoor Air
Montgomery, AL 36115
Steve Reimer
U.S. EPA Region 10 - Manchester Laboratory
Port Orchard, WA 98366
Heath Mash
National Risk Management Research Laboratory
Cincinnati, OH 45268

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SAM Companion - Sample Collection Information Document
Disclaimer
This document is undergoing review in accordance with EPA policy prior to publication. Note that
approval for publication does not signify that the contents necessarily reflect the views of the Agency.
Mention of trade names, products, or services does not convey EPA approval, endorsement, or
recommendation.
Questions concerning this document or its application should be addressed to:
Romy Campisano
National Homeland Security Research Center
Office of Research and Development (NG16)
U.S. Environmental Protection Agency
26 West Martin Luther King Drive
Cincinnati, OH 45268
(513) 569-7016
campisano.romv@, epa.gov
Kathy Hall
National Homeland Security Research Center
Office of Research and Development (NG16)
U.S. Environmental Protection Agency
26 West Martin Luther King Drive
Cincinnati, OH 45268
(513) 379-5260
hall.kathv@,epa.gov
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Acronyms and Abbreviations
AOAC	AOAC International (formerly the Association of Official Analytical Chemists)
Anal. Chem.	Analytical Chemistry
APHA	American Public Health Association
ASTM	ASTM International (formerly American Society for Testing and Materials)
BZ	Quinuclidinyl benzilate
°C	Degree Celsius
CDC	U.S. Centers for Disease Control and Prevention
CFR	Code of Federal Regulations
CLP	Contract Laboratory Program
cm	Centimeter(s)
cm2	Centimeter(s) squared
COC	Chain of custody
CVAA	2-Chlorovinylarsonous acid
CVAOA	2-Chlorovinylarsonic acid
DAS	Diacetoxyscirpenol
DGR	Dangerous Goods Regulations
DHS	U.S. Department of Homeland Security
DIMP	Diisopropyl methylphosphonate
DNPH	Dinitrophenylhydrazine
DOE	U.S. Department of Energy
DOL	U.S. Department of Labor
DOT	U.S. Department of Transportation
EA2192	[S-2-(diisopropylamino) ethylmethylphosphono-thioic acid]
ECL	Electrochemiluminescence
ED	Ethyldichloroarsine
EDEA	N-Ethyldiethanolamine
ELFA	Enzyme-linked fluorescent immunoassay
ELISA	Enzyme-linked immunosorbent assay
EMPA	Ethyl methylphosphonic acid
EMSL	Environmental Monitoring and Support Laboratory
EPA	U.S. Environmental Protection Agency
ERT	Environmental Response Team (EPA)
ft2	Square foot (square feet)
FDA	U.S. Food and Drug Administration
FRET	Fluorescence resonance energy transfer
FRMAC	Federal Radiological Monitoring and Assessment Center
g	Gram(s)
GA	Tabun
gal	Gallon
GB	Sarin
GD	Soman
GE	1-Methylethyl ester ethyl phosphonofluoridic acid
GF	Cyclohexyl sarin
GPS	Global Positioning System
HASL	Health and Safety Laboratory, currently known as Environmental Measurements
Laboratory (EML)
HASP	Health and Safety Plan
HC1	Hydrochloric acid
HD	Mustard, sulfur
Hg	Mercury
Hg(CN)2	Mercury (II) cyanide
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HILIC MS-MS
2-HMP
HMTD
HMX
HN-1
HN-2
HN-3
HN03
HPLC-FL
HSRP
i.d.
I AT A
IMPA
10
ISM
ISO
kPpa
L
L-l
L-2
L-3
lbs
LC-ESI-MS-MS
LC-MS
LC-MS-MS
LC-UV
LFA
M
m3
jiL
(im
MALDI-TOF-MS
MCE
MDEA
mg
min
mL
mm
mM
MPA
NA
Na2C03
NaOH
NAREL
NEMI
NH3
NH4CI
NH4OH
NHSRC
NIOSH
n.o.s.
NTT A A
o.d.
Hydrophilic interaction-tandem mass spectrometry
(2-[hydroxymethyl] piperidine)
Hexamethylenetriperoxidediamine
Octahydro-1,3,5,7-tetranitro-1,3,5,7 -tetrazocine
Mustard 1, nitrogen
Mustard 2, nitrogen
Mustard 3, nitrogen
Nitric acid
High performance liquid chromatography-fluorescence
Homeland Security Research Program
Inner diameter
International Air Transportation Association
Isopropyl methylphosphonic acid
Inorganic
Inorganic Superfund Methods
International Organization for Standardization
Kilopascals
Liter(s)
Lewisite 1
Lewisite 2
Lewisite 3
Pounds
Liquid chromatography-electrospray ionization-tandem mass spectrometry
Liquid chromatography-mass spectrometry
Liquid chromatography-tandem mass spectrometry
Liquid chromatography-ultraviolet
Lateral flow immunoassay
Molar
Cubic meter(s)
Microliter(s)
Micrometer(s)
Matrix-assisted laser desorption ionization-time-of-flight mass spectrometry
Mixed cellulose ester
N-Methyl diethanolamine
Milligram(s)
Minute(s)
Milliliter(s)
Millimeter(s)
Millimolar
Methylphosphonic acid
Not applicable
Sodium carbonate
Sodium hydroxide
National Air and Radiation Environmental Laboratory (EPA)
National Environmental Methods Index
Ammonia
Ammonium chloride
Ammonium hydroxide
National Homeland Security Research Center (EPA)
National Institute for Occupational Safety and Health
Not otherwise specified
National Technology Transfer and Advancement Act
Outer diameter
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OMB
Office of Management and Budget Directives
ORD
Office of Research and Development (EPA)
ORISE
Oak Ridge Institute for Science and Education
OSHA
Occupational Safety and Health Administration
OVS
OSHA versatile sampler
OW
Office of Water (EPA)
oz.
Ounce (s)
PETN
Pentaerythritol tetranitrate
Pg-
Page(s)
PHILIS
Portable High-Throughput Integrated Laboratory Identification Systems
PMPA
Pinacolyl methyl phosphonic acid
ppbv
Parts-per-billion by volume
PPE
Personal protective equipment
PPm
Parts per million
pptv
Parts per trillion by volume
psig
Pounds per square inch gauge
PSN
Proper shipping name
PTFE
Polytetrafluoroethylene
PUF
Polyurethane foam
PVC
Polyvinyl chloride
QC
Quality control
R 33
Methylphosphonic acid, S-[2-(diethylamino)ethyl]0-2-methylpropylester]
RDX
Hexahydro-1,3,5 -trinitro-1,3,5 -triazine
RESL
Radiological and Environmental Sciences Laboratory
Rev
Revision
SAM
Selected Analytical Methods for Environmental Remediation and Recovery
SCID
Sample Collection Information Document
SCP
Sample Collection Plan
SM
Standard Methods for the Examination of Water and Wastewater
SOP
Standard Operating Procedure
SRS
Savannah River National Laboratory, Savannah River Site
SW
Solid Waste
TBD
To be determined
TDG
Thiodiglycol
TEA
T riethanolamine
TEPP
Tetraethyl pyrophosphate
TETS
T etramethylenedisulfotetramine
TI
Transportation Index
1,3,5-TNB
1,3,5 -T rinitrobenzene
2,4,6-TNT
2,4,6-Trinitrotoluene
TO
Toxic organics
UN#
United Nations numbers
USGS
United States Geological Survey
VCSB
Voluntary Consensus Standards Body
VOA
Volatile Organic Analysis
Vol.
Volume
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Acknowledgments
This document was developed by the U.S. Environmental Protection Agency's (EPA) Homeland Security
Research Program (HSRP) within EPA's Office of Research and Development as a companion to
Selected Analytical Methods for Environmental Remediation and Recovery (SAM) 2017. The document
was prepared by CSRA Inc. under EPA Contract No. EP-C-15-012. Contributions of the following
individuals and organizations to the development of the information provided in this document are
acknowledged:
•	Joan Bursey, EPA, NHSRC (SEE Grantee)
•	Romy Campisano, EPA, NHSRC
•	Lesley V. D'Anglada, EPA, Office of Water
•	George Gardenier, EPA, Office ofWater
•	Diane Gregg, EPA, Region 6 Laboratory
•	John Griggs, EPA, National Analytical Radiation Environmental Laboratory
•	Kathy Hall, EPA, NHSRC
•	Scott Hudson, EPA, Office of Land and Emergency Management
•	Mario Ierardi, EPA, Office of Land and Emergency Management
•	Matthew Magnuson, EPA, NHSRC
•	Heath Mash, EPA, National Risk Management Research Laboratory
•	Emily Parry, EPA, NHSRC
•	Steve Reimer, EPA, Region 10 Laboratory
•	Sanjiv Shah, EPA, NHSRC
•	Erin Silvestri, EPA, NHSRC
•	James Sinclair, EPA, Office ofWater
•	Gerard Stelma, EPA, National Exposure Research Laboratory
•	Allison Tamasi, EPA, National Exposure Research Laboratory
•	Sue Warner, EPA, Region 3 Laboratory
•	Ernest Waterman, EPA, New England Regional Laboratory
•	Stuart Willison, EPA, NHSRC
•	Jeanette Van Emon, EPA, National Exposure Research Laboratory
•	Shen-yi Yang, EPA, Office of Land and Emergency Management
•	Rebecca Coleman, U.S. Centers for Disease Control and Prevention
•	Marcie Jaffee, U.S. Centers for Disease Control and Prevention
•	Richard Wang, U.S. Centers for Disease Control and Prevention
•	Luisa Cheng, U.S. Department of Agriculture
•	Xiaohua He, U.S. Department of Agriculture
•	Gretchen Farming, U.S. Air Force
•	Marty Johnson, U.S. Army
•	Aurelie Soreefan, U.S. Air Force
•	Sara McGrath, U.S. Food and Drug Administration
•	Shashi Sharma, U.S. Food and Drug Administration
•	Peter Moeller, National Oceanic & Atmospheric Administration
•	Donivan Porterfield, Los Alamos National Laboratory
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•	Sanwat Chaudhuri, Utah Public Health Laboratory
•	Heather Raymond, Ohio EPA
•	Anthony Rattonetti, San Francisco Public Utilities Commission Southeast Laboratory
•	Bob Read, Tennessee Department of Health
•	Christopher Retarides, Virginia Division of Consolidated Laboratory Services
•	Eric Boring, CSRA, Inc.
•	John Chandler, CSRA, Inc.
•	Sang Chung, Consolidated Safety Services, Inc.
•	Joan Cuddeback, CSRA, Inc.
•	W. Gordeuk, Consolidated Safety Services, Inc.
•	Kelly Head, Consolidated Safety Services, Inc.
•	Emily King, CSRA, Inc.
•	Robert Rosson, CSRA, Inc.
•	Sarah Staggs, Consolidated Safety Services, Inc.
•	Jim Travis, Consolidated Safety Services, Inc.
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Table of Contents
DISCLAIMER	M
ACRONYMS AND ABBREVIATIONS	Mi
ACKNOWLEDGMENTS	vi
LIST OF ATTACHMENTS	ix
SAMPLE COLLECTION INFORMATION DOCUMENT	1
1.0 BACKGROUND	1
2.0 SCOPE AND APPLICATION	1
2.1	Sample Collection Information Attachments	2
2.2	Document Development	2
2.3	Limitations	4
3.0 HEALTH AND SAFETY CONSIDERATIONS	4
3.1	Heal th and Safety Plans	4
3.2	Personal Protective Equipment and Monitoring	5
3.3	Training	5
4.0 PREPARATION FOR SAMPLE COLLECTION	5
4.1	Field Sampling Equipment and Supplies	6
4.2	Field Data Documentation	6
4.3	Equipment Operation and Calibration	7
5.0 PREPARATION OF SAMPLE CONTAINERS	7
5.1	Sample Container Labels	7
5.2	Preparing Sample Containers for Packaging	7
5.3	General Sample Shipment Guidelines	7
5.4	Chain-of-Custody Forms	8
5.5	Custody Seals/Tamper-evidentBags	8
6.0 DEFINITIONS	9
7.0 BIBLIOGRAPHY	11
List of Attachments
Attachment A: Sample Collection Information for the Chemical Analytes and Methods Listed in
SAM 2017
Attachment B1: Sample Collection Information for the Environmental Sample Types, Radiochemical
Analytes and Methods Listed in SAM 2017
Attachment B2: Sample Collection Information for the Outdoor Building and Infrastructure Materials,
Radiochemical Analytes and Methods Listed in SAM 2017
Attachment C: Sample Collection Information for the Biotoxins and Methods Listed in SAM 2017
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Sample Collection Information Document
for Chemicals, Radiochemicals and Biotoxins
[Companion to Selected Analytical Methods for Environmental Remediation
and Recovery (SAM) 2017]
1.0 Background
The U.S. Environmental Protection Agency's (EPA's) Homeland Security Research Program
(HSRP) has worked with experts from across EPA and its sister agencies since 2003 to develop a
compendium of analytical methods to be used when responding to intentional or unintentional
contamination incidents. Analytical methods have been selected for chemical, radiochemical,
pathogen and biotoxin analytes of concern for the types of environmental sample matrices that
are anticipated in such incidents. The results of these efforts have been published in several
revisions of EPA's Selected Analytical Methods for Environmental Remediation and Recovery
(SAM).1 HSRP periodically reviews and updates this information to address the needs of
homeland security, reflect improvements in analytical methods and new technologies, and
incorporate changes in target analytes.
In support of efforts to select appropriate analytical methods, EPA also recognizes the need for
companion documents to provide information regarding collection of samples for analysis using
the selected methods. This document is intended to address this need, in part, by providing
information regarding sample containers, preservation, size, packaging and sources for
additional information supporting collection of chemical, radiochemical and biotoxin samples to
be analyzed using the methods selected. As with SAM 2017, HSRP plans to update the
information in this document periodically, to reflect changes to the analytes addressed and/or
methods that have been selected.
The information contained in this document is intended to support and be used with the
methods listed in EPA's SAM 2017. The information will be reviewed and updated
periodically, along with the selected methods, to reflect advances in technologies, results
of method evaluation and validation studies, and additional analytes or matrices.
2.0 Scope and Application
This Sample Collection Information Document (SCID) provides general information for use by
EPA and its contractors when collecting samples during environmental remediation following a
contamination incident. The document is intended to be used with SAM 2017 (EPA/600/R-
17/356; U.S. EPA 2017) and to provide information needed for collection of samples to be
analyzed using the specific methods and procedures that have been selected for chemicals,
radiochemicals and biotoxins. Where possible, the information provided was obtained from the
sample collection requirements and guidelines included in the analytical methods. Where this
information was not available, additional sources were used (see Section 7.0).
The information in this document is intended to be used during site assessment, remediation and
clearance activities following a contamination incident; it assumes that samples will be collected
1 Selected Analytical Methods for Environmental Remediation and Recovery (SAM) and its methods are available at:
https ://www. epa. gov/homeland-securitv-research/sam.
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by personnel trained in collection of environmental samples suspected of containing the target
analytes and in dealing with the corresponding safety concerns. Information is included regarding
containers, collection volume or weight, preservation, holding times, and packaging of samples
representing the sample types and analytes included in SAM 2017. Sample collection information
for pathogens is addressed in a separate document.2 Sample collection personnel should consult
the incident-specific Sample Collection Plan (SCP) and/or receiving laboratory(ies) prior to
initiating sample collection activities.
NOTE: It is possible that some of the information in this document should be modified to address
site- or incident-specific data needs; for example, additional sample volume may be needed for quality
control (QC) or in cases where an unusually low level is required to meet site clearance goals. Sample
Collection Plans (SCPs) should be in place and consulted for specific sample collection requirements
prior to initiation of sample collection activities. Site- or incident-specific SCPs include information
regarding laboratory capacity; the extent of contamination; target analytes, including their preservation
and holding times; data quality objectives; sample locations; and the number and type of samples
needed.
2.1	Sample Collection Information Attachments
This document contains the following attachments listing information for collection
of samples that will be analyzed for measurement of the analytes listed in Selected
Analytical Methods for Environmental Remediation and Recovery.
•	Attachment A: Sample Collection Information for the Chemical Analytes and
Methods Listed in SAM 2017
•	Attachment B1: Sample Collection Information for the Environmental Samples,
Radiochemical Analytes and Methods Listed in SAM 2017
•	Attachment B2: Sample Collection Information for the Outdoor Building and
Infrastructure Materials, Radiochemical Analytes and Methods Listed in SAM 2017
•	Attachment C: Sample Collection Information for the Biotoxins and Methods Listed
in SAM 2017
Each attachment provides the sample size that should be collected to support sample
analysis, the preservatives and/or temperature needed to maintain sample integrity prior
to analysis, the maximum amount of time that should elapse between sample collection
and the initiation of analytical procedures (e.g., sample analysis, digestion or extraction),
the appropriate type of container, the sample label and packaging procedures needed for
sample shipment, and the source(s) used to provide the information. The information in
each attachment is arranged by analyte and corresponds to the sample types that are
addressed by the analytical methods that have been selected.
2.2	Document Development
EPA employed several references to identify the information that is included in this
2 EPA's Sample Collection Information Document for Pathogens - Companion to SAM 2017 (U.S. EPA.
EPA/600/R-17/374) is available at: https://www.epa.gov/homeland-securitv-research/sam-companion-documents-
and-sample-collection-procedures
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document. The first sources consulted were the methods listed in SAM 2017. These
methods are listed in the "Selected Analytical Methods" columns throughout Appendices
A, Bl, B2 and C. If the selected methods include sample collection information, the
information was evaluated and, if appropriate, included in the sample collection
information tables provided in Attachments A, Bl, B2 and C. The second sources
consulted were EPA procedures for collection of samples addressing the specific
analyte/matrix pairs. If there were no EPA procedures available, other federal agency or
Voluntary Consensus Standards Body (VCSB)3 methods were consulted, and best
professional judgment applied by technical work groups to address collection of each of
the analyte/sample type pairs. In many cases, information was adjusted for consistency
across similar analytes (e.g., volatile organic compounds) and sample types, to facilitate
sample collection without compromising analytical results.
Information was evaluated from the following agencies, organizations, and publications:
•	EPA - United States Environmental Protection Agency
•	AO AC International (formerly Association of Official Analytical Chemists)
•	ASTM - ASTM International (formerly American Society for Testing and Materials)
•	CFR - Code of Federal Regulations
•	U.S. CDC - United States Centers for Disease Control and Prevention
•	USDA - United States Department of Agriculture
•	U.S. DHS - United States Department of Homeland Security
•	U.S. DOE - United States Department of Energy
•	U.S. DOL - United States Department of Labor
•	U.S. DOT - United States Department of Transportation
•	U.S. FDA - United States Food and Drug Administration
•	USGS - United States Geological Survey
•	IATA - International Air Transport Association
•	ISO - International Organization for Standardization
•	NEMI - National Environmental Methods Index
•	NIOSH - National Institute for Occupational Safety and Health
•	OPCW - Organisation for the Prohibition of Chemical Weapons
•	OSHA - Occupational Safety and Health Administration
•	Standard Methods for the Examination of Water and Wastewater, 22nd Edition. 2005.
American Public Health Association
•	Journals: Analyst, Chromatographia, European Journal of Lipid Science and
Technology, Journal of Chromatography A, Journal of Chromatography B, Journal
of Forensic Sciences, Water Research
Sample collection information was not identified for all the analyte/sample type pairs
listed in SAM 2017. In some cases, "TBD" (to be determined) is used to identify gaps of
information that have yet to be determined. In other cases, analytes are listed as not a
concern in a particular sample type; in these cases, SAM work groups have determined
that the analyte is not a concern due to a number of factors, including low likelihood of
persistence, toxicity, mobility or solubility.
3 EPA OMB Circular No. A-l 19, February 1998. VCSBs are domestic or international organizations which plan,
develop, establish, or coordinate voluntary consensus standards using agreed-upon procedures. Under the National
Technology Transfer and Advancement Act (NTTAA), participation of federal representatives in VCSBs is
encouraged to increase the likelihood that the standards they develop will meet both public and private sector needs.
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2.3 Limitations
This document provides summary information only regarding collection of samples to be
analyzed for measurement of the chemicals, radiochemicals and biotoxins listed in SAM
2017. It does not provide details regarding sample collection procedures or the
corresponding analytical methods. Although at this time much of the information has not
been tested for some of the analytes or sample types, the information listed is considered
to be the most appropriate currently available. Many of the target analytes listed in this
document have only recently become an environmental concern, and EPA is actively
pursuing development and validation of appropriate sample collection procedures. Users
should consult the SAM website for periodic updates: https://www.epa.gov/homeland-
securitv-research/sam.
Sample collection plans must be consulted for site- or incident-specific requirements,
including QC and reporting. The information sources cited in this document also should
be consulted for additional details regarding sample collection, including QC
requirements, sample handling, packaging, shipping, and safety procedures. Sample
collectors should check with the incident commanders for special instructions regarding
evidentiary matters prior to sample collection.
3.0 Health and Safety Considerations
This document assumes that a site- or incident-specific Health and Safety Plan (HASP) is in place
that includes the safety concerns and requirements regarding the specific types of hazards that
should be considered during sample collection. This section provides general guidelines regarding
health and safety concerns. At a minimum, all sampling team members should be trained in
Occupational Safety and Health Administration (OSHA) requirements for hazardous waste
operations and emergency response at 29 CFR 1910.120 or 29 CFR 1926.65 and have current
medical screening.
3.1 Health and Safety Plans
Health and Safety Plans (HASPs) will vary depending on the site, the sampling phase
(site assessment, remediation or final status determination) and the responsible
organization. The purpose of these plans is to ensure maximum protection to workers, the
environment and surrounding communities, in a way that is consistent with requirements
needed to perform operational activities. HASPs should follow guidelines provided by
OSHA at: https://www.osha.gov/Publications/OSHA3114/OSHA-3114-hazwoper.pdf
(last accessed September 2017). At a minimum, HASPs should include instructions and
guidelines regarding:
Names, positions, and contact information of key personnel and of health and safety
personnel
Site- or incident-specific risk assessment addressing sample collection activities
Training requirements
Personal protective equipment (PPE) on site and usage requirements
Medical screening requirements (maintain confidential documents properly and
securely)
Site or incident control
Emergency response plan, containing off-site emergency contact information such as
local hazardous materials response teams or additional trained rescue personnel (29
CFR 1910.38)
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Entry and egress procedures
Spill containment
Decontamination procedures
NOTE: Entry and decontamination procedures should address personnel monitoring and
decontamination during entry and egress.
3.2	Personal Protective Equipment and Monitoring
Each site or incident also will dictate the level of PPE that will be required. Selection of
protective clothing is dependent on site conditions and sample collection requirements
included in the SCP. Specific guidance for selection of PPE is provided in 29 CFR
1910.120, Appendix B. Factors that should be considered during selection include:
contaminant identification, routes of exposure (i.e., inhalation, skin absorption, ingestion
and injection), performance of equipment in protecting against exposure, activity
duration, and stress induced by work requirements. Because the use of PPE can also
cause hazards to workers (e.g., heat stress, impaired vision and mobility), care should be
taken to provide a level of protection that is sufficient to prevent exposure yet is not so
high as to create other unnecessary hazards.
3.3	Training
Sample collectors must be trained in collection and handling of samples suspected of
containing the contaminants of concern (see Attachments A, Bl, B2 and C) and must be
up to date regarding medical screening requirements. Additionally, sample collectors and
packers must be trained in and comply with the site HASP and all site-specific training
requirements, including the following:
Ability to select and work with the appropriate level of PPE
Ability to utilize personnel monitoring equipment
Decontamination procedures
Prevention of sample cross-contamination
Training frequency and documentation
4.0 Preparation for Sample Collection
It is highly recommended that sampling kits be used during sample collection, and that these kits
be properly equipped, maintained, and organized before deployment of sample collection
personnel. These kits should be checked for quality assurance prior to initiation of sample
collection activities. Sample collectors should consult with project managers and the SCP to
determine what equipment and materials should be assembled, whether samples should be
preserved in the field, and how sample containers will be packaged for shipment. Prior to sample
collection, sample collectors should also contact the laboratory that will be analyzing the samples
to understand laboratory-specific requirements. Sample kits should contain all containers,
materials, supplies and forms needed to perform sample collection, decontamination,
documentation and field packaging activities. Procedures for preparing samples for shipment
should be in place and understood.
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4.1	Field Sampling Equipment and Supplies
Before starting field sampling activities, all necessary equipment and supplies should be
checked, identified and available. The following is a preliminary list:
Sampling devices (e.g., soil coring device, water autosampler, air filter canister or
collection tube, wipes)
Preservatives and dechlorinating agents (if feasible, it is recommended that
preservatives and dechlorinating agents be added to sample containers prior to
sample collection)
Sample volumetric measuring devices and/or weighing devices
Sample containers and packaging materials, including ice
• PPE
Record keeping devices (e.g., logs, chain-of-custody [COC] forms, writing
instruments)
Site maps, Global Positioning System (GPS) recorders, etc.
Sample location markers
Shipping containers, shipping forms, and shipping labels
Waste containers
Materials for cleaning equipment and sample container exteriors
Samples should be collected using dedicated, sterile or sufficiently clean sampling
equipment to minimize interferences and cross-contamination. In some cases, pre-
packaged equipment and materials are available and can be used for efficiency. When
disposable equipment is not used, contaminated equipment must be appropriately cleaned
and decontaminated prior to reuse.
4.2	Field Data Documentation
All data collected in the field should be adequately documented. Documented
information should include (for example):
Names of field sampling personnel
Sample Collection Plan (SCP)
Sample location(s)
Date and time of sampling
Sample identification number
Sampling depth
Sample type
Sample collection medium
Physical and meteorological conditions
Expected contaminants
Expected radionuclides (if applicable)
Sample size (weight, volume), sample duration (air filters), air volume, etc.
Sample handling precautions
Radiological dose rate measurements of samples performed in the field should be
documented and transmitted to the laboratory along with the samples. Documentation
should include the background count rates; units; and the type, serial number and
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calibration date of the instrument used to obtain the dose rate. It is EPA Policy to use
Scribe4 wherever practical to collect, store and report sampling and analytical data.
4.3 Equipment Operation and Calibration
Sampling equipment should be verified to be in working order before it is deployed with
the sampling teams. Equipment should be operated in accordance with manufacturer's
operating instructions (unless otherwise specified in the SCP). Equipment also should
undergo routine maintenance according to manufacturer instructions, and be calibrated
and the calibration documented prior to use.
5.0 Preparation of Sample Containers
5.1	Sample Container Labels
Each sample container has a label that provides information uniquely identifying and
describing the sample. A single, unique label is affixed to each individual sample
container, sample information is added in waterproof ink, and the label is covered with
clear tape. Alternatively, a pre-prepared label that uniquely identifies the sample, such as
a bar code that tracks the sample information, can be affixed to the container. Sample
container labels include information regarding the date and time of sample collection;
sample collection site; date, time and type of sample preservation; sample identification
numbers; and the names and signatures of sample collectors.
5.2	Preparing Sample Containers for Packaging
Once samples have been collected and preserved as specified, the containers are prepared
for shipment to the analytical laboratory. Sample containers should be labeled, sealed,
and decontaminated and/or disinfected prior to packing into transport or shipping
containers. For samples containing radionuclides, each sample container should have
dose rate measurements taken and surface contamination surveys completed, and the
results recorded on a field sample tracking form (see EPA's Sample Collection
Procedures for Radiochemical Analvtes in Environmental Matrices. July 2012 and
Sample Collection Procedures for Radiochemical Analytes in Outdoor Building and
Infrastructure Materials. September 2016). Summary procedures for cleaning and sealing
sample containers are provided in the tables included in Attachments A, Bl, B2 and C.
General information regarding packing samples into transport containers outside the
contaminated area is provided as a footnote to each table.
5.3	General Sample Shipment Guidelines
Sample collectors are responsible for ensuring compliance with DOT and IATA
regulations regarding the transfer of hazardous substances and environmental samples.
Regulations 49 CFR 172 and 173 for DOT (organized by separate subparts as references
in Section 7.0), and the Dangerous Goods Regulations (DGR) for IATA, provide specific
details regarding proper marking, labeling, placarding, packaging and shipment of
hazardous materials, substances and wastes. Regulatory exceptions, such as those for
4 Scribe is a software tool developed by EPA's Environmental Response Team (ERT) to assist in managing
environmental data. For additional information regarding this tool see https://www.epa.gov/ert/environmental-
response-team-information-management (last accessed September 2017).
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shipping environmental samples, are also included. These regulations must be consulted
prior to preparation of or planning for sample shipment. Summary information regarding
appropriate labeling and packaging of sample transport containers is provided in the
sample collection information tables included in Attachments A, Bl, B2 and C.
5.4	Chain-of-Custody Forms
COC forms create a written record that can be used to trace the creation, possession, and
handling of the sample from the moment of its collection through analysis. A COC form
accompanies each sample or group of samples as custody of the sample(s) is transferred
from one custodian to another. One copy of the form is retained by the original sample
collector. If multiple laboratories are receiving a sample, individual COCs are provided to
each individual laboratory, each COC representing the contents of the sample shipment.
Sample collectors are responsible for the initial maintenance and completion of COC
forms. Although COC forms vary in style, format and detail, the forms should contain the
same minimal information required to identify the sample and to document custody.
EPA policy is to use Scribe (see Section 4.2) wherever practical to generate COC forms.
At a minimum, sample collectors are responsible for providing the following information
on the COC form:
General incident information (sample owners, contact information, site name)
Sample information (e.g., sample identification number, sample type [matrix],
whether grab or composite, number and type of sample containers, and date/time
sample was collected)
Date and time the sample was relinquished
Signature of persons transferring and receiving the samples
5.5	Custody Seals / Tamper-evident Bags
Custody seals are attached over the cap of each sample container to ensure the sample has
not been opened or tampered with after collection and packaging. A custody seal also can
be placed over the shipping or transport container, making it impossible to open the
container without ripping the seal. Typically, there is one seal per sample container and
two seals are placed on opposite sides of the shipping container. Custody seals contain
the signature of the person responsible for packing the container and the date sealed. The
seal must be sturdy to resist incidental contact but able to break when the cap or lid is
moved. Sample collectors should:
Sign and date the sample custody seal using waterproof ink, usually a 1- by 3-inch
white paper label with black lettering and an adhesive backing. The custody seal is
part of the COC process and is used to prevent or identify tampering with samples.
Place the custody seal across the container lid so that the seal will be broken if a
container is opened. If a cooler is used, ensure that the water drainage point is secure.
Alternatively, sample containers may be placed into a tamper-evident bag. Bags/seals
with a unique identifier must be associated with the person collecting the sample through
logbook entries, preservation of tear-off strips in the logbook, or similar means. When
using a tape-type tamper-evident seal, the initials of the person securing the container and
the date that it was secured must be recorded on the seal.
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6.0 Definitions
The following definitions are provided to describe the sample collection information listed in the
tables in Attachments A, Bl, B2 and C:
Analyte - The chemical compound, class of compound, radionuclide, radioactivity or
biotoxin that will be analyzed/measured in the sample. The analytes in this document are
intended to address the analytes listed in SAM 2017.
Selected Analytical Method - The analytical methods selected by technical work group
members to address the target analytes.
Tiers are provided for the chemistry methods cited in Attachment A and the biotoxin methods
cited in Attachment C, to indicate the level of method usability assigned for the specific
analyte and sample type.
-	For chemistry methods, these tiers are described in SAM 2017 as:
Tier I: Analyte/sample type is a target of the method(s). Data are available for all aspects
of method performance and quality control measures supporting its use for analysis of
environmental samples following a contamination incident. Evaluation and/or use of the
method(s) in multiple laboratories indicate that the method can be implemented with no
additional modifications for the analyte/sample type.
Tier II: (1) The analyte/sample type is a target of the method(s) and the method(s) has
been evaluated for the analyte/sample type by one or more laboratories, or (2) the
analyte/sample type is not a target of the method(s), but the method has been used by
laboratories to address the analyte/sample type. In either case, available data and/or
information indicate that modifications will likely be needed for use of the method(s) to
address the analyte/sample type.
Tier III: The analyte/sample type is not a target of the method(s), and/or no reliable data
supporting the method's fitness for its intended use are available. Data from other
analytes or sample types, however, suggest that the method(s), with significant
modification, may be applicable.
-	For biotoxin methods, these tiers are described in SAM 2017 as:
Tier I: The biotoxin and sample type are both targets of the method(s). Data are available
for all aspects of method performance and QC measures supporting its use without
modifications.
Tier II: The biotoxin is a target of the method, and the method has been evaluated by one
or more laboratories. The sample type may or may not be a target of the method, and
available data and/or information regarding sample preparation indicate that analyses of
similar sample types were successful. However, additional testing and/or modifications
may be needed.
Tier III: The sample type is not a target of the method, and no reliable data supporting
the method's fitness for its intended use are available. Data suggest, however, that the
method(s) may be applicable with significant modification.
Method types are provided for the radiochemistry methods cited in Attachment B1 and the
biotoxin methods cited in Attachment C, to indicate the intended analytical purpose.
-	For radiochemistry methods, these method types are described in SAM 2017 as:
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Qualitative: The identified method is intended to determine the presence of a
radionuclide. Although quantitative, these methods have been selected as qualitative
methods since they can be utilized with shorter counting times, at greater uncertainty,
when increased sample throughput and more rapid reporting of results are required.
Confirmatory: The identified method is for measurement of the activity from a
particular radionuclide per unit of mass, volume or area sampled.
- For biotoxin methods, these method types are described in SAM 2017 as:
Presumptive: Presumptive methods are generally more rapid than confirmatory methods,
and might be used during the initial stages of remediation to evaluate the extent of
contamination. Presumptive methods also might be used to identify samples that should
be analyzed using the more extensive confirmatory methods, and can be adapted for
large-scale sample analysis while maintaining an appropriate level of analytical certainty.
Confirmatory: Confirmatory methods are generally more time consuming and
expensive, and are intended to provide results with a higher level of certainty than those
provided by presumptive methods. These methods should be considered for use when
presumptive analysis indicates the presence of the biotoxin, a smaller subset of samples
requires analysis, or as required for a tiered approach to remediation.
Biological Activity: Methods that address biological activity tend to be time consuming
and expensive, and are intended to provide a high level of certainty in corroborating
results of presumptive and/or confirmatory assays. Depending on the goals of the
remediation phase, biological activity methods may also be needed to determine
bioactivity of a given biotoxin detected by a presumptive and/or confirmatory assay that
responds to inactivated or non-viable biotoxin.
Container - The type of container (e.g., bottle, bag) that must be used to hold the sample.
The container must be sufficient to maintain sample integrity and be composed of materials
that will remain inert when in contact with the sample.
• Holding Time - The maximum amount of time allowable from sample collection until
sample analysis or extraction. The actual holding time depends on the target analyte(s), the
analytical method that will be used, and the data requirements for the contamination incident.
Sample collectors should consult the analytical method and/or receiving laboratory for
confirmation.
Packaging - Sample container packaging requirements for shipment of samples to the
laboratory.
Preservation - Conditions and/or chemicals used to maintain the integrity of a sample. Some
examples of common preservatives include nitric acid, hydrochloric acid, sodium thiosulfate,
and temperatures in the range of 0-6 °C. The actual preservation requirements depend on the
target analyte(s), the analytical method that will be used, and the data requirements for the
contamination incident. Sample collectors should consult the analytical method and/or
receiving laboratory for confirmation.
Sample Size - The amount of sample that should be collected for a minimum of one analysis.
The actual volume and weight requirements depend on the target analyte(s), the analytical
method that will be used, and the data requirements for the contamination incident. Sample
collectors should consult the analytical method and/or receiving laboratory for confirmation.
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Sample Type - The type of material to be collected for analysis (e.g., air, drinking water,
non-drinking water, solid, soil and sediment, wipe, vegetation). In cases where the same
analytical method(s) is indicated for analysis of both drinking and non-drinking water sample
types, the sample types and corresponding sample collection information are combined into a
single row.
Sampling Device/Medium - The device or medium used to collect samples to be analyzed
for biotoxins.
Shipping Label - U.S. DOT shipping label requirements under 49 CFR 172 and 173.
7.0 Bibliography
Analytical methods listed in Attachments A, Bl, B2 and C can be accessed through the EPA
Homeland Security Research Program's Sampling and Analytical Methods website at
https://www.epa.gov/homeland-securitv-research/sam. In addition to these methods, the
following resources were used to prepare this document:
•	U.S. Centers for Disease Control and Prevention. December 2009. Biosafety in
Microbiological and Biomedical Laboratories, 5th Edition.
https://www.cdc.gov/biosafetv/publications/bmbl5/bmbl.pdf (accessed September 2017)
U.S. Department of Energy. March 1979. "Radiochemical Analytical Procedures for Analysis
of Environmental Samples." Environmental Monitoring and Support Laboratory. EMSL-LV-
0539-17. http://www.health.state.mn.us/divs/phl/accreditation/docs/refmethodepa053917.pdf
(accessed September 2017).
U.S. Department of Labor. 29 CFR 1910.120, "Hazardous Waste Operations and Emergency
Response," 29 CFR 1910.120, Appendix B, "General Description and Discussion of the
Levels of Protection and Protective Gear," and 1910.38 "Emergency Action Plans."
http://www.osha.gov/pls/oshaweb/owasrch.search form?p doc tvpe=STANDARDS&p toe
level=l&p kewalue=1910 (accessed September 2017).
U.S. Department of Labor. 29 CFR 1926.65. "Hazardous Waste Operations and Emergency
Response."
http://www.osha.gov/pls/oshaweb/owadisp.show document?p table=STANDARDS&p id=l
0651 (accessed September 2017).
U.S. Department of Transportation. 49 CFR 172.101. "Purpose and Use of Hazardous
Materials Table." http://www.ecfr.gov/cgi-bin/text-
idx?tpl=/ecfrbrowse/Title49/49cfrl72 main 02.tpl (accessed September 2017).
•	U.S. Department of Transportation. 49 CFR 172.301. "General Marking Requirements for
Non-bulk Packagings." http://www.ecfr.gov/cgi-bin/text-
idx?tpl=/ecfrbrowse/Title49/49cfrl72 main 02.tpl (accessed September 2017).
U.S. Department of Transportation. 49 CFR 173. "Shippers - General Requirements for
Shipments and Packaging." http://www.ecfr.gov/cgi-bin/text-
idx?tpl=/ecfrbrowse/Title49/49cfrl73 main 02.tpl (accessed September 2017).
- 49 CFR 173.132. "Class 6, Division 6.1-Definitions." http://www.ecfr.gov/cgi-bin/text-
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idx'.)SID=dfbaf3da73f9ccbc9c9bclacdS52()d97&mc=truc&nodc=sc49.2.173 1 132&rgn=
div8 (accessed September 2017).
-	49 CFR 173.150. "Exceptions for Class 3 (flammable and combustible liquids)."
http://www.ecfr.gov/cgi-bin/text-
idx?SID=dfbaf3da73f9cebe9c9bclaed8520d97&mc=true&node=se49.2.173 1150&rgn=
div8 (accessed September 2017).
-	49 CFR 173.153. "Exceptions for Division 6.1 (poisonous materials)."
http://www.ecfr.gov/cgi-bin/text-
idx?SID=dfbaf3da73f9cebe9c9bclaed8520d97&mc=true&node=se49.2.173 1153&rgn=
div8 (accessed September 2017).
-	49 CFR 173.154. "Exceptions for Class 8 (corrosive materials)."
http://www.ecfr.gov/cgi-bin/text-
idx?SID=dfbaf3da73f9cebe9c9bclaed8520d97&mc=true&node=se49.2.173 1154&rgn=
div8 (accessed September 2017).
-	49 CFR 173.24 and 173.24a. "General Requirements for Packaging" and "Packages and
Additional General Requirements for Non-bulk Packaging and Packages."
http://www.ecfr.gov/cgi-bin/text-
idx?SID=ee650c0b6877d30fc0c3bb9637a4b9c3&mc=true&node=se49.2.173 124&rgn=
div8 (accessed September 2017) and http://www.ecfr.gov/cgi-bin/text-
idx?SID=ee650c0b6877d30fc0c3bb9637a4b9c3&mc=true&node=se49.2.173 124a&rgn
=div8 (accessed September 2017).
-	49 CFR 173.403. "Definitions." http://www.ecfr.gov/cgi-bin/text-
idx?SID=dfbaf3da73f9cebe9c9bclaed8520d97&mc=true&node=se49.2.173 1403&rgn=
div8 (accessed September 2017).
-	49 CFR 173.453. "Fissile Materials - Exceptions." http://www.ecfr.gov/cgi-bin/text-
idx?SID=dfbaf3da73f9cebe9c9bclaed8520d97&mc=true&node=se49.2.173 1453&rgn=
div8 (accessed September 2017).
• U.S. Environmental Protection Agency. 40 CFR 61, Appendix B. "Standards of Performance
for New Stationary Sources, Performance Specifications - Test Methods."
http://www.ecfr.gov/cgi-bin/text-
idx?SID=4ac3 5 9277bd961623 7111031429 le70b&node=40:9.0.1.1.1.29.1.21,5&rgn=div9
(accessed September 2017).
U.S. Environmental Protection Agency. July 2012. "Sample Collection Procedures for
Radiochemical Analytes in Environmental Matrices." EPA/600/R-12/566, National
Homeland Security Research Center. Cincinnati, OH.
https://www.epa.gov/sites/production/files/2015-
07/documents/sample collection procedures for radiochemical analvtes.pdf (accessed
September 2017).
U.S. Environmental Protection Agency. September 2016. "Sample Collection Procedures for
Radiochemical Analytes in Outdoor Building and Infrastructure Materials." EPA/600/R-
16/128, National Homeland Security Research Center. Cincinnati, OH.
https://cfpub.epa.gov/si/si public record report.cfm?dirEntrvId=335065 (accessed
September 2017).
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U.S. Environmental Protection Agency. Office of Solid Waste and Emergency Response
(OSWER), SW-846 Methods on Line.
http://www.epa.gov/osw/hazard/testmethods/sw846/online/ (accessed September 2017).
U.S. Environmental Protection Agency. Office ofWater. February 2017. Sampling Guidance
for Unknown Contaminants in Drinking Water. EPA-817-R-08-003.
https://www.epa.gov/waterlabnetwork/sampling-guidance-unknown-contaminants-drinking-
water (accessed September 2017)
U.S. Office of Management and Budget. January 27, 2016. 81 Federal Register 4673:
Revisions of OMB Circular No. A-l 19 "Federal Participation in the Development and Use
of Voluntary Consensus Standards and in Conformity Assessment Activities."
https://www.gpo.gov/fdsys/pkg/FR-2016-01-27/pdf/2016-01606.pdf (accessed September
2017).
* U.S. Environmental Protection Agency. September 2017. Selected Analytical Methods for
Environmental Remediation and Recovery (SAM) 2017. EPA/600/R-17/356, National
Homeland Security Research Center. Cincinnati, OH. https://www.epa.gov/homeland-
security-research/sam (accessed September 2017).
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Attachment A
Sample Collection Information for the
Chemical Analytes and Methods
Listed in SAM 2017
[Note: The acronyms and abbreviations used in this attachment are
listed and defined in the beginning of the report.]

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Sample Collection Information Document - Attachment A
September 2017
Attachment A: Sample Collection Information for the Chemical Analytes and Methods Listed in SAM 2017
Note: In some cases, analytes are listed as not a concern in a particular sample type; in these cases, SAM work groups have determined that the analyte is not a concern due to a number of factors, including low likelihood of persistence, toxicity, mobility or solubility.
Analyte
Selected Analytical
Methods -SAM2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Acephate
J. Chromatogr. A (2007)
1154(1): 3-25
[Tier III]
Air
TBD
TBD
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

Chromatographia, 63(5/6):
223-237
[Tier II]
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

538
(EPA OW)
[Tier I]
Drinking Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Prior to collection, add 400
pL of ammonium acetate
concentrated stock and 80 [jL
of concentrated sodium
omadine stock to sample
container [Concentrations of
ammonium acetate and
sodium omadine in the sample
should be 1.5 g/L and 64
mg/L, respectively.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

J. Chromatogr. A (2007)
1154(1): 3-25
[Tier II]
Solid
250 mL
Wide-mouth glass or
fluoropolymer container with
fluoropolymer-lined lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

J. Chromatogr. A (2007)
1154(1): 3-25
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fluoropolymer-lined lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
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Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Acrylamide
PV2004
(OSHA)
[Tier I]
Air
120 L (flow rate = 1
L/min)
Filter/solid sorbent tube
(13mm quartz fiber filter)
•	OVS-7 tube (XAD-7 resin)
•	OVS-2 (XAD-2 resin)
•	OVS-SG (silica gel)
13 days
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Acrylamide, solid, 6.1,
Poison, UN2074

8316
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Acrylamide solution,
6.1, Poison, UN3426

Water Extraction /
8316 (EPA SW-846)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septa or lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the bottle with
non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Acrylamide, solid, 6.1,
Poison, UN2074

3570 / 8290A Appendix A /
8316
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Acrylamide, solid, 6.1,
Poison, UN2074
Acrylonitrile
PV2004
(OSHA)
[Tier III]
Air
120 L (flow rate = 1
L/min)
Filter/solid sorbent tube
(13mm quartz fiber filter)
•	OVS-7 tube (XAD-7 resin)
•	OVS-2 (XAD-2 resin)
•	OVS-SG (silica gel)
13 days
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Acrylonitrile, stabilized,
3, Flammable liquid,
6.1, Poison, UN1093

524.2/524.3/524.4
(EPA OW)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw cap VOA vial with
fluoro polymer-lined septum,
filled with no headspace
14 days with
acidification; 24 hours if
not acidified
Prior to collection of treated
water samples, add 25 mg
ascorbic acid to container for
removal of residual chlorine
Method 524.2:
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Acrylonitrile, stabilized,
3, Flammable liquid,
6.1, Poison, UN1093






• Adjust to pH < 2 with 1:1
HCI







Methods 524.3 and 524.4:








• Adjust to pH < 2 with maleic
acid
For all samples:








•	If residual chlorine is > 5
mg/L, add an additional 25 mg
ascorbic acid per each 5 mg/L
chlorine
•	Cool to < 6°C; keep from
freezing



5035A / 8260D
(EPA SW-846)
[Tier II]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen; 48
hours if not frozen
Cool to <6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below -20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Acrylonitrile, stabilized,
3, Flammable liquid,
6.1, Poison, UN1093
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Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131

3570 /8290A Appendix A/
8260D
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Acrylonitrile, stabilized,
3, Flammable liquid,
6.1, Poison, UN1093
Aldicarb (Temik)
5601
(NIOSH)
[Tier I]
Air
240 - 480 L
(flow rate = 0.1 - 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz fiber
filter, XAD-2 [270 mg/140 mg])
30 days if frozen; 7 days
at room temperature
(24°C)
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

D7645-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
14 days
•	Acidify to pH < 3.8 with
glacial acetic acid
•	Cool to < 6°C; keep from
freezing
•	Prior to collection of treated
water samples, add 10 mg
ascorbic acid to sample
container
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

531.2
(EPA OW)
[Tier I]
Drinking Water
40 ml.
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
28 days
•	Prior to collection, add 0.4 g
potassium dihydrogen citrate
and 3.2 - 4.8 mg sodium
thiosulfate to sample container
•	Agitate for 1 minute after
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

8318A
(EPA SW-846)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

3570 / 8290A Appendix A /
8318A
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
SAM Companion - Sample Collection Information Document
A1-3
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Aldicarb sulfone
5601
(NIOSH)
[Tier III]
Air
240 - 480 L
(flow rate = 0.1 - 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz filter,
XAD-2, [270 mg/140 mg])
30 days if frozen; 7 days
at room temperature
(24°C)
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
D7645-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Acidify to pH < 3.8 with
glacial acetic acid
•	Cool to < 6°C; keep from
freezing
•	Prior to collection of treated
water samples, add 10 mg
ascorbic acid to sample
container
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
531.2
(EPA OW)
[Tier I]
Drinking Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
28 days
•	Prior to collection, add 0.4 g
potassium dihydrogen citrate
and 3.2 - 4.8 mg sodium
thiosulfate to sample container
•	Agitate for 1 minute after
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992
8318A
(EPA SW-846)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
3570/8290A Appendix A/
8318A
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
SAM Companion - Sample Collection Information Document
A1-4
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -SAM2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Aldicarb sulfoxide
5601
(NIOSH)
[Tier III]
Air
240 - 480 L
(flow rate = 0.1 - 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz filter,
XAD-2, [270 mg/140 mg])
30 days if frozen; 7 days
at room temperature
(24°C)
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

D7645-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Acidify to pH < 3.8 with
glacial acetic acid
•	Cool to < 6°C; keep from
freezing
•	Prior to collection of treated
water samples, add 10 mg
ascorbic acid to sample
container
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

531.2
(EPA OW)
[Tier I]
Drinking Water
40 mL
Amber glass or fluoropolymer
container with fIuoropolymer-
lined septum or lid
28 days
•	Prior to sample collection,
add 0.4 g potassium
dihydrogen citrate and 3.2 -
4.8 mg sodium thiosulfate to
sample container
•	Agitate for 1 minute after
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

8318A
(EPA SW-846)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

3570 / 8290A Appendix A /
8318A
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Allyl alcohol
TO-15
(EPA ORD)
[Tier III]
Air
1-Lor 6-L canister
(depending on
suspected
concentration)'6'
Specially prepared stainless
steel canister
For subatmospheric pressure
sampling, the canister is
evacuated to 0.05 mm Hg; for
pressurized sampling, the
sample is collected using a
pump and flow control
arrangement to achieve a
typical 101 - 202 kPa (15-30
psig)
30 days
None
Ship canister in container provided by
laboratory
Standard carrier
shipping label AND Allyl
alcohol, 3, Flammable
liquid, 6.1, Poison,
UN1098

5030C / 8260D
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw cap VOA vial with
fluoro polymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap glass bottles with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND Allyl
alcohol, 3, Flammable
liquid, 6.1, Poison,
UN1098

5035A / 8260D
(EPA SW-846)
[Tier II]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen; 48
hours if not frozen
Cool to <6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below -20 °C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND Allyl
alcohol, 3, Flammable
liquid, 6.1, Poison,
UN1098

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-5
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
4-Aminopyridine
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8330B
(EPA SW-846)
[Tier III]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Aminopyridines, 6.1,
Poison, UN2671

8330B
(EPA SW-846)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
14 days
Cool to< 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Aminopyridines, 6.1,
Poison, UN2671

3570 / 8290A Appendix A /
8330B
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Aminopyridines, 6.1,
Poison, UN2671
Ammonia
6015
(NIOSH)
[Tier I]
Air
0.1 (at 50 ppm) - 96
L (flow rate = 0.1 -
0.2 L/min)
Solid sorbenttube (sulfuric
acid-treated silica gel)
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of sorbenttube clean using a
damp, then dry cloth. Cap tube with plastic
(not rubber) caps immediately after
sampling. Place tubes in double plastic
bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND (if
greater than 10%
ammonia by volume)
Ammonia solution, 8,
Corrosive, UN2672

4500-NH3B/
4500- NH3G
(SM)
[Tier I]
Non-Drinking
Water
500 mL
Polyethylene or glass
container
28 days with
acidification; analyze
immediately / as soon as
possible if not acidified
•	Cool to < 6°C or acidify to pH
< 2; keep from freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples (5) (Can
be added in the field or upon
receipt in the laboratory.)
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND (if
greater than 10%
ammonia by volume)
Ammonia solution, 8,
Corrosive, UN2672

350.1
(EPA OW)
[Tier I]
Drinking Water
500 mL
Polyethylene or glass
container
28 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples 151 (Can
be added in the field or upon
receipt in the laboratory.)
•	Adjust to pH < 2 with H2S04
•	Cool to< 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND (if
greater than 10%
ammonia by volume)
Ammonia solution, 8,
Corrosive, UN2672

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-6
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Ammonium metavanadate
(analyze as total vanadium)
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859

3015A /
6010D/6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately / as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859

9102 (NIOSH)/
6010D / 6020B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately / as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ammonium
metavanadate, 6.1,
Poison, UN2859
Arsenic trioxide
(analyze as total arsenic)
IO-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561

3050B / 3051 A/
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561

9102 (NIOSH)/
6010D / 6020B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic trioxide, 6.1,
Poison, UN1561
SAM Companion - Sample Collection Information Document
A1-7
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Arsenic, Total
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558

9102 (NIOSH)/
6010D / 6020B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsenic, 6.1, Poison,
UN1558
Arsine
(analyze as total arsenic in
non-air samples)
6001
(NIOSH)
[Tier I]
Air
0.1 L (at 0.05 ppm)
- 10 L (flow rate =
0.01 -0.2 L/min)
Solid sorbenttube (coconut
shell charcoal [100 mg/50 mg])
6 days
Cool to < 6°C
Wipe outside of sorbenttube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Arsine, 2.1, Flammable
gas, 2.3, Poisonous
gas, UN2188

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsine, 2.1, Flammable
gas, 2.3, Poisonous
gas, UN2188

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsine, 2.1, Flammable
gas, 2.3, Poisonous
gas, UN2188

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
40 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsine, 2.1, Flammable
gas, 2.3, Poisonous
gas, UN2188

9102 (NIOSH)/
6010D / 6020B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Arsine, 2.1, Flammable
gas, 2.3, Poisonous
gas, UN2188
SAM Companion - Sample Collection Information Document
A1-8
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Asbestos
10312:1995
(ISO)
[Tier I]
Air
500 - 5000 L
(flow rate = 1 -10
L/min)
Polycarbonate or cellulose
ester filter
Samples can be held
indefinitely
None
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Asbestos, 9, Class 9,
NA2212

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

D5755-03
(soft surfaces-micro vac)
(ASTM)
[Tier III]
Solid
200 mL
Wide-mouth, sealable glass or
fluoropolymer container
Samples can be held
indefinitely
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Asbestos, 9, Class 9,
NA2212

D6480-05
(ASTM)
[Tier I]
Wipes
1 particle-free
wipe/100 cm2
Wide-mouth, sealable glass or
fluoropolymer container
Samples can be held
indefinitely
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Asbestos, 9, Class 9,
NA2212
Boron trifluoride
ID216SG
(OSHA)
[Tier I]
Air
Up to 480 L
(flow rate = 1 L/min)
Midget glass bubbler
containing 10 mL of 0.1 M
NH4F; sample solution
transferred to 20 mL glass vial
with fluoropolymer-lined cap
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Boron trifluoride, 2.3,
Poisonous gas,
UN1008

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Brodifacoum
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

D7644-16
(ASTM)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Add 10 mg of dry ascorbic
acid to each 40 mL vial prior to
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid, toxic,
6.1, Poison, UN3023

3541 /3545A
(EPA SW-846)/
D7644-16
(ASTM)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septa or lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026

3570/8290A Appendix A
(EPA SW-846)/
D7644-16 (ASTM)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
SAM Companion - Sample Collection Information Document
A1-9
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Bromadiolone
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

D7644-16
(ASTM)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Add 10 mg of dry ascorbic
acid to each 40 mL vial prior to
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid, toxic,
6.1, Poison, UN3023

3541 /3545A
(EPA SW-846)/
D7644-16
(ASTM)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026

3570/8290A Appendix A
(EPA SW-846)/
D7644-16 (ASTM)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
[BZ] Quinuclidinyl benzilate
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
Analyze as soon as
possible until holding
time are available
Cool to < 6°C
Wrap cartridge in aluminum foil, and place
in a clean sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

J. Chromatogr. B (2008) 874:
42-50
[Tier III]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fiuoro polymer-
lined septum or lid
Analyze as soon as
possible until holding
time data are available
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

3541/3545A (EPA SW-846) /
J. Chromatogr. B (2008) 874:
42-50
[Tier III]
Solid
40 mL
Amber glass or fluoropolymer
container with fiuoro polymer-
lined septum or lid
Analyze as soon as
possible until holding
time data are available
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

3570/8290A Appendix A
(EPA SW-846) /
J. Chromatogr. B (2008) 874:
42-50
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
Analyze as soon as
possible until holding
time data are available
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-10
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Calcium arsenate
(analyze as total arsenic)
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Calcium arsenate, 6.1,
Poison, UN 1573

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Calcium arsenate, 6.1,
Poison, UN 1573

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Calcium arsenate, 6.1,
Poison, UN 1573

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Calcium arsenate, 6.1,
Poison, UN 1573

9102 (NIOSH)/
6010D / 6020B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Calcium arsenate, 6.1,
Poison, UN 1573
SAM Companion - Sample Collection Information Document
A1-11
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Carbofuran (Furadan)
5601
(NIOSH)
[Tier I]
Air
240 - 480 L
(flow rate = 0.1 - 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz fiber
filter, XAD-2 [270 mg/140 mg])
30 days if frozen; 7 days
at room temperature
(24°C)
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

D7645-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Acidify to pH < 3.8 with
glacial acetic acid
•	Cool to < 6°C; keep from
freezing
•	Prior to collection of treated
water samples, add 10 mg
ascorbic acid to sample
container
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

531.2
(EPA OW)
[Tier I]
Drinking Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
28 days
•	Prior to collection, add 0.4 g
potassium dihydrogen citrate
and 3.2 - 4.8 mg sodium
thiosulfate to sample container
•	Agitate for 1 minute after
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

8318A
(EPA SW-846)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

3570 / 8290A Appendix A /
8318A
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
SAM Companion - Sample Collection Information Document
A1-12
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Carbon disulfide
TO-15
(EPA ORD)
[Tier I]
Air
1-L or 6-L canister
(depending on
suspected
concentration)'6'
Specially prepared stainless
steel canister
For subatmospheric pressure
sampling, the canister is
evacuated to 0.05 mm Hg; for
pressurized sampling, the
sample is collected using a
pump and flow control
arrangement to achieve a
typical 101 - 202 kPa (15-30
psig)
30 days
None
Ship canister in container provided by
laboratory
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid, 6.1,
Poison, UN 1131

5030C / 8260D
(EPA SW-846)
[Tier I]
Non-Drinking
Water
40 ml.
Screw cap VOA vial with
fluoropolymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid, 6.1,
Poison, UN 1131

524.2/524.3/524.4
(EPA OW)
[Tier I]
Drinking Water
40 ml.
Amber glass or fluoropolymer
screw cap VOA vial with
fluoro polymer-lined septum,
filled with no headspace
14 days with
acidification; 24 hours if
not acidified
Prior to collection of treated
water samples, add 25 mg
ascorbic acid to container for
removal of residual chlorine
Method 524.2:
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid, 6.1,
Poison, UN 1131






• Adjust to pH < 2 with 1:1
HCI







Methods 524.3 and 524.4:








• Adjust to pH < 2 with maleic
acid








For all samoles:








•	If residual chlorine is > 5
mg/L, add an additional 25 mg
ascorbic acid per each 5 mg/L
chlorine
•	Cool to < 6°C; keep from
freezing



5035A / 8260D
(EPA SW-846)
[Tier I]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen; 48
hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Carbon disulfide, 3,
Flammable liquid, 6.1,
Poison, UN 1131

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-13
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Carfentanil
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type
3520C / 3535A
(EPA SW-846) /
J. Chromatogr. B (2014) 962:
52-58
[Tier III]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organic, n.o.s., 6.1,
toxic, UN2810
3541 /3545A
(EPA SW-846)
J. Chromatogr. B (2014) 962:
52-58
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organic, n.o.s., 6.1,
toxic, UN2810
3570 /8290A Appendix A
(EPA SW-846)/
J. Chromatogr. B (2014) 962:
52-58
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organic, n.o.s., 6.1,
toxic, UN2810
Chlorfenvinphos
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
3520C/3535A / 8270E
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Chlorine
Analyst (1999) 124(12): 1853-
1857/
4500-CI G (SM)
[Tier II]
Air
8 L (at 0.1 ppm)-
360 L (flow rate =
0.039 - 2.94 L/min)
Prefilter and filter
(fluoropolymer, 0.5 |jm and
silver membrane, 25 mm, 0.45
Mm)
30 days
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Chlorine, 2.3, 5.1,
Oxidizer, 8, Poison gas,
UN1017
4500-CI G
(SM)
[Tier I]
Drinking Water
Non-Drinking
Water
500 mL
Amber glass or fluoropolymer
container
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Avoid excessive agitation
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Chlorine, 2.3, 5.1,
Oxidizer, 8, Poison gas,
UN1017
NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-14
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
2-Chloroethanol
2513
(NIOSH)
[Tier I]
Air
2 (at 5 ppm) - 35 L
(flow rate = 0.01 -
0.2 L/min)
Solid sorbenttube (petroleum
charcoal [100 mg/50 mg])
14 days
Cool to < 6°C
Wipe outside of sorbenttube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Ethylene chlorohydrin,
3, Flammable liquid, 6.1
Poison, UN 1135

5030C / 8260D
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw cap VOA vial with
fluoropolymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples.15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Ethylene chlorohydrin,
3, Flammable liquid, 6.1
Poison, UN 1135

5035A / 8260D
(EPA SW-846)
[Tier II]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen; 48
hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Ethylene chlorohydrin,
3, Flammable liquid, 6.1
Poison, UN 1135

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Chloropicrin
PV2103
(OSHA)
[Tier I]
Air
5 L (flow rate = 0.2
L/min)
Solid sorbenttube (XAD-4
[100 mg/50 mg])
Until holding time data
are available, analyze
immediately/ as soon as
possible
•	Cool to < 6°C
•	Protect from light
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN 1580

551.1
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
60 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C; keep from
freezing
• Prior to collection of treated
water samples, add 6 mg
NH4CI to sample container
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN 1580

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN 1580

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool 2 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Chloropicrin, 6.1,
Poison, UN 1580
SAM Companion - Sample Collection Information Document
A1-15
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
3-Chloro-1,2-propanediol
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Glycerol alpha-
monochlorohydrin, 6.1,
Toxic substance,
UN2689

J. Chromatogr. A (2000) 866:
65-77
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
15 days
•	Adjust pH to 3 - 8 with
sodium sulfite or 1:1 HCI
•	Cool to <°6; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Glycerol alpha-
monochlorohydrin, 6.1,
Toxic substance,
UN2689

Eur. J. Lipid Sci. Technol.
(2011) 113:
345-355
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Glycerol alpha-
monochlorohydrin, 6.1,
Toxic substance,
UN2689

Eur. J. Lipid Sci. Technol.
(2011) 113:
345-355
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Glycerol alpha-
monochlorohydrin, 6.1,
Toxic substance,
UN2689
Chlorosarin
TO-17
(EPA ORD)
[Tier III]
Air
1 -4 L
(flow rate = 16-67
m L/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples(5)
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Solid
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-16
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Chlorosoman
TO-17
(EPA ORD)
[Tier III]
Air
1 -4 L
(flow rate = 16-67
mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
2-Chlorovinyl arsonic acid
(CVAOA) (degradation product
of Lewisite)
10-3.1
IO-3.4/IO-3.5
(EPA ORD)
[Tier I]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
E PA/60 O/R-15/258
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
VOA vial with fluoropolymer-
lined cap
14 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-15/258
(EPA NHSRC)
[Tier II]
Solid
40 ml.
VOA vial with fluoropolymer-
lined cap
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/60 O/R-15/258
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
VOA vial with fluoropolymer-
lined cap
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-17
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
2-Chlorovinylarsonous acid (2-
CVAA) (degradation product of
Lewisite)
10-3.1
IO-3.4/IO-3.5
(EPA ORD)
[Tier I]
Air
Up to 1700 m"
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-15/258
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
VOA vial with fluoropolymer-
lined cap
14 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-15/258
(EPA NHSRC)
[Tier II]
Solid
40 ml.
VOA vial with fluoropolymer-
lined cap
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-15/258
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
VOA vial with fluoropolymer-
lined cap
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-18
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Chlorpyrifos
TO-10A
(EPA ORD)
[Tier I]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
For treated water samoles:
Preservatives/dechlorinating
agents not required, but the
analyte is not affected by the
following, if added to address
other analytes:
•	1.6-2.0 mg NH4CI
For all other samoles:
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

525.2 / 525.3
(EPA OW)
[Tier I]
Drinking Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
Method 525.2:
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018














Method 525.3 Cto emotv
sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing



EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-19
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Chlorpyrifos oxon
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

540
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
250 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Prior to collection, add solid
ascorbic acid (dechlorinating
agent), Trizma® base
(buffering agent) and
chloroacetamide (antimicrobial
preservative) at concentrations
of 7.75 g/L, 2 g/L and 100
mg/L, respectively to an empty
sample container
•	After collecting the sample,
cap the container and agitate
until preservative is dissolved
•	Cool samples to <10°C; keep
from freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Crimidine
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
For treated water samoles:
Preservatives/dechlorinating
agents not required, but the
analyte is not affected by the
following, if added to address
other analytes:
•2.0 mg NH4CI
• Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Pesticide, n.o.s., liquid,
6.1, Poison, UN2902

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Pesticide, n.o.s., solid,
6.1, Poison, UN2588

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Pesticide, n.o.s., solid,
6.1, Poison, UN2588
SAM Companion - Sample Collection Information Document
A1-20
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Cyanide, Amenable to
chlorination
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3135.21
(EPA Regional Lab)
[Tier 1]
Drinking Water
Non-Drinking
Water
1 L
Glass or polyethylene
container
14 days
For treated water samoles:
•	Add 0.6 g of ascorbic acid for
each liter of sample volume
For all samoles:
•	Adjust to pH > 12 with NaOH
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanide solutions n.o.s,
6.1, Poison, UN1935

3135.21
(EPA Regional Lab)
[Tier 1]
Solid
250 mL
Wide-mouth glass or
polyethylene container
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanide inorganic solid
n.o.s, 6.1, Poison,
UN1588

3135.21
(EPA Regional Lab)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
polyethylene container
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanide inorganic solid
n.o.s, 6.1, Poison,
UN1588
Cyanide, Total
6010
(NIOSH)
[Tier I]
Air
2 (at 5 ppm) - 90 L
(flow rate = 0.05 -
0.2 L/min)
Solid sorbenttube (soda lime
[600 mg/200 mg])
14 days
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Cyanides, inorganic,
solid, n.o.s, 6.1, Poison,
UN1588

ISM 02.3 CN
(EPA CLP)
[Tier I]
Non-Drinking
Water
500 mL
Amber glass or polyethylene
container
14 days
For treated water samoles:
'• Add 0.6 g of ascorbic acid
for each liter of sample volume
For all samoles:
•	Adjust to pH > 12 with NaOH
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanide solutions n.o.s,
6.1, Poison, UN1935

335.4
(EPA OW)
[Tier I]
Drinking Water
125 mL
Amber glass or polyethylene
container
14 days
•	Add 0.6 g of ascorbic acid for
each liter of sample volume
•	Adjust to pH > 12 with NaOH
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanide solutions n.o.s,
6.1, Poison, UN1935

ISM 02.3 CN
(EPA CLP)
[Tier I]
Solid
40 mL
Wide-mouth amber glass or
polyethylene container
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanides, inorganic,
solid, n.o.s, 6.1, Poison,
UN1588

ISM 02.3 CN
(EPA CLP)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
polyethylene container
14 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanides, inorganic,
solid, n.o.s, 6.1, Poison,
UN1588
SAM Companion - Sample Collection Information Document
A1-21
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Cyanogen chloride
TO-15
(EPA ORD)
[Tier III]
Air
1-L or 6-L canister
(depending on
suspected
concentration)'6'
Specially prepared stainless
steel canister
For subatmospheric pressure
sampling, the canister is
evacuated to 0.05 mm Hg; for
pressurized sampling, the
sample is collected using a
pump and flow control
arrangement to achieve a
typical 101 - 202 kPa (15-30
psig)
Analyze immediately/ as
soon as possible
None
Ship canister in container provided by
laboratory
Standard carrier
shipping label AND
Cyanogen chloride, 2.3,
Poisonous gas,
UN1589

Encyclopedia of Anal. Chem.
(2006) DOI:
10.1002/9780470027
318.a0809
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
screw cap VOA vial with
fluoropolymer-lined septum,
filled with no headspace
14 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated wastewater samples151
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of container lean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Cyanogen chloride, 2.3,
Poisonous gas,
UN1589

Encyclopedia of Anal. Chem.
(2006) DOI:
10.1002/9780470027
318.a0809
[Tier II]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen; 48
hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Cyanogen chloride, 2.3,
Poisonous gas,
UN1589

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Cyclohexyl sarin (GF)
TO-17
(EPA ORD)
[Tier III]
Air
1 -4 L
(flow rate = 16-67
mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch O.D.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated wastewater samples151
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-22
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
1,2-Dichloroethane
(degradation product of HD)
TO-15
(EPA ORD)
[Tier I]
Air
1-L or 6-L canister
(depending on
suspected
concentration)'6'
Specially prepared stainless
steel canister
For subatmospheric pressure
sampling, the canister is
evacuated to 0.05 mm Hg; for
pressurized sampling, the
sample is collected using a
pump and flow control
arrangement to achieve a
typical 101 - 202 kPa (15-30
psig)
30 days
None
Ship canister in container provided by
laboratory
Standard carrier
shipping label AND
Ethylene dichloride, 3,
Flammable, 6.1,
Poison, UN 1184

5030C / 8260D
(EPA SW-846)
[Tier I]
Non-Drinking
Water
40 ml.
Screw cap VOA vial with
fluoropolymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Ethylene dichloride, 3,
Flammable, 6.1,
Poison, UN 1184

524.2/524.3/524.4
(EPA OW)
[Tier I]
Drinking Water
40 ml.
Amber glass or fluoropolymer
screw cap VOA vial with
fluoro polymer-lined septum,
filled with no headspace
14 days with
acidification; 24 hours if
not acidified
Prior to collection of treated
water samples, add 25 mg
ascorbic acid to container for
removal of residual chlorine
Method 524.2:
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethylene dichloride, 3,
Flammable, 6.1,
Poison, UN 1184






• Adjust to pH < 2 with 1:1
HCI







Methods 524.3 and 524.4:








• Adjust to pH < 2 with maleic
acid








For all samples:








•	If residual chlorine is > 5
mg/L, add an additional 25 mg
ascorbic acid per each 5 mg/L
chlorine
•	Cool to < 6°C; keep from
freezing



5035A / 8260D
(EPA SW-846)
[Tier I]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen; 48
hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Ethylene dichloride, 3,
Flammable, 6.1,
Poison, UN 1184

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-23
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Dichlorvos
TO-10A
(EPA ORD)
[Tier I]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
3535A / 8270E
(EPA SW-846)
[Tier I]
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
525.2 / 525.3
(EPA OW)
[Tier I]
Drinking Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
Method 525.2:
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Method 525.3 Cto emotv
sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Dicrotophos
TO-10A
(EPA ORD)
[Tier I]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
3535A / 8270E
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-24
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Diesel Range Organics
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3520C / 3535A / 8015D
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Diesel fuel, 3,
flammable, UN 1203

3541 / 3545A / 8015D
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Diesel fuel, 3,
flammable, UN 1203

3570 / 8290A Appendix A /
8015D
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Diesel fuel, 3,
flammable, UN 1203
Diisopropyl methyl-
phosphonate (DIMP)
(degradation product of GB)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label

D7597-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
24 hours
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label

538
(EPA OW)
[Tier I]
Drinking Water
40 mL
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
14 days
•	Prior to sample collection,
add 400 |jL of ammonium
acetate concentrated stock
and 80 |jL of concentrated
sodium omadine stock to
sample container. [If volumes
other than 40-mL are
collected, the concentration of
ammonium acetate and
sodium omadine in the sample
should be 1.5 g/L and 64
mg/L, respectively.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label

E2866-12
(ASTM)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label

EPA/600/R-13/224
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
SAM Companion - Sample Collection Information Document
A1-25
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Dimethylphosphoramidic acid
(degradation product of GA)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

D7597-16
(ASTM)
[Tier III]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
24 hours
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278

E2866-12
(ASTM)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

E PA/60 0/R-13/224
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Dimethylphosphite
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
Analyze immediately/ as
soon as possible
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
SAM Companion - Sample Collection Information Document
A1-26
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Diphacinone
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type
D7644-16
(ASTM)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Prior to collection of treated
water samples, add 10 mg of
dry ascorbic acid to sample
container for removal of
residual chlorine
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the -container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, liquid, toxic,
6.1, Poison, UN3023
3541 /3545A
(EPA SW-846) /
D7644-16 (ASTM)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
3570/8290A Appendix A
(EPA SW-846) /
D7644-16 (ASTM)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Coumarin derivative
pesticides, solid, toxic,
6.1, Poison, UN3026
Disulfoton
5600
(NIOSH)
[Tier I]
Air
12-240 L
(flow rate = 0.2 to 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz filter,
XAD-2, [270 mg/140 mg])
30 days if frozen; 10
days if not frozen
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
525.2 / 525.3
(EPA OW)
[Tier II]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
Analyze immediately/ as
soon as possible
Method 525.2:
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Method 525.3 Cto emotv
sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-27
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Disulfoton sulfone oxon
5600
(NIOSH)
[Tier III]
Air
12-240 L
(flow rate = 0.2 to 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz filter,
XAD-2, [270 mg/140 mg])
30 days if frozen; 10
days if not frozen
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

525.2/525.3
Drinking Water
1 L
Amber glass or fluoropolymer
Analyze immediately/ as
Method 525.2:
Wipe outside of container clean using a
Standard carrier

(EPA OW)
[Tier III]
Non-Drinking
Water

container with fluoropolymer-
lined septum or lid
soon as possible
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Method 525.3 Cto emptv
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018














sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing



EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-28
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Disulfoton sulfoxide
Disulfoton sulfoxide oxon
5600
(NIOSH)
[Tier III]
Air
12-240 L
(flow rate = 0.2 to 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz filter,
XAD-2, [270 mg/140 mg])
30 days if frozen;
10 days if not frozen
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
525.2 / 525.3
(EPA OW)
[Tier II]
Drinking Water
Non-Drinking
Water
1 L
Amber glass orfluoropolymer
container with fluoropolymer-
lined septum or lid
Analyze immediately/ as
soon as possible
Method 525.2:
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Method 525.3 Cto emotv
sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
1,4-Dithiane
(degradation product of HD)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type.
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
•	Cool to < 6°C; keep from
freezing
For treated water samoles:
Preservatives/dechlorinating
agents not required, but the
analyte is not affected by the
following, if added to address
other analytes:
•	Sodium sulfite (5)
•	1.6-2.0 mg NH4CI
For all other samoles:
•	Adjust pH < 2 with 1:1 HCI
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label
SAM Companion - Sample Collection Information Document
A1-29
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
EA2192 [S-2-
(diisopropylamino)ethyl
methylphosphonothioic acid]
(hydrolysis product of VX)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-15/097
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
3541 /3545A
(EPA SW-846) /
E PA/60 0/R-15/097
(EPA NHSRC)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
3570 /8290A Appendix A
(EPA SW-846) /
E PA/60 0/R-15/097
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
Ethyl methylphosphonic acid
(EMPA)
(degradation product of VX)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
D7597-16
(ASTM)
[Tier III - Drinking Water]
[Tier II - Non-Drinking Water]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fiuoro polymer-
lined septum or lid
24 hours
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278
E2866-12
(ASTM)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
E PA/60 0/R-13/224
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
SAM Companion - Sample Collection Information Document
A1-30
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Ethyldichloroarsine (ED)
TO-15
(EPA ORD)
[Tier III]
Air
1-L or 6-L canister
(depending on
suspected
concentration)'6'
Specially prepared stainless
steel canister
For subatmospheric pressure
sampling, the canister is
evacuated to 0.05 mm Hg; for
pressurized sampling, the
sample is collected using a
pump and flow control
arrangement to achieve a
typical 101 - 202 kPa (15-30
psig)
Analyze immediately/ as
soon as possible
None
Ship canister in container provided by
laboratory
Standard carrier
shipping label AND
Ethyldichloroarsine, 6.1,
Poison, UN 1892

3535A / 8270E
(EPA SW-846)
[Tier III]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethyldichloroarsine, 6.1,
Poison, UN 1892

3541 /3545A / 8270E
(EPA SW-846)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethyldichloroarsine, 6.1,
Poison, UN 1892

9102 (NIOSH)/
8270 E (EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethyldichloroarsine, 6.1,
Poison, UN 1892
Ethylene oxide
TO-15
(EPA ORD)
[Tier I]
Air
1-L or 6-L canister
(depending on
suspected
concentration)'6'
Specially prepared stainless
steel canister
For subatmospheric pressure
sampling, the canister is
evacuated to 0.05 mm Hg; for
pressurized sampling, the
sample is collected using a
pump and flow control
arrangement to achieve a
typical 101 - 202 kPa (15-30
psig)
30 days
None
Ship canister in container provided by
laboratory
Standard carrier
shipping label AND
Ethylene oxide
(concentration
dependent, refer to 40
CFR 172.101 for more
information)

5030C / 8260D
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw cap VOA vial with
fiuoro polymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Ethylene oxide
(concentration
dependent, refer to 40
CFR 172.101 for more
information)

5035A / 8260D
(EPA SW-846)
[Tier II]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen; 48
hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Ethylene oxide
(concentration
dependent, refer to 40
CFR 172.101 for more
information)

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-31
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Fenamiphos
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
Analyze immediately/ as
soon as possible.
Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
525.2 / 525.3
(EPA OW)
[Tier I]
Drinking Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
Analyze immediately/ as
soon as possible
Method 525.2:
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Method 525.3 Cto emotv
sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Fentanyl
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type
3520C / 3535A
(EPA SW-846) /
J. Chromatogr. A (2011)
1218: 1620- 1649
[Tier III]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
3541 /3545A
(EPA SW-846) /
J. Chromatogr. A (2011)
1218: 1620- 1649
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
3570 /8290A Appendix A
(EPA SW-846)
J. Chromatogr. A (2011)
1218: 1620- 1649
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label
SAM Companion - Sample Collection Information Document
A1-32
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Fluoride
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

300.1, Rev 1.0
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
40 ml.
Fluoropolymer, plastic or glass
container
28 days
Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Fluoroacetamide
J. Chromatogr. B (2008)
876(1): 103-108
[Tier III]
Air
TBD
TBD
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to <6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetamide, 6.1,
Poison, UN 1687

J. Chromatogr. B (2008)
876(1): 103-108
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Screw-cap VOA vial with
fluoropolymer-lined septum
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to <6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetamide, 6.1,
Poison, UN 1687

J. Chromatogr. B (2008)
876(1): 103-108
[Tier II]
Solid
40 ml.
Screw-cap VOA vial with
fluoro polymer-lined septum
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to <6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetamide, 6.1,
Poison, UN 1687

J. Chromatogr. B (2008)
876(1): 103-108
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Screw-cap VOA vial with
fluoro polymer-lined septum
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to <6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetamide, 6.1,
Poison, UN 1687
Fluoroacetic acid and
fluoroacetate salts (analyze as
fluoroacetate ion)
S301-1
(NIOSH)
J. Chromatogr. A (2007)
1139: 271-278
[Tier III]
Air
Up to 480 L (at 1.5-
2.0 L/min)
Cellulose ester membrane
filter/cleaned and rinsed
glass or plastic bottles
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642

J. Chromatogr. B (2010) 878:
1045-1050
[Tier III]
Drinking Water
Non-Drinking
Water
40 ml.
Screw-cap VOA vial with
fluoro polymer-lined septum
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to <6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642

J. Chromatogr. A (2007)
1139: 271-278
[Tier III]
Solid
250 mL
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642

J. Chromatogr. A (2007)
1139: 271-278
[ Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642
SAM Companion - Sample Collection Information Document
A1-33
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
2-Fluoroethanol
2513
(NIOSH)
[Tier III]
Air
2 (at 5 ppm) - 35 L
(flow rate = 0.01 -
0.2 L/min)
Solid sorbenttube (petroleum
charcoal [100 mg/50 mg])
14 days
Cool to < 6°C
Wipe outside of sorbenttube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label

5030C / 8260D
(SW-846)
[Tier III]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
screw cap VOA vial with
fluoropolymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film, and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label

5035A / 8260D
(EPA SW-846)
[Tier III]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen;
48 hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Fluorosilicic acid (analyze as
fluoride)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

300.1, Rev 1.0
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
40 ml.
Screw-cap VOA vial with
fluoro polymer-lined septum
28 days
Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-34
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Formaldehyde
2016
(NIOSH)
[Tier I]
Air
1 L (at 0.25 mg/m3)
- 15 L (at 2.5
mg/m3)
(flow rate = 0.03 -
1.5 L/min)
Dinitrophenylhydrazine
(DNPH)-coated silica gel
cartridge
30 days
Cool to < 6°C
Place end caps onto the cartridge and seal
sampler in an envelope. Place cartridge in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR 172.101 for more
information)

8315A
(EPA SW-846)
[Tier I]
Non-Drinking
Water
100 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
3 days
•	Preserve to pH 5.0 with 1:1
HCI or NaOH
•	Cool to < 6°C; keep from
freezing
•	Add 10 mg NH4CI to remove
residual chlorine from treated
water samples
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR 172.101 for more
information).

556.1
(EPA OW)
[Tier I]
Drinking Water
30 mL
Amber glass or fluoropolymer
container with polypropylene
screw cap equipped with
fluoropolymer-lined septum
7 days
•	Prior to collecting treated
water samples, add 15 mg
copper sulfate pentahydrate
and 15 mg NH4CI to sample
container
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR 172.101 for more
information)

8315A
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
3 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR 172.101 for more
information)

3570 / 8290A Appendix A /
8315A (EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
3 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Formaldehyde
(concentration
dependent, refer to 40
CFR 172.101 for more
information)
Gasoline Range Organics
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

5030C / 8015D
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw cap VOA vial with
fluoro polymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier AND
Gasoline identification
set, 2.3, Poison gas,
NA9035 shipping label

5035A / 8015C
(EPA SW-846)
[Tier I]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen;
48 hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below -20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier AND
Gasoline identification
set, 2.3, Poison gas,
NA9035

3570 /8290A Appendix A/
8015D (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier AND
Gasoline identification
set, 2.3, Poison gas,
NA9035
SAM Companion - Sample Collection Information Document
A1-35
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Hexahydro-1,3,5-trin itro-1,3,5-
triazine (RDX)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8330B
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
RDX, 1.1, Explosive,
UN0483®

8330B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
RDX, 1.1, Explosive,
UN0483™

3570 / 8290A Appendix A /
8330B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
RDX, 1.1, Explosive,
UN0483™
Hexamethylene
triperoxidediamine (HMTD)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8330B
(EPA SW-846) /
Analyst (2001) 126:1689-1693
[Tier II]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
HMTD, 1.1, Explosive181

8330B
(EPA SW-846) /
Analyst (2001) 126:1689-1693
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
HMTD, 1.1, Explosive181

3570 /8290A Appendix A
(EPA SW-846) /
Analyst (2001) 126:1689-1693
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
HMTD, 1.1 ,
Explosive'8'
Hydrogen bromide
7907
(NIOSH)
[Tier I]
Air
30-600 L (flow rate
= 2 L/min)
Two filters in series separated
with chemically inert spacer:
•	pre-filter: 37-mm diameter
quartz fiber
•	sampling filter: 37-mm
diameter quartz fiber
impregnated with 1 M 500-|jL
Na2C03
28 days
Cool to < 6°C
Wipe outside of filter clean using a damp,
then dry cloth. Place filter in double plastic
bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Hydrogen bromide, 2.3,
Poisonous gas,
UN1048

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-36
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Hydrogen chloride
7907
(NIOSH)
[Tier I]
Air
30-600 L (flow rate
= 2 L/min)
Two filters in series separated
with chemically inert spacer:
•	pre-filter: 37-mm diameter
quartz fiber
•	sampling filter: 37-mm
diameter quartz fiber
impregnated with 1 M 500-|jL
Na2C03
28 days
Cool to < 6°C
Wipe outside of filter clean using a damp,
then dry cloth. Place filter in double plastic
bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Hydrogen chloride, 2.3,
Poisonous gas,
UN1050
NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Hydrogen cyanide
6010
(NIOSH)
[Tier I]
Air
2 (at 5 ppm) - 90 L
(flow rate = 0.05 -
0.2 L/min)
Solid sorbenttube (soda lime
[600 mg/200 mg])
14 days
Cool to < e°c
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Hydrogen cyanide, 2.3,
Poisonous gas,
UN1956
NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Hydrogen fluoride
7906
(NIOSH)
[Tier I]
Air
30 - 600 L (flow rate
= 2 L/min)
Two filters in series separated
by a chemically inert spacer:
•	pre-filter: cellulose nitrate, 0.8
l_im pore size, 37-mm diameter
•	treated filter: cellulose nitrate
impregnated with 0.75 M
Na2C03, 0.8 |jm pore size, 37-
mm diameter
28 days
Cool to < 6°C
Wipe outside of filter clean using a damp,
then dry cloth. Place filter in double plastic
bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Hydrogen fluoride, 2.3,
Poisonous gas,
Corrosive, UN1052
NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Hydrogen sulfide
6013
(NIOSH)
[Tier I]
Air
1.2 (at 10 ppm)-40
L (flow rate = 0.1 -
1.5 L/min; 0.2 L/min
is recommended)
Filter/solid sorbent tube
(0.5 pm/coconut shell charcoal
[400 mg/200 mg])
21 days
Cool to < 6°C
Wipe filter and sorbenttube clean, using a
damp, then dry cloth. Place filter and
sorbenttube in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Hydrogen sulfide, 2.3,
Poisonous gas,
Corrosive, UN 1053
NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-37
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Isopropyl methylphosphonic
acid (IMPA) (degradation
product of GB)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

D7597-16
(ASTM)
[Tier III - Drinking Water]
[Tier II - Non-Drinking Water]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
24 hours
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278

E2866-12
(ASTM)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

EPA/600/R-13/224
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Kerosene
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3520C / 3535A / 8015D
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fiuoro polymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Kerosene, 3,
Flammable, UN 1223

3541 / 3545A / 8015D
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Kerosene, 3,
Flammable, UN 1223

3570 / 8290A Appendix A /
8015D
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Kerosene, 3,
Flammable, UN 1223
SAM Companion - Sample Collection Information Document
A1-38
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Lead arsenate
(analyze as total arsenic)
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617

200.7/200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617

9102 (NIOSH)
6010D / 6020B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Lead arsenate, 6.1,
Poison, UN1617
Lewisite 1 (L-1)
Lewisite 2 (L-2)
Lewisite 3 (L-3)
IO-3.1
IO-3.4/IO-3.5
(EPA ORD)
[Tier I]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

E PA/60 O/R-15/258
(EPA NHSRC)
[Tier II - Lewisite I]
[Tier III - Lewisites II and III]
Drinking Water
Non-Drinking
Water
40 mL
VOA vial with fluoropolymer-
lined cap
14 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-15/258
(EPA NHSRC)
[Tier II - Lewisite I]
[Tier III - Lewisites II and III]
Solid
40 mL
VOA vial with fluoropolymer-
lined cap
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labelinq.

EPA/60 O/R-15/258
(EPA NHSRC)
[Tier II - Lewisite I]
[Tier III - Lewisites II and III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
VOA vial with fluoropolymer-
lined cap
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labelina.
SAM Companion - Sample Collection Information Document
A1-39
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Lewisite oxide
(degradation product of
Lewisite)
(analyze as total arsenic)
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m"
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-15/258
(EPA NHSRC)
[Tier III]
Drinking Water
Non-Drinking
Water
40 mL
Screw-cap VOA vial with
fluoropolymer-lined septum
14 days
•	Acidify to pH < 2 with HN03
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-15/258
(EPA NHSRC)
[Tier III]
Solid
40 mL
Screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-15/258
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
Mercuric chloride (analyze as
total mercury)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

245.1
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
28 days
Acidify to pH < 2 with HN03(71
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercuric chloride, 6.1,
Poison, UN 1624

7473 / 7471B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
28 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercuric chloride, 6.1,
Poison, UN 1624

9102 (NIOSH)/
7473 / 7471B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
28 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercuric chloride, 6.1,
Poison, UN 1624
SAM Companion - Sample Collection Information Document
A1-40
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Mercury, Total
IO-5
(EPA ORD)
[Tier I]
Air
Typical flow rate is
30 L/minfor 12-24
hours
Trap apparatus:
•	Vapor phase: Sampling
pumps specially designed for
trace-level pollutant sampling;
vapor phase Hg collected
using two gold traps in series,
attached to a fluoropolymer
filter pack
•	Particle phase: Glass fiber
filter
7 days
[Particle-phase Hg filters
can be stored indefinitely
at negative
(-) 40°C.]
Cool to < 6°C
Wipe the outside of apparatus clean, cap
both ends. Place in double plastic bags
and wrap with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN2809

245.1
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
28 days
Acidify to pH < 2 with HN03(71
[If dissolved mercury is to be
determined, filter the sample
prior to acidification.]
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN2809

7473 / 7471B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
28 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN2809

9102 (NIOSH)/
7473 / 7471B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
28 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercury, 8, Corrosive,
UN2809
SAM Companion - Sample Collection Information Document
A1-41
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Methamidophos
J. Chromatogr. A (2007)
1154(1): 3-25
[Tier III]
Air
TBD
TBD
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

Chromatographia (2006)
63(5/6): 223-237
[Tier II]
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

538
(EPA OW)
[Tier I]
Drinking Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Prior to collection, add 400
pL of ammonium acetate
concentrated stock and 80 pL
of concentrated sodium
omadine stock to sample
container. [If volumes other
than 40-mL are collected, the
concentration of ammonium
acetate and sodium omadine
in the sample should be 1.5
g/L and 64 mg/L, respectively.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

J. Chromatogr. A (2007)
1154(1): 3-25
[Tier II]
Solid
250 mL
Fluoropolymer centrifuge tube
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

J. Chromatogr. A (2007)
1154(1): 3-25
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fluoropolymer-lined lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-42
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Methomyl
5601
(NIOSH)
[Tier I]
Air
12-480 L
(flow rate = 0.1 - 1
L/min)
Filter/solid sorbenttube:
•	13- mm quartz fiber filter
•	OVS-2 tube (XAD-2 resin
[270mg/140 mg])
30 days if frozen; 7 days
at room temperature
(24°C)
Cool to < 6°C
Wipe outside of sorbenttube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

D7645-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Acidify to pH < 3.8 with
glacial acetic acid
•	Cool to < 6°C; keep from
freezing
•	Prior to collection of treated
water samples, add 10 mg
ascorbic acid to sample
container
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

531.2
(EPA OW)
[Tier I]
Drinking Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
28 days
•	Prior to collection, add 0.4 g
potassium dihydrogen citrate
and 3.2 - 4.8 mg sodium
thiosulfate to sample container
•	Agitate for 1 minute after
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

8318A
(EPA SW-846)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

3570/8290A Appendix A/
8318A (EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
Methoxyethylmercuric acetate
(analyze as total mercury)
IO-5
(EPA ORD)
[Tier I]
Air
Typical flow rate of
30 L/min for 12-24
hours
Trap apparatus:
•	Vapor phase: Sampling
pumps specially designed for
trace-level pollutant sampling;
vapor phase Hg collected
using two gold traps in series,
attached to a fluoropolymer
filter pack
•	Particle phase: Glass fiber
filter
7 days
[Particle-phase Hg filters
can be stored indefinitely
at negative
(-) 40°C.]
Cool to < 6°C
Wipe the outside of trap apparatus clean,
cap both ends. Place in double plastic
bags and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Mercury compounds,
solid, n.o.s, 6.1, Poison,
UN2025

245.1
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
28 days
Acidify to pH < 2 with HN03(71
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercury compounds,
liquid, n.o.s, 6.1,
Poison, UN2024

7473 / 7471B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
28 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercury compounds,
solid, n.o.s, 6.1, Poison,
UN2025

9102 (NIOSH)/
7473 / 7471B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
28 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Mercury compounds,
solid, n.o.s, 6.1, Poison,
UN2025
SAM Companion - Sample Collection Information Document
A1-43
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Methyl acrylonitrile
PV2004
(OSHA)
[Tier III]
Air
120 L (flow rate = 1
L/min)
Filter/solid sorbenttube (13-
mm quartz fiber filter)
•	OVS-7 tube (XAD-7 resin)
•	OVS-2 (XAD-2 resin)
•	OVS-SG (silica gel)
13 days
Cool to < 6°C
Wipe outside of sorbenttube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Methyl acrylonitrile, 3.0,
Flammable Liquid, 6.1,
Poison, UN3079
524.2/524.3/524.4
(EPA OW)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
screw cap VOA vial with
fluoropolymer-lined septum,
filled with no headspace
14 days with
acidification; 24 hours if
not acidified
Prior to collection of treated
water samples, add 25 mg
ascorbic acid to container for
removal of residual chlorine
Method 524.2:
Wipe outside of container clean using a
damp, then dry cloth. Seal the-container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Methyl acrylonitrile, 3.0,
Flammable Liquid, 6.1,
Poison, UN3079
• Adjust to pH < 2 with 1:1
HCI
Methods 524.3 and 524.4:
• Adjust to pH < 2 with maleic
acid
For all samples:
•	If residual chlorine is > 5
mg/L, add an additional 25 mg
ascorbic acid per each 5 mg/L
chlorine
•	Cool to < 6°C; keep from
freezing
5035A / 8260D
(EPA SW-846)
[Tier II]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen;
48 hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C.
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Methyl acrylonitrile, 3.0,
Flammable Liquid, 6.1,
Poison, UN3079
3570 /8290A Appendix A/
8260D (EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Screw-cap VOA vial with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Methyl acrylonitrile, 3.0,
Flammable Liquid, 6.1,
Poison, UN3079
3-Methyl fentanyl
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type
3520C / 3535A
(EPA SW-846) /
J. Chromatogr. B (2014) 962:
52-58
[Tier III]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organic, n.o.s., liquid,
6.1, Poison, UN2810
3541 /3545A
(EPA SW-846) /
J. Chromatogr. B (2014) 962:
52-58
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organic, n.o.s., solid,
6.1, Poison, UN2811
3570 /8290A
(EPA SW-846) /
J. Chromatogr. B (2014) 962:
52-58
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organic, n.o.s., solid,
6.1, Poison, UN2811
SAM Companion - Sample Collection Information Document
A1-44
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Methyl fluoroacetate (analyze
as fluoroacetate ion)
S301-1
(NIOSH)
J. Chromatogr. A (2007)
1139: 271-278
[Tier III]
Air
Up to 480 L (flow
rate = 1.5-2.0
L/min)
Cellulose ester membrane
filter/cleaned and rinsed glass
or plastic bottles
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642

J. Chromatogr. B (2010) 878:
1045-1050
[Tier III]
Drinking Water
Non-Drinking
Water
40 mL
Screw-cap VOA vial with
fluoropolymer-lined septum
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to <6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642

J. Chromatogr. A (2007)
1139: 271-278
[Tier III]
Solid
250 mL
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642

J. Chromatogr. A (2007)
1139: 271-278
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Fluoroacetic acid, 6.1,
Poison, UN2642
Methyl hydrazine
3510
(NIOSH)
[Tier I]
Air
3 (at 0.2 ppm) - 20
L (flow rate = 0.5 to
1.5 L/min)
Bubbler (0.1 M HCI). Seal and
transfer the bubbler to
container for shipping.
5 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Methyl hydrazine, 6.1,
Poison, UN 1244

J. Chromatogr. (1993) 617:
157-162
[Tier II]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Methyl hydrazine, 6.1,
Poison, UN 1244

3541 /3545A
(EPA SW-846)
J. Chromatogr. (1993) 617:
157-162
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Methyl hydrazine, 6.1,
Poison, UN 1244

3570 /8290A Appendix A
(EPA SW-846) /
J. Chromatogr. (1993)617:
157-162
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Methyl hydrazine, 6.1,
Poison, UN 1244
Methyl isocyanate
OSHA54
[Tier I]
Air
15 L (flow rate =
0.05 L/min)
Solid sorbenttube (XAD-7
tubes coated with 0.03 mg of 1-
(2- py ri dy I) pi pe raz i ne
18 days
•	Cool to < 6°C
•	Protect from light
Wipe outside of tube clean using a damp,
then dry cloth. Cap ends of tube, wrap tube
with OSHA seal, and place in container.
Seal the container with non-reactive tape
or film. Wrap glass containers with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Methyl isocyanate, 6.1,
Poison, UN2480

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-45
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Methyl paraoxon
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3535A / 8270E
(EPA SW-846)
[Tier III]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Methyl parathion
TO-10A
(EPA ORD)
[Tier I]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3535A / 8270E
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Methylamine
OSHA40
[Tier I]
Air
10 L (flow rate = 0.2
L/min)
Solid sorbent tubes containing
XAD-7 resin coated with 10%
NBD chloride (7-chloro-4-
nitrobenzo-2-oxa-1,3-diazole)
by weight
15 days
Cool to < 6°C
Wipe outside of tube clean using a damp,
then dry cloth. Cap ends of tube, wrap tube
with OSHA seal, and place in container.
Seal the container with non-reactive tape
or film (e.g., fluoropolymer-based). Wrap
glass containers with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND,
Methylamine,
anhydrous, 2.1,
Flammable gas,
UN1061

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-46
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Methylphosphonic acid (MPA)
(degradation product of VX,
GB, &GD)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

D7597-16
(ASTM)
[Tier III - Drinking Water]
[Tier II - Non-Drinking Water]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
24 hours
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278

E2866-12
(ASTM)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

E PA/60 0/R-13/224
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
SAM Companion - Sample Collection Information Document
A1-47
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Mevinphos
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
3535A / 8270E
(EPA SW-846)
[Tier I]
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
525.2 / 525.3
(EPA OW)
[Tier I]
Drinking Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
Analyze immediately/ as
soon as possible
Method 525.2:
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Method 525.3 Cto emotv
sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-48
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Monocrotophos
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3535A / 8270E
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

3541 / 3545A / 8270E
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3570 / 8290 Appendix A/
8270 E (EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool 2 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Mustard, nitrogen (HN-1)
Mustard, nitrogen (HN-2)
Mustard, nitrogen (HN-3)
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16-67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-12/653
(EPA NHSRC)
[Tier II- HN-1 and HN-3]
[Tier III - HN-2]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fiuoro polymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

E PA/60 0/R-12/653
(EPA NHSRC)
[Tier II- HN-1 and HN-3]
[Tier III - HN-2]
Solid
40 mL
Amber glass or fluoropolymer
container with fiuoro polymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-12/653
(EPA NHSRC)
[Tier II- HN-1 and HN-3]
[Tier III - HN-2]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-49
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Mustard, sulfur (HD)
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16 - 67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
Analyze immediately/ as
soon as possible
Cool to < 6°C; keep from
freezing
• Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Solid
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
N-Ethyldiethanolamine (EDEA)
(degradation product of HN-1)
3509
(NIOSH)
[Tier III]
Air
0.5 - 300 L (flow
rate = 0.5-1 L/min)
Impinger (15 mL 2 mM
hexanesulfonic acid).
[Impinger contents are
transferred into VOA vial for
shipping.]
21 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film, and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491

D7599-16
(ASTM)
[Tier II Non-Drinking Water]
[Tier III Drinking Water]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491

3541 /3545A
(EPA SW-846) /
E PA/60 0/R-11/143
(EPA NHSRC/CDC)
[SAM Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491

EPA/600/R-11/123
(EPA NHSRC/CDC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
125 mL polypropylene
container with a polypropylene
screw cap
28 days
•	Cool to < 6°C
•	Protect from light
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
SAM Companion - Sample Collection Information Document
A1-50
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Nicotine compounds (analyze
as nicotine)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type
3535A / 8270E
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Nicotine compounds,
liquid, n.o.s, 6.1,
Poison, UN3144
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Nicotine compounds,
solid, n.o.s, 6.1, Poison,
UN1655
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Nicotine compounds,
solid, n.o.s, 6.1, Poison,
UN1655
N-Methyl
diethanolamine (MDEA)
(degradation product of HN-2)
3509
(NIOSH)
[Tier III]
Air
0.5 - 300 L (flow
rate = 0.5-1 L/min)
Impinger (15 mL 2 mM
hexanesulfonic acid)
[Impinger contents are
transferred into VOA vial for
shipping.]
21 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
D7599-16
(ASTM)
[Tier III - Drinking Water]
[Tier II - Non-Drinking Water]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
3541 /3545A
(EPA SW-846) /
EPA/600/R-11/123
(EPA NHSRC/CDC)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
EPA/600/R-11/123
(EPA NHSRC/CDC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
125 mL polypropylene
container with a polypropylene
screw cap
28 days
•	Cool to < 6°C
•	Protect from light
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
SAM Companion - Sample Collection Information Document
A1-51
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
1-Methylethyl ester
ethylphosphonofluoridic acid
(GE)
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16 - 67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
Octahydro-1,3,5,7-tetranitro-
1,3,5,7-tetrazocine (HMX)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8330B
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
HMX, 1.1, Explosive,
UN0391™

8330B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
HMX, 1.1 Explosive,
UN0391™

3570 / 8290 Appendix A/
8330B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
HMX, 1.1, Explosive,
UN0391™
SAM Companion - Sample Collection Information Document
A1-52
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Osmium tetraoxide
(analyze for total osmium)
10-3.1 / IO-3.4
(EPA ORD)
[Tier II]
Air
Up to 1700 m3
Filter (quartz, silica or cellulose
fiber)
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Osmium tetroxide, 6.1,
Poison, UN2471

3015A /
6010D / 6020B
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
125 mL
Glass container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
1% nh4oh 171
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Osmium tetroxide, 6.1,
Poison, UN2471

3051A /
6010D / 6020B
(EPA SW-846)
[Tier II]
Solid
250 mL
Wide-mouth fluoropolymer or
glass container with
fluoropolymer-lined lid
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Osmium tetroxide, 6.1,
Poison, UN2471

3051A /
6010D / 6020B
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer or
glass container with
fluoropolymer-lined lid
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Osmium tetroxide, 6.1,
Poison, UN2471
Oxamyl
5601
(NIOSH)
[Tier I]
Air
240 - 480 L
(flow rate = 0.1 - 1
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz fiber
filter, XAD-2 [270mg/140 mg])
30 days if frozen; 7 days
at room temperature
(24°C)
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

D7645-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Acidify to pH < 3.8 with
glacial acetic acid
•	Cool to < 6°C; keep from
freezing
•	Prior to collection of treated
water samples, add 10 mg
ascorbic acid to sample
container
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

531.2
(EPA OW)
[Tier I]
Drinking Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
28 days
•	Prior to collection, add 0.4 g
potassium dihydrogen citrate
and 3.2 - 4.8 mg sodium
thiosulfate to sample container
•	Agitate for 1 minute after
collection
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

8318A
(EPA SW-846)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

3570 / 8290 Appendix A /
8318A (EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
SAM Companion - Sample Collection Information Document
A1-53
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Paraoxon
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3520C/3535A / 8270E
(EPA SW-846)
[Tier III]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Paraquat
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

549.2
(EPA OW)
[Tier I]
Drinking Water
Non-Drinking
Water
250 mL
High density PVC or silanized
amber glass bottle fitted with
screw cap
7 days
•	Add 100 mg/L sodium
thiosulfate to remove residual
chlorine from treated water
samples
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Bipyridilium pesticides,
liquid, 6.1, Toxic,
UN3016

J. Chromatogr. A (2008) 1196-
1197:110-116
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Bipyridilium pesticides,
Solid, 6.1, Toxic,
UN2811

J. Chromatogr. A (2008) 1196-
1197:110-116
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Bipyridilium pesticides,
Solid, 6.1, Toxic,
UN2811
SAM Companion - Sample Collection Information Document
A1-54
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Parathion
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3520C / 3535A / 8270E
(SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Pentaerythritol tetranitrate
(PETN)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8330B
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
PETN, 1.1, Explosive,
UN0411|::|

8330B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
PETN, 1.1 Explosive,
UN0411|::|

3570 / 8290A Appendix A /
8330B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
PETN, 1.1 , Explosive,
UN0411|::|
SAM Companion - Sample Collection Information Document
A1-55
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Phencyclidine
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
•	Cool to < 6°C; keep from
freezing
For treated water samoles:
Preservatives/dechlorinating
agents not required, but the
analyte is not affected by the
following, if added to address
other analytes:
•	Sodium sulfite (5)
•	1.6-2.0 mg NH4CI
For all other samoles:
•	Can be adjusted to pH < 2
with 1:1 HCI, but this is not
required
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label

9106/9109
[NIOSH]
(Tier II)
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
30 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label
Phorate
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3535A / 8270E
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoro polymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-56
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Phorate sulfone
Phorate sulfone oxon
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

540
(EPA OW)
[Tier I - Phorate sulfone]
[Tier III - Phorate sulfone oxon]
Drinking Water
Non-Drinking
Water
250 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
28 days
Add the followina to samole
containers oriorto collection:
•	100 mg/L solid ascorbic acid
(for removal of residual
chlorine from treated water
samples)
•	2 g/L 2-chloroacetamide
(antimicrobial preservative)
•	7.75 g/L Trizma® base
(buffering agent)
After collectina the samole:
•	Cap the container and
agitate until preservative is
dissolved
•	Cool to <10°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fiuoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fiuoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-57
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Phorate sulfoxide
Phorate sulfoxide oxon
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

540
(EPA OW)
[Tier I - Phorate sulfoxide]
[Tier III - Phorate sulfoxide
oxon]
Drinking Water
Non-Drinking
Water
250 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
28 days
Add the followina to samole
containers oriorto collection:
•	100 mg/L solid ascorbic acid
(for removal of residual
chlorine from treated water
samples)
•	2 g/L 2-chloroacetamide
(antimicrobial preservative)
•	7.75 g/L Trizma® base
(buffering agent)
After collectina the samole:
•	Cap the container and
agitate until preservative is
dissolved
•	Cool to <10°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Phosgene
OSHA61
[Tier I]
Air
240 L (flow rate = 1
L/min)
Si lane-treated glass tubes [4-
mm i.d. * 6-mm o.d. * 11-cm
long, and packed with 150
mg/75 mg of pre treated XAD-2
adsorbent coated with 2-HMP
(2-[hydroxymethyl] piperidine)]
19 days
Cool to < 6°C
Wipe outside of tube clean using a damp,
then dry cloth. Cap ends of tube, wrap tube
with OSHA seal, and place in an air tight
container containing activated carbon. Seal
the container with non-reactive tape or film
(e.g., fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Phosgene, 2.3,
Poisonous gas,
UN1076

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-58
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Phosphamidon
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3520C / 3535A / 8270E
(EPA SW-846)
[Tier I]
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

525.3
(EPA OW)
[Tier I]
Drinking Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
Method 525.2:
•	Add sodium sulfite to empty
sample container to remove
residual chlorine from treated
water samples
•	Acidify to pH < 2 with 1:1
HCI(a
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018














Method 525.3 Cto emotv
sample container):
•	Add 4 mg ascorbic acid to
remove residual chlorine from
treated water samples
•	Add 14 mg trisodium EDTA,
and 400 mg potassium
dihydrogen citrate
•	Cool to < 6°C; keep from
freezing



EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
Phosphine
6002
(NIOSH)
[Tier I]
Air
1 (at 0.3 ppm) - 16
L (flow rate = 0.01 -
0.2 L/min)
Sorbent tube (Hg(CN)2 coated
silica gel [300 mg/150 mg])
7 days
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Phosphine, 2.3,
Poisonous gas,
UN2199

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-59
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Phosphorus trichloride
6402
(NIOSH)
[Tier I]
Air
11 (at 0.5 ppm)-
100 L (flow rate =
0.05-0.2 L/min)
Bubbler (15 mL H20)
Seal and transfer the bubbler
to container for shipping.
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C; keep from
freezing
Wipe outside of ontainer clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap each glass
container with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Phosphorus trichloride,
6.1, Poison, UN1809

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Solid
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Pinacolyl methyl phosphonic
acid (PMPA) (degradation
product of GD)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

D7597-16
(ASTM)
[Tier III - Drinking Water]
[Tier II - Non-Drinking Water]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
24 hours
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, liquid,
n.o.s, 6.1, Poison,
UN3278

E2866-12
(ASTM)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464

EPA/600/R-13/224
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
compound, toxic, solid,
n.o.s, 6.1, Poison,
UN3464
Propylene oxide
1612
(NIOSH)
[Tier I]
Air
0.5 (at 100 ppm) - 5
L (flow rate = 0.01 -
0.2 L/min)
Solid sorbent tube (coconut
shell charcoal [100 mg/50 mg])
6	weeks if frozen;
7	days if not frozen
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Propylene oxide, 3,
Flammable, UN1280.

5030C / 8260D
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw cap VOA vial with
fiuoro polymer-lined septum,
filled with no headspace
14 days with
acidification; 7 days if not
acidified
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Adjust to pH < 2 with 1:1 HCI
•	Cool to < 6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Propylene oxide, 3,
Flammable liquid,
UN1280

5035A / 8260D
(EPA SW-846)
[Tier II]
Solid
5-g coring device or
amber VOA vial
AND
1 - 2 oz. glass jar
(if needed to
determine percent
moisture)
Coring device (If coring device
is to be cleaned and reused,
samples can be transferred to
an amber VOA vial.)
AND glass jar (if needed to
determine percent moisture)
14 days if frozen;
48 hours if not frozen
Cool to < 6°C; freeze within 48
hours to < negative (-) 7°C
[Coring tools should not be
frozen below-20°C.]
Wipe outside of coring device or container
clean using a damp, then dry cloth. Place
the coring device or container in a zipper
bag. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Propylene oxide, 3,
Flammable, UN 1280

NA
Wipes
For the purposes of this document, this analyte is not considered to be a concern in this sample type
SAM Companion - Sample Collection Information Document
A1-60
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
R-33 (VR)
[methylphosphonothioic acid,
S-[2-(diethyIamino)ethyl]0-2-
m ethyl propyl ester]
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16 - 67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-12/653
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-12/653
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-12/653
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
Sarin (GB)
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16-67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-61
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Sodium arsenite (analyze as
total arsenic)
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Sodium arsenite, solid,
6.1, Poison, UN2027

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Sodium arsenite,
aqueous solutions, 6.1,
Poison, UN 1686

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
[If arsenic species are to be
determined, remove
unpreserved aliquot prior to
sample preservation.]
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Sodium arsenite,
aqueous solutions, 6.1,
Poison, UN 1686

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Sodium arsenite, solid,
6.1, Poison, UN2027

9102 (NIOSH)/
6010D / 6020B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Sodium arsenite, solid,
6.1, Poison, UN2027
Sodium azide (analyze as azide
ion)
ID-211
(OSHA)
[Tier I]
Air
5 L (flow rate = 1
L/min)
Filter / Sorbent tube (PVC or
quartz filter with silica coated
sorbent [150 mg/75 mg])
10 days
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN 1687

J. of Forensic Sciences
(1998) 43(1): 200-202/
300.1, Rev 1.0 (EPA OW)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Screw-cap VOA vial with
fluoropolymer-lined septum
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to <6°C; keep from
freezing
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN 1687

J. of Forensic Sciences
(1998) 43(1): 200-202/
300.1, Rev 1.0 (EPA OW)
[Tier II]
Solid
250 mL
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN 1687

ID-211
(OSHA)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
10 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Sodium azide, 6.1,
Poison, UN 1687
SAM Companion - Sample Collection Information Document
A1-62
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Soman (GD)
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16 - 67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/115
(EPA NHSRC)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
Strychnine
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8270E
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film. Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Strychnine, 6.1, Poison,
UN1692

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Strychnine, 6.1, Poison,
UN1692

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Strychnine, 6.1, Poison,
UN1692
SAM Companion - Sample Collection Information Document
A1-63
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
Tabun (GA)
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16 - 67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-12/653
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-12/653
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-12/653
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap containers with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
Tetraethyl pyrophosphate
(TEPP)
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

3511 / 8270E
(EPA SW-846)
[Tier II]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, liquid, 6.1,
Poison, UN3018

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 ml.
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool samples to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fiuoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool samples to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fiuoropolymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Organophosphorus
pesticides, solid, 6.1,
Poison, UN2783
SAM Companion - Sample Collection Information Document
A1-64
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Tetramethylenedisulfo-
tetramine (TETS)
TO-10A
(EPA ORD)
[Tier II]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Pesticides, solid, toxic,
n.o.s, 6.1, Poison,
UN2588

EPA/600/R-16/114
(EPA NHSRC)
[Tier I]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
• Cool to < 6°C; keep from
freezing
For treated water samoles:
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
Standard carrier
shipping label AND
Pesticides, liquid, toxic,
n.o.s, 6.1, Poison,





Preservatives/dechlorinating
agents not required, but the
analyte is not affected by the
following, if added to address
other analytes:
•	Sodium sulfite (5)
•	1.6-2.0 mg NH4CI
For all other samples:
samples as described in Footnote (4).
UN2902






• Can be adjusted to pH < 2
with 1:1 HCI, but this is not
required



EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Pesticides, solid, toxic,
n.o.s, 6.1, Poison,
UN2588

EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Pesticides, solid, toxic,
n.o.s, 6.1, Poison,
UN2588
Thallium sulfate (analyze as
total thallium)
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[ Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707

9102 (NIOSH)/
6010D / 6020B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Thallium compounds
n.o.s, 6.1, Poison,
UN1707
SAM Companion - Sample Collection Information Document
A1-65
September 2017

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Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Thiodiglycol (TDG)
(degradation product of HD)
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Aviation regulated solid,
n.o.s, UN3335

D7598-16
(ASTM)
[Tier III - Drinking Water]
[Tier II - Non-Drinking Water]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
24 hours
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Aviation regulated
liquid, n.o.s, UN3334

E2787-11
(ASTM)
[Tier II]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fluoropolymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Aviation regulated solid,
n.o.s, UN3335

E2838-11
(ASTM)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fluoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Aviation regulated solid,
n.o.s, UN3335
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Thiofanox
5601
(NIOSH)
[Tier III]
Air
240 - 480 L
(flow rate = 0.1-1.0
L/min)
Filter/solid sorbent tube (OVS-
2 tube: 13 mm quartz filter,
XAD-2, [270 mg/140 mg])
30 days if frozen; 7 days
at room temperature
(24°C)
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap both ends of the
tube with plastic caps. Place tube in double
plastic bags and wrap with bubble wrap.
Pack samples as described in Footnote
(4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

D7645-16
(ASTM)
[Tier II]
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
14 days
•	Acidify to pH < 3.8 with
glacial acetic acid
•	Cool to < 6°C; keep from
freezing
•	Prior to collection of treated
water samples, add 10 mg
ascorbic acid to sample
container
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

538
(EPA OW)
[Tier I]
Drinking Water
40 mL
Amber glass or fluoropolymer
container with fIuoropolymer-
lined septum or lid
14 days
•	Prior to collection, add 400
pL of ammonium acetate
concentrated stock and 80 [jL
of concentrated sodium
omadine stock to sample
container. [If volumes other
than 40-mL are collected, the
concentration of ammonium
acetate and sodium omadine
in the sample should be 1.5
g/L and 64 mg/L, respectively.]
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
liquid, toxic, 6.1,
Poison, UN2992

3541 / 3545A (EPA SW-846) /
D7645-16 (ASTM)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
Until holding time data
are available, analyze
immediately/ as soon as
possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757

3570/8290A Appendix A
(EPA SW-846) /
D7645-16 (ASTM)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Carbamate pesticides,
solid, toxic, 6.1,
UN2757
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
1,4-Thioxane
(degradation product of HD)
NA
Air
Not of concern in this sample type
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoropolymer-lined septum
14 days
• Cool to < 6°C; keep from
freezing
For treated water samoles:
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Flammable Liquids,
n.o.s, 3, Flammable,
UN1993
• Add sodium sulfite to remove
residual chlorine151 OR
•Add 1.6-2.0 mg NH4CI
For all other samples:
• Adjust to pH < 2 with 1:1 HCI
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Flammable Solid, n.o.s,
3, Flammable, UN1325
EPA/600/R-16/114
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
screw-cap VOA vial with
fluoro polymer-lined septum
14 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film (e.g., fluoro polymer-
based), and wrap with bubble wrap. Pack
samples as described in Footnote (4).
Standard carrier
shipping label AND
Flammable Solid, n.o.s,
3, Flammable, UN1325
Titanium tetrachloride (analyze
as total titanium)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type
3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Titanium tetrachloride,
8, Corrosive, UN1838
3051A /
6010D / 6020B
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer or
glass container with
fluoropolymer-lined lid
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Titanium tetrachloride,
8, Corrosive, UN1838
Triethanolamine (TEA)
(degradation product of HN-3)
3509
(NIOSH)
[Tier II]
Air
0.5 - 300 L (flow
rate = 0.5-1 L/min)
Impinger (15 mL 2 mM
hexanesulfonic acid)
[Impinger contents are
transferred into VOA vial for
21 days
Cool to < 6°C
Wipe outside of vial clean using a damp,
then dry cloth. Seal the vial with non-
reactive tape or film, and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
D7599-16
(ASTM)
[Tier III - Drinking Water]
[Tier II - Non-Drinking Water]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
3541 /3545A
(EPA SW-846) /
EPA/600/R-11/123
(EPA NHSRC/CDC)
[Tier III]
Solid
250 mL
Wide-mouth amber glass,
fluoropolymer or polypropylene
container
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
EPA/600/R-11/123
(EPA NHSRC/CDC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass,
fluoropolymer or polypropylene
container
28 days
•	Cool to < 6°C
•	Protect from light
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Ethanolamine solutions,
8, Corrosive, UN2491
SAM Companion - Sample Collection Information Document
A1-68
September 2017

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Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size<1)
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label131
Trimethyl phosphite
TO-10A
(EPA ORD)
[Tier III]
Air
240 - 7200 L
(flow rate =1-5
L/min)
Sorbent cartridge containing
PUF or PUF in combination
with other solid sorbent
7 days
Cool to < 6°C
Remove PUF cartridge from sampler, wrap
with aluminum foil used to store cartridge,
and place in a sealed container. Place
container in double plastic bags and wrap
with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Trimethyl phosphite, 3,
Flammable, UN2329

NA
Non-Drinking
Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

NA
Drinking Water
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3541 / 3545A / 8270E
(EPA SW-846)
[Tier III]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trimethyl phosphite, 3,
Flammable, UN2329

3570 / 8290 Appendix A /
8270 E (EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trimethyl phosphite, 3,
Flammable, UN2329
1,3,5-Trinitrobenzene
(1,3,5-TNB)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8330B
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fiuoro polymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzeneand
trinitrotoluene mixtures,
1.1, Explosive,
UN0388™

8330B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzeneand
trinitrotoluene mixtures,
1.1, Explosive,
UN0388™

3570 / 8290A Appendix A /
8330B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzeneand
trinitrotoluene mixtures,
1.1, Explosive,
UN0388|::|
SAM Companion - Sample Collection Information Document
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September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container*2'
Holding Time
Preservation
Packaging Requirements
Shipping Label131
2,4,6-Trinitrotoluene
(2,4,6-TNT)
NA
Air
For the purposes of this document, this analyte is not considered to be a concern in this sample type

3535A / 8330B
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
1 L
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
•	Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzeneand
trinitrotoluene mixtures,
1.1, Explosive,
UN0388™

8330B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
14 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzeneand
trinitrotoluene mixtures,
1.1, Explosive,
UN0388™

3570 /8290A Appendix A/
8330B
(EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Trinitrobenzeneand
trinitrotoluene mixtures,
1.1, Explosive,
UN0388|::|
Vanadium pentoxide (analyze
as total vanadium)
10-3.1 /
10-3.4/ 10-3.5
(EPA ORD)
[Tier 1]
Air
Up to 1700 m3
Filter (quartz, silica, or
cellulose fiber)
6 months
Cool to < 6°C
Place filter in protective covering. Place
protected filter in double plastic bags, and
wrap with bubble wrap. Pack samples as
described in Footnote (4).
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862

3015A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Non-Drinking
Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862

200.7 / 200.8
(EPA OW)
[Tier I]
Drinking Water
125 mL
Fluoropolymer, plastic or glass
container
6 months with
acidification. Samples
must be acidified within
14 days of collection.
•	Acidify to pH < 2 with HN03(7)
•	Acidified samples can be
cooled to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862

3050B / 3051A /
6010D / 6020B
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862

9102 (NIOSH)/
6010D / 6020B (EPA SW-846)
[Tier I]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth fluoropolymer,
plastic or glass container
Analyze immediately/ as
soon as possible
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fluoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Vanadium pentoxide,
6.1, Poison, UN2862
SAM Companion - Sample Collection Information Document
A1-70
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
VE [Phosphonothioic acid,
ethyl-, S~(2-(diethylamino)ethyl)
0-ethyl ester]
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16 - 67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
SAM Companion - Sample Collection Information Document
A1-71
September 2017

-------
Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
VG [Phosphonothioic acid, S-
(2-(diethylamino)ethyl) 0,0-
diethyl ester]
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16 - 67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
VM [Phosphonothioic acid,
methyl-,S-(2-
(diethylamino)ethyl) O-ethyl
ester]
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16-67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Drinking Water
Non-Drinking
Water
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Solid
40 ml.
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
EPA/600/R-16/116
(EPA NHSRC)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
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Sample Collection Information Document - Attachment A
September 2017
Analyte
Selected Analytical
Methods -sAM 2017*
Sample Type
Sample Size'11
Sample Container'21
Holding Time
Preservation
Packaging Requirements
Shipping Label'31
VX [0-ethyl-S-(2-
diisopropylaminoethyl) methyl-
phosphonothiolate]
TO-17
(EPA ORD)
[Tier III]
Air
1 - 4 L (flow rate =
16-67 mL/min)
Stainless steel, 3.5-inch long
tubes with a 6-cm sorbent bed
and 1/4-inch o.d.
7 days
Cool to < 6°C
Wrap tube in aluminum foil, and place in a
clean sealed container. Place container in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/116
(EPA NHSRC)
[Tier I]
Drinking Water
Non-Drinking
Water
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
•	Cool to < 6°C; keep from
freezing
•	Add sodium thiosulfate to
remove residual chlorine from
treated water samples15'
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/116
(EPA NHSRC)
[Tier II]
Solid
40 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.

EPA/600/R-16/116
(EPA NHSRC)
[Tier II]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid
7 days
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Wrap container with
bubble wrap. Place in gallon plastic
(polypropylene or polyethylene) bag with
zipper lock and durability to resist
punctures, then into metal can before
placing in cooler.
Consult laboratory
and/or shipping vendor
on specifics regarding
shipping label. Wipe
outer surface of
package with a bleach
wipe, taking care not to
obscure labeling.
White phosphorus
7905
(NIOSH)
[Tier I]
Air
5 L (at 0.1 mg/m3) -
100 L (flow rate =
0.01 -0.2 L/min)
Solid sorbent tube (Tenax GC
[100 mg/50 mg])
7 days
Cool to < 6°C
Wipe outside of sorbent tube clean using a
damp, then dry cloth. Cap tubes with
plastic (not rubber) caps. Place tubes in
double plastic bags and wrap with bubble
wrap. Pack samples as described in
Footnote (4).
Standard carrier
shipping label AND
Phosphorus, white (dry
or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381

7580
(EPA SW-846)
[Tier I]
Drinking Water
Non-Drinking
Water
500 mL
Amber glass or fluoropolymer
container with fluoropolymer-
lined septum or lid; fill to
overflowing to eliminate
headspace
5 days
Cool to < 6°C; keep from
freezing
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Phosphorus, white (dry
or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381

7580
(EPA SW-846)
[Tier I]
Solid
250 mL
Wide-mouth amber glass or
fluoropolymer container with
fiuoropolymer-lined septum or
lid
Samples can be held
indefinitely if sealed
tightly to eliminate
moisture loss
Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Phosphorus, white (dry
or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381

3570/8290A Appendix A/
7580
(EPA SW-846)
[Tier III]
Wipes
1 wipe/100 cm2 or
1 wipe/ft2
Wide-mouth amber glass or
fluoropolymer container with
fiuoro polymer-lined septum or
lid
Samples can be held
indefinitely if sealed
tightly to eliminate
moisture loss.
• Cool to < 6°C
Wipe outside of container clean using a
damp, then dry cloth. Seal the container
with non-reactive tape or film (e.g.,
fiuoropolymer-based). Wrap glass
containers with bubble wrap. Pack samples
as described in Footnote (4).
Standard carrier
shipping label AND
Phosphorus, white (dry
or wetted), 4.2,
Spontaneously
combustible, 6.1,
Poison, UN1381
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Sample Collection Information Document - Attachment A
September 2017
Footnotes:
NA Not applicable
*	EPA's SAM lists the analytical methods that have been selected by multi-agency technical work groups for use by laboratories that are tasked with sample analysis following a contamination incident. The
method tiers listed reflect the extent of method validation and indicate the level of method usability for the specific analyte and sample type. These tiers are defined in the Chemical Methods Query on the
Selected Analytical Methods for Environmental Remediation and Recovery website:
https://www.epa.gov/homeland-securitv-research/sam-chemical-methods-auerv.
(1)	Sample sizes are based on the minimum amount needed for analysis of a single sample. Additional sample amounts may be requested or needed for laboratory quality control analyses (e.g., duplicates,
matrix spikes) or for measurement of low analyte concentrations. It is also recommended that additional sample(s) be collected in case of the need for reanalysis due to sample spillage or unforeseen
analytical difficulties. Where possible, sample sizes are based on specifications included in the selected analytical methods.
~	Wipe areas may need to be adjusted based on anticipated analyte concentration. Wipe sample areas are based on U.S. Office of Research and Development, "A Literature Review of Wipe Sampling
Methods for Chemical Warfare Agents and Toxic Industrial Chemicals," EPA/600/R-07/004 January 2007.
~	Solid samples should be collected into containers without packing.
(2)	Use of "certified clean" containers is preferred. Otherwise, use glassware cleaning instructions found in Chapter 3 of SW-846. Rinse with detergent, followed by tap water, 1:1 nitric acid:tap water, 1:1
hydrochloric acid:tap water, and reagent water. Prior to use, wash vials and septa with detergent and rinse with tap and distilled water. Allow the vials and septa to air dry at room temperature, place in a 105°C
oven for 1 hr, then remove and allow to cool in an area known to be free of organics.
(3)	Environmental samples are shipped as nonhazardous cargo if they do not exhibit one of the following U.S. DOT hazard classes: explosive, corrosive, flammable, or poisonous. Only a standard shipping
carrier's label is needed in these cases. If any sample is listed under one of these classes, DOT labeling is required. The DOT label must indicate, PSN (49 CFR 172.301), the UN Number (49 CFR 172.301),
appropriate hazard class and descriptor (49 CFR 172.101), and "Limited Quantity" when a quantity exception is used (49 CFR 172.101). When the quantity limit for a given substance is exceeded, the phrase
"Limited Quantity" should be excluded from the label. Note that there are no "exceptions" for substances belonging to DOT Division 1.1, Division 2.1, Division 2.3 or Division 4.2. Exception quantities include:
~	Exception for Class 3, flammable and combustible liquids: Ensure total net quantity of Class 3 substances does not exceed 1 L (0.3 gal) (49 CFR 173.150)
~	Exception for Division 5.1, oxidizers and Class 9, miscellaneous hazardous materials (see 49 CFR 173.127 for packing group definitions), Packing group II: Ensure the total net quantity does not
exceed 1.0 L (0.3 gallons) of liquid or 1.0 kg (2.2 lbs) of solid (49 CFR 173.152); Packing group III: Ensure the total net quantity does not exceed 5 L (1.3 gallons) of liquid or 5.0 kg (11 lbs) of solid
(49 CFR 173.152)
~	Exception for Division 6.1, poisonous liquids: Ensure the total net quantity of Class 6.1 liquids does not exceed 4 L (1 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.153)
~	Exception for Class 8, corrosive materials: Ensure total net quantity of Class 8 materials does not exceed 5 L (1.3 gal) of liquid or 5 kg (11 lbs) of solid (49 CFR 173.154)
~	Shipment of samples containing reactive levels (>12%) of energetic material residues using domestic carriers is prohibited. If samples are known or suspected to contain >12% of energetic material
residues, ship and label according to DOT requirements for secondary explosive materials.
(4)	Pack sample transport containers outside the contaminated area. Samples must be packed in a manner that protects the integrity of the samples and provides temperature conditions required for sample
preservation. Samples should be surrounded by shock- and water-absorbent packing materials or ice (if required for preservation) and shipped in a cooler to ensure sample temperatures do not exceed
preservation requirements. If the target analytes are unknown, samples should be maintained at < 6®C, but above freezing. Ice should be placed in separate plastic bags or cold packs should be used to avoid
leakage, and the bags placed around, among, and on top of the sample containers.
(5)	Sodium thiosulfate or sodium sulfite should be added to treated drinking water or wastewater samples containing residual chlorine. These dechlorinating agents can be added either prior to or after sample
collection, but before sample preservation.
~	For sodium thiosulfate, an amount equivalent to the following is recommended: 3 mg/40-mL sample, or 3 mg/5 mg chlorine residual.
~	For sodium sulfite, an amount equivalent to the following is recommended: for a 1-L sample, add 40 - 50 mg sodium sulfite (1.6 - 2 mg/40-mL sample), either prior to or after collecting the sample.
(6)	This method applies to ambient concentrations of VOCs above 0.5 ppbv and typically requires VOC enrichment by concentrating up to 1 L of sample volume; however, when using current technologies,
quantifications of approximately 100 pptv have been achieved with 0.5-L sample volumes.
(7)	If sample collectors are not able to preserve samples in the field (e.g., acid preservatives are not available), the samples may be preserved in the laboratory. If preserved in the laboratory, however, samples
must be held for at least 24 hours prior to analysis.
(8)	Samples containing secondary explosives at concentrations less than 10% by weight (100,000 mg/kg) or primary explosives at concentrations less than 2% can be sent as normal environmental samples.
Consult laboratory on specifics regarding shipping label and shipping requirements for samples with concentrations greater than these amounts.
SAM Companion - Sample Collection Information Document
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Attachment B1
Sample Collection Information for the
Environmental Samples, Radiochemical Analytes and
Methods Listed in SAM 2017
[Note: The acronyms and abbreviations used in this attachment are
listed and defined in the beginning of the report.]

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Sample Collection Information Document - Attachment B1
September 2017
Attachment B1: Sample Collection Information for the Environmental Samples, Radiochemical Analytes and Methods Listed in SAM 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Gross Alpha
Air Filter
1 filter (limited to
counting geometry size)
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
No preservation required
FRMAC, Vol. 2, pg. 33 (DOE)

Aqueous & Liquid
2 - 4 L (solids limited)
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
Preserve sample with
HN03 or HCI topH < 2 (6)
7110 B (SM)

Drinking Water
2 - 4 L (solids limited)
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
Preserve sample with
HN03 or HCI topH < 2 (6)
900.0 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
No preservation required
AP1 (ORISE)

Surface Wipes
1 wipe (limited to
counting geometry size)
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
No preservation required
FRMAC, Vol. 2, pg. 33 (DOE)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
No preservation required
AP1 (ORISE)
Gross Beta
Air Filter
1 filter (limited to
counting geometry size)
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
No preservation required
FRMAC, Vol. 2, pg. 33 (DOE)

Aqueous & Liquid
2 - 4 L (solids limited)
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
Preserve sample with
HNOs or HCI to pH < 2 (6)
7110 B (SM)

Drinking Water
2 - 4 L (solids limited)
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
Preserve sample with
HNOs or HCI to pH < 2 (6)
900.0 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar,
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
No preservation required
AP1 (ORISE)

Surface Wipes
1 wipe (limited to
counting geometry size)
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
No preservation required
FRMAC, Vol. 2, pg. 33 (DOE)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
No preservation required
AP1 (ORISE)
SAM Companion - Sample Collection Information Document
B1 - 1
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Gamma
Select Mixed
Air Filter
1 filter (limited to
counting geometry size)
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic baq
Maximum 6 months'4'
No preservation required
Ga-01-R (HASL-300)
Fission Products
Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
Preserve sample with
HN03 or HCI topH < 2 (6)
Ga-01 -R (HASL-300)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
Preserve sample with
HN03 or HCI topH < 2 (6)
901.1 (EPA)

Soil & Sediment
100-1,000 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
No preservation required
Ga-01-R (HASL-300)

Surface Wipes
1 wipe (limited to
counting geometry size)
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
No preservation required
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
No preservation required
Ga-01-R (HASL-300)
Total Activity
Screening
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
No preservation required
Preparation of Samples for Total Activity
Screening (Y-12)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
No preservation required
Preparation of Samples for Total Activity
Screening (Y-12)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
No preservation required
Preparation of Samples for Total Activity
Screening (Y-12)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
No preservation required. If Tc-
99 is to be assessed, a separate
sample will be necessary.
Preparation of Samples for Total Activity
Screening (Y-12)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
No preservation required. If Tc-
99 is to be assessed, a separate
sample will be necessary.
Preparation of Samples for Total Activity
Screening (Y-12)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
No preservation required. If Tc-
99 is to be assessed, a separate
sample will be necessary.
Preparation of Samples for Total Activity
Screening (Y-12)
SAM Companion - Sample Collection Information Document
B1 - 2
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Americium-241
(alpha)
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv:
Am-04-RC (HASL-300)
Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Am-241 half life = 432 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative: D3084-05 (ASTM)
Confirmatorv:
Am-04-RC (HASL-300)
Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Am-241 half life = 432 years)
Qualitative: No sample
preservation is required if sample
is delivered to the laboratory
within 3 days of collection.
If the sample is to be held for
more than 3 days, add
concentrated HN03 to achieve a
pH < 2.
Confirmatory: Preserve sample
with HN03or HCI to pH < 2 (6)
Qualitative: Rapid Radiochemical Method
for Am-241 (EPA)
Confirmatorv:
Am-04-RC (HASL-300)
Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative: Rapid Method for Fusion of
Soil and Soil-Related Matrices (EPA)
Confirmatorv:
Am-01-RC (HASL-300)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv:
Am-04-RC (HASL-300)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative: Actinidesand
Sr-89/90 in Vegetation (DOE SRS)
Confirmatorv:
Am-06-RC (HASL-300)
SAM Companion - Sample Collection Information Document
B1 - 3
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Americium-241
(gamma)
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Am-241 half life = 432 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Am-241 half life = 432 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Am-241 half life = 432 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
Californium-252
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Cf-252 half life = 2.64 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv: Raoid Radiochemical
Method for Californium-252 (EPA)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Cf-252 half life = 2.64 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative: D3084-05 (ASTM)
Confirmatorv: Raoid Radiochemical
Method for Californium-252 (EPA)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Cf-252 half life = 2.64 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative: D3084-05 (ASTM)
Confirmatorv: Rapid Radiochemical
Method for Californium-252 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar,
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Cf-252 half life = 2.64 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv: Rapid Radiochemical
Method for Californium-252 (EPA)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Cf-252 half life = 2.64 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv: Rapid Radiochemical
Method for Californium-252 (EPA)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Cf-252 half life = 2.64 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv:
Am-06-RC (HASL-300)
SAM Companion - Sample Collection Information Document
B1 - 4
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Cesium-137
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Cs-137 half life = 30.17 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Cs-137 half life = 30.17 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Cs-137 half life = 30.17 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Cs-137 half life = 30.17 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Cs-137 half life = 30.17 years)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Cs-137 half life = 30.17 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
Cobalt-60
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Co-60 half life = 5.27 years)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Co-60 half life = 5.27 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Co-60 half life = 5.27 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Co-60 half life = 5.27 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Co-60 half life = 5.27 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Co-60 half life = 5.27 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -5
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Curium-244
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Cm-244 half life = 18.1 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv: Rapid Radiochemical
Method for Curium-244 in Air Particulate
Filters, Swipes and Soil (EPA)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Cm-244 half life = 18.1 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative: D3084-05 (ASTM)
Confirmatorv: Rapid Radiochemical
Method for Curium-244 in Air Particulate
Filters, Swipes and Soil (EPA)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Cm-244 half life = 18.1 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative: D3084-05 (ASTM)
Confirmatorv: Rapid Radiochemical
Method for Curium-244 in Air Particulate
Filters, Swipes and Soil (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Cm-244 half life = 18.1 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv: Raoid Radiochemical
Method for Curium-244 in Air Particulate
Filters, Swipes and Soil (EPA)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Cm-244 half life = 18.1 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv: Raoid Radiochemical
Method for Curium-244 in Air Particulate
Filters, Swipes and Soil (EPA)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Cm-244 half life = 18.1 years)
No preservation required
Qualitative: D3084-05 (ASTM)
Confirmatorv:
Am-06-RC (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -6
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Europium-154
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Eu-154 half life = 8.59 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Eu-154 half life = 8.59 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Eu-154 half life = 8.59 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Eu-154 half life = 8.59 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Eu-154 half life = 8.59 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Eu-154 half life = 8.59 years)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
lndium-111
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(ln-111 half life = 2.8 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
(ln-111 half life = 2.8 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Drinking Water
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
(ln-111 half life = 2.8 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Borosilicate glass wide-mouth jar
Maximum 6 months'4'
(ln-111 half life = 2.8 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(ln-111 half life = 2.8 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(ln-111 half life = 2.8 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
B1 - 7
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
lodine-125
Air Filter
1 charcoal cartridge
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(1-125 half life = 59.4 days)
No preservation required
Qualitative and Confirmatorv:
Procedure #9P) (ORISE)
Aqueous & Liquid
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
(1-125 half life = 59.4 days)
No preservation required
Qualitative and Confirmatorv:
Procedure #9 (ORISE)
Drinking Water
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
(1-125 half life = 59.4 days)
No preservation required
Qualitative and Confirmatorv:
Procedure #9 (ORISE)
Soil & Sediment
100 g
Borosilicate glass wide-mouth jar
Maximum 6 months'4'
(1-125 half life = 59.4 days)
No preservation required.
1-125 will volatilize with heat;
store samples at room
temperature if stored before
shippinq.
Qualitative and Confirmatorv:
Procedure #9 (ORISE)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(1-125 half life = 59.4 days)
No preservation required
Qualitative and Confirmatorv:
Procedure #9 (ORISE)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(1-125 half life = 59.4 days)
No preservation required.
1-125 will volatilize with heat;
store samples at room
temperature if stored before
shipping.
Qualitative and Confirmatory:
Procedure #9 (ORISE)
lodine-131
Air Filter
Charcoal or silver
zeolite cartridge
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(1-131 half life = 8.03 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01 -R(7) (HASL-300)
Aqueous & Liquid
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
(1-131 half life = 8.03 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
Drinking Water
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
(1-131 half life = 8.03 days)
No preservation required
(Sample acidification
recommended in Method 901.1
should not be applied to samples
collected for analysis of 1-131)
Qualitative and Confirmatorv:
901.1 (EPA)
Soil & Sediment
100 g
Borosilicate glass wide-mouth jar
Maximum 6 months'4'
(1-131 half life = 8.03 days)
No preservation required.
1-131 will volatilize with heat;
store samples at room
temperature if stored before
shipping.
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(1-131 half life = 8.03 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(1-131 half life = 8.03 days)
No preservation required.
1-131 will volatilize with heat;
store samples at room
temperature if stored before
shipping.
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -8
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
lridium-192
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(lr-192 half life = 173 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(lr-192 half life = 173 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(lr-192 half life = 173 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(lr-192 half life = 173 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(lr-192 half life = 173 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(lr-192 half life = 173 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
Molybdenum-99
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Mo-99 half life = 65.94 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Mo-99 half life = 65.94 hours)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Mo-99 half life = 65.94 hours)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Mo-99 half life = 65.94 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Mo-99 half life = 65.94 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Mo-99 half life = 65.94 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -9
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Neptunium-237
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Np-237 half life = 2.14 million years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Np-237 half life = 2.14 million years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Np-237 half life = 2.14 million years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
907.0 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Np-237 half life = 2.14 million years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Np-237 half life = 2.14 million years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Np-237 half life = 2.14 million years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)
Neptunium-239
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Np-239 half life = 2.4 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Np-239 half life = 2.4 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Np-239 half life = 2.4 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Np-239 half life = 2.4 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Np-239 half life = 2.4 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Np-239 half life = 2.4 days)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -10
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Phosphorus-32
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(P-32 half life = 14.26 days)
No preservation required
Qualitative and Confirmatorv:
RESL P-2 (DOE)
Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(P-32 half life = 14.26 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
R4-73-014 (EPA)
Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(P-32 half life = 14.26 days)
Qualitative: No sample
preservation is required if sample
is delivered to the laboratory
within 3 days of sampling
date/time. If the sample is to be
held for more than 3 days, add
concentrated HN03 to achieve a
pH < 2.
Confirmatorv: Preserve samole
with HNOs or HCI to pH < 2 (6)
Qualitative: Rapid Radiochemical Method
for P-32 in Water (EPA)
Confirmatorv: R4-73-014 (EPA)
Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(P-32 half life = 14.26 days)
No preservation required
Qualitative and Confirmatorv:
RESL P-2 (DOE)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(P-32 half life = 14.26 days)
No preservation required
Qualitative and Confirmatorv:
RESL P-2 (DOE)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(P-32 half life = 14.26 days)
No preservation required
Qualitative and Confirmatorv:
RESL P-2 (DOE)
SAM Companion - Sample Collection Information Document
B1 - 11
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Plutonium-238
Plutonium-239
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Pu-238 half life = 87.7 years)
(Pu-239 half life = 24,100 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: SOP for Actinides in
Environmental Matrices (EPA-NAREL)
Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Pu-238 half life = 87.7 years)
(Pu-239 half life = 24,100 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative: D3084-05 (ASTM)
Confirmatorv: SOP for Actinides in
Environmental Matrices (EPA-NAREL)
Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Pu-238 half life = 87.7 years)
(Pu-239 half life = 24,100 years)
Qualitative: No sample
preservation is required if sample
is delivered to the laboratory
within 3 days of collection.
If the sample is to be held for
more than 3 days, add
concentrated HN03 to achieve a
pH < 2.
Confirmatory: Preserve sample
with HN03 or HCI to pH < 2 (6)
Qualitative: Rapid Radiochemical Method
for Pu (EPA)
Confirmatorv: EMSL-33 (EPA)
Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Pu-238 half life = 87.7 years)
(Pu-239 half life = 24,100 years)
No preservation required
Qualitative: Rapid Method for Fusion of
Soil and Soil-Related Matrices (EPA)
Confirmatorv: SOP for Actinides in
Environmental Matrices (EPA-NAREL)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Pu-238 half life = 87.7 years)
(Pu-239 half life = 24,100 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: SOP for Actinides in
Environmental Matrices (EPA-NAREL)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Pu-238 half life = 87.7 years)
(Pu-239 half life = 24,100 years)
No preservation required
Qualitative: Actinides and
Sr-89/90 in Vegetation (DOE SRS)
Confirmatorv: Am-06-RC (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -12
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the
container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Polonium-210
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Po-210 half life = 138 days)
No preservation required
Qualitative and Confirmatorv:
Method 111 (EPA)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Po-210 half life = 138 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
Po-02-RC (HASL-300)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Po-210 half life = 138 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
Po-02-RC (HASL-300)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Po-210 half life = 138 days)
No preservation required
Qualitative and Confirmatorv:
Po-02-RC (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Po-210 half life = 138 days)
No preservation required
Qualitative and Confirmatorv:
Method 111 (EPA)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Po-210 half life = 138 days)
No preservation required
Qualitative and Confirmatorv:
Po-02-RC (HASL-300)
Radium-223
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ra-223 half life = 11.4 days)
No preservation required
Qualitative and Confirmatorv:
Rapid Radiochemical Method
for Ra-226 (EPA)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ra-223 half life = 11.4 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
Rapid Radiochemical Method
for Ra-226 (EPA)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ra-223 half life = 11.4 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatorv:
Rapid Radiochemical Method
for Ra-226 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Ra-223 half life = 11.4 days)
No preservation required
Qualitative and Confirmatorv:
Rapid Radiochemical Method
for Ra-226 (EPA)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ra-223 half life = 11.4 days)
No preservation required
Qualitative and Confirmatorv:
Rapid Radiochemical Method
for Ra-226 (EPA)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Ra-223 half life = 11.4 days)
No preservation required
Qualitative and Confirmatorv:
Rapid Radiochemical Method
for Ra-226 (EPA)
SAM Companion - Sample Collection Information Document
B1 -13
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Radium-226
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ra-226 half life = 1,600 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: Raoid Radiochemical
Method for Radium-226 in Building
Materials (EPA)
Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ra-226 half life = 1,600 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative: 7500-Ra B (SM)
Confirmatorv: 7500-Ra C (SM)
Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ra-226 half life = 1,600 years)
Qualitative: No sample
preservation is required if sample
is delivered to the laboratory
within 3 days of collection.
If the sample is to be held for
more than 3 days, add
concentrated HN03 to achieve a
pH < 2.
Confirmatorv: Preserve samole
with HNOs or HCI to pH < 2 (6)
Qualitative: Raoid Radiochemical
Methods for Ra-226 (EPA)
Confirmatorv: 903.1 (EPA)
Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Ra-226 half life = 1,600 years)
No preservation required
Qualitative: Raoid Method for Radium in
Soil (EPA)
Confirmatorv: AP7 (ORISE)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ra-226 half life = 1,600 years)
No preservation required
Qualitative: Raoid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: Rapid Radiochemical
Method for Radium-226 in Building
Materials (EPA)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Ra-226 half life = 1,600 years)
No preservation required
Qualitative and Confirmatorv:
Ra-03-RC (HASL-300)
SAM Companion - Sample Collection Information Document
B1 - 14
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Rhenium-188
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months
(Re-188 half life = 16.9 hours)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months
(Re-188 half life = 16.9 hours)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months
(Re-188 half life = 16.9 hours)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatory:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months
(Re-188 half life = 16.9 hours)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months
(Re-188 half life = 16.9 hours)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months
(Re-188 half life = 16.9 hours)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)
Rubidium-82
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Rb-82 half life = 75 seconds)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Rb-82 half life = 75 seconds)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Rb-82 half life = 75 seconds)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatory:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Rb-82 half life = 75 seconds)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Rb-82 half life = 75 seconds)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Rb-82 half life = 75 seconds)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -15
September 2017

-------
Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Ruthenium-103
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ru-103 half life = 39.3 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ru-103 half life = 39.3 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatory:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ru-103 half life = 39.3 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatory:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Ru-103 half life = 39.3 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ru-103 half life = 39.3 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Ru-103 half life = 39.3 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)
Ruthenium-106
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ru-106 half life = 374 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ru-106 half life = 374 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatory:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Ru-106 half life = 374 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatory:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Ru-106 half life = 374 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Ru-106 half life = 374 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Ru-106 half life = 374 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
B1 -16
September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the
container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Selenium-75
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Se-75 half life = 120 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Se-75 half life = 120 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatory:
7120 (SM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Se-75 half life = 120 days)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatory:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Se-75 half life = 120 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Se-75 half life = 120 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Se-75 half life = 120 days)
No preservation required
Qualitative and Confirmatory:
Ga-01-R (HASL-300)
Strontium-89
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Sr-89 half life = 50.53 days)
No preservation required
Qualitative and Confirmatory:
Strontium in Food and Bioenvironmental
Samples (EPA)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Sr-89 half life = 50.53 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatory:
905.0 (EPA)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Sr-89 half life = 50.53 days)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative and Confirmatory:
905.0 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Sr-89 half life = 50.53 days)
No preservation required
Qualitative: Actinidesand
Sr-89/90 in Soil Samples (DOE SRS)
Confirmatory: Strontium in Food and
Bioenvironmental Samples (EPA)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Sr-89 half life = 50.53 days)
No preservation required
Qualitative and Confirmatory:
Strontium in Food and Bioenvironmental
Samples (EPA)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Sr-89 half life = 50.53 days)
No preservation required
Qualitative: Actinidesand
Sr-89/90 in Soil Samples (DOE SRS)
Confirmatory: Strontium in Food and
Bioenvironmental Samples (EPA)
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September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Strontium-90
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Sr-90 half life = 28.8 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: Sr-03-RC (HASL-300)
Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Sr-90 half life = 28.8 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
D5811-08 (ASTM)
Drinking Water
2 - 4 L
Samples should be collected in 1 -L
plastic containers
Maximum 6 months'4'
(Sr-90 half life = 28.8 years)
Qualitative: No sample
preservation is required if sample
is delivered to the laboratory
within 3 days of sampling
date/time. If the sample is to be
held for more than 3 days, add
concentrated HN03 to achieve a
pH < 2.
Confirmatorv: Preserve sample
with HNOs or HCI to pH < 2 (6)
Qualitative: Rapid Radiochemical
Methods for Sr-90 (EPA)
Confirmatorv: 905.0 (EPA)
Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Sr-90 half life = 28.8 years)
No preservation required
Qualitative: Rapid Method for Sodium
Carbonate Fusion of Soil and Soil-
Related Matrices (EPA)
Confirmatorv: Sr-03-RC (HASL-300)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Sr-90 half life = 28.8 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: Sr-03-RC (HASL-300)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Sr-90 half life = 28.8 years)
No preservation required
Qualitative: Actinides and Sr-89/90 in
Vegetation (DOE SRS)
Confirmatorv: Sr-03-RC (HASL-300)
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Technetium-99
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Tc-99 half life = 211,000 years)
No preservation required
Qualitative and Confirmatorv:
AP5 (ORISE)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Tc-99 half life = 211,000 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
D7168-05 (ASTM)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Tc-99 half life = 211,000 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
Tc-02-RC (HASL-300)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Tc-99 half life = 211,000 years)
No preservation required
Qualitative and Confirmatorv:
AP5 (ORISE)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Tc-99 half life = 211,000 years)
No preservation required
Qualitative and Confirmatorv:
AP5 (ORISE)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Tc-99 half life = 211,000 years)
No preservation required
Qualitative: AP5 (ORISE)
Confirmatorv: Tc-01-RC (HASL-300)
Technetium-99m
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Tc-99m half life = 6 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Tc-99m half life = 6 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Tc-99m half life = 6 hours)
No preservation required
Qualitative and Confirmatorv:
901.1 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Tc-99m half life = 6 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Tc-99m half life = 6 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Tc-99m half life = 6 hours)
No preservation required
Qualitative and Confirmatorv:
Ga-01-R (HASL-300)
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Thorium-227
Thorium-228
Thorium-230
Thorium-232
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Th-227 half life = 18.7 days)
(Th-228 half life = 1.9 years)
(Th-230 half life = 7.5 years)
(Th-232 half life = 1.4 x 1010 years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Th-227 half life = 18.7 days)
(Th-228 half life = 1.9 years)
(Th-230 half life = 7.5 years)
(Th-232 half life = 1.4 x 1010 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
(Th-227 half life = 18.7 days)
(Th-228 half life = 1.9 years)
(Th-230 half life = 7.5 years)
(Th-232 half life = 1.4 x 1010 years)
Preserve sample with
HN03 or HCI topH < 2 (6)
Qualitative and Confirmatorv:
907.0 (EPA)

Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
(Th-227 half life = 18.7 days)
(Th-228 half life = 1.9 years)
(Th-230 half life = 7.5 years)
(Th-232 half life = 1.4 x 1010 years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
(Th-227 half life = 18.7 days)
(Th-228 half life = 1.9 years)
(Th-230 half life = 7.5 years)
(Th-232 half life = 1.4 x 1010 years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)

Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(Th-227 half life = 18.7 days)
(Th-228 half life = 1.9 years)
(Th-230 half life = 7.5 years)
(Th-232 half life = 1.4 x 1010 years)
No preservation required
Qualitative and Confirmatorv:
SOP for Actinides in Environmental
Matrices (EPA-NAREL)
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Tritium
(Hydrogen-3)
Air Filter
For the purposes of this document, this analyte is not considered to be a concern in this sample type
Aqueous & Liquid
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
(3H half life = 12.32 years)
No preservation required
Qualitative and Confirmatorv:
906.0 (EPA)
Drinking Water
2 - 4 L
Borosilicate glass small-mouth bottle
Maximum 6 months'4'
("H half life = 12.32 years)
No preservation required
Qualitative and Confirmatorv:
906.0 (EPA)
Soil & Sediment
100 g
Borosilicate glass wide-mouth jar
Maximum 6 months'4'
("H half life = 12.32 years)
No preservation required. Tritium
will volatilize with heat; store
samples at room temperature if
stored before shipping.
Qualitative and Confirmatorv:
AP2 (ORISE)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
("H half life = 12.32 years)
No preservation required. Tritium
will volatilize with heat; do not dry
sample before analysis.
Qualitative and Confirmatorv:
AP2 (ORISE)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
(3H half life = 12.32 years)
No preservation required. Tritium
will volatilize with heat; do not dry
sample prior to analysis.
Qualitative and Confirmatorv:
AP2 (ORISE)
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples
outside the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected'3'
Sample Container'4'
Holding Time'4'
Sample Preservation'4'
Analytical Method'5'
Uranium-234
Uranium-235
Uranium-238
Air Filter
1 filter
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
~	(U-234 half life = 244,000 years)
~	(U-235 half life = 700 x 106 years)
~	(U-238 half life = 4.47 x 109 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: SOP for Actinides in
Environmental Matrices (EPA-NAREL)
Aqueous & Liquid
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
~	(U-234 half life = 244,000 years)
~	(U-235 half life = 700 x 106 years)
~	(U-238 half life = 4.47 x 109 years)
Preserve sample with
HNOs or HCI to pH < 2 (6)
Qualitative: 7500-U B (SM)
Confirmatorv: 7500-U C (SM)
Drinking Water
2 - 4 L
Plastic (polypropylene or
polyethylene) or borosilicate glass
small-mouth bottle
Maximum 6 months'4'
~	(U-234 half life = 244,000 years)
~	(U-235 half life = 700 x 106 years)
~	(U-238 half life = 4.47 x 109 years)
Qualitative: No sample
preservation is required if sample
is delivered to the laboratory
within 3 days of collection.
If the sample is to be held for
more than 3 days, add
concentrated HN03 to achieve a
pH < 2.
Confirmatory: Preserve sample
with HNOs or HCI to pH < 2 (6)
Qualitative: Rapid Radiochemical Method
for U (EPA)
Confirmatorv: D3972-02 (ASTM)
Soil & Sediment
100 g
Plastic (polypropylene or
polyethylene) large-mouth bottle, jar
or plastic bag. Borosilicate glass
wide-mouth jar may also be used.
Maximum 6 months'4'
~	(U-234 half life = 244,000 years)
~	(U-235 half life = 700 x 106 years)
~	(U-238 half life = 4.47 x 109 years)
No preservation required
Qualitative: Rapid Method for Fusion of
Soil and Soil-Related Matrices (EPA)
Confirmatorv: SOP for Actinides in
Environmental Matrices (EPA-NAREL)
Surface Wipes
1 wipe
Glassine envelope, polyacrylic
plastic Petri dish, or polyethylene
plastic bag
Maximum 6 months'4'
~	(U-234 half life = 244,000 years)
~	(U-235 half life = 700 x 106 years)
~	(U-238 half life = 4.47 x 109 years)
No preservation required
Qualitative: Rapid Methods for Acid or
Fusion Digestion (EPA)
Confirmatorv: SOP for Actinides in
Environmental Matrices (EPA-NAREL)
Vegetation
1 -gallon tightly packed
zipper-locked bag or
plastic container
Plastic (polypropylene or
polyethylene) bag with zipper lock
and durability to resist punctures OR
wide-mouth plastic container
Maximum 6 months'4'
~	(U-234 half life = 244,000 years)
~	(U-235 half life = 700 x 106 years)
~	(U-238 half life = 4.47 x 109 years)
No preservation required
Qualitative: Actinides and
Sr-89/90 in Vegetation (DOE SRS)
Confirmatorv: U-02-RC (HASL-300)
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September 2017

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Sample Collection Information Document - Attachment B1
September 2017
Footnotes:
(1)	Sample transport containers are packed outside the contaminated area. Samples must be packed in a manner that protects the integrity of the containers. Samples should be surrounded by shock absorbing and liquid
absorbent packing materials (49 CFR 173.24 and 173.453). Check the radiation-specific activity from the packaged samples (49 CFR 173.403).
(2)	Although the package required for transporting radioactive material is based on the activity INSIDE the package, the label required on the transport package is based on the radiation hazard OUTSIDE the package.
Radioactive material is the only hazardous material that has three possible labels, depending on the relative radiation levels external to the package. Labels for radioactive material also require a Transportation Index (Tl)
number which indicates the highest radiation level measured at 1 meter from the surface of the package. The three possible labels are commonly called White 1, Yellow 2, and Yellow 3, referring to the color of the label
and the number prominently displayed. The specific label required (White 1, Yellow 2, or Yellow 3) is based on the limits specified in 49 CFR 172.403.
(3)	Sample sizes are provided for guidance, and may vary depending on the specific contamination incident, data quality objectives and requirements, and laboratory radiochemistry license considerations. With the
exception of total gamma, the sample sizes listed are based on the amount needed to support analyses addressing all the radioisotopes listed in this attachment; the sample size listed for total gamma is based on the
amount needed to determine only total gamma radiation.
(4)	Sample container, holding times, preservation, and sample preparation information has been derived from requirements stated in the analytical methods, documents cited under "Analytical Method" or in Section 7.0 of
this document, or best professional judgment. Holding times can be significantly less than 6 months, depending on the specific isotope targeted and its concentration in the sample.
(5)	Methods listed in this column can be located using U.S. Environmental Protection Agency, National Homeland Security Research Center's (NHSRC) Selected Analytical Methods for Environmental Remediation and
Recovery (SAM) 2017 (https://www.epa.aov/homeland-securitv-research/samV The SAM document is intended to be used concurrently with this Sample Collection Information Document. Full citations for references not
cited and/or accessed through the SAM website are provided in Section 7.0 of this document.
(6)	If dissolved components are to be determined, samples requiring preservation must be filtered prior to preservation. Drinking water samples can be preserved in the laboratory within 5 days of collection, if sample
collectors are not able to preserve the samples in the field
(7)	This procedure should be used only for filters specifically designed for iodine.
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Attachment B2
Sample Collection Information for the
Outdoor Building and Infrastructure Materials,
Radiochemical Analytes and Methods Listed in
SAM 2017
[Note: The acronyms and abbreviations used in this attachment are
listed and defined in the beginning of the report.]

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Sample Collection Information Document - Attachment B2
September 2017
Attachment B2: Sample Collection Information for the Outdoor Building and Infrastructure Materials, Radiochemical Analytes and Methods Listed in
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples outside
the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected131
Sample Container*4'
Holding Time*4'
Sample Preservative*4'
Sample Preparation Methods*5'
Analytical Methods*5'

Asphalt shingles
250 grams
Chips, rubble, particulates:
250-mL or larger plastic jars
or sample bottles
Cores, cuttings, bulk
Maximum 6 months
(Am-241 half life =
432 years)
No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Asphalt Matrices
Prior to Americium, Plutonium,
Strontium, Radium, and Uranium
Analyses
• EPA NAREL - Rapid
Radiochemical Method for
Americium-241 in Building
Materials

Asphalt paving
material
25 grams
materials: Large zip-locking
or plastic bag with ties,
and/or box (steel, wood or
fiberboard)

No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Asphalt Roofing
Material Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses


Concrete
25 grams


No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Concrete and


Brick
25 grams


No preservation required
Brick Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses for Environmental
Remediation Following Radiological
Incidents


Granite
25 grams


No preservation required


Stucco
25 grams


No preservation required

Plutonium-238
Plutonium-239
Asphalt shingles
250 grams
Chips, rubble, particulates:
250-mL or larger plastic jars
or sample bottles
Cores, cuttings, bulk
materials: Large zip-locking
or plastic bag with ties,
and/or box (steel, wood or
fiberboard)
Maximum 6 months
(Pu-238 half life =
87.7 years)
(Pu-239 half life -
24,100 years)
No preservation required
~ Rapid Method for Sodium
Hydroxide Fusion of Asphalt Matrices
Prior to Americium, Plutonium,
Strontium, Radium, and Uranium
Analyses
• EPA NAREL - Rapid
Radiochemical Method for
Plutonium-238 and Plutonium-
239/240 in Building Materials

Asphalt
25 grams
No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Asphalt Roofing
Material Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses


Concrete
25 grams


No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Concrete and


Brick
25 grams


No preservation required
Brick Matrices Prior to Americium,
Plutonium, Strontium, Radium, and


Granite
25 grams


No preservation required
Uranium Analyses for Environmental
Remediation Following Radiological
Incidents


Stucco
25 grams


No preservation required

Sample Collection Information Document
B2-1
September 2017

-------
Sample Collection Information Document - Attachment B2
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples outside
the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected131
Sample Container*4'
Holding Time*4'
Sample Preservative*4'
Sample Preparation Methods*5'
Analytical Methods*5'
Radium-226
Asphalt shingles
250 grams
Chips, rubble, particulates:
250-mL or larger plastic jars
or sample bottles
Cores, cuttings, bulk
materials: Large zip-locking
Maximum 6 months
(Ra-226 half life =
1,600 years)
No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Asphalt Matrices
Prior to Americium, Plutonium,
Strontium, Radium, and Uranium
Analyses
• EPA NAREL - Radium-226 in
Bitumen, Aggregate, Stone or
other Solid Samples: Rapid
Method for High-Activity
Samples

Asphalt
25 grams
or plastic bag with ties,
and/or box (steel, wood or
fiberboard)

No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Asphalt Roofing
Material Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses
• EPA NAREL - Rapid
Radiochemical Method for
Radium-226 in Building
Materials for Environmental
Remediation Following
Radiological Incidents

Concrete
25 grams


No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Concrete and
Brick Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses for Environmental
Remediation Following Radiological
Incidents
• EPA NAREL - Rapid
Radiochemical Method for
Radium-226 in Building
Materials for Environmental
Remediation Following
Radiological Incidents

Brick
25 grams


No preservation required

Granite
25 grams


No preservation required

Stucco
25 grams


No preservation required


Stontium-90
Asphalt shingles
250 grams
Chips, rubble, particulates:
250-mL or larger plastic jars
or sample bottles
Cores, cuttings, bulk
materials: Large zip-locking
or plastic bag with ties,
and/or box (steel, wood or
fiberboard)
Maximum 6 months
(Sr-90 half life = 28.8
years)
No preservation required
~ Rapid Method for Sodium
Hydroxide Fusion of Asphalt Matrices
Prior to Americium, Plutonium,
Strontium, Radium, and Uranium
Analyses
• EPA NAREL - Rapid
Radiochemical Method for
Strontium-90 (Sr-90) in Building
Materials for Environmental
Remediation Following
Radiological Incidents

Asphalt
25 grams

No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Asphalt Roofing
Material Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses

Concrete
25 grams


No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Concrete and


Brick
25 grams


No preservation required
Brick Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses for Environmental
Remediation Following Radiological
Incidents


Granite
25 grams


No preservation required


Stucco
25 grams


No preservation required

Sample Collection Information Document
B2 -2
September 2017

-------
Sample Collection Information Document - Attachment B2
September 2017
Packaging Requirements: Wipe outside of each container clean using a damp, then dry cloth. Seal the container with non-reactive tape or film. Determine the radiation-specific activity of the sample(s) and pack samples outside
the contaminated area as described in Footnote (1).
Shipping Label: Shipping labels per requirements of 49 CFR 173. Determine the radiation levels on the surface and at 1 meter from the surface of the package, and label. Refer to information in Footnote (2).
Analyte
Sample Type
Sample Size
Collected131
Sample Container*4'
Holding Time*4'
Sample Preservative*4'
Sample Preparation Methods*5'
Analytical Methods*5'
Uranium-234
Uranium-235
Uranium-238
Asphalt shingles
250 grams
Chips, rubble, particulates:
250-mL or larger plastic jars
or sample bottles
Cores, cuttings, bulk
materials: Large zip-locking
or plastic bag with ties,
and/or box (steel, wood or
fiberboard)
Maximum 6 months
(U-234 half life =
244,000 years)
(U-235 half life -
700 million years)
(U-238 half life =
4.47 billion years)
No preservation required
•	Rapid Method for Sodium
Hydroxide Fusion of Asphalt Matrices
Prior to Americium, Plutonium,
Strontium, Radium, and Uranium
Analyses
•	Rapid Method for Sodium
Hydroxide Fusion of Asphalt Roofing
Material Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses
• EPA NAREL - Rapid
Radiochemical Method for
Isotopic Uranium in Building
Materials for Environmental
Remediation Following
Radiological Incidents
Asphalt
25 grams
No preservation required
Concrete
25 grams
No preservation required
• Rapid Method for Sodium
Hydroxide Fusion of Concrete and
Brick Matrices Prior to Americium,
Plutonium, Strontium, Radium, and
Uranium Analyses for Environmental
Remediation Following Radiological
Incidents
Brick
25 grams
No preservation required
Granite
25 grams
No preservation required
Stucco
25 grams
No preservation required
Footnotes:
(1)	Sample transport containers are packed outside the contaminated area. Samples must be packed in a manner that protects the integrity of the sample containers. Samples should be surrounded by shock absorbing and liquid
absorbent packing materials (49 CFR 173.24 and 173.453). Check the radiation-specific activity from the packaged samples (49 CFR 173.403).
(2)	Although the package required for transporting radioactive material is based on the activity INSIDE the package, the label required on the transport package is based on the radiation hazard OUTSIDE the package. Radioactive
material is the only hazardous material that has three possible labels, depending on the relative radiation levels external to the package. Labels for radioactive material also require a Transportation Index (Tl) number which
indicates the highest radiation level measured at 1 meter from the surface of the package. The three possible labels are commonly called White 1, Yellow 2, and Yellow 3, referring to the color of the label and the number
prominently displayed. The specific label required (White 1, Yellow 2, or Yellow 3) is based on the limits specified in 49 CFR 172.403.
(3)	Sample sizes are provided for guidance, and may vary depending on the specific contamination incident, data quality objectives and requirements, and laboratory radiochemistry license considerations. The sample sizes listed
are based on the amount needed to support analyses addressing all the radioisotopes listed in this attachment.
(4)	Sample container, holding times, preservation, and sample preparation information has been derived from requirements stated in the analytical methods, documents cited under "Analytical Method" or in Section 7.0 of this
document, or best professional judgment. Holding times can be significantly less than 6 months, depending on the specific isotope targeted and its concentration in the sample.
(5)	Methods listed in this column can be located using U.S. Environmental Protection Agency, National Homeland Security Research Center's (NHSRC) Selected Analytical Methods for Environmental Remediation and Recovery
(SAM) 2017 (https://www.epa.aov/homeland-securitv-research/samV The Selected Analytical Methods document is intended to be used concurrently with this Sample Collection Information Document. Full citations for references
not cited and/or accessed through the SAM website are provided in Section 7.0 of this document.
Sample Collection Information Document
B2 -3
September 2017

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Attachment C
Sample Collection Information for the
Biotoxins and Methods Listed in SAM 2017
[Note: The acronyms and abbreviations used in this attachment are
listed and defined in the beginning of the report.]

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Sample Collection Information Document - Attachment C
September 2017
Attachment C: Sample Collection Information for the Biotoxin Analytes and Methods Listed in SAM 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Abrin and
Abrine (abrin marker)
Presumptive:
~	[LFA] Adapted from
Biosecurity and
Bio terrorism: Biodefense
Strategy, Practice, and
Science (2014) 12(1):
49-62 [Tier I / Tier II]
~	as Abrine [LC-MS-MS]
EPA 600/R-13/022
[Tier I/Tier II]
Confirmatorv:
~	[ELISA and ECL]
Adapted from Journal of
Food Protection (2008)
71(9): 1868-1874 [Tier II]
Bioloaical Activity:
~	[Enzyme Activity]
Adapted from Analytical
Biochemistry (2008)
378(1): 87-89 [Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
~	Avoid freeze-thaw
cycles during transport of
samples collected for
abrin.
NOTE: For detection and
measurement of abrine in
treated water samples,
add the following to the
sample container prior to
collection:
~	8 mg sodium
thiosulfate/100-mL
sample
~	6.4 mg sodium omadine
/100-mL sample
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
NOTE: 28 days for
abrine in water
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnote (5).
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, liquid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 ml_
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
NOTE: Collect water
samples for analysis of
abrine in polypropylene
container with
polyethylene screw-cap.
100 mL
Aflatoxins
(B1, B2, G1, G2)
Presumptive and
Confirmatorv:
~ [Immunoaffinity (column)
purification / HPLC-FL]
Adapted from 991.31
(AOAC) [Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
SAM Companion - Sample Collection Information Document
C1 -1
September 2017

-------
Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
a-Amanitin
Presumptive:
~	[ELISA] Adapted from
Journal of Food Protection
(2005) 68(6): 1294-1301
[Tier II]
Confirmatorv:
~	[LC-MS-MS]
EPA 600/R-13/022 (EPA)
[Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
NOTE: For treated water:
~	Add 8 mg sodium
thiosulfate and 6.4 mg
sodium omadine /100-
mL sample.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
NOTE: 28 days for
water samples
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group II
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes or
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50-100 g
Water
(surface water, waste
water, drinking
water)
Polypropylene container
with polyethylene screw-
cap
100 mL
Anatoxin-a
Presumptive:
~	ELISA [Tier III] (No
reference is available at
this time. Please consult
the SAM website* for
information regarding the
status of this assay.)
Confirmatorv:
~	[LC-ESI-MS-MS]
Method 545 (EPA)
[Tier I/Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter. Place the filter
in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
NOTE: Use amber alass
or amber PETG
containers (or protect
from light)
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
~	Protect from light
NOTE: For treated water
samples, add 1 g sodium
bisulfate and 0.1 g
ascorbic acid / 1-L
sample.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
NOTE: 28 days for
water samples cooled
to < 10°C
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnote (5).
Belongs to Packing Group II
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, liquid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
100 mL
SAM Companion - Sample Collection Information Document
C1 - 2
September 2017

-------
Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Botulinum neurotoxins
(Serotypes A - G)
Presumptive:
~	[LFA] Adapted from EPA
Environmental Technology
Verification report
[Tier I/Tier II]
~	[ECL] Adapted from
Journal of the Science of
Food and Agriculture
(2014) 94: 707-712
[Tier II]
~	[Fluorescent bead-based
assay] Multi-agency
Report. Rapid Botulinum
Toxin Assay Test,
Evaluation and Validation
Study Report [Tier III]
~	[Antibody capture FRET-
based activity] Adapted
from Analytical
Biochemistry (2011)
411: 200-209 [Tier II]
Confirmatorv:
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
~	Avoid freeze-thaw
cycles during transport.
NOTE: For treated water,
add 50 mg sodium
thiosulfate / L sample
(DO NOT add sodium
thiosulfate to samples
that will be analyzed
using MS)
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, liquid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 ml_
~	[LC-ESI-MS-MS / MALDI-
TOF MS] Adapted from
Analytical Chemistry
(2005) 77: 3916-3924
[Tier II]
Bioloaical Activity:
~	[Mouse Bioassay] APHA
Press Compendium of
Methods, Chapter 32
[Tier I]
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
SAM Companion - Sample Collection Information Document
C1 - 3
September 2017

-------
Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Brevetoxins
(A and B Forms)
Presumptive and
Confirmatorv:
• [ELISA / LC-MS]
Adapted from Toxicon
(2015) 96: 82-88 [Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group II
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name: "Toxic
solids, organic, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile, leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 ml_
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
Cylindrospermopsin
Presumptive:
~	[ELISA] Adapted from
Environmental Sciences
and Technology (2010)
44: 7361-7368 [Tier II]
Confirmatorv:
~	[LC-ESI-MS-MS]
Method 545 (EPA)
[Tier I/Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
NOTE: Use amber alass
or amber PETG
containers (or protect
from light)
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
NOTE: For treated water,
add 1 g sodium bisulfate
and 0.1 g ascorbic acid /
1-L sample.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
NOTE: 28 days for
water samples cooled
to < 10°C
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnote (5).
This substance does not
require specific labeling for
transport
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Amber glass container
with fluoropolymer- lined
screw cap
100 mL
SAM Companion - Sample Collection Information Document
C1 - 4
September 2017

-------
Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Diacetoxyscirpenol (DAS)
Presumptive:
~	[ELISA] Adapted from
Journal of Food
Microbiology (1988)
6(1): 9-17 [Tier III]
Confirmatorv:
~	[LC-MS-MS] Adapted
from Food Research
International (2015)
72: 247-255 [Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group II
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
Domoic acid
Presumptive:
~	[ELISA] Adapted from
Journal of AOAC
International (2007)
90(4): 1011-1027 [Tier II]
~	[ELISA] Adapted from
Journal of Shellfish
Research (2008)
27(5): 1301-1310 [Tier II]
Confirmatorv:
~	[LC-UV] Adapted from
Journal of the Mexican
Chemical Society (2011)
55(2): 65-71 [Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnote (5).
This substance does not
require specific labeling for
transport
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50-100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
A minimum of 100
mL
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Microcystins
(LA, LF, LR, LY, RR, YR)
Presumptive:
~ [ELISA]
Method 546 (EPA)
[Tier I/Tier II]
Confirmatorv:
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
< 10°C; do not freeze]
~	Protect from light
NOTE:
Prior to collection, add
the following to
containers used to collect
treated water samples:
~	For samples to be
analyzed using ELISA
(Method 546), 100 mg
sodium thiosulfate / 1-L
sample.
~	For samples to be
analyzed using LC-MS-
MS (Method 544), add 1)
7.75 g Trizma, 2) 2 g 2-
chloroacetamide, 3) 100
mg ascorbic acid, 4) 0.35
g ethylenediamine-
tetraacetic acid trisodium
salt /1-L sample.
Method 544 analysis:
28 days
Method 546 analysis:
48 hours (14 days if
frozen within 48
hours)
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
~ [LC-MS-MS]
Method 544 (EPA)
[Tier I/Tier II]
contents into sterile leak
proof container for
shipping.
NOTE: Use amber alass
or amber PETG
containers (or protect
from light)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
50 -100 ml_
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
500 mL
Picrotoxin
Confirmatorv:
~ [LC-UV] Adapted from
Journal of Pharmaceutical
and Biomedical Analysis
(1989) 7(3): 369-375
[Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
~	Protect from light.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group II
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
SAM Companion - Sample Collection Information Document
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September 2017

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Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Ricin and
Ricinine (ricin marker)
Presumptive:
~	[LFA] Adapted from
Biosecurity and
Bio terrorism: Biodefense
Strategy, Practice, and
Science (2013)
11(4): 237-250 [Tier I]
~	[ELISA] Adapted from
Journal of Food Protection
(2005) 68(6): 1294-1301
[Tier II]
~	[ECL] Adapted from
Journal of AOAC
International (2008)
91(2): 376-382 [Tier II]
~	as Ricinine [LC-MS-MS]
EPA 600/R-13/022
(EPA/CDC)
[Tier I/Tier II]
Confirmatorv and
Bioloaical Activity:
~	[Isotope Dilution LC-MS /
MALDI-TOF MS] Adapted
from Analytical Chemistry
(2011) 83: 2897-2905
[Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
~	Avoid freeze-thaw
cycles during transport of
samples collected for
ricin.
NOTE: For treated water,
add 50 mg sodium
thiosulfate / 1-L sample
NOTE: For samples
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group III
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, liquid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes,
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 ml_
collected for detection
and measurement of
ricinine in treated water,
add the following to the
sample container prior to
collection:
~	8 mg sodium
thiosulfate/100mL
sample
~	6.4 mg sodium omadine
/ 100-mL sample
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
SAM Companion - Sample Collection Information Document
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September 2017

-------
Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Saxitoxins
(STX, NEOSTX, dcSTX,
dcNEOSTX, doSTX,
GTX1-6, dcGTX 1-4)
Presumptive:
~	[Receptor binding assay]
Method 2011.27 (AOAC)
[Tier II]
~	[ELISA] Adapted from
Toxicon (2009) 54: 313-
320 [Tier II] and (water
samples) Harmful Algae
(2016) 56: 77-90 [Tier I]
Confirmatorv:
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
NOTE: Use amber alass
or amber PETG
containers (or protect
from light)
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
NOTE: For treated water,
add 100-1,000 mg/L
sodium thiosulfate or 100
mg/L ascorbic acid
NOTE: For untreated
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, liquid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
• [HILIC MS-MS] Adapted
from Journal of
Chromatography A (2015)
1387: 1-12 [Tier II]
freshwater samples to be
analyzed using ELISA
kits, 10X concentrated
diluent is added to the
sample container prior to
or immediately following
sample collection.
Therefore, coordinate
with receiving
laboratory(ies) prior to
sample collection.
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
At least 2 sterile,
synthetic, and
moistened wipes or
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
50 -100 ml_
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container - amber glass or
amber PETG (or protect
from light)
A minimum of 100
mL
Shiga and Shiga-like
Toxins
Presumptive:
~	[ELISA] Adapted from
Austin Immunology (2016)
1(2): 1007:1-7
[Tier I/Tier II]
Confirmatorv:
~	[LC-MS-MS] Adapted
from Analytical Chemistry
(2014) 86: 4698-4706
[Tier II]
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.® Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
~	Avoid freeze-thaw
cycles during transport.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution..
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, liquid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes or
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
SAM Companion - Sample Collection Information Document
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September 2017

-------
Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Staphylococcal
enterotoxins
(SEA, SEB, SEC, SED,
SEE)
Presumptive:
~	[ELFA] 2007.06 (AOAC)
[Tier II]
~	[ECL] Adapted from
Journal of AOAC
International (2014)
97(3): 862-867 [Tier III]
Confirmatorv:
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~	Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
~	Avoid freeze-thaw
cycles during transport.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
~ [ELISA] Adapted from
Letters in Applied
Microbiology (2011)
52: 468-474 [Tier II]
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes or
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
T-2 Mycotoxin
(T-2, HT-2)
Presumptive:
~ [ELISA] Adapted from
Journal of Food Protection
(2005) 68(6): 1294-1301
[Tier II]
Confirmatorv:
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
ImDinaer: Transfer
contents into sterile leak
proof container for
shipping.
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
NOTE: For treated water.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
Aircraft: Cargo only
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
~ [LC-MS] Adapted from
Rapid Communications in
Mass Spectrometry (2006)
20(9): 1422-1428 [Tier II]
add 8 mg sodium
thiosulfate and 6.4 mg
sodium omadine /100-
mL sample
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes or
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
SAM Companion - Sample Collection Information Document
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September 2017

-------
Sample Collection Information Document - Attachment C
September 2017
Analyte(s)
Selected Analytical
Methods - SAM 2017*
Sample Type
Sampling Device /
Medium
Sample Container
Size111
Preservation
Holding Time
Packaging
Shipping Label'2'
Tetrodotoxin
Presumptive:
~ [Receptor binding assay]
Method 2011.27 (AOAC)
[Tier II]
Confirmatorv:
Aerosol
(filter/cassette, liquid
impinger)'3'
Filter: Sterile MCE or
PTFE filter.(3) Place the
filter in a sterile leak proof
container.
See Footnote (4)
~ Immediately place on
ice (e.g., ice packs,
secure double-bagged
ice). Target temperature
<10°C.
Minimize transport
and storage time. If
feasible, analyze or
extract immediately
upon receipt at the
laboratory.
Seal container with tape or
film and decontaminate the
exterior of the container with
bleach wipes or
decontamination solution.
Place in a cooler and package
the samples outside the
contaminated area as
described in Footnotes (5) and
(6).
Belongs to Packing Group I
See Footnote (2) for
environmental samples.
For neat materials:
Label outer package with the
proper shipping name:
"Toxins, extracted from living
sources, solid, n.o.s." AND
~	UN# 2811 (inhalation
hazard),
~	UN# 3172 (liquid hazard), or
~	UN# 3462 (solid hazard)
~ [LC-MS-MS] Adapted
from Toxicon (2016)
119: 64-71 [Tier II]
contents into sterile leak
proof container for
shipping.
Particulate
(swabs, wipes, dust
socks)
Sterile leak proof
container
At least 2 sterile,
synthetic, and
moistened wipes or
swabs, or dust
socks
Solid
(soil, powder)
Sterile leak proof
container
50 -100 mL
Water
(surface water, waste
water, drinking
water)
Sterile leak proof
container
100 mL
Footnotes:
* Methods listed in this column can be located using the SAM website (https://www.epa.aov/homeland-securitv-research/selected-analvtical-methods-environmental-remediation-and-recoven/-sarTl. Full citations for references not cited and/or
accessed through this document or its website are provided in Section 7.0. Analytical technologies and methods addressing biotoxins continue to be developed and improved; the contact information on this website should be used for
updates regarding analytical procedures.
(1)	Sample sizes are provided for guidance, and may vary depending on the specific contamination incident, data quality objectives and requirements, and laboratory needs. If requested by the laboratory, additional sample(s) must be
collected for analyses using multiple methods, or for laboratory quality control analyses (e.g., duplicates, matrix spikes). It is also recommended that additional sample(s) be collected in cases where low concentrations are expected or in the
case of an anticipated need for reanalysis due to sample spillage or unforseen analytical difficulties.
(2)	The exterior of the package must be labeled with the proper shipping name and the UN Number (49 CFR 172.301). For packages meeting the small quantity exception (49 CFR 173.153), label the exterior of the package as follows: "This
package conforms to 49 CFR 173.4." No other hazard labeling is required. Packaging must meet the minimum standards as described in 49 CFR 173.4. Environmental samples meet the small quantities exception for Division 6.1 (poisonous)
materials if the maximum quantity of material per inner receptacle or article is limited to—(i) Thirty (30) mL (1 ounce) for authorized liquids, other than Division 6.1, Packing Group I, Flazard Zone A or B materials; (ii) Thirty (30) g (1 ounce) for
authorized solid materials; (iii) One (1) g (0.04 ounce) for authorized materials meeting the definition of a Division 6.1, Packing Group I, Flazard Zone A or B material. Environmental samples sufficiently diluted so as to no longer meet the
standards of a poisonous material (49 CFR 173.132, Class 6, Division 6.1 - Definitions) do not require hazard labeling. For packages using dry ice to maintain temperature preservation requirements, attach a dry ice label to the exterior of the
packaging, inform the shipper of the weight of the dry ice, and the name and address of the shipper and recipient.
(3)	Information regarding the types of filters used for collection of aerosol samples to be analyzed for toxins is limited. Sample collectors also should consult the Sample Collection Plan (SCP), Health and Safety Plan (FIASP) and/or analytical
laboratory to determine the appropriate air collection filter(s).
(4)	Volumes of collected air samples are dependent on the concentration of the toxin and the collection device used. Sample collectors should consult the incident-specific Sample Collection Plan (SCP), Health and Safety Plan (FIASP) and/or
analytical laboratory for appropriate volumes.
(5)	Sample transport containers are packed outside the contaminated area. Samples must be packed in a manner that protects the integrity of the sample containers and provides temperature conditions required for sample preservation.
Samples should be surrounded by shock- and enough water-absorbent packing material to absorb sample contents. If required for preservation, samples should be surrounded by ice or dry ice in a cooler to ensure sample temperatures do
not exceed temperature requirements. If dry ice is used, the outer packaging must be appropriately labeled (Footnote (3). Ice should be placed in separate plastic bags or cold packs should be used to avoid leakage, and the bags placed
around, among, and on top of the secondary sample containers. Further guidance can be obtained from 49 CFR 173.199 http://edocket.access.apo.aov/cfr 2002/octatr/pdf/49cfr173.199.pdft and 42 CFR 72 and 73
(http://oig.hhs,go v/authorities/docs/05/032905FRselecta gents, pdfl.
(6)	Flazardous substances belonging to Class 6, Division 6.1 are packaged according to Packing Groups. Specifications for the non-bulk packaging for Packing Groups I, II, and III are found at 49 CFR 173.201 - 173.203 for liquids, and at
173.211 - 173.213 for solids. For samples meeting the small quantities exception, packaging must meet the minimum standards as described in 49 CFR 173.4. Sample collectors also should consult the incident-specific SCP for instructions
regarding shipping labels.
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&EPA
United States
Environmental Protection
Agency
PRESORTED STANDARD
POSTAGE & FEES PAID
EPA
PERMIT NO. G-35
Office of Research and Development
Homeland Security Research Program
Cincinnati, OH 45268

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