FACT SHEET ON A DRINKING WATER CHEMICAL CONTAMINANT GENERAL INFORMATION Synonyms: • Tradenames: Aatrex; Aatrem; Atranex; Atratol; Atred; Aktikon; Crisatrina; Crisazine; Cyazin; Farmco Afrazine; G riff ex: Shell Afrazine Herbicide: Vecfal SC: Gesapnm; Primaze Primafol A • Component of: Bicep, Bullet, Extrazine, lanar Marksman, Prozine, and Sutazine Chemical Description: • An herbicide which is a member of the chemical family of friazmes Properties: • Colorless crystalline solid af room temperature • tow vapor pressure » Slightly soluble in water Production and Use: • Used chsefly as an herbicide to control grasses and broadleaf weeds in numerous crops; also used in industrial (reforestation), and home and garden (turf and ornamentals) settings to control perennial weeds and grasses • Used primarily on corn and sorghum crops, generally applied early in the growing season • Most widely used herbicide in the U.S. ENVIRONMENTAL PROFILE Occurrence: • Reported to occur in both ground and surface waters • Results of the EPA's 1990 National Pesticide Survey (NPS) indicate that atrazine is seldom present above the MCI of 0.003 mg/l in both rural drinking water wells and Community Water System (CWS) wells nationwide Releases: • Enters surface water as a result of runoff from treated fields, and enters ground water by teaching of treated croo soils » Mav enter ground water from direct entry mto a well through accidental chemical spills or improper storage near a well Environmental Fate: • Moderately persistent in soils: degrades by photolysis, and microbial, cnemtcal. and '?liat degradation processes • Stable in neutral, slightly acidic, or slightly basic media; hydrolyzed rapidly in acdic or Peso media • Soil Mobility: * High: sand, fine sandy loam, silt loam, loam * Intermediate: sand, silty clay loam, sen ay loam * Low to Intermediate: clay loam • Persistent in water: relatively staple under environmental pH conditions; concentrations are reduced by dilution, transport, ana metabolism by aquatic plants, algae, and bacteria; will adsorb to sediment • tow potential for bioaccumutafion, but having an ecological magnification of 11 times »n fish HEALTH EFFECTS Humans: • No adequate studies available on the health risks to humans Experimental Animal*: • Short-term, high-dose oral exposure s'.ses showed adverse effects upon the hear lungs, liver, kidney, spleen, adrenal glands, and c-a - observed effects include congestion of "~e heart, lungs, and kidney, hypotension antidiuresis, muscle spasms, anorexia, ana degeneration of the adrenal glands; a so a dermal irritant • Young animals are more sensitive to atrazsne than adults • Long-term, high-dose oral exposure studies showed such effects as anorexia, fluctuates . in heart, liver, and kidney weights, carccc degeneration and thrombosis, degeneration of the retina, altered blood charocter-sf-cs stiffness of the rear limbs (degeneration c' -~e rectus femoris muscle), and mammary gora tumors • No fetotoxic or teratogenic effects, bu? c a ~ses reduced fetal weights and delays m s>ee-o development • inconclusive studies on mutagenic pete-'-* 3: and carcinogenicity of atrazine • Causes mammary gland cancer in Seas-® Dawley rats ------- REGULATORY PROFILE Heotth Advitorist: Existing Standards: •Clean Air Act (CAA): Not regulated •Clean Water Act (CWA): No criteria established •Resource Conservation and Recovery Act (RCRA): Not regulated ~Superfund (CERCLA): ~Not regulated •SARA; (Mot listed •Federal Insecticide, Fungicide, and Rodenttclde Act (FIFRA): Registered •Toxic Substances Control Act (T5CA): Not regulated HEALTH INFORMATION Maximum Contaminant Level Goals (MCLG): • Non-enforceable levels based solely on an evaluation of possible hearth risks and exposure, and taking into consideration a margin for public safety • Set at 0.003 mg/L to protect against damage to the Heart, mammary glands and repro- ductive effects MCLG for Atrazlne 3 §,003 mg/l {effective July Iff2) Maximum Contaminant Levels (MCL): • Legally enforceable levels for contaminants in public drinking wafer supplies • Based on health risks associated with the contaminants, analytical methods for their assay, and water treatment feasibility and practicality aspects • Exceedance of the MCI in drinking water may result in adverse effects which will depend upon the contaminant concentration in water, amount of water/contaminant ingested, length of exposure, and other biological parameters MCL for Atrazine = 0.003 mg/l (effective July 1992) EPA Health Advisories (HA): • Short-term HAs: Provide acceptacle concentrations of contaminants in water tor up to 10 day exposures, primarily to evaluate the public health risk resulting from an accidental spill or an emergency contamination situation • longer-term HAs: Provide guidance for persistent water contamination situations to cover a oeriod of up to ? years • Lifetime HAs; Derived in the same way as an MCLG Short-term HA for a child = 0 1 mg L Longer-term HA for a child = 0.05 mg I Longer-term HA for an adult = 0.03 mg L Lifetime HA = 0.003 mg I ANALYTICAL METHODS • Microextraction and Gas Chromatography EPA Method 505 • Gas Chromatography with a Nitrogen- Phosphorous Defector EPA Method 507 • Liquid-Solid Extraction and Capillary Column Gas Chromafograpby/Mass Spectrometry EPA Method 525 WATER TREATMENT Permanent Treatment: • Best Available Technology (BAT): • Granular Activated Carbon SHORT-TERM HAZARD ELIMINATION » If the drinking water standards are exceeded, install SAT or use an alternative drinmng water supply such as bottled water ADDITIONAL HELP • State of county health officials can indicate a certified laboratory for testing • Experts in the state Department of Environmental Protection or Natural Resources may also be of help • The EPA has toll-free numbers for further information on drinking water quality, treatment technologies, for obtaining Health Advisories, and for other regulatory information • EPA Hotlines are available Monday through Friday •Safe Drinking Water 800-426-4791 •National Pesticides: 800-858-7378 •Superfund/RCRA: 800-424-9346 • For information on the Clean Water Act. call (202) 260-7301 • For information on the Toxic Substances Control Act, call (202) 554-1404 • for information on the Clean Air Act, call (919) 541-2777 ------- |