.v^1L0 STIik FACT SHEET ON A DRINKING WATER CHEMICAL CONTAMINANT GENERAL INFORMATION Synonyms: • 1-Chloro-2.3-£poxypropane. 3-Chloro-l ,2- Sooxypfopane; (Chloromethyl) Oxirane; 2- (Chloromefhyl) Oxirane; Chloropropylene oxide Chemical Description: • Volatile synthetic organic chemical Properties: • Colorless liquid with a pungent, garlic, sweet, chloroform-like odor • Slightly heavier than water • Moderately soluble in water • High vapor pressure Production and Use: • Used in the manufacture of glycerol and expoxy resins, pharmaceuticals, agricultural chemicals, plasticizers, dyes, aahesives, polymers, stabilizers, and paper-sizing agents • Polymers made from epichlorohydrin are sometimes usen as a flocculant to remove particulate mauer in the treatment of water supplies ENVIRONMENTAL PROFILE Occurence: • Not expected to occur in drinking water at levels to cause detrimental health effects Releases: » Principle source of epichlorohydrin in drinking wafer is impurities in wafer treatment chemicals and surfaces in contact with drinking water • Other releases to water are the result of industrial effluents, disposal of solid wastes, and occidental chemical spills • The primary source .of releases to the environment occur to air from manufacturing processes and its use as an intermediate Environmental Fate: • Considered to be not persistent: • will volatilize fairly rapidly to the atmosphere from surface water and soil (major removal mechanism) • expected to be mobile in soil {low potential for adsorbtion to soil or sediment), with mgh potential to migrate to ground water • expected to biodegrade in soil and water » will be removed from both surface and ground wafer by hydrolysis • low potential for bioaccumutation HEALTH EFFECTS Humans; • Cases of acute exposure indicate that dermal exposure produces predominantly local irritation effects, and inhalation exposure produces detrimental effects upon functions of the liver and kidneys • Chronic exposure has been associated with chromosome abberations and detrimental effects upon the blood (blood dyscrasta) Experimental Animals: » High acute toxicity following oral, dermal, or inhalation exposure, producing similar symptoms in each case • acute exposure has the greatest effect upon the central nervous system (CNS). with death being due to depression of the respiratory center, and causes detrimental effects upon the functions of the lungs, liver, and kidneys • Chronic oral exposure causes stomach cancer, and inhalation exposure ccuses respiratory tract cancer and eye and skin irritation • Causes sterility in male rats, but is reversible once exposure has ceased • Equivocal evidence of maternal toxicity and fefotoxtcity • High mutagenic and carcinogenic potential ------- REGULATORY PROFILE Existing Standards: •Clean Air Act (CAA): Reguiated •Clean Water Act CWA): No criteria established 'Resource Conservation and Recovery Act (RCRA); Hazardous waste •Superfund (CERCLA): •Hazardous substance •SARA: Toxic chemical •Federal Insecticide. Fungicide, and Rodenticide Act (FIFRA): Registered •Toxic Substancet Control Act (ISCA): Regulated HEALTH INFORMATION Treatment Technique Requirements: • Because no standardized analytical methods are available for epichlorohydrin at low levels in drinking water, EPA proposed a treatment technique rather than an MCLG/MCL in order to reduce the chance of exposure to epichlorohydrin • EPA proposed to limit the allowable levels of epichlorohydrin monomers in products used during water treatment, storage, and distribution • Under the proposed rule, a water system using a product containing epichlorohydrin must certify annually in writing to the State that the combination of the amount of residual monomer in the polymer and the dosage rate does not cause the concentration in finished wafer to exceed the specified level: 0.01 percent residual epichlorohydrin concentration dosed at 20.0 ppm (effective July 1992) • Exceedonc© of the specified level in drinking water may result in adverse effects which will depend upon the contaminant concentration in wafer, amount c; water/contaminant ingested, length of exposure, and other biological parameters IPA Hearth Advisories (HA): • Short-term HAs: Provide acceptable concentrations of contaminants in wafer for up to 10 day exposures, primarily to evaluate the public health risk resulting from an accidental spill or an emergency contamination situation • Longer-term HAs: Provice gu:aa-ce t* persistent water contamination situations *o cover a period of up to 7 years • Lifetime HA*: Derived in the same way as an MCIG Health Advisories: Short-term HA for a child = 0.1 mg, I Longer-term HA for a child = 0.07 mg L Longer-term HA for an adult = 0.07 mg L Lifetime HA = Not recommended ANALYTICAL METHODS • No standardized analytical methods are available for epichlorohydrin at low levels in drinking water WATER TREATMENT • Since a 8est Available Technology (BAT) does not exist for epichlorohydrin, EPA suggests that water systems limit the use of products containing epichlorohydrin SHORT-TERM HAZARD ELIMINATION • If the drinking water standards are exceeded, use an alternative drinking wafer supply such as bottled water ADDITIONAL HELP • State or county health officials can indicate a certified laboratory for testing • Experts in the state Department of Environmental Protection or Natural Resources may also be of help • The EPA has toll-free numbers for further information ¦ on drinking water quality, treatment technologies, for obtaining Health Advisories, and for other regulatory information • EPA Hotlines are available Monday through Friday •Safe Drinking Water 800-426-4791 • Natlonal Pesticides: 800-858-7378 •Superfund/RCRA: 800-424-9346 •' For information on the Clean Water Act, call (202) 260-7301 • For information on the Toxic' Substances Control Act, caH (202) 564-1404 » For information on the Clean Air Act, call (919) 541-2777 ------- |