PEER REVIEW DRAFT - DO NOT CITE OR QUOTE EPA United States Environmental Protection Agency Office of Chemical Safety and Pollution Prevention Draft Risk Evaluation for 1-Bromopropane (n-Propyl Bromide) 1-BP Systematic Review Supplemental File: Data Quality Evaluation of Ecological Hazard Studies CASRN: 106-94-5 July, 2019, DRAFT ------- Table of Contents HERO Data Type Reference 1 ID 32171 Acute (0-96 hour); Aquatic; Fish Geiger, D. L.,Call, D. J.,Bro°ke, L. T.. 1988. Acute toxicities of organic chem- 1 icals to fathead minnows (Pimephales promelas): Volume IV. ------- Study Citation: Geiger, D. L.,Call, D. J.,Brooke, L. T.. 1988. Acute toxicities of organic chemicals to fathead minnows (Pimephales promelas): Volume IV. Data Type: Acute (0-96 hour); Aquatic; Fish Hero ID: 32171 Domain Metric Rating^ MWF* Score Comments^ Domain 1: Test Substance Metric 1: Test Substance Identity High X 2 2 Metric 2: Test Substance Source High X 1 1 Metric 3: Test Substance Purity High X 1 1 Domain 2: Test Design Metric 4: Negative Controls Low x 2 6 Metric 5: Negative Control Response High x 1 1 Metric 6: Randomized Allocation High x 1 1 Negative control was used, but the specific condi- tions were not reported. No mortalities reported in the negative control, so this is not expected to im- pact the outcome of this study. No mortalities reported in the negative control. Study Authors reported that, "at the start of a test, individuals were removed from the common pool of fish with a net and distributed at random among the exposure chambers." Domain 3: Exposure Characterization Metric 7: Experimental System/Test Media Prepara- Medium x 2 tion Metric 8: Consistency of Exposure Administration High x 1 1 Metric 9: Measurement of Test Substance Concentra- High x 1 1 tion Metric 10: Exposure Duration and Frequency High x 2 2 Metric 11: Number of Exposure Groups/Spacing of Ex- High x 1 1 posure Levels The experimental system and/or test media prepara- tion methods wereadequately reported but did not completely account for physical-chemicalproperties in that the volatilization was reported for the test material. However, the identified limitations are un- likely to have a substantial impact on results, as the authors analytically-verified the exposure concentra- tions during the experiment. Flow-through system used Gas-Liquid Chromatography used to analyze test concentrations. 96-Hour exposure duration reported by the study authors Continued on next page ------- . continued from previous page Study Citation: Geiger, D. L.,Call, D. J.,Brooke, L. T.. 1988. Acute toxicities of organic chemicals to fathead minnows (Pimephales promelas): Volume IV. Data Type: Acute (0-96 hour); Aquatic; Fish Hero ID: 32171 Domain Metric Rating^ MWF* Score Comments^ Metric 12: Testing at or Below Solubility Limit High X 1 1 Domain 4: Test Organism Metric 13: Test Organism Characteristics High X 2 2 Use of fathead minnows as a test species is consistent with EPA guideline-recommended practices for con- ducting acute toxicity testing with fish. The intro- duction of the study report describes specific details of the test organisms including age and life-stage as well as a description of the species. The source of the test organisms was described by the authors as, "Fathead minnows used in the tests were cultured at the U.S. EPA Environmental Research Laboratory- Duluth and the University of Wisconsin- Superior campus." Metric 14: Acclimitization and Pretreatment Conditions High X 1 1 Metric 15: Number of Organisms and Replicates per High X 1 1 Group Metric 16: Adequacy of Test Conditions High X 1 1 Domain 5: Outcome Assessment Metric 17: Outcome Assessment Methodology High x 2 2 Metric 18: Consistency of Outcome Assessment High x 1 1 Domain 6: Confounding / Variable Control Metric 19: Confounding Variables in Test Design and High x 2 2 Procedures Metric 20: Outcomes Unrelated to Exposure High x 1 1 Domain 7: Data Presentation and Analysis Metric 21: Statistical Methods High X 1 1 The estimated LC50 and EC50 with correspond- ing 95 percent confidence intervals were calculated using the corrected average of the analyzed tank concentrations and the Trimmed Spearman-Karber Method. Metric 22: Reporting of Data High x 2 2 Continued on next page . . . ------- . continued from previous page Study Citation: Geiger, D. L.,Call, D. J.,Brooke, L. T.. 1988. Acute toxicities of organic chemicals to fathead minnows (Pimephales promelas): Volume IV. Data Type: Acute (0-96 hour); Aquatic; Fish Hero ID: 32171 Domain Metric Rating^ MWF* Score Comments^ Metric 23: Explanation of Unexpected Outcomes High x 1 Overall Quality Determination"'" High 1.2 Extracted Yes * MWF = Metric Weighting Factor t High = 1; Medium = 2; Low = 3; Unacceptable = 4; N/A has no value. * The overall rating is calculated as necessary. EPA may not always provide a comment for a metric that has been categorized as High. ( 4 if any metric is Unacceptable Overall rating = I V. (Metric Score,- x MWF,') I V .. '3 J]. (Metric Score; x MWF;) / J] . MWFj (round to the nearest tenth) otherwise where High: > 1 to < 1.7; Medium: > 1.7 to < 2.3; Low: > 2.3 to < 3. If the reviewer determines that the overall rating needs adjustment, the original rating is crossed out and an arrow points to the new rating, ft Metrics that are rated 'High' met the criteria for high confidence as expected for this type of study, and may not require additional comments. ------- |