EPA/600/R-19/102 | September 2019 | www.epa.gov/research
Investigation of a Sustainable
Approach to In-situ Remediation
of Arsenic Impacted Groundwater
APPENDICES
United States
Environmental Protection
Agency
-------
Appendix A
Metals by EPA 6000/7000 Series Methods and
Sequential Extraction Results for ASB-1 and ASB-2
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
13 July 2016
Joe Loeper
Philadelphia District
Wanamaker Building, 100 Penn Square East
Philadelphia, PA 19107-3390
RE: Vineland
Enclosed are the results of analyses for samples received by the laboratory on 07-Apr-2016. The samples
associated with this report will be held for 90 days from the date of this report. The raw data associated with this
report will be held for 5 years from the date of this report. If you need us to hold onto the samples or the data
longer then these specified times, you will need to notify us in writing at least 30 days before the expiration dates.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Jenifer Milam For Dale Rosado, Ph. D.
Chemist
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project:
Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager:
Joe Loeper
13-Jul-2016
WORK ORDER SUMMARY
Sample ID
Laboratory ID
Matrix
Date Sampled
Date of Work Order
ASB-2 26-27
6040703-01
Soil/Sediment
05-Apr-2016
07-Apr-2016
ASB-2 30-31
6040703-02
Soil/Sediment
05-Apr-2016
07-Apr-2016
ASB-2 31-32
6040703-03
Soil/Sediment
05-Apr-2016
07-Apr-2016
ASB-1 26-27
6040703-04
Soil/Sediment
05-Apr-2016
07-Apr-2016
ASB-1 27-28
6040703-05
Soil/Sediment
05-Apr-2016
07-Apr-2016
ASB-1 28-29
6040703-06
Soil/Sediment
05-Apr-2016
07-Apr-2016
ASB-1 29-30
6040703-07
Soil/Sediment
05-Apr-2016
07-Apr-2016
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 1 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Case Narrative
No issues were experienced during the analysis of Work Order 6040703 unless specified below.
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 2 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project:
Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager:
Joe Loeper
13-Jul-2016
Notes and Definitions
U Analyte included in the analysis, but not detected
RPD-06 RPD exceeds acceptance limit.
RPD-01 Analyses are not controlled on RPD values from sample concentrations less than the reporting limit.
QM-11 The spike recovery was outside of QC acceptance limits for the MS and/or MSD due to inherent analyte concentration greater than the
spike concentration. The QC batch was accepted based on LCS and/or LCSD recoveries within the acceptance limits.
J Detected but below the Reporting Limit; therefore, result is an estimated concentration.
B Analyte is found in the associated blank as well as in the sample.
DET Analyte DETECTED
ND Analyte NOT DETECTED at or above the reporting limit
NR Not Reported
dry Sample results reported on a dry weight basis
RPD Relative Percent Difference
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 3 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 26-27
6040703-01 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals bv EPA 6000/7000 Series Methods
Aluminum
2240
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Antimony
ND
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Arsenic
94.7
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Barium
4.10
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Beryllium
ND
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Boron
7.59
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cadmium
0.612
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Calcium
79.9
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Chromium
5.42
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cobalt
ND
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Copper
2.89
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
B
Iron
22000
1.58
7.91
mg/kg
18-Apr-2016
20-Apr-2016
SW 846/6010
Lead
3.10
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Lithium
ND
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Magnesium
24.0
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Manganese
4.83
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Nickel
0.416
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Phosphorus
85.4
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Potassium
82.1
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Selenium
ND
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Silver
ND
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Sodium
ND
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Strontium
0.996
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Sulfur
28.5
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Thallium
0.817
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Tin
1.32
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Titanium
15.4
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Vanadium
26.0
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Zinc
4.06
0.396
1.98
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 4 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 26-27
6040703-01 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Carbonate
Aluminum
8.38
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Iron
10.9
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
0.665
0.0395
0.197
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Exchaneeable
Aluminum
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Lead
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
9.87
49.3
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Oxide
Aluminum
163
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
817
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
6.42
0.395
1.97
mg/kg
27-May-2016
31-May-2016
SW 846/6020
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 5 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 26-27
6040703-01 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Residual
Aluminum
463
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
20.1
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
4250
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
3.05
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
18.0
0.197
0.987
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Soluble
Aluminum
17.5
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
34.6
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
8.34
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic-75 [2]
ND
0.197
0.987
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Sulfide / Organic
Aluminum
35.7
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
35.2
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.395
1.97
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 6 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 30-31
6040703-02 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals bv EPA 6000/7000 Series Methods
Aluminum
696
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Antimony
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Arsenic
88.3
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Barium
2.36
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Beryllium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Boron
3.97
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cadmium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Calcium
50.0
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Chromium
1.68
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Cobalt
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Copper
2.42
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
B
Iron
11800
1.59
7.96
mg/kg
18-Apr-2016
20-Apr-2016
SW 846/6010
Lead
0.434
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Lithium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Magnesium
10.3
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Manganese
2.32
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
NJickel
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Phosphorus
31.4
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Potassium
5.83
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Selenium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Silver
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Sodium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Strontium
0.703
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Sulfur
16.4
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Thallium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Tin
0.600
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Titanium
15.7
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Vanadium
3.57
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Zinc
1.70
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 7 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 30-31
6040703-02 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Carbonate
Aluminum
7.25
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Iron
7.46
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
0.636
0.0391
0.196
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Exchaneeable
Aluminum
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Lead
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
9.78
48.9
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Oxide
Aluminum
60.3
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
8.83
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
412
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
6.15
0.391
1.96
mg/kg
27-May-2016
31-May-2016
SW 846/6020
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 8 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 30-31
6040703-02 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Residual
Aluminum
119
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
14.9
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
2090
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
3.50
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
18.5
0.196
0.978
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Soluble
Aluminum
11.6
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
35.9
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.196
0.978
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Sulfide / Organic
Aluminum
12.5
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
30.2
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.391
1.96
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 9 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 31-32
6040703-03 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals bv EPA 6000/7000 Series Methods
Aluminum
536
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Antimony
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Arsenic
83.9
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Barium
3.44
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Beryllium
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Boron
2.82
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cadmium
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Calcium
57.1
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Chromium
1.55
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Cobalt
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Copper
2.89
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
B
Iron
10100
1.53
7.63
mg/kg
18-Apr-2016
20-Apr-2016
SW 846/6010
Lead
2.07
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Lithium
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Magnesium
8.16
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Manganese
1.85
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
NJickel
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Phosphorus
27.4
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Potassium
5.59
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Selenium
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Silver
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Sodium
ND
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Strontium
2.18
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Sulfur
16.1
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Thallium
0.868
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Tin
0.564
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Titanium
12.3
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Vanadium
2.84
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Zinc
1.21
0.382
1.91
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 10 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 31-32
6040703-03 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Carbonate
Aluminum
8.46
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Iron
11.2
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
3.66
0.0393
0.197
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Exchaneeable
Aluminum
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Lead
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
9.83
49.1
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Oxide
Aluminum
61.2
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
9.57
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
427
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
23.2
0.393
1.97
mg/kg
27-May-2016
31-May-2016
SW 846/6020
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 11 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-2 31-32
6040703-03 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Residual
Aluminum
102
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
14.4
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
1850
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
2.51
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
14.1
0.197
0.983
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Soluble
Aluminum
22.6
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
2.41
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
78.8
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
1.70
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
1.40
0.197
0.983
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Sulfide / Organic
Aluminum
13.1
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
38.7
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.393
1.97
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 12 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 26-27
6040703-04 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals bv EPA 6000/7000 Series Methods
Aluminum
3120
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Antimony
ND
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Arsenic
170
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Barium
7.23
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Beryllium
ND
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Boron
5.44
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cadmium
0.625
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Calcium
89.2
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Chromium
8.20
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cobalt
0.394
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Copper
1.15
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J, B
Iron
22600
1.52
7.59
mg/kg
18-Apr-2016
20-Apr-2016
SW 846/6010
Lead
2.01
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Lithium
0.809
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Magnesium
97.8
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Manganese
7.35
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Nickel
0.772
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Phosphorus
111
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Potassium
137
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Selenium
ND
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Silver
ND
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Sodium
ND
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Strontium
1.70
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Sulfur
20.4
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Thallium
1.56
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Tin
ND
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Titanium
59.2
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Vanadium
7.04
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Zinc
7.05
0.379
1.90
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 13 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 26-27
6040703-04 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Carbonate
Aluminum
8.65
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
4.85
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
7.95
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
7.02
0.0393
0.196
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Exchaneeable
Aluminum
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Lead
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
9.81
49.1
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Oxide
Aluminum
218
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
21.7
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
1150
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
44.8
0.393
1.96
mg/kg
27-May-2016
31-May-2016
SW 846/6020
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 14 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 26-27
6040703-04 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Residual
Aluminum
658
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
35.8
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
4530
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Manganese
1.58
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Sulfur
3.86
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
33.4
0.196
0.981
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Soluble
Aluminum
52.3
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
3.50
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
54.4
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
4.74
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
2.92
0.196
0.981
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Sulfide / Organic
Aluminum
69.8
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
44.1
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.393
1.96
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 15 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 27-28
6040703-05 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals bv EPA 6000/7000 Series Methods
Aluminum
2410
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Antimony
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Arsenic
519
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Barium
2.16
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Beryllium
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Boron
10.3
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cadmium
1.35
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Calcium
44.1
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Chromium
12.8
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cobalt
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Copper
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Iron
50200
1.57
7.86
mg/kg
18-Apr-2016
20-Apr-2016
SW 846/6010
Lead
4.85
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Lithium
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Magnesium
7.44
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Manganese
16.0
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
NJickel
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Phosphorus
173
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Potassium
48.3
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Selenium
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Silver
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Sodium
ND
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Strontium
0.856
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Sulfur
40.1
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Thallium
2.28
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Tin
2.40
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Titanium
33.7
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Vanadium
4.21
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Zinc
13.6
0.393
1.97
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 16 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 27-28
6040703-05 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Carbonate
Aluminum
7.27
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
14.7
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
20.9
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
19.4
0.0400
0.200
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Exchaneeable
Aluminum
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Lead
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
10.6
9.99
50.0
mg/kg
27-May-2016
31-May-2016
SW 846/6020
J
Metals Seauential Extractions Oxide
Aluminum
172
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
50.4
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
923
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
104
0.400
2.00
mg/kg
27-May-2016
31-May-2016
SW 846/6020
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 17 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 27-28
6040703-05 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Residual
Aluminum
343
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
69.5
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
6780
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Manganese
2.43
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Sulfur
5.56
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic-75 [2]
62.9
0.200
0.999
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Soluble
Aluminum
4.37
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
8.93
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
25.9
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
2.51
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
8.18
0.200
0.999
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Sulfide / Organic
Aluminum
29.7
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
49.9
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.400
2.00
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 18 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 28-29
6040703-06 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals bv EPA 6000/7000 Series Methods
Aluminum
4110
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Antimony
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Arsenic
567
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Barium
7.00
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Beryllium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Boron
7.56
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cadmium
1.23
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Calcium
51.0
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Chromium
32.1
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cobalt
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Copper
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Iron
45300
1.59
7.96
mg/kg
18-Apr-2016
20-Apr-2016
SW 846/6010
Lead
3.03
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Lithium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Magnesium
32.7
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Manganese
11.7
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
NJickel
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Phosphorus
174
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Potassium
331
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Selenium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Silver
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Sodium
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Strontium
2.30
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Sulfur
41.5
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Thallium
2.76
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Tin
ND
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Titanium
125
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Vanadium
37.9
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Zinc
10.2
0.398
1.99
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 19 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 28-29
6040703-06 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Carbonate
Aluminum
10.7
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
18.0
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
10.8
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
24.3
0.0393
0.197
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Exchaneeable
Aluminum
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Lead
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
9.83
49.1
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Oxide
Aluminum
244
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
46.2
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
1270
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
92.9
0.393
1.97
mg/kg
27-May-2016
31-May-2016
SW 846/6020
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 20 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 28-29
6040703-06 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Residual
Aluminum
887
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
122
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
8750
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Manganese
2.78
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Sulfur
6.88
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic-75 [2]
108
0.197
0.983
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Soluble
Aluminum
7.14
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
10.3
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
5.58
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Lead
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
10.0
0.197
0.983
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Sulfide / Organic
Aluminum
75.0
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
49.2
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Manganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.393
1.97
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 21 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 29-30
6040703-07 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals bv EPA 6000/7000 Series Methods
Aluminum
1220
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Antimony
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
U
Arsenic
229
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Barium
1.85
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Beryllium
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Boron
3.50
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cadmium
0.554
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Calcium
71.7
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Chromium
5.78
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Cobalt
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Copper
0.531
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J, B
Iron
21600
1.54
7.70
mg/kg
18-Apr-2016
20-Apr-2016
SW 846/6010
Lead
1.47
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Lithium
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Magnesium
6.28
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Manganese
3.31
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
NJickel
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Phosphorus
107
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Potassium
26.7
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Selenium
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Silver
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Sodium
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Strontium
0.529
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Sulfur
20.0
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Thallium
1.36
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
J
Tin
ND
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
u
Titanium
51.3
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Vanadium
6.35
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
Zinc
4.01
0.385
1.92
mg/kg
18-Apr-2016
18-Apr-2016
SW 846/6010
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 22 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 29-30
6040703-07 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Carbonate
Aluminum
9.10
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic
10.2
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
9.78
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
13.7
0.0398
0.199
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Exchaneeable
Aluminum
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Lead
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
80.0
400
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
9.95
49.8
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
Metals Seauential Extractions Oxide
Aluminum
85.9
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
33.4
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
524
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
74.9
0.398
1.99
mg/kg
27-May-2016
31-May-2016
SW 846/6020
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 23 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
ASB-1 29-30
6040703-07 (Soil/Sediment)
Detection
Reporting
Analyte
Result
Limit
Limit
Units
Prepared
Analyzed
Method
Notes
ERDC-EL-EP-C
Metals Seauential Extractions Residual
Aluminum
243
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
40.9
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Iron
4400
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Vlanganese
ND
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
U
Sulfur
5.30
0.800
4.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic-75 [2]
38.6
0.199
0.995
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Soluble
Aluminum
17.2
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
5.64
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Iron
24.0
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
4.95
1.60
8.00
mg/kg
09-May-2016
10-May-2016
SW 846/6010
J
Arsenic-75 [2]
5.31
0.199
0.995
mg/kg
27-May-2016
31-May-2016
SW 846/6020
Metals Seauential Extractions Sulfide / Organic
Aluminum
20.8
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Arsenic
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Iron
27.3
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
Lead
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Vlanganese
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Sulfur
ND
4.00
20.0
mg/kg
09-May-2016
10-May-2016
SW 846/6010
u
Arsenic-75 [2]
ND
0.398
1.99
mg/kg
27-May-2016
31-May-2016
SW 846/6020
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 24 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals by EPA 6000/7000 Series Methods - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike
Source
%REC
RPD
Analyte
Result Limit
Limit Units
Level
Result
%REC
Limits
RPD
Limit
Notes
Batch B604066 - Default Prep Metals
Blank (B604066-BLK1) Prepared & Analyzed: 18-Apr-2016
Aluminum
1.71
0.400
2.00
mg/kg
J
Antimony
ND
0.400
2.00
mg/kg
U
Arsenic
ND
0.400
2.00
mg/kg
U
Barium
ND
0.400
2.00
mg/kg
u
Beryllium
ND
0.400
2.00
mg/kg
u
Boron
1.58
0.400
2.00
mg/kg
J
Cadmium
ND
0.400
2.00
mg/kg
u
Calcium
0.878
0.400
2.00
mg/kg
J
Chromium
ND
0.400
2.00
mg/kg
u
Cobalt
ND
0.400
2.00
mg/kg
u
Copper
8.46
0.400
2.00
mg/kg
Iron
1.12
0.400
2.00
mg/kg
J
Lead
ND
0.400
2.00
mg/kg
u
Lithium
ND
0.400
2.00
mg/kg
u
Magnesium
ND
0.400
2.00
mg/kg
u
Manganese
ND
0.400
2.00
mg/kg
u
Nickel
ND
0.400
2.00
mg/kg
u
Phosphorus
1.35
0.400
2.00
mg/kg
J
Potassium
ND
0.400
2.00
mg/kg
u
Selenium
ND
0.400
2.00
mg/kg
u
Silver
ND
0.400
2.00
mg/kg
u
Sodium
ND
0.400
2.00
mg/kg
u
Strontium
ND
0.400
2.00
mg/kg
u
Sulfur
ND
0.400
2.00
mg/kg
u
Thallium
ND
0.400
2.00
mg/kg
u
Tin
0.592
0.400
2.00
mg/kg
J
Titanium
ND
0.400
2.00
mg/kg
u
Vanadium
ND
0.400
2.00
mg/kg
u
Zinc
ND
0.400
2.00
mg/kg
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 25 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals by EPA 6000/7000 Series Methods - Quality Control
ERDC-EL-EP-C
Analyte
Detection Reporting
Result Limit Limit Units
Spike
Level
Source %REC
Result %REC Limits
RPD
RPD
Limit
Notes
Batch B604066 - Default Prep Metals
LCS (B604066-BS1)
Prepared 6
£ Analyzed: 18-Apr-2016
Aluminum
4620
0.400
2.00
mg/kg
5000
92.3
80-120
Antimony
96.5
0.400
2.00
mg/kg
100.0
96.5
80-120
Arsenic
48.5
0.400
2.00
mg/kg
50.00
97.0
80-120
Barium
188
0.400
2.00
mg/kg
200.0
94.1
80-120
Beryllium
47.2
0.400
2.00
mg/kg
50.00
94.5
80-120
Boron
49.0
0.400
2.00
mg/kg
50.00
98.0
80-120
Cadmium
49.8
0.400
2.00
mg/kg
50.00
99.6
80-120
Calcium
4920
0.400
2.00
mg/kg
5000
98.4
80-120
Chromium
101
0.400
2.00
mg/kg
100.0
101
80-120
Cobalt
118
0.400
2.00
mg/kg
100.0
118
80-120
Copper
106
0.400
2.00
mg/kg
100.0
106
80-120
Iron
5030
0.400
2.00
mg/kg
5000
101
80-120
Lead
91.8
0.400
2.00
mg/kg
100.0
91.8
80-120
Lithium
91.6
0.400
2.00
mg/kg
100.0
91.6
80-120
Magnesium
4710
0.400
2.00
mg/kg
5000
94.3
80-120
Manganese
239
0.400
2.00
mg/kg
250.0
95.6
80-120
Nickel
90.4
0.400
2.00
mg/kg
100.0
90.4
80-120
Phosphorus
99.5
0.400
2.00
mg/kg
100.0
99.5
80-120
Potassium
4370
0.400
2.00
mg/kg
5000
87.4
80-120
Selenium
44.3
0.400
2.00
mg/kg
50.00
88.6
80-120
Silver
48.9
0.400
2.00
mg/kg
50.00
97.9
80-120
Sodium
4620
0.400
2.00
mg/kg
5000
92.3
80-120
Strontium
48.9
0.400
2.00
mg/kg
50.00
97.9
80-120
Sulfur
95.6
0.400
2.00
mg/kg
100.0
95.6
80-120
Thallium
44.5
0.400
2.00
mg/kg
50.00
89.0
80-120
Tin
50.8
0.400
2.00
mg/kg
50.00
102
80-120
Titanium
51.9
0.400
2.00
mg/kg
50.00
104
80-120
Vanadium
103
0.400
2.00
mg/kg
100.0
103
80-120
Zinc
183
0.400
2.00
mg/kg
200.0
91.5
80-120
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 26 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals by EPA 6000/7000 Series Methods - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike
Source
%REC
RPD
Analyte
Result Limit
Limit Units
Level
Result
%REC
Limits
RPD
Limit
Notes
Batch B604066 - Default Prep Metals
Duplicate (B604066-DUP1) Source: 6040702-10 Prepared & Analyzed: 18-Apr-2016
Aluminum
748
0.378
1.89
mg/kg
695
7.26
20
Antimony
ND
0.378
1.89
mg/kg
ND
20
U
Arsenic
9.48
0.378
1.89
mg/kg
8.62
9.51
20
Barium
2.47
0.378
1.89
mg/kg
2.34
5.05
20
Beryllium
ND
0.378
1.89
mg/kg
ND
20
U
Boron
ND
0.378
1.89
mg/kg
ND
20
U
Cadmium
ND
0.378
1.89
mg/kg
ND
20
U
Calcium
55.6
0.378
1.89
mg/kg
49.5
11.6
20
Chromium
2.39
0.378
1.89
mg/kg
2.17
9.73
20
Cobalt
ND
0.378
1.89
mg/kg
ND
20
U
Copper
4.93
0.378
1.89
mg/kg
2.12
79.6
20
RPD-06, B
Iron
2260
0.378
1.89
mg/kg
1950
14.9
20
Lead
1.05
0.378
1.89
mg/kg
1.01
3.29
20
J
Lithium
ND
0.378
1.89
mg/kg
ND
20
U
Magnesium
23.2
0.378
1.89
mg/kg
21.6
7.21
20
Manganese
2.62
0.378
1.89
mg/kg
2.49
4.87
20
Nickel
0.443
0.378
1.89
mg/kg
0.448
1.15
20
J
Phosphorus
20.8
0.378
1.89
mg/kg
19.4
7.19
20
Potassium
17.1
0.378
1.89
mg/kg
15.6
9.12
20
Selenium
ND
0.378
1.89
mg/kg
ND
20
u
Silver
ND
0.378
1.89
mg/kg
ND
20
u
Sodium
ND
0.378
1.89
mg/kg
ND
20
u
Strontium
0.780
0.378
1.89
mg/kg
0.744
4.75
20
J
Sulfur
ND
0.378
1.89
mg/kg
ND
20
u
Thallium
0.812
0.378
1.89
mg/kg
0.927
13.2
20
J
Tin
5.41
0.378
1.89
mg/kg
ND
20
Titanium
30.7
0.378
1.89
mg/kg
29.5
3.94
20
Vanadium
2.52
0.378
1.89
mg/kg
2.14
16.3
20
Zinc
1.60
0.378
1.89
mg/kg
1.05
41.3
20
RPD-01, J
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 27 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals by EPA 6000/7000 Series Methods - Quality Control
ERDC-EL-EP-C
Analyte
Detection Reporting
Result Limit Limit Units
Spike
Level
Source %REC
Result %REC Limits
RPD
RPD
Limit
Notes
Batch B604066 - Default Prep Metals
Matrix Spike (B604066-MS1)
Source: 6040702-10
Prepared 6
£ Analyzed: 18-Apr-2016
Aluminum
5730
0.394
1.97
mg/kg
4919
695
102
80-120
Antimony
39.1
0.394
1.97
mg/kg
98.39
ND
39.7
80-120
QM-11
Arsenic
56.9
0.394
1.97
mg/kg
49.19
8.62
98.2
80-120
Barium
187
0.394
1.97
mg/kg
196.8
2.34
93.9
80-120
Beryllium
45.9
0.394
1.97
mg/kg
49.19
ND
93.2
80-120
Boron
46.0
0.394
1.97
mg/kg
49.19
ND
93.4
80-120
Cadmium
47.5
0.394
1.97
mg/kg
49.19
ND
96.6
80-120
Calcium
4770
0.394
1.97
mg/kg
4919
49.5
95.9
80-120
Chromium
99.9
0.394
1.97
mg/kg
98.39
2.17
99.4
80-120
Cobalt
97.8
0.394
1.97
mg/kg
98.39
ND
99.4
80-120
Copper
97.8
0.394
1.97
mg/kg
98.39
2.12
97.3
80-120
B
Iron
7000
0.394
1.97
mg/kg
4919
1950
103
80-120
Lead
90.8
0.394
1.97
mg/kg
98.39
1.01
91.3
80-120
Lithium
89.5
0.394
1.97
mg/kg
98.39
ND
90.9
80-120
Magnesium
4600
0.394
1.97
mg/kg
4919
21.6
93.0
80-120
Manganese
235
0.394
1.97
mg/kg
246.0
2.49
94.4
80-120
Nickel
87.5
0.394
1.97
mg/kg
98.39
0.448
88.5
80-120
Phosphorus
113
0.394
1.97
mg/kg
98.39
19.4
95.4
80-120
Potassium
4310
0.394
1.97
mg/kg
4919
15.6
87.2
80-120
Selenium
41.9
0.394
1.97
mg/kg
49.19
ND
85.3
80-120
Silver
42.8
0.394
1.97
mg/kg
49.19
ND
87.0
80-120
Sodium
4500
0.394
1.97
mg/kg
4919
ND
91.5
80-120
Strontium
48.0
0.394
1.97
mg/kg
49.19
0.744
96.1
80-120
Sulfur
84.0
0.394
1.97
mg/kg
98.39
ND
85.4
80-120
Thallium
43.2
0.394
1.97
mg/kg
49.19
0.927
86.0
80-120
Tin
37.9
0.394
1.97
mg/kg
49.19
ND
77.0
80-120
QM-11
Titanium
68.0
0.394
1.97
mg/kg
49.19
29.5
78.2
80-120
QM-11
Vanadium
101
0.394
1.97
mg/kg
98.39
2.14
100
80-120
Zinc
176
0.394
1.97
mg/kg
196.8
1.05
88.7
80-120
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 28 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals Sequential Extractions Carbonate - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike Source %REC
RPD
Analyte
Result
Limit
Limit
Units
Level Result %REC Limits RPD
Limit
Notes
Batch B606014 - Default Prep Metals
Blank (B606014-BLK1)
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
ND
0.400
2.00
mg/kg
U
Arsenic
ND
0.400
2.00
mg/kg
U
[ron
ND
0.400
2.00
mg/kg
u
Lead
ND
0.400
2.00
mg/kg
u
Vlanganese
ND
0.400
2.00
mg/kg
u
Sulfur
ND
0.400
2.00
mg/kg
u
Duplicate (B606014-DUP1)
Source: 6040703-01
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
8.14
4.00
20.0
mg/kg
8.38 3.01
20
J
Arsenic
ND
4.00
20.0
mg/kg
ND
20
u
[ron
11.4
4.00
20.0
mg/kg
10.9 4.61
20
J
Lead
ND
4.00
20.0
mg/kg
ND
20
u
Vlanganese
ND
4.00
20.0
mg/kg
ND
20
u
Sulfur
ND
4.00
20.0
mg/kg
ND
20
u
Batch B606057 - Default Prep Metals
Blank (B606057-BLK1)
Prepared: 27-May-2016 Analyzed: 31-May-2016
Arsenic-75 [2]
ND
0.0400
0.200
mg/kg
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 29 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals Sequential Extractions Exchangeable - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike Source %REC RPD
Analyte
Result
Limit
Limit
Units
Level Result %REC Limits RPD Limit
Notes
Batch B606013 - Default Prep Metals
Blank (B606013-BLK1)
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
ND
80.0
400
mg/kg
U
Arsenic
ND
80.0
400
mg/kg
U
[ron
ND
80.0
400
mg/kg
u
Lead
ND
80.0
400
mg/kg
u
Vlanganese
ND
80.0
400
mg/kg
u
Sulfur
ND
80.0
400
mg/kg
u
Batch B606058 - Default Prep Metals
Blank (B606058-BLK1)
Prepared: 27-May-2016 Analyzed: 31-May-2016
Arsenic-75 [2]
ND
10.0
50.0
mg/kg
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 30 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals Sequential Extractions Oxide - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike Source %REC
RPD
Analyte
Result
Limit
Limit
Units
Level Result %REC Limits RPD
Limit
Notes
Batch B606015 - Default Prep Metals
Blank (B606015-BLK1)
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
ND
0.400
2.00
mg/kg
U
Arsenic
ND
0.400
2.00
mg/kg
U
[ron
ND
0.400
2.00
mg/kg
u
Lead
ND
0.400
2.00
mg/kg
u
Vlanganese
ND
0.400
2.00
mg/kg
u
Sulfur
ND
0.400
2.00
mg/kg
u
Duplicate (B606015-DUP1)
Source: 6040703-01
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
165
4.00
20.0
mg/kg
163 1.14
20
Arsenic
ND
4.00
20.0
mg/kg
ND
20
u
[ron
827
4.00
20.0
mg/kg
817 1.17
20
Lead
ND
4.00
20.0
mg/kg
ND
20
u
Vlanganese
ND
4.00
20.0
mg/kg
ND
20
u
Sulfur
ND
4.00
20.0
mg/kg
ND
20
u
Batch B606059 - Default Prep Metals
Blank (B606059-BLK1)
Prepared: 27-May-2016 Analyzed: 31-May-2016
Arsenic-75 [2]
ND
0.400
2.00
mg/kg
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 31 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals Sequential Extractions Residual - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike Source %REC
RPD
Analyte
Result
Limit
Limit
Units
Level Result %REC Limits RPD
Limit
Notes
Batch B606017 - Default Prep Metals
Blank (B606017-BLK1)
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
ND
0.400
2.00
mg/kg
U
Arsenic
ND
0.400
2.00
mg/kg
U
[ron
ND
0.400
2.00
mg/kg
u
Lead
ND
0.400
2.00
mg/kg
u
Vlanganese
ND
0.400
2.00
mg/kg
u
Sulfur
ND
0.400
2.00
mg/kg
u
Duplicate (B606017-DUP1)
Source: 6040703-01
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
494
0.800
4.00
mg/kg
463 6.44
20
Arsenic
20.9
0.800
4.00
mg/kg
20.1 3.71
20
[ron
4460
0.800
4.00
mg/kg
4250 4.97
20
Lead
ND
0.800
4.00
mg/kg
ND
20
u
Vlanganese
ND
0.800
4.00
mg/kg
ND
20
u
Sulfur
3.42
0.800
4.00
mg/kg
3.05 11.3
20
J
Batch B606060 - Default Prep Metals
Blank (B606060-BLK1)
Prepared: 27-May-2016 Analyzed: 31-May-2016
Arsenic-75 [2]
ND
0.200
1.00
mg/kg
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 32 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals Sequential Extractions Soluble - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike Source %REC RPD
Analyte
Result
Limit
Limit
Units
Level Result %REC Limits RPD Limit
Notes
Batch B606012 - Default Prep Metals
Blank (B606012-BLK1)
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
ND
1.60
8.00
mg/kg
U
Arsenic
ND
1.60
8.00
mg/kg
U
[ron
ND
1.60
8.00
mg/kg
u
Lead
ND
1.60
8.00
mg/kg
u
Vlanganese
ND
1.60
8.00
mg/kg
u
Sulfur
ND
1.60
8.00
mg/kg
u
Batch B606061 - Default Prep Metals
Blank (B606061-BLK1)
Prepared: 27-May-2016 Analyzed: 31-May-2016
Arsenic-75 [2]
ND
0.200
1.00
mg/kg
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 33 of 36
-------
USACE ERDC-EP-C
3909 Halls Ferry Road
Vicksburg, MS 39180-6199
Philadelphia District
Project: Vineland
Wanamaker Building, 100 Penn Square East
Reported:
Philadelphia PA, 19107-3390
Project Manager: Joe Loeper
13-Jul-2016
Metals Sequential Extractions Sulfide / Organic - Quality Control
ERDC-EL-EP-C
Detection
Reporting
Spike Source %REC
RPD
Analyte
Result
Limit
Limit
Units
Level Result %REC Limits RPD
Limit
Notes
Batch B606016 - Default Prep Metals
Blank (B606016-BLK1)
Prepared: 09-May-2016 Analyzed: 03-Jun-2016
Aluminum
ND
0.400
2.00
mg/kg
U
Arsenic
ND
4.00
20.0
mg/kg
U
[ron
ND
0.400
2.00
mg/kg
u
Lead
ND
4.00
20.0
mg/kg
u
Vlanganese
ND
0.400
2.00
mg/kg
u
Sulfur
ND
4.00
20.0
mg/kg
u
Duplicate (B606016-DUP1)
Source: 6040703-01
Prepared: 09-May-2016 Analyzed: 10-May-2016
Aluminum
37.0
4.00
20.0
mg/kg
35.7 3.52
20
[ron
37.5
4.00
20.0
mg/kg
35.2 6.28
20
Vlanganese
ND
4.00
20.0
mg/kg
ND
20
u
Batch B606062 - Default Prep Metals
Blank (B606062-BLK1)
Prepared: 27-May-2016 Analyzed: 31-May-2016
Arsenic-75 [2]
ND
0.400
2.00
mg/kg
u
The results in this report apply to the samples analyzed in accordance with the chain of
custody document. This analytical report must be reproduced in its entirety.
Page 34 of 36
-------
-------
-------
Items for Project Manager Review
LabNumber Analysis Analyte Exception
-------
Appendix B
XRD Analysis for ASB-1 and ASB-2
ERDC-EL
-------
EBC ID: 6040703-01A
ASB-2 26-27
6040703-01A-10-130 degrees
6040703-01A -2-70 degrees
<
W,,. 5
mm*
I Quartz low • Si02
; Goethite • FeO(OH) ,
_L
Ferrihvdrite • Fe.390.5&5
ICIinobhlore light • Mg2,5Fe 1.65^1.1.5Si2.2AH/„8Q-10IQy)8r..,,
CM '<
CO 00
CM CN
o CM
160107-1 WPF Report
Scan ID: Chris 2-70 scan time 2h_160107-1.xrdml • 160107-1
Scan Parameters: 2.511769.9970.0167r/219.71(s), w= 1.255678734.99573", q)=0.0c. I(p)=35558/216. Co<45kV.40mA). Tuesday.
ConIiguralion=Sample Sp>nner Relleclion-Transmlsslon. Owner=User-' Creation date=12/23/20O9 3:41:59 PM
Goniome;ei=PVV3050,'60 (Thela^Thela); Minimum step size 2Theta:0.001 Minimum step size 0mega:0.001
Sample stage=Reflection-Transmission Spinner PW3064/60; Minimum step size Phi:0 1
Diftractorneler system-XPERT-PRO
Measurement program=CHns 2-70 scan time 2h, Owner="User-1, Creation date=6/23/2011 8:43:04 AM
v Ka2 Peaks Present v Zero Offset = 0.00633 (0.00094)
Variable-Slit Pattern Displacement = 0.0
Geometry: Diffractometer Lp Fitted-Range: 4.0 - 70.0"
PSF: Pearson-VII Broadening: Individual FWHM Curve
Chemical Formula
X-Ray Polarization = 1.0
Ka2/Ka1 Ratio = 0.5
BG-Model: Polynomial (7) 1.78899 A (Co)
Instrument: Constant FWHM = 01'
Phase ID (4)
Quartz low
Goethite
Ctinochlore-1Mllb, ferroan
Ferrihydrite
Si02
Fe02
(Mg,Fe)e(Si,AIUOlo(OHh
NA NR NP Wt% (esd) RIR
— 12 11 88.1(3.6) 2.88
3 25 3 0.5 (0.0) 2.66
— 21 6 10.5(4.1) 0.40
3 8 3 0.9(0,1) 1.17
XRF(Wt%): Fe203=5.2%, SiO2=90.1%. AI203=1.7%. MgO=2.0%
Refinement Converged (R'E=158),« Round=3, lter=3. P=27. R=6.45% (E=4.0B%. EPS=0.5)
R=8.4% ¦ Quartz low • S/02
¦ Cbnochlore-lMllb • (Mg,Fe)6(Si,AI)4
¦ Ferrihydrite • Fe. 390.595
~ Goethite • Fe02
Refinement Converged (R/E=1
Ferrihydrite Ctnochlore-IMIIb
160107-1
Observed Pattern
WPFffte'Q raMl""
. I ll I i I.
IS Army Corp Engineers
-------
EBC ID: 6040703-01A
ASB-2 26-27
6040703-01A-10-130 degrees
6040703-01A -2-70 degrees
<
Quartz low • Si02
Goethite • FeO(OH) ,
I Fetrihvdrite • Fe.390.565
iClincfchlore 1 #la . Mg^FeteafJJ .5Si?.JAl1|rfO,ig®ld)8..
CM <
CO CO
CM CN
CO CM
160107-1 WPF Report
Scan ID: 1601107-1_160107-1.xrdml • 160107-1
Scan Parameters: 10.008'/129.99370.01671710.16(s), u>=5.004178764.99763°. (p=0.0", l(p)= 1695.0/1.0, Co(45kV.40mA), Friday,
10-130 degrees
•/ Ka2 Peaks Present
«/ Zero Offset = 0.00487 (0.00191)
X-Ray Polarization = 1.0
Variable-Slit Pattern
Displacement = 0.0
Ka2/Ka1 Ratio =0.5
Geometry: Diffractometer Lp
Fitted-Range: 10.0-130.0°
BG-Model:
Polynomial (7) A: 1.781
99 A (Co)
PSF: Pearson-VII Broadening: Individual FWHM Curve
Instrument:
Constant FWHM =0.1*
Phase ID (4)
Chemical Formula
NA
NR
NP Wt% (esd)
RIR
Quartz low
S/Oj
29
12 98.0(1.7)
2.88
Clinochlore-IMIIb, ferroan
(Mg.Fe)e(Si,AIUOw(OH)s
26
7 0.0 (0.4)
0.40
Ferrihydrite
Fe3aOs95
3
27
4 0.0(0.1)
1.17
Goethite
FeOj
3
93
4 1.9(0.6)
2.70
XRF(Wt%): Fb203=1,8%. S>02=98,0%. AI203=0.0%, MgO=0.0%
Refinement Converged (R/E=
R=31.4%
V
.21), ~ Round=3. Iler=3. P=30. R=27 56% (E=22.78%, EPS=0.5)
I Quartz lov/ • Si02
I Goethite • Fe02
I Clinochlore-IMIIb • (Mg,Fe)6(Si,AI)4...
I Ferrihydrite • Fe. 390.595
Refinement Converged (R/E=1_21)
- Observed Pattern
*WPmed»Patterr
160107-1
Ferrihydrite Ctnochlore-1Mllb GoethSe
160107-1
C 'iU58!5\RDGSLERGlOesklop\16(>1Q7'i1601 ID
• US Army Crop Engineers
-------
ECBID:6040703-02A
ASB-2 30-31
160107-2-2-70 degrees
6040703-02A -10-130 degrees
6
£
G
<<
co
Quartz low • Si02
Goethite • FeO(OlH)
Phosphoru£|Oxide • P4010
160107-2 WPF Report
Scan ID: Chris 2-70 scan time 2h_160107-2.xrdml • 160107-2
Scan Parameters: 2.511769.99'/0.01671V219.71(s), w= 1.255678734.99573", q>=0.0'. I(p)=47665/152. Co<45kV.40mA). Tuesday.
Ccnfigurat»on=Sample Spinner Reflection-Transmission, Owner=User-' Creation date=12/23/20O9 3:41:59 PM
Goniomeier=PW3050,'60 (ThetafTtMla); Minimum step size 2Theta:0.001 Minimum step size 0mega:0.001
Sample stage=Reflection-Transmission Spinner PW 3064/60; Minimum step size Phi:0 1
Diftractorneler system=XPERT-PRO
Measurement program=Cfms 2-70 scan time 2h, Ownen»User-1, Creation date*6/23/2011 8:43:04 AM
v Ka2 Peaks Present
Variable-Slit Pattern
Geometry: Diffractometer Lp
v Zero Offset = -0.00158 (0.00077)
Displacement = 0.0
Fitted-Range: 5.0 - 70.0" BG-Model: Polynomial (7)
X-Ray Polarization = 1
Ka2/Ka1 Ratio = 0.5
PSF: Pearson-Vli Broadening: Individual FWHM Curve Instrument: Constant FWHM =0 1"
Phase ID (3)
Quartz low, syn
Goethite. syn
Phosphorus Oxide
Refinement Converged (R/E=1
R=8.6%
Chemical Formula
SiOz
FeO(OH)
PDF-#
01-083-2465
01-081-0464
03-065-4587
NA NR NP
Wt% (esd) RIR
99.6 (0,5) 3,05
0.4 (0.0) 2.67
0.0 (0.0) 8.82
XRF(Wt%): F62O3=0.3%. P205=0.0%. Si02=99.B%
~ Round=3. lter=3, P=24 R=7.22% (E=4 24%, EPS«0.5)
¦ Quartz low, syn • Si02
¦ Goethite. syn • FeO(OH)
Refinement Converged (R*E=1.7)
FeO(OH)
160107-2
Observed Pattern
r WPFittetf-Patt&rn"*
160107-2
Uu_l1
is 3i_1601Q?-2,*nimt
W«l-->B5dav, May 18.2016. 1:37 PM • US Army Cotp Engine.
-------
ECB ID: 6040703-02A
ASB-2 30-31
160107-2-2-70 degrees
6040703-02A -10-130 degrees
< <
cn r-'
< <<
» ® ^
oo ^ rsi
CN CN ^
<
& f
"2 %
<
'<
'¦.O
c";
O
Quartz low • Si02
Goethite • FeCXOfo)
Phosphoru£ [Oxide • P^OtQ i
WPF Report
Scan ID: 1601107-2.xrdml
Scan Parameters: 10.008°/129.993°/0.0167r/10.16(s), u>=5.00417876
4.99763°. 9=0.0°, l(p)=2167.Q/1.0, Co(45kV,40mA). Friday.
10-130 degrees
: Fe2O3=0.3%. P205=0.1%, Si02=99.6%
Refinement Converged (R/E=1.24). * Round=3. Iter=3. P=23, R=30.51% (E=24.55%. EPS=0.5)
¦ Quartz lov/, syn • Si02
¦ Goethite. syn • FeO(OH)
~ P4O10 • Phosphors Oxidi
/ 99 6% I
II
Refinement Converged (R/E=1-24)
Observed Pattern
WR&jtte ABa ttemv*
LkuJuuLX
C '.UsersiRDGSLERG',Desktop*160107', t (
1 ;<10 PM • US Array Cop Engineers
-------
6040703-03A
ASB-2 31-32
6040703-03A-10-130 degrees
6040703-03A -2-70 degrees
J0
PhosphoruklOxide • P.401Q.
Quartz low • Si02 I
CM CM
00 <<
CO ® K ,
OD tO c\J
CM CM Ki CM
°< =1.255678°/34.99573°. cp=0.0°. I(p)=43666/111. Co(45kV.40mA), Tuesday.
Con!iguralion=Samp!e Sp
-------
6040703-03A
ASB-2 31-32
6040703-03A-10-130 degrees
6040703-03A -2-70 degrees
< --T t |
C << c<
CO CO
CO (N '
CM OJ CM
CM °=0.0°, l(p)=2136.0/1.0, Co(45kV.40mA), Friday.
Con!iguralioti=Sampie Spinner Reflection-Transmission. Owner=User-1. Creation date=12/23/2009 3:41:59 PM
Goniomeler=PW3050/60 (Theta/Theia); Minimum slop sizo 2Theta:0.001: Minimum stop size 0rnega:0.001
Sample stage-Relledion-Transmission Spinner PW3064/60 Minimum step size Phi:0 1
Dlflraclomelat syslem=XPERT-PRO
Measurement programme hris 2-70 scan time 2h, Ownef=MJser-1, Creation date=6/23/2011 8:43:04 AM
' Ka2 Peaks Present
Variable-Slit Pattern
X-Ray Polarization = 1.0
Ka2/Ka1 Ratio = 0.5
Geometry: Diffractometer Lp Fitted-Range: 11.0-130.0"
PSF: Pearson-VII Broadening: Individual FWHM Curve
Phase ID (4) Chemical Formula
Quartz SiO,
Zero Offset = 0.01911 (0.00082)
Displacement = O.O
BG-Model: Polynomial (7) 1 78899 A (Co)
Instrument: Constant FWHM = 0.1"
FeS05
Phosphorus Oxide
Quartz • K(0)
FeSOs
P«O,0
PDF-# Wt% (esd)
01-079-1906 100.0(1.2)
98-000-4784 0.0 (0.0)
03-065-4587 0.0 (0.0)
01-079-1906 0.0 (0.0)
4.75
2.52
8.82
4.75
XRF(Wt%): Fe2O3=0.0%, S03=0.0%. P205=0.0%. 8102=100.0%
Refinement Halted |R/£=1.19), * Round=4, lter=6, P=23. R=31.24% (E=26.17%. EPS=0.5)
2*31.34%
E=26.17%
Refinement Halted (R/E=1.19)
Observed Pattern
•WPHtrn'MttW'
P4O10
* 10-130 degrees
C :'.UseiBVRDGSLERG',D05Mop\160107116011D
Tuesday May 24. 2016, 2:50 PM • US Army Co'p Engirssers
-------
6040703-04A
ABS-1 26-27
6040703-04A-10-130 degrees
6040703-04A -2-70 degrees
£ ™ a
CM CM
CM CM
Quartz low* Siu2
Brucite • Mg02h)2
=0.0°. l(p)=44014/200. Co(45kV.40mA), Tuesday.
Con!iguralion=Samp!e Sp MgQ2H2
PDF-# Wt% (esd) RIR
00-046-1045 100.0(0.3) 3.41
98-000-9712 0.0(0.0) 2.42
00-046-1045 0.0(0.0) 3.41
XRF(Wt%): SiQ2=100.0% MgO=0.0%
3=66*/.
4=6.6%
jf^.62%
Refinement Halted (R/E=1.5!
Observed Pattern
WPFitted Pattern
160107-4
.. . i
I ll I I
l
I
I
—"HHH—
ev..'.RDSSLERGiDesWopHfi0107\ChrB2-?05«
ie 03, 2016.8:35 AM • US Army Corp Engine
-------
6040703-04A
ABS-1 26-27
6040703-04A -10-130 degrees
6040703-04A -2-70 degrees
<
|
W
Quartz low • Si02 T
Brucite * MqQ2HI2
• -r S w W
CO Ifi fvi H CO CO T—
cvj CN P o o
• 10-130 degrees WPF Report
Scan ID: 1601107-4.xrdml • • 10-130 degrees
Scan Parameters: 10.008";129.993V0.01671V10.16 00-046-1045 99.5(1.2} 3.41
Brucite MgChH2 98-000-9712 0.5(0.2) 2.42
XRF(Wt%): Si02»99.5%, MgO-O.3%
Refinement Converged (R/E=1.16). * Round=4. lter=3. P=21. R=26.72% (E=22.98%. EPS=0.5)
~ 0 uartz • Si02
2=267% ® Brucite • Mg02H2
-R=26 72%
E=22.98%
Refinement Converged (R/E=116)
Observed Pattern
• 10-130 degrees
• 10-130 degrees
Florenskyite • FeTiP
Brucite • MgOiH.'
'OesKtopM60107\160t 107-4 Mini
I • US Army Cotp Engine
-------
6040703-05A
ABS-1 27-28
6040703-05A-10-130 degrees
S040703-05A -2-70 degrees
L -
«c =39103/397. Co(45kV.40mA), Tuesday.
ConfigurBlion=Sample Spinner Reflect ion-Transmission. Owner=User-1. Crealion date=12/23/2009 3:41:59 PM
Goniomeler=PW3050/60 (Theia/Thaia); Minimum slop sizo 2Theta:0.001: Minimum stop size 0mega:0.001
Sample stage-Relledion-Transmission Spinner PW3064/60 Minimum step size Phi:0 1
Dlflraclomelat syslem=XPERT-PRO
Measurement programme hris 2-70 scan time 2h, Ownef=MJser-1, Creation dale=6/23/2011 8:43:04 AM
' Ka2 Peaks Present
Variable-Slit Pattern
' Zero Offset = -0,01491 (0.00043)
Displacement = 0.0
X-Ray Polarization = 1.0
Ka2/Ka1 Ratio = 0.5
Geometry: Diffractometer Ip Fitted-Range: 5.0 - 70.0"
PSF: Pearson-VII Broadening: Individual FWHM Curve
BG-Model: Polynomial (7) 1.78899 A (Co)
Instrument: Constant FWHM =0.1°
Phase ID (7)
Chemical Formula
PDF-#
Wt% (esd)
RIR
Quartz
SiO:
00-046-1045
91.9(0.3)
3.41
Kaolinlte 1A
AI2(ShO,J(OH)<
01-080-0886
1.4(0.1)
1.08
Goethite
FeO(OH)
01-081-0464
6.4 (0.2)
2.67
Hematite
Fe?03
01-089-8103
0.0 (0.0)
3.25
Periclase
MgO
98-001-0160
0.0 (0.0)
3.42
Cnstobalite
Si02
98-001-3212
0.3 (0.0)
5.06
Quartz • K(P)
SIO!
00-046-1045
0.0 (0.0)
3.41
Refinement Halted (R/E=1,33). • Round=4. Iter=6. P=31. R=4.75% (E:
R=5.57.
2=4.7*/.
XRF(Wt%): Fe203=5.8%, SI02=92.8%, AI2O3=0.6%, MgO=0.0%
56%. EPS=0.5)
Quartz • S/02
Goethite • FeO(OH)
Kaolmite 1A . AI2(Si205)(0H)4
Cnstobalite • S/02
Hematite • Fe203
Periclase • MgO
Refinement Halted (R/E=1.33)
Observed-Pattern-
WPFitted Pattern
160107-5
| Quam »SiOi
I KaoUtuto (A •4b!Se0sJ|0/«! ,
| Goe/hrfe •FeO(OH)
htemaMe » FaiO-
IWite«HaO
CrgloCuMa «5)Ct>
Quartz » KffiJ» SiO?
-4—M~t I lr—rfr-r
¦j. .L.m. I. I . ¦¦Ji.i.l.li.i
I " ' ' ' *
CX..'.RDGSLERG'iDesKtop^ 1 G0107\Chn32-70 scan tims 2ft_160107-5jodrrt Friday. June 03, 2016,8:47 AM • US Army Coip Engineer
-------
6040703-05A
ABS-1 27-28
6040703-05A-10-130 degrees
6040703-05A -2-70 degrees
<
1"
=? SK S
cn S
=0.0°, l(p)= 1844.0/6.0, Co(45kV.40mA). Friday.
Con!iguralioti=Sampie Spinner Reflection-Transmission. Owner=User-1. Creation date=12/23/2009 3:41:59 PM
Goniomeler=PW3050/60 (Theta/Theia); Minimum slop sizo 2Theta:0.001: Minimum stop size 0mega:0.001
Sample stage-Relledion-Transmission Spinner PW3064/60 Minimum step size Phi:0 1
Dlflraclomelat syslem=XPERT-PRO
Measurement programme hris 2-70 scan time 2h, Owner=MJs©r-1, Creation dale=6/23/2011 8:43:04 AM
' Ka2 Peaks Present
Variable-Slit Pattern
' Zero Offset = -0,02697 (0.00114)
Displacement = 0.0
X-Ray Polarization = 1.0
Ka2/Ka1 Ratio = 0.5
Geometry: DiHractometer Lp Fitted-Range: 10-0-130.0"
PSF: Pearson-VII Broadening: individual FWHM Curve
Chemical Formula
SI02
Ptiase ID (2)
Cristobalite
Quartz
SIQt
BG-Model: Polynomial (7) X: 1.78899 A (Co)
Instrument: Constant FWHM =0.1°
PDF-# Wt% (esd) RIR
98-001-0969 1.5(0.6) 2.41
00-046-1045 98.5(1.5) 3.41
XRF(Wt%): Si02=100.0%
Refinement Converged (R/E-1.12). * Round=3. Iter=3, P=19. R=21 22% (E=18.96%. E
I Cnstobalite • S/02
E=18.96%
Refinemenl Converged (R/E=1.12)
Observed Pattern
• 10-130 degrees
LyiffiV'iil i*i 11
m
MiM
CristataMe •$%».< J
r5l,RDGSLERG\Desktop>160107',1601107-5xdiri
ie 03, 2016.8:38 AM • US Army Corp Engineers
-------
6040703-06A
ABS-1 28-29
6040703-06A-10-130 degrees
:s>- 6040703-06A -2-70 degrees
Wi
Quartz • Si02
! Kaolinite 1A • AI2(Si2Q5yfam „ _ _
Goethite • FeO(OH) "~T
I Muscovite » KAll2QfSi3AI)Q.975O10((QH)1.72QQ.28), I
160107-6 WPF Report
Scan ID: Chris 2-70 scan lime 2h_160107-6.xrdml • 160107-6
Scan Parameters: 2.511769.9970.016717219.71(s). ui=1.255678734.99573°. cp=0.0*, l(p)=35171/334, Co(45kV ,40mA), Tuesday,
Conflguration=Sample Spinner Reflection-Transmission. Owner=User-1. Creation date=l2/23^2009 3:41:59 PM
Goniometer=PW3050/60 (Theia/Thela), Minimum step size 2Theta:0.0Q1; Minimum slap size Omega:0.001
Sample siage=Refieclion-Trartsroission Spinner PW3064/80; Minimum step size Phi:0.1
Dllfraclomeler systam=XPERT-PRO
Measurement program=Ctms 2-70 scan time 2h, Owner=User-1, Creation
-------
6040703-06A
ABS-1 28-29
6040703-06A-10-130 degrees
6040703-06A -2-70 degrees
O
g
Quartz • Si02
Kaolinite 1A • AI2(Sj205)(d)H)4 , I h i,.|
Goethite • FeO(OH) I
Muscovite. KAll20(Si3Al)0.975Q10((QH)172PQ-2^ I I ¦ I,
• 10-130 degrees
WPF Report
Scan ID: 1601107-6.xrdml • • 10-130 degrees
Scan Parameters: 10_008°V 129.993V0.01671 °/10 16(s>, k,y Llil J .I^dbr
V..lRDGSLERG'Ossk!oe'.160107\Chri5 2-70 scan lim« 2h_160107-7.xrdml Frelay, June 03. 2016. 9:07 AM • US Army Corp Engirsers
-------
6040703-07A
ASB-1 29-30
6040706-07A -10-130 degrees
•so- 6040703-07A -2-70 degrees
<
Cn CM in
i^gp-es),
Quartz » St02 i I
Kaolihite 1A • AI2(6i205KDH)4.
Goethite . FeO(Olk)
I Muscovite . KAI|2,2Q«3i3W10|97pO10(((
Cristobalite • Si021 . .
Microc[in|6 maxipiilir^tftijiAlpg.
WPF Report
Scan ID: 1601107-7.xrdml • • 10-130 degrees
Scan Parameters: 10.0087129.99370.01671*710.16(s), w=5.004178764.99763°. q>=0.0°, l(p)=2082.0/2.0, Co(45kV.40mA). Friday.
Contiguralioti=Sampie Spinner Reflection-Transmission. Owner=User-1. Creation date=12/23/2009 3:41:59 PM
Goniomeiei=PW3050/60 (Theta/Thaia); Minimum slop sizo 2Theta:0.001: Minimum stop size 0mega:0.001
Sample slage-Retlection-Transmission Spinner PW3064/60 Minimum step size Phi:0 1
Dlflraclomelat system=XPERT-PRO
Measurement programme hris 2-70 scan time 2h, Owner=MJser-1, Creation da te=6/23/2011 8:43:04 AM
1 Ka2 Peaks Present
Variable-Slit Pattern
' Zero Offset = 0.01336 (0.0008)
Displacement = 0.0
Geometry: Diftractometer Lp Fitted-Range: 11.0-130.0"
PSF: Pearson-VII Broadening: Individual FWHM Curve
X-Ray Polarization = 1.0
Ka2/Ka1 Ratio = 0.5
BG-Model: Polynomial (7) 1.78
Instrument: Constant FWHM = 0.1"
Phase ID (7)
Chemical Formula
PDF-#
Wl% (esd)
RIR
Quartz
Si02
00-046-1045
97.7(1.7)
3.41
Kaolinlte 1A
AI2(ShO'J(OH)<
01-080-0886
1.9 (0.2)
1.08
Goethite
FeO(OH)
01-081-0464
0.3 (0.0)
2.67
Muscovite
KA1Z 2o(SiaAlb 97sOto«OH)inOo.2B)
01-089-5401
0.0 (0.0)
0.43
Microcline maximum
K(Si3At)0B
01-076-1239
0.0 (0.0)
0.62
Cristobalite
SiOj
98-001-3212
0.1 (0.1)
5.06
Quartz • K(P)
SI02
00-046-1045
0.0 (0.0)
3.41
Refinement Converged (R.'E=1.12)
R=26.1*i
2=25.4*/.
3=25,
XRF(WI%)' Fb2O3=0.2%, K20=0.0%, 3102=96.7%, AI2O3=0.7%
I. Iter=3 P=31. R=25.37% (E=22.61% EPS=0.5)
¦ S/02 • Quartz
¦ AI2{Si205)(0H)4 > Kaolmite 1A
U FeO(OH) • Goethite
H Cristobalite • S/02
El Muscovite • KAI2.20(Si3AI)0..
¦ Microcline maximum • K(Si3AI)08
Refinement Converged (R/E=1.12)
p Engir»ers
-------
Appendix C
Final Report
Survey of arsenite biotransformation potential in contaminated soils
and groundwater affected by the Vineland Chemical Company
contamination around Vineland, NJ.
ERDC-EL
-------
FINAL REPORT
Survey of arsenite biotransformation potential in contaminated soils and
groundwater affected by the Vineland Chemical Company contamination around
Vineland, NJ
Carina M. Jung
U. S. Army Engineer Research and Development Center
Environmental Laboratory
3909 Halls Ferry Road
Vicksburg, Mississippi 39180-6199
Phone: 601 634-7247
Email: carina, m. iung(a)_usace. army, mil
-------
Arsenite Final Report Jung- October 26, 2015
1. Purpose. Determine the overall physiological potential for microbiological
transformation of Arsenite (As(lll)) in soils and groundwater site samples affected by the
Vineland Chemical Company contamination around Vineland, NJ.
2. Background. Preliminary determinations from field efforts conducted through 2015
for the purpose of remediating As contamination from soils and groundwater in sites
affected by the Vineland Chemical Company contamination around Vineland, NJ,
indicated a role for microbiological transformation of As(lll). As(lll) is soluble but
uncharged and typically more difficult to remove from solution, while the oxidized
species, As(V) can be collected via reverse osmosis, anion exchange, or through
precipitation and immobilization onto soil particles. Determination of effective and
appropriate remediation of the site(s) is needed to meet environmental cleanup goals.
Among potential remedial efforts, effective biotransformation may be enhanced through
understanding the physiological potential of the microbiological community and how to
better manage the site(s) as a means to encourage transformation of As(lll) to As(V).
2.1 General Requirement. The sponsor requires a PCR-directed genomic
survey of up to 20 contaminated groundwater and 20 contaminated soil samples.
Genes of interest to be targeted for PCR will be aioA and arxA, which are
involved in oxidation of As(lll) to As(V), and dsr1 which is a likely candidate for
providing an electron acceptor for As(l 11) oxidation via dissimilatory sulfate
reduction.
Validation of the PCR reaction would require that control bacterial strains be
purchased and parameters of the PCR reaction be established so that a
definitive yes or no answer regarding the detection of a gene in the samples can
be given. A final report of the findings and general conclusions about the
physiological potential of each sample/site toward biological transformation of
As(lll) to As(V) will be presented to the sponsor in an agreed upon time frame.
2.2 Project History. Previous analyses and studies at the site(s) have led to
suppositions regarding a biological role for transformation of As(lll) to As(V).
Management of the microbiological constituent of the site(s) may enhance
ongoing and future efforts for meeting environmental cleanup goals.
3. Materials and Methods. In order to assess the physiological potential of sponsor-
selected samples toward the oxidative biotransformation of As(lll) to As(V) PCR-based
surveys targeting three relevant genes were employed. Samples were processed by
standard DNA extraction techniques and traditional PCR was performed. Qualitative
results represented as +/- are presented herein.
Sampling protocol (sponsor). Soil samples (15 at ~15 g each) were taken at
the discretion of the sponsor from the contaminated site(s). Sterile sampling
tubes and alcohol swabs were provided by ERDC. Gloves were to be worn and
2
-------
Arsenite Final Report Jung- October 26, 2015
either replaced or wiped clean with alcohol swabs between each sampling.
Collection instruments (spatula, spoon, etc.) were to be wiped with alcohol swabs
between each sample to ensure no sample carryover. Sampling tubes (15 ml)
were filled to the top with sample to minimize air space and placed immediately
on ice in the field. Samples were placed in a 4°C refrigerator once back at the lab
and shipped to ERDC via overnight express on ice. The ice had melted by the
time the samples arrived at ERDC and the bag with the sample tubes was filled
with water, causing the labels to begin detaching. The labels were reattached,
and to our knowledge all tubes were properly relabeled.
Groundwater samples (11 at ~ 1 L each) were taken at the discretion of the
sponsor from the contaminated site(s). Gloves were to be worn and either
replaced or wiped clean between sampling to avoid cross-contamination.
Samples were collected by in-line filtration with a 0.22|jm PES filter unit, placed
on ice in the field, stored at -20°C once back in the lab, and then shipped to
ERDC via overnight express on ice. As with the soil samples, the filtration units
were floating in water that had not been completely filtered or that had breached
each bag from the melted ice in the cooler.
DNA Extraction and Sample Preparation. Each soil sample was extracted with
MoBio Power Soil DNA extraction kit and quantified spectrophotometrically. Each
sample was then PCR amplified with 16S rDNA primers (Table 1) as a quality
control check for amplification of the isolated DNA (this targets ribosomal DNA
and is always present if bacteria are present; a negative reaction means the
sample may need to be re-extracted). Fourteen samples failed to amplify and
were thus extracted twice more, followed by another 16S rDNA PCR
amplification. The same 14 sampled failed each time and were thus pooled and
processed with a Microcon DNA concentrating and cleanup filter. These samples
were again 16S rDNA PCR amplified and all were determined to be suitable for
PCR (Figure 1). Soil DNA samples were then amplified with the primer sets
specific for three gene targets (Table 1).
The water samples were concentrated in the field with a non-retrievable filter.
This led to difficulties in sample processing. Sterile water (~ 10 ml) was added via
pipette to the top of the filter, both ends were capped with parafilm, and the filter
unit was vortexed vigorously. Liquid was allowed to pour out from the top of the
filter into a 50 ml Falcon tube and this process was repeated twice more. The
debris/cells were then separated from each water/filter sample by centrifugation
and extracted with a MoBio Power Water DNA extraction kit following the
manufacturer's instructions. DNA was quantified spectrophotometrically and 16S
rDNA PCR reactions were performed as a quality control check for amplification
of the isolated DNA. Each of the 11 water samples successfully amplified (Figure
2). Water DNA samples were then amplified with the primer sets specific for
three gene targets (Table 1).
3
-------
Arsenite Final Report Jung- October 26, 2015
PGR Parameters. PGR amplification was performed using published methods
for the following PGR primer sets for the three genes of interest:
Tabie 1. Primers and conditions for targeted PGR.
Primer
Primers (5'-3')
PCR parameters
Reference
aioA
F-CCACTTCTGCATCGTGGG
R-TGTCGTTGCCCCAGATGA
95°C for 10 min, 35 cycles of
95°C for 1 min, 70°C for 1 min,
72°C for 2:30 min, and final
extension at 72°C for 10 min
Ghosh 2014
arxA
F - ACGGCAACGACTCCTACAAC
R - CGCACATCAATGGTGGTTAC
95°C for 1 min; 29 cycles of
55°C for 30 s and 72'C for 1
min; and a final extension of
72°C for 10 min
Zarger 2010
cferl
F - ACSCACTGGAAGCACG
R-GTGGAGCCGTGCAT GTT
95°C for 10 min, 40 cycles of 15
s at 94°C, 1 min at 59°C, 45 s
at 72 °C
Leloup 2007
16S rRNA
F - AGAGTTTGATCATGGCTCAG
R -TACGGYTACCTTGTTACGACTT
95°C for 5 min; 32 cycles of
94°C for 45 s 55°C for 45 s and
72°C for 1 min; and a final
extension of 72°C for 10 min
krause 2000
M123456789 10 11 12 13 14 15 16 17 18 19
L
J
Figure 1. Gel showing positive results for 16S rRNA with
bands (some very faint) for soil samples 1-15 in sequence.
Lane 16 is a positive control and 17 and 18 are negative
controls.
Figure 2. Gel showing positive
results for 16S rDNA with bands
(some very faint) for water
samples 1-8 on the top gel and
9-11 on the bottom, in sequence.
4. Results and Discussion. Samples were PGR amplified with primers for aioA and
arxA, which are involved in oxidation of As(lll) to As(V) via aerobic and anaerobic
mechanisms, respectively. Primers for the dissimilatory sulfate reduction pathway, dsr1
were also assessed since this pathway/mechanism is a likely candidate for providing an
electron acceptor for As(lll) oxidation.
There was no visual amplification of any of the soil or water samples with either the aioA
and arxA primers (Table 2). These results indicate the organisms responsible for
4
-------
Arsenite Final Report Jung- October 26, 2015
oxidation of As(lll) to As(V) by specific physiological mechanisms are either not present
or are in extremely low concentration. Conversely, 6 soil samples and all of the water
samples were visually positive for PCR amplification with primers for the dissimilatory
sulfate reduction pathway, dsr1 (Table 2; Figures 3-4). These results indicate that
oxidation of As(lll) to As(V) may be occurring anaerobically via coupling of AS(III)
oxidation with S04 reduction. Sulfate is thought to play a critical role in the site
geochemistry and is therefore a likely mechanism for AS(III) oxidation.
Table 2. PCR results for Vineland soil and water samples using three different primer sets.
Sample
aioA
arxA
dsr1
Soill - MP1 25-26
-
-
-
Soil2 - MP1 27-28
-
-
-
Soil3 - MP1 31-32
-
-
+
Soil4 - MP1 42-43
-
-
+
Soil5 - MP1 50-51
-
-
-
Soil6 - MP4 18-19
-
-
-
Soil7 - MP4 28-29
-
-
+
Soil8-MP4 31-32
-
-
+
Soil9 - MP4 38-39
-
-
-
Soill 0 - MP4 43-44
-
-
-
Soill 1 -AS1 32-32.5
-
-
-
Soil12-AS2 28-29
-
-
-
Soill 3 - AS2 34-34.5
-
-
+
Soil14-AS3 29-30
-
-
-
Soill 5-AS4 29-30
-
-
+
Waterl - PZ9 1245
-
-
+
Water2 - MW755 0945
-
-
+
Water3 - ASMP4L 1338
-
-
+
Water4 - WW25M 1055
-
-
+
Water5 - PZ10 0935
-
-
+
Water6 - ASMP9L 1238
-
-
+
Water7 - ASMP1L 1025
-
-
+
Water8 - WP225A 0938
-
-
+
Water9 - PZ17 1340
-
-
+
Waterl 0-MW525 1110
-
-
+
Waterl 1 -PZ12 1152
-
-
+
5
-------
Arsenite Final Report Jung- October 26, 2015
g
I
Figure 3. Gel of soil samples PCR-amplified with dsr primers in
sequence, 1-15. Sample 3, 7, and 13 are faint while 4, 8, and 15
amplified strongly.
Figure 4. Gel of water samples PCR-amplified with dsr primers in
sequence, 1-11 plus a positive control in lane 14. Samples 7, and 9
weakly amplified while the others exhibited stronger reactions.
5. References.
Ghosh, D., P. Bhadury, and J. Routh. 2014. Diversity of arsenite oxidizing bacterial
communities in arsenic-rich deltaic aquifers in West Bengal, India. Front. Microbiol.
5: (602).
Krause, D O., W.J. Smith, F.M. Ryan. R.I. Mackie, C.S McSweeney. 1999. Use of 16S-
rRNA based techniques to investigate the ecological succession of microbial
populations in the immature lamb rumen: tracking of a specific strain of inoculated
Ruminococcus and interactions with other microbial populations in vivo. Micob. Ecol
38(4):365-376.
Leloup,J., A. Loy, N J. Knab, C. Borowski, M. Wagner and B.B. J0rgensen. 2007.
Diversity and abundance of sulfate-reducing microorganisms in the sulfate and methane
zones of a marine sediment, Black Sea. Environ. Microbiol. 9(1): 131—142.
Zargar, K , S. Hoeft, R. Oremland, and C.W. Saltikov. 2010. Identification of a novel
arsenite oxidase gene, arxA. in the haloalkaliphilic, arsenite-oxidizing bacterium
Alkalilimriicola ehrlichii strain MLHE-1. J. Bacteriol. 192(14):3755-3762.
6
-------
Biotic Oxidation : PCR-directed genomic survey
PCR results for Vineland soil and water samples using three different primer sets.
Sample
aioA
arxA
dsr1
SoiH -MP1 25-26
-
-
-
Soil2 - MP1 27-28
-
-
-
Soil3 - MP1 31-32
-
-
+
Soil4 - MP1 42-43
-
-
+
Soil5 - MP1 50-51
-
-
-
Soil6 - MP4 18-19
.
.
.
Soil7 - MP4 28-29
-
-
+
Soil8 - MP4 31-32
-
-
+
Soil9 - MP4 38-39
-
-
-
SoiHO - MP4 43-44
.
.
.
SoiM 1 - AS1 32-32.5
-
-
-
Soil12 - AS2 28-29
-
-
-
SoiM 3 - AS2 34-34.5
-
-
+
SoiM 4 — AS3 29-30
.
.
.
SoiM 5 - AS4 29-30
-
-
+
Waterl - PZ9 1245
-
-
+
Water2 - MW755 0945
-
-
+
Wate r3 - AS M P4 L 1338
.
.
+
Water4 - VWV25M 1055
-
-
+
Water5 - PZ10 0935
-
-
+
Wate r6 - AS M P9 L 1238
-
-
+
Water7 - ASMP1L 1025
-
-
+
Water8 - WP225A 0938
-
-
+
Water9 - PZ17 1340
-
-
+
Waterl0 - MW525 1110
-
-
+
Waterl 1 -PZ12 1152
-
-
+
The polymerase chain reaction (PCR) is a technique used in
molecular biology to amplify a single copy or a few copies of a
piece of DNA across several orders of magnitude, generating
thousands to millions of copies of a particular DNA sequence.
Samples were PCR amplified with primers for aioA and
arxA, which are involved in oxidation of As(lll) to As(V) via
aerobic and anaerobic mechanisms, respectively. Primers
for the dissimilatory sulfate reduction pathway, dsr1 were
also assessed since this pathway/mechanism is a likely
candidate for providing an electron acceptor for As(l 11)
oxidation.
There was no visual amplification of any of the soil or
water samples with either the aioA and arxA primers.
These results indicate the organisms responsible for oxidation
of As(lll) to As(V) by specific physiological mechanisms are
either not present or are in extremely low concentration.
-------
Biotic Oxidation : PCR-directed genomic survey
PCR results for Vineland soil and water samples using three different primer sets.
Sample
aioA
arxA
dsr1
SoiH -MP1 25-26
-
-
-
Soil2 - MP1 27-28
-
-
-
Soil3 - MP1 31-32
-
-
+
Soil4 - MP1 42-43
-
-
+
Soil5 - MP1 50-51
-
-
-
Soil6 - MP4 18-19
.
.
.
Soil7 - MP4 28-29
-
-
+
Soil8 - MP4 31-32
-
-
+
Soil9 - MP4 38-39
-
-
-
SoiHO - MP4 43-44
.
.
.
SoiM 1 - AS1 32-32.5
-
-
-
Soil12 - AS2 28-29
-
-
-
SoiM 3 - AS2 34-34.5
-
-
+
SoiM 4 — AS3 29-30
.
.
.
SoiM 5 - AS4 29-30
-
-
+
Waterl - PZ9 1245
-
-
+
Water2 - MW755 0945
-
-
+
Wate r3 - AS M P4 L 1338
.
.
+
Water4 - VWV25M 1055
-
-
+
Water5 - PZ10 0935
-
-
+
Wate r6 - AS M P9 L 1238
-
-
+
Water7 - ASMP1L 1025
-
-
+
Water8 - WP225A 0938
-
-
+
Water9 - PZ17 1340
-
-
+
Waterl0 - MW525 1110
-
-
+
Waterl 1 -PZ12 1152
-
-
+
6 soil samples and all of the water samples were visually
positive for PCR amplification with primers for the
dissimilatory sulfate reduction pathway, dsr1. These results
indicate that oxidation of As(lll) to As(V) may be occurring
anaerobically via coupling of AS(III) oxidation with S04
reduction.
-------
Appendix D
Modifications to Wateq4f
-------
Arsenic species (arsenate and arsenite) and iron species (ferric iron and ferrous iron) were redefined in
the database as shown below. Values of equilibrium constants were not changed.
SOLUTION_MASTER_SPECIES
Fe di Fe di+2 0.0 Fe di 55.847
Fe tri Fe tri+3 0.0 Fe tri 55.847
Arsenate H3Arsenate -1 74.9216 74.9216
Arsenite H3Arsenite 0 74.9216 74.9216
SOLUTION_SPECIES
Fe di+2 = Fe di+2
log k 0.0
Fe tri+3 = Fe tri+3
log k 0.0
#
# Fe+2 species
#
Fe_di+2 + H20 = Fe_diOH+ + H+
log k -9.5
delta h 13.20 kcal
Fe_di+2 + Cl-~= Fe_diCl+
log_k 0.14
Fe_di+2 + C03-2 = Fe_diC03
log_k 4.38
Fe_di+2 + HC03- = Fe_diHC03+
log k 2.0
Fe_di+2 + S04-2 = Fe_diS04
log k 2.25
delta h 3.230 kcal
Fe_di+2 + HS04- = Fe_diHS04+
log_k 1.08
Fe_di+2 + 2HS- = Fe_di(HS)2
log_k 8.95
Fe_di+2 + 3HS- = Fe_di(HS)3-
log_k 10.987
Fe_di+2 + HP04-2 = Fe_diHP04
log k 3.6
Fe_di+2 + H2P04- = Fe_diH2P04+
log_k 2.7
Fe di+2 + F- = Fe diF+
log k 1.0
#
# Fe+3 species
#
Fe_tri+3 + H20 = Fe_triOH+2 + H+
log_k -2.19
delta h 10.4 kcal
Fe_tri+3 + 2 H20 = Fe_tri(OH)2+ + 2 H+
log_k -5.67
delta h 17.1 kcal
Fe_tri+3 + 3 H20 = Fe_tri(OH)3 + 3 H+
log_k -12.56
delta h 24.8 kcal
-------
Fe_tri+3 + 4 H20 = Fe_tri(OH)4- + 4 H+
log_k -21.6
delta h 31.9 kcal
2 Fe_tri+3 + 2 H20 = Fe_tri2(OH)2+4 + 2 H+
log_k -2.95
delta h 13.5 kcal
3 Fe_tri+3 + 4 H20 = Fe_tri3(OH)4+5 + 4 H+
log k -6.3
delta h 14.3 kcal
Fe_tri+3 + Clr = Fe_triCl+2
log_k 1.4 8
delta h 5.6 kcal
Fe_tri+3 + 2 CI- = Fe_triC12+
log_k 2.13
Fe_tri+3 + 3 CI- = Fe_triC13
log_k 1.13
Fe_tri+3 + S04-2 = Fe_triS04+
log k 4.04
delta h 3.91 kcal
Fe_tri+3 + HS04- = Fe_triHS04+2
log_k 2.4 8
Fe_tri+3 + 2 S04-2 = Fe_tri(S04)2-
log k 5.38
delta h 4.60 kcal
Fe_tri+3 + HP04-2 = Fe_triHP04+
log_k 5.43
delta h 5.76 kcal
Fe_tri+3 + H2P04- = Fe_triH2P04+2
log_k 5.43
Fe tri+3 + F- = Fe triF+2
log k 6.2
delta h 2.7 kcal
Fe_tri+3 + 2 F- = Fe_triF2+
log_k 10.8
delta h 4.8 kcal
Fe_tri+3 + 3 F- = Fe_triF3
log_k 14.0
delta h 5.4 kcal
#
# Arsenate and Arenite species
#
H3Arsenate = H3Arsenate
log k 0
H3Arsenite = H3Arsenite
log k 0
H3Arsenite = H2Arsenite- + H+
log_k -9.15
delta h 27.54 kJ
H3Arsenite = HArsenite-2 + 2H+
log k -23.85
delta h 59.41 kJ
H3Arsenite = Arsenite-3 + 3H+
log_k -39.55
delta h 84.73 kJ
H3Arsenite + H+ = H4Arsenite+
log k -0.305
H3Arsenate = H2Arsenate- +H+
-------
log k -2.3
delta h -7.066 kJ
H3Arsenate = HArsenate-2 +2H+
log k -9.46
delta h -3.846kJ
H3Arsenate = Arsenate-3 +3H+
log_k -21.11
delta h 14.354 kJ
SURFACE_SPECIES
Hfo wOH + Arsenate-3 + 3H+ = Hfo wH2Arsenate + H20
~log_k 29.31
Hfo wOH + Arsenate-3 + 2H+ = Hfo wHArsenate- + H20
~log_k 23.51
Hfo wOH + Arsenate-3 = Hfo wOHArsenate-3
~log_k 10.58
Hfo wOH + H3Arsenite = Hfo wH2Arsenite + H20
log k 5.41
PHASES
Goethite
Fe_triOOH + 3 H+ = Fe_tri+3 + 2 H20
log k -1.0
Siderite 9
Fe_diC03 = Fe_di+2 + C03-2
log_k -10.45
Mackinawite 67
Fe_diS + H+ = Fe_di+2 + HS-
log k -4.64 8
Magnetite 107
Fe_di0Fe_tri203 + 8H+ = 2Fe_tri+3 + Fe_di+2 + 4H20
log_k 3.737
delta h -50.460 kcal
Hematite 108
Fe_tri203 + 6H+ = 2Fe_tri+3 + 3H20
log k -4.008
delta h -30.845 kcal
Maghemite 109
Fe_tri203 + 6H+ = 2Fe_tri+3 + 3H20
log k 6.386
Fe(OH)3(a) ~ 112
Fe_tri(OH)3 + 3H+ = Fe_tri+3 + 3H20
log_k 4.891
Pyrite 114
Fe_diS2 + 2H+ + 2e- = Fe_di+2 + 2HS-
log_k -18.479
delta h 11.3 kcal
FeS (ppt) 119
Fe_diS + H+ = Fe_di+2 + HS-
log_k -3.915
-------
Appendix E
Model assumptions and results
-------
Batch Tests with pH Adjustment
Measured Values
Modeled Values
1
MW75S
' 1
Ground-
As
Fe
water
H2S04
NaOH
As
Fe
Error
Error
PH
Description
Date
(mL)
Soil (g)
(mL)
(mL)
(mg/L)
(mg/L)
pH
As (mg/L)
Fe (mg/L)
pH
(mg/L)
(mg/L)
Error
3/31/2016
N/A-lnitial Condition
2.05
10
5.7
N/A-lnitial Condition
4/1/2016
552
0
0
0
1.41
6
5.68
1.45
6.02
5.83
0.040
0.020
0.15
3.) Sorption/
Rxn, Low Fe
Sand,
varaible pH
4/1/2016
517
67.5
0
0
1.34
6.34
5.81
1.38
6.34
5.86
0.040
0.000
0.05
4/1/2016
505
67.5
10
0
1.43
8.77
5.38
1.485863
8.833562
5.34
0.056
0.064
-0.04
4/1/2016
503
67.5
20
0
1.56
13.7
4.73
1.53
13.74
4.73
-0.030
0.040
0.00
4/1/2016
492
67.5
30
0
1.61
15.2
4.41
1.65
15.24
4.41
0.040
0.040
0.00
4/1/2016
487
67.5
40
0
1.64
15.2
4.19
1.7
15.23
4.19
0.060
0.030
0.00
4/1/2016
475
67.5
50
0
1.65
17.9
4.01
1.71
17.91
4.01
0.060
0.010
0.00
4/1/2016
515
67.5
0
5
1.33
2.65
6.83
0.812
2.64
6.83
-0.518
-0.010
0.00
3/23/2016
N/A-lnitial Condition
1.54
7.81
6.01
N/A-lnitial Condition
3/24/2016
550
67.5
0
0
0.896
3.14
5.57
0.86
3.15
5.95
-0.036
0.010
0.38
4.) Sorption/
3/24/2016
508
67.5
0
0
0.176
15.9
5.92
0.106
15.92
6.39
-0.070
0.019
0.47
Rxn, Red/
3/24/2016
507
67.5
5
0
0.256
18.5
5.84
0.208
18.52
5.84
-0.048
0.019
0.00
orange sand,
3/24/2016
505
67.5
10
0
0.24
21.4
5.89
0.201
21.35
5.89
-0.039
-0.050
0.00
variable pH
3/24/2016
498
67.5
20
0
0.284
22.6
5.45
0.345
22.58
5.45
0.061
-0.021
0.00
3/24/2016
481
67.5
30
0
0.26
28.3
5.00
0.311
28.29
5
0.051
-0.006
0.00
3/24/2016
515
67.5
0
4
0.179
1.4
6.27
0.114
2.529
6.27
-0.065
1.13
0.00
-------
Batch Tests with pH Adjustment
MW75S
%Fe in
% Fe in
Ground-
soil used
sand used
water
H2S04
NaOH
Initial 02
% C02
for Fe3+
for
Description
Date
(mL)
Soil (g)
(mL)
(mL)
(mg/L)
Degassing
in rate eq
sorption
Assumed Equilibrium Phases
3/31/2016
N/A-lnitial Condition
4/1/2016
552
0
0
0
0.8
41%
N/A
N/A
None
3.) Sorption/
Rxn, Low Fe
Sand,
varaible pH
4/1/2016
517
67.5
0
0
0.8
40%
0.2%
0.5%
0.55% Fe in soil as siderite
4/1/2016
505
67.5
10
0
0.8
65%
0.2%
2.0%
0.28% Fe in soil as siderite
4/1/2016
503
67.5
20
0
0.8
41%
0.2%
5.0%
2.9% Fe in soil as siderite
4/1/2016
492
67.5
30
0
0.8
41%
0.2%
5.0%
2.9% Fe in soil as siderite
4/1/2016
487
67.5
40
0
0.8
50%
0.2%
5.0%
3.9% Fe in soil as siderite
4/1/2016
475
67.5
50
0
0.8
42%
0.2%
5.0%
5.8% Fe in soil as siderite
4/1/2016
515
67.5
0
5
1.04
67%
0.2%
0.5%
None
3/23/2016
N/A-lnitial Condition
3/24/2016
550
67.5
0
0
1.0
17%
N/A
N/A
None
4.) Sorption/
3/24/2016
508
67.5
0
0
0.8
17%
0.20%
2.0%
Magnetite and 1.2% Fe in soil as siderite
Rxn, Red/
3/24/2016
507
67.5
5
0
0.8
17%
0.20%
2.0%
Magnetite and 1.4% Fe in soil as siderite
orange sand,
3/24/2016
505
67.5
10
0
0.8
17%
0.20%
2.0%
Magnetite and 1.6% Fe in soil as siderite
variable pH
3/24/2016
498
67.5
20
0
0.8
17%
0.20%
2.0%
Magnetite and 1.56% Fe in soil as siderite
3/24/2016
481
67.5
30
0
0.8
17%
0.20%
5.0%
Magnetite and 1.77% Fe in soil as siderite
3/24/2016
515
67.5
0
4
0.8
17%
0.20%
2.0%
None
-------
Batch Tests without pH Adjustment
Description
Date
MW75S
Groundwater
(mL)
Soil (g)
Measured Values
Modeled Values
As Error
(mg/L)
Fe Error
(mg/L)
pH Error
As (mg/L)
Fe (mg/L)
pH
As (mg/L)
Fe (mg/L)
pH
1.) Sorption/
Reaction, sand, no
pH adjustment
10/1/2015
N/A-lnitial Condition
1.87
10.2
5.64
10/1/2015
575
0
1.72
9.57
5.74
1.78
9.53
5.72
0.060
-0.040
-0.02
10/1/2015
550
100
1.57
9.46
5.81
1.61
9.45
5.72
0.040
-0.010
-0.09
2.) Sorption/
Reaction,
Red/orange sand,
no pH adjustment
12/3/2015
N/A-lnitial Condition
1.832
9.247
5.66
12/3/2015
575
None
1.422
6.896
5.58
1.504
6.92
5.71
0.082
0.022
0.13
12/3/2015
550
33.25
0.428
6.283
5.50
0.418
6.24
5.61
-0.010
-0.048
0.11
12/3/2015
550
67.5
0.267
5.855
5.46
0.206
5.80
5.63
-0.061
-0.055
0.17
12/3/2015
500
133
0.118
9.379
5.64
0.076
9.37
5.86
-0.042
-0.014
0.22
12/3/2015
450
266
0.054
11.5
5.47
0.063
11.49
5.95
0.009
-0.008
0.48
12/3/2015
350
399
0.03
13.81
5.51
0.012
13.79
6.1
-0.018
-0.021
0.59
-------
Batch Tests without pH Adjustment
Model Assumptions
MW75S
%Fe in soil
% Fe in soil
Groundwater
Initial 02
% C02
used for initial
used for
Description
Date
(mL)
Soil (g)
(mg/L)
Degassing
Fe3+ in rate eq
sorption
Assumed Equilibrium Phases
1.) Sorption/
10/1/2015
N/A-lnitial Condition
Reaction, sand, no
10/1/2015
575
0
0.2
21%
N/A
N/A
None
pH adjustment
10/1/2015
550
100
0.2
21%
0.20%
0.50%
None
12/3/2015
N/A-lnitial Condition
2.) Sorption/
Reaction,
Red/orange sand,
no pH adjustment
12/3/2015
575
None
0.8
23%
N/A
N/A
None
12/3/2015
550
33.25
0.8
23%
0.20%
2.0%
Magnetite and 0.016% of Fe as siderite
12/3/2015
550
67.5
0.8
23%
0.20%
2.0%
Magnetite and 0.033% of Fe as siderite
12/3/2015
500
133
0.8
23%
0.20%
2.0%
Magnetite and 0.3% of Fe as siderite
12/3/2015
450
266
0.8
23%
0.20%
2.0%
Magnetite and 0.17% of Fe as siderite
12/3/2015
350
399
0.8
23%
0.20%
2.0%
Magnetite and 0.11% of Fe as siderite
-------
Column Tests
Column
Pore
Volume
Measured Values
Modeled Values
As Error
Fe Error
-0.056
0.16
Fe (mg/L)
pH
1
1
8/24/2016 10:15
0.393
0.437
6.35
0.411
0.381
6.51
0.018
1
3
8/24/2016 11:35
0.987
0.225
6.34
1.018
0.228
6.55
0.031
0.003
0.21
1
5
8/24/2016 12:40
1.67
1.97
6.19
1.663
2.036
6.41
-0.007
0.066
0.22
1
7
8/24/2016 14:00
1.8
6.28
6.09
1.79
6.34
6.20
-0.011
0.057
0.11
1
9
8/24/2016 15:29
1.75
9.08
6.31
1.688
9.018
5.99
-0.062
-0.062
-0.32
2
1
8/24/2016 10:40
0.204
13.5
5.61
0.238
13.465
6.14
0.034
-0.035
0.53
2
3
8/24/2016 11:43
0.387
5.99
5.84
0.320
5.993
6.08
-0.067
0.003
0.24
2
5
8/24/2016 12:44
0.257
6.05
6.2
0.338
6.060
6.06
0.081
0.010
-0.14
2
7
8/24/2016 14:05
0.0026
4.64
5.63
0.078
4.588
6.30
0.075
-0.052
0.67
2
9
8/24/2016 15:36
0.337
3.77
6.03
0.360
3.751
6.32
0.023
-0.019
0.29
-------
Column Tests
Model Assumptions g
%Fe in soil used
% Fe in soil
Pore
Initial 02
% C02
for initial Fe3+ in
used for
Column
Volume
Time Collected
(mg/L)
Degassing
rate eq
sorption
Assumed Equilibrium Phases
1
1
8/24/2016 10:15
2
92%
0.20%
0.10%
none
1
3
8/24/2016 11:35
2
90%
0.20%
< precip amt
none
1
5
8/24/2016 12:40
1.45
79%
0.20%
< precip amt
none
1
7
8/24/2016 14:00
0.85
48%
0.20%
< precip amt
none
1
9
8/24/2016 15:29
0.2
18%
none
0.05%
none
2
1
8/24/2016 10:40
0.85
8%
0.20%
0.10%
0.02% Fe in soil as siderite
2
3
8/24/2016 11:43
0.88
27%
0.20%
0.03%
none
2
5
8/24/2016 12:44
0.85
27%
0.20%
0.03%
none
2
7
8/24/2016 14:05
0.83
59%
0.20%
0.10%
none
2
9
8/24/2016 15:36
0.83
59%
0.57%
0.02%
none
------- |