EPA/600/R-20/125 | June 2020 www.epa.gov/homeland-security-research United States Environmental Protection Agency &EPA Report for Assessment of Non- Destructive Decontamination Methodologies for Mixed Porous Surfaces: Aging of Technology under High Humidity and UV Conditions Office of Research and Development Homeland Security Research Program ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Page intentionally left blank ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Report for Assessment of Non-Destructive Decontamination Methodologies for Mixed Porous Surfaces: Aging of Technology under High Humidity and UV Conditions Kathy Hall U.S. Environmental Protection Agency Center for Environmental Solutions and Emergency Response Homeland Security & Materials and Management Division Disaster Characterization Branch Cincinnati, OH 45268 Ryan James, Xiaoyan Xia, Zachary Willenberg Battelle; Columbus OH EPA Contract No. EP-C-10-060 and EP-C-15-012. June 2020 ------- - Page intentionally left blank - ii ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Disclaimer The U.S. Environmental Protection Agency (EPA), through its Office of Research and Development's Homeland Security Research Program, funded and managed this evaluation. The document was prepared by Battelle Memorial Institute under EPA Contract Number EP-C-15-002; Task Order 13. This document was reviewed in accordance with EPA policy prior to publication. Note that approval for publication does not signify that the contents necessarily reflect the views of the Agency. Mention of trade names or commercial products does not constitute endorsement or recommendation for use of a specific product. Questions concerning this document or its application should be addressed to: Kathy Hall Center for Environmental Solutions and Emergency Response Office of Research and Development (NG16) U.S. Environmental Protection Agency 26 West Martin Luther King Drive Cincinnati, OH 45268 (513) 379-5260 hall.kathy@epa.gov ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Foreword The U.S. Environmental Protection Agency (EPA) is charged by Congress with protecting the Nation's land, air, and water resources. Under a mandate of national environmental laws, the Agency strives to formulate and implement actions leading to a compatible balance between human activities and the ability of natural systems to support and nurture life. To meet this mandate, EPA's research program is providing data and technical support for solving environmental problems today and building a science knowledge base necessary to manage our ecological resources wisely, understand how pollutants affect our health, and prevent or reduce environmental risks in the future The Center for Environmental Solutions and Emergency Response (CESER) within the Office of Research and Development (ORD) conducts applied, stakeholder-driven research and provides responsive technical support to help solve the Nation's environmental challenges. The Center's research focuses on innovative approaches to address environmental challenges associated with the built environment. We develop technologies and decision-support tools to help safeguard public water systems and groundwater, guide sustainable materials management, remediate sites from traditional contamination sources and emerging environmental stressors, and address potential threats from terrorism and natural disasters. CESER collaborates with both public and private sector partners to foster technologies that improve the effectiveness and reduce the cost of compliance, while anticipating emerging problems. We provide technical support to EPA regions and programs, states, tribal nations, and federal partners, and serve as the interagency liaison for EPA in homeland security research and technology. The Center is a leader in providing scientific solutions to protect human health and the environment. Gregory Sales, Director Center for Environmental Solutions and Emergency Response iv ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 List of Abbreviations %R percent removal cm centimeter Cs-137 cesium-137 DeconGel DeconGel™ 1128 strippable coating EPA U.S. Environmental Protection Agency HSRP Homeland Security Research Program mL milliliter mm millimeter Nal sodium iodide NIST National Institute of Standards and Technology QA quality assurance QC quality control RH relative humidity SC strippable coating Stripcoat Stripcoat TLC Free™ strippable coating STDEV Standard deviation T temperature UV ultra-violet UVA ultra-violet A-rays UVB ultra-violet B-rays piCi microCurie Hw/cm2 microwatt per square centimeter V ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 ACKNOWLEDGMENTS This document was developed by the U.S. Environmental Protection Agency's (EPA) Homeland Security Research Program (HSRP) within EPA's Office of Research and Development. Kathy Hall was the project lead for this document. Contributions of the following individuals and organizations to the development of this document are acknowledged. United States Environmental Protection Agency Kathy Hall, Center for Environmental Solutions and Emergency Response John Hall, Center for Environmental Solutions and Emergency Response Terry Stilman, Region 4 Rick Demmer, Idaho National Laboratory Michael Kaminski, Argonne National Laboratory Battelle Memorial Institute Ryan James Xiaoyan Xia Dalia Natour Zachary Willenberg vi ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Table of Contents Page List of Abbreviations v Table of Contents vii Executive Summary ix 1.0 Introduction 1 2.0 Technology Descriptions 2 2.1 Stripcoat TLC Free™ 2 2.2 DeconGel™ 1128 2 3.0 Experimental Details 2 3.1 Coupon Preparation 4 3.2 Contaminant Application 4 3.4 Controlled Coupon Storage 6 3.5 Application and Evaluation of Decontamination Technologies 6 3.6 Calculation of Decontamination Factor and Percent Removal 8 4. Quality Assurance/Quality Control 8 4.1 Quality Assurance Measurements 8 4.2 Technical Systems Audit 8 4.3 Data Quality Audit 8 4.4 QA/QC Reporting 8 5. Evaluation Results and Performance Summary 9 5.1 Evaluation Results 9 5.1.1 Phase 1. Bricks Stored and Strippable Coatings Dried in Elevated T and RH 9 5.1.2 Phase 2. Bricks Stored in Elevated T and RH with Strippable Coating Dried Under Elevated UV 12 5.1.3 Phase 3. Baseline Study using Bricks Stored in Ambient Environmental Conditions 16 5.1.4 Summary of Strippable Coating Deployment and Operational Factors 16 5.1.5. Conclusions 18 6. References 18 LIST OF FIGURES Figure 1. Phase 1 and 3 brick (left) and Phase 2 brick (right) 4 Figure 2. Handheld pump sprayer 4 Figure 3. Activity measurement by Canberra Inspector 1000 5 Figure 4. Coupon Storage Chamber 6 Figure 5. Application of Stripcoat (left) and DeconGel (right) 6 Figure 6. RH controlled chamber with UV light exposure 7 Figure 7. Removal of decontamination technologies Stripcoat (left) and DeconGel (right) 7 LIST OF TABLES Table 1. Number and Type of Mixed Brick Coupons Used for Each Experimental Condition 3 vii ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Table 2. %R for Bricks Stored and Strippable Coatings Dried in Elevated T and RH 9 Table 3. Qualitative Results for Bricks Stored and SCs Dried in Elevated T and RH 11 Table 4. %R of Bricks Stored in Elevated T and RH with Strippable Coating Dried under Elevated UV...12 Table 5. Abbreviated Brick-only Comparison of Phase 1 and Phase 2 Bricks 14 Table 6. Qualitative Data for Bricks Stored in Elevated T and RH with Strippable Coating Dried under Elevated UV 14 Table 7. Stripcoat Deployment and Operation Factors 16 Table 8. DeconGel 1128 Deployment and Operation Factors 17 viii ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Executive Summary The U.S. Environmental Protection Agency's (EPA's) Homeland Security Research Program (HSRP) is protecting human health and the environment from adverse impacts resulting from chemical, biological, radiological and nuclear contamination. Such contamination can result from an intentional act (such as terrorism), or an unintentional act (such as a natural disaster or industrial accident). One way the HSRP protects human health and the environment is by carrying out performance tests and operational demonstrations on homeland security decontamination technologies. In 2015, EPA and Battelle conducted an operational demonstration of two strippable coating (SC) decontamination technologies, Stripcoat TLC Free™ SC (Stripcoat) and DeconGel™ 1128 SC (DeconGel). During this demonstration (which occurred during the summer), Stripcoat and DeconGel were sprayed onto a brick building and allowed to dry for approximately 24 hours. Following the drying step, the coatings were unable to be removed from the brick surface. To further explore the result of this demonstration, the HSRP recently evaluated the performance of Stripcoat and DeconGel under controlled elevated temperature (T), relative humidity (RH), and ultra-violet (UV) light conditions. The research included observation of the operational removal of the SCs as well as determination of the efficacy for the removal of radioactive Cesium-137 (Cs-137) from aged mixed porous surfaces. Brick coupons (excised samples) were contaminated with a liquid aerosol of Cs-137. At this point, pre- contamination radiological activity was measured. Coupons were then placed in a vertical test stand. Following manufacturer's recommendations, the SC decontamination technologies were applied to all of the coupons in the test stand. Following the application of the SCs, Phases 1 and 2 of testing included storing the contaminated brick coupons at elevated temperature (T) (81.8 °F ± 1.5 °F) and relative humidity (RH) (averaged 82% ± 1%) conditions. Phase 1 experiments included drying the coupons with the applied SCs under the elevated T and RH conditions over durations of overnight, and 3, 6, and 9 months. Phase 2 experiments included drying coupons with the applied SCs under elevated T and RH conditions with UV light exposure over durations of overnight, and 3, 6, 9, and 12 weeks. After the specified experimental durations, the post-decontamination radiological activity were measured for each brick coupon tested. The decontamination efficacy was determined by calculating a percent removal for each decontamination technology based on the measurements of pre- and post-decontamination activity. Important deployment and operational factors were also documented and reported. Decontamination Efficacy: The decontamination efficacy (in terms of percent removal, %R) of Stripcoat and DeconGel was evaluated following contamination of the coupons with approximately 1.7 microCurie (piCi) Cs-137 measured by gamma counting. The Phase 1 decontamination efficacies of Stripcoat in terms of %R for Cs-137 were: • 26% ± 5% after contaminant application without any storage in elevated T and RH • 26% ± 6% after contaminated bricks were stored in elevated T and RH for 3 months • 20% ± 2% after contaminated bricks were stored in elevated T and RH for 6 months • 19% ± 3% after contaminated bricks were stored in elevated T and RH for 9 months The Phase 1 decontamination efficacies of DeconGel in terms of %R were: ix ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 • 28% ± 8% after contaminant application without any storage in elevated T and RH • 28% ± 3% after contaminated bricks were stored in elevated T and RH for 3 months • 36% ± 1% after contaminated bricks were stored in elevated T and RH for 6 months • 39% ± 6% after contaminated bricks were stored in elevated T and RH for 9 months The Phase 2 decontamination efficacies of Stripcoat with UV light exposure were: • 52% ± 6% without any storage in elevated T and RH • 43% ± 18% after contaminated bricks were stored in elevated T and RH for 3 weeks • 45% ± 5% after contaminated bricks were stored in elevated T and RH for 6 weeks • 40% ± 5% after contaminated bricks were stored in elevated T and RH for 9 weeks • 51% ± 10% after contaminated bricks were stored in elevated T and RH for 12 weeks The Phase 2 decontamination efficacies of DeconGel with UV light exposure were: • Under ambient storage conditions (non-elevated RH and T) none of the dried DeconGel was able to be removed from the surface and therefore, no removal occurred • 58% ± 4% after contaminated bricks were stored in elevated T and RH for 3 weeks • 55% ± 6% after contaminated bricks were stored in elevated T and RH for 6 weeks • 54% ± 6% after contaminated bricks were stored in elevated T and RH for 9 weeks • 56% ± 1% after contaminated bricks were stored in elevated T and RH for 12 weeks Deployment and Operational Factors: Stripcoat and DeconGel were applied with a paint sprayer, dried overnight, and removed by peeling off the dried coating. Stripcoat was demonstrated to be easily removed from the surface of the bricks regardless of the pre-decontamination brick storage or SC drying conditions. DeconGel was demonstrated to be extremely difficult to remove following pre- decontamination storage of bricks in ambient (non-humidified) conditions. However, after pre- decontamination storage in elevated T and RH conditions, DeconGel was able to be applied, dried overnight, and then removed relatively easily from the brick surface. Drying under elevated UV conditions did not impact the ease of removal for either SC. Research Conclusions: • Stripcoat decontamination efficacy and operational removal were independent of storage and drying conditions. This is not consistent with results obtained during 2015 field testing. However, variables of scale, brick, and aging conditions contribute to these differences. • DeconGel is extremely difficult and sometimes impossible to remove (using the standard removal approach) after storage in ambient humidity conditions. • DeconGel removal efficacy may increase slightly after longer storage in elevated humidity conditions. • DeconGel removal efficacy and operational removal were independent of the drying under elevated UV exposure. • Decontamination efficacy is highly impacted by the brick surface as seen in the very different %Rs from bricks from two different buildings built only 5 year apart. x ------- 1.0 Introduction The National Response Framework, Nuclear/Radiological Annex, published in June of 2008, designated U.S. Environmental Protection Agency (EPA) as a coordinating agency for long term recovery following terrorist incidents involving radioactive materials. Consistent with EPA's legislated mission, this directive gives the EPA the governmental responsibility for the environmental response following releases of radiological materials that impact non-coastal private property. To meet the expected technology needs associated with acts of radiological terrorism, the EPA's Office of Research and Development, Homeland Security Research Program (HSRP), is conducting research to develop and deliver information on decontamination methods and technologies evaluations. These decontamination technology evaluations provide data to be used in support of decisions concerning the selection and use of decontamination technologies for buildings contaminated with radiological threat agents. The decontamination efficacy of Stripcoat TLC Free™ SC (Stripcoat) and DeconGel™ 1128 SC (DeconGel) has been evaluated previously to remove radioactive cesium (Cs)-137 from different types of surfaces in laboratory and pilot-scale experiments (1-7). The percent removals of Cs-137 from different surfaces such as concrete, limestone, granite and marble were somewhat variable. In the evaluation of Stripcoat on separate concrete surfaces study, the percent removal of cesium-137 between the 7-day and 30-day tests was determined to not be significantly different from one another. However, the thinner application did result in the Stripcoat tearing at the borders of the test coupons. In 2015, EPA and Battelle conducted an operational demonstration of these two strippable coating (SC) decontamination technologies, Stripcoat and DeconGel (8). During this demonstration (which occurred during the summer), Stripcoat and DeconGel were sprayed onto a brick building and allowed to dry for approximately 24 hours. It was found that after applying multiple coats and additional overnight dry time, both Stripcoat and DeconGel coatings were unable to be peeled off the wall in pieces larger than a few square inches, having become entrapped in the mortar joints. It is not clear if the lack of ability to peel was solely due to thickness of the layers of Stripcoat and DeconGel or if surface characteristics or some other variable such as humidity or exposure to sunlight played a role. To further explore the result of this demonstration, Battelle performed the project "Non-destructive decontamination methodologies for mixed porous surfaces under high humidity and UV conditions" under the direction of the U.S. EPA's HSRP through Contract EP-C-15-002. The experimental work involved in this technology evaluation was performed at Battelle following their quality assurance project plan. The experimental plan to evaluate the decontamination efficacy of two selected commercial decontamination technologies for removal of Cesium-137 (Cs-137) from mixed brick surfaces typically found in urban buildings and infrastructure is described below. During this evaluation, the two SCs were applied to brick surfaces and aged under high temperature (T) and relative humidity (RH) for a period of nine months. In addition, the same procedure was conducted except the experimental time period was 12 weeks and the coupons with SCs were dried overnight under elevated T and elevated ultra-violet (UV) conditions. As an operational baseline experiment, the SCs were also applied to uncontaminated brick coupons (excised samples) that had been stored under ambient environmental conditions (never in elevated RH). The evaluations took place between November 2017 and October 2019. This report describes the quantitative results and qualitative observations gathered during the evaluations. 1 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 2.0 Technology Descriptions 2.1 Stripcoat TLC Free™ Stripcoat (Stripcoat TLC Free™, Sanchem Inc., Chicago, IL) is a non-hazardous, non-toxic strippable coating designed for safely removing and preventing the spread of radioactive contamination. As shown in Figure 1, Stripcoat is sold as a "paint-like" formulation and application options include use of a brush, roller, or sprayer (a sprayer was used during this project). The target thickness for application is 1 millimeter (mm). While curing, Stripcoat mechanically entraps contamination. Following application, the coating requires 410 hours to cure prior to removal (overnight was used during this evaluation). The dried coating containing the encapsulated contamination can then be peeled off the surface and disposed. Stripcoat can also serve as a barrier to prevent contamination from attaching to a surface or as a covering to contain contamination. More information is available at https://www.bhienergv.com/services/power-services/technologies/specialtv-coatings/ 2.2 DeconGel™ 1128 DeconGel (DeconGel™ 1128, CBI Polymers Inc, Honolulu, HI) is a strippable coating designed for safely removing radioactive contamination from surfaces or as a covering to contain contamination. DeconGel 1128 is sold as a gel formulation and application options include use of a paint brush, roller, or sprayer (a sprayer was used during this project). The water-based wet coating (hydrogel) can be applied to horizontal, vertical or inverted surfaces and can be applied to most surfaces including bare, coated and painted concrete, aluminum, steel, lead, rubber, Plexiglas®, Herculite®, wood, porcelain, tile grout, vinyl, and ceramic and linoleum floor tiles. Following application, the coating requires approximately 12 hours to cure prior to removal. When dry, the product binds the contaminants into a polymer matrix. The dried coating containing the encapsulated contamination can then be peeled off the surface and disposed. More information is available at www.decongel.com. 3.0 Experimental Details The experimental steps included application of radioactive contaminant Cs-137 to the brick coupons, measurement of radioactive contamination present on coupons by gamma counting, application of the SC decontamination technologies, and subsequent measurement of residual contamination. This study was performed in three phases characterized by how the contaminated brick coupons were stored prior to decontamination and conditioned upon application of the SCs. Phase 1 included storage of the contaminated coupons under elevated T and RH and post-application SC drying under the same elevated T and RH conditions. Phase 2 was similar in that the contaminated brick coupons were stored under elevated T and RH prior to application of the SCs, but upon application of the SCs, Figure 1. Stripcoat (left) and DeconGel (right). 2 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 the overnight drying of the SCs took place under elevated T, RH and UV. Phase 3 was an operational baseline experiment using non-contaminated brick coupons stored in ambient environment conditions. The SCs were applied to these coupons and removed after overnight drying in ambient environmental conditions. Phase 1 was conducted over 9 months. For each of the SCs, 16 brick coupons were contaminated at the start of the experiment, pre-decontamination activity measurements were collected, and then four replicate contaminated coupons were decontaminated with SCs immediately with SC drying under elevated T and RH. The rest of the coupons were placed in elevated T and RH storage. Then, four replicate contaminated coupons were removed from elevated T and RH storage for pre- decontamination activity measurements collection and SC decontamination (with drying under elevated RH) in three-month increments (3, 6, and 9 months). The process was repeated with brick coupons stored under elevated T and RH except that the coupons with SCs were dried overnight under elevated T, RH and UV conditions in three-week increments (3, 6, 9 and 12 weeks) to determine the decontamination efficacy attained by each decontamination technology. Phase 3 was conducted as a one-time operational performance of the SC assessed by applying to brick coupons that had been stored in ambient environmental conditions. The coupons with SCs were then dried under ambient environmental conditions (never having been exposed to elevated RH or UV light). In addition, Quality Control (QC) samples that included background and positive control coupons were evaluated using four replicates each. Table 1 summarized the overall experimental design. Table 1. Number and Type of Mixed Brick Coupons Used for Each Experimental Condition Condition # of Decon Technologies Sample Collection Cycles Replicate Samples Total test Samples Background Samples Positive Controls Total Coupons Elevated T and RH 2 4 (0, 3, 6, 9 months) 4 32 4 4 40 Elevated T, RH and UV (drying) 2 5 (0, 3, 6, 9, 12 weeks) 4 40 4 4 48 Ambient Baseline 2 1 (time zero) 4 8 NA1 NA1 8 1NA - Not applicable as the ambient baseline experiment was an operational only test performed without radiological contamination. 3 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 3.1 Coupon Preparation All the brick coupons used during this study were collected during the demolition of two red- brick buildings at Battelle. Phase 1 (elevated T and RH) and Phase 3 (ambient environment condition) experiments were performed using bricks from a building that was constructed in 1956 (mortar made up approximately 10% of the surface) and Phase 2 experiments were performed using bricks (mortar was not salvaged during demolition) from a building that was constructed in 1951 (2). Full-sized bricks were cut using a diamond saw to dimensions of approximately 10 centimeter (cm) x 15 cm with the outward face of the brick unaltered for testing. Each coupon was marked with an identifying number using a permanent marker. Figure 2. Phase 1 and 3 brick (left) and Phase 2 brick (right). 3.2 Contaminant Application Each coupon was contaminated with approximately one milliliter (mL) of unbuffered, slightly acidic aqueous solution containing 1.7 microCurie (|iCi)/mL of Cs-137. This corresponded to the desired activity level of 1.7 fiCi per coupon delivered to each coupon using a handheld pump sprayer (Figure 3) that had been calibrated to dispense the desired volume. The liquid spike was prepared by diluting a 20 |iCi/mL solution of Cs-137 to the proper spiking concentration using volumetric pipettes and glassware. The contaminant spray was applied all the way to the edges of the coupon. A small amount of pooling was expected and occurred during contaminant application, but the coupon was air dried briefly prior to activity measurement. Figures. Handheld pump sprayer. r 4 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 3.3 Contaminant Measurement During each phase of testing, each contaminated coupon was removed from the radiological containment storage in sealed containers and a pre-decontamination activity measurement was acquired (in the energy levels specific to Cs-137 [662 keV] and Rb-86 [1,774 keV] only) using a sodium-iodide (Nal) radiation detector, (Inspector™ 1000, Canberra, Meriden, Connecticut), as shown in Figure 4. Following application of the decontamination technologies, the residual radioactive contamination on the same coupons was measured again, in the identical geometry (by placing the bricks approximately 2.5 cm below the detector face in a marked location), to calculate the percent removal (%R). In addition, four coupons that had not been contaminated were measured for background activity with each set of conditions. The BG coupons were exposed to the same storage conditions but were not exposed to the decontamination technologies being evaluated. The pre- and post-decontamination counts were collected over a 100-second measurement period. Because of the variable geometries of contaminant application, no activity calculations were performed. Net counts per second were used as the quantitative unit for determining decontamination efficacy by comparing the counts before decontamination to those after decontamination. A National Institute of Standards and Technology (NIST) traceable button source of Cs-137 was used for a daily instrument check by placing it below the detector face in a common geometry. Figure 4. Activity measurement by Canberra Inspector 1000. 5 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 3.4 Controlled Coupon Storage The contaminated brick coupons were stored within T and RH controlled radiological containment. Specifically, the temperature- controlled coupon storage chamber (HPI-1836, Avantco Equipment, Lancaster, PA) shown in Figure 5 was located within a radiological containment area in which a humidifier was used to elevate and maintain the RH. The T and RH of the storage chamber were continuously monitored and the data were stored in a HOBO data logger (Onset, Bourne, MA). Over the course of Phase 1 (November 2017 - September 2018) and Phase 2 (July 2019 - October 2019), the T averaged 81.8 °F ± 1.5 °F and the RH averaged 82% ± 1%. Phase 2 included drying of the SCs under UV light exposure in the same storage cabinet. UV light exposure was provided using a 24- inch FLUVAL T5 QUAD fluorescent lighting system (Rolf C. Hagen Corp., Mansfield, MA), which provided both the UV-A (wavelengths 320-400 nanometers [nm]) and UV-B (wavelengths 280-320 nm) light to which the brick coupons were exposed. The brick coupons were placed 5 cm below the lighting system for overnight drying. Over the illuminated area, the UVA intensity averaged 98 microwatt per square centimeter (|iw/cm2) ± 6 |iw/cm2 and the UVB intensity averaged 11 |iw/cm2 ± 3 |iw/cm2. This UV light intensity corresponds to a UV Index of at least 10 (considered 'Very High' by EPA)(9-11). 3.5 Application and Evaluation of Decontamination Technologies For each experimental cycle, eight brick coupons that had been stored in the T and RH-controlled chamber and had undergone pre-decontamination activity measurement were transferred to a fume hood to be decontaminated using Stripcoat and DeconGel (four brick coupons for each). Then the brick coupons were placed on a stand inside an open-ended box for coating and radiological containment. One coat of SC was applied to the surface of the coupons using a Wagner paint sprayer with iSpray™ nozzle (Wagner SprayTech Corporation, Plymouth, MN). After an hour, another coat was applied (Figure 6). Then, the coupons were transferred back to the chamber to dry overnight. Figure 6. Application of Stripcoat (left) and DeconGel (right). 6 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 For Phase 1 experiments, the brick coupons were dried under elevated T and RH and for Phase 2 experiments, the brick coupons were dried under elevated T and RH as well as UV exposure for 15 hours. This was accomplished by illuminating the cabinet with UV bulbs as shown in Figure 7. For Phase 3 experiments, the brick coupons were never contaminated, but they were stored under ambient environmental conditions and when the SCs were applied, they were dried overnight under ambient environmental conditions. Figure 7. RH controlled chamber with UV light exposure. After drying of the coupons coated with SCs, each of the dried coupons were transferred from the chamber to a plastic container, sealed with duct tape, and put in a plastic transfer container. All of the brick coupons tested were transferred to a radiological containment fume hood for SC removal. Removal of the dried Stripcoat coating was easily removed by grabbing the edge of the dried SC and pulling the SC off the surface in one piece. The dried DeconGel coating always required some additional effort, such as a plastic knife, to free a corner or an edge so that the dried coating could be removed from the surface as it was more tightly bound to the brick. Figure 8 shows a photograph of removal of Stripcoat and DeconGel. After removal of the dried strippable coating, the post-decontamination radiological activity was measured Figure 8. Removal of decontamination technologies Stripcoat for each brick coupon tested. (left) and DeconGel (right). / " ^ 7 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 3.6 Calculation of Decontamination Factor and Percent Removal The efficacy of decontamination was calculated for each contaminated coupon in order to evaluate the performance of each decontamination technology. The decontamination efficacy was represented using the following equation for %R: %R = l-(Af/A0) x 100% where A0 is the radiological activity from the surface of the coupon before application of a decontamination procedure and Af is radiological activity from the surface of the coupon after application of the decontamination procedure. The %R is the percent of contamination that was removed by the decontamination technology. 4. Quality Assurance/Quality Control 4.1 Quality Assurance Measurements Quality assurance (QA)/quality control (QC) procedures were performed in accordance with the project quality requirements. The measurement of gamma radiation from the surface of the coupons was performed using a Nal gamma radiation detector and its accuracy was monitored through daily performance checks that included analysis of a Cs-137 NIST standard. The counts per second from this standard were required to be within 10% of the average response throughout the duration of testing. Across 27 days of performing check samples, the average response was 152 ± 3 counts per second. The percent difference from the average ranged from 1% to 7% with an average of 2% ± 1%. Both pre- decontamination and post-decontamination activity measurements were conducted in triplicate. The standard deviation of activity measurement for all of the replicate brick coupons were less than 10%. The background activity of four non-contaminated coupons were measured for each decontamination technology. No background subtraction was performed. 4.2 Technical Systems Audit A technical systems audit was conducted during testing to ensure that the evaluation was performed in accordance with project quality requirements. As part of the audit, the actual evaluation procedures were compared with those specified in the project quality requirements. In addition, the data acquisition and handling procedures were reviewed. No significant adverse findings were noted in this audit. The records concerning the audit are stored indefinitely with the Battelle QA Manager. 4.3 Data Quality Audit At least 10% of the data acquired during the evaluation were audited. The Battelle QA Manager traced the data from the initial acquisition, through reduction and statistical analysis, to final reporting, to ensure the integrity of the reported results. All calculations performed on the data undergoing the audit were checked. No significant findings were noted. 4.4 QA/QC Reporting Each assessment and audit was documented in accordance with project quality requirements. 8 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 5. Evaluation Results and Performance Summary 5.1 Evaluation Results The decontamination efficacy of the Stripcoat and DeconGel was measured for each contaminated coupon in terms of percent removal (%R). The removal percentage of decontamination for each brick coupon was calculated using the equation in Section 3.6. Since all of the background activity is below detection limit, the raw count rate was used to calculate %R. The results are discussed below based on different experimental conditions. 5.1.1 Phase 1. Bricks Stored and Strippable Coatings Dried in Elevated T and RH Table 2 gives the %R for each brick coupon tested, the average %R and standard deviation for each decontamination technology over four replicates collected during each month of testing. Table 2. %R for Bricks Stored and Strippable Coatings Dried in Elevated T and RH Month Stripcoat DeconGel % removal Average STDEV % removal Average STDEV 22% 21% 0 27% 26% 5% 33% 28% 8% 24% 37% 33% 20% 29% 28% 3 20% 26% 6% 28% 28% 3% 33% 31% 21% 23% 20% 36% 6 17% 20% 2% 38% 36% 1% 20% 36% 22% 36% 21% 35% 9 21% 19% 3% 47% 39% 6% 15% 33% 18% 41% The decontamination efficacies of Stripcoat in terms of %R for Cs-137 were: • 26% ± 5% after contaminant application without any storage in elevated T and RH • 26% ± 6% after contaminated bricks were stored in elevated T and RH for 3 months • 20% ± 2% after contaminated bricks were stored in elevated T and RH for 6 months • 19% ± 3% after contaminated bricks were stored in elevated T and RH for 9 months 9 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Several t-tests were performed to evaluate the likelihood that the average Stripcoat %R results for each month were the same. The t-test results indicated the %R from each successive month of testing were not significantly different from one another. The %R associated with the initial test referred to as month 0 was significantly different from month 6 (p=0.041) and month 9 (p=0.032). Differences were significant at the 95% confidence level (p-values < 0.05). Even with these significant differences the overall average %Rs for Stripcoat spanned only 7 % so the magnitude of difference was not large. The decontamination efficacies of DeconGel in terms of %R were: • 28% ± 8% after contaminant application without any storage in elevated T and RH • 28% ± 3% after contaminated bricks were stored in elevated T and RH for 3 months • 36% ± 1% after contaminated bricks were stored in elevated T and RH for 6 months • 39% ± 6% after contaminated bricks were stored in elevated T and RH for 9 months Several t-tests were performed to evaluate the likelihood that the average DeconGel %R results for each month were the same (at the 95% confidence level). The t-test results indicated the %R from month 0 was not significantly different from any of the other months. Month 3 was significantly less than months 6 (p=0.002) and 9 (p=0.018). Moreover, months 6 and 9 (p=0.46) were not significantly different from one another at the 95% confidence level. Even with these significant differences, the overall average %Rs for DeconGel spanned only 11 % so the magnitude of difference is not large. Additional t-tests were performed to evaluate the likelihood that the average %Rs of Stripcoat and DeconGel between months were different. For months 0 (p=0.73) and 3 (p=0.64), these analyses confirmed what seems obvious just by comparing the averages and standard deviations (which clearly overlap) as the t-test indicated there was not a significant difference between the Stripcoat and DeconGel %Rs. The t-test results demonstrated significant differences between Stripcoat and DeconGel during month 6 (p<0.0001) and 9 (p=0.001), confirming the comparison of averages and standard deviation of the Stripcoat and DeonGel. The %Rs of DeconGel were higher than that of Stripcoat with 36%±1% compared to 20%±1% month 6 and 39%±6% compared to 19%±3% for month 9 indicating that DeconGel demonstrated a greater efficacy when the coupons were stored in high RH chamber longer. Note that during months 0 and 3, for DeconGel, not all of the dried SC was able to be removed from the brick surface, therefore decreasing the %R attained to various extents that are not fully captured by the quantitative data. These qualitative operational factors are described below. In addition to the quantitative %R determinations, another important set of data were the operation factors surrounding the removal of the strippable coatings throughout the course of the experiment. Table 3 presents the qualitative data for the bricks stored and strippable coatings dried in elevated T and RH (Phase 1 experiments). These qualitative data include the approximate time required for removal of the strippable coating for each brick as well as the approximate amount of coating that was able to be removed from the brick and mortar. Summary observations are included below. 10 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Table 3. Qualitative Results for Bricks Stored and SCs Dried in Elevated T and RH Month Stripcoat DeconGel Time for removal (min) Coating removed Time for removal (min) Coating removed 0 1 100% 10 ~90% from brick, ~10% from mortar 1 100% 10 ~95% from brick and mortar 1 100% 10 ~95% from brick, ~90% from mortar 1 100% 20 ~75% from brick, ~0% from mortar 3 1 100% 13 ~95% from brick, ~0% from mortar 1 100% 8 ~95% from brick, ~0% from mortar 1 100% 35 ~95% from brick, ~0% from mortar 1 100% >20 ~66% from brick, ~0% from mortar 6 1 100% 5 100% 2 100% 4 100% 2 100% 3 100% 5 100% 3 100% 9 1 100% 4 100% 1 100% 5 100% 1 100% 5 100% 1 100% 3 100% Observations from the qualitative data for elevated RH experiments include: • Dried Stripcoat was relatively easy to peel off as 100% was always able to be removed from the brick and mortar components of the coupons. The time required for removal of the dried coating from each brick was in the range of 1 to 5 minutes. • Dried DeconGel was more difficult to peel off, especially on mortar. During the 0- and 3- month experiments, after 8-35 minutes of working on the removal, complete removal of DeconGel was not able to be attained from any of the brick coupons. In several cases, almost all (>95%) of the DeconGel was removed, but in three instances between 10-33% remained on the brick and there were several instances that most or all of the DeconGel remained on the mortar component of the brick. In the cases where the DeconGel could not be removed, it was because the edges of the coating were not able to be peeled up from the surface at all, thereby not allowing the decontamination technician to be able to grip and then peel off the coating from the rest of the surface. • While still more difficult to remove than the Stripcoat (note the removal times for each), during the 6 and 9-month experiments, the dried DeconGel coating was completely removed from both brick and mortar surfaces in a single piece. • Dried Stripcoat coating was able to be removed by starting to peel the edge of the brick by gripping the dried coating by hand and then peeling the rest of the coating off of the surface. Dried DeconGel could be peeled off in similar manner, but in order to grip the edge of the 11 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 coating a plastic knife was required to pry the edge of the coating off the surface in order to allow gripping it by hand. Then the peeling had to be done little by little in order to keep the dried DeconGel coating from tearing. In contrast, dried Stripcoat was more elastic, not tearing easily, therefore easily removed in one piece once the edge was started. Overall, the data indicate that for Stripcoat, the operational function is largely independent of the storage and/or drying in elevated T and RH conditions, but for DeconGel, the longer that the bricks are stored within elevated T and RH conditions, the more likely it is that the dried DeconGel coating will be able to be removed from the bricks. 5.1.2 Phase 2. Bricks Stored in Elevated T and RH with Strippable Coating Dried Under Elevated UV Table 4 gives the %R for each brick coupon tested, the average %R and standard deviation for each decontamination technology over four replicates collected during each week of testing. The decontamination efficacies of Stripcoat were determined after the contaminated bricks had been stored in elevated T and RH for timeframes ranging from 0 to 12 weeks. In separate Stripcoat experiments after 0, 3, 9, and 12 weeks, the Stripcoat was applied to the contaminated surfaces and then dried over 15 h with elevated T and UV. Under these conditions, the %Rs were: • 52% ± 6% without any storage in elevated T and RH • 43% ± 18% after contaminated bricks were stored in elevated T and RH for 3 weeks • 45% ± 5% after contaminated bricks were stored in elevated T and RH for 6 weeks • 40% ± 5% after contaminated bricks were stored in elevated T and RH for 9 weeks • 51% ± 10% after contaminated bricks were stored in elevated T and RH for 12 weeks Several t-tests were performed to evaluate the likelihood that the average Stripcoat %R results for each week were the same. The t-test results indicated the %Rs from each successive week of testing were not significantly different from one another while the %R associated with the initial test, referred to as Week 0, was significantly different from Week 6 (p=0.021). Even with this significant difference the overall average %R for Stripcoat spanned only 12 % so the magnitude of difference is not large. Table 4. %R of Bricks Stored in Elevated T and RH with Strippable Coating Dried under Elevated UV Weeks Stripcoat DeconGel % removal Average STDEV % removal Average STDEV 0 60% 52% 6% NR NR NR 52% NR 50% NR 46% NR 3 37% 43% 18% 56% 58% 4% 70% 54% 33% 62% 33% 61% 6 45% 45% 5% 56% 55% 6% 12 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Weeks Stripcoat DeconGel % removal Average STDEV % removal Average STDEV 50% 46% 38% 59% 46% 57% 43% 60% 9 41% 40% 5% 58% 54% 6% 33% 50% 43% 47% 66% 57% 12 47% 51% 10% 56% 56% 1% 48% 57% 43% 55% NR - no removal as the dried SC was not able to be removed from the brick. The decontamination efficacies of DeconGel after the contaminated bricks had been stored in elevated T and RH from 0 to 12 weeks and the drying was done over 15 h of elevated T and UV were: • Under ambient storage conditions (non-elevated RH and T) none of the dried DeconGel was able to be removed from the surface and therefore, no removal occurred • 58% ± 4% after contaminated bricks were stored in elevated T and RH for 3 weeks • 55% ± 6% after contaminated bricks were stored in elevated T and RH for 6 weeks • 54% ± 6% after contaminated bricks were stored in elevated T and RH for 9 weeks • 56% ± 1% after contaminated bricks were stored in elevated T and RH for 12 weeks The average %Rs from the Phase 2 experiments range from 54% to 58%. This compares with a range of 28% to 39% during the Phase 1 experiments. As for the Stripcoat results discussed above, this was somewhat unexpected but was attributed to the bricks being sourced from different buildings. Another interesting aspect of the DeconGel results is that the Week 0 experiments resulted in none of the dried DeconGel being removed from the brick surface. Therefore, none of the Cs-137 was able to be removed. Consistent with the Phase 1 results, this is attributed to the storage of the bricks in ambient conditions prior to the start of the elevated T and RH experiments. This will be discussed further in the discussion of qualitative factors below. Several t-tests were performed to evaluate the likelihood that the average DeconGel %R results for each week were the same. The t-test results indicated the %Rs across the entire experiment were not significantly different from one another (p-values ranged from 0.29 to 0.84). Additional t-tests were performed to evaluate the likelihood that the average %Rs of Stripcoat and DeconGel between weeks were different. For Weeks 3 (p=0.19) and 12 (p=0.38), these analyses confirmed what seems obvious just by comparing the averages and standard deviations (which clearly overlap) as the t-test indicated there was not a significant difference between the Stripcoat and DeconGel %Rs. The t-test results demonstrated significant differences between Stripcoat and DeconGel during month 6 (p=0.040) and 9 (p=0.013), confirming the comparison of averages and standard deviation of the Stripcoat and DeconGel. The %Rs of DeconGel were higher than that of 13 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Stripcoat with 55%±6% compared to 45%±5% for month 6 and 54%±6% compared to 40%±5% for month 9. The average %Rs from the Phase 2 experiments range from 40% to 52%. This compares with a range of 19% to 26% during the Phase 1 experiments. This was somewhat unexpected as the bricks used in each experiment looked similar; however, they were collected from different buildings and apparently had different characteristics that impacted the %Rs. The Phase 1 bricks were from a building built in 1956 and the Phase 2 bricks from a building built in 1951. One possible reason for this discrepancy was that the Phase 1 bricks had mortar on one edge while the Phase 2 bricks had no mortar. It is possible that the Phase 1 bricks (or perhaps the mortar) had a higher affinity for Cs-137 or that Cs-137 was transported below the surface where there would be no access to the strippable coating for removal. An abbreviated experiment was performed to study the impact of mortar on the decontamination efficacy. There were four bricks remaining from the Phase 1 project so an abbreviated experiment was performed where the Phase 1 and Phase 2 bricks were contaminated onto the brick only (no contamination was sprayed onto the mortar of the Phase 1 bricks) that had been stored at 80% RH for 5 days. Then Stripcoat was applied to 2 bricks and DeconGel was applied to 2 bricks and overnight drying was performed without elevated RH or UV. The results (Table 5) show that the %Rs are very similar to the Phase 2 removals suggesting that the presence of mortar tends to increase the affinity of mixed surfaces for Cs-137, decreasing the decontamination efficacy (as was seen when mortar was included during the Phase 1 experiments). Table 5. Abbreviated Brick-only Comparison of Phase 1 and Phase 2 Bricks Bricks Stripcoat DeconGel % removal Average % removal Average Phase 1 47% 40% 52% 54% 32% 55% Phase 2 49% 48% 59% 60% 47% 60% As during Phase 1, the operational factors surrounding the removal of the strippable coatings were documented throughout the course of the experiment. Table 6 presents the qualitative data for the (Phase 2 experiments). These qualitative data include the approximate time required for removal of the strippable coating for each brick as well as the approximate amount of coating that was able to be removed from the brick surface. Table 6. Qualitative Data for Bricks Stored in Elevated T and RH with Strippable Coating Dried under Elevated UV Week Stripcoat DeconGel Time for removal (min) Coating removed Time for removal (min) Coating removed 0 1 100% ~10 0% 1 100% ~10 0% 14 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Stripcoat DeconGel Week Time for removal (min) Coating removed Time for removal (min) Coating removed 1 100% "10 0% 1 100% ~10 0% 2-3 100% 10 100% 3 2-3 100% 2 100% 2-3 100% 10 100% 2-3 100% 3 100% 1.5-2 100% 2-3 >90% 6 1.5-2 100% 2 100% 1.5-2 100% 2 100% 1.5-2 100% 2 100% 2 100% 15 >95% 9 1 100% <10 >95% 1 100% 3 100% 1 100% 3 100% ~2 100% ~2 >95% 12 ~2 100% ~2 >95% ~2 100% ~2 >95% ~2 100% ~12 >90% Observations from the qualitative data for Phase 2 experiments including bricks stored in elevated T and RH with strippable coating dried under elevated UV include: • Dried Stripcoat coating was relatively easy to peel off as 100% was always able to be removed from the brick coupons. The time required for removal of the dried coating from each brick was in the range of 1 to 3 minutes. There was not a notable difference in Stripcoat removal between the Phase 1 and Phase 2 experiments. • Dried DeconGel coating was more difficult to peel off than Stripcoat. During the initial week of experiments, after 10 minutes of effort, the decontamination technicians were not able to get a grip on the dried coating at the edge of the brick. Because no progress seemed likely the effort to remove it was abandoned. • Lack of DeconGel removal during Week 0 suggested that the UV drying may have been the cause of the removal difficulty. However, during the Weeks 3-12 experiments using bricks stored at elevated T and RH (with UV applied only during SC drying), between 90%-100% of the dried DeconGel was able to be removed from every brick with the removal time ranging from 2-15 minutes, but in most cases removal occurring in 2 or 3 minutes, which is similar to Stripcoat. During Weeks 3-12, there was not a notable difference in DeconGel removal between Phase 1 and Phase 2 experiments. • Similar to the Phase 1 experiments, dried Stripcoat coating was able to be removed by starting to peel the edge of the brick by gripping the dried coating by hand and then peeling the rest of the coating off of the surface. Dried DeconGel could be peeled off in similar manner, but in 15 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 order to grip the edge of the coating a plastic knife was required to pry the edge of the coating off the surface in order to allow gripping it by hand. Then the peeling had to be done little by little in order to keep the dried DeconGel coating from tearing. In contrast, dried Stripcoat was more elastic, not tearing easily, and therefore easily removed in one piece once the edge was started. These data also indicate that for Stripcoat, the operational function is largely independent of the storage in elevated T and RH conditions and drying with elevated UV exposure. For DeconGel, storage of brick in ambient environmental conditions (specifically non-humidified) have a detrimental effect on the ability to remove dried DeconGel from the brick surfaces. In addition, the data suggest that DeconGel removal function is independent of UV drying. 5.1.3 Phase 3. Baseline Study using Bricks Stored in Ambient Environmental Conditions The Phase 3 study was purely an operational evaluation (no Cs-137 contamination was applied to the bricks) of Stripcoat and DeconGel being applied to brick coupons to observe its removal after bricks had been stored in ambient environmental conditions. Consistent with the Phase 2 experimental results, the Stripcoat was able to be removed from the bricks in approximately 1 minute while the DeconGel was not able to be removed from the bricks at all. Again, after 10 minutes of effort the removal attempt was abandoned. 5.1.4 Summary of Strippable Coating Deployment and Operational Factors Tables 7 and 8 summarize various practical information (both qualitative and quantitative) gained during the evaluation of Stripcoat during this and previous technology evaluations (12,13)involving these strippable coatings. A number of operational factors were documented by the technician who performed the testing. Table 7. Stripcoat Deployment and Operation Factors Parameter Description/Information Decontamination rate Coating preparation: Provided ready for use Application: Approximately 3 minutes at 100 mL per coat onto 0.16 m2 for an application rate of 3.2 m2/hour and a Stripcoat use rate of 625 mL/m2 for each coat Drying time: overnight Applicability to irregular surfaces Application to more irregular surfaces than were tested here is unlikely to be a problem as a sprayer can coat most surfaces accessible to an operator Stripcoat cures to a very elastic film that is conducive for use on irregular surfaces (such as brick) Skilled labor requirement After a brief training session to explain the procedures, no special skills would be required to successfully perform both the application and removal procedures Utilities requirement No utilities were needed when paint brush application was used Stripcoat was applied using a paint sprayer, which requires minimum 120 volts alternating current power _ ^ ^ ^ • With the exception of extreme cold, which would prevent the application of the Extent ot portability , , . water-based Stripcoat, the technology is portable 16 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 Shelf life of media • Shelf life is advertised as one year Secondary waste • Solid waste production: approximately 400 g/m2for two applications of two management coats Surface damage • No visible surface damage; removed only loose particles that were consequently stuck to the removed coating • $24/L corresponding to $17/m2 per application; Bartlett suggests three applications, which would correspond to approximately $50/m2 Table 8. DeconGel 1128 Deployment and Operation Factors Parameter Decontamination rate Description/Information Coating preparation: Provided ready for use Application: Approximately 3 minutes at 250 mL per coat onto 0.16 m2 for an application rate of 3.2 m2/hour and a DG 1128 use rate of 1.56 L/m2 for each coat Drying time: overnight Applicability to irregular surfaces Application to more irregular surfaces than were tested here is unlikely to be a problem as a sprayer can coat most types of surfaces accessible to an operator DG 1128 cures to a relatively strong but flexible film that is conducive for use on the surfaces made from brick as was used during this evaluation Skilled labor requirement After a brief training session to explain the procedures, no special skills would be required to successfully perform both the application and removal procedures Utilities requirement No utilities when paint brush application was used DeconGel 1128 was applied using a paint sprayer, which requires minimum 120 volts alternating current power Extent of portability With the exception of extreme cold, which would prevent the application of the water-based DG 1128, the technology is not limited due to portability Shelf life of media Shelf life is advertised as one year Secondary waste management Solid waste production: approximately 460 g/m2for two applications of two coats Surface damage No visible surface damage; removed only loose particles that were consequently stuck to the removed coating Cost Cost is $40/L, which corresponds to approximately $240/m2 if used in a similar way as used during this evaluation. 17 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 5.1.5. Conclusions • Stripcoat decontamination efficacy and operational removal were independent of storage and drying conditions. They might be related to the coating thickness applied and the length of curing. However, the effect of loading volume (thickness) and the curing time were not investigated in this study. • DeconGel is extremely difficult to remove after storage in ambient humidity conditions. • DeconGel removal efficacy may increase slightly after longer storage in elevated humidity conditions. • DeconGel removal efficacy and operational removal were independent of the drying under elevated UV exposure. • Decontamination efficacy is highly impacted by the brick surface as seen in the very different %Rs from bricks from two different buildings built only 5 year apart. This indicated that the property of the brick surface might affect the binding of Cs-137 to the decontamination technology or the percentage of peeling. 6. References 1. U.S. Environmental Protection Agency (U.S. EPA). Bartlett Services, Inc. Stripcoat TLC FreeTM Radiological Decontamination Strippable Coating Technology Evaluation Report. U.S. Environmental Protection Agency, Cincinnati, OH. EPA/600/R-08/099, September 2008. 2. U.S. Environmental Protection Agency (U.S. EPA). Removing Radiological Contamination from Concrete Using Strippable Coatings, EPA Technical Brief. U.S. Environmental Protection Agency, Cincinnati, OH. EPA/660/S-08/021, October 2008. 3. U.S. Environmental Protection Agency (U.S. EPA). CBI Polymers DeconGel® 1101 and 1108 for Radiological Decontamination. U.S. Environmental Protection Agency, Cincinnati, OH. EPA 600/R- 11/084, August 2011. 4. U.S. Environmental Protection Agency (U.S. EPA). Evaluation of Nine Chemical-Based Technologies for Removal of Radiological Contamination from Concrete Surfaces. U.S. Environmental Protection Agency, Cincinnati, OH. EPA Technical Brief, August 2011. 5. U.S. Environmental Protection Agency (U.S. EPA). Decontamination of Cesium, Cobalt, Strontium, and Americium from Porous Surfaces. U.S. Environmental Protection Agency, Cincinnati, OH. EPA/600/R-13/232, November 2013. 6. U.S. Environmental Protection Agency (U.S. EPA). Technology Evaluation Report: Non-Destructive Decontamination Methodologies for Mixed Porous surfaces. U.S. Environmental Protection Agency, Cincinnati, OH. EPA/600/R-16/150 June 2016. 18 ------- Radiological Decontamination of Mixed Porous Surfaces: High Humidity and UV Conditions Date: 6/29/2020 E PA/600/R-20/125 Version: 0 7. U.S. Environmental Protection Agency (U.S. EPA). Evaluation of the Curing Times of Strippable Coatings and Gels as used for Radiological Decontamination. U.S. Environmental Protection Agency, Cincinnati, OH. EPA/600/R-14/238, September 2014. 8. U.S. Environmental Protection Agency (U.S. EPA). Technical Report for the Demonstration of Wide Area Radiological Decontamination and Mitigation Technologies for Building Structures and Vehicles. U.S. Environmental Protection Agency, Cincinnati, OH. EPA/600/R-16/019, 2016. 9. Craig S. Long, Alvin J. Miller, Hai-Tien Lee, Jeannette D. Wiid, Richard C. Przywarty, and Drusilla Hufford. [National Weather Service] Ultraviolet Index Forecast Vol. 77, No. 4, April 1996. 10. UV radiation monitoring: UV index and UV dose, http://www.temis.nl/uvradiation/info/ (accessed March 30, 2020). 11. U.S. EPA. Action Steps for Sun Protection, U.S. Environmental Protection Agency, Washington DC. EPA/430-F-99-026; September 1999. 12. U.S. EPA. Bartlett Services, Inc. StripcoatTLC Free™ Radiological Decontamination of Americium, U.S. Environmental Protection Agency, Cincinnati, OH. EPA 600/R-13/005, February 2013. 13. U.S. EPA. CBI Polymers DeconGel® 1108 for Radiological Decontamination of Americium, U.S. Environmental Protection Agency, Cincinnati, OH. EPA 600/R-12/067, January 2013. 19 ------- vvEPA United States Environmental Protection Agency PRESORTED STANDARD POSTAGE & FEES PAID EPA PERMIT NO. G-35 Office of Research and Development (8101R) Washington, DC 20460 Official Business Penalty for Private Use $300 ------- |