United States
Environmental Protection Agency
Office of Water
Office of Science and Technology
4304T
EPA-822R21001
February 2021
SERV
United States
Environmental Protection
Agency
Biennial Review of 40 CFR Part 503
as Required under the Clean Water
Act Section 405(d)(2)(C)
Biosolids Biennial Report N-8
(Reporting Period 2018-2019)
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Biosolids Biennial Review
Reporting Period 2018-2019
EPA-822R21001
Biennial Review of 40 CFR Part 503
as Required under the Clean Water Act Section
405(d)(2)(C)
Biosolids Biennial Report N-8
(Reporting Period 2018-2019)
U.S. Environmental Protection Agency
Office of Water
Office of Science and Technology
Washington, DC
February 2021
ii
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Biosolids Biennial Review
Reporting Period 2018-2019
NOTICE
This document has been reviewed in accordance with U.S. Environmental Protection Agency (EPA)
policy and approved for publication.
This document is not a regulation, nor does it change or substitute for any statutory provisions or
EPA regulations. Thus, it imposes no legally binding requirements on EPA, states, tribes, or the
regulated community. While EPA has made every effort to ensure the accuracy of the content of this
document, obligations of the regulated community continue to be determined by statutes, regulations,
or other legally binding requirements. In the event of a conflict between the discussion in this
document and any statute or regulation, this document would not be controlling. Mention of trade
names or commercial products does not constitute endorsement or recommendation for their use.
This document can be downloaded from EPA's website at http://www.epa.gov/biosolids.
Definition of Biosolids
For the purposes of this biennial review, "biosolids" is used to mean sewage sludge, as defined in
Title 40 of the Code of Federal Regulations (CFR) Part 503:
Sewage sludge is solid, semi-solid, or liquid residue generated during the treatment of domestic
sewage in a treatment works. Sewage sludge includes, but is not limited to, domestic septage; scum
or solids removed in primary, secondary, or advanced wastewater treatment processes; and a material
derived from sewage sludge. Sewage sludge does not include ash generated during the firing of
sewage sludge in a sewage sludge incinerator or grit and screenings generated during preliminary
treatment of domestic sewage in a treatment works (40 CFR ง 503.9(w)).
Terms in italics are defined as follows:
Domestic sewage is waste and wastewater from humans or household operations that is
discharged to or otherwise enters a treatment works (40 CFR ง 503.9(g)).
Industrial wastewater is wastewater generated in a commercial or industrial process (40 CFR
ง 503.9(n)).
Treatment works is either a federally owned, publicly owned, or privately owned device or
system used to treat (including recycle and reclaim) either domestic sewage or a combination
of domestic sewage and industrial waste of a liquid nature (40 CFR ง 503.9(aa)).
Taken together, these definitions mean that biosolids, or sewage sludge, for the purposes of 40 CFR
Part 503, are the residues from treatment of domestic sewage, whether that domestic sewage is
combined with industrial wastewater or not. It does not include sludge originating from treatment of
industrial wastes in the absence of domestic sewage.
in
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Biosolids Biennial Review
Reporting Period 2018-2019
Executive Summary
During the biennial review process, the U.S. Environmental Protection Agency (EPA) collected and
reviewed publicly available information for (1) pollutants in biosolids that were newly identified
during the literature search timeframe (2018-2019) for Biennial Report N-8; and (2) pollutants in
biosolids that were previously identified in EPA national sewage sludge surveys conducted in 1988,
2001, and 2009 and/or in previous biennial reviews. Information was collected on the occurrence,
fate and transport of these pollutants in the environment and their effects on human health and
ecological receptors. The types of information collected are needed to conduct risk assessments.
As a result of a literature search, EPA found 18 new articles that provide relevant data on chemical
pollutants that may occur in biosolids in the United States. The articles identified 116 new chemicals
in biosolids: 50 poly chlorinated biphenyls (PCBs) (39 congeners, 10 homologs and total PCBs); four
pesticides; 19 flame retardants; eight perfluoroalkyl substances (PFAS); three antibiotics; one metal;
two inorganics; and 29 other organics. The articles also identified new data for 48 chemicals that
were previously identified in biosolids. Concentration data for biosolids were found for 61 of the 116
new chemicals and for 34 chemicals identified in previous biennial reviews.
EPA searched additional data sources for data needed for risk assessment. Human health toxicity
values were found in multiple sources for four of the new chemicals and 112 previously identified
chemicals. Ecological toxicity data were found for 63 newly identified chemicals and 71 previously
identified chemicals in the ECOTOX database. Additional ecological toxicity data were found for 99
of the newly identified chemicals in the Estimation Programs Interface (EPI) Suite (U.S. EPA
2017). Physical-chemical properties were identified for 102 new chemicals and five previously
identified chemicals. Bioconcentration or bioaccumulation factors were identified for one new
chemical in the literature; for 99 new chemicals in EPI Suite; and for 40 new chemicals in peer-
reviewed databases maintained by Arnot and Gobas (2006), Environment and Climate Change
Canada (2006), and Oak Ridge National Laboratory (2020).
Two of the new articles provided relevant data for microbial pollutants that may occur in U.S.
biosolids. Review of these articles identified five new microbial pollutants in biosolids and data for
five previously identified microbial pollutants.
IV
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Biosolids Biennial Review
Reporting Period 2018-2019
Contents
NOTICE 111
Definition of Biosolids iii
Executive Summary iv
1 Introduction 1
2 Approach for the 2018-2019 Biennial Review 1
2.1 Two-Phase Literature Search and Review 2
2.2 Literature Identification and Review 4
2.2.1 Literature Search for Pollutant Occurrence 4
2.2.2 Occurrence Literature Selection and Review 5
2.3 Chemical Data Collection 6
2.3.1 Human Health Toxicity Value Sources and Selection 6
2.3.2 Ecological Toxicity Value Sources and Selection 7
2.3.3 Environmental Fate and Transport Data 8
3 Results from the 2018-2019 Biosolids Biennial Review 9
3.1 Chemicals Newly Identified in the 2018-2019 Biennial Review 10
3.2 Chemicals Identified in Previous Biennial Reviews 15
3.3 Microbial Pollutants Identified in the 2018-2019 Biennial Review 22
4 Conclusions 23
5 References 23
Appendix A Abstracts for Papers Reviewed for the 2018-2019 Biennial Review A-l
Appendix B Pollutants Identified in Biosolids B-l
Appendix C Concentrations of Chemicals Found in Biosolids C-l
Appendix D Human Health Toxicity Values for Chemicals Found in Biosolids D-l
Appendix E Ecological Toxicity Data E-l
Appendix F Environmental Fate and Transport Data: Bioaccumulation and Bioconcentration
Data F-l
Appendix G Environmental Fate and Transport Data: Physical-Chemical Properties G-l
Figures
Figure 1. Overview of the 2018-2019 Biennial Review Process 3
Tables
Table 1. Chemicals Newly Identified in Biosolids in the 2018-2019 Reporting Period and
Types of Data Available 11
Table 2. Previously Identified Chemicals with Data Found in the 2018-2019 Reporting Period
and Types of Data Available 16
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Biosolids Biennial Review Reporting Period 2018-2019
Table 3. Microbial Pollutants Identified during the Biosolids Biennial Review for the 2018-
2019 Reporting Period 22
VI
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Biosolids Biennial Review
Reporting Period 2018-2019
1 Introduction
Section 405(d) of the Clean Water Act (CWA) requires the U.S. Environmental Protection Agency
(EPA) to review sewage sludge regulations every two years to identify any additional pollutants that
may occur in biosolids and to set regulations for those pollutants if sufficient scientific evidence
shows they could harm, or present a risk to, human health or the environment. EPA's biennial review
process is intended to assist in fulfilling this CWA requirement. The data gleaned from the process
are analyzed to determine whether they are sufficient to be used for assessing potential risk. Reports
documenting the findings of the biosolids biennial reviews are posted to EPA's website for 2005
(Biennial Report N- 1), 2007 (Biennial Report Nฐ 2), 2009 (Biennial Report Nฐ 3), 2011 (Biennial
Report N- 4), 2013 (Biennial Report N- 5), 2015 (Biennial Report N- 6), and 2017 (Biennial Report
N- 7) (see https://www.epa.gov/biosolids/bientiial-reviews-sewage-sliidge-standards).
Once additional pollutants that may occur in biosolids are identified, EPA assesses the pollutants to
determine whether they pose a risk to human health or the environment. EPA is currently developing
a prioritization process and screening model to evaluate pollutants found in biosolids for potential
risk. The screening results will be used to make informed decisions about the need to perform more
refined risk assessments or to address data gaps or uncertainties. EPA is also developing a
probabilistic risk assessment modeling framework to conduct more refined assessments of pollutants
that fail the screening process.
Addressing potential risk from pollutants identified in biosolids is the top priority for EPA's
Biosolids Program. EPA continues to make significant progress in building capacity to assess
pollutants by developing the required tools and data, and expects to begin risk evaluations once
review of its screening model has been completed.
Biennial Report N- 8 provides the approach used and the results of EPA's 2018-2019 biosolids
biennial review.
2 Approach for the 2018-2019 Biennial Review
Every two years, EPA collects and reviews publicly available information about pollutants that have
been found in biosolids in the United States. The types of data gleaned from the biennial reviews and
presented here are needed to conduct risk assessments.
Occurrence and Concentration. Both the ability to detect a given pollutant in biosolids and
the determination of the concentration at which that pollutant is present are highly dependent
on the existence of analytical methods for the pollutant in the biosolids matrix.
Toxicity to Human Health. These data include values such as reference doses (RfDs),
reference concentrations (RfCs), cancer slope factors (CSFs), and inhalation unit risks
(IURs).
Toxicity to Ecological Receptors. These data include values such as lethal dose, lethal
concentration, and chronic endpoints related to survival, growth, and reproduction.
Environmental Fate and Transport. These data are necessary for assessing exposure and
include various physical-chemical properties as well as bioconcentration or bioaccumulation
factors (BCFs and BAFs, respectively), which describe the tendency of a chemical to move
from one medium (e.g., soil) to another (e.g., plant matter).
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2.1 Two-Phase Literature Search and Review
The 2018-2019 biennial review process consisted of a series of steps designed to effectively search
for and review data on chemical and microbial pollutants and was divided into the following phases
(Figure 1):
Phase 1. Search for Pollutant Occurrence. EPA conducted a search of open literature
published from January 2018 through December 2019 for papers that provided evidence of
the occurrence of chemical or microbial pollutants in biosolids in the United States and
Canada. EPA reported available concentration data for both newly found and previously
found chemicals in biosolids. EPA did not search the open literature for the 10 metals already
regulated under 40 CFRPart 503: arsenic, cadmium, chromium, copper, lead, mercury,
molybdenum, nickel, selenium, and zinc.
Phase 2. Searches for Data Collection. For newly identified chemicals found in biosolids,
EPA conducted additional literature searches not limited to 2018-2019 and collected data for
environmental fate and transport, and human health and ecological effects. For chemicals
previously found to occur in biosolids, based on EPA national sewage sludge surveys and
previous biennial reviews, EPA collected environmental fate and transport data if those data
also were included in literature identified in phase 1 of the 2018-2019 search. The literature
search for human toxicity data was not limited to 2018-2019 reporting period while the
literature search for ecological toxicity data was limited to 2018-2019. No additional
literature searches were conducted for microbial pollutants.
In the Phase 2 search, for newly identified chemicals, EPA typically does not limit the time period for
the search for human health toxicity data in the databases or for ecological toxicity information in the
ECOTOXicology knowledgebase (ECOTOX). Also, for data on chemicals previously identified in
past biennial reviews, data sources are searched within the 2018-2019 time period. For the 2018-
2019 biennial review, EPA took this approach for the ecological toxicity information search but took
a slightly different approach for the human health toxicity data search. For the 2018-2019 biennial
review, EPA updated the human toxicity data sources searched to be consistent with other human
health effects assessments conducted by the EPA's Office of Water. Therefore, for Biennial Report
N- 8we did not limit the review search period to 2018-2019 for human toxicity data for previously
identified chemicals.
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Biosolids Biennial Review
Reporting Period 2018-2019
PHASE 1; SEARCH FOR POLLUTANT OCCURRENCE
342 papers
273 papers eliminated
1 papers eliminated
INCLUI
PHASE 2; SEARCHES FOR DMA COLLECTION
MICROBIALS IDEN
(5 new, 5 previ-
*Data extraction and
further data collection to be
conducted in the future
ฆfill
116 chemicals
I
164 chemicals
ENTIFIEf)
48 chemicals
1
COLLECT DA
USING ONLINE SOURCES
Human Health Toxicity
Ecologic.il Toxicity
Figure 1. Overview of the 2018-2019 Biennial Review Process.
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Biosolids Biennial Review
Reporting Period 2018-2019
2.2 Literature Identification and Review
2.2.1 Literature Search for Pollutant Occurrence
EPA conducted a literature search for articles published in peer-reviewed, English language-based
journals. The search, conducted for the period of January 2018 through December 2019, focused on
identifying data published in electronically or print since the previous biennial review search period
ended in December 2017. The bibliographic databases searched for the current review included
ProQuest, PubMed, and Web of Science. Conference abstracts, reports, comments, letters, and
editorials were excluded.
For chemical pollutants, health-related keywords were combined with chemical-related keywords
and land application keywords. Geographical search terms were used to restrict the searches to
studies conducted in the United States and Canada. Asterisks at the end of a search term broadened
the search by returning results of that term with any relevant ending. Specifically, to be identified as
a candidate, a paper had to have at least one biosolids-related keyword, one chemical keyword, one
land application keyword, one health-related keyword, and one geographic keyword, based on the
following search strings:
Biosolids-related keywords, sewage sludge OR biosolids OR treated sewage OR sludge
treatment OR sewage treatment
AND
Land application-related keywords: land application OR farm OR agriculture OR soil
AND
Chemical-related keywords: pollutant* OR toxic* OR chemical OR constituent OR
contaminant* OR metal* OR dioxin* OR inorganic* OR organic* OR flame retardant* OR
pharmaceutical* OR steroid* OR hormone* OR antibiotic* OR (personal care product*)
AND
Property-related eywords: occurrence OR concentration OR effect* OR propert* OR fate OR
transport OR health
AND
Geographical keywords: United States OR Canada OR USA OR U.S.A. OR U.S. OR US
For microbial pollutants, health-related keywords were combined with microbial pollutant-related
keywords and land application keywords. Land-application keywords were retained because 40 CFR
ง 503.32(b)(5) includes site restrictions specific to land application of Class B biosolids that allow
time for environmental conditions to further reduce pathogen levels. Geographical search terms were
used to restrict the searches to studies conducted in the United States and Canada. Specifically, to be
identified as a candidate, a paper had to have at least one biosolids-related keyword, one land
application-related keyword, one microbial pollutant-related keyword, one property-related keyword,
and one geographic keyword, based on the following search strings:
Biosolids-related keywords: sewage sludge OR biosolids OR treated sewage OR sludge
treatment OR sewage treatment
AND
Land application-related keywords: land application OR farm OR agriculture OR soil
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AND
Microbial pollutant-related keywords: pathogen* OR Salmonella OR microb*
AND
Property-related keywords: occurrence OR concentration OR effect OR propert* OR fate OR
transport OR health
AND
Geographical keywords: United States OR Canada OR USA OR U.S.A. OR U.S. OR US
2.2.2 Occurrence Literature Selection and Review
For the papers identified in the chemical and microbial literature searches for the occurrence of
pollutants in biosolids (Phase 1), EPA first screened the citation titles and eliminated papers based on
their titles if it was possible to determine the papers did not provide relevant data for pollutants that
might occur in U.S. biosolids. Studies not related to biosolids or not conducted in the United States
or Canada were eliminated from further evaluation.
For the remaining papers, EPA reviewed their abstracts and eliminated papers based on the following
five criteria:
1. Endpoints are not pollutant-specific (i.e., overall effects of biosolids on plant growth, crop
yield, soil microbe community, or soil nutrients).
2. The medium evaluated is not primarily sewage sludge, as defined in 40 CFR Part 503,
including:
a. influent and effluent wastewater;
b. industrial sewage sludge (e.g., pulp and paper mill residuals);
c. activated carbon;
d. activated sludge;
e. biochar; and
f. biosolids compost.
3. Only an analytical method or effectiveness-of-treatment method is described and no data are
provided on pollutant concentration in biosolids.
4. The study was conducted outside of the United States, or Canada.
Finally, EPA reviewed the full text of remaining papers. During this review, additional papers were
eliminated based on the five exclusion criteria outlined previously. Papers were also eliminated based
on the following three criteria:
1. Only spiked concentration data were reported.
2. There was no evidence of the occurrence of new pollutants in biosolids AND no new data
were reported for previously identified chemicals.
3. The only reported data were for metals in biosolids that are already regulated (i.e., arsenic,
cadmium, chromium, copper, lead, mercury, molybdenum, nickel, selenium and zinc).
Appendix A provides abstracts of the papers retained after full-text review for chemical pollutants
(18 papers) and microbial pollutants (two papers).
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2.3 Chemical Data Collection
Information on pollutants in biosolids was collected on their occurrence and concentration, fate and
transport, and their human health and ecological effects. This section provides detailed information.
Appendix B provides a complete list of new and previously identified pollutants in biosolids.
2.3.1 Human Health Toxicity Value Sources and Selection
EPA uses human health effects information to assess the potential risk from pollutants that occur in
biosolids. Specifically, EPA uses RfD and RfC values to evaluate noncancer risk associated with oral
and inhalation exposures, respectively. Oral CSF and IUR values are used to evaluate risk from
carcinogens associated with oral and inhalation exposures, respectively. These four values were
searched for and obtained for existing and newly identified chemicals found in biosolids during this
review for Biennial Report Nฐ 8. The search for human toxicity data was not time-limited for this
biennial review.
EPA's Integrated Risk Information System (IRIS) is considered the preferred source for human
health toxicity values for most EPA risk assessments and was the primary source of toxicity values
for this review (U.S. EPA 2020a).
IRIS does not contain toxicity values for all chemicals and some chemicals with a toxicity value in
IRIS do not necessarily have all four of the values EPA uses for risk assessments (RfD, RfC, CSF,
and IUR) Therefore, EPA conducted a search of peer-reviewed, publicly available sources to obtain
oral toxicity values (RfD or CSF) and the inhalation toxicity values (RfC or IUR) for potential use in
biosolids risk assessments. EPA also searched for toxicological assessments from EPA program
offices, other national and international programs, and state programs. The following data sources
were searched:
Human Health Benchmarks for Pesticides (HHBPs): EPA Office of Pesticide Programs
risk assessments for pesticides using health effects data submitted during the pesticide
registration process (U.S. EPA 2020b).
Provisional Peer-Reviewed Toxicity Values (PPRTVs) PPRTVs are peer reviewed toxicity
values that address chronic and sub-chronic exposure. EPA's Office of Research and
Development (ORD) develops PPRTVs in support of EPA's Superfund Program. (U.S. EPA
2020c).
Health Effects Support Documents (HESDs): EPA's Office of Science and Technology
(within EPA's Office of Water) develops toxicity values for chemicals in drinking water in
these peer-reviewed documents (U.S. EPA 2020e).
Agency for Toxic Substances and Disease Registry (ATSDR): ATSDR develops oral and
inhalation minimum risk levels (MRLs) that are oral noncancer toxicity values equivalent to
RfDs and RfCs, respectively (ATSDR 2020).
California Environmental Protection Agency (CalEPA): CalEPA develops reference
exposure levels that are noncancer toxicity values equivalent to RfDs or RfCs, and cancer
potency factors that are equivalent to CSFs or IURs (CalEPA 2015).
Health Canada: Health Canada develops guidelines and technical documents with tolerable
daily in-take values that are noncancer toxicity values used in risk evaluation (Health Canada
2020).
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2.3.2 Ecological Toxicity Value Sources and Selection
To evaluate the potential for ecological risks from biosolids, EPA assesses direct contact and
ingestion pathways for aquatic and terrestrial species. For the direct contact exposure pathway,
species assemblages (or communities) are assessed in soil, sediment, and surface water where they
are assumed to be exposed through direct contact with the contaminated medium. For the ingestion
pathway, species are assumed to ingest contaminated food and prey from biosolids-treated
agricultural fields and from farm ponds that receive runoff from biosolids-treated fields. The
ecological toxicity values are expressed in terms of media concentration (e.g., milligrams [mg] per
liter [L] for surface water and mg/kilograms [kg] for soil) for the direct contact pathway and in terms
of dose (mg/kg/day) for the ingestion pathway.
ECOTOXicology Knowledgebase (ECOTOX)
ECOTOX (U.S. EPA 2020d) is a comprehensive database providing single chemical environmental
toxicity data on aquatic life, terrestrial plants and wildlife. For known chemicals, the search was
limited to data added to ECOTOX from studies published in 2018-2019. For newly identified
chemicals in biosolids, the search was not time-limited.
To be included in ECOTOX, studies must meet the following ECOTOX applicability criteria:
The toxic effects are related to single-chemical exposure.
A biological effect on live, whole organisms is reported.
Chemical test concentrations are reported.
There is an explicit duration of exposure.
Toxicology information is reported for the chemical of concern.
The paper is published in the English language.
The paper is available as a full article (not an abstract).
The paper is publicly available.
The paper is the primary source of the data.
A calculated endpoint is reported or can be calculated using reported or available
information.
Treatment(s) are compared to an acceptable control.
The location of the study (e.g., laboratory versus field) is reported.
The tested species is reported (with recognized nomenclature).
EPA considered studies from the open literature papers in ECOTOX potentially relevant for
inclusion in its risk assessments.
Ecological Structure Activity Relationships
EPA also searched for ecotoxicity data in the Estimation Programs Interface (EPI Suite), a group of
physical-chemical property and environmental fate estimation programs developed by EPA and
Syracuse Research Corporation (U.S. EPA 2017). EPI Suite contains predicted values generated by
the Ecological Structure Activity Relationships (ECOSAR) program (U.S. EPA 2017). EPA
extracted the following ECOSAR data for this biennial review for newly identified chemicals:
Chemical class
Organism common name
Duration
Endpoint
Predicted value
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For previously identified chemicals, no new data were available in EPI Suite; it was last updated in
2017. Data contained in EPI Suite prior to 2017 were captured in the 2016-2017 biennial review
process for Biennial Report N2 7.
2.3.3 Environmental Fate and Transport Data
EPA uses risk assessment models that require physical-chemical properties and transfer factors to
estimate the potential for chemical transport and uptake from agricultural lands amended with
biosolids.
Physical-Chemical Properties
EPA's preferred source for physical-chemical properties is EPI Suite, (U.S. EPA 2017). It uses
available physical-chemical inputs to estimate physical-chemical properties and bioconcentration
factors (BCFs)bioaccumulation factors (BAFs). EPI Suite sometimes uses more than one method to
estimate a property. In some of these cases, results for both methods were extracted. Physical-
chemical properties extracted from EPI Suite for chemicals newly identified during this biennial
review include the following:
Molecular weight
Solubility
- Method 1: based on log Kow
- Method 2: estimated using a "fragment constant" method
Vapor pressure
Henry's law constant
- Method 1: group contribution
- Method 2: bond contribution
Log octanol-water partition coefficients (log Kow)
Soil-water partition coefficient (Koc)
- Method 1: Sabljic molecular connectivity method
- Method 2: based on log Kow
Degradation rates in air, water, and soil
Air overall OH degradation rate constant
Air overall ozone degradation rate
Air fraction sorbed to airborne particulates
- Method 1: Junge-Pankow/Mackay average
- Method 2: based on Koa
Fugacity in air, water, and soil
Advection in air, water, and soil
EPA also searched for and extracted data from the Oak Ridge National Laboratory (ORNL) Risk
Assessment Information System (RAIS) database (ORNL 2020) for several additional parameters
that are not available in EPI Suite. These parameters include the following:
Diffusivities in air and water
Soil-water partition coefficient (Kd)
Organic carbon partition coefficient (Foc)
Uptake and Transfer Factors
For many organic chemicals, the plant and animal product uptake and transfer factors can be
estimated using empirical relationships between the transfer factor and log Kow. BCFs are preferred
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over estimated transfer factors if available. If some physical-chemical property data were available,
fish BCFs and BAFs were estimated using EPI Suite, and the following data were searched for and
extracted during this biennial review:
Log BCF (regression-based estimate)
Log BCF and BAF (Arnot-Gobas upper, mid, and lower trophic; Arnot and Gobas 2006)
EPA also searched for and extracted species-specific, field-measured BAFs and laboratory-measured
BCFs from two peer-reviewed, publicly available databasesArnot and Gobas (2006) and
Environment and Climate Change Canada (2006)as well as bioaccumulation values published by
ORNL (2020). These sources are routinely used by EPA in risk-based assessments. These data
included the following:
Log BCF or BAF
Organism scientific name
Organism common name
The ORNL RAIS database (ORNL 2020) contains additional uptake and transfer data, which were
also searched for and extracted. These include the following:
Diffusivities in air and water
Soil-to-dry plant uptake
Soil-to-wet plant uptake
Beef transfer coefficient
Milk transfer coefficient
Soil-water partition coefficient (Kd)
Organic carbon partition coefficient (Foc)
3 Results from the 2018-2019 Biosolids Biennial Review
During the 2018-2019 biennial review, EPA identified 18 articles that met the eligibility criteria for
chemicals. Review of these articles identified 116 new chemicals that occur in biosolids (see Table
1): 50 polychlorinated biphenyls (PCBs) (39 congeners, 10 homologs, and total PCB); four
pesticides; 19 flame retardants; eight perfluoroalkyl substances (PFAS); three antibiotics; one metal;
two inorganics; and 29 other organics. These articles also provided new or additional data on 48
previously identified chemicals (see Table 2). Of the 18 papers, 12 identified or provided data on
new chemicals and 15 provided data on previously identified chemicals. Abstracts for all the articles
are provided in Appendix A. Data identified from all sources EPA reviewed include the following:
Concentration data for 61 newly identified chemicals and 34 previously identified chemicals
(see Appendix C).
Human health toxicity data for four newly identified chemicals and 112 previously identified
chemicals (see Appendix D).
ECOTOX records for 63 newly identified chemicals and 71 previously identified chemicals
(see Appendix E).
ECOSAR toxicity data for 99 newly identified chemicals (see Appendix E).
BAFs and BCFs for 99 newly identified chemicals (see Appendix F).
Physical-chemical property data for 102 newly identified chemicals and five previously
identified chemicals (see Appendix G).
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3.1 Chemicals Newly Identified in the 2018-2019 Biennial Review
Table 1 lists the 116 chemicals newly identified as occurring in biosolids in the 2018-2019 biennial
review1.
Concentration data for 61 newly identified chemicals were extracted from the reviewed literature.
These data are provided in Appendix C. Additional chemicals were detected in biosolids, but
concentration values were not extracted because either the values were reported only in graphical
form, the values were tentatively identified values, or the occurrence of the chemical was noted in the
paper but concentration data were not provided. The chemicals for which concentration values were
not collected include 55 newly identified chemicals (39 PCB congeners, 10 PCB homologs, and six
PFAS).
Human health toxicity values were found for four chemicals newly identified in biosolids during this
review period. Data were found in four different sources (ATSDR, CalEPA, IRIS, and PPRTV).
These values are reported in Appendix D.
Ecotoxocoty data were found in published studies for 63 newly identified chemicals in ECOTOX
(U.S. EPA 2020d). The results are presented in Appendix E, Table E-l. These papers will require
further evaluation for relevance for inclusion in risk assessments.
Ecotoxicity data from EPI Suite were identified for 99 newly identified chemicals. These values are
provided in Appendix E, Table E-3.
BAFs were available from the papers reviewed for one of the newly identified chemicals. These
values are provided in Table F-l in Appendix F. BAFs and BCFs were reported by trophic level for
99 of the newly identified chemicals in EPI Suite, but the values are not species-specific. They are
provided in Table F-2 in Appendix F. Additionally, species-specific, field-measured BAFs and
laboratory-measured BCFs were found in peer-reviewed databases published by Arnot and Gobas
(2006), Environment and Climate Change Canada (2006), and ORNL (2020) for 40 of the newly
identified chemicals; these data are provided in Tables F-l and F-3.
Table G-l in Appendix G presents the physical-chemical properties for 31 of the newly identified
chemicals as obtained from the papers reviewed.
1 Table 1 includes 39 PCB congeners, 10 PCB homologs, and total PCBs, which were reported in
Needham and Ghosh 2019. Needham and Ghosh (2019) used an adapted version of U.S. EPA SW-
846 method 8082A for PCB analysis which provides procedures for determining a selected group of
the 209 possible PCB congeners representing the most common congeners historically used in
Aroclor commercial mixtures. They measured 129 commonly detected PCB congeners in their study,
of which some were reported as the sum of two congeners per method 8082A. Total PCB
concentrations were calculated as the sum of the PCB congeners/congener groups representing the
most common congeners historically used in the Aroclor commercial mixtures detected using method
8082A. Additionally, the authors reported concentrations of 10 PCB homologs detected in biosolids
using their results from method 8082A. Some of the PCB congeners in Table 2 are also part of the
PCB homologs and total PCB, and thus they could be considered triple counted.
10
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Additionally, physical-chemical properties were extracted from EPI Suite and ORNL for 99 of the
newly identified chemicals, and are provided in Tables G-2 through G-5 in Appendix G. As
described in Section 2.2.3, no new data for previously identified chemicals were available.
Table 1. Chemicals Newly Identified in Biosolids in the 2018-2019 Reporting Period and Types of
Data Available
Chemical
CAS number
Category
Concentra-
tion
Human
health
Ecological
toxicity
Environmental
fate and
data
toxicity
data
data
transport data
2,2',3,3',4,4',5,6'-
Octachlorobiphenyl
42740-50-1
PCB
X
X
1
K
2,2',3,3',4,4',5-
Heptachlorobiphenyl
35065-30-6
PCB
X
X
H 1
K M N
2,2',3,3',4,4'-Hexachlorobiphenyl
38380-07-3
PCB
X
X
H 1
K M
2,2',3,3',4,5',6,6'-
Octachlorobiphenyl
40186-71-8
PCB
X
X
1
K M
2,2',3,3',4,5-Hexachlorobiphenyl
55215-18-4
PCB
X
X
1
K
2,2',3,3',4,6-Hexachlorobiphenyl
61798-70-7
PCB
X
X
1
K
2,2',3,3',5,5',6-
Heptachlorobiphenyl
52663-67-9
PCB
X
X
1
K
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
PCB
X
X
1
K M
2,2',3,4,4',5,5',6-
Octachlorobiphenyl
52663-76-0
PCB
X
X
1
K M
2,2',3,4,4',5,5'-
Heptachlorobiphenyl
35065-29-3
PCB
X
X
H 1
K M N
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
PCB
X
X
H 1
K M
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
PCB
X
X
1
K M
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
PCB
X
X
H 1
K M
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
PCB
X
X
1
K M
2,2',3,5-Tetrachlorobiphenyl
70362-46-8
PCB
X
X
1
K
2,2',3,6-Tetrachlorobiphenyl
70362-45-7
PCB
X
X
1
K
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
PCB
X
X
H 1
K M
2,2',4,4'-Tetrachlorobiphenyl
2437-79-8
PCB
X
X
H 1
K M
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
PCB
X
X
H 1
K M
2,2',4,5'-Tetrachlorobiphenyl
41464-40-8
PCB
X
X
H 1
K M
2,2',4,5-Tetrachlorobiphenyl
70362-47-9
PCB
X
X
H 1
K
2,2',4,6'-Tetrachlorobiphenyl
68194-04-7
PCB
X
X
1
K
2,2',5,5'-Tetrachlorobiphenyl
35693-99-3
PCB
X
X
H 1
K M
2,2',6-T richlorobiphenyl
38444-73-4
PCB
X
X
H 1
K
2,2-Bis(chloromethyl)-1,3-
propanediyl tetrakis(2-chloroethyl)
38051-10-4
Other organics
X
H 1
J K
ester phosphoric acid
11
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS number
Category
Concentra-
tion
data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
2,2'-Dichlorobiphenyl
13029-08-8
PCB
X
X
H 1
K M
2,3,3',4,4',5,6-
Heptachlorobiphenyl
41411-64-7
PCB
X
X
H 1
K
2,3,3',4,4',6-Hexachlorobiphenyl
74472-42-7
PCB
X
X
1
K
2,3,3',4',5,6-Hexachlorobiphenyl
74472-44-9
PCB
X
X
1
K
2,3',4,4'-Tetrachlorobiphenyl
32598-10-0
PCB
X
X
1
K M
2,3,4'-T richlorobiphenyl
38444-85-8
PCB
X
X
H 1
K M
2,3,6-T richlorobiphenyl
55702-45-9
PCB
X
X
1
K
2,3',6-T richlorobiphenyl
38444-76-7
PCB
X
X
1
K
2,3-Dichiorobipheny
16605-91-7
PCB
X
X
H 1
K M
2,4',5-T richlorobiphenyl
16606-02-3
PCB
X
X
H 1
K M
2,4,6-Tris(tert-butyl)phenol (2,4,6-
TTBP)
732-26-3
Other organics
V
X
H 1
K L M
2,4'-Dichlorobiphenyl
34883-43-7
PCB
X
X
H 1
K M
2,4-Di-tert-butylphenol (2,4-DTBP)
96-76-4
Other organics
>/
X
1
K L
2,4-Di-tert-pentylphenol (2,4-
DTPP)
120-95-6
Other organics
X
1
K
2,5-Di-tert-butylphenol (2,5-DTBP)
5875-45-6
Other organics
X
1
K L M
2,6-Dichlorobiphenyl
33146-45-1
PCB
X
X
1
K
2-Butoxy-, hydrogen phosphate
ethanol
14260-97-0
Other organics
X
1
J K
2-Chlorobiphenyl
2051-60-7
PCB
X
X
H 1
K
2-Ethylhexyl diphenyl phosphate
1241-94-7
Flame
retardant
X
H 1
J K L M
2H,2H,3H,3H-Perfluorooctanoic
acid
914637-49-3
PFAS
X
H
X
2-Hydroxy-N-(2-hydroxyethyl)-
N,N-dimethyl-ethanaminium
esters with C16-18 and C18-
unsatd. fatty acids, chlorides
(DEEDMAC)
1079184-43-2
Other organics
V
X
X
X
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,1
1,11,12,12,12-
Henicosafluorododecyl
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,1
O-heptadecafluorodecyl hydrogen
phosphate
1158182-60-5
PFAS
V
X
X
X
3,4,4'-T richlorobiphenyl
38444-90-5
PCB
X
X
H 1
K
3,5-Bis( 1,1 -dimethylethyl)-4-
hydroxy-, 2,4-bis(1,1-
4221-80-1
Other organics
X
1
K
12
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS number
Category
Concentra-
tion
data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
dimethylethyl)phenyl ester benzoic
acid
4,4'-Thiobis(6-tert-butyl-m-cresol)
(A044S25)
96-69-5
Other organics
~
X
1
K
4,4'-Methylenebis(2,6-di-t-
butylphenol) (AO-702)
118-82-1
Other organics
~
X
1
K
4,4',4"-( 1 -Methyl-1 -propanyl-3-
ylidene)tris 2-(1,1 -dimethylethyl)-
5-methyl-phenol
1843-03-4
Other organics
~
X
1
K
4-Chlorobiphenyl
2051-62-9
PCB
X
X
H 1
K N
4-(Butan-2-yl)-2,6-di-tert-
butylphenol
17540-75-9
PFAS
>/
X
1
K
6:2 Fluorotelomer phosphate
diester
57677-95-9
PFAS
X
X
H
X
6:2 Fluorotelomer sulfonic acid
27619-97-2
PFAS
X
X
H 1
K
6:2/8:2 Fluorotelomer phosphate
diester (diPAPs)
943913-15-3
PFAS
X
X
X
X
8:2 Fluorotelomer phosphate
diester
678-41-1
PFAS
X
X
H
X
8:2 Fluorotelomer sulfonic acid
39108-34-4
PFAS
X
X
1
K
Ammelide
645-93-2
Other organics
~
X
1
J K
Ammeline
645-92-1
Other organics
X
H 1
J K
Amoxicillin
26787-78-0
Antibiotic
X
H 1
K
Ampicillin
69-53-4
Antibiotic
>/
X
H 1
K
Bis( 1,3-dichloropropan-2-yl)
hydrogen phosphate
72236-72-7
Flame
retardant
>/
X
X
J
Bis(1 -cloropropan-2-yl) hydrogen
phosphate
789440-10-4
Flame
retardant
X
X
X
Bis(2-chloroethyl) phosphate
3040-56-0
Other organics
X
1
J K
Bis(2-ethylhexyl) phosphate
298-07-7
Other organics
X
H 1
J K L M
Bis(2-methylphenyl) hydrogen
phosphate
35787-74-7
Other organics
>/
X
1
J K
Bisphenol A bis(diphenyl
phosphate) (BDP)
5945-33-5
Other organics
X
X
J
Cesium
7440-46-2
Metals
V
X
H
K
Cresyl diphenyl phosphate
(CDPP)
26444-49-5
Flame
retardant
~
X
H 1
J K L M
Cyanuric acid
108-80-5
Other organics
>/
X
H 1
J K
Decachlorobiphenyl
2051-24-3
PCB
X
X
H 1
K M
Dibutyl ester phosphoric acid
107-66-4
Other organics
~
X
H 1
J K
13
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS number
Category
Concentra-
tion
data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
Dichlorobiphenyl
25512-42-9
PCB
X
X
1
K M
Diethyl hydrogen phosphate
598-02-7
Flame
retardant
X
H 1
J K
Diisobutyl hydrogen phosphate
6303-30-6
Other organics
X
1
J K
Diphenyl phosphate (DPHP)
838-85-7
Other organics
<~
X
1
J K
Dipropyl ester phosphoric acid
1804-93-9
Other organics
~
X
1
J K
Fipronil amide
205650-69-7
Pesticides
>/
X
H
X
Fipronii desulfinyi
205650-65-3
Pesticides
V
X
H
X
Fipronil sulfide
120067-83-6
Pesticides
~
X
H
X
Fipronil sulfone
120068-36-2
Pesticides
>/
X
H
X
Heptachlorobiphenyl
28655-71-2
PCB
X
X
1
K
Hexachlorobiphenyl
26601-64-9
PCB
X
X
H 1
K M
Isodecyl diphenyl phosphate
(IDDP)
29761-21-5
Flame
retardant
~
X
H 1
JKLMN
Melamine
108-78-1
Other organics
X
H 1
J K L M
Monochlorobiphenyl
27323-18-8
PCB
X
X
H 1
K
Nalidixic acid
389-08-2
Antibiotic
V
X
H 1
K
Nonachlorobiphenyl
53742-07-7
PCB
X
X
1
K
Octachlorobiphenyl
55722-26-4
PCB
X
X
H 1
K
Pentachlorobiphenyl
25429-29-2
PCB
X
X
H 1
K
Polycarbonate (PC)
25766-59-0
Other organics
X
X
X
Polychlorinated biphenyl (PCB)
1336-36-3
PCB
V
A E F
H 1
JKMN
Polyethylene terephthalate (PET)
25038-59-9
Other organics
>/
X
X
X
Resorcinol bis(diphenyl
phosphate) (RDP)
57583-54-7
Flame
retardant
X
H 1
J K
Sodium perfluorodecanesulfonate
(PFDS)
2806-15-7
PFAS
X
X
X
X
Sulfate
14808-79-8
Inorganics
V
X
1
K
Sulfur
7704-34-9
Inorganics
V
X
H
K N
Terephthalic acid (TPA)
100-21-0
Other organics
~
X
X
X
Tert-butylphenyl diphenyl
phosphate
56803-37-3
Flame
retardant
~
X
H 1
JKL
Tetrabutyl ethylidenebisphenol
(A022E46)
35958-30-6
Other organics
V
X
1
K
Tetrachlorobiphenyl
26914-33-0
PCB
X
X
H 1
K M
Tributyl phosphate
126-73-8
Flame
retardant
V
c
H 1
JKLMN
14
-------
Biosolids Biennial Review Reporting Period 2018-2019
Chemical
CAS number
Category
Concentra-
tion
data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
Trichlorobiphenyl
25323-68-6
PCB
X
X
1
K M
Triethyl phosphate (TEP)
78-40-0
Flame
retardant
V
X
H 1
J K L M
Triethylene glycol bis(3-tert-butyl-
4-hydroxy-5-
methylphenyl)propionate (AO-245)
36443-68-2
Other organics
V
X
1
K
Triisobutyl phosphate
126-71-6
Flame
retardant
>/
X
H 1
J K
Trimethyl phosphate (TMP)
512-56-1
Flame
retardant
c
H 1
J K L M N
Trimethylsilanol (TMS)
1066-40-6
Other organics
X
1
K
Tripropyl phosphate
513-08-6
Flame
retardant
X
H 1
J K
Tris( 1,3-dichloro-2-propyl)
phosphate (TDCIPP)
13674-87-8
Flame
retardant
X
H 1
J K L M N
T ris(2-chloroisopropyl) phosphate
13674-84-5
Flame
retardant
~
c
H 1
J K L M N
Tris(2-ethylhexyl) phosphate
(TEHP)
78-42-2
Flame
retardant
c
H 1
J K L M N
T ris(4-tert-butylphenyl) phosphate
78-33-1
Flame
retardant
~
X
1
J K
Tris(methylphenyl) phosphate
1330-78-5
Flame
retardant
X
H 1
J K
>/ = Literature data (Table C-1)
X = No data were found
A = IRIS (Table D-1)
B = HHBP (Table D-2)
C = PPRTV (Table D-3)
D = HESD (Table D-4)
E = ATSDR (Table D-5)
F = CalEPA (Table D-6)
G = Health Canada (Table D-7)
H = ECOTOX (Table E-1)
I = ECOSAR values in EPI Suite (Table E-3)
J = Literature (Tables F-1, G-1)
K = EPI Suite (Tables F-2, G-2, G-3, G-4)
L = Environment and Climate Change Canada
(BCF/BAF only) (Table F-1)
M = Arnot and Gobas (BCF/BAF only) (Table F-1)
N = ORNL RAIS (Tables F-3, G-5)
3.2 New data for Chemicals Identified in Previous Biennial Reviews
In addition to reporting newly identified chemicals in biosolids, EPA reviewed the literature for new
(i.e., published after the previous biennial review period January 2016-December 2017)
concentration data, physical-chemical properties, human health and ecological toxicity data, and
environmental fate and transport data for chemical pollutants previously identified in biosolids.
Appendix B provides a complete list of these chemicals. Table 2 shows previously identified
chemicals for which new data were found, along with the types of data available for the chemicals.
Concentration data for 34 previously identified chemicals were available in the reviewed literature.
These data are provided in Appendix C. Additional chemicals were detected in biosolids, but
concentration values were not collected because either the concentration values were reported only in
graphical form, the values were tentatively identified values, or the occurrence of the chemical was
15
-------
Biosolids Biennial Review
Reporting Period 2018-2019
noted in the paper but concentration data were not provided. The chemicals for which concentration
values were not collected include 14 previously identified chemicals (12 PFAS and two PCBs).
All seven sources EPA reviewed (ATSDR, CalEPA, Health Canada, HESD, HHBP, IRIS, and
PPRTV) contained one or more human health toxicity value for 112 previously identified chemicals.
These values are reported in Appendix D.
Papers published in ECOTOX (U.S. EPA 2020d) from 2018-2019 were found for 71 previously
identified chemicals. The results are presented in Appendix E, Table E-2. These papers will require
further evaluation for relevance for inclusion in risk assessments.
Table G-l in Appendix G presents the physical-chemical properties for five of the previously
identified chemicals as obtained from the papers reviewed.
There were no new data available since the last reporting period (i.e., after 2017) from the following
sources: EPI Suite (U.S. EPA 2017), ORNL (2020), Arnot and Gobas (2006), and Environment and
Climate Change Canada (2006).
Table 2. Previously Identified Chemicals with Data Found in the 2018-2019 Reporting Period and
Types of Data Available
Chemical
CAS
Category
Concentra-
Human
Ecological
Environmental
number
tion data
health
toxicity
data
toxicity
data
fate and
transport data
(+/-)-Verapamil
52-53-9
Drugs
X
X
H
X
1-(p-Chlorobenzoyl)-5-methoxy-2-
methyl-lndole-3-acetic acid
53-86-1
Drugs
X
X
H
X
1,2,3,4,6,7,8,9-
Octabromodibenzofuran
103582-29-2
Dioxins/Furans
X
X
X
X
1,2,3,4,6,7,8-
Heptabromodibenzofuran
107555-95-3
Dioxins/Furans
X
X
X
X
1,2,3,4,6,7,8-
Heptachlorodibenzodioxin
35822-46-9
Dioxins/Furans
X
F
X
X
1,2,3,4,7,8,9-
Heptachlorodibenzofuran
55673-89-7
Dioxins/Furans
X
F
X
X
1,2,3,4,7,8-
Hexachlorodibenzodioxin
39227-28-6
Dioxins/Furans
X
F
X
X
1,2,3,4,7,8-
Hexachlorodibenzofuran
70648-26-9
Dioxins/Furans
X
X
X
X
1,2,3,6,7,8-
Hexachlorodibenzofuran
57117-44-9
Dioxins/Furans
X
F
X
X
1,2,3,6,7,8-Hexachlorodibenzo-p-
dioxin
57653-85-7
Dioxins/Furans
X
A F
X
X
1,2,3,7,8,9-Hexachlorodibenzo-p-
dioxin
19408-74-3
Dioxins/Furans
X
A F
X
X
1,2,3,7,8-Pentabromodibenzo-p-
dioxin
109333-34-8
Dioxins/Furans
X
X
X
X
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
Dioxins/Furans
X
F
X
X
1,3-Dichlorobenzene
541-73-1
Volatile organic
X
E
X
X
16
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS
number
Category
Concentra-
tion data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
1,4-Dichlorobenzene
17beta~Estradiol
106-46-7
50-28-2
Volatile organic
Drugs
X
X
A E F
X
X
X
H
H
X
X
A E
H
2,2',4,4',5,5'-Hexabromodiphenyl
ether
68631-49-2
PBDEs
X
A
X
X
E
X
2,2',4,4'-Tetrabroinodiphenyl ether
5436-43-1
PBDEs
X
X
F
H
X
X
2,3,3',4,4',5'-Hexachlorobipheriyl
2!3,3'!4,4'-Pentachiorobiphenyl
69782-90-7
32598-14-4
PCB
PCB
X
X
F
F
F
XXX
X X
2,3,4,4',5-Pentachlorobiphenyl
74472-37-0
PCB
X
F
F
F
XXX
X
2',3,4,4',5-Pentachlorobiphenyl
65510-44-3
PCB
X
F
X
X
X
X
2,3,4,6,7,8-
Hexachlorodibenzo[b,d]furan
2,3,7,8-Tetrachlorodibenzofuran
60851-34-5
51207-31-9
Dioxins/Furans
Dioxins/Furans
X X
F
E F
F
A E F
X
X
X
H
X
X
2,4,5-T richlorophenol
95-95-4
Pesticides
X
A C
ACE
G
X
X
X
2,4-Dichlorophenoxyacetic acid
94-75-7
Pesticides
X
A
H
X
2-Methylnaphthalene
3,3',4,4',5,5'-Hexachlorobiphenyl
91-57-6
32774-16-6
Other organics
PCB
X X
A C
A C
X
F
X X X X
X X
3,3',4,4'-Tetrachlorobiphenyl
32598-13-3
PCB
X
F
X
X
17
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS
number
Category
Concentra-
tion data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
3,3',5,5'-Tetrabromobisphenol A
79-94-7
Flame retardant
X
X
H
X
3.4.4',5-Tetrachlorobiphenyl
70362-50-4
PCB
X
F
X
X
4-( 1,1,3,3-T etramethylbutyl)phenol
140-66-9
Other organics
X
X
H
X
4-Chloroaniline
106-47-8
Other organics
X
A C
X
X
Acetaminophen
103-90-2
Drugs
X
X
H
X
Acetic acid
64-19-7
Drugs
X
X
H
X
Acetone
67-64-1
Volatile organic
X
A E
H
X
Acetophenone
98-86-2
Drugs
X
A C
H
X
Aluminum
7429-90-5
Metals
V
C E
X
X
Ammonium
14798-03-9
Inorganics
<~
X
X
X
Anhydroerythromycin A
23893-13-2
Drugs
X
X
X
X
Anthracene
120-12-7
PAHs
X
ACE
X
X
Antimony
7440-36-0
Metals
X
AEG
X
X
Arsenic
7440-38-2
Metals
X
A E F
X
X
Aspirin
50-78-2
Drugs
X
X
H
X
Azithromycin
83905-01-5
Antibiotic
<~
X
X
~
Barium
7440-39-3
Metals
>/
AEG
X
X
Benz(a)anthracene
56-55-3
PAHs
X
C F
H
X
Benzo(a)pyrene
50-32-8
PAHs
X
A F G
H
X
Benzo(b)fluoranthene
205-99-2
PAHs
X
F
H
X
Benzo(k)fiuoranthene
207-08-9
PAHs
X
F
X
X
Benzoic acid
65-85-0
Pesticides
X
A C
X
X
Beryllium
7440-41-7
Metals
>/
E F
X
X
Bisphenol A
80-05-7
Drugs
V
A
H
X
Boron
7440-42-8
Inorganics
A D E
G
X
X
Butylated hydroxytoluene
128-37-0
Other organics
~
C
H
X
Butylparaben
94-26-8
Antimicrobial
X
X
H
X
Cadmium
7440-43-9
Metals
V
A E F
X
X
Caffeine
58-08-2
Drugs
X
X
H
X
Calcium
7440-70-2
Metals
~
X
X
X
Carbamazepine
298-46-4
Drugs
X
X
H
X
18
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Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS
number
Category
Concentra-
tion data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
Carbon tetrachloride
56-23-5
Volatile organic
X
A E F
G
X
X
A E F
H
Chromium
7440-47-3
Metals
~
X
X
X
F
X
Ciprofloxacin
85721-33-1
Antibiotic
V
X
X
~
X
H
Clotrimazole
23593-75-1
Drugs
X
X
H
X
X
H
Cobalt
7440-48-4
Metals
~
C E
X
X
E F G
X
Cyanide
57-12-5
Inorganics
X
A F
X
X
X
H
DEET
134-62-3
Pesticides
X
E
X
X
A E F
H
Dibutyl phthaiate
84-74-2
Other organics
X
A
H
X
A F G
H
Diclofenac
15307-86-5
Drugs
X
X
H
X
G
H
Dimethyl phthaiate
131-11-3
Other organics
X
X
H
X
C E
H
Erythromycin
114-07-8
Antibiotic
~
X
X
X
A E F
G
X
Ethylparaben
120-47-8
Antimicrobial
X
X
H
X
X
H
Fluoranthene
206-44-0
PAHs
X
A C
X
X
Furosemide
54-31-9
Drugs
X
X
H
X
Heptachlor epoxide B
1024-57-3
Pesticides
X
A
X
X
ibuprofen
15687-27-1
Drugs
X
X
H
X
19
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Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS
number
Category
Concentra-
tion data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
Lead
7439-92-1
Metals
X
F
X
X
X
X
Manganese
7439-96-5
Metals
ซ~
A D E
F G
X
X
A E F
G
X
Methylparaben
99-76-3
Other organics
X
X
A E
H
X
X
m-Xylene
108-38-3
Volatile organic
X
F G
A D E
F
X
H
X
Nickel
7440-02-0
Metals
X
A E F
A E
X
X
X
Nitrite
14797-65-0
Inorganics
V
A E
C
X
X
X
Nitrogen
7727-37-9
Inorganics
~
X
X
X
A F
X
N-Nitrosodiethylamine
55-18-5
Other organics
X
A F
AC F
X
X
X
N-Nitrosodiphenylamine
86-30-6
Other organics
X
A F
A F
H
X
X
Oxolinic acid
14698-29-4
Antibiotic
v'
X
F G
X
H
X
Oxytetracycline
79-57-2
Antibiotic
V
B
C F
X
X
X
Pentabromodiphenyi ether
32534-81-9
PBDEs
X
A
X
X
A
X
Perfluorobutanesulfonate
45187-15-3
PFAS
X
X
c
H
H
X
Perfluorobutanoic acid (PFBA)
375-22-4
PFAS
X
X
H
X
Perfluorododecanoic acid
(PFDoDA)
307-55-1
PFAS
X
X
H
X
20
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Biosolids Biennial Review
Reporting Period 2018-2019
Chemical
CAS
Category
Concentra-
Human
Ecological
Environmental
number
tion data
health
toxicity
data
toxicity
data
fate and
transport data
Perfluorohexanesulfonate
108427-53-8
PFAS
X
X
E
H
H
X
Perfluorohexanoic acid (PFHxA)
307-24-4
PFAS
X
X
X
H
H
X
Perfluorooctanesulfonamide
(PFOSA)
754-91-6
PFAS
X
X
H
X
D E G
H
Perfluorooctanoic acid (PFOA)
335-67-1
PFAS
X
D E G
H
X
X
H
Perfluorotetradecanoic acid
(PFTeDA)
376-06-7
PFAS
X
X X
X
H
X
Perfluoroundecanoic acid
(PFUnDA)
2058-94-8
PFAS
X
X
A E F
H
H
X
Phosphorus
7723-14-0
Inorganics
V
A E
X
X X
X
Potassium
perfluorooctanesulfonate
2795-39-3
PFAS
X
X
H
X
X
H
p-Xyiene
106-42-3
Volatile organic
X
F G
A
X
H
X
Rubidium
7440-17-7
Metals
X
C
A E F
X X
X
Silver
7440-22-4
Metals
ซ~
A
X
X X
X
Styrene
100-42-5
Other organics
X
A E F
X
X
A F G
H
Tetracycline
60-54-8
Antibiotic
X
X
X
X
c
X
Thiabendazole
148-79-8
Pesticides
X
B
X
X
21
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Biosolids Biennial Review Reporting Period 2018-2019
Chemical
CAS
number
Category
Concentra-
tion data
Human
health
toxicity
data
Ecological
toxicity
data
Environmental
fate and
transport data
Toluene
108-88-3
Volatile organic
X
A E F
G
X
X
Tonalide
21145-77-7
Fragrance
X
X
H
X
Triclocarban
101-20-2
Antimicrobial
>/
X
X
X
Triclosan
3380-34-5
Drugs
X
B
H
X
Trimethoprim
738-70-5
Antibiotic
X
X
H
X
Triphenyl phosphate
115-86-6
Flame retardant
V
X
H
V
Tris(2-butoxyethyl) phosphate
78-51-3
Flame retardant
>s
E
H
Tris(2-chloroethyl) phosphate
115-96-8
Flame retardant
C E
H
V
Vanadium
7440-62-2
Metals
C E
X
X
Warfarin
81-81-2
Drugs
X
A
X
X
Zinc
7440-66-6
Metals
X
A E
X
X
*/ = Literature data (Tables C-1, G-1) D = HESD (Table D-4)
X = No data were found E = ATSDR (Tab|e D.5)
A = IRIS (Table D-1) p = Cg|EpA (Tgb|e D g)
B - HHBP (Table D-2) q = Hea|th Canada (Tab|e D.7)
C = PPRTV (Table D-3) H = EC0T0X (Tgb|e E2)
3.3 Microbial Pollutants Identified in the 2018-2019 Biennial Review
EPA identified two articles that met the eligibility criteria for microbial pollutants (abstracts of the
articles are provided in Appendix A). Review of the articles identified five newly identified microbial
pollutants in biosolids and provided potentially useful data on five previously identified microbial
pollutants. Table 3 lists these microbial pollutants.
Table 3. Microbial Pollutants Identified during the Biosolids Biennial Review for the 2018-2019
Reporting Period
Name
Category
New or
previous
Reference
Clostridium perfrirgers
Bacteria
New
Murray et al. 2019
Enterococcus spp.
Bacteria
New
Murray et al. 2019
Fecal coliforms
Bacteria
New
Murray et al. 2019
Total coliforms
Bacteria
New
Murray et al. 2019
Yersinia spp.
Bacteria
New
Murray et al. 2019
Adenovirus
Virus
Previous
Abd-Elmaksound et al. 2019
Aeromonas spp.
Bacteria
Previous
Murray et al. 2019
Antibiotic-resistant gene targets
Bacteria
Previous
Murray et al. 2019
Escherichia coli
Bacteria
Previous
Murray et al. 2019
22
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Biosolids Biennial Review
Reporting Period 2018-2019
[ Enterovirus
Virus [ Previous J Abd-Elmaksoundetal. 2019
4 Conclusions
EPA collected and reviewed publicly available information on the occurrence, human health and
ecological effects, and fate and transport in the environment of pollutants that have been found in
U.S. biosolids during the reporting period 2018-2019. The information collected and presented in
Biennial Report N- 8 is needed to conduct risk assessments.
EPA identified 18 new articles that provide relevant data for chemical pollutants that may occur in
U.S. biosolids. Review of the 18 articles identified 116 new chemicals in biosolids: 50
poly chlorinated biphenyls (PCBs) (39 congeners, 10 homologs, and total PCBs); four pesticides; 19
flame retardants; eight perfluoroalkyl substances (PFAS); three antibiotics; one metal; two
inorganics; and 29 other organics. These articles also identified new data for 48 chemicals that were
previously identified in biosolids. Concentration data in biosolids were found for 61 new chemicals
and for 34 chemicals identified in a previous biennial review. Human health toxicity values were
found for four of the new chemicals and 112 previously identified chemicals. ECOTOX (U.S. EPA
2020d) contained published studies containing data for 63 newly identified chemicals and 71
previously identified chemicals. Additional ecotoxicity data were found in EPI Suite for 99 newly
identified chemicals. Physical-chemical properties were identified in the literature for 31 new
chemicals and five chemicals previously identified in biosolids, and in EPI Suite for 99 new
chemicals. BCFs or BAFs were identified in the literature for one new chemical; in EPI Suite for 99
new chemicals; and in Arnot and Gobas (2006), Environment and Climate Change Canada (2006), or
ORNL (2020) for 40 new chemicals.
In addition, the articles identified five new microbial pollutants in biosolids, and potentially useful
data on five previously identified microbial pollutants.
Assessing the potential risk for pollutants identified in biosolids is the top priority for EPA's
Biosolids Program. EPA continues to make significant progress in building capacity to assess
pollutants by developing the necessary tools and data. EPA expects to begin risk screening of
pollutants found in biosolids once review of its screening tool has been completed.
For additional information about EPA's Biosolids Program, please visit the website at:
http://epa.gov/biosoltds.
5 References
Arnot, J. A., and A.P.C. Gobas. 2006. A review of bioconcentration factor (BCF) and
bioaccumulation factor (BAF) assessments for organic chemicals in aquatic organisms.
Environmental Reviews 14(4):257-297.
ATSDR (Agency for Toxic Substances and Disease Registry). 2020. Minimal Risk Levels (MRLs) for
Hazardous Substances. Accessed May 2020. https://www.atsdr.cdc.gov/mrls/mrHist.asp.
CalEPA (California Environmental Protection Agency). 2015. Air Toxics Hot Spots Program Risk
Assessment Guidelines: Guidance Manual for Preparation of Health Risk Assessments. Air,
Community, and Environmental Research Branch, Office of Environmental Health Hazard
Assessment, California Environmental Protection Agency. Accessed May 2020.
23
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Biosolids Biennial Review Reporting Period 2018-2019
https://oehha.ca.gov/air/cmr/notice~adoption~air~toxics~hot~spots~prograrn~guidance~rnanual~
preparation-health-risk-O.
Environment and Climate Change Canada. 2006. Bioaccumulation Canada. In The OECD QSAR
Toolbox, Version 3.3.2. An online database. Retrieved January 5, 2015. Organisation for
Economic Co-operation and Development, Paris, France.
http://www.oecd.org/env/ehs/nsk~assessment/oecd~asar-toolt3Qx.htm.
Health Canada. 2020. Guidelines for Canadian Drinking Water Quality - Technical Documents.
Environmental and Workplace Health, Health Canada. Accessed May 2020.
https://www.canada.ca/en/health-canada/services/environmental-workpIace-health/reports-
ORNL (Oak Ridge National Laboratory). 2020. Risk Assessment Information System (RAIS). RAIS
Contaminated Media Risk Calculator. Accessed May 2020. https://rais.oml. gov/.
U.S. EPA (U.S. Environmental Protection Agency). 2009. Targeted National Sewage Sludge Survey
Statistical Analysis Report. U.S. Environmental Protection Agency, Office of Water,
Washington, DC. EPA-822-R-08-018. Accessed June 2020.
https://www.epa.gov/biosolids/sewage~sludge~survevs.
U.S. EPA (U.S. Environmental Protection Agency). 2017. Estimation Programs Interface Suitefor
Microsoftฎ Windows, v 4.11. Updated July 19, 2017. U.S. Environmental Protection Agency,
Washington, DC. Accessed May 2020. https://www.epa.gov/tsca-screening-tools/download-
epi-suitetm~estimation~program~inteiface-v4.1.1.
U.S. EPA (U.S. Environmental Protection Agency). 2020a. Integrated Risk Information System
(IRIS). U.S. Environmental Protection Agency, Office of Research and Development,
National Center for Environmental Assessment, Washington, DC. Accessed May 2020.
http: // www, epa. gov/i ris/.
U.S. EPA (U.S. Environmental Protection Agency). 2020b. Human Health Benchmarks for
Pesticides. U.S. Environmental Protection Agency, Office of Pesticide Programs,
Washington, DC. Accessed May 2020.
https://iaspub.epa. gov/apex/pesticides/f?p=CHEMIC ALSEARCH: .1:0: :NO: .1.
U.S. EPA (U.S. Environmental Protection Agency). 2020c. Superfund Provisional Peer-Reviewed
Toxicity Values. U.S. Environmental Protection Agency, Washington, DC. Accessed May
2020. https://www.epa.gov/pprtv/provisional-peer-reviewed-toxicity-values-pprtvs-
assessments.
U.S. EPA (U.S. Environmental Protection Agency). 2020d. ECOTOXicology Knowledgebase
(ECOTOX). U.S. Environmental Protection Agency, Washington, DC. Accessed June 2020.
https: //cfpub. epa. gov/ecotox/.
U.S. EPA (U.S. Environmental Protection Agency). 2020e. Health Effects Support Documents. U.S.
Environmental Protection Agency, Office of Water, Office of Science and Technology,
Washington, DC. Accessed May 2020. https://www.epa.gov/sdwa/drinking~water~
Gontaroinant~human~health~effects~information#regulatory.
24
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Biosolids Biennial Review
Reporting Period 2018-2019
Appendix A Abstracts for Papers Reviewed for the 2018-2019
Biennial Review
Abd-Elmaksoud, S., N. Castro-del Campo, C. Gerba, I. Pepper, and K. Bright. 2019.
Comparative assessment of BGM and PLC/PRF/5 cell lines for enteric virus detection in
biosolids. Food and Environmental Virology 11:32-39.
The BGM cell line is required for the detection of enteric viruses in biosolids through a total
culturable viral assay (TCVA) by the United States Environmental Protection Agency. In the present
study, BGM and PLC/PRF/5 cell lines were evaluated for TCVA and for their use in determining the
incidence of adenoviruses and enteroviruses in raw sludge and Class B biosolids. Six raw sludge and
17 Class B biosolid samples were collected from 13 wastewater treatment plants from seven U.S.
states. Samples were processed via organic flocculation and concentrate volumes equivalent to 4 g
total solids were assayed on BGM and PLC/PRF/5 cells. Cell monolayers were observed for
cytopathic effect (CPE) after two 14-d passages. Cell lysates were tested for the presence of
adenoviruses and enteroviruses by PCR or RT-PCR. The PLC/PRF/5 cells detected more culturable
viruses than the BGM cells by CPE (73.9% versus 56.5%, respectively). Fifty-two percent of the
samples were positive for CPE using both cell lines. No viruses were detected in either cell line by
PCR in flasks in which CPE was not observed. No adenoviruses were detected in 13 CPE-positive
samples from BGM lysates. In contrast, of the 17 samples exhibiting CPE on PLC/PRF/5 cells, 14
were positive for adenoviruses (82.4%). In conclusion, PLC/PRF/5 cells were superior for the
detection of adenoviruses in both raw sludge and Class B biosolids. Thus, the use of BGM cells alone
for TCVA may underestimate the viral concentration in sludge/biosolid samples.
Kim Lazcano, R., C. de Perre, M.L. Mashtare, and L.S. Lee. 2019. Per- and polyfluoroalkyl
substances in commercially available biosolid-based products: The effect of treatment
processes. Water Environment Research 91:1669-1677.
Per- and polyfluoroalkyl substances (PFAS) have been used in a variety of consumer and industrial
products and are known to accumulate in sewage sludge due to sorption and their recalcitrant nature.
Treatment processes ensure safe and high-quality biosolids by reducing the potential for adverse
environmental impacts such as pathogen levels; however, they have yet to be evaluated for their
impact on the fate of PFAS. The objective of this study was to compare PFAS concentrations in four
commercially available biosolid-based products that received different types of treatments: heat
treatment, composting, blending, and thermal hydrolysis. Seventeen perfluoroalkyl acids (PFAAs)
were quantified using liquid chromatography with tandem quadrupole time-of-flight mass
spectrometry followed by screening for 30 PFAA precursors. Treatment processes did not reduce
PFAA loads except for blending, which served only to dilute concentrations. Several PFAA
precursors were identified with 6:2 and 8:2 fluorotelomer phosphate diesters in all samples pre- and
post-treatment.
Li, S., R. Li, Y. Tang, and G. Chen. 2019. Microwave-induced heavy metal removal from
dewatered biosolids for cost-effective composting. Journal of Cleaner Production 241:1-9.
Urbanization and population growth have resulted in the accumulation of heavy metals in biosolids,
and these metals act as potent environmental contaminants. In this study, a novel microwave-
mediated method of extracting heavy metals from dewatered biosolids was developed. With an
electromagnetic power of 140 W for a contact time of 10 s, microwave irradiation effectively
induced the immobilization of heavy metals. The treated biosolids were subsequently mixed with
acetic acid, sulfuric acid, or ethylenediaminetetraacetic acid (EDTA) for heavy metal extraction. The
A-l
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Biosolids Biennial Review
Reporting Period 2018-2019
biosolids in this study were contaminated by different heavy metals, including Cd, Cu, Fe, Pb, Ni,
and Zn. Among them, the concentrations of Cd (94.3 ฑ 14.2 mg/kg) and Pb (888.7 ฑ 79.8 mg/kg)
were considerably above the limits allowed for land application. Conventional extraction methods
were found to be insufficient in lowering heavy metal contents below regulation limits, while the
microwave-mediated method efficiently increased heavy metal removal by as much as ~3x. After the
biosolids were treated, Cd and Pb concentrations decreased to 80.2 ฑ 2.7 and 159.8 ฑ 22.1 mg/kg,
respectively. The treated biosolids and their products were eligible for land application as an
alternative treatment. The microwave-mediated method also lowered the demand for extractants.
Using a reduced concentration of sulfuric acid, acetic acid, or EDTA, at least 90% of Cu, 70% of Zn
and Pb, 45% of Fe, and 20% of Ni were simultaneously removed from the contaminated biosolids.
Cost analyses revealed that the microwave-mediated method could decrease the net total cost of
biosolid handling by as much as 62.7%. Considering its simplicity, cost-effectiveness, and minimal
environmental impacts, the proposed method offers a promising solution to the problem of heavy
metal accumulation in biosolids.
Lozano, N., C.P. Rice, M. Ramirez, and A. Torren. 2018. Fate of triclocarban in agricultural
soils after biosolid applications. Environmental Science Pollution Research 25:222-232.
Triclocarban [N-(4-chlorophenyl)-N-(3,4-dichlorophenyl) urea] (TCC) is an antimicrobial agent
utilized in a variety of consumer products. It is released into domestic wastewaters and, upon
treatment, it is known to accumulate in biosolids. This study examines the occurrence of TCC in
biosolids and its long-term fate in biosolid-treated soils. TCC levels in the biosolids from a large
wastewater treatment plant (WWTP) over 2 years showed little variability at 18,800 ฑ 700 ng g ' dry
wt. (mean ฑ SEM). Surface soil samples (top 10 cm) were collected from 26 commercial farms
located in northern VA, US that had received biosolid applications from the WWTP. Samples were
grouped as farms receiving no biosolids, farms with a single biosolid application, and those receiving
multiple biosolid applications from 1992 to 2006. Our results illustrate that TCC soil residues
remained years after biosolid application. The two most important parameters controlling TCC
topsoil concentrations were the biosolid application rate and the period since the last application. No
TCC removal was observed in farms where the time since biosolid application was between 7 and 9
months. TCC concentration analyzed 7 and 8 years after biosolid applications were 45.8 ฑ 6.1 and
72.4 ฑ 15.3 ng g ' dry wt., respectively, showing its persistence in soils and build-up upon multiple
biosolid applications. A soil TCC half-life of 287.5 ฑ 45.5 days was estimated.
Lu, Z., S.A. Smyth, and A.O. De Silva. 2019. Distribution and fate of synthetic phenolic
antioxidants in various wastewater treatment processes in Canada. Chemosphere 219:826-835.
Synthetic phenolic antioxidants (SPAs) are of emerging concern due to their potential environmental
risks. However, the environmental occurrence and fate of SPAs are poorly understood. In this study,
13 SPAs were analyzed in 70 liquid and 21 solid samples from 12 wastewater treatment plants
(WWTPs) in 2016 to investigate the distribution and composition of SPAs in different wastewater
treatment processes in Canada. Wastewater samples were liquid-liquid extracted and biosolids were
treated using ultrasonic assisted solvent extraction. SPAs were analyzed by ultra-performance liquid
chromatography-tandem mass spectrometry. The concentrations of total SPAs were in the ranges of
71-3193 ng/L in influent, less than method quantification limits (MQLs)-520 ng/L in effluent, and
479-4794 ng/g in biosolids (dry weight (dw)). SPAs were effectively removed (median > 75%) from
the liquid stream in most WWTPs. In one aerated lagoon and two primary treatment sites, low
removal efficiency (median 26%-43%) was observed for 4-tert-octylphenol(4-tOP). These results
indicate that wastewater effluent is a vector for SPAs, including the endocrine disruptor 4-tOP, to
aquatic environments. The mass balance approximation found major removal mechanisms are sludge
A-2
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Biosolids Biennial Review
Reporting Period 2018-2019
sorption/separation and degradation. A preliminary risk assessment suggested that most SPAs in
WWTP effluent were unlikely to pose eco-toxicological risks to aquatic organisms in the receiving
waters. Future research should evaluate the environmental risks of SPAs associated with land
application of biosolids and investigate the occurrence and fate of the degradation products of these
contaminants.
Magee, H.Y., M.M. Maurer, A. Cobos, B.F.G. Pycke, A.K. Venkatesan, D. Magee, M. Scotch,
and R.U. Hal den. 2018. U.S. nationwide reconnaissance of ten infrequently monitored
antibiotics in municipal biosolids. Science of the Environment 643:460-467.
Ten infrequently monitored antibiotics in biosolids were examined in archived American sewage
sludges (n = 79) collected as part of the 2006/2007 U.S. Environmental Protection Agency (EPA)
Targeted National Sewage Sludge Survey. This study inspected the occurrence of amoxicillin,
ampicillin, erythromycin, furazolidone [proxy metabolite: 3-(2-nitrobenzylidenamino)-2-
oxazolidinone (NP-AOZ)], nalidixic acid, oxolinic acid, oxytetracycline, spiramycin, sulfadimidine,
and sulfadimethoxine in sewage sludges after nearly a decade in frozen storage. Six antibiotics were
detected at the following average concentrations (ng/g dry weight): amoxicillin (1.0), nalidixic acid
(19.1), oxolinic acid (2.7), erythromycin (0.6), oxytetracycline (4.5), and ampicillin (14.8). The
remaining four were not detected in any samples (
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Biosolids Biennial Review
Reporting Period 2018-2019
Biosolids were obtained from four Ontario municipalities that vary in how the sewage sludge is
treated. These included a Class B biosolids that was anaerobically digested, a Class A biosolids that
were heat treated and pelletized (Propell), and two Class A biosolids that were stabilized using either
the N-Viro (N-Rich) or Lystek (LysteGro) processes. Viable enteric indicator or pathogenic bacteria
in the biosolids were enumerated by plate count, gene targets associated with antibiotic resistance or
horizontal gene transfer were detected by PCR, and a subset of these gene targets were quantified by
qPCR. Following application at commercial rates to field plots, the persistence of enteric bacteria and
gene targets in soil was followed during the growing season. Carrots, radishes and lettuce were sown
into the amended and unamended control plots, and the diversity and abundance of gene targets they
carried at harvest determined. All three Class A biosolids carried fewer and less abundant antibiotic
resistance genes than did the Class B biosolids, in particular the very alkaline N-Viro product (N-
Rich). Following application, some gene targets (e.g. in/ 1, sull, strAfB, aadA) that are typically
associated with mobile gene cassettes remained detectable throughout the growing season, whereas
others (e.g. ermB, ermF, blaoxpzo) that are not associated with cassettes became undetectable within
three weeks or less. At harvest a larger number of gene targets were detected on the carrots and
radishes than in the lettuce. Overall, land application of Class A biosolids will entrain fewer viable
bacteria and genes associated with antibiotic resistance into crop ground than will amendment with
Class B biosolids.
Needham, T.P., and U. Ghosh. 2019. Four decades since the ban, old urban wastewater
treatment plant remains a dominant source of PCBs to the environment. Environmental
Pollution 246:390-397.
Despite the ban on new manufacture and commercial use of PCBs, municipal sewer systems continue
to serve as ongoing secondary sources for contamination in receiving water bodies. Ongoing PCB
sources have made it difficult to achieve desired recovery after implementation of sediment cleanup
efforts. We report on a 16-month surveillance to determine the inputs, fate, and export of PCBs
within a municipal waste collection/treatment system by strategic sampling of the freely dissolved
and biosolids-associated PCBs. The total PCBs entering the treatment plant was found to be 170
g/day of which 100 g/day exited the plant associated with the biosolids and 5.2 g/day was discharged
in the form of freely dissolved PCBs in the effluent. A net loss of 68 g/day was calculated for the
plant, attributable to volatilization and biodegradation. Freely dissolved PCBs in the treated effluent
was an order of magnitude higher than the water quality criteria for the protection of human health
through fish consumption and found to be a major contributor to the dissolved concentration in the
receiving river. Predicted bioaccumulation in fish from dissolved PCBs in the effluent exceeded the
threshold for human consumption. The biosolids, currently land applied as fertilizer, contained an
average PCB concentration of 760 mg/kg. The sludge produced in this treatment plant is processed in
large anaerobic digesters and changes to the homolog distribution point to some microbial
dechlorination. Application of biosolids to clean agricultural soil resulted in a 6-fold increase in PCB
levels in the earthworm E. fetida which could be eliminated by the amendment of 1% by weight of
activated carbon.
Onchoke, K.K., C.M. Franclemont, and P.W. Weatherford. 2018. Structural characterization
and evaluation of municipal wastewater sludge (biosolids) from two rural wastewater
treatment plants in East Texas, USA. Spectrochimica Acta Part A: Molecular and Biomolecular
Spectroscopy 204:514-524.
Wastewater sludge (or) biosolids collected from two rural wastewater treatment plants (NWWTP,
LWWTP) in East Texas, USA were characterized and evaluated via inductively coupled plasma
optical emission spectrometry, scanning electron microscopy (SEM), energy dispersive X-ray
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spectroscopy (EDX), thermogravimetric analysis, X-ray diffraction, Fourier transform infrared
spectroscopy (FTIR), and ion chromatography. The proximate organic and inorganic compositions
and spectroscopic characteristics of sewage sludge were determined. The results show that the
concentrations of toxic metals Cd, Cr, Cu, Mo, Ni, Pb, Hg, and Zn meet USEPA guideline
recommendations for land applications. Notably, metals concentrations in biosolids from NWWTP
(Mn (700 ฑ 83) > Zn (422.5 ฑ 35.4 ppm) > Ba (319.5 ฑ 87 ppm) > Cu (240 ฑ 27 ppm) > B (107 ฑ 14
ppm) > V (24 ฑ 3.3 ppm) > Cr (20 ฑ 3.3 ppm) > Ni (16.7 ฑ 2.0 ppm) > Pb (16.8 ฑ1.1 ppm) > As
(11.99 ฑ 1.27 ppm) > Co (7.6 ฑ 0.7 ppm) > Mo (6.4 ฑ 1.4 ppm) > Hg (0.55 ฑ 0.24 ppm) > Cd (0.130
ฑ0.109 ppm)) and LWWTP follow similar trends. Macro-elements concentrations in LWWTP
follow the trend P (19,648 ฑ 169) > Fe (22,688 ฑ 2110) > Ca (9372 ฑ 163) > S (9010 ฑ 1009) > A1
(12,538 ฑ 2116) > K (3514 ฑ 550) > Mg (33,370 ฑ 502) > Na (1511 ฑ 472). The Br , NOs", N02~,
F , CP, and SO-t2 concentrations meet USEPA guidelines. Whereas biosolid particle sizes were in
the range -20 |im to 500 |im, mineralogical results show quartz and vermiculite to be major
constituents with abundancies 12.94%, and 10.87% w/wt, respectively.
Sadaria, A.M., C.W. Labban, J.C. Steele, M.M. Maurer, and R.U. Halden. 2019. Retrospective
nationwide occurrence of fipronil and its degradates in U.S. wastewater and sewage sludge
from 2001-2016. Water Research 155:465-473.
The insecticide fipronil is under regulatory scrutiny worldwide for its toxicity to pollinators and
aquatic invertebrates. We conducted the first U.S. nationwide, longitudinal study of sewage sludges
for fiproles, i.e., the sum of fipronil and its major degradates (fipronil sulfone, sulfide, amide, and
desulfinyl). Archived sludges (n = 109) collected in three campaigns over 15 years were analyzed by
isotope dilution liquid chromatography tandem mass spectrometry, revealing ubiquitous fiprole
occurrence (0.2-385.3 |ig/kg) since 2001 and a significant increase (2.4 ฑ 0.3 fold; p < 0.005) both
from 2001 to 2006/7 and from 2001 to 2015/6, but not a significant increase from 2006/7 to 2015/6
(p = 0.275). A geospatial analysis showed fiprole levels in municipal sludges to be uncoupled from
agricultural use of fipronil on cropland surrounding sampled municipalities, thus pointing to non-
agricultural uses (i.e., spot-on treatment and urban pest control) as a major source of fiprole loading
to wastewater. Whereas anaerobic digestion was correlated with increases in fipronil sulfide at the
expense of parental fipronil (p < 0.001), total fiprole levels in sewage sludges were similar regardless
of the solids treatment approach applied (p = 0.519). Treatment plant effluent available from 12
facilities in 2015/6 contained fiproles at 0.3-112.9 ng/L, exceeding the United States Environmental
Protection Agency (USEPA) aquatic invertebrate life benchmark for chronic fipronil exposure (11
ng/L) in 67% of cases. Whereas the USEPA identified fipronil in sludge only recently (2015),
retrospective analyses and modeling conducted here show contaminant ubiquity and nationwide
increases of fiprole mass (compared to 2001 levels) in U.S. municipal sludge (1140 ฑ 230 kg in
2015/6), and treated effluent nationwide (1970 ฑ 390 kg in 2015/6) over the past 15 years.
Sidhu, H., G. O'Conner, A. Ogram, and K. Kumar. 2019. Bioavailability of biosolids-borne
ciprofloxacin and azithromycin to terrestrial organisms: Microbial toxicity and earthworm
responses. Science of the Total Environment 650:18-26.
Information on bioavailability of two antibiotic trace organic chemicals (TOrCs), ciprofloxacin (CIP)
and azithromycin (AZ), to terrestrial organisms is severely limited, especially in the biosolids
context. Responses of two terrestrial organisms, earthworms and microbes, to a range of
environmentally relevant concentrations of biosolids-borne CIP and AZ were assessed in laboratory
incubation studies involving 3H-labeled compounds. Earthworm assessments were based on the
Earthworm Sub-chronic Toxicity Test (OCSPP 850.3100). Microbial impacts were assessed using
respiration and reverse transcriptase-quantitative PCR (mRNA) analyses of nutrient (N and P)
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cycling genes as toxicity markers. Antibiotic extractability and stability during incubations were
assessed using sequential extractions with CaCh, methanol: water, and accelerated solvent extraction
and analyses using thin layer chromatography. Subsample combustion, in addition to sequential
extraction, recovered nearly 100% of the added antibiotic. The two compounds persisted (estimated
half-lives > 3 y), but extractable fractions (especially of CIP) decreased over time. Neither biosolids-
borne antibiotic significantly impacted overall respiration or N and P cycling. Microbial toxicity
responses were minimal; complementary DNA (cDNA) concentrations of ammonia oxidizing
bacterial genes were affected, but only initially. Similarly, earthworms showed no apparent response
related to toxicity to environmentally relevant (and much greater) concentrations of biosolids-borne
CIP and AZ. Earthworms, however, accumulated both compounds, and the bioaccumulation factor
(BAF) values (dry weight basis) were ~4 (CIP) and ~7 (AZ) in depurated worms and -20 (CIP and
AZ) in un-depurated worms. The microbial and earthworm responses strongly to moderately
correlated with "bioaccessible" fractions of the target TOrCs. The results suggest that biosolids-borne
CIP and AZ toxicity to terrestrial microbes and earthworms is minimal, but there is a potential for
target TOrC entry into ecological food web.
Sidhu, H., G. O'Conner, and J. Kruse. 2019. Plant toxicity and accumulation of biosolids-borne
ciprofloxacin and azithromycin. Science of the Total Environment 648:1219-1226.
Trace organic chemicals (TOrCs) in land applied biosolids can cause phytotoxicities and contaminate
human and animal food chains. Information on phytotoxicity and phytoaccumulation of
environmentally relevant concentrations of two antibiotic TOrCs, ciprofloxacin (CIP) and
azithromycin (AZ), from biosolids-amended soils is limited. Greenhouse studies were conducted to
assess the plant toxicity and accumulation of a range of environmentally relevant concentrations of
biosolids-borne CIP and AZ in biosolids-amended soils. Separate studies assessed phytotoxicity
potential of soil-borne CIP and AZ (soils directly spiked with the target antibiotics without biosolids)
at concentrations much greater than those of environmental relevance in biosolids-amended soils.
Both the biosolids-borne and the soil-borne antibiotic studies involved three plants (radish (Raphanus
sativus), lettuce {Lactuca sativa), and tall fescue grass (Festuca arundinacea)) of different
morphologies, physiologies, and chemical exposure scenarios. Phytotoxicity and phytoaccumulation
from the biosolids-borne antibiotics were minimal at environmentally relevant concentrations, even
in sand. The separate phytotoxicity experiments involving the soil-borne antibiotics revealed no
observed adverse effect concentration (NOAEC) of 3.2 mg kg-1 (AZ) and 36.1 mg kg-1 (CIP) for the
three plants grown in soils mimicking typical agricultural soils. These NOAEC values are about 100-
fold greater than the antibiotic concentrations expected in biosolids-amended soils. NOAEC values
under an unrealistic worst case where the antibiotics were directly spiked to sand (NOAEC = 3.2 mg
kg-1 for AZ; and >0.36 mg kg-1 for CIP) were also greater than the environmentally relevant
concentrations of the biosolids-borne antibiotics. The results suggest that land application of
biosolids-borne CIP and AZ pose De minimis risks to plants. Point estimates of plant
bioaccumulation factors (dry weight basis) were 0.01 (CIP) and 0.1 (AZ), suggesting minimal
impacts of the target TOrCs on human and/or animal food chains.
Sidhu, H., E. D'Angelo, and G. O'Conner. 2019. Retention-release of ciprofloxacin and
azithromycin in biosolids and biosolids-amended soils. Science of the Total Environment
650:173-183.
Ciprofloxacin (CIP) and azithromycin (AZ) are commonly prescribed antibiotics, often found at
elevated concentrations in treated sewage sludge (biosolids), and could pose human and ecological
risks when land applied. Limited retention-release data preclude assessing potential risks from the
target antibiotics in biosolids and biosolids-amended soils. The present work assessed sorption-
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Reporting Period 2018-2019
desorption of CIP and AZ in biosolids and biosolids-amended soils using the "traditional" batch
equilibration method. The batch equilibration method also included unamended soils for comparison.
Release potentials of the biosolids-borne antibiotics were assessed via multiple desorption
equilibrations in the presence of CaC12, soils, PbC12, or competing antibiotic (CIP versus AZ)
solutions. Desorption kinetics of CIP from biosolids were also evaluated by the diffusive gradient in
thin films technique (DGT), coupled with a diffusion transport-exchange model available in 2D-
DIFs. Sorption of both antibiotics followed linear models with partitioning coefficient (Kd) values for
CIP ranging between 40 and 334 L kg-1 in soils and 357 L kg-1 in biosolids, and values for AZ
ranging between 11 and 202 L kg-1 in soils and 428 L kg-1 in biosolids. Antibiotic desorption from
the biosolids was highly hysteretic (hysteresis coefficients b 0.003) and desorption of the biosolids-
borne chemicals was extremely small (<3%) using any of the various desorption equilibration
approaches. Desorption was hysteric in soils too; where desorption percentages were 4, 5, and 26%
for CIP and 6, 32, and 50% for AZ in the silt loam soil, manured sand, and sand, respectively. CIP
release from biosolids determined by DGT was also small (<1%), ascribed to low dissolved and
labile concentrations in the solid phase and a small effective diffusion coefficient. Results obtained
using equilibrium and dynamic approaches suggest that the target antibiotic bioaccessibilities from
biosolids and finer-textured (typical agricultural) soils would be minimal and that biosolids (not soils)
control desorption of the two biosolids-borne chemicals.
Silveira, M.L., G.A. O'Connor, Y. Lu, J.E. Erickson, C. Brandani, and M.M. Kohmann. 2019.
Runoff and leachate phosphorus and nitrogen losses from grass-vegetated soil boxes amended
with biosolids and fertilizer. Journal of Environmental Quality 48:1498-1506.
Recent evidence suggests an upward trend in surface water phosphorus (P) concentrations in many
segments of Florida, including the upper basin of the St. Johns River, a region that currently receives
about two-thirds of the state Class B biosolids land application. Concerns about water quality in this
area are encouraging reexamination of the regulations governing biosolids programs. The objectives
of this study were (i) to identify and thoroughly characterize the main biosolids sources routinely
applied in the region, and (ii) to evaluate runoff and leachate N and P losses from a typical Florida
Spodosol amended with biosolids or commercial inorganic fertilizer. Biosolids and inorganic
fertilizer were surface applied uniformly at a rate equivalent to ~114 kg P ha"1, which corresponded
to a typical P load associated with nitrogen (N)-based biosolids application. Soluble reactive P (SRP)
was the predominant form of P lost in runoff and leachate. Inorganic P fertilizer increased flow-
weighted runoff total P concentrations nearly 60-fold relative to control treatment (0.4 vs. 22 mg P L"
1 for control and fertilizer treatments, respectively). With exception of biological P removal (BPR)
biosolids, all other tested biosolids yielded flow-weighted runoff P concentrations similar to
untreated soils. Cumulative P and N losses (as a percentage of P and N applied) were greater from
commercial inorganic fertilizer (-38% of P and 46% of N) than any biosolids source (3% of P and
6% of N). Results demonstrate the value of water-extractable P (WEP) as an indicator of biosolids P
loss potential.
Vaughn, S.F., F.D. Dinelli, J.A. Kenar, M.A. Jackson, A.J. Thomas, and S.C. Peterson. 2018.
Physical and chemical properties of pyrolyzed biosolids for utilization in sand-based turfgrass
rootzones. Waste Management 76:98-105.
Biosolids are several forms of treated sewage sludge that are intended for use as soil conditioners for
horticultural, agricultural and industrial crops. The objectives of this research were to determine the
chemical and physical properties of biosolids pyrolyzed at several different temperatures, and their
effect on perennial ryegrass seed germination and growth. Biosolids were thermally treated in an
oxygen-free (nitrogen atmosphere) retort oven at 300, 400, 500, 700 and 900 ฐC. As pyrolysis
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Reporting Period 2018-2019
temperatures increased, bulk densities, total surface areas, micropore surface areas, % minerals and
pH values of the pyrolyzed biosolids increased, while carbon percentage decreased compared to
untreated biosolids. Fourier-transform infrared spectroscopy analysis showed decreased surface
functionality as pyrolysis temperature increased. Perennial ryegrass (Loliumperenne L. 'Nui') plants
were grown in mixtures of 10% (v/v) biosolids or 10% (v/v) of the various pyrolyzed biosolids and
90% coarse sand. Ryegrass plants grown in the biosolids and the 300 ฐC pyrolyzed biosolids mixture
had the greatest shoot heights of any of the treatments after 4 weeks of growth. These results indicate
that pyrolyzing biosolids at 300 ฐC would produce material with excellent potential as a long-term
peat replacement for water and nutrient retention in sand-based rootzones.
Wang, Y., P. Kannan, R.U. Halden, and K. Kannan. 2019. A nationwide survey of 31
organophosphate esters in sewage sludge from the United States. Science of the Total
Environment 655:446-453.
Organophosphate esters (OPEs) are used as flame retardants and plasticizers in a wide range of
consumer products. Nevertheless, studies on the occurrence and inventory of OPEs in sewage sludge
are limited. In this study, 20 OP triesters and 11 diesters were measured in 75 archived sewage
sludge samples collected from 67 wastewater treatment plants (WWTPs) across the United States
(US). The median concentrations of X2oOP-triesters and X"OP-diesters in sludge were 1290 and
78.4 ng/g dry weight (dw), respectively. Sludge samples originating from the Western and
Northeastern US contained higher concentrations of OP triesters than did those from the Midwestern
and Southern US. Sludge samples from WWTPs with larger treatment capacity (>38 million liters
per day) contained higher concentrations of OP diesters (p < 0.05). OP diesters in sludge originated
from two sources, triester degradation and direct inputs. Land application of sludge to US soils was
estimated to result in annual mass inputs of 12,400-14,900 kg/year of OP triesters and 663-
796 kg/year of OP diesters. A hazard assessment was performed for 14 OPEs found in sludge, which
suggested a low level of risk at the current land application practices of sludge.
Xu, S. 2019. Extraction and quantitative analysis of water, sediment, soil and biosolids for
trace-level trimethylsilanol. International Journal of Environmental Analytical Chemistry
100(3):268-281.
Methylsilanols such as trimethylsilanol (TMS) are considered as the major hydrolytic degradation
products of methylsiloxanes, a class of anthropogenic organometallic substances with a wide range
of applications. The distribution of these silanols in various environmental compartments, therefore,
could provide direct information on silanols' chemical fate and environmental exposure. Existing
methods for the quantification of the silanols are not sensitive and robust enough for analyzing
environmental media where trace and ultra-trace-level concentrations may be expected. In the present
study, solid-phase extraction (SPE) and solvent extraction in combination with gas chromatography-
mass spectrometry (GC/MS) were tested for analyzing water, sediment, soil and biosolids samples
for TMS. ISOLUTEฎ ENV+ solid-phase sorbent was found to be most suitable for extraction of
water samples for ultra-trace TMS, while direct solvent extraction worked for solids samples such as
soil, sediment and biosolids. Coupling with an isotopic internal standard and SPE extraction, direct
GC/MS analysis without derivatization can reach a method detection limit for TMS as low as 0.10 |_ig
L"1 in water. The detection limits for solid samples varied from 0.21 ng g"1 ww (wet weights) to 10 ng
g"1 ww, mostly limited by background concentrations of TMS in extraction solvents. It was also
observed that prolonged sample storage may lead to a reduction in TMS concentrations, regardless of
the concentrations of coexisting methylsiloxanes.
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Zhang, J., L. Wang, R.U. Halden, and K. Kan nan. 2019. Polyethylene terephthalate and
polycarbonate microplastics in sewage sludge collected from the United States. Environmental
Science & Technology Letters 6:650-655.
Microplastics (MPs) are emerging pollutants of public health and environmental concern. Sewage
sludge is a sink for MPs that originate from domestic sources and can provide an indication of the
magnitude of discharge of MPs by local populations. Nevertheless, reports of quantitative analysis of
MPs present in sewage sludge are limited. In this study, 65 sewage sludge samples collected from
sewage treatment plants (STPs) across the United States were analyzed for MPs originating from
polyethylene terephthalate (PET) and polycarbonate (PC) using alkali-assisted thermal
depolymerization and liquid chromatography-tandem mass spectrometry. PET and PC were detected
in all sludge samples at concentrations (dry weight) in the ranges of 28-12000 ng/g (median of 370
|ig/g) and 0.70-8400 ng/g (median of 5.9 ng/g), respectively. The concentrations of PET and PC
varied, depending on the treatment capacity of the STPs. The annual environmental emission of MPs
through sludge disposal was estimated at 3,700,000 kg/year for PET and 310,000 kg/year for PC. Our
results provide a quantitative estimate of emission of MPs through land application of sludge.
Zhu, H., R.U. Halden, and K. Kannan. 2019. A nationwide survey of the occurrence of
melamine and its derivatives in archived sewage sludge from the United States. Environmental
Pollution 245:994-999.
Melamine-based resins are used extensively in laminates, plastics, coatings, glues, and dinnerware.
Little is known, however, about the occurrence of melamine and its derivatives in the environment.
In this study, a nationwide survey of melamine and its derivatives, namely ammeline, ammelide, and
cyanuric acid, was conducted, using archived sewage sludge samples collected from 68 wastewater
treatment plants in the United States (U.S.). The sum concentrations of four target compounds in
sludge ranged from 34 to 1800 ng/g dry weight (dw), with a mean concentration of 240 ng/g dw;
melamine (46%) and cyanuric acid (40%) collectively accounted for 86% of the total mass of
analytes. No significant geographical variation in the concentrations of melamine and its derivatives
in sewage sludge was found. The estimated emission of melamine and its derivatives via land-
application of sludge was approximately 1600 kg/yr in the U.S. The hazard quotient values for
melamine in sludge-amended soils ranged from 2.2 x 10"5 to 4.4 x 10"3, indicating that the current
levels of melamine in sludge pose a minimal risk to the soil environment.
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Biosolids Biennial Review
Appendix B Pollutants Identified in Biosolids
Reporting Period 2018-2019
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Appendix C Concentrations of Chemicals Found in Biosolids
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Appendix D Human Health Toxicity Values for Chemicals Found in
Biosolids
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Appendix E Ecological Toxicity Data
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Biosolids Biennial Review Reporting Period 2018-2019
Appendix F Environmental Fate and Transport Data:
Bioaccumulation and Bioconcentration Data
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Appendix G Environmental Fate and Transport Data: Physical-
Chemical Properties
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Appendix B. Pollutants Identified in Biosolids
Reporting Period 2018-2019
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Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Chemical Pollutants
(+)-Diltiazem
42399-41-7
Drugs
2005 BR
(-ty-)-Verapamil
52-53-9
Drugs
2013 BR
(3alpha,5beta)-Cholestan-3-ol
516-92-7
Other organics
2009 TNSSS
(3beta,5alpha)-Stigmastan-3-ol
83-45-4
Other organics
2009 TNSSS
(4R,4aS, 12aR)-7-Chloro-4-(dimethylamino)-1,10,11,12a-
tetrahydroxy-6-methyl-3,12-dioxo-3,4,4a,5,12,12a-
hexahydrotetracene-2-carboxamide-hydrogen chloride (1/1)
158018-53-2
Other organics
2009 TNSSS
1 -(p-Chlorobenzoyl)-5-methoxy-2-methyl-lndole-3-acetic acid
53-86-1
Drugs
2005 BR
1,1'-Biphenyl, 2,2',4,4',6-pentabromo-
97038-97-6
PCB
2009 TNSSS
1,1 '-Biphenyl, 2,3',4,4'-tetrabromo-
84303-45-7
PCB
2009 TNSSS
1,1'-Biphenyl, 2,4,4'-tribromo-
6430-90-6
PCB
2009 TNSSS
1,1 '-Ethane-1,2-diylbis(pentabromobenzene)
84852-53-9
Flame retardant
2017 BR
1,2,3,4,6,7,8,9,10,10,11,11 -dodecachloro-1,4,4a,5a,6,9,9a,9b-
octahydro-1,4:6,9-dimethanodibenzofuran
31107-44-5
Dioxins/Furans
2017 BR
1,2,3,4,6,7,8,9-octabromodibenzofuran
103582-29-2
Dioxins/Furans
2015 BR
1,2,3,4,6,7,8-Heptabromodibenzofuran
107555-95-3
Dioxins/Furans
2015 BR
1,2,3,4,6,7,8-Heptabromodibenzo-p-dioxin
110999-47-8
Dioxins/Furans
2015 BR
1,2,3,4,6,7,8-Heptachlorodibenzodioxin
35822-46-9
Dioxins/Furans
1988 NSSS
1,2,3,4,7,8,9-Heptabromodibenzo[b,d]furan
161880-51-9
Dioxins/Furans
2015 BR
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
Dioxins/Furans
1988 NSSS
1,2,3,4,7,8-Hexabromodibenzofuran
129880-08-6
Dioxins/Furans
2015 BR
1,2,3,4,7,8-Hexabromodibenzo-p-dioxin
110999-44-5
Dioxins/Furans
2015 BR
1,2,3,4,7,8-Hexachlorodibenzodioxin
39227-28-6
Dioxins/Furans
1988 NSSS
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
Dioxins/Furans
1988 NSSS
1,2,3,4-tetrachlorodibenzo[b,d]furan
24478-72-6
Dioxins/Furans
1988 NSSS1
1,2,3,6,7,8-Hexabromodibenzofuran
107555-94-2
Dioxins/Furans
2015 BR
1,2,3,6,7,8-Hexabromodibenzo-p-dioxin
110999-45-6
Dioxins/Furans
2015 BR
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
Dioxins/Furans
1988 NSSS
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
Dioxins/Furans
1988 NSSS
1,2,3,7,8,9-Hexabromodibenzo[b,d]furan
161880-49-5
Dioxins/Furans
2015 BR
1,2,3,7,8,9-Hexabromodibenzo-p-dioxin
110999-46-7
Dioxins/Furans
2015 BR
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
Dioxins/Furans
1988 NSSS
1,2,3,7,8-Pentabromodibenzo[b,d]furan
107555-93-1
Dioxins/Furans
2015 BR
1,2,3,7,8-Pentabromodibenzo-p-dioxin
109333-34-8
Dioxins/Furans
2015 BR
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
Dioxins/Furans
1988 NSSS
1,2,5,6,9,10-Hexabromocyclododecane
3194-55-6
Flame retardant
2017 BR
1,2-Bis(2,4,6-tribromophenoxy)ethane
37853-59-1
Flame retardant
2017 BR
1,3,5-Trichlorobenzene
108-70-3
Volatile organic
2005 BR
1,3-Dichlorobenzene
541-73-1
Volatile organic
2005 BR
1,4-Dichlorobenzene
10646-7
Volatile organic
1988 NSSS
1,7-Dimethylxanthine
611-59-6
Other organics
2005 BR
10-Hydroxy Amitriptyline Oxalate
1246833-15-7
Drugs
2013 BR
10-Hydroxyamitriptyline
1159-82-6
Drugs
2013 BR
17alpha-Estradiol
57-91-0
Drugs
2005 BR
17alpha-Ethinylestradiol
57-63-6
Drugs
2005 BR
17beta-Estradiol
50-28-2
Hormones
2005 BR
2,2'-(1,2-Ethanediyl)bis(5-aminobenzenesulfonic acid)
5136-34-5
Drugs
2005 BR
B-2
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
2,2',3,3',4,4',5,5',6,6'-decabromodiphenyl ether
1163-19-5
PBDEs
2009 BR
2,2',3,3',4,4',5,6'-Octachlorobiphenyl
42740-50-1
PCB
2019 BR
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
PCB
2019 BR
2,2',3,3',4,4'-Hexachlorobiphenyl
38380-07-3
PCB
2019 BR
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
PCB
2019 BR
2,2',3,3',4,5-Hexachlorobiphenyl
55215-18-4
PCB
2019 BR
2,2',3,3',4,6-Hexachlorobiphenyl
61798-70-7
PCB
2019 BR
2,2',3,3',5,5',6-Heptachlorobiphenyl
52663-67-9
PCB
2019 BR
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
PCB
2019 BR
2,2',3,4,4',5,5',6-Octachlorobiphenyl
52663-76-0
PCB
2019 BR
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
PCB
2019 BR
2,2',3,4,4',5',6-Heptabromodiphenyl ether
207122-16-5
PBDEs
2009 TNSSS
2,2',3,4,4',5-Hexabromobiphenyl
67888-98-6
PCB
2009 TNSSS
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
PCB
2019 BR
2,2',3,4,4',6,6'-Heptabromodiphenyl ether
117948-63-7
PBDEs
2017 BR
2,2',3,4,4'-Pentabromodiphenyl ether
182346-21-0
PBDEs
2009 BR
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
PCB
2019 BR
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
PCB
2019 BR
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
PCB
2019 BR
2,2',3,5-Tetrachlorobiphenyl
7036246-8
PCB
2019 BR
2,2',3,6-Tetrachlorobiphenyl
7036245-7
PCB
2019 BR
2,2',4,4',5,5'-Hexabromobiphenyl
5908040-9
Flame retardant
2005 BR
2,2',4,4',5,5'-Hexabromodiphenyl ether
6863149-2
PBDEs
2009 TNSSS
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
PCB
2019 BR
2,2',4,4',5,6'-Hexabromodiphenyl ether
207122-154
PBDEs
2009 TNSSS
2,2',4,4',5-Pentabromodiphenyl ether
60348-60-9
PBDEs
2009 TNSSS
2,2',4,4'-T etrabromodiphenyl ether
5436-43-1
PBDEs
2009 TNSSS
2,2',4,4'-Tetrachlorobiphenyl
2437-79-8
PCB
2019 BR
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
PCB
2019 BR
2,2',4,5'-Tetrachlorobiphenyl
4146440-8
PCB
2019 BR
2,2',4,5-Tetrachlorobiphenyl
7036247-9
PCB
2019 BR
2,2',4,6'-Tetrachlorobiphenyl
68194-04-7
PCB
2019 BR
2,2',4-T ribromodiphenyl ether
147217-75-2
PBDEs
2017 BR
2,2',5,5'-Tetrachlorobiphenyl
35693-99-3
PCB
2019 BR
2,2',6-Trichlorobiphenyl
38444-734
PCB
2019 BR
2,2',3,3',4,4',5,5',6-Nonabromodiphenyl ether
63387-28-0
PBDEs
2017 BR
2,2',3,3',4,4',5,6,6'-Nonabromodiphenyl ether
437701-79-6
PBDEs
2017 BR
2,2',3,3',4,4',5,6'-Octabromodiphenyl ether
446255-39-6
PBDEs
2017 BR
2,2',3,3',4,4',6,6'-Octabromodiphenyl ether
117964-21-3
PBDEs
2017 BR
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl) ester
phosphoric acid
38051-104
Other organics
2019 BR
2,2'-Dichlorobiphenyl
13029-08-8
PCB
2019 BR
2,3,3',4,4',5,5'-Heptachlorobiphenyl
39635-31-9
PCB
2001 NSSS
2,3,3',4,4',5',6-Heptabromodiphenyl ether
446255-30-7
PBDEs
2017 BR
2,3,3',4,4',5,6-Heptachlorobiphenyl
41411-64-7
PCB
2019 BR
2,3,3',4,4',5'-Hexachlorobiphenyl
69782-90-7
PCB
2001 NSSS
2,3,3',4,4',5-Hexachlorobiphenyl
38380-084
PCB
2001 NSSS
2,3,3',4,4',6-Hexachlorobiphenyl
74472-42-7
PCB
2019 BR
2,3,3',4,4'-Pentachlorobiphenyl
32598-144
PCB
2001 NSSS
B-3
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
2,3,3',4',5,6-Hexachlorobiphenyl
74472-44-9
PCB
2019 BR
2,3',4,4',5,5'-Hexachlorobiphenyl
52663-72-6
PCB
2001 NSSS
2,3,4,4',5-Pentachlorobiphenyl
74472-37-0
PCB
2001 NSSS
2,3',4,4',5-Pentachlorobiphenyl
31508-00-6
PCB
2001 NSSS
2',3,4,4',5-Pentachlorobiphenyl
65510-44-3
PCB
2001 NSSS
2,3',4,4'-Tetrachlorobiphenyl
32598-10-0
PCB
2019 BR
2,3,4,5,6-Pentabromoethylbenzene
85-22-3
Flame retardant
2017 BR
2,3,4,6,7,8-Hexabromodibenzo[b,d]furan
161880-50-8
Dioxins/Furans
2015 BR
2,3,4,6,7,8-Hexachlorodibenzo[b,d]furan
60851-34-5
Dioxins/Furans
1988 NSSS
2,3,4,7,8-Pentabromodibenzofuran
131166-92-2
Dioxins/Furans
2015 BR
2,3,4,7,8-Pentachlorodibenzofuran
57117-314
Dioxins/Furans
1988 NSSS
2,3,4'-Trichlorobiphenyl
38444-85-8
PCB
2019 BR
2,3,6-Trichlorobiphenyl
55702-45-9
PCB
2019 BR
2,3',6-Trichlorobiphenyl
38444-76-7
PCB
2019 BR
2,3,7,8-Tetrabromodibenzofuran
67733-57-7
Dioxins/Furans
2015 BR
2,3,7,8-Tetrabromodibenzo-p-dioxin
50585-41-6
Dioxins/Furans
2015 BR
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
Dioxins/Furans
1988 NSSS1
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
Dioxins/Furans
1988 NSSS
2,3-Dichlorobiphenyl
16605-91-7
PCB
2019 BR
2,4',5-Trichlorobiphenyl
16606-02-3
PCB
2019 BR
2,4,5-Trichlorophenol
95-95-4
Pesticides
2015 BR
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
Other organics
2019 BR
2,4'-Dichlorobiphenyl
34883-43-7
PCB
2019 BR
2,4-Dichlorophenol
120-83-2
Pesticides
2017 BR
2,4-Dichlorophenoxyacetic acid
94-75-7
Pesticides
1988 NSSS
2,4-Di-tert-butylphenol (2,4-DTBP)
96-76-4
Other organics
2019 BR
2,4-Di-tert-pentylphenol (2,4-DTPP)
120-95-6
Other organics
2019 BR
2,5-Di-tert-butylphenol (2,5-DTBP)
587545-6
Other organics
2019 BR
2,6-Dichlorobiphenyl
33146-45-1
PCB
2019 BR
2,6-Di-tert-butylphenol
128-39-2
Other organics
2005 BR
2-Butoxy-, hydrogen phosphate ethanol
14260-97-0
Other organics
2019 BR
2-Chloro-4-phenylphenol
92-04-6
Other organics
2015 BR
2-Chlorobiphenyl
2051-60-7
PCB
2019 BR
2-Chloronaphthalene
91-58-7
Other organics
2005 BR
2-Ethylhexyl diphenyl phosphate
1241-94-7
Flame retardant
2019 BR
2H,2H,3H,3H-Perfluorooctanoic acid
914637-49-3
PFAS
2019 BR
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
Other organics
2019 BR
2-Methylnaphthalene
91-57-6
Other organics
2005 BR
2-tert-Butyl-4-methoxyphenol
121-00-6
Other organics
2005 BR
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-
Henicosafluorododecyl 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-
heptadecafluorodecyl hydrogen phosphate
1158182-60-5
PFAS
2019 BR
3,3',4,4',5,5'-Hexachlorobiphenyl
32774-16-6
PCB
2001 NSSS
3,3',4,4',5-Pentachlorobiphenyl
57465-28-8
PCB
2001 NSSS
3,3',4,4'-Tetrachlorobiphenyl
32598-13-3
PCB
2001 NSSS
3,3',5,5'-Tetrabromobisphenol A
79-94-7
Flame retardant
2005 BR
3,4,4',5-Tetrachlorobiphenyl
70362-504
PCB
2001 NSSS
3,4,4'-Trichlorobiphenyl
38444-90-5
PCB
2019 BR
B-4
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
3,4-Dihydroxybenzoic acid
99-50-3
Drugs
2017 BR
3,5-Bis(1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis(1,1 -
dimethylethyl)phenyl ester benzoic acid
4221-80-1
Other organics
2019 BR
3-Methylindole
83-34-1
Other organics
2009 TNSSS
4-(1,1,3,3-T etramethylbutyl)phenol
140-66-9
Other organics
2007 BR1
4-(Butan-2-yl)-2,6-di-tert-butylphenol
17540-75-9
Other organics
2019 BR
4,4',4"-(1 -Methyl-1 -propanyl-3-ylidene)tris 2-(1,1 -dimethylethyl)-5-
methyl-phenol
1843-034
Other organics
2019 BR
4,4'-Dichlorocarbanilide
1219-994
Antimicrobial
2011 BR
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)
118-82-1
Other organics
2019 BR
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)
96-69-5
Other organics
2019 BR
4-Androstene-3,17-dione
63-05-8
Hormones
2009 TNSSS
4-Chloroaniline
10647-8
Other organics
1988 NSSS
4-Chlorobiphenyl
2051-62-9
PCB
2019 BR
4-Dimethylaminoantipyrine
58-15-1
Drugs
2005 BR
4-E pian hy droch lortetracycl ine
81163-11-3
Antibiotic
2009 TNSSS
4-Epianhydrotetracycline
7518-174
Antibiotic
2009 TNSSS
4-Epianhydrotetracycline hydrochloride
4465-65-0
Antibiotic
2009 TNSSS
4-Epichlortetracycline
14297-93-9
Antibiotic
2009 TNSSS
4-epi-0xytetracycline
14206-58-7
Antibiotic
2009 TNSSS
4-Hydroxybenzoic acid
99-96-7
Drugs
2017 BR
4-Nitrophenol
100-02-7
Drugs
2005 BR
4-Nonylphenol
104-40-5
Other organics
2005 BR
4-Nonylphenol diethoxylate
20427-84-3
Other organics
2007 BR
4-Nonylphenol, branched
84852-15-3
Other organics
2005 BR
4-Octylphenol
1806-264
Other organics
2007 BR
5-Aminosalicylic acid
89-57-6
Drugs
2005 BR
6:2 Fluorotelomer phosphate diester
57677-95-9
PFAS
2019 BR
6:2 Fluorotelomer sulfonic acid
27619-97-2
PFAS
2019 BR
6:2/8:2 Fluorotelomer phosphate diester (diPAPs)
943913-15-3
PFAS
2019 BR
8:2 Fluorotelomer phosphate diester
67841-1
PFAS
2019 BR
8:2 Fluorotelomer sulfonic acid
39108-34-4
PFAS
2019 BR
Acetaminophen
103-90-2
Drugs
2005 BR
Acetic acid
64-19-7
Drugs
1988 NSSS
Acetone
67-64-1
Volatile organic
1988 NSSS
Acetophenone
98-86-2
Drugs
1988 NSSS
Albuterol
18559-94-9
Drugs
2005 BR
Alkylbenzenesulfonate, linear
42615-29-2
Other organics
2005 BR
Alprazolam
28981-97-7
Drugs
2013 BR
Aluminum
7429-90-5
Metals
1988 NSSS
Amitriptyline
50-48-6
Drugs
2013 BR
Amlodipine
88150-42-9
Drugs
2013 BR
Ammelide
645-93-2
Other organics
2019 BR
Ammeline
645-92-1
Other organics
2019 BR
Ammonium
14798-03-9
Inorganics
2007 BR
Amoxicillin
26787-78-0
Antibiotic
2019 BR
Amphetamine
300-62-9
Drugs
2007 BR
Ampicillin
69-53-4
Antibiotic
2019 BR
Androsterone
53-41-8
Drugs
2009 TNSSS
B-5
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Anhydro-6-demethyltetracycline
4496-85-9
Antibiotic
2009 TNSSS
An hy droch lortetracycli ne
4497-08-9
Antibiotic
2009 TNSSS
Anhydroerythromycin A
23893-13-2
Drugs
2007 BR
Anhydrotetracycline
1665-56-1
Antibiotic
2009 TNSSS
Anthracene
120-12-7
PAHs
1988 NSSS
Antimony
7440-36-0
Metals
1988 NSSS
Arsenic
7440-38-2
Metals
1988 NSSS
Aspirin
50-78-2
Drugs
2005 BR
Atenolol
29122-68-7
Drugs
2015 BR
Atorvastatin
134523-00-5
Drugs
2013 BR
Azithromycin
83905-01-5
Antibiotic
2007 BR
Barium
7440-39-3
Metals
1988 NSSS
Benz(a)anthracene
56-55-3
PAHs
1988 NSSS
Benzo(a)pyrene
50-32-8
PAHs
1988 NSSS
Benzo(b)fluoranthene
205-99-2
PAHs
1988 NSSS
Benzo(k)fluoranthene
207-08-9
PAHs
1988 NSSS
Benzoic acid
65-85-0
Pesticides
1988 NSSS
Benzoylecgonine
519-09-5
Drugs
2013 BR
Benztropine
86-13-5
Drugs
2013 BR
Benzyl 4-hydroxybenzoate
94-18-8
Other organics
2017 BR
Beryllium
744041-7
Metals
1988 NSSS
beta-Sitosterol
83-46-5
Drugs
2007 BR
Bezafibrate
41859-67-0
Drugs
2005 BR
Bis(1,3-dichloropropan-2-yl) hydrogen phosphate
72236-72-7
Flame retardant
2019 BR
Bis(1 -chloropropan-2-yl) hydrogen phosphate
789440-10-4
Flame retardant
2019 BR
Bis(2-chloroethyl) phosphate
3040-56-0
Other organics
2019 BR
Bis(2-ethylhexyl) phosphate
298-07-7
Other organics
2019 BR
Bis(2-methylphenyl) hydrogen phosphate
35787-74-7
Other organics
2019 BR
Bisphenol A
80-05-7
Drugs
2007 BR
Bisphenol A bis(diphenyl phosphate) (BDP)
5945-33-5
Other organics
2019 BR
Bisphenol A Polycarbonate
25766-59-0
Other organics
2019 BR
Boron
744042-8
Inorganics
1988 NSSS
Butylated hydroxyanisole
25013-16-5
Other organics
2005 BR
Butylated hydroxytoluene
128-37-0
Other organics
2005 BR
Butylparaben
94-26-8
Antimicrobial
2017 BR
Cadmium
744043-9
Metals
1988 NSSS
Caffeine
58-08-2
Drugs
2005 BR
Calcium
7440-70-2
Metals
1988 NSSS
Campesterol
474-62-4
Other organics
2009 TNSSS
Carbadox
6804-07-5
Antibiotic
2005 BR
Carbamazepine
298-46-4
Drugs
2005 BR
Carbon tetrachloride
56-23-5
Volatile organic
2005 BR
Cefotaxime
63527-52-6
Antibiotic
2009 TNSSS
Cerium
744045-1
Metals
2005 BR
Cesium
744046-2
Metals
2019 BR
Chloroform
67-66-3
Volatile organic
1988 NSSS
Chlortetracycline
57-62-5
Antibiotic
2009 BR
Cholestan-3-ol, (3.beta.,5.alpha.)-
80-97-7
Other organics
2009 TNSSS
Cholesterol
57-88-5
Drugs
2005 BR
B-6
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Chromium
744047-3
Metals
1988 NSSS
Chrysene
218-01-9
PAHs
1988 NSSS
Cimetidine
51481-61-9
Drugs
2005 BR
Ciprofloxacin
85721-33-1
Antibiotic
2005 BR
Clarithromycin
81103-11-9
Antibiotic
2007 BR
Clinafloxacin
105956-97-6
Antibiotic
2009 TNSSS
Clindamycin
18323-44-9
Antibiotic
2011 BR
Clofibric acid
882-09-7
Drugs
2005 BR
Clorophene
120-32-1
Pesticides
2015 BR
Clotrimazole
23593-75-1
Drugs
2011 BR
Cloxacillin
61-72-3
Antibiotic
2009 TNSSS
Cobalt
744048-4
Metals
1988 NSSS
Cocaine
50-36-2
Drugs
2013 BR
Codeine
76-57-3
Drugs
2005 BR
Copper
7440-50-8
Metals
1988 NSSS
Coprosterol
360-68-9
Other organics
2007 BR
Cotinine
486-56-6
Other organics
2005 BR
Cresyl diphenyl phosphate (CDPP)
2644449-5
Flame retardant
2019 BR
Cyanide
57-12-5
Inorganics
1988 NSSS
Cyanuric acid
108-80-5
Other organics
2019 BR
Cyclophosphamide
50-18-0
Drugs
2005 BR
Decachlorobiphenyl
2051-24-3
PCB
2019 BR
Decamethylcyclopentasiloxane
541-02-6
Other organics
2015 BR
Dechlorane 603
13560-924
Flame retardant
2017 BR
Dechlorane Plus
13560-89-9
Flame retardant
2017 BR
DEET
134-62-3
Pesticides
2005 BR
Demeclocycline
127-33-3
Antibiotic
2009 TNSSS
Desmosterol
313-04-2
Other organics
2009 TNSSS
Di(2-ethylhexyl) phthalate
117-81-7
Other organics
2005 BR
Diazepam
439-14-5
Drugs
2005 BR
Dibutyl ester phosphoric acid
107-66-4
Other organics
2019 BR
Dibutyl phthalate
84-74-2
Other organics
1988 NSSS
Dichlorobiphenyl
25512-42-9
PCB
2019 BR
Dichloromethane
75-09-2
Volatile organic
1988 NSSS
Dichlorophen
97-23-4
Pesticides
2015 BR
Diclofenac
15307-86-5
Drugs
2011 BR
Diclofenac sodium
15307-79-6
Drugs
2005 BR
Diethyl hydrogen phosphate
598-02-7
Flame retardant
2019 BR
Digoxigenin
1672464
Drugs
2009 TNSSS
Digoxin
20830-75-5
Drugs
2005 BR
Diisobutyl hydrogen phosphate
6303-30-6
Other organics
2019 BR
Dimethoate
60-51-5
Pesticides
1988 NSSS
Dimethyl 2,6-dimethyl-4-(2-nitrophenyl)-3,5-pyridinedicarboxylate
67035-22-7
Drugs
2009 TNSSS
Dimethyl phthalate
131-11-3
Other organics
1988 NSSS
Di-n-octyl phthalate
117-84-0
Other organics
1988 NSSS
Diphenhydramine
58-73-1
Drugs
2007 BR
Diphenyl phosphate (DPHP)
838-85-7
Other organics
2019 BR
Dipropyl ester phosphoric acid
1804-93-9
Other organics
2019 BR
D-Limonene
5989-27-5
Fragrance
2007 BR
B-7
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Doxycycline
564-25-0
Antibiotic
2005 BR
Endosulfan I
959-98-8
Pesticides
1988 NSSS
Endosulfan II
33213-65-9
Pesticides
1988 NSSS
Enrofloxacin
93106-60-6
Antibiotic
2009 TNSSS
Epitetracycline
79-85-6
Antibiotic
2009 TNSSS
Epitetracycline hydrochloride
23313-80-6
Antibiotic
2009 TNSSS
Equilenin
517-09-9
Drugs
2009 TNSSS
Equilin
474-86-2
Drugs
2005 BR
Ergosterol
57-87-4
Drugs
2009 TNSSS
Erythromycin
114-07-8
Antibiotic
2005 BR
Estradiol benzoate
50-50-0
Drugs
2009 TNSSS
Estriol
50-27-1
Hormones
2005 BR
Estrone
53-16-7
Hormones
2005 BR
Ethylbenzene
100-41-4
Volatile organic
1988 NSSS
Ethylene glycol nonylphenyl ether
27986-36-3
Other organics
2007 BR
Ethylparaben
120-47-8
Antimicrobial
2017 BR
Fenofibric acid
42017-89-0
Drugs
2005 BR
Fenthion
55-38-9
Pesticides
2005 BR
Fipronil
120068-37-3
Pesticides
2011 BR
Fipronil amide
205650-69-7
Pesticides
2019 BR
Fipronil sulfide
120067-83-6
Pesticides
2019 BR
Fipronil sulfone
120068-36-2
Pesticides
2019 BR
Fipronil desulfinyl
205650-65-3
Pesticides
2019 BR
Floxacillin
5250-39-5
Antibiotic
2005 BR
Flumequine
42835-25-6
Antibiotic
2009 TNSSS
Fluoranthene
206-44-0
PAHs
1988 NSSS
Fluoride
1698448-8
Inorganics
1988 NSSS
Fluoxetine
54910-89-3
Drugs
2005 BR
Furosemide
54-31-9
Drugs
2013 BR
Galaxolide
1222-05-5
Fragrance
2005 BR
Gemfibrozil
25812-30-0
Drugs
2005 BR
Glybenclamide
10238-21-8
Drugs
2013 BR
Heptachlor epoxide B
1024-57-3
Pesticides
1988 NSSS
Heptachlorobiphenyl
28655-71-2
PCB
2019 BR
Heptachlorodibenzofuran
38998-75-3
Dioxins/Furans
1988 NSSS
Heptachlorodibenzo-p-dioxin
37871-004
Dioxins/Furans
1988 NSSS
Hexabromobenzene
87-82-1
Flame retardant
2017 BR
Hexachlorobiphenyl
26601-64-9
PCB
2019 BR
Hexachlorodibenzofuran
55684-94-1
Dioxins/Furans
1988 NSSS
Hexachlorodibenzo-p-dioxin
34465-46-8
Dioxins/Furans
1988 NSSS
Hexanoic acid
142-62-1
Other organics
1988 NSSS
Hydrocodone
125-29-1
Drugs
2013 BR
Ibuprofen
15687-27-1
Drugs
2005 BR
Indole
120-72-9
Drugs
2007 BR
Iron
7439-89-6
Metals
1988 NSSS
I soch I ortetracycl i n e
514-53-4
Antibiotic
2009 TNSSS
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
Flame retardant
2019 BR
Ketoprofen
22071-154
Drugs
2005 BR
Lead
7439-92-1
Metals
1988 NSSS
B-8
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Levonorgestrel
797-63-7
Drugs
2005 BR
Lincomycin
154-21-2
Antibiotic
2009 BR
Lomefloxacin
98079-51-7
Antibiotic
2009 TNSSS
Magnesium
7439-95-4
Metals
1988 NSSS
Manganese
7439-96-5
Metals
1988 NSSS
MDMA
42542-10-9
Drugs
2009 BR
Mefenamic acid
61-68-7
Drugs
2005 BR
Melamine
108-78-1
Other organics
2019 BR
Mercury
7439-97-6
Metals
1988 NSSS
Mestranol
72-33-3
Drugs
2005 BR
Metformin
657-24-9
Drugs
2009 TNSSS
Methamphetamine
53746-2
Drugs
2007 BR
Methyl 3,4-dihydroxybenzoate
215043-8
Other organics
2017 BR
Methyl triclosan
4640-01-1
Antimicrobial
2017 BR
Methylparaben
99-76-3
Other organics
2017 BR
Metoprolol
51384-51-1
Drugs
2005 BR
Miconazole
22916-47-8
Drugs
2009 TNSSS
Minocycline
10118-90-8
Antibiotic
2009 TNSSS
Molybdenum
7439-98-7
Metals
1988 NSSS
Monochlorobiphenyl
27323-18-8
PCB
2019 BR
Monuron
150-68-5
Pesticides
2005 BR
Musk ketone
81-14-1
Fragrance
2005 BR
Musk Xylene
81-15-2
Fragrance
2005 BR
m-Xylene
108-38-3
Volatile organic
1988 NSSS
Nadolol
42200-33-9
Drugs
2005 BR
Nalidixic acid
389-08-2
Antibiotic
2019 BR
Naphthalene
91-20-3
PAHs
1988 NSSS
Naproxen
22204-53-1
Drugs
2005 BR
N-Demethyldiltiazem hydrochloride
130606-60-9
Drugs
2013 BR
N-Desmethyldiltiazem
86408-45-9
Drugs
2013 BR
Nickel
7440-02-0
Metals
1988 NSSS
Nitrate
14797-55-8
Inorganics
1988 NSSS
Nitrite
14797-65-0
Inorganics
1988 NSSS
Nitrofen
1836-75-5
Pesticides
1988 NSSS
Nitrogen
7727-37-9
Inorganics
2007 BR
N-Nitrosodibutylamine
924-16-3
Other organics
2015 BR
N-Nitrosodiethylamine
55-18-5
Other organics
2015 BR
N-Nitrosodimethylamine
62-75-9
Other organics
2015 BR
N-Nitrosodi-n-propylamine
621-64-7
Other organics
2015 BR
N-Nitrosodiphenylamine
86-30-6
Other organics
1988 NSSS
N-Nitrosopiperidine
100-75-4
Other organics
2015 BR
N-Nitrosopyrrolidine
930-55-2
Other organics
2015 BR
n-Nonylphenol
25154-52-3
Other organics
2005 BR
n-Octylphenol
67554-50-1
Other organics
2005 BR
Nonabromodiphenyl ether
63936-56-1
PBDEs
2017 BR
Nonachlorobiphenyl
53742-07-7
PCB
2019 BR
Norethindrone
68-22-4
Drugs
2005 BR
Norfloxacin
70458-96-7
Antibiotic
2005 BR
Norfluoxetine
83891-03-6
Drugs
2011 BR
B-9
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Norgestimate
35189-28-7
Drugs
2009 TNSSS
Norverapamil
67018-85-3
Drugs
2013 BR
Octabromodibenzo-p-dioxin
217045-8
Dioxins/Furans
2015 BR
Octachlorobiphenyl
55722-264
PCB
2019 BR
Octachlorodibenzofuran
39001-02-0
Dioxins/Furans
1988 NSSS
Octachlorodibenzo-p-dioxin
3268-87-9
Dioxins/Furans
1988 NSSS
Ofloxacin
82419-36-1
Antibiotic
2009 TNSSS
Ormetoprim
6981-18-6
Antibiotic
2009 TNSSS
Oxacillin
66-79-5
Antibiotic
2009 TNSSS
Oxolinic acid
14698-294
Antibiotic
2009 TNSSS
Oxycodone
76-42-6
Drugs
2013 BR
o-Xylene
95-47-6
Volatile organic
1988 NSSS
Oxytetracycline
79-57-2
Antibiotic
2005 BR
Paroxetine
61869-08-7
Drugs
2013 BR
p-Cresol
106-44-5
Volatile organic
1988 NSSS
Penicillin G
61-33-6
Antibiotic
2009 TNSSS
Penicillin V
87-08-1
Antibiotic
2005 BR
Pentabromodiphenyl ether
32534-81-9
PBDEs
2009 BR
Pentachlorobiphenyl
25429-29-2
PCB
2019 BR
Pentachlorodibenzodioxin
36088-22-9
Dioxins/Furans
1988 NSSS
Pentachlorodibenzofuran
30402-154
Dioxins/Furans
1988 NSSS
Pentachloronitrobenzene
82-68-8
Pesticides
1988 NSSS
Perfluorobutanesulfonate
45187-15-3
PFAS
2013 BR
Perfluorobutanesulfonic acid (PFBS)
375-73-5
PFAS
2013 BR3
Perfluorobutanoic acid (PFBA)
375-22-4
PFAS
2013 BR
Perfluorodecanoic acid (PFDA)
335-76-2
PFAS
2013 BR
Perfluorododecanoic acid (PFDoDA)
307-55-1
PFAS
2013 BR
Perfluoroheptanoic acid (PFHpA)
375-85-9
PFAS
2013 BR
Perfluorohexanesulfonate
108427-53-8
PFAS
2013 BR
Perfluorohexanesulfonic acid (PFHxS)
35546-4
PFAS
2013 BR2
Perfluorohexanoic acid (PFHxA)
307-24-4
PFAS
2013 BR
Perfluorononanoic acid (PFNA)
375-95-1
PFAS
2013 BR
Perfluorooctanesulfonamide (PFOSA)
754-91-6
PFAS
2013 BR
Perfluorooctanesulfonic acid (PFOS)
1763-23-1
PFAS
2013 BR
Perfluorooctanoic acid (PFOA)
335-67-1
PFAS
2013 BR
Perfluoropentanoic acid (PFPeA)
2706-90-3
PFAS
2013 BR
Perfluorotetradecanoic acid (PFTeDA)
376-06-7
PFAS
2017 BR
Perfluorotridecanoic acid (PFTrDA)
72629-94-8
PFAS
2017 BR
Perfluoroundecanoic acid (PFUdA)
2058-94-8
PFAS
2013 BR
Phenanthrene
85-01-8
PAHs
1988 NSSS
Phenazone
60-80-0
Drugs
2005 BR
Phenol
108-95-2
Drugs
1988 NSSS
Phosphate
14265-44-2
Inorganics
2005 BR
Phosphorus
7723-14-0
Inorganics
2007 BR
Polychlorinated biphenyl (PCB)
1336-36-3
PCB
2019 BR
Polyethylene glycol
25322-68-3
Drugs
2005 BR
Polyethylene terephthalate
25038-59-9
Other organics
2019 BR
Potassium
7440-09-7
Metals
2007 BR
B-10
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Potassium perfluorooctanesulfonate
2795-39-3
PFAS
2013 BR
Progesterone
57-83-0
Hormones
2005 BR
Promethazine
60-87-7
Drugs
2013 BR
Propoxyphene
469-62-5
Drugs
2013 BR
Propranolol
525-66-6
Drugs
2005 BR
Propylparaben
94-13-3
Other organics
2017 BR
p-Xylene
106-42-3
Volatile organic
1988 NSSS
Pyrene
129-00-0
PAHs
1988 NSSS
Quinine sulfate
7778-93-0
Other organics
2005 BR
Ranitidine
66357-35-5
Drugs
2005 BR
Resorcinol bis(diphenyl phosphate) (RDP)
57583-54-7
Flame retardant
2019 BR
Roxithromycin
80214-83-1
Antibiotic
2007 BR
Rubidium
7440-17-7
Metals
2005 BR
Salicylic acid
69-72-7
Drugs
2005 BR
Sarafloxacin
98105-99-8
Antibiotic
2009 TNSSS
Selenium
778249-2
Metals
1988 NSSS
Sertraline
79617-96-2
Drugs
2013 BR
Silver
7440-22-4
Metals
1988 NSSS
Sodium
7440-23-5
Metals
1988 NSSS
Sodium perfluorodecanesulfonate (PFDS)
2806-15-7
PFAS
2019 BR
Sodium valproate
1069-66-5
Drugs
2005 BR
Stigmastan-3beta-ol
19466-47-8
Other organics
2007 BR
Stigmastanol
138126-65-5
Drugs
2007 BRb
Stigmasterol
83-48-7
Drugs
2009 TNSSS
Styrene
100-42-5
Other organics
1988 NSSS
Sulfachloropyridazine
80-32-0
Ant
biotic
2009 TNSSS
Sulfadiazine
68-35-9
Ant
biotic
2009 TNSSS
Sulfadimethoxine
122-11-2
Ant
biotic
2009 BR
Sulfamerazine
127-79-7
Ant
biotic
2005 BR
Sulfamethazine
57-68-1
Ant
biotic
2005 BR
Sulfamethizole
144-82-1
Ant
biotic
2009 TNSSS
Sulfamethoxazole
723-46-6
Ant
biotic
2009 TNSSS
Sulfanilamide
63-74-1
Ant
biotic
2009 TNSSS
Sulfasalazine
599-79-1
Ant
biotic
2005 BR
Sulfate
14808-79-8
Inorganics
2019 BR
Sulfathiazole
72-14-0
Antibiotic
2009 TNSSS
Sulfur
7704-34-9
Inorganics
2019 BR
Terephthalic acid
100-21-0
Other organics
2019 BR
tert-Butylphenyl diphenyl phosphate
56803-37-3
Flame retardant
2019 BR
Testosterone
58-22-0
Hormones
2009 BR
Tetrabromodiphenyl ether
40088-47-9
PBDEs
2009 TNSSS4
Tetrabutyl ethylidenebisphenol (A022E46)
35958-30-6
Other organics
2019 BR
Tetrachlorobiphenyl
26914-33-0
PCB
2019 BR
Tetrachlorodibenzodioxin
41903-57-5
Dioxins/Furans
1988 NSSS
Tetrachlorodibenzofuran
30402-14-3
Dioxins/Furans
1988 NSSS
Tetrachloroethylene
127-18-4
Volatile organic
2005 BR
Tetracycline
60-54-8
Antibiotic
2009 BR
Thallium
7440-28-0
Metals
1988 NSSS
B-ll
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Thiabendazole
148-79-8
Pesticides
2009 TNSSS
Tin
7440-31-5
Metals
1988 NSSS
Titanium
7440-32-6
Metals
1988 NSSS
Toluene
108-88-3
Volatile organic
1988 NSSS
Tonalide
21145-77-7
Fragrance
2007 BR
Tr
amterene
396-01-0
Drugs
2013 BR
Tr
butyl phosphate
126-73-8
Flame retardant
2019 BR
Tr
chlorfon
52-68-6
Pesticides
2005 BR
Tr
chlorobiphenyl
25323-68-6
PCB
2019 BR
Tr
clocarban
101-20-2
Antimicrobial
2007 BR
Tr
closan
3380-34-5
Drugs
2005 BR
Tr
ethyl phosphate (TEP)
78-40-0
Flame retardant
2019 BR
Tr
ethylene glycol bis(3-tert-butyI-4-hydroxy-5-
methylphenyl)propionate (AO-245)
36443-68-2
Other organics
2019 BR
Tr
isobutyl phosphate
126-71-6
Flame retardant
2019 BR
Tr
methoprim
738-70-5
Antibiotic
2005 BR
Tr
methyl phosphate (TMP)
512-56-1
Flame retardant
2019 BR
Tr
methylsilanol (TMS)
1066-40-6
Flame retardant
2019 BR
Tr
phenyl phosphate
115-86-6
Flame retardant
2005 BR
Tr
propyl phosphate
513-08-6
Flame retardant
2019 BR
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
Flame retardant
2019 BR
Tr
s(2-butoxyethyl) phosphate
78-51-3
Flame retardant
2005 BR
Tr
s(2-chloroethyl) phosphate
115-96-8
Flame retardant
2005 BR
Tr
s(2-chloroisopropyl) phosphate
13674-84-5
Flame retardant
2019 BR
Tr
s(2-ethylhexyl) phosphate (TEHP)
7842-2
Flame retardant
2019 BR
Tr
s(4-tert-butylphenyl) phosphate
78-33-1
Flame retardant
2019 BR
Tr
s(methylphenyl) phosphate
1330-78-5
Flame retardant
2019 BR
Tylosin
1401-69-0
Antibiotic
2005 BR
Valsartan
137862-53-4
Drugs
2013 BR
Vanadium
7440-62-2
Metals
1988 NSSS
Virginiamycin
11006-76-1
Antibiotic
2005 BR
Warfarin
81-81-2
Drugs
2009 TNSSS
Yttrium
7440-65-5
Metals
1988 NSSS
Zinc
7440-66-6
Metals
1988 NSSS
a-Dihydroequilin
651-55-8
Drugs
2009 TNSSS
Microbial Pollutants
Aerobic endospores
NA
Bacteria
2013 BR
Aeromonas spp.
NA
Bacteria
2009 BR
Antibiotic-resistant bacteria (ARB) or Antibiotic-resistant genes
(ARG)
NA
Bacteria
2013 BR
Clostridia spp.
NA
Bacteria
2007 BR
Clostridium perfringens
NA
Bacteria
2019 BR
Coronavirus HKU1
NA
Virus
2013 BR
Cosavirus
NA
Virus
2013 BR
Cryptosporidium parvum
NA
Protozoan parasite
2007 BR
Endotoxin
NA
Micrbial toxin
2007 BR
Enterovirus
NA
Virus
2009 BR
Enterococcus spp.
NA
Bacteria
2019 BR
B-12
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table B-1. Chemical and Microbial Pollutants Identified in Biosolids
Chemical
CAS number
Category
When identified
Escherichia coli
NA
Bacteria
2009 BR
Fecal coliforms
NA
Bacteria
2019 BR
Giardia spp.
NA
Protozoan parasite
2009 BR
Human adenoviruses
NA
Virus
2009 BR
Human norovirus
NA
Virus
2013 BR
Human polyomaviruses
NA
Virus
2011 BR
Klassevirus
NA
Virus
2013 BR
Listeria spp.
NA
Bacteria
2009 BR
Salmonella spp.
NA
Bacteria
2007 BR
Total coliforms
NA
Bacteria
2019 BR
Yersinia spp.
NA
Bacteria
2019 BR
Notes:
BR = Biennial Review
CAS = Chemical Abstracts Service
NA = Not applicable
NSSS = National Sewage Sludge Survey
PBDE = Polybrominated diphenyl ethers
PFAS = Per- and polyfluoroalkyl substances
TNSSS = Targeted National Sewage Sludge Survey
1 = The class Total tetrachlorodibenzofurans' was analyzed in the 1988 NSSS. This is a specific chemical member of the class of
tetrachlorodibenzofurans.
2 = Chemicals in the PFAS family can exist in various ion states (e.g., acids, anions, cations). This is the acid state of perfluorohexanesulfonate.
3 = Chemicals in the PFAS family can exist in various ion states (e.g., acids, anions, cations). This is the acid state of perfluorobutanesulfonate.
4 = Two chemicals from the class 'Tetrabromodiphenyl ether1 were analyzed in the 2009 TNSSS. This is the chemical class 'Tetrabromodiphenyl ether'
that contain members of the family.
5 = Members of the class 'Stigmastanol' were analyzed beginning in the 2007 Biennial Review. This is the chemical class 'Stigmastanol' that contain
members of that family.
The list includes only chemicals identified through biennial reviews and sewage sludge surveys. This list does not include chemicals identified in the
2003 literature review conducted as part of of the EPA response to the 2002 National Research Council (NRC) report reviewing the biosolids
regulation (68 FR 75531).
B-13
-------
Biosolids Biennial Review Reporting Period 2018-2019
Appendix C. Concentrations of Chemicals Found in Biosolids
c-i
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Tetrabutyl ethylidenebisphenol (A022E46)
35958-30-6
New
Various
No
2016
57
ng/g, dw
median
Luetal. 2019
Tetrabutyl ethylidenebisphenol (A022E46)
35958-30-6
New
Various
No
2016
6.6
ng/g, dw
min
Luetal. 2019
Tetrabutyl ethylidenebisphenol (A022E46)
35958-30-6
New
Various
No
2016
86
ng/g, dw
max
Luetal. 2019
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
New
Various
No
2016
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Bis(1,3-dichloropropan-2-yl) hydrogen phosphate
72236-72-7
New
Not specif
ed
Yes
2006-2007
81.7
ng/g, dw
mean
Wang et al. 2019
Bis(1,3-dichloropropan-2-yl) hydrogen phosphate
72236-72-7
New
Not specif
ed
Yes
2006-2007
9.48
ng/g, dw
median
Wang et al. 2019
Bis(1,3-dichloropropan-2-yl) hydrogen phosphate
72236-72-7
New
Not specif
ed
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Bis(1,3-dichloropropan-2-yl) hydrogen phosphate
72236-72-7
New
Not specif
ed
Yes
2006-2007
1880
ng/g, dw
max
Wang et al. 2019
Bis(1 -Chloropropan-2-yl) hydrogen phosphate
789440-10-4
New
Not specif
ed
Yes
2006-2007
2.13
ng/g, dw
mean
Wang et al. 2019
Bis(1 -Chloropropan-2-yl) hydrogen phosphate
789440-10-4
New
Not specif
ed
Yes
2006-2007
n.d.
ng/g, dw
median
Wang et al. 2019
Bis(1 -Chloropropan-2-yl) hydrogen phosphate
789440-10-4
New
Not specif
ed
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Bis(1 -Chloropropan-2-yl) hydrogen phosphate
789440-10-4
New
Not specif
ed
Yes
2006-2007
62.9
ng/g, dw
max
Wang et al. 2019
Bis(2-chloroethyl) phosphate
3040-56-0
New
Not specif
ed
Yes
2006-2007
5.08
ng/g, dw
mean
Wang et al. 2019
Bis(2-chloroethyl) phosphate
3040-56-0
New
Not specif
ed
Yes
2006-2007
1.72
ng/g, dw
median
Wang et al. 2019
Bis(2-chloroethyl) phosphate
3040-56-0
New
Not specif
ed
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Bis(2-chloroethyl) phosphate
3040-56-0
New
Not specif
ed
Yes
2006-2007
26.2
ng/g, dw
max
Wang et al. 2019
Bis(2-ethylhexyl) phosphate
298-07-7
New
Not specif
ed
Yes
2006-2007
26.6
ng/g, dw
mean
Wang et al. 2019
Bis(2-ethylhexyl) phosphate
298-07-7
New
Not specif
ed
Yes
2006-2007
7.31
ng/g, dw
median
Wang et al. 2019
Bis(2-ethylhexyl) phosphate
298-07-7
New
Not specif
ed
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Bis(2-ethylhexyl) phosphate
298-07-7
New
Not specif
ed
Yes
2006-2007
366
ng/g, dw
max
Wang et al. 2019
2-Butoxy-, hydrogen phosphate ethanol
14260-97-0
New
Not specif
ed
Yes
2006-2007
31.3
ng/g, dw
mean
Wang et al. 2019
2-Butoxy-, hydrogen phosphate ethanol
14260-97-0
New
Not specif
ed
Yes
2006-2007
17.7
ng/g, dw
median
Wang et al. 2019
2-Butoxy-, hydrogen phosphate ethanol
14260-97-0
New
Not specif
ed
Yes
2006-2007
3.21
ng/g, dw
min
Wang et al. 2019
2-Butoxy- hydrogen phosphate ethanol
14260-97-0
New
Not specif
ed
Yes
2006-2007
219
ng/g, dw
max
Wang et al. 2019
Bis(2-methylphenyl) hydrogen phosphate
35787-74-7
New
Not specif
ed
Yes
2006-2007
4.57
ng/g, dw
mean
Wang et al. 2019
Bis(2-methylphenyl) hydrogen phosphate
35787-74-7
New
Not specif
ed
Yes
2006-2007
0.15
ng/g, dw
median
Wang et al. 2019
Bis(2-methylphenyl) hydrogen phosphate
35787-74-7
New
Not specif
ed
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Bis(2-methylphenyl) hydrogen phosphate
35787-74-7
New
Not specif
ed
Yes
2006-2007
305
ng/g, dw
max
Wang et al. 2019
Bisphenol A bis(diphenyl phosphate) (BDP)
5945-33-5
New
Not specif
ed
Yes
2006-2007
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Diethyl hydrogen phosphate
598-02-7
New
Not specified
Yes
2006-2007
5.28
ng/g, dw
mean
Wang et al. 2019
Diethyl hydrogen phosphate
598-02-7
New
Not specified
Yes
2006-2007
3.44
ng/g, dw
median
Wang et al. 2019
Diethyl hydrogen phosphate
598-02-7
New
Not specified
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Diethyl hydrogen phosphate
598-02-7
New
Not specified
Yes
2006-2007
50.6
ng/g, dw
max
Wang et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
29.2
mg/kg, dw
mean
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
0.707
mg/kg, dw
min
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
314
mg/kg, dw
max
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
62.78
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
16.84
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
27.50
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
18.48
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
28.18
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
17.66
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
59.37
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
20.97
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
39.56
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
46.15
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
2.37
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
18.62
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
5.22
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
7.32
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N, N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
6.98
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
20.08
mg/kg, dw
individual
Menzies et al. 2019
C-4
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
0.71
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyi)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
27.64
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
10.59
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
37.93
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
14.51
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
1.85
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
25.72
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
25.72
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
79.84
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
2.08
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
14.03
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
0.97
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N, N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
16.74
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
4.76
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N, N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
13.14
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N, N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
7.24
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N, N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
2.24
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
31.44
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
3.94
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
81.74
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
7.11
mg/kg, dw
individual
Menzies et al. 2019
C-5
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
1.03
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyi)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
51.91
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
18.56
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
30.62
mg/kg, dw
individual
Menzies et al. 2019
2-Hydroxy-N-(2-hydroxyethyl)-N,N-dimethyl-ethanaminium esters
with C16-18 and C18-unsatd. fatty acids, chlorides (DEEDMAC)
1079184-43-2
New
Not specified
No
Jul-Nov 2017
313.96
mg/kg, dw
individual
Menzies et al. 2019
Diisobutyl hydrogen phosphate
6303-30-6
New
Not specified
Yes
2006-2007
10.3
ng/g, dw
mean
Wang et al. 2019
Diisobutyl hydrogen phosphate
6303-30-6
New
Not specified
Yes
2006-2007
5.27
ng/g, dw
median
Wang et al. 2019
Diisobutyl hydrogen phosphate
6303-30-6
New
Not specified
Yes
2006-2007
2.13
ng/g, dw
min
Wang et al. 2019
Diisobutyl hydrogen phosphate
6303-30-6
New
Not specified
Yes
2006-2007
130
ng/g, dw
max
Wang et al. 2019
Diphenyl phosphate (DPHP)
838-85-7
New
Not specified
Yes
2006-2007
33.5
ng/g, dw
mean
Wang et al. 2019
Diphenyl phosphate (DPHP)
838-85-7
New
Not specified
Yes
2006-2007
5.47
ng/g, dw
median
Wang et al. 2019
Diphenyl phosphate (DPHP)
838-85-7
New
Not specified
Yes
2006-2007
0.93
ng/g, dw
min
Wang et al. 2019
Diphenyl phosphate (DPHP)
838-85-7
New
Not specified
Yes
2006-2007
1680
ng/g, dw
max
Wang etal. 2019
Dipropyl ester phosphoric acid
1804-93-9
New
Not specified
Yes
2006-2007
1.12
ng/g, dw
mean
Wang etal. 2019
Dipropyl ester phosphoric acid
1804-93-9
New
Not specified
Yes
2006-2007
0.68
ng/g, dw
median
Wang etal. 2019
Dipropyl ester phosphoric acid
1804-93-9
New
Not specified
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Dipropyl ester phosphoric acid
1804-93-9
New
Not specified
Yes
2006-2007
8.93
ng/g, dw
max
Wang et al. 2019
pronil amide
205650-69-7
New
Class B
Yes
2001
2.3
ug/kg, dw
mean
Sadar
a etal. 2019
pronil amide
205650-69-7
New
Class B
Yes
2001
2.6
ug/kg, dw
median
Sadar
a etal. 2019
pronil amide
205650-69-7
New
Class B
Yes
2001
0.9
ug/kg, dw
min
Sadar
aet al. 2019
pronil amide
205650-69-7
New
Class B
Yes
2001
3.8
ug/kg, dw
max
Sadar
aet al. 2019
pronil amide
205650-69-7
New
Class B
Yes
2006-2007
4.6
ug/kg, dw
mean
Sadar
a etal. 2019
pronil amide
205650-69-7
New
Class B
Yes
2006-2007
4.0
ug/kg, dw
median
Sadar
a etal. 2019
pronil amide
205650-69-7
New
Class B
Yes
2006-2007
0.4
ug/kg, dw
min
Sadar
a etal. 2019
pronil amide
205650-69-7
New
Class B
Yes
2006-2007
18.7
ug/kg, dw
max
Sadar
a etal. 2019
pronil amide
205650-69-7
New
Class B
Yes
2015-2016
3.7
ug/kg, dw
mean
Sadar
aet al. 2019
pronil amide
205650-69-7
New
Class B
Yes
2015-2016
2.2
ug/kg, dw
median
Sadar
aet al. 2019
pronil amide
205650-69-7
New
Class B
Yes
2015-2016
1.1
ug/kg, dw
min
Sadar
a etal. 2019
pronil amide
205650-69-7
New
Class B
Yes
2015-2016
7.9
ug/kg, dw
max
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2001
0.5
ug/kg, dw
mean
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2001
0.5
ug/kg, dw
median
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2001
0.2
ug/kg, dw
min
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2001
1.3
ug/kg, dw
max
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class AA
Yes
2006-2007
1.5
ug/kg, dw
mean
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class AA
Yes
2006-2007
1.0
ug/kg, dw
median
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class AA
Yes
2006-2007
0.3
ug/kg, dw
min
Sadar
a etal. 2019
C-6
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
pronil desulfinyl
205650-65-3
New
Class AA
Yes
2006-2007
3.7
ug/kg, dw
max
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2015-2016
2.0
ug/kg, dw
mean
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2015-2016
1.7
ug/kg, dw
median
Sadar
a etal. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2015-2016
0.4
ug/kg, dw
min
Sadar
aet al. 2019
pronil desulfinyl
205650-65-3
New
Class B
Yes
2015-2016
6.6
ug/kg, dw
max
Sadar
aet al. 2019
pronil sulfide
120067-83-6
New
Class AA
Yes
2001
16.4
ug/kg, dw
mean
Sadar
aet al. 2019
pronil sulfide
120067-83-6
New
Class AA
Yes
2001
10.2
ug/kg, dw
median
Sadar
aet al. 2019
pronil sulfide
120067-83-6
New
Class AA
Yes
2001
1.2
ug/kg, dw
min
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class AA
Yes
2001
113.4
ug/kg, dw
max
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2006-2007
35.6
ug/kg, dw
mean
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2006-2007
27.5
ug/kg, dw
median
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2006-2007
1.5
ug/kg, dw
min
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2006-2007
149.2
ug/kg, dw
max
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2015-2016
27.5
ug/kg, dw
mean
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2015-2016
21.0
ug/kg, dw
median
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2015-2016
0.9
ug/kg, dw
min
Sadar
a etal. 2019
pronil sulfide
120067-83-6
New
Class B
Yes
2015-2016
114.7
ug/kg, dw
max
Sadar
aet al. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2001
18.3
ug/kg, dw
mean
Sadar
aet al. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2001
11.6
ug/kg, dw
median
Sadar
aet al. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2001
1.3
ug/kg, dw
min
Sadar
aet al. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2001
56.0
ug/kg, dw
max
Sadar
aet al. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2006-2007
53.4
ug/kg, dw
mean
Sadar
a etal. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2006-2007
37.5
ug/kg, dw
median
Sadar
a etal. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2006-2007
0.1
ug/kg, dw
min
Sadar
a etal. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2006-2007
208.6
ug/kg, dw
max
Sadar
a etal. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2015-2016
45.0
ug/kg, dw
mean
Sadar
aet al. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2015-2016
40.0
ug/kg, dw
median
Sadar
aet al. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2015-2016
2.2
ug/kg, dw
min
Sadar
a etal. 2019
pronil sulfone
120068-36-2
New
Class B
Yes
2015-2016
110.1
ug/kg, dw
max
Sadar
a etal. 2019
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
New
Not specified
Yes
2006-2007
243
ng/g, dw
mean
Wang etal. 2019
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
New
Not specified
Yes
2006-2007
31.0
ng/g, dw
median
Wang etal. 2019
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
New
Not specified
Yes
2006-2007
n.d.
ng/g, dw
min
Wang etal. 2019
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
New
Not specified
Yes
2006-2007
6150
ng/g, dw
max
Wang etal. 2019
Melamine
108-78-1
New
Not specified
Yes
2006-2007
110
ng/g, dw
mean
Zhuet al. 2019
Melamine
108-78-1
New
Not specified
Yes
2006-2007
37
ng/g, dw
median
Zhuet al. 2019
Melamine
108-78-1
New
Not specified
Yes
2006-2007
6.5
ng/g, dw
min
Zhuet al. 2019
Melamine
108-78-1
New
Not specified
Yes
2006-2007
1,300
ng/g, dw
max
Zhuet al. 2019
Nalidixic acid
389-08-2
New
Not specified
Yes
2006-2007
19.1
ng/g, dw
mean
Magee et al. 2018
Nalidixic acid
389-08-2
New
Not specified
Yes
2006-2007
9.4
ng/g, dw
min
Magee et al. 2018
Nalidixic acid
389-08-2
New
Not specified
Yes
2006-2007
33.2
ng/g, dw
max
Magee et al. 2018
C-7
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Bisphenol A Polycarbonate
25766-59-0
New
Not specified
Yes
2006-2007
47
ug/g, dw
mean
Zhang et al. 2019
Bisphenol A Polycarbonate
25766-59-0
New
Not specified
Yes
2006-2007
5.9
ug/g, dw
median
Zhang et al. 2019
Bisphenol A Polycarbonate
25766-59-0
New
Not specified
Yes
2006-2007
0.70
ug/g, dw
min
Zhang et al. 2019
Bisphenol A Polycarbonate
25766-59-0
New
Not specified
Yes
2006-2007
840
ug/g, dw
max
Zhang et al. 2019
Polychlorinated biphenyl (PCBf
1336-36-3
New
Not specified
No
2014-2015
790
ug/kg, dw
mean
2019
Polyethylene terephthalate (PET)
25038-59-9
New
Not specified
Yes
2006-2007
560
ug/g, dw
mean
Zhang et al. 2019
Polyethylene terephthalate (PET)
25038-59-9
New
Not specified
Yes
2006-2007
12,000
ug/g, dw
max
Zhang et al. 2019
Resorcinol bis(diphenyl phosphate) (RDP)
57583-54-7
New
Not specified
Yes
2006-2007
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Tr
isobutyl phosphate
126-71-6
New
Not specif
ed
Yes
2006-2007
0.15
ng/g, dw
median
Wang et al. 2019
Tr
isobutyl phosphate
126-71-6
New
Not specif
ed
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Tr
isobutyl phosphate
126-71-6
New
Not specif
ed
Yes
2006-2007
30.7
ng/g, dw
max
Wang et al. 2019
Tr
methyl phosphate (TMP)
512-56-1
New
Not specif
ed
Yes
2006-2007
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Aluminum
7429-90-5
Previous
Class A
No
Not specified
600
mg/kg
individual
Sidhuetal. 2019b
Ammonium
14798-03-9
Previous
Class B
No
Not specified
17
g/kg
individual
Silveira et al. 2019
Ammonium
14798-03-9
Previous
Class B
No
Not specified
24
g/kg
individual
Silveira et al. 2019
Ammonium
14798-03-9
Previous
Class B
No
Not specified
14
g/kg
individual
Silveira et al. 2019
Ammonium
14798-03-9
Previous
Class B
No
Not specified
11
g/kg
individual
Silveira et al. 2019
Ammonium
14798-03-9
Previous
Class AA
No
Not specified
6
g/kg
individual
Silveira et al. 2019
Ammonium
14798-03-9
Previous
Class B
No
Not specified
11
g/kg
individual
Silveira et al. 2019
Ammonium
14798-03-9
Previous
Class B
No
Not specified
3
g/kg
individual
Silveira et al. 2019
Ammonium
14798-03-9
Previous
Class A
No
Not specified
3700
mg/kg
individual
Sidhuetal. 2019b
Ammonium
14798-03-9
Previous
Not specified
No
June 2016-Sep 2017
170
mg/kg, dw
mean
Onchoke et al. 2018
Ammonium
14798-03-9
Previous
Not specified
No
June 2016-Sep 2017
205
mg/kg, dw
mean
Onchoke et al. 2018
Azithromycin
83905-01-5
Previous
Class A
No
Not specified
0.06
mg/kg, dw
individual
Sidhu et al. 2019a
Azithromycin
83905-01-5
Previous
Class A
No
Not specified
0.06
mg/kg, dw
individual
Sidhuetal. 2019b
Azithromycin
83905-01-5
Previous
Class A
No
Not specified
0.06
mg/kg, dw
individual
Sidhu et al. 2019c
Barium
7440-39-3
Previous
Not specified
No
June 2016-Sep 2017
319
mg/kg, dw
mean
Onchoke et al. 2018
Barium
7440-39-3
Previous
Not specified
No
June 2016-Sep 2017
316
mg/kg, dw
mean
Onchoke et al. 2018
Barium
7440-39-3
Previous
Class A
No
Not specified
358
mg/kg
mean
Vaughn et al. 2018
Beryllium
7440-41-7
Previous
Not specified
No
June 2016-Sep 2017
2.53
mg/kg, dw
mean
Onchoke et al. 2018
Beryllium
7440-41-7
Previous
Not specified
No
June 2016-Sep 2017
4.90
mg/kg, dw
mean
Onchoke et al. 2018
Bisphenol A
80-05-7
Previous
Not specified
Yes
2006-2007
0.43
ug/g, dw
mean
Zhang et al. 2019
Bisphenol A
80-05-7
Previous
Not specified
Yes
2006-2007
0.20
ug/g, dw
median
Zhang et al. 2019
Bisphenol A
80-05-7
Previous
Not specified
Yes
2006-2007
0.0083
ug/g, dw
min
Zhang et al. 2019
Bisphenol A
80-05-7
Previous
Not specified
Yes
2006-2007
2.5
ug/g, dw
max
Zhang et al. 2019
Boron
7440-42-8
Previous
Not specified
No
June 2016-Sep 2017
107
mg/kg, dw
mean
Onchoke et al. 2018
Boron
7440-42-8
Previous
Not specified
No
June 2016-Sep 2017
91
mg/kg, dw
mean
Onchoke et al. 2018
Butylated hydroxytoluene
128-37-0
Previous
Various
No
2016
477
ng/g, dw
median
Lu et al. 2019
Butylated hydroxytoluene
128-37-0
Previous
Various
No
2016
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Fipronil
120068-37-3
Previous
Not specified
Yes
2001
9.2
ug/kg, dw
mean
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2001
6.6
ug/kg, dw
median
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2001
0.04
ug/kg, dw
min
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2001
44.3
ug/kg, dw
max
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2006-2007
31.4
ug/kg, dw
mean
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2006-2007
12.7
ug/kg, dw
median
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2006-2007
0.1
ug/kg, dw
min
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2006-2007
191.8
ug/kg, dw
max
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2015-2016
17.0
ug/kg, dw
mean
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2015-2016
10.2
ug/kg, dw
median
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2015-2016
0.3
ug/kg, dw
min
Sadaria et al. 2019
Fipronil
120068-37-3
Previous
Not specified
Yes
2015-2016
62.7
ug/kg, dw
max
Sadaria et al. 2019
Fluoride
16984-48-8
Previous
Not specified
No
June 2016-Sep 2017
1.51
mg/L
mean
Onchoke et al. 2018
Fluoride
16984-48-8
Previous
Not specified
No
June 2016-Sep 2017
1.53
mg/L
mean
Onchoke et al. 2018
Iron
7439-89-6
Previous
Naturally air-dried
No
Not specified
12,779.3
mg/kg, dw
individual
Lietal. 2019
Iron
7439-89-6
Previous
Treated by thickening,
anaerobic digestion,
dewatering, and
thermal heat-drying
No
Not specified
1,586.2
mg/kg, dw
individual
Lietal. 2019
Iron
7439-89-6
Previous
Class A
No
Not specified
360
mg/kg
individual
Sidhuetal. 2019b
Iron
7439-89-6
Previous
Class A
No
Not specified
19,440
mg/kg
individual
Vaughn et al. 2018
Iron
7439-89-6
Previous
Not specified
No
June 2016-Sep 2017
22,688
mg/kg, dw
mean
Onchoke et al. 2018
Iron
7439-89-6
Previous
Not specified
No
June 2016-Sep 2017
17,304
mg/kg, dw
mean
Onchoke et al. 2018
Magnesium
7439-95-4
Previous
Not specified
No
June 2016-Sep 2017
3370
mg/kg, dw
mean
Onchoke et al. 2018
Magnesium
7439-95-4
Previous
Not specified
No
June 2016-Sep 2017
3136
mg/kg, dw
mean
Onchoke et al. 2018
Magnesium
7439-95-4
Previous
Class A
No
Not specified
22,600
mg/kg
individual
Vaughn et al. 2018
Manganese
7439-96-5
Previous
Not specified
No
June 2016-Sep 2017
700.34
mg/kg, dw
mean
Onchoke et al. 2018
Manganese
7439-96-5
Previous
Not specified
No
June 2016-Sep 2017
1103.78
mg/kg, dw
mean
Onchoke et al. 2018
Manganese
7439-96-5
Previous
Class A
No
Not specified
553
mg/kg
mean
Vaughn et al. 2018
N
trate
14797-55-8
Previous
Class B
No
Not specified
3
g/kg
individual
Silveira et al. 2019
N
trate
14797-55-8
Previous
Class B
No
Not specified
3
g/kg
individual
Silveira et al. 2019
N
trate
14797-55-8
Previous
Class B
No
Not specified
3
g/kg
individual
Silveira et al. 2019
N
trate
14797-55-8
Previous
Class B
No
Not specified
3
g/kg
individual
Silveira et al. 2019
N
trate
14797-55-8
Previous
Class AA
No
Not specified
2
g/kg
individual
Silveira et al. 2019
N
trate
14797-55-8
Previous
Class B
No
Not specified
7
g/kg
individual
Silveira et al. 2019
N
trate
14797-55-8
Previous
Class B
No
Not specified
9
g/kg
individual
Silveira et al. 2019
N
trate
14797-55-8
Previous
Class A
No
Not specified
1540
mg/kg
individual
Vaughn et al. 2018
N
trate
14797-55-8
Previous
Not specified
No
June 2016-Sep 2017
1.31
mg/L
mean
Onchoke et al. 2018
N
trate
14797-55-8
Previous
Not specified
No
June 2016-Sep 2017
1.26
mg/L
mean
Onchoke et al. 2018
N
trite
14797-65-0
Previous
Not specified
No
June 2016-Sep 2017
0.32
mg/L
mean
Onchoke et al. 2018
N
trite
14797-65-0
Previous
Not specified
No
June 2016-Sep 2017
0.244
mg/L
mean
Onchoke et al. 2018
N
trogen
7727-37-9
Previous
Class B
No
Not specified
72
g/kg
individual
Silveira et al. 2019
C-ll
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
N
trogen
7727-37-9
Previous
Class B
No
Not specified
84
g/kg
individual
Silveira et al. 2019
N
trogen
7727-37-9
Previous
Class B
No
Not specified
61
g/kg
individual
Silveira et al. 2019
N
trogen
7727-37-9
Previous
Class B
No
Not specified
76
g/kg
individual
Silveira et al. 2019
N
trogen
7727-37-9
Previous
Class AA
No
Not specified
66
g/kg
individual
Silveira et al. 2019
N
trogen
7727-37-9
Previous
Class B
No
Not specified
48
g/kg
individual
Silveira et al. 2019
N
trogen
7727-37-9
Previous
Class B
No
Not specified
76
g/kg
individual
Silveira et al. 2019
Oxolinic acid
14698-29-4
Previous
Not specified
Yes
2006-2007
2.7
ng/g, dw
mean
Magee et al. 2018
Oxolinic acid
14698-29-4
Previous
Not specified
Yes
2006-2007
0.1
ng/g, dw
min
Magee et al. 2018
Oxolinic acid
14698-29-4
Previous
Not specified
Yes
2006-2007
5.2
ng/g, dw
max
Magee et al. 2018
Oxytetracycline
79-57-2
Previous
Not specified
Yes
2006-2007
4.5
ng/g, dw
mean
Magee et al. 2018
Oxytetracycline
79-57-2
Previous
Not specified
Yes
2006-2007
1
ng/g, dw
min
Magee et al. 2018
Oxytetracycline
79-57-2
Previous
Not specified
Yes
2006-2007
9.7
ng/g, dw
max
Magee et al. 2018
Phosphate
14265-44-2
Previous
Not specified
No
June 2016-Sep 2017
22.60
mg/L
mean
Onchoke et al. 2018
Phosphate
14265-44-2
Previous
Not specified
No
June 2016-Sep 2017
25.43
mg/L
mean
Onchoke et al. 2018
Phosphorus
7723-14-0
Previous
Not specified
No
June 2016-Sep 2017
17,804
mg/kg, dw
mean
Onchoke et al. 2018
Phosphorus
7723-14-0
Previous
Not specified
No
June 2016-Sep 2017
19,648
mg/kg, dw
mean
Onchoke et al. 2018
Phosphorus
7723-14-0
Previous
Class B
No
Not specified
23
g/kg
individual
Silveira et al. 2019
Phosphorus
7723-14-0
Previous
Class B
No
Not specified
28
g/kg
individual
Silveira et al. 2019
Phosphorus
7723-14-0
Previous
Class B
No
Not specified
18
g/kg
individual
Silveira et al. 2019
Phosphorus
7723-14-0
Previous
Class B
No
Not specified
34
g/kg
individual
Silveira et al. 2019
Phosphorus
7723-14-0
Previous
Class AA
No
Not specified
19
g/kg
individual
Silveira et al. 2019
Phosphorus
7723-14-0
Previous
Class B
No
Not specified
33
g/kg
individual
Silveira et al. 2019
Phosphorus
7723-14-0
Previous
Class B
No
Not specified
34
g/kg
individual
Silveira et al. 2019
Phosphorus
7723-14-0
Previous
Class A
No
Not specified
24,380
mg/kg
individual
Vaughn et al. 2018
Potassium
7440-09-7
Previous
Not specified
No
June 2016-Sep 2017
3514
mg/kg, dw
mean
Onchoke et al. 2018
Potassium
7440-09-7
Previous
Not specified
No
June 2016-Sep 2017
1385
mg/kg, dw
mean
Onchoke et al. 2018
Potassium
7440-09-7
Previous
Class A
No
Not specified
4200
mg/kg
individual
Sidhuetal. 2019b
Potassium
7440-09-7
Previous
Class A
No
Not specified
3886
mg/kg
individual
Vaughn et al. 2018
Silver
7440-22-4
Previous
Not specified
No
June 2016-Sep 2017
17.13
mg/kg, dw
mean
Onchoke et al. 2018
Silver
7440-22-4
Previous
Not specified
No
June 2016-Sep 2017
56.92
mg/kg, dw
mean
Onchoke et al. 2018
Silver
7440-22-4
Previous
Class A
No
Not specified
7.1
mg/kg
individual
Vaughn et al. 2018
Sodium
7440-23-5
Previous
Not specified
No
June 2016-Sep 2017
1510.8
mg/kg, dw
mean
Onchoke et al. 2018
Sodium
7440-23-5
Previous
Not specified
No
June 2016-Sep 2017
2303.7
mg/kg, dw
mean
Onchoke et al. 2018
Sodium
7440-23-5
Previous
Class A
No
Not specified
2452
mg/kg
individual
Vaughn et al. 2018
Triclocarban
101-20-2
Previous
Class B
No
2005-2007
18,800
ng/g, dw
mean
Lozano et al. 2018
Triclocarban
101-20-2
Previous
Class B
No
2005-2007
14,000
ng/g, dw
min
Lozano et al. 2018
Triclocarban
101-20-2
Previous
Class B
No
2005-2007
22,900
ng/g, dw
max
Lozano et al. 2018
Triphenyl phosphate
115-86-6
Previous
Not specified
Yes
2006-2007
30.4
ng/g, dw
mean
Wang et al. 2019
Triphenyl phosphate
115-86-6
Previous
Not specified
Yes
2006-2007
3.84
ng/g, dw
median
Wang et al. 2019
Triphenyl phosphate
115-86-6
Previous
Not specified
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Triphenyl phosphate
115-86-6
Previous
Not specified
Yes
2006-2007
1170
ng/g, dw
max
Wang et al. 2019
Tris(2-butoxyethyl) phosphate
78-51-3
Previous
Not specified
Yes
2006-2007
1760
ng/g, dw
mean
Wang et al. 2019
C-12
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table C-1. Concentrations of Newly and Previously Identified Chemicals in Biosolids for the 2018-2019 Biennial Review
Chemical
CAS number
New or
previous
Biosolid type
Did study use
archived
samples from
TNSSS?
Date(s) of sample
collection
Biosolids
concentration
Biosolids
units
Data type
(individual,
mean, median,
min, max)
Source
Tris(2-butoxyethyl) phosphate
78-51-3
Previous
Not specified
Yes
2006-2007
580
ng/g, dw
median
Wang et al. 2019
Tris(2-butoxyethyl) phosphate
78-51-3
Previous
Not specified
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Tris(2-butoxyethyl) phosphate
78-51-3
Previous
Not specified
Yes
2006-2007
28,300
ng/g, dw
max
Wang et al. 2019
Tris(2-chloroethyl) phosphate
115-96-8
Previous
Not specified
Yes
2006-2007
10.6
ng/g, dw
mean
Wang et al. 2019
Tris(2-chloroethyl) phosphate
115-96-8
Previous
Not specified
Yes
2006-2007
2.46
ng/g, dw
median
Wang et al. 2019
Tris(2-chloroethyl) phosphate
115-96-8
Previous
Not specified
Yes
2006-2007
n.d.
ng/g, dw
min
Wang et al. 2019
Tris(2-chloroethyl) phosphate
115-96-8
Previous
Not specified
Yes
2006-2007
317
ng/g, dw
max
Wang et al. 2019
Vanadium
7440-62-2
Previous
Not specified
No
June 2016-Sep 2017
24.06
mg/kg, dw
mean
Onchoke et al. 2018
Vanadium
7440-62-2
Previous
Not specified
No
June 2016-Sep 2017
13.05
mg/kg, dw
mean
Onchoke et al. 2018
Notes:
CAS = Chemical Abstracts Service
n.d. = No date
TNSSS = Targeted National Sewage Sludge Survey
3 = Total PCBs were analyzed using U.S. EPA method 8082A and is the sum of 129 PCB congeners.
C-13
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Biosolids Biennial Review Reporting Period 2018-2019
Appendix D. Human Health Toxicity Values for Chemicals Found in
Biosolids
D-l
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table D-1. Human Health Toxicity Values from EPA's Integrated Risk Information System (IRIS) for Chemicals Newly and Previously Identified in Biosolids
Chemical
CAS number
New or
previous
RfD
mg/kg/day
Date of last
update
RfC
mg/m3
Date of last
update
CSF
mg/kg/day
Date of last
update
IUR
Mg/m3
Date of last
update
Polychlorinated biphenyl (PCB)a
1336-36-3
New
2.0
10/1/1996
0.0001
10/1/1996
Polychlorinated biphenyl (PCB)b
1336-36-3
New
1.0
10/1/1996
Polychlorinated biphenyl (PCB)c
1336-36-3
New
0.4
10/1/1996
Polychlorinated biphenyl (PCB)d
1336-36-3
New
0.3
10/1/1996
Polychlorinated biphenyl (PCB)6
1336-36-3
New
0.07
10/1/1996
Polychlorinated biphenyl (PCB)f
1336-36-3
New
0.04
10/1/1996
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin9
57653-85-7
Previous
6.20E+03
3/31/1987
1.3
3/31/1987
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin9
19408-74-3
Previous
6.20E+03
3/31/1987
1.3
3/31/1987
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxing
19408-74-3
Previous
6.2E+03
3/31/1987
1.3
3/31/1987
1,4-Dichlorobenzene
106-46-7
Previous
8.00E-01
1/1/1994
2,2',3,3',4,4',5,5',6,6'-decabromodiphenyl ether
1163-19-5
Previous
0.007
6/30/2008
0.0007
6/30/2008
2,2',4,4',5,5'-Hexabromodiphenyl ether
68631-49-2
Previous
0.0002
6/30/2008
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
Previous
7.00E-10
2/17/2012
2,4,5-T richlorophenol
95-95-4
Previous
1.00E-01
1/31/1987
2,4-Dichlorophenol
120-83-2
Previous
3.00E-03
1/31/1987
2,4-Dichlorophenoxyacetic acid
94-75-7
Previous
1.00E-02
3/31/1987
2-Chloronaphthalene
91-58-7
Previous
8.00E-02
11/1/1990
2-Methylnaphthalene
91-57-6
Previous
4.00E-03
12/22/2003
4-Chloroaniline
106-47-8
Previous
4.00E-03
8/22/1988
Acetone
67-64-1
Previous
0.9
7/31/2003
Acetophenone
98-86-2
Previous
1.00E-01
8/22/1988
Anthracene
120-12-7
Previous
3.00E-01
9/1/1990
Antimony
7440-36-0
Previous
4.00E-04
1/31/1987
Arsenic
7440-38-2
Previous
3.00E-04
9/1/1991
1.5
6/1/1995
4.30E-03
6/1/1995
Barium
7440-39-3
Previous
0.2
7/11/2005
Benzo(a)pyrene
50-32-8
Previous
3.00E-04
1/19/2017
2.00E-06
1/19/2017
1
1/19/2017
Benzoic acid
65-85-0
Previous
4
9/7/1988
Bisphenol A
80-05-7
Previous
5.00E-02
9/26/1988
Boron
7440-42-8
Previous
2.00E-01
8/5/2004
Cadmium11
7440-43-9
Previous
5.00E-04
10/1/1989
1.80E-03
3/31/1987
Cadmium1
7440-43-9
Previous
1.00E-03
10/1/1989
Carbon tetrachloride
56-23-5
Previous
0.004
3/31/2010
0.1
3/31/2010
7.00E-02
3/31/2010
6E10-6
3/31/2010
Chloroform
67-66-3
Previous
0.01
10/19/2001
2.30E-05
10/19/2001
Cyanide
57-12-5
Previous
6.30E-04
9/28/2010
0.00083
9/28/2010
9/28/2010
Di(2-ethylhexyl) phthalate
117-81-7
Previous
2.00E-02
1/31/1987
1.40E-02
9/7/1988
Dibutyl phthalate
84-74-2
Previous
1.00E-01
1/31/1987
Dichloromethane
75-09-2
Previous
6.00E-03
11/18/2011
0.6
11/18/2011
2.00E-03
11/18/2011
1 x 10-8
11/18/2011
Ethylbenzene
100-41-4
Previous
1.00E-01
1/31/1987
1.00E+00
3/1/1991
Fluoranthene
206-44-0
Previous
4.00E-02
9/1/1990
Heptachlor epoxide B
1024-57-3
Previous
1.30E-05
9/30/1987
9.10E+00
9/30/1987
2.60E-03
9/30/1987
D-2
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table D-1. Human Health Toxicity Values from EPA's Integrated Risk Information System (IRIS) for Chemicals Newly and Previously Identified in Biosolids
New or
RfD
Date of last
RfC
Date of last
CSF
Date of last
IUR
Date of last
Chemical
CAS number
previous
mg/kg/day
update
mg/m3
update
mg/kg/day
update
Mg/m3
update
Hexabromobenzene
87-82-1
Previous
2.00E-03
3/31/1987
Manganese
7439-96-5
Previous
1.40E-01
11/1/1995
5.00E-05
12/1/1993
Mercury
7439-97-6
Previous
3.00E-04
6/1/1995
Molybdenum
7439-98-7
Previous
5.00E-03
11/1/1992
Naphthalene
91-20-3
Previous
2.00E-02
9/17/1998
3.00E-03
9/17/1998
Nickel
7440-02-0
Previous
2.00E-02
12/1/1991
Nitrate
14797-55-8
Previous
1.6
5/1/1991
Nitrite
14797-65-0
Previous
0.1
1/31/1987
N-N itrosodibutylamine
924-16-3
Previous
5.40E+00
1/31/1987
1.60E-03
1/31/1987
N-N itrosodiethylamine
55-18-5
Previous
1.50E+02
1/31/1987
4.30E-02
1/31/1987
N-Nitrosodimethylamine
62-75-9
Previous
5.10E+01
1/31/1987
1.40E-02
N-Nitrosodiphenylamine
86-30-6
Previous
4.90E-03
N-N itrosopyrrolidine
930-55-2
Previous
2.10E+00
1/31/1987
6.10E-04
Pentabromodiphenyl ether
32534-81-9
Previous
2.00E-03
3/31/1987
Pentachloronitrobenzene
82-68-8
Previous
3.00E-03
9/30/1987
Phenol
108-95-2
Previous
3.00E-01
9/30/2002
Phosphorus
7723-14-0
Previous
2.00E-05
8/1/1990
Pyrene
129-00-0
Previous
3.00E-02
9/1/1990
Selenium
7782-49-2
Previous
5.00E-03
6/1/1991
Silver
7440-22-4
Previous
5.00E-03
12/1/1991
Styrene
100-42-5
Previous
2.00E-01
1/31/1987
1
11/1/1992
Tetrachloroethylene
127-18-4
Previous
0.006
2/10/2012
0.04
2/10/2012
2.10E-03
2/10/2012
3.00E-07
2/10/2012
Toluene
108-88-3
Previous
0.08
9/23/2005
5
9/23/2005
Warfarin
81-81-2
Previous
3.00E-04
3/31/1987
Zinc
7440-66-6
Previous
0.3
8/3/2005
Notes:
CAS = Chemical Abstracts Service
a = High risk and persistence, upper bound
b = High risk and persistence, central estimate
c = Low risk and persistence, upper bound
d = Low risk and persistence, central estimate
0 = Lowest risk and persistence, upper bound
'= Lowest risk and persistence, central estimate
9 = Values are for a mixture of 1,2,3,6,7,8-HxCDD and 1,2,3,7,8,9-HxCDD (CASRN 57653-85-7 and 19408-74-3)
h = RfD is for significant proteinuria
1 = RfD is for human studies involving chronic exposures
D-3
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Biosolids Biennial Review Reporting Period 2018-2019
Table D-2. Human Health Toxicity Values from EPA's Human Health Benchmarks for Pesticides (HHBP) for Chemicals Newly and Previously Identified in
Biosolids
New or
Chemical
CAS number
previous
PAD or RfD
Units
Date
Notes
Oxytetracycline
79-57-2
Previous
0.0005
mg/kg/day
6/1/2006
Thiabendazole
148-79-8
Previous
0.025
mg/kg/day
8/22/2007
Acute or one day PAD
Thiabendazole
148-79-8
Previous
0.0002
mg/kg/day
8/22/2007
Chronic or lifetime HHBP (general population)
Thiabendazole
148-79-8
Previous
170
ppb
8/22/2007
Acute or one day HHBP (children)
Thiabendazole
148-79-8
Previous
1
ppb
8/22/2007
Chronic or lifetime HHBP (general population)
Thiabendazole
148-79-8
Previous
0.05
mg/kg/day
2015
Acute (children)
Thiabendazole
148-79-8
Previous
0.033
mg/kg/day
2015
Chronic (general population)
Thiabendazole
148-79-8
Previous
300
ppb
2015
Accute HHBP (children)
Thiabendazole
148-79-8
Previous
210
ppb
2015
Chronic HHBP (general population)
Triclosan
3380-34-5
Previous
0.3
mg/kg/day
1998
Acute, children (drinking water HHBP is 2000 ppb)
Triclosan
3380-34-5
Previous
0.3
mg/kg/day
1998
Chronic, general population (drinking water HHBP is 2000 ppb)
Notes:
CAS = Chemical Abstracts Service
PAD = Population adjusted does
D-4
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table D-3. EPA's Provisional Peer Reviewed Toxicity Values (PPRTVs) for Chemicals Newly and Previously Identified in Biosolids
Chemical
CAS number
New or
previous
RfD
mg/kg/day
RfC
mg/m3
CSF
mg/kg/day
Date of last
revision
Notes
Trimethyl phosphate (TMP)
512-56-1
New
0.01
0.017
9/30/2010
Subchronic and chronic provisional RfD and provisional
oral slope factor
Tributyl phosphate
126-73-8
New
0.0325
_
0.009
11/8/2010
Subchronic provisional RfD and provisional oral slope
factor
Tributyl phosphate
126-73-8
New
0.011
11/8/2010
Chronic provisional RfD
Tris(2-chloroisopropyl) phosphate
13674-84-5
New
1.00E-02
11/29/2012
Screening Chronic RfD
Tris(2-chloroisopropyl) phosphate
13674-84-5
New
1.00E-01
11/29/2012
Screening Subchronic RfD
2,4,5-Trichlorophenol
95-95-4
Previous
3.00E-01
7/27/2007
Subchronic provisional RfD
2,4-Dichlorophenol
120-83-2
Previous
2.00E-02
7/30/2007
Subchronic provisional RfD
2-Chloronaphthalene
91-58-7
Previous
0.2
9/3/2009
Subchronic provisional RfD
2-Methylnaphthalene
91-57-6
Previous
4.00E-03
9/18/2007
Subchronic provisional RfD
4-Chloroaniline
106-47-8
Previous
5.00E-04
0.2
9/30/2008
Subchronic provisional RfD
Acetophenone
98-86-2
Previous
8.00E-01
6/15/2011
Screening level subchronic RfD
Aluminum
7429-90-5
Previous
1
5.00E-03
8/25/2008
Chronic
Anthracene
120-12-7
Previous
1
6/15/2009
Subchronic provisional RfD
Antimony
7440-36-0
Previous
4.00E-04
7/30/2008
Subschronic RfD
Benz(a)anthracene
56-55-3
Previous
0.7
6/19/2007
Screening value
Benzoic acid
65-85-0
Previous
4
0.002
3/29/2005
Provisional subchronic RfD was derived by adopting
chronic provisional RfD from IRIS; provisional subchronic
RfC
Butylated hydroxytoluene
128-37-0
Previous
3.00E-01
3.60E-03
6/5/2013
Chronic
Butylated hydroxytoluene
128-37-0
Previous
1
3.60E-03
6/5/2013
Subchronic
Butylated hydroxytoluene
128-37-0
Previous
1.00E+00
6/5/2013
Subchronic provisional RfD
Butylated hydroxytoluene
128-37-0
Previous
3.00E-01
3.60E-03
6/5/2013
Chronic provisional RfD and provisional oral slope factor
Butylated hydroxytoluene
128-37-0
Previous
3.00E-01
3.60E-03
6/5/2013
Chronic provisional RfD
Butylated hydroxytoluene
128-37-0
Previous
1
6/5/2013
Subchronic provisional RfD
Cobalt
7440-48-4
Previous
3.00E-04
6.00E-06
8/25/2008
Chronic
Di-n-octyl phthalate
117-84-0
Previous
1.00E-01
12/20/2012
Subchronic provisional RfD
Di-n-octyl phthalate
117-84-0
Previous
1.00E-02
12/20/2012
Chronic provisional RfD
Fluoranthene
206-44-0
Previous
1.00E-01
12/27/2012
Subchronic provisional RfD
Iron
7439-89-6
Previous
0.7
9/11/2006
Subchronic and chronic provisional RfD
Nitrofen
1836-75-5
Previous
3.00E-03
3.80E-02
11/5/2012
Provisional subchronic RfD and oral slope factor
Nitrofen
1836-75-5
Previous
3.00E-03
11/5/2012
Provisional chronic RfD
N-Nitrosodimethylamine
62-75-9
Previous
0.000008
0.12
6/19/2007
Subchronic and chronic provisional RfD and screening
value
p-Cresol
106-44-5
Previous
0.02
9/29/2010
Subchronic provisional RfD
D-5
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Biosolids Biennial Review Reporting Period 2018-2019
Table D-3. EPA's Provisional Peer Reviewed Toxicity Values (PPRTVs) for Chemicals Newly and Previously Identified in Biosolids
New or
RfD
RfC
CSF
Date of last
Chemical
CAS number
previous
mg/kg/day
mg/m3
mg/kg/day
revision
Notes
Perfluorobutanesulfonic acid (PFBS)
375-73-5
Previous
2.00E-01
7/17/2014
Chronic provisional RfD
Perfluorobutanesulfonic acid (PFBS)
375-73-5
Previous
2.00E-02
7/17/2014
Subchronic provisional RfD
Rubidium
7440-17-7
Previous
4.00E-03
9/2/2016
Screening value provisional RfD
Screening value for soluble thallium subchronic provisional
Thallium
7440-28-0
Previous
4.00E-05
11/1/2012
RfD
Screening value for soluble thallium chronic provisional
Thallium
7440-28-0
Previous
1.00E-05
11/1/2012
RfD
Subchronic provisional RfD and provisional oral slope
Tris(2-chloroethyl) phosphate
115-96-8
Previous
2.00E-01
0.02
9/30/2009
factor
Tris(2-chloroethyl) phosphate
115-96-8
Previous
0.007
9/30/2009
Chronic provisional RfD
Tris(2-ethylhexyl) phosphate (TEHP)
78-42-2
Previous
1.00E-01
3.20E-03
9/10/2002
Provisional values with low confidence in the RfD
Vanadium
7440-62-2
Previous
0.0007
9/30/2009
Subchronic provisional RfD
Vanadium
7440-62-2
Previous
0.00007
9/30/2009
Chronic provisional RfD
Notes:
CAS = Chemical Abstracts Service
D-6
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table D-4. Human Health Toxicity Values from EPA's Health Effects Support Documents (HESDs) for Chemicals
Newly and Previously Identified in Biosolids
Chemical
CAS number
New or
previous
RfD
mg/kg/day
RfC
mg/m3
CSF
mg/kg/day
Date of last
revision
Boron
7440-42-8
Previous
0.2
1/1/2008
Manganese
7439-96-5
Previous
0.14
5.00E-05
2/1/2003
Naphthalene
91-20-3
Previous
0.02
3.00E-03
2/1/2003
Perfluorooctanesulfonic acid (PFOS)
1763-23-1
Previous
0.00002
5/1/2016
Perfluorooctanoic acid (PFOA)
335-67-1
Previous
0.00002
0.07
5/1/2016
Notes:
CAS = Chemical Abstracts Service
D-7
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Biosolids Biennial Review Reporting Period 2018-2019
Table D-5. Human Health Toxicity Values from the Agency for Toxic Substances and Disease Registry (ATSDR) for Chemicals Newly and Previously Identified in Biosolids
Inhalation
New or
Oral MRL
Oral MRL
Oral MRL
Inhalation
Inhalation MRL
MRL
Date of last
Chemical
CAS number
previous
(acute)
Units
(intermediate)
Units
(chronic)
Units
MRL (acute)
Units
(intermediate)
Units
(chronic)
Units
revision
Polychlorinated biphenyl (PCB)
1336-36-3
New
0.03
pg/kg-d
0.02
pg/kg/day
11/1/2000
1,3-Dichlorobenzene
541-73-1
Previous
0.4
mg/kg/day
0.02
mg/kg/day
8/1/2006
1,4-Dichlorobenzene
106-46-7
Previous
0.07
mg/kg/day
0.07
mg/kg/day
2
ppm
0.2
ppm
0.001
ppm
8/1/2006
2,2l,3,3',4,4l,5,5l,6,6l-Decabromodiphenyl ether
1163-19-5
Previous
0.01
mg/kg/day
0.0002
mg/kg/day
3/1/2017
2,2',4,4',5-Pentabromodiphenyl ether
60348-60-9
Previous
0.00006
mg/kg/day
0.000003
mg/kg/day
0.006
mg/m3
3/1/2017
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
Previous
0.001
pg/kg-d
0.00003
pg/kg-d
5/1/1994
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
Previous
0.0002
pg/kg-d
0.00002
pg/kg-d
0.000001
pg/kg-d
12/1/1998
2,4-Dichlorophenol
120-83-2
Previous
0.003
mg/kg/day
7/1/1999
Acetone
67-64-1
Previous
2
mg/kg/day
26
ppm
13
ppm
13
ppm
5/1/1994
Aluminum
7429-90-5
Previous
1
mg/kg/day
1
mg/kg/day
9/1/2008
Anthracene
120-12-7
Previous
10
mg/kg/day
8/1/1995
Antimony
7440-36-0
Previous
1
mg/kg/day
0.0006
mg/kg/day
0.001
mg/m3
0.001
mg/m3
0.0003
mg/m3
10/1/2019
Arsenic
7440-38-2
Previous
0.005
mg/kg/day
0.0003
mg/kg/day
8/1/2007
Barium
7440-39-3
Previous
0.2
mg/kg/day
0.2
mg/kg/day
8/1/2007
Beryllium
7440-41-7
Previous
0.002
mg/kg/day
9/1/2002
Boron
7440-42-8
Previous
0.2
mg/kg/day
0.2
mg/kg/day
0.3
mg/m3
11/1/2010
Cadmium
7440-43-9
Previous
0.0005
mg/kg/day
0.0001
mg/kg/day
0.00003
mg/m3
0.00001
mg/m3
9/1/2012
Carbon tetrachloride
56-23-5
Previous
0.02
mg/kg/day
0.007
mg/kg/day
0.03
ppm
0.03
ppm
8/1/2005
Chloroform
67-66-3
Previous
0.3
mg/kg/day
0.1
mg/kg/day
0.01
mg/kg/day
0.1
ppm
0.05
ppm
0.02
ppm
9/1/1997
Cobalt
7440-48-4
Previous
0.01
mg/kg/day
0.0001
mg/m3
4/1/2004
Copper
7440-50-8
Previous
0.01
mg/kg/day
0.01
mg/kg/day
9/1/2004
DEET
134-62-3
Previous
1
mg/kg/day
8/1/2017
Di(2-ethylhexyl) phthalate
117-81-7
Previous
3
pg/kg-d
0.1
pg/kg-d
0.2
PPb
12/1/2019
Di-n-octyl phthalate
117-84-0
Previous
3
mg/kg/day
0.4
mg/kg/day
9/1/1997
Ethyl benzene
100-41-4
Previous
0.4
mg/kg/day
5
ppm
2
ppm
0.06
ppm
11/1/2010
Manganese
7439-96-5
Previous
0.3
Mg/m3
Mercury
7439-97-6
Previous
0.0002
mg/m3
Molybdenum
7439-98-7
Previous
0.05
mg/kg/day
0.008
mg/kg/day
0.0004
mg/m3
4/1/2017
Naphthalene
91-20-3
Previous
0.6
mg/kg/day
0.6
mg/kg/day
0.0007
ppm
8/1/2005
Nickel
7440-02-0
Previous
0.0002
mg/m3
0.00009
mg/m3
Nitrate
14797-55-8
Previous
4
mg/kg/day
4
mg/kg/day
4
mg/kg/day
7/1/2017
Nitrite
14797-65-0
Previous
0.1
mg/kg/day
0.1
mg/kg/day
0.1
mg/kg/day
7/1/2017
Perfluorohexanesulfonic acid (PFHxS)
355-46-4
Previous
0.00002
mg/kg/day
6/1/2018
Perfluorooctanesulfonic acid (PFOS)
1763-23-1
Previous
0.000002
mg/kg/day
6/1/2018
Perfluorooctanoic acid (PFOA)
335-67-1
Previous
0.000003
mg/kg/day
6/1/2018
Phenol
108-95-2
Previous
1
mg/kg/day
9/1/2008
Phosphorus
7723-14-0
Previous
0.0002
mg/kg/day
0.02
mg/m3
9/1/1997
Selenium
7782-49-2
Previous
0.005
mg/kg/day
9/1/2003
Styrene
100-42-5
Previous
0.1
mg/kg/day
5
ppm
0.2
ppm
11/1/2010
Tin
7440-31-5
Previous
0.3
mg/kg/day
8/1/2005
Toluene
108-88-3
Previous
0.8
mg/kg/day
0.2
mg/kg/day
2
ppm
1
ppm
6/1/2017
Tris(2-butoxyethyl) phosphate
78-51-3
Previous
4.8
mg/kg/day
0.09
mg/kg/day
9/1/2012
Tris(2-chloroethyl) phosphate
115-96-8
Previous
0.6
mg/kg/day
0.2
mg/kg/day
9/1/2012
Vanadium
7440-62-2
Previous
0.01
mg/kg/day
0.0008
mg/m3
0.0001
mg/m3
9/1/2012
Zinc
7440-66-6
Previous
-
-
0.3
mg/kg/day
0.3
mg/kg/day
-
-
-
-
-
-
8/1/2005
Notes:
CAS = Chemical Abstracts Service
D-8
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table D-6. Human Health Toxicity Values from the California Environmental Protection Agency (CalEPA) for Chemicals Newly and Previously Identified in Biosolids
Chemical
PCB
congener#
CAS number
New or
previous
Inhalation
REL (acute)
|jg/m3
Date
reviewed
Inhalation
REL
(8-hour)
|jg/m3
Inhalation REL
(chronic)
|jg/m3
Date
reviewed
Oral REL
(chronic)
Units
Date
reviewed
Unit risk
(|ig/m3)"1
Inhalation slope
factor
mg/kg/day
Date
reviewed
[added]
Oral slope
factor
mg/kg/day
Date reviewed
[added]
Polychlorinated biphenyl (PCB)a
NA
1336-36-3
New
0.00057
2.00E+00
Apr-99
2.00E+00
Oct-OO
Polychlorinated biphenyl (PCB)b
NA
1336-36-3
New
0.00011
4.00E-01
Apr-99
4.00E-01
Oct-OO
Polychlorinated biphenyl (PCB)b
NA
1336-36-3
New
0.00002
7.00E-02
Apr-99
7.00E-02
Oct-OO
1,2,3,4,6,7,8-Heptachlorodibenzodioxin
NA
35822-46-9
Previous
0.004
Feb-00
1.00E-06
mg/kg/day
Oct-OO
3.80E-01
1.30E+03
Apr-99
1.30E+03
Oct-OO
1,2,3,4,7,8,9-Heptachlorodibenzofuran
NA
55673-89-7
Previous
-
-
-
0.004
Feb-00
1.00E-06
mg/kg/day
Oct-OO
3.80E-01
1.30E+03
Apr-99
1.30E+03
Oct-OO
1,2,3,4,7,8-Hexachlorodibenzodioxin
NA
39227-28-6
Previous
0.0004
Feb-00
1.00E-07
mg/kg/day
Oct-OO
3.80E-KX)
1.30E+04
Apr-99
1.30E+04
Oct-OO
1,2,3,6,7,8-Hexachlorodibenzofuran
NA
57117-44-9
Previous
-
-
-
0.0004
Feb-00
1.00E-07
mg/kg/day
Oct-OO
3.80E-KX)
1.30E+04
Apr-99
1.30E+04
Oct-OO
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
NA
57653-85-7
Previous
0.0004
Feb-00
1.00E-07
mg/kg/day
Oct-OO
3.80E-KX)
1.30E+04
Apr-99
1.30E+04
Oct-OO
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
NA
19408-74-3
Previous
-
-
-
0.0004
Feb-00
1.00E-07
mg/kg/day
Oct-OO
3.80E-KX)
1.30E+04
Apr-99
1.30E+04
Oct-OO
1,2,3,7,8-Pentachlorodibenzofuran
NA
57117-41-6
Previous
0.0013
Jan-11
3.30E-07
mg/kg/day
Jan-11
1.10E+00
3.90E-HD3
Jan-11
3.90E-HD3
Jan-11
1,4-Dichlorobenzene
NA
106-46-7
Previous
8.00E-HD2
Jan-01
1.10E-05
4.00E-02
4/1999
[1/1991]
1,4-Dichlorobenzene
NA
106-46-7
Previous
8.00E+02
Jan-01
1.10E-05
4.00E-02
Apr-99
2,3,3',4,4',5,5'-Heptachlorobiphenyl
189
39635-31-9
Previous
-
-
-
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.10E+03
3.90E-KX)
Jan-11
3.90E-HD0
Jan-11
2,3,3',4,4',5'-Hexachlorobiphenyl
157
69782-90-7
Previous
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.30E-03
3.90E-KX)
Jan-11
3.90E-KX)
Jan-11
2,3,3',4,4',5-Hexachlorobiphenyl
156
38380-08-4
Previous
-
-
-
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.10E-03
3.90E-KX)
Jan-11
3.90E-HD0
Jan-11
2,3,3',4,4'-Pentachlorobiphenyl
105
32598-14-4
Previous
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.10E-03
3.90E-KX)
Jan-11
3.90E-HD0
Jan-11
2,3',4,4',5,5'-Hexachlorobiphenyl
167
52663-72-6
Previous
-
-
-
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.10E-03
3.90E-KX)
Jan-11
3.90E-HD0
Jan-11
2,3,4,4',5-Pentachlorobiphenyl
114
74472-37-0
Previous
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.10E-03
3.90E-KX)
Jan-11
3.90E-HD0
Jan-11
2,3',4,4',5-Pentachlorobiphenyl
118
31508-00-6
Previous
-
-
-
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.10E-03
3.90E-KX)
Jan-11
3.90E-KX)
Jan-11
2',3,4,4',5-Pentachlorobiphenyl
123
65510-44-3
Previous
1.3
Jan-11
0.00033
mg/kg/day
Jan-11
1.10E-03
3.90E-KX)
Jan-11
3.90E-HD0
Jan-11
2,3,4,6,7,8-Hexachlorodibenzo[b,d]furan
NA
60851-34-5
Previous
-
-
-
0.0004
Feb-00
1.00E-07
mg/kg/day
Oct-OO
3.8
1.30E+04
Oct-OO
1.30E+04
Oct-OO
2,3,4,7,8-Pentachlorodibenzofuran
NA
57117-31-4
Previous
0.00013
Jan-11
3.30E-08
mg/kg/day
Jan-11
1.10E+01
3.90E-KM
Jan-11
3.90E-KM
Jan-11
2,3,7,8-Tetrachlorodibenzofuran
NA
51207-31-9
Previous
-
-
-
0.0004
Feb-00
1.00E-07
mg/kg/day
Oct-OO
3.80E-KX)
1.30E+04
Apr-99
1.30E+04
Oct-OO
2,3,7,8-Tetrachlorodibenzo-p-dioxin
NA
1746-01-6
Previous
0.00004
Feb-00
1.00E-05
ng/kg-d
Oct-OO
3.80E+01
1.30E+05
Aug-86
1.30E+05
Aug-86
2,3,7,8-Tetrachlorodibenzo-p-dioxin
NA
1746-01-6
Previous
-
-
-
0.00004
Feb-00
1.00E-08
mg/kg/day
Oct-OO
3.80E+01
1.30E+05
Apr-99
1.30E+05
Oct-OO
3,3',4,4',5,5'-Hexachlorobiphenyl
169
32774-16-6
Previous
0.013
Jan-11
0.00000033
mg/kg/day
Jan-11
1.10E+00
3.90E-HD3
Jan-11
3.90E-HD3
Jan-11
3,3',4,4',5-Pentachlorobiphenyl
126
57465-28-8
Previous
-
-
-
0.0004
Aug-03
0.0000001
mg/kg/day
Aug-03
3.80E-KX)
1.30E+04
Aug-03
1.30E+04
Aug-03
3,3',4,4'-Tetrachlorobiphenyl
77
32598-13-3
Previous
0.4
Aug-03
0.0001
mg/kg/day
Aug-03
3.80E-03
1.30E+01
Aug-03
1.30E+01
Aug-03
3,4,4',5-Tetrachlorobiphenyl
81
70362-50-4
Previous
-
-
-
0.13
Jan-11
0.000033
mg/kg/day
Jan-11
1.10E-02
3.90E+01
Jan-11
3.90E+01
Jan-11
Arsenic
NA
7440-38-2
Previous
2.00E-01
Dec-08
0.015
0.015
Dec-08
0.0035
ug/kg-d
Dec-08
3.30E-03
1.20E+01
Jul-90
1.5
Oct-OO
Benz(a)anthracene
NA
56-55-3
Previous
1.10E-04
3.90E-01
4/1999
[4/1994]
1.20E+00
2011
Benzo(a)pyrene
NA
50-32-8
Previous
1.10E-03
3.90E-HD0
4/1999
[4/1994]
1.20E+01
10/2000
[4/1994]
Benzo(b)fluoranthene
NA
205-99-2
Previous
1.10E-04
3.90E-01
4/1999
[4/1994]
1.20E+00
10/2000
[4/1994]
Benzo(k)fluoranthene
NA
207-08-9
Previous
1.10E-04
3.90E-01
4/1999
[4/1994]
1.20E+00
10/2000
[4/1994]
Cadmium
NA
7440-43-9
Previous
-
-
-
0.02
Jan-01
0.5
ng/kg-d
Oct-OO
4.20E-03
1.5 E1
Jan-87
-
Carbon tetrachloride
NA
56-23-5
Previous
1.90E+03
Apr-99
40
Jan-01
4.20E-05
1.5 E-1
Sep-87
2011
Chloroform
NA
67-66-3
Previous
1.50E+02
Apr-99
-
300
Apr-00
-
-
5.30E-06
1.9 E-2
Dec-90
-
-
Chrysene
NA
218-01-9
Previous
1.10E-05
3.90E-02
1.20E-01
NS
Copper
NA
7440-50-8
Previous
1.00E-02
Apr-99
-
-
-
-
-
-
-
-
-
-
-
Cyanide
NA
57-12-5
Previous
3.40E+02
Apr-99
9
Apr-00
Di(2-ethylhexyl) phthalate
NA
117-81-7
Previous
2.40E-06
8.40E-03
4/1999
[1/1992]
8.40E-03
Oct-OO
Dichloromethane
NA
75-09-2
Previous
1.40E+04
Apr-99
4.00E-HD2
Feb-00
1.00E-06
3.50E-03
Jul-89
Ethylbenzene
NA
100-41-4
Previous
-
-
-
2.00E-HD3
Feb-00
-
-
-
2.50E-06
8.70E-03
Nov-07
-
-
D-9
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table D-6. Human Health Toxicity Values from the California Environmental Protection Agency (CalEPA) for Chemicals Newly and Previously Identified in Biosolids
Chemical
PCB
congener#
CAS number
New or
previous
Inhalation
REL (acute)
|jg/m3
Date
reviewed
Inhalation
REL
(8-hour)
|jg/m3
Inhalation REL
(chronic)
|jg/m3
Date
reviewed
Oral REL
(chronic)
Units
Date
reviewed
Unit risk
(|ig/m3)"1
Inhalation slope
factor
mg/kg/day
Date
reviewed
[added]
Oral slope
factor
mg/kg/day
Date reviewed
[added]
Lead
NA
7439-92-1
Previous
1.20E-05
4.20E-02
8.50E-03
NS
Manganese
NA
7439-96-5
Previous
-
-
0.17
0.09
Dec-08
-
-
-
-
-
-
-
-
Mercury
NA
7439-97-6
Previous
6.00E-01
Dec-08
0.06
0.03
Dec-08
0.16
ng/kg-d
Dec-08
m-Xylene
NA
108-38-3
Previous
2.20E-04
Apr-99
700
Apr-00
-
-
-
-
-
-
-
Naphthalene
NA
91-20-3
Previous
9
Apr-00
3.40E-05
1.20E-01
Aug-04
Nickel
NA
7440-02-0
Previous
2.00E-01
Mar-12
0.06
0.014
Mar-12
11
ng/kg-d
Mar-12
2.60E-04
9.10E-01
Aug-91
-
-
N-Nitrosodibutylamine
NA
924-16-3
Previous
3.10E-03
1.10E+01
4/1999
[1/1992]
N-Nitrosodiethylamine
NA
55-18-5
Previous
1.00E-02
3.60E+01
4/1999
[1/1991]
N-Nitrosodimethylamine
NA
62-75-9
Previous
4.60E-03
1.60E+01
Apr-99
N-Nitrosodiphenylamine
NA
86-30-6
Previous
-
-
-
-
-
-
-
2.60E-06
9.00E-03
Apr-99
-
-
N-Nitrosopyrrolidine
NA
930-55-2
Previous
6.00E-04
2.10E+00
4/1999
[7/90]
o-Xylene
NA
95-47-6
Previous
2.20E+04
Apr-99
-
700
Apr-00
-
-
-
-
-
-
-
p-Cresol
NA
106-44-5
Previous
6.00E-HD2
Jan-20
Phenol
NA
108-95-2
Previous
5.80E+03
Apr-99
-
200
Apr-00
-
-
-
-
-
-
-
-
p-Xylene
NA
106-42-3
Previous
22000
Apr-99
700
Apr-00
Selenium
NA
7782-49-2
Previous
-
-
-
20
Dec-01
5
ng/kg-d
Dec-01
-
-
-
-
-
Styrene
NA
100-42-5
Previous
2.10E+04
Apr-99
900
Apr-00
Tetrachloroethylene
NA
127-18-4
Previous
2.00 E+04
Apr-99
-
-
-
-
-
5.90E-06
2.10E-02
Oct-91
-
-
Toluene
NA
108-88-3
Previous
3.70E+04
Apr-99
-
300
Apr-00
-
-
-
-
-
-
-
Notes:
CAS = Chemical Abstracts Service
a = High risk
b = Low risk
c = Lowest risk
D-10
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table D-7. Human Health Toxicity Values from Health Canada's List of Priority Substances for Chemicals
Newly and Previously Identified in Biosolids
Chemical
CAS number
New or
previous
TDI
Units
Date
2,4-Dichlorophenol
120-83-2
Previous
0.1*
mg/kg/day
2/1/1987
Antimony
7440-36-0
Previous
0.0002
mg/kg/day
5/1/1997
Barium
7440-39-3
Previous
0.19
mg/kg/day
1/1/2020
Benzo(a)pyrene
50-32-8
Previous
0.0667
Ijg/kg/day
1/1/2016
Boron
7440-42-8
Previous
0.035*
mg/kg/day
5/1/1991
Carbon tetrachloride
56-23-5
Previous
0.71
Ijg/kg/day
11/1/2010
Copper
7440-50-8
Previous
426
Ijg/kg/day
6/1/2019
Dichloromethane
75-09-2
Previous
0.014
mg/kg/day
3/1/2011
Dimethoate
60-51-5
Previous
0.002*
mg/kg/day
2/1/1991
Ethylbenzene
100-41-4
Previous
0.022
mg/kg/day
8/1/2014
Fluoride
16984-48-8
Previous
0.105
mg/kg/day
12/1/2010
Manganese
7439-96-5
Previous
0.025
mg/kg/day
5/1/2019
Mercury
7439-97-6
Previous
0.03
mg/kg/day
9/1/1986
m-Xylene
108-38-3
Previous
0.013
mg/kg/day
8/1/2014
o-Xylene
95-47-6
Previous
0.013
mg/kg/day
8/1/2014
Perfluorooctanesulfonic acid (PFOS)
1763-23-1
Previous
0.0011
mg/kg/day
12/1/2018
Perfluorooctanoic acid (PFOA)
335-67-1
Previous
0.003
mg/kg/day
12/1/2018
p-Xylene
106-42-3
Previous
0.013
mg/kg/day
8/1/2014
Tetrachloroethylene
127-18-4
Previous
0.0068
mg/kg/day
1/1/2015
Toluene
108-88-3
Previous
0.0097
mg/kg/day
8/1/2014
Notes:
CAS = Chemical Abstracts Service
* Value is acceptable daily intake (ADI), not tolerable daily intake (TDI).
D-ll
-------
Biosolids Biennial Review
Appendix E. Ecological Toxicity Data
Reporting Period 2018-2019
E-l
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table E-1. Summary of Papers Found in ECOTOX for Chemicals Newly Identified in Biosolids in the 2018-2019
Reporting Period
Chemical
CAS number
# of terrestrial
species
# of papers
terrestrial
# of aquatic
species
# of papers aquatic
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
0
0
3
2
2,2',3,3',4,4'-Hexachlorobiphenyl
38380-07-3
0
0
5
6
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
1
1
1
1
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
1
1
2
2
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
1
1
7
7
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
0
0
1
1
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
3
3
43
50
2,2',4,4'-Tetrachlorobiphenyl
2437-79-8
1
1
20
14
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
0
0
19
16
2,2',4,5'-Tetrachlorobiphenyl
41464-40-8
0
0
4
4
2,2', 4,5-T etrac h I orob ip h eny I
70362-47-9
0
0
2
3
2,2',5,5'-Tetrachlorobiphenyl
35693-99-3
4
4
23
33
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-
chloroethyl) ester phosphoric acid
38051-10-4
0
0
1
1
2,2'-Dichlorobiphenyl
13029-08-8
1
2
12
14
2,3,3',4,4',5,6-Heptachlorobiphenyl
41411-64-7
0
0
1
2
2,3,4'-Trichlorobiphenyl
38444-85-8
0
0
2
2
2,3-Dichlorobiphenyl
16605-91-7
1
1
2
2
2,4',5-Trichlorobiphenyl
16606-02-3
1
1
20
16
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
1
1
1
1
2,4'-Dichlorobiphenyl
34883-43-7
0
0
4
3
2-Chlorobiphenyl
2051-60-7
0
0
9
6
2-Ethylhexyl diphenyl phosphate
1241-94-7
3
3
6
7
2H,2H,3H,3H-Perfluorooctanoic acid
914637-49-3
0
0
1
3
3,4,4'-Trichlorobiphenyl
38444-90-5
0
0
1
1
4-C h I orob ip h eny I
2051-62-9
0
0
15
10
6:2 Fluorotelomer phosphate diester
57677-95-9
0
0
1
2
6:2 Fluorotelomer sulfonic acid
27619-97-2
1
1
4
2
8:2 Fluorotelomer phosphate diester
678-41-1
2
1
1
2
Ammeline
645-92-1
1
1
1
1
Amoxicillin
26787-78-0
3
1
17
10
Ampicillin
69-53-4
5
5
10
6
Bis(2-ethylhexyl) phosphate
298-07-7
0
0
4
4
Cesium
7440-46-2
1
1
4
5
Cresyl diphenyl phosphate (CDPP)
26444-49-5
1
1
4
2
Cyanuric acid
108-80-5
4
13
2
11
Decachlorobiphenyl
2051-24-3
0
0
7
7
Dibutyl ester phosphoric acid
107-66-4
0
0
1
1
Diethyl hydrogen phosphate
598-02-7
0
0
2
2
Fipronil amide
205650-69-7
1
1
1
1
Fipronil sulfide
120067-83-6
1
1
11
5
Fipronil sulfone
120068-36-2
2
3
15
4
Fipronil desulfinyl
205650-65-3
0
0
3
3
Hexachlorobiphenyl
26601-64-9
1
1
3
3
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
1
1
4
3
Melamine
108-78-1
7
19
8
8
Monochlorobiphenyl
27323-18-8
0
0
2
1
Nalidixic acid
389-08-2
1
1
3
3
Octachlorobiphenyl
55722-26-4
0
0
1
1
E-2
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table E-1. Summary of Papers Found in ECOTOX for Chemicals Newly Identified in Biosolids in the 2018-2019
Reporting Period
# of terrestrial
# of papers
# of aquatic
Chemical
CAS number
species
terrestrial
species
# of papers aquatic
Pentachlorobiphenyl
25429-29-2
1
1
5
5
Polychlorinated biphenyl (PCB)
1336-36-3
5
7
38
39
Resorcinol bis(diphenyl phosphate) (RDP)
57583-54-7
0
0
1
1
Sulfur
7704-34-9
121
102
12
9
Tert-butylphenyl diphenyl phosphate
56803-37-3
1
1
5
3
Tetrachlorobiphenyl
26914-33-0
0
0
3
3
Tributyl phosphate
126-73-8
1
1
32
28
Triethyl phosphate (TEP)
78-40-0
3
1
13
7
Triisobutyl phosphate
126-71-6
1
1
3
1
Trimethyl phosphate (TMP)
512-56-1
2
2
4
4
Tripropyl phosphate
513-08-6
0
0
1
2
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
3
3
6
28
T ris(2-ch loroisopropyl) phosphate
13674-84-5
2
2
2
4
Tris(2-ethylhexyl) phosphate (TEHP)
78-42-2
1
1
1
1
Tris(methylphenyl) phosphate
1330-78-5
3
4
4
20
Notes:
CAS = Chemical Abstracts Service
E-3
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-2. Summary of Papers Found in ECOTOX for Chemicals Previously Identified in Biosolids
in the 2018-2019 Reporting Period
Chemical
CAS number
# of terrestrial
species
# of papers
terrestrial
# of aquatic
species
# of papers
aquatic
(+/-)-Verapamil
52-53-9
0
0
1
1
1-(p-Chlorobenzoyl)-5-methoxy-2-methyl-
lndole-3-acetic acid
53-86-1
0
0
1
1
17alpha-Ethinylestradiol
57-63-6
0
0
2
2
17beta-Estradiol
50-28-2
0
0
4
7
2,2',3,3',4,4',5,5',6,6'-decabromodiphenyl
ether
1163-19-5
1
1
0
0
2,2',4,4'-Tetrabromodiphenyl ether
5436-43-1
0
0
1
1
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
0
0
1
1
2,4-Dichlorophenoxyacetic acid
94-75-7
1
1
1
1
3,3',5,5'-Tetrabromobisphenol A
79-94-7
6
5
5
8
4-(1,1,3,3-Tetramethylbutyl)phenol
140-66-9
2
2
0
0
Acetaminophen
103-90-2
0
0
1
1
Acetic acid
64-19-7
0
0
1
1
Acetone
67-64-1
0
0
6
6
Acetophenone
98-86-2
0
0
1
1
Aspirin
50-78-2
0
0
1
1
Benz(a)anthracene
56-55-3
0
0
1
1
Benzo(a)pyrene
50-32-8
0
0
2
3
Benzo(b)fiuoranthene
205-99-2
0
0
1
1
Bisphenoi A
80-05-7
0
0
7
16
Butyiated hydroxytoluene
128-37-0
2
5
8
8
Butylparaben
94-26-8
0
0
1
1
Caffeine
58-08-2
0
0
1
1
Carbamazepine
298-46-4
0
0
1
1
Chloroform
67-66-3
0
0
1
1
Clorophene
120-32-1
0
0
1
1
Clotrimazole
23593-75-1
1
1
3
2
Cloxacillin
61-72-3
0
0
1
1
Cyclophosphamide
50-18-0
0
0
1
1
Di(2-ethylhexyl) phthalate
117-81-7
1
1
4
6
Dibutyl phthalate
84-74-2
4
4
9
12
Dichloromethane
75-09-2
0
0
1
1
Diclofenac
15307-86-5
0
0
1
1
Dimethoate
60-51-5
1
1
0
0
Dimethyl phthalate
131-11-3
0
0
2
2
Di-n-octyl phthalate
117-84-0
0
0
1
1
Ethylparaben
120-47-8
0
0
1
1
Fipronil
120068-37-3
0
0
1
1
Furosemide
54-31-9
0
0
1
1
Galaxolide
1222-05-5
3
3
14
4
Ibuprofen
15687-27-1
0
0
2
2
Methylparaben
99-76-3
0
0
1
1
E-4
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-2. Summary of Papers Found in ECOTOX for Chemicals Previously Identified in Biosolids
in the 2018-2019 Reporting Period
# of terrestrial
# of papers
# of aquatic
# of papers
Chemical
CAS number
species
terrestrial
species
aquatic
Naphthalene
91-20-3
0
0
1
1
N-Nitrosodiphenylamine
86-30-6
0
0
1
1
o-Xylene
95-47-6
0
0
1
1
Perfluorobutanesulfonate
45187-15-3
2
2
2
4
Perfluorobutanesulfonic acid (PFBS)
375-73-5
1
1
0
0
Perfluorobutanoic acid (PFBA)
375-22-4
1
1
2
2
Perfluorodecanoic acid (PFDA)
335-76-2
0
0
2
2
Perfluorododecanoic acid (PFDoDA)
307-55-1
0
0
2
3
Perfluoroheptanoic acid (PFHpA)
375-85-9
2
2
1
1
Perfluorohexanesulfonate
108427-53-8
1
1
3
3
Perfluorohexanesulfonic acid (PFHxS)
355-46-4
1
1
0
0
Perfluorohexanoic acid (PFHxA)
307-24-4
1
1
3
4
Perfluorononanoic acid (PFNA)
375-95-1
1
1
2
2
Perfluoroundecanoic acid (PFUdA)
2058-94-8
7
5
8
7
Perfluorooctanesulfonamide (PFOSA)
754-91-6
4
2
0
0
Perfluorooctanesulfonic acid (PFOS)
1763-23-1
0
0
5
7
Perfluorooctanoic acid (PFOA)
335-67-1
3
5
12
14
Perfluoropentanoic acid (PFPeA)
2706-90-3
1
1
0
0
Perfluorotridecanoic acid (PFTrDA)
72629-94-8
5
2
1
1
Phenol
108-95-2
1
1
0
0
Potassium perfluorooctanesulfonate
2795-39-3
6
5
8
12
Propylparaben
94-13-3
0
0
2
2
Pyrene
129-00-0
0
0
1
1
Tetrachloroethylene
127-18-4
0
0
1
1
Tonalide
21145-77-7
0
0
1
1
Triclosan
3380-34-5
0
0
2
3
Trimethoprim
738-70-5
0
0
1
1
Triphenyl phosphate
115-86-6
1
1
5
11
Tris(2-butoxyethyl) phosphate
78-51-3
0
0
4
4
Tris(2-chloroethyl) phosphate
115-96-8
1
1
4
4
Notes:
CAS = Chemical Abstracts Service
E-5
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Fish
96-hr
LC50
0.000218
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Daphnid
48-hr
LC50
0.000235
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Green Algae
96-hr
EC50
0.002
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Fish
ChV
4.53E-05
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Daphnid
ChV
0.000135
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Green Algae
ChV
0.003
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Fish(SW)
96-hr
LC50
0.000287
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Mysid
96-hr
LC50
1.97E-06
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Fish(SW)
ChV
0.002
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Mysid(SW)
ChV
2.20E-08
2,2',3,3',4,4',5,6'-Octachlorobiphenylb
196
42740-50-1
Neutral Organics
Earthworm
14-day
LC50
143.404
2,2',3,3' ,4,4', 5-Heptach lorobipheny 1
170
35065-30-6
Neutral Organics
Fish
96-hr
LC50
0.000762
2,2',3,3' ,4,4', 5-Heptach lorobipheny 1
170
35065-30-6
Neutral Organics
Daphnid
48-hr
LC50
0.000772
2,2',3,3',4,4',5-Heptachlorobiphenylb
170
35065-30-6
Neutral Organics
Green Algae
96-hr
EC50
0.006
2,2',3,3',4,4',5-Heptachlorobiphenyl
170
35065-30-6
Neutral Organics
Fish
ChV
0.000147
2,2',3,3',4,4',5-Heptachlorobiphenyl
170
35065-30-6
Neutral Organics
Daphnid
ChV
0.000377
2,2',3,3',4,4',5-Heptachlorobiphenylb
170
35065-30-6
Neutral Organics
Green Algae
ChV
0.006
2,2',3,3', 4,4', 5-Heptach lorobipheny 1
170
35065-30-6
Neutral Organics
Fish (SW)
96-hr
LC50
0.000996
2,2',3,3' ,4,4', 5-Heptach lorobipheny 1
170
35065-30-6
Neutral Organics
Mysid
96-hr
LC50
1.06E-05
2,2',3,3',4,4',5-Heptachlorobiphenylb
170
35065-30-6
Neutral Organics
Fish (SW)
ChV
0.005
2,2',3,3' ,4,4', 5-Heptach lorobipheny 1
170
35065-30-6
Neutral Organics
Mysid (SW)
ChV
1.43E-07
2,2',3,3',4,4',5-Heptachlorobiphenylb
170
35065-30-6
Neutral Organics
Earthworm
14-day
LC50
153.856
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Fish
96-hr
LC50
0.003
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Daphnid
48-hr
LC50
0.003
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Fish
ChV
0.000476
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Daphnid
ChV
0.00104
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Green Algae
ChV
0.013
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,2',3,3',4,4'-Hexachlorobiphenyl
128
38380-07-3
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Fish (SW)
ChV
0.012
2,2',3,3',4,4'-Hexachlorobiphenyl
128
38380-07-3
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,2',3,3',4,4'-Hexachlorobiphenylb
128
38380-07-3
Neutral Organics
Earthworm
14-day
LC50
163.817
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
201
40186-71-8
Neutral Organics
Fish
96-hr
LC50
0.000218
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
201
40186-71-8
Neutral Organics
Daphnid
48-hr
LC50
0.000235
2,2',3,3',4,5',6,6'-Octachlorobiphenylb
201
40186-71-8
Neutral Organics
Green Algae
96-hr
EC50
0.002
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
201
40186-71-8
Neutral Organics
Fish
ChV
4.53E-05
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
201
40186-71-8
Neutral Organics
Daphnid
ChV
0.000135
2,2',3,3',4,5',6,6'-Octachlorobiphenylb
201
40186-71-8
Neutral Organics
Green Algae
ChV
0.003
2,2',3,3',4,5',6,6'-Octachlorobiphenylb
201
40186-71-8
Neutral Organics
Fish (SW)
96-hr
LC50
0.000287
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
201
40186-71-8
Neutral Organics
Mysid
96-hr
LC50
1.97E-06
2,2',3,3',4,5',6,6'-Octachlorobiphenylb
201
40186-71-8
Neutral Organics
Fish (SW)
ChV
0.002
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
201
40186-71-8
Neutral Organics
Mysid (SW)
ChV
2.20E-08
2,2',3,3',4,5',6,6'-Octachlorobiphenylb
201
40186-71-8
Neutral Organics
Earthworm
14-day
LC50
143.404
2,2',3,3',4,5-Hexachlorobiphenylb
129
55215-18-4
Neutral Organics
Fish
96-hr
LC50
0.003
2,2',3,3',4,5-Hexachlorobiphenylb
129
55215-18-4
Neutral Organics
Daphnid
48-hr
LC50
0.003
2,2',3,3',4,5-Hexachlorobiphenylb
129
55215-18-4
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,2',3,3',4,5-Hexachlorobiphenyl
129
55215-18-4
Neutral Organics
Fish
ChV
0.000476
2,2',3,3',4,5-Hexachlorobiphenyl
129
55215-18-4
Neutral Organics
Daphnid
ChV
0.00104
2,2',3,3',4,5-Hexachlorobiphenylb
129
55215-18-4
Neutral Organics
Green Algae
ChV
0.013
2,2',3,3',4,5-Hexachlorobiphenylb
129
55215-18-4
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,2',3,3',4,5-Hexachlorobiphenyl
129
55215-18-4
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,2',3,3',4,5-Hexachlorobiphenylb
129
55215-18-4
Neutral Organics
Fish (SW)
ChV
0.012
2,2',3,3',4,5-Hexachlorobiphenyl
129
55215-18-4
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,2',3,3',4,5-Hexachlorobiphenylb
129
55215-18-4
Neutral Organics
Earthworm
14-day
LC50
163.817
2,2',3,3',4,6-Hexachlorobiphenylb
131
61798-70-7
Neutral Organics
Fish
96-hr
LC50
0.003
2,2',3,3',4,6-Hexachlorobiphenylb
131
61798-70-7
Neutral Organics
Daphnid
48-hr
LC50
0.003
E-6
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,2',3,3',4,6-Hexachlorobiphenylb
131
61798-70-7
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,2',3,3',4,6-Hexachlorobiphenyl
131
61798-70-7
Neutral Organics
Fish
ChV
0.000476
2,2',3,3',4,6-Hexachlorobiphenyl
131
61798-70-7
Neutral Organics
Daphnid
ChV
0.00104
2,2',3,3',4,6-Hexachlorobiphenylb
131
61798-70-7
Neutral Organics
Green Algae
ChV
0.013
2,2',3,3',4,6-Hexachlorobiphenylb
131
61798-70-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,2',3,3',4,6-Hexachlorobiphenyl
131
61798-70-7
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,2',3,3',4,6-Hexachlorobiphenylb
131
61798-70-7
Neutral Organics
Fish (SW)
ChV
0.012
2,2',3,3',4,6-Hexachlorobiphenyl
131
61798-70-7
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,2',3,3',4,6-Hexachlorobiphenylb
131
61798-70-7
Neutral Organics
Earthworm
14-day
LC50
163.817
2,2',3,3' ,5,5', 6-Heptach lorobipheny 1
178
52663-67-9
Neutral Organics
Fish
96-hr
LC50
0.000762
2,2',3,3' ,5,5', 6-Heptach lorobipheny 1
178
52663-67-9
Neutral Organics
Daphnid
48-hr
LC50
0.000772
2,2',3,3',5,5',6-Heptachlorobiphenylb
178
52663-67-9
Neutral Organics
Green Algae
96-hr
EC50
0.006
2,2',3,3',5,5',6-Heptachlorobiphenyl
178
52663-67-9
Neutral Organics
Fish
ChV
0.000147
2,2',3,3',5,5',6-Heptachlorobiphenyl
178
52663-67-9
Neutral Organics
Daphnid
ChV
0.000377
2,2',3,3',5,5',6-Heptachlorobiphenylb
178
52663-67-9
Neutral Organics
Green Algae
ChV
0.006
2,2',3,3',5,5',6-Heptachlorobiphenyl
178
52663-67-9
Neutral Organics
Fish (SW)
96-hr
LC50
0.000996
2,2',3,3' ,5,5', 6-Heptach lorobipheny 1
178
52663-67-9
Neutral Organics
Mysid
96-hr
LC50
1.06E-05
2,2',3,3',5,5',6-Heptachlorobiphenylb
178
52663-67-9
Neutral Organics
Fish (SW)
ChV
0.005
2,2',3,3' ,5,5', 6-Heptach lorobipheny 1
178
52663-67-9
Neutral Organics
Mysid (SW)
ChV
1.43E-07
2,2',3,3',5,5',6-Heptachlorobiphenylb
178
52663-67-9
Neutral Organics
Earthworm
14-day
LC50
153.856
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
Neutral Organics
Fish
96-hr
LC50
0.003
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
Neutral Organics
Daphnid
48-hr
LC50
0.003
2,2',3,3',6,6'-Hexachlorobiphenylb
136
38411-22-2
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
Neutral Organics
Fish
ChV
0.000476
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
Neutral Organics
Daphnid
ChV
0.00104
2,2',3,3',6,6'-Hexachlorobiphenylb
136
38411-22-2
Neutral Organics
Green Algae
ChV
0.013
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,2',3,3',6,6'-Hexachlorobiphenylb
136
38411-22-2
Neutral Organics
Fish (SW)
ChV
0.012
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,2',3,3',6,6'-Hexachlorobiphenylb
136
38411-22-2
Neutral Organics
Earthworm
14-day
LC50
163.817
2,2',3,4,4',5,5',6-Octachlorobiphenylb
203
52663-76-0
Neutral Organics
Fish
96-hr
LC50
0.000218
2,2',3,4,4',5,5',6-Octachlorobiphenylb
203
52663-76-0
Neutral Organics
Daphnid
48-hr
LC50
0.000235
2,2',3,4,4',5,5',6-Octachlorobiphenylb
203
52663-76-0
Neutral Organics
Green Algae
96-hr
EC50
0.002
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
Neutral Organics
Fish
ChV
4.53E-05
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
Neutral Organics
Daphnid
ChV
0.000135
2,2',3,4,4',5,5',6-Octachlorobiphenylb
203
52663-76-0
Neutral Organics
Green Algae
ChV
0.003
2,2',3,4,4',5,5',6-Octachlorobiphenylb
203
52663-76-0
Neutral Organics
Fish (SW)
96-hr
LC50
0.000287
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
Neutral Organics
Mysid
96-hr
LC50
1.97E-06
2,2',3,4,4',5,5',6-Octachlorobiphenylb
203
52663-76-0
Neutral Organics
Fish (SW)
ChV
0.002
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
Neutral Organics
Mysid (SW)
ChV
2.20E-08
2,2',3,4,4',5,5',6-Octachlorobiphenylb
203
52663-76-0
Neutral Organics
Earthworm
14-day
LC50
143.404
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
Neutral Organics
Fish
96-hr
LC50
0.000762
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
Neutral Organics
Daphnid
48-hr
LC50
0.000772
2,2',3,4,4',5,5'-Heptachlorobiphenylb
180
35065-29-3
Neutral Organics
Green Algae
96-hr
EC50
0.006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
Neutral Organics
Fish
ChV
0.000147
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
Neutral Organics
Daphnid
ChV
0.000377
2,2',3,4,4',5,5'-Heptachlorobiphenylb
180
35065-29-3
Neutral Organics
Green Algae
ChV
0.006
2,2',3,4,4',5,5'-Heptachlorobiphenylb
180
35065-29-3
Neutral Organics
Fish (SW)
96-hr
LC50
0.000996
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
Neutral Organics
Mysid
96-hr
LC50
1.06E-05
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
Neutral Organics
Fish (SW)
ChV
0.005
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
Neutral Organics
Mysid (SW)
ChV
1.43E-07
2,2',3,4,4',5,5'-Heptachlorobiphenylb
180
35065-29-3
Neutral Organics
Earthworm
14-day
LC50
153.856
2,2',3,4,4',5'-Hexachlorobiphenylb
138
35065-28-2
Neutral Organics
Fish
96-hr
LC50
0.003
2,2',3,4,4',5'-Hexachlorobiphenylb
138
35065-28-2
Neutral Organics
Daphnid
48-hr
LC50
0.003
2,2',3,4,4',5'-Hexachlorobiphenylb
138
35065-28-2
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,2',3,4,4',5'-Hexachlorobiphenyl
138
35065-28-2
Neutral Organics
Fish
ChV
0.000476
2,2',3,4,4',5'-Hexachlorobiphenyl
138
35065-28-2
Neutral Organics
Daphnid
ChV
0.00104
E-7
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,2',3,4,4',5'-Hexachlorobiphenylb
138
35065-28-2
Neutral Organics
Green Algae
ChV
0.013
2,2',3,4,4',5'-Hexachlorobiphenylb
138
35065-28-2
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,2',3,4,4',5'-Hexachlorobiphenyl
138
35065-28-2
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,2',3,4,4',5'-Hexachlorobiphenylb
138
35065-28-2
Neutral Organics
Fish (SW)
ChV
0.012
2,2',3,4,4',5'-Hexachlorobiphenyl
138
35065-28-2
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,2',3,4,4',5'-Hexachlorobiphenylb
138
35065-28-2
Neutral Organics
Earthworm
14-day
LC50
163.817
2,2',3,4,4'-Pentachlorobiphenylb
85
65510-45-4
Neutral Organics
Fish
96-hr
LC50
0.009
2,2',3,4,4'-Pentachlorobiphenylb
85
65510-45-4
Neutral Organics
Daphnid
48-hr
LC50
0.008
2,2',3,4,4'-Pentachlorobiphenylb
85
65510-45-4
Neutral Organics
Green Algae
96-hr
EC50
0.041
2,2',3,4,4'-Pentachlorobiphenyl
85
65510-45-4
Neutral Organics
Fish
ChV
0.00152
2,2',3,4,4'-Pentachlorobiphenyl
85
65510-45-4
Neutral Organics
Daphnid
ChV
0.003
2,2',3,4,4'-Pentachlorobiphenylb
85
65510-45-4
Neutral Organics
Green Algae
ChV
0.03
2,2',3,4,4'-Pentachlorobiphenylb
85
65510-45-4
Neutral Organics
Fish (SW)
96-hr
LC50
0.012
2,2',3,4,4'-Pentachlorobiphenyl
85
65510-45-4
Neutral Organics
Mysid
96-hr
LC50
0.000299
2,2',3,4,4'-Pentachlorobiphenylb
85
65510-45-4
Neutral Organics
Fish (SW)
ChV
0.027
2,2',3,4,4'-Pentachlorobiphenyl
85
65510-45-4
Neutral Organics
Mysid (SW)
ChV
5.91E-06
2,2',3,4,4'-Pentachlorobiphenylb
85
65510-45-4
Neutral Organics
Earthworm
14-day
LC50
172.833
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
Neutral Organics
Fish
96-hr
LC50
0.009
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
Neutral Organics
Daphnid
48-hr
LC50
0.008
2,2',3,4,5'-Pentachlorobiphenylb
87
38380-02-8
Neutral Organics
Green Algae
96-hr
EC50
0.041
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
Neutral Organics
Fish
ChV
0.00152
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
Neutral Organics
Daphnid
ChV
0.003
2,2',3,4,5'-Pentachlorobiphenylb
87
38380-02-8
Neutral Organics
Green Algae
ChV
0.03
2,2',3,4,5'-Pentachlorobiphenylb
87
38380-02-8
Neutral Organics
Fish (SW)
96-hr
LC50
0.012
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
Neutral Organics
Mysid
96-hr
LC50
0.000299
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
Neutral Organics
Fish (SW)
ChV
0.027
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
Neutral Organics
Mysid (SW)
ChV
5.91E-06
2,2',3,4,5'-Pentachlorobiphenylb
87
38380-02-8
Neutral Organics
Earthworm
14-day
LC50
172.833
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
Neutral Organics
Fish
96-hr
LC50
0.009
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
Neutral Organics
Daphnid
48-hr
LC50
0.008
2,2',3,5',6-Pentachlorobiphenylb
95
38379-99-6
Neutral Organics
Green Algae
96-hr
EC50
0.041
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
Neutral Organics
Fish
ChV
0.00152
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
Neutral Organics
Daphnid
ChV
0.003
2,2',3,5',6-Pentachlorobiphenylb
95
38379-99-6
Neutral Organics
Green Algae
ChV
0.03
2,2',3,5',6-Pentachlorobiphenylb
95
38379-99-6
Neutral Organics
Fish (SW)
96-hr
LC50
0.012
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
Neutral Organics
Mysid
96-hr
LC50
0.000299
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
Neutral Organics
Fish (SW)
ChV
0.027
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
Neutral Organics
Mysid (SW)
ChV
5.91E-06
2,2',3,5',6-Pentachlorobiphenylb
95
38379-99-6
Neutral Organics
Earthworm
14-day
LC50
172.833
2,2',3,5-Tetrachlorobiphenylb
43
70362-46-8
Neutral Organics
Fish
96-hr
LC50
0.031
2,2',3,5-Tetrachlorobiphenylb
43
70362-46-8
Neutral Organics
Daphnid
48-hr
LC50
0.026
2,2',3,5-Tetrachlorobiphenylb
43
70362-46-8
Neutral Organics
Green Algae
96-hr
EC50
0.101
2,2',3,5-Tetrachlorobiphenyl
43
70362-46-8
Neutral Organics
Fish
ChV
0.005
2,2',3,5-Tetrachlorobiphenyl
43
70362-46-8
Neutral Organics
Daphnid
ChV
0.008
2,2',3,5-Tetrachlorobiphenylb
43
70362-46-8
Neutral Organics
Green Algae
ChV
0.065
2,2',3,5-Tetrachlorobiphenylb
43
70362-46-8
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
2,2',3,5-Tetrachlorobiphenyl
43
70362-46-8
Neutral Organics
Mysid
96-hr
LC50
0.00156
2,2',3,5-Tetrachlorobiphenylb
43
70362-46-8
Neutral Organics
Fish (SW)
ChV
0.061
2,2',3,5-Tetrachlorobiphenyl
43
70362-46-8
Neutral Organics
Mysid (SW)
ChV
3.74E-05
2,2',3,5-Tetrachlorobiphenylb
43
70362-46-8
Neutral Organics
Earthworm
14-day
LC50
180.316
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Fish
96-hr
LC50
0.031
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Daphnid
48-hr
LC50
0.026
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Green Algae
96-hr
EC50
0.101
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Fish
ChV
0.005
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Daphnid
ChV
0.008
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Green Algae
ChV
0.065
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Mysid
96-hr
LC50
0.00156
E-8
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Fish (SW)
ChV
0.061
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
Neutral Organics
Mysid (SW)
ChV
3.74E-05
2,2',3,6-Tetrachlorobiphenylb
45
70362-45-7
Neutral Organics
Earthworm
14-day
LC50
180.316
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Fish
96-hr
LC50
0.003
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Daphnid
48-hr
LC50
0.003
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,2',4,4',5,5'-Hexachlorobiphenyl
153
35065-27-1
Neutral Organics
Fish
ChV
0.000476
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Daphnid
ChV
0.00104
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Green Algae
ChV
0.013
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,2',4,4',5,5'-Hexachlorobiphenyl
153
35065-27-1
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Fish (SW)
ChV
0.012
2,2',4,4',5,5'-Hexachlorobiphenyl
153
35065-27-1
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,2',4,4',5,5'-Hexachlorobiphenylb
153
35065-27-1
Neutral Organics
Earthworm
14-day
LC50
163.817
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Fish
96-hr
LC50
0.031
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Daphnid
48-hr
LC50
0.026
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Green Algae
96-hr
EC50
0.101
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Fish
ChV
0.005
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Daphnid
ChV
0.008
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Green Algae
ChV
0.065
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Mysid
96-hr
LC50
0.00156
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Fish (SW)
ChV
0.061
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
Neutral Organics
Mysid (SW)
ChV
3.74E-05
2,2',4,4'-Tetrachlorobiphenylb
47
2437-79-8
Neutral Organics
Earthworm
14-day
LC50
180.316
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
Neutral Organics
Fish
96-hr
LC50
0.009
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
Neutral Organics
Daphnid
48-hr
LC50
0.008
2,2',4,5,5'-Pentachlorobiphenylb
101
37680-73-2
Neutral Organics
Green Algae
96-hr
EC50
0.041
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
Neutral Organics
Fish
ChV
0.00152
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
Neutral Organics
Daphnid
ChV
0.003
2,2',4,5,5'-Pentachlorobiphenylb
101
37680-73-2
Neutral Organics
Green Algae
ChV
0.03
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
Neutral Organics
Fish (SW)
96-hr
LC50
0.012
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
Neutral Organics
Mysid
96-hr
LC50
0.000299
2,2',4,5,5'-Pentachlorobiphenylb
101
37680-73-2
Neutral Organics
Fish (SW)
ChV
0.027
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
Neutral Organics
Mysid (SW)
ChV
5.91E-06
2,2',4,5,5'-Pentachlorobiphenylb
101
37680-73-2
Neutral Organics
Earthworm
14-day
LC50
172.833
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Fish
96-hr
LC50
0.031
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Daphnid
48-hr
LC50
0.026
2,2',4,5'-Tetrachlorobiphenylb
49
41464-40-8
Neutral Organics
Green Algae
96-hr
EC50
0.101
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Fish
ChV
0.005
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Daphnid
ChV
0.008
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Green Algae
ChV
0.065
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Mysid
96-hr
LC50
0.00156
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Fish (SW)
ChV
0.061
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
Neutral Organics
Mysid (SW)
ChV
3.74E-05
2,2',4,5'-Tetrachlorobiphenylb
49
41464-40-8
Neutral Organics
Earthworm
14-day
LC50
180.316
2,2',4,5-Tetrachlorobiphenylb
48
70362-47-9
Neutral Organics
Fish
96-hr
LC50
0.031
2,2',4,5-Tetrachlorobiphenylb
48
70362-47-9
Neutral Organics
Daphnid
48-hr
LC50
0.026
2,2',4,5-Tetrachlorobiphenylb
48
70362-47-9
Neutral Organics
Green Algae
96-hr
EC50
0.101
2,2',4,5-Tetrachlorobiphenyl
48
70362-47-9
Neutral Organics
Fish
ChV
0.005
2,2',4,5-Tetrachlorobiphenyl
48
70362-47-9
Neutral Organics
Daphnid
ChV
0.008
2,2',4,5-Tetrachlorobiphenylb
48
70362-47-9
Neutral Organics
Green Algae
ChV
0.065
2,2',4,5-Tetrachlorobiphenylb
48
70362-47-9
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
2,2',4,5-Tetrachlorobiphenyl
48
70362-47-9
Neutral Organics
Mysid
96-hr
LC50
0.00156
2,2',4,5-Tetrachlorobiphenylb
48
70362-47-9
Neutral Organics
Fish (SW)
ChV
0.061
2,2',4,5-Tetrachlorobiphenyl
48
70362-47-9
Neutral Organics
Mysid (SW)
ChV
3.74E-05
2,2',4,5-Tetrachlorobiphenylb
48
70362-47-9
Neutral Organics
Earthworm
14-day
LC50
180.316
E-9
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Fish
96-hr
LC50
0.031
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Daphnid
48-hr
LC50
0.026
2,2',4,6'-Tetrachlorobiphenylb
51
68194-04-7
Neutra
Organics
Green Algae
96-hr
EC50
0.101
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Fish
ChV
0.005
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Daphnid
ChV
0.008
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Green Algae
ChV
0.065
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Fish (SW)
96-hr
LC50
0.04
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Mysid
96-hr
LC50
0.00156
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Fish (SW)
ChV
0.061
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
Neutra
Organics
Mysid (SW)
ChV
3.74E-05
2,2',4,6'-Tetrachlorobiphenylb
51
68194-04-7
Neutra
Organics
Earthworm
14-day
LC50
180.316
2,2',5,5'-Tetrachlorobiphenylb
52
35693-99-3
Neutra
Organics
Fish
96-hr
LC50
0.031
2,2',5,5'-Tetrachlorobiphenylb
52
35693-99-3
Neutra
Organics
Daphnid
48-hr
LC50
0.026
2,2',5,5'-Tetrachlorobiphenylb
52
35693-99-3
Neutra
Organics
Green Algae
96-hr
EC50
0.101
2,2',5,5'-Tetrachlorobiphenyl
52
35693-99-3
Neutra
Organics
Fish
ChV
0.005
2,2',5,5'-Tetrachlorobiphenyl
52
35693-99-3
Neutra
Organics
Daphnid
ChV
0.008
2,2',5,5'-Tetrachlorobiphenylb
52
35693-99-3
Neutra
Organics
Green Algae
ChV
0.065
2,2',5,5'-Tetrachlorobiphenylb
52
35693-99-3
Neutra
Organics
Fish (SW)
96-hr
LC50
0.04
2,2',5,5'-Tetrachlorobiphenyl
52
35693-99-3
Neutra
Organics
Mysid
96-hr
LC50
0.00156
2,2',5,5'-Tetrachlorobiphenyl
52
35693-99-3
Neutra
Organics
Fish (SW)
ChV
0.061
2,2',5,5'-Tetrachlorobiphenylb
52
35693-99-3
Neutra
Organics
Mysid (SW)
ChV
3.74E-05
2,2',5,5'-Tetrachlorobiphenylb
52
35693-99-3
Neutra
Organics
Earthworm
14-day
LC50
180.316
2,2',6-Trichlorobiphenylb
19
38444-73-4
Neutra
Organics
Fish
96-hr
LC50
0.103
2,2',6-Trichlorobiphenyl
19
38444-73-4
Neutra
Organics
Daphnid
48-hr
LC50
0.082
2,2',6-Trichlorobiphenylb
19
38444-73-4
Neutra
Organics
Green Algae
96-hr
EC50
0.25
2,2',6-Trichlorobiphenyl
19
38444-73-4
Neutra
Organics
Fish
ChV
0.015
2,2',6-Trichlorobiphenyl
19
38444-73-4
Neutra
Organics
Daphnid
ChV
0.021
2,2',6-Trichlorobiphenylb
19
38444-73-4
Neutra
Organics
Green Algae
ChV
0.14
2,2',6-Trichlorobiphenyl
19
38444-73-4
Neutra
Organics
Fish (SW)
96-hr
LC50
0.132
2,2',6-Trichlorobiphenyl
19
38444-73-4
Neutra
Organics
Mysid
96-hr
LC50
0.008
2,2',6-Trichlorobiphenylb
19
38444-73-4
Neutra
Organics
Fish (SW)
ChV
0.136
2,2',6-Trichlorobiphenyl
19
38444-73-4
Neutra
Organics
Mysid (SW)
ChV
0.000233
2,2',6-Trichlorobiphenylb
19
38444-73-4
Neutra
Organics
Earthworm
14-day
LC50
185.504
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Fish
96-hr
LC50
13.461
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Daphnid
48-hr
LC50
24.33
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Green Algae
96-hr
EC50
8.419
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Fish
ChV
0.77
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Daphnid
ChV
11.427
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Green Algae
ChV
3.298
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Fish (SW)
96-hr
LC50
18.903
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Mysid
96-hr
LC50
9.769
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Fish (SW)
ChV
3.428
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Mysid (SW)
ChV
50.199
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters
Earthworm
14-day
LC50
2882.783
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters (phosphate)
Fish
96-hr
LC50
4.413
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters (phosphate)
Daphnid
48-hr
LC50
0.007
E-10
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
38051-10-4
ester phosphoric acidb
NA
Esters (phosphate)
Green Algae
96-hr
EC50
311.506
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters (phosphate)
Fish
ChV
0.019
2,2-Bis(chioromethyi)-1,3-propanediyl tetrakis(2-chloroethyl)
38051-10-4
ester phosphoric acidb
NA
Esters (phosphate)
Green Algae
ChV
42.414
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters (phosphate)
Fish (SW)
96-hr
LC50
2.225
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
38051-10-4
ester phosphoric acidb
NA
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.016
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acidb
NA
38051-10-4
Esters (phosphate)
Fish (SW)
ChV
0.094
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
38051-10-4
ester phosphoric acidb
NA
Esters (phosphate)
Mysid (SW)
ChV
0.000171
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Fish
96-hr
LC50
0.337
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Daphnid
48-hr
LC50
0.253
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Green Algae
96-hr
EC50
0.604
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Fish
ChV
0.046
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Daphnid
ChV
0.054
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Green Algae
ChV
0.296
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Fish (SW)
96-hr
LC50
0.432
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Mysid
96-hr
LC50
0.041
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Fish (SW)
ChV
0.301
2,2'-Dichlorobiphenyl
4
13029-08-8
Neutral Organics
Mysid (SW)
ChV
0.00143
2,2'-Dichlorobiphenylb
4
13029-08-8
Neutral Organics
Earthworm
14-day
LC50
187.428
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Fish
96-hr
LC50
0.000762
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Daphnid
48-hr
LC50
0.000772
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Green Algae
96-hr
EC50
0.006
2,3,3',4,4',5,6-Heptachlorobiphenyl
190
41411-64-7
Neutral Organics
Fish
ChV
0.000147
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Daphnid
ChV
0.000377
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Green Algae
ChV
0.006
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.000996
2,3,3',4,4',5,6-Heptachlorobiphenyl
190
41411-64-7
Neutral Organics
Mysid
96-hr
LC50
1.06E-05
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Fish (SW)
ChV
0.005
2,3,3',4,4',5,6-Heptachlorobiphenyl
190
41411-64-7
Neutral Organics
Mysid (SW)
ChV
1.43E-07
2,3,3',4,4',5,6-Heptachlorobiphenylb
190
41411-64-7
Neutral Organics
Earthworm
14-day
LC50
153.856
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Fish
96-hr
LC50
0.003
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Daphnid
48-hr
LC50
0.003
2,3,3',4,4',6-Hexachlorobiphenylb
158
74472-42-7
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Fish
ChV
0.000476
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Daphnid
ChV
0.00104
2,3,3',4,4',6-Hexachlorobiphenylb
158
74472-42-7
Neutral Organics
Green Algae
ChV
0.013
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Fish (SW)
ChV
0.012
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,3,3',4,4',6-Hexachlorobiphenylb
158
74472-42-7
Neutral Organics
Earthworm
14-day
LC50
163.817
2,3,3',4',5,6-Hexachlorobiphenylb
163
74472-44-9
Neutral Organics
Fish
96-hr
LC50
0.003
2,3,3',4',5,6-Hexachlorobiphenylb
163
74472-44-9
Neutral Organics
Daphnid
48-hr
LC50
0.003
2,3,3',4',5,6-Hexachlorobiphenylb
163
74472-44-9
Neutral Organics
Green Algae
96-hr
EC50
0.016
2,3,3',4',5,6-Hexachlorobiphenyl
163
74472-44-9
Neutral Organics
Fish
ChV
0.000476
2,3,3',4',5,6-Hexachlorobiphenyl
163
74472-44-9
Neutral Organics
Daphnid
ChV
0.00104
2,3,3',4',5,6-Hexachlorobiphenylb
163
74472-44-9
Neutral Organics
Green Algae
ChV
0.013
2,3,3',4',5,6-Hexachlorobiphenylb
163
74472-44-9
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
2,3,3', 4' ,5,6-Hexach lorobipheny I
163
74472-44-9
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
2,3,3',4',5,6-Hexachlorobiphenylb
163
74472-44-9
Neutral Organics
Fish (SW)
ChV
0.012
2,3,3', 4' ,5,6-Hexach lorobipheny I
163
74472-44-9
Neutral Organics
Mysid (SW)
ChV
9.23E-07
2,3,3',4',5,6-Hexachlorobiphenylb
163
74472-44-9
Neutral Organics
Earthworm
14-day
LC50
163.817
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
Neutral Organics
Fish
96-hr
LC50
0.031
E-ll
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
Neutral Organics
Daphnid
48-hr
LC50
0.026
2,3',4,4'-Tetrachlorobiphenylb
66
32598-10-0
Neutral Organics
Green Algae
96-hr
EC50
0.101
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
Neutral Organics
Fish
ChV
0.005
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
Neutral Organics
Daphnid
ChV
0.008
2,3',4,4'-Tetrachlorobiphenylb
66
32598-10-0
Neutral Organics
Green Algae
ChV
0.065
2,3',4,4'-Tetrachlorobiphenylb
66
32598-10-0
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
Neutral Organics
Mysid
96-hr
LC50
0.00156
2,3',4,4'-Tetrachlorobiphenylb
66
32598-10-0
Neutral Organics
Fish (SW)
ChV
0.061
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
Neutral Organics
Mysid (SW)
ChV
3.74E-05
2,3',4,4'-Tetrachlorobiphenylb
66
32598-10-0
Neutral Organics
Earthworm
14-day
LC50
180.316
2,3,4'-Trichlorobiphenyl
22
38444-85-8
Neutral Organics
Fish
96-hr
LC50
0.103
2,3,4'-Trichlorobiphenyl
22
38444-85-8
Neutral Organics
Daphnid
48-hr
LC50
0.082
2,3,4'-Trichlorobiphenylb
22
38444-85-8
Neutral Organics
Green Algae
96-hr
EC50
0.25
2,3,4'-Trichlorobiphenyl
22
38444-85-8
Neutral Organics
Fish
ChV
0.015
2,3,4'-Trichlorobiphenyl
22
38444-85-8
Neutral Organics
Daphnid
ChV
0.021
2,3,4'-Trichlorobiphenylb
22
38444-85-8
Neutral Organics
Green Algae
ChV
0.14
2,3,4'-Trichlorobiphenylb
22
38444-85-8
Neutral Organics
Fish (SW)
96-hr
LC50
0.132
2,3,4'-Trichlorobiphenyl
22
38444-85-8
Neutral Organics
Mysid
96-hr
LC50
0.008
2,3,4'-Trichlorobiphenylb
22
38444-85-8
Neutral Organics
Fish (SW)
ChV
0.136
2,3,4'-Trichlorobiphenyl
22
38444-85-8
Neutral Organics
Mysid (SW)
ChV
0.000233
2,3,4'-Trichlorobiphenylb
22
38444-85-8
Neutral Organics
Earthworm
14-day
LC50
185.504
2,3,6-Trichlorobiphenylb
24
55702-45-9
Neutral Organics
Fish
96-hr
LC50
0.103
2,3,6-Trichlorobiphenyl
24
55702-45-9
Neutral Organics
Daphnid
48-hr
LC50
0.082
2,3,6-Trichlorobiphenylb
24
55702-45-9
Neutral Organics
Green Algae
96-hr
EC50
0.25
2,3,6-Trichlorobiphenyl
24
55702-45-9
Neutral Organics
Fish
ChV
0.015
2,3,6-Trichlorobiphenyl
24
55702-45-9
Neutral Organics
Daphnid
ChV
0.021
2,3,6-Trichlorobiphenyl
24
55702-45-9
Neutral Organics
Green Algae
ChV
0.14
2,3,6-Trichlorobiphenyl
24
55702-45-9
Neutral Organics
Fish (SW)
96-hr
LC50
0.132
2,3,6-Trichlorobiphenyl
24
55702-45-9
Neutral Organics
Mysid
96-hr
LC50
0.008
2,3,6-Trichlorobiphenylb
24
55702-45-9
Neutral Organics
Fish (SW)
ChV
0.136
2,3,6-Trichlorobiphenyl
24
55702-45-9
Neutral Organics
Mysid (SW)
ChV
0.000233
2,3,6-Trichlorobiphenylb
24
55702-45-9
Neutral Organics
Earthworm
14-day
LC50
185.504
2,3',6-Trichlorobiphenylb
27
38444-76-7
Neutral Organics
Fish
96-hr
LC50
0.103
2,3',6-Trichlorobiphenylb
27
38444-76-7
Neutral Organics
Daphnid
48-hr
LC50
0.082
2,3',6-Trichlorobiphenylb
27
38444-76-7
Neutral Organics
Green Algae
96-hr
EC50
0.25
2,3',6-Trichlorobiphenyl
27
38444-76-7
Neutral Organics
Fish
ChV
0.015
2,3',6-Trichlorobiphenyl
27
38444-76-7
Neutral Organics
Daphnid
ChV
0.021
2,3',6-Trichlorobiphenylb
27
38444-76-7
Neutral Organics
Green Algae
ChV
0.14
2,3',6-Trichlorobiphenylb
27
38444-76-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.132
2,3',6-Trichlorobiphenyl
27
38444-76-7
Neutral Organics
Mysid
96-hr
LC50
0.008
2,3',6-Trichlorobiphenylb
27
38444-76-7
Neutral Organics
Fish (SW)
ChV
0.136
2,3',6-Trichlorobiphenyl
27
38444-76-7
Neutral Organics
Mysid (SW)
ChV
0.000233
2,3',6-Trichlorobiphenylb
27
38444-76-7
Neutral Organics
Earthworm
14-day
LC50
185.504
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Fish
96-hr
LC50
0.337
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Daphnid
48-hr
LC50
0.253
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Green Algae
96-hr
EC50
0.604
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Fish
ChV
0.046
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Daphnid
ChV
0.054
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Green Algae
ChV
0.296
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.432
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Mysid
96-hr
LC50
0.041
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Fish (SW)
ChV
0.301
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Mysid (SW)
ChV
0.00143
2,3-Dichlorobiphenyl
5
16605-91-7
Neutral Organics
Earthworm
14-day
LC50
187.428
2,4',5-Trichlorobiphenylb
31
16606-02-3
Neutral Organics
Fish
96-hr
LC50
0.103
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Daphnid
48-hr
LC50
0.082
2,4',5-Trichlorobiphenylb
31
16606-02-3
Neutral Organics
Green Algae
96-hr
EC50
0.25
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Fish
ChV
0.015
E-12
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Daphnid
ChV
0.021
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Green Algae
ChV
0.14
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Fish (SW)
96-hr
LC50
0.132
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Mysid
96-hr
LC50
0.008
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Fish (SW)
ChV
0.136
2,4',5-Trichlorobiphenyl
31
16606-02-3
Neutral Organics
Mysid (SW)
ChV
0.000233
2,4',5-Trichlorobiphenylb
31
16606-02-3
Neutral Organics
Earthworm
14-day
LC50
185.504
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Fish
96-hr
LC50
0.021
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Daphnid
48-hr
LC50
0.045
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Green Algae
96-hr
EC50
0.134
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Fish
ChV
0.004
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Daphnid
ChV
0.008
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Green Algae
ChV
0.059
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Fish (SW)
96-hr
LC50
0.004
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Earthworm
14-day
LC50
3.903
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
Phenols
Lemna gibba
7-day
EC50
0.005
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Fish
96-hr
LC50
0.337
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Daphnid
48-hr
LC50
0.253
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Green Algae
96-hr
EC50
0.604
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Fish
ChV
0.046
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Daphnid
ChV
0.054
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Green Algae
ChV
0.296
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.432
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Mysid
96-hr
LC50
0.041
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Fish (SW)
ChV
0.301
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Mysid (SW)
ChV
0.00143
2,4'-Dichlorobiphenyl
8
34883-43-7
Neutral Organics
Earthworm
14-day
LC50
187.428
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Fish
96-hr
LC50
0.105
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Daphnid
48-hr
LC50
0.14
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Green Algae
96-hr
EC50
0.465
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Fish
ChV
0.017
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Daphnid
ChV
0.026
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Green Algae
ChV
0.209
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Fish (SW)
96-hr
LC50
0.026
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Earthworm
14-day
LC50
8.321
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
Phenols
Lemna gibba
7-day
EC50
0.033
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Fish
96-hr
LC50
0.021
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Daphnid
48-hr
LC50
0.044
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Green Algae
96-hr
EC50
0.133
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Fish
ChV
0.004
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Daphnid
ChV
0.008
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Green Algae
ChV
0.059
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Fish (SW)
96-hr
LC50
0.004
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Earthworm
14-day
LC50
3.749
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
Phenols
Lemna gibba
7-day
EC50
0.005
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Fish
96-hr
LC50
0.105
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Daphnid
48-hr
LC50
0.14
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Green Algae
96-hr
EC50
0.465
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Fish
ChV
0.017
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Daphnid
ChV
0.026
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Green Algae
ChV
0.209
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Fish (SW)
96-hr
LC50
0.026
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
Phenols
Earthworm
14-day
LC50
8.321
2,5-Di-tert-butylphenol (2,5-DTBP)b
NA
5875-45-6
Phenols
Lemna gibba
7-day
EC50
0.033
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Fish
96-hr
LC50
0.337
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Daphnid
48-hr
LC50
0.253
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Green Algae
96-hr
EC50
0.604
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Fish
ChV
0.046
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Daphnid
ChV
0.054
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Green Algae
ChV
0.296
E-13
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Fish (SW)
96-hr
LC50
0.432
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Mysid
96-hr
LC50
0.041
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Fish (SW)
ChV
0.301
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Mysid (SW)
ChV
0.00143
2,6-Dichlorobiphenyl
10
33146-45-1
Neutral Organics
Earthworm
14-day
LC50
187.428
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters
Fish
96-hr
LC50
6.277
2-Butoxy-, hydrogen phosphate ethanolb
NA
14260-97-0
Esters
Daphnid
48-hr
LC50
10.937
2-Butoxy-, hydrogen phosphate ethanolb
NA
14260-97-0
Esters
Green Algae
96-hr
EC50
3.585
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters
Fish
ChV
0.334
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters
Daphnid
ChV
4.655
2-Butoxy-, hydrogen phosphate ethanolb
NA
14260-97-0
Esters
Green Algae
ChV
1.569
2-Butoxy-, hydrogen phosphate ethanolb
NA
14260-97-0
Esters
Fish (SW)
96-hr
LC50
8.632
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters
Mysid
96-hr
LC50
3.768
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters
Fish (SW)
ChV
1.665
2-Butoxy-, hydrogen phosphate ethanolb
NA
14260-97-0
Esters
Mysid (SW)
ChV
9.635
2-Butoxy-, hydrogen phosphate ethanolb
NA
14260-97-0
Esters
Earthworm
14-day
LC50
1652.378
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Fish
96-hr
LC50
2.474
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Daphnid
48-hr
LC50
0.004
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Green Algae
96-hr
EC50
89.715
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Fish
ChV
0.012
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Green Algae
ChV
19.413
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Fish (SW)
96-hr
LC50
1.387
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.01
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Fish (SW)
ChV
0.055
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
Esters (phosphate)
Mysid (SW)
ChV
9.60E-05
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Fish
96-hr
LC50
1.08
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Daphnid
48-hr
LC50
0.766
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Green Algae
96-hr
EC50
1.426
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Fish
ChV
0.137
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Daphnid
ChV
0.138
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Green Algae
ChV
0.612
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Fish (SW)
96-hr
LC50
1.38
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Mysid
96-hr
LC50
0.202
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Fish (SW)
ChV
0.649
2-Chlorobiphenyl
1
2051-60-7
Neutral Organics
Mysid (SW)
ChV
0.009
2-Chlorobiphenylb
1
2051-60-7
Neutral Organics
Earthworm
14-day
LC50
184.859
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Fish
96-hr
LC50
0.15
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Daphnid
48-hr
LC50
0.197
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Green Algae
96-hr
EC50
0.042
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Fish
ChV
0.005
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Daphnid
ChV
0.039
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Green Algae
ChV
0.044
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Fish (SW)
96-hr
LC50
0.175
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Mysid
96-hr
LC50
0.021
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Fish (SW)
ChV
0.054
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Mysid (SW)
ChV
0.00024
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters
Earthworm
14-day
LC50
194.499
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Fish
96-hr
LC50
0.246
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Daphnid
48-hr
LC50
0.000335
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Green Algae
96-hr
EC50
0.052
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Fish
ChV
0.005
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Green Algae
ChV
0.401
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.312
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.00176
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
Esters (phosphate)
Fish (SW)
ChV
0.008
2-Ethylhexyl diphenyl phosphateb
NA
1241-94-7
Esters (phosphate)
Mysid (SW)
ChV
9.86E-06
3,4,4'-Trichlorobiphenylb
37
38444-90-5
Neutral Organics
Fish
96-hr
LC50
0.103
3,4,4'-Trichlorobiphenyl
37
38444-90-5
Neutral Organics
Daphnid
48-hr
LC50
0.082
3,4,4'-Trichlorobiphenylb
37
38444-90-5
Neutral Organics
Green Algae
96-hr
EC50
0.25
E-14
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Predicted
PCB
Organism -
Duration -
Endpoint-
value-
Chemical
congener #
CAS number
Chemical class - ECOSAR
ECOSAR
ECOSAR
ECOSAR
ECOSAR
3,4,4'-Trichlorobiphenyl
37
38444-90-5
Neutral Organics
Fish
ChV
0.015
3,4,4'-Trichlorobiphenyl
37
38444-90-5
Neutral Organics
Daphnid
ChV
0.021
3,4,4'-Trichlorobiphenylb
37
38444-90-5
Neutral Organics
Green Algae
ChV
0.14
3,4,4'-Trichlorobiphenyl
37
38444-90-5
Neutral Organics
Fish (SW)
96-hr
LC50
0.132
3,4,4'-Trichlorobiphenyl
37
38444-90-5
Neutral Organics
Mysid
96-hr
LC50
0.008
3,4,4'-Trichlorobiphenylb
37
38444-90-5
Neutral Organics
Fish (SW)
ChV
0.136
3,4,4'-Trichlorobiphenyl
37
38444-90-5
Neutral Organics
Mysid (SW)
ChV
0.000233
3,4,4'-Trichlorobiphenylb
37
38444-90-5
Neutral Organics
Earthworm
14-day
LC50
185.504
3,5-Bis(1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis(1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Esters
Fish
96-hr
LC50
0.00125
3,5-Bis(1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis(1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Esters
Daphnid
48-hr
LC50
0.0011
3,5-Bis(1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis(1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Esters
Green Algae
96-hr
EC50
0.000132
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1-
4221-80-1
dimethylethyl)phenyl ester benzoic acid
NA
Esters
Fish
ChV
1.75E-05
3,5-Bis(1,1-dimethyiethyi)-4-hydroxy-, 2,4-bis(1,1-
4221-80-1
dimethylethyl)phenyl ester benzoic acid
NA
Esters
Daphnid
ChV
7.53E-05
3,5-Bis(1,1 -dimethyiethyi)-4-hydroxy-, 2,4-bis(1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Esters
Green Algae
ChV
0.000454
3,5-Bis( 1,1 -dimethyiethyi)-4-hydroxy-, 2,4-bis( 1,1-
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Esters
Fish (SW)
96-hr
LC50
0.00116
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1-
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Esters
Mysid
96-hr
LC50
2.21E-05
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1-
4221-80-1
dimethylethyl)phenyl ester benzoic acid
NA
Esters
Fish (SW)
ChV
0.000703
3,5-Bis(1,1-dimethyiethyi)-4-hydroxy-, 2,4-bis(1,1-
4221-80-1
dimethyiethyl)phenyl ester benzoic acid
NA
Esters
Mysid (SW)
ChV
1.35E-10
3,5-Bis(1,1 -dimethyiethyi)-4-hydroxy-, 2,4-bis(1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Esters
Earthworm
14-day
LC50
15.055
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Phenols
Fish
96-hr
LC50
6.31E-05
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Phenols
Daphnid
48-hr
LC50
0.00067
3,5-Bis( 1,1 -dimethyiethyi)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Phenols
Green Algae
96-hr
EC50
0.00142
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Phenols
Fish
ChV
2.06E-05
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Phenols
Daphnid
ChV
0.000126
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Phenols
Green Algae
ChV
0.000601
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acid
NA
Phenols
Fish (SW)
96-hr
LC50
6.51E-06
3,5-Bis( 1,1 -dimethyiethyi)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acidb
NA
Phenols
Earthworm
14-day
LC50
0.218
3,5-Bis( 1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis( 1,1 -
4221-80-1
dimethylethyl)phenyl ester benzoic acid
NA
Phenols
Lemna gibba
7-day
EC50
6.17E-06
4-(Butan-2-yl)-2,6-di-tert-butylphenol
NA
17540-75-9
Phenols
Fish
96-hr
LC50
0.02
4-(Butan-2-yi)-2,6-di-tert-butyiphenol
NA
17540-75-9
Phenols
Daphnid
48-hr
LC50
0.042
4-(Butan-2-yl)-2,6-di-tert-butylphenol
NA
17540-75-9
Phenols
Green Algae
96-hr
EC50
0.127
4-(Butan-2-yi)-2,6-di-tert-butyiphenol
NA
17540-75-9
Phenols
Fish
ChV
0.004
4-(Butan-2-yi)-2,6-di-tert-butyiphenol
NA
17540-75-9
Phenols
Daphnid
ChV
0.008
4-(Butan-2-yi)-2,6-di-tert-butyiphenol
NA
17540-75-9
Phenols
Green Algae
ChV
0.056
4-(Butan-2-yi)-2,6-di-tert-butyiphenol
NA
17540-75-9
Phenols
Fish (SW)
96-hr
LC50
0.004
4-(Butan-2-yl)-2,6-di-tert-butylphenol
NA
17540-75-9
Phenols
Earthworm
14-day
LC50
3.767
4-(Butan-2-yi)-2,6-di-tert-butyiphenolb
NA
17540-75-9
Phenols
Lemna gibba
7-day
EC50
0.005
4,4',4"-(1 -Methyi-1 -propanyl-3-ylidene)tris 2-(1,1 -dimethylethyl)-
5-methyl-phenolb
NA
1843-03-4
Phenols, Poly
Fish
96-hr
LC50
1.24E-05
E-15
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
4,4',4"-(1 -Methyl-1 -propanyl-3-ylidene)tris 2-( 1,1 -dimethylethyl)-
5-methyl-phenolb
NA
1843-03-4
Phenols, Poly
Daphnid
48-hr
LC50
1.38E-06
4,4', 4"-( 1 -Methyl-1 -propanyl-3-ylidene)tris 2-(1,1 -dimethylethyl)-
5-methyl-phenolb
NA
1843-03-4
Phenols, Poly
Green Algae
96-hr
EC50
0.003
4,4', 4"-( 1 -Methyl-1 -propanyl-3-ylidene)tris 2-(1,1 -dimethylethyl)-
5-methyl-phenolb
NA
1843-03-4
Phenols, Poly
Fish
ChV
1.34E-06
4,4', 4"-( 1 -Methyl-1 -propanyl-3-ylidene)tris 2-(1,1 -dimethylethyl)-
5-methyl-phenolb
NA
1843-03-4
Phenols, Poly
Daphnid
ChV
2.71E-07
4,4', 4"-( 1 -Methyl-1 -propanyl-3-ylidene)tris 2-(1,1 -dimethylethyl)-
5-methyl-phenolb
NA
1843-03-4
Phenols, Poly
Green Algae
ChV
0.00179
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Fish
96-hr
LC50
0.00155
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Daphnid
48-hr
LC50
0.000755
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Green Algae
96-hr
EC50
0.038
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Fish
ChV
0.000295
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Daphnid
ChV
0.000185
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Green Algae
ChV
0.014
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Fish
96-hr
LC50
0.000183
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Daphnid
48-hr
LC50
0.000198
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Green Algae
96-hr
EC50
0.002
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)
NA
118-82-1
Phenols, Poly
Fish
ChV
3.83E-05
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)
NA
118-82-1
Phenols, Poly
Daphnid
ChV
0.000116
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)b
NA
118-82-1
Phenols, Poly
Green Algae
ChV
0.002
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)b
NA
96-69-5
Phenols, Poly
Fish
96-hr
LC50
0.004
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)b
NA
96-69-5
Phenols, Poly
Daphnid
48-hr
LC50
0.002
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)b
NA
96-69-5
Phenols, Poly
Green Algae
96-hr
EC50
0.058
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)
NA
96-69-5
Phenols, Poly
Fish
ChV
0.00078
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)
NA
96-69-5
Phenols, Poly
Daphnid
ChV
0.000615
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)b
NA
96-69-5
Phenols, Poly
Green Algae
ChV
0.02
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Fish
96-hr
LC50
1.08
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Daphnid
48-hr
LC50
0.766
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Green Algae
96-hr
EC50
1.426
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Fish
ChV
0.137
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Daphnid
ChV
0.138
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Green Algae
ChV
0.612
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Fish (SW)
96-hr
LC50
1.38
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Mysid
96-hr
LC50
0.202
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Fish (SW)
ChV
0.649
4-Chlorobiphenyl
3
2051-62-9
Neutral Organics
Mysid (SW)
ChV
0.009
4-Chlorobiphenylb
3
2051-62-9
Neutral Organics
Earthworm
14-day
LC50
184.859
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Fish
96-hr
LC50
900.811
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Daphnid
48-hr
LC50
543.56
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Green Algae
96-hr
EC50
520.667
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Fish
ChV
94.6
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Daphnid
ChV
62.785
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Green Algae
ChV
156.128
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Fish (SW)
96-hr
LC50
1138.535
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Mysid
96-hr
LC50
541.573
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Fish (SW)
ChV
184.771
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Mysid (SW)
ChV
38.511
6:2 Fluorotelomer sulfonic acidb
NA
27619-97-2
Neutral Organics-acid
Earthworm
14-day
LC50
6360.704
8:2 Fluorotelomer sulfonic acid
NA
39108-34-4
Neutral Organics-acid
Fish
96-hr
LC50
69.818
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Daphnid
48-hr
LC50
47.67
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Green Algae
96-hr
EC50
76.108
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Fish
ChV
8.482
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Daphnid
ChV
7.766
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Green Algae
ChV
30.051
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Fish (SW)
96-hr
LC50
88.953
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Mysid
96-hr
LC50
17.091
E-16
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Fish (SW)
ChV
32.684
8:2 Fluorotelomer sulfonic acidb
NA
39108-34-4
Neutral Organics-acid
Mysid (SW)
ChV
0.817
Ammelide
NA
645-93-2
Aliphatic Amines
Fish
96-hr
LC50
3192.474
Ammelide
NA
645-93-2
Aliphatic Amines
Daphnid
48-hr
LC50
261.821
Ammelide
NA
645-93-2
Aliphatic Amines
Green Algae
96-hr
EC50
452.702
Ammelide
NA
645-93-2
Aliphatic Amines
Fish
ChV
581.053
Ammelide
NA
645-93-2
Aliphatic Amines
Daphnid
ChV
14.951
Ammelide
NA
645-93-2
Aliphatic Amines
Green Algae
ChV
114.773
Ammelide
NA
645-93-2
Triazines, Aromatic
Fish
96-hr
LC50
37829.289
Ammelide
NA
645-93-2
Triazines, Aromatic
Daphnid
48-hr
LC50
2680.09
Ammelide
NA
645-93-2
Triazines, Aromatic
Green Algae
96-hr
EC50
2.91
Ammelide
NA
645-93-2
Triazines, Aromatic
Fish
ChV
831.762
Ammelide
NA
645-93-2
Triazines, Aromatic
Daphnid
ChV
140.511
Ammelide
NA
645-93-2
Triazines, Aromatic
Green Algae
ChV
0.568
Ammelide
NA
645-93-2
Triazines, Aromatic
Fish (SW)
96-hr
LC50
7546.853
Ammelide
NA
645-93-2
Triazines, Aromatic
Mysid (SW)
96-hr
LC50
1222.794
Ammelide
NA
645-93-2
Triazines, Aromatic
Fish (SW)
ChV
91.971
Ammelide
NA
645-93-2
Triazines, Aromatic
Mysid (SW)
ChV
39508.148
Ammeline
NA
645-92-1
Aliphatic Amines
Fish
96-hr
LC50
1.25E+05
Ammeline
NA
645-92-1
Aliphatic Amines
Daphnid
48-hr
LC50
7.75E+03
Ammeline
NA
645-92-1
Aliphatic Amines
Green Algae
96-hr
EC50
2.34E+04
Ammeline
NA
645-92-1
Aliphatic Amines
Fish
ChV
5.40E+04
Ammeline
NA
645-92-1
Aliphatic Amines
Daphnid
ChV
3.36E+02
Ammeline
NA
645-92-1
Aliphatic Amines
Green Algae
ChV
4.85E+03
Ammeline
NA
645-92-1
Triazines, Aromatic
Fish
96-hr
LC50
4.62E+06
Ammeline
NA
645-92-1
Triazines, Aromatic
Daphnid
48-hr
LC50
7.52E+04
Ammeline
NA
645-92-1
Triazines, Aromatic
Green Algae
96-hr
EC50
3.48E+01
Ammeline
NA
645-92-1
Triazines, Aromatic
Fish
ChV
9.00E+04
Ammeline
NA
645-92-1
Triazines, Aromatic
Daphnid
ChV
4.59E+03
Ammeline
NA
645-92-1
Triazines, Aromatic
Green Algae
ChV
3.31 E+00
Ammeline
NA
645-92-1
Triazines, Aromatic
Fish (SW)
96-hr
LC50
3.72E+05
Ammeline
NA
645-92-1
Triazines, Aromatic
Mysid (SW)
96-hr
LC50
6.42E+04
Ammeline
NA
645-92-1
Triazines, Aromatic
Fish (SW)
ChV
1.48E+03
Ammeline
NA
645-92-1
Triazines, Aromatic
Mysid (SW)
ChV
3.97E+07
Amoxicillin
NA
26787-78-0
Aliphatic Amines-acid
Fish
96-hr
LC50
3316.052
Amoxicillin
NA
26787-78-0
Aliphatic Amines-acid
Daphnid
48-hr
LC50
350.823
Amoxicillin
NA
26787-78-0
Aliphatic Amines-acid
Green Algae
96-hr
EC50
366.544
Amoxicillin
NA
26787-78-0
Aliphatic Amines-acid
Fish
ChV
277.769
Amoxicillin
NA
26787-78-0
Aliphatic Amines-acid
Daphnid
ChV
25.662
Amoxicillin
NA
26787-78-0
Aliphatic Amines-acid
Green Algae
ChV
111.651
Amoxicillin
NA
26787-78-0
Phenols-acid
Fish
96-hr
LC50
3825.984
Amoxicillin
NA
26787-78-0
Phenols-acid
Daphnid
48-hr
LC50
729.352
Amoxicillin
NA
26787-78-0
Phenols-acid
Green Algae
96-hr
EC50
3706.393
Amoxicillin
NA
26787-78-0
Phenols-acid
Fish
ChV
332.326
Amoxicillin
NA
26787-78-0
Phenols-acid
Daphnid
ChV
138.981
Amoxicillin
NA
26787-78-0
Phenols-acid
Green Algae
ChV
1763.992
Amoxicillin
NA
26787-78-0
Phenols-acid
Fish (SW)
96-hr
LC50
2081.878
Amoxicillin13
NA
26787-78-0
Phenols-acid
Earthworm
14-day
LC50
8922.189
Amoxicillin
NA
26787-78-0
Phenols-acid
Lemna gibba
7-day
EC50
3530.973
Amoxicillin13
NA
26787-78-0
Amides -acid
Fish
96-hr
LC50
5916.368
Amoxicillin13
NA
26787-78-0
Amides -acid
Daphnid
48-hr
LC50
10452.924
Amoxicillin
NA
26787-78-0
Amides -acid
Green Algae
96-hr
EC50
149.101
Amoxicillin
NA
26787-78-0
Amides -acid
Fish
ChV
5.51
Amoxicillin
NA
26787-78-0
Amides -acid
Daphnid
ChV
297.762
Amoxicillin
NA
26787-78-0
Amides -acid
Green Algae
ChV
90.833
Amoxicillin13
NA
26787-78-0
Amides -acid
Fish (SW)
96-hr
LC50
5171.768
Amoxicillin
NA
26787-78-0
Amides -acid
Mysid (SW)
96-hr
LC50
236.604
Amoxicillin
NA
26787-78-0
Phenol Amines -acid
Fish
96-hr
LC50
370.208
Amoxicillin
NA
26787-78-0
Phenol Amines -acid
Daphnid
48-hr
LC50
28.89
Amoxicillin
NA
26787-78-0
Phenol Amines -acid
Green Algae
96-hr
EC50
157.124
E-17
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Predicted
PCB
Organism -
Duration -
Endpoint-
value-
Chemical
congener #
CAS number
Chemical class - ECOSAR
ECOSAR
ECOSAR
ECOSAR
ECOSAR
Amoxicillin
NA
26787-78-0
Phenol Amines -acid
Fish
ChV
26.014
Amoxicillin
NA
26787-78-0
Phenol Amines -acid
Daphnid
ChV
13.678
Amoxicillin
NA
26787-78-0
Phenol Amines -acid
Green Algae
ChV
24.702
Ampicillin
NA
69-53-4
Aliphatic Amines-acid
Fish
96-hr
LC50
1533.506
Ampicillin
NA
69-53-4
Aliphatic Amines-acid
Daphnid
48-hr
LC50
171.555
Ampicillin
NA
69-53-4
Aliphatic Amines-acid
Green Algae
96-hr
EC50
160.497
Ampicillin
NA
69-53-4
Aliphatic Amines-acid
Fish
ChV
108.354
Ampicillin
NA
69-53-4
Aliphatic Amines-acid
Daphnid
ChV
13.249
Ampicillin
NA
69-53-4
Aliphatic Amines-acid
Green Algae
ChV
50.896
Ampicillin
NA
69-53-4
Amides -acid
Fish
96-hr
LC50
2565.781
Ampicillin
NA
69-53-4
Amides -acid
Daphnid
48-hr
LC50
3633.408
Ampicillin
NA
69-53-4
Amides -acid
Green Algae
96-hr
EC50
71.72
Ampicillin
NA
69-53-4
Amides -acid
Fish
ChV
3.179
Ampicillin
NA
69-53-4
Amides -acid
Daphnid
ChV
142.108
Ampicillin
NA
69-53-4
Amides -acid
Green Algae
ChV
53.503
Ampicillin
NA
69-53-4
Amides -acid
Fish (SW)
96-hr
LC50
2253.805
Ampicillin
NA
69-53-4
Amides -acid
Mysid (SW)
96-hr
LC50
119.974
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Fish
96-hr
LC50
2048.446
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Daphnid
48-hr
LC50
1044.258
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Green Algae
96-hr
EC50
498.123
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Fish
ChV
176.32
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Daphnid
ChV
75.442
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Green Algae
ChV
102.607
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Fish (SW)
96-hr
LC50
2560.879
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Mysid
96-hr
LC50
4197.276
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Fish (SW)
ChV
136.26
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Mysid (SW)
ChV
512.773
Bis(2-chloroethyl) phosphate
NA
3040-56-0
Neutral Organics
Earthworm
14-day
LC50
512.345
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Fish
96-hr
LC50
0.058
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Daphnid
48-hr
LC50
0.048
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Green Algae
96-hr
EC50
0.17
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Fish
ChV
0.009
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Daphnid
ChV
0.013
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Green Algae
ChV
0.103
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Fish (SW)
96-hr
LC50
0.075
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Mysid
96-hr
LC50
0.004
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Fish (SW)
ChV
0.098
Bis(2-ethylhexyl) phosphate
NA
298-07-7
Neutral Organics
Mysid (SW)
ChV
9.20E-05
Bis(2-ethylhexyl) phosphateb
NA
298-07-7
Neutral Organics
Earthworm
ChV
2.12E+02
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Fish
96-hr
LC50
3.875
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Daphnid
48-hr
LC50
2.639
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Green Algae
96-hr
EC50
4.174
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Fish
ChV
0.469
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Daphnid
ChV
0.427
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Green Algae
ChV
1.639
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Fish (SW)
96-hr
LC50
4.936
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Mysid
96-hr
LC50
0.965
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Fish (SW)
ChV
1.786
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
Neutral Organics
Mysid (SW)
ChV
0.046
Bis(2-methylphenyl) hydrogen phosphateb
NA
35787-74-7
Neutral Organics
Earthworm
14-day
LC50
302.11
Cresyl diphenyl phosphate (CDPP)b
NA
26444-49-5
Esters
Fish
96-hr
LC50
0.577
Cresyl diphenyl phosphate (CDPP)b
NA
26444-49-5
Esters
Daphnid
48-hr
LC50
0.847
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters
Green Algae
96-hr
EC50
0.216
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters
Fish
ChV
0.022
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters
Daphnid
ChV
0.228
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters
Green Algae
ChV
0.159
Cresyl diphenyl phosphate (CDPP)b
NA
26444-49-5
Esters
Fish (SW)
96-hr
LC50
0.719
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters
Mysid
96-hr
LC50
0.143
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters
Fish (SW)
ChV
0.185
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters
Mysid (SW)
ChV
0.014
E-18
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
Cresyl diphenyl phosphate (CDPP)b
NA
26444-49-5
Esters
Earthworm
14-day
LC50
398.073
Cresyl diphenyl phosphate (CDPP)b
NA
26444-49-5
Esters (phosphate)
Fish
96-hr
LC50
0.538
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters (phosphate)
Daphnid
48-hr
LC50
0.00079
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters (phosphate)
Green Algae
96-hr
EC50
0.869
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters (phosphate)
Fish
ChV
0.006
Cresyl diphenyl phosphate (CDPP)b
NA
26444-49-5
Esters (phosphate)
Green Algae
ChV
1.635
Cresyl diphenyl phosphate (CDPP)b
NA
26444-49-5
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.494
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.003
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters (phosphate)
Fish (SW)
ChV
0.015
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
Esters (phosphate)
Mysid (SW)
ChV
2.13E-05
Cyanuric acid
NA
108-80-5
Neutral Organics
Fish
96-hr
LC50
0.000218
Cyanuric acid
NA
108-80-5
Neutral Organics
Daphnid
48-hr
LC50
0.000235
Cyanuric acidb
NA
108-80-5
Neutral Organics
Green Algae
96-hr
EC50
0.002
Cyanuric acid
NA
108-80-5
Neutral Organics
Fish
ChV
4.53E-05
Cyanuric acid
NA
108-80-5
Neutral Organics
Daphnid
ChV
0.000135
Cyanuric acidb
NA
108-80-5
Neutral Organics
Green Algae
ChV
0.003
Cyanuric acidb
NA
108-80-5
Neutral Organics
Fish (SW)
96-hr
LC50
0.000287
Cyanuric acid
NA
108-80-5
Neutral Organics
Mysid
96-hr
LC50
1.97E-06
Cyanuric acidb
NA
108-80-5
Neutral Organics
Fish (SW)
ChV
0.002
Cyanuric acid
NA
108-80-5
Neutral Organics
Mysid (SW)
ChV
2.20E-08
Cyanuric acidb
NA
108-80-5
Neutral Organics
Earthworm
14-day
LC50
143.404
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish
96-hr
LC50
1.76E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Daphnid
48-hr
LC50
2.13E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Green Algae
96-hr
EC50
0.000364
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish
ChV
4.21E-06
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Daphnid
ChV
1.71E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Green Algae
ChV
0.000515
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish (SW)
96-hr
LC50
2.33E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Mysid
96-hr
LC50
6.69E-08
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish (SW)
ChV
0.000379
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Mysid (SW)
ChV
5.09E-10
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Earthworm
14-day
LC50
122.309
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish
96-hr
LC50
1.76E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Daphnid
48-hr
LC50
2.13E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Green Algae
96-hr
EC50
0.000364
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish
ChV
4.21E-06
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Daphnid
ChV
1.71E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Green Algae
ChV
0.000515
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish (SW)
96-hr
LC50
2.33E-05
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Mysid
96-hr
LC50
6.69E-08
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Fish (SW)
ChV
0.000379
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Mysid (SW)
ChV
5.09E-10
Decachlorobiphenylb
NA
2051-24-3
Neutral Organics
Earthworm
14-day
LC50
122.309
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Fish
96-hr
LC50
95.016
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Daphnid
48-hr
LC50
55.409
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Green Algae
96-hr
EC50
46.087
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Fish
ChV
9.584
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Daphnid
ChV
5.82
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Green Algae
ChV
12.808
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Fish (SW)
96-hr
LC50
119.825
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Mysid
96-hr
LC50
73.224
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Fish (SW)
ChV
15.515
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Mysid (SW)
ChV
5.81
Dibutyl ester phosphoric acid
NA
107-66-4
Neutral Organics
Earthworm
14-day
LC50
341.114
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Fish
96-hr
LC50
0.337
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Daphnid
48-hr
LC50
0.253
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Green Algae
96-hr
EC50
0.604
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Fish
ChV
0.046
E-19
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Daphnid
ChV
0.054
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Green Algae
ChV
0.296
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Fish (SW)
96-hr
LC50
0.432
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Mysid
96-hr
LC50
0.041
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Fish (SW)
ChV
0.301
Dichlorobiphenyl
NA
25512-42-9
Neutral Organics
Mysid (SW)
ChV
0.00143
Dichlorobiphenyl11
NA
25512-42-9
Neutral Organics
Earthworm
14-day
LC50
187.428
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Fish
96-hr
LC50
4047.436
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Daphnid
48-hr
LC50
1968.758
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Green Algae
96-hr
EC50
773.561
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Fish
ChV
329.632
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Daphnid
ChV
124.826
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Green Algae
ChV
143.54
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Fish (SW)
96-hr
LC50
5044.564
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Mysid
96-hr
LC50
11664.221
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Fish (SW)
ChV
196.825
Diethyl hydrogen phosphate
NA
598-02-7
Neutral Organics
Mysid (SW)
ChV
1656.504
Diethyl hydrogen phosphateb
NA
598-02-7
Neutral Organics
Earthworm
14-day
LC50
399.726
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Fish
96-hr
LC50
128.771
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Daphnid
48-hr
LC50
74.081
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Green Algae
96-hr
EC50
58.255
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Fish
ChV
12.783
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Daphnid
ChV
7.493
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Green Algae
ChV
15.707
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Fish (SW)
96-hr
LC50
162.251
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Mysid
96-hr
LC50
109.532
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Fish (SW)
ChV
19.205
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Mysid (SW)
ChV
9.078
Diisobutyl hydrogen phosphate
NA
6303-30-6
Neutral Organics
Earthworm
14-day
LC50
353.299
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Fish
96-hr
LC50
33.508
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Daphnid
48-hr
LC50
20.631
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Green Algae
96-hr
EC50
21.481
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Fish
ChV
3.604
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Daphnid
ChV
2.521
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Green Algae
ChV
6.737
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Fish (SW)
96-hr
LC50
42.406
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Mysid
96-hr
LC50
17.398
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Fish (SW)
ChV
7.864
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Mysid (SW)
ChV
1.16
Diphenyl phosphate (DPHP)
NA
838-85-7
Neutral Organics
Earthworm
14-day
LC50
352.792
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Fish
96-hr
LC50
627.626
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Daphnid
48-hr
LC50
334.272
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Green Algae
96-hr
EC50
191.096
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Fish
ChV
56.886
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Daphnid
ChV
56.886
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Green Algae
ChV
43.395
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Fish (SW)
96-hr
LC50
786.862
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Mysid
96-hr
LC50
935.335
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Fish (SW)
ChV
55.929
Dipropyl ester phosphoric acid
NA
1804-93-9
Neutral Organics
Mysid (SW)
ChV
99.288
Dipropyl ester phosphoric acid
1804-93-9
Neutral Organics
Earthworm
14-day
LC50
373.718
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Fish
96-hr
LC50
0.000762
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Daphnid
48-hr
LC50
0.000772
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Green Algae
96-hr
EC50
0.006
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Fish
ChV
0.000147
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Daphnid
ChV
0.000377
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Green Algae
ChV
0.006
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Fish (SW)
96-hr
LC50
0.000996
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Mysid
96-hr
LC50
1.06E-05
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Fish (SW)
ChV
0.005
E-20
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Mysid (SW)
ChV
1.43E-07
Heptachlorobiphenyl
NA
28655-71-2
Neutral Organics
Earthworm
14-day
LC50
153.856
Hexachlorobiphenylb
NA
26601-64-9
Neutral Organics
Fish
96-hr
LC50
0.003
Hexachlorobiphenylb
NA
26601-64-9
Neutral Organics
Daphnid
48-hr
LC50
0.003
Hexachlorobiphenylb
NA
26601-64-9
Neutral Organics
Green Algae
96-hr
EC50
0.016
Hexachlorobiphenyl
NA
26601-64-9
Neutral Organics
Fish
ChV
0.000476
Hexachlorobiphenylb
NA
26601-64-9
Neutral Organics
Daphnid
ChV
0.00104
Hexachlorobiphenylb
NA
26601-64-9
Neutral Organics
Green Algae
ChV
0.013
Hexachlorobiphenylb
NA
26601-64-9
Neutral Organics
Fish (SW)
96-hr
LC50
0.003
Hexachlorobiphenyl
NA
26601-64-9
Neutral Organics
Mysid
96-hr
LC50
5.65E-05
Hexachlorobiphenylb
NA
26601-64-9
Neutral Organics
Fish (SW)
ChV
0.012
Hexachlorobiphenyl
NA
26601-64-9
Neutral Organics
Mysid (SW)
ChV
9.23E-07
Hexachlorobiphenyl11
NA
26601-64-9
Neutral Organics
Earthworm
14-day
LC50
163.817
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Fish
96-hr
LC50
0.043
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Daphnid
48-hr
LC50
0.051
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Green Algae
96-hr
EC50
0.009
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Fish
ChV
0.00107
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Daphnid
ChV
0.008
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Green Algae
ChV
0.013
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Fish (SW)
96-hr
LC50
0.047
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Mysid
96-hr
LC50
0.003
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Fish (SW)
ChV
0.018
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters
Mysid (SW)
ChV
5.41E-06
Isodecyl diphenyl phosphate (IDDP)b
NA
29761-21-5
Esters
Earthworm
14-day
LC50
101.074
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Fish
96-hr
LC50
0.12
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Daphnid
48-hr
LC50
0.000152
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Green Algae
96-hr
EC50
0.004
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Fish
ChV
0.004
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Green Algae
ChV
0.109
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.207
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.00108
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Fish (SW)
ChV
0.005
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
Esters (phosphate)
Mysid (SW)
ChV
4.86E-06
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Fish
96-hr
LC50
2680.134
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Daphnid
48-hr
LC50
6.226
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Green Algae
96-hr
EC50
2.785
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Fish
ChV
263.18
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Daphnid
ChV
0.078
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Green Algae
ChV
0.697
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Fish
96-hr
LC50
390.883
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Daphnid
48-hr
LC50
144.341
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Green Algae
96-hr
EC50
325.036
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Fish
ChV
1102.257
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Daphnid
ChV
14.845
Melamine
NA
108-78-1
ilines (amino-meta)
melamin
Green Algae
ChV
81.258
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Fish
96-hr
LC50
1.08
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Daphnid
48-hr
LC50
0.766
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Green Algae
96-hr
EC50
1.426
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Fish
ChV
0.137
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Daphnid
ChV
0.138
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Green Algae
ChV
0.612
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Fish (SW)
96-hr
LC50
1.38
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Mysid
96-hr
LC50
0.202
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Fish (SW)
ChV
0.649
Monochlorobiphenyl
NA
27323-18-8
Neutral Organics
Mysid (SW)
ChV
0.009
Monochlorobiphenyl11
NA
27323-18-8
Neutral Organics
Earthworm
14-day
LC50
184.859
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Fish
96-hr
LC50
4420.071
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Daphnid
48-hr
LC50
3285.149
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Green Algae
96-hr
EC50
1804.829
E-21
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Fish
ChV
1538.409
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Daphnid
ChV
465.658
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Green Algae
ChV
499.939
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Fish (SW)
96-hr
LC50
78675.867
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Mysid (SW)
96-hr
LC50
2745.547
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Fish (SW)
ChV
12245.601
Nalidixic acid
NA
389-08-2
Vinyl/Allyl Ketones-acid
Mysid (SW)
ChV
422.439
Nonachlorobiphenylb
NA
53742-07-7
Neutra
Organics
Fish
96-hr
LC50
6.22E-05
Nonachlorobiphenylb
NA
53742-07-7
Neutra
Organics
Daphnid
48-hr
LC50
7.10E-05
Nonachlorobiphenylb
NA
53742-07-7
Neutra
Organics
Green Algae
96-hr
EC50
0.000947
Nonachlorobiphenyl
NA
53742-07-7
Neutra
Organics
Fish
ChV
1.39E-05
Nonachlorobiphenylb
NA
53742-07-7
Neutra
Organics
Daphnid
ChV
4.83E-05
Nonachlorobiphenyl13
NA
53742-07-7
Neutra
Organics
Green Algae
ChV
0.00117
Nonachlorobiphenyl13
NA
53742-07-7
Neutra
Organics
Fish (SW)
96-hr
LC50
8.20E-05
Nonachlorobiphenyl
NA
53742-07-7
Neutra
Organics
Mysid
96-hr
LC50
3.64E-07
Nonachlorobiphenyl13
NA
53742-07-7
Neutra
Organics
Fish (SW)
ChV
0.000898
Nonachlorobiphenyl
NA
53742-07-7
Neutra
Organics
Mysid (SW)
ChV
3.35E-09
Nonachlorobiphenyl13
NA
53742-07-7
Neutra
Organics
Earthworm
14-day
LC50
132.803
Octachlorobiphenyl
NA
55722-26-4
Neutra
Organics
Fish
96-hr
LC50
0.000218
Octachlorobiphenyl
NA
55722-26-4
Neutra
Organics
Daphnid
48-hr
LC50
0.000235
Octachlorobiphenyl13
NA
55722-26-4
Neutra
Organics
Green Algae
96-hr
EC50
0.002
Octachlorobiphenyl
NA
55722-26-4
Neutra
Organics
Fish
ChV
4.53E-05
Octachlorobiphenyl
NA
55722-26-4
Neutra
Organics
Daphnid
ChV
0.000135
Octachlorobiphenyl13
NA
55722-26-4
Neutra
Organics
Green Algae
ChV
0.003
Octachlorobiphenyl13
NA
55722-26-4
Neutra
Organics
Fish (SW)
96-hr
LC50
0.000287
Octachlorobiphenyl
NA
55722-26-4
Neutra
Organics
Mysid
96-hr
LC50
1.97E-06
Octachlorobiphenyl13
NA
55722-26-4
Neutra
Organics
Fish (SW)
ChV
0.002
Octachlorobiphenyl
NA
55722-26-4
Neutra
Organics
Mysid (SW)
ChV
2.20E-08
Octachlorobiphenyl13
NA
55722-26-4
Neutra
Organics
Earthworm
14-day
LC50
143.404
Pentachlorobiphenyl
NA
25429-29-2
Neutra
Organics
Fish
96-hr
LC50
0.009
Pentachlorobiphenyl
NA
25429-29-2
Neutra
Organics
Daphnid
48-hr
LC50
0.008
Pentachlorobiphenyl13
NA
25429-29-2
Neutra
Organics
Green Algae
96-hr
EC50
0.041
Pentachlorobiphenyl
NA
25429-29-2
Neutra
Organics
Fish
ChV
0.00152
Pentachlorobiphenyl
NA
25429-29-2
Neutra
Organics
Daphnid
ChV
0.003
Pentachlorobiphenyl13
NA
25429-29-2
Neutra
Organics
Green Algae
ChV
0.03
Pentachlorobiphenyl
NA
25429-29-2
Neutra
Organics
Fish (SW)
96-hr
LC50
0.012
Pentachlorobiphenyl
NA
25429-29-2
Neutra
Organics
Mysid
96-hr
LC50
0.000299
Pentachlorobiphenyl13
NA
25429-29-2
Neutra
Organics
Fish (SW)
ChV
0.027
Pentachlorobiphenyl
NA
25429-29-2
Neutra
Organics
Mysid (SW)
ChV
5.91E-06
Pentachlorobiphenyl13
NA
25429-29-2
Neutra
Organics
Earthworm
14-day
LC50
172.833
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Fish
96-hr
LC50
3597.024
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Daphnid
48-hr
LC50
2008.247
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Green Algae
96-hr
EC50
1395.165
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Fish
ChV
344.669
Perfluorobutanesulfonic acid (PFBS)
NA
375-73-5
Neutral Organics-acid
Daphnid
ChV
186.865
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Green Algae
ChV
351.893
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Fish (SW)
96-hr
LC50
4523.436
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Mysid
96-hr
LC50
3804.685
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Fish (SW)
ChV
439.153
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Mysid (SW)
ChV
347.162
Perfluorobutanesulfonic acid (PFBS)b
NA
375-73-5
Neutral Organics-acid
Earthworm
14-day
LC50
5450.125
Perfluorotridecanoic acid (PFTrDA)
NA
72629-94-8
Neutral Organics-acid
Fish
96-hr
LC50
0.016
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Daphnid
48-hr
LC50
0.016
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Green Algae
96-hr
EC50
0.126
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Fish
ChV
0.003
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Daphnid
ChV
0.008
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Green Algae
ChV
0.117
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Fish (SW)
96-hr
LC50
0.021
E-22
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Mysid
96-hr
LC50
0.00024
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Fish (SW)
ChV
0.098
Perfluorotridecanoic acid (PFTrDA)
NA
72629-94-8
Neutral Organics-acid
Mysid (SW)
ChV
3.34E-06
Perfluorotridecanoic acid (PFTrDA)b
NA
72629-94-8
Neutral Organics-acid
Earthworm
14-day
LC50
2652.713
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Fish
96-hr
LC50
0.031
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Daphnid
48-hr
LC50
0.026
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Green Algae
96-hr
EC50
0.101
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Fish
ChV
0.005
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Daphnid
ChV
0.008
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Green Algae
ChV
0.065
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Mysid
96-hr
LC50
0.00156
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Fish (SW)
ChV
0.061
Polychlorinated biphenyl (PCB)
NA
1336-36-3
Neutral Organics
Mysid (SW)
ChV
3.74E-05
Polychlorinated biphenyl (PCB)b
NA
1336-36-3
Neutral Organics
Earthworm
14-day
LC50
180.316
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Fish
96-hr
LC50
0.053
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Daphnid
48-hr
LC50
0.062
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Green Algae
96-hr
EC50
0.011
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Fish
ChV
0.00129
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Daphnid
ChV
0.009
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Green Algae
ChV
0.017
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Fish (SW)
96-hr
LC50
0.058
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Mysid
96-hr
LC50
0.004
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Fish (SW)
ChV
0.022
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Mysid (SW)
ChV
4.79E-06
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters
Earthworm
14-day
LC50
135.164
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Fish
96-hr
LC50
0.159
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Daphnid
48-hr
LC50
0.0002
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Green Algae
96-hr
EC50
0.004
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Fish
ChV
0.005
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Green Algae
ChV
0.134
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.285
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.00148
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
Esters (phosphate)
Fish (SW)
ChV
0.006
Sulfate
NA
14808-79-8
Inorganic Compound
Fish
96-hr
LC50
4.77E+05
Sulfate
NA
14808-79-8
Inorganic Compound
Daphnid
48-hr
LC50
1.84E+05
Sulfate
NA
14808-79-8
Inorganic Compound
Green Algae
96-hr
EC50
27531.549
Sulfate
NA
14808-79-8
Inorganic Compound
Fish
ChV
29497.303
Sulfate
NA
14808-79-8
Inorganic Compound
Daphnid
ChV
6088.096
Sulfate
NA
14808-79-8
Inorganic Compound
Green Algae
ChV
3039.855
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Fish
96-hr
LC50
0.104
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Daphnid
48-hr
LC50
0.132
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Green Algae
96-hr
EC50
0.027
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Fish
ChV
0.003
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Daphnid
ChV
0.024
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Green Algae
ChV
0.031
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Fish (SW)
96-hr
LC50
0.119
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Mysid
96-hr
LC50
0.012
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Fish (SW)
ChV
0.039
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters
Mysid (SW)
ChV
7.39E-05
Tert-butylphenyl diphenyl phosphateb
NA
56803-37-3
Esters
Earthworm
14-day
LC50
162.713
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Fish
96-hr
LC50
0.201
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Daphnid
48-hr
LC50
0.000269
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Green Algae
96-hr
EC50
0.023
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Fish
ChV
0.005
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Green Algae
ChV
0.273
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.282
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.00156
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Fish (SW)
ChV
0.007
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
Esters (phosphate)
Mysid (SW)
ChV
8.10E-06
E-23
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
Tetrabutyl ethylidenebisphenol (A022E46)b
NA
35958-30-6
Phenols, Poly
Fish
96-hr
LC50
0.00133
Tetrabutyl ethylidenebisphenol (A022E46)b
NA
35958-30-6
Phenols, Poly
Daphnid
48-hr
LC50
0.000615
Tetrabutyl ethylidenebisphenol (A022E46)b
NA
35958-30-6
Phenols, Poly
Green Algae
96-hr
EC50
0.036
Tetrabutyl ethylidenebisphenol (A022E46)b
NA
35958-30-6
Phenols, Poly
Fish
ChV
0.000248
Tetrabutyl ethylidenebisphenol (A022E46)b
NA
35958-30-6
Phenols, Poly
Daphnid
ChV
0.000149
Tetrabutyl ethylidenebisphenol (A022E46)b
NA
35958-30-6
Phenols, Poly
Green Algae
ChV
0.014
Tetrachlorobiphenylb
NA
26914-33-0
Neutral Organics
Fish
96-hr
LC50
0.031
Tetrachlorobiphenylb
NA
26914-33-0
Neutral Organics
Daphnid
48-hr
LC50
0.026
Tetrachlorobiphenylb
NA
26914-33-0
Neutral Organics
Green Algae
96-hr
EC50
0.101
Tetrachlorobiphenyl
NA
26914-33-0
Neutral Organics
Fish
ChV
0.005
Tetrachlorobiphenyl
NA
26914-33-0
Neutral Organics
Daphnid
ChV
0.008
Tetrachlorobiphenylb
NA
26914-33-0
Neutral Organics
Green Algae
ChV
0.065
Tetrachlorobiphenyl11
NA
26914-33-0
Neutral Organics
Fish (SW)
96-hr
LC50
0.04
Tetrachlorobiphenyl
NA
26914-33-0
Neutral Organics
Mysid
96-hr
LC50
0.00156
Tetrachlorobiphenyl11
NA
26914-33-0
Neutral Organics
Fish (SW)
ChV
0.061
Tetrachlorobiphenyl
NA
26914-33-0
Neutral Organics
Mysid (SW)
ChV
3.74E-05
Tetrachlorobiphenyl11
NA
26914-33-0
Neutral Organics
Earthworm
14-day
LC50
180.316
Tr
butyl phosphate
NA
126-73-8
Esters
Fish
96-hr
LC50
3.088
Tr
butyl phosphate
NA
126-73-8
Esters
Daphnid
48-hr
LC50
5.283
Tr
butyl phosphate
NA
126-73-8
Esters
Green Algae
96-hr
EC50
1.686
Tr
butyl phosphate
NA
126-73-8
Esters
Fish
ChV
0.159
Tr
butyl phosphate
NA
126-73-8
Esters
Daphnid
ChV
2.141
Tr
butyl phosphate
NA
126-73-8
Esters
Green Algae
ChV
0.78
Tr
butyl phosphate
NA
126-73-8
Esters
Fish (SW)
96-hr
LC50
4.202
Tr
butyl phosphate
NA
126-73-8
Esters
Mysid
96-hr
LC50
1.687
Tr
butyl phosphate
NA
126-73-8
Esters
Fish (SW)
ChV
0.836
Tr
butyl phosphate
NA
126-73-8
Esters
Mysid (SW)
ChV
3.052
Tr
butyl phosphate11
NA
126-73-8
Esters
Earthworm
14-day
LC50
900.295
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Fish
96-hr
LC50
1.333
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Daphnid
48-hr
LC50
0.002
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Green Algae
96-hr
EC50
34.75
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Fish
ChV
0.007
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Green Algae
ChV
9.461
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.788
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.005
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Fish (SW)
ChV
0.031
Tr
butyl phosphate
NA
126-73-8
Esters (phosphate)
Mysid (SW)
ChV
5.19E-05
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Fish
96-hr
LC50
0.103
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Daphnid
48-hr
LC50
0.082
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Green Algae
96-hr
EC50
0.25
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Fish
ChV
0.015
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Daphnid
ChV
0.021
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Green Algae
ChV
0.14
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Fish (SW)
96-hr
LC50
0.132
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Mysid
96-hr
LC50
0.008
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Fish (SW)
ChV
0.136
Tr
chlorobiphenyl
NA
25323-68-6
Neutral Organics
Mysid (SW)
ChV
2.33E-04
Tr
chlorobiphenyl11
NA
25323-68-6
Neutral Organics
Earthworm
14-day
LC50
185.504
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Fish
96-hr
LC50
111.039
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Daphnid
48-hr
LC50
260.46
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Green Algae
96-hr
EC50
132.547
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Fish
ChV
10.585
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Daphnid
ChV
246.358
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Green Algae
ChV
23.555
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Fish (SW)
96-hr
LC50
181.004
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Mysid
96-hr
LC50
310.416
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Fish (SW)
ChV
21.177
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Mysid (SW)
ChV
2.28E+05
Tr
ethyl phosphate (TEP)
NA
78-40-0
Esters
Earthworm
14-day
LC50
5487.976
E-24
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Predicted
PCB
Organism -
Duration -
Endpoint-
value-
Chemical
congener #
CAS number
Chemical class - ECOSAR
ECOSAR
ECOSAR
ECOSAR
ECOSAR
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Fish
96-hr
LC50
9.829
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Daphnid
48-hr
LC50
0.02
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Green Algae
96-hr
EC50
78973.203
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Fish
ChV
0.012
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Green Algae
ChV
399.591
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Fish (SW)
96-hr
LC50
2.333
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.02
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Fish (SW)
ChV
0.148
Triethyl phosphate (TEP)
NA
78-40-0
Esters (phosphate)
Mysid (SW)
ChV
0.000368
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Fish
96-hr
LC50
0.019
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Daphnid
48-hr
LC50
0.02
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Green Algae
96-hr
EC50
0.003
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Fish
ChV
0.00038
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Daphnid
ChV
0.002
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Green Algae
ChV
0.006
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Fish (SW)
96-hr
LC50
0.019
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Mysid
96-hr
LC50
0.000894
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Fish (SW)
ChV
0.008
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
methylphenyl)propionate (AO-245)
NA
36443-68-2
Esters
Mysid (SW)
ChV
2.11E-07
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Esters
Earthworm
14-day
LC50
76.301
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Phenols, Poly
Fish
96-hr
LC50
0.006
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Phenols, Poly
Daphnid
48-hr
LC50
0.004
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Phenols, Poly
Green Algae
96-hr
EC50
0.098
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Phenols, Poly
Fish
ChV
0.00135
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Phenols, Poly
Daphnid
ChV
0.00108
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
36443-68-2
methylphenyl)propionate (AO-245)b
NA
Phenols, Poly
Green Algae
ChV
0.033
Triisobutyl phosphate
NA
126-71-6
Esters
Fish
96-hr
LC50
0.15
Triisobutyl phosphate
NA
126-71-6
Esters
Daphnid
48-hr
LC50
0.197
Triisobutyl phosphate
NA
126-71-6
Esters
Green Algae
96-hr
EC50
0.042
Triisobutyl phosphate
NA
126-71-6
Esters
Fish
ChV
0.005
Triisobutyl phosphate
NA
126-71-6
Esters
Daphnid
ChV
0.039
Triisobutyl phosphate
NA
126-71-6
Esters
Green Algae
ChV
0.044
Triisobutyl phosphate
NA
126-71-6
Esters
Fish (SW)
96-hr
LC50
0.175
Triisobutyl phosphate
NA
126-71-6
Esters
Mysid
96-hr
LC50
0.021
Triisobutyl phosphate
NA
126-71-6
Esters
Fish (SW)
ChV
0.054
Triisobutyl phosphate
NA
126-71-6
Esters
Mysid (SW)
ChV
0.00024
Triisobutyl phosphateb
NA
126-71-6
Esters
Earthworm
14-day
LC50
194.499
Triisobutyl phosphate
NA
126-71-6
Esters (phosphate)
Fish
96-hr
LC50
0.246
Triisobutyl phosphate
NA
126-71-6
Esters (phosphate)
Daphnid
48-hr
LC50
0.000335
Triisobutyl phosphate
NA
126-71-6
Esters (phosphate)
Green Algae
96-hr
EC50
0.052
Triisobutyl phosphate
NA
126-71-6
Esters (phosphate)
Fish
ChV
0.005
Triisobutyl phosphate
NA
126-71-6
Esters (phosphate)
Green Algae
ChV
0.401
Triisobutyl phosphate
NA
126-71-6
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.312
E-25
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Predicted
PCB
Organism -
Duration -
Endpoint-
value-
Chemical
congener #
CAS number
Chemical class - ECOSAR
ECOSAR
ECOSAR
ECOSAR
ECOSAR
Tr
isobutyl phosphate
NA
126-71-6
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.00176
Tr
isobutyl phosphate
NA
126-71-6
Esters (phosphate)
Fish (SW)
ChV
0.008
Tr
isobutyl phosphate
NA
126-71-6
Esters (phosphate)
Mysid (SW)
ChV
9.86E-06
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Fish
96-hr
LC50
619.156
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Daphnid
48-hr
LC50
1700.493
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Green Algae
96-hr
EC50
1092.861
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Fish
ChV
80.42
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Daphnid
ChV
2457.053
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Green Algae
ChV
120.376
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Fish (SW)
96-hr
LC50
1104.594
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Mysid
96-hr
LC50
3915.122
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Fish (SW)
ChV
99.119
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Mysid (SW)
ChV
5.78E+07
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters
Earthworm
14-day
LC50
12598.584
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Fish
96-hr
LC50
24.812
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Daphnid
48-hr
LC50
0.055
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Green Algae
96-hr
EC50
3.50E+06
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Fish
ChV
0.014
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Green Algae
ChV
2414.672
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Fish (SW)
96-hr
LC50
3.733
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.035
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Fish (SW)
ChV
0.302
Tr
methyl phosphate (TMP)
NA
512-56-1
Esters (phosphate)
Mysid (SW)
ChV
0.000913
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Fish
96-hr
LC50
436.615
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Daphnid
48-hr
LC50
229.036
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Green Algae
96-hr
EC50
122.97
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Fish
ChV
38.871
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Daphnid
ChV
17.918
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Green Algae
ChV
26.996
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Fish (SW)
96-hr
LC50
546.85
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Mysid
96-hr
LC50
726.614
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Fish (SW)
ChV
35.157
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Mysid (SW)
ChV
80.982
Tr
methylsilanol (TMS)
NA
1066-40-6
Neutral Organics
Earthworm
14-day
LC50
192.46
Tr
oropyl phosphate
NA
513-08-6
Esters
Fish
96-hr
LC50
18.851
Tr
propyl phosphate
NA
513-08-6
Esters
Daphnid
48-hr
LC50
37.765
Tr
propyl phosphate
NA
513-08-6
Esters
Green Algae
96-hr
EC50
15.218
Tr
propyl phosphate
NA
513-08-6
Esters
Fish
ChV
1.319
Tr
oropyl phosphate
NA
513-08-6
Esters
Daphnid
ChV
23.383
Tr
oropyl phosphate
NA
513-08-6
Esters
Green Algae
ChV
4.363
Tr
oropyl phosphate
NA
513-08-6
Esters
Fish (SW)
96-hr
LC50
28.077
Tr
oropyl phosphate
NA
513-08-6
Esters
Mysid
96-hr
LC50
23.298
Tr
oropyl phosphate
NA
513-08-6
Esters
Fish (SW)
ChV
4.283
Tr
oropyl phosphate
NA
513-08-6
Esters
Mysid (SW)
ChV
848.721
Tr
oropyl phosphate
NA
513-08-6
Esters
Earthworm
14-day
LC50
2262.996
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Fish
96-hr
LC50
3.686
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Daphnid
48-hr
LC50
0.007
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Green Algae
96-hr
EC50
1686.563
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Fish
ChV
0.01
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Green Algae
ChV
62.597
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Fish (SW)
96-hr
LC50
1.38
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.01
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Fish (SW)
ChV
0.068
Tr
oropyl phosphate
NA
513-08-6
Esters (phosphate)
Mysid (SW)
ChV
0.000141
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters
Fish
96-hr
LC50
6.277
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)b
NA
13674-87-8
Esters
Daphnid
48-hr
LC50
10.937
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters
Green Algae
96-hr
EC50
3.585
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters
Fish
ChV
0.334
Tr
s( 1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters
Daphnid
ChV
4.655
Tr
s( 1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters
Green Algae
ChV
1.569
E-26
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Predicted
PCB
Organism -
Duration -
Endpoint-
value-
Chemical
congener #
CAS number
Chemical class - ECOSAR
ECOSAR
ECOSAR
ECOSAR
ECOSAR
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)b
NA
13674-87-8
Esters
Fish (SW)
96-hr
LC50
8.632
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters
Mysid
96-hr
LC50
3.768
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters
Fish (SW)
ChV
1.665
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)b
NA
13674-87-8
Esters
Mysid (SW)
ChV
9.635
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)b
NA
13674-87-8
Esters
Earthworm
14-day
LC50
1652.378
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters (phosphate)
Fish
96-hr
LC50
2.474
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters (phosphate)
Daphnid
48-hr
LC50
0.004
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)b
NA
13674-87-8
Esters (phosphate)
Green Algae
96-hr
EC50
89.715
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters (phosphate)
Fish
ChV
0.012
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)b
NA
13674-87-8
Esters (phosphate)
Green Algae
ChV
19.413
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters (phosphate)
Fish (SW)
96-hr
LC50
1.387
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.01
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters (phosphate)
Fish (SW)
ChV
0.055
Tr
s(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
Esters (phosphate)
Mysid (SW)
ChV
9.60E-05
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Fish
96-hr
LC50
13.295
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Daphnid
48-hr
LC50
25.135
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Green Algae
96-hr
EC50
9.296
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Fish
ChV
0.83
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Daphnid
ChV
13.318
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Green Algae
ChV
3.177
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Fish (SW)
96-hr
LC50
19.156
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Mysid
96-hr
LC50
12.173
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Fish (SW)
ChV
3.221
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Mysid (SW)
ChV
147.082
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters
Earthworm
14-day
LC50
2211.578
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Fish
96-hr
LC50
3.478
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Daphnid
48-hr
LC50
0.006
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Green Algae
96-hr
EC50
555.206
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Fish
ChV
0.012
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Green Algae
ChV
42.863
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Fish (SW)
96-hr
LC50
1.54
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.011
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Fish (SW)
ChV
0.07
Tr
s(2-chloroisopropyl) phosphate
NA
13674-84-5
Esters (phosphate)
Mysid (SW)
ChV
0.000134
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Fish
96-hr
LC50
0.002
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Daphnid
48-hr
LC50
0.002
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Green Algae
96-hr
EC50
0.000297
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Fish
ChV
3.82E-05
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Daphnid
ChV
0.000181
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Green Algae
ChV
0.000866
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Fish (SW)
96-hr
LC50
0.002
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Mysid
96-hr
LC50
5.78E-05
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Fish (SW)
ChV
0.0013
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters
Mysid (SW)
ChV
9.97E-10
Tr
s(2-ethylhexyl) phosphate (TEHP)b
NA
78-42-2
Esters
Earthworm
14-day
LC50
21.789
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Fish
96-hr
LC50
0.022
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Daphnid
48-hr
LC50
2.44E-05
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Green Algae
96-hr
EC50
9.42E-06
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Fish
ChV
0.002
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Green Algae
ChV
0.006
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.077
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.000341
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Fish (SW)
ChV
0.00116
Tr
s(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
Esters (phosphate)
Mysid (SW)
ChV
9.34E-07
Tr
s(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Fish
96-hr
LC50
0.00079
Tr
s(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Daphnid
48-hr
LC50
0.000666
Tr
s(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Green Algae
96-hr
EC50
7.46E-05
Tr
s(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Fish
ChV
1.01E-05
Tr
s(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Daphnid
ChV
4.03E-05
E-27
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table E-3. ECOSAR Values from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener #
CAS number
Chemical class - ECOSAR
Organism -
ECOSAR
Duration -
ECOSAR
Endpoint-
ECOSAR
Predicted
value-
ECOSAR
Tris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Green Algae
ChV
0.000295
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Fish (SW)
96-hr
LC50
0.000717
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Mysid
96-hr
LC50
1.11E-05
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Fish (SW)
ChV
0.000469
T ris(4-tert-butylphenyl) phosphate
NA
78-33-1
Esters
Mysid (SW)
ChV
2.82E-11
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters
Earthworm
14-day
LC50
12.357
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters (phosphate)
Fish
96-hr
LC50
0.012
T ris(4-tert-butylphenyl) phosphate
NA
78-33-1
Esters (phosphate)
Daphnid
48-hr
LC50
1.22E-05
T ris(4-tert-butylphenyl) phosphate
NA
78-33-1
Esters (phosphate)
Green Algae
96-hr
EC50
8.11E-07
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters (phosphate)
Fish
ChV
0.0019
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters (phosphate)
Green Algae
ChV
0.00169
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.055
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.000227
T ris(4-tert-butylphenyl) phosphateb
NA
78-33-1
Esters (phosphate)
Fish (SW)
ChV
0.000706
T ris(4-tert-butylphenyl) phosphate
NA
78-33-1
Esters (phosphate)
Mysid (SW)
ChV
5.05E-07
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Fish
96-hr
LC50
0.143
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Daphnid
48-hr
LC50
0.187
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Green Algae
96-hr
EC50
0.04
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Fish
ChV
0.004
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Daphnid
ChV
0.037
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Green Algae
ChV
0.042
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Fish (SW)
96-hr
LC50
0.167
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Mysid
96-hr
LC50
0.019
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Fish (SW)
ChV
0.052
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters
Mysid (SW)
ChV
0.000204
Tris(methylphenyl) phosphateb
NA
1330-78-5
Esters
Earthworm
14-day
LC50
191.19
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Fish
96-hr
LC50
0.241
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Daphnid
48-hr
LC50
0.000327
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Green Algae
96-hr
EC50
0.046
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Fish
ChV
0.005
Tris(methylphenyl) phosphateb
NA
1330-78-5
Esters (phosphate)
Green Algae
ChV
0.383
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Fish (SW)
96-hr
LC50
0.311
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Mysid (SW)
96-hr
LC50
0.00175
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Fish (SW)
ChV
0.008
Tris(methylphenyl) phosphate
NA
1330-78-5
Esters (phosphate)
Mysid (SW)
ChV
9.66E-06
Notes
CAS = Chemical Abstracts Service
NA= Not applicable
SW= Saltwater
8 = Inorganic compound, outside of EPISuite estimation domain.
b = Chemical may not be soluble enough to measure ECOSAR predicted effect.
E-28
-------
Biosolids Biennial Review Reporting Period 2018-2019
Appendix F. Environmental Fate and Transport Data: Bioaccumulation
and Bioconcentration Data
F-l
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
5.57
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
6.45
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
6.22
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
6.35
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
6.40
BAF
Osmerus mordax
Rainbow smelt
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
6.71
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
6.87
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
6.93
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
7.30
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,3',4,4',5-Heptachlorobiphenyl
35065-30-6
7.49
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,3',4,4'-Hexachlorobiphenyl
38380-07-3
5.77
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.82
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.85
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.99
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.95
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.18
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.25
BAF
Stizostedion vitreum
Walleye
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.59
BAF
Pomoxis nigromacuiatus
Black crappie
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.21
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.10
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.90
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.60
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.98
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.43
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.90
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.37
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.51
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.84
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
6.37
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
5.49
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
40186-71-8
4.70
BAF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
5.56
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
4.91
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
4.27
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
5.97
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
5.91
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
F-2
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
6.29
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
4.80
BAF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,3',6,6'-Hexachlorobiphenyl
38411-22-2
5.43
BAF
Danio rerio
Zebra danio
Arnot & Gobas 2006
2,2',3,4,4',5,5',6-Octachlorobiphenyl
52663-76-0
6.40
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',3,4,4',5,5',6-Octachlorobiphenyl
52663-76-0
6.73
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',3,4,4',5,5',6-Octachlorobiphenyl
52663-76-0
6.66
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4',5,5',6-Octachlorobiphenyl
52663-76-0
7.05
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,4',5,5',6-Octachlorobiphenyl
52663-76-0
7.30
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.21
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.29
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.58
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.44
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.63
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.25
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
5.61
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
5.17
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
5.51
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.45
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.15
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.28
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.40
BAF
Osmems mordax
Rainbow smelt
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.01
BAF
Pomoxis nigromaculatus
Black crappie
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.58
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.45
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.26
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.73
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.35
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.77
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
7.33
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.81
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.65
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.44
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.81
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.79
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.03
BAF
Osmems mordax
Smelt (small)
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.31
BAF
Osmems mordax
Smelt (large)
Arnot & Gobas 2006
F-3
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.25
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.61
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
6.87
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
5.57
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
4.47
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
4.48
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,4,4',5,5'-Heptachlorobiphenyl
35065-29-3
4.58
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.92
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.00
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.31
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.12
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.31
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.97
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.76
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.04
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.45
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.45
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.13
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.32
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.42
BAF
Osmems mordax
Rainbow smelt
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.43
BAF
Stizostedion vitreum
Walleye
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.77
BAF
Pomoxis nigromaculatus
Black crappie
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.36
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.13
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.87
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.61
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.06
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.38
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
7.00
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.60
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.55
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.23
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.60
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.48
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.10
BAF
Osmems mordax
Smelt (small)
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.45
BAF
Osmems mordax
Smelt (large)
Arnot & Gobas 2006
F-4
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.37
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.59
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
6.97
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
5.34
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,4,4',5'-Hexachlorobiphenyl
35065-28-2
4.63
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
5.94
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
5.67
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
5.23
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
5.87
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
6.31
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
6.37
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
6.26
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
6.79
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,4,4'-Pentachlorobiphenyl
65510-45-4
4.93
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.03
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.06
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.71
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.18
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.27
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
4.99
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.12
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.74
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.82
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.11
BAF
Osmems mordax
Rainbow smelt
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
4.76
BAF
Stizostedion vitreum
Walleye
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
4.96
BAF
Pomoxis nigromacuiatus
Black crappie
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.64
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.33
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
4.98
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.74
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.30
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.48
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.23
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.98
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.80
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.48
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
F-5
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.98
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.82
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.25
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.52
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.59
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.30
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
6.98
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
5.38
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
2,2',3,4,5'-Pentachlorobiphenyl
38380-02-8
4.67
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
5.63
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
4.73
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
4.97
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
5.33
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
5.66
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
5.89
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
5.78
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
6.19
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',3,5',6-Pentachlorobiphenyl
38379-99-6
4.78
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.05
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.12
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.37
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.24
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.46
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.95
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.78
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.18
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.14
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.30
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.47
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.12
BAF
Lampsilis lampsilis
Mussel
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.54
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.44
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.41
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.12
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.31
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.43
BAF
Osmervs mordax
Rainbow smelt
Arnot & Gobas 2006
F-6
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.51
BAF
Stizostedion vitreum
Walleye
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.88
BAF
Pomoxis nigmmaculatus
Black crappie
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.45
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.09
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.05
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.70
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.05
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.45
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
7.10
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.52
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.60
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.30
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.52
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.70
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.11
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.41
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.24
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.53
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.93
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.80
BAF
Ambloplites mpestris
Rock bass
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.59
BAF
Noturus flavus
Stonecat
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.98
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.85
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.18
BAF
Moxostoma macrolepidotum
Shorthead redhorse
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.76
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
7.11
BAF
Morone chrysops
White bass
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.31
BAF
Cottus bairdi
Mottled sculpin
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.56
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.88
BAF
Ambloplites mpestris
Rock bass
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.14
BAF
Notropis hudsonius
Spottail shiner
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.81
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.91
BAF
Ambloplites mpestris
Rock bass
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.39
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
6.27
BAF
Labidesthes sicculus
Brook silversides
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.49
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
4.64
BCF
Various
Phytoplankton
Arnot & Gobas 2006
F-7
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.69
BCF
Poecilia reticulata
Guppy
Arnot & Gobas 2006
2,2',4,4',5,5'-Hexachlorobiphenyl
35065-27-1
5.65
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
2,2',4,4'-T etrachlorobiphenyl
2437-79-8
5.28
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',4,4'-T etrachlorobiphenyl
2437-79-8
5.77
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',4,4'-T etrachlorobiphenyl
2437-79-8
5.64
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,4'-T etrachlorobiphenyl
2437-79-8
5.00
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,2',4,4'-T etrachlorobiphenyl
2437-79-8
6.17
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',4,4'-T etrachlorobiphenyl
2437-79-8
4.40
BCF
Oncorhynchus mykiss
Rainbow trout
Arnot & Gobas 2006
2,2',4,4'-T etrachlorobiphenyl
2437-79-8
4.39
BCF
Oncorhynchus mykiss
Rainbow trout
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.19
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.19
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.77
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.34
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.43
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.45
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.14
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
4.77
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
4.83
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.25
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
4.88
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.17
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
4.82
BAF
Lampsilis lampsilis
Mussel
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.01
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.06
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.13
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.84
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.92
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.14
BAF
Osmervs mordax
Rainbow smelt
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
4.88
BAF
Stizostedion vitreum
Walleye
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.13
BAF
Pomoxis nigmmaculatus
Black crappie
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.73
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.29
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.12
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.85
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.46
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.63
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
F-8
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.33
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.65
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.82
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.66
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.04
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.05
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.48
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.78
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.93
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.03
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.32
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.40
BAF
Ambloplites rupestris
Rock bass
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.99
BAF
Noturus flavus
Stonecat
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.55
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.34
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.65
BAF
Moxostoma macrolepidotum
Shorthead redhorse
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.28
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.57
BAF
Morone chrysops
White bass
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.35
BAF
Coitus bairdi
Mottled sculpin
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.29
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.61
BAF
Ambloplites mpestris
Rock bass
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.80
BAF
Notropis hudsonius
Spottail shiner
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.78
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.68
BAF
Ambloplites mpestris
Rock bass
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
6.07
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.96
BAF
Labidesthes sicculus
Brook silversides
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
4.94
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
4.47
BCF
Various
Arnot & Gobas 2006
2,2',4,5,5'-Pentachlorobiphenyl
37680-73-2
5.47
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.69
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.84
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.44
BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.83
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.70
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.82
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.98
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
F-9
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.16
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.04
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.62
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.24
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.51
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.49
BAF
Osmerus mordax
Rainbow smelt
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.23
BAF
Stizostedion vitreum
Walleye
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.49
BAF
Pomoxis nigromacuiatus
Black crappie
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.25
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.73
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.47
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.13
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.75
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.06
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.81
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.82
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.60
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.06
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.79
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.46
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.00
BAF
Osmems mordax
Smelt (small)
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.57
BAF
Osmems mordax
Smelt (large)
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.77
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
5.62
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
6.11
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.47
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.57
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,2',4,5'-T etrachlorobiphenyl
41464-40-8
4.84
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.69
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.82
BCF and BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.29
BCF and BAF
Hexagenia limbata
Mayfly
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.78
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.85
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.54
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.74
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.00
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
F-10
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.00
BAF
Dreissena polymorphs
Zebra mussel
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.54
BAF
Gammarus fasciatus
Amphipod
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.85
BAF
Hydropychidae alterans
Caddisfly larvae
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.70
BAF
Lampsilis lampsilis
Mussel
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.57
BAF
Orconectes propinquus
Crayfish
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.41
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.78
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.35
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.63
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.73
BAF
Osmerus mordax
Rainbow smelt
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.31
BAF
Stizostedion vitreum
Walleye
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.51
BAF
Pomoxis nigromaculatus
Black crappie
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.17
BAF
Micropterus dolomieu
Smallmouth bass
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.21
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.49
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.08
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.88
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.02
BAF
Percopsis omiscomaycus
Troutperch
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.75
BAF
Micropterus salmoides
Largemouth bass
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.26
BAF
Morone americana
White perch
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.53
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.11
BAF
Mixed (mostly yellow perch and smelt)
Young of the year
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.66
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.30
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.08
BAF
Osmervs mordax
Smelt (small)
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.46
BAF
Osmervs mordax
Smelt (large)
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.63
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.65
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.99
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.87
BAF
Ambloplites mpestris
Rock bass
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.24
BAF
Noturus flaws
Stonecat
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.16
BAF
Aplodinotus grunniens
Freshwater drum
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.04
BAF
Perca flavescens
Yellow perch
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.98
BAF
Morone chrysops
White bass
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.25
BAF
Moxostoma macrolepidotum
Shorthead redhorse
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
6.11
BAF
Morone americana
White perch
Arnot & Gobas 2006
F-11
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.87
BAF
Coitus bairdi
Mottled sculpin
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.11
BAF
Dorosoma cepedianum
Gizzard shad
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.36
BAF
Ambloplites rupestris
Rock bass
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.74
BAF
Notropis hudsonius
Spottail shiner
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.44
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.48
BAF
Ambloplites rupestris
Rock bass
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.79
BAF
Notropis atherinoides
Emerald shiner
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.69
BAF
Labidesthes sicculus
Brook silversides
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.83
BCF
Poecilia reticulata
Guppy
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
4.64
BCF
Poecilia reticulata
Guppy
Arnot & Gobas 2006
2,2',5,5'-T etrachlorobiphenyl
35693-99-3
5.65
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
2,2'-Dichlorobiphenyl
13029-08-8
3.43
BCF
Chlorella fusca
Green algae
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.99
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.68
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.43
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.40
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
6.53
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
6.13
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
6.30
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
6.57
BAF
Osmerus mordax
Rainbow smelt
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
4.94
BAF
Osmerus mordax
Smelt (small)
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.37
BAF
Osmerus mordax
Smelt (large)
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.29
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.23
BAF
Cottus cognatus
Sculpin
Arnot & Gobas 2006
2,3',4,4'-T etrachlorobiphenyl
32598-10-0
5.71
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,3,4'-T ric hlorobi p henyl
38444-85-8
5.71
BAF
Pontoporeia hoyi
Amphipod
Arnot & Gobas 2006
2,3,4'-T ric hlorobi p henyl
38444-85-8
4.87
BAF
Mysis relicta
Shrimp
Arnot & Gobas 2006
2,3,4'-Tric hlorobi p henyl
38444-85-8
5.32
BAF
Tubifex tubifex
Oligocheate
Arnot & Gobas 2006
2,3,4'-Tric hlorobi p henyl
38444-85-8
5.40
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
2,3,4'-Tric hlorobi p henyl
38444-85-8
4.47
BCF
Various
Phytoplankton
Arnot & Gobas 2006
2,3-Dichlorobiphenyl
16605-91-7
4.11
BCF
Oncorhynchus mykiss
Rainbow trout
Arnot & Gobas 2006
2,3-Dichlorobiphenyl
16605-91-7
4.04
BCF
Oncorhynchus mykiss
Rainbow trout
Arnot & Gobas 2006
2,3-Dichlorobiphenyl
16605-91-7
4.08
BCF
Oncorhynchus mykiss
Rainbow trout
Arnot & Gobas 2006
2,4',5-Trichlorobiphenyl
16606-02-3
4.01
BCF
Chlorella fusca
Green algae
Arnot & Gobas 2006
2,4',5-Trichlorobiphenyl
16606-02-3
4.15
BCF
Poecilia reticulata
Guppy
Arnot & Gobas 2006
2,4',5-Trichlorobiphenyl
16606-02-3
4.66
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
F-12
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
2,4',5-Trichlorobiphenyl
16606-02-3
5.38
BCF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,4',5-Trichlorobiphenyl
16606-02-3
4.91
BCF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,4',5-Trichlorobiphenyl
16606-02-3
4.69
BCF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,4',5-Trichlorobiphenyl
16606-02-3
5.32
BCF
Osmerus mordax
Rainbow smelt
Arnot & Gobas 2006
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
4.14
BCF
Cyprinus carpio
Common carp
ECCC 2020
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
5.38
BAF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
4.91
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
4.69
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
5.32
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
4.01
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
732-26-3
4.14
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
2,4'-Dichlorobiphenyl
34883-43-7
3.83
BCF
Chlorella fusca
Green algae
Arnot & Gobas 2006
2,4-Di-tert-butylphenol (2,4-DTBP)
96-76-4
2.45
BCF
Cyprinus carpio
Common carp
ECCC 2020
2,4-Di-tert-butylphenol (2,4-DTBP)
96-76-4
2.40
BCF
Cyprinus carpio
Common carp
ECCC 2020
2-Ethylhexyl diphenyl phosphate
1241-94-7
2.49
BCF
Cyprinus carpio
Common carp
ECCC 2020
2-Ethylhexyl diphenyl phosphate
1241-94-7
2.77
BCF
Cyprinus carpio
Common carp
ECCC 2020
2-Ethylhexyl diphenyl phosphate
1241-94-7
2.49
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
2-Ethylhexyl diphenyl phosphate
1241-94-7
2.77
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Bi s(2-ethyl hexyl) phosphate
298-07-7
0.64
BCF
Cyprinus carpio
Common carp
ECCC 2020
Bis (2-ethyl hexyl) phosphate
298-07-7
0.64
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Cresyl diphenyl phosphate (CDPP)
26444-49-5
2.51
BCF
Cyprinus carpio
Common carp
ECCC 2020
Cresyl diphenyl phosphate (CDPP)
26444-49-5
2.52
BCF
Cyprinus carpio
Common carp
ECCC 2020
Cresyl diphenyl phosphate (CDPP)
26444-49-5
2.51
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Cresyl diphenyl phosphate (CDPP)
26444-49-5
2.52
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
5.11
BAF
Catostomus commersonii
White sucker
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
6.56
BAF
Salvelinus namaycush
Lake trout
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
6.35
BAF
Alosa pseudoharengus
Alewife
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
6.85
BAF
Coitus cognatus
Sculpin
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
6.49
BAF
Osmervs mordax
Rainbow smelt
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
5.74
BAF
Mixed - see refererence
Salmonid
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
3.92
BCF
Poecilia reticulata
Guppy
Arnot & Gobas 2006
Decachlorobiphenyl
2051-24-3
5.44
BCF
Danio rerio
Zebra danio
Arnot & Gobas 2006
Dichlorobiphenyl
25512-42-9
4.10
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Dichlorobiphenyl
25512-42-9
3.75
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Hexachlorobiphenyl
26601-64-9
4.34
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
2.43
BCF
Cyprinus carpio
Common carp
ECCC 2020
F-13
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
2.83
BCF
Cyprinus carpio
Common carp
ECCC 2020
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
2.43
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
2.83
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Melamine
108-78-1
-0.42
BCF
Cyprinus carpio
Common carp
ECCC 2020
Melamine
108-78-1
0.58
BCF
Cyprinus carpio
Common carp
ECCC 2020
Melamine
108-78-1
-0.42
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Melamine
108-78-1
0.58
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Polychlorinated biphenyl (PCB)
1336-36-3
4.30
BAF
Dreissena polymorpha
Zebra mussel
Arnot & Gobas 2006
Polychlorinated biphenyl (PCB)a
1336-36-3
2.10
BAF
E. fetida
Earthworm
Needham and Ghosh 2019
Tetrachlorobiphenyl
26914-33-0
4.18
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tetrachlorobiphenyl
26914-33-0
4.10
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
1.48
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tributyl phosphate
126-73-8
0.78
BCF
Carassius auratus
Goldfish
ECCC 2020
Tributyl phosphate
126-73-8
0.89
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tributyl phosphate
126-73-8
0.85
BCF
Carassius auratus
Goldfish
ECCC 2020
Tributyl phosphate
126-73-8
1.13
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tributyl phosphate
126-73-8
1.43
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tributyl phosphate
126-73-8
1.49
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tributyl phosphate
126-73-8
1.54
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tributyl phosphate
126-73-8
1.48
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
1.13
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
0.89
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
1.54
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
1.49
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
0.85
BCF
Carassius auratus
Goldfish
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
0.78
BCF
Carassius auratus
Goldfish
Arnot & Gobas 2006
Tributyl phosphate
126-73-8
1.43
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Trichlorobiphenyl
25323-68-6
4.12
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Trichlorobiphenyl
25323-68-6
4.03
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Triethyl phosphate (TEP)
78-40-0
-0.19
BCF
Cyprinus carpio
Common carp
ECCC 2020
Triethyl phosphate (TEP)
78-40-0
0.11
BCF
Cyprinus carpio
Common carp
ECCC 2020
Triethyl phosphate (TEP)
78-40-0
-0.19
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Triethyl phosphate (TEP)
78-40-0
0.11
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Trimethyl phosphate (TMP)
512-56-1
-0.52
BCF
Cyprinus carpio
Common carp
ECCC 2020
Trimethyl phosphate (TMP)
512-56-1
0.15
BCF
Cyprinus carpio
Common carp
ECCC 2020
Trimethyl phosphate (TMP)
512-56-1
-0.52
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
F-14
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-1. Bioaccumulation and Bioconcentration Factors as Reported in the Literature, Arnot & Gobas 2006, and Environment and Climate Change Canada for
Newly Identified Chemicals in Biosolids
Chemical
CAS number
Log BAF or Log
BCF
(L/kg, ww)
BAF or BCF
Organism scientific name
Organism
common name
Source
Trimethyl phosphate (TMP)
512-56-1
0.15
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.69
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
0.52
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
0.26
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.08
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
0.48
BCF
Carassius auratus
Goldfish
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
0.70
BCF
Carassius auratus
Goldfish
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.89
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
2.04
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
2.05
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.77
BCF
Oryzias latipes
Medaka, high-eyes
ECCC 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.69
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.08
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
0.26
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
2.04
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.89
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
2.05
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
0.70
BCF
Carassius auratus
Goldfish
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
0.48
BCF
Carassius auratus
Goldfish
Arnot & Gobas 2006
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
1.77
BCF
Oryzias latipes
Medaka, high-eyes
Arnot & Gobas 2006
Tris(2-chloroisopropyl) phosphate
13674-84-5
0.26
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tris(2-chloroisopropyl) phosphate
13674-84-5
0.26
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tris(2-chloroisopropyl) phosphate
13674-84-5
0.52
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Tris(2-ethylhexyl) phosphate (TEHP)
78-42-2
0.65
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tris(2-ethylhexyl) phosphate (TEHP)
78-42-2
1.08
BCF
Cyprinus carpio
Common carp
ECCC 2020
Tris(2-ethylhexyl) phosphate (TEHP)
78-42-2
0.65
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
T ris (2-ethyl hexyl) phosphate (TEHP)
78-42-2
1.08
BCF
Cyprinus carpio
Common carp
Arnot & Gobas 2006
Notes:
CAS = Chemical Abstracts Service
ECCC 2020 = Environment and Climate Change Canada
a = Total PCBs were analyzed using U.S. EPA method 8082A and is the sum of 129 PCB congeners.
F-15
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-2. Bioaccumlation and Bioconcentration Factors from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener#
CAS number
EPISuite
Log BCF
(regression based
estimate) (L/kg,
ww) - BCFBAF
EPISuite
Log BCF (Arnot-
Gobas upper
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
EPISuite
Log BCF (Arnot-
Gobas mid trophic
incl biotrans)
(L/kg, ww) -
BCFBAF
EPISuite
Log BCF (Arnot-
Gobas lower
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
EPISuite
Log BAF (Arnot-
Gobas upper
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
EPISuite
Log BAF (Arnot-
Gobas mid trophic
incl biotrans)
(L/kg, ww) -
BCFBAF
EPISuite
Log BAF (Arnot-
Gobas lower
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
2,2', 3,3', 4,4', 5,6'-Octachlorobipheny 1
196
42740-50-1
3.77
2.828
3.007
3.061
6.482
6.126
5.851
2,2',3,3',4,4',5-Heptachlorobiphenyl
170
35065-30-6
4.09
3.277
3.463
3.519
6.848
6.508
6.241
2,2', 3,3', 4,4'-Hexachlorobipheny 1
128
38380-07-3
4.56
3.821
4.012
4.068
6.966
6.65
6.399
2,2', 3,3', 4,5', 6,6'-0ctachl o robi phe ny 1
201
40186-71-8
3.77
2.586
2.747
2.796
6.139
5.811
5.569
2,2',3,3',4,5-Hexachlorobiphenyl
129
55215-18-4
4.55
3.804
3.994
4.049
6.945
6.632
6.385
2,2',3,3',4,6-Hexachlorobiphenyl
131
61798-70-7
4.59
3.842
4.03
4.085
6.93
6.619
6.373
2,2',3,3',5,5',6-Heptachlorobiphenyl
178
52663-67-9
4.09
3.277
3.463
3.519
6.848
6.508
6.241
2,2', 3,3', 6,6'-Hexachlorobipheny 1
136
38411-22-2
4.65
3.86
4.041
4.093
6.788
6.499
6.276
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
3.77
2.828
3.007
3.061
6.482
6.126
5.851
2,2', 3,4,4', 5,5'- Heptachlorobipheny 1
180
35065-29-3
4.09
3.277
3.463
3.519
6.848
6.508
6.241
2,2', 3,4,4', 5'-Hexachlorobipheny 1
138
35065-28-2
4.49
3.731
3.921
3.977
6.947
6.635
6.388
2,2', 3,4,4'-Pentach lorobipheny 1
85
65510-45-4
4.61
4.111
4.274
4.317
6.615
6.309
6.077
2,2', 3,4,5'-Pentach lorobipheny 1
87
38380-02-8
4.77
3.998
4.172
4.221
6.699
6.409
6.187
2,2', 3,5', 6- Pentach lorobipheny 1
95
38379-99-6
4.575
4.127
4.286
4.327
6.57
6.263
6.032
2,2',3,5-Tetrachlorobiphenyl
43
70362-46-8
4.43
4.259
4.399
4.43
6.613
6.238
5.957
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
4.43
4.196
4.336
4.368
6.458
6.125
5.88
2,2', 4,4', 5,5'-Hexachlorobipheny 1
153
35065-27-1
4.34
3.525
3.711
3.766
6.888
6.575
6.331
2,2',4,4'-T etrachlorobiphenyl
47
2437-79-8
4.4
4.164
4.299
4.33
6.323
6.013
5.791
2,2', 4,5,5'-Pentach lorobipheny 1
101
37680-73-2
4.74
4.06
4.235
4.283
6.768
6.457
6.216
2,2,4,5'-T etrachlorobiphenyl
49
41464-40-8
4.36
4.168
4.295
4.323
6.251
5.939
5.718
2,2',4,5-Tetrachlorobiphenyl
48
70362-47-9
4.43
4.159
4.299
4.332
6.367
6.059
5.835
2,2,4,6'-T etrachlorobiphenyl
51
68194-04-7
4.433
4.214
4.354
4.385
6.502
6.157
5.902
2,2,5,5'-T etrachlorobiphenyl
52
35693-99-3
4.27
4.168
4.279
4.3
6.108
5.791
5.572
2,2',6-T richlorobiphenyl
19
38444-73-4
3.87
4.134
4.114
4.092
5.607
5.124
4.846
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl)
ester phosphoric acid
NA
38051-10-4
1.023
1.492
1.564
1.577
1.492
1.564
1.578
2,2-Dichlorobiphenyl
4
13029-08-8
3.53
3.76
3.683
3.647
4.426
4.126
3.996
2,3,3',4,4',5,6-Heptachlorobiphenyl
190
41411-64-7
4.09
3.277
3.463
3.519
6.848
6.508
6.241
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
4.4
3.613
3.801
3.857
6.925
6.612
6.366
2,3,3',4',5,6-Hexachlorobiphenyl
163
74472-44-9
4.61
3.88
4.069
4.124
6.943
6.628
6.379
2,3',4,4'-T etrachlorobiphenyl
66
32598-10-0
4.42
4.111
4.248
4.281
6.213
5.941
5.747
2,3,4'-T richlorobiphenyl
22
38444-85-8
3.83
4.061
4.043
4.022
5.357
4.94
4.71
2,3,6-T richlorobiphenyl
24
55702-45-9
3.99
3.807
3.894
3.91
4.719
4.702
4.695
2,3',6-T richlorobiphenyl
27
38444-76-7
4.01
4.099
4.147
4.146
5.576
5.246
5.047
2,3-Dichlorobiphenyl
5
16605-91-7
3.57
3.855
3.76
3.72
4.781
4.333
4.126
2,4',5-T richlorobiphenyl
31
16606-02-3
4.01
4.063
4.118
4.119
5.469
5.181
5.008
2,4,6-T ris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
3.443
4.033
4.148
4.173
5.714
5.511
5.377
2,4-Dichlorobiphenyl
8
34883-43-7
3.61
3.834
3.775
3.744
4.623
4.31
4.167
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
2.87
2.243
2.376
2.415
2.244
2.394
2.527
F-16
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-2. Bioaccumlation and Bioconcentration Factors from EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener#
CAS number
EPISuite
Log BCF
(regression based
estimate) (L/kg,
ww) - BCFBAF
EPISuite
Log BCF (Arnot-
Gobas upper
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
EPISuite
Log BCF (Arnot-
Gobas mid trophic
incl biotrans)
(L/kg, ww) -
BCFBAF
EPISuite
Log BCF (Arnot-
Gobas lower
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
EPISuite
Log BAF (Arnot-
Gobas upper
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
EPISuite
Log BAF (Arnot-
Gobas mid trophic
incl biotrans)
(L/kg, ww) -
BCFBAF
EPISuite
Log BAF (Arnot-
Gobas lower
trophic incl
biotrans) (L/kg,
ww) - BCFBAF
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
3.61
3.07
3.208
3.249
3.49
4
4.331
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
2.96
2.928
3.049
3.083
2.95
3.166
3.362
2,6-Dichlorobiphenyl
10
33146-45-1
3.54
3.535
3.535
3.522
3.762
3.78
3.798
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
1.25
2.003
2.048
2.05
2.003
2.048
2.05
2-Chlorobiphenyl
1
2051-60-7
2.66
3.269
3.208
3.178
3.324
3.287
3.284
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
2.62
2.43
2.566
2.607
2.436
2.664
2.968
3,4,4'-T richlorobipheny 1
37
38444-90-5
4.15
4.143
4.227
4.238
5.858
5.538
5.33
3,5-Bis(1,1-dimethylethyl)-4-hydroxy-, 2,4-bis(1,1 -
dimethylethyl)phenyl ester benzoic acid
NA
4221-80-1
2.431
0.75
0.873
0.911
3.459
3.483
3.5
4-(Butan-2-yl)-2,6-di-tert-butylphenol
NA
17540-75-9
3.687
2.917
3.055
3.097
3.267
3.843
4.229
4,4',4"-(1 -Methyl-1-propanyl-3-ylidene)tris 2-(1,1-dimethylethyl)-
5- methyl-phenol
NA
1843-03-4
1.111
-0.047
-0.027
-0.023
0.368
0.507
0.6
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)
NA
118-82-1
2.925
1.304
1.438
1.48
3.44
3.761
3.956
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)
NA
96-69-5
3.293
1.45
1.586
1.627
2.488
3.307
3.784
4-Chlorobiphenyl
3
2051-62-9
2.66
3.269
3.208
3.178
3.324
3.287
3.284
6:2 Fluorotelomer sulfonic acid
NA
27619-97-2
0.5
1.654
1.487
1.434
1.654
1.488
1.435
8:2 Fluorotelomer sulfonic acid
NA
39108-34-4
0.5
2.87
2.754
2.71
2.877
2.77
2.738
Ammelide
NA
645-93-2
0.5
-0.049
-0.03
-0.026
-0.049
-0.03
-0.026
Ammeline
NA
645-92-1
0.5
-0.049
-0.031
-0.027
-0.049
-0.031
-0.027
Amoxicillin
NA
26787-78-0
0.5
0.04
0.06
0.063
0.04
0.06
0.063
Ampicillin
NA
69-53-4
0.5
0.262
0.26
0.253
0.262
0.26
0.253
Bis(2-chloroethyl) phosphate
NA
3040-56-0
0.5
0.164
0.128
0.116
0.164
0.128
0.116
Bis(2-ethylhexyl) phosphate
NA
298-07-7
1.47
2.926
3.062
3.103
3.066
3.526
3.894
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
1.46
2.719
2.654
2.623
2.72
2.661
2.641
Cesium3
NA
7440-46-2
0.5
-0.017
-0.001
0.001
-0.017
-0.001
0.001
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
1.82
2.329
2.438
2.466
2.329
2.443
2.495
Cyanuric acid
NA
108-80-5
3.773
2.586
2.747
2.796
6.139
5.811
5.569
Decachlorobiphenyl
NA
2051-24-3
4.088
3.267
3.451
3.507
6.833
6.494
6.229
Dibutyl ester phosphoric acid
NA
107-66-4
0.35
1.214
1.094
1.052
1.214
1.094
1.052
Dichlorobiphenyl
NA
25512-42-9
3.552
3.779
3.706
3.672
4.476
4.171
4.039
Diethyl hydrogen phosphate
NA
598-02-7
0.5
0.018
0.021
0.02
0.018
0.021
0.02
Diisobutyl hydrogen phosphate
NA
6303-30-6
0.255
1.074
0.958
0.918
1.074
0.958
0.918
Diphenyl phosphate (DPHP)
NA
838-85-7
0.74
1.604
1.551
1.524
1.604
1.551
1.524
Dipropyl ester phosphoric acid
NA
1804-93-9
-0.3
0.406
0.331
0.307
0.406
0.331
0.307
Heptachlorobiphenyl
NA
28655-71-2
4.09
3.277
3.463
3.519
6.848
6.508
6.241
Hexachlorobiphenyl
NA
26601-64-9
4.343
3.525
3.711
3.766
6.888
6.575
6.331
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
1.06
2.46
2.593
2.633
2.463
2.648
2.858
Melamine
NA
108-78-1
0.5
-0.049
-0.03
-0.026
-0.049
-0.03
-0.026
Monochlorobiphenyl
NA
27323-18-8
2.689
3.3
3.246
3.218
3.365
3.336
3.337
F-17
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-2. Bioaccumlation and Bioconcentration Factors from EPISuite for Newly Identified Chemicals in Biosolids
EPISuite
EPISuite
EPISuite
EPISuite
EPISuite
EPISuite
EPISuite
Log BCF (Arnot-
Log BCF (Arnot-
Log BCF (Arnot-
Log BAF (Arnot-
Log BAF (Arnot-
Log BAF (Arnot-
Log BCF
Gobas upper
Gobas mid trophic
Gobas lower
Gobas upper
Gobas mid trophic
Gobas lower
(regression based
trophic incl
incl biotrans)
trophic incl
trophic incl
incl biotrans)
trophic incl
Chemical
PCB
congener#
CAS number
estimate) (L/kg,
ww) - BCFBAF
biotrans) (L/kg,
ww) - BCFBAF
(L/kg, ww) -
BCFBAF
biotrans) (L/kg,
ww) - BCFBAF
biotrans) (L/kg,
ww) - BCFBAF
(L/kg, ww) -
BCFBAF
biotrans) (L/kg,
ww) - BCFBAF
Nalidixic acid
NA
389-08-2
0.5
0.235
0.268
0.272
0.235
0.268
0.272
Nonachlorobiphenyl
NA
53742-07-7
3.661
2.482
2.647
2.697
6.091
5.745
5.486
Octachlorobiphenyl
NA
55722-26-4
3.773
2.828
3.007
3.061
6.482
6.126
5.851
Pentachlorobiphenyl
NA
25429-29-2
4.74
4.06
4.235
4.283
6.768
6.457
6.216
Polychlorinated biphenyl (PCB)
NA
1336-36-3
4.403
4.164
4.299
4.33
6.323
6.013
5.791
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
3.1
1.725
1.861
1.903
1.909
2.828
3.516
Sulfate
NA
14808-79-8
0.5
-0.049
-0.031
-0.027
-0.049
-0.031
-0.027
Sulfur3
NA
7704-34-9
2.08
2.016
2.058
2.06
2.016
2.058
2.063
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
2.22
2.724
2.845
2.878
2.73
2.893
3.036
Tetrabutyl ethylidenebisphenol (A022E46)
NA
35958-30-6
2.86
1.291
1.426
1.467
3.63
3.855
3.994
Tetrachlorobiphenyl
NA
26914-33-0
4.271
4.168
4.279
4.3
6.108
5.791
5.572
Tributyl phosphate
NA
126-73-8
1.48
1.843
1.949
1.977
1.843
1.95
1.982
Trichlorobiphenyl
NA
25323-68-6
3.915
4.02
4.051
4.045
5.261
4.973
4.81
Triethyl phosphate (TEP)
NA
78-40-0
0.5
0.146
0.146
0.116
0.116
0.106
0.106
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
methylphenyl)propionate (AO-245)
NA
36443-68-2
2.71
0.089
0.143
0.16
0.089
0.222
0.971
Triisobutyl phosphate
NA
126-71-6
2.62
2.43
2.566
2.607
2.436
2.664
2.968
Trimethyl phosphate (TMP)
NA
512-56-1
0.5
-0.046
-0.027
-0.023
-0.046
-0.027
-0.023
Trimethylsilanol (TMS)
NA
1066-40-6
0.42
0.342
0.261
0.238
0.342
0.261
0.238
Tripropyl phosphate
NA
513-08-6
0.08
0.726
0.666
0.64
0.726
0.666
0.641
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
1.25
2.003
2.048
2.05
2.003
2.048
2.054
T ris(2-chloroisopropyl) phosphate
NA
13674-84-5
0.55
1.108
1.123
1.116
1.108
1.123
1.116
Tris(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
1.48
0.086
0.14
0.156
0.146
0.872
1.623
Tris(4-tert-butylphenyl) phosphate
NA
78-33-1
1.619
1.367
1.533
1.583
5.017
4.656
4.381
Tris(methylphenyl) phosphate
NA
1330-78-5
2.214
3.107
3.203
3.225
3.14
3.314
3.449
Notes
CAS = Chemical Abstracts Service
NA = Not applicable
8 = Inorganic compound, outside of EPISuite estimation domain
F-18
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table F-3. Bioconcentration Factors (BCF) as Reported by ORNL for Newly Identified Chemicals in
Biosolids
Chemical
CAS number
BCF
(L/g)
Source
Polychlorinated biphenyl (PCB)
1336-36-3
25300
ORNL 2020
Tributyl phosphate
126-73-8
29.60056495
ORNL 2020
Tris(2-chloroisopropyl) phosphate
13674-84-5
3.56
ORNL 2020
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
13674-87-8
12.0005182
ORNL 2020
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
672.9766563
ORNL 2020
Trimethyl phosphate (TMP)
512-56-1
1.399909627
ORNL 2020
T ris(2-ethyl hexyl) phosphate (TEHP)
78-42-2
50.11872336
ORNL 2020
Notes
CAS = Chemical Abstracts Service
F-19
-------
Biosolids Biennial Review Reporting Period 2018-2019
Appendix G. Environmental Fate and Transport Data: Physical/
Chemical Properties
G-l
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table G-1. Physical/Chemical Properties as Reported in the Literature for Newly and Previously Identified Chemicals in Biosolids
Vapor
New or
Molecular
Solubility
pressure
(mmHg @
PNECsoil
Sludge
adsorption
Soil half-
lifetime
MDL
Chemical
CAS number
previous
weight
(mg/L @ 25 C)
25 C)
LogK,,.
Log Koc
Log Koa
(ng/g)
(%)
(h)
(ng/g dw)
Source
2,2-Bi s(ch loro methyl)-1,3-propanediy I tetrakis(2-chloroethyl)
ester phosphoric acid
38051-10-4
New
582.9
2.1
0.0ฑ1.7
1.92
3.08
0.70
Wangetal. 2019
2-Butoxy-, hydrogen phosphate ethanol
14260-97-0
New
298.3
410.1
3.16E-07
1.74
3.775
12.116
552
1.97
-
0.68
Wangetal. 2019
2-Ethylhexyl diphenyl phosphate
1241-94-7
New
362.40
1.90
3.34E-05
6.30
4.20
8.92
30.2
89.79
720
0.90
Wang et al. 2019
Ammelide0
645-93-2
New
-
50,000,000
-1.22
1.68
-
-
1.75
3240
-
Zhuetal. 2019
Ammeline0
645-92-1
New
-
1,000,000,000
-
-4.08
2.35
-
-
1.75
3240
-
Zhuetal. 2019
Bis(1,3-dichloropropan-2-yl) hydrogen phosphate
72236-72-7
New
319.9
130
1.03E-07
2.18
2.640
10.998
-
2.35
-
0.03
Wangetal. 2019
Bis(2-chloroethyl) phosphate
3040-56-0
New
222.9
6456
1.22E-05
0.83
1.649
8.988
512
1.78
-
1.11
Wangetal. 2019
Bis(2-ethylhexyl) phosphate
298-07-7
New
322.4
0.05926
1.8E-07
6.07
4.235
11.845
-
91.66
-
1.38
Wangetal. 2019
Bis(2-methylphenyl) hydrogen phosphate
35787-74-7
New
278.2
6.652
4.69E-08
3.97
2.519
12.245
-
28.4
-
0.02
Wangetal. 2019
Bisphenol A bis(diphenyl phosphate) (BDP)
5945-33-5
New
692.6
0.42
0.0ฑ2.0
8.66
5.72
-
-
0.42
Wangetal. 2019
Cresyl diphenyl phosphate (CDPP)
26444-49-5
New
340.3
0.233
1.04E-07
5.25
3.92
10.9
-
83.47
1.8E+03
1.59E+O0
Wang et al. 2019
Cyanuric acidd
108-80-5
New
-
1,990,000
-
1.95
1.00
-
2.11
3240
-
Zhuetal. 2019
Dibutyl ester phosphoric acid
107-66-4
New
210.2
430.1
3.79E-05
2.29
2.180
9.049
341
2.52
-
1.17
Wangetal. 2019
Diethyl hydrogen phosphate
598-02-7
New
154.1
3.844E+04
1.83E-03
0.32
1.117
7.572
-
1.76
-
0.40
Wangetal. 2019
Diisobutyl hydrogen phosphate
6303-30-6
New
210.2
574.3
1.12E-04
2.14
2.027
8.899
-
2.3
-
0.47
Wangetal. 2019
Diphenyl phosphate (DPHP)
838-85-7
New
250.1
82.38
2.26E-07
2.88
2.082
11.243
353
4.67
-
0.39
Wangetal. 2019
Dipropyl ester phosphoric acid
1804-93-9
New
182.1
4115
2.39E-04
1.31
1.649
8.315
-
1.84
-
0.13
Wangetal. 2019
Isodecyl diphenyl phosphate (IDDP)
29761-21-5
New
390.4
0.75
4.72E-08
7.28
4.69
12.0
-
93.16
1.8E+03
6.3E-01
Wangetal. 2019
Melamine0
108-78-1
New
-
3,240,000
-
-1.37
1.32
-
500
1.75
1800
-
Zhuetal. 2019
Resorcinol bis(diphenyl phosphate) (RDP)
57583-54-7
New
574.5
1.10E+04
0.0ฑ1.6
5.97
4.54
-
-
-
-
0.60
Wangetal. 2019
Tert-butylphenyI diphenyl phosphate
56803-37-3
New
382.3
8.90E-03
2.61E-08
6.61
4.57
11.9
-
92.79
1.8E+03
9.6E-01
Wangetal. 2019
T ributyl phosphate
126-73-8
New
266.31
7.35
3.49E-03
3.82
3.27
9.21
900
29.74
416
1.70
Wang et al. 2019
Triethyl phosphate (TEP)
78-40-0
New
182.15
5.00E+05
0.165
0.87
1.68
6.63
-
1.78
720
0.98
Wangetal. 2019
T riisobutyl phosphate
126-71-6
New
266.32
16.2
1.28E-02
3.6
3.04
7.48
1060
15.3
720
0.15
Wang et al. 2019
Tri methyl phosphate (TlvlP)
512-56-1
New
140.8
5.00E+05
0.85
-0.65
0.88
5.88
1.76
720
0.26
Wang et al. 2019
Tripropyl phosphate
513-08-6
New
224.23
6.45E+03
2.31E-02
2.35
2.47
6.42
226
2.05
720
1.68
Wang et al. 2019
Tri s( 1,3-dich loro-2-propyl) phosphate (TDCIPP)
13674-87-8
New
430.90
7.00
2.86E-07
3.65
3.96
10.6
320
16.7
8.64E+03
7.2E-01
Wang et al. 2019
Tris(2-chloroisopropyl) phosphate
13674-84-5
New
327.57
1.20E+O3
5.64E-05
2.89
3.10
8.20
1700
3.27
2.88E+03
5.6E-01
Wang et al. 2019
Tris(2-ethylhexyl) phosphate (TEHP)
78-42-2
New
434.63
0.6
6.07E-07
9.49
6.35
14.9
21.8
93.26
416
1.62
Wangetal. 2019
T ris(4-tert-buty Iphenyl) phosphate
78-33-1
New
494
9.62E-07
2.06E-08
10.43
6.28
14.9
93.26
8.64E+03
1.26E+00
Wangetal. 2019
Tris(methylphenyl) phosphate
1330-78-5
New
368.36
0.30
3.49E-08
6.34
4.34
12.0
2.70
92.39
1.8E+03
2.8E-01
Wang et al. 2019
1990 L/kg
Azithromycin8
83905-01-5
Previous
-
-
-
-
(not log)
-
-
-
-
-
Sidhu et al. 2019c
1660 L/kg
Ciprofloxacin13
85721-33-1
Previous
-
-
-
-
(not log)
-
-
-
-
-
Sidhu et al. 2019c
Triphenyl phosphate
115-86-6
Previous
326.28
1.90
4.72E-07
4.70
3.71
8.45
130
60.09
1.8E+03
7.30E-01
Wang et al. 2019
Tris(2-butoxyethyl) phosphate
78-51-3
Previous
398.47
1.10E+O3
1.23E-06
3.00
5.66
13.0
2480
19.84
416
0.40
Wang et al. 2019
Tris(2-chloroethyl) phosphate
115-96-8
Previous
285.49
7.00E+03
3.91E-04
1.63
2.47
7.42
386
1.86
2.88E+03
6.40E-01
Wang et al. 2019
Notes
CAS = Chemical Abstracts Service
a = Kd is 428 L/kg
b = Kd is 357 L/kg
c = Degradation rate is 0.09%
d = Degradation rate is 0.1%
G-2
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table G-2. Physical/Chemical Properties Related to Water and Soil from EPISUITE and ORNLfor Newly Identified Chemicals in Biosolids
Solubility
Solubility
Log K,,.
based on
based on
(atom
Water
log Kow
fragment
fragment
Log Koc (MCI
Log Koc (log
Foc-Organic
degradation
Soil degradation
(mg/L) -
constant
contrib
method
Kow method
carbon partition
half-life (hr) -
half-life (hr) -
PCB
WSKOWWI
(mg/L)
Solubility
Solubility units
method) -
Log Kow
corrected) -
corrected) -
coefficient
AOPWIN &
AOPWIN &
Chemical
congener#
CAS number
N
WATERNT
(PHYSPROP)
(PHYSPROP)
KOWWIN
(PHYSPROP)
KOCWIN
KOCWIN
(Ukg)-ORNL
BIOWIN
BIOWIN
2,2',3,3',4,4l,5,6l-Octachlorobiphenyl
196
42740-50-1
4.88E-05
8.10E-05
0.000163
mg/L at 25 C
8.98
5.7665
5.9979
4320
8640
2,2',3,3',4,4',5-Heptachlorobiphenyl
170
35065-30-6
0.0002842
0.00036674
0.00347
mg/L at 20 C
8.27
-
5.5525
5.6439
356800
4320
8640
2,2',3,3',4,4'-Hexachlorobiphenyl
128
38380-07-3
0.003044
0.0016469
0.00035
mg/L at 25 C
7.31
7.31
5.3384
5.1129
-
4320
8640
2,2',3,3',4,5l,6,6l-Octachlorobiphenyl
201
40186-71-8
4.88E-05
8.10E-05
0.000271
mg/L at 25 C
8.91
-
5.7665
5.9979
-
4320
8640
2,2',3,3',4,5-Hexachlorobiphenyl
129
55215-18-4
0.002984
0.0016469
0.00137
mg/L at 25 C
7.32
7.32
5.3384
5.1184
-
4320
8640
2,2',3,3',4,6-Hexachlorobiphenyl
131
61798-70-7
0.003425
0.0016469
0.0012
mg/L at 25 C
7.25
7.25
5.3384
5.0797
-
4320
8640
2,2',3,3',5,5',6-Heptachlorobiphenyl
178
52663-67-9
0.0002842
0.00036674
0.00102
mg/L at 25 C
8.2685
-
5.5437
5.6439
-
4320
8640
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
0.004422
0.0016469
0.00451
mg/L at 25 C
7.12
7.12
5.3384
5.0078
-
4320
8640
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
4.88E-05
8.10E-05
0.000136
mg/L at 25 C
8.913
-
5.7665
5.9979
-
4320
8640
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
0.0002842
0.00036674
0.00385
mg/L at 20 C
8.27
-
5.5437
5.6439
349700
4320
8640
2,2',3,4,4',5'-Hexachlorobiphenyl
138
35065-28-2
0.002357
0.0016469
0.0015
mg/L at 20 C
7.44
7.44
5.3296
5.1848
-
4320
8640
2,2',3,4,4'-Pentachlorobiphenyl
85
65510-45-4
0.01943
0.0073282
0.00783
mg/L at 25 C
6.61
6.61
5.1155
4.7257
-
4320
8640
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
0.01212
0.0073282
0.0294
mg/L at 20 C
6.85
6.85
5.1155
4.8584
-
4320
8640
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
0.02186
0.0073282
0.0211
mg/L at 20 C
6.55
6.55
5.1155
4.6925
-
4320
8640
2,2',3,5-Tetrachlorobiphenyl
43
70362-46-8
0.05316
0.032245
0.172
mg/L at 25 C
6.34
-
4.9014
4.5763
-
4320
8640
2,2',3,6-Tetrachl orobiphenyl
45
70362-45-7
0.05316
0.032245
0.146
mg/L at 25 C
6.34
-
4.91
4.5763
-
4320
8640
2,2',4,4',5,5'-Hexachlorobiphenyl
153
35065-27-1
0.001281
0.0016469
0.00095
mg/L at 24 C
7.75
7.75
5.3208
5.3563
-
4320
8640
2,2',4,4'-Tetrachl orobiphenyl
47
2437-79-8
0.05808
0.032245
0.0541
mg/L at 22 C
6.29
6.29
4.8926
4.5487
-
4320
8640
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
0.01337
0.0073282
0.0154
mg/L at 25 C
6.8
6.8
5.1067
4.8308
-
4320
8640
2,2',4,5'-Tetrachl orobiphenyl
49
41464-40-8
0.06665
0.032245
0.0781
mg/L at 25 C
-
6.22
4.8926
4.51
-
4320
8640
2,2',4,5-Tetrac hi orobiphenyl
48
70362-47-9
0.05316
0.032245
0.0164
mg/L at 25 C
6.335
-
4.9014
4.5763
-
4320
8640
2,2',4,6'-Tetrachl orobiphenyl
51
68194-04-7
0.05316
0.032245
0.0654
mg/L at 25 C
6.34
-
4.9014
4.5763
-
4320
8640
2,2',5,5'-Tetrachl orobiphenyl
52
35693-99-3
0.08606
0.032245
0.0153
mg/L at 25 C
-
-
4.8926
4.4381
-
4320
8640
2,2',6-Trichl orobiphenyl
19
38444-73-4
0.448
0.13991
0.324
mg/L at 25 C
5.48
5.48
4.696
4.1006
-
1440
2880
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-
chloroethyl) ester phosphoric acid
NA
38051-10-4
0.312
33.402
-
-
3.31
-
6.288
2.859
-
4.32E+03
8.64E+03
2,2'-Dichl orobiphenyl
4
13029-08-8
1.714
0.59619
1.85
mg/L at 25 C
4.97
4.1382
4.3131
-
900
1800
2,3,3',4,4',5,6-Heptachlorobiphenyl
190
41411-64-7
0.0002842
0.00036674
-
-
8.27
-
5.5525
5.6439
-
4320
8640
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
0.001641
0.0016469
0.00807
mg/L at 20 C
7.62
-
5.3296
5.2843
-
4320
8640
2,3,3',4',5,6-Hexachl orobiphenyl
163
74472-44-9
0.003779
0.0016469
0.0012
mg/L at 25 C
7.2
7.2
5.3296
5.052
-
4320
8640
2,3',4,4'-Tetrachl orobiphenyl
66
32598-10-0
0.05584
0.032245
0.0368
mg/L at 20 C
6.31
6.31
4.8926
4.5597
-
4320
8640
2,3,4'-Trichl orobiphenyl
22
38444-85-8
0.5049
0.13991
0.142
mg/L at 20 C
5.42
5.42
4.6873
4.0675
-
1440
2880
2,3,6-Trichl orobiphenyl
24
55702-45-9
0.3088
0.13991
0.0833
mg/L at 25 C
5.67
5.67
4.6961
4.2057
-
1440
2880
2,3',6-Trichl orobiphenyl
27
38444-76-7
0.2966
0.13991
0.0386
mg/L at 20 C
5.69
4.6873
4.2168
-
1440
2880
2,3-Dichl orobiphenyl
5
16605-91-7
1.711
0.59619
0.997
mg/L at 25 C
5.02
5.02
4.1382
4.3565
-
900
1.80E+03
2,4',5-Trichl orobiphenyl
31
16606-02-3
0.2969
0.13991
0.143
mg/L at 25 C
5.69
5.69
4.6785
4.2168
-
1400
2880
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
0.512
0.74303
35
mg/L at 25 C
6.39
6.06
4.8
4.444
-
1440
2880
2,4'-Dichl orobiphenyl
8
34883-43-7
1.491
0.59619
1.17
mg/L at 25 C
5.09
5.09
4.1294
4.4172
-
900
1800
2,4-Di-tert-butylphend (2,4-DTBP)
NA
96-76-4
5.704
32.493
35
mg/L at 25 C
5.3318
5.19
3.9547
3.9627
-
900
1800
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
0.4441
3.1126
-
-
6.314
-
4.5393
4.5822
-
900
1800
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
4.316
32.493
-
-
5.33
-
3.955
4.04
-
900
1800
2,6-Dichl orobiphenyl
10
33146-45-1
1.851
0.59619
2.41
mg/L at 25 C
4.98
4.98
4.1382
4.3217
-
900
1800
2-Butoxy-, hydrogen phosphate ethand
NA
14260-97-0
1.501
30.169
-
-
3.65
-
4.0465
3.0474
-
4320
8640
2-Chl orobiphenyl
1
2051-60-7
8.804
2.48
4.83
mg/L at 25 C
4.402
4.53
3.9241
3.9312
-
900
1800
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
0.06659
0.1844
1.9
mg/L at 25 C
5.73
5.73
4.5074
3.8683
-
360
720
3,4,4'-T richl orobiphenyl
37
38444-90-5
0.1965
0.13991
0.0719
mg/L at 20 C
5.9
5.9
4.6785
4.333
-
1440
2880
G-3
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table G-2. Physical/Chemical Properties Related to Water and Soil from EPISUITE and ORNLfor Newly Identified Chemicals in Biosolids
Solubility
Solubility
Log K,,.
based on
based on
(atom
Water
log Kow
fragment
fragment
Log Koc (MCI
Log Koc (log
Foc-Organic
degradation
Soil degradation
(mg/L) -
constant
contrib
method
Kow method
carbon partition
half-life (hr) -
half-life (hr) -
PCB
WSKOWWI
(mg/L)
Solubility
Solubility units
method) -
Log Kow
corrected) -
corrected) -
coefficient
AOPWIN &
AOPWIN &
Chemical
congener#
CAS number
N
WATERNT
(PHYSPROP)
(PHYSPROP)
KOWWIN
(PHYSPROP)
KOCWIN
KOCWIN
(Ukg)-ORNL
BIOWIN
BIOWIN
3,5-Bis(1,1-dimethylethyl)-4-hydroxy-, 2,4-bis(1,1-
dimethylethyl)phenyl ester benzoic acid
NA
4221-80-1
1.92E-05
1.62E-05
-
-
10
-
6.62E+00
6.558
-
4.32E+03
8.64E+03
4-(Butan-2-yl)-2,6-di-tert-butylphenol
NA
17540-75-9
0.2479
0.50593
-
-
6.43
-
4.924
4.649
-
1.44E+03
2.88E+03
4,4',4"-(1-Methyl-1-propanyl-3-ylidene)tris 2-(1,1-
di methyl ethyl )-5-methyl -phenol
NA
1843-03-4
2.01 E-08
5.45E-07
12.7
9.7575
8.4504
4.32E+03
8.64E+03
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)
NA
118-82-1
0.0001707
0.00013684
-
-
8.99
-
7.562
6.231
-
4.32E+03
8.64E+03
4,4'-Thiobis(6-tert-butyl-m-cresd) (A044S25)
NA
96-69-5
0.001906
0.0568
-
-
8.24
-
6.299
5.817
-
3.27
55.6
4-Chlorobiphenyl
3
2051-62-9
8.804
2.48
1.34
mg/L at 25 C
4.4015
4.61
8229
900
1800
6:2 Fluorotelomer sulfonic acid
NA
27619-97-2
10.97
1.9609
-
-
2.66
-
4.0511
2.3964
-
4320
8640
8:2 Fluorotelomer sulfonic acid
NA
39108-34-4
0.1821
0.00445
-
-
4
-
5.354
3.138
-
4320
8640
Ammelide
NA
645-93-2
5.01 E+04
9.32E+05
76.9
mg/L at 2 C
-1.2163
-
1.3504
0.1965
-
360
720
Ammeline
NA
645-92-1
1.00E+06
1.00E+06
75
mg/L at 23 C
-3.6476
-
2.1414
-1.1592
-
360
720
Amoxicillin
NA
26787-78-0
3433
1.00E+06
-
-
0.9736
0.87
2.035
0.7091
-
900
1800
Ampicillin
NA
69-53-4
439.3
1.00E+06
1.00E+04
mg/L at 21 C
1.4538
1.35
1.9263
0.8077
-
900
1800
Bis(2-chloroethyl) phosphate
NA
3040-56-0
6456
56368
-
-
0.83
-
1.7756
1.4875
-
900
1800
Bis(2-ethyl hexyl) phosphate
NA
298-07-7
0.05926
0.83431
182
mg/L at 25 C
6.07
-
4.311
4.3859
-
360
720
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
6.652
50.767
-
-
3.97
-
2.8368
2.8948
-
900
1800
Cesium8
NA
7440-46-2
5.71 E+04
2.36E+05
-
-
0.23
-
1.121
0.199
-
360
720
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
0.9973
1.454
0.24
mg/L at 25 C
4.51
4.51
4.245
3.1934
-
900
1800
Cyanuric acid
NA
108-80-5
4.88E-05
8.10E-05
-
-
8.91
-
5.7665
5.9979
-
4320
8640
Decachlorobiphenyl
NA
2051-24-3
6.32E-05
3.89E-06
7.43E-06
mg/L at 25 C
10.2
8.27
-
-
-
Dibutyl ester phosphoric acid
NA
107-66-4
430.1
3830.2
1.72E+04
mg/L at 25 C
2.29
-
2.2969
2.2951
-
208.1
416.2
Dichlorobi phenyl
NA
25512-42-9
1.78
0.59619
0.055
mg/L
5.05
5
4.1382
4.3391
-
Diethyl hydrogen phosphate
NA
598-02-7
3.84E+04
3.95E+05
-
-
0.32
-
1.254
1.205
-
360
720
Diisobutyl hydrogen phosphate
NA
6303-30-6
574.3
10757
-
-
2.14
-
2.147
2.212
-
900
1800
Diphenyl phosphate (DPHP)
NA
838-85-7
82.38
513.03
-
-
2.88
-
2.426
2.292
-
900
1.80E+03
Dipropyl ester phosphoric acid
NA
1804-93-9
4115
39359
-
-
1.31
-
1.7756
1.753
-
360
720
Heptachlorobiphenyl
NA
28655-71-2
0.0002842
0.00036674
0.000314
mg/L at 25 C
8.27
-
5.544
5.644
-
4.32E+03
8.64E+03
Hexachlorobiphenyl
NA
26601-64-9
0.001281
0.0016469
0.0035
mg/L at 25 C
6.34
6.34
5.321
5.365
-
4.32E+03
8.64E+03
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
0.07929
0.016753
0.75
mg/L at 25 C
5.44
5.44
4.9891
3.7079
97530
900
1800
Melamine
NA
108-78-1
1.00E+06
1040.5
3230
mg/L at 20 C
-
-1.37
1.509
0.0002
-
900
1800
Monochlorobiphenyl
NA
27323-18-8
6.122
2.48
-
-
4.58
-
3.915
3.975
-
900
1800
Nalidixic acid
NA
389-08-2
3224
1.50E+05
100
mg/L at 23 C
-
1.59
0.7816
1.342
-
900
1800
Nonachlorobiphenyl
NA
53742-07-7
1.90E-05
1.78E-05
0.00011
mg/L at 182 C
9.14
-
5.989
6.125
-
4.32E+03
8.64E+03
Octachlorobiphenyl
NA
55722-26-4
4.88E-05
8.10E-05
0.000271
mg/L at 25 C
8.91
-
5.767
5.998
-
4320
8640
Pentachlorobiphenyl
NA
25429-29-2
0.01337
0.007282
-
-
6.98
5.68
5.107
4.831
-
4.32E+03
8.64E+03
Polychlorinated biphenyl (PCB)
NA
1336-36-3
0.05808
0.032245
0.7
mg/L at 25 C
6.29
7.1
4.893
4.549
78100
4.32E+03
8.64E+04
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
0.0001113
0.0068756
-
-
7.41
-
8.3237
4.7975
-
900
1800
Sulfate
NA
14808-79-8
1.00E+06
1.00E+06
-
-
-2.2
-
0.3444
-0.1303
-
360
720
Sulfur3'e
NA
7704-34-9
1.00E+06
60488
-
-
-1.38
-
1.121
3.1674
-
360
720
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
0.1668
0.098469
32
mg/L at 25 C
5.12
5.12
4.8676
3.5309
-
900
1800
Tetrabutyl ethylidenebisphenol (A022E46)
NA
35958-30-6
0.000107
6.88E-05
-
-
9.13
-
7.7844
6.3089
-
4320
8640
Tetrachlorobiphenyl
NA
26914-33-0
0.08606
0.032245
0.046
mg/L
6.09
-
4.893
4.438
-
4.32E+03
3.89E+04
Tributyl phosphate
NA
126-73-8
7.355
101.04
280
mg/L at 25 C
-
4
3.3711
3.241
2350
208.1
416.2
Trie hi orobiphenyl
NA
25323-68-6
0.391
0.13991
-
-
5.55
5.48
4.687
4.139
-
1.44E+03
2.88E+03
Triethyl phosphate (TEP)
NA
78-40-0
1.12E+04
1.15E+05
5.00E+05
mg/L at 25 C
-
0.8
1.8072
1.471
-
360
720
G-4
-------
Biosolids Biennial Review
Reporting Period 2018-2019
Table G-2. Physical/Chemical Properties Related to Water and Soil from EPISUITE and ORNLfor Newly Identified Chemicals in Biosolids
Solubility
Solubility
Log K
based on
based on
(atom
Water
log Kow
fragment
fragment
Log Koc (MCI
Log Koc (log
Foc-Organic
degradation
Soil degradation
(mg/L) -
constant
contrib
method
Kow method
carbon partition
half-life (hr) -
half-life (hr) -
PCB
WSKOWWI
(mg/L)
Solubility
Solubility units
method) -
Log Kow
corrected) -
corrected) -
coefficient
AOPWIN &
AOPWIN &
Chemical
congener#
CAS number
N
WATERNT
(PHYSPROP)
(PHYSPROP)
KOWWIN
(PHYSPROP)
KOCWIN
KOCWIN
(Ukg)-ORNL
BIOWIN
BIOWIN
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
methylphenyl)propionate (AO-245)d
NA
36443-68-2
7.31 E-05
0.0038365
-
-
8.207
-
6.2819
5.4876
-
4320
8640
Triisobutyl phosphate
NA
126-71-6
0.06659
0.1844
-
-
5.73
-
4.5074
3.8683
-
360
720
Trimethyl phosphate (TMP)
NA
512-56-1
3.00E+05
1.00E+06
5.00E+05
mg/L at 25 C
-0.65
-0.65
1.0253
0.6689
10.6
360
720
Trimethylsilanol (TMS)
NA
1066-40-6
4.26E+04
1.00E+06
-
-
1.14
-
1.6424
0.989
-
360
720
Tripropyl phosphate
NA
513-08-6
826.6
3474.1
6450
mg/L at 25 C
-
1.87
2.5892
2.0628
-
360
720
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
1.501
30.169
7
mg/L at 24 C
3.65
3.65
4.0465
3.0474
11130
4320
8640
Tris(2-chloroisopropyl) phosphate
NA
13674-84-5
51.85
740.16
1200
mg/L at 25 C
2.59
2.59
3.2051
2.4611
1604
1440
2880
T ris (2-ethyl hexyl) phosphate (TEHP)
NA
78-42-2
1.46E-05
0.00027907
0.6
mg/L at 24 C
9.49
-
6.3923
6.2777
2468000
208.1
416.2
T ris (4-tert-butyl phenyl) phosphate
NA
78-33-1
9.62E-07
4.12E-05
-
-
10.43
-
6.541
6.468
-
4.32E+03
8.64E+03
Tris (methyl phenyl) phosphate
NA
1330-78-5
0.2073
0.14004
-
-
5.11
-
4.6731
3.5253
-
900
1800
Notes
CAS = Chemical Abstracts Service
3 = Inorganic compound, outside of EPISuite estimation domain
b = Kd is 7.5 cm3/g
c = Water degradation - hydrolysis rate constant (estimated using HYDROWIN) is 2.48E^
d = Water degradation - hydrolysis rate constant (estimated using HYDROWIN) is 3.5E"1
e = Koc is not corrected
G-5
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-3. Physical/Chemical Properties Related to Air in EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener#
CAS number
Molecular
weight
Vapor pressure
(mmHg) ฆ
MPBPWIN
Vapor pressure
(PHYSPROP)
Vapor pressure
units
(PHYSPROP)
Henry's law
constant-bond est
(atm-m3fmole) -
HENRYWIN
Henry's law
constant - group
est (atm-m3fmole) -
HENRYWIN
Henry's law
constant
(PHYSPROP)
Henry's law
constant units
(PHYSPROP)
Air degradation
half-life (hr) -
AOPWIN &
BIOWIN
Air overall OH
degradation rate
constant
(cm3fmolecule-sec)
AOP
Air fraction sorbed
to airborne
particulates
(Junge-Pankow,
Mackayavg)-AOP
Air fraction
sorbed to
airborne
particulates (KM)
-AOP
2,2', 3,3', 4,4', 5,6'-0ctachl orobi phenyl
196
42740-50-1
429.77
2.87E-08
-
-
3.76E-05
1.17E-04
1.00E-05
atm-m3/mole at 25 C
3650
7.03E-14
0.502
0.975
2,2', 3,3', 4,4',5-Heptachl orobi phenyl
170
35065-30-6
395.33
1.30E-07
6.28E-07
mm Hg at 25 C
5.07E-05
1.38E-04
9.00E-06
atm-m3/mole at 25 C
2453
1.05E-13
0.0807
0.909
2,2', 3,3', 4,4'-Hexachlorobiphenyl
128
38380-07-3
360.88
5.81 E-07
2.56E-06
mm Hg at 25 C
6.85E-05
1.62E-04
1.30E-05
atm-m3/mole at 25 C
1565
1.64E-13
0.031
0.43
2,2', 3,3', 4,5', 6,6'-0ctachl orobi phenyl
201
40186-71-8
429.77
2.87E-08
-
-
3.76E-05
1.17E-04
1.70E-05
atm-m3/mole at 25 C
3650
7.03E-14
0.502
0.958
2,2',3,3', 4,5-Hexachl orobiphenyl
129
55215-18-4
360.88
5.81 E-07
-
-
6.85E-05
1.62E-04
2.90E-05
atm-m3/mole at 25 C
1217
2.11E-13
0.115
0.257
2,2',3,3', 4,6-Hexachl orobiphenyl
131
61798-70-7
360.88
5.81 E-07
-
-
6.85E-05
1.62E-04
3.90E-05
atm-m3/mole at 25 C
1169
2.20E-13
0.115
0.18
2,2', 3,3', 5,5', 6-Heptachl orobi phenyl
178
52663-67-9
395.33
1.30E-07
-
-
5.07E-05
1.38E-04
2.30E-05
atm-m3/mole at 25 C
1833
1.40E-13
0.266
0.796
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
360.88
5.81 E-07
-
-
6.85E-05
1.62E-04
8.80E-05
atm-m3/mole at 25 C
1565
1.64E-13
0.115
0.0671
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
429.77
2.87E-08
-
-
3.76E-05
1.17E-04
-
-
4202
6.11E-14
0.502
0.912
2,2', 3,4,4', 5,5'-Heptachl orobi phenyl
180
35065-29-3
395.33
1.30E-07
9.77E-07
mm Hg at 25 C
5.07E-05
1.38E-04
1.00E-05
atm-m3/mole at 25 C
2453
1.05E-13
0.0536
0.13
2,2', 3,4,4', 5'-Hexachlorobiphenyl
138
35065-28-2
360.88
5.81 E-07
3.80E-06
mm Hg at 25 C
6.85E-05
1.62E-04
2.10E-05
atm-m3/mole at 25 C
1565
1.64E-13
0.0212
0.0597
2,2', 3,4,4'-Pentachlorobi phenyl
85
65510-45-4
326.44
2.22E-06
-
-
9.24E-05
1.90E-04
6.60E-05
atm-m3/mole at 25 C
642.5
4.00E-13
0.0443
0.0288
2,2', 3,4,5'-Pentachlorobi phenyl
87
38380-02-8
326.44
2.22E-06
1.70E-05
mm Hg at 25 C
9.24E-05
1.90E-04
7.40E-05
atm-m3/mole at 25 C
766.8
3.35E-13
0.0063
0.0439
2,2', 3,5', 6-Pentachlorobi phenyl
95
38379-99-6
326.44
2.22E-06
-
-
9.24E-05
1.90E-04
1.20E-04
atm-m3/mole at 25 C
641.8
3.35E-13
0.0443
0.012
2,2', 3,5-Tetrachl orobiphenyl
43
70362-46-8
291.99
8.45E-06
-
-
1.25E-04
2.23E-04
-
-
337.9
7.60E-13
0.0164
0.00835
2,2', 3,6-Tetrachl orobi phenyl
45
70362-45-7
291.99
8.45E-06
-
-
1.25E-04
2.23E-04
-
-
445.2
5.77E-13
0.0164
0.00835
2,2', 4,4', 5,5'-Hexachlorobiphenyl
153
35065-27-1
360.88
5.81 E-07
3.43E-06
mm Hg at 25 C
6.85E-05
1.62E-04
2.30E-05
atm-m3/mole at 25 C
1565
1.64E-13
0.0234
0.0954
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
291.99
8.45E-06
8.63E-05
mm Hg at 25 C
1.25E-04
2.23E-04
1.90E-04
atm-m3/mole at 25 C
256.8
8.13E-13
0.00165
0.00491
2,2',4,5,5'-Pentachlorobi phenyl
101
37680-73-2
326.44
2.22E-06
2.50E-05
mm Hg at 25 C
9.24E-05
1.90E-04
9.00E-05
atm-m3/mole at 25 C
766.8
3.35E-13
0.00425
0.022
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
291.99
8.45E-06
8.48E-06
mm Hg at 25 C
1.25E-04
2.23E-04
2.10E-04
atm-m3/mole at 25 C
332.6
7.72E-13
0.0165
0.0048
2,2',4,5-Tetrachl orobi phenyl
48
70362-47-9
291.99
8.45E-06
-
-
1.25E-04
2.23E-04
-
-
445.2
5.77E-13
0.0164
0.00835
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
291.99
8.45E-06
-
-
1.25E-04
2.23E-04
1.40E-04
atm-m3/mole at 25 C
315.6
8.13E-13
0.0164
0.00744
2,2',5,5'-Tetrachlorobiphenyl
52
35693-99-3
291.99
8.45E-06
-
-
1.25E-04
2.23E-04
2.00E-04
atm-m3/mole at 25 C
351.6
7.30E-13
0.0164
0.00576
2,2',6-Trichlorobiphenyl
19
38444-73-4
257.55
4.00E-05
-
-
1.68E-04
2.62E-04
2.30E-04
atm-m3/mole at 25 C
216.5
1.19E-12
0.00592
0.000631
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-chloroethyl) ester
phosphoric acid
NA
38051-10-4
583
2.06E-08
_
_
1.55E-14
_
_
_
3.322
7.73E-11
0.928
1
2,2'-Dichl orobi phenyl
4
13029-08-8
223.1
0.00275
0.00275
mmHg at 25
2.27E-04
3.08E-04
2.30E-04
atm-m3/mole at 25 C
128.4
1.73E-12
0.000207
0.000297
2,3,3',4,4',5,6-Heptachlorobiphenyl
190
41411-64-7
395.33
1.30E-07
-
-
5.07E-05
1.38E-04
-
-
2065
1.24E-13
0.266
0.638
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
360.88
1.55E-06
-
-
6.85E-05
1.62E-04
-
-
1169
2.20E-13
0.115
0.226
2,3,3',4',5,6-Hexachlorobiphenyl
163
74472-44-9
360.88
5.81 E-07
-
-
6.85E-05
1.62E-04
1.50E-05
atm-m3/mole at 25 C
1.22E+03
2.11E-13
0.115
0.336
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
291.99
8.45E-06
4.60E-05
mm Hg at 25
1.25E-04
2.23E-04
1.20E-04
atm-m3/mole at 25 C
332.6
7.72E-13
0.00307
0.0201
2,3,4'-Trichlorobiphenyl
22
38444-85-8
257.55
4.00E-05
-
-
1.68E-04
2.62E-04
1.40E-04
atm-m3/mole at 25 C
235.3
1.09E-12
0.00592
0.000901
2,3,6-Tri chlorobiphenyl
24
55702-45-9
257.55
4.00E-05
-
-
1.68E-04
2.62E-04
2.20E-04
atm-m3/mole at 25 C
204.5
1.26E-12
0.00592
0.00102
2,3',6-Trichlorobiphenyl
27
38444-76-7
257.55
4.00E-05
-
-
1.68E-04
2.62E-04
-
-
138.2
1.86E-12
0.00592
0.0014
2,3-Dichlorobiphenyl
5
16605-91-7
223.1
0.00019
-
-
2.27E-04
3.08E-04
2.30E-04
atm-m3/mole at 25 C
104
2.47E-12
0.00198
0.000219
2,4',5-Trichlorobiphenyl
31
16606-02-3
257.55
4.00E-05
0.0004
mm Hg at 25 C
1.68E-04
2.62E-04
-
-
213.9
0.00058
0.00163
2,4,6-Tri s(tert-butyl )phenol (2,4,6-TTBP)
NA
732-26-3
262.44
0.0002
0.000661
mm Hg extrap at
25 C
9.65E-06
6.89E-06
_
_
16.04
1.60E-11
0.000177
0.0541
2,4'-Dichl orobi phenyl
8
34883-43-7
223.1
0.000191
0.00209
mm Hg at 25 C
2.27E-04
3.08E-04
2.30E-04
atm-m3/mole at 25 C
148.7
1.73E-12
0.000173
0.000493
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
206.33
0.00267
0.0047
mm Hg extrap at
25 C
0.00000374
0.00000315
_
_
5.227
4.91 E-11
0.000134
0.0195
2,4-Di-tert-pentyl phenol (2,4-DTPP)
NA
120-95-6
234.38
0.000347
-
-
6.59E-06
6.29E-06
-
-
4.994
5.14E-11
0.00375
0.13
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
206.33
0.000618
-
-
3.74E-06
3.15E-06
-
-
2.878
8.92E-11
0.000676
0.0267
2,6-Dichlorobiphenyl
10
33146-45-1
223.1
0.000191
-
-
2.27E-04
3.08E-04
2.30E-04
atm-m3/mole at 25 C
104.1
2.47E-12
0.00198
0.0002
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
430.91
2.86E-07
-
-
2.61 E-09
14.2
1.81 E-11
0.795
0.451
2-Chlorobiphenyl
1
2051-60-7
188.66
0.00637
0.00138
mm Hg at 25 C
3.07E-04
3.62E-04
7.36E-04
atm-m3/mole at 25 C
91.03
3.48E-12
0.000772
2.21 E-05
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
362.41
3.34E-05
5.00E-05
mm Hg at 25 C
2.48E-07
5.42E-05
atm-m3/mole at 25 C
6.442
3.98E-11
0.0254
0.00473
3,4,4'-Trichlorobiphenyl
37
38444-90-5
257.55
4.00E-05
-
-
1.68E-04
2.62E-04
1.00E-04
atm-m3/mole at 25 C
235.3
1.09E-12
0.00592
0.0038
G-6
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-3. Physical/Chemical Properties Related to Air in EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener#
CAS number
Molecular
weight
Vapor pressure
(mmHg) ฆ
MPBPWIN
Vapor pressure
(PHYSPROP)
Vapor pressure
units
(PHYSPROP)
Henry's law
constant-bond est
(atm-m3fmole) -
HENRYWIN
Henry's law
constant - group
est (atm-m3fmole) -
HENRYWIN
Henry's law
constant
(PHYSPROP)
Henry's law
constant units
(PHYSPROP)
Air degradation
half-life (hr) -
AOPWIN &
BIOWIN
Air overall OH
degradation rate
constant
(cm3fmolecule-sec)
AOP
Air fraction sorbed
to airborne
particulates
(Junge-Pankow,
Mackayavg)-AOP
Air fraction
sorbed to
airborne
particulates (KM)
-AOP
3,5-Bis(1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis(1,1-
dimethylethyl)phenyl ester benzoic acid
NA
4221-80-1
438.66
1.35E-10
_
_
5.93E-08
_
_
_
21.67
1.18E-11
0.991
1
4-(Butan-2-yl)-2,6-di-tert-butylphenol
NA
17540-75-9
262.44
2.07E-05
-
-
9.65E-06
1.02E-05
-
-
12.54
2.05E-11
0.011
0.118
4,4',4"-(1 -Methyl-1 -propanyl-3-ylidene)tris 2-(1,1 -dimethyl ethyl)-5-
methyl-phenol
NA
1843-03-4
544.82
1.55E-15
_
_
2.36E-15
_
_
_
1.23
2.09E-10
1
1
4,4'-Methyl enebis(2,6-di-t-butylphenol) (AO-702)
NA
118-82-1
424.67
1.19E-11
-
-
2.31 E-10
3.30E-11
-
-
7.21
3.56E-11
0.999
1
4,4'-Thi obis(6-tert-butyl -m-cresol) (A044S25)
NA
96-69-5
358.54
2.17E-10
-
-
2.76E-12
-
-
-
0.000653
1.30E-10
0.995
1
4-Chlorobiphenyl
3
2051-62-9
188.66
0.00138
0.0105
mm Hg at 25 C
3.07E-04
3.62E-04
5.73E-04
atm-m3/mole at 25 C
66.5
3.48E-12
0.000772
0.000124
6:2 Fluorotelomer sulfonic acid
NA
27619-97-2
428.17
0.000862
-
-
7.00E-04
-
-
-
196
1.31 E-12
0.000637
3.13E-07
8:2 Fluorotelomer sulfonic acid
NA
39108-34-4
528.18
0.00045
-
-
1.93E-02
-
-
-
196
1.31 E-12
0.00102
2.49E-07
Ammelide
NA
645-93-2
128.09
8.40E-09
-
-
9.73E-15
-
-
-
11.16
2.30E-11
0.722
0.748
Ammeline
NA
645-92-1
127.11
3.44E-07
-
-
1.19E-16
-
-
-
5.969
4.30E-11
0.12
0.475
Amoxicillin
NA
26787-78-0
365.41
4.69E-17
-
-
2.49E-21
-
-
-
1.848
1.39E-10
1
1
Ampicillin
NA
69-53-4
349.41
2.84E-13
-
-
2.39E-17
-
-
-
2.484
1.03E-10
1
1
Bis(2-chloroethyl) phosphate
NA
3040-56-0
222.99
4.42E-06
-
-
1.70E-10
-
-
-
17.35
1.48E-11
0.0955
0.0187
Bis(2-ethylhexyl) phosphate
NA
298-07-7
322.43
1.80E-07
-
-
4.11 E-08
-
-
-
3.926
6.54E-11
0.864
0.932
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
278.25
1.26E-08
-
-
1.30E-10
-
-
-
27.67
9.27E-12
0.96
0.972
Cesium3
NA
7440-46-2
132.91
4.24E-09
-
-
2.45E-02
-
-
-
1.00E+05
0.00E+00
0.84
3.33E-11
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
340.32
1.04E-07
4.70E-06
mm Hg at 25 C
4.39E+00
-
-
-
21.77
1.18E-11
0.062
0.27
Cyanuric acid
NA
108-80-5
429.77
2.87E-08
-
-
3.76E-05
1.17E-04
-
-
3650
7.03E-14
0.502
0.958
Decachlorobiphenyl
NA
2051-24-3
498.66
1.02E-10
1.06E-07
mm Hg at 25 C
2.06E-05
8.48E-05
-
-
1.82E-14
0.0201
0.00942
Dibutyl ester phosphoric acid
NA
107-66-4
210.21
3.79E-05
-
-
4.26E-09
-
-
-
4.872
5.27E-11
0.0332
0.0215
Dichlorobi phenyl
NA
25512-42-9
223.1
0.000301
-
-
2.27E-04
3.08E-04
-
-
1.73E-12
0.000207
0.000297
Diethyl hydrogen phosphate
NA
598-02-7
154.1
0.00183
-
-
1.37E-09
-
-
-
6.622
3.88E-11
0.000713
0.000732
Diisobutyl hydrogen phosphate
NA
6303-30-6
210.21
0.000107
-
-
4.26E-09
-
-
-
4.87
5.27E-11
0.0115
0.0153
Diphenyl phosphate (DPHP)
NA
838-85-7
250.19
9.12E-08
-
-
1.06E-10
-
-
-
34.8
7.37E-12
0.835
0.775
Dipropyl ester phosphoric acid
NA
1804-93-9
182.16
0.00021
-
-
2.42E-09
-
-
-
5.148
4.99E-11
0.00543
0.00404
Heptachlorobiphenyl
NA
28655-71-2
395.33
1.30E-07
-
-
5.07E-05
1.38E-04
-
-
1.83E+03
1.40E-13
0.266
0.638
Hexachlorobiphenyl
NA
26601-64-9
360.88
5.81 E-07
3.75E-06
mm Hg at 25 C
6.85E-05
1.62E-04
-
-
1.57E+03
1.64E-13
0.0234
0.0954
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
390.46
4.72E-08
8.93E-08
4.36E-07
-
-
-
6.115
4.20E-11
0.854
0.233
Melamine
NA
108-78-1
126.12
8.93E-08
3.59E-10
mm Hg extrap at
20 C
1.89E-13
_
_
_
389.3
6.60E-13
0.691
0.527
Monochlorobi phenyl
NA
27323-18-8
188.66
0.00443
0.0084
mm Hg
3.07E-04
3.62E-04
-
-
48.62
4.88E-12
0.000295
0.00013
Nalidixic acid
NA
389-08-2
232.24
6.17E-08
-
-
5.12E-16
-
-
11.09
2.15E-11
0.117
1
Nonachlorobi phenyl
NA
53742-07-7
464.22
7.60E-09
-
-
2.79E-05
9.96E-05
-
-
7.80E+03
3.29E-14
0.738
0.96
Octachlorobiphenyl
NA
55722-26-4
429.77
2.87E-08
-
-
3.76E-05
1.17E-04
1.70E-05
atm-m3/mole at 25 C
3650
7.03E-14
0.502
0.958
Pentachlorobiphenyl
NA
25429-29-2
326.44
2.22E-06
-
-
9.24E-05
1.90E-04
-
-
766.8
3.35E-13
0.00425
0.022
Polychlorinated biphenyl (PCB)
NA
1336-36-3
291.99
8.45E-06
-
-
1.25E-04
2.23E-04
4.15E-04
atm-m3/mole at 25 C
257
8.13E-13
0.00165
0.00491
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
574.47
2.06E-08
-
-
2.94E-13
-
-
-
12.13
2.12E-11
0.928
1
Sulfate
NA
14808-79-8
98.07
-
0.000143
2.54E-11
-
-
-
916.8
2.80E-13
0.0215
0.000119
Sulfur8
NA
7704-34-9
34.08
-
-
-
8.69E-03
-
-
-
1.00E+05
0.00E+00
0.897
2.30E-12
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
382.4
2.61 E-08
1.40E-06
mm Hg at 25 C
1.03E-07
-
8.80E-07
atm-m3/mole at 25 C
16.36
1.57E-11
0.172
0.0666
Tetrabutyl ethylidenebisphenol (A022E46)
NA
35958-30-6
438.7
8.23E-12
-
-
3.07E-10
-
-
-
7.27
3.53E-11
0.999
1
Tetrachl orobiphenyl
NA
26914-33-0
291.99
8.45E-06
-
-
1.25E-04
2.23E-04
-
-
3.52E+02
7.30E-13
0.0164
0.00576
Tributyl phosphate
NA
126-73-8
266.32
3.49E-03
0.00113
mm Hg at 25 C
3.19E-06
-
-
-
3.257
7.88E-11
0.00115
0.00339
Trichlorobiphenyl
NA
25323-68-6
257.55
4.00E-05
-
-
1.68E-04
2.62E-04
-
-
235
1.09E-12
0.000221
0.000781
Triethyl phosphate (TEP)
NA
78-40-0
182.16
0.153
0.393
mm Hg at 25 C
5.83E-07
-
3.60E-08
atm-m3/mole at 20 C
4.642
5.79E-11
3.32E-06
8.41 E-05
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
methylphenyl)propionate (AO-245)
NA
36443-68-2
586.77
1.14E-16
_
_
1.35E-19
1.94E-23
_
_
3.439
7.46E-11
1
1
G-7
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-3. Physical/Chemical Properties Related to Air in EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB
congener#
CAS number
Molecular
weight
Vapor pressure
(mmHg) ฆ
MPBPWIN
Vapor pressure
(PHYSPROP)
Vapor pressure
units
(PHYSPROP)
Henry's law
constant-bond est
(atm-m3fmole) -
HENRYWIN
Henry's law
constant - group
est (atm-m3fmole) -
HENRYWIN
Henry's law
constant
(PHYSPROP)
Henry's law
constant units
(PHYSPROP)
Air degradation
half-life (hr) -
AOPWIN &
BIOWIN
Air overall OH
degradation rate
constant
(cm3fmolecule-sec)
AOP
Air fraction sorbed
to airborne
particulates
(Junge-Pankow,
Mackayavg)-AOP
Air fraction
sorbed to
airborne
particulates (KM)
-AOP
Triisobutyl phosphate
NA
126-71-6
362.41
3.34E-05
-
-
2.48E-07
-
-
-
6.442
3.98E-11
0.0254
0.00473
Trimethyl phosphate (TMP)
NA
512-56-1
140.08
0.379
0.85
mm Hg extrap at
25 C
_
7.20E-09
atm-m3/mole at 20 C
34.82
8.36E-12
1.54E-06
1.49E-05
Trimethylsilanol (TMS)
NA
1066-40-6
90.2
12.9
-
-
5.06E-05
-
-
-
64.99
3.90E-12
1.01 E-07
1.31 E-07
Tripropyl phosphate
NA
513-08-6
224.24
0.0231
-
-
1.36E-06
-
6.80E-07
atm-m3/mole at 20 C
3.442
7.46E-11
5.44E-05
5.24E-05
Tris(1,3-di chloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
430.91
2.86E-07
-
-
2.61 E-09
-
-
-
14.2
1.81 E-11
0.795
0.451
Tris(2-butoxyethyl) phosphate
NA
78-51-3
398.48
1.23E-06
3.75
-
1.20E-11
-
-
-
1.994
1.29E-10
0.496
0.996
Tri s(2-chloroisopropyl) phosphate
NA
13674-84-5
327.57
5.64E-05
-
-
5.96E-08
-
-
-
5.734
4.48E-11
0.0226
0.00312
Tris(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
434.65
6.07E-07
8.25E-08
mm Hg at 25 C
9.56E-05
-
-
-
2.623
9.79E-11
0.932
1
Tris(4-tert-butyl phenyl) phosphate
NA
78-33-1
494.62
2.06E-08
-
-
6.85E-07
-
-
-
17.7
1.45E-11
0.928
1
Tris(methylphenyl) phosphate
NA
1330-78-5
368.37
0.0123
-
-
5.35E-08
-
-
-
18.74
1.37E-11
0.663
0.0711
Notes
CAS = Chemical Abstracts Service
a = Inorganic compound, outside of EPISuite estimation domain
G-8
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-4. Physical/Chemical Properties Related to Fugacity and Advection in EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB congener #
CAS number
Fugacity in air
(atm) - Level III
Fugacity Model
Fugacity in
water (atm) -
Level III
Fugacity Model
Fugacity in soil
(atm) - Level III
Fugacity Model
Advection in air
(kg/hr) - Level
III Fugacity
Model
Advection in
water (kg/hr) -
Level III
Fugacity Model
2,2',3,3',4,4',5,6'-Octachlorobiphenyl
196
42740-50-1
1.21E-11
2.38E-12
1.75E-12
404
870
2,2',3,3',4,4',5-Heptachlorobiphenyl
170
35065-30-6
2.71E-11
8.39E-12
2.50E-12
5.68E+02
8.00E+02
2,2',3,3',4,4'-Hexachlorobiphenyl
128
38380-07-3
4.64E-11
4.86E-11
5.69E-12
752
633
2,2',3,3',4,5',6,6'-Octachlorobiphenyl
201
40186-71-8
1.21E-11
4.04E-12
2.97E-12
405
869
2,2',3,3',4,5-Hexachlorobiphenyl
129
55215-18-4
4.80E-11
1.04E-10
1.27E-11
778
613
2,2',3,3',4,6-Hexachlorobiphenyl
131
61798-70-7
4.90E-11
1.43E-10
1.71E-11
795
588
2,2',3,3',5,5',6-Heptachlorobiphenyl
178
52663-67-9
2.74E-11
2.13E-11
6.51E-12
575
794
2,2',3,3',6,6'-Hexachlorobiphenyl
136
38411-22-2
5.37E-11
3.19E-10
3.90E-01
8.70E+02
520
2,2',3,4,4',5,5',6-Octachlorobiphenyl
203
52663-76-0
1.24E-11
2.74E-11
2.05E-11
413
857
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
2.71E-11
9.35E-12
2.84E-12
569
801
2,2',3,4,4',5'-Hexachlorobiphenyl
138
35065-28-2
4.73E-11
7.03E-11
9.36E-12
767
652
2,2',3,4,4'-Pentachlorobiphenyl
85
65510-45-4
6.97E-11
3.80E-10
4.85E-11
962
526
2,2',3,4,5'-Pentachlorobiphenyl
87
38380-02-8
7.09E-11
3.94E-10
5.45E-11
979
539
2,2',3,5',6-Pentachlorobiphenyl
95
38379-99-6
7.50E-11
6.30E-10
8.86E-11
1.03E+03
471
2,2',3,5-Tetrachlorobiphenyl
43
70362-46-8
9.25E-11
1.32E-09
2.84E-10
1.12E+03
424
2,2',3,6-Tetrachlorobiphenyl
45
70362-45-7
9.61E-11
1.31 E-09
2.79E-10
1.16E+03
423
2,2',4,4',5,5'-Hexachlorobiphenyl
153
35065-27-1
4.69E-11
5.58E-11
1.04E-11
760
722
2,2',4,4'-Tetrachlorobiphenyl
47
2437-79-8
8.67E-11
1.17E-09
2.47E-10
1.05E+03
437
2,2',4,5,5'-Pentachlorobiphenyl
101
37680-73-2
7.28E-11
4.75E-10
6.77E-11
1.01E+03
519
2,2',4,5'-Tetrachlorobiphenyl
49
41464-40-8
9.20E-11
1.27E-09
2.73E-10
1.11E+03
425
2,2',4,5-Tetrachlorobiphenyl
48
70362-47-9
9.62E-11
1.32E-09
2.85E-10
1.16E+03
424
2,2',4,6'-Tetrachlorobiphenyl
51
68194-04-7
8.67E-11
9.16E-10
1.79E-10
1.05E+03
469
2,2',5,5'-Tetrachlorobiphenyl
52
35693-99-3
9.26E-11
1.24E-09
2.60E-10
1.12E+03
426
2,2',6-T richlorobiphenyl
19
38444-73-4
9.75E-11
1.47E-09
1.75E-10
1.03E+03
360
2,2-Bis(chloromethyl)-1,3-propanediyl tetrakis(2-
chloroethyl) ester phosphoric acid
NA
38051-10-4
2.66E-18
1.04E-20
7.49E-22
0.00069
307
2,2'-Dichlorobiphenyl
4
13029-08-8
9.82E-11
1.70E-09
4.47E-10
897
338
2,3,3',4,4',5,6-Heptachlorobiphenyl
190
41411-64-7
2.91E-11
1.21E-10
3.88E-11
610
754
2,3,3',4,4',6-Hexachlorobiphenyl
158
74472-42-7
6.41E-11
3.90E-10
6.63E-11
981
592
G-9
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-4. Physical/Chemical Properties Related to Fugacity and Advection in EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB congener #
CAS number
Fugacity in air
(atm) - Level III
Fugacity Model
Fugacity in
water (atm) -
Level III
Fugacity Model
Fugacity in soil
(atm) - Level III
Fugacity Model
Advection in air
(kg/hr) - Level
III Fugacity
Model
Advection in
water (kg/hr) -
Level III
Fugacity Model
2,3,3',4',5,6-Hexachlorobiphenyl
163
74472-44-9
4.64E-11
6.03E-11
6.69E-12
753
613
2,3',4,4'-Tetrachlorobiphenyl
66
32598-10-0
8.60E-11
8.18E-10
1.56E-10
1.04E+03
485
2,3,4'-Trichlorobiphenyl
22
38444-85-8
9.42E-11
1.00E-09
1.09E-10
997
401
2,3,6-Trichlorobiphenyl
24
55702-45-9
9.56E-11
1.42E-09
1.67E-10
1.01E+03
364
2,3',6-Trichlorobiphenyl
27
38444-76-7
8.70E-11
1.63E-09
2.02E-10
920
351
2,3-Dichlorobiphenyl
5
16605-91-7
9.05E-11
1.69E-09
4.48E-10
827
337
2,4',5-Trichlorobiphenyl
31
16606-02-3
9.53E-11
1.27E-09
1.50E-10
1.01E+03
377
2,4,6-Tris(tert-butyl)phenol (2,4,6-TTBP)
NA
732-26-3
1.78E-11
6.19E-11
4.02E-12
191
543
2,4'-Dichlorobiphenyl
8
34883-43-7
1.03E-10
1.70E-09
4.58E-10
939
339
2,4-Di-tert-butylphenol (2,4-DTBP)
NA
96-76-4
8.37E-12
4.06E-11
1.02E-11
70.7
543
2,4-Di-tert-pentylphenol (2,4-DTPP)
NA
120-95-6
7.15E-12
5.80E-11
4.67E-12
68.6
499
2,5-Di-tert-butylphenol (2,5-DTBP)
NA
5875-45-6
4.78E-12
4.04E-11
1.02E-11
40.3
542
2,6-Dichlorobiphenyl
10
33146-45-1
9.06E-11
1.70E-09
4.48E-10
828
337
2-Butoxy-, hydrogen phosphate ethanol
NA
14260-97-0
5.32E-13
2.74E-14
2.81E-14
16.4
921
2-Chlorobiphenyl
1
2051-60-7
1.13E-10
5.31 E-09
2.68E-09
871
276
2-Ethylhexyl diphenyl phosphate
NA
1241-94-7
6.34E-12
1.97E-10
1.12E-11
94.7
283
3,4,4'-Trichlorobiphenyl
37
38444-90-5
9.02E-11
7.59E-10
7.92E-11
955
435
3,5-Bis(1,1 -dimethylethyl)-4-hydroxy-, 2,4-bis(1,1 -
dimethylethyl)phenyl ester benzoic acid
NA
4221-80-1
6.84E-14
1.16E-15
1.28E-15
139
869
4-(Butan-2-yl)-2,6-di-tert-butylphenol
NA
17540-75-9
1.45E-11
7.97E-11
4.48E-12
157
517
4,4',4"-(1 -Methyl-1 -propanyl-3-ylidene)tris 2-(1,1-
di methylethy l)-5-methyl-phenol
NA
1843-03-4
1.99E-19
6.92E-26
3.14E-26
8.94
828
4,4'-Methylenebis(2,6-di-t-butylphenol) (AO-702)
NA
118-82-1
2.48E-15
1.36E-18
8.74E-20
50
365
4,4'-Thiobis(6-tert-butyl-m-cresol) (A044S25)
NA
96-69-5
7.42E-16
1.39E-18
6.96E-20
0.912
0.912
4-Chlorobiphenyl
3
2051-62-9
9.74E-11
5.31 E-09
2.73E-09
753
276
6:2 Fluoroteiomer sulfonic acid
NA
27619-97-2
7.22E-11
2.72E-09
3.67E-09
1.27E+03
339
8:2 Fluoroteiomer sulfonic acid
NA
39108-34-4
5.57E-11
3.57E-08
3.96E-09
1.20E+03
262
Ammelide
NA
645-93-2
7.60E-18
2.01E-19
7.59E-18
0.000139
530
Ammeline
NA
645-92-1
9.36E-20
1.96E-21
2.64E-20
5.40E-07
419
G-10
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-4. Physical/Chemical Properties Related to Fugacity and Advection in EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB congener #
CAS number
Fugacity in air
(atm) - Level III
Fugacity Model
Fugacity in
water (atm) -
Level III
Fugacity Model
Fugacity in soil
(atm) - Level III
Fugacity Model
Advection in air
(kg/hr) - Level
III Fugacity
Model
Advection in
water (kg/hr) -
Level III
Fugacity Model
Amoxicillin
NA
26787-78-0
6.81 E-25
2.79E-26
5.26E-25
0.000189
818
Ampicillin
NA
69-53-4
6.84E-21
2.93E-22
6.30E-21
0.000336
856
Bis(2-chloroethyl) phosphate
NA
3040-56-0
7.59E-14
3.48E-15
8.76E-14
0.742
913
Bis(2-ethylhexyl) phosphate
NA
298-07-7
1.47E-12
1.95E-13
1.75E-14
43.3
334
Bis(2-methylphenyl) hydrogen phosphate
NA
35787-74-7
4.38E-14
1.53E-15
7.23E-15
9.71
658
Cesium3
NA
7440-46-2
6.36E-11
2.64E-07
5.86E-07
2.12E+03
286
Cresyl diphenyl phosphate (CDPP)
NA
26444-49-5
2.85E-12
3.37E-13
6.07E-14
122
561
Cyanuric acid
NA
108-80-5
1.21E-11
4.04E-12
2.97E-12
405
869
Decachlorobiphenyl
NA
2051-24-3
8.27E-14
4.06E-09
5.79E-10
282
549
Dibutyl ester phosphoric acid
NA
107-66-4
1.59E-12
2.64E-14
2.22E-13
13.8
260
Dichlorobiphenyl
NA
25512-42-9
9.80E-11
1.70E-09
4.48E-10
896
338
Diethyl hydrogen phosphate
NA
598-02-7
8.35E-13
2.40E-14
9.56E-13
5.27
539
Diisobutyl hydrogen phosphate
NA
6303-30-6
1.59E-12
7.65E-14
1.16E-12
13.8
755
Diphenyl phosphate (DPHP)
NA
838-85-7
4.20E-14
1.51E-15
1.58E-14
1.49
715
Dipropyl ester phosphoric acid
NA
1804-93-9
1.16E-12
3.00E-14
6.88E-13
8.67
451
Heptachlorobiphenyl
NA
28655-71-2
2.90E-11
1.22E-10
3.95E-11
6.08E+02
756
Hexachlorobiphenyl
NA
26601-64-9
4.69E-11
5.58E-01
1.04E-11
760
722
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
7.72E-13
2.13E-12
7.94E-14
67.2
442
Melamine
NA
108-78-1
1.46E-17
7.48E-19
2.32E-17
0.00014
1.03E+03
Monochlorobiphenyl
NA
27323-18-8
8.11E-11
4.53E-09
2.29E-09
627
283
Nalidixic acid
NA
389-08-2
2.20E-19
1.33E-20
5.08E-19
3.37E-06
1.21 E+03
Nonachlorobiphenyl
NA
53742-07-7
4.44E-12
1.30E-11
1.03E-11
314
868
Octachlorobiphenyl
NA
55722-26-4
1.21E-11
1.21E-11
1.75E-12
404
870
Pentachlorobiphenyl
NA
25429-29-2
7.28E-11
4.75E-10
6.77E-11
1.01E+03
519
Polychlorinated biphenyl (PCB)
NA
1336-36-3
8.67E-11
1.17E-09
2.47E-10
1.05E+03
437
Resorcinol bis(diphenyl phosphate) (RDP)
NA
57583-54-7
5.12E-17
1.49E-21
2.77E-23
0.0131
185
Sulfate
NA
14808-79-8
2.59E-14
8.43E-16
4.63E-14
0.104
651
Sulfur3
NA
7704-34-9
1.85E-10
3.74E-07
2.26E-06
2.03E+03
294
Tert-butylphenyl diphenyl phosphate
NA
56803-37-3
9.11E-13
4.91E-12
2.47E-13
126
472
G-ll
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-4. Physical/Chemical Properties Related to Fugacity and Advection in EPISuite for Newly Identified Chemicals in Biosolids
Chemical
PCB congener #
CAS number
Fugacity in air
(atm) - Level III
Fugacity Model
Fugacity in
water (atm) -
Level III
Fugacity Model
Fugacity in soil
(atm) - Level III
Fugacity Model
Advection in air
(kg/hr) - Level
III Fugacity
Model
Advection in
water (kg/hr) -
Level III
Fugacity Model
Tetrabutyl ethylidenebisphenol (A022E46)
NA
35958-30-6
2.49E-15
7.42E-18
4.06E-19
71.3
339
Tetrachlorobiphenyl
NA
26914-33-0
9.26E-11
1.24E-09
2.60E-10
1.12E+03
426
Tributyl phosphate
NA
126-73-8
4.09E-12
6.08E-12
3.13E-12
44.6
230
Trichlorobiphenyl
NA
25323-68-6
1.00E-10
1.58E-09
1.94E-10
1.06E+03
3.55E+02
Triethyl phosphate (TEP)
NA
78-40-0
5.90E-12
4.01E-13
6.88E-12
44
406
Triethylene glycol bis(3-tert-butyl-4-hydroxy-5-
methylphenyl)propionate (AO-245)
NA
36443-68-2
3.31 E-27
7.83E-30
9.46E-31
2.15E-06
567
Triisobutyl phosphate
NA
126-71-6
6.34E-12
1.97E-10
1.12E-11
94.7
283
Trimethyl phosphate (TMP)
NA
512-56-1
4.74E-12
1.47E-13
6.65E-12
27.2
573
Trimethylsilanol (TMS)
NA
1066-40-6
1.65E-10
9.73E-10
1.73E-08
610
347
Tripropyl phosphate
NA
513-08-6
5.09E-12
5.32E-12
1.79E-11
46.7
351
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
5.32E-13
2.74E-14
2.81E-14
16.4
921
Tris(2-butoxyethyl) phosphate
NA
78-51-3
3.01E-15
3.84E-17
6.19E-17
0.058
255
Tris(2-chloroisopropyl) phosphate
NA
13674-84-5
4.27E-12
6.45E-13
1.29E-12
57.6
711
T ris(2-ethyl hexyl) phosphate (TEHP)
NA
78-42-2
1.35E-12
1.29E-15
1.11E-16
32.6
228
T ris(4-tert-butylphenyl) phosphate
NA
78-33-1
5.91E-13
4.53E-15
1.52E-14
130
885
Tris(methylphenyl) phosphate
NA
1330-78-5
1.31E-11
5.04E-12
2.96E-13
198
495
Notes
CAS = Chemical Abstracts Service
a = Inorganic compound, outside of EPISuite estimation domain
G-12
-------
Biosolids Biennial Review Reporting Period 2018-2019
Table G-5. Physical/Chemical Properties Related to Diffusivity and Transfer Factors as Reported by ORNL for Newly Identified Chemicals in Biosolids
Chemical
PCB congener
#
CAS number
Diffusivity in
air (cm2/s) -
ORNL
Diffusivity in
water (cm2/s) -
ORNL
Beef transfer
coefficient
(day/kg) -
ORNL
Milk transfer
coefficient
(day/kg) -
ORNL
Soil-to-dry
plant uptake -
ORNL
Soil-to-wet
Plant uptake -
ORNL
2,2',3,3',4,4',5-Heptachlorobiphenyl
170
35065-30-6
0.042441369
4.12142E-06
4.655217842
1.471048838
0.00061498
0.000122996
2,2',3,4,4',5,5'-Heptachlorobiphenyl
180
35065-29-3
0.042441369
4.12142E-06
4.655217842
1.471048838
0.00061498
0.000122996
4-Chlorobiphenyl
3
2051-62-9
0.031830682
7.04598E-06
0.001018451
0.00032183
0.081594471
0.016318894
Isodecyl diphenyl phosphate (IDDP)
NA
29761-21-5
0.035566072
4.15561 E-06
0.006885572
0.002175841
0.026931512
0.005386302
Polychlorinated biphenyl (PCB)
NA
1336-36-3
0.024339655
6.26713E-06
0.314731353
0.099455108
0.002934004
0.000586801
Sulfur3
NA
7704-34-9
4.24561 E-08
1.34161 E-08
28.31787951
5.663575902
Tributyl phosphate
NA
126-73-8
0.021184112
5.2338E-06
0.00025
0.000079
0.184272586
0.036854517
Trimethyl phosphate (TMP)
NA
512-56-1
0.058254687
8.7915E-06
5.5968E-09
1.76859E-09
91.71929957
18.34385991
Tris(1,3-dichloro-2-propyl) phosphate (TDCIPP)
NA
13674-87-8
0.033303961
3.8913E-06
0.000111671
3.5288E-05
0.294076777
0.058815355
Tris(2-chloroisopropyl) phosphate
NA
13674-84-5
0.039983811
4.67179E-06
9.72613E-06
3.07346E-06
1.211325137
0.242265027
Tris(2-ethylhexyl) phosphate (TEHP)
NA
78-42-2
0.016451124
3.94248E-06
77.25738581
24.41333392
0.000120576
2.41152E-05
G-13
------- |