EPA-600/R-98-131
October 1998
DEMONSTRATION OF A
NO-VOC/NO-HAP WOOD KITCHEN CABINET COATING SYSTEM
Prepared by:
Eddy W. Huang
AeroVironment Environmental Services, Inc.
222 E. Huntington Drive
Monrovia, CA 91016
EPA Contract No. 68-D5-0128 (Option 2)
EPA Project Officer:
Robert C. McCrillis
U.S. Environmental Protection Agency (MD-61)
National Risk Management Research Laboratory
Air Pollution Prevention and Control Division
Research Triangle Park, NC 27711
Prepared for:
U.S. Environmental Protection Agency
Office of Research and Development
Washington, D.C. 20460
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III lllflllllllllllilll INI III
1. REPORT NO, 2.
EPA-6Q0/ rR_q«/i qt
3. 111 ,l" « ¦¦¦!¦¦¦11'« H • " H IH
PB99-114563
4, TITLE AND SUBTITLE
Demonstration of a No-VOC/No-HAP Wood Kitchen
Cabinet Coating System
5. REPORT DATE
October 1998
6. PERFORMING ORGANIZATION CODE
7. AUTHORtS)
Eddy W. Huang
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
AeroVironment Environmental Services, Inc.
222 E, Huntington Drive
Monrovia, California 91016
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
68-D5-0128 (Option 2)
12. SPONSORING AGENCY NAME AND ADDRESS
EPA, Office of Research and Development
Air Pollution Prevention and Control Division
Research Triangle Park, NC 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final; 4/96 - 8/98
14. SPONSORING AGENCY CODE
EPA/600/13
Ik supplementary notes APpCD project officer is Robert C. McCrillis, Mail Drop 61,
919/541-2733. EPA-600/R-98-019 (NTIS PB98-127301) was EPA base report.
is. abstract rep0rt gives results of the development and demonstration of a no-VOC
(volatile organic compound)/no-HAP (hazardous air pollutant) wood furniture coating
system at two cabinet manufacturing plants: one in Portland, OR, and the other in
Redwood City, CA. Technology transfer efforts were made by presentations at con-
ferences and workshops and publication in journals. Seven wood kitchen cabinet
manufacturers in California's South Coast Basin were surveyed to gain a more in
depth understanding of problems faced when switching from solvent- to water-based
coatings. Although not under this contract, the report also discusses the adaptability
of the coating to metal substrates on chassis components, demonstrated at two large
recreational vehicle manufacturers. It also discusses a preliminary analysis of the
potential for incorporating epoxidized vegetable oils into new resins.
17. KEY WORDS AND OOCUMENT ANALYSIS
DESCRIPTORS
b.IDENTIFIERS/OPEN ENDED TERMS
c. cosati Field/Group
Pollution Toxicity
Coatings
Furniture
Wood Products
V olatility
Organic Compounds
Pollution Control
Stationary Sources
No-VOC/No-HAP
Coatings
13 B 06T
lie
15E
11L
20 M
07C
IB. DISTRIBUTION STATEMENT
Release to Public
19. SECURITY CLASS (This Report/
Unclassified
21. NO. OF PAGES
20. SECURITY CLASS (This page)
Unclassified
22. PRICE
EPA Form 2220-1 (9-73J
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ABSTRACT
The United States Environmental Protection Agency has contracted with AeroVironment
Environmental Services, Inc. and its subcontractor, Adhesive Coatings Co., to develop and
demonstrate a no-VOC (volatile organic compound)/no-HAP (hazardous air pollutant) wood
furniture coating system. The overall objective of this contract was to promote the wider utilization
of low-to-no-VOC/HAP wood furniture coatings. The results of the basic contract, to demonstrate
the application of this coating system to residential wood furniture, have already been published.
The objective of Option 2 (Option 1 was not exercised) of this contract was to demonstrate the
coating system at one or more kitchen cabinet manufacturing plants and to implement the technology
transfer plan to make furniture manufacturers aware of the product's application and performance
characteristics.
This no-VOC/no-HAP coating system was demonstrated at cabinet manufacturing plants in Portland,
OR, and Redwood City, CA . Technology transfer efforts were made by presentations at
conferences and workshops and publication in journals.
A survey of seven wood kitchen cabinet manufacturers in California's South Coast Basin was
conducted to gain a more in depth understanding of the problems they faced when switching from
solvent- to water-based coatings.
Outside of this contract, the adaptability of the coating to metal substrates on chassis components
was demonstrated at two large recreational vehicle manufacturers. Also outside of this contract,
preliminary analysis of the potential for incorporating epoxidized vegetable oils into new resins was
completed.
PROTECTED UNDER INTERNATIONAL COPYRIGHT
ALL RIGHTS RESERVED.
NATIONAL TECHNICAL INFORMATION SERVICE
U.S. DEPARTMENT OF COMMERCE
NOTICE*
This document has been reviewed in accordance with
U.S. Environmental Protection Agency policy and
approved for publication. Mention of trade names
or commercial products does not constitute endorse
ment or recommendation for use.
Reproduced from
best available copy.
ii
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CONTENTS
Section Page
ABSTRACT ii
LIST OF FIGURES iv
ACKNOWLEDGMENTS iv
1.0 INTRODUCTION 1
2.0 DEMONSTRATION 2
3.0 TECHNOLOGY TRANSFER 8
4.0 MANUFACTURER FOLLOW-UP PROGRAM 9
5.0 CONCLUSIONS AND RECOMMENDATIONS 11
6.0 REFERENCES 12
APPENDICES
APPENDIX A-MANUFACTURER TELEPHONE INTERVIEW NOTES A1
APPENDIX B - COATING TECHNICAL DATA SHEETS AND MATERIAL
SAFETY DATA SHEETS B1
B.l. TOP COAT Bl.l
B.2. SANDING SEALER B2.1
B.3. STAIN BASE B3.1
APPENDIX C - CASE STUDIES CI
C.l. FIELD DEMONSTRATION FOR APPLICATION ON METALS Cl.l
C.2. POTENTIAL FORMULATION USING SOY BEAN OIL C2.1
iii
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LIST OF FIGURES
Page
Figure 1. Stanford University library cabinet (doors open) after refmishing with zero VOC/
HAP stain, sanding sealer, and satin topcoat 6
Figure 2. Stanford University library cabinet (doors closed) after refmishing with zero VOC/
HAP stain, sanding sealer, and satin topcoat 7
ACKNOWLEDGMENTS
This study was conducted under USEPA Contract 68D50128 (Option 2) by AeroVironment
Environmental Services, Inc. The author would like to thank the Adhesive Coatings Co. staff for
their technical support, Boden Store Fixtures in Portland, OR, for their participation in the
demonstration, and wood kitchen cabinet coaters for sharing their data and concerns with us.
iv
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1.0 INTRODUCTION
Under United States Environmental Protection Agency (USEPA) sponsorship, AeroVironment
Environmental Services, Inc. and Adhesive Coatings Co. (ADCO) are teamed to develop and
demonstrate a no-VOC (volatile organic compound)/no-HAP (hazardous air pollutant) wood
furniture/cabinet coating system. This two-part system consists, in general, of an epoxy resin
emulsion and an aqueous solution of a reaction product of certain polyamines and urea-formaldehyde
ether monomers1'2,3. The performance characteristics of this new coating system are excellent in
terms of adhesion, drying times, gloss, hardness, mar resistance, level of solvents, and stain
resistance4,5. In Option 2 of this contract, the coating system has been demonstrated by two cabinet
manufacturers. A technology transfer plan was implemented to encourage widespread usage.
A survey of seven kitchen cabinet manu facturers was conducted to gain an understanding of the
effort made by the kitchen cabinet industry to change over to water-based coating systems in general.
Two activities germane to the project but not funded by this EPA contract are described in Appendix
C of the final report. (1) Results of demonstrations by Sierra Performance Coatings at two
recreational vehicle (RV) manufacturers, where the new coating system was evaluated as a rust-
inhibiting coating for chassis components. (2) ADCO undertook a preliminary analysis of the
potential for incorporating epoxidized vegetable oils into new resins.
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2.0 DEMONSTRATION
2.1 Approaches
Many facilities were contacted to find 1 or 2 that would try this no-VOC/no-HAP wood coating.
Information sent to the contacted parties included technical data sheets, material safety data sheets
(MSDS) and published papers. Then, AVES and ADCO staff made follow-up phone calls and/or
visited the facilities who were interested in this system. Wood panels coated with this coating
system were also sent to some of the facilities for their examination and testing. The following is a
list of facilities contacted.
American Classics Cabinetry
7333 Cold Water Canyon, Bid. No. 38
North Hollywood, CA 91605
(818) 503-0485/(818) 503-0542 (FAX)
Asian Neighborhood Design
1232 Connecticut Street
San Francisco, CA 94017
(415) 648-7070/(415) 648-6303 (FAX)
Barbosa Cabinets
5000 Bailey Ave.
Tracy, CA 95376
(209) 836-2501/(209) 836-0847 (FAX)
Becker Zeyko
1030 Marina Village Pkwy.
Alameda, CA 94501
(510) 865-1616
Boden Store Fixtures
41780 Christy Street
Portland, Oregon 97230
(503) 252-4728/(503) 252-4932 (FAX)
Cal Mode Furniture Mfg. Co.
Culver City, CA
(213) 870-4821/(310) 202-0720 (FAX)
Catalina Furniture
La Mirada, CA 90638
(714) 523-7000
Cervitor Kitchens
10775 Lower Azusa
El Monte, CA 91731
(818) 443-0184/(818) 443-0400 (FAX)
Douglas Furniture Corp,
Redondo Beach, CA 90277
(310) 692-7668/(310) 536-0636 (FAX)
Douglas Furniture of California, Inc.
Redondo Beach, CA 90277
(310) 643-7200
Edgewater Cabinets
P.O. Box 127
Boring, OR 97009
(503)663-1341/(503) 663-2523 (FAX)
Eurodesign Cabinets, Inc.
13428 Benson Ave.
Chino, CA 91710
(909) 590-4300
Fairway Painting
1150 University Drive, Suite 109
Menlo Park, CA 94025
(650) 322-4166
G&H Cabinet, Co.
7660 Densmore
Van Nuys, CA 91406
(818) 786-4141
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Gaylan Industries
2106 Glassel
Orange, CA
(714) 282-2284
Gem's Cabinet, Inc.
12201 Magnolia Ave.
Riverside, CA 92503
(909) 371-3530
Houck Industries, Inc.
Tulare, CA 93274
(209) 688-2983
Keller Thomas Woodworks
Redwood City, CA 94063
(415) 369-2468
Kitchen Cabinet Manufacturers Association
1899 Preston White Dr.
Reston, VA 22091-4326
(703) 264-1690
Marge Carson
9056 E. Garvey
Rosemead, CA 91770
(818)571-1111
Monschein Industries, Inc.
6344 Rosclle Ave. Suite 101
Rivcrbank, CA 95367
(209) 869-4514/(209) 869-1464 (FAX)
Quality Cabinets
515 Big Stone Gap Road
Duncanville,TX 75115
(972) 298-6101/(972) 709-7753 (FAX)
Royal Cabinets
Pomona, CA 91769
(909) 629-8565
Snaidero Intl.
201 W 132nd St.
Los Angeles, CA 90061
(310) 516-8499
South Coast Cabinet
755 Pinefalls Ave.
Walnut, CA 91789
(909) 444-1380
Standard Cabinet Works, Inc
Los Angeles, CA 90086
(213) 749-2111
Texas Cabinet Doors, Inc
4078 Shilling Way
Dallas, TX 75237
(423) 586-7233
Virco Mfg. Group
Torrance, CA 90503
(310) 533-0474
W. L. Rubottom Co., Inc.
320 West Lewis Street
Ventura, CA 93001
(805) 648-6943/(805) 648-7856 (FAX)
Walker Wood Products, Inc.
2872 South Santa Fe Ave.
San Marcos, CA 92069-6099
(619) 727-4700/(619) 727-3022 (FAX)
Wambold Furniture
Simi Valley, CA 93065
(805) 526-5200
Western Construction and Engineering
1535 Chestnut Street
Redwood City, CA 94063
(650) 322-4166
Worthern Enterprises, Inc.
Dba Classic Cabinets
4620 Raley Blvd.
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Sacramento, CA 95838
(916) 922-6029/(916) 922-2904 (FAX)
Zelco Cabinet Manufacturing
298 West Robles Ave.
Santa Rosa, CA 95407
(707) 584-1121/(707) 584-5071 (FAX)
2.2 First Demonstration
The first cabinet demonstration was conducted at Boden Store Fixtures, Portland, Oregon, on
September 29,1997. This plant manufactures wood products including cabinets. The purpose of
the demonstration was to show that this new no-VOC/no-HAP wood coating system could be used
successfully on kitchen cabinets. Product Data Sheets and Material Safety Data Sheets can be found
in Appendix B. The following summarizes the demonstration process.
Date; September 29,1997
Place: Boden Store Fixtures
41780 Christy Street
Portland, OR 97203
Present: Robert McCrillis - U.S. Environmental Protection Agency
F.ddy Huang - AcroVironmcnt Environmental Services, Inc.
Gary Effenberger - Boden Store Fixtures
James Shannon, Jr. - Adhesive Coatings Co.
James Birdsall - Adhesive Coatings Co.
Products used: New No-VOC/No-HAP Wood Topcoat Gloss (WTC-96-RT4)
New No-VOC/No-HAP Wood Topcoat Satin (WTC-96-ISA)
New No-VOC/No-HAP Wood Sanding Sealer (WSS-96-25)
New No-VOC/No-HAP Stain Base (WST-96-3)
AVES and ADCO worked with Gary Effenberger ofBoden Store Fixtures, Portland, Oregon to set
up a demonstration on September 29, 1997. During the demonstration, Boden and ADCO staff
applied with a rag, the stain base mixed with Boden's pigmentation to meet their color requirements.
Sanding sealer was then sprayed on the maple "Coffee Story" cabinet custom made for Star Buck
Coffee Stores. This step was performed in the spraying booth. After the sanding sealer was dry
enough to be sanded (in about 15 minutes), the wood surface was lightly sanded. The satin top coat
was then sprayed onto the cabinet. It took about 20 minutes for the top coat to dry. Stain, sanding
sealer, and gloss and satin top coat were also applied to other wood panels including pine, oak, and
mahogany. Boden Store Fixtures staff were quite satisfied with the results. They asked for a gallon
of clear satin top coat so that they could spray it on their current products without having to worry
about matching the color. Boden Store Fixtures staff will try to use existing stains and sealer, then
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apply the new top coat on their products. This type of stepwise conversion is much easier for the
manufacturer to accept.
2.3 Second Demonstration
There is severe water damage in the Stanford University Main Library Basement due to flooding.
Stanford University contracted Fairway Painting (Menlo Park, California) to restore the damaged
cabinets including repainting and re finishing. AVES and ADCO staff contacted Fairway Painting
and set up the arrangement to use ADCO's no-VOC/no-HAP wood cabinet coatings in the
refinishing process.
Demonstration of the new no-VOC/no-HAP wood coating system was conducted at Fairway
Painting's offsite shop (Western Construction and Engineering) at Redwood City, California, on
March 23,1998. This shop specializes in painting and refinishing wood products (including
cabinets). The purpose of the demonstration was to show that this new wood coating system could
be used successfully to finish/refmish cabinets. Product Data Sheets and Material Safety Data
Sheets can be found in Appendix B. The following summarizes the demonstration activity.
Date: March 23, 1998
Place: Western Construction and Engineering
1535 Chestnut Street
Redwood City, CA 94063
Present: Eddy Huang - AeroVironment Environmental Services, Inc.
Harry Finkle - Fairway Painting
Norm Biron - Fairway Painting
Jim Shannon - Adhesive Coatings Co.
Patrick Terrizzi - Adhesive Coatings Co.
Bill Durgall - Sierra Performance Coatings (licensed by ADCO to market the
new coatings)
Products used: New No-VOC/No-HAP Wood Topcoat Satin (S-81 -03)
New No-VOC/No-HAP Wood Sanding Sealer (S-91-03)
New No-VOC/No-HAP Stain Base (S-93-03)
During the demonstration, ADCO staff applied the no-VOC stain base mixed with Fairway
Painting's pigmentation to meet color requirements. The sanding sealer was then sprayed on the
alder cabinet and oak molding pieces. This step was performed in the spraying booth. After the
sanding sealer was dry enough to be sanded (in about 12 minutes), the wood surface was lightly
sanded. A second coat of sanding sealer was then applied on the cabinet surface to improve its
durability. Since the wood surface was filled with the first layer of sanding sealer, it took about 15
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minutes for the second layer of sanding sealer to dry. The topcoat was then applied on the cabinet
surfaces. (See Figures 1 and 2.) It took about 20 minutes for the topcoat to dry to touch. Stain,
sanding sealer, and topcoat were also applied to other wood panels including oak molding. Western
Construction and Engineering staff were quite satisfied with the results.
It should be noted that the coatings dried quickly without leaving any milky appearance, in spite of
the fact that it was a cold, rainy day and the demonstration took place in an old, drafty warehouse. In
fact, dry times were not significantly different from those observed under more favorable weather
conditions.
Figure 1. Stanford University library cabinet (doors open) after refinishing with no-VOC/HAP
stain, sanding sealer, and satin top coat. Nonparallel sides caused by camera closeup lens distortion.
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Figure 2, Stanford University library cabinet (doors closed) after refmishing with no-VOC/HAP
stain, sanding sealer, and satin top coat. Note that nonparallel sides are due to distortion caused by
camera closeup lens.
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3.0 TECHNOLOGY TRANSFER
The following is a summary of the technology transfer efforts made by AVES and ADCO staff for
this contract.
• An article authored by AVES staff (Eddy W. Huang, Ruiling Guan) and EPA Project Officer
(Robert C. McCrillis) and presented at an AWMA Specialty Conference6 was also published in
Coatings World journal7.
• AVES Staff, Eddy Huang was invited to present "No-VOC Coating Technologies" at the
"Pollution Prevention 2000 Conference and Exhibition" held in Southern California Gas
Company Energy Resources Center, Downey, CA, August 7,1997.
• The team prepared and presented new information on no-VOC/no-HAP wood furniture/cabinet
coatings at the "New Technologies for Clean Air" symposium from September 29,1997 through
October 1,1997 in U.C. Irvine, California. This symposium is co-sponsored by the California
Air Resources Board (CARB), the California Air Pollution Control Officers Association, the
U.S. Environmental Protection Agency, and the California Environmental Dialogue. This was a
good opportunity for community outreach and technology transfer.
• AVES and ADCO worked with the EPA Project Officer, Robert C. McCrillis, to present new
information on no-VOC/no-HAP wood furniture/cabinet coatings at the "EPA Pollution
Prevention/Green Manufacturing Conference" held November 17-19,1997 in Atlanta, GA. In
addition to the new coating's performance characteristics, cost analysis and environmental
impac t analysis data were also included in the presentation8. ADCO staff set up an exhibition
booth and displayed wood panels coated with the new stain, sealer, and topcoat. Coating product
data sheets and material safety data sheets were displayed on the table and distributed in the
exhibition. This was the second occasion for community outreach and technology transfer.
• ADCO finalized a licensing agreement with Sierra Performance Coatings, Inc. to manufacture
ADCO's no-VOC coatings; the complete no-VOC/no-HAP wood furniture coating system is
now commercially available.
• Eddy Huang was invited as a conference speaker to present new information on no-VOC/no-
HAP wood furniture/cabinet coatings at the "Emerging Low-Emission Technologies and
Innovative Approaches to Air Pollution Control"symposium on December 5,1997 at the South
Coast Air Quality Management District. In addition to the new coating's performance
characteristics, cost analysis and environmental impact analysis data were also included in the
presentation. This was the third event of the technology transfer efforts.
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4.0 MANUFACTURER FOLLOW-UP PROGRAM
As noted previously, AVES staff contacted many cabinets manufacturers and solicited their
participation in production scale demonstrations. In addition, a survey of seven kitchen cabinet
manufacturers using a variety of water-based coatings (but not the new coating) was conducted to
better understand the problems they faced when switching from solvent-based coatings. The
following is a summary of the survey results. Appendix A contains a brief description of the current
coatings used by the seven companies.
1. Question: What kind of wood is coated at this facility?
Answers:
Type
Oak
Walnut
Maple
Solid
6
1
4
Veneer
6
1
3
Plywood
4
1
1
2. Question: Is the final product finish satisfactory? Any comments about no-/low-VOC coatings?
Answers:
• We are able to overcome the difficulties when converting to water-based coatings
• Happy with the appearance
• The current water-base coating we use dries as fast as the solvent-based coating
• More time is needed for drying and it takes a lot of storage space
• Milking problem
• Difficulties in achieving film thickness
• Since the current (solvent-based) coating system meets the regulations, we don't want to
switch to water-based coating
• Water-base coatings don't pass UV stability test
• Edge soak is an issue when we test water-based coatings
• Can't compete with the quality achieved with the solvent-based coatings
• Positive response in general
3. Question: Are additional steps in your manufacturing process necessary in order to use the no-
/low-VOC coatings you've tried?
Answers:
Yes. (5)
4. Question: Will additional employees be required because of the implementation of no-/low-VOC
coatings?
Answers:
No. (5)
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5. Question: What type of application equipment are you using?
Answers:
HVLP/Air Assisted Airless (5/1)
6. Question: Do you experience any problems cleaning the equipment?
Answers:
Yes/No. As long as you handle it properly. (2/3)
7. Question: Does your coating need to be force dried? Do you have ovens or drying equipment?
Answers:
Yes/No (4a/3)
8. Question: Do you have a conveyor?
Answers:
Yes/No (1/5)
a 3 Gas Ovens and 1IR,
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5.0 CONCLUSIONS AND RECOMMENDATIONS
1. There are water-based coatings available on the market9. Some manufacturers are able to
overcome the difficulties associated with water-based coating (such as grain raising, color
matching and edge soak) when converting from solvent based coatings.
2. The performance characteristics of this new wood coating are excellent. This water-based
coating system drys as fast as many of the solvent-based coating systems and faster than most
combination water/solvent coatings.
3. When using this new no-VOC, no-HAP water-based coating, additional finishing steps may
required. However, most facility owners do not expect to add additional employees.
4. The keys to successful conversion to new water-based coatings are staff training and technical
support from the coating manufacturers. Personnel may need retraining on spraying techniques
for water-based wood coating applications10.
5. As a first step, manufacturers will try to use existing stains and sealer, then apply the no-VOC
top coat on their products. This type of stepwise conversion is much easier for the manufacturer
to accept
6. Demonstrations at two cabinet manufacturing facilities showed that the new coating system was
adaptable to this type of application. Dry times of 15 - 20 minutes for each coat were typical
without use of auxiliary heating, even in humid atmospheric conditions.
7. Independent demonstrations by the coating vendor at two large RV manufacturers showed that
the new coating provided excellent corrosion protection on chassis components. The current
organic solvent-based coating failed the ASTM salt spray test after 192 hours, whereas the new
coating continued on for 1700 hours before showing any sign of failure.
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6.0 REFERENCES
1. U.S. Patent No. 4,812,493, "Dual cure rate water-based coating composition," Adhesive
Coatings Co., San Mateo, CA, March 14,1989.
2. U.S. Patent No. 4,906,726, "Water-based coating compositions containing hydroxides and
oxides of calcium and strontium and barium," Adhesive Coatings Co., San Mateo, CA,
March 6, 1990.
3. Huang, E.W., L. Watkins, and R.C. McCrillis, "Formulating Ultra-Low VOC Wood
Furniture Coatings," Modern Paints and Coatings. Vol. 83, No. 12, November 1993, pg. 41-
43.
4. Huang, E.W., and R.C. McCrillis, "Developing a No-VOC Wood Topcoat," Modern Paints
and Coatings. Vol. 85, No. 7, My 1995, pg. 38-41.
5. Huang, E.W., Development of a No-VQC/No-HAP Wood Furniture Coatings System. EPA-
600/R-98-019 (NTIS PB98-127301), U.S. Environmental Protection Agency, National Risk
Management Research Laboratory, Research Triangle Park, NC, February 1998.
6. Huang, E.W., R. Guan, and R.C. McCrillis, "Demonstration of No-VOC/No-HAP Wood
Furniture Coating System," in Proceedings: Emerging Solutions to VOC and Air Toxics
Control. Air & Waste Management Association, February 25-27, 1997, San Diego, CA,
7. Huang, E.W., Ruiling Guan, and R.C. McCrillis, "Demonstration of a No-VOC/No-HAP
Wood Furniture Coating System," published in: Coatings World. Vol. 2, No. 6,
November/December, 1997, pg. 21-26.
8. McCrillis, R.C., E.W. Huang, and R. Guan, "A No-VOC/No-HAP Wood Furniture Coating
System," presented at EPA Pollution Prevention/Green Manufacturing Conference, Atlanta,
GA, November 17-19,1997.
9. Huang, E.W. and R.C. McCrillis, "Demonstration of No-VOC Wood Topcoat," presented at
the Low- and No-VOC Coating Technologies 2nd Biennial International Conference, Durham,
NC, March 13-15, 1995.
10. Huang, E.W. and R.C. McCrillis, "Source Reduction of VOC and Hazardous Organic
Emissions from Wood Furniture Coatings," in Proceedings: The Emission Inventory: Kev to
Planning. Permits. Compliance and Reporting. New Orleans, LA, Sept. 4-6,1996.
12
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APPENDIX A
MANUFACTURER INTERVIEW NOTES (BY TELEPHONE)
Facility A: A Kitchen Cabinet Manufacturer
Comments:
This is a big kitchen cabinet manufacture in southern California. They are looking for a water-based
coating with very good UV stability. In addition, for 2-component coatings, they are looking for a
special feature; they want to be able to deactivate the mix to prolong the coating shelf life (for
example, overnight). Usually, after part A and part B mixed, the remainder of the coating will be
wasted if not totally consumed. Therefore, an agent to deactivate the mixed coating will be very
useful.
Facility B: A Kitchen Cabinet Manufacturer
Comments:
This facility is using solvent-based coatings. Because the VOC content of the coatings complies
with the current rule limits, they do not intend to switch to water-based coating now. However,
they foresee the switching several years down the road. They have tested some water-based
coatings. Several issues are of concern:
• Drying time
• Grain raising
• Proper cleaning of the gun
Facility C: A Kitchen Cabinet Manufacturer
Comments:
It takes a lot of money to convert to low-VOC coatings. New procedures need to be learned.
Because of longer drying time, large space is needed to store the products. The following properties
need to be improved:
• Grain raising
• Milking
• Film thickness
There are lots of new products on the market; therefore, it takes a lot of effort to test new coating
products.
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Facility D: A Kitchen Cabinet Manufacturer
Comments:
This facility is located in San Francisco. Currently they use solvent-based coatings. Solvent-based
coatings dry very fast. No heating required.
Facility E: A Kitchen Cabinet Manufacturer
Comments:
This company manufactures high-end kitchen cabinets. They have converted to water-based
coatings. They are able to overcome the problems associated with water-based coatings. Grain
raising, color matching and edge soak are the concerns when selecting new coatings.
Facility F: A Kitchen Cabinet Manufacturer
Comments:
This company use both solvent-base and water-base coatings. They like the appearance that water-
base coatings deliver; they dry fast too. Overall cost o f using water-base coating is higher than using
solvent-base coating. They are interested in exploring new water-base coatings.
Facility G: A Kitchen Cabinet Manufacturer
Comments:
Water-base coating have very good mar resistance. The concerns of using water-base coatings are:
• Film thickness
• Making repairs
• Matching color
• Milking
In their experience application procedures are more complex for water-base coatings. A step-wise
change over to a new coating system is the preferred approach. He thinks that appearance of water-
base coating can't compete with solvent-base coating.
A2
-------
APPENDIX B
A nrWPkT^ TIT1 /"•TT\TTr< A T T\ ATP* C* TT17* XT' TiC* A TkTTfc W4T A TPT7>T1T AT OA 17^17 nPI./ ¥V A HP A C*TTT?*^nnC?
COATING TECHNICAL DATA SHEETS AND IVI ATE RIAL SAFETY DATA SHEETS
B1
-------
APPENDIX B.1
TOP COAT
Sierra
Performance Coatings Product Data Sheet
Clear Wood Top Coat Product Code: WTC-97-2
This two component, high performance, water based wood top coat is a hard, durable, chemical and stain resistant interior wood coating that contains
no organic solvents. This wood top coat is designed to be used with the companion Zero VOC Stain and Sanding Sealer for furniture, cabinets and
other wood applications.
Very low odor - no solvent smell
Non-flammable
Chemical and stain resistant
Bright, clear finish
Easily washed and cleaned
Surpasses all VOC air quality regulations
SPECIFICATIONS
Color: Clear
Finish: Gloss & Satin
Pot Life: 6 hours @ 70 °F
Clean Up: Use warm, soapy water
Density: 8.85 #/gal (Mixed System)
Volume Solids: 35%
Weight Solids: 39%
Theor. Coverage @ 2 mils: 270 sq.ft/gal
Flash Point: >350 °F
Shelf Life: > I year
Dry Time; @ 77 °T & 50% RK 3 mil film
To Touch: 30 minutes
To Recoat: 1 hour
Full cure: 1 week
VOC: Coating 0 #/gal, 0 grams per liter
Material 0 #/gal, 0 grams per liter
Viscosity (Part A & B mixed) @ 25°C
#3 spindle @ 12 rpm: 500 cps
Usage: Part A Part B
By Volume 1.0 1.0
By Weight 1.0 1.0
Pencil Hardness: 2H
Intercoat Adhesion: Excellent
KCMA A161.1 1990 Testing
Detergent & Water Resistance: Pass
Edge Test: Pass
Hot Cold Check: Pass
Stain Resistance: 24 hour exposure
Coffee
Grape Juice
Lemon Juice
Orange Juice
Olive Oil
100 Proof Alcohol
Detergent
Mustard (1 hour)
Pint Sol
Fantastic
Simple Green
Bleach
Ketchup
Distilled water
Sierra Performance Coatings, Inc.
2755 Campus Drive, San Mateo, CA 94403 Phone: 415-378-8659 Fax 415-574-3412
For technical assistance, please call: 510-451-2326
Bl.l
-------
MATERIAL SAFETY DATA SHEET
PRODUCT: Wood Top Coat Part A (WTC-97-2)
(PART 1 - GENERAL INFORMATION
Manufacturer: NPCA HMIS Rating
Sierra Performance Coatings, Inc. Health: 1
2755 Campus Drive Flammability: 0
San Mateo, CA 94403 Reactivity: 0
(650)378-8659 Personal Protection: D
Emergency Numbers: 1-800-424-9300 (Chemtrec)
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class:
Revision: 6Date: 10/10/97
Latex Paint
Water Based Epoxy Paint
Water Based Paint, n.o.s.
Not Regulated
[PART 2 - Ingredients
Ingredient Name CAS # % weight OSHAfpeP ACGlH(tlv)
RESILEX™ Epoxy Polymer 025085-99-8 52% N/A N/A
PART % - PHVSTf AI AND fHFMTCAT DATA
JT £ X JL a J* IlJLh/ jL LI »JL' V*—'Jt ¦ 1 ¦/i.VJLJL x1l i t I f i. JL JL ¦>
0 grams/liter and 0 #/gal
0 grams/liter and 0 #/gal
VOC of Material:
VOC excluding water:
Volatile portion: 45 % wt
Specific Gravity: 1.09 @20°C
Solubility in water: Dilutable
Appearance and Odor: Milky White Liquid / mild odor
Conditions and materials to avoid: High temperatures, oxidizing conditions.
Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released
upon decomposition.
Boiling Point: 100°C
pH: 6.5 -7.5
Freezing Point: 0°C
Viscosity: 600.eps
Vapor Pressure: Negligible
PART 4 - FIRE AND EXPLOSION
Flash Point: > 250°C (Method: ISO 3679)
Autoignition temperature: N/DA
Flammable limits (%volume in air) Lower: N/DA Upper: N/DA
Fire and explosion hazards: Not-flammable
Extinguishing media: Dry chemical, C02, Water spray, Foam, Water fog.
Special fire-fighting procedures: Do not enter fire area without special protection. Fight fire from safe
B1.2
-------
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture
closed containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for
cooling. Notify authorities if liquid enters sewer or public waters.
PART 5 - EMERGENCY AND FIRST AID
Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain emergency medical attention, prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious
and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency
medical attention.
Emergency Medical Treatment: Treat symptomatically.
PART 6 - EFFECTS OF EXPOSURE
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its
low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as
coughing, shortness of breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness
and swelling.
Skin absorption: Potential route. Although no data was found for this product, the potential for skin
absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some -
individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated bv exposure: No additional medical information found.
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment.
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
protection should be worn. This equipment should be cleaned after each use.
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation
is recommended.
Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or
using the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower
B1.3
-------
after work using plenty of soap and water.
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility: Strong bases and acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9 - SPILL OR LEAK PROCEDURES
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with
federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Practice caution and personal cleanliness to avoid skin and eye contact Avoid breathing vapors of heated
material.
[PART 11 - REGULATORY INFORMATION
TRANSPORTATION
Not Regulated
PART 12 - LABEL INFORMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant.
May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.
Wash thoroughly after handling.
Do not swallow. Prevent contact with food, chewing or smoking materials.
EYES: Immediately flush with plenty of clean water
INHALATION; Remove to fresh air if effects occur. Consult a physician.
SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.
INGESTION: Give fluids. Call a physician.
NOTE TO PHYSICIAN: No specific antidote. Supportive carc. Treatment based on judgment of
physician in response to reaction of the patient.
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The
information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,
express or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our
control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss,
damage, or expense allsing out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared
and is to be used only for this product If the product is used as a component in another product, this MSDS information may not be applicable.
B1.4
-------
This MSDS has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard {29 CFR 1200).
C:\SierraMSDS\SPCMEA.msd.doc
B1.5
-------
MATERIAL SAFETY DATA SHEET
PRODUCT: WOOD TOP COAT PART B (WTC-97-2)
PART 1 - GENERAL INFORMATION
Manufacturer:.
Adhesive Coatings Co.,
2755 Campus Drive
San Mateo, CA 94403
(415)571-7947
Emergency Numbers:, 1-800-424-9300 (Chemtree)
NPCAHMIS Rating
Health:
Flammability:
Reactivity:
Personal Protection:
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class
Revision: 1 Date: 6/1B/96
Polyamine
Polyamine curing agent
Paint related materials, n.o.s.
:Not regulated
D
PART 2 - ingredients
Ingredient Name
CAS#
%weieht
OSHAfoeh
ACGIHftlv)
Tetraethyienepentbmine (polyamine)
112-57-2
<1%
N/A
N/A
PART 3 - PHYSICAL AND CHEMI
CAL DATA
VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C
VOC excluding water: 0 grams/fiter and 0 #/gal pH: 11,5
Volatile portion: 28.5 % wt Freezing Point: 0°C
Specific Gravity: 1.8 @20°C Viscosity: 900 ± 50 cps
Solubility in water: Dilutable Vapor Pressure: Negligible
Appearance and Odor: Amber milky liquid / slight ammonia odor
Conditions and materials to avoid: High temperatures, oxidizing conditions.
Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released
upon decomposition.
PART 4 - FIRE AND EXPLOSION
Flash Point: >250°C (Method: ISO 3679)
Autoignition temperature: N/DA
Flammable limits (%volume in air) Lower: N/DA Upper: N/DA
Fire and explosion hazards: Not-flammable
Extinguishing media: Dry chemical, C02, Water spray, Foam, Water fog.
Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture
B1.6
-------
closed containers spreading fire and increase the risk of burns and injuries. Use .water spray/fog for
cooling. Notify authorities if liquid enters sewer or public waters.
I PART 5 - EMERGENCY AND FIRST AID
Inhalation: If overcome by exposure, remove victim to fresh air immediately, Give oxygen or artificial
respiration as needed. Obtain emergency medical attention, prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (11 pint) if victim is completely conscious
and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency
medical attention.
Emergency Medical Treatment: Treat symptomatica!!y.
PART 6 - EFFECTS OF EXPOSURE .
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its
low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as
coughing, shortness of breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness
and swelling.
Skin absorption: Potential route. Although no data was found for this product, the potential for skin
absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some
individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated by exposure: No additional medical information found.
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment.
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
protection should be worn. This equipment should be cleaned after each use.
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation
is recommended.
Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or
using the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower
after work using plenty of soap and water.
B1.7
-------
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility: Strong bases and acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9 - SPILL OR LEAK PROCEDURES
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with
federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE;
Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated
material.
jPARTMlT^iB^^
TRANSPORTATION
Not regulated
California Proposition 65: NA
[pARtT^LABELlpNTOiMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant.
May-cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.
Wash thoroughly after handling.
Do not swallow. Prevent contact with food, chewing or smoking materials.
FIRST AID
EYES: Immediately flush with plenty of clean water
INHALATION: Remove to fresh air if effects occur. Consult a physician.
SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.
INGESTION: Give fluids. Call a physician.
NOTE TO PI IYS1CIAN: No specific antidote. Supportive care. Treatment based on judgment of
physician in response to reaction of the patient.
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The
information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,
express or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our
control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss,
damage, or expense arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared
and is to be used only for this product. If the product is used as a component in another product, this IVISDS information may not be applicable.
B1.8
-------
APPENDIX B,2
SANDING SEALER
MATERIAL SAFETY DATA SHEET
PRODUCT: Wood Sanding Sealer, Part 1 (S91-03)
PART 1 - GENERAL INFORMATION
Manufacturer:
Sierra Performance Coatings, Inc.
330 Primrose Road #502
Burlingame, CA 94010
(650) 548-5188
Emergency Numbers: 1-800-424-9300 (Chcmtrec)
NPCA HMIS Rating
Health: 1
Flammability: 0
Reactivity: 0
Personal Protection: D
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class:
Revision: 6 Date: 10/10/97
Latex Paint
Water Based Epoxy Paint
Water Based Paint, n.o.s.
Not Regulated
PART 2 - Ingredients
Ingredient Name
CAS#
%weight OSHA(pel) ACGlHftM
RESILEX™ Epoxy Polymer
025085-99-8 52%
N/A
N/A
PART 3 - PHYSICAL AND CHEMICAL DATA
VOC of Material: 0 grams/liter and 0 #/gal
VOC excluding water: 0 grams/liter and 0 #/gal
Volatile portion: 45 % wt
Specific Gravity: 1.09 @20°C
Solubility in water: Dilutable
Appearance and Odor: Milky White Liquid / mild odor
Conditions and materials to avoid: High temperatures, oxidizing conditions.
Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon
decomposition.
Boiling Point: 100°C
pH: 6.5 - 7.5
Freezing Point: 0°C
Viscosity: 600 +/- 200 cps
Vapor Pressure: Negligible
PART 4 - FIRE AND EXPLOSION
B2.1
-------
Flash Point; > 250°C (Method: ISO 3679)
Autoignition temperature: N/DA
Flammable limits (%volume in air) Lower: N/DA Upper: N/DA
Fire and explosion hazards: Not-flammable
Extinguishing media: Dry chemical, CO„ Water spray, Foam, Water fog.
Special fire-fighting procedures: Do not enter fire area without special protection. Fight fire from safe
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed
containers spreading fire and increase the risk of bums and injuries. Use water ^pray/fog for cooling.
Notify authorities if liquid enters sewer or public waters.
PART 5 - EMERGENCY AND FIRST AID
Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain emergency medical attention, prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious
and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency
medical attention.
Emergency Medical Treatment: Treat symptomatically.
PART 6 - EFFECTS OF EXPOSURE
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its
low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as
coughing, shortness of breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness
and swelling.
Skin absorption: Potential route. Although no data was found for this product, the potential for skin
absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some
individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated bv exposure: No additional medical information found.
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment.
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
B2.2
-------
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
protection should be worn. This equipment should be cleaned after each use.
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation
is recommended.
Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using
the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work
using plenty of soap and water.
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility: Strong bases and acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9 - SPILL OR LEAK PROCEDURES
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with
federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated
material.
PART 11 - REGULATORY INFORMATION
TRANSPORTATION
Not Regulated
PART 12 - LABEL INFORMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant.
May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.
Wash thoroughly after handling. Do not swallow. Prevent contact with food, chewing or smoking
materials.
B2.3
-------
FIRST AID
EYES; Immediately flush with plenty of clean water
INHALATION: Remove to fresh air if effects occur. Consult a physician,
SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.
INGESTION: Give fluids. Call a physician.
NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of
physician in response to reaction of the patient.
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information
in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or
implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense
arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only
for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been
prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).
C:\SierraMSDS\SPCMEA.msd.doc
B2.4
-------
MATERIAL SAFETY DATA SHEET
PRODUCT: WOOD SANDING SEALER - PART 2 (S91-03)
PART 1 - GENERAL INFORMATION
Manufacturer:
Sierra Performance Coatings, Inc.
330 Primrose Road #502
Burlingame, CA 94010
(650) 548-5188
Emergency Numbers; 1-800-424-9300 (Chemtrec)
NPCA HMIS Rating
Health: 1
Flammability: 0
Reactivity: 0
Personal Protection: D
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class:
Revision: 1 Date: 6/18/96
Polyamine /latex blend
Polyamine curing agent
Paint related materials, n.o.s.
Not regulated
PART 2 - Ingredients
Ineredient Name CAS #
%weieht
OSHAfoeD
ACGIHftlvl
RESILINK™ B-2003 (polyamine) 170904-70-8
<1.2%
N/A
N/A
PART 3 - PHYSICAL AND CHEMICAL DATA
0 grams/liter and 0 #/gal
0 grams/liter and 0 #/gal
VOC of Material:
VOC excluding water:
Volatile portion: 70 % wt
Specific Gravity: 1.03 @20°C
Solubility in water: Dilutable
Appearance and Odor: Amber milky liquid / slight ammonia odor
Conditions and materials to avoid: High temperatures, oxidizing conditions.
Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon
decomposition.
Boiling Point:. 100°C
pH: 9.5-10.0
Freezing Point: 0°C
Viscosity: 900 ±150 cps
Vapor Pressure: Negligible
PART 4 - FIRE AND EXPLOSION
Flash Point: > 250°C (Method: ISO 3679)
Autoignition temperature: N/'DA
Flammable limits (%volume in air) Lower: N/DA
Upper: N/DA
B2.5
-------
Fire and explosion hazards; Not-flammable
Extinguishing media: Dry chemical, C02, Water spray, Foam, Water fog.
Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed
containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for cooling.
Notify authorities if liquid enters sewer or public waters.
PART 5 - EMERGENCY AND FIRST AID
Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain emergency medical attention, prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious
and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency
medical attention.
Emergency Medical Treatment: Treat symptomatically.
PART 6 - EFFECTS OF EXPOSURE
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its
low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as
coughing, shortness of breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness
and swelling.
Skin absorption: Potential route. Although no data was found for this product, the potential for skin
absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some
individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated by exposure: No additional medical information found.
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment.
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
protection should be worn. This equipment should be cleaned after each use.
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation
B2.6
-------
is recommended.
Other Hygienic Practices: Emergency eye wash fountains and safely showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using
the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work
using plenty of soap and water.
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility; Strong bases and acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9 - SPILL OR LEAK PROCEDURES
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with
federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated
material.
PART 11 - REGULATORY INFORMATION
TRANSPORTATION
Not regulated
California Proposition 65: NA
PART 12 - LABEL INFORMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant.
May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.
Wash thoroughly after handling. Do not swallow. Prevent contact with food, chewing or smoking
materials.
FIRST AID
EYES: Immediately flush with plenty of clean water
INHALATION: Remove to fresh air if effects occur. Consult a physician.
SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.
B2.7
-------
INGESTION: Give fluids. Call a physician.
NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of
physician in response to reaction of the patient.
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information
in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or
implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense
arising out of or in any way connected with the handling, storage, use, or disposal of the product This MSDS was prepared and is to be used only
for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been
prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200).
C:\adco\msds\wss961 Sb.msd
B2.8
-------
Sierra
Performance Coatings Product Data Sheet
Wood Sanding Sealer Product Code: WSS-96-25
This two component epoxy/acrylic, clear sanding sealer is a fast drying sealer that provides a sandable surface for wood
finishing that contains no organic solvents. This sanding sealer is designed to be used with the companion Zero VOC Stain
and Top Coat,
Very low odor - no solvent smell
Non-flammable
Sandable
Fast Drying
Surpasses all VOC air quality regulations
SPECIFICATIONS
Color; Clear
When used with ADCO Wood Top Coat
Finish: Matte
Intercoat Adhesion: Excellent
Pot Life: 6 hours @ 70°F
KCMA A161.1 1990 Testing
Clean Up: Use warm, soarp water
Detergent & Water Resistance: Pass
Density: 8.7 #/gal (Mixed System)
Edge Test: Pass
Volume Solids: 27. 1 %
Hot Cold Check: Pass "
Weight Solids: 30.1%
Stain Resistance: 24 hour exposure
Theor. Coverage @ I mils: 435 sq.ft/gal
Coffee
Flash Point: >3 50 T
Grape Juice
Shelf Life: > 1 year
Lemon Juice
Dry Time: @ 77 °F & 50% RKI mil film
Orange Juice
To Touch: 15 minutes
Olive Oil
To Re-oat: 20 minutes
100 proof alcohol
VOC: Coating 0 #/gal, 0 grams per liter
Detergent
Material 0#/gal, 0 grams per liter
Mustard (I hour)
Viscosity (Part A & B mixed) @ 25 "C
Pine Sol
#3 spindle @ 12 rpm: 500 cps
Fantastic
Usage: Part A Part B
Simple Green
By Volume 1.0 4.0
Bleach
By Weight 1.0 4.0
Ketchup
Distilled water
Sierra Performance Coatings, Inc.
2755 Campus Drive, San Mateo, CA 94403 Phone: 415-378-8659 Fax: 415-574-3412
For technical assistance, please call; 510-451-2326
B2.9
-------
MATERIAL SAFETY DATA SHEET
PRODUCT: Wood Sanding Sealer Part A (WSS-96-25)
PART I - GENERAL INFORMATION
Manufacturer:
NPCA HMIS Rating
Sierra Performance Coatings, Inc.
Health:
1
2755 Campus Drive
Flammability:
0
San Mateo, CA 94403
Reactivity:
0
(650)378-8659
Personal Protection:
D
Emergency Numbers: 1-800-424-9300 (Chemtrec)
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class:
Revision: 6 Date: 10/10/97
Latex Paint
Water Based Epoxy Paint
Water Based Paint, n.o.s.
Not Regulated
PART 2 - Ingredients
Ingredient Name CAS # %weight OSHAfflefi ACGIHCtlv)
RHSILEX1"1 Epoxy Polymer 025085-99-8 52% N/A N/A
PART 3 - PHYSICAL AND CHEMICAL DATA
VOC of Material: 0 grams/liter and 0 #/gal Boiling Point: 100°C
VOC excluding water: 0 grams/liter and 0 #/gal pH: 6,5 - 7.5
Volatile portion: 45 % wt Freezing Point: 0°C
Specific Gravity: 1.09 @20°C Viscosity: 600 cps
Solubility in water: Dilutable Vapor Pressure: Negligible
Appearance and Odor: Milky White Liquid / mild odor
Conditions and materials to avoid: High temperatures, oxidizing conditions.
Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon
decomposition.
PART 4 - FIRE AND EXPLOSION
Flash Point: > 250°C- (Method: ISO 3679)
Autoignition temperature: N/DA
B2.10
-------
Flammable limits (%volume in air) Lower: N/DA Upper: N/DA
Fire and explosion hazards: Not-flammable
Extinguishing media: Dry chemical, C02, Water spray, Foam, Water fog.
Special fire-fighting procedures: Dc not enter fire irea without special protection. Fight fire from safe
distance or protected location. Heat or impurities may increase temperature, build pressire, rupture closed
containers spreading fire and increase the risk of burns and injuries. Use water spray 1 fog for cooling.
Notify authorities if liquid enters sewer or public waters.
PART 5 - EMERGENCY AND FIRST AID
Inhalation: If Overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain emergency medical attention, prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly-with mild soap and water.
Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious
and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency
medical attention.
Emergency Medical Treatment: Treat symptomatically.
PART 6 - EFFECTS OF EXPOSURE
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its
low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as
coughing, shortness of breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness
and swelling.
Skin absorption: Potential route. Although no data was found for this product, the potential for skin
absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause -.n allergic skin reaction in some
individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated bv exposure: No additional medical information found.
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment.
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
B2.ll
-------
protection should be worn. This equipment should be cleaned after each use.
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation is
recommended.
Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using
the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work
using plenty of soap and water.
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility: Strong bases and acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9 - SPILL OR -LEAK PROCEDURES
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with
federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated
material.
PART 11 - REGULATORY INFORMATION
TRANSPORTATION
Not Regulated
PART 12 - LABEL INFORMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant.
May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.
Wash thoroughly after handling.
Do not swallow. Prevent contact with food, chewing or smoking materials.
FIRST AID
B2.12
-------
EYES: Immediately flush with plenty of clean water
INHALATION: Remove to fresh air if effects occur. Consult a physician.
SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower,
INGESTION: Give fluids. Call a physician.
NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of physician
in response to reaction of the
patient.
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information
in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or
implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense
arising out ofor in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only
for this product If the product is used as a component in another product, this MSDS information may not be applicable, This MSDS has been
prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200). C:\SierraMSDS\SPCMEA.msd.doc
B2.13
-------
MATERIAL SAFETY DATA SHEET
PRODUCT: WOOD SANDING SEALER - PART B (WSS-96-25)
PART 1 - GENERAL INFORMATION
Manufacturer:
Adhesive Coatings Co.
2755 Campus Drive
San Mateo, CA 94403
(415)571-7947
NPCAHMIS Rating
Health:
Flammability:
Reactivity:
Personal Protection:
1
D
Emergency Numbers: 1-800-424-9300 (Chemtrec)
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class:
Revision: 1 Date: 6/18/96
Polyamine /LATEX BLEND
Polyamine curing agent
Paint related materials, n.o.s.
Not regulated
PART 2 - Ingredients
Ingredient Name CAS#
%weiaht
OSHAfoel) ACGIHftlv")
RESILINK- B-2003 (polyamine) 170904-70-8
<1.2%
N/A N/A
PART 3 - PHYSICAL AND CHEMICAL DATA
VOC of Material: 0 grams/liter and 0 #/gal
VOC excluding water: 0 grams/liter and 0 #/gal
Volatile portion: 70 % wt
Specific Gravity: 1.03 @20 °C
Solubility in water: Dilutable
Boiling Point: 100°C
pH: 9.5-10,0
Freezing Point': 0°C
Viscosity: 900 ± 50 cps
Vapor Pressure: Negligible
Appearance and Odor: Amber milky liquid / slight ammonia odor
Conditions and materials to avoid: High temperatures, oxidizing conditions.
Hazardous decomposition products: Acrid smoke, fames, carbon monoxide/dioxide may be released upon
decomposition.
PART 4 - FIRE AND EXPLOSION
Flash Point: > 250°C (Method: ISO 3679)
Autoignition temperature: N/DA
Flammable limits (%volume in air) Lower N/DA
Fire and explosion hazards: Not-flammable
Upper: N/DA
B2.I4
-------
Extinguishing media: Dry chemical, C02, Water spray, Foam, Water fog.
Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed
containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for cooling.
Notify authorities if liquid enters sewer or public waters.
PART 5 - EMERGENCY AND FIRST AID
Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain emergency medical attention, prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for
15 minutes. If sticky, use waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (11 pint) if victim is completely conscious
and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency
medical attention.
Emergency Medical Treatment: Treat symptomatically.
PART 6 - EFFECTS OF EXPOSURE
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to Its
low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as
coughing, shortness of breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness
and swelling.
Skin absorption: Potential route. Although no data was found for this product, the potential for skin
absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some
individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated by exposure: No additional medical information found.
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment.
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
protection should be worn. This equipment should be cleaned after each use.
B2.15
-------
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation is
recommended.
Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using
the toilet facilities. Promptly
remove soiled clothing and wash thoroughly before reuse. Shower after work using plenty of soap and
water.
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility- Strong bases and acids.
Hazardous Polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9-SPILL OR LEAK PROCEDURES , |
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting.
Flush contaminated area with water. Dispose in accordance with federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice caution and
personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated material.
PART 11 - REGULATORY INFORMATION
TRANSPORTATION
Not regulated
California Proposition 65: NA
PART 12 - LABEL INFORMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant.
May, cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.
Wash thoroughly after handling.
Do not swallow. Prevent contact with food, chewing or smoking materials.
FIRST AID
B2.16
-------
EYES: Immediately flush with plenty of clean water
INHALATION: Remove to fresh air if effects occur. Consult a physician.
SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.
INGESTION: Give fluids. Call a physician.
NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of physician
in response to reaction of the patient.
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information
in this IV1SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or
implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense
arising out of or in any way connected with the handling, storage, use, or disposal of the product This MSDS was prepared and is to be used only
for this product. If the product is used as a component in another product, this 1V1SDS information may not be applicable. This MSDS has been
prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200). C:\adco\msds\wss9616b.msd
W2.ll
-------
Sierra
Performance Coatings
APPENDIX B.3
STAIN BASE
Product Data Sheet
Wood Stain Base Product Code: WST-96-3
This fast dry ing stain base can be colored with a variety of water dispersed pigments, dyes and tints into
a wide variety of hues, colors and stains and contains ag organic solvents. This stain base is designed to
be used with the companion Zero VOC Sanding Scaler and Top Coat
Very low odor - no solvent smell
Non-flammable
Fast drying
Improves corrosion resistance
Surpasses all VOC air quality regulations
SPECIFICATIONS
Color: Clear
VOC: Coating 0 #gal, 0 grams per liter
Finish: Matte
Material 0 #/gal, 0 gram per liter
Pot Lift: 6 hours
Clean Up: Warm, soapy water
Viscosity (Part A & B mixed) @ 25 °C
Density: 8.6 #/gal (Mixed system)
#3 spindle @ 12 rpm: 500 cps
Volume Solids: 17.8%
Weight Solids: 19.8%
Theor. Coverage @ 1 mils: 285 sq.ft/gal
Flash Point: > 350 °F
Shelf Life: > I year
Dry Time: @ 77°F & 50% RH, 1 mil film
To Touch: 15 minutes
To Re coat: 15 minutes
Sierra Performance Coatings, Inc.
2755 Campus Drive, San Mateo, CA 94403 Phone: 415-378-8659 Fax: 415-574-3412
For technical assistance, please call: 510-451-2326
B3.1
-------
MA TERIAL SAFETY DATA SHEET
PRODUCT: WOOD STAIN BASE (WST-96-3)
PART 1 - GENERAL INFORMATION
Manufacturer:
Adhesive Coatings Co.
2755 Campus Drive
San Mateo, CA 94403
(415)571-7947
NPCA HMiS Rating
Health: 1
Flammability: 0
Reactivity: 0
Personal Protection: D
Emergency Numbers: 1-800-424-9300 (Chemtrec)
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class:
Revision: 1 Date: 6/18/96
Latex Paint
Water Based Stain
Water Based Paint, n.o.s.
Not Regulated
PART 2 - Ingredients
Ingredient Name CAS # %weieht
OSHA(pel)
ACGIH(tlv)
Acrylic Polymer N/A 15%
N/A
N/A
PART 3 - PHYSICAL AND CHEMICAL DATA
0 grams/liter and 0 #/gal
0 grams/liter and 0 #/gal
VOC of Material:
VOC excluding water:
Boiling Point: 100°C
pH: 6.0 - 7.0
Volatile portion: 80.1 % wt
Freezing Point: 0°C
Specific Gravity: 1.03 @20 °C
Viscosity: 500;± 50 cps
Solubility in water: Slight
Vapor Pressure: Negligible
Appearance and Odor: Milky white liquid/mild odor Conditions and materials to avoid: High
temperatures, oxidizing conditions. Hazardous decomposition products: Acrid smoke, fumes, carbon
monoxide/dioxide may be released upon decomposition.
Stability: Stable
B3.2
-------
PART 4 - FIRE AND EXPLOSION
Flash Point: > 212°C (Method: ISO 3679)
Autoignition temperature: N/DA
Flammable limits (%volume in air) Lower: N/DA Upper: NIDA
Fire and explosion hazards: Not-flammable
Extinguishing media: Dry chemical,CO,,Water spray, Foam, Water fog.
Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture
closed containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for
cooling. Notify authorities if liquid enters sewer or public waters.
PART 5 - EMERGENCY AND FIRST AID
Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give
oxygen or artificial respiration as needed. Obtain emergency medical attention,
prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for
20 - 30 minutes. Retract eyelids often. Obtain emergency medical attention if pain,
blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly
with rriild soap and water. Flush with lukewarm water for 15 minutes. If sticky, use
waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is
completely conscious and alert. Do not induce vomiting, risk of damage to lungs
exceeds poisoning risk. Obtain emergency medical attention.
Emergency Medical Treatment: Treat symptomatically.
PART 6 - EFFECTS OF EXPOSURE
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at
standard conditions due to its low volatility. However, overexposure to
mists/aerosols may cause respiratory tract irritation such as coughing, shortness of
breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include
tearing, blinking, redness and swelling.
Skin absorption: Potential route. Although no data was found for this product, the
potential for skin absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause an allergic
skin reaction in some individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated by exposure: No additional medical information'
found.
B3.3
-------
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment.
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
protection should be worn. This equipment should be cleaned after each use.
Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation
is recommended.
Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or
using the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower
after work using plenty of soap and water.
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility: Strong bases and acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9 - SPILL OR LEAK PROCEDURES
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with
federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Practice caution and
personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated material.
PART 11 - REGULATORY INFORMATION
None required for this product.
PART 12 - LABEL INFORMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant. May cause allergic
reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist. Wash thoroughly
B3.4
-------
after handling. Do not swallow. Prevent contact with food, chewing or smoking materials.
FIRST AID
Eves: Immediately flush with plenty of clean water
Inhalation: Remove to fresh air if effects occur. Consult a physician.
Skin contact: Wash thoroughly with mild soap and flowing water or shower.
Ingestion: Give fluids. Call a physician.
NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of
physician in response to reaction of the patient.
SPILLS
Avoid all personal contact. Take up with absorbent material. Shovel into closed container. Flush
contaminated area with water. Dispose of collected materials in accordance with federal, state, and local
regulations. Avoid breathing vapors of heated material.
DISCLAIMERS
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The
information in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty,
express or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our
control and may he beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss,
damage, or expense arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared
and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
This MSDS has been prepared in accordance with the requirements of the OSHA Hazard Communication Standard (29 CFR 1200),
B3.5
-------
MATERIAL SAFETY DATA SHEET
PRODUCT: WOOD STAIN BASE (S93-03)
PART 1 - GENERAL INFORMATION
Manufacturer:
Sierra Performance Coatings, Inc.
330 Primrose Road #502
Burlingame, CA 94010
(650)548-5188
NPCA HMIS Rating
Health: 1
Flammability: 0
Reactivity: 0
Personal Protection: D
Emergency Numbers: 1-800-424-9300 (Chemtrec)
Chemical Family:
Generic Name:
DOT Proper Shipping Name:
DOT Hazard Class:
Revision: 1 Date: 6/18/96
Latex Paint
Water Based Stain
Water Based Paint, n.o.s.
Not Regulated
PART 2 - Ingredients
Ingredient Name
CAS# %weisht OSIIAfpeD ACGIHftlvl
Acrylic Polymer
N/A
<15%
N/A
N/A
PART 3 - PHYSICAL AND CHEMICAL DATA
VOC of Material: 0 grams/liter and 0 #/gal
VOC excluding water: 0 grams/liter and 0 #/gal
Volatile portion: 80 % wt
Specific Gravity: 1.03 @20°C
Solubility in water: Slight
Appearance and Odor: Milky white liquid/mild odor
Conditions and materials to avoid: High temperatures, oxidizing conditions.
Hazardous decomposition products: Acrid smoke, fumes, carbon monoxide/dioxide may be released upon
decomposition.
Stability: Stable
Boiling Point: 100°C
pH: 6.0 - 7.0
Freezing Point: 0°C
Viscosity: 200 ±150 cps
Vapor Pressure: Negligible
PART 4 - FIRE AND EXPLOSION
Flash Point: > 212°C (Method: ISO 3679)
Autoignition temperature: N/DA
Flammable limits (%volume in air) Lower: N/DA
Upper: N/DA
B3.6
-------
Fire and explosion hazards: Not-flammable
Extinguishing media: Dry chemical, CO,, Water spray, Foam, Water fog.
Special firefighting procedures: Do not enter fire area without special protection. Fight fire from safe
distance or protected location. Heat or impurities may increase temperature, build pressure, rupture closed
containers spreading fire and increase the risk of burns and injuries. Use water spray/fog for cooling.
Notify authorities if liquid enters sewer or public waters.
PART 5 - EMERGENCY AND FIRST AID
Inhalation: If overcome by exposure, remove victim to fresh air immediately. Give oxygen or artificial
respiration as needed. Obtain emergency medical attention, prompt action is essential.
Eve Contact: In case of eye contact, immediately flush eyes with clean water for 20 - 30 minutes. Retract
eyelids often. Obtain emergency medical attention if pain, blinking, tears, or redness persist.
Skin Contact: Remove contaminated clothing as needed. Wash skin thoroughly with mild soap and water.
Flush with lukewarm water for 15 minutes. If sticky, use waterless hand cleaner first.
Ingestion: If large quantity is swallowed, give lukewarm water (1 pint) if victim is completely conscious
and alert. Do not induce vomiting, risk of damage to lungs exceeds poisoning risk. Obtain emergency
medical attention.
Emergency Medical Treatment: Treat symptomatieally.
PART 6 - EFFECTS OF EXPOSURE
Routes of exposure:
Inhalation: This material is not expected to present an inhalation hazard at standard conditions due to its
low volatility. However, overexposure to mists/aerosols may cause respiratory tract irritation such as
coughing, shortness of breath, and mucus production.
Eve Contact: Potential route. May cause eye irritation. Symptoms may include tearing, blinking, redness
and swelling.
Skin absorption: Potential route. Although no data was found for this product, the potential for skin
absorption does exist.
Skin Irritation: Potential route. May produce skin irritation. May cause an allergic skin reaction in some
individuals after repeated skin contact.
Ingestion: This material may be a health hazard if ingested in large quantities.
Medical conditions aggravated by exposure: No additional medical information found.
PART 7 - PROTECTIVE EQUIPMENT AND CONTROL MEASURES
Respiratory Protection: If this material is handled under mist forming conditions, use NIOSH/MSHA
approved respiratory protection equipment
Eve Protection: Eye protection such as chemical splash goggles and/or face shield must be worn when
possibility exists for eye contact due to splashing or spraying, liquid, airborne particles, or vapor. Contact
lenses should not be worn.
Skin Protection: Depending on the conditions for use, protective gloves, apron, boots, head, and face
protection should be worn. This equipment should be cleaned after each use. ,
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Engineering Controls: If handling results in mist or aerosol or vapor generation, local exhaust ventilation
is recommended.
Other Hygienic Practices: Emergency eye wash fountains and safety showers should be available in the
immediate vicinity of any potential exposure.
Other Work Practices: Use good personal hygiene. Wash hands before eating, drinking, smoking, or using
the toilet facilities. Promptly remove soiled clothing and wash thoroughly before reuse. Shower after work
using plenty of soap and water.
PART 8 - REACTIVITY DATA
Stability: Stable
Incompatibility: Strong bases and acids.
Hazardous polymerization: Will not occur.
Hazardous decomposition: Will not occur.
PART 9 - SPILL OR LEAK PROCEDURES
Avoid all personal contact. Take up with absorbent material. Scoop and vacuum up, place in closed
container for disposal. Avoid dusting. Flush contaminated area with water. Dispose in accordance with
federal, state, and local regulations.
PART 10 - STORAGE AND SPECIAL PRECAUTIONS
SPECIAL PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Practice caution and personal cleanliness to avoid skin and eye contact. Avoid breathing vapors of heated
material.
PART 11 - REGULATORY INFORMATION
None required for this product.
PART 12 - LABEL INFORMATION
FOR INDUSTRIAL USE ONLY!! Skin contact hazard. Eye and skin irritant
May cause allergic reaction. Avoid contact with eyes, skin, and clothing. Do not breath vapors or mist.
Wash thoroughly after handling. Do not swallow. Prevent contact with food, chewing or smoking
materials.
FIRST AID
EYES: Immediately flush with plenty of clean water
INHALATION; Remove to fresh air if effects occur. Consult a physician.
SKIN CONTACT: Wash thoroughly with mild soap and flowing water or shower.
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INGESTION: Give fluids. Call a physician.
NOTE TO PHYSICIAN: No specific antidote. Supportive care. Treatment based on judgment of
physician in response to reaction of the patient.
SPILLS
Avoid all personal contact. Take up with absorbent material. Shovel into closed container. Flush
contaminated area with water. Dispose of collected materials in accordance with federal, state, and local
regulations. Avoid breathing vapors of heated material.
DISCLAIMERS
Some of the information presented and conclusions drawn herein are from sources other than direct test data on the product itself. The information
in this MSDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or
implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the product are beyond our control and may
be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage, or expense
arising out of or in any way connected with the handling, storage, use, or disposal of the product. This MSDS was prepared and is to be used only
for this product. If the product is used as a component in another product, this MSDS information may not be applicable. This MSDS has been
prepared in accordance with the requirements of the OS11A Hazard Communication Standard (29 CFR 1200).
C:\adco\msds\WST963_msd
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APPENDIX C
CASE STUDIES
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APPENDIX C.l
FIELD DEMONSTRATIONS FOR APPLICATION ON METALS
This No-VOC coating technology can formulate coatings that are applied not only on wood
products, but also on metals. AVES, working jointly with ADCO, formulated a state of the art
metal coating and demonstrated the potential for commercialization of this metal coating system.
Performance features of this new no-VOC industrial maintenance coating are:
• Requires no solvents.
• Delivers hardness with flexibility.
• Versatile—compatible with most lattices.
• Increases toughness/scrub resistance.
• Increases chemical resistance.
• Decreases dry times in slow dry systems.
• Aids in coalescence to allow reduction or elimination of solvents.
Demonstrations of the new metal coating system were conducted at two manufacturing facilities.
The purpose of the demonstrations was to show that this new coating system could be used
successfully in a commercial metal finishing operation. The following summarizes the
demonstration processes.
C.1.1. Demonstrations at Facility A
Facility A manufactures motor homes. The operations at the Riverside facility include wood and
metal coatings, metal fabrication, wood and metal cutting, drywall fabrication, and engine
mounting. One of metal coatings involves coating of the metal chassis and structural beams of
the motor homes. The metal chassis provides the motor home frame on which other components
such as wheels and engine are mounted. The structural beams are referred to as Paco beams.
The metal Paco beams are mounted on top of the chassis, forming the sides and bottom of the
motor home.
Facility A coats the chassis and Paco beams to provide rust protection. The coating operation is
conducted inside a large spray booth with a dimension of 48' L. x 22' W. x 12' H. Current
coating system used is a compliant coating with a VOC content of 1.2 lb/gal. Approximately,
half of a gallon is used for a singe chassis. The coating is applied using a high volume/ low
pressure (HVLP) gun. Four 5-HP fans exhaust the coating fumes from the spray booth.
Since the motor home is manufactured using an assembly line process, dry time is a critical
parameter. The current coating system dry time is approximately half an hour. Depending on
ambient temperature, the dry time for the current compliant coating product could vary
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substantially (from 1/2 hour on a dry day to 2 days on high humidity days).
Demonstration. Conducted on January 20, 1998
Representatives of AVES, ADCO, GRACO Equipment Manufacturer, and Butler Compressor &
Spray Equipment Co. conducted testing at Facility A on January 20,199&. Two sets of a regular
RV chassis platform and several metal pieces were coated with ADCO's no-VOC metal coatings.
The chassis surfaces were dry quickly. However, the Production Supervisor of Facility A
suggested that the painting be done by a professional painter, because the testing took too long
and the production schedule allowed only 30 minutes per chassis.
Staff took the plant's advise and brought a professional painter from Fairway Painting to Facility
A on January 28,1998. Two sets of a Paco-Beam RV chassis platform were coated. The first set
of Paco-Beam RV chassis platform was coated within 40 minutes and consumed 1.5 gallons of
coating. The painter changed the air pressure of the spray gun and reduced overspray from the
second set of Paco-Beam RV chassis platform. About 1.25 gallons of coating was consumed for
the second set of RV chassis. At 65°F temperature and 78% relative humidity, the coated chassis
surface was dry in less than 30 minutes. Facility A staff was satisfied with the demonstration
results.
C.1.2. Demonstrations at Facility B
Facility B also manufactures motor homes. The process is very similar to the process at Facility
A. Facility B is planning a large expansion, and is thus expressing high interest in a non-VOC
coating like the ADCO system.
Currently, Facility B does not coat the whole chassis and Paco beam. Only the metal weld joints
on the chassis and Paco are coated using aerosol cans. The joints are coated for rust protection.
The coating is conducted outdoors without any confinement. The current coating system used
has a VOC content of 2 lb/gal. Facility B indicates that rust protection is a major issue. Another
critical parameter is dry time. Half an hour is an acceptable dry time for the coating process.
Demonstration. Conducted on January 12. 1998
Representatives of AVES, ADCO, GRACO Equipment Manufacturer, and Butler Compressor &
Spray Equipment Co. conducted testing at Facility B on January 12,1998. The purposes of this
testing were: (1) to test the feasibility of the in-situ mixing spray gun to avoid premixing a two
part component coating system, and (2) to coordinate with Facility B personnel to expand the no-
VOC metal coating application (both RV chassis and trailer chassis). Two sets of power-
structure RV chassis platform were coated with ADCO's no-VOC metal coatings. The first set of
power-structure RV chassis platform was slightly overcoated and resulted in dripping. Butler
Compressor & Spray Equipment Co. staff changed the tip size of the spray gun and reduced
dripping from the second set of power-structure RV chassis platform. About 1 to 1.25 gallons of
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coating was consumed for each set of RV chassis. Even if it was a cold day (temperature less
than 55°F outdoors), the coated chassis surfaces were dry in about 30 minutes. After completion
of these two sets of power-structure RV chassis platform, the engineering services manager of
Facility B asked staff to coat a rusted trailer chassis to see whether this new no-VOC metal
coating can be applied to rusted surfaces and protect the surfaces from further corrosion. About
1.5 gallons of coating was used to cover this big trailer chassis. Facility B was satisfied with the
demonstration results.
C.1.3. Coating Comparison
Comparison of No-VOC/No-HAP Coating and the Current Compliant Coating
This no-YOC/no-HAP coating and the current compliant coating, (VOC 333 g/1) were sprayed
on metal panels and put in a salt spray cabinet using ASTM Method B117 for corrosion
resistance testing. The current compliant coating failed after 192 hours (showed cracks and
blisters on coating surface) and the no-VOC coating reached 1700 hours before signs of cracking
appeared.
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APPENDIX C.2
POTENTIAL FORMULATION USING SOY BEAN OIL
For the past five years ADCO has been developing resin systems for industrial paints and
coatings that emit no volatile organic compounds (VOCs), and no hazardous air pollutants
(HAPs). These systems are based on ADCO's patented technology which utilizes epoxy
functional materials emulsified in water, and then reacted to increase the molecular weight and
thus create unique resin systems which combine the qualities of high performance with the
practical benefits of ease of use, very low odor, and no volatiles other than water. Increasing the
molecular weight in such a manner creates resins that are well on their way to forming resin
films which are the binders for paints and coatings and which, to a large extent, define the
performance characteristics of a finished paint.
The same resin technology can be used to develop a high performance soy polymer (HPSP) that
employs epoxidized soybean oils and ADCO's patented epoxy-functional, high molecular weight
technology as a resin for paints and coatings. The HPSP can be used with a variety of cross-
linking materials including carboxyl, amino and hydroxyl functional resins, as well as
conventional driers. When developed these products could make a significant impact on sizable
markets offering these advantages: high performance at relatively low cost (up to 30-50% less
than competitive paint systems), user friendliness (water-based with no odor), versatility (can be
air dry or low bake), and environmental consciousness (utilizing a renewable resource material to
replace non-renewable resources as well as eliminating VOC and HAP emitting materials).
These systems differ from the epoxy systems in molecular backbone structure but not in
functionality. This research and development work focuses on the homopolymerization and
polymer chain extension of commercially available epoxidized soybean oils completed as water
emulsions or dispersions. The resultant high molecular weight soybean oil in water has distinct
advantages to paint and coating performance and versatility. One advantage is that when a paint
is applied fully, about one third to one half of the resin is already polymerized, so the cure time
is shortened considerably. This is an important consideration for all resin systems, specifically
for soy based paint products which are typically slow curing or require significant heat to give a
reasonable cure response. Another advantage would be that, when polymerized in this fashion,
the resulting resin usually requires no extra coalescing aids (normally VOCs) that contribute odor
and potential health risks allowing a lower odor, safer paint or coating product to be produced.
Still another advantage is that, being a water-based system, the paint or coating could be
pigmented using conventional dispersing techniques and tinted with commercially available
water-based tints for the full color spectrum.
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