EPA FY2009 Annual Report
EPA Implementation of Executive Order 13329 (Encouraging Innovation in Manufacturing)
BACKGROUND:
Executive Order 1 3329 was signed on February 26, 2004. The purpose of Executive Order
13329 is to help ensure that Federal agencies properly and effectively assist the private sectoi in
its manufacturing innovation so as to sustain a strong manufacturing sector in the United States
economy by advancing innovation, including innovation in manufacturing, through small
business. HP A submitted its HO 13329 Action Plan to SB A on July 1, 2004 and our lirst report
was submitted on March 14r 2005. HPA's "Y 2008 report was submitted in September 2009.
Manulacturing-rclated R&l) encompasses improvements in existing methods or processes, or
wholly new processes, machines or systems. Manufacturing innovation is fostered bv research
and development of technologies that are aimed at increasing the competitive eapab.lity ol
manufacturing concerns. Four main areas include: (1) I.nit process level technologies thai create
or improve manufacturing processes; (2) Machine level technologies that create or improve
manufacturinu equipment; (3) Systems level technologies tor innovation in the manufacturing
enterprise; and (4) Environment or societa level technologies that improve workforce abilities
and manufacturing competitiveness.
This report covers: (1) Examples of Manufacturing-related SBIR Projects: (2) Procedures and
Mechanisms Used to (live Priority to Manufacturing-Related SBIR Projects, and (-.¦>) 1 romotion
and Outreach to promote F.xccutix c Order awareness.
1 EXAMPLES of Manufacturing-related SBIR Projects
Manufacturing related SBIR Phase 1 and Phase II awards, LPA reeentK awarded 23 new- SBIR
Phase I awards and 8 new Phase II awards. Six Phase I awards (S420.000) and 2 Phase II awards
($450,000) are manufacturing related awards under E.O. 1 3329. These awards valued at
$870,000 are for unit process level technologies that create or improve manufacturing processes,
machine level technologies that create or improve manufacturing equipment, systems level
technologies for innovation in the manulaoturing enterprise or environmental or societal lex c 1
technologies that improve workforce abili.ies and manufacturing competitheness. I he IA -00)
Phase 1 "Innovation in Manufacturing"" awards are summarized below:
Award EPD-09-018
Jxovalive Design, LLC (1 roy. NTV )
Testinu the Viability of Agricultural By-products as a Replacement for Mineral Particles
in a Novel. Low embodied Energy, Construction Material
Award EPD-09-021
Faraday Technology. Inc. (Clavton, OH)
Lnablina Commercialization of a Lead-Free Coating Manufacturing Process

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Award EPD-09-23
Gevo. Inc. (Denver. CO)
Second-Generation Isobutanol Producing Biocatalyst
Award EPD-09-027
Inlegran Technologies USA, Inc. (Pittsburgh, PA)
Amorphous Alloy Coatings tor Ha:d Chromium Replacement
Award EPD-09-029
Eight Curable Coatings (Valley V cw, OH)
Chromium-Free Corrosion-Resistant Hybrid EV Coatings
Award EPD-09-031
Mountain Creek Enterprises (Monroe. GA)
Feasibility Study to Produce Biodiesel from I ow Cost Oils and Hew Catalysts
Derived from Agricultural & Forestry Residues
The FY 2009 Phase II "Innovation in Manufacturing" awards are summarized below:
Award EPD-09-044
Materials and Electrochemical Research (Tucson, AZ)
A New Innovative Fow Cost Manufacturing Process to Produce Titanium.
Award EPD-09-047
TDA Research. Inc. (Wheat Ridge, CO)
Process-Intensified Low-Cost Biodiesel Using Meat Rendering, Greases and Food Waste
Manufacturing-Related Success Stories,
EPA developed a success stories publication that includes manulacturing related technologies
and products. Five example success stories demonstrate the impact of the SB1R program on
manufacturinc related innovation: (1) Solid Scrubber in the Semiconductor Industry (A 1 Ml,
Inc.): (2) Replacement of Toxic Ilexavalent Chromium in the Plating Process (Faraday, Inc.);
(3) New Coating Methods to Replace Waste and Hazards in Plating; (4) Environmentally
Friendly Conversion Coating (Eynntech, Inc.): and (5) Electrochemical Production ot
Potassium Ferrate (Lynntech. Inc.).
2. Procedures/Mechanisms Used to Give Priority to Manufacturing-Related SBIR Projects
EPA has integrated manufacturing related priorities into Agency goals. EPA encouraged
Agency managers to continue to include and possibly expand manufacturing related priorities in
the EPA strategic goals and objectives that cover the SBIR Program, One mechanism used to
give priority to manufacturing related projects is a specific topic in our solicitation tor
manufacturing. Ihc EPA SBIR program solicitation includes the following topic:

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TOPIC B. INNOVATION IN MANUFACTURING
Executive Order 13329 directs EPA to properly and effectively assist the private sector in its
manufacturing innovation in order to sustain a strong manufacturing sector in the US cconorm by
advancing innovation. Manufacturing-related R&D encompasses improvements in existing methods or
processes- or wholly new processes, machines or systems. Manufacturing innovation is fostered b\
technology R&D aimed at increasing the competitive capability of manufacturing concerns. Areas of
interest include unit process level technologies that create or improve manufacturing processes, machine
level technologies that create or improve manufacturing equipment, systems level technologies lot-
innovation in the manufacturing enterprise, and environmental technologies that improve workforce
abilities and manufacturing competitiveness. Companies seeking assistance with project development in
this topic area are encouraged to contact their local National Institutes of Standards and Technology
Manufacturing Extension Partnership office at http: w w w. me p. n i st. g o v. Specific areas ot interest
include, but are not limited to:
•	Manufacturing process changes that utilize green technology to improve process efficiency and
reduce pollution. These technologies may include non-traditional reactors, novel processing
methods, new feedstocks, solvents or chemical systems that impro\e production efficiency and
performance while eliminating or minimizing the use or generation ol harmful materials.
•	New filtration membranes for organic solvent recovery and similar applications, Also,
development of technology for solvent free production of chemical products and new or
improved catalyst products.
•	Prevention or reuse of paint sludges from captured overspray in painting operations and use of
low volatile organic compounds (VOC) products for purging paint lines and painting guns, and
alternate filter technologies, reusable filters or new technologies for collection of spray in dry
paint booths.
Other solicitation topics also cover manufacturing related needs. Topic C Nanotechnology
includes new cleaner manufacturing processes, environmentally sound coatings, belter
monitoring sensors and machine-level anc system level controls that improve manufacturing
efficiency and effectiveness. Air. water and waste management programs cover new clean up
technology and better manufacturing systems. Specific topics deal with automobile and
chemical manufacturing, metal finishing trnd electronics manufacturing, green building products
and water security and decontamination technologies and systems. I he EPA SBIR Solicitation
emphasizes manufacturing related opportunities and needs,
3, Promotion and Outreach to promote Executive Order awareness
Manufacturing has been integrated at EPA into manufacturing related priorities and Agency
goals. EPA has encouraged Agency managers to continue to include and possibly expand
manufacturing related priorities in the EPA strategic goals and objectives that cover the SBIR
Program. EPA's SBIR program has emphasized manufacturing related topics and priorities at
National, regional and state SBIR conferences. Emphasis has been placed on opportunities for
businesses to submit new critical manufacturing technologies.

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EPA has provided information on SBIR success stories including manufacturing related
technologies and products. 1 .ynnteclTs "Hctcropolymolybdate Conversion Coatings is an
example success story showing the impact of the SBIR program on manufacturing related
innovation. Part of the success story is provided below.
Problem: The use of chemical conversion coalings on aluminum alloys to achieve long-term
corrosion resistance of painted spacecraft and aircralt structures has found widespread military
and commercial applications. With increasing environmental concerns, the use of chemical
conversion coatings that do 1101 contain harmful chemicals is of particular interest to the
Department of Defense. National Aeronautics and Space Administration, and other federal
agencies. At the core of the problem is the demonstration of human health effects associated with
exposure to hexavalent chromium. Because hcxavaient chromium is a human carcinogen,
concern exists not only about workplace exposure at high levels, but also about environmental
exposure at much lower levels.
SBIR Technology Solution: The new conversion coating is based on heteropolyrnolybdates, a
class of compounds known as polyoxometalates. Ihese species are remarkable lor t:ieir
molecular and electronic structural diversify. The heteropolymolyodate is a significant departure
from the use of molybdate (Mo'r"().f~) as a conversion coating. Tests of coatings prepared from
formulations consisting of hcteropolymolvbdates and several important additives demonstrate
exceptional corrosion resistance. Some coatings outperformed the chromate-based conversion
coatings in electrochemical corrosion-resistance tests and passed a standard 14-dav salt log test.
The key to this technology is heteropolyrnolybdates. The primary effect of the hetero atom is an
effective transformation of Mo (III) and Tvio (IV) to stable Mo (V) and Mo (VI). thereby
enhancing the formulation oi conversion coatings on aluminum alloys, 1 his unique charactciistic
provides an elusive self-healing capability. Surface spectroscopic studies indicate the presence of
a stable reservoir of Mo(Vl) in the oxide layer that acts in an analogous way to Cr(VI).
Com111creiatization: Lvnntech made significant headway towards commercialization ot this
technology, Lvnnteeh's conversion coatings were designed to be environmentally Iriendly,
which lowers cost because hazardous disposal fees are not required. Lvnntech established
collaborations with otic of the leading aerospace contractors, as well as a leading supplier in the
metal finishina industry. Through these collaborations, the company was invited to participate in
a national study in search of chromium alternatives funded by the National Center for
Manufacturing Sciences. In (his study. Lymtech demonstrated two lormulations that have the
capabilities and potential to successfully replace chromium-based conversion coatings.
Impact: Lvnntech dex eloped a new environmental^ friendly conversion coating based on
heteropolyrnolybdates. The coatings demonstrate exceptional corrosion resistance; some
outperformed chromate-based conversion coatings in electrochemical corrosion-resistance tests
and passed a standard 14-day salt fog test. These coatings provide long-term corrosion
resistance of painted surfaces and can be applied by painting, dipping, or spraying. 1 hese
coatings are low-cost, require short treatment times, used at room temperatures, and compatible
with existing cleaning and pretreatment processes.

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