£EPA
United States EPA-600/R-03/099b
Environmental Protection
Agency November 2003
Source Sampling Fine
Particulate Matter: A
Kraft Process Recovery
Boiler at a Pulp and
Paper Facility: Volume 2,
Appendices
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EPA-600/R-03/099b
November 2003
Source Sampling Fine Particulate
Matter: A Kraft Process Recovery
Boiler at a Pulp and Paper Facility:
Volume 2, Appendices
by
Joan T. Bursey and Dave-Paul Dayton
Eastern Research Group, Inc.
1600 Perimeter Park Drive
Morrisville, NC 27560
Contract No. 68-D7-0001
EPA Project Officer: N. Dean Smith
Air Pollution Prevention and Control Division
National Risk Management and Research Laboratory
Research Triangle Park, NC 27711
Prepared for:
U.S. Environmental Protection Agency
Office of Research and Development
Washington, DC 20460
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Abstract
Fine particulate matter of aerodynamic diameter 2.5 |im or less (PM25) has been
implicated in adverse health effects, and a National Ambient Air Quality Standard for PM2 5
was promulgated in July 1977 by the U.S. Environmental Protection Agency. A national
network of ambient monitoring stations has been established to assist states in determining
areas which do not meet the ambient standard for PM2 5. For such areas, it is important to
determine the major sources of the PM2 5 so states can devise and institute a control strategy
to attain the ambient concentrations set by the standard.
One of the tools often used by states in apportioning ambient PM2 5 to the sources is a
source-receptor model. Such a model requires a knowledge of the PM2 5 chemical
composition emitted from each of the major sources contributing to the ambient PM2 5 as
well as the chemical composition of the PM2 5 collected at the receptor (ambient monitoring)
sites. This report provides such a profile for a Recovery Boiler at a pulp and paper facility.
Along with the PM2 5 emission profile, data are also provided for gas-phase emissions of
several organic compounds. Data are provided in a format suitable for inclusion in the EPA
source profile database, SPECIATE.
11
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Foreword
The U.S. Environmental Protection Agency (EPA) is charged by Congress with protecting
the Nation's land, air, and water resources. Under a mandate of national environmental laws,
the Agency strives to formulate and implement actions leading to a compatible balance
between human activities and the ability of natural systems to support and nurture life. To meet
this mandate, EPA's research program is providing data and technical support for solving
environmental problems today and building a science knowledge base necessary to manage
our ecological resources wisely, understand how pollutants affect our health, and prevent or
reduce environmental risks in the future.
The National Risk Management Research Laboratory (NRMRL) is the Agency's center for
investigation of technological and management approaches for preventing and reducing risks
from pollution that threaten human health and the environment. The focus of the Laboratory's
research program is on methods and their cost-effectiveness for prevention and control of
pollution to air, land, water, and subsurface resources; protection of water quality in public
water systems; remediation of contaminated sites, sediments and ground water; prevention
and control of indoor air pollution; and restoration of ecosystems. NRMRL collaborates with
both public and private sector partners to foster technologies that reduce the cost of
compliance and to anticipate emerging problems. NRMRL's research provides solutions to
environmental problems by: developing and promoting technologies that protect and improve
the environment; advancing scientific and engineering information to support regulatory and
policy decisions; and providing the technical support and information transfer to ensure
implementation of environmental regulations and strategies at the national, state, and
community levels.
This publication has been produced as part of the Laboratory's strategic long-term research
plan. It is published and made available by EPA's Office of Research and Development to
assist the user community and to link researchers with their clients.
Lawrence W. Reiter, Acting Director.
National Risk Management Research Laboratory
111
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EPA Review Notice
This report has been peer and administratively reviewed by the U.S. Environmental
Protection Agency and approved for publication. Mention of trade names or commercial
products does not constitute endorsement or recommendation for use.
This document is available to the public through the National Technical Information
Service, Springfield, Virginia 22161.
iv
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Table of Contents
Volume 1, Report
Section Page
Abstract ii
List of Tables viii
List of Figures x
Nomenclature xi
Acknowledgments xii
Introduction 1
Characterization of a Recovery Boiler at a Pulp and Paper Facility 2
Report Organization 3
Conclusions 5
Methods and Materials 7
Description of Test Equipment 8
Dilution Sampling System 9
Dilution Sampling System Control Instrumentation 12
Sample Collection Arrays 14
Process Description/Site Operation 14
Pre-Test Survey 18
Experimental Procedures 19
Preparation for Test Setup 19
Traverse Point Determination Using EPA Method 1 19
Volumetric Flow Rate Determination Using EPA Method 2 21
Pitot Tube Calibration 21
Calculation of Average Flue Gas Velocity 21
Nozzle Size Determination 22
Measurement of 02, C02, and CO Concentrations for Calculating Stack
Parameters 22
Stationary Gas Distribution (as Percent Volume) 23
Dry Molecular Weight of Flue Gas 23
Wet Molecular Weight of Flue Gas 23
Determination of Average Moisture Using EPA Method 4 24
v
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Table of Contents (continued)
Section Page
Volume of Dry Flue Gas Sampled at Standard Conditions (dscf) 24
Volume of Water Vapor at Standard Conditions (dscf) 25
Calculation of Moisture/Water Content (as percent volume) 25
Calculation of Dry Mole Fraction of Flue Gas 25
Setup of the Dilution Sampling System 26
Pre-Test Leak Check 29
Orifice Flow Check 30
Determination of Test Duration 31
Canister/Veriflow Blanks 31
Determination of Flow Rates 31
Sample Collection Arrays 32
Dilution Chamber Sample Collection Arrays 32
Residence Chamber Sample Collection Arrays 34
Use of the ELPI Particle Size Distribution Analyzer 35
Measurement of 02 and C02 Process Concentrations 36
Operation of the Dilution Sampling System with Sample Collection Arrays 36
Dilution System Sample Collection Arrays: Sample Recovery 46
Laboratory Experimental Methodology 47
PM2 5 Mass 47
Elemental Analysis 48
Water-Soluble Inorganic Ions 48
Elemental Carbon/Organic Carbon 48
Organic Compounds 49
Carbonyl Compounds 50
Canister Analyses: Air Toxics and Speciated Nonmethane Organic
Compounds 51
Particle Size Distribution Data 52
Results and Discussion 53
Calculated Emission Factors for PM Mass, Carbonyls, and Nonmethane Organic
Compounds 53
Gas-Phase Carbonyl Compounds 54
Gas-Phase Air Toxic Compounds 54
Gas-Phase Speciated Nonmethane Organic Compounds 57
EC/OC, Major Inorganic Ions, and Major Elements 62
vi
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Table of Contents (continued)
Section Page
Particle Size Distribution Data 63
Semivolatile Organic Compounds 63
Process 02 and C02 Concentrations 68
Quality Assurance/Quality Control 73
Field Sampling 73
Carbonyl Compound Analysis 75
Concurrent Air Toxics/Speciated Nonmethane Organic Compound (SNMOC)
Analysis 77
PM Mass Measurements, Elemental Analysis, Water-Soluble Ion Analysis,
Organic/Elemental Carbon, and GC/MS Analysis 79
References 85
Volume 2, Appendices
A Table of Unit Conversions A-l
B Recovery Boiler No. 5, Test 1, Chain of Custody Documentation B-l
C Sample Log with Sample IDs C-l
D List of ERG SOPs and EPA MOPs by Title D-l
E Method Detection Limits for Carbonyl Compounds, Air Toxics,
and Speciated NMOCs E-l
F Example Calculations F-l
G PM Emission Factor Calculations G-l
H Data Tables for Individual PM25 Mass Measurements H-l
I Supporting Data for Carbonyl Analysis 1-1
J Supporting Data for Air Toxics Analysis J-l
K Supporting Data for Speciated and Unspeciated Nonmethane Organic
Compounds K-l
L Data Tables for Individual PM25 EC/OC Samples L-l
M Data Tables for Individual PM2 5 Elemental Samples M-l
N Data Tables for Individual PM2 5 Inorganic Ion Samples N-l
O Supporting Calibration and Data Tables for Individual Semivolatile
Organic Compounds 0-1
vii
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Nomenclature
Term Definition
CMB chemical mass balance
DNPH 2,4-dinitrophenylhydrazine
EC/OC elemental carbon and organic carbon
ELPI electrical low pressure impactor
EPA U.S. Environmental Protection Agency
ERG Eastern Research Group
FID flame ionization detector
GC gas chromatography analytical technique
GRAV gravimetric analytical technique
HEPA high efficiency particulate arresting
HPLC high performance liquid chromatography analytical technique
IC ion chromatography analytical technique
MDLs method detection limits
MOPs method operating procedures
MS mass spectrometry analytical technique
MSD mass selective detector
NH3 ammonia
NMOCs nonmethane organic compounds
NOx nitrogen oxides
PM particulate matter
PM2 5 particulate matter of aerodynamic diameter 2.5 |im or less
PM10 particulate matter of aerodynamic diameter 10 |im or less
PUF polyurethane foam
QAPPs quality assurance project plans
SIPs State Implementation Plans
SNMOCs speciated nonmethane organic compounds
SOPs standard operating procedures
SOx sulfur oxides
TMS trimethylsilyl
TOE thermal-optical evolution
VOCs volatile organic compounds
XRF X-ray fluorescence analytical technique
viii
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Appendix A
Table of Unit Conversions
A-l
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Contents
Table Page
A-l Unit Conversion Table A-3
A-2
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Table A-1. Unit Conversion Table
Multiply
By
-O
o
o
H
atmospheres
101.3
kilopascals
atmospheres
29.92
inches of mercury
atmospheres
760
mm of mercury
atmospheres
33.94
feet of water
atmospheres
14.70
lb/in.2 (psi)
Btu
1054
joules
Btu
2.982 x 10"4
kilowatt-hours
centimeters
0.3937
inches
cm/sec
1.969
ft/min
cm/sec
0.03281
ft/sec
cm/sec
0.036
km/hr
cm/sec
0.6
m/min
cm3
3.53 x 10"2
ft3
cm3
10"3
liters
ft3
0.02832
m3
ft3/min
0.4720
L/sec
in.3
16.39
cm3
m3
35.31
ft3
ft
12
in.
ft
0.3048
m
ft of water
0.8826
in. of mercury
grams
0.03527
ounces
inches
2.540
cm
inches of water
0.07355
in. of mercury
kg
2.20462
lb
km
3280.84
ft
km
0.6214
miles
kilowatts
56.92
Btu/min.
liters
0.03531
ft3
liters
61.02
in.3
liters
10"3
m3
liters per minute
5.855 x 10"4
ft3/sec
m
3.28084
ft
m
39.37
in.
m3
0.02832
ft3
miles
5280
feet
miles
1.6093
km
ounces
28.35
grams
continued
A-3
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Table A-1. (concluded)
Multiply
By
To Obtain
pounds
453.6
grams
pounds per square inch
703.1
kg/m2
cm2
0.1550
in.2
ft2
929.0
cm2
ft2
0.09290
m2
temperature (°C + 273)
1
absolute temperature (K)
temperature (°C + 17.8)
1.8
temperature (°F)
temperature (°F + 460)
1
temperature (°Rankin)
temperature (°F-32)
5/9
temperature (°C)
watts
0.05692
Btu/min.
watts
44.26
foot-pounds/min.
A-4
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Appendix B
Recovery Boiler No. 5, Test 1,
Chain of Custody Documentation
B-l
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Contents
Table Page
Sampling Configurations (10/30/01) B-3
Chain of Custody Records (10/30/01) B-9
Sampling Configurations (10/31/01) B-13
Chain of Custody Records (10/31/01) B-19
Sampling Configurations (11/01/01) B-22
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U* UK ONLY
MOCNtOHMUttamiOnvilr:
mil
I*] Afcrtlt MJ p^.
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uy&ifiSf
-------
CLEAN SUBSTRATES
P-89C 1
Data Sulatrsn OlvtrbirtMi
To Whom Substrate DfstfiulKl
FPMCC Lad Personnel
12111
t5m~~
Yuaualf
Chamber
KsFori
00318011
(Mil SOt H
¦mmmf
0052301J
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M6W01Q
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Q0804I31W
OO0O4O1X
B-33
-------
clean substrates
Out# Substn&i Dtstrtbutad
V A * fa §- t ay. IT%.t... ifr». lr lf< nif. n
,1:0 VTnC-Tl syD5t/,1^
lowtaoi
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tioaeoia
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nomif
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TtaiaiF
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TtO&Mt
tiqodij
Tlfl8»1K
TKMBWU
TT02&01M
TlQSZOtN
Tt 082010-
B-34
-------
CLEAN SUBSTRATES
Da» Imlwtwii DtotrfeulMl
To Whom Substrate Ot*MbuMl
FPMCB labPananmt
NO
.11
JL.
_1L
mm.
Tom
"WSj
TVpm
Al fori , A1017D1A
MM
w
AI foil
Altai
A! fal
MM
M foil
.MM.
A101791
A101
A1Q17Q1C
Hi
™!L_
A1017Q1G
A1Q17Q1H
*1017011
A1017I1
Tin: B
jiiufSTW
ctamm
A 101701k
A10! 701.L
AI toil AT01?gt;M.
.A101.7
"ggtie.fi < Of'
S>mp
-------
clean mvsmxtm _ 5
Ditu gyiafwtB DirirftKiMf IQttSBOOl
to Whom Substrate Distributed Tom'..'.'''
FPMCC um Promt*I gT""
»
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f
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1. '
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B-36
-------
OMAN SUBSTRATES
Pafp i
0* Subttani DfofrfeuM
To Whom ftafastrntt Dtetrlfeitad
IfPWCC UbMn«im«t
Ntt
$SSBL
Jk=
Typ*
Subsir-ito ID
TmMW
SamplingPatttfan
Port Position Hoktar
piiifti*
'"wjf'
pitifiii
'pfoffoic
wm<.
Pi 01701D
mmmm
t
21
/
t:
-&
¦RJF
PlOfTDlE
Ti5!7ClF
w
PUF
PlQlTOlG.
"PUF
-pgr
P101701H
' lOlSSf H
"Wmm
tn ie«' »
-taJsLjaiJl
- ?..
-0-
a
pop
P1017QU
It
"ia
±yL
PUF
-WWM
P1Q1701L
JA2SJ5L
f.
/—
3'-F
pioitoim'
J0 ?'¦ £1
£_e,
JL
pfiiroiw
FtOITOlO
jlmMMJL
jblm
j±±i
IS
PUF
-£*1l£UL
ii
PUF
P101T01P
1?
PUP
P1C1TQ1Q
ii
PUF
ft
PUF
P101701S
»
tl
pyp
PM1701?
PUF
pwwiy
-t
t
JL
23
24
JUL
w
•G3UBE-.
PMHTOtW.
a
f ff',4
PUF
piotwix'
110 101.. H
-A
25.
PUF
piotaom
35
pietao'8.
3?
PUF
PtiliDlC
28
m
PUF
"pip wo.
mr
2M5ie
—
tiWotTf
JSl
31
33
36
"37
TT
at
40
•>VL
TOT
Piiiais
.w
proiaaiH"
.PUF
Xf
pioiaflfi
W
PUF
ptoiaou
•mmmm
P101881L.
«Hje
PUF
PW1W1A
FSfiSlT"
PUF
ptiiwc
PUP
"P1019010.
B-37
-------
Appendix C
Sample Log with Sample IDs
c-i
-------
Table C-1. Sample Log, Recovery Boiler
Test Date:
10/30/01
10/31/01
11/1/01
Chamber
Port
Position
Substrate
Holder#
Substrate ID
Substrate ID
Substrate ID
Residence
2
A1
TF
585
T100201B
T100201J
T1002010
B1
TF
614
T100201C
T100201I
T100201N
3
Ml
DNPH
IB103001HR1M1
IB103101HR1M1
IB110101HR1M1
M2
DNPH
IB103001HR1M2
IB103101HR1M2
IB110101HR1M2
4
A1
QF
618
Q051601N
Q052501Xa
Q052901Gb
A2
PUF
B
P101701C
P101701Q
P101801A
A3
PUF
B
P101701D
P101701R
P101801B
B1
QF
641
Q052301C
Q052901Aa
Q052901Hb
5
M2
SUMMA
IB103001H-SR5M2
IB103101H-SR5M2
IB110101H-SR5M2
6
A1
TF
613
T100201D
T100201H
T100201M
B1
TF
633
T100201E
T100201G
T100201L
7
Ml
ELPI
run time = 303 min
run time = 480 min
run time = 480 min
8
A1
QF
564
Q052301J
Q052501Va
Q052901Fb
A2
PUF
C
P101701E
P101701S
P101801C
A3
PUF
C
P101701F
P101701T
P101801D
B1
QF
610
Q052301V
Q052501Ta
Q052901Eb
10
Ml
Denuder
D060501-1049-3
D060501-1013-2
D010901-1259-4
M2
Denuder
D010901-1261-3
D071900-995-3
D042601-1551-2
A3
QF
481
Q052401X
Q052501R3
Q052901Cb
A4
PUF
D
P101701G
P101701U
P101801E
A5
PUF
D
P101701H
P101701V
P101801F
B3
QF
640
Q052501E
Q052501P
Q052901Db
Dilution
1
A1
QF
622
Q051601I
Q052901B
Q052901K
A2
PUF
A
P101701A
P101701O
P101701W
A3
PUF
A
P101701B
P101701P
P101701X
B1
TF
642
T100201A
T100201K
T100201P
2
M2
SUMMA
IB103001H-SD2M2
IB103101H-SD2M2
IB110101H-SD2M2
3
Ml
DNPH
IB103001HD3M1
IB103101HD3M1
IB110101HD3M1
M2
DNPH
IB103001HD3M2
IB103101HD3M2
IB110101HD3M2
Field Blank
QF
Q052501G
TF
T100201F
Denuder
D060501-1049-4
Denuder
D010901-1261-4
PUF
Field
P101701M
PUF
Field
P101701N
PUF
B-l
P102501L
SUMMA
IB103001H-SUMA-FB
DNPH
IB 103001H-DNPH-FB
a All quartz filter samples in the Residence Chamber for the 10/31/01 test were composited for analysis.
b All quartz filter samples in the Residence Chamber for the 11/1/01 test were composited for analysis.
C-2
-------
Appendix D
List of ERG SOPs and EPA MOPs by Title
D-l
-------
Contents
Table Page
D-l ERG Standard Operating Procedures by Title D-3
D-2 EPA Method Operating Procedures by Title D-6
D-2
-------
Table D-1. ERG Standard Operating Procedures by Title
SOP
Tr SOP Title
No.
1 Documentation of Field Recovery Activities
2 Gravimetric Determination for Particulate Emissions Measurements
3 Field Procedure for Collecting Ambient Air Toxics and Carbonyl Compounds Samples
using the ERG:AT/C Sampling System
3B Field Procedure for Collecting Ambient Air Toxics and Carbonyl Compounds Samples
using the ERG:AT/C Sampling System
4 SOP for Preventive Maintenance in the Gas Chromatography/Mass Spectrometry
Laboratory
5 SOP for the Concurrent GC/FID/MS Analysis of Canister Air Toxic Samples
6 SOP for the Analysis of Tenax® Tubes According to EPA Method TO- 1/TO-17
7 SOP for the Preparation of Review Packages for Mass Spectrometry Data Sets
8 Procedure for Preparation of Standard Operating Procedures
9 SOP for the Operation of the Documentation System
10 SOP for the Determination of Method Detection Limits in the GC/MS Air Toxics
Laboratory
11 SOP for Sample Storage and Checkout from Freezers/Refrigerators at the Laboratory
12 SOP for Basic Training Requirements for Sample Preparation Laboratory Personnel
13 Field Procedure for Collecting Ambient Air Hexavalent Chromium Samples Using the
ERG:CR6 Sampling System
14 SOP for Sample Preparation Quality Control
15 SOP for Documentation Procedures for the Sample Preparation Laboratory
16 SOP for the Varian 9000 Series High Performance Liquid Chromatograph (HPLC)
17 SOP for Developing, Documenting, and Evaluating the Accuracy of Spreadsheet Data
18 Maintaining and Recording Data Records
19 SOP for Transferring, Storing, and Using Confidential Business Information (CBI)
20 SOP for Conducting a Laboratory Systems Audit
21 Calibration and Operation of Analytical Balances
22 SOP for the Preparation of Standards in the ERG Organic Preparation Laboratory
23 SOP for the Use of Significant Figures and Rounding Off Numbers When Reporting Data
24 SOP for Preparing Aldehyde Derivatizing Reagents and Extracting Derivatized Samples
25 SOP for the Operation of the Rainin High Performance Liquid Chromatography System
26 SOP for Documentation: Labeling of Samples and Standards Prepared in the Laboratory
27 SOP for the Operation of a Gas Chromatograph
28 SOP for Quality Assurance/Quality Control in Gas Chromatography/Mass Spectrometry
29 SOP for Concentration of Sample Extracts Using the Kuderna-Danish Concentrator
30 SOP for Canister Sampling System Certification Procedures
continued
D-3
-------
Table D-1. (continued)
vr SOP Title
No.
31 SOP for Cleaning Glassware and Syringes for Organic Analysis
32 Statistical Manual Standard Operating Procedure
33 SOP for Solid and Hazardous Waste Disposal
34 Analytical Chemistry Training at PPK Laboratory
35 SOP for Quality Assurance/Quality Control
36 SOP for Laboratory Security
37 SOP for Chemical Inventory
38 SOP for Personal Protective Equipment Program
39 SOP for Maintaining Laboratory Notebooks
40 SOP for Chemical Storage Facilities
41 SOP for Tracer Gas Release and Integrated Bag Sampling for Analysis by FTIR
Spectroscopy
42 SOP for the Dionex-300 Ion Chromatograph
43 SOP for the Analysis of Semivolatile Organic Compounds in Gaseous Emissions using the
SemiVOST Method
44 SOP for Method 8270C - GC/MS Analysis of Semivolatile Organics
45 SOP for Sample Log-in at the ERG Chemistry Laboratory
46 Field Procedure for Collecting Speciated and/or Total Nonmethane Organic Compounds
Ambient Air Samples Using the ERG:S/NMOC Sampling System
47 Field Procedure for Collecting Ambient Carbonyl Compounds Samples Using the ERG:C
Sampling System
47B Field Procedure for Collecting Ambient Carbonyl Compounds Samples Using the ERG:C
Sampling System
48 SOP for Cleaning XAD-2® with Quality Control Measures to Assure Cleanliness
49 SOP for the Extraction and Analysis of PAHs from XAD-2® Traps
50 SOP for Separatory Funnel Liquid-Liquid Extraction by EPA SW-846 Method 3510C
51 SOP for Continuous Liquid-Liquid Extraction by EPA SW-846 Method 3520C
52 SOP for Acid-Base Partition Cleanup by EPA SW-846 Method 3650B
53 SOP for Soxhlet Extraction by EPA SW-846 Method 3540C
54 SOP for Preparation, Evaluation, and Shipping of Performance Evaluation Samples for
Method 24
55 SOP for Maintenance of NANOPure-A Deionized Water System
56 SOP for Daily Maintenance of Cold Storage Units
57 SOP for Project Peer Review
58 SOP for Preparing Method 25 Audit Samples Using the Transfill System
59 SOP for High Performance Liquid Chromatography
60 SOP for PDFID Sample Analysis
61 SOP for Standard Preparation Using Dynamic Flow Dilution System
continued
D-4
-------
Table D-1. (concluded)
SOP
Tr SOP Title
No.
62 SOP for UATMP and NMOC Canister Cleaning
63 SOP for the Analysis of Ambient Air for Hexavalent Chromium by IC
64 SOP for Shipping Method 6, 7, 8, and 26 Audit Samples
65 SOP for the ERG Sample Database
66 Cylinder Recycling
67 SOP for Producing Standard Mixtures of Organic Compounds in Air by Liquid Injection
68 SOP for Refrigerator and Freezer Temperature Monitoring
69 SOP for Shipping Method 23 Audit Samples
70 SOP for Storing and Shipping Method 13A, 13B, and 29 Audit Samples
71 SOP for Documentation Requirements for the GC/MS Laboratory and for GC/MS
Systems in the VOC Laboratory
72 SOP for Stack Sampling Using FTIR Spectroscopy
73 SOP for the ECD Wipe Test
74 SOP for the Preparation of Spiked Sorbent Samples Using Liquid Spiking into Tenax-GC®
Tubes
75 SOP for the Preparation of Spiked Sorbent Samples Using Liquid Spiking onto XAD-2®
76 SOP for the Preparation of Spiked Sorbent Samples Using Flash Evaporation Spiking onto
XAD-2®
77 SOP for Method 624
78 SOP for Method 625
79 SOP for Method 1624C
80 SOP for Method 1625C
81 SOP for the Preparation of Spiked Method 8 Samples as Stationary Source Audit
Materials
D-5
-------
Table D-2. EPA Method Operating Procedures by Title
MOP No. MOP Title
2501
Preparation of Clean Substrates, Glassware, and Other Materials
2502
Purification of Benzene Solvent
2503
Mass Measurements of Blank and Exposed Sampling Substrates
2504
Solvent Extraction of Samples and Extract Concentration
2505
Diazomethane Preparation and Extract Methylation
2506
Silylation of Methylated Extracts
2507
GC/MS Calibration and Analysis of Extracts
2508
Denuder Coating, Cleanup, and Extraction
2509
PUF Cleanup and Extraction
NIOSH Method 5040
Elemental/Organic Carbon Analysis
D-6
-------
Appendix E
Method Detection Limits for Carbonyl Compounds,
Air Toxics, and Speciated NMOC
E-l
-------
Contents
Table Page
E-l Method Detection Limits for Carbonyl Compounds Analyzed by High
Performance Liquid Chromatography E-3
E-2 Method Detection Limits for Air Toxics Compounds (Analytical
Method TO-15) E-4
E-3 Method Detection Limits for Speciated Nonmethane Organic Compounds E-6
E-2
-------
Table E-1. Method Detection Limits for Carbonyl Compounds Analyzed by High
Performance Liquid Chromatography
Compound
CAS No.
Method Detection Limits
(us)
formaldehyde
50-00-0
0.0838
acetaldehyde
75-07-0
0.0916
acetone
67-64-1
0.0428
propionaldehyde
123-38-6
0.0934
crotonaldehyde
4170-30-3
0.1283
butyraldehyde
123-72-8
0.0956
benzaldehyde
100-52-7
0.0959
isovaleraldehyde
590-86-3
0.1076
valeraldehyde
110-62-3
0.1758
o-tolualdehyde
529-20-4
0.1439
m-tolualdchvdc
620-23-5
0.1439
/Molualdchvdc
104-87-0
0.1439
hexaldehyde
66-25-1
0.1377
2,5 -dimethylbenzaldehyde
5779-94-2
0.13373
diacetyl
432-03-8
0.01543
methacrolein
78-85-3
0.01253
2-butanone
78-93-3
0.01253
glyoxal
107-22-2
0.04123
acetophenone
98-86-2
0.02503
methylglyoxal
78-98-8
0.02443
octanal
124-13-0
0.01003
nonanal
124-19-6
0.01823
a Estimated value.
E-3
-------
Table E-2. Method Detection Limits for Air Toxics Compounds (Analytical Method
TO-15)
Target Compounds CAS No.
Method Detection Limit3
(Ug/m3)
acetylene 74-86-2 0.24
propylene 115-07-1 0.17
dichlorodifluoromethane 75-71-8 0.40
chloromethane 74-87-3 0.24
dichlorotetrafluoroethane 1320-37-2 0.70
vinyl chloride 75-01-4 0.31
1,3-butadiene 106-99-0 0.31
bromomethane 74-83-9 0.70
chloroethane 75-00-3 0.42
acetonitrile 75-05-8 0.84
acetone 67-64-1 1.23
trichlorofluoromethane 75-69-4 0.45
acrylonitrile 107-13-1 0.91
1,1-dichloroethene 75-35-4 0.79
methylene chloride 75-09-2 0.42
trichlorotrifluoroethane 26523-64-8 1.07
trans-1,2-dichloroethy lene 56-60-5 0.47
1.1-dichloroethane 75-34-3 0.65
methyl tert-butyl ether 1634-04-1 1.29
methyl ethyl ketone 78-93-3 0.88
chloroprene 126-99-8 0.73
cis-1,3-dichlorocthylcnc 156-59-2 0.79
bromochloromethane 74-97-5 1.26
chloroform 67-66-3 0.49
ethyl fert-butyl ether 637-92-3 1.25
1.2-dichloroethane 107-06-2 0.48
l,l,l_trichloroethane 71-55-6 0.65
benzene 71-43-2 0.25
carbon tetrachloride 56-23-5 1.01
fert-amyl methyl ether 994-05-8 1.00
1,2-dichloropropane 78-87-5 0.65
ethyl acrylate 140-88-5 1.31
bromodichloromethane 75-27-4 0.80
trichloroethylene 79-01-6 0.75
methyl methacrylate 80-62-6 1.47
c/s-l,2-dichloropropene 10061-01-5 0.82
continued
E-4
-------
Table E-2. (concluded)
Target Compounds
CAS No.
Method Detection Limit3
(Us/m3)
methyl isobutyl ketone
108-10-1
1.36
trans-1,2-dichloropropene
10061-02-6
1.00
1,1,2-trichloroethane
79-00-5
0.65
toluene
108-88-3
0.45
dibromochloromethane
124-48-1
1.36
1,2-dibromoethane
106-93-4
1.23
/7-octanc
111-65-9
0.56
tetrachloroethylene
127-18-4
0.81
chlorobenzene
108-90-7
0.55
ethylbenzene
100-41-4
0.35
m-, /;-xylcnc
108-38-3/106-42-3
0.87
bromoform
75-25-2
1.65
styrene
100-42-5
0.59
1,1,2,2-tetrachloroethane
79-34-5
0.82
o-xylene
95-47-6
0.43
1,3,5 -trimethy lbenzene
108-67-8
0.69
1,2,4-trimethy lbenzene
95-63-6
0.69
m-dichlorobcnzcnc
541-73-1
0.60
chloromethylbenzene
100-44-7
0.72
/?-dichlorobcnzcnc
106-46-7
1.08
o-dichlorobenzene
95-50-1
0.72
1,2,4-trichlorobenzene
120-82-1
0.89
hexachloro-1.3 -butadiene
87-68-3
1.28
MDLs are instrument detection limits based on Fed. Reg., 1984. MDLs reported here are based on nominal
injection volume of 200 mL of gas.
E-5
-------
Table E-3. Method Detection Limits for Speciated Nonmethane Organic Compounds
("Technical Assistance Document for Sampling and Analysis of Ozone Precursors,"
U.S. EPA, 1998)
Compound
CAS No.
Method Detection Limits
,3\
(Ug/mj)
ethylene
acetylene
ethane
propylene
propane
propyne
isobutane
isobutene/1 -butene
1,3-butadiene
/7-butane
fra«s-2-butene
cy.v-2-butcnc
3 -methyl-1 -butene
isopentane
1-pentene
2-methyl-1 -butene
/7-pentane
isoprene
/ram-2-pcntcnc
cy.v-2-pcntcnc
2-methyl-2-butene
2,2-dimethylbutane
cyclopentene
4-methyl-1 -pentene
cyclopentane
2,3 -dimethylbutane
2-methylpentane
3-methylpentane
2-methyl-1 -pentene
1-hexene
2-ethyl-l-butene
/7-hexane
fra«s-2-hexene
cv.v-2-hcxcnc
methylcyclopentane
74-85-1
74-86-2
74-84-0
115-07-1
74-98-6
74-99-7
75-28-5
115-11-7/106-98-0
106-99-0
106-97-8
624-64-6
590-18-1
563-45-1
78-78-4
109-67-1
563-46-2
109-66-0
78-79-4
646-04-8
627-20-3
513-35-9
75-83-2
142-29-0
691-37-2
287-92-3
79-29-8
107-83-5
96-14-0
763-29-1
592-41-6
760-21-4
110-54-3
4050-45-7
7688-21-3
96-37-7
0.50
0.47
0.54
0.44
0.46
0.42
0.43
0.21
0.40
0.43
0.42
0.42
0.32
0.33
0.32
0.45
0.33
0.31
0.33
0.33
0.32
0.46
0.31
0.45
0.32
0.46
0.46
0.46
0.46
0.46
0.45
0.46
0.46
0.46
0.45
continued
E-6
-------
Table E-3. (continued)
Compound
CAS No.
Method Detection Limits
,3\
(Ug/m3)
2,4-dimethylpentane
benzene
cyclohexane
2-methylhexane
2,3 -dimethylpentane
3-methylhexane
1-heptene
2,2,4-trimethylpentane
/7-hcptanc
methylcyclohexane
2.2.3-trimethylpentane
2.3.4-trimethylpentane
toluene
2-methylheptane
3-methylheptane
1-octene
/7-octane
ethylbenzene
m-, /^-xylene
styrene
0-xylene
1-nonene
/7-nonane
isopropylbenzene
a-pincnc
/7-propylbcnzcne
m-cthyltolucne
/;-ethyltoluene
1,3,5 -trimethy lbenzene
0-ethyltoluene
P-pinene
1,2,4-trimethy lbenzene
1-decene
«-decane
1,2,3 -trimethy lbenzene
m-dicthylbcnzcnc
/?-diethylbenzene
108-08-7
71-43-2
110-82-7
591-76-4
565-59-3
589-34-4
592-76-7
540-84-1
142-82-5
108-87-2
564-02-3
565-75-3
108-88-3
592-27-8
589-81-1
111-66-0
111-65-9
100-41-4
108-38-3/106-42-3
100-42-5
95-47-6
124-11-8
111-84-2
98-82-8
80-56-8
103-65-1
620-14-4
622-96-8
108-67-8
611-14-3
127-91-3
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
0.35
0.42
0.45
0.40
0.40
0.40
0.39
0.51
0.40
0.39
0.51
0.51
0.37
0.51
0.51
0.50
0.51
0.52
0.47
0.46
0.47
0.40
0.41
0.38
0.39
0.38
0.38
0.38
0.38
0.38
0.39
0.38
0.33
0.33
0.38
0.32
0.32
continued
E-7
-------
Table E-3. (concluded)
Compound
CAS No.
Method Detection Limits
(Ug/m3)
1-undecene
821-95-4
0.49
/7-undccanc
1120-21-4
0.50
1-dodecene
112-41-4
0.49
/7-dodccanc
112-40-3
0.50
1-tridecene
2437-56-1
0.49
/7-tridccanc
629-50-5
0.50
E-8
-------
Appendix F
Example Calculations
F-l
-------
Contents
Table Page
F-l Calculation of Mass Emission Rates of Speciated Carbonyls, Recovery
Boiler No. 5 (10/30/01) 1-3
F-2 Calculation of Mass Emission Rates of Speciated Carbonyls, Recovery
Boiler No. 5 (10/31/01) F-4
F-3 Calculation of Mass Emission Rates of Speciated Carbonyls, Recovery
Boiler No. 5 (11/01/01) 1-5
F-4 Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
Carbonyls, Recovery Boiler No. 5 (10/30/01) F-6
F-5 Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
Carbonyls, Recovery Boiler No. 5 (10/31/01) F-7
F-6 Calculations of Mass Emission Rates of Total (Speciated + Unspeciated)
Carbonyls, Recovery Boiler No. 5 (11/01/01) F-8
F-7 Calculation of Mass Emission Rates of Speciated NMOC (SNMOC),
Recovery Boiler No. 5 (10/30/01) F-9
F-8 Calculation of Mass Emission Rates of Speciated NMOC (SMNOC),
Recovery Boiler No. 5 (10/31/01) F-10
F-9 Calculation of Mass Emission Rates of Speciated NMOC (SNMOC),
Recovery Boiler No. 5 (11/01/01) F-ll
F-10 Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
NMOC, Recovery Boiler No. 5 (10/30/01) F-12
F-ll Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
NMOC, Recovery Boiler No. 5 (10/31/01) F-13
F-12 Calculation of Mass Emission Rates to Total (Speciated + Unspeciated)
NMOC, Recovery Boiler No. 5 (11/01/01) 1-14
F-2
-------
Table F-1. Calculation of Mass Emission Rates of Speciated Carbonyls, Recovery
Boiler No. 5(10/30/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air 0.2810 |ig
Mass Fuel Consumed 725,707 kg
Combustion Airflow Rate (Average) 212,493.61 sft3/mina
Run Time 482.42 min
Venturi Flow Rate (Average) 20.25 sL/minb
Dilution Airflow Rate (Average) 861.48 sL/min
Flow Rate at Sample Collection Unit 1.37 L/min
Calculations
Total Volume of Air Sampled 2,902,793,349.0000 L
Volume of Combustion Air Sampled 9,769.0050 L
Volume of Dilution Air 415,595.1816 L
Dilution Ratio 43.5422
Mass Flow Rate of Speciated Carbonyls in Diluted Sample 0.0004 |ig/L
Mass Flow Rate of Speciated Carbonyls in Undiluted Sample 0.0185 |ig/L
Total Mass of Speciated Carbonyls in Sampled Air 180.8512 |ig
Total Speciated Carbonyls in Total Combustion Air 53,738,700.1900 |ig
Mass Emission Rate of Total Speciated Carbonyls 74.0501 (ig/kg
0.0741 mg/kg
a sft3/min = cubic feel per minute at standard temperature and pressure.
b sL/min = liters per minute at standard temperature and pressure.
F-3
-------
Table F-2. Calculation of Mass Emission Rates of Speciated Carbonyls, Recovery
Boiler No. 5(10/31/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air 5.4830 |ig
Mass Fuel Consumed 1,170,190 kg
Combustion Airflow Rate (Average) 212,493.61 sft3/mina
Run Time 480.03 min
Venturi Flow Rate (Average) 18.88 sL/minb
Dilution Airflow Rate (Average) 859.33 sL/min
Flow Rate at Sample Collection Unit 1.17 L/min
Calculations
Total Volume of Combustion Air 2,888,412,361.0000 L
Volume of Combustion Air Sampled 9,062.9664 L
Volume of Dilution Air 412,504.1799 L
Dilution Ratio 46.5154
Mass Flow Rate of Speciated Carbonyls in Diluted Sample 0.0098 |ig/L
Mass Flow Rate of Speciated Carbonyls in Undiluted Sample 0.4541 |ig/L
Total Mass of Speciated Carbonyls in Sampled Air 4,115.5773 |ig
Total Speciated Carbonyls in Total Combustion Air 1,311,654,904.0000 |ig
Mass Emission Rate of Total Speciated Carbonyls 1.120.8905 Mg/kg
1.1209 mg/kg
a sft3/min = cubic feel per minute at standard temperature and pressure.
b sL/min = liters per minute at standard temperature and pressure.
F-4
-------
Table F-3. Calculation of Mass Emission Rates of Speciated Carbonyls, Recovery
Boiler No. 5(11/01/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air 2.6310 |ig
Mass Fuel Consumed 1,254,201 kg
Combustion Airflow Rate (Average) 212,493.61 sft3/mina
Run Time 479.03 min
Venturi Flow Rate (Average) 18.87 sL/minb
Dilution Airflow Rate (Average) 854.46 sL/min
Flow Rate at Sample Collection Unit 1.22 L/min
Calculations
Total Volume of Combustion Air 2,882,395,211.0000 L
Volume of Combustion Air Sampled 9,039.2961 L
Volume of Dilution Air 409,311.9740 L
Dilution Ratio 46.2814
Mass Flow Rate of Speciated Carbonyls in Diluted Sample 0.0045 |ig/L
Mass Flow Rate of Speciated Carbonyls in Undiluted Sample 0.2084 |ig/L
Total Mass of Speciated Carbonyls in Sampled Air 1,883.3863 |ig
Total Speciated Carbonyls in Total Combustion Air 600,562,639.0000 |ig
Mass Emission Rate of Total Speciated Carbonyls 478.8408 (ig/kg
0.4788 nig/kg
a sft3/min = cubic feel per minute at standard temperature and pressure.
b sL/min = liters per minute at standard temperature and pressure.
F-5
-------
Table F-4. Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
Carbonyls, Recovery Boiler No. 5 (10/30/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air 2.1055 |ig
Mass Fuel Consumed 725,707 kg
Combustion Airflow Rate (Average) 212,493.61 sft3/mina
Run Time 482.42 min
Venturi Flow Rate (Average) 20.25 sL/minb
Dilution Airflow Rate (Average) 861.48 sL/min
Flow Rate at Sample Collection Unit 1.37 L/min
Calculations
Total Volume of Air Sampled 2,902,793,349.0000 L
Volume of Combustion Air Sampled 9,769.0050 L
Volume of Dilution Air 415,595.1816 L
Dilution Ratio 43.5422
Mass Flow Rate of Total Carbonyls in Diluted Sample 0.0032 |ig/L
Mass Flow Rate of Total Carbonyls in Undiluted Sample 0.1387 |ig/L
Total Mass of Total Carbonyls in Sampled Air 1,355.0967 |ig
Total Carbonyls in Total Combustion Air 402,657,769.5000 |ig
Mass Emission Rate of Total Carbonyls 554.8491 (ig/kg
0.5548 mg/kg
a sft3/min = cubic feel per minute at standard temperature and pressure.
b sL/min = liters per minute at standard temperature and pressure.
F-6
-------
Table F-5. Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
Carbonyls, Recovery Boiler No. 5 (10/31/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air 8.5025 |ig
Mass Fuel Consumed 1,170,190 kg
Combustion Airflow Rate (Average) 212,493.61 sft3/mina
Run Time 480.03 min
Venturi Flow Rate (Average) 18.88 sL/minb
Dilution Airflow Rate (Average) 859.33 sL/min
Flow Rate at Sample Collection Unit 1.17 L/min
Calculations
Total Volume of Combustion Air 2,888,412,361.0000 L
Volume of Combustion Air Sampled 9,062.9664 L
Volume of Dilution Air 412,504.1799 L
Dilution Ratio 46.5154
Mass Flow Rate of Total Carbonyls in Diluted Sample 0.0151 |ig/L
Mass Flow Rate of Total Carbonyls in Undiluted Sample 0.7042 |ig/L
Total Mass of Total Carbonyls in Sampled Air 6,382.0346 |ig
Total Carbonyls in Total Combustion Air 2,033,986,106.0000 |ig
Mass Emission Rate of Total Carbonyls 1.738.1674 Mg/kg
1.7382 mg/kg
a sft3/min = standard cubic feel per minute at standard temperature and pressure.
b sL/min = standard liters per minute at standard temperature and pressure.
F-7
-------
Table F-6. Calculations of Mass Emission Rates of Total (Speciated + Unspeciated)
Carbonyls, Recovery Boiler No. 5 (11/01/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air 5.9245 |ig
Mass Fuel Consumed 1,254,201 kg
Combustion Airflow Rate (Average) 212,493.61 sft3/mina
Run Time 479.03 min
Venturi Flow Rate (Average) 18.87 sL/minb
Dilution Airflow Rate (Average) 854.46 sL/min
Flow Rate at Sample Collection Unit 1.22 L/min
Calculations
Total Volume of Combustion Air 2,882,395,211.0000 L
Volume of Combustion Air Sampled 9,039.2961 L
Volume of Dilution Air 409,311.9740 L
Dilution Ratio 46.2814
Mass Flow Rate of Total Carbonyls in Diluted Sample 0.0101 |ig/L
Mass Flow Rate of Total Carbonyls in Undiluted Sample 0.4692 |ig/L
Total Mass of TotalCarbonyls in Sampled Air 4,241.0193 |ig
Total Carbonyls in Total Combustion Air 1,352,350,192.0000 |ig
Mass Emission Rate of Total Carbonyls 1.078.2564 (ig/kg
a sft3/min = cubic feel per minute at standard temperature and pressure.
b sL/min = liters per minute at standard temperature and pressure.
F-8
-------
Table F-7. Calculation of Mass Emission Rates of Speciated NMOC (SNMOC),
Recovery Boiler No. 5 (10/30/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air
0.0994
Mass Fuel Consumed
725,707
kg
Combustion Airflow Rate (Average)
212,493.61
sft3/mina
Run Time
482.42
min
Venturi Flow Rate (Average)
20.25
sL/minb
Dilution Airflow Rate (Average)
861.48
sL/min
Flow Rate at Sample Collection Unit
0.0081
L/min
Calculations
Total Volume of Air Sampled
2.903 x 109
L
Volume of Combustion Air Sampled
9,769.005
L
Volume of Dilution Air
415,595.18
L
Dilution Ratio
43.5422
Mass Flow Rate of SNMOC in Diluted Sample
0.0254
M-g/L
Mass Flow Rate of SNMOC in Undiluted Sample
1.1039
M-g/L
Total Mass of Speciated SNMOC in Sampled Air
10,784.265
Speciated NMOC in Total Combustion Air
3.204 x 109
^g
Mass Emission Rate of Speciated NMOC
4.415.6553
Mg/l
-------
Table F-8. Calculation of Mass Emission Rates of Speciated NMOC (SMNOC),
Recovery Boiler No. 5 (10/31/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air
0.07295977
Mass Fuel Consumed
1,170,190
kg
Combustion Airflow Rate (Average)
212,493.61
sftVmin3
Run Time
480.03
min
Venturi Flow Rate (Average)
18.88
sL/minb
Dilution Airflow Rate (Average)
859.33
sL/min
Flow Rate at Sample Collection Unit
0.008541
L/min
Calculations
Total Volume of Combustion Air
2,888,412,361.0000
L
Volume of Combustion Air Sampled
9,062.9664
L
Volume of Dilution Air
412,504.1799
L
Dilution Ratio
46.5154
Mass Flow Rate of SNMOC in Diluted Sample
0.0178
M-g/L
Mass Flow Rate of SNMOC in Undiluted Sample
0.8278
M-g/L
Total Mass of Speciated NMOC in Sampled Air
7,501.9318
Speciated NMOC in Total Combustion Air
2,390,902,892.0000
^g
Mass Emission Rate of SNMOC
2.043.1756
Mg/l
-------
Table F-9. Calculation of Mass Emission Rates of Speciated NMOC (SNMOC),
Recovery Boiler No. 5 (11/01/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air
0.0741
Mass Fuel Consumed
1,254,201
kg
Combustion Airflow Rate (Average)
212,493.61
sft3/mina
Run Time
479.03
min
Venturi Flow Rate (Average)
18.87
sL/minb
Dilution Airflow Rate (Average)
854.46
sL/min
Flow Rate at Sample Collection Unit
0.0085
L/min
Calculations
Total Volume of Combustion Air
2.882 x 109
L
Volume of Combustion Air Sampled
9,039.2961
L
Volume of Dilution Air
409,311.97
L
Dilution Ratio
46.2814
Mass Flow Rate of SNMOC in Diluted Sample
0.0181
M-g/L
Mass Flow Rate of SNMOC in Undiluted Sample
0.8383
M-g/L
Total Mass of Speciated NMOC in Sampled Air
7,578.0382
Speciated NMOC in Total Combustion Air
2.416 x 109
^g
Mass Emission Rate of Speciated NMOC
1.926.6761
Mg/l
-------
Table F-10. Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
NMOC, Recovery Boiler No. 5 (10/30/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air
0.2032
Mass Fuel Consumed
725,707
kg
Combustion Airflow Rate (Average)
212,493.61
sft3/mina
Run Time
482.42
min
Venturi Flow Rate (Average)
20.25
sL/minb
Dilution Airflow Rate (Average)
861.48
sL/min
Flow Rate at Sample Collection Unit
0.0081
L/min
Calculations
Total Volume of Air Sampled
2,902,793,349
L
Volume of Combustion Air Sampled
9,769.005
L
Volume of Dilution Air
415,595.182
L
Dilution Ratio
43.5422
Mass Flow Rate of Total NMOC in Diluted Sample
0.0518
M-g/L
Mass Flow Rate of Total NMOC in Undiluted Sample
2.2567
M-g/L
Total Mass of Total NMOC in Sampled Air
22,045.4201
Total NMOC in Total Combustion Air
6,550,646,557
^g
Mass Emission Rate of Total NMOC
9.026.5721
Mg/l
-------
Table F-11. Calculation of Mass Emission Rates of Total (Speciated + Unspeciated)
NMOC, Recovery Boiler No. 5 (10/31/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air
0.1570
Mass Fuel Consumed
1,170,190
kg
Combustion Airflow Rate (Average)
212,493.61
sft3/mina
Run Time
480.03
min
Venturi Flow Rate (Average)
18.88
sL/minb
Dilution Airflow Rate (Average)
859.33
sL/min
Flow Rate at Sample Collection Unit
0.0085
L/min
Calculations
Total Volume of Combustion Air
2.888 x 109
L
Volume of Combustion Air Sampled
9,062.9664
L
Volume of Dilution Air
412,504.18
L
Dilution Ratio
46.5154
Mass Flow Rate of Total NMOC in Diluted Sample
0.0383
M-g/L
Mass Flow Rate of Total NMOC in Undiluted Sample
1.7814
M-g/L
Total Mass of Total NMOC in Sampled Air
16,144.741
Total NMOC in Total Combustion Air
5.145 x 109
^g
Mass Emission Rate of Total NMOC
4.397.0729
Mg/l
-------
Table F-12. Calculation of Mass Emission Rates to Total (Speciated + Unspeciated)
NMOC, Recovery Boiler No. 5 (11/01/01)
Parameters Required Units
Mass of Analyte in Total Combustion Air
0.1665
Mass Fuel Consumed
1,254,201
kg
Combustion Airflow Rate (Average)
212,493.61
sftVmin3
Run Time
479.03
min
Venturi Flow Rate (Average)
18.87
sL/minb
Dilution Airflow Rate (Average)
854.46
sL/min
Flow Rate at Sample Collection Unit
0.0085
L/min
Calculations
Total Volume of Combustion Air
2,882,395,211
L
Volume of Combustion Air Sampled
9,039.2961
L
Volume of Dilution Air
409,311.974
L
Dilution Ratio
46.2814
Mass Flow Rate of Total NMOC in Diluted Sample
0.0407
M-g/L
Mass Flow Rate of Total NMOC in Undiluted Sample
1.8838
M-g/L
Total Mass of Total NMOC in Sampled Air
17,028.3297
Total NMOC in Total Combustion Air
5,429,889,183
^g
Mass Emission Rate of Total NMOC
4.329.3612
Mg/l
-------
Appendix G
PM Emission Factor Calculations
G-l
-------
Contents
Table Page
G-l Calculation of PM Emission Factors (10/30/01) G-3
G-2 Calculation of PM Emission Factors (10/31/01) G-4
G-3 Calculation of PM Emission Factors (11/01/01) G-5
G-4 Calculation of Individual Filter Emission Factors (10/30/01) G-6
G-5 Calculation of Individual Filter Emission Factors (10/31/01) G-l
G-6 Calculation of Individual Filter Emission Factors (11/01/01) G-8
G-2
-------
Table G-1. Calculation of PM Emission Factors (10/30/01)
Test
10/30/2001 (ave)
1
Sampling time (min)
482.42
2
TF sample
T100201B
T100201C T100201D
T100201E
3
PM mass on filter (mg)
1.206
1.13 1.226
1.17
4
Array flow (sL/mina)
8.843
8.843 8.843
8.843
5
PM cone at filter (mg/L)
0.0003
0.0003 0.0003
0.0003
6a
avg. PM cone at filter (mg/L)
0.0003
6b
PM mass on dilution chamber filter (mg)
0.069
6c
Array flow (sL/min)
8.539
6d
PM cone at dilution air (mg/L)
NDb
6e
Net PM mass cone after dilution (mg/L)
0.0003
7
Probe flow (sL/min)
20.25
8
Probe flow (m3)
9.77
9
Dilution air (sL/min)
861.78
10
Dilution air (m3)
415.74
11
Dilution ratio
43.56
12
PM cone at stack (mg/L)
0.0113
13
Stack gas velocity (ft/min)
2,745.8
14
Stack temperature (°F)
367.7
15
Stack pressure (in. Hg)
30.248
16
Stack area (ft2)
120
17
Stack flow (sft3/minc)
212,493.8
18
Stack flow (sL/min)
6,017,823.4
19
PM emission rate from stack (mg/min)
68,296.7
20
Fuel type
Black liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
265.43
41.31
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
1,372.3
131.8
25
Fuel mass feed rate (lb/min)
3,025.9
290.6
26
Fuel heating value (Btu/lb)
4,208
19,374
27
Fuel heat feed rate (Btu/min)
12,732,995.6
5,629,551.1
28
Total fuel mass feed rate (kg/min)
1,504.1
29
Emission factor (mg/kg)
45.41
30
Total fuel heat feed rate (Btu/min)
18.362.546.74
31
Emission factor (lls/kJ)
3.53
a sL/min = liters per minute at standard temperature and pressure.
b ND = not detected.
c sft3/min = cubic feel per minute at standard temperature and pressure.
G-3
-------
Table G-2. Calculation of PM Emission Factors (10/31/01)
Test 10/31/2001 (ave)
1
Sampling time (min)
480.03
2
TF sample
T100201J
T100201I
T100201H T100201G
3
PM mass on filter (mg)
0.429
0.377
0.411 0.405
4
Array flow (sL/mina)
8.902
8.902
8.825 8.825
5
PM cone at filter (mg/L)
0.0001
0.0001
0.0001 0.0001
6a
avg. PM cone at filter (mg/L)
0.0001
6b
PM mass on dilution chamber filter (mg)
0.014
6c
Array flow (sL/min)
8.825
6d
PM cone at dilution air (mg/L)
NDb
6e
Net PM mass cone after dilution (mg/L)
0.0001
7
Probe flow (sL/min)
18.88
8
Probe flow (m3)
9.06
9
Dilution air (sL/min)
859.33
10
Dilution air (m3)
412.50
11
Dilution ratio
46.52
12
PM cone at stack (mg/L)
0.0043
13
Stack gas velocity (ft/min)
2745.8
14
Stack temperature (°F)
367.7
15
Stack pressure (in. Hg)
30.248
16
Stack area (ft2)
120
17
Stack flow (sft3/minc)
212,493.8
18
Stack flow (sL/min)
6,017,823.4
19
PM emission rate from stack (mg/min)
25,754.1
20
Fuel type
Black liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
471.43
ND
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
2,437.3
ND
25
Fuel mass feed rate (lb/min)
5,374.3
ND
26
Fuel heating value (Btu/lb)
4,208
19,374
27
Fuel heat feed rate (Btu/min)
22,615,062.8
ND
28
Total fuel mass feed rate (kg/min)
2,437.3
29
Emission factor (mg/kg)
1,0.57
30
Total fuel heat feed rate (Btu/min)
22.615.062.82
31
Emission factor (lls/kJ)
1.08
a sL/min = liters per minute at standard temperature and pressure.
b ND = not detected.
c sft3/min = cubic feel per minute at standard temperature and pressure.
G-4
-------
Table G-3. Calculation of PM Emission Factors (11/01/01)
Test 11/01/2001 (ave)
1
Sampling time (min)
479.03
2
TF sample
T1002010
T100201N
T100201M T100201L
3
PM mass on filter (mg)
0.57
0.53
0.574 0.57
4
Array flow (sL/mina)
8.891
8.891
8.853 8.853
5
PM cone at filter (mg/L)
0.0001
0.0001
0.0001 0.0001
6a
avg. PM cone at filter (mg/L)
0.0001
6b
PM mass on dilution chamber filter (mg)
0.005
6c
Array flow (sL/min)
8.815
6d
PM cone at dilution air (mg/L)
NDb
6e
Net PM mass cone after dilution (mg/L)
0.0001
7
Probe flow (sL/min)
18.87
8
Probe flow (m3)
9.04
9
Dilution air (sL/min)
854.46
10
Dilution air (m3)
409.31
11
Dilution ratio
46.28
12
PM cone at stack (mg/L)
0.0061
13
Stack gas velocity (ft/min)
2,745.8
14
Stack temperature (°F)
367.7
15
Stack pressure (in. Hg)
30.248
16
Stack area (ft2)
120
17
Stack flow (sft3/minc)
212,493.8
18
Stack flow (sL/min)
6,017,823.4
19
PM emission rate from stack (mg/min)
36,436.1
20
Fuel type
Black liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
506.33
ND
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
2,617.8
ND
25
Fuel mass feed rate (lb/min)
5,772.2
ND
26
Fuel heating value (Btu/lb)
4,208
19,374
27
Fuel heat feed rate (Btu/min)
24,289,257.7
ND
28
Total fuel mass feed rate (kg/min)
2,617.8
29
Emission factor (mg/kg)
13.92
30
Total fuel heat feed rate (Btu/min)
24,289,257.70
31
Emission factor (lls/kJ)
1.42
a sL/min = liters per minute at standard temperature and pressure.
b ND = not detected.
c sft3/min = cubic feel per minute at standard temperature and pressure
G-5
-------
Table G-4. Calculation of Individual Filter Emission Factors (10/30/01)
Test 10/30/2001 (individual filters)
1
Sampling time (min)
482.42
2
TF sample
T100201B
T100201C
T100201D
T100201E
3
PM mass on filter (mg)
1.206
1.13
1.226
1.17
4
Array flow (sL/mina)
8.843
8.843
8.843
8.843
5
PM cone at filter (mg/L)
0.0003
0.0003
0.0003
0.0003
6b
PM mass on dilution chamber filter (mg)
0.069
6c
6d
Array flow (sL/min)
PM cone at dilution air (mg/L)
8.539
NDb
6e
Net PM mass cone after dilution (mg/L)
0.0003
0.0002
0.0003
0.0003
7
8
Probe flow (sL/min)
Probe flow (m3)
20.25
9.77
9
Dilution air (sL/min)
861.78
10
Dilution air (m3)
415.74
11
Dilution ratio
43.56
12
PM cone at stack (mg/L)
0.0116
0.0108
0.0118
0.0112
13
Stack gas velocity (ft/min)
2,745.8
14
Stack temperature (°F)
367.7
15
Stack pressure (in. Hg)
30.248
16
Stack area (ft2)
120
17
Stack flow (sft3/minc)
212,493.8
18
Stack flow (sL/min)
6,017,823.4
19
PM emission rate from stack (mg/min)
69,709.9
65,040.2
70,938.7
67,497.9
20
Fuel type
Black liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
265.43
41.31
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
1,372.3
131.8
25
Fuel mass feed rate (lb/min)
3,025.9
290.6
26
Fuel heating value (Btu/lb)
4,208
19374
27
Fuel heat feed rate (Btu/min)
12,732,995.6
5,629,551.1
28
Total fuel mass feed rate (kg/min)
1,504.1
29
Emission factor (mg/kg)
46.35
43.24
47.16
44.88
30
Total fuel heat feed rate (Btu/min)
18.362.546.74
31
Emission factor (|Xg/kJ)
3.60
3.36
3.66
3.48
32
Ave. Emission factor (mg/kg)
45.41
33
Ave. Emission factor (us/kJ)
3.53
a sL/min = liters per minute at standard temperature and pressure.
b ND = not detected.
c sft3/min = cubic feel per minute at standard temperature and pressure
G-6
-------
Table G-5. Calculation of Individual Filter Emission Factors (10/31/01)
Test 10/31/2001 (individual filters)
1
Sampling time (min)
480.03
2
TF sample
T100201J
T100201I
T100201H
T100201G
3
PM mass on filter (mg)
0.429
0.377
0.411
0.405
4
Array flow (sL/mina)
8.902
8.902
8.825
8.825
5
PM cone at filter (mg/L)
0.0001
0.0001
0.0001
0.0001
6b
PM mass on dilution chamber filter (mg)
0.014
6c
6d
Array flow (sL/min)
PM cone at dilution air (mg/L)
8.825
NDb
6e
Net PM mass cone after dilution (mg/L)
0.0001
0.0001
0.0001
0.0001
7
8
Probe flow (sL/min)
Probe flow (m3)
18.88
9.06
9
Dilution air (sL/min)
859.33
10
Dilution air (m3)
412.50
11
Dilution ratio
46.52
12
PM cone at stack (mg/L)
0.0045
0.0040
0.0044
0.0043
13
Stack gas velocity (ft/min)
2,745.8
14
Stack temperature (°F)
367.7
15
Stack pressure (in. Hg)
30.248
16
Stack area (ft2)
120
17
Stack flow (sft3/minc)
212,493.8
18
Stack flow (sL/min)
6,017,823.4
19
PM emission rate from stack (mg/min)
27,176.9
23,770.6
26,232.7
25,836.3
20
Fuel type
Black liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
471.43
ND
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
2,437.3
ND
25
Fuel mass feed rate (lb/min)
5,374.3
0.0
26
Fuel heating value (Btu/lb)
4,208
19,374
27
Fuel heat feed rate (Btu/min)
22,615,062.8
ND
28
Total fuel mass feed rate (kg/min)
2,437.3
29
Emission factor (mg/kg)
11.15
9.75
10.76
10.60
30
Total fuel heat feed rate (Btu/min)
22.615.062.82
31
Emission factor (|Xg/kJ)
1.14
1.00
1.10
1.08
32
Ave. Emission factor (mg/kg)
10.57
33
Ave. Emission factor (llg/kJ)
1.08
a sL/min = liters per minute at standard temperature and pressure.
b ND = not detected.
c sft3/min = cubic feel per minute at standard temperature and pressure
G-7
-------
Table G-6. Calculation of Individual Filter Emission Factors (11/01/01)
Test 11/01/2001 (individual filters)
1
Sampling time (min)
479.03
2
TF sample
T1002010
T100201N
T100201M T100201L
3
PM mass on filter (mg)
0.57
0.53
0.574
0.57
4
Array flow (sL/mina)
8.891
8.891
8.853
8.853
5
PM cone at filter (mg/L)
0.0001
0.0001
0.0001
0.0001
6b
PM mass on dilution chamber filter (mg)
0.005
6c
6d
Array flow (sL/min)
PM cone at dilution air (mg/L)
8.815
NDb
6e
Net PM mass cone after dilution (mg/L)
0.0001
0.0001
0.0001
0.0001
7
8
Probe flow (sL/min)
Probe flow (m3)
18.87
9.04
9
Dilution air (sL/min)
854.46
10
Dilution air (m3)
409.31
11
Dilution ratio
46.28
12
PM cone at stack (mg/L)
0.0061
0.0057
0.0062
0.0062
13
Stack gas velocity (fit/min)
2,745.8
14
Stack temperature (°F)
367.7
15
Stack pressure (in. Hg)
30.248
16
Stack area (ft2)
120
17
Stack flow (sft3/minc)
212,493.8
18
Stack flow (sL/min)
6,017,823.4
19
PM emission rate from stack (mg/min)
36,944.3
34,328.6
37,367.0
37,104.3
20
Fuel type
Black liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
506.33
ND
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
2,617.8
ND
25
Fuel mass feed rate (lb/min)
5,772.2
ND
26
Fuel heating value (Btu/lb)
4,208
19,374
27
Fuel heat feed rate (Btu/min)
24,289,257.7
ND
28
Total fuel mass feed rate (kg/min)
2,617.8
29
Emission factor (mg/kg)
14.11
13.11
14.27
14.17
30
Total fuel heat feed rate (Btu/min)
24,289,257.70
31
Emission factor (jxg/kj)
1.44
1.34
1.46
1.45
32
Ave. Emission factor (mg/kg)
13.92
33
Ave. Emission factor (lls/kJ)
1.42
a sL/min = standard liters per minute at standard temperature and pressure.
b ND = not detected.
c sft3/min = standard cubic feel per minute at standard temperature and pressure
G-8
-------
Appendix H
Data Tables for Individual PM25 Mass
Measurements
H-l
-------
Contents
Table Page
H-l Recovery Boiler, PM25 Mass Samples, Gravimetric Measurements of
Electric Low-Pressure Impactor (ELPI) Stages H-3
H-2 Recovery Boiler, PM25 Mass Samples, Gravimetric Measurements of
Teflon Filters H-4
H-2
-------
Table H-1. Recovery Boiler, PM25 Mass Samples, Gravimetric Measurements of
Electric Low-Pressure Impactor (ELPI) Stages
ID Initial Weight Final Weight PM Mass
mg mg mg
A101601A
IB110101H ELPI 13
32.7
32.707
0.007
A101601C
IB110101H ELPI 12
33.871
33.872
0.001
A101601D
IB110101H ELPI 11
33.216
33.237
0.021
A101601E
IB110101H ELPI 10
33.077
33.142
0.065
A101601F
IB110101H ELPI 9
32.992
33.163
0.171
A101601G
IB110101H ELPI 8
32.645
33.205
0.56
A101601H
IB110101H ELPI 7
33.404
33.83
0.426
A101601I
IB110101H ELPI 6
33.984
34.09
0.106
A101601J
IB110101H ELPI 5
33.493
33.514
0.021
A101601K
IB110101H ELPI 4
32.593
32.592
-0.001
A101601L
IB110101H ELPI 3
33.529
33.535
0.006
A101601M
IB110101H ELPI 2
33.292
33.296
0.004
A101601N
IB110101H ELPI 1
33.736
33.74
0.004
A1016010
IB110101H ELPI FB
33.883
33.885
0.002
H-3
-------
Table H-2. Recovery Boiler, PM25 Mass Samples, Gravimetric Measurements of
Teflon Filters
Initial PM Mass PM Mass
ID Weight Final Weight g mg
T100201A
IB103001HD1B1
0.195007
0.195076
6.9 x 10"5
0.069
T100201B
IB103001HR2A1
0.190933
0.192139
0.001206
1.206
T100201C
IB103001HR2B1
0.189077
0.190207
0.00113
1.13
T100201D
IB103001HR6A1
0.189015
0.190241
0.001226
1.226
T100201E
IB103001HR6B1
0.188268
0.189438
0.00117
1.17
T100201F
IB103001H-FB
0.185403
0.189399
0.003996
3.996
T100201G
IB103101HR6B1
0.152951
0.153356
0.000405
0.405
T100201H
IB103101HR6A1
0.188192
0.188603
0.000411
0.411
T100201I
IB103101HR2B1
0.154084
0.154461
0.000377
0.377
T100201J
IB103101HR2A1
0.152429
0.152858
0.000429
0.429
T100201K
IB103101HD1B1
0.197521
0.197535
1.4 x 10"5
0.014
T100201L
IB110101HR6B1
0.192915
0.193485
0.00057
0.57
T100201M
IB110101HR6A1
0.197837
0.198411
0.000574
0.574
T100201N
IB110101HR2B1
0.186827
0.187358
0.000531
0.531
T1002010
IB110101HR2A1
0.186442
0.187012
0.00057
0.57
T100201P
IB110101HD1B1
0.189353
0.189358
5. x 10"6
0.005
T100201R
BT111301H
0.18307
0.183077
7. x 10"6
0.007
H-4
-------
Appendix I
Supporting Data for Carbonyl Analysis
i-i
-------
Contents
Table Page
1-1 Carbonyls, Individual Tube Results, Blanks, Test Dates: 10/30/01 to 11/01/01 1-3
I-2A Carbonyls, Recovery Boiler #5 Individual Tube Results for Field Samples (10/30/01) .... 1-4
I-2B Carbonyls, Recovery Boiler #5 Individual Tube Results for Field Samples (10/31/01) .... 1-6
I-2C Carbonyls, Recovery Boiler #5 Individual Tube Results for Field Samples (11/01/01) .... 1-8
I-3A Carbonyls from Recovery Boiler #5 for Test Day 10/30/01 1-10
I-3B Carbonyls from Recovery Boiler #5 for Test Day 10/31/01 1-11
I-3C Carbonyls from Recovery Boiler #5 for Test Day 11/01/01 1-12
1-4 Carbonyls from Recovery Boiler #5, 10/30/01 to 11/01/01 1-13
1-2
-------
Table 1-1. Carbonyls, Individual Tube Results, Blanks, Test Dates: 10/30/01 to
11/01/01
Compound
CAS No.
Method Blank
(Rg)
Field
Blank
(Hg)
formaldehyde
50-00-0
0.0200
0.0235
acetaldehyde
75-07-0
0.0700
0.0760
acetone
67-64-1
0.2000
0.1965
propionaldehyde
123-38-6
NDa
ND
crotonaldehyde
4170-30-0
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0500
0.0460
benzaldehyde
100-52-7
ND
ND
isovaleraldehyde
590-86-3
ND
ND
valeraldehyde
110-62-3
ND
0.0065
o-tolualdehyde
529-20-4
ND
ND
m-tolualdchydc
620-23-5
ND
ND
/Molualdchyde
104-87-0
0.0400
0.0365
hexaldehyde
66-25-1
0.0200
0.0170
2,5-dimethylbenzaldehyde
5779-94-2
ND
ND
diacetyl
431-03-8
ND
ND
methacrolein
78-85-3
ND
ND
2-butanone
78-93-3
0.0100
0.0230
glyoxal
107-22-2
0.0800
0.0900
acetophenone
98-86-2
ND
ND
methylglyoxal
78-98-8
0.0400
0.0420
octanal
124-13-0
ND
ND
nonanal
124-19-6
0.1000
0.0990
Sum, Speciated
0.6300
0.6560
Sum, Unspeciated
0.8170
0.7885
Total (soeciated + unspeciated)
1.4470
1.4445
a ND = not detected.
1-3
-------
Table I-2A. Carbonyls, Recovery Boiler #5 Individual Tube Results for Field Samples (10/30/01)
Site ID
WRB#5
WRB#5
WRB#5
WRB#5
Field ID
Hd3Al
Hd3A2
Hr3Al
Hr3A2
Volume Sampled
603.83
603.83
717.15
717.5
ERG ID
23733
23734
23735
23736
Sampling Date
10/30/01
10/30/01
10/30/01
10/30/01
Analysis Date
12/21/01
12/21/01
12/21/01
12/21/01
Data File
F1LU007
F1LU008
F1LU009
F1LU010
Compound
CAS No.
DAa, front
DA, back
DA (front +
back)
RCb, front
RC, back
RC (front +
back)
Carbonyls
RC-DA
Rg
Rg
^g
^g
^g
^g
formaldehyde
50-00-0
0.0850
0.0425
0.1275
0.8995
0.0480
0.9475
0.8200
acetaldehyde
75-07-0
0.2920
0.0730
0.3650
0.7360
0.0880
0.8240
0.4590
acetone
67-64-1
0.7155
0.4455
1.1610
0.4355
0.3845
0.8200
NDC
propionaldehyde
123-38-6
0.0215
0.0085
0.0215
0.0255
ND
ND
ND
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0810
0.0565
0.1375
0.1030
0.0635
0.1665
0.0290
benzaldehyde
100-52-7
0.0110
0.0010
0.0120
0.0210
0.0050
0.0260
0.0140
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
0.0250
ND
0.0250
0.0170
ND
0.0170
ND
o-tolualdehyde
529-20-4
ND
ND
ND
0.0155
ND
0.0155
0.0155
m-tolualdchydc
620-23-5
ND
ND
ND
ND
ND
ND
ND
/Molualdchydc
104-87-0
0.0310
ND
0.0310
0.0545
ND
0.0545
0.0235
hexaldehyde
66-25-1
0.0415
0.0140
0.0555
0.0335
0.0305
0.0640
0.0085
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
ND
ND
ND
diacetyl
431-03-8
ND
ND
ND
ND
ND
ND
ND
continued
-------
Table I-2A. (concluded)
Site ID
WRB#5
WRB#5
WRB#5
WRB#5
Field ID
Hd3Al
Hd3A2
Hr3Al
Hr3A2
Volume Sampled
603.83
603.83
717.15
717.5
ERG ID
23733
23734
23735
23736
Sampling Date
10/30/01
10/30/01
10/30/01
10/30/01
Analysis Date
12/21/01
12/21/01
12/21/01
12/21/01
Data File
F1LU007
F1LU008
F1LU009
F1LU010
Compound
CAS No.
DAa, front
DA, back
DA (front +
back)
RCb, front
RC, back
RC (front +
back)
Carbonyls
RC-DA
Rg
Hg
Rg
Hg
Hg
^g
^g
methacrolein
78-85-3
ND
ND
ND
ND
ND
ND
ND
2-butanone
78-93-3
1.0100
0.0380
1.0480
0.2040
0.0460
0.2500
ND
glyoxal
107-22-2
0.0800
0.0790
0.1590
0.1510
0.0910
0.2420
0.0830
acetophenone
98-86-2
0.0600
ND
0.0600
0.0420
ND
0.0420
ND
methylglyoxal
78-98-8
0.0510
0.0440
0.0950
0.0730
0.0690
0.1420
0.0470
octanal
124-13-0
0.0160
ND
0.0160
0.0430
ND
0.0430
0.0270
nonanal
124-19-6
0.3130
0.1290
0.4420
0.2540
0.1120
0.3660
ND
Sum, Speciated
2.8335
0.9310
3.7645
3.1080
0.9375
4.0455
0.2810
Sum, Unspeciated
1.8250
1.1670
2.9920
3.6875
1.1290
4.8165
1.8245
Total (speciated + un
speciated)
4.6585
2.0980
6.7565
6.7955
2.0665
8.8620
2.1055
a DA = dilution air.
b RC = residence chamber;
c ND = not detected.
-------
Table I-2B. Carbonyls, Recovery Boiler #5 Individual Tube Results for Field Samples (10/31/01)
Site ID
WRB#5
WRB#5
WRB#5
WRB#5
Field ID
Hd3Al
Hd3A2
Hr3Al
Hr3A2
Volume Sampled
556.21
556.21
567.56
567.56
ERG ID
23737
23738
23739
23739
Sampling Date
10/31/01
10/31/01
10/31/01
10/31/01
Analysis Date
12/21/01
12/21/01
12/21/01
12/21/01
Data File
F1LU011
F1LU011
F1LU013
F1LU14
Compound
CAS No.
DAa, front
U2
DA, back
U2
DA (front +
back)
U2
RCb, front
U2
RC, back
U2
RC (front +
back)
U2
Carbonyls
RC-DA
U2
formaldehyde
50-00-0
0.0625
0.0525
0.1150
1.3095
0.0605
1.3700
1.2550
acetaldehyde
75-07-0
0.2195
0.1595
0.3790
3.2355
0.5450
3.7805
3.4015
^ acetone
On
propionaldehyde
67-64-1
0.4535
0.3190
0.7725
0.3275
0.8510
1.1785
0.4060
123-38-6
0.0080
0.0075
0.0155
0.0350
NDC
0.0350
0.0195
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0755
0.0695
0.1450
0.0830
0.0815
0.1645
0.0195
benzaldehyde
100-52-7
0.0055
0.0005
0.0060
0.0130
0.0030
0.0160
0.0100
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
0.0055
0.0055
0.0115
ND
0.1150
0.1095
o-tolualdehyde
529-20-4
ND
ND
ND
ND
ND
ND
ND
m-tolualdchydc
620-23-5
ND
ND
ND
ND
ND
ND
ND
/Molualdchydc
104-87-0
ND
ND
ND
ND
ND
ND
ND
hexaldehyde
66-25-1
0.0210
0.0180
0.0390
0.0360
0.0235
0.0595
0.0205
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
ND
ND
ND
diacetyl
431-03-8
ND
ND
ND
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
0.0210
ND
0.0210
0.0210
continued
-------
Table I-2B. (concluded)
Site ID
WRB#5
WRB#5
WRB#5
WRB#5
Field ID
Hd3Al
Hd3A2
Hr3Al
Hr3A2
Volume Sampled
556.21
556.21
567.56
567.56
ERG ID
23737
23738
23739
23739
Sampling Date
10/31/01
10/31/01
10/31/01
10/31/01
Analysis Date
12/21/01
12/21/01
12/21/01
12/21/01
Data File
F1LU011
F1LU011
F1LU013
F1LU14
Compound
CAS No.
DAa, front
U2
DA, back
U2
DA (front +
back)
U2
RCb, front
U2
RC, back
U2
RC (front +
back)
U2
Carbonyls
RC-DA
U2
2-butanone
78-93-3
0.0350
0.0540
0.0890
0.1460
0.1050
0.2510
0.1620
glyoxal
107-22-2
0.0970
0.0950
0.1920
0.1860
0.0780
0.2640
0.0720
acetophenone
98-86-2
0.0260
ND
0.0260
0.0300
ND
0.0300
0.0040
methylglyoxal
78-98-8
0.0450
0.0450
0.0900
0.0680
0.0540
0.1220
0.0320
octanal
124-13-0
0.0380
ND
0.0380
0.0700
ND
0.0700
0.0320
nonanal
124-19-6
0.2440
0.1110
0.3550
0.2730
0.1040
0.3770
0.0220
Sum, Speciated
1.3305
0.9370
2.2675
5.8450
1.9055
7.7505
5.4830
Sum, Unspeciated
1.2695
0.9855
2.2550
3.9465
1.3280
5.2745
3.0195
Total (speciated + un
speciated)
2.6000
1.9225
4.5225
9.7915
3.2335
13.0250
8.5025
a DA = dilution air.
b RC = residence chamber;
c ND = not detected.
-------
Table I-2C. Carbonyls, Recovery Boiler #5 Individual Tube Results for Field Samples (11/01/01)
Site ID
WRB#5
WRB#5
WRB#5
WRB#5
Field ID
Hd3Al
Hd3A2
Hr3Al
Hr3A2
Volume Sampled
543.08
543.08
625.85
625.85
ERG ID
23741
23742
23743
23744
Sampling Date
1/11/01
1/11/01
1/11/01
1/11/01
Analysis Date
12/22/01
12/22/01
12/22/01
12/22/01
Data File
F1LU015
F1LU016
FLU017
FLU018
Compound
CAS No.
DAa, front
DA, back
DA (front +
back)
RCb, front
RC, back
RC (front +
back)
Carbonyls
RC-DA
U2
U2
U2
U2
U2
U2
U2
formaldehyde
50-00-0
0.0630
0.0435
0.1065
1.8100
0.0460
1.8560
1.7495
acetaldehyde
75-07-0
0.5085
0.1180
0.6265
0.8085
0.143
0.9515
0.3250
acetone
67-64-1
0.2270
0.2785
0.5055
0.3670
0.4475
0.8145
0.3090
propionaldehyde
123-38-6
0.0070
NDC
0.0070
0.0325
ND
0.0325
0.0255
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0775
0.0730
0.1505
0.0790
0.1075
0.1865
0.0360
benzaldehyde
100-52-7
0.0045
0.0015
0.0060
0.0205
ND
0.0205
0.0145
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
0.0165
ND
0.0165
ND
o-tolualdehyde
529-20-4
ND
ND
ND
ND
ND
ND
ND
m-tolualdchydc
620-23-5
ND
ND
ND
ND
ND
ND
ND
/Molualdchvdc
104-87-0
0.0395
0.0395
0.0790
ND
ND
ND
ND
hexaldehyde
66-25-1
0.0265
0.0200
0.0465
0.0335
0.0200
0.0535
0.0070
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
ND
ND
ND
diacetyl
431-03-8
0.0060
ND
0.0060
0.0050
ND
0.0050
ND
methacrolein
78-85-3
ND
ND
ND
0.0090
ND
0.0090
ND
continued
-------
Table I-2C. (concluded)
Site ID
WRB#5
WRB#5
WRB#5
WRB#5
Field ID
Hd3Al
Hd3A2
Hr3Al
Hr3A2
Volume Sampled
543.08
543.08
625.85
625.85
ERG ID
23741
23742
23743
23744
Sampling Date
1/11/01
1/11/01
1/11/01
1/11/01
Analysis Date
12/22/01
12/22/01
12/22/01
12/22/01
Data File
F1LU015
F1LU016
FLU017
FLU018
Compound CAS No. DAa, front DA, back DA (front + RCb, front RC, back RC (front + Carbonyls
U2
U2
back)
U2
U2
U2
back)
U2
RC-DA
U2
2-butanone
78-93-3
0.0520
0.0510
0.1030
0.0990
0.1890
0.2880
0.1850
glyoxal
107-22-2
0.1150
0.1080
0.2230
0.2190
0.0910
0.3100
0.0870
acetophenone
98-86-2
ND
ND
ND
0.0230
ND
0.0230
ND
methylglyoxal
78-98-8
0.0750
0.0550
0.1300
0.0720
0.0520
0.1240
ND
octanal
124-13-0
0.0460
0.0330
0.0790
0.0330
ND
0.0330
ND
nonanal
124-19-6
0.2820
0.0890
0.3710
0.2500
0.0970
0.3470
ND
Sum, Speciated
1.5295
0.9100
2.4395
3.8775
1.1930
5.0705
2.6310
Sum, Unspeciated
1.2995
1.0195
2.3190
4.2480
1.3645
5.6125
3.2935
Total (speciated + unspeciated)
2.8290
1.9295
4.7585
8.1255
2.5575
10.6830
5.9245
a DA = dilution air.
b RC = residence chamber;
c ND = not detected.
-------
Table I-3A. Carbonyls from Recovery Boiler #5 for Test Day 10/30/01
Compound
CAS No.
RC-DA1
10/30/01
Uncertainty
Plus/Minus
%
Total
Uncertainty
Plus/Minus
formaldehyde
50-00-0
0.82
0.0904
38.946
4.292
acetaldehyde
75-07-0
0.4590
0.0052
21.800
0.249
acetone
67-64-1
NDb
propionaldehyde
123-38-6
ND
crotonaldehyde
4170-30-0
ND
butyr/isobutyraldehyde
123-72-8
0.0290
0.0017
1.377
0.080
benzaldehyde
100-52-7
0.0140
0.0004
0.665
0.020
isovaleraldehyde
590-86-3
ND
valeraldehyde
110-62-3
ND
o-tolualdehyde
529-20-4
0.0155
0.0002
0.736
0.010
m-tolualdchvdc
620-23-5
ND
/Molualdchvdc
104-87-0
0.0235
0.0013
1.116
0.063
hexaldehyde
66-25-1
0.0085
0.0008
0.404
0.038
2,5 -dimethylbenzaldehyde
5779-94-2
ND
diacetyl
431-03-8
ND
methacrolein
78-85-3
ND
2-butanone
78-93-3
ND
glyoxal
107-22-2
0.0830
0.0023
3.942
0.108
acetophenone
98-86-2
ND
methylglyoxal
78-98-8
0.0470
0.0058
2.232
0.274
octanal
124-13-0
0.0270
0.0022
1.282
0.103
nonanal
124-19-6
ND
Sum, Speciated
0.2810
Sum, Unspeciated
1.8245
Total (speciated + unspeciated)
2.1055
a RC = residence chamber; DA = dilution air.
b ND = not detected.
1-10
-------
Table I-3B. Carbonyls from Recovery Boiler #5 for Test Day 10/31/01
Compound
CAS No.
RC-DA1
Uncertainty
Plus/Minus
%
Total
Uncertainty
Plus/Minus
formaldehyde
50-00-0
1.2550
0.1383
14.5828
1.6070
acetaldehyde
75-07-0
3.4015
0.0388
39.5248
0.4506
acetone
67-64-1
0.406
0.0172
43.8682
1.8556
propionaldehyde
123-38-6
0.0195
0.0001
0.2266
0.0000
crotonaldehyde
4170-30-0
NDb
butyr/isobutyraldehyde
123-72-8
0.0195
0.0011
0.2266
0.0132
benzaldehyde
100-52-7
0.0100
0.0003
0.1162
0.0036
isovaleraldehyde
590-86-3
ND
valeraldehyde
110-62-3
0.1095
0.0105
1.2724
0.1219
o-tolualdehyde
529-20-4
ND
m-tolualdehyde
620-23-5
ND
/Molualdchydc
104-87-0
ND
hexaldehyde
66-25-1
0.0205
0.0019
0.2382
0.0222
2,5 -dimethylbenzaldehyde
5779-94-2
ND
diacetyl
431-03-8
ND
methacrolein
78-85-3
0.021
0.0012
0.0143
0.0008
2-butanone
78-93-3
0.1620
0.0132
1.8824
0.1530
glyoxal
107-22-2
0.0720
0.0020
0.8366
0.0228
acetophenone
98-86-2
0.0040
0.0002
0.0465
0.0022
methylglyoxal
78-98-8
0.0320
0.0039
0.3718
0.0457
octanal
124-13-0
0.0320
0.0026
0.3718
0.0300
nonanal
124-19-6
0.0220
0.0018
0.2556
0.0206
Sum, Speciated
5.5865
Sum, Unspeciated
3.0195
Total (speciated + unspeciated)
8.6060
a RC = residence chamber; DA = dilution air.
b ND = not detected.
1-11
-------
Table I-3C. Carbonyls from
Recovery Boiler #5 for Test Day 11/01/01
Compound
CAS No.
RC-DA"
Uncertainty
Plus/Minus
%
Total
Uncertainty
Plus/Minus
formaldehyde
50-00-0
1.7495
0.1928
29.5299
3.2542
acetaldehyde
75-07-0
0.325
0.0037
5.4857
0.0625
acetone
67-64-1
0.3090
0.0131
5.2156
0.2206
propionaldehyde
123-38-6
0.0255
0.0002
0.4304
0.0028
crotonaldehyde
4170-30-0
NDb
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.036
0.0021
0.6076
0.0355
benzaldehyde
100-52-7
0.0145
0.0004
0.2447
0.0075
isovaleraldehyde
590-86-3
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
ND
o-tolualdehyde
529-20-4
ND
ND
ND
ND
m-tolualdchydc
620-23-5
ND
ND
ND
ND
/Molualdchvdc
104-87-0
ND
ND
ND
ND
hexaldehyde
66-25-1
0.007
0.0007
0.1182
0.0110
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
diacetyl
431-03-8
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
2-butanone
78-93-3
0.1850
0.0150
3.1226
0.2539
glyoxal
107-22-2
0.0870
0.0024
1.4685
0.0401
acetophenone
98-86-2
ND
ND
ND
ND
methylglyoxal
78-98-8
ND
ND
ND
ND
octanal
124-13-0
ND
ND
ND
ND
nonanal
124-19-6
ND
ND
ND
ND
Sum, Speciated
2.6310
Sum, Unspeciated
3.2935
Total (speciated + unspeciated)
5.9245
a RC = residence chamber; DA = dilution air.
b ND = not detected.
1-12
-------
Table 1-4. Carbonyls from Recovery Boiler #5, 10/30/01 to 11/01/01
Compound
CAS No.
Field Blank
Rg
RC-DA1
10/30/01
Hg
RC-DA
10/31/01
Hg
RC-DA
11/01/01
Rg
formaldehyde
50-00-0
0.0235
0.8200
1.2550
1.7495
acetaldehyde
75-07-0
0.0760
0.4590
3.4015
0.3250
acetone
67-64-1
0.1965
NDb
0.4060
0.3090
propionaldehyde
123-38-6
ND
ND
0.0195
0.0255
crotonaldehyde
4170-30-0
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0460
0.0290
0.0195
0.0360
benzaldehyde
100-52-7
ND
0.0140
0.01
0.0145
isovaleraldehyde
590-86-3
ND
ND
ND
ND
valeraldehyde
110-62-3
0.0065
ND
0.1095
ND
o-tolualdehyde
529-20-4
ND
0.0155
ND
ND
m-tolualdchvdc
620-23-5
ND
ND
ND
ND
/Molualdchvdc
104-87-0
0.0365
0.0235
ND
ND
hexaldehyde
66-25-1
0.0170
0.0085
0.0205
0.0070
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
diacetyl
431-03-8
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
0.0210
ND
2-butanone
78-93-3
0.0230
ND
0.1620
0.1850
glyoxal
107-22-2
0.0900
0.0830
0.0720
0.0870
acetophenone
98-86-2
ND
ND
0.0040
ND
methylglyoxal
78-98-8
0.0420
0.0470
0.0320
ND
octanal
124-13-0
ND
0.0270
0.0320
ND
nonanal
124-19-6
0.0990
ND
0.0220
ND
Sum, Speciated
0.6560
0.2810
5.4830
2.6310
Sum, Unspeciated
0.7885
1.8245
3.0195
3.2935
Total (soeciated + unspeciated)
1.4445
2.1055
8.5025
5.9245
a RC = residence chamber; DA = dilution air.
b ND = not detected.
1-13
-------
Appendix J
Supporting Data for Air Toxics Analysis
j-i
-------
Contents
Table Page
J-l Air Toxics for Recovery Boiler #5 Field Test—Laboratory Blank and
Ambient Air (10/3 0/01) J-3
J-2A Air Toxics from Recovery Boiler #5 for Test Day 10/30/01 J-5
J-2B Air Toxics from Recovery Boiler #5 for Test Day 10/31/01 J-7
J-2C Air Toxics from Recovery Boiler #5 for Test Day 11/01/01 J-9
J-3 Daily Air Toxics from Recovery Boiler #5 Compared to Ambient J-l 1
J-4 Summary of Air Toxics from Recovery Boiler #5 J-13
J-2
-------
Table J-1. Air Toxics for Recovery Boiler #5, Field Test—Laboratory
Blank and Ambient Air (10/30/01)
Compound
CAS No.
Laboratory
Blank
l-tg/m3
Ambient Air
M'g/m3
acetylene
74-86-2
NDa
0.71
propylene
115-07-1
ND
0.26
dichlorodifluoromethane
75-71-8
ND
2.85
chloromethane
74-87-3
ND
1.11
dichlorotetrafluoroethane
1320-37-2
ND
ND
vinyl chloride
75-01-4
ND
ND
1,3-butadiene
106-99-0
ND
ND
bromomethane
74-83-9
ND
ND
chloroethane
75-00-3
ND
ND
acetonitrile
75-05-8
ND
ND
acetone
67-64-1
ND
ND
trichlorofluoromethane
75-69-4
ND
1.41
acrylonitrile
107-13-1
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
methylene chloride
75-09-2
ND
0.15
trichlorotrifluoroethane
26523-64-8
ND
0.65
trans-1,2-dichloroethylene
56-60-5
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
chloroprene
126-99-8
ND
ND
cis-1,3 -dichloroethy lene
156-59-2
ND
ND
bromochloromethane
74-97-5
ND
ND
chloroform
67-66-3
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
0.16
benzene
71-43-2
0.07
0.74
carbon tetrachloride
56-23-5
ND
0.65
tert-amyl methyl ether
994-05-8
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ethyl acrylate
140-88-5
ND
ND
bromodichloromethane
75-27-4
ND
ND
trichloroethylene
79-01-6
ND
ND
methyl methacrylate
80-62-6
ND
ND
continued
J-3
-------
Table J-1. (concluded)
Compound
CAS No.
Laboratory
Blank
Hg/m3
Ambient Air
M-g/m3
cis-1,2-dichloropropene
10061-01-5
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
toluene
108-88-3
0.06
1.11
dibromochloromethane
124-48-1
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
«-octanc
111-65-9
ND
ND
tetrachloroethylene
127-18-4
ND
ND
chlorobenzene
108-90-7
ND
ND
ethylbenzene
100-41-4
ND
0.30
m-, /^-xylene
108-38-3/106-42-3
ND
1.40
bromoform
75-25-2
ND
ND
styrene
100-42-5
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
o-xylene
95-47-6
ND
0.35
1,3,5 -trimethylbenzene
108-67-8
ND
0.08
1,2,4-trimethylbenzene
95-63-6
ND
0.31
m-d i ch 1 o ro be n ze n e
541-73-1
ND
ND
chloromethylbenzene
100-44-7
ND
ND
/>dichlorobcnzcnc
106-46-7
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
a ND = not detected.
J-4
-------
Table J-2A. Air Toxics from Recovery Boiler #5 for Test Day 10/30/01
Residence
Dilution
Air Toxics
Ambient
Mg/m3
Compounds
CAS No.
Chamber
Air
RC-DA1
M-g/m3
M-g/m3
M-g/m3
acetylene
74-86-2
2.60
0.65
1.95
0.71
propylene
115-07-1
0.80
0.42
0.38
0.26
dichlorodifluoromethane
75-71-8
1.74
1.65
0.09
2.85
chloromethane
74-87-3
0.85
0.83
0.02
1.11
dichlorotetrafluoroethane
1320-37-2
NDb
ND
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
ND
acetonitrile
75-05-8
ND
ND
ND
ND
acetone
67-64-1
ND
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
ND
ND
1.41
acrylonitrile
107-13-1
ND
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
ND
methylene chloride
75-09-2
ND
ND
ND
0.15
trichlorotrifluoroethane
26523-64-8
ND
ND
ND
0.65
trans-1,2-dichloroethylene
56-60-5
ND
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
ND
chloroprene
126-99-8
ND
ND
ND
ND
67. v-1,3-dichloroethylene
156-59-2
ND
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
0.16
benzene
71-43-2
0.73
0.13
0.60
0.74
carbon tetrachloride
56-23-5
ND
ND
ND
0.65
tert-amyl methyl ether
994-05-8
ND
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
ND
bromodichloromethane
75-27-4
ND
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
ND
continued
J-5
-------
Table J-2A. (concluded)
Compounds
CAS No.
Residence
Chamber
M-g/m3
Dilution
Air
M-g/m3
Air Toxics
RC-DA1
M-g/m3
Ambient
Mg/m3
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
ND
ND
toluene
108-88-3
0.95
0.24
0.71
1.11
dibromochloromethane
124-48-1
ND
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
ND
/7-octane
111-65-9
ND
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ND
ethylbenzene
100-41-4
0.39
0.11
0.28
0.30
m-, /^-xylene
108-38-3/106-42-3
1.03
0.34
0.69
1.40
bromoform
75-25-2
ND
ND
ND
ND
styrene
100-42-5
ND
0.10
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
ND
o-xylene
95-47-6
0.37
ND
ND
0.35
1,3,5 -trimethylbenzene
108-67-8
ND
0.09
ND
0.08
1,2,4-trimethylbenzene
95-63-6
0.41
0.12
0.29
0.31
OT-dichlorobenzcne
541-73-1
ND
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
ND
ND
a RC = residence chamber; DA = dilution air.
b ND = not detected.
J-6
-------
Table J-2B. Air Toxics from Recovery Boiler #5 for Test Day 10/31/01
Compounds
CAS No.
Residence
Chamber
Hg/m3
Dilution
Air
Hg/m3
Air Toxics
RC-DA1
Hg/m3
acetylene
74-86-2
0.87
0.50
0.37
propylene
115-07-1
0.89
0.60
0.29
dichlorodifluoromethane
75-71-8
1.44
1.93
-0.49
chloromethane
74-87-3
1.35
1.41
-0.06
dichlorotetrafluoroethane
1320-37-2
NDb
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
acetonitrile
75-05-8
ND
ND
ND
acetone
67-64-1
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
ND
ND
acrylonitrile
107-13-1
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
methylene chloride
75-09-2
ND
ND
ND
trichlorotrifluoroethane
26523-64-8
ND
ND
ND
trans-1,2-dichloroethylene
56-60-5
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
chloroprene
126-99-8
ND
ND
ND
67. v-1,3-dichloroethylene
156-59-2
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
benzene
71-43-2
0.90
0.14
0.76
carbon tetrachloride
56-23-5
ND
ND
ND
tert-amyl methyl ether
994-05-8
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
bromodichloromethane
75-27-4
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
continued
J-7
-------
Table J-2B. (concluded)
Residence
Dilution
Air Toxics
Compounds
CAS No.
Chamber
Air
RC-DA1
Hg/m3
M-g/m3
Hg/m3
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
ND
toluene
108-88-3
0.87
0.18
0.69
dibromochloromethane
124-48-1
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
/7-octane
111-65-9
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ethylbenzene
100-41-4
0.33
0.08
0.25
m-, /^-xylene
108-38-3/106-42-3
1.20
0.20
1
bromoform
75-25-2
ND
ND
ND
styrene
100-42-5
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
o-xylene
95-47-6
0.33
0.08
0.25
1,3,5 -trimethylbenzene
108-67-8
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.36
0.11
0.25
m-dichlorobcnzcnc
541-73-1
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
ND
a RC = residence chamber; DA = dilution air.
b ND = not detected.
J-8
-------
Table J-2C. Air Toxics from Recovery Boiler #5 for Test Day 11/01/01
Compounds
CAS No.
Residence
Chamber
Hg/m3
Dilution
Air
Hg/m3
Air Toxics
RC-DA1
Hg/m3
acetylene
74-86-2
0.98
0.68
0.3
propylene
115-07-1
1.32
1.05
0.27
dichlorodifluoromethane
75-71-8
2.14
2.31
NDb
chloromethane
74-87-3
1.16
2.12
ND
dichlorotetrafluoroethane
1320-37-2
ND
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
acetonitrile
75-05-8
ND
ND
ND
acetone
67-64-1
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
0.08
ND
acrylonitrile
107-13-1
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
methylene chloride
75-09-2
ND
0.54
ND
trichlorotrifluoroethane
26523-64-8
ND
ND
ND
trans-1,2-dichloroethylene
56-60-5
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
chloroprene
126-99-8
ND
ND
ND
67. v-1,3-dichloroethylene
156-59-2
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
benzene
71-43-2
1.21
0.13
1.08
carbon tetrachloride
56-23-5
ND
ND
ND
tert-amyl methyl ether
994-05-8
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
bromodichloromethane
75-27-4
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
continued
J-9
-------
Table J-2C. (concluded)
Residence
Dilution
Air Toxics
Compounds
CAS No.
Chamber
Air
RC-DA1
Jlg/m3
M-g/m3
Jlg/m3
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
ND
toluene
108-88-3
0.86
0.17
0.69
dibromochloromethane
124-48-1
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
/7-octane
111-65-9
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ethylbenzene
100-41-4
0.27
0.05
0.22
m-, /^-xylene
108-38-3/106-42-3
1.39
0.28
1.11
bromoform
75-25-2
ND
ND
ND
styrene
100-42-5
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
o-xylene
95-47-6
0.32
0.09
0.23
1,3,5 -trimethylbenzene
108-67-8
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.39
0.09
0.3
m-dichlorobcnzcnc
541-73-1
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
ND
a RC = residence chamber; DA = dilution air.
b ND = not detected.
J-10
-------
Table J-3. Daily Air Toxics from Recovery Boiler #5 Compared to Ambient
Ambient
10/30/01
M-g/m3
Air Toxics
Air Toxics
Air Toxics
Compounds
CAS No.
RC-DA1
10/30/01
RC-DA
10/31/01
RC-DA
11/01/01
M-g/m3
l-tg/m3
l-tg/m3
acetylene
74-86-2
0.71
1.95
0.37
0.3
propylene
115-07-1
0.26
0.38
0.29
0.27
dichlorodifluoromethane
75-71-8
2.85
0.09
NDb
ND
chloromethane
74-87-3
1.11
0.02
ND
ND
dichlorotetrafluoroethane
1320-37-2
ND
ND
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
ND
acetonitrile
75-05-8
ND
ND
ND
ND
acetone
67-64-1
ND
ND
ND
ND
trichlorofluoromethane
75-69-4
1.41
ND
ND
ND
acrylonitrile
107-13-1
ND
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
ND
methylene chloride
75-09-2
0.15
ND
ND
ND
trichlorotrifluoroethane
26523-64-8
0.65
ND
ND
ND
trans-1,2-dichloroethylene
56-60-5
ND
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
ND
chloroprene
126-99-8
ND
ND
ND
ND
67. v-1,3-dichloroethylene
156-59-2
ND
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
0.16
ND
ND
ND
benzene
71-43-2
0.74
0.6
0.76
1.08
carbon tetrachloride
56-23-5
0.65
ND
ND
ND
tert-amyl methyl ether
994-05-8
ND
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
ND
bromodichloromethane
75-27-4
ND
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
ND
continued
J-ll
-------
Table J-3. (concluded)
Ambient
Air Toxics
Air Toxics
Air Toxics
Compounds
CAS No.
RC-DA1
RC-DA
RC-DA
10/30/01
Hg/m3
10/30/01
10/31/01
11/01/01
Hg/m3
Hg/m3
Hg/m3
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
ND
ND
toluene
108-88-3
1.11
0.71
0.69
0.69
dibromochloromethane
124-48-1
ND
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
ND
/7-octane
111-65-9
ND
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ND
ethylbenzene
100-41-4
0.30
0.28
0.25
0.22
m-, /^-xy lene
108-38-3/106-42-3
1.40
0.69
1.00
1.11
bromoform
75-25-2
ND
ND
ND
ND
styrene
100-42-5
ND
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
ND
o-xylene
95-47-6
0.35
0.37
0.25
0.23
1,3,5 -trimethylbenzene
108-67-8
0.08
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.31
0.29
0.25
0.3
m-dichlorobcnzcnc
541-73-1
ND
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
ND
/?-dichlorobenzene
106-46-7
ND
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
ND
ND
a RC = residence chamber; DA = dilution air.
b ND = not detected.
J-12
-------
Table J-4. Summary of Air Toxics from Recovery Boiler #5
Ambient
M-g/m3
RC-DA1
RC-DA
RC-DA
Compounds Detected
CAS No.
10/30/01
10/31/01
11/01/01
M'g/m3
M-g/m3
|^g/m3
acetylene
74-86-2
0.71
1.95
0.37
0.3
propylene
115-07-1
0.26
0.38
0.29
0.27
dichlorodifluoromethane
75-71-8
2.85
0.09
NDb
ND
chloromethane
74-87-3
1.11
0.02
ND
ND
trichlorofluoromethane
75-69-4
1.41
ND
ND
ND
methylene chloride
75-09-2
0.15
ND
ND
ND
trichlorotrifluoroethane
26253-64-8
0.65
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
0.16
ND
ND
ND
benzene
71-43-2
0.74
0.6
0.76
1.08
carbon tetrachloride
56-23-5
0.65
ND
ND
ND
toluene
108-88-3
1.11
0.71
0.69
0.69
ethylbenzene
100-41-4
0.30
0.28
0.25
0.22
m-, /^-xy lene
108-38-3/106-42-3
1.4
0.69
1.00
1.11
o-xylene
95-47-6
0.35
0.37
0.25
0.23
1,3,5 -trimethylbenzene
108-67-8
0.08
ND
ND
ND
1,2.4-trimethylbenzene
95-63-6
0.31
0.29
0.25
0.3
a RC = residence chamber; DA = dilution air.
b ND = not detected.
J-13
-------
Appendix K
Supporting Data for Speciated and Unspeciated
Nonmethane Organic Compounds
K-l
-------
Contents
Table Page
K-l Recovery Boiler #5 Field Test Laboratory Blank and Ambient SNMOCs on 10/30/01 . . K-3
K-2A SNMOCs Collected in Canisters from Recovery Boiler #5 on Test Day 10/30/01 K-6
K-2B SNMOCs Collected in Canisters from Recovery Boiler #5 on Test Day 10/31/01 K-10
K-2C SNMOCs Collected in Canisters from Recovery Boiler #5 on Test Day 11/01/01 K-14
K-3 Summary of SNMOCs Collected in Canisters from Recovery Boiler #5 for Tests
10/30/01 through 11/01/01 K-18
K-4A Total SNMOCs Collected from Recovery Boiler #5 on Test Day 10/30/01 K-21
K-4B Total SNMOCs Collected from Recovery Boiler #5 on Test Day 10/31/01 K-25
K-4C Total SNMOCs Collected from Recovery Boiler #5 on Test Day 11/01/01 K-29
K-5A SNMOC Values for 10/30/01 in SPECIATE Format K-33
K-5B SNMOC Values for 10/31/01 in SPECIATE Format K-36
K-5C SNMOC Values for 11/01/01 in SPECIATE Format K-39
K-6A Calculation of Mass of SNMOCs Collected on 10/30/01 K-42
K-6B Calculation of Mass of SNMOCs Collected on 10/31/01 K-43
K-6C Calculation of Mass of SNMOCs Collected on 11/01/01 K-44
K-7 Summary of SNMOCs from Recovery Boiler #5 for All Test Days as Weight
Percent of Total K-45
K-2
-------
Table K-1. Recovery Boiler #5 Field Test Laboratory Blank and Ambient
SNMOCs3 on 10/30/01
Compound
CAS No.
Laboratory
Blank
|-Lg/m3
Ambient
ERG #23725
|-Lg/m3
ethylene
74-85-1
0.12
1.03
acetylene
74-86-2
0.14
1.00
ethane
74-84-0
0.12
5.19
propylene
115-07-1
NDb
0.37
propane
74-98-6
0.08
4.16
propyne
74-99-7
ND
ND
isobutane
75-28-5
ND
1.00
isobutene/1 -butene
115-11-7/106-98-0
ND
0.33
1,3-butadiene
106-99-0
ND
ND
butane
106-97-8
ND
2.23
trans-2-butQnQ
624-64-6
ND
0.12
c7.v-2-butene
590-18-1
ND
0.17
3 -methyl-1 -butene
563-45-1
ND
ND
isopentane
78-78-4
0.09
1.70
1-pentene
109-67-1
ND
0.18
2-methyl-1 -butene
563-46-2
ND
0.09
/7-pentane
109-66-0
ND
0.93
isoprene
78-79-4
ND
0.21
fra«s-2-pentene
646-04-8
ND
1.25
c7.v-2-pcntene
627-20-3
0.09
0.15
2-methyl-2-butene
513-35-9
ND
ND
2,2-dimethylbutane
75-83-2
0.10
0.30
cyclopentene
142-29-0
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
cyclopentane
287-92-3
ND
0.19
2,3 -dimethy lbutane
79-29-8
0.08
0.37
2-methylpentane
107-83-5
0.57
0.67
3-methylpentane
96-14-0
0.08
0.50
2-methyl-1 -pentene
763-29-1
ND
ND
1-hexene
592-41-6
0.10
0.26
2-ethyl-l-butene
760-21-4
ND
ND
/7-hexane
110-54-3
ND
0.62
fra«s-2-hexene
4050-45-7
ND
ND
c7.v-2-hcxene
7688-21-3
ND
ND
continued
K-3
-------
Table K-1. (continued)
Compound
CAS No.
Laboratory
Blank
M-g/m3
Ambient
ERG #23725
M-g/m3
methylcyclopentane
96-37-7
ND
0.30
2,4-dimethylpentane
108-08-7
0.07
0.22
benzene
71-43-2
0.07
0.69
cyclohexane
110-82-7
0.08
0.22
2-methylhexane
591-76-4
ND
0.25
2,3-dimethylpentane
565-59-3
0.14
0.35
3-methylhexane
589-34-4
0.10
0.34
1-heptene
592-76-7
ND
ND
2,2,4-trimethylpentane
540-84-1
ND
0.36
/7-heptane
142-82-5
ND
0.30
methylcyclohexane
108-87-2
0.08
0.27
2,2,3 -trimethylpentane
564-02-3
ND
ND
2,3,4-trimethylpentane
565-75-3
ND
0.17
toluene
108-88-3
0.09
0.98
2-methylheptane
592-27-8
ND
0.13
3-methylheptane
589-81-1
ND
0.15
1-octene
111-66-0
ND
0.00
/7-octane
111-65-9
ND
0.26
ethylbenzene
100-41-4
ND
0.28
«7-xylcnc//>xylcnc
108-38-3/106-42-3
ND
0.61
styrene
100-42-5
ND
0.26
o-xylene
95-47-6
ND
0.27
1-nonene
124-11-8
ND
ND
/7-nonane
111-84-2
ND
0.21
isopropylbenzene
98-82-8
ND
0.16
alpha-pinene
80-56-8
ND
0.58
/7-propylbcnzcne
103-65-1
ND
0.13
OT-cthyltolucne
620-14-4
ND
0.20
/;-cthyltolucnc
622-96-8
ND
0.17
1,3,5 -trimethylbenzene
108-67-8
ND
0.12
o-ethyltoluene
611-14-3
ND
0.17
beta-pinene
127-91-3
ND
0.29
1,2,4-trimethylbenzene
95-63-6
0.07
0.29
1-decene
872-05-9
ND
ND
«-dccanc
124-18-5
0.08
0.26
1,2,3-trimethylbenzene
526-73-8
ND
0.08
continued
K-4
-------
Table K-1. (concluded)
Laboratory
Ambient
Compound
CAS No.
Blank
ERG #23725
M-g/m3
M-g/m3
m-dicthylbcnzcnc
141-93-5
ND
0.13
/;-dicthylbcnzcnc
105-05-5
ND
ND
1-undecene
821-95-4
ND
ND
«-undccanc
1120-21-4
0.13
0.39
1-dodecene
112-41-4
ND
ND
«-dodccanc
112-40-3
0.34
0.85
1-tridecene
2437-56-1
ND
ND
«-tridccanc
629-50-5
ND
0.16
Total Speciated
2.82
33.62
Total Unspeciated
6.18
40.36
Total (speciated + unspeciated)0
9.00
73.98
a SNMOCs = speciated nonmethane organic compounds.
b ND = not detected.
c Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
K-5
-------
Table K-2A. SNMOCs3 Collected in Canisters from Recovery Boiler #5 on Test Day 10/30/01
Residence „ . . Dilution >
, Residence .. Dilution
Compound CAS No. V_3™20L Chamber ^ ^ol
Hg/m3 |lg/m3
SNMOC
RC-DAb
Hg
SNMOC
RC-DA
(no negs)c
Hg
ethylene
74-85-1
2.23
0.0087
1.38
0.0054
0.0033
0.0033
acetylene
74-86-2
2.99
0.0117
1.01
0.0040
0.0078
0.0078
ethane
74-84-0
6.31
0.0247
5.80
0.0227
0.0020
0.0020
propylene
115-07-01
0.94
0.0037
0.50
0.0020
0.0017
0.0017
propane
74-98-6
3.01
0.0118
2.39
0.0094
0.0024
0.0024
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
0.50
0.0020
0.19
0.0007
0.0012
0.0012
isobutene/1 -butene
115-11-7/106-98-0
0.50
0.0020
0.24
0.0009
0.0010
0.0010
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.94
0.0037
0.32
0.0013
0.0024
0.0024
/ram-2-butcnc
624-64-6
0.46
0.0018
0.11
0.0004
0.0014
0.0014
c7.v-2-butcne
590-18-1
0.64
0.0025
0.16
0.0006
0.0019
0.0019
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.85
0.0033
0.26
0.0010
0.0023
0.0023
1-pentene
109-67-1
0.49
0.0019
0.13
0.0005
0.0014
0.0014
2-methyl-1 -butene
563-46-2
ND
ND
0.65
0.0025
-0.0025
ND
/7-pentane
109-66-0
0.57
0.0022
0.16
0.0006
0.0016
0.0016
isoprene
78-79-4
0.43
0.0017
0.11
0.0004
0.0013
0.0013
/ram-2-pentene
646-04-8
ND
ND
0.43
0.0017
-0.0017
ND
c7.v-2-pcntene
627-20-3
0.61
0.0024
0.18
0.0007
0.0017
0.0017
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
0.84
0.0033
0.27
0.0011
0.0022
0.0022
continued
-------
Table K-2A. (continued)
Compound
CAS No.
Residence
Chamber
V=3.920L
Hg/m3
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
0.60
2,3 -dimethy lbutane
79-29-8
0.98
2-methylpentane
107-83-5
1.43
3-methylpentane
96-14-0
0.82
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
1.04
2-ethyl-l-butene
760-21-4
ND
/7-hexane
110-54-3
0.73
fra«s-2-hexene
4050-45-7
ND
c7\-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
0.63
2,4-dimethylpentane
108-08-7
0.67
benzene
71-43-2
0.68
cyclohexane
110-82-7
0.62
2-methylhexane
591-76-4
0.43
2,3 -dimethy lpentane
565-59-3
1.19
3-methylhexane
589-34-4
0.75
1-heptene
592-76-7
ND
2,2,4-trimethylpentane
540-84-1
0.81
/7-heptane
142-82-5
0.51
Residence
Chamber
Hg
Dilution
Air
V=3.920L
Hg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
^g
SNMOC
RC-DA
(no negs)1
^g
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0024
0.20
0.0008
0.0016
0.0016
0.0038
0.27
0.0011
0.0028
0.0028
0.0056
0.21
0.0008
0.0048
0.0048
0.0032
0.23
0.0009
0.0023
0.0023
ND
ND
ND
ND
ND
0.0041
0.26
0.0010
0.0031
0.0031
ND
ND
ND
ND
ND
0.0029
0.19
0.0007
0.0021
0.0021
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0025
0.16
0.0006
0.0018
0.0018
0.0026
0.16
0.0006
0.0020
0.0020
0.0027
0.16
0.0006
0.0020
0.0020
0.0024
0.22
0.0009
0.0016
0.0016
0.0017
0.13
0.0005
0.0012
0.0012
0.0047
0.29
0.0011
0.0035
0.0035
0.0029
0.08
0.0003
0.0026
0.0026
ND
ND
ND
ND
ND
0.0032
0.16
0.0006
0.0025
0.0025
0.0020
0.12
0.0005
0.0015
0.0015
continued
-------
Table K-2A. (continued)
Compound
CAS No.
Residence
Chamber
V=3.920L
Hg/m3
methylcyclohexane
108-87-2
0.72
2,2,3 -trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.51
toluene
108-88-3
0.84
2-methylheptane
592-27-8
0.42
3-methylheptane
589-81-1
0.47
1-octene
111-66-0
ND
/7-octanc
111-65-9
0.56
ethylbenzene
100-41-4
0.39
«7-xylcnc//>xylcnc
108-38-3/106-42-3
0.57
styrene
100-42-5
ND
o-xylene
95-47-6
0.42
1-nonene
124-11-8
ND
«-nonanc
111-84-2
0.35
isopropylbenzene
98-82-8
0.55
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.34
m-cthyltolucnc
620-14-4
0.32
/;-cthvltolucnc
622-96-8
0.57
1,3,5 -trimethylbenzene
108-67-8
0.33
o-ethyltoluene
611-14-3
0.41
beta-pinene
127-91-3
0.46
Residence
Chamber
Hg
Dilution
Air
V=3.920L
Hg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
^g
SNMOC
RC-DA
(no negs)1
^g
0.0028
0.16
0.0006
0.0022
0.0022
ND
ND
ND
ND
ND
0.0020
0.13
0.0005
0.0015
0.0015
0.0033
0.25
0.0010
0.0023
0.0023
0.0016
0.11
0.0004
0.0012
0.0012
0.0018
0.12
0.0005
0.0014
0.0014
ND
ND
ND
ND
ND
0.0022
0.11
0.0004
0.0018
0.0018
0.0015
0.09
0.0004
0.0012
0.0012
0.0022
0.16
0.0006
0.0016
0.0016
ND
0.08
0.0003
-0.0003
ND
0.0016
0.12
0.0005
0.0012
0.0012
ND
ND
ND
ND
ND
0.0014
0.11
0.0004
0.0009
0.0009
0.0022
0.11
0.0004
0.0017
0.0017
ND
0.25
0.0010
-0.0010
ND
0.0013
0.09
0.0004
0.0010
0.0010
0.0013
0.10
0.0004
0.0009
0.0009
0.0022
0.13
0.0005
0.0017
0.0017
0.0013
0.07
0.0003
0.0010
0.0010
0.0016
0.09
0.0004
0.0013
0.0013
0.0018
0.16
0.0006
0.0012
0.0012
continued
-------
Table K-2A. (concluded)
Compound
CAS No.
Residence
Chamber
V=3.920L
Hg/m3
Residence
Chamber
Hg
Dilution
Air
V=3.920L
Hg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
^g
SNMOC
RC-DA
(no negs)c
^g
1,2,4-trimethylbenzene
95-63-6
0.45
0.0018
0.15
0.0006
0.0012
0.0012
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
/7-dccanc
124-18-5
0.44
0.0017
0.16
0.0006
0.0011
0.0011
1,2,3 -trimethylbenzene
526-73-8
ND
ND
ND
ND
ND
ND
m-dicthylbcnzcnc
141-93-5
0.36
0.0014
0.07
0.0003
0.0011
0.0011
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
0.59
0.0023
0.29
0.0011
0.0012
0.0012
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
/7-dodccanc
112-40-3
0.55
0.0022
0.63
0.0025
-0.0003
0.0000
1-tridecene
2437-56-1
ND
ND
ND
0.0000
0.0000
0.0000
/7-tridccanc
629-50-5
ND
ND
ND
0.0000
0.0000
0.0000
Total Speciated
44.82
0.1757
20.87
0.0818
0.0939
0.0997
Total Unspeciated
51.00
0.1999
23.12
0.0906
0.1093
0.1093
Total (speciated + unspeciated)6
95.82
0.3756
43.99
0.1724
0.2032
0.2090
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |ag/m3 is an estimate based on propane only.
-------
Table K-2B. SNMOCs3 Collected in Canisters from Recovery Boiler #5 on Test Day 10/31/01
Compound
CAS No.
Residence
Chamber
V=3.9L
|^g/m3
Residence
Chamber
Rg
Dilution
Air
10/31/01
M'g/m3
Dilution
Air
Rg
SNMOC
RC-DAb
^g
SNMOC
RC-DA
(no negs)1
Hg
ethylene
74-85-1
2.84
0.0111
2.03
0.0087
0.0023
0.0023
acetylene
74-86-2
0.91
0.0035
0.73
0.0031
0.0004
0.0004
ethane
74-84-0
7.59
0.0296
7.41
0.0319
-0.0023
NDd
propylene
115-07-01
1.01
0.0039
0.70
0.0030
0.0009
0.0009
propane
74-98-6
3.49
0.0136
2.95
0.0127
0.0009
0.0009
propyne
74-99-7
ND
ND
ND
ND
ND
ND
isobutane
75-28-5
0.50
0.0020
0.23
0.0010
0.0010
0.0010
isobutene/1 -butene
115-11-7/106-98-0
0.73
0.0028
0.25
0.0011
0.0018
0.0018
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.91
0.0035
0.36
0.0015
0.0020
0.0020
trans-2-butQnQ
624-64-6
0.47
0.0018
0.13
0.0006
0.0013
0.0013
c7.v-2-butcnc
590-18-1
0.61
0.0024
0.19
0.0008
0.0016
0.0016
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.82
0.0032
0.24
0.0010
0.0022
0.0022
1-pentene
109-67-1
0.43
0.0017
0.13
0.0006
0.0011
0.0011
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
0.47
0.0018
0.17
0.0007
0.0011
0.0011
isoprene
78-79-4
0.35
0.0014
0.12
0.0005
0.0008
0.0008
fra«s-2-pentene
646-04-8
ND
ND
0.12
0.0005
-0.0005
ND
c7.v-2-pcntene
627-20-3
0.57
0.0022
0.16
0.0007
0.0015
0.0015
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.01
0.0039
0.20
0.0009
0.0031
0.0031
continued
-------
Table K-2B. (continued)
Compound
CAS No.
Residence
Chamber
V=3.9L
|-Lg/m3
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
0.50
2,3 -dimethy lbutane
79-29-8
0.92
2-methylpentane
107-83-5
1.32
3-methylpentane
96-14-0
0.77
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
0.95
2-ethyl-l-butene
760-21-4
ND
/7-hexane
110-54-3
0.60
fra«s-2-hexene
4050-45-7
ND
c7.v-2-hcxene
7688-21-3
ND
methylcyclopentane
96-37-7
0.52
2,4-dimethylpentane
108-08-7
0.61
benzene
71-43-2
1.08
cyclohexane
110-82-7
0.73
2-methylhexane
591-76-4
0.40
2,3 -dimethy lpentane
565-59-3
1.02
3-methylhexane
589-34-4
0.52
1-heptene
592-76-7
0.41
2,2,4-trimethylpentane
540-84-1
0.71
/7-heptane
142-82-5
0.48
Residence
Chamber
Hg
Dilution
Air
10/31/01
|-Lg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
Hg
SNMOC
RC-DA
(no negs)1
Rg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0020
0.11
0.0005
0.0015
0.0015
0.0036
0.25
0.0011
0.0025
0.0025
0.0051
0.12
0.0005
0.0046
0.0046
0.0030
0.21
0.0009
0.0021
0.0021
ND
ND
ND
ND
ND
0.0037
0.23
0.0010
0.0027
0.0027
ND
ND
ND
ND
ND
0.0023
0.17
0.0007
0.0016
0.0016
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0020
0.13
0.0006
0.0015
0.0015
0.0024
0.17
0.0007
0.0016
0.0016
0.0042
0.16
0.0007
0.0035
0.0035
0.0028
0.19
0.0008
0.0020
0.0020
0.0016
0.11
0.0005
0.0011
0.0011
0.0040
0.24
0.0010
0.0029
0.0029
0.0020
0.24
0.0010
0.0010
0.0010
0.0016
ND
ND
0.0016
0.0016
0.0028
0.17
0.0007
0.0020
0.0020
0.0019
0.12
0.0005
0.0014
0.0014
continued
-------
Table K-2B. (continued)
Compound
CAS No.
Residence
Chamber
V=3.9L
|-Lg/m3
methylcyclohexane
108-87-2
0.54
2,2,3 -trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.47
toluene
108-88-3
0.66
2-methylheptane
592-27-8
0.40
3-methylheptane
589-81-1
0.44
1-octene
111-66-0
ND
/7-octanc
111-65-9
0.43
ethylbenzene
100-41-4
0.35
«?-xylcnc//>x\icnc
108-38-3/106-42-3
ND
styrene
100-42-5
ND
o-xylene
95-47-6
0.45
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
0.40
isopropylbenzene
98-82-8
0.54
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.37
m-cthyltolucnc
620-14-4
0.31
/;-cthyl toluene
622-96-8
0.61
1,3,5 -trimethylbenzene
108-67-8
0.28
o-ethyltoluene
611-14-3
0.42
beta-pinene
127-91-3
ND
Residence
Chamber
Hg
Dilution
Air
10/31/01
|-Lg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
Hg
SNMOC
RC-DA
(no negs)1
Rg
0.0021
0.15
0.0006
0.0015
0.0015
ND
ND
ND
ND
ND
0.0018
0.11
0.0005
0.0014
0.0014
0.0026
0.09
0.0004
0.0022
0.0022
0.0016
0.09
0.0004
0.0012
0.0012
0.0017
0.09
0.0004
0.0013
0.0013
ND
ND
ND
ND
ND
0.0017
0.14
0.0006
0.0011
0.0011
0.0014
0.08
0.0003
0.0010
0.0010
ND
0.15
0.0006
-0.0007
ND
ND
ND
ND
ND
ND
0.0018
0.08
0.0003
0.0014
0.0014
ND
ND
ND
ND
ND
0.0016
0.10
0.0004
0.0011
0.0011
0.0021
0.15
0.0006
0.0015
0.0015
ND
ND
ND
ND
ND
0.0014
0.08
0.0003
0.0011
0.0011
0.0012
0.07
0.0003
0.0009
0.0009
0.0024
0.10
0.0004
0.0019
0.0019
0.0011
0.09
0.0004
0.0007
0.0007
0.0016
0.09
0.0004
0.0013
0.0013
ND
ND
ND
ND
ND
continued
-------
Table K-2B. (concluded)
Residence
„ , „. „ ., Chamber
Compound CAS No. ^
|lg/m
3
1,2,4-trimethylbenzene 95-63-6 0.36
1-decene 872-05-9 ND
«-decane 124-18-5 0.39
1,2,3-trimethylbenzene 526-73-8 ND
m-dicthylbcnzcnc 141-93-5 ND
/^-diethyl benzene 105-05-5 ND
1-undecene 821-95-4 ND
/7-undccanc 1120-21-4 0.36
W 1-dodecene 112-41-4 ND
oj «-dodecane 112-40-3 ND
1-tridecene 2437-56-1 ND
/7-tridccanc 629-50-5 ND
Total Speciated 42.03
Total Unspeciated 47.29
Total (speciated + unspeciated)* 89.32
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
Residence
Chamber
Hg
0.0014
ND
0.0015
ND
ND
ND
ND
0.0014
ND
ND
ND
ND
0.1639
0.1844
0.3483
Dilution
Air
10/31/01
\lglm3
0.12
ND
0.14
ND
0.08
ND
ND
0.17
ND
0.24
ND
ND
21.15
23.34
44.49
Dilution
Air
Hg
0.0005
ND
0.0006
ND
0.0003
ND
ND
0.0007
ND
0.0010
ND
ND
0.0909
0.1004
0.1913
SNMOC
RC-DAb
Hg
0.0009
ND
0.0009
ND
-0.0003
ND
ND
0.0007
ND
-0.0010
ND
ND
0.0730
0.0841
0.1570
SNMOC
RC-DA
(no negs)c
Hg
0.0009
ND
0.0009
ND
0.0000
ND
ND
0.0007
ND
ND
ND
ND
0.0778
0.0841
0.1618
-------
Table K-2C. SNMOCs3 Collected in Canisters from Recovery Boiler #5 on Test Day 11/01/01
Residence „ . . Dilution >
, Residence .. Dilution
Compound CAS No. V-3™92L Chamber 291L
|Ig/m3 |Ig/m3
SNMOC
RC-DAb
SNMOC
RC-DA
(no negs)c
Hg
ethylene
74-85-1
1.76
0.0069
0.95
0.0041
0.0028
0.0028
acetylene
74-86-2
1.08
0.0042
1.03
0.0044
-0.0002
NDd
ethane
74-84-0
3.35
0.0130
2.98
0.0128
0.0003
0.0003
propylene
115-07-01
1.37
0.0053
1.14
0.0049
0.0004
0.0004
propane
74-98-6
5.81
0.0226
5.19
0.0223
0.0003
0.0003
propyne
74-99-7
ND
ND
ND
ND
ND
ND
isobutane
75-28-5
0.43
0.0017
0.22
0.0009
0.0007
0.0007
isobutene/1 -butene
115-11-7/106-98-0
0.65
0.0025
0.27
0.0012
0.0014
0.0014
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.88
0.0034
0.40
0.0017
0.0017
0.0017
/ram-2-butcnc
624-64-6
0.51
0.0020
0.13
0.0006
0.0014
0.0014
c7.v-2-butcne
590-18-1
0.57
0.0022
0.16
0.0007
0.0015
0.0015
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.80
0.0031
0.28
0.0012
0.0019
0.0019
1-pentene
109-67-1
0.41
0.0016
0.10
0.0004
0.0012
0.0012
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
0.57
0.0022
0.17
0.0007
0.0015
0.0015
isoprene
78-79-4
0.38
0.0015
0.12
0.0005
0.0010
0.0010
/ram-2-pentene
646-04-8
ND
ND
0.12
0.0005
-0.0005
ND
c7.v-2-pcntene
627-20-3
0.69
0.0027
0.16
0.0007
0.0020
0.0020
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
0.97
0.0038
0.23
0.0010
0.0028
0.0028
continued
-------
Table K-2C. (continued)
Compound
CAS No.
Residence
Chamber
V=3.892L
|-Lg/m3
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
0.61
2,3 -dimethy lbutane
79-29-8
0.91
2-methylpentane
107-83-5
0.35
3-methylpentane
96-14-0
0.92
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
0.97
2-ethyl-l-butene
760-21-4
ND
/7-hexane
110-54-3
0.75
fra«s-2-hexene
4050-45-7
ND
c7\-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
0.63
2,4-dimethylpentane
108-08-7
0.68
benzene
71-43-2
1.22
cyclohexane
110-82-7
0.72
2-methylhexane
591-76-4
0.44
2,3 -dimethy lpentane
565-59-3
1.15
3-methylhexane
589-34-4
0.66
1-heptene
592-76-7
0.61
2,2,4-trimethylpentane
540-84-1
0.52
/7-heptane
142-82-5
0.51
Residence
Chamber
Hg
Dilution
Air
V=4.291L
|-Lg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
Hg
SNMOC
RC-DA
(no negs)1
Rg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0024
0.13
0.0006
0.0018
0.0018
0.0035
0.24
0.0010
0.0025
0.0025
0.0014
0.26
0.0011
0.0002
0.0002
0.0036
0.21
0.0009
0.0027
0.0027
ND
ND
ND
ND
ND
0.0038
0.24
0.0010
0.0027
0.0027
ND
ND
ND
ND
ND
0.0029
0.40
0.0017
0.0012
0.0012
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0025
0.20
0.0009
0.0016
0.0016
0.0026
0.17
0.0007
0.0019
0.0019
0.0047
0.15
0.0006
0.0041
0.0041
0.0028
0.16
0.0007
0.0021
0.0021
0.0017
0.12
0.0005
0.0012
0.0012
0.0045
0.31
0.0013
0.0031
0.0031
0.0026
0.17
0.0007
0.0018
0.0018
0.0024
ND
ND
0.0024
0.0024
0.0020
0.15
0.0006
0.0014
0.0014
0.0020
0.12
0.0005
0.0015
0.0015
continued
-------
Table K-2C. (continued)
Compound
CAS No.
Residence
Chamber
V=3.892L
|-Lg/m3
methylcyclohexane
108-87-2
0.60
2,2,3 -trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.50
toluene
108-88-3
0.78
2-methylheptane
592-27-8
0.42
3-methylheptane
589-81-1
0.45
1-octene
111-66-0
ND
/7-octanc
111-65-9
0.52
ethylbenzene
100-41-4
0.37
«7-xylcnc//>xylcnc
108-38-3/106-42-3
0.60
styrene
100-42-5
ND
o-xylene
95-47-6
0.60
1-nonene
124-11-8
ND
«-nonanc
111-84-2
0.37
isopropylbenzene
98-82-8
0.56
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.35
m-cthyltolucnc
620-14-4
0.29
/;-cthvltolucnc
622-96-8
0.44
1,3,5 -trimethylbenzene
108-67-8
0.28
o-ethyltoluene
611-14-3
0.39
beta-pinene
127-91-3
ND
Residence
Chamber
Hg
Dilution
Air
V=4.291L
|-Lg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
Hg
SNMOC
RC-DA
(no negs)1
Rg
0.0023
0.16
0.0007
0.0016
0.0016
ND
ND
ND
ND
ND
0.0019
0.19
0.0008
0.0011
0.0011
0.0030
0.17
0.0007
0.0023
0.0023
0.0016
0.09
0.0004
0.0012
0.0012
0.0018
0.11
0.0005
0.0013
0.0013
ND
ND
ND
ND
ND
0.0020
0.14
0.0006
0.0014
0.0014
0.0014
0.09
0.0004
0.0011
0.0011
0.0023
0.11
0.0005
0.0019
0.0019
ND
0.10
0.0004
-0.0004
ND
0.0023
0.10
0.0004
0.0019
0.0019
ND
ND
ND
ND
ND
0.0014
0.10
0.0004
0.0010
0.0010
0.0022
0.09
0.0004
0.0018
0.0018
ND
ND
ND
ND
ND
0.0014
ND
ND
0.0014
0.0014
0.0011
0.08
0.0003
0.0008
0.0008
0.0017
0.11
0.0005
0.0012
0.0012
0.0011
0.10
0.0004
0.0007
0.0007
0.0015
0.07
0.0003
0.0012
0.0012
ND
ND
ND
ND
ND
continued
-------
Table K-2C. (concluded)
Compound
CAS No.
Residence
Chamber
V=3.892L
|-Lg/m3
Residence
Chamber
Hg
Dilution
Air
V=4.291L
|-Lg/m3
Dilution
Air
Hg
SNMOC
RC-DAb
Hg
SNMOC
RC-DA
(no negs)c
Rg
1,2,4-trimethylbenzene
95-63-6
0.46
0.0018
0.12
0.0005
0.0013
0.0013
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
/7-dccanc
124-18-5
0.41
0.0016
0.20
0.0009
0.0007
0.0007
1,2,3 -trimethylbenzene
526-73-8
ND
ND
0.07
0.0003
-0.0003
ND
m-dicthylbcnzcnc
141-93-5
0.41
0.0016
0.10
0.0004
0.0012
0.0012
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
0.38
0.0015
0.54
0.0023
-0.0008
ND
!1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
| /7-dodccanc
112-40-3
ND
ND
0.45
0.0019
-0.0019
ND
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
41.06
0.1598
19.97
0.0857
0.0741
0.0783
Total Unspeciated
48.51
0.1888
22.46
0.0964
0.0924
0.0924
Total (speciated + unspeciated)6
89.57
0.3486
42.43
0.1821
0.1665
0.1708
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
-------
Table K-3. Summary of SNMOCs3 Collected in Canisters from Recovery Boiler #5 for
Tests 10/30/01 through 11/01/01
Compound
CAS No.
No Negsb
SNMOC
RC-DAC
10/30/01
Hg
No Negs
SNMOC
RC-DA
10/31/01
Hg
No Negs
SNMOC
RC-DA
11/01/01
ng
ethylene
74-85-1
0.0033
0.0023
0.0028
acetylene
74-86-2
0.0078
0.0004
NDd
ethane
74-84-0
0.0020
ND
0.0003
propylene
115-07-1
0.0017
0.0009
0.0004
propane
74-98-6
0.0024
0.0009
0.0003
propyne
74-99-7
ND
ND
ND
isobutane
75-28-5
0.0012
0.0010
0.0007
isobutene/1 -butene
115-11-7/106-98-0
0.0010
0.0018
0.0014
1,3-butadiene
106-99-0
ND
ND
ND
/7-butane
106-97-8
0.0024
0.0020
0.0017
trans-2-butQnQ
624-64-6
0.0014
0.0013
0.0014
c7.v-2-butene
590-18-1
0.0019
0.0016
0.0015
3 -methyl-1 -butene
563-45-1
ND
ND
ND
isopentane
78-78-4
0.0023
0.0022
0.0019
1-pentene
109-67-1
0.0014
0.0011
0.0012
2-methyl-1 -butene
563-46-2
ND
ND
ND
/7-pentane
109-66-0
0.0016
0.0011
0.0015
isoprene
78-79-4
0.0013
0.0008
0.0010
fra«s-2-pentene
646-04-8
ND
ND
ND
c7.v-2-pcntene
627-20-3
0.0017
0.0015
0.0020
2-methyl-2-butene
513-35-9
ND
ND
ND
2,2-dimethylbutane
75-83-2
0.0022
0.0031
0.0028
cyclopentene
142-29-0
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
cyclopentane
287-92-3
0.0016
0.0015
0.0018
2,3 -dimethy lbutane
79-29-8
0.0028
0.0025
0.0025
2-methylpentane
107-83-5
0.0048
0.0046
0.0002
3-methylpentane
96-14-0
0.0023
0.0021
0.0027
2-methyl-1 -pentene
763-29-1
ND
ND
ND
1-hexene
592-41-6
0.0031
0.0027
0.0027
2-ethyl-l-butene
760-21-4
ND
ND
ND
/7-hexane
110-54-3
0.0021
0.0016
0.0012
trans-2-hexene
4050-45-7
ND
ND
ND
continued
K-18
-------
Table K-3. (continued)
No Negsb
No Negs
No Negs
SNMOC
SNMOC
SNMOC
Compound
CAS No.
RC-DAC
RC-DA
RC-DA
10/30/01
10/31/01
11/01/01
^g
c7.v-2-hcxcnc
7688-21-3
ND
ND
ND
methylcyclopentane
96-37-7
0.0018
0.0015
0.0016
2,4-dimethylpentane
108-08-7
0.0020
0.0016
0.0019
benzene
71-43-2
0.0020
0.0035
0.0041
cyclohexane
110-82-7
0.0016
0.0020
0.0021
2-methylhexane
591-76-4
0.0012
0.0011
0.0012
2,3 -dimethylpentane
565-59-3
0.0035
0.0029
0.0031
3-methylhexane
589-34-4
0.0026
0.0010
0.0018
1-heptene
592-76-7
ND
0.0016
0.0024
2,2,4-trimethylpentane
540-84-1
0.0025
0.0020
0.0014
/7-heptane
142-82-5
0.0015
0.0014
0.0015
methylcyclohexane
108-87-2
0.0022
0.0015
0.0016
2,2,3 -trimethylpentane
564-02-3
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
0.0015
0.0014
0.0011
toluene
108-88-3
0.0023
0.0022
0.0023
2-methylheptane
592-27-8
0.0012
0.0012
0.0012
3-methylheptane
589-81-1
0.0014
0.0013
0.0013
1-octene
111-66-0
ND
ND
ND
/7-octane
111-65-9
0.0018
0.0011
0.0014
ethylbenzene
100-41-4
0.0012
0.0010
0.0011
«?-xvlcnc//>xylcnc
108-38-3/106-42-3
0.0016
ND
0.0019
styrene
100-42-5
ND
ND
ND
o-xylene
95-47-6
0.0012
0.0014
0.0019
1-nonene
124-11-8
ND
ND
ND
/7-nonane
111-84-2
0.0009
0.0011
0.0010
isopropylbenzene
98-82-8
0.0017
0.0015
0.0018
alpha-pinene
80-56-8
ND
ND
ND
/7-propylbcnzene
103-65-1
0.0010
0.0011
0.0014
m-cthyltolucnc
620-14-4
0.0009
0.0009
0.0008
/;-ethyltoluene
622-96-8
0.0017
0.0019
0.0012
1,3,5 -trimethylbenzene
108-67-8
0.0010
0.0007
0.0007
o-ethyltoluene
611-14-3
0.0013
0.0013
0.0012
beta-pinene
127-91-3
0.0012
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.0012
0.0009
0.0013
continued
K-19
-------
Table K-3. (concluded)
No Negsb
No Negs
No Negs
SNMOC
SNMOC
SNMOC
Compound
CAS No.
RC-DAC
RC-DA
RC-DA
10/30/01
10/31/01
11/01/01
^g
1-decene
872-05-9
ND
ND
ND
/7-dccanc
124-18-5
0.0011
0.0009
0.0007
1,2,3 -trimethylbenzene
526-73-8
ND
ND
ND
m-dicthylbcnzcnc
141-93-5
0.0011
ND
0.0012
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
/7-undccanc
1120-21-4
0.0012
0.0007
ND
1-dodecene
112-41-4
ND
ND
ND
/7-dodccanc
112-40-3
ND
ND
ND
1-tridecene
2437-56-1
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
Total Speciated
0.0997
0.0778
0.0783
Total Unspeciated
0.1093
0.0841
0.0924
Total (speciated + unspeciated)6
0.2090
0.1618
0.1708
a SNMOCs = speciated nonmethane organic compounds.
b compounds for which DA>RC are listed as ND or zero.
c RC = residence chamber; DA = dilution air.
d ND = not detected.
e Total NMOC with unknowns in |j.g/m3 is an estimate based on propane only.
K-20
-------
Table K-4A. Total SNMOCs3 Collected from Recovery Boiler #5 on Test Day 10/30/01
Residence
Residence
Dilution
Dilution
Chamber
Chamber
Air
Air
pp n \ b
RC-DA
Compound
CAS No.
Canister
Total
Canister
Total
KV -U:\
(no negs)c
(V=3.920L)
Collected
(V=3.920L)
Collected
M-g
Rg
|^g/m3
Hg
|^g/m3
Hg
ethylene
74-85-1
2.23
948.5621
1.38
573.5213
375.0408
375.0408
acetylene
74-86-2
2.99
1271.8389
1.01
419.7511
852.0878
852.0878
ethane
74-84-0
6.31
2684.0480
5.8
2410.4520
273.5960
273.5960
propylene
115-07-1
0.94
399.8423
0.5
207.7976
192.0447
192.0448
propane
74-98-6
3.01
1280.3462
2.39
993.2725
287.0737
287.0737
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
0.5
212.6821
0.19
78.9631
133.7190
133.7190
isobutene/1 -butene
115-11-7/106-98-0
0.5
212.6821
0.24
99.7428
112.9393
112.9393
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.94
399.8423
0.32
132.9905
266.8519
266.8519
trans-2-butQnQ
624-64-6
0.46
195.6675
0.11
45.7155
149.9521
149.9521
c7.v-2-butcnc
590-18-1
0.64
272.2331
0.16
66.4952
205.7379
205.7379
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.85
361.5596
0.26
108.0547
253.5048
253.5048
1-pentene
109-67-1
0.49
208.4285
0.13
54.0274
154.4011
154.4011
2-methyl-1 -butene
563-46-2
ND
0.0000
0.65
270.1369
-270.1369
ND
/7-pentane
109-66-0
0.57
242.4576
0.16
66.4952
175.9624
175.9624
isoprene
78-79-4
0.43
182.9066
0.11
45.7155
137.1911
137.1911
fra«s-2-pentene
646-04-8
ND
ND
0.43
178.7059
-178.7059
ND
c7.v-2-pcntene
627-20-3
0.61
259.4722
0.18
74.8071
184.6650
184.6650
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
continued
-------
Table K-4A. (continued)
Compound
CAS No.
Residence
Chamber
Canister
(V=3.920L)
|-Lg/m3
2,2-dimethylbutane
75-83-2
0.84
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
0.6
2,3 -dimethy lbutane
79-29-8
0.98
2-methylpentane
107-83-5
1.43
3-methylpentane
96-14-0
0.82
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
1.04
2-ethyl-l-butene
760-21-4
ND
/7-hexane
110-54-3
0.73
fra«s-2-hexene
4050-45-7
ND
c7\-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
0.63
2,4-dimethylpentane
108-08-7
0.67
benzene
71-43-2
0.68
cyclohexane
110-82-7
0.62
2-methylhexane
591-76-4
0.43
2,3 -dimethy lpentane
565-59-3
1.19
3-methylhexane
589-34-4
0.75
1-heptene
592-76-7
ND
2,2,4-trimethylpentane
540-84-1
0.81
Residence
Dilution
Dilution
Chamber
Air
Air
nr TV\ b
RC-DA
Total
Canister
Total
KL-UA
(no negs)c
Collected
(V=3.920L)
Collected
^g
Hg
Rg
|-Lg/m3
Rg
357.3059
0.27
112.2107
245.0952
245.0952
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
255.2185
0.2
83.1190
172.0995
172.0995
416.8569
0.27
112.2107
304.6462
304.6462
608.2708
0.21
87.2750
520.9958
520.9958
348.7986
0.23
95.5869
253.2117
253.2117
ND
ND
ND
ND
ND
442.3788
0.26
108.0547
334.3240
334.3240
ND
ND
ND
ND
ND
310.5159
0.19
78.9631
231.5528
231.5528
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
267.9794
0.16
66.4952
201.4842
201.4842
284.9940
0.16
66.4952
218.4988
218.4988
289.2476
0.16
66.4952
222.7524
222.7524
263.7258
0.22
91.4309
172.2949
172.2949
182.9066
0.13
54.0274
128.8792
128.8792
506.1834
0.29
120.5226
385.6608
385.6608
319.0231
0.08
33.2476
285.7755
285.7755
ND
ND
ND
ND
ND
344.5450
0.16
66.4952
278.0498
278.0498
continued
-------
Table K-4A. (continued)
Compound
CAS No.
Residence
Chamber
Canister
(V=3.920L)
|-Lg/m3
/7-hcptanc
142-82-5
0.51
methylcyclohexane
108-87-2
0.72
2,2,3 -trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.51
toluene
108-88-3
0.84
2-methylheptane
592-27-8
0.42
3-methylheptane
589-81-1
0.47
1-octene
111-66-0
ND
«-octanc
111-65-9
0.56
ethylbenzene
100-41-4
0.39
«?-xylcnc//>xvlcnc
108-38-3/106-42-3
0.57
styrene
100-42-5
ND
o-xylene
95-47-6
0.42
1-nonene
124-11-8
ND
«-nonanc
111-84-2
0.35
isopropylbenzene
98-82-8
0.55
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.34
m-cthyltolucnc
620-14-4
0.32
/;-cth\ ltolucnc
622-96-8
0.57
1,3,5 -trimethylbenzene
108-67-8
0.33
o-ethyltoluene
611-14-3
0.41
Residence
Dilution
Dilution
Chamber
Air
Air
nr TV\ b
RC-DA
Total
Canister
Total
KL-liA
(no negs)c
Collected
(V=3.920L)
Collected
^g
Hg
Rg
|-Lg/m3
Rg
216.9357
0.12
49.8714
167.0643
167.0643
306.2622
0.16
66.4952
239.7670
239.7670
ND
ND
ND
ND
ND
216.9357
0.13
54.0274
162.9084
162.9084
357.3059
0.25
103.8988
253.4071
253.4071
178.6530
0.11
45.7155
132.9375
132.9375
199.9212
0.12
49.8714
150.0497
150.0498
ND
ND
ND
ND
ND
238.2039
0.11
45.7155
192.4885
192.4885
165.8920
0.09
37.4036
128.4885
128.4885
242.4576
0.16
66.4952
175.9624
175.9624
ND
0.08
33.2476
-33.2476
ND
178.6530
0.12
49.8714
128.7815
128.7815
ND
ND
ND
ND
ND
148.8775
0.11
45.7155
103.1620
103.1620
233.9503
0.11
45.7155
188.2348
188.2348
ND
0.25
103.8988
-103.8988
ND
144.6238
0.09
37.4036
107.2203
107.2203
136.1165
0.1
41.5595
94.5570
94.5570
242.4576
0.13
54.0274
188.4302
188.4302
140.3702
0.07
29.0917
111.2785
111.2785
174.3993
0.09
37.4036
136.9958
136.9958
continued
-------
Table K-4A. (concluded)
Residence
Chamber
Compound CAS No. Canister
(V=3.920L)
llg/m3
beta-pinene 127-91-3 0.46
1,2,4-trimethylbenzene 95-63-6 0.45
1-decene 872-05-9 ND
«-decane 124-18-5 0.44
1,2,3-trimethylbenzene 526-73-8 ND
m-dicthylbcnzcnc 141-93-5 0.36
/;-dicthylbcnzcnc 105-05-5 ND
1-undecene 821-95-4 ND
/7-undccanc 1120-21-4 0.59
1-dodecene 112-41-4 ND
«-dodecane 112-40-3 0.55
1-tridecene 2437-56-1 ND
/7-tridccanc 629-50-5 ND
Total Speciated 44.82
Total Unspeciated 51
Total (speciated + unspeciated)6 95.82
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |j.g/m3 is an estimate based on propane only.
Residence
Dilution
Dilution
Chamber
Air
Air
nr TV\ b
RC-DA
Total
Canister
Total
KL-1JA
(no negs)c
Collected
(V=3.920L)
Collected
^g
Hg
Rg
|-Lg/m3
Rg
195.6675
0.16
66.4952
129.1723
129.1723
191.4139
0.15
62.3393
129.0746
129.0746
ND
ND
ND
ND
ND
187.1602
0.16
66.4952
120.6650
120.6650
ND
ND
ND
ND
ND
153.1311
0.07
29.0917
124.0394
124.0395
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
250.9649
0.29
120.5226
130.4423
130.4423
ND
ND
ND
ND
ND
233.9503
0.63
261.8250
-27.8747
0.0000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
19,064.8230
21,693.5737
40,758.3967
20.87
23.12
43.99
8,673.4714 10,391.3516 11,005.2150
9,608.5606 12,085.0131 12,085.0130
18,282.0320 22,476.3647 23,090.2290
-------
Table K-4B. Total SNMOCs3 Collected from Recovery Boiler #5 on Test Day 10/31/01
Residence
Residence
Dilution
Dilution
Chamber
Chamber
Air
Air
RC-DAb
RC-DA
Compound
CAS No.
Canister
Total
Canister
Total
(no negs)c
V=3.9L
Collected
V=4.3L
Collected
Ug
Ug
Ug/m3
Ug
Ug/m3
US
ethylene
74-85-1
2.84
1197.2507
2.03
837.3835
359.8672
359.8672
acetylene
74-86-2
0.91
383.6261
0.73
301.1281
82.4981
82.4981
ethane
74-84-0
7.59
3199.6946
7.41
3056.6560
143.0387
143.0387
propylene
115-07-1
1.01
425.7828
0.7
288.7529
137.0299
137.0299
propane
74-98-6
3.49
1471.2693
2.95
1216.8873
254.3820
254.3820
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
0.50
210.7836
0.23
94.8760
115.9076
115.9076
W isobutene/l-butene
115-11-7/106-98-0
0.73
307.7440
0.25
103.1260
204.6180
204.6180
bi 1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.91
383.6261
0.36
148.5015
235.1246
235.1246
/ram-2-butcnc
624-64-6
0.47
198.1366
0.13
53.6255
144.5110
144.5110
c7.v-2-butcne
590-18-1
0.61
257.1560
0.19
78.3758
178.7802
178.7802
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.82
345.6851
0.24
99.0010
246.6841
246.6841
1-pentene
109-67-1
0.43
181.2739
0.13
53.6255
127.6483
127.6483
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
0.47
198.1366
0.17
70.1257
128.0108
128.0108
isoprene
78-79-4
0.35
147.5485
0.12
49.5005
98.0480
98.0480
/ram-2-pentene
646-04-8
ND
ND
0.12
49.5005
-49.5005
ND
c7.v-2-pcntene
627-20-3
0.57
240.2933
0.16
66.0007
174.2926
174.2926
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
continued
-------
Table K-4B. (continued)
Compound
CAS No.
Residence
Chamber
Canister
V=3.9L
Ug/m3
2,2-dimethylbutane
75-83-2
1.01
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
0.5
2,3 -dimethy lbutane
79-29-8
0.92
2-methylpentane
107-83-5
1.32
3-methylpentane
96-14-0
0.77
2-methyl-1 -pen-tene
763-29-1
ND
1-hexene
592-41-6
0.95
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
0.6
/ram-2-hcxcnc
4050-45-7
ND
c7\-2-hcxcnc
7688-21-3
ND
methylcyclopen-tane
96-37-7
0.52
2,4-dimethylpen-tane
108-08-7
0.61
benzene
71-43-2
1.08
cyclohexane
110-82-7
0.73
2-methylhexane
591-76-4
0.4
2,3 -dimethy lpen-tane
565-59-3
1.02
3-methylhexane
589-34-4
0.52
1-heptene
592-76-7
0.41
2,2,4-trimethyl-pentane
540-84-1
0.71
Residence
Chamber
Total
Collected
US
Dilution
Air
Canister
V=4.3L
Ug/m3
Dilution
Air
Total
Collected
US
RC-DAb
Ug
RC-DA
(no negs)c
Hg
425.7828
0.2
82.5008
343.2820
343.2820
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
210.7836
0.11
45.3755
165.4081
165.4081
387.8418
0.25
103.1260
284.7157
284.7157
556.4686
0.12
49.5005
506.9681
506.9681
324.6067
0.21
86.6259
237.9808
237.9808
ND
ND
ND
ND
ND
400.4888
0.23
94.8760
305.6128
305.6128
ND
ND
ND
ND
ND
252.9403
0.17
70.1257
182.8146
182.8146
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
219.2149
0.13
53.6255
165.5894
165.5894
257.1560
0.17
70.1257
187.0302
187.0302
455.2925
0.16
66.0007
389.2918
389.2918
307.7440
0.19
78.3758
229.3682
229.3682
168.6269
0.11
45.3755
123.2514
123.2514
429.9985
0.24
99.0010
330.9975
330.9975
219.2149
0.24
99.0010
120.2139
120.2139
172.8425
0
0.0000
172.8425
172.8425
299.3127
0.17
70.1257
229.1870
229.1870
continued
-------
Table K-4B. (continued)
Compound
CAS No.
Residence
Chamber
Canister
V=3.9L
Ug/m3
/7-hcptanc
142-82-5
0.48
methylcyclohex-ane
108-87-2
0.54
2,2,3 -trimethyl-pentane
564-02-3
ND
2,3,4-trimethyl-pentane
565-75-3
0.47
toluene
108-88-3
0.66
2-methylheptane
592-27-8
0.4
3-methylheptane
589-81-1
0.44
1-octene
111-66-0
ND
«-octanc
111-65-9
0.43
ethylbenzene
100-41-4
0.35
«?-xylcnc//>xvlcnc
108-38-3/106-42-3
ND
styrene
100-42-5
ND
o-xylene
95-47-6
0.45
1-nonene
124-11-8
ND
«-nonanc
111-84-2
0.4
isopropylbenzene
98-82-8
0.54
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.37
m-cthyltolucnc
620-14-4
0.31
/;-eth\ ltoluene
622-96-8
0.61
1,3,5 -trimethyl-benzene
108-67-8
0.28
o-ethyltoluene
611-14-3
0.42
Residence
Chamber
Total
Collected
US
Dilution
Air
Canister
V=4.3L
Ug/m3
Dilution
Air
Total
Collected
US
RC-DAb
Ug
RC-DA
(no negs)c
Hg
202.3522
0.12
49.5005
152.8517
152.8517
227.6463
0.15
61.8756
165.7706
165.7706
ND
ND
ND
ND
ND
198.1366
0.11
45.3755
152.7611
152.7611
278.2343
0.09
37.1254
241.1089
241.1089
168.6269
0.09
37.1254
131.5015
131.5015
185.4895
0.09
37.1254
148.3642
148.3642
ND
ND
ND
ND
ND
181.2739
0.14
57.7506
123.5233
123.5233
147.5485
0.08
33.0003
114.5482
114.5482
ND
0.15
61.8756
-61.8756
ND
ND
ND
ND
ND
ND
189.7052
0.08
33.0003
156.7049
156.7049
ND
ND
ND
ND
ND
168.6269
0.1
41.2504
127.3764
127.3764
227.6463
0.15
61.8756
165.7706
165.7706
ND
ND
ND
ND
ND
155.9798
0.08
33.0003
122.9795
122.9795
130.6858
0.07
28.8753
101.8105
101.8105
257.1560
0.1
41.2504
215.9055
215.9055
118.0388
0.09
37.1254
80.9134
80.9134
177.0582
0.09
37.1254
139.9328
139.9328
continued
-------
Table K-4B. (concluded)
Residence
Chamber
Compound CAS No. Canister
V=3.9L
M
m
3
beta-pinene 127-91-3 ND
1,2,4-trimethyl-benzene 95-63-6 0.36
1-decene 872-05-9 ND
«-decane 124-18-5 0.39
1,2,3-trimethyl-benzene 526-73-8 ND
m-dicthylbcnzcnc 141-93-5 ND
/;-diethylbenzene 105-05-5 ND
1-undecene 821-95-4 ND
/7-undecane 1120-21-4 0.36
00
1-dodecene 112-41-4 ND
/7-dodccanc 112-40-3 ND
1-tridecene 2437-56-1 ND
/7-tridccanc 629-50-5 ND
Total Speciated 42.03
Total Unspeciated 47.29
Total (speciated + unspeciated)6 89.32
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
Residence
Chamber
Total
Collected
US
Dilution
Air
Canister
V=4.3L
Ug/m3
Dilution
Air
Total
Collected
US
RC-DAb
RC-DA
(no negs)c
Hg
ND
ND
ND
ND
ND
151.7642
0.12
49.5005
102.2637
102.2637
ND
ND
ND
ND
ND
164.4112
0.14
57.7506
106.6606
106.6606
ND
ND
ND
ND
ND
ND
0.08
33.0003
-33.0003
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
151.7642
0.17
70.1257
81.6385
81.6385
ND
ND
ND
ND
ND
ND
0.24
99.0010
-99.0010
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
17,718.4672 21.15 8,724.4634 8,994.0038 9,237.3812
19,935.9104 23.34 9,627.8476 10,308.0628 10,308.0628
37,654.3775 44.49 18,352.3110 19,302.0665 19,545.4440
-------
Table K-4C. Total SNMOCs3 Collected from Recovery Boiler #5 on Test Day 11/01/01
Compound
CAS No.
Residence
Chamber
Canister
V=3.892L
Ug/m3
Residence
Chamber
Total
Collected
Ug
Dilution
Air
Canister
V=4.291L
Ug/m3
Dilution
Air
Total
Collected
Ug
RC-DAb
Total
Ug
RC-DA
(no negs)c
Total
Ug
ethylene
74-85-1
1.76
736.2982
0.95
388.8460
347.4520
347.4519
acetylene
74-86-2
1.08
451.8194
1.03
421.5910
30.2280
30.2280
ethane
74-84-0
3.35
1401.4768
2.98
1219.7500
181.7270
181.7271
propylene
115-07-1
1.37
573.1412
1.14
466.6160
106.5260
106.5256
propane
74-98-6
5.81
2430.6209
5.19
2124.3300
306.2920
306.2917
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
0.43
179.8910
0.22
90.0486
89.8424
89.8424
isobutene/1 -butene
115-11-7/106-98-0
0.65
271.9283
0.27
110.5140
161.4140
161.4141
to
VO
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.88
368.1491
0.4
163.7250
204.4240
204.4243
/ram-2-butcnc
624-64-6
0.51
213.3591
0.13
53.2106
160.1490
160.1486
c7.v-2-butcne
590-18-1
0.57
238.4602
0.16
65.4899
172.9700
172.9703
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.8
334.6810
0.28
114.6070
220.0740
220.0737
1-pentene
109-67-1
0.41
171.5240
0.1
40.9312
130.5930
130.5928
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
0.57
238.4602
0.17
69.5830
168.8770
168.8772
isoprene
78-79-4
0.38
158.9735
0.12
49.1174
109.8560
109.8560
/ram-2-pentene
646-04-8
ND
ND
0.12
49.1174
-49.1174
ND
c7.v-2-pcntene
627-20-3
0.69
288.6624
0.16
65.4899
223.1720
223.1725
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
0.97
405.8007
0.23
94.1418
311.6590
311.6590
-------
Table K-4C. (continued)
Compound
CAS No.
Residence
Chamber
Canister
V=3.892L
Ug/m3
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
0.61
2,3 -dimethy lbutane
79-29-8
0.91
2-methylpentane
107-83-5
0.35
3-methylpentane
96-14-0
0.92
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
0.97
2-ethyl-l-butene
760-21-4
ND
/7-hexane
110-54-3
0.75
fra«s-2-hexene
4050-45-7
ND
c7\-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
0.63
2,4-dimethylpentane
108-08-7
0.68
benzene
71-43-2
1.22
cyclohexane
110-82-7
0.72
2-methylhexane
591-76-4
0.44
2,3 -dimethy lpentane
565-59-3
1.15
3-methylhexane
589-34-4
0.66
1-heptene
592-76-7
0.61
2,2,4-trimethylpentane
540-84-1
0.52
/7-heptane
142-82-5
0.51
Residence
Chamber
Total
Collected
US
Dilution
Air
Canister
V=4.291L
Ug/m3
Dilution
Air
Total
Collected
US
RC-DAb
Total
Ug
RC-DA
(no negs)c
Total
Hg
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
255.1943
0.13
53.2106
201.9840
201.9837
380.6997
0.24
98.2349
282.4650
282.4648
146.4229
0.26
106.4210
40.0018
40.0018
384.8832
0.21
85.9555
298.9280
298.9277
ND
ND
ND
ND
ND
405.8007
0.24
98.2349
307.5660
307.5659
ND
ND
ND
ND
ND
313.7635
0.4
163.7250
150.0390
150.0387
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
263.5613
0.2
81.8624
181.6990
181.6989
284.4789
0.17
69.5830
214.8960
214.8958
510.3885
0.15
61.3968
448.9920
448.9918
301.2129
0.16
65.4899
235.7230
235.7230
184.0746
0.12
49.1174
134.9570
134.9571
481.1040
0.31
126.8870
354.2170
354.2172
276.1118
0.17
69.5830
206.5290
206.5288
255.1943
ND
ND
255.1940
255.1943
217.5427
0.15
61.3968
156.1460
156.1459
213.3591
0.12
49.1174
164.2420
164.2417
continued
-------
Table K-4C. (continued)
Compound
CAS No.
Residence
Chamber
Canister
V=3.892L
Ug/m3
methylcyclohexane
108-87-2
0.6
2,2,3 -trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.50
toluene
108-88-3
0.78
2-methylheptane
592-27-8
0.42
3-methylheptane
589-81-1
0.45
1-octene
111-66-0
0
/7-octanc
111-65-9
0.52
ethylbenzene
100-41-4
0.37
«7-xylcnc//>xylcnc
108-38-3/106-42-3
0.6
styrene
100-42-5
ND
o-xylene
95-47-6
0.6
1-nonene
124-11-8
ND
«-nonanc
111-84-2
0.37
isopropylbenzene
98-82-8
0.56
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.35
m-cthyltolucnc
620-14-4
0.29
/;-cthyltolucnc
622-96-8
0.44
1,3,5 -trimethylbenzene
108-67-8
0.28
o-ethyltoluene
611-14-3
0.39
beta-pinene
127-91-3
ND
Residence
Chamber
Total
Collected
US
Dilution
Air
Canister
V=4.291L
Ug/m3
Dilution
Air
Total
Collected
US
RC-DAb
Total
Ug
RC-DA
(no negs)c
Total
Hg
251.0108
0.16
65.4899
185.5210
185.5208
ND
ND
ND
ND
ND
209.1756
0.19
77.7693
131.4060
131.4064
326.3140
0.17
69.5830
256.7310
256.7310
175.7075
0.09
36.8381
138.8690
138.8695
188.2581
0.11
45.0243
143.2340
143.2338
0.0000
0
0.0000
0.0000
0.0000
217.5427
0.14
57.3037
160.2390
160.2390
154.7900
0.09
36.8381
117.9520
117.9519
251.0108
0.11
45.0243
205.9860
205.9864
ND
0.1
40.9312
-40.9312
ND
251.0108
0.1
40.9312
210.0800
210.0796
ND
ND
ND
ND
ND
154.7900
0.1
40.9312
113.8590
113.8588
234.2767
0.09
36.8381
197.4390
197.4386
ND
ND
ND
ND
ND
146.4229
ND
ND
146.4230
146.4229
121.3219
0.08
32.7450
88.5769
88.5769
184.0746
0.11
45.0243
139.0500
139.0502
117.1384
0.1
40.9312
76.2072
76.2072
163.1570
0.07
28.6518
134.5050
134.5052
ND
ND
ND
ND
ND
continued
-------
Table K-4C. (concluded)
Compound
CAS No.
Residence
Chamber
Canister
V=3.892L
M
m
1,2,4-trimethylbenzene
1-decene
/7-dccanc
1,2,3 -trimethylbenzene
m-dicthylbcnzcnc
/;-dicthylbcnzcnc
1-undecene
/7-undccanc
^ 1-dodecene
LtJ
I J /7-dodccanc
1-tridecene
/7-tridccanc
95-63-6
872-05-9
124-18-5
526-73-8
141-93-5
105-05-5
821-95-4
1120-21-4
112-41-4
112-40-3
2437-56-1
629-50-5
0.46
ND
0.41
ND
0.41
ND
ND
0.38
ND
ND
ND
ND
Total Speciated 41.06
Total Unspeciated 48.51
Total (speciated + unspeciated)6 89.57
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
Residence
Chamber
Total
Collected
US
Dilution
Air
Canister
V=4.291L
Ug/m3
Dilution
Air
Total
Collected
US
RC-DAb
Total
Hg
RC-DA
(no negs)1
Total
Hg
192.4416
0.12
49.1174
143.3240
143.3241
ND
ND
ND
ND
ND
171.5240
0.2
81.8624
89.6616
89.6616
ND
0.07
28.6518
-28.6518
ND
171.5240
0.1
40.9312
130.5930
130.5928
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
158.9735
0.54
221.0280
-62.0550
0.0000
ND
ND
ND
ND
ND
ND
0.45
184.1900
-184.1900
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
17,177.5031
20,294.2201
37,471.7233
19.97 8,173.9600 9,003.5400 9,368.4890
22.46 9,193.1500 11,101.1000 11,101.0700
42.43 17,367.1000 20,104.6000 20,469.5600
-------
Table K-5A. SNMOC3 Values for 10/30/01 in SPECIATE Format
Compound
CAS No.
RC-DAb
Rg
Uncertainty
Hg
RC-DA
% Total
Uncertainty
% Total
ethylene
74-85-1
375.0408
11.4297
1.6242
0.0495
acetylene
74-86-2
852.0878
10.5505
3.6903
0.0457
ethane
74-84-0
273.5960
9.5736
1.1849
0.0415
propylene
115-07-1
192.0447
6.0568
0.8317
0.0262
propane
74-98-6
287.0737
10.7459
1.2433
0.0465
propyne
74-99-7
NDC
9.7690
ND
isobutane
75-28-5
133.7190
5.4706
0.5791
0.0237
isobutene/1 -butene
115-11-7/106-98-0
112.9393
3.5168
0.4891
0.0152
1,3-butadiene
106-99-0
ND
5.1776
ND
ND
/7-butane
106-97-8
266.8519
9.8667
1.1557
0.0427
fra«s-2-butene
624-64-6
149.9521
6.3499
0.6494
0.0275
c7.v-2-butcne
590-18-1
205.7379
9.4759
0.8910
0.0410
3 -methyl-1 -butene
563-45-1
ND
13.7743
ND
ND
isopentane
78-78-4
253.5048
14.1651
1.0979
0.0613
1-pentene
109-67-1
154.4011
7.9129
0.6687
0.0343
2-methyl-1 -butene
563-46-2
0.0000
7.9129
0.0000
0.0000
/7-pentane
109-66-0
175.9624
9.8667
0.7621
0.0427
isoprene
78-79-4
137.1911
1.1723
0.5942
ND
/ram-2-pentene
646-04-8
ND
8.0106
ND
ND
c/.v-2-pentene
627-20-3
184.6650
11.8205
0.7998
0.0512
2-methyl-2-butene
513-35-9
ND
11.4297
ND
ND
2,2-dimethylbutane
75-83-2
245.0952
14.4581
1.0615
0.0626
cyclopentene
142-29-0
ND
13.6766
ND
ND
4-methyl-1 -pentene
691-37-2
ND
14.0674
ND
ND
cyclopentane
287-92-3
172.0995
6.7406
0.7453
0.0292
2,3 -dimethy lbutane
79-29-8
304.6462
16.7050
1.3194
0.0000
2-methylpentane
107-83-5
520.9958
7.7175
2.2563
0.0334
3-methylpentane
96-14-0
253.2117
14.7512
1.0966
0.0639
2-methyl-1 -pentene
763-29-1
ND
14.7512
ND
ND
1-hexene
592-41-6
334.3240
14.9466
1.4479
0.0647
2-ethyl-l-butene
760-21-4
ND
14.6535
ND
ND
/7-hexane
110-54-3
231.5528
11.3320
1.0028
0.0491
fra«s-2-hexene
4050-45-7
ND
11.3320
ND
ND
c7\-2-hcxcne
7688-21-3
ND
11.3320
ND
ND
methylcyclopentane
96-37-7
201.4842
9.3782
0.8726
0.0406
2,4-dimethylpentane
108-08-7
218.4988
11.7228
0.9463
0.0508
continued
K-33
-------
Table K-5A. (continued)
Compound
CAS No.
RC-DAb
Rg
Uncertainty
Hg
RC-DA
% Total
Uncertainl
% Total
benzene
71-43-2
222.7524
7.4244
0.9647
0.0322
cyclohexane
110-82-7
172.2949
16.6073
0.7462
ND
2-methylhexane
591-76-4
128.8792
1.9538
0.5582
0.0085
2,3 -dimethylpentane
565-59-3
385.6608
9.7690
1.6702
0.0423
3-methylhexane
589-34-4
285.7755
8.2060
1.2376
ND
1-heptene
592-76-7
ND
8.1083
ND
ND
2,2,4-trimethylpentane
540-84-1
278.0498
9.8667
1.2042
0.0427
/7-heptane
142-82-5
167.0643
4.9822
0.7235
0.0216
methylcyclohexane
108-87-2
239.7670
9.4759
1.0384
0.0410
2,2,3 -trimethylpentane
564-02-3
ND
9.8667
ND
ND
2,3,4-trimethylpentane
565-75-3
162.9084
6.8383
0.7055
0.0296
toluene
108-88-3
253.4071
3.9076
1.0975
0.0169
2-methylheptane
592-27-8
132.9375
3.8099
0.5757
ND
3-methylheptane
589-81-1
150.0497
3.7122
0.6498
0.0161
1-octene
111-66-0
ND
3.6145
ND
ND
«-octanc
111-65-9
192.4885
1.9538
0.8336
0.0085
ethylbenzene
100-41-4
128.4885
2.6376
0.5565
ND
«?-xylcnc//>xylcnc
108-38-3/106-42-3
175.9624
4.1030
0.7621
ND
styrene
100-42-5
ND
6.7406
ND
ND
o-xylene
95-47-6
128.7815
2.6376
0.5577
0.0114
1-nonene
124-11-8
ND
2.0515
ND
ND
/7-nonane
111-84-2
103.1620
2.0515
0.4468
0.0089
isopropylbenzene
98-82-8
188.2348
3.9076
0.8152
ND
alpha-pinene
80-56-8
ND
2.0515
ND
ND
/7-propylbenzene
103-65-1
107.2203
1.9538
0.4644
0.0085
m-cthyltolucnc
620-14-4
94.5570
4.4937
0.4095
0.0195
/;-ethyl toluene
622-96-8
188.4302
5.1776
0.8161
0.0224
1,3,5 -trimethylbenzene
108-67-8
111.2785
2.8330
0.4819
0.0123
o-ethyltoluene
611-14-3
136.9958
3.0284
0.5933
0.0131
beta-pinene
127-91-3
129.1723
2.0515
0.5594
ND
1,2,4-trimethylbenzene
95-63-6
129.0746
2.8330
0.5590
0.0123
1-decene
872-05-9
ND
2.1492
ND
ND
/7-decane
124-18-5
120.6650
2.1492
0.5226
ND
1,2,3-trimethylbenzene
526-73-8
ND
2.3446
ND
ND
m-dicthylbcnzcnc
141-93-5
124.0394
1.2700
0.5372
0.0055
/;-diethylbenzene
105-05-5
ND
1.4654
ND
ND
continued
K-34
-------
Table K-5A. (concluded)
Compound
CAS No.
RC-DAb
Rg
Uncertainty
Hg
RC-DA
% Total
Uncertainty
% Total
1-undecene
821-95-4
ND
1.8561
ND
ND
/7-undccanc
1120-21-4
130.4423
1.8561
0.5649
0.0080
1-dodecene
112-41-4
ND
4.1030
ND
ND
/7-dodccanc
112-40-3
ND
4.2007
ND
ND
1-tridecene
2437-56-1
ND
4.1030
ND
ND
/7-tridccanc
629-50-5
ND
4.2007
ND
Total Speciated
11,005.22
Total Unspeciated
12,085.01
Total (speciated + unspeciated)11
23,090.23
a SNMOC = speciated nonmethane organic compound.
b RC = residence chamber; DA = dilution air.
c ND = not detected.
d Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
K-35
-------
Table K-5B. SNMOC3 Values for 10/31/01 in SPECIATE Format
Compound
CAS No.
RC-DAb
Hg
Uncertainty
Hg
RC-DA
% Total
Uncertainty
% Total
ethylene
74-85-1
359.8672
10.6037
1.8412
0.0543
acetylene
74-86-2
82.4981
9.7880
0.4221
0.0501
ethane
74-84-0
143.0387
8.8817
0.7318
0.0454
propylene
115-07-1
137.0299
5.6190
0.7011
0.0287
propane
74-98-6
254.3820
9.9693
1.3015
0.0510
propyne
74-99-7
NDC
9.0630
ND
isobutane
75-28-5
115.9076
5.0753
0.5930
0.0260
isobutene/1 -butene
115-11-7/106-98-0
204.6180
3.2627
1.0469
0.0167
1,3-butadiene
106-99-0
ND
4.8034
ND
/7-butane
106-97-8
235.1246
9.1536
1.2030
0.0468
fra«s-2-butene
624-64-6
144.5110
5.8909
0.7394
0.0301
c7.v-2-butene
590-18-1
178.7802
8.7911
0.9147
0.0450
3 -methyl-1 -butene
563-45-1
ND
12.7788
ND
isopentane
78-78-4
246.6841
13.1413
1.2621
0.0672
1-pentene
109-67-1
127.6483
7.3410
0.6531
0.0376
2-methyl-1 -butene
563-46-2
ND
7.3410
ND
/7-pentane
109-66-0
128.0108
9.1536
0.6549
0.0468
isoprene
78-79-4
98.0480
1.0876
0.5016
0.0056
/ram-2-pentene
646-04-8
ND
7.4316
ND
ND
c7.v-2-pcntene
627-20-3
174.2926
10.9662
0.8917
0.0561
2-methyl-2-butene
513-35-9
ND
10.6037
ND
2,2-dimethylbutane
75-83-2
343.2820
13.4132
1.7563
0.0686
cyclopentene
142-29-0
ND
12.6882
ND
ND
4-methyl-1 -pentene
691-37-2
ND
13.0507
ND
cyclopentane
287-92-3
165.4081
6.2534
0.8463
0.0320
2,3 -dimethy lbutane
79-29-8
284.7157
15.4977
1.4567
0.0793
2-methylpentane
107-83-5
506.9681
7.1597
2.5938
0.0366
3-methylpentane
96-14-0
237.9808
13.6851
1.2176
0.0700
2-methyl-1 -pentene
763-29-1
ND
13.6851
ND
1-hexene
592-41-6
305.6128
13.8663
1.5636
0.0709
2-ethyl-l-butene
760-21-4
ND
13.5945
ND
/7-hexane
110-54-3
182.8146
10.5130
0.9353
0.0538
fra«s-2-hexene
4050-45-7
ND
10.5130
ND
c7.v-2-hcxene
7688-21-3
ND
10.5130
ND
methylcyclopentane
96-37-7
165.5894
8.7004
0.8472
0.0445
2,4-dimethylpentane
108-08-7
187.0302
10.8756
0.9569
0.0556
continued
K-36
-------
Table K-5B. (continued)
Compound
CAS No.
RC-DAb
Uncertainty
RC-DA
% Total
Uncertainty
% Total
benzene
71-43-2
389.2918
6.8879
1.9917
0.0352
cyclohexane
110-82-7
229.3682
15.4070
1.1735
2-methylhexane
591-76-4
123.2514
1.8126
0.6306
0.0093
2,3 -dimethylpentane
565-59-3
330.9975
9.0630
1.6935
0.0464
3-methylhexane
589-34-4
120.2139
7.6129
0.6150
0.0390
1-heptene
592-76-7
172.8425
7.5223
0.8843
2,2,4-trimethylpentane
540-84-1
229.1870
9.1536
1.1726
0.0468
/7-heptane
142-82-5
152.8517
4.6221
0.7820
0.0236
methylcyclohexane
108-87-2
165.7706
8.7911
0.8481
0.0450
2,2,3 -trimethylpentane
564-02-3
ND
9.1536
ND
2,3,4-trimethylpentane
565-75-3
152.7611
6.3441
0.7816
0.0325
toluene
108-88-3
241.1089
3.6252
1.2336
0.0185
2-methylheptane
592-27-8
131.5015
3.5346
0.6728
0.0181
3-methylheptane
589-81-1
148.3642
3.4439
0.7591
0.0176
1-octene
111-66-0
ND
3.3533
ND
/7-octane
111-65-9
123.5233
1.8126
0.6320
0.0093
ethylbenzene
100-41-4
114.5482
2.4470
0.5861
0.0125
m-xylcnc//;-xylcnc
108-38-3/106-42-3
ND
3.8064
ND
ND
styrene
100-42-5
ND
6.2534
ND
ND
o-xylene
95-47-6
156.7049
2.4470
0.8017
0.0125
1-nonene
124-11-8
ND
1.9032
ND
/7-nonane
111-84-2
127.3764
1.9032
0.6517
0.0097
isopropylbenzene
98-82-8
165.7706
3.6252
0.8481
0.0185
alpha-pinene
80-56-8
ND
1.9032
ND
/7-propylbcnzcne
103-65-1
122.9795
1.8126
0.6292
0.0093
m-cthyltolucnc
620-14-4
101.8105
4.1690
0.5209
0.0213
/;-cth\ ltolucnc
622-96-8
215.9055
4.8034
1.1046
0.0246
1,3,5 -trimethylbenzene
108-67-8
80.9134
2.6283
0.4140
0.0134
o-ethyltoluene
611-14-3
139.9328
2.8095
0.7159
0.0144
beta-pinene
127-91-3
ND
1.9032
ND
ND
1,2,4-trimethylbenzene
95-63-6
102.2637
2.6283
0.5232
0.0134
1-decene
872-05-9
ND
1.9939
ND
«-dccanc
124-18-5
106.6606
1.9939
0.5457
0.0102
1,2,3-trimethylbenzene
526-73-8
ND
2.1751
ND
ND
m-dicthylbcnzcnc
141-93-5
ND
1.1782
ND
ND
/?-dicthylbcnzcnc
105-05-5
ND
1.3594
ND
ND
continued
K-37
-------
Table K-5B. (concluded)
Compound
CAS No.
RC-DAb
Uncertainty
RC-DA
% Total
Uncertainty
% Total
1-undecene
821-95-4
ND
1.7220
ND
«-undccanc
1120-21-4
81.6385
1.7220
0.4177
0.0088
1-dodecene
112-41-4
ND
3.8064
ND
ND
«-dodccanc
112-40-3
ND
3.8971
ND
ND
1-tridecene
2437-56-1
ND
3.8064
ND
ND
/7-tridccanc
629-50-5
ND
3.8971
ND
ND
Total Speciated
Total Unspeciated
Total (speciated + unspeciated)d
a SNMOC = speciated nonmethane organic compound.
b RC = residence chamber; DA = dilution air.
c ND = not detected.
d Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
9,237.3810
10,308.0600
19,545.4400
K-38
-------
Table K-5C. SNMOC3 Values for 11/01/01 in SPECIATE Format
Compound CAS No. RC-DAb Uncertainty RC-DA Uncertainty
% Total
% Total
ethylene
74-85-1
347.4519
10.5760
1.6974
0.0517
acetylene
74-86-2
30.2280
9.7624
0.1477
0.0477
ethane
74-84-0
181.7271
8.8585
0.8878
0.0433
propylene
115-07-1
106.5256
5.6044
0.5204
0.0274
propane
74-98-6
306.2917
9.9432
1.4963
0.0486
propyne
74-99-7
NDC
9.0393
ND
ND
isobutane
75-28-5
89.8424
5.0620
0.4389
0.0247
isobutene/1 -butene
115-11-7/106-98-0
161.4141
3.2541
0.7886
0.0159
1,3-butadiene
106-99-0
ND
4.7908
ND
ND
/7-butane
106-97-8
204.4243
9.1297
0.9987
0.0446
fra«s-2-butene
624-64-6
160.1486
5.8755
0.7824
0.0287
c7.v-2-butcne
590-18-1
172.9703
8.7681
0.8450
0.0428
3 -methyl-1 -butene
563-45-1
ND
12.7454
ND
ND
isopentane
78-78-4
220.0737
13.1070
1.0751
0.0640
1-pentene
109-67-1
130.5928
7.3218
0.6380
0.0358
2-methyl-1 -butene
563-46-2
ND
7.3218
ND
ND
/7-pentane
109-66-0
168.8772
9.1297
0.8250
0.0446
isoprene
78-79-4
109.8560
1.0847
0.5367
0.0053
fra«s-2-pentene
646-04-8
ND
7.4122
ND
ND
c7.v-2-pcntene
627-20-3
223.1725
10.9375
1.0903
0.0534
2-methyl-2-butene
513-35-9
ND
10.5760
ND
ND
2,2-dimethylbutane
75-83-2
311.6590
13.3782
1.5225
0.0654
cyclopentene
142-29-0
ND
12.6550
ND
ND
4-methyl-1 -pentene
691-37-2
ND
13.0166
ND
ND
cyclopentane
287-92-3
201.9837
6.2371
0.9868
0.0305
2,3 -dimethy lbutane
79-29-8
282.4648
15.4572
1.3799
0.0755
2-methylpentane
107-83-5
40.0018
7.1410
0.1954
0.0349
3-methylpentane
96-14-0
298.9277
13.6493
1.4604
0.0667
2-methyl-1 -pentene
763-29-1
ND
13.6493
ND
ND
1-hexene
592-41-6
307.5659
13.8301
1.5026
0.0676
2-ethyl-l-butene
760-21-4
ND
13.5589
ND
ND
/7-hexane
110-54-3
150.0387
10.4856
0.7330
0.0512
trans-2-hexene
4050-45-7
ND
10.4856
ND
ND
c7.v-2-hcxene
7688-21-3
ND
10.4856
ND
ND
methylcyclopentane
96-37-7
181.6989
8.6777
0.8877
0.0424
2,4-dimethylpentane
108-08-7
214.8958
10.8472
1.0498
0.0530
continued
K-39
-------
Table K-5C. (continued)
Compound CAS No. RC-DAb Uncertainty RC-DA Uncertainty
Hg
Hg
% Total
% Total
benzene
71-43-2
448.9918
6.8699
2.1935
0.0336
cyclohexane
110-82-7
235.7230
15.3668
1.1516
0.0751
2-methylhexane
591-76-4
134.9571
1.8079
0.6593
0.0088
2,3 -dimethylpentane
565-59-3
354.2172
9.0393
1.7305
0.0442
3-methylhexane
589-34-4
206.5288
7.5930
1.0090
0.0371
1-heptene
592-76-7
255.1943
7.5026
1.2467
0.0367
2,2,4-trimethylpentane
540-84-1
156.1459
9.1297
0.7628
0.0446
/7-heptane
142-82-5
164.2417
4.6100
0.8024
0.0225
methylcyclohexane
108-87-2
185.5208
8.7681
0.9063
0.0428
2,2,3 -trimethylpentane
564-02-3
ND
9.1297
ND
ND
2,3,4-trimethylpentane
565-75-3
131.4064
6.3275
0.6420
0.0309
toluene
108-88-3
256.7310
3.6157
1.2542
0.0177
2-methylheptane
592-27-8
138.8695
3.5253
0.6784
0.0172
3-methylheptane
589-81-1
143.2338
3.4349
0.6997
0.0168
1-octene
111-66-0
ND
3.3445
ND
ND
/7-octane
111-65-9
160.2390
1.8079
0.7828
0.0088
ethylbenzene
100-41-4
117.9519
2.4406
0.5762
0.0119
«?-xylcnc//>xylcne
108-38-3/106-42-3
205.9864
3.7965
1.0063
0.0185
styrene
100-42-5
ND
6.2371
ND
ND
o-xylene
95-47-6
210.0796
2.4406
1.0263
0.0119
1-nonene
124-11-8
ND
1.8983
ND
ND
/7-nonane
111-84-2
113.8588
1.8983
0.5562
0.0093
isopropylbenzene
98-82-8
197.4386
3.6157
0.9645
0.0177
alpha-pinene
80-56-8
ND
1.8983
ND
ND
/7-propylbcnzcne
103-65-1
146.4229
1.8079
0.7153
0.0088
m-cthyltolucnc
620-14-4
88.5769
4.1581
0.4327
0.0203
/;-cthyltolucnc
622-96-8
139.0502
4.7908
0.6793
0.0234
1,3,5 -trimethylbenzene
108-67-8
76.2072
2.6214
0.3723
0.0128
o-ethyltoluene
611-14-3
134.5052
2.8022
0.6571
0.0137
beta-pinene
127-91-3
ND
1.8983
ND
ND
1,2,4-trimethylbenzene
95-63-6
143.3241
2.6214
0.7002
0.0128
1-decene
872-05-9
ND
1.9886
ND
ND
/7-dccanc
124-18-5
89.6616
1.9886
0.4380
0.0097
1,2,3-trimethylbenzene
526-73-8
ND
2.1694
ND
ND
OT-dicthylbenzcne
141-93-5
130.5928
1.1751
0.6380
0.0057
/;-diethylbenzene
105-05-5
ND
1.3559
ND
ND
continued
K-40
-------
Table K-5C. (concluded)
Compound
CAS No.
RC-DAb
Uncertainty
RC-DA
Uncertainty
Hg
Hg
% Total
% Total
1-undecene
821-95-4
ND
1.7175
ND
ND
/7-undccanc
1120-21-4
ND
1.7175
ND
ND
1-dodecene
112-41-4
ND
3.7965
ND
ND
/7-dodccanc
112-40-3
ND
3.8869
ND
ND
1-tridecene
2437-56-1
ND
3.7965
ND
ND
/7-tridccanc
629-50-5
ND
3.8869
ND
ND
Total Speciated
9,368.4890
Total Unspeciated
11,101.0700
Total (speciated + unspeciated)*
20,469.5600
a SNMOC = speciated nonmethane organic compound.
b RC = residence chamber; DA = dilution air.
c ND = not detected.
d Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
K-41
-------
Table K-6A. Calculation of Mass of SNMOCs Collected on 10/30/01
Calculation of Mass of Speciated NMOC Collected
Volume Canister = flow rate into canister x test duration
Test Duration 482.42 min
Flow Rate, Dilution Air Canister 0.0081 L/min 3.9201 L
Flow Rate, Residence Chamber Air Canister 0.0081 L/min 3.9201 L
Mass Total SNMOC Collected = [SNMOC Cone. Res. Ch. - SNMOC Cone. Dil. Air]/Volume Canister
SNMOCRC = 44.82 |lg/m3 = 44.82 ng/L = 0.044482 |ig/L 0.1744 jig
SNMOC DA = 20.87 |ig/m3 = 20.87 ng/L = 0.02087 |ig/L 0.0818 jig
Mass Total SNMOC Collected 0.0926 |ig
Calculation of Mass of Total (Speciated + Unspeciated) NMOC Collected
Volume Canister = flow rate into canister x test duration
Test Duration 482.42 min
Flow Rate, dilution Air Canister 0.0081 L/min 3.9201 L
Flow Rate, Residence Chamber Air Canister 0.0081 L/min 3.9201 L
Mass Total NMOC Collected = [NMOC Cone. Res. Ch. - NMOC Cone. Dil. Air]xVolume Canister
NMOC RC = 95.82 |ig/m3 = 95.82 ng/L = 0.09582 |ig/L 0.3756 jig
NMOC DA = 43.997 |ig/m3 = 43.99 ng/L = 0.04399 |ig/L 0.1724 jig
Mass Total NMOC (Speciated + Unspeciated) Collected 0.2032 |ig
K-42
-------
Table K-6B. Calculation of Mass of SNMOCs Collected on 10/31/01
Calculation of Mass of Speciated NMOC Collected
Volume Canister = flow rate into canister x test duration
Test Duration 480.03 min
Flow Rate, Dilution Air Canister 0.0090 I ./min 4.3001 L
Flow Rate, Residence Chamber Air Canister 0.0081 I ./min 3.8998 L
Mass Total SNMOC Collected = [SNMOC Cone. Res. Ch. - SNMOC Cone. Dil. Air] /Volume Canister
SNMOC RC = 42.03 |lg/m3 = 42.03 ng/L = 0.04203 |ig/L 0.1639
SNMOC DA = 21.15 |lg/m3 = 21.15 ng/L = 0.02115 |ig/L 0.0909 jig
Mass Total SNMOC Collected 0.0730 |ig
Calculation of Mass of Total (Speciated + Unspeciated) NMOC Collected
Volume Canister = flow rate into canister x test duration
Test Duration 480.03 min
Flow Rate, dilution Air Canister 0.0090 I ./min 4.3001 L
Flow Rate, Residence Chamber Air Canister 0.0081 I ./min 3.8998 L
Mass Total NMOC Collected = [NMOC Cone. Res. Ch. - NMOC Cone. Dil. Air]xVolume Canister
NMOC RC = 89.32 yig/m3 = 89.32 ng/L = 0.08932 ^ig/L 0.3483 ^ig
NMOC DA = 44.49 |ig/m3 = 44.49 ng/L = 0.04449 |ig/L 0.1913 jig
Mass Total NMOC (Speciated + Unspeciated) Collected 0.1570 |ig
K-43
-------
Table K-6C. Calculation of Mass of SNMOCs Collected (11/01/01)
Calculation of Mass of Speciated NMOC Collected
Volume Canister = flow rate into canister x test duration
Test Duration 479.03 min
Flow Rate, Dilution Air Canister 0.0090 I ./min 4.2912 L
Flow Rate, Residence Chamber Air Canister 0.0081 I ./min 3.8921 L
Mass Total SNMOC Collected = [SNMOC Cone. Res. Ch. - SNMOC Cone. Dil. Air]/Volume Canister
SNMOC RC = 41.06 |lg/m3 = 41.06 ng/L = 0.04106 |ig/L 0.1598
SNMOC DA = 19.97 |ig/m3 = 19.97 ng/L = 0.01997 |ig/L 0.0857 jig
Mass Total SNMOC Collected 0.0741
Calculation of Mass of (Speciated + Unspeciated) NMOC Collected
Volume Canister = flow rate into canister x test duration
Test Duration 482.42 min
Flow Rate, dilution Air Canister 0.0081 I ./min 3.9201 L
Flow Rate, Residence Chamber Air Canister 0.0081 I ./min 3.9201 L
Mass Total NMOC Collected = [NMOC Cone. Res. Ch. - NMOC Cone. Dil. Air]xVolume Canister
NMOC RC = 44.82 |ig/m3 = 44.82 ng/L = 0.044482 |ig/L 0.1744 jig
NMOC DA = 20.87 |ig/m3 = 20.87 ng/L = 0.02087 |ig/L 0.0818 jig
Mass Total NMOC (Speciated + Unspeciated) Collected 0.0926 |ig
K-44
-------
Table K-7. Summary of SNMOCs3 from Recovery Boiler #5 for All Test Days as Weight Percent of Total
Compound
CAS No.
10/30/01
RC-DAb
Percent
Total
10/31/01
RC-DA
Percent
Total
11/01/01
RC-DA
Percent
Total
ethylene
74-85-1
375.0408
1.6242
359.8672
1.8412
347.4519
1.6974
acetylene
74-86-2
852.0878
3.6903
82.4981
0.4221
30.2280
0.1477
ethane
74-84-0
273.5960
1.1849
143.0387
0.7318
181.7271
0.8878
propylene
115-07-1
192.0447
0.8317
137.0299
0.7011
106.5256
0.5204
propane
74-98-6
287.0737
1.2433
254.3820
1.3015
306.2917
1.4963
propyne
74-99-7
NDC
ND
ND
ND
ND
ND
isobutane
75-28-5
133.7190
0.5791
115.9076
0.5930
89.8424
0.4389
isobutene/1 -butene
115-11-7/106-98-0
112.9393
0.4891
204.6180
1.0469
161.4141
0.7886
7^ 1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
«-butane
106-97-8
266.8519
1.1557
235.1246
1.2030
204.4243
0.9987
/ram-2-butcnc
624-64-6
149.9521
0.6494
144.5110
0.7394
160.1486
0.7824
c7.v-2-butcne
590-18-1
205.7379
0.8910
178.7802
0.9147
172.9703
0.8450
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
253.5048
1.0979
246.6841
1.2621
220.0737
1.0751
1-pentene
109-67-1
154.4011
0.6687
127.6483
0.6531
130.5928
0.6380
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
175.9624
0.7621
128.0108
0.6549
168.8772
0.8250
isoprene
78-79-4
137.1911
0.5942
98.0480
0.5016
109.8560
0.5367
/ram-2-pentene
646-04-8
ND
ND
ND
ND
ND
ND
c7.v-2-pcntene
627-20-3
184.6650
0.7998
174.2926
0.8917
223.1725
1.0903
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
245.0952
1.0615
343.2820
1.7563
311.6590
1.5225
continued
-------
Table K-7. (continued)
Compound
CAS No.
10/30/01
RC-DAb
Hg
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
172.0995
2,3 -dimethy lbutane
79-29-8
304.6462
2-methylpentane
107-83-5
520.9958
3-methylpentane
96-14-0
253.2117
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
334.3240
2-ethyl-l-butene
760-21-4
ND
/7-hexane
110-54-3
231.5528
fra«s-2-hexene
4050-45-7
ND
c7.v-2-hcxene
7688-21-3
ND
methylcyclopentane
96-37-7
201.4842
2,4-dimethylpentane
108-08-7
218.4988
benzene
71-43-2
222.7524
cyclohexane
110-82-7
172.2949
2-methylhexane
591-76-4
128.8792
2,3 -dimethy lpentane
565-59-3
385.6608
3-methylhexane
589-34-4
285.7755
1-heptene
592-76-7
ND
2,2,4-trimethylpentane
540-84-1
278.0498
/7-heptane
142-82-5
167.0643
methylcyclohexane
108-87-2
239.7670
Percent
Total
10/31/01
RC-DA
Hg
Percent
Total
11/01/01
RC-DA
Hg
Percent
Total
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.7453
165.4081
0.8463
201.9837
0.9868
1.3194
284.7157
1.4567
282.4648
1.3799
2.2563
506.9681
2.5938
40.0018
0.1954
1.0966
237.9808
1.2176
298.9277
1.4604
ND
ND
ND
ND
ND
1.4479
305.6128
1.5636
307.5659
1.5026
ND
ND
ND
ND
ND
1.0028
182.8146
0.9353
150.0387
0.7330
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.8726
165.5894
0.8472
181.6989
0.8877
0.9463
187.0302
0.9569
214.8958
1.0498
0.9647
389.2918
1.9917
448.9918
2.1935
0.7462
229.3682
1.1735
235.7230
1.1516
0.5582
123.2514
0.6306
134.9571
0.6593
1.6702
330.9975
1.6935
354.2172
1.7305
1.2376
120.2139
0.6150
206.5288
1.0090
ND
172.8425
0.8843
255.1943
1.2467
1.2042
229.1870
1.1726
156.1459
0.7628
0.7235
152.8517
0.7820
164.2417
0.8024
1.0384
165.7706
0.8481
185.5208
0.9063
continued
-------
Table K-7. (continued)
10/30/01
Compound CAS No. RC-DAb
Hg
2,2,3 -trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
162.9084
toluene
108-88-3
253.4071
2-methylheptane
592-27-8
132.9375
3-methylheptane
589-81-1
150.0497
1-octene
111-66-0
ND
/7-octanc
111-65-9
192.4885
ethylbenzene
100-41-4
128.4885
«?-xylcnc//;-xylcnc
108-38-3/106-42-3
175.9624
styrene
100-42-5
ND
o-xylene
95-47-6
128.7815
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
103.1620
isopropylbenzene
98-82-8
188.2348
alpha-pinene
80-56-8
ND
«-propylbcnzcnc
103-65-1
107.2203
OT-cthyltolucnc
620-14-4
94.5570
/;-cthyl toluene
622-96-8
188.4302
1,3,5 -trimethylbenzene
108-67-8
111.2785
o-ethyltoluene
611-14-3
136.9958
beta-pinene
127-91-3
129.1723
1,2,4-trimethylbenzene
95-63-6
129.0746
1-decene
872-05-9
ND
Percent
Total
10/31/01
RC-DA
Hg
Percent
Total
11/01/01
RC-DA
Hg
Percent
Total
ND
ND
ND
ND
ND
0.7055
152.7611
0.7816
131.4064
0.6420
1.0975
241.1089
1.2336
256.7310
1.2542
0.5757
131.5015
0.6728
138.8695
0.6784
0.6498
148.3642
0.7591
143.2338
0.6997
ND
ND
ND
ND
ND
0.8336
123.5233
0.6320
160.2390
0.7828
0.5565
114.5482
0.5861
117.9519
0.5762
0.7621
ND
ND
205.9864
1.0063
ND
ND
ND
ND
ND
0.5577
156.7049
0.8017
210.0796
1.0263
ND
ND
ND
ND
ND
0.4468
127.3764
0.6517
113.8588
0.5562
0.8152
165.7706
0.8481
197.4386
0.9645
ND
ND
ND
ND
ND
0.4644
122.9795
0.6292
146.4229
0.7153
0.4095
101.8105
0.5209
88.5769
0.4327
0.8161
215.9055
1.1046
139.0502
0.6793
0.4819
80.9134
0.4140
76.2072
0.3723
0.5933
139.9328
0.7159
134.5052
0.6571
0.5594
ND
ND
ND
ND
0.5590
102.2637
0.5232
143.3241
0.7002
ND
ND
ND
ND
ND
continued
-------
Table K-7. (concluded)
10/30/01
Compound CAS No. RC-DAb
Hg
«-decane 124-18-5 120.6650
1,2,3-trimethylbenzene 526-73-8 ND
ra-diethylbenzene 141-93-5 124.0394
/;-dicthylbcnzcnc 105-05-5 ND
1-undecene 821-95-4 ND
«-undecane 1120-21-4 130.4423
1-dodecene 112-41-4 ND
«-dodecane 112-40-3 ND
1-tridecene 2437-56-1 ND
/7-tridccanc 629-50-5 ND
Total Speciated
Total Unspeciated
Total (Speciated + Unspeciated)d
a SNMOC = speciated nonmethane organic compound.
b RC = residence chamber; DA = dilution air.
c ND = not detected.
d Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
11005.22
12085.01
23090.23
Percent
Total
10/31/01
RC-DA
Hg
Percent
Total
11/01/01
RC-DA
Hg
Percent
Total
0.5226
106.6606
0.5457
89.6616
0.4380
ND
ND
ND
ND
ND
0.5372
ND
ND
130.5928
0.6380
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.5649
81.6385
0.4177
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
9237.381
10308.06
19545.44
9368.489
11101.07
20469.56
-------
Appendix L
Data Tables for Individual PM25 EC/OC Samples
L-l
-------
Table L-1. Recovery Boiler, Organic/Elemental Carbon Samples—NIOSH Method
5040 (Thermal-Optical Transmittance)
OC/EC Data (wt.% of PM mass) by Sample
Filter ID
oc
EC
Q051601N IB103001HR4A1
-3.0
0.5
Q052301C IB103001HR4B1
-3.0
0.4
Q052301J IB103001HR8A1
-2.9
0.4
Q052301V IB 103001HR8B1
-3.0
0.6
Q052401X IB 103001HR10A3
-3.2
0.5
Q052301E IB 103001HR10B3
-4.1
0.2
Q052501X IB103101HR4A1
-0.2
0.0
Q052901A IB103101HR4B1
-0.3
0.0
Q052501V IB103101HR8A1
-0.4
0.0
Q052501T IB103101HR8B1
-0.2
0.1
Q052501 IB103101HR10A3
-0.4
0.1
Q052501J IB103101HR10B3
-0.4
0.0
Q052901G IB110101HR4A1
-0.2
0.1
Q052901H IB 110101HR4B1
-0.2
0.0
Q052901F IB110101HR8A1
-0.1
0.0
Q052901E IB110101HR8B1
-0.3
0.0
Q052901C IB110101HR10A3
-0.3
0.3
Q052901D IB110101HR10B3
-0.3
0.2
L-2
-------
Appendix M
Data Tables for Individual PM25 Elemental Samples
M-l
-------
Contents
Table Page
M-l Recovery Boiler, PM25 Elemental Analysis, XRF Elemental Analysis Results
from Sample IB103001HR2A1 M-3
M-2 Recovery Boiler, PM2 5 Elemental Analysis, XRF Elemental Analysis Results
from Sample IB103001HR2B1 M-3
M-3 Recovery Boiler, PM2 5 Elemental Analysis, XRF Elemental Analysis Results
from Sample IB 103101HR2A1 M-4
M-4 Recovery Boiler, PM2 5 Elemental Analysis, XRF Elemental Analysis Results
from Sample IB 103101HR2B1 M-4
M-5 Recovery Boiler, PM2 5 Elemental Analysis, XRF Elemental Analysis Results
from Sample IB 110101HR2A1 M-5
M-6 Recovery Boiler, PM2 5 Elemental Analysis, XRF Elemental Analysis Results
from Sample IB 110101HR2B1 M-5
M-2
-------
Table M-1. Recovery Boiler, PM25 Elemental Analysis, XRF Elemental Analysis
Results from Sample IB103001HR2A1
IB103001HR2A1
EDXRF WDXRF WD2 % diff % diff % diff
XRF 229004 T100201B ED/WD ED/WD2 WD/WD2
Na
27.42
28.36
28.2
-3.4
-2.8
Mg
0.025
0.0236
Si
S
16.93
15.2
15.06
10.2
11.0
CI
1.94
2.05
2.08
-5.5
-7.0
K
2.56
2.79
2.7
-8.9
-5.4
Ca
Ti
Br
Rb 0.02
Table M-2. Recovery Boiler, PM25 Elemental Analysis, XRF Elemental Analysis
Results from Sample IB103001HR2B1
IB103001HR2B1
XRFID EDXRF WDXRF % diff
229005 T100201C ED/WD
Na
28.78
30.67
-6.6
Mg
0.0262
Si
S
17.12
15.92
7.0
CI
1.93
2.09
-8.4
K
2.56
2.79
-9.0
Ca
Ti
Br
Rb
M-3
-------
Table M-3. Recovery Boiler, PM25 Elemental Analysis, XRF Elemental Analysis
Results from Sample IB103101HR2A1
IB103101HR2A1
EDXRF WDXRF
XRF 229007 T100201J
WD2
% diff
ED/WD
% diff
ED/WD2
% diff
WD/WD2
Na
28.52
30
29.48
-5.2
-3.4
1.7
Mg
0.0248
0.0307
-23.8
Si
S
19.07
17.45
17.38
8.5
8.9
0.4
CI
1.84
2.07
1.98
-12.6
-7.7
4.3
K
2.44
2.59
2.64
-6.0
-8.1
-1.9
Ca
Ti
Br
Rb
Table M-4. Recovery Boiler, PM25 Elemental Analysis, XRF Elemental Analysis
Results from Sample IB103101HR2B1
IB103101HR2B1
EDXRF WDXRF
XRF 229008 T100201I
WD2
% diff
ED/WD
% diff
ED/WD2
% diff
WD/WD2
Na
28.16
29.2
28.37
-3.7
-0.8
2.8
Mg
0.0266
0.0296
-11.3
Si
S
19.01
17.45
16.61
8.2
12.6
4.8
CI
1.84
2.07
2.16
-12.4
-17.3
-4.3
K
2.44
2.59
2.58
-4.6
-4.2
-0.4
Ca
Ti
Br
Rb
M-4
-------
Table M-5. Recovery Boiler, PM25 Elemental Analysis, XRF Elemental Analysis
Results from Sample IB110101HR2A1
IB110101HR2A1
EDXRF WDXRF WD2 % diff % diff % diff
XRF 229010 T100201Q ED/WD ED/WD2 WD/WD2
Na 28.39 29.79 30.15 -4.9 -6.2 -1.2
Mg 0.0232 0.0285 -22.8
Si
S 19.85 17.83 17.48 10.2 11.9 2.0
CI 1.90 2.08 2.09 -9.6 -10.1 -0.5
K 2.61 2.85 2.74 -9.3 -5.1 3.9
Ca 0.02
Ti
Br 0.02
Rb 0.02
Table M-6. Recovery Boiler, PM25 Elemental Analysis, XRF Elemental Analysis
Results from Sample IB110101HR2B1
IB110101HR2B1
EDXRF WDXRF WD2 % diff % diff % diff
XRF 229011 T100201N ED/WD ED/WD2 WD/WD2
Na
28.45
29.5
29.94
-3.7
-5.2
-1.5
Mg
0.0202
0.0358
-77.2
Si
S
19.37
17.32
17.44
10.6
10.0
-0.7
CI
1.94
2.25
2.14
-15.9
-10.2
4.9
K
2.52
2.79
2.63
-10.9
-4.5
5.7
Ca
Ti
0.02
Br
0.02
Rb
M-5
-------
Appendix N
Data Tables for Individual PM25
Inorganic Ion Samples
N-l
-------
Table N-1. Recovery Boiler, Calibration Ranges for PM25 Inorganic Ion Analyses
Inorganic Ions by Ion Chromatography
Ion High Concentration Low Concentration
ppm ppm
chloride 1.3 0.6
nitrate 1.3 0.6
sulfate 1.3 0.6
ammonium 2.9 0.6
potassium 3.1 0.6
magnesium 3.1 0.7
calcium 2.9 0.6
Table N-2. Recovery Boiler, Inorganic Ion Samples, Ion Chromatography Results (wt% of PM mass) by
Sample
Filter ID
Ion T100201D T100201E T100201H T100201G T100201M T100201L
IB103001HR6A1 IB103001HR6B1 IB103101HR6A1 IB103101HR6B1 IB110101HR6A1 IB110101HR6B1
nh4
NDa
ND
ND
ND
ND
ND
K
2.40
2.38
2.68
2.70
2.57
2.55
Mg
ND
ND
ND
ND
ND
ND
Ca
ND
ND
ND
ND
ND
ND
CI
2.01
1.91
2.17
1.85
1.93
1.93
no3
NQb
NQ
NQ
NQ
NQ
NQ
so4
44.95
45.62
50.49
50.62
50.81
50.44
S203
ND
ND
ND
ND
ND
ND
a ND = not detected.
b NQ = not quantified.
N-2
-------
Appendix O
Calibration Data Tables for Individual
Semivolatile Organic Compounds
0-1
-------
Contents
Table Page
0-1 Calibration Ranges for Speciated PM Organic Compounds, Standard Suite #1 ... 0-3
0-2 Calibration Ranges for Speciated PM Organic Compounds, Standard Suite #2 . . . 0-5
0-3 Calibration Ranges for Speciated PM Organic Compounds, Standard Suite #3 ... 0-7
0-4 Emission Factors (mg/kg fuel) for //-Alkanes from Recovery Boiler #5
as obtained from PUF Samples (WRP1) 0-9
0-5 Emission Factors (mg/kg fuel) for PAHs from Recovery Boiler #5 as
obtained from PUF Samples (WRP2) 0-11
0-6 Emission Factors (mg/kg fuel) for //-Alkanoic Acids from Recovery
Boiler #5 as obtained from PUF Samples (WRP3) 0-12
0-7 Emission Factors (mg/kg fuel) for //-Alkanes from Recovery Boiler #5
as obtained from Quartz Filter Samples (WRQ1) 0-13
0-8 Emission Factors (mg/kg fuel) for PAHs from Recovery Boiler #5 as
obtained from Quartz Filter Samples (WRQ2) 0-14
0-9 Emission Factors (mg/kg fuel) for //-Alkanoic Acids from Recovery
Boiler #5 as obtained from Quartz Filter Samples (WRQ3) 0-14
0-2
-------
Table 0-1. Calibration Ranges for PM Speciated Organic Compounds, Standard
Suite #1
High Calibration
Low Calibration
Compound
Concentration
Concentration
|Ig/mL
jlg/mL
dimethyl phthalate
19
0.8
diethyl phthalate
19
0.8
naphthalene
10
0.8
2-methylnaphthalene
21.28
0.968
1 -methylnaphthalene
21.28
0.896
2,7-dimethylnaphthalene
18.24
0.768
1,3 -dimethylnaphthalene
18.24
0.768
2,6-dimethylnaphthalene
18.24
0.768
acenaphthylene
38
1.6
acenaphthene
19
0.8
fluorene
3.8
0.16
1 -methylfluorene
9.5
0.4
phenanthrene
1.9
0.08
anthracene
1.9
0.08
9-methylanthracene
18.62
0.784
octylcyclohexane
9.5
0.4
norpristane
9.5
0.4
decylcyclohexane
9.5
0.4
pristane
9.5
0.4
phytane
9.5
0.4
tridecylcyclohexane
9.5
0.4
dibutyl phthalate
19
0.8
butylbenzyl phthalate
19
0.8
bis(2-ethylhexyl) phthalate
19
0.8
dioctyl phthalate
19
0.8
fluoranthene
3.8
0.16
pyrene
1.9
0.08
chrysene
1.9
0.08
benzo [a] anthracene
1.9
0.08
benzo [k]fluoranthene
1.9
0.08
benzo [b]fluoranthene
3.8
0.16
benzo [a]pyrene
1.9
0.08
nonadecylcyclohexane
9.5
0.4
squalane
19.855
0.836
indeno [1,2,3 -cd]py rene
1.9
0.08
continued
0-3
-------
Table 0-1. (concluded)
High Calibration
Low Calibration
Compound
Concentration
Concentration
p,g/mL
p,g/mL
dibenzo [a,h] anthracene
3.8
0.16
benzo [ghi]perylene
3.8
0.16
coronene
2.375
0.1
cholestane 1
0.95
0.04
cholestane 2
0.95
0.04
cholestane 3
0.95
0.04
cholestane 4
0.95
0.04
ABB-20R-24S-methylcholestane
0.95
0.04
ABB-20R-ethylcholestane
0.95
0.04
17A(H)-22,29,30-trisnorhopane
0.95
0.04
17B(H)-21 A(H)-norhopane
0.95
0.04
17B(H)-21B(H)-hopane
0.95
0.04
17B(H)-21A(H)-hopane
0.95
0.04
17A(H)-21B(H)-hopane
0.95
0.04
0-4
-------
Table 0-2. Calibration Ranges for PM Speciated Organic Compounds, Standard
Suite #2
High Calibration
Low Calibration
Compound
Concentration
Concentration
jlg/mL
|Ig/mL
«-decane (n-CIO)
8.2
0.41
«-undccanc (n-Cll)
8.2
0.41
/7-dodccanc (n-C12)
8.2
0.41
/7-tridccanc (n-C13)
8.2
0.41
9h-fluoren-9-one
8.68
0.434
/7-tctradccanc (n-C14)
8.2
0.41
/7-pcntadccanc (n-C15)
8.2
0.41
«-hcxadccanc (n-16)
8.2
0.41
/7-hcptadccanc (n-C17)
8.2
0.41
1-octadecene
15.32
0.766
/7-octadccanc (n-C18)
8.2
0.41
2-methylnonadecane (iso-C20)
1.96
0.098
3 -methylnonadecane (anteiso-C20)
1.96
0.098
«-nonadccanc (n-C19)
8.2
0.41
«-eicosane (n-C20)
8.2
0.41
«-hcncicosanc (n-C21)
8.2
0.41
«-docosane (n-C22)
8.2
0.41
/7-tricosanc (n-C23)
8.2
0.41
z'so-docosane (C23)
8.2
0.41
aw/e/.vo-docosanc (C23)
8.2
0.41
pyrene
0.4
0.02
anthraquinone
4.72
0.236
naphthalic anhydride
8.16
0.408
methylfluoranthene
0.4
0.02
retene
1.96
0.098
acepyrene (cyclopenta[c,d]pyrene)
1.96
0.098
benzanthraquinone
8.28
0.414
1 -methylchry sene
0.4
0.02
benzo[a]pyrene
3.92
0.196
«-tctracosanc (n-C24)
8.2
0.41
z'so-tricosane (C24)
8.2
0.41
a/7/t'/.vo-tricosanc (C24)
8.2
0.41
/7-pcntacosanc (n-C25)
8.2
0.41
/.vo-tctracosanc (C25)
8.2
0.41
fl/7/t'/.vo-tctracosanc (C25)
8.2
0.41
continued
0-5
-------
Table 0-2. (concluded)
High Calibration
Low Calibration
Compound
Concentration
Concentration
(Ig/mL
Hg/mL
/7-hcxacosanc (n-C26)
8.2
0.41
/w-pcntacosanc (C26)
8.2
0.41
a«/t'/.vo-pcntacosanc (C26)
8.2
0.41
heptacosane (n-C27)
8.2
0.41
/.vo-hcxacosanc (C27)
8.2
0.41
an te is a-h c xaco san c (C27)
8.2
0.41
/.vo-hcptacosanc (C28)
8.2
0.41
an te is a-he p taco san c (C28)
8.2
0.41
/.vo-octacosanc (C29)
8.2
0.41
anteiso-octacosane (C29)
8.2
0.41
octacosane (n-C28)
8.2
0.41
nonacosane (n-C29)
8.2
0.41
/.vo-nonacosanc (C30)
8.2
0.41
an/6'/.s'o-nonacosane (C30)
8.2
0.41
squalene
16.56
0.828
dibenzo [a,e]pyrene
0.4
0.02
hexatriacontane-d74
10.15
10.15
/7-triacontanc (n-C30)
17.2
0.86
/7-hcntriacontanc (n-C31)
17.2
0.86
/w-triacontanc (C31)
17.2
0.86
anteiso-triacontane (C31)
17.2
0.86
/w-hcntriacontanc (C32)
8.2
0.41
an te is a-h c n t ri aco n tan c (C32)
8.2
0.41
/w-dotriacontanc (C33)
8.2
0.41
an te is a-do t ri aco n tan c (C33)
8.2
0.41
dotriacontane (n-C32)
8.2
0.41
tritriacontane (n-C33)
8.2
0.41
tetratriacontane (n-C34)
8.2
0.41
/.vo-tritriacontanc (C34)
8.2
0.41
an te/.vo-tritri aco n tan c (C34)
8.2
0.41
pentatriacontane (n-C35)
8.2
0.41
hexatriacontane (n-C36)
8.2
0.41
tetracontane («-C40)
8.2
0.41
0-6
-------
Table 0-3. Calibration Ranges for Speciated PM Organic Compounds, Standard
Suite #3
Compound
High Calibration
Hg/mL
Low Calibration
(Ig/mL
Caproic or Hexanoic acid, methyl ester
18.68
0.75
Succinic or butanedioic acid, methyl ester
6.13
0.25
Caprylic or Octanoic acid, methyl ester
18.53
0.74
Glutaric or Pentanedioic acid, dimethyl ester
7.25
0.29
Nonanoic acid, methyl ester
14.66
0.59
Adipic or Hexanedioic acid, dimethyl ester
6.27
0.25
Capric or Decanoic acid, methyl ester
14.66
0.59
Undecanoic acid, methyl ester
14.66
0.59
Pimelic or Heptanedioic acid, dimethyl ester
6.32
0.25
Suberic or Octanedioic acid, dimethyl ester
6.32
0.25
Dodecanoic acid, methyl ester
17.16
0.69
Azelaic or Nonanedioic acid, dimethyl ester
5.64
0.23
Tridecanoic acid, methyl ester
17.16
0.69
Pinonic Acid (methyl ester)
22.11
0.88
Dimethyl phthalate
6.18
0.25
1,4-Benzenedicarboxylic acid, methyl ester
6.08
0.24
1,3-Benzenedicarboxylic acid, methyl ester
6.42
0.26
1,2-Benzenedicarboxylic acid, 4-methyl,
6.27
0.25
1,2,4-Benzenetricarboxylic acid, trimethyl ester
6.03
0.24
Benzenetetracarboxylic acid, methyl ester
5.93
0.24
Abietic acid, methyl ester
17.16
0.71
Pimaric acid, methyl ester (secondary)
17.16
0.71
sandaracopimaric acid, methyl ester (secondary std)
17.16
0.69
Isopimaric acid, methyl ester (secondary std)
17.16
0.71
6,18,1 l,13-Abetatetraen-18-oic acid, methyl ester
17.16
0.71
Dehydroabietic acid, methyl ester (secondary std)
17.16
0.71
Sebacic or Decanedioic Acid, dimethyl ester
5.74
0.23
Tetradecanoic acid, methyl ester
15.05
0.6
Pentadecanoic acid, methyl ester
15.05
0.6
Palmitoleic or 9-Hexadecenoic acid, methyl ester
15.74
0.63
Hexadecanoic acid, methyl ester
14.71
0.59
Heptadecanoic acid, methyl ester
14.71
0.59
Linoleic or 8,11-Octadecadienoic acid, methyl ester
14.07
0.56
Oleic or 9-Octadecenoic acid, methyl ester
16.52
0.66
Linolenic 9,12,15-Octadecatrienoic acid, methyl ester
17.6
0.7
Octadecanoic acid, methyl ester
11.67
0.47
continued
0-7
-------
Table 0-3. (concluded)
Compound
High Calibration
[Ig/mL
Low Calibration
jlg/mL
Nonadecanoic acid, methyl ester
11.67
0.47
Eicosanoic acid, methyl ester
12.06
0.48
Heneicosanoic acid, methyl ester
12.06
0.48
Docosanoic acid, methyl ester
12.21
0.49
Tricosanoic acid, methyl ester
12.21
0.49
Tetracosanoic acid, methyl ester
13.73
0.55
Pentacosanoic acid, methyl ester
13.73
0.55
Hexacosanoic acid, methyl ester
13.73
0.55
Heptacosanoic Acid, methyl ester
14.85
0.59
Octacosanoic acid, methyl ester
14.85
0.59
Nonacosanoic acid, methyl ester
14.85
0.59
Triacontanoic acid, methyl ester
14.85
0.58
0-8
-------
Table 0-4. Emission Factors (mg/kg fuel) for n-Alkanes from Recovery Boiler #5 as obtained from PUF Samples (WRP#1)
«-Alkanes
Ports R4 & R8
Port R10
10/30/01
10/31/01
11/01/01
Average
S.D.a
RSDb
10/30/01
10/31/01
11/01/01
Average
S.D.
RSD
«-C10
NDC
ND
ND
ND
ND
—
ND
ND
ND
ND
ND
—
n-Cll
5.6 xlO"5
4x 10~6
-9x 10~5
-0.0000
7.4 xlO"5
-740
0.0002
lxlO"5
ND
5x 10~5
lxlO"5
198.8738
n-C12
0.0008
-3x 10~5
0.0015
0.0007
0.0008
101.259
0.0010
ND
0.002
0.001
7x 10~5
74.53288
n-C13
1.7 xlO"5
-4x 10~5
0.0002
4.9x 10~5
0.0001
221.624
4.1xl0"6
ND
lxlO"4
3x 10~5
7x 10~5
195.4223
n-CU
4.7xl0"5
7x 10~7
0.0001
5.3 xlO"5
5.5 xlO"5
104.367
9.1xl0"6
lxlO"7
lxlO"4
4x 10~5
6x 10~5
176.5824
n-C15
7.2 xlO"5
lxlO"6
5.1xl0"5
4.1xl0"5
3.6 xlO"5
88.2429
3.7 xlO"5
lxlO"7
6x 10~5
3x 10~5
2x 10~5
50.24755
n-C16
6.1xl0"5
lxlO"6
1.6 xlO"5
2.6x 10~5
3.1xl0"5
120.096
3.5 xlO"5
6x 10~7
2x 10~6
lxlO"5
2x 10~5
186.1797
n-Cll
6.4 xlO"5
8x 10~5
0.0003
0.0001
0.0001
124.832
5.2 xlO"5
4x 10~7
3x 10~4
0.0001
2x 10~4
149.287
n-C18
4.7x 10~5
6x 10~7
-lxlO"5
1.3 xlO"5
3x 10~5
241.882
-2x 10~5
ND
ND
-7xl0"6
lxlO"5
-212.132
n-C19
0.0001
7x 10~7
3.4 xlO"5
3.8x 10~5
4x 10~5
104.148
4.7x 10~5
5x 10~7
2x 10~5
2x 10~5
2x 10~5
84.85281
n-C20
0.0004
9x 10~7
1.7 xlO"5
0.0001
0.0002
161.336
7.3 xlO"5
4x 10~7
ND
2x 10~5
5x 10~5
210.976
n-C21
0.0001
7x 10~7
-3x 10~6
4.3 xlO"5
7.6x 10~5
177.938
0.0002
lxlO"6
ND
6x 10~5
lxlO"4
210.8915
«-C22
8.3 xlO"5
2x 10~6
-9x 10~6
2.5 xlO"5
5x 10~5
198.327
0.0001
2x 10~6
ND
4x 10~5
9x 10~5
208.9179
n-C23
0.0017
2x 10~5
0.00011
0.0006
0.0009
154.725
0.0016
2x 10~5
ND
0.0005
0.001
209.4804
n-C24
0.00013
3x 10~6
-0.0005
-0.0001
0.0003
-272.35
0.0003
2x 10~6
ND
0.0001
2x 10~5
210.7272
«-C25
0.00454
7x 10~5
-0.0009
0.0012
0.0029
234.63
0.0048
6x 10~5
ND
0.0016
0.003
209.5292
n-C26
0.00226
0.0044
-0.0016
0.0017
0.0030
180.285
0.0016
2x 10~6
ND
0.0005
0.001
211.8688
n-C27
0.00091
6x 10~6
-0.0021
-0.0004
0.0015
-391.34
0.0010
8x 10~6
ND
0.0003
7x 10~4
210.5127
«-C28
0.0008
lxlO"5
-0.0015
-0.0002
0.0012
-508.1
0.0007
6x 10~6
ND
0.0002
5x 10~4
210.1918
n-C29
0.00071
9x 10~6
-0.0016
-0.0003
0.0012
-403.3
0.0007
0.001
ND
0.0006
5x 10~4
83.56717
n-C30
ND
8x 10~6
-lxlO"5
-6.7x 10~7
9x 10~6
-1352.8
ND
7x 10~6
ND
2x 10~6
ND
ND
n-C3\
ND
ND
-0.0002
-6.7x 10~5
0.0001
-173.21
ND
ND
ND
ND
ND
—
n-C32
ND
ND
5.5x 10~7
1.8x 10~7
3.2x 10~7
173.205
ND
ND
7x 10~7
2x 10~7
5x 10~7
212.132
continued
-------
Table 0-4. (concluded)
«-Alkanes
Ports R4 & R8
Port R10
10/30/01
10/31/01
11/01/01
Average
S.D.a
RSDb
10/30/01
10/31/01
11/01/01
Average
S.D.
RSD
n-C33
ND
ND
-7x 10~7
-2.3 xlO"7
4x 10~7
-173.21
ND
ND
ND
ND
ND
—
n-C34
ND
ND
5.2 xlO"5
1.7 xlO"5
3x 10~5
173.205
ND
ND
ND
ND
ND
—
n-C35
ND
ND
-3x 10~7
-lxlO"7
1.7x 10~7
-173.21
ND
ND
ND
ND
ND
—
n-C36
ND
ND
-3x 10~6
-lxlO"6
1.7x 10~6
-173.21
ND
ND
ND
ND
ND
n-C40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
SUM
0.01284
0.0045
-0.0062
a S.D. = standard deviation.
b RSD = relative standard deviation.
c ND = not detected.
-------
Table 0-5. Emission Factors (mg/kg fuel) for PAHsa from Recovery Boiler #5 as obtained from PUF Samples (WRP#2)
PAH
Ports R4 & R8
Port R10
10/30/01
10/31/01
11/01/01
Average
S.D.b
RSDC
10/30/01
10/31/01
11/01/01
Average
S.D.
RSD
dimethyl phthalate
2.6* 10~5
5.4* 10~7
9.5x 10~7
9x 10~6
1>
<10"5
159.1
lxlO"5
7>
10"7
-4
<10"6
2x 10~6
1>
<10"5
443.3
diethyl phthalate
0.0003
2.2xl0"6
6.2x 10~5
0.0001
1>
<10"4
123.5
0.0001
2>
10"6
2>
10"5
4x 10~5
6>
<10"5
139.1
naphthalene
NDd
6.8x 10~7
1.1 xlO-5
lxlO"5
1>
<10"5
107
3 xlO"5
1>
10"6
2>
10"5
2x 10~5
7>
<10"6
41.59
2-methylnaphthalene
3.2 xlO"5
7x 10~7
-7x 10~6
9x 10~6
2>
<10"5
241.1
2x 10~5
8>
10"7
-7
<10"6
5x 10~6
2>
<10"5
415
1 -methylnaphthalene
ND
5x 10~7
-7x 10~6
8x 10~6
2>
<10"5
249.7
2x 10~5
5>
10"7
-7
<10"6
5x 10~6
2>
<10"5
424.3
dibutyl phthalate
-2x 10~5
3x 10~6
5.4 xlO"5
lxlO"5
4>
<10"5
307.1
0.0012
4>
10"7
7»
10"5
0.0004
8>
<10"4
188.7
butyl benzyl phthalate
-0.0008
3.5x 10~6
-7x 10~5
-3x 10~4
4>
<10"4
-154
0.0006
-2
<10"7
-1
<10"5
0.0002
4>
<10"4
219.4
bis-2-ethylhexyl
0.0001
1.4 xlO"5
7.6x 10~5
7x 10~5
6>
<10"5
79.15
0.0003
1>
10"6
8>
10"5
0.0001
2>
<10"4
122.5
phthalate
O a PAHs = poly cyclic aromatic hydrocarbons.
^ b S.D. = standard deviation.
c RSD = relative standard deviation.
d ND = not detected.
-------
Table 0-6. Emission Factors (mg/kg fuel) for n-Alkanoic Acids from Recovery Boiler #5 as obtained from PUF Samples
(WRP#3)
Ports R4 & R8
Port R10
«-Alkanoic
Acid
10/30/01
10/31/01
11/01/01
Average
S.D.a
RSDb
10/30/01
10/31/01
11/01/01
Average
S.D.
RSD
C8
0.0004
-8.7 xlO"7
NDC
0.0001
0.0002
173.13
0.0003
2.3x
10"7
9x 10~8
lxlO"4
2>
<10"4
173
C9
0.0005
ND
ND
0.0002
0.0003
173.16
0.0001
-1.7>
<10"6
ND
3x 10~5
6>
<10"5
168
CIO
0.0002
ND
ND
6.5 xlO"5
0.0001
177.97
ND
-7.4>
<10"7
ND
8x 10~6
1>
<10"5
126
Cll
ND
ND
ND
7.4* 10~6
2x 10~5
265.14
ND
1.79
<10"6
ND
-0
5>
<10"6
-267
C12
ND
ND
ND
lxlO"5
3x 10~5
256.26
ND
1.4x
10"6
ND
-0
5>
<10"6
-231
C13
ND
-1.6x 10~7
ND
4.4x 10~6
lxlO"5
311.19
ND
-2.6>
<10"8
ND
-0
4>
<10"6
-172
C14
0.0003
ND
0.0001
0.0002
0.0001
98.674
0.0005
2.5x
10"6
0.0001
2x 10~4
3>
<10"4
141
C15
0.0004
ND
0.0002
0.0002
0.0002
99.724
0.0007
2.64
<10"6
ND
2x 10~4
4>
<10"4
169
C16
0.0009
0.0004
0.0458
0.0157
0.0261
166.45
0.0590
0.000122
0.0148
0.025
0.031
124
C17
0.0024
ND
0.0002
0.0009
0.0013
155.15
0.0006
2.56
<10"8
0.0001
2x 10~4
3>
<10"4
150
C18
0.0032
0.0003
0.0112
0.0049
0.0057
115.63
0.0090
4.13
<10"5
0.0012
0.003
0.005
143
a S.D. = standard deviation.
b RSD = relative standard deviation.
c ND = not detected.
-------
Table 0-7. Emission Factors (mg/kg fuel)
for n-Alkanes from Recovery Boiler #5 as
obtained from Quartz Filter Samples
(WRQ#1)
n-Alkanes A™>ge°f3 RSD"
Days
H-C10
2.7xl0"6
87.338
n-Cll
0.0002
173.21
n-C12
5x10^
132.43
n- C13
NDb
n-C14
-3xl0"5
-22.22
n- C15
4.8x 10"6
316.49
n- C16
2.9x 10"6
173.21
n-Cll
5.4x 10"6
118.26
n-C18
2.9x 10"6
107.7
n- C19
ND
n-C20
-2x 10"5
-12.13
n-C21
-6x 10"5
-12.15
n-C22
-4x 10"5
-81.97
n-C23
-0.0002
-36.82
n-C24
4.9x 10"5
248.44
n-C25
-0.0002
-89.76
n-C26
-0.0002
-116.6
n-C27
-0.0003
-79.66
n-C28
-0.0002
-148.2
n-C29
-0.0005
-55.57
n-C30
2.9x 10"6
166.08
n-C31
-4x 10"5
-278
n-C32
4x10^
172.6
n-C33
4.2x 10"7
173.21
n-C34
9.9x 10"5
97.56
n-C35
ND
ND
n-C36
ND
ND
n-C40
a RSD = relative standard deviation.
b ND = not detected.
0-13
-------
Table 0-8. Emission Factors (mg/kg fuel) for PAHsa from
Recovery Boiler #5 as obtained from Quartz Filter
Samples (WRQ2)
PAH Average of 3 Days RSDb
dimethyl phthalate 1 x 10-6 317.5
diethyl phthalate 3.6/10~" 217.5
naphthalene 1.4 x 10~6 151.7
2-methylnaphthalene 0 0
1-methylnaphthalene 0 0
dibutylphthalate 8.2* 10~5 69.06
butylbenzylphthalate 4.1/1 0~s 63.19
bis-2-ethylhexylphth 2.5/10~5 65.63
Table 0-9. Emission Factors (mg/kg fuel) for n-Alkanoic Acids
from Recovery Boiler #5 as obtained from Quartz Filter
Samples (WRQ3)
No data due to low recovery of internal standard
0-14
-------
TECHNICAL REPORT DATA
1. REPORT NO.
EPA-600/R-03/099b
2.
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Source Sampling Fine Particulate Matter: A Kraft Process Recovery
5. REPORT DATE
November 2003
Boiler at a Pulp and Paper Facility: Volume 2 Appendices
6. PERFORMING ORGANIZATION CODE
7. AUTHORS
Joan T. Bursey and Dave-Paul Dayton
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Eastern Research Group, Inc.
10. PROGRAM ELEMENT NO.
1600 Perimeter Park Drive
Morrisville, NC 27560
11. CONTRACT/GRANT NO.
Contract No. 68-D7-001
12. SPONSORING AGENCY NAME AND ADDRESS
U. S. EPA, Office of Research and Development
13. TYPE OF REPORT AND PERIOD COVERED
Final; 02/05/01 - 05/30/03
Air Pollution Prevention and Control Division
Research Triangle Park, North Carolina 27711
14. SPONSORING AGENCY CODE
EPA/600/13
15. SUPPLEMENTARY NOTES
The EPA Project Officer is N. Dean Smith, mail drop E343-02, phone (919) 541-2708
16. ABSTRACT
The report provides a profile of the chemical composition of particulate matter (PM) with aerodynamic
diameter 2.5 |_im or less (PM25) emitted from a recovery boiler at a pulp and paper facility using the Kraft
pulping process. Recovery boilers, common to nearly all pulp and paper mills, are usually one of the major
contributors to atmospheric emissions from the mill. Processing wood chips in a pulp mill utilizing the Kraft
process involves digesting the wood in a solution of sodium sulfide and sodium hydroxide. The spent
digestion liquor combined with water used to wash the resulting pulp is called "black liquor." After
undergoing concentration by evaporation to about 65% solids, the black liquor is fed to the recovery boiler
as fuel. Dissolved organics in the concentrated black liquor are combusted in the recovery boiler to yield
heat to generate process steam and to convert sodium sulfate formed in the process back to sodium sulfide
which can be recycled to the digestion step as a reactant. The recovery boiler tested here was equipped
with two parallel electrostatic precipitators with 169,194 linear feet of plate area per precipitator, installed in
the flue gas exhaust ducting. The data obtained during this research will assist States in determining the
major sources of PM2 5 so they can devise and institute a control strategy to attain the ambient
concentrations set by the National Ambient Air Quality Standard for PM2 5 that was promulgated in July
1977 by the U.S. EPA. Along with the PM25 emission profile, data are also provided for gas-phase
emissions of several organic compounds. Data are provided in a format suitable to be included in the EPA
source profile database, SPECIATE.
17.
KEYWORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
b. IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Air Pollution
Paper Industry
Wood Pulp
Fine Particulate Matter
Chemical Composition
Organic Compounds
Volatility
Pollution Control
Stationary Sources
13B
11L
14G
07D
07C
20M
18. DISTRIBUTION STATEMENT
19. SECURITY CLASS (This Report)
Unclassified
21. NO. OF PAGES
98
Release to Public
20. SECURITY CLASS (This Page)
Unclassified
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
forms/admin/techrpt.frm 7/8/99 pad
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