-------
Table C-13. Calculation of PM Emission Factors (11/27/01)
Test
11/27/2001 (ave)
1
2
3
4
5
6a
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (sL/mina)
PM conc. at filter (mg/L)
avg. PM conc. at filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (sL/min)
PM conc. at dilution air (mg/L)
Net PM mass conc. after dilution (mg/L)
Probe flow (sL/min)
Probe flow (m3)
Dilution air (sL/min)
Dilution air (m3)
Dilution ratio
PM conc. at stack (mg/L)
Stack gas velocity (ft/min)
Stack temperature (°F)
Stack pressure (in. Hg)
Stack area (ft2)
Stack flow (sft3/minb)
Stack flow (sL/min)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (lb/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (lb/min)
Fuel heating value (Btu/lb)
Fuel heat feed rate (Btu/min)
Total fuel mass feed rate (kg/min)
Emission factor (mg/kg)
Total fuel heat feed rate (Btu/min)
Emission factor (llg/kJ)
478.67
T100201T T100201U T100201V T100201W
0.79 0.767 0.787 0.845
8.518 8.518 8.594 8.594
0.0001940 0.0001880 0.0001910 0.0002050
0.0001910
0.0010000
8.5940000
0.0000000
0.0001910
18.7500000
8.9800000
843.9200000
403.9600000
46.0100000
0.0088000
2153.4000000
320.0000000
29.9800000
113.0973000
165191.0000000
4678208.3000000
41071.6000000
coal
229.8000000
506.7000000
13335.0000000
6756844.5000000
wood
560.9000000
1236.7000000
4392.0000000
5431586.4000000
790.7000000
51.9500000
12188430.9000000
3.1900000
a sL/min = liters per minute at standard temperature and pressure.
b sft3/min = cubic feet per minute at standard temperature and pressure.
C-15
-------
Table C-14. Calculation of PM Emission Factors (11/28/01)
Test
11/28/2001 (ave)
1
2
3
4
5
6a
6b
6c
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (sL/mina)
PM conc. at filter (mg/L)
avg. PM conc. at filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (sL/min)
PM conc. at dilution air (mg/L)
Net PM mass conc. after dilution (mg/L)
Probe flow (sL/min)
Probe flow (m3)
Dilution air (sL/min)
Dilution air (m3)
Dilution ratio
PM conc. at stack (mg/L)
Stack gas velocity (ft/min)
Stack temperature (°F)
Stack pressure (in. Hg)
Stack area (ft2)
Stack flow (sft3/minb)
Stack flow (sL/min)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (lb/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (lb/min)
Fuel heating value (Btu/lb)
Fuel heat feed rate (Btu/min)
Total fuel mass feed rate (kg/min)
Emission factor (mg/kg)
Total fuel heat feed rate (Btu/min)
Emission factor (llg/kJ)
480.17
T100201A T100201B T100201Y T100201Z
0.808 0.849 0.718 0.845
8.643 8.643 8.530 8.530
0.0001950 0.0002050 0.0001750 0.0002060
0.0001950
0.0000000
8.5680000
0.0000000
0.0001950
18.7200000
8.9900000
843.8200000
405.1800000
46.0800000
0.0090000
2153.4000000
320.0000000
29.9800000
113.0973000
165191.0000000
4678208.3000000
42079.7000000
coal wood
228.9000000
504.7000000
13335.0000000
6730174.5000000
615.7000000
1357.7000000
4392.0000000
5963018.4000000
844.6000000
49.8200000
12693192.9000000
3.1400000
a sL/min = liters per minute at standard temperature and pressure.
b sft3/min = cubic feet per minute at standard temperature and pressure.
C-16
-------
Table C-15. Calculation of PM Emission Factors (11/29/01)
Test
11/29/2001 (ave)
1
2
3
4
5
6a
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (sL/mina)
PM conc. at filter (mg/L)
avg. PM conc. at filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (sL/min)
PM conc. at dilution air (mg/L)
Net PM mass conc. after dilution (mg/L)
Probe flow (sL/min)
Probe flow (m3)
Dilution air (sL/min)
Dilution air (m3)
Dilution ratio
PM conc. at stack (mg/L)
Stack gas velocity (ft/min)
Stack temperature (°F)
Stack pressure (in. Hg)
Stack area (ft2)
Stack flow (sft3/minb)
Stack flow (sL/min)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (lb/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (lb/min)
Fuel heating value (Btu/lb)
Fuel heat feed rate (Btu/min)
Total fuel mass feed rate (kg/min)
Emission factor (mg/kg)
Total fuel heat feed rate (Btu/min)
Emission factor (llg/kJ)
480.5
T100201F T100201G T100201D T100201E
0.79 0.767 0.72 0.748
8.621 8.621 8.584 8.584
0.0001910 0.0001850 0.0001750 0.0001810
0.0001830
0.0000000
8.6210000
0.0000000
0.0001830
18.7700000
9.0200000
845.5200000
406.2700000
46.0500000
0.0084000
2153.4000000
320.0000000
29.9800000
113.0973000
165191.0000000
4678208.3000000
39409.1000000
coal wood
213.2000000
470.0000000
13335.0000000
6267450.0000000
604.7000000
1333.3000000
4392.0000000
5855853.6000000
817.8000000
48.1900000
12123303.6000000
3.0800000
a sL/min = liters per minute at standard temperature and pressure.
b sft3/min = cubic feet per minute at standard temperature and pressure.
C-17
-------
Table C-16. Calculation of Individual Filter PM Emission Factors (11/27/01)
Test 11/27/2001 (ave)
1
Sampling time (min)
478.67
2
TF sample
T100201T
T100201U T100201V
T100201W
3
PM mass on filter (mg)
0.79
0.767 0.787
0.845
4
Array flow (sL/mina)
8.518
8.518 8.594
8.594
5
PM conc. at filter (mg/L)
0.0001940
0.0001880 0.0001910
0.0002050
6b
PM mass on dilution chamber filter (mg)
0.0010000
6c
Array flow (sL/min)
8.5940000
6d
PM conc. at dilution air (mg/L)
0.0000000
6e
Net PM mass conc. after dilution (mg/L)
0.0001940
0.0001880 0.0001910
0.0002050
7
Probe flow (sL/min)
18.7500000
8
Probe flow (m3)
8.9800000
9
Dilution air (sL/min)
843.9200000
10
Dilution air (m3)
403.9600000
11
Dilution ratio
46.0100000
12
PM conc. at stack (mg/L)
0.0089000
0.0086000 0.0088000
0.0094000
13
Stack gas velocity (ft/min)
2153.4000000
14
Stack temperature (°F)
320.0000000
15
Stack pressure (in. Hg)
29.9800000
16
Stack area (ft2)
113.0973000
17
Stack flow (sft3/minb)
165191.0000000
18
Stack flow (sL/min)
4678208.3000000
19
PM emission rate from stack (mg/min)
41651.5000
40437.4000 41125.8000
44160.5000
20
Fuel type
coal wood
21
Fuel volumetric feed (gal/min)
22
Fuel density (lb/gal)
23
Fuel density (kg/gal)
24
Fuel mass feed rate (kg/min)
229.8000000 560.9000000
25
Fuel mass feed rate (lb/min)
506.7000000 1236.7000000
26
Fuel heating value (Btu/lb)
13335.0000000 4392.0000000
27
Fuel heat feed rate (Btu/min)
6756844.5000000 5431586.4000000
28
Total fuel mass feed rate (kg/min)
790.7000000
29
Emission factor (mg/kg)
52.680
51.140 52.010
55.850
30
Total fuel heat feed rate (Btu/min)
12188430.9000000
31
Emission factor (|Xg/kJ)
3.240
3.150 3.200
3.430
32
Ave. Emission Factor (mg/kg)
51.9500000
33
Ave. Emission Factor (us/kJ)
3.1900000
a sL/min = liters per minute at standard temperature and pressure.
b sfWmin = cubic feet per minute at standard temperature and pressure.
C-18
-------
Table C-17. Calculation of Individual Filter PM Emission Factors (11/28/01)
Test
11/28/2001 (ave)
1
2
3
4
5
6b
6c
6d
6e
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
Sampling time (min)
TF sample
PM mass on filter (mg)
Array flow (sL/mina)
PM conc. at filter (mg/L)
PM mass on dilution chamber filter (mg)
Array flow (sL/min)
PM conc. at dilution air (mg/L)
Net PM mass conc. after dilution (mg/L)
Probe flow (sL/min)
Probe flow (m3)
Dilution air (sL/min)
Dilution air (m3)
Dilution ratio
PM conc. at stack (mg/L)
Stack gas velocity (ft/min)
Stack temperature (°F)
Stack pressure (in. Hg)
Stack area (ft2)
Stack flow (sft3/minb)
Stack flow (sL/min)
PM emission rate from stack (mg/min)
Fuel type
Fuel volumetric feed (gal/min)
Fuel density (lb/gal)
Fuel density (kg/gal)
Fuel mass feed rate (kg/min)
Fuel mass feed rate (lb/min)
Fuel heating value (Btu/lb)
Fuel heat feed rate (Btu/min)
Total fuel mass feed rate (kg/min)
Emission factor (mg/kg)
Total fuel heat feed rate (Btu/min)
Emission factor (|ig/kJ)
Ave. Emission Factor (mg/kg)
T100201A
0.808
8.643
0.0001950
0.0001950
T100201Z
0.845
8.530
0.0002060
0.0002060
480.3
T100201B T100201Y
0.849 0.718
8.643 8.530
0.0002050 0.0001750
0.0000000
8.5680000
0.0000000
0.0002050 0.0001750
18.7200000
8.9900000
843.8200000
405.0600000
46.0800000
0.0094000 0.0081000
2153.4000000
320.0000000
29.9800000
113.0973000
165191.0000000
4678208.3000000
41978.90 44109.10 37797.20 44482.80
0.0090000
0.0095000
coal
228.9000000
504.7000000
13335.0000000
6730474.5000000
wood
615.7000000
1357.7000000
4392.0000000
5963018.4000000
844.6000000
49.700 52.220 44.750
12693192.9000000
3.140 3.290 2.820
49.8400000
3.1400000
52.670
3.320
a sL/min = liters per minute at standard temperature and pressure.
b sft3/min = cubic feet per minute at standard temperature and pressure.
C-19
-------
Table C-18. Calculation of Individual Filter PM Emission Factors (11/29/01)
Test 11/29/2001 (ave)
1
Sampling time (min)
480.5
2
TF sample
T100201F
T100201G T100201D
T100201E
3
PM mass on filter (mg)
0.79
0.767 0.720
0.748
4
Array flow (sL/mina)
8.621
8.621 8.584
8.584
5
PM conc. at filter (mg/L)
0.0001910
0.0001850 0.0001750
0.0001810
6b
PM mass on dilution chamber filter (mg)
0.0000000
6c
Array flow (sL/min)
8.6210000
6d
PM conc. at dilution air (mg/L)
0.0000000
6e
Net PM mass conc. after dilution (mg/L)
0.0001910
0.0001850 0.0001750
0.0001810
7
Probe flow (sL/min)
18.7700000
8
Probe flow (m3)
9.0200000
9
Dilution air (sL/min)
845.5200000
10
Dilution air (m3)
406.2700000
11
Dilution ratio
46.0500000
12
PM conc. at stack (mg/L)
0.0088000
0.0085000 0.0080000
0.0084000
13
Stack gas velocity (ft/min)
2153.4000000
14
Stack temperature (°F)
320.0000000
15
Stack pressure (in. Hg)
29.9800000
16
Stack area (ft2)
113.0973000
17
Stack flow (sft3/minb)
165191.0000000
18
Stack flow (sL/min)
4678208.3000000
19
PM emission rate from stack (mg/min)
41081.9000
39885.9000 37603.1000
39065.5000
20
Fuel type
coal wood
21
Fuel volumetric feed (gal/min)
22
Fuel density (lb/gal)
23
Fuel density (kg/gal)
24
Fuel mass feed rate (kg/min)
213.2000000 604.7000000
25
Fuel mass feed rate (lb/min)
470.0000000 1333.3000000
26
Fuel heating value (Btu/lb)
13335.0000000 4392.0000000
27
Fuel heat feed rate (Btu/min)
6267450.0000000 5855853.6000000
28
Total fuel mass feed rate (kg/min)
817.8000000
29
Emission factor (mg/kg)
50.230
48.770 45.980
47.770
30
Total fuel heat feed rate (Btu/min)
12123303.6000000
31
Emission factor (|Xg/kJ)
3.210
3.120 2.940
3.050
32
Ave. Emission Factor (mg/kg)
48.1900000
33
Ave. Emission Factor (us/kJ)
3.0800000
a sL/min = liters per minute at standard temperature and pressure.
b sfWmin = cubic feet per minute at standard temperature and pressure.
C-20
-------
Appendix D
Data Tables for Individual PM25
Mass Measurements
D-l
-------
Contents
Table Page
D-l Gravimetric Measurements: Electrical Low Pressure Impactor
Stages: Filters D-3
D-2 Gravimetric Measurements: Teflon Filters D-4
D-2
-------
Table D-1. Gravimetric Measurements: Electrical Low Pressure Impactor Stages:
Filters
ID Initial Weight Final Weight PM mass
mg mg m£
A101701C
IB112901H ELPI 1
32.723
32.721
-0.002
A101701B
IB112901H ELPI 2
33.929
33.974
0.045
A101701A
IB 112901H ELPI 3
34.108
34.174
0.066
A101601Y
IB112901H ELPI 4
33.332
33.369
0.037
A101601X
IB 112901H ELPI 5
33.164
33.193
0.029
A101601W
IB 112901H ELPI 6
33.753
33.745
-0.008
A101601V
IB 112901H ELPI 7
33.559
33.718
0.159
A101601U
IB112901H ELPI 8
33.182
33.578
0.396
A101601T
IB 112901H ELPI 9
33.804
34.132
0.328
A101601S
IB112901H ELPI 10
33.316
33.425
0.109
A101601R
IB112901H ELPI 11
33.31
33.331
0.021
A101601Q
IB112901H ELPI 12
33.24
33.252
0.012
A101601P
IB112901H ELPI 13
32.848
32.852
0.004
A101701D
IB112901H ELPI FB
33.265
33.273
0.008
D-3
-------
Table D-2. Gravimetric Measurements: Teflon Filters
ID Initial wt. Final wt. PM mass PM mass
g
g
g
mg
T100201T
IB112701HR2A1
0.185371
0.186161
0.00079
0.790
T100201U
IB112701HR2B1
0.186555
0.187322
0.000767
0.767
T100201X
IB112701HFB
0.186201
0.186211
10"5
0.010
T100201V
IB112701HR6A1
0.183932
0.184719
0.000787
0.787
T100201W
IB112701HR6B1
0.188563
0.189408
0.000845
0.845
small hole in filter
T100201S
IB112701HD1B1
0.187256
0.187257
1
0.001
T102201A
IB112801HR2A1
0.196291
0.197099
0.000808
0.808
T102201B
IB112801HR2B1
0.184383
0.185232
0.000849
0.849
T102201C
IB112801HD1B1
0.171894
0.171886
-8x 10~6
-0.008
small hole in filter
T100201Y
IB112801HR6A1
0.191657
0.192375
0.000718
0.718
T100201Z
IB112801HR6B1
0.189683
0.190528
0.000845
0.845
T102201F
IB112901HR2A1
0.187373
0.188133
0.00076
0.760
T102201G
IB112901HR2B1
0.193098
0.193844
0.000746
0.746
T102201H
IB112901H FB
0.186498
0.186489
-9x 10~6
-0.009
T102201D
IB112901HR6A1
0.189819
0.190539
0.00072
0.720
T102201E
IB112901HR6B1
0.173496
0.174244
0.000748
0.748
D-4
-------
Appendix E
Data Tables for Individual Carbonyl Samples
E-l
-------
Contents
Table Page
E-l Carbonyls; Method and Field Blanks E-3
E-2A Carbonyls, Individual Tube Results, Field Samples (11/27/01) E-4
E-2B Carbonyls, Individual Tube Results, Field Samples (11/28/01) E-6
E-2C Carbonyls, Individual Tube Results, Field Samples (11/29/01) E-8
E-3A Hogged Fuel Boiler, Carbonyls and Uncertainties (11/27/01) E-10
E-3B Hogged Fuel Boiler, Carbonyls and Uncertainties (11/28/01) E-l 1
E-3C Hogged Fuel Boiler, Carbonyls and Uncertainties (11/29/01) E-12
E-4 Hogged Fuel Boiler, Summary of Carbonyls for Test Days 11/27-29/01 E-13
E-2
-------
Table E-1. Carbonyls, Method and Field Blanks
Method Field
Blank Blank
Compound CAS No. |ig |Xg
formaldehyde
50-00-0
0.0 320
0.036
acetaldehyde
75-07-0
0.1480
0.065
acetone
67-64-1
0.2090
0.181
propionaldehyde
123-38-6
0.007
NDa
crotonaldehyde
4170-30-0
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0500
0.052
benzaldehyde
100-52-7
ND
ND
isovaleraldehyde
590-86-3
ND
ND
valeraldehyde
110-62-3
0.008
ND
o-tolualdehyde
529-20-4
ND
ND
m-tolualdchydc
620-23-5
ND
ND
/Molualdchydc
104-87-0
ND
ND
hexaldehyde
66-25-1
0.0180
0.018
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
diacetyl
431-03-8
ND
ND
methacrolein
78-85-3
ND
ND
2-butanone
78-93-3
0.0440
0.016
glyoxal
107-22-2
0.0940
0.083
acetophenone
98-86-2
ND
ND
methylglyoxal
78-98-8
0.0490
0.048
octanal
124-13-0
ND
ND
nonanal
124-19-6
0.1110
0.125
Sum, Speciated
0.7700
0.624
Sum, Unspeciated
0.8170
0.873
Total (Soeciated + Unspeciated)
1.5870
1.497
a ND = not detected.
E-3
-------
Table E-2A. Carbonyls, Individual Tube Results, Field Samples (11/27/01)
Site ID
WHF#2
WHF#2
WHF#2
WHB#2
WHB#2
Will}# 2
Field ID
Hd3Al
Hd3A2
Hd3A3
Hr3Al
Hr3A2
Hr3A3
Volume Sampled
395.82
395.82
395.82
385.13
385.13
385.13
ERG ID
24261
24262
24263
24264
24265
24266
Sampling Date
11/27/01
11/27/01
11/27/01
11/27/01
11/27/01
11/27/01
Analysis Date
12/27/01
12/27/01
12/27/01
12/27/01
12/27/01
12/27/01
Data File
F1L-007
F1L-008
F1L-009
F1L-010
F1L-011
F1L-012
Carbonyls
DA,
DA
RC,
RC
No negsc
DA,a front
middle
DA, rear
3 tubes
RC,b front
middle
RC, rear
3 tubes
RC-DA
RC-DA
Compound
CAS No.
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
formaldehyde
50-00-0
0.0650
0.0380
0.0360
0.1390
0.3490
0.0420
0.0250
0.4160
0.2770
0.2770
acetaldehyde
75-07-0
0.3190
0.0830
0.0690
0.4710
0.1070
0.1090
0.1040
0.3200
-0.1510
NDd
acetone
67-64-1
0.2540
0.2280
0.2270
0.7090
2.3060
1.8820
0.4570
4.6450
3.9360
3.9360
propionaldehyde
123-38-6
0.0060
0.0070
ND
0.0130
0.1390
ND
ND
0.1390
0.1260
0.1260
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.1110
0.1000
0.0790
0.2900
0.1770
0.1020
0.0940
0.3730
0.0830
0.0830
benzaldehyde
100-52-7
ND
0.0020
ND
0.0020
0.0670
0.0030
ND
0.0700
0.0680
0.0680
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
ND
0.0690
ND
ND
0.0690
0.0690
0.0690
o-tolualdehyde
529-20-4
ND
0.0330
ND
0.0330
ND
ND
ND
ND
-0.0330
ND
/M-toliialdchydc
620-23-5
ND
0.0190
ND
0.0190
ND
ND
ND
ND
-0.0190
ND
/Molualdchydc
104-87-0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
hexaldehyde
66-25-1
0.0180
ND
ND
0.0180
0.0870
0.0230
0.0160
0.1260
0.1080
0.1080
2,5-dimethylbenzal-
5779-94-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
dehyde
diacetyl
431-03-8
ND
ND
ND
ND
ND
0.0040
ND
0.0040
0.0040
0.0040
methacrolein
78-85-3
ND
ND
ND
ND
0.0020
ND
ND
0.0020
0.0020
0.0020
2-butanone
78-93-3
0.0250
0.0520
0.0380
0.1150
0.0780
0.0350
0.0380
0.1510
0.0360
0.0360
continued
glyoxal
107-22-2
0.1310
0.1370
0.0850
0.3530
0.1390
0.1270
0.0930
0.3590
0.0060
0.0060
acetophenone
98-86-2
ND
ND
ND
ND
0.0390
ND
ND
0.0390
0.0390
0.0390
methylglyoxal
78-98-8
0.0470
0.0390
0.0460
0.1320
0.0780
0.0550
0.0490
0.1820
0.0500
0.0500
-------
Table E-2A. (concluded)
Will}# 2
Hr3A3
385.13
24266
11/27/01
12/27/01
F1L-012
Carbonyls
DA,
DA
RC,
RC
No negsc
DA,a front
middle
DA, rear
3 tubes
RC,b front
middle
RC, rear
3 tubes
RC-DA
RC-DA
Compound
CAS No.
Hg
Hg
^g
Hg
Hg
Hg
^g
Hg
Hg
Hg
octanal
124-13-0
0.0390
ND
ND
0.0390
0.0720
0.0480
ND
0.1200
0.0810
0.0810
nonanal
124-19-6
0.2330
0.1210
1.0600
1.4140
0.2950
0.1190
0.0870
0.5010
-0.9130
ND
Sum, Speciated
1.2480
0.8590
1.6400
3.7470
4.0040
2.5490
0.9630
7.5160
3.7690
4.8850
frt Sum, Unspeciated
2.3845
1.0940
1.0580
4.5365
2.3495
1.0790
1.0300
4.4585
-0.0780
e
^ Total (Sncciatcd +
llnsncciatcd)
3.6325
1.9530
2.6980
8.2835
6.3535
3.6280
1.9930
11.9745
3.6910
4.8850
a DA = dilution air.
b RC = residence chamber.
c Entries for which RC-DA are negative are considered to be zero, or not detected.
d ND = not detected.
e RC-DA is a small negative number; zero is used in the calculations, and the "Total (Speciated + Unspeciated)" is considered to equal the "Sum, Speciated" for 11/27/01.
Site ID
WHF#2
WHF#2
WHF#2
WHB#2
WHB#2
Field ID
Hd3Al
Hd3A2
Hd3A3
Hr3Al
Hr3A2
Volume Sampled
395.82
395.82
395.82
385.13
385.13
ERG ID
24261
24262
24263
24264
24265
Sampling Date
11/27/01
11/27/01
11/27/01
11/27/01
11/27/01
Analysis Date
12/27/01
12/27/01
12/27/01
12/27/01
12/27/01
Data File
F1L-007
F1L-008
F1L-009
F1L-010
F1L-011
-------
Table E-2B. Carbonyls, Individual Tube Results, Field Samples (11/28/01)
Site ID
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
Field ID
Hd3Al
Hd3A2
Hd3A3
Hr3Al
Hr3A2
Hr3A3
Volume Sampled
408.35
408.35
408.35
391.57
391.57
391.57
ERG ID
24267
24268
24269
24272
24271
24270
Sampling Date
11/28/01
11/28/01
11/28/01
11/28/01
11/28/01
11/28/01
Analysis Date
12/17/01
12/17/01
12/17/01
12/28/01
12/28/01
12/28/01
Data File
F1L-013
F1L-014
F1L-017
F1L-020
F1L-019
F1L-018
Compound
CAS No.
DA,a front
DA, middle
DA, rear
DA, 3 tubes
RC,b front
RC, middle
RC, rear
RC, 3 tubes
Carbonyl
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
RC-DA
Hg
formaldehyde
50-00-0
0.0500
0.0330
0.0330
0.1160
0.0260
0.0330
0.4970
0.5560
0.4400
acetaldehyde
75-07-0
0.1020
0.0730
0.0740
0.2490
0.1220
0.1180
0.9310
1.1710
0.9220
acetone
67-64-1
0.1280
0.2520
0.2330
0.6130
NDC
ND
ND
ND
ND
propionaldehyde
123-38-6
ND
ND
ND
ND
ND
ND
0.069
0.0690
0.0690
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0980
0.0930
0.0790
0.2700
0.0760
0.0940
0.1680
0.3380
0.0680
benzaldehyde
100-52-7
0.004
0.0010
0.0050
0.0100
ND
0.0010
0.0520
0.0530
0.0430
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
ND
ND
ND
0.047
0.0470
0.0470
o-tolualdehyde
529-20-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
/M-toliialdchydc
620-23-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
/Molualdchydc
104-87-0
ND
ND
ND
ND
ND
0.033
ND
0.0330
0.0330
hexaldehyde
66-25-1
0.0160
0.0140
0.0160
0.0460
0.0240
0.0160
0.0600
0.1000
0.0540
2,5-dimethylbenzal-
5779-94-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
dehyde
diacetyl
431-03-8
ND
ND
ND
ND
ND
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-butanone
78-93-3
0.0160
0.0330
0.0250
0.0740
0.0680
0.0220
0.0500
0.1400
0.0660
glyoxal
107-22-2
0.0810
0.1420
0.0910
0.3140
ND
ND
0.0890
0.0890
ND
acetophenone
98-86-2
ND
ND
ND
ND
ND
ND
0.028
0.0280
0.0280
continui
methylglyoxal
78-98-8
0.0510
0.0340
0.0340
0.1190
0.0550
0.0510
0.0750
0.1810
0.0620
octanal
124-13-0
0.0340
ND
ND
0.0340
ND
ND
0.0650
0.0650
0.0310
-------
Table E-2B. (concluded)
Site ID
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
Field ID
Hd3Al
Hd3A2
Hd3A3
Hr3Al
Hr3A2
Hr3A3
Volume Sampled
408.35
408.35
408.35
391.57
391.57
391.57
ERG ID
24267
24268
24269
24272
24271
24270
Sampling Date
11/28/01
11/28/01
11/28/01
11/28/01
11/28/01
11/28/01
Analysis Date
12/17/01
12/17/01
12/17/01
12/28/01
12/28/01
12/28/01
Data File
F1L-013
F1L-014
F1L-017
F1L-020
F1L-019
F1L-018
Compound
CAS No.
DA,a front
DA, middle
DA, rear
DA, 3 tubes
RC,b front
RC, middle
RC, rear
RC, 3 tubes
Carbonyls
Hg
Hg
Hg
Hg
^g
Hg
Hg
Hg
RC-DA
H'g
nonanal
124-19-6
0.2350
0.0840
0.0450
0.3640
0.0980
0.1020
0.2740
0.4740
0.1100
Sum, Speciated
0.8150
0.7590
0.6350
2.2090
0.4690
0.4700
2.4050
3.3440
1.9730
Sum, Unspeciated
1.642
0.9775
1.0140
3.6335
0.8775
1.6925
3.8500
6.4200
2.7865
Total (Sncciatcd +
llnsncciatcd)
2.4570
1.7365
1.6490
5.8425
1.3465
2.1625
6.2550
9.7640
4.7595
a DA = dilution air.
b RC = residence chamber.
c ND = not detected.
-------
Table E-2C. Carbonyls, Individual Tube Results, Field Samples (11/29/01)
Site ID
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
Field ID
Hd3Al
Hd3A2
Hd3A3
Hr3Al
Hr3A2
Hr3A3
Volume Sampled
464.65
464.65
464.65
403.44
403.44
403.44
ERG ID
24273
24273
24273
24276
24277
24278
Sampling Date
11/29/01
11/29/01
11/29/01
11/29/01
11/29/01
11/29/01
Analysis Date
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
Data File
F1L-021
F1L-022
F1L-023
F1L-024
F1L-025
F1L-026
Carbonyls
DA,a front DA, middle DA, rear DA, 3 tubes RC,b front RC, middle RC, rear RC, 3 tubes RC-DA
Compound
CAS No.
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
Hg
formaldehyde
50-00-0
0.0560
0.0360
0.0480
0.1400
0.3140
0.0350
0.0310
0.3800
0.2400
acetaldehyde
75-07-0
0.2310
0.0690
0.1360
0.4360
0.7020
0.071
0.115
0.8880
0.4520
acetone
67-64-1
0.1270
0.2340
0.2360
0.5970
0.6140
0.4200
0.2330
1.2670
0.6700
propionaldehyde
123-38-6
0.0090
NDC
ND
0.0090
0.049
ND
0.011
0.0600
0.0510
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.1120
0.1080
0.1050
0.3250
0.1480
0.1300
0.1180
0.3960
0.0710
benzaldehyde
100-52-7
ND
0.0010
0.0030
0.0040
0.0340
0.0050
0.0010
0.0400
0.0360
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
ND
0.032
ND
ND
0.0320
0.0320
o-tolualdehyde
529-20-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
/M-toliialdchydc
620-23-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
/Molualdchydc
104-87-0
ND
ND
ND
ND
ND
ND
ND
ND
ND
hexaldehyde
66-25-1
0.0270
0.0140
0.0190
0.0600
0.0470
0.0160
0.0180
0.0810
0.0210
2,5 -dimethy lbenzal-
5779-94-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
dehyde
diacetyl
431-03-8
0.0030
ND
ND
0.0030
0.0010
0.001
ND
0.0010
ND
methacrolein
78-85-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-butanone
78-93-3
0.0040
0.0290
0.0370
0.0700
0.0310
0.0350
0.0420
0.1080
0.0380
glyoxal
107-22-2
0.0720
0.0670
0.1560
0.2950
0.1040
0.1200
ND
0.2240
ND
acetophenone
98-86-2
ND
ND
ND
ND
0.0300
ND
ND
0.0300
0.0300
-------
Table E-2C. (concluded)
Site ID
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
WHB#2
Field ID
Hd3Al
Hd3A2
Hd3A3
Hr3Al
Hr3A2
Hr3A3
Volume Sampled
464.65
464.65
464.65
403.44
403.44
403.44
ERG ID
24273
24273
24273
24276
24277
24278
Sampling Date
11/29/01
11/29/01
11/29/01
11/29/01
11/29/01
11/29/01
Analysis Date
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
Data File
F1L-021
F1L-022
F1L-023
F1L-024
F1L-025
F1L-026
Carbonyls
DA,a front
DA, middle
DA, rear
DA, 3 tubes
RC,b front
RC, middle
RC, rear
RC, 3 tubes
RC-DA
Compound
CAS No.
JAg
JAg
JAg
JAg
JAg
JAg
JAg
M-g
M-g
methylglyoxal
78-98-8
0.0500
0.0500
0.0540
0.1540
0.0560
0.0530
0.0480
0.1570
0.0030
octanal
124-13-0
0.0400
0.0370
ND
0.0770
0.0580
ND
ND
0.0580
ND
nonanal
124-19-6
0.2630
0.0920
0.1120
0.4670
0.2880
0.0770
0.1050
0.4700
0.0030
Sum, Speciated
0.9940
0.7370
0.9060
2.6370
2.5080
0.9630
0.7220
4.1920
1.6470
Sum, Unspeciated
1.2215
1.0145
0.9305
3.1665
2.4570
0.9880
0.9960
4.4410
1.2745
Total (Speciated +
Unspeciated)
2.2155
1.7515
1.8365
5.8035
4.9650
1.9510
1.7180
8.6340
2.9215
a DA = dilution air.
b RC = residence chamber.
c ND = not detected.
-------
Table E-3A. Hogged Fuel Boiler, Carbonyls and Uncertainties (11/27/01)
RC-DA1
Uncertainty
%
Uncertainty
Comnound
CAS No.
LLP
Plus/Minus
Total
Plus/Minus
formaldehyde
50-00-0
0.277
0.0305
7.349
0.810
acetaldehyde
75-07-0
NDb
acetone
67-64-1
3.9360
0.1665
104.431
4.417
propionaldehyde
123-38-6
0.1260
3.343
ND
crotonaldehyde
4170-30-0
ND
butyr/isobutyraldehyde
123-72-8
0.0830
0.0048
2.202
0.129
benzaldehyde
100-52-7
0.0680
0.0021
1.804
0.055
isovaleraldehyde
590-86-3
ND
valeraldehyde
110-62-3
0.0690
1.831
ND
o-tolualdehyde
529-20-4
ND
m-toliialdchyde
620-23-5
ND
/Molualdchvdc
104-87-0
ND
hexaldehyde
66-25-1
0.1080
0.0100
2.865
0.266
2,5 -dimethylbenzaldehyde
5779-94-2
ND
diacetyl
431-03-8
0.0040
0.0003
0.106
0.009
methacrolein
78-85-3
0.0020
0.0001
0.053
0.003
2-butanone
78-93-3
0.0360
0.0029
0.955
0.078
glyoxal
107-22-2
0.0060
0.0002
0.159
0.004
acetophenone
98-86-2
0.0390
0.0019
1.035
0.049
methylglyoxal
78-98-8
0.0500
0.0061
1.327
0.163
octanal
124-13-0
0.0810
0.0065
2.149
0.173
nonanal
124-19-6
ND
Sum, Speciated
4.8850
Sum, Unspeciated
Total (Soeciated + UnsDeciated)
4.8850
a RC = residence chamber; DA = dilution air.
b ND = not detected.
E-10
-------
Table E-3B. Hogged Fuel Boiler, Carbonyls and Uncertainties (11/28/01)
RC-DA1
Uncertainty
%
Uncertainty
Compound
CAS No.
Hg
Plus/Minus
Total
Plus/Minus
formaldehyde
50-00-0
0.4400
0.0485
0.3676
0.0405
acetaldehyde
75-07-0
0.9220
0.0105
0.7703
0.0088
acetone
67-64-1
NDb
ND
ND
propionaldehyde
123-38-6
0.0690
0.0005
0.0576
0.0004
crotonaldehyde
4170-30-0
ND
butyr/isobutyraldehyde
123-72-8
0.0680
0.0040
0.0568
0.0033
benzaldehyde
100-52-7
0.0430
0.0013
0.0359
0.0011
isovaleraldehyde
590-86-3
ND
valeraldehyde
110-62-3
0.0470
0.0045
0.0393
0.0038
o-tolualdehyde
529-20-4
ND
m-tolualdchydc
620-23-5
ND
/Molualdchydc
104-87-0
0.0330
0.0019
0.0276
0.0015
hexaldehyde
66-25-1
0.0540
0.0050
0.0451
0.0042
2,5 -dimethylbenzaldehyde
5779-94-2
ND
diacetyl
431-03-8
ND
methacrolein
78-85-3
ND
2-butanone
78-93-3
0.0660
0.0054
0.0551
0.0045
glyoxal
107-22-2
ND
acetophenone
98-86-2
0.0280
0.0013
0.0234
0.0011
methylglyoxal
78-98-8
0.0620
0.0076
0.0518
0.0064
octanal
124-13-0
0.0310
0.0025
0.0259
0.0021
nonanal
124-19-6
0.1100
0.0089
0.0919
0.0074
Sum, Speciated
1.9730
Sum, Unspeciated
2.7865
Total (Soeciated + UnsDeciated)
4.7595
a RC = residence chamber; DA = dilution air.
b ND = not detected.
E-ll
-------
Table E-3C. Hogged Fuel Boiler, Carbonyls and Uncertainties (11/29/01)
RC-DA1
Uncertainty
%
Uncertainty Uncertainty
Compound
CAS No.
US
Plus/Minus
Total
Plus/Minus
Ug/m3
formaldehyde
50-00-0
0.24
0.0264
8.4791
0.9344
0.0035
acetaldehyde
75-07-0
0.452
0.0052
15.9689
0.1820
0.005
acetone
67-64-1
0.6700
0.0283
23.6707
1.0013
0.0058
propionaldehyde
123-38-6
0.051
0.0003
1.8018
0.0119
0.0027
crotonaldehyde
4170-30-0
NDb
0.003
butyr/isobutyraldehyde
123-72-8
0.071
0.0041
2.5084
0.1465
0.0076
benzaldehyde
100-52-7
0.036
0.0011
1.2719
0.0389
0.004
isovaleraldehyde
590-86-3
ND
0.0044
valeraldehyde
110-62-3
0.032
0.0031
1.1305
0.1083
0.004
o-tolualdehyde
529-20-4
ND
0.0199
m-toliialdchyde
620-23-5
ND
0.0199
/Molualdchvdc
104-87-0
ND
0.0199
hexaldehyde
66-25-1
0.021
0.0020
0.7419
0.0690
0.0028
2,5 -dimethylbenzaldehyde 5 779-94-2
ND
0.0159
diacetyl
431-03-8
ND
0.011
methacrolein
78-85-3
ND
0.0072
2-butanone
78-93-3
0.0380
0.0031
1.3425
0.1091
0.0077
glyoxal
107-22-2
ND
0.0196
acetophenone
98-86-2
0.03
0.0014
1.0599
0.0505
1.0258
methylglyoxal
78-98-8
0.0030
0.0004
0.1060
0.0130
0.0146
octanal
124-13-0
ND
0.0106
nonanal
124-19-6
0.003
0.0002
0.1060
0.0085
0.0211
Sum, Speciated
1.5560
Sum, Unspeciated
1.2745
Total (Speciated + Unspeciated)
2.8305
a RC = residence chamber; DA = dilution air.
b ND = not detected.
E-12
-------
Table E-4. Hogged Fuel Boiler, Summary of Carbonyls for Test Days 11/27-29/01
Field
RC-DA3
RC-DA
RC-DA
Blank
11/27/01
11/28/01
11/29/01
Compound
CAS No.
US
US
US
US
formaldehyde
50-00-0
0.036
0.2770
0.4400
0.2400
acetaldehyde
75-07-0
0.0650
NDb
0.922
0.4520
acetone
67-64-1
0.181
3.936
ND
0.6700
propionaldehyde
123-38-6
ND
0.126
0.069
0.0510
crotonaldehyde
4170-30-0
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0520
0.0830
0.068
0.0710
benzaldehyde
100-52-7
ND
0.0680
0.043
0.0360
isovaleraldehyde
590-86-3
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
0.0690
0.047
0.0320
o-tolualdehyde
529-20-4
ND
ND
ND
ND
m-tolualdchvdc
620-23-5
ND
ND
ND
ND
/Molualdchvdc
104-87-0
ND
ND
0.033
ND
hexaldehyde
66-25-1
0.0180
0.1080
0.054
0.0210
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
diacetyl
431-03-8
ND
0.0040
ND
ND
methacrolein
78-85-3
ND
0.0020
ND
ND
2-butanone
78-93-3
0.0160
0.0360
0.0660
0.0380
glyoxal
107-22-2
0.0830
0.0060
ND
ND
acetophenone
98-86-2
ND
0.0390
0.0280
0.0300
methylglyoxal
78-98-8
0.0480
0.0500
0.0620
0.0030
octanal
124-13-0
ND
0.0810
0.0310
ND
nonanal
124-19-6
0.1250
ND
0.1100
0.0030
Sum, Speciated
0.6240
4.8850
1.9730
1.6470
Mean, Speciated
2.8350
Standard Deviation, Speciated
1.7828
Sum, Unspeciated
0.8730
C
2.7865
1.2745
Total (Speciated + Unspeciated)
1.4970
4.8850
4.7595
2.9215
Mean, Total
4.1887
Standard Deviation, Total
1.0992
a RC = residence chamber; DA = dilution air.
b ND = not detected.
c RC-DA is a small negative number; zero is used in the calculations, and the "Total (Speciated + Unspeciated)" is
considered to equal the "Sum, Speciated" for 11/27/01.
E-13
-------
Appendix F
Data Tables for Individual NMOC Samples
F-l
-------
Contents
Table Page
F-l SNMOCs from Hogged Fuel Boiler No 2: Laboratory Blank and
Ambient Canisters (11/27/01) F-3
F-2A SNMOCs from Hogged Fuel Boiler #2 Collected in Canisters on 11/27/01 F-6
F-2B SNMOCs from Hogged Fuel Boiler #2 Collected in Canisters on 11/28/01 .... F-10
F-2C SNMOCs from Hogged Fuel Boiler #2 Collected in Canisters on 11/29/01 .... F-14
F-3 Summary of SNMOCs Collected in Canisters from Hogged Fuel Boiler #2
on Test 11/27/01 through 11/29/01 F-l8
F-4A Total SNMOCs Collected from Hogged Fuel Boiler #2 on 11/27/01 F-21
F-4B Total SNMOCs Collected from Hogged Fuel Boiler #2 on 11/28/01 F-25
F-4C Total SNMOCs Collected from Hogged Fuel Boiler #2 on 11/29/01 F-29
F-5A SNMOC Values for 11/27/01 in SPECIATE Format F-33
F-5B SNMOC Values for 11/28/01 in SPECIATE Format F-36
F-5C SNMOC Values for 11/29/01 in SPECIATE Format F-39
F-6 Summary of SNMOC from Hogged Fuel Boiler #2 for All Test Days
as Weight Percent of Total F-42
F-2
-------
Table F-1. SNMOCs from Hogged Fuel Boiler No 2: Laboratory Blank and Ambient
Canisters (11/27/01)
Laboratory
Ambient
Blank
Canisters
Compound
CAS No.
U2/m3
U2/m3
ethylene
74-85-1
0.11
0.84
acetylene
74-86-2
NDa
0.54
ethane
74-84-0
0.09
1.84
propylene
115-07-1
ND
0.31
propane
74-98-6
ND
1.79
propyne
74-99-7
ND
ND
isobutane
75-28-5
ND
0.55
isobutene/1 -butene
115-11-7/106-98-0
ND
0.26
1,3-butadiene
106-99-0
ND
ND
/7-butane
106-97-8
0.13
1.08
/ram-2-butcnc
624-64-6
ND
0.13
cy.v-2-butcnc
590-18-1
ND
0.16
3 -methyl-1 -butene
563-45-1
ND
ND
isopentane
78-78-4
0.13
ND
1-pentene
109-67-1
ND
0.13
2-methyl-1 -butene
563-46-2
ND
0.16
/7-pentane
109-66-0
0.09
0.53
isoprene
78-79-4
ND
0.17
/ram-2-pentene
646-04-8
ND
0.19
cy.v-2-pcntcnc
627-20-3
ND
0.18
2-methyl-2-butene
513-35-9
ND
ND
2,2-dimethylbutane
75-83-2
0.10
0.28
cyclopentene
142-29-0
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
cyclopentane
287-92-3
ND
0.17
2,3 -dimethylbutane
79-29-8
ND
0.29
2-methylpentane
107-83-5
ND
1.37
3-methylpentane
96-14-0
0.09
10.14
2-methyl-1 -pentene
763-29-1
ND
ND
1-hexene
592-41-6
0.10
0.23
2-ethyl-l-butene
760-21-4
ND
ND
/7-hexane
110-54-3
0.08
404.42b
fra«s-2-hexene
4050-45-7
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
methylcyclopentane
96-37-7
ND
52.95
2,4-dimethylpentane
108-08-7
0.07
0.21
benzene
71-43-2
0.09
2.11
continued
F-3
-------
Table F-1. (continued)
Laboratory
Ambient
Blank
Canisters
Compound
CAS No.
U2/m3
U2/m3
cyclohexane
110-82-7
0.11
0.36
2-methylhexane
591-76-4
ND
0.46
2,3 -dimethylpentane
565-59-3
0.11
0.35
3-methylhexane
589-34-4
ND
0.33
1-heptene
592-76-7
ND
ND
2,2,4-trimethylpentane
540-84-1
ND
0.26
/7-hcptanc
142-82-5
ND
0.24
methylcyclohexane
108-87-2
ND
0.25
2,2,3-trimethylpentane
564-02-3
ND
ND
2,3,4-trimethylpentane
565-75-3
ND
0.14
toluene
108-88-3
0.09
0.75
2-methylheptane
592-27-8
ND
0.14
3-methylheptane
589-81-1
ND
0.14
1-octene
111-66-0
ND
ND
/7-octanc
111-65-9
ND
0.18
ethylbenzene
100-41-4
ND
0.16
m-xylene//?-xylene
108-38-3/106-42-3
ND
0.29
styrene
100-42-5
ND
0.12
o-xylene
95-47-6
ND
0.18
1-nonene
124-11-8
ND
ND
/7-nonanc
111-84-2
ND
0.14
isopropylbenzene
98-82-8
ND
0.14
alpha-pinene
80-56-8
ND
10.35
«-propylbcnzcnc
103-65-1
ND
0.11
m-cthyltolucnc
620-14-4
0.07
0.80
/;-cthyltolucnc
622-96-8
ND
0.16
1,3,5 -trimethylbenzene
108-67-8
ND
0.09
o-ethyltoluene
611-14-3
ND
ND
beta-pinene
127-91-3
ND
1.21
1,2,4-trimethylbenzene
95-63-6
0.08
0.21
1-decene
872-05-9
ND
ND
«-dccanc
124-18-5
0.07
0.23
1,2,3 -trimethylbenzene
526-73-8
ND
0.13
m-dicthylbcnzcnc
141-93-5
ND
0.11
/;-dieth\ lbenzene
105-05-5
ND
ND
1-undecene
821-95-4
ND
0.13
/7-undccanc
1120-21-4
0.27
0.49
1-dodecene
112-41-4
ND
ND
continued
F-4
-------
Table F-1. (concluded)
Laboratory Ambient
Blank Canisters
Compound CAS No. Ug/m3 Ug/m3
/7-dodccanc
112-40-3
0.26
0.61
1-tridecene
2437-56-1
ND
ND
/7-tridccanc
629-50-5
ND
ND
Total Speciated
2.14
500.29
Total Unspeciated
1.56
147.28
Total (Speciated + Unspeciated)0
3.70
647.57
a ND = not detected.
b w-Hexane in the ambient canister is a contaminant from the denuders. Since the ambient canister is not
involved in further calculations, the w-hexane value is included as a reference.
c Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
F-5
-------
Table F-2A. SNMOCsafrom Hogged Fuel Boiler #2 Collected in Canisters on 11/27/01
Residence
Dilution
No Negsc
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
V=3.900L
Chamber
V=3.900L
Air
RC-DAb
RC-DA
Compound
CAS No.
Ug/m3
US
Ug/m3
Ug
Ug
Ug
ethylene
74-85-1
1.59
0.0062
0.97
0.0038
0.0024
0.0024
acetylene
74-86-2
0.96
0.0037
0.55
0.0021
0.0016
0.0016
ethane
74-84-0
3.72
0.0145
3.30
0.0129
0.0016
0.0016
propylene
115-07-01
2.09
0.0082
1.42
0.0055
0.0026
0.0026
propane
74-98-6
7.25
0.0283
6.73
0.0262
0.0020
0.0020
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
0.73
0.0028
0.46
0.0018
0.0011
0.0011
isobutene/1 -butene
115-11-7/106-98-0
1.24
0.0048
0.28
0.0011
0.0037
0.0037
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
1.01
0.0039
0.50
0.0020
0.0020
0.0020
fra«s-2-butene
624-64-6
0.42
0.0016
0.12
0.0005
0.0012
0.0012
cy.v-2-butcnc
590-18-1
0.65
0.0025
0.17
0.0007
0.0019
0.0019
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.79
0.0031
0.23
0.0009
0.0022
0.0022
1-pentene
109-67-1
0.44
0.0017
0.17
0.0007
0.0011
0.0011
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
0.73
0.0028
0.23
0.0009
0.0020
0.0020
isoprene
78-79-4
0.33
0.0013
0.13
0.0005
0.0008
0.0008
fra«s-2-pentene
646-04-8
0.49
0.0019
0.11
0.0004
0.0015
0.0015
cy.v-2-pcntcnc
627-20-3
0.54
0.0021
0.16
0.0006
0.0015
0.0015
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.13
0.0044
0.22
0.0009
0.0035
0.0035
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
continued
-------
Table F-2A. (continued)
Compound
CAS No.
Residence
Chamber
V=3.900L
Ug/m3
cyclopentane
287-92-3
0.49
2,3 -dimethy lbutane
79-29-8
0.91
2-methylpentane
107-83-5
10.85
3-methylpentane
96-14-0
0.75
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
1.00
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
3.48
/ram-2-hcxcnc
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
0.75
2,4-dimethylpentane
108-08-7
0.55
benzene
71-43-2
8.63
cyclohexane
110-82-7
0.73
2-methylhexane
591-76-4
0.98
2,3 -dimethy lpentane
565-59-3
0.94
3-methylhexane
589-34-4
0.52
1-heptene
592-76-7
2.44
2,2,4-trimethylpentane
540-84-1
0.47
^-heptane
142-82-5
0.49
methylcyclohexane
108-87-2
0.54
2,2,3-trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.48
toluene
108-88-3
0.89
Dilution
No Negsc
Residence
Air
Dilution
SNMOC
SNMOC
Chamber
V=3.900L
Air
RC-DAb
RC-DA
US
Ug/m3
US
US
US
0.0019
0.16
0.0006
0.0013
0.0013
0.0035
0.25
0.0010
0.0026
0.0026
0.0423
0.23
0.0009
0.0414
0.0414
0.0029
0.25
0.0010
0.0020
0.0020
ND
ND
ND
ND
ND
0.0039
0.25
0.0010
0.0029
0.0029
ND
ND
ND
ND
ND
0.0136
1.27
0.0050
0.0086
0.0086
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0029
0.28
0.0011
0.0018
0.0018
0.0021
0.19
0.0007
0.0014
0.0014
0.0337
0.27
0.0011
0.0326
0.0326
0.0028
0.20
0.0008
0.0021
0.0021
0.0038
0.13
0.0005
0.0033
0.0033
0.0037
0.25
0.0010
0.0027
0.0027
0.0020
0.16
0.0006
0.0014
0.0014
0.0095
ND
ND
0.0095
0.0095
0.0018
0.14
0.0005
0.0013
0.0013
0.0019
0.14
0.0005
0.0014
0.0014
0.0021
0.18
0.0007
0.0014
0.0014
ND
ND
ND
ND
ND
0.0019
0.09
0.0004
0.0015
0.0015
0.0035
0.26
0.0010
0.0025
0.0025
continued
-------
Table F-2A. (continued)
Compound
CAS No.
Residence
Chamber
V=3.900L
Ug/m3
2-methylheptane
592-27-8
0.37
3-methylheptane
589-81-1
0.38
1-octene
111-66-0
ND
/7-octanc
111-65-9
0.77
ethylbenzene
100-41-4
0.36
«7-xylcnc//>xylcnc
108-38-3/106-42-3
0.67
styrene
100-42-5
ND
o-xylene
95-47-6
1.40
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
0.51
isopropylbenzene
98-82-8
0.35
alpha-pinene
80-56-8
ND
«-propylbcnzcnc
103-65-1
ND
m-cthyltolucnc
620-14-4
0.33
/;-cthyltolucnc
622-96-8
0.38
1,3,5 -trimethy lbenzene
108-67-8
ND
o-ethyltoluene
611-14-3
0.39
beta-pinene
127-91-3
ND
1,2,4-trimethylbenzene
95-63-6
0.36
1-decene
872-05-9
ND
/7-dccanc
124-18-5
0.63
1,2,3-trimethylbenzene
526-73-8
ND
m-dicthylbcnzcnc
141-93-5
ND
/;-dicthylbcnzcnc
105-05-5
ND
Dilution
No Negsc
Residence
Air
Dilution
SNMOC
SNMOC
Chamber
V=3.900L
Air
RC-DAb
RC-DA
US
Ug/m3
US
US
US
0.0014
0.12
0.0005
0.0010
0.0010
0.0015
0.09
0.0004
0.0011
0.0011
ND
ND
ND
ND
ND
0.0030
0.14
0.0005
0.0025
0.0025
0.0014
0.08
0.0003
0.0011
0.0011
0.0026
0.14
0.0005
0.0021
0.0021
ND
ND
ND
ND
ND
0.0055
ND
ND
0.0055
0.0055
ND
ND
ND
ND
ND
0.0020
0.10
0.0004
0.0016
0.0016
0.0014
0.11
0.0004
0.0009
0.0009
ND
ND
ND
ND
ND
ND
0.08
0.0003
-0.0003
ND
0.0013
0.16
0.0006
0.0007
0.0007
0.0015
0.09
0.0004
0.0011
0.0011
ND
ND
ND
ND
ND
0.0015
ND
ND
0.0015
0.0015
ND
ND
ND
ND
ND
0.0014
0.13
0.0005
0.0009
0.0009
ND
ND
ND
ND
ND
0.0025
0.21
0.0008
0.0016
0.0016
ND
0.09
0.0004
-0.0004
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
continued
-------
Table F-2A. (concluded)
Residence
Chamber
V=3.900L
Compound CAS No. Ug/m3
1-undecene 821-95-4 ND
«-undecane 1120-21-4 0.50
1-dodecene 112-41-4 ND
«-dodecane 112-40-3 1.21
1-tridecene 2437-56-1 ND
«-tridecane 629-50-5 ND
Total Speciated 68.61
Total Unspeciated 10.70
Total (Speciated + Unspeciated)6 79.31
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber: DA = dilution air.
c Compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
Residence
Chamber
US
Dilution
Air
V=3.900L
Ug/m3
Dilution
Air
US
SNMOC
RC-DAb
US
No Negsc
SNMOC
RC-DA
US
ND
ND
ND
ND
ND
0.0020
0.47
0.0018
0.0001
0.0001
ND
ND
ND
ND
ND
0.0047
0.98
0.0038
0.0009
0.0009
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.2676
0.0417
0.3093
23.44
14.15
37.59
0.0914
0.0552
0.1466
0.1762
-0.0135
0.1627
0.1768
0.1768
-------
Table F-2B. SNMOCsafrom Hogged Fuel Boiler #2 Collected in Canisters on 11/28/01
Residence
Dilution
No Negsc
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
V=3/900L
Chamber
V=30900L
Air
RC-DAb
RC-DA
Compound
CAS No.
Ug/m3
US
Ug/m3
Ug
Ug
Ug
ethylene
74-85-1
1.67
0.0065
0.89
0.0035
0.0030
0.0030
acetylene
74-86-2
0.88
0.0034
0.48
0.0019
0.0016
0.0016
ethane
74-84-0
2.45
0.0096
1.85
0.0072
0.0023
0.0023
propylene
115-07-01
1.88
0.0073
1.23
0.0048
0.0025
0.0025
propane
74-98-6
8.66
0.0338
8.18
0.0319
0.0019
0.0019
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
0.48
0.0019
0.30
0.0012
0.0007
0.0007
isobutene/1 -butene
115-11-7/106-98-0
0.91
0.0035
0.29
0.0011
0.0024
0.0024
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.96
0.0037
0.42
0.0016
0.0021
0.0021
fra«s-2-butene
624-64-6
0.39
0.0015
0.17
0.0007
0.0009
0.0009
cy.v-2-butcnc
590-18-1
0.62
0.0024
0.19
0.0007
0.0017
0.0017
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
ND
ND
0.26
0.0010
-0.0010
ND
1-pentene
109-67-1
0.58
0.0023
0.10
0.0004
0.0019
0.0019
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
0.73
0.0028
0.17
0.0007
0.0022
0.0022
isoprene
78-79-4
ND
ND
0.11
0.0004
-0.0004
ND
fra«s-2-pentene
646-04-8
0.46
0.0018
0.15
0.0006
0.0012
0.0012
cy.v-2-pcntcnc
627-20-3
0.51
0.0020
0.17
0.0007
0.0013
0.0013
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.14
0.0044
0.21
0.0008
0.0036
0.0036
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
continued
-------
Table F-2B. (continued)
Compound
CAS No.
Residence
Chamber
V=3/900L
Ug/m3
cyclopentane
287-92-3
0.46
2,3 -dimethy lbutane
79-29-8
0.97
2-methylpentane
107-83-5
10.41
3-methylpentane
96-14-0
9.17
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
1.19
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
ND
/ram-2-hcxcnc
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
53.42
2,4-dimethylpentane
108-08-7
0.66
benzene
71-43-2
10.90
cyclohexane
110-82-7
0.68
2-methylhexane
591-76-4
0.45
2,3 -dimethy lpentane
565-59-3
1.15
3-methylhexane
589-34-4
0.45
1-heptene
592-76-7
ND
2,2,4-trimethylpentane
540-84-1
ND
^-heptane
142-82-5
0.62
methylcyclohexane
108-87-2
0.62
2,2,3-trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.42
toluene
108-88-3
0.72
Dilution
No Negsc
Residence
Air
Dilution
SNMOC
SNMOC
Chamber
V=30900L
Air
RC-DAb
RC-DA
US
Ug/m3
US
US
US
0.0018
0.12
0.0005
0.0013
0.0013
0.0038
0.26
0.0010
0.0028
0.0028
0.0406
0.36
0.0014
0.0392
0.0392
0.0358
0.24
0.0009
0.0348
0.0348
ND
ND
ND
ND
ND
0.0046
0.27
0.0011
0.0036
0.0036
ND
ND
ND
ND
ND
1.4612
2.60
0.0101
-0.0104
NDe
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.2083
0.50
0.0020
0.2064
0.2064
0.0026
0.15
0.0006
0.0020
0.0020
0.0425
0.24
0.0009
0.0416
0.0416
0.0027
0.20
0.0008
0.0019
0.0019
0.0018
0.24
0.0009
0.0008
0.0008
0.0045
0.31
0.0012
0.0033
0.0033
0.0018
0.14
0.0005
0.0012
0.0012
ND
ND
ND
ND
ND
ND
0.18
0.0007
-0.0007
ND
0.0024
0.12
0.0005
0.0020
0.0020
0.0024
0.16
0.0006
0.0018
0.0018
ND
ND
ND
ND
ND
0.0016
0.11
0.0004
0.0012
0.0012
0.0028
0.26
0.0010
0.0018
0.0018
continued
-------
Table F-2B. (continued)
Compound
CAS No.
Residence
Chamber
V=3/900L
Ug/m3
2-methylheptane
592-27-8
0.42
3-methylheptane
589-81-1
0.51
1-octene
111-66-0
ND
/7-octanc
111-65-9
0.79
ethylbenzene
100-41-4
0.37
«7-xylcnc//>xylcnc
108-38-3/106-42-3
0.74
styrene
100-42-5
ND
o-xylene
95-47-6
1.62
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
0.69
isopropylbenzene
98-82-8
0.55
alpha-pinene
80-56-8
ND
«-propylbcnzcnc
103-65-1
0.33
m-cthyltolucnc
620-14-4
0.35
/;-cthyltolucnc
622-96-8
0.34
1,3,5 -trimethy lbenzene
108-67-8
ND
o-ethyltoluene
611-14-3
ND
beta-pinene
127-91-3
ND
1,2,4-trimethylbenzene
95-63-6
0.40
1-decene
872-05-9
ND
/7-dccanc
124-18-5
0.55
1,2,3 -trimethy lbenzene
526-73-8
ND
m-dicthylbcnzcnc
141-93-5
ND
/;-diethylbenzene
105-05-5
ND
Dilution
No Negsc
Residence
Air
Dilution
SNMOC
SNMOC
Chamber
V=30900L
Air
RC-DAb
RC-DA
US
Ug/m3
US
US
US
0.0016
0.11
0.0004
0.0012
0.0012
0.0020
0.10
0.0004
0.0016
0.0016
ND
ND
ND
ND
ND
0.0031
0.15
0.0006
0.0025
0.0025
0.0014
0.08
0.0003
0.0011
0.0011
0.0003
ND
ND
0.0029
0.0029
ND
ND
ND
ND
ND
0.0063
0.08
0.0003
0.0060
0.0060
ND
ND
ND
ND
ND
0.0027
0.00
ND
0.0027
0.0027
0.0021
0.09
0.0004
0.0018
0.0018
ND
ND
ND
ND
ND
0.0013
0.09
0.0004
0.0009
0.0009
0.0014
0.13
0.0005
0.0009
0.0009
0.0013
0.10
0.0004
0.0009
0.0009
ND
ND
ND
ND
ND
ND
0.08
0.0003
-0.0003
ND
ND
ND
ND
ND
ND
0.0016
0.14
0.0005
0.0010
0.0010
ND
ND
ND
ND
ND
0.0021
0.14
0.0005
0.0016
0.0016
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
continued
-------
Table F-2B. (concluded)
Compound
CAS No.
Residence
Chamber
V=3/900L
Ug/m3
Residence
Chamber
US
Dilution
Air
V=30900L
Ug/m3
Dilution
Air
US
SNMOC
RC-DAb
US
No Negsc
SNMOC
RC-DA
US
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
0.56
0.0022
0.22
0.0009
0.0013
0.0013
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
«-dodccanc
112-40-3
0.30
0.0012
0.28
0.0011
7.8* 10~5
7.8* 10~5
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
«-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated 123.13 0.4802 23.42 0.0913 0.3889 1.8525
Total Unspeciated 37.98 0.1481 3.52 0.0137 0.1344 0.1344
Total (Speciated + Unspeciated)f 161.11 0.6283 26.94 0.1051 0.5233 1.9869
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber: DA = dilution air.
c Compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e w-hexane on 11/28/01 is considered an artifact from denuder solvent; a value of zero is used in calculations.
f Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
-------
Table F-2C. SNMOCsafrom Hogged Fuel Boiler #2 Collected in Canisters on 11/29/01
Residence
Dilution
No Negsc
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
V=3.900L
Chamber
V=3.900L
Air
RC-DAb
RC-DA
Compound
CAS No.
Ug/m3
US
Ug/m3
Ug
Ug
Ug
ethylene
74-85-1
1.41
0.0055
0.68
0.0027
0.0028
0.0028
acetylene
74-86-2
0.95
0.0037
0.35
0.0014
0.0023
0.0023
ethane
74-84-0
2.07
0.0081
1.49
0.0058
0.0023
0.0023
propylene
115-07-01
1.01
0.0039
0.50
0.0020
0.0020
0.0020
propane
74-98-6
5.23
0.0204
4.61
0.0180
0.0024
0.0024
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
0.53
0.0021
0.25
0.0010
0.0011
0.0011
isobutene/1 -butene
115-11-7/106-98-0
0.97
0.0038
0.32
0.0012
0.0025
0.0025
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
1.08
0.0042
0.42
0.0016
0.0026
0.0026
fra«s-2-butene
624-64-6
0.43
0.0017
0.16
0.0006
0.0011
0.0011
cy.v-2-butcnc
590-18-1
0.62
0.0024
0.23
0.0009
0.0015
0.0015
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.92
0.0036
0.28
0.0011
0.0025
0.0025
1-pentene
109-67-1
0.52
0.0020
0.13
0.0005
0.0015
0.0015
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
0.52
0.0020
0.18
0.0007
0.0013
0.0013
isoprene
78-79-4
ND
ND
0.14
0.0005
-0.0006
ND
fra«s-2-pentene
646-04-8
0.49
0.0019
0.13
0.0005
0.0014
0.0014
cy.v-2-pcntcnc
627-20-3
0.62
0.0024
0.16
0.0006
0.0018
0.0018
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
2.17
0.0085
0.21
0.0008
0.0076
0.0076
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
continued
-------
Table F-2C. (continued)
Compound
CAS No.
Residence
Chamber
V=3.900L
Ug/m3
cyclopentane
287-92-3
0.50
2,3 -dimethy lbutane
79-29-8
0.95
2-methylpentane
107-83-5
7.63
3-methylpentane
96-14-0
0.88
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
0.85
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
5.12
/ram-2-hcxcnc
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
1.14
2,4-dimethylpentane
108-08-7
0.77
benzene
71-43-2
9.27
cyclohexane
110-82-7
0.82
2-methylhexane
591-76-4
0.97
2,3 -dimethy lpentane
565-59-3
1.19
3-methylhexane
589-34-4
0.63
1-heptene
592-76-7
ND
2,2,4-trimethylpentane
540-84-1
6.12
^-heptane
142-82-5
0.36
methylcyclohexane
108-87-2
0.54
2,2,3-trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.42
toluene
108-88-3
0.68
Dilution
No Negsc
Residence
Air
Dilution
SNMOC
SNMOC
Chamber
V=3.900L
Air
RC-DAb
RC-DA
US
Ug/m3
US
US
US
0.0020
0.15
0.0006
0.0014
0.0014
0.0037
0.26
0.0010
0.0027
0.0027
0.0298
0.39
0.0015
0.0282
0.0282
0.0034
0.19
0.0007
0.0027
0.0027
ND
ND
ND
ND
ND
0.0033
0.25
0.0010
0.0023
0.0023
ND
ND
ND
ND
ND
0.0200
0.23
0.0009
0.0191
0.0191
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0044
0.17
0.0007
0.0038
0.0038
0.0030
0.17
0.0007
0.0023
0.0023
0.0362
0.14
0.0005
0.0356
0.0356
0.0032
0.21
0.0008
0.0024
0.0024
0.0038
0.15
0.0006
0.0032
0.0032
0.0046
0.28
0.0011
0.0035
0.0035
0.0025
0.22
0.0009
0.0016
0.0016
ND
ND
ND
ND
ND
0.0239
0.17
0.0007
0.0232
0.0232
0.0014
0.10
0.0004
0.0010
0.0010
0.0021
0.19
0.0007
0.0014
0.0014
ND
ND
ND
ND
ND
0.0016
0.12
0.0005
0.0012
0.0012
0.0027
0.23
0.0009
0.0018
0.0018
continued
-------
Table F-2C. (continued)
Compound
CAS No.
Residence
Chamber
V=3.900L
Ug/m3
2-methylheptane
592-27-8
0.37
3-methylheptane
589-81-1
0.44
1-octene
111-66-0
0
/7-octanc
111-65-9
0.71
ethylbenzene
100-41-4
ND
«7-xylcnc//>xylcnc
108-38-3/106-42-3
0.44
styrene
100-42-5
0.00
o-xylene
95-47-6
1.51
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
0.54
isopropylbenzene
98-82-8
0.45
alpha-pinene
80-56-8
ND
«-propylbcnzcnc
103-65-1
0.43
m-cthyltolucnc
620-14-4
0.33
/;-cthyltolucnc
622-96-8
0.37
1,3,5 -trimethylbenzene
108-67-8
0.30
o-ethyltoluene
611-14-3
0
beta-pinene
127-91-3
0.00
1,2,4-trimethylbenzene
95-63-6
0.35
1-decene
872-05-9
0
/7-dccanc
124-18-5
0.51
1,2,3 -trimethylbenzene
526-73-8
ND
m-dicthylbcnzcnc
141-93-5
0.00
/;-diethylbenzene
105-05-5
ND
Dilution
No Negsc
Residence
Air
Dilution
SNMOC
SNMOC
Chamber
V=3.900L
Air
RC-DAb
RC-DA
US
Ug/m3
US
US
US
0.0014
0.11
0.0004
0.0010
0.0010
0.0017
0.11
0.0004
0.0013
0.0013
ND
0
ND
ND
ND
0.0028
0.10
0.0004
0.0024
0.0024
ND
0.09
0.0004
-0.0004
ND
0.0017
0.12
0.0005
0.0012
0.0012
ND
0.00
ND
ND
ND
0.0059
0.00
ND
0.0059
0.0059
ND
ND
ND
ND
ND
0.0021
0.00
ND
0.0021
0.0021
0.0018
0.12
0.0005
0.0013
0.0013
ND
ND
ND
ND
ND
0.0017
0.08
0.0003
0.0014
0.0014
0.0013
0.10
0.0004
0.0009
0.0009
0.0014
0.11
0.0004
0.0010
0.0010
0.0012
0.07
0.0003
0.0009
0.0009
ND
0.07
0.0003
-0.0003
ND
ND
0.19
0.0007
-0.0007
ND
0.0014
0.14
0.0005
0.0008
0.0008
ND
0
ND
ND
ND
0.0020
0.22
0.0009
0.0011
0.0011
ND
ND
ND
ND
ND
ND
0.09
0.0004
-0.0004
ND
ND
ND
ND
ND
ND
continued
-------
Table F-2C. (concluded)
Compound
CAS No.
Residence
Chamber
V=3.900L
Ug/m3
1-undecene
821-95-4
ND
/7-undccanc
1120-21-4
0.74
1-dodecene
112-41-4
ND
«-dodccanc
112-40-3
0.45
1-tridecene
2437-56-1
ND
«-tridccanc
629-50-5
ND
Total Speciated 66.32
Total Unspeciated 5.29
Total (Speciated +Unspeciated)e 71.61
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber: DA = dilution air.
c Compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
Residence
Chamber
US
Dilution
Air
V=3.900L
Ug/m3
Dilution
Air
US
SNMOC
RC-DAb
US
No Negsc
SNMOC
RC-DA
US
ND
ND
ND
ND
ND
0.0029
1.20
0.0047
-0.0018
ND
ND
ND
ND
ND
ND
0.0018
1.20
0.0047
-0.0029
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.2586
0.0206
0.2793
17.98
2.96
20.94
0.0701
0.0115
0.0817
0.1885
0.0091
0.1976
0.1955
0.0091
0.2046
-------
Table F-3. Summary of SNMOCs3 Collected in Canisters from Hogged Fuel Boiler #2
on Test 11/27/01 through 11/29/01
No Negsb
No Negs
No Negs
SNMOC
SNMOC
SNMOC
RC-DAC
RC-DA
RC-DA
11/27/01
11/28/01
11/29/01
Compound
CAS No.
Ug
US
US
ethylene
74-85-1
0.0024
0.0030
0.0028
acetylene
74-86-2
0.0016
0.0016
0.0023
ethane
74-84-0
0.0016
0.0023
0.0023
propylene
115-07-1
0.0026
0.0025
0.0020
propane
74-98-6
0.0020
0.0019
0.0024
propyne
74-99-7
NDd
ND
ND
isobutane
75-28-5
0.0011
0.0007
0.0011
isobutene/1 -butene
115-11-7/106-98-0
0.0037
0.0024
0.0025
1,3-butadiene
106-99-0
ND
ND
ND
/7-butane
106-97-8
0.0020
0.0021
0.0026
fra«s-2-butene
624-64-6
0.0012
0.0009
0.0011
cy.v-2-butcnc
590-18-1
0.0019
0.0017
0.0015
3 -methyl-1 -butene
563-45-1
ND
ND
ND
isopentane
78-78-4
0.0022
ND
0.0025
1-pentene
109-67-1
0.0011
0.0019
0.0015
2-methyl-1 -butene
563-46-2
ND
ND
ND
/7-pentane
109-66-0
0.0020
0.0022
0.0013
isoprene
78-79-4
0.0008
ND
ND
fra«s-2-pentene
646-04-8
0.0015
0.0012
0.0014
cy.v-2-pcntcnc
627-20-3
0.0015
0.0013
0.0018
2-methyl-2-butene
513-35-9
ND
ND
ND
2,2-dimethylbutane
75-83-2
0.0035
0.0036
0.0076
cyclopentene
142-29-0
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
cyclopentane
287-92-3
0.0013
0.0013
0.0014
2,3 -dimethy lbutane
79-29-8
0.0026
0.0028
0.0027
2-methylpentane
107-83-5
0.0414
0.0392
0.0282
3-methylpentane
96-14-0
0.0020
0.0348
0.0027
2-methyl-1 -pentene
763-29-1
ND
ND
ND
1-hexene
592-41-6
0.0029
0.0036
0.0023
2-ethyl-l-butene
760-21-4
ND
ND
ND
/7-hexane
110-54-3
0.0086
NDe
0.0191
fra«s-2-hexene
4050-45-7
ND
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
ND
methylcyclopentane
96-37-7
0.0018
0.2064
0.0038
continued
F-18
-------
Table F-3. (continued)
No Negsb
No Negs
No Negs
SNMOC
SNMOC
SNMOC
RC-DAC
RC-DA
RC-DA
11/27/01
11/28/01
11/29/01
Compound
CAS No.
US
US
Ug
2,4-dimethylpentane
108-08-7
0.0014
0.0020
0.0023
benzene
71-43-2
0.0326
0.0416
0.0356
cyclohexane
110-82-7
0.0021
0.0019
0.0024
2-methylhexane
591-76-4
0.0033
0.0008
0.0032
2,3 -dimethylpentane
565-59-3
0.0027
0.0033
0.0035
3-methylhexane
589-34-4
0.0014
0.0012
0.0016
1-heptene
592-76-7
0.0095
ND
ND
2,2,4-trimethylpentane
540-84-1
0.0013
ND
0.0232
/7-heptane
142-82-5
0.0014
0.0020
0.0010
methylcyclohexane
108-87-2
0.0014
0.0018
0.0014
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
0.0015
0.0012
0.0012
toluene
108-88-3
0.0025
0.0018
0.0018
2-methylheptane
592-27-8
0.0010
0.0012
0.0010
3-methylheptane
589-81-1
0.0011
0.0016
0.0013
1-octene
111-66-0
ND
ND
ND
«-octanc
111-65-9
0.0025
0.0025
0.0024
ethylbenzene
100-41-4
0.0011
0.0011
ND
m-xylcnc//>xylcne
108-38-3/106-42-3
0.0021
0.0029
0.0012
styrene
100-42-5
ND
ND
ND
o-xylene
95-47-6
0.0055
0.0060
0.0059
1-nonene
124-11-8
ND
ND
ND
/7-nonane
111-84-2
0.0016
0.0027
0.0021
isopropylbenzene
98-82-8
0.0009
0.0018
0.0013
alpha-pinene
80-56-8
ND
ND
ND
/7-propylbcnzcne
103-65-1
ND
0.0009
0.0014
m-cthyltolucnc
620-14-4
0.0007
0.0009
0.0009
/;-ethvltoluene
622-96-8
0.0011
0.0009
0.0010
1,3,5 -trimethy lbenzene
108-67-8
ND
ND
0.0009
o-ethyltoluene
611-14-3
0.0015
ND
ND
beta-pinene
127-91-3
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.0009
0.0010
0.0008
1-decene
872-05-9
ND
ND
ND
«-decane
124-18-5
0.0016
0.0016
0.0011
1,2,3 -trimethy lbenzene
526-73-8
ND
ND
ND
m-dicthylbcnzcnc
141-93-5
ND
ND
ND
continued
F-19
-------
Table F-3. (concluded)
No Negsb
No Negs
No Negs
SNMOC
SNMOC
SNMOC
RC-DAC
RC-DA
RC-DA
11/27/01
11/28/01
11/29/01
Compound
CAS No.
US
US
Ug
/?-dicthylbcnzcnc
105-05-5
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
«-undccanc
1120-21-4
0.0001
0.0013
ND
1-dodecene
112-41-4
ND
ND
ND
/7-dodccanc
112-40-3
0.0009
7.8xl0"5
ND
1-tridecene
2437-56-1
ND
ND
ND
«-tridccanc
629-50-5
ND
ND
ND
Total Speciated
0.1768
0.4015
0.1955
Total Unspeciated
f
0.1344
0.0091
Total (Speciated + Unspeciated)1
0.1768
0.5359
0.2046
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber: DA = dilution air.
c Compounds for which DA>RC are listed as ND or zero.
d ND = not detected.
e w-hexane on 11/28/01 is considered an artifact from denuder solvent; a value of zero is used in calculations.
f RC-DA is a small negative number; zero is used in the calculations, and the "Total (Speciated + Unspeciated)"
is considered to equal the "Total Speciated" for 11/27/01.
g Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
F-20
-------
Table F-4A. Total SNMOCs3 Collected from Hogged Fuel Boiler #2 on 11/27/01
Residence
RCb
Dilution
DAC
No Negsd
Chamber
Total
Air
Total
SNMOC
SNMOC
V=3.900L
Collected
V=3.900L
Collected
RC-DA
RC-DA
Compound
CAS No.
Ug/m3
US
Ug/m3
Ug
Ug
Ug
ethylene
74-85-1
1.59
656.5655
0.97
391.8404
264.7250
264.7250
acetylene
74-86-2
0.96
396.4169
0.55
222.1776
174.2393
174.2393
ethane
74-84-0
3.72
1536.1154
3.3
1333.0650
203.0501
203.0501
propylene
115-07-1
2.09
863.0326
1.42
573.6220
289.4105
289.4105
propane
74-98-6
7.25
2993.7733
6.73
2718.6450
275.1280
275.1280
propyne
74-99-7
NDe
ND
ND
ND
ND
ND
isobutane
75-28-5
0.73
301.4420
0.46
185.8212
115.6208
115.6208
isobutene/1 -butene
115-11-7/106-98-0
1.24
512.0385
0.28
113.1086
398.9299
398.9299
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
1.01
417.0636
0.50
201.9796
215.0840
215.0840
fra«s-2-butene
624-64-6
0.42
173.4324
0.12
48.4751
124.9573
124.9573
cy.v-2-butcnc
590-18-1
0.65
268.4073
0.17
68.6731
199.7342
199.7342
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.79
326.2181
0.23
92.9106
233.3074
233.3074
1-pentene
109-67-1
0.44
181.6911
0.17
68.6731
113.0180
113.0180
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pcntane
109-66-0
0.73
301.4420
0.23
92.9106
208.5314
208.5314
isoprene
78-79-4
0.33
136.2683
0.13
52.5147
83.7536
83.7536
/ram-2-pentene
646-04-8
0.49
202.3378
0.11
44.4355
157.9023
157.9023
cy.v-2-pcntcnc
627-20-3
0.54
222.9845
0.16
64.6335
158.3510
158.3510
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.13
466.6157
0.22
88.8710
377.7447
377.7447
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
continued
-------
Table F-4A. (continued)
Residence
Chamber
V=3.900L
Compound
CAS No.
Ug/m3
cyclopentane
287-92-3
0.49
2,3 -dimethy lbutane
79-29-8
0.91
2-methylpentane
107-83-5
10.85
3-methylpentane
96-14-0
0.75
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
1
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
3.48
/ram-2-hcxcnc
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
0.75
2,4-dimethylpentane
108-08-7
0.55
benzene
71-43-2
8.63
cyclohexane
110-82-7
0.73
2-methylhexane
591-76-4
0.98
2,3 -dimethy lpentane
565-59-3
0.94
3-methylhexane
589-34-4
0.52
1-heptene
592-76-7
2.44
2,2,4-trimethylpentane
540-84-1
0.47
/7-heptane
142-82-5
0.49
methylcyclohexane
108-87-2
0.54
2,2,3-trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.48
toluene
108-88-3
0.89
RCb
Dilution
DAC
No Negsd
Total
Air
Total
SNMOC
SNMOC
Collected
V=3.900L
Collected
RC-DA
RC-DA
US
Ug/m3
US
US
US
202.3378
0.16
64.6335
137.7043
137.7043
375.7702
0.25
100.9898
274.7804
274.7804
4480.3366
0.23
92.9106
4387.4260
4387.4260
309.7007
0.25
100.9898
208.7109
208.7109
ND
ND
ND
ND
ND
412.9343
0.25
100.9898
311.9445
311.9445
ND
ND
ND
ND
ND
1437.0112
1.27
513.0282
923.9830
923.9830
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
309.7007
0.28
113.1086
196.5921
196.5921
227.1138
0.19
76.7523
150.3616
150.3616
3563.6226
0.27
109.0690
3454.5540
3454.5540
301.4420
0.2
80.7918
220.6502
220.6502
404.6756
0.13
52.5147
352.1609
352.1609
388.1582
0.25
100.9898
287.1684
287.1684
214.7258
0.16
64.6335
150.0923
150.0923
1007.5596
ND
ND
1007.5600
1007.5600
194.0791
0.14
56.5543
137.5248
137.5248
202.3378
0.14
56.5543
145.7835
145.7835
222.9845
0.18
72.7127
150.2718
150.2718
ND
0
ND
ND
ND
198.2084
0.09
36.3563
161.8521
161.8521
367.5115
0.26
105.0294
262.4821
262.4821
continued
-------
Table F-4A. (continued)
Compound
CAS No.
Residence
Chamber
V=3.900L
Ug/m3
2-methylheptane
592-27-8
0.37
3-methylheptane
589-81-1
0.38
1-octene
111-66-0
ND
«-octanc
111-65-9
0.77
ethylbenzene
100-41-4
0.36
«?-xylcnc//>xylcnc
108-38-3/106-42-3
0.67
styrene
100-42-5
ND
o-xylene
95-47-6
1.4
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
0.51
isopropylbenzene
98-82-8
0.35
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
ND
m-cthyltolucnc
620-14-4
0.33
/;-cthyltolucnc
622-96-8
0.38
1,3,5 -trimethy lbenzene
108-67-8
ND
o-ethyltoluene
611-14-3
0.39
beta-pinene
127-91-3
ND
1,2,4-trimethylbenzene
95-63-6
0.36
1-decene
872-05-9
ND
«-dccanc
124-18-5
0.63
1,2,3-trimethylbenzene
526-73-8
ND
m-dicthylbcnzcnc
141-93-5
ND
/;-dicth\ lbcnzcnc
105-05-5
ND
RCb
Dilution
DAC
No Negsd
Total
Air
Total
SNMOC
SNMOC
Collected
V=3.900L
Collected
RC-DA
RC-DA
US
Ug/m3
US
US
US
152.7857
0.12
48.4751
104.3106
104.3106
156.9150
0.09
36.3563
120.5587
120.5587
ND
ND
ND
ND
ND
317.9594
0.14
56.5543
261.4051
261.4051
148.6563
0.08
32.3167
116.3396
116.3396
276.6660
0.14
56.5543
220.1117
220.1117
ND
ND
ND
ND
ND
578.1080
ND
ND
578.1080
578.1080
ND
ND
ND
ND
ND
210.5965
0.1
40.3959
170.2005
170.2005
144.5270
0.11
44.4355
100.0915
100.0915
ND
ND
ND
ND
ND
ND
0.08
32.3167
-32.3167
ND
136.2683
0.16
64.6335
71.6348
71.6348
156.9150
0.09
36.3563
120.5587
120.5587
ND
ND
ND
ND
ND
161.0444
ND
ND
161.0444
161.0444
ND
ND
ND
ND
ND
148.6563
0.13
52.5147
96.1416
96.1416
ND
ND
ND
ND
ND
260.1486
0.21
84.8314
175.3171
175.3171
ND
0.09
36.3563
-36.3563
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
continued
-------
Table F-4A. (concluded)
Residence
RCb
Dilution
DAC
No Negsd
Chamber
Total
Air
Total
SNMOC
SNMOC
V=3.900L
Collected
V=3.900L
Collected
RC-DA
RC-DA
Compound
CAS No.
Ug/m3
US
Ug/m3
US
US
US
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
0.50
206.4671
0.47
189.8608
16.6063
16.6063
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
/7-dodccanc
112-40-3
1.21
499.6504
0.98
395.8800
103.7704
103.7704
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
68.61
28331.4190
23.44
9468.8030
18862.6200
18931.2900
Total Unspeciated
10.70
4418.3965
14.15
5716.0230
-1297.6300
0.0000f
Total (Speciated + Unspeciated)8
79.31
32749.8150
37.59
15184.8300
17564.9900
18931.2900
a SNMOCs = speciated nonmethane organic compounds.
^ b RC = residence chamber.
^ c DA = dilution air.
d Compounds for which DA>RC are listed as ND or zero.
e ND = not detected.
f RC-DA is a negative number; zero is used in the calculations, and the "Total (Speciated + Unspeciated)" is considered to equal the "Total Speciated" for 11/27/01.
g Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
-------
Table F-4B. Total SNMOCs3 Collected from Hogged Fuel Boiler #2 on 11/28/01
Residence
RCb
Dilution
DAC
No Negsd
Chamber
Total
Air
Total
SNMOC
SNMOC
V=3.9L
Collected
V=3.900L
Collected
RC-DA
RC-DA
Compound
CAS No.
Ug/m3
US
Ug/m3
Ug
Ug
Ug
ethylene
74-85-1
1.67
691.6569
0.89
360.6
331.0494
331.0494
acetylene
74-86-2
0.88
364.4659
0.48
194.5
169.9809
169.9809
ethane
74-84-0
2.45
1014.7063
1.85
749.6
265.1287
265.1287
propylene
115-07-1
1.88
778.6318
1.23
498.4
280.2640
280.2640
propane
74-98-6
8.66
3586.6761
8.18
3314.3
272.3278
272.3278
propyne
74-99-7
NDe
ND
ND
ND
ND
ND
isobutane
75-28-5
0.48
198.7996
0.3
121.6
77.2465
77.2465
isobutene/1 -butene
115-11-7/106-98-0
0.9100
376.8909
0.3
117.5013
259.3896
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
0.96
397.5992
0.42
170.2
227.4248
227.4248
fra«s-2-butene
624-64-6
0.39
161.5247
0.17
68.9
92.6446
92.6446
cy.v-2-butcnc
590-18-1
0.62
256.7828
0.19
77.0
179.7992
179.7992
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0
ND
0.26
105.3
-105.3460
ND
1-pentene
109-67-1
0.58
240.2162
0.1
40.5
199.6985
199.6985
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pcntane
109-66-0
0.73
302.3411
0.17
68.9
233.4610
233.4610
isoprene
78-79-4
ND
ND
0.11
44.6
-44.5695
ND
/ram-2-pentene
646-04-8
0.46
190.5163
0.15
60.8
129.7397
129.7397
cy.v-2-pcntcnc
627-20-3
0.51
211.2246
0.17
68.9
142.3445
142.3445
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.14
472.1490
0.21
85.1
387.0619
387.0619
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
continued
-------
Table F-4B. (continued)
Compound
CAS No.
Residence
Chamber
V=3.9L
Ug/m3
cyclopentane
287-92-3
0.46
2,3 -dimethy lbutane
79-29-8
0.97
2-methylpentane
107-83-5
10.41
3-methylpentane
96-14-0
9.17
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
1.19
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
NDf
/ram-2-hcxcnc
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
53.42
2,4-dimethylpentane
108-08-7
0.66
benzene
71-43-2
10.9
cyclohexane
110-82-7
0.68
2-methylhexane
591-76-4
0.45
2,3 -dimethy lpentane
565-59-3
1.15
3-methylhexane
589-34-4
0.45
1-heptene
592-76-7
ND
2,2,4-trimethylpentane
540-84-1
ND
/7-heptane
142-82-5
0.62
methylcyclohexane
108-87-2
0.62
2,2,3-trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
0.42
toluene
108-88-3
0.72
RCb
Dilution
DAC
No Negsd
Total
Air
Total
SNMOC
SNMOC
Collected
V=3.900L
Collected
RC-DA
RC-DA
US
Ug/m3
US
US
US
190.5163
0.12
48.6
141.8950
141.8950
401.7409
0.26
105.3
296.3948
296.3948
4311.4663
0.36
145.9
4165.6026
4165.6026
3797.9007
0.24
97.2
3700.6582
3700.6582
ND
ND
ND
ND
ND
492.8573
0.27
109.4
383.4595
383.4595
ND
ND
ND
ND
ND
NDf
2.6
1053.5
-1053.5000
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
22124.7387
0.5
202.6
21922.1502
21922.1502
273.3494
0.15
60.8
212.5729
212.5729
4514.4076
0.24
97.2
4417.1651
4417.1651
281.6328
0.2
81.0
200.5974
200.5974
186.3746
0.24
97.2
89.1321
89.1321
476.2907
0.31
125.6
350.6858
350.6858
186.3746
0.14
56.7
129.6498
129.6498
ND
ND
ND
ND
ND
ND
0.18
72.9
-72.9319
ND
256.7828
0.12
48.6
208.1616
208.1616
256.7828
0.16
64.8
191.9545
191.9545
ND
ND
ND
ND
ND
173.9496
0.11
44.6
129.3802
129.3802
298.1994
0.26
105.3
192.8534
192.8534
continued
-------
Table F-4B. (continued)
Residence
Chamber
V=3.9L
Compound
CAS No.
Ug/m
2-methylheptane
592-27-8
0.42
3-methylheptane
589-81-1
0.51
1-octene
111-66-0
ND
«-octanc
111-65-9
0.79
ethylbenzene
100-41-4
0.37
«?-xylcnc//>xylcnc
108-38-3/106-42-3
styrene
100-42-5
ND
o-xylene
95-47-6
1.62
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
0.69
isopropylbenzene
98-82-8
0.55
-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.33
m-cthyltolucnc
620-14-4
0.35
/;-cthyltolucnc
622-96-8
0.34
1,3,5trimethylbenzene
108-67-8
ND
o-ethyltoluene
611-14-3
ND
beta-pinene
127-91-3
ND
1,2,4-trimethylbenzene
95-63-6
0.4
1-decene
872-05-9
ND
«-dccanc
124-18-5
0.55
1,2,3 -trimethy lbenzene
526-73-8
ND
m-dicthylbcnzcnc
141-93-5
ND
/;-dicthylbcnzcnc
105-05-5
ND
RCb
Dilution
DAC
No Negsd
Total
Air
Total
SNMOC
SNMOC
Collected
V=3.900L
Collected
RC-DA
RC-DA
US
Ug/m3
US
US
US
173.9496
0.11
44.6
129.3802
129.3802
211.2246
0.10
40.5
170.7069
170.7069
ND
ND
ND
ND
ND
327.1910
0.15
60.8
266.4145
266.4145
153.2414
0.08
32.4
120.8272
120.8272
0.7400
306.4827
ND
ND
306.4827
ND
ND
ND
ND
ND
670.9486
0.08
32.4
638.5345
638.5345
ND
ND
ND
ND
ND
285.7744
0
ND
285.7744
285.7744
227.7912
0.09
36.5
191.3253
191.3253
ND
ND
ND
ND
ND
136.6747
0.09
36.5
100.2088
100.2088
144.9580
0.13
52.7
92.2850
92.2850
140.8164
0.1
40.5
100.2987
100.2987
ND
ND
ND
ND
ND
ND
0.08
32.4
-32.4142
ND
ND
ND
ND
ND
ND
165.6663
0.14
56.7
108.9415
108.9415
ND
ND
ND
ND
ND
227.7912
0.14
56.7
171.0664
171.0664
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
continued
-------
Table F-4B. (concluded)
Residence
RCb
Dilution
DAC
No Negsd
Chamber
Total
Air
Total
SNMOC
SNMOC
V=3.9L
Collected
V=3.900L
Collected
RC-DA
RC-DA
Compound
CAS No.
Ug/m3
US
Ug/m3
US
US
US
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
0.56
231.9329
0.22
89.1
142.7939
142.7939
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
/7-dodccanc
112-40-3
0.3
124.2497
0.28
113.5
10.8002
10.8002
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
123.13
50996.2389
23.42
9489.2
41506.9924
42815.7142
Total Unspeciated
37.98
15730.0183
3.52
1426.2
14303.7951
14303.7951
Total (Speciated + Unspeciated)8
161.11
66726.2571
26.94
10915.5
55810.7875
57119.5093
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber.
'rl c DA = dilution air.
d Compounds for which DA>RC are listed as ND or zero,
oo r
e ND = not detected.
f w-hexane on 11/28/01 is considered an artifact from denuder solvent; a value of zero is used in calculations.
g Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
-------
Table F-4C. Total SNMOCs3 Collected from Hogged Fuel Boiler #2 on 11/29/01
Residence
RCb
Dilution
DAC
No Negsd
Chamber
Total
Air
Total
RC-DA
RC-DA
V=3.900L
Collected
V=3.900L
Collected
SNMOC
SNMOC
Compound
CAS No.
Ug/m3
US
Ug/m3
Ug
Ug
Ug
ethylene
74-85-1
1.41
585.5608
0.68
278.3320
307.2290
307.2287
acetylene
74-86-2
0.95
394.5268
0.35
143.2590
251.2680
251.2676
ethane
74-84-0
2.07
859.6531
1.49
609.8750
249.7780
249.7782
propylene
115-07-1
1.01
419.4443
0.50
204.6560
214.7880
214.7883
propane
74-98-6
5.23
2171.9737
4.61
1886.9300
285.0460
285.0455
propyne
74-99-7
NDe
ND
ND
ND
ND
ND
isobutane
75-28-5
0.53
220.1044
0.25
102.3280
117.7760
117.7764
isobutene/1 -butene
115-11-7/106-98-0
0.9700
402.8326
0.3200
130.9800
271.8528
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
1.08
448.5147
0.42
171.9110
276.6040
276.6036
fra«s-2-butene
624-64-6
0.43
178.5753
0.16
65.4899
113.0850
113.0854
cy.v-2-butcnc
590-18-1
0.62
257.4806
0.23
94.1418
163.3390
163.3389
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
0.92
382.0680
0.28
114.6070
267.4610
267.4607
1-pentene
109-67-1
0.52
215.9515
0.13
53.2106
162.7410
162.7409
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pcntane
109-66-0
0.52
215.9515
0.18
73.6762
142.2750
142.2753
isoprene
78-79-4
0
ND
0.14
57.3037
-57.3037
ND
/ram-2-pentene
646-04-8
0.49
203.4928
0.13
53.2106
150.2820
150.2822
cy.v-2-pcntcnc
627-20-3
0.62
257.4806
0.16
65.4899
191.9910
191.9907
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
2.17
901.1822
0.21
85.9555
815.2270
815.2267
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
continued
-------
Table F-4C. (continued)
Compound
CAS No.
Residence
Chamber
V=3.900L
Ug/m3
cyclopentane
287-92-3
0.5
2,3 -dimethy lbutane
79-29-8
0.95
2-methylpentane
107-83-5
7.63
3-methylpentane
96-14-0
0.88
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
0.85
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
5.12
/ram-2-hcxcnc
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
1.14
2,4-dimethylpentane
108-08-7
0.77
benzene
71-43-2
9.27
cyclohexane
110-82-7
0.82
2-methylhexane
591-76-4
0.97
2,3 -dimethy lpentane
565-59-3
1.19
3-methylhexane
589-34-4
0.63
1-heptene
592-76-7
ND
2,2,4-trimethylpentane
540-84-1
6.12
2,3,4-trimethylpentane
565-75-3
0.42
toluene
108-88-3
0.68
2-methylheptane
592-27-8
0.37
3-methylheptane
589-81-1
0.44
1-octene
111-66-0
ND
RCb
Dilution
DAC
No Negsd
Total
Air
Total
RC-DA
RC-DA
Collected
V=3.900L
Collected
SNMOC
SNMOC
US
Ug/m3
US
US
US
207.6457
0.15
61.3968
146.2490
146.2489
394.5268
0.26
106.4210
288.1060
288.1057
3168.6730
0.39
159.6320
3009.0400
3009.0410
365.4564
0.19
77.7693
287.6870
287.6871
ND
ND
ND
ND
ND
352.9976
0.25
102.3280
250.6700
250.6696
ND
ND
ND
ND
ND
2126.2917
0.23
94.1418
2032.1500
2032.1500
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
473.4321
0.17
69.5830
403.8490
403.8491
319.7743
0.17
69.5830
250.1910
250.1913
3849.7508
0.14
57.3037
3792.4500
3792.4470
340.5389
0.21
85.9555
254.5830
254.5834
402.8326
0.15
61.3968
341.4360
341.4358
494.1967
0.28
114.6070
379.5890
379.5893
261.6335
0.22
90.0486
171.5850
171.5849
ND
ND
ND
ND
ND
2541.5830
0.17
69.5830
2472.0000
2472.0000
174.4224
0.12
49.1174
125.3050
125.3049
282.3981
0.23
94.1418
188.2560
188.2564
153.6578
0.11
45.0243
108.6330
108.6335
182.7282
0.11
45.0243
137.7040
137.7039
ND
ND
ND
ND
ND
continued
-------
Table F-4C. (continued)
Residence
Chamber
V=3.900L
Compound
CAS No.
Ug/m
/7-octanc
111-65-9
0.71
ethylbenzene
100-41-4
ND
«?-xylcnc//?-xylcnc
108-38-3/106-42-3
styrene
100-42-5
ND
o-xylene
95-47-6
1.51
1-nonene
124-11-8
ND
«-nonanc
111-84-2
0.54
isopropylbenzene
98-82-8
0.45
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
0.43
/77-cthyltolucnc
620-14-4
0.33
/;-cthyltolucnc
622-96-8
0.37
1,3,5 -trimethylbenzene
108-67-8
0.3
o-ethyltoluene
611-14-3
ND
beta-pinene
127-91-3
ND
1,2,4-trimethylbenzene
95-63-6
0.35
1-decene
872-05-9
ND
/7-dccanc
124-18-5
0.51
1,2,3 -trimethylbenzene
526-73-8
ND
m-dicthylbcnzcnc
141-93-5
ND
/;-dicthylbcnzcnc
105-05-5
ND
1-undecene
821-95-4
ND
«-undccanc
1120-21-4
0.74
1-dodecene
112-41-4
ND
RCb
Dilution
DAC
No Negsd
Total
Air
Total
RC-DA
RC-DA
Collected
V=3.900L
Collected
SNMOC
SNMOC
US
Ug/m3
US
US
US
294.8569
0.1
40.9312
253.9260
253.9257
ND
0.09
36.8381
-36.8381
ND
0.4400
182.7282
0.1200
49.1174
133.6108
ND
ND
ND
ND
ND
627.0899
ND
ND
627.0900
627.0899
ND
ND
ND
ND
ND
224.2573
ND
ND
224.2570
224.2573
186.8811
0.12
49.1174
137.7640
137.7637
ND
ND
ND
ND
ND
178.5753
0.08
32.7450
145.8300
145.8303
137.0461
0.1
40.9312
96.1149
96.1150
153.6578
0.11
45.0243
108.6330
108.6335
124.5874
0.07
28.6518
95.9356
95.9356
ND
0.07
28.6518
-28.6518
ND
ND
0.19
77.7693
-77.7693
ND
145.3520
0.14
57.3037
88.0483
88.0483
ND
ND
ND
ND
ND
211.7986
0.22
90.0486
121.7500
121.7500
ND
ND
ND
ND
ND
ND
0.09
36.8381
-36.8381
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
307.3156
1.2
491.1740
-183.8590
ND
ND
ND
ND
ND
ND
continued
-------
Table F-4C. (concluded)
Residence
Chamber
V=3.900L
Compound CAS No. Ug/m3
«-dodecane 112-40-3 0.45
1-tridecene 2437-56-1 ND
«-tridecane 629-50-5 ND
Total Speciated 66.32
Total Unspeciated 5.29
Total (Speciated + Unspeciated)f 71.61
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber.
c DA = dilution air.
d Compounds for which DA>RC are listed as ND or zero.
e ND = not detected.
^ f Total NMOC with unknowns in |ig/m3 is an estimate based on propane only,
to
RCb
Dilution
DAC
No Negsd
Total
Air
Total
RC-DA
RC-DA
Collected
V=3.900L
Collected
SNMOC
SNMOC
US
Ug/m3
US
US
US
186.8811
1.2
491.1740
-304.2930
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
27542.1220
2196.8912
29739.0132
17.98
2.96
20.94
7359.4300 20182.7000 20908.2500
1211.5600 985.328 985.3278
8570.9900 21168 21893.57
-------
Table F-5A. SNMOC Values for 11/27/01 in SPECIATE Format
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
US
US
Total
as % Total
ethylene
74-85-1
264.7250
10.5008
1.3983
0.0555
acetylene
74-86-2
174.2393
9.6931
0.9204
0.0512
ethane
74-84-0
203.0501
8.7956
1.0726
0.0465
propylene
115-07-1
289.4105
5.5645
1.5287
0.0294
propane
74-98-6
275.1280
9.8726
1.4533
0.0521
propyne
74-99-7
NDC
8.9751
ND
ND
isobutane
75-28-5
115.6208
5.0260
0.6107
0.0265
isobutene/1 -butene
115-11-7/106-98-0
398.9299
3.2310
2.1073
0.0171
1,3-butadiene
106-99-0
ND
4.7568
ND
ND
/7-butane
106-97-8
215.0840
9.0648
1.1361
0.0479
fra«s-2-butene
624-64-6
124.9573
5.8338
0.6601
0.0308
cy.v-2-butcnc
590-18-1
199.7342
8.7058
1.0550
0.0460
3 -methyl-1 -butene
563-45-1
ND
12.6548
ND
ND
isopentane
78-78-4
233.3074
13.0138
1.2324
0.0687
1-pentene
109-67-1
113.0180
7.2698
0.5970
0.0384
2-methyl-1 -butene
563-46-2
ND
7.2698
ND
ND
/7-pentane
109-66-0
208.5314
9.0648
1.1015
0.0479
isoprene
78-79-4
83.7536
1.0770
0.4424
ND
/ram-2-pentene
646-04-8
157.9023
7.3596
0.8341
ND
cy.v-2-pcntcnc
627-20-3
158.3510
10.8598
0.8365
0.0574
2-methyl-2-butene
513-35-9
ND
10.5008
ND
ND
2,2-dimethylbutane
75-83-2
377.7447
13.2831
1.9953
0.0702
cyclopentene
142-29-0
ND
12.5651
ND
ND
4-methyl-1 -pentene
691-37-2
ND
12.9241
ND
ND
cyclopentane
287-92-3
137.7043
6.1928
0.7274
0.0327
2,3 -dimethylbutane
79-29-8
274.7804
15.3474
1.4515
ND
2-methylpentane
107-83-5
4387.4260
7.0903
23.1755
0.0375
3-methylpentane
96-14-0
208.7109
13.5523
1.1025
0.0716
2-methyl-1 -pentene
763-29-1
ND
13.5523
ND
ND
1-hexene
592-41-6
311.9445
13.7318
1.6478
0.0725
2-ethyl-l-butene
760-21-4
ND
13.4626
ND
ND
/7-hexane
110-54-3
923.9830
10.4111
4.8807
0.0550
fra«s-2-hexene
4050-45-7
ND
10.4111
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
10.4111
ND
ND
methylcyclopentane
96-37-7
196.5921
8.6161
1.0385
0.0455
2,4-dimethylpentane
108-08-7
150.3616
10.7701
0.7942
0.0569
benzene
71-43-2
3454.5540
6.8210
18.2479
0.0360
cyclohexane
110-82-7
220.6502
15.2576
1.1655
ND
continued
F-33
-------
Table F-5A. (continued)
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
U2
U2
Total
as % Total
2-methylhexane
591-76-4
352.1609
1.7950
1.8602
0.0095
2,3 -dimethylpentane
565-59-3
287.1684
8.9751
1.5169
0.0474
3-methylhexane
589-34-4
150.0923
7.5391
0.7928
ND
1-heptene
592-76-7
1007.5600
7.4493
5.3222
ND
2,2,4-trimethylpentane
540-84-1
137.5248
9.0648
0.7264
0.0479
«-hcptanc
142-82-5
145.7835
4.5773
0.7701
0.0242
methylcyclohexane
108-87-2
150.2718
8.7058
0.7938
0.0460
2,2,3-trimethylpentane
564-02-3
ND
9.0648
ND
ND
2,3,4-trimethylpentane
565-75-3
161.8521
6.2825
0.8549
0.0332
toluene
108-88-3
262.4821
3.5900
1.3865
0.0190
2-methylheptane
592-27-8
104.3106
3.5003
0.5510
ND
3-methylheptane
589-81-1
120.5587
3.4105
0.6368
0.0180
1-octene
111-66-0
ND
3.3208
ND
ND
«-octanc
111-65-9
261.4051
1.7950
1.3808
0.0095
ethylbenzene
100-41-4
116.3396
2.4233
0.6145
ND
«7-xylcnc//;-xylcnc
108-38-3/106-42-3
220.1117
3.7695
1.1627
ND
styrene
100-42-5
ND
6.1928
ND
ND
o-xylene
95-47-6
578.1080
2.4233
3.0537
0.0128
1-nonene
124-11-8
ND
1.8848
ND
ND
/7-nonanc
111-84-2
170.2005
1.8848
0.8990
0.0100
isopropylbenzene
98-82-8
100.0915
3.5900
0.5287
ND
alpha-pinene
80-56-8
ND
1.8848
ND
ND
/7-propylbcnzcnc
103-65-1
ND
1.7950
ND
ND
m-cthyltolucnc
620-14-4
71.6348
4.1285
0.3784
0.0218
/;-cthy ltolucnc
622-96-8
120.5587
4.7568
0.6368
0.0251
1,3,5 -trimethy lbenzene
108-67-8
ND
2.6028
ND
ND
o-ethyltoluene
611-14-3
161.0444
2.7823
0.8507
0.0147
beta-pinene
127-91-3
ND
1.8848
ND
ND
1,2,4-trimethylbenzene
95-63-6
96.1416
2.6028
0.5078
0.0137
1-decene
872-05-9
ND
1.9745
ND
ND
/7-dccanc
124-18-5
175.3171
1.9745
0.9261
ND
1,2,3 -trimethy lbenzene
526-73-8
ND
2.1540
ND
ND
/77-dicthylbcnzcne
141-93-5
ND
1.1668
ND
ND
/?-dicthy lbenzene
105-05-5
ND
1.3463
ND
ND
1-undecene
821-95-4
ND
1.7053
ND
ND
/7-undccanc
1120-21-4
16.6063
1.7053
0.0877
0.0090
1-dodecene
112-41-4
ND
3.7695
ND
ND
«-dodccanc
112-40-3
103.7704
3.8593
0.5481
ND
continued
F-34
-------
Table F-5A. (concluded)
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
U2
U2
Total
as % Total
1-tridecene
2437-56-1
ND
3.7695
ND
ND
/7-tridccanc
629-50-5
ND
3.8593
ND
ND
Total Speciated 18931.2885
Total Unspeciated 0.0000d
Total (Speciated + Unspeciated)6 18931.2885
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c ND = not detected.
d RC-DA is a negative number; zero is used in the calculations, and the "Total (Speciated + Unspeciated)" is considered
to equal the "Total Speciated" for 11/27/01.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
F-35
-------
Table F-5B. SNMOC Values for 11/28/01 in SPECIATE Format
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
US
US
Total
as % Total
ethylene
74-85-1
331.0494
10.5169
0.1567
0.0050
acetylene
74-86-2
169.9809
9.7079
0.0805
0.0046
ethane
74-84-0
265.1287
8.8090
0.1255
0.0042
propylene
115-07-1
280.2640
5.5730
0.1327
0.0026
propane
74-98-6
272.3278
9.8877
0.1289
0.0047
propyne
74-99-7
NDC
8.9888
ND
isobutane
75-28-5
77.2465
5.0337
0.0366
0.0024
isobutene/1 -butene
115-11-7/106-98-0
259.3896
3.2360
0.1228
0.0015
1,3-butadiene
106-99-0
ND
4.7641
ND
/7-butane
106-97-8
227.4248
9.0787
0.1077
0.0043
fra«s-2-butene
624-64-6
92.6446
5.8427
0.0439
0.0028
cy.v-2-butcnc
590-18-1
179.7992
8.7191
0.0851
0.0041
3 -methyl-1 -butene
563-45-1
ND
12.6742
ND
isopentane
78-78-4
ND
13.0337
ND
1-pentene
109-67-1
199.6985
7.2809
0.0945
0.0034
2-methyl-1 -butene
563-46-2
ND
7.2809
ND
/7-pentane
109-66-0
233.4610
9.0787
0.1105
0.0043
isoprene
78-79-4
ND
1.0787
ND
fra«s-2-pentene
646-04-8
129.7397
7.3708
0.0614
cy.v-2-pcntcnc
627-20-3
142.3445
10.8764
0.0674
0.0051
2-methyl-2-butene
513-35-9
ND
10.5169
ND
2,2-dimethylbutane
75-83-2
387.0619
13.3034
0.1832
0.0063
cyclopentene
142-29-0
ND
12.5843
ND
4-methyl-1 -pentene
691-37-2
ND
12.9438
ND
cyclopentane
287-92-3
141.8950
6.2023
0.0672
0.0029
2,3 -dimethy lbutane
79-29-8
296.3948
15.3708
0.1403
0.0073
2-methylpentane
107-83-5
4165.6030
7.1011
1.9721
0.0034
3-methylpentane
96-14-0
3700.6580
13.5731
1.7520
0.0064
2-methyl-1 -pentene
763-29-1
ND
13.5731
ND
1-hexene
592-41-6
383.4595
13.7528
0.1815
0.0065
2-ethyl-l-butene
760-21-4
ND
13.4832
ND
/7-hcxane
110-54-3
NDd
NDd
NDd
fra«s-2-hexene
4050-45-7
ND
10.4270
ND
cv.v-2-hcxcnc
7688-21-3
ND
10.4270
ND
methylcyclopentane
96-37-7
21922.1500
8.6292
10.3786
0.0041
2,4-dimethylpentane
108-08-7
212.5729
10.7865
0.1006
0.0051
benzene
71-43-2
4417.1650
6.8315
2.0912
0.0032
cyclohexane
110-82-7
200.5974
15.2809
0.0950
continued
F-36
-------
Table F-5B. (continued)
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
U2
U2
Total
as % Total
2-methylhexane
591-76-4
89.1321
1.7978
0.0422
0.0009
2,3 -dimethylpentane
565-59-3
350.6858
8.9888
0.1660
0.0043
3-methylhexane
589-34-4
129.6498
7.5506
0.0614
0.0036
1-heptene
592-76-7
ND
7.4607
ND
2,2,4-trimethylpentane
540-84-1
ND
9.0787
ND
/7-hcptanc
142-82-5
208.1616
4.5843
0.0985
0.0022
methylcyclohexane
108-87-2
191.9545
8.7191
0.0909
0.0041
2,2,3-trimethylpentane
564-02-3
ND
9.0787
ND
2,3,4-trimethylpentane
565-75-3
129.3802
6.2921
0.0613
0.0030
toluene
108-88-3
192.8534
3.5955
0.0913
0.0017
2-methylheptane
592-27-8
129.3802
3.5056
0.0613
0.0017
3-methylheptane
589-81-1
170.7069
3.4157
0.0808
0.0016
1-octene
111-66-0
ND
3.3258
ND
/7-octanc
111-65-9
266.4144
1.7978
0.1261
0.0009
ethylbenzene
100-41-4
120.8272
2.4270
0.0572
0.0011
«?-xylcnc//>xylcnc
108-38-3/106-42-3
306.4827
3.7753
0.1451
0.0018
styrene
100-42-5
ND
6.2023
ND
ND
o-xylene
95-47-6
638.5345
2.4270
0.3023
0.0011
1-nonene
124-11-8
ND
1.8876
ND
«-nonanc
111-84-2
285.7744
1.8876
0.1353
0.0009
isopropylbenzene
98-82-8
191.3253
3.5955
0.0906
0.0017
alpha-pinene
80-56-8
ND
1.8876
ND
/7-propylbcnzcnc
103-65-1
100.2088
1.7978
0.0474
0.0009
m-cthyltolucnc
620-14-4
92.2850
4.1348
0.0437
0.0020
/;-cthyltolucnc
622-96-8
100.2987
4.7641
0.0475
0.0023
1,3,5 -trimethy lbenzene
108-67-8
ND
2.6067
ND
o-ethyltoluene
611-14-3
ND
2.7865
ND
beta-pinene
127-91-3
ND
1.8876
ND
ND
1,2,4-trimethylbenzene
95-63-6
108.9415
2.6067
0.0516
0.0012
1-decene
872-05-9
ND
1.9775
ND
/7-dccanc
124-18-5
171.0664
1.9775
0.0810
0.0009
1,2,3 -trimethy lbenzene
526-73-8
ND
2.1573
ND
ND
m-dicthylbcnzcnc
141-93-5
ND
1.1685
ND
ND
/;-dicthylbcnzcnc
105-05-5
ND
1.3483
ND
ND
1-undecene
821-95-4
ND
1.7079
ND
«-undccanc
1120-21-4
142.7939
1.7079
0.0676
0.0008
1-dodecene
112-41-4
ND
3.7753
ND
ND
/7-dodccanc
112-40-3
10.8002
3.8652
0.0051
ND
continued
F-37
-------
Table F-5B. (concluded)
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
U2
U2
Total
as % Total
1-tridecene
2437-56-1
ND
3.7753
ND
«-tridccanc
629-50-5
ND
3.8652
ND
ND
Total Speciated 42815.71
Total Unspeciated 14303.8
Total (Speciated + Unspeciated)6 57119.51
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c ND = not detected.
d w-hexane on 11/28/01 is considered an artifact from denuder solvent; a value of zero is used in calculations.
e Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
F-38
-------
Table F-5C. SNMOC Values for 11/29/01 in SPECIATE Format
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
US
US
Total
as % Total
ethylene
74-85-1
307.2287
10.5522
1.4033
0.0482
acetylene
74-86-2
251.2676
9.7405
1.1477
0.0445
ethane
74-84-0
249.7782
8.8386
1.1409
0.0404
propylene
115-07-1
214.7883
5.5918
0.9811
0.0255
propane
74-98-6
285.0455
9.9209
1.3020
0.0453
propyne
74-99-7
NDC
ND
ND
ND
isobutane
75-28-5
117.7764
5.0506
0.5380
0.0231
isobutene/1 -butene
115-11-7/106-98-0
271.8528
3.2468
1.2417
0.0148
1,3-butadiene
106-99-0
ND
ND
ND
ND
/7-butane
106-97-8
276.6036
9.1092
1.2634
0.0416
fra«s-2-butene
624-64-6
113.0854
5.8623
0.5165
0.0268
cy.v-2-butcnc
590-18-1
163.3389
8.7484
0.7461
0.0400
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
isopentane
78-78-4
267.4607
13.0775
1.2216
0.0597
1-pentene
109-67-1
162.7409
7.3054
0.7433
0.0334
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
/7-pentane
109-66-0
142.2753
9.1092
0.6499
0.0416
isoprene
78-79-4
ND
ND
ND
ND
/ram-2-pentene
646-04-8
150.2822
7.3956
0.6864
ND
cy.v-2-pcntcnc
627-20-3
191.9907
10.9130
0.8769
0.0498
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
815.2267
13.3481
3.7236
0.0610
cyclopentene
142-29-0
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
cyclopentane
287-92-3
146.2489
6.2231
0.6680
0.0284
2,3 -dimethy lbutane
79-29-8
288.1057
15.4225
1.3159
0.0704
2-methylpentane
107-83-5
3009.0410
7.1250
13.7440
0.0325
3-methylpentane
96-14-0
287.6871
13.6187
1.3140
0.0622
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
1-hexene
592-41-6
250.6696
13.7990
1.1449
0.0630
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
/7-hexane
110-54-3
2032.1500
10.4620
9.2819
0.0478
fra«s-2-hexene
4050-45-7
ND
ND
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
ND
ND
methylcyclopentane
96-37-7
403.8491
8.6582
1.8446
0.0395
2,4-dimethylpentane
108-08-7
250.1913
10.8228
1.1428
0.0494
benzene
71-43-2
3792.4470
6.8544
17.3222
0.0313
cyclohexane
110-82-7
254.5834
15.3323
1.1628
0.0700
continued
F-39
-------
Table F-5C. (continued)
SNMOC3
RC-DAb Uncertainty Percent Uncertainty
Compound
CAS No.
U2
U2
Total
as % Total
2-methylhexane
591-76-4
341.4358
1.8038
1.5595
0.0082
2,3 -dimethylpentane
565-59-3
379.5893
9.0190
1.7338
0.0412
3-methylhexane
589-34-4
171.5849
7.5759
0.7837
0.0346
1-heptene
592-76-7
ND
ND
ND
ND
2,2,4-trimethylpentane
540-84-1
2472.0000
9.1092
11.2910
0.0416
«-hcptanc
142-82-5
108.5737
4.5997
0.4959
0.0210
methylcyclohexane
108-87-2
146.4881
8.7484
0.6691
0.0400
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
125.3049
6.3133
0.5723
0.0288
toluene
108-88-3
188.2564
3.6076
0.8599
0.0165
2-methylheptane
592-27-8
108.6335
3.5174
0.4962
0.0161
3-methylheptane
589-81-1
137.7039
3.4272
0.6290
0.0157
1-octene
111-66-0
ND
ND
ND
ND
«-octanc
111-65-9
253.9257
1.8038
1.1598
0.0082
ethylbenzene
100-41-4
ND
ND
ND
ND
«7-xylcnc//;-xylcnc
108-38-3/106-42-3
133.6108
3.7880
0.6103
0.0173
styrene
100-42-5
ND
ND
ND
ND
o-xylene
95-47-6
627.0899
2.4351
2.8643
0.0111
1-nonene
124-11-8
ND
ND
ND
ND
/7-nonanc
111-84-2
224.2573
1.8940
1.0243
0.0087
isopropylbenzene
98-82-8
137.7637
3.6076
0.6292
0.0165
alpha-pinene
80-56-8
ND
ND
ND
ND
/7-propylbcnzcnc
103-65-1
145.8303
1.8038
0.6661
0.0082
m-cthyltolucnc
620-14-4
96.1150
4.1487
0.4390
0.0189
/;-cthyltolucnc
622-96-8
108.6335
4.7801
0.4962
0.0218
1,3,5 -trimethylbenzene
108-67-8
95.9356
2.6155
0.4382
0.0119
o-ethyltoluene
611-14-3
ND
ND
ND
ND
beta-pinene
127-91-3
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
88.0483
2.6155
0.4022
0.0119
1-decene
872-05-9
ND
ND
ND
ND
/7-dccanc
124-18-5
121.7500
1.9842
0.5561
0.0091
1,2,3 -trimethylbenzene
526-73-8
ND
ND
ND
ND
/77-dicthylbcnzcne
141-93-5
ND
ND
ND
ND
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
/7-undccanc
1120-21-4
ND
ND
ND
ND
1-dodecene
112-41-4
ND
ND
ND
ND
«-dodccanc
112-40-3
ND
ND
ND
ND
continued
F-40
-------
Table F-5C. (concluded)
Compound
CAS No.
SNMOC3
RC-DAb
U2
Uncertainty
U2
Percent
Total
Uncertainty
as % Total
1-tridecene
2437-56-1
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
Total Speciated
20908.25
Total Unspeciated
21168.02
Total (Speciated +
Unspeciated)d
42076.27
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber; DA = dilution air.
c ND = not detected.
d Total NMOC with unknowns in |ig/m3 is an estimate based on propane only.
F-41
-------
Table F-6. Summary of SNMOCs3 from Hogged Fuel Boiler #2 for All Test Days as Weight Percent of Total
11/27/01
11/28/01
11/29/01
RC-DAb
Percent
RC-DA
Percent
RC-DA
Percent
Compound
CAS No.
US
Total
US
Total
US
Total
ethylene
74-85-1
264.7250
1.3983
331.0494
0.5796
307.2287
1.4033
acetylene
74-86-2
174.2393
0.9204
169.9809
0.2976
251.2676
1.1477
ethane
74-84-0
203.0501
1.0726
265.1287
0.4642
249.7782
1.1409
propylene
115-07-1
289.4105
1.5287
280.2640
0.4907
214.7883
0.9811
propane
74-98-6
275.1280
1.4533
272.3278
0.4768
285.0455
1.3020
propyne
74-99-7
NDC
ND
ND
ND
ND
ND
isobutane
75-28-5
115.6208
0.6107
77.2465
0.1352
117.7764
0.5380
isobutene/1 -butene
115-11-7/106-98-0
398.9299
2.1073
259.3896
0.4541
271.8528
1.2417
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
215.0840
1.1361
227.4248
0.3982
276.6036
1.2634
/ram-2-butcnc
624-64-6
124.9573
0.6601
92.6446
0.1622
113.0854
0.5165
cy.v-2-butcnc
590-18-1
199.7342
1.0550
179.7992
0.3148
163.3389
0.7461
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
233.3074
1.2324
ND
ND
267.4607
1.2216
1-pentene
109-67-1
113.0180
0.5970
199.6985
0.3496
162.7409
0.7433
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
208.5314
1.1015
233.4610
0.4087
142.2753
0.6499
isoprene
78-79-4
83.7536
0.4424
ND
ND
ND
ND
/ram-2-pentene
646-04-8
157.9023
0.8341
129.7397
0.2271
150.2822
0.6864
cy.v-2-pcntcnc
627-20-3
158.3510
0.8365
142.3445
0.2492
191.9907
0.8769
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
377.7447
1.9953
387.0619
0.6776
815.2267
3.7236
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
cyclopentane
287-92-3
137.7043
0.7274
141.8950
0.2484
146.2489
0.6680
continued
-------
Table F-6. (continued)
11/27/01
RC-DAb
Compound
CAS No.
US
3 -dimethy lbutane
79-29-8
274.7804
2-methylpentane
107-83-5
4387.4260
3-methylpentane
96-14-0
208.7109
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
311.9445
2-ethyl-l-butene
760-21-4
ND
/7-hcxanc
110-54-3
923.9830
/ram-2-hcxcnc
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
196.5921
2,4-dimethylpentane
108-08-7
150.3616
benzene
71-43-2
3454.5540
cyclohexane
110-82-7
220.6502
2-methylhexane
591-76-4
352.1609
2,3 -dimethy lpentane
565-59-3
287.1684
3-methylhexane
589-34-4
150.0923
1-heptene
592-76-7
1007.5600
2,2,4-trimethylpentane
540-84-1
137.5248
/7-heptane
142-82-5
145.7835
methylcyclohexane
108-87-2
150.2718
2,2,3-trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
161.8521
toluene
108-88-3
262.4821
2-methylheptane
592-27-8
104.3106
3-methylheptane
589-81-1
120.5587
11/28/01
11/29/01
Percent
RC-DA
Percent
RC-DA
Percent
Total
US
Total
US
Total
1.4515
296.3948
0.5189
288.1057
1.3159
23.1755
4165.6030
7.2928
3009.0410
13.7440
1.1025
3700.6580
6.4788
287.6871
1.3140
ND
ND
ND
ND
ND
1.6478
383.4595
0.6713
250.6696
1.1449
ND
ND
ND
ND
ND
4.8807
NDd
NDd
2032.1500
9.2819
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1.0385
21922.1500
38.3794
403.8491
1.8446
0.7942
212.5729
0.3722
250.1913
1.1428
18.2479
4417.1650
7.7332
3792.4470
17.3222
1.1655
200.5974
0.3512
254.5834
1.1628
1.8602
89.1321
0.1560
341.4358
1.5600
1.5169
350.6858
0.6140
379.5893
1.7338
0.7928
129.6498
0.2270
171.5849
0.7837
5.3222
ND
ND
ND
ND
0.7264
ND
ND
2472.0000
11.2091
0.7701
208.1616
0.3644
108.5737
0.4959
0.7938
191.9545
0.3361
146.4881
0.6691
ND
ND
ND
ND
ND
0.8549
129.3802
0.2265
125.3049
0.5723
1.3865
192.8534
0.3376
188.2564
0.8599
0.5510
129.3802
0.2265
108.6335
0.4962
0.6368
170.7069
0.2989
137.7039
0.6290
continued
-------
Table F-6. (continued)
11/27/01
RC-DAb
Compound
CAS No.
US
1-octene
111-66-0
ND
/7-octanc
111-65-9
261.4051
ethylbenzene
100-41-4
116.3396
«?-xylcnc//?-xylcnc
108-38-3/106-42-3
220.1117
styrene
100-42-5
ND
o-xylene
95-47-6
578.1080
1-nonene
124-11-8
ND
«-nonanc
111-84-2
170.2005
isopropylbenzene
98-82-8
100.0915
alpha-pinene
80-56-8
ND
/7-propylbcnzcnc
103-65-1
ND
/77-cthyltolucnc
620-14-4
71.6348
/;-cthyltolucnc
622-96-8
120.5587
1,3,5 -trimethylbenzene
108-67-8
ND
o-ethyltoluene
611-14-3
161.0444
beta-pinene
127-91-3
ND
1,2,4-trimethylbenzene
95-63-6
96.1416
1-decene
872-05-9
ND
/7-dccanc
124-18-5
175.3171
1,2,3 -trimethylbenzene
526-73-8
ND
m-dicthylbcnzcnc
141-93-5
ND
/;-dicthylbcnzcnc
105-05-5
ND
1-undecene
821-95-4
ND
«-undccanc
1120-21-4
16.6063
1-dodecene
112-41-4
ND
11/28/01
11/29/01
'ercent
RC-DA
Percent
RC-DA
Percent
Total
US
Total
US
Total
ND
ND
ND
ND
ND
1.3808
266.4144
0.4664
253.9257
1.1598
0.6145
120.8272
0.2115
ND
ND
1.1627
306.4827
0.5366
133.6108
0.6103
ND
ND
ND
ND
ND
3.0537
638.5345
1.1179
627.0899
2.8643
ND
ND
ND
ND
ND
0.8990
285.7744
0.5003
224.2573
1.0243
0.5287
191.3253
0.3350
137.7637
0.6292
ND
ND
ND
ND
ND
ND
100.2088
0.1754
145.8303
0.6661
0.3784
92.2850
0.1616
96.1150
0.4390
0.6368
100.2987
0.1756
108.6335
0.4962
ND
ND
ND
95.9356
0.4382
0.8507
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.5078
108.9415
0.1907
88.0483
0.4022
ND
ND
ND
ND
ND
0.9261
171.0664
0.2995
121.7500
0.5561
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.0877
142.7939
0.2500
ND
ND
ND
ND
ND
ND
ND
continued
-------
Table F-6. (concluded)
Compound
CAS No.
11/27/01
RC-DAb
US
Percent
Total
11/28/01
RC-DA
US
Percent
Total
11/29/01
RC-DA
US
Percent
Total
/7-dodccanc
112-40-3
103.7704
0.5481
10.8002
0.1891
ND
ND
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
18931.29
42815.71
20908.25
Total Unspeciated
0e
14303.8
985.3278
Total (Speciated + Unspeciated)f
18931.29
57119.51
21893.57
a SNMOCs = speciated nonmethane organic compounds.
b RC = residence chamber: DA = dilution air.
c ND = not detected.
d w-hexane on 11/28/01 is considered an artifact from denuder solvent; a value of zero is used in calculations.
e RC-DA is a small negative number; zero is used in the calculations, and the "Total (Speciated + Unspeciated)" is considered to equal the "Total Speciated" for 11/27/01.
f Total NMOC with unknowns in |j.g/m3 is an estimate based on propane only.
-------
Appendix G
Data Tables for Individual Air Toxics Samples
G-l
-------
Contents
Table Page
G-l Air Toxics, Hogged Fuel Boiler #2, Laboratory Blank and Ambient Air G-3
G-2A Air Toxics from Hogged Fuel Boiler #2 on 11/27/01 G-5
G-2B Air Toxics from Hogged Fuel Boiler #2 on 11/28/01 G-l
G-2C Air Toxics from Hogged Fuel Boiler #2 on 11/29/01 G-9
G-3 Summary of Air Toxics from Hogged Fuel Boiler #2 for All Test Days G-l 1
G-2
-------
Table G-1. Air Toxics, Hogged Fuel Boiler #2, Laboratory Blank and Ambient Air
Laboratory Ambient Air
Blank
11/27/01
Compounds
CAS No.
US/m3
US/m3
ethylene
acetylene
74-86-2
NDa
0.39
propylene
115-07-1
ND
ND
dichlorodifluoromethane
75-71-8
ND
2.58
chloromethane
74-87-3
ND
1.80
dichlorotetrafluoroethane
1320-37-2
ND
ND
vinyl chloride
75-01-4
ND
ND
1,3-butadiene
106-99-0
ND
ND
bromomethane
74-83-9
ND
ND
chloroethane
75-00-3
ND
ND
acetonitrile
75-05-8
ND
ND
acetone
67-64-1
ND
ND
trichlorofluoromethane
75-69-4
ND
1.40
acrylonitrile
107-13-1
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
methylene chloride
75-09-2
ND
485.21b
trichlorotrifluoroethane
26523-64-8
ND
0.60
trans-1,2-dichloroethylene
56-60-5
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
chloroprene
126-99-8
ND
ND
cis-1,3 -dichloroethy lene
156-59-2
ND
ND
bromochloromethane
74-97-5
ND
ND
chloroform
67-66-3
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
0.13
benzene
71-43-2
ND
2.24
carbon tetrachloride
56-23-5
ND
0.61
tert-amyl methyl ether
994-05-8
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ethyl acrylate
140-88-5
ND
ND
bromodichloromethane
75-27-4
ND
ND
trichloroethylene
79-01-6
ND
ND
methyl methacrylate
80-62-6
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
continued
G-3
-------
Table G-1. (concluded)
Laboratory Ambient Air
Blank
11/27/01
Compounds
CAS No.
U2/m3
H2/m3
trans-1,2-dichloropropene
10061-02-6
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
toluene
108-88-3
ND
0.74
dibromochloromethane
124-48-1
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
«-octanc
111-65-9
ND
ND
tetrachloroethylene
127-18-4
ND
ND
chlorobenzene
108-90-7
ND
ND
ethylbenzene
100-41-4
ND
0.14
m-, /;-xylene
108-38-3/106-42-3
ND
0.67
bromoform
75-25-2
ND
ND
styrene
100-42-5
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
o-xylene
95-47-6
ND
0.16
1,3,5 -trimethylbenzene
108-67-8
ND
ND
1,2,4-trimethylbenzene
95-63-6
ND
0.20
«7-d i ch 1 o ro be n zc n c
541-73-1
ND
ND
chloromethylbenzene
100-44-7
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
a ND = not detected.
b Methylene chloride in the ambient canister is a contaminant from the denuders. The value is
included as a reference.
G-4
-------
Table G-2A. Air Toxics from Hogged Fuel Boiler #2 on 11/27/01
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA1
Ambient
Compounds
CAS No.
US/m3
US/m3
US/m3
US/m3
acetylene
74-86-2
0.72
0.41
0.31
0.39
propylene
115-07-1
1.59
1.29
0.30
NDb
dichlorodifluoromethane
75-71-8
4.31
4.48
-0.17
2.58
chloromethane
74-87-3
1.56
1.80
-0.24
1.8
dichlorotetrafluoroethane
1320-37-2
ND
ND
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
ND
acetonitrile
75-05-8
ND
ND
ND
ND
acetone
67-64-1
ND
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
0.06
-0.06
1.4
acrylonitrile
107-13-1
ND
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
ND
methylene chloride
75-09-2
65.07
3.48
61.59
485.21°
trichlorotrifluoroethane
26523-64-8
ND
ND
ND
0.6
trans- 1,2-dichloroethylene
56-60-5
ND
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
ND
chloroprene
126-99-8
ND
ND
ND
ND
cis-1,3-dichloroethylene
156-59-2
ND
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
0.13
benzene
71-43-2
9.57
0.22
9.35
2.24
carbon tetrachloride
56-23-5
ND
ND
ND
0.61
tert-amyl methyl ether
994-05-8
ND
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
ND
bromodichloromethane
75-27-4
ND
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
ND
continued
G-5
-------
Table G-2A. (concluded)
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA1
Ambient
Compounds
CAS No.
H2/m3
U2/m3
H2/m3
H2/m3
1,1,2-trichloroethane
79-00-5
ND
ND
ND
ND
toluene
108-88-3
0.77
0.25
0.52
0.74
dibromochloromethane
124-48-1
ND
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
ND
/7-octanc
111-65-9
ND
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ND
ethylbenzene
100-41-4
0.29
0.09
0.20
0.14
m-, /^-xylene
108-38-3/106-42-3
ND
ND
ND
0.67
bromoform
75-25-2
ND
ND
ND
ND
styrene
100-42-5
ND
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
0.16
1,3,5 -trimethy lbenzene
108-67-8
ND
ND
ND
ND
1,2,4-trimethy lbenzene
95-63-6
0.34
0.11
0.23
0.20
m-dichlorobcnzcnc
541-73-1
ND
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
ND
/;-dichlorobcnzcnc
106-46-7
ND
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
ND
ND
a RC = residence chamber: DA = dilution air.
b ND = not detected.
c Methylene chloride in the ambient canister is a contaminant from the denuders. The value is included as a reference.
G-6
-------
Table G-2B. Air Toxics from Hogged Fuel Boiler #2 on 11/28/01
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA1
Compounds
CAS No.
US/m3
US/m3
US/m3
acetylene
74-86-2
0.67
0.37
0.30
propylene
115-07-1
1.22
1.14
0.08
dichlorodifluoromethane
75-71-8
4.34
5.34
-1
chloromethane
74-87-3
1.25
1.59
-0.34
dichlorotetrafluoroethane
1320-37-2
NDb
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
acetonitrile
75-05-8
ND
ND
ND
acetone
67-64-1
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
0.09
-0.09
acrylonitrile
107-13-1
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
methylene chloride
75-09-2
ND
9.18
-9.18
trichlorotrifluoroethane
26523-64-8
ND
ND
ND
trans- 1,2-dichloroethylene
56-60-5
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
chloroprene
126-99-8
ND
ND
ND
cis-1,3-dichloroethylene
156-59-2
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
benzene
71-43-2
11.14
0.20
10.94
carbon tetrachloride
56-23-5
ND
ND
ND
tert-amyl methyl ether
994-05-8
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
bromodichloromethane
75-27-4
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
continued
G-7
-------
Table G-2B. (concluded)
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA1
Compounds
CAS No.
H2/m3
H2/m3
H2/m3
1,1,2-trichloroethane
79-00-5
ND
ND
ND
toluene
108-88-3
0.56
0.18
0.38
dibromochloromethane
124-48-1
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
/7-octanc
111-65-9
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ethylbenzene
100-41-4
0.30
ND
0.3
m-, /^-xylene
108-38-3/106-42-3
ND
ND
ND
bromoform
75-25-2
ND
ND
ND
styrene
100-42-5
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
1,3,5 -trimethy lbenzene
108-67-8
ND
ND
ND
1,2,4-trimethy lbenzene
95-63-6
ND
ND
ND
m-dichlorobcnzcnc
541-73-1
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
/;-dichlorobcnzcnc
106-46-7
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
ND
a RC = residence chamber: DA = dilution air.
b ND = not detected.
G-8
-------
Table G-2C. Air Toxics from Hogged Fuel Boiler #2 on 11/29/01
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA1
Compounds
CAS No.
US/m3
US/m3
US/m3
acetylene
74-86-2
0.75
0.27
0.48
propylene
115-07-1
0.35
0.37
-0.02
dichlorodifluoromethane
75-71-8
4.70
5.46
-0.76
chloromethane
74-87-3
1.33
1.32
0.01
dichlorotetrafluoroethane
1320-37-2
NDb
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
acetonitrile
75-05-8
ND
ND
ND
acetone
67-64-1
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
0.07
-0.07
acrylonitrile
107-13-1
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
methylene chloride
75-09-2
9.78
1.11
8.67
trichlorotrifluoroethane
26523-64-8
ND
ND
ND
trans- 1,2-dichloroethylene
56-60-5
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
chloroprene
126-99-8
ND
ND
ND
cis-1,3-dichloroethylene
156-59-2
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
erthyl tert-butyl ether
637-92-3
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
benzene
71-43-2
9.75
0.16
9.59
carbon tetrachloride
56-23-5
ND
ND
ND
tert-amyl methyl ether
994-05-8
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
bromodichloromethane
75-27-4
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
continued
G-9
-------
Table G-2C. (concluded)
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA1
Compounds
CAS No.
H2/m3
H2/m3
H2/m3
1,1,2-trichloroethane
79-00-5
ND
ND
ND
toluene
108-88-3
0.52
0.19
0.33
dibromochloromethane
124-48-1
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
/7-octanc
111-65-9
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ethylbenzene
100-41-4
0.29
0.07
0.22
m-, /^-xylene
108-38-3/106-42-3
ND
ND
ND
bromoform
75-25-2
ND
ND
ND
styrene
100-42-5
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
1,3,5 -trimethy lbenzene
108-67-8
ND
ND
ND
1,2,4-trimethy lbenzene
95-63-6
ND
ND
ND
m-dichlorobcnzcnc
541-73-1
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
/;-dichlorobcnzcnc
106-46-7
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
1,2,4-trichlorobenzene
120-82-1
ND
ND
ND
hexachloro-1.3 -butadiene
87-68-3
ND
ND
ND
a RC = residence chamber: DA = dilution air.
b ND = not detected.
G-10
-------
Table G-3. Summary of Air Toxics from Hogged Fuel Boiler #2 for All Test Days
Compounds
CAS No.
Ambient
|lg/m3
Air Toxics
RC-DA1
11/27/01
Ug/m3
Air Toxics
RC-DA
11/28/01
Ug/m3
Air Toxics
RC-DA
11/29/01
Ug/m3
acetylene
74-86-2
0.39
0.31
0.30
0.48
propylene
115-07-1
NDb
0.30
0.08
ND
dichlorodifluoromethane
75-71-8
2.58
ND
ND
ND
chloromethane
74-87-3
1.80
ND
ND
0.01
trichlorofluoromethane
75-69-4
1.40
ND
ND
ND
methylene chloride
75-09-2
485.21°
61.59
454.07d
8.67
trichlorotrifluoroethane
26523-64-8
0.60
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
0.13
ND
ND
ND
benzene
71-43-2
2.24
9.35
10.94
9.59
carbon tetrachloride
56-23-5
0.61
ND
ND
ND
1,1,2-trichloroethane
79-00-5
0
0
0
0
toluene
108-88-3
0.74
0.52
0.38
0.33
ethylbenzene
100-41-4
0.14
0.20
0.30
0.22
m-, /^-xylene
108-38-3/106-42-3
0.67
ND
ND
ND
o-xylene
95-47-6
0.16
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.20
0.23
ND
ND
a RC = residence chamber: DA = dilution air.
b ND = not detected.
c Methylene chloride in the ambient canister is a contaminant from the denuders. The value is included as a reference.
d Methylene chloride on 11/28/01 is considered an artifact.
G-ll
-------
Appendix H
Data Tables for Individual PM25 Elemental Samples
H-l
-------
Table H-1. PM25 Elemental Analysis, Hogged Fuel Boiler #2
XRF Elemental Analysis Results (wt.% of PM2 5 Mass) by Sample
Filter ID
T100201T
T100201U
T102201A
T102201B
T102201F
T102201G
IB112701
IB112701
IB112801H
IB112801
IB112901
IB112901
Element
HR2A1
HR2B1
R2A1
HR2A1
HR2A1
HR2B1
Sodium
0.877
0.828
0.957
0.859
0.963
1.03
Magnesium
0.519
0.519
0.494
0.483
0.538
0.534
Aluminum
16.41
16.41
15.71
14.55
15.32
15.43
Silicon
17.84
17.73
17.43
16.06
17
17.21
Phosphorus
0.547
0.558
0.573
0.514
0.678
0.571
Sulfur
3.08
3.08
2.66
2.33
3.02
3
Chlorine
1.03
0.783
0.608
1.11
1.02
1.1
Potassium
6.97
6.83
6.4
5.85
7.27
7.49
Calcium
2.36
2.47
2.46
2.01
2.42
2.46
Titanium
1.59
1.67
1.64
1.51
1.62
1.63
Vanadium
0.094
0.121
0.123
0.107
0.104
0.089
Manganese
0.395
Iron
4.51
4.5
4.54
4.95
4.39
4.57
Cobalt
0.103
Nickel
0.182
0.33
Copper
0.206
0.199
Zinc
0.211
0.325
0.352
0.298
0.247
0.194
Bromine
0.276
0.306
Strontium
0.39
0.43
0.36
H-2
-------
Appendix I
Data Tables for Individual PM25 EC/OC Samples
i-i
-------
Table 1-1. EC/OC Carbon Samples, NIOSH Method 5040, Hogged Fuel Boiler #2
OC/EC data (wt% of PM mass) by Sample
Filter ID
oc
EC
Q05290 IN IB 112701HR4A1
5.8
1.5
Q053001A IB112701HR4B1
7.1
0.8
Q060401J IB112701HR8A1
5.1
1.6
Q060401KIB112701HR8B1
5.5
1.7
Q060401M IB 112701HR10A3
0.5
0.4
q060401N IB112701HR10B3
0.3
0.4
Q060401U IB112801HR4A1
7.0
1.3
Q060401V IB112801HR4B1
6.3
1.4
Q060401S IB112801HR8A1
5.8
2.2
Q060401TIB112801HR8B1
6.0
2.0
Q060401P IB112801HR10A3
1.5
0.7
Q060401Q IB112801HR10B3
1.0
0.9
Q101501E IB112901HR4A1
6.4
2.3
Q10150ID IB112901HR4B1
6.2
2.0
Q101501A IB112901HR8A1
6.8
2.1
Q101501B IB112901HR8B1
6.1
2.1
Q060401X IB112901HR10A3
1.6
1.2
0060401Y IB112901HR10B3
1.2
1.0
1-2
-------
Appendix J
Data Tables for Individual PM25
Inorganic Ion Samples
j-i
-------
Table J-1. Calibration Ranges for PM25 Inorganic Ion Analyses, Hogged Fuel Boiler
Inorganic Ions by Ion Chromatography
Date
11/27/01
-11/28/01
11/29/01
High
Low
High
Low
Cone.
Cone.
Cone.
Cone.
Ion
ppm
ppm
ppm
ppm
Chloride
2.7
1
2.5
0.9
Nitrate
2.8
1
2.65
0.94
Sulfate
3.2
1.1
2.71
1
Ammonium
1.87
0.67
2.2
0.9
Potassium
1.85
0.66
2
0.8
Magnesium
0.68
1.9
2.3
0.95
Calcium
1.8
0.64
2.2
0.91
Table J-2. Inorganic Ion Samples, Hogged Fuel Boiler #2
Ion Chromatography Results (wt. % of PM25 Mass) by Sample
Filter ID
T100201V
T100201W
T100201Y
T100201Z
T102201D
T102201E
IB112701H
IB112701H
IB112801H
IB112801H
IB112901H
IB112901H
Ion
R6A1
R6B1
R6A1
R6B1
R6A1
R6B1
Ammonium
NDa
ND
ND
ND
ND
ND
Potassium
2.36
2.15
2.17
1.85
2.83
2.76
Magnesium
ND
ND
ND
ND
ND
ND
Calcium
0.93
0.81
0.80
0.77
0.95
0.91
Chloride
1.57
1.28
1.52
1.64
1.52
1.34
Nitrate
ND
ND
ND
ND
ND
ND
Sulphate
8.74
8.62
8.16
8.50
8.63
8.52
SoO*
ND
ND
ND
ND
ND
ND
a ND = not detected.
J-2
-------
Appendix K
Supporting Calibration and Data Tables for
Individual Semivolatile Organic Compounds
K-l
-------
Contents
Table Page
K-l Calibration Ranges for PM Speciated Organic Compounds, Standard Suite #1 . . K-3
K-2 Calibration Ranges for PM Speciated Organic Compounds, Standard Suite #2 . . K-5
K-3 Calibration Ranges for Speciated PM Organic Compounds, Standard Suite #3 . . K-7
K-4 Emission Factors (mg/kg fuel) for //-Alkanoic Acids from Hogged Fuel
Boiler #2 as Obtained from PUF Samples (WHP#1) K-9
K-5 Emission Factors (mg/kg fuel) for n-Alkanoic Acids from Hogged Fuel
Boiler #2 as Obtained from PUF Samples (WHP#3) K-l 1
K-6 Emission Factors (mg/kg fuel) for PAHs from Hogged Fuel Boiler #2
as Obtained from PUF Samples (WHP#2) K-l2
K-7 Emission Factors (mg/kg fuel) for n-Alkanoic Acids from Hogged Fuel
Boiler #2 as Obtained from Quartz Filters K-l3
K-8 Emission Factors (mg/kg fuel) for //-Alkanes from Hogged Fuel Boiler #2
as Obtained from Quartz Filters K-l4
K-9 Emission Factors (mg/kg fuel) for PAHsa from Hogged Fuel Boiler #2
as Obtained from Quartz Filters K-l6
K-2
-------
Table K-1. Calibration Ranges for PM Speciated Organic Compounds, Standard
Suite #1
High Calibration Low Calibration
Concentration Concentration
Compound |Ig/mL |lg/mL
dimethyl phthalate 19 0.8
diethyl phthalate 19 0.8
naphthalene 10 0.8
2-methylnaphthalene 21.28 0.968
1-methylnaphthalene 21.28 0.896
2,7-dimethylnaphthalene 18.24 0.768
1,3-dimethylnaphthalene 18.24 0.768
2,6-dimethylnaphthalene 18.24 0.768
acenaphthylene 38 1.6
acenaphthene 19 0.8
fluorene 3.8 0.16
1-methylfluorene 9.5 0.4
phenanthrene 1.9 0.08
anthracene 1.9 0.08
9-methylanthracene 18.62 0.784
octylcyclohexane 9.5 0.4
norpristane 9.5 0.4
decylcyclohexane 9.5 0.4
pristane 9.5 0.4
phytane 9.5 0.4
tridecylcyclohexane 9.5 0.4
dibutyl phthalate 19 0.8
butyl benzyl phthalate 19 0.8
A/.s/2-ethylhexyl) phthalate 19 0.8
dioctyl phthalate 19 0.8
fluoranthene 3.8 0.16
pyrene 1.9 0.08
chrysene 1.9 0.08
benzo [a] anthracene 1.9 0.08
benzo[k]fluoranthene 1.9 0.08
benzo [b]fluoranthene 3.8 0.16
benzo [a]pyrene 1.9 0.08
nonadecylcyclohexane 9.5 0.4
squalane 19.855 0.836
indeno[l,2,3-cd]pyrene 1.9 0.08
dibenzo [a,h] anthracene 3.8 0.16
benzo [ghijperylene 3.8 0.16
continued
K-3
-------
Table K-1. (concluded)
High Calibration
Low Calibration
Concentration
Concentration
Compound
p,g/mL
p,g/mL
coronene
2.375
0.1
cholestane 1
0.95
0.04
cholestane 2
0.95
0.04
cholestane 3
0.95
0.04
cholestane 4
0.95
0.04
ABB-20R-24S-methylcholestane
0.95
0.04
ABB-20R-ethylcholestane
0.95
0.04
17A(H)-22,29,30-trisnorhopane
0.95
0.04
17B(H)-21 A(H)-norhopane
0.95
0.04
17B(H)-21B(H)-hopane
0.95
0.04
17B(H)-21A(H)-hopane
0.95
0.04
17A(H)-21B(H)-hoDane
0.95
0.04
K-4
-------
Table K-2. Calibration Ranges for PM Speciated Organic Compounds, Standard
Suite #2
High Calibration Low Calibration
Concentration Concentration
Compound
|Ig/mL
|j,g/mL
«-decane (n-CIO)
8.2
0.41
/7-undccanc (n-Cll)
8.2
0.41
/7-dodccanc (n-C12)
8.2
0.41
/7-tridccanc (n-C13)
8.2
0.41
9h-fluoren-9-one
8.68
0.434
/7-tctradccanc (n-C14)
8.2
0.41
/7-pcntadccanc (n-C15)
8.2
0.41
/7-hcxadccanc (n-16)
8.2
0.41
«-hcptadccanc (n-C17)
8.2
0.41
1-octadecene
15.32
0.766
/7-octadccanc (n-C18)
8.2
0.41
2-methylnonadecane (iso-C20)
1.96
0.098
3 -methylnonadecane {anteiso-C20)
1.96
0.098
/7-nonadccanc (n-C19)
8.2
0.41
«-eicosane (n-C20)
8.2
0.41
/7-hcncicosanc (n-C21)
8.2
0.41
«-docosane (n-C22)
8.2
0.41
/7-tricosanc (n-C23)
8.2
0.41
z'so-docosane (C23)
8.2
0.41
anteiso-docosane (C23)
8.2
0.41
pyrene
0.4
0.02
anthraquinone
4.72
0.236
naphthalic anhydride
8.16
0.408
methylfluoranthene
0.4
0.02
retene
1.96
0.098
acepyrene (cyclopenta[c,d]pyrene)
1.96
0.098
benzanthraquinone
8.28
0.414
1 -methylchry sene
0.4
0.02
benzo[a]pyrene
3.92
0.196
/7-tctracosanc (n-C24)
8.2
0.41
z'so-tricosane (C24)
8.2
0.41
a«/t'/.vo-tricosanc (C24)
8.2
0.41
«-pcntacosanc (n-C25)
8.2
0.41
/.vo-tctracosanc (C25)
8.2
0.41
a«to'so-tetracosane (C25)
8.2
0.41
/7-hcxacosanc (n-C26)
8.2
0.41
/.vo-pcntacosanc (C26)
8.2
0.41
continued
K-5
-------
Table K-2. (concluded)
High Calibration
Low Calibration
Concentration
Concentration
Compound
[ig/mL
[Ig/mL
anie/.so -pc ntacosanc (C26)
8.2
0.41
heptacosane (n-C27)
8.2
0.41
/.vo-hcxacosanc (C27)
8.2
0.41
an ie is a-h c xaco san c (C27)
8.2
0.41
/w-hcptacosanc (C28)
8.2
0.41
an ie is a-h c p taco san c (C28)
8.2
0.41
/.vo-octacosanc (C29)
8.2
0.41
anteiso-octacosane (C29)
8.2
0.41
octacosane (n-C28)
8.2
0.41
nonacosane (n-C29)
8.2
0.41
/w-nonacosanc (C30)
8.2
0.41
an/6'/.s'o-nonacosane (C30)
8.2
0.41
squalene
16.56
0.828
dibenzo [a,e]pyrene
0.4
0.02
hexatriacontane-d74
10.15
10.15
/7-triacontanc (n-C30)
17.2
0.86
/7-hcntriacontanc (n-C31)
17.2
0.86
/.vo-triacontanc (C31)
17.2
0.86
anteiso-triacontane (C31)
17.2
0.86
/w-hcntriacontanc (C32)
8.2
0.41
an ie is a-h c n t ri aco n tan c (C32)
8.2
0.41
/.vo-dotriacontanc (C33)
8.2
0.41
an ie iso-do t ri aco n tan c (C33)
8.2
0.41
dotriacontane (n-C32)
8.2
0.41
tritriacontane (n-C33)
8.2
0.41
tetratriacontane («-C34)
8.2
0.41
/.vo-tritriacontanc (C34)
8.2
0.41
an ie/.vo-tritri aco n tan c (C34)
8.2
0.41
pentatriacontane (n-C35)
8.2
0.41
hexatriacontane (n-C36)
8.2
0.41
tetracontane (/7-C40)
8.2
0.41
K-6
-------
Table K-3. Calibration Ranges for Speciated PM Organic Compounds, Standard
Suite #3
High Calibration Low Calibration
Compound
[ig/mL
|Xg/mL
Caproic or Hexanoic acid, methyl ester
18.68
0.75
Succinic or Butanedioic acid, methyl ester
6.13
0.25
Caprylic or Octanoic acid, methyl ester
18.53
0.74
Glutaric or Pentanedioic acid, dimethyl ester
7.25
0.29
Nonanoic acid, methyl ester
14.66
0.59
Adipic or Hexanedioic acid, dimethyl ester
6.27
0.25
Capric or Decanoic acid, methyl ester
14.66
0.59
Undecanoic acid, methyl ester
14.66
0.59
Pimelic or Heptanedioic acid, dimethyl ester
6.32
0.25
Suberic or Octanedioic acid, dimethyl ester
6.32
0.25
Dodecanoic acid, methyl ester
17.16
0.69
Azelaic or Nonanedioic acid, dimethyl ester
5.64
0.23
Tridecanoic acid, methyl ester
17.16
0.69
Pinonic Acid, methyl ester
22.11
0.88
Dimethyl phthalate
6.18
0.25
1,4-Benzenedicarboxylic acid, methyl ester
6.08
0.24
1,3-Benzenedicarboxylic acid, methyl ester
6.42
0.26
1,2-Benzenedicarboxylic acid, 4-methyl,
6.27
0.25
1,2,4-Benzenetricarboxylic acid, trimethyl ester
6.03
0.24
Benzenetetracarboxylic acid, methyl ester
5.93
0.24
Abietic acid, methyl ester
17.16
0.71
Pimaric acid, methyl ester (secondary)
17.16
0.71
Sandaracopimaric acid, methyl ester (secondary std)
17.16
0.69
Isopimaric acid, methyl ester (secondary std)
17.16
0.71
6,18,1 l,13-Abetatetraen-18-oic acid, methyl ester
17.16
0.71
Dehydroabietic acid, methyl ester (secondary std)
17.16
0.71
Sebacic or Decanedioic Acid, dimethyl ester
5.74
0.23
Tetradecanoic acid, methyl ester
15.05
0.6
Pentadecanoic acid, methyl ester
15.05
0.6
Palmitoleic or 9-Hexadecenoic acid, methyl ester
15.74
0.63
Hexadecanoic acid, methyl ester
14.71
0.59
Heptadecanoic acid, methyl ester
14.71
0.59
Linoleic or 8,11-Octadecadienoic acid, methyl ester
14.07
0.56
Oleic or 9-Octadecenoic acid, methyl ester
16.52
0.66
Linolenic 9,12,15-Octadecatrienoic acid, methyl ester
17.6
0.7
Octadecanoic acid, methyl ester
11.67
0.47
Nonadecanoic acid, methyl ester
11.67
0.47
Eicosanoic acid, methyl ester
12.06
0.48
continued
K-7
-------
Table K-3. (concluded)
High Calibration
Low Calibration
Compound
|lg/mL
|lg/mL
Heneicosanoic acid, methyl ester
12.06
0.48
Docosanoic acid, methyl ester
12.21
0.49
Tricosanoic acid, methyl ester
12.21
0.49
Tetracosanoic acid, methyl ester
13.73
0.55
Pentacosanoic acid, methyl ester
13.73
0.55
Hexacosanoic acid, methyl ester
13.73
0.55
Heptacosanoic Acid, methyl ester
14.85
0.59
Octacosanoic acid, methyl ester
14.85
0.59
Nonacosanoic acid, methyl ester
14.85
0.59
Triacontanoic acid, methvl ester
14.85
0.58
K-8
-------
Table K-4. Emission Factors (mg/kg fuel) for n-Alkanoic Acids from Hogged Fuel Boiler #2 as Obtained from PUF Samples
(WHP#1)
Ports R4 & R8
Port R10
w-Alkane IB112701H
IB112801H IB112901H
Average
S.D.a
RSD"
IB112701
IB112801
IB112901
Average
S.D.
RSD
[R4+R81-R10
H-C10
0.0034
0.0068
0.0013
0.0039
0.0028
71.46
0.0070
0.0100
NDC
0.0057
0.005
87.35
-0.0018
n-Cll
0.0020
0.0030
0.0012
0.0021
0.0009
43.9412
0.0050
0.0070
ND
0.0040
0.004
88.39
-0.0020
n-C12
0.0016
0.1132
-0.0001
0.0382
0.0649
169.773
0.0190
0.0350
0.002
0.0187
0.012
64.4
0.0196
n-C13
0.0035
0.0010
-0.0003
0.0014
0.0019
140.068
0.0030
0.0020
0.0006
0.0019
0.002
90.91
-0.0005
«-C14
0.0006
0.0005
ND
0.0004
0.0003
81.6381
0.0007
0.0005
ND
0.0004
5 xlO"4
115.6
-3.6 xlO"5
«-C15
0.0003
0.0004
0.0001
0.0002
0.0002
63.6183
0.0002
0.0003
2xl0"6
0.0002
lxlO"4
83.67
8.19 xlO"5
n-C16
0.0002
0.0003
ND
0.0002
0.0001
76.811
ND
0.0002
ND
6.7 xlO"5
ND
ND
0.0001
n-Cll
0.0014
0.0018
0.0001
0.0011
0.0009
83.2193
0.0040
0.0020
5xl0"6
0.0020
0.003
141.1
-0.0009
«-C18
0.0003
0.0002
0.0001
0.0002
0.0001
62.0077
0.0002
0.0005
ND
0.0002
lxlO"4
60.61
-6.5 xlO"5
n-C19
0.0001
0.0002
-0.0001
0.0001
0.0001
166.278
0.0001
0.0002
0.0001
0.0001
3 xlO"5
24.96
-3.4 xlO"5
n-C20
0.0001
0.0001
ND
0.0001
ND
52.1756
0.0006
0.0001
ND
0.0002
4 xlO"4
190
-0.0001
«-C21
0.0001
0.0007
0.0003
0.0003
0.0003
94.2338
0.0001
0.0004
ND
0.0002
7 xlO"5
42.43
0.0002
«-C22
0.0007
0.0015
0.0001
0.0008
0.0007
87.9995
0.0003
0.0006
ND
0.0003
2 xlO"4
70.71
0.0005
«-C23
0.0025
0.0060
-0.0023
0.0020
0.0042
203.391
0.0030
0.0060
0.002
0.0037
7 xlO"4
19.28
-0.0016
«-C24
0.0003
0.0006
-0.0008
ND
0.0007
2722.13
0.0003
0.0006
0.0008
0.0006
4 xlO"4
62.39
-0.0005
n-C25
0.0021
0.0111
-0.0097
0.0011
0.0104
919.877
ND
0.0130
0.008
0.0070
0.006
80.81
-0.0059
n-C26
0.0001
0.0044
-0.0054
-0.0003
0.0049
-1676.9
0.0070
0.0040
0.005
0.0053
0.001
26.52
-0.0056
«-C27
0.0015
0.0014
-0.0054
-0.0008
0.0040
-488.2
0.0030
0.0030
0.005
0.0037
0.001
38.57
-0.0045
«-C28
0.0012
0.0006
-0.0041
-0.0008
0.0029
-361.92
0.0020
0.0010
0.004
0.0023
0.001
60.61
-0.0031
«-C29
0.0018
0.0006
-0.0049
-0.0008
0.0036
-430.28
0.0010
0.0010
0.004
0.0020
0.002
106.1
-0.0028
«-C30
0.0001
ND
-0.0001
ND
0.0001
763.275
0.0020
ND
ND
0.0007
0.001
202.8
-0.0007
«-C31
0.0015
0.0001
-0.0011
0.0001
0.0013
876.404
ND
0.0002
0.0008
0.0003
5 xlO"4
158.6
-0.0002
«-C32
0.0001
ND
ND
ND
0.0001
234.777
0.0006
ND
9xl0"6
0.0002
4 xlO"4
202.5
-0.0002
«-C33
ND
ND
ND
ND
ND
335.069
ND
ND
lxlO"7
1.3 xlO"5
3 xlO"5
211.1
-1.3xl0"5
continued
-------
Table K-4. (concluded)
Ports R4 & R8
Port R10
w-Alkane IB112701H
IB112801H IB112901H
Average
S.D.a
RSD"
IB112701
IB112801
IB112901
Average
S.D.
RSD
[R4+R81-R10
n-C34
0.0010
ND
-0.0001
0.0003
0.0006
211.985
ND
0.0001
ND
1.7xl0"5
ND
ND
0.0003
n-C35
ND
ND
ND
ND
ND
-3151.2
0.0004
ND
lxlO"6
0.0001
3X10"4
211.1
-0.0001
n-C36
ND
ND
ND
ND
ND
173.205
ND
ND
ND
ND
ND
3 x 10"7
n-C40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
SUM
0.0263
0.1543
-0.0312
SUM
-0.0101
a S.D. = standard deviation.
b RSD = relative standard deviation.
c ND = not detected.
-------
Table K-5. Emission Factors (mg/kg fuel) for n-Alkanoic Acids from Hogged Fuel Boiler #2 as Obtained from PUF Samples
(WHP#3)
«-Alkanoic Acid
Ports R4 & R8
RIO
11/27/01
11/28/01
11/29/01
Average
S.D.a
RSDb
11/27/01
11/28/01
11/29/01
Average
S.D.
RSD
C8
0.0001
0.0003
NDC
0.0001
0.0001
119
0.0001
0.0003
0.0001
0.0002
0
63.5
C9
0.0004
0.0002
ND
0.0002
0.0002
99.638
0.0002
0.0022
ND
0.0008
0
151
CIO
0.0003
0.0004
ND
0.0002
0.0002
73.469
0.0002
0.0026
0.0002
0.0010
0
140
Cll
0.0001
0.0008
0.0001
0.0003
0.0004
131.87
0.0006
0.0009
0.0004
0.0006
0
32.8
C12
0.0007
0.0007
0.0001
0.0005
0.0004
74.153
0.0004
0.0006
0.0005
0.0005
0
23.1
C13
0.0017
0.0009
0.0001
0.0009
0.0008
87.684
0.0002
0.0006
0.0017
0.0008
0
92.7
C14
0.0002
0.0006
0.0001
0.0003
0.0003
94.651
0.0001
0.0001
0.0009
0.0003
0
132
C15
-0.0001
0.0021
ND
0.0007
0.0012
178.88
0.0020
0.0021
0.0003
0.0015
0
69
C16
ND
0.0003
ND
0.0001
0.0001
192.96
0.0001
0.0001
0.0001
0.0001
0
11.2
C17
-0.0004
0.0018
0.0003
0.0006
0.0011
195.1
ND
ND
0.0029
0.0010
0
173
C18
ND
0.0003
ND
0.0001
0.0002
178.53
ND
ND
0.0001
3.3* 10~5
0
173
a S.D. = standard deviation.
b RSD = relative standard deviation.
c ND = not detected.
-------
Table K-6. Emission Factors (mg/kg fuel) for PAHsa from Hogged Fuel Boiler #2 as Obtained from PUF Samples (WHP#2)
Ports R4&R8
Port RIO
11/27/01
11/28/01
11/29/01
11/27/01
11/28/01
11/29/01
PAH
IB121701 IB121801 IB121901 Average
S.D.b
RSDC
IB121701 IB121801 IB121901 Average
S.D.
RSD
[R4+R8]-R10
dimethyl phthalate
4 xlO"5
3.7xl0"5
NDd
2.6xl0"5
2>
<10"5
86.8
ND
ND
ND
ND
ND
3xl0"5
diethyl phthalate
0.0003
0.0002
0.0002
0.00024
6
xlO"5
25.24
0.0005
0.0002
0.0001
0.0003
2xl0"4
98.99
-lxlO"5
naphthalene
2xl0"5
9.3 xlO"6
-2.6xl0"6
8.9xl0"6
1>
<10"5
127
ND
ND
ND
ND
lxlO"5
601
7xl0"6
2-
methylnaphthalene
2xl0"5
ND
1.21
xlO"5
l.lxlO"5
1>
<10"5
94.14
ND
ND
ND
ND
ND
1-
methylnaphthalene
ND
ND
ND
ND
ND
ND
ND
ND
dibutyl phthalate
0.0009
0.0004
0.0009
0.00074
3>
<10"4
42.1
0.0009
0.0006
0.0017
0.0011
6xl0"4
53.86
-3 xlO"4
butyl benzyl
phthalate
0.0004
0.0001
0.0008
0.00045
4>
<10"4
80.12
0.0003
0.0003
0.0098
0.0035
0.007
194.2
-0.003
bis-2-ethylhexyl
phthalate
0.0017
0.0011
0.0021
0.00164
5>
<10"4
31.56
0.0013
0.0013
0.0089
0.0038
0.005
139.3
-0.002
a PAH = polycyclic aromatic hydrocarbon.
b S.D. = standard deviation.
c RSD = relative standard deviation.
d ND = not detected.
-------
Table K-7. Emission Factors (mg/kg fuel) for n-Alkanoic Acids from Hogged Fuel Boiler #2 as Obtained from Quartz Filters
Amount in Extract
Total in Extract
Amount in Sample Air
ng/jiL
ng
ng/L
n-
DAa
RCb Ports
Emission Factor
Alkanoic
Port D1
R4&R8
DA
RC Ports
RC Ports
mg/kg of Fuel
Acid
Port D1
R4 &R8
DA Port D1
R4 &R8
RC-DA
Average
C8
NDC
ND
1915
ND
0.0760
ND
-0.0760
-1.0198
C9
ND
ND
2280
ND
0.0905
ND
-0.0905
-1.2141
CIO
2.41
4.84
668.75
605
0.0265
0.0246
-0.0020
-0.0265
Cll
15.32
2.09
235
261.25
0.0093
0.0106
0.0013
0.0172
C12
18.24
2.49
112.5
311.25
0.0045
0.0126
0.0082
0.1096
C13
5.35
22.75
305
2843.75
0.0121
0.1154
0.1033
1.3867
C14
1.88
0.36
133.75
45
0.0053
0.0018
-0.0035
-0.0467
C15
0.9
1.13
850
141.25
0.0337
0.0057
-0.0280
-0.3757
C16
2.44
0.51
ND
63.75
ND
0.0026
0.0026
0.0347
C17
1.07
0.33
ND
41.25
ND
0.0017
0.0017
0.0225
C18
6.8
0.17
ND
21.25
ND
0.0009
0.0009
0.0116
a DA = dilution air.
b RC = residence chamber.
c ND = not detected.
-------
Table K-8. Emission Factors (mg/kg fuel) for n-Alkanes from Hogged Fuel Boiler #2 as Obtained from Quartz Filters
Amount in Extract
ng/jiL
Total in Extract (is=125 |iL)
ng
Amount in Air Sample
ng/jlL
Emission Factors
mg/kg fuel
n-
Alkane
DAa Port
D1
RCb
Ports
R4&R8
RC Port
R10
DA Port
D1
RC Ports
R4&R8
RC Port
R10
DA Port
D1
RC Ports
R4&R8
RC Port
R10
Ports Port
R4 & R8 R10
(RC-DA) (RC-DA)
Ports
R4&R8
Port
R10
Average
n-CIO
NDC
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
n-Cll
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
n-C12
ND
8.22
ND
ND
1027.5
ND
ND
0.0208
ND
0.0208
ND
0.0001
ND
0.0001
n-C13
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
n-CU
0.13
ND
ND
16.25
ND
ND
0.0013
ND
ND
-0.0013
-0.0013
ND
ND
ND
n-C15
0.26
ND
ND
32.5
ND
ND
0.0026
ND
ND
-0.0026
-0.0026
ND
ND
ND
n-C16
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
n-Cll
ND
1.96
ND
ND
245
ND
ND
0.0050
ND
0.0050
ND
ND
ND
ND
n-C18
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
n-C19
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
«-C20
ND
1.97
ND
ND
246.25
ND
ND
0.0050
ND
0.0050
ND
ND
ND
ND
«-C21
0.41
1.31
ND
51.25
163.75
ND
0.0041
0.0033
ND
-0.0008
-0.0041
ND
ND
ND
n-C22
0.42
10.24
2.99
52.5
1280
373.75
0.0042
0.0260
0.0178
0.0217
0.0136
0.0001
0.0001
0.0001
n-C23
0.86
53.08
22.22
107.5
6635
2777.5
0.0087
0.1346
0.1325
0.1259
0.1238
0.0007
0.0007
0.0007
«-C24
1.13
106.57
54.92
141.25
13321.25
6865
0.0114
0.2702
0.3275
0.2588
0.3161
0.0015
0.0018
0.0016
n-C25
1.89
217.46
126.77
236.25
27182.5
15846
0.0191
0.5514
0.7560
0.5323
0.7369
0.0030
0.0042
0.0036
n-C26
2.4
212.41
126.27
300
26551.25
15784
0.0243
0.5386
0.7530
0.5143
0.7287
0.0029
0.0042
0.0036
«-C27
2.62
146.1
83.34
327.5
18262.5
10418
0.0265
0.3704
0.4970
0.3440
0.4705
0.0020
0.0027
0.0023
«-C28
1.89
58.18
33.87
236.25
7272.5
4233.8
0.0191
0.1475
0.2020
0.1284
0.1829
0.0007
0.0010
0.0009
n-C29
2.21
35.68
21.02
276.25
4460
2627.5
0.0223
0.0905
0.1253
0.0681
0.1030
0.0004
0.0006
0.0005
«-C30
0.06
0.71
0.26
7.5
88.75
32.5
0.0006
0.0018
0.0016
0.0012
0.0009
6.83x10^
5.4X10"6
6.12xl0"6
«-C31
1.41
10.18
4.01
176.25
1272.5
501.25
0.0142
0.0258
0.0239
0.0116
0.0097
6.62xl0"5
5.53 xlO"5
6.07 xlO"5
«-C32
0.07
0.35
0.18
8.75
43.75
22.5
0.0007
0.0009
0.0011
0.0002
0.0004
1.03x10^
2.1 xlO"6
1.56 xlO"6
«-C33
ND
0.01
0.01
ND
1.25
1.25
ND
2.54xl0"5
5.96xl0"5
2.535
xlO"5
5.96xl0"5
1.45 xlO"7
3.41 xlO"7
2.43 xlO"7
continued
-------
Table K-8. (concluded)
Amount in Extract
Total in Extract (is=125 p.L)
Amount in Air Sample
Emission Factors
ng/p.L
ng
ng/nL
mg/kg fuel
RCb
Ports
Port
it- DAa Port
Ports
RC Port
DA Port
RC Ports
RC Port
DA Port
RC Ports
RC Port
R4&R8
R10
Ports
Port
Alkane
D1
R4&R8
RIO
D1
R4&R8
RIO
D1
R4&R8
R10
(RC-DA) (RC-DA)
R4&R8
R10
Average
n-C34
1.38
2.58
2.98
172.5
322.5
372.5
0.0139
0.0065
0.0178
-0.0074
0.0038
-4.2 xlO"5
2.19xl0"5
-lxlO"5
n-C35
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
n-C36
0.01
ND
ND
1.25
ND
ND
0.0001
ND
ND
-0.0001
-0.0001
-5.8xl0"7
-5.8xl0"7
-5.8xl0"7
n-C40
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
Sum
2.0250
2.6821
0.0135
stack flow, L/min
14034637
4113.69
16382
6502.496
time, min
480
4114.097
16456.39
7239.6
fuel mass, kg
1176992
4142.391
16461.93
7219.8
12370.18
49300.32
20961.9
a DA = dilution air.
b RC = residence chamber.
c ND = not detected.
-------
Table K-9. Emission Factors (mg/kg fuel) for PAHsa from Hogged Fuel Boiler #2 as Obtained from Quartz Filters
Composite in Extract
Total in Extract (is=125 |iL)
Amount in Air Sample
Emission Factors
ng/jlL
ng
ng/*lL
mg/kg fuel
DA"
RCC
RC Port
DA Port RC Ports RC Port
DA
RC Ports RC Port
Ports
Port R10
Ports
Port
Port D1
Ports
R10
D1
R4 &R8
R10
Port D1
R4&R8
R10
R4 & R8 (RC-DA)
R4&R8
R10
R4&R8
(RC-DA)
dimethyl phthalate
NDd
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
diethyl phthalate
0.26
1.45
ND
32.5
181.25
ND
0.0013
0.0074
ND
0.0061
-0.0013
0.0002
ND
naphthalene
0.18
0.03
ND
22.5
3.75
ND
0.0009
0.0002
ND
-0.0007
-0.0009
-2.0705
-3.60551
xlO"5
xlO"5
2-methylnaphthalene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
-2.49612
xirr5
1 -methy lnaphthalene
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
A1U
ND
dibutyl phthalate
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
butyl benzyl phthalate
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
bis-2-ethyl hexyl
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
phthalate
Sum
1.48937
-6.10163
xlO"4
xlO"5
L/min
Time
total
L/min
Time
total
L/min
Time
total
min
liters
min
liters
min
liters
IB112701H
17.188
478.67
8227.38
17.036
478.67
8154.622
16.588
392
6502.496
17.188
478.67
8227.38
IB112801H
16.088
480.17
7724.975
17.136
480.17
8228.193
16.088
450
7239.6
17.136
480.17
8228.193
IB112901H
19.242
480.5
9245.781
17.168
480.5
8249.224
16.044
450
7219.8
17.092
480.5
8212.706
25198.14
24632.04
20961.90
a PAH = polycyclic aromatic hydrocarbons.
b DA = dilution air.
c RC = residence chamber.
d ND = not detected.
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Appendix L
List of ERG SOPs and EPA MOPs by Title
L-l
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Contents
Table Page
L-l ERG Standard Operating Procedures by Title L-3
L-2 EPA Method Operating Procedures by Title L-6
L-2
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Table L-1. ERG Standard Operating Procedures by Title
SOP
Tr SOP Title
No.
1 Documentation of Field Recovery Activities
2 Gravimetric Determination for Particulate Emissions Measurements
3 Field Procedure for Collecting Ambient Air Toxics and Carbonyl Compounds Samples
using the ERG:AT/C Sampling System
3B Field Procedure for Collecting Ambient Air Toxics and Carbonyl Compounds Samples
using the ERG:AT/C Sampling System
4 SOP for Preventive Maintenance in the Gas Chromatography/Mass Spectrometry
Laboratory
5 SOP for the Concurrent GC/FID/MS Analysis of Canister Air Toxic Samples
6 SOP for the Analysis of Tenax® Tubes According to EPA Method TO-l/TO-17
7 SOP for the Preparation of Review Packages for Mass Spectrometry Data Sets
8 Procedure for Preparation of Standard Operating Procedures
9 SOP for the Operation of the Documentation System
10 SOP for the Determination of Method Detection Limits in the GC/MS Air Toxics
Laboratory
11 SOP for Sample Storage and Checkout from Freezers/Refrigerators at the Laboratory
12 SOP for Basic Training Requirements for Sample Preparation Laboratory Personnel
13 Field Procedure for Collecting Ambient Air Hexavalent Chromium Samples Using the
ERG:CR6 Sampling System
14 SOP for Sample Preparation Quality Control
15 SOP for Documentation Procedures for the Sample Preparation Laboratory
16 SOP for the Varian 9000 Series High Performance Liquid Chromatograph (HPLC)
17 SOP for Developing, Documenting, and Evaluating the Accuracy of Spreadsheet Data
18 Maintaining and Recording Data Records
19 SOP for Transferring, Storing, and Using Confidential Business Information (CBI)
20 SOP for Conducting a Laboratory Systems Audit
21 Calibration and Operation of Analytical Balances
22 SOP for the Preparation of Standards in the ERG Organic Preparation Laboratory
23 SOP for the Use of Significant Figures and Rounding Off Numbers When Reporting
Data
24 SOP for Preparing Aldehyde Derivatizing Reagents and Extracting Derivatized Samples
25 SOP for the Operation of the Rainin High Performance Liquid Chromatography System
26 SOP for Documentation: Labeling of Samples and Standards Prepared in the Laboratory
27 SOP for the Operation of a Gas Chromatograph
28 SOP for Quality Assurance/Quality Control in Gas Chromatography/Mass Spectrometry
29 SOP for Concentration of Sample Extracts Using the Kuderna-Danish Concentrator
30 SOP for Canister Sampling System Certification Procedures
31 SOP for Cleaning Glassware and Syringes for Organic Analysis
32 Statistical Manual Standard Operating Procedure
33 SOP for Solid and Hazardous Waste Disposal
continued
L-3
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Table L-1. (continued)
vr SOP Title
No.
34 Analytical Chemistry Training at PPK Laboratory
35 SOP for Quality Assurance/Quality Control
36 SOP for Laboratory Security
37 SOP for Chemical Inventory
38 SOP for Personal Protective Equipment Program
39 SOP for Maintaining Laboratory Notebooks
40 SOP for Chemical Storage Facilities
41 SOP for Tracer Gas Release and Integrated Bag Sampling for Analysis by FTIR
Spectroscopy
42 SOP for the Dionex-300 Ion Chromatograph
43 SOP for the Analysis of Semivolatile Organic Compounds in Gaseous Emissions using
the SemiVOST Method
44 SOP for Method 8270C - GC/MS Analysis of Semivolatile Organics
45 SOP for Sample Log-in at the ERG Chemistry Laboratory
46 Field Procedure for Collecting Speciated and/or Total Nonmethane Organic Compounds
Ambient Air Samples Using the ERG:S/NMOC Sampling System
47 Field Procedure for Collecting Ambient Carbonyl Compounds Samples Using the
ERG:C Sampling System
47B Field Procedure for Collecting Ambient Carbonyl Compounds Samples Using the
ERG:C Sampling System
48 SOP for Cleaning XAD-2® with Quality Control Measures to Assure Cleanliness
49 SOP for the Extraction and Analysis of PAHs from XAD-2® Traps
50 SOP for Separatory Funnel Liquid-Liquid Extraction by EPA SW-846 Method 3510C
51 SOP for Continuous Liquid-Liquid Extraction by EPA SW-846 Method 3520C
52 SOP for Acid-Base Partition Cleanup by EPA SW-846 Method 3650B
53 SOP for Soxhlet Extraction by EPA SW-846 Method 3540C
54 SOP for Preparation, Evaluation, and Shipping of Performance Evaluation Samples for
Method 24
55 SOP for Maintenance of NANOPure-A Deionized Water System
56 SOP for Daily Maintenance of Cold Storage Units
57 SOP for Project Peer Review
58 SOP for Preparing Method 25 Audit Samples Using the Transfill System
59 SOP for High Performance Liquid Chromatography
60 SOP for PDFID Sample Analysis
61 SOP for Standard Preparation Using Dynamic Flow Dilution System
62 SOP for UATMP and NMOC Canister Cleaning
63 SOP for the Analysis of Ambient Air for Hexavalent Chromium by IC
64 SOP for Shipping Method 6, 7, 8, and 26 Audit Samples
65 SOP for the ERG Sample Database
66 Cylinder Recycling
continued
L-4
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Table L-1. (concluded)
SOP
No.
SOP Title
67
SOP for Producing Standard Mixtures of Organic Compounds in Air by Liquid Injection
68
SOP for Refrigerator and Freezer Temperature Monitoring
69
SOP for Shipping Method 23 Audit Samples
70
SOP for Storing and Shipping Method 13A, 13B, and 29 Audit Samples
71
SOP for Documentation Requirements for the GC/MS Laboratory and for GC/MS
Systems in the VOC Laboratory
72
SOP for Stack Sampling Using FTIR Spectroscopy
73
SOP for the ECD Wipe Test
74
SOP for the Preparation of Spiked Sorbent Samples Using Liquid Spiking into
Tenax-GC® Tubes
75
SOP for the Preparation of Spiked Sorbent Samples Using Liquid Spiking onto XAD-2®
76
SOP for the Preparation of Spiked Sorbent Samples Using Flash Evaporation Spiking
onto XAD-2®
77
SOP for Method 624
78
SOP for Method 625
79
SOP for Method 1624C
80
SOP for Method 1625C
81
SOP for the Preparation of Spiked Method 8 Samples as Stationary Source Audit
Materials
L-5
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Table L-2. EPA Method Operating Procedures by Title
MOP No.
MOP Title
2501
Preparation of Clean Substrates, Glassware, and Other Materials
2502
Purification of Benzene Solvent
2503
Mass Measurements of Blank and Exposed Sampling Substrates
2504
Solvent Extraction of Samples and Extract Concentration
2505
Diazomethane Preparation and Extract Methylation
2506
Silylation of Methylated Extracts
2507
GC/MS Calibration and Analysis of Extracts
2508
Denuder Coating, Cleanup, and Extraction
2509
PUF Cleanup and Extraction
NIOSH Method 5040
Elemental/Oraanic Carbon Analvsis
L-6
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TECHNICAL REPORT DATA
1. REPORT NO.
EPA-600/R-03/100b
2.
3. RECIPIENTS ACCESSION NO.
4. TITLE AND SUBTITLE
Source Sampling Fine Particulate Matter: A Kraft Process Recovery
5. REPORT DATE
November 2003
Boiler at a Pulp and Paper Facility: Volume 1, Report
6. PERFORMING ORGANIZATION CODE
7. AUTHORS
Joan T. Bursey and Dave-Paul Dayton
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Eastern Research Group, Inc.
10. PROGRAM ELEMENT NO.
1600 Perimeter Park Drive
Morrisville, NC 27560
11. CONTRACT/GRANT NO.
Contract No. 68-D7-001
12. SPONSORING AGENCY NAME AND ADDRESS
U. S. EPA, Office of Research and Development
13. TYPE OF REPORT AND PERIOD COVERED
Final; 02/05/01 - 05/30/03
Air Pollution Prevention and Control Division
Research Triangle Park, North Carolina 27711
14. SPONSORING AGENCY CODE
EPA/600/13
15. SUPPLEMENTARY NOTES
The EPA Project Officer is N. Dean Smith, mail drop E343-02, phone (919) 541-2708
16. ABSTRACT
The report provides a profile of the chemical composition of particulate matter (PM) with aerodynamic
diameter 2.5 |_im or less (PM25) emitted from an auxiliary boiler at a pulp and paper facility using the Kraft
pulping process. The auxiliary boiler was fired with a mixture of wood bark (hogged wood waste) and
bituminous coal and was rated to generate a maximum of 889 Mbtu/hour. It was equipped with a control
system that included a multicyclone-electroscrubber system installed on the flue gas duct and bag filters
installed on the vents of the coal bins, scrubber ash silo, and boiler ash silo. The data obtained during this
research will assist States in determining the major sources of PM2 5 so they can devise and institute a
control strategy to attain the ambient concentrations set by the National Ambient Air Quality Standard for
PM2 5 that was promulgated in July 1977 by the U.S. EPA. Along with the PM2 5 emission profile, data are
also provided for gas-phase emissions of several organic compounds. Data are provided in a format
suitable to be included in the EPA source profile database, SPECIATE.
17.
KEYWORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
b. IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Air Pollution
Paper Industry
Wood Pulp
Fine Particulate Matter
Chemical Composition
Organic Compounds
Volatility
Pollution Control
Stationary Sources
13B
11L
14G
07D
07C
20M
18. DISTRIBUTION STATEMENT
19. SECURITY CLASS (This Report)
Unclassified
21. NO. OF PAGES
190
Release to Public
20. SECURITY CLASS (This Page)
Unclassified
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE
forms/admin/techrpt.frm 7/8/99 pad
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