vvEPA
United States FPA-R00/R-0'V101 h
Environmental Protection OUU/fi Uo/ IU I D
Agency November 2003
Source Sampling Fine
Particulate Matter:
Stationary Source
Characterization
Testing of a Smelt Tank
at a Pulp and Paper
Facility: Volume 2,
Appendices
-------
-------
EPA-600/R-03/101 b
November 2003
Source Sampling Fine Particulate Matter:
Stationary Source Characterization Testing
of a Smelt Tank at a Pulp and Paper
Facility: Volume 2, Appendices
by
Joan T. Bursey and Dave-Paul Dayton
Eastern Research Group, Inc.
1600 Perimeter Park Drive
Morrisville, NC 27560
Contract No. 68-D7-0001
EPA Project Officer: N. Dean Smith
Air Pollution Prevention and Control Division
National Risk Management and Research Laboratory
Research Triangle Park, NC 27711
Prepared for:
U.S. Environmental Protection Agency
Office of Research and Development
Washington, DC 20460
-------
Abstract
Fine particulate matter (PM) of aerodynamic diameter 2.5 |im or less (PM2 5) has been
implicated in adverse health effects, and a National Ambient Air Quality Standard for PM2 5 has
been promulgated (July 1977) by the U.S. Environmental Protection Agency. A national
network of ambient monitoring stations has been established to assist States in determining
areas which do not meet the ambient standard for PM2 5. For such areas, it is important to
determine the major sources of the PM2 5 so States can devise and institute a control strategy to
attain the ambient concentrations set by the standard.
One of the tools often used by States in apportioning ambient PM2 5 to the sources is a
source-receptor model. Such a model requires a knowledge of the PM2 5 chemical composition
emitted from each of the major sources contributing to the ambient PM2 5 as well as the
chemical composition of the PM2 5 collected at the receptor (ambient monitoring) sites. This
report provides such a profile for a smelt tank at a pulp and paper facility. Along with the
PM2 5 emission profile, data are also provided for gas-phase emissions of several organic
compounds. Data are provided in a format suitable to be included in the EPA source profile
database, SPECIATE.
li
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Foreword
The U.S. Environmental Protection Agency (EPA) is charged by Congress with protecting the
Nation's land, air, and water resources. Under a mandate of national environmental laws, the
Agency strives to formulate and implement actions leading to a compatible balance between
human activities and the ability of natural systems to support and nurture life. To meet this
mandate, EPA's research program is providing data and technical support for solving
environmental problems today and building a science knowledge base necessary to manage our
ecological resources wisely, understand how pollutants affect our health, and prevent or reduce
environmental risks in the future.
The National Risk Management Research Laboratory (NRMRL) is the Agency's center for
investigation of technological and management approaches for preventing and reducing risks from
pollution that threaten human health and the environment. The focus of the Laboratory's research
program is on methods and their cost-effectiveness for prevention and control of pollution to air,
land, water, and subsurface resources; protection of water quality in public water systems;
remediation of contaminated sites, sediments and ground water; prevention and control of indoor
air pollution; and restoration of ecosystems. NRMRL collaborates with both public and private
sector partners to foster technologies that reduce the cost of compliance and to anticipate
emerging problems. NRMRL's research provides solutions to environmental problems by:
developing and promoting technologies that protect and improve the environment; advancing
scientific and engineering information to support regulatory and policy decisions; and providing
the technical support and information transfer to ensure implementation of environmental
regulations and strategies at the national, state, and community levels.
This publication has been produced as part of the Laboratory's strategic long-term research
plan. It is published and made available by EPA's Office of Research and Development to assist
the user community and to link researchers with their clients.
Lawrence W. Reiter, Acting Director.
National Risk Management Research Laboratory
111
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EPA Review Notice
This report has been peer and administratively reviewed by the U.S. Environmental Protection
Agency and approved for publication. Mention of trade names or commercial products does not
constitute endorsement or recommendation for use.
This document is available to the public through the National Technical Information Service,
Springfield, Virginia 22161.
iv
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Table of Contents
Volume 1, Report
Section Page
Abstract ii
List of Tables viii
List of Figures x
Nomenclature xi
Acknowledgments xii
Introduction 1
Characterization of a Smelt Tank at a Pulp and Paper Facility 2
Organization of Report 3
Conclusions 5
Methods and Materials 7
Description of Test Equipment 8
Dilution Sampling System 9
Dilution Sampling System Control Instrumentation 12
Process Description/Site Operation 14
Pre-Test Survey 18
Experimental Procedures 21
Preparation for Test Setup 21
Traverse Point Determination Using EPA Method 1 22
Volumetric Flow Rate Determination Using EPA Method 2 23
Pitot Tube Calibration 23
Calculation of Average Flue Gas Velocity 23
Nozzle Size Determination 24
Measurement of 02 and C02 Concentrations 25
Stationary Gas Distribution (as Percent Volume) 25
Dry Molecular Weight of Flue Gas 25
Wet Molecular Weight of Flue Gas 25
Determination of Average Moisture Using EPA Method 4 26
Volume of Dry Gas Sampled at Standard Conditions (dscf) 26
Volume of Water Vapor at Standard Conditions (dscf) 27
v
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Table of Contents (continued)
Section Page
Calculation of Moisture/Water Content (as Percent Volume) 27
Calculation of Dry Mole Fraction of Flue Gas 28
Setup of the Dilution Sampling System 28
Pre-Test Leak Check 31
Orifice Flow Check 33
Determination of Test Duration 33
Canister/Veriflow Blanks 33
Determination of Flow Rates 34
Sample Collection Arrays 34
Use of the ELPI Particle Size Distribution Analyzer 37
Operation of the Dilution Sampling System with Sample Collection Arrays 40
Dilution System Sample Collection Arrays Recovery 49
Laboratory Experimental Methodology 51
PM2 5 Mass 51
Elemental Analysis 51
Water-Soluble Inorganic Ions 51
Elemental Carbon/Organic Carbon 52
Organic Compounds 52
Carbonyl Compounds 53
Canister Analysis: Air Toxics and Speciated Nonmethane Organic
Compounds 55
Particle Size Distribution Data 60
Results and Discussion 61
Calculated Emission Factors for PM Mass, Carbonyl Compounds, and
Nonmethane Organic Compounds 62
Gas-Phase Carbonyl Compounds 63
Gas-Phase Air Toxics Whole Air Samples 66
Gas-Phase Speciated Nonmethane Organic Compounds 67
PM2 5 Elemental Carbon/Organic Carbon, Inorganic Ions, and Element Profile 72
Semivolatile Organic Compounds 73
Particle Size Distribution Data 74
Quality Assurance/Quality Control 79
Field Sampling 79
vi
-------
Table of Contents (continued)
Section Page
Carbonyl Compound Analysis 81
Concurrent Air Toxics/Speciated Nonmethane Organic Compound Analysis 83
PM Mass Measurements, Elemental Analysis, Water-Soluble Ion Analysis, and
GC/MS Analysis 85
References 89
Volume 2, Appendices
A Table of Unit Conversions A-l
B Smelt Tank Vent, Chain of Custody Documentation B-l
C Example Calculations: NMOC, Carbonyl, and PM25 Mass Emission Factors .... C-l
D Data Tables for Individual PM25 Mass Measurements D-l
E Data Tables for Individual Carbonyl Samples E-l
F Data Tables for Individual NMOC Samples F-l
G Data Tables for Individual Air Toxics Samples G-l
H Data Tables for Individual PM2 5 Elemental Samples H-l
I Data Tables for Individual PM2 5 EC/OC Samples 1-1
J Data Tables for Individual PM2 5 Inorganic Ion Samples J-l
K Data Tables for Individual Semivolatile Organic Compounds K-l
L List of ERG SOPs and EPA MOPs by Title I.-l
vii
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Term
Nomenclature
Definition
CMB
chemical mass balance
DNPH
2,4-dinitrophenylhydrazine
EC
elemental carbon
ELPI
Electrical Low Pressure Impactor
EPA
U.S. Environmental Protection Agency
ERG
Eastern Research Group
FID
flame ionization detector
GC/MS
gas chromatography/mass spectrometry
GRAV
gravimetric analytical method
HEPA
high efficiency particulate arresting
HPLC
high performance liquid chromatography
IC
ion chromatography
MDLs
method detection limits
MSD
mass selective detector
NAAQS
National Ambient Air Quality Standards
NaOH
sodium hydroxide
Na2C03
sodium carbonate
Na2S
sodium sulfide
Na2S04
sodium sulfate
nh3
ammonia
NMOCs
nonmethane organic compounds
NOx
nitrogen oxides
oc
organic carbon
PM
particulate matter
PM10
PM of aerodynamic diameter 10 |_im or less
pm25
PM of aerodynamic diameter 2.5 |_im or less
PUF
polyurethane foam
RH
relative humidity
SIPs
State Implementation Plans
SOx
sulfur oxides
SNMOCs
speciated nonmethane organic compounds
TOE
thermal-optical evolution
TRS
total reduced sulfur
TSP
total suspended particulate
VOCs
volatile organic compounds
XRF
X-ray fluorescence
viii
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Acknowledgments
Dave-Paul Dayton, Mark Owens, and Robert Martz of Eastern Research Group, Inc.
(ERG) were responsible for conducting sampling at the test site and for preparing collected
samples for transport to the analytical laboratories. Amy Frame, Donna Tedder, and Randy
Bower of ERG were responsible for the carbonyl and volatile organic compound analyses. Joan
Bursey and Raymond Merrill of ERG provided calculations, data analysis, and sections of the
report pertaining to the ERG work on this project. Wendy Morgan of ERG prepared the
typewritten manuscript.
Michael Hays, Kara Linna, and Jimmy Pau of the EPA, NRMRL-RTP, were responsible
for the analysis of organic compounds, elements, and ionic species. Yuanji Dong, John Lee,
David Proffitt, and Tomasz Balicki of ARCADIS, Geraghty & Miller, Inc., provided technical
support in preparing the dilution sampling system and sampling substrates, in performing the
elemental/organic carbon analyses, and in extracting organic compounds from the various
sampling substrates. N. Dean Smith was the EPA Project Officer responsible for overall project
performance.
IX
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Appendix A
Table of Unit Conversions
A-l
-------
Contents
Table Page
Unit Conversion Table A-3
A-2
-------
Unit Conversion Table
Multiply
By
To Obt
atmospheres
101.3
kilopascals
atmospheres
29.92
inches of mercury
atmospheres
760
mm of mercury
atmospheres
33.94
feet of water
atmospheres
14.70
lb/in.2 (psi)
Btu
1054
joules
Btu
2.982 x 10"4
kilowatt-hours
centimeters
0.3937
inches
cm/sec
1.969
ft/min
cm/sec
0.03281
ft/sec
cm/sec
0.036
km/hr
cm/sec
0.6
m/min
cm3
3.53 x 10"2
ft3
cm3
10"3
liters
ft3
0.02832
m3
ft3/min
0.4720
liters per second
in.3
16.39
cm3
m3
35.31
ft3
ft
12
in.
ft
0.3048
m
ft of water
0.8826
in. mercury
grams
0.03527
ounces
inches
2.540
cm
inches of water
0.07355
inches of mercury
kg
2.20462
lb
km
3280.84
ft
km
0.6214
miles
kilowatts
56.92
Btu per min.
liters
0.03531
ft3
liters
61.02
in.3
liters
10"3
m3
liters per minute
5.855 x 10"4
ft3 per second
m
3.28084
ft
(continued)
A-3
-------
Multiply
By
To Obtain
m
39.37
in.
m3
0.02832
ft3
miles
5280
feet
miles
1.6093
km
ounces
28.35
grams
pounds
453.6
grams
pounds per square inch
703.1
kg/m2
cm2
0.1550
in.2
ft2
929.0
cm2
ft2
0.09290
m2
temperature (°C + 273)
1
absolute temperature (K)
temperature (°C + 17.8)
1.8
temperature (°F)
temperature (°F + 460)
1
temperature (°Rankin)
temperature (°F-32)
5/9
temperature (°C)
watts
0.05692
Btu per min.
watts
44.26
foot-pounds per min.
A-4
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APPENDIX B
SMELT TANK VENT
CHAIN OF CUSTODY DOCUMENTATION
B-l
-------
Contents
Table Page
B-l. Sample Log with Sample Identification B-3
B-2. Denuder Sample Log B-4
Substrate Logs B-5
Chain of Custody Records (12/14/01) B-27
Chain of Custody Records (12/15/01) B-42
Chain of Custody Records (12/16/01) B-56
B-2
-------
Table B-l. Sample Log with Sample Identification
Smelt Tank Vent Sample Log
12/14/01 12/15/01 12/16/01
Chamber Port Position Substrate Holder Substrate ID Substrate ID Substrate ID
residence 2
A1
TF
614
T102201J
T102201S
T082101N
B1
TF
618
T102201K
T102201T
T100301A
3
Ml
DNPH
IB121401HR1M1
IB121501HR1M1
IB121601HR1M1
M2
DNPH
IB121401HR1M2
IB121501HR1M2
IB121601HR1M2
4
A1
QF
622
Q101501H*
Q101501T*
Q101601C
A2
PUF
A
P102501A
P102901E
P120401C
A3
PUF
A
P102501B
P102901F
P120401D
A4
PUF
B
P102501C
P102901G
P120401E
A5
PUF
B
P102501D
P102901H
P120401F
B1
QF
640
Q101501K"
Q101501U"
Q101601B"
5
M2
SUMMA
IB121401H-SR5M2
IB121501H-SR5M2
IB121601H-SR5M2
6
A1
TF
633
T102201L
T102201Q
T100301C
B1
TF
642
T102201N
T102201R
T100301D
7
Ml
ELPI
ran time=400 min
ran time=479.6 min
ran time=479.6 min
8
A1
QF
585
Q101501J"
Q101501S"
Q101601D"
A2
PUF
C
P102501E
P102901I
P113001K
A3
PUF
C
P102501F
P102901J
P113001L
A4
PUF
D
P102501G
P102901K
P120401A
A5
PUF
D
P102501H
P102901L
P120401B
B1
QF
641
Q101501L"
Q101501R"
Q101601E"
10
Ml
M2
D
D
see Table B-2
see Table B-2
see Table B-2
A3
QF
610
Q101501M"
Q101501P"
Q101601F"
A4
PUF
G
P102501I
P113001A
P113001G
A5
PUF
G
P102501J
P113001B
P113001H
A6
PUF
H
P102501K
P113001C
P113001I
A7
PUF
H
P101801L
P113001D
P113001J
B3
QF
613
Q101501Nb
Q101501Qb
Q101601Gb
dilution 1
A1
QF
481
Q101501IC
Q101501V0
Q101601A0
A2
PUF
E
P102901A
P102901C
P120401G
A3
PUF
E
P102901B
P102901D
P120401H
B1
TF
564
T102201M
T102201U
T082101M
2
M2
SUMMA
IB121401H-SD2M2
IB121501H-SD2M2
IB121601H-SD2M2
3
Ml
DNPH
IB121401HD3M1
IB121501HD3M1
IB121601HD3M1
M2
DNPH
IB121401HD3M2
IB121501HD3M2
IB121601HD3M2
field blank
QF
Q101501O
IB 121501H-SUM A-FB
IB 121601H-SUMA-FB
TF
T1022010
IB 121501H-DNPH-FB
IB121601H-DNPH-FB
PUF
field
P113001E
PUF
field
P113001F
SUMMA
IB121401H-SUMA-FB
DNPH
IB121401H-DNPH-FB
a All quartz filter samples in Ports 4 and 8 of the residence chamber for the three day smelt tank tests were composited for analysis.
b All quartz filter samples in Port 10 of the residence chamber for th ethree day smelt tank tests were composited for analysis.
c All quartz filter samples from the dilution chamber for the three day tests were composited for analysis.
B-3
-------
Table B-2. Denuder Sample Log
Denuder Sample Log (smelt tank vent)
Pair Position
Denuder
Start End min Start
td
Ml 7:45 8:15 30 D120601-995-1 7:15
M2 D120601-1259-1
Ml 8:18 8:48 30 D120601-1013-1 7:46
M2 D120601-1049-1
Ml 8:50 9:20 30 D120601-1261-1 8:49
M2 D120601-1551-1
Ml 9:22 9:50 28 D120601-995-2 10:51
M2 D120601-1259-2
Ml 9:51 10:20 29 D120601-1013-2
M2 D120601-1049-2
Ml 10:21 10:51 30 D120601-1261-2
4^ M2 D120601-1551-2
7 Ml 10:53 11:19 26 D120601-995-3
M2 D120601-1259-3
8 Ml 11:30 12:00 30 D120601-1013-3
M2 D120601-1049-3
9 Ml 12:01 12:30 29 D120601-1261-3
M2 D120601-1551-3
10 Ml 12:31 13:01 30 D120601-995-4
M2 D120601-1259-4
11 Ml 13:02 13:32 30 D120601-1013-4
M2 D120601-1049-4
12 Ml 13:34 14:04 30 D120601-1261-4
M2 D120601-1551-4
13 Ml 14:06 14:36 30 D120601-995-5
M2 D120601-1259-5
Denuder
Denuder
End
min
Start End min
7:45
8:46
10:49
14:51
30
60
D120601-
D120601-
D120601-
D120601-
120 D120601-
D120601-
240 D120601-
D120601-
1261-5
1551-5
1013-5
1049-5
995-6
1259-6
1261-6
1551-6
7:15 7:45
7:47 8:47
8:49 10:49
10:50 14:50
30
60
D120601-
D120601-
D120601-
D120601-
120 D120601-
D120601-
240 D120601 ¦
D120601-
995-7
1259-7
1013-6
1049-6
1261-7
1551-7
995-8
1259-8
-------
CLEAN SUBSTRATES
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61
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Q101501A
Q101501B
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Q101501E
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B-6
-------
CLEAN SUBSTRATES
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12
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18
19
20
21
22
23
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29
30
31
32
33
34
35
36
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38
39
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TF
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TF
TF
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Substrate !D
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T1002018
T100201C
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T100201E
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T100201V
T100201W
T100201X
T100201Y
T100201Z
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-------
CLEAN SUBSTRATES
Date Substrate Distributed
To Whom Substrate Distributed
FPMCC Lab Personnel
10/25/2001
Tom
Yuanji
No
Type
Substrate ID
Test 10
Sampling Position
Chamber
Port
Position
Holder
41
TF
T102201Q
+~r> h f ci h-
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45
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T102201U
;
-------
CLEAN SUBSTRATES
Page 5
i Subctratt Distributed
To Whom Substrate Distribute
FPMCC Lab Purswnnal
togszoot
Tom
Yuanji
fct
PM
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Type
Substrate ID
Taat 10
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Chamber
Port
Position
Hcscr
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0C71900-995-5
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B-9
-------
CLEAN SUBSTRATES
Page 6
Gm Sutatwto Dtatrtbutad
To Whom Substrate Distributed
FPHCC Lab Pereonn#!
10/25/2001
Tom
Yuanjl
Position
Sampling
Test ID
Substrate ID
Holder
Chmnber
Position
!G2$C(h'
PI 01701A
P101701B
P1Q1701C
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PI 01701E
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P101701S
P101701T
P101701U
701V
P101701W
[[Bto
P101701X
PI01801A
P1018018
P101801C
P1018010
P101801E
-------
CLEAN SUBSTRATES
Page 7
Onto Substrata Distributed
To Whom Substrata Distributed
PPMCC Lab Pursoiwisl
10/25/2001
Tom
Yuanjt
No
Type
Substrate ID
iri
Samclinq
Position
Chamber
Port
Position
Holder
41
PUF
P101901E
¦z.
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42
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46
PUF
P101301J
H
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-------
CLEAN SUBSTRATES
Mi Substrata Otetrfbutad
To Whom Substrate OiifrllMrtwi
FPMCC Lab P«rs»w»l
3
1Q/25/2001
Tom
Yuanjl
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Chamber
Port
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81
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82
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B-12
-------
CLEAN SUBSTRATES
Date Subctrate Distributed
To Whom Substrate Distributed
FPMCC Lab Personnel
11/30/2001
Yuansi
No
Type
Subsets IE
Test ID
Sampling Position
Chamber
Port
Position
Holder
1
PUF
P112901A
J/l X'tOf/f
4
I
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2
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3
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r&r^
B-13
-------
CLEAN SUBSTRATES
Date Substrate Distributed
To Whom Substrate Distributed
PPMCC Lab Psraonnul
12/312001
Typ«
PUF
PUF
Substrata ID
P113001A
P113001B
Test ID
"^ifCfeTW'
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Port
Position
/
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PUF
P113001C
4
~
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P113001D
PUF
P113001E
PUF
P113001F
PUF
P113001G
PUF
P113001H
PUF
P1130011
PUF
P113001J
PUP
PUF
P113001K
P1130C1L
4-rlZt^e; .~+
I
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B-14
-------
CLEAN SUBSTRATES
P»se
Date Substrate Distributed
To Whom Substrate Ototrtbutsd
FPMCC Lab Parsonnel
12/5/2001
Tom
Yuanjt
No
Type
Substrate JD
TastlO
Sampling Position
Chamber
Port
Position
Holder
1
PUF
P120401A
srt zifoi t-f
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7
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9
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10
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P*20401J
11
PUF
P120401K
12
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1
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B-15
-------
CLEAN SUBSTRATES
Pag« 12
Bate Subatrata Distributed
To Whom Subatrala Distributed
FPMCC Lab Personnel
wmmmi
No
Type
Substrate ID
Tast 10
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Chamber
Port 1 Position
Holder
121
\ oil
A102001U
122
A1 foil
A102001V
123
Al foil
A102001W
124
Ai foil
A102001X
125
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A102001Y
12S
Al foil
A102101A
127
Al foil
Al 021018
128
Al foil
A102101C
129
Ai foil
A102101D
1
130
Ai foil
A102101E
1
131
Al foil
A1Q2101F
1
132
At foil
A102101G
1
133
Ai foil
A102101H
I
134
A! foil
A1021011
1
135
Al foil
A10210*J
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3
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B-16
-------
CLEAN SUBSTRATES
Pag« 9
Date Substrate Distributed
To Whom Substrate Distributed
FPMCC Lab Personnel
10/2S2001
Torn
Yuan}!
10
11
12
13
14
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Type
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Al toil
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A! foil
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A101701E
A101701F
A101701G
A1Q1701H
A1017011
A101701J
A101701K
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16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
33
34
3S
36
3?
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A1017Q1P
A! foil
A1Q1701Q
Al foil
AID"1701 ft
Al foil
A101701S
Al foil
A1017Q1T
AI foil
A1Q170HJ
Al foil
A101701V
Al foil
AI foil
At foil
Ai foil
Al foil
Al foil
Al foil
Al foil
Ai foil
Al foil
Al foil
Al foil
Al foil
Al foil
Al foil
A1Q1701W
A101701X
A101701Y
A101S01A
A101601B
A101601C
A101601D
f
A101601E
A1Q1S01F
A101601G
A101601H
A1016011
A101601J
A1016O1K
Al foil
AJ foil
Al foil
A1016Q1L
A101601M
A101601N
A1016010
"7"
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B-17
-------
CLEAN SUBSTRATES
Date Substrate Distributed
To Whom Substrate Distributed
FPMCC Lab Personnel
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Tom
Yuanji
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Substrata 10
, „Test ID
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Port
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41
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A1Q1601P
42
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A101S010
43
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44
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A"! 01601S
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45
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A1Q1601T
t/
46
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A1Q1SQ1U
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47
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A101501V
~
48
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A101801W
iS
49
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A1Q1S01X
1S
50
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i A*016{TY
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51
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A101801A
52
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A1018018
53
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A10'801C
1
54
Al foil
A1018Q1D
55
Al foil
A10T801E
56
Al foil
A10180TF
57
Al foii
A101801G
58
Al foil
A101801H
59
Al fori
¦- ¦¦18011
60
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A10130U
81
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A101S01K
" S2
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Al 018011
83
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A1O1801M
64
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A101801N
65
Al foil
A1018015
66
Al foil
A101801P
87
Al fort
A101801Q
88
Al foil
A101801R
Al foil
A101B01S
70
Al foil
A101801T
71
Al foil
A101801U
72
Al foil
A101801V
73
Al toil
A101801W
74
Al foil
A101801X
75
Al foil
A1O10O1Y
76
AJ foil
A101901A
77
Al foil
A1019018
78
Al foil
A101901C
79
Al foil
A1019010
80
Ai foil
A101901E
1
B-18
-------
CLEAN SUBSTRATES
Pag* 11
Oat* Subsfrafe Distributed . I.QffiSfflOOl
To Whom Substrate Di«trfbut«d Tom „
FPMCC Lab Personnel Yuanj
No
Type
Substrate ID
Test tO
Sampling Position
Chamber
Port
Position
Holder
81
At fori
A1019Q1F
82
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A101901G
33
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A101901H
84
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Al019011
35
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A10130U
86
Al foil
A101901K
87
Ai foil
A101901L
88 j At-foil
A101901M
89 | At
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Appendix C
Example Calculations: NMOC, Carbonyl,
and PM25 Mass Emission Factors
c-i
-------
Contents
Table Page
C-l. Calculation of Mass Emission Rates: Speciated NMOC (SNMOC),
Smelt Tank Vent (12/14/01) C-3
C-2. Calculation of Mass Emission Rates: Speciated NMOC (SNMOC),
Smelt Tank Vent (12/15/01) C-4
C-3. Calculation of Mass Emission Rates: Speciated NMOC (SNMOC),
Smelt Tank Vent (12/16/01) C-5
C-4. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred)
NMOC, Smelt Tank Vent (12/14/01) C-6
C-5. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred)
NMOC, Smelt Tank Vent (12/15/01) C-l
C-6. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred)
NMOC, Smelt Tank Vent (12/16/01) C-8
C-l. Calculation of Mass Emission Rates: Speciated Carbonyls, Smelt Tank
Vent (12/14/01) C-9
C-8. Calculation of Mass Emission Rates: Speciated Carbonyls, Smelt Tank
Vent (12/15/01) C-10
C-9. Calculation of Mass Emission Rates: Speciated Carbonyls, Smelt Tank
Vent (12/16/01) C-l 1
C-10. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred)
Carbonyls, Smelt Tank Vent (12/14/01) C-12
C-l 1. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred)
Carbonyls, Smelt Tank Vent (12/15/01) C-13
C-12. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred)
Carbonyls, Smelt Tank Vent (12/16/01) C-14
C-13. Calculation of PM Emission Factors (12/14/01) C-15
C-14. Calculation of PM Emission Factors (12/15/01) C-16
C-15. Calculation of PM Emission Factors (12/16/01) C-17
C-16. Calculation of Individual Filter PM Emission Factors (12/14/01) C-18
C-17. Calculation of Individual Filter PM Emission Factors (12/15/01) C-19
C-18. Calculation of Individual Filter PM Emission Factors (12/16/01) C-20
C-2
-------
Table C-l. Calculation of Mass Emission Rates: Speciated NMOC (SNMOC), Smelt Tank
Vent (12/14/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
0.16926
Hg
Mass fuel consumed
1,016,465
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
400
min
Average venturi flow rate
22.5
sL/min
Average dilution air flow rate
841.73
sL/min
Flow rate at sample collection unit
0.00975
L/min
Calculations
Total volume of air sampled 266,636,007.8000
L
Volume of combustion air sampled
9000
L
Volume of dilution air
336,692
L
Dilution ratio
38.4102
Mass flow rate of SNMOC in diluted sample
0.0434
Hg/L
Mass flow rate of SNMOC in undiluted sample
1.6670
Hg/L
Total mass of SNMOC in sampled air
15,003.0328
Hg
SNMOC in total combustion air
377,803,051
Hg
Mass emission rate of SNMOC
371.633
Mg/kg
Mass emission rate of SNMOC
0.3717
mg/kg
Mass SNMOC Collected
Volume canister = flow rate into canister x test duration
Parameter Value Units
Volume
Units
Test duration 400.0 min
Flow rate, dilution air canister 0.009750 L/min
3.9000
L
Flow rate, residence chamber canister 0.009750 L/min
3.9000
L
Mass SNMOC collected = SNMOC concentration x canister volume
Parameter Value Units
Mass
Units
SNMOC residence chamber 0.06751 |jg/L
0.2633
Hg
SNMOC dilution air 0.02411 |ig/L
0.0940
Hg
Mass SNMOC collected
0.1693
Residence chamber 67.51 |ig/m3
Dilution air 24.11 nig/m3
Note: Contaminants (w-hexane and acetone) deleted from data 12/14/01.
C-3
-------
Table C-2. Calculation of Mass Emission Rates: Speciated NMOC (SNMOC), Smelt Tank
Vent (12/15/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
0.281363
Hg
Mass fuel consumed
916,019
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
479.4
min
Average venturi flow rate
23.2
sL/min
Average dilution air flow rate
851.97
sL/min
Flow rate at sample collection unit
0.008136
L/min
Calculations
Total volume of air sampled 271,623,255.4000
L
Volume of combustion air sampled
11,122.0800
L
Volume of dilution air
408,434.4180
L
Dilution ratio
37.7228
Mass flow rate of SNMOC in diluted sample
0.0721
Hg/L
Mass flow rate of SNMOC in undiluted sample
2.7212
Hg/L
Total mass of SNMOC in sampled air
30,265.5429
Hg
SNMOC in total combustion air 739,144,591.4000
Hg
Mass emission rate of SNMOC
806.9101
Mg/kg
Mass emission rate of SNMOC
0.8069
mg/kg
Mass SNMOC Collected
Volume canister = flow rate into canister x test duration
Parameter Value Units
Volume
Units
Test duration 479.38 min
Flow rate, dilution air canister 0.008136 L/min 3.9002 L
Flow rate, residence chamber canister 0.008136 L/min 3.9002 L
Mass SNMOC collected = SNMOC concentration x canister volume
Parameter Value Units Mass Units
SNMOC residence chamber
0.10706
y.g/L
0.4176
Hg
SNMOC dilution air
0.03495
Hg/L
0.1362
Hg
Mass SNMOC collected
0.2814
34.95 ug/i
C-4
-------
Table C-3. Calculation of Mass Emission Rates: Speciated NMOC (SNMOC), Smelt Tank
Vent (12/16/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
0.1509
Hg
Mass fuel consumed
1,127,456
kg
Average combustion air flow rate
20,009
sft3/m
Run time
479.58
min
Average venturi flow rate
22.91
sL/min
Average dilution air flow rate
856.03
sL/min
Flow rate at sample collection unit
0.0090
L/min
Calculations
Total volume of air sampled 271,725,241.6000
L
Volume of combustion air sampled
10,987.1778
L
Volume of dilution air
410,534.8674
L
Dilution ratio
38.3649
Mass flow rate of SNMOC in diluted sample
0.0351
Hg/L
Mass flow rate of SNMOC in undiluted sample
1.3464
Hg/L
Total mass of SNMOC in sampled air
14,792.7778
Hg
SNMOC in total combustion air 365,842,002.5000
Hg
Mass emission rate of SNMOC
324.4845
Mg/kg
Mass emission rate of SNMOC
0.3245
mg/kg
Mass SNMOC Collected
Volume canister = flow rate into canister x test duration
Parameter Value Units
Volume
Units
Test duration 479.58 min
Flow rate, dilution air canister 0.009383 L/min 4.4999 L
Flow rate, residence chamber canister 0.008966 L/min 4.2999 L
Mass SNMOC collected = SNMOC concentration x canister volume
Parameter Value Units Mass Units
SNMOC residence chamber
0.05931
y.g/L
0.2550
Hg
SNMOC dilution air
0.02314
Hg/L
0.1041
Hg
Mass SNMOC collected
0.1509
Residence chamber
59.31
|ig/m3
Dilution air
23.14
Us/m3
C-5
-------
Table C-4. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred) NMOC,
Smelt Tank Vent (12/14/01)
Quantity Value Units
Parameters Required
Mass of analyte in total combustion air
0.40092
Hg
Mass fuel consumed
1,016,465
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
400.
min
Average venturi flow rate
22.5
sL/min
Average dilution air flow rate
841.73
sL/min
Flow rate at sample collection unit
0.0098
L/min
Calculations
Total volume of air sampled
226,636,008
L
Volume of combustion air sampled
9000
L
Volume of dilution air
336,692
L
Dilution ratio
38.4102
Mass flow rate of total NMOC in diluted sample
0.1028
Hg/L
Mass flow rate of NMOC in undiluted sample
3.9486
Hg/L
Total mass of total NMOC in sampled air
35,537.1376
Hg
Total NMOC in total combustion air
894,888,333
Hg
Mass emission rate of total NMOC
880.3927
Mg/kg
Mass emission rate of total NMOC
0.8803927
mg/kg
Mass Total NMOC Collected
Volume canister = flow rate into canister x test duration
Parameter Value Units
Volume
Units
Test duration 400. min
Flow rate, dilution air canister 0.00975 L/min
3.9000
L
Flow rate, residence chamber canister 0.00975 L/min
3.9000
L
Mass Total NMOC collected = Total NMOC concentration x canister volume
Parameter Value Units
Mass
Units
Total NMOC residence chamber 0.13030 |ig/L
0.5082
Hg
Total NMOC dilution air 0.02750 |ig/L
0.1073
Hg
Mass Total NMOC collected
0.4009
27.50 ug/i
C-6
-------
Table C-5. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred) NMOC,
Smelt Tank Vent (12/15/01)
Quantity Value Units
Parameters Required
Mass of analyte in total combustion air
0.496422
Hg
Mass fuel consumed
916,019
kg
Average combustion air flow rate
20,008.935
sft3/m
Run time
479.4
min
Average venturi flow rate
23.2
sL/min
Average dilution air flow rate
851.97
sL/min
Flow rate at sample collection unit
0.0081
L/min
Calculations
Total volume of air sampled
271,623,255
L
Volume of combustion air sampled
11,122.0800
L
Volume of dilution air
408,434.4200
L
Dilution ratio
37.7229
Mass flow rate of total NMOC in diluted sample
0.1273
Hg/L
Mass flow rate of total NMOC in undiluted sample
4.8012
Hg/L
Total mass of total NMOC in sampled air
53,398.9240
Hg
Total NMOC in total combustion air
1,304,117,572
Hg
Mass emission rate of total NMOC
1423.6695
Mg/kg
Mass emission rate of total NMOC
1.4237
mg/kg
Mass Total NMOC Collected
Volume canister = flow rate into canister x test duration
Parameter Value
Units
Volume
Units
Test duration 479.38
min
Flow rate, dilution air canister 0.008136
L/min
3.9002
L
Flow rate, residence chamber canister 0.008136
L/min
3.9002
L
Mass Total NMOC collected = Total NMOC concentration x
canister volume
Parameter Value
Units
Mass
Units
Total NMOC residence chamber 0.16925
Hg/L
0.6601
Hg
Total NMOC dilution air 0.04197
Hg/L
0.1637
Hg
Mass Total NMOC collected
0.4964
Hg
Residence chamber 169.25 |lg/m3
Dilution air 41.97 ug/m3
C-7
-------
Table C-6. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred) NMOC,
Smelt Tank Vent (12/16/01)
Quantity Value Units
Parameters Required
Mass of analyte in total combustion air
0.3550
Hg
Mass fuel consumed
1,127,456
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
479.5800
min
Average venturi flow rate
22.91
sL/min
Average dilution air flow rate
856.03
sL/min
Flow rate at sample collection unit
0.0090
L/min
Calculations
Total volume of air sampled
271,725,242
L
Volume of combustion air sampled
10,987.1778
L
Volume of dilution air
410,534.8670
L
Dilution ratio
38.3649
Mass flow rate of total NMOC in diluted sample
0.0826
Hg/L
Mass flow rate of total NMOC in undiluted sample
3.1671
Hg/L
Total mass of total NMOC in sampled air
34,797.4365
Hg
Total NMOC in total combustion air
860,579,670
Hg
Mass emission rate of total NMOC
763.2934
Mg/kg
Mass emission rate of total NMOC
0.7633
mg/kg
Mass Total NMOC Collected
Volume canister = flow rate into canister x test duration
Parameter Value Units
Volume
Units
Test duration 479.58 min
Flow rate, dilution air canister 0.009383 L/min
4.4999
L
Flow rate, residence chamber canister 0.008966 L/min
4.2999
L
Mass Total NMOC collected = Total NMOC concentration x canister volume
Parameter Value Units
Mass
Units
Total NMOC residence chamber 0.10996 |ig/L
0.4728
Hg
Total NMOC dilution air 0.02619 |ig/L
0.1179
Hg
Mass TotalNMOC collected
0.3550
Residence chamber 109.96 |ig/m3
Dilution air 23.14 nig/m3
C-8
-------
Table C-7. Calculation of Mass Emission Rates: Speciated Carbonyls, Smelt Tank Vent
(12/14/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
Mass fuel consumed
Average combustion air flow rate
Run time
Average venturi flow rate
Average dilution air flow rate
Flow rate at sample collection unit
Calculations
Total volume of air sampled
Volume of combustion air sampled
Volume of dilution air
Dilution ratio
Mass flow rate of speciated carbonyls in diluted sample
Mass flow rate of speciated carbonyls in undiluted sample
Total mass of speciated carbonyls in sampled air
Total speciated carbonyls in total combustion air
Mass emission rate of total speciated carbonyls
Mass emission rate of total speciated carbonyls
4.3690
1,016,465
20,008.9353
400.
22.5
841.73
0.73
226,636,007.8000
9000
336,692
38.4102
0.0150
0.5771
5194.0586
130,795,632.9
128.6770
0.1287
Hg
kg
sft3/m
min
sL/min
sL/min
L/min
L
L
L
Hg/L
Hg/L
Hg
Hg
Mg/kg
msfcs
C-9
-------
Table C-8. Calculation of Mass Emission Rates: Speciated Carbonyls, Smelt Tank Vent
(12/15/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
17.7180
Hg
Mass fuel consumed
916,019
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
479.4
min
Average venturi flow rate
23.2
sL/min
Average dilution air flow rate
851.97
sL/min
Flow rate at sample collection unit
0.81
L/min
Calculations
Total volume of air sampled
271,623,255.4000
L
Volume of combustion air sampled
11,122.0800
L
Volume of dilution air
408,434.4180
L
Dilution ratio
37.7228
Mass flow rate of speciated carbonyls in diluted sample
0.04566
Hg/L
Mass flow rate of speciated carbonyls in undiluted sample
1.7225
Hg/L
Total mass of speciated carbonyls in sampled air
19,157.5113
Hg
Total speciated carbonyls in total combustion air
467,864,426.7000
Hg
Mass emission rate of speciated carbonyls
Mass emission rate of speciated carbonyls
510.7587
0.5108
Mg/kg
mg/kg
C-10
-------
Table C-9. Calculation of Mass Emission Rates: Speciated Carbonyls, Smelt Tank Vent
(12/16/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
Mass fuel consumed
Average combustion air flow rate
Run time
Average venturi flow rate
Average dilution air flow rate
Flow rate at sample collection unit
Calculations
Total volume of air sampled
Volume of combustion air sampled
Volume of dilution air
Dilution ratio
Mass flow rate of speciated carbonyls in diluted sample
Mass flow rate of speciated carbonyls in undiluted sample
Total mass of speciated carbonyls in sampled air
Total speciated carbonyls in total combustion air
Mass emission rate of total speciated carbonyls
Mass emission rate of total speciated carbonyls
8.3460
1,127,456
20,008.9353
479.58
22.91
856.03
0.84
271,725,242
10,987.1778
410,534.8670
38.3649
0.02079
0.7975
8762.2293
216,699,768
192.2024
0.1922
Hg
kg
sft3/m
min
sL/min
sL/min
L/min
L
L
L
Hg/L
Hg/L
Hg
Hg
Mg/kg
msfcs
C-ll
-------
Table C-10. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred) Carbonyls,
Smelt Tank Vent (12/14/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
5.6075
Hg
Mass fuel consumed
1,016,465
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
400.
min
Average venturi flow rate
22.5
sL/min
Average dilution air flow rate
841.73
sL/min
Flow rate at sample collection unit
0.73
L/min
Calculations
Total volume of air sampled
226,636,007.8000
L
Volume of combustion air sampled
9000
L
Volume of dilution air
336,692
L
Dilution ratio
38.4102
Mass flow rate of total carbonyls in diluted sample
0.0193
Hg/L
Mass flow rate of total carbonyls in undiluted sample
0.7407
Hg/L
Total mass of total carbonyls in sampled air
6666.4416
Hg
Total carbonyls in total combustion air
167,872,856.9
Hg
Mass emission rate of total carbonyls
Mass emission rate of total carbonyls
165.1536
0.1652
Mg/kg
mg/kg
C-12
-------
Table C-l 1. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred) Carbonyls,
Smelt Tank Vent (12/15/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
20.035
Hg
Mass fuel consumed
916,019
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
479.4
min
Average venturi flow rate
23.2
sL/min
Average dilution air flow rate
851.97
sL/min
Flow rate at sample collection unit
0.81
L/min
Calculations
Total volume of air sampled
271,623,255.4000
L
Volume of combustion air sampled
11,122.0800
L
Volume of dilution air
408,434.4180
L
Dilution ratio
37.7228
Mass flow rate of total carbonyls in diluted sample
0.05163
Hg/L
Mass flow rate of total carbonyls in undiluted sample
1.9477
Hg/L
Total mass of total carbonyls in sampled air
21,662.7576
Hg
Total carbonyls in total combustion air
529,047,510.4000
Hg
Mass emission rate of total carbonyls
Mass emission rate of total carbonyls
577.5511
0.5776
Mg/kg
mg/kg
C-13
-------
Table C-12. Calculation of Mass Emission Rates: Total (Speciated + Unspeciatred) Carbonyls,
Smelt Tank Vent (12/16/01)
Quantity
Value
Units
Parameters Required
Mass of analyte in total combustion air
9.2310
Hg
Mass fuel consumed
1,127,456
kg
Average combustion air flow rate
20,008.9353
sft3/m
Run time
479.58
min
Average venturi flow rate
22.91
sL/min
Average dilution air flow rate
856.03
sL/min
Flow rate at sample collection unit
0.84
L/min
Calculations
Total volume of air sampled
271,725,242
L
Volume of combustion air sampled
10,987.1778
L
Volume of dilution air
410,534.8670
L
Dilution ratio
38.3649
Mass flow rate of total carbonyls in diluted sample
0.02230
Hg/L
Mass flow rate of total carbonyls in undiluted sample
0.8821
Hg/L
Total mass of total carbonyls in sampled air
9691.3658
Hg
Total carbonyls in total combustion air
239,678,356
Hg
Mass emission rate of total carbonyls
Mass emission rate of total carbonyls
212.5833
0.2126
Mg/kg
mg/kg
C-14
-------
Table C-13. Calculation of PM Emission Factors (12/14/01)
Test
12/14/01 (ave)
1
Sampling time (min)
400
2
TF sample
T102201J T102201K T102201L T102201N
3
PM mass on filter (mg)
1.743 1.705 1.684
1.757
4
Array flow (sL/min)
8.528 8.528 8.566
8.566
5
PM concentration at filter (mg/L)
0.000511 0.000500 0.000491 0.000513
6a
avg. PM concentration at filter (mg/L)
0.000504
6b
PM mass on dilution chamber filter (mg)
0.002
6c
Array flow (sL/min)
8.528
6d
PM concentration at dilution air (mg/L)
0.000001
6e
Net PM mass concentration after dilution (mg/L)
0.000503
7
Probe flow (sL/min)
22.67
8
Probe flow (m3)
9.07
9
Dilution air (sL/min)
841.28
10
Dilution air (m3)
336.51
11
Dilution ratio
38.11
12
PM concentration at stack (mg/L)
0.0192
13
Stack gas velocity (ft/min)
1021
14
Stack temperature (°F)
160.1
15
Stack pressure (in. Hg)
29.882
16
Stack area (ft2)
23.0438
17
Stack flow (sftVmin)
20,007.8
18
Stack flow (sL/min)
566,621.9
19
PM emission rate from stack (mg/min)
10,865.5
20
Fuel type
Black Liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
491.43
0
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
2540.7
0.0
25
Fuel mass feed rate (lb/min)
5602.3
0.0
26
Fuel heating value (Btu/lb)
4208
19374
27
Fuel heat feed rate (Btu/min)
23,574,486.8
0.0
28
Total fuel mass feed rate (kg/min)
2540.7
29
Emission factor (mg/kg)
4.28
30
Total fuel heat feed rate (Btu/min)
23,574,486.82
31
Emission factor (us/kJ)
0.44
Stage Time Venturi Total Time Fraction of Time in Stage
1 213.8 215 400 0.5345
2 186.2 22.87 0.4655
C-15
-------
Table C-14. Calculation of PM Emission Factors (12/15/01)
Test
12/15/2001 (ave)
1
Sampling time (min)
479.4
2
TF sample T102201S T102201T T102201Q T102201R
3
PM mass on filter (mg) 2.867 2.979 2.978 2.999
4
Array flow (sL/min) 8.:
541 8.541 8.541 8.541
5
PM concentration at filter (mg/L) 0.000700 0.000728 0.000727 0.000732
6a
avg. PM concentration at filter (mg/L)
0.000722
6b
PM mass on dilution chamber filter (mg)
0.000
6c
Array flow (sL/min)
8.466
6d
PM concentration at dilution air (mg/L)
0.000000
6e
Net PM mass concentration after dilution (mg/L)
0.000722
7
Probe flow (sL/min)
23.20
8
Probe flow (m3)
11.12
9
Dilution air (sL/min)
851.97
10
Dilution air (m3)
408.43
11
Dilution ratio
37.72
12
PM concentration at stack (mg/L)
0.0272
13
Stack gas velocity (ft/min)
1021
14
Stack temperature (°F)
160.1
15
Stack pressure (in. Hg)
29.882
16
Stack area (ft2)
23.0438
17
Stack flow (sft3/min)
20,007.8
18
Stack flow (sL/min)
566,621.9
19
PM emission rate from stack (mg/min)
15,429.7
20
Fuel type
Black Liquor #2 Oil
21
Fuel volumetric feed (gal/min)
356.93 20.43
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17 3.19
24
Fuel mass feed rate (kg/min)
1845.4 65.2
25
Fuel mass feed rate (lb/min)
4069.0 143.7
26
Fuel heating value (Btu/lb)
4208 19,374
27
Fuel heat feed rate (Btu/min)
17,122,360.4 2,784,113.5
28
Total fuel mass feed rate (kg/min)
1910.5
29
Emission factor (mg/kg)
8.08
30
Total fuel heat feed rate (Btu/min)
19,906,473.93
31
Emission factor (|ig/kJ)
0.73
C-16
-------
Table C-15. Calculation of PM Emission Factors (12/16/01)
Test
12/16/2001 (ave)
1
Sampling time (min)
479.58
2
TF sample T082101N T100301A T100301C T100301D
3
PM mass on filter (mg) 2.725 2.706 2.743
2.806
4
Array flow (sL/min) 8.
586 8.586 8.662
8.662
5
PM concentration at filter (mg/L) 0.000662 0.000657 0.000660 0.000675
6a
avg. PM concentration at filter (mg/L)
0.000664
6b
PM mass on dilution chamber filter (mg)
0.005
6c
Array flow (sL/min)
8.700
6d
PM concentration at dilution air (mg/L)
0.000001
6e
Net PM mass concentration after dilution (mg/L)
0.000662
7
Probe flow (sL/min)
22.91
8
Probe flow (m3)
10.99
9
Dilution air (sL/min)
856.03
10
Dilution air (m3)
410.53
11
Dilution ratio
38.36
12
PM concentration at stack (mg/L)
0.0254
13
Stack gas velocity (ft/min)
1021
14
Stack temperature (°F)
160.1
15
Stack pressure (in. Hg)
29.882
16
Stack area (ft2)
23.0438
17
Stack flow (sft3/min)
20,007.8
18
Stack flow (sL/min)
566,621.9
19
PM emission rate from stack (mg/min)
14,401.3
20
Fuel type
Black Liquor
#2 Oil
21
Fuel volumetric feed (gal/min)
454.54
0
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17
3.19
24
Fuel mass feed rate (kg/min)
2350.0
0.0
25
Fuel mass feed rate (lb/min)
5181.8
0.0
26
Fuel heating value (Btu/lb)
4208
19,374
27
Fuel heat feed rate (Btu/min)
21,804,829.2
0.0
28
Total fuel mass feed rate (kg/min)
2350.0
29
Emission factor (mg/kg)
6.13
30
Total fuel heat feed rate (Btu/min)
21804829.25
31
Emission factor (ug/kJ)
0.63
C-17
-------
Table C-16. Calculation of Individual Filter PM Emission Factors (12/14/01)
12/14/2001
Test (individual filters)
1
Sampling time (min)
400
2
TF sample
T102201J
T102201K T102201L T102201N
3
PM mass on filter (mg)
1.743
1.705 1.684 1.757
4
Array flow (sL/min)
8.528
8.528 8.566 8.566
5
PM concentration at filter (mg/L)
0.000511
0.000500 0.000491 0.000513
6b
PM mass on dilution chamber filter (mg)
0.002
6c
Array flow (sL/min)
8.528
6d
PM concentration at dilution air (mg/L)
0.000001
6e
Net PM mass concentration after dilution (mg/L)
0.000510
0.000499 0.000491 0.000512
7
Probe flow (sL/min)
22.67
8
Probe flow (m3)
9.07
9
Dilution air (sL/min)
841.28
10
Dilution air (m3)
336.51
11
Dilution ratio
38.11
12
PM concentration at stack (mg/L)
0.0195
0.0190 0.0187 0.0195
13
Stack gas velocity (ft/min)
1021
14
Stack temperature (°F)
160.1
15
Stack pressure (in. Hg)
29.882
16
Stack area (ft2)
23.0438
17
Stack flow (sft3/min)
20,007.8
18
Stack flow (sL/min)
566,621.9
19
PM emission rate from stack (mg/min)
11,021.0
10,780.5 10,600.2 11,060.3
20
Fuel type
Black Liquor #2 Oil
21
Fuel volumetric feed (gal/min)
491.43 0
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17 3.19
24
Fuel mass feed rate (kg/min)
2540.7 0.0
25
Fuel mass feed rate (lb/min)
5602.3 0.0
26
Fuel heating value (Btu/lb)
4208 19,374
27
Fuel heat feed rate (Btu/min)
23,574,486.8 0.0
28
Total fuel mass feed rate (kg/min)
2540.7
29
Emission factor (mg/kg)
4.34
4.24 4.17 4.35
30
Total fuel heat feed rate (Btu/min)
23,574,486.82
31
Emission factor (|ig/kJ)
0.44
0.43 0.43 0.44
32
Ave. Emission Factor (mg/kg)
4.28
33
Ave. Emission Factor (ng/kJ)
0.44
C-18
-------
Table C-17. Calculation of Individual Filter PM Emission Factors (12/15/01)
12/15/2001
Test (individual filters)
1
Sampling time (min)
479.4
2
TF sample
T102201S
T102201T T102201Q
T102201R
3
PM mass on filter (mg)
2.867
2.979 2.978
2.999
4
Array flow (sL/min)
8.541
8.541 8.541
8.541
5
PM concentration at filter (mg/L)
0.000700
0.000728 0.000727
0.000732
6b
PM mass on dilution chamber filter (mg)
0.000
6c
Array flow (sL/min)
8.466
6d
PM concentration at dilution air (mg/L)
0.00000
6e
Net PM mass concentration after dilution (mg/L)
0.000700
0.000728 0.000727
0.000732
7
Probe flow (sL/min)
23.20
8
Probe flow (m3)
11.12
9
Dilution air (sL/min)
851.97
10
Dilution air (m3)
408.43
11
Dilution ratio
37.72
12
PM concentration at stack (mg/L)
0.0264
0.0274 0.0274
0.0276
13
Stack gas velocity (ft/min)
1021
14
Stack temperature (°F)
160.1
15
Stack pressure (in. Hg)
29.882
16
Stack area (ft2)
23.0438
17
Stack flow (sft3/min)
20,007.8
18
Stack flow (sL/min)
566,621.9
19
PM emission rate from stack (mg/min)
14,966.4
15,551.1 15,545.9
15,655.5
20
Fuel type
Black Liquor #2 Oil
21
Fuel volumetric feed (gal/min)
356.93 20.43
22
Fuel density (lb/gal)
11.4
23
Fuel density (kg/gal)
5.17 3.19
24
Fuel mass feed rate (kg/min)
1845.4 65.2
25
Fuel mass feed rate (lb/min)
4069.0 143.7
26
Fuel heating value (Btu/lb)
4208 19,374
27
Fuel heat feed rate (Btu/min)
17,122,360.4 2,784,113.5
28
Total fuel mass feed rate (kg/min)
1910.5
29
Emission factor (mg/kg)
7.83
8.14 8.14
8.19
30
Total fuel heat feed rate (Btu/min)
19,906,473.93
31
Emission factor (|ig/kJ)
0.71
0.74 0.74
0.75
32
Ave. Emission Factor (mg/kg)
8.08
33
Ave. Emission Factor (ng/kJ)
0.73
C-19
-------
Table C-18. Calculation of Individual Filter PM Emission Factors (12/16/01)
12/16/2001
Test (individual filters)
1 Sampling time (min) 479.58
2 TF sample T082101N T100301A T100301C T100301D
3 PM mass on filter (mg) 2.725 2.706 2.743 2.806
4 Array flow (sL/min) 8.586 8.586 8.662 8.662
5 PM concentration at filter (mg/L) 0.000662 0.000657 0.000660 0.000675
6b PM mass on dilution chamber filter (mg) 0.005
6c Array flow (sL/min) 8.700
6d PM concentration at dilution air (mg/L) 0.000001
6e Net PM mass cone after dilution (mg/L) 0.000661 0.000656 0.000659 0.000674
7 Probe flow (sL/min) 22.91
8 Probe flow (m3) 10.99
9 Dilution air (sL/min) 856.03
10 Dilution air (m3) 410.53
11 Dilution ratio 38.36
12 PM concentration at stack (mg/L) 0.0253 0.0252 0.0253 0.0259
13 Stack gas velocity (ft/min) 1021
14 Stack temperature (°F) 160.1
15 Stack pressure (in. Hg) 29.882
16 Stack area (ft2) 23.0438
17 Stack flow (sft3/min) 20,007.8
18 Stack flow (sL/min) 566,621.9
19 PM emission rate from stack (mg/min) 14,360.0 14,259.7 14,328.0 14,657.7
20 Fuel type Black Liquor #2 Oil
21 Fuel volumetric feed (gal/min) 454.54 0
22 Fuel density (lb/gal) 11.4
23 Fuel density (kg/gal) 5.17 3.19
24 Fuel mass feed rate (kg/min) 2350.0 0.0
25 Fuel mass feed rate (lb/min) 5181.8 0.0
26 Fuel heating value (Btu/lb) 4208 19374
27 Fuel heat feed rate (Btu/min) 21,804,829.2 0.0
28 Total fuel mass feed rate (kg/min) 2350.0
29 Emission factor (mg/kg) 6.11 6.07 6.10 6.24
30 Total fuel heat feed rate (Btu/min) 21,804,829.25
31 Emission factor (|ig/kJ) 0.62 0.62 0.62 0.64
32 Ave. Emission Factor (mg/kg) 6.13
33 Ave. Emission Factor (ng/kJ) 0.63
C-20
-------
Appendix D
Data Tables for Individual PM25
Mass Measurements
D-l
-------
Contents
Table Page
D-l. Gravimetric Measurements: Electrical Low Pressure Impactor Stages - Filters D-3
D-2. Gravimetric Measurements: Teflon Filters D-4
D-2
-------
Table D-l. Gravimetric Measurements: Electrical Low Pressure Impactor Stages - Filters
ID
Initial Weight
(mg)
Final Weight
(mg)
PM Mass
(mg)
A101701T
IB121501H
ELPI 1
33.852
33.86
0.008
A101701R
IB121501H
ELPI2
33.766
33.789
0.023
A101701Q
IB121501H
ELPI 3
32.769
32.909
0.14
A101701P
IB121501H
ELPI 4
33.004
33.35
0.346
A1017010
IB121501H
ELPI 5
32.919
33.345
0.426
A101701M
IB121501H
ELPI 6
33.92
34.547
0.627
A101701L
IB121501H
ELPI 7
32.93
33.352
0.422
A101701K
IB121501H
ELPI 8
34.053
34.228
0.175
A101701J
IB121501H
ELPI 9
33.353
33.439
0.086
A101701H
IB121501H
ELPI 10
33.45
33.404
-0.046
A101701G
IB121501H
ELPI 11
33.887
33.909
0.022
A101701F
IB121501H
ELPI 12
34.409
34.395
-0.014
A101701E
IB121501H
ELPI 13
33.529
33.553
0.024
A101701U
IB121501H
ELPI FB
33.138
33.144
0.006
A102101I
IB121601H
ELPI 1
33.33
A102101H
IB121601H
ELPI 2
32.962
A102101G
IB121601H
ELPI 3
33.765
A102101F
IB121601H
ELPI 4
33.187
A102101E
IB121601H
ELPI 5
33.234
A102101D
IB121601H
ELPI 6
33.102
A102101C
IB121601H
ELPI 7
34.012
A102101B
IB121601H
ELPI 8
32.837
A102101A
IB121601H
ELPI 9
33.257
A101701Y
IB121601H
ELPI 10
33.459
33.577
0.118
A101701X
IB121601H
ELPI 11
32.229
32.263
0.034
A101701W
IB121601H
ELPI 12
33.249
33.257
0.008
A101701V
IB121601H
ELPI 13
33.952
33.965
0.013
D-3
-------
Table D-2. Gravimetric Measurements: Teflon Filters
ID
Initial
Weight
(g)
Final
Weight
(g)
PM Mass
(g)
PM Mass
(mg)
T102201M
IB121401HD1B1
0.174085
0.174087
0.000002
0.002
T102201J
IB121401HR2A1
0.195529
0.197272
0.001743
1.743
T102201K
IB121401HR2B1
0.181935
0.18364
0.001705
1.705
T102201L
IB1121401HR6A1
0.170991
0.172675
0.001684
1.684
T102201N
IB121401HR6B1
0.174756
0.176513
0.001757
1.757
T1022010
IB121401HFB
0.177514
0.17751
-0.000004
-0.004
T102201U
IB121501HD1B1
0.19466
0.194656
-0.000004
-0.004
T102201S
IB121501HR2A1
0.159946
0.162813
0.002867
2.867
T102201T
IB121501HR2B1
0.158719
0.161698
0.002979
2.979
T102201Q
IB121501HR6A1
0.185376
0.188354
0.002978
2.978
T102201R
IB121501HR6B1
0.179448
0.182447
0.002999
2.999
T082101M
IB121601HD1B1
0.18583
0.185835
0.000005
0.005
T082101N
IB121601HR2A1
0.189623
0.192348
0.002725
2.725
T100301A
IB121601HR2B1
0.191138
0.193844
0.002706
2.706
T100301C
IB121601HR6A1
0.19494
0.197683
0.002743
2.743
T100301D
IB121501HR6B1
0.194825
0.197631
0.002806
2.806
D-4
-------
Appendix E
Data Tables for Individual Carbonyl Samples
E-l
-------
Contents
Table Page
E-l. Carbonyls, Individual Tube Results, Blanks, Test Dates: 12/14/01 - 12/16/01 E-3
E-2A. Carbonyls, Individual Tube Results, Field Samples (12/14/01) E-4
E-2B. Carbonyls, Individual Tube Results, Field Samples (12/15/01) E-6
E-2C. Carbonyls, Individual Tube Results, Field Samples (12/16/01) E-8
E-3 A. Carbonyls: Smelt Tank Vent Carbonyls for Each Test Day E-10
E-3B. Carbonyls: Smelt Tank Vent Carbonyls for Each Test Day E-ll
E-3C. Carbonyls: Smelt Tank Vent Carbonyls for Each Test Day E-12
E-4. Carbonyls Summary: Smelt Tank Vent, 12/14/01 - 12/16/01 E-13
E-2
-------
Table E-l. Carbonyls, Individual Tube Results, Blanks, Test Dates: 12/14/01 -
12/16/01
Method
Field
Compound
CAS No.
Blank
Blank
US
US
formaldehyde
50-00-0
0.0280
0.0230
acetaldehyde
75-07-0
0.0230
0.0210
acetone
67-64-1
0.2210
0.2280
propionaldehyde
123-38-6
ND
ND
crotonaldehyde
4170-30-0
ND
ND
butyr/isobutyraldehyde
123-72-8
0.0780
0.0840
benzaldehyde
100-52-7
ND
ND
isovaleraldehyde
590-86-3
ND
ND
valeraldehyde
110-62-3
ND
ND
o-tolualdehyde
529-20-4
ND
ND
m-tolualdchydc
620-23-5
ND
ND
/Molualdchydc
104-87-0
ND
ND
hexaldehyde
66-25-1
ND
0.0280
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
diacetyl
431-03-8
ND
ND
methacrolein
78-85-3
ND
ND
2-butanone
78-93-3
ND
0.0050
glyoxal
107-22-2
ND
0.0820
acetophenone
98-86-2
ND
ND
methylglyoxal
78-98-8
0.0390
0.0490
octanal
124-13-0
ND
ND
nonanal
124-19-6
0.0670
0.1070
Sum, Speciated
0.4560
0.6270
Sum, Unspeciated
0.8170
0.8850
Total (Speciated + Unspeciated)
1.2730
1.5120
E-3
-------
Table E-2A. Carbonyls, Individual Tube Results, Field Samples (12/14/01)
Site ID
WSTV
WSTV
WSTV
Dilution
Air
WSTV
WSTV
WSTV
Residence
Chamber
Carbonyls
Carbonyls
Field ID
Hd3Al
Hd3A2
Hd3A3
Three
Tubes
Hr3Al
Hr3A2
Hr3A3
Three
Tubes
RC-DA
RC-DAa
Characterization
DA,
FRONT
DA,
MIDDLE
DA,
REAR
12/14/01
RC,
FRONT
RC,
MIDDLE
RC,
REAR
12/14/01
12/14/01
12/14/01
Volume Sampled
310.17
310.17
310.17
290.78
290.78
290.78
ERG ID
24566
24567
24568
24570
24571
24569
Sampling Date
12/14/01
12/14/01
12/14/01
12/14/01
12/14/01
12/14/01
Analysis Date
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
Data File
F1L-031
F1L—032
F1L-033
F1L-035
F1L-036
F1L-034
Compound
CAS No.
(M-g)
(Hg)
(Hg)
(M-g)
(H-g)
(H-g)
(H-g)
(Hg)
Gig)
(M-g)
formaldehyde
50-00-0
0.0750
0.0400
0.0420
0.1570
0.0390
0.0390
0.1290
0.2070
0.0500
0.0500
acetaldehyde
75-07-0
0.0950
0.0470
0.0580
0.2000
0.0900
0.1110
2.2720
2.4730
2.2730
2.2730
acetone
67-64-1
0.2780
0.2550
0.2520
0.7850
NDb
ND
ND
ND
-0.7850
ND
propionaldehyde
123-38-6
ND
ND
ND
ND
ND
ND
0.0770
0.0770
0.0770
0.0770
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.1290
0.1270
0.1220
0.3780
0.2920
0.1370
0.2110
0.6400
0.2620
0.2620
benzaldehyde
100-52-7
ND
ND
ND
ND
ND
ND
0.0080
0.0080
0.0080
0.0080
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
ND
0.0100
ND
0.0350
0.0450
0.0450
0.0450
o-tolualdehyde
529-20-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/w-tolualdehyde
620-23-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/Molualdchydc
104-87-0
ND
ND
ND
ND
ND
ND
0.0130
0.0130
0.0130
0.0130
hexaldehyde
66-25-1
0.0280
0.0180
0.0190
0.0650
0.0220
0.0200
0.0450
0.0870
0.0220
0.0220
2,5-dimethylbenzaldehyde 5779-94-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
Table E-2A. Carbonyls, Individual Tube Results, Field Samples (12/14/01) (concluded)
Site ID
WSTV
WSTV
WSTV
Dilution
Air
WSTV
WSTV
WSTV
Residence
Chamber
Carbonyls
Carbonyls
Field ID
Hd3Al
Hd3A2
Hd3A3
Three
Tubes
Hr3Al
Hr3A2
Hr3A3
Three
Tubes
RC-DA
RC-DAa
Characterization
DA,
FRONT
DA,
MIDDLE
DA,
REAR
12/14/01
RC,
RONT
RC,
MIDDLE
RC,
REAR
12/14/01
12/14/01
12/14/01
Volume Sampled
310.17
310.17
310.17
290.78
290.78
290.78
ERG ID
24566
24567
24568
24570
24571
24569
Sampling Date
12/14/01
12/14/01
12/14/01
12/14/01
12/14/01
12/14/01
Analysis Date
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
Data File
F1L-031
F1L—032
F1L-033
F1L-035
F1L-036
F1L-034
Compound
CAS No.
(M-g)
(Hg)
(Hg)
(M-g)
(M-g)
(M-g)
(Mg)
(Mg)
Gig)
(Mg)
diacetyl
431-03-8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-butanone
78-93-3
0.0030
0.0050
0.0040
0.0120
1.0860
0.0830
0.3460
1.5150
1.5030
1.5030
glyoxal
107-22-2
0.0850
0.0720
ND
0.1570
0.2320
ND
ND
0.2320
00750
0.0750
acetophenone
98-86-2
ND
ND
ND
ND
ND
ND
0.0300
0.0300
0.0300
0.0300
methylglyoxal
78-98-8
0.0510
0.0450
0.0450
0.1410
0.0490
0.0410
0.0520
0.1420
0.0010
0.0010
octanal
124-13-0
0.0380
ND
ND
0.0380
ND
ND
0.0420
0.0420
0.0040
0.0040
nonanal
124-19-6
0.1320
0.0950
0.0880
0.3150
0.0790
0.0930
0.1490
0.3210
0.0060
0.0060
Sum, Speciated
0.9140
0.7040
0.6300
2.2480
1.8990
0.5240
3.4090
5.8320
4.3690
Sum, Unspeciated
1.0185
0.9380
0.9155
2.8720
1.0645
0.9195
2.1265
4.1105
1.2385
Total (Speciated + Unspeciated)
1.9325
1.6420
1.5455
5.1200
2.9635
1.4435
5.5355
9.9425
5.6075
a Negatives eliminated
b ND = not detected
Note: When the subtraction of the value of the Dilution Air from the Residence Chamber air results in a negative number, the value of "0" rather than the negative number is used for all
subsequent calculations.
-------
Table E-2B. Carbonyls, Individual Tube Results, Field Samples (12/15/01)
Site ID
WSTV
WSTV
WSTV
Dilution
Air
WSTV
WSTV
WSTV
Residence
Chamber
Carbonyls
Carbonyls
Field ID
Hd3Al
Hd3A2
Hd3A3
Three
Tubes
Hr3Al
Hr3A2
Hr3A3
Three
Tubes
RC-DA
RC-DAa
Characterization
DA,
FRONT
DA,
MIDDLE
DA,
REAR
12/15/01
RC,
FRONT
RC,
MIDDLE
RC,
REAR
12/15/01
12/15/01
12/15/01
Volume Sampled
399.32
399.32
399.32
388.02
388.02
388.02
ERG ID
24572
24573
24574
24577
24576
24575
Sampling Date
12/15/01
12/15/01
12/15/01
12/15/01
12/15/01
12/15/01
Analysis Date
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
Data File
F1L—037
F1L-038
F1L-039
F1L-044
F1L-043
F1L-040
Compound
CAS No.
Gig)
fog)
(M-g)
(us)
Gig)
Gig)
Gig)
Gig)
(Mg)
Gig)
formaldehyde
50-00-0
0.0960
0.0500
0.0410
0.1870
0.0530
0.0590
0.2660
0.3780
0.1910
0.1910
F acetaldehyde
On
acetone
75-07-0
0.1090
0.0990
0.0500
0.2580
0.0640
0.2790
5.7420
6.0850
5.8270
5.8270
67-64-1
0.3250
0.2930
0.2810
0.8990
1.4540
5.2810
0.9830
7.7180
6.8190
6.8190
propionaldehyde
123-38-6
0.0060
NDb
ND
ND
ND
ND
0.340
0.3400
0.3400
0.3400
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
0.011
0.0110
0.0110
0.0110
butyr/isobutyraldehyde
123-72-8
0.1380
0.1270
0.1100
0.3750
0.1350
0.6170
0.2810
1.0330
0.6580
0.6580
benzaldehyde
100-52-7
ND
ND
ND
ND
ND
ND
0.0860
0.0860
0.0860
0.0860
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
ND
ND
0.032
0.060
0.0920
0.0920
0.0920
o-tolualdehyde
529-20-4
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/w-tolualdehyde
620-23-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/?-tolualdehyde
104-87-0
ND
ND
ND
ND
ND
0.012
0.076
0.0880
0.0880
0.0880
hexaldehyde
66-25-1
0.0330
0.0240
0.0190
0.0760
0.0170
0.0250
0.0850
0.1270
0.0510
0.0510
2,5-dimethylbenzaldehyde 5779-94-2
ND
ND
ND
ND
ND
ND
0.021
0.0210
0.021
0.0210
(continued)
-------
Table E-2B. Carbonyls, Individual Tube Results, Field Samples (12/15/01) (concluded)
Site ID
WSTV
WSTV
WSTV
Dilution
Air
WSTV
WSTV
WSTV
Residence
Chamber
Carbonyl
Carbonyls
Field ID
Hd3Al
Hd3A2
Hd3A3
Three
Tubes
Hr3Al
Hr3A2
Hr3A3
Three
Tubes
RC-DA
RC-DAa
Characterization
DA,
FRONT
DA,
MIDDLE
DA,
REAR
12/15/01
RC,
FRONT
RC,
MIDDLE
RC,
REAR
12/15/01
12/15/01
12/15/01
Volume Sampled
399.32
399.32
399.32
388.02
388.02
388.02
ERG ID
24572
24573
24574
24577
24576
24575
Sampling Date
12/15/01
12/15/01
12/15/01
12/15/01
12/15/01
12/15/01
Analysis Date
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
12/28/01
Data File
F1L—037
F1L-038
F1L-039
F1L-044
F1L-043
F1L-040
Compound
CAS No.
Gig)
fog)
(us)
Gig)
(fig)
(fig)
(fig)
Gig)
Gig)
Gig)
diacetyl
431-03-8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-butanone
78-93-3
0.0290
0.0300
0.0130
0.0720
0.1370
2.8140
0.5170
3.4680
3.3960
3.3960
glyoxal
107-22-2
0.0750
ND
ND
0.0750
0.0810
ND
ND
0.0810
0.0060
0.0060
acetophenone
98-86-2
ND
ND
ND
ND
ND
ND
0.041
0.0410
0.0410
0.0410
methylglyoxal
78-98-8
0.0540
0.0540
0.0510
0.1590
0.0380
0.0500
0.0630
0.1510
-0.0080
ND
octanal
124-13-0
0.0320
ND
ND
0.0320
ND
ND
0.0610
0.0610
0.0290
0.0290
nonanal
124-19-6
0.1550
0.1170
0.0710
0.3430
0.0820
0.0880
0.2350
0.4050
0.0620
0.0620
Sum, Speciated
1.0520
0.7940
0.6360
2.4820
2.0610
9.2570
8.8680
20.1860
17.7100
Sum, Unspeciated
0.9655
0.9275
0.9000
2.7930
0.9310
1.3150
2.8640
5.1100
2.3170
Total (Speciated + Unspeciated)
2.0175
1.7215
1.5360
5.2750
2.9920
10.5720
11.7320
25.2960
20.0270
a Negatives eliminated
b ND = not detected
Note: When the subtraction of the value of the Dilution Air from the Residence Chamber air results in a negative number, the value of "0" rather than the negative number is used for all
subsequent calculations.
-------
Table E-2C. Carbonyls, Individual Tube Results, Field Samples (12/16/01)
Site ID
WSTV
WSTV
WSTV
Dilution
Air
WSTV
WSTV
WSTV
Residence
Chamber
Carbonyls
Carbonyls
Field ID
Hd3Al
Hd3A2
Hd3A3
Three
Tubes
Hr3Al
Hr3A2
Hr3A3
Three
Tubes
RC-DA
RC-DAa
Characterization
DA,
FRONT
DA,
MIDDLE
DA,
REAR
12/16/01
RC,
FRONT
RC,
MIDDLE
RC,
REAR
12/16/01
12/16/01
12/16/01
Volume Sampled
401.5
401.5
401.5
401.5
401.5
401.5
ERG ID
24578
24579
24580
24581
24582
24583
Sampling Date
12/16/01
12/16/01
12/16/01
12/16/01
12/16/01
12/16/01
Analysis Date
12/29/01
12/29/01
12/29/01
12/29/01
12/29/01
12/29/01
Data File
F1L—045
F1L-046
F1L-047
F1L-048
F1L-049
F1L-050
Compound
CAS No.
Gig)
fog)
(us)
Gig)
(fig)
(fig)
(fig)
Gig)
Gig)
Gig)
m formaldehyde
50-00-0
0.0580
0.0400
0.0360
0.1340
0.1060
0.0430
0.0340
0.1830
0.0490
0.0490
00 acetaldehyde
75-07-0
0.0820
0.0570
0.0570
0.1960
2.7830
0.1030
0.0480
2.9340
2.7380
2.7380
acetone
67-64-1
0.1710
0.2470
0.2350
0.6530
0.8570
2.7860
0.3350
3.9780
3.3250
3.3250
propionaldehyde
123-38-6
NDb
ND
ND
ND
0.1170
ND
ND
0.1170
0.1170
0.1170
crotonaldehyde
4170-30-0
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.1420
0.1280
0.1110
0.3810
0.2280
0.3650
ND
0.5930
0.2120
0.2120
benzaldehyde
100-52-7
ND
ND
0.0020
0.0020
0.0050
ND
ND
0.0050
0.0030
0.0030
isovaleraldehyde
590-86-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
ND
ND
ND
0.0410
0.0110
ND
0.0520
0.0520
0.0520
o-tolualdehyde
529-20-4
ND
ND
ND
ND
0.0090
ND
ND
0.0090
0.0090
0.0090
/w-tolualdehyde
620-23-5
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
/?-tolualdehyde
104-87-0
ND
ND
ND
ND
0.0110
ND
ND
0.0110
0.0110
0.0110
hexaldehyde
66-25-1
0.0250
0.0180
0.0170
0.0600
0.0530
0.0230
0.0180
0.0940
0.0340
0.0340
2,5-dimethylbenzaldehyde 5779-94-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
(continued)
-------
Table E-2C. Carbonyls, Individual Tube Results, Field Samples (12/16/01) (concluded)
Site ID
WSTV
WSTV
WSTV
Dilution
Air
WSTV
WSTV
WSTV
Residence
Chamber
Carbonyls
Carbonyls
Field ID
Hd3Al
Hd3A2
Hd3A3
Three
Tubes
Hr3Al
Hr3A2
Hr3A3
Three
Tubes
RC-DA
RC-DAa
Characterization
DA,
FRONT
DA,
MIDDLE
DA,
REAR
12/16/01
RC,
FRONT
RC,
MIDDLE
RC,
REAR
12/16/01
12/16/01
12/16/01
Volume Sampled
401.5
401.5
401.5
401.5
401.5
401.5
ERG ID
24578
24579
24580
24581
24582
24583
Sampling Date
12/16/01
12/16/01
12/16/01
12/16/01
12/16/01
12/16/01
Analysis Date
12/29/01
12/29/01
12/29/01
12/29/01
12/29/01
12/29/01
Data File
F1L—045
F1L-046
F1L-047
F1L-048
F1L-049
F1L-050
Compound
CAS No.
Gig)
fog)
(us)
Gig)
(fig)
(fig)
(fig)
Gig)
Gig)
Gig)
diacetyl
431-03-8
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2-butanone
78-93-3
0.0160
0.0150
0.0110
0.0420
0.4680
1.3220
0.0140
1.8040
1.7620
1.7620
glyoxal
107-22-2
0.0950
ND
ND
0.0950
ND
ND
ND
ND
-0.0950
ND
acetophenone
98-86-2
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
methylglyoxal
78-98-8
0.0500
0.0380
0.0410
0.1290
0.0530
0.0460
0.0440
0.1430
0.0140
0.0140
octanal
124-13-0
0.0410
ND
ND
0.0410
0.0360
ND
ND
0.0360
-0.0050
ND
nonanal
124-19-6
0.1660
0.0910
0.0820
0.3390
0.1740
0.0820
0.1030
0.3590
0.0200
0.0200
Sum, Speciated
0.8460
0.6340
0.5920
2.0720
4.9410
4.7810
0.5960
10.3180
8.2460
Sum, Unspeciated
0.9370
0.9250
0.8910
2.7530
1.5075
1.1375
0.9930
3.6380
0.8850
Total (Speciated + Unspeciated)
1.7830
1.5590
1.4830
4.8250
6.4485
5.9185
1.5890
13.9560
9.1310
a Negatives eliminated
b ND = not detected
Note: When the subtraction of the value of the Dilution Air from the Residence Chamber air results in a negative number, the value of "0" rather than the negative number is used for all
subsequent calculations.
-------
Table E-3A. Carbonyls: Smelt Tank Vent Carbonyls for Each Test Day
RC-DA
Compound
CAS No.
12/14/01
(ng)
Uncertainty
Plus/Minus
%
Total
Uncertainty
Plus/Minus
formaldehyde
50-00-0
0.05
0.0055
0.074
0.008
acetaldehyde
75-07-0
2.2730
0.0259
3.362
0.038
acetone
67-64-1
NDa
2.6230
91.707
3.879
propionaldehyde
123-38-6
0.0770
0.0005
0.114
0.001
crotonaldehyde
4170-30-0
ND
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.2620
0.0153
0.387
0.023
benzaldehyde
100-52-7
0.0080
0.0002
0.012
ND
isovaleraldehyde
590-86-3
ND
ND
ND
ND
valeraldehyde
110-62-3
0.0450
0.0043
0.067
0.006
o-tolualdehyde
529-20-4
ND
ND
ND
ND
m-tolualdehyde
620-23-5
ND
ND
ND
ND
/Molualdchydc
104-87-0
0.0130
0.0007
0.019
0.001
hexaldehyde
66-25-1
0.0220
0.0020
0.033
0.003
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
diacetyl
431-03-8
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
2-butanone
78-93-3
1.5030
0.1222
2.223
0.181
glyoxal
107-22-2
0.0750
0.0020
0.111
0.003
acetophenone
98-86-2
0.0300
0.0014
0.044
0.002
methylglyoxal
78-98-8
0.0010
0.0001
0.001
ND
octanal
124-13-0
0.0040
0.0003
0.006
ND
nonanal
124-19-6
0.0060
0.0005
0.009
0.001
Sum, Speciated
4.3690
Sum, Unspeciated
1.2385
Total (Speciated + Unspeciated)
5.6075
a ND = not detected
E-10
-------
Table E-3B. Carbonyls: Smelt Tank Vent Carbonyls for Each Test Day
RC-DA
Compound
CAS No.
12/15/01
(ng)
Uncertainty
Plus/Minus
%
Total
Uncertainty
Plus/Minus
formaldehyde
50-00-0
0.1910
0.0210
0.9533
0.1051
acetaldehyde
75-07-0
5.827
0.0664
29.0841
0.3316
acetone
67-64-1
6.819
0.2884
34.0354
1.4397
propionaldehyde
123-38-6
0.34
0.0022
1.6970
0.0112
crotonaldehyde
4170-30-0
0.011
0.0003
0.0549
0.0014
butyr/isobutyraldehyde
123-72-8
0.6580
0.0384
3.2843
0.1918
benzaldehyde
100-52-7
0.0860
0.0026
0.4292
0.0131
isovaleraldehyde
590-86-3
NDa
ND
ND
ND
valeraldehyde
110-62-3
0.092
0.0088
0.4592
0.0440
o-tolualdehyde
529-20-4
ND
ND
ND
ND
m-tolualdchvdc
620-23-5
ND
ND
ND
ND
/Molualdchydc
104-87-0
0.088
0.0049
0.4392
0.0246
hexaldehyde
66-25-1
0.051
0.0047
0.2546
0.0237
2,5-dimethylbenzaldehyde
5779-94-2
0.021
0.0006
0.1048
0.0032
diacetyl
431-03-8
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
2-butanone
78-93-3
3.3960
0.2761
16.9503
1.3781
glyoxal
107-22-2
0.0060
0.0002
0.0299
0.0008
acetophenone
98-86-2
0.0410
0.0020
0.2046
0.0097
methylglyoxal
78-98-8
ND
ND
ND
ND
octanal
124-13-0
0.0290
0.0023
0.1447
0.0117
nonanal
124-19-6
0.0620
0.0050
0.3095
0.0249
Sum, Speciated
17.7180
Sum, Unspeciated
2.3170
Total (Speciated + Unspeciated)
20.0350
a ND = not detected
E-ll
-------
Table E-3C. Carbonyls: Smelt Tank Vent Carbonyls for Each Test Day
RC-DA
12/16/01
Uncertainty
%
Uncertainty
Compound
CAS No.
(ng)
Plus/Minus
Total
Plus/Minus
formaldehyde
50-00-0
0.049
0.0054
0.5308
0.0585
acetaldehyde
75-07-0
2.738
0.0312
29.6609
0.3381
acetone
67-64-1
3.3250
0.1406
36.0199
1.5236
propionaldehyde
123-38-6
0.117
0.0008
1.2675
0.0084
crotonaldehyde
4170-30-0
NDa
ND
ND
ND
butyr/isobutyraldehyde
123-72-8
0.212
0.0124
2.2966
0.1341
benzaldehyde
100-52-7
0.003
0.0001
0.0325
0.0010
isovaleraldehyde
590-86-3
ND
ND
ND
ND
valeraldehyde
110-62-3
0.052
0.0050
0.5633
0.0540
o-tolualdehyde
529-20-4
0.009
0.0001
0.0975
0.0013
m-tolualdehyde
620-23-5
ND
ND
ND
ND
/Molualdchydc
104-87-0
0.011
0.0006
0.1192
0.0067
hexaldehyde
66-25-1
0.034
0.0032
0.3683
0.0343
2,5-dimethylbenzaldehyde
5779-94-2
ND
ND
ND
ND
diacetyl
431-03-8
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
2-butanone
78-93-3
1.7620
0.1433
19.0879
1.5518
glyoxal
107-22-2
ND
ND
ND
ND
acetophenone
98-86-2
ND
ND
ND
ND
methylglyoxal
78-98-8
0.0140
0.0017
0.1517
0.0186
octanal
124-13-0
ND
ND
ND
ND
nonanal
124-19-6
0.02
0.0016
0.2167
0.0175
Sum, Speciated
8.3460
Sum, Unspeciated
0.8850
Total (Speciated +
Unspeciated)
9.2310
a ND = not detected
E-12
-------
Table E-4. Carbonyls Summary: Smelt Tank Vent, 12/14/01 - 12/16/01
Carbonyls
Carbonyls
Carbonyls
Field
RC-DA
RC-DA
RC-DA
Blank
12/14/01
12/15/01
12/16/01
Compound
CAS No.
(ng)
(M.g)
(us)
(ng)
formaldehyde
50-00-0
0.0230
0.0500
0.1910
0.0490
acetaldehyde
75-07-0
0.0210
2.2730
5.8270
2.7380
acetone
67-64-1
0.2280
NDa
6.8190
3.3250
propionaldehyde
123-38-6
ND
0.0770
0.3400
0.1170
crotonaldehyde
4170-30-0
ND
ND
0.0110
ND
butyr/isobutyraldehyde
123-72-8
0.0840
0.2620
0.6580
0.2120
benzaldehyde
100-52-7
ND
0.0080
0.0860
0.0030
isovaleraldehyde
590-86-3
ND
ND
ND
ND
valeraldehyde
110-62-3
ND
0.0450
0.0920
0.0520
o-tolualdehyde
529-20-4
ND
ND
ND
0.0090
m-tolualdchvdc
620-23-5
ND
ND
ND
ND
/Molualdchydc
104-87-0
ND
0.0130
0.0880
0.0110
hexaldehyde
66-25-1
0.0280
0.0220
0.0510
0.0340
2,5 -dimethylbenzaldehyde
5779-94-2
ND
ND
0.0210
ND
diacetyl
431-03-8
ND
ND
ND
ND
methacrolein
78-85-3
ND
ND
ND
ND
2-butanone
78-93-3
0.0050
1.5030
3.3960
1.7620
glyoxal
107-22-2
0.0820
0.0750
0.0060
ND
acetophenone
98-86-2
ND
0.0300
0.0410
ND
methylglyoxal
78-98-8
0.0490
0.0010
ND
0.0140
octanal
124-13-0
ND
0.0040
0.0290
ND
nonanal
124-19-6
0.1070
0.0060
0.0620
0.0200
Sum, Speciated
0.6270
4.3690
17.7180
8.3460
Sum, Unspeciated
0.8850
1.2385
2.3170
0.8850
Total (Speciated + Unspeciated)
1.5120
5.6075
20.0350
9.2310
a ND = not detected
E-13
-------
Appendix F
Data Tables for Individual NMOC Samples
F-l
-------
Contents
Table Page
F-l. Smelt Tank Vent: Field Test (12/14/01) SNMOC Analysis from Laboratory
Blanks and Field Ambient Sampling F-3
F-2A. Smelt Tank Vent: Field Test (12/14/01), SNMOCs Collected in Canisters F-6
F-2B. Smelt Tank Vent: Field Test (12/15/01), SNMOCs Collected in Canisters F-l 1
F-2C. Smelt Tank Vent: Field Test (12/16/01), SNMOCs Collected in Canisters F-16
F-3. Smelt Tank Vent: Field Test (12/14/01 - 12/16/01), Summary of SNMOCs
Collected in Canisters F-21
F-4A. Smelt Tank Vent: Field Test (12/14/01), Total SNMOCs Collected F-23
F-4B. Smelt Tank Vent: Field Test (12/15/01), Total SNMOCs Collected F-26
F-4C. Smelt Tank Vent: Field Test (12/16/01), Total SNMOCs Collected F-30
F-5A. SNMOC Values for 12/14/01 in SPECIATE Format F-33
F-5B. SNMOC Values for 12/15/01 in SPECIATE Format F-36
F-5C. SNMOC Values for 12/16/01 in SPECIATE Format F-39
F-6. SNMOC, Reported as Weight Percent of Total F-42
F-2
-------
Table F-l. Smelt Tank Vent: Field Test (12/14/01) SNMOC Analysis from Laboratory
Blanks and Field Ambient Sampling
Laboratory
Blank Ambient
12/14/01 12/14/01
ERG #24592 ERG #24593
Compound
CAS No.
(Hg/m3)
(Hg/m3)
ethylene
74-85-1
0.48
1.17
acetylene
74-86-2
NDa
0.56
ethane
74-85-1
0.49
1.63
propylene
115-07-1
0.24
0.54
propane
74-98-6
0.50
3.11
propyne
74-99-7
ND
ND
isobutane
75-28-5
0.26
0.68
isobutene/1 -butene
115-11-7/106-98-0
0.27
0.51
1,3-butadiene
106-99-0
ND
ND
/7-butane
106-97-8
0.43
1.57
/ram-2-butcnc
624-64-6
0.19
0.28
cy.v-2-butcnc
590-18-1
0.23
0.31
3 -methyl-1 -butene
563-45-1
ND
ND
isopentane
78-78-4
0.43
1.37
1-pentene
109-67-1
0.22
0.30
2-methyl-1 -butene
563-46-2
ND
ND
/7-pentane
109-66-0
0.22
0.98
isoprene
78-79-4
0.25
0.30
/ram-2-pentene
646-04-8
ND
ND
cy.v-2-pcntcnc
627-20-3
0.32
0.32
2-methyl-2-butene
513-35-9
ND
ND
2,2-dimethylbutane
75-83-2
0.40
0.57
cyclopentene
142-29-0
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
cyclopentane
287-92-3
0.21
0.29
2,3 -dimethylbutane
79-29-8
0.45
0.61
2-methylpentane
107-83-5
0.27
0.83
3-methylpentane
96-14-0
0.38
3.63
2-methyl-1 -pentene
763-29-1
ND
ND
1-hexene
592-41-6
0.39
0.55
(continued)
F-3
-------
Table F-l. Smelt Tank Vent: Field Test (12/14/01) SNMOC Analysis from Laboratory
Blanks and Field Ambient Sampling (continued)
Laboratory
Blank Ambient
12/14/01 12/14/01
ERG #24592 ERG #24593
Compound
CAS No.
(Hg/m3)
(Hg/m3)
2-ethyl-l-butene
760-21-4
ND
ND
/7-hcxanc
110-54-3
0.37
139.09b
/ram-2-hcxcnc
4050-45-7
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
methylcyclopentane
96-37-7
0.23
18.17
2,4-dimethylpentane
108-08-7
0.30
0.43
benzene
71-43-2
0.27
1.09
cyclohexane
110-82-7
0.39
0.45
2-methylhexane
591-76-4
ND
0.62
2,3 -dimethylpentane
565-59-3
0.48
0.60
3-methylhexane
589-34-4
0.32
0.38
1-heptene
592-76-7
ND
ND
2,2,4-trimethylpentane
540-84-1
0.24
0.44
/7-heptane
142-82-5
0.24
0.34
methylcyclohexane
108-87-2
0.30
0.41
2,2,3-trimethylpentane
564-02-3
ND
ND
2,3,4-trimethylpentane
565-75-3
0.22
0.32
toluene
108-88-3
0.70
1.22
2-methylheptane
592-27-8
0.19
0.29
3-methylheptane
589-81-1
0.19
0.25
1-octene
111-66-0
ND
ND
/7-octanc
111-65-9
0.20
0.36
ethylbenzene
100-41-4
ND
ND
«?-xvlcnc//?-xylcnc
108-38-3/106-42-3
0.19
0.49
styrene
100-42-5
ND
0.17
o-xylene
95-47-6
0.15
0.24
1-nonene
124-11-8
ND
ND
/7-nonane
111-84-2
0.15
0.47
isopropylbenzene
98-82-8
ND
0.15
alpha-pinene
80-56-8
ND
15.24
(continued)
F-4
-------
Table F-l. Smelt Tank Vent: Field Test (12/14/01) SNMOC Analysis from Laboratory
Blanks and Field Ambient Sampling (concluded)
Compound
CAS No.
Laboratory
Blank
12/14/01
ERG #24592
(Hg/m3)
Ambient
12/14/01
ERG #24593
(|ig/m3)
/7-propylbcnzcnc
103-65-1
0.17
0.24
m-cthyltolucnc
620-14-4
0.07
1.02
/;-ethyltoluene
622-96-8
0.15
0.35
1,3,5 -trimethy lbenzene
108-67-8
ND
0.25
o-ethyltoluene
611-14-3
ND
0.27
beta-pinene
127-91-3
ND
0.42
1,2,4-trimethy lbenzene
95-63-6
0.20
0.57
1-decene
872-05-9
ND
ND
«-decane
124-18-5
0.23
0.60
1,2,3 -trimethy lbenzene
526-73-8
ND
0.23
/77-dicthylbcnzene
141-93-5
ND
0.16
/?-diethy lbenzene
105-05-5
ND
ND
1-undecene
821-95-4
ND
ND
/7-undccane
1120-21-4
0.20
0.37
1-dodecene
112-41-4
ND
ND
/7-dodecane
112-40-3
ND
0.96
1-tridecene
2437-56-1
ND
ND
/7-tridecane
629-50-5
ND
ND
Total Speciated
12.70
206.77
Total Unspeciated
1.77
43.02
Total (Speciated + Unspeciated)0
14.47
249.79
a ND = not detected
b w-hexane deleted from 12/14/01 data as a contaminant from the denuders
c Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-5
-------
Table F-2A. Smelt Tank Vent: Field Test (12/14/01), SNMOCs Collected in Canisters
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/14/01
Chamber
12/14/01
Air
RC-DA3
RC-DA
V=3.900L
12/14/01
V=3.900L
12/14/01
12/14/01
12/14/01
Compound
CAS No.
(jig/m3)
(Jig)
(M-g/m3)
(ng)
(Jig)
(ng)
ethylene
74-85-1
2.68
0.0105
1.2300
0.0048
0.0057
0.0057
acetylene
74-86-2
0.74
0.0029
0.5300
0.0021
0.0008
0.0008
ethane
74-85-1
4.12
0.0161
2.4600
0.0096
0.0065
0.0065
propylene
115-07-01
1.98
0.0077
0.9600
0.0037
0.0040
0.0040
propane
74-98-6
8.94
0.0349
6.0900
0.0238
0.0111
0.0111
propyne
74-99-7
NDC
ND
ND
ND
ND
ND
isobutane
75-28-5
0.87
0.0034
0.4500
0.0018
0.0016
0.0016
isobutene/1 -butene
115-11-7/106-98-0
0.69
0.0027
0.3400
0.0013
0.0014
0.0014
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
1.68
0.0066
0.6200
0.0024
0.0041
0.0041
fra«s-2-butene
624-64-6
0.71
0.0028
0.1700
0.0007
0.0021
0.0021
cy.v-2-butcnc
590-18-1
0.86
0.0034
0.2600
0.0010
0.0023
0.0023
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
1.61
0.0063
0.5800
0.0023
0.0040
0.0040
1-pentene
109-67-1
0.69
0.0027
0.2000
0.0008
0.0019
0.0019
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
1.21
0.0047
0.5900
0.0023
0.0024
0.0024
isoprene
78-79-4
0.74
0.0029
ND
ND
0.0029
0.0029
/ram-2-pentene
646-04-8
ND
ND
ND
ND
ND
ND
(continued)
-------
Table F-2A. Smelt Tank Vent: Field Test (12/14/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/14/01
Chamber
12/14/01
Air
RC-DA3
RC-DA
V=3.900L
12/14/01
V=3.900L
12/14/01
12/14/01
12/14/01
Compound
CAS No.
(jig/m3)
(Jig)
(M-g/m3)
(ng)
(Jig)
(ng)
cy.v-2-pcntcnc
627-20-3
0.95
0.0037
0.2900
0.0011
0.0026
0.0026
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.46
0.0057
0.4500
0.0018
0.0039
0.0039
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
cyclopentane
287-92-3
ND
ND
0.3400
0.0013
-0.0013
NDd
2,3 -dimethy lbutane
79-29-8
1.91
0.0074
0.4900
0.0019
0.0055
0.0055
2-methylpentane
107-83-5
0.98
0.0038
0.3100
0.0012
0.0026
0.0026
3-methylpentane
96-14-0
2.24
0.0087
0.4000
0.0016
0.0072
0.0072
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
ND
ND
1-hexene
592-41-6
1.63
0.0064
0.4600
0.0018
0.0046
0.0046
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
ND
ND
/7-hcxanc
110-54-3
NDe
NDe
0.4500
0.0018
0.1105
0.1105
fra«s-2-hexene
4050-45-7
ND
ND
ND
ND
ND
ND
cy.v-2-hcxcnc
7688-21-3
ND
ND
ND
ND
ND
ND
methylcyclopentane
96-37-7
5.21
0.0203
0.2600
0.0010
0.0193
0.0193
2,4-dimethylpentane
108-08-7
1.36
0.0053
0.3500
0.0014
0.0039
0.0039
benzene
71-43-2
1.67
0.0065
0.2800
0.0011
0.0054
0.0054
cyclohexane
110-82-7
1.58
0.0062
0.4100
0.0016
0.0046
0.0046
(continued)
-------
Table F-2A. Smelt Tank Vent: Field Test (12/14/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/14/01
Chamber
12/14/01
Air
RC-DA3
RC-DA
V=3.900L
12/14/01
V=3.900L
12/14/01
12/14/01
12/14/01
Compound
CAS No.
(jig/m3)
(Jig)
(M-g/m3)
(ng)
(Jig)
(ng)
2-methylhexane
591-76-4
ND
ND
ND
ND
ND
ND
2,3 -dimethylpentane
565-59-3
2.36
0.0092
0.4200
0.0016
0.0076
0.0076
3-methylhexane
589-34-4
0.89
0.0035
0.3300
0.0013
0.0022
0.0022
1-heptene
592-76-7
1.45
0.0057
ND
ND
0.0057
0.0057
2,2,4-trimethylpentane
540-84-1
1.01
0.0039
0.2700
0.0011
0.0029
0.0029
/7-hcptanc
142-82-5
1.02
0.0040
0.2400
0.0009
0.0030
0.0030
methylcyclohexane
108-87-2
0.90
0.0035
0.3200
0.0012
0.0023
0.0023
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
0.83
0.0032
0.2500
0.0010
0.0023
0.0023
toluene
108-88-3
4.14
0.0161
0.4000
0.0016
0.0146
0.0146
2-methylheptane
592-27-8
0.82
0.0032
0.1700
0.0007
0.0025
0.0025
3-methylheptane
589-81-1
ND
ND
0.1900
0.0007
-0.0007
NDd
1-octene
111-66-0
ND
ND
ND
ND
ND
ND
«-octanc
111-65-9
0.99
0.0039
0.2200
0.0009
0.0030
0.0030
ethylbenzene
100-41-4
ND
ND
ND
ND
ND
ND
«7-xylcnc//;-xylcnc
108-38-3/106-42-3
0.00
ND
ND
ND
ND
ND
styrene
100-42-5
ND
ND
ND
ND
ND
ND
o-xylene
95-47-6
0.73
0.0028
ND
ND
0.0028
0.0028
1-nonene
124-11-8
ND
ND
ND
ND
ND
ND
(continued)
-------
Table F-2A. Smelt Tank Vent: Field Test (12/14/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/14/01
Chamber
12/14/01
Air
RC-DA3
RC-DA
V=3.900L
12/14/01
V=3.900L
12/14/01
12/14/01
12/14/01
Compound
CAS No.
(jig/m3)
(Jig)
(M-g/m3)
(ng)
(Jig)
(ng)
/7-nonanc
111-84-2
ND
ND
ND
ND
ND
ND
isopropylbenzene
98-82-8
0.82
0.0032
0.2000
0.0008
0.0024
0.0024
alpha-pinene
80-56-8
1.12
0.0044
0.2200
0.0009
0.0035
0.0035
«-propylbcnzcnc
103-65-1
ND
ND
0.1400
0.0005
-0.0005
NDd
m-cthyltolucnc
620-14-4
ND
ND
ND
ND
ND
ND
/;-cthyltolucnc
622-96-8
ND
ND
0.1600
0.0006
-0.0006
NDd
1,3,5 -trimethylbenzene
108-67-8
0.82
0.0032
0.1500
0.0006
0.0026
0.0026
o-ethyltoluene
611-14-3
0.67
0.0026
0.1800
0.0007
0.0019
0.0019
beta-pinene
127-91-3
ND
ND
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.92
0.0036
0.1900
0.0007
0.0028
0.0028
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
/7-dccanc
124-18-5
ND
ND
0.2500
0.0010
-0.0010
NDd
1,2,3 -trimethylbenzene
526-73-8
ND
ND
ND
ND
ND
ND
m-dicthylbcnzcnc
141-93-5
ND
ND
ND
ND
ND
ND
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
0.70
0.0027
0.1500
0.0006
0.0021
0.0021
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
/7-dodccanc
112-40-3
0.81
0.0032
0.7100
0.0028
0.0004
0.0004
(continued)
-------
Table F-2A. Smelt Tank Vent: Field Test (12/14/01), SNMOCs Collected in Canisters (concluded)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/14/01
Chamber
12/14/01
Air
RC-DA3
RC-DA
V=3.900L
12/14/01
V=3.900L
12/14/01
12/14/01
12/14/01
Compound
CAS No.
(lig/m3)
(Jig)
(M-g/m3)
(ng)
(Jig)
(ng)
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
67.51
0.2633
24.1300
0.0941
0.1692
0.1751
Total Unspeciated
62.79
0.2449
3.3700
0.0131
0.2317
0.2317
Total (Speciated + Unspeciated)'
130.30
0.5082
27.5000
0.1073
0.4009
0.4069
a RC = residence chamber; DA = dilution air.
b When subtraction of the value of the Dilution Air from the Residence Chamber Air results in a negative number, the value "0" rather than the negative value is used for all subsequent
calculations.
c ND = not detected
d When the value in Dilution Air is greater than that in the Residence Chamber Air, a negative number results from the subtraction. This negatige number is treated as ND, or "0."
e w-hexane deleted from 12/14/01 data as a contaminant from the denuders
f Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
-------
Table F-2B. Smelt Tank Vent: Field Test (12/15/01), SNMOCs Collected in Canisters
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/15/01
Chamber
12/15/01
Air
RC-DA3
RC-DA
V=3.900L
12/15/01
V=3.900L
12/15/01
12/15/01
12/15/01
Compound
CAS No.
(jig/m3)
(Jig)
(jig/m3)
(Jig)
(Jig)
(Jig)
ethylene
74-85-1
12.0400
0.0470
1.8100
0.0071
0.0399
0.0399
acetylene
74-86-2
3.2200
0.0126
0.7400
0.0029
0.0097
0.0097
ethane
74-85-1
13.6400
0.0532
4.3400
0.0169
0.0363
0.0363
propylene
115-07-01
4.6300
0.0181
0.6700
0.0026
0.0154
0.0154
propane
74-98-6
8.6200
0.0336
4.2100
0.0164
0.0172
0.0172
propyne
74-99-7
NDC
ND
ND
ND
ND
ND
isobutane
75-28-5
1.2400
0.0048
0.3700
0.0014
0.0034
0.0034
isobutene/1 -butene
115-11-7/106-98-0
2.2800
0.0089
0.4100
0.0016
0.0073
0.0073
1,3-butadiene
106-99-0
0.6000
0.0023
ND
ND
0.0023
0.0023
/7-butane
106-97-8
2.4000
0.0094
0.5300
0.0021
0.0073
0.0073
/ram-2-butcnc
624-64-6
1.0600
0.0041
0.1900
0.0007
0.0034
0.0034
cy.v-2-butcnc
590-18-1
1.2700
0.0050
0.2700
0.0011
0.0039
0.0039
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
1.8400
0.0072
0.5400
0.0021
0.0051
0.0051
1-pentene
109-67-1
1.0000
0.0039
0.2100
0.0008
0.0031
0.0031
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
1.3600
0.0053
0.3900
0.0015
0.0038
0.0038
isoprene
78-79-4
0.9800
0.0038
0.2000
0.0008
0.0030
0.0030
/ram-2-pcntcnc
646-04-8
ND
ND
0.5200
0.0020
-0.0020
NDd
(continued)
-------
Table F-2B. Smelt Tank Vent: Field Test (12/15/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/15/01
Chamber
12/15/01
Air
RC-DA3
RC-DA
V=3.900L
12/15/01
V=3.900L
12/15/01
12/15/01
12/15/01
Compound
CAS No.
(jig/m3)
(Jig)
(jig/m3)
(Jig)
(Jig)
(Jig)
cy.v-2-pcntcnc
627-20-3
1.1300
0.0044
0.3100
0.0012
0.0032
0.0032
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.6200
0.0063
0.4000
0.0016
0.0048
0.0048
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
cyclopentane
287-92-3
1.2900
0.0050
0.2400
0.0009
0.0041
0.0041
2,3 -dimethy lbutane
79-29-8
1.8500
0.0072
0.4900
0.0019
0.0053
0.0053
2-methylpentane
107-83-5
0.6000
0.0023
0.6700
0.0026
-0.0003
NDd
3-methylpentane
96-14-0
1.6900
0.0066
0.5300
0.0021
0.0045
0.0045
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
ND
ND
1-hexene
592-41-6
1.7200
0.0067
0.5000
0.0020
0.0048
0.0048
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
ND
ND
/7-hcxanc
110-54-3
5.5200
0.0215
8.1400
0.0317
-0.0102
NDd
trans-2-hexene
4050-45-7
ND
ND
ND
ND
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
ND
ND
ND
ND
methylcyclopentane
96-37-7
1.7500
0.0068
1.3000
0.0051
0.0018
0.0018
2,4-dimethylpentane
108-08-7
1.2900
0.0050
0.3100
0.0012
0.0038
0.0038
benzene
71-43-2
8.0600
0.0314
0.3700
0.0014
0.0300
0.0300
cyclohexane
110-82-7
1.3300
0.0052
0.4800
0.0019
0.0033
0.0033
(continued)
-------
Table F-2B. Smelt Tank Vent: Field Test (12/15/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/15/01
Chamber
12/15/01
Air
RC-DA3
RC-DA
V=3.900L
12/15/01
V=3.900L
12/15/01
12/15/01
12/15/01
Compound
CAS No.
(jig/m3)
(Jig)
(jig/m3)
(Jig)
(Jig)
(Jig)
2-methylhexane
591-76-4
ND
ND
ND
ND
ND
ND
2,3 -dimethylpentane
565-59-3
2.6700
0.0104
0.5200
0.0020
0.0084
0.0084
3-methylhexane
589-34-4
ND
ND
0.3900
0.0015
-0.0015
NDd
1-heptene
592-76-7
ND
ND
ND
ND
ND
ND
2,2,4-trimethylpentane
540-84-1
1.0500
0.0041
0.2600
0.0010
0.0031
0.0031
«-hcptanc
142-82-5
0.8300
0.0032
0.1900
0.0007
0.0025
0.0025
methylcyclohexane
108-87-2
1.1600
0.0045
0.3000
0.0012
0.0034
0.0034
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
0.7700
0.0030
0.1700
0.0007
0.0023
0.0023
toluene
108-88-3
7.5200
0.0293
0.4200
0.0016
0.0277
0.0277
2-methylheptane
592-27-8
0.9400
0.0037
0.2000
0.0008
0.0029
0.0029
3-methylheptane
589-81-1
0.6300
0.0025
0.1900
0.0007
0.0017
0.0017
1-octene
111-66-0
ND
ND
ND
ND
ND
ND
/7-octanc
111-65-9
0.8100
0.0032
0.2700
0.0011
0.0021
0.0021
ethylbenzene
100-41-4
ND
ND
0.1500
0.0006
-0.0006
NDd
«?-xvlcnc//?-xylcnc
108-38-3/106-42-3
1.4100
0.0055
ND
ND
0.0055
0.0055
styrene
100-42-5
0.6700
0.0026
ND
ND
0.0026
0.0026
o-xylene
95-47-6
0.6000
0.0023
ND
ND
0.0023
0.0023
1-nonene
124-11-8
ND
ND
ND
ND
ND
ND
(continued)
-------
Table F-2B. Smelt Tank Vent: Field Test (12/15/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/15/01
Chamber
12/15/01
Air
RC-DA3
RC-DA
V=3.900L
12/15/01
V=3.900L
12/15/01
12/15/01
12/15/01
Compound
CAS No.
(jig/m3)
(Jig)
(jig/m3)
(Jig)
(Jig)
(Jig)
/7-nonanc
111-84-2
ND
ND
0.1500
0.0006
-0.0006
NDd
isopropylbenzene
98-82-8
0.9600
0.0037
ND
ND
0.0037
0.0037
alpha-pinene
80-56-8
ND
ND
ND
ND
ND
ND
/7-propylbcnzcnc
103-65-1
ND
ND
0.1800
0.0007
-0.0007
NDd
m-cthyltolucnc
620-14-4
ND
ND
0.1400
0.0005
-0.0005
NDd
/;-cthyltolucnc
622-96-8
1.2700
0.0050
0.2100
0.0008
0.0041
0.0041
1,3,5 -trimethylbenzene
108-67-8
ND
ND
0.1400
0.0005
-0.0005
NDd
o-ethyltoluene
611-14-3
ND
ND
0.1500
0.0006
-0.0006
NDd
beta-pinene
127-91-3
ND
ND
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
1.1100
0.0043
0.1700
0.0007
0.0037
0.0037
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
«-dccanc
124-18-5
ND
ND
0.2700
0.0011
-0.0011
NDd
1,2,3 -trimethylbenzene
526-73-8
ND
ND
ND
ND
ND
ND
m-dicthylbcnzcnc
141-93-5
ND
ND
0.1500
0.0006
-0.0006
NDd
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
0.6600
0.0026
0.1900
0.0007
0.0018
0.0018
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
«-dodccanc
112-40-3
ND
ND
0.9700
0.0038
-0.0038
NDd
(continued)
-------
Table F-2B. Smelt Tank Vent: Field Test (12/15/01), SNMOCs Collected in Canisters (concluded)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/15/01
Chamber
12/15/01
Air
RC-DA3
RC-DA
V=3.900L
12/15/01
V=3.900L
12/15/01
12/15/01
12/15/01
Compound
CAS No.
(jig/m3)
(Jig)
(lig/m3)
(Jig)
(Jig)
(Jig)
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
«-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
107.0900
0.4177
34.9200
0.1362
0.2815
0.3045
Total Unspeciated
62.1600
0.2424
7.0500
0.0275
0.2149
0.2149
Total (Speciated + Unspeciated)*
169.2500
0.6601
41.9700
0.1637
0.4964
0.5194
a RC = residence chamber; DA = dilution air.
b When subtraction of the value of the Dilution Air from the Residence Chamber Air results in a negative number, the value "0" rather than the negative value is used for all subsequent
calculations.
c ND = not detected
d When the value in Dilution Air is greater than that in the Residence Chamber Air, a negative number results from the subtraction. This negatige number is treated as ND, or "0."
e Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
-------
Table F-2C. Smelt Tank Vent: Field Test (12/16/01), SNMOCs Collected in Canisters
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/16/01
Chamber
12/16/01
Air
RC-DA1
RC-DA
V=4.300L
12/16/01
V=4.500L
12/16/01
12/16/01
12/16/01
Compound
CAS No.
(jig/m3)
(ng)
(M-g/m3)
(Jig)
(Jig)
(ng)
ethylene
74-85-1
2.4100
0.0104
1.0700
0.0048
0.0055
0.0055
acetylene
74-86-2
0.7200
0.0031
0.6900
0.0031
NDC
ND
ethane
74-85-1
5.1600
0.0222
3.4100
0.0153
0.0068
0.0068
propylene
115-07-01
1.5500
0.0067
0.5200
0.0023
0.0043
0.0043
propane
74-98-6
3.5900
0.0154
2.4300
0.0109
0.0045
0.0045
propyne
74-99-7
ND
ND
ND
ND
ND
ND
isobutane
75-28-5
0.7400
0.0032
0.4300
0.0019
0.0012
0.0012
isobutene/1 -butene
115-11-7/106-98-0
0.7500
0.0032
0.4300
0.0019
0.0013
0.0013
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
/7-butane
106-97-8
1.6200
0.0070
0.7900
0.0036
0.0034
0.0034
/ram-2-butcnc
624-64-6
0.8000
0.0034
0.2500
0.0011
0.0023
0.0023
c7.v-2-butcnc
590-18-1
1.0300
0.0044
0.3500
0.0016
0.0029
0.0029
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
1.4800
0.0064
0.6300
0.0028
0.0035
0.0035
1-pentene
109-67-1
0.8500
0.0037
0.2500
0.0011
0.0025
0.0025
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
/7-pentane
109-66-0
1.2200
0.0052
0.4000
0.0018
0.0034
0.0034
isoprene
78-79-4
0.9600
0.0041
0.2200
0.0010
0.0031
0.0031
/ram-2-pcntcnc
646-04-8
ND
ND
0.3000
0.0014
-0.0014
NDd
(continued)
-------
Table F-2C. Smelt Tank Vent: Field Test (12/16/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/16/01
Chamber
12/16/01
Air
RC-DA1
RC-DA
V=4.300L
12/16/01
V=4.500L
12/16/01
12/16/01
12/16/01
Compound
CAS No.
(jig/m3)
(ng)
(M-g/m3)
(Jig)
(Jig)
(ng)
c7.v-2-pcntcnc
627-20-3
1.2800
0.0055
0.3300
0.0015
0.0040
0.0040
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.6700
0.0072
0.4700
0.0021
0.0051
0.0051
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
cyclopentane
287-92-3
0.6900
0.0030
0.3600
0.0016
0.0013
0.0013
2,3 -dimethy lbutane
79-29-8
1.8300
0.0079
0.5500
0.0025
0.0054
0.0054
2-methylpentane
107-83-5
1.2800
0.0055
0.3100
0.0014
0.0041
0.0041
3-methylpentane
96-14-0
1.5300
0.0066
0.4600
0.0021
0.0045
0.0045
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
ND
ND
1-hexene
592-41-6
1.7100
0.0074
0.5000
0.0023
0.0051
0.0051
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
ND
ND
/7-hcxanc
110-54-3
1.6700
0.0072
1.1400
0.0051
0.0021
0.0021
fra«s-2-hexene
4050-45-7
ND
ND
ND
ND
ND
ND
c7.v-2-hcxcnc
7688-21-3
ND
ND
ND
ND
ND
ND
methylcyclopentane
96-37-7
0.9200
0.0040
0.3800
0.0017
0.0022
0.0022
2,4-dimethylpentane
108-08-7
1.2100
0.0052
0.3300
0.0015
0.0037
0.0037
benzene
71-43-2
0.9900
0.0043
0.3600
0.0016
0.0026
0.0026
cyclohexane
110-82-7
1.5700
0.0068
0.4500
0.0020
0.0047
0.0047
(continued)
-------
Table F-2C. Smelt Tank Vent: Field Test (12/16/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/16/01
Chamber
12/16/01
Air
RC-DA1
RC-DA
V=4.300L
12/16/01
V=4.500L
12/16/01
12/16/01
12/16/01
Compound
CAS No.
(jig/m3)
(ng)
(M-g/m3)
(Jig)
(Jig)
(ng)
2-methylhexane
591-76-4
1.3800
0.0059
0.3600
0.0016
0.0043
0.0043
2,3 -dimethylpentane
565-59-3
3.0700
0.0132
0.7500
0.0034
0.0098
0.0098
3-methylhexane
589-34-4
0.6600
0.0028
0.3500
0.0016
0.0013
0.0013
1-heptene
592-76-7
ND
ND
ND
ND
ND
ND
2,2,4-trimethylpentane
540-84-1
0.9800
0.0042
0.3000
0.0014
0.0029
0.0029
/7-hcptanc
142-82-5
0.9400
0.0040
0.2000
0.0009
0.0031
0.0031
methylcyclohexane
108-87-2
0.9800
0.0042
0.3300
0.0015
0.0027
0.0027
2,2,3 -trimethylpentane
564-02-3
ND
ND
ND
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
1.0600
0.0046
0.2400
0.0011
0.0035
0.0035
toluene
108-88-3
3.1800
0.0137
0.3200
0.0014
0.0122
0.0122
2-methylheptane
592-27-8
0.7800
0.0034
0.1800
0.0008
0.0025
0.0025
3-methylheptane
589-81-1
0.6700
0.0029
0.2200
0.0010
0.0019
0.0019
1-octene
111-66-0
ND
ND
ND
ND
ND
ND
/7-octanc
111-65-9
0.8400
0.0036
0.2300
0.0010
0.0026
0.0026
ethylbenzene
100-41-4
0.7100
0.0031
ND
ND
0.0031
0.0031
«?-xvlcnc//>xylcnc
108-38-3/106-42-3
0.9400
0.0040
0.2800
0.0013
0.0028
0.0028
styrene
100-42-5
ND
ND
ND
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
ND
ND
ND
1-nonene
124-11-8
ND
ND
ND
ND
ND
ND
(continued)
-------
Table F-2C. Smelt Tank Vent: Field Test (12/16/01), SNMOCs Collected in Canisters (continued)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/16/01
Chamber
12/16/01
Air
RC-DA1
RC-DA
V=4.300L
12/16/01
V=4.500L
12/16/01
12/16/01
12/16/01
Compound
CAS No.
(jig/m3)
(ng)
(M-g/m3)
(Jig)
(Jig)
(ng)
/7-nonanc
111-84-2
ND
ND
0.1800
0.0008
-0.0008
NDd
isopropylbenzene
98-82-8
1.0400
0.0045
ND
ND
0.0045
0.0045
alpha-pinene
80-56-8
ND
ND
ND
ND
ND
ND
/7-propylbcnzcnc
103-65-1
ND
ND
0.1500
0.0007
-0.0007
NDd
m-cthyltolucnc
620-14-4
ND
ND
0.3300
0.0015
-0.0015
NDd
/;-ethyltoluene
622-96-8
0.7200
0.0031
0.1800
0.0008
0.0023
0.0023
1,3,5 -trimethylbenzene
108-67-8
ND
ND
ND
ND
ND
ND
o-ethyltoluene
611-14-3
0.6100
0.0026
0.2000
0.0009
0.0017
0.0017
beta-pinene
127-91-3
ND
ND
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.7900
0.0034
0.2000
0.0009
0.0025
0.0025
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
«-dccanc
124-18-5
0.7500
0.0032
0.1900
0.0009
0.0024
0.0024
1,2,3-trimethylbenzene
526-73-8
ND
ND
ND
ND
ND
ND
/77-dicthylbcnzcne
141-93-5
ND
ND
0.1600
0.0007
-0.0007
NDd
/;-diethylbenzene
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
/7-undccanc
1120-21-4
ND
ND
ND
ND
ND
ND
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
«-dodccanc
112-40-3
ND
ND
ND
ND
ND
ND
(continued)
-------
Table F-2C. Smelt Tank Vent: Field Test (12/16/01), SNMOCs Collected in Canisters (concluded)
Residence
Dilution
No Negsb
Chamber
Residence
Air
Dilution
SNMOC
SNMOC
12/16/01
Chamber
12/16/01
Air
RC-DA1
RC-DA
V=4.300L
12/16/01
V=4.500L
12/16/01
12/16/01
12/16/01
Compound
CAS No.
(jig/m3)
(ng)
(M-g/m3)
(Jig)
(Jig)
(ng)
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
«-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
59.3300
0.2551
23.1600
0.1042
0.1509
0.1559
Total Unspeciated
50.6300
0.2177
3.0300
0.0136
0.2041
0.2041
Total (Speciated + Unspeciated)*
109.9600
0.4728
26.1900
0.1179
0.3550
0.3600
a RC = residence chamber; DA = dilution air.
b When subtraction of the value of the Dilution Air from the Residence Chamber Air results in a negative number, the value "0" rather than the negative value is used for all subsequent
calculations.
c ND = not detected
d When the value in Dilution Air is greater than that in the Residence Chamber Air, a negative number results from the subtraction. This negatige number is treated as ND, or "0."
e Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
-------
Table F-3. Smelt Tank Vent: Field Test (12/14/01 - 12/16/01), Summary of SNMOCs
Collected in Canisters
No Negsa
No Negsa
No Negsa
SNMOC
SNMOC
SNMOC
RC-DAb
RC-DA
RC-DA
12/14/01
12/15/01
12/16/01
Compound
CAS No.
(ng)
(ng)
(ng)
ethylene
74-85-1
0.0057
0.0399
0.0055
acetylene
74-86-2
0.0008
0.0097
NDC
ethane
74-85-1
0.0065
0.0363
0.0068
propylene
115-07-1
0.0040
0.0154
0.0043
propane
74-98-6
0.0111
0.0172
0.0045
propyne
74-99-7
ND
ND
ND
isobutane
75-28-5
0.0016
0.0034
0.0012
isobutene/1 -butene
115-11-7/106-98-0
0.0014
0.0073
0.0013
1,3-butadiene
106-99-0
ND
0.0023
ND
/7-butane
106-97-8
0.0041
0.0073
0.0034
fra«s-2-butene
624-64-6
0.0021
0.0034
0.0023
cy.v-2-butcnc
590-18-1
0.0023
0.0039
0.0029
3 -methyl-1 -butene
563-45-1
ND
ND
ND
isopentane
78-78-4
0.0040
0.0051
0.0035
1-pentene
109-67-1
0.0019
0.0031
0.0025
2-methyl-1 -butene
563-46-2
ND
ND
ND
/7-pentane
109-66-0
0.0024
0.0038
0.0034
isoprene
78-79-4
0.0029
0.0030
0.0031
fra«s-2-pentene
646-04-8
ND
ND
ND
cy.v-2-pcntcnc
627-20-3
0.0026
0.0032
0.0040
2-methyl-2-butene
513-35-9
ND
ND
ND
2,2-dimethylbutane
75-83-2
0.0039
0.0048
0.0051
cyclopentene
142-29-0
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
cyclopentane
287-92-3
ND
0.0041
0.0013
2,3 -dimethy lbutane
79-29-8
0.0055
0.0053
0.0054
2-methylpentane
107-83-5
0.0026
ND
0.0041
3-methylpentane
96-14-0
0.0072
0.0045
0.0045
2-methyl-1 -pentene
763-29-1
ND
ND
ND
1-hexene
592-41-6
0.0046
0.0048
0.0051
(continued)
F-21
-------
TableF-3. Smelt Tank Vent: Field Test(12/14/01 -12/16/01), Summary of SNMOCs Collected
in Canisters (continued)
No Negsa
No Negsa
No Negsa
SNMOC
SNMOC
SNMOC
RC-DA
RC-DA
RC-DA
12/14/01
12/15/01
12/16/01
Compound
CAS No.
(ng)
(ng)
(Hg)
2-ethyl-l-butene
760-21-4
ND
ND
ND
/7-hcxanc
110-54-3
NDd
ND
0.0021
trans-2-hexene
4050-45-7
ND
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
ND
methylcyclopentane
96-37-7
0.0193
0.0018
0.0022
2,4-dimethylpentane
108-08-7
0.0039
0.0038
0.0037
benzene
71-43-2
0.0054
0.0300
0.0026
cyclohexane
110-82-7
0.0046
0.0033
0.0047
2-methylhexane
591-76-4
ND
ND
0.0043
2,3 -dimethylpentane
565-59-3
0.0076
0.0084
0.0098
3-methylhexane
589-34-4
0.0022
ND
0.0013
1-heptene
592-76-7
0.0057
ND
ND
2,2,4-trimethylpentane
540-84-1
0.0029
0.0031
0.0029
/7-heptane
142-82-5
0.0030
0.0025
0.0031
methylcyclohexane
108-87-2
0.0023
0.0034
0.0027
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
0.0023
0.0023
0.0035
toluene
108-88-3
0.0146
0.0277
0.0122
2-methylheptane
592-27-8
0.0025
0.0029
0.0025
3-methylheptane
589-81-1
ND
0.0017
0.0019
1-octene
111-66-0
ND
ND
ND
/7-octane
111-65-9
0.0030
0.0021
0.0026
ethylbenzene
100-41-4
ND
ND
0.0031
«7-xylcne//;-xylcne
108-38-3/106-42-3
ND
0.0055
0.0028
styrene
100-42-5
ND
0.0026
ND
o-xylene
95-47-6
0.0028
0.0023
ND
1-nonene
124-11-8
ND
ND
ND
/7-nonane
111-84-2
ND
ND
ND
isopropylbenzene
98-82-8
0.0024
0.0037
0.0045
alpha-pinene
80-56-8
0.0035
ND
ND
(continued)
F-22
-------
TableF-3. Smelt Tank Vent: Field Test (12/14/01 -12/16/01), Summary of SNMOCs Collected
in Canisters (concluded)
No Negsa
No Negsa
No Negsa
SNMOC
SNMOC
SNMOC
RC-DA
RC-DA
RC-DA
12/14/01
12/15/01
12/16/01
Compound
CAS No.
(ng)
(ng)
(Hg)
/7-propylbcnzcnc
103-65-1
ND
ND
ND
m-cthyltolucnc
620-14-4
ND
ND
ND
/;-cthyltolucnc
622-96-8
ND
0.0041
0.0023
1,3,5 -trimethy lbenzene
108-67-8
0.0026
ND
ND
o-ethyltoluene
611-14-3
0.0019
ND
0.0017
beta-pinene
127-91-3
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
0.0028
0.0037
0.0025
1-decene
872-05-9
ND
ND
ND
/7-dccanc
124-18-5
ND
ND
0.0024
1,2,3 -trimethy lbenzene
526-73-8
ND
ND
ND
/77-dicthylbcnzcne
141-93-5
ND
ND
ND
/?-dicthy lbenzene
105-05-5
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
/7-undccanc
1120-21-4
0.0021
0.0018
ND
1-dodecene
112-41-4
ND
ND
ND
«-dodccanc
112-40-3
0.0004
ND
ND
1-tridecene
2437-56-1
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
Total Speciated
0.1751
0.3045
0.1559
Total Unspeciated
0.2317
0.2149
0.2041
Total (Speciated + Unspeciated)"
0.4068
0.5194
0.3600
a When subtraction of the value of the Dilution Air from the Residence Chamber Air results in a negative number, the value "0"
rather than the negative value is used for all subsequent calculations.
b RC = residence chamber; DA = dilution air.
c ND = not detected
d n-hexane deleted from 12/14/01 data as a contaminant from the denuders
e Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-23
-------
Table F-4A. Smelt Tank Vent: Field Test (12/14/01), Total SNMOCs Collected
RCa
DA"
Residence
RC
Dilution
DA
Chamber
Collected
Air
Collected
No Negsc
Canister
V=345.692
Canister
V=336.692
RC-DA
RC-DA
Compound
CAS No.
(u2/m3)
(US)
(u2/m3)
(US)
(US)
(US)
ethylene
74-85-1
2.68
926.455
1.230
414.131
512.323
512.323
acetylene
74-86-2
0.74
255.812
0.530
178.447
77.365
77.365
ethane
74-85-1
4.12
1424.251
2.460
828.262
595.989
595.989
propylene
115-07-1
1.98
684.470
0.960
323.224
361.246
361.246
propane
74-98-6
8.94
3090.486
6.090
2050.454
1040.032
1040.032
propyne
74-99-7
0
0.000
0.000
0.000
0.000
0.000
isobutane
75-28-5
0.87
300.752
0.450
151.511
149.241
149.241
isobutene/1 -butene
115-11-7/106-98-0
0.69
238.527
0.340
114.475
124.052
124.052
1,3-butadiene
106-99-0
0
0.000
0.000
0.000
0.000
0.000
//-butane
106-97-8
1.68
580.763
0.620
208.749
372.014
372.014
trans-2-butene
624-64-6
0.71
245.441
0.170
57.238
188.204
188.204
cv.v-2-butcne
590-18-1
0.86
297.295
0.260
87.540
209.755
209.755
3 -methyl-1 -butene
563-45-1
0
0.000
0.000
0.000
0.000
0.000
isopentane
78-78-4
1.61
556.564
0.580
195.281
361.283
361.283
1-pentene
109-67-1
0.69
238.527
0.200
67.338
171.189
171.189
2-methyl-1 -butene
563-46-2
0
0.000
0.000
0.000
0.000
0.000
//-pcntanc
109-66-0
1.21
418.287
0.590
198.648
219.639
219.639
isoprene
78-79-4
0.74
255.812
0.000
0.000
255.812
255.812
;ra«.v-2-pcntene
646-04-8
0
0.000
0.000
0.000
0.000
0.000
c/.v-2-pcntcnc
627-20-3
0.95
328.407
0.290
97.641
230.767
230.767
2-methyl-2-butene
513-35-9
0
0.000
0.000
0.000
0.000
0.000
2,2-dimethylbutane
75-83-2
1.46
504.710
0.450
151.511
353.199
353.199
cyclopentene
142-29-0
0
0.000
0.000
0.000
0.000
0.000
4-methyl-1 -pentene
691-37-2
0
0.000
0.000
0.000
0.000
0.000
cyclopentane
287-92-3
0
0.000
0.340
114.475
-114.475
0.000c
2,3 -dimethylbutane
79-29-8
1.91
660.272
0.490
164.979
495.293
495.293
2-methylpentane
107-83-5
0.98
338.778
0.310
104.375
234.404
234.404
3-methylpentane
96-14-0
2.24
774.350
0.400
134.677
639.673
639.673
2-methyl-1 -pentene
763-29-1
0
0.000
0.000
0.000
0.000
0.000
1-hexene
592-41-6
1.63
563.478
0.460
154.878
408.600
408.600
2-ethyl-l-butene
760-21-4
0
0.000
0.000
0.000
0.000
0.000
«-hexaned
110-54-3
0
0.000
0.450
151.511
-151.511
0.000c
;rfl/?.v-2-hc\ene
4050-45-7
NDe
ND
ND
ND
ND
ND
cv.v-2-hc.\cnc
7688-21-3
ND
ND
ND
ND
ND
ND
methylcyclopentane
96-37-7
5.21
1801.055
0.260
87.540
1713.515
1713.515
(continued)
F-24
-------
Table F-4A. Smelt Tank Vent: Field Test (12/14/01), Total SNMOCs Collected (continued)
RCa
DAb
Residence
RC
Dilution
DA
Chamber
Collected
Air
Collected
No Negsc
Canister
V=345.692
Canister
V=336.692
RC-DA
RC-DA
Compound
CAS No.
(u2/m3)
(U2)
(u2/m3)
(U2)
(U2)
(U2)
2,4-dimethylpentane
108-08-7
1.36
470.141
0.350
117.842
352.299
352.299
benzene
71-43-2
1.67
577.306
0.280
94.274
483.032
483.032
cyclohexane
110-82-7
1.58
546.193
0.410
138.044
408.150
408.150
2-methylhexane
591-76-4
ND
ND
ND
ND
ND
ND
2,3 -dimethylpentane
565-59-3
2.36
815.833
0.420
141.411
674.422
674.422
3-methylhexane
589-34-4
0.89
307.666
0.330
111.108
196.558
196.558
1-heptene
592-76-7
1.45
501.253
ND
ND
501.253
501.253
2,2,4-trimethyl-
pentane
540-84-1
1.01
349.149
0.270
90.907
258.242
258.242
//-heptane
142-82-5
1.02
352.606
0.240
80.806
271.800
271.800
methylcyclohexane
108-87-2
0.9
311.123
0.320
107.741
203.381
203.381
2,2,3-trimethyl-
pentane
564-02-3
ND
ND
ND
ND
ND
ND
2,3,4-trimethyl-
pentane
565-75-3
0.83
286.924
0.250
84.173
202.751
202.751
toluene
108-88-3
4.14
1431.165
0.400
134.677
1296.488
1296.488
2-methylheptane
592-27-8
0.82
283.467
0.170
57.238
226.230
226.230
3-methylheptane
589-81-1
ND
ND
0.190
63.971
-63.971
NDC
1-octene
111-66-0
ND
ND
ND
ND
ND
ND
«-octane
111-65-9
0.99
342.235
0.220
74.072
268.163
268.163
ethylbenzene
100-41-4
ND
ND
ND
ND
ND
ND
w/-.\ylcnc//?-.\ylcne
108-38-3/106-42-3
ND
ND
ND
ND
ND
ND
styrene
100-42-5
ND
ND
ND
ND
ND
ND
o-xylene
95-47-6
0.73
252.355
ND
ND
252.355
252.355
1-nonene
124-11-8
ND
ND
ND
ND
ND
ND
//-nonanc
111-84-2
ND
ND
ND
ND
ND
ND
isopropylbenzene
98-82-8
0.82
283.467
0.200
67.338
216.129
216.129
alpha-pinene
80-56-8
1.12
387.175
0.220
74.072
313.103
313.103
//-propylbcn/cnc
103-65-1
ND
ND
0.140
47.137
-47.137
NDC
/H-cthvltolucnc
620-14-4
ND
ND
ND
ND
ND
ND
p-ethyltoluene
622-96-8
ND
ND
0.160
53.871
-53.871
NDC
1,3,5-trimethyl-
benzene
108-67-8
0.82
283.467
0.150
50.504
232.964
232.964
o-ethyltoluene
611-14-3
0.67
231.614
0.180
60.605
171.009
171.009
beta-pinene
127-91-3
ND
ND
ND
ND
ND
ND
(continued)
F-25
-------
Table F-4A. Smelt Tank Vent: Field Test (12/14/01), Total SNMOCs Collected (concluded)
RCa
DAb
Residence
RC
Dilution
DA
Chamber i
Collected
Air
Collected
No Negsc
Canister V=345.692
Canister
V=336.692
RC-DA
RC-DA
Compound
CAS No.
(u2/m3)
(U2)
(u2/m3)
(U2)
(U2)
(U2)
1,2,4-trimethyl-
benzene
95-63-6
0.92
318.037
0.190
63.971
254.065
254.065
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
n-decane
124-18-5
ND
ND
0.250
84.173
-84.173
NDC
1,2,3-trimethyl-
benzene
526-73-8
ND
ND
ND
ND
ND
ND
/M-dicthvlbcnzcnc
141-93-5
ND
ND
ND
ND
ND
ND
/>-diethylbenzene
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
«-undecane
1120-21-4
0.70
241.984
0.150
50.504
191.481
191.481
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
//-dodccanc
112-40-3
0.81
280.011
0.710
239.051
40.959
40.959
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
rt-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
67.51 23337.667
24.130
8124.378
15213.289
15728.428
Total Unspeciated
62.79 21706.001
3.370
1134.652
20571.349
45737.110
Total (Speciated +
Unspeciated)'
130.30 45043.668
27.500
9259.030
35784.638
61465.538
a RC = residence chamber = combustion air + dilution air
b DA = dilution air
c When the value in Dilution Air is greater than that in the Residence Chamber Air, a negative number results from the
subtraction. This negative number is treated as ND, or "0."
d w-hexane deleted from 12/14/01 data as a contaminant from the denuders
e ND = not detected.
f Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-26
-------
Table F-4B. Smelt Tank Vent: Field Test (12/15/01), Total SNMOCs Collected
RCa
DAb
Residence
RC
Dilution
DA
Chamber
Collected
Air
Collected
No Negsc
Canister
V=419.539
Canister
V=408.417
RC-DA
RC-DA
Compound
CAS No.
(M.2/m3)
(US)
(M.2/m3)
(US)
(US)
(US)
ethylene
74-85-1
12.040
5051.249
1.810
739.235
4312.014
4312.014
acetylene
74-86-2
3.220
1350.916
0.740
302.229
1048.687
1048.687
ethane
74-85-1
13.640
5722.512
4.340
1772.531
3949.980
3949.980
propylene
115-07-1
4.630
1942.466
0.670
273.640
1668.826
1668.826
propane
74-98-6
8.620
3616.426
4.210
1719.437
1896.989
1896.989
propyne
74-99-7
NDd
ND
ND
ND
ND
ND
isobutane
75-28-5
1.240
520.228
0.370
151.114
369.114
369.114
isobutene/1 -butene
115-11-7/106-98-0
2.280
956.549
0.410
167.451
789.098
789.098
1,3-butadiene
106-99-0
0.600
251.723
ND
ND
251.723
251.723
//-butane
106-97-8
2.400
1006.894
0.530
216.461
790.432
790.432
/ra«s-2-butene
624-64-6
1.060
444.711
0.190
77.599
367.112
367.112
c/.v-2-butcnc
590-18-1
1.270
532.815
0.270
110.273
422.542
422.542
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
1.840
771.952
0.540
220.545
551.406
551.406
1-pentene
109-67-1
1.000
419.539
0.210
85.768
333.771
333.771
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
rt-pentane
109-66-0
1.360
570.573
0.390
159.283
411.290
411.290
isoprene
78-79-4
0.980
411.148
0.200
81.683
329.465
329.465
/ra«s-2-pentene
646-04-8
ND
ND
0.520
212.377
-212.377
NDC
c/.v-2-pcntcnc
627-20-3
1.130
474.079
0.310
126.609
347.470
347.470
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
1.620
679.653
0.400
163.367
516.286
516.286
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
cyclopentane
287-92-3
1.290
541.205
0.240
98.020
443.185
443.185
2,3 -dimethylbutane
79-29-8
1.850
776.147
0.490
200.125
576.023
576.023
2-methylpentane
107-83-5
0.600
251.723
0.670
273.640
-21.916
ND
3-methylpentane
96-14-0
1.690
709.021
0.530
216.461
492.560
492.560
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
ND
ND
1-hexene
592-41-6
1.720
721.607
0.500
204.209
517.398
517.398
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
ND
ND
rt-hexane
110-54-3
5.520
2315.855
8.140
3324.517
-1008.662
NDC
;ra«.v-2-hc.\cnc
4050-45-7
ND
ND
ND
ND
ND
ND
67.v-2-hc.xcnc
7688-21-3
ND
ND
ND
ND
ND
ND
(continued)
F-27
-------
Table F-4B. Smelt Tank Vent: Field Test (12/15/01), Total SNMOCs Collected (continued)
RCa
DAb
Residence
RC
Dilution
DA
Chamber
Collected
Air i
Collected
No Negsc
Canister
V=419.539
Canister V=408.417
RC-DA
RC-DA
Compound
CAS No.
(u2/m3)
(U2)
(u2/m3)
(U2)
(U2)
(U2)
methylcyclopentane
96-37-7
1.750
734.193
1.300
530.943
203.251
203.251
2,4-dimethyl-
pentane
108-08-7
1.290
541.205
0.310
126.609
414.596
414.596
benzene
71-43-2
8.060
3381.484
0.370
151.114
3230.370
3230.370
cyclohexane
110-82-7
1.330
557.987
0.480
196.040
361.947
361.947
2-methylhexane
591-76-4
ND
ND
ND
ND
ND
ND
2,3-dimethyl-
pentane
565-59-3
2.670
1120.169
0.520
212.377
907.792
907.792
3-methylhexane
589-34-4
ND
ND
0.390
159.283
-159.283
NDC
1-heptene
592-76-7
ND
ND
ND
ND
ND
ND
2,2,4-trimethyl-
pentane
540-84-1
1.050
440.516
0.260
106.189
334.327
334.327
//-heptane
142-82-5
0.830
348.217
0.190
77.599
270.618
270.618
methyleyelohexane
108-87-2
1.160
486.665
0.300
122.525
364.140
364.140
2,2,3-trimethyl-
pentane
564-02-3
ND
ND
ND
ND
ND
ND
2,3,4-trimethyl-
pentane
565-75-3
0.770
323.045
0.170
69.431
253.614
253.614
toluene
108-88-3
7.520
3154.933
0.420
171.535
2983.398
2983.398
2-methylheptane
592-27-8
0.940
394.367
0.200
81.683
312.683
312.683
3-methylheptane
589-81-1
0.630
264.310
0.190
77.599
186.710
186.710
1-octene
111-66-0
ND
ND
ND
ND
ND
ND
//-octane
111-65-9
0.810
339.827
0.270
110.273
229.554
229.554
ethylbenzene
100-41-4
ND
ND
0.150
61.263
-61.263
NDC
///-xy 1 c nc/p-xy le nc
108-38-3/106-42-3
1.410
591.550
ND
ND
591.550
591.550
styrene
100-42-5
0.670
281.091
ND
ND
281.091
281.091
o-xylene
95-47-6
0.600
251.723
ND
ND
251.723
251.723
1-nonene
124-11-8
ND
ND
ND
ND
ND
ND
n-nonane
111-84-2
ND
ND
0.150
61.263
-61.263
NDC
isopropylbenzene
98-82-8
0.960
402.757
ND
ND
402.757
402.757
alpha-pinene
80-56-8
ND
ND
ND
ND
ND
ND
//-propylbcnzcnc
103-65-1
ND
ND
0.180
73.515
-73.515
NDC
///-cthyltolucnc
620-14-4
ND
ND
0.140
57.178
-57.178
NDC
/?-ethyltoluene
622-96-8
1.270
532.815
0.210
85.768
447.047
447.047
1,3,5-trimethyl-
benzene
108-67-8
ND
ND
0.140
57.178
-57.178
NDC
o-ethyltoluene
611-14-3
ND
ND
0.150
61.263
-61.263
NDC
F-28
-------
Table F-4B. Smelt Tank Vent: Field Test (12/15/01), Total SNMOCs Collected (concluded)
RCa
DAb
Residence
RC
Dilution
DA
Chamber
Collected
Air
Collected
No Negsc
Canister
V=419.539
Canister
V=408.417
RC-DA
RC-DA
Compound
CAS No.
(M.2/m3)
(U2)
(M.2/m3)
(U2)
(U2)
(U2)
beta-pinene
127-91-3
ND
ND
ND
ND
ND
ND
1,2,4-trimethyl-
benzene
95-63-6
1.110
465.688
0.170
69.431
396.257
396.257
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
n-decane
124-18-5
ND
ND
0.270
110.273
-110.273
NDC
1,2,3-trimethyl-
benzene
526-73-8
ND
ND
ND
ND
ND
ND
/w-diethylbenzene
141-93-5
ND
ND
0.150
61.263
-61.263
NDC
p-dicthvlbcnzcnc
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
«-undecane
1120-21-4
0.660
276.896
0.190
77.599
199.296
199.296
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
//-dodccanc
112-40-3
ND
ND
0.970
396.165
-396.165
NDC
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
rt-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
107.090
44928.431
34.920
14261.935
30666.496
33008.094
Total Unspeciated
62.160
26078.544
7.050
2879.343
23199.201
53865.697
Total (Speciated + Unspeciated)6
169.250
71006.975
41.970
17141.277
53865.697
86873.792
a RC = residence chamber = combustion air + dilution air
b DA = dilution air
c When the value in Dilution Air is greater than that in the Residence Chamber Air, a negative number results from the
subtraction. This negative number is treated as ND, or "0."
d ND = not detected.
e Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-29
-------
Table F-4C. Smelt Tank Vent: Field Test (12/16/01), Total SNMOCs Collected
RCa DAb
Residence
RC
Dilution
DA
Chamber
Collected
Air
Collected
No Negsc
Canister
V=421.522
Canister
V=410.535
RC-DA
RC-DA
Compound
CAS No.
(Hg/m3)
(Hg)
(Hg/m3)
(Hg)
(Hg)
(Hg)
ethylene
74-85-1
2410
1015.868
1.070
439.272
576.596
576.596
acetylene
74-86-2
0.720
303.496
0.690
283.269
20.227
20.227
ethane
74-85-1
5.160
2175.054
3.410
1399.924
775.130
775.130
propylene
115-07-1
1.550
653.359
0.520
213.478
439.881
439.881
propane
74-98-6
3.590
1513.264
2.430
997.600
515.664
515.664
propyne
74-99-7
ND
ND
ND
ND
ND
ND
isobutane
75-28-5
0.740
311.926
0.430
176.530
135.396
135.396
isobutene/1 -butene
115-11-7/106-98-0
0.750
316.142
0.430
176.530
139.612
139.612
1,3-butadiene
106-99-0
ND
ND
ND
ND
ND
ND
//-butane
106-97-8
1.620
682.866
0.790
324.323
358.543
358.543
trans-2-butene
624-64-6
0.800
337.218
0.250
102.634
234.584
234.584
c/s-2-butene
590-18-1
1.030
434.168
0.350
143.687
290.481
290.481
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
ND
ND
isopentane
78-78-4
1.480
623.853
0.630
258.637
365.216
365.216
1-pentene
109-67-1
0.850
358.294
0.250
102.634
255.660
255.660
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
ND
ND
//-pcntanc
109-66-0
1.220
514.257
0.400
164.214
350.043
350.043
isoprene
78-79-4
0.960
404.661
0.220
90.318
314.343
314.343
trans-2-pentene
646-04-8
ND
ND
0.300
123.160
-123.160
NDC
c/.v-2-pcntcnc
627-20-3
1.280
539.548
0.330
135.477
404.072
404.072
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
ND
ND
2,2-dimethyl-butane
75-83-2
1.670
703.942
0.470
192.951
510.990
510.990
cyclopentene
142-29-0
ND
ND
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
ND
ND
cyclopentane
287-92-3
0.690
290.850
0.360
147.793
143.058
143.058
2,3 -dimethyl-butane
79-29-8
1.830
771.385
0.550
225.794
545.591
545.591
2-methylpentane
107-83-5
1.280
539.548
0.310
127.266
412.282
412.282
3-methylpentane
96-14-0
1.530
644.929
0.460
188.846
456.083
456.083
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
ND
ND
1-hexene
592-41-6
1.710
720.803
0.500
205.267
515.535
515.535
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
ND
ND
(continued)
F-30
-------
Table F-4C. Smelt Tank Vent: Field Test (12/16/01), Total SNMOCs Collected (continued)
RCa
DAb
Residence
RC
Dilution
DA
Chamber
Collected
Air
Collected
No Negsc
Canister
V=421.522
Canister
V=410.535
RC-DA
RC-DA
Compound
CAS No.
(Hg/m3)
(M-g)
(Hg/m3)
(M-g)
(M-g)
(ng)
//-hcxanc
110-54-3
1.670
703.942
1.140
468.010
235.932
235.932
;rcw?.v-2-hcxcnc
4050-45-7
ND
ND
ND
ND
ND
ND
67.v-2-hc.xcnc
7688-21-3
ND
ND
ND
ND
ND
ND
methylcyclo-
pentane
96-37-7
0.920
387.800
0.380
156.003
231.797
231.797
2,4-dimethyl-
pentane
108-08-7
1.210
510.042
0.330
135.477
374.565
374.565
benzene
71-43-2
0.990
417.307
0.360
147.793
269.514
269.514
cyclohexane
110-82-7
1.570
661.790
0.450
184.741
477.049
477.049
2-methylhexane
591-76-4
1.380
581.700
0.360
147.793
433.908
433.908
2,3-dimethyl-
pentane
565-59-3
3.070
1294.073
0.750
307.901
986.172
986.172
3-methylhexane
589-34-4
0.660
278.205
0.350
143.687
134.517
134.517
1-heptene
592-76-7
ND
ND
ND
ND
ND
ND
2,2,4-trimethyl-
pentane
540-84-1
0.980
413.092
0.300
123.160
289.931
289.931
//-heptane
142-82-5
0.940
396.231
0.200
82.107
314.124
314.124
methylcyclo-hexane
108-87-2
0.980
413.092
0.330
135.477
277.615
277.615
2,2,3-trimethyl-
pentane
564-02-3
ND
ND
ND
ND
ND
ND
2,3,4-trimethyl-
pentane
565-75-3
1.060
446.813
0.240
98.528
348.285
348.285
toluene
108-88-3
3.180
1340.440
0.320
131.371
1209.069
1209.069
2-methylheptane
592-27-8
0.780
328.787
0.180
73.896
254.891
254.891
3-methylheptane
589-81-1
0.670
282.420
0.220
90.318
192.102
192.102
1-octene
111-66-0
ND
ND
ND
ND
ND
ND
//-octane
111-65-9
0.840
354.079
0.230
94.423
259.655
259.655
ethylbenzene
100-41-4
0.710
299.281
ND
ND
299.281
299.281
///-xy 1 c nc/p-xy lc nc
108-38-3/106-42-3
0.940
396.231
0.280
114.950
281.281
281.281
styrene
100-42-5
ND
ND
ND
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
ND
ND
ND
1-nonene
124-11-8
ND
ND
ND
ND
ND
ND
//-nonanc
111-84-2
ND
ND
0.180
73.896
-73.896
NDC
(continued)
F-31
-------
Table F-4C. Smelt Tank Vent: Field Test (12/16/01), Total SNMOCs (concluded)
RCa
DAb
Residence
RC
Dilution
DA
Chamber
Collected
Air
Collected
No Negsc
Canister
V=421.522
Canister
V=410.535
RC-DA
RC-DA
Compound
CAS No.
(Hg/m3)
(M-g)
(Hg/m3)
(M-g)
(M-g)
(ng)
isopropylbenzene
98-82-8
1.040
438.383
ND
ND
438.383
438.383
alpha-pinene
80-56-8
ND
ND
ND
ND
ND
ND
//-propylbcnzcnc
103-65-1
ND
ND
0.150
61.580
-61.580
NDC
///-cthyltolucnc
620-14-4
ND
ND
0.330
135.477
-135.477
NDC
/?-ctln itolucnc
622-96-8
0.720
303.496
0.180
73.896
229.600
229.600
1,3,5-trimethyl-
benzene
108-67-8
ND
ND
ND
ND
ND
ND
o-ethyltoluene
611-14-3
0.610
257.128
0.200
82.107
175.021
175.021
beta-pinene
127-91-3
ND
ND
ND
ND
ND
ND
1,2,4-trimethyl-
benzene
95-63-6
0.790
333.002
0.200
82.107
250.895
250.895
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
«-decane
124-18-5
0.750
316.142
0.190
78.002
238.140
238.140
1,2,3-trimethyl-
benzene
526-73-8
ND
ND
ND
ND
ND
ND
/M-dicthylbcnzcnc
141-93-5
ND
ND
0.160
65.686
-65.686
NDC
/j-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
«-undecane
1120-21-4
ND
ND
ND
ND
ND
ND
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
«-dodecane
112-40-3
ND
ND
ND
ND
ND
ND
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
rt-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
Total Speciated
59.330
25008.903
23.160
9507.988
15500.915
15960.714
Total Unspeciated
50.630
21341.661
3.030
1243.921
20097.740
35598.656
Total (Speciated +
Unspeciated)d
109.960
46350.564
26.190
10751.908
35598.656
51559.370
a RC = residence chamber = combustion air + dilution air
b DA = dilution air
c When the value in Dilution Air is greater than that in the Residence Chamber Air, a negative number results from the
subtraction. This negative number is treated as ND, or "0."
d ND = not detected.
e Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-32
-------
Table F-5A. SNMOC Values for 12/14/01 in SPECIATE Format
RC-DA1' Uncertainty Percent Uncertainty
Compound
CAS No.
(us)
(us)
Total
as % Total
ethylene
74-85-1
512.32
83.38
0.72
0.12
acetylene
74-86-2
77.37
76.97
0.11
0.11
ethane
74-85-1
595.99
69.84
0.84
0.10
propylene
115-07-1
361.25
44.19
0.51
0.06
propane
74-98-6
1040.03
78.39
1.46
0.11
propyne
74-99-7
NDb
ND
ND
ND
isobutane
75-28-5
149.24
39.91
0.21
0.06
isobutene/1 -butene
115-11-7/106-98-0
124.05
25.66
0.17
0.04
1,3-butadiene
106-99-0
ND
ND
ND
ND
/7-butane
106-97-8
372.01
71.98
0.52
0.10
fra«s-2-butene
624-64-6
188.20
46.32
0.26
0.07
cy.v-2-butcnc
590-18-1
209.76
69.13
0.29
0.10
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
isopentane
78-78-4
361.28
103.34
0.51
0.15
1-pentene
109-67-1
171.19
57.73
0.24
0.08
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
/7-pentane
109-66-0
219.64
71.98
0.31
0.10
isoprene
78-79-4
255.81
8.55
0.36
0.01
/ram-2-pentene
646-04-8
ND
ND
ND
ND
cy.v-2-pcntcnc
627-20-3
230.77
86.23
0.32
0.12
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
353.20
105.47
0.50
0.15
cyclopentene
142-29-0
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
cyclopentane
287-92-3
ND
ND
ND
ND
2,3 -dimethy lbutane
79-29-8
495.29
121.87
0.69
0.17
2-methylpentane
107-83-5
234.40
56.30
0.33
0.08
3-methylpentane
96-14-0
639.67
107.61
0.90
0.15
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
1-hexene
592-41-6
408.60
109.04
0.57
0.15
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
/7-hexane
110-54-3
NDC
82.67
NDC
NDC
trans-2-hexene
4050-45-7
ND
ND
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
ND
ND
methylcyclopentane
96-37-7
1713.52
68.42
2.40
0.10
(continued)
F-33
-------
Table F-5A. SNMOC Values for 12/14/01 in SPECIATE Format (continued)
RC-DA" Uncertainty Percent Uncertainty
Compound
CAS No.
(Hg)
(ng)
Total
as % Total
2,4-dimethylpentane
108-08-7
352.30
85.52
0.49
0.12
benzene
71-43-2
483.03
54.16
0.68
0.08
cyclohexane
110-82-7
408.15
121.15
0.57
0.17
2-methylhexane
591-76-4
ND
ND
ND
ND
2,3 -dimethylpentane
565-59-3
674.42
71.27
0.95
0.10
3-methylhexane
589-34-4
196.56
59.86
0.28
0.08
1-heptene
592-76-7
501.25
59.15
0.70
0.08
2,2,4-trimethylpentane
540-84-1
258.24
71.98
0.36
0.10
/7-heptane
142-82-5
271.80
36.35
0.38
0.05
methylcyclohexane
108-87-2
203.38
69.13
0.29
0.10
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
202.75
49.89
0.28
0.07
toluene
108-88-3
1296.49
28.51
1.82
0.04
2-methylheptane
592-27-8
226.23
27.79
0.32
0.04
3-methylheptane
589-81-1
ND
ND
ND
ND
1-octene
111-66-0
ND
ND
ND
ND
/7-octane
111-65-9
268.16
14.25
0.38
0.02
ethylbenzene
100-41-4
ND
ND
ND
ND
«7-xylcnc//>xylcne
108-38-3/106-42-3
ND
ND
ND
ND
styrene
100-42-5
ND
ND
ND
ND
o-xylene
95-47-6
252.36
19.24
0.35
0.03
1-nonene
124-11-8
ND
ND
ND
ND
/7-nonane
111-84-2
ND
ND
ND
ND
isopropylbenzene
98-82-8
216.13
28.51
0.30
0.04
alpha-pinene
80-56-8
313.10
14.97
0.44
0.02
/7-propylbcnzcne
103-65-1
ND
ND
ND
ND
/77-cthyltolucne
620-14-4
ND
ND
ND
ND
/;-ethyltoluene
622-96-8
ND
ND
ND
ND
1,3,5 -trimethylbenzene
108-67-8
232.96
20.67
0.33
0.03
o-ethyltoluene
611-14-3
171.01
22.09
0.24
0.03
beta-pinene
127-91-3
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
254.07
20.67
0.36
0.03
1-decene
872-05-9
ND
ND
ND
ND
«-decane
124-18-5
ND
ND
ND
ND
1,2,3 -trimethylbenzene
526-73-8
ND
ND
ND
ND
(continued)
F-34
-------
Table F-5A. SNMOC Values for 12/14/01 in SPECIATE Format (concluded)
Compound
CAS No.
RC-DA1
(Hg)
Uncertainty
(ng)
Percent
Total
Uncertainty
as % Total
«7-dicthylbcnzcnc
141-93-5
ND
ND
ND
ND
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
«-undccanc
1120-21-4
191.48
13.54
0.27
0.02
1-dodecene
112-41-4
ND
ND
ND
ND
/7-dodccanc
112-40-3
40.96
30.64
0.06
0.04
1-tridecene
2437-56-1
ND
ND
ND
ND
«-tridccanc
629-50-5
ND
ND
ND
ND
Total Speciated
15728.43
Total Unspeciated
45737.11
Total (Speciated + Unspeciated)d
61465.54
a RC = residence chamber = combustion air + dilution air; DA = dilution air.
b ND = not detected.
c w-hexane deleted from 12/14/01 data as a contaminant from the denuders
d Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-35
-------
Table F-5B. SNMOC Values for 12/15/01 in SPECIATE Format
RC-DA1' Uncertainty Percent Uncertainty
Compound
CAS No.
(m-s)
(us)
Total
as % Total
ethylene
74-85-1
4312.01
101.64
5.02
0.12
acetylene
74-86-2
1048.69
93.82
1.22
0.11
ethane
74-85-1
3949.98
85.14
4.60
0.10
propylene
115-07-1
1668.83
53.86
1.94
0.06
propane
74-98-6
1896.99
95.56
2.21
0.11
propyne
74-99-7
NDb
ND
ND
ND
isobutane
75-28-5
369.11
48.65
0.43
0.06
isobutene/1 -butene
115-11-7/106-98-0
789.10
31.27
0.92
0.04
1,3-butadiene
106-99-0
251.72
46.04
0.29
0.05
/7-butane
106-97-8
790.43
87.74
0.92
0.10
fra«s-2-butene
624-64-6
367.11
56.47
0.43
0.07
cy.v-2-butcnc
590-18-1
422.54
84.27
0.49
0.10
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
isopentane
78-78-4
551.41
125.97
0.64
0.15
1-pentene
109-67-1
333.77
70.37
0.39
0.08
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
/7-pentane
109-66-0
411.29
87.74
0.48
0.10
isoprene
78-79-4
329.46
10.42
0.38
0.01
/ram-2-pentene
646-04-8
ND
ND
ND
ND
cy.v-2-pcntcnc
627-20-3
347.47
105.12
0.40
0.12
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
516.29
128.57
0.60
0.15
cyclopentene
142-29-0
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
cyclopentane
287-92-3
443.19
59.94
0.52
0.07
2,3 -dimethy lbutane
79-29-8
576.02
148.55
0.67
0.17
2-methylpentane
107-83-5
ND
ND
ND
ND
3-methylpentane
96-14-0
492.56
131.18
0.57
0.15
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
1-hexene
592-41-6
517.40
132.92
0.60
0.15
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
/7-hexane
110-54-3
ND
ND
ND
ND
fra«s-2-hexene
4050-45-7
ND
ND
ND
ND
(continued)
F-36
-------
Table F-5B. SNMOC Values for 12/15/01 in SPECIATE Format (continued)
RC-DA" Uncertainty Percent Uncertainty
Compound
CAS No.
(ng)
(ng)
Total
as % Total
cv.v-2-hcxcnc
7688-21-3
ND
ND
ND
ND
methylcyclopentane
96-37-7
203.25
83.40
0.24
0.10
2,4-dimethylpentane
108-08-7
414.60
104.25
0.48
0.12
benzene
71-43-2
3230.37
66.02
3.76
0.08
cyclohexane
110-82-7
361.95
147.69
0.42
0.17
2-methylhexane
591-76-4
ND
ND
ND
ND
2,3 -dimethylpentane
565-59-3
907.79
86.87
1.06
0.10
3-methylhexane
589-34-4
ND
ND
ND
ND
1-heptene
592-76-7
ND
ND
ND
ND
2,2,4-trimethylpentane
540-84-1
334.33
87.74
0.39
0.10
/7-heptane
142-82-5
270.62
44.31
0.32
0.05
methylcyclohexane
108-87-2
364.14
84.27
0.42
0.10
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
253.61
60.81
0.30
0.07
toluene
108-88-3
2983.40
34.75
3.47
0.04
2-methylheptane
592-27-8
312.68
33.88
0.36
0.04
3-methylheptane
589-81-1
186.71
33.01
0.22
0.04
1-octene
111-66-0
ND
ND
ND
ND
/7-octane
111-65-9
229.55
17.37
0.27
0.02
ethylbenzene
100-41-4
ND
ND
ND
ND
«7-xylcne//;-xylcne
108-38-3/106-42-3
591.55
36.49
0.69
0.04
styrene
100-42-5
281.09
59.94
0.33
0.07
o-xylene
95-47-6
251.72
23.46
0.29
0.03
1-nonene
124-11-8
ND
ND
ND
ND
/7-nonane
111-84-2
ND
ND
ND
ND
isopropylbenzene
98-82-8
402.76
34.75
0.47
0.04
alpha-pinene
80-56-8
ND
ND
ND
ND
/7-propylbcnzene
103-65-1
ND
ND
ND
ND
/77-cthyltolucne
620-14-4
ND
ND
ND
ND
/;-ethyltoluene
622-96-8
447.05
46.04
0.52
0.05
o-ethyltoluene
611-14-3
ND
ND
ND
ND
beta-pinene
127-91-3
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
396.26
25.19
0.46
0.03
1-decene
872-05-9
ND
ND
ND
ND
«-decane
124-18-5
ND
ND
ND
ND
(continued)
F-37
-------
Table F-5B. SNMOC Values for 12/15/01 in SPECIATE Format (concluded)
Compound
CAS No.
RC-DA1
(ng)
Uncertainty
(ng)
Percent
Total
Uncertainty
as % Total
1,2,3 -trimethy lbenzene
526-73-8
ND
ND
ND
ND
m-dicthylbcnzcnc
141-93-5
ND
ND
ND
ND
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
/7-undccanc
1120-21-4
199.30
16.51
0.23
0.02
1-dodecene
112-41-4
ND
ND
ND
ND
/7-dodccanc
112-40-3
ND
ND
ND
ND
1-tridecene
2437-56-1
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
Total Speciated
33008.094
Total Unspeciated
53865.697
Total (Speciated + Unspeciated)0
86873.792
a RC = residence chamber = combustion air + dilution air; DA = dilution air.
b ND = not detected.
c Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-38
-------
Table F-5C. SNMOC Values for 12/16/01 in SPECIATE Format
RC-DA" Uncertainty Percent Uncertainty
Compound
CAS No.
(m-s)
(us)
Total
as % Total
ethylene
74-85-1
576.60
60.32
1.12
0.12
acetylene
74-86-2
20.23
55.68
0.04
0.11
ethane
74-85-1
775.13
50.53
1.50
0.10
propylene
115-07-1
439.88
31.97
0.85
0.06
propane
74-98-6
515.66
56.72
1.00
0.11
propyne
74-99-7
NDb
ND
ND
ND
isobutane
75-28-5
135.40
28.87
0.26
0.06
isobutene/1 -butene
115-11-7/106-98-0
139.61
18.56
0.27
0.04
1,3-butadiene
106-99-0
ND
ND
ND
ND
/7-butane
106-97-8
358.54
52.07
0.70
0.10
fra«s-2-butene
624-64-6
234.58
33.51
0.45
0.07
cy.v-2-butcnc
590-18-1
290.48
50.01
0.56
0.10
3 -methyl-1 -butene
563-45-1
ND
ND
ND
ND
isopentane
78-78-4
365.22
74.76
0.71
0.15
1-pentene
109-67-1
255.66
41.76
0.50
0.08
2-methyl-1 -butene
563-46-2
ND
ND
ND
ND
/7-pentane
109-66-0
350.04
52.07
0.68
0.10
isoprene
78-79-4
314.34
6.19
0.61
0.01
/ram-2-pentene
646-04-8
ND
ND
ND
ND
cy.v-2-pcntcnc
627-20-3
404.07
62.39
0.78
0.12
2-methyl-2-butene
513-35-9
ND
ND
ND
ND
2,2-dimethylbutane
75-83-2
510.99
76.31
0.99
0.15
cyclopentene
142-29-0
ND
ND
ND
ND
4-methyl-1 -pentene
691-37-2
ND
ND
ND
ND
cyclopentane
287-92-3
143.06
35.58
0.28
0.07
2,3 -dimethy lbutane
79-29-8
545.59
88.17
1.06
0.17
2-methylpentane
107-83-5
412.28
40.73
0.80
0.08
3-methylpentane
96-14-0
456.08
77.85
0.88
0.15
2-methyl-1 -pentene
763-29-1
ND
ND
ND
ND
1-hexene
592-41-6
515.54
78.89
1.00
0.15
2-ethyl-l-butene
760-21-4
ND
ND
ND
ND
/7-hexane
110-54-3
235.93
59.81
0.46
0.12
fra«s-2-hexene
4050-45-7
ND
ND
ND
ND
cv.v-2-hcxcnc
7688-21-3
ND
ND
ND
ND
methylcyclopentane
96-37-7
231.80
49.50
0.45
0.10
(continued)
F-39
-------
Table F-5C. SNMOC Values for 12/16/01 in SPECIATE Format (continued)
RC-DA1' Uncertainty Percent Uncertainty
Compound
CAS No.
(ng)
(ng)
Total
as % Total
2,4-dimethylpentane
108-08-7
374.57
61.87
0.73
0.12
benzene
71-43-2
269.51
39.19
0.52
0.08
cyclohexane
110-82-7
477.05
87.65
0.93
0.17
2-methylhexane
591-76-4
433.91
10.31
0.84
0.02
2,3 -dimethylpentane
565-59-3
986.17
51.56
1.91
0.10
3-methylhexane
589-34-4
134.52
43.31
0.26
0.08
1-heptene
592-76-7
ND
ND
ND
ND
2,2,4-trimethylpentane
540-84-1
289.93
52.07
0.56
0.10
/7-heptane
142-82-5
314.12
26.30
0.61
0.05
methylcyclohexane
108-87-2
277.62
50.01
0.54
0.10
2,2,3-trimethylpentane
564-02-3
ND
ND
ND
ND
2,3,4-trimethylpentane
565-75-3
348.28
36.09
0.68
0.07
toluene
108-88-3
1209.07
20.62
2.35
0.04
2-methylheptane
592-27-8
254.89
20.11
0.49
0.04
3-methylheptane
589-81-1
192.10
19.59
0.37
0.04
1-octene
111-66-0
ND
ND
ND
ND
/7-octane
111-65-9
259.66
10.31
0.50
0.02
ethylbenzene
100-41-4
299.28
13.92
0.58
0.03
«7-xylcne//;-xylcne
108-38-3/106-42-3
281.28
21.65
0.55
0.04
styrene
100-42-5
ND
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
ND
1-nonene
124-11-8
ND
ND
ND
ND
/7-nonane
111-84-2
ND
ND
ND
ND
isopropylbenzene
98-82-8
438.38
20.62
0.85
0.04
alpha-pinene
80-56-8
ND
ND
ND
ND
/7-propylbcnzene
103-65-1
ND
ND
ND
ND
/77-cthyltolucne
620-14-4
ND
ND
ND
ND
/;-ethyltoluene
622-96-8
229.60
27.33
0.45
0.05
1,3,5 -trimethy lbenzene
108-67-8
ND
ND
ND
ND
o-ethyltoluene
611-14-3
175.02
15.98
0.34
0.03
beta-pinene
127-91-3
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
250.90
14.95
0.49
0.03
1-decene
872-05-9
ND
ND
ND
ND
«-decane
124-18-5
238.14
11.34
0.46
0.02
1,2,3 -trimethy lbenzene
526-73-8
ND
ND
ND
ND
(continued)
F-40
-------
Table F-5C. SNMOC Values for 12/16/01 in SPECIATE Format (concluded)
RC-DA1
Uncertainty
Percent
Uncertainty
Compound
CAS No.
(ng)
(ng)
Total
as % Total
«7-dicthylbcnzcnc
141-93-5
ND
ND
ND
ND
/;-dicthylbcnzcnc
105-05-5
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
«-undccanc
1120-21-4
ND
ND
ND
ND
1-dodecene
112-41-4
ND
ND
ND
ND
/7-dodccanc
112-40-3
ND
ND
ND
ND
1-tridecene
2437-56-1
ND
ND
ND
ND
«-tridccanc
629-50-5
ND
ND
ND
ND
Total Speciated
15960.714
Total Unspeciated
35598.656
Total (Speciated + Unspeciated)0
51559.37
a RC = residence chamber = combustion air + dilution air; DA = dilution air.
b ND = not detected.
c Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
F-41
-------
Table F-6. SNMOC, Reported as Weight Percent of Total
RC-DA1
12/14/01
Compound
CAS No.
(Hg)
ethylene
74-85-1
512.3234
acetylene
74-86-2
77.3653
ethane
74-85-1
595.9887
propylene
115-07-1
361.2458
propane
74-98-6
1040.032
propyne
74-99-7
NDb
isobutane
75-28-5
149.2406
isobutene/1 -butene
115-11-7/106-98-0
124.0522
1,3-butadiene
106-99-0
ND
/7-butane
106-97-8
372.0135
fra«s-2-butene
624-64-6
188.2037
cy.v-2-butcnc
590-18-1
209.7552
3 -methyl-1 -butene
563-45-1
ND
isopentane
78-78-4
361.2828
1-pentene
109-67-1
171.1891
2-methyl-1 -butene
563-46-2
ND
/7-pentane
109-66-0
219.639
isoprene
78-79-4
255.8121
/ram-2-pcntcnc
646-04-8
ND
cv.v-2-pcntcnc
627-20-3
230.7667
2-methyl-2-butene
513-35-9
ND
RC-DA
RC-DA
Percent
12/15/01
Percent
12/16/01
Percent
Total
(M-g)
Total
(Hg)
Total
0.718884
4312.014
4.963538
576.5958
1.118314
0.108558
1048.687
1.207138
20.2268
0.03923
0.836282
3949.98
4.546803
775.1299
1.503373
0.506894
1668.826
1.920977
439.881
0.853154
1.459356
1896.989
2.183615
515.6644
1.000137
ND
ND
ND
ND
ND
0.209412
369.1139
0.424885
135.3963
0.262603
0.174068
789.0978
0.908327
139.6115
0.270778
ND
251.7234
0.289758
ND
ND
0.522003
790.4324
0.909863
358.5432
0.695399
0.264084
367.112
0.422581
234.5839
0.454978
0.294325
422.5418
0.486386
290.4805
0.56339
ND
ND
ND
ND
ND
0.506946
551.4064
0.634721
365.2157
0.70834
0.24021
333.7713
0.384203
255.66
0.495856
ND
ND
ND
ND
ND
0.308194
411.2903
0.473434
350.0429
0.678912
0.358951
329.4647
0.379245
314.3435
0.609673
ND
ND
ND
ND
ND
0.323808
347.4697
0.399971
404.0717
0.783702
ND
ND
ND
ND
ND
(continued)
-------
Table F-6. SNMOC, Reported as Weight Percent of Total (continued)
RC-DA1
12/14/01
Compound
CAS No.
(M-g)
2,2-dimethylbutane
75-83-2
353.1989
cyclopentene
142-29-0
ND
4-methyl-1 -pentene
691-37-2
ND
cyclopentane
287-92-3
ND
2,3 -dimethy lbutane
79-29-8
495.2926
2-methylpentane
107-83-5
234.4036
3-methylpentane
96-14-0
639.6733
2-methyl-1 -pentene
763-29-1
ND
1-hexene
592-41-6
408.5996
2-ethyl-l-butene
760-21-4
ND
/7-hexane
110-54-3
NDC
trans-2-hexene
4050-45-7
ND
cv.v-2-hcxcnc
7688-21-3
ND
methylcyclopentane
96-37-7
1713.515
2,4-dimethylpentane
108-08-7
352.2989
benzene
71-43-2
483.0319
cyclohexane
110-82-7
408.1496
2-methylhexane
591-76-4
ND
2,3-dimethylpentane
565-59-3
674.4225
3-methylhexane
589-34-4
196.5575
1-heptene
592-76-7
501.2534
RC-DA
RC-DA
Percent
12/15/01
Percent
12/16/01
Percent
Total
(H-g)
Total
(M-g)
Total
0.495603
516.2862
0.594295
510.9904
0.991072
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
443.1851
0.510148
143.0577
0.277462
0.694987
576.0226
0.663057
545.5912
1.05818
0.328911
ND
ND
412.2824
0.799627
0.897579
492.5597
0.566983
456.0827
0.884578
JD
ND
ND
ND
ND
0.57334
517.3984
0.595575
515.5353
0.999887
ND
ND
ND
ND
ND
NDC
ND
ND
235.9321
0.457593
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
2.404377
203.2506
0.233961
231.797
0.449573
0.49434
414.5959
0.477239
374.5652
0.726474
0.677783
3230.37
3.718463
269.5143
0.522726
0.572709
361.9465
0.416635
477.0489
0.925242
ND
ND
ND
433.9079
0.841569
0.946339
907.7921
1.044955
986.1715
1.912691
0.275806
0
0
134.5173
0.260898
0.703351
ND
ND
ND
ND
(continued)
-------
Table F-6. SNMOC, Reported as Weight Percent of Total (continued)
RC-DA1
12/14/01
Compound
CAS No.
(M-g)
2,2,4-trimethylpentane
540-84-1
258.2421
/7-hcptanc
142-82-5
271.7998
methylcyclohexane
108-87-2
203.3814
2,2,3-trimethylpentane
564-02-3
ND
2,3,4-trimethylpentane
565-75-3
202.7514
toluene
108-88-3
1296.488
2-methylheptane
592-27-8
226.2298
3-methylheptane
589-81-1
ND
1-octene
111-66-0
ND
/7-octanc
111-65-9
268.1628
ethylbenzene
100-41-4
ND
«7-xylcnc//;-xylcnc
108-38-3/106-42-3
ND
styrene
100-42-5
ND
o-xylene
95-47-6
252.3552
1-nonene
124-11-8
ND
/7-nonanc
111-84-2
ND
isopropylbenzene
98-82-8
216.129
alpha-pinene
80-56-8
313.1028
/7-propylbcnzcnc
103-65-1
ND
m-cthvltolucnc
620-14-4
ND
/;-ethyltoluene
622-96-8
ND
RC-DA
RC-DA
Percent
12/15/01
Percent
12/16/01
Percent
Total
(M-g)
Total
(M-g)
Total
0.362361
334.3274
0.384843
289.9311
0.562325
0.381385
270.6181
0.311507
314.1237
0.609247
0.285381
364.14
0.41916
277.6151
0.538438
ND
ND
ND
ND
ND
0.284497
253.6141
0.291934
348.285
0.675503
1.819211
2983.398
3.434175
1209.069
2.345003
0.317442
312.6832
0.359928
254.8909
0.494364
ND
186.7103
0.214921
192.1021
0.372584
ND
ND
ND
ND
ND
0.376282
229.5539
0.264238
259.6555
0.503605
ND
ND
ND
299.2807
0.580458
ND
591.55
0.68093
281.281
0.545548
ND
281.0911
0.323563
ND
ND
0.354101
251.7234
0.289758
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
0.303269
402.7574
0.463612
438.3829
0.850249
0.439341
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
447.0469
0.514593
229.5996
0.445311
(continued)
-------
Table F-6. SNMOC, Reported as Weight Percent of Total (concluded)
RC-DA1
RC-DA
RC-DA
12/14/01
Percent
12/15/01
Percent
12/16/01
Percent
Compound
CAS No.
(M-g)
Total
(M-g)
Total
(M-g)
Total
1,3,5 -trimethy lbenzene
108-67-8
232.9636
0.326891
ND
ND
ND
ND
o-ethyltoluene
611-14-3
171.0091
0.239957
ND
ND
175.0215
0.339456
beta-pinene
127-91-3
ND
ND
ND
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
254.0652
0.3565
396.2573
0.45613
250.8954
0.486615
1-decene
872-05-9
ND
ND
ND
ND
ND
ND
/7-dccanc
124-18-5
ND
ND
ND
ND
238.1399
0.461875
1,2,3 -trimethy lbenzene
526-73-8
ND
ND
ND
ND
ND
ND
m-dicthylbcnzcnc
141-93-5
ND
ND
ND
ND
ND
ND
/;-dicth\ lbenzene
105-05-5
ND
ND
ND
ND
ND
ND
1-undecene
821-95-4
ND
ND
ND
ND
ND
ND
Hrj «-undecane
1120-21-4
191.4806
0.268682
199.2964
0.229409
ND
ND
1-dodecene
112-41-4
ND
ND
ND
ND
ND
ND
/7-dodccanc
112-40-3
40.9592
0.057473
ND
ND
ND
ND
1-tridecene
2437-56-1
ND
ND
ND
ND
ND
ND
/7-tridccanc
629-50-5
ND
ND
ND
ND
ND
ND
15960.71
35598.66
51559.37
a RC = residence chamber = combustion air + dilution air; DA = dilution air.
b ND = not detected.
c w-hexane deleted from 12/14/01 data as a contaminant from the denuders
d Total NMOC with unknowns in |_ig/m3 is an estimate based on propane only.
Total Speciated
Total Unspeciated
Total (Speciated + Unspeciated)d
15728.43
45737.11
61465.54
33008.09
53865.70
86873.79
-------
-------
Appendix G
Data Tables for Individual
Air Toxics Samples
G-l
-------
Contents
Table Page
G-l. Smelt Tank Vent: Field Test (12/14/01) Air Toxics Analysis from
Laboratory Blanks and Field Ambient Sampling G3
G-2A. Smelt Tank Vent: Field Test (12/14/01) Air Toxics Analysis from
Residence Chamber, Dilution Air, and the Difference G5
G-2B. Smelt Tank Vent: Field Test (12/15/01) Air Toxics Analysis from
Residence Chamber, Dilution Air, and the Difference G7
G-2C. Smelt Tank Vent: Field Test (12/16/01) Air Toxics Analysis from
Residence Chamber, Dilution Air, and the Difference G9
G-2
-------
Table G-l. Smelt Tank Vent: Field Test (12/14/01) Air Toxics Analysis from Laboratory
Blanks and Field Ambient Sampling
Laboratory
Blank Ambient
12/14/01 12/14/01
Compound
CAS No.
(Hg/m3)
(Hg/m3)
acetylene
74-86-2
NDa
0.49
propylene
115-07-1
ND
ND
dichlorodifluoromethane
75-71-8
ND
2.94
chloromethane
74-87-3
ND
1.43
dichlorotetrafluoroethane
1320-37-2
ND
ND
vinyl chloride
75-01-4
ND
ND
1,3-butadiene
106-99-0
ND
ND
bromomethane
74-83-9
ND
ND
chloroethane
75-00-3
ND
ND
acetronitrile
75-05-8
ND
ND
acetone
67-64-1
ND
ND
trichlorofluoromethane
75-69-4
ND
1.40
acrylonitrile
107-13-1
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
methylene chloride
75-09-2
ND
159.7 lb
trichlorotrifluororthane
26523-64-8
ND
0.30
trans- 1,2-dichloroethylene
56-60-5
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
chloroprene
126-99-9
ND
ND
cis-1,3-dichloroethylene
156-59-2
ND
ND
bromochloromethane
74-97-5
ND
ND
chloroform
67-66-3
ND
ND
ethyl tert-butyl ether
637-92-3
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
benzene
71-43-2
0.30
1.10
carbon tetrachloride
56-23-5
ND
0.21
tert-amyl methyl ether
994-05-8
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ethyl acrylate
140-88-5
ND
ND
(continued)
G-3
-------
Table G-l. Smelt Tank Vent: Field Test (12/14/01) Air Toxics Analysis from Laboratory
Blanks and Field Ambient Sampling (concluded)
Laboratory
Blank Ambient
12/14/01 12/14/01
Compound
CAS No.
(Hg/m3)
(Hg/m3)
bromodichloromethane
75-27-4
ND
ND
trichloroethylene
79-01-6
ND
ND
methyl methacrylate
80-62-6
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
toluene
108-88-3
0.70
1.28
dibromochloromethane
124-48-1
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
/7-octanc
111-65-9
ND
ND
tetrachloroethylene
127-18-4
ND
ND
chlorobenzene
108-90-7
ND
ND
ethylbenzene
100-41-4
ND
0.25
m-, /^-xylene
108-38-3/106-42-3
ND
0.60
bromoform
75-25-2
ND
ND
styrene
100-42-5
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
o-xylene
95-47-6
ND
0.19
1,3,5 -trimethy lbenzene
106-67-8
ND
ND
1,2,4-trimethy lbenzene
95-63-6
ND
0.44
«?-d i ch 1 o ro be n ze n e
541-73-1
ND
ND
chloromethylbenzene
100-44-7
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
1,2,4,-trichlorobenzene
120-82-1
ND
ND
hexachloro- 1,3-butadiene
87-68-3
ND
ND
a ND = not detected.
b Methylene chloride from 12/14/01 has bee deleted as a contaminant from the solvents used for the denuders.
G-4
-------
Table G-2A. Smelt Tank Vent: Field Test (12/14/01) Air Toxics Analysis from Residence
Chamber, Dilution Air, and the Difference
RCa
DAb
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA
Ambient
Compound
CAS No.
(Hg/m3
(Hg/m3
(Hg/m3)
(Hg/m3)
acetylene
74-86-2
NDC
0.59
-0.59
0.49
propylene
115-07-1
ND
0.77
-0.77
ND
dichlorodifluoromethane
75-71-8
4.06
4.72
-0.66
2.94
chloromethane
74-87-3
1.38
1.97
-0.59
1.43
dichlorotetrafluoroethane
1320-37-2
ND
ND
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
ND
acetronitrile
75-05-8
ND
ND
ND
ND
acetone
67-64-1
ND
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
ND
ND
1.40
acrylonitrile
107-13-1
ND
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
ND
methylene chloride
75-09-2
ND
3.87
-3.87
159.7 ld
trichlorotrifluororthane
26523-64-8
ND
ND
ND
0.30
trans- 1,2-dichloroethylene
56-60-5
ND
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
ND
methyl ethyl ketone
78-93-3
12.67
ND
12.67
ND
chloroprene
126-99-9
ND
ND
ND
ND
cis-1,3-dichloroethylene
156-59-2
ND
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
ND
ethyl tert-butyl ether
637-92-3
ND
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
ND
benzene
71-43-2
1.16
0.36
0.80
1.10
carbon tetrachloride
56-23-5
ND
ND
ND
0.21
tert-amyl methyl ether
994-05-8
ND
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
ND
(continued)
G-5
-------
Table G-2A. Smelt Tank Vent: Field Test (12/14/01) Air Toxics Analysis from Residence
Chamber, Dilution Air, and the Difference (concluded)
RCa
DAb
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA
Ambient
Compound
CAS No.
(Hg/m3
(Hg/m3
(Hg/m3)
(Hg/m3)
bromodichloromethane
75-27-4
ND
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
ND
ND
toluene
108-88-3
3.83
0.37
3.46
1.28
dibromochloromethane
124-48-1
ND
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
ND
/7-octane
111-65-9
ND
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ND
ethylbenzene
100-41-4
ND
ND
ND
0.25
m-, /^-xy lene
108-38-3/106-42-3
ND
ND
ND
0.60
bromoform
75-25-2
ND
ND
ND
ND
styrene
100-42-5
ND
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
0.19
1,3,5 -trimethy lbenzene
106-67-8
ND
ND
ND
ND
1,2,4-trimethy lbenzene
95-63-6
ND
ND
ND
0.44
«7-d i ch 1 o ro be n ze n e
541-73-1
ND
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
ND
1,2,4,-trichlorobenzene
120-82-1
ND
ND
ND
ND
hexachloro- 1,3-butadiene
87-68-3
ND
ND
ND
ND
a RC = residence chamber.
b DA = dilution air.
c ND = not detected.
d Methylene chloride from 12/14/01 has bee deleted as a contaminant from the solvents used for the denuders.
G-6
-------
Table G-2B. Smelt Tank Vent: Field Test (12/15/01) Air Toxics Analysis from
Residence Chamber, Dilution Air, and the Difference
RCa
DAb
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA
Compound
CAS No.
(Ug/m3
(Ug/m3
(Ug/m3)
acetylene
74-86-2
2.48
0.67
1.81
propylene
115-07-1
NDC
ND
ND
dichlorodifluoromethane
75-71-8
2.57
2.73
-0.16
chloromethane
74-87-3
ND
1.19
-1.19
dichlorotetrafluoroethane
1320-37-2
ND
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
acetronitrile
75-05-8
ND
ND
ND
acetone
67-64-1
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
ND
ND
acrylonitrile
107-13-1
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
methylene chloride
75-09-2
28.20
18.70
9.5
trichlorotrifluororthane
26523-64-8
ND
ND
ND
trans-1,2-dichloroethylene
56-60-5
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
chloroprene
126-99-9
ND
ND
ND
cis-1,3 -dichloroethylene
156-59-2
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
ethyl tert-butyl ether
637-92-3
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
benzene
71-43-2
7.91
0.35
7.56
carbon tetrachloride
56-23-5
ND
ND
ND
tert-amyl methyl ether
994-05-8
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
(continued)
G-7
-------
Table G-2B. Smelt Tank Vent: Field Test (12/15/01) Air Toxics Analysis from
Residence Chamber, Dilution Air, and the Difference (concluded)
RCa DAb
Residence Dilution Air Toxics
Chamber Air RC-DA
Compound
CAS No.
(Ug/m3
(Ug/m3
(Ug/m3)
bromodichloromethane
75-27-4
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
ND
toluene
108-88-3
7.13
0.28
6.85
dibromochloromethane
124-48-1
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
/7-octane
111-65-9
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ethylbenzene
100-41-4
ND
ND
ND
m-, />-xylene
108-38-3/106-42-3
ND
ND
ND
bromoform
75-25-2
ND
ND
ND
styrene
100-42-5
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
1,3,5 -trimethylbenzene
106-67-8
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
ND
ND
ND
/77-dichlorobcnzcne
541-73-1
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
1,2,4,-trichlorobenzene
120-82-1
ND
ND
ND
hexachloro- 1,3-butadiene
87-68-3
ND
ND
ND
a RC = residence chamber.
b DA = dilution air.
c ND = not detected.
G-8
-------
Table G-2C. Smelt Tank Vent: Field Test (12/16/01) Air Toxics Analysis from
Residence Chamber, Dilution Air, and the Difference
RCa
DAb
Residence
Dilution
Air Toxics
Chamber
Air
RC-DA
Compound
CAS No.
(Ug/m3
(Ug/m3
(Ug/m3)
acetylene
74-86-2
NDC
0.57
-0.57
propylene
115-07-1
ND
ND
ND
dichlorodifluoromethane
75-71-8
ND
1.67
-1.67
chloromethane
74-87-3
ND
0.87
-0.87
dichlorotetrafluoroethane
1320-37-2
ND
ND
ND
vinyl chloride
75-01-4
ND
ND
ND
1,3-butadiene
106-99-0
ND
ND
ND
bromomethane
74-83-9
ND
ND
ND
chloroethane
75-00-3
ND
ND
ND
acetronitrile
75-05-8
ND
ND
ND
acetone
67-64-1
ND
ND
ND
trichlorofluoromethane
75-69-4
ND
ND
ND
acrylonitrile
107-13-1
ND
ND
ND
1,1 -dichloroethene
75-35-4
ND
ND
ND
methylene chloride
75-09-2
2.99
4.11
-1.12
trichlorotrifluororthane
26523-64-8
ND
ND
ND
trans-1,2-dichloroethylene
56-60-5
ND
ND
ND
1,1 -dichloroethane
75-34-3
ND
ND
ND
methyl tert-butyl ether
1634-04-1
ND
ND
ND
methyl ethyl ketone
78-93-3
ND
ND
ND
chloroprene
126-99-9
ND
ND
ND
cis-1,3 -dichloroethylene
156-59-2
ND
ND
ND
bromochloromethane
74-97-5
ND
ND
ND
chloroform
67-66-3
ND
ND
ND
ethyl tert-butyl ether
637-92-3
ND
ND
ND
1,2-dichloroethane
107-06-2
ND
ND
ND
1,1,1 -trichloroethane
71-55-6
ND
ND
ND
benzene
71-43-2
ND
0.30
-0.30
carbon tetrachloride
56-23-5
ND
ND
ND
tert-amyl methyl ether
994-05-8
ND
ND
ND
1,2-dichloropropane
78-87-5
ND
ND
ND
ethyl acrylate
140-88-5
ND
ND
ND
(continued)
G-9
-------
Table G-2C. Smelt Tank Vent: Field Test (12/16/01) Air Toxics Analysis from
Residence Chamber, Dilution Air, and the Difference (concluded)
RCa DAb
Residence Dilution Air Toxics
Chamber Air RC-DA
Compound
CAS No.
(Ug/m3
(Ug/m3
(Ug/m3)
bromodichloromethane
75-27-4
ND
ND
ND
trichloroethylene
79-01-6
ND
ND
ND
methyl methacrylate
80-62-6
ND
ND
ND
cis-1,2-dichloropropene
10061-01-5
ND
ND
ND
methyl isobutyl ketone
108-10-1
ND
ND
ND
trans-1,2-dichloropropene
10061-02-6
ND
ND
ND
1,1,2-trichloroethane
79-00-5
ND
ND
ND
toluene
108-88-3
2.94
0.26
2.68
dibromochloromethane
124-48-1
ND
ND
ND
1,2-dibromoethane
106-93-4
ND
ND
ND
/7-octane
111-65-9
ND
ND
ND
tetrachloroethylene
127-18-4
ND
ND
ND
chlorobenzene
108-90-7
ND
ND
ND
ethylbenzene
100-41-4
ND
ND
ND
m-, />-xylene
108-38-3/106-42-3
ND
ND
ND
bromoform
75-25-2
ND
ND
ND
styrene
100-42-5
ND
ND
ND
1,1,2,2-tetrachloroethane
79-34-5
ND
ND
ND
o-xylene
95-47-6
ND
ND
ND
1,3,5 -trimethylbenzene
106-67-8
ND
ND
ND
1,2,4-trimethylbenzene
95-63-6
ND
ND
ND
m-dichlorobcnzcnc
541-73-1
ND
ND
ND
chloromethylbenzene
100-44-7
ND
ND
ND
/;-dichlorobenzene
106-46-7
ND
ND
ND
o-dichlorobenzene
95-50-1
ND
ND
ND
1,2,4,-trichlorobenzene
120-82-1
ND
ND
ND
hexachloro- 1,3-butadiene
87-68-3
ND
ND
ND
a RC = residence chamber.
b DA = dilution air.
c ND = not detected.
G-10
-------
Appendix H
Data Tables for Individual
PM25 Elemental Samples
H-l
-------
Table H-l. Smelt Tank Vent Individual PM25 Elemental Samples: XRF Elemental Analysis
Results by Sample
wt% of PM2 5 Mass
T102201J
T102201K
T102201S
T102201T
T082101N
T100301A
IB121401H
IB121401H
IB121501H
IB121501H
IB121601H
IB121601H
Element
R2A1
R2B1
R2A1
R2B1
R2A1
R2B1
Sodium
13.55
13.93
16
19.97
11.05
11.21
Magnesium
0.0206
0.0287
0.0288
0.0346
0.0233
0.0202
Silicon
0.0637
0.0737
0.0694
0.0622
0.052
0.055
Phosphorus
0.0045
0.0058
0.0056
0.0047
0.0063
Sulfur
9.03
9.49
10.72
11.69
7.05
7.33
Chlorine
1.87
1.59
1.66
1.69
1.32
1.41
Potassium
4.98
4.97
5.27
5.14
4.47
4.68
Calcium
0.057
0.056
0.0533
0.0508
0.0554
0.0585
Vanadium
NDa
ND
ND
ND
ND
ND
a ND = not detected
H-2
-------
Appendix I
Data Tables for Individual
PM25 EC/OC Samples
i-i
-------
Table 1-1. Smelt Tank Vent EC/OC Carbon Samples: NIOSH Method 5040 EC/OC Data by
Sample
wt% of PM2 5 Mass
Filter ID
OC
EC
Q10
501H IB121401HR4A1
2.8
0.3
Q10
501K IB121401HR4B1
2.9
0.1
Q10
501J IB121401HR8A1
2.1
0.2
Q10
501L IB121401HR4B1
2.1
0.2
Q10
501M IB121401HR10A3
2.2
0.2
Q10
501N IB121401HR10B1
1.7
0.1
Q10
501T IB121501HR4A1
4.5
0.2
Q10
501U IB121501HR4B1
4.6
0.2
Q10
501S IB121501HR8A1
4.7
0.2
Q10
501RIB121501HR8B1
4.6
0.2
Q10
501P IB121501HR10A3
4.6
0.2
Q10
501Q IB121501HR10B3
3.6
0.1
Q10
601C IB121601HR4A1
3.2
0.2
Q10
601B IB121601HR4B1
3.4
0.3
Q10
601D IB121601HR8A1
5.7
0.2
Q10
601E IB121601HR8B1
5.7
0.2
Q10
601F IB121601HR10A3
8.0
0.3
Q10
601GIB121601HR10B3
3.7
0.2
1-2
-------
Appendix J
Data Tables for Individual
PM25 Inorganic Ion Samples
j-i
-------
Contents
Table Page
J-l. Ion Chromatography Calibration Ranges for PM2 5 Inorganic Ion
Analysis: Smelt Tank Vent J-3
J-2. Smelt Tank Vent Inorganic Ion Samples: Ion Chromatography Results by Sample . J-4
J-2
-------
Table J-l. Ion Chromatography Calibration Ranges for PM25 Inorganic Ion Analysis: Smelt
Tank Vent
Ion
High
Cone.
(PPm)
Low
Cone.
(PPm)
Ammonium
2.67
0.97
Calcium
2.3
0.83
Chloride
5.2
2.8
Magnesium
2.8
1.02
Nitrate
5.2
2.8
Potassium
2.6
0.95
Sulfate
5.3
2.85
J-3
-------
Table J-2. Smelt Tank Vent Inorganic Ion Samples: Ion Chromatography Results by
Sample
wt% of PM2 5 Mass
T102201L
T102201N
T102201Q
T102201R
T100301C
T100301D
IB121401H
IB121401H
IB121501H
IB121501H
IB121601H
IB121601H
Ion
R6A1
R6B1
R6A1
R6B1
R6A1
R6B1
Ammonium
NDa
ND
ND
ND
ND
ND
Calcium
ND
ND
ND
ND
ND
ND
Chloride
1.94
1.92
1.61
1.65
1.84
1.74
Magnesium
ND
ND
ND
ND
ND
ND
Nitrate
ND
ND
ND
ND
ND
ND
Potassium
4.72
4.64
4.50
4.51
4.79
4.70
Sulphate
11.69
11.32
18.43
20.10
9.40
9.48
S90,
14.10
13.37
10.75
10.67
12.30
12.01
a ND = not detected
J-4
-------
Appendix K
Data Tables for Individual
Semivolatile Organic Compounds
K-l
-------
Contents
Table Page
K-l. Calibration Ranges forPM Speciated Organic Compounds, Standard Suite 1 .... K-3
K-2. Calibration Ranges for PM Speciated Organic Compounds, Standard Suite 2 ... . K-5
K-3. Calibration Ranges forPM Speciated Organic Compounds, Standard Suite 3 . . . . K-7
K-2
-------
Table K-l. Calibration Ranges for PM Speciated Organic Compounds, Standard Suite 1
High Cone. Low Cone.
Compound (jlg/mL) (jj,g/mL)
dimethyl phthalate
19
0.8
diethyl phthalate
19
0.8
naphthalene
10
0.8
2-methylnaphthalene
21.28
0.968
1 -methylnaphthalene
21.28
0.896
2,7-dimethylnaphthalene
18.24
0.768
1,3-dimethylnaphthalene
18.24
0.768
2,6-dimethylnaphthalene
18.24
0.768
acenaphthalene
38
1.6
acenaphthene
19
0.8
fluorene
3.8
0.16
1 -methylfluorene
9.5
0.4
phenanthrene
1.9
0.08
anthracene
1.9
0.08
9-methylanthracene
18.62
0.784
octylcyclohexane
9.5
0.4
norpristane
9.5
0.4
decylcyclohexane
9.5
0.4
pristane
9.5
0.4
phytane
9.5
0.4
tridecylcyclohexane
9.5
0.4
dibutyl phthalate
19
0.8
butyl benzyl phthalate
19
0.8
6z's(2-ethylhexyl) phthalate
19
0.8
dioctyl phthalate
19
0.8
fluoranthene
3.8
0.16
pyrene
1.9
0.08
chrysene
1.9
0.08
benzo[a]anthracene
1.9
0.08
b enzo [k] fluoranthene
1.9
0.08
b enzo [b ] fluoranthene
3.8
0.16
benzo[a]pyrene
1.9
0.08
(continued)
K-3
-------
Table K-l. Calibration Ranges for PM Speciated Organic Compounds, Standard Suite 1
(concluded)
High Cone. Low Cone.
Compound (|lg/mL) (|lg/mL)
nonadecylcyclohexane
9.5
0.4
squalane
19.855
0.836
ideno[ 1,2,3 -cdjpyrene
1.9
0.08
dib enzo [a, h] anthracene
3.8
0.16
benzo[ghi]perylene
3.8
0.16
coronene
2.375
0.1
cholestane 1
0.95
0.04
cholestane 2
0.95
0.04
cholestane 3
0.95
0.04
cholestane 4
0.95
0.04
ABB-20R-24S-methylcholestane
0.95
0.04
ABB-20R-ethylcholestane
0.95
0.04
17A(H)-22,29,30-trisnorhopane
0.95
0.04
17B(H)-21 A(H)-norhopane
0.95
0.04
17B(H)-2 lB(H)-hopane
0.95
0.04
17B(H)-21 A(H)-hopane
0.95
0.04
17A(H)-2 lB(H)-hopane
0.95
0.04
K-4
-------
Table K-2. Calibration Ranges for PM Speciated Organic Compounds, Standard Suite 2
High Cone. Low Cone.
Compound
(M-g/mL)
(M-g/mL)
«-decane (n-CIO)
8.2
0.41
«-undecane (n-Cl 1)
8.2
0.41
«-dodecane (n-C12)
8.2
0.41
«-tridecane (n-C13)
8.2
0.41
9h-fluoren-9-one
8.68
0.434
«-tetradecane (n-C14)
8.2
0.41
«-pentadecane (n-C15)
8.2
0.41
«-hexadecane (n-C16)
8.2
0.41
«-heptadecane (n-C17)
8.2
0.41
1-octadecene
15.32
0.766
«-octadecane (n-C18)
8.2
0.41
2-methylnonadecane (/.so-C20)
1.96
0.098
3 -methylnonadecane {anteiso-C20)
1.96
0.098
«-nonadecane (n-C19)
8.2
0.41
«-eicosane (n-C20)
8.2
0.41
«-heneicosane (n-C21)
8.2
0.41
«-docosane (n-C22)
8.2
0.41
«-tricosane (n-C23)
8.2
0.41
z'so-docosane (n-C23)
8.2
0.41
anteiso-docosane (n-C23)
8.2
0.41
pyrene
0.4
0.02
anthraquinone
4.72
0.236
naphthalic anhydride
8.16
0.408
methylfluoranthene
0.4
0.02
retene
1.96
0.098
acepyrene (cyclopenta[c,d]pyrene)
1.96
0.098
benzanthraquinone
8.28
0.414
1 -methylchry sene
0.4
0.02
benzo[a]pyrene
3.92
0.196
«-tetracosane (n-C24)
8.2
0.41
/.so-tricosane (C24)
8.2
0.41
awfe/so-tricosane (C24)
8.2
0.41
«-pentacosane (n-C25)
8.2
0.41
/.so-tetracosane (C25)
8.2
0.41
(continued)
K-5
-------
Table K-2. Calibration Ranges for PM Speciated Organic Compounds, Standard Suite 2
(concluded)
High Cone. Low Cone.
Compound
(P-g/mL)
(P-g/mL)
anteiso-tetracosane (C25)
8.2
0.41
«-hexacosane (n-C26)
8.2
0.41
/.so-pentacosane (C26)
8.2
0.41
c//7/f/.so-pentacosane (C26)
8.2
0.41
heptacosane («-C27)
8.2
0.41
z'so-hexacosane (C27)
8.2
0.41
anteiso-hexacosane (C27)
8.2
0.41
/.so-heptacosane (C28)
8.2
0.41
awfe/so-heptacosane (C28)
8.2
0.41
/'so-octacosane (C29)
8.2
0.41
anteiso-octacosane (C29)
8.2
0.41
octacosane (n-C28)
8.2
0.41
nonacosane (n-C29)
8.2
0.41
/'so-nonacosane (C30)
8.2
0.41
anteiso-nonacosane (C30)
8.2
0.41
squalene
16.56
0.828
dibenzo[a,e]pyrene
0.4
0.02
hexatriacontane-d74
10.15
10.15
//-triacontane (n-C30)
17.2
0.86
//-hentriacontane (n-C31)
17.2
0.86
/.so-tri acontane (C31)
17.2
0.86
anteiso-tnacontane (C31)
17.2
0.86
/.so-hentri acontane (C32)
8.2
0.41
anteiso-hentriacontane (C32)
8.2
0.41
z'so-dotriacontane (C33)
8.2
0.41
anteiso-dotriacontane (C33)
8.2
0.41
dotriacontane (n-C32)
8.2
0.41
tritriacontane (n-C33)
8.2
0.41
tetratriacontane (n-C34)
8.2
0.41
/so-tri tri acontane (C34)
8.2
0.41
anteiso-in tri acontane (C34)
8.2
0.41
pentatriacontane (//-C35)
8.2
0.41
hexatriacontane (//-C36)
8.2
0.41
tetracontane (n-C40)
8.2
0.41
K-6
-------
Table K-3. Calibration Ranges for PM Speciated Organic Compounds, Standard Suite 3
High Cone. Low Cone.
Compound
(|Ig/mL)
(M-g/mL)
caproic or hexanoic acid, methyl ester
18.68
0.75
succinic or butanedioic acid, methyl ester
6.13
0.25
caprylic or octanoic acid, methyl ester
18.53
0.74
glutaric or pentanedioic acid, dimethyl ester
7.25
0.29
nonanoic acid, methyl ester
14.66
0.59
adipic or hexanedioic acid, dimethyl ester
6.27
0.25
capric or decanoic acid, methyl ester
14.66
0.59
undecanoic acid, methyl ester
14.66
0.59
pimelic or heptanedioic acid, dimethyl ester
6.32
0.25
suberic or octanedioic acid, dimethyl ester
6.32
0.25
dodecanoic acid, methyl ester
17.16
0.69
azelaic or nonanedioic acid, dimethyl ester
5.64
0.23
tridecanoic acid, methyl ester
17.16
0.69
pinonic acid, methyl ester
22.11
0.88
dimethyl phthalate
6.18
0.25
1,4-benzenedicarboxylic acid, methyl ester
6.08
0.24
1,3-benzenedicarboxylic acid, methyl ester
6.42
0.26
1,2-benzenedicarboxylic acid, 4-methyl
6.27
0.25
1,2,4-benzenetricarboxylic acid, methyl ester
6.03
0.24
benzenetetracarboxylic acid, methyl ester
5.93
0.24
abietic acid, methyl ester
17.16
0.71
pimaric acid, methyl ester (secondary)
17.16
0.71
sandaracopimaric acid, methyl ester (secondary std)
17.16
0.69
isopimaric acid, methyl ester (secondary std)
17.16
0.71
6,18,11,13-abetatetraen-18-oic acid, methyl ester
17.16
0.71
dehydroabdietic acid, methyl ester (secondary std)
17.16
0.71
sebacic or decanedioic acid, dimethyl ester
5.74
0.23
tetradecanoic acid, methyl ester
15.05
0.6
pentadecanoic acid, methyl ester
15.05
0.6
palmitoleic or 9-hexadecanoic acid, methyl ester
15.74
0.63
hexadecanoic acid, methyl ester
14.71
0.59
heptadecanoic acid, methyl ester
14.71
0.59
(continued)
K-7
-------
Table K-3. Calibration Ranges for PM Speciated Organic Compounds, Standard Suite 3
(concluded)
High Cone. Low Cone.
Compound
(Hg/mL)
(P-g/mL)
linoleic or 8,11-octadecadienoic acid, methyl ester
14.07
0.56
oleic or 9-octadecenoic acid, methyl ester
16.52
0.66
linolenic or 9,12,15-octadecatrienoic acid, methyl ester
17.6
0.7
octadecanoic acid, methyl ester
11.67
0.47
nonadecanoic acid, methyl ester
11.67
0.47
eicosanoic acid, methyl ester
12.06
0.48
heneicosanoic acid, methyl ester
12.06
0.48
docosanoic acid, methyl ester
12.21
0.49
tricosanoic acid, methyl ester
12.21
0.49
tetracosanoic acid, methyl ester
13.73
0.55
pentacosanoic acid, methyl ester
13.73
0.55
hexacosanoic acid, methyl ester
13.73
0.55
heptacosanoic acid, methyl ester
14.85
0.59
octacosanoic acid, methyl ester
14.85
0.59
nonacosanoic acid, methyl ester
14.85
0.59
triacontanoic acid, methyl ester
14.85
0.58
K-8
-------
Appendix L
List of ERG SOPs and EPA MOPs by Title
L-l
-------
Table L-l. ERG Standard Operating Procedures by Title
SOP
No. SOP Title
1 Documentation of Field Recovery Activities
2 Gravimetric Determination for Particulate Emissions Measurements
3 Field Procedure for Collecting Ambient Air Toxics and Carbonyl Compounds Samples
using the ERG:AT/C Sampling System
3B Field Procedure for Collecting Ambient Air Toxics and Carbonyl Compounds Samples
using the ERG:AT/C Sampling System
4 SOP for Preventive Maintenance in the Gas Chromatography/Mass Spectrometry
Laboratory
5 SOP for the Concurrent GC/FID/MS Analysis of Canister Air Toxic Samples
6 SOP for the Analysis of Tenax Tubes According to EPA Method TO-l/TO-17
7 SOP for the Preparation of Review Packages for Mass Spectrometry Data Sets
8 Procedure for Preparation of Standard Operating Procedures
9 SOP for the Operation of the Documentation System
10 SOP for the Determination of Method Detection Limits in the GC/MS Air Toxics
Laboratory
11 SOP for Sample Storage and Checkout from Freezers/Refrigerators at the Laboratory
12 SOP for Basic Training Requirements for Sample Preparation Laboratory Personnel
13 Field Procedure for Collecting Ambient Air Hexavalent Chromium Samples Using the
ERG:CR6 Sampling System
14 SOP for Sample Preparation Quality Control
15 SOP for Documentation Procedures for the Sample Preparation Laboratory
16 SOP for the Varian 9000 Series High Performance Liquid Chromatograph (HPLC)
17 SOP for Developing, Documenting, and Evaluating the Accuracy of Spreadsheet Data
18 Maintaining and Recording Data Records
19 SOP for Transferring, Storing, and Using Confidential Business Information (CBI)
20 SOP for Conducting a Laboratory Systems Audit
21 Calibration and Operation of Analytical Balances
22 SOP for the Preparation of Standards in the ERG Organic Preparation Laboratory
23 SOP for the Use of Significant Figures and Rounding Off Numbers When Reporting Data
24 SOP for Preparing Aldehyde Derivatizing Reagents and Extracting Derivatized Samples
25 SOP for the Operation of the Rainin High Performance Liquid Chromatography System
26 SOP for Documentation: Labeling of Samples and Standards Prepared in the Laboratory
27 SOP for the Operation of a Gas Chromatograph
28 SOP for Quality Assurance/Quality Control in Gas Chromatography/Mass Spectrometry
29 SOP for Concentration of Sample Extracts Using the Kuderna-Danish Concentrator
30 SOP for Canister Sampling System Certification Procedures
(continued)
L-2
-------
Table L-l. ERG Standard Operating Procedures by Title (continued)
SOP
No.
SOP Title
31
32
SOP for Cleaning Glassware and Syringes for Organic Analysis
Statistical Manual Standard Operating Procedure
33 SOP for Solid and Hazardous Waste Disposal
34 Analytical Chemistry Training at PPK Laboratory
35 SOP for Quality Assurance/Quality Control
36 SOP for Laboratory Security
37 SOP for Chemical Inventory
38 SOP for Personal Protective Equipment Program
39 SOP for Maintaining Laboratory Notebooks
40 SOP for Chemical Storage Facilities
41 SOP for Tracer Gas Release and Integrated Bag Sampling for Analysis by FTIR
Spectroscopy
42 SOP for the Dionex-300 Ion Chromatograph
43 SOP for the Analysis of Semivolatile Organic Compounds in Gaseous Emissions using
the SemiVOST Method
44 SOP for Method 82'70C - GC/MS Analysis of Semivolatile Organics
45 SOP for Sample Log-in at the ERG Chemistry Laboratory
46 Field Procedure for Collecting Speciated and/or Total Nonrnethane Organic Compounds
Ambient Air Samples Using the ERG:S/NMOC Sampling System
47 Field Procedure for Collecting Ambient Carbonyl Compounds Samples Using the ERG:C
Sampling System
47B Field Procedure for Collecting Ambient Carbonyl Compounds Samples Using the ERG:C
Sampling System
48 SOP for Cleaning XAD-2 with Quality Control Measures to Assure Cleanliness
49 SOP for the Extraction and Analysis of PAHs from XAD-20 Traps
50 SOP for Separatory Funnel Liquid-Liquid Extraction by EPA SW-846 Method 3510C
51 SOP for Continuous Liquid-Liquid Extraction by EPA SW-846 Method 3520C
52 SOP for Acid-Base Partition Cleanup by EPA SW-846 Method 3650B
53 SOP for Soxhlet Extraction by EPA SW-846 Method 3540C
54 SOP for Preparation, Evaluation, and Shipping of Performance Evaluation Samples for
Method 24
55 SOP for Maintenance of NANOPure-A Deionized Water System
56 SOP for Daily Maintenance of Cold Storage Units
57 SOP for Project Peer Review
58 SOP for Preparing Method 25 Audit Samples Using the Transfill System
59 SOP for High Performance Liquid Chromatography
(continued)
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Table L-l. ERG Standard Operating Procedures by Title (concluded)
SOP
No. SOP Title
60 SOP for PDFID Sample Analysis
61 SOP for Standard Preparation Using Dynamic Flow Dilution System
62 SOP for UATMP and NMOC Canister Cleaning
63 SOP for the Analysis of Ambient Air for Hexavalent Chromium by IC
64 SOP for Shipping Method 6, 7, 8, and 26 Audit Samples
65 SOP for the ERG Sample Database
66 Cylinder Recycling
67 SOP for Producing Standard Mixtures of Organic Compounds in Air by Liquid Injection
68 SOP for Refrigerator and Freezer Temperature Monitoring
69 SOP for Shipping Method 23 Audit Samples
70 SOP for Storing and Shipping Method 13A, 13B, and 29 Audit Samples
71 SOP for Documentation Requirements for the GC/MS Laboratory and for GC/MS
Systems in the VOC Laboratory
72 SOP for Stack Sampling Using FTIR Spectroscopy
73 SOP for the ECD Wipe Test
74 SOP for the Preparation of Spiked Sorbent Samples Using Liquid Spiking into Tenax-GC
Tubes
75 SOP for the Preparation of Spiked Sorbent Samples Using Liquid Spiking onto XAD-2
76 SOP for the Preparation of Spiked Sorbent Samples Using Flash Evaporation Spiking
onto XAD-2
77 SOP for Method 624
78 SOP for Method 625
79 SOP for Method 1624C
80 SOP for Method 1625C
81 SOP for the Preparation of Spiked Method 8 Samples as Stationary Source Audit
Materials
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Table L-2. EPA Method Operating Procedures by Title
MOP No. MOP Title
2501
Preparation of Clean Substrates, Glassware, and Other Materials
2502
Purification of Benzene Solvent
2503
Mass Measurements of Blank and Exposed Sampling Substrates
2504
Solvent Extraction of Samples and Extract Concentration
2505
Diazomethane Preparation and Extract Methylation
2506
Silylation of Methylated Extracts
2507
GC/MS Calibration and Analysis of Extracts
2508
Denuder Coating, Cleanup, and Extraction
2509
PUF Cleanup and Extraction
NIOSH Method 5040
Elemental/Organic Carbon Analysis
L-5
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TECHNICAL REPORT DATA
1. REPORT NO. 2.
EPA-600/R-03/101 b
3. RECIPIENT'S ACCESSION NO.
4. TITLE AND SUBTITLE
Source Sampling Fine Particulate Matter: Stationary Source
Characterization Testing of a Smelt Tank at a Pulp and Paper
Farility Vnliimp ? Annpndirps
5. REPORT DATE
November 2003
6. PERFORMING ORGANIZATION CODE
7. AUTHORS ' ' '
Joan T. Bursey and Dave-Paul Dayton
8. PERFORMING ORGANIZATION REPORT NO.
9. PERFORMING ORGANIZATION NAME AND ADDRESS
Eastern Research Group, Inc.
1600 Perimeter Park Drive
Morrisville, NC 27560
10. PROGRAM ELEMENT NO.
11. CONTRACT/GRANT NO.
Contract No. 68-D7-0001
12. SPONSORING AGENCY NAME AND ADDRESS
U. S. EPA, Office of Research and Development
Air Pollution Prevention and Control Division
Research Triangle Park, North Carolina 27711
13. TYPE OF REPORT AND PERIOD COVERED
Final; 02/05/01 - 05/30/03
14. SPONSORING AGENCY CODE
EPA/600/13
15. SUPPLEMENTARY NOTES
The EPA Project Officer is N. Dean Smith, mail drop E343-02, phone (919) 541-2708
16. ABSTRACT
The report provides a profile of the chemical composition of particulate matter (PM) with aerodynamic
diameter 2.5 |_im or less (PM2 5) emitted from a smelt tank at a pulp and paper facility using the Kraft pulping
process. The first step in the Kraft process is to form pulp by digesting wood chips in an aqueous solution of
sodium sulfide and sodium hydroxide at elevated temperature and pressure. This extracts the cellulose
from the wood by dissolving the lignin that binds the cellulose fibers together. The pulp is washed, and the
spent digestion liquor/wash water solution (black liquor) is separated from the cellulose (which forms the
paper) and is sent through a process to recover the digestion chemicals. The black liquor undergoes a
sequence of evaporation steps to yield a concentrated black liquor which is sent as fuel to a recovery boiler
used to generate heat for process steam in the plant. Combusting the black liquor results in a molten smelt,
which is composed primarily of inorganic chemicals, at the bottom of the recovery furnace. The smelt is
collected, dissolved in water, and transferred to a tank where quicklime is added to regenerate the digestion
reactants, sodium sulfide and sodium hydroxide. The data obtained during this research will assist States in
determining the major sources of PM25 so they can devise and institute a control strategy to attain the
ambient concentrations set by the National Ambient Air Quality Standard for PM2 5 that was promulgated in
July 1977 by the U.S. EPA. Along with the PM25 emission profile, data are also provided for gas-phase
emissions of several organic compounds. Data are provided in a format suitable to be included in the EPA
source profile database, SPECIATE.
17. KEY WORDS AND DOCUMENT ANALYSIS
a. DESCRIPTORS
b. IDENTIFIERS/OPEN ENDED TERMS
c. COSATI Field/Group
Air Pollution
Paper Industry
Wood Pulp
Fine Particulate Matter
Chemical Composition
Organic Compounds
Volatility
Pollution Control
Stationary Sources
13B
11L
14G
07D
07C
20M
18. DISTRIBUTION STATEMENT
Release to Public
19. SECURITY CLASS (This Report)
Unclassified
21. NO. OF PAGES
102
20. SECURITY CLASS (This Page)
Unclassified
22. PRICE
EPA Form 2220-1 (Rev. 4-77) PREVIOUS EDITION IS OBSOLETE forms/admin/techrpt.frm 7/8/99 pad
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