&ERA United States Environmental Protection 1200PennsylvaniaAvenue, N.W Agency V\&shington, DC20460 November 2009 Office of Solid V\&ste and Emergency Ftesponse Support Document for the Revised National Priorities List Final Rule - Peck Iron and Metal Guam Trust Territories American Samoa Northern Mariana Islands ------- Support Document for the Revised National Priorities List Final Rule Peck Iron and Metal November 2009 Site Assessment and Remedy Decisions Branch Office of Superfund Remediation and Technology Innovation Office of Solid Waste and Emergency Response U.S. Environmental Protection Agency Washington, DC 20460 ------- Peck Iron and Metal NPL Listing Support Document November 2009 Table of Contents Executive Summary iii Introduction iv Background of the NPL iv Development of the NPL v Hazard Ranking System v Other Mechanisms for Listing vi Organization of this Document vii Glossary vii 1.0 List of Commenters and Correspondence 1 2.0 Support for Listing 1 3.0 Adverse Comments 2 4.0 Conclusion 13 li ------- Peck Iron and Metal NPL Listing Support Document November 2009 Executive Summary Section 105(a)(8)(B) of CERCLA, as amended by SARA, requires that the EPA prepare a list of national priorities among the known releases or threatened releases of hazardous substances, pollutants, or contaminants throughout the United States. An original National Priorities List (NPL) was promulgated on September 8, 1983 (48 FR 40658). CERCLA requires that EPA update the list at least annually. This document provides responses to public comments received on the Peck Iron and Metal site, proposed on April 9, 2009 (74 FR 16162). This site is being added to the NPL based on an evaluation under EPA's Hazard Ranking System (HRS) in a final rule published in the Federal Register in November 2009. in ------- Peck Iron and Metal NPL Listing Support Document November 2009 Introduction This document explains the rationale for adding the Peck Iron and Metal site in City of Portsmouth, Virginia, to the National Priorities List (NPL) of uncontrolled hazardous waste sites and also provides the responses to public comments received on this site. The EPA proposed this site on April 9, 2009 (74 FR 16162). This site is being added to the NPL based on an evaluation under the Hazard Ranking System (HRS) in a final rule published in the Federal Register in November 2009. Background of the NPL In 1980, Congress enacted the Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA), 42 U.S.C. Sections 9601 etseq. in response to the dangers of uncontrolled hazardous waste sites. CERCLA was amended on October 17, 1986, by the Superfund Amendments and Reauthorization Act (SARA), Public Law No. 99-499, stat., 1613 el seq. To implement CERCLA, EPA promulgated the revised National Oil and Hazardous Substances Pollution Contingency Plan (NCP), 40 CFR Part 300, on July 16, 1982 (47 FR 31180), pursuant to CERCLA Section 105 and Executive Order 12316 (46 FR 42237, August 20, 1981). The NCP, further revised by EPA on September 16, 1985 (50 FR 37624) and November 20, 1985 (50 FR 47912), sets forth guidelines and procedures needed to respond under CERCLA to releases and threatened releases of hazardous substances, pollutants, or contaminants. On March 8, 1990 (55 FR 8666), EPA further revised the NCP in response to SARA. Section 105(a)(8)(A) of CERCLA, as amended by SARA, requires that the NCP include criteria for determining priorities among releases or threatened releases throughout the United States for the purpose of taking remedial action and, to the extent practicable, take into account the potential urgency of such action, for the purpose of taking removal action. Removal action involves cleanup or other actions that are taken in response to emergency conditions or on a short-term or temporary basis (CERCLA Section 101). Remedial action is generally long-term in nature and involves response actions that are consistent with a permanent remedy for a release (CERCLA Section 101). Criteria for placing sites on the NPL, which makes them eligible for remedial actions financed by the Trust Fund established under CERCLA, were included in the HRS. EPA promulgated the HRS as Appendix A of the NCP (47 FR 31219, July 16, 1982). On December 14, 1990 (56 FR 51532), EPA promulgated revisions to the HRS in response to SARA, and established the effective date for the HRS revisions as March 15, 1991. Section 105(a)(8)(B) of CERCLA, as amended, requires that the statutory criteria provided by the HRS be used to prepare a list of national priorities among the known releases or threatened releases of hazardous substances, pollutants, or contaminants throughout the United States. The list, which is Appendix B of the NCP, is the NPL. An original NPL of 406 sites was promulgated on September 8, 1983 (48 FR 40658). At that time, an HRS score of 28.5 was established as the cutoff for listing because it yielded an initial NPL of at least 400 sites, as suggested by CERCLA. The NPL has been expanded several times since then, most recently on September 23, 2009 (74 FR 48412). The Agency also has published a number of proposed rulemakings to add sites to the NPL. The most recent proposal was on September 23, 2009 (74 FR 48412). IV ------- Peck Iron and Metal NPL Listing Support Document November 2009 Development of the NPL The primary purpose of the NPL is stated in the legislative history of CERCLA (Report of the Committee on Environment and Public Works, Senate Report No. 96-848, 96th Cong., 2d Sess. 60 [1980]). The priority list serves primarily informational purposes, identifying for the States and the public those facilities and sites or other releases which appear to warrant remedial actions. Inclusion of a facility or site on the list does not in itself reflect a judgment of the activities of its owner or operator, it does not require those persons to undertake any action, nor does it assign liability to any person. Subsequent government actions will be necessary in order to do so, and these actions will be attended by all appropriate procedural safeguards. The NPL, therefore, is primarily an informational and management tool. The identification of a site for the NPL is intended primarily to guide EPA in determining which sites warrant further investigation to assess the nature and extent of the human health and environmental risks associated with the site and to determine what CERCLA-financed remedial action(s), if any, may be appropriate. The NPL also serves to notify the public of sites EPA believes warrant further investigation. Finally, listing a site may, to the extent potentially responsible parties are identifiable at the time of listing, serve as notice to such parties that the Agency may initiate CERCLA-financed remedial action. CERCLA Section 105(a)(8)(B) directs EPA to list priority sites among the known releases or threatened release of hazardous substances, pollutants, or contaminants, and Section 105(a)(8)(A) directs EPA to consider certain enumerated and other appropriate factors in doing so. Thus, as a matter of policy, EPA has the discretion not to use CERCLA to respond to certain types of releases. Where other authorities exist, placing sites on the NPL for possible remedial action under CERCLA may not be appropriate. Therefore, EPA has chosen not to place certain types of sites on the NPL even though CERCLA does not exclude such action. If, however, the Agency later determines that sites not listed as a matter of policy are not being properly responded to, the Agency may consider placing them on the NPL. Hazard Ranking System The HRS is the principle mechanism EPA uses to place uncontrolled waste sites on the NPL. It is a numerically based screening system that uses information from initial, limited investigations ~ the preliminary assessment and site inspection ~ to assess the relative potential of sites to pose a threat to human health or the environment. HRS scores, however, do not determine the sequence in which EPA funds remedial response actions, because the information collected to develop HRS scores is not sufficient in itself to determine either the extent of contamination or the appropriate response for a particular site. Moreover, the sites with the highest scores do not necessarily come to the Agency's attention first, so that addressing sites strictly on the basis of ranking would in some cases require stopping work at sites where it was already underway. Thus, EPA relies on further, more detailed studies in the remedial investigation/feasibility study that typically follows listing. The HRS uses a structured value analysis approach to scoring sites. This approach assigns numerical values to factors that relate to or indicate risk, based on conditions at the site. The factors are grouped into three categories. Each category has a maximum value. The categories are: • likelihood that a site has released or has the potential to release hazardous substances into the environment; v ------- Peck Iron and Metal NPL Listing Support Document November 2009 • characteristics of the waste (toxicity and waste quantity); and • people or sensitive environments (targets) affected by the release. Under the HRS, four pathways can be scored for one or more threats as identified below: • Ground Water Migration (Sgw) - drinking water • Surface Water Migration (Ssw) The following threats are evaluated for two separate migration components, overland/flood migration and ground water to surface water. - drinking water - human food chain - sensitive environments • Soil Exposure (Ss) - resident population - nearby population - sensitive environments • Air Migration (Sa) - population - sensitive environments After scores are calculated for one or more pathways according to prescribed guidelines, they are combined using the following root-mean-square equation to determine the overall site score (S), which ranges from 0 to 100: If all pathway scores are low, the HRS score is low. However, the HRS score can be relatively high even if only one pathway score is high. This is an important requirement for HRS scoring because some extremely dangerous sites pose threats through only one pathway. For example, buried leaking drums of hazardous substances can contaminate drinking water wells, but ~ if the drums are buried deep enough and the substances not very volatile ~ not surface water or air. Other Mechanisms for Listing There are two mechanisms other than the HRS by which sites can be placed on the NPL. The first of these mechanisms, authorized by the NCP at 40 CFR 300.425(c)(2), allows each State and Territory to designate one site as its highest priority regardless of score. The last mechanism, authorized by the NCP at 40 CFR 300.425(c)(3), allows listing a site if it meets the following three requirements: • Agency for Toxic Substances and Disease Registry (ATSDR) of the U.S. Public Health Service has issued a health advisory that recommends dissociation of individuals from the release; • EPA determines the site poses a significant threat to public health; and VI ------- Peck Iron and Metal NPL Listing Support Document November 2009 • EPA anticipates it will be more cost-effective to use its remedial authority than to use its emergency removal authority to respond to the site. Organization of this Document The following section contains EPA responses to site-specific public comments received on the proposal of the Peck Iron and Metal site on April 9, 2009 (74 FR 16162). The site discussion begins with a list of commenters, followed by a summary of comments, and Agency responses to each comment. A concluding statement indicates the effect of the comments on the HRS score for the site. Glossary The following acronyms and abbreviations are used throughout the text: Agency U.S. Environmental Protection Agency ARARS Applicable or Relevant and Appropriate Requirements ATSDR Agency for Toxic Substances and Disease Registry CERCLA Comprehensive Environmental Response, Compensation, and Liability Act of 1980, 42 U.S.C. Sections 9601 etseq., also known as Superfund CFR Code of Federal Regulations CLP EPA Contract Laboratory Program EOC Extent of Contamination EPA U.S. Environmental Protection Agency FR Federal Register FS Feasibility study HRS Hazard Ranking System, Appendix A of the NCP HRS score Overall site score calculated using the Hazard Ranking System; ranges from 0 to 100 MDL Method detection limit mg/kg microgram per kilogram MOA Memorandum of Agreement MS/MSD Matrix spike/matrix spike duplicates NCP National Oil and Hazardous Substances Pollution Contingency Plan, 40 C.F.R. Part 300 NPL National Priorities List, Appendix B of the NCP PCB polychlorinated biphenyls ppm parts per million PRP Potentially responsible party QAPP Quality Assurance Project Plan QA/QC Quality assurance/quality control Vll ------- Peck Iron and Metal NPL Listing Support Document November 2009 RI/FS Remedial investigation/feasibility study ROD Record of Decision SARA Superfund Amendments and Reauthorization Act TDL Target distance limit TSCA Toxic Substances Control Act HQ/kg microgram per kilogram UAO Unilateral Administrative Order VADEQ Virginia Department of Environmental Quality VDEQ Virginia Department of Environmental Quality VRP Voluntary Remediation Program Vlll ------- Peck Iron and Metal NPL Listing Support Document November 2009 1.0 List of Commenters and Correspondence EPA-HQ-SFUND-2009-0066-0003 Correspondence, dated January 9, 2009, from Rick F. Weeks, Jr., Virginia Department of Environmental Quality. EPA-HQ-SFUND-2009-0066-0005 Comment, posted May 12, 2009, from C. Taylor, Public Commenter. EPA-HQ-SFUND-2009-0066-0006 Comment, posted May 27, 2009, from Anonymous Public Commenter. EPA-HQ-SFUND-2009-0066-0007 Comment, dated June 8, 2009, from Brian L. Buniva, Counsel, LeClairRyan on behalf of The Peck Company. EPA-HQ-SFUND-2009-0066-0008 Comment, dated May 13, 2009, from S. Harris- Elliot, Public Commenter. EPA-HQ-SFUND-2009-0066-0009 Comment, dated June 8, 2009, from Brian L. Buniva, Counsel, LeClairRyan on behalf of The Peck Companies. 2.0 Support for Listing Comment: S. Harris-Elliott, C. Taylor and the anonymous commenter all supported listing. One stated that federal funding is necessary, another stated that EPA should do whatever is necessary to protect the public, and a third expressed interest in assisting EPA in making the community a safe place and working with EPA and the community to do so. Response: The Agency has added the Site to the NPL. Listing the Site makes it eligible for remedial action funding under CERCLA, and EPA will examine the Site to determine what response, if any, is appropriate. Actual funding may not necessarily be undertaken in the precise order of HRS scores, however, and upon more detailed investigation, may not be necessary at all in some cases. EPA will determine the need for using Superfund monies for remedial activities on a site-by-site basis, taking into account the NPL ranking, State priorities, further site investigation, other response alternatives, and other factors as appropriate. Finally, EPA's community involvement group will coordinate with the commenter that expressed interest in being involved. 1 ------- Peck Iron and Metal NPL Listing Support Document November 2009 3.0 Adverse Comments Brian L. Buniva, LeClairRyan, on behalf of The Peck Companies ("Peck"), raised a number of concerns related to the site, although none affected the final HRS site score of 48.52. EPA addresses the comments below. Comment 1: Peck asserted that EPA has not provided any comments on the Extent of Contamination Report conducted on behalf of Peck, and that the work necessary for the extent of contamination (EOC) study was performed and the study was performed in a manner consistent with the National Contingency Plan (NCP). Peck stated that the EOC has been under review by EPA for more than seven (7) months, and its consultants are waiting for written confirmation as to whether it meets the requirements of the Unilateral Administrative Order (UAO), or requires modification. Peck also stated that without any apparent consideration of the EOC study, EPA now proposes listing the Site on the NPL. Response: With respect to EPA's consideration of the draft The Extent of Contamination Report, EPA used much of the data generated for the draft EOC report in the calculation of the HRS score. In particular, the data was used to outline the extent of the contaminated soil throughout the property and to document an observed release of contaminants to surface water. Although EPA used the data from the draft EOC report in the HRS scoring, EPA has not provided comments on the EOC study. Whether or not EPA has provided those comments is irrelevant to the HRS site score. Comment 2: Peck commented that "[i]t appears that EPA is determined to ignore more cost- effective recommendations for addressing this Site that are presented in the [EOC] Study." Response: See discussion above in response to comment 1. This comment does not go to, or affect, the HRS score and is not therefore relevant to this rulemaking. As discussed above, EPA proposed the site to the NPL based upon its HRS score. In light of its specific purpose, the HRS does not take into account the merits of various cleanup options when calculating a site score. Those options are developed and evaluated during the subsequent remedy selection process. In accordance with Section 300.430 of the NCP, 40 C.F.R. § 300.430, EPA expects that a remedial investigation/feasibility study (RI/FS) will be conducted at the site. Among other factors such as the overall protection of human health and the environment, long term effectiveness, and the reduction of toxicity, mobility, or volume through treatment, EPA will consider cost in accordance with Section 300.430(e) (9)(iii)(G) and (f)(l)(ii)(D) of the NCP, 40 C.F.R. § 300.430(e) (9)(iii)(G) and (f)(l)(ii)(D). Comment 3: Peck urged EPA to accept the recommendations for remedial efforts at the Site presented in the EOC study, and that "EPA apply cleanup standards that are appropriate for evaluating ground water and soil remedial actions in a manner consistent with the true risks to human health and the environment." Response: See discussion above in response to comments 1 and 2. EPA will select appropriate cleanup standards in accordance with CERCLA, and the NCP after a RI/FS, including human 2 ------- Peck Iron and Metal NPL Listing Support Document November 2009 health and ecological risk assessments, has been completed by the Agency, when it issues its selected remedy in a Record of Decision. Comment 4: Peck stated that it was about to implement the Virginia Voluntary Remediation Program (VRP) sanctioned soil consolidation and capping remedy before EPA Region III took certain steps that caused the withdrawal of the Site from the VRP shortly thereafter. Prior to issuance of the UAO, the VRP determined that consolidating and capping the soils at the Site was the appropriate remedy and VDEQ had decided to recommend approval of a $1,000,000 loan/grant to Peck for implementation of this remedy. Peck stated that "removal of the Site from the VRP pursuant to concerns expressed by EPA appears contrary to the spirit if not the letter of the January 11, 2002 Memorandum of Agreement between EPA Region III and the Commonwealth of Virginia[.]" Response: With regard to whether the Site could remain in the VRP, the assertions made by Peck's counsel do not comport with the facts. Upon becoming aware of the poly chlorinated biphenyl (PCB) contamination at the Site, EPA and VADEQ conferred and it was determined that the Virginia state law does not provide VDEQ with the authority to handle PCB cleanups as part of the VRP or otherwise. As such, EPA's Region III Toxic Substances Control Act (TSCA) branch worked with both VADEQ and Peck to provide an adequate TSCA sampling plan in order to work in conjunction with the VRP cleanup. On June 28, 2005, Mr. David Peck, acting on behalf of the Peck Company, withdrew the self-implementing PCB cleanup plan [Attachment 1], thereby withdrawing the Site from the VRP. Finally, Section IV (E) of the Memorandum of Agreement (MOA) between EPA and VADEQ states: This MOA is solely between EPA and VADEQ for the exclusive benefit of the working relationship between EPA and VADEQ, and is not intended to be enforceable by any party in any administrative or judicial forum. Nothing herein is intended to create any rights, obligations, responsibilities, expectations, or benefits from any third parties, (emphasis added). In short, the MOA was entered by EPA and the Virginia state Department of Environmental Quality (the VADEQ or VDEQ) to foster a "working relationship." As part of that relationship, VADEQ advised EPA that it could not handle a PCB cleanup under its state authority. EPA then made good faith efforts to provide TSCA support to Peck on a self-implementing PCB cleanup. Peck voluntarily and unilaterally withdrew that TSCA PCB Cleanup plan. VADEQ's January 9, 2009, letter to EPA supporting the proposal of the Site to the NPL only underscores the fact that VADEQ actually supports the exclusion of the Site from the VRP. Comment 5: Peck argued that the placement of the Site on the NPL will more than likely prevent the implementation of any cost-effective remedial action at the Site for several years if not another decade. Response: EPA does not agree that proceeding with the listing process will necessarily delay implementation of a remedial action. Even upon NPL listing, EPA may take any necessary response actions, including removal actions, necessary to protect human health and the 3 ------- Peck Iron and Metal NPL Listing Support Document November 2009 environment. The fact that a site is listed on the NPL does not preclude EPA from taking such actions pending the implementation of a cleanup remedy. If a potentially responsible party (PRP) wishes to expedite cleanup efforts, the PRP may undertake the RI/FS and/or remedial design/remedial action stages under EPA supervision and pursuant to appropriate agreements with governmental authorities (under enforcement authorities of CERCLA or those of other statutes). The listing process does not encumber or preclude PRPs from entering into these agreements. The EPA has entered into many such agreements before and after a site's promulgation to the NPL, and such an alternative is available to the commenter. Comment 6: Peck commented, "It seems fair to ask what more of substance has been learned about the Site as a result of the at least $1,000,000 in additional investigatory costs necessitated by the UAO,"and "[w]ill the remedy selection that is most appropriate for this site be materially different than that authorized by VDEQ ....?" Response: See discussion above in responses to comments 1, 2 and 3. These comments are not relevant to the HRS scoring of the Site or the decision to place the Site on the NPL. However, the EOC study, though incomplete, has to date provided a more thorough understanding of site conditions, including by clarifying the magnitude and extent of the contamination. Comment 7: Peck provided a summary of the Draft Report Findings and Recommendations, and included discussions of earlier studies, and soil, sediment and ground water results. In referring to the findings of the EOC study, Peck asserted that many of the contaminant concentrations were below regulatory limits and/or Applicable or Relevant and Appropriate Requirements (ARARs). For example: • Of the 36 sediment samples, only 3 PCB samples exceeded the 59.8 |ig/kg screening level for sediments in Paradise Creek. • No PCBs detected in ground water exceeded the Maximum Contaminant Level (MCL) of 0.50 |ig/L • The dissolved metals detected above screening levels in one or more samples were arsenic and nickel. Peck disputed that a "25 ppm PCB soil cleanup standard is either legally required or factually justified at this Site," and that they were 'Applicable or Relevant and Appropriate Requirements ("ARARS"), which are required to be considered, but not mandated under CERCLA.' Peck also disputed the applicable criteria for PCBs in surface water for the site. Peck further argued that even if the TSCA clean-up standard regulations are mandatory, "in low occupancy areas PCB contaminated soils may remain at the Site at concentrations > 25 ppm up to 100 ppm if the site is covered with a cap meeting specified requirements." Peck also argued that EPA is authorized "to consider any other remediation method and clean up standard for PCB soils so long as the method will not pose an unreasonable risk of injury to health or the environment." 4 ------- Peck Iron and Metal NPL Listing Support Document November 2009 Peck summarized the results of the EOC, saying it believed that there had been minimal exceedances of drinking water standards, all adjacent properties are on public water supply, and there appear to be no potential human receptors impacted by site ground water. Peck wrote that "[a]ll PCB samples are below drinking water standards, which reduce the concern for bioaccumulation of PCBs in aquatic life." Further, the study concluded that impacts to aquatic life in the Elizabeth River or in Paradise Creek were not anticipated due to low concentrations of metals in ground water. The conclusion of the EOC "urge[d] that an appropriate remedy to prevent leaching of metals and PCBs to groundwater and preventing off-site migration is the placement of a soil cap over contaminated soils at the site." Peck also stated that "sampling results (including the most recent results) reported in the [EOC] Study reveal no significant surface or groundwater impacts leaching from these soils." Response: See responses to above comments 2 and 3. Peck's comments on the draft EOC report findings have no effect on the HRS evaluation or the score assigned to the site. While the HRS evaluation of this site did reflect contaminant concentrations (e.g., PCBs) in defining the site source and identifying an observed release to surface water, neither of these evaluations were dependent on the contaminant concentration being above a regulatory limit or an ARAR. In general, the HRS is not restricted to evaluating contaminant levels above regulatory limits. On July 16, 1982, when responding to public comments on the proposed (original) HRS (47 FR 31188), and again on September 8, 1983 (48 FR 40665), the Agency rejected the idea that releases within regulatory limits should not be considered under the HRS. As the Agency noted in 1982: emission or effluent limits do not necessarily represent levels which cause no harm to public health or the environment. These limitations are frequently established on the basis of economic impacts or achievability. The HRS does, however, consider whether releases are above regulatory limits specifically identified in the HRS in evaluating target populations, increasing by a factor of 10 the weight assigned populations exposed to contaminants above the limits. However, at this site, the HRS score was not based on target populations being exposed to contaminants above regulatory limits. The observed release factor and the association of contaminants with sources do not represent the risk to human health and the environment posed by a site. Instead, the relative risk posed by a site is approximated by the total HRS score, which incorporates the observed release factors with other factors such as waste characteristics (including waste quantity, toxicity, and persistence) and targets. This total HRS score reflects the risk of the site relative only to the other sites that have been scored. The actual degree of contamination and its effects are more fully determined during the RI that typically follows listing. Specifically, the HRS evaluation of the Peck Iron and Metal Site has appropriately documented a source at this site and associated hazardous substances with it without consideration of regulatory limits, consistent with the HRS. 5 ------- Peck Iron and Metal NPL Listing Support Document November 2009 The HRS defines a "source" in section 1.1 as: [a]ny area where a hazardous substance has been deposited, stored, disposed, or placed, plus those soils that have become contaminated from migration of a hazardous substance. Sources do not include those volumes of air, ground water, surface water, or surface water sediments that have become contaminated by migration, except: in the case of either a ground water plume with no identified source or contaminated surface water sediments with no identified source, the plume or contaminated sediments may be considered a source. HRS Section 2.2.2, Identify hazardous substances associated with a source, further states to: consider those hazardous substances documented in a source (for example, by sampling, labels, manifests, oral or written statements) to be associated with that source when evaluating each pathway. Therefore, the HRS does not require a source to contain a substance(s) above regulatory criteria to consider the source or the substances associated with it in the HRS evaluation of a site. At the Peck Iron and Metal site, one source, Source 1, Contaminated Soil, was evaluated as part of the HRS scoring of the site. The HRS documentation record at proposal states on page 14: Source 1 is characterized using soil samples collected from the Peck Iron property during the extent of contamination study conducted in 2007. The soil samples were collected from a 50-foot by 50-foot grid, as shown in Figure 2-1 of Reference 40. The soil samples were analyzed for metals (arsenic, cadmium, chromium, lead, mercury, nickel, and silver) and PCBs. The soil samples were analyzed for metals (arsenic, cadmium, chromium, lead, mercury, nickel, and silver) and PCBs. Metals were analyzed using EPA SW-846 Methods 6010/7471, and PCBs were analyzed using EPA SW-846 Method 8082. The laboratory analyses were conducted at a Level IV Contract Laboratory Program (CLP)- equivalent data quality that included quality assurance/quality control (QA/QC) samples such as laboratory control standards, matrix spike/matrix spike duplicates (MS/MSD), and surrogates (at a minimum). The QAPP for the sample collection, documentation, and analysis is provided in Reference 8. Because Source 1 is made up of contaminated soil, background soil samples were used to show that the soils came to be contaminated by migration. This was illustrated by documenting that the levels of PCBs and lead in Source 1 at the site are significantly above background levels. The HRS documentation record at proposal states on page 15: 6 ------- Peck Iron and Metal NPL Listing Support Document November 2009 The background soil samples were collected from locations in the northern portion of the Peck Iron property. Figures illustrating sampling locations and their corresponding PCB and lead analytical results indicate these northern site locations were not as impacted by facility operations (Ref. 38; Ref. 40, Figures 4- 1, 4-2, 4-3, and 4-4). [See Page 15 of the HRS documentation record at proposal.] The HRS documentation record at proposal further states that the sampling locations contaminated with PCBs and lead are within the area where the majority of facility operations were conducted (page 15 of the HRS documentation record at proposal). The HRS documentation record at proposal shows in Table 1 that PCBs were not detected at or above the method detection limit (MDL) in the background samples but shows in Tables 2 and 3 that PCBs were detected in Source 1 soil samples above the respective background MDL as well as above the contaminated soil samples MDL. PCB contamination in soil samples used to associate PCBs with Source 1 ranged from 41 to 1,100,000 |ig/kg (see pages 18 - 44 of the HRS documentation record at proposal). In Table 4, the HRS documentation record at proposal shows lead concentration ranged from 6.6 mg/kg to 140 mg/kg in the soil background samples. The contaminated soil samples documenting lead in Source 1 ranged from 420 mg/kg to 27,000 mg/kg (see page 46 - 49 of the HRS documentation record at proposal). These data show that PCBs and lead in Source 1 are above background levels. EPA finds the concentrations of PCBs and lead, in combination with the other elements of the HRS score, were sufficiently high to warrant listing. EPA also used contaminated sediments in the wetlands to establish an observed release by direct observation to the surface water pathway. According to HRS Section 2.3, Likelihood of release, an observed release by direct observation is established by direct observation of the release of a hazardous substance into the media being evaluated. Regarding the surface water migration pathway, HRS Section 4.1.2.1.1, Observed release, provides further details in establishing an observed release by direct observation. It states the following: • Direct observation: A material that contains one or more hazardous substance has been seen entering surface water through migration or is known to have entered surface water through direct deposition, or A source area has been flooded at a time that hazardous substances were present, and one or more hazardous substances were in contact with the flood waters, or - When evidence supports the inference of a release of a material that contains one or more hazardous substances by the site to surface water, demonstrated adverse effects associated with that release may also be used to establish an observed release. The presence of PCBs and lead in the contaminated soils present in the wetland constitutes an observed release by direct observation from the site into a wetland, which is a surface water pursuant to HRS Section 4.0.2. HRS Section 4.0.2 provides that eligible surface waters, 7 ------- Peck Iron and Metal NPL Listing Support Document November 2009 specifically rivers, include "perennially flowing waters from point of origin to the ocean or to coastal tidal waters, whichever comes first, and wetlands contiguous to these flowing waters." Since the southern portion of the Peck Iron and Metal Site is a wetland which is contiguous to Paradise Creek, a perennially flowing water, this wetland is part of an HRS-eligible surface water body. Therefore, the source at the site and the observed release by direct observation were both established consistent with the HRS. Regarding the pathway data cited by Peck, the surface water pathway was sufficient to achieve an HRS score for the site above 28.50, the score necessary for placing the site on the NPL. Therefore, the comments regarding ground water contamination are not relevant to the site score. Because only the surface water pathway was used to score the site, ground water targets were not assessed, hence the comments regarding ground water have no effect on the HRS score for the site. That residents are on public water does not affect the surface water pathway portion of the site score. As stated in section 4.1.2.3 of the HRS documentation record at proposal, no drinking water intakes have been identified in the 15-mile target distance limit (TDL), and so no score was assigned based upon the population using drinking water in the area. Regarding Peck's statement that "[a]ll PCB samples are below drinking water standards, which reduce the concern for bioaccumulation of PCBs in aquatic life," simply because PCB levels are below a human drinking water standard does not mean they pose no concern. Bioaccumulation is the process in which contaminants in aquatic life can, over time, increase in concentration many magnitudes above that found in the ambient environment. These increased levels can then pose a threat not only to the aquatic life but also to human targets consuming the aquatic life. Further, the actual degree of contamination and its effects are more fully determined during the RI that typically follows listing. See response to comment 8 below regarding cleanup criteria. Comment 8: Peck stated that "we do not believe that a 25 ppm [(parts per million)] soil cleanup standard is either legally required or factually justified at the Site[,]" and that "the insistence of such standard by EPA not only turns what was once a $1,000,000 to $2,000,000 project under the VRP, into a project that could well exceed $20,000,000 after listing it as a NPL site . . . with no tangible benefit to human health and the environment^ ]" In support of this, Peck argued that the TSCA regulations under 40 C.F.R. Part 761 are not required by the UAO because they are Applicable or Relevant and Appropriate Requirements ("ARARs"), which are required to be considered, but not mandated under CERCLA Section 9621. Peck also argued that the self- implementing TSCA cleanup provisions are not binding upon cleanups conducted under other authorities, including but not limited to actions conducted under Section 104 or 106 of CERCLA pursuant to 40 C.F.R. Sec. 761.61 (a)( 1 )(ii). Peck argued that the Site qualifies as a low occupancy area as defined at 40 C.F.R. § 761.3. Response: See discussion above in responses to comments 1, 2 and 3. Consideration of the appropriate cleanup standards will occur during the RI/FS after listing. The requirements of the 8 ------- Peck Iron and Metal NPL Listing Support Document November 2009 UAO are not relevant to the HRS score. The final UAO did not address cleanup standards or the status of any specific ARARs, but rather, required study of conditions at the Site. Further, the decision to list the site on the NPL is based upon the HRS score, and therefore, the contents of the UAO are not relevant to this action. Also, whether 40 CFR § 761.61 is used at a later stage in the remedy selection process as an ARAR when determining cleanup levels at this site is not relevant to the HRS score or the decision to include this site on the NPL. Comment 9: Pursuant to Section 121 of CERCLA, the remedy selection chosen by EPA must be cost-effective and must address both the short and long term costs of such removal or remedial actions. Response: Section 121 of CERCLA applies to remedial actions, not removals. As such, these considerations will be relevant to remedy selection in the Record of Decision. Comment 10: Peck also cited the Neal's Landfill Record of Decision (ROD) amendment to support the proposition that EPA has considerable discretion in fashioning a remedy for a PCB site under CERCLA. Response: As the commenter itself recognizes, each site is unique, and what was determined to be appropriate at Neal's Landfill may or may not be appropriate at this site. Further study is necessary before any decisions are made as to remedy selection, which occurs at a later stage of the Superfund process. Comment 11: Peck cited to Appendix H of the Draft EOC Report, which it stated provides cost estimates for various remedies. Peck concluded that "[t]he cost differential for the remedies, which our consultants believe will be equally protective of human health and the environment in this historically heavy industrial area, is simply astounding." Response: See discussion above in responses to comments 1, 2 and 3. Consideration of the appropriate cleanup standards will occur during the RI/FS. As stated in the response to comment number 2, EPA will consider cost in accordance with 300.430(e) (9)(iii)(G) and (f)(l)(ii)(D). Comment 12: Peck stated that it "has reason to believe that EPA's decision to propose that this Site be listed on the NPL is due, in part, from the misapplication of an erroneous PCB standard to groundwater data obtained at the Site in the summer of 2008." Peck also stated that "the groundwater results at this Site demonstrate that the PCB concentration in groundwater at the Site is far below the appropriate and applicable legal standard established by EPA of 0.50 ug/L " Response: See discussion above in responses to comments 1, 2 and 3. The ground water pathway was not scored in the HRS evaluation, and therefore these comments have no effect on the site score, nor on the decision to list the Site on the NPL. In any case, a comparison of the appropriate water quality criteria with ground water data is typically the first step utilized in ecological risk assessment to evaluate ground water data when the ground water may discharge to surface water. It is a screening step to determine if 1) the 9 ------- Peck Iron and Metal NPL Listing Support Document November 2009 potential for ecological risk exists if ground water discharges to surface water, and, 2) if further investigation is warranted. An ecological risk assessment will be performed during the RI/FS. Comment 13: According to the EOC, total PCB concentrations (addition of all PCB homologues detected in each well) were detected in three wells but at concentrations less than the 0.50 |ig/L MCL. Response: The site was scored based on surface water, such that PCB concentrations in ground water are not relevant. See discussion above in responses to comments 1, 2 and 3. Consideration of the appropriate cleanup standards will occur during the RI/FS. Comment 14: Peck asserted that utilization of the 0.000064 |ig/L surface water criterion for human consumption of fish is inappropriate. Peck stated that a fish consumption advisory is in place due to the "presence of PCBs in the James and its tributaries," and that the "imposition of the virtually unmeasurable standard applied to this Site will have no impact lifting a health advisory that has been in effect for decades." Response: This 0.000064 |ig/L surface water value was not used in the HRS scoring. The site was scored based upon the identification of contaminated soils in wetlands on the site property and adjacent to Paradise Creek. Although EPA did identify potential human food chain population in the area (crab pots were noted in the area adjacent to the contaminated wetlands), EPA could not document the amount of fish and crabs harvested from this area and therefore assigned a value of "'0" to the human food chain population value. Therefore, no surface water criterion for human consumption of fish was considered in the HRS score. Even without consideration of this criterion, the site still scores high enough to warrant its placement on the NPL. The RI/FS will address the risks to both humans and the environment by performing human health and ecological risk assessments, and appropriate criteria will be used for these assessments. The presence of the fish advisory does not change the Site score. In the HRS documentation record at proposal, EPA noted the presence of the fish advisory in section 4.1.3.3. EPA has evidence that, despite fish consumption advisories, individuals utilize the Elizabeth River and Paradise Creek for subsistence fishing activities. Comment 15: Peck stated that despite the 2001 Memorandum of Agreement between EPA and VDEQ moving toward implementation of an approved remedy, this Site has been singled out by EPA for listing. Response: As explained above in response to comment 4, this site is not eligible for the VRP program and the Commonwealth of Virginia supported the listing of the site on the NPL. EPA has decided to use the broad comprehensive authority of CERCLA to comprehensively address the threat posed by all releases from this site to human health and the environment. Comment 16: Peck commented that it is uncertain if sediment sample exceeding the screening levels for metals (arsenic, cadmium, chromium, nickel, lead, mercury and silver) are due to 10 ------- Peck Iron and Metal NPL Listing Support Document November 2009 runoff from the site, are from heavy industrial sources adjacent to these tidal waters, or are typical background soil concentrations for the area. Response: The HRS score for the site was based on the establishment of an observed release by direct observation of PCBs and lead into the wetlands at the site. This direct observation establishes that the PCBs and the lead came to be located in the wetland due to the hazardous substances coming from the Peck site. According to HRS Section 2.3, Likelihood of release, an observed release by direct observation is established by direct observation of the release of a hazardous substance into the media being evaluated. With regard to the surface water migration pathway, HRS Section 4.1.2.1.1, Observed release, provides further details in establishing an observed release by direct observation. It states the following: • Direct observation: A material that contains one or more hazardous substances has been seen entering surface water through migration or is known to have entered surface water through direct deposition, or A source area has been flooded at a time that hazardous substances were present, and one or more hazardous substances were in contact with the flood waters, or - When evidence supports the inference of a release of a material that contains one or more hazardous substances by the site to surface water, demonstrated adverse effects associated with that release may also be used to establish an observed release. At the Peck Iron and Metal site, the first criterion listed for the demonstration of an observed release by direct observation in HRS Section 4.1.2.1.1 to surface water was met. Under the direction of the HRS, no separate attribution is required when an observed release by direct observation is documented. While no formal attribution is required, the HRS documentation record at proposal, on pages 56 through 61, explains that at least some of the contamination in the wetlands is coming from the Peck Iron and Metal site. The HRS documentation record at proposal states that the substances in the wetlands are associated with the Peck operations and that the source is not contained to prevent contaminant migration: The contaminated soil within Source 1 is attributed to the former operations at Peck Iron. In response to a request for information issued by EPA pursuant to Section 104(e) of CERCLA, Peck Company, Inc., acknowledged that from 1945 to approximately 1990 the business conducted at the facility was the purchase, processing, storage, and shipping of metal scrap from various military bases; other federal, state, and local government agencies; and local businesses. Scrap metal handled at the facility included damaged and obsolete equipment, attachments, parts, and other miscellaneous materials, including scrapped naval vessels. Peck Company, Inc., disclosed that some of these scrap materials 11 ------- Peck Iron and Metal NPL Listing Support Document November 2009 contained cadmium (automobile parts); PCBs (insulated wire, gaskets, fluorescent lights and transformer oils); and lead (scrapped bridge sections and automobile batteries) (Ref. 4, p. 3; Ref. 32, p. 5). Therefore, the PCB and lead contamination identified in Source 1 is attributed to operations at Peck Iron and not from adjacent properties or other sources [see Page 56 of the HRS documentation record at proposal]. The contamination in Source 1 is expected to migrate to wetlands on the southwestern border of the Peck Iron property adjacent to Paradise Creek because of the slight topographic gradient across the Peck Iron property and Source 1 towards the wetlands (Ref. 53; Ref. 67). Additionally, the areas of Source 1 are not contained and are subject to flooding. Source 1 is located in the flood plain of Paradise Creek and is subject to extensive flooding and erosion during weather events such as tropical storms and hurricanes. Source 1 is within a 100-year flood plain (Ref. 6, pp. 3, 4 and Appendix B; Ref. 45; Ref. 68) [see page 56 of the HRS documentation record at proposal]. In addition, while Peck questioned whether the contamination [in the wetland sediments] is attributable solely to its operations, Peck does not refute the documentation of PCBs and lead in site soils above background levels, nor EPA's finding that these PCBs and lead contaminated soils extend into an intertidal emergent wetland which is part of Source 1 and located along the Paradise Creek shoreline. As such, the hazardous substances (PCBs and lead) associated with sampling locations within Source 1 and sampling locations within the intertidal emergent wetland, a surface water body, at the site, document an observed release by direct observation. Page 52 of the HRS documentation record at proposal states: The soil contamination in Source 1 extends into an intertidal emergent wetland, as shown in References 38, 41, and 67. The wetland is contiguous to Paradise Creek. Therefore, an observed release to the wetland and to Paradise Creek can be documented by direct observation. Soil sampling locations within the wetland include grid cells AA2 through AA5; BB4; BB5; DD5; DD6; EE3; EE4; EE5; GG-8; GG9; GG10; GG12; HH10; HH11; HH12; andHH13 (Ref. 38; Ref. 41; Ref. 67). Concentrations of PCBs and lead detected in soil samples collected from the wetland portion of Source 1 are summarized in Table 8. The HRS documentation record at proposal continues by listing in Table 8 all the sampling locations documenting PCBs and lead in the portions of Source 1 that are within the intertidal emergent wetland, a surface water body1 at the site. PCBs contamination in the wetland ranged from 66 |ig/kg to 16,000 |ig/kg, and lead contamination ranged from 430 |ig/kg to 6,500 |ig/kg. The sampling locations are depicted Reference 38 and 41 and the wetland location is depicted in References 38 and 67 of the HRS documentation record at proposal. 1 HRS Section 4.0.2, Surface water categories, includes wetlands contiguous to perennial flowing waters as an eligible surface water. See HRS section 4.0.2 for more discussion on HRS eligible surface water categories. 12 ------- Peck Iron and Metal NPL Listing Support Document November 2009 4.0 Conclusion The original HRS score for this site was 48.52. Based on the above responses to public comments, the score remains unchanged. The final scores for the Peck Iron and Metal site are: Ground Water: Surface Water: Soil Exposure: Air Pathway: HRS Score: Not Scored 97.05 Not Scored Not Scored 48.52 13 ------- |