Chesapeake Bay Program

Voluntary

Volume 1, Issue 1

Zones Phaseout

August 2001

What did we commit to?

The Governors of MD, VA, and PA, the EPA Administrator,
the Administrator of the Chesapeake Bay Commission and
the Mayor of District of Columbia endorse voluntary
phaseout of mixing zones for persistent or bioaccumulative
toxics in Chesapeake Bay Watershed. By signing both the
Chesapeake Bay Agreement and the Toxics 2000 Strategy,
the signatories are asking that point sources in the
Chesapeake Bay Watershed commit to the following
commitments:

Zero Release Objective: To achieve the following
Chesapeake 2000 Bay Agreement commitment "Through
continual improvement of pollution prevention measures and
other voluntary means, strive for zero release of chemical
contaminants from point sources, including air sources.
Particular emphasis shall be placed on achieving, by 2010,
elimination of mixing zones for persistent or bioaccumulative
toxics.

What are mixing zones?

A mixing zone is an area where pollutants from a point
source's discharge pipe are mixed with receiving waters to
dilute the pollutant's concentration. Inside a mixing zone,
discharges of the pollutant are allowed to exceed the water
quality limits set by a state. It is assumed that the brief
exceedance of the water quality standard will not
significantly impact aquatic organisms. At the boundary of
the mixing zone, the concentration of the chemical must
meet the water quality standard set for that particular body of
water. The size of mixing zones is site specific and may
vary.

How a mixing zone is determined?

Mixing zones are a legal regulatory option a point source can
choose to comply with water quality standards. Mixing
zones are site specific, scientifically based, developed
according to applicable rules, regulations and policies and
undergo rigorous regulatory review prior to issuance of a
National Pollution Discharge Elimination System (NPDES)
permit by the states and EPA. In order to issue a NPDES
permit with a mixing zone, the permitting authority has
determined that 1) the mixing zone would not cause
impairment of the receiving water, 2) There is no lethality to
organisms passing through the mixing zone and 3) there are
no significant health risks, considering likely pathways of
exposure. A NPDES permit is issued in accordance with the
administrative process act (APA) of the NPDES authority.

How will we do it?

To accomplish this objective, the signatories commit to:
Mixing Zone Phase Out

Strive to meet water quality standards for persistent or
bioaccumulative chemical contaminants at the point of
discharge through continual improvement of pollution
prevention measures and other voluntary means.

•	By 2001, establish a baseline for the facilities not
meeting water quality standards at the point of
discharge for persistent or bioaccumulative chemical
contaminants and by 2003 and 2007 report on their
progress in reducing concentrations at the point of
discharge in order to eliminate mixing zones.

•	An initial emphasis shall be placed on phasing out
mixing zones for persistent or bioaccumulative
chemical contaminants in the following areas:

Regions of Concern,

Areas of Emphasis,

-	303(d) listed waters for persistent or
bioaccumulative chemical contaminants,

-	Areas under finfish or shellfish advisories caused
by persistent or bioaccumulative chemical -

contaminants.

i

Emphasis is placed on voluntary pollution prevention
Measures to achieve this goal.

Continued on page 2

Point source
facility

What is a mixing zone?

Concentration of
contaminant briefly exceeds
water quality standard within
the mixing zone

At the Edge of mixing zone
the concentration of the
contaminant meets the
water quality standard


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Why would a point source have a mixing
zone?

Regulatory agencies have long recognized that the
potential toxicity of an effluent will tend to decrease as it
mixes with the receiving water body, simply due to
dilution. Certain regulatory procedures have evolved to
account for this tendency. These procedures result in
less stringent permit effluent limitations compared to the
limits that would be applied if dilution was ignored. In
theory these procedures can be used to develop less
stringent limits without compromising enviromnental
protection.

Concerns have arisen that this practice of recognizing a
"mixing zone" may not be sufficiently protective in all
cases, e.g. where sediment contamination may be an
issue. While there are often significant costs that a
discharger must bear when mixing zones are eliminated,
it may be difficult to directly identify a specific
enviromnental improvement that would be associated
with the elimination of a particular mixing zone.
Nonetheless, the Chesapeake Bay Program has
determined that the concerns about the reduced level of
protection associated with applying mixing zones are
sufficiently high that dischargers should be encouraged
to eliminate them whenever feasible, on a voluntary
basis.

Why phaseout mixing zones?

A voluntary mixing zone phase out is one step toward
achieving the "zero release" goal that industries have
agreed to in the Chesapeake 2000 Agreement.
impaired. By 2010, we are asking point sources to
voluntarily eliminate all mixing zones for these
contaminants throughout the watershed. In addition
there are other benefits and reasons:

Reduced acute and chronic water quality impacts
Eliminating mixing zones will result in the reduced
potential for acute and chronic impacts to aquatic
resources from persistent or bioaccumulative toxics
briefly exceeding water quality standards in the actual
mixing zone. An elimination of mixing zones will also
result in a reduction of mass loading to the ecosystem,
especially to the sediment habitat, and a reduced
potential long term bioaccumulative impacts from that
facility. Bioaccumulative impacts from mercury and
PCBs can be seen in the fish advisories which exist in
many parts of the Bay for these substances, and in EPA's
issuance of a nationwide advisory for freshwater fish
containing mercury.

Cont'd on column 2

Continued from column 1

Reduced loadings to sediment
The 1999 Chesapeake Bay Basinwide Toxics Loading
Inventory indicates that anywhere from 60-90% of metals
such as copper and mercury are trapped in the tidal river
sediments and not flushed out of the tidal rivers. The 1999
Toxics Characterization report indicates that in some
Chesapeake Bay tidal rivers the concentrations of metals,
pesticides, PAHs, and PCBs are elevated to levels that
indicate probable adverse effects to aquatic resources. At
these levels, these chemical contaminants may be
bioavailable and impacting living resources. A voluntary
phaseout of mixing zones is one step to reduce net loadings
to the Chesapeake Bay sediments of metals and other
persistent chemical contaminants.

Limitations of the Mixing Zone designation
There are also examples of shortcomings in the design of a
mixing zone. One, mixing zones that have been established
in State's permitting policies have still resulted in unintended
benthic degradation in the mixing zone. Second, the design
may not consider the cumulative load and effect from
multiple sources of different contaminants within a mixing
zone. Third, mixing zones may be subjected to extreme tide
or enviromnental conditions, when these events occur
violations of the water quality standard outside of the mixing
zone edge may occur at no fault to the facility, but rather due
to a limitation in the hydrological design of the mixing zone.
For these and other reasons, the Bay Program urges a
voluntary phaseout of mixing zones for persistent or
bioaccumulative toxics.

Benefits to the Facility

Recognition for committing to voluntary phaseout:

-	Press for committing to voluntary phaseout

-	Potential pollution prevention awards and public
exposure for enviromnental stewardship

-	Potential regulatory incentives

What chemicals will we focus on?

EPA's Great Lakes regulatory Mixing Zone phase out
focuses on bioaccumulative chemicals of concern (BCC).
The Chesapeake Bay Program will focus on some of the
chemicals on the BCC list, but not others because these
contaminants are not being released by point sources in the
Chesapeake Bay Watershed, although some of these "legacy
contaminants" appear to be impacting living resources from
other sources. Due to the State impaired water list and the
Toxics Characterization report this phaseout will also focus
on metals. Data indicate these persistent toxics are
potentially impacting aquatic living resources in the
Chesapeake Bay tidal waters.

Cont'd on page 3, column 1


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Cont'd from page 2, column 2
The final consensus based list for the voluntary phaseout of
persistent or bioaccumulative toxics is under development.
Additionally, an effort is underway to prioritise the
chemicals to focus the phaseout. A preliminary very draft
list of focus chemicals is: mercury and its compounds, lead
and its compounds, chromium, copper, arsenic, cadmium,
nickel, zinc, PAHs, PCBs, hexachlorobenzene, dioxins and
furans, and octachlorostyrene.

Where we will focus efforts?

The Chesapeake Bay Agreement goal commits the Bay
Program to voluntarily phase out mixing zones for persistent
or bioaccumulative toxics throughout the Chesapeake Bay
Watershed. In the Toxics 2000 Strategy, it is further clarified
by the Chesapeake Executive Council to initially focus on
point sources with mixing zones for persistent or
bioaccumulative toxics located in the watersheds of the
Regions of Concern, the Areas of Emphasis, watersheds
with a fish consumption advisory or watersheds listed as
being impaired (on the 303 (d) list for each state).

What is our early implementation strategy?

A voluntary strategy to guide progress...

The Bay Program, (EPA, state agencies, pollution prevention
programs, enviromnental groups, publicly owned treatment
works operators, and industry representatives), is working to
identify areas to focus collective efforts of the Bay Program
to achieve this commitment over the next ten years. The
strategy contains the following focus areas:

-	Establishing a baseline of facilities

-	Education and outreach

-	Identify technological needs

-	Recognition and incentives

-	One on one targeting

What is EPA's Policy Stance on the National
Mixing Zone Regulation?

Currently, the Administration is not proposing a regulatory
phaseout of mixing zones. They are currently evaluating
standards and criteria and it appears that mixing zones will
not be an issue or area for regulatory change.

Other EPA initiatives related to the voluntary phaseout:
EPA's PBT (persistent bioaccumulative toxics) intiative
outlines a strategy to help reduce these contaminants from
the enviromnent as well as monitoring initiatives. Our effort
should seek to coordinate with these initiatives.

Cont'd on column 2

How do TMDLs affect this voluntary initiative?

Total Maximum Daily Loads may require point source
facilities to comply with stricter than water quality standards.
The voluntary mixing zone phaseout may be one step for
industries to get ahead of a proposed TMDL. However, this
will be evaluated on a case by case basis.

How will the State/Bay Program permitting
offices handle new and renewal applications for
mixing zones?

It will be the jurisdictions policy to actively explore and
encourage non-mixing zone options to new and renewal
permit applications to mixing zones.

For More Information Contact:

Bob Steidel

Chair of the Point Source Workgroup

Hopewell Regional Wastewater Treatment Facility

804-541-2210

bsteidel(®,hrwtf.org

Bob Dunn

Chair of the Pollution Prevention Workgroup

DuPont

804-383-3895

Robert .L. Dunn(S?U SA. dupont. com

Allison Wiedeman, Technologies Coordinator
Chesapeake Bay Program Office
410-267-5733 '
wiedeman.allison@epa.gov

Darin Crew, Toxics Fellow
Chesapeake Research Consortium
410-267-9860
crew.darin@epa.gov

1 The Toxics 2000 Strategy and other reports and information
on mixing zones, chemical contaminants and the Bay
Program can be obtained at:

www.chesapeakebay.net


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