United States Environmental Protection Agency	Office of Research and Development

National Exposure Research Laboratory
Research Abstract

Government Performance Results Act (GPRA) Goal 3.3.2
Annual Performance Measure 232

Significant Research Findings:

Report on comparison of ecosystem exposure resulting from various
response scenarios including tested software and user's guide.

Oil spills can cause widespread environmental contamination and damage
to shorelines, wildlife and resources. There is a universal desire to
minimize this damage through various response approaches. One approach
is to use chemical dispersing agents-dispersants—to prevent shoreline and
wildlife oiling. The chemical dispersing agent, which consists of mixtures
containing surfactants, has the ability to facilitate breakup of an oil slick
into droplets that can be dispersed into the water column. The disadvantage
of dispersants is that the oil and dispersant may then contaminate the water
column and cause harmful effects on fish and other aquatic organisms. Part
of the decision-making process regarding dispersant use should include a
scientifically defensible assessment of the impact of dispersants.

Application of models is limited, however, due to limited data being
collected during oil spill responses. Thus, models can provide some insight
into oil slick and dispersant behavior, but it is unlikely that all required data
will be collected to support their usage. This means that careful evaluation
of the uncertainties inherent in use of oil spill models is required, and this
uncertainty needs to be factored into the decision-making process.

Research	The impact of dispersants on oil spills is assessed through use of an

Approach	extensible model development platform (MDP) developed for this project.

The MDP consists of graphical user interface components, object-oriented
numerical solvers, and a hierarchy of models and data for oil spills. The
object-oriented approach was selected, because some features of oil spills
align naturally with object-oriented programming - the common splitting of
oil slicks into small patches behave in similar ways. Such behavior is
ideally suited to the "object" paradigm of this kind of programming. A side
benefit is that the models, data and graphical user interfaces can be
combined to build the hierarchy of applications. The resulting model is
called the EPA Object-Oriented Oil Spill (ER03S) model.

Scientific
Problem and
Policy Issues

Along with development of the model, there were unmet data needs
concerning the behavior of dispersants and the properties and composition


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of certain crude oils. The project therefore included development of these
data to support use of the model. Because the commonly used dispersant
formulations are proprietary, the best way to include their interaction with
spilled oil is through empirical relationships. These were developed using a
new testing protocol developed by ORD for the Oil Spill program. This
protocol uses a baffled flask test (BFT) that was adopted for this work.

ER03S contains five separate models, built from a collection of model
components and data: 1) empirical dispersant data evaluation, 2) an
analytical dispersant model for the laboratory test, 3) a single oil
spreading/dispersant application model, 4) a patchy oil slick model that
uses components of items 1 and 3, and 5) an uncertainty calculation that
incorporates features of items 1, 3, and 4.

Each product supporting the development of the model was subjected to
peer review prior to publication.

Results and	The ER03S model is intended for use by on-scene coordinators and oil spill

Impact	response planners. Feedback from use of the first version of the model is

being gathered and used for revision and enhancement of the model. The
benefit of developing an EPA model is that the Agency will have access to
a public-domain model wherein all assumptions and limitations of the
model are transparent to the Agency.

The oil spill modeling has been an in-house, Federal effort that has been
augmented by collaboration with outside research groups. These included
Environment Canada Emergencies Science and Technology Division, and
the University of Cincinnati Department of Civil and Environmental
Engineering.

Zhendi Wang, B.P. Hollebone, M. Fingas, B. Fieldhouse,

L. Sigouin, M. Landriault, P. Smith, J. Noonan, and G. Thouin, 2003.
Characteristics of Spilled Oils, Fuels, and Petroleum Products:
1. Composition and Properties of Selected Oils, EPA/600/R-03/072.

George Sorial, Subhashini Chandrasekar, James W. Weaver, 2004.
Characteristics of Spilled Oils, Fuels, and Petroleum Products: 2a.
Dispersant Effectiveness Data for a Suite of Environmental Conditions -
The Effects of Temperature, Volatilization, and Energy, EPA Report in
Preparation.

James W. Weaver, 2004, Characteristics of Spilled Oils, Fuels, and
Petroleum Products: 3: Simulation of Oil Spills and Dispersants Under
Conditions of Uncertainty, EPA Report in Preparation.

Research
Collaboration and
Research
Products


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Future Research Development of oil spill modeling will continue with emphasis on the
multicomponent nature of the oil, transport of dissolved species and
droplets and coupling of the model with additional models and data on
bathymetry and climatic data. Future development will be coordinated and
shaped by interaction with EPA on-scene coordinators and oil spill
response planners in the EPA Regional offices. An Internet presentation of
the model and its supporting data is in preparation.

Contacts for

Additional

Information

Questions and inquiries can be directed to:

James W. Weaver, Ph.D.

U.S. EPA, Office of Research and Development
National Exposure Research Laboratory
960 College Station Road
Athens, Georgia 30605
Phone: 706-355-8329
E-mail: weaver.jim@epa.gov

Federal funding for this research was administered under EPA contract
numbers 1D-5859-NAFX, 68-W-01-032, and 69-C-00-159. Support for the
internal portion of this project was provided through the U.S. EPA's Office
of Research and Development, National Exposure Research Laboratory,
Ecosystems Research Division.


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