United States

Environmental Protection Agency

&EPA
OR9

US EPA Office of Research and Development

National Exposure Research Laboratory

Ozone Research

Ozone

Ozone is a naturally occurring chemical in the atmosphere. However, ozone concentrations can be
increased many fold in the lower atmosphere (troposphere) by emissions of atmospheric contaminants
such as Volatile Organic Compounds (VOCs) and Nitrogen Oxides (NOx). Increases in tropospheric
ozone concentrations are widespread, and elevated tropospheric ozone can make vegetation and humans
vulnerable to injury. NERL scientists play key roles in state-of-the science research into assessing ozone
concentrations and behavior, and in demonstrating the relevance of the science to policy and regulatory
requirements.

The North American Research Strategy for Tropospheric Ozone

The North American Research Strategy for Tropospheric Ozone (NARSTO) is a collaborative public
and private effort to define and implement research to further understand the science of tropospheric
ozone. NARSTO's first major project was to initiate an assessment for tropospheric ozone. This
assessment described the current state of ozone science as well as highlighted the relevance of ozone
science to policy makers in the United States, Canada, and Mexico. Taking into account the lessons
learned from the assessment, a revised research strategy is being drafted for ozone. NERL Scientists and
managers played significant roles in the initiation and production of the NARSTO assessment.

The Role of Nitrogen Oxides and Volatile Organic Compounds in
Ozone Formation

According to a 1991 National Research Council report, the previous United States emissions control
efforts may have focused too heavily on control of VOCs for reducing ozone pollution. The Southern
Oxidants Study, funded by EPA, explored the scientific issues concerning the roles that both VOCs and
NOx play in contributing to ozone levels. This research used observation-based models to investigate the
relative effectiveness of VOC and NOx controls for reducing ozone in urban and rural areas in the
southeast. Based on the study's data, control of VOCs would be more effective than controlling NOx for
reducing ozone in urban areas. In rural areas the opposite of this trend was seen. The findings in the
Southern Oxidants Study are significant because they provide invaluable guidance about the most
effective emission control efforts.

Good

Moderate

Unhealthy For



Very
Unhealthy



Sensitive
Groups

Unhealthy

Hazardous

Color Codes for Ozone Action Days


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Ozone Research

Benefits

Findings from the Southern Oxidants Study provides significant regulatory guidance about the most
effective emission control efforts.

Results of the Southern Oxidants Study report are directly relevant to the improvement of
instrumentation for national monitoring networks associated with the National Ambient Air Quality
Standards.

•	NARSTO ozone assessment includes many significant findings, including: ozone concentrations are
decreasing or remaining constant in most areas in North America, and decreases in ozone is likely
associated with decreases in mobile source emissions.

Purpose

•	NERL's participation in ozone research and assessment supports EPA's efforts to improve the
management community's ability to evaluate and assess impacts of ozone management practices,
particularly in controlling VOC and NOx emissions in ozone formation.

The NARSTO assessment described ozone science and highlighted its relevance to policymakers
across North America.

•	NERL's ozone research aids in the implementation of sound regulatory decision-making.

Accomplishments

A series of NARSTO Critical Review papers were commissioned that span the horizon of ozone
science, including trends assessment, monitoring/measurement methods, atmospheric modeling, and
source emissions.

A NARSTO Assessment Document was written that relates the current knowledge of ozone to the
needs of air quality managers in North America.

Observation-Based Modeling methods were used to determine the relative effectiveness of VOC and
NOx controls for reducing ozone in urban and rural areas in the southeastern United States.

Participants

Southern Oxidants Study: U.S. Environmental Protection Agency, Georgia Institute of Technology,
North Carolina State University, University of Alabama at Huntsville, University Corporation for
Atmospheric Research National Center for Atmospheric Research, Brookhaven National Laboratory,
and the Tennessee Valley Authority.

Tropospheric Ozone Assessment: U.S. Environmental Protection Agency, Office of Research and
Development, National Exposure Research Laboratory; other participants include
federal/state/provincial/local governments, industry groups, universities consultants, and others.

NARSTO	Southern Oxidants Study

For More Information*.	Kenneth Schere	Dr. Paul Solomon

schere.kenneth@epa.gov	solomon.paul@epa.gov

WEB ANNOUNCEMENT

MARCH 2001


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