Technical BRIEF INNOVATIVE RESEARCH FOR A SUSTAINABLE FUTURE Pressure Washing Surfaces Contaminated with Fixed or Loose Radioactive Material Best Practices for Urban Surfaces Purpose This technical brief provides a guide for using common pressure washers and tap water to decontaminate urban surfaces following a radiological contamination incident. These urban surfaces include porous, hard surfaces such as brick, concrete, granite, limestone, and their composites; non-porous surfaces such as glass, metal, and painted metal; and semi-porous surfaces such as asphalt. Vegetation and wood are not addressed. This brief provides general operating procedures, as well as estimated time, personnel requirements, and approaches for minimization and management of generated waste. Background The rapid decontamination of high-density urban areas is critical in the face of a radiological incident, particularly for contaminants (radionuclides) that have long half-lives, high-energy gamma emission(s), and/or present an inhalation or ingestion hazard. Such radionuclides can be released from dirty bombs, nuclear power plant accidents, transportations accidents, etc. Decontamination using readily-available equipment and resources can help mitigate the consequences of and expedite recovery from a radiological contamination incident (e.g., the nuclear power station accident in Fukushima, Japan). Decontamination by washing can be performed with equipment found in the inventories of many governmental agencies, local home supply stores, and the garages of businesses and homeowners. Many of these groups and individuals have experience and skill at using this equipment for various sorts of cleaning operations, although few, if any, have used it for radioactive contamination. For radioactive contamination, the efficacy of pressure washing depends on the pressure washer configuration (e.g., pressure rating and the nozzle's spray angle), the contaminant, the contaminated surface, and the time between the contamination incident and the pressure washing. This brief provides operating information based on reviewed field experience [1] and laboratory experiments [2-5], While it discusses general safety, this technical brief does not discuss the safe operation of pressurized sprayer equipment to avoid physical hazards, which is typically covered in the user's manual. It also includes but does not detail issues related to operation of the equipment to avoid unnecessary exposure of the equipment operator to radioactivity. Best Practices for Urban Surfaces I. General Safety The operator should avoid being wetted from splashes and by spray droplets and aerosols reflecting backwards from the surface. Always don appropriate personal protective equipment: protective eyewear, face cover, easily washable or disposable water-repelling clothing that covers the arms and legs completely, and closed-toe waterproof shoes. Steel-toe shoes should be worn if the pressure washer is rated at 4,000 psi or greater. Read the equipment operator's manual before use and review additional information provided by the CDC (https://www.cdc.Rov/disasters/pressurewashersafetv.ht ml). When equipment is operated appropriately, most of the spray wiii go forward, away from the operator, carrying with it the majority of the radioactivity, which is expected to be in the form of heavy particulates that present less inhalational hazard. The generation of reflected spray is greatly reduced if spray operations are performed under low wind conditions; wind will increase the spread of potentially contaminated droplets and aerosols. When necessary to operate under windy conditions or when spraying areas where excessive reflection of spray is unavoidable, consider this in the choice of face cover and/or think about alternatives to pressure washing. II. Choice of Wand and Spray Attachments There are a variety of wand and spray attachments provided by vendors (Fig. 1). Four primary, common attachments are the fan nozzle, turbo nozzle, water U.S. Environmental Protection Agency EPA/600/S-23/042 ------- broom, and surface cleaner. Fan nozzles produce a specified fan pattern that creates a fixed spray angle of 0°, 15°, 20° or 40°. The 0° nozzle is the most powerful for ablating materials but rarely recommended because it concentrates the spray into a jet that is difficult to control. The turbo nozzle (Fig. lb) solves the problem of control with the 0° nozzle by rapidly rotating the 0° jet in a 25° cone while retaining the power of the 0° nozzle. The fan and turbo nozzles generally are not shrouded (covered by a shroud to control splash aerosol), so caution should be exercised to minimize reflected splash. The water broom attachment (Fig. lc) allows for cleaning of a horizontal surface and/or movement of material to a common collection area, and some models come with a shroud to protect the operator against splash and reflected spray aerosol. To minimize contact with potentially- contaminated splash aerosol, it is recommended to use a shroud, if available, that contains the spray. The surface cleaner attachment (Fig. Id) surrounds the rotating spray nozzle system with a shroud to minimize aerosol generation and can be used on horizontal or vertical surfaces. Some industrial models of pressure washers have vacuum systems within the shroud that further minimize the splash and spray aerosol hazard and the potential for cross-contamination. Figure 1. Four primary types of pressure washer attachments: a) standard fan pattern nozzle (spray angle 0°, 15°, 25°, or 40°); b) turbo nozzle; c) water broom attachment; and d) surface cleaner attachment that surrounds the rotating spray nozzle system with a shroud to minimize splash and reflected spray aerosol generation. Ill, Fixed Contamination Guidelines Contamination fixed to the surface will require pressures sufficient to remove or ablate a very thin layer of surface material to effect decontamination. For horizontal surfaces, work from the highest elevation toward the lowest elevation so that the sprayed water moves downhill, away from the operator. For vertical surfaces, work from the top toward the bottom. To obtain the impact pressures on which this technical brief is based (i.e., the scientific literature cited), it is important to utilize the appropriate "contact angle" (i.e., the angle between the wand and the surface) and "spray angle" of the nozzle discussed earlier (e.g., 0°, 15°). Fig. 2a illustrates these angles for conventional applications. For radioactive decontamination, however, the spray nozzle should be directed as closely as possible to a contact angle of 90°, although for a freely open (unshrouded) nozzle, a contact angle of 90° should be avoided to prevent a significant splash of potentially contaminated water onto the operator. Instead, for open (unshrouded) nozzle operation, hold the wand at a contact angle that is slightly less than 90°. A contact angle of 85° (Fig. 2b) will significantly reduce splash onto the operator. A contact angle of less than 75° (Fig. 2c) should be avoided, as the impact pressure will not achieve the desired cleaning (ablation) effect. The spray fan pattern should be oriented parallel to the plane of the user for horizontal surfaces (Fig. 3a) to ensure a constant contact angle for the spray. For vertical surfaces, the fan should be oriented vertically, with the operator moving perpendicular of the fan direction (Fig. 3b). Figure 2. a) Example pressure washing system with variables identified. The power washer flowrate and pressure rating, nozzle spray angle, the contact angle between the wand and the surface, and the distance between the nozzle and surface influence the decontamination efficacy, b) 85° and c) 75° contact angles are shown. Targeted surface removal is 0.25 mm (0.01"). Based on experimental data, this can be achieved by holding the wand no greater than 15 cm (6 in) from the contaminated surface with a contact angle close to 90° using a 15- degree nozzle or turbo nozzle. To avoid splash contamination of the operator, use a contact angle of 85°. Other nozzle spray angles are not recommended as the experimental data found poor decontamination at larger spray angles and longer spray distances [3-5], At the 15 U.S. Environmental Protection Agency ------- cm (6 in) distance and with the 15° nozzle, the fan will cover a width of approximately 4 cm (1.6 in). The nozzle is moved slowly along the surface at ~0.3 m/min or ~1 ft/min for porous surfaces and ~3 m/min (~10 ft/min) for non-porous surfaces. These operating conditions are all important for efficacy, and they are simple to achieve with practice. The pressure washer should be rated at least 2,000 psi with a flow rate of at least 4.5 liters per minute (1.2 gpm). If the 15° or turbo nozzle is not supplied with the washer, choose a nozzle orifice size according to the washer manufacturer's instructions. Figure 3. Orientation of the spray fan and sweep pattern: horizontal surfaces (left) where the fan plane is as shown, and movement will be perpendicular to the fan plane; vertical surfaces (right) where the fan plane is as shown, and movement will be perpendicular to the fan plane. For turbo nozzles, the user may move in the forward or left-to-right directions without regard to the plane. With the surface cleaner attachment, the user may move in any direction of both horizontal and vertical surfaces because the spray is shrouded against splash and spray aerosol. Water brooms generally do not allow the user to controllably spray at contact angles greater than 75°. Therefore, they are not generally suitable for removal of fixed contamination, unless they can be adjusted to or operated at the 85° contact angle indicated by experimental data and have 15° spray angle nozzles. Surface cleaner attachments have fixed contact angle nozzles designed to spin the spray bar to generate a large, circular cleaning pattern. For this system, 15°nozzles should be installed with a pressure washer rated for at least 2,000 psi with a flow rate of at least 4.5 liters per minute (1.2 gpm) to produce the desired ablation. The surface cleaner attachment should be moved slowly at around 0.3 m/min (1 ft/min) for porous surfaces and ~3 m/min (~10 ft/min) for non-porous surfaces. IV. Loose Contamination Guidelines Contamination ioosely held to or simply sitting on the surface will require pressures sufficient to move the material along the surface to effect decontamination. For horizontal surfaces, work from the highest elevation toward the lowest elevation, so that the sprayed water moves downhill, away from the operator. For vertical surfaces, work from the top toward the bottom. For loose contamination, the turbo nozzle and the 15°, 25°, or 40° fan nozzles should be effective. The wand should be held no more than 27 cm (11 in) from the contaminated surface with a contact angle close to 90°. To avoid splash contamination of the operator, use a contact angle of 85°. These operating conditions are based on experimental data obtained using a 40° nozzle at a distance no greater than 28 cm (11 in) [3], which produces a fan width of 23 cm (9.2 in). For other nozzle angles, consult Fig. 4 to determine an equivalent distance between surface and nozzle. The nozzle is moved slowly along the surface (~0.3 m/min or 1 ft/min) for porous surfaces and ~3 m/min (~10 ft/min) for non-porous surfaces. The pressure washer should be rated for at least 2,000 psi with a flow rate of at least 4.5 liters per minute (1.2 gpm). If not supplied with the washer, choose a nozzle orifice size according to the washer manufacturer's instructions. Water broom and surface cleaner attachments will be effective at removing loose contamination and should be used with a pressure washer rated for at least 2,000 psi with a flow rate of at least 4.5 liters per minute (1.2 gpm); and moved slowly along the surface (~0.3 m/min or ~1 ft/min) for porous surfaces and ~3 m/min (~10 ft/min) for non-porous surfaces. Follow the manufacturer's instructions for recommended pressure washer rating (psi and gpm). Table 1. Recommended power washing parameters for fixed and loose contamination (based on 2,000 psi and flow rate of at least 4.5 L/min or 1.2 gpm). Contamination type Spray attachment type Maximum distance between nozzle and surface Contact angle Fixed 15° fan and turbo nozzles; surface cleaner 15 cm (6 in) 85° Loose 15°, 25°, 40° and turbo nozzles, water 28 cm (11 in)* 85° broom, surface cleaners *The water broom and surface cleaner attachments have fixed distances and contact angles, but because of the short distance between nozzle and surface, they remove loose contamination effectively. U.S. Environmental Protection Agency ------- V. Applying Guidelines to Other Washer Configurations The pressure applied through the washer nozzle is at the heart of the efficacy of pressure washing. The parameters in Table 1 are those of the pressure washer used to generate the experimental efficacy data. To mimic this experimental set-up, it is recommended that a 40° nozzle be used at a distance of 28 cm (11 in) for loose contamination, producing a fan width of 23 cm (9.2 in) (Figure 4, blue line). However, operators may wish to use different nozzles or nozzle distances above the surface, perhaps in conjunction with different spray attachments (Figure 1). Figure 4 can help users select alternate configurations. As an example, if the user chooses a 25° nozzle, the equivalent distance is found by marking the point where the 40° nozzle line is at 11 in (red dot) and drawing a vertical line until it meets the 25° nozzle line (red line). The new distance is 20 in for the 25° nozzle. For washers with other ratings, to maintain a similar impact force on the surface, the distance from the nozzle to the surface needs to change. For washers with higher ratings than 2,000 psi, the nozzle distance can be increased and for those rated less than 2000 psi, the maximum nozzle distance will decrease. Guidelines are being developed. -14-12-10 -8 -6 -4 -2 0 2 4 6 8 10 12 14 Fan width (in) Figure 4. Theoretical coverage for different nozzle fan angles. This chart can be used to choose an equivalent nozzle type and distance to the surface for loose contamination and estimate the application times. Time and Personnel Estimates The estimated application times per 100 m2 (~1,100 ft2) for pressure washing fixed and loose contamination from U.S. Environmental Protection Agency porous and non-porous urban surfaces are given in Table 2. The times are represented as person-hours (person-h), which is one person working for one hour. Table 2. Approximate application times per 100 m2 (~1,100 ft2) for fixed or loose contamination on porous and non- porous surfaces [6], The listed person-hrs are only for pressure washing, not associated activities like waste management. Additional time for another worker may also be needed as part of good safety practice. Contamination Porous surface Non-porous surface type (1 ft/min) (10 ft/min) Fixed 140 person-h 14 person-h Loose 24 person-h 2.4 person-h In Table 2, the person-hours for power washing are estimated to be a factor of ten less for non-porous surfaces (such as glass, bare or painted metal, painted and sealed masonry) than porous surfaces (such as concrete, brick, other masonry) because of the larger fan pattern necessary [3]. Higher rates were also reported for loose contamination with simulated fallout particles by another washing approach [4]. Assuming non-porous surfaces are smooth and contaminants cannot seep into the subsurface, all contaminant forms will be quickly removed from non-porous materials. Asphalt, while it is generally non-porous unless cracked or aged, can have fixed contamination if its aggregate is exposed and porous. Thus, materials that are essentially only slightly porous, such as asphalt, can be cleaned at a faster rate using a 15° nozzle held no greater than 15 cm (6 in) from the contaminated surface and moved at a faster rate of ~3 m/min (~10 ft/min) than suggested in Table 2 for porous surfaces. The application time is influenced by the choice of spray nozzle and height, which can vary by spray attachment (Fig. 1). Figure 4 can be used to estimate application time. To do this, the operator first finds the fan width for their nozzle type (for the turbo nozzle, use the 25° line) and distance. The total contaminated surface area is calculated by multiplying the area's width by its height, and then this value is divided by the product of the movement rate and the fan width. For example, a 10m x 10m (32.8 ft x 32.8 ft) wall has a surface area of 100m2 (1,100 ft2). For loose contamination, the operator decides to use a 25° nozzle from the example in Section 5 that produces a fan width of 23 cm (9.2 in). Because the recommended movement rate is 0.3 m/min (1 ft/min), the calculated application time is: 100 m2 ¦ = 1449 min =24 h 0.23m x 0.3- ------- Waste Management Decontamination will produce solid and/or liquid waste, depending on the contaminant and contaminated surface. Prepare to capture and store any waste liquid and debris from washing activities until guidance from local, responsible authorities on the management of such waste is determined. Additional information about equipment for waste management can be found elsewhere [7, 8]. The amount of liquid waste generated by pressure washing can be estimated by multiplying the rated pressure washer flow rate and the application time. If the application time is not pre-established, it can be estimated via Fig. 4, as described above using the nozzle degree, distance between the nozzle and contaminated surface, and the wand movement rate. Additional Challenges and Concerns There are challenges related to the use of pressure washing for contaminant removal not fully considered in this brief. One is the reabsorption of contaminants onto surfaces after pressure washing, particularly runoff from higher surfaces contaminating lower surfaces. Reabsorption is mainly a concern for contaminants in the liquid phase of the waste/runoff. Relatedly, particles may become forced into cracks in the surface at the site of pressure washing, or particles in the runoff water may become trapped in downstream cracks. Another consideration arises from filtering and collecting the solid waste generated from power washing contaminated surfaces; this affects both dose accumulation from collected solids and the deployment of such a system at field scale. For pressure washing activities occurring after a large contamination incident, acceptable work periods based on projected dose can vary. Lower-level areas would not be expected to produce doses that would limit working times [7], but pressure washing in higher radiation zones may require limited work periods to limit dose to personnel. Also, one must consider that personnel may need to stand much closer to contaminated surfaces for fixed contamination pressure washing than for loose contamination pressure washing, thus incurring higher dose. Contacts Technical Contacts • Matthew Magnuson, magnuson.matthew@epa.gov • Michael Kaminski, kaminski@anl.gov • Katherine Hepler, khepler@anl.gov General Feedback/Questions Contact • CESER@epa.gov U.S. Environmental Protection Agency Disclaimer: This technical brief is for informational purposes only. It was subject to administrative review but does not necessarily reflect the view of the U.S. Environmental Protection Agency (EPA). No official endorsement should be inferred, as the EPA does not endorse the purchase or sale of any commercial products or services. The submitted technical brief has been created by UChicago Argonne, LLC, Operator of Argonne National Laboratory ("Argonne"). Argonne, a U.S. Department of Energy Office of Science laboratory, is operated under Contract No. DE-AC02-06CH11357. The U.S. Government retains for itself, and others acting on its behalf, a paid-up nonexclusive, irrevocable worldwide license in said article to reproduce, prepare derivative works, distribute copies to the public, and perform publicly and display publicly, by or on behalf of the Government. All figures are courtesy of Shutterstock or not subject to license. References 1) M.D. Kaminski, S.D. Lee, and M. Magnuson. Wide-area decontamination in an urban environment after radiological dispersion: A review and perspectives. J. Haz.Mat., Vol. 305, pp. 67- 86, 2015. 2) W. C. Jolin, M. L. Magnuson, and M. D. Kaminski. High Pressure Decontamination of Building Materials during Radiological Incident Recovery. J. Environ. Radioact., p. 105858, Jun. 2019. 3) K. Hepler, M. D. Kaminski, W. Jolin, and M. Magnuson. Decontamination of Urban Surfaces Contaminated with Radioactive Materials and Consequent Onsite Recycling of the Waste Water. Environ. Technol. Innov., p. 101177, 2021. 4) W. Jolin and M.D. Kaminski. Developing surrogate far-field nuclear fallout and its rapid decontamination from aircraft surfaces. ANL/SSS-19/1, 2019. https://doi.ore/10.2172/1543295. 5) M.D. Kaminski, C. Oster, N. Kivenas, S. Lopykinski, and M. Magnuson. Penetration of Fission Products Ions into Complex Solids and the Effect of Ionic Wash Methods. Environ Sci. Pollut. Res., 28, 10114-10124, 2021. https://doi.org/10.1007/sll356-02Q-11392-w. 6) W. Jolin, M.D. Kaminski, K. Hepler, and M. Magnuson. Detailed Guidelines for the Decontamination of Porous and Non-Porous Surfaces from Radioactive Contaminations. In preparation. 7) M.D. Kaminski, K. McConkey, M. Magnuson, and S.D. Lee. Municipal and commercial equipment for radiological response and recovery in an urban environment: State of science, research needs, and evaluation of implementation towards critical infrastructure resilience. ANL-NE-17-37, 2017. https://doi.ore/10.2172/1528921. 8) M. Magnuson and M.D. Kaminski. Readily Available Equipment for Response and Recovery. U.S. EPA Emergency Response Research Webinar Series, 2021. https://www.epa.gov/emergencv- response-research/readilv-available-equipment-response-and- recoverv-webinar. 9) M.D. Kaminski, K. Sanders, M. Magnuson, K. Hepler, and J. Slagley. External Dose to Recovery Teams Following a Nuclear or Radiological Release Event. Health Physics, 120(6), pp. 591-599, June 2021. https://doi.org/10.1097/hp.00000000000Q1381. ------- |