£ < 5 \ ^60 sx Q "U PRO^ LU a Analytical Methods Recommended for Drinking Water Monitoring of Secondary Contaminants Analysis for the following contaminants may be conducted in accordance with the methods in the following table, or their equivalent as determined by EPA. Methods for copper, fluoride, and pH are listed in 40 CFR 141.23 and methods for the remaining contaminants are in 40 CFR 143.4. Additional methods are listed in Appendix A to Subpart C of Part 141. The recommended monitoring for these contaminants is specified in 40 CFR 143.4. The CFR is the legal reference for approved methods and takes precedent over this table. The table should accurately reflect the analytical methods information published in 40 CFR 141.23, 143.4, and Appendix A to Subpart C of Part 141. If you find discrepancies, please notify' The Safe Drinking Water Hotline (800-426-4791) so that EPA can correct the table. Contaminant.. „ „ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Aluminum EPA 200.5 Rev 4.2 Determination of Trace Elements October 2003 EPA/600/R-06/115 in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery http ://www.epa. gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http://www.nemi.sov EPA 200.8 Rev 5.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http://www.nemi.sov EPA 200.9 Rev 2.2 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 http://www.nemi.sov Standard Methods 3111 D Standard Methods for the Examination of Water and Wastewater, 18th Edition 1992 Standard Methods Standard Methods 3111 D Standard Methods for the Examination of Water and Wastewater, 19th Edition 1995 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 1 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Aluminum Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard Methods 3111 D Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3111 D-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 2 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Aluminum Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). http ://www. standardmethods. org/ http ://www. standardmethods. org/ http ://www. standardmethods. org/ Standard 3113 B-04 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Standard 3113 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Chloride ASTM D4327-03 Annual Book of ASTM Standards, http://www.astm.ori> International Vol. 11.01 ASTM International D4327-97 Annual Book of ASTM Standards, Vol. 11.01 http ://www. astm. org ASTM D512-04 B Annual Book of ASTM Standards, htto ://www. astm. org International Vol. 11.01 ASTM D512-89 B Annual Book of ASTM Standards, httD ://www. astm. org International (Reapproved Vol. 11.01 1999) Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 3 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Chloride EPA 300.0 Rev 2.1 In Methods for the Determination August 1993 EPA/600/R-93/100 PB94-120821 http://www.nemi.aov of Inorganic Substances in Environmental Samples EPA 300.1 Rev 1.0 In Methods for the Determination August 2000 EPA 815-R-00-014 PB2000-106981 http://www.epa.aov/safewater/methods/anaiYticaimethods oBwdw.htmi of Organic and Inorganic Compounds in Drinking Water, Volume 1 Standard 4110 B Standard Methods for the 1992 Standard Methods Methods Examination of Water and Wastewater, 18 th Edition Standard 4110 B Standard Methods for the 1995 Standard Methods Methods Examination of Water and Wastewater, 19 th Edition Standard 4110 B Standard Methods for the 1998 Standard Methods Methods Examination of Water and Wastewater, 20th Edition Standard Methods 4110 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 4500-C1- B Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 4500-C1- B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 4500-C1-B Standard Methods for the 1998 Standard Methods Methods Examination of Water and Wastewater, 20th Edition Standard 4500-C1- B Standard Methods for the 2005 Standard Methods Methods Examination of Water and Wastewater, 21 st Edition Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 4 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Chloride Standard 4500-C1-D Standard Methods for the 1992 Standard Methods Methods Examination of Water and Wastewater, 18 th Edition Standard 4500-C1-D Standard Methods for the 1995 Standard Methods Methods Examination of Water and Wastewater, 19 th Edition Standard 4500-C1-D Standard Methods for the 1998 Standard Methods Methods Examination of Water and Wastewater, 20th Edition Standard 4500-C1- D Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 4110 B-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 4500-C1- B-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 4500-C1- D-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 5 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Chloride Waters Method Test Method for Determination of Corporation D6508, Dissolved Inorganic Anions in Revision 2 Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Waters Corporation Color Standard Methods 2120 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 2120 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 2120 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 2120 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 2120 B-01 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Copper Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). ASTM D1688-02 A Annual Book of ASTM Standards, International Vol. 11.01 http ://www. astm. org ASTM D1688-02 C Annual Book of ASTM Standards, International Vol. 11.01 http ://www. astm. org Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 6 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are V 1 contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). ASTM International D1688-07 A Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ora ASTM International D1688-07 C Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ora ASTM International D1688-90 A Annual Book of ASTM Standards, Vol. 11.01 ASTM International (ASTM) ASTM International D1688-90 C Annual Book of ASTM Standards, Vol. 11.01 ASTM International (ASTM) ASTM International D1688-95 A Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ora ASTM International D1688-95 C Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ora EPA 200.5 Rev 4.2 Determination of Trace Elements October 2003 EPA/600/R-06/115 http J/www, epa. aov/nericwww/ordmeth.htm in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov EPA 200.8 Rev 5.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov EPA 200.9 Rev 2.2 In Methods for the Determination May 1994 EPA/600/R-94/111 PB95-125472 http://www.nemi.Bov of Metals in Environmental Samples Supplement 1 Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 7 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Copper Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 3111 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 8 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Copper Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3111 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3113 B-04 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3113 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Fluoride ASTM D1179-04 B Annual Book of ASTM Standards, http://www.astm.ora International Vol. 11.01 Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 9 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Fluoride ASTM D1179-93 B Annual Book of ASTM Standards, ASTM International (ASTM) International Vol. 11.01 ASTM International D1179-99 B Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ore ASTM International D4327-03 Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ora ASTM International D4327-97 Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ore Bran + Luebbe 129-71W Fluoride in Water and Wastewater December 1972 Bran+Luebbe Bran + Luebbe 380-75WE Fluoride in Water and Wastewater February 1976 Bran+Luebbe EPA 300.0 Rev 2.1 In Methods for the Determination of Inorganic Substances in Environmental Samples August 1993 EPA/600/R-93/100 PB94-120821 httD: //www. nemi. 2 ov EPA 300.1 Rev 1.0 In Methods for the Determination of Organic and Inorganic Compounds in Drinking Water, Volume 1 August 2000 EPA 815-R-00-014 PB2000-106981 httD://www.eDa.20v/safewater/methods/analvticalmethods 02wdw.html Hach Co. 10225 Hach Company SPADNS 2 (Arsenite-Free) Fluoride Method 10225—Spectrophotometry; Measurement of Fluoride in Water and Wastewater January 2011 httD ://www. hach. com Standard Methods 4110 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 4110 B Standard Methods for the Examination of Water and 1995 Standard Methods Wastewater, 19 th Edition Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 10 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Fluoride Standard Methods 4110 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 4110 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 4500-F-B Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 4500-F-B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 4500-F-B Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 4500-F-B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 4500-F-C Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 4500-F-C Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 4500-F-C Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 4500-F-C Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 11 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Fluoride Standard 4500-F-D Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 4500-F-D Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 4500-F-D Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 4500-F-D Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 4500-F-E Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 4500-F-E Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 4500-F-E Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 4500-F-E Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 4110 B-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 12 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Fluoride Standard 4500-F-B-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 4500-F-C-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 4500-F-D-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 4500-F-E-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Waters Method Test Method for Determination of Corporation D6508, Dissolved Inorganic Anions in Revision 2 Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Waters Corporation Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 13 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Foaming Agent^ Standard Methods 5540 C Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 5540 C Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition Supplement 1996 Standard Methods Standard Methods 5540 C Standard Methods for the 1998 Examination of Water and Wastewater, 20th Edition Standard Methods Standard Methods 5540 C Standard Methods for the 2005 Examination of Water and Wastewater, 21 st Edition Standard Methods Standard Methods Online 5540 C-00 Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Iron Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery October 2003 EPA/600/R-06/115 http://www.epa.gov/nerlcwww/ordmeth.htm EPA 200.7 Rev 4.4 In Methods for the Determination May 1994 of Metals in Environmental Samples Supplement 1 EPA/600/R-94/111 PB95-125472 http: //www. nemi. g ov Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 14 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Iron Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.9 Rev 2.2 In Methods for the Determination May 1994 EPA/600/R-94/111 of Metals in Environmental Samples Supplement 1 PB95-125472 http: //www. nemi. g ov Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3111 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 15 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Iron Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3120 B Standard Methods for the 1998 Standard Methods Methods Examination of Water and Wastewater, 20th Edition Standard 3120 B Standard Methods for the 2005 Standard Methods Methods Examination of Water and Wastewater, 21 st Edition Standard 3111 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Standard 3113 B-04 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Standard 3113 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ http ://www. standardmethods. org/ http ://www. standardmethods. org/ http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 16 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method j Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are anganese contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements October 2003 EPA/600/R-06/115 http://ww».epa.aov/nericwww/ordmeth.htm in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov EPA 200.8 Rev 5.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov EPA 200.9 Rev 2.2 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 17 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Manganese Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3113 B Standard Methods for the 2005 Standard Methods Methods Examination of Water and Wastewater, 21 st Edition Standard 3120 B Standard Methods for the 1992 Standard Methods Methods Examination of Water and Wastewater, 18 th Edition Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3111 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3113 B-04 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 18 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Manganese Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3113 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Odor Standard 2150 B Standard Methods for the 1992 Standard Methods Methods Examination of Water and Wastewater, 18 th Edition Standard 2150 B Standard Methods for the 1995 Standard Methods Methods Examination of Water and Wastewater, 19 th Edition Standard 2150 B Standard Methods for the 1998 Standard Methods Methods Examination of Water and Wastewater, 20th Edition Standard 2150 B Standard Methods for the 2005 Standard Methods Methods Examination of Water and Wastewater, 21 st Edition Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 19 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Odor Standard 2150 B-97 Online version of Standard http ://www. standardmethods. or g/ Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. pH ASTM International D1293-84 Annual Book of ASTM Standards, Vol. 11.01 ASTM International (ASTM) ASTM International D1293-95 Annual Book of ASTM Standards, Vol. 11.01 ASTM International (ASTM) ASTM International D1293-99 Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ora EPA 150.1 In Methods for Chemical Analysis of Water and Wastes March 1983 EPA/600/4-79/020 PB84-128677 httD: //www. nemi. 2 ov EPA 150.2 In Methods for Chemical Analysis of Water and Wastes March 1983 EPA/600/4-79/020 PB84-128677 httD: //www. nemi. 2 ov Standard Methods 4500-H+ B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 4500-H+ B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 4500-H+ B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4500-H+ B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 20 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method PH Online version of Standard http://www, standardmethods. orB/ Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. .j I Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements October 2003 EPA/600/R-06/115 http://www.epa.aov/nericwww/ordmeth.htm in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery EPA 200.7 Rev 4.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov EPA 200.8 Rev 5.4 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov EPA 200.9 Rev 2.2 In Methods for the Determination of Metals in Environmental Samples Supplement 1 May 1994 EPA/600/R-94/111 PB95-125472 httD: //www. nemi. 2 ov Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3111 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 21 of30 Standard 4500-H+ B-00 Methods Online ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Silver Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 3113 B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 3113 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3111 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 22 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Silver Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3113 B-04 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3113 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ U.S. 1-3720-85 In Methods for Determination of Geological Inorganic Substances in Water and Survey Fluvial Sediments, USGS Series: Techniques of Water-Resource Investigation Report; edited by Fishman, M.J. & Friedman, L.C. 1989 05-A1 http://infotrek.er.usgs.gov/pubs/ Sulfate ASTM D4327-03 Annual Book of ASTM Standards, http://www.astm.ora International Vol. 11.01 ASTM D4327-97 Annual Book of ASTM Standards, http://www.astm.orB International Vol. 11.01 Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 23 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Sulfate ASTM D516-02 Annual Book of ASTM Standards, http://www.astm.ora International Vol. 11.01 ASTM International D516-07 Annual Book of ASTM Standards, Vol. 11.01 httD ://www. astm. ore ASTM International D516-90 Annual Book of ASTM Standards, Vol. 11.01 ASTM International (ASTM) EPA 300.0 Rev 2.1 In Methods for the Determination of Inorganic Substances in Environmental Samples August 1993 EPA/600/R-93/100 PB94-120821 httD: //www. nemi. 2 ov EPA 300.1 Rev 1.0 In Methods for the Determination of Organic and Inorganic Compounds in Drinking Water, Volume 1 August 2000 EPA 815-R-00-014 PB2000-106981 httD://www.eDa.20v/safewater/methods/analvticalmethods 02wdw.html EPA 375.2 Rev 2.0 In Methods for the Determination of Inorganic Substances in Environmental Samples August 1993 EPA/600/R-93/100 PB94-120821 httD: //www. nemi. 2 ov Standard Methods 4110 B Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 4110 B Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 4110 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4110 B Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 4500-S042- C Standard Methods for the Examination of Water and 1992 Standard Methods Wastewater, 18 th Edition Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 24 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Sulfate Standard Methods 4500-S042- C Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 4500-S042- C Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4500-S042- C Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 4500-S042- D Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 4500-S042- D Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 4500-S042- D Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4500-S042- D Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 4500-S042- E Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 4500-S042- E Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 4500-S042- E Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 25 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method Sulfate Standard Methods 4500-S042- E Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard Methods 4500-S042- F Standard Methods for the Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard Methods 4500-S042- F Standard Methods for the Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 4500-S042- F Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard Methods 4500-S042- F Standard Methods for the Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 4110 B-00 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 4500-S042- C- Online version of Standard Methods 97 Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 26 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Sulfate Standard 4500-S042- D- Online version of Standard http ://www. standardmethods. or g/ Methods 97 Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. Standard Methods Online 4500-S042- E- 97 Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. httD ://www. standardmethods. ora/ Standard Methods Online 4500-S042- F- 97 Online version of Standard Methods for the Examination of Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. httD ://www. standardmethods. ora/ Waters Corporation Method D6508, Revision 2 Test Method for Determination of Dissolved Inorganic Anions in Aqueous Matrices Using Capillary Ion Electrophoresis and Chromate Electrolyte Waters Corporation TDS Standard Methods 2540 C Standard Methods for the 1992 Examination of Water and Wastewater, 18 th Edition Standard Methods Standard Methods 2540 C Standard Methods for the 1995 Examination of Water and Wastewater, 19 th Edition Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 27 of 30 ------- Contaminant Method Organization Number Reference Title Date EPA Publication Number Publication Order Number Source of Method TDS Standard Methods 2540 C Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 2540 C Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 2540 C-97 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Zinc Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). EPA 200.5 Rev 4.2 Determination of Trace Elements October 2003 EPA/600/R-06/115 http J/www, epa. aov/nericwww/ordmeth.htm in Drinking Water by Axially Viewed Inductively Coupled Plasma - Atomic Emission Spectrometery EPA 200.7 Rev 4.4 In Methods for the Determination May 1994 EPA/600/R-94/111 PB95-125472 http://www.nemi.Bov of Metals in Environmental Samples Supplement 1 EPA 200.8 Rev 5.4 In Methods for the Determination May 1994 EPA/600/R-94/111 of Metals in Environmental Samples Supplement 1 PB95-125472 http: //www. nemi. g ov Standard 3111 B Standard Methods for the Methods Examination of Water and Wastewater, 18 th Edition 1992 Standard Methods Standard 3111 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 28 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Zinc Criteria for analyzing aluminum, copper, iron, manganese, silver, and zinc samples with digestion or directly without digestion, and other recommended procedures are contained in Section IV of Technical Notes on Drinking Water Methods (EPA/600/R-94/173) available through EPA's digital publications National Environmental Publications Internet Site (NEPIS) database (http://www.epa.gov/nscep/). Standard 3111 B Standard Methods for the 2005 Standard Methods Methods Examination of Water and Wastewater, 21 st Edition Standard 3120 B Standard Methods for the 1992 Standard Methods Methods Examination of Water and Wastewater, 18 th Edition Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 19 th Edition 1995 Standard Methods Standard Methods 3120 B Standard Methods for the Examination of Water and Wastewater, 20th Edition 1998 Standard Methods Standard 3120 B Standard Methods for the Methods Examination of Water and Wastewater, 21 st Edition 2005 Standard Methods Standard 3111 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Standard 3120 B-99 Online version of Standard Methods Methods for the Examination of Online Water and Wastewater. Approval year by Standard Methods Committee is designated by last 2 digits. This is the only online version that is approved. http ://www. standardmethods. org/ Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 29 of 30 ------- Contaminant„ EPA Publication Method Publication Order Organization Number Reference Title Date Number Number Source of Method Contact information for methods that are not available on the Internet are summarized in the report titled "Sources of Approved Analytical Methods for National Drinking Water Regulations." Revised June 2011 Recommended Methods for Secondary Drinking Water Contaminants Page 30 of 30 ------- |