United States Environmental Protection Agency	Office of Research and Development

National Exposure Research Laboratory
Research Abstract

Government Performance Results Act (GPRA) Goal 3, Land Preservation and Restoration
Annual Performance Measure #213

Significant Research Findings:

Provide data for use in NRMRL's Annual Superfund Innovative
Technology Evaluation (SITE) Program Progress Report

The use of field analysis often provides a savings in time and cost over the
usual 'sample and ship' to a conventional laboratory for analysis approach
to site characterization and monitoring. With improvements in technology
and appropriate quality assurance/quality control, field analysis has been
shown to provide high quality data useful for most environmental
monitoring or characterization projects. The objective of the SITE program
is to promote the acceptance and use of innovative field technologies by
providing well-documented performance and cost data obtained from field
demonstrations.

The Measurement and Monitoring Technology (MMT) Program, a part of
the overall SITE program, is designed to conduct demonstrations that will
generate high-quality data so that potential users have reliable information
regarding the technology performance and cost. Four steps are inherent in
the process: (1) needs identification and technology selection, (2)
demonstration planning and implementation, (3) report preparation, and (4)
information distribution.

The first step of the technology verification process begins with identifying
technology needs of the EPA and regulated community. The EPA Regional
offices, the U.S. Department of Energy, the U.S. Department of Defense,
industry, and state environmental regulatory agencies are asked to identify
technology needs for sampling, measurement, and monitoring of
environmental media. The second step of the technology verification
process is to plan and implement a demonstration that will generate
representative, high-quality data to assist potential users in selecting a
technology. The third step of the technology verification process is for
EPA to publish a verification statement and a detailed evaluation of each
technology in an innovative technology verification report (ITVR). Lastly,
EPA distributes demonstration information through the use of fact sheets,
newsletters, brochures, bulletins and ITVRs through direct mailings, at
conferences, and on the Internet. Summary MMT input is provided to the

Scientific
Problem and
Policy Issues

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National Risk Management Research Laboratory (NRMRL) for inclusion in
the annual SITE program progress report.

Results and	In FY03, the MMT program completed a demonstration of technologies for

Impact	the determination of mercury in soils and sediments with the final reports

being published in FY04. Results from the demonstration are being used
by the Office of Solid Waste to revise their SW-846 method for measuring
mercury contamination. The SITE reports have also been used by the
manufacturers of the technologies participating in the demonstration as
indications of their technology's performance capabilities.

The field element of a demonstration of assays for dioxin and dioxin-like
compounds was completed in the spring of 2004 and the ITVRs are in
preparation. When published, the results from this demonstration may be
used by many programs including the EPA's National Dioxin program and
the Superfund's Contract Laboratory program to change/modify their
methodologies and regulations.

Planning for an X-ray fluorescence (XRF) instrumentation demonstration is
underway, and the field component is planned to start in 2005. Results
from the demonstration may be used by the Office of Solid Waste to revise
their SW-846 Method 6200 - Field Portable X-Ray Fluorescence
Spectrometry for the Determination of Elemental Concentrations in Soil
and Sediment.

SITE demonstrations are performed in collaboration with numerous federal
and state agencies. For example, the mercury in soil and sediment
demonstration was conducted at the Department of Energy's Oak Ridge
National Laboratory with contaminated samples being obtained from
multiple sites and multiple Regions. The dioxin in soil and sediment
demonstration was conducted at a State of Michigan park and was strongly
supported by the State and Region V. Summary MMT input was provided
to NRMRL for incorporation in the annual SITE program progress report
to Congress.

The results of each SITE demonstration are published as individual
reports; one report per participant. The reports published in FY04 are:

Billets, S.N. and A.B. Dindal. 2004. Demonstration and quality assurance project plan for
the monitoring and measurement of dioxin and dioxin-like compounds in soil and
sediment. EPA/600/R-04/036.

Billets, S.N., J. Nicklas, and J. Evans. 2004. Field measurement for mercury in soil and
sediment. Metorex X-MET 2000 X-ray fluorescence technology. EPA/600/R-03/149.

Billets, S.N., J. Nicklas, and J. Evans. 2004. Field measurement for mercury in soil and

Research
Collaboration and
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sediment. Milestone Inc. Direct mercury analyzer (DMA) -80. EPA/600/R-04/012.

Billets, S.N., J. Nicklas, and J. Evans. 2004. Field measurement for mercury in soil and
sediment. MTI, Inc. PDV 6000 Anodic stripping voltammetry. EPA/600/R-04/028.

Billets, S.N., J. Nicklas, and J. Evans. 2004. Field measurement for mercury in soil and
sediment. NITON Xli/XLt 700 series X-ray fluorescence analyzer. EPA/600/R-03/148.

Billets, S.N., J. Nicklas, and J. Evans. 2004. Field measurement for mercury in soil and
sediment. Ohio Lumex RA-915+/RP-91C mercury analyzer. EPA/600/R-03/147.

Future Research The XRF demonstration was initiated in FY04. This demonstration will
include eleven technology developers and includes a partnership with
NASA to host the demonstration at the Kennedy Space Center in Florida.
The demonstration will take place in January 2005.

The development of microelectronic devices, some of which incorporate
biosensor technology, will be the focus of the next planned demonstration.
This future demonstration will address the analysis of halogenated phenols
in soil and sediment. The demonstration will be initiated in FY05.

Questions and inquiries regarding NERL's SITE Program work can be
directed to:

Stephen Billets, Ph.D.

U.S. EPA

National Exposure Research Laboratory
944 East Harmon Ave., Las Vegas, NV 89119
Phone: 702-798-2232
E-mail: billets.stephen@epa.gov

Federal funding for this research was administered under EPA contract
numbers 68CO0179 (mercury), 68CO0185 (dioxins), and 68CO0181
(XRF).

Contacts for

Additional

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