DRAFT
CASTNET
2019 Annual Report

Prepared for:

U.S. Environmental Protection Agency
Office of Atmospheric Programs

Prepared by:

environmental engineering
& measurement services, inc.

4475E NW 6th Street, Ext
Gainesville, FL 32609

Contract No. EP-W-18-005
October 2020


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

Table of Contents

1.0 Introduction	1-1

2.0 Project Objectives	2-1

3.0 CASTNET Sites Visited in 2019	3-1

4.0 Performance Audit Results	4-1

4.1	Ozone	4-3

4.1.1 Ozone Bias	4-6

4.2	Flow Rate	4-11

4.3	Shelter Temperature	4-11

4.4	Wind Speed	4-14

4.4.1 Wind Speed Starting Threshold	4-14

4.5	Wind Direction	4-14

4.5.1 Wind Direction Starting Threshold	4-14

4.6	Temperature and Two-Meter Temperature	4-15

4.6.1 Temperature Shield Blower Motors	4-16

4.7	Relative Humidity	4-16

4.8	Solar Radiation	4-19

4.9	Precipitation	4-19

4.10	Data Acquisition Systems (DAS)	4-20

4.10.1	Analog Test	4-20

4.10.2	Functionality Tests	4-20

5.0 Systems Audit Results	5-1

5.1	Siting Criteria	5-1

5.2	Sample Inlets	5-1

5.3	Infrastructure	5-2

5.4	Site Operators	5-2

5.5	Documentation	5-2

5.6	Site Sensor and FSAD Identification	5-3

6.0 Summary and Recommendations	6-1

6.1 In Situ Comparisons	6-1

7.0 References	7-1

location

1

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

List of Appendices

Appendix 1. Audit Standards Certifications
List of Tables

Table 2-1. Performance Audit Challenge and Acceptance Criteria	2-1

Table 3-1. Systems and Performance Site Audits	3-1

Table 3-2. Site Ozone PE Visits	3-3

Table 4-1. Performance Audit Results by Variable Tested	4-2

Table 4-2. Performance Audit Results for Ozone	4-3

Table 4-3. Performance Audit Results Shelter Temperature, and Flow Rate	4-12

Table 4-4. Performance Audit Results for Wind Sensors	4-15

Table 4-5. Performance Audit Results for Temperature and Relative	4-17

Table 4-6. Performance Audit Results for Solar Radiation and Precipitation	4-20

Table 4-7. Performance Audit Results for Data Acquisition Systems	4-21

List of Figures

Figure 4-1. 2017 and 2018 Ozone PE Actual Difference Level 2 Audits Performed by EEMS. 4-8

Figure 4-2. 2019 Ozone PE Actual Difference Level 2 Audits Performed by EEMS	4-8

Figure 4-3. 2019 Actual Difference Level 2 NPAP Audits	4-9

Figure 4-4. 2019 Ozone PE Actual Difference Level 2 Audits Not Performed by EEMS	4-10

location

11

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

List of Acronyms and Abbreviations

% diff	percent difference

A/D	analog to digital converter

AQS	Air Quality System

ARS	Air Resource Specialists, Inc.

ASTM	American Society for Testing and Materials

BLM	Bureau of Land Management

BLM-WSO Bureau of Land Management-Wyoming State Office

CASTNET Clean Air Status and Trends Network

CFR	Code of Federal Regulation

CMAQ	Community Multi-scale Air Quality

DAS	data acquisition system

DC	direct current

DEP	Department of Environmental Protection

deg	degree

DQO	data quality objectives

DVM	digital voltmeter

ECCC	Environment and Climate Change Canada

EEMS	Environmental, Engineering & Measurement Services, Inc.

EPA	U.S. Environmental Protection Agency

ESC	Environmental Systems Corporation

FSAD	Field Site Audit Database

g-cm	gram centimeter

GPS	goblal positioning system

k	kilo (1000)

km	kilometer

lpm	liters per minute

MLM	Multilayer Model

m/s	meters per second

mv	millivolt

NADP	National Atmospheric Deposition Program

NIST	National Institute of Standards and Technology

NOAA	National Oceanic and Atmospheric Administration

NPAP	National Performance Audit Program

NPS	National Park Service

OAQPS	Office of Air Quality Planning and Standards

PE	Performance Evaluation

ppb	parts per billion

ppm	parts per million

location

111

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

PSD	Prevention of Significant Deterioration

QA	quality assurance

QA/QC	quality assurance/quality control

QAPP	Quality Assurance Project Plan

RH	relative humidity

RTD	Resistance Temperature Detector

SJRWMD	Saint John's Water Management District

SLAMS	State or Local Air Monitoring Stations

SOP	standard operating procedure

SRP	standard reference photometer

SSRF	Site Status Report Forms

STP	standard temperature and pressure

TEI	Thermo Environmental Instruments

TTP	Through The Probe

USEPA	U.S. Environmental Protection Agency

USFS	U.S. Forest Service

USNO	United States Naval Observatory

V	volts

VDC	volts direct current

Wood	Wood Environment and Infrastructure Solutions

WRR	World Radiation Reference

location

IV

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

1.0 Introduction

The Clean Air Status and Trends Network (CASTNET) is a national air monitoring program
established in 1988 by the US EPA. Nearly all CASTNET sites measure weekly concentrations of
acidic gases and particles to provide accountability for EPA's emission reduction programs. Most
sites measure ground-level ozone as well as supplemental measurements such as meteorology
and/or other trace gas concentrations.

Ambient concentrations are used to estimate deposition rates of the various pollutants with the
objective of determining relationships between emissions, air quality, deposition, and ecological
effects. In conjunction with other national monitoring networks, CASTNET data are used to
determine the effectiveness of national emissions control programs and to assess temporal trends
and spatial deposition patterns in atmospheric pollutants. CASTNET data are also used for long-
range transport model evaluations and critical loads research.

Historically, CASTNET pollutant flux measurements have been reported as the aggregate product
of weekly measured concentrations and model-estimated deposition velocities. The Multi-layer
Model (MLM) was used to derive deposition velocity estimates from on-site meteorological
parameters, land use types, and site characteristics. In 2011, EPA discontinued meteorological
measurements at most EPA-sponsored CASTNET sites.

Currently, CASTNET pollutant flux estimates are calculated as the aggregate product of weekly
measured chemical concentrations and gridded model-estimated deposition velocities. Total
deposition is assessed using the NADP's Total Deposition Hybrid Method (TDEP; EPA, 2015c;
Schwede and Lear, 2014), which combines data from established ambient monitoring networks and
chemical-transport models. To estimate dry deposition, ambient measurement data from
CASTNET were merged with dry deposition rates and flux output from the Community Multiscale
Air Quality (CMAQ) modeling system. The dry deposition surface is then merged with wet
deposition grids from NADP and the Parameter-elevation Regressions on Independent Slopes
Model (PRISM) to estimate total deposition.

Since 2011 nearly all CASTNET ozone monitors have adhered to the requirements for State or
Local Air Monitoring Stations (SLAMS) as specified by the EPA in 40 CFR Part 58. As such, the
ozone data collected must meet the requirements in 40 CFR Part 58 Appendix A, which defines the
quality assurance (QA) requirements for gaseous pollutant ambient air monitoring. The audits
performed by EEMS under this contract fulfill the requirement for annual performance evaluation
(PE) audits of pollutant monitors in the network. The QA requirements can be found at:
https://www3.epa.gov/ttn/amtic/files/ambient/pm25/qa/APP D%20validation%20template%20ve
rsion%2003 2017 for%20AMTIC%20Rev l.pdf

location

1-1

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

Currently 86 sites at 84 distinct locations measure ground-level ozone concentrations. Annual PE
audit QA data are submitted to the Air Quality System (AQS) database.

As of December 2019, the network is comprised of 95 active rural sampling sites across the United
States and Canada, cooperatively operated by the Environmental Protection Agency (EPA), the
National Park Service (NPS), Bureau of Land Management - Wyoming State Office (BLM-WSO)
and several independent partners. Wood Environment and Infrastructure Solutions (Wood) is
responsible for operating the EPA sponsored sites and Air Resource Specialist, Inc. (ARS) is
responsible for operating the NPS and BLM-WSO sponsored sites.

location

1-2

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

2.0 Project Objectives

The objectives of this project are to establish an independent and unbiased program of performance
and systems audits for all CASTNET sampling sites. Ongoing QA programs are an essential part
of any long-term monitoring network.

Performance audits verify that all reported parameters are consistent with the accuracy goals as
defined in the CASTNET Quality Assurance Project Plan (QAPP). The acceptance criteria have
changed over the years and EEMS relies on the CASTNET contractor to provide updates to the
acceptance criteria. The current criteria are included in Table 2-1.

Due to budgetary necessity, the meteorological measurements were shifted to operating on an as-
funded basis. The meteorological sensors were audited on an as directed basis.

Table 2-1. Performance Audit Challenge and Acceptance Criteria

Sensor

Parameter

Audit Challenge

Acceptance Criteria

Precipitation

Response

10 manual tips

1 DAS count per tip

Precipitation

Accuracy

2 introductions of known
amounts of water

< ±10.0% of input amount

Relative
Humidity

Accuracy

Compared to reference
instrument or standard
solution

<±10.0%

Solar
Radiation

Accuracy

Compared to WRR traceable
standard

< ±10.0% of daytime average

Surface
Wetness

Response

Distilled water spray mist

Positive response

Surface
Wetness

Sensitivity

1% decade resistance

N/A

Shelter
Temperature

Average
Difference

Comparison to RTD at 3
observed points

2 °C

Temperature

Accuracy

Comparison to 3 N1ST
measured baths (~ 0° C,
ambient, ~ full-scale)

<± 0.5° C

location

2-1

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Sensor

Parameter

Audit Challenge

Acceptance Criteria

Delta
Temperature

Accuracy

Comparison to temperature
sensor at same test point

< ± 0.50° C

Wind
Direction

Orientation
Accuracy

Parallel to alignment
rod/crossarm, or sighted to
distant point

< ±5° from degrees true

Wind
Direction

Linearity

Eight cardinal points on test
fixture

< ±5° mean absolute error

Wind
Direction

Response
Threshold

Starting torque tested with
torque gauge

<	10 g-cm Climatronics;

<	20 g-cm R. M. Young

Wind Speed

Accuracy

Shaft rotational speed
generated and measured with
certified synchronous motor

< ±0.5 mps below 5.0 mps input;
< ±5.0% of input at or above 5.0 mps

Wind Speed

Starting
Threshold

Starting torque tested with
torque gauge

<0.5 g-cm

Mass Flow
Controller

Flow Rate

Comparison with Primary
Standard

< ± 5.0% of designated rate

Ozone

Slope

Linear regression of multi-
point test gas concentration
as measured with a certified
transfer standard

0.9000 
-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Planning and Standards (OAQPS) through the annual National Performance Audit Program
(NPAP) training which EEMS attended in October 2019 (see end of Appendix for NPAP training
certifications). EEMS personnel performed the Through-The-Probe (TTP) pollutant monitor audits
following EPA's Quality Assurance Guidance Document - Method Compendium - Field Standard
Operating Procedures (SOP) for the Federal PM2.5 Performance Evaluation Program and NPAP-
TTP Audit Standard Operating Procedures (SOP). All procedures and guidance documents used
to perform these audits can be found at the EPA OAQPS website:
https: //www3. epa. gov/ttn/amtic/npepq a. html

The NPAP is a QA program implemented by the OAQPS to conduct audits of gaseous air pollutant
monitors by standard methods throughout each region of the U.S. The method includes
introduction of National Institute of Standards and Traceability (NIST) traceable audit gases to the
station monitors through the ambient sample inlet, including all filters and fittings. This method
evaluates measurement system accuracy including the entire sample train. The audit gas
concentrations are also measured and verified with an audit analyzer on-site. For gases other than
ozone the audit analyzer is calibrated at the time of the audit.

Performance audits are conducted using standards that are certified as currently traceable to the
NIST or another authoritative organization. All standards are certified annually with the exception
of ozone standards which are verified as level 2 standards at EPA regional labs at least twice per
year.

Site systems audits are intended to provide a qualitative appraisal of the total measurement system.
Site planning, organization, and operation are evaluated to ensure that good Quality
Assurance/Quality Control (QA/QC) practices are being applied. At a minimum the following
audit issues are addressed at each site systems audit:

•	Site locations and configurations match those provided in the CASTNET QAPP.

•	Meteorological instruments are in good physical and operational condition and are sited to
meet EPA ambient monitoring guidelines (EPA-600/4-82-060).

•	Sites are accessible, orderly, and if applicable, compliant with OSHA safety standards.

•	Sampling lines are free of leaks, kinks, visible contamination, weathering, and moisture.

•	Site shelters provide adequate temperature control.

•	All ambient air quality instruments are functional, being operated in the appropriate range,
and the zero air supply desiccant is unsaturated.

•	All instruments are in current calibration.

•	Site documentation (maintenance schedules, on-site SOPs, etc.) is current and log book
records are complete.

location

2-3

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

•	All maintenance and on-site SOPs are performed on schedule.

•	Corrective actions are documented and appropriate for required maintenance/repair
activity.

•	Site operators demonstrate an adequate knowledge and ability to perform required site
activities, including documentation and maintenance activities.

location

2-4

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

3.0 CASTNET Sites Visited in 2019

This report covers the CASTNET sites audited in 2019. Only those variables that were supported
by the CASTNET program were audited. From February through December 2019, EEMS
conducted field performance and systems audits at 59 monitoring sites. Meteorological sensors at
four of the sites were also audited. The locations, sponsor agency and dates of the audits along
with states and EPA Regions are presented in Table 3-1.

Table 3-1. Systems and Performance Site Audits

Site ID

Sponsor
Agency

Site Location

State and EPA
Region

Audit dates

ACA416

NPS

Acadia NP

ME/Rl

9/18/2019

ALC188

EPA

Alabama-Coushatta

TX/R6

2/25/2019

ALH157

EPA

Alhambra

IL/R5

12/16/2019

BAS601

EPA

Basin

WY / R8

8/19/2019

BBE401

NPS

Big Bend NP

TX/R6

2/27/2019

BFT142

EPA

Beaufort

NC/R4

12/17/2019

BUF603

BLM

Buffalo

WY / R8

8/20/2019

BVL130

EPA

Bondville

IL/R5

11/7/2019

BWR139

EPA

Blackwater NWR

MD/R3

11/19/2019

CAD150

EPA

Caddo Valley

AR/R6

4/16/2019

CDR119

EPA

Cedar Creek St. Park

WV/R3

11/12/2019

CDZ171

EPA

Cadiz

KY / R4

12/17/2019

CHC432

NPS

Chaco NHP

NM/R6

8/5/2019

CHE185

EPA

Cherokee Nation

OK/R6

4/15/2019

CKT136

EPA

Crockett

KY / R4

11/11/2019

CND125

EPA

Candor

NC / R4

6/14/2019

CNT169

EPA

Centennial

WY / R8

7/16/2019

CVL151

EPA

Coffeeville

MS/R4

4/13/2019

DCP114

EPA

Deer Creek St. Park

OH/R5

10/24/2019

EGB181

EPA

Egbert

ON

11/12/2019

location

3-1

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Site ID

Sponsor
Agency

Site Location

State and EPA
Region

Audit dates

EVE419

NPS

Everglades NP

FL/R4

3/19/2019

GLR468

NPS

Glacier NP

MT/R8

7/3/2019

GRS420

NPS

Great Smoky Mountains NP

TN/R4

10/7/2019

GTH161

EPA

Gothic

CO/R8

8/6/2019

KIC003

EPA

Kickapoo Res

KS/R7

10/23/2019

KNZ184

EPA

Konza Prairie

KS/R7

10/22/2019

LAV410

NPS

Lassen Volcanic NP

CA/R9

5/7/2019

LRL117

EPA

Laurel Hill St. Park

PA/R3

9/26/2019

MAC426

NPS

Mammoth Cave NP

KY / R4

10/17/2019

MCK131

EPA

Mackville

KY / R4

11/5/2019

MCK231

EPA

Mackville (precision site)

KY / R4

11/5/2019

NEC602

EPA

Newcastle

WY / R8

7/23/2019

NIC001

EPA

Nick's Lake

NY / R2

7/10/2019

OXF122

EPA

Oxford

OH/R5

10/25/2019

PAL190

EPA

Palo Duro

TX/R6

3/1/2019

PAR107

EPA

Parsons

WV/R3

9/25/2019

PED108

EPA

Prince Edward

VA/R3

7/26/2019

PIN414

NPS

Pinnacles NM

CA/R9

5/8/2019

PND165

EPA

Pinedale

WY / R8

7/1/2019

PRK134

EPA

Perkinstown

WI/R5

8/27/2019

QAK172

EPA

Quaker City

OH/R5

11/10/2019

ROM206

EPA

Rocky Mountain NP

CO/R8

6/11/2019

ROM406

NPS

Rocky Mountain NP

CO/R8

6/6/2019

SAN189

EPA

Santee Sioux

NE/R7

10/25/2019

SEK430

NPS

Sequoia NP

CA/R9

5/14/2019

SHE604

BLM

Sheridan

WY / R8

8/20/2019

location

3-2

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Site ID

Sponsor
Agency

Site Location

State and EPA
Region

Audit dates

SHN418

NPS

Shenandoah NP - Big Meadows

VA/R3

10/22/2019

STK138

EPA

Stockton

IL/R5

11/5/2019

THR422

NPS

Theodore Roosevelt NP

ND/R8

7/22/2019

UND002

EPA

Underhill

VT/R1

7/9/2019

VIN140

EPA

Vincennes

IN/R5

11/7/2019

VOY413

NPS

Voyageurs NP

MN/R5

8/29/2019

VPI120

EPA

Horton Station

VA/R3

9/24/2019

WFM105

EPA

White Face Mountain

NY / R2

7/2/2019

WNC429

NPS

Wind Cave NP

SD/R8

7/24/2019

WSP144

EPA

Washington Crossing St. Park

NJ/R2

6/17/2019

YEL408

NPS

Yellowstone NP

WY / R8

7/2/2019

YOS404

NPS

Yosemite NP

CA/R9

5/13/2019

ZI0433

NPS

Zion NP

UT / R8

8/3/2019

In addition to the sites listed in Table 3-1 that were visited for complete systems and performance
audits, the 30 sites listed in Table 3-2 were visited to conduct TTP ozone and other pollutant gas
PE.

Table 3-2. Site Ozone PE Visits

Site ID

Sponsor Agency

Site Location

State and EPA
Region

Audit dates

ABT147

EPA

Abington

CT/Rl

9/25/2019

ANA115

EPA

Ann Arbor

MI/R5

8/22/2019

ARE 128

EPA

Arendtsville

PA/R3

7/24/2019

ASH135

EPA

Ashland

ME/R1

9/19/2019

BEL116

EPA

Beltsville

MD/R3

11/18/2019

CAN407

NPS

Canyonlands NP

UT / R8

8/7/2019

CHA467

NPS

Chiricahua NM

AZ/R9

4/11/2019

location

3-3

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Site ID

Sponsor Agency

Site Location

State and EPA
Region

Audit dates

COW 137

EPA

Coweeta

NC/R4

6/13/2019

CTH110

EPA

Connecticut Hill

NY / R2

7/15/2019

DEN417

NPS

Denali NP

AK / RIO

9/5/2019

DIN431

NPS

Dinosaur NM

UT / R8

8/8/2019

ESP127

EPA

Edgar Evins St. Park

TN/R4

4/28/2019

GAS 153

EPA

Georgia Station

GA/R4

3/26/2019

GRB411

NPS

Great Basin NP

NV/R9

9/16/2019

GRC474

NPS

Grand Canyon NP

AZ/R9

4/9/2019

HOX148

EPA

Hoxeyville

MI/R5

8/23/2019

HWF187

EPA

Huntington Wildlife Forest

NY / R2

7/5/2019

IRL141

EPA

Indian River Lagoon

FL/R4

3/19/2019

KEF112

EPA

Kane Experimental Forest

PA/R3

7/24/2019

MKG113

EPA

M. K. Goddard St. Park

PA/R3

7/25/2019

NPT006

EPA

Nez Perce Tribe

ID/RIO

7/8/2019

PET427

NPS

Petrified Forest NP

AZ/R9

4/8/2019

PNF126

EPA

Cranberry

NC/R4

10/5/2019

PSU106

EPA

Penn State University

PA/R3

7/25/2019

SAL133

EPA

Salamonie Reservoir

IN/R5

5/8/2019

SND152

EPA

Sand Mountain

AL/R4

4/27/2019

SPD111

EPA

Speedwell

TN/R4

11/6/2019

SUM 156

EPA

Sumatra

FL/R4

3/27/2019

UVL124

EPA

Unionville

MI/R5

8/22/2019

WST109

EPA

Woodstock

NH/R1

8/19/2019

location

3-4

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

4.0 Performance Audit Results

This section provides the summarized performance evaluation (audit) results of each variable
challenged at each station visited except for trace gas audit results. CASTNET operates trace gas
monitors at several sites including three sites that are part of the NCORE Network (GRS420,
MAC426, and BVL130). Performance evaluation audits of the CASTNET trace gas monitors were
performed at BVL130, ROM206, PND165, HWF187, GRS420, and PNF126 in 2019. Results of
the NOy, CO, and SO2 monitor audits for those sites have been uploaded to the EPA AQS database
and are not included in this report. All PE results for all monitors were within acceptance limits.
The NOy PE audit was not performed at MAC426 due to site monitor malfunction.

Performance audit results are discussed for each variable in the following sections. Tables are
included to summarize the average and maximum error between the audit challenges and site results
as recorded by the on-site Data Acquisition System (DAS). Linear regression and percent
difference (% diff) calculation results are included where appropriate. Results that are outside the
CASTNET QAPP acceptance criteria are shaded in the tables.

The errors presented in the tables in the following sections are reported as the difference of the
measurement recorded by the DAS and the audit standard. Where appropriate, negative values
indicate readings that were lower than the standard, and positive values indicate readings that were
above the standard value. The results are arranged by audit date. Viewing the results in this order
helps to detect any errors that could have been caused by the degradation or drift of the audit
standards during the year. The audit standards are transported and handled with care, and properly
maintained to help prevent such occurrences. No known problems with the standards were apparent
during the year. All standards were within specifications when re-certified at the end of the year.
Errors for all parameters other than ozone appear to be random and without bias.

The ozone results are sorted by the level 2 photometer standard used for the audit and arranged by
audit date. The audit results obtained by the newest ozone standard (model 49iQPS) indicate a
slight negative trend throughout the year. Ozone audit results in general indicate a slight negative
bias which will be discussed in the following section.

Detailed reports of the field site audits, which contain all test points for each variable at each site,
can be found in the Appendices of each of the 2019 Quarterly reports. The variable specific data
forms included in Appendix A of each quarter's report contain the challenge input values, the output
of the DAS, additional relevant information pertaining to the variable and equipment, and all
available means of identification of the sensors and equipment for each site.

Table 4.1 summarizes the number of test failures by variable tested. All station data are recorded
from the station's primary datalogger.

location

4-1

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Table 4-1. Performance Audit Results by Variable Tested

Variable Tested

Number of Tests

Number of tests
Failed

% Failed

Ozone

80

14

17.5

Flow Rate

57

1

1.8

Shelter Temperature (average)

52

1

1.9

Wind Direction Orientation Average
Error

4

1

25

Orientation Maximum Error

4

2

50

Wind Direction Linearity
Average Error

4

0

0

Linearity Maximum Error

4

0

0

Wind Direction Starting Torque

4

1

25

Wind Speed Low Range
Average Error

3

0

0

Low Range Maximum Error

3

0

0

Wind Speed High Range
Average Error

3

1

33.3

High Range Maximum Error

3

1

33.3

Wind Speed Starting Torque

4

0

0

All Temperature Sensors

58

0

0

Relative Humidity

3

0

0

Solar Radiation

4

0

0

Precipitation

4

0

0

DAS Analog to Digital

33

0

0

location

4-2

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

4.1 Ozone

Eighty ozone performance evaluation audits were performed in 2019. All ozone challenges were
conducted to comply with the OAQPS NPAP-TTP Standard Operating Procedures (SOP) which
can be found at https: //www3. epa. gov/ttn/amtic/npapsop .html. Each ozone monitor was
challenged with ozone-free air and four up-scale concentrations. The ozone test gas concentrations
were measured with aNIST-traceable photometer that was verified as a level 2 standard by USEPA.
The results of the ozone audits were uploaded to the AQS database at the end of each quarter.

Results of all ozone audits performed are included in Table 4-2. Fourteen monitors tested failed
the annual PE with a level 2 test point difference above ±1.5 ppb. These are highlighted in the
table below. The monitors at THR422, ACA416 and WNC429 are not CASTNET monitors, and
are operated by state agencies. It was determined that the monitor at UVL124 required
maintenance.

Some monitors responded low to ozone-free air which may also contribute to low response at the
level 2 audit point.

Table 4-2. Performance Audit Results for Ozone

Site ID

Actual
Difference
for Level 2

Average
(% diff)
for Levels
3, 4 and 6

Maximum
(% diff)
for Levels
3, 4 and 6

Ozone
Slope

Ozone
Intercept

Ozone
Correlation

EEMS
Standard
Number

Date

ALC188

-0.34

-3.2

-4.2

0.96029

0.55012

0.99988

1110

2/25/2019

BBE401

-0.22

-0.6

-0.7

0.99057

0.23958

0.99999

1110

2/27/2019

PAL190

-0.4

-1.2

-1.8

0.99603

-0.33515

0.99999

1110

3/1/2019

PET427

-0.38

-1.3

-2.4

0.98967

-0.11093

0.99997

1110

4/8/2019

GRC474

-0.48

-0.8

-1.6

0.99520

-0.13062

0.99996

1110

4/9/2019

CHA467

-0.37

-1.7

-2.0

0.97661

0.55123

0.99994

1110

4/11/2019

LAV410

-1.28

-4.0

-6.9

0.98111

-0.72695

0.99986

1110

5/7/2019

PIN414

-0.33

0.3

0.7

1.00749

-0.27178

0.99999

1110

5/8/2019

YOS404

-0.6

0.2

-1.2

1.01307

-0.42535

0.99995

1110

5/13/2019

SEK430

-0.59

-3.8

-4.2

0.96157

0.10304

0.99998

1110

5/14/2019

ROM406

-1.86

-4.6

-5.8

0.97271

-1.15458

0.99999

1110

6/6/2019

ROM206

-1.01

-1.3

-3.3

1.00644

-0.90695

0.99996

1110

6/11/2019

PND165

-2.25

-9.5

-13.5

0.95438

-2.08948

0.99964

1110

7/1/2019

location

4-3

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Site ID

Actual
Difference
for Level 2

Average
(% diff)
for Levels
3, 4 and 6

Maximum
(% diff)
for Levels
3, 4 and 6

Ozone
Slope

Ozone
Intercept

Ozone
Correlation

EEMS
Standard
Number

Date

YEL408

-0.31

0.3

0.6

1.00478

-0.1015

0.99999

1110

7/2/2019

GLR468

-0.04

2.5

3.6

1.03800

-0.521

0.99997

1110

7/3/2019

NPT006

-0.42

-0.7

-1.7

1.00136

-0.45783

0.99999

1110

7/8/2019

CNT169

0.39

3.5

4.0

1.03170

0.05684

1

1110

7/16/2019

THR422

-1.7

-6.0

-8.1

0.96757

-1.34024

0.99998

1110

7/22/2019

NEC602

-1.81

-4.8

-6.8

0.97785

-1.07778

0.99981

1110

7/23/2019

WNC429

0.73

-0.5

-1.2

0.97856

1.03205

1

1110

7/24/2019

ZI0433

-0.51

-1.9

-2.0

0.98129

-0.02606

1

1110

8/3/2019

CHC432

-0.3

-0.5

-0.8

0.99233

0.12613

0.99999

1110

8/5/2019

GTH161

-0.05

1.0

1.9

1.01969

-0.35367

0.99998

1110

8/6/2019

CAN407

-1

-4.0

-5.2

0.97119

-0.339

0.99995

1110

8/7/2019

DIN431

-0.75

-2.0

-2.6

0.99070

-0.52028

0.99998

1110

8/8/2019

BAS601

-0.54

-1.2

-3.5

0.99416

-0.21771

0.99981

1110

8/19/2019

DEN417

1.62

5.5

6.6

1.03417

1.35257

0.99995

1110

9/5/2019

GRB411

-0.99

-3.1

-3.9

0.97911

-0.40853

0.99996

1110

9/16/2019

SAN189

-1.45

-3.9

-5.4

0.98555

-1.28329

0.99999

1110

10/25/2019

ALH157

0.19

-0.3

-0.8

0.99500

0.11306

0.99999

1110

12/16/2019

CDZ171

-0.85

-1.3

-3.5

1.01071

-1.10155

0.99997

1110

12/17/2019

IRL141

-1.12

-1.6

-2.6

1.00208

-1.09943

1

1114

3/19/2019

GAS 153

-1.97

-4.6

-6.9

0.98742

-1.85433

1

1114

3/26/2019

SUM 156

-1.64

-1.1

-2.9

1.02263

-2.10227

1

1114

3/27/2019

CVL151

-0.27

-1.2

-2.3

0.98143

0.14908

0.9999

1114

4/13/2019

CHE185

0.18

-0.6

-0.9

0.99049

0.12824

0.99999

1114

4/15/2019

CAD 150

-1.66

-2.5

-3.3

0.98939

-1.43004

0.99988

1114

4/16/2019

SND152

-1.14

-2.8

-3.8

0.99028

-0.99572

1

1114

4/27/2019

ESP127

-0.58

0.0

-0.7

1.01038

-0.61174

1

1114

4/28/2019

SAL133

-0.37

-0.8

-1.6

1.00057

-0.48793

1

1114

5/8/2019

location

4-4

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Site ID

Actual
Difference
for Level 2

Average
(% diff)
for Levels
3, 4 and 6

Maximum
(% diff)
for Levels
3, 4 and 6

Ozone
Slope

Ozone
Intercept

Ozone
Correlation

EEMS
Standard
Number

Date

WSP144

-0.89

-0.1

-1.1

1.01500

-0.94684

1

1114

6/17/2019

HWF187

-0.66

-2.7

-2.8

0.97682

-0.2718

1

1114

7/5/2019

CTH110

-0.83

-4.3

-4.6

0.96273

-0.36734

1

1114

7/15/2019

KEF112

-0.28

-0.5

-1.2

1.00429

-0.46454

1

1114

7/24/2019

MKG113

-1.02

-3.9

-4.2

0.97286

-0.68795

0.99999

1114

7/25/2019

PED108

0.02

-0.9

-1.7

0.99796

-0.29137

0.99999

1114

7/26/2019

CND125

-0.1

-2.3

-2.5

0.97601

0.12496

1

1114

7/31/2019

ANA115

-0.26

0.4

0.8

1.00901

-0.33313

0.99999

1114

8/22/2019

UVL124

-3.54

-9.0

-12.3

0.96589

-3.15365

0.99993

1114

8/22/2019

HOX148

-0.55

-1.8

-2.6

0.99012

-0.37417

1

1114

8/23/2019

PRK134

-2.08

-5.5

-6.9

0.9664

-1.33743

0.99999

1114

8/27/2019

VOY413

-0.47

-0.2

-0.5

1.00464

-0.49771

0.99999

1114

8/29/2019

VPI120

-0.6

-4.0

-4.9

0.96526

-0.04806

0.99996

1114

9/24/2019

PAR107

-1.17

-1.9

-3.3

0.98162

-0.62791

0.99985

1114

9/25/2019

LRL117

-0.99

-2.6

-3.6

0.98045

-0.50137

0.99994

1114

9/26/2019

PNF126

-1.05

-1.0

-2.3

1.00778

-1.06583

1

1114

10/5/2019

GRS420

-0.78

-1.3

-2.0

0.99738

-0.61972

1

1114

10/7/2019

MAC 426

1.86

2.9

5.8

0.98781

2.24646

0.99999

1114

10/17/2019

STK138

-0.53

-2.2

-2.4

0.97775

-0.12925

0.99999

1114

11/5/2019

BVL130

-0.67

-2.6

-2.9

0.97565

-0.11353

1

1114

11/7/2019

BEL116

-0.73

-1.5

-1.8

0.99282

-0.54196

0.99999

1114

11/18/2019

BWR139

-1.39

-4.3

-4.9

0.97304

-1.01079

0.99999

1114

11/19/2019

BFT142

-1.21

-4.3

-5.1

0.96728

-0.58271

1

1114

12/17/2019

COW 137

-1.28

-3.9

-5.6

0.96767

0.17821

0.99958

1115

6/13/2019

ARE 128

-0.78

-2.4

-2.9

0.97944

-0.31014

0.99998

1115

7/24/2019

PSU106

-0.74

-4.1

-4.3

0.95555

0.12622

1

1115

7/25/2019

WST109

-0.81

-3.8

-4.0

0.96271

-0.07811

0.99999

1115

8/19/2019

location

4-5

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Site ID

Actual
Difference
for Level 2

Average
(% diff)
for Levels
3, 4 and 6

Maximum
(% diff)
for Levels
3, 4 and 6

Ozone
Slope

Ozone
Intercept

Ozone
Correlation

EEMS
Standard
Number

Date

ACA416

-0.23

4.6

5.9

1.06837

-1.25419

0.99999

1115

9/18/2019

ASH135

-2.51

-4.2

-5.7

0.99454

-2.50547

0.99993

1115

9/19/2019

ABT147

-0.39

-0.9

-1.3

0.99630

-0.32338

1

1115

9/25/2019

SHN418

-0.6

-2.0

-2.3

0.98595

-0.2997

0.99999

1115

10/22/2019

DCP114

-1.3

-4.4

-4.8

0.96442

-0.53192

0.99999

1115

10/24/2019

OXF122

-1.21

-2.3

-3.3

0.99496

-1.07432

1

1115

10/25/2019

MCK131

-1.4

-2.6

-4.4

0.99511

-1.37691

0.99993

1115

11/5/2019

MCK231

-1.51

-2.3

-3.0

1.00181

-1.68192

0.99994

1115

11/5/2019

SPD111

-1.24

-2.2

-3.6

0.99213

-1.02793

0.99988

1115

11/6/2019

VIN140

-1.01

-1.6

-1.9

0.99069

-0.37885

0.99997

1115

11/7/2019

QAK172

-0.93

-1.4

-3.2

1.00619

-1.01653

0.99999

1115

11/10/2019

CKT136

-2.1

-8.7

-9.2

0.92747

-0.93752

0.99999

1115

11/11/2019

CDR119

-0.5

0.3

1.0

1.01370

-0.6245

0.99999

1115

11/12/2019

4.1.1 Ozone Bias

EEMS is aware of the EPA Technical Assistance Document "Transfer Standards for Calibration of
Air Monitoring Analyzers for Ozone'1 October 2013 which can be found at the AMTIC website:
https://www3.epa.gov/ttn/amtic/files/ambient/qaqc/OzoneTransferStandardGuidance.pdf.

The document provides the rationale for standard photometer designation and the procedures
required to ensure photometer stability. The process involves comparisons to a higher-level
standard (in this case a regional EPA level 1 standard) and multiple comparisons on separate days,
known as "6x6 verification". As described in the document, once the transfer standard comparison
relationship with the level 1 standard has been established and the stability requirements are met,
the actual ozone concentration is calculated by:

1	_

Std. 03 conc. = — (Indicated 03 conc. — /)

Where:

m = average slope
/ = average intercept

location

4-6

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

EEMS used this equation prior to 2017 with a rolling 6x6 average slope and intercept to correct
level 2 standard photometer measurements back to the regional EPA level 1 standard reference
photometer (SRP) for ozone PE audits. Since the technical assistance document also states that if
any adjustments are made to the transfer standard a new 6x6 verification is required, EEMS did not
adjust the physical settings (background and span) of the level 2 standards unless the photometer
did not meet the criteria (+/- 3 %) comparison to the level 1 standard. Thereby only mathematical
corrections were applied to the level 2 standard photometers.

Review of data prior to 2017 indicated that this procedure may have introduced a bias to the
standard since the level 2 standards are only compared to the level 1 SRP two or three times per
year. The rolling 6x6 slope and intercept averages may not have reflected the current relationship
between the level 2 and the level 1 standards. This bias was observed in the data from the 2016
ozone PE audits.

In 2017, EEMS elected to deviate from the EPA Technical Assistance Document and began
correcting the level 2 standard photometer using the most recent verification results rather than the
rolling 6x6 results. All ozone audit standard measurements have been corrected back to the EPA
level 1 standard using most recent slope and intercept relationship to the SRP since 2017.

The remainder of this section will focus on only Level 2 audit results. Data presented includes not
only EEMS audit data, but audit data available in AQS from other audit agencies. Station monitor
response to ozone-free (zero-air) audit gas are not available in AQS. Since EEMS frequently
observes negative responses to zero-air from station monitors, it is likely that the lowest audit
concentrations are impacted. Level 2 audit results provide the lowest concentration data with
enough data points for a cursory comparison, therefore only level 2 audit data are compared.

Figures 4-1 presents annual PE ozone results for Level 2 concentrations performed by EEMS in
2017 and 2018 respectively. As previously stated, beginning in 2017 calculations of standard
values only include the most recent comparison to the SRP (not a rolling 6x6 average) and little if
any bias is evident in the audit results. In 2018 it appears that there may be a slight negative increase
in bias.

location

4-7

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Figure 4-1. 2017 and 2018 Ozone PE Actual Difference Level 2 Audits Performed by EEMS

Actual Difference for Level 2

©



Ffb-JOI7 Ml'-2017 *e









f









J 1
%

i o

~



- \ , .

*•*%* %£ »~* %—
~ ~ •





~ t

* S

• . M .* *

^ t

8

O 4



~





"

-

MB *P< Xll* Mj» XH*

M JUla kl-MIA Auf JIH»

Dale

^11 Ml A All Mill Sip. MIA WfJUlD

Figure 4-2 presents 2019 Level 2 annual PE audit results performed by EEMS. It seems clear that
the negative bias trend has increased from 2018 through 2019.

Figure 4-2. 2019 Ozone PE Actual Difference Level 2 Audits Performed by EEMS

2019 EEMS Level 2 Results

4
3

-3
-4

EEMS has not observed this bias when performing ozone audits for stations that are not part of
CASTNET (see previous annual reports). Although data are not included in this report, the
contractors responsible for calibrations and maintenance of CASTNET ozone monitors have not
reported negative responses to zero-air or bias low audit results. Therefore, as further investigation,
audit data of CASTNET ozone monitors performed by other agencies was obtained from AQS.

location

4-8

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Figure 4-3 presents 2019 NPAP Level 2 audit data. NPAP audits are performed at each CASTNET
site approximately once every three years by each EPA regional laboratory or contractor. NPAP
audit data should be directly comparable to EEMS annual PE audit data since the identical method
is used by NPAP and EEMS field scientists and both NPAP and EEMS use very similar mobile
laboratory systems to perform the audits. Most notably the zero-air generator and dilution systems
are identical. The data were downloaded from AQS but not parsed to determine which regional
mobile lab or agency performed the NPAP audit. Data are not available to indicate the site monitor
response to zero-air. It is most likely that data are obtained from more than one NPAP mobile
laboratory and field scientist. Although not as prominent as EEMS annual PE results, there appears
to be a slight negative bias.

Figure 4-3. 2019 Actual Difference Level 2 NPAP Audits



2019 NPAP Level 2 Results

o







~



CO
Q_

Q_

r o

o

~



1—

LU

-1

~





~







Several state and local agencies perform annual ozone PE at CASTNET stations. Those data were
downloaded from AQS for those audits performed in 2019. Figure 4.4 presents the level 2
concentration audit results. It is unknown what methods and equipment the state and local agencies
use to perform the audits. It is not known if the audits are performed TTP or back-of-the-analyzer
(BOA). Data were not parsed to determine which sites were audited or which agency performed
the audits. No data are available to indicate the station response to zero-air. It appears there is no
bias at the level 2 audit concentration for audits performed by state and local agencies.

location

4-9

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Figure 4-4. 2019 Ozone PE Actual Difference Level 2 Audits Not Performed by EEMS

The data, and observations of monitor response to audit zero-air, indicate that the bias at low
concentrations might be attributed to the negative response to ozone-free audit gas. A likely theory
is that the audit gas is much drier than the ambient air that is being sampled by the monitor prior to
the audit. The moisture contained in the ambient air has likely coated and permeated the sample
lines and filters upstream of the monitor and is slightly impacting the response. This could also
explain why the effect is not observed at sites other than CASTNET, since the sample lines at those
sites are much shorter and usually do not contain a filter at the inlet that is subject to moisture
permeation.

The zero-air generators used by EEMS and NPAP produce very dry air. The audit gas dew point
is most likely much lower than the on-site zero-air system, and the zero-air systems used by the
state and local agencies to generate audit gas. This may be why the EEMS and NPAP results differ
from the automatic on-site checks and audits by local agencies.

EEMS is continuing to investigate the observed bias. Thirty EPA sponsored CASTNET ozone
monitors incorporate an inline Nafion™ dryer to help dry the sample air as it enters the monitor.
The dryer is located near the back of the monitor inside the station shelter and is operated by
vacuum from the dry deposition filter pump. In 2020 EEMS is performing ozone PE with the
vacuum pump engaged and the dryer active. This has not been done in previous years.

A more thorough analysis of this phenomenon could include investigation of correlation with site
humidity and elevation. It is also suspected that on-site calibration methods could contribute to the
impact depending on the flow rate and pressure of the calibration gas generated.

location

4-10

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

4.2	Flow Rate

The controlled flow rate operated by the CASTNET filter pack system was audited at 57 sites in
2019. All flow rates are in standard temperature and pressure (at 25 °C) (STP). A NIST-traceable
dry-piston primary flow rate device was used for the tests. The readings obtained from this primary
standard are the STP flow rate observed, while the DAS flow rate was read from the on-site data
logger. All but one (MAC426) of the flow rate data accuracy results were found to be within the
acceptance limits.

4.3	Shelter Temperature

At each site reporting ozone concentrations to AQS, the hourly average shelter temperature must
be maintained between 20.0 to 30.0 degrees C or per manufacturers specifications if designated to
a wider temperature range. Shelter temperature was audited at 52 of the sites visited. All but two
(CHC432 and ZI0433) of the shelter temperature data accuracy results were found to be within the
acceptance criterion of ± 2 °C. The method consisted of placing the audit standard in close
proximity (in situ) to the shelter temperature sensor and recording either instantaneous observations
of both sensors, or averages from both sensors. A Resistance Temperature Detector (RTD) was
used as the audit standard.

Nearly all of the site sensors were observed to lag behind the audit sensor during the rapid changes
in temperature inside the shelter as the air conditioning or heating cycled on and off. In most
instances the shelter temperature sensors never reached the minimum or maximum temperature
measured with the audit standard. This is not likely to add a large error to the hourly averaged
shelter temperature measurements. However, since the output of the shelter temperature sensors
follow a sine wave curve but the actual shelter temperature does not change following a sine wave
curve, if the shelter temperature is set near the lower or higher allowable limits (20 to 30 degrees
C)1 the actual hourly averages may be lower or higher than those measured by the site sensors.

The shelter temperature and flow rate audit results are summarized in Table 4-3. Flow rate and
shelter temperature data are reported only for the sites that were visited for complete systems and
performance audits.

1 The revised acceptable operating temperature range for Thermo 40/ monitor is 5 to 40 degrees C.

4-11

location

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Table 4-3. Performance Audit Results Shelter Temperature, and Flow Rate

Site ID

Shelter Temp.

Average
Error (C)

Shelter Temp.
Maximum
Error (C)

STP Flow Rate

Primary
Standard (1pm)

STP Flow Rate
Site DAS
(1pm)

Flow Error
(% diff)

Audit date

ALC188

-0.93

-0.96

1.54

1.50

-2.38

2/25/2019

BBE401

0.30

1.08

2.98

3.00

0.67

2/27/2019

PAL190

-0.34

1.99

3.02

3.00

-0.55

3/1/2019

EVE419

-

-

3.02

3.01

-0.44

3/19/2019

CVL151

-0.11

-0.16

1.52

1.50

-1.32

4/13/2019

CHE185

0.14

0.33

1.53

1.50

-1.96

4/15/2019

CAD 150

0.27

0.31

1.52

1.50

-1.32

4/16/2019

LAV410

-0.05

-1.75

3.02

3.01

-0.22

5/7/2019

PIN414

0.11

0.74

2.97

3.01

1.23

5/8/2019

YOS404

1.61

2.31

3.00

3.00

-0.33

5/13/2019

SEK430

0.29

0.46

3.04

3.01

-1.10

5/14/2019

ROM406

2.00

2.98

3.00

2.95

-1.66

6/6/2019

ROM206

0.97

1.49

3.04

3.00

-1.31

6/11/2019

CND125

1.03

1.13

1.50

1.50

-0.22

6/14/2019

WSP144

-0.05

0.31

1.49

1.50

0.45

6/17/2019

PND165

-0.60

-1.14

3.04

3.00

-1.21

7/1/2019

WFM105

-

-

2.96

3.00

1.47

7/2/2019

WNC429

0.82

1.13

2.99

3.08

3.12

7/2/2019

YEL408

-0.08

1.17

2.98

3.00

0.54

7/2/2019

GLR468

-0.99

-1.09

3.01

3.00

-0.33

7/3/2019

UND002

-

-

3.04

3.00

-1.21

7/9/2019

NIC001

-

-

3.00

3.00

-0.11

7/10/2019

CNT169

-0.13

-0.41

3.02

2.99

-0.77

7/16/2019

THR422

1.70

2.1

3.05

3.07

0.77

7/22/2019

NEC602

0.88

1.06

3.12

3.00

-3.64

7/23/2019

PED108

0.55

1.47

1.47

1.50

2.04

7/26/2019

ZI0433

2.4

3.44

-

-

-

8/3/2019

CHC432

2.32

2.88

-

-

-

8/5/2019

GTH161

0.04

0.13

3.04

3.01

-1.10

8/6/2019

location

4-12

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Site ID

Shelter Temp.

Average
Error (C)

Shelter Temp.
Maximum
Error (C)

STP Flow Rate

Primary
Standard (1pm)

STP Flow Rate
Site DAS
(1pm)

Flow Error
(% diff)

Audit date

BAS601

0.43

0.45

3.04

3.00

-1.42

8/19/2019

BUF603

--

-

2.92

3.00

2.86

8/20/2019

SHE604

--

-

3.03

3.11

2.88

8/20/2019

PRK134

-0.26

-0.28

1.49

1.50

0.90

8/27/2019

VOY413

0.18

0.28

2.99

3.00

0.22

8/29/2019

ACA416

1.83

2.1

1.53

1.52

-0.44

9/18/2019

VPI120

0.72

0.87

1.50

1.50

0.00

9/24/2019

PAR107

0.17

0.61

1.54

1.51

-2.16

9/25/2019

LRL117

-0.08

-0.94

1.50

1.49

-0.45

9/26/2019

GRS420

0.15

0.35

2.92

3.00

2.62

10/7/2019

MAC426

-0.06

0.53

1.59

1.51

-5.03

10/17/2019

KNZ184

0.10

1.23

2.99

2.99

-0.11

10/22/2019

SHN418

-0.04

-0.06

1.52

1.50

-1.53

10/22/2019

KIC003

-

-

2.98

2.99

0.45

10/23/2019

DCP114

1.32

1.42

1.53

1.50

-2.17

10/24/2019

OXF122

0.09

0.46

1.51

1.50

-0.88

10/25/2019

SAN189

-0.03

0.42

2.98

3.00

0.78

10/25/2019

MCK131

0.00

0.30

1.55

1.51

-3.00

11/5/2019

MCK231

0.56

0.98

1.54

1.51

-2.16

11/5/2019

STK138

-0.67

-0.8

1.43

1.50

4.65

11/5/2019

BVL130

0.08

0.28

1.51

1.50

-0.88

11/7/2019

VIN140

-0.17

-0.98

1.53

1.50

-1.96

11/7/2019

QAK172

0.59

0.80

1.49

1.50

0.67

11/10/2019

CKT136

1.07

1.12

1.50

1.50

-0.22

11/11/2019

CDR119

0.71

0.9

1.51

1.50

-0.66

11/12/2019

EGB181

-0.55

-0.56

1.47

1.49

1.36

11/12/2019

BWR139

0.49

0.61

1.54

1.50

-2.39

11/19/2019

ALH157

-0.41

-0.67

1.48

1.50

1.35

12/16/2019

BFT142

0.09

0.20

1.49

1.49

0.22

12/17/2019

CDZ171

-0.02

-1.04

1.54

1.50

-2.39

12/17/2019

location

4-13

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

4.4	Wind Speed

The wind speed sensors at three sites (only low speed tested at BVL130) equipped for
meteorological measurements were audited. The wind speed data accuracy results at ACA416 were
above the acceptance limit. The results of the wind speed performance audits are presented in
Table 4-4. The state of Maine operates the meteorological sensors at ACA416. Audits in previous
years have indicated similar results. The sensor appears to be accurate up to speeds above 20 m/s
(over 45 mph) and then fails at higher speeds. It is likely that the sensor is not tested by the state
at high wind speeds and this is not a concern.

4.4.1 Wind Speed Starting Threshold

The condition of the wind speed bearings was evaluated as part of the performance audits. The
data acceptance criterion for wind speed bearing torque is not defined in the QAPP. However,
Appendix 1: CASTNET Field Standard Operating Procedures, states that the wind speed bearing
torque should be < 0.2 g-cm. To establish the wind speed bearing torque criterion for audit purposes
the rational described in the QAPP measurement criteria was applied. The QAPP states that field
criteria are more stringent than DQO and established to maintain the system within DQO.
Typically, field measurement criteria are set at approximately one-half the DQO. Therefore, 0.5 g-
cm was used for the acceptance limit for audit purposes. This value is within the manufacturers'
specifications for a properly maintained system.

4.5	Wind Direction

Two separate tests were performed to evaluate the accuracy of each wind direction sensor:

•	A linearity test was performed to evaluate the ability of the sensor to function properly and
accurately throughout the range from 1 to 360 degrees. This test evaluates the sensor
independently of orientation and can be performed with the sensor mounted on a test
fixture.

•	An orientation test was used to determine if the sensor was aligned properly when installed
to measure wind direction accurately in degrees true. An audit standard compass was used
to perform the orientation tests.

The results of the wind direction performance audits are presented in Table 4-4. The average errors
for all sensors were within the acceptance limits or the linearity test. The average errors for all
sensors except ZI0433 were within the acceptance limits or the orientation test.

4.5.1 Wind Direction Starting Threshold

The condition of the wind direction bearings were evaluated as part of the performance audits. The
data acceptance criterion for wind direction bearing torque is not defined in the QAPP. However,

location

4-14

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Appendix 1: CASTNET Field Standard Operating Procedures, states that the wind direction
bearing torque should be < 10 g-cm for R. M. Young sensors. The manufacturer states that a
properly maintained sensor will be accurate up to a starting threshold of 11 g-cm. To establish the
wind direction bearing torque criterion for audit purposes the rational described in the QAPP
measurement criteria was applied. The QAPP states that field criteria are more stringent than DQO
and established to maintain the system within DQO. Typically, field criteria are set to
approximately one-half the DQO. For audit purposes 20 g-cm was used for the acceptance limit
for R. M. Young sensors. Climatronics sensors typically have a lower starting torque. For audit
purposes a threshold of 10 g-cm was selected for Climatronics sensors. The sensor at ACA416
tested outside of acceptance limits for wind direction starting threshold. The test results are
provided in Table 4-4.

Table 4-4. Performance Audit Results for Wind Sensors

Site ID

Wind Direction

Wind Speed

Orientation Error

Linearity Error

Starting
Torque
(g-cm)

Low Range Error

High Range Error

Starting
Torque

(g-cm)

Ave
(deg)

Max
(deg)

Ave
(deg)

Max
(deg)

Ave
(rn/s)

Max
(rn/s)

Ave
(% diff)

Max
(% diff)

ACA416

-3.8

-5.2

1.78

3.2

11.5

-0.08

-0.21

-7.0

-25.67

0.45

BVL130

0.3

-2

1.0

2.0

14

-0.07

-0.20

NP

NP

0.4

CHC432

-1.4

-3.2

1.73

4.4

10

-0.05

-0.20

0.10

0.20

0.3

ZI0433

-9.5

-12

1.35

2.9

15

-0.05

-0.20

0.0

0.0

0.3

* Note: The wind systems acceptance criteria were applied to the average of the results. The data validation section of the
CASTNET QAPP states that if any wmd direction or wind speed challenge result is outside the acceptance criterion the variable
is flagged. (NP = not performed)

4.6 Temperature and Two-Meter Temperature

The EPA sponsored site temperature measurement systems consist of a temperature sensor
mounted on a tower approximately 9 meters above ground-level. Sites operated by the Park Service
have moved the temperature sensors to approximately two meters above the ground (2-meter
temperature).

The BLM has recently upgraded the temperature sensors at their sites to submersible RTD sensors.
However, the sensor operating at NPS sponsored CHC432 site, is a combined relative humidity
and temperature sensor and not standalone RTD or encased thermistor temperature sensor. Due to
the design of the RH/Temperature sensor, it cannot be submerged in water baths to challenge the
sensor at different temperature audit levels. For that reason, the combination RH/Temperature
sensor was audited by placing the sensor in a watertight chamber (RH salt chamber) and then
placing the chamber in an ice-water bath, ambient bath, and hot water bath. Therefore, the

location

4-15

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

temperature audit results for site CHC432 are not directly comparable to audit results of RTD or
encased thermistor sensors, and not reported.

All sites use shields to house the sensors that are either mechanically aspirated with forced air, or
naturally aspirated. In all cases the sensors were removed from the sensor shields and placed in a
uniform temperature bath with a precision NIST-traceable RTD, during the audit.

A total of 58 temperature sensors were tested, and all were found to be within the acceptance
criterion. It should be noted that one of those sensors (CHC432) is a combination RH/Temperature
sensor as described above and cannot be submersed in a water-bath. The average errors for all
sensors are presented in Table 4-5.

4.6.1 Temperature Shield Blower Motors

All fourteen of the temperature systems with sensor shield blower motors (forced-air aspiration)
encountered during the site audits conducted during 2019 were found to be functioning.

4.7 Relative Humidity

The three relative humidity systems that were audited were tested with a combination of primary
standard salt solutions, and aNIST traceable transfer standard relative humidity probe. The results
of the average and maximum errors throughout the measurement range of approximately 30% to
95% are presented in Table 4-5. All humidity sensors were within the acceptable limits.

As in previous years, operation of both temperature and humidity sensors with respect to natural or
forced-air aspiration can vary between sites. At most EPA sponsored sites temperature and
humidity sensors are operating in naturally aspirated shields. At most NPS sponsored sites
temperature and humidity sensors are operating in shields designed to be mechanically aspirated
with forced-air blowers.

During humidity audit tests with the primary standard salt solutions, the sensors were removed
from the shields and placed in a temperature-controlled enclosure. During audit tests with the
transfer standard probe, the sensor and transfer were placed in the same ambient conditions.
Therefore, the audit tests do not account for differences in the operation of the sensors due to the
different shield configurations.

location

4-16

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Table 4-5. Performance Audit Results for Temperature and Relative

Audit Date

Site ID

9-meter
Temperature
Ave. Error

(degC)

2-Meter
Temperature
Ave. Error

(degC)

Relative Humidity

Range 0 -100%

Ave. Error

(%)

Max. Error

(%)

2/25/2019

ALC188

-0.26

-

-

-

2/27/2019

BBE401

--

0.26

-

-

3/1/2019

PAL190

-0.03

-

-

-

4/13/2019

CVL151

-0.05

-

-

-

4/15/2019

CHE185

-0.33

-

-

-

4/16/2019

CAD 150

-0.05

-

-

-

5/7/2019

LAV410

-

-0.05

-

-

5/8/2019

PIN414

-

-0.15

-

-

5/13/2019

YOS404

-

-0.15

-

-

5/14/2019

SEK430

-

-0.23

-

-

6/6/2019

ROM406

-

0.22

-

-

6/11/2019

ROM206

-0.10

-

-

-

6/14/2019

CND125

0.32

-

-

-

6/17/2019

WSP144

-0.11

-

-

-

7/1/2019

PND165

-0.04

-

-

-

7/2/2019

WFM105

0.12

-

-

-

7/2/2019

YEL408

-

-0.29

-

-

7/3/2019

GLR468

-

0.23

-

-

7/9/2019

UND002

0.06

-

-

-

7/10/2019

NIC001

0.00

-

-

-

7/16/2019

CNT169

0.05

-

-

-

7/22/2019

THR422

-

0.04

-

-

7/23/2019

NEC602

-

0.09

-

-

7/24/2019

WNC429

-

0.11

-

-

7/26/2019

PED108

-0.13

-

-

-

location

4-17

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Audit Date

Site ID

9-meter
Temperature
Ave. Error

(degC)

2-Meter
Temperature
Ave. Error

(degC)

Relative Humidity

Range 0 -100%

Ave. Error

(%)

Max. Error

(%)

8/3/2019

ZI0433

--

0.30

-

-

8/5/2019

CHC432

--

-

-1.81

-2.7

8/6/2019

GTH161

0.09

-

-

-

8/19/2019

BAS601

--

0.12

-

-

8/20/2019

BUF603

--

0.08

-

-

8/20/2019

SHE604

--

0.07

-

-

8/27/2019

PRK134

-0.07

-

-

-

8/29/2019

VOY413

--

-0.37

-

-

9/18/2019

ACA416

--

0.10

-0.79

-2.2

9/24/2019

VPI120

-0.01

-

-

-

9/25/2019

PAR107

-0.19

-

-

-

9/26/2019

LRL117

-0.04

-

-

-

10/7/2019

GRS420

-

0.01

-

-

10/17/2019

MAC426

-

0.18

-

-

10/22/2019

KNZ184

-0.13

-

-

-

10/22/2019

SHN418

-

0.11

-

-

10/23/2019

KIC003

0.08

-

-

-

10/24/2019

DCP114

0.07

-

-

-

10/25/2019

OXF122

0.33

-

-

-

10/25/2019

SAN189

-0.06

-

-

-

11/5/2019

MCK131

0.05

-

-

-

11/5/2019

MCK231

-0.20

-

-

-

11/5/2019

STK138

-0.01

-

-

-

11/7/2019

BVL130

-0.08

0.03

0.53

3.1

11/7/2019

VIN140

0.05

-

-

-

11/10/2019

QAK172

0.17

-

-

-

location

4-18

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Audit Date

Site ID

9-meter
Temperature
Ave. Error

(degC)

2-Meter
Temperature
Ave. Error

(degC)

Relative Humidity

Range 0 -100%

Ave. Error

(%)

Max. Error

(%)

11/11/2019

CKT136

0.28

-

-

-

11/12/2019

CDR119

0.07

-

-

-

11/12/2019

EGB181

-0.10

-

-

-

11/19/2019

BWR139

0.10

-

-

-

12/16/2019

ALH157

-0.03

-

-

-

12/17/2019

BFT142

0.08

-

-

-

12/17/2019

CDZ171

-0.08

-

-

-

4.8	Solar Radiation

The ambient conditions encountered during the audit visits were suitable (high enough light levels)
for accurate comparisons of solar radiation measurements. A World Radiation Reference (WRR)
traceable Eppley PSP radiometer and translator or a model 8-48 were used as the audit standard
system.

Three sites were tested. All sites had daytime average results that were within the acceptance
criterion. The results of the individual tests for each site are included in Table 4-6. The percent
difference of the maximum single-hour average solar radiation value observed during each site
audit is also reported in Table 4-6 although this criterion is not part of the CASTNET data quality
indicators. All maximum values were also within ±10%.

4.9	Precipitation

The four sites audited used a tipping bucket rain gauge for obtaining precipitation measurement
data. The audit challenges consisted of entering multiple amounts of a known volume of water into
the tipping bucket funnel at a rate equal to approximately 2 inches of rain per hour. Equivalent
amounts of water entered were compared to the amount recorded by the DAS. The results are
summarized in Tables 4-6. All sensors were within the acceptance criteria.

location

4-19

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Table 4-6. Performance Audit Results for Solar Radiation and Precipitation

Site ID

Solar Radiation Error

Precipitation
Ave. Error
(% diff)

Daytime Ave.
(% diff)

Std. Max.
Value (w/m2)

Site Max.
Observed
(w/m2)

Max. Value
(% diff)

ACA416

--

-

-

-

-2.0

BVL130

7.5

481

523

8.7

2.0

CHC432

-1.6

991

963

-3.4

-0.9

ZI0433

-0.8

791

794

-2.3

-0.1

4.10 Data Acquisition Systems (DAS)

All of the NPS sponsored sites visited utilized an ESC logger as the primary and only DAS. All
EPA sites visited operated Campbell Scientific loggers as their only DAS. The results presented
in table 4-7 include the tests performed on the logger at each site. The BLM sites utilize a Campbell
Scientific CR1000. The CR1000 and some of the other loggers encountered are not configured to
allow analog tests.

4.10.1	Analog Test

The accuracy of each logger was tested on two different channels (if two channels were available
to be used) with aNIST-traceable Fluke digital voltmeter. At the EPA sponsored sites the channels
above analog channel 8 could not be tested since there were no empty channels available to test.
All data loggers were within the acceptance criterion of ± 0.003 volts.

4.10.2	Functionality Tests

Other performance tests used to evaluate the DAS included the verification of the date and time.
All site data loggers were found to be set to the correct date and within ±5 minutes per the
acceptance criterion for time except for EGB181. The NPS sponsored site data loggers were found
to be set to the correct date and within ±5 minutes of the acceptance criterion for time. However,
most of the NPS clocks were found to be 1 to 3 minutes different than the standard, whereas the
EPA sponsored site clocks were all within 2-3 seconds. The Campbell Scientific logger clocks at
the EPA sites are synchronized with the internet, whereas the ESC loggers at the NPS sites are not.

location

4-20

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Table 4-7. Performance Audit Results for Data Acquisition Systems

Audit
Date

Site ID

Analog Test Error (volts)

Date
Correct

(Y/N)

Time
Error
(minutes)

Low Channel

High Channel

Average

Maximum

Average

Maximum

2/25/2019

ALC188

0.0001

0.0004

-

-

Y

0.00

2/27/2019

BBE401

--

-

0.0000

-0.0003

Y

-1.85

3/1/2019

PAL190

0.0001

0.0002

-

-

Y

-1.00

3/19/2019

EVE419

0.0000

0.0002

-

-

Y

-1.72

4/13/2019

CVL151

-0.0001

-0.0002

-

-

Y

0.00

4/15/2019

CHE185

-0.0020

-0.0030

-

-

Y

-0.15

4/16/2019

CAD150

0.0000

-0.0001

-

-

Y

0.00

5/7/2019

LAV410

-

-

-0.0001

-0.0004

Y

1.45

5/8/2019

PIN414

-

-

0.0002

0.0005

Y

-0.95

5/13/2019

YOS404

-0.0001

-0.0003

-

-

Y

0.92

5/14/2019

SEK430

-

-

0.0003

0.0008

Y

1.90

6/6/2019

ROM406

-

-

-

-

Y

-1.25

6/11/2019

ROM206

-0.0002

-0.0005

-

-

Y

0.00

6/14/2019

CND125

-0.0001

-0.0001

-

-

Y

0.02

6/17/2019

WSP144

-0.0001

-0.0002

-

-

Y

-0.08

7/1/2019

PND165

-0.0001

-0.0004

-

-

Y

-0.05

7/2/2019

YEL408

0.0000

-0.0004

-

-

Y

-0.08

7/3/2019

GLR468

-

-

-0.0001

-0.0005

Y

-0.67

7/16/2019

CNT169

-0.0001

-0.0003

-

-

Y

0.08

7/22/2019

THR422

-

-

0.0002

0.0004

Y

1.10

7/24/2019

WNC429

-0.0001

-0.0003

-

-

Y

-1.67

7/26/2019

PED108

-0.0001

-0.0003

-

-

Y

0.00

8/3/2019

ZI0433

-0.0002

-0.0003

-

-

Y

-0.75

8/5/2019

CHC432

0.0003

0.0007

-

-

Y

0.95

8/6/2019

GTH161

-0.0002

-0.0010

-

-

Y

0.00

8/27/2019

PRK134

0.0000

-0.0001

-

-

Y

0.03

8/29/2019

VOY413

0.0000

0.0001

-

-

Y

1.83

location

4-21

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

Audit
Date

Site ID

Analog Test Error (volts)

Date
Correct

(Y/N)

Time
Error
(minutes)

Low Channel

High Channel

Average

Maximum

Average

Maximum

9/18/2019

ACA416

--

-

-0.0006

-0.0019

Y

-0.17

9/24/2019

VPI120

0.0000

0.0001

-

-

Y

0.00

9/25/2019

PAR 107

0.0000

-0.0001

-

-

Y

0.00

9/26/2019

LRL117

0.0000

0.0001

-

-

Y

0.00

10/7/2019

GRS420

-0.0001

-0.0002

-

-

Y

-0.13

10/17/2019

MAC426

0.0000

0.0001

-

-

Y

-0.73

10/22/2019

KNZ184

0.0000

0.0003

-

-

Y

-0.08

10/24/2019

DCP114

0.0000

-0.0001

-

-

Y

0.00

10/25/2019

OXF122

-0.0001

-0.0001

-

-

Y

0.00

10/25/2019

SAN 189

0.0001

0.0003

-

-

Y

0.00

11/5/2019

MCK131

0.0000

0.0000

-

-

Y

0.00

11/5/2019

MCK231

0.0000

0.0000

-

-

Y

0.00

11/5/2019

STK138

0.0001

0.0002

-

-

Y

0.00

11/7/2019

BVL130

0.0002

0.0003

-

-

Y

0.00

11/7/2019

VIN140

0.0000

0.0001

-

-

Y

0.00

11/10/2019

QAK172

0.0000

-0.0001

-

-

Y

0.03

11/11/2019

CKT136

-0.0001

-0.0001

-

-

Y

0.00

11/12/2019

CDR119

0.0000

-0.0001

-

-

Y

-0.02

11/12/2019

EGB181

-0.0001

-0.0002

-

-

Y

5.75

11/19/2019

BWR139

0.0000

0.0001

-

-

Y

-1.00

12/16/2019

ALH157

0.0000

0.0002

-

-

Y

0.00

12/17/2019

BFT142

0.0000

0.0001

-

-

Y

-0.05

12/17/2019

CDZ171

0.0001

0.0002

-

-

Y

-0.03

location

4-22

EEAlS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

5.0 Systems Audit Results

The following sections summarize the site systems audit findings and provide information observed
regarding the measurement processes at the sites. Conditions that directly affect data accuracy have
been reported in the previous sections. Other conditions that affect data quality and improvements
to some measurement systems or procedures are suggested in the following sections.

5.1	Siting Criteria

All of the sites that were visited have undergone changes during the period of site operation which
include population growth, road construction, and foresting activities. None of those changes were
determined to have a significant impact on the siting criteria that did not exist when the site was
initially established.

Some sites that are located in state and national parks are not in open areas and have trees within
the 50 meter criterion established in the QAPP. Given the land use and aesthetic concerns, these
sites are acceptable and represent an adequate compromise with regard to siting criteria and the
goal of long-term monitoring. For sites that measure ozone data designated as NAAQS compliant,
these sites may violate recommended siting criteria in 40 CFR Part 58.

The CASTNET QAPP is currently being revised to more closely follow 40 CFR Part 58 Appendix
E. The audit program will incorporate those changes when they are implemented beginning with
audits in 2020.

5.2	Sample Inlets

Based on the siting criteria information provided in the CASTNET QAPP, with consideration given
to the siting criteria compromises described in the previous section, all but four sites (LAV410,
YEL408, VOY413, and CDR119) visited in 2019 have ozone monitor sample trains that are sited
properly and in accordance with the CASTNET QAPP. All ozone sample inlets are currently being
evaluated with respect to obstructions above the inlet. The acceptance criterion requires that there
should be no obstructions (including trees) within a 26.6 degree angle (object distance must be at
least two times the height) above the ozone inlet. There are trees that violate the 26.6 degree sample
inlet requirement at the four sites listed above.

All but two CASTNET ozone monitors have sample inlet heights at 10 meters the exceptions are
WNC429 at 3.35 meters and THR422 at 12.2 meters. With the exception of the state operated
sites (WNC429 and THE422), the ozone zero, span, and precision calibration test gases are
introduced at the ozone sample inlet, through all filters and the entire sample train. All sample

location

5-1

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

trains are comprised of only Teflon or Kynar fittings and materials. Sample inlet particulate filters
of 5 micron are present at most sites.

The dry deposition filter packs are designed to sample from a height of 10 meters. Most of the
filter pack sample lines are also Teflon. Inline filters are present in the sample trains to prevent
moisture and particulates from damaging the flow rate controller. A few sites were configured with
the dry deposition filter face below the edge of the rain shield enclosure. This may impact the size
of the particles collected on the filter. The standard CASTNET configuration is the filter face must
not extend below the edge of the enclosure.

5.3	Infrastructure

Sites continue to be improved by repairing the site shelters which had deteriorated throughout the
years of operation. A few of the site shelters are still in need of repair, but overall, the condition of
the sites has improved again during the past year. Wi-Fi routers with improved internet service
have been installed at most sites.

5.4	Site Operators

Generally the site operators are very conscientious and eager to complete the site activities
correctly. They are willing to, and have performed sensor replacements and repairs at the sites with
support provided by the Wood and ARS field operations centers. In some cases, where
replacements or repairs were made, documentation of the activities was not complete, and did not
include serial numbers of the removed and installed equipment.

Many of the CASTNET site operators also perform site operator duties for the National
Atmospheric Deposition Program (NADP). Many of the NPS site operators also perform other air,
or environmental quality functions within their park. All are a valuable resource for the program.

Still many of the site operators have not been formally trained to perform the CASTNET duties by
either Wood or ARS. They had been given instructions by the previous site operators and over the
phone instructions from the field operation centers at Wood and ARS.

5.5	Documentation

The NPS site operator procedures are well developed and readily accessible at all of the NPS sites
visited. There is an electronic interface (DataView 2) available to view, analyze, and print site
data. There are electronic "checklists" for the site operator to complete during the site visits;
however, all of the CASTNET filter pack procedures are not included in the "checklists". Flow
rates and leak check results are not recorded electronically.

location

5-2

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

An electronic logbook is included in the interface software. This system permits easy access to site
documentation data. Complete calibration reports have been added to the system and accessible
through the site computer, however the reports available on-site are not up to date.

5.6 Site Sensor and FSAD Identification

Continued improvement has also been made in the area of documentation of sensors and systems
used at the sites. It is important to maintain proper sensor identification for the purposes of site
inventory and to properly identify operational sensors for data validation procedures. Many sensors
have had new numbers affixed for proper identification.

Where possible the identification numbers assigned (serial numbers and barcodes) are used within
the field site audit database for all the sensors encountered during the site audits. The records are
used for both the performance and systems audits. If a sensor is not assigned a serial number by
the manufacturer, that field is entered as "none". If it is unknown whether an additional client ID
number is assigned to a sensor, and a number is not found, the client ID is also entered as "none".
If it is typical for a manufacturer and/or client ID number to be assigned to a sensor, and that number
is not present, the field is entered as "missing". If either the serial number or the client ID numbers
cannot be read, the field is entered as "illegible". An auto-number field is assigned to each sensor
in the database in order to make the records unique.

location

5-3

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP-W-18-005

USEPA
October 2020

6.0 Summary and Recommendations

The CASTNET Site Audit Program has been successful in evaluating the field operations of the
sites. The results of performance and systems audits are recorded and archived in a relational
database, the Field Site Audit Database (FSAD). CASTNET site operations are generally
acceptable and continue to improve. Some differences between actual site operations and
operations described in the QAPP have been identified and described. Procedural differences
between EPA and NPS sponsored sites have also been described.

As discussed previously the shelters have received some much needed attention. It was also
observed that improvements were made to the shelter temperature control systems. As a
requirement in 40 CFR Part 58 for ozone monitoring, shelter temperature is an important variable.
Additional improvement could be made to accurately measure and report shelter temperature.

The previous paragraphs and sections included some recommendations for improving the field
operations systems. One recommendation for improving the audit program is presented in the
following section.

6.1 In Situ Comparisons

An improvement to the audit procedures designed to evaluate the differences in measurement
technique would be to develop an "In Situ" audit measurement system. This would require a suite
of sensors that would be collocated with the site sensors. Ideally the audit sensors would address
the inconsistent sensor installations observed throughout the network. By deploying a suite of
certified NIST traceable sensors installed and operating as recommended by the manufacturer and
to EPA guidelines, subtle differences in the operation of the existing CASTNET measurement
systems could be evaluated. The "In Situ" sensors would be operated at each site for a 24 hour
period and the measurements would be compared to the CASTNET measurements. A portable
system of meteorological sensors would be beneficial for meteorological measurement evaluations
particularly at BLM sponsored sites. EEMS is still pursuing this type of audit system.

location

6-1

EEMS/transfer/clients/EPA


-------
2019 Annual Report — CASTNET
Contract No. EP- W-18- 005

USEPA
October 2020

7.0 References

Office of Air Quality and Planning Standards AMTIC website, SOP and guidance
documents: www.epa.gov/ttn/amtic/

Quality Assurance Handbook for Air Pollution Measurement Systems: Volume II - Ambient Air
Specific Methods - EPA.

Quality Assurance Handbook for Air Pollution Measurement Systems: Volume IV -
Meteorological Measurements - EPA.

Clean Air Status and Trends Network (CASTNET) Quality Assurance Project Plan (2003) -
EPA.

Quality Assurance Handbook for Air Pollution Measurement Systems: Volume I: - A Field
Guide To Environmental Quality Assurance - EPA.

Quality Assurance Handbook for Air Pollution Measurement Systems: Volume II: Parti
Ambient Air Quality Monitoring Program Quality System Development - EPA.

Sensitivity of the National Oceanic and Atmospheric Administration multilayer model to
instrument error and parameterization uncertainty: Journal of Geophysical Research, Vol. 105.
No. D5, March 16, 2000.

Wind System Calibration, Recommended Calibration Interval, Procedure, and Test Equipment:
November 1999, R. M. Young Company

Bowker, G.E., Schwede, D.B.; lear, G.G.; Warren-Hicks, W.J., and Finkelstein, P.L., 2011.
Quality assurance decisions with air models: a case study of imputation of missing input data
using EPA multi-layer model. Water, Air, and Soil Pollution 222, 391e402.

Schwede, D., & lear, G.C. (2014). A novel hybrid approach for estimating total deposition in the
United States. Atmospheric Environment, 92, 207-220.

location

7-1

EEAlS/transfer/clients/EPA


-------
APPENDIX 1
Audit Standards Certifications


-------
Certificate Number
A3079040
Issue Date: 01/23/19

Certificate	of

Page 1 of 2

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES
1128 NW 39TH DRIVE
GAINESVILLE, FL 32605
FEDEX

P.O. Number:

ID Numbe
III! IIII llll

Description: DIGITAL STIK THERMOMETER

Manufacturer: FLUKE

Model Number: 1551A EX

Serial Number: 2085085

Technician: STEVE TORRES

On-Site Calibration: ~

Comments: TUR is 2 to 1

Calibration Da
Calibration Du

Procedure:

01/23/2019
01/23/2020 ,,
FLUKE"T§51A EX.52A EX
Rev: 11/1/2010
Temperature:	71 F

Humidity:	43 % RH

As Found Condition: IN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute:! 	_				"			

This Instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (NIST) or other National
Metro logical Institute (NMI). The method of calibration is direct comparison to a known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainly values at an approximately 95% confidence level using a coverage factor of k=2 Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement.

TMl's Quality System is accredited to ISO/IEC 17025:2017 and ANSl/NCSL Z540-1-1994. ISO/IEC 17025:2017 is written in a language relevant to laboratory
operations, meeting the principles of ISO 9001 and aligned with Its pertinent requirements. This calibration complies with all the requirements of ANSI/NCSL Z540-1-
1994 and TMl's Quality Manual, QM-1.

Results contained in this document relate only to the item calibrated. Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do not imply continued conformance to specifications

This certificate shall not be reproduced, except In full, without the written permission of Technical Maintenance, Inc.

Measurements not currently on TMl's Scope of Accreditation are identified with an asterisk.

FRANK BAHMANN, BRANCH MANAGER	Scott Chamberlain, QUALITY MANAGER

Calibration Standards

Asset Number Manufacturer Model Number	Date Calibrated	Cal Due

05535 FLUKE 5609-12-D	7/3/2018	7/3/2019

660TL18010015

ADDITEL

ADT875PC-155

6/1/2018

6/1/2019

A88072

FLUKE/HART

1502A

12/17/2018

4/2/2019



Rev 13
8/17/20 IS

Technical Maintenance, Inc.

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z540-1-1994


-------
Certificate Number
A3079040
Issue Date: 01/23/19

Certificate	of

Data Sheet

Parameter

Nominal

Minimum

Maximum

As Found

As Left

Unit

Temperature Accuracy

-25.00

-25.05

-24.95

-25,02

-25.02

°c

Temperature Accuracy

0.00

-0.05

0.05

0.00

0.00

*c

Temperature Accuracy

100.00

99.95

100.05

99.99

99 99

°c

Temperature Accuracy

150.00

149.95

150.05

149.96

149.96

°c

Page 2 of 2

Unit ADJ/FAIL



b c

- 0.0 \ o
/„ e&d®0

T

mi

Technical Maintenance, Inc.

~~ANSI/NCSL Z540-1 -1994

12530 TELECOM DRIVE, TEMPLE TERRACE. FL 33637
Rev 13	Phone: 813-978-3054 Fax 813-978-3758

8/17/2018	www,tmicalibration.com


-------
Certificate Number
A3079044
Issue Date: 01/23/19

Certificate of Calibration

Page 1 of 2

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES
1128 NW 39TH DRIVE
GAINESVILLE, FL 32605
FEDEX

P.O. Number:

ID Number: (EEMS 01229

iiiiiiiiiiiiiiiiiiiiiiiii

Description: DIGITAL STIK THERMOMETER

Manufacturer: FLUKE

Model Number: 1551A EX

Serial Number: 3275143

Technician: STEVE TORRES

On-Site Calibration: ~

Comments: TUR Is 2 to 1

Calibration Date:
Calibration Due:
Procedure:

Temperature:
Humidity;

FLUKE 1551A EX.52A EX
Rev: 11/1/2010
71 F
43 % RH

As Found Condition: IN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute:				

This Instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (NIST) or other National
Metro logical Institute (NMI). The method of calibration is direct comparison to a known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainty values at an approximately 95% confidence level using a coverage factor of k=2. Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement,

TMI's Quality System is accredited to SO/IEC 17025:2017 and ANSI/NCSL Z54Q-1-1994, ISO/IEC 17025:2017 is written in a language relevant to laboratory
operations, meeting the principles of ISO 9001 and aligned with its pertinent requirements, This calibration complies with all the requirements of ANSI/NCSL Z540-1-
1994 and TMI's Quality Manual, QM-1,

Results contained in this document relate only to the item calibrated. Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do not imply continued conformance to specifications.

This certificate shall not be reproduced, except In full, without the written permission of Technical Maintenance, Inc.

Measurements not currently on TMI's Scope of Accreditation are identified with an asterisk.











JLqJs*-

FRANK BAHMANN, BRANCH MANAGER



Scott Chamberlain, QUALITY MANAGER





Calibration Standards





Asset Number

Manufacturer

Model Number

Date Calibrated

Cal Due

05535

FLUKE

5609-12-D

7/3/2018

7/3/2019

660TL18010015

ADDITEL

ADT875PC-155

6/1/2018

6/1/2019

A88072

FLUKE/HART

1502A

12/17/2018

4/2/2019

Rev. 13
8/17/20 IS

Technical Maintenance, Inc.

12530 TELECOM DRIVE, TEMPLE TERRACE. FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL ZS40-1 -1994


-------
Certificate Number
A3079044
Issue Date: 01/23/19

Certificate of Calibration

Data Sheet

Parameter

Nominal

Minimum

Maximum

As Found

As Left

Unit

Temperature Accuracy

-25.00

-25 05

-24.95

¦25 02

-25.02

°c

Temperature Accuracy

0.00

-0.05

0.05

0.01

0.01

°c

Temperature Accuracy

100.00

99,95

100.05

99.99

99.99

°C

Temperature Accuracy

150.00

149,95

150.05

149 97

149.97

"C

Page 2 of 2

Unit ADJ/FAIL



* r 0WW

y c	-0-

Rev. 13
8/17/2018

Technical Maintenance, Inc.

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z540-I-I994


-------
Date

2/12/2019 - - Calibration and certification of fluke Thermocouples

TMI Cert data -

1/23/2019









EEMS





STD

RTD





cert # =

A3079044

01229











diff

corrected



-25.00



-25.02



0.020

-25.02



0.00



0.01



-0.010

0.02



100.00



99.99



0.010

100.01



150.00



149.97



0.030

149.99











0.000

0.01











0.000

0.01







RTD 01229



2019 correction:

slope=

0.99989313





intercept=

-0.0064885





1.0000000



2/12/2019

At Date fluke =
EEMS 2/12/2019

RTD

01229	thermo =

raw corrected

0.02

0.03

88.74

88.76

79.50

79.51

61.50

61.51

51.65

51.66

39.60

39.61

31.07

31.08

15.64

15.65

Thermocouple offset =
POST CALIBRATION CHECK

20.88 20.89

slope =
intercept =
correlation =

01311

offset
-0.3

EEMS
van3
01236

raw

0.7
89.4

80.1
62.0
52.3
40.0
31.6

16.2

-0.3

corrected
0.14
88.84
79.54
61.44
51.74
39.44
31.04
15.64

01312

offset
-0.2

EEMS
van 2
01237

raw

0.1
89.8

80.6
62.5
52.8
40.5
32.0

16.7

-0.2

corrected
-0.46
88.59
79.45
61.49
51.86
39.65
31.21
16.02

01310

offset
0.8

EEMS
van 1
01238

raw

0.3
89.5
80.2

62.2

52.3
39.9

31.4
16.2

0.3

corrected
0.01
88.76
79.51
61.60
51.75
39.41
30.95
15.83

20.9
1.00007
0.557902
1.0000

20.34

21.0
1.0073916
0.5587589
1.0000

20.29

20.9
1.005088
0.289648
1.0000

20.51


-------
Date

2/12/2019 - - Calibration and verification of three RTD meters with most recent certification of EEMS RTD

TMI Cert data -- 1/23/2019

TMI

EEMS





STD

RTD





Cert#

A2380069

01229











diff

corrected



-25.00



-25.02



0.020

-25.016



0.00



0.01



-0.010

0.016



100.00



99.99



0.010

100.007



150.00



149.97



0.030

149.993







RTD 01229



2019 correction:

slope=

0.99989313





intercept=

-0.0064885



corr=

1.0000000



t~~	2/12/2019

RTD	RTD	RTD

At Date	01230 101231	01227/1	01228/2

EEMS

2/12/2019

EEMS



EEMS



EEMS



RTD

AER



van3



van1



01229













raw

corrected

raw

corrected

raw

corrected

raw

corrected

0.02

0.03

0.04

0.01

0.15

0.00

-0.09

0.02

10.32

10.33

10.35

10.34

10.56

10.09

10.31

10.57

21.10

21.11

21.12

21.12

21.43

20.89

21.19

21.35

30.30

30.31

30.32

30.33

30.67

30.30

30.47

30.30

40.00

40.01

39.98

40.00

40.46

40.02

40.28

40.03

47.91

47.92

47.89

47.92

48.40

47.90

48.23

47.90

25.00

25.01

25.00

25.00

25.34

25.01

25.14

25.02



slope =

0.998872



1.007333



1.009092





intercept =

0.026147



0.144973



-0.11036





correlation =

1.0000



1.0000



1.0000




-------
Date

2/14/2019

- Calculation of correction factor for RH standard with n

TMI Cert date =2/6/2019

TMI

EEMS





STD

AZ 8723





Cert #

A3092730

01222









diff



corrected











0.0

2.0











0.0

2.0











0.0

2.0



33.0



31.7



1.3

32.8



50.0



49.6



0.4

50.3



75.0



74.9



0.1

74.9







RH 01222



2019 correction:

slope=



1.0273





intercept=

-2.0396



corr =

0.9999400



M-Sh" 2/14/2019


-------
Certificate	of

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES

1128 NW 39TH DRIVE
GAINESVILLE, FL 32605
FEDEX

P.O. Number:

ID NumbecTEEMS 01222

llllllllllllllillllllilllillllllllllllllll

Description: PSYCHROMETER
Manufacturer: AZ INSTRUMENTS
Model Number: AZ 8723
Serial Number: 10325187
Technician: STEVE TORRES

On-Site Calibration: ~

Comments:

Calibration Date:
Calibration Due:
Procedure:

Temperature:
Humidity:

THERMOGRAPHS

Rev: 2/22/2011
71 F
43 % RH

As Found Condition: IN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute: j

This instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (NIST) or other National
Metrological Institute (NMI). The method of calibration is direct comparison to a Known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainty values at an approximately 95% confidence level using a coverage factor of k=2. Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement,

TMI's Quality System Is accredited to ISO/IEC 17025:2017 and ANSI/NCSL Z540-1-1994 ISO/IEC 17025:2017 Is written In a language relevant to laboratory
operations, meeting the principles of ISO 9001 and aligned with its pertinent requirements. This calibration complies with all the requirements of ANSI/NCSL Z540-1-
1994 and TMI's Quality Manual. QM-1

Results contained in this document relate only to the item calibrated. Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do not imply continued conformance to specifications.

This certificate shall not be reproduced, except in full, without the written permission of Technical Maintenance, Inc.

Measurements not currently on TMI's Scope of Accreditation are identified with an asterisk.

FRANK BAHMANN, BRANCH MANAGER

Scott Chamberlain, QUALITY MANAGER

Asset Number
0710649

Manufacturer
THUNDER SCIENTIFIC

Calibration Standards

Model Number
2500ST

Date Calibrated
11/2/2018

Cal Due
6/23/2019

tMt

Technical Maintenance, Inc.

Rev. 13
8/17/2018

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637

Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z540-1-1994


-------
Certificate Number
A3092730
issue Date; 02/06/19

Certificate	of

Data Sheet

Parameter

Nominal

Minimum

Maximum

As Found

As Left

Unit

Temperature Accuracy

50.0

49.0

51.0

49.7

49.7

°F

Temperature Accuracy

70.0

69.0

71.0

69 5

69.5

°F

Temperature Accuracy

90.0

89 0

91.0

89,4

89.4

°F

Humid it/ Accuracy

33.0

30.0

36,0

31.7

31.7

%RH

Humidity Accuracy

50.0

47.0

53.0

496

49.6

%RH

Humidity Accuracy

75.0

72,0

78.0

74.9

74.9

%RH

Unit ADJ/FAIL



OL2.Z2-

nA -
\or

ra

/. 00.7 5

- x.



tMi

Technical Maintenance, Inc.

Rev. 13
8/17/2018

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z54CM-I994


-------
Date

2/14/2019

- Calculation of correction factor for RH standard with n

TMI Cert date =2/6/2019

TMI

EEMS





STD

AZ 8723





Cert #

A3092732

01223









diff



corrected











0.0

1.3











0.0

1.3











0.0

1.3



33.0



32.0



1.0

32.8



50.0



49.7



0.3

50.3



75.0



74.7



0.3

74.9







RH 01223



2019 correction:

slope=



1.0154





intercept=

-1.3456



corr =

0.9999379



M-Sh" 2/14/2019


-------
Certificate Number
A3092732
fssue Date: 02/06/19

Certificate of Calibration

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES

1128 NW 39TH DRIVE	P.O. Number:

GAINESVILLE, FL 32605
FEDEX

ID Number: EEMS 01223

llllll II MJUMIU

Description: PSYCHROMETER
Manufacturer AZ INSTRUMENTS
Model Number: AZ 8723
Serial Number: 10325189
Technician: STEVE TORRES

On-Site Calibration: ~

Comments:

Calibration Date:

: / 02/06/2019 N
Calibration Due: , 02/06/2020 /

Procedure:	"~~~T:MHvttTf5ROTHERMOGRAPHS

Rev: 2/22/2011
Temperature:	71 F

Humidity:	43 % RH

As Found Condition: IN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute:!	I

This instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (NlST) or other National
Metrological Institute (NMI). The method of calibration is direct comparison to a known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainty values at an approximately 95% confidence level using a coverage factor of k=2. Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement.

TMI's Quality System is accredited to ISO/IEC 17025:2017 and ANSI/NCSL Z54Q-1-1994 ISO/IEC 17025:2017 is written in a language relevant to laboratory
operations, meeting the principles of ISO 9001 and aligned with its pertinent requirements. This calibration complies with all the requirements of ANSI/NCSL Z540-1-
1994 and TMI's Quality Manual, QM-1.

Results contained in this document relate only to the item calibrated. Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do not imply continued conformance to specifications.

This certificate shall not be reproduced, except in full, without the written permission of Technical Maintenance, Inc.

Measurements not currently on TMI's Scope of Accreditation are identified with an asterisk.

FRANK BAHMANN, BRANCH MANAGER	Scott Chamberlain, QUALITY MANAGER

Calibration Standards

Asset Number Manufacturer Model Number	Date Calibrated Cal Due

0710649 THUNDER SCIENTIFIC 2500ST	11/2/2018	6/23/2019



Rev. 13
8/17/2018

Technical Maintenance, Inc.

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibrationxom

ANSI/NCSL Z540-I-I994


-------
Certificate Number
' A3092732
Issue Pate: 02/06/19

Certificate of Calibration

Data Sheet

Parameter

Nominal

Minimum

Maximum

As Found

As Left

Unit

Temperature Accuracy

50.0

49.0

51.0

49.5

49.5

"F

Temperature Accuracy

70.0

69.0

71.0

69.7

69.7

"F

Temperature Accuracy

80.0

89 0

91 0

89.4

09.4

°F

Humidity Accuracy

33.0

30.0

36.0

32.0

32.0

%RH

Humidity Accuracy

50.0

47.0

53.0

49.7

49,7

%RH

Humidity Accuracy

75.0

72.0

78.0

74.7

74.7

%RH

Unit ADJ/FAIL

M - (.0154
t? = -I .Z*ZL>
f z =. o.

'Ml

Technical Maintenance, Inc.

Rev. 13
8/17/2018

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z540-1-I994


-------
Date

2/14/2019 - - Calculation of correction factor for RH standard with n

TMI Cert date =2/6/2019

TMI

EEMS



STD

Hygropalm



Cert #

A3092720

01220/01225







diff

corrected









0.0

-2.7









0.0

-2.7









0.0

-2.7



33.0



34.2

-1.2

33.1



50.0



50.2

-0.2

49.8



75.0



74.3

0.7

75.1





RH 01220/01225



2019 correction:

slope=

0.9555





intercept=

2.5795



corr =

0.9999784



M-Sh" 2/14/2019


-------
Certificate Number
A3092720
-fssue Date: 02/06/19

y

Certificate	of

Page 1 of 2

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES
1128 NW 39TH DRIVE
GAINESVILLE, FL 32605
FEDEX



P.O. Number:
ID Numb

JIOllll

Description: THERMO HYGROMETER
Manufacturer: ROTRONIC
Model Number: HYGROPALM
Serial Number: 40861 002/124431
Technician: STEVE TORRES

On-Site Calibration: [~|

Comments:

Calibration Dati
Calibration Due>
Procedure:

Temperature:
Humidity:

02/06/2019
02/06/2020,

fWffiYGROTHERMOGRAPHS
Rev: 2/22/2011
71 F
43 % RH

As Found Condition: IN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute:;

This instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (MIST) or other National
Metrological Institute (NMI), The method of calibration is direct comparison to a known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainty values at an approximately 96% confidence level using a coverage factor of k-2 Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement,

TMI's Quality System is accredited to ISO/IEC 17025:2017 and ANSI/NCSL Z540-1-1994, ISO/1EC 17025:2017 is written in a language relevant to laboratory
operations, meeting the principles of ISO 9001 and aligned with its pertinent requirements This calibration complies with all the requirements of ANSI/NCSL Z540-1-
1994 and TMI's Quality Manual, QM-1.

Results contained In this document relate only to the item calibrated. Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do not imply continued conformance to specifications.

This certificate shall not be reproduced, except In full, without the written permission of Technical Maintenance, Inc.

Measurements not currently on TMI's Scope of Accreditation are identified with an asterisk,

-

FRANK BAHMANN, BRANCH MANAGER

Asset Number
05535

Manufacturer
FLUKE

0710649

THUNDER SCIENTIFIC

2500ST

A88072

FLUKE/HART

1502A

Scott Chamberlain, QUALITY MANAGER

Calibration Standards

Model Number
5609-12-D

Date Calibrated
7/3/2018

11/2/2018

12/17/2018

Cal Due
7/3/2019

6/23/2019

4/2/2019

TMj

Technical Maintenance, Inc.

Rev 13
8/17/2018

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z540-I-1994


-------
Certificate of Calibration

Data Sheet

Parameter

Nominal

Minimum

Maximum

As Found

As Left

Unit

Temperature Accuracy

15 0

14.6

15.4

14.9

14 9

C

Temperature Accuracy

25 0

24 6

25.4

24.7

247

C

Temperature Accuracy

35.0

34,6

35.4

34.7

34.7

C

Humidity Accuracy

33.0

31.4

34.6

34.2

34.2

%

Humidity Accuracy

50.0

48.4

51.6

50.2

50.2

%

Humidity Accuracy

75.0

73.4

76.6

74.3

74.3

%

Unit ADJ/FAIL



4^

m -

b ~

(/tfc-fl-

G.'R $"55

Z. r


-------
EEMS 01240 — Licor LI-200 and RMY soiar radiation system

• Range = 0 to 1 volt = 0 to 1400 w/m2
Compared with EEMS 01245/01246 Eppley PSP standard.
3/9/2019 At EEMS by Eric Hebert

SiteReport - Site Van3 Report TimeBeginning
Date&Time 09/03/2019 12:40 12:40:00- 15:45:00



1100-J



1050-



1000-



950-



900-



850-



800-



750-



700-



650-





>

600-



550-



500-



450-



400-



350-



300-



250-



200-



150-1













































u 1





































to

































A

1 a

V































n '

, l

1











V i

























l











I

\\l





















A
( \















i



i



















I fx

J





1

1







A



ft













i





if 1

























































i



















a



































































J i

V





















I













J



i







1





























l





















1

/

















i





















/

















































12:50 13:00 13:10 13:20 13:30 13:40 13:50 14:00 14:10 14:20 14:30 14:40 14:50 15:00 15:10 15:20 15:30 15:40

Date & Time

- SR Std[W/M2] 	SR test[W/M2]

slope =
intercept =
correlation =

0.9646
4.3322
0.99959


-------


I J- i.

THE EPPLEY LABORATORY, INC.

12 Sheffield Avenue, PO Box 419, Newport, Rhode Island USA 02840
Phone: 401.847.1020 Fax: 401.847.J031 Email: info@eppleylab.com

Calibration Certificate



Instrument:
Procedure:

Precision Spectral Pyranometer, Model PSP, Serial Number 34341F3
This pyranometer was compared in Eppley's Integrating H e m i sp hm rrl in o to
procedures described in ISO 9847 Section 5.3.1 and Technical Procedure, TP01 of
The Eppley Laboratory. Inc.'s Quality Assurance Manual on Calibrations.

Transfer Standard: Eppley Precision Spectral Pyranometer, Model PSP, Serial Number 21231F3

-2

Results:

Sensitivity: S = 9.29 nV / Wnf

Uncertainty:	U95 = ±0.91% (95% confidence level, k=2)

Resistance:	699 Q at 23°C

Date of Test:

January 22,2019

Traceability:

Due Date:

Customer:

This calibration is traceable to the World Radiation Reference (WRR) through
comparisons with Eppley's AHF standard self-calibrating cavity pyrheliometers
which participated in the Twelfth International Pyrheliometric Comparisons (IPC
XII) at Davos, Switzerland in September-October 2015. Unless otherwise stated in
the remarks section below or on the Sales Order, the results of this calibration are
"AS FOUND / AS LEFT".

Eppley recommends a minimum calibration cycle of Five (5) years but encourages
annual calibrations for highest measurement accuracy.

EEMS

Gainesville, FL

Signatures:
Eppley S(i__

'4

In Charge of Test:
65367

Reviewed by:

Date of Certificate January 23, 2019

Remarks:

Amplifier #10765 set with gain of 76.89 so pair produces 1 V = 1400 Wm"2.

End of Report


-------
PACKING LIST

The Eppley Laboratory, Inc.

12 Sheffield Ave.

Phone # 4Q1-B47-1Q20 Fed. ID No. 05-0136490

Name / Address

EEMS

Att: Eric Hebert
1128 NW 39th Drive
Gainesville, EL 32605

s.o. No. 65367

1/23/2019

f





Ship To

EEMS

Att: Eric Hebert
1128 NW 39th Drive
Gainesville, FL 32605

Ol f &

P.O...

ShipDate 1/30/2019

Ship Via

FedEx COLLECT

Recalibration Model 8-4 8 « T-SfefZ-M
Recalibration of Model PSP - 3^,^ ^ Wl£lA
Reset Amplifier a	5"

Cs.t cksAua 5^ | V - iMtO LO _2"



> M

s -



s = L^il

» S * moo

iO

G?P\ 1 ^ —

O £> 1 3 CO

t	\



£>- ov 3 6

"7^,©^ ]

¦J

Made in USA

Terms Credit Card

FOB Newport, Rl USA


-------
f9a$L~

THE EPPLEY LABORATORY, INC.

12 Sheffield Avenue, PO Box 419, Newport, Rhode Island USA 02840
Phone: 401.847.1020 Fax: 401.847.1031 Email: info@eppleylab.com

A-



Calibration Certificate

Oi 2Jty

Instrument:
Procedure:

Black & White Pyranometer, Model 8-48, Serial Number 23824

This pyranometer was compared in Eppley's Integrating Hemisphere according to
procedures described in ISO 9847 Section 5.3.1 and Technical Procedure, TP01 of

The Eppley Laboratory, Inc.'s Quality Assurance Manual on Calibrations.

Transfer Standard: Eppley Black & White Pyranometer, Model 8-48, Serial Number 14061

-2

Results:

Sensitivity: S =8.80 \iV / Wm

Uncertainty:	Ug5 = ±0.91% (95% confidence level, k=2)

Resistance:	347 Q at 23°C

Date of Test:

January 22,2019

Traceabilitv:

Due Date:

This calibration is traceable to the World Radiation Reference (WRR) through
comparisons with Eppley's AHF standard self-calibrating cavity pyrheliometers
which participated in the Twelfth International Pyrheliometric Comparisons (IPC
XTI) at Davos, Switzerland in September-October 2015. Unless otherwise stated in
the remarks section below or on the Sales Order, the results of this calibration are
"AS FOUND / AS LEFT".

Eppley recommends a minimum calibration cycle of five (5) years but encourages
annual calibrations for highest measurement accuracy.

Customer:

Signatures:
Eppley SO:

EEMS

Gainesville, FL

Charge of Test:

In

65367

Reviewed by:

Date of Certificate January 23, 2019

Remarks:

End of Report


-------


m

Warren-Knight Instrument Company
2045 Bennett Road
Philadelphia, PA 19116
Phone: 215-464-9300; Fax: 215-464-9303
Web: hrtn://w ww.warrcrtind.cam

V,



2_

Temperature:

77SW77<4^

Humidity:

4-

3 *

Calibration Data Record



Customer Name

Item Name

Manufacturer

Model	

Calibration OrtS



Serial Number

(T&037

/-?- 3 ~/f

:

Calibration Frequency

job CareKNumber



Customer Reference Number

Date of Ce rt ifi cati on

Z-23-/?

M&asurtfMnE Standards		 	.

Theodolite Wild T-3 S/N 18301 Calibration 01/16/13 Due 01/16/20 WjT Number 73S/229329-S3 73S/22-3-39S"

Optical Wedge K&e'71-7020 S/N 5167 Calibration; 01/16/29 Due 01fl6/24,>nSFf4w»d*r-73tfZ3W84-S9 731/?21617~

Initial Report

Vanes

OirtKtiert
(Oegwj

iota-ranee
(Minute)

ComjHii NfPdic Error
(Minute)

Pivot in line with Circle/Sights

~ Pass O Fail

+/- 30

Needle

+A 30

Pivot Sharpness

~ Pass ~ Fail

+/-30

Straightness (¦*•/-!5 Minutes)

~ Pass ~ Fall

+/- 30

Balance

~ Pass ~ Fait

*/- 30

Ufter Function

~ Pass ~ Fail

+/- 30

Azimuth Ring

~A 30

Contra! Knob Function

~ Pass ~ Fail

*t 30

Pinion Gesr

~ Pass ~ Fail

Graduation Clarity

~ Pass ~ Fail

Graduation less than 1 minute in any position

~ Pass ~ Fail

Level Bubble

Bubble in Level

~ Pass ~ Fail

Physical Condition

~ Pass ~ Fail

Pass/Rgpair/Replatf

Pass

N/A

Replace \ Repair

~

~

~

O

~

~

~

~

~

o

~

~

~

~

~

~

~

0

~

~

~

~

D

~

~

~

~

~

~

~

O

~

~

o

~

~

~

o

~

~

~

o

~

~

~

~

~

~

~

~

~

~

~

~

~

~

D

~

D

~

0

~

~

~

Needle ~ Sharpen o Magnetize

Cap with Jewel

Pivot a Sharpen

Level ~ Remount

North Sight

North Sight Block

South Sight

South Sight Block

Vane Spring

Drive

Control Knob Assembly

Cover Glass

Cover Glass Gasket

Clamp Screw

Pinion Gear

Compass Ring

Fins* Report 	

Vanes

/

Direction

Toiswie*

(MjfiuteJ

Compass Mc«5?e loot
(Minute]

Pivot in line with Circle/Sights

rif Pass ~ Fail

D

+A30

<

Needle

/

45

+A30



Pivot Sharpness

$ Pass ~ Fail

90

~A 30

< ~?0

Straightness {+/-15 Minutes)

Wf Pass ~ Fail

135

+A30

/ 3d

Balance

CTf^ass P Fail

160

+A 30

< 3o

Lifter function

[jS^Pass ~ Fall

225

•4/-30

< 36





270

¦*¦/• 30

< 20

Control Knob Function

repass ~ Fail

325

~A 30

C

Pinion Gear

B'.Pass ~ Fall

Graduation Clarity

(0,P'ass ~ Fail

Graduation less than 1 minute in any position

0 Pass ~ Fail

Bubble i / J 	—		:	

Bubble in level

[3/^ass ~ Fail

Physical Condition

0 Pass ~ Fail

pairTemnlc



5l

John Noga, Quality Assurance

77 '




-------
£t-W>

€¦>

*71 Warren -Knight Instrument Company
if J 2045 Bennett Road
£ Philadelphia, PA 19116

Phone: 215-464-9300; Fax: 215^54-9303
Web: httn://*v*w. warreni nd.com

& £>(. Z7X-

Calibration Dats Record

Customer Name

Manufacturer

Serial K'umber

Calibration Frequency



7775W

Herri Name

Mode!

Calibration Date

Job Card Number ,
Date of Cprtifit^rtioi

Temperatures .-ry1^ Humidity; 3T7/«>_

—(/{UAK/+77\	~

/^zrr^TT

\S~ %&(?

azT-/?

Customer Reference Number

Meaiuramgnt Standards

TheodoSitf'wild T-3S/N 18S01 CalifarationOi/16/19 Due 01/16/ZQ NiSTSomber738/229329-83 73S/Z3339.
Optical Wedge KSE 71-7020 S/N 516? Calibration.; 01/15/19 Due 01/36/24, NiS

U/32161?

Inrti;s? ftfrpcrt

Vanes

Pivot In line with Circle/Sights

~ Pass ~ Fail

thntiUon

Tolerance

IMfrtutel

+/-30

+/ 30

Compare	if rot

fMj rafted

Pivot Sharpness

Straightness (+/-15 Minutes)

Balance

Lifter Fir net ion

~ Pass ~ Fail

+1- 30

~ Pass ~ Fail

*/- 30

~ Pass P Fail

+/- 30

~ Pass D Fail

+/- 30

Azimuth Ring

+/- 30

Control Knob Function

Pinion Gear

Gradual ion Clarity

Graduation less than 1 minute in any position

~ Pass ~ fail

»/- 30

~ Pass ~ Fail

~ Pass ~ Fail

~ Pass ~ Fail

Bubble

Bubble ir. Level

~ Pass ~ Fail

Physical Condition

~ Pass ~ Fait



I':!:,:

H/A ") Replace | Repair

~

~

O

~

~

~

~

a

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

D

~

o

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

~

o

o

Needle c Sharpen a Magnetize

Cap with Jewel

Pivot D Sharpen

Level o Remount

North Sight

North Sifrht Block

South Sight

South Sipht Slock

Va ne Spring

Drive

Control Knob Assembly

Cover Glass

Cover Glass Gasket

Clamp Screw

Pinion Gear

Compass Rjnr

* ins! hpc-sn
Verses

/

Uir*ctipn
(Depce)

Tolersrss

fV-ittuf*;

Co-nixm NwHc &fur
(Minute'

Pivot in line with Circle/Sights

fS Pass ~ Fail

0

r/-30

< 30



, /

45

*f- 30

< Ji O

Pivot Sharpness

£? /'ass ~ Fail

90

*¦/- 30

<

Straightrvess (+/-15 Minutes)

Br p^ss O Fail

13S

*/ 30

< 3t)

Balance

Q/'ass ~ Fail

ibo

V-30

< 3 O

Lifter Function

M Pass ~ Fail

225

<^-30

>W



270

~A 30

———

Control Knob Function

tj/psss O Fail

315

+/- 30





tj'yass ~ Fail







Graduation Clantf

P/f ass ~ Fail

Graduation less then 1 minute in any position

0 P^ss D Fail

Level Bubbt®

fa/f^ass ~ Fait . .

Physical Condition X)

0 Pass ~ Fail

1/

CSrrrrjcatKi-*' f / //					

/*<*/ •• s7—f

A J i ^'1

FTebair TecSiidan ' /

John Noga. Quality Assurance I f


-------
Certificate Number	^^	#•	i ¦ i am

A3081102	Certificate

Issue Date: 01/25/19	-	—

Page 1 ofS.

v.

cere

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES*

1128 NW 39TH DRIVE
GAINESVILLE, FL 32605
FEDEX

P.O. Number:

ID Number; 01310

Description: DIGITAL MULTIMETER
Manufacturer: FLUKE
Model Number: 187
Serial Number: 86590148
Technician: TAYLOR FLOYD

On-Site Calibration: Q
Comments:

Calibration Date:
Calibration Due:
Procedure:

Temperature:
Humidity:

01/25/2019
01/25/2020,

METCAL FLUKE 187
Rev: 6/15/2015
70 F
42 % RH

As Found ConditionrlN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute:

This instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (NIST) or other National
Metroiogica! Institute (NMI). The method of calibration is direct comparison to a known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainty values at an approximately 95% confidence level using a coverage factor of k=2. Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement.

TMI's Quality System is accredited to ISO/IEC 17025:2017 and ANSI/NCSL Z540-1-1994. I SO/I EC 17025:2017 is written in a language relevant to laboratory
operations, meeting the principles of ISO 9001 and aligned with its pertinent requirements. This calibration complies with all the requirements of ANSI/NCSL Z540-1-
1994 and TMI's Quality Manual, QM-1.

Results contained in this document relate only to the item calibrated. Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do net imply continued conformance to specifications.

This certificate shall not be reproduced, except in full, without the written permission of Technical Maintenance. Inc.

Measurements not currently on TMI's Scope of Accreditation are identified with an asterisk,

FRANK BAHMANN, BRANCH MANAGER

Scott Chamberlain, QUALITY MANAGER

Asset Number
7040208

Manufacturer
FLUKE

Calibration Standards

Model Number
5520A

Date Calibrated
3/12/2018

Cal Due
3/12/2019

\

rYI]

Technical Maintenance, Inc.

Rev. 13
8/17/2018

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z540-1-1994


-------
CsrtS,rbe Certificate of Calibration

Issue Date: 01/25/19

Page 1 of S_

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES
1128 NW 39TH DRIVE
GAINESVILLE, FL 32605
FEDEX

v/,



P.O. Number:
ID Numbe

llll IIII II 111!

Description: DIGITAL MULTIMETER
Manufacturer: FLUKE
Model Number: 287
Serial Number: 95740135
Technician: TAYLOR FLOYD

On-Site Calibration: ~

Comments:

Calibration Date;
Calibration Due:'
Procedure:

Temperature:
Humidity:

01/25/2019
01/25/202;

5AL FLUKE 287
Rev: 6/15/2015
70 F
42 % RH

As Found Condition:IN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute:

This instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (NIST) or other National
Metrological Institute (NMI). The method of calibration is direct comparison to a known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainty values at an approximately 95% confidence level using a coverage factor of k=2. Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement.

TMI's Quality System is accredited to ISO/IEC 17025:2017 and ANSI/NCSL Z540-1-15S4 ISO/IEC 17025:2017 is written in a language relevant to laboratory
operations, meeting the principles of ISO' 9001 and aligned with Its pertinent requirements. This calibration complies with all the requirements of ANSI/NCSL Z540-1-
1994 and TMI's Quality Manual, QM-1.

Results contained in this document relate only to the item calibrated- Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do not imply continued conformance to specifications.

This certificate shall not be reproduced, except in full, without the written permission of Technical Maintenance, Inc.

Measurements not currently on TMI's Scope of Accreditation are identified with an asterisk.

-

FRANK BAHMANN, BRANCH MANAGER	Scott Chamberlain, QUALITY MANAGER

Calibration Standards

Asset Number	Manufacturer	Model Number	Date Calibrated Cal Due

7040208	FLUKE	5520A	3/12/2018	3/12/2019

\

tMi

Technical Maintenance, Inc.

Rev. 13
8/17/2018

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978=3054 Fax 813-978-3758
www.tmicalibration.com

ANSI/NCSL Z540-1-1994


-------
A3081107 Certificate of Calibration

Issue Date: 01/25/19	'

Page 1 of 5_

Customer: ENVIRONMENTAL ENGINEERING & MEASUREMENT SERVICES
1128 NW 39TH DRIVE
GAINESVILLE, FL 32605
FEDEX

Uuc2.

P.O. Number:



01/25/2019 )
01/25/2020 ^
METCAL FLUKE 287
Rev: 6/15/2015
70 F
42 % RH

Description: DIGITAL MULTIMETER
Manufacturer: FLUKE
Model Number: 287
Serial Number: 95740243
Technician: TAYLOR FLOYD

On-Site Calibration: ~

Comments:

Calibration Date
Calibration Due:
Procedure:

Temperature:
Humidity:

As Found Condition:IN TOLERANCE
Calibration Results: IN TOLERANCE

Limiting Attribute:^

This instrument has been calibrated using standards traceable to the SI units through the National Institute of Standards and Technology (NIST) or other National
Metrologlcal Institute (NMf). The method of calibration is direct comparison to a known standard, derived from natural physical constants, ratio measurements or
compared to consensus standards.

Reported uncertainties are expressed as expanded uncertainty values at an approximately 95% confidence level using a coverage factor of k=2. Statements of
compliance are based on test results falling within specified limits with no reduction by the uncertainty of the measurement.

TMI's Quality System is accredited to ISO/IEC 17025:2017 and ANSl/NCSL Z54G-1-1994. ISO/IEC 17025:2017 is written in a language relevant to laboratory
operations, meeting the principles of ISO 9001 and aligned with its pertinent requirements. This calibration complies with all the requirements of ANSl/NCSL Z540-1-
1994 and TMI's Quality Manual. QM-1 -

Results contained in this document relate only to the item calibrated. Calibration due dates appearing on the certificate or label are determined by the client for
administrative purposes and do not imply continued conformance to specifications.

This certificate shall not be reproduced, except in full, without the written permission of Technical Maintenance, Inc.

Measurements not currently on TMI's Scope of Accreditation are identified with an asterisk.

FRANK BAHMANN, BRANCH MANAGER	Scott Chamberlain, QUALITY MANAGER

Calibration Standards

Asset Number Manufacturer Model Number	Date Calibrated Cal Due

7040208 FLUKE 5520A	3/12/2018	3/12/2019

\

tMi

Technical Maintenance, Inc.

Rev. 13
8/17/2018

12530 TELECOM DRIVE, TEMPLE TERRACE, FL 33637
Phone: 813-978-3054 Fax 813-978-3758
www.tmicalibration.com

ANSl/NCSL Z540-M994


-------
~

MesaLabs

As Shipped Calibration Data

Certificate No	281466 	

Technician	Lil+ann 3 Ma I i n o w s k a

f,

OLr

v2-

Instrument Reading
25344 seem
5017.9 seem
1508.4 seem
21.3 °C
748 mmHg

Lab Standard Reacting

25183 seem
5000.8 seem
1501.65 seem
21.3 °C
748 mmHg

Deviation

0.64%
0.34%
0.45%

Mesa Laboratories Standards Used

Description
ML-800-44

Percision Thermometer
Precision Barometer

Standard Serial Number
101897

305460
2981392

2.^2-





014 If

Lab. Pressure
Lab. Temperature

NV/LAP Lab Code 200661
Calibration

748 mmHg
21.3 °C



Allowable Deviation

1.00%

1.00%

1.00%

± 0,8°C
± 3.5 mmHg

As Shipped
In Tolerance
In Tolerance
In Tolerance
In Tolerance
In Tolerance

Calibration Date
Q1-May-2018
02-0ct-2018
1 S-Jul-2018

Calibration Due Date

01-May-2019

02-0ct-2019
18-Jul-2019

Calibration Notes

The expanded uncertainty of flow, temperature, and pressure measurements all have a coverage factor of k = 2 for a confidence
interval of approximately 95%.

Flow testing is in accordance with our test number PR18-13 with an expanded uncertainty of 0.18% using high-purity nitrogen or
filtered laboratory air Flow readings in seem are performed at STP of 21 1°C and 760 mmHg

Pressure testing is in accordance with our test number PR18-11 with an expanded uncertainty of 0.16 mmHg.

Temperature testing is in accordance with our test number PR18-12 with an expanded uncertainty of 0.04 °C.

Traceability to the International System of Units (SI) is verified by accreditation to ISO/IEC 17025 by NVLAP under NVLAP Code
200661-0.

Technician Notes:
By:

Mohammed Aziz

Director of Engineering

Mesa Laboratories, Inc.. Butler, NJ

m
\> '•

-2--

0. ^"33> I	°l37

2 of 2

Mesa Laboratories Inc. 10 Park Place Butler. NJ 07405 USA
(973) 492-8400 FAX (973) 492-8270 www.mesalabs com Symbol "MLA0'' on the NAS

CAL02-48 Rev G05


-------
E

MesaLabs



T-

I 2_

DW(1&0J

NV/LAP Lab Code 200661-0
Calibration

Serial No.
Cal. Date

Calibration Certificate
Sold To:

I-530+ High Defender 530+ High Flow

159956		*4(4

0a-Feb-2019	" " '



Environmental Engineering & Measurement
Services

8010 SW 17th Place
Gainesville, FL 32607
US

All calibrations are performed at Mesa Laboratories, Inc.. 10 Park Place, Butler, NJ, 07405, an ISO 17025:2005 accredited laboratory
through NVLAP of NIST, This report shall not be reproduced except in full without the written approval of the laboratory. Results only
relate to the items calibrated. This report must not be used to claim product certification, approval, or endorsement by NVLAP, NIST, or
any agency of the Federal Govemment.

As Received Calibration Data

Technician

Instrument Reacting

25880 seem
5145.1 seem
1542.4 seem
22.4 °C
756 mmHg

Lilianna Malinowska

Lab Standard Reading

25126 seem
5000.7 seem
1500.35 seem
22 6 X
757 mmHg

Deviation

3.0%

2.89%

2.8%

Lab, Pressure
Lab. Temperature

757 mmHg
21.3 X

Allowable Deviation

1.00%

1.00%

1.00%

± 0.8X

+ 3.5 mmHg

As Received
Out of Tolerance
Out of Tolerance
Out of Tolerance
In Tolerance
In Tolerance

Mesa Laboratories Standards Used

Description
ML-800-44

Percision Thermometer
Precision Barometer

Standard Serial Number

103521

305460

2981392

Calibration Date
11-Jun-2018

02-0ct-2018
20-Jul-2018

Calibration Due Date
11-Jun-2019
02-0ct-2019
20-Jul-2019

Mesa Laboratories Inc. 10 Park Place Butler, NJ 07405 USA
(973) 492-8400 FAX (973) 492-8270 www.mesalabs.corr Symbol "MLAB" or the NAS

1 of 2	CAL02-48 Rev G05


-------
~

MesaLabs



DWlL&S)

NVLAP Lab Code 200661-0
Calibration

CertificateNo.

Product
Serial No.
Cal. Date

322657

Calibration Certificate
Sold To:

200-220H Definer 220 High Flow
122974
19-Jul-2019

Environmental Engineering & Measurement
Services

8010 SW 17th Place
Gainesville, FL 32607
US

All calibrations are performed at Mesa Laboratories, Inc., 10 Park Place, Butler, NJ, 07405, an ISO 17025:2005 accredited laboratory
through NVLAP of NIST. This report shall not be reproduced except in full without the written approval of the laboratory. Results only
relate to the items calibrated. This report must not be used to claim product certification, approval, or endorsement by NVLAP, NIST, or
any agency of the Federal Government.

As Received Calibration Data

Technician

Instrument Reading
25240.6 seem
5142.08 seem
1599.51 seem
22.3 °C
754 mmHg

Lilianna Malinowska

Lab Standard Reading
25289.71 seem
5128.72 seem
1588.16 seem
22.3 °C
754 mmHg

Deviation
-0.19%
0.26%
0.71%

Lab. Pressure
Lab. Temperature

754 mmHg
22.4 °C

Allowable Deviation

1.00%

1.00%

1.00%

± 0.8°C

± 3.5 mmHg

As Received
In Tolerance
In Tolerance
In tolerance
In Tolerance
In Tolerance

Mesa Laboratories Standards Used

Description
ML-800-44

Percision Thermometer
Precision Barometer

Standard Serial Number

101897

305460

41000LOB

Calibration Date
03-May-2019
02-0ct-2018
27-Nov-2018

Calibration Due Date
02-May-2020
02-0ct-2019
27-Nov-2019

1 of 2

Mesa Laboratories Inc. 10 Park Place Butler, NJ 07405 USA
(973) 492-8400 FAX (973) 492-8270 www.mesalabs.com Symbol "MLAB" on the NAS

CAL02-48 Rev G05


-------
~

MesaLabs







NVLAP Lab Code 200661-0
Calibration

As Shipped Calibration Data

Certificate No
Technician

Instrument Reading
25205.3 seem
5118.46 seem
1576.23 seem
22.8 °C
753 mmHg

322657

Lilianna Malinowska

Lab Standard Reading
25276.27 seem
5120.13 seem
1580.85 seem
22.8 °C
753 mmHg

Lab. Pressure
Lab. Temperature

750 mmHg
22.4 °C

Deviation
-0.28%
-0.03%
-0.29%

Allowable Deviation

1.00%

1.00%

1.00%

+ 0.8°C

± 3.5 mmHg

As Shipped
In Tolerance
In Tolerance
In Tolerance
In Tolerance
In Tolerance

Mesa Laboratories Standards Used

Description
ML-800-44

Percision Thermometer
Precision Barometer

Standard Serial Number

101897

305460

41000LOB

Calibration Date
03-May-2019
02-0ct-2018
27-Nov-2018

Calibration Due Date
02-May-2020
02-0ct-2019
27-Nov-2019

Calibration Notes

The expanded uncertainty of flow, temperature, and pressure measurements all have a coverage factor of k = 2 for a confidence
interval of approximately 95%.

Flow testing is in accordance with our test number PR18-13 with an expanded uncertainty of 0.18% using high-purity nitrogen or
filtered laboratory air. Flow readings in seem are performed at STP of 21.1 °C and 760 mmHg.

Pressure testing is in accordance with our test number PR18-11 with an expanded uncertainty of 0.16 mmHg.

Temperature testing is in accordance with our test number PR18-12 with an expanded uncertainty of 0.04 °C.

Traceability to the International System of Units (SI) is verified by accreditation to ISO/IEC 17025 by NVLAP under NVLAP Code
200661-0.

Technician Notes:
By:

Mohammed Aziz

Director of Engineering

Mesa Laboratories, Inc., Butler, NJ

M = 0.99698188
B = 0.0064171pm
R2 = 0.99999

Use uncorrected readings for
CASTNET range



2 of 2

Mesa Laboratories Inc. 10 Park Place Butler, NJ 07405 USA
(973) 492-8400 FAX (973) 492-8270 www.mesalabs.com Symbol "MLAB" on the NAS

CAL02-48 Rev G05


-------
~

MesaLabs

As Shipped Calibration Data

v ^

\ £



ram/&£5)

NVLAP Lab Code 200661-0
Calibration

Instrument Reading

25266 sccrn
5043.7 seem
1513.7 seem
21.6 °C
748 mmHg

281467

Lilifuww"Malinowska

Lab Standard Reading
25112.5 seem
5001.35 seem
1501A seem
21.6 °C
748 mmHg

Deviation
0.61 %
0.85%
0.82%

Lab, Pressure 748 mmHg
Lab.Temperature 21.6 °C

Allowable Deviation

1.00%

1.00%

1.00%

± 0.8°C
± 3.5 mmHg

/»/

ZO&

As Shipped

In Tolerance
In Tolerance
In Tolerance
In Tolerance
In Tolerance

Mesa Laboratories Standards Used

Description
ML-800-44

Percision Thermometer
Precision Barometer

Standard Serial Number

101897

305460

2981392

Calibration Date

01-May-2018

02-0ct-2018
18-Jul-2018

Calibration Due Date

01-May-2019

02-0ct-2019
18-Jul-2019

Calibration Notes

The expanded uncertainty of flow, temperature, and pressure measurements all have a coverage factor of k = 2 for a confidence
Interval of approximately 95%.

Flow testing is in accordance with our test number PR18-13 with an expanded uncertainty of 0.18% using high-purity nitrogen or
filtered laboratory air. Flow readings in seem are performed at STP of 21.1 °C and 760 mmHg

Pressure testing is in accordance with our test number PR18-11 with an expanded uncertainty of 0 16 mmHg

Temperature testing is in accordance with our test number PR18-12 with an expanded uncertainty of 0.04 °C.

Traceability to the International System of Units (SI) is verified by accreditation to ISO/IEC 17025 by NVLAP under NVLAP Code
200661-0.

Technician Notes:
By:

m -

b -

r2-

- 7.4S"i1



Mohammed Aziz

Director of Engineering

Mesa Laboratories, Inc., Butler, NJ



2 of 2

Mesa Laboratories Inc. 10 Park Place Butler, NJ 07405 USA
(973) 492-8400 FAX (973) 492-8270 www mesalabs com Symbol "MLAB" on the NAS

CAL02-4-S Rev G05


-------
~

MesaLabs



1 O



(7

NVLAP Lab Code 200661-0
Calibration



CertificateNo.

281467

Calibration Certificate
Sold To:

rodtict	200-220H Definer 220 High Flow

Serial No. "isie
Cal. Date D8-Feb-2019

Environmental Engineering & Measurement
Services

8010 SW 17th Place
Gainesville, FL 32607
US

All calibrations are performed at Mesa Laboratories, Inc.. 10 Park Place, Butler, NJ, 07405, an ISO 17025:2005 accredited laboratory
through NVLAP of NISI. This report shall not be reproduced except in full without the written approval of the laboratory. Results only
relate to the items calibrated. This report must not be used to claim product certification, approval, or endorsement by NVLAP, NIST, or
any agency of the Federal Government.

As Received Calibration Data

Technician

Instrument Reading
0 seem
0 seem
0 seem
22 2 °C
759 mmHg

Lilianna Malinowska

Lab Standard Reading
25111.5 seem
5001.3 seem
1501 seem
22.3 °C
757 mmHg

Deviation
-100.0%
-100.0%
-100.0%

Lab. Pressure
Lab. Temperature

757 mmHg
21.6 °C

Allowable Deviation
1.00%

1.00%

1.00%

± Q,8°C
± 3.5 mmHg

As Received
Out of Tolerance
Out of Tolerance
Out of Tolerance
In Tolerance
In Tolerance

Mesa Laboratories Standards Used

Description
ML-800-44

Pereision Thermometer
Precision Barometer

Standard Serial Number

103521

305460

2981392

Calibration Date
11-Jun-2018
02-0ct-2018
18-Jul-2018

Calibration Due Date
11-Jun-2019
02-0ct-2019
18-Jul-2019

Mesa Laboratories Inc. 10 Park Place Butler NJ 07405 USA
(973) 492-8400 FAX (973) 492-8270 www mesalabs.com Symbol "MLAB" on the NAS

1 of2	CAL02-48 Rev G05


-------
fct^" Z ^

~

MesaLabs

As Shipped Calibration Data

&

0

\HU



~ZO

OWlL&E)

NVLAP Lab Code 200661-0
Calibration

Certificate No
Technician

Instrument Reading

25125 seem
5004.1 seem
1502.7 seem
20.6 °C
746 mmHg

287690

Lilianna Malinowska

Lab Standard Reading
25097.5 seem
5001 seem
1500.3 seem
20.6 °C
746 mmHg

Lab. Pressure
La b. Tern p e rat u re

746 mmHg
20.6 °C

Deviation
0.11%

0.06%
0.16%

Allowable Deviation

1.00%

1.00%

1.00%

± 0.8°C
±3.5 mmHg

As Shipped
In Tolerance
In Tolerance
In Tolerance
In Tolerance
In Tolerance

Mesa Laboratories Standards Used

Description
ML-800-44

Pereision Thermometer
Precision Barometer

Standard Serial Number

101897

305460

2981392

Calibration Date

01-May-2018

02-0et-2018
IS-Jul-2018

Calibration Due Date

01-May-2019

02-0ct-2019
1 S-Jul-2019

Calibration Notes

The expanded uncertainty of flow, temperature, and pressure measurements all have a coverage factor of k = 2 for a confidence
interval of approximately 95%.

Flow testing is in accordance with our test number PR18-13 with an expanded uncertainty of 0.18% using high-purity nitrogen or
filtered laboratory air. Flow readings in seem are performed at STP of 21.1 °C and 760 mmHg.

Pressure testing Is in accordance with our test number PR18-11 with an expanded uncertainty of 0.16 mmHg

Temperature testing is in accordance with our test number PR18-12 with an expanded uncertainty of 0.04 °C.

Traceability to the International System of Units (SI) is verified by accreditation to ISO/IEC 17025 by NVLAP under NVLAP Code
200661-0.

Technician Notes:
By:

Mohammed Aziz

Director of Engineering

Mesa Laboratories. Inc., Butler, NJ

ivy

h '
rv



I.

- ' I, % 3

0-Hci

CO i' c-C-C-

icX

for

Mesa Laboratories Inc. 10 Park Place Butler. NJ 07405 USA
(973) 492-8400 FAX (973) 492-8270 www.mesalabs.com Symbol "MLAS" on the NAS

:1C



2 of 2

CAL02-48 Rev G0S


-------
%

YOUNG

R.M. Young Company

2801 Aero Park Drive
Traverse City, Michigan 49686 USA

• A N

1/

CERTIFICATE OF CALIBRATION AND TESTING

Model: 18802/18811
Serial Number: CA04353 /

Description: Anemometer Drive - 2 motors, 20 to 15,000 RPM

(18802 comprised of 18820A Control Unit and 18830A Motor Assembly)
(18811 comprised of 18820A Control Unit and 18831A Motor Assembly)

R. M. Young Company certifies that the above equipment was inspected and calibrated prior to shipment in
accordance with established manufacturing and testing procedures. Standards established by R.M. Young
Company for calibrating the measuring and test equipment used in controlling product quality are traceable to the
National Institute of Standards and Technology.

Nominal
Motor RPM
RPM

27106D Output
Frequency
Hz (1)

Calculated
RPM (2)

Indicated
RPM (3)

18802 [3 Clockwise and Counterclockwise rotation verified.

300

50

300

300

2700

450

2700

2700

5100

850

5100

5100

7500

1250

7500

7500

10200

1700

10200

10200

12600

2100

12600

12600

15000

2500

15000

15000

18811 PI Clockwise and Counterclockwise rotation verified.

30.0

5

30.0

30.0

150.0

25

150.0

150.0

300.0

50

300.0

300.0

450.0

75

450.0

450,0

600.0

100

600.0

600.0

750.0

125

750.0

750.0

990.0

165

990.0

990.0

(1)	Measured output frequency of YOUNG model 27106D standard anemometer attached to motor
shaft.

(2)	YOUNG model 27106D produces 10 pulsed per revolution of the anemometer shaft.

(3)	Indicated on the Control Unit LCD.

* Indicates out of tolerance.

[ I New Unit	P] Service / Repair Unit	I I As found

0 No calibration adjustments required	Q As left

Traceable frequency meter used for calibration:
Model: 34405A

Serial Number: TW46290020

Date: 16 April 2019
Calibration Interval: One year_

Tested By:	6-0

METEOROLOGICAL INSTRUMENTS

Tel: 231-946-3980 Fax:231-946-4772 Email: met.sales@youngusa.com Website: youngusa.com

ISO 9001:2008 CERTIFIED


-------
Ozone Transfer Standard Verification Summary Report

I I

U. S. Environmental Protection Agency
Region 4 Science and Ecosystem Support Division
Enforcement and Investigations Branch
Superfund and Air Section
980 College Station Rd.

Athens, GA 30605



SESD Project#:
Test #:

19-0229
# 1

"as left"

EPA
Standard

EPA Region 4
Keith Harris
INI ST
SRP
10

Guest Test Status:
Guest Known Offset:

Agency:
Contact:
Make:
Model:
S/N:

GUEST
Instrument

EEMS
Eric Hebert
TEI

49 iQps

1180930075

PASS



Level 2 Slope Intercept
Averages: 1.0080 -0,4021

R^ High 03 Lower 03

C|.9999972 465 0

Upper Tolerahce:
LowerToleranVe:

/

,







/



Upper

Lower











Range

Range

Cycle Start Date / Time

File Name

Slope

—Thtercept

R2

{ppb O,)

(ppb Os)

3/25/19 4:13 PM

Cal19032501.xls

1.0014

-0.5404

0.9999967

463

-0.14

3/25/19 5:54 PM

Cal19032502.xls

1.0020

-0.5316

0.9999971

465

-0.06

3/25/19 7:31 PM

Cal19032503.xls

1.0132

-0.4537

09999977

467

-0.17

3/25/19 9:09 PM

Cal19032504.xls

1.0121

-0.3056

09999979

466

-0.20

3/25/19 10:45 PM

Cal19032505.xls

1.0140

0.0000

09999975

464

0.12

3/26/19 12:22 AM
/ 3/26/19 1:59 AM

Cal19032600.xls

1.0057

-0 4967

0 9999960

465

0.05

Cal19032601.xls

1.0073

-0.4869

0.9999976

465

0.14

Comments:

New Level 2 standard Prior to test one instrument was adjusted to more closely match the SRP.
Ozone calibration factors at time of test: 03 BKG 0.31 ppb Q3COEF: 1.013

Verification Expires oft:

March 26, 2020

Keith Harris

/)

Date



Page 1 of 1

SESDFORM-046-R0


-------
Ozone Transfer Standard Verification Summary Report

/?
I 33

I.

SSI?

r>,	r s

PRO^

Uil

oj

pV

SESD Project #:
Test #:

U, S, Environmental Protection Agency
Region 4 Science and Ecosystem Support Division
Enforcement and Investigations Branch
Superfund and Air Section
980 College Station Rd.

Athens, GA 30605

#1

"as found"

EPA
Standard

EPA Region 4
Mike Crowe
NIST
SRP
10

Guest Test Status:
Guest Known Offset:

Agency:
Contact:
Make:
Model:

S/N:

GUEST
Instrument

EEMS

Eric Hebert

Thermo

49i

1180030022
PASS
0

£¦ t

iOiltt





and "as left"

Level 2

Slope

Intercept



Averages:

0.9984

0.2709



Upper Tolerance:

1.0300

3.0000



LowerTolerance:

0.9700

-3.0000

R5

0.9999986

High 03

363

Lower

0

Cycle Start Date / Time

File Name

Slope

Intercept

R2

6/11/19 5:01 PM

Cal19061101.xls

0,9984

0.2057

0.9999981

6/11/19 6:37 PM

Cal19G611Q2.xls

0.9975

0.3485

0.9999992

6/11/19 8:13 PM

Cal19061103.xls

0.9992

0.1985

0.9999984

6/11/19 9:50 PM

Cal19061104.xls

0.9980

0.3826

0.9999987

6/11/19 11:26 PM

Cal190611G5.xls

0.9991

0.0000

0.9999981

6/12/19 1:02 AM

Cal19061200.xls

0.9983

0.3572

0,9999990

6/12/19 2:39 AM

Cal19061201.xls

0.9986

0.4040

0.9999988

Upper
Range
(ppb 03)

360
363

363

364

364

365
365

Lower
Range
(ppb

0.2.
-0.0
0.1:
-0.1
-0.1
0.1:

-o.o

Comments:

Instrument tested as found.

Ozone calibration factors at time of test:

03BKG: -0.4 ppb 03 COEF: 0.990

Instrument within tolerance

Verification Expires oi^:

June 12,2020
September 12, 2019

(For NPAP use)

Mike Crowe

Date

!^2l

Page 1 of 1

SESDFORM-046-R0


-------
Ozone Certification Records

TEI # 49CPS-70008-364 49 CPS

settings at time of test:

EPA file	date	start time

EEMS# 01110
bkg= 0.0

slope

Van 2
coef= 1.018

intercept

correlatioin location

call9102801
call9102802
call9102803

28-Oct-19
28-Oct-19
28-Oct-19

17:34
18:47
20:03

1.00336
1.00323
1.00334

-0.10250
-0.06933
-0.03624

R-7
R-7
R-7
R-7
R-7
R-7
R-7
R-7

AVG =

1.003310

-0.069357

TEI #1180030022	49i

settings at time of test:

EPA file	date	start time

EEMS# 01114
bkg= -0.4

slope

Van 3
coef= 0.990

intercept

correlatioin location

call9102902
call9102803
call9102904

29-Oct-19
29-Oct-19
29-Oct-19

11:19
12:32
13:44

0.98637
0.98590
0.98574

0.39175
0.47568
0.38138

R-7
R-7
R-7
R-7
R-7
R-7
R-7
R-7

AVG =

0.986003

0.416270


-------
FINAL SUMMARY AUDIT REPORT CO BASED
EEMS Van-3

Site Name: EPA R-7 - LOW









Audit Date:

10/28/2019

Parameter

NPAP Lab Response
(ppm)

Station Response
(ppm)

Percent
Difference

Actual
Difference
(ppm)

Pass/Fail

Warning

Ozone













Pre Zero













Ozone audit level 6









N/A



Ozone audit level 5









N/A



Ozone audit level 4









N/A



Ozone audit level 3









N/A



Ozone audit level 2









N/A



Post Zero













Carbon Monoxide













Pre Zero

-0.0069

0.003



0.00976

Pass



CO Audit level 4

2.6066

2.576

-1.2

-0.03039

Pass



CO Audit level 4

1.5093

1.495

-1.0

-0.01476

Pass



CO Audit level 3

0.5511

0.554

0.5

0.00303

Pass



CO Audit level 2

0.1390

0.143

2.9

0.00402

Pass



CO Audit level 1

0.0465

0.055

18.2

0.00847

Pass



Post Zero

-0.0036

0.002



0.00516

Pass



Oxides of Nitrogen

Pre Zero

-0.00020

0.00000



0.00020

Pass

NO Audit Point #1

0.07600

0.07460

-1.8

-0.00140

Pass

NO Audit Point #2

0.04400

0.04360

-0.9

-0.00040

Pass

NO Audit Point #3

0.01607

0.01580

-1.7

-0.00027

Pass

NO Audit Point #4

0.00405

0.00410

1.2

0.00005

Pass

NO Audit Point #5

0.00136

0.00140

2.9

0.00004

Pass

Post Zero

-0.00010

0.00000



0.00010

Pass

Pre Zero

-0.00020

0.00000



0.00020

Pass

NOx Audit Point #1

0.07732

0.07450

-3.6

-0.00282

Pass

NOx Audit Point #2

0.04477

0.04340

-3.1

-0.00137

Pass

NOx Audit Point #3

0.01635

0.01570

-4.0

-0.00065

Pass

NOx Audit Point #4

0.00412

0.00400

-2.9

-0.00012

Pass

NOx Audit Point #5

0.00138

0.00130

-5.8

-0.00008

Pass

Post Zero

-0.00011

0.00000



0.00011

Pass













Pre Zero

0.00000

-0.00010



-0.00010



N02 Audit level 5

0.04930

0.04760

-3.4

-0.00170

Pass

N02 Audit level 4

0.01818

0.01690

-7.0

-0.00128

Pass

N02 Audit level 2

0.00435

0.00390

-10.3

-0.00045

Pass

N02 Audit level 1

0.00159

0.00140

-11.9

-0.00019

Pass

Post Zero

0.00000

0.00000



0.00000

Pass

Converter Efficiency N02 level 5

101.7%







Pass

Converter Efficiency N02 level 4

100.6%







Pass

Converter Efficiency N02 level 2

102.5%







Pass

Converter Efficiency N02 level 1

100.0%







Pass

Sulfur Dioxide











Pre Zero

-0.00022

0.0000



0.0003

Pass

S02 Audit level 6

0.08235

0.0790

-4.1

-0.0033

Pass

S02 Audit level 5

0.04768

0.0455

-4.5

-0.0022

Pass

S02 Audit level 4

0.01741

0.0167

-4.3

-0.0007

Pass

S02 Audit level 2

0.00439

0.0040

-10.0

-0.0004

Pass

S02 Audit level 1

0.00147

0.0014

-5.4

-0.0001

Pass

Post Zero

-0.00011

0.0001



0.0002

Pass


-------
FINAL SUMMARY AUDIT REPORT CO BASED
EE MS Van-2

Site Name: EPA-R7 - LOW	Audit Date: 10/29/2019

Parameter

NPAP Lab Response
(ppm)

Station Response
(ppm)

Percent
Difference

Actual
Difference
(ppm)

Pass/Fail Warning

Ozone











Pre Zero











Audit Level 6









N/A

Audit Level 4









N/A

Audit Level 3









N/A

Audit Level 2









N/A

Post Zero











Carbon Monoxide











Pre Zero

0.0011

-0.010



-0.01065

Pass

CO Audit level 4

2.2014

2.257

2.5

0.05562

Pass

CO Audit level 4

1.5373

1.550

0.8

0.01272

Pass

CO Audit level 3

0.6120

0.617

0.8

0.00501

Pass

CO Audit level 3

0.3315

0.334

0.8

0.00255

Pass

CO Audit level 1

0.0544

0.064

17.6

0.00960

Pass

Post Zero

-0.0115

-0.006



0.00532

Pass

Oxides of Nitrogen











Pre Zero

0.00003

0.0000



0.0000

Pass

NO Audit Point #1

0.06568

0.0666

1.4

0.0009

Pass

NO Audit Point #2

0.04586

0.0457

-0.3

-0.0002

Pass

NO Audit Point #3

0.01826

0.0182

-0.3

0.0000

Pass

NO Audit Point #4

0.00989

0.0090

-9.0

-0.0009

Pass

NO Audit Point #5

0.00162

0.0021

29.6

0.0005

Pass

Post Zero

-0.00034

0.0001



0.0004

Pass













Pre Zero

0.00003

0.0000



0.0000

Pass

NOx Audit Point #1

0.06563

0.0665

1.3

0.0009

Pass

NOx Audit Point #2

0.04583

0.0455

-0.7

-0.0003

Pass

NOx Audit Point #3

0.01825

0.0180

-1.4

-0.0003

Pass

NOx Audit Point #4

0.00988

0.0098

-0.8

-0.0001

Pass

NOx Audit Point #5

0.00162

0.0020

23.5

0.0004

Pass

Post Zero

-0.00034

0.0000



0.0003

Pass

Pre Zero

0.00000

-0.00010



| -0.00010

Pass

N02 Audit level 5

0.04552

0.04530

-0.5

-0.00022

Pass

N02 Audit level 4

0.01853

0.01840

-0.7

-0.00013

Pass

N02 Audit level 3

0.00694

0.00670

-3.5

-0.00024

Pass

N02 Audit level 1
Post Zero

0.00257
0.00000

0.00350
-0.00010

36.2

J 0.00093

Pass
Pass



I -0.00010

Converter Efficiency N02 level 5	99.1 %	Pass

Converter Efficiency N02 level 4	99.5%	Pass

Converter Efficiency N02 level 3	100.0%	Pass

Converter Efficiency N02 level 1	103.9%	Pass

Sulfur Dioxide

Pre Zero
S02 Audit level 6
S02 Audit level 5
S02 Audit level 4
S02 Audit level 4
S02 Audit level 1
Post Zero

0.00003
0.06637
0.04635
0.01845
0.00999
0.00164
-0.00035

0.00006
0.06771
0.04638
0.01845
0.00980
0.00207
0.00004

2.0
0.1
0.0
-1.9
26.2

0.00003
0.00134
0.00003
0.00000
-0.00019
0.00043
0.00039

Pass
Pass
Pass
Pass
Pass
Pass
Pass


-------
FINAL SUMMARY AUDIT REPORT CO BASED
EE MS Van-2

Site Name: EPA-R7 - LOW	Audit Date: 10/29/2019

Parameter

NPAP Lab Response
(ppm)

Station Response
(ppm)

Percent
Difference

Actual
Difference
(ppm)

Pass/Fail Warning

Ozone











Pre Zero











Audit Level 6









N/A

Audit Level 4









N/A

Audit Level 3









N/A

Audit Level 2









N/A

Post Zero











Carbon Monoxide











Pre Zero

0.0011

-0.010



-0.01065

Pass

CO Audit level 4

2.2014

2.257

2.5

0.05562

Pass

CO Audit level 4

1.5373

1.550

0.8

0.01272

Pass

CO Audit level 3

0.6120

0.617

0.8

0.00501

Pass

CO Audit level 2

0.1275

0.129

1.5

0.00190

Pass

CO Audit level 1

0.0544

0.064

17.6

0.00960

Pass

Post Zero

-0.0115

-0.006



0.00532

Pass

Oxides of Nitrogen











Pre Zero

0.00003

0.0000



0.0000

Pass

NO Audit Point #1

0.06568

0.0666

1.4

0.0009

Pass

NO Audit Point #2

0.04586

0.0457

-0.3

-0.0002

Pass

NO Audit Point #3

0.01826

0.0182

-0.3

0.0000

Pass

NO Audit Point #4

0.00380

0.0040

5.3

0.0002

Pass

NO Audit Point #5

0.00162

0.0021

29.6

0.0005

Pass

Post Zero

-0.00034

0.0001



0.0004

Pass













Pre Zero

0.00003

0.0000



0.0000

Pass

NOx Audit Point #1

0.06563

0.0665

1.3

0.0009

Pass

NOx Audit Point #2

0.04583

0.0455

-0.7

-0.0003

Pass

NOx Audit Point #3

0.01825

0.0180

-1.4

-0.0003

Pass

NOx Audit Point #4

0.00380

0.0039

2.6

0.0001

Pass

NOx Audit Point #5

0.00162

0.0020

23.5

0.0004

Pass

Post Zero

-0.00034

0.0000



0.0003

Pass













Pre Zero

0.00000

-0.00010



-0.00010

Pass

N02 Audit level 5

0.04565

0.04530

-0.8

-0.00035

Pass

N02 Audit level 4

0.01858

0.01840

-1.0

-0.00018

Pass

N02 Audit level 3

0.00697

0.00670

-3.9

-0.00027

Pass

N02 Audit level 1









N/A

Post Zero

0.00000

-0.00010



-0.00010

Pass

Converter Efficiency N02 level 5

99.1%







Pass

Converter Efficiency N02 level 4

99.5%







Pass

Converter Efficiency N02 level 3

100.0%







Pass

Converter Efficiency N02 level 1









N/A

Sulfur Dioxide











Pre Zero

0.00003

0.00006



0.00003

Pass

S02 Audit level 6

0.06637

0.06771

2.0

0.00134

Pass

S02 Audit level 5

0.04635

0.04638

0.1

0.00003

Pass

S02 Audit level 4

0.01845

0.01845

0.0

0.00000

Pass

S02 Audit level 2

0.00384

0.00380

-1.0

-0.00004

Pass

S02 Audit level 1

0.00164

0.00207

26.2

0.00043

Pass

Post Zero

-0.00035

0.00004



0.00039

Pass


-------
Field Scientist Certification

EricfjeBert

Has satisfactorily

The US Environmental
"National Performance Audit Program (NPAP)
Field Scientist Re-certification

Office of Air Quality Planning and Standards
Research Triangle Park, NC
Course Dates: October 2-4,2019

Gregory W. Noah
NPAP National Coordinator
USEPA, OAQPS, AAMG


-------
Field Scientist Certification

Korev (Devins

Has satisfactorily

The US Environmental
"National Performance Audit Program (NPAP)
Field Scientist Re-certification

Office of Air Quality Planning and Standards
Research Triangle Park, NC
Course Dates: October 2-4, 2019

Gregory W. Noah
NPAP National Coordinator
USEPA, OAQPS, AAMG


-------
Field Scientist Certification

MgrtjnVaCvur

Has satisfactorily

The US Environmental
"National Performance Audit Program (NPAP)
Field Scientist Re-certification

Office of Air Quality Planning and Standards
Research Triangle Park, NC
Course Dates: October 2-4, 2019

Gregory W. Noah
NPAP National Coordinator
USEPA, OAQPS, AAMG


-------