Methodology
Report for
Inventory of U.S.
Greenhouse Gas
Emissions and
Sinks by State:
1990-2020

EPA-430-R-22-005

U.S. Environmental Protection Agency
Office of Atmospheric Programs
Climate Change Division
August 29, 2022


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Contents

Section	Page

Table of Contents	i

Figures	iv

Tables	v

1	Introduction	1-1

1.1	Areas Where Differences Between State GHG Inventories and the EPA State-Level Estimates

May Occur	1-2

1.2	Institutional Arrangements for Compiling State-Level Inventory Estimates	1-3

1.3	Methods Overview	1-4

1.4	Summary of Updates Since Previous Report	1-5

1.5	Quality Assurance and Quality Control (QA/QC) Procedures	1-6

1.5.1	Peer Review	1-7

1.5.2	State Expert Review	1-7

1.6	Uncertainty	1-8

1.7	Planned Improvements	1-8

2	Energy (NIR Chapter 3)	2-1

2.1	Emissions Related to Fuel Use	2-2

2.1.1	Fossil Fuel Combustion (NIR Section 3.1)	2-2

2.1.2	Carbon Emitted from Nonenergy Uses of Fossil Fuel (NIR Section 3.2)	2-29

2.1.3	Geothermal Emissions	2-32

2.1.4	Incineration of Waste (NIR Section 3.3)	2-33

2.1.5	International Bunker Fuels (NIR Section 3.10)	2-35

2.1.6	Wood Biomass and Biofuels Consumption (NIR Section 3.11)	2-36

2.2	Fugitive Emissions	2-38

2.2.1	Coal Mining (NIR Section 3.4)	2-38

2.2.2	Abandoned Underground Coal Mines (NIR Section 3.5)	2-41

2.2.3	Petroleum Systems (NIR Section 3.6)	2-44

2.2.4	Natural Gas Systems (NIR Section 3.7)	2-48

2.2.5	Abandoned Oil and Gas Wells (NIR Section 3.8)	2-53

3	Industrial Processes and Product Use (IPPU) (NIR Chapter 4)	3-1

3.1 Minerals	3-2

3.1.1	Cement Production (NIR Section 4.1)	3-3

3.1.2	Lime Production (NIR Section 4.2)	3-5

3.1.3	Glass Production (NIR Section 4.3)	3-11

3.1.4	Other Process Uses of Carbonates (NIR Section 4.4)	3-13


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3.1.5 Carbon Dioxide Consumption (NIR Section 4.15)	3-17

3.2	Chemicals	3-18

3.2.1	Ammonia Production (NIR Section 4.5)	3-19

3.2.2	Urea Consumption for Nonagricultural Purposes (NIR Section 4.6)	3-21

3.2.3	Nitric Acid Production (NIR Section 4.7)	3-23

3.2.4	Adipic Acid Production (NIR Section 4.8)	3-25

3.2.5	Caprolactam, Glyoxal, and Glyoxylic Acid Production (NIR Section 4.9)	3-26

3.2.6	Carbide Production and Consumption (NIR Section 4.10)	3-28

3.2.7	Titanium Dioxide Production (NIR Section 4.11)	3-32

3.2.8	Soda Ash Production (NIR Section 4.12)	3-34

3.2.9	Petrochemical Production (NIR Section 4.13)	3-35

3.2.10	HCFC-22 Production (NIR Section 4.14)	3-42

3.2.11	Phosphoric Acid Production (NIR Section 4.16)	3-46

3.3	Metals	3-48

3.3.1	Iron & Steel Production and Metallurgical Coke Production (NIR Section 4.17)	3-49

3.3.2	Ferroalloys Production (NIR Section 4.18)	3-54

3.3.3	Aluminum Production (NIR Section 4.19)	3-57

3.3.4	Magnesium Production and Processing (NIR Section 4.20)	3-60

3.3.5	Lead Production (NIR Section 4.21)	3-63

3.3.6	Zinc Production (NIR Section 4.22)	3-66

3.4	Product Use (Fluorinated Sources, N2O)	3-69

3.4.1	Electronics Industry (NIR Section 4.23)	3-69

3.4.2	Substitution of Ozone-Depleting Substances (NIR Section 4.24)	3-75

3.4.3	Electrical Transmission and Distribution (NIR Section 4.25)	3-78

3.4.4	Nitrous Oxide from Product Uses (NIR Section 4.26)	3-84

4	Agriculture (NIR Chapter 5)	4-1

4.1	Livestock Management	4-1

4.1.1	Enteric Fermentation (NIR Section 5.1)	4-1

4.1.2	Manure Management (NIR Section 5.2)	4-3

4.2	Other (Agriculture)	4-4

4.2.1	Rice Cultivation (NIR Section 5.3)	4-4

4.2.2	Agricultural Soil Management (NIR Section 5.4)	4-6

4.2.3	Liming (NIR Section 5.5)	4-7

4.2.4	Urea Fertilization (NIR Section 5.6)	4-9

4.2.5	Field Burning of Agricultural Residues (NIR Section 5.7)	4-9

5	Land Use, Land-Use Change, and Forestry (NIR Chapter 6)	5-1

5.1.1	Forest Land Remaining Forest Land (NIR Section 6.2)	5-2

5.1.2	Land Converted to Forest Land (NIR Section 6.3)	5-4

5.1.3	Cropland Remaining Cropland (NIR Section 6.4)	5-5


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5.1.4	Land Converted to Cropland (NIR Section 6.5)	5-7

5.1.5	Grassland Remaining Grassland (NIR Section 6.6)	5-8

5.1.6	Land Converted to Grassland (NIR Section 6. NIR Section 6.7)	5-9

5.1.7	Wetlands Remaining Wetlands (NIR Section 6.8)	5-11

5.1.8	Flooded Land Remaining Flooded Land (NIR Section 6.8)	5-17

5.1.9	Land Converted to Wetlands (NIR Section 6.9)	5-18

5.1.10	Settlements Remaining Settlements (NIR Section 6.10)	5-21

5.1.11	Land Converted to Settlements (NIR Section 6.11)	5-27

5.1.12	Other Land Remaining Other Land (NIR Section 6.12) and Land Converted to Other

Land (NIR Section 6.13)	5-28

6 Waste (NIR Chapter 7)	6-1

6.1	Solid Waste Disposal	6-1

6.1.1	Landfills (NIR Section 7.1)	6-1

6.1.2	Composting (NIR Section 7.3)	6-6

6.1.3	Stand-Alone Anaerobic Digestion (NIR Section 7.4)	6-9

6.2	Wastewater Management	6-12

6.2.1 Wastewater Treatment and Discharge (NIR Section 7.2)	6-12

Appendix	A

A: Energy Sector Combustion Estimates	A

B: Energy Sector Fugitive Estimates	A

C: IPPU Minerals Sector Estimates	A

D: IPPU Chemicals Sector Estimates	A

E: Agriculture LULUCF Estimates	A

F: Waste Estimates	A

G: US Population Data Used in Estimates	A

H: IPPU Metals Sector Estimates	A

I: IPPU Product Use Sector Estimates	A

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Figures

Number	Page

Figure 2-1: Adjustments to Energy Consumption for Emissions Estimates	2-3

Figure 2-2: Differences Between State-Level and National Total Energy Use for Coal and Natural Gas	2-6

Figure 2-3: Differences Between State-Level and National Total Energy Use for Petroleum Coke	2-7

Figure 2-4: 2020 Differences Between Sectors for Petroleum Fuels (SEDS—National Inventory)	2-8

Figure 2-5: Adjustments Made to Industrial Sector Energy Use to Account for Emissions Reported in IPPU	2-9

Figure 2-6: Comparison of Gasoline Sector Allocation	2-13

Figure 2-7: Comparison of Diesel Fuel Sector Allocation	2-14

Figure 2-8: Comparison of Transportation Sector Fuel Use	2-15

Figure 2-9: Transportation Sector State-Level Allocation Examples	2-17

Figure 2-10: Adjustments Made to Industrial Sector Energy Use to Account for Emissions Reported as

NEUs	2-19

Figure 2-11: Adjustments Made to Transportation Sector Energy Use to Account for IBFs	2-21

Figure 2-12: Differences in State-Level Total and National Total FFC CO2 Emissions	2-23

Figure 2-13: Mobile Source Non-CCh Calculation Methodology	2-25

Figure 2-14: Adjustments to Energy Consumption for Emissions Estimates	2-30

Figure 2-15: Differences in State-Level and National Total NEU CO2 Emissions	2-32

Figure 3-1: U.S. Transmission Lines Separated by State Using GIS Processing Tool	3-81

iv


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Tables

Number	Page

Table 1-1.	Category Estimates Updated Since Release of Previous Inventory by U.S. State	1-5

Table 2-1.	Overview of Approaches for Estimating State-Level Energy Sector GHG Emissions	2-1

Table 2-2.	Comparison of Approaches/Data Sources Used to Determine FFC Emissions	2-4

Table 2-3:	Default Data Sources for Mobile Source Non-CCh Emissions	2-25

Table 2-4.	Summary of Approaches to Disaggregate Waste Incineration Emissions Across Time Series	2-34

Table 2-5.	Example State Allocation Factors for the Illinois Coal Basin (Sealed Mines)	2-43

Table 3-1.	Overview of Approaches for Estimating State-Level IPPU Sector GHG Emissions	3-1

Table 3-2. Summary of Approaches to Disaggregate the National Inventory for Cement Production

Across Time Series	3-4

Table 3-3. Summary of Approaches to Disaggregate the National Inventory for Lime Production Across

Time Series	3-6

Table 3-4. Summary of Approaches to Disaggregate the National Inventory for Glass Production Across

Time Series	3-11

Table 3-5. Summary of Approaches to Disaggregate the National Inventory for Ammonia Production

Across Time Series	3-19

Table 3-6. Summary of Approaches to Disaggregate the National Inventory for Nitric Acid Production

Across Time Series	3-24

Table 3-7. Summary of Approaches to Disaggregate the National Inventory for Titanium Dioxide

Production Across Time Series	3-33

Table 3-8. Summary of Approaches to Disaggregate the National Inventory for HCFC-22 Production

Across Time Series	3-43

Table 3-9. Facilities Producing HCFC-22 or Destroying HFC-23 Generated During HCFC-22 Production

from 1990 to 2020	3-45

Table 3-10. Summary of Approaches to Disaggregate the National Inventory for Phosphoric Acid

Production Across Time Series	3-46

Table 3-11. Summary of Approaches to Disaggregate the National Inventory for Ferroalloys Production

Across Time Series	3-54

Table 3-12. Summary of Approaches to Disaggregate the National Inventory for Aluminum Production

Across Time Series	3-58

Table 3-13. Summary of Approaches to Disaggregate the National Inventory for Magnesium Production

Across Time Series	3-61

Table 3-14. Summary of Approaches to Disaggregate the National Inventory for Lead Production Across

Time Series	3-64

Table 3-15. Summary of Approaches to Disaggregate the National Inventory for Zinc Production Across

Time Series	3-67

Table 3-16. Summary of Approaches to Disaggregate the National Inventory for Semiconductor and

MEMS Manufacturing Across Time Series	3-70

Table 3-17. Summary of Approaches to Disaggregate the National Inventory for Fluorinated Heat Transfer

Fluids Across Time Series	3-72

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Table 3-18. Summary of Approaches to Disaggregate the National Inventory for Photovoltaics Across Time

Series	3-73

Table 3-19. Summary of Approaches to Disaggregate the National Inventory for Electrical Transmission

and Distribution Across Time Series	3-80

Table 3-20. Summary of Approaches to Disaggregate the National Inventory for Manufacture of Electrical

Equipment Across Time Series	3-82

Table 4-1. Overview of Approaches for Estimating State-Level Agriculture Sector GHG Emissions	4-1

Table 4-2. Approaches to Estimate Enteric Fermentation Methane Across Time Series	4-2

Table 4-3. Approaches to Estimate Manure Management Methane and Nitrous Oxide Across Time Series	4-3

Table 5-1. Overview of Approaches for Estimating State-Level Land Use, Land Use Change and Forestry

Sector Greenhouse Gas Emissions and Sinks	5-1

Table 6-1. Overview of Approaches for Estimating State-Level Waste Sector Greenhouse Gas Emissions

and Sinks	6-1

Table 6-2. Summary of Approaches to Disaggregate the National Inventory for MSW Landfills Across

Time Series	6-2

Table 6-3. Summary of Availability and Sources for Composting Data	6-6

RECOMMENDED CITATION

EPA. 2022. Methodology Report: Inventory of U.S. Greenhouse Gas Emissions and Sinks by State: 1990-2020. U.S.
Environmental Protection Agency, EPA 430-R-22-005. https://www.epa.gov/ghgemissions/state-ghg-emissions-
and-removals

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1 Introduction

This report describes methods used to compile the annual publication of U.S. anthropogenic greenhouse gas
(GHG) emissions and sinks disaggregated by U.S. state consistent with the Inventory of U.S. Greenhouse Gas
Emissions and Sinks (national Inventory hereafter). By April of each year, the U.S. Environmental Protection Agency
(EPA) prepares the official national Inventory, presenting time-series estimates by gas, source/sink, and sector. The
latest annual report includes estimates from 1990-2020 and is available here:

https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks. This state-level report is an
ongoing, complementary publication released annually after the national Inventory report.

The EPA recognizes that a number of states have compiled or are developing their own state-level GHG
inventories on a regular or periodic basis. The state-level inventory data presented here should not be viewed as
official data of any state government, and the EPA provides users information on where they can find official state-
level data from the EPA's website, i.e., please visit https://www.epa.gov/ghgemissions/learn-more-about-official-
state-greenhouse-gas-inventories. In addition, for states where an official inventory is available, links are also
provided with the published state-level data in the EPA's GHG Data Explorer so that when users query information
for a particular state, the link to view the official state inventory will be shown. States themselves may find this
information useful to facilitate comparisons, for quality assurance/quality control (QA/QC), to supplement and
complement existing state efforts, or to serve as official estimates, depending on their own circumstances and
policy needs.

The state-level estimates described in this document are consistent with the national Inventory, meaning they

•	Adhere to international standards, including the Intergovernmental Panel on Climate Changes (IPCC)
Guidelines and United Nations Framework Convention on Climate Change (UNFCCC) transparency
reporting system (i.e., the emissions and removals presented in this report and the report are organized
by source and sink categories within IPCC sectors [energy, industrial processes and product use (IPPU),
agriculture, Land Use, Land-Use Change, and Forestry (LULUCF) and waste] and their respective source
and sink categories).

•	Are based on the same methodologies as the national Inventory and reflect the latest methodological
improvements in the national Inventory, including the use of Greenhouse Gas Reporting Program (GHGRP)
data.

•	Cover the complete time series consistent with the national Inventory, starting with 1990 through the
latest national Inventory year (i.e., 2020).

•	Cover all anthropogenic sources and sinks, and all seven gases (carbon dioxide [CO2], methane [CH4],
nitrous oxide [N2O], hydrofluorocarbons [HFCs], perfluorocarbons [PFCs], sulfur hexafluoride [SFs], and
nitrogen trifluoride [NF3]). The completeness and geographic disaggregation of the report are consistent
with the national Inventory, meaning in addition to estimates for states, the methods also address
emissions and removals occurring in the District of Columbia, U.S. territories, and tribal lands.

•	Estimates were compiled to avoid double counting or gaps in emissions coverage between states. This
ensures that state totals, when summed, will equal totals in the national Inventory. This is important for
those looking for consistent, comparable, and complete state data for analyses and other purposes where
double counting or omissions would be problematic.

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METHODOLOGY DOCUMENTATION

The report's chapters are organized by UNFCCC reporting sectors1 and their respective source and sink
categories. Domestic and international users alike will recognize this format given its long-established use by
countries for UNFCCC reporting. The chapter and category section titles all include a reference to the
corresponding section in the national Inventory report (NIR), e.g., NIR Section 3.1. This is to facilitate
understanding national inventory methods in relation to approaches applied to allocate national emissions to the
state level and, for each category, we recommend reading this report in conjunction with the referenced with
national Inventory sections. Each category section within a chapter includes a background discussion, a description
of methods/approaches, and a discussion of planned improvements. The background includes a brief overview of
the source or sink category consistent with the national Inventory. The methods section includes the approach to
develop state-level estimates and the gases covered. The planned improvements indicate areas for improvement
identified during this first effort to disaggregate state-level emissions and sinks.

1.1 Areas Where Differences Between State GHG Inventories and the EPA State-Level
Estimates May Occur

The EPA recognizes that there will be differences between the EPA's state-level estimates and some inventory
estimates developed independently by individual state governments. Inventories compiled by states may differ for
several reasons and differences do not necessarily mean that one set of estimates is more accurate, or "correct."
The EPA has strived to ensure that the coverage, methodological and accounting approaches are clearly described
so that users can clearly understand differences with how states may compile their inventories. The results should
be viewed as complementary and supplement existing state data.

•	Organization of sectors. The EPA has organized estimates by sector and their respective source and sink
categories consistent with the national Inventory and international reporting guidelines. Standardization
of sectors in international reporting promotes comparability across countries and supports cooperation
on climate action. States may use alternate organization of data, such as economic sectors, for presenting
emissions rather than IPCC sectors. Some states may use IPCC sectors as the basis of their inventory, but
allocate some categories differently across sectors, such as reporting some Industrial Process and Product
Use categories in the Energy sector (e.g., SF6 from electrical transmission and distribution). Comparability
also depends on similar coverage. The completeness and geographic disaggregation of the estimates are
consistent with the national Inventory, meaning in addition to estimates for states, the methods also
address emissions and removals occurring in the District of Columbia, U.S. territories, and tribal lands.

•	Methods and data. In some cases, the EPA may be using different methodologies, activity data, and
emissions factors, or may have access to the latest facility-level information through the EPA's
Greenhouse Gas Reporting Program (GHGRP). The EPA used as a basis, or starting point, the same
methods or methods based on those used to compile the national-level estimates. States may use the
same methods but use different sources of activity data.

•	Accounting approaches. In other cases, states may have adopted different accounting decisions that
differ from those adopted by the IPCC and UNFCCC (e.g., use of different category definitions and
emission scopes consistent with state laws and regulations). For example, the EPA's approach is to focus
on emissions that occur within geographic state boundaries ("Scope 1"), whereas some states include
emissions that are caused by activity within their borders but which actually occur in other states ("Scope

1 The international reporting guidelines under the UNFCCC require reporting of GHG emissions and removals across five sectors:
energy, industrial processes and product use (IPPU), agriculture, land use, land use change and forestry (LULUCF) and waste.
Note, while the UNFCCC reporting guidelines require use of methods from the 2006 IPCC Guidelines for estimating GHG
emissions and removals, they require separate, rather than combined reporting of emission and sinks from agriculture, forestry
and other land use sectors as presented in the IPCC guidelines.

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SECTION 1 — INTRODUCTION

2 or 3") or use consumption-based accounting approaches. For example, some states include emissions
from imported electricity, or electricity production that occurs outside state boundaries. EPA's use of
geographic state boundaries to allocate emissions is consistent with IPCC guidelines.2 Differences in
accounting approaches also include differences in the approach to estimating transportation, cross-
border aviation and marine emissions, or treatment of biogenic CO2. For example, the EPA does not
include biogenic CO2 emissions in state energy sector totals because, in accordance with IPCC
methodological guidelines, CO2 emissions and removals due to the harvesting, combustion and growth of
biomass are included in the carbon stock changes of the relevant land use category of the Agriculture and
LULUCF sectors, where the biomass originates, and inclusion of these emissions in energy sector totals
would result in double-counting.3 Users of state GHG data should take care to review and understand
differences in accounting approaches to ensure that any comparisons of estimates is equivalent or an
apples to apples comparison of estimates.

•	Time series. The EPA has developed state-level estimates for 1990-2020 consistent with the national
Inventory published in April 2022 and current UNFCCC reporting requirements. States may estimate
emissions and sinks over a different time period based on state goals, designation of different base years,
legislation and available state data. Some states may not estimate back to 1990 and include only more
recent years. Other states may have published estimates for earlier years previously, but which have not
been recalculated or otherwise updated in more recent publications despite changes in methods, activity
data, or emissions factors. Similarly, new emissions sources may be added in recent years but not
estimated for more distant years.

•	Global warming potentials (GWPs). States may use different metrics for carbon equivalency of non-CC>2
gases, such as different values for GWPs. Consistent with the national Inventory, in this report the EPA is
using 100-year GWP from IPCC's Fourth Assessment Report (AR4) calculate carbon dioxide equivalency of
non-CC>2 emissions, as required in reporting annual inventories to the UNFCCC. The EPA will be shifting to
use of 100-year GWPs from the IPCC's Fifth Assessment Report (AR5) in 2024 with the first reporting
under the Paris Agreement starting in 2024. Until then, consistent with UNFCCC reporting guidelines the
EPA will continue to use AR4 100-year GWPs.

1.2 Institutional Arrangements for Compiling State-Level Inventory Estimates

In preparing the state-level inventory, the EPA took advantage of existing data arrangements used to compile
the national Inventory (see Chapter 1.2 of the national Inventory). The EPA acknowledges the additional
contributions from the U.S. Department of Agriculture's U.S. Forest Service (USDA-USFS) and National Oceanic and
Atmospheric Administration (NOAA). USDA-USFS has ongoing efforts to prepare state-level data4 to track
emissions and sinks from land use and land use change in forested lands and settlement lands. NOAA has compiled
the state-level emissions and removals from coastal wetlands. The EPA also acknowledges additional effort from
the USDA for providing state-level data on energy use in agriculture and the Department of Energy, Energy
Information Administration, for providing state-level energy use data.

2	Per the 2006 IPCC Guidelines, national inventories include greenhouse gas emissions and removals taking place within
national territory and offshore areas over which the country has jurisdiction with some minor exceptions. For example, an
exception, "C02 emissions from road vehicles should be attributed to the country where the fuel is sold to the end user." See
Volume 1, Chapter 8, Section 8.2.1, on Coverage, available online at: https://www.ipcc-
nggip.iges.or.jp/public/2006gl/pdf/l Volumel/Vl 8 Ch8 Reporting Guidance.pdf.

3	See Q2-10 of Frequently Asked Questions on general guidance and other inventory issues: https://www.ipcc-
nggip.iges.or.ip/faq/faq.html.

4https://www.fs.fed.us/nrs/pubs/download/ru fs307 Appendix2.pdf.

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METHODOLOGY DOCUMENTATION

The EPA also collects GHG emissions data from individual facilities and suppliers of certain fossil fuels and
industrial gases through its GHGRP.5 The GHGRP does not provide full economy-wide coverage of total annual U.S.
greenhouse emissions and sinks (e.g., the GHGRP does not collect data on emissions from the agricultural, land
use, and forestry sectors), but it is an important input to the calculations of state-level estimates in the Inventory.
In general, the threshold for reporting is 25,000 metric tons or more of CO2 equivalent per year. Facilities in most
source categories subject to GHGRP began reporting for the 2010 reporting year, while additional types of
industrial operations began reporting for reporting year 2011. When incorporating this data from GHGRP,
consistent with the national Inventory, EPA considers good practice guidance from the 2019 Refinement to the
2006 IPCC Guidelines (Volume 1, Chapter 2)6 and IPCC's Technical Bulletin on Use of Facility-Specific Data in
National GHG Inventories7 to ensure transparency, completeness, and time series consistency in state-level
estimates.

Data presented in this state-level inventory report and the EPA's GHGRP are complementary. As discussed
across this report, in addition to annual emissions information, the GHGRP also provides other annual information
such as activity data and emissions factors that can improve and refine state-level trends over time. More
information on the relationship between GHGRP and the national Inventory is available online at:
https://www.epa.gov/ghgreporting/greenhouse-gas-reporting-program-and-us-inventorv-greenhouse-gas-
emissions-and-sinks.

1.3 Methods Overview

In developing the state-level estimates consistent with the national Inventory, the EPA used as a basis, or
starting point, the same methods or methods based on those used to compile the national-level estimates. From
this starting point, there were three different approaches taken to arrive at state-level estimates:

•	Approach 1—Estimates were built by applying national methods directly to more geographically
disaggregated data (at state or finer level). For example, estimates of forest land remaining forest land
and lands converted to forestland are built from existing datasets that already disaggregate to the state
level (see Section 5.1.1). Also, portions of fossil fuel combustion emissions were based on the same
approach as the national estimates using state disaggregated energy consumption data (see Section
2.1.1).

•	Approach 2—Estimates were disaggregated from national-level estimates using geographic proxies or
other indicators (i.e., population, production capacity, GHGRP, etc.). This approach was used for
categories where the type of state data used in Approach 1 were not available or were incomplete. For
example, Approach 2 is used to estimate state-level emissions from other process uses of carbonates (see
Section 3.1.4) where state-level population is used as a proxy to allocate national emissions. A key factor
in Approach 2 is how well emissions correlate with proxies, and where multiple options exist, how to
choose among them.

•	Hybrid approach: Under this approach, estimates used a combination of Approach 1 and Approach 2
methods over the time series because data availability limited the use of Approach 1 for all years of the
time series. For example, some estimates may use the EPA's Greenhouse Gas Reporting Program, which
began collecting data in 2010, as a basis for national- and state-level estimates. For these categories, the
EPA uses Approach 1 for 2010-2020 and uses Approach 2 for earlier years of the time series to arrive at
state-level estimates, using IPCC guidance to ensure consistency over the time series to the extent

5	https://www.epa.gov/ghgreporting

6	https://www.ipcc-nggip.iges.or.jP/public/2019rf/pdf/l Volumel/19R VI Ch02 DataCollection.pdf

7	https://www.ipcc-nggip.iges.or.jp/public/tb/TFI Technical Bulletin l.pdf

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SECTION 1 — INTRODUCTION

possible. For example, the Hybrid approach is used to estimate state-level CO2 and PFC emission from
aluminum production (see Section 3.3.3).

Across this report, in addition to a sector-level summary, under each category, the EPA has indicated the
approach used to disaggregate national estimates to the state level. Where appropriate for explaining methods
used under Approach 2 or the Hybrid approach, the EPA has included equations to enhance understanding of the
implementation of disaggregation methods. The EPA has also included data appendices to provide underlying data
to estimate emissions and sinks.

1.4 Summary of Updates Since Previous Report

Each year, many emission and sink estimates in the national Inventory are recalculated and revised, as efforts
are made to improve the estimates through the use of better methods and/or data with the goal of improving
inventory quality and reducing uncertainties, including the transparency, completeness, consistency, and overall
usefulness of the report. The same is the case with state-level estimates where updates were made to improve
inventory quality. In general, when methodological changes have been implemented, the previous Inventory's time
series (i.e., 1990 to 2019) was recalculated to reflect the change. Note that the most common reason for
recalculating national greenhouse gas emission estimates is to update recent historical activity data. Changes in
historical data are generally the result of changes in statistical data supplied by other U.S. government agencies,
and do not necessarily impact the entire time series.

A summary of methodological changes and historical data updates made to the state level data is presented
below by category. Table 1-1 notes whether changes are due to refinements in the national Inventory methods and
data, including new categories, and/or an update due to a refinement in the approach and data used to
disaggregate national estimates to the state level. Note that some category-level changes in absolute state-level
emissions or removals for a state between this version and the previous state report are due to recalculations and
improvements implemented in the national Inventory. In such cases, changes are indicated only in the national-
level column in Table 1-1 below, as the approach to disaggregation of the updated national estimates to the state
level remains unchanged. Categories not listed had no changes for either the national or state-level estimates. See
the recalculations section of each category for more detail on the updates within this report.

Table 1-1. Category Estimates Updated Since Release of Previous Inventory by U.S. State

IPCC
Sector

Category

Changes to Inventory (i.e., Refined
Method/Data or New Category)
National-Level State-Level

E

Fuel Combustion

• •

E

Non-Energy Use of Fuels

•

E

Waste Incineration

• •

E

Coal Mining (inclusion of new subcategory of fugitive CO2
from underground coal mining activities)

•

E

Oil and Gas Systems (inclusion of new subcategory of
post-meter and inclusion of emissions from large
anomalous leak events, such as well blow-outs),
Abandoned Oil and Gas Wells

•

I

Glass Production

•

I

Other Process Uses of Carbonates

• •

I CO2 Emissions from CO2 Consumption •

I Ammonia Production •

I CO2 from Urea Use •

I

Adipic Acid

• •

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METHODOLOGY DOCUMENTATION

IPCC
Sector

Category

Changes to Inventory (i.e., Refined
Method/Data or New Category)
National-Level State-Level

I

CChfrom Carbide Production

•

I

Titanium Dioxide Production

•

I

Petrochemicals

•

I

Phosphoric Acid Production

•

I Iron and Steel Production •

I Aluminum Production •

I

Magnesium Production

• •

I

Lead Production

•

I Zinc Production •

I

Electronics Industry

• •

I ODS Substitutes •

I Electrical Transmission and Distribution •

I

N2O from Product Use

•

A

Enteric Fermentation

•

A

Manure Management

•

A

Agricultural Soil Management

•

A

Liming

•

A

Urea Fertilization

•

L Forest Land Remaining Forest Land •

L Land Converted to Forest Land •

L Land Converted to Cropland •

L Grassland Remaining Grassland •

L Land Converted to Grassland •

L

Wetlands Remaining Wetlands (subcategory peatlands,
new category flooded lands)

• •

L

Land Converted to Wetlands (new category flooded lands)

• •

L

Settlements Remaining Settlements (subcategory N2O
from soils, subcategory landfilled yard trimmings and food
scraps)

• •

L

Land Converted to Settlements

•

W

Landfills

•

W

Composting

•

W

Anerobic Digestion at Biogas Facilities

•

W

Wastewater Treatment and Discharge

• •

E = Energy Sector, IPPU = Industrial Processes and Product Use, A = Agriculture, L = Land Use Change, Land Use Change and
Forestry, W = Waste

1.5 Quality Assurance and Quality Control (QA/QC) Procedures

In disaggregating emissions and sinks from the national Inventory, the EPA implemented QC procedures during
the compilation process to ensure quality, transparency, and credibility of the state GHG data. The EPA
implemented general QC procedures drawn from the existing QA/QC plan8 for the national Inventory to ensure
that data processing and application of methods could easily identify and correct errors (i.e., data/unit
transcription, computation, and trend checks). The EPA also implemented additional category-specific QC

8 See the introduction (Section 1.6) and Annex 8 of the national Inventory for more information on the QA/QC plan available
online at: https://www.epa.eov/gheemissions/inventorv-us-ereenhouse-eas-emissions-and-sinks-1990-2019.

1-6

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SECTION 1 — INTRODUCTION

procedures to assess disaggregation approaches (e.g., comparisons with other data such as available state GHG
inventories) to further review methods estimates, including comparing category estimates to available state GHG
inventories and comparing the sum of State estimates to national estimates. When additional category-specific QC
procedures were implemented, this procedure and findings are discussed in the respective category section.

The EPA also implemented QA procedures outlined by the EPA and IPCC good practices. The EPA conducted a
peer review and state expert review from September 17 to November 1, 2021. Both reviews are described further
below. The QA/QC findings also informed the overall improvement planning, and specific improvements are noted
in the planned improvements sections of respective categories.

1.5.1	Peer Review

The methodology report and the resulting state-level estimates for the 1990-2019 data were independently
peer reviewed in the fall of 2021. Seventeen external experts participated in a process independently coordinated
by RTI International and an EPA peer-review coordinator.

The EPA gratefully acknowledges all the peer reviewers for their useful comments. The peer review report and
responses from EPA are available online here: https://www.epa.gov/ghgemissions/state-ghg-emissions-and-
removals. The information and views expressed in this report do not necessarily represent those of the peer
reviewers, who also bear no responsibility for any remaining errors or omissions. Details describing this review can
be found below. Peer review of the report followed the procedures in the EPA's Peer Review Handbook, 4th
Edition (EPA/100/B-15/001) for reports that do not provide influential scientific information.

The review was managed by a contractor under the direction of a designated EPA peer review leader, who
coordinated the preparation of a peer review plan, the scope of work for the review contract, and the charge for
the reviewers. The peer review leader played no role in producing the draft report. Each sectoral reviewer was
charged with reviewing the Introduction and the sector or subsector of the report relevant to their expertise,
resulting estimates and data appendices. Peer reviewers were charged with making specific comments and edits as
well as providing written response to a set of general and category-specific charge questions. The EPA author team
then responded to and addressed all comments from the peer reviewers in a written summary and revised the
report accordingly.

1.5.2	State Expert Review

Technical staff from each state (e.g., environmental agencies, other state agencies, and/or institutions) were
provided with an opportunity to review the draft data and a draft of this methodology report from July 15-August
16, 2022. The methodology report and state-level estimates were shared with state experts from all 50 U.S. states
and D.C. for review.

The EPA gratefully acknowledges all the state experts for their review. The EPA asked state experts for
feedback on this methodology report, its data appendices and the resulting estimates.

No additional technical comments were received on the draft report. Responses to comments from the
previous review are available here: https://www.epa.gov/ghgemissions/state-ghg-emissions-and-removals. See
category-specific planned improvement discussions throughout this report reflecting updates planned for future
publications of this data.

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METHODOLOGY DOCUMENTATION

1.6	Uncertainty

The EPA has not assessed quantitative uncertainties for the activity data and other parameters used to
estimate state-level emissions for this current publication but has included qualitative information on how
uncertainties compare to those assessed quantitively for each category in the national Inventory.9

The uncertainties of state-level emissions estimates are generally expected to be comparable or higher than
the uncertainties of national-level emissions estimates for two reasons. First, where emissions are estimated at the
national level and then allocated to states based on proxy or surrogate data and indicators other than those used
to estimate emissions (i.e., where Approach 2 is used), uncertainties in the relationship between the allocation
indicator and the emissions increase the uncertainty of the allocation. For example, where total US production is
multiplied by an emissions factor to obtain total national-level emissions, but production capacity rather than
production is used to allocate the US emissions to facilities and states, variation in each facility's capacity
utilization will not be reflected in the estimates, increasing their uncertainty. Second, for some categories where
state-level emissions are estimated using the same facility-based methods as are used for national-level emissions
(i.e., where Approach 1 is used), state-level uncertainties will generally be higher than US-level uncertainties (in
percentage terms), assuming the uncertainties in the estimates for each facility and state are independent of each
other. For example, the EPA estimates the uncertainties in emissions from aluminum production at individual
smelters to be +/-6%, +/-16%, and +/-20% for CO2, CF4, and C2F6 emissions respectively, but when propagated to
the US level across the seven smelters that operated in 2019, these uncertainties decline to -2.3/+2.4% for CO2 and
-7.8/+7.7% for PFCs. Since the states with aluminum production each have just one to two smelters, the
uncertainties in the state-level emissions will be closer to the uncertainties in the emissions for individual smelters
than to the uncertainties in the national-level emissions.

For more information on uncertainties with national-level GHG estimates, see the Section 1.7 of the
Introduction chapter to the national Inventory. Category-specific uncertainties for national estimates are included
in the category-specific methodological discussions across the national Inventory report.

1.7	Planned Improvements

Across the report, per the EPA's quality control and feedback from the previous peer and state reviews, the
EPA has outlined areas for improving future annual publications of this data at the category level across the report.
Based on feedback, the EPA continues to prioritize the following cross-cutting improvements for future annual
publications of this data:

• A key category analysis for each state consistent with IPCC guidance and international reporting
guidelines to help identify categories that are more significant at the state level.

9 Within the Forest Land remaining Forest Land and Lands Converted to Forest Land categories, the U.S. Forest Service has
quantified uncertainties for state-level estimates for net C02 flux from forest ecosystem carbon pools and non-C02 emissions
from forest fires that are the basis for the estimates also in the national Inventory. The quantified uncertainties are available in

1-8

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2 Energy (NIR Chapter 3)

For this methodology report, energy emissions are broken into two main categories: emissions associated with
fuel use (including fossil fuel combustion [FFC] and nonenergy use [NEU]-related emissions) and fugitive emissions
mainly from fuel production. The energy emissions presented here include some categories that are not added to
Energy sector totals in the national Inventory but are instead presented as memo items (including international
bunker fuels10 and biomass emissions11), consistent with UNFCCC reporting guidelines. This approach directly
affects state-level energy sector estimates and, in some cases, may account for differences with official estimates
published by individual state governments. For more information on energy sector emissions, see Chapter 3 of the
national Inventory. Table 2-1 summarizes the different approaches used to estimate state-level energy emissions
and completeness across states. Geographic completeness is consistent with the national Inventory. The sections
below provide more detail on each category.

Table 2-1. Overview of Approaches for Estimating State-Level Energy Sector GHG Emissions

Category

Gas

Approach

Geographic Completeness

Fossil Fuel Combustion

C02,

Hybrid approach

Includes emissions from all states,



CH4,

• Approach 1 used for most

Washington D.C., and territories



l\l20

fuels and sectors
• Approach 2 proxy data used
to allocate national totals for
some fuels and sectors

(i.e., American Soma, Guam, Puerto
Rico, U.S. Virgin Islands, Northern
Mariana Islands and other outlying
minor islands) as applicable.

Non Energy Uses of

CO2

Approach 2

Includes emissions from all states,

Fossil Fuels





Washington D.C., and territories
(i.e., American Soma, Guam, Puerto
Rico, U.S. Virgin Islands, Northern
Mariana Islands and other outlying
minor islands) as applicable.

Geothermal Emissions

CO2

Approach 2

Includes emissions from all states
and Washington D.C. as applicable.1

Incineration of Waste

CO2,

Hybrid approach

Includes emissions from all states



CH4,

• 2011-2020: Approach 1

and Washington D.C. as applicable.1



N2O

• 1990-2010: Approach 2



International Bunker

CO2,

Approach 2

Includes emissions from all states

Fuels (memo item)

cm,

l\l2o



and Washington D.C as applicable.

Wood Biomass and

C02

Approach 2

Includes emissions from all states

Biofuels Consumption





and Washington D.C. as applicable.1

(memo item)







Coal Mining

cm

Approach 1: Active Underground
Mines

Approach 1: Surface Mining and
Post-mining Activities

Includes emissions from all states
and Washington D.C. as applicable.1

10	Emissions from international bunker fuels are not included specifically in summing energy sector totals. The values are
presented for informational purposes only, in line with the 2006 IPCC Guidelines and UNFCCC reporting obligations.

11	Emissions from wood biomass, ethanol, and biodiesel consumption are not included specifically in summing energy sector
totals. The values are presented for informational purposes only, in line with the 2006 IPCC Guidelines and UNFCCC reporting
obligations net carbon fluxes from changes in biogenic carbon reservoirs are accounted for in the estimates for LULUCF.

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METHODOLOGY DOCUMENTATION

Category

Gas

Approach

Geographic Completeness

Abandoned

CH4

Approach 2

Includes emissions from all states

Underground Coal





and Washington D.C. as applicable.1

Mines







Petroleum and Natural

CO2,

Approach 2

Includes emissions from all states,

Gas Systems

ch4,

l\l2o



Washington D.C. and territories
(i.e., American Soma, Guam, Puerto
Rico, U.S. Virgin Islands, Northern
Mariana Islands and other outlying
minor islands) as applicable.1

Abandoned Oil and Gas

C02,

Approach 2

Includes emissions from all states,

Wells

ch4



Washington D.C. and territories
(i.e., American Soma, Guam, Puerto
Rico, U.S. Virgin Islands, Northern
Mariana Islands and other outlying
minor islands) as applicable.1

1 Emissions are not likely occurring in U.S. territories; due to a lack of available data and the nature of this category, territories
not listed are not estimated.

2.1 Emissions Related to Fuel Use

This section presents the methodology used to estimate the fuel use portion of emissions, which consists of
the following sources:

•	FFC (C02, CH4, N2O)

•	Carbon emitted from NEUs of fossil fuels (CO2)

•	Geothermal emissions (CO2)

•	Incineration of waste (CO2, CH4, N2O)

•	International bunker fuels (IBFs) (CO2, CH4, N2O)

•	Wood biomass and biofuels consumption (CO2)

2.1.1 Fossil Fuel Combustion (NIR Section 3.1)

2.1.1.1	Background

Emissions from the combustion of fossil fuels include the GHGs CO2, CH4, and N2O. CChis the primary gas
emitted from FFC and represents the largest share of U.S. total GHG emissions. The methods for estimating CO2
emissions from FFC and the methods used to estimate CH4 and N2O emissions from stationary and mobile
combustion rely in large part on the same underlying data. However, there are some differences; therefore, the
methods used to estimate CO2 and non-CC>2 emissions are presented separately.

2.1.1.2	Methods/Approach

The approach for determining national-level FFC emissions is based on multiplying emissions factors times
activity data on fuel consumption. The activity data on fuel consumption was taken from national-level energy
balances prepared by the U.S. Energy Information Administration (EIA) Monthly Energy Review (MER) estimates
(EIA 2020). The EIA prepares national-level energy statistics that consider energy production imports/exports and
stock changes to determine energy supply/consumption. The fuel consumption information is used as a starting

2-2

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SECTION 2 — ENERGY (NIR CHAPTER 3)

point for determining emissions.12 The approach starts with determining fuel use by fuel type because different
types of fuels have different C content and therefore different emissions factors. The information is also broken
out by energy-consuming sectors of U.S. society to provide more detail and information on trends; the sectors
included are residential, commercial, industrial, transportation, and electric power. Data from U.S. territories were
also included in the analysis as per international reporting requirements. Several adjustments were made to the
data to account for fuel use and emissions that are either excluded or reported in other parts of the national
Inventory, as shown in Figure 2-1.

Figure 2-1: Adjustments to Energy Consumption for Emissions Estimates

Determine Fuel
Use by Type and
Sector

Subtract Fuel Use Subtract Biofuelsand

Adjust Sectoral Allocation Subtract Consumption

Accounted for in
IPPU

Exported C02

of Distillate Fuel Oil and
Motor Gasoline

for Non-Energy Use
(NEU)

International
Bunker Fuel (IBFs)

Calculate non-
C02 Emissions

coking & other coal, natural gas,

asphalt, diesel fuel, HGL,
lubricants, misc prod, naphtha,
other oil, pentanes plus, pet coke,
still gas, special naphtha and waxes

Counted as part of FFC
Counted elsewhere
Reported as memo items
Not part of Inv totals

This section describes how national-level estimates for FFC were disaggregated to the state level for the
following separate sources:

•	FFC C02

•	Stationary non-CCh emissions

•	Mobile non-CCh emissions

This section also discusses how energy use data were broken out at the state level as part of the adjustments
noted in Figure 2-1 and then used to report emissions elsewhere in the national Inventory. Emissions from energy
use that were excluded from FFC are discussed in other sections of the report as follows:

•	Energy used in the IPPU sector—see Chapter 3

•	Biofuel use—see Section 2.1.6

•	NEUs of fuels—see Section 2.1.2

•	IBFs—see Section 2.1.5

12 The energy balance data include information on all energy sources. Emissions estimates exclude data on non-emitting
sources (e.g., nuclear, wind, solar); however, they are considered when looking at overall energy use and efficiency.

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METHODOLOGY DOCUMENTATION

Disaggregating FFC emissions to the state level largely followed the same process and energy consumption
data that are used at the national level. However, in several instances the data used to develop national estimates
are not available at the state level, and additional steps were needed to distribute national-level emissions across
the states while maintaining consistency with national-level totals. Therefore, Approach 3, the Hybrid approach as
described in Section 1.3 of the Introduction chapter, was used to determine state-level emissions for FFC, including
some data that were directly used in the national Inventory and some surrogate data as discussed in the following
sections.

FFC C02 State-Level Breakout

CO2 emissions from FFC at the national level are estimated with a Tier 2 method described by the IPCC in the
2006 IPCC Guidelines for National Greenhouse Gas Inventories (IPCC 2006). As discussed above, this method is
based on multiplying activity data on fuel use (that have been adjusted to allocate and report data consistent with
UNFCCC reporting guidelines and avoid double counting) by emissions factors to determine emissions.

Determining adjusted fuel use activity data is based on the seven steps discussed in Table 2-2. The result of
these seven steps is an adjusted amount of fuel use activity data that are then used to determine FFC CO2
emissions. In Appendix A to this document (included as separate Excel files), the "National 2020 FFC C02" Tab
provides more details on an example of the adjustments made to the national-level energy use data to determine
adjusted fuel use activity data for 2020. Three additional steps (Steps 8-10 in Table 2-2) are required to determine
CO2 emissions in the national Inventory, also discussed below.

Ideally, to determine state-level FFC CO2 emissions estimates, the same approach could be used, and adjusted
energy use, as shown in Appendix A, the "National 2020 FFC C02" Tab, could be developed for each state.
However, the national-level emissions were developed based on multiple factors and inputs, some of which were
not available or readily published at the state level. Therefore, a Hybrid approach was taken where state-level data
were used when available and in cases where state-level data were not available, national-level estimates were
used with available surrogate data to determine state-level percentages of each fuel use. Table 2-2 shows a high-
level comparison of the different data sources used for the different steps to determine national-level and state-
level estimates.

Table 2-2. Comparison of Approaches/Data Sources Used to Determine FFC Emissions

Calculation Step

National-Level Estimates

State-Level Estimates

Determine Activity Data

Step 1: Determine Total

Based on EIA MER

Based on EIASEDS (adjusted to match

Fuel Consumption by Fuel



national totals as applicable)

Type and Sector





Step 2: Subtract Uses that

Taken from industry data or

National-level data allocated to states

are Accounted for in the

based on national-level

based on state-level emissions

IPPU Sector

emissions

estimates for each IPPU category in





question as calculated in Chapter 3

Step 3: Adjust for Biofuels

Based on national-level data

Not needed (see Step 5)

and Petroleum

from EIA MER



Denaturant





Step 4: Adjust for CO2

Based on industry data and

Based on industry data and Canadian

Exports

Canadian import data

import data

Step 5: Adjust Sectoral

Based on bottom-up

National-level data (already excluding

Allocation of Diesel Fuel

transportation sector data on

biofuels) allocated to states based on

and Gasoline

fuel use by vehicle type

state-level fuel use data (not vehicle





specific)

2-4

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Calculation Step

National-Level Estimates

State-Level Estimates

Step 6: Subtract

Based on data from EIA MER

National-level data allocated to states

Consumption for



based on SEDS

Nonenergy Uses (NEUs)





Step 7: Subtract

Based on data from Federal

National-level data allocated to states

Consumption of IBFs

Aviation Administration (FAA)

based on SEDS and other sources



and other national-level





sources



Calculate CO2 Emissions

Step 8: Determine the

National-level average C

National-level average C content values

Carbon content of each

content values



fuel consumed





Step 9: Estimate CO2

Multiply C content by activity

Multiply C content by activity data and

Emissions

data and oxidation percentage

oxidation percentage

Step 10: Allocate

Allocated at the national level

Not done

transportation emissions

based on data from Step 5



by vehicle type





The following discussion details what data were used for each step in Table 2-2 to determine national and
state-level FFC emissions. Appendix A Table A-l in the "State FCC CO2" Tab provides more details on where state-
level data were used directly and where other data were used to make adjustments to disaggregate national
numbers across fuel types and sectors for each of the steps identified.

Step 1: Determine Total Fuel Consumption by Fuel Type and Sector

As discussed above, national-level data on fuel supply/consumption comes from ElA's national energy balance
in the MER. Because not all fuel supplied/consumed directly results in GHG emissions or could be included as part
of other emissions reporting in the national Inventory, adjustments have to be made as shown above and
described in the following steps. State-level energy data are available from the ElA's State Energy Data System
(SEDS). Those data are broken out by fuel type and sector (residential, commercial, industrial, transportation, and
electric power) and are available for the years 1960-2020 (EIA 2022a). SEDS estimates energy consumption using
data from surveys of energy suppliers that report consumption, sales, or distribution of energy at the state level.
Most of the SEDS estimates rely directly on collected state-level consumption data. For example, SEDS uses state-
level sales survey data and other proxies of consumption to allocate the national petroleum product supplied
totals to the states. The sums of the state estimates equal the national totals as closely as possible for each energy
type and end-use sector, and energy consumption estimates are generally comparable to the national statistics in
ElA's MER because both datasets rely largely on the same survey returns for producers and consumers.

However, the totals across all states (and the District of Columbia) from SEDS do not always match the U.S.
total energy data used in the national Inventory, which is based on the EIA February 2022 MER estimates (EIA
2022b). The main differences are for coal and natural gas and primarily in the industrial sector, as shown in Figure
2-2. For coal, there are differences in both energy content and short tons, but the differences are not consistent
across time or sectors. For natural gas, the difference is mainly in the energy content. The reason for the
differences is that SEDS uses state-level energy content conversion factors for coal and natural gas, while the MER
uses national-level conversion factors. This sometimes causes the sums of the SEDS states to be different than the
MER values. Although the percentage differences are not large (max 5.2% and 1.4% for coal and natural gas,
respectively, in the industrial sector), they cause noticeable differences when comparing emissions totals across all
states to national totals, especially by sector.

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METHODOLOGY DOCUMENTATION

Figure 2-2: Differences Between State-Level and National Total Energy Use for Coal and Natural Gas

-100.0

Differences in Coal State Totals vs. National Totals



V

I
/

I



20.0

0.0

-20.0

-40.0

e

o

o

-60.0 §

-100.0

oooooooooo

> Residential (Tbtu)

¦ Electric Power (Tbtu)
1 Industrial ('000 Short Tons)

¦	Commercial (Tbtu)	<
> Residential ('000 Short Tons) <

¦	Electric Power ('000 ShortTons)

¦	Industrial (Tbtu)

¦	Commercial ('000 ShortTons)

Differences in NG State Totals vs. National Totals

150.0

100.0

50.0

0.0

-50.0

-100.0

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cn^aicnai^^cicncD
cncicnffioicnoaicriffi

*H *H *H »

h-ooCTio^rvjm^u-jiDr^oooo

_ OOOrHt—IrHrHrHt—IrHrH*—l*H Industrial (Bill Cu Ft)

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¦ Residential (Bill Cu Ft)
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12.0

10.0

8.0

6.0

4.0

2.0

0.0

-2.0

-4.0

-6.0

-8.0

The petroleum categories generally line up well across state-level and national totals. There are only minor
differences in petroleum coke, mainly in the industrial sector, as shown in Figure 2-3. For petroleum coke, there
are differences in energy content and barrels, but the difference in energy content appears in 2004, which is when
petroleum coke heating values were changed from a constant value to values based on marketable and catalyst
coke. Again, this difference is because of different national-level and state-level conversion factors. Beginning in
2004, the MER uses an annual national-level "quantity-weighted" average petroleum coke conversion factor

2-6

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SECTION 2 — ENERGY (NIR CHAPTER 3)

(instead of a fixed factor). SEDS applies the marketable and catalyst coke conversion factors to the state-level
consumption of each petroleum coke category within each state.

Figure 2-3: Differences Between State-Level and National Total Energy Use for Petroleum Coke

Differences in Pet Coke State Totals vs. National Totals

1.6
1.4
1.2
1.0
0.8
0.6
0.4
0.2
0.0
-0.2

	JD

0.2% of 1 nd Sec total





























	/ I





V —i—h

V / \_ > - v - „

O rl (N rfl	1/1

O*) d 0*1	0*1

d G) G) G) G) G)

N CO (Jl
Cl 
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METHODOLOGY DOCUMENTATION

Figure 2-4: 2020 Differences Between Sectors for Petroleum Fuels (SEDS—National Inventory)

5.0

4.0

3.0

2.0

1.0

£ 0.0
h-

-1.0
-2.0
-3.0
-4.0
-5.0

i

2020 Sectoral Differences in Select Fuels

I

I

I

i

i

fU	TO

O)	CD

50
40
30
20
10
0

-10
-20
-30
-40
-50

Kerosene	Residual Fuel	Lubricants	LPG [Right Axis]

¦ Kerosene ¦ Residual Fuel ¦ Lubricants ¦ LPG [Right Axis]

Furthermore, some of the fuel use reported in SEDS is different from the reporting in the national Inventory.
For example, natural gas reported in SEDS includes supplemental gas, which is included in the national Inventory
under the primary fuel used to make the supplemental gas so including it would result in double counting.

Liquefied petroleum gas (LPG) in SEDS is reported differently over time, including as total hydrocarbon gas liquids
(HGLs) that include natural gasoline (pentanes plus) and as a mix of different gases. Natural gasoline (called
pentanes plus in the national Inventory) is accounted for separately from other HGLs in the national Inventory.
Gasoline and distillate fuels in SEDS include biofuels (fuel ethanol and biodiesel only, renewable diesel and other
biofuels are included in the MER but not estimated in SEDS yet), which were reported separately in the national
Inventory. These differences make it difficult to use the SEDS data directly to determine state-level fuel use data, in
a manner consistent with the national Inventory.

Therefore, the following approach was used in determining fuel use by type by sector at the state level:

•	If SEDS data totals matched the national totals and there were no further adjustments needed (as per
Steps 2-7), the SEDS data were used directly to represent state-level energy use.

•	For fuels where the SEDS totals did not match the national totals (i.e., coal, natural gas, and petroleum
coke), fuel use in each sector was adjusted to match the national totals used in the national Inventory.

This calculation was based on the percentage of each fuel used in each state from the SEDS data. For the
industrial sector, this adjustment was made after subtracting for uses in the IPPU sector (see Step 2
below).

•	For other fuels where sector totals did not match up (e.g., gasoline and diesel fuel), totals for each fuel
type were generally taken from the national Inventory (see Step 5), and the SEDS data or other proxy data
sources were used to determine state-level percentages of each fuel use.

This approach generally results in state-level energy use data that are consistent with national totals used in
the national Inventory. More details on further adjustments made during the different steps are discussed below.

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Appendix A has details on how the SEDS data were adjusted to determine state-level energy use by fuel type
and sector. Tables A-2 through A-6 in the "FFC CO2 Residential" Tab describe the residential sector adjustments.
Tables A-9 to A-13 in the "FFC CO2 Commercial" Tab describe the commercial sector adjustments. Tables A-44
through A-47 in the "FFC CO2 Industrial" Tab describe the industrial sector adjustments for petroleum coke and
HGL, the remaining industrial sector adjustments are described further in Steps 2 and 3 below. Tables A-50 and A-
51 in the "FFC CO2 Transportation" Tab describe the transportation sector adjustments. Tables A-52 to A-56 in the
"FFC CO2 Electricity" Tab describe the electricity production sector adjustments.

Step 2: Subtract Uses That Are Accounted for in the IPPU Sector

In the national Inventory, portions of fuel consumption data for several fuel categories (coking coal, other coal,
natural gas, residual fuel, and distillate fuel) are reallocated from Energy to the Industrial Processes and Product
Use (IPPU) chapter, because these portions were consumed as raw materials during nonenergy-related industrial
processes. As per IPCC Guidelines that distinguish between the Energy and IPPU sector reporting (IPCC 2006,
Volume 3, Chapter 1), emissions from fuels used as raw materials are presented as part of IPPU and are removed
from the energy use estimates. Portions of fuel use were therefore subtracted from the industrial sector fuel
consumption data before determining combustion emissions. Note: Other adjustments were also made to the NEU
calculations to reflect energy use accounted for under IPPU; see Step 6 and the NEU emissions discussion below.

The adjustments vary over time and represent from about 4% to 8% of total unadjusted industrial sector
energy use, as shown in Figure 2-5.

Figure 2-5: Adjustments Made to Industrial Sector Energy Use to Account for Emissions Reported in IPPU

Industrial Sector Energy Use Adjustments for IPPU

1,800

9%

1,600
|> 1,400

 C*) d d

to r--

 CT)



1%

0%

o

1 Amount Removed

i of Unadj Ind. SectorTotal

Adjustments for each fuel type were made based on industry data or assumptions about fuel use based on
emissions reported under IPPU. The following bullets discuss the assumptions made regarding the different
industrial sector fuel types at the national and state levels to reflect their use in IPPU:

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METHODOLOGY DOCUMENTATION

•	Coking coal: Coking coal is used to make coke that, in turn, is used in industrial processes. The national
total amount of coking coal used in IPPU was back-calculated based on the amount of coking coal needed
to make the coke used as input to iron and steel (l&S) and lead and zinc production (the majority ~94% is
used in l&S). National-level coke use in l&S production was based on industry data that are not available
at the state level. Coke used in lead and zinc production was based on the amount of carbon emitted from
the processes and is also not available specifically at the state level. Therefore, the national total amount
of coking coal used in IPPU was allocated per state based on the percentage of total coking coal used per
state from the SEDS data. This approach assumes that coke use in l&S and lead and zinc production is
proportional to the amount of coking coal used in a state. This assumption may not be the case because
state-level coking coal use is based on coke production in a given state, not necessarily coke use. The coke
could be produced in one state and shipped for use in another state. However, given the lack of specific
data, coking coal use was determined to be a good surrogate for coke use within a given state because
coke production is often integrated with l&S production where the coke is used. As one further
adjustment, if the amount of coking coal used in IPPU was greater than the total coking coal reported in
the national energy statistics, the amount of coking coal used in the energy sector results were zeroed out
to avoid negative values (this only occurs in 1990, 1991, 1992, and 1997), and additional other coal use
was subtracted to make up the difference (see other coal below). Appendix A, Tables A-19 and A-20 in the
"FFC C02 Industrial" Tab, describe the coking coal use in IPPU.

•	Other coal: Two adjustments were made to account for other coal used in the industrial sector. The first
adjustment was to subtract the extra amount of coking coal required for years where the coking coal
adjustment was more than coking coal total (see above). Similar to coking coal, this adjustment was based
on the percentage of coking coal consumption per state from SEDS. Appendix A, Tables A-21 and A-22 in
the "FFC C02 Industrial" Tab, describe this adjustment. The second adjustment was to subtract coal used
as direct use in the l&S sector. In addition to being used indirectly to produce coke, coal can be used
directly as a process input to l&S production; note, this does not include coal combusted at l&S facilities
to produce power. National-level other coal used in l&S production was based on industry data that are
not available at the state level. Therefore, this adjustment was based on the percentage of l&S emissions
per state. l&S emissions per state were taken from the IPPU breakout for l&S, as described in Section
3.3.1, and the percentage for basic oxygen furnaces (BOFs) was assumed to best represent other coal use
in l&S. BOF emissions were determined to be a good surrogate for other coal direct use in l&S because
coal is primarily used in the BOF process and would be proportional to emissions from the process.
Appendix A, Table A-24 in the "FFC C02 Industrial" Tab, describes this adjustment. An IPPU-adjusted other
coal total was then calculated by subtracting the adjustments described above (note: this also included
the adjustments for conversion of fuels and C02 exports as described in Step 4 below). Appendix A, Table
A-25 in the "FFC C02 Industrial" Tab, shows this total. The total other coal use was then adjusted to
match the total other coal from the national Inventory (as per Step 1); this adjustment was based on the
percentage of other coal used after the IPPU adjustment. Appendix A, Table A-26 in the "FFC C02
Industrial" Tab, describes this adjustment.

•	Natural gas: Two adjustments were made to account for natural gas used in the industrial sector. The first
adjustment was to subtract the amount of natural gas consumption that was used in ammonia production
from energy sector natural gas use. The national-level natural gas used in ammonia production was back-
calculated based on assumed CO2 emissions from ammonia production and calculations on the amount of
C in natural gas needed to produce those CO2 emissions. Therefore, the state-level natural gas used for
ammonia was based on the percentage of ammonia emissions per state. Ammonia emissions per state
were taken from the IPPU breakout for ammonia, as described in Section 3.2.1. Appendix A, Tables A-27
through A-29 in the "FFC C02 Industrial" Tab, describe this adjustment. The second adjustment was to
subtract natural gas used as direct use in l&S. National-level natural gas used in l&S production was based

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SECTION 2 — ENERGY (NIR CHAPTER 3)

on industry data that are not available at the state level. Therefore, similar to other coal, the adjustment
was based on the percentage of l&S emissions per state from the IPPU breakout for l&S, as described in
Section 3.3.1, and the percentage for BOFs was assumed to best represent natural gas use in l&S. Similar
to other coal direct use, BOF emissions were determined to be a good surrogate for natural gas direct use
in l&S. Appendix A, Table A-30 in the "FFC C02 Industrial" Tab, describes this adjustment. An IPPU-
adjusted natural gas total was then calculated by subtracting the adjustments described above. Appendix
A, Table A-31 in the "FFC C02 Industrial" Tab, shows this total. The total natural gas use was then adjusted
to match the total natural gas use from the national Inventory (as per Step 1); this adjustment was based
on the percentage of natural gas used after the IPPU adjustment. Appendix A, Table A-32 in the "FFC C02
Industrial" Tab, describes this adjustment.

•	Residual fuel: The residual fuel use was adjusted to subtract the amount of residual fuel used in carbon
black production. Carbon black was the only IPPU use of residual oil. The national-level residual oil used in
IPPU was based on NEUs of residual oil from EIA data, which are not available at the state level.

Therefore, the residual oil IPPU state-level adjustment was based on the percentage of carbon black
emissions per state. Carbon black emissions per state were taken from the IPPU breakout for
petrochemicals, as described in Section 3.2.9, and the percentage for carbon black specifically was used.
Carbon black emissions were determined to be a good surrogate for residual oil use because the
emissions from carbon black production would be directly proportional to residual oil use. Appendix A,
Tables A-33 and A-34 in the "FFC C02 Industrial" Tab, describe this adjustment. An IPPU-adjusted residual
fuel total was then calculated. Appendix A, Table A-35 in the "FFC C02 Industrial" Tab, shows this total.
The total residual fuel use was then adjusted to match the total residual fuel from the national Inventory
(similar to what was done for coal and natural gas in Step 1); this adjustment was based on the
percentage of residual fuel used after the IPPU adjustment. This was done because after the adjustment
the residual fuel use summed across states did not match the national totals anymore (likely due to the
distribution of adjustment based on petrochemical production, which resulted in negative emissions in
some states that were then zeroed out). Appendix A, Table A-36 in the "FFC C02 Industrial" Tab, describes
this adjustment.

•	Distillate fuel: Distillate fuel use was adjusted to subtract the amount of distillate fuel used as direct use in
l&S production. National-level diesel fuel used in l&S production was based on industry data that are not
available at the state level. Therefore, similar to other coal and natural gas direct use in l&S, the
adjustment was based on the percentage of l&S emissions per state from the IPPU breakout for l&S, as
described in Section 3.3.1, and the percentage for BOFs was assumed to best represent distillate fuel use.
Similar to other coal and natural gas direct use in l&S, BOF emissions were determined to be a good
surrogate for diesel fuel direct use in l&S. Appendix A, Tables A-37 and A-38 in the "FFC C02 Industrial"
Tab, describe this adjustment. An IPPU-adjusted distillate fuel total was then calculated. Appendix A,

Table A-39 in the "FFC C02 Industrial" Tab, shows this total. This total was adjusted further based on
reallocation of diesel fuel use across sectors, as shown in Step 5 below.

Step 3: Adjust for Biofuels and Petroleum Denaturant

Fuel consumption estimates used for CO2 calculations were adjusted downward to exclude fuels with biogenic
origins consistent with the IPCC Guidelines. CO2 emissions from ethanol and biodiesel consumption are not
included in fuel combustion totals in line with the 2006 IPCC Guidelines and UNFCCC reporting obligations to avoid
double counting with net carbon fluxes from changes in biogenic carbon reservoirs accounted for in the estimates
for LULUCF. CO2 emissions from biogenic fuels under fuel combustion are estimated separately and reported as
memo items for informational purposes under the energy sector. Furthermore, for several years of the time series,
denaturant used in ethanol production was double counted in both transportation and industrial sector energy use
statistics. It was therefore subtracted from transportation sector energy use to avoid double counting. Fuels with

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METHODOLOGY DOCUMENTATION

biogenic origins (ethanol and biodiesel) and ethanol denaturant adjustments at the state level are handled by
adjusting gasoline and diesel fuel use based on the total nonbiogenic components of those fuels only, as described
in Step 5 below (which also include any adjustments for denaturant). So, in effect the state-level energy use
calculations used to determine FFC emissions for gasoline and diesel fuel combine this Step 3 with Step 5 below.
See Section 2.1.6 for more detail on biofuel use at the state level used to calculate biomass CO2 as a memo item.

Step 4: Adjust for C02 Exports

Since October 2000, the Dakota Gasification Plant has been exporting CO2 produced in a coal gasification
process to Canada by pipeline. Because this CO2 is not emitted to the atmosphere in the United States, the coal
that is gasified to create the exported CO2 is subtracted from fuel consumption statistics used to calculate
combustion emissions in the national Inventory. Consistent with the approach currently used in the national
Inventory, the coal used to produce exported CO2 from the Dakota gas plant to Canada was subtracted from other
coal use to determine state-level emissions. This was all assumed to be subtracted from North Dakota, the location
of the Dakota gas plant. Appendix A, Table A-23 in the "FFC C02 Industrial" Tab, describes this adjustment.

Step 5: Adjust Sectoral Allocation of Distillate Fuel Oil and Motor Gasoline

Motor gasoline and diesel fuel are used across all sectors. The total amount of motor gasoline and diesel fuel
consumed as reported in the MER is based on petroleum supply data from refineries. Gasoline use is allocated
across the sectors in proportion to aggregations of categories reported by the U.S. Department of Transportation,
Federal Highway Administration (FHWA), Highway Statistics data (FHWA 2021). Diesel fuel use is allocated to the
electric power sector based on industry surveys. The remaining diesel fuel use is allocated across the remaining
sectors in a similar way to gasoline use based on sales data to different categories from ElA's Fuel Oil and Kerosene
Sales (FOKS) data (EIA 2022c). For the national Inventory, data are needed on fuel use by vehicle type to determine
emissions, so a bottom-up method is used to estimate transportation sector gasoline and diesel fuel use. The
national Inventory determines gasoline and diesel fuel use by vehicle type based on FHWA and DOE data (FHWA &
DOE, numerous years). The national Inventory then allocates the remaining fuel use to the remaining sectors based
on the proportions in the EIA data. The differences in the EIA and national Inventory gasoline and diesel fuel
allocation approach across sectors are shown in Figure 2-6 and Figure 2-7, including information on the categories
of use included in each sector and data for 2020 as an example.

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Figure 2-6: Comparison of Gasoline Sector Allocation

From the MER, Based or
Refinery Supply Data

EIA National Energy Balance

From FHWA Data

National Sector Split

I Commercial Sector



Public non-highway

105,450

Lawn and garden*

3,028,675

Misc.

27,062

Non-Transportation
Percent

Sector Total: 3,161,187





I 2020 ('000 Gal) | % Of Total I

Ag 134,866

Total Supply | 2020 ('000 Gal)

Construction

389,428

Motor Gasoline 123,729,228

~]ndr&Tommi—

Sector Total:

1,766,839

2,291,133" * 1.8

Transportation Sector 2020 ('000 Gal) % of Total



Highway

117,251,028



Boating

X£326,171



Rec. vehicles*

1,691,458.

Commercial Sector 2020 ('000 Gal)

Motor Gasoline

Industrial Sector	2020 ('000 Gal)

Motor Gasoline



Sector Total: 121,268,627

Motor Gasoline	118,410,516

* Note FHWA added the lawn and garden and recreational vehicle use categories in 2015 which causes a time series discontinuity in the split
between the different sectors. EPA for the national Inventory back calculated fuel use for those categories and adjusts the FHWA data accordingly.

| Total

| 2020 ('000 Gal) |

Motor Gasoline

126,720,947

From the MER, Based on
Refinery Supply Data

EPA National Inventory

From FHWA& DOT Data

Non-Transportation
Percent from EIA

National Sector Split

| Total Supply

| 2020 ('000 Gal) |

Motor Gasoline

123,729,228



Automobiles

75,875,710

Motorcycles

408,026

Buse^v

107,183

Light Trucks

35,845,026

Other Trucks\

5,015,083

Boats (Recreational)

. 1,251,125

Sector Total: ' 118,502,153

1 Commercial Sector

2020 ('000 Gal) 1

v-

Motor Gasoline

3,027,787



1 Industrial Sector

2020 ('000 Gal) 1

Motor Gasoline

2,199,288

Motor Gasoline	118,502,153

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METHODOLOGY DOCUMENTATION

Figure 2-7: Comparison of Diesel Fuel Sector Allocation

From the MER,
Based on Refinery
Supply Data

From Electric
Power Data

Remaining
57,875,580

—bihiiBsrai

Diesel Fuel 58.198.392

EIA National Energy Balance

From FOKS Data

Residential Sector 2020 ('000 Gal) % of Total

Residential

Commercial Sector

Commercial

Industrial Sector

industrial
Oil Co.

^arm

Off-Highway

National Sector Split

Non-Transportation
Non-Electric Percent
MMHH-ffiMiMJ.III.I.I.IJM



1,531,770
405,313
3,730,779
~~~2;2H,974

ector Total: 7,879,836

Transportation Sector 2020 ('000 Gal) % of Total

Highway
Railroad
Bunkering
Military

40,790,502
^2^59,907
1,81(^8.64
159,160 \

Sector Total: 45,726,433	78.0

Total	2020 ('000 Gal)

Industrial Sector 2020 ('000 Gal)

Diesel Fuel

m—mm

45,116,820

WiUJ.IU,!,!.IJW

322,812

From the MER,
Based on Refinery
Supply Data

From Electric
Power Data

Remaining
57,875,580

EPA National Inventory

Non-Transportation
From FHWA / DOT Data Non-Electric Percent

NationalSectorSplit





1 K!wiTffiT!T!Teffw

Diesel Fuel



2,715,679











Diesel Fuel



1,843,285

\

Industrial Sector 1

2020 ('000 Gal)

l		

Diesel Fuel 7,119,863

| Transportation Sector

| 2020 ('000 Gal) |

Passenger Cars

364,462

\

Buses

1,604,585

Light-Duty Trucl<5\

1,439,641

Medium- and Heav^pDuty Trucks

38,524,772

Recreational Boats \

271,704

Ships and Non-Recreational Boats

788,379

Rail

, 3,203,210
46,196,753	

Sector Total:

«Wi—

46,196,753









Diesel Fuel

322,812

Diesel Fuel

322,812

The bottom-up approach used by the national Inventory to determine transportation sector fuel use generally
results in less allocation of gasoline to the transportation sector (and more to other sectors) and more diesel fuel
allocated to the transportation sector (and less to other sectors) compared with the original MER energy balance
data as shown in Figure 2-8.

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Figure 2-8: Comparison of Transportation Sector Fuel Use

Differences in Transportation Sector Gasoline Use

200
100
0

-100
-200
-300
-400
-500
-600
-700
-800

ipmHij





I 	

OrHfNm^LntDr-OOCTiO
Os)ChOsiO,i0^dOsiO^OsiOsiO
oioioiaiffiaiciijiijiffi

Lnr^cocriOrH
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METHODOLOGY DOCUMENTATION

the total was based on FHWA form MF-225, and the motor gasoline total was based on FHWA form MF-
226, both of which have time series of fuel use by state. Appendix A, Tables A-48 and A-49 in the "FFC
C02 Transportation" Tab, describe this adjustment. The FHWA data reflect on-highway fuel use, but, as
seen in Figure 2-6 and Figure 2-7, the transportation sector fuel use includes some mobile sources that
are considered off-highway (e.g., recreational boating, railroads). However, because the majority of the
motor gasoline and diesel fuel use is for on-highway purposes, using FHWA data to allocate transportation
sector fuel use to the state level is reasonable. Note that FHWA state-level fuel consumption data are
representative of the point-of-sale and not the point-of-use, so fuel sold in one state that may be
combusted in other states is assigned to the state where the fuel was purchased. This approach is
consistent with IPCC Guidelines (IPCC 2006) for country-level reporting that indicate that "where cross-
border transfers take place in vehicle tanks, emissions from road vehicles should be attributed to the
country where the fuel is loaded into the vehicle." Therefore, when applying the IPCC approach to the
state-level inventory, vehicle emissions are attributed to the state where the vehicle fuel is sold. This
approach could introduce some differences in state-level transportation sector fuel use and emissions
allocations reported here and those reported by individual states. For example, in addition to fuel sales
data, state-level vehicle miles traveled (VMT) data are another potential surrogate for allocating fuel use
to the state level, but that approach does not account for vehicle and fleet fuel economy variability
between states. The EPA will consider alternative or complementary approaches to allocate
transportation fuel across states, including VMT data and other sources (e.g., NEI—based on county-level
fleet and activity data to generate a bottom-up inventory [NEI 2017]).13 Figure 2-9 shows the
transportation sector emissions in 201714 from the top 10 emitting states using different allocation
approaches. As seen in the figure, the approach used will lead to different allocations across states.

13	Note the NEI uses a bottom-up method for determining transportation sector fuel use and emissions based on VMT and
assumed vehicle fleet fuel efficiency, etc., at the county level through the MOVES model. However, that approach if applied
across all states could lead to differences with national totals. The approach used here is to allocate national totals to states
and not perform a bottom-up analysis for each state.

14	2017 is shown because that is the latest year of NEI data that are produced every 3 years.

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Figure 2-9: Transportation Sector State-Level Allocation Examples

2017 Transportation Sector Emissions (Top 10 States)

250.0

200.0

150.0

¦ Inv/FHWA ¦ Fuel/EIA ¦ VMT ¦ NEI

•	Residential sector: The total amount of distillate fuel used in the residential sector was taken from the
national Inventory totals. It was allocated across states based on the percentage of existing fuel use in the
residential sector per state from SEDS. Appendix A, Tables A-7 and A-8 in the "FFC C02 Residential" Tab,
describe this adjustment. Based on the reallocation of sector fuel use, the residential sector fuel use from
the national Inventory is different from the value in SEDS; therefore, the state-level allocation from SEDS
may not represent exactly the fuel values from the national Inventory. However, residential sector fuel
use represented by the national Inventory should be consistent with what is included in SEDS (e.g., home
heating); therefore, the SEDS state-level breakout is assumed to be representative.

•	Commercial sector: The total amount of distillate fuel and motor gasoline used in the commercial sector
was taken from the national Inventory totals. It was allocated across states based on the percentage of
existing fuel use in the commercial sector per state from SEDS. Appendix A, Tables A-14 to A-18 in the
"FFC C02 Commercial" Tab, describe this adjustment. Based on the reallocation of sector fuel use, the
commercial sector fuel use from the national Inventory is different from the value in SEDS; therefore, the
state-level allocation from SEDS may not represent exactly the fuel values from the national Inventory.
However, commercial sector fuel use represented by the national Inventory should be consistent with
what is included in SEDS (e.g., construction equipment); therefore, the SEDS state-level breakout is
assumed to be representative.

•	Industrial sector: The total amount of distillate fuel and motor gasoline used in the industrial sector was
taken from the national Inventory totals. Distillate fuel was allocated across states based on the
percentage of existing fuel use in the industrial sector per state after the IPPU adjustments described in
Step 2. Motor gasoline was allocated across states based on the percentage of existing fuel use in the
industrial sector per state from SEDS. Appendix A, Tables A-40 and A-43 in the "FFC C02 Industrial" Tab,
describe this adjustment. Based on the reallocation of sector fuel use, the industrial sector fuel use from
the national Inventory is different from the value in SEDS; therefore, the state-level allocation from SEDS
may not represent exactly the fuel values from the national Inventory. However, industrial sector fuel use
represented by the national Inventory should be consistent with what is included in SEDS (e.g., process
energy use); therefore, the SEDS state-level breakout is assumed to be representative.

•	Electric power sector: The total amount of distillate fuel used in the electric power sector was taken from
the national Inventory totals. It was allocated across states based on the percentage of existing fuel use in

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METHODOLOGY DOCUMENTATION

the electric power sector per state from SEDS. Appendix A, Tables A-57 and A-58 in the "FFC C02
Electricity" Tab, describe this adjustment. The electric power sector fuel use was not adjusted in the
national Inventory compared with what is represented in SEDS; therefore, the SEDS state-level breakout is
considered representative.

Step 6: Subtract Consumption for NEU

The energy statistics include consumption of fossil fuels for nonenergy purposes. Most fossil fuels consumed
are combusted to produce heat and power. However, some are used directly for noncombustion use as
construction materials, chemical feedstocks, lubricants, solvents, and waxes.15 For example, asphalt and road oil
are used for roofing and paving, and hydrocarbon gas liquids are used to create intermediate products. In the
national Inventory, emissions from these NEUs are estimated separately under the Carbon Emitted and Stored in
Products from NEUs source category. Therefore, the amount of fuels used for nonenergy purposes needs to be
subtracted from fuel consumption data for determining combustion emissions.

The adjustments vary over time and represent from about 25% to 30% of total unadjusted industrial sector
energy use, as shown in Figure 2-10.

15 Under IPCC Inventory guidance, emissions from these noncombustion sources should be reported as part of IPPU. However,
because of national circumstances and the inability to separate these uses from the national energy balance, the United States
reports these emissions as part of energy. This is an area for future planned improvement as part of the national Inventory, and
any updates will be carried over to the state-level reporting.

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Figure 2-10: Adjustments Made to Industrial Sector Energy Use to Account for Emissions Reported as

NEUs

Industrial Sector Energy Use Adjustments for NEU

7,000

6,000

QJ

c 5,000

<§ 4,000

"O

d)

2 3,000

¦i—»

_o

Z5

(jO

w 2,000

-t-"

CD
H

1,000

35%

30%

5%

0%

z>

&


o

OHNm'fLniDNMIJlOHlNm'Jl^iDhCOaiOHlNrO't

cncnosicricno^cr)crichcri000000000000005-jc_)c_j^c_)t_)t_)
HHHHplrlrlrlrlHfM(N(NN(N(NMlN(NN(N(N(N(N(N(N(NfM(N(NN

LTJ ID N 00 CJ1 O
I T—I T—I <—I  of Unadj Ind. Sector Total

Adjustments for each fuel type were made at the national level based on data and assumptions from the EIA
as used in the national energy balance. More detail on the amount and types of fuels used for NEU at the national
level are shown in Appendix A in the "National 2020 NEU C02" Tab.

The following approaches were taken to determine the amounts of different fuels used for NEUs that needed
to be subtracted from energy combustion estimates at the state level. The subtractions were all made in the
industrial sector except for lubricants; those subtractions were used in both the industrial and transportation
sectors and for NEU from territories:

•	Coking coal: As per the national Inventory, the amount of coking coal used for NEUs was determined to be
the total of the adjusted coking coal (after subtracting for IPPU use, as per Step 2). Therefore, the state-
level totals from Step 2 for coking coal were used to represent NEUs. Appendix A, Table A-59 in the "NEU"
Tab, shows this state-level breakout.

•	Other coal: The coal used to produce synthetic natural gas at the Eastman gas plant (based on data from
the national Inventory) was assumed to be used for chemical feedstock and therefore was accounted for
under NEU. This other coal NEU was allocated across states by assuming it all occurred in Tennessee, the
location of the Eastman facility. Appendix A, Table A-60 in the "NEU" Tab, shows this state-level breakout.

•	Natural gas: The total national-level amount of natural gas used for NEUs was taken from the national
Inventory (based on data from EIA) and represents natural gas used for chemical plants and other uses.
Natural gas used for NEUs was allocated across states based on the percentage of petrochemical
emissions per state. This is an area where there was not any specific data on natural gas used for NEU in
chemical plants and other uses by state. Using petrochemical emissions to allocate natural gas NEU use by
state was considered a reasonable approach as emissions are a good indication of petrochemical
production in a state, and therefore a good indication of how much NEU fuel was used in that state.

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METHODOLOGY DOCUMENTATION

Petrochemical emissions per state were taken from the IPPU breakout for petrochemicals, as described in
Section 3.2.9, and the total percentage for all petrochemicals was used. Appendix A, Table A-61 in the
"NEU" Tab, shows this state-level breakout.

•	LPG, pentanes plus, still gas, and petroleum coke: The national-level amount of these fuels used for NEUs
was taken from the national Inventory (from EIA data) and assumed to be used primarily as chemical
feedstocks. The amount of NEUs was allocated across states based on the percentage of each total fuel
use in the industrial sector per the original state-level data from SEDS. This approach assumes that the
percentage of these fuel products used in NEU applications per state are proportional to the overall or
other, fuel combustion, uses of these fuel products in a given state. This assumption was felt to be
reasonable as the fuel and NEU applications of these fuel products are likely to be in the same types of
chemical facilities. Appendix A, Table A-63, Table A-64, Table A-65, Table A-69, Table A-70, Table A-71 and
Table A-72 in the "NEU" Tab, show these state-level breakouts.

•	Distillate fuel: The total national-level amount of distillate fuel used for NEUs was taken from the national
Inventory (based on data from EIA). Distillate fuel used for NEUs was allocated across states based on the
percentage of distillate fuel use in the industrial sector per state after IPPU adjustments described in Step
2. As per the previous group of fuel products, this approach assumed that the percentage of distillate fuel
used in NEU applications per state is proportional to the overall or other, fuel combustion, uses of
distillate fuel in a given state. The national-level data on distillate fuel used in NEU applications are based
on industry surveys for nonfuel uses in the chemical industry. Therefore, the assumption that NEUs of
distillate fuel are proportional to the total industrial sector amount of distillate fuel use in a given state
may not be completely representative because other or fuel uses of distillate fuel in the industrial sector
could be very broad. However, it was felt to be a reasonable approach because specific state-level
distillate fuel used in NEU applications was not readily available and the percentage of NEUs of distillate
fuel was a small fraction of overall industrial sector distillate fuel use (less than 1%). The EPA will continue
to examine other possible sources for distillate fuel NEU state-level data for future reports. Appendix A,
Table A-74 in the "NEU" Tab, shows this state-level breakout.

•	Asphalt and road oil, lubricants (in both industrial and transportation sector), naphtha (<401 deg. F), other
oil (>401 deg. F), special naphtha, waxes and miscellaneous products: As per the national Inventory, the
total amounts of these fuel products were all assumed to be used in NEUs. Therefore, the total state-level
data from SEDS were used to represent NEUs for these fuel products. Appendix A, Table A-62, Table A-66,
Table A-67, Table A-68, Table A-73, Table A-75, Table A-76 and Table A-77 in the "NEU" Tab, show these
state-level breakouts.

Emissions associated with NEUs were calculated and reported separately from FFC emissions. Some further
adjustments were made to NEU energy use, and carbon factors were applied; see further discussion in Section
2.1.2 below.

Step 7: Subtract Consumption of International Bunker Fuel

The energy statistics include consumption of fossil fuels that are ultimately used for international bunkers. In
the national Inventory, emissions from bunker fuel consumption are not included in national totals and are instead
reported separately as a memo item, as required by the IPCC and UNFCCC inventory reporting guidelines. There
are other international organizations, including the International Civil Aviation Organization (ICAO) and the
International Maritime Organization (IMO), that consider global action from these sectors. Therefore, the amount
of each fuel type used for international bunkers was subtracted from fuel consumption data when determining
fuel combustion emissions. The adjustments vary over time and represent about 4% to 7% of total unadjusted
transportation sector energy use as shown in Figure 2-11.

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Figure 2-11: Adjustments Made to Transportation Sector Energy Use to Account for IBFs

Transportation Sector Energy Use Adjustments for IBFs

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Adjustments for each fuel type were made at the national level based on data and assumptions from different
data sources, including FAA flight data and information on international shipping; see the national Inventory report
for more details. More details on the amount and types of fuels used for IBFs at the national level are shown in
Appendix A in the "National 2020 FFC C02" Tab.

The following approaches were taken to determine the state-level amount of different fuels used for IBFs that
needed to be subtracted from energy combustion estimates. The subtractions were all made in the transportation
sector:

•	Residual fuel and distillate fuel: The total national-level amount of residual and distillate fuel used for IBF
was taken directly from the national Inventory (IBF subtractions). The fuels used for IBF were allocated
across states based on the percentage of fuel use for bunkers from the EIA FOKS data (EIA 2022c). This
approach was considered reasonable because the FOKS data have information directly on bunker fuel
used at the state level. Appendix A, Table A-78 and Table A-79 in the "IBF" Tab, show these state-level
breakouts.

•	Jet fuel: The total national-level amount of jet fuel used for IBF was taken directly from the national
Inventory (IBF subtractions). Jet fuel used for IBF was allocated across states based on the percentage of
total jet fuel use in the transportation sector by state per the original state-level data from SEDS.

Appendix A, Table A-80 and Table A-81 in the "IBF" Tab, show the state-level breakout data on jet fuel
specifically used for international flights were difficult to find at the state level. The approach used here to
allocate bunker fuels by state based on the total amount of jet fuel used by state could potentially lead to
an overestimation of bunker fuel emissions for some states with below average international flight
activity or underestimation for other states with significantly greater than average international flight

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METHODOLOGY DOCUMENTATION

activity. This is an area of future planned improvements. Also note that this adjustment is for IBFs. Fuel
use and emissions from interstate flights are still included in the national- and state-level FFC emissions.
They were allocated to the state where the jet fuel is purchased/sold as per the SEDS data.

The result of these previous seven steps is an adjusted amount of fuel use activity data that is then used to
determine FFC CO2 emissions. Three additional steps are then required to determine CO2 emissions discussed
further below.

Step 8: Determine the Carbon Content of All Fuels

To determine emissions, the amount of carbon per unit of energy in each fuel was needed. Because different
fuels have different C contents, a different factor was determined for each fuel type. The total C estimate defines
the maximum amount of C that could potentially be released to the atmosphere if all of the C in each fuel was
converted to CO2. Fuel-specific carbon content coefficients for each fuel type were taken from the national
Inventory; see Annex 2 of the national Inventory for more details on carbon factors used. The national total factors
for each fuel used in the national Inventory were applied for fuel use at the state level. This was considered a
reasonable assumption since fossil fuels are widely traded and regulated, and carbon contents within the United
States do not vary appreciably. Two possible exceptions to this are coal and gasoline where state-specific carbon
contents could vary based on the type of coal used and the gasoline blend and grade used. Those fuel emissions
factors in the national Inventory were based on weighted averages of state-level factors. For these factors, the EPA
will look into using specific state-level factors in the state-level estimates in future reports.

Step 9: Estimate C02 Emissions

Total CO2 emissions for each fuel are the product of the adjusted energy consumption (from the previous
methodology Steps 1-7), the carbon content of the fuels consumed (from Step 8), and the fraction of C that is
oxidized. Carbon emissions were multiplied by the molecular-to-atomic weight ratio of CO2 to C (44/12) and the
fraction of carbon that was oxidized to obtain total CO2 emitted from FFC. The fraction oxidized was assumed to be
100% for petroleum, coal, and natural gas.

State-level fuel use by fuel type per sector from Steps 1-7 was multiplied by national-level carbon factors from
Step 8 (and also multiplied by molecular weight ratios and oxidation fractions) to determine state-level emissions
by fuel type and by sector.

Step 10: Allocate Transportation Emissions Step 10: Allocate Transportation Emissions by Vehicle Type

As discussed in Step 5 above, fuel use at the national level was determined by specific vehicle type in the
transportation sector because non-CC>2 emissions differ by vehicle type and activity data were needed by vehicle
type to use higher tier methods for non-CC>2 emissions. The national Inventory is, therefore, also able to provide
the same level of detail for CO2 emissions by specific vehicle type from transportation. For fuel types other than jet
fuel, fuel consumption data by vehicle type and transportation mode were used to allocate emissions by fuel type
calculated for the transportation end-use sector in the national Inventory. However, as also discussed in Step 5
above, state-level information on fuel use by vehicle type was not readily available. For CO2 emissions, vehicle type
is not critical for determining emissions because they are based primarily on fuel use; therefore, vehicle type by
state was not specifically needed for the state-level calculations, and a state-level CO2 emissions breakout by
vehicle type was not done at this time. This is an area of future planned improvements.

The above calculations resulted in state-level GHG estimates that generally add up to the total estimates in
the national Inventory with small differences occurring at the more disaggregated sector level, as shown in Figure
2-12 for FFC CO2 emissions. The differences are due to the vintage of the different data sources used. As discussed
above in Step 1, the national Inventory was based on the February 2022 MER, while the state-level values were
based on the April 2022 SEDS. The SEDS used updated information on the sector allocation of some fuels, which

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SECTION 2 — ENERGY (NIR CHAPTER 3)

will be reflected in the next national Inventory report. There is also a minor difference in total emissions due to the
differences in emissions factors for LPG across sectors. The updated SEDS data shows more LPG in the industrial
sector, which has a higher emissions factor than LPG use in other sectors, so the result is slightly higher total
emissions in the state-level estimates. The percentage differences in the 2020 sector totals are small (a 0.8%
difference in the residential sector, a 0.8% difference in the commercial sector, a 0.1% difference in the industrial
sector, and a 0.02% difference in the transportation sector). The percentage difference in total emissions is also
very minor, a 0.002% difference.

Figure 2-12: Differences in State-Level Total and National Total FFC CO2 Emissions

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METHODOLOGY DOCUMENTATION

Stationary Non-CO2 State-Level Breakout

Stationary non-CC>2 emissions include CFU and N2O emissions from four energy consumption sectors
(residential, commercial, industrial, and electric power) and four fuel types (coal, fuel oil, natural gas, and wood).

Non-CCh emissions from FFC at the national level were estimated in line with Tier 1 and 2 methods described
by the IPCC in the 2006IPCC Guidelines for National Greenhouse Gas Inventories (IPCC 2006). For most categories,
a Tier 1 approach was used, which multiplies the adjusted activity data on fuel use by default emissions factors to
determine emissions. The electric power sector used a Tier 2 approach that relied on the adjusted fuel use activity
data and country-specific emissions factors by combustion technology type.

National-level emissions for all sectors were allocated across states based on the same percentage as CO2
emissions from those sectors and fuel types as described in the previous section. Appendix A, Table A-89 through
Table A-104 in the "Stationary non-C02" Tab, show the percentage breakout of each fuel across sectors that were
used in the analysis. For the residential, commercial, and industrial sector, it is reasonable to assume non-CC>2
emissions by fuel type would be proportional to CO2 emissions across states because the fuel use activity data are
the same and only one non-CC>2 emissions factor was applied per fuel type per category for each gas.

Electric power sector non-CC>2 emissions could differ across states based on the type of combustion
technology used, but the analysis was not able to assess these potential differences. The overall impact of these
simplifying assumptions on total state combustion emissions is expected to be small.

Mobile Non-C02 State-Level Breakout

Mobile non-CC>2 emissions include CFU and N2O emissions. National-level estimates of CFU and N2O emissions
from mobile combustion are calculated by multiplying emissions factors by measures of activity for each fuel and
vehicle type (e.g., light-duty gasoline trucks). Activity data include VMT for on-road vehicles and fuel consumption
for nonroad mobile sources. State-level mobile non-CC>2 emissions were calculated for four main categories of
mobile source emissions: gasoline highway, diesel highway, alternative fuel highway, and nonhighway. More detail
on the approach and what is included under each of the categories is shown in Figure 2-13 (EPA 2020).

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Figure 2-13: Mobile Source Non-C02 Calculation Methodology

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The approach was to develop state-level estimates by fuel type/category and use those estimates to develop
the percentage of emissions by state. The percentage of emissions by state were then applied to the national
totals from the national Inventory to disaggregate national totals at the state levei. Table 2-3 shows the default
data type and source used in developing the state-level estimates. Appendix A, Table A-105 through Table A-116 in
the "Mobile non-C02" Tab, show the percentages of emissions by vehicle type by state that were used in the
analysis.

Table 2-3: Default Data Sources for Mobile Source Non-COa Emissions

Source/Category	Type of Input	Default Source

Highway Vehicles-

ChUand N2O emissions factors (g/km

Not state specific, using national factors;

Emissions Factors and

traveled) for each type of control

see Annex 3,2 of the national Inventory

VMT

technology





State total VMT, 1990-present, for all

VMT by state for each year from FHWA



vehicle types

Table VM-2. Apportioned to vehicle type
based on national vehicle type
distributions from FHWA Table VM-1. The
fuel type distribution within each vehicle
type (i.e., the distribution between

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METHODOLOGY DOCUMENTATION

Source/Category

Type of Input

Default Source





gasoline and diesel) was taken from the





national Inventory

Highway Vehicles-

Annual vehicle mileage accumulation

Not state specific, using national factors;

Allocating VMT by

(miles) for each model year in use and

see Annex 3.2 of the national Inventory

Model Year

age distribution of vehicles (%) in the
current year



Highway Vehicles-

Percentage of vehicles with each control

Not state specific, using national factors;

Allocating Control

type, 1960-present

see Annex 3.2 of the national Inventory

Technology by Model





Year





Aviation

N2O and CH4 emissions factors (g/kg fuel)

Not state specific, using national factors;



for each type of fuel

see Annex 3.2 of the national Inventory



Aviation fuel consumption (million BTU),

EIASEDS (EIA 2022a)



1990-present by fuel type



Marine

N2O and CH4 emissions factors (g/kg fuel)

Not state specific, using national factors;



for each type of fuel

see Annex 3.2 of the national Inventory



Marine fuel consumption (gallons), 1990-

Gasoline from FHWA Highway Statistics,



present

Table MF-24, boating column, other fuels
from EIASEDS

Locomotive

N2O and CH4 emissions factors (g/kg fuel)

Not state specific, using national factors;



for each type of fuel

see Annex 3.2 of the national Inventory



Locomotive fuel consumption (gal or

EIA FOKS



tons), 1990-present



Other Nonhighway

N2O and CH4 emissions factors (g/kg fuel)

Not state specific, using national factors;



for diesel and gasoline tractors,

see Annex 3.2 of the national Inventory



construction equipment, and other





equipment





Fuel consumption (gal), 1990-present, for

Gasoline from FHWA Table MF-24,



agriculture equipment

agriculture column, diesel fuel from EIA
FOKS



Fuel consumption (gal), 1990-present, for

Gasoline from FHWA Table MF-24,



construction equipment

construction column, diesel fuel total
from the national Inventory apportioned
based on gasoline percentage



Fuel consumption (gal), 1990-present, for

Gasoline from FHWA Table MF-24,



other equipment

industrial and commercial column plus
totals from other small sources from the
national Inventory, diesel fuel from EIA
FOKS

Alternative Fuel

CH4 and N2O emissions factors (g/km

Not state specific, using national factors;

Vehicles

traveled) for each type of alternative fuel
(methanol, ethanol, LPG, liquefied natural
gas, compressed natural gas)

see Annex 3.2 of the national Inventory



State total VMT, 1990-present, for

Based on national totals and assumptions



alternative fuel vehicles

on alternative fuel vehicle use by state
from EIA alternative fuel vehicle data

The bottom-up approach to develop mobile source non-CC>2 state-level estimates by fuel type/category
described above results in a different overall emissions total compared with the national Inventory values. That is
why the estimates are used to develop the percentage of emissions by state that are applied to the national totals

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SECTION 2 — ENERGY (NIR CHAPTER 3)

from the national Inventory to disaggregate national totals at the state level. The approach above could also over-
or underestimate emissions by state by assuming a national average of age distribution of vehicles across states
when each state could have a different mix of vehicle fleet age distribution. However, the approach is considered
reasonable, and the overall impact of these simplifying assumptions on state emissions is expected to be small.

Breaking Out Data by Economic Sector

The EIA data used for this analysis report fuel use for five sectors (residential, commercial, industrial,
transportation, and electric power). The reporting of emissions at the state level in this analysis also included
emissions from the combustion of fossil fuels in the agriculture economic sector (which is not the case with the
agriculture sector as defined by the IPCC). Agriculture sector fuel use at the national level was based on
supplementary sources of data because EIA includes agriculture equipment in the industrial fuel-consuming sector.
State-level agriculture fuel use estimates were obtained from USDA survey data, in combination with EIA FOKS
data. Agricultural operations are based on annual energy expense data from the Agricultural Resource
Management Survey (ARMS) conducted by the National Agricultural Statistics Service (NASS) of the USDA. NASS
collects information on farm production expenditures including expenditures on diesel fuel, gasoline, LP gas,
natural gas, and electricity use on the farm with the annual ARMS. A USDA publication (USDA/NASS 2020) shows
national totals, as well as select states and ARMS production regions. State estimates were survey derived for 15
states (AK, CA, FL, GA, IA, IL, IN, KS, MN, MO, NC, NE, TX, WA, and Wl) and model derived for the remaining states
using data and methods developed by the Economic Research Service of USDA.

These supplementary data were subtracted from the industrial fuel use reported by the EIA to obtain
agriculture fuel use. CO2 emissions from FFC and CFU and N2O emissions from stationary and mobile combustion
were then apportioned to the agriculture economic sector based on agricultural fuel use.

2.1.1.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and non-CC>2 emissions from FFC
was calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described further in
Chapter 3 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020
for FFC were -2%/+4% for CO2, -34%/+125% for stationary source CFU, -24%/+51% for stationary source N2O,
-8%/+24% for mobile source CH4, and -8%/+19% for mobile source N2O.

The uncertainty estimates for the national Inventory largely account for uncertainty in the magnitude of
emissions and consider uncertainty in activity data and emissions factors used to develop the national estimates.
State-level estimates of annual emissions will likely have a higher relative uncertainty compared with these
national estimates as a result of the additional requirement in some cases of apportioning national emissions to
each state using spatial proxy and supplemental surrogate datasets. As discussed above, the steps involved in
determining state-level FFC emissions could result in some over- or underestimation of state-level emissions in
some cases. The sources of uncertainty for this category are consistent over time because the same approaches
are applied across the entire time series. As with the national Inventory, the state-level uncertainty estimates for
this category may change as the understanding of the uncertainty of estimates and underlying datasets and
methodologies improves.

2.1.1.4	Recalculations

Consistent with recalculations at the national level, EIA updated energy consumption statistics across the time
series relative to the previous Inventory. For example, propane consumption and the heat content were adjusted
for 2019, which affected LPG by sector in 2019.

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METHODOLOGY DOCUMENTATION

2.1.1.5	Planned Improvements

For coking coal, the percentage subtracted by state could be based on other factors like BOFs l&S production
in each state, as opposed to the percentage of total coking coal use. For all fuels in some cases, a state could have
negative emissions if the amount subtracted determined from assumed distribution was greater than consumption
data from SEDS for that state. This value was corrected to zero if that was the case, but alternative ways to
readjust it across other states will be considered.

For petrochemical feedstocks, natural gas NEU was allocated across states based on GHGRP petrochemicals
emissions data per state, while other fuels NEU use was allocated based on the underlying SEDS data. Allocating
across states based on the underlying SEDS data ensures that in no states is NEU use larger than in the original
SEDS data which, if that was the case, would result in negative numbers associated with subtracting NEU (it is not
an issue for natural gas because use is so high overall compared with NEU). However, the EPA will explore different
percentages or a way to use GHGRP petrochemical data without resulting in negative use in any given state.

The EPA will look into using state-level bottom-up data for bunkers directly from FOKS, as opposed to basing
IBF on top-down estimates from the national Inventory and allocating to states based on the FOKS percentage,
taking into account how FOKS data line up with national Inventory totals. We will look for better ways to allocate
jet fuel bunker data across states as opposed to basing it on percentage of total use, for example, FAA data or
assuming based on states with international airports and flights.

The EPA will look into more state-level activity data for different mobile combustion sources to better allocate
mobile non-C02 emissions.

The coal carbon factors in the national Inventory are based in part on state-level data. It might be possible to
build out weighted state-level coal carbon factors that would still amount to the national totals. For natural gas,
state-level heat content data could be used to develop state-level carbon factors for natural gas, but they would
have to be compared with national totals. It might be possible to develop gasoline and distillate fuel factors per
state for the transportation sector, but we would have to ensure they are consistent with the national-level
factors.

The EPA will look into allocating power sector non-C02 emissions based on other sources like eGRID and EPA
Air Markets Program Data, for instance.

The national Inventory distributes electricity emissions across end-use sectors to present results with
electricity distributed by sector. That calculation was not done at the state level. The national Inventory also breaks
out transportation sector emissions by vehicle type; that calculation was also not done at the state level. The EPA
will look into reporting this disaggregated data in future state-level reports.

2.1.1.6	References

Energy Information Administration. (2022a). EIA State Energy Data System (SEDS), Energy Consumption Data for
1990-2020. Accessed July 2022. Available online at: https://www.eia.gov/State/seds/

Energy Information Administration. (2022b). Monthly Energy Review, February 2022. DOE/EIA-0035(2022/2).
Energy Information Administration, U.S. Department of Energy, Washington, DC.

Energy Information Administration. (2022c). Fuel Oil and Kerosene Sales. Energy Information Administration, U.S.
Department of Energy, Washington, DC. Available online at: http://www.eia.gov/petroleum/fueloilkerosene

Federal Highway Administration. (2021). Highway Statistics. Federal Highway Administration, U.S. Department of
Transportation, Washington, DC. Reports: Private and Commercial Highway Use of Special Fuel, by State,
1949-2020 MF-225, and Highway Use of Gasoline, by State, 1949-2020 MF-226. Released November 2021.
Available online at: https://www.fhwa.dot.gov/policvinformation/statistics.cfm

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SECTION 2 — ENERGY (NIR CHAPTER 3)

Federal Highway Administration. (1996 through 2020). Highway Statistics. (Report FHWA-PL-96-023-annual.)
Federal Highway Administration, U.S. Department of Transportation, Washington, DC. Available online at:
http://www.fhwa.dot.gov/policv/ohpi/hss/hsspubs.htm

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. National Greenhouse Gas Inventories Programme. H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara,
and K. Tanabe (eds.). Hayama, Kanagawa, Japan.

National Emissions Inventory. (2017). 2017 National Emissions Inventory (NEI) Data. Available online at:
https://www.epa.gov/air-emissions-inventories/2017-national-emissions-inventorv-nei-data

U.S. Department of Agriculture, National Agricultural Statistics Service. (2020). Farm Production Expenditures
Annual Summary. National Agricultural Statistics Service, U.S. Department of Agriculture, Washington DC.
Available online at: https://usda.librarv.Cornell.edu/concern/publications/qz20ss48r?locale=en

U.S. Department of Energy. (1993 through 2020). Transportation Energy Data Book. (ORNL-5198). Office of
Transportation Technologies, Center for Transportation Analysis, Energy Division, Oak Ridge National
Laboratory.

U.S. Environmental Protection Agency (2020). User's Guide for Estimating Methane and Nitrous Oxide Emissions
from Mobile Combustion Using The State Inventory Tool. Prepared by: ICF, Prepared for: State Energy and
Environment Program, U.S. Environmental Protection Agency.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 3: Energy. Available online at: https://www.epa.gov/ghgemissions/inventorv-us-
greenhouse-gas-emissions-and-sinks

2.1.2 Carbon Emitted from Nonenergy Uses of Fossil Fuel (NIR Section 3.2)

2.1.2.1	Background

In addition to being combusted for energy, fossil fuels are consumed for NEUs. The fuels used for these
purposes and the nonenergy applications of these fuels are diverse, including feedstocks for the manufacture of
plastics, rubber, synthetic fibers, and other materials; reducing agents for the production of various metals and
inorganic products; and products such as lubricants, waxes, and asphalt. CO2 emissions arise via several pathways.
Emissions may occur during the manufacture of a product, as is the case in producing plastics or rubber from fuel-
derived feedstocks. Additionally, emissions may occur during the product's lifetime, such as during solvent use. As
discussed above in the FFC section, emissions from these NEUs are estimated separately and, therefore, the
amount of fuels used for non-energy purposes are subtracted from fuel consumption data. Given the linkages
between NEUs and combustion emissions, the NEU adjustments and calculations are presented here.

2.1.2.2	Methods/Approach

FFC CO2 emissions calculations discussed above (as per Step 6) were adjusted for fuels used for NEUs. CO2
emissions arise from NEUs via several pathways, including emissions from the manufacture of a product and
during the product's useful lifetime and ultimate disposal. The approach for determining national-level NEU
emissions is based for the most part on multiplying NEU activity data by C contents and assumed C storage factors.
The activity data on NEU by fuel were taken from the FFC adjustments. Then several adjustments were made to
the data to account for fuel exports and IPPU emissions that are either excluded or reported in other parts of the
national Inventory as shown in Figure 2-14. C storage factors are based on the end use of the fuel and assumed
fate of the C in the products. Appendix A in the "National 2020 NEU C02" Tab provides more details on an example
of the adjustments made to the national-level NEU data to determine adjusted NEU activity data for 2020.

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Figure 2-14: Adjustments to Energy Consumption for Emissions Estimates

Determine NEU by	Subtract Fuels	Subtract Fuel Use	Determine C	Calculate C02

Fuel Type and Sector	Exported	Accounted for in	Storage Factor	Emissions

(From Step 6 of FFC)	IPPU

Industrial Sector
NEU

coking & other coal, natural gas,

asphalt, diesel fuel, HGL,
lubricants, misc prod, naphtha,
other oil, pentanes plus, pet coke,
still gas, special naphtha and waxes

natural gas, HGL,
naphtha, other oil,
pentanes plus and
special naphtha

Transportation



Sector NEU

¦



Territories NEU

lubricants and
mic prod

Emissions Key

^ Counted as part of NEU
) Counted elsewhere
) Not part of Inv totals

NEU emissions at the state level were calculated based on the same approach as used to determine national-
level NEU emissions. The following steps describe the approach used to determine state-level NEU emissions.

Step 1: Determine Total NEU by Fuel Type and Sector

State-level NEU energy data by sector and fuel type were calculated from Step 6 of the FFC calculations, as
discussed above. The NEU adjustments to the FFC data were used as the input to the NEU calculations. The same
state-level breakout of the NEU data used in the FFC calculations was used here.

Step 2: Adjust for Portions of NEU in Exported Products

State-level NEU energy data calculated from Step 6 above were adjusted to account for exports. Natural gas,
HGL, pentanes plus, naphtha (<401 °F), other oil (>401 °F), and special naphtha were adjusted down to subtract
out net exports of these products that are not reflected in the raw NEU data from the EIA. Consumption values
were also adjusted to subtract net exports of HGL components (e.g., propylene, ethane). Similar to exported CO2
discussed in the FFC calculations, because any potential CO2 emissions from exported products are not emitted to
the atmosphere in the United States, the fuel that is used to create the exported products is subtracted from
statistics used to calculate NEU emissions. The national-level total export energy adjustment data were taken from
the national Inventory. The export adjustments were allocated to states based on the total amount of NEU fuel use
by state from Step 1 under the simplifying assumption that the share of nonenergy fuels exported matched the
amount of nonenergy fuels used by a given state. This could lead to an over- or underestimation of NEU emissions
in a given state based on the actual amount of product exported. However, it was felt to be a reasonable
assumption given the lack of export data by state and the small overall adjustment made (2020 export adjustments
represent 5.9% of unadjusted nonenergy fuel use). Appendix A, Table A-82 through Table A-86 and Table A-88 in
the "NEU Adj" Tab, show these adjusted totals.

Step 3: Adjust for Portions of NEU Accounted for in IPPU

State-level NEU energy data were also adjusted down to account for other oil (>401 °F) and petroleum coke
use in IPPU. As per Step 2 in the FFC calculations, emissions from fuels used as raw materials presented as part of
IPPU were removed from the NEU estimates. Portions of nonenergy fuel use were, therefore, subtracted from the
industrial sector nonenergy fuel consumption data before determining NEU emissions. The national-level total

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IPPU energy adjustment data for NEU were taken from the national Inventory. The IPPU adjustments were
allocated to states based on the total amount of NEU fuel use by state from Step 1 under the simplifying
assumption that the share of nonenergy fuels used in IPPU matched the amount of nonenergy fuels used by a
given state. This assumption could lead to an over- or underestimation of NEU emissions in a given state based on
the actual amount of fuel used in IPPU. However, it was felt to be a reasonable assumption given the lack of data
by state on NEU fuels used in IPPU and the small overall adjustment made (2020 IPPU adjustments represent 1.1%
of unadjusted NEU fuel use). Appendix A, Table A-86 and Table A-87 in the "NEU Adj" Tab, show these adjusted
totals.

Step 4: Determine C Storage Factor by Fuel Type

CO2 emissions can arise from NEUs via several pathways. Emissions may occur during the manufacture of a
product, as is the case in producing plastics or rubber from fuel-derived feedstocks, or emissions may occur during
the product's lifetime, such as during solvent use. C can also be stored from NEUs such as in a final product like
plastics or asphalt. Overall, at a national level, about 62% of the total C consumed for nonenergy purposes is
stored in products (e.g., plastics), and not released to the atmosphere. For state-level calculations, the storage
factors per fuel type were taken from the national Inventory values and vary across fuel types and, for some fuels,
over time. See Annex 2.3 of the national Inventory for more details on storage factors used.

Step 5: Calculate NEU CO2 Emissions

Emissions from NEUs were calculated based on multiplying the adjusted NEU fuel use by state (from Steps 1-
3) by the national-level carbon factors by fuel type (same as used in the FFC calculations, including oxidation and
molecular weight ratio with the exception that HGLs and still gas have separate carbon factors for combustion and
NEUs) and by 1 minus the storage factor of each fuel type (from Step 4). See Annex 2.2 of the national Inventory
for more details on carbon factors used.

There are some small differences in the NEU-calculated state-level emissions totals compared with what is
reported in the national Inventory, as shown in Figure 2-15. As with FFC, these differences represent a very small
percentage of total NEU emissions (the maximum percentage difference over time is ~0.03% of total NEU
emissions).

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Figure 2-15: Differences in State-Level and National Total NEU C02 Emissions

Difference Inv Totals - State Totals

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2.1.2.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from NEUs was calculated using
the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described further in Chapter 3 and Annex 7 of
the national Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020 were -37%/+49% for CO2.
State-level estimates are expected to have a higher uncertainty because some of the national-level data were
apportioned to each state. For example, the allocations of export and IPPU adjustments are likely to add to the
uncertainty at a state level compared with the national totals.

2.1.2.4	Recalculations

Consistent with national estimates, EIA updated energy consumption statistics across the time series relative
to the previous Inventory. This resulted in a slight decrease in emissions across most years.

2.1.2.5	Planned Improvements

Planned improvements are consistent with those planned for improving national estimates for NEUs. The EPA
will also look into the export and IPPU adjustments to see if they could be done based on state-level data, if these
data are available, as opposed to assuming the percentage based on SEDS state-level totals.

2.1.2.6	References
See Section 2.1.1.6.

2.1.3 Geothermal Emissions
2.1.3.1 Background

Although not a fossil fuel, geothermal energy does cause CO2 emissions, which are included in the national
Inventory. The source of CO2 is non-condensable gases in subterranean heated water that is released during the
process.

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2.1.3.2	Methods/Approach

National-level geothermal electricity production emissions were estimated by multiplying technology-specific
net generation by technology-specific C contents based on geotype (i.e., flash steam and dry steam).

For state-level geothermal emissions, the total national-level geothermal emissions were taken from the
national Inventory, and they were allocated across states based on the amount of geothermal energy consumed by
each state from the SEDS data. All geothermal emissions were assumed to be in the electricity sector. Almost every
state reported some level of geothermal energy consumption across the time series. The top 5 states in 2020 were
California, Nevada, Florida, Michigan, and Indiana, accounting for about 80% of all geothermal energy
consumption.

2.1.3.3	Uncertainty

Given its small contribution to the overall FFC portion of the national Inventory (0.009% in 2020), an
uncertainty analysis was not performed for CO2 emissions from geothermal production.

2.1.3.4	Recalculations

No recalculations were applied for this current report.

2.1.3.5	Planned Improvements

The EPA will consider if geothermal emissions could be allocated by the type of geothermal production per
state (because different types have different emissions factors) if that data are available.

2.1.3.6	References
See Section 2.1.1.6.

2.1.4 Incineration of Waste (NIR Section 3.3)

2.1.4.1	Background

In the context of this section, waste includes all municipal solid waste (MSW) and scrap tires. In the United
States, incineration of MSW tends to occur at waste-to-energy facilities or industrial facilities where useful energy
is recovered; thus, emissions from waste incineration are accounted for as part of the energy sector. Similarly,
scrap tires are combusted for energy recovery in industrial and utility boilers, pulp and paper mills, and cement
kilns. Incineration of waste results in conversion of the organic inputs to CO2. Thus, the CO2 emissions from waste
incineration are calculated by estimating the quantity of waste combusted and an emission factor based on the
fraction of the waste that is carbon derived from fossil sources.

2.1.4.2	Methods/Approach

The different categories of national-level waste incinerations emissions include CO2 emissions from MSW fossil
components (plastics, synthetic rubber, and synthetic fibers), tire fossil components (synthetic rubber and carbon
black), and non-CC>2 emissions of CH4 and N2O from total waste combustion. Any net CO2 that ultimately results
from incinerated biogenic waste is counted through carbon stock change methodologies in the agriculture and
land use, land use change and forestry sectors discussed in Chapters 4 and 5 of this report.

National emissions from all the categories were allocated to states based on the percentage of total MSW
combusted. The amount of waste combusted by state was estimated based on several different sources depending
on the year of data, as shown in Table 2-4. This is the same approach as currently used in the national Inventory
(EPA 2022a). The national Inventory has more information on the data sources used.

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Table 2-4. Summary of Approaches to Disaggregate Waste Incineration Emissions Across Time Series

Time Series Range

Summary of Data Used

1990-2005

• Waste combusted by state was based on BioCycle report data.

2006-2010

• Waste combusted was based on data from BioCycle, EPA, EIA and ERC on waste
combustion.

2011-2019

• Waste combustion data were based on the U.S. EPA GHGRP.

The methodology used for 1990-2005 was to estimate waste combusted by state based on data from multiple
years of BioCycle reports.

The methodology used for 2006-2010 was to estimate waste combusted by state based on data from the
BioCycle reports, U.S. EPA Facts and Figures, EIA (EIA 2019), and Energy Recovery Council data.

The methodology used for 2011-2020 was to estimate waste combustion based on the U.S. EPA GHGRP (EPA
2022b). The GHGRP reports facility-level emissions of GHG by fuel type from Subpart C data. The Cm and N2O data
from MSW combustion by facility/unit can be divided by default Cm and N2O emissions factors to back-calculate
tons of MSW combusted.

See Appendix A, Table A-117 in the "Waste Incineration" Tab, for the percent of MSW combusted assumed by
state by year from the different sources and also the national Inventory report for more information on the data
sources and methodology used.

The approach used assumed that individual states' waste combustion emissions are proportional to their
share of waste combusted. This assumption is considered reasonable because currently there is no distinction in
the national Inventory on different MSW compositions and fossil component (e.g., plastics) percentages across
states. There could potentially be differences in waste compositions and, therefore, emissions across states, for
example, because of state waste management policies. The EPA update to the national-level waste incineration
emissions estimates could provide more information on state-level CO2 emissions factors per ton of MSW. This is
an area for future work. Assuming scrap tire emissions are produced in proportion to MSW combustion per state
could lead to over- or underestimating tire combustion emissions at the state level. However, given the lack of
readily available data, the assumption that tire combustion emissions occur in proportion to MSW tons combusted
in a given state is considered reasonable.

2.1.4.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and N2O from waste incineration
was calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described further in
Chapter 3 and Annex 7 of the national Inventory (EPA 2022a), levels of uncertainty in the national estimates in
2020 were -17%/+17% for CO2 and -53%/+162% for N2O. State-level estimates are expected to have a higher
uncertainty because the national-level data were apportioned to each state based on MSW tonnage. In particular,
assuming emissions are proportional to total MSW combusted adds uncertainty associated with different waste
compositions across different states. Furthermore, assuming tire combustion emissions are proportional to MSW
tonnage also adds uncertainty associated with the differences in tire and MSW combustion across states.

2.1.4.4	Recalculations

Consistent with the national Inventory, recalculations in state-level waste incineration include substantial
updates to the methods for calculating CO2 emissions. The updates include a new methodology using a carbon
emissions factor per ton of total MSW (as opposed to per specific waste component) calculated from the EPA's
GHGRP data for 2011-2020. An emissions factor for years before 2011 was estimated using the average of 2011
through 2020 emissions factors. State-level estimates were updated based on the new approach.

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2.1.4.5	Planned Improvements

The EPA will look into separating emissions by state based on the category of emissions (e.g., MSW
combustion vs. tire combustion). The EPA will also consider developing state-level MSW C factors based on the
GHGRP state-level data.

2.1.4.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Energy Information Administration. (2020). ElASt. Louis Federal Reserve's Economic Data (FRED) Consumer
Price Index for All Urban Consumers: Education and Communication (CPIEDUSL). Available online at:
https://www.eia.gov/opendata/excel/

U.S. Environmental Protection Agency. (2022a). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 3: Energy. Available online at: https://www.epa.gov/ghgemissions/inventorv-us-
greenhouse-gas-emissions-and-sinks

U.S. Environmental Protection Agency. (2022b). Greenhouse Gas Reporting Program Data. Washington, DC: U.S.
Environmental Protection Agency. Available online at: https://www.epa.gov/ghgreporting/ghg-reporting-
program-data-sets

2.1.5 International Bunker Fuels (NIR Section 3.10)

2.1.5.1	Background

Emissions resulting from the combustion of fuels used for international transport activities, termed IBFs under
the UNFCCC, are not included in national emissions totals but are reported separately based on location of fuel
sales. Two transport modes are addressed under the IPCC definition of IBFs: aviation and marine. GHGs emitted
from the combustion of IBFs, like other fossil fuels, include CO2, CH4, and N2O for marine transport modes and CO2
and N2O for aviation transport modes. Emissions from ground transport activities—by road vehicles and trains-
even when crossing international borders are allocated to the country where the fuel was loaded into the vehicle
and, therefore, are not counted as bunker fuel emissions.

Although reporting on IBFs is a memo item in national-level reports, it does affect the total jet fuel emissions
that are reported because it is a subtraction from total jet fuel use. The same is true at the state level where
subtraction of bunker fuel affects jet fuel emissions that are reported in a given state (as per Step 7 of the FFC
emissions calculations).

2.1.5.2	Methods/Approach

As noted, emissions resulting from the combustion of fuels used for international transport activities, termed
IBF under the UNFCCC, are not included in national emissions totals but are reported separately as a memo item
based on the location of fuel sales. The same approach was used at the state level where estimates of bunker fuels
were determined by state. Although bunker fuels are memo items and do not affect state-level total GHG
emissions, the allocation of bunker fuels across states could affect the total amount of jet fuel used per state,
including domestic jet fuel use and emissions. Bunker fuel emissions include CO2, CFU, and N2O emissions from jet
fuel, diesel fuel, and residual fuel. The jet fuel emissions are broken into commercial and military use. See
Appendix A, Tables A-78 through Table A-81 in the "IBF" Tab, for details on IBF energy use breakout by state.

The approach used here at the state level to allocate and report IBF and other cross state transportation
sector emissions to the state where the fuel is sold is considered reasonable. However, it is an accounting decision

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and may differ from how individual states account for those cross state and international fuel use emissions in
their own inventories.

Jet Fuel

National-level jet fuel CO2 emissions from commercial aircraft came directly from FAA emissions data, CO2
emissions from military use were based on fuel use data multiplied by the national Inventory CO2 emissions factor.
National-level CH4 and N2O emissions were based on fuel use data times an emissions factor, CH4 emissions were
assumed to be 0 from jet fuel use. N2O emissions were split between commercial and military based on the
percentage of total CO2 emissions.

Jet fuel emissions from bunker fuels were allocated to states based on jet fuel use sales data from SEDS.
Residual and Diesel Fuel

National-level residual and diesel fuel emissions were based on fuel use data multiplied by emissions factors
for the different emissions. The emissions were allocated to states based on EIA FOKS data for bunker fuel use for
diesel and residual fuels.

2.1.5.3	Uncertainty

A quantitative uncertainty analysis associated with the national estimates of CO2, CFU, and N2O from IBFs was
not calculated because the estimates are only considered memo items. However, there is a qualitative discussion
of uncertainty associated with national-level IBF emissions in the national Inventory. State-level estimates are
expected to have a higher uncertainty because of the assumptions related to allocating IBF fuels to the state level.
For example, a high degree of uncertainty is associated with allocating jet fuel bunkers to states based on the total
amount of jet fuel used per state.

2.1.5.4	Recalculations

No recalculations were applied for this current report.

2.1.5.5	Planned Improvements

As discussed previously, the approach used here to allocate bunker fuels by state based on the total amount
of jet fuel used by state could potentially lead to an over- or underestimation for some states of bunker fuel
emissions. Therefore, the EPA will look into data specific to jet fuel bunkers by state, for example, flight-level data
on departures and destinations.

Currently, the approach used here allocates total IBF use to the 50 states and the District of Columbia. The EPA
will examine if it is possible to allocate some jet fuel and marine bunkers to territories as they are also covered as
part of the National Inventory.

2.1.5.6	References

See Section 2.1.1.6.

2.1.6 Wood Biomass and Biofuels Consumption (NIR Section 3.11)

2.1.6.1 Background

In line with the reporting requirements for national-level inventories submitted under the UNFCCC, CO2
emissions from biomass combustion are estimated separately from fossil fuel CO2 emissions and are not directly
included in the energy sector contributions to U.S. totals. In accordance with IPCC methodological guidelines, any
such emissions are calculated by accounting for net carbon fluxes from changes in biogenic C reservoirs in the

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AFOLU sector. Biomass non-CC>2 emissions are reported as part of emissions totals and are included under fossil
fuel non-CC>2 emissions for both stationary and mobile sources.

2.1.6.2	Methods/Approach

The combustion of biomass fuels—such as wood, charcoal, and wood waste and biomass-based fuels such as
ethanol, biogas, and biodiesel—generates CO2 in addition to CH4 and N2O already covered earlier. In line with the
reporting requirements for inventories submitted under the UNFCCC, CO2 emissions from biomass combustion
have been estimated separately from fossil fuel CO2 emissions and are not directly included in the energy sector
contributions to U.S. totals. In accordance with IPCC methodological guidelines, any such emissions were
calculated by accounting for net carbon fluxes from changes in biogenic C reservoirs in the AFOLU sector.

Therefore, CO2 emissions from wood biomass and biofuel consumption were not included specifically in
summing energy sector totals. However, they are presented here for informational purposes and to provide detail
on wood biomass and biofuels consumption. See Appendix A, Tables A-118 through Table A-129 in the "Biomass
C02" Tab, for the breakout of biomass CO2 emissions by fuel type and sector.

Biomass—Ethanol, Transportation

National-level ethanol CO2 emissions from the transportation sector were taken from the national Inventory.
Emissions were allocated to states based on the percentage of gasoline used in the transportation sector by state,
which is based on FHWA data.

Biomass—Ethanol, Industrial

National-level ethanol CO2 emissions from the industrial sector were taken from the national Inventory.
Emissions were allocated to states based on the percentage of gasoline used in the industrial sector by state,
which is based on SEDS data.

Biomass—Ethanol, Commercial

National-level ethanol CO2 emissions from the commercial sector were taken from the national Inventory.
Emissions were allocated to states based on the percentage of gasoline used in the commercial sector by state,
which is based on SEDS data.

Biomass—Biodiesel, Transportation

National-level biodiesel CO2 emissions from the transportation sector were taken from the national Inventory.
Emissions were allocated to states based on the percentage of diesel fuel used in the transportation sector by
state, which is based on FHWA data.

Biomass—Wood, Industrial/Residential/Commercial/Electric Power

National-level wood CO2 emissions from all sectors were taken from the national Inventory. Emissions were
allocated to states based on the percentage of wood used in each sector by state, which is based on SEDS data.

2.1.6.3	Uncertainty

A quantitative uncertainty analysis associated with the national estimates of CO2, CH4, and N2O from wood
biomass and biofuels combustion has not been considered a priority and has not been estimated. The priority is to
estimate uncertainty for estimates that get rolled into national totals as opposed to estimates that are considered
memo items. However, a qualitative discussion of uncertainty is associated with national-level wood biomass and
biofuels combustion emissions in the national Inventory. State-level estimates are expected to have a higher
uncertainty because of the assumptions related to allocating emissions to the state level based on fuel use data.

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2.1.6.4	Recalculations

No recalculations were applied for this current report.

2.1.6.5	Planned Improvements

For CO2 emissions from wood fuels, there is likely considerable variation among states. The EPA will look into
other data sources, including from the USFS on wood used as a fuel.

The EPA will look into variability in ethanol consumption across states. It is not likely that ethanol is blended in
the same percentage annually across all states.

2.1.6.6	References

See Section 2.1.1.6.

2.2 Fugitive Emissions

This section presents the methodology used to estimate the fugitive portion of energy emissions and consists
of the following sources:

•	Coal mining (CH4, CO2)

•	Abandoned underground coal mines (Cm)

•	Petroleum and natural gas systems (CO2, CFU, N2O)

•	Abandoned oil and gas wells (CO2, CH4)

2.2.1 Coal Mining (NIR Section 3.4)

2.2.1.1	Background

Three types of coal mining-related activities release CFU to the atmosphere: underground mining, surface
mining, and post-mining (i.e., coal-handling) activities. For the national Inventory, the EPA compiles emissions
estimates for each mine into a national total for active underground mines and compiles coal production data to
estimate emissions from surface coal mining and post-mining activity.

2.2.1.2	Methods/Approach

The methods used to determine state-level estimates for Coal Mining fugitive emissions consists of two
separate sources consistent with the national Inventory:

•	Active underground mines

•	Surface mining and post-mining activities

Active Underground Mines

To compile national estimates of CFU emissions from active underground coal mines for the national
Inventory, the EPA develops emissions estimates for each mine and sums them to a national total, as described
below. The approach to arrive at state-by-state estimates of CH4 emissions from active underground mines is
consistent with the national methods (i.e., using Approach 1 as defined in the Introduction of this report). Rather
than summing estimates to a national total, the EPA instead totals these mine-specific estimates into a state-level
total for each state, based on the estimates for each of the mines located in a state. In prior years, these estimates
have been published in Annex 3.4 to the national Inventory (EPA 2022b).

As described in Section 3.4 of the national Inventory, the EPA uses an IPCC Tier 3 method for estimating CH4
emissions from underground coal mining. These emissions have two sources: ventilation systems and

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degasification systems. Emissions are estimated using mine-specific data, then summed to determine total Cm
liberated. The Cm recovered and used is then subtracted from this total, resulting in an estimate of net emissions
to the atmosphere. See Section 3.4 of the national Inventory (EPA 2022a) for more detail.

To estimate Cm liberated from ventilation systems, the EPA uses data collected through its GHGRP16 (Subpart
FF, "Underground Coal Mines"), data provided by the U.S. Mine Safety and Health Administration (MSHA) (MSHA
2020), and occasionally data collected from other sources on a site-specific level (e.g., state gas production
databases). Since 2011, the Nation's "gassiest" underground coal mines—those that liberate more than
36,500,000 actual cubic feet of CFU per year (about 17,525 metric tons CO2 equivalent)—have been required to
report to the EPA's GHGRP (EPA 2021).17 Mines that report to the EPA's GHGRP must report quarterly
measurements of CH4 emissions from ventilation systems; they have the option of recording and reporting their
own measurements or using the measurements taken by MSHA as part of that agency's quarterly safety
inspections of all mines in the United States with detectable CH4 concentrations.18 More information can be found
in the national Inventory (Chapter 3, Section 3.4 and Annex 3.4) per links included above.

EPA estimates fugitive CO2 emissions from underground mining using an IPCC Tier 1 method. Emission
estimates are based on the IPCC Tier 1 emission factor (5.9 m3/metric ton) and annual coal production from
underground mines from EIA (IPCC 2019) (EIA 2021). The underground mining default emission factor accounts for
all the fugitive CO2 likely to be emitted from underground coal mining. Estimates of fugitive CO2 emissions were
included for the first time in the national Inventory for 1990-2020 (see Planned Improvements section).

Surface Mining and Post-mining Activities

Mine-specific data are not available for estimating CH4 emissions from surface coal mines or for post-mining
activities. For surface mines, basin-specific coal production obtained from the ElA's Annual Coal Report (EIA 2020)
are multiplied by basin-specific CH4 contents (EPA 1996, 2005) and a 150% emissions factor (to account for CH4
from over- and under-burden) to estimate CH4 emissions (King 1994, Saghafi 2013). For post-mining activities,
basin-specific coal production are multiplied by basin-specific gas contents and a mid-range 32.5% emissions factor
for CH4 desorption during coal transportation and storage (Creedy 1993). Basin-specific in situ gas content data
were compiled from AAPG (1984) and U.S. Bureau of Mines (1986).

To determine state-level CH4 emissions estimates for surface coal mining and post-mining activities, emissions
estimates are apportioned based on the coal production in each state, as reported in the EIA Annual Coal Report
(i.e., using Approach 1 as defined in the Introduction of this report). The appropriate basin-specific CH4 content for
the coal produced in a state was assigned based on the coal basin in which the state is located. For post-mining
activities, these emissions are assigned to the state where the coal was produced, even if a portion of such
emissions may occur outside the state, for example, during interstate transport and storage before use. More
information can be found in the national Inventory (Chapter 3, Section 3.4 and Annex 3.4). EPA estimates fugitive
CO2 emissions from surface mining using an IPCC Tier 1 method. Emission estimates are based on the IPCC Tier 1
emission factor (0.44 m3 /metric ton) and annual coal production from surface mines (EIA 2021). IPCC methods and
data to estimate fugitive CO2 emissions from post-mining activities (for both underground and surface coal mining)
are currently not available. Estimates of fugitive CO2 emissions were included for the first time in the national
Inventory for 1990-2020 (see Planned Improvements section).

16	In implementing improvements and integrating data from EPA's GHGRP, the EPA follows the latest guidance from the IPCC in
its Technical Bulletin on the use of Facility-Specific Data in National Greenhouse Gas Inventories (IPCC 2011).

17	Underground coal mines report to the EPA under Subpart FF of the GHGRP (40 CFR Part 98). In 2020, 71 underground coal
mines reported to the program.

18	MSHA records coal mine CH4 readings with concentrations of greater than 50 ppm (parts per million) CH4. Readings below
this threshold are considered nondetectable.

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2.2.1.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of Cm and CO2 emissions from coal
mining was calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006), which is described
further in Chapter 3 of the national Inventory (EPA 2022a). The level of uncertainty in the 2020 national CH4
estimate is -9.2 percent to +17.1 percent; for the national fugitive CO2 estimate, the level of uncertainty is -68.3
percent to +76.3 percent. Because Cm emissions estimates from underground mine ventilation and degasification
systems were based on actual measurement data from EPA's GHGRP and from MSHA, uncertainty is relatively low.
Surface mining and post-mining CH4 emissions, which are based on coal production and the application of
emissions factors, are associated with considerably more uncertainty than underground mines because of the
difficulty in developing accurate basin-level emissions factors from field measurements. However, because
underground mine emissions constitute the majority of total coal mining emissions, the uncertainty associated
with underground emissions is the primary factor that determines the overall uncertainty of the CH4 emissions
estimates. The major sources of uncertainty for estimates of fugitive CO2 emissions are the Tier 1 IPCC default
emission factors used for underground mining (-50 percent to +100 percent) and surface mining (-67 percent to
+200 percent) (IPCC 2019).

National-level emissions estimates for underground mines were developed by aggregating mine-level
estimates. Similarly, state-level emissions estimates for underground mines were developed by aggregating mine-
level estimates for all the coal mines located within each state. The relatively low uncertainty associated with
underground mine emissions at the national level is assumed to be the same for state-level underground mine
emissions estimates. State-level emissions estimates for surface mining and post-mining emissions are associated
with higher uncertainty than underground estimates because they are based on coal production within a state and
the application of emissions factors. Because state-level estimates are based on the coal production within a state,
the uncertainty associated with surface mining and post-mining emissions at the national level is assumed to be
the same for state-level estimates. However, as with the national estimates, underground emissions account for
the majority of state-level coal mining emissions, and the uncertainty associated with underground emissions is
the primary factor that determines overall uncertainty for state-level emissions estimates.

2.2.1.4	Recalculations

No recalculations were applied for this current report.

2.2.1.5	Planned Improvements

The 1990-2020 national Inventory includes—for the first time—estimates of fugitive CO2 emissions from
underground and surface mining. These estimates are produced at the state level using coal production data and
are based on methods from the 2019 Refinement to the 2006 IPCC Guidelines for National Greenhouse Gas
Inventories (IPCC 2019). For more information, see Chapter 3, Section 3.4, of the national Inventory.

2.2.1.6	References

AAPG. (1984). Coalbed Methane Resources of the United States. AAPG Studies in Geology Series #17.

Creedy, D.P. (1993). Methane Emissions from Coal Related Sources in Britain: Development of a Methodology.
Chemosphere, 26: 419-439.

Intergovernmental Panel on Climate Change. (2019) 2019 Refinement to the 2006 IPCC Guidelines for National
Greenhouse Gas Inventories. Calvo Buendia, E., Tanabe, K., Kranjc, A., Baasansuren, J., Fukuda, M., Ngarize S.,
Osako, A., Pyrozhenko, Y., Shermanau, P. and Federici, S. (eds). Published: IPCC, Switzerland

Intergovernmental Panel on Climate Change. (2011). Technical Bulletin on the Use of Facility-Specific Data in
National Greenhouse Gas Inventories. Available online at: https://www.ipcc-
nggip.iges.or.jp/public/tb/TFI Technical Bulletin l.pdf

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Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

King, B. (1994). Management of Methane Emissions from Coal Mines: Environmental, Engineering, Economic and
Institutional Implication of Options. Neil and Gunter Ltd.

Mine Safety and Health Administration. (2020). Data Transparency at MSHA. Available online at:
http://www.msha.gov/

Saghafi, A. (2013). Estimation of Fugitive Emissions from Open Cut Coal Mining and Measurable Gas Content. 13th
Coal Operators' Conference, University of Wollongong, The Australian Institute of Mining and Metallurgy &
Mine Managers Association of Australia. 306-313.

U.S. Bureau of Mines. (1986). Results of the Direct Method Determination of the Gas Contents of U.S. Coal Basins.
Circular 9067. U.S. Bureau of Mines.

U.S. Energy Information Administration. (2021). Annual Coal Report 2020. Table 1. Energy Information
Administration, U.S. Department of Energy. Washington, DC.

U.S. Environmental Protection Agency. (1996). Evaluation and Analysis of Gas Content and Coal Properties of Major
Coal Bearing Regions of the United States. EPA/600/R-96-065. U.S. Environmental Protection Agency.

U.S. Environmental Protection Agency. (2005). Surface Mines Emissions Assessment. Draft. U.S. Environmental
Protection Agency.

U.S. Environmental Protection Agency. (2021). Greenhouse Gas Reporting Program (GHGRP) 2020 Envirofacts.
Subpart FF: Underground Coal Mines. Available online at:
http://www.epa.gov/ghgreporting/ghgdata/reported/coalmines.html

U.S. Environmental Protection Agency. (2022a). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 3: Energy. Available online at: https://www.epa.gov/sites/production/files/2021-
04/documents/us-ghg-inventorv-2021-chapter-3-energy.pdf

U.S. Environmental Protection Agency. (2022b). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-21-005), Annex 3.4. Available online at: https://www.epa.gov/sites/production/files/2021-
04/documents/us-ghg-inventorv-2021-annex-3-additional-source-or-sink-categories-part-a.pdf

2.2.2 Abandoned Underground Coal Mines (NIR Section 3.5)

2.2.2.1	Background

Underground coal mines continue to release CFU after closure. As mines mature and coal seams are mined
through, mines are closed and abandoned. Many are sealed, and some flood through intrusion of groundwater or
surface water into the void. Shafts or portals are generally filled with gravel and capped with a concrete seal, while
vent pipes and boreholes are plugged in a manner similar to oil and gas wells. Some abandoned mines are vented
to the atmosphere to prevent the buildup of CFU that may find its way to surface structures through overburden
fractures. As work stops within the mines, CFU liberation decreases, but it does not stop completely. Following an
initial decline, abandoned mines can liberate CFU at a near-steady rate over an extended period of time, or, if
flooded, produce gas for only a few years. The gas can migrate to the surface through the conduits described
above, particularly if they have not been sealed adequately. In addition, diffuse emissions can occur when CFU
migrates to the surface through cracks and fissures in the strata overlying the coal mine.

2.2.2.2	Methods/Approach

For the national Inventory, the EPA estimates national-level CFU emissions from abandoned underground coal
mines using the Abandoned Mine Methane (AMM) model. The AMM model predicts mine-level CFU estimates
from the time of abandonment through the inventory year of interest. The flow of Cm from the coal to the mine

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void is primarily dependent on the mine's emissions when active and the extent to which the mine is flooded,
sealed, or vented. For each abandoned mine, the AMM model takes into account mine status, date of
abandonment, and the reported average daily emission rate at the time of abandonment to estimate emissions
using decline curves specific to mine status and coal basin. For the 1990-2019 time series, the model results, by
coal basin and mine status, are then aggregated to the national level.19 More information on the estimation
methodology and model input data can be found in the national Inventory (Chapter 3, Section 3.5) (EPA 2022a).

For the latest national Inventory, the EPA updated the AMM model to include state-level estimates as a
regular output. These state-level estimates apply for the 2020 reporting year and future publications of this data.
Previously, the AMM model included only coal basin identifiers; the EPA has added state identifiers. Under this
approach, both national-level and state-level estimates are generated for a reporting year by the AMM model. The
modified model output contains emissions subtotals by state, coal basin, and mine status. These subtotals are then
aggregated to generate state-level estimates. The final model result (i.e., national-level estimates) is the average of
10,000 model iterations, but the calculated state estimates are not. Therefore, the sum of the state-level estimates
may not exactly equal the final national-level estimate. The state-level estimates are normalized to the final
national-level model result using the difference between the national-level total and the sum of state-level totals.
This approach relies on model simulations using decline curves based on mine location (state and basin) and mine
status, rather than using state allocation factors (as described above) to develop state-level estimates. Therefore,
this approach provides more accurate state-level estimates.

The disaggregation method used to estimate state-level emission estimates for the 1990-2019 time series is
described below. State-level emissions estimates for the 1990-2019 time series were developed from the national-
level emissions estimates using Approach 2 as defined in the Introduction to this report. Specifically, estimates
were disaggregated using mine-level average daily Cm emissions at the time of abandonment, mine status (i.e.,
flooded, sealed, vented, and unknown), date of abandonment, and mine location (basin and state) as follows.

Step 1: Develop state allocation factors by basin and mine status

For liberated CFU, the estimated mine-level average daily emissions from the AMM model were totaled by
state, mine status, and coal basin (Central Appalachia, Illinois, Northern Appalachia, Warrior, and Western basin)
for each year in the 1990-2019 time series. Using these state-level totals of average daily emissions and the basin-
level totals of average daily emissions by mine status, state allocation factors (percent) were developed by state,
mine status, and coal basin such that allocation factors across all states within the same coal basin and same mine
status total to 100 percent for each year in the time series (see Appendix B, Tables B-l to B-4, for these data).

State allocation factors for recovered Cm were calculated similarly to liberated Cm state allocation factors,
with the exception that allocation factors were calculated by basin only (not mine status). There are very few CFU
recovery projects for each year in the time series, so the breakdown by coal basin was sufficient to develop state
allocation factors.

For pre-1972 emissions,20 state allocation factors for mines abandoned before 1972 (referred to as "pre-1972
mines") were developed using 2019 emissions estimates. For these mines, 2019 emissions estimates serve as a
good proxy for the entire time series because the pre-1972 mine estimates are developed using county-level
default percentages built into the AMM model.

19	The AMM model is run using @Risk software, which is a stochastic Monte Carlo simulation software.

20	Because of limited data availability for mines abandoned before 1972, a different approach was used in the AMM model to
estimate emissions from these mines (referred to as "pre-1972 mines") compared with mines abandoned in 1972 and later
years. The AMM model estimates emissions for the pre-1972 mines at the county level and does not use mine-level average
daily emissions at the time of abandonment. Refer to the national Inventory Chapter 3, Section 3.5, for further details.

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As an example, Table 2-5 presents the state allocation factors for liberated Cm for all states in the Illinois Basin
with sealed abandoned mines for year 2019 in the time series.

Table 2-5. Example State Allocation Factors for the
Illinois Coal Basin (Sealed Mines)

State

Basin

Status

Percentage (%) of Emissions

IL

Illinois

Sealed

77%

IN

Illinois

Sealed

6%

KY

Illinois

Sealed

17%

Step 2: Develop master table of basin and mine status-level emissions for 1990-2019

Compile data from previous AMM models. The AMM model only estimates annual emissions for a single
reporting year (i.e., for the 1990-2019 time series, there are 29 separate AMM models, each addressing a single
year in the time series). The EPA compiled into a master table the time-series estimates of liberated Cm, recovered
Cm, and Cm emissions from previous annual versions of the AMM model for the 1990-2019 time series.

Normalize direct calculations to match model iterations. The master table contains the following AMM model
outputs for each year in the time series (under separate categories for liberated emissions, recovered emissions,
and emissions from pre-1972 mines):

1.	Annual emissions subtotals by coal basin and by mine status (calculated using in-built decline curves in the
AMM model and input data, such as average daily emissions at the time of abandonment, date of
abandonment, and mine status indicator)

2.	Annual national-level total emissions (based on an average of 10,000 stochastic iterations performed on
the AMM model output #1 above and their associated uncertainty ranges)

The master table contains annual subtotals by coal basin and mine status; however, the aggregate of the
annual subtotals by basin and mine status (i.e., sum of AMM model output #1 above) does not match the annual
national-level total emissions estimate (AMM model output #2 above). Model output #2 above is the average
value for 10,000 model iterations. Therefore, there is a very small difference between the two national-level totals
for each year in the time series (typically less than 0.5 percent in any year of the time series). For this reason, the
annual estimates in the master table (i.e., annual subtotals by coal basin and by mine status; AMM model output
#1) must be normalized21 to equal the national-level emissions estimate (AMM model output #2) that represents
the national emissions estimates used in the national Inventory.

Step 3: Apply state allocation factors to basin- and mine status-level emissions.

The emissions values from the master table generated in Step 2 were multiplied by the state allocation factors
generated in Step 1 to develop 1990-2019 annual state-level CH4 estimates.

For pre-1972 mines, 2019 state allocation factors were applied to the annual pre-1972 national estimates in
the master table.

For mines abandoned after 1972, annual basin and mine status-level state allocation factors were applied to
the normalized basin- and mine status-level emissions estimates in the master table.

21 The difference between the national total and summed total of modeled emissions by coal basin and mine status was
allocated to a coal basin and mine status grouping based on their share of the national total (before normalization).

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2.2.2.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of Cm emissions from abandoned coal
mines was calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described in
Chapter 3 of the national Inventory (EPA 2022), the level of uncertainty in the 2020 national Cm emission estimate
is -21.9 percent to +19.5 percent.

National-level abandoned mine emissions estimates were developed by predicting the emissions of a mine
since the time of abandonment using basin-level decline curves. Multiple aspects of the estimation method
introduce uncertainty for the emissions estimates. In developing national estimates, because of a lack of mine-
specific data, abandoned mines are grouped by basin with the assumption that they will generally have the same
initial pressures, permeability, and isotherm. Other sources of uncertainty in the national estimates are mine
status (venting, flooded, or sealed) and Cm liberation rates at the time of abandonment. These data are not
available for all the abandoned mines in the national Inventory. Abandoned mines with unknown status are
assigned a status based on the known status of other mines located within the same basin. Mine-specific Cm
liberation rates at the time of abandonment are not available for mines abandoned before 1972. It is assumed that
pre-1972 mines are governed by the same physical, geologic, and hydrologic constraints that apply to post-1971
mines; thus, their emissions may be characterized by the same decline curves.

State-level estimates have a higher uncertainty because the national emissions estimates were apportioned to
each state based on mine-specific Cm liberation rates, mine status, and basin information for all the abandoned
mines located within the state. Additionally, the number of mines with unknown status in each state affects the
relative uncertainty of state-level estimates. Estimates for states with a greater number of mines with unknown
status are expected to have relatively higher uncertainty compared with states with fewer abandoned mines with
unknown status. Similarly, states with a greater number of pre-1972 abandoned mines are expected to have
relatively higher uncertainty compared with states with fewer pre-1972 mines.

2.2.2.4	Recalculations

No recalculations were applied for this current report.

2.2.2.5	Planned Improvements

For the 1990-2020 national inventory, the EPA updated the AMM model to include state-level estimates as a
regular output, as described above, implementing planned improvements described in the previous report. These
state-level estimates apply for the 2020 reporting year and future years.

2.2.2.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 3: Energy, Section 3.5. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

2.2.3 Petroleum Systems (NIR Section 3.6)

2.2.3.1 Background

This section describes methods used to estimate state-level CO2, CH4, and N2O emissions from petroleum
systems. This category includes fugitive emissions from leaks, venting, and flaring. Methane emissions from
petroleum systems are primarily associated with onshore and offshore crude oil production, transportation, and
refining operations. During these activities, Cm is released to the atmosphere as emissions from leaks, venting

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(including emissions from operational upsets), and flaring. CO2 emissions from petroleum systems are primarily
associated with onshore and offshore crude oil production and refining operations. Note, CO2 emissions in
petroleum systems exclude all combustion emissions (e.g., engine combustion) except for flaring CO2 emissions. All
combustion CO2 emissions (except for flaring) are accounted for in the FFC section. Emissions of N2O from
petroleum systems are primarily associated with flaring.

The methods used to develop the state-level estimates for petroleum systems follow Approach 2, as defined
in the Introduction of this report. They primarily rely on relative differences in basic state activity levels (e.g.,
petroleum production), and do not reflect differences between states due to differences in practices, technologies,
or formation types. One exception is for petroleum refining emissions, which are allocated to states for years after
2010 using facility-level emissions reported to the GHGRP, Subpart Y. Future state-level inventory reports may
incorporate additional state- or region-specific data to improve estimates and better reflect these differences.

2.2.3.2 Methods/Approach

To compile national Inventory estimates of GHG emissions (CH4, CO2, and N2O) from petroleum, the EPA
compiles emissions estimates for emissions sources in each segment of petroleum systems (e.g., exploration,
production, transport, refining) into a national total (EPA 2022). Additional information on emissions estimates and
data used to develop the national-level emissions estimates for petroleum systems is available at
https://www.epa.gov/ghgemissions/natural-gas-and-petroleum-svstems-ghg-inventory-additional-information-
1990-2019-ghg.

The state-level methodology for petroleum systems follows Approach 2, in which national emissions from
each segment to all U.S. states, territories, and federal offshore waters (for the production segment only) are
allocated to each state using activity datasets that have information broken out at a state level, such as the
number of oil wells or volume of oil production in each state. Where possible, these datasets are chosen to align
with current activity datasets used to develop national Inventory estimates. See Appendix B for information on the
current state-level underlying proxy datasets, i.e., Tables B-5 to B-7. The specific datasets used to disaggregate
national emissions to the state level vary by segment, as described in the following sections.

Exploration and Production

For the national Inventory, the EPA uses emissions data collected by the GHGRP to quantify emissions for most
exploration and production sources in recent years (i.e., 2010-2020). For sources for which recent data are
unavailable, and for earlier years of the time series, estimates are developed using emissions factors from EPA/GRI
(1996) and Radian (1999) studies. Other key data sources for the national estimates include oil well counts and
production levels from Enverus, the Bureau of Ocean Energy Management (BOEM), and total crude oil production
from the EIA.

To develop state-level emissions from petroleum exploration and production, national Inventory emissions
were allocated to each state, primarily based on the fraction of oil wells in each state relative to national totals
across each year in the time series (Appendix B, Tables B-5 and B-6). Other key state-level proxy datasets used to
disaggregate national emissions include the number of oil well completions with and without hydraulic fracturing
in each state, as well as the total volume of oil produced in each state. These state data were derived from time
series of oil and gas well data from Enverus, consistent with the Enverus dataset used as activity data to derive
total national emissions. For offshore activities, emissions from state waters in the Gulf of Mexico were allocated
based on relative state-level oil production levels, while emissions from activities in federal waters were retained
as a separate category (i.e., not allocated to states). For both exploration and production segments, the datasets
used for state allocation were consistent across the entire emissions time series.

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Crude Oil Transport

For the national Inventory, EPA estimates emissions of Cm, CO2, and N2O from crude oil transport for
petroleum systems using a combination of crude oil transportation and pipeline and crude deliveries data from the
EIA, American Petroleum Institute, and Oil and Gas Journal.

To develop state-level emissions from crude oil transport, national Inventory emissions were allocated to each
state based on three state proxy datasets. Vented emissions from marine loading were allocated to states based
on oil production from offshore wells in state waters from the Enverus dataset (Appendix B, Table B-6). Similarly,
vented emissions from truck loading and rail loading were allocated based on onshore levels of oil well production
in each state. All other transport emissions, including tanks, pump stations, and floating roof tanks, were allocated
based on the relative state counts of oil refineries from GHGRP Subpart Y data after 2010 and EIA atmospheric
crude oil distillation capacity for 1990-2009, as described in the next section (Appendix B, Table B-7).

Refineries

For the national Inventory, the EPA uses data from the GHGRP Subpart Y and national-level activity data. All
U.S. refineries have been required to report CFU, CO2, and N2O emissions for all major activities starting with
emissions that occurred in 2010. The reported total CFU, CO2, and N2O emissions are used for the emissions in each
year from 2010 forward. Certain activities that are not reported to the GHGRP are estimated using data from
Radian (1999). These sources account for a small fraction of refinery emissions. To estimate emissions for 1990-
2009, the emissions data from the GHGRP, along with the refinery feed data, are used to derive emissions factors
that are applied to the annual refinery feed in years 1990-2009.

To develop state-level estimates for refineries for 2010-2030, national Inventory emissions from refineries
were apportioned to each state based on that state's share of refinery emissions of each gas, as reported to
GHGRP subpart Y. This method is consistent with national inventory estimates for refineries over these years. For
1990-2009, national Inventory emissions from refineries were apportioned to each state based on that state's
share of national operating atmospheric crude oil distillation capacity (barrels per calendar day) (EIA 2022)
(Appendix B, Table B-7).

2.2.3.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and CH4 from petroleum systems
was calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). Uncertainty estimates for
N2O applied the same uncertainty bounds as calculated for CO2. As described further in Chapter 3 and Annex 7 of
the national Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020 were -22%/+26% for CO2
and N2O and -28%/+32% for CH4.

The uncertainty estimates for the national Inventory largely account for uncertainties in the magnitude of
emissions and activity factors used to develop the national estimates for the largest contributing sources. State-
level estimates of annual emissions and removals have a higher relative uncertainty compared with these national
estimates because of the additional step of apportioning national emissions to each state using spatial proxy
datasets. This allocation method introduces additional uncertainty due to sources of uncertainty associated with
the location information in each underlying dataset (e.g., number of oil wells in each state), as well as the ability of
each proxy to accurately represent the point of emission from each source within the petroleum supply chain.
Where possible, this second source of uncertainty was minimized in the petroleum state-level analysis by selecting
proxy datasets that are consistent with activity factors used in the national Inventory. For example, national CO2
and CH4 from vented emissions in the production segment largely relied on national counts of oil wells and
production volumes as activity factors; therefore, additional uncertainty in the state-level estimates is largely
associated with the uncertainty in oil well locations. The sources of uncertainty for this category, other than
refinery emissions, are also consistent over time because the same proxy datasets were applied across the entire

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time series. This allocation method, however, cannot account for state-specific mitigation programs and reduction
efforts or state-specific variations in emissions factors, which each introduce additional uncertainty in the
emissions estimates. As with the national Inventory, the state-level uncertainty estimates for this category may
change as the understanding of the uncertainty and underlying datasets and methodologies improve.

Given the variability of practices and technologies across oil and gas systems and the occurrence of episodic
events, it is possible that EPA's estimates do not include all methane emissions from abnormal events. For many
equipment types and activities, the EPA's emissions estimates include the full range of conditions, including
"super-emitters." For other situations, where data are available, emissions estimates for abnormal events were
calculated separately and included in the GHG Inventory (e.g., Aliso Canyon leak event). The EPA continues to work
through its stakeholder process to review new data from the EPA's GHGRP and research studies to assess how
emissions estimates can be improved.

2.2.3.4	Recalculations

As described in Chapter 3 of the national Inventory report, some emission and sink estimates in the Inventory
are recalculated and revised with improved methods and/or data. In general, recalculations are made to
incorporate new methodologies, or to update activity and emissions factor datasets with the most current
versions. These improvements are implemented across the previous Inventory's entire time series to ensure that
the national emission trend is accurate. See Chapter 3 in the national Inventory report for more details on
recalculations in the latest Inventory estimates.

As the state-level emissions here are estimated using Approach 2 (national emissions are disaggregated to the
state level), changes in absolute state-level emissions between this version and the previous state report will
largely reflect recalculations and improvements implemented in the national Inventory. Similar to the national
Inventory, the calculation of state-level estimates has been updated to incorporate updates to the underlying
state-level proxy datasets. State-level proxy datasets have been updated across the entire time series, to ensure
that the state emission trends are accurate. No methodological updates have been implemented in the current
state-level estimates. Therefore, changes in the relative emissions in each state will reflect updates in the
underlying state-level proxy datasets, and not in the state-level methodology, described in this report.

2.2.3.5	Planned Improvements

Potential refinements to exploration and production estimates in future state-level inventories include the
refinement of state proxies used within each segment and the incorporation of additional GHGRP data.

Potential refinements to crude transport estimates in future state-level inventories include the refinement of
state proxies used for individual sources within each segment.

2.2.3.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

Radian. (1999). Methane Emissions from the U.S. Petroleum Industry. Prepared by Radian International. U.S.
Environmental Protection Agency.

U.S. Energy Information Administration. (2022). Crude Oil Production. Energy Information Administration.

U.S. Environmental Protection Agency/GRI. (April 1996). Methane Emissions from the Natural Gas Industry.
Prepared by Radian. U.S. Environmental Protection Agency.

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U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020

(EPA 430-R-22-003), Chapter 3: Energy, Section 3.6. Available online at:

https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

2.2.4 Natural Gas Systems (NIR Section 3.7)

2.2.4.1	Background

This section describes methods used to estimate state-level CO2, CH4, and N2O emissions from natural gas
systems. Similar to petroleum systems, this category includes fugitive emissions from leaks, venting, and flaring.
The U.S. natural gas system encompasses hundreds of thousands of wells, hundreds of processing facilities, and
over a million miles of gathering, transmission, and distribution pipelines. Methane and CO2 emissions from
natural gas systems include those resulting from normal operations, routine maintenance, and system upsets.
Emissions from normal operations include natural gas engine and turbine uncombusted exhaust, flaring, and leak
emissions from system components. Routine maintenance emissions originate from pipelines, equipment, and
wells during repair and maintenance activities. Pressure surge relief systems and accidents can lead to system
upset emissions. New to the 1990-2020 national Inventory are CH4 emissions from observed well blowout events
in Ohio, Texas, and Louisiana in 2018 and 2019, as well as CFU and CO2 emission estimates from post-meter
sources across the entire time series. Emissions of N2O from flaring activities are included in the national Inventory,
with most of the emissions occurring in the processing and production segments. Note, CO2 emissions exclude all
combustion emissions (e.g., engine combustion) except for flaring CO2 emissions. All combustion CO2 emissions
(except for flaring) are accounted for in the FFC section.

The methods used to develop the state-level estimates for natural gas systems follow Approach 2, as defined
in the Introduction of this report, and primarily rely on relative differences in basic state activity levels (e.g., gas
production), and do not reflect differences between states due to differences in practices, technologies, or
formation types. Future state-level inventory reports may incorporate additional state-state or region-specific data
to improve estimates and better reflect these differences.

2.2.4.2	Methods/Approach

To compile national estimates of CFU, CO2, and N2O emissions from natural gas systems for the national
Inventory, the EPA compiles emissions estimates for emissions sources in each segment of natural gas systems
(i.e., exploration, production, processing, transmission and storage, distribution, and post-meter sources) into a
national total. Additional information on emissions estimates and data used to develop the national-level
emissions estimates for natural gas systems is available online at: https://www.epa.gov/ghgemissions/natural-gas-
and-petroleum-svstems-ghg-inventorv-additional-information-1990-2019-ghg.

The state-level methodology for natural gas systems follows Approach 2, in which national emissions from
each segment within all U.S. states, territories, and federal offshore waters (production segment only) are
allocated to each state using activity datasets that have information broken out at a state level, such as the
number of gas wells or volume of gas produced in each state. Where possible, these datasets are chosen to align
with current activity datasets used to develop national Inventory estimates. See Appendix B for information
underlying the estimates, i.e., Tables B-8 to B-12. The specific datasets used to disaggregate national emissions to
the state level vary by segment, as described in the following sections.

Exploration and Production

For the national Inventory, the EPA uses emissions data collected by the GHGRP to quantify emissions for most
sources in recent years (i.e., 2011-2020) and data from a GRI/EPA 1996 study for earlier years of the time series or
for sources for which recent data are unavailable. Other key data sources include data provided in Zimmerle et al.
(2019), production and well count data from Enverus, and offshore production emissions data from the BOEM.

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Each emissions source for production in the national Inventory was generally scaled to the national level using
either well counts, gas production, or condensate production.

To develop state-level emissions from natural gas exploration and production, national Inventory emissions
were generally allocated to states using state-level proxy datasets that align with the activity data used in the
national Inventory (i.e., well counts, gas production, or condensate production). For example, state counts of gas
wells were derived from time series of gas well data from Enverus, consistent with the Enverus data used as
national-level activity data in the national Inventory (see Appendix B, Table B-8). In addition, state-level proxy
datasets for natural gas production from Enverus (Appendix B, Table B-9) and state-level lease condensate
production from the EIA (2020) aligned with national activity data sources. Proxy data for exploration included the
number of wells and well completions with and without hydraulic fracturing, as well as the total number of gas
wells drilled in each state relative to the national total. Offshore emissions in the Gulf of Mexico and the state of
Alaska were allocated based on natural gas production at each platform. Additional production emissions from
offshore federal waters were not allocated to individual states but were included as a separate total, and
emissions from gathering and boosting were allocated based on the relative emissions in each state of from all
other production sources. To account for updates to the national Inventory that incorporate Cm emission
estimates from well blowout events in Ohio, Texas, and Louisiana, Cm emissions from these one-time events were
allocated each state in the appropriate year (e.g., 60,000 metric tons in Ohio in 2018, 4,800 metric tons in
Louisiana in 2019, and 49,000 metric tons in Texas in 2019). In addition, the allocation of national Inventory
estimates from produced water has been updated to using produced water volumes from Enverus to align the
activity data used in the national Inventory. For both exploration and production segments, the sources of proxy
data used for state allocation were consistent across the entire emissions time series.

Processing

For the national Inventory, the EPA uses emissions data collected by GHGRP to quantify emissions for most
sources in recent years (i.e., 2011-2020) and data from GRI/EPA (1996) for earlier years of the time series or for
sources for which recent data are unavailable. Key activity data include processing plant counts from the Oil and
Gas Journal.

To develop state-level estimates for the processing segment for each year of the time series, the EPA
apportioned the total national processing segment emissions to each state based on the fraction of national
onshore marketed natural gas production (EIA 2020) occurring in each state (Appendix B, Table B-10).

Transmission and Storage

For the national Inventory, the EPA uses emissions data collected by the GHGRP and data from a Zimmerle et
al. (2015) study to quantify emissions from most sources in recent years (i.e., 2011-2020), and GRI/EPA (1996)
data for earlier years of the time series and for sources for which recent data are unavailable. Key activity data
include transmission stations (calculated using the GHGRP data and Zimmerle et al.), storage stations (calculated
using Zimmerle et al. and EIA data), and transmission pipeline miles (Pipeline and Hazardous Materials Safety
Administration [PHMSA] 2019).

To develop state-level estimates for the transmission and storage segment for each year of the time series,
the EPA apportioned the total national transmission and storage segment emissions to each state based on the
fraction of national transmission pipeline mileage occurring in each state (Appendix B, Table B-ll). In the national
Inventory, CH4 emissions from the Aliso Canyon blowout event are added to storage emission totals in 2015 and
2016. In the state-level estimates, these emissions are allocated to the state of California for 2015 and 2016 (e.g.,
78,350 metric tons CH4 in 2015, 21,288 metric tons CH4 in 2016), while remaining emissions from storage wells are
allocated based on the relative transmission pipeline mileage in each state.

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Distribution

For the national Inventory, the EPA uses data collected by the GHGRP and data from a Lamb et al. (2015) study
to quantify emissions from most sources in recent years (i.e., 2011-2020) and GRI/EPA (1996) data for earlier years
of the time series or for sources for which recent data are unavailable. Key activity data include pipeline mileage by
material from the PHMSA station counts from subpart W of the GHGRP and number of natural gas residential,
commercial, and industrial consumers from the EIA.

To develop state-level estimates for the distribution segment for each year of the time series, the EPA national
total emissions from pipeline leaks were allocated based on the relative pipeline mileage (by material [cast iron,
unprotected/protected steel, plastic]) in each state; the relative number of natural gas residential, commercial,
and industrial consumers in each state from the EIA; and the number of above- and below-grade stations in each
state as reported to the GHGRP (scaled up by the ratio of PHMSA to GHGRP pipeline mileage in each state to
include non-reporters). Complete PHMSA data are available starting in the year 2003 and GHGRP data are
available for all years starting in 2011. For all earlier years, national emissions were allocated using the same
relative state contributions as those values in the earliest available years (e.g., relative state-level pipeline mileage
amounts held constant before 2003) (Appendix B, Table B-12).

Post-meter Sources

For the national Inventory, post-meter sources include leak emissions from residential and commercial
appliances, industrial facilities and power plants, and natural-gas-fueled vehicles. Leak emissions from residential
appliances and industrial facilities and power plants account for the majority of post-meter CH4 emissions. CO2
emissions from residential appliances are included in the natural gas residential source within the energy sector
and are not accounted for here. There are no N2O emissions from the post-meter segment. Key activity data
include the counts of homes in the United States with natural gas appliances from the American Housing Survey
(AHS) national dataset, the number of commercial natural gas customers from the EIA, natural gas consumption
volumes for industrial and electric generating units (EGU) from the EIA, and counts of compressed natural gas
(CNG) vehicles from the EPA MOVES model. For more information on the post-meter emissions in the national
Inventory, see Chapter 3 of the national Inventory report.

To develop state-level estimates for post-meter emissions for each year of the time series, the EPA national
total emissions from residential and commercial appliances were allocated to states using the relative number of
residential and commercial natural gas customers in each state from the EIA. Industrial and EGU emissions were
allocated based on the relative consumption volumes from the EIA SEDS and CNG vehicles were allocated to the
number of CNG vehicles in each state, derived from the MOVES model. These proxy datasets are generally
consistent with the activity datasets used in the national Inventory, except for residential emissions, which are
allocated based on data from the EIA rather than the AHS due to the limited state-level information in the AHS
dataset. The same proxy datasets are used across the entire time series for this segment.

2.2.4.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and CH4 from natural gas systems
was calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). Uncertainty estimates for
N2O applied the same uncertainty bounds as CO2. As described further in Chapter 3 and Annex 7 of the national
Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020 were -16%/+19% for CO2 and N2O and
-18%/+18% for CH4.

The uncertainty estimates for the national Inventory largely account for uncertainty in the magnitude of
emissions and activity factors used to develop the national estimates for the largest contributing sources. State-
level estimates of annual emissions and removals have a higher relative uncertainty compared with these national
estimates due to the additional step of apportioning national emissions to each state using spatial proxy datasets.

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This allocation method introduces additional uncertainty due to sources of uncertainty associated with the
location information in each underlying dataset (e.g., number of non-associated gas wells in each state), as well as
the ability of each proxy to accurately represent the point of emission from each source within the natural gas
supply chain. Where possible, this second source of uncertainty is minimized in the natural gas state-level analysis
by selecting proxy datasets that are consistent with activity factors used in the national Inventory. However, this is
not always possible when activity factor datasets only include national aggregate statistics. For example, national
CO2 and Cm emissions from transmission and storage compressor stations largely rely on station counts developed
from GHGRP station counts and scaled up to the national level with an adjustment factor. In the state-level
estimates, these emissions are allocated based on share of national transmission pipeline mileage occurring in
each state and will therefore include additional uncertainty associated with the accuracy of the state-specific data
in the PHMSA dataset, as well as the accuracy in which relative state-level pipeline mileage reflect the relative
state-level emissions from compressor stations and other sources in transmission and storage. In contrast, the
national Inventory estimates for sources within the natural gas production segment typically use national well
counts and production volumes as activity factors. Therefore, additional uncertainty in the state-level estimates for
these sources will largely be the spatial representation of gas wells in the activity factor dataset. The sources of
uncertainty for this category are also consistent over time because the same proxy datasets are applied across the
entire time series. This allocation method, however, cannot account for state-specific mitigation programs and
reduction efforts or state-specific variations in emissions factors, which each introduce additional uncertainty in
the emissions estimates. As with the national Inventory, the state-level uncertainty estimates for this category may
change as the understanding of the uncertainty of estimates and underlying datasets and methodologies improve.

Given the variability of practices and technologies across oil and gas systems and the occurrence of episodic
events, it is possible that the EPA's estimates do not include all methane emissions from abnormal events. For
many equipment types and activities, the EPA's emissions estimates include the full range of conditions, including
"super-emitters." For other situations, where data are available, emission estimates for abnormal events were
calculated separately and included in the GHG Inventory (e.g., Aliso Canyon leak event and the three well blowout
events included for the first time in the 2022 Inventory). The EPA continues to work through its stakeholder
process to review new data from the EPA's GHGRP and research studies to assess how emissions estimates can be
improved.

2.2.4.4 Recalculations

As described in Chapter 3 of the national Inventory report, some emission and sink estimates in the Inventory
are recalculated and revised with improved methods and/or data. In general, recalculations are made to
incorporate new methodologies, or to update activity and emissions factor datasets with the most current
versions. These improvements are implemented across the previous Inventory's entire time series to ensure that
the national emission trend is accurate. See section 3.7 of Chapter 3 in the national Inventory report for more
details on recalculations in the latest Inventory estimates.

As the state-level emissions are estimated using Approach 2 (national emissions are disaggregated to the state
level), changes in absolute state-level emissions between this version and the previous state report will largely
reflect recalculations and improvements implemented in the national Inventory. For example, to account for
updates to the national Inventory that incorporate CH4 emission estimates from well blowout events in Ohio,

Texas, and Louisiana, as described above. In addition, CH4 and CO2 estimates from post-meter sources have been
included for the first time across the entire time series. See Chapter 3 in the national Inventory report for further
details on these updates in the national Inventory.

To align with these methodological improvements in the national Inventory, methodological updates to the
state estimates, relative to the previous version, include the incorporation of one-time event well blowout
emissions as described above (production and exploration segment) and the addition of post-meter emission

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estimates from residential, commercial, and industrial sources and natural gas vehicles (post-meter segment).
These new sources have been allocated to the state level following the approaches described in the segment-
specific sections above.

In addition, storage well Cm emissions in the national Inventory from the Aliso Canyon blowout event in 2015
and 2016 are now allocated to the state of California. In the 1990-2019 state-level inventory, emissions from this
event in 2015 and 2016 were allocated across all states based on the relative mileage of transmission pipeline
miles in each state (Appendix B, Table B-ll). Emissions from produced water in the production segment have also
been updated to use the volumes of produced water from Enverus, consistent with the national Inventory. In the
1990-2019 state inventory, produced water emissions had previously been allocated to the relative state-level
counts of gas wells.

For other sources, the calculation of state-level estimates has been updated to incorporate updates to the
underlying state-level proxy datasets, following the same procedure as in the national Inventory. State-level proxy
datasets have been updated across the entire time series to ensure that the state-emission trends are accurate. No
methodological updates have been implemented in the current state-level estimates. Therefore, changes in the
relative emissions in each state will largely reflect updates in the underlying state-level proxy datasets and updates
to the national GHG Inventory.

2.2.4.5	Planned Improvements

Potential refinements to exploration and production estimates in future state-level inventories include the
refinement of state proxies used for individual sources within each segment and the incorporation of additional
GHGRP data for the allocation of emissions within the production segment.

Potential refinements to processing estimates in future state-level inventories include the use of emissions
level reported to the GHGRP (along with other data) to apportion emissions to each state. In addition, information
on processing plant locations from other datasets or use of Oil and Gas Journal or EIA data on gas processing
volumes could be incorporated to improve estimates. Potential refinements to transmission and storage estimates
in future state-level inventories include the use of emissions levels reported to the GHGRP (along with other data)
to apportion emissions to each state. In addition, information on transmission and storage station locations from
other datasets could be incorporated to improve estimates.

2.2.4.6	References

GRI/U.S. Environmental Protection Agency. (1996). Methane Emissions from the Natural Gas Industry. Prepared by
Harrison, M., T. Shires, J. Wessels, and R. Cowgill, eds., Radian International LLC for National Risk Management
Research Laboratory, Air Pollution Prevention and Control Division, Research Triangle Park, NC. EPA-600/R-96-
080a.

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

Lamb, et al. (2015). "Direct Measurements Show Decreasing Methane Emissions from Natural Gas Local
Distribution Systems in the United States." Environmental Science & Technology, Vol. 49, 5161-5169.

Pipeline and Hazardous Materials Safety Administration. (2022). Gas Distribution Annual Data. Pipeline and
Hazardous Materials Safety Administration, U.S. Department of Transportation, Washington, DC. Available
online at: https://cms.phmsa.dot.gov/data-andstatistics/pipeline/gas-distribution-gas-gathering-gas-
transmission-hazardous-liquids

U.S. Energy Information Administration. (2022). Crude Oil Production. Energy Information Administration.

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U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 3: Energy, Section 3.7. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

Zimmerle et al. (2015). "Methane Emissions from the Natural Gas Transmission and Storage System in the United
States." Environmental Science and Technology, Vol. 49, 9374-9383.

Zimmerle et al. (2019). "Characterization of Methane Emissions from Gathering Compressor Stations." October
2019. Available online at: https://mountainscholar.org/handle/10217/195489

2.2.5 Abandoned Oil and Gas Wells (NIR Section 3.8)

2.2.5.1	Background

This section describes methods used to estimate state-level CO2 and Cm emissions from Abandoned Oil and
Gas Wells. The term "abandoned wells" encompasses various types of wells, including orphaned wells and other
nonproducing wells:

•	Wells with no recent production, and not plugged. Common terms (such as those used in state databases)
might include inactive, temporarily abandoned, shut-in, dormant, and idle.

•	Wells with no recent production and no responsible operator. Common terms might include orphaned,
deserted, long-term idle, and abandoned.

•	Wells that have been plugged to prevent migration of gas or fluids.

The U.S. population of abandoned wells (including orphaned wells and other nonproducing wells) is around
3.8 million (with around 3.0 million abandoned oil wells and 0.8 million abandoned gas wells). The methods to
calculate emissions from abandoned wells involved calculating the total populations of plugged and unplugged
abandoned oil and gas wells in the United States. An estimate of the number of orphaned wells within this
population is not developed as part of the methodology for the national- or state-level inventory. Other groups
have developed estimates of the total national number of orphaned wells. The Interstate Oil and Gas Compact
Commission, for example, estimates 92,198 orphaned wells in the United States (IOGCC 2021). State applications
for grants to plug orphaned wells indicate over 130,000 orphaned wells in the United States (Department of
Interior 2022).

The state-level methodology for abandoned oil and gas wells follows Approach 2, as defined in the
Introduction of the report, where emissions from this segment are allocated to all U.S. states and territories using
activity datasets with information broken out at the state level, including well counts, type (e.g., oil vs. gas), and
plugging status. These data were chosen to align with the current activity datasets used to develop national
estimates. See Appendix B, Table B-13, for the underlying datasets.

2.2.5.2	Methods/Approach

To compile national estimates of Cm and CO2 emissions from abandoned oil and gas wells for the national
Inventory, the EPA compiles emissions estimates for plugged and unplugged abandoned wells for two regions:
Appalachia and outside of Appalachia. Key data sources are two research studies (Kang et al. [2016] and
Townsend-Small et al. [2016]) for emissions factors and Enverus database and historical state-level datasets for
abandoned well counts. Additional information on emissions estimates and data used to develop the national-level
emissions estimates for abandoned wells is available at https://www.epa.gov/system/files/documents/2022-
04/2022 ghgi update - wells.pdf.

To develop state-level estimates of GHG emissions from abandoned natural gas and oil wells, national
emissions were allocated based on an estimate of the number of abandoned wells in each state (developed using
Enverus and historical datasets, consistent with the approach used in the national Inventory), as well as their type

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and plugging status. As a result of the use of regional-specific emissions factors (described above), the national
estimates in the national Inventory were derived from the sum of emissions estimates from plugged and
unplugged natural gas and oil wells in Appalachia and outside of Appalachia. Emissions from the national Inventory
for each region were then allocated based on the counts of abandoned wells in each state and their plugging
status. For example, emissions from plugged natural gas wells in the Appalachia region (OH, PA, WV, NY, KY, TN)
were allocated to each of the six Appalachia states based on the fraction of plugged abandoned natural gas wells in
each state relative to the total for all six states. For all remaining states, emissions from plugged natural gas wells
were allocated to each state based on the fraction of plugged abandoned natural gas wells in each of the non-
Appalachia states relative to the total for all 44 states. State-level counts of abandoned oil and natural gas wells
are from the Enverus dataset supplemented with historical estimates of state-level abandoned well counts from
state databases, as described in a previous EPA memo on abandoned oil and gas wells (EPA 2018) (see Appendix B,
Table B-13, for data). The state-level well plugging status was derived from the fraction of plugged and unplugged
wells in each state, also derived from the Enverus dataset.

2.2.5.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and CFU from abandoned oil and
gas wells was each calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described
further in Chapter 3 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 for both abandoned oil and gas wells were -83%/+197% for CChand -83%/+197% for Cm.

The uncertainty estimates for the national Inventory largely account for uncertainty in the magnitude of
emissions and activity factors used to develop the national estimates. State-level estimates of annual emissions
and removals have a higher relative uncertainty compared with these national estimates because of the additional
step of apportioning national emissions to each state using spatial proxy datasets. This allocation method for
abandoned oil and gas wells used the same activity factor dataset used in the national Inventory. However, this
method introduces additional uncertainty in the state estimates due to uncertainties in the reported locations of
abandoned oil and gas wells in each state. The sources of uncertainty for this category are consistent over time
and the same proxy datasets were applied across the entire time series. This allocation method, however, cannot
account for state-specific mitigation programs and reduction efforts or state-specific variations in emissions
factors, which each introduce additional uncertainty in the emissions estimates. As with the national Inventory, the
state-level uncertainty estimates for this category may change as the understanding of the uncertainty of
estimates and underlying datasets and methodologies improve.

2.2.5.4	Recalculations

As described in Chapter 3 of the national Inventory report, some emission and sink estimates in the Inventory
are recalculated and revised with improved methods and/or data. In general, recalculations are made to
incorporate new methodologies, or to update activity and emissions factor datasets with the most current
versions. These improvements are implemented across the previous Inventory's entire time series to ensure that
the national emission trend is accurate. See Chapter 3 in the national Inventory report for more details on
recalculations in the latest Inventory estimates.

As the state-level emissions here are estimated using Approach 2 (national emissions are disaggregated to the
state level), changes in absolute state-level emissions between this version and the previous state report will
largely reflect recalculations and improvements implemented in the national Inventory. Similar to the national
Inventory, the calculation of state-level estimates has been updated to incorporate updates to the underlying
state-level proxy datasets. State-level proxy datasets have been updated across the entire time series to ensure
that the state-emission trends are accurate. No methodological updates have been implemented in the current
state-level estimates for abandoned oil and gas wells. Therefore, changes in the relative emissions in each state

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will reflect updates in the underlying state-level proxy datasets and updates to the national level GHG Inventory,
and not in the state-level methodology, described in this report.

2.2.5.5	Planned Improvements

Potential refinements include the incorporation of improved state-level abandoned well counts for each year
of the time series. The approach taken here to estimate state-level well count data uses estimates developed for
select years (1990 and 2015) and interpolated for other years.

2.2.5.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

Interstate Oil and Gas Compact Commission (2021). Idle and Orphan Oil and Gas Wells: State and Provincial
Regulatory Strategies 2021. Available online at:

https://iogcc.ok.gOv/sites/g/files/gmc836/f/iogcc idle and orphan wells 2021 final web.pdf

Kang, et al. (2016). "Identification and characterization of high methane-emitting abandoned oil and gas wells."
PNAS, Vol. 113, No. 48, 13636-13641, doi: 10.1073/pnas.l605913113.

Townsend-Small, et al. (2016). "Emissions of coalbed and natural gas methane from abandoned oil and gas wells in
the United States." Geophysical Research Letters, Vol. 43,1789-1792.

United States Department of Interior (2022). Overwhelming Interest in Orphan Well Infrastructure Investments.
Available online at: https://content.govdelivery.com/accounts/USDOI/bulletins/30416b5.

U.S. Environmental Protection Agency. (2018). Inventory of U.S. Greenhouse Gas Emissions and Sinks 1990-2016:
Abandoned Oil and Gas Wells. Available online at: https://www.epa.gov/sites/production/files/2018-
04/documents/ghgemissions abandoned wells.pdf

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 3: Energy, Section 3.6. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

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3 Industrial Processes and Product Use (IPPU) (NIR Chapter 4)

For this methodology report, the IPPU sector is organized into four subsectors: minerals, chemicals, metals,
and product use (fluorinated sources, N2O). For more information on IPPU sector emissions, see Chapter 4 of the
national Inventory. Table 3-1 summarizes the different approaches used to estimate state-level IPPU sector
emissions and completeness. Geographic completeness is consistent with the national Inventory. The sections
below provide more detail on each category.

Table 3-1. Overview of Approaches for Estimating State-Level IPPU Sector GHG Emissions

Category

Gas

Approach

Geographic Completeness

Cement

CO2

Hybrid approach

Includes emissions from all states,

Production



•	2010-2020: Approach 2

•	1990-2009: Approach 1

Washington D.C., and territories (i.e., Puerto
Rico) as applicable.

Lime Production

CO2

Approach 2

Includes emissions from all states,
Washington D.C., and territories (i.e., Puerto
Rico) as applicable.

Glass Production

CO2

Approach 2

Includes emissions from all states,
Washington D.C., and territories1 (i.e., Puerto
Rico) as applicable.

Other Process

CO2

Approach 2

Includes emissions from all states,

Uses of





Washington D.C., and territories1 (i.e., Puerto

Carbonates





Rico, American Samoa, Guam, Northern
Mariana Islands, U.S. Virgin Islands) as
applicable.

Carbon Dioxide

CO2

Approach 2

Includes emissions from all states,

Consumption





Washington D.C., and territories1 (i.e., Puerto
Rico, American Samoa, Guam, Northern
Mariana Islands, U.S. Virgin Islands) as
applicable.

Ammonia

CO2

Approach 2

Includes emissions from all states,

Production





Washington D.C., and territories as applicable.

Urea

CO2

Approach 2

Includes emissions from all states,

Consumption for





Washington D.C., and territories1 (i.e., Puerto

Nonagricultural





Rico, American Samoa, Guam, Northern

Purposes





Mariana Islands, U.S. Virgin Islands) as
applicable.

Nitric Acid

l\l20

Approach 2

Includes emissions from all states,

Production





Washington D.C., and territories as applicable.

Adipic Acid

l\l20

Approach 1

Includes emissions from all states,

Production





Washington D.C., and territories as applicable.

Caprolactam,

l\l20

Approach 2

Includes emissions from all states,

Glyoxal and





Washington D.C., and territories as applicable.

Glyoxylic Acid







Production







Carbide

CO2

Hybrid approach

Includes emissions from all states,

Production and

CH4

• Production: Approach 1

Washington D.C., and territories1 (i.e., Puerto

Consumption



• Consumption: Approach 2

Rico) as applicable.

Titanium Dioxide

CO2

Approach 2

Includes emissions from all states,

Production





Washington D.C., and territories as applicable.

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Category

Gas

Approach

Geographic Completeness

Soda Ash

C02

Approach 1

Includes emissions from all states,

Production





Washington D.C., and territories as applicable.

Petrochemical

CO2

Approach 2

Includes emissions from all states,

Production

CH4



Washington D.C., and territories as applicable.

HCFC-22

HFCs

Hybrid approach

Includes emissions from all states,

Production



•	2010-2020: Approach 1

•	1990-2009: Approach 2

Washington D.C., and territories as applicable.

Phosphoric Acid

CO2

Approach 2

Includes emissions from all states,

Production





Washington D.C., and territories as applicable.

Iron & Steel

CO2

Approach 2

Includes emissions from all states,

Production and

cm



Washington D.C., and territories as applicable.

Metallurgical







Coke Production







Ferroalloys

C02

Approach 2

Includes emissions from all states,

Production

cm



Washington D.C., and territories as applicable.

Aluminum

CO2

Hybrid approach

Includes emissions from all states,

Production

PFCs

•	2010-2020: Approach 1

•	1990-2009: Approach 2

Washington D.C., and territories as applicable.

Magnesium

CO2

Hybrid approach

Includes emissions from all states,

Production and

SFs

• 1999-2020: Approach 1 & 2

Washington D.C., and territories as applicable.

Processing

HFCs

• 1990-1998: Approach 2



Lead Production

CO2

Approach 2

Includes emissions from all states,

Washington D.C., and territories as applicable.

Zinc Production

CO2

Approach 2

Includes emissions from all states,

Washington D.C., and territories as applicable.

Electronics

N2O

Hybrid approach

Includes emissions from all states,

Industry

NFs
SFs
HFCs
PFCs

•	2011-2020: Approach 1 & 2

•	1990-2010: Approach 2

Washington D.C., and territories as applicable.

Substitution of

HFCs

Hybrid approach

Includes emissions from all states,

Ozone-Depleting

PFCs



Washington D.C., and territories1 (i.e., Puerto

Substances





Rico, American Samoa, Guam, Northern
Mariana Islands, U.S. Virgin Islands) as
applicable.

Electrical

SFs

Hybrid approach

Includes emissions from all states,

Transmission



• 2011-2020: Approach 1 & 2

Washington D.C., and territories1 (i.e., Puerto

and Distribution



• 1990-2010: Approach 2

Rico, U.S. Virgin Islands) as applicable.

Nitrous Oxide

N2O

Approach 2

Includes emissions from all states,

from Product





Washington D.C., and territories1 (i.e., Puerto

Uses





Rico, American Samoa, Guam, Northern
Mariana Islands, U.S. Virgin Islands) as
applicable.

1 Emissions are likely occurring in other U.S. territories; however, due to a lack of available data and the nature of this category,
this analysis includes emissions for only the territories indicated. Territories not listed are not estimated.

3.1 Minerals

This section presents the methodology used to estimate the minerals portion of IPPU emissions, which consist
of the following sources:

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•	Cement production (CO2)

•	Lime production (CO2)

•	Glass production (CO2)

•	Other process uses of carbonates (CO2)

•	Carbon dioxide consumption (CO2)

3.1.1 Cement Production (NIR Section 4.1)

3.1.1.1	Background

Cement Production is an energy- and raw material-intensive process that results in the generation of CO2 both
from the energy consumed in making the clinker precursor to cement and from the chemical process to make the
clinker. Emissions from fuels consumed for energy purposes during the production of cement are accounted for in
the energy sector. Process emissions from cement production are based primarily on clinker production. During
the clinker production process, the key reaction occurs when calcium carbonate (CaC03), in the form of limestone
or similar rocks, is heated in a cement kiln at a temperature range of about 700 to 1,000 degrees Celsius (1,300 to
1,800 degrees Fahrenheit) to form lime (i.e., calcium oxide, or CaO) and CO2 in a process known as calcination or
calcining. The quantity of CO2 emitted during clinker production is directly proportional to the lime content of the
clinker. During clinker production, some of the raw materials, partially reacted raw materials, and clinker enter the
kiln line's exhaust system as noncalcinated, partially calcinated, or fully calcinated cement kiln dust (CKD). To the
degree that the CKD contains carbonate raw materials that are returned to the kiln and calcined, there are
associated CO2 emissions.

Cement is produced in 34 states and Puerto Rico; in descending order, production is most concentrated in
Texas, Missouri, California, and Florida. In 2020, these four leading cement-producing states accounted for nearly
45% of U.S. production (USGS 2021).

3.1.1.2	Methods/Approach

To develop state-level estimates of emissions from cement production, national emissions from the national
Inventory were disaggregated using a combination of facility-level emissions data reported to the GHGRP from
2010-2020 as a surrogate for clinker production data and U.S. Geological Survey (USGS) clinker production data for
1990-2009 (EPA 2022), as shown in Table 3-2. See Appendix C, Table C-l and C-2 in the "Cement" Tab, for more
details on the data used.

This Hybrid approach, as defined in the Introduction chapter of this report, is used due to limitations in the
availability of state-specific activity data for the time series. While GHGRP clinker production data by state are
considered confidential business information, emissions data by state are not and are available for this analysis.
State-level emissions of CO2 from the production of cement were calculated using the Tier 2 method provided by
the 2006 IPCC Guidelines (IPCC 2006).

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Table 3-2. Summary of Approaches to Disaggregate the National Inventory for Cement Production Across
Time Series

Time Series Range

Summary of Method

2010-2020

• Applied national Inventory emissions factors to clinker production data
estimated using GHGRP emissions data (IPCC 2006 Tier 2).

1990-2009

• Applied the national Inventory emissions factors to actual and estimated clinker
production data from the USGS (IPCC 2006 Tier 2).

The Approach 2 method used for 2010-2020 was based on state-level emissions data from the GHGRP to
distribute clinker production by state. Facilities that use the Continuous Emissions Monitoring System (CEMS) to
measure emissions reported combined combustion and process emissions, while facilities that do not use CEMS
reported their process and combustion emissions separately. Using the data from facilities that do not use CEMS,
average annual process emissions factors were estimated and applied to the CEMS emissions data to estimate
process-only emissions by state. Those process emissions by state were converted into a percentage of national
process emissions and applied to national clinker production data to estimate state-level clinker production. Under
the GHGRP, any facility that manufactures Portland cement must report their GHG emissions regardless of the
level of emissions.

The Approach 1 method used for 1990-2009 relied on USGS clinker production data, which is the same data
source for the national Inventory. At the state level, the USGS reports clinker production for a few individual states
and combines other states in groups of two to four to protect company proprietary data. Because of limited
information about clinker production or other relevant proxy data by state, production for grouped states was
evenly divided among the states in the group to estimate clinker production.

National emissions factors for CO2 from clinker production and CKD from the national Inventory were applied
to state clinker production to calculate GHG emissions by state.

3.1.1.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from cement production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -6%/+6% for CO2.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of state-level clinker production data from the
same source used in the national Inventory and GHGRP emissions data by state as a surrogate for clinker
production data. These assumptions were required because of a general lack of more granular state-level data.

For the 2010-2020 period, GHGRP emissions by state were used to apportion clinker production over
individual states. Over 90% of the cement facilities use CEMS to measure CO2 emissions, which includes
combustion emissions as well as process emissions. Using the data from facilities that do not use CEMS, average
annual process emissions factors were estimated and applied to the CEMS emissions data to estimate process-only
emissions by state. Although this approach approximates GHG emissions from CEMS-monitored kilns, it is not
possible to state whether emissions are overestimated or underestimated.

While the USGS reports the clinker production for a few individual states, most state clinker production is
combined with the clinker production of multiple other states to protect sensitive production data of individual
facilities. For 1990-2009, the method of apportioning the grouped clinker production evenly among individual
states to estimate state GHG emissions likely results in overestimating emissions for some states and

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underestimating emissions for others. On a national scale, GHGRP clinker production closely approximates that
reported by the USGS.

3.1.1.4	Recalculations

No recalculations were applied for this current report consistent with the national Inventory (see Section 4.1,
page 4-14).

3.1.1.5	Planned Improvements

An important data gap is the production of clinker by each cement-producing state for the full time series
1990-2020. The USGS Mineral Yearbook series reports clinker production data for 11 individual states and Puerto
Rico; the remainder of the clinker production data are reported for groups of states to protect industry-sensitive
data. The EPA will assess whether industry GDP per state or other state-level data would provide a better way to
disaggregate this grouped data. Clinker capacity by facility for these states was considered, but incomplete data on
facilities' clinker capacity limited the ability to estimate clinker production in these groups of states. Additionally,
cement kilns do not typically operate at 100% capacity for an entire year, and utilization rates vary from kiln to
kiln, facility to facility, and year to year. Furthermore, the EPA is looking to reflect changes occurring in the cement
industry to modernize production methods that affect process emissions (e.g., improve kiln efficiency and
capacity). These and other factors will be examined to identify improvements in the methods used to estimate
state-level GHG emissions.

3.1.1.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas
Inventories. The National Greenhouse Gas Inventories Programme, Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Geological Survey. (January 2021). Mineral Commodity Summaries, Cement. U.S. Geological Survey, Reston,
VA.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

3.1.2 Lime Production (NIR Section 4.2)

3.1.2.1	Background

Lime is an important manufactured product with many industrial, chemical, and environmental applications.
Lime production involves three main processes: stone preparation, calcination, and hydration. CChis generated
during the calcination stage, when limestone—consisting of calcium (CaCOs) and/or magnesium (MgCOs)
carbonate—is roasted at high temperatures in a kiln to produce calcium oxide (CaO) and CO2. The CO2 is given off
as a gas and is normally emitted to the atmosphere. Emissions are also generated with the formation of calcined
waste produced during lime production, primarily lime kiln dust (LKD) and also off-spec lime, scrubber sludge, and
other miscellaneous waste. Some of the CO2 generated during the production process, however, is recovered at
some facilities for use in sugar refining and precipitated calcium carbonate production. Emissions from fuels
consumed for energy purposes during the production of lime are included in the energy sector. Lime production
emissions from the national Inventory were disaggregated to 28 states in 2020.

3.1.2.2	Methods/Approach

National estimates were downscaled across states because of limitations in availability of state-specific data
across the time series needed to apply national methods (i.e., IPCC Tier 2 methods) at the state level. The
Approach 2 methodology allocated gross process emissions from lime production to each producing state using a

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combination of process emissions reported to the GHGRP and the number of facilities in a state as surrogates for
lime production data. The number of facilities in a state that captured CO2 for use in on-site processes was then
used to calculate captured process emissions, which was subtracted from gross emissions to estimate net process
emissions, as shown in Table 3-3. The sum of emissions by state is consistent with national process emissions as
reported in the national Inventory. See Appendix C, Table C-3 through Table C-6 in the "Lime" Tab, for more details
on the data used.

Table 3-3. Summary of Approaches to Disaggregate the National Inventory for Lime Production Across
Time Series

Time Series Range

Summary of Method

2010-2020

•	GHGRP process emissions data were used to estimate the percentage of gross
emissions by state, multiplied by the national emissions (IPCC 2006 Tier 2).

•	GHGRP data on number and type of facilities that captured CO2 for use in on-site
processes were used to estimate the CO2 emissions captured and subtracted
from gross emissions to get net emissions from lime production.

1990-2009

•	USGS data on number of lime facilities were used to estimate the percentage of
lime production by state, multiplied by the national emissions (IPCC 2006 Tier 2).

•	GHGRP data on number of facilities that captured CO2 for use in on-site
processes from 2010-2019 were used to estimate the percentage of emissions
captured, multiplied by national emissions, and subtracted from gross emissions
to get net emissions from lime production.

The methodology used for 2010-2020 was based on process emissions data reported to the GHGRP summed
by state (EPA 2010-2020) to calculate a percentage of gross emissions from each state. That percentage was then
applied to the national emissions from lime production per year to calculate disaggregated gross CO2 emissions by
state. The GHGRP has a reporting threshold of 25,000 metric tons of CO2 equivalent for lime production, so these
emissions data are representative of the larger facilities in the industry. Using GHGRP emissions data means that
emissions from states with smaller facilities were possibly underestimated.

The methodology used for 1990-2009 was based on dividing the number of facilities in each state by the
number of facilities nationally to calculate a percentage of total U.S. facilities in each state for each year. This
percentage was applied to the gross national CO2 emissions from lime production per year (EPA 2021) to calculate
disaggregated gross CO2 emissions by state for each year. The number of facilities per state was compiled from the
USGS Minerals Yearbooks for Lime, Table 2, "Lime Sold or Used by Producers in the United States, by State" (USGS
1991-2010). For some years, the USGS aggregated the number of facilities for some states to avoid disclosing
proprietary information related to individual facility production. For those states and years, the individual state
facility counts were estimated based on the knowledge of facility locations in 2010-2019 and the number of
facilities in a state reported in the USGS Minerals Yearbook for Lime, Table 2 when that state was not aggregated.
In the absence of state-specific activity data, using the number of facilities per state to determine the state
allocation percentage assumes that each facility has the same amount of input and output.

The USGS Mineral Commodity Summaries for lime (1990-2020) only contain U.S. total lime production, with
no breakdown by lime type or state. While the USGS Minerals Yearbooks for Lime (1990-2017) have hydrated and
quicklime production data by region (Northeast, Midwest, South Atlantic, East South Central, West South Central,
and West), additional detail by high-calcium or dolomitic lime or by individual states is not available, and these
data could not be used as activity data in the state disaggregation estimates. Thus, the following activity data were
not available by state from current data sources used to estimate national emissions (USGS Minerals Yearbooks):
lime production data for high-calcium quicklime; dolomitic quicklime; high-calcium, hydrated; dolomitic, hydrated;

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dead-burned dolomite; and CO2 captured on-site. As such, these data could not be used as activity data in the state
disaggregation estimates.

Although the national Inventory value was adjusted to account for CO2 emissions from the production of LKD,
the state disaggregated values do not account for specific facility per state-level CO2 emissions from the
production of LKD. The adjustment to the national Inventory value was spread equally across the states with
facilities. In addition, the national Inventory value was not adjusted to account for CO2 emissions from other waste
production (e.g., off-spec lime, scrubber sludge, other miscellaneous site-specific waste).

CE MS Adjustment for 2010-2020

In 2010, facilities producing lime started reporting both process and combustion emissions to the GHGRP. For
facilities using a CEMS approach to measure and report CO2emissions, a combined total value for process and
combustion emissions were reported together under subpart S; otherwise, facilities reported process emissions
under subpart S and combustion emissions under subpart C using engineering and calculation approaches. To
disaggregate process emissions for those facilities reporting CO2 with CEMS, an industry-wide ratio of process
emissions to total emissions for facilities that do not report using CEMS was calculated for each year from 2010-
2020. While some facilities produce lime as a secondary product, facilities using CEMS were found to produce lime
as a primary product with a primary North American Industry Classification System (NAICS) code of 327410 for lime
manufacturing. Emissions reported to subpart S and C were compiled for all facilities with this NAICS code, and the
ratio of process emissions to total emissions for non-CEMS facilities was applied to the total CO2 emissions for each
CEMS facility to calculate process emissions for each year that emissions were reported using CEMS. The results
were an estimated process CO2 emissions-only value for that CEMS facility.

Because the methodology for 1990-2009 does not use GHGRP emissions data to calculate the state emissions,
there is no need to adjust for CEMS facilities for those years.

Adjustment for C02 Captured for Use in On-Site Processes

Some facilities recover CO2 generated during the lime production process for use in sugar refining and
precipitated calcium carbonate (PCC) production. Emissions from use of lime for sugar refining are reported under
Section 3.1.4, Other Process Uses of Carbonates. PCC is used as a filler or coating in the paper, food, and plastic
industries and is derived from reacting hydrated high-calcium quicklime with CO2. Per the 2006 IPCC Guidelines, it
is assumed that the recovery of CO2 for use in the sugar refining process, and PCC production does not result in net
emissions of CO2 to the atmosphere. Consistent with the national Inventory methodology, gross emissions per
state from lime production were adjusted to subtract the amount of CO2 captured for use in on-site processes such
as purification.

For 2010-2020, although the quantity of CO2 captured on-site at a facility was reported to the GHGRP, these
data are considered confidential business information (CBI) and are not available by facility or state; they are,
however, available at the aggregated national level and are used in the national Inventory. Which facilities
captured CO2 for on-site use in 2010-2020 and the states where these facilities are located are publicly available
through the GHGRP. The GHGRP indicator of CO2 capture on-site along with each facility's reported primary NAICS
code were used to identify two types of facilities capturing CO2 on-site: Beet Sugar Manufacturing (NAICS 311313)
and Lime Manufacturing (NACIS 327410). For beet sugar manufacturing facilities capturing CO2 on-site in 2010-
2020, all process emissions generated from the lime kiln were assumed to be captured and used on-site for further
beet sugar manufacturing, resulting in net zero CO2 emissions. Note that some states with beet sugar
manufacturing facilities that capture CO2 also have additional facilities that do not capture CO2, resulting in net CO2
emissions greater than zero.

To estimate the quantity of CO2 captured for beet manufacturing facilities per state per year for 2010-2020,
each facility's reported GHGRP process CO2 emissions per year were divided by the total annual GHGRP process

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CO2 value per year. The facility percentage values were summed by state and applied to the national Inventory
gross CO2 emissions value. The resulting state quantities of CO2 captured for beet manufacturing facilities were
summed for a total value of CO2 captured for beet sugar manufacturing facilities, which was subtracted from the
GHGRP national captured CO2 value to calculate the quantity of captured CO2 at lime manufacturing plants. The
quantity of captured CO2 for lime manufacturing facilities was divided by the total number of lime manufacturing
facilities capturing CO2 per year to calculate a per-facility CO2 captured value per year. The lime manufacturing per
facility CO2 captured value was then allocated to each lime manufacturing plant that captures CO2 per state and
year.

For 1990-2009, because of a lack of available data on both the quantity of CO2 captured on-site at facilities
per state for all years and on the number of facilities that captured CO2 on-site in 2009, an alternative
methodology was devised to estimate the quantity of emissions captured, based on available GHGRP data. The
number of facilities that captured CO2 for on-site use in 2010-2019 and their locations were used to estimate the
number of facilities in each state that captured CO2 for use in on-site processes in 1990-2009. The number of
facilities that captured CChon-site in a state was divided by the total number of facilities in the state was divided
by the total number for 2010-2019 to calculate a percentage of facilities in the state capturing CO2. The annual
percentages for 2010-2019 were averaged and then applied to the number of facilities per state for each year in
1990-2009 to estimate the number of facilities per state that captured CO2 on-site.

In the absence of available state or facility data, the current methodology for 1990-2009 distributed annual
CO2 captured on-site evenly among all facilities that reported capturing CO2 on-site to the GHGRP, assuming that
all facilities that captured CO2 on-site captured the same quantity of emissions each year. To estimate the quantity
of CO2 captured on-site for 1990-2009 per state, the number of facilities per state that captured CO2 on-site in
2010-2019 was divided by the total number of facilities across the country that captured CO2 on-site for each year
over the same time period to calculate state allocation percentages. Each state's percentage was applied to the
national data on CO2 captured on-site to estimate the quantity of CO2 captured on-site per state per year. These
values were subtracted from the gross CO2 emissions to calculate net CO2 emissions by state.

3.1.2.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from lime production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -2%/+2% for CO2.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of GHGRP emissions data for 2010-2020 and
the estimated number of facilities for 1990-2009. These assumptions were required because of a general lack of
more granular state-level data.

For 1990-2009, the methodology does not differentiate between the type of lime produced at a facility
because of a lack of available data, which increases uncertainty. The chemical composition of the limestone and
dolomite feedstocks is different, resulting in different emissions factors for calculating CO2. This difference has the
potential to under- or overestimate CO2 emissions from a facility, depending on the types of lime produced.

The diversity of lime manufacturing facility types adds uncertainty to the analysis. The current methodology
for 1990-2009 assumes that each facility has the same amount of inputs and outputs, which overestimates
emissions for smaller facilities (e.g., beet sugar manufacturing) and underestimates emissions for larger facilities
(e.g., lime manufacturing). The 1990-2009 methodology for estimating the quantity of CO2 captured on-site does
not differentiate between the type of facility (e.g., beet sugar manufacturing compared with lime manufacturing),
which increases uncertainty. The resulting captured CO2 values may overestimate the quantify of CO2 captured

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from beet manufacturing facilities, while underestimating the quantity of CO2 captured from lime manufacturing
facilities.

Additionally, some lime facilities go idle for periods of time, and the lack of data on when a facility is in
operation or idle during the year increases uncertainty in the analysis. The GHGRP does not currently acquire
information on whether or how long plants are idled.

3.1.2.4	Recalculations

No recalculations were applied for this current report consistent with the national Inventory (see Section 4.2,
page 4-20).

3.1.2.5	Planned Improvements

The EPA will consider weighting gross CO2 emissions and captured CO2 emissions by the type of facility
(primary NAICS code) to better allocate CO2 emissions and reduce the uncertainty around over- or underestimating
emissions for certain facility types. Of the facilities reporting to the lime subpart S under the GHGRP, seven
different types of facilities reported using the following primary NAICS codes: 212312 (Crushed and Broken
Limestone Mining and Quarrying), 212391 (Potash, Soda, and Borate Mineral Mining), 311313 (Beet Sugar
Manufacturing), 327125 (Nonclay Refractory Manufacturing), 327310 (Cement Manufacturing), 327410 (Lime
Manufacturing), and 331111 (Iron and Steel Mills).

Further refinements include identifying additional sources of data to confirm facilities within each state for
1990-2009 and better reflect their associated production (including production by type of lime), especially for the
states that were aggregated in the USGS Minerals Yearbooks. Another potential refinement includes assessing the
range of facilities' production quantity or capacity and improving on the current underlying assumption associated
with using the number of facilities to estimate emissions.

Another potential refinement is to improve the CaO contents and emissions factors used for estimating CO2
emissions from high-calcium lime and dolomitic lime. Consistent with the 2006 IPCC Guidelines, the current CaO
content is assumed to be 95% for both high-calcium and dolomitic lime, which results in emissions factors of 0.785
metric ton CO2 per metric ton CaO for high-calcium and 0.913 metric ton CO2 per metric ton CaO for dolomitic
lime. The average CaO contents and emissions factors per product are reported to the GHGRP but are considered
CBI. Data aggregation may address CBI concerns.

Potential refinements also include identifying additional information to determine which facilities captured
CO2 on-site in 1990-2009, prior to GHGRP reporting. Most but not all of the beet sugar manufacturing facilities
reporting to the GHGRP captured CO2 on-site; in 2020, three lime manufacturing facilities that reported to GHGRP
captured CO2 on-site. In addition, further research on the use and prevalence of capturing CO2 for use in on-site
processes in 1990-2009 is needed. The current methodology assumes that facilities captured CO2 on-site over the
full time series and that the quantity of emissions captured is evenly distributed among those facilities. More
research on the range of CO2 captured on-site per facility and per year is needed. EPA plans to initiate a review to
understand if PCC production practices have changed and if literature is available since the publication of the 2006
IPCC guidelines to understand if any CO2 is ultimately emitted from the use of captured CO2 in PCC production or
during sugar refining purification processes.

The EPA will review time-series consistency issues, due to the two methodologies for 1990-2009 and 2010-
2020. Surrogate data (number of facilities per state and number of facilities per state capturing CO2 on-site) were
used in place of activity data for the 1990-2009 portion of the time series, and more research is needed so that
calculations more closely simulate state trends in emissions.

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3.1.2.6 References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2010-2020). Greenhouse Gas Reporting Program (GHGRP). Envirofacts
GHGRP subpart S and subpart C data. Accessed May 7, 2022. Available online at:
https://www.epa.gov/enviro/greenhouse-gas-customized-search

U.S. Environmental Protection Agency. (2021). Greenhouse Gas Reporting Program (GHGRP). Aggregation of

Reported Facility Level Data under Subpart S-National Lime Production for Calendar Years 2010 through 2020.
Office of Air and Radiation, Office of Atmospheric Programs, U.S. Environmental Protection Agency,
Washington, DC.

U.S. Environmental Protection Agency. (2021). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2019
(EPA 430-R-21-005), Chapter 4: Industrial Processes and Product Use. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (1991). 1990 Minerals Yearbook: Lime. Table 4. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1992). 1991 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1993). 1992 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1994). 1993 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1995). 1994 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1996). 1995 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1997). 1996 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1998). 1997 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1999). 1998 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2000). 1999 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2001). 2000 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2002). 2001 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2003). 2002 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2004). 2003 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

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U.S. Geological Survey. (2005). 2004 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2006). 2005 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2007). 2006 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2008). 2007 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2009). 2008 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2010). 2009 Minerals Yearbook: Lime. Table 2. Lime Sold or Used by Producers in the
United States, by State. U.S. Geological Survey, Reston, VA.

3.1.3 Glass Production (NIR Section 4.3)

3.1.3.1	Background

Glass production is an energy- and raw material-intensive process that results in the generation of CO2 from
both the energy consumed in making glass and the glass production process itself. Emissions from fuels consumed
for energy purposes during the production of glass are included in the energy sector. The raw materials (primarily
soda ash, limestone, and dolomite) release CO2 emissions in a complex high-temperature chemical reaction during
the glass melting process. This process is not directly comparable to the calcination process used in lime
manufacturing, cement manufacturing, and process uses of carbonates (i.e., limestone/dolomite use) but has the
same net effect in terms of CO2 emissions. In 2020, glass was produced in 29 states (GHGRP 2021).

3.1.3.2	Methods/Approach

The national Inventory method was adapted to calculate state-level GHG emissions from glass production to
ensure consistency with national estimates (EPA 2022). National estimates were downscaled across states, instead
of reapplying the national Tier 3 methodology at the state level, because of limitations in availability of state-
specific data across the time series.

To compile process emissions by state from glass production, an Approach 2 methodology was used to
allocate process emissions to all states with glass production using a combination of process emissions reported to
the GHGRP for 2010-2020 and the number of glass facilities in each state for 1990-2009, as shown in Table 3-4.
The sum of emissions by state is consistent with national process emissions as reported in the national Inventory.
See Appendix C, Tables C-7 and C-8 in the "Glass" Tab, for more details on the data used.

Table 3-4. Summary of Approaches to Disaggregate the National Inventory for Glass Production Across
Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP process emissions data were used to estimate the percentage of

emissions by state, multiplied by the national emissions (2006 IPCC Guidelines
Tier 3).

1990-2009

• Data on number of glass facilities were used to estimate the percentage of
production by state, multiplied by the national emissions (2006 IPCC Guidelines
Tier 3).

The method used for 2010-2020 was based on process emissions reported to the GHGRP summed by state
(GHGRP 2021) to calculate a percentage of emissions from each state. That percentage was then applied to the

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national emissions from glass production per year to calculate disaggregated CO2 emissions by state. GHGRP has a
reporting threshold of 25,000 metric tons CO2 for glass production, so these emissions data are representative of
the larger glass producers in the industry. The GHGRP threshold excludes small entities (i.e., artisan facilities).

Using GHGRP emissions data means that emissions from states with smaller facilities were possibly
underestimated.

The method used for 1990-2009 was based on the number of glass facilities in each state divided by the
number of facilities nationally to calculate a percentage of glass facilities in each state for each year. This
percentage was applied to the national CO2 emissions from glass production per year (GHGRP 2021) to calculate
disaggregated CO2 emissions by state for each year. The number of facilities per state was estimated based on the
knowledge of facility locations in 2010-2020 and research on when these facilities and others began or ceased
operations. Using the number of facilities per state to determine the state allocation percentage assumes that
each facility has the same amount of input and output.

CEMS Adjustment for 2010-2020

Starting in 2010, facilities producing glass and emitting more than 25,000 metric tons of CO2 equivalent per
year reported both process and combustion emissions to the GHGRP. For facilities using a CEMS approach to
measure and report CO2 emissions, process and combustion emissions were reported together under subpart N;
otherwise, facilities reported process emissions under subpart N and combustion emissions under subpart C using
engineering and calculation approaches.22 To disaggregate process emissions for those facilities reporting CO2 with
CEMS, the ratio of process emissions to total emissions for facilities that do not report using CEMS was calculated
for each year from 2010-2020 and applied to the total CO2 emissions for each CEMS facility to calculate process
emissions for each year that emissions were reported using CEMS. The results were an estimated process CO2
emissions-only value for that CEMS facility.

Because the methodology for 1990-2009 does not use GHGRP emissions data to calculate the state emissions,
there was no need to adjust for CEMS facilities for those years.

3.1.3.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of C02 from Glass Production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -2%/+2% for C02.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of GHGRP emissions data for 2010-2020 and
the estimated number of facilities for 1990-2009.

For 2010-2020, uncertainty is expected to be lower than for 1990-2009 because of the use of GHGRP
emissions data by state to calculate emissions; however, because the sum of GHGRP emissions from glass
production is higher than the national Inventory emissions from glass production and the GHGRP does not include
emissions from smaller glass production facilities, this methodology could underestimate emissions in states with
smaller facilities and overestimate emissions in states with larger facilities, potentially increasing the uncertainty of
the state-by-state percentage compared with the national Inventory.

For 1990-2009, this allocation method does not address facilities' production capacities or utilization rates,
which vary from facility to facility and from year to year. Because this approach assumes emissions from all

22 For more information on the GHGRP, see 74 FR 56374, Oct. 30, 2009. Available online at:
https://www.eovinfo.eov/content/pke/FR-2009-10-30/pdf/E9-23315.pdf.

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facilities are equal regardless of production capacity or utilization rates, this approach could overestimate
emissions in states with higher shares of smaller facilities and underestimate emissions in states with larger
facilities.

3.1.3.4	Recalculations

A new methodology was implemented for the current national Inventory, using more complete activity data
from the GHGRP for 2010-2020 and the industrial production index for glass and glass product manufacturing
from the Federal Reserve for 1990-2009 to address time-series consistency. The revised values for 1990 through
2019 resulted in increased emissions estimates for all years. Across the time series, national emissions increased
by an average of 52% compared to the previous Inventory. For 23 states, emissions increased between 51% and
55% over the time series.

3.1.3.5	Planned Improvements

Potential refinements include identifying data to improve the completeness of state allocation and reflect
smaller facilities. Data gaps to calculate emissions from glass production include partial datasets on glass
production by state and the number of glass facilities by state for the full time series. GHGRP has a reporting
threshold for glass production facilities; facilities emitting more than 25,000 metric tons of CO2 equivalent per year
must report to the program. Facilities emitting less emissions per year were not captured in GHGRP data and are
not reflected in this state-level estimate; therefore, it is likely that emissions from smaller facilities are being
attributed to larger facilities that report to GHGRP. Facilities with lower emissions (e.g., artisan glass production
facilities) were not captured in this estimation. The EPA could apply other methods that may improve estimates if
more complete activity data are available by state (e.g., glass production, carbonate consumption used for glass
production, glass sales data by state, or gross domestic product related to glass production by state).

The EPA will assess the consistency of the estimates over time, given the use of two approaches to compile
state-level estimates, to ensure that changes in estimates over time are not significantly biased by methodological
and data approaches to the extent possible.

3.1.3.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Environmental Protection Agency Greenhouse Gas Reporting Program (GHGRP). (2021). Dataset as of August
7, 2021. Available online at: https://ghgdata.epa.gov

3.1.4 Other Process Uses of Carbonates (NIR Section 4.4)

3.1.4.1 Background

Limestone, dolomite, and other carbonates such as soda ash, magnesite, and siderite are basic materials used
by a wide variety of industries, including construction, agriculture, chemical, metallurgy, glass production, and
environmental pollution control. This section addresses only limestone, dolomite, and soda ash use. For industrial
applications, carbonates such as limestone and dolomite are heated sufficiently enough to calcine the material and
generate CO2 as a by-product. Emissions from limestone and dolomite used in other process sectors, such as the
production of cement, lime, glass, and iron & steel, were excluded from this category and are reported under their

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respective source sections (e.g., Glass Production). Emissions from soda ash production are reported under soda
ash production. Emissions from soda ash consumption associated with glass manufacturing are reported under
glass production. Emissions from the use of limestone and dolomite in liming of agricultural soils are included in
the agriculture chapter under liming. Emissions from fuels consumed for energy purposes during these processes
are accounted for in the energy sector. Both lime and limestone can be used as a sorbent for flue gas
desulfurization (FGD) systems. Emissions from lime consumption for FGD systems are reported under lime
production.

3.1.4.2 Methods/Approach

The Approach 2 state-level methodology for Other Process Uses of Carbonates allocates total national process
emissions to all applicable U.S. states and territories using state-level consumption of limestone and dolomite and
state population as a surrogate for soda ash consumption, due to limitations in availability of state-specific data.

Limestone and Dolomite Consumption

National CO2 emissions from the consumption of limestone and dolomite for emissive sources, including flux
stone, FGD systems, chemical stone, mine dusting or acid water treatment, acid neutralization, and sugar refining,
were calculated based on USGS data on the national-level consumption of each carbonate for each end use. The
USGS does not provide the state-level consumption of limestone and dolomite for each end use; however, the
USGS does publish annual state-level data on the total consumption of each carbonate. Because no other source of
data on state-level limestone and dolomite consumption were identified for any of the emissive sources, the USGS
total consumption data by state were used.

For 1991 and 1993-2020, state-level CO2 emissions for the national Inventory were estimated using the USGS
annual state-level values for limestone and dolomite sold or used by producers compiled from the USGS Minerals
Yearbook for Crushed Stone (U.S. Bureau of Mines 1991-1995, USGS 1995-2021, 2022). The national CO2
emissions from limestone and dolomite consumption were disaggregated independently by calculating the fraction
of each state-level consumption for each carbonate and applying that fraction to the national-level CO2 estimated
for each of the two carbonates in the national Inventory. The USGS state-level consumption data exclude the
District of Columbia and territories; therefore, CO2 emissions from limestone and dolomite consumption were not
estimated for those states.

During 1990 and 1992, the USGS did not publish limestone and dolomite consumption by state. Data on
consumption by state for 1990 were estimated by applying the 1991 ratios of total limestone and dolomite
consumption by state to total 1990 limestone and dolomite consumption values. Similarly, the 1992 consumption
figures were approximated by applying an average of the 1991 and 1993 ratios of total limestone and dolomite use
by state to the 1992 total values. For 2019 and 2020, no data on limestone and dolomite consumption were
available from the USGS, so state-level consumption values from 2018 were used as a proxy for these years.

In 1991 and 1993-2006, certain state-level limestone and dolomite consumption data were withheld from the
USGS publications to avoid disclosing proprietary information. Those limestone and dolomite values were
aggregated and included in a category entitled "Other." To ensure that the total reported consumption values for
both limestone and dolomite were accounted for, the "Other" value was equally distributed to the states for which
consumption data were withheld. In 1991, the USGS provided an "Other" value for limestone consumption;
however, no states that were included in the state-level table contained an indication that data were withheld. To
account for this limestone usage, the "Other" value was proportionally allocated to all of the states for which data
were reported in 1991 based on their reported usage. See Appendix C, Table C-9 through Table C-12 in the "Other
Process Uses of Carbonates" Tab, for more details on the data used.

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Soda Ash Consumption Not Associated with Glass Manufacturing

The national Inventory also estimates national CO2 emissions from the consumption of soda ash. Excluding
soda ash consumption for glass manufacturing, most soda ash is consumed in chemical production, with minor
amounts used in soap production, pulp and paper, FGD, and water treatment. Emissions from soda ash
consumption from glass manufacturing are accounted for under Section 4.3 Glass Production. Data on the
consumption of soda ash by state, however, are not available, and due to the distribution of these end-uses across
the country and lack of other surrogate data on end uses by state, population was used to allocate emissions. To
calculate state-level CO2 emissions from soda ash consumption, national CO2 estimates from the national Inventory
were distributed among the 50 states, the District of Columbia, Puerto Rico, American Samoa, Guam, Northern
Mariana Islands, and U.S. Virgin Islands using U.S. population statistics as a surrogate for data on soda ash
consumption not associated with glass manufacturing (U.S. Census Bureau 2002, 2011, 2021, 2022, Instituto de
Estadisticas de Puerto Rico 2021). For each year in the 1990-2020 time series, the fraction of the total U.S.
population in each state, the District of Columbia, and territories was calculated by dividing the state population by
the total U.S. population. To estimate CO2 emissions for each year by state, national Inventory CO2 emissions from
soda ash consumption were multiplied by each state's fraction of the total population for that year. See Appendix
G, Table G-l in the "Population Data" Tab, for more details on the data used.

3.1.4.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from other process uses of
carbonate was calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As
described further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the
national estimates in 2020 were -19%/+28% for CO2.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based on state data of total limestone and dolomite consumption and state
population for soda ash consumption.

3.1.4.4	Recalculations

Emissions from carbonate consumption for magnesium metal production previously included in this chapter
have been moved from Other Process Uses of Carbonates to Magnesium Production and Processing (CRF Source
Category 2C4) in this inventory, consistent with the 2006 IPCC Guidelines and the 2022 national Inventory report.
Emissions were removed from this chapter for 1990 through 2001, resulting in approximately 50 to 70 kt CO2
reduction for these years for Washington state.

Emissions previously included in this chapter for limestone consumption for sugar refining have been removed
in this inventory, as it was determined that these emissions are already accounted for in the lime production
source category emissions. This is consistent with the 2022 national Inventory report. Emissions were removed
from this chapter for 1990 through 2019, resulting in a range of 0 to 1,500 kt CO2 reduction for these years.
Additionally, for the current Inventory, updated USGS data on limestone and dolomite consumption were available
for 2019, resulting in updated emissions estimates for that year. Compared to the previous Inventory, emissions
for 2019 increased by 32% (2,391 kt CO2 equivalent).

Recalculations were performed for the 1990-2019 time series to reflect the addition of population data for
four U.S. territories not previously included: American Samoa, Guam, Northern Mariana Islands, and U.S. Virgin
Islands. The addition of these territories had a negligible impact on the emissions estimated from soda ash
consumption for the 50 states, the District of Columbia, and Puerto Rico due to their small population sizes.

Additional recalculations for emissions from soda ash consumption were performed for the 2010-2019 time
series as updated population data were made available from the U.S. Census Bureau for the time series. The

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updated population data had a negligible impact on the emissions estimated for the 50 states, the District of
Columbia, and Puerto Rico due to the low emissions estimated for each state or territory for the sector.

3.1.4.5	Planned Improvements

The disaggregation methodology for limestone and dolomite consumption does not take into account the
consumption of these carbonates from the l&S sector, as is done in the national Inventory CO2 emissions
calculations. Given that the methodology for the disaggregation of the l&S sector was developed concurrently with
this sector, the EPA was not able to fully assess if the state-level percentages for the l&S sector could be applied to
the l&S limestone and carbonate consumption and then subtracted out from each of the state-level CO2 emissions
calculated using the methodology described above. Initial attempts yielded negative CO2 emissions in certain
states, thus requiring additional review and likely refinement of approaches to disaggregate these emissions.

Additionally, further research is needed to determine if data sources may be available to attribute CO2
emissions more accurately from each of the emissive sources for limestone and dolomite consumption to each
state. Currently, it is assumed that limestone and dolomite consumption for flux stone, FGD systems, chemical
stone, mine dusting or acid water treatment, acid neutralization, and sugar refining activities is distributed equally
geographically among all states, excluding the District of Columbia and Puerto Rico.

Data gaps for the soda ash consumption category include data on soda ash consumption by state.

3.1.4.6	References

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Bureau of Mines. (1991 through 1995). Minerals Yearbook 1990,1991,1992,1993.

U.S. Census Bureau. (2022). International Database: World Population Estimates and Projections. Accessed January
4, 2022. Available online at: https://www.census.gov/programs-survevs/international-
programs/about/idb.html

U.S. Census Bureau, Population Division. (2002). Table CO-EST2001-12-00—Time Series of Intercensal State
Population Estimates: April 1,1990 to April 1, 2000, Release Date: April 11, 2002.

U.S. Census Bureau, Population Division. (2011). Table 1. Intercensal Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01), Release Date:
September 2011.

U.S. Census Bureau, Population Division. (2021). Table 1. Annual Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2010 to July 1, 20202 (NST-EST2020), Release Date:
July 2021.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventory-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (1995 through 2021). Minerals Yearbook: Crushed Stone Annual Report. U.S. Geological
Survey, Reston, VA.

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U.S. Geological Survey. (2022). Advanced Data Release of the 2018 Annual Tables, Minerals Yearbook: Crushed
Stone Annual Report. U.S. Geological Survey, Reston, VA. Posted April 28, 2022. Available online at:
https://www.usgs.gov/centers/national-minerals-information-center/crushed-stone-statistics-and-
information

3.1.5 Carbon Dioxide Consumption (NIR Section 4.15)

3.1.5.1	Background

CO2 is used for a variety of commercial applications, including food processing, chemical production,
carbonated beverage production, and refrigeration, and is also used in petroleum production for enhanced oil
recovery (EOR). CChused for EOR is injected underground to enable additional petroleum to be produced. For the
purposes of this analysis, CO2 used in commercial applications other than EOR is assumed to be emitted to the
atmosphere. A further discussion of CO2 used in EOR is described in the national Inventory Energy chapter in Box 3-
6 titled "Carbon Dioxide Transport, Injection, and Geological Storage" and is not included in this section.

3.1.5.2	Methods/Approach

Data on the consumption of CO2 by state are not readily available; therefore, using an Approach 2 method, the
state-level methodology for emissions from CO2 consumption allocates emissions from CO2 consumption across all
U.S. states and territories using population as a surrogate. See Appendix G, Table G-l in the "Population Data" Tab,
for more details on the data used. National estimates were used to disaggregate emissions by state because of the
limitations in the availability of state-specific data for the time series. The approach is considered reasonable, given
many of the sources are end-use categories (e.g., carbonated beverage use, dry ice), where per capita use is not
likely to vary across states.

To calculate state-level CO2 emissions from CO2 consumption, national CO2 estimates from the national
Inventory were distributed among the 50 states, the District of Columbia, Puerto Rico, American Samoa, Guam,
Northern Mariana Islands, and U.S. Virgin Islands, using U.S. population statistics as a surrogate for CO2
consumption data (U.S. Census Bureau 2002, 2011, 2021, 2022; Instituto de Estadisticas de Puerto Rico 2021). For
each year in the 1990-2020 time series, the fraction of the total U.S. population in each state, the District of
Columbia, and each territory was calculated by dividing the state population by the total U.S. population.

3.1.5.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 consumption was calculated using
the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described further in Chapter 4
and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020 were
-5%/+5% for CO2.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based solely on state population. This assumption was required because of a
general lack of more granular state-level data. This allocation method introduces additional uncertainty because of
limited data on the quantity of CO2 consumption by state or nationally for the full time series. The sources of
uncertainty for this category are also consistent over time because the same surrogate data are applied across the
entire time series.

3.1.5.4	Recalculations

Recalculations were performed for the 1990-2019 time series to reflect the addition of population data for
four U.S. territories not previously included: American Samoa, Guam, Northern Mariana Islands, and U.S. Virgin
Islands. The addition of these territories had a negligible impact on the emissions estimated for the 50 states, the
District of Columbia, and Puerto Rico due to their small population sizes.

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Additional recalculations were performed for the 2010-2019 time series as updated population data were
made available from the U.S. Census Bureau for the time series. The updated population data had a negligible
impact on the emissions estimated for the 50 states, the District of Columbia, and Puerto Rico due to the low
emissions estimated for each state or territory for the sector.

3.1.5.5	Planned Improvements

The EPA will explore other sources of data on the consumption of CO2 by state for the full 1990-2019 time
series.

3.1.5.6	References

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Census Bureau. (2022). International Database: World Population Estimates and Projections. Accessed January
4, 2022. Available online at: https://www.census.gov/programs-survevs/international-
programs/about/idb.html

U.S. Census Bureau, Population Division. (2002). Table CO-EST2001-12-00—Time Series of Intercensal State
Population Estimates: April 1,1990 to April 1, 2000, Release Date: April 11, 2002.

U.S. Census Bureau, Population Division. (2011). Table 1. Intercensal Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01), Release Date:
September 2011.

U.S. Census Bureau, Population Division. (2021). Table 1. Annual Estimates of the Resident Population for the

United States, Regions, States, and Puerto Rico: April 1, 2010 to July 1, 2020 (NST-EST2020), Release Date: July
2021.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

3.2 Chemicals

This section presents the methodology used to estimate the chemicals portion of IPPU emissions, which
consist of the following sources:

•	Ammonia production (CO2)

•	Urea consumption for nonagricultural purposes (CO2)

•	Nitric acid production (N2O)

•	Adipic acid production (N2O)

•	Caprolactam, glyoxal and glyoxylic acid production (N2O)

•	Carbide production and consumption (CO2, CH4)

•	Titanium dioxide production (CO2)

•	Soda ash production (CO2)

•	Petrochemical production (CO2)

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•	HCFC-22 production (HFCs)

•	Phosphoric acid production (CO2)

3.2.1 Ammonia Production (NIR Section 4.5)

3.2.1.1	Background

Emissions of CO2 occur during the production of synthetic ammonia, primarily through the use of natural gas,
petroleum coke, or naphtha as a feedstock. The natural gas-, naphtha-, and petroleum coke-based processes
produce CO2 and hydrogen, the latter of which is used in the production of ammonia. Natural gas is also used as a
fuel in the process. The 2006 IPCC Guidelines recommend including emissions from fuels consumed for energy
purposes during the production of ammonia along with feedstock emissions; however, data on total fuel use
(including fuel used for ammonia feedstock and fuel used for energy) for Ammonia Production are not known in
the U.S. National energy use information is only available at the broad industry sector level and does not provide
data broken out by industrial category. Emissions from fuel used for energy at ammonia plants are accounted for
in the Energy sector. In 2020,16 companies operated 35 ammonia producing facilities in 16 states. As of 2020,
approximately 60% of domestic ammonia production capacity was concentrated in the states of Louisiana,
Oklahoma, and Texas (USGS 2021).

3.2.1.2	Methods/Approach

To compile emissions by state from ammonia production, the state-level inventory disaggregated national
emissions from the national Inventory with an Approach 2 method as defined in the Introduction chapter of this
report, using a combination of process emissions reported to the GHGRP for 2010-2020 and ammonia production
capacity by state by year for 1990-2009, as shown in Table 3-5. This approach was taken due to limitations in
state-level activity data on ammonia production by feedstock or feedstock consumption for ammonia production.
The sum of emissions by state is consistent with the process emissions reported in the national Inventory (EPA
2022). See Appendix D, Tables D-l and D-2 in the "Ammonia" Tab, for more on the data used.

Table 3-5. Summary of Approaches to Disaggregate the National Inventory for Ammonia Production
Across Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP (Subpart G) process emissions data were used to estimate the

percentage of emissions by state, multiplied by the national emissions (IPCC
2006 Tier 2).

1990-2009

• USGS data on ammonia production capacity were used to estimate the

percentage of production by state, multiplied by the national emissions (IPCC
2006 Tier 2).

The methodology used for 2010-2020 was based on process emissions reported to the GHGRP and summed
by state (GHGRP 2021) to calculate a percentage of emissions from each state. That state percentage was then
applied to the national Inventory emissions from ammonia production per year to disaggregate CO2 emissions by
state and by year and ensure emissions are consistent with estimates in the national Inventory. The GHGRP has no
reporting threshold for ammonia production, so all facilities are included, and these emissions data are, therefore,
representative of the industry.

Facilities began reporting process emissions to the GHGRP in 2010. To calculate earlier emissions, initial
research looked at using state- or region-specific permit websites to determine whether facilities in operation in
2010, known through the GHGRP, were also in operation each year from 1990-2009 and to estimate production
data by facility; however, the permit information lacked relevant data on ammonia production or feedstock

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consumption for all states and years, and more complete production capacity data were available in the USGS data
sources.

The methodology used for 1990-2009 was based on the total ammonia production capacity in each state
divided by the total ammonia capacity in the United States to calculate a percentage of ammonia capacity in each
state for each year. This percentage was applied to the national CO2 emissions from ammonia production per year
to calculate disaggregated CO2 emissions by state for each year. The ammonia capacities per facility per state were
compiled from the Minerals Yearbook: Metals and Minerals for Nitrogen, Table 5, "Domestic Producers of
Anhydrous Ammonia" for 1990 and 1991 (U.S. Bureau of Mines 1990-1991); the Minerals Yearbook: Metals and
Minerals for Nitrogen, Table 4, "Domestic Producers of Anhydrous Ammonia" for 1992 and 1993 (U.S. Bureau of
Mines 1992-1993); and the Minerals Yearbook: Nitrogen, Table 4, "Domestic Producers of Anhydrous Ammonia"
for 1994 through 2009 (USGS 1994-2010). Using the ammonia capacity per state to determine the state allocation
percentage assumes that facility utilization rates are roughly the same from state to state and that production
capacity is a reasonable surrogate for production.

3.2.1.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of C02 from ammonia production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -10%/+11% for C02.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of process emissions reported to the GHGRP for
2010-2020 and ammonia production capacity by state by year for 1990-2009. These assumptions were required
because of a general lack of more granular state-level data.

For 2010-2020, uncertainty is expected to be lower due to the use of GHGRP emissions data by state as a
surrogate for ammonia production data by state to calculate emissions; however, because the sum of GHGRP
emissions from ammonia production is higher than the national Inventory emissions from ammonia production,
the uncertainty of the state-by-state percentage may be higher. This may have led to over- or underestimating the
percentage of emissions apportioned to each state.

For 1990-2009, this allocation method does not address utilization rates, which vary from facility to facility
and from year to year. While this approach implicitly accounts for the size of a facility in a state, it could
overestimate emissions in states where facilities used less of their capacity and underestimate emissions in states
where facilities used more of their capacity, as a result of the lack of data on utilization rates.

3.2.1.4	Recalculations

Based on updated ammonia facility-level emissions obtained from the GHGRP for 2019, recalculations were
performed for 2019. Compared to the previous inventory, CO2 from ammonia production in 2019 increased by
2.0% (6 kt CO2) for Nebraska. Compared to the previous inventory, CO2 from ammonia production in Oregon
decreased by 3.0% (2 kt CO2) in 2016 and decreased by 12.0% (7 kt CO2) in 2018.

3.2.1.5	Planned Improvements

For the GHGRP emissions data used for 2010-2020, the quantity of CO2 that is captured at ammonia
production facilities and used to produce urea has not been subtracted and allocated under Urea Consumption for
Nonagricultural Purposes (Section 3.2.2) and Urea Fertilization (Section 4.2.4) because this data by state is
considered CBI and is not available. Reporters must report all CO2 created during the ammonia production process
under subpart G of the GHGRP. The amount of CO2 from the production of ammonia that is then captured and
used to produce urea is reported to the GHGRP. More research on possible aggregation options is needed.

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For the state-level ammonia capacity data used for 1990-2009, additional research is needed to determine
whether the capacities can be adjusted to account for facilities that also produce urea, to be consistent with the
national Inventory.

The EPA will review potential time-series consistency issues due to the two methodologies for 1990-2009 and
for 2010-2020. Surrogate data (production capacity) are used in place of activity data for the 1990-2009 portion of
the time series, and more research is needed so that calculations more closely simulate state trends in emissions.

3.2.1.6 References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Bureau of Mines. (1990 through 1993). Minerals Yearbook: Metals and Minerals: Nitrogen. Available online at:
https://www.usgs.gov/centers/nmic/bureau-mines-minerals-vearbook-1932-1993

U.S. Environmental Protection Agency Greenhouse Gas Reporting Program (GHGRP). (2021). Dataset as of August
7, 2021. Available online at: https://ghgdata.epa.gov/ghgp/

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (1994 through 2010). Minerals Yearbook: Nitrogen. Available online at:
https://www.usgs.gov/centers/nmic/nitrogen-statistics-and-information

U.S. Geological Survey. (2021) 2021 Mineral Commodity Summaries: Nitrogen (Fixed)—Ammonia. January 2021.
Available online at: https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-nitrogen.pdf

3.2.2 Urea Consumption for N on agricultural Purposes (NIR Section 4.6)

3.2.2.1	Background

Urea is produced using ammonia and CO2 as raw materials. All urea produced in the United States was
assumed to be produced at ammonia production facilities where both ammonia and CO2 are generated. This
section accounts for CO2 emissions associated with urea consumed exclusively for nonagricultural purposes.
Emissions of CO2 resulting from agricultural applications of urea are accounted for in the urea fertilization section
of the Agriculture chapter.

3.2.2.2	Methods/Approach

To compile emissions by state from ammonia production, the state-level inventory disaggregated national
emissions from the national Inventory with an Approach 2 method as defined in the Introduction chapter of this
report, using U.S. population statistics as a surrogate for data on nonagricultural applications of urea due to
limitations in the availability of state-specific activity data. See Appendix G, Table G-l in the "Population Data" Tab,
for more details on the data used.

The national Inventory estimates national CO2 emissions from the consumption of urea for nonagricultural
purposes consistent with the Tier 1 method for ammonia production in the 2006 IPCC Guidelines (IPCC 2006).

While data on the consumption of urea by state are not available, due to the widespread use of urea for
nonagricultural purposes, population by state is a reasonable surrogate. To calculate state-level CO2 emissions
from urea consumption, national CO2 estimates from the national Inventory were distributed among the 50 states,
the District of Columbia, Puerto Rico, American Samoa, Guam, Northern Mariana Islands, U.S. Virgin Islands, and
U.S. Minor Outlying Islands, using U.S. population statistics as a surrogate (U.S. Census Bureau 2002, 2011, 2021,

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2022; Instituto de Estadisticas de Puerto Rico 2021). For each year in the time series, the fraction of the total U.S.
population in each state, as well as the District of Columbia and the territories, was calculated by dividing the state
population by the total U.S. population. To estimate CO2 emissions for each year by state, national Inventory CO2
emissions from urea consumption were multiplied by each state's fraction of the total population for that year.

3.2.2.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from urea consumption for
nonagricultural purposes was calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty
(IPCC 2006). As described further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of
uncertainty in the national estimates in 2020 were -14%/+14% for CO2.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based solely on state population. This assumption was required because of a
general lack of more granular state-level data. This allocation method introduces additional uncertainty due to
limited data on the quantity of urea used for industrial applications by state or nationally for the full time series.
The sources of uncertainty for this category are consistent over time because the same surrogate data are applied
across the entire time series.

3.2.2.4	Recalculations

Recalculations were performed for the 1990-2019 time series to reflect the addition of population data for
five U.S. territories not previously included: American Samoa, Guam, Northern Mariana Islands, U.S. Virgin Islands,
and U.S. Minor Outlying Islands. Due to these territories' relatively small populations, adding them had a negligible
impact on the emissions estimated for the 50 states, the District of Columbia, and Puerto Rico.

Further recalculations were performed for the 2010-2019 time series as updated population data were made
available from the U.S. Census Bureau for the time series. The updated population data had a negligible impact on
the emissions estimated for the 50 states, the District of Columbia, and Puerto Rico due to the low emissions
estimated for each state or territory for the sector.

Based on updates to the national Inventory— updated quantities of urea applied for agricultural uses for 2014-
2019, updated national-level urea import data from the USGS for 2018 and 2019, and updated national-level urea
exports from the USGS for 2018 and 2019—recalculations were performed for 2014 through 2019. Compared to
the previous Inventory, state-level emissions increased for every state by less than 1.0% for 2014, between 1.4%
and 1.7% for 2015, between 3.6% and 4.0% for 2016, between 2.9% and 3.2% for 2017, and between 2.7% and
3.2% in 2018. For 2019, emissions for all states decreased between 2.7% and 3.2% compared to the previous
inventory.

3.2.2.5	Planned Improvements

Data gaps include data on urea consumption for nonagricultural purposes by state for the full 1990-2020 time
series.

3.2.2.6	References

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

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U.S. Census Bureau. (2022). International Database: World Population Estimates and Projections. Accessed January
4, 2022. Available online at: https://www.census.gov/programs-survevs/international-
programs/about/idb.html

U.S. Census Bureau, Population Division. (2002). Table CO-EST2001-12-00—Time Series of Intercensal State
Population Estimates: April 1,1990 to April 1, 2000, Release Date: April 11, 2002.

U.S. Census Bureau, Population Division. (2011). Table 1. Intercensal Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01), Release Date:
September 2011.

U.S. Census Bureau, Population Division. (2021). Table 1. Annual Estimates of the Resident Population for the

United States, Regions, States, and Puerto Rico: April 1, 2010 to July 1, 2020 (NST-EST2020), Release Date: July
2021.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (2021) 2021 Mineral Commodity Summaries: Nitrogen (Fixed)—Ammonia. January 2021.
Available at: https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-nitrogen.pdf.

3.2.3 Nitric A cid Production (NIR Section 4.7)

3.2.3.1	Background

Nitrous oxide (N2O) is emitted during the production of nitric acid (HNO3), an inorganic compound used
primarily to make synthetic commercial fertilizers. Nitric acid is also a major component in the production of adipic
acid—a feedstock for nylon—and explosives. Virtually all of the nitric acid produced in the United States is
manufactured by the high-temperature catalytic oxidation of ammonia. The basic process technology for
producing nitric acid has not changed significantly over time. During this process, N2O is formed as a by-product
and is released from reactor vents into the atmosphere, unless mitigation measures are put in place. Emissions
from fuels consumed for energy purposes during the production of nitric acid are included in the energy sector. As
of 2020, there were 32 active nitric acid production plants in 20 states (EPA 2022).

3.2.3.2	Methods/Approach

The national Inventory methodology was adapted to calculate state-level GHG emissions from nitric acid
production to ensure consistency with national estimates (EPA 2022). For the national Inventory, the 2006 IPCC
Guidelines Tier 2 method was used to estimate emissions from nitric acid production for 1990-2009, and a
country-specific approach similar to the IPCC Tier 3 method was used to estimate N2O emissions for 2010-2020.
(IPCC 2006).

To compile emissions by state from nitric acid production, the state-level inventory disaggregated national
emissions from the national Inventory using Approach 2 as defined in the Introduction chapter of this report and a
combination of process emissions reported to the GHGRP for 2010-2020 and nitric acid production capacity by
state by year for 1990-2009, as shown in Table 3-6. The sum of emissions by state is consistent with the national
process emissions reported in the national Inventory. See Appendix D, Tables D-3 and D-4 in the "Nitric Acid" Tab,
for more details on the data used.

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Table 3-6. Summary of Approaches to Disaggregate the National Inventory for Nitric Acid Production
Across Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP process emissions data were used to estimate the percentage of
emissions by state, multiplied by the national emissions (a country-specific
approach similar to IPCC 2006 Tier 3).

1990-2009

• ICIS data on nitric acid production capacity were used to estimate the percentage
of production by state, multiplied by the national emissions (IPCC 2006 Tier 2).

The methodology used for 2010-2020 was based on process emissions reported to the GHGRP and summed
by state (GHGRP 2021) to calculate a percentage of emissions from each state. That percentage was then applied
to the national Inventory emissions from nitric acid production per year to disaggregate CO2 emissions by state and
by year. The GHGRP has no reporting threshold for nitric acid production, so these emissions data are
representative of the industry.

The methodology used for 1990-2009 was based on the total nitric acid production capacity in each state
divided by the total nitric acid production capacity in the United States to calculate a percentage of nitric acid
capacity in each state for each year. This percentage was applied to the national CO2 emissions from nitric acid
production per year to calculate disaggregated CO2 emissions by state for each year. The nitric acid capacities per
facility per state were compiled from the EPA for 1984 and from ICIS for 2008 (EPA 1984, ICIS 2008). Due to limited
data availability, the capacity data for 1984 were applied to years 1990-2007, and the capacity data for 2008 were
applied to years 2008 and 2009. Using the nitric acid capacity per state to determine the state allocation
percentage assumed that facility utilization rates are roughly the same from state to state.

Additional research included using state-level or region-specific permit websites to determine whether
facilities in operation in 2010, known through the GHGRP, were also in operation each year from 1990-2009 and
to estimate production data by facility. Because of the lack of permit data available online for all states and years,
this approach was not used.

3.2.3.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of N2O from nitric acid production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -5%/+5% for N20.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of nitric acid production capacity by state by
year for 1990-2009 and process emissions reported to the GHGRP for 2010-2020. These assumptions were
required because of a general lack of more granular state-level data.

For 2010-2020, uncertainty is expected to be lower as a result of the use of GHGRP emissions data by state as
a surrogate for using nitric acid production data by state to calculate emissions. The uncertainty is also lower
because GHGRP emissions account for the use of any abatement technologies at nitric acid production facilities.
The GHGRP emissions are comparable to the national Inventory totals; therefore, the use of GHGRP emissions to
estimate the percentage of emissions by state does not appear to introduce greater uncertainty for this time
period.

For 1990-2009, this allocation method does not address utilization rates, which vary from facility to facility
and from year to year. While this approach implicitly accounts for the size of a facility in a state, it could
overestimate emissions in states where facilities used less of their capacity and underestimate emissions in states

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where facilities used more of their capacity as a result of the lack of data on utilization rates. This approach also
does not account for abatement technologies at nitric acid production facilities because the information is not
known for this time period; therefore, this approach could overestimate emissions in states where abatement
technologies were used.

3.2.3.4	Recalculations

No recalculations were applied for this current report.

3.2.3.5	Planned Improvements

Data gaps include nitric acid capacity and utilization rates per facility and state, information about abatement
technology installation and use per facility, and nitric acid production per state for the full time series.

The EPA will review time-series consistency issues due to the two methodologies for 1990-2009 and for 2010-
2020. Incomplete surrogate data (production capacity) were used in place of activity data for the 1990-2009
portion of the time series, and more research is needed to refine the method to enhance accuracy and consistency
of estimated state GHG emissions and trends.

3.2.3.6	References

Independent Commodity Intelligence Services. (2008). Chemical profile: nitric acid. Capacities by nitric acid
company as of May 15, 2008. Available online at:

https://www.icis.com/explore/resources/news/2008/05/19/9124327/chemical-profile-nitric-acid/

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (1984). Office of Air Quality Planning and Standards. Review of New Source
Performance Standards for Nitric Acid Plants. EPA Document number 450/3-84-011. Available online at:
https://nepis.epa.gov/Exe/ZvPDF.cgi/2000LT0V.PDF?Dockev=2000LT0V.PDF

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Environmental Protection Agency Greenhouse Gas Reporting Program (GHGRP). (2021). Dataset as of August
7, 2021. Available online at: https://ghgdata.epa.gov/ghgp/

3.2.4 Adipic Acid Production (NIR Section 4.8)

3.2.4.1 Background

Adipic acid is produced through a two-stage process during which N2O is generated in the second stage.
Emissions from fuels consumed for energy purposes during the production of adipic acid are accounted for in the
Energy sector. The first stage of manufacturing usually involves the oxidation of cyclohexane to form a
cyclohexanone/cyclohexanol mixture. The second stage involves oxidizing this mixture with nitric acid to produce
adipic acid. Nitrous oxide is generated as a by-product of the nitric acid oxidation stage and, without mitigation
technology, is emitted in the waste gas stream. Process emissions from the production of adipic acid vary with the
types of technologies and level of emissions controls employed by a facility. The largest facility producing adipic
acid uses an N2O abatement device, but its usage has varied considerably from year to year over the period from
2010-2020, resulting in varying levels of N2O control at that facility and varying levels of total N2O emissions over
that time period. Four adipic acid facilities, located in Florida, Texas, and Virginia, have produced adipic acid in the
United States over the period 1990-2020.

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3.2.4.2	Methods/Approach

The national Inventory methodology was used to calculate state-level GHG emissions, using an Approach 1
method as defined in the Introduction chapter of this report. The methodology for 2010-2020 used facility-level
process emissions reported to the GHGRP (GHGRP 2021). The methodology for 1990-2009 used emissions
calculations consistent with Tier 2 methods for two facilities and Tier 3 methods for the other two facilities, as
provided by the 2006 IPCC Guidelines (IPCC 2006). Emissions for each year were summed by state (GHGRP 2021)
to calculate a percentage of emissions from each state. That percentage was then applied to the national
emissions from adipic acid production over the full time series to calculate disaggregated CO2 emissions by state.
See Appendix D, Table D-5 in the "Adipic Acid" Tab, for more details on the data used. The GHGRP has no reporting
threshold for adipic acid production, so these emissions data are representative of the industry.

3.2.4.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of N2O from adipic acid production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -5%/+5% for N2O.

State-level estimates are expected to have a slightly higher level of uncertainty than the national Inventory
over the full time series as a result of the rounding of the facility-level GHGRP process emissions used to calculate
the percentage of emissions from each state.

3.2.4.4	Recalculations

Based on updated adipic acid facility-level emissions obtained from the GHGRP for 2016 through 2019,
recalculations were performed for these years. Compared to the previous inventory, N2O emissions from adipic
acid production in Texas for 2016 through 2018 increased by 20.2% (0.38 kt N2O), 13.8% (0.29 kt N2O), and 37.6%
(0.6 kt N2O), respectively. In 2019, the N2O emissions decreased in Texas by 4.5% (0.06 kt N2O).

3.2.4.5	Planned Improvements

There are no planned methodological refinements for the adipic acid production category.

3.2.4.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Environmental Protection Agency Greenhouse Gas Reporting Program (GHGRP). (2021). Dataset as of August
7, 2021. Available online at: https://ghgdata.epa.gov/ghgp/.

3.2.5 Caprolactam, Glyoxal, and Glyoxylic Acid Production (NIR Section 4.9)

3.2.5.1 Background

Caprolactam is a colorless monomer produced for nylon-6 fibers and plastics. A substantial proportion of the
fiber is used in carpet manufacturing. In the most commonly used caprolactam production process, benzene is
hydrogenated to cyclohexane, which is then oxidized to produce cyclohexanone, which in turn is used to produce
caprolactam. The production of caprolactam can give rise to significant emissions of N2O from the ammonia

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oxidation step. Since 1990, caprolactam has been produced in three states: Virginia, Texas, and Georgia. The
facility in Georgia closed in 2018.

The EPA does not currently estimate the emissions associated with the production of glyoxal and glyoxylic acid
because of data availability and a lack of publicly available information on the industry in the United States.

3.2.5.2	Methods/Approach

To compile emissions by state from caprolactam production, the state-level inventory disaggregated national
emissions from the national Inventory with an Approach 2 method, as defined in the Introduction chapter of this
report, using caprolactam production capacity by state by year for 1990-2020 as a surrogate for caprolactam
production data. The GHGRP does not currently cover caprolactam production. See Appendix D, Table D-6 in the
"Caprolactam" Tab, for more details on the data used. State-level emissions for 1990-2020 were estimated as a
percentage of total national emissions by state and by year. Emissions of N2O from the production of caprolactam
were calculated using the Tier 1 method provided by the 2006 IPCC Guidelines.

For 1990-2020, the total caprolactam production capacity in each state was divided by the total caprolactam
capacity in the United States to calculate a percentage of caprolactam capacity in each state for each year. This
percentage was applied to the national N2O emissions from caprolactam production per year to calculate
disaggregated N2O emissions by state for each year.

The caprolactam production capacities per facility per state were compiled from ICIS for 2004 and 2006 (ICIS
2004, ICIS 2006). The capacity data for 2004 were applied to years 1990-2005, and the capacity data for 2006 were
applied to years 2006-2020. An additional caprolactam facility (Evergreen Recycling) was added for 2000 and 2001
(ICIS 2004, Textile World 2000) and for 2007-2015 (U.S. Department of Energy 2011, Shaw Industries Group, Inc.
2015). Using the caprolactam capacity per state to determine the state allocation percentage assumes that facility
utilization rates are roughly the same from state to state.

3.2.5.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of N20 from caprolactam production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -31%/+32% for N20.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based on caprolactam production capacity by state by year for 1990-2020. This
assumption was required because of a general lack of more granular state-level data.

For 1990-2020, this allocation method does not address utilization rates, which vary from facility to facility
and from year to year. While this approach implicitly accounts for the size of a facility in a state, it could
overestimate emissions in states where facilities used less of their capacity and underestimate emissions in states
where facilities used more of their capacity as a result of the lack of data on utilization rates.

3.2.5.4	Recalculations

No recalculations were applied for this current report.

3.2.5.5	Planned Improvements

Data gaps to calculate emissions from caprolactam production include caprolactam production by state for the
full time series. Under the current methodology, data gaps include caprolactam capacities per facility per state and
utilization rates per facility for the full time series.

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The EPA will review time-series consistency issues resulting from a lack of activity data (caprolactam
production) by state and the use of surrogate data (facility production data) that may not reflect reduced
production before facilities closed. More research is needed to refine the method to enhance accuracy and
consistency of estimated state GHG emissions and trends.

3.2.5.6 References

Independent Commodity Intelligence Services (ICIS). (2004). Chemical Profile—Caprolactam. January 5, 2004.
Available online at: https://www.icis.com/explore/resources/news/2005/12/Q2/547244/chemical-profile-
caprolactam/

ICIS. (2006). Chemical Profile - Caprolactam. October 15, 2006. Available online at:

https://www.icis.com/explore/resources/news/2006/10/18/2Q16832/chemical-profile-caprolactam/

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

Shaw Industries Group, Inc. (2015). "Shaw Carpet Recycling Facility Successfully Processes Nylon and Polyester."
July 13, 2015. Available online at: https://shawinc.com/Newsroom/Press-Releases/Shaw-Carpet-Recvcling-
Facilitv-Successfullv-Proces/

Textile World. (2000). "Evergreen Makes Nylon Live Forever." Textile World. October 1, 2000. Available online at:
https://www.textileworld.com/textile-world/textile-news/2000/10/evergreen-makes-nvlon-live-forever/

U.S. Department of Energy. (2011). Office of Energy Efficiency and Renewable Energy. "New Process Recovers and
Reuses Nylon from Waste Carpeting Saving Energy and Costs" Available online at:
https://www.energv.gov/eere/amo/nvlon-carpet-recvcling

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

3.2.6 Carbide Production and Consumption (NIR Section 4.10)

3.2.6.1	Background

Carbon dioxide (CO2) and methane (CH4) are emitted from the production of silicon carbide (SiC), a material
used for industrial abrasive, metallurgical, and other nonabrasive applications in the United States. Emissions from
fuels consumed for energy purposes during the production of silicon carbide are accounted for in the Energy
sector. C02and CH4 are also emitted during the production of calcium carbide, a chemical used to produce
acetylene. CO2 emissions from production of calcium carbide are implicitly accounted for in the storage factor
calculation for the nonenergy use of petroleum coke in the energy sector. Methane emissions from calcium
carbide production are not estimated because data are not available.

3.2.6.2	Methods/Approach

Total emissions for each state are the sum of emissions from SiC production and SiC consumption. A Hybrid
approach, defined in the Introduction chapter of this report, was used to calculate emissions for each state,
described below. To estimate state-level emissions from SiC production, national SiC production data were evenly
distributed among the two states identified as being home to SiC production facilities—Illinois and Kentucky. See
Appendix D, Table D-7 in the "Carbide Prod" Tab, for more details on the data used. State-level estimates from SiC
consumption were estimated using population statistics as a surrogate for consumption data and used to
disaggregate national SiC consumption emissions. See Appendix G, Table G-l in the "Population Data" Tab, for
more details on the data used.

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The national Inventory methodology was adapted to calculate state-level GHG emissions of SiC to ensure
consistency with national estimates. National estimates were used to estimate state-level emissions across states
because of limitations in the availability of state-specific data for the time series.

SiC Production

Emissions of CO2 and CH4 from the production of SiC were calculated using Approach 1, as defined in the
Introduction chapter of this report, which is consistent with the Tier 1 method provided by the 2006 IPCC
Guidelines, and the same annual USGS production data (U.S. Bureau of Mines 1990-1993, USGS 1994-2017, USGS
2022) used in the national Inventory (EPA 2022). For the period 1990 through 2001, reported USGS production
data included production from a facility in Canada that ceased operations in 2001. Using national-level SiC
production emissions data from Canada (UNFCCC 2021), U.S. SiC production for 1990 through 2001 was revised to
reflect only U.S. production. Because of the lack of information on production level by state, national SiC
production data were evenly distributed among the two states identified in the USGS Minerals Yearbook series as
being home to SiC production facilities. The state-level SiC production was multiplied by the national emissions
factors for CO2 and Cm to calculate GHG emissions by state.

SiC Consumption

Emissions of CO2 from the consumption of SiC were calculated using Approach 2, as defined in the
Introduction chapter of this report. SiC is used primarily for abrasive but also metallurgical and other nonabrasive
applications. Data on the consumption of SiC by state, however, are not available. To calculate state-level CO2
emissions from SiC consumption, national CO2 estimates from the national Inventory were distributed among the
50 states, the District of Columbia, and Puerto Rico using U.S. population statistics as a surrogate for SiC
consumption data (U.S. Census Bureau 2002, 2011, 2021; Instituto de Estadisticas de Puerto Rico 2021). The
fraction of the total U.S. population in each state, as well as the District of Columbia and Puerto Rico, was
calculated for each year by dividing the state population by the total U.S. population. To estimate CO2 emissions
for each year by state, national Inventory CO2 emissions from SiC consumption were multiplied by each state's
fraction of the total population for that year.

3.2.6.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from carbides production and
consumption was calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006).
As described further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the
national estimates in 2020 were -9%/+9% for CO2.

State-level estimates of production are expected to have a higher uncertainty because the national emissions
estimates were equally apportioned to each of the two states that produce SiC, which assumes that they produce
the same amount of SiC. There is also uncertainty due to the lack of information on production processes and
production levels at the two facilities.

State-level estimates of consumption also have a high uncertainty because national emissions estimates were
apportioned to all 50 states, the District of Columbia, and Puerto Rico using U.S. population statistics as a surrogate
for consumption. These assumptions were required because of a general lack of more granular state-level data.

3.2.6.4	Recalculations

Based on updates to the national Inventory for 1990-2001 to exclude production from one facility in Canada,
recalculations were performed for 1990-2001 to reflect only U.S. production. Recalculations were performed for
Illinois and Kentucky for the 1990-2001 time series to reflect this change in national-level emissions associated
with SiC production. As SiC consumption is based on U.S. production and net imports, the update to national

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production led to recalculations of consumption emissions from each state, the District of Columbia, and Puerto
Rico for the 1990-2001 time series as well.

Compared to the previous inventory, Illinois and Kentucky emissions decreased by about 20% to 50% per year
for each state. Illinois CO2 emissions decreased by about 10 to 100 kt per year and CFU emissions decreased by less
than 0.5 kt per year. Kentucky CO2 emissions decreased by about 10 to 50 kt per year and CFU emissions decreased
by less than 0.2 kt per year. Compared to the previous inventory for all other states, the District of Columbia, and
Puerto Rico, CO2 emissions decreased for each by 5% to 30% per year, a decrease of 0.1 to 2.5 kt CO2 per year.

Additional recalculations were performed for 2010 through 2019 as updated population data were available
from the U.S. Census Bureau. The updated population data had a negligible impact on the emissions estimated for
the 50 states, the District of Columbia, and Puerto Rico due to the low emissions estimated for each state or
territory for the sector.

3.2.6.5	Planned Improvements

Data gaps include the production of SiC by state and the consumption of SiC by state for the full time series.
Information to better simulate production at the two SiC facilities is needed and may include researching state
operating permits. The EPA will research whether GDP from metal production or a relevant NAICS code by state is
available that would be a better surrogate than population for estimating SiC consumption emissions.

3.2.6.6	References

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

UN Framework Convention on Climate Change. (2021). Greenhouse Gas Inventory Data—Flexible Queries Annex I
Parties. Accessed 13 September 2021. Available online at: https://di.unfccc.int/flex annexl

U.S. Bureau of Mines. (1990). Bureau of Mines Minerals Yearbook: Abrasive Materials. Table 15. Crude
Manufactured Abrasives Produced in the United States and Canada, by Kind. U.S. Bureau of Mines,
Washington, DC.

U.S. Bureau of Mines. (1991). Bureau of Mines Minerals Yearbook: Abrasive Materials. Table 15. Crude
Manufactured Abrasives Produced in the United States and Canada, by Kind. U.S. Bureau of Mines,
Washington, DC.

U.S. Bureau of Mines. (1992). Bureau of Mines Minerals Yearbook: Abrasive Materials. Table 12. End Uses of Crude
Silicon Carbide and Aluminum Oxide (Abrasive Grade) in the United States and Canada, as Reported by
Producers. U.S. Bureau of Mines, Washington, DC.

U.S. Bureau of Mines. (1993). Bureau of Mines Minerals Yearbook: Abrasive Materials. Table 12. End Uses of Crude
Silicon Carbide and Aluminum Oxide (Abrasive Grade) in the United States and Canada, as Reported by
Producers. U.S. Bureau of Mines, Washington, DC.

U.S. Census Bureau, Population Division. (2002). Table CO-EST2001-12-00—Time Series of Intercensal State
Population Estimates: April 1,1990 to April 1, 2000, Release Date: April 11, 2002.

U.S. Census Bureau, Population Division. (2011). Table 1. Intercensal Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01), Release Date:
September 2011.

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U.S. Census Bureau, Population Division. (2021). Table 1. Annual Estimates of the Resident Population for the

United States, Regions, States, and Puerto Rico: April 1, 2010 to July 1, 2020 (NST-EST2020), Release Date: July
2021.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (1994). Minerals Yearbook: Manufactured Abrasives. Table 2. End Uses of Crude Silicon
Carbide and Aluminum Oxide (Abrasive Grade) in the United States and Canada, as Reported by Producers.
U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1995). Bureau of Mines Minerals Yearbook: Manufactured Abrasives. Table 2. End Uses of
Crude Silicon Carbide and Aluminum Oxide (Abrasive Grade) in the United States and Canada, as Reported by
Producers. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1996). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1997). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1998). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (1999). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2000). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2001). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2002). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2003). Minerals Yearbook: Manufactured Abrasives. Table 2. Production of Crude Silicon
Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (2004). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2005). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2006). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2007). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2008). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

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U.S. Geological Survey. (2009). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2010). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2011). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2012). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2013). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2014). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2015). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2016). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2017). Minerals Yearbook: Manufactured Abrasives. Table 2. Estimated Production of
Crude Silicon Carbide and Fused Aluminum Oxide in the United States and Canada. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2020). Mineral Commodity Summaries: Manufactured Abrasives. U.S. Geological Survey,
Reston, VA.

U.S. Geological Survey. (2022). Mineral Commodity Summaries: Manufactured Abrasives. U.S. Geological Survey,
Reston, VA.

3.2.7 Titanium Dioxide Production (NIR Section 4.11)

3.2.7.1	Background

Titanium dioxide (Ti02> is manufactured using one of two processes: the chloride process and the sulfate
process. The chloride process uses petroleum coke and chlorine as raw materials and emits process-related CO2.
Emissions from fuels consumed for energy purposes during the production of TiOzare accounted for in the energy
sector. The sulfate process does not use petroleum coke or other forms of carbon as a raw material and does not
emit process CO2. Since 2004, all Ti02 produced in the United States has been produced using the chloride process.
Production of titanium dioxide in 2020 took place in Mississippi, Ohio, Tennessee, and Louisiana.

3.2.7.2	Methods/Approach

To develop state-level estimates of emissions from titanium dioxide production, national emissions from the
national Inventory were disaggregated with an Approach 2 method as defined in the Introduction chapter of this
report, using a combination of GHGRP emissions data for 2010-2020 as a surrogate for titanium dioxide

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production data and production capacity for 1990-2009 (see Table 3-7). See Appendix D, Tables D-8 and D-9 in the
"Ti02" Tab, for more details on the data used.

The national Inventory methodology was adapted to calculate state-level GHG emissions of TiC>2 to ensure
consistency with national estimates. National estimates were used to estimate state-level emissions across states
because of limitations in availability of state-specific activity data for the time series.

Emissions of CO2 from the production of TiCh were calculated using the Tier 1 method provided by the 2006
IPCC Guidelines and the same annual USGS production data (USGS Minerals Yearbook 1991-2015, USGS Mineral
Commodity Summaries 2014-2021) used in the national Inventory to calculate national emissions (EPA 2022).
National TiCh production data were allocated among the eight states with TiCh production facilities over the 1990-
2020 time series, based on GHGRP emissions data or production capacity, and multiplied by the national emissions
factor.

Table 3-7. Summary of Approaches to Disaggregate the National Inventory for Titanium Dioxide
Production Across Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP process emissions data from TiC>2 facilities were used to allocate

production by state, multiplied by the national emissions factor to get emissions
(IPCC 2006 Tier 1).

1990-2009

• USGS data on TiC>2 production capacity were used to allocate production by
state, multiplied by the national emissions factor to get emissions (IPCC 2006
Tier 1).

The methodology used for 2010-2020 was based on GHGRP CO2 emissions data reported by facilities summed
to state-level totals and used to estimate the fraction of total TiCh produced in each state. The GHGRP has no
reporting threshold for Ti02, so these emissions data are representative of the industry. The methodology used for
1990-2009 used USGS production capacity data for each facility to estimate the fraction of total TiCh produced in
each state.

The estimated state-level TiCh production was multiplied by the national emissions factor for CO2 to calculate
GHG emissions by state (IPCC 2006).

3.2.7.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from TiChwas calculated using the
2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described further in Chapter 4 and
Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020 were
-13%/+13% for CO2.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of GHGRP emissions data for 2010-2020 and
facility production capacity for 1990-2009. These assumptions were required because of a general lack of more
granular state-level data.

For 2010-2020, uncertainty is expected to be lower because of the use of GHGRP emissions data by state as a
surrogate for using TiC>2 production data by state to calculate emissions. For 2010-2020, national Inventory
emissions have exceeded GHGRP emissions from 25% to 35%, possibly indicating that emissions are overestimated
in some states.

For 1990-2009, this allocation method does not address utilization rates, which vary from facility to facility
and from year to year or differences in the carbon consumption rate for chloride and sulfate processes. While this

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approach implicitly accounts for the size of a facility in a state, it could overestimate emissions in states where
facilities used less of their capacity and underestimate emissions in states where facilities used more of their
capacity as a result of the lack of data on utilization rates and production data. This method also does not account
for different production processes. The sulfate process does not use petroleum coke or other forms of carbon as a
raw material and does not emit CO2. Although the chloride process has been the only one used in U.S. facilities
since 2004, this allocation approach could overestimate emissions in states where facilities used the sulfate
process earlier in the time series.

3.2.7.4	Recalculations

Based on updated TiCh facility-level emissions obtained from the GHGRP for 2019, recalculations were
performed for 2019. One facility in Tennessee resubmitted its GHGRP report for 2019, resulting in updates to the
percentage of emissions for each state. Compared to the previous inventory, CO2 from TiCh production increased
by 1.3% (3 kt CO2) for Louisiana, 1.2% (8 kt CO2) for Mississippi, and 1.3% (4 kt CO2) for Ohio and decreased by 5.2%
(14 kt CO2) for Tennessee.

3.2.7.5	Planned Improvements

Data gaps include state-level data on Ti02 production for the full time series 1990-2020. GHGRP emissions
data are available for the period 2010-2020 and were used for state inventory calculations, and these data will be
examined for possible use to improve data for the 1990-2009 period.

To address utilization rates that vary from facility to facility and from year to year or differences in the carbon
consumption rate for chloride and sulfate processes, the EPA will research how to account for varying utilization
rates and carbon consumption rate differences for sulfate (nonemissive) and chloride (emissive) processes.

The EPA will review potential time-series consistency issues due to the two methodologies for 1990-2009 and
for 2010-2020. Surrogate data (production capacity) were used in place of activity data for the 1990-2009 portion
of the time series, and more research on data gaps (e.g., apply overlap technique) is needed to refine the method
to enhance accuracy and consistency of estimated state GHG emissions and trends.

3.2.7.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas
Inventories. The National Greenhouse Gas Inventories Programme, Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (1991 through 2015). Minerals Yearbook: Titanium. U.S. Geological Survey, Reston, VA.

U.S. Geological Survey. (January 2021). Mineral Commodity Summaries: Titanium and Titanium Dioxide. U.S.
Geological Survey, Reston, VA. Available online at: https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-
titanium-minerals.pdf

3.2.8 Soda Ash Production (NIR Section 4.12)

3.2.8.1 Background

CO2 is generated as a by-product of calcining trona ore to produce soda ash and is eventually emitted into the
atmosphere. In addition, CO2 may also be released when soda ash is consumed. Emissions from soda ash
consumption in chemical production processes are reported under other process uses of carbonates, and
emissions from fuels consumed for energy purposes during the production and consumption of soda ash are
accounted for in the energy sector.

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3.2.8.2	Methods/Approach

All of the national Soda Ash Production emissions can be attributed to Wyoming for the entirety of the 1990-
2020 time series. See Appendix D, Table D-10 in the "Soda Ash" Tab, for more details on the data used.

The national Inventory methodology was used to calculate state-level GHG emissions to ensure consistency
with national estimates, consistent with an Approach 1 method as defined in the Introduction chapter of this
report. As discussed in the national Inventory (EPA 2022), only two states produce natural soda ash in the United
States: Wyoming and California. Only CO2 emissions from Wyoming soda ash production facilities, which produced
soda ash from trona ore, are included in the national estimate for the 1990-2020 time series because no CO2 is
emitted from the processes used in the California facility, which produced soda ash from sodium-carbonate-rich
brines. Additionally, one facility in Colorado produced soda ash from nahcolite between 2000 and 2004; however,
similar to the California facility, the Colorado facility's production process did not generate CO2 emissions. As a
result, all of the national CO2 emissions can be attributed to Wyoming for the entirety of the 1990-2020 time
series. Emissions calculations are consistent with the Tier 1 method provided by the 2006 IPCC Guidelines.

3.2.8.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from Soda Ash Production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described further in Chapter 4
and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020 were
-9%/+8% for CO2.

State-level estimates have a consistent level of uncertainty as the national Inventory over the full time series
because the same methodology was used and emissive soda ash production takes place in one state.

3.2.8.4	Recalculations

No recalculations were applied for this current report consistent with Section 4.12 (page 4-61) of the national
Inventory.

3.2.8.5	Planned Improvements

There are no planned improvements for the soda ash production category. The EPA will monitor the U.S. soda
ash production sector to ensure that any new production facilities using emissive processes are accounted for in
the state-level disaggregation.

3.2.8.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
Office of Air and Radiation, Office of Atmospheric Programs, U.S. Environmental Protection Agency,
Washington, DC. Available online at: https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-
emissions-and-sinks

3.2.9 Petrochemical Production (NIR Section 4.13)

3.2.9.1 Background

The production of some petrochemicals results in the release of CO2 and Cm emissions. Petrochemicals are
chemicals isolated or derived from petroleum or natural gas. C02emissions from the production of acrylonitrile,
carbon black, ethylene, ethylene dichloride, ethylene oxide, and methanol, and Cm emissions from the production
of methanol and acrylonitrile are presented here. The petrochemical industry uses primary fossil fuels (i.e., natural

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gas, coal, petroleum) for nonfuel purposes in the production of carbon black and other petrochemicals. Emissions
from fuels and feedstocks transferred out of the system for use in energy purposes (e.g., fuel combustion for
indirect or direct process heat or steam production) are currently accounted for in the Energy sector.

In 2020, petrochemicals were produced at 72 facilities in 10 states (EPA 2022a). Over 95% of total production
capacity is in Texas and Louisiana.

3.2.9.2 Methods/Approach

To develop state-level estimates of emissions from petrochemical production, the EPA disaggregated national
emissions from the national Inventory to all applicable U.S. states and territories using production capacities by
petrochemical process by state as a surrogate for emissions activity data. This methodology is consistent with
Approach 2, as defined in the Introduction chapter of this report. See Appendix D, Table D-ll through Table D-16
in the "Petrochemical" Tab, for more details on the data used.

The national Inventory methodology was adapted to calculate state-level GHG emissions from petrochemical
production to ensure consistency with national estimates. Consistency with the national estimates and IPCC
Guidelines requires reporting emissions by petrochemical type (i.e., acrylonitrile, carbon black, ethylene, ethylene
dichloride, ethylene oxide, and methanol). State-level emissions were estimated as a percentage of total national
emissions by state and by year.

The national Inventory derived national estimates for carbon black, ethylene, ethylene dichloride, and
ethylene oxide based on facility-level GHGRP emissions for 2010-2020. The GHGRP has no reporting threshold for
petrochemical production, so these emissions data are representative of the industry. For 1990-2009, estimates
were based on emissions factors derived from GHGRP data and production data from the American Chemistry
Council (ACC) and the International Carbon Black Association (EPA 2022a). For all years, the national emissions
estimates for acrylonitrile and methanol were based on emissions factors and production data from the ACC
because the national GHGRP data are considered CBI.

The method used for the national Inventory is not possible for state-level petrochemical emissions because
additional GHGRP CBI concerns with all the petrochemical types become an issue when considering data by state.
For example, all ethylene oxide production facilities are in Louisiana and Texas. For reporting year (RY) 2019 and RY
2020, it appears that GHGRP emissions data could pass the CBI aggregation criteria in both states; however, for RY
2010-RY 2018, there were only three companies in Louisiana, so data cannot be aggregated in either state for the
same reasons noted below for ethylene, ethylene dichloride, and carbon black.

GHGRP emissions data for ethylene, ethylene dichloride, and carbon black could also pass CBI aggregation
criteria at the state level in Louisiana and Texas (at least for RY 2019 and RY 2020); however, because there are
fewer than four companies making each of these petrochemicals in other states (typically only one facility per
state), it is not possible to aggregate the emissions by petrochemical type in Louisiana and Texas without revealing
the facility-specific emissions at the facilities in other states.

Aggregating total emissions from all types of petrochemical processes rather than by type of petrochemical
was also not possible because of CBI concerns, particularly the concern that aggregated data for one state could
reveal, or allow for back calculation of, CBI information about individual facilities in other states. For example,
some states have only one facility producing one type of petrochemical, and reporting GHGRP emissions by state
could disclose facility-specific data considered CBI for those states.

Aggregated GHGRP production data (the activity data used to calculate emissions when GHGRP emissions are
not available or do not meet CBI aggregation criteria) also have the same CBI concerns as GHGRP emissions data.

As an alternative, production capacities were used as a surrogate for actual production and emissions data. In
effect, this approach assumes that all facilities producing a particular type of petrochemical have the same capacity

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utilization and that emissions are proportional to production. As a result, this approach may result in
overestimating emissions for some states and underestimating emissions for other states.

To calculate emissions, the capacities per year per type of petrochemical per state were summed. The fraction
of the total capacity attributable to each facility in each year per state was determined. This percentage was
multiplied by the annual national Inventory emissions per petrochemical (i.e., the aggregated GHGRP emissions for
ethylene, ethylene dichloride, ethylene oxide, and carbon black in RY 2010-RY 2020, and the calculated
nationwide emissions for other years and for methanol and acrylonitrile in all years). For years where production
capacity was not known, data were extrapolated and interpolated to fill in data gaps. Several facilities have opened
and closed over the last 30 years; the precise years of facilities' operations were not always available because
capacities for only a handful of years were known. Details on how capacities were determined for each
petrochemical are described below.

Acrylonitrile

Facility production capacity and location data were available for 1992,1997, and 2005 from the SRI Directory
of Chemical Producers (SRI 1992,1997, 2005) and for 2008, 2009, 2011, 2013, and 2017 from the ICIS (ICIS 2008,
2009a, 2011, 2013, 2017). The 1997 SRI data consisted of only the facility locations and the percentages of the
nationwide capacity held by the two companies with the largest percentage of the total nationwide capacity.

For 1990 and 199^ production capacity per state was assumed to be equal to the 1992 values. The 1997
capacities were estimated based on adjusting the 1992 and 2005 capacities to meet the corporate percentages
cited in SRI's 1997 Directory. Specifically, the capacity for one facility was assumed to be the same as in 2005, the
availability of new production capacity at a second facility known to have expanded in 1996 was assumed to be
evenly split between 1997 and 1998, and capacities for the other four facilities in 1997 were assumed to be the
same as in 1992. For other interim years, a linear extrapolation between the different years of known data were
assumed. Some further adjustments were made when plant openings or closings were known. For example, one
facility in Texas closed in 2005, and another closed in 2009.

Carbon Black

ICIS capacity data were available for 1999, 2002, and 2005. For 1999, only a partial dataset was available;
these data were not used because some of the data appeared to be inconsistent with data for other years (ICIS
1999, 2002a, 2005). SRI data were available for 1992,1997, and 2005 (SRI 1992,1997, 2005). For 2005, this
analysis used ICIS data.

Capacities in 1990 and 1991 were assumed to be equal to the 1992 value. Data were extrapolated from 1992-
1997 and from 1997-2002. No plant closures were assumed during those time periods.

Capacities for years between the years for which SRI or ICIS data were available, or until the year when a plant
closed, were estimated using linear interpolation. The plant in Arkansas was assumed to operate in 2002 but not in
2005, so capacity was extrapolated from 2002 levels to zero in 2005. It was assumed another plant in Texas closed
in 2003, so the 2005 value was set to zero. It was assumed one plant in West Virginia closed in 2008 and the other
closed in 2009. It was assumed another plant in Texas closed in 2010. Capacities for 2011-2020 were assumed to
be equal to the capacities in 2010.

Ethylene

SRI data on production capacities were available for 1992 and 2005. The Oil & Gas Journal publishes capacities
of ethylene production facilities, and data were available for 2007, 2013, and 2015 (O&GJ 2007, 2013, 2015). The
capacity for a new unit that started up in 2020 was also available from the Oil & Gas Journal (O&GJ 2020).

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Capacities in 1990 and 1991 were assumed to be equal to the 1992 value. Because site-specific capacities for
the intermediate years were not known, a straight-line interpolation of capacities was assumed between 1992 and
2005. This resulted in the total capacity being less than the total annual production for 3 years in the late 1990s
because some of the more significant expansions must have occurred in the mid-1990s. Capacities for 2016-2020
were assumed to be the same as in 2015, except for one new plant start-up in 2017, one new plant start-up in
2019, one new plant start-up in 2020, one restart of an idled plant in 2019, one expansion in 2017, two expansions
in 2018, and one expansion in 2019 (Chevon Phillips Chemical 2018, ExxonMobil 2018, Indorama Ventures 2015,
LACC 2016, LyondellBasell 2017, OxyChem 2017, BIC Magazine 2019, O&GJ 2020). For all other interim years, a
linear extrapolation between the different years of known data were assumed.

Ethylene Dichloride

The SRI Directory of Chemical Producers production capacity data for ethylene dichloride were available for
1992,1997, and 2005 (SRI 1992,1997, 2005). The 1997 SRI data consisted of only the facility locations and the
percentages of the nationwide capacity held by the three companies with the largest percentage of the total
nationwide capacity.

ICIS data on production capacity are available for the years 2003, 2009 and 2018, although it is not clear
whether the data are complete. The 2003 report has capacities listed for 16 facilities, with two being idle that year.
The 2009 report lists capacities for 14 facilities, the 2018 report lists only 10 facilities, and the total capacity
reporting for 2018 is less than the assumed production in that year.

Capacities in 1990 and 1991 were assumed to be equal to the 1992 value. Capacities in 1993-1997 were
assumed to be the same as in 1992, with the exception of the 1997 capacity for one facility that was assumed to be
the same as the capacity in the 2003 ICIS data; with this assumption, the percentages of total nationwide capacity
were close to the percentages provided in the 1997 SRI Directory. Linear interpolation was used to estimate
capacities for 1998-2002, with two exceptions: the capacity for the facility that expanded in 1997 was assumed to
be the same over all of the years, and 0 capacity was assumed for two plants in years where ICIS indicated the
plants were idle.

The capacities in 2005 were assumed to be the same as the capacities reported by ICIS for 2003. While the
2005 SRI list had similar values for most facilities, one facility seemed low compared to ICIS values for 2003 and
2009. The ICIS capacities in 2009 matched the capacities in 2005; thus, all capacities were assumed to be
unchanged from 2003-2009. The capacities in 2010-2020 also were assumed to be the same as in 2009, except for
one facility that closed in 2011 and one new facility that started one new unit in 2010 and a second new unit in
2011.

The capacity utilization (dividing total production from the national Inventory by assumed capacity) was
calculated over the time period as a check on the capacity assumptions used. If production exceeded assumed
capacity, it would indicate the capacity assumptions were too low, while an extremely low-capacity utilization
could indicate that capacity assumptions were too high. The average total capacity utilization over time was 70%,
with a high of almost 100% in 1998 and a low of 47% in 2011. While these indicate there may be some over- or
underestimation of capacity in a few years, they were still within the range of possible values and no further
adjustments to capacities were made.

Ethylene Oxide

SRI data were available for 1992,1997, and 2005 (SRI 1992, 1997, 2005). ICIS data on plant capacities were
available for 2004, 2010, 2012, and 2018 (ICIS 2004, 2010, 2012, 2018b). Capacities in 1990 and 1991 were
assumed to be equal to the 1992 value. The 2004 ICIS capacities were very similar to the 2005 SRI capacities; the
2004 ICIS capacities were used in this analysis to maintain consistency with capacities for subsequent years that
were also based on ICIS data.

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There were several plant openings and closing and capacity changes over the time period. Plant openings and
closings were based on data provided in ICIS writeups, press releases, and other documentation on company
websites (as opposed to extrapolating over time). For example, capacities for new ethylene oxide units started up
by Sasol and MEGIobal in 2019 were reported directly or could be estimated from other data reported on company
websites (Sasol 2019, Sasol 2020, EQUATE 2019).

Capacity utilization was calculated over the time period as a check on the capacity assumptions used. Assumed
total capacity was generally greater than assumed total production across the time series, with the exception of
1995 and 2004 where production was 102% of capacity. Average capacity utilization over time was 85%. Although
this may indicate some underestimation of capacity in a few years (especially 1995 and 2004), no further
adjustments to capacities were made.

Methanol

SRI data on methanol production capacity were available for 1992,1997, and 2005 (SRI 1992 1997 2005). ICIS
data were available for 2002, 2014, 2016, and 2018 (ICIS 2002b, 2014, 2016, 2018c).

Capacities in 1990 and 1991 were assumed to be equal to the 1992 value. Data on plant closures between
1998 and 2005 were from OCI (OCI Partners 2016; see the Appendix). Data on start-up dates for expansions and
new plants between 2012 and 2019 were obtained from documentation on company websites (Celanese 2019, OCI
2018, OCI Partners 2016, Methanex 2017). These data were used to estimate capacities for years between the
years for which ICIS data were available and to prorate capacities based on the approximate percentage of the
year that they operated after start-up. Capacity for one new unit started up in 2020 was estimated based on data
in the permit to install and operate (Ohio EPA 2017), and it was assumed to be in operation for 33% of the year
based on information provided in the Toxics Release Inventory Form R (EPA 2022b).

3.2.9.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and CFU from Petrochemical
Production was calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As
described further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022a), levels of uncertainty in the
national estimates in 2020 were -5%/+6% for CO2 and -57%/+47% for CH4.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based on facility production capacity. These assumptions were required because
the CBI concerns related to GHGRP data and a general lack of other more granular state-level data.

This allocation method does not address actual utilization rates, which vary from facility to facility and from
year to year. While this approach implicitly accounts for the size of a facility in a state, it could overestimate
emissions in states where facilities used less of their capacity and underestimate emissions in states where
facilities used more of their capacity.

3.2.9.4	Recalculations

The CO2 emissions in the national Inventory were revised for ethylene, ethylene dichloride, and ethylene oxide
production in 2014, ethylene production in 2016, and carbon black production in 2017 due to updates in the
GHGRP data (EPA 2022a). Updated national acrylonitrile production data were reduced for 2019 (ACC 2021); this
reduced the national Inventory emissions of CO2 and CFU from acrylonitrile production because the emissions are
calculated using an emissions factor that is related to production. As a result, the distribution of estimated
emissions at the state level also changed for 2014, 2016, 2017, and 2019.

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3.2.9.5	Planned Improvements

Continued research is needed for more information on timing of facility expansions, openings, and temporary
or permanent closures (e.g., permits, permit applications, trade industry data) and on facility production capacities
to address data gaps (e.g., earlier versions of SRI International Directory of Chemical Producers data, annual or
biannual Oil & Gas Journal surveys of ethylene steam cracker capacities).

For 2010-2020, the state-level inventory totals based on production capacity can be compared with the
GHGRP data on total emissions by state to assess how well the estimates represent the industry. Although
petrochemical production emissions by state and petrochemical type are CBI, total petrochemical production
emissions by state across all petrochemical types are not CBI under the GHGRP.

3.2.9.6	References

ACC. (2021). Business of Chemistry (Annual Data). American Chemistry Council, Arlington, VA.

BIC Magazine. (2019). Sasol achieves beneficial operation of Louisiana ethane cracker. November 28, 2019.
Available online at: https://www.bicmagazine.com/industrv/refining-petchem/sasol-achieves-beneficial-
operation-of-louisiana-ethane-cracker/

Celanese. (2019). Celanese Expands Methanol Production at Clear Lake Facility. April 17, 2019. Available online at:
https://www.celanese.com/news-media/2019/April/celanese-expands-methanol-production-at-clear-lake-
facility.aspx

Chevron Phillips Chemical. (2018). Chevron Phillips Chemical Successfully Starts New Ethane Cracker in Baytown,
Texas. March 12, 2018. Available online at: https://www.cpchem.com/media-events/news/news-
release/chevron-phillips-chemical-successfullv-starts-new-ethane-cracker

EQUATE. (2019). EQUATE Group Announces Official Start-Up of MEGIobal Oyster Creek, TX Site. October 14, 2019.
Available online at: https://www.meglobal.biz/ovster-creek-start-up/

ExxonMobil (2018). ExxonMobil Starts up new Ethane Cracker in Baytown, Texas. July 26, 2018. Available online at:
https://corporate.exxonmobil.com/News/Newsroom/News-releases/2018/0726 ExxonMobil-starts-up-new-
ethane-cracker-in-Baytown-Texas

Independent Commodity Intelligence Services. (ICIS) (1999). Carbon black. August 29,1999. Available online at:
https://www.icis.com/explore/resources/news/1999/08/30/93545/carbon-black/

ICIS. (2002). Chemical Profile—Carbon Black. June 23, 2002. Available online at:

https://www.icis.com/explore/resources/news/2005/12/02/175824/chemical-profile-carbon-black/

ICIS. (2002). Chemical Profile—Methanol. December 16, 2002. Available online at:

https://www.icis.com/explore/resources/news/2005/12/02/186772/chemical-profile-methanol/

ICIS. (2003). Chemical Profile Ethylene Dichloride. November 10, 2010. Available online at:

https://www.icis.com/explore/resources/news/2005/12/02/532639/chemical-profile-ethvlene-dichloride/

ICIS. (2004). Chemical Profile Ethylene Oxide (EO). Author: Mark Kirschner. October 10, 2004. Available online at:
https//www.icis.com/explore/resources/news/2005/12/08/618912/chemical-profile-ethvlene-oxide-eo-/

ICIS. (2005). Chemical profile: Carbon Black. Author: Mark Kirschner. June 19, 2005. Available online at:
https://www.icis.com/explore/resources/news/2005/06/17/686446/chemical-profile-carbon-black/

ICIS. (2008). Chemical profile: acrylonitrile. Author: Elaine Burridge. August 17, 2008. Available online at:
https://www.icis.com/explore/resources/news/2008/08/18/9149113/chemical-profile-acrvlonitrile/

ICIS. (2009a). Chemical profile: acrylonitrile. January 27, 2009. Available online at:

https://www.icis.com/explore/resources/news/2009/01/27/9188Q94/chemical-profile-acrvlonitrile/

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ICIS. (2009b). US chemical profile: Ethylene dichloride. Author: Feliza Mirasol. September 13, 2009. Available

online at: https://www.icis.com/explore/resources/news/2009/Q9/14/9246931/us-chemical-profile-ethvlene-
dichloride/

ICIS. (2010). US chemical profile: ethylene oxide. Author: Feliza Mirasol. August 1, 2010. Available online at:
https://www.icis.com/explore/resources/news/2010/08/02/9380662/us-chemical-profile-ethvlene-oxide/

ICIS. (2011). U.S. chemical profile: acrylonitrile. Author: Anna Jagger. September 4, 2011. Available online at:
https://www.icis.com/explore/resources/news/2011/09/05/9489888/us-chemical-profile-acrvlonitrile/

ICIS. (2012). US Chemical Profile: Ethylene oxide. Author: Feliza Mirasol. March 12, 2012. Available online at:
https://www.icis.com/explore/resources/news/2012/03/12/9539954/us-chemical-profile-ethvlene-oxide/

ICIS. (2013). Chemical Profile: US acrylonitrile. Author: Mark Yost. May 24, 2013. Available online at:

https://www.icis.com/explore/resources/news/2013/05/26/967200Q/chemical-profile-us-acrvlonitrile/

ICIS. (2014). Chemical profile: US methanol. Author: Lane Kelley. May 2, 2014. Available online at:

https://www.icis.com/explore/resources/news/2014/05/02/9777442/chemical-profile-us-methanol/

ICIS. (2016). Chemical profile: US methanol. Author: Bobby Clark. April 7, 2016. Available online at:

https://www.icis.com/explore/resources/news/2016/04/07/9986Q81/chemical-profile-us-methanol

ICIS. (2017). Chemical Profile: US acrylonitrile. Author: Christie Moffat. January 12, 2017. Available online at:
https://www.icis.com/explore/resources/news/2017/01/12/10Q69751/chemical-profile-us-acrvlonitrile/

ICIS. (2018a). Chemical profile: US ethylene dichloride. Author: Bill Bowen. August 10, 2018. Available online at:
https://www.icis.com/explore/resources/news/2018/08/Q9/10249213/chemical-profile-us-ethvlene-
dichloride/?redirect=english

ICIS. (2018b). Chemical profile: US ethylene oxide. Author: Tarun Raizada. April 13, 2018. Available online at:
https://www.icis.com/explore/resources/news/2018/04/12/10211482/chemical-profile-us-ethvlene-oxide/

ICIS. (2018c). Chemical profile: US methanol. Author: Lane Kelley. September 13, 2018. Available online at:
https://www.icis.com/explore/resources/news/2018/09/13/10259297/chemical-profile-us-methanol/

Indorama Ventures. (2015). Olefins. Acquisition in 2015. Available online at:

https://www.indoramaventures.com/en/worldwide/1214/indorama-ventures-olefins

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

LACC. (2016). Axiall and Lotte Chemical Hold LACC Ethane Cracker Groundbreaking Ceremony. June 14, 2016.
Available online at: https://www.westlake.com/axiall-and-lotte-chemical-hold-lacc-ethane-cracker-
groundbreaking-ceremony

LyondellBasell. (2017). LyondellBasell Corpus Christi Complex Expansion Complete. January 19, 2017. Available
online at: https://www.lvondellbasell.com/en/news-events/corporate-financial-news/lvondellbasell-corpus-
christi-complex-expansion-complete/

Methanex. (2017). Methanex Corporate History 1968-2017. Available online at:
https://www.methanex.com/sites/default/files/news/media-
resources/MX%20Corporate%20Historv 2017.pdf

OCI. (2018). Press Release. Natgasoline LLC Begins Production at Largest Methanol Facility in the United States.
June 25, 2018. Available online at: https://www.oci.nl/media/1335/natgasoline-begins-methanol-production-
final.pdf

OCI Partners LP. (2016). Corporate Presentation, November 2016. Available online at:
http://ocipartnerslp.investorroom.com/presentations

Oil & Gas Journal. (O&GJ) (2007). International Survey of Ethylene From Steam Crackers. July 16, 2007.

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O&GJ. (2013). International Survey of Ethylene from Steam Crackers.

O&GJ. (2015). International Survey of Ethylene from Steam Crackers July 6, 2015.

O&GJ. (2020). Shintech Commissions Louisiana Ethylene Plant. February 14, 2020. Available online at:

https://www.ogi.com/refining-processing/petrochemicals/article/14167793/shintech-commissions-louisiana-
ethylene-plant

Ohio EPA. (2017). Final Permit-to-lnstall and Operate. Ohio Environmental Protection Agency. Permit number
P0122449. August 23, 2017. Available online at:
http://wwwapp.epa.ohio.gov/dapc/permits issued/1595429.pdf

OxyChem. (2017). OxyChem and Mexichem Announce Startup of their Joint Venture Ethylene Cracker in Ingleside,
Texas. February 27, 2017. Available online at: https://www.oxv.com/News/Print/5865.PDF

Sasol. (2019). Ethylene Oxide/Ethylene Glycol (EO/EG) Unit. Fast Facts. 2019. Available online at:
https://3lkevlwlrsfaewp8nifu43u6-wpengine.netdna-ssl.com/wp-
content/uploads/2019/07/fact sheet eoeg.pdf

Sasol. (2020). Project Update. June 1, 2020. Available online at:
https://www.sasolnorthamerica.com/proiectupdate/

SRI Consulting. (2005). A Division of Access Intelligence, LLC (SRI). 2005 Directory of Chemical Producers. United
States. Menlo Park, CA. 2005.

SRI. (1992). 1992 Directory of Chemical Producers. United States of America. Menlo Park. California. 1992.

SRI. (1997). 1997 Directory of Chemical Producers. United States of America. Menlo Park. California. 1997.

U.S. Environmental Protection Agency. (2022a). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Environmental Protection Agency. (2022b). Toxics Release Inventory Form R data. Accessed May 16, 2022.
Available online at:

https://enviro.epa.gov/enviro/tri formr v2.fac list?rptyear=2020&facopt=fac name&fvalue=Alpont&fac sea
rch=fac beginning&postal code=&city name=Oregon&county name=&state code=OH&industry type=&bia
code=&tribe Name=&tribe search=fac beginning

U.S. Environmental Protection Agency Greenhouse Gas Reporting Program (GHGRP). (2021). Dataset as of August
7. 2021. Available online at: https://ghgdata.epa.gov/ghgp/

3.2.10 HCFC-22 Production (NIR Section 4.14)

3.2.10.1	Background

Trifluoromethane (HFC-23 or CHF3) is generated as a by-product during the manufacture of
chlorodifluoromethane (HCFC-22), which is used as a feedstock for several fluoropolymers. Before 2010, HCFC-22
was widely used as a refrigerant, but its production and import for this application in the United States were
phased out between 2010 and 2020 under Title VI of the Clean Air Act, which controls production and
consumption of HCFCs and other compounds that deplete stratospheric ozone. Production of HCFC-22 for use as a
feedstock is allowed to continue indefinitely.

3.2.10.2	Methods/Approach

As discussed on page 4-71 of the Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020, methods
comparable to the Tier 3 methods in the 2006 IPCC Guidelines (IPCC 2006) were used to estimate HFC-23
emissions for five of the eight HCFC-22 plants that have operated in the United States since 1990. For the other

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three plants, the last of which closed in 1993, methods comparable to the Tier 1 method in the 2006 IPCC
Guidelines were used. However, as discussed further below, the EPA does not have access to the individual plant
estimates for 1990-2009; for those years, the EPA has access only to national totals aggregated across the plants.

To develop state-level estimates of HFC-23 emissions from HCFC-22 Production, the EPA disaggregated national
emissions from the national Inventory using a combination of facility-level reporting to the GHGRP from 2010-
2020, reports verifying emissions by facility for earlier years, and production capacity data, as shown in Table 3-8.
The sum of emissions by state is consistent with national process emissions as reported in the national Inventory
over the time series.

Table 3-8. Summary of Approaches to Disaggregate the National Inventory for HCFC-22 Production Across
Time Series

Time Series Range

Summary of Method

1990-2009

• Facility-specific information on emissions control efforts and production

capacities, in combination with facility-specific GHGRP data for 2010, was used
to estimate emissions by state (Approach 2).

2010-2020

• Facility-specific GHGRP data on HFC-23 emissions were compiled by state
(Approach 1).

For each state, HFC-23 emissions from 2010-2020 were drawn from facility-level reporting to the GHGRP. The
same data were used for the national Inventory.

Facility-level reports of HFC-23 emissions are not available for years before 2010, which was the first year of
GHGRP reporting. As described in the national Inventory, national totals for 1990-2009 were based on totals
provided to EPA by the Alliance for Responsible Atmospheric Policy, which aggregated the HFC-23 emissions and
HCFC-22 production reported to the Alliance by each HCFC-22 production facility and HFC-23 destruction facility.
(A list of the nine facilities that have operated in the United States since 1990, their locations, and dates of opening
or closure is shown in Table 3-9 below.) These totals, as well as the individual facility reports, were reviewed and
corrected, as necessary, by an EPA contractor in 1997 and 2008. The totals and qualitative information on each
plant's emissions estimation methods, trends, and control measures were summarized in two reports. The EPA
used the second of these reports, Verification of Emission Estimates of HFC-23 from the Production of HCFC-22:
Emissions from 1990 through 2006 (hereinafter referred to as the 2008 Verification Report) (RTI 2008), to estimate
facility-level emissions and develop state-level estimates for 1990-2009. The EPA also used GHGRP data from
2010-2020 and the estimated 2003 HCFC-22 production capacity of each facility from the 2004 edition of the
Chemical and Economics Handbook (CEH) Research Report: Fluorocarbons (SRI 2004).

In combination with two key trends seen at the national level, these resources provide some insight into the
magnitudes and trends of emissions of the various facilities. The two key national trends are a steady decrease in
the HFC-23/HCFC-22 emissions factor from 1990-2010 and a slow increase in HCFC-22 production from 1990-
2000, followed by fluctuating production through 2007, followed by a decline in later years. The 2008 Verification
Report indicates that the downward trend in the emissions factor was at least partially driven by (1) the closure
during the early 1990s of four HCFC-22 production facilities whose emissions were uncontrolled and whose
production was replaced by a facility that opened in 1993 in Alabama with tight emissions controls and (2) actions
taken by a production facility in Kentucky to significantly reduce its emissions rate beginning in 2000. While HCFC-
22 production and production capacity data were not available for all the plants operating before 2003, the
generally upward trend in national production seen between 1990 and 2003 indicates that the closure of the four
plants in the early 1990s, in combination with the opening of the Alabama plant in 1993, likely did not result in a
significant net loss of production capacity in the United States as a whole during that period. Thus, the EPA
estimated production at the four plants by equating their joint production capacity to that of the Alabama plant,
which was available from the CEH report.

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To allocate national emissions to each facility, the EPA first back-cast the relatively small emissions reported
by the HCFC-22 production facility in Alabama and one HFC-23 destruction facility in West Virginia. As noted
above, the Alabama HCFC-22 production facility was known to have tightly controlled HFC-23 emissions since it
began operating in 1993; thus, emissions from 1996-2009 were assumed to equal the average of the emissions
reported by this facility from 2010-2014, a period during which emissions were relatively flat before they began to
decline in 2015. (Emissions from 1993-1996 were assumed to rise gradually as the plant replaced HCFC-22
production from closing plants.) The HFC-23 destruction facility in West Virginia is understood to have begun
destroying HFC-23 in 2000 when an HCFC-22 production facility owned by the same company began capturing by-
product HFC-23 and shipping some of it to the West Virginia facility for destruction. Emissions from 2000-2009
were equated to the average emissions reported by the West Virginia facility under subpart O of the GHGRP from
2010-2013 (about 3 kg per year), after which emissions dropped.

To estimate the 2003-2009 emissions from the other two HCFC-22 production facilities that operated during
that period (in Kentucky and Louisiana), the emissions estimated for the Alabama and West Virginia facilities were
subtracted from the national total, and the remaining emissions were then allocated to the Kentucky and Louisiana
facilities based on each facility's estimated production and estimated emissions rate. The production of each
facility throughout the time series was estimated based on the 2003 capacity reported in the CEH report. The 1999
emissions rates of both facilities were assumed to be equal to the national emissions rate in that year after
subtracting out the estimated emissions and production of the (controlled) Alabama facility; the resulting
emissions rate was 0.018 kg HFC-23/kg HCFC-22. The emissions rate of the Louisiana facility was assumed to have
remained constant at this level based on the characterization of that facility's emissions control efforts in the 2008
Verification Report. The emissions rate for the Kentucky facility was assumed to have declined linearly to 0.005 kg
HFC-23/kg HCFC-22 as the facility implemented the emissions reduction efforts documented in the 2008
Verification Report.23 To estimate the share of national emissions attributable to each facility, each facility's
estimated production was multiplied by its estimated emissions rate, resulting in a provisional emissions estimate
for each facility for each year. Each facility's provisional emissions estimate was then divided by the sum of the
provisional emissions estimates for both facilities. The resulting fraction was multiplied by the national emissions
(less the emissions of the Alabama and West Virginia facilities) to obtain the final estimate of emissions for each
facility.

To estimate facility-level emissions from 1990-2002, it was necessary to account for the emissions of the five
HCFC-22 production facilities that ceased production before 2003. These facilities, which operated through 1991,
1992,1993,1995, and 2002, respectively, did not have production capacities listed in the CEH report and did not
control their emissions, based on the 2008 Verification Report. The production capacity of the facility that
operated through 2002, in Kansas, was estimated as the difference between the total U.S. HCFC-22 production in
2000 and the sum of the CEH-estimated production capacities for the other three plants in operation during that
year. (U.S. HCFC-22 production reached a peak in 2000.) This plant was assumed to have linearly decreased
production to zero between 2000 and 2003. Its emissions factor was assumed to equal the value calculated for
uncontrolled plants in 1999, 0.018 kg HFC-23/kg HCFC-22. U.S. emissions from 2000-2002 were then allocated to
this plant and to the Kentucky and Louisiana plants as described above.

As noted earlier, the production capacities of the four facilities that closed in the early 1990s were each
assumed to equal one-fourth of the production capacity of the Alabama facility that opened in 1993. Because none
of the four plants controlled their emissions, their emissions factors were assumed to be equal to those of the
Kansas, Kentucky, and Louisiana plants from 1990-1999. U.S. emissions (less those of the Alabama plant) from

23 The 0.005 emissions factor was estimated by subtracting the 2010 HFC-23 emissions reported by the other facilities from the
national emissions total, subtracting the 2010 production estimated for the other facilities (based on their production capacities
and national production) from the 2010 national production total, and dividing the first by the second.

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1990-1999 were therefore allocated to each facility based on its estimated share of U.S. HCFC-22 production
capacity.

Table 3-9. Facilities Producing HCFC-22 or Destroying HFC-23 Generated During HCFC-22 Production from
1990 to 2020





Years When HCFC-22 Was Produced or HFC-23 Was

Company

Plant Location

Destroyed

Arkema

Calvert City, KY

1990-1991



Wichita, KS

1990-2002

DuPont/Chemours

Montague, Ml

1990-1995



Louisville, KY

1990-2020



Washington, WV

2000-2020

Honeywell

El Segundo, CA

1990-1992



Baton Rouge, LA

1990-2012

LaRoche Industries

Gramercy, LA

1990-1993

MDA Manufacturing/Daikin

Decatur, AL

1993-2020

3.2.10.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of HFC-23 from HCFC-22 production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described further on page 4-72
of the Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020 (EPA 2022), the uncertainty in the
national estimate in 2019 was estimated at -7% to +10%. Based on an uncertainty analysis that was performed for
the 2008 Verification Report, the uncertainties in the emissions of the individual plants that have accounted for
most of the emissions since 2010 (i.e., the plants in Kentucky and Louisiana) were comparable to this in 2006 (-5%
to +11% and -9% to +11%, respectively). The 2006 uncertainty in the much smaller emissions from the plant in
Alabama was estimated at -48% to +47%. Because the methods used to estimate emissions at these plants are not
believed to have changed significantly since 2006 and because plant-level emissions data are available for these
plants for 2010 and later years, the uncertainties in the emissions of the Kentucky, Louisiana, and Alabama plants
for 2010 and later years are believed to be similar to those estimated in the 2008 Verification Report.

For the years 1990-2009, plant-level data are not available, significantly increasing the uncertainty of
emissions estimates for individual facilities and states. This is particularly true for the five HCFC-22 production
facilities that closed before 2003 and for which production capacity data are therefore not available. The
uncertainties of the emissions of these five facilities also increased the uncertainties of the 1990-2002 emissions
of the three HCFC-22 production facilities for which production capacity data are available, because the (unknown)
production at the five facilities probably affected the capacity utilization of the other three. Capacity utilization can
vary significantly across plants and from year to year.

3.2.10.4	Recalculations

No recalculations were applied for this current report.

3.2.10.5	Planned Improvements

During the 2007-2008 review of the HFC-23 emissions estimates provided to the EPA by the Alliance for
Responsible Atmospheric Policy, RTI International (the EPA's contractor) was able to review the annual estimates
of individual HCFC-22 production facilities, but under the confidentiality agreements in place at the time of the
review, the EPA did not have direct access to the individual plant- or facility-level estimates. If one or more HCFC-
22 production facilities were able to share their 1990-2009 emissions estimates with the EPA, this would
considerably reduce the uncertainty of the EPA's 1990-2009 state-level estimates.

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3.2.10.6 References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

RTI International. (March 2008). "Verification of Emission Estimates of HFC-23 from the Production of HCFC-22:
Emissions from 1990 through 2006." Report prepared by RTI International for the Climate Change Division.

SRI Consulting. (2004). CEH Market Research Report: Fluorocarbons.

3.2.11 Phosphoric Acid Production (NIR Section 4.16)

3.2.11.1	Background

Phosphoric acid (H3PO4) is a basic raw material used in the production of phosphate-based fertilizers.
Phosphoric acid production from natural phosphate rock is a source of CO2 emissions, due to the chemical reaction
of the inorganic carbon (calcium carbonate) component of the phosphate rock. In 2020, phosphoric acid was
produced in Florida, Idaho, Louisiana, North Carolina, and Wyoming.

3.2.11.2	Methods/Approach

To develop state-level estimates of emissions from phosphoric acid production, the EPA disaggregated
national emissions from the national Inventory to all applicable U.S. states using an Approach 2 method, as defined
in the Introduction chapter of this report, using a combination of process emissions reported to the GHGRP for
2010-2020 and estimated phosphoric acid production capacity by state for 1990-2009, as shown in Table 3-10.
The national Inventory methodology was adapted to calculate state-level GHG emissions from phosphoric acid
production to ensure consistency with national estimates. The sum of emissions by state are consistent with
national process emissions as reported in the national Inventory. See Appendix D, Table D-17 through Table D-22 in
the "Phosphoric Acid" Tab, for more details on the data used.

Table 3-10. Summary of Approaches to Disaggregate the National Inventory for Phosphoric Acid Production
Across Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP process emissions data were used to estimate the percentage of
emissions by state, multiplied by the national emissions (consistent with IPCC
2006 Tier 1).

1990-2009

• Phosphoric acid production capacity data were used to estimate the percentage
of production by state, multiplied by the national emissions (consistent with
IPCC 2006 Tier 1).

The methodology used for 2010-2020 used a combination of process emissions reported to the GHGRP for
each phosphoric acid facility and their assumed use of phosphate rock by origin. The GHGRP has no reporting
threshold for phosphoric acid production, so these emissions data are representative of the industry. Consistent
with national CO2 emissions calculations in the national Inventory, state-level emissions from phosphoric acid
production were estimated using the CO2 content and usage of three categories of phosphate rock origin, where
rocks sourced from each category were assumed to have consistent CO2 content: (1) Florida and North Carolina
(FL/NC), (2) Idaho and Utah (ID/UT), and (3) imports from Morocco and Peru (Import).

Phosphoric acid production facilities operated in Florida, Idaho, Louisiana, Mississippi, North Carolina, Texas,
and Wyoming over the time series. As noted in the national Inventory, all phosphate rock mining companies in the
U.S. are vertically integrated, with fertilizer plants that produce phosphoric acid located near the mines. Based on
the location of mines, all phosphoric acid produced in Florida and North Carolina was attributed to the FL/NC rock

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type, and the phosphoric acid produced in Idaho and Wyoming was attributed to the ID/UT rock type. For
production facilities in Louisiana, Mississippi, and Texas, USGS Mineral Yearbook information was used to assign
the phosphate rock origin for each year from 1990 to 2020 (USGS 1994-2020). Where the USGS Mineral Yearbook
did not discuss the rock origin for a facility in a given year, the EPA made assumptions regarding the rock origin
based on information available in prior or subsequent year publications. Because the rock usage by origin was not
available for facilities, it was assumed that when domestic phosphate rock and imported rock were both used at a
facility, they were used in equal amounts such that half of the plant capacity used each rock type. One facility in
Louisiana was assumed to use half FL/NC phosphate rock and half imported phosphate rock, whereas another was
assumed to use only imported rock. The facilities in Mississippi and Texas were assumed to only use imported
phosphate rock.

For each of the three rock origin categories, the aggregated phosphoric acid production capacities for each
state were calculated and then used to allocate percentages of national emissions to each facility on an annual
basis. The estimated emissions from each facility for each rock type were then used to calculate a percentage of
emissions from each state for each rock type. That percentage was then applied to the national Inventory
emissions for each rock type per year to disaggregate national CO2 emissions by state and by year.

The methodology used for 1990-2009 attributes annual national phosphate rock usage to states based on the
production capacities of phosphoric acid production facilities and their assumed use of phosphate rock by origin.
Using location and estimated production capacity information on phosphoric acid production facilities for 1989
and 1991, the EPA generated an initial list of facilities operating in 1990 in each state (National Fertilizer
Development Center 1986, EPA 1993). Based on USGS Mineral Yearbook information on the operations of each
facility, the operational status and rock origin for each facility were identified on an annual basis. State-level
emissions from phosphoric acid production were estimated using the CO2 content and usage of the same three
categories of phosphate rock origin described above in the methodology for 2010-2020. For each of the three rock
origin categories, the aggregated phosphoric acid production capacities for each state were calculated and then
used to allocate percentages of national emissions to each state on an annual basis.

3.2.11.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from Phosphoric Acid Production
was calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -18%/+20% for CO2.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of GHGRP process emissions data for 2010-
2020 facility production capacity for 1990-2009. These assumptions were required because of a general lack of
more granular state-level data.

For 2010-2020, uncertainty is expected to be lower because of the use of GHGRP emissions data by state as a
surrogate for using phosphoric acid production data by state to calculate emissions.

For 1990-2009, this allocation method does not address actual utilization or production rates, which vary
from facility to facility and from year to year. While this approach implicitly accounts for the size of a facility in a
state, it could overestimate emissions in states where facilities used less of their capacity and underestimate
emissions in states where facilities used more of their capacity as a result of the lack of data on utilization rates
and production data.

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3.2.11.4	Recalculations

Recalculations were performed for the 2017-2019 portion of the time series to reflect an updated breakdown
of phosphate rock mined in Florida and North Carolina and the amount mined in Idaho and Utah as provided by
the USGS commodity specialist (EPA 2022). Additionally, the 2019 value for the total U.S. production of phosphate
rock was updated based on updated USGS data. These updates resulted in minor decreases of 3 kt CO2 in both
2017 and 2018 and an increase of 18 kt CO2 in 2019 at the national level. The updates to the national-level
emissions methodology for 2017-2019 resulted in decreases of between 1% and 3% for Florida (4 to 14 kt CO2) and
North Carolina (1 to 4 kt CO2), increases between 9% and 11% for Idaho (8 to 10 kt CO2), and a 1% decrease (1 kt
CO2) in 2018 and 5% increase (7 kt CO2) in 2019 for Louisiana.

3.2.11.5	Planned Improvements

For the facility-level phosphoric acid production capacity data used for 1990-2009, additional research is
needed to more accurately represent the level of production and emissions associated with each state. Initial
research included using corporate-level information on actual production levels at facilities in operation during the
1990-2009 time series. Because of the lack of comprehensive publicly available production data for all states and
years, this approach was not used in the initial analysis. The EPA also attempted to identify phosphoric acid
production facility expansions and temporary shutdowns that would affect production capacities. Similarly,
because of the lack of comprehensive publicly available data on changes to annual facility production capacities,
this approach was not used. Other data gaps include the origin of phosphate rock used in some facilities and some
years.

3.2.11.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

National Fertilizer Development Center, Tennessee Valley Authority. (1986). Fertilizer Trends. (1986).

U.S. Environmental Protection Agency. (1993). Background Report, AP-42 Section 5.11, Phosphoric Acid. Available
online at: https://www.epa.gov/sites/production/files/2020-
09/documents/final background document for phosphoric acid section 8.9.pdf

U.S. Environmental Protection Agency (EPA), Greenhouse Gas Reporting Program (GHGRP) (2021) Dataset as of
August 7, 2021. Available online at: https://ghgdata.epa.gov/ghgp/

U.S. Geological Survey (USGS). (1994 through 2020) Minerals Yearbook. Phosphate Rock Annual Report. 1990
through 2017. U.S. Geological Survey, Reston, VA.

3.3 Metals

This section presents the methodology used to estimate the metals portion of IPPU emissions, which consist
of the following sources:

•	Iron and steel production (CO2, CH4)

•	Ferroalloy production (CO2, CH4)

•	Aluminum production (CO2, PFCs)

•	Magnesium production and processing (CO2, HFCs, SFs)

•	Lead production (CO2)

•	Zinc production (CO2)

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3.3.1 Iron & Steel Production and Metallurgical Coke Production (NIR Section 4.17)

3.3.1.1	Background

Iron and steel (l&S) production is a multistep process that generates process-related emissions of CO2 and CFU
as raw materials are refined into iron and then transformed into crude steel. Emissions from conventional fuels
(e.g., natural gas, fuel oil) consumed for energy purposes (fuel combustion) during the production of l&S are
accounted for in the Energy sector. l&S production includes seven distinct production processes: metallurgical coke
production, sinter production, direct reduced iron (DRI) production, pellet production, pig iron24 production,
electric arc furnace (EAF) steel production, and basic oxygen furnace (BOF) steel production. In addition to the
production processes, CO2 is also generated at l&S mills through the consumption of process by-products (e.g.,
blast furnace gas, coke oven gas) used for various purposes including heating, annealing, and electricity
generation. In general, CO2 emissions are generated in these production processes through the reduction and
consumption of various carbon-containing inputs (e.g., ore, scrap, flux, coke by-products). Fugitive CFU emissions
can also be generated from these processes, as well as from sinter, direct iron, and pellet production.

In 2020, l&S production occurred in 26 states, and Indiana, Alabama, Tennessee, Kentucky, Mississippi, and
Arkansas were the leading l&S-producing states, accounting for 51% of total U.S. production (EPA 2022).

3.3.1.2	Methods/Approach

To compile emissions by state from l&S and metallurgical coke production using available data, this state-level
inventory disaggregated national emissions from the national Inventory with an Approach 2 method as defined in
the Introduction chapter of this report, using a combination of coking coal consumption data, process emissions
reported to the GHGRP, and data on steel production and employment as a surrogate for steel production data.
The sum of emissions by state is consistent with the national total process emissions reported in the national
Inventory. See Appendix H, Table H-l through Table H-4 in the "l&S" Tab, for more details on the data used.

The national Inventory methodology was adapted to calculate state-level GHG emissions to ensure consistency
with national estimates. National estimates were downscaled across states because of limitations in the availability
of state-specific data across the time series to use national methods at the state level (i.e., IPCC Tier 1 and 2
methods).

The emissions from l&S and metallurgical coke production were broken into the following categories for
national emissions calculations in the national Inventory and also as part of the state-level breakout:

•	Metallurgical coke production

•	Steel production—BOF

•	Steel production—EAF

•	Sinter production

•	Iron production

•	Pellet production

•	Other activities

The methodologies for calculating state emissions from each category are detailed below.

24 "Pig iron" is the common industry term to describe what should technically be called crude iron. Pig iron is a subset of crude
iron that has lost popularity over time as industry trends have shifted. Throughout this report and consistent with the national
Inventory, "pig iron" will be used interchangeably with "crude iron," but it should be noted that other datasets or reports may
not use "pig iron" and "crude iron" interchangeably and may provide different values for the two.

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Metallurgical Coke Production

National emissions from metallurgical coke production used for l&S are estimated based on the amount of
coke used in l&S and a carbon balance around the amount of coking coal used to produce the coke used and
accounting for any co-products produced. Specific state-level data on coke production for l&S are not readily
available; however, state-level data on coking coal consumption are available from the ElA's State Energy Data
System (SEDS). Those data are broken out by fuel type and energy consumption sector (i.e., residential,
commercial, industrial, transportation, and electric power) and available for the years 1960-2019 (EIA 2021).
Energy consumption estimates from SEDS use data from surveys of energy suppliers that report consumption,
sales, or distribution of energy at the state level, and most of the SEDS estimates rely directly on collected state-
level consumption data. The sums of the state estimates equal the national totals as closely as possible for each
energy type and end-use sector, and energy consumption estimates are generally comparable to national energy
statistics. National-level metallurgical coke production emissions from l&S were allocated to the state level based
on the percentage of total coking coal consumed per state. This approach assumes that emissions from
metallurgical coke production are directly proportional to the amount of coking coal consumed in a state. As
discussed in the Energy chapter, state-level coking coal use is based on coke production in a given state, which is
not necessarily equal to coke use. Given lack of specific data, however, coking coal production was determined to
be a reasonable surrogate for coke use within a given state because coke production is often integrated with l&S
production where the coke is used.

Steel Production

National emissions from steel production (BOF and EAF) were estimated based on a carbon balance around
carbon-containing inputs and outputs. State-level data on all the process inputs and outputs were not readily
available; therefore, surrogate data on steel production by state were used to allocate national-level steel
production emissions to the state level.

For 2010-2020, process emissions reported to the GHGRP under subpart Q (l&S facilities) were summed by
state (EPA 2010-2020) to calculate a percentage of emissions from each state. Fuel combustion emissions from
l&S facilities reporting to the GHGRP are reported separately under subpart C (combustion units). Generally, fuel
combustion emissions are reported under the energy portion of the national Inventory; however, some of these
emissions were included in l&S national Inventory calculations, specifically blast furnace emissions. Portions of fuel
consumption data for several fuel categories were included in the IPPU calculations (e.g., l&S) because they are
consumed during nonenergy-related industrial process activity. A consistent approach to avoid double counting
emissions from l&S was taken for state-level emissions, subtracting state-level l&S process emissions from each
state's energy sector emissions. More information on this allocation process is available in the Energy chapter of
this report.

A combination of subpart Q and subpart C data was used when estimating state emissions percentages from
l&S facilities in 2010-2020. Because emissions are reported by unit type in the GHGRP, the EPA was able to
disaggregate state-level emissions at the process level, including steel production by type, iron, sinter, pellet,
metallurgical coke, and other activities. For steel production, GHGRP data were available by process type: BOF and
EAF. The percentage of total emissions by steel type per state from the GHGRP data was then applied to the
national emissions of steel production by type from the national Inventory per year to calculate disaggregated CO2
emissions by state.

GHGRP has a reporting threshold of 25,000 metric tons of CO2 equivalent for l&S production, so these
emissions data are representative of the larger facilities in the industry. Using GHGRP emissions data means that
emissions from states with smaller facilities were possibly underestimated.

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For the years 1990-2009, a combination of employment data from the U.S. Census and production data from
the American Iron and Steel Institute (AISI) was used to allocate national emissions from steel production to states
(Census 1992,1997, 2002, 2007, AISI 1997-2021). AISI total steel production data were available at the state level
for the top 5 l&S-producing states, and data for the other states were combined into regions. Percentages of steel
production for these lower producing states were appropriated using the Census industry employment data. It was
assumed steel production was directly proportional to the number of employees in the state.

Census data were available for the years 1992,1997, 2002, and 2007. Data for the years 1990 and 1991 were
proxied based on 1992, and data for the years 2008 and 2009 were proxied based on 2007. Data for interim years
were interpolated. For 1992, data were pulled by state for the NAICS codes Subsector 331: Primary Metal
Manufacturing and Subsector 332: Fabricated Metal Product Manufacturing. For 1997, 2002 and 2007, state data
were pulled for NAICS codes 331111 Iron and Steel Mills and Ferroalloy Manufacturing, 331210 Iron and Steel Pipe
and Tube Manufacturing from Purchased Steel, 331221 Rolled Steel Shape Manufacturing, 331222 Steel Wire
Drawing, 331511 Iron Foundries, 331512 Steel Investment Foundries, 331513 Steel Foundries (except Investment),
and 332111 Iron and Steel Forging. For some states, the NAICS code had a low number of employees or low
number of facilities to the point where it was not reported because of anonymity concerns; therefore, these states
were not included in this analysis. For some cases, states were included if data were available at a higher NAICS
code. One exception was Maryland where data were withheld to maintain anonymity, but the state is known to
have had sizable steel production. It was assumed Maryland had 2,000 employees in the steel sector in the latest
year of Census data (2007).25 The percentage of employees and steel production across the region aggregated with
Maryland in the AISI data (Rhode Island, Connecticut, New Jersey, New York, Delaware, and Maryland) based on
the 2007 data were applied across the entire time series.

Furthermore, steel production by state was broken out into BOF and EAF steel production based on the
national totals of each type of steel produced from AISI data. Steel production in each state by type was assumed
to be proportional to the national totals by type for each year. Once data on steel production by type were
determined for each state and year, the total national emissions by steel type was attributed to each state based
on steel production in each state. This approach assumes that emissions from steel production are directly
proportional to the amount of steel produced in a state. This assumption could lead to over- or underestimations
of emissions per state depending on the type of steel production and relative emissions profile of steel production
in a given state. Furthermore, basing the state-level split of BOF and EAF on the national averages could lead to
over- or underestimation of a specific type of steel production in a given state. Given the lack of data, this
approach is considered reasonable. This is an area for future improvement based on consideration of any available
state-level steel production data.

Sinter Production, Iron Production, Pellet Production, and Other Activities

For 2010-2020, emissions from sinter production, iron production, pellet production, and other activities were
allocated based on the GHGRP data for the process types. The GHGRP reporting threshold of 25,000 metric tons of
CO2 equivalent for l&S production is applicable for these process types as well.

For 1990-2009, emissions from sinter production, iron production, pellet production, and other activities were
allocated to states based on the percentage of BOF steel production by state from the Census employment and
AISI production data (Census 1992,1997, 2002, 2007, AISI 1997-2021), as described above. It was assumed that
emissions from sinter production, iron production, pellet production, and other activities would be most closely
aligned with BOF steel production.

25 Based on https://millstories.umbc.edu/sparrows-point/.

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3.3.1.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and Cm from l&S production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -17%/+17% for CO2 and -21%/+23% for Cm.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based on a combination of coking coal consumption data, process emissions
reported to GHGRP, and data on steel production and employment,, and. These assumptions were required
because of a general lack of more granular state-level data.

Emissions from metallurgical coke production for l&S were assumed to be directly proportional to the amount
of coking coal consumed in a state, and metallurgical coke was assumed to be used in the same state it was
produced. While industry trends suggest mostly on-site use, this method could overestimate emissions from
coking coal for states where facilities transfer coking coal off-site and underestimate emissions for states where
facilities transfer coking coal for metallurgical coke production across state boundaries.

For 2010-2020, GHGRP data were used to disaggregate national Inventory emissions to the state level for
steel, sinter, iron, pellet, and other activities. Because GHGRP receives detailed data down to the process unit
level, uncertainty is lower. While the GHGRP data have a reporting threshold of 25,000 metric tons of CO2
equivalent, GHGRP estimates that 99.8% of industry emissions are accounted for (EPA 2008), and the GHGRP data
are likely representative of the whole industry.

For 1990-2009, the Census data were used as a surrogate for production data for steel, sinter, iron, pellet, and
other activities to disaggregate national Inventory data by state. Because this method assumes that all facilities
produce the same amount of emissions regardless of production capacities, it could overestimate emissions in
states with smaller facilities and underestimate emissions in states with larger facilities. Additionally, for sinter,
iron, pellet, and other activities, emissions are based on BOF steel production for the state, which may
overestimate or underestimate state-level emissions for these activities.

By-product fuels are assumed to be used on-site in this method. Although industry trends show facilities using
by-product fuels such as coke oven gas or blast furnace gas on-site, if these by-products are shipped off-site, this
adds an additional level of uncertainty to state-level estimates. If these by-products are shipped across state lines
for energy use, emissions may be overestimated for states where facilities transfer by-products off-site and across
state boundaries and underestimated for states where facilities use by-products on-site from across state
boundaries.

3.3.1.4	Recalculations

For the national Inventory, recalculations were performed for the year 2019 with updated values for coke
production at coke plants, scrap steel consumption for EAF steel production, scrap steel consumption for BOF steel
production, and pellet consumption in blast furnaces from the EIA, the USGS, and AISI. These updates resulted in
emissions increases of 114% from metallurgical coke production (1.6 million metric tons (MMT) CO2), less than 1%
from iron production (87 kt CO2), 1.2% from pellet production (11 kt CO2), and less than 1% from steel production
(42 kt CO2). State emissions values for 2019 for iron production, pellet production, steel production, other
activities, and coke production were similarly impacted by these changes and also were updated.

3.3.1.5	Planned Improvements

AISI production data were only available from 1997-2020 (AISI 1997-2021), so data are incomplete for earlier
years of the time series. This is an area for future improvement based on consideration of any available state-level
production data.

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Census employment data are released every 5 years, and employment estimates were based on NAICS codes.
The NAICS codes used might not encompass the whole industry, and generally as a method, the number of
employees may not correlate well to emissions. One area of future improvement is to better understand the
completeness of employment data and make adjustments as necessary.

Combustion emissions from GHGRP data are not entirely consistent across reporters because some facilities
report under subpart C and some report combined emissions using CEMS. Also, fuel use data from the GHGRP
might not be equivalent to data included in the national Inventory calculations under l&S because the GHGRP data
do not specifically indicate if fuel is used in nonenergy applications. One area of future improvement is to examine
the GHGRP energy use estimates in comparison to what is assumed in the national Inventory calculations and
adjust as needed.

The EPA plans to compare coking coal consumption data from EIA SEDS to the data from the GHGRP reporting
program for the years 2010-2020 as a QA/QC check.

The EPA also plans to compare BOF and EAF data by state from the GHGRP to the AISI national percentage
breakout of EAF and BOF by state to see if there is a better approach to allocating BOF and EAF production by state
for 1990-2009. In general, the EPA plans to compare the industry data to the GHGRP program data across time to
see how close they are to see if using the industry data is a reasonable approach.

The EPA will review time-series consistency issues related particularly to steel production. Surrogate data
(industry employment) were used in place of activity data for all but the top 5 producing states for the 1990-2009
portion of the time series, and more research will be undertaken to identify potential methodological refinements
to enhance the accuracy and consistency of estimated state GHG emissions and trends.

3.3.1.6 References

American Iron and Steel Institute. (1997-2021). Annual Statistical Report. Available online at:
https://www.steel.org/industrv-data/reports/

Energy Information Administration. (2021). EIA State Energy Data System (SEDS), energy consumption data for
1990-2019. Released: June 25, 2021. Available online at: https://www.eia.gov/State/seds/

Energy Information Administration. (1990-2009). Quarterly Coal Report. Available online at:
https://www.eia.gov/coal/production/auarterlv/

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Census Bureau. (1992,1997, 2002, 2007). Geographic Area Series, Manufacturing. Available online at:
1992: https://www.census.gov/librarv/publications/1995/econ/mc92-a.html
https://www.census.gov/librarv/publications/1995/econ/mc92-a.html
1997: https://www.census.gov/librarv/publications/1997/econ/census/manufacturing-
reports. htmlhttps://www. census.gov/librarv/publications/1997/econ/census/manufa cturing-reports.html
2002: https://www.census.gov/librarv/publications/2002/econ/census/manufacturing-
reports. htmlhttps://www. census.gov/librarv/publications/2002/econ/census/manufa cturing-reports.html
2007: https://www.census.gov/data/tables/2007/econ/census/manufacturing-
reports. htmlhttps://www.census.gov/data/tables/2007/econ/census/manufacturing-reports. html

U.S. Environmental Protection Agency. (September 10, 2008). Technical Support Document for the Iron and Steel
Sector: Proposed Rule for Mandatory Reporting of Greenhouse Gases.

U.S. Environmental Protection Agency. (2010-2020). Greenhouse Gas Reporting Program (GHGRP). Envirofacts
GHGRP subpart Q, subpart C, and common data. Accessed May 10, 2022. Available online at:
https://www.epa.gov/enviro/greenhouse-gas-customized-search

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U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

3.3.2 Ferroalloys Production (NIR Section 4.18)

3.3.2.1	Background

CO2 and Cm are emitted from the production of several ferroalloys. Ferroalloys are composites of iron (Fe)
and other elements such as silicon (Si), manganese (Mn), and chromium (Cr). Emissions from fuels consumed for
energy purposes during the production of ferroalloys are accounted for in the Energy sector. Emissions from the
production of two types of ferrosilicon (25% to 55% and 56% to 95% silicon), silicon metal (96% to 99% silicon), and
miscellaneous alloys (32% to 65%) have been calculated.

Consistent with the national Inventory, emissions from the production of ferrochromium and ferromanganese
are not included because of the small number of manufacturers of these materials in the United States.
Government information disclosure rules prevent the publication of production data for these production facilities.
Additionally, production of ferrochromium in the United States ceased in 2009.

Similar to emissions from the production of l&S, CO2 is emitted when metallurgical coke is oxidized during a
high-temperature reaction with iron and the selected alloying element. Although most of the carbon contained in
the process materials is released to the atmosphere as CO2, a percentage is also released as CH4 and other
volatiles. The amount of CH4 that is released depends on furnace efficiency, operation technique, and control
technology.

In 2020, ferroalloy production occurred in six states: Ohio, Pennsylvania, Alabama, Kentucky, Michigan, and
West Virginia.

3.3.2.2	Methods/Approach

To compile emissions by state from ferroalloy production, the state-level inventory disaggregated national
emissions from the national Inventory with an Approach 2 method as defined in the Introduction chapter of this
report, using a combination of process emissions reported to the GHGRP and the number of facilities in a state
(see Table 3-11). See Appendix H, Tables H-5 and H-6 in the "Ferroalloy" Tab, for more details on the data used.

The national Inventory methodology was adapted to calculate state-level GHG emissions to ensure consistency
with national estimates. National estimates were downscaled across states because of limitations in the availability
of state-specific data across the time series to use national methods (i.e., IPCC Tier 1 methods) at the state level.
The sum of emissions by state is consistent with the national process emissions reported in the national Inventory.

Table 3-11. Summary of Approaches to Disaggregate the National Inventory for Ferroalloys Production
Across Time Series

Time Series Range

Summary of Method

2010-2020

•	GHGRP facility process emissions data were used.

•	Remaining emissions reported in the national Inventory were allocated across
remaining known facilities (IPCC 2006 Tier 1).

1990-2009

• Data on number of facilities from the GHGRP-reported emissions were used to
allocate emissions for those facilities. Remaining emissions were allocated
evenly across remaining known facilities (IPCC 2006 Tier 1).

To identify all ferroalloy-producing facilities for 1990-2020, the number of facilities in each state was compiled
from the USGS Minerals Yearbooks for ferroalloys as available (USGS 2008-2016) and compared with the facilities

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reporting to the GHGRP. The GHGRP has a reporting threshold of 25,000 metric tons of CO2 equivalent for
ferroalloy production, so these emissions data are representative of the larger facilities in the industry. Combining
GHGRP emissions data with the number of facilities in each state includes smaller facilities and improves the
completeness of the state-level inventory. The total number of facilities from the 2008 USGS Minerals Yearbook
for ferroalloys was used for 1990-2007 because the Mineral Yearbooks for years before 2008 did not contain the
number of facilities. Additionally, facilities were not included in years that the EPA determined the facility was not
operational. The EPA used internet searches to determine the opening dates of ferroalloys facilities and to
determine whether they were operational during all inventory years (AMG 2017, Bloomberg Bear 2021, Bloomberg
Eramet 2021, Businesswire 2020, Businesswire 2017, Centerra 2021, Chattanooga 2015, D&B 2021, Ferroglobe
2020, Global 2010, Vanadium 2019, Wikipedia 2021).

Five of the facilities listed in the USGS Mineral Yearbook also reported to the GHGRP in 2010-2020, and the
reported process emissions data were used for these facilities. To improve the completeness of this state-level
inventory and estimate emissions from the remaining known facilities in 2010-2020, process emissions reported to
the GHGRP were summed (EPA 2010-2020) for each year and subtracted from the national Inventory total
emissions for each year. The remaining balance was distributed equally among the facilities listed in the USGS
Minerals Yearbook that did not report to the GHGRP.

For 1990-2009, the average GHGRP emissions from each GHGRP facility for the years 2010-2012 were applied
to each year, and the remaining emissions were evenly distributed among the remaining facilities. Values for the
years 2010-2012 were used because these were expected to be a more accurate representation of emissions in
1990-2009.

Once facility-level emissions were calculated, the emissions were summed by state to calculate CChand CH4
emissions by state for each year.

3.3.2.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 and CH4 from ferroalloy production
was calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -13%/+13% for CO2 and -12%/+13% for CH4.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based on process emissions reported to the GHGRP and the number of facilities in
a state. These assumptions were required because of a general lack of more granular state-level data.

For 2010-2020, this allocation method relies partially on GHGRP emissions data, which have a lower
uncertainty for states where those reporting facilities are located but have a higher uncertainty for states where
smaller facilities that did not report to the GHGRP are located. This method could underestimate emissions from
larger facilities and overestimate emissions from smaller facilities.

For 1990-2009, this allocation method does not fully address facilities' production capacities or utilization
rates, which vary from facility to facility and from year to year. Because this approach implicitly assumes that
emissions from facilities that did not report to the GHGRP are equal regardless of production capacity or utilization
rates and that facilities that did report to the GHGRP had the same annual emissions levels for these years, this
approach could overestimate emissions in some states and underestimate emissions in others.

Emissions for ferromanganese and ferrochromium are not included in the national Inventory estimate because
of the small number of manufacturers in the United States. The facilities producing these ferroalloys, however, are
included in the state Inventory disaggregation; thus, state-level estimates are likely an underestimate.

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3.3.2.4	Recalculations

No recalculations were applied for this current report.

3.3.2.5	Planned Improvements

There are significant differences between USGS and GHGRP data regarding which facilities are included in the
ferroalloys industry. Six facilities reported to the GHGRP but were not listed by the USGS, and six facilities were
listed by the USGS but did not report to the GHGRP. The GHGRP has a reporting threshold for ferroalloys
production, which may contribute to the difference in the latter group of facilities. Clarifying why this discrepancy
exists would improve inventory data accuracy both at the national and disaggregated state levels.

Because USGS do not list ferroalloy production at the state level, the EPA estimated that all facilities that did
not report to the GHGRP produced equal emissions. Data on the size and capacity of each facility would allow the
EPA to distribute emissions more accurately. As a future improvement, the EPA may use Title V or state-level
permits to look for capacity data for each facility to better estimate emissions by state.

While production of ferrochromium in the United States ceased in 2009, the EPA will assess whether data are
available to incorporate emissions from facilities producing ferromanganese and ferrochromium in the national-
and state-level inventories over the time series.

3.3.2.6	References

AMG. (2017). Our History. Advanced Metallurgical Group Vanadium (Metallurg Vanadium Corp.) 2017. Available
online at: https://amg-v.com/timeline amg v/

Bloomberg Bear. (2021). Bloomberg company profile for Bear Metallurgical Co. Available online at:
https://www.bloomberg.eom/profile/companv/0589837D:US

Bloomberg Eramet. (2021). Bloomberg company profile for Eramet Marietta Inc. Available online at:
https://www.bloomberg.eom/profile/companv/0205877D:US

Businesswire. (2020). CC Metals and Alloys, LLC is Shutting Down its Operations on July 1 Due to Poor Market
Conditions. Businesswire, June 24, 2020. Available online at:

https://www.businesswire.com/news/home/202006240Q5217/en/CC-Metals-and-Allovs-LLC-is-Shutting-
Down-its-Operations-on-Julv-l-Due-to-Poor-Market-Conditions

Businesswire. (2017). Felman Production Reports on Temporary Shut Down of Its New Haven, W. Va. Facility.
Businesswire, July 25, 2017. Available online at:

https://www.businesswire.com/news/home/201707250Q6161/en/Felman-Production-Reports-on-
Temporarv-Shut-Down-of-lts-New-Haven-W.-Va.-Facility

Centerra. (2021). Langeloth Metallurgical Facility. Centerra Gold. 2021. Available online at:
https://www.centerragold.com/operations/thompson-creek-metals/langeloth/historv

Chattanooga. (2015). Focus on the worker: Lesson learned in Bridgeport aids growing silicon industry. Chattanooga
Times Free Press, August 16, 2015. Available online at:

https://www.timesfreepress.com/news/business/aroundregion/storv/2015/aug/16/lessons-learned-

bridgeport-inform-merger/319744/?bcsubid=81b8962b-36f8-4876-9b5f-77ela0bbf54b&pbdialog=reg-wall-

login-created-tfp

D&B. (2021). Dun & Bradstreet company profile for Reading Alloys, Inc. Available online at:
https://www.dnb.com/business-directorv/companv-
profiles.reading alloys inc.21d7f6ff83866c7a6c9580cl45fb46e5.html

Ferroglobe. (2020). Beverly: History. Ferroglobe (Globe Metallurgical Inc.) 2020. Available online at:
https://www.ferroglobe.com/about-ferroglobe/factories-mines/beverlv/

Global. (2010). History. Global Titanium Inc. 2010. Available online at: http://www.globaltitanium.net/historv.htm

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Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2010-2020). Greenhouse Gas Reporting Program (GHGRP). Envirofacts
GHGRP subpart K data. Accessed August 7, 2021. Available online at:
https://www.epa.gov/enviro/greenhouse-gas-customized-search

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (2008 through 2016). Minerals Yearbook: Ferroalloys Annual Report. U.S. Geological
Survey, Reston, VA.

Vanadium. (2019). US Vanadium LLC Announces Agreement to Acquire Evraz Stratcor, Inc. Vanadiumprice.com
August 12, 2019. Available online at: https://www.vanadiumprice.com/us-vanadium-llc-announces-
agreement-to-acquire-evraz-stratcor-inc/

Wikipedia. (2021). RTI International Metals, Inc. 2021. Available online at:
https://en.wikipedia.org/wiki/RTI International Metals

3.3.3 Aluminum Production (NIR Section 4.19)

3.3.3.1	Background

The production of primary aluminum—in addition to consuming large quantities of electricity—results in
process-related emissions of carbon dioxide (CO2) and two perfluorocarbons (PFCs): perfluoromethane (CF4) and
perfluoroethane (C2F6). Aluminum Production occurs or has occurred in the past in the following 14 states: Indiana,
Kentucky, Maryland, Missouri, Montana, North Carolina, New York, Ohio, Oregon, South Carolina, Tennessee,
Texas, Washington, and West Virginia.

Carbon dioxide is emitted during the aluminum smelting process when alumina (aluminum oxide, AI2O3) is
reduced to aluminum using the Hall-Heroult reduction process. The reduction of the alumina occurs through
electrolysis in a molten bath of natural or synthetic cryolite (NasAIFs). The reduction cells contain a carbon (C)
lining that serves as the cathode. Carbon is also contained in the anode, which can be a C mass of paste, coke
briquettes, or prebaked C blocks from petroleum coke. During reduction, most of this C is oxidized and released to
the atmosphere as CO2.

In addition to CO2 emissions, the aluminum production industry is also a source of PFC emissions. During the
smelting process, when the alumina ore content of the electrolytic bath falls below critical levels required for
electrolysis, rapid voltage increases occur, which are termed high-voltage anode effects (HVAEs) HVAEs cause C
from the anode and fluorine from the dissociated molten cryolite bath to combine, thereby producing fugitive
emissions of CF4 and C2F6. In general, the magnitude of emissions for a given smelter and level of production
depends on the frequency and duration of these anode effects. As the frequency and duration of the anode effects
increase, emissions increase. Another type of anode effect, low-voltage anode effects (LVAEs), became a concern
in the early 2010s as the aluminum industry increasingly began to use cell technologies with higher amperage and
additional anodes (IPCC, 2019). LVAEs emit CF4 and are included in PFC emissions totals from 2006 forward.

3.3.3.2	Methods/Approach

National emissions of CO2 and PFCs from aluminum production are estimated using a combination of IPCC Tier
1, Tier 2 and Tier 3 methods (i.e., EPA GHGRP data) over the time series as discussed in Chapter 4, Section 4.19 (on

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pages 4-93 through 4-97) of the national Inventory. IPCC Tier 1 methods were used only to estimate PFC emissions
from LVAEs.

Aluminum production emissions calculated nationally were allocated to the state level using a Hybrid
approach due to lack of facility-level and/or state-level production data for earlier years of the time series. For
2010 and later, the EPA used the same underlying methods as the as those used for the national Inventory, i.e.,
facility-specific process emissions reported to the EPA's GHGRP under subpart F: Aluminum Production to estimate
state-level emissions; for 1990-2009, the EPA used the ratio of each state's smelter capacity to the U.S. total
capacity to allocate national emissions to each state. The approach summarized in Table 3-12 was taken to compile
aluminum production estimates by state consistent with national totals.

Table 3-12. Summary of Approaches to Disaggregate the National Inventory for Aluminum Production
Across Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP process emissions data were used to get emissions by state (i.e.,
Approach 1).

1990-2009

• Data on smelter capacity were used to get percentage of production by state,
which was then multiplied by national emissions (Approach 2).

For 2010-2020, the EPA used facility-specific emissions reported to the GHGRP and facility locations to
allocate estimated emissions to each state. All aluminum production facilities in the United States report their
emissions to the EPA. CF4 emissions from LVAEs were estimated by allocating total U.S. LVAE emissions according
to each state's yearly percentage of total HVAE CF4 emissions. The percentages were calculated on a yearly basis
(state total/yearly total) to account for non-reporting years.

For 1990-2009, the EPA allocated national totals to each state using the ratio of each state's smelter capacity
to the U.S. total capacity, on a yearly basis (i.e., state X emissions = national emissions * (ratio = state X smelter
capacity/national smelter capacity)). Capacity data for the years 1990,1993, 2001, and 2004-2009 were collected
from the respective years' USGS Aluminum yearbook, and capacities for other years were interpolated from the
aforementioned USGS Aluminum yearbooks' capacity data trends. Information on idle facilities and shutdowns was
incorporated in determining state smelter capacities based on USGS aluminum yearbooks notes, and additional
sources (including expert reviewers' feedback, and public articles). National emissions during this time period were
developed using smelter capacity data and the USAA U.S. primary aluminum production estimates, combined with
the process emissions and activity data reported under the EPA's Voluntary Aluminum Industrial Partnership
Program (VAIP).

3.3.3.3 Uncertainty

The overall uncertainties associated with the 2020 national estimates of CO2 and PFC emissions from
Aluminum production were calculated using the 2019 Refinement to the 2006 IPCC Guidelines. As described
further in Chapter 4 of the national Inventory, levels of uncertainty in the national estimates in 2020 surrounding
the reported CO2, CF4, and C2F6 emission values were determined to have a normal distribution with uncertainty
ranges of approximately 2% below to 2% above, 7% below to 8% above, and 11% below to 11% above their 2020
emission estimates, respectively.

For the 2010 to 2020 time series, the uncertainties associated with the state-level estimates are expected to
be lower than those for the 1990-2009 time series because emissions are estimated and reported at the facility
level. Nevertheless, the 2010 to 2020 state-level uncertainties are somewhat higher than 2010 to 2020 national-
level uncertainties because, for each gas, the uncertainty of each smelter's emissions is higher than the uncertainty

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of the emissions across all smelters.26 The uncertainty of each smelter's CO2 emissions is estimated at -/+6%; the
uncertainty of each smelter's HVAE CF4 emissions is estimated to range from -/+16%; and the uncertainty of each
smelter's HVAE C2F6 emissions is estimated to range from -/+20%. The uncertainty associated with LVAE emissions
is estimated based on the smelter technology type and is estimated to range from -/+99% for each smelter.
Because LVAE emissions make up a small share of total PFC emissions, this uncertainty does not have a large
impact on the overall uncertainty of PFC emissions at either the smelter or the US level. For more details on
national-level uncertainty, see the Uncertainty discussion in Chapter 4 of the national Inventory.

State-level estimates are expected to have significantly higher uncertainties for 1990-2009 than more recent
years due to the methods used to apportion the national emission estimates to each state based on the capacity
data from the USGS Aluminum yearbooks. This approach does not reflect the volatility in actual aluminum
production activities in each smelter (and thus in the different states) from year to year, and the estimated
emissions in each state may therefore differ from the actual emissions resulting from aluminum production
activities in that state.

3.3.3.4	Recalculations

Refer to section 4.19 (page 4-103) of the national Inventory report for a complete list of recalculations for the
national Inventory.

3.3.3.5	Planned Improvements

The EPA identified a potential refinement in the approach to compile annual state estimates over 1990-2009
that would allocate emissions based on emissions data reported under the EPA's VAIP. Where facility-specific data
were not reported under VAIP, additional data, including technology type and estimated production, could be used
to allocate data to the states from the VAIP data.

The EPA will further investigate the sources of historical total primary aluminum production estimates for the
earlier years in the time series and potentially update historical estimates to aim for increased consistency
throughout the time series. As part of this planned improvement, EPA will review whether historical estimates are
broken down into smelter specific production estimates, which are the basis for calculating smelter, and therefore
state, PFC (for non-partners) and CO2 emissions (for all facilities) for the 1990 through 2009 time series (years
preceding GHGRP reporting). Additional improvements include evaluating the LVAE emissions calculations method
by state for the 2010-2020 time series. Currently, the LVAE CF4 emissions are based on each state's yearly
percentage of total HVAE CF4 emissions. Future iterations of the state disaggregation estimates of LVAE CF4
emissions will be based on estimates of aluminum production, consistent with the Tier 1 LVAE method and the
national Inventory.

3.3.3.6	References

IPPC (2019) 2019 Refinement to the 2006IPCC Guidelines for National Greenhouse Gas Inventories. The National
Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate Change. [Calvo Buendia, E.,
Tanabe, K., Kranjc, A., Baasansuren, J., Fukuda, M., Ngarize, S., Osako, A., Pyrozhenko, Y., Shermanau, P. and
Federici, S. (eds.)]. Hayama, Kanagawa, Japan.

U.S.A.A. (September 2020). U.S. Primary Aluminum Production: Report for August 2020. U.S. Aluminum
Association, Washington, DC.

26 Note that this holds true generally for the sum of variables with independent errors: the error of the sum tends to be lower
than the error of each variable.

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U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4.19: Aluminum Production (CRF Source Category 2C3). Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-main-text.pdf

U.S. Environmental Protection Agency. Greenhouse Gas Reporting Program (GHGRP). Envirofacts. Subpart F:
Aluminum Production. Available online at: http://www.epa.gov/enviro/facts/ghg/search.html

U.S. Geological Survey. (1996-2021). Minerals Yearbook: Aluminum. U.S. Geological Survey, Reston, VA.
3.3.4 Magnesium Production and Processing (NIR Section 4.20)

3.3.4.1	Background

The magnesium metal production and casting industry uses sulfur hexafluoride (SFs) and other greenhouse
gases (i.e., HFC-134a and Novec 612) to prevent the rapid oxidation of molten magnesium in the presence of air. A
dilute gaseous mixture of these gases with dry air and/or CO2 is blown over molten magnesium metal to induce
and stabilize the formation of a protective crust. A small portion of the cover gas reacts with the magnesium to
form a thin molecular film of mostly magnesium oxide and magnesium fluoride. The amount of cover gas reacting
in magnesium production and processing is considered to be negligible; thus, all cover gas used is assumed to be
emitted into the atmosphere. Magnesium production occurs or has occurred previously in the following states:
California, Illinois, Indiana, Michigan, Minnesota, Missouri, Ohio, Tennessee, Utah, and Washington.

3.3.4.2	Methods/Approach

National emissions of SF6, HFC-134a, Novec 612, and CO2 from magnesium production and processing are
estimated using a combination of IPCC Tier 2 and Tier 3 methods over the time series as discussed in Chapter 4,
Section 4.20 (on pages 4-100 through and 4-102) of the national Inventory.

National magnesium processing and production emissions were allocated to the state level using a Hybrid
approach due to a lack of facility-level data for some years and for some facilities. For 2011-2020, the EPA used
facility-specific emissions data from the EPA's GHGRP for primary and secondary production, die casting, and sand
casting. For these same years estimates of national emissions from permanent mold, wrought, and anode
production were allocated to the state level based on state emissions percentages developed using data reported
to the GHGRP. No producers of permanent mold, wrought, and anode magnesium products report to the GHGRP.
The EPA assumed that non-reporting facilities were located in the same states as reporting facilities.

For 1999-2010, the EPA used company-specific reported cover gas emissions data reported to the EPA
through the SF6 Emission Reduction Partnership for the Magnesium Industry to both allocate emissions to the
states and process types with reporting partner companies, as well as derive a percentage of emissions by state.
These percentages by state were applied to the remaining non-Partner emissions such that the full complement of
national magnesium emission could be apportioned to the state level, similar to the approach used for later years
when GHGRP data became available. For 1990-1998, where GHGRP and Partnership data are not available, a
simplified assumption of national to state-level apportionment based on 1999 data was used to estimate emissions
from all magnesium production and processes.

Table 3-13 provides additional specifics on the approaches taken to compile state-level estimates of emissions
for magnesium production consistent with national totals.

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Table 3-13. Summary of Approaches to Disaggregate the National Inventory for Magnesium Production
Across Time Series

Time Series Range

Summary of Method

2011-2020

•	For primary, secondary, die casting, and sand casting, emissions were allocated
by facility locations based on information reported to the GHGRP (Approach 1).

•	For permanent, wrought, and anode, emissions were allocated proportionally to
states with reported emissions (Approach 2).

1999-2010

•	For primary, secondary, die casting, and sand casting, emissions were allocated
by company and facility locations based on cover gas usage reported to the EPA
Partnership Program (Approach 1).

•	For permanent, wrought, and anode, emissions were allocated proportionally to
states with reported emissions for secondary, die casting, and sand casting,
excluding the primary production company (Approach 2).

1990-1998

• Percentage of emissions by state and process type in 1999 was used to allocate
national emissions across states from 1990 to 1998 and included all process
types (Approach 2; please refer to the national Inventory for more details).

All Processes

The methodology used for all process for 1990-1998 is based on disaggregating 1999 national emissions by
process type and by state and then using that to develop shares of state emissions as a portion of total national
emissions. These 1999 state emissions shares by process type were used to allocate estimated total U.S. emissions
by process type to states for 1990-1998.

Primary, Secondary; Die Casting, and Sand Casting

The methodology used for 2011-2020 relied on GHGRP-reported emissions. The EPA allocated emissions from
GHGRP reporting facilities to the states in which the reporting facilities are located. For non-reported estimated
emissions or emissions estimated from smaller casting facilities falling under the GHGRP reporting threshold, the
EPA allocated emissions associated with the non-reporting population proportionally to states with reported
emissions. For example, if state A had X% of total reported GHGRP emissions for a particular process type, state A
got X% of total U.S. estimated non-reported emissions for that particular process type.

The methodology used for 1999-2010 relied on emissions reported to the EPA as under EPA's SF6 Emission
Reduction Partnership for the Magnesium Industry. The EPA allocated emissions from partners to the state in
which facilities are located as reported through the GHGRP or identified through online research. Note that the
national Inventory assumes that all U.S. emissions from primary and secondary production in 1999-2010 were
from partners. This is not the case for die casting and sand casting. For non-reported estimated emissions, the EPA
allocated emissions associated with the non-reporting population proportionally to states with reported emissions
for the appropriate process type.

Permanent, Wrought, and Anode

For 2011-2020, emissions associated with these processes are not reported through the GHGRP. Total U.S.
production is reported through the USGS Yearbook. Therefore, the EPA used a similar methodology that is used for
the non-reported emissions state allocation for primary, secondary, die, and sand casting. Emissions associated
with these types of processes were allocated proportionally to states with reported emissions, with the exclusion
of primary production facilities because there is only one facility and it is not in a state that has other magnesium
facilities.

For 1999-2010, emissions associated with these processes were not reported through the Partnership
Program. Total U.S. production is reported through the USGS Yearbook. Therefore, the EPA used a methodology

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similar to the methodology for allocating non-reported emissions for primary, secondary, die, and sand casting to
the states. The EPA allocated total U.S. emissions associated with these types of processes proportionally to states
with reported emissions for secondary, die casting, and sand casting, excluding the primary production facility,
assuming that these states were the most likely to contain facilities that produced magnesium products via
permanent, wrought, and anode processes; however, it is possible that other states have emissions from these
production processes.

3.3.4.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of SF6, HFC-134a, and CO2emissions from
magnesium production and processing were calculated using the were calculated using the 2019 Refinement to the
2006IPCC Guidelines. As described further in Chapter 4 of the national Inventory, levels of uncertainty in the
national estimates in 2020 for all gases in aggregate were -9%/+9%.

Overall, the state-level estimates of emissions for magnesium are expected to have a higher uncertainty than
the national estimates; however, the variability in uncertainty levels between state-level estimates and national
estimates differs throughout the time series. For the 2011-2020 time series, the uncertainties associated with the
state-level estimates are expected to be low because emissions are estimated and reported at the facility level for
the most part. Nevertheless, the 2011-2020 state-level uncertainties are somewhat higher than 2011-2020
national-level uncertainties because for some process types facility-reported data are not available (i.e.,
permanent, wrought, and anode). For 1999-2010, state-level estimates have a higher uncertainty that national
estimates in the same time period, as well as more uncertainty than that of the state-level estimates for 2011-
2020. This is due to a higher proportion of facility data being available through the GHGRP as compared to the EPA
Partnership for each year. Allocation of estimated but unreported emissions for specific process types (i.e., sand
casting, die casting, permanent, wrought, and anode) is also done within this time period based on the state
proportions of reported emissions, leading to increased uncertainty due to the assumption that unreported
emissions occur in the same proportion across states as reported emissions. For 1990-1998, state-level estimates
are expected to have a significantly higher level of uncertainty than that of more recent years because no facility-
specific emissions are available and because emissions have been allocated to states based on a single year of
state-level data, which does not account for changes in emitters over the time period, such as plant openings and
closures or process changes. These assumptions were required due to lack of available state- or regional-level
data. For more details on national-level uncertainty, see the Uncertainty discussion in Chapter 4 of the national
Inventory.

3.3.4.4	Recalculations

Additional data and new information became available through the GHGRP that affected state estimates:

•	Primary production SF6 emissions were set equal to zero from 2016 through 2020 because of a
confirmation that the facility completed its transition to HFC-134a in 2016.

•	Additional GHGRP data became available for CO2 and HFC-134a emissions that occurred in 2017
production. These data were used to replace proxy data for this year, which were previously held
constant from 2016.

•	A correction was made for a die casting facility for 2016. This facility did not report in 2016, and previously
2016 SFs emissions were held constant at 2015 levels. This approach was updated to estimate 2016 SF6
emissions through interpolation between 2015 and 2017.

CO2 emissions from permanent, wrought, and anodes were estimated and added for all inventory years based
on the rate of CO2 emissions from other processes (i.e., primary, secondary, die and sand casting). A correction was
made to include CO2 emissions from sand casting were not included from 1990 through 2010. These emissions
were added in the national Inventory and therefore carried through in the state estimates. Emissions from

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dolomite calcination were also added and accounted for in this source category, adding significant CO2 emissions
from 1990 to 2001.

Refer to Section 4.19 (page 4-109) of the national Inventory report for a complete list of recalculations for the
national Inventory.

3.3.4.5	Planned Improvements

One planned improvement would be to investigate information that could be used to update the factors used
to allocate emissions from non-reporters. Currently, this is based on the fraction of GHGRP reported emissions in
each state.

Planned improvements are the same as those planned for improving national estimates, given that the
underlying methods for state GHG estimates are the same as those in the national Inventory, given that
improvements in the national Inventory will lead directly to improvements in the quality of state-level estimates as
well. For more information, see Chapter 4, Section 4.20, of the national Inventory.

3.3.4.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4.20: Magnesium Production (CRF Source Category 2C4). Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-main-text.pdf

U.S. Environmental Protection Agency. Greenhouse Gas Reporting Program (GHGRP). Envirofacts. Subpart T:
Magnesium Production. Available online at: http://www.epa.gov/enviro/facts/ghg/search.html

U.S. Geological Survey. (2021, 2020, 2017, 2016, 2015, 2014, 2013, 2012, 2011, 2010, 2009, 2008, 2007, 2006,
2005a, 2003, 2002). Minerals Yearbook: Magnesium Annual Report. U.S. Geological Survey, Reston, VA.
Available online at: http://minerals.usgs.gOv/minerals/pubs/commoditv/magnesium/index.html#mis

3.3.5 Lead Production (NIR Section 4.21)

3.3.5.1	Background

Primary production of lead through the direct smelting of lead concentrate produces CO2 emissions as the
lead concentrates are reduced in a furnace using metallurgical coke. Similar to primary lead production, CO2
emissions from secondary lead production result when a reducing agent, usually metallurgical coke, is added to the
smelter to aid in the reduction process. CO2 emissions from secondary production also occur through the
treatment of secondary raw materials. Emissions from fuels consumed for energy purposes during the production
of lead are accounted for in the Energy sector. In 2020, emissive lead production occurred in nine states: Alabama,
Minnesota, Indiana, Missouri, New York, Florida, California, South Carolina, and Pennsylvania. The last primary
lead production facility in the United States closed at the end of 2013.

3.3.5.2	Methods/Approach

To compile emissions by state from lead production using available data, this state-level inventory
disaggregated national emissions from the national Inventory with an Approach 2 method as defined in the
Introduction chapter, using a combination of process emissions reported to the GHGRP to calculate process
emissions and the number of facilities in a state (see Table 3-14). See Appendix H, Table H-7 through Table H-9 in
the "Lead" Tab, for more details on the data used.

The national Inventory methodology was adapted to calculate state-level GHG emissions to ensure consistency
with national estimates. National estimates were downscaled across states because of limitations in availability of
state-specific data across the time series to use national methods (i.e., IPCC Tier 1 methods) at the state level. The
sum of emissions by state are consistent with national process emissions as reported in the national Inventory.

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Table 3-14. Summary of Approaches to Disaggregate the National Inventory for Lead Production Across
Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP process emissions data were used to estimate the percentage of
emissions by state, multiplied by the national emissions (IPCC 2006 Tier 1).

1990-2009

• Data on number of lead facilities were used to estimate the percentage of
production by state, multiplied by the national emissions (IPCC 2006 Tier 1).

The methodology used for 2010-2020 was based on process emissions reported to the GHGRP summed by
state (EPA 2010-2020) to calculate a percentage of emissions from each state. The GHGRP has a reporting
threshold of 25,000 metric tons of CO2 equivalent for lead production, so these emissions data are representative
of the larger facilities in the industry. Using GHGRP emissions data means that emissions from states with smaller
facilities were possibly underestimated. That percentage was then applied to the national emissions from lead
production per year to calculate disaggregated gross CO2 emissions by state.

The methodology used for 1990-2009 was based on the number of facilities in each state divided by the
number of facilities nationally to calculate a percentage of facilities in each state for each year. This percentage
was applied to the national CO2 emissions from lead production per year (EPA 2022) to disaggregate CO2 emissions
by state for each year. For 1995-2009, the number of facilities per state was compiled from the USGS Minerals
Yearbooks for lead, as available (USGS 1995-2009), and locations were estimated based on available information.
For 1990-1994, the number of facilities from the 1995 USGS Minerals Yearbook for lead was used because the
Mineral Yearbooks for those years did not contain the number of facilities.

The USGS Mineral Commodity Summaries for lead (1990-2020) only provide primary and secondary lead
production as total national values, with no breakdown by state. The USGS Mineral Yearbooks for lead also did not
have any state-specific production data. As such, these sources could not be used for state-level data in the state
disaggregation estimates.

Primary vs. Secondary Production Adjustment

In general, CO2 emissions from primary lead production facilities are about two times the CO2 emissions from
secondary lead facilities on a per-unit or production basis. To account for the difference between primary and
secondary lead facilities from 1990-2013 when primary lead production took place in the United States, an
adjustment was made to the state primary and secondary facility counts. The GHGRP CO2 emissions for the one
primary facility and the secondary facilities for reporting years 2010-2013 were compiled. Next, the production for
the primary facility and secondary facilities from the USGS Mineral Yearbooks was compiled for 2010-2013. The
ratio of CO2 emissions to production for each year for the primary facility and secondary facilities was calculated
and then averaged across those years. Primary facilities have, on average, a 1:1 ratio of CO2 emissions to
production tons. Secondary facilities have, on average, a 1:2 ratio of CO2 emissions to production tons. The
average ratios for primary and secondary facilities were applied to each state's primary and secondary facility
count to calculate a weighted percentage of emissions per state for primary and secondary facilities.

CEMS Adjustment for 2010-2020

Starting in 2010, lead-producing facilities with emissions over the GHGRP reporting threshold reported both
process and combustion emissions to the GHGRP. One facility started using a CEMS to measure and report CO2
emissions in 2016. For this facility starting in 2016, process and combustion emissions were reported together
under subpart C per the GHGRP requirements. All other facilities not using a CEMS reported process emissions

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under subpart R and combustion emissions under subpart C.27 To disaggregate process emissions for the facility
using a CEMS, a facility-specific default ratio of process emissions to total emissions was calculated for each year
from 2010-2015 and averaged. Emissions reported to subparts R and C were compiled for the one facility, and the
percentage of process emissions to total emissions for the non-CEMS years was applied to the total CO2 emissions
for each year the facility used CEMS in order to calculate process emissions for each year. The results were an
estimated process CO2 emissions value for that CEMS facility for 2016-2020.

Because the methodology for 1990-2009 does not use GHGRP emissions data to calculate the state emissions
and the facility did not begin using a CEMS to report emissions until 2016, there is no need to adjust for CEMS
facilities for those years.

3.3.5.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from lead production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -15%/+16% for CO2.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on a combination of GHGRP emissions data for 2010-2020 and
the estimated number and location of facilities for 1990-2009.

For 2010-2020, uncertainty is expected to be lower because of the use of GHGRP emissions data by state to
allocate national GHG emissions by state, which is a surrogate for using lead production data by state to calculate
emissions. National Inventory estimates, however, have been 6% to 38% lower than GHGRP estimates for 2010-
2020. State-level inventory estimates are derived from the national Inventory figures and, therefore, are lower
than the corresponding totals for facilities from a given state that reports to the GHGRP.

For 1990-2009, this allocation method does not address facilities' production capacities or utilization rates,
which vary from facility to facility and from year to year. While this approach does assume differences in primary
and secondary production processes, it implicitly assumes emissions from those primary and secondary facilities,
respectively, are equal regardless of production capacity or utilization rates, which could overestimate emissions in
states with smaller facilities and underestimate emissions in states with larger facilities.

Primary lead production occurred in the United States from 1990 to 2013. To minimize uncertainty, methods
were adjusted to account for differences in emissions from primary and secondary lead production.

3.3.5.4	Recalculations

Minor recalculations were performed in this report for 2019 state-level inventory estimates due to updates to
the GHGRP and GHGI datasets. For the facility reporting to the GHGRP using a CEMS, 2019 emissions data were
updated to a value 0.04% lower than the prior reported emissions. The 2019 GHGI national estimate for emissions
from lead production decreased 2.5% due to updates in USGS secondary lead production data. This update results
in a corresponding minor decrease in state-level emissions for 2019.

3.3.5.5	Planned Improvements

More information on combustion CO2 emissions from smelting furnaces is needed to disaggregate combustion
and process emissions from the facility reporting CO2 with a CEMS to the GHGRP in 2016-2020. Additionally,
because the GHGRP dataset is available starting with 2010, EPA is assessing the feasibility to review and update

27 For more information on the GHGRP, see 74 FR 56374, Oct. 30, 2009. Available online at:
https://www.eovinfo.eov/content/pke/FR-2009-10-30/pdf/E9-23315.pdf.

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lead production data by state for earlier parts of the time series. For example, the estimated number and location
of facilities producing lead per state for 1990-2009 still need to be confirmed, especially for 1990-1994.

The EPA will review time-series consistency issues due to the two methodologies for 1990-2009 and for 2010-
2020. Surrogate data (number of primary and secondary lead production facilities) were used in place of activity
data for the 1990-2009 portion of the time series, and more research is needed so that calculations more closely
reflect state trends in emissions.

3.3.5.6 References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2010-2020). Greenhouse Gas Reporting Program (GHGRP). Envirofacts
GHGRP subpart S and subpart C data. Accessed May 9, 2021. Available online at:
https://www.epa.gov/enviro/greenhouse-gas-customized-search

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

U.S. Geological Survey. (1995 through 2009). Minerals Yearbook: Lead Annual Report. U.S. Geological Survey,
Reston, VA.

3.3.6 Zinc Production (NIR Section 4.22)

3.3.6.1	Background

Zinc production in the United States consists of both primary and secondary processes. Of the primary and
secondary processes currently in use in the United States, only the Waelz kiln secondary process results in
nonenergy CO2 emissions. For earlier years in the time series, the emissive electrothermic, PIZO furnace, and flame
reactor processes were also utilized, from before 1990 to 2014, 2009 to 2012, and 1993 to 2013, respectively.
Emissions from fuels consumed for energy purposes during the production of zinc are accounted for in the energy
sector. In 2020, emissive zinc production occurred in five states: Alabama, Pennsylvania, South Carolina,

Tennessee, and Illinois.

3.3.6.2	Methods/Approach

To compile emissions by state from zinc production using available data, this state-level inventory
disaggregated national emissions from the national Inventory with an Approach 2 method as defined in the
Introduction chapter, using a combination of process emissions reported to the GHGRP and the number of
facilities in a state (see Table 3-15). See Appendix H, Table H-10 through Table H-14 in the "Zinc" Tab, for more
details on the data used.

The national Inventory methodology was adapted to calculate state-level GHG emissions to ensure consistency
with national estimates. National estimates were downscaled across states because of limitations in the availability
of state-specific data across the time series to use national methods at the state level (e.g., IPCC Tier 2 methods).
The sum of emissions by state is consistent with national process emissions as reported in the national Inventory.

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Table 3-15. Summary of Approaches to Disaggregate the National Inventory for Zinc Production Across
Time Series

Time Series Range

Summary of Method

2010-2020

• GHGRP process emissions data were used to estimate the percentage of
emissions by state, multiplied by the national emissions (IPCC 2006 Tier 2).

1990-2009

• Data on number of zinc facilities were used to estimate the percentage of
production by state, multiplied by the national emissions (IPCC 2006 Tier 2).

The methodology used for 1990-2009 used the number of facilities in each state divided by the number of
facilities nationally to calculate a percentage of facilities in each state for each year. This percentage was applied to
the national CO2 emissions from zinc production per year (EPA 2022) to calculate disaggregated CO2 emissions by
state for each year. The number of facilities per state was determined from reviewing the number of facilities
reporting to the GHGRP and using company websites to confirm when facilities opened and closed and the number
of electrothermic furnaces, Waelz kilns, other furnaces, and flame reactor units.

The methodology used for 2010-2020 used process emissions reported to the GHGRP summed by state and
nationally (EPA 2010-2020) to calculate a percentage of emissions from each state. That percentage was then
applied to the national emissions from zinc production per year to calculate disaggregated gross CO2 emissions by
state. The GHGRP has a reporting threshold of 25,000 metric tons of CO2 equivalent for zinc production, so these
emissions data are representative of the larger facilities in the industry. Using GHGRP emissions data means that
emissions from states with smaller facilities were possibly underestimated.

The USGS Mineral Commodity Summaries for zinc (1990-2020) only had U.S. zinc production as total national
values with no breakdown by state. The USGS Mineral Yearbooks for zinc also did not have any state-specific
production data. As such, these sources could not be used for state-level data in the state disaggregation
estimates.

EAF Dust Consumption Facility Accounting for 2010-2020

Since 2010, the GHGRP has required zinc manufacturing facilities that operate electrothermic furnaces or
Waelz kilns to report CO2 emissions. The national Inventory includes emissive facilities that operate electrothermic
furnaces or Waelz kilns and other facilities that process EAF dust. The one facility utilizing an electrothermic
furnace was in operation from before 1990 to 2014. Two additional facilities that process EAF dust do not have
electrothermic furnaces or Waelz kilns and do not report to the GHGRP, but they are accounted for in the national
Inventory: PIZO in Blytheville, AR, and American Zinc Recycling Corp. (Horsehead Corp.) in Beaumont, TX.

The PIZO Blytheville, AR, facility was in operation from 2009 to 2012 (PIZO 2021). The national Inventory
methodology of using estimated EAF dust consumed values and an emissions factor of 1.24 metric ton CO2 per
metric ton EAF dust consumed was used to calculate CO2 emissions for each year.

The American Zinc Recycling Corp. (Horsehead) Beaumont, TX, facility was in operation from around 1993 to
2009 (AZR 2021). The EAF dust recycling and processing capacity for the Beaumont, TX, facility for 2009 was
obtained from the U.S. Securities and Exchange Commission (Horsehead 2010). The CO2 emissions for the
Beaumont, TX, facility were calculated using the national Inventory methodology, using estimated EAF dust
consumed values and an emissions factor of 1.24 metric ton CO2 per metric ton EAF dust consumed.

Electrothermic Furnace, Waelz Kiln, Other Furnaces, and Flame Reactor Unit Adjustment for 1990-
2009

Per-unit production CO2 emissions from Waelz kilns are about 2 times the CO2 emissions from electrothermic
furnaces (EPA 2010-2019). To account for the difference in the quantity of CO2 emissions from electrothermic

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furnaces and Waelz kilns, an adjustment was made to the number of electrothermic furnaces and Waelz kilns per
state. The 2010-2019 GHGRP CO2 emissions for electrothermic furnaces and Waelz kilns and number of units by
type (i.e., electrothermic furnaces, Waelz kilns) per facility were compiled to calculate the average CO2 emissions
per facility and average CO2 emissions per unit per facility. Note that 2020 GHGRP emissions data were not
included in calculating these averages, as 2020 and future year data may not be as representative to apply to
1990-2009 emissions estimates. Only one facility had electrothermic furnaces. The average CO2 emissions per unit
per facility were calculated across the five facilities with Waelz kilns.

The 2009 CO2 emissions value for the PIZO Blytheville, AR, facility was used to estimate CO2 emissions for
other furnaces, while the 2009 CO2 emissions value for the American Zinc Recycling Corp. (Horsehead) Beaumont,
TX, facility was used to estimate CO2 emissions for flame reactor units.

The average CO2 per unit for electrothermic furnaces and Waelz kilns and the 2009 CO2 per unit value for
other furnaces and flame reactor units were applied to calculate a weighted percentage of emissions per state for
electrothermic furnaces, Waelz kilns, other furnaces, and flame reactor units. Each percentage of emissions per
state was applied to the national CO2 emissions from the national Inventory to calculate CO2 emissions per state.

3.3.6.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2 from Zinc Production was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -19%/+20% for CO2.

State-level estimates are expected to have an overall higher uncertainty because the national emissions
estimates were apportioned to each state based on the number of facilities and production processes for 1990-
2009 and GHGRP emissions data for 2010-2020.

For 1990-2009, this allocation method does not address production capacity or utilization rate at a facility-
specific level. This approach could overestimate emissions in states with smaller capacity or less used production
units and underestimate emissions in states with larger capacity or high utilization production units.

For 2010-2020, uncertainty is expected to be lower than the period from 1990-2009 because of the use of
GHGRP emissions data by state to calculate emissions. Smaller facilities do not report to GHGRP, however, and
were excluded from these estimates, affecting the completeness of these estimates.

3.3.6.4	Recalculations

Minor recalculations were performed in this report for 2019 state-level inventory estimates due to a revision
to the national Inventory. The 2019 national Inventory estimate for emissions from zinc production was revised
from 1.02587 to 1.02577 million metric tons of CO2 equivalent (a 0.01% decrease) due to recalculation of the
emissions factor for EAF dust consumption to address rounding in the intermediate calculation. This update results
in a corresponding minor decrease in estimated state-level emissions for 2019.

3.3.6.5	Planned Improvements

Data gaps to calculate emissions from zinc production include zinc production by unit type by state for the full
time series. The estimated number of facilities producing zinc per state for 1990-2009 needs to be confirmed,
including the zinc production methodology (e.g., electrothermic furnaces, Waelz kilns, other facilities processing
EAF dust).

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3.3.6.6 References

American Zinc Recycling (AZR). (2021). Summary of Company History. Available online at: https://azr.com/our-
historv/

Horsehead Corp. (2010). 10-k Annual Report for the Fiscal Year Ended December 31, 2009. Submitted on March 16,
2010. Available online at: https://lastl0k.eom/sec-filings/zinca/0000950123-10-025167.htm#link fullReport

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

PIZO. (2021). Personal communication. Thomas Rheaume, Arkansas Department of Environment and Environment
and Amanda Chiu, U.S. Environmental Protection Agency. February 16, 2021.

U.S. Environmental Protection Agency. (2010-2020). Greenhouse Gas Reporting Program (GHGRP). Envirofacts
GHGRP subpart S and subpart C data. Accessed May 9, 2022. Available online at:
https://www.epa.gov/enviro/greenhouse-gas-customized-search

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
(EPA 430-R-22-003), Chapter 4: Industrial Processes and Product Use. Office of Air and Radiation, Office of
Atmospheric Programs, U.S. Environmental Protection Agency, Washington, DC. Available online at:
https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-emissions-and-sinks

3.4 Product Use (Fluorinated Sources, N2O)

The product use portion of IPPU emissions is a catchall category that consists of the following:

•	Electronics industry (HFCs, PFCs, SF6, NF3, N2O)

•	Substitution of ozone-depleting substances (ODSs) (HFCs, PFCs)

•	Electrical transmission and distribution (SFs)

•	Nitrous oxide from product uses (N2O)

3.4.1 Electronics Industry (NIR Section 4.23)

3.4.1.1 Background

The electronics industry uses multiple greenhouse gases in its manufacturing processes. In semiconductor
manufacturing, these include long-lived fluorinated greenhouse gases used for plasma etching and chamber
cleaning (CRF Source Category 2E1), fluorinated heat transfer fluids (CRF Source Category 2E4) used for
temperature control and other applications, and nitrous oxide (N2O) used to produce thin films through chemical
vapor deposition (reported under CRF Source Category 2H3). Similar to semiconductor manufacturing, the
manufacturing of micro-electro-mechanical systems (MEMS) devices (reported under CRF Source Category 2E5
Other) and photovoltaic cells (CRF Source Category 2E3) requires the use of multiple long-lived fluorinated
greenhouse gases for various processes. Electronics manufacturing occurs in the following states: Arizona,
California, Colorado, Florida, Georgia, Hawaii, Idaho, Indiana, Maine, Maryland, Massachusetts, Minnesota,
Mississippi, Missouri, New Jersey, New Mexico, New York, North Carolina, Oregon, Pennsylvania, Texas, Utah,
Vermont, Virginia, and Washington.

For semiconductors, a single 300 mm silicon wafer that yields between 400 to 600 semiconductor products
(devices or chips) may require more than 100 distinct fluorinated-gas-using process steps, principally to deposit
and pattern dielectric films. Plasma etching (or patterning) of dielectric films, such as silicon dioxide and silicon
nitride, is performed to provide pathways for conducting material to connect individual circuit components in each
device. The patterning process uses plasma-generated fluorine atoms, which chemically react with exposed
dielectric film to selectively remove the desired portions of the film. The material removed as well as undissociated

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fluorinated gases flow into waste streams and, unless emission abatement systems are employed, into the
atmosphere. Plasma enhanced chemical vapor deposition chambers, used for depositing dielectric films, are
cleaned periodically using fluorinated and other gases. During the cleaning cycle the gas is converted to fluorine
atoms in plasma, which etches away residual material from chamber walls, electrodes, and chamber hardware.
Undissociated fluorinated gases and other products pass from the chamber to waste streams and, unless
abatement systems are employed, into the atmosphere.

In addition to emissions of unreacted gases, some fluorinated compounds can also be transformed in the
plasma processes into different fluorinated compounds which are then exhausted, unless abated, into the
atmosphere. For example, when C2F6 is used in cleaning or etching, CF4 is typically generated and emitted as a
process by-product. In some cases, emissions of the by-product gas can rival or even exceed emissions of the input
gas, as is the case for NF3 used in remote plasma chamber cleaning, which often generates CF4 as a by-product.

Nitrous oxide is used in manufacturing semiconductor devices to produce thin films by CVD and nitridation
processes as well as for N-doping of compound semiconductors and reaction chamber conditioning (Doering
2000).

Liquid perfluorinated compounds are also used as heat transfer fluids (F-HTFs) for temperature control, device
testing, cleaning substrate surfaces and other parts, and soldering in certain types of semiconductor
manufacturing production processes. Leakage and evaporation of these fluids during use is a source of fluorinated
gas emissions (EPA 2006).

3.4.1.2 Methods/Approach

Emissions associated with the electronics industry include emissions from semiconductors, MEMS, heat
transfer fluids, and PV. National emissions were estimated using IPCC Tier 2 methods as discussed further in
Chapter 4, Section 4.23 (on page 4-124) of the national Inventory. In general, the EPA used a Hybrid approach to
disaggregate national estimates.

Semiconductor and Micro-Electro-Mechanical Systems (MEMS) Manufacturing

To disaggregate emissions by state for semiconductors and MEMS, the EPA used data sources from the GHGRP
and the World Fab Forecast (WFF).28 A Hybrid approach was used to estimate emissions from semiconductor and
MEMS manufacturing, relying on a mix of state-level data derived from the GHGRP, the EPA partnership and
program data, and disaggregation of national-level emission estimates, where facility-level data were not available.
For years prior to the GHGRP data being available (i.e., before 2011), a simplified assumption was used by applying
the proportional state-level estimates for total manufactured layer area (TMLA) to the national semiconductor
emissions estimate. For MEMS emissions, a linear interpolation was used between 1990 (assuming zero emissions
from MEMS manufacturing) and 2011, the first year of available GHGRP data. Table 3-16 summarizes methods
used to compile emissions of CF4, C2F6, C3F8, CHF3, SF6, NF3, C4F8, C4F6, C4F8O, CsFs, CH2F2, CH3F, CH2FCF3, C2H2F4, and
N2O from semiconductor and MEMS manufacturing.

Table 3-16. Summary of Approaches to Disaggregate the National Inventory for Semiconductor and MEMS
Manufacturing Across Time Series

Time Series Range	Summary of Method

2014-2020	' Emissions from reported fabs were allocated to the state in which the

reporting facility was located as reported through the GHGRP (Approach 1).
• Emissions from non-reporting facilities were allocated by calculating the
percentage of TMLA estimated for non-reporting facilities in each state using

28 EPA periodically purchases the World Fab Forecast from SEMI (https://www.semi.org/en/products-services/market-
data/world-fab-forecast).

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Time Series Range

Summary of Method



the WFF dataset and multiplying by the total estimate of non-reported



emissions in the national Inventory (Approach 2).



• Emissions from non-reporting MEMS facilities were not estimated, which is



consistent with the national Inventory.

2013

•	Emissions from reported fabs, adjusted for time-series consistency in the
national Inventory, were allocated based on the location of the GHGRP facility.
The reported emissions were scaled up by 0.017% to account for time series
consistency (Approach 1).

•	Emissions from non-reporting facilities were allocated by calculating the
percentage of TMLA estimated for non-reporting facilities in each state using
the WFF dataset and multiplying by the total estimate of non-reported
emissions in the national Inventory. The unreported emissions were scaled up
by 0.017% to account for time series consistency (Approach 2).

•	Emissions from non-reporting MEMS facilities were not estimated, which is
consistent with the national Inventory.

2011-2012

•	Emissions from reported fabs, adjusted for time-series consistency in the
national Inventory, were allocated based on the location of the GHGRP facility
(Approach 1).

•	Emissions from non-reporting facilities were allocated by calculating the
percentage of TMLA estimated for non-reporting facilities in each state using
the WFF dataset and multiplying by the total estimate of non-reported
emissions in the national Inventory (Approach 2).

•	Emissions from non-reporting MEMS facilities were not estimated, which is
consistent with the national Inventory.

2008-2010

• Emissions were allocated to states using the proportional state-level TMLA
breakdowns for the respective year, which were applied to total estimates
from the national Inventory (Approach 2).

1990-2007

•	Emissions from semiconductor manufacturing were allocated between states
from the national Inventory in the same proportion as they were in 2008
(Approach 2).

•	Emissions from MEMS were assumed to be zero in 1990. Emissions from
MEMS facilities from 1991 to 2010 were then estimated by interpolating
between 1990 emissions and the emissions estimated for 2011 for each state
(Approach 2).

•	N2O emissions data were first reported in 2015, so emissions from MEMS
facilities from 1991-2014 were interpolated for N2O (Approach 2).

From 2014 to 2020, emissions from reported fabs were allocated to the state in which the reporting facility
was located as reported through the GHGRP.

From 2011 to 2013, fluorinated GHGs (F-GHG) and N2O emissions from reported fabs, adjusted for time-series
consistency in the national Inventory, were allocated based on the location of the GHGRP facility. Emissions from
non-reporters were allocated to each state as described above. Emissions from non-reporting facilities that
manufactured semiconductors were estimated by calculating the percentage of TMLA estimated for non-reporting
facilities in each state using the WFF dataset; the state's percentage of total non-reporter TMLA was then used to
allocate the non-reporter portion of national emissions as calculated in the national Inventory. Reporter and non-
reporter emissions from 2013 were scaled up by 0.017% to account for the differences in emissions factor utilized.
Emissions from non-reporting MEMS facilities are not estimated, which is consistent with the national Inventory.

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From 2008 to 2010, F-GHG and N2O emissions from semiconductor manufacturing were allocated to states
using the proportional state-level TMLA breakdowns for the respective year, which were applied to total estimates
from the national Inventory.

From 1990 to 2007, F-GHG and N2O from semiconductor manufacturing emissions were allocated between
states in the same proportion as they were in 2008.

From 1990 to 2011, emissions from MEMS facilities were estimated by interpolating between 1990 emissions
and the emissions estimated for 2011. Emissions from MEMS were assumed to be zero in 1990. N2O emissions
from MEMS facilities were first reported in 2015 and assumed to be zero in 1990. Emissions from 1991-2014 were
interpolated between 1990 emissions and the emissions estimate for 2015. Only one facility in New York, GE
Global Research Center, reported N2O emissions, so all emissions in the time series were attributed to New York.

Only 26 states were identified as containing semiconductor fabs, six of which also reported emissions from the
production of MEMS.

Fluorinated Heat Transfer Fluids (F-HTFs)

To estimate state-level emissions of F-HTFs, the EPA used a Hybrid approach to disaggregate national
emissions. For the national Inventory, for years when GHGRP data were available, the EPA estimated state-level
emissions based on facility location. For earlier years, the EPA allocated national F-HTF emissions to each state
based on that state's share of national F-GHG emissions from semiconductor manufacturing. This Hybrid approach
was used due to a lack of available data on reported HTF emissions or HTF consumption at the facility or state level
for years prior to GHGRP's availability. Table 3-17 summarizes methods used to compile HTF emissions.

Table 3-17. Summary of Approaches to Disaggregate the National Inventory for Fluorinated HeatTransfer
Fluids Across Time Series

Time Series Range

Summary of Method

2011-2020

•	National F-HTF emissions were allocated to the states in the same proportion as
emissions from reported fabs were allocated to the states in which the reporting
facilities were located, as reported through the GHGRP (Approach 1).

•	Emissions from non-reporters were added to each state's emissions from HTFs
by multiplying state emissions of HTFs by the estimated non-reporter GHGRP
emissions percentage taken from the national Inventory (Approach 2).

2000-2010

• National F-HTF emissions were allocated to states in the same proportion as F-
GHG emissions associated with semiconductor manufacturing (Approach 2).

1990-1999

• F-HTF emissions do not occur and are not estimated in the national Inventory
during 1990-1999 and thus are estimated to not occur at state levels.

From 2011 to 2020, emissions from reported fabs were allocated to the state in which the reporting facility
was located as reported through the GHGRP. Emissions from non-reporters were added to each state's emissions
from HTFs by multiplying state emissions of HTFs by the estimated non-reporter GHGRP emissions percentage
taken from the national Inventory.

For emissions from 2000 to 2010, F-HTF emissions were allocated between states in the same proportion as F-
GHG emissions associated with semiconductor manufacturing. Emissions data were taken directly from the
national Inventory and the allocation was only applied to the HTF emissions that were included in the national
Inventory totals. HTF emissions were assumed to not occur during or before 2000. A total of 23 states were
identified as reporting emissions of F-HTFs.

Emissions from 1990 to 1999 are assumed not to have occurred. Fluorinated HTF use in semiconductor
manufacturing is assumed to have begun in the early 2000s.

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Photovoltaics

To estimate state-level emissions from photovoltaics (PV) manufacturing, the EPA used a Hybrid approach,
applying a GHGRP-derived emissions factor to state-level manufacturing capacity data. Two different emissions
factors were developed: one for fluorinated GHGs and one for N2O. For years with available GHGRP data, Approach
1 was used for manufacturers that reported PV emissions at the state level. This Hybrid approach was used due to
a lack of available data on reported emissions at the state level for years prior to the GHGRP's availability. Table
3-18 summarizes methods used to compile state-level emissions from C2F6, C3F8, CF4, CHF3, SF6, NF3, C4F8, and N2O.

Table 3-18. Summary of Approaches to Disaggregate the National Inventory for Photovoltaics Across Time
Series

Time Series Range

	

Summary of Method

2011-2020

•	State-level estimates of manufacturing capacity were used to allocate emissions
for non-reporters (Approach 2).

•	Reported facility data were allocated to the state where the facility was located
(Approach 1).

2000-2010

• State-level estimates of manufacturing capacity based on facility-level

manufacturing capacity data were used to allocate emissions. Capacity was
interpolated for years in which capacity data were unavailable (Approach 2).

1998-1999

• State-level emissions were interpolated for 1998 and 1999 (Approach 2).

1990-1997

• Capacity was assumed to be zero during 1990-1997 (Approaches 1 and 2).

For 2011-2020, reported state-level emissions from photovoltaics (PV) manufacturing were estimated by
allocating emissions from GHGRP reporters to the state in which the reporting facility is located. Two PV facilities,
Micron Technology and Mission Solar, reported to the GHGRP, during this time period (neither for the full period
of 2011 through 2020). Therefore, all the reported emissions were allocated to Idaho and Texas—the states in
which Micron Technology and Mission Solar are located, respectively—for the years for which reported data are
available. Non-reporter emissions were estimated using manufacturing capacity data from DisplaySearch (2010),
which provides facility-specific data, including the facility's state. Emissions from non-reporters were calculated by
multiplying the manufacturing capacity of each state by emissions factors in million metric tons CC>2e per
megawatt (MW) (two emissions factors were developed, one for F-GHGs and one for N2O) based on reported
emissions from Mission Solar.

For 2000-2010, non-reporter emissions were estimated using the proportion of each state's manufacturing
capacity in 2009 (the most recent year of DisplaySearch data purchased) to the overall non-reporter estimate used
in the national Inventory.

Manufacturing capacity was interpolated between 1997 and 2000 and used to estimate emissions in 1998 and
1999 using the same emissions factor described above. Manufacturing capacity was assumed to be zero in 1997
and before based on an assessment of available industry manufacturing data (Platzer 2015). Manufacturing
capacity was interpolated between 1997 and 2000 and used to estimate emissions in 1998 and 1999 using the
same emissions factor described above.

3.4.1.3 Uncertainty

The overall uncertainty associated with the national emissions estimates for the electronics industry was
calculated using the 2019 Refinement to the 2006 IPCC Guidelines. As described further in Chapter 4 of the

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national Inventory, levels of uncertainty in the national estimates in 2020 were -6%/+6% across the electronics
industry.

State-level estimates are expected to have a higher uncertainty than national estimates because the
uncertainty of each facility's emissions is higher than the uncertainty of emissions across all facilities, or in other
words the uncertainty of a sum of independent variables is lower than the uncertainty of the variables. For years
with state- and facility-level GHGRP data, state-level estimates will still be higher than national totals due to the
uncertainty of many additional independent variables. State-level estimates will have the most uncertainty for
years where state-level activity data were not available, namely years before the start of GHGRP data. Pre-2011
estimates are generated by apportioning the national totals by state-level TMLA estimates, which come from
various sources including World Fab Watch and WFF. State-level estimates for 1990-2007 are apportioned using
the most recent year of state-level TMLA data (2008), which will add significant uncertainty to those estimates. For
more details on national-level uncertainty, see the Uncertainty discussion in Section 4.23 of the national Inventory.

3.4.1.4	Recalculations

State-level estimates from 2015 to 2020 were updated to reflect updated emissions reported through the
GHGRP, relative to the previous Inventory. Gases were added to the state-level estimates for semiconductor
manufacturing, MEMS, HTFs, and PV. PV estimates were corrected for 2003 through 2011 to align with the
national Inventory and address a summing error related to the total U.S. manufacturing capacity of crystalline
silicon. In addition, 2013 emissions for semiconductor manufacturing increased by 0.017%, reflecting adjustments
made for time series consistency, in line with the national Inventory. State-level N2O emissions were added for PV
and MEMS. Refer to the national Inventory report for a complete list of recalculations for the national Inventory.

3.4.1.5	Planned Improvements

Planned improvements are consistent with those planned for improving national estimates, given that the
underlying methods for state GHG estimates are the same as those in the national Inventory. For more
information, see Chapter 4, Section 4.23, of the national Inventory.

3.4.1.6	References

DisplaySearch. (2010). DisplaySearch Q4'09 Quarterly FPD Supply/Demand and Capital Spending Report.
DisplaySearch, LLC.

SEMI

(Semiconductor

Equipment

and

Materials

Industry).

(2021).

World Fab Forecast, June 2021 Edition.

SEMI

(Semiconductor

Equipment

and

Materials

Industry).

(2018).

World Fab Forecast, June 2018 Edition.

SEMI

(Semiconductor

Equipment

and

Materials

Industry).

(2017).

World Fab Forecast, August 2018 Edition.

SEMI

(Semiconductor

Equipment

and

Materials

Industry).

(2016).

World Fab Forecast, May 2017 Edition.

SEMI

(Semiconductor

Equipment

and

Materials

Industry).

(2013).

World Fab Forecast, May 2013 Edition.

SEMI

(Semiconductor

Equipment

and

Materials

Industry).

(2012).

World Fab Forecast, August 2012 Edition.

U.S. Environmental Protection Agency. (2006). Uses and Emissions of Liquid PFC Heat Transfer Fluids from the
Electronics Sector (EPA-430-R-06-901).

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4.23: Electronics Industry (CRF Source Category 2E). Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-main-text.pdf

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U.S. Environmental Protection Agency. Greenhouse Gas Reporting Program (GHGRP) Envirofacts. Subpart I:

Electronics Manufacture. Available online at: http://www.epa.gov/enviro/facts/ghg/search.html

M. Platzer. (2015). U. S. Solar Photovoltaic Manufacturing: Industry Trends, Global Competition, Federal Support.

Congressional Research Service.

3.4.2 Substitution of Ozone-Depleting Substances (NIR Section 4.24)

3.4.2.1	Background

Hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs) are used as alternatives to several classes of ODSs
that are being phased out under the terms of the Montreal Protocol and the Clean Air Act Amendments of 1990.29
Ozone-depleting substances—chlorofluorocarbons (CFCs), halons, carbon tetrachloride, methyl chloroform, and
hydrochlorofluorocarbons (HCFCs)—are used in a variety of industrial applications including refrigeration and air-
conditioning equipment, solvent cleaning, foam production, sterilization, fire extinguishing, and aerosols. Although
HFCs and PFCs are not harmful to the stratospheric ozone layer, they are potent greenhouse gases.

3.4.2.2	Methods/Approach

As described in the national Inventory report (EPA 2022), the EPA employs its Vintaging Model to estimate
national use, banks, emissions, and transition of ODS-containing equipment and products to substitutes, including
HFCs and perfluorocarbons (PFCs) and blends that contain such substances.). The Vintaging Model estimates ODS
and ODS substitute trends in the United States based on modeled estimates of the quantity of equipment or
products sold each year containing these chemicals and the amount of the chemical required to manufacture or
maintain equipment and products over time. Emissions for each end use were estimated by applying annual leak
rates and release profiles, which account for the lag in emissions from equipment as it leaks over time. The model
uses a Tier 2 bottom-up modeling methodology to estimate emissions and hence requires extensive research,
data, assumptions, and expert judgment to develop the activity levels and emissions profiles over the time series
for each of the 78 end uses modeled (see Section 4.24 and Annex 3.9 of the national Inventory for additional
description of the Vintaging Model and further details such as the end uses modeled [EPA 2022]).

An approach similar to the Vintaging Model can be used to develop state-level emissions estimates. California,
for one, uses this approach (California Air Resources Board [CARB] 2016). Doing so however requires the same
extensive data gathering and may be difficult to monitor given the interstate commerce that occurs for many of
the products involved.

Another approach to estimate a state's emissions would be to assume the state's proportion of national
emissions is the same as the state's proportion of national population. For many ODS substitute equipment types,
this is a reasonable approach. For instance, the number of supermarkets, home refrigerators, and light-duty
vehicles with air-conditioning, per person, is not expected to vary significantly from state to state. For some other
end uses, however, this is not the case. For instance, EIA (2021) statistics confirm that the use of air-conditioning
varies by region. This could lead to a significant difference that is not directly related to population. As noted in the
national Inventory, the EPA estimates that residential unitary air-conditioning is the second largest emitting (in
C02e terms) end use within the refrigeration and air-conditioning sector, which accounts for 78% of national
emissions (EPA 2022).

The disaggregation approach used here is a combination of using population as a proxy for emissions (i.e.,
"Approach 2") while incorporating data provided at a finer geographical distribution than the national emissions
estimates (i.e., "Approach 1").

' 42 U.S.C § 7671, CAA Title VI.

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Analysis by NOAA further points to the varying nature of emissions across the United States (Hu et al. 2017).
The analysis incorporated data from a variety of ground- and air-level measurements of various fluorocarbons. By
applying Lagrangian atmospheric transport models and a Bayesian inverse modeling technique, Hu et al. estimated
emissions on a 1° x 1° grid across the contiguous states and District of Columbia. The paper estimated emissions of
various fluorocarbons (ODS and HFCs) over six regions of the United States through this approach. The authors
observed that spatial patterns for individual compounds agree well with qualitative expectations, pointing to
examples of higher per capita emissions for chemicals used as blowing agents in building insulation foams (CFC-11,
HCFC-142b, and HFC-365mfc) in the northern states and higher per capita emissions of HCFC-22, HFC-125, and
HFC-32 used in residential and commercial air-conditioning in southeastern and central south states. These results
agreed with recommendations for thermal insulation (DOE, 2016) in northern regions and the higher percentage of
homes with air-conditioning (EIA, 2018a, b) in southern regions. Derived per capita emissions of HFC-134a
displayed similar regional patterns as refrigerants used in residential air-conditioning, except in the central north
region where the per capita emissions was comparable to that in southern regions. The authors surmised that this
distribution may stem from additional use of HFC-134a in refrigeration and as a foam-blowing agent in building
insulation in northern regions.

A population distribution was modified with data from Hu et al. (2017) to disaggregate national emissions to
individual states, territories, and the District of Columbia. For this exercise, multiple references from the U.S.
Census were used to gather population estimates to distribute national-level emissions to the regions incorporated
into the national emissions estimates (i.e., for the 50 states, the District of Columbia, Puerto Rico, American
Samoa, Guam, Northern Mariana Islands, and the U.S. Virgin Islands) (U.S. Census Bureau 2002, 2011, 2021, 2022;
Instituto de Estadisticas de Puerto Rico 2021). Population estimates across the time series were not available for
the Federated states of Micronesia, Marshall Islands, and Palau; therefore, none of the U.S. national emissions
estimates was attributed to those territories. For years in which a population estimate was not provided, linear
interpolation was used.

Annual emissions per capita for the six regions analyzed in Hu et al. (2017) were used. Specifically, emissions
for HFC-125, HFC-134a, and HFC-143a from 2008-2014 and emissions for HFC-32 from 2010-2014 were available
(Hu 2021). The six regions described in the paper are West (California, Oregon, and Washington), Mountain
(Montana to New Mexico), Central North (North Dakota to Kansas to Ohio), Central South (Texas to Alabama to
Kentucky), Southeast (North Carolina to Florida), and Northeast (West Virginia to Maine).

Because the Hu et al. (2017) estimates cover the 48 contiguous states and the District of Columbia, emissions
estimates from the remaining states (Alaska and Hawaii) and the five other territories were derived strictly based
on the state's or territory's population compared to the national population for the full 1990-2019 time series.
Likewise, the emissions of HFCs other than the four listed above were distributed to all states and territories by
population. The emissions of HFC-32, HFC-125, HFC-134a, and HFC-143a were distributed to the six regions in the
same ratio as the best estimate of such distribution shown in Hu et al. (2017). Error bars from Hu et al. were not
applied or analyzed here. Because these data ended in 2014, the ratio from that year was used for 2015-2019 as
well. Likewise, ratios from 2008 (or 2010 for HFC-32) were used for 1990-2008 (or 2010). Once regional
distributions were made in this way, each region's emissions were distributed to the states within the region by
population.

3.4.2.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of HFC emissions as ODS substitutes was
calculated using a Monte Carlo analysis. As described further in Chapter 4, Section 4.24 of the national Inventory of
U.S. Greenhouse Gas Emissions and Sinks (EPA 2022), the uncertainty of national emissions was -3.4% to +14.0%
for a 95% confidence interval. State-level estimates are expected to have a higher uncertainty because of the use

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of population by state or territory during certain steps of the methodology, as described above, and from the use
of atmospheric inversions to apportion emissions of four HFCs by state.

This analysis did not calculate the specific activity data and emissions factor (and importantly for this category,
the reuse of chemicals not emitted) at each state and how the national activity data and emissions factors could
vary based on conditions other than population for the different end uses that comprise the sector. For this
reason, the division of emissions by sector (e.g., Refrigeration and Air Conditioning, Foams) cannot be provided at
the state level under this approach. The Hu et al. (2017) paper used in these state-level emissions estimates shows
that certain HFC emissions do not distribute evenly by population; hence, the steps of this methodology that use
population distributions introduce uncertainty. In addition to the uncertainty introduced from population
distributions, use of the Hu et al. work introduces uncertainty into the state-level estimates in two basic ways.

First, there is uncertainty in the regional emissions estimated from atmospheric inversions, as described in the
paper; such uncertainties would extrapolate through to the regional apportionment of HFC-32, HFC-125, HFC-
134a, and HFC-143a calculated during the state-level estimate approach. Secondly, the Hu et al. analysis is limited
in scope in both geography and time. Because their results cover only the contiguous 48 states (and the District of
Columbia), uncertainty from the population distribution described above exists outside that area and again when
distributing emissions to states within each of the six regions from the Hu et al. work. The time frame of the Hu et
al. analysis is 2008-2014, so extrapolation before and after that time frame introduces additional uncertainty.

3.4.2.4	Recalculations

No recalculations were applied to the state disaggregation method for this current report. Changes that
resulted from recalculations to the state-level estimates are the same as those presented in Section 4.24 of the
national Inventory (page 4-151), given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

3.4.2.5	Planned Improvements

This approach combining population and atmospheric measurement information can be improved in several
ways in future publications of this annual data. First, atmospherically derived emissions estimates similar to those
from Hu et al. (2017) for additional years, primarily after 2014, are anticipated. These data, when available, can
then be used to redistribute the annual emissions after 2014. Also, although emissions derived from atmospheric
measurements were not available before 2008, one could look at the trends, if any, in the data to see if a back-
year extrapolation of the data would give better results than applying the earliest year ratios back to 1990. The Hu
et al. (2017) data also include information for HFC-227ea and HFC-365mfc. While the emissions of these chemicals
are much lower than the four HFCs used here, the same approach could be used. It might also be appropriate to
use ODS information as a proxy for other HFCs. For instance, the paper found that emissions of CFC-11 and HCFC-
142b (and HFC-365mfc) showed regional distributions expected based on their primary use as a blowing agent for
insulating foam. These datasets could be used to distribute HFC-245fa and HCFO-1233zd(E) emissions, because
these two chemicals are also used primarily in foams, noting that such foam use in household refrigerator foam
and commercial refrigeration foam is unlikely to be affected by regional weather patterns.

Other improvements could be made by combining more bottom-up information to distribute national
emissions to states or to derive separate state-level emissions estimates. Data on the number of supermarkets, car
registrations, and air-conditioning use, or value added data in representative sectors, could all apply directly to
modeled end uses. Other data could be used as a proxy for end uses, such as commercial real estate square
footage as a proxy for commercial air-conditioning.

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3.4.2.6 References

California Air Resources Board. (April 2016). California's High Global Warming Potential Gases Emission Inventory
Emission Inventory Methodology and Technical Support Document. Available online at:
https://ww3.arb.ca.gov/cc/inventorv/slcp/doc/hfc inventory tsd 20160411.pdf

Hu, L. (2021). Personal communication.

Hu, L., et al. (2017). Considerable contribution of the Montreal Protocol to declining greenhouse gas emissions
from the United States, Geophys. Res. Lett., 44, 8075-8083, doi:10.1002/2017GL074388.

U.S. Census Bureau. (2022). International Database: World Population Estimates and Protections. Accessed January
4, 2022. Available online at: https://www.census.gov/programs-survevs/international-
programs/about/idb.html

U.S. Census Bureau. (2021). Table 1. Annual Estimates of the Resident Population for the United States, Regions,
States, the District of Columbia, and Puerto Rico: April 1, 2010 to July 1, 2019; April 1, 2020; and July 1, 2020
(NST-EST2020). Release Date: July 2021.

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

U.S. Census Bureau. (2011). Table 1. Intercensal Estimates of the Resident Population for the United States,

Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01). Release Date: September
2011.

U.S. Census Bureau. (2002). Table CO-EST2001-12-00—Time Series of Intercensal State Population Estimates: April
1,1990 to April 1, 2000. Release Date: April 11, 2002.

U.S. Department of Energy. (2016). Insulation. Available online at: http://energv.gov/energysaver/insulation

U.S. Energy Information Administration. (2021). Use of energy explained. Available online at:
https://www.eia.gov/energvexplained/use-of-energy/homes.php

U.S. Energy Information Administration. (2018a). Residential Energy Consumption Survey (RECS), Table HC7.7 Air
conditioning in homes in the Northeast and Midwest regions, 2015. Revised May 2018. Available online at:
https://www.eia.gOv/consumption/residential/data/2015/hc/php/hc7.7.php

U.S. Energy Information Administration. (2018b). Residential Energy Consumption Survey (RECS), Table HC7.8 Air
conditioning in homes in the South and West regions, 2015. Revised May 2018. Available online at:
https://www.eia.gOv/consumption/residential/data/2015/hc/php/hc7.8.php

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 4.24: Substitution of Ozone Depleting Substances (CRF Source Category 2F).
Available online at: https://www.epa.gov/system/files/documents/2022-04/us-ghg-inventorv-2022-chapter-4-
industrial-processes-and-product-use.pdf

3.4.3 Electrical Transmission and Distribution (NIR Section 4.25)

3.4.3.1 Background

The section describes methods used to estimate state-level SF6 emissions consistent with the national
Inventory. Fugitive emissions of SF6 can escape from gas-insulated substations and switchgear through seals,
especially from older equipment. The gas can also be released during equipment manufacturing, installation,
servicing, and disposal. These emissions occur in all 50 states and have also been estimated for two territories (i.e.,
Puerto Rico, and the Virgin Islands). Future updates to the national Inventory will also include Guam.

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3.4.3.2 Methods/Approach (Transmission and Distribution)

As discussed in Chapter 4, Section 4.25 (on page 4-141) of the national Inventory, the EPA used a combination
of IPCC Tier 2, Tier 3, and country-specific methods to estimate national SF6 emissions from Electrical Transmission
and Distribution.

The national Inventory uses facility-level data reported to the GHGRP or the SF6 Emission Reduction
Partnership for Electric Power Systems combined with information on total transmission miles in the US to develop
SFs emission estimates from electrical transmission and distribution. However, facilities, as defined in the GHGRP
or the Partnership, in the electrical transmission and distribution sector, often cross multiple states. Thus,

Approach 2 as described in the Introduction was used to estimate emissions from electrical transmission and
distribution. To disaggregate emissions by state for electrical transmission and distribution, the EPA used data
sources from the GHGRP and Homeland Infrastructure Foundation Level Data (HIFLD) (U.S. Department of
Homeland Security 2019 and 2020). For years prior to 2011 before GHGRP data were available, state-level SF6
emissions from electrical transmission and distribution (ET&D) equipment were determined by applying the
percentage of the total U.S. transmission miles for each state to the total U.S. emissions estimate for the entire
time series, modified to include additional state-level or facility-level information in the years it is available. For
2011 and later, the method was modified as described below to first allocate emissions to states as reported to the
GHGRP if the facility only reported one state or if the facility reported multiple states and there was a reasonable
match between the states and total transmission miles reported to the GHGRP and reported by HIFLD, before
applying to the above method to remaining transmission miles. See Table 3-19 for a summary of methods across
the time series.

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Table 3-19. Summary of Approaches to Disaggregate the National Inventory for Electrical Transmission and
Distribution Across Time Series

Time Series Range

Summary of Method

2011-2020	' For all GHGRP reporters that reported having transmission miles in only one state

(according to RY 2017-RY 2020 reports, excluding California), their facility-reported
emissions and transmission miles were allocated to that state. (Approach 1).

•	For GHGRP reporters that had transmission miles in multiple states and had a
reasonable match between the states and total transmission miles reported to the
GHGRP and reported by HIFLD, facility-reported emissions and transmission miles
were allocated to each state in which their facility lies by the percentage of their
transmission miles in each state according to HIFLD (Approach 2).

•	Emissions for California were obtained from the California Air Resources Board
California High GWP Gases Inventory for 2000-2020 (Approach 2).

•	The remaining emissions from the national Inventory were allocated to states by
calculating the percentage of remaining transmission miles by state (adjusted state
transmission miles/adjusted national transmission miles). These state percentages
were then applied to the adjusted national emissions estimate (national emissions
excluding GHGRP single-state emissions, emissions from matched multi-state
facilities and California emissions). State transmission miles were obtained from
HIFLD data (2020) and scaled using the transmission mile growth rate from UDI
datasets (Approach 2).

1990-2010	' Emissions from the national Inventory were allocated to states by calculating the

percentage of transmission miles by state. These state percentages were then
applied to the national emissions estimate. State transmission miles were obtained
from HIFLD data (2020) for all states. State percentages of the total transmission
were held constant at the 2020 percentage for all states. (Approach 2).

For disaggregating national ET&D estimates, state emissions (gas) were determined by multiplying the
percentage of the total U.S. transmission miles for each state by the total national estimate from the Inventory for
the entire time series. U.S. transmission miles were obtained from the EIA. Specifically, the EIA has published on
their U.S. Energy Mapping System web map30 the electric transmission lines data from Homeland Infrastructure
Foundation—Level Data (HIFLD) (Department of Homeland Security 2019), which was last updated June 2020. The
dataset includes mileage of transmission lines operated at relatively high voltages varying from 3 kV up to 765 kV.
Geographic coverage includes the United States and the U.S. territories.31

The fraction of transmission miles greater than 34.5 kV in each state was calculated using geographic
information system (GIS) mapping. Figure 3-1 displays the GIS mapping of the transmission lines by state.
Geographic software that identifies lines within state boundaries was used for the disaggregation because it
removed the task of identifying and addressing changes to ownership of service territories as part of this
methodology.

30	https://www.eia.eov/State/maps.php.

31	Transmission miles greater than 34.5 kv in 2020 totaled 734,291 miles based on the HIFLD dataset and 749,847 miles based
on the UDI dataset and GHGRP-reported transmission mileage. Despite the discrepancy, HIFLD data provide the closest match
of total miles compared to other datasets previously examined, which gives us reasonable confidence on using the percentage
breakdown by state that can be obtained using GIS mapping.

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Source: Department of Homeland Security 2019

As described below, this method was modified to include additional state-level or facility-level information in
the years for which it was available.

For 2011-2018, CARB provides emissions of SFe from California's electric power systems as reported through
the Regulation for Reducing Sulfur Hexafluoride Emissions from Gas Insulated Switchgear for 2011-2018 (CARB
2020). The EPA concluded that these reported values were a more accurate representation of state-level emissions
from California. To estimate emissions for all other states and territories, the EPA removed California from the
total transmission miles and adjusted the percentage breakdown of transmission miles by state accordingly. State
and territory emissions were then disaggregated using the revised percentages.

For 2011-2020, for all GHGRP reporters that reported having transmission miles in only one state (according
to RY 2017-RY 2020 reports), their facility-reported emissions and transmission miles were allocated to that state.
Approximately 62% of reporting facilities had transmission miles in only one state during RY 2017-RY 2020. On
average, these facilities constituted approximately 20% of the national emissions between 2011 and 2020.
Emissions from GHGRP reporters that reported having transmission miles in multiple states were allocated to the
states reported by percentage of transmission miles in each state according to HIFLD if the GHGRP facility could be
cross-walked to the HIFLD data by state and total transmission miles. Approximately 9% of reporting facilities had
transmission miles in multiple states during RY 2017-RY 2020 that were successfully cross-walked and matched to
the HIFLD data. On average, these facilities constituted an additional 24% of the national emissions between RY
2017 and RY 2020.

For states where this scenario applied, the GHGRP-reported transmission miles for these facilities were
subtracted from the state transmission mile total, as determined by the HIFLD data, to arrive at an adjusted total
of state transmission miles.32 The sum of GHGRP-reported transmission miles in only one state and the cross-

32 California transmission miles were removed from the HIFLD transmission miles because the state-re ported emissions were
used in lieu of this approach. Therefore, state percentages were calculated out of the total national transmission miles minus
California.

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walked multi-state facilities was also deducted from the total national transmission miles. Because the HIFLD data
represent 2020 transmission miles, transmission mileage was scaled down using UDI's transmission mile growth
rate for 2011-2020 (UDI 2017, UDI 2013, UDI 2010).

Total facility-reported emissions for cases where a facility's transmission miles are reported in only one state
and for multi-state facilities that were cross-walked with the HIFLD data were summed and subtracted from the
national emissions estimate.33 To allocate the remaining national emissions by state, the percentage transmission
miles by state was calculated (adjusted state transmission miles/adjusted national transmission miles). These state
percentages were then applied to the adjusted national emissions estimate (national emissions excluding GHGRP-
only one state emissions and California emissions).

Finally, state-level emissions for GHGRP-reported facilities that reported as being located in only one state
(where applicable) were summed with the calculated state-level emissions based on the calculation above to arrive
at a total state emissions estimate for electric power systems.

The approach taken to disaggregate national emissions enables the EPA to use facility-level emissions data
from the reporting program starting in 2011. While this approach has limitations, it also sets up the emissions
estimations for future improvements as more data become available (e.g., additional facility-level information on
state locations of transmission lines obtained through research or additional reporting would facilitate greater use
of GHGRP data). Additionally, using reported data for California better represents impacts of regulations on
emissions in that state (e.g., California). Similarly, using data reported to the EPA can help account for any state-
influenced actions (e.g., climate action planning at state and local levels).

Total emissions from 1990-1999 were disaggregated using the percentage breakdown of transmission miles
by state from the HIFLD data.

3.4.3.3 Methods/Approach (Manufacture of Electrical Equipment)

Emissions were reported by facility for 2011-2020. The EPA determined state-level emissions using Approach
1 based on reported facility locations, which included Connecticut, Illinois, Mississippi, and Pennsylvania. In the
absence of additional industry information, the EPA used Approach 2 and assumed that all non-reporting facilities
are located in the same states as reporting facilities. The EPA estimates that GHGRP reporters represent about 50%
of all original equipment manufacturers (OEM) emissions and for state-level estimates, applied the national scale-
up factor at the state level.

For years prior to when GHGRP data were reported, using Approach 2, an average percentage state
breakdown across the reporting time series (RY 2011-2020) was applied to emissions in each year to calculate
state emissions from OEMs before 2011. The methods used are summarized in Table 3-20.

Additional research is required to understand 1) if the EPA's assumption about the portion of OEM emissions
covered is accurate and 2) in what states these non-reporting emissions occur. Additionally, further research is
necessary to determine whether the reporting facilities were in operation in all years before 2011.

Table 3-20. Summary of Approaches to Disaggregate the National Inventory for Manufacture of Electrical
Equipment Across Time Series

Time Series Range	Summary of Method

2011-2020	' Emissions reported to the GHGRP were allocated based on reported facility

locations (Approach 1). Non-reporters were assumed to be located in the same
states with emissions allocated at the same state percentage of the total non-
reporting emissions as for the emissions reported to the GHGRP (Approach 2).

33 The national emissions estimate was adjusted by deducting California's CARB-reported emissions.

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1990-2010	' Emissions from the national Inventory were allocated to states by applying the

average percentage state breakdown across the GHGRP reporting years (2011-
2020) to national estimate for each year between 1990-2010 in the Inventory
(Approach 2).

3.4.3.4	Uncertainty

The overall uncertainty associated with the national Inventory of SF6 emissions from electric transmission and
distribution source category were calculated using the 2019 Refinement to the 2006IPCC Guidelines. Partner
reported emissions uncertainty was estimated to be -/+ 10% and GHGRP reporter emissions uncertainty was
estimated to be -/+ 20%. As described further in Chapter 4 of the national Inventory (EPA 2022), levels of
uncertainty in the national estimates in 2020 of the source category were -16%/+18%.

State-level estimates are expected to have a higher uncertainty across the time series due to the use of HIFLD
transmission mileage data to apportion the emissions of facilities that either do not report to the GHGRP or that
operate in multiple states. This allocation method introduces additional uncertainty due to the potential
inaccuracy of transmission mile locations and the variability of emission rates per transmission mile across
reporting facilities. As with the national Inventory, the state-level uncertainty estimates for this category may
change as the understanding of the uncertainty of estimates and underlying datasets and methodologies improve.

3.4.3.5	Recalculations

No recalculations were applied to the state disaggregation method for this current report. Changes that
resulted from recalculations to the state-level estimates are the same as those presented in Section 4.23 of the
national Inventory (page 4-135), given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

3.4.3.6	Planned Improvements

The EPA plans to incorporate facility-specific reported data from the SF6 Emission Reduction Partnership into
the inventory for 1999-2010 based on historical emissions estimates collected under the EPA's SF6 Emission
Reduction Partnership for Electric Power Systems. The EPA will consider smoothing emissions for states where
reported emissions cause an unexpected trend in overall state emissions of SF6. Improvements will be
incorporated as more data becomes available (e.g., additional facility-level information on state locations of
transmission lines obtained through research or additional reporting would facilitate greater use of GHGRP and/or
Partnership data). Additional research into regional or state-level trends will also be conducted to refine the
estimates where possible. In line with planned improvements to the national Inventory, the EPA plans to
incorporate estimates for additional U.S. territories, such as Guam.

Additional research into state distribution of OEMs will also be conducted to 1) confirm or revise the 50%
assumption of non-reported emissions and 2) understand the states in which these emissions take place for non-
reporters.

3.4.3.7	References

California Air Resources Board. (2007). Sulfur Hexafluoride (SFs) Emission Reductions from Gas Insulated
Switchgear Chapter 10, sections 95350 to 95359, title 17.

California Air Resources Board. (2020). California High GWP Gases Inventory for 2000-2019—by IPCC Category.
Available at https://ww3.arb.ca.gov/cc/inventorv/data/tables/ghg inventory ipcc sum 2000-18.pdf

UDI. (2017) 2017 UDI Directory of Electric Power Producers and Distributors, 125th Edition, Platts.

UDI. (2013) 2013 UDI Directory of Electric Power Producers and Distributors,121st Edition, Platts.

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UDI. (2010) 2010 UDI Directory of Electric Power Producers and Distributors, 118th Edition, Platts.

UDI. (2007) 2007 UDI Directory of Electric Power Producers and Distributors, 115th Edition, Platts.

UDI. (2004) 2004 UDI Directory of Electric Power Producers and Distributors, 112th Edition, Platts.

UDI. (2001) 2001 UDI Directory of Electric Power Producers and Distributors, 109th Edition, Platts.

U.S. Department of Homeland Security. (2019). HIFLD (2019) Federal Energy Regulatory Commission. Homeland
Infrastructure Foundation-Level Data (HIFLD). 2019. Accessed March 2021. Available online at: https://hifld-
geoplatform.opendata.arcgis.com/datasets/electric-power-transmission-lines.

U.S. Department of Homeland Security (2020). Homeland Infrastructure Foundation-Level Data (HIFLD). 2020.
Accessed October 2021. Available online at: https://hifld-geoplatform.opendata.arcgis.com/datasets/electric-
power-transmission-lines/explore?showTable=true.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-033), Chapter 4.25: Electrical Transmission and Distribution (CRF Source Category 2G1).
Available online at: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-main-
text.pdf

3.4.4 Nitrous Oxide from Product Uses (NIR Section 4.26)

3.4.4.1	Background

N2O is primarily used in carrier gases with oxygen to administer more potent inhalation anesthetics for general
anesthesia, and as an anesthetic in various dental and veterinary applications. The second main use of N2O is as a
propellant in pressure and aerosol products, the largest application being pressure-packaged whipped cream.
Smaller quantities of N2O also are used in the following applications: oxidizing agent and etchant used in
semiconductor manufacturing, oxidizing agent used with acetylene in atomic absorption spectrometry, production
of sodium azide for use in airbags, fuel oxidant in auto racing, and oxidizing agent in blowtorches used by jewelers
and others. The amount of N2O that is actually emitted depends on the specific product use or application. Only
the medical/dental and food propellant subcategories were assumed to release emissions into the atmosphere
that are not captured under another source category; therefore, these subcategories were the only usage
subcategories with emissions rates. N2O product use emissions from the national Inventory were disaggregated
across all 50 states, the District of Columbia, and U.S. territories in 2020.

3.4.4.2	Methods/Approach

The state-level methodology for N2O emissions from product usage is to allocate emissions to all applicable
U.S. states and territories using population statistics as a surrogate for state-specific N2O usage, consistent with
Approach 2 as defined in the Introduction chapter. See Appendix I, Table 1-1 in the "N20 Use" Tab, for more details
on the N2O product use categories and their assumed emissions factors and Appendix G, Table G-l in the
"Population Data" Tab, for details on the population data used. The national Inventory methodology was adapted
to calculate state-level GHG emissions of N2O to ensure consistency with national estimates. National estimates
were used to disaggregate emissions by state because of limitations in the availability of state-specific data for the
time series. Total emissions for each state are the sum of emissions from N2O product use.

State-level emissions of N2O usage for medicine/dental anesthesia, sodium azide production, food processing
propellant and aerosols, and other applications (may include fuel oxidant in auto racing, oxidizing agent in
blowtorches, etc.) were calculated using the same methodology in the national Inventory to calculate national
emissions (EPA 2022). Data on the usage of N2O by state, however, are not available. To calculate N2O product
usage by state, national N2O usage and emissions were distributed among the 50 states, the District of Columbia,

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and U.S. territories (including Puerto Rico, American Samoa, Guam, Northern Mariana Islands, and the U.S. Virgin
Islands) using U.S. population statistics as a surrogate for state-specific N2O usage (U.S. Census Bureau 2002, 2011,
2021, 2022; Instituto de Estadisticas de Puerto Rico 2021). For each year in the 1990-2020 time series, the fraction
of the total U.S. population in each state, as well as the District of Columbia and U.S. territories, was calculated by
dividing the state population by the total U.S. population.

To estimate N2O emissions for each year by state, total national Inventory N2O production was multiplied by
the share of national usage and emissions rate for each respective application and then multiplied by each state's
fraction of the total population for that year. The calculated emissions by application and by state were then
summed by state. Use of state populations to calculate the N2O use and emissions by state assumed that N2O use
is consistent across all states.

3.4.4.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of N2O from N2O product use was
calculated using the 2006 IPCC Guidelines Approach 2 methodology for uncertainty (IPCC 2006). As described
further in Chapter 4 and Annex 7 of the national Inventory (EPA 2022), levels of uncertainty in the national
estimates in 2020 were -24%/+24% for N2O.

State-level estimates are expected to have a higher uncertainty because the national emissions estimates
were apportioned to each state based solely on state population for some subcategories. This assumption was
required because of a general lack of more granular state-level data. Use of state population for medical/dental
anesthesia and for food propellant in the state-level estimates may have lower uncertainty because these uses
tend to be related to population. Use of state population for other uses (e.g., fuel oxidant in auto racing, oxidizing
agent in blowtorches) introduces higher uncertainty because state-level activities are not known and less likely to
be related to population. This allocation method introduces additional uncertainty due to limited data on the
quantity of N2O used by state or nationally for the full time series. The sources of uncertainty for this category are
also consistent over time because the same surrogate data are applied across the entire time series.

3.4.4.4	Recalculations

Recalculations were performed for the 1990 through 2019 time series to reflect the addition of population
data for four U.S. territories not previously included: American Samoa, Guam, Northern Mariana Islands, and U.S.
Virgin Islands. The addition of these territories had a negligible impact on the emissions estimated for the 50
states, the District of Columbia, and Puerto Rico due to their small population sizes.

Additional recalculations were performed for the 2010 through 2019 time series as updated population data
were made available from the U.S. Census Bureau for the time series. The updated population data had a
negligible impact on the emissions estimated for the 50 states, the District of Columbia, and Puerto Rico due to the
low emissions estimated for each state or territory for the sector.

3.4.4.5	Planned Improvements

Data gaps include the actual usage of N2O from products by state for each application for the entire time
series. Research is also needed to better characterize each application's N2O usage.

3.4.4.6	References

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

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Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Census Bureau. (2022). International Database: World Population Estimates and Projections. Accessed January
4, 2022. Available online at: https://www.census.gov/programs-survevs/international-
programs/about/idb.html

U.S. Census Bureau, Population Division. (2002). Table CO-EST2001-12-00—Time Series of Intercensal State
Population Estimates: April 1,1990 to April 1, 2000, Release Date: April 11, 2002.

U.S. Census Bureau, Population Division. (2011). Table 1. Intercensal Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01), Release Date:
September 2011.

U.S. Census Bureau, Population Division. (2021). Table 1. Annual Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2010 to July 1, 2019; April 1, 2020; and July 1, 2020
(NST-EST2020), Release Date: July 2021.

U.S. Census Bureau. (2022). International Database: World Population Estimates and Projections. Population of US
territories. Accessed January 2022. Available online at: https://www.census.gov/programs-
survevs/international-programs/about/idb.html

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020.
Office of Air and Radiation, Office of Atmospheric Programs, U.S. Environmental Protection Agency,
Washington, DC. Available online at: https://www.epa.gov/ghgemissions/inventorv-us-greenhouse-gas-
emissions-and-sinks

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4 Agriculture (NIR Chapter 5)

For this methodology report, the Agriculture chapter consists of two subsectors: livestock management and
other agriculture activities. More information on national-level emissions and methods is available in Chapter 5 of
the national Inventory. Table 4-1 summarizes the different approaches used to estimate state-level agriculture
emissions. The sections below provide more detail on each category.

Table 4-1. Overview of Approaches for Estimating State-Level Agriculture Sector GHG Emissions

Category

Gas

Approach

Completeness

Enteric Fermentation

CH4

Approach 1

Includes emissions from all states.1

Manure Management

cm, n2o

Approach 1

Includes emissions from all states.1

Agricultural Soil

l\l2o

Hybrid (see Section 4.2.2.2,

Includes emissions from all states,

Management



Methods/Approach)

Washington D.C, and territories,1 but
some components of Alaska and
Hawaii were not estimated.

Rice Cultivation

cm

Hybrid:

•	1990-2015: Approach 1

•	2016-2020: Approach 2

Includes emissions from all 13 states
cultivating rice.1

Liming

CO2

Hybrid:

•	1990-2018: Approach 1

•	2019-2020: Approach 2

Includes emissions from all states for
which the USGS (through Minerals
Yearbook and Mineral Industry
Survey) reports limestone and
dolomite consumption for agriculture
in current and historical yearbooks
and surveys.1

Urea

CO2

Approach 1

Includes emissions from all states and
territories1 (i.e., Puerto Rico) were
estimated.

Field Burning of

cm, n2o

Hybrid:

Includes emissions from all states

Agricultural Residues



•	1990-2014: Approach 1

•	2015-2020: Approach 2

except Alaska and Hawaii.1

1 Emissions are likely occurring in other U.S. territories; however, due to a lack of available data and the nature of this category,
this analysis includes emissions for only the territories indicated. Territories not listed are not estimated. See planned
improvements.

4.1 Livestock Management

This section presents the methodology applied to estimate the livestock management emissions, which
consist of the following sources:

•	Enteric fermentation (CH4)

•	Manure management (CH4, N2O)

4.1.1 Enteric Fermentation (NIR Section 5.1)

4.1.1.1 Background

Methane is produced as part of normal digestive processes in animals. During digestion, microbes resident in
an animal's digestive system ferment food consumed by the animal. This microbial fermentation process, referred
to as Enteric Fermentation, produces Cm as a by-product, which can be exhaled or eructated by the animal. The

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amount of CFUproduced and emitted by an individual animal depends primarily upon the animal's digestive
system, and the amount and type of feed it consumes.

4.1.1.2 Methods/Approach

The EPA compiles state-level CH4 emissions from enteric fermentation using the same methods applied in the
national Inventory available online at: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-
2022-chapter-5-agriculture.pdf. The methods applied in the national Inventory are summarized below in Table 4-2.
Estimates are available for all 50 States.

Table 4-2. Approaches to Estimate Enteric Fermentation Methane Across Time Series

Time Series Range	Method

1990-2020	' Cattle: IPCC Tier 2 (Cattle Enteric Fermentation Model (CEFM) model)

• Noncattle: IPCC Tier 1 (population * default emissions factor)

Please refer to the national Inventory Section 5.1 and Annex 3.10 on enteric fermentation for details on the
methods applied to estimate state-level emissions for the years 1990-2020 (EPA 2022a; EPA 2022b).

•	For cattle, the CEFM was used to estimate CFU emissions using the IPCC Tier 2 method. The CEFM utilizes
the IPCC Tier 2 method and also other analyses of cattle population, feeding practices, diet data and
production characteristics.

•	For noncattle animals, USDA state population estimates (from USDA QuickStats and the U.S. Census of
Agriculture) were multiplied by the corresponding default IPCC emissions factors (IPCC 2006).

4.1.1.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CFU from enteric fermentation was
calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described further in Chapter 5
of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022a), levels of uncertainty in the
national estimates in 2020 were CFU (-11/+18%). State-level estimates have a higher uncertainty due to
apportioning the national or default emission estimates to each state. This approach does not address state-level
differences in uncertainty when applying regional diet data or factors. It is important to note that beef and dairy
cattle diets can vary significantly even between states that are in similar regions because of the wide variety of
forage types being grown on range and pastureland. Additionally, producers often develop unique feed for their
livestock based on the availability of specific feed inputs in their area. Regionally derived data were applied at the
state level because state-level data were limited or unavailable for many parameters. For more details on national-
level uncertainty, see the Uncertainty discussion in Section 5.1 of the national Inventory (see link included above).

4.1.1.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 5.1 of the national Inventory (page 5-9), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well. In particular, in the previous inventory
cycle, 1990 to 2017 estimates were retained and 2018 and 2019 were based on a simplified approach; however,
for this cycle, the cattle enteric fermentation model (CEFM) was used for cattle for all years.

4.1.1.5	Planned Improvements

Planned improvements to the state-level estimates are the same as those presented in Section 5.1 of the
national Inventory (page 5-10), given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well. In particular, state-level livestock diet data would be
of value for improving estimates of enteric fermentation.

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4.1.1.6 References

IPCC (2006). Emissions from Livestock and Manure Management, Volume 4, Chapter 10, in 2006 IPCC Guidelines
for National Greenhouse Gas Inventories. The National Greenhouse Gas Inventories Programme, The
Intergovernmental Panel on Climate Change. H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe
(eds.). Hayama, Kanagawa, Japan. Available online at: https://www.ipcc-
nggip.iges.or.jp/public/2006gl/pdf/4 Volume4/V4 10 ChlO Livestock.pdf

U.S. Environmental Protection Agency. (2022a). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 5: Agriculture. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf

U.S. Environmental Protection Agency. (2022b). Annexes to the Inventory of U.S. GHG Emissions and Sinks: Annex
3.10, Methodology for Estimating Cm Emissions from Enteric Fermentation (EPA 430-R-22-003). Washington,
DC. Available online at: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-
annexes.pdf

4.1.2 Manure Management (NIR Section 5.2)

4.1.2.1	Background

The treatment, storage, and transportation of livestock manure can produce anthropogenic CFU and N2O
emissions. Methane is produced by the anaerobic decomposition of manure and nitrous oxide is produced from
direct and indirect pathways through the processes of nitrification and denitrification, volatilization, and runoff
and leaching. In addition, there are many underlying factors that can affect these resulting emissions from Manure
Management. For CH4, the type of manure management system, ambient temperature, moisture, and residency
(storage) time of the manure affect bacteria growth and therefore subsequent emissions. For N2O, the
composition of the manure (manure includes both feces and urine), the type of bacteria involved in the process,
and the amount of oxygen and liquid in the manure system affect the resulting emissions.

4.1.2.2	Methods/Approach

The EPA compiles state-level emissions from manure management using the same methods applied in the
national Inventory as summarized in Table 4-3.

Table 4-3. Approaches to Estimate Manure Management Methane and Nitrous Oxide Across Time Series

Time Series Range

Method

1990-2020

• Combination of IPCC Tier 1 and 2 approaches as described in the national
Inventory

For 1990-2020, please refer to the national Inventory Chapter 5, Section 5.2 and Annex 3.11, which provides
additional detail on the methods to estimate state-level manure management emissions (EPA 2022a; EPA 2022b).
As noted in that section, the basic approach applies a combination of IPCC Tier 1 and Tier 2 methodologies. The
EPA applies Tier 1 default N2O emissions factors and methane conversion factors (MCF) for dry systems from the
IPCC (2006), U.S.-specific MCFs for liquid systems, and U.S.-specific values for the volatile solids production rate
and the nitrogen excretion rate for some animal types, including cattle values from the CEFM (see Enteric
Fermentation).

4.1.2.3 Uncertainty

The overall uncertainty associated with the 2020 national estimates of CH4 and N2O from Manure
Management were calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described
further in Chapter 5 of the national Inventory (EPA 2022a), levels of uncertainty in the national estimates in 2020
were CFU (-18/+20%) and N2O (-16/+24%). State-level estimates have a higher uncertainty due to apportioning

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the national or default emission estimates to each state. This approach does not address state-level differences in
uncertainty when applying regional waste management system distributions or factors. These assumptions were
applied because state-level data is limited or unavailable for many parameters. For more details on national-level
uncertainty see the Uncertainty discussion in Section 5.2 of the national Inventory (EPA 2022a).

4.1.2.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 5.2 of the national Inventory (page 5-19), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well. In particular, the EPA developed an
updated methodology to determine animal populations for states with previously undisclosed animal population
data.

4.1.2.5	Planned Improvements

Planned improvements to the state-level estimates are the same as those presented in Chapter 5, Section 5.2,
of the national Inventory, given that improvements in the national Inventory will lead directly to improvements in
the quality of state-level estimates as well.

4.1.2.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2022a). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 5: Agriculture. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf

U.S. Environmental Protection Agency. (2022b). Annexes to the Inventory of U.S. GHG Emissions and Sinks: Annex
3.11, Methodology for Estimating Cm and N2O Emissions from Manure Management (EPA 430-R-22-003).
Washington, DC. Available online at: https://www.epa.gov/system/files/documents/2022-04/us-ghg-
inventory-2022-annexes.pdf

4.2 Other (Agriculture)

This section presents the methodology applied to estimate the other agricultural activity emissions, which
consist of the following source categories:

•	Rice cultivation (CH4)

•	Agricultural soil management (N2O)

•	Liming (CO2)

•	Urea fertilization (CO2)

•	Field burning of agricultural residues (Cm, N2O)

4.2.1 Rice Cultivation (NIR Section 5.3)

4.2.1.1 Background

Most of the world's rice is grown on flooded fields that create anaerobic conditions leading to CFU production
through a process known as methanogenesis. Approximately 60% to 90% of the CH4 produced by methanogenic
bacteria in flooded rice fields is oxidized in the soil and converted to CO2 by methanotrophic bacteria. The
remainder is emitted to the atmosphere (or transported as dissolved CH4 into groundwater and waterways.

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Methane is transported to the atmosphere primarily through the rice plants, but some CFU also escapes via
ebullition (i.e., bubbling through the water) and to a much lesser extent by diffusion through the water.

4.2.1.2	Methods/Approach

The EPA compiles state-level CH4 emissions from Rice Cultivation using the same methods applied in the
national Inventory. Rice is currently cultivated in 13 states: Arkansas, California, Florida, Illinois, Kentucky,
Louisiana, Minnesota, Mississippi, Missouri, New York, South Carolina, Tennessee, and Texas. This is described in
Chapter 5, Section 3, of the national Inventory, available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf.
Additional information on the methodologies and data is also provided in Annex 3.12.

The most recent national Inventory includes State-level emissions for the 13 states mentioned above for the
years 1990-2015, which were used for this report, Approach 1. See Appendix E for time series information
underlying the estimates. Within the national Inventory, the EPA does not currently estimate State-level emissions
from rice cultivation for the years 2016-2020 because the NRI data are not available for the 2016-2019 time
period, so it is not possible to develop state-level estimates for those years using the same approach. The national-
level emissions for 2016-2020 are estimated using a surrogate data method. For this report, the national totals for
2016-2020 were disaggregated to the state level in a two-step process, Approach 2. First, the average proportion
of the total national emissions was computed for each state from 2013-2015, which are the last 3 years for which
state-level emissions have been estimated. Second, the state-level proportions were multiplied by the total
national emissions to approximate the amount of emissions occurring in each state from 2016-2020.

4.2.1.3	Uncertainty

The overall uncertainty associated with national estimates of CFU from rice cultivation was calculated using
the IPCC Approach 2 (i.e., Monte Carlo simulation). As described in Chapter 5 of the national Inventory of U.S.
Greenhouse Gas Emissions and Sinks (EPA 2022), sources of uncertainty include incomplete information on
management practices, uncertainties in model structure (i.e., algorithms and parameterization), emissions factors,
and variance associated with the NRI sample. Levels of uncertainty in the national CFU rice cultivation estimates in
2020 were -88/+88% for the Tier 1 method and -48/+48% for the Tier 3 method, with a combined uncertainty of
-75/+75%. For the years 2016-2020, in which the national Inventory did not estimate state emissions but those
estimates were developed for this report, uncertainty will be greater.

4.2.1.4	Recalculations

No recalculations were applied for this current report, consistent with the national Inventory (see Section 5.3,
page 5-27).

4.2.1.5	Planned Improvements

Planned improvements to the state-level estimates are anticipated to be the same as those presented in
Section 5.3 of the national Inventory, given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

4.2.1.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 5: Agriculture. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf

Full citations of references included in Chapter 5.3 (Rice Cultivation) and Annex 3.12 of the national Inventory
are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-

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10-references.pdf and https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-annex-3-
additional-source-or-sink-categories-part-b.pdf.

4.2.2 Agricultural Soil Management (NIR Section 5.4)

4.2.2.1	Background

Nitrous oxide (N2O) is naturally produced in soils through the microbial processes of nitrification and
denitrification that is driven by the availability of mineral nitrogen (N). Mineral N is made available in soils through
decomposition of soil organic matter and plant litter, asymbiotic fixation of N from the atmosphere, and
agricultural management practices, which are discussed below.

Several agricultural activities increase mineral N availability in soils that lead to direct N2O emissions at the site
of a management activity. These activities include synthetic N fertilization; application of managed livestock
manure; application of other organic materials such as biosolids (i.e., treated sewage sludge); deposition of
manure on soils by domesticated animals in pastures, range, and paddocks (PRP) (i.e., unmanaged manure);
retention of crop residues (N-fixing legumes and non-legume crops and forages); and drainage of organic soils (i.e.,
Histosols) (IPCC 2006). Additionally, Agricultural Soil Management activities, including irrigation, drainage, tillage
practices, cover crops, and fallowing of land, can influence N mineralization from soil organic matter and plant
litter in addition to levels of asymbiotic N fixation.

Indirect emissions of N2O occur when N is transported from a site and is subsequently converted to N2O; there
are two pathways for indirect emissions: (1) volatilization and subsequent atmospheric deposition of
applied/mineralized N and (2) surface runoff and leaching of applied/mineralized N into groundwater and surface
water.

4.2.2.2	Methods/Approach

The EPA compiles state-level N2O emissions from Agricultural Soil Management using the same methods
applied in the national Inventory. Please see the methodologies described in Chapter 5, Section 5.4 (pages 5-27
through 5-45), of the national Inventory, available online here:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf.

For this report, a hybrid of Approach 1 and 2 was applied in developing state-level estimates. Estimates are
available for all 50 states and the District of Columbia; however, some components of this category are not
estimated for Alaska and Hawaii, as described in the national Inventory. The EPA currently estimates N2O emissions
from mineral fertilizer and PRP N additions in Alaska and Hawaii, and drained organic soils in Hawaii. For the state-
level estimates, the EPA extracted soil N2O emissions data that were compiled at the state level for drained organic
soils across the entire time series; for crop residue N for 1990-2018; and for synthetic fertilizer, managed manure
N, PRP manure N, and mineralization of soil organic matter from 1990-2015. The remaining years in the time
series for these N sources were only estimated at the national scale using a surrogate data method. A two-step
process was used to approximate the state-level emissions for the remaining years. First, the average proportion of
the total national emissions was computed for each state from the last 3 years in the time series with state-level
data (e.g., 2013-2015 for synthetic fertilizer). Second, the state-level proportions were multiplied by the total
national emissions to approximate the amount of emissions occurring in each state for the years (through 2020)
with only national-level estimates in the national Inventory. Soil N2O emissions for additions of biosolid N and
other organic amendment N to soils are only estimated at the national scale for the entire time series. For these
two sources of N, soil N2O emissions were disaggregated to the state level based on the proportion of the U.S.
population occurring in each state.

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Additional information on methodologies and data is also provided in Annex 3.12, available online here:
https://www.epa.gov/system/files/documents/2022-04/us-ghg-inventorv-2022-annex-3-additional-source-or-sink-
categories-part-b.pdf.

4.2.2.3	Uncertainty

The overall uncertainty associated with national estimates of N2O from agricultural soil management is
described in Chapter 5 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022).
Uncertainty is estimated for each of the following five components of N2O emissions from agricultural soil
management: (1) direct emissions simulated by DayCent, (2) the components of indirect emissions (N volatilized
and leached or runoff) simulated by DayCent, (3) direct emissions estimated with the IPCC Tier 1 method, (4) the
components of indirect emissions (N volatilized and leached or runoff) estimated with the IPCC (2006) Tier 1
method, and (5) indirect emissions estimated with the IPCC Tier 1 method.

Levels of uncertainty in the national N2O agricultural soil management estimates in 2020 were direct N2O
(-33/+33%) and indirect l\l20 (-67/+145%).

4.2.2.4	Recalculations

No recalculations were applied to the state disaggregation method for this current report. Changes that
resulted from recalculations to the state-level estimates are the same as those presented in Section 5.4 of the
national Inventory (page 5-45), given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

4.2.2.5	Planned Improvements

Planned improvements to the state-level estimates are anticipated to be the same as those presented in
Section 5.4 of the national Inventory, given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

4.2.2.6	References

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. The National Greenhouse Gas Inventories Programme, The Intergovernmental Panel on Climate
Change. [H.S. Eggleston, L Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.)]. Hayama, Kanagawa, Japan.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 5: Agriculture. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf

Full citations of references included in Chapter 5.4 (Agricultural Soil Management) and Annex 3.12 of the
national Inventory are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-chapter-10-references.pdf and https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventory-2022-annex-3-additional-source-or-sink-categories-part-b.pdf f.

4.2.3 Liming (NIR Section 5.5)

4.2.3.1 Background

Crushed limestone (CaCOs) and dolomite (CaMg(CC>3)2) are added to soils by land managers to increase soil pH
(i.e., to reduce acidification). Carbon dioxide emissions occur as these compounds react with hydrogen ions in
soils. The rate of degradation of applied limestone and dolomite depends on the soil conditions, soil type, climate
regime, and whether limestone or dolomite is applied. Emissions from limestone and dolomite that are used in
industrial processes (e.g., cement production, glass production, etc.) are reported under the IPPU chapter.

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4.2.3.2	Methods/Approach

The EPA compiles state-level CO2 emissions from Liming using the same methods applied in the national
Inventory. The national method is a Tier 2 approach based on the amount of limestone and dolomite applied to
agricultural soils, multiplied by a country-specific emissions factor. This is described in Chapter 5, Section 5.5
(pages 5-46 through 5-49), of the national Inventory, available online here:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf.

The current national Inventory includes state-level emissions for the years 1990-2018. See Appendix E for time
series information underlying the estimates. It did not include state-level emissions from liming for the years
2019-2020 because state-level activity data were not available34. For this report, a hybrid Approach 1 and
Approach 2 was used. The national estimates for 2019-2020, which were estimated using a linear extrapolation
method, is disaggregated to the state level based on the proportion of total CO2 emissions from carbonate lime
application occurring in each state for 2018. Estimates are currently available for states other than Alaska, Arizona,
Colorado, Delaware, Hawaii, Louisiana, Maryland, and New Hampshire, because USGS data did not indicate
consumption of crushed limestone and dolomite; however, the District of Columbia is currently estimated.

4.2.3.3	Uncertainty

The overall uncertainty associated with national estimates of CO2 from liming is described in Chapter 5 of the
national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022). A Monte Carlo uncertainty analysis was
applied. Uncertainty analysis was performed on the amount of limestone and dolomite applied to soils, the
emissions factors included the fraction of lime dissolved by nitric acid versus the fraction that reacts with carbonic
acid, and the portion of bicarbonate that leaches through the soil and is transported to the ocean. Uncertainty
regarding the time associated with leaching and transport is not addressed in the national Inventory uncertainty
analysis. The overall level of uncertainty in the national CO2 liming estimates in 2020 was -lll/+97%.

4.2.3.4	Recalculations

No recalculations were applied to the state disaggregation method for this current report. Changes that
resulted from recalculations to the state-level estimates are the same as those presented in Section 5.5 of the
national Inventory (page 5-49), given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

4.2.3.5	Planned Improvements

Planned improvements to the state-level estimates are anticipated to be the same as those presented in
Section 5.5 of the national Inventory, given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

4.2.3.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 5: Agriculture. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf

Full citations of references included in Chapter 5.5 (Liming) of the national Inventory are available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-references.pdf.

34 Also, state totals do not sum to national totals for some years of the time series (i.e., 1999, 2002, 2005-2009, 2017) due to
some state level data being withheld by USGS to avoid disclosing confidential business information.

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4.2.4	Urea Fertilization (NIR Section 5.6)

4.2.4.1	Background

The use of urea (COfNHzh) as a fertilizer leads to greenhouse gas emissions through the release of CO2 that
was fixed during the production of urea. In the presence of water and urease enzymes, urea that is applied to soils
as fertilizer is converted into ammonium (NH4+), hydroxyl ion (OH), and bicarbonate (HCO3-). The bicarbonate then
evolves into CO2 and water.

4.2.4.2	Methods/Approach

The EPA compiles state-level CO2 emissions from Urea Fertilization using the same IPCC Tier 1 methods
applied in the national Inventory, Approach 1. With this approach, state-level fertilizer sales data are multiplied by
the default IPCC emissions factor. See Appendix E for time-series information underlying the estimates. This is
described in Chapter 5, Section 5.6 (pages 5-49 through 5-51), of the national Inventory, available online here:
https://www.epa.gov/system/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf.
Estimates are currently available for all 50 states and Puerto Rico.

4.2.4.3	Uncertainty

The overall uncertainty associated with national estimates of CO2 from urea fertilization is described in
Chapter 5 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022). A Monte Carlo
uncertainty analysis was applied. The largest source of uncertainty is the default emissions factor, which assumes
that 100% of the C in CO(NH2)2 applied to soils is emitted as CO2. The overall level of uncertainty in the national
CO2 urea fertilization estimates in 2020 was -43%/+3%.

4.2.4.4	Recalculations

No recalculations were applied to the state disaggregation method for this current report. Changes that
resulted from recalculations to the state-level estimates are the same as those presented in Section 5.6 of the
national Inventory (page 5-51), given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

4.2.4.5	Planned Improvements

Planned improvements to the state-level estimates are anticipated to be the same as those presented in
Section 5.6 of the national Inventory, given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

4.2.4.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 5: Agriculture. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf

Full citations of references included in Chapter 5.6 (Urea Fertilization) of the national Inventory are available
online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-
references.pdf.

4.2.5	Field Burning of Agricultural Residues (NIR Section 5.7)

4.2.5.1 Background

Crop production creates large quantities of agricultural crop residues, which farmers manage in a variety of
ways. For example, crop residues can be left in the field and possibly incorporated into the soil with tillage;
collected and used as fuel, animal bedding material, supplemental animal feed, or construction material;

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composted and applied to soils; transported to landfills; or burned in the field. Field Burning of Crop Residues is
not considered a net source of CO2 emissions because the C released to the atmosphere as CO2 during burning is
reabsorbed during the next growing season by the crop. However, crop residue burning is a net source of CH4, N2O,
CO, and NOx, which are released during combustion.

In the United States, field burning of agricultural residues is more common in southeastern states, the Great
Plains, and the Pacific Northwest. The primary crops that are managed with residue burning include corn, cotton,
lentils, rice, soybeans, sugarcane, and wheat.

4.2.5.2	Methods/Approach

The EPA compiles state-level CH4 and N2O emissions from field burning of agricultural residues using the same
methods applied in the national Inventory. The national Inventory applies a country-specific Tier 2 methodology.
This is described in Chapter 5, Section 5.7 (pages 5-51 through 5-60), of the national Inventory available online
here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf.

The most recent national Inventory includes state-level emissions for the years 1990-2014, but not for the
years 2015 through 2020. State estimates were developed using Approach 1 for 1990-2014 and Approach 2 for
disaggregating 2015-2020 national estimates. National-level emissions for 2015-2020 are estimated using a linear
extrapolation of the pattern from the previous years in the Inventory. For this report, these national totals were
disaggregated to the state level in a two-step process. First, the average proportion of the total national emissions
was computed for each state from 2012-2014, which are the last 3 years in which state-level emissions had been
estimated. Second, the state-level proportions were multiplied by the total national emissions to approximate the
amount of emissions occurring in each state from 2015-2020. Estimates are currently available for all states
excluding Alaska and Hawaii, consistent with the national Inventory, because these two states are not captured in
the current analysis. See Appendix E for time series information underlying the estimates.

4.2.5.3	Uncertainty

The overall uncertainty associated with national estimates of CH4 and N2O from field burning of agricultural
residues is described in Chapter 5 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022).
As described in the national Inventory, emissions are estimated using a linear regression model with autoregressive
moving-average (ARMA) errors for 2020. The linear regression ARMA model also produced estimates of the upper
and lower bounds to quantify uncertainty.

Because of data limitations, there are additional uncertainties in agricultural residue burning, particularly the
potential omission of burning associated with Kentucky bluegrass (produced on farms for turf grass installation)
and sugarcane. The EPA is aware that some agricultural residue burning is not currently captured in the national
Inventory analysis; please see planned improvements information. Overall levels of uncertainty in the national CH4
and N2O field burning of agricultural residue estimates in 2020 were: CH4 (-18/+18%) and N2O (-17/+17%).

4.2.5.4	Recalculations

No recalculations were applied for this current report, consistent with the national Inventory (see Section 5.7,
page 5-60).

4.2.5.5	Planned Improvements

Planned improvements to the state-level estimates are anticipated to be the same as those presented in
Section 5.7 of the national Inventory, given that improvements in the national Inventory will lead directly to
improvements in the quality of state-level estimates as well.

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4.2.5.6 References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 5: Agriculture. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-5-agriculture.pdf

Full citations of references included in Chapter 5.7 (Field Burning of Agricultural Residues) of the national
Inventory are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-
2022-chapter-10-references.pdf.

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5 Land Use, Land-Use Change, and Forestry (NIR Chapter 6)

This chapter describes the methods applied to estimate state-level GHG fluxes resulting from land use and
land-use change within states according to changes within and conversions between all land-use types, including
Forest Land, Cropland, Grassland, Wetlands, and Settlements (as well as Other Land). The EPA works closely with
the USDA-USFS, and NOAA on estimates for the national Inventory. USFS35 and NOAA develop state-level
estimates for the forest land and wetlands land use and land-use change categories, which are used for the
national Inventory and this state-level report. Table 5-1 summarizes the different approaches used to estimate
state-level land Use, land-Use Change, and forestry emissions and sinks completeness. State completeness is
consistent with the national Inventory. The sections below provide more detail on each category.

See also the national Inventory report Chapter 6.1 for a description of how the U.S. land base is represented to
identify land areas consistent with IPCC Guidelines. Work is underway to provide additional spatial and temporal
resolution to the representation of the U.S. land base and will help refine methods for state-level estimates in
subsequent annual publications of this data.

Table 5-1. Overview of Approaches for Estimating State-Level Land Use, Land Use Change and Forestry
Sector Greenhouse Gas Emissions and Sinks

Category

Gas

Approach

Geographic Completeness

Forest Land Remaining Forest

Carbon,

Approach 1

Includes estimates from all

Land and Lands Converted to

CH4, N20



states except Hawaii.1 For

Forest Land





Alaska, Lands Converted to
Forest are included in the Forest
Land Remaining Forest Land
data.

Cropland and Lands

Carbon

Hybrid:

Includes estimates from all

Converted to Cropland



•	1990-2015: Approach 1

•	2016-2020: Approach 2

states except Alaska.1

Grassland and Lands Converted to Grassland

Carbon Stock Changes

Carbon

Hybrid:

•	1990-2015: Approach 1

•	2016-2020: Approach 2

Includes estimates from all
states except Alaska.1

Non-C02 Emissions from

CH4, N20

Hybrid:

Includes estimates from all

Grassland Fires



•	1990-2014: Approach 1

•	2015-2020: Approach 2

states except Alaska.

Wetlands and Lands Converted to Wetlands

Coastal Wetlands

Carbon,

CH4

Approach 1

Includes estimates from all
states and Washington, D.C.,
with coastal wetlands except
Alaska and Hawaii.1

Peatlands

co2, ch4,

l\l2o

Approach 2

Includes estimates from all
states except Hawaii.

Flooded Lands

CO2, cm

Approach 1

Includes estimates from all
states and Washington, D.C.,
except Alaska and Hawaii.

35 U.S. Forest Service 2022 Resource Update (in preparation, to be published online at https://www.nrs.fs.fed.us/pubs/.

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Category

Gas

Approach

Geographic Completeness

Settlements and Land Converted to Settlements

Soil C

Carbon

Hybrid:

•	1990-2015: Approach 1

•	2016-2020: Approach 2

Includes estimates from all
states except Alaska.1

Settlement Trees

Carbon

Hybrid:

•	1990-2015: Approach 1

•	2016-2020: Approach 2

Includes estimates from all
states and Washington, D.C.1

Soil N2O

N2O

Hybrid:

•	1990-2015: Approach 1

•	2016-2020: Approach 2

Includes estimates from all
states except Alaska.1

Landfilled Yard Trimmings and
Food Scrap (LFYTFS)

Carbon

Approach 2

Includes estimates from all
states, Washington, D.C., and
territories1 (i.e., Puerto Rico).

1 Emissions are likely occurring in other U.S. territories; however, due to a lack of available data and the nature of this category,
this analysis includes emissions for only the territories indicated. Territories not listed are not estimated. See planned
improvements.

5.1.1 Forest Land Remaining Forest Land (NIR Section 6.2)

5.1.1.1	Background

Carbon is continuously cycled among the forest ecosystem carbon storage pools (i.e., aboveground biomass,
belowground biomass, dead wood, litter, and soil organic carbon) and the atmosphere because of biogeochemical
processes in forests (e.g., photosynthesis, respiration, decomposition, and disturbances such as fires or pest
outbreaks) and anthropogenic activities (e.g., harvesting, thinning, and replanting). The net change in forest
carbon, however, is not equivalent to the net flux between forests and the atmosphere because timber harvests
do not cause an immediate flux of all harvested biomass carbon to the atmosphere. Instead, harvesting transfers a
portion of the carbon stored in wood to a "product pool." Once in a product pool, the carbon is emitted over time
as CO2 in the case of decomposition and as CO2, Cm, N2O, CO, and NOx when the wood product combusts.
Emissions of non-C02 gases from forest fires, both wild and prescribed, along with N2O emissions from nitrogen
additions to the soil and CO2, Cm, and N2O emissions from drained organic soils also occur.

5.1.1.2	Methods/Approach

To compile national estimates of carbon stock changes from forest ecosystem carbon pools on forest land
remaining forest land, and non-C02 emissions from fires, along with non-C02 emissions from drained organic soils,
on forest land remaining forest land and land converted to forest land for the national Inventory, estimates for
each state were produced and summed into a national total. This is described in Chapter 6, Section 6.2 (pages 6-24
through 6-46), of the national Inventory, available online here:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf. Additional information on the methodologies and data is also provided in Annex 3.13.

Please note that N2O emissions from nitrogen additions to the soil are not included in the state-level estimates
and that Hawaii is not included in the national total or available at the state level at this time. Emissions of non-C02
gases from forest fires and non-C02 emissions from drained organic soils include emissions from both forest land
remaining forest land and land converted to forest land because it is not possible to report them separately at this
time. Additionally, the estimates of the carbon stock change in harvested wood are not currently available at the
state level. Work is underway to develop an approach for disaggregating the national estimates down to state
level.

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5.1.1.3	Uncertainty

The subcategories included in this state-level report include the carbon stock changes in forest ecosystem
carbon storage pools, non-CC>2 gases from forest fires and non-CC>2 emissions from drained organic soils. A brief
overview of the uncertainty analyses for each of the subcategories included in the national Inventory is provided
below. In addition, quantitative uncertainty estimates for individual states (2020) for the carbon stock changes in
forest ecosystem carbon storage pools and non-CC>2 gases from forest fires are provided in the USFS 2022
Resource Update (in preparation, to be published online at https://www.nrs.fs.fed.us/pubs/).

•	Carbon stock changes in forest ecosystem carbon storage pools: The overall uncertainty associated with
the 2020 national estimate of the carbon stock changes in forest ecosystem carbon storage pools was
calculated through a combination of sample-based and model-based approaches to uncertainty for forest
ecosystem CChflux using IPCC Approach 1 (IPCC 2006). As described further in Chapter 6.2 of the national
Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022), levels of uncertainty in the national
estimates in 2020 were (-11.5/+11.4%). State-level estimates of uncertainty vary significantly among the
states but, in general, tend to be higher than those provided for the United States in the national
Inventory. These higher uncertainties can occur when the models and factors developed from studies
done at a larger geographical scale are used to generate estimates at smaller geographic scales, such as
state-level, the potential for unique circumstances occurring within a state can potentially reduce the
accuracy and precision of the flux estimates and increase the overall uncertainty. For more details on
national-level uncertainty, see the Uncertainty discussion in Section 6.2 and Annex 3.13 of the national
Inventory.

•	Non-CQ2 gases from forest fires (includes both forest land remaining forest land and land converted to
forest land): The overall uncertainty associated with the 2020 national estimate of non-CC>2 gases from
forest fires was calculated through a Monte Carlo (IPCC Approach 2 [IPCC 2006]) sampling approach
employed to propagate uncertainty based on the model and data applied for US forest land. As shown in
Chapter 6 of the national Inventory, levels of uncertainty in the national estimates in 2020 were Cm
(-37/+42%) and N2O (-35/+39%). State-level estimates of uncertainty vary significantly among the states,
but, in general, tend to be higher than those provided in the national Inventory. These higher
uncertainties can occur when the models and factors developed from studies done at a larger
geographical scale are used to generate estimates at smaller geographic scales, such as state-level, the
potential for unique circumstances occurring within a state can potentially reduce the accuracy and
precision of the flux estimates and increase the overall uncertainty. For more details on national-level
uncertainty and the quantities and assumptions employed to define and propagate uncertainty, see the
Uncertainty discussion in Section 6.2 and Annex 3.13 of the national Inventory.

•	Non-CCh gases from drained organic soils (includes both forest land remaining forest land and land
converted to forest land): The overall uncertainty associated with the 2020 national estimate of non-CC>2
gases from drained organic soils was calculated through IPCC Approach 1 (IPCC 2006). As described
further in Chapter 6 of the national Inventory, levels of uncertainty in the national estimates in 2020 were
Cm (-69/+82%) and N2O (-118/+132%). State-level estimates of uncertainty vary significantly among the
states but, in general, tend to be higher than those provided in the national Inventory. For more details on
national-level uncertainty and the quantities and assumptions employed to define and propagate
uncertainty, see the Uncertainty discussion in Section 6.2 and Annex 3.13 of the national Inventory.

5.1.1.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 6.2 of the national Inventory (page 6-37, 6-41, and 6-46), given that improvements in the national

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Inventory will lead directly to improvements in the quality of state-level estimates as well. In particular, the EPA
new National Forest Inventory (NFI) data in most states were incorporated in the latest Inventory.

5.1.1.5	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for the state-level GHG estimates are the same as those in the national Inventory. To view
the planned improvements to the methods and data for estimating emissions and removals from forest land
remaining forest land, see the planned improvements discussion on pp. 6-38 through 6-39 and 6-41 of Chapter 6.2
in the national Inventory for a description of future work to improve these estimates. In addition, as noted by the
USFS 2022 Resource Update (in preparation, to be published online at https://www.nrs.fs.fed.us/pubs/),
investments are being made to leverage existing state-level forest products information to allow for the
disaggregation of HWP estimates at the state level in the future.

5.1.1.6	References

USFS 2022 Resource Update (in preparation). To be published online at: https://www.nrs.fs.fed.us/pubs/

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of all references included in Chapter 6.2 (Forest Land Remaining Forest Land) of the national
Inventory are found on pages 10-66 to 10-70 of Chapter 10 (References) and available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventory-2022-chapter-10-references.pdf.

5.1.2 Land Converted to Forest Land (NIR Section 6.3)

5.1.2.1	Background

Land use conversions into forest land can result in carbon stock changes to all forest ecosystem carbon pools
(i.e., aboveground biomass, belowground biomass, dead wood, litter, and soil organic carbon). Section 5.1.2
provides estimates of carbon stock changes resulting from conversion of cropland, grassland, wetlands,
settlements, and other lands to forest land.

5.1.2.2	Methods/Approach

The methods applied for estimating carbon stock changes in land converted to forest land are the same as
those applied for forest land remaining forest land. This is described in Chapter 6, Section 6.3 (pages 6-47 through
6-54), of the national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-
ghg-inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf. Additional information on the
methodologies and data is also provided in Annex 3.13 of the national Inventory. Please note that estimates for
Hawaii are not included in the national total or available at the state level at this time. Forest ecosystem carbon
stock changes from land conversion in Alaska are currently included in the forest land remaining forest land
chapter because there are insufficient data to separate the changes at this time.

5.1.2.3	Uncertainty

The overall uncertainty associated with the 2020 national estimate of the carbon stock changes in forest
ecosystem carbon storage pools for land converted to forest land is described in Chapter 6.3 of the national
Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022). The uncertainty estimates were calculated
through a combination of sample-based and model-based approaches to uncertainty for non-soil forest ecosystem
CChflux using IPCC Approach 1 (IPCC 2006), in combination with IPCC Approach 2 for mineral soils (described in

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Section 6.4, Cropland Remaining Cropland, of the Inventory report). Uncertainty estimates are provided for each
land conversion category and carbon pool. The combined level of uncertainty in the national estimates in 2020 was
-11/+11%. State-level estimates of uncertainty are not available but are likely to vary significantly from the
national estimates and, in general, tend to be higher than those provided for the United States in the national
Inventory. These higher uncertainties can occur when the models and factors developed from studies done at a
larger geographical scale are used to generate estimates at smaller geographic scales, such as state-level, the
potential for unique circumstances occurring within a state can potentially reduce the accuracy and precision of
the flux estimates and increase the overall uncertainty. For more details on national-level uncertainty, see the
Uncertainty discussion in Section 6.4 and Annex 3.13 of the national Inventory.

5.1.2.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 6.3 of the national Inventory (page 6-53), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well.

5.1.2.5	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for state GHG estimates are the same as those in the national Inventory. To review the
planned improvements to the methods and data for estimating emissions and removals from land converted to
forest land, see the planned improvements discussion on page 6-53 of Chapter 6.3, in the national Inventory.

5.1.2.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of references included in Chapter 6.3 (Land Converted to Forest Land) of the national Inventory
are found on pages 10-71 to 10-72 of Chapter 10 (References) and available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-10-references.pdf.

5.1.3 Cropland Remaining Cropland (NIR Section 6.4)

5.1.3.1 Background

Carbon in cropland ecosystems occurs in biomass, dead organic matter, and soils. However, carbon storage in
cropland biomass and dead organic matter is relatively ephemeral and does not need to be reported according to
the IPCC (2006), with the exception of carbon stored in perennial woody crop biomass, such as citrus groves and
apple orchards, in addition to the biomass, downed wood and dead organic matter in agroforestry systems. Within
soils, carbon is found in organic and inorganic forms of carbon, but soil organic carbon is the main source and sink
for atmospheric CO2 in most soils.

The IPCC (2006) recommends reporting changes in soil organic carbon stocks due to agricultural land-use and
management activities for mineral and organic soils. Management of croplands and cropland soils has an impact
on organic matter inputs and microbial decomposition, and thereby result in a net carbon stock change.

Cropland remaining cropland includes all cropland in an inventory year that has been cropland for a
continuous time period of at least 20 years. This determination is based on the USDA NRI for nonfederal lands and
the National Land Cover Dataset for federal lands. Cropland includes all land that is used to produce food and fiber,
forage that is harvested and used as feed (e.g., hay and silage), in addition to cropland that has been enrolled in
the Conservation Reserve Program (i.e., considered set-aside cropland).

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5.1.3.2	Methods/Approach

The EPA compiles state-level emissions from Cropland Remaining Cropland using the same methods applied
in the national Inventory. Please see the methodologies described in Chapter 6, Section 6.4 (pages 6-54 through 6-
665), of the national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-
ghg-inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf. For this report, estimates were
developed using a hybrid of Approach 1 and Approach 2. The current national Inventory includes state-level
emissions for the years 1990-2015 for soil organic C stock changes. The remaining years in the time series were
only estimated at the national scale using a surrogate data method, and a two-step process was used to
approximate the state-level emissions for the remaining years. First, the average proportion of the total national
emissions was computed for each state from 2013-2015. Second, the state-level proportions were multiplied by
the total national emissions to approximate the amount of emissions occurring in each state for 2016-2020.
Estimates are included for all states with the exception of Alaska.

Additional information on methodologies and data is also provided in Annex 3.12, available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-annex-3-additional-source-or-sink-
categories-part-b.pdf

5.1.3.3	Uncertainty

The overall uncertainty associated with national estimates from Cropland Remaining Cropland is described in
Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022) and in further detail in
Annex 3.12. Uncertainty for the Tier 2 and 3 approaches is derived using a Monte Carlo approach. The combined
uncertainty for soil organic C stocks in Cropland Remaining Cropland in 2020 ranges from -317% to +317%.

5.1.3.4	Recalculations

No recalculations were applied for this current report, consistent with the national Inventory (see Section 6.4,
page 6-64).

5.1.3.5	Planned Improvements

The planned improvements are anticipated to be the same as those planned for improving the national
estimates given that the underlying methods for state GHG estimates are the same as those in the national
Inventory and will lead directly to improvements in the quality of state-level estimates as well. To review the
planned improvements to the methods and data for estimating emissions and removals from cropland remaining
cropland, see the planned improvements discussion on pages 6-65 and 6-66 of Chapter 6.4 in the national
Inventory.

5.1.3.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of references included in Chapter 6.4 (Cropland Remaining Cropland) and Annex 3.12 of the
national Inventory are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-chapter-10-references.pdf and https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventory-2022-annex-3-additional-source-or-sink-categories-part-b.pdf.

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5.1.4 Land Converted to Cropland (NIR Section 6.5)

5.1.4.1	Background

Land-use change can lead to large losses of C to the atmosphere, particularly conversions from forest land.
Moreover, conversion of forest to another land use (i.e., deforestation) is one of the largest anthropogenic sources
of emissions to the atmosphere globally.

Land converted to cropland includes all cropland in an inventory year that had been in another land use(s)
during the previous 20 years, and used to produce food or fiber, or forage that is harvested and used as feed (e.g.,
hay and silage). For example, grassland or forest land converted to cropland during the past 20 years would be
reported in this category. Recently converted lands are retained in this category for 20 years as recommended by
IPCC (2006).

5.1.4.2	Methods/Approach

The EPA compiles state-level emissions from land converted to cropland using the same methods applied in
the national Inventory. Please see the methodologies described in Chapter 6, Section 6.5 (pages 6-66 through 6-
72), of the national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-
ghg-inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf. For this report, estimates were
developed using a hybrid of Approach 1 and Approach 2. The current national Inventory includes state-level fluxes
for the years 1990-2020 for biomass, standing dead, deadwood, and litter and for the years 1990-2015 for soil
organic C stock changes. The remaining years in the time series for soil organic C stock changes were only
estimated at the national scale using a surrogate data method, and a two-step process was used to approximate
the state-level emissions for the remaining years. First, the average proportion of the total national emissions was
computed for each state from 2013-2015. Second, the state-level proportions were multiplied by the total
national emissions to approximate the amount of emissions occurring in each state for 2016-2020. Estimates are
included for all states with the exception of Alaska.

Additional information on methodologies and data is also provided in Annex 3.12, available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-annex-3-additional-source-or-sink-
categories-part-b.pdf.

5.1.4.3	Uncertainty

The overall uncertainty associated with national estimates from Land Converted to Cropland is described in
Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022) and in further details in
Annex 3.12 and Annex 3.13 (Forestland Converted to Cropland). The uncertainty analyses for mineral soil organic C
stock changes using the Tier 3 and Tier 2 methodologies are based on a Monte Carlo approach that is used in
Cropland Remaining Cropland analysis. The combined uncertainty for total C stocks in Land Converted to Cropland
in 2020 ranged from -952% to +95%.

5.1.4.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 6.5 of the national Inventory (page 6-72), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well.

5.1.4.5	Planned Improvements

The planned improvements are anticipated to be the same as those planned for improving the national
estimates, given that the underlying methods for state GHG estimates are the same as those in the national
Inventory and will lead directly to improvements in the quality of state-level estimates as well. To review the
planned improvements to the methods and data for estimating emissions and removals from land converted to

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cropland, see the planned improvements discussion on pages 6-72 and 6-73 of Chapter 6.5 in the national
Inventory.

5.1.4.6 References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020

(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-

change-and-forestry.pdf

Full citations of references included in Chapter 6.5 (Land Converted to Cropland) and Annex 3.12 of the
national Inventory are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-chapter-10-references.pdf and https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-annex-3-additional-source-or-sink-categories-part-b.pdf.

5.1.5 Grassland Remaining Grassland (NIR Section 6.6)

5.1.5.1	Background

Carbon in grassland ecosystems occurs in biomass, dead organic matter, and soils. Soils are the largest pool of
carbon in grasslands and have the greatest potential for longer-term storage or release of carbon. Biomass and
dead organic matter carbon pools are relatively ephemeral compared to the soil carbon pool, with the exception of
carbon stored in tree and shrub biomass that occurs on grasslands.

The 2006 IPCC Guidelines recommend reporting changes in biomass, dead organic matter and soil organic
carbon stocks with land use and management. Carbon stock changes for aboveground and belowground biomass,
dead wood and litter pools are reported for woodlands (i.e., a subcategory of grasslands), and may be extended to
include agroforestry management associated with grasslands in the future. For soil organic carbon, the 2006 IPCC
Guidelines (IPCC 2006) recommend reporting changes due to (1) agricultural land-use and management activities
on mineral soils, and (2) agricultural land-use and management activities on organic soils.

Grassland remaining grassland includes all grassland in an inventory year that had been grassland for a
continuous time period of at least 20 years. Grassland includes pasture and rangeland that are primarily, but not
exclusively used for livestock grazing. Rangelands are typically extensive areas of native grassland that are not
intensively managed, while pastures are typically seeded grassland (possibly following tree removal) that may also
have additional management, such as irrigation or inter-seeding of legumes. Woodlands are also considered
grassland and are areas of continuous tree cover that do not meet the definition of forest land.

Non-CCh emissions from grassland fires are also included. Non-CC>2 emissions from grassland fires do not
currently include emissions from burning perennial biomass (a national Inventory planned improvement).

5.1.5.2	Methods/Approach

The EPA compiles state-level emissions from grassland remaining grassland using the same methods applied in
the national Inventory. Please see the methodologies described in Chapter 6.6 (pages 6-73 through 6-84) of the
national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf. For this report, estimates were developed
using a hybrid of Approach land Approach 2. The current national Inventory includes state-level emissions for the
years 1990-2020 for biomass, standing dead, deadwood, and litter and for the years 1990-2015 for soil organic C
stock changes. The remaining years in the time series for soil organic C stock changes were only estimated at the
national scale using a surrogate data method, and a two-step process was used to approximate the state-level
emissions for the remaining years. First, the average proportion of the total national emissions was computed for
each state from 2013-2015. Second, the state-level proportions were multiplied by the total national emissions to

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approximate the amount of emissions occurring in each state for 2016-2020. Estimates are included for all states
with the exception of Alaska.

Additional information on national Inventory methodologies and data is also provided in Annex 3.12, available
online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-annex-3-additional-
source-or-sink-categories-part-b.pdf.

5.1.5.3	Uncertainty

The overall uncertainty associated with national estimates from Grassland Remaining Grassland is described in
Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022) and in further details in
Annex 3.12. The uncertainty analyses for mineral soil organic C stock changes using the Tier 3 and Tier 2
methodologies are based on a Monte Carlo approach that is used in Cropland Remaining Cropland analysis.
Uncertainty estimates are also developed for Biomass Burning in Grassland using a linear regression ARMA model
to estimate the upper and lower bounds of the emission estimate. The combined uncertainty for total C stocks in
Grassland Remaining Grassland in 2020 ranged from -3,256% to +3,256%.

5.1.5.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 6.6 of the national Inventory (page 6-80), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well.

5.1.5.5	Planned Improvements

The planned improvements are anticipated to be the same as those planned for improving the national
estimates given that the underlying methods for state GHG estimates are the same as those in the national
Inventory and will lead directly to improvements in the quality of state-level estimates as well. To review the
planned improvements to the methods and data for estimating emissions and removals from Grassland Remaining
Grassland, see the planned improvements discussion on pages 6-80 and 6-81 of Chapter 6.6 in the national
Inventory.

5.1.5.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of references included in Chapter 6.6 (Grassland Remaining Grassland) and Annex 3.12 of the
national Inventory are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-chapter-10-references.pdf and https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-annex-3-additional-source-or-sink-categories-part-b.pdf.

5.1.6 Land Converted to Grassland (NIR Section 6. NIR Section 6.7)

5.1.6.1 Background

Land-use change can lead to large losses of C to the atmosphere, particularly conversions from forest land.
Moreover, conversion of forest to another land use (i.e., deforestation) is one of the largest anthropogenic sources
of emissions to the atmosphere globally.

Land converted to grassland includes all grassland in an inventory year that had been in another land use(s)
during the previous 20 years. For example, cropland or forest land converted to grassland during the past 20 years

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would be reported in this category. Recently converted lands are retained in this category for 20 years as
recommended by IPCC (2006).

5.1.6.2	Methods/Approach

The EPA compiles state-level emissions from land converted to grassland using the same methods applied in
the national Inventory. Please see the methodologies described in Chapter 6, Section 6.7 (pages 6-85 through 6-
92), of the national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-
ghg-inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf. For this report, estimates were
developed using a hybrid of Approach 1 and Approach 2. The current national Inventory includes state-level
emissions for the years 1990-2020 for biomass, standing dead, deadwood, and litter and for the years 1990-2015
for soil organic C stock changes. The remaining years in the time series for soil organic C stock changes were only
estimated at the national scale using a surrogate data method, and a two-step process was used to approximate
the state-level emissions for the remaining years. First, the average proportion of the total national emissions was
computed for each state from 2013-2015. Second, the state-level proportions were multiplied by the total
national emissions to approximate the amount of emissions occurring in each state for 2016-2020. Estimates are
included for all states with the exception of Alaska.

Additional information on methodologies and data is also provided in Annex 3.12, available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventory-2022-annex-3-additional-source-or-sink-
categories-part-b.pdf.

5.1.6.3	Uncertainty

The overall uncertainty associated with national estimates from Land Converted to Grassland is described in
Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022) and in further details in
Annex 3.12. The uncertainty analyses for mineral soil organic C stock changes using the Tier 3 and Tier 2
methodologies are based on a Monte Carlo approach that is used in Cropland Remaining Cropland analysis. The
combined uncertainty for total C stocks in Land Converted to Grassland in 2020 ranged from -153% to +153 %.

5.1.6.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 6.7 of the national Inventory (page 6-91), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well.

5.1.6.5	Planned Improvements

The planned improvements are anticipated to be the same as those planned for improving the national
estimates given that the underlying methods for state GHG estimates are the same as those in the national
Inventory. To review the planned improvements to the methods and data for estimating emissions and removals
from land converted to grassland, see the planned improvements discussion on pages 6-91 and 6-92 of Chapter 6.7
in the national Inventory.

5.1.6.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of references included in Chapter 6.7 (Land Converted to Grassland) and Annex 3.12 of the
national Inventory are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-

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inventorv-2022-chapter-10-references.pdf and https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-annex-3-additional-source-or-sink-categories-part-b.pdf.

5.1.7 Wetlands Remaining Wetlands (NIR Section 6.8)

This section presents methods for estimating state-level CO2, CH4, and N2O emissions and removals from
management of wetlands consistent with the national Inventory, specifically:

•	Coastal wetlands remaining coastal wetlands (CO2, CH4)

•	Peatlands remaining peatlands (CO2, CH4, and N2O)

•	Flooded land remaining flooded land (CH4)

5.1.7.1	Coastal Wetlands Remaining Coastal Wetlands

5.1.7.2	Background

Consistent with ecological definitions of wetlands, the United States has historically included under the
category of Wetlands those coastal shallow water areas of estuaries and bays that lie within the extent of the Land
Representation. The national Inventory includes all privately owned and publicly owned coastal wetlands (i.e.,
mangroves and tidal marsh) along the oceanic shores on the conterminous United States but does not include
coastal wetlands remaining coastal wetlands in Alaska or Hawaii. Soil and biomass C stocks from seagrasses are not
currently included in the Inventory because of insufficient data on distribution, change through time, and carbon
(C) stocks or C stock changes as a result of anthropogenic influence. Additionally, the estimates of N2O emissions
from aquaculture are only available at the national level because of data limitations and have not been included in
the current state estimates.

Under the Coastal Wetlands Remaining Coastal Wetlands category, the following emissions and removals
subcategories are quantified at the state level:

•	Carbon stock changes and Cm emissions on vegetated coastal wetlands remaining vegetated coastal
wetlands,

•	Carbon stock changes on vegetated coastal wetlands converted to unvegetated open water coastal
wetlands, and

•	Carbon stock changes on unvegetated open water coastal wetlands converted to vegetated coastal
wetlands.

5.1.7.3	Methods/Approach

To compile national estimates of carbon stock changes and Cm emissions from coastal wetlands remaining
coastal wetlands for the national Inventory, estimates for each state and the District of Columbia with coastal
wetlands were produced and summed into a national total. A description of the methods and data used to
estimate state-level emissions is provided in Chapter 6, Section 6.8 (pages 6-99 through 6-115), of the national
Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-
chapter-6-land-use-land-use-change-and-forestrv.pdf.

States (plus the District of Columbia) with coastal wetlands currently included in the national Inventory are
Alabama, California, Connecticut, Delaware, Florida, Georgia, Louisiana, Maine, Maryland, Massachusetts,
Mississippi, New Hampshire, New Jersey, New York, North Carolina, Oregon, Pennsylvania, Rhode Island, South
Carolina, Texas, Virginia, and Washington. Please note that estimates for Hawaii and Alaska are not included in the
national total or available at the state level at this time.

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5.1.7.4 Uncertainty

Uncertainty estimates for each of the emissions and removals categories are only available at the national
level. A brief overview of the uncertainty analyses for each of the subcategories included in the national Inventory
is provided below.

•	Carbon stock changes and Cm emissions on vegetated coastal wetlands remaining vegetated coastal
wetlands: Underlying uncertainties in the estimates of soil and biomass C stock changes and CH4 emissions
include uncertainties associated with Tier 2 literature values of soil C stocks, biomass C stocks and CH4
flux, assumptions that underlie the methodological approaches applied and uncertainties linked to
interpretation of remote sensing data. Uncertainty specific to Vegetated Coastal Wetlands Remaining
Vegetated Coastal Wetlands include differentiation of palustrine and estuarine community classes, which
determines the soil C stock and CFUflux applied. Uncertainties for soil and biomass C stock data for all
subcategories are not available and thus assumptions were applied using expert judgment about the most
appropriate assignment of a C stock to a disaggregation of a community class. IPCC Approach 1 (IPCC
2006) was used to calculate these uncertainties. As described further in Chapter 6.8 of the national
Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022), levels of uncertainty in the national
estimates in 2020 for biomass carbon stock change are (-24.1/+24.1%), soil carbon stock change are
(-17.8/+17.8%) and CFU emissions are (-29.8/+29.8%). The combined uncertainty across all subsources is
(-36.6/+36.6%), which is primarily driven by the uncertainty in the CH4estimates because there is high
variability in CH4 emissions when the salinity is less than 18 ppt. State-level estimates of uncertainty will
vary significantly among the states but, in general, tend be higher than those provided for the United
States in the national Inventory. For more details on national-level uncertainty, see the Uncertainty
discussion in Section 6.8 of the national Inventory.

•	Carbon stock changes on vegetated coastal wetlands converted to unvegetated open water coastal
wetlands: Underlying uncertainties in the estimates of soil and biomass C stock changes are associated
with country-specific (Tier 2) literature values of these stocks, while the uncertainties with the Tier 1
estimates are associated with subtropical estuarine forested wetland DOM stocks. Assumptions that
underlie the methodological approaches applied and uncertainties linked to interpretation of remote
sensing data are also included in this uncertainty assessment. IPCC Approach 1 (IPCC 2006) was used to
calculate these uncertainties. As described further in Chapter 6.8 of the national Inventory of U.S.
Greenhouse Gas Emissions and Sinks (EPA 2022), levels of uncertainty in the national estimates in 2020 for
biomass carbon stock change are (-24.1/+24.1%), dead organic matter carbon stock change are
(-25.8/+25.8%) and soil carbon stock change are (-15/+15%). The combined uncertainty across all
subsources is (-32/+32%), which is primarily driven by the uncertainty in the soil carbon stock change
estimates. State-level estimates of uncertainty will vary significantly among the states but, in general,
tend to be higher than those provided for the United States in the national Inventory. For more details on
national-level uncertainty, see the Uncertainty discussion in Section 6.8 of the national Inventory.

•	Carbon stock changes on unvegetated open water coastal wetlands converted to vegetated coastal
wetlands: Underlying uncertainties in estimates of soil and biomass C stock changes include uncertainties
associated with country-specific (Tier 2) literature values of these C stocks and assumptions that underlie
the methodological approaches applied and uncertainties linked to interpretation of remote sensing data.
Uncertainty specific to coastal wetlands include differentiation of palustrine and estuarine community
classes that determines the soil C stock applied. IPCC Approach 1 (IPCC 2006) was used to calculate these
uncertainties. As described further in Chapter 6.8 of the national Inventory of U.S. Greenhouse Gas
Emissions and Sinks (EPA 2022), levels of uncertainty in the national estimates in 2020 for biomass carbon
stock change are (-20/+20%), dead organic matter carbon stock change are (-25.8/+25.8%) and soil
carbon stock change are (-17.8/+17.8%). The combined uncertainty across all subsources is

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(-33.4/+33.4%). State-level estimates of uncertainty will vary significantly among the states but, in
general, tend to be higher than those provided for the United States in the national Inventory. For more
details on national-level uncertainty, see the Uncertainty discussion in Section 6.8 of the national
Inventory.

5.1.7.5	Recalculations

No recalculations were applied for this current report, consistent with the national Inventory (see Section 6.8,
page 6-105).

5.1.7.6	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for the state GHG estimates are the same as those in the national Inventory. To review the
planned improvements to the methods and data for estimating emissions and removals from Coastal Wetlands
Remaining Coastal Wetlands, see the planned improvements discussions on pp. 6-106, 6-109 through 6-110, and 6-
113 through 6-114 of Chapter 6.8, in the national Inventory.

While the N2O flux from aquaculture has not been estimated for this initial version of the Inventory by state,
the EPA intends to include this in future annual publications of this data.

5.1.7.7	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of the references included in Chapter 6.8 (Wetlands Remaining Wetlands) of the national
Inventory are listed on pages 10-83 to 10-85 in Chapter 10 (References) of the Inventory and available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-references.pdf.

5.1.7.8	Peatlands Remaining Peatlands

5.1.7.9	Background

This section describes methods to estimate state-level CO2, CH4, and N2O emissions from peatlands remaining
peatlands (managed peatlands).

Managed peatlands are peatlands that have been cleared and drained for peat production. The production
cycle of a managed peatland has three phases: land conversion in preparation for peat extraction (e.g., clearing
surface biomass, draining), extraction (which results in the emissions reported under peatlands remaining
peatlands), and abandonment, restoration, rewetting, or conversion of the land to another use. On-site and off-
site emissions also result from managed peatlands. On-site emissions from managed peatlands occur as the land is
cleared of vegetation and the underlying peat is exposed to sun and weather. Off-site CO2 emissions from
managed peatlands occur from waterborne carbon losses and the horticultural and landscaping use of peat.

5.1.7.10	Methods/Approach

State-level estimates were compiled using Approach 2 and are based on the national-level methods included
in Chapter 6.8, Wetlands Remaining Wetlands, of the national Inventory. State-level peat production was
estimated using Bureau of Mines and USGS's Minerals Yearbooks from 1990-2018, covering the contiguous 48
states and the District of Columbia. For Alaska, the method is the same as the national-level method; the national
Inventory historically breaks out peat production and emissions separately for Alaska because of data availability.

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Hawaii and Puerto Rico are not estimated because peat production data were not available, and regional data
provided in the USGS yearbooks did not include these states as peat producers.

For annual state-level peat production for 1990-2020, the primary activity data used to estimate emissions
were calculated as follows given that no single data source covers all years:

•	For 1990-1993, state-level annual peat production data were obtained from the Bureau of Mines
Minerals Yearbooks (Bureau of Mines, 1990,1991,1992,1993). These data were available for only select
states and The Bureau of Mines also reported a total national production value. The Bureau of Mines
state peat production data were summed by year to obtain total known state peat production. States with
no individual peat production data and that are not within a peat-producing region are assumed to not be
producing peat. State production values were normalized to sum to the national production value. See
Appendix E.

•	For 1994-1997, state-level annual peat production data were obtained from the USGS Minerals
Yearbooks-for those years, respectively (USGS 2020a). Regional total data became available in 1994. To
determine peat production for states within a "peat-producing region" (i.e., Northeast, Great Lakes,
Southeast, West), but with no individual reported peat production data, individual state values were
summed and then subtracted from the available regional total peat production value to determine the
peat production not accounted for in the regional data.-The peat production for states with individual
reported peat production data and peat production estimated from region-based peat production data
were then summed. This value was subtracted from the total national peat production of the contiguous
48 states available from the USGS annual Minerals Commodities Summary (2020b). States with no
individual peat production data and that are not within a peat-producing region are assumed to not be
producing peat. State production values were normalized to sum to the national production value. See
Appendix E.

•	For 1998-2018, state-level annual peat production data were obtained from the USGS Minerals
Yearbooks (USGS 2020a) from the respective years. To determine peat production for states within a
"peat-producing region" (i.e., East, Great Lakes, West), but with no individual reported peat production
data, individual state values were summed and then subtracted from the available regional total peat
production value to determine the peat production not accounted for in the regional data. Note that
between 1997 and 1998, peat-producing regions changed from Northeast, Great Lakes, Southeast, and
West to East, Great Lakes, and West. States placed within these regions varied from year to year. The peat
production for states with individual reported peat production data and peat production estimated from
region-based peat production data were then summed. States with no individual peat production data
and that are not within a peat-producing region are assumed to not be producing peat. State production
values were normalized to sum to the national production value. See Appendix E.

•	2019 state-level peat production was estimated as an average fraction of total peat production for the
previous 10 years because 2019 USGS data were not available at the time of Inventory development.

There is annual variability in the peat production values, which lends itself to using an average, rather
than relying solely on the previous year (2018) to estimate peat production. An average percentage was
estimated by calculating the average fraction of total U.S. peat production over the past 10 years for a
given state. This average fraction was then multiplied by the 2019 total U.S. peat production of the
conterminous 48 states available from the USGS annual Minerals Commodities Summary. See Appendix E.

•	2020 state-level peat production was set to the same values as 2019 state-level peat production since no
new data were available since the 2018 release of the USGS Minerals Yearbook (USGS 2020a). State
production values were normalized to sum to the national production value.

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Following peat production estimation, peat production area was calculated using a standard conversion factor
from mass of peat production to land area required for that mass of peat production: 100 metric tons of peat per
hectare per year (Vacuum method, Canada) (Cleary et al. 2005).

To estimate state-level emissions from peatlands remaining peatlands, national assumptions were applied to
estimate the percentage of nutrient-rich vs. the percentage of nutrient-poor peat soil, which affects emissions. Six
separate calculations were then performed to yield CO2, CH4, and N2O emissions estimates.

•	Emissions factors for off-site C02 emissions from horticulture use (which differentiates between rich and
poor peat) and dissolved organic carbon were applied to peat production and the areas of peat
production were calculated to yield off-site C02 emissions. Because of a lack of peat application data, off-
site peat was assumed to be applied proportionally to U.S. domestic state population in two separate
components: horticulture use (which includes peat application in non-conterminous states and Puerto
Rico) and dissolved organic carbon. Off-site CO2 emissions were distributed proportionally by the
percentage of the total U.S. population (1990-1999: U.S. Census Bureau 2002; 2000-2009: U.S. Census
Bureau 2011; 2010-2020: U.S. Census Bureau 2021; Instituto de Estadisticas de Puerto Rico 2021), as it is
assumed that horticulture use is positively correlated to population. The EPA intends to continue to
review this assumption; see Planned Improvements below.

•	IPCC (2013) emissions factor for on-site C02 emissions of drained organic soils was applied to peat
production to yield on-site C02 emissions.

•	IPCC (2013) emissions factors for direct CH4emissions for drained land surfaces and drainage ditches
created from peat extraction were applied to the peat production area to yield on-site CH4 emissions.

•	IPCC (2013) emissions factor for on-site N20 emissions was applied to the peat production area of
nutrient-rich peat soil only to yield on-site N20 emissions.

5.1.7.11	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CO2, CH4 and N2O from peatlands
remaining peatlands were calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As
described further in Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022),
levels of uncertainty in the national estimates in 2020 were CO2 (-17/+17%), CH4 (-58/+77%) and N2O (-53/+53%).
State-level estimates have a higher uncertainty due to apportioning national data to the state level and due to the
assumption that any state without data on peat production is a non-producing state. These assumptions were
required due to a general lack of data confirming that states are either producing or non-producing. For more
details on national-level uncertainty, see the Uncertainty discussion in Section 6.8 of the national Inventory.

5.1.7.12	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in the
national Inventory, given that improvements in the national Inventory will lead directly to improvements in the
quality of state-level estimates, see Section 6.8 of the national Inventory, page 6-98. In particular, the lower 48
states peat production estimates were updated using the peat section of the Mineral Commodity Summaries 2021.
The 2021 edition updated 2018, 2019, and 2020 national peat estimates (which are used to estimate state peat
production).

EPA revised the state peat production estimation methodology by assuming that states that are both not in
peat-producing regions and not identified as peat-producing states in the applicable year's Minerals Yearbook are
not producing peat. In cases where the sum of the state-level data did not match the national-level data, EPA
normalized the state peat production estimates to ensure consistency. These changes did not affect estimates of
off-site emissions. See Planned Improvements below for more detail.

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5.1.7.13	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates, given that
the underlying methods for state GHG estimates are based on those used in the national Inventory. In addition, the
methodology used to estimate state-level emissions will be reviewed and revised over time as to identify other
data to update assumptions (e.g., data and approaches to proxy peat production (better refine where peat is
produced) and consumption).

•	The EPA plans to investigate estimating emissions for Hawaii, Puerto Rico, and applicable territories,
pending data availability. Emissions from off-site horticulture use are currently not estimated in non-
conterminous states and territories, even though peat spreading is not limited to conterminous states.

•	The EPA will continue monitoring for data sources to reduce or eliminate the disparity between estimated
state peat production and the national peat production estimate, especially for production values in
1990-2000. Some amount of normalization is currently done for most years throughout the time series.

To find information on planned improvements to refine methods for estimating emissions and removals from
wetlands remaining wetlands (coastal wetlands remaining coastal wetlands and peatlands remaining peatlands),
see the planned improvements discussion on pages 6-98, 6-99 described in the national Inventory at the link
provided above.

5.1.7.14	References

Bureau of Mines. (1990). Minerals yearbook: peat. U.S. Department of the Interior. Available online at:
https://digital.librarv.wisc.edu/1711.dl/EZRI27J2VYVCG8G.

Bureau of Mines. (1991). Minerals yearbook: peat. U.S. Department of the Interior. Available online at:
https://digital.librarv.wisc.edu/1711.dl/5X7AVV22D2URQ8R.

Bureau of Mines. (1992). Minerals yearbook: peat. U.S. Department of the Interior. Available online at:
https://digital.librarv.wisc.edu/1711.dl/FYIUSH2IKTZTI8Q.

Bureau of Mines. (1993). Minerals yearbook: peat. U.S. Department of the Interior. Available online at:
https://digital.librarv.wisc.edu/1711.dl/2YIJA2GUJDKQB86.

Cleary, J., N. Roulet and T.R. Moore. (2005). Greenhouse gas emissions from Canadian peat extraction, 1990-2000:
A life-cycle analysis. Ambio 34: 456-461.

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

IPCC (2013). 2013 Supplement to the 2006IPCC Guidelines for National Greenhouse Gas Inventories: Wetlands.
Hiraishi, T., Krug, T., Tanabe, K., Srivastava, N., Baasansuren, J., Fukuda, M. and Troxler, T.G. (eds.). Published:
IPCC, Switzerland.

U.S. Census Bureau. (2021a). Annual Estimates of the Resident Population for the United States, Regions, States,
and Puerto Rico: April 1, 2010 to July 1, 2020. Available online at: https://www.census.gov/data/tables/time-
series/demo/popest/2010s-state-total.html

U.S. Census Bureau, Population Division. (2011). Table 1. Intercensal Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01), Release Date:
September 2011. Available online at: https://www2.census.gov/programs-survevs/popest/datasets/200Q-
2010/intercensal/state/st-est00int- alldata.csv

U.S. Census Bureau, Population Division (2002). Table CO-EST2001-12-00—Time Series of Intercensal State

Population Estimates: April 1,1990 to April 1, 2000. Available online at: https://www2.census.gov/programs-
survevs/popest/tables/1990-2000/intercensal/st- co/co-est2001-12-00.pdf

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U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

U.S. Geological Survey (USGS). (2020a). Minerals Yearbook: Peat (1994-2018). U.S. Geological Survey, Reston, VA.
Available online at: http://minerals.usgs.gOv/minerals/pubs/commoditv/peat/index.html#mvb.

U.S. Geological Survey (USGS). (2020b). Mineral Commodity Summaries: Peat (1996-2021). U.S. Geological Survey,
Reston, VA. Available online at: https://pubs.usgs.gov/periodicals/mcs2020/mcs2020.pdf

Full citations of other references relevant to Chapter 6.8 (Wetlands Remaining Wetlands) and 6.9 (Land
Converted to Wetlands) of the national Inventory are listed on pages 10-80 to 10-83 in Chapter 10 (References) of
the Inventory and available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-
2022-chapter-10-references.pdf.

5.1.8 Flooded Land Remaining Flooded Land (NIR Section 6.8)

5.1.8.1	Background

Flooded lands are defined as 1) waterbodies where human activities have caused changes in the amount of
surface area covered by water, typically through water level regulation (e.g., constructing a dam); 2) waterbodies
where human activities have changed the hydrology of existing natural waterbodies, thereby altering water
residence times and/or sedimentation rates, in turn causing changes to the natural emission of greenhouse gases;
and 3) waterbodies that have been created by excavation, such as canals, ditches, and ponds (IPCC 2019). Flooded
lands include waterbodies with seasonally variable degrees of inundation, but these waterbodies would be
expected to retain some inundated area throughout the year under normal conditions.

Flooded lands are broadly classified as "reservoirs" or "other constructed waterbodies" (IPCC 2019).

Reservoirs are defined as flooded land greater than 8 hectares and include the seasonally flooded land on the
perimeter of permanently flooded land (i.e., inundation areas). IPCC guidance (IPCC 2019) provides default
emissions factors for reservoirs and several types of "other constructed waterbodies" including freshwater ponds
and canals/ditches.

Land that has been flooded for more than 20 years is defined as flooded land remaining flooded land and land
flooded for 20 years or less is defined as land converted to flooded land. The distinction is based on literature
reports that Cm and CO2 emissions are high immediately following flooding (as labile organic matter is rapidly
degraded) but decline to a steady background level approximately 20 years after flooding. Emissions of Cm are
estimated for flooded land remaining flooded land, but CO2 emissions are not included as they are primarily the
result of decomposition of organic matter entering the waterbody from the catchment or contained in inundated
soils are included elsewhere in the IPCC guidelines (IPCC 2006).

5.1.8.2	Methods/Approach

The EPA compiles state-level emissions from flooded land remaining flooded land using the same methods
applied in the national Inventory. Please see the methodologies described in Chapter 6.8 (pages 6-115 through 6-
130) of the national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-
ghg-inventorv-2022-chapter-6-land-use-land-use-change-and-forestry.pdf. For this report, the state-level
estimates were developed using Approach 1. Estimates of emissions from reservoirs and associated inundation
areas and other constructed waterbodies that include freshwater ponds and canals/ditches include all states and
Washington D.C. but do not include Alaska or Hawaii due to lack of data.

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5.1.8.3	Uncertainty

The overall uncertainty associated with national estimates from reservoirs and associated inundation area and
other constructed waterbodies, including freshwater ponds and canals/ditches on flooded land remaining flooded
land, is described in Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022).
Uncertainty for both reservoirs and associated inundation area and other constructed waterbodies including
freshwater ponds and canals/ditches are developed using IPCC Approach 2. The total uncertainty for reservoirs
and associated inundation areas ranges from -1.8% to +2.6%, and the total uncertainty for other constructed
waterbodies including freshwater ponds and canals/ditches is -8% to +7.9%. State-level estimates of uncertainty
will vary significantly among the states but, in general, tend to be higher than those provided for the United States
in the national Inventory. For more details on national-level uncertainty, see the Uncertainty discussion in Section
6.8 of the national Inventory.

5.1.8.4	Recalculations

This is a new category, so the first year a time series of estimates are being included in the national Inventory
(starting page 6-115 of Section 6.8). Therefore, there are no recalculations were applied for this current report.

5.1.8.5	Planned Improvements

The planned improvements are anticipated to be the same as those planned for improving the national
estimates, given that the underlying methods for state GHG estimates are the same as those in the national
Inventory and will lead directly to improvements in the quality of state-level estimates as well. To review the
planned improvements to the methods and data for estimating emissions from flooded land remaining flooded
land, see the planned improvements discussion on pages 6-123 and 6-130 of Chapter 6.8 in the national Inventory.

5.1.8.6	References

IPCC 2006, 2006 IPCC Guidelines for National Greenhouse Gas Inventories, Prepared by the National Greenhouse
Gas Inventories Programme, Eggleston H.S., Buendia L, Miwa K., Ngara T. and Tanabe K. (eds). Published:

IGES, Japan.

IPCC 2019, 2019 Refinement to the 2006 IPCC Guidelines for National Greenhouse Gas Inventories, Calvo Buendia,
E., Tanabe, K., Kranjc, A., Baasansuren, J., Fukuda, M., Ngarize, S., Osako, A., Pyrozhenko, Y., Shermanau, P.
and Federici, S. (eds). Published: IPCC, Switzerland.

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of references included in Chapter 6.8 (for flooded land remaining flooded land) of the national
Inventory are available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-
2022-chapter-10-references.pdf.

5.1.9 Land Converted to Wetlands (NIR Section 6.9)

This section describes methods for estimating state-level CO2 and CFU emissions from management of
wetlands consistent with the national Inventory, specifically:

•	Lands converted to coastal wetlands (CO2 and CH4)

•	Land converted to flooded land (CO2 and CH4)

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5.1.9.1	Land Converted to Coastal Wetlands

5.1.9.2	Background

Land converted to vegetated coastal wetlands occurs as a result of inundation of unprotected low-lying
coastal areas with gradual sea-level rise, flooding of previously drained land behind hydrological barriers, and
through active restoration and creation of coastal wetlands through removal of hydrological barriers. Land use
conversions into coastal wetlands can result in carbon stock changes to all coastal wetland carbon pools (i.e.,
aboveground biomass, belowground biomass, dead wood, litter, and soil organic carbon) and emissions of Cm if
inundated with fresh water. This chapter provides estimates of CO2 and CH4 emission and removals resulting from
conversion of cropland, grassland, wetlands, settlements, and other lands to vegetated coastal wetlands.

5.1.9.3	Methods/Approach

To compile national estimates of carbon stock changes and Cm emissions from land converted to vegetated
coastal wetlands for the national Inventory, estimates for each state and the District of Columbia with coastal
wetlands were produced and summed into a national total. A description of the methods and data used to
estimate state-level emissions is provided in Chapter 6, Section 6.9 (pages 6-130 through 6-136), of the national
Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-
chapter-6-land-use-land-use-change-and-forestrv.pdf. Please note that estimates for Hawaii and Alaska are not
included in the national total or available at the state level at this time.

States (plus the District of Columbia) with coastal wetlands currently included in the national Inventory are
Alabama, California, Connecticut, Delaware, Florida, Georgia, Louisiana, Maine, Maryland, Massachusetts,
Mississippi, New Hampshire, New Jersey, New York, North Carolina, Oregon, Pennsylvania, Rhode Island, South
Carolina, Texas, Virginia, and Washington.

5.1.9.4	Uncertainty

Underlying uncertainties in estimates of soil C removal factors, biomass change, DOM, and CH4 emissions
include error in uncertainties associated with Tier 2 literature values of soil C removal estimates, biomass stocks,
DOM, and IPCC default CH4 emissions factors, uncertainties linked to interpretation of remote sensing data, as well
as assumptions that underlie the methodological approaches applied. IPCC Approach 1 (IPCC 2006) was used to
calculate these uncertainties. As described further in Chapter 6.9 of the national Inventory of U.S. Greenhouse Gas
Emissions and Sinks (EPA 2022), levels of uncertainty in the national estimates in 2020 for biomass carbon stock
change are (-20/+20%), dead organic matter carbon stock change are (-25.8/+25.8%), soil carbon stock change are
(-17.8/+17.8%) and CH4 emissions are (-29.9/+29.9%). The combined uncertainty across all subcategories
(-42.2/+42.2%). State-level estimates of uncertainty will vary significantly among the states but, in general, tend to
have a higher uncertainty than those provided for the United States in the national Inventory. For more details on
national-level uncertainty see the Uncertainty discussion in Section 6.9 of the national Inventory.

5.1.9.5	Recalculations

No recalculations were applied for this current report, consistent with the national Inventory (see Section 6.9,
page 6-136).

5.1.9.6	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for the state GHG estimates are the same as those in the national Inventory. To review the
planned improvements to the methods and data for estimating emissions and removals from land converted to
vegetated coastal wetlands, see the planned improvements discussions on page 6-136 of Chapter 6.9, in the
national Inventory.

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5.1.9.7	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of the references included in Chapter 6.9 (Lands Converted to Coastal Wetlands) of the national
Inventory are listed on pages 10-83 to 10-85 in Chapter 10 (References) of the Inventory and available online here:
https://www.epa.gov/system/files/documents/2022-04/us-ghg-inventorv-2022-chapter-10-references.pdf.

5.1.9.8	Land Converted to Flooded Land

5.1.9.9	Background

Land that has been flooded for less than 20 years is defined as land converted to flooded land. The distinction
is based on literature reports that CO2 and CH4 emissions are high immediately following flooding (as labile organic
matter is rapidly degraded) but decline to a steady background level approximately 20 years after flooding. Both
CO2 and Cm emissions are inventoried for both reservoirs and associated inundation areas and freshwater ponds
within the "other constructed waterbodies" subcategory of land converted to flooded land.

5.1.9.10	Methods/Approach

To compile national estimates of carbon stock changes and CH4 emissions from land converted to flooded land
for the national Inventory, estimates for each state and the District of Columbia were produced and summed into a
national total. A description of the methods and data used to estimate state-level emissions is provided in Chapter
6, Section 6.9 (pages 6-136 through 6-151), of the national Inventory, available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf. Please note that estimates for Hawaii and Alaska are not included in the national total or
available at the state level at this time.

5.1.9.11	Uncertainty

The overall uncertainty associated with national estimates of CO2 and CH4 from reservoirs and associated
inundation area and freshwater ponds on flooded land remaining flooded land is described in Chapter 6.9 of the
national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022). Uncertainty for both reservoirs and
associated inundation area and freshwater ponds is developed using IPCC Approach 2. The total uncertainty for
CO2 and CH4 emissions from reservoirs and associated inundation areas ranges from -13.1% to +16.0%, and the
total uncertainty for CO2 and CH4 emissions from freshwater ponds is -3.6 to +4.1%. State-level estimates of
uncertainty will vary significantly among the states but, in general, tend to be higher than those provided for the
United States in the national Inventory. For more details on national-level uncertainty, see the Uncertainty
discussion in Section 6.9 of the national Inventory.

5.1.9.12	Recalculations

This is a new category, so the first year a time series of estimates are being included in the national Inventory
(starting page 6-136 of Section 6.8). Therefore, there are no recalculations were applied for this current report.

5.1.9.13	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for the state GHG estimates are the same as those in the national Inventory. To review the
planned improvements to the methods and data for estimating emissions and removals from Land Converted to

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Flooded Land, see the planned improvements discussions on pages 6-145 and 6-151 of Chapter 6.9, in the national
Inventory.

5.1.9.14 References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestry.pdf

Full citations of the references included in Chapter 6.9 (for land converted to flooded land) of the national
Inventory are listed on page 10-88 in Chapter 10 (References) of the Inventory and available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-references.pdf.

5.1.10 Settlements Remaining Settlements (NIR Section 6.10)

This section presents methods used to estimate state-level CO2, CH4, and N2O emissions and removals from
settlements remaining settlements consistent with the national Inventory. Settlements are land uses where human
populations and activities are concentrated. The section is organized to address the following subcategories:

•	Carbon dioxide emissions from drained organic soils (CO2)

•	Changes in carbon stocks in settlement trees (CO2)

•	Nitrous oxide emissions from settlement soils (N2O)

•	Carbon stock changes in landfilled yard trimmings and food scraps (CO2)

5.1.10.1	Soil Carbon Stock Changes

5.1.10.2	Background

Soil organic C stock changes for settlements remaining settlements occur in both mineral and organic soils.
However, the United States does not estimate changes in soil organic C stocks for mineral soils in settlements
remaining settlements. This approach is consistent with the assumption of the Tier 1 method in the 2006 IPCC
Guidelines (IPCC 2006) that inputs equal outputs, and therefore the soil organic C stocks do not change. In
contrast, drainage of organic soils can lead to continued losses of C for an extended period of time.

Drainage of organic soils is common when wetland areas have been developed for settlements. Organic soils,
also referred to as Histosols, include all soils with more than 12 to 20% organic C by weight, depending on clay
content. The organic layer of these soils can be very deep (i.e., several meters), and form under inundated
conditions that results in minimal decomposition of plant residues. Drainage of organic soils leads to aeration of
the soil that accelerates decomposition rate and CO2 emissions. Due to the depth and richness of the organic
layers, C loss from drained organic soils can continue over long periods of time, which varies depending on climate
and composition (i.e., decomposability) of the organic matter. See Chapter 6 of the national Inventory for more
information (EPA 2022).

5.1.10.3	Methods/Approach

The EPA compiles state-level estimates of soil carbon stock changes using the same methods applied in the
national Inventory. Please see the methodologies described in Chapter 6, Section 6.10 (pages 6-152 through 6-
155), of the national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-
ghg-inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf. The EPA used a hybrid Approach 1 and
Approach 2 for state-level estimates. The current national Inventory includes state-level emissions for the years
1990-2015 for soil organic C stock changes. The remaining years in the time series were only estimated at the
national scale using a linear extrapolation method, and a two-step process was used to approximate the state-level

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emissions for the remaining years. First, the average proportion of the total national emissions was computed for
each state from 2013-2015. Second, the state-level proportions were multiplied by the total national emissions to
approximate the amount of emissions occurring in each state for 2016-2020. Estimates are included for all states
with the exception of Alaska.

5.1.10.4	Uncertainty

The overall uncertainty associated with national estimates from Soil Carbon Stock Changes is described in
Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022). Uncertainty for the
Tier 2 approach is derived using a Monte Carlo approach. The uncertainty for total Soil Carbon Stock Changes in
2020 ranged from -53% to +53%.

5.1.10.5	Recalculations

No recalculations were applied for this current report, consistent with the national Inventory (see Section 6.9,
page 6-154).

5.1.10.6	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for the state GHG estimates are the same as those in the national Inventory. To review the
planned improvements to the methods and data for estimating emissions and removals from Soil Carbon Stock
Changes, see the planned improvements discussions on pages 6-154 and 6-155 of Chapter 6.10, in the national
Inventory.

5.1.10.7	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestry.pdf

Full citations of the references included in Chapter 6.10 (for soil carbon stock changes) of the national
Inventory are listed on pages 10-88 to 10-89 in Chapter 10 (References) of the Inventory and available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-references.pdf.

5.1.10.8	Changes in Carbon Stocks in Settlement Trees

5.1.10.9	Background

In settlement areas, the anthropogenic impacts on tree growth, stocking and mortality are particularly
pronounced (Nowak 2012) in comparison to forest lands where non-anthropogenic forces can have more
significant impacts. Trees in settlement areas of the United States are a significant sink over the time series.
Dominant factors affecting carbon flux trends for settlement trees are changes in the amount of settlement area
(increasing sequestration due to more settlement lands and trees) and net changes in tree cover (e.g., tree losses
vs tree gains through planting and natural regeneration), with percent tree cover trending downward recently. In
addition, changes in species composition, tree sizes and tree densities affect base C flux estimates. Annual
sequestration increased by 35% between 1990 and 2020 due to increases in settlement area and changes in tree
cover. Trees in settlements often grow faster than forest trees because of their relatively open structure (Nowak
and Crane 2002). Because tree density in settlements is typically much lower than in forested areas, the C storage
per hectare of land is in fact smaller for settlement areas than for forest areas. Also, percent tree cover in
settlement areas are less than in forests and this tree cover varies significantly across the United States (e.g.,
Nowak and Greenfield 2018a).

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5.1.10.10	Methods/Approach

To compile national estimates of CO2 emissions and removals from carbon stock changes from settlement
trees for the national Inventory, estimates for all 50 states and the District of Columbia were produced and
summed into a national total. In this case, the EPA is applying an Approach 1 method (i.e., using methods
consistent with the national Inventory). A description of the methods and data used to estimate changes in carbon
stocks in settlement trees is found in Chapter 6, Section 6.10 (pages 6-155 through 6-162), of the national
Inventory (EPA 2022), available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf.

5.1.10.11	Uncertainty

Uncertainty associated with changes in C stocks in settlement trees includes the uncertainty associated with
settlement area, percent tree cover in developed land and how well it represents percent tree cover in settlement
areas and estimates of gross and net C sequestration for each of the 50 states and the District of Columbia.
Additional uncertainty is associated with the biomass models, conversion factors, and decomposition assumptions
used to calculate C sequestration and emission estimates (Nowak et al. 2002). These results also exclude changes
in soil C stocks, and there is likely some overlap between the settlement tree C estimates and the forest tree C
estimates (e.g., Nowak et al. 2013). IPCC Approach 2 (IPCC 2006) was used to calculate these uncertainties. As
described further in Chapter 6.10 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022),
levels of uncertainty in the national estimates in 2020 for carbon stock change are (-51/+52%). State-level
estimates of uncertainty will vary significantly among the states but, in general, tend to have a higher uncertainty
than those provided for the United States in the national Inventory. For more details on national-level uncertainty
see the Uncertainty discussion in Section 6.10 of the national Inventory.

5.1.10.12	Recalculations

No recalculations were applied for this current report, consistent with the national Inventory (see Section 6.9,
page 6-162).

5.1.10.13	Planned Improvements

The planned improvements are consistent with those planned for improving national estimates given that the
underlying methods for state GHG estimates are the same as those in the national Inventory. To review planned
improvements to refine methods for estimating changes in Settlement trees carbon stocks, see the planned
improvements discussion on page 6-162 of Section 6.10 in the national Inventory for a description of future work
to further refine these estimates.

5.1.10.14	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of the references included in Chapter 6.10 (for changes in carbon stocks in settlement trees) of
the national Inventory are listed on pages 10-89 to 10-90 in Chapter 10 (References) of the Inventory and available
online here: https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-
references.pdf.

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5.1.10.15	N20 Emissions from Settlement Soils

5.1.10.16	Background

Of the synthetic N fertilizers applied to soils in the United States, approximately 1% to 2% are currently
applied to lawns, golf courses, and other landscaping within settlement areas, and contributes to soil N2O
emissions. The area of settlements is considerably smaller than other land uses that are managed with fertilizer,
particularly cropland soils, and therefore, settlements account for a smaller proportion of total synthetic fertilizer
application in the United States. In addition to synthetic N fertilizers, a portion of surface applied biosolids (i.e.,
treated sewage sludge) is used as an organic fertilizer in settlement areas, and drained organic soils (i.e., soils with
high organic matter content, known as Histosols) also contribute to emissions of soil N2O.

N additions to soils result in direct and indirect N2O emissions. Direct emissions occur on-site due to the N
additions in the form of synthetic fertilizers and biosolids as well as enhanced mineralization of N in drained
organic soils. Indirect emissions result from fertilizer and biosolids N that is transformed and transported to
another location in a form other than N2O (i.e., ammonia [NH3] and nitrogen oxide [NOx] volatilization, nitrate
[NO3-] leaching and runoff), and later converted into N2O at the offsite location. The indirect emissions are
assigned to settlements because the management activity leading to the emissions occurred in settlements (EPA
2022)

5.1.10.17	Methods/Approach

The EPA compiles state-level estimates of N2O Emissions from Settlement Soils using the same methods
applied in the national Inventory. Please see the methodologies described in Chapter 6, Section 6.10 (pages 6-162
through 6-165) of the national Inventory available online here:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestry.pdf. The EPA applied a hybrid Approach 1 and Approach 2 for state-level estimates. The
current national Inventory includes state-level emissions for the years 1990-2015 for synthetic N and N inputs
from drained organic soils. The remaining years in the time series were only estimated at the national scale using a
surrogate data method, and a two-step process was used to approximate the state-level emissions for the
remaining years. First, the average proportion of the total national emissions was computed for each state from
2013-2015. Second, the state-level proportions were multiplied by the total national emissions to approximate the
amount of emissions occurring in each state for 2016-2020. Soil N2O emissions for additions of biosolid N are only
estimated at the national scale for the entire time series. For this source of N, soil N2O emissions were
disaggregated to the state level based on the proportion of the U.S. population occurring in each state. Estimates
are included for all states with the exception of Alaska.

5.1.10.18	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 6.10 of the national Inventory (page 6-165), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well.

5.1.10.19	Uncertainty

The overall uncertainty associated with national estimates from N2O emissions from Settlement Soils is
described in Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022). As
described:

• The amount of N2O emitted from settlement soils depends not only on N inputs and area of drained
organic soils, but also on a large number of variables that can influence rates of nitrification and
denitrification, including organic C availability; rate, application method, and timing of N input; oxygen gas

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partial pressure; soil moisture content; pH; temperature; and irrigation/watering practices. The effect of
the combined interaction of these variables on N2O emissions is complex and highly uncertain. The IPCC
default methodology does not explicitly incorporate any of these variables, except variation in the total
amount of fertilizer N and biosolids application, which in turn, leads to uncertainty in the results.

• Uncertainties exist in both the fertilizer N and biosolids application rates in addition to the emissions
factors. Uncertainty in the area of drained organic soils is based on the estimated variance from the NRI
survey. For biosolids, there is uncertainty in the amounts of biosolids applied to nonagricultural lands and
used in surface disposal. These uncertainties are derived from variability in several factors, including: (1) N
content of biosolids; (2) total sludge applied in 2000; (3) wastewater existing flow in 1996 and 2000; and
(4) the biosolids disposal practice distributions to nonagricultural land application and surface disposal. In
addition, there is uncertainty in the direct and indirect emissions factors that are provided by IPCC (2006).

Uncertainty is propagated through the calculations of N2O emissions from fertilizer N and drainage of organic soils
based on a Monte Carlo analysis. The overall levels of uncertainty for national Inventory Direct N2O Emissions from
Soils and Indirect N2O Emissions are -38/+22% and -38/+38%, respectively.

5.1.10.20	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for the state GHG estimates are the same as those in the national Inventory. To review the
planned improvements to the methods and data for estimating N2O emissions from settlement soils, see the
planned improvements discussions on page 6-165 of Chapter 6.10 in the national Inventory.

5.1.10.21	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of the references included in Chapter 6.10 (for N2O emissions from soils) of the national
Inventory are listed on page 10-90 in Chapter 10 (References) of the Inventory and available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-references.pdf.

5.1.10.22	Changes in Yard Trimmings and Food Scrap Carbon Stocks in Landfills

5.1.10.23	Background

In the United States, yard trimmings (i.e., grass clippings, leaves, and branches) and food scraps account for a
significant portion of the municipal waste stream, and a large fraction of the collected yard trimmings and food
scraps are put in landfills. Carbon (C) contained in landfilled yard trimmings and food scraps can be stored for very
long periods. Carbon stock changes in yard trimmings and food scraps and associated CO2 emissions and removals
are reported under settlements remaining settlements because the bulk of the C, which comes from yard
trimmings, originates from settlement areas. While the majority of food scraps originate from cropland and
grassland, in the national Inventory they are reported with the yard trimmings in the Settlements Remaining
Settlements section. Additionally, landfills are considered part of the managed land base under settlements and
reporting these C stock changes that occur entirely within landfills fits most appropriately in the Settlements
Remaining Settlements section.

5.1.10.24	Methods/Approach

State-level carbon stocks were compiled using Approach 2, by allocating net national changes in carbon stocks
and associated emissions and removals to states, the District of Columbia, and territories based on the state's

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fraction of total U.S. land area classified as urban area. "Urban area" is defined by the U.S Department of
Agriculture as land area containing densely populated areas with at least 50,000 people (urbanized areas) and
densely populated areas with 2,500 to 50,000 people (urban clusters). The EPA assumed "Urban area" matched
the definition of "settlements area" for the purpose of state-level estimates. This approach was applied due to
unavailability of state-level activity data on mass of yard trimmings and food scraps discarded to managed landfills,
and the assumption that most yard trimmings and food scraps would be generated in densely populated areas.
The EPA used settlement area estimates from the U.S. Department of Agriculture Economic Research Service's
Major Land Uses data. The total settlements area in the United States includes all U.S. states and the District of
Columbia but excludes territories such as Puerto Rico. See Appendix E for time series information underlying the
estimates.

State emissions were calculated using the following stepwise process:

1.	The EPA obtained U.S. settlements area data from the U.S Department of Agriculture (USDA 2017).

2.	The fraction of total settlements area was calculated for each state, including the District of Columbia, by
dividing the state settlements area by the U.S. total settlements area.

3.	The state fraction of settlements area was multiplied by the total national yard trimmings and food scraps
carbon stocks from the 1990-2020 Inventory to estimate state-level yard trimmings and food scraps
carbon stocks. This calculation was also performed for grass, leaves, branches, and food scraps to yield
state-level carbon stocks for each subcategory.

5.1.10.25	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CChfrom Changes in Yard Trimmings
and Food Scraps Carbon Stocks were calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC
2006). As described further in Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA
2022), levels of uncertainty in the national estimates in 2020 were CO2 (-68/+56%). State-level estimates have a
higher uncertainty due to apportioning the national estimates to states based on fraction of settlements area.
These assumptions were required because of a general lack of available state-level data for peat production. For
more details on national-level uncertainty, see the Uncertainty discussion in Section 6.10 of the national Inventory.

5.1.10.26	Recalculations

EPA revised its methodology to allocate national-level yard trimmings and food scraps carbon stocks to the
states based on review comments received during the previous state Inventory cycle. The revised allocation is
based on the state fraction of land area classified as settlements, rather than the state population from the U.S.
Census. This change resulted in states with a higher ratio of urban area to total land area to have an increase in
carbon stocks, and states with a lower ratio of urban area to total land area to have a decrease in carbon stocks.

5.1.10.27	Planned Improvements

The EPA will review and revise the state-level methodology over the time series, and as appropriate, assess if
other information would better reflect state-level activity (e.g., mass of yard trimmings and food scraps discarded
to managed landfills) to improve the accuracy of the estimates. Sources of settlements area data for Puerto Rico
and other U.S. territories are also needed to provide a more accurate estimate of net carbon stock changes in the
U.S. Additional planned improvements are consistent with those planned for improving national estimates given
that the underlying methods for state GHG estimates are the derived from those in the national Inventory. The
discussion of planned improvements to refine methods for estimating changes in carbon stocks in landfilled yard
trimmings at the national level starts on pp. 6-165 of Chapter 6.1 in the national Inventory.

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5.1.10.28 References

USDA. (August 2017). Urban Area, 1945-2012, by State: Densely-populated areas with at least 50,000 people

(urbanized areas) and densely-populated areas with 2,500 to 50,000 people (urban clusters). U.S. Department
of Agriculture, Economic Research Service. Available at: https://www.ers.usda.gov/data-products/maior-land-
uses/

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

Full citations of all other relevant references to estimating landfilled yard trimmings and food scraps carbon
stock changes included in Chapter 6.10 (Settlements Remaining Settlements) are listed in Chapter 10 (References)
of the national Inventory on pages 10-90 to 10-91 and available online at

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-10-references.pdf.
5.1.11 Land Converted to Settlements (NIR Section 6.11)

5.1.11.1	Background

Land converted to settlements includes all settlements in an inventory year that had been in another land
use(s) during the previous 20 years. For example, cropland, grassland, or forest land converted to settlements
during the past 20 years would be reported in this category. Converted lands are retained in this category for 20
years as recommended by IPCC (2006). The national Inventory includes all settlements in the conterminous United
States and Hawaii but does not include settlements in Alaska. Areas of drained organic soils on settlements in
federal lands are also not included in the national Inventory.

Land use change can lead to large losses of carbon (C) to the atmosphere, particularly conversions from forest
land. Moreover, conversion of forest to another land use (i.e., deforestation) is one of the largest anthropogenic
sources of emissions to the atmosphere globally, although this source may be declining globally according to a
recent assessment.

The IPCC (2006) recommends reporting changes in biomass, dead organic matter, and soil organic C stocks due
to land use change. All soil organic C stock changes are estimated and reported for land converted to settlements,
but there is limited reporting of other pools in the national Inventory. Loss of aboveground and belowground
biomass, dead wood and litter C are reported for forest land converted to settlements, but not for other land use
conversions to settlements (EPA 2022).

5.1.11.2	Methods/Approach

The EPA compiles state-level estimates of land converted to settlements using the same methods applied in
the national Inventory. Please see the methodologies described in Chapter 6, Section 6.10 (pages 6-172 through 6-
178) of the national Inventory, available online here: https://www.epa.gov/svstem/files/documents/2022-04/us-
ghg-inventorv-2022-chapter-6-land-use-land-use-change-and-forestrv.pdf. The EPA used a hybrid Approach 1 and
Approach 2 for state-level estimates. The current national Inventory includes state-level emissions for the years
1990-2020 for biomass, standing dead, deadwood, and litter, and for the years 1990-2015 for soil organic C stock
changes. The remaining years in the time series for soil organic C stock changes were only estimated at the
national scale using a surrogate data method, and a two-step process was used to approximate the state-level
emissions for the remaining years. First, the average proportion of the total national emissions was computed for
each state from 2013-2015. Second, the state-level proportions were multiplied by the total national emissions to
approximate the amount of emissions occurring in each state for 2016-2020. Estimates are included for all states
with the exception of Alaska.

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5.1.11.3	Uncertainty

The overall uncertainty associated with national estimates from land converted to settlements is described in
Chapter 6 of the national Inventory of U.S. Greenhouse Gas Emissions and Sinks (EPA 2022). As described:

•	The uncertainty analysis for C losses with forest land converted to settlements is conducted in the same
way as the uncertainty assessment for forest ecosystem C flux in the Forest Land Remaining Forest Land
category. For additional details, see the Uncertainty Analysis in Annex 3.13.

•	The uncertainty analysis for mineral soil organic C stock changes and annual C emission estimates from
drained organic soils in land converted to settlements is estimated using a Monte Carlo approach, which is
also described in the Cropland Remaining Cropland section.

The overall level of uncertainty for national Inventory land converted to settlements estimates is -34/+34%.

5.1.11.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 6.11 of the national Inventory (page 6-177), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well.

5.1.11.5	Planned Improvements

The planned improvements are consistent with those planned for improving the national estimates given that
the underlying methods for the state GHG estimates are the same as those in the national Inventory. To review the
planned improvements to the methods and data for estimating emissions and removals from land converted to
settlements, see the planned improvements discussions on pages 6-177 and 6-178 of Chapter 6.10, in the national
Inventory.

5.1.11.6	References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestry.pdf

Full citations of the references included in Chapter 6.11 (Land Converted to Settlements) of the national
Inventory are listed on pages 10-91 to 10-93 in Chapter 10 (References) of the Inventory and available online here:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-10-references.pdf.

5.1.12 Other Land Remaining Other Land (NIR Section 6.12) and Land Converted to Other
Land (NIR Section 6.13)

Other Land is a land-use category that includes bare soil, rock, ice, and all land areas that do not fall into any of
the other five land-use categories (i.e., forest land, cropland, grassland, wetlands, and settlements). Following the
guidance provided by the IPCC (2006), C stock changes and non-CC>2 emissions are not estimated for other land
because these areas are largely devoid of biomass, litter, and soil C pools. However, C stock changes and non-CC>2
emissions are estimated for land converted to other land during the first 20 years following conversion to account
for legacy effects. While the magnitude of these area changes is known (see national Inventory, page 6-11, Table 6-
5), research is ongoing to track C across other land remaining other land and land converted to other land. Until
reliable and comprehensive estimates of C across these land-use and land-use change categories can be produced,
it is not possible to separate CO2, CFU, or N2O fluxes on land converted to other land from fluxes on other land
remaining other land. Emissions and removals from other lands and lands converted to other lands will be included
in future versions of this publications when they are integrated into the national Inventory. See Chapters 6.12 and
6.13 on pages 6-178 to 6-179 of the national Inventory (EPA 2022).

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5.1.12.1 References

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 6: Land Use, Land-Use Change, and Forestry. Washington, DC. Available online at:
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2Q22-chapter-6-land-use-land-use-
change-and-forestrv.pdf

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6 Waste (NIR Chapter 7)

For this methodology report, the Waste chapter consists of two subsectors: Solid Waste Disposal and
Wastewater Treatment and Discharge. More information on national-level emissions and methods is available in
Chapter 7 of the national Inventory. Note that emissions from waste incineration are discussed in Section 2.1.4 of
this methodology report. Table 6-1 summarizes the different approaches used to estimate state-level waste
emissions and completeness across states. Geographic completeness is consistent with the national Inventory. The
sections below provide more detail on each category.

Table 6-1. Overview of Approaches for Estimating State-Level Waste Sector Greenhouse Gas Emissions
and Sinks

Category

Gas

Approach

Geographic Completeness

Landfills

ch4

Approach 2

Includes emissions from all states, Washington D.C., and
territories (i.e., Guam, Puerto Rico) as applicable.

Wastewater

ch4/ n2o

Approach 2

Includes emissions from all states, Washington D.C. and
territories1 (i.e., Guam, Puerto Rico, US Virgin Islands, and
Northern Mariana Islands for domestic wastewater).

Composting

ch4, n20

Approach 2

Includes emissions from all states, Washington D.C., and
territories as applicable.

Standalone

ch4

Approach 2

Includes emissions from all states, Washington D.C., and

Anaerobic Digestion





territories as applicable.

1 Emissions are likely occurring in other U.S. territories; however, due to a lack of available data and the nature of this category,
this analysis includes emissions for only the territories indicated. Territories not listed are not estimated.

6.1 Solid Waste Disposal

This section presents the methodology used to estimate the emissions from solid waste disposal management
activities, which consist of the following sources:

•	Landfills (MSW and industrial waste) (Cm)

•	Composting (CH4, N2O)

•	Stand-alone anaerobic digestion at biogas facilities (Cm)

6.1.1 Landfills (NIR Section 7.1)

6.1.1.1 Background

After being placed in a landfill, organic waste (such as paper, food scraps, and yard trimmings) is initially
decomposed by aerobic bacteria. After the oxygen has been depleted, the remaining waste is available for
consumption by anaerobic bacteria, which break down organic matter into substances such as cellulose, amino
acids, and sugars. These substances are further broken down through fermentation into gases and short-chain
organic compounds that form the substrates for the growth of methanogenic bacteria. These CH4-producing
anaerobic bacteria convert the fermentation products into stabilized organic materials and biogas consisting of
approximately 50% biogenic CO2 and 50% Cm, by volume. Methane and CChare the primary constituents of
landfill gas generation and emissions. Consistent with the 2006 IPCC Guidelines, net CO2 flux from carbon stock
changes in landfills are estimated and reported under the LULUCF sector (see Chapter 5 of this report) (IPCC 2006).

More information on emission pathways and national-level emissions from landfills and associated methods
can be found in the Waste chapter (Chapter 7), Section 7.1 of the national Inventory available online at
https://www.epa.gov/system/files/documents/2022-04/us-ghg-inventorv-2022-chapter-7-waste.pdf

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6.1.1.2 Methods/Approach (Municipal Solid Waste Landfills)

The MSW landfill state emissions inventories applied Approach 2 for disaggregating national estimates and
relied heavily on the subpart HH data collected through the GHGRP. As explained in the methodology discussion of
Section 7.1 of the national Inventory, the EPA uses an IPCCTier 2 approach and several data sources, methods, and
assumptions to estimate emissions (see pp. 7-7 through 7-12 for details on the inputs and equations). The state
inventories applied a state percentage of either waste landfilled or net Cm emissions by state as reported to
subpart HH (EPA 2021a) as a proxy for each state's share of CH4 net emissions over the time series. Table 6-2
below summarizes the methodology used to develop the state-level estimates, followed by additional detail. The
annual state percentages were applied to the national estimates to retain an IPCC Tier 2 approach consistent with
the national Inventory.

Table 6-2. Summary of Approaches to Disaggregate the National Inventory for MSW Landfills Across Time
Series

Time Series Range

Summary of Method

2010-2020

•	Applied the percentage of net CH4 emissions by state (aggregated total as
reported by landfills in each state to subpart HH) to the national CH4 net
emissions for each year.

•	The state percentage approach accounts for all emissions, including those
calculated by scaling up emissions to account for smaller landfills that do not
report through subpart HH.

1990-2009

•	Applied the percentage of waste landfilled by state (aggregated total as reported
by landfills in each state to subpart HH for historical years) to the national CH4 net
emissions for each year (IPCC 2006 Tier 2).

•	The state percentage approach accounts for all emissions, including those that
were calculated in the national Inventory through back-casting subpart HH data
and scaling up emissions to account for smaller landfills that do not report
through subpart HH.

Historical waste disposed of since a facility began operating is reported using prescribed methods in the rule
to maintain consistency across the facility data. The quantity of waste landfilled by subpart HH reporters was
assumed to be representative of the universe of MSW landfills in the United States because subpart HH reporters
include each state's highest emitting MSW landfills, which is directly tied to the quantity of waste landfilled. The
national Inventory methodology back-casts subpart HH net CH4 emissions and uses a scale-up factor to account for
lower-emitting MSW landfills (e.g., non-reporters). The intent of the scale-up factor is to estimate CH4 emissions
from MSW landfills that do not report to the GHGRP. The national Inventory team has put significant effort into
identifying landfills that do not report to the GHGRP, most recently in 2021. Basic landfill characteristics such as
the landfill name and location, first year of operation, current operational status, and waste-in-place data have
been compiled for these landfills, when available. Disaggregating the subpart HH data by state was determined to
be a reasonable assumption considering the lack of historical data for landfills that do not report to the GHGRP.

The methodology for 2010-2020 applies a state percentage of net CH4 emissions reported by landfills under
subpart HH to the national estimates of CH4 emissions. Using net CH4 emissions is consistent with the recent
methodological refinements in the national Inventory to incorporate reported subpart HH net CH4 emissions.

Unlike the national Inventory, scale-up factors for each state were not developed. Developing state-specific scale-
up factors would require significant effort; instead, the national emissions values are disaggregated by a proxy that
is assumed to be generally representative of state-by-state emissions.

The methodology used for 1990-2009 applies a state percentage of waste landfilled for this time frame as
reported by landfills under subpart HH of the GHGRP to the national estimates of CH4 emissions. Approximately

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1,200 MSW landfills have reported to the GHGRP since reporting began in 2010. This approach disaggregates
national net emissions values by applying the state percentage as a proxy of net emissions.

Emissions from managed landfills located in Puerto Rico and Guam were included because facilities in these
territories report to subpart HH.

6.1.1.3 Methods/Approach (Industrial Landfills)

The EPA estimates Cm emissions from industrial waste landfills for two industry categories consistent with the
national Inventory: pulp and paper and food and beverage. Data reported to the GHGRP on industrial waste
landfills suggest that most of the organic waste that would result in methane emissions is disposed of at pulp and
paper and food processing facilities. Information on both industry categories with respect to the amount of waste
generated and disposed of in a dedicated industrial waste landfill is limited; thus, the EPA uses a Tier 1 approach to
estimate Cm emissions. Additionally, no comprehensive list of industrial waste landfills exists. While the
information is available in the Waste Business Journal (WBJ), the quality of the data is unknown and the date of
data related to each waste management facility included is also unknown. Therefore, the EPA does not have
information on the number of industrial waste landfills that were operational over the time series and information
regarding the number of industrial waste landfills located in each state. The types and amounts of waste disposed
of in the operational industrial waste landfills are also limited.

A portion of pulp and paper mills in the United States report to subpart TT (Industrial Waste Landfills) of the
GHGRP. Previous analyses of the 2016 pulp and paper emissions from the GHGRP (RTI 2018) showed that total
subpart TT emissions from facilities associated with a pulp and paper NAICS code generally align (within
approximately 10 to 20%) of the national Inventory's national estimate of emissions from the pulp and paper
manufacturing sector. On the other hand, a small number of facilities associated with a food and beverage NAICS
code report to subpart TT, and emissions are vastly different between subpart TT and the national Inventory.

Because of the data limitations described above, Approach 2 was used to disaggregate the national Inventory
CH4 emissions for both industry categories, rather than a more detailed facility-specific bottom-up approach.

Pulp and Paper Manufacturing

For the pulp and paper source category, we extracted a state-by-state count of mills in the United States from
two sources: DataBasin for 2008 and MillsOnline for 2015-2016. The count of facilities is approximately 233 and
332 from DataBasin and MillsOnline, respectively. The count and percentage of mills by state are shown in
Appendix F (Table F-l). The Industrial Resources Council states that 430 pulp and paper mills are operational in the
United States, although the exact year of this data is unknown and no state-specific counts are provided. According
to the Industrial Resources Council, mills are located in 41 states except Alaska, Colorado, North Dakota, Nebraska,
Nevada, Rhode Island, South Dakota, Utah, and Wyoming. For comparison, the subpart TT pulp and paper facilities
across the 2011-2019 reporting years represent a maximum of 92 facilities located across 21 states.

To estimate CH4 generation and CH4 emissions, the DataBasin 2008 percentages by state were applied to the
national Inventory estimate for the pulp and paper manufacturing sector for 1990-2010, and the MillsOnline
2015-2016 percentages by state were applied for 2011-2020. This approach assumes broadly that each facility is
generating an equal amount of waste that is landfilled and, therefore, an equal amount of CH4 emissions.
Consistent with the national Inventory, this assumption and approach were used in an attempt to ensure
completeness in coverage of industrial waste landfills in the United States because the subpart TT pulp and paper
facilities may not equal the total number of pulp and paper facilities disposing of waste in dedicated industrial
waste landfills. The exact number of pulp and paper manufacturing facilities that dispose of waste in industrial
waste landfills is unknown.

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Methane emissions from the pulp and paper sector were disaggregated by applying the percentage of the
mills by state as a proxy of facilities generating and disposing of waste in industrial waste landfills. No additional
calculations were performed, and the IPCC Tier 1 methodology (IPCC 2006) used to generate the national
emissions estimates was applied by default.

Food and Beverage Manufacturing

Minimal data are available to characterize the amounts and types of waste generated nationally from food
and beverage manufacturers and disposed of in industrial waste landfills. Less is known about the number of
facilities in each state that disposed of waste in a dedicated industrial landfill.

A similar approach using a count of assumed industrial food and beverage manufacturing facilities that dispose
of waste in an industrial waste landfill by state was applied to the national food and beverage category estimates.
The list of food and beverage manufacturing facilities consists of 13 NAICS codes as shown in Appendix F (Table F-
2) comprising 9,175 facilities (can be shared upon request). This list was extracted from the EPA Excess Food
Opportunities database (2021 update [EPA 2021b]).

The EPA Excess Food Opportunities database includes a low- and high-end estimate of the amount of excess
food generated (tons/year). These data were not used in the methodology. Rather, the average percentage of the
amount of excess food generated by each state across the selected NAICS codes was used as a proxy for the share
of CFUgeneration and emissions estimates. The same approach used for the pulp and paper manufacturing sector
was applied whereby the average percentage of excess food by state was applied to the national total amount of
Cm generation and CFU emissions for each year of the time series. This is a broad assumption but allows for the
calculation of emissions with limited knowledge on the location of facilities disposing of food waste into industrial
waste landfills.

The percentage of excess food generated by state is presented in Appendix F (see Table F-3). Note that the
Excess Food Opportunities database and map do not indicate the management pathway for the excess food. The
EPA Facts and Figures methodology (EPA 2020) also does not include an estimation of the amount of excess food
being disposed of in industrial waste landfills. Therefore, the percentage of waste disposed of is likely
overrepresented for some states and is why the estimates for the District of Columbia, the Virgin Islands, and
Puerto Rico have been zeroed out.

6.1.1.4 Uncertainty

The overall uncertainty associated with the 2020 national estimates of Cl-Ufrom MSW and industrial waste
landfills was calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As described further
in Chapter 7 of the national Inventory (EPA 2022), levels of uncertainty in the national estimates in 2020 were
-22%/+31% of the estimated CFU emissions for MSW landfills and -31%/+25% of the estimated CFU emissions for
industrial waste landfills.

State-level estimates likely have a higher uncertainty due to apportioning the national emissions estimates to
each state based on assumptions made to disaggregate the national emissions estimates based on state
percentages as reported to the GHGRP and the application of the scale-up factor to nationally compiled landfill gas
recovery databases used in the national Inventory. Additionally, state-level estimates before the GHGRP began
(i.e., before 2010) may have more uncertainty than state-level estimates after the GHGRP began (i.e., 2010 and
afterward). For more details on national-level uncertainty see the uncertainty discussion in Section 7.2 of the
national Inventory at the link provided in the Background discussion above.

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6.1.1.5	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 7.1 of the national Inventory (pages 7-16 and 7-17), given that improvements in the national Inventory will
lead directly to improvements in the quality of state-level estimates as well.

6.1.1.6	Planned Improvements

Potential refinements to landfill estimation methods include the following:

MSW Landfills

•	Planned improvements to the state-level estimates are consistent with those presented in Section 7.1 of
the national Inventory. In particular, the EPA plans to improve completeness of emissions from all waste
management practices (i.e., open dumpsites) in U.S. territories by identifying data and applying methods
to include emissions from open dumpsites in territories.

Industrial Waste Landfills

•	Identifying a more a complete and comprehensive list of pulp and paper facilities in the United States,
including years of operation since 1990. Further quality control on this inventory will be performed by
comparing the counts of industrial waste landfills by state in available datasets.

6.1.1.7	References

Data Basin. (2008). Available online at:

https://databasin.org/maps/new/#datasets=lf2a22eelaa441568cbf5bealb275c88.

Industrial Resources Council. Available online at:

http://www.industrialresourcescouncil.org/lndustrvSector/PulpPaperManufacturing/tabid/374/Default.aspx.

Intergovernmental Panel on Climate Change (IPCC). (2006). 2006IPCC Guidelines for National Greenhouse Gas
Inventories. Volume 3: Waste, Chapter 4: Solid Waste Disposal. The National Greenhouse Gas Inventories
Programme, The Intergovernmental Panel on Climate Change, H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara,
and K. Tanabe (eds.). Hayama, Kanagawa, Japan. Available online at: https://www.ipcc-
nggip.iges.or.jp/public/2006gl/pdf/5 Volume5/V5 3 Ch3 SWDS.pdf>.

MillsOnline. MillsOnline filterable list of pulp and paper mills. Available online at:
https://cpbis.gatech.edu/data/mills-online.

RTI International. (October 12, 2018). Comparison of industrial waste data reported under Subpart TT and the Solid
Waste chapter of the GHG Inventory. Memorandum prepared by K. Bronstein, B. Jackson, and M. McGrath for
R. Schmeltz (EPA).

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 7: Waste. Washington, DC. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-7-waste.pdf

U.S. Environmental Protection Agency. (2021a). Greenhouse Gas Reporting Program (GHGRP). 2021 Envirofacts
Data. Subpart HH: Municipal Solid Waste Landfills.

U.S. Environmental Protection Agency. (2021b). EPA Excess Food Opportunities database, 2021 update. Available
online at: https://www.epa.gov/sustainable-management-food/excess-food-opportunities-map

U.S. Environmental Protection Agency. (2020). Advancing Sustainable Materials Management: Facts and Figures
2018. December 2020. Available online at: https://www.epa.gov/sites/production/files/2020-
ll/documents/2018 tables and figures fnl 508.pdf

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6.1.2 Composting (NIR Section 7.3)

6.1.2.1	Background

This section presents methods used to estimate state-Level GHGs from large-scale commercial composting
facilities that typically include sections of the waste that operate in an anaerobic environment where degradable
organic carbon in the waste material is broken down, generating Cm and N2O. Even though CO2 emissions are
generated, they are not included in net GHG emissions for composting. Consistent with the national Inventory,
emissions from residential (backyard) composting are not included in the scope. Additionally, the national
Inventory assumes windrow is the composting method used, and the waste mixture is homogeneous, consisting
primarily of yard waste and some food. Annual throughput data on static and in-vessel commercial composting
methods were not identified in secondary (published) data. Consistent with the 2006 IPCC Guidelines, net CChflux
from carbon stock changes in waste material is estimated and reported under the LULUCF sector (see Chapter 5 of
this report) (IPCC 2006).

More information on emission pathways and national-level emissions from composting and associated
methods can be found in the Waste chapter (Chapter 7), Section 7.3 of the national Inventory available online at
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-7-waste.pdf.

6.1.2.2	Methods/Approach

The EPA compiles national CFU and N2O emissions estimates for commercial composting facilities in the United
States using an IPCC Tier 1 method by which an IPCC default emissions factor is applied to the national quantity of
material composted. No facility-specific information is used because it is generally unavailable over the time series.

The national Inventory was disaggregated to the state level using Approach 2 on the basis of data available for
the proportion of material composted by state for select years. Table 6-3 summarizes published state-level
estimates of material composted used in this inventory.

Table 6-3. Summary of Availability and Sources for Composting Data

Year Composting Data

Reference Abbreviation (for



Available for

Purposes of This Methodology)

Full Reference (Author Year)

2000

BioCycle 2001

Goldstein & Madtes 2001

2002

BioCycle 2004

Kaufman et al. 2004

2004

BioCycle 2006

Goldstein et al. 2006

2006

BioCycle 2008

Arsova et al. 2008

2008

BioCycle 2010

Arsova et al. 2010

2010

EREF 2016

Environmental Research & Education
Foundation 2016

2011

Shin 2014

Shin, 2014

2012

ILSR 2014

Institute for Local Self-Reliance 2014

2013

EREF2016

EREF2016

2016

WBJ 2016

Waste Business Journal 2016

2020

WBJ 2020

Waste Business Journal 2020

The state-level data were largely compiled from voluntary surveys of state agencies that reported MSW
generated and estimates by relevant management pathways (e.g., landfill, recycling, composting). Composting
estimates may be directly reported by the state agencies or estimated or adjusted by the report authors using the
best available information for available years. Occasionally, data for some states are not available and are
indicated as such in the data sources. The WBJ is an annually updated database of which the quality is unknown,

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but it is used because there is a general lack of data. Both the WBJ 2016 and 2020 were used to estimate state data
for 2017-2019. Completeness is one limitation with the available state data used.

The general methodology to estimate the annual quantity of waste composted per year is as follows:

Composteds = %s x Nc

where:

Composteds = the mass of material composted by state (tons/year)

%os	= the state percentage of material composted, calculated using available state data (%)

Nc	= the national estimate of material composted as reported in the EPA Advancing Sustainable

Materials Facts and Figures reports (tons/year) (EPA 2020)

The state percentages of material composted were calculated by dividing each state-reported amount of
waste composted by the total of all material composted for that year. The sum of all state-reported data is
referred to as national estimates by the report authors, but to avoid confusion with the Facts and Figures data, we
refer to this as the sum of state-reported data. Limitations with the state-reported survey data include its
voluntary nature and occasional missingness of state data for states that did not provide a survey response. The
report authors noted they made assumptions to estimate and adjust data to the extent possible. For years where
no state data were reported in a specific survey, the EPA estimated the data using the prior or next year of
available data. These gaps were minimal (i.e., five or fewer states for each survey year).

Because state data are only available for select years, interpolation and extrapolation were required to
generate estimates for each year of the time series. State proportions applied to 1990-1999 are the same as those
for 2000 (BioCycle 2001). No state data exist for this portion of the time series, and there is a large amount of
uncertainty surrounding the number of facilities and amount of material composted. This is a conservative
approach in that it is unknown when a state began compositing operations, so it is assumed if they had operations
in 2000 that they did in 1990 as well. Data in between the survey data were interpolated using the prior year and
next year's survey data (the state proportion of material composted). Annual state data were interpolated for
2001, 2003, 2005, 2007, 2009, 2014, 2015, 2017, 2018, and 2019. State percentages for each year are presented in
Appendix F (Table F-4).

The formula used for interpolation of the state percentage for the year in question is as follows:

? = (|=f)

where:





y

= state percentage of waste composted

for the year without data, %

yi

= state percentage of waste composted

for the prior year with data, %

y2

= state percentage of waste composted

for the next year with data, %

X

= the year without data



Xi

= the prior year with data



X2

= the next year with data



The state percentage data were multiplied by the national estimate of material composted from the EPA Facts
and Figures reports to cap the total quantity composted across the states and match the state totals to the
national Inventory. The EPA Facts and Figures national estimates (EPA 2020) were directly used to estimate the
national Inventory. The IPCC Tier 1 method used in the national Inventory estimates (IPCC 2006) is the product of
an emissions factor and the mass of organic waste composted.

The final step in developing the state inventory was estimating the CFU and N2O emissions. For simplicity, the
state percentages were multiplied by the annual national emissions estimates.

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6.1.2.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CFU and N2O from composting
(specifically large-scale, commercial composting facilities) was calculated using the 2006 IPCC Guidelines Approach
1 methodology (IPCC 2006). As described further in Chapter 7 of the national Inventory, levels of uncertainty in the
national estimates in 2020 were CFU (-58%/+58%) and N2O (-58%/+58%). State-level estimates will have a higher
uncertainty than the national estimates because of apportioning the national quantity of material composted
(sourced from the EPA Sustainable Materials Management reports and calculated with a mass balance
methodology) to each state based on sporadically published waste management data from a voluntary state
agency survey for select years. The national methodology also assumes most composting in the United States use
the windrow method and treats a homogenous mixture of primarily yard trimmings, some food waste, and some
paper waste. For more details on national-level uncertainty, see the uncertainty discussion in Section 7.3 of the
national Inventory, available online at https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-
2022-chapter-7-waste.pdf.

6.1.2.4	Recalculations

Changes that resulted from recalculations to the state-level estimates are the same as those presented in
Section 7.3 of the national Inventory (pages 7-57), given that improvements in the national Inventory will lead
directly to improvements in the quality of state-level estimates as well.

6.1.2.5	Planned Improvements

In future annual publications, the EPA plans to investigate state volumes of material composted further where
the report authors (from referenced composting data sources) indicated potentially combined volumes of waste
sent to composting, recycling, and anaerobic digestion. The EPA will continue to identify annual quantities of
material composted in states where data are lacking (e.g., Alaska, Guam). For example, a 2021 desk-based
investigation into composting facilities in Alaska revealed operational aerated composting facilities, but the annual
capacity and throughput were not identified. The EPA will continue to search for relevant data for commercial
composting facilities in these states. Planned improvements to the national estimates for composting outlined in
Section 7.3 (p. 7-57) of the national Inventory will lead directly to improvements in the quality of state-level
estimates as well.

6.1.2.6	References

Arsova, L, R. van Haaren, N. Goldstein, S.M. Kaufman, and N.J. Themelis. (2008). "16th Annual BioCycle
Nationwide Survey: The State of Garbage in America" BioCycle, JG Press, Emmaus, PA. December.

Arsova, L, R. Van Haaren, N. Goldstein, S. Kaufman, and N. Themelis. (2010). 'The State of Garbage in America"
BioCycle. December 2010. Available online at: https://www.biocvcle.net/2010/10/26/the-State-ofgarbage-in-
america-4/

Environmental Research & Education Foundation. (2016). Municipal solid waste management in the United States:
2010 & 2013.

Goldstein, N. and C. Madtes. (2001). "13th Annual BioCycle Nationwide Survey: The State of Garbage in America."
BioCycle, JG Press, Emmaus, PA. December 2001.

Goldstein, N., S. Kaufman, N. Themelis, and J. Thompson Jr. (2006). The State of Garbage in America. BioCycle.

April 2006. Available online at: https://www.biocvcle.net/2006/04/21/the-State-of-garbage-in-america2/

Institute for Local Self-Reliance. (2014). State of composting in the US: What, why, where & how. Available online
at: http://ilsr.org/wp-content/uploads/2014/07/State-of-composting-in-us.pdf

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Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. National Greenhouse Gas Inventories Programme. H.S. Eggleston, L Buendia, K. Miwa, T. Ngara,
and K. Tanabe (eds.). Hayama, Kanagawa, Japan.

Kaufman, et al. (2004). 14th Annual BioCycle Nationwide Survey: The State of Garbage in America 2004. BioCycle,
JG Press, Emmaus, PA.

Shin, D. (2014). Generation and Disposition of Municipal Solid Waste (MSW) in the United States-A National
Survey. Thesis. Columbia University, Department of Earth and Environmental Engineering, January 3, 2014.

U.S. Environmental Protection Agency. (2020). Advancing Sustainable Materials Management: Facts and Figures
2018. Available online at: https://www.epa.gov/sites/production/files/2020-
ll/documents/2018 tables and figures fnl 508.pdf

Waste Business Journal (WBJ). (2016). Directory of Waste Processing & Disposal Sites 2016.

Waste Business Journal (WBJ). (2020). Directory of Waste Processing & Disposal Sites 2020.
6.1.3 Stand-Alone Anaerobic Digestion (NIR Section 7.4)

6.1.3.1	Background

Anaerobic digestion is a series of biological processes in the absence of oxygen in which microorganisms break
down organic matter, producing biogas and soil. Stand-alone digestion is one of three main categories of anaerobic
digestion facilities, which also includes on-farm digesters and digesters at water resource recovery facilities. This
section focuses exclusively on stand-alone digesters, which typically manage food waste from different sources,
including food and beverage processing industries. Emissions from on-farm digesters and digesters at water
resource recovery facilities are reflected under Sections 4.1.2 Manure Management and 6.2.1 Wastewater
Treatment and Discharge of this report. Based on available data, anerobic digestion occurs in the following 31
states: Arizona, California, Colorado, Connecticut, Florida, Georgia, Iowa, Idaho, Indiana, Kansas, Massachusetts,
Maryland, Maine, Michigan, Minnesota, Missouri, North Carolina, North Dakota, New Hampshire, New Jersey, New
York, Ohio, Oregon, Pennsylvania, Rhode Island, Tennessee, Texas, Virginia, Vermont, Washington, and Wisconsin.

At stand-alone digesters, methane (Cm) emissions may result from a fraction of the biogas that is lost during
the process due to leakages and other unexpected events (0% to 10% of the amount of CFU generated, IPCC 2006),
collected biogas that is not completely combusted, and entrained gas bubbles and residual gas potential in the
digested sludge. CO2 emissions are biogenic in origin and should be reported as an informational item in the
Energy Sector (IPCC 2006).

More information on emission pathways and national-level emissions and methods can be found in Section
7.4 of the national Inventory.

6.1.3.2	Methods/Approach

The EPA compiles national CFU emissions estimates for stand-alone anaerobic digester facilities in the United
States using an IPCC Tier 1 method, where an IPCC default emissions factor is applied to the estimated national
quantity of material digested. A default CH4 emissions factor (IPCC 2006) was multiplied by a weighted average
annual quantity of material digested by stand-alone digesters from three voluntary EPA data collection surveys
(EPA 2018, 2019, 2021) and an estimated number of operating facilities per year (see Table 7-47 and Table 7-48,
respectively, of the national Inventory). No facility-specific quantities of material digested were directly used
because of a general lack of facility-specific data over the time series. The methodology applied to generate the
national Inventory was based on two large assumptions—the number of operational facilities and the weighted
average of material digested for two of the 30 years in the time series (1990-2020). The state inventory further
takes these assumptions to a state level by assuming that the same percentage of total operational facilities is the
same for each year of the time series because of a general lack of data on total operational facilities by state across

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the time series. Therefore, the state-level inventories are a gross estimate that may be refined in future years if
available information by state is obtained. The national Inventory was disaggregated to the state level using
Approach 2 on the basis of survey data for the number of operational facilities by state for select years.

In the national Inventory, the EPA calculated a weighted average of material digested using masked survey
data from the three available survey reports for 2015 thru 2018 (EPA 2018, 2019, 2021). The weighted average was
applied to an estimated number of operational facilities per year to estimate the annual quantity of material
digested. The first step to calculating the state inventory was to disaggregate the annual estimates of the material
digested. This was disaggregated by applying a state percentage of operational facilities as reported to the three
published EPA survey reports (EPA 2018, 2019, 2021). The state proportions of operational facilities in 2015 thru
2018 are presented in Appendix F (Table F-5).

The state proportions were multiplied by the national quantity digested for each year in the time series, which
forced the total quantities across the states to match the national Inventory estimates. The same state percentage
was used for each year in the time series because of a lack of compiled data on the number of stand-alone
digesters by state between 1990 and 2020.

The equation used to estimate the annual quantity of material digested per year by state is presented as
Equation 1.

Digesteds = %s x ND	Equation 1

where:

Digesteds = the quantity of material digested by state (kilotons/year)

%os	= the state proportion of operational facilities, calculated from the number of operational

stand-alone digesters as reported in the EPA surveys (EPA 2018, 2019) for 2015 and 2016; the
same state percentage was applied to each year in the time series (%, see Appendix F [Table
F-5])

Nd	= the annual national estimate of material digested (kilotons/year).

The state-specific annual CFU generation estimates were calculated using Equation 2:

Gch4 = Digesteds x EFcm x ^	Equation 2

where:

Gch4	= CFU generation from stand-alone anaerobic digesters, kt CFU

Digesteds = mass (quantity) of material digested by state, kt

EFm	= CFU emissions factor, 0.8 Megagram/Gigagram (Mg/Gg, wet basis) (IPCC 2006)

1/1,000 = conversion factor, Gg/Mg

The national Inventory estimates for CFU recovery were estimated using the 2 years of available EPA survey
data (EPA 2018, 2019). The state-specific CFU recovery estimates were calculated using Equation 3:

RCh4 = %s x National RCh4	Equation 3

where:

Rm	= CFU recovery from stand-alone anaerobic digesters, kt CFU

%os	= state percentage of operational facilities, % (see Appendix F [Table F-5])

National Rch4 = national amount of recovered CFU, kt

Lastly, the state estimates of net CFU emissions were calculated by summing the CFU generation and CFU
recovery estimates:

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EmissCH4 — GCH4 Rch4

Equation 4

Where:

EmisscH4

Gem

RcH4

Cm emissions by state, kt

CH4 generation from stand-alone anaerobic digesters, kt CH4
CH4 recovery from stand-alone anaerobic digesters, kt CH4

6.1.3.3	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CH4 from Stand-Alone Anaerobic
Digesters was calculated using the 2006 IPCC Guidelines Approach 1 methodology (IPCC 2006). As described
further in Chapter 7 of the national Inventory, levels of uncertainty in the national estimates in 2019 were CH4
(-54%/+54%). State-level estimates will have a higher uncertainty because of apportioning the national emissions
estimates to each state based solely on the number of stand-alone anerobic digester facilities from EPA survey
data collected between 2015 and 2018. Emissions estimates before 2015 will have a higher uncertainty than those
in 2015 and later years. These assumptions were required because of limited facility-specific data presented in
secondary resources. No attempt was made to collect state-maintained permitting data on annual throughput
because the EPA is collecting this information under an Information Collection Request. For more details on
national-level uncertainty see the uncertainty discussion in Section 7.4 of the national Inventory.

6.1.3.4	Recalculations

While no changes or refinements were made to the approach to disaggregate estimates from national to state
level, changes in the state-level estimates are also due to recalculations presented in Section 7.4 of the national
Inventory (pages 7-63), given that improvements in the national Inventory will lead directly to improvements in the
quality of state-level estimates as well.

6.1.3.5	Planned Improvements

The planned improvements are consistent with those planned for improving national estimates given that the
underlying methods for state GHG estimates are the same as those in the national Inventory. To find information
on planned improvements to refine methods for estimating emissions stand-alone anaerobic digestion, see the
planned improvements discussion in Section 7.4 of the national Inventory for a description of future work to
further improve these estimates.

6.1.3.6	References

Intergovernmental Panel on Climate Change (IPCC). (2006). 2006 IPCC Guidelines for National Greenhouse Gas
Inventories. Volume 5: Waste, Chapter 4: Biological Treatment of Solid Waste, Table 4.1. The National
Greenhouse Gas Inventories Programme, Intergovernmental Panel on Climate Change, H.S. Eggleston, L.
Buendia, K. Miwa, T. Ngara, and K. Tanabe (eds.). Hayama, Kanagawa, Japan. Available online at:
http://www.ipcc-nggip.iges.or.ip/public/2006gl/pdf/5 Volume5/V5 4 CH4 Bio Treat.pdf.

U.S. Environmental Protection Agency. (2018). Anaerobic Digestion Facilities Processing Food Waste in the United
States in 2015: Survey Results. May 2018 EPA/903/S-18/001. Available online at:

https://www.epa.gov/sites/production/files/2019-09/documents/ad data report vlO - 508 comp vl.pdf

U.S. Environmental Protection Agency. (2019). Anaerobic Digestion Facilities Processing Food Waste in the United
States in 2016: Survey Results. September 2019 EPA/903/S-19/001. Available online at:
https://www.epa.gov/sites/production/files/2Q18-
08/documents/ad data report final 508 compliant no password.pdf

U.S. Environmental Protection Agency. (2021). Anaerobic Digestion Facilities Processing Food Waste in the United
States (2017 & 2018): Survey Results. January 2021 EPA/903/S-21/001. Available online at
https://www.epa.gov/sites/default/files/2021-02/documents/2Q21 final ad report feb 2 with links.pdf.

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6.2 Wastewater Management

This section presents the methodology used to estimate the emissions from domestic and industrial
wastewater treatment and discharge (Cm, N2O).

6.2.1 Wastewater Treatment and Discharge (NIR Section 7.2)

6.2.1.1	Background

Consistent with the national Inventory and international guidance, the EPA has developed disaggregated state
estimates for both domestic and industrial wastewater treatment and discharge as discussed below.

•	Domestic wastewater Cl-Uand N2O emissions originate from both septic systems and from centralized
treatment plants. Within these centralized plants, CH4 emissions can arise from aerobic systems that
liberate dissolved Cl-Uthat formed within the collection system or that are designed to have periods of
anaerobic activity, from anaerobic systems, and from anaerobic sludge digesters when the captured
biogas is not completely combusted. N2O emissions can result from aerobic systems as a by-product of
nitrification, or as an intermediate product of denitrification. Methane emissions will also result from the
discharge of treated effluent from centralized treatment plants to waterbodies where carbon
accumulates in sediments while N2O emissions will also result from discharge of centrally treated
wastewater to waterbodies with nutrient-impacted/eutrophic conditions.

•	Industrial wastewater CH4 emissions originate from in-plant treatment systems, typically comprising
biological treatment operations in which some are designed to have anaerobic activity or may periodically
have anaerobic conditions form. N2O emissions are primarily expected to occur from aerobic treatment
systems as a by-product of nitrification, or as an intermediate product of denitrification. Emissions will
also result from discharge of treated effluent to waterbodies.

6.2.1.2	Methods/Approach (Domestic Wastewater)

The EPA estimated state-level domestic wastewater treatment and discharge emissions (CH4) using a
simplified approach to apportion the national emission estimates to each state based on population (i.e., Approach
2 as defined in the Introduction to this report). In this method, the EPA accessed historic U.S. Census data to
compile state-level population data for each year of the inventory (1990-1999: U.S. Census Bureau 2002; 2000-
2009: U.S. Census Bureau 2011; 2010-2020: U.S. Census Bureau 2021a and 2021b, Instituto de Estadisticas de
Puerto Rico 2021). The EPA then calculated state-level and territory-level emissions by multiplying the percentage
of the U.S. population in each state or territory by the Cl-Uand N2O national emissions for each year of the time
series.

This simplified approach assumes the following:

•	Every state has the same wastewater treatment system usage as the national Inventory.

•	Every state has same distribution of discharge to various waterbody types as the national Inventory.

•	Kitchen disposal usage is the same in every state, and wastewater biochemical oxygen demand (BOD)
produced per capita, with and without kitchen scraps, is the same in every state (i.e., assumes total
wastewater BOD produced per capita is the same as national production).

•	Per capita protein consumption in the United States is the same in every state (i.e., assumes per capita
consumption is the same as national consumption).

The EPA did not perform a more detailed approach that would account for the types of treatment (e.g., on-site
such as septic systems and centralized systems such as publicly owned treatment works [POTWs]) used in each

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state (see planned improvements below in Section 6.2.1.6). Similarly, there are insufficient readily available data
sources to allow classification of the type of specific waterbodies within each state so the EPA did not consider the
type of waterbody receiving wastewater discharges within each state.

6.2.1.3 Methods/Approach (Industrial Wastewater)

Consistent with the national Inventory and national estimates, both CH4 and N2O emissions were estimated for
treating industrial wastewater from pulp and paper manufacturing; meat and poultry processing; petroleum
refining; and breweries, while CH4 emissions were also estimated for treating industrial wastewater from
vegetables, fruits, and juices processing, and for starch-based ethanol production. These are the Industry
categories that are likely to produce significant GHG emissions from wastewater treatment. Data on industrial
production by state are available or can be estimated from other readily available data for at least some of the
time series of the inventory.

The EPA estimated state-level emissions by estimating the percentage of the industry production that occurs
in each state (i.e., using Approach 2 as described in the Introduction to this report). Where data were readily
available, the EPA estimated the distribution of production for each year of the time series and multiplied that by
the national emissions estimate for each year of the time series. In some cases, due to time and resources, the EPA
was able to estimate the distribution of production for a subset of years in the time series, as discussed by
industry, below.

For pulp and paper manufacturing, state-level production data are not available, so the EPA estimated state-
level emissions by estimating the percentage of wastewater directly discharged in that state compared to the total
flow of wastewater directly discharged for that industry, using data reported to the EPA's ICIS-NPDES database.

The EPA then multiplied that percentage by the national emissions estimate to obtain a state-level emissions
estimate. Because of the limitation of data resources for this effort, the EPA accepted the ICIS-NPDES data as is and
did not conduct further outlier or data gap analyses (see planned improvements below in Section 6.2.1.6).

Both approaches assume the following:

•	All facilities in an industry within a state have the same distribution of wastewater treatment operations
as the national distribution.

•	Every state has the same BOD and total nitrogen in untreated industry wastewater as the national-level
estimates.

•	Every state has the same nitrogen removal factor as the national-level estimates.

•	The percentage of wastewater directly discharged by the state represents the distribution of all pulp and
paper production by the state.

Further details on methods and data sources assumptions for each industry treating wastewater are described
below.

Pulp and Paper Manufacturing

•	Industrial production data for pulp and paper are highly confidential and are not available by state.

•	The EPA used the amount of wastewater directly discharged by pulp mills by state (reported to both ICIS-
NPDES from Enforcement Compliance History Online [ECHO], ECHO 2022, and Washington Department of
Ecology Permitting and Reporting Information System [PARIS], PARIS 2022) to proportion U.S. national
emissions estimates to a state [as shown in Appendix F (Table F-6)]. Because wastewater flow data
housed in ECHO changed in 2016, using older data may cause discontinuities in the time series. The EPA
determined the distribution of discharge flow by state for 2019 using 2019 ECHO and PARIS data and

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applied this distribution to all years of the national Inventory. There was no wastewater flow reported for
the District of Columbia or the territories for this industry.

•	For facilities in states other than Washington, the EPA:

-	Downloaded the total pulp and paper facility universe in ECHO, focusing on facilities that have actual
discharge monitoring report data, not just facility information (e.g., address). In 2019, 352 facilities
made up the industry universe based on this criterion.

-	Downloaded 2019 flow data where available (ECHO 2022). Not all facilities report total flow if it is not
required by their permit.

-	For facilities without flow data, downloaded all solids discharge data for the industry universe and
estimated total flow by using average daily flow per concentration of solids by state.

¦	For facilities that have both an average daily flow (MGD) and an average concentration of solids
(mg/L), calculated the average flow per average concentration (MGD/mg/L).

¦	Averaged these values by state.

¦	For facilities with missing flow data but with solids concentration data, multiplied the average
solids concentration (m/L) by the calculated state average concentration per flow (MGD/mg/L) to
get an estimated daily flow rate (MGD).

¦	Multiplied the daily flow rate by 365.25 days to estimate a total yearly flow.

-	For facilities without flow or solids concentration data, applied the same methodology above using
ECHO'S "Organic Enrichment" pollutant category.

-	If a facility did not have data for flow, solids, or organic enrichment, estimated total flow as zero. This
assumption of zero flow was applied to 11 facilities.

•	Washington facilities are currently not reported within ECHO due to lagging electronic reporting. To fill
this known gap, the EPA investigated a separate source for these data. For state of Washington facilities,
the EPA:

-	Downloaded and reviewed permit data for known pulp mills determined from the Washington
Department of Ecology, Industrial Facility Permits website.

-	Downloaded 2019 flow data where available (PARIS 2022) for monitoring locations that are
associated with process wastewater, per the facility permit.

-	Multiplied the daily flow rate by 365.25 days to estimate a total yearly flow, then multiplied by
number of months data were reported (to prevent overestimating annual flow which was done to
better match the methodology in ECHO).

-	Integrated into the other state data.

•	The EPA calculated the percentage of national flow by state:

-	As with Washington, some states are missing from ECHO (e.g., Montana, Colorado). The EPA assumed
some of these states have nonzero emissions, but they do not have the data to estimate them, so
they are reported as not applicable.

•	The EPA calculated the state-level emissions by multiplying national emissions by the percentage of
national flow by state.

•	Example: 2019 California emissions

-	California has two facilities in the facility universe with reported data. In 2019, one reported a total
annual flow of 589.4 MMGal and the other 0 MMGal.

-	The total flow based on the sum of reported flows and calculated flows for all reporting facilities was
1,931,834 MMGal in 2019.

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-	California's flow was 0.04% of this total flow.

-	Pulp and paper's national methane emissions in 2019 was 29 Gg CFU, so California's 2019 emissions
were estimated to be (29 Gg CFU* 0.04% = 0.011 Gg CFU).

Meat and Poultry Processing

•	Annual U.S. and state-level production data for red meat processing and poultry processing data are
available from USDA-NASS [as shown in Appendix F (Table F-7)]. Depending on the commodity, limited
state-level data are available. Typically, the USDA reports only break out the primary states where the
commodity is processed and then present production in "other states."

•	For red meat processing:

-	The EPA gathered state-level 2020 and 2004 average live weight and total head slaughtered for the
following commodities: beef, calves, hogs, and lamb/mutton (USDA 2021a; USDA 2004). EPA retained
2019 data from the 1990-2019 state-level production data.

¦	Territories and Washington, D.C., are not included in USDA-reported data.

-	For total head slaughtered (thousand head):

¦	To populate states for which specific production data are not disclosed by USDA ("D" states), the
EPA evenly divided the difference between the sum of the state-level data and the reported
national-level total to those D states.

¦	Similarly, USDA provided a total for New England states that was evenly distributed to those
states noted (Connecticut, Maine, Massachusetts, New Hampshire, Rhode Island, and Vermont).

-	For average live weight (pounds):

¦	The EPA used the average of available state-level data and the national average to determine the
appropriate average live weight for the remaining states (D states). This calculated value was
applied to all D states.

¦	Similarly, the reported average live weight value for New England states was applied to those
states.

-	As with the national Inventory, the EPA determined live weight killed (LWK) by multiplying the
average live weight by the total head/1,000 to get to million pounds LWK.

-	The EPA added the disaggregated red meat processing data by state and divided the data by the
reported national production to determine the proportion distributed to states. Because of the
estimated nature of the calculated values, the total state-level LWK is estimated as about 95% of the
national total, so the percentages were normalized to 100%.

•	For poultry processing:

-	The EPA gathered state-level 2020 and 2004 poultry live weight data. EPA retained 2019 data from
the 1990-2019 state-level production data. Only broilers had state-level data available. Turkeys and
mature chickens did not.

¦	Young turkey data were available by state. The EPA assumed that states with young turkeys
would be representative of turkey processing production; therefore, young turkey data were
used as a proxy for total turkeys (USDA 2021a; USDA 2004).

¦	Broilers (or young chickens) were used to represent mature chicken processing production by
state (USDA 2021a; USDA 2004).

-	To populate D states for 2020, the EPA evenly divided the difference between the sum of the state-
level data and the reported national-level total to those D states.

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-	To populate D states for 2004, the EPA first proxied the reported D states for 2020 because the
individual states for 2004 were not available or reported by USDA. This was done to encourage time
series consistency and avoid showing states known to have poultry processing as having no emissions
for the industry. EPA acknowledges this method could attribute minor emissions to states without
poultry in 2004. Then, as with 2020, EPA evenly divided the difference between the sum of the state-
level data and the reported national-level total to those D states.

-	For turkeys and mature chickens, the proportion of young turkeys and young chickens, respectively,
was multiplied by the national-level value to determine the pounds of processing production per
state.

-	Those values were added together and then divided by the total poultry (broilers, mature chickens,
turkeys) values to determine the proportion of poultry LWK for states.

•	To calculate CH4emissions, the EPA:

Multiplied national red meat plant Cm emissions by the percentage of U.S. total meat processing and
added that to the national poultry plant CFU emissions multiplied by the percentage of U.S. total
poultry processing by state.

-	Multiplied the 2004, 2019 (from the 1990-2019 inventory), and 2020 state-level proportion of U.S.
meat and poultry BOD treated on-site by the national effluent CFU emissions from meat and poultry.

-	For 2005 through 2018, used linear interpolation of 2004 and 2019 state-level proportions. Multiplied
those values by the national effluent Cm emissions from meat and poultry.

-	For 1990 through 2003, assumed the state-level proportions to be the same as those determined for
2004.

-	Added plant and effluent emissions for total state-level emissions.

•	To calculate N2O emissions, the EPA:

-	Multiplied the 2004, 2019 (from the 1990-2019 inventory), and 2020 state-level proportion of U.S.
total nitrogen in aerobically treated meat and poultry wastewater by the N2O emissions from meat
and poultry processing wastewater treatment for each year in the time series.

-	Multiplied the 2004, 2019 (from the 1990-2019 inventory), and 2020 state-level proportion of U.S.
total nitrogen in discharged meat and poultry wastewater by the N2O emissions from meat and
poultry processing wastewater treatment effluent for each year in the time series.

-	For 2005 through 2018, used linear interpolation of 2004 and 2019 state-level proportions. Multiplied
those values by the national effluent N2O emissions from meat and poultry.

For 1990 through 2003, assumed the state-level proportions to be the same as those determined for
2004.

-	Added plant and effluent emissions for total state-level emissions.

Vegetables, Fruits, and Juices Processing

•	Annual U.S. production data for vegetables, fruits, and juices processing are available from the USDA.

Depending on the commodity, state-level data are available [as shown in Appendix F (Table F-8)].

Typically, the USDA reports only identify the primary states where the commodity is processed. For

example, production data on broccoli are provided for California and "other states," while production

data on asparagus are provided for Michigan, Washington, and "other states."

-	Territories and Washington, D.C., are not included in the USDA-reported data.

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•	The EPA determined that the most recent year with complete state-level production values is 2017
because the USDA suspended the reporting of some state-level production values in 2018 and more
notably in 2019 and 2020.

•	To better inform the time series, the EPA also investigated an earlier year, determined 2004 to be
complete, and subsequently determined the state-level production values for 2004.

•	For processing production data:

-	Potatoes: State-level data for potato processing were not available. Instead, the EPA used state-level
potato production (i.e., the production of potatoes grown not processed) as a proxy to determine the
states to include (USDA 2004; USDA 2006; USDA 2021a).

-	Other vegetables: The EPA gathered data for asparagus, broccoli, carrots, cauliflower, sweet corn,
cucumber (for pickles), lima beans, green peas, snap beans, spinach, and tomatoes (USDA 2020b).
Where USDA reported data for "other states" those data were distributed equally among the
commodities. The EPA added the production for these commodities to determine the percentage of
the U.S. total for all "other vegetables," which is the production value used in the national Inventory
(not the individual commodities).

-	Processed apples, grapes used for wine, and citrus fruits were also determined at a state level. For
apples, where USDA reported data for "other states," those data were distributed equally (USDA
2020a).

-	Noncitrus fruits are split out into separate commodities (e.g., blueberries, sweet cherries36); no state-
level data are available for the aggregated "noncitrus fruit" category. Therefore, the EPA gathered the
state-level "utilized production" data for these separate commodities to determine the appropriate
states and relative percentage of utilized production for noncitrus fruits (USDA 2020a).

-	For processed noncitrus fruit data, the data used for Inventory calculations, are typically calculated in
the national Inventory (utilized production minus fresh minus apples minus grapes for wine);
however, because of the intensive nature of gathering data for the separate commodities, "utilized
production" was used as a proxy for processed production data.

•	To calculate emissions, the EPA calculated the 2004 and 2017 percentage of U.S. total BOD by state and
multiplied that by the national vegetables and fruits emissions for each year in the time series.

•	For 2005 through 2016, determined state-level proportions by linearly interpolation of 2004 and 2017
values. 2018 through 2020 were assumed to be the same as 2017.

Petroleum Refining

•	Annual production data are available from the EIA within DOE (EIA 2022a) (as shown in Appendix F [Table
F-9] )¦

•	Because state-level data may reveal confidential data, production data are aggregated by Petroleum
Administration for Defense Districts, or PADDs. Production data for the following PADDs and subdistricts
are available:

-	PADD I (East Coast)

¦ Subdistrict A (New England): Connecticut, Maine, Massachusetts, New Hampshire, Rhode Island,
and Vermont

36 The EPA gathered 2004 and 2017 production for apricots, avocados, blueberries, boysenberries (2004 only), cultivated
blueberries (2004 only), and wild blueberries; sweet and tart cherries; coffee (2017 only); cranberries; dates; loganberries (2004
only); nectarines; olives; papaya, including guavas and pineapples (Hawaii crops, 2004 only); peaches; pears; plums; prunes
(combined with plums in 2004); raspberries; and strawberries.

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¦	Subdistrict B (Central Atlantic): Delaware, District of Columbia, Maryland, New Jersey, New York,
and Pennsylvania

¦	Subdistrict C (Lower Atlantic): Florida, Georgia, North Carolina, South Carolina, Virginia, and West
Virginia

-	PADD II (Midwest): Illinois, Indiana, Iowa, Kansas, Kentucky, Michigan, Minnesota, Missouri,

Nebraska, North Dakota, South Dakota, Ohio, Oklahoma, Tennessee, and Wisconsin

-	PADD III (Gulf Coast): Alabama, Arkansas, Louisiana, Mississippi, New Mexico, and Texas

-	PADD IV (Rocky Mountain): Colorado, Idaho, Montana, Utah, and Wyoming

-	PADD V (West Coast): Alaska, Arizona, California, Hawaii, Nevada, Oregon, and Washington

•	Operating capacity by state are available from EIA (EIA 2022b).

•	The EPA created state-level annual production data for each year of the time series by dividing the annual
production for each PADD subdistrict by the percentage of operating capacity each state provided in that
year.

•	Petroleum operating capacity values were not available for 1996 and 1998. These values were linearly
interpolated.

•	Example: 2019 California Emissions

-	California data are included in PADD V.

-	PADD V has a total of 27 refineries with an operating capacity of 2,875,071 barrels.

-	California has a total of 15 refineries with an operating capacity of 1,909,671 barrels (or 66.4% of
PADD V capacity).

-	PADD V produced 1,122,935 barrels in 2019.

-	Estimate California production as (1,122,935 barrels * 66.4%=) 745,629 barrels.

-	Calculate percentage of national production that is California (745,629 barrels/7,460,380 barrels =
10%).

-	Calculate California emissions as national emissions * percentage of national production (4.6 Gg Cm *
10% = 0.46 Gg CH4).

Starch-based Ethanol Production

•	State-level ethanol production data are available from SEDS (EIA 2019) (as shown in Appendix F [Table F-
10]).

-	Fuel ethanol production data, including denaturant, in thousand barrels are available for 1960- 2019
(EIA 2019).

-	The EPA checked the difference between SEDS national production and the reported production in
the national Inventory and found small differences—on average 0.9% difference for the time series-
further confirming this is a good source of state-level production.

-	The calculated 2019 percentage of national production by state was used for 2020 values.

•	Calculated the percentage of national production by state for 1990-2018.

•	Calculated the state-level emissions by multiplying national emissions by percentage production by state.

•	Example: 2019 California Emissions

-	2018 California production value is 5,170 thousand barrels.

-	National production for 2018 is 383,128 thousand barrels.

-	California produced 1.4% of the national production in 2018, and this value is used for 2019.

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-	Calculate 2019 California emissions as national emissions * percentage of national production (6.4 Gg
cm * 1.4% = o.o9 Gg ch4).

Breweries

•	Annual production data by state are available from the Alcohol and Tobacco Tax and Trade Bureau (TTB
2021) (as shown in Appendix F [Table F-10]).

-	Data are available for 2008-2020. Therefore, the calculated percentage of national production for
2008 was used for 1990-2007.

-	These data are for taxable production values only, which accounts for 94% of total production in
2020. Approach assumes that this portion of production is still representative of relative production
percentages for each state.

-	Data are not available broken out between craft and noncraft production, so the approach assumes
each state has the same distribution of craft and noncraft production as the national distribution.

•	Calculated the percentage of national production by state.

•	Calculated the state-level emissions by multiplying national emissions by percentage production by state.

•	Example: 2019 California Emissions

-	California production is 17,872,597 barrels.

-	National production is 167,077,233 barrels.

-	California produces 10.7% of national production.

-	Calculate California emissions as national emissions * percentage of national production (5.6 Gg Cm *
10.7% = 0.599 Gg CH4).

6.2.1.4	Recalculations

Recalculations discussed here are specific to state-level production or disaggregated data. To see impacts from
updates to national-level data, see the Recalculations discussion in the Waste chapter (Chapter 7), Section 7.2 of
the national Inventory, available online at https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-
inventorv-2022-chapter-7-waste.pdf.

The source of state-level Puerto Rico population was updated which impacted the entire time series for
domestic wastewater treatment emissions estimates. This update was made to ensure consistency in activity data
sources across Inventory sectors. These updates, in conjunction with the changes to the national Inventory37,
resulted in changes for the entire time series for all state-level domestic CH4 and N2O emission estimates.

Updates to the following state-level industrial production data, in conjunction with national-level updates,
resulted in changes for the entire time series for every state-level total industrial CH4 and N2O emission estimates:

•	Pulp and paper: Including 2019 flow estimates for Washington State.

•	Meat and poultry processing: Including 2004 and 2020 production data.

•	Vegetables, fruits, and juices processing: Including 2004 production data.

6.2.1.5	Uncertainty

The overall uncertainty associated with the 2020 national estimates of CH4 and N2O from wastewater
treatment and discharge were calculated using the 2006 IPCC Guidelines Approach 2 methodology (IPCC 2006). As
described further in Chapter 7 of the National Inventory of U.S. Greenhouse Gas Emissions and Sinks (U.S. EPA

37 See Section 7.2, page 7-52, of the national Inventory.

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2022), levels of uncertainty in the national estimates in 2020 were Cm (-35/+23%) and N2O (-35/+194%). State-
level estimates have a higher uncertainty due to apportioning the national emissions estimates to each state based
solely on state population (for domestic) or state industry sector production (for industrial). This approach does
not address state- level differences in the type of wastewater treatment systems in use or in the conditions of the
state's receiving waterbodies. For all sectors other than domestic, petroleum refining, starch-based ethanol, and
breweries, state- level emissions for the time series were estimated based on a single year of state-level data,
which also results in higher uncertainty for the state estimates. These assumptions were required due to the
general lack of readily available state- or regional-level data. For more details on national-level uncertainty, see the
Uncertainty discussion in the Waste chapter (Chapter 7), Section 7.2 of the national Inventory, available online at
https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-7-waste.pdf.

6.2.1.6 Planned Improvements

Generally, the EPA plans to review and assess recommendations on potential comparable datasets provided
during review of the inventory methods. These sources may inform the following potential improvements for both
domestic and industrial state-level emissions estimates.

•	Determine state-level sources for the type of wastewater treatment systems in use for municipal or
domestic or for industrial wastewater (by industrial sector).

•	Determine state-level sources for BOD or total nitrogen data in municipal or domestic wastewater or
industrial wastewater (by industrial sector).

•	As stated in Section 7.2 of the national Inventory, investigate additional sources for estimating
wastewater volume discharged and discharge location for both domestic and industrial sources.

•	Investigate sources to better define a state-level breakdown of centralized and septic systems. Peer and
state technical review comments indicated that national assumptions are likely not representative of
certain individual states.

•	For individual industries, the EPA notes the following potential improvements:

Pulp and Paper Manufacturing

•	Investigate state-level sources for the production of pulp, paper, and paperboard.

•	Investigate additional years of ECHO data to improve the time series. Part of this includes evaluating the
facilities present year to year to confirm time series consistency.

•	Confirm whether facilities with no reported flow or the investigated discharge parameter data did not
operate in 2019 (or other years of interest). In particular, this includes states that currently do not report
data to ECHO. If operated, the EPA could determine other appropriate methods to estimate flow.

•	Investigate states where data are reported as not applicable and confirm emissions estimates do not
apply. Pending findings, determine another source to estimate wastewater flow for these states.

Meat and Poultry Processing

•	Investigate additional years of available USDA data for inclusion to improve the time series.

•	Investigate the presence of meat and poultry processing in the U.S. territories or the District of Columbia
and, pending findings, additional sources for estimating those emissions. For the District of Columbia,
reach out to USDA NASS to confirm if the District of Columbia is already included in reporting.

Vegetables, Fruits, and Juices Processing

•	Continue to investigate other years of available USDA data for inclusion.

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•	Investigate the presence of vegetables, fruits, and juices processing in the U.S. territories or the District of
Columbia and, pending findings, additional sources for estimating those emissions. For the District of
Columbia, reach out to USDA NASS to confirm if the District of Columbia is already included in reporting.

Starch-based Ethanol Production

•	Investigate sources to break down wet and dry milling by state over the time series.

Breweries

•	Investigate sources to break down craft and noncraft breweries by state over the time series.
6.2.1.7 References

ECHO. (2022). Pulp, paper, and paperboard Water Pollution Search Results. Available online at:
https://echo.epa.gov/trends/loading-tool/water-pollution-search.

Energy Information Administration (EIA). (2019). U.S. State Energy Data System (SEDS): 1960-2019 (complete).
Available online at: https://www.eia.gov/state/seds/seds-data-complete.php?sid=US

Energy Information Administration (EIA). (2022a). U.S. Refinery and Blender Net Production of Crude Oil and
Petroleum Products (Thousand Barrels). Available online at:
https://www.eia.gov/dnav/pet/pet pnp refp a epOO ypr mbbl a.htm

Energy Information Administration (EIA). (2022b). U.S. Number and Capacity of Petroleum Refineries. Available
online at: https://www.eia.gov/dnav/pet/pet pnp capl dcu nus a.htm

Instituto de Estadisticas de Puerto Rico. (2021). Population of Puerto Rico from 1990-1999 from "Estimados
anuales poblacionales de los municipios desde 1950." Accessed February 2021. Available online at:
https://censo.estadisticas.pr/EstimadosPoblacionales

Intergovernmental Panel on Climate Change. (2006). 2006 IPCC Guidelines for National Greenhouse Gas

Inventories. National Greenhouse Gas Inventories Programme. H.S. Eggleston, L. Buendia, K. Miwa, T. Ngara,
and K. Tanabe (eds.). Hayama, Kanagawa, Japan.

TTB. (2021). Alcohol and Tobacco Tax and Trade Bureau. Beer Statistics. Available online at:
https://www.ttb.gov/images/pdfs/statistics/aggregated/aggr-data-beer 2008-2019.pdf

PARIS (2022). Washington Water Quality Permitting and Reporting Information System DMR Data. Available online
at: https://apps.ecology.wa.gov/paris/DischargeMonitoringData.aspx

U.S. Census Bureau. (2021a). Annual Estimates of the Resident Population for the United States, Regions, States,
and Puerto Rico: April 1, 2010 to July 1, 2020. Available online at: https://www.census.gov/data/tables/time-
series/demo/popest/2010s-state-total.html

U.S. Census Bureau. (2021b). International Database: World Population Estimates and Projections. Available online
at: https://www.census.gov/programs-survevs/international-programs/about/idb.html. Accessed January
2022.

U.S. Census Bureau, Population Division. (2011). Table 1. Intercensal Estimates of the Resident Population for the
United States, Regions, States, and Puerto Rico: April 1, 2000 to July 1, 2010 (ST-EST00INT-01), Release Date:
September 2011. Available online at: https://www2.census.gov/programs-survevs/popest/datasets/200Q-
2010/intercensal/state/st-est00int- alldata.csv

U.S. Census Bureau, Population Division (2002). Table CO-EST2001-12-00—Time Series of Intercensal State

Population Estimates: April 1,1990 to April 1, 2000. Available online at: https://www2.census.gov/programs-
survevs/popest/tables/1990-2000/intercensal/st- co/co-est2001-12-00.pdfU.S. Department of Agriculture
(USDA). (2021a). National Agricultural Statistics Service. Washington, DC. Available online at:
https://www.nass.usda.gov/Publications/ and https://quickstats.nass.usda.gov

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METHODOLOGY DOCUMENTATION

U.S. Department of Agriculture (USDA). (2021b). National Agricultural Statistics Service. Vegetables 2020 Summary.
Available online at: https://usda.librarv.Cornell.edu/concern/publications/02870v86p?locale=enU.S.
Department of Agriculture (USDA). (2004). National Agricultural Statistics Service. Washington, DC. Available
online at: https://www.nass.usda.gov/Publications/ and https://quickstats.nass.usda.gov

U.S. Department of Agriculture (USDA). (2006). National Agricultural Statistics Service. Vegetables 2006 Summary.
Available online at: https://usda. libra rv.Cornell.edu/concern/publications/02870v86p?locale=en

U.S. Environmental Protection Agency. (2022). Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2020
(EPA 430-R-22-003), Chapter 7: Waste. Available online at:

https://www.epa.gov/svstem/files/documents/2022-04/us-ghg-inventorv-2022-chapter-7-waste.pdf

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Appendix

A: Energy Sector Combustion Estimates

Please see separate xlsx file.

B: Energy Sector Fugitive Estimates

Please see separate xlsx file.

C: iPPU Minerals Sector Estimates

Please see separate xlsx file.

D: IPPU Chemicals Sector Estimates

Please see separate xlsx file.

E: Agriculture LULUCF Estimates

Please see separate xlsx file.

F: Waste Estimates

Please see separate xlsx file.

G: US Population Data Used in Estimates

Please see separate xlsx file.

H: IPPU Metals Sector Estimates

Please see separate xlsx file.

I: IPPU Product Use Sector Estimates

Please see separate xlsx file.

Methodology Report: Inventory of U.S. GHG Emissions and Sinks by State

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