FIRST FIVE-YEAR REVIEW REPORT
FOR THE
IOWA CITY FORMER MANUFACTURED GAS PLANT SUPERFUND SITE
JOHNSON COUNTY, IOWA
S7k,*c
Prepared by
U.S. Environmental Protection Agency
Region 7
Lenexa, Kansas
Robeft Whfackson, Acting Director
Superfund Division
Date
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Table of Contents
List of Abbreviations 5
Executive Summary 7
Five-Year Review Summary Form 10
I. Introduction 11
A. Site Chronology....; 12
B. Background 12
Physical Characteristics 12
Land and Resource Use 12
History of Contamination 13
Initial Response 14
Basis for Taking Action 15
C. Remedial Actions 16
Remedy Selection 16
Remedy Implementation 19
System Operations/Operation and Maintenance (O&M) 21
II. Progress Since the Last Five-Year Review ....21
III. Five-Year Review Process 22
Administrative Components 22
Community Notification and Involvement 22
Document Review 22
Data Review 22
Site Inspection 28
IV. Technical Assessment 28
Question A: Is the remedy functioning as intended by the decision documents? 28
Question B: Are the exposure assumptions, toxicity data, cleanup levels, and
remedial action objectives (RAOs) used at the time of the remedy
selection still valid? 30
Question C: Has any other information come to light that could call into question
the protectiveness of the remedy? 33
Technical Assessment Summary 33
V. Issues, Recommendations and Follow-up Actions 34
VI. Protectiveness Statement(s) 34
VII. Next Review 34
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Tables
Table 1 - Chronology of Site Events
Table 2 - Action Levels for Groundwater
Table 3 - Ralston Creek Sediment Performance Standards
Table 4 - Operation and Maintenance Costs
Table 5 - Air Monitoring Results
.12
.18
.19
.21
.27
Figures
1. Current Site Layout
2. Site Vicinity and Current Groundwater Monitoring Network
3. Ralston Creek Sediment Sampling Location and Tile Liner Inspection Area
4. Air Sampling Locations
Attachments
1. List of Documents Reviewed
2. Groundwater Monitoring Results
3. Sediment Sampling Results
4. Groundwater Contaminants of Concern Trend Analysis Summary
5. Five-Year Review Inspection Form
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LIST OF ABBREVIATIONS
AOC Administrative Order on Consent
ARAR Applicable or Relevant and Appropriate Requirement
BTEX Benzene, Toluene, Ethylbenzene and Xylenes
CERCLA Comprehensive Environmental Response, Compensation and Liability Act
COC Contaminant of Concern
DNAPL Dense Nonaqueous Phase Liquid
EPA United States Environmental Protection Agency
FMGP Former Manufactured Gas Plant
FYR Five-Year Review
IIGE Iowa-Illinois Gas and Electric Company
IDNR Iowa Department of Natural Resources
LLC Limited Liability Company
LNAPL Light Nonaqueous Phase Liquid
MCL Maximum Contaminant Level
NPL National Priorities List
OU Operable Unit
O&M Operation and Maintenance
PAHs Polynuclear Aromatic Hydrocarbons
PECs Probable Effects Concentrations
PQL Practical Quantitation Limit
RAO Remedial Action Objective
RBC Risk Based Concentration
ROD Record of Decision
RSL Regional Screening Level
TBCs To Be Considereds
TI Technical Impracticability
UCL Upper Confidence Limit
VOC Volatile Organic Compound
Hg/kg Microgram per kilogram
jig/L Microgram per Liter
|iig/m3 Microgram per cubic meter
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EXECUTIVE SUMMARY
This is the first Five-Year Review (FYR) for the Iowa City Former Manufactured Gas Plant (FMGP)
Superfund site located in Iowa City, Johnson County, and Iowa. The purpose of this FYR is to review
information to determine if the remedy is and will continue to be protective of human health and the
environment. The triggering action for this statutory review is the date of the start of on-site construction
of the remedial action.
The site is located east of downtown Iowa City at 505 East Burlington Street in a mixed commercial and
residential area and is approximately 1.5 acres in size. The site property is currently occupied by the
Iowa-Illinois Square (formerly known as the Iowa-Illinois Manor) apartment building, which contains
54 units, occupied by approximately 150 residents. The apartment building and paved parking areas
cover the majority of the site.
Ralston Creek runs parallel to Van Buren Street, which is located on the west side of the site, and
adjacent to the site. This reach of the creek is tile lined and heavily vegetated. The city owns the creek in
this area.
Manufactured coal gas was produced at the site beginning in approximately 1857 until approximately
1937, when natural gas became available in the area. The production of manufactured gas created waste
products that are resistant to natural decay and typically remain at FMGP sites for decades. The primary
waste is a dense, oily liquid known as "coal tar", which condensed out of the gas during various stages
of its production, leading to contamination of soil, groundwater and sediment which came into contact
with the coal tar. Coal tar is a mixture of chemicals known as polynuclear aromatic hydrocarbons
(PAHs) and volatile organic compounds (VOCs), specifically benzene, toluene, ethylbenzene and
xylenes (BTEX). Other contaminants frequently associated with the production of manufactured gas are
arsenic, cyanides and some metals.
In 1983, during the design and construction of the apartment building, an investigation was conducted
by the property owner due to the discovery of oily wastes at the site. During this investigation, it was
determined that fill material containing what was believed to be manufactured gas plant refuse was
present in the subsurface. As a result of the discovery of this material in the subsurface and vapors
encountered during the investigation, the design of the foundation of the apartment building was
modified, a liner was placed under a portion of the building and a passive venting system was installed
in the crawl space.
In March 1999, the EPA, MidAmerican Energy Company and the Iowa-Illinois Manor Partnership
entered into an Administrative Order on Consent (AOC) for site characterization activities. In December
2003, when the EPA determined that a time-critical removal action was necessary to remove
contamination associated with the FMGP along the northern edge of the site, MidAmerican and the
Manor Partnership entered into a second AOC to conduct this work. In January 2004, MidAmerican
removed the contents of the underground tank, filled it with inert material, and recovered groundwater
and light nonaqueous phase liquid (LNAPL) from two monitoring wells.
In August 2004, MidAmerican and the Manor Partnership entered into a third AOC with the EPA to
conduct a feasibility study. MidAmerican conducted some additional limited field investigations,
completed a treatability study involving the removal of LNAPL, and completed a Feasibility Study
Report dated June 2006.
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In September 2006 the EPA signed a Record of Decision (ROD) that selected the remedy for the site.
The major components of the selected remedy are:
• Implementation of institutional controls to prohibit the installation of water wells, maintain
conditions in Ralston Creek, and maintain conditions within the lowa-Illinois Square apartment
building.
• Implementation of a technical impracticability (TI) waiver of applicable or relevant and appropriate
requirements (ARARs) within the identified TI zone.
• Groundwater monitoring for contaminants of concern (COCs) and natural attenuation parameters.
• Evaluation of potential indoor air exposure at off-site locations from groundwater within the TI
zone.
• Sediment monitoring for COCs in Ralston Creek.
• Indoor air monitoring for COCs in the Iowa-Illinois Square apartment building.
• Recovery of LNAPL from the unconsolidated aquifer.
On November 26, 2008, MidAmerican Energy Company and Iowa-Illinois Manor, LLC, entered into a
Consent Decree to perform a remedial design and remedial actions at the site. Remedial actions include
recovery of LNAPL from monitoring wells; monitored natural attenuation of groundwater; monitoring
of air, sediment, and groundwater; and implementation of ICs, including environmental covenants. The
remedial design was started on July 10, 2008, and concluded on January 29, 2010. On-site construction
of the remedial action began on February 17, 2010.
The remedy is performing as expected, with natural attenuation processes continuing to occur in the
contaminated groundwater plume as demonstrated through evaluation of contaminant concentrations and
natural attenuation parameters. Groundwater outside of the TI zone is meeting the action levels except
for elevated levels of manganese at MW-7 and intermittent elevated levels of naphthalene at MW-35.
MW-7 is upgradient of the contamination source so it is likely that the manganese is naturally occurring
and not the result of contamination from the site.
Sediment sampling results have been quite variable, with six of the nine COCs exceeding the
performance standards in one downstream sample in 2011, compared to one COC performance standard
exceedance in 2012 and none exceeded in 2013. As additional samples are collected, the statistical
analysis of this data will become more robust. The condition of the tile lining has not degraded
significantly during the remedial action but there are areas of damage, which was discussed with
representatives of the city during the five-year review inspection.
LNAPL gauging and recovery continues consistent with the LNAPL Recovery Plan. LNAPL recovery
has been minimal since the beginning of the remedial action.
Air in the crawlspace beneath the Iowa-Illinois Square apartment building is monitored through annual
sampling for benzene and naphthalene, the COCs present at the site that are sufficiently volatile to
potentially move from groundwater into air. While low levels of benzene have been detected in air in the
crawlspace that exceeded the indoor air action level on two occasions, these wells were within the
acceptable cancer risk range and remain protective of human health for indoor air for apartment
dwellers. Naphthalene has not been detected above the analytical detection limit.
An institutional control in the form of an environmental covenant was filed with the Johnson County
Recorder on June 4, 2009, on the site property, currently occupied by the Iowa-Illinois Square
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apartments. The environmental covenant prohibits installation of wells on the site, other than monitoring
wells, restricts excavation deeper than six feet below grade without prior notification and approval of the
EPA except in cases of emergency, and requires notification to the EPA a minimum of 60 calendar days
prior to transfer of title of the property or change in use.
An institutional control in the form of an environmental covenant was filed with the Johnson County
Recorder on December 15, 2010, on the stretch of Ralston Creek located west of the site. The
environmental covenant prohibits installation of wells on the property, other than monitoring wells and
restricts excavation or other disturbance to the tile lining without prior notification and approval of the
EPA, except in cases of emergency.
Additional institutional controls in the form of a state rule governing installation of wells in areas of
contamination, a city code requiring connection to the public water supply and a county ordinance
requiring notification regarding setbacks from contamination for groundwater well installation remain in
force and provide additional layers of protection.
The remedy for the Iowa City FMGP site is protective of human health and the environment.
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Five-Year Review Summary Form
SI I !-. Ii)I \ 1 11 1( \ I l<>\
Site Name: Iowa City Former Manufactured Gas Plant Site
EPA ID: IAD 984591172
Region: 7
State: 1A
City/Countv: Iowa < 'its 'Johnson County
NPL Status: Non-NPL
Multiple Oils?
No
Has the site achieved construction completion?
Yes
Lead agency: EPA
/If "Other 1 'ederai Agency", enter Agency name/: I
Author name (Federal or State Project Manager): Diana Engeman
Author affiliation: EPA-Region 7
Review period: 1/28/2014-1/12/2015
Date of site inspection: 7/7/2014
Type of review: Statulorv
Review number: 1
Triggering action date: 2/17/2010
Due date (fiveyears after triggering action date)-. 2/17/2015
issues/Recommendations
OU(s) without IsMies/Rfcumim'ndiilifins Identified in the five Yoor Review:
OU 00. There are no issues or recommendations identified in the Five-Year Review,
Sitewide Protectiveness Statement
Protectiveness Determination; Addendum Due Date (if applicable);
Protective
Protectiveness Statement; The remedy at the Iowa City Former Manufactured Gas Plant site is
protective of human health and the environment,
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I. INTRODUCTION
The purpose of conducting a five-year review (FYR) is to evaluate the implementation and performance
of a remedy to determine if the remedy continues to be protective of human health and the environment.
The methods, findings and conclusions of a FYR are documented in a FYR report. In addition, a FYR
report identifies any issues found during the review, and documents any recommendations to address the
issues.
The U.S. Environmental Protection Agency conducts a FYR and prepares a FYR report pursuant to the
Comprehensive Environmental Response, Compensation and Liability Act, section 121, and the
National Contingency Plan. CERCLA 121 states:
If the President selects a remedial action that results in any hazardous substances,
pollutants, or contaminants remaining at the site, the President shall review such remedial
action no less often than each five years after the initiation of such remedial action to
assure that human health and the environment are being protected by the remedial action
being implemented. In addition, if upon such review it is the judgment of the President
that action is appropriate at such site in accordance with section [104] or [106], the
President shall take or require such action. The President shall report to the Congress a
list of facilities for which such review is required, the results of all such reviews, and any
actions taken as a result of such reviews.
The EPA interpreted this requirement further in the National Contingency Plan, 40 Code of Federal
Regulations section 300.430(f)(4)(ii), which states:
If a remedial action is selected that results in hazardous substances, pollutants, or
contaminants remaining at the site above levels that allow for unlimited use and
unrestricted exposure, the lead agency shall review such actions no less often than every
five years after the initiation of the selected remedial action.
The EPA conducted a FYR on the remedy implemented at the Iowa City Former Manufactured Gas
Plant (FMGP) Superfund site in Iowa City, Johnson County, Iowa. The EPA is the lead agency for
developing and implementing the remedy for the site. The Iowa Department of Natural Resources
(IDNR), as the support agency representing the state of Iowa, has reviewed the supporting
documentation and provided input to the EPA during the FYR process.
This is the first FYR for the Iowa City FMGP Superfund site. The triggering action for this statutory
review is the date of the start of on-site construction of the remedial action. The FYR is required because
hazardous substances, pollutants or contaminants remain at the site above levels that allow for unlimited
use and unrestricted exposure. The site is addressed as one Operable Unit (OU). This OU is the subject
of this FYR.
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A. SITE CHRONOLOGY
Table 1
\ \«111
i»afi'
Initial discovery of problem or contamination
12 12 1990
Preliminary Assessment complet
4 19 1991
Site Investigation completed
8 7' 1996
Expanded Site Investigation completed
9'9/1998
Administrative Order on ( on^em t V'H > lor Site t haracterization signed
3'291999
AOC for Removal Action si a
12 16 2003
Removal Action completed
6/2004
AOC for Feasibility Study signed
3 '2004
Remedial Investigation Feasibility Stud) complete and Record of Decision (ROD)
signed
9 26 2006
ROD modified by memorandum
008
Consent Decree entered
6 20081
Remedial Design start
^ 74(1,2008
Remedial Design complete
9 2
On-site Remedial Action construction start
2/17/2010
Construction completion date
8 2 7'
B. BACKGROUND
Physical Characteristics
The site is located east of downtown Iowa City at 505 F.ast Burlington Street in a mixed commercial and
residential area and is approximately 1.5 acres in si/e. The site property is currently occupied by the
Iowa-Illinois Square apartment building. Nearby commercial enterprises include the I.&NT Mighty Shop,
a convenience store and gas station, to the north: an apartment building to the south on the property
previously occupied by two auto garages. To the west, across Ralston Creek, the Burlington Commons
apartment building was constructed on property previously occupied by Hanson Auto Body Shop. The
Iowa City Recreation Center and municipal parking lot are located northwest of the site. The current site
layout is shown in Figure 1. The site \ icinity ant! current groundw ater monitoring network is depicted in
Figure 2.
Land and Resource Use
The site property is currently occupied by the Iowa-Illinois Square (formerly known as the Iowa-Illinois
Manor) apartment building, which contains 54 units, occupied by approximately 150 residents. As
shown in Figure 1, the apartment building and paved parking areas cover the majority of the site. Grass-
covered and landscaped areas arc located along the adjacent streets and along the margins of the
building with the exception of the eastern side of the building, which is covered with landscaping rock.
Ralston Creek runs parallel to Van Burcn Street, which is located on the w est side, and adjacent to the
site. This reach of the creek is tile lined and heavily \ egetated. The city owns the creek in this area.
A survey of water wells and potential groundwater usage within a one-mile radius of the site was
conducted. Eleven water wells were identified within the search radius and four of these are potentially
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used as a source of drinking water. None of the existing water wells are located in the contaminated
plume area or are likely to ever be impacted by the site.
The city supplies potable water to the University of Iowa, residences and businesses within the city
limits of Iowa City. The municipal water supply is drawn from intakes located on the Iowa River and a
well field located north of Iowa City, outside the one-mile search radius. Wells screened in the Silurian
and Cambro-Ordovician aquifers within the one-mile radius and owned by the University were utilized
by the city primarily for blending with the surface water supply during spring runoff. However, with the
completion of a new city water treatment plant, the city no longer uses these wells as a blending source.
The University also supplies some of its own water. The University-owned wells described in the
previous paragraph are on standby as a potential blending source for times when the University's surface
water supply is not of suitable quality. The other water wells located within the one-mile radius are not
utilized for drinking water.
The potential for new water well installations within the search radius is low. The city enforces a
municipal ordinance (City Code Section 14-3C-10) that prohibits the installation of private water wells
where a municipal water supply line is available within 300 feet. Additionally, the ordinance provides
the city authority to require owners of existing private wells to connect to the municipal water supply if
a water supply line exists within 300 feet. The Iowa City well ordinance has been approved for use as an
institutional control by the IDNR for leaking underground storage tank sites and other state-lead
projects.
Ralston Creek is a perennial stream with highly variable flow. It is managed primarily for storm water
drainage rather than for recreational use. Buried utility lines run beside and beneath Ralston Creek near
the site. In the immediate vicinity of Ralston Creek, it appears that groundwater discharges to the creek
under base-flow conditions. It is not anticipated that the use or management of the creek will change in
the future. The stretch of the creek adjacent to the site is owned by the city.
Ralston Creek ultimately discharges in the Iowa River several miles downstream of the site. The
confluence of Ralston Creek and the Iowa River is a fishery and likely a nursery for fish. The Iowa
River is used as a source of drinking water for the city of Iowa City and the University. It is not
anticipated that this usage will change in the future.
History of Contamination
Manufactured coal gas was produced at the site beginning in approximately 1857 until approximately
1937, when natural gas became available in the area. After ceasing gas production, the facilities were
used into the 1950s for distribution of natural gas. The layout of the FMGP facilities as they existed in
1926 is shown in blue in Figure 1.
The production of manufactured gas created waste products that are resistant to natural decay and
typically remain at FMGP sites for decades. The primary waste is a dense, oily liquid known as "coal
tar", which condensed out of the gas during various stages of its production. Although some of this coal
tar was sold, substantial amounts leaked from storage and processing facilities or was discharged at the
site. Soil, groundwater and sediment which came into contact with the coal tar became contaminated,
and in many cases, continues to be contaminated. Coal tar was a mixture of chemicals known as
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polynuclear aromatic hydrocarbons (PAHs) and volatile organic compounds (VOCs), specifically
benzene, toluene, ethylbenzene and xylenes (BTEX). Other contaminants frequently associated with the
production of manufactured gas are arsenic, cyanides and some metals.
The Iowa City FMGP operated under several names throughout its period of operation. For the majority
of the years it was operated by Tri-City Railway and Light Company, a subsidiary of United Light and
Power Company. In the early 1940s Iowa-Illinois Gas and Electric Company (IIGE) purchased Tri-City
Railway and Light Company.
Following closure of the manufactured gas plant operations, the site was utilized by IIGE as a service
facility until approximately 1971. At some point after 1971, the property was sold to Ron Shank, who
operated a bar on the property. The property was purchased from Ron Shank on December 31, 1982, by
the Iowa-Illinois Manor Partnership. The buildings on the property were demolished and the Iowa-
Illinois Manor apartments were constructed in 1983. The property is currently owned by Iowa-Illinois
Square, following its June 18, 2009, purchase from the Iowa-Illinois Manor Partnership.
In 1983, during the design and construction of the apartment building, an investigation was conducted
by the property owner due to the discovery of oily wastes at the site. During this investigation, it was
determined that fill material containing what was believed to be manufactured gas plant refuse was
present in the subsurface. As a result of the discovery of this material in the subsurface and vapors
encountered during the investigation, the design of the foundation of the apartment building was
modified, a liner was placed under a portion of the building and a passive venting system was installed
in the crawl space.
Based on historical maps, Ralston Creek has been relocated twice during development of the area. The
portion of Ralston Creek located near the site has been relocated and channelized from its native
location. An 1839 map of Iowa City shows Ralston Creek meandering across the current location of the
site. Based on a review of Sanborn® maps, it appears the meander at the site was eliminated prior to
1888, and then Ralston Creek was further straightened and tile-lined at some time between 1948 and
1970 to place it in its current location. Ralston Creek is currently located approximately 40 feet west of
the site.
The EPA conducted investigations at the site and issued an Expanded Site Investigation Report in 1998
in which it was determined further investigation was warranted due to the presence of elevated levels of
BTEX, PAHs, cyanides, arsenic and lead. Contamination was found in soil and groundwater.
Initial Response
In March 1999, the EPA, MidAmerican Energy Company (a successor to IIGE) and the Manor
Partnership entered into an Administrative Order on Consent (AOC) for site characterization activities.
From October 1999 through March 2004 MidAmerican conducted this investigative work. The final Site
Characterization Report, dated August 2003, including the baseline risk assessment and all amendments
to the Report, constitute the final Remedial Investigation Report for the site.
In December 2003, the EPA determined that a time-critical removal action was necessary to remove
contamination associated with the FMGP along the northern edge of the site. This work was necessary
to minimize exposure to city and utility workers doing construction work in the area, and to address an
underground tank in the area. MidAmerican and the Manor Partnership entered into an AOC to conduct
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this work. In January 2004, MidAmerican removed the contents of the underground tank, filled it with
inert material, and recovered groundwater and light nonaqueous phase liquid (LNAPL) from two
monitoring wells.
In August 2004, MidAmerican and the Manor Partnership entered into a third AOC with the EPA to
conduct a feasibility study. MidAmerican conducted some additional limited field investigations,
completed a treatability study involving the removal of LNAPL, and completed a Feasibility Study
Report dated June 2006. The Site Characterization Report, the Feasibility Study Report and other
documents in the Administrative Record file may be reviewed for a more complete source of
information regarding the history of the site.
Basis for Taking Action
A baseline risk assessment was conducted as part of the site characterization. It included a human health
baseline risk assessment and a screening level ecological risk assessment. The following lists the
contaminants that were identified as contaminants of concern (COCs) for each media affected:
Soil
Arsenic
Cyanide
Iron
Manganese
Aroclor 1254
Aroclor 1260
Acenaphthylene
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(k)fluoranthene
Benzo(a)pyrene
Chrysene
Dibenzo(a,h)anthracene
Indeno(l ,2,3-c,d)pyrene
2-Methylnaphthalene
Naphthalene
Benzene
Ethylbenzene
Indoor Air
Benzene
Naphthalene
Groundwater
Aluminum
Arsenic
Chromium
Cyanide
Iron
Lead
Manganese
Acenaphthene
Acenaphthylene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fl uoranthene
Benzo(k)fluoranthene
Chrysene
Dibenzo(a,h)anthracene
Fluorene
Indeno(l,2,3-c,d)pyrene
2-Methylnaphthalene
Naphthalene
Phenanthrene
Benzene
Ethylbenzene
Toluene
Xylenes, total
Surface Water
Benzene
Sediment
Arsenic
Iron
Benzo(a)anthracene
Benzo(b)fluoranthene
Benzo(a)pyrene
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Although there were no current exposures to groundwater for residents, it was determined that potential
future exposures through consumption of contaminated groundwater or through inhalation of the vapor
from showering or cooking could present a significant carcinogenic risk as well as noncarcinogenic
health effects if exposure were to occur. The contaminants posing the greatest carcinogenic risks in
groundwater were benzo(a)pyrene, benzene and dibenzo(a,h)anthracene. The majority of the
noncarcinogenic health effects due to exposure to groundwater were posed by naphthalene and benzene.
Contaminants in soil and indoor air did not pose a significant threat provided exposure to subsurface soil
contamination did not occur in the future and site conditions preventing indoor air exposures did not
change in the future.
Exposure to contaminants in surface water did not pose an unacceptable level of risk to humans or
ecological receptors. The significant ecological resource to be protected is the fishery located at the
confluence of Ralston Creek and the Iowa River. It was determined that in the future, comparing
sediment samples from Ralston Creek in the vicinity of the site to consensus-based probable effects
concentrations of PAHs for freshwater ecosystems would serve as an indicator of possible new
contribution of contamination from the site into the creek.
C. REMEDIAL ACTIONS
Remedy Selection
The ROD for the Iowa City FMGP site was signed on September 26, 2006. Remedial action objectives
(RAOs) were developed during the Feasibility Study, utilizing data collected during the remedial
investigation, to aid in the development and screening of remedial alternatives that were considered for
the ROD. Separate RAOs were developed for soil, groundwater, indoor air and Ralston Creek. The
RAOs for the site are to:
• Prevent and/or reduce human exposure to groundwater containing COCs that exceed
applicable or relevant and appropriate requirements (ARARs) or health-based levels.
• Prevent and/or reduce future soil exposure risks to acceptable levels by maintaining the
existing land use. The future soil RAO may be reevaluated if the building is removed or
its use changed.
• Prevent and/or reduce future human exposure to indoor air containing COCs that exceed
health-based levels. ,
• Maintain the existing ecological steady state and prevent and/or reduce future
unacceptable risks to human health and the environment in Ralston Creek.
The major components of the selected remedy are:
• Implementation of institutional controls to prohibit the installation of water wells,
maintain conditions in Ralston Creek, and maintain conditions within the Iowa-Illinois
Square apartment building.
• Implementation of a technical impracticability (TI) waiver of ARARs within the
identified TI zone.
• Monitored natural attenuation of groundwater.
• Groundwater monitoring for COCs and natural attenuation parameters.
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• Evaluation of potential indoor air exposure at off-site locations from groundwater within
the TI zone.
• Sediment monitoring for COCs in Ralston Creek.
• Indoor air monitoring for COCs in the Iowa-Illinois Square apartment building.
• Recovery of LNAPL from the unconsolidated aquifer.
Action levels are the concentrations of the COCs in the affected media that must not be exceeded to
ensure that the RAOs will be met. These levels were initially developed for this site during the
Feasibility Study. The processes for doing so for each media are described below.
The action levels for groundwater were determined based upon the following hierarchy:
• The maximum contaminant level (MCL) pursuant to the Safe Drinking Water Act for the
contaminant when an MCL is available.
• For contaminants without an MCL, the action level is calculated based on an excess
lifetime cancer risk of 1 x 10"6 and/or a target hazard quotient of 1.
• When the calculated risk-based action level is below the laboratory practical quantitation
limit (PQL), the PQL is used as the action level, provided it falls within the acceptable
risk range of lxlO"4 to lxlO"6 excess lifetime cancer risk.
The action levels for groundwater at the site, and the rationale for their selection, as described in the
ROD, are as listed in Table 2.
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Table 2
ACTION LEVELS FOR GROUNDWATER
in ng/L
Contaminant of
Potential Concern
Chemical-
Specific
ARARs
(MCLs)
Risk-Based
Concentration
(RBC)
PQL
Selected
Groundwater
Action Level
(Basis for
Selection)
2-methylnaphthalene
-
61.2
-
61.2 (RBC)
Acenaphthene
-
914
-
914 (RBC)
Acenaphthylene
-
362
-
362 (RBC)
Benzene
5
-
-
5 (MCL)
Benzo(a)anthracene
-
0.009
0.13
0.13 (PQL)
Benzo(a)pyrene
0.2
-
-
0.2 (MCL)
Benzo(b)fluoranthene
-
0.005
0.1
0.1 (PQL)
Benzo(k)fluoranthene
-
0.05
0.14
0.14 (PQL)
Chrysene
-
0.85
-
0.85 (RBC)
Cyanide
200
-
-
200 (MCL)
Dibenzo(a,h)anthracene
-
0.0003
0.033
0.033 (PQL)
Ethylbenzene
700
-
-
700 (MCL)
Fluorene
-
490
-
490 (RBC)
Indeno( 1,2,3-cd)pyrene
-
0.005
0.1
0.1 (PQL)
Naphthalene
-
6.2
-
6.2 (RBC)*
Phenanthrene
-
294
-
294 (RBC)
Toluene
1,000
-
-
1,000 (MCL)
Xylenes, total
10,000
-
-
10,000 (MCL)
Manganese
-
' 775
-
775 (RBC)
Cyanide
200
-
-
200 (MCL)
Note:
* The groundwater action level for naphthalene was 6.2 jag/L in the 2006 ROD. It was changed to
1.1 jj.g/L based on a change from health-based levels for noncancer health effects to humans to health-
based levels due to cancer risk to humans. This change was documented in a June 17, 2008,
Memorandum for Record.
Soil action levels were not established as surface soil at the site does not pose an unacceptable level of
risk. Prevention of future exposure to subsurface soil is addressed through institutional controls.
Action levels for indoor air were calculated for benzene and naphthalene based on an excess cancer risk
of 1 x 10"6 and/or a target hazard quotient of 1. The action levels for benzene and naphthalene in indoor
air, established in the ROD, were 0.8 microgram per cubic meter (jag/m3) and 1.3 |ig/m3, respectively.
The action level for naphthalene in indoor air was changed from 1.3 |J.g/m3 to 0.056 |J,g/m3 in a June 17,
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2008 Memorandum for Record. The action level was modified due to a change from health-based levels
for noncancer health effects to human beings to health-based levels due to cancer risk in humans.
Sediment samples from Ralston Creek were compared against consensus-based probable effects
concentrations (PECs) of PAHs for freshwater ecosystems (nonhuman receptors) as indicators of
possible contribution of contaminants from the site into the creek. PECs are contaminant concentrations
that have been developed for specific compounds above which the inhabitants of a body of freshwater
could be negatively affected. The PECs are listed in Table 3. These levels are significantly lower than
any concentration that would pose a threat to human health, so they are sufficiently low to be protective
of human exposure to creek sediment.
Table 3
RALSTON CREEK SEDIMENT PERFORMANCE STANDARDS
in micrograms per kilogram (jig/kg) dry weight
Contaminant of Performance
Potential Concern Standards
Anthracene
845
Benzo(a)anthracene
1,050
Benzo(a)pyrene
1,450
Chrysene
1,290
Fluoranthene
2,230
Fluorene
536
Naphthalene
561
Phenanthrene
1,170
Pyrene
1,520
Total PAHs
22,800
Remedy Implementation
On November 26, 2008, MidAmerican Energy Company and Iowa-Illinois Manor, LLC, entered into a
Consent Decree to perform a remedial design and remedial actions at the site. Remedial actions include
recovery of LNAPL from monitoring wells; monitored natural attenuation of groundwater; monitoring
of air, sediment, and groundwater; and implementation of institutional controls, including environmental
covenants. The remedial design was started on July 10, 2008, and concluded on January 29, 2010. On-
site construction of the remedial action began on February 17, 2010.
A groundwater monitoring program was designed to monitor groundwater for COCs and natural
attenuation parameters. Groundwater monitoring events have occurred semiannually, generally in April
and October, since October 2009. These data are used to evaluate compliance with groundwater action
levels, groundwater plume stability and remedial action progress via natural attenuation over time.
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It was noted in the ROD that the extent of groundwater contamination in bedrock downgradient of the
site had not been fully characterized during the remedial investigation but that this lack of information
would not change the decision regarding the appropriate remedy. It was further noted that determining
this extent of contamination might necessitate a change in the boundaries of the TI zone. In 2011, two
additional monitoring wells were installed to delineate the downgradient extent of contamination in
bedrock and the TI zone. Those wells are MW-56 and MW-57. Based on sampling of those wells, it was
determined that there was no need to change the boundaries of the TI zone as described in the ROD.
An LNAPL recovery plan was developed to manage the recovery of free product from the
unconsolidated aquifer in the vicinity of monitoring well MW-8 on the northern edge of the site. Per the
LNAPL Recovery Plan, LNAPL recovery and gauging will continue in the wells near MW-8 until the
recovery rate is less than or equal to 0.1 gallon per month and the LNAPL thickness remains less than
0.02 foot for 12 consecutive months. LNAPL is recovered through the placement of absorbent "socks"
in the affected wells to passively recover free product.
In October 2009, at the request of the EPA, the dense nonaqueous phase liquid (DNAPL) thickness was
measured and then the DNAPL was removed in two monitoring wells, MW-26 and MW-27, so that a
recovery rate could be determined. Since that time, the DNAPL has been gauged and removed from
those wells at least semiannually.
An indoor air monitoring program was designed to monitor benzene and naphthalene in the crawlspace
beneath the Iowa-Illinois Square apartment building. Air monitoring is conducted in the crawlspace as
this area is directly over the source of contamination and should be unaffected by sources of the
contaminants other than the site. Benzene and naphthalene can be found in many other sources routinely
found in indoor living spaces, such as cigarette smoke. Air samples are collected annually at three
locations, generally in March. The action levels were established in the ROD for indoor air in living
spaces. Since the air that is sampled is not in the actual living space, the indoor air monitoring program
assumed that there was an attenuation factor of 0.01 for samples collected in the crawlspace so
established that as long as the contaminant levels measured in the crawlspace do not exceed 80 |ig/m3
for benzene or 5.6 |ig/m3 for naphthalene it is assumed that the indoor air in the apartments does not
exceed the indoor air action levels and remains protective of human health.
In addition to air monitoring at the Iowa-Illinois Square apartment building, subslab soil gas at another
off-site building located over the contaminated groundwater plume was sampled in 2010 to determine
whether there were potential off-site impacts to indoor air. It was determined that there were no off-site
indoor air impacts due to the site.
A sediment monitoring program was designed to determine whether there are measurable changes in the
concentrations of contaminants entering Ralston Creek sediment from subsurface soil or groundwater.
Sediment samples are collected annually, generally in October, from two locations near the site. One is
at the upstream end of the site and the other is at the downstream end of the site. During the sampling
event, the tile liner of the creek is inspected to determine whether its condition is remaining relatively
the same. It is recognized that the tile liner has not been completely intact since investigations began at
the site but it has served as a barrier to movement of contamination from the site into the creek in the
condition that it was in at the time the remedy for the site was selected.
An institutional control in the form of an environmental covenant has been placed on the site property
(currently occupied by the Iowa-Illinois Square apartment building) and was filed with the Johnson
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County Recorder on June 4, 2009. The environmental covenant prohibits installation of wells on the site,
other than monitoring wells, restricts excavation deeper than six feet below grade without prior
notification and approval of the EPA except in cases of emergency, and requires notification to the EPA
a minimum of 60 calendar days prior to transfer of title of the property or change in use.
An institutional control in the form of an environmental covenant has been placed on the stretch of
Ralston Creek located west of the site and was filed with the Johnson County Recorder on December 15,
2010. The environmental covenant prohibits installation of wells on the site, other than monitoring wells
and restricts excavation or other disturbance to the tile lining without prior notification and approval of
the EPA, except in cases of emergency.
System Operations/Operation and Maintenance
Operation and maintenance activities at the site include semiannual groundwater monitoring, periodic
LNAPL and DNAPL gauging and recovery, annual inspection of the Ralston Creek tile liner, annual
sediment sampling, annual inspection of the liner and venting system beneath the Iowa-Illinois Square
apartment building and annual sampling of the crawlspace air beneath the building. The condition of all
monitoring wells is noted during each sampling event. The condition of the tile liner in Ralston Creek is
noted during annual sediment sampling and during the last two years representatives of the city have
been present to discuss maintenance of the creek banks. LNAPL recovery has occurred consistent with
the LNAPL Recovery Plan in the Remedial Design.
The operation and maintenance (O&M) costs are shown in the following table. The actual costs were
provided by MidAmerican Energy Company.
Table 4
O&M COSTS
Year
Approximate Cost
2010
$87,000
2011
$282,000
2012
$61,000
2013
$91,000
2014 (January-October)
$65,000
TOTAL
$586,000
These costs are consistent with the O&M costs for this remedy in the ROD, which are estimated to be
approximately $82,000 per year during this period. Not included in that estimate was the additional air
monitoring that occurred in a building over the groundwater plume in 2010 and the installation of two
deep monitoring wells in 2011. These activities account for the elevated costs in 2011.
II. PROGRESS SINCE THE LAST REVIEW
This is the first FYR for this site.
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III. FIVE YEAR REVIEW PROCESS
Administrative Components
MidAmerican Energy Company, the property owner, the city and the state were notified of the initiation
of the FYR. The FYR team was led by Diana Engeman, the EPA Remedial Project Manager for the site.
EPA support personnel on the FYR team included a hydrogeologist, human health and ecological risk
assessors, the site attorney and the community engagement specialist. A representative of the Iowa
Department of Natural Resources reviewed the FYR Report.
The review, which began on January 28, 2014, consisted of the following components:
• Community Involvement
• Document Review
• Data Review
• Site Inspection
• Five-Year Review Report Development and Review
Community Notification and Involvement
Activities to involve the community in the five-year review process were initiated with a notice that was
published in the local newspaper, the Iowa City Press Citizen on April 18, 2014, stating that the EPA
was conducting a review of the remedy at the site and inviting the public to submit any comments to the
EPA. The results of the review and the report will be made available at the site information repository
located at Iowa City Public Library, 123 South Linn Street, Iowa City, Iowa. The EPA did not receive
any comments from the public during the FYR.
Document Review
This FYR consisted of a review of relevant documents including annual progress reports and monitoring
data. Applicable groundwater, sediment and air cleanup standards as listed in the September 2006 ROD,
as modified by a memorandum dated June 17, 2008, were reviewed. A list of documents reviewed is in
Attachment 1.
Data Review
Groundwater
Groundwater sampling has occurred semiannually, in April and October, since the start of the remedial
action in 2010. Several of the wells have been sampled periodically since 1999. Sampling is conducted
to determine if COC concentrations in groundwater outside the TI zone comply with the action levels
and natural attenuation processes are sufficient to maintain COC compliance with action levels outside
the TI zone. During each sampling event, water levels are measured in wells so that groundwater flow
direction may be determined in each of the water-bearing units. The unconsolidated aquifer at the site is
an unconfined unit that has been divided into two units, referred to as the water table zone and the
bedrock surface zone, to facilitate evaluation. The groundwater flow at the water table is westerly at the
site with an overall southwesterly flow in this zone, toward the Ralston Creek channel. Groundwater
flow at the bedrock surface is consistently in a southwesterly direction at the site. Groundwater flow in
the Devonian and Silurian bedrock aquifers is southwesterly at the site.
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Compliance with action levels outside of the TI zone is evaluated by sampling seven compliance
monitoring wells: MW-7, MW-29, MW-33, MW-35 MW-41, MW-56 and MW-57, for the COCs listed
in Table 2. Well locations can be referenced in Figure 2. Compliance with the action levels is
determined by performing a statistical hypothesis test. A 95-percent upper confidence level (UCL) of the
true mean concentration for each COC is calculated using data from the site. By definition, the 95-
percent UCL of the true mean concentration of a COC at a monitoring well is a value that, when
calculated repeatedly for randomly drawn data sets, equals or exceeds the true mean concentration of the
COC 95-percent of the time.
Thirteen of the seventeen COCs have not been detected in any of the seven compliance monitoring wells
during the remedial action monitoring events. The 13 COCs that have not been detected are benzene,
toluene, ethylbenzene, xylenes, acenaphthylene, benzo(a)anthracene, benzo(a)pyrene,
benzo(b)fluoranthene, benzo(k)fluoranthene, chrysene, debenzo(a,h)anthracene, indeno(l,2,3-cd)pyrene
and cyanide. In the unconsolidated aquifer, only manganese at MW-7 exceeded the action level.
Manganese levels have fluctuated above the risk-based level during sampling events since the
implementation of the remedial action. Because MW-7 is upgradient of the TI zone and the site, and
manganese is not present in other compliance wells in the unconsolidated aquifer, it is probable that
elevated levels of manganese in this well are naturally occurring and not site-related.
In the bedrock aquifer, the action level for naphthalene was exceeded at MW-35 in October 2010 and
April 2013. However, the April 2013 detection of naphthalene at 1.11 ng/L only exceeded the action
level of 1.1 ng/L by a very small amount and was also detected in the associated method blank, bringing
into question the validity of this value. Manganese exceeded the action level at MW-33 in April 2010.
The exceedances of naphthalene and manganese have been sporadic and do not indicate any plume
stability issues. There have been no other exceedances of an action level in the compliance monitoring
wells in the bedrock aquifer. Attachment 2 lists the groundwater monitoring results.
Containment of the contaminated groundwater plume within the TI zone through natural attenuation
processes is evaluated through analysis of COC concentrations and plume stability. Trends in
contaminant mass and plume stability provide the primary line of evidence of the natural attenuation of
COCs. Geochemical data provide a secondary line of evidence of natural attenuation by indicating
destruction of COC mass through biodegradation processes. Concentrations of COCs are measured at
wells within the Tl zone as well as at the compliance wells outside the TI zone to evaluate the COC
distribution throughout the plume. The Mann-Kendall trend test analysis is used to identify increasing
and decreasing concentration trends at the 90-percent confidence level for each COC detected in each
monitoring well. Detailed analyses of each COC at each monitoring well is included in each Remedial
Action Annual Report. Numerous field measurements and laboratory analyses were performed to
evaluate the destruction of COC mass through biodegradation processes. Detailed analyses of these data
are reported in each Remedial Action Annual Report.
Attachment 4 is a table that shows the most recent summary of this trend analysis. The contaminated
groundwater plume appears to be stable, however, 8 of 13 wells sampled within the TI zone has at least
one COC with a statistically significant increasing concentration trend. These data also indicate that 17
of 19 COCs exhibit no statistically significant trend or a statistically significant decreasing concentration
for each of the seven compliance monitoring wells which are outside of the TI zone. Naphthalene was
determined to be statistically increasing at MW-35 at the 90-percent confidence level. Manganese was
determined to be statistically increasing at MW-35 but has not exceeded the action level since October
2003. The furthest downgradient monitoring wells within the TI zone are MW-36 and MW-37, which
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are located approximately 75 feet from the southwest boundary of the TI zone. Benzene exceeded the
MCL in samples from these wells in 2013. In addition, six COCs have statistically significant increasing
concentration trends at these wells but have not ever exceeded the action level. Compliance wells MW-
56 and MW-57 are over 500 feet downgradient of MW-36 and MW-37 therefore it is possible for
elevated levels of benzene to exist in groundwater in the area between these monitoring points.
Locations of the monitoring wells were determined based on the ability to obtain access to the property
for well installation and continue to have access for long-term monitoring. It is difficult to place
monitoring wells in technically optimal locations in an area as highly developed as the one where this
plume is located.
It has been concluded that natural attenuation of organic COCs is occurring as depth increases through
various microbial degradation processes along the groundwater flow path to the southwest.
Based on limited exceedances of COCs in compliance monitoring wells, and the evidence that
biodegradation is occurring within the TI zone, it is concluded that the plume is stable and the TI zone
established in the 2006 ROD is still appropriate.
LNAPL Gauging and Recovery
Significant quantities of LNAPL were observed in monitoring wells LMW-4, MW-2, MW-8, MW-44,
MW-47 and MW-48 during the course of investigations at the site. Prior to completion of the feasibility
study, a treatability study was conducted to assess vacuum extraction for recovery of LNAPL. During
the course of that treatability study, which took place from April through August 2005, approximately
105 gallons of LNAPL were removed from LMW-4, MW-8 and MW-48 through vacuum extraction,
with the rate decreasing significantly with each recovery event. It was determined through data gathered
during that study that the use of absorbent socks would be the most effective method to remediate
residual LNAPL.
Six monitoring wells that are within the TI zone were originally designated as LNAPL recovery wells in
the LNAPL Recovery Plan. The wells are LMW-4, MW-2, MW-8, MW-44, MW-47 and MW-48.
Monitoring wells MW-3, MW-45, MW-46, MW-49, MW-50 and MW-51 were gauged to monitor for
potential migration of LNAPL. In general, the plan was to place absorbent socks into wells that had a
measurable amount of LNAPL of greater than 0.02 foot. A sock would remain in the well until a
recovery rate is less than or equal to 0.1 gallon per month and the LNAPL thickness is less than 0.02
foot for 12 consecutive months. Gauging and recovery was to occur every two weeks to begin with and
eventually move to a quarterly basis when the rate of LNAPL recovery warranted the reduced
frequency.
LNAPL gauging and recovery began in March 2010. Biweekly events ended after one month because
the absorbent socks were not fully saturated. Gauging and recovery continued on a monthly basis for
three months and then decreased to a quarterly basis because, once again, the socks were not fully
saturated. LNAPL gauging and recovery continues on a quarterly basis except at MW-46 and LMW-4.
MW-46 was abandoned in 2013 due to an obstruction in the well. LNAPL greater than 0.02 foot in
thickness had not ever been measured in that well. In 2013, LMW-4 met the criteria for termination of
LNAPL recovery and monitoring, as stated in the LNAPL Recovery Plan. That well was re-designated
as a monitoring well.
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LNAPL recovery rates at all recovery wells were less than 0.1 gallon per month from March 2010
through 2014 and recovery rates have been very low. LNAPL gauging and recovery will continue as
described in the LNAPL Recovery Plan, with the addition and deletion of recovery wells occurring as
the plan describes and with the approval of the EPA.
DNAPL Gauging and Recovery
DNAPL recovery was not a component of the remedy selected in the ROD but in 2011 the EPA
requested that MidAmerican Energy add semiannual DNAPL gauging and recovery at MW-26 and
MW-27. This request was made by the EPA due to investigative work done in 2009 and 2010 to
determine the rate of DNAPL recovery that could be achieved in these two wells which had historically
been found to have significant amounts on DNAPL in them. DNAPL gauging and recovery was
conducted semiannually in 2011 and quarterly since 2012. Since 2009, 25.5 gallons of DNAPL have
been removed from MW-26 and 6.1 gallons from MW-27. While the rate of DNAPL recovery has
decreased in both wells over this time period, significant quantities of DNAPL continue to be recovered
and current plans are to continue to do so in the future.
Ralston Creek Sediment Sampling and Liner Inspection
Sediment sampling and creek liner inspection have been conducted annually since 2010 to determine
whether changes have occurred that may result in movement of contamination from the subsurface at the
site into the sediment of Ralston Creek. It was recognized at the time the ROD was written that there
were multiple off-site sources of the same contaminants found at the site making their way into the creek
but the levels of those contaminants were found at higher levels in sediment adjacent to the site.
Ensuring that the levels of those contaminants did not increase over time would ensure that the sediment
in the creek did not pose an unacceptable level of risk to ecological receptors or humans. In the ROD, it
was recognized that the liner, while not fully intact, does provide a physical barrier between
contamination at the site and the creek sediment.
Sediment is sampled at one upstream and one downstream location annually and analyzed for total
PAHs and nine COCs: anthracene, benzo(a)anthracene, benzo(a)pyrene, chrysene, fluoranthene,
fluorene, naphthalene, phenathrene and pyrene. Figure 3 shows the sediment sampling locations.
Attachment 3 lists the sediment sampling results. At the upstream sampling location, RC-4, only one
COC, naphthalene, exceeded the performance standard during one sampling event in April 2010. At the
downstream sampling location, RC-5, naphthalene has exceeded the performance standard in 2010,
2011 and 2012. In November 2011, benzo(a)anthracene, chrysene, fluoranthene, phenanthrene and
pyrene were also above their respective performance standards at RC-5. The concentrations of COCs
have been highly variable over time, likely due to the transient nature of sediment in creek channels. It
will be more valuable to evaluate trends in the data rather than relying on the assessment of individual
data points. The Mann-Kendall analysis has been used to evaluate trends but to date, no statistical trends
at the 90-percent confidence level were evident. In addition to review of trends, statistical testing using a
95-percent UCL of the true mean concentration for each COC will be conducted once the minimum of
eight samples needed have been collected. Data will continue to be collected annually and those results
will provide a more robust data set with which to conduct the statistical trend and mean analyses.
The creek liner is inspected annually when the sediment samples are collected. One of the most
significant observations during these inspections has been the amount of vegetation growing along the
steep creek banks. Small vegetation is needed to maintain the stability of the creek bank but large trees
growing along the bank, with roots pushing into the liner, are likely to damage the liner. This has been
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brought to the attention of the city and they have made a commitment to remove the woody growth. The
tile liner has never been in particularly good condition and it has been noted during the annual
inspections that further degradation appears to be occurring, likely due to freeze-thaw cycles. This was
also discussed with representatives of the city during the five-year review inspection and they
acknowledged that it was in the city's best interest to maintain the stability of the creek bank. They said
they were willing to look into whether there was anything they might be able to do to provide at least
minimal maintenance of the liner.
Air Monitoring and Building Inspection
Air sampling of the air in the crawlspace of the Iowa-Illinois Square apartment building has been
conducted annually since March 2010. Air samples are collected from three locations and analyzed for
naphthalene and benzene, the two contaminants in groundwater that are sufficiently volatile to move
from the subsurface soil or groundwater into the crawlspace air. The air monitoring results are shown in
Table 5. The air sampling locations are shown in Figure 4.
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Table 5
AIR MONITORING RESULTS
in Eig/m3
Sample Location
Sample Date
Parameter (jig/m3)
Benzene
Naphthalene
SP-N
March 15-16,2010
ND*
ND
SP-N
March 10-11,2011
0.65
ND
SP-N
March 15-16, 2012
0.68
ND
SP-N
March 12-13,2013
ND
ND
SP-N
March 13-14,2014
0.60
ND
SP-C
March 15-16, 2010
ND
ND
SP-C
March 10-11,2011
0.81
ND
SP-C
March 15-16,2012
0.81
ND
SP-C
March 12-13,2013
ND
ND
SP-C
March 13-14, 2014
0.81
ND
SP-S
March 15-16, 2010
ND
ND
SP-S
March 10-11,2011
0.74
ND
SP-S
March 15-16, 2012
0.79
ND
SP-S
March 12-13,2013
0.66
ND
SP-S
March 13-14, 2014
1.0
ND
DUPLICATE SP-S
March 15-16,2010
ND
ND
DUPLICATE SP-S
March 10-11,2011
0.75
ND
DUPLICATE SP-C
March 15-16,2012
0.85
ND
DUPLICATE SP-N
March 12-13,2013
ND
ND
DUPLICATE SP-N
March 13-14, 2014
0.58
ND
* ND—Non-detect
As described previously, since the air that is sampled is not in the actual living space, the Air Monitoring
Plan established that as long as the contaminant levels measured in the crawlspace do not exceed
performance standards of 80 |ig/m3 for benzene or 5.6 ng/m3 for naphthalene it could be assumed that
the indoor air in the apartments would not exceed the action levels. This was based on an assumption
that an attenuation factor of 0.01 for the crawlspace was appropriate. During the past five years
naphthalene has not been detected in crawlspace air above the detection limit of 2.6 ng/m3. Benzene has
been detected on several occasions with concentrations ranging from 0.58 to 1.0 ng/m3, well below the
performance standard of 80 |ig/m3.
Recently the EPA has revised guidance pertaining to vapor intrusion sampling that establishes an
attenuation factor of 1.0 when using crawlspace samples to predict indoor air levels, rather than an
attenuation factor of 0.01. This means that the air sampling results obtained in the crawlspace should be
compared to the indoor air action levels to determine protectiveness. The benzene levels that have been
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detected in the crawlspace air, in Table 5, exceeded the established indoor air action levels of 0.85
Hg/m3 in 2014. Although the action level was exceeded, the sampling result is still within the acceptable
cancer risk range of lxlO"4 to 1x10". Changes to the Air Monitoring Plan need to be made to reflect the
change in attenuation factor for the crawlspace air sampling. It would also be advisable to determine
whether an analytical method exists that could achieve lower detection limits for both compounds.
During each air sampling event, the condition of the passive venting system and the liner that is under a
portion of the crawlspace is observed. The venting system has always been unobstructed and the liner,
with a thick layer of gravel over the top, has been undisturbed.
Site Inspection
The inspection of the site was conducted on July 7 and 8, 2014. In attendance were Diana Engeman,
EPA project manager; Venessa Madden, EPA ecological risk assessor; Bryan Clark, property owner;
Jennifer Mclvor, Environmental Manager for MidAmerican Energy Company; Kevin Armstrong,
MWH, project manager for MidAmerican's environmental consultant; Ron Knoche, City Engineer, city
of Iowa City; and Ben Clark, Senior Civil Engineer, city of Iowa City. The purpose of the inspection
was to assess the protectiveness of the remedy. The Site Inspection Report is Attachment 5.
The building owner provided access to the crawlspace beneath the Iowa-Illinois Square apartment
building so that conditions there could be observed. There is nothing stored in the crawlspace that could
impact air sampling. The area with the liner cover with gravel was undisturbed.
The members of the city engineering office were present to discuss maintenance of the eastern bank of
Ralston Creek. The city provides maintenance of the creek bank and earlier in the summer had done
some trimming of vegetation on the eastern bank. However, the woody growth along the eastern bank
was not removed and several trees have grown up over the years in that area. While vegetation of the
creek banks helps to maintain the stability of the steep slope, tree roots will tend to have a destructive
effect on the tile liner. The EPA asked that trees and woody growth be removed and continue to be
removed periodically. The city engineer agreed that they could do that. The site inspection also included
an examination of the tile liner conditions, to the extent that it was possible to do so because the water
level was a bit higher than normal and vegetation covered a lot of the liner. The EPA requested that the
city consider more aggressive maintenance to improve or maintain the condition of the liner on the
eastern bank of the stretch of the creek adjacent to the site as it is a physical barrier that limits the
movement of site contaminants into the surface water and sediment in that area.
The city inquired whether the EPA had any grants available that might assist them in their liner
maintenance effort. At this time there are no EPA grant monies available to fund the tile liner and creek
bank maintenance efforts. The city engineer confirmed that maintaining a stable creek bank is something
that the city recognizes as important.
IV. TECHNICAL ASSESSMENT
Question A: Is the remedy functioning as intended by the decision documents?
Remedial Action Performance
The remedy is performing as expected, with natural attenuation processes continuing to occur in the
contaminated groundwater plume within the TI zone as demonstrated through evaluation of the
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contaminant concentrations and natural attenuation parameters that are sampled. Groundwater outside of
the TI zone in the unconsolidated aquifer is meeting the action levels except for sporadic exceedances of
manganese at MW-7. This well is upgradient of the site contamination source so it is likely that the
manganese is naturally occurring and not the result of contamination from the site. In the bedrock
aquifer, the action level for naphthalene was exceeded at MW-35 in October 2010 and April 2013.
However, the April 2013 detection of naphthalene at 1.11 jig/L only exceeded the action level of 1.1
(a,g/L by a very small amount and was also detected in the associated method blank, bringing into
question the validity of this value. Due to the sporadic exceedances and recent sampling results, it was
determined that these results were not indicative of a remedy issue. Manganese exceeded the action level
at MW-33 in April 2010 but has not exceeded risk-based levels since that sampling event in the bedrock
aquifer. There have no other exceedances of an action level in the compliance monitoring wells in the
bedrock aquifer.
Data for each COC in groundwater were statistically evaluated annually for concentration trends using
the Mann-Kendall test. This test is used to identify increasing and decreasing concentration trends at the
90-percent confidence level for each COC detected at each monitoring well. Based on this analysis for
COCs in each well, the contaminated groundwater plume appears to be stable.
Numerous geochemical parameters are measured to determine the presence and identity of
biodegradation processes occurring within the groundwater plume. A detailed description of these
processes are included in each Remedial Action Annual Report. In general, the data analysis supports
the conclusion that intrinsic bioremediation is occurring to some degree throughout the contaminated
groundwater plume.
Sediment sampling results have been quite variable, with six of the nine COCs exceeding the
performance standards in one downstream sample in 2011, compared to one COC exceedance in 2012
and none exceeded in 2013. As additional samples are collected, the statistical analysis of this data will
become more robust. The condition of the tile lining has not degraded significantly during the remedial
action but there are areas of damage, which was discussed with representatives of the city during the
five-year review inspection.
LNAPL gauging and recovery continues consistent with the LNAPL Recovery Plan. Six wells are
identified as recovery wells and an additional six wells were gauged. One of the wells that was gauged,
MW-46, was plugged and abandoned in 2013 due to an obstruction in the well. One recovery well,
LMW-4, was reclassified as a monitoring well in 2013 because it met the criteria for termination of
LNAPL recovery as laid out in the LNAPL Recovery Plan. LNAPL recovery continues at a very low
rate in the remaining five recovery wells Since implementation of the remedy, the PRP have been
recovering DNAPL from two additional bedrock wells where DNAPL has historically been found in
recoverable quantities. DNAPL recovery will continue from these two wells.
The vapor intrusion mitigation system components (liner and passive venting) are operating as intended
in the crawlspace. Air in the crawlspace beneath the Iowa-Illinois Square apartment building is
monitored through annual sampling for benzene and naphthalene, the COCs present at the site that are
sufficiently volatile to potentially move from groundwater into air. While benzene has been detected in
air in the crawlspace and has exceeded the indoor air action level action level in March 2014 and in a
duplicate sample in March 2012, these levels did not exceed the acceptable cancer risk range that would
indicate it could pose a health threat for indoor air for apartment dwellers. Naphthalene has not been
detected above the analytical detection limit. In the future it will be advisable to determine whether an
analytical method is available that can achieve lower detection limits for both compounds.
29
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System Operations/O&M J
The operating procedures, as currently implemented, continue to maintain the effectiveness of the
remedy and are expected to do so in the future. Requests to modify the operating procedures will be
reviewed by the EPA when any requests are made. The process for DNAPL recovery will be added to
the LNAPL Recovery Plan. In addition, the EPA is working with the city to develop a more robust
maintenance plan for woody vegetation and tile integrity in Ralston Creek.
Implementation of ICs and Other Measures
An institutional control in the form of an environmental covenant was filed with the Johnson County
Recorder on June 4, 2009, on the site property, currently occupied by the Iowa-Illinois Square
apartments. The environmental covenant prohibits installation of wells on the site, other than monitoring
wells, restricts excavation deeper than six feet below grade without prior notification and approval of the
EPA except in cases of emergency, and requires notification to the EPA a minimum of 60 calendar days
prior to transfer of title of the property or change in use. This institutional control remains protective,
and has resulted in notification to the EPA twice in the past five years that excavation was required in
areas that were potentially contaminated, ensuring that appropriate measures were taken to protect
workers and the public from exposure and proper disposal of contaminated soil.
An institutional control in the form of an environmental covenant was filed with the Johnson County
Recorder on December 15, 2010, on the stretch of Ralston Creek located west of the site. The
environmental covenant prohibits installation of wells on the property, other than monitoring wells and
restricts excavation or other disturbance to the tile lining without prior notification and approval of the
EPA, except in cases of emergency. This institutional control continues to be protective.
Institutional controls in the form of a state rule governing installation of wells in areas of contamination,
a city code requiring connection to the public water supply and a county ordinance requiring notification
regarding setbacks from contamination for groundwater well installation remain in force and provide
additional layers of protection.
Question B: Are the exposure assumptions, toxicity data, cleanup levels and RAOs used at the time of
the remedy section still valid?
Changes in Standards and To-Be-Considereds (TBCs)
• Have there been changes to risk-based cleanup levels or standards identified as ARARs in the
ROD that call into question the protectiveness of the remedy?
In 2008, the ROD was modified by memorandum to change the action levels for naphthalene in
groundwater and indoor air because a significant change was made to the toxicity values for that
compound which made the previous action levels not sufficiently protective. The revised action
levels in the ROD are protective and reflect the latest science and toxicity information.
No other changes to ARARs or the ROD have been made, and the action levels remain
protective of potential current/future land and resource uses.
30
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Are there newly promulgated standards that call into question the protectiveness of the remedy?
No new standards have been promulgated.
Have TBCs used in selecting cleanup levels at the site changed in way that could affect the
protectiveness of the remedy?
Ecological TBCs are based on Probable Effect Levels (MacDonald et al., 2000), which have not
changed.
Changes in Exposure Pathways
Has land use or expected land use on or near the site changed (e.g., industrial to residential,
commercial to residential)?
Land use of the site remains unchanged but the use of two parcels of property adjacent to or very
near the site have changed since implementation of the remedial action. An apartment building
has been constructed to the south of the site on property previously occupied by two auto
garages. According to the owner of this building, it was constructed on a slab with the garages
occupying the ground level of the building. To the west, across Ralston Creek, the Burlington
Commons apartment building was constructed on property previously occupied by Hanson Auto
Body Shop.
Have any human health or ecological routes of exposure or receptors changed or been newly
identified (e.g., dermal contact where none previously existed, new populations or species
identified on site or near the site) that could affect the protectiveness of the remedy?
No new contaminants, exposure pathways or receptors have been identified.
Are there newly identified contaminants or contaminant sources?
We are not aware of any new contaminants.
Are there unanticipated toxic byproducts of the retnedy not previously addressed by the decision
documents (e.g., byproducts not evaluated at the time of remedy selection)?
No toxic by-products of the remedy have been identified.
Have physical site conditions or the understanding of these conditions changed in a way that
could affect the protectiveness of the remedy?
The tile lining of Ralston Creek is deteriorating partially due to vegetation growing through the
tiles. This lining provides a protective barrier for the creek, as it blocks migration of some of the
site-related waste. If the liner continues to deteriorate, contaminant concentrations in the
sediment may increase. Therefore, the EPA has requested that the city assist with the
maintenance of the liner by removing the woody vegetation that has become established along
the eastern bank of the creek. The city engineer said they were agreeable to this request.
31
-------
Changes in Toxicity and Other Contaminant Characteristics
Have toxicity factors for contaminants of concern at the site changed in a way that could affect
the protectiveness of the remedy?
There have been some changes to the toxicity factors which have changed the regional screening
levels (RSLs) found in the Regional Screening Levels Summary Table
(http://www.epa.gov/region9/superfund/prg/), however none of the changes rise to the level of
significance that would call into question the protectiveness of the remedy. The default exposure
factors were modified in February 2014, therefore some RSLs may have increased based on
current information, while others decreased. The overall impact of those changes may make a
particular RSL increase or decrease, however, the overall effect on the contaminants for this site
does not call into question the protectiveness of the remedy.
Have other contaminant characteristics changed in a way that could affect protectiveness of the
remedy?
No.
Changes in Risk Assessment Methods
Have standardized risk assessment methodologies changed in a way that could affect the
protectiveness of the remedy?
There were no changes to the human health or ecological standardized risk assessment
methodologies that would affect the protectiveness of the remedy.
Recently, vapor intrusion guidance has modified the attenuation factor to 1.0 when using
crawlspace samples to predict indoor air levels, rather than an attenuation factor of 0.01. This
means that the air sampling results obtained in the crawlspace should be compared to the indoor
air action levels to determine protectiveness. The most recent sampling events were analyzed
using the 1.0 attenuation factor and both benzene and napthalene concentrations remain within
the acceptable risk range for both contaminants. Due to this change, it is recommended that
changes to the Air Monitoring Plan be made to reflect the change in attenuation factor for the.
crawlspace air sampling. It would also be advisable to determine whether an analytical method
exists that could achieve lower detection limits for both compounds.
Expected Progress Toward Meeting RAOs
The remedy is progressing as expected toward meeting the RAOs.
The remedy is preventing human exposure to groundwater containing COCs that exceed
applicable or relevant and appropriate requirements (ARARs) or health-based levels.
The remedy is preventing soil exposure risks to acceptable levels by maintaining the existing
land use. If necessary, the future soil RAO may be reevaluated if the building is removed or its
use changed.
The remedy is preventing human exposure to indoor air containing COCs that exceed health-
based levels.
32
-------
• The remedy continues to maintain the existing ecological steady state and prevent and/or reduce
future unacceptable risks to human health and the environment in Ralston Creek.
Question C: Has any other information come to light that could call into question the protectiveness of
the remedy? No.
• Have newly found ecological risks been found?
No.
• Are there impacts from natural disasters (e.g., a 100-year flood)?
No.
• Has any other information come to light which could affect the protectiveness of the remedy?
There have been changes in the use of properties near the site but it is not believed that these
changes in land use impact the protectiveness of the remedy. The property directly south of the
site was originally an auto repair facility. That building and another garage to the south of that
building were demolished and a multi-unit residential building was built on the property. It is
owned by the owner of the Iowa-Illinois Square apartment building. Since they were aware of
the potential for contamination related to the site, the building was constructed on a slab with
garage space on the ground level and living spaces above. This should minimize any potential for
vapor intrusion from the site.
The other property where the land use has changed is across Ralston Creek to the west of the
site. Formerly that property was the location of an automotive body shop. That building was
demolished and a multi-unit apartment building was constructed on the property. Previous
sampling of that property did not indicate that this change in use should be of concern.
Technical Assessment Summary
Based upon a review of the analytical data, an inspection of the site and a review of the institutional
controls for the site, the remedy is performing as intended by the ROD. There is no exposure to
groundwater contamination due to the institutional controls that are in place for the plume within the TI
zone. Groundwater monitoring confirms that water outside the TI zone is not exceeding action levels.
Natural attenuation continues to occur within the contaminated groundwater plume.
The LNAPL recovery system has been effective in reducing the volume of LNAPL in the subsurface
and continues to function as designed. DNAPL recovery from two bedrock wells has been implemented.
This activity is planned to continue and will be incorporated into the LNAPL Recovery Plan.
The implementation of institutional controls for Ralston Creek and maintenance of the creek bank and
liner have been effective in maintaining the ecological steady state in the creek. Improved maintenance
of the eastern creek bank and liner by the city will aid in the future protectiveness of the element of the
remedy.
33
-------
The crawlspace liner and passive venting system continue to prevent exposure to indoor air containing
contaminants above health-based levels as has been demonstrated by air monitoring in the crawlspace.
In the future, levels of air contaminants measured in the crawlspace will be compared to the indoor air
action levels due to a change in the attenuation factor from 0.01 to 1.0 when comparing crawlspace air
samples to indoor air levels. The EPA will work with the PRP to determine if the analytical methods for
indoor air should be modified to allow for lower detection limits.
V. ISSUES/RECOMMENDATIONS AND FOLLOW-UP ACTIONS
There are no issues that adversely affect current or future protectiveness of the remedy.
The following recommendations are technical improvements but do not affect the protectiveness of the
remedy were identified:
• The analytical method utilized for air samples should be reviewed to determine whether a
method is available with detection limits below the indoor air action levels.
• Since the attenuation factor for comparison of crawlspace air samples to indoor air levels is now
1.0, crawlspace air samples should be compared to the air action levels rather than performance
standards that are two orders of magnitude greater than the action levels. The Air Monitoring
Plan should be modified to document this change to the data evaluation protocol and action
levels.
• DNAPL recovery has begun from two monitoring wells with significant product recovery.
DNAPL recovery from these wells will continue and the LNAPL Recovery Plan should be
modified to reflect this change.
During the site inspection, evidence of deterioration of the tile liner in Ralston Creek was identified. The
EPA will work with the city to develop plans for removal of woody vegetation and alternatives to
improve tile liner integrity.
VI. PROTECTIVENESS STATEMENT
Sitewide Protectiveness Statement
Protectiveness Determination: Addendum Due Date (if applicable):
Protective Click here to enter a date.
Protectiveness Statement:
The remedy for the Iowa City FMGP is protective of human health and the environment.
VII. NEXT REVIEW
The next FYR report for the Iowa City Former Manufactured Gas Plant Superfund site is required five
years from the completion date of this review.
34
-------
FIGURE 1
Current Site Layout
-------
c
c
UW-27a
LJ
LM#-3
~I
' LMW-S
~
LMW-2 .
• LM * -6
v_
J
l
u
~
LEGEND-
lmw. WATER TABLE MONITORING WELL (L&M MIGHTY SHOP SITE)
WATER TABLE MONITORING WELL (FMGP SITE)
~ BEDROCK SURFACE MONITORING WELL
NOTES'
1. HISTORIC STRUCTURES SHOWN IN BLUE.
2. HISTORIC MAP SOURCE = 1926 & 1933
SANBORN FIRE INSURANCE MAPS
APPROVED >V
JAMCT IMJMflN
tOEVW AMttTftONO
KEVW MttttTKMO
SO
SCALE IN FEET
MIDAMERICAN ENERGY COMPANY
FORMER MANUFACTURED GAS PLANT SITE
IOWA CITY, IOWA
1TOT
SITE LAYOUT
-------
FIGURE 2
Site Vicinity and Current Groundwater Monitoring Network
-------
_
-------
FIGURE 3
Ralston Creek Sediment Sampling Location & Tile Liner Inspection Area
-------
Lj u
il
L..J,
~
•LMW-6
J
L
~
BURLINGTON STREET
LEGEND:
LMW* WATER TABLE MONITORING WELL
• BEDROCK MONITORING WELL
~ BEDROCK SURFACE MONITORING WELL
o ABANDONED WELL
RC © RALSTON CREEK SEDIMENT SAMPLING LOCATION
I TILE LINER INSPECTION AREA
APPROVED BY
PROJECT MANAGER
KEVIN ARMSTRONG
KEVW ARMSTRONG
KEVIN ARMSTRONG
KEVIN ARMSTRONG
MIDAMERICAN ENERGY COMPANY
FORMER MANUFACTURED GAS PLANT SITE
IOWA CITY, IOWA
RALSTON CREEK
SEDIMENT SAMPLING LOCATIONS
AND TILE LINER INSPECTION AREA
MWH
2-2
-------
FIGURE 4
Air Sampling Locations
-------
Figure 4
BURLINGTON STREET
l-ECEMfr
iMWt WATER TASLt* MONTOKING WEU. (LfcM MIGHT V SHOP SITE)
W«TEH TABLE MONITORING WELL (FUBP SirE)
*¦ BEDROCK SURFACE UOMTOHWC WELL
®AIK SAMPLING LOCATION (ESI)
tl AkBIENT MR SAMPLING LOCATION
920 tt 1S.U
' SANBORN FIRE INSURANCE MAPS
I
® MWH
On Mln«l
MtOAUERICAN ENCKGT COMPANY
FORMER MANUFACTURED
CAS PLANT SHE
iowa cny. iowa
AIR SAMPLING LOCATIONS
43
-------
ATTACHMENT 1
List of Documents Reviewed
-------
ATTACHMENT 1
DOCUMENTS REVIEWED
Record of Decision, Iowa City Former Manufactured Gas Plant Site, Iowa City, Iowa, prepared by
USEPA, September 26, 2006.
Letter regarding Further Evaluation of Metals in Groundwater, from MWH to USEPA, January 17,
2008.
Letter regarding Approval of Elimination of Some Metals from List of COCs, USEPA to MidAmerican
Energy Company, April 10, 2008.
Memorandum for Record regarding Record of Decision Modification, Change to Action Levels for
Naphthalene in Groundwater and Indoor Air, prepared by USEPA, June 17, 2008.
Consent Decree, Docket Number 3:08-cv-0133-JAJ, November 26, 2008.
Quality Assurance Project Plan for Air Monitoring, prepared by Stanley Consultants, Inc., April 2009.
Air Monitoring Program, prepared by Stanley Consultants, Inc., April 2009.
Environmental Covenant, Iowa-Illinois Manor, LLC, May 21, 2009.
Remedial Design Report, prepared by MWH, November 11, 2009.
Air Sampling Report, prepared by Stanley Consultants, Inc., May 2010.
Air Annual Progress Report, prepared by Stanley Consultants, Inc., July 2010.
Environmental Covenant, City of Iowa City, December 15, 2010.
Remedial Action Annual Report 2010, prepared by MWH, March 2011.
Air Sampling Report, prepared by Stanley Consultants, Inc., April 2011.
Air Annual Progress Report, prepared by Stanley Consultants, Inc., June 2011.
Remedial Action Annual Report 2011, prepared by MWH, February 2012.
Air Sampling Report, prepared by Stanley Consultants, Inc., April 2012.
Air Annual Progress Report, prepared by Stanley Consultants, Inc., August 2012.
Remedial Action Annual Report 2012, prepared by MWH, February 2013.
Air Annual Progress Report, prepared by Stanley Consultants, Inc., July 2013.
Remedial Action Annual Report 2013, prepared by MWH, February 2014.
-------
A'VSamP,'n« Report, prepared bvst ,
^'r Annua] Progress Re o " ^ •, May 2014
nc; Decernber 2014
-------
ATTACHMENT 2
Groundwater Monitoring Results
-------
/ \ / Nn
1
y
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW03-GW-001 MW03-GW-002 MW03-GW-003 MW03-GW-004 MW03-GW-0410 MW03-GW-1010 MW03-GW-0411
Standard 25-Oct-1999 22-Jun-2000 11-Jul-2001 12-Dec-2001 09-Apr-2010 06-0ct-2010 13-Apr-2011
DV
VOCs
Units
Benzene
MQ/L
5
175
56
139
125
1540
134
81.8
Toluene
t-tg/L
1000
38.8
7.6
74.3
' 19.7
934
29.0
37.2-
Ethyl benzene
M9/L
700
363
113
382
355
1460
C9 J+
492
298
Xylenes, Total
(jg/L
10000
278
96.6
259
286
1280
285
206
PAHs
Acenaphthene
Hg/L
914
25.6
8.89
23.8
26.4
209
76.5
35.3
Acenaphthylene
ug/L
362
37.5
9.43
20.4
0.19
U
177
11.8
5.75
Anthracene
ug/L
...
0.69
0.54
0.65
1.03
136
2.47
0.994
Berizo(a)anthracene
Mg/L
0.13
0.10
U
0.10
U
0.10
U
0.10
U
51.7
0.100
U
0.111
U
Benzo(a)pyrene
mq/l
0.2
0.10
U
0.10
U
0.10
U
0.10
U
35.3
0.100
U
0.111
U
Benzo(b)fluoranthene
pg/L
0.1
0.10
U
0.10
U
0.10
U
0.10
U
29.1
0.100
U
0.111
U
Benzo(ghi)perylene
|jg/L
...
0.10
U
0.10
U
0.10
U
. 0.10
U
9.36
0.100 .
U
0.111
U
Benzo(k)fluoranthene
ijg/L
0.14
0.10
U
0.10
U
0.10
U
0.10
U
7.16
0.100
U
0.111
U
Chrysene
|jg/L
0.85
0.10
U
0.10
U
0.10
U
0.10
U
40.9
0.100
U
0.111
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.10
U
0.10
U
0.10
U
0.22
2.67
MDL
0.00810
U.MDL
0.111
U
Fluoranthene
ng/L
...
0.10
U
0.23
0.10
U
0.10
U
110
0.337
0.231
Fluorene
Mg/L
490
11.5
3.22
11.7
18.4
184
28.4
10.2
lndeno(1,2,3-cd)pyrene
ng/L
0.1
0.10
U
0.10
U
0.10
U
0.10
U
8.49
0.100
U
0.111
U
Naphthalene
(jg/L
1.1
493
2.83
J
438
501
5370
309
119
Phenanthrene
ng/L
294
7.6
0.58
6.59
12
348
8.18
3.80
Pyrene
^g/L
...
0.19
U
0.19
U
0.19
U
0.19
U
97.7
0.302
0.111
U
1-Meth'ylnaphthalene
ijg/L
...
na
na
na
208
793
288
149
2-Methylnaphthalene
. pg/L
61.2
7.1
0.72
6.13
7.82
132
0.931
0.216
Inoraanics
Cyanide, Total
mg/L
...
8.4
3.21
5.63
J
3.2
na
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
0.0100
U
0.0100
U.CN5
0.0100
U,CN5
Manganese, Total
mg/L
0.775
4
2.8
2.52
2.77
2.45
2.54
1.71
Natural Attenuation Parameters
Nitrate
mg/L
...
1.0 '
U
1.0
U
1.0
UJ
na
na
na
na
Nitrite
mg/L
na
na
na
na
na
na
na
Ammonia
mg/L
...
18
5.27
13.6
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
2.08
2.5
na
na
na
Iron, Dissolved
mg/L
...
na
na
0.20
0.14
na
na
na
Sulfate
mg/L
...
110..
440
120
na
na
na
na
Sulfide
mg/L
. ...
.7-5
0.69
5.6
na
na
na
na
Methane
Mg/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
—
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na.
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Water Table Wells Page 1 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW03-GW-1011 MW03-GW-0412 MW3-GW-1012 MW3-GW-0413 MW3-GW-1013 MW12-GW-001
Standard 25-Oct-2011 12-Apr-2012' 10-0ct-2012 11 -Apr-2013 23-Oct-2013 25-Oct-1999
DV DV DV DV DV
VOCs
Units
Benzene
pg/L 5
82.2
77.2
91.8
20.1
86.1
10
Toluene
pg/L 100C
I 29.7
23.6
29.7
8.90
26.8
1.0
U
Ethyl be nzene
pg/L 700
344
340
435
76.2
360
1.0
U
Xylenes, Total
pg/L 10000 230
218
266
68.1
238
5.3
PAHs
Acenaphthene
pg/L 914
41.1
RL1
J-
59.2
J-
60.4
J-
26.1
J-
54.5
J-
16.1
Acenaphthylene
pg/L 362
14.3
RL1
J-
7.47
J-
5.62
J-
5.46
J-
5.58
J-
33.8
Anthracene
pg/L
2.84
RL1
J-
1.07
J-
0.928
J-
0.900
J-
1.01
U
UJ
0.61
Benzo(a)anthracene
pg/L 0.13
1.00
U.RL1
UJ
0.100
U
UJ
0.100
U
UJ
0.128
U
UJ
1.01
U
UJ
0.10
U
Benzo(a)pyrene
pg/L 0.2
1.00
U.RL1
UJ
0.100
U
UJ
0.100
U
UJ
0.149
U
UJ
1.01
U
UJ
0.10
U
Benzo(b)fluoranthene
pg/L 0.1
1.00
U.RL1
UJ
0.100
U
UJ
0.100
U
UJ
0.287
u
UJ
1.01
U
UJ
0.10
U
Benzo(ghi)perylene
pg/L
1.00
U.RL1
UJ
0.100
U
UJ
0.100
U
UJ
0.181
u
UJ
1.01
U
UJ
0.10
U
Benzo(k)fluoranthene
pg/L 0.14
1.00
U.RL1
UJ
0.100
U
UJ
0.100
U
UJ
0.191
u
UJ
1.01
U
UJ
0.10
U
Chrysene
pg/L 0.85
1.00
U.RL1
UJ
0.100
U
UJ
0.100
U
UJ
0.117
u
UJ
1.01
u
UJ
0.10
U
Dibenzo(a,h)anthracene
pg/L 0.033 0.289
RL1.J.MDL J-
0.0170
U,MDL
UJ
0.0130
U.MDL
UJ
0.181
u
UJ
0.172
u
UJ
0.10
U
Fluoranthene
pg/L
1.00
U.RL1
UJ
0.135
J-
0.258
J-
0.521
u
UJ
1.01
u
UJ
0.10
U
Fluorene
pg/L 490
10.4
RL1
J-
20.8
J-
19.1
J-
8.57
J-
17.4
J-
8.7
lndeno( 1,2,3-cd)pyrene
pg/L 0.1
1.00
U.RL1
UJ
0.100
U
UJ
0.100
U
UJ
0.181
u
UJ
1.01
u
UJ
0.10
U
Naphthalene
pg/L 1.1
270
RL1
J-
212
B1,B
B, J'
227
J-
2.62
B
B,J-
100 .
B*
J-,J+,B
3.32
J
Phenanthrene
pg/L 294
12.2
RL1 .
J-
10.4
J-
10.9
J-
3.00
J-
9.7
J-
10.3
Pyrene
pg/L
1.00
U.RL1
UJ
0.118
J-
0.176
J-
0.585
u
UJ
1.01
U
UJ
0.19
U
1 -Methylnaphthalene
pg/L
237
RL1
J-
232
J-
234
J-
57.8
J-
177
J-
na
2-Methylnaphthale'ne
pg/L 61.2
1.32
RL1
J-
0.414
J-
0.574
J-
. 0.143
J-
1.01
U
UJ
1.8
Inoraanics
Cyanide, Total
mg/L
na
na
na
na
na
0.0694
Cyanide, WAD
mg/L 0.2
0.0100
U
0.0264
0.0100
U
0.0730
0.0233
na
Manganese, Total
mg/L 0.775 1.70
2.40
2.00
1.010
1.2
4
Natural Attenuation Parameters
Nitrate
mg/L
na.
na
na
na
na
1.0
U
Nitrite
mg/L
na
na
na
na
na
0.10
U
Ammonia
mg/L
na
na
na
na
na
2.5
Manganese, Dissolved
mg/L
na
na
na
na
na
na
Iron, Dissolved
mg/L
na
na
na
na
na
na
Sulfate
mg/L
na
na
na
na
na
150
Sulfide
mg/L
na
na
na
na
na
5.2
Methane
pg/L
na
-
na
na
. na
- na
59
Alkalinity, Total
mg/L
na
na
na
na
na
460
Total Kjeldahl Nitrogen
mg/L
na
'na
na
na
na
2.9
Orthophosphate
mg/L
na
na
na
na
na
0.10
U
Total Organic Carbon
mg/L
na
na
na
na
na
26.33
Chloride
mg/L ' —
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/?'s=!=!0J 4 Way-==^\ble Wells of 53
/ \ ! \ f \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW12-GW-002 MW12-GW-003 MW12-GW-004 MW12-GW-005 MW12-GW-1002 MW12-GW-0103 MW12-GW-1003 MW12-GW-0404
Standard 21-Jun-2000 11 -Jul-2001 12-Dec-2001 16-Apr-2002 01-Nov-2002 07-Jan-2003 22-Oct-2003 06-Apr-2004
VOCs
Units
Benzene
Mg/L
5
2.5
15.5
7
1.0
U
2.1
11.0
7.5
1.0
U
Toluene
pg/L
1000
1.0
U
1.0
U
1.0
U
1.0
U
2
U
1.0 u
1.0
U
1.0
U
Ethyl benzene
MS/L
700
1.0
U
1.8
1.0
U
1.0
U
2
U
1.0 u
1.0
U
1.0
U
Xylenes, Total
ms/l
10000
3.0
U
7.3
3.0
U
3.0
U
7
u
3.0 U
2.6
1.0
U
PAHs "
Acenaphthene
MQ/L
914
4.80
40.4
21.9
1.48
21
52
22
2.4
U
Acenaphthylene
Mg/L
362
11.1
82.6
27.3
1.29
1
u
1.0 U
100
8.4
Anthracene
Mg/L
--
0.10
U
0.13
0.39
0.19
U
0.17
0.17
0.51
0.018
Ja
Benzo(a)anthracene
fjg/L
0.13
0.10
U
0.10
U
0.10
U
0.19
U
0.10
u
0.10 U
0.14
u
0.12
U
Benzo(a)pyrene
|jg/i-
0.2
0.10
U
0.10
U
0.10
U
0.19
U
0.10
u
0.10 . U
0.14
u
0.12
U
Benzo(b)fluoranthene
Mg/L
0.1
0.10
U
0.10
U
.0.10
U
0.10
U
0.10
u
0.10 . U
0.052
u
0.048
U
Benzo(ghi)perylene
(jg/L
...
0.10
U
0.10
U
0.10
U
0.10
U
0.10
u
0.10 u
0.21
u
0.19
U
Benzo(k)fluoranthene
ng/L
0.14
0.10
U
0.10
U
0.10
U
0.10
U
0.10
u
0.10 u
0.052
u
0.048
U
Chrysene
Mg/L .
0.85
0.10
U
0.10
U
0.10
U
0.10
U
0.10
u
0.10 u
0.14
u
0.12
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.10
U
0.10
U
0.10
U
0.10
U
0.10
u
0.10. u
0.31
u
0.29
U
Fluoranthene
Mg/L
...
0.10
U
0.10
U
0.10
U
0.19
U
0.18
0.15
1.0
0.12 .
. U
Fluorene
Mg/L
490
1.71
22.8
3.51
0.35
5
5.3
7.2
0.19
Ja
lndeno(1,2,3-cd)pyrene
ng/L
0.1
0.10
U
0.10
U
0.10
U
0.10
U
0.10
0.10 U
0.14
u
0.12
U
Naphthalene
ng/L
1.1
0.33
J
2.05
0.11
0.10
U
1
0.62
0.95
Ja
1.2
U
Phenanthrene
kig/L
294
0.47
13.6
1.1
0.26
5.4
5.1
8.3
0.16
Pyrene
MQ/L
...
"0.19
U
0.19
U
0.19
U
0.19
U
0.1
0.10 U
0.26
U
0.24
U
1-Methylnaphthalene
ug'L .
...
na
na
0.19
U
0.19
U
na
na
na
na
2-Methylnaphthalene
mq/l
61.2
0.19
U
0.19
U
0.19
U
0.19
U
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
0.0217
0.016
0.022
0.010
U
0.009
0.0166
0.018
0.0084
B
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
4.2
3.04
4.39
3
3.41
3.4
2.6
2.1
Natural Attenuation Parameters
Nitrate
mg/L
...
1.0
UJ
1.0
U
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
1.29
2.73
na
na
na
na
na
na
Manganese, Dissolved
mg/L
—
na
2.97
4.69
2.8
3.2
2.92
2.6
2.1
Iron, Dissolved
mg/L
...
na
3.84
4.74
4.9
6.48
6.89
6.0
4.1
Sulfate
mg/L "•
...
140
-130
na
na
na
na
na
na
Sulfide
mg/L
...
0.05
U
0.12
na
na
na
na
na
na
Methane
pg/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total'Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Water Table Wells Page 3 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW12-GW-1004 MW12-GW-0405 MW12-GW-1005 MW12-GW-0406 MW12-GW-1006 MW-12-GW-0407 MW12-GW-1007 MW12-GW-0408
Standard 20-0ct-2004 15-Apr-2005 11-0ct-2005 10-Apr-2006 10-0ct-2006 17-Apr-2007 09-0ct-2007 15-Apr-2008
VOCs
Units
Benzene
M9'L
5
6.0
1.0
U*
3.8
1
U
2.27
1
U
5.09
1
U
Toluene
uq/l
1000
1.0
U
1.0
u-
1.0
U
1
U
1
U
1
U
1
U
1
u
Ethylbenzene
mq/l
700
1.0
U
1.0
U*
1.0
U
1
U
1
U
1
U
1
U
1
u
Xylenes, Total
mq/l
10000
1.9
2.0
U*
1.6
J
3
U
3
U
3
U
3
U
3
u
PAHs
Acenaphthene
tjg/L
914
29
1.2
Ja
50
1.68
33.1
0.915
39.8
2.59
Acenaphthylene
|jg/L
362
110
6.7
180
1.17
49
0.6
34.9
1.87
Anthracene
ijg/L
...
0.80
0.032
Ja
1.2
0.0585
1.94
0.01
U
1.18
0.0264
J
Benzo(a)anthracene
Mg/L
0.13
0.13
u
0.12
U
0.042
Ja
0.019
U
0.00419
J
0.003
U
0.0102
J
0.003
u
Benzo(a)pyrene
Mg/L
0.2
0.13
u
0.12
U
0.034
Ja
0.019
U
0.032
U
0.032
U
0.032
U
0.032
u
Benzo(b)fluoranthene
mq/l
0.1
0.050
u
0.047
U
0.037
Ja
0.037
U
0.013
U
0.013
U
0.013
U
0.013
u
Benzo(ghi)perylene
Mg/L
...
0.20
u
0.19
U
0.20'
U
0.032
U
0.009
U
0.009
U
0.009
U
0.009
u
Benzo(k)fluoranthene
Mg/L
0.14
0.050
u
0.047
U
0.051
U
0.023
U
0.015
U
0.015
U
0.015
U
0.015
u
Chrysene
Mg/L
0.85
0.13
u
0.12
U
0.027
Ja
0.02
U
0.0281
J
0.005
U
0.005
U
0.005
u
Dibenzo(a,h)anthracene
ng/L
0.033
0.30
u
0.28
U
0.31
U
0.033
U
0.01
U
0.01
U
0.01
U
0.01
u
Fluoranthene
Mg/L
...
1.5
0.050
Ja
4.2
0.0813
1.68
0.01
U
1.42
0.01
u
Fluorene
M9/L- .
490
14
0.28
21
0.718
29
0.328
41.1
1.99
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.13
u
0.12
U
0.13
U
0.038
U
0.007
U
0.007
U
0.007
U
0.007
u
Naphthalene
Mg/L
1.1
0.58
Ja
1.2
U
1.3
U
0.104
1.02
0.054
U
14.6
0.054
u
Phenanthrene
. Mg/L
294
15
0.20 .
24
0.271
24
0.0328
J
24.2
0.007
u
Pyrene
ng/L
...
0.34
0.23
Ua
1.8
0.271
6.93
0.019
U
3.44
0.029
J
1 -Methylnaphthalene
Mg/L
...
na
na
na
na
na
na
na
na
2-Methylnaphthalene
ng/L
61.2
na
na
na
na
0.052
U
0.052
U
1.34 ,
0.052
u
Inoraarics
Cyanide, Total
mg/L
...
0.013
0.012
0.0066
B
0.01
U
0.01
U
0.01
U
0.01
U
0.0139
Cyanide, WAD
mg/L
0.2
¦ na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
2.6
2.2
2.9
1.77
2.15
1.85
2.28
' 2.13
Natural Attenuation Parameters
Nitrate
mg/L
...
na
0.10
U
0.10
U
0.1
U
0.1
U
na
na
na
Nitrite
mg/L
...
na
0.020
U
0.020
U
0.1
U
0.1
U
na
na-
na
Ammonia
mg/L
...
na
0.14
B
3.4
0.84
0.84
na
na
na
Manganese, Dissolved
mg/L
...
2.6
2.2
2.7
1.68
na
na
na
na
Iron, Dissolved
mg/L
...
6.6
5.4
6.9
3.55
3.55
na
na
na
Sulfate
mg/L
...
na
53
140
87.9
87.9
na
na
na
Sulfide
mg/L
...
na
1.0
U
0.50
B
1
U
1
U
na
na
na
Methane
Mg/L
na
36
-
59
329
329
na
na
na
Alkalinity, Total
mg/L
...
na
380
350
347
347
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
¦ na
0.73
• 3.8-
1.27
1.27
na
na
na
Orthophosphate
mg/L
...
na
0.015
B
0.050
U
0.1
U
0.1
U
na
na
na
Total Organic Carbon
mg/L
...
na
3.6
3.3
3.46
3.46
na
na
na
Chloride
mg/L
...
na
na .
na
144
144
na
na
na
icgp_gw_2013-10.xlsx
14 Wat^^ble Wells P'-^.4 of 53
! \ 1 \ / \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW12-GW-0410 MW12-GW-1010 MW12-GW-0411 MW12-GW-1011 MW12-GW-0412 MW12-GW-1012
Standard 08-Apr-2010 05-0ct-2010 13-Apr-2011 26-Oct-2011 12-Apr-2012 10-0ct-2012
DV DV DV
VOCs
Units
Benzene
ng/L
5
2.07
15.2
1.00
U
2.52
1.00
U
1.00
U
Toluene
pg/L
1000
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethylbenzene
mq/l
700
1.00
U
1.00
U
1.00
u
1.00
U
1.00
'U
1.00
U
Xylenes, Total
pg/L
10000
6.00
U
7.77
3.00
u
5.15
3.00
U
3.00
U
PAHs
Acenaphthene
Mg/L
914
20.4
J+
65.0
6.32
27.4
J-
5.73
29.8
Acenaphthylene
Mg/L
362
15.4
J+
37.5
3.43
21.6
J-
5.11
31.6
Anthracene
pg/L
...
0.409
J+
1.40
0.100
u
0.340
J-
0.100
U
0.173
Benzo(a)'anthracene
pg/L
0.13
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
0.100
U
Benzo(a)pyrene
ijg/L
0.2
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
0.100
U
Benzo(b)fluoranthene
ng/L
0.1
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
0.100
U
Benzo(ghi)perylene
|jg/L
...
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
0.100
U
Benzo(k)fluoranthene
ng/L
0.14
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
0.100
U
Chrysene
ijg/L
0.85
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
0.100
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.00810
U,MDL
0.00810
U,MDL
0.100
u
0.0207
J.MDL
J-
0.0170
U,MDL
0.0130
U,MDL
Fluoranthene
ng/L
...
0.552
J+
2.78
0.155
0.927
J-
0.15
0.702
Fluorene
fjg/L
490
10.1
J+
30.3
2.00
14.5
J-
1.28
14.7
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
0.100
U
Naphthalene
fjg/L
1.1
0.569
J+
1.89
0.102
0.683
J-
0.186
B UB
0.420
Phenanthrene
Mg/L
294
7.68
J+
23.9
0.741
8.46
J-
0.452
1.46
Pyrene
ug/L
...
0.270
J+
1.56
0.100
u
0.656
J-
0.112
0.488
1-Methylnaphthalene
ng/L
...
1.46
J+
9.14
0.185
0.975
J- .
0.153
0.455
2-Methylnaphthalen'e
^g/L
61.2
0.100
U
0.125
0.100
u
0.100
U
UJ
0.100
0.171
Inoraanics
Cyanide, Total.
mg/L
...
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
0.0100
u
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
1.82
2.55
1.90
2.33
1.65
2.19
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
Iron, Dissolved
mg/L
...
na
na
na
na
na
na
Sulfate
mg/L
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
Methane ;
Mg/L
...
na
-
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Water Table Wells Page 5 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW12-GW-0413 MW12-GW-1013 MW16-GW-001 MW16-GW-002 MW16-GW-003 MW16-GW-004 MW16-GW-005
Standard 11-Apr-2013 23-Oct-2013 26-Oct-1999 22-Jun-2000 11 -Jul-2001 12-Dec-2001 18-Apr-2002
DV DV ¦0
VOCs
Units
Benzene
Mg/L
5
0.500
U
82.7
24.1
8.1
10.2
8.7
6.2
Toluene
M9'L
1000
1.00
U
5.24
56.9
10.6
3.5
2.8
1.7
Ethylbenzene
M9/I-
700
1.00
u
17.3
14.5
5.9
11.7
8.7
4
Xylenes, Total
|jg/L
10000
3.00
u
39.8
111
33.0
28.9
18.6
9.7
PAHs
Acenaphthene
Mg/L
914
2.82
J-
78
12.7
6.36
2.57
6.37
2.3
Acenaphthylene
Mg/L
362
1.39
J-
26
41.7
13.1
3.12
17
6.88
Anthracene
ng/L
...
0.100
u
UJ
1.91
9.5
11.3
3.83
4.38
1.57
Benzo(a)anthracene
|jg/L
0.13
0.100
u
UJ
0.100
U
3.7
5.46
2.86
1.27
0.69
Benzo(a)pyrene
ijg/L
0.2
0.100
u
UJ
0.100
U
1.88
3.75
1.62
0.77
0.44
Benzo(b)fluoranthene
MQ/L
0.1
0.100
u
UJ
0.100
U
0.58
1.53
0.45
0.12
0.14
Benzo(ghi)perylene
|jg/L
...
0.100
u
UJ
0.100
U
0.79
1.81
0.65
0.33
0.18
Benzo(k)fluoranthene
Mg/L
0.14
0.100
u
UJ
0.100
U
0.14
0.10
U
0.11
0.10 U
0.10
U
Chrysene
ng/L
0.85
0.100
u
UJ
0.100
u
1.9
2.98
1.3
0.56
0.39
Dibenzo(a,h)anthracene
ng'L
0.033
0.0177
u
UJ
0.0173
u
0.14
0.11
0.21
0.1
0.10
U
Fluoranthene
ng/i-
...
0.100
u
UJ
3.04
6.5
15.8
6.44
2.64
2.62
Fluorene
. ng/L
490
0.490
J-
30.5
28.3
22.6
4.11
10.1
3.85
lndeno(1,2,3-cd)pyrene
Vg/L
0.1
0.100
u
UJ
0.100
u
0.78
1.30
0.69
0.23
0.2
Naphthalene
Hg/L
1.1
0.310
B
J-
18.2
B* J+,B
190
83.6
0.53
30.8
16.4
Phenanthrene
pg/i-
294
0.100
u
UJ
27.7
28.6
9.71
2.86
12.6
3.77
Pyrene
yg/L
...
0.100
u
UJ
1.13
2.18
7.94
2.16
0.39
' 1.35
1-Methylnaphthalene
(jg/L
...
0.100
u
UJ
89.3
na
na
na
22
na
2-Methylnaphthalene
Mg/L
61.2
0.100
u
UJ
0.192
55.1
0.19
U
0.19
U
2.58
1.1
Inoraanics
Cyanide, Total
mg/L
...
na
na
0.3917
0.217
0.176
J
0.216
0.087
Cyanide, WAD
mg/L
0.2
0.0100
u
0.0100
U
na
na
na
na
na
Manganese, Total
mg/L
0.775
2.120
2.53
4
1.7
0.623
0.694
0.249
' Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
1.0
U
1.0
U
1.0
.UJ
na
na
Nitrite
mg/L
...
na
na
0.10
U
na
na
na
na
Ammonia
mg/L
...
na
na
1.2
0.93
0.63
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
0.231
0.225
0.181
Iron, Dissolved
mg/L
...
na
na
na
na
2.19
2.35
2
Sulfate
mg/L
...
na
na
310
370
300
na
na
Sulfide
mg/L
...
na
na
1.8
0.18
1.0
U
na
¦ na
Methane •
M9/L
...
.- - na
na
279
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
350
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
na
na
1.6
na
na
na
na
Orthophosphate
mg/L
...
na
na
0.10
u
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
35.64
na
na
na
na
Chloride
mg/L
...
na
. na
na
na
na
na
na
icgp_gw_2013-10.xlsx
Wat^^ble Wells of 53
\ / \ / \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW16-GW-1002 MW16-GW-0103 MW16-GW-0404 MW16-GW-0405 MW16-GW-0406 MW16-GW-1006 MW16-GW-0407 MW16-GW-1007
Standard 28-Oct-2002 08-Jan-2003 06-Apr-2004 15-Apr-2005 12-Apr-2006 11-0ct-2006 17-Apr-2007 10-0ct-2007
VOCs
Units
Benzene
MQ/L
5
6.6
9.8
3.2
7.8
*
3.5
. 5.01
3.18
5.2
Toluene
mq/l
1000
2
U
2.0
0.66
Ja
1.6
*
1
U
1
U
1
U
1
U
Ethyl benzene
MQ/L
700
5.1
9.4
2.3
7.6
*
2.45
3.72
2.6
2.56
Xylenes, Total
Mg/L
10000
11
15
4.7
13
-
3
U
4.21
3.18
4.36
PAHs
Acenaphthene
ug/L
914
11
6.3 J
4.1
5.7
3.07
5.15
2.27
8.23
Acenaphthylene
ug/L
362
11
U
10 U
28
78
7.83
14.4
7.51
33.1
Anthracene
(jg/L
2.6
6.0 J
2.2
4.4
2.16
4.1
1.58
3.59
Benzo(a)anthracene
^g/L
0,13
2.5
10 J
0.63
1.9
0.35
0.232
0.108
J
0.361
Benzo(a)pyrene
pg/L
0.2
1.7
6.4 J
0.53
1.2
0.271
0.032
U
0.032
U
0.058
J
Benzo(b)fluoranthene
ug/L
0.1
2.4
8.9 J
0.3
0.69
0.293
0.0529
J
0.013
U
0.013
U
Benzo(ghi)perylene
ug/L
—
0.36
2.2 J
0.19
Ja
0.43
0.0989
J
0.009
U
0.009
U
0.0577
J
Benzo(k)fluoranthene
(jg/L
0.14
0.68
2.5 J
0.17
M
0.45
0.113
J
0.015
U
0.015
U
0.0163
J
Chrysene
Mg/L
0.85
1.6
6.7 J
0.46
1.2
0.334
0.147
0.0969
J
0.204
Dibenzo(a,h)anthracene
ijg/L
0.033
1.20
3.3 J
0.29
U
0.25
J
0.033
u
0.01
U
0.01
U
0.01
U
Fluoranthene
Mg/L
...
8.8
19 J
4.8
9.8
2.78
6.2
2.34
4.72
Fluorene
MQ/L
490
8.2
13 J
7.1
12
9.31
18.5
8.87
26.4
lndeno(1,2,3-cd)pyrene
pg/L
0.1
1.1
U
1.0 U
0.16
0.46
0.132
0.007
U
0.007
U
0.007
U
Naphthalene
Mg/L
1.1
26
16 J
7.6
44
3.53
3.95
3.99
7.19
Phenanthrene
ng/t-
294
6.1
21 J
3.1
13
6.17
10.3
4.22
15.6
Pyrene
^g/L
—
5.4
15 J
1.9
4.8
8
11.3
4.54
12.3
1 -Methylnaphthalene
^g/L
...
na
na
na
na
na
na
na
na
2-Methylnaphthalene
ng/L
61.2
na
na
na
na
na
1.27
0.552
1.78
Inoraanics
Cyanide, Total
mg/L
...
0.217
0.137
0.12
0.17
0.198 .
0.287
0.132
0.264
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.21
1.27
0.15
0.18
0.124
0.174
0.12
0.178
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
0.061
B
0.1
u
na
na
na
Nitrite
mg/L
...
na
na
na
0.012
B
0.1
u
na
na
na
Ammonia
mg/L
...
na
na
na
0.2
U
0.257
na
na
na
Manganese, Dissolved
mg/L
—
0.182
0.268
0.14
0.16
0.13
na
na
na
Iron, Dissolved
mg/L
1.64
2.71
1.7
2.3
2.19
na
na
na
Sulfate
mg/L
...
na
na
na
240
241
na
na
na
Sulfide
mg/L
— .
na
na
na
1.5
1
u
na
na
na
Methane
Mg/L
...
na
na
na
48
26
u
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
360
428
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
0.72
1
u
na
na
na
Orthophosphate
mg/L
...
na
na
na
0.017
B
0.1
u
na
na
na
Total Organic Carbon
mg/L
—
na
na
na
3.3
4.6
na
na
na
Chloride
mg/L
...
na
na
na
na
54.3
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Water Table Wells Page 7 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW16-GW-0408 MW16-GW-0410 MW16-GW-1010 MW16-GW-0411 MW16-GW-1011 MW16-GW-0412
Standard 15-Apr-2008 08-Apr-2010 06-0ct-2010 12-Apr-2011 25-Oct-2011 11-Apr-2012
DV DV
I'OCs
Units
Benzene
Mg/L
5
9.14
30.2
41.4
16.8
10.9
6.62
Toluene
pg/L
1000
1.06
5.40
3.29
5.09
1.00
U
1.00
U
Ethyl benzene
ijg/L
700
6.62
21.0
33.4.
12.8
10.8
6.12
Xylenes, Total
fjg/L
10000
5.56
24.8
33.7
14.3
8.67
4.75
PAHs
Acenaphthene
Mg/L
914
4.63
5.75
5.14
102
4.54
4.10
RL1
J-
Acenaphthylene
Mg/L
362
14.4
16.2
10.0
108
12.9
9.05
RL1
J-
Anthracene
Mg/L
...
1.44
3.19
3.06
2.51
2.31
1.72
RL1
d-
Benzo(a)anthracene
pg/L
0.13
0.34
0.588
2.55
1.96
4.46
3.39
RL1
J-
Benzo(a)pyrene
Mg/L
0.2
0.25
0.575
2.90
1.62
3.64
2.59
RL1
J-
Benzo(b)fluoranthene
ng/i-
0.1
0.218
0.501
2.62
1.51
3.17
2.31
RL1
J-
Benzo(ghi)perylene
Mg/L
...
0.148
0.157
0.923
0.623
1.34
1.00
U.RL1
UJ
Benzo(k)fluoranthene
Mg/L
0.14
0.121 J
0.2
0.920
0.559
1.52
1.14
RL1
J-
Chrysene
pg'L
0.85
0.336
0.520
2.27
1.75
3.64
2.75
RL1
J-
Dibenzo(a,h)anthracene
pg/L
0.033
0.0349 J
0.0547
J,MDL
0.326
MDL
0.207
MDL
0.461
J,MDL J
0.332
RL1.J.MDL
J-
Fluoranthene
Mg/L
...
3.98
3.03
6.94
4.80
5.84
7.85
RL1
J-
Fluorene
ng/L
490
12.5
13.6
7.96
21.5
7.85
4.99
RL1
J-
lndeno(1,2,3-cd)pyrene
pg/i-
0.1
0.138
0.155
0.999
0.612
1.36
1.00
U.RL1
UJ
Naphthalene
Mg/L
1.1
2.77
42.4
39.3
310
6.91
4.18
RL1
J-
Phenanthrene
ng/L
294
5.84
8.38
5.20
35.4
3.82
2.46
RL1
J-
Pyrene
|jg/L
...
2.55
2.30
6.23
4.00
10.7
8.36
RL1
J-
1 -Methylnaphthalene
ug/L
...
na
9.24
21.9
595
7.29
4.19
RL1
J-
2-Methylnaphthalene
|jg/L
61.2
0.855
0.194
0.326
8.82
0.349
1.00
U,RL1
UJ
tnoraanics
Cyanide, Total
mg/L
...
0.131
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
na
0.0198
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.171
0.153
0.102
0.128
0.142
0.29
Natural Attenuation Parameters
Nitrate
mg/L
...
na
0.10
U
0.10
U
0.10
U
0.10
U
0.100
U
Nitrite
mg/L
...
na
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Ammonia
mg/L
...
na
0.461
0.613
0.468
0.535
0.509
Manganese, Dissolved
mg/L
...
na
0.156
0.0797
S3
0.106
0.104
0.146
Iron, Dissolved
mg/L
...
na
1.59
0.906
1.73
1.23
2.38
Sulfate
mg/L
...
na
243
385
244
206
183
Sulfide
mg/L
...
na
5.00
U
5.00
U
17
10
U
10
U
Methane
pg/L
...
na
261
274
87
120
120
Alkalinity, Total
mg/L
...
na
319
201
269
266
306
Total Kjeldahl Nitrogen
mg/L
na
1.00
U
1.19
1.00
U
1.31
1.00
U
Orthophosphate
mg/L
...
na
0.1
U
0.100
U
0.100
U
0.100
U
0.100
U
Total Organic Carbon
mg/L
...
na
2.59
1.93
ET
na
2.50
na
Chloride
mg/L
...
"na
33.6
28.8
na
na
na
icgp_gw_2013-10.xlsx
2//-^=i=
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW16-GW-1012 MW16-GW-0413 MW16-GW-1013 MW18-GW-001 MW18-GW-002 MW18-GW-003 MW18-GW-004
Standard 10-0ct-2012 10-Apr-2013 23-Oct-2013 04-Apr-2000 21-Jun-2000 10-Jul-2001 12-Dec-2001
DV
VOCs
Units
Benzene
ng/L
5
8.21
4.14
6.12
0.5
U
0.5
U
0.5
U
1.0
U
Toluene
mq/l
1000
1.24
1.00
U
1.00
U
1.0
U
1.0
U
1.0
U
1.0
U
. Ethylbenzene
Mg/L
700
8.05
3.64
5.7
1.0
U
1.0
U
1.0
u
1.0
U
Xylenes, Total
|jg/L
10000
7.74
5.25
5.31 ¦
3.0
U
3.0
U
3.0
u
3.0
U
PAHs
Acenaphthene
ug/L
914
6.18
3.06
5.75
0.19
U
0.19
U
0.19
u
0.19
U
Acenaphthylene
pg/L
362
16.5
8.08
10.8
0.19
U
0.19
U
0.19
u
0.19
U
Anthracene
pg/L
...
1.69
1.12
0.969
0.10
u
0.10
U
0.10
u
0.10
U
Benzo(a)anthracene
|jg/L
0.13
1.38
1.57
0.449
0.10
u
0.10
U
0.10
u
0.10
U
Benzo(a)pyrene
pg/L
0.2
0.650
1.76
0.219
0.10
u
0.10
U
0.10
u
0.10
U
Berizo(b)fluoranthene
Mgfl-
0.1
0.708
1.66
0.199
0.10
u
0.10
U
0.10
u
0.10
U
Benzo(ghi)perylene
Mg/L
...
0.168
0.650
0.10
U
0.10
u
0.10
U
0.10
u
0.10
U '
Benzo(k)fluoranthene
|jg/L
0.14
0.23
0.724
0.138
0.10
u
0.10
U
0.10
u
0.10
U
Chrysene
^g/L
0.85
1.05
1.57
0.439
0.10
u
0.10 ¦
U
0.10
u
0.10
U
Dibenzo(a,h)anthracene
pg/L
0.033
0.0666
J.MDL
0.288
0.0332
0.10
u
0.10
U
0.10
u
0.10
U
Fluoranthene
pg/L
...
5.57
4.78
4.03
0.10
u
0.10
U
0.10
u
0.10
U
Fluorene
Mg/L
490
10.6
4.92
8.48
0.19
u
0.19
U
0.19
u
0.19
U
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.170
0.629
0.10
U
0.10
u
0.10
U
0.10
u
0.10
U
Naphthalene
Mg/L
1.1
6.70
7.90
4.28
B" J+,B
0.10
u
0.14
0.14
0.10
U
Phenanthrene
Mg/L
294
4.39
2.18
3.33
0.10
u
0.10
U
0.10
u
0.10
U
Pyrene
Mg/L
...
6.21
4.63
1.61
. 0.19
u
0.19
U
0.19
u
0.19
U
1-Methylnaphthalene
mq/l
...
7.56
6.56
4.02
na
na
na
0.19
U
2-Methylnaphthalene
pg'L
61.2
0.231
0.258
0.312
0.19
u
0.19
U
0.19
u
0.19
U
Inoraanics
Cyanide, Total
mg/L
...
na
na
na.
0.0148
0.0158
J
0.010
u
0.028
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
0.0121
na
na
na
na
Manganese, Total
mg/L
0.775
0.234
0.0974
0.142
2.8
4
5.76
3.26
Natural Attenuation Parameters
Nitrate
mg/L
...
0.100
U
0.471
na
1.0
u
1.0
U
1.0
u
na
Nitrite
mg/L
...
0.100
U
0.100
u
na
na
na
na
na
Ammonia
'mg/L
...
0.492
0.238
na
0.20
u
0.44
0.20
u
na
Manganese, Dissolved
mg/L
...
0.125
0.0704
na
na
na
4.72
2.91
Iron, Dissolved
mg/L
1.74
0.505
na
na
na
1.18
2.7
Sulfate
mg/L
...
169
114
na
310
300
230
na
Sulfide
mg/L
10
U
12.0
na
5.0
UJ
0.05
U
1.0
u
na
Methane
Mg/L
...
180
44.4
na
na
na
na
na
Alkalinity, Total
mg/L
316
255
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
1.00
U
1:00
u
na
na
na
na
na
Orthophosphate
mg/L.
...
0.100
U
0.100
u
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Water Table Wells Page 9 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW18-GW-005 MW18-GW-1002 MW18-GW-0103 MW18-GW-1003 MW18-GW-0404 MW18-GW-1004 MW18-GW-0405 MW18-GW-1005
Standard 16-Apr-2002 30-0ct-2002 08-Jan-2003 22-Oct-2003 07-Apr-2004 19-0ct-2004 14-Apr-2005 12-0ct-2005
VOCs
Units
Benzene
Pg/L
5
1.0
U
2.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
Toluene
pg/L
1000
1.0
U
2.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1-0
U
Ethylbenzene
pg/L
700
1.0
U
2.0
U
1.0
U
1.0
U
1.0
u
1..0
U
1.0
U
1.0
U
Xylenes, Total
pg/L
10000
3.0
U
7.0
•u
3.0
U
1.0
U
1.0
u
1.0
U
2.0
U
2.0
U
PAHs
Acenaphthene
pg/L'
914
0.19
U
0.51
U
0.55
U
2.9
U
2.8
u
2.6
U
2.3
U
2.6
U
Acenaphthylene
Mg/L
362
0.19
U
1
U
1.1
U
1.5
U
1.4
u
1.3
U
1.2
U
1.3
U
Anthracene
pg/L
...
0.19
U
0.051
U
0.055
U.
0.057
U
0.056
u
0.052
U
. 0.047
U
0.052
U
Benzo(a)anthracene
MQ/L
0.13
0.19
U
0.1
U
0.11
U
0.15
U
0.14
u
0.13
U
0.12
U
0.13
U
Benzo(a)pyrene
pg/L
0.2
0.19
U
0.1
U
0.11
U
0.15
U
0.14
u
0.13
U
0.12
U
0.13
U
Benzo(b)fluoranthene
pg/L.
0.1
0.10
U
0.1
U
0.11
U
0.057
U
0.056
u
0.052
U
0.047
U
0.052
U
Benzo(ghi)perylene
pg/L
—
0.10
U
0.1
U
0.11
U
0.23
U
0.22
u
0.21
U
0.19
U
0.21
U
Benzo(k)fluoranthene
pg/L
0.14
0.10
U
0.1
U
0.11
U
0.057
U
0.056
u
0.052
U
0.047
U
0.052
U
Chrysene
pg/L
0.85 '
0.10
U
0.1
U
0.11
U
0.15
U
0.14
u
0.13
U
0.12
U
0.13
U
Dibenzo(a,h)anthracene
pg/L
0.033
0.11
0.1
(J
0.11
U
0.34
U
0.33
u
0.31
U
0.28
U
0.31
U
Fluoranthene
pg/L
...
0.19 ,
U
0.1
U
0.11
U
0.15
U
0.14
u
0.13
U
0.12
u
0.13
U
Fluorene
pg/L
490
0.19
U
0.1
U
0.11
U .
0.29
U
0.28
u
0.26
U
0.23
u
0.26
u
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.10
U
0.1
U
0.11
U
0.15
U
0.14
u
0.13
U
0.12
u
0.13
u
Naphthalene
pg/L
1.1
0.10
U
0.51
U
0.55
U
1.5
U
1.4
u
1.3
U
1.2
u
1.3
u
Phenanthrene
pg/L
294
0.10
U
0.10
U
0.11
U
0.11
U
0.11
u
0.10
U
0.093
Ua
" 0.10
u
Pyrene
pg/L
...
0.19
U
0.1
U
0.11
U
0.29
U
0.28
u
0.26
U
0.23
u
0.26
u
1-Methylnaphthalene
pg/L
...
0.19
U
na
na
na
na
na
na
na
2-Methylnaphthalene
pg/L
61.2
0.19
u
na
na
na
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
0.013
0.005
U
0.00983
0.018
0.0060
B
0.013
0.010
u
0.020
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
3.4
2.4
2.65
2.4
3.6
1.7
. 3.2
1-5
Natural Attenuation Parameters
Nitrate
mg/L
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
2.9
2.44
2.18
2.0
3.1
1.6
2.9
1.5
Iron, Dissolved
mg/L
...
1.3
2.89
2.53
3.1
4.1
5.4
6.0
3.1
Sulfate
mg/L
na
na
na
na
na
na
na
na
Sulfide
mg/L
— .
na
na
na
na
na
na.
na
na
Methane
pg/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na .
na
na
na
na
na
Chloride
mg/L
...
na
na.
na
¦na
na
na
na
na
icgp_gw_2013-10.xlsx
2A"^~\14 WaJ-^^f.ble Wells 0 of 53
: } { ) ' 1
-------
H
\ /
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW18-GW-0406 MW18-GW-1006 MW18-GW-0407 MW18-GW-1007 MW18-GW-0408 MW18-GW-0410 MW18-GW-1010 MW18-GW-0411
Standard 12-Apr-2006 10-0ct-2006 17-Apr-2007 10-0ct-2007 15-Apr-2008 08-Apr-2010 06-0ct-2010 12-Apr-2011
VOCs
Units
Benzene
M9/L
5
1
U
1.00
U
1
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Toluene
mq/l
1000
1
U
1.00
U
1
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethylbenzene
jjg/L
700
1
u
1.00
U
1
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Xylenes, Total
10000
3
u
3.00
U
3
U
3.00
U
3.00
U
6.00
U
3.00
U
3.00
U
PAHs
Acenaphthene
Mg/i-
914
0.13
u
0.0490
U
0.049
U
0.0544
U
0.049
U
0.100
U
0.124
0.100
U
Acenaphthylene
ng/L
362
0.17
u
0.0850
U
0.085
U
0.0944
U
0.085
U
0.100
U
0.139
0.100
U
Anthracene
Mg/L
...
0.0093
u
0.0100
U
0.01
U
0.0111
U
0.01
U
0.100
U
0.100
U
0.100
U
Benzo(a)anthracene
^g/L
0.13
0.019
u
0.0030
U
0.003
U
0.00333
U
0.003
U
0.100.
U
0.100
U
0.100
U
Benzo(a)pyrene
mq/l
0.2
0.019
u
0.0320
U
0.032
U
0.0356
U
0.032
U
0.100
U
0.100
U
0.100
U
Benzo(b)fluoranthene
Mg/L
0.1
0.037
u
0.0130
U
0.013
U
0.0144
U
0.013
U
0.100
U
0.100
U
0.100
U
Benzo(ghi)perylene
Mg/L
...
0.032
u
0.0090
U
0.009
U
0.01
U
0.009
U
0.100
U
0.100
U
0.100
U
Benzo(k)fluoranthene
ng/L
0.14
0.023
u
0.0150
U
0.015
U
0.0167
U
0.015
U
0.100
U
0.100
U
0.100
U
Chrysene
¦ Mg/L
0.85
0.02
u
0.0050
U
0.005
U
0.00556
U
0.005
U
0.100.
U
0.100
U
0.100
U
Dibenzo(a,h)anthracene
pg/L
0.033
0.033
u
0.0.100
U
0.01
U
0.0111
U
0.01
U
0.00810
U,MDL
0.00973
J.MDL
0.0170
U.MDL
Fluoranthene
M9/L
—
0.032
u
0.0100
U
0.01
U
0.0111
U
0.01
U
0.100
U
0.100
U
0.100
U
Fluorene
Mg/i-
490
0.029
u
0.0100
U
0.01
U
0.0111
U
0.01
U
0.100
U
0.100
U
0.100
U
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.038
u
0.0070
U
0.007
U
0.00778
U
0.007
U
0.100
U
0.100
U
0.100
U
Naphthalene
pg/L
1.1
0.23
0.0540
U
0.054
U '
0.06
U
0.054
U
0.100
U
1.99
0.132
Phenanthrene
ug/L
294
0.015
u
0.0202'
J
0.007
U
0.00778
U
0.007
U
0.100
U
0.100
U
0.100
U
Pyrene
ug/L
...
0.036
u
0.0190
U
0.019
U
0.0211
U
0.019
U
0.100
U
0.100
U
0.100
U
1-Methylnaphthalene
ug/L
...
na
na
na
na
na
0.100
U
0.919
0.101
2-Methylnaphthalene
ng/L
61.2
na
0.0520
U
0.052
U
0.0578
U
0.052
U
0.100
U
0.123
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
0.021
0.0255
0.0208
0.0213
0.0133
na
na
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
0.0100
U
0.0100
U
0.0113
Manganese, Total
mg/L
0.775
1.87
na
na
na
na
3.44
1.35
1.70
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
—
1.86
na
na
na
na
na
na
na
Iron, Dissolved
mg/L
...
3
na
na
na
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
...
• na
na
na
na
na
na
na
na
Methane
Mg/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na ¦
na
na
na
na
Chloride
mg/L
...
na
na
na
na .
¦ na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Water Table Wells Page11of53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW18-GW-1011 MW18-GW-0412 MW18-GW-1012 MW18-GW-0413 MW18-GW-1013
Standard 25-Oct-2011 11-Apr-2012 10-0ct-2012 10-Apr-2013 23-Oct-2013
DV DV DV
VOCs
Units
Benzene
pg/L
5
1.00
U
1.00
U
1.00
U
0.500
U
0.500
u
Toluene
pg/L
1000
1.00
u
1.00
U
1.00
U
1.00
U
1.00
U
Ethyl benzene
pg/L
700
1.00
u
1.00
u
1.00
U
1.00
U
1.00
U
Xylenes, Total
pg/L
10000
3.00
u
3.00
u
3.00
U
3.00
U
3.00
U
PAHs
Acenaphthene
pg/L
914
0.100
u
UJ
0.225
0.100
U
UJ
0.455
1.09
U
Acenaphthylene
pg/L
362
0.100
u
UJ
0.100
u
0.100
U
UJ
0.450
1.09
U
Anthracene
mq/l
...
0.100
u
UJ
1.250
0.100
U
UJ
0.100
U
1.09
U
Benzo(a)anthracene
ug/L
0.13
0.100
u
UJ
0.100
u
0.100
U
UJ
0.100
U
1.09
U
Benzo(a)pyrene
pg/L
0.2
0.100
u
UJ
0.100
u
0.100
U
UJ
0.100
U
1.09
U
Benzo(b)fluoranthene
pg/L
0.1
0.100
u
UJ
0.100
u
0.100
U
UJ
0.100
U
1.09
U
Benzo(ghi)perylene
pg/L
...
0.100
u
UJ
0.100
u
0.100
U
UJ
0.100
u
1.09
U
Benzo(k)fluoranthene
pg/L
0.14
0.100
u
UJ
0.100
u
0.100
U
UJ
0.100
u '
1.09
u
Chrysene
pg/L
0.85
0.100
u
UJ
0.100
u
0.100
U
UJ
0.100
u
1.09
u
Dibenzo(a,h)anthracene
pg/L
0.033
0.0170
U.MDL
UJ
0.0170
U,MDL
0.0130
U.MDL
UJ
0.0172
u
0.185
u
Fluoranthene
pg/L
—
0.100
U
UJ
0.100
U
0.100
U
UJ
0.100
u
1.09
u
Fluorene
pg/L
490
0.100
U
UJ
0.990
0.100
U
UJ
0.106
1.09
u
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.100
U
UJ
0.100
U
0.100
U
UJ
0.100
u
1.09
u
Naphthalene
jjg/L
1.1
0.157
J-
1.71
0.339
J-
1.42
3.27
B' J+,B
Phenanthrene
pg/L
294
0.100
U
UJ
0.416
0.100
U
UJ
0.172
1.09
U
Pyrene
. fjg/L
...
0.100
U
UJ
0.105
0.100
U
UJ
0.100
u
1.09
U
1-Methylnaphthalene
pg/L
...
0.142
J-
0.71
0.114
J-
2.52
1.09
U
2-Methylnaphthalene
MQ/L
. 61.2
0.100
U
UJ
0.162
0.100
U
UJ
0.100
u
1.09
U
Inoroanics
Cyanide, Total
mg/L
...
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
0.0100
U
0.0100
u
0.0100
U
Manganese, Total
mg/L
0.775
1.22
1.64
1.22
1.410
1.34
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
Iron, Dissolved
mg/L
...
na
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
¦Methane- ^
pg/L
...
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
Chloride
mg/L
...
na-
na
na
na
na
icgp_gw_2013-10.xlsx
2/'*
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW07-GW-001 MW07-GW-002 MW07-GW-003 MW07-GW-004 MW07-GW-005 MW07-GW-1002 MW07-GW-0103 MW07-GW-0404
Standard 26-Oct-1999 21-Jun-2000 10-Jul-2001 11-Dec-2001 16-Apr-2002 28-Oct-2002 07-Jan-2003 08-Apr-2004
VOCs
Units
Benzene
ng'L
5
0.5
U
0.5
U
0.5
U
1.0
U
1.0
U
2.0
U
1.0
U
1.0
U
Toluene
ug'L
1000
. 1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
2.0
U
¦1.0
U
1.0
U
Ethylbenzene
Mg/L
700
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
2.0
U
1.0
U
1.0
U
Xylenes, Total
fjg/L
10000
3.0
U
3.0
U
3.0
u
3.0
U
3.0
U
7.0
U
3.0
U
1.0
U
PAHs
Acenaphthene
M9/L
914
0.19
U
0.19
U
0.19
u
0.19
U
0.19
U
0.53
U
0.51
U
2.7
U
Acenaphthylene
Mg/L
362
0.19
U
0.19
U
0.19
u
0.19
U
0.19
U
1.1
U
1.0
U
1.4
U
Anthracene
Mg/L
...
0.10
U
0.10
U
.0.10
u
0.10
U
0.19
U
0.053
U
0.051
U
0.054
U
Benzo(a)anthracene
fjg/L
0.13
0.10
U
0.10
U
0.10
u
0.10
U
0.19
U
0.11
U
0.10
U
0.14
U
Benzo(a)pyrene
ijg/L
0.2
0.10
U
0.10
U
0.10
u
0.10
U
0.19
U
0.11
U
0.10
U
0.14
U
Benzo(b)fluoranthene
Mg/L
0.1
0.10
U
0.10
U
0.10
u
0.10
U
0.10
U
0.11
U
0.10
U
0.054
U
Benzo(ghi)perylene
M9/L
...
0.10
U
0.10
U
0.10
u
0.10
U
0.10
U
0.11
U
0.10
U
0.22
U
Benzo(k)fluoranthene
MQ/L
0.14
0.10
U
0.10
U
0.10
u
0.10
U
0.10
U
0.11
U
0.10
U
0.054
U
Chrysene
Mg/L
0.85
0.10
U
0.10
U
0.10
u
0.10
U
0.10
U
0.11
U
0.10
U
0.14
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.10
U
0.10
U
0.10
u
0.10
U
0.10
U
0.11
U
0.10
U
0.33
U*
Fluoranthene
Mg/L
...
0.10
U
0.10
U
0.10
u
0.10
U
0.19
U
0.11
U
0.10
U
0.14
U
Fluorene
ng/L
490
0.19
U
0.19
U
0.19
u
0.19
U
0.19
U
0.11
U
0.10
U
0.27
U
lndeno(1,2,3-cd)pyrene
^g/L
0.1
0.10
U
0.10
U
0.10
u
0.10
U
0.10
U
0.11
U
0.10
U
0.14
U
Naphthalene
Mg/L
1.1
0.10
UJ
0.10
U
0.10
u
0.17
0.10
U
0.53
U
0.51
U
1.4
u-
Phenanthrene
Mg/L
294
0.10
U
0.10
U
0.10
u
0.10
U
0.10
U
0.11
U
0.10
U
0.11
U
Pyrene
mq/l
...
0.19
U
0.19
U
0.19
u
0.19
U
0.19
U
0.11
U
0.10
U
0.27
U
1-Methylnaphthalene
pg/L
...
na
na
na
0.19
U
0.19
U
na
na
na
2-Methylnaphthalene
pg/L
61.2
0.25
U
0.19
U
0.19
u
0.19
U
0.19
U
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
0.0085
0.0050
UJ
0.010
u
0.010
U
0.010
U
0.005
U
0.00500
U
0.010
U
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
13
10
4.37
3.96
3.6
na
9.28
9.6
Natural Attenuation Parameters
Nitrate
mg/L
...
1.0
U
2.4
2.4
na
na
na
na
na
Nitrite
mg/L
...
0.10
U
na
na
na
na
na
ria
na
Ammonia
mg/L
...
0.20
U
0.20
U
0.20
u
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
2.80
3.37
0.838
2.65
1.88
1.2
Iron, Dissolved
mg/L
...
na
na
0.10
u
0.10
U
0.10
U
0.05
U
"0.05
U
0.10
U
Sulfate
mg/L
—
330
200
180
na
na
na
na
na
Sulfide
mg/L .
...
1.00
U
0.05
U
0.41
na
na
na
na •
na
Methane
ug/L
—
26
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
370
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
1.0
u
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
0.10
u
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
26.48
na
•na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Bedrock Surface Wells Page 13 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance
Standard
MW7-GW-0405
13-Apr-2005
MW7-GW-0406
12-Apr-2006
MW7-GW-0407
17-Apr-2007
MW7-GW-0408
15-Apr-2008
MW7-GW-0410
08-Apr-2010
MW7-GW-0411
12-Apr-2011
MW7-GW-0412
11-Apr-2012
DV
MW07-GW-0413
09-Apr-2013
VOCs
Units
Benzene
ng/L
5
1.0
U
1
U
1
U
1
U
1.00
U
1.00
U
1.00
U
0.500
U
Toluene
M9'L
1000
1.0
U
1
U
1
U
1
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethyl benzene
pg/L
700
1.0
U
1
U
1
u
1
U
1.00
U
1.00
U
1.00
U
1.00
U
Xylenes, Total
- ng/L
10000
2.0
U
3
U
3
u
3
U
6.00
U
3.00
U
3.00
U
3.00
U
PAHS'
Acenaphthene
mq/l
914
2.3
U
0.13
U
0.049
u
0.049
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
Acenaphthylene
pg/L
362
1.2
U
0.17
U
0.085
u
0.085
U
0.100
u
0.100
U
0.100
U
UJ
0.10
U
Anthracene
pg/L
...
0.047
U
0.0093
U
0.01
u
0.01
U
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Benzo(a)anthraoene
pg/L
0.13
0.12
U
0.019
U
0.003
u
0.003
U
0.100
u
0.100
U
0.100
u
UJ
0.100
U
Benzo(a)pyrene
pg/L
0.2
0.12
U
0.019
U
0.032
u
0.032
U
0.100
u
0.100
u
0.100
u
UJ
0.100
U
Benzo(b)fluoranthene
pg/L
0.1
0.047
U
0.037
U
0.013
u
0.013
U
0.100
u
0.100
u
0.100
u
UJ
0.100
U
Benzo(ghi)perylene
pg/L
...
0.19
U
0.032
U
0.009
u
0.009
U
0.100
u
0.100
u
0.100
u
UJ
0.100
u
Benzo(k)fluoranthene
pg/L
0.14
0.047
U
0.023
U
0.015
u
0.015
U
0.100
u
0.100
u
0.100
u
UJ
0.100
u
Chrysene
pg/L
0.85
0.12
U
0.02
U
0.005
u
0.005
U
0.100
u
0.100
u
0.100
u
UJ
0.100
u
Dibe'nzo(a,h)anthracene
pg/L
0.033
0.28
" U
0.033
U
0.01
u
0.01
U
0.0081
U.MDL
0.017
U.MDL
0.017
U.MDL
UJ
0.0175
u
Fluoranthene
pg/L
...
0.12
U
0.032
U
0.01
u
0.01
U
0.100
U
0.100
U
0.100
U
UJ
0.100
u
Fl uorene
pg/L
490
0.23
U
0.029
U
0.01
u
0.01
U
0.100
U
0.100
U
0.100
U
UJ
0.100
u
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.12
¦ U
0.038
U
0.007
u
0.007
U
0.100
U
0.100
U
0.100
U
UJ
0.100
u
Naphthalene
pg/L
1.1
1.2
U
0.1
U
0.054
u
0.054
U
0.100
U
0.100
U
0.100
U
UJ
0.100
u
Phenanthrene
pg/L
294
0.093
U
0.015
U
0.007
u
0.007
U
0.100
U
0.100
U
0.100
U
UJ
0.100
u
Pyrene ¦
pg/L
...
0.23
u
0.036
U
0.019
u
0.019
U
0.100
U
0.100
U
0.100
U
UJ
0.100
u
1-Methylnaphthalene
Mg/L
...
na
na
na
na
0.100
U
0.100
U
0.100
U
UJ
0.100
u
2-Methylnaphthalene
pg/L
61.2
na
na
0.052
u
0.052
U
0.100
U
0.100
U
0.100
U
UJ
0.100
u
Inoraanics
Cyanide, Total
mg/L
...
0.010
u
0.01
U
0.01
u
0.01
U
na
na
na
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
0.01
u
0.01
U
0.01
u
0.0100
u
Manganese, Total
mg/L
0.775
2.3
16
na
na
2.42
6.15
1.67
1.350
Natural Attenuation Parameters
Nitrate
mg/L
1.8
3.69
na
na
0.95
P2
0.93
P2
1.37
P2
3.28
Nitrite
mg/L
0.020
U
0.1
U
na
na
0.100
U
0.100
-u
0.100
U
0.100
U
Ammonia
mg/L
0.20
U
0.2
U
na
na
0.200
U
0.200
U
0.200
U
0.200
U
Manganese, Dissolved
mg/L
2.0
1.19
na
na
2.11
1.77
1.45
1.18
Iron, Dissolved
mg/L
0.10
U
0.1
U
na
na
0.100
U
0.100
U
0.100
U
0.100
U
Sulfate
mg/L
180
139
na
na
156
146
139
118
Sulfide
mg/L
1.0
U
1
U
na
na
5.00
U
19.00
10
U
12.8
Methane
pg/L
na
26
-U
na
na
26.0
U
0.58
U
0.58
U
0.580
u
Alkalinity, Total
mg/L
370
399
na
na
400
372
375
432
Total Kjeldahl Nitrogen
mg/L
0.34
B
1
U
na
na
1.00
U
0.10
U
1.00
U
1.39
Orthophosphate
mg/L
0.099
0.1
U
na
na
0.100
u
0.100
U
0.100
U
0.100
u
Total Organic Carbon
mg/L
2.0
2.19
na
¦ na
1.13
na
na
na
Chloride
mg/L
na
138
na
na .
227
na
na
na
icgp_gw_2013-10.xlsx
2//^-S!n.14 Bedro^'-^'.irface Wells Pr'--J4 of 53
-------
,o
\ /
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW13-GW-001 MW13-GW-002 MW13-GW-003 MW13-GW-004 MW13-GW-0410 MW13-GW-1010 MW13-GW-0411
Standard 25-Oct-1999 ,21-Jun-2000 11 -Jul-2001 12-Dec-2001 09-Apr-2010 05-0ct-2010 13-Apr-2011
¦ DV
VOCs
Units
Benzene
mq/l
5
62.8
18.5
97.2
68.9
5.65
5.85
4.07
Toluene
Mg/L
1000
122
1.5
3.0
5.0
U
1.00
U
1.00
U
1.00
U
Ethyl benzene
Mg/L
700
261
16.4
68.9
41.6
2.55
2.58
1.57
Xylenes, Total
fjg/L
10000
374
19.1
60.3
25
6.00
U
3.90
3.29
PAHs
Acenaphthene
pg/L
914
43.6
54.9
63.0
35.8
17.0
J+
19.1
14.3
Acenaphthylene
ng/L
362
246
177
223
12.6
70.1
J+
67.0
56.3
Anthracene
Mg/L
...
13.5
18.9
19.7
13.7
5.01
J+
8.72
1.66
Benzo(a)anthracene
Mg/L
0.13
5.1
5.0
U
8.5
6.78
1.27
J+
3.85
0.544
Benzo(a)pyrene
Mg/L
0.2
2.27
2.36
3.9
3.77
1.00
U
2.61
0.199
Benzo(b)fluoranthene
ijg/L
0.1
0.58
0.86
1.0
U
1.0
U
1.00
U
1.96
0.173
Benzo(ghi)perylene
Mg/L
—
1.08
0.10
U
1.0
U
1.88
1.00
U
0.895
0.100
U
Benzo(k)fluoranthene
Mg/L
0.14
0.43
0.16
1.0
U
1.0
U
1.00
U
0.922
0.100
"U
Chrysene
fjg/L
0.85
2.04
5.0
U
2.8
2.95
1.16
J+
3.64
0.475
Dibenzo(a,h)anthracene
ug/L
0.033
0.2
0.20
1.0
U
1.0
u-
0.0810
U.MDL
0.280
MDL
0.100
U
Fluoranthene
Mg/L
...
0.10
U
11.8
12.6
10.7
4.97
J+
8.25
2.21
Fluorene
ng/L
490
77.2
121
129
47.2
26.7
J+
25.0
21.8
lndeno(1,2,3-cd)pyrene
fjg/L
0.1
0.9
0.79
1.9
1.0
U
1.00
U
0.814
0.100
U
Naphthalene
Mg/L
1.1
943
8.19
J
175
13.9
1.44
J+
1.49
0.474
Phenanthrene
Mg/L
294
46.9
70.4
87.3
39.1
36.8
J+
34.7
31.8
Pyrene
Mg/L
—
0.19
U
0.19
U
1.9
U
1.9
U
4.23
J+
11.0
2.87
1 -Methylnaphthalene
(jg/L
...
na
na
na
81.5
12.1
J+
12.4
5.31
2-Methylnaphthalene
ug/L
61.2
346
70.9
53.9
7.66
1.00
U
0.431
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
0.0143
0.0099
0.010
UJ
0.010
U
na
na
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
15
6.3
5.35
2.99
2.26
2.21
2.33
Natural Attenuation Parameters
Nitrate
mg/L
...
1.0
U
1
UJ
1.0
U
na
na
na
na
Nitrite
' mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
0.91
1.49
1.14
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
2.87
3.03
na
na
na
Iron, Dissolved
mg/L
...
na
na
9.60
10.2
na
na
na
Sulfate
mg/L
...
190
170
140
na
na
na
na
Sulfide
mg/L
...
1.00
U
1
U
1.0
U
na
na
na
na
Methane
Mg/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Bedrock Surface Wells Page 15 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW13-GW-1011 MW13-GW-0412 MW13-GW-1012 MW13-GW-0413 MW13-GW-1013 MW19-GW-001 MW19-GW-002
Standard 26-Oct-2011 12-Apr-2012 10-0ct-2012 11 -Apr-2013 23-Oct-2013 04-Apr-2000 21-Jun-2000
DV DV DV DV DV
VOCs
Units
Benzene
pg/L
5
3.84
3.17
3.68
3.29
4.59
915
1070
Toluene
Mg/L
1000
1.00
U 1.00
U
1.00
U
1.00
U
1.00
U
91.5
110
Ethylbenzene
Hg/L
700
1.28
1.08
1.00
U
1.00
U
1.00
U
225
241
Xylenes, Total
ug/L
10000
3.00
U 3.00
U
3.00
U
3.00
u
3.00
u
457
511
PAHs
Acenaphthene
pg/L
914
7.08
7.37
J-
10.6
J-
11.3
J-
13.8
71.7
29.0
Acenaphthylene
Mg/L
362
48.7
29.9
J-
44.9
J-
41.4
J-
47.8
272
52.3
Anthracene
pg/i-
...
1.92
1.04
J-
0.900
J-
1.08
J-
1.29
8.2
3.54
Benzo(a)anthracene
M9/I-
0.13
0.908
0.294
J-
0.363
J-
0.347
J-
0.709
5.0
u
0.69
J
Benzo(a)pyrene
Mg/L
0.2
0.526
0.100
U
UJ
0.100
U
UJ
0.141
U
UJ
0.314
5.0
u
0.39
Benzo(b)fluoranthene
ng/i
0.1
0.489
0.100
U
UJ
0.100
U
UJ
0.273
U
UJ
0.288
5.0
U
0.14
Benzo(ghi)perylene
Mg/L
...
0.194
0.100
U
UJ
0.100
U
UJ
0.172
U
UJ
0.123
5.0
u
0.15
Benzo(k)fluoranthene
Mg/i-
0.14
0.112
0.100
U
UJ
0.100
U
UJ
0.182
u
UJ
0.112
5.0
U
0.10
U
Chrysene
Mg/L
0.85
0.743
0.250
J-
0.265
J-
0.245
J-
0.715
5.0
U
0.10
U
Dibenzo(a,h)anthracene
(jg/L
0.033
0.0695
J,MDL UB 0.0170
U.MDL
UJ
0.0130
U,MDL
UJ
0.172
u
UJ
0.0425
5.0
U
0.10
U
Fluoranthene
Mg'L
...
2.59
2.52
J-
2.55
J-
2.91
J-
4.47
5.0
U
3.84
Fluorene
Mg/L
490
15.4
12
J-
16.8
J-
16.5
J-
20.1
77.0
20.3
lndeno( 1,2,3-cd)pyrene
Mg/L
0.1
0.150
0.100
U
UJ
0.100
U
UJ
0.172
u
UJ
0.1
u
5.0
U
0.10
Naphthalene
Mg/L
1.1
0.579
0.362
B
UB,J-
0.572
UB,J-
1.43
B
UB,J-
0.724
B' J+,B
1680
924
Phenanthrene
pg/L
294
16.1
17.8
J-
19.0
J-
14.8
J-
22.9
38.4
14.9
Pyrene
mq/l
...
3.83
2.73
J-
3.66
J-
3.74
J-
2.14
9.5
U
0.19
U
1-Methylnaphthalene
pg/L
...
4.59
2.47
J-
3.55
J-
3.17
J-
3.13
na
na
2-Methylnaphthalene
pg/L
61.2
0:100
U 0.100
U
UJ
0.122
J-
0.237
J-
0.106
39.6
21.6
Inoraanics¦
Cyanide? Total
mg/L
...
na
na
na
na
na
0.0100
0.0113
J
Cyanide, WAD
mg/L
0.2
0.0100
U 0.0100
U
0.0100
U
0.0100
U
0.0100
u
na
na
Manganese, Total
mg/L
0.775
2.13
2.16
2.28
2.260
2.34
10
9.4
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
1.0
U
1.0
U
Nitrite
mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
2.03
2.34
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
na
Iron, Dissolved
mg/L
...
na
. na
na
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
53
48
Sulfide
mg/L
...
na
na
na
na
na
5.0
UJ
0.05
U
Methane
Mg/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/^^^qj4 Bedro^^^^irface Wells Pf ^^^6 of 53
/
^ ^ 'r™ V \'
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW19-GW-003 MW19-GW-004 MW19-GW-005 MW19-GW-1002 MW19-GW-0103 MW19-GW-1003 MW19-GW-0404 MW19-GW-1004
Standard 10-Jul-2001 12-Dec-2001 17-Apr-2002 30-0ct-2002 08-Jan-2003 22-Oct-2003 07-Apr-2004 19-0ct-2004
VOCs
Units
Benzene
ng/L
5
867
868
829
760
J
34
J
960
1100
1400
Toluene
ng/L
1000
108
122
94
89
J
4.4
J
110
150
110
Ethyl benzene
ng/L
700
258
250
196
190
J
12
J
270
270
270
Xylenes, Total
kig/L
10000
528
450
419
410
J
25
J
540
500
490
PAHs
Acenaphthene
ng/L
914
3.8
U
58.1
79.4
140
J
280
J
120
120
140
Acenaphthylene
ijg/L
362
9.3
206
122
10
U
10
U
1900
1600
2200
Anthracene
iig/L
...
2.0
U
3.68
9.5
U
7
6.6
J
7.3
7.1
7.8
Benzo(a)anthracene
ijg/L
0.13
0.10
0.11
0.19
U
1
U
1.0
U
1.3
U
0.12
Ja
1.4
U
Benzo(a)pyrene
ng/L
0.2
0.10
u
0.10
U
0.19
U
1
U
1.0
U
1.3
U
0.052
Ja
1.4
U
Benzo(b)fluoranthene
mq/l
0.1
0.10
u
0.10
U
0.10
U
1
U
1.0
U
0.51
U
0.052
Ua
0.54
U
Benzo(ghi)perylene
|jg/L
...
0.10
u
0.10
U
0.10
U
1
U
1.0
U
2.0
U
0.21
U
2.2
U
Benzo(k)tluoranthene
MQ/L
0.14
0.10
u
0.10
U
0.10
U
1
U
1.0
U
0.51
U
0.052
U
0.54
U
Chrysene
ijg/L
0.85
0.10
u
0.10
U
0.10
U
0.16
1.0
U
1.3
U
0.10
Ja
1.4
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.10
u
0.10
U
0.11
1
U
1.0
U
3.0
U
0.31
U
3.2
U
Fluoranthene
ijg/L
...
0.10
u
0.81
1.78
4.9
4.6
J
5.6
5.1
5.4
Fluorene
M9/L
490
3.8
u
28.5
50.8
27
30
J
28
25
25
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.10
u
0.10
U
0.10
U
1.00
U
1.0
U
1.3
U
0.14
U
1.4
U
Naphthalene
Mg/L
1.1
998
1,160
1,530
1,900
1,600
J
2200
1800
2100
Phenanthrene
ijg/L
294
2.0
u
22.3
29.6
39
43
J
45
45
46
Pyrene
Mg/L
...
0.19
u
0.19
U
1.61
2.6
2.3
J
2.5
Ua
0.84
2.7
Ua
1-Methylnaphthalene
Mg/L
...
na
388
510
na
na
na
na
na
2-Methyl naphthalene
Mg/L
61.2
3.8
u
31
35.6
na
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
0.011
0.010
U
0.010
U
0.005
U
0.006
0.012
0.010
U
0.010
U
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
6.63
5.52
5.3
5.09
5.08
5.7
5.3
5.1
Natural Attenuation Parameters
Nitrate
mg/L
...
1.0
u
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
—
2.07
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
5.45
5.52
4.9
5.06
5.21
5.0
5.1
4.8
Iron, Dissolved
mg/L
...
5.14
5.59
5.0
6.87
7.42
5.6
5.4
5.6
Sulfate
mg/L
...
80
na
na
na
na
na
na
na
Sulfide
mg/L
...
1.0
u
na
na ¦
na
na
na
na
na
Methane
ijg/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
—
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp gw 2013-10.xlsx
2/11/2014
Bedrock Surface Wells
Page 17 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW19-GW-0405 MW19-GW-1005 MW19-GW-0406 MW19-GW-1006 MW19-GW-0407 MW19-GW-1007 MW19-GW-0408 MW19-GW-0410
Standard 14-Apr-2005 12-0ct-2005 12-Apr.-2006 10-0ct-2006 17-Apr-2007 10-0ct-2007 15-Apr-2008 08-Apr-2010
VOCs
Units
Benzene
^g/L
5
2000
-
1000
1130
1290
1180
538
870
1100
Toluene
^g/L
1000
150
•
120
48.4
82.2
112
179
87.3
158
Ethylbenzene
ng/L
700
300
*
220
173
211
184
112
151
187
Xylenes, Total
Mg/L
10000
550
*
380
312
368
331
293
261
440
PAHs
Acenaphthene.'
pg/L
914
160
170
135
147
155
158
146
152
RL1
Acenaphthylene
ng/L
362
2200
2200
125
148
120
201
156
152
RL1
Anthracene
ug/L
...
7.7
9.1
7.32
7.88
7.19
7.88
6.86
13.8
RL1
Benzo(a)anthracene
ng/L
0.13
0.12
0.36
Ja
0.704
0.167
0.0784
J
0.148
0.214
1.00
U,RL1
Benzo(a)pyrene
ijg/L
0.2
0.12
U
0.16
Ja
0.019
U
0.0909
J
0.0356
U
0.032
U
0.186
J
1.00
U.RL1
Benzo(b)fluoranthene
Mg/L
0.1
0.047
U
0.23
U
0.037
U
0.0702
J
0.0144
U
0.013
U
0.117
1.00
U.RL1
Benzo(ghi)perylene
pg/L
0.19
u
0.93
U
0.032
u
0.009
(J
0.01
U
0.009
U
0.113
1.00
U,RL1
Benzo(k)fluoranthene
Mg'L
0.14
0.047
u
0.23
U
0.023
u
0.0381
J
0.0167
U
0.015
U
0.015
U
1.00
U.RL1
Chrysene
Mg/L
0.85
0.067
Ja
0.24
Ja
0.02
u
0.0972
J
0.0409
J
0.0839
J
0.005
U
1.00
U.RL1
Dibenzo(a,h)anfhracene
pg/L
0.033
0.28
U
1.4
U
0.033
u
0.01
U
0.0111
U
0.01
U
0.0287
J
0.0810
U.RL1.MDL
Fluoranthene
ng/i-
...
5.9
6.1
0.032
u
3.95
3.11
2.89
4.79
2.65
RL1
Fluorene
pg/L
490
27
25
69.2
86.5
81.6
162
106
34.8
RL1
lndeno(1,2,3-cd)pyrene'
pg/L
0.1
0.12
U
0.60
U
0.038
u
0.007
U
0.00778
U
0:007
u
0.0833
J
1.00
U,RL1
Naphthalene
ng/L
1.1
1700
1300
1030
1060
967
871
737
620
RL1
Phenanthrene
pg/L
294
48
49
45.8
48.6
47.1
60.3
62.1
45.4
RL1
Pyrene
pg/L
...
0.57
1.4
M
23.8
16.8
16
14.3
0.019
U
1.92
RL1
1-Methylnaphthalene
MQ/L
...
na
na
na
na
na
na
na
900
RL1
2-Methylnaphthalene
pg/i-
61.2
na
na
na
46.5
43.1
29.9
40
13.6
RL1
Inoraanics
Cyanide, Total
mg/L
...
0.010
U
0.0058
B
0.01
u
0.01
U
0.01
U
0.01
u
0.01
U
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
0.0100
U
Manganese, Total
mg/L
0.775
4.9
4.8
7.63
na
na
na
na
3.84
Natural Attenuation Parameters
Nitrate
mg/L
— .
na
na
na
na
na
na
na
0.10
U
Nitrite
mg/L
...
na
na
na
na
na
na
na
0.100
Ammonia
mg/L
...
na
na
na
na
na
na
na
2.31
Manganese, Dissolved
mg/L
...
4.9
4.3
4.3
na
na
na
na
3.70
Iron, Dissolved
mg/L
¦
6.3
6.0
4.77 ¦
na
na
na
na
"5.31
Sulfate
mg/L
...
na
na
na
na
na
na
na
34.4
Sulfide
mg/L
...
na
na
na
na
na
na
na
5.00
U
Methane
pg/L
...
na.
na
na
na
na
na
na
• 68.0
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
389
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
2.61
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
0.100
U
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
3.01
Chloride
mg/L
na
na
na
na
na
na
na
182
icgp_gw_2013-10.xlsx
Bedro^'^Mrface Wells Pp-~tJ8 of 53
i ) : ) ¦ ^
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW19-GW-1010 MW19-GW-0411 MW19-GW-1011 MW19-GW-0412 DP02-GW-0412 MW19-GW-1012
Standard 06-0ct-2010 12-Apr-2011 25-Oct-2011 11-Apr-2012 11-Apr-2012 10-0ct-2012
DV DV DV
VOCs
Units
Benzene
M9/L
5
1060
864
964
968
984
870
Toluene
M9/L
1000
161
170
152
173
176
139
Ethylbenzene
Mg/L
700
256
217
208
212
212
229
Xylenes, Total
pg/L
10000
406
347
328
319
315
355
PAHs
Acenaphthene
pg/L
914
126
99.5
56.5
J-
89.2
97.6
RL1
J-
91.0
J-
Acenaphthylene
pg/L
' 362
127
99.9
129
J-
98.3
103
RL1
J-
73.8
J-
Anthracene
pg/L
...
13.3
10.3
6.50
J-.J-
8.05
8.21
RL1
J-
8.30
J-
Benz'o(a)anthracene
pg/L
0.13
0.144
0.120
0.147
J-,J-
0.145
1.00
U.RL1
UJ
0.161
J-
Benzo(a)pyrene
pg/L
0.2
0.100
U
0.100
U
0.100
U
UJ
0.100
U
1.00
U.RL1
UJ
0.100
U
UJ
Benzo(b)fluoranthene
ug/L
0.1
0.100
U
0.100
U
0.100
U
UJ
0.100
U
1.00
U.RL1
UJ
0.100
U
UJ
Benzo(ghi)perylene
|jg/i-
...
0.100
U
0.100
U
0.100
U
uj-
0.100
U
1.00
U.RL1
UJ
0.100
u
UJ
Benzo(k)fluoranthene
mq/l
0.14
0.100
U
0.100
U
0.100
U
UJ
0.100
U
1.00
U.RL1
UJ
0.100
u
UJ
Chrysene
pg/i-
0.85
0.122
0.106
0.127
J-.J-
0.125
1.00
U.RL1
UJ
0.101
J-
Dibenzo(a,h)anthracene
pg/L
0.033
0.00810
U,MDL
0.017
U.MDL
0.0170
U,MDL
UJ
0.0170
U.MDL
0.170
U.RL1.MDL
UJ
0.0130
U.MDL
UJ
Fluoranthene
pg/L
...
1.66
1.46
2.62
J-.J-
1.93
2.11
RL1
J-
2.13
J-
Fluorene
pg/L
490
28.8
24.8
8.07
J-
20.5
23.6
RL1
J-
27.7
J-
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.100
U
0.100
U
0.100
U
UJ
0.100
U
1.00
U.RL1
UJ
0.100
U
UJ
Naphthalene
pg/L
1.1
488
384
416
J-
292
372
RL1
J-
292
J-
Phenanthrene
pg/L
294
53.5
37.7
29.8
J-
37.1
44.8
RL1
J-
31.1
J-
Pyrene
Mg/L
...
1.03
1.47
5.55
J-,J-
1.85
2.21
RL1
J-
2.12
J-
1 -Methylnaphthalene
pg/L
733
619
652
J-
483
595
RL1
J-
504
J-
2-Methylnaphthalene
pg/L
61.2
10.8
5.84
9.71
J-,J-
8.85
11.3
RL1
J-
11.8
J-
tnoraanics
Cyanide, Total
mg/L
—
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
3.63
4.11
3.59
3.89
3.67
3.92
Natural Attenuation Parameters
Nitrate
mg/L
...
0.10
U,M1
0.10
U
0.10
U
0.100
U
na
0.100
u
Nitrite
mg/L
...
0.100
U
0.100
U
0.100
(J
0.100
U
na
0.100
u
Ammonia
mg/L
...
2.23
2.26
2.14
2.22
na
2.14
Manganese, Dissolved
mg/L
...
3.64
3.51
3.76
3.99
na
4.10
Iron, Dissolved
mg/L
...
5.46
4.37
5.21
5.56
na
5.76
Sulfate
mg/L
...
31.4
34.4
36.5
36.8
na
38.0
Sulfide
mg/L
...
5.00
U
10.00
U
10
U
10
U
na
10
u
Methane
Mg/L
...
74.6
-
21
28
31
na
43
Alkalinity, Total
mg/L
...
376
351
345
311
na
345
Total Kjeldahl Nitrogen
mg/L
...
2.90
2.85
2.85
2.4
na
2.57
Orthophosphate
mg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
na
0.100
u
Total Organic Carbon
mg/L
...
2.65
na
2.32
ET
na
na
na
Chloride
mg/L
—
193
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11 /2014 Bedrock Surface Wells Page 19 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW19-GW-0413 MW19-GW-1013 MW20-GW-0D1 MW20-GW-003 MW20-GW-004 MW20-GW-005 MW20-GW-1002 MW20-GW-0103
Standard 10-Apr-2013 23-Oct-2013 02-Apr-2001 10-Jul-2001 12-Dec-2001 18-Apr-2002 30-0ct-2002 09-Jan-2003
DV DV
VOCs
Units
Benzene
^g/L
5
977
J-
840
2300
2800
3000
3140
1.7
2000
J
Toluene
t-ig/L
1000
134
99.9
906
1130
1430
1270
0.79
1300
J
Ethyl benzene
pg/L
700
186
179
969
987
1220
1050
0.67
1300
Xylenes, Total
|jg/L
10000
316
296
997
1010
1220
1170
0.78
450
PAHs
Acenaphthene
ng/L
914
134
112
71.9
65.5
95.7
54.6
0.041
420
J
Acenaphthylene
Ug/L
362
134
111
198
250
- 443
240
11
U
10
U
Anthracene
—
9.27
5.31
10
U
5.91
10
U
5.0
U
7.8
6.4
J
Benzo(a)anthracene
Mg/L
0.13
0.147
1.02
U
0.39
0.13
0.4
0.56
0.71
0.45
J
Benzo(a)pyrene
pg/L
0.2
0.100
U
1.02
U
0.22
0.10
U
0.17
0.22
0.34
0.18
J
Benzo(b)fluoranthene
ug/L
0.1
0.100
U
1.02
U
0.10
U
0.10
U
0.10
U
0.10
U
0.45
0.24
J
Benzo(ghi)perylene
tjg/L
—
0.100
U
1.02
U
0.10
U
0.10
U
0.10
U
0.10
u
1.1
U
1.0
u
Benzo(k)fluoranthene
Mg/L
0.14
0.100
U
1.02
U
0.10
U
0.10
U
0.10
U
0.10
u
1.1
U
1.0
u
Chrysene
|jg/L
0.85
0.137
1.02
U
0.26
0.10
U
0.10
U
0.21
0.34
0.24
J
Dibenzo(a,h)anthracene
ug'L
0.033
0.0173
U
0.173
U
0.10
U
0.10
U
0.10
U
0.10
u
1.1
U
1.0
u
Fluoranthene
ng/L
...
1.55
1.29
1.5
2.07
0.10
U
0.10
u
6.4
3.8
J
Fl uorene
M9/L
490
31.7
25.8
56.9
58.3
74.3
64.7
29
41
J
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.100
U
1.02
U
0.10
U
0.1
U
0.10
U
0.10
u
1.1
U
1.0
u
Naphthalene
ng/L
1.1
400
352
B* J+,B
1880
1940
3220
1830
2700
2700
J
Phenanthrene
kig/L
294
38.2
60.1
29.4
26.3
40.1
27.8
43
43
J
Pyrene
ug/L
...
1.59
1.83
0.19
U
0.19
U
0.19
U
1.52
3.8
2.1
J
1-Methylnaphthalene
pg'L
...
770
665
na
na
662
na
na
na
2-Methylnaphthalene
Mg/L
61.2
13.4
11.1
353
303
485
277
na
na
Inoraanics
Cyanide, Total
mg/L
...
na
na
0.021
0.17
0.02
0.015
0.005
U
0.00574
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
4.05
3.61
1.07
0.918
0.94
0.986
0.897
0.953
Natural Attenuation Parameters
Nitrate
mg/L
... .
0.100
U
na
1.0
U
1.0
U
na
na
na
na
Nitrite
mg/L
...
0.100
U
na
*
na
na
na
na
na
na
Ammonia
mg/L
...
2.25
na
0.20
UJ
0.20
U
na
na
na
na
Manganese, Dissolved
mg/L
...
4.11
na
na
0.884
0.94
0.926
0.824
0.906
Iron, Dissolved
mg/L
...
5.56
na
na
14.9
15.5
16
14.6
15.8
Sulfate
mg/L
...
34.9
na
120
130
na
na
na
na
Sulfide
mg/L
...
10.0
U
na
2.0
U
0.10
U
na
na
na
na
Methane
ug'L
...
28.8
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
365
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
2.83
na
¦ na
na
na
na
na
na
Orthophosphate
mg/L
...
0.100
U
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-1O.xlsx
2//^'^14 Bedro^^'.irface Wells of 53
¦' \ /' \
-------
>/
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW20-GW-1003 MW20-GW-0404 MW20-GW-1004 MW20-GW-0405 MW20-GW-1005 MW20-GW-0406 MW20-GW-1006 MW20-GW-0407
Standard 22-Oct-2003 08-Apr-2004 20-0ct-2004 14-Apr-2005 11-0ct-2005 12-Apr-2006 10-0ct-2006 17-Apr-2007
VOCs
Units
Benzene
ng/L
5
2800
2800
1700
4700
2700
2830
2140
2360
Toluene
ug/L
¦ 1000
1500
1400
920
3500
1500
1860
1180
1510
Ethylbenzene
UQ/L
700
1300
1300
830
1900
1200
1540
1170
1290
Xylenes, Total
pg/L
10000
1400
1400
900
2500
1800
1730
1260
1380
PAHs
Acenaphthene
Mg/L
914
96
140
100
120
160
205
141
121
Acenaphthylene
ug/L
362
2000
1900
1400
1900
1900
168
119
85.6
Anthracene
ng/L
...
7.0
5.6
5.4
6.7
17
38
7.16
5.75
Benzo(a)anthracene
Hg/L
0.13
0.62
Ja
0.54
Ja
0.50
Ja
0.16
6.6
17
0.609
0.131
J
Benzo(a)pyrene
ng/L
¦ 0.2
1.4
Ua
0.37
Ja
1.3
U
0.018
Ja
3.9
16.5
0.542
0.0759
J
Benzo(b)fluoranthene
Mg/L
0.1
0.53
U
0.53
U
0.50
U
0.047
U
1.6
10.9
0.37
0.0144
U
Benzo(ghi)perylene
pg/i-
...
2.1
U
2.1
U
2.0
U
0.19
U
1.0
Ja
5.74
0.168
0.01
U
Benzo(k)fluoranthene
ijg/L
0.14
0.53
U
0.53
U
0.50
U
0.047
U
0.90
7.01
0.21
0.0167
U
Chrysene
Mg/L
0.85
0.33
Ja
0.43
Ja
0.32
Ja
0.090
Ja
4.6
11.5
0.44
0.0589
J
Dibenzo(a,h)anthracene
ng/t-
0.033
3.2
U
3.2
U
3.0
U
0.28
u ¦
3.0
U
1.81
0.0322 J
0.0111
U
Fluoranthene
pg/L
...
7.2
7.0
5.5
6.3
23
42.6
4.42
5.32
Fluorene
Mg/L
490
34
40
29
37
44
140
88.6
79.1
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
1.4
U
1.4
U
1.3
U
0.12
U
1.2
Ja
6.19
0.129
0.00778
u
Naphthalene
Mg/L
1.1
3800
3700
2400
3400
3400
3340
2640
2470
Phenanthrene
ng'L
294
41
48
33
43
64
120
40.8
32
Pyrene
ug/L
...
2.6
Ua
2.3
Ja
2.5
Ua
0.72
13
234
22.4
13.7
1 -Methylnaphthalene
Mg/L
...
na
na
na
na
na
na
na
na
2-Methylnaphthalene
ng/L
61.2
na
na
na
na
na
na
428
388
Inoroanics
Cyanide, Total
mg/L
...
0.011
0.0079
B
0.010
0.0099
B
0.0085
B
0.1
U
0.01 U
0.0108
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
1.2
0.88
0.79
0.78
0.89
1.18
na
na
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
0.10
U
0.020
U
0.1
U
na
na
Nitrite
mg/L
...
na
na
na
0.020
U
0.020
U
0.1
u ¦
na
na
Ammonia
mg/L
...
na
na
na
0.20
u
0.22
0.2
u
na
na
Manganese, Dissolved
mg/L
...
0.85
0.81
0.79
0.80
0.74
0.698
na
na
Iron, Dissolved
mg/L
...
15
15
14
15
14
13.4
na
na
Sulfate
mg/L
...
na
na
na
88
130
112
na
na
Sulfide
mg/L
...
na
na
na
1.0
u
0.90
B
1
u
na
na
Methane
fjg/L
...
na
na
na
26
63
151
na '
na
Alkalinity, Total
mg/L
...
na
na
na
430
380
456
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
0.26
B
0.50
1
u
na
na
Orthophosphate
mg/L
...
na
na
na
0.019
B
0.050
U
0.1
u
na
na
Total Organic Carbon
mg/L
...
na
na
na
6.7
9.5
6.66
na
na
Chloride
mg/L
...
na
na
na
na
na
134
na
na
icgp_gw_2013-1O.xlsx
2/11/2014
Bedrock Surface Wells
Page 21 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW20-GW-1007 MW20-GW-0408 MW20-GW-0410 MW20-GW-1010 MW20-GW-0411 MW20-GW-1011 MW20-GW-0412
Standard 09-0ct-2007 15-Apr-2008 08-Apr-2010 06-0ct-2010 12-Apr-2011 25-Oct-2011 11-Apr-2012
DV DV DV
VOCs
Units
Benzene
pg/L
5
1800
1920
549
637
919
1250
2490
Toluene
pg/L
1000
1120
1070
272
247
353
361
846
Ethylbenzene
ng/L
700
1100
1100
978
C9 J+
947
865
974
1180
Xylenes, Total
pg/L
10000
1170
1240
929
1010
1160
1090
1190
PAHs
Acenaphthene
pg'L
914
149
123
79.5
RL1
92.9
94.0
39.3
J-
78.6
RL1
J-
Acenaphthylene
pg/L
362
301
77.1
82.5
RL1
133
96.9
91.9
J-
48.3
RL1
J-
Anthracene
pg/L
5.67
6.07
10.0
U,RL1
8.98
7.13
6.51
J-
2.37
RL1
J-
Benzo(a)anthracene
pg/L
0.13
0.22
.0.348
10.0
U.RL1
0.161
0.100
U
1.00
U
UJ
1.00
U.RL1
UJ
Benzo(a)pyrene
pg/L
0.2
0.156
J
0.304
10.0
U,RL1
0.100
U
0.100
U
1.00.
U
UJ
1.00
U.RL1
UJ
Benzo(b)fluoranthene
pg/L
0.1
0.013'
U
0.203
10.0
U.RL1
0.100
U
0.100
U
1.00
U
UJ
1.00
U.RL1
UJ
Benzo(ghi)perylene
pg/L
...
1.18
0.137
10.0
U.RL1
0.100
u
0.100
U
1.00
U
UJ
1.00
U,RL1
UJ
Benzo(k)fluoranthene
pg/L
0.14
0.015
u
0.015
U
.10.0
U,RL1
0.100
u
0.100
U
1.00
U
UJ
1.00
U,RL1
UJ
Chrysene
pg/L
0.85
0.18
0.0649
J
10.0
U.RL1
0.140
0.100
U
1.00
U
UJ
1.00
U.RL1
UJ
Dibenzo(a,h)anthracene
pg/L
0.033
0.01
u
0.01
U
0.81
U,RL1,MDL
0.00810
U.MDL
0.0170
U,MDL
0.276
J.MDL
J-
0.170
U,MDL
UJ
Fluoranthene
pg/L
...
2.14
3.87
10
U,RL1
3.25
1.37
2.23
J-
1.14
RL1
J-
Fluorene
pg/L
490
152
88.2
41.1
RL1
49.8
48.5
19.6
J-
30.6
RL1
J-
lndeno( 1,2,3-cd)pyrene
pg/L
0.1
0.007
u.
0.14
10.0
U,RL1
0.100
U
0.100
U
1.00
U
UJ
1.00
U.RL1
UJ
Naphthalene
pg/L
1.1
3210
2180
1940
RL1
2100
1890
1690
J-
1510
B1 B
J-
Phenanthrene
pg/L
294
42.7
44.4
42.4
RL1
42.2
37.4
22.9
J-
28.4
RL1
J-
Pyrene
pg/L
...
13
0.019
U
10.0
U,RL1
2.52
1.48
3.77
J-
1.23
RL1
J-
1-Methylnaphthalene
pg/L
...
na
na
457
RL1
637
497
430
J-
328
RL1
J-
2-Methyinaphthalene
pg/L
61.2
482
362
154
RL1
164
146
158
J-
176
RL1
J-
Inoraanics
Cyanide, Total
mg/L
...
0.0109
0.01
U
na
na
na
na
na
Cyanide, WAD 1
mg/L
0.2
na
na
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
na
na
0.592
0.557
0.616
0.581
0.584
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
na
Iron, Dissolved-
mg/L
...
na
na
'na
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
Methane
pg/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon .
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/^^014 Bedrcr-'-S'.jrface Wells of 53
/ \ \
-------
I
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW20-GW-1012 MW20-GW-0413 MW20-GW-1013 MW23-GW-005 MW23-GW-1002 MW23-GW-0103 MW23-GW-1003 MW23-GW-0404
Standard 10-0ct-2012 10-Apr-2013 23-Oct-2013 17-Apr-2002 31-0ct-2002 08-Jan-2003 21-0ct-2003 Q6-Apr-2004
DV DV DV .
VOCs
Units
Benzene
MQ/L
5
3640
3310
2770
14.1
10
16
22
13
Toluene
MQ/L
1000
1360
1440
1320
1.0
U
2.0
U
1.0
U
1
U
1
U
Ethylbenzene
Mg/L
700
1600
1510
1460
1.0
U
2.0
U
4.1
0.79
J
0.73
Ja
Xylenes, Total ¦
ng/L
10000
1620
1610
1530
6.9
7.9
11
8.8
7.6
PAHs
Acenaphthene
ng/L
914
75.0
J-
143
J+
88.3
J-
0.19
U
110
45
J
24
28
Acenaphthylene
pg/L
362
40.2
J-
50.5
J+
40.4
J-
52.6
1.0
U
1.0
U
240
200
Anthracene
MQ/L
1.77
J-
29.6
U
2.38
J-
0.26
0.22
0.42
J
0.34
0.47
Benzo(a)anthracene
ijg/L
0.13
0.111
J-
12.2
U
1.02
U
UJ
0.19
U
0.1
U
0.10
U
0.14
U
0.12
U
Benzo(a)pyrene
ng/L
0.2
0.100
U
UJ
14.3
U
1.02
U
UJ
0.19
U
0.1
U
0.10
U
0.14
U
0.12
U
Benzo(b)fluoranthene
Mg/L
0.1
0.100
U
UJ
27.6
U
1.02
u
UJ
0.10
U
0.10
U
0.10
U
0.054
U
0.048
U
Benzo(ghi)perylene
Mg/L
...
0.100
U
UJ
17.3
U
1.02
u
UJ
0.10
U
0.10
U
0.10
U
0.22
U
0.19
U
Benzo(k)fluoranthene
Mg/L
0.14
0.100
U
UJ
18.4
U
1.02
u
UJ
0.10
U
0.10
U
0.10
U
0.054
U
0.048
U
Chrysene
^g/L
0.85
0.100
U
UJ
11.2
U
1.02
u
UJ
0.10
U
0.10
U
0.10
U
0.14
U
0.12
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.0130
U.MDL
UJ
17.3
U
0.173
U
UJ
0.10
U
0.10
U
0.10
U
0.33
U
0.29
U
Fluoranthene
ng/L
...
1.14
J-
50
U
1.02
u
UJ
0.19
U
0.1
0.22
J
0.37
0.82
Fluorene
Mg/L
490
26.1
J-
47.7
J+
29.3
J-
7.38
J
15
9.6
J
9.0
9.4
lndeno(1,2,3-cd)pyrene
ijg/L
0.1
0.100
U
UJ
17.3
U
1.02
u
UJ
0.10
U
0.10
U
0.10
U
0.14
U
0.12
U
Naphthalene
pg/L
1.1
2380
J-
3870
B
B,J+
2290
B"
J-,J+,B
1.32
0.9
3.7
J
10.
Ja
1.3
Phenanthrene
Mg/L
294
19.3
J-
43.5
J+
32.1
J-
2.88
4
J
5.9
J
5.0
6.8
Pyrene
pg/L
...
1.23 '
J-
56.1
U
1.09
J-
0.19
U
0.1
U
0.10
U
0.27
U
0.24
U
1 -Methylnaphthalene
pg/L
...
371
J-
604
J+
412
J-
14.4
14.4
na
na
na
2-Methylnaphthalene
^g/L
61.2
262
J-
505
J+
307
J-
0.19
u
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
0.010
u
0.005
U
0.005
U
0.01
U
0.01
U
Cyanide, WAD
mg/L
0.2
0.0100
U
0.189
0.0100
u
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.607
0.587
0.603
0.302
0.299
0.309
3.9
0.63
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg'/L
...
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
0.295
0.272
0.296
0.28
0.28
Iron, Dissolved
mg/L
... ¦
na
na
na
4
3.63
4.61"
' 3.4
3.5
Sulfate
mg/L
...
na.
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
na
Methane
Mg/L
...
na
na
na ¦
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Bedrock Surface Wells Page 23 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW23-GW-1004 MW23-GW-0405 MW23-GW-1005 MW23-GW-0406 MW23-GW-1006 MW23-GW-0407 MW23-GW-1007 MW23-GW-0408
Standard 20-0ct-2004 15-Apr-2005 11-0ct-2005 11-Apr-2006 11-0ct-2006 18-Apr-2007 10-0ct-2007 16-Apr-2008
VOCs
Units
Benzene
ug/L
5
21
22
¦
21
8.7
5.91
9.25
13.3
12.7
Toluene
Mg/L
1000
^ 1
U
1.0
U*
1.0
U
1
U
1
U
1
U
1
U
1
U
Ethyl benzene
|jg/L
700
1
U
1.0
U*
1.0
U
1
U
1
U
1
U
1
U
1
U
Xylenes, Total
i^g/i-
10000
7.4
8.2
*
5.9
7.12
6.08
5.84
6.15
5.56
PAHs
Acenaphthene
pg/i-
914
25
36
32
27.3
24.7
21.3
28.2
20
Acenaphthylene
MQ/L
362
240
340
270
48.1
41.6
38.9
35.8
37.2
Anthracene
fjg/L
...
0.47
0.72
0.40
0.0106
U
0.706
0.592
0.664
0.291
Benzo(a)anthracene
(ig/L
0.13
0.13
u
0.12
u
0.12
U
0.0216
U
0.003
u
0.004
U
0.003
U
0.003
u
Benzo(a)pyrene
|jg/i-
0.2
0.13
u
0.12
u
0.12
U
0.0216
U
0.032
u
0.0427
U
0.032
U
0.032
u
Benzo(b)fluoranthene
Mg/L
0.1
0.050
u
0.047
u
0.046
U
0.0216
U
0.013
u
0.0173
U
0.013
U
0.013
u
Benzo(ghi)perylene
fjg/L
—
0.20
u
0.19
u
0.19
U
0.0364
U
0.009
u
0.012
U
0.009
U
0.009
u
Benzo(k)fluoranthene
ng/L
0.14
0.050
u
0.047
u
0.046
U
0.0261
U
0.015
u
0.02
U
0.015
U
0.015
u
Chrysene
ng/L
0.85
0.13
u
0.12
u
0.12
U
0.0227
U
0.005
u
0.00667
U
0.005
U
0.005
u
Dibenzo(a,h)anthracene
fjg/L
0.033
0.30
u
0.28
u
0.28
U
0.0375
U
0.01
u
0.0133
U
0.01
U
0.01
u
Fluoranthene
Mg/L
0.73
1.1
0.63
0.0364
U
0.603
0.466
0.447
0.272
Fluorene
Mg/L
490
9.6
14
10
24.8
24
19.7
37.3
24.5
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.13
u
0.12
u
0.12
U
0.0432
U
0.007
u
0.00933
U
0.007
U
0.007
u
Naphthalene
ng/L
1.1
1.3
u
1.2
u
1.2
U
1.04
1.34
1.6
1.13
0.663
Phenanthrene
Mg/L
294
6.6
10
' 5.9
8.74
7.94
6.8
8.41
7.16
Pyrene
ng/L
...
0.25
u
0.23
u
0.23
U
3.44
2.62
2.21
2.64
0.019
u
1 -Methylnaphthalene
ug/L
...
na
na
na
na
na
na
na
na
2-Methylnaphthalene
Mg/L
61.2
na
na
na:
na
0.513
0.378
0.052
U
0.052
u
Iroraanics
Cyanide, Total
mg/L
...
0.01
u
0.0027
B
0.0027
B
0.01
U
0.01
u
0.01
U
0.01
U
0.01
u
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.35
0.29
0.54
0.257
na
na
na
na
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
0.29
0.30
0.28
0.294
na
na
na
na
Iron, Dissolved
mg/L
...
3.7
3.8
0.17
4.29
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
. —
na
na
na
na
na
na
na
na
Methane
Mg/L
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
¦ na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
Bedro^-^'-irface Wells Prp~--'>4 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW23-GW-0410 DUP2-GW-0410 MW23-GW-1010 MW23-GW-0411 MW23-GW-1011 MW23-GW-0412 MW23-GW-1012
Standard 08-Apr-2010 08-Apr-2010 05-0ct-2010 12-Apr-2011 24-Oct-2011 11-Apr-2012 09-0ct-2012
DV DV
VOCs
Units
Benzene
M9/L
5
11.4
13.2
13.2
15.3
16.8
10.8
9.99
Toluene
fjg/L
1000
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethylbenzene
ug/L
700
1.00
U,C9
1.00
U,C9
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
•Xylenes, Total
ug/L
10000
6.00
U
6.00
U
4.11
5.22
4.44
4.43
4.57
PAHs
Acenaphthene
Mg/L
914
19.3
21.4
17.7
22.5
9.14
J-
16.5
J-
21.1
Acenaphthylene
Mg/L
362
39.2
45.0
34.1
41.0
31.6
J-
30.5
J-
33.8
Anthracene
Mg/L
...
0.778
0.705
0.479
0.485
0.252
J-
0.225
J-
0.279
Benzo(a)anthracene
Mg/L
0.13
0.100
U
0.100
U
0.100
u
0.100
U
0.100
u
UJ
0.100
U
UJ
0.100
U
Benzo(a)pyrene
Mg/L
0.2
0.100
U
0.100
U
0.100
u
0.100
U
0.100
u
UJ
0.100
U
UJ
0.100
U
Benzo(b)fluoranthene
MQ/L
0.1
0.100
U
0.100
U
0.100
u
0.100
U
0.100
u
UJ
0.100
U
UJ
0.100
u
Benzo(ghi)perylene
ijg/L
...
0.100
U
0.100
U
0.100
u
0.100
U
0.100
u
UJ
0.100
U
UJ
0.100
u
Benzo(k)fluoranthene
Mg/L
0.14
0.100
U
0.100
u
0.100
u
0.100
U
0.100
u
UJ
0.100
U
UJ
0.100
u
Chrysene
Mg/L
"0.85
0.100
U
0.100
u
0.100
u
0.100
U
0.100
u
UJ
0.100
U
UJ
0.100
u
Dibenzo(a,h)anthracene
Mg/L
0.033
0.00810
U.MDL
0.00810
U.MDL
0.00810
U,MDL
0.0170
U.MDL
0.0170
U.MDL
UJ
0.0170
U.MDL
UJ
0.0130
U.MDL
Fluoranthene
pg/L
...
0.425
0.430
0.299
0.400
0.247
J-
0.208
J-
0.245
Fluorene
ng/L
490
13.1
15.4
11.5
14.2
5.43
J-
9.75
J-
13.8
lndeno(1,2,3-cd)pyrene
ug/L
0.1
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
Naphthalene
(jg/L
1.1
0.701
0.614
0.407
0.449
0.514
J-
0.491
B
UB,J-
0.816
Phenanthrene
fjg/L
294
8.66
11.6
8.18
8.68
7.37
J-
5.55
J-
8.00
Pyrene
...
0.311
0.299
0.327
0.428
0.253
J-
0.229
J-
0.235
1-Methylnaphthalene
Ug/L
...
1.86
1.56
1.25
1.34
0.934
J-
0.933
J-
1.22
2-Methylnaphthalene
M9'L
61.2
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
0.126
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.01
U
0.0100
U
0.0100
U
0.0100
U
UJ
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.323
0.325
0.464
0.397
0.316
0.339
0.362
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
na
Iron, Dissolved
mg/L
...
na
na
na
na
na
na
na
Sulfate
mg/L
...
na
na.
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
• na
na
- na
na
Methane
Mg/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na>
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014
Bedrock Surface Wells
Page 25 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW23-GW-0413 MW23-GW-1013 MW25-GW-005 MW25-GW-1002 MW25-GW-0103 MW25-GW-1003 MW25-GW-0404 MW25-GW-1004
Standard 10-Apr-2013 22-Oct-2013 17-Apr-2002 29-Oct-2002 08-Jan-2003 21-0ct-2003 06-Apr-2004 20-0ct-2004
DV DV
VOCs
Units
Benzene
ng/L
5
5.35
8.41
39.9
19
31
5.9
2.2
5.3
Toluene
mq/l
1000
1.00
U
1.00
U
1.0
U
2.0
U
1.0
U
1.0
U
1.0
U
1.0
U
. Elhylbenzene
ug'L
700
1.00
U
1.00
U
1.0
U
2.0
U
1.0
U
1.0
U
1.0
U
1.0
u
Xylenes, Total
pg/L
10000
4.11
3.72
6.4
J
7
U
3.0
U
1.8
1.1
1.6
PAHs
Acenaphthene
ug'L
914
24.1
17
3.81
J
6.4
9.0
4.4
5-°,
4.3
Acenaphthylene
pg/L
362
39.9
24.6
7.4
J
1
U
1.0
U
53
40 '
41
Anthracene
ug/L
...
0.336
0.206
0.19
U
0.051
U
0.051
U
0.049
Ua
0.0073
Ja
0.0073
Ja
Benzo(a)anthracene
pg/L
0.13
0.121
U
0.100
U
0.19
U
0.1
U
0.10
U
0.13
U
0.13
U
0.13
U
Benzo(a)pyrene
ng/L
0.2
0.141
U
0.100
U
0.19
U
0.1
U
0.10
U
0.13
U
0.13
U
0.13
U
Benzo(b)fluoranthene
"¦ ijg/L
0.1
0.273
U
0.100
U
0.10
U
0.1
U
0.10
U
0.049
U
0.049
U
0.050
U
Benzo(ghi)perylene
Mg/i-
...
0.172
U
0.100
U
0.10
U
0.1
U
0.10
U
0.19
U
0.19
u
0.20
U
Benzo(k)fluoranthene
ug/L
0.14
0.182
U
0.100
U
0.10
U
0.1
U
0.10
U
0.049
U
0.049
u
0.050
U
Chrysene
pg/L
0.85
0.111
U
0.100
U
0.10
U
0.1
u
0.10
U
0.13
U
0.13
u
0.13
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.172
U
0.0173
U
0.10
U
0.1
u
0.10
U
0.29
U
0.29
u
0.30
U
Fluoranthene
pg/L
...
0.495
U
0.223
0.19
U
0.1
u
0.10
U
0.13
U
0.13
u
0.13
U
Fluorene
Mg/L
490
15.4
9.47
0.19
U
"0.1
u
0.25
0.28
0.35
0.26
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.172
U
0.100
U
0.10
U
0.1
u
0.10
U
0.13
U
0.13
u
0.13
U
Naphthalene
pg/L
1.1
¦ 0.923
B
UB
0.451
0.10
U
1.5
0.8
1.3
U
1.3
u
1.3
U
Phenanthrene
Mg/L
294
10.2
4.02
0.10
U
0.10
u
0.10
U
0.014
Ja
0.097
u
0.099
U
Pyrene
ng/L
...
0.556
U
0.236
0.19
U
0.1
u
0.10
U
0.24
U
0.24
u
0.25
U
1 -Methylnaphthalene
[jg/L
...
1.33
0.841
0.19
U
na
na
na
na
na
2-Methylnaphthalene
Mg/L
61.2
0.118
0.100
U
0.19
U
na
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
na
na
0.010
U
0.005
u
0.009
0.010
U
0.010
u
0.010
U
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.318
J-
0.303
0.406
0.41
0.42
0.74
0.49
0.46
Natural Attenuation Parameters
Nitrate
mg/L
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
0.382
0.488
0.41
0.38
0.38
0.34
Iron, Dissolved
mg/L
...
na
na
3.7
3.84
3.92"
3.3
3.2
2.8
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na '
na
na
na
na
na
Methane
Mg/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
. mg/L
...
na
na
na
na '
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
Bedro^^^'.irface Wells of 53
N ! \ ' \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW25-GW-0405 MW25-GW-1005 MW25-GW-0406 MW25-GW-1006 MW25-GW-0407 MW25-GW-1007 MW25-GW-0408
Standard 14-Apr-2005 11-0ct-2005 13-Apr-2006 11-0ct-2006 18-Apr-2007 10-0ct-2007 15-Apr-2008
VOCs
Units
Benzene
t-ig/L
5
11
' 1.8
25.8
10.7
27
14.4
27.2
Toluene
[jg/L
1000
1.0
U
1.0
U
1
U
1
U
1
U
1
U
1
U
Ethylbenzene
fjg/L
700
1.0
U
1.0
U
1
U
1
U
1
U
1
U
1
U
Xylenes, Total
ug/L
10000
2.3
1.1
J
7.81
5.15
4.39
3.8
6.14
PAHs
Acenaphthene
ng/L
914
6.2
5.2
7.58
8.71
7.32
12.5
11.2
Acenaphthylene
pg/L
362
57
48
13.5
16.5
12.2
0.085
u
19.4
Anthracene
ug/L
...
0.047
Ua
0.051
U
0.0395
J
0.0472
J
0.0287
J
0.0235
J
0.0299
J
Benzo(a)anthracene
ug/L
0.13
0.12
U
0.13
U
0.019
U
0.003
U
0.003
u
0.00908
J
0.003
U
Benzo(a)pyrene
pg/L
0.2
0.12
U
0.13
U
0.019
U
0.032
U
0.032
u
0.032
u
0.032
U
Benzo(b)fluoranthene
ng/L
0.1
0.047
U
0.051
U
0.037
U
0.013
U
0.013
-u
0.013
u
0.013
U
Benzo(ghi)perylene
ng/L
...
0.19
U
0.20
U
0.032
U
0.009
U
0.009
u
0.009
u
0.009
U
Benzo(k)fluoranthene
pg/L
0.14
0.047
U
0.051
U
0.023
U
0.015
U
0.015
u
0.015
u
0.015
U
Chrysene
|ig/L
0.85
0.12
U
0.13
U
0.02
U
0.094
J
0.005
u
0.0221
J
0.005
U
Dibenzo(a,h)anthracene
ijg/L
0.033
0.28
U
0.30
U
0.033
U
0.01
U
0.01
u
0.01
u
0.01
U
Fluoranthene
ng/L
...
0.12
U
0.13
U
0.032
U
0.0149
J
0.01
u
0.01
u
0.01
U
Fluorene
Mg/L
490
0.37
0.29
2.77
3.31
2.79
10.6
8.81
lndeno(1,2,3-cd)pyrene
i-ig/L
0.1
0.12
U
0.13
U
0.038
U
0.007
U
0.007
u
0.007
u
0.007
U
Naphthalene
Mg/L
1.1
1.2
U
¦ 1-3
U
0.401
0.534
1.16
0.632
0.62
Phenanthrene
Mg/L
294
0.093
U
0.10
U
0.161
0.214
0.164
0.22
0.007
U
Pyrene
ms/l
...
0.23
Ua
0.25
U
0.036
u
0.019
U
0.019
u
0.019
u
0.019
U
1-Methylnaphthalene
ng/L
...
na
na
na
na
na
na
na
2-Methylnaphthalene
ijg/L
61.2
na
na
' na
0.171
J
0.17
J
0.0793
J
0.052
U
Inorganics
Cyanide, Total
mg/L
...
0.010
U
0.010
U
0.01
u
0.01
U
0.01
u
0.01
u
0.01
U
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.42
0.40
0.305
na1
na
na
na
Natural Attenuation Parameters
Nitrate
mg/L
...
0.10
U
0.10
U
0.1
u
na
na
na
na
Nitrite
mg/L
...
0.020
U
0.020
U
0.1
u
na
na
na
na
Ammonia
mg/L
...
0.15
B
0.20
U
0.2
u
na
na
na
na
Manganese, Dissolved
mg/L
...
0.39
0.37
0.336
na
na
na
na
Iron, Dissolved
mg/L
...
2.7
3.0
2.89
na
na
na
na
Sulfate
mg/L
...
120
120
112
M1
na
na
na ¦
na
Sulfide
mg/L
...
1.0
U
1.0
u
1
U
na
na .
na
na
Methane
na/L .
...
4
4.2
26
U
na
na
na
na
Alkalinity, Total
mg/L
...
360
330
385
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
0.18
B
0.17
B
1
u
na
na
na
na
Orthophosphate
mg/L
...
0.008
B
0.050
U
0.1
u
na
na
na
na
Total Organic Carbon
mg/L
...
1.4
.1.5
1:42
na
na
na
na
Chloride
mg/L
...
na
na
99.4
M1
na.
na
na
na
icgp gw 2013-10.xlsx
2/11/2014
Bedrock Surface Wells
Page 27 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance
Standard
MW25-GW-0410
08-Apr-2010
MW25-GW-1010
05-0ct-2010
MW25-GW-0411
12-Apr-2011
MW25-GW-1011
25-Oct-2011
DV
DP02-GW-1011
25-Oct-2011
DV
MW25-GW-0412
10-Apr-2012
DV
DP01-GW-0412
10-Apr-2012
DV
VOCs
Units
Benzene
5
139
131
46.4
88.6
88.4
82.2
76.8
Toluene
M9/1-
1000
1.76
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethylbenzene
700
1.72
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Xylenes, Total
m/l
10000
19.2
13.2
4.32
3.41
3.01
3.00
U
3.00
U
PAHs
Acenaphthene
pg/L
914
18.5
16.6
10.1
8.95
J-
8.94
J-
6.19
J-
7.56
J-
Acenaphthylene
M9/I-
362
. 22.1
18.3
9.94
9.21
J-
9.50
J-
6.56
J-
9.43
J-
Anthracene
w/l
...
0.359
0.322
0.118
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Benzo(a)anthracene
Mg/L
0.13
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Benzo(a)pyrene
Mg/L
0.2
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Benzo(b)fluoranthene
M9'L
0.1
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Benzo(ghi)perylene
Mg/L
...
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Benzo(k)fluoranthene
^g/L
0.14
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Chrysene
ng/L
0.85
0.100
U
0.100
U
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Dibenzo(a,h)anthracene
Mg/L
0.033
0.00810
U,MDL
0.00810
U.MDL
0.0170
U,MI 0.0170
U.MDL
UJ
0.0170
U,MDL
UJ
0.0170
U,MDL
UJ
0.0170
U.MDL
UJ
Fluoranthene
Mg/L
...
0.150
0.163
0.123
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Fluorene
Mg/L
490
4.64
5.09
2.35
1.56
J-
1.60
J-
0.804
J-
1.00
J-
lndeno(1,2,3-cd)pyrene
pg'L
0.1
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
Naphthalene
Mg/L
1.1
1.87
0.738
0.789
0.240
J-
0.162
J-
0.12
J-
0.135
J-
Phenanthrene
Mg/L
294
2.70
2.59
1.74
1.19
J-
1.25
J-
0.381
J-
0.545
J-
Pyrene
fjg/L
...
0.112
0.183
0.145
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
1-Methylnaphthalene
Mg/L
...
26.3
18.0
2.2
0.938
J-
0.863
J-
0.332
J-
0.426
J-
2-Methylnaphthalene
^g/L
61.2
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
u
UJ
0.100
U
UJ
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
u
0.0100
U
0.0100
U
0.0100
U
0.0100
u
0.0100
U
Manganese, Total
mg/L
0.775
0.354
0.336
0.373
0.315
0.312
0.325'
R
0.295
Natural Attenuation Parameters
Nitrate
mg/L
...
0.10
U
0.10
u
0.10
U
0.10
U
0.100
u
0.100
U
0.100
U
Nitrite
mg/L
...
0.100
U
0.100
u
0.100
U
0.100
U
'0.100
u
0.100
U
0.100
U,H
Ammonia
mg/L
...
0.200
U
0.200
u
0.200
U
0.200
U
0.200
u
0.200
U
0.200
U
Manganese, Dissolved
mg/L
...
0.343
0.324
0.317
0.333
0.328
0.311
0.316
Iron, Dissolved
mg/L
...
2.76
2.78
2.54
2.81
"
2.82
2.68
2.81
Sulfate
mg/L
...
81.4
81.4
103
91.6
36.8
86.8
84.8
Sulfide
mg/L
...
5.00
U
5.00
u
10.00
U
10
u
10
u
10
u
10
U
Methane
Mg/L
...
43.0
39.8
10
16
14
31
31
Alkalinity, Total
mg/L
...
394
371
341
340
336
321
321
Total Kjeldahl Nitrogen
mg/L
...
1.00
U
1.00
u
1.00
u
¦ 1.00
u
1.00
u
1.00
u
1.00
U
Orthophosphate
mg/L
...
0.100
U
0.100
u
0.100
u
0.100
u
0.100
u
0.100
u
0.100
U
Total Organic Carbon
mg/L
...
1.00
U
1.00
u
na
1.00
U.ET
1.00
U,ET
na
na
Chloride
mg/L
...
83.5
89.1
na
na
na
na
na
icgp_gw_20l3-10.xlsx
2/;^\14
Bedros-
/
^'jrface Wells
Pp.-_^?8 of 53
/ \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW25-GW-1012 DP02-GW-1012 MW25-GW-0413 DP02-GW-0413 MW25-GW-1013 DP02-GW-1013
Standard 10-0ct-2012 10-0ct-2012 10-Apr-2013 10-Apr-2013 23-Oct-2013 23-Oct-2013
DV . DV
VOCs
Units
Benzene
pg/L
5
120
126
1140
J-
10.3
43.5
44.3
Toluene
pg/L
1000
1.00
U
1.00
U
161
1.00
U
1.00
U
1.00
U
Ethylbenzene
pg/L
700
1.00
U
1.00
U
22.4
1.00
U
1.85
1.69
Xylenes, Total
MQ/L
10000
4.65
4.95
317
3.00
U
5.24
5.21
PAHs
Acenaphthene
pg/L
914
8.33
8.64
10.1
10.8
15.1
14.6
Acenaphthylene
pg/L
362
11.2
11.6
8.56
11
13.9
13.4
Anthracene
pg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)anthracene
pg/L
0.13
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)pyrene
pg/L
0.2
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(b)fluoranthene
pg/L
0.1
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(ghi)perylene
pg/L
...
0.100
U
0.100-
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(k)fluoranthene
pg/L
0.14
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Chrysene
pg/L
0.85
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Dibenzo(a,h)anthracene
pg/L
0.033
0.0130
U.MDL
0.0130
U,MDL
0.0173
U
0.0179
U
0.0183
U
0.0179
U
Fluoranthene
pg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Fluorene
pg/L
490
0.795
0.882
0.807
0.77
.1.5
1.48
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Naphthalene
pg/L
1.1
0.185
0.220
0.989
0.218
1.66
1.57
Phenanthrene
pg/L
294
0.331
0.400
0.158
0.107
0.464
0.433
Pyrene
pg/L
...
0.100
U
0.100
u
0.100
U
0.100
U
0.100
U
0.100
U
1-Methylnaphthalene
pg/L
0.479
0.542
1.60
0.756
2.27
2.19
2-Methylnaphthalene
pg/L
61.2
0.100
U
0.225
0.100
U
0.100
U
0.100
U
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
u
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.343
0.332
0.343
0.342
0.355
0.427
Natural Attenuation Parameters
Nitrate
mg/L
...
0.100
U
0.100
u
0.100
U
0.100
U
na
na
Nitrite
mg/L
...
0.100
U
0.100
u
0.100
U
0.100
U
na
na
Ammonia
mg/L
...
0.200
U
0.200
u
0.200
U
0.200
U
na
na
Manganese, Dissolved
mg/L
...
0.318
0.326
0.353
0.36
na
na
Iron; Dissolved
mg/L
...
2.81
2.85
3.030
2.980
na
na
Sulfate
mg/L
...
80.7
82.6
92.2
92.7
na
na
Sulfide
mg/L
...
10
U
10-
u
16.9
20.9
na
na
Methane
pg/L
...
28..
28
.5.65
8.01
na
na
Alkalinity, Total
mg/L
...
355
350
365
365
na
na
Total Kjeldahl Nitrogen
mg/L
...
1.00
U
1.00
u
1.00
U
1.00
U
na
na
Orthophosphate
mg/L
...
0.100
U
0.100
u
0.100
U
0.100
U
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
icgp gw 2013-10.xls*
2/11/2014
Bedrock Surface Wells
Page 29 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW29-GW-1002 MW29-GW-0103 MW29-GW-1003 MW29-GW-0404 MW29-GW-1004 MW29-GW-0405 MW29-GW-1005 MW29-GW-0406
Standard 28-Oct-2002 07-Jan-2003 20-0ct-2003 07-Apr-2004 18-0ct-2004 14-Apr-2005 11-0ct-2005 12-Apr-2006
l/QCs Unrfs
Benzene pg/L
Toluene pg/L
Ethylbenzene pg/L
Xylenes, Total pg/L
RAHs
Acenaphthene ' pg/L
Acenaphthylene pg/L
Anthracene pg/L
Benzo(a)anthracene pg/L
Benzo(a)pyrene pg/L
Benzo(b)fluoranthene pg/L
Benzo(ghi)perylene pg/L
Benzo(k)fluoranthene pg/L
Chrysene pg/L
Dibenzo(a,h)anthracene pg/L
Fluoranthene pg/L
Fluorene pg/L
lndeno(1,2,3-cd)pyrene pg/L
Naphthalene pg/L
Phenanthrene pg/L
Pyrene pg/L
1-Methylnaphthalene. pg/L
2-Methylnaphthalene pg/L
Inorganics
Cyanide, Total mg/L
Cyanide, WAD mg/L
Manganese, Total mg/L
Natural Attenuation Parameters
Nitrate mg/L
Nitrite mg/L
Ammonia mg/L
Manganese, Dissolved mg/L
Iron, Dissolved mg/L
Sulfate mg/L
Sulfide mg/L
Methane pg/L
Alkalinity, Total - mg/L
Total Kjeldahl Nitrogen mg/L
Orthophosphate mg/L
Total Organic Carbon mg/L
Chloride mg/L
5
2
U
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1
U
1000
2
U
1.0
U
1.0
U
1.0
U
1.0 "
U
1.0
U
1.0
U
1
U
700
2
U
1.0
U
1.0
U
1.0
u
1.0
U
1.0
U
1.0
u
1
U
10000
7
U
3.0
U
1.0
U
1.0
u
1.0
U
2.0
U
2.0
u
3
U
914
0.52
U
0.54
U
2.6
U
. 2.4
u
2.4
U
2.5
U
2.4
u
0.13
u'
362
1
U
1.1
U
1.3
U
1.2
u
1.2
U
1.3
U
1.2
u
0.17
U
...
0.052
U
0.054
U
0.051
U*
0.047
u
0.048
U
0.050
U
0.047
u
0.0093
U
0.13
0.1
U
0.11
U
0.13
U
0.12
u
0.12
U
0.13
U
0.12
u
0.019
U
0.2
0.1
U
0.11
U
0.13
U
0.12
u
0.12
U
0.13
U
0.12
u
0.019
U
0.1
0.1
U
0.11
U
0.051
U
0.047
u
0.048
U
0.050
U
0.047
u
0.037
U
...
0.1
U
0.11
U
0.20
U
0.19
u
0.19
U
0.20
U
0.19
u
0.032
U
0.14
0.1
U
0.11
U
0.051
U
0.047
u
0.048
U
0.050
U
0.047
u
0.023
U
0.85
0.1
U
0.11
U
0.13
U
0.12
u
0.12
U
0.13
U
0.12
u
0.02
U
0.033
0.1
U
0.11
U
0.31
U
0.28
u
0.29
U
0.30
U
0.28
u
0.033
U
...
0.1
U
0.11
U
0.13
U
0.12
u
0.12
U
0.13
U
0.12
u
0.032
U
490
0.1
U
0.11
U
0.26
U
0.24
u
0.24
U
0.25
U
0.24
u
0.029
U
0.1
0.1
U
0.11
U
0.13
U
0.12
u
0.12
U
0.13
U
0.12
u
0:038
u
1.1
0.52
U
0.54
U
1.3
U
1.2
u
1.2
U
1.3
U
1.2
u
0.1
u
294
0.1
U
0.11
U
0.10
U
0.094
u
0.096
U
0.10
U
0.094
u
0.015
u
—
0.1
u ¦
0.11
U
0.26
U
0.24
u
0.24
U
0.25
U
0.24
u
0.036
u
...
na
na
na
na
na
na
na
na
61.2
na
na
na
na
na
na
na
na
...
0.005
U
0.00500
U
0.010
U
0.010
u
0.010
U
0.010
U
0.010
u
0.01
u
0.2
na
na
na
na
na
na
na
na
0.775
0.19
0.0871
0.17
0.065
0.10
0.050
0.053
0.0579
—
na
na
na
na
na
0.10
U
0.027
B
0.1
u
...
na
na
na
na
na
0.020
U
0.020
u
0.1
u
...
na
na
na
na
na
0.45
0.27
0.377
...
0.0541
0.0445
0.043
0.044
0.040
0.041
0.039
0.0432
...
0.807
1.16
1.1
1.2
1.1
1.0
1.4
1.4
...
na
na
na
na
na
110
120
111
...
na
na
na
na
na
1.0
U
1.0
u
1
u
...
na
na
na
na
na
2
U
2
u
26
u
...
na
na
na
na
na
330
320
366
na
na
na
na
na
0.43
0.71
1
u
...
na
na
na
na
na
0.011
B
0.050
u
0.1
u
...
na
na
na
na
na
1.3
1.4
1.77
...
na
na
na
na
na
na
na
24.8
icgp_gw_2013-10.xlsx
2/s-^.14
Wells
/ \
Pp-^-30 of 53
¦ N
-------
/ \
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW29-GW-1006 MW29-GW-0407 MW29-GW-1007 MW29-GW-0408 MW29-GW-0410 MW29-GW-0411 MW29-GW-0412 MW29-GW-0413
Standard 11-0ct-2006 17-Apr-2007 09-0ct-2007 14-Apr-2008 08-Apr-2010 12-Apr-2011 11 -Apr-2012 09-Apr-2013
VOCs Units
Benzene
Mg/L
5
1
U
1
U
1 U
1
U
1.00
U
1.00
U
1.00
U
0.500
U
Toluene
M9/L
1000
1
U
1
U
- 1 U
1
U
1.00
U
1.00
U
1.00
u
1.00
U
Ethyl benzene
Mg/L
700
1
U
1
U
1 U
1
U
1.00
U
1.00
U
1.00
u
1.00
U
Xylenes, Total
ng/L
10000
3
U
3
U
3 U
3
U
6.00
U
3.00
u
3.00
u
3.00
u
PAHs
Acenaphthene
pg/L
914
0.049
U
0.049
U
0.049
U
0.049
U
0.100
U
0.100
U
0.100
U
0.100
U
Acenaphthylene
Mg/i-
362
0.085
U
0.085
U
0.085
U
0.085
U
0.100
.U
0.100
U
0.100
U
0.100
U
Anthracene
ng/L
...
0.01
U
0.01
U
0.01
U
0.01
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)anthracene
pg/L
0.13
0.003
U
0.003
U
0.003
U
0.003
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)pyrene
0.2
0.032
U
0.032
U
0.032
U
0.032
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(b)fluoranthene
ijg/L
0.1
0.013
U
0.013
U
0.013
U
0.013
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(ghi)perylene
ng/L
...
0.009
U
0.009
U
0.009
U
0.009
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(k)fluoranthene
ng/L
0.14
0.015
U
0.015
U
0.015
U
0.015
U
0.100
U
0.100
U
0.100
U
0.100
U
Chrysene
fjg/L
0.85
0.005
U
0.005
U
0.005
U
0.005
U
0.100
U
0.100
U
0.100
U
0.100
U
Dibenzo(a,h)anthracene
|jg/L
0.033
0.01
U
0.01
u
0.01
U
0.01
U
0.0081
U.MDL
0.0170
U,MDL
0.0170
U.MDL
0.0183
U
Fluoranthene
Mg/L
...
0.01
U
0.01
u
0.01
U
0.01
U
0.100
U
0.100
U
0.100
U
0.100
U
Fluorene
ng/L
490
0.01
U
0.01
u
0.01
U
0.01
U
0.100
U
0.100
U
0.100
U
0.100
U
lndeno(1,2,3-cd)pyrene
fjg/L
0.1
0.007
U
0.007
u
0.007
U
0.007
U
0.100.
U
0.100
U
0.100
U
0.100
U
Naphthalene
pg/L
1.1
1.37
0.054
u
0.054
U
0.054
U
0.100
U
0.100
U
0.100
U
0.100
U
Phenanthrene
Mg/L
294
0.007
U
0.007
u
0.007
U
0.007
U
0.100
U
0.100
U
0.100
U
0.100
U
Pyrene
ng/L
...
0.019
U
0.019
u
0.11
J
0.019
U
0.100
U
0.100
U
0.100
U
0.100
U
1-Methylnaphthalene
Mg/i-
...
na
na
na
na
0.100
U
0.100
U
0.100
U
0.100
U
2-Methylnaphthalene
pg/L
61.2
0.129
J
0.052
u
0.052
U
0.052
U
0.100
U
0.100
U
0.100
U
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
0.01
U
0.01
u
0.01
U
0.01
U.
na
na
na
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
na
na
na
na
0.0444
0.0427
0.0942
0.241
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
0.10
U,R
0.100
U
0.100
U
0.100
U
Nitrite
mg/L
...
na
na
na
na
0.100
U
0.100
U
0.100
U
0.100
U
Ammonia
mg/L
...
na
na
na
na
0.322
0.35
0.338
0.371
Manganese, Dissolved
mg/L
...
na
na
na
na
0.0381
0.0392
0.0397
0.0403
Iron, Dissolved
mg/L
...
na
na
na
na
1.43
1.35
1.57
1.690
Sulfate
mg/L
na
na
na
na
94.5
94.1
96:5
94.2
Sulfide
mg/L
...
na
na
na
na
5.00
U
10.0
U
10.0
U
26.6
Methane
pg/L
...
na
na
na
na
26.0
U
0.61
0.76
1.45
Alkalinity, Total
mg/L
...
na
na
na
na
389
351
316
365
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
1.00
U
1.00
U
1.00
U
1.00
U
Orthophosphate
mg/L
...
na
na
na
na
0.100
U
0.100
U
0.100
U
0.100
U
Total Organic Carbon
mg/L
...
na
na
na
na
1.00
U
na
na
na
Chloride
mg/L
—
na
na
na
na
28.3
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 BedrockWells Page31of53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW31-GW-1002 MW31-GW-0103 MW31-GW-1003 MW31-GW-0404 MW31-GW-1004 MW31-GW-0405 MW31-GW-1005 MW31-GW-0406
Standard 01-Nov-2002 07-Jan-2003 21-0ct-2003 06-Apr-2004 18-0ct-2004 13-Apr-2005 11-0ct-2005 11-Apr-2006
VOCs
Units
Benzene
Mg/L
5
370
190
380
300
180
350
360
370
Toluene
yg/L
1000
7.5
8.7
9.0
7.1
Ja
4.7
Ja
8.6
8.1
8.27
Ethyl benzene
ra'L
700
420
180
370
320
200
380
350
385
Xylenes, Total
Mg/L
10000
220
250
250
210
130
250
240
243
PAHs
Acenaphthene
Mg/L
914
140
180 J
79
71
73
83
78
64.1
Acenaphthylene
|jg/L
362
1
U
1.1 U
730
560
670
790
750
0.17
U
Anthracene
pg/L
...
1.4
J
1.6 J
1.8
•
1.7
1.9
2.1
2.4
1.88
Benzo(a)anthracene
pg/L
0.13
0.1
U
3 J
0.027
Ja
0.020
Ja
0.023
Ja
0.025
Ja
0.038
Ja
0.0608
Benzo(a)pyrene
pg/L
0.2
0.1
U
0.11 U
0.13
U
0.13
U
0.13
U
0.13
U
0.12
U
0.0261
Benzo(b)fluoranthene
ug/L
0.1
0.1
U
0.11 U
0.051
U
0.051
U
0.049
U
0.049
U
0.047
U
0.124
Benzo(ghi)perylene
ug/L
...
0.1
U
0.11 U
0.20
U
0.20
U
0.19
U
0.19
U
0.19
U
0.0861
Benzo(k)fluoranthene
ug/L
0.14
0.1
U
0.11 U
0.051
U
0.051
U
0.049
U
0.049
U
0.047
U
0.0515
Chrysene
pg/L
0.85
0.1
u
0.11 U
0.13
U
0.13
U
0.13
U
0.13
U
0.12
U
0.0808
Dibenzo(a,h)anthracene
Mg/L
0.033
0.1
u
0.11 U
0.31
U
0.31
U
0.29
U
0.29
U
0.28
U
0.033
U
Fluoranthene
pg/L
—
0.88
0.82 J
1.5
1.7
1.4
1.6
1.7
0.032
U
Fluorene
pg/L
490
16
20 J
16
15
15
17
16
30.8
lndeno( 1,2,3-cd)pyrene
pg/L
0.1
0.1
u
0.11 U
0.13
U
0.13
U
0.13
U
0.13
U
0.12
U
0.111
Naphthalene
pg/L
1.1
280
260 J
360
230
280
300
310
209
Phenanthrene
ug/t-
294 ¦
11
11 J
14
14
12
14
14
12.3
Pyrene
Hg/L
...
0.38
0.34 J
0.26
U
0.62
0.28
0.30
M
0.30
M
6.04
1 -Methylnaphthalene
tig/L
...
na
na
na
na
na
na
na
na
2-Methylnaphthalene
pg/i-
61.2
na
na
na
na
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
0.005
u
0.00500 U
0.010
U
0.010
U
0.010
U
0.010
U
0.010
U
0.01
U
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.146
0.158
0.16
0.15
0.15
0.16
0.16
0.157
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
0.10
U
0.043
B
0.1
U
Nitrite
mg/L
...
na
na
na
na
na
0.020
U
0.020
U
0.1
U
Ammonia
mg/L
...
na
na
na
na
na
0.17
B
0.20
U
0.2
U
Manganese, Dissolved
mg/L
...
0.144
u
0.165
0.15
0.15
0.15
0.15
0.17
0.151
Iron, Dissolved
mg/L
...
0.552
u
0.625
0.57
0.45
0.52
0.47
0.76
0.516
Sulfate
mg/L
...
na
na
na
na
na
24
31
26.3
Sulfide
mg/L
...
na
na
na
na
na
1.5
1.2
1
U
Methane
pg/i-
...
na
na
na
na
na
16
27
54
Alkalinity, Total
mg/L
...
na
na
na
na
na
460
430
499
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
0.22
B
0.26
B
1
U
Orthophosphate
mg/L
...
na
na
na
na
na
0.13
0.016
B
0.1
U
Total Organic Carbon
mg/L
...
na
na
na
na
na
2.5
2.6
2.9
Chloride
mg/L
...
na
na
na
na
na
na
na
69.9
icgp_gw_2013-10.xlsx
2/.'^=-°-ai4 Wells Pjs2»32 of 53
N / \ \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW31-GW-1006 MW31-GW-0407 MW31-GW-1007 MW31-GW-0408 MW31-GW-0409 MW31-GW-1009 MW31-GW-0110
Standard 10-0ct-2006 18-Apr-2007 09-0ct-2007 15-Apr-2008 22-Apr-2009 14-0ct-2009 14-Jan-2010
VOCs
Units
Benzene
|jg/L
5
360
326
304
334
157
150
251
Toluene
|jg/L
1000
9.46
8.37
7.47
8.82
4.27
3.96
5.82
Ethyl benzene
fig/L
700
376
369
321
319
17.9
164
248
Xylenes, Total
MQ/L
10000
237
241
201
219
117
105
167
PAHs
Acenaphthene
mq/l
914
81.2
71.9
63.6
78.5
27.2
29.6
M1
37.7
Acenaphthylene
|ig/L
362
0.085
U
53.4
0.085
U
0.085
U
8.73
12.5
16.6
Anthracene
Mg/L
...
2.25
2.01
1.24
2.21
0.903
2.32
1.95
Benzo(a)anthracene
Mg/L
0.13
0.0336
J
.0.0198
J
0.0167
0.0303
J
0.0907
J
0.0682
J
0.101
Benzo(a)pyrene
ng/L
0.2
0.032
U
0.032
U
0.032
U
0.032
U
0.123
0.0616
J
0.133
Benzo(b)fluoranthene
ng/L
0.1
0.0542
J
0.0538
J
0.013
u
0.013
u
0.261
0.131
0.229
Benzo(ghi)perylene
Mg/L
...
0.009
U
0.0203
J
0.009
u
0.009
u
0.148
0.0652
J
0.158
Benzo(k)fluoranthene
w/L
0.14
0.015
U
0.0366
J
0.015
u
0.015
u
0.0732
J
0.0372
J
0.105
Chrysene
ng/L
0.85
0.0407
J
0.0376
J
0.0265
0.0418
J
0.149
0.0855
J
0.161
Dibenzo(a,h)anthracene
MQ/L
0.033
0.01
U
0.01
U
0.01
u
0.01
u
0.0214
J
0.0122
J
0.0286
Fluoranthene
fig/L
...
1.34
1.13
0.549
1.72
0.407
0.618.
0.633
Fluorene
Mg/L
490
36.2
35.4
61.2
49.2
6.40
9.87
M1
11.0
lndeno(1,2,3-cd)pyrene
ng/L
0.1
0.007
U
0.0448
J
0.007
u
0.007
u
0.129
0.0518
J
0.135
Naphthalene
Mg/i-
1.1
270
202
238
274
93.0
121
M1
161
Phenanthrene
pg/L
294
13.5
13.1
13.7
17.8
5.41
6.98
M1
9.80
Pyrene
ug/L
...
5.35
5.05
2.97
0.019
u
0.434
0.618
0.989
1-Methyl naphthalene
Mg/L
...
na
na
na
na
na
na
2-Methylnaphthalene
fg/L
61.2
15.7
11.1
11.2
15.7
2.69
5.41
M1
5.48
Inoraanics
Cyanide, Total
mg/L
...
0.01
U
0.01
U
0.01
u
0.01
u
na
na
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
0.0100
Manganese, Total
mg/L
0.775
na
na
na
na
na
na
0.159
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
na
Iron, Dissolved
mg/L
...
na
na
na
na
na .
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
Methane
Mg/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014
Bedrock Wells
Page 33 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance
MW31-GW-0410
Dup1-GW-0410
MW31
-GW-0710
DP01
-GW-0710
MW31
-GW-1010
MW31(DP)-GW-1010
Standard
07-Apr-2010
07-Apr-2010
07-Jul-2010
07-Jul-2010
05-0ct-2010
05-0ct-2010
DV
DV
DV
DV
DV
VOCs
Units
Benzene
M9/I-
5
206
M1
198
M1
237
220
299
293
Toluene
pg/L
1000
7.35
6.6
5.73
5.45
8.17
7.86
Ethyl benzene
pg/L
700
340
C9
316
C9
288
263
357
341
Xylenes, Total
pg/L
10000
241
M1
224
M1
174
162
202
194
PAHs
Acenaphthene
pg/L
914
68.9
J+
68.5 -
J+
35.6
H2 J-
37
H2
J-
24.9
RL1
27.8
Acenaphthylene
fig/L
362
26.6
J+
25.0
J+
10.2
9.93
9.41
RL1
10.8
Anthracene
pg/L
...
2.69
M1
J+
2.35
J+
1.36
1.2
1.60
RL1
1.20
Benzo(a)anthracene
pg/L
0.13
0.151
J+
0.113
J+
0.100
U
0.100
U
1.00
U.RL1
0.100
U
Benzo(a)pyrene
fig/L
0.2
0.230
J+
0.160
J+
0.100
U
0.100
U
1.00
U.RL1
0.122
Benzo(b)fluoranthene
M9/L
0.1
0.410
J+
0.288
J+
0.104
0.114
1.00
U.RL1
0.241
Benzo(ghi)perylene
fig/L
...
0.250
J+
0.175
J+
0.100
U
0.100
U
1.00
U.RL1
0.166
Benzo(k)fluoranthene
pg/L
0.14
0.162
J+
0.130
J+
0.100
U
0.100
U
1.00
U,RL1
0.110
Chrysene
pg/L
0.85
0.234
J+
0.175
J+
0.100
U
0.100
U
1.00
U,RL1
0.183
Dibenzo(a,h)anthracene
pg/L
0.033
0.0414
J, MDL
J+
0.0142
J,MDL
J+
0.00994
J,MDL
0.0103
J, MDL
0.0810
U,RL1, MDL
0.0194
J, MDL
Fluoranthene
pg/L
...
0.832
J+
0.764
J+
0.406
0.397
1.00
U,RL1
0.517
Fluorene
pg/L
490
19.4
J+
18.8
J+
7.69
7.24
6.80
RL1
7.83
lndeno( 1,2,3-cd)pyrene
pg/L
0.1
0.208
J+
0.147
J+
0.100
U
0.100
U
1.00
U,RL1
0.129
Naphthalene
pg/L
1.1
217
J+
223
J+
120
H2 J-
130
H2
J-
92.0
RL1
106
Phenanthrene
mq/l
294
9.03
M1
J+
9.06
J+
6.09
5.43
5.30
RL1
5.15
Pyrene
pg/L
—
0.767
J+
0.647
J+
0.464
0.448
1.00
U,RL1
0.541
1-Methylnaphthalene
pg/L
—
267
J+
273
J+
135
H2 J-
145
H2
J-
93.5
RL1
109
2-Methylnaphthalene
pg/L
61.2
4.61
M1
J+
4.38
J+
3.09
3.14
3.44
RL1
3.89
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U,M1, R
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.149
0.145
0.152
0.154
0.148
0.140
Natural Attenuation Parameters
Nitrate
mg/L
...
0.10
U
0.10
U
na
na
0.10
U
0.10
U
Nitrite
mg/L
...
0.100
U,M1
0.100
U
na
na
0.100
U
0.100
U
Ammonia
mg/L
...
0.200
U
0.200
U
na
na
0.200
U.
0.200
U
Manganese, Dissolved
mg/L
...
0.134
0.144
na
na
0.141
0.141
Iron, Dissolved
mg/L
...
0.860
0.934
na
na
1.11
1.11
Sulfate
mg/L
...
37.5
40.7
na
na
51.4
50.6
Sulfide
mg/L
...
5.00
U
5.00
U
na
na
5.00
U
5.00
U
Methane
pg/L
...
87
101
na
na
109 '
103
Alkalinity, Total
mg/L
...
497
497
na
na
453
458
Total Kjeldahl Nitrogen
mg/L
...
1.00
U,M1
1.00
U
na
na
1.00
U
1.00
U
Orthophosphate
mg/L
...
0.100
U
0.100
U
na
na
0.100
U
0.100
U
Total Organic Carbon
mg/L
...
1.23
1.27
na
na
1.21 .
1.21
Chloride
mg/L
...
56.4
54.2
na
na
50.0
50.6
icgp_gw_2013-10.xlsx
B's-^pk Wells of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW31-GW-0411 MW31-GW-1011 MW31-GW-0412 MW31-GW-1012 MW31-GW-0413 MW31-GW-1013 MW33-GW-1002
Standard 12-Apr-2011 25-Oct-2011 10-Apr-2012 09-0ct-2012 10-Apr-2013 22-Oct-2013 29-Oct-2002
DV DV DV
VOCs
Units
Benzene
ug/L
5
264
MHA
213
229
218
255
289
2
u
Toluene
|jg/L
1000
6.06
5.97
7.62
6.49
345
10.1
2
U
Ethylbenzene
pg/L
700
284
MHA
262
313
296
7.19
367
2
U
Xylenes, Total
Hg/L
10000
175
MHA
J-
162
180
172
206
236
7
U
PAHs
Acenaphthene
pg/L
914
28.2
M1
16.6
J-
37.9
31.5
52.4
34.1
0.52
u
Acenaphthylene
pg/L
362
8.63
M1
14.0
J-
14.4
15.0
18.8
12.9
1
U
Anthracene
pg/L
1.26
1.46
J-
1.49
1.24
1.74
1.69
0.052
U
Benzo(a)anthracene
pg/L
0.13
0.100
U
0.100
U
UJ
0.100
U
0.100
U
0.100
U
0.100
U
0.1
u
Benzo(a)pyrene
pg/L
0.2
0.100
U
0.100
U
UJ
0.100
U
0.100
u
0.100
U
0.100
U
0.1
U
Benzo(b)fluoranthene
pg/L
0.1
0.106
0.100
u
UJ
0.100
U
0.100
u
0.100
U
0.100
U
0.1
U
Benzo(ghi)perylene
pg/L
—
0.100
U
0.100
u
UJ
0.100
U
0.100
u
0.100
U
0.100
U
0.1
U
Benzo(k)fluoranthene
pg/L
0.14
0.100
U
0.100
u
UJ
0.100
U
0.100
u
0.100
U
0.100
u
0.1
U
Chrysene
pg/L
0.85
0.100
U
0.100
u
UJ
0.100
U
0.100
u
0.100
U
0.100
U
0.1
U
Dibenzo(a,h)anthracene
pg/L
0.033
0.0170
U.MDL
0.0170
U.MDL
UJ
0.0170
U,MDL
0.013
U.MDL
0.0191
U
0.0179
U
0.1
U
Fluoranthene
pg/L
...
0.387
0.420
J-
0.515
0.389
0.59
0.654
0.1
U
Fluorene
pg/L .
490
7.06
M1
J-
9.90
J-
9.60
10.3
15.6
9.91
0.1
U
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.100
0.100
U
UJ
0.100
U
0.100
U
0.100-
U
0.100
u
0.1
U
Naphthalene
pg/L
1.1
88.5
M1
128
J-
154
122
180
166
J-
0.52
U
Phenanthrene
pg/L
294
5.67
M1
J-
8.07
J-
9.32
7.14
8.27
6.09
0.1
U
Pyrene
pg/L
...
0.413
0.416
J-
0.516
0.395
0.643
0.846
0.1
U
1-Methylnaphthalene
pg/L
...
108
M1
117
J-
164
121
198
145
J-
na
2-Methylnaphthalene
pg/L
61.2
2.96
M1
J-
4.89
J-
5.21
5.99
9.15
7.5
na
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
0.00637
Cyanide,-WAD
mg/L
0.2
0.0100
U,M1
UJ
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
u
na
Manganese, Total
mg/L
0.775
0.152
0.145
0.151
0.150
0.108
0.143
0.295
Natural Attenuation Parameters
Nitrate
mg/L
...
0.10
U
0.100
U
0.100
U
0.100
U
0.100
U
na
na
Nitrite
mg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
na
na
Ammonia
mg/L
...
0.200
U
0.200
U
0.200
U
0.200
U
0.200
U
na
na
Manganese, Dissolved
mg/L
...
0.136
0.152
0.145
0.152
0.148
na
0.23
Iron, Dissolved
mg/L
...
0.949
1.23
1.15
1.32
0.951
na
.1.79
Sulfate
mg/L
...
50.7
18.3
44.2
55.8
26.8
na
na
Sulfide
mg/L
...
43
10
U
10
U
10
U
21.7
¦' na
na
Methane
mq/l
...
32
26
71
71
49
na
na
Alkalinity, Total
mg/L
444
444
434
429
487
na
na
Total Kjeldahl Nitrogen
mg/L
...
1.00
U,M1
1.00
U
1.00
U
1.00
U
1.00
U
na
na
Orthophosphate
mg/L
0.100
U
0.100
Li
O'.IOO
U
0.100
U
0.100
U
na
na
Total Organic Carbon
mg/L
—
na
1.29
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Bedrock Wells Page 35 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW33-GW-0103 MW33-GW-0103 MW33-GW-1003 MW33-GW-0404 MW33-GW-1004 MW33-GW-0405 MW33-GW1005
Standard 06-Jan-2003 09-Jan-2003 21-0ct-2003 05-Apr-2004 19-0ct-2004 12-Apr-2005 10-0ct-2005
VOCs
Units
Benzene
5
1.0
U
ns
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
Toluene
m/l
1000
1.0
U
ns
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
Ethyl benzene
ng/L
700
1.0
u
ns
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
Xylenes, Total
ng/L
10000
3.0
u
ns
1.0
U
1.0
U
1.0
U
2.0
U
2.0
U
PAHs
Acenaphthene
Mg/L
914
0.51
u
0.52
U
2.6
u
2.5
LI-
2.5
U
2.5
U
2.5
U
Acenaphthylene
kig/L
362
1.0
u
1
U
1.4
u
1.3
LI*
1.3
U
1.3
U
1.3
U
Anthracene
Mg/L
...
0.051
u
0.052
U
0.052
u*
0.050
U
0.050
U
0.050
U
0.050
U
Benzo(a)anthracene
Mg/L
0.13
0.10
u
0.1
U
0.14
u
0.13
U
0.13
U
0.13
U
0.13
U
Benzo(a)pyrene
0.2
0.10
u
0.1
U
0.14
u
0.13
U
0.13
U
0.13
U
0.13
U
Benzo(b)fluoranthene
mq/l
0.1
0.10
u
0.1
u
0.052
u
0.050
U
0.050
U
0.050
U
0.050
U
Benzo(ghi)perylene
MQ/L
...
0.10
u
0.1
u
0.21
u
0.20
U
0.20
U
0.20
U
0.20
U
Benzo(k)fluoranthene
Mg/L
0.14
0.10
u
0.1
u
0.052
u
0.050
U
0.050
U
0.050
U
0.050
U
Chrysene
Mg/L
0.85
0.10
u
0.1
u
0.14
u
0.13
U
0.13
U
0.13
U
0.13
U
Dibenzo(a,h)anthracene
Mg/i-
0.033
0.10
u
0.1
u
0.31
u
0.30
U
0.30
U "
0.30
U
0.30
U
Fluoranthene
pg/L
...
0.10
u
0.1
u
0.14
u
0.13
U
0.13
U
0.13
U
0.13
U
Fluorene
Mg/L
490
0.10
u
0.1
u
0.26
u
0.25
U"
0.25
U
0.25
U
0.25
U
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.10
u
0.1
u
0.14
u
0.13
U
0.13
U
0.13
U
0.13
U
Naphthalene
ng/L
1.1
0.51
u
0.52
u
1.4
u
1.3
U*
1.3
U
1.3
U
1.3
U
Phenanthrene
Mg/L
294
0.10
u
0.1
u
0.10
u
0.099
U*
0.10
U
0.099
U
0.10
U
Pyrene
tjg/L
...
0.10
u
0.1
u
0.26
u
0.25
U
0.25
U
0.25
U
0.25
U
1 -Methylnaphthalene
ng/L
...
na
na
na
na
na
na
na
2-Methylnaphthalene
|jg/L
61.2
na
na
na
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
0.00595
ns
0.0086
B
0.0087
B
0.010
U
0.010
U
0.010
U
Cyanide, WAD
mg/L
0.2
na
ns
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.247
ns
0.24
0.21
0.25
0.23
0.26
Natural Attenuation Parameters
Nitrate
mg/L
...
na
ns
na
na
na
na
na
Nitrite
mg/L
na
ns
na
na
na
na
na
Ammonia
mg/L
...
na
ns
na
na
na
na
na
Manganese, Dissolved
mg/L
...
0.233
ns
0.22
0.21
0.21
0.22
0.31
Iron, Dissolved
mg/L
...
2.09
ns
2.1
2.0
1.9
1.8
2.4
Sulfate
mg/L
...
na
ns
na
na
na
na
na
Sulfide
mg/L
...
na
ns
na
na
na
na
na
Methane
ng/L
...
na
ns
na
na
na
na
na
Alkalinity, Total
mg/L
—
na
ns
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
ns
na
na
na
na
na
Orthophosphate
mg/L
...
na
ns
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
ns
na
na
na
na
na
Chloride
mg/L
...
na
ns
na
na
na
na
na
icgp_gw_2013-10.xlsx
4 B'-'-^pk Wells £s-==-36 of 53
i \ ! "\ \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW33-GW-0406 MW33-GW-0410 MW33-GW-0411 MW33-GW-0412 MW33-GW-0413 MW35-GW-1002 MW35-GW-0103 MW35-GW-1003
Standard 10-Apr-2006 07-Apr-2010 11 -Apr-2011 10-Apr-2012 09-Apr-2013 28-Oct-2002 07-Jan-2003 22-Oct-2003
VOCs
Units
Benzene
Mg/L
5
1
U
1.00
U
1.00
U
1.0
U
0.50
U
2
U
1.0
U
1.0
U
Toluene
mq/l
1000
1
U
1.00
U
1.00
U
1.0
U
1.00
U
2
U
1.0
U
1.0
U
Ethylbenzene
hq/l
700
1
U
1.00
U
1.00.
U
1.0
U
1.00
U
2
U
1.0
U
1.0
U
Xylenes, Total
mq/l
10000
3
U
6.00
U
3.00
U
1.0
U
3.00
U
7
u
3.0
U
1.0
U
PAHs
Acenaphthene
Mg/L
914
0.13
U
0.100
U
0.100
U
0.100
U
0.100
U
0.52
u
0.54
U
2.6
U
Acenaphthylene
MQ/L
362
0.17
U
0.100
U
0.100
u
0.100
U
0.100
U
1
u
1.1
U
1.4
U
Anthracene
Mg/L
...
0.0093
U
0.100
U
0.100
u
0.100
U
0.100
U
0.052
u
0.054
U
0.052
U
Benzo(a)anthracene
Mg/L
0.13
0.019
U
0.100
U
0.100.
u
0.100
U
0.100
U
0.1
u
0.11
U
0.14
U
Benzo(a)pyrene
Mg/L
0.2
0.019
U
0.100
U
0.100
u
0.100
U
0.100
U
0.1
u
0.11
u
0.14
U
Benzo(b)fluoranthene
Mg/L
0.1
0.037
U '
0.100
U
0.100
u
0.100
U
0.100
U
0.1
u
0.11
u
0.052
U
Benzo(ghi)perylene
Mg/L
...
0.032
U
0.100
U
0.100
u
0.100
U
0.100
U
0.1
u
0.11
u
0.21
U
Benzo(k)fluoranthene
Mg/L
0.14
0.023
U
0.100
U
0.100
u
0.100
U
0.100
U
0.1
u
0.11
u
0.052
U
Chrysene
Mg/L
0.85
0.02
U
0.100
U
0.100
u
0.100
U
0.100
U
0.1
u
0.11
u
0.14
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.033
U
0.00810
U,J,MDL
0.0170
U,MDL
0.0170
U,MDL
0.0172
U
0.1
u
0.11
u
0.31
U
Fluoranthene
ms/l
...
0.032
U
0.100
U
0.100
U
0.100
U
0.100
U
0.1
u
0.11
u
0.14
U
Fluorene
Mg/L
490
0.029
U
0.100
U
0.100
U
0.100
U
0.100
U
0.1
u
0.11
u
0.26
U
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.038
U
0.100
U
0.100
U
0.100
U
0.100
U
0.1
u
0.11
u
0.14
U
Naphthalene
m9/l
1.1
0.1
U
0.100
U
0.100
U
0.100
U
0.100
U
0.52
u
0.54
u
1.4
U
Phenanthrene
Mg/L
294
0.015
U
0.100
U
0.100
U
0.100
U
0.100
u
0.1
u
0.11
u
0.10
U
Pyrene
Mg/L
...
0.036
U
0.100
U'
0.100
U
0.100
U
0.100
(J
0.1
u
0.11
u
0.26
U
1-Methylnaphthaiene
Mg/L
...
na
0.100
U
0.100
U
0.100
U
0.100
u
na
na
na
2-Methylnaphthalene
Mg/L
61.2
na
0.100
U
0.100
U
0.100
U
0.100
u
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
0.01
U
na
na
na
na
0.005
u
0.00500
u
0.010
U
Cyanide, WAD
mg/L
0.2
na
0.0100
U
0.0100
U
0.0100
U
0.0100
u
na
na
na
Manganese, Total
mg/L
0.775
0.208
1.06
0.218
0.188
0.205
0.0251
0.0158
0.98
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
0.204
na
na
na
na
0.0137
0.00744
0.0094
B
Iron, Dissolved
mg/L
...
2.26
na
na
na
na
0.198
u
0.123
0.050
U
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
...
. na
na
na
na1.
na
na
na
na
Methane
Mg/L
. —
na
na
na
na
na
na
na
na
Alkalinity, Total ¦
mg/L
...
na
na
na
na ""
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Bedrock Wells Page 37 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW35-GW-0404 MW35-GW-1004 MW35-GW-0405 MW35-GW1005 MW35-GW-0406 MW35-GW-1006 MW35-GW-0407
Standard 07-Apr-2004 - 20-0ct-2004 13-Apr-2005 12-0ct-2005 11-Apr-2006 10-0ct-2006 16-Apr-2007
VOCs Units
Benzene
|jg/L
5
1.0
u
1.0
u
1.0
u
1.0
u
1 u
1
U
1.00
u
Toluene
M9/L
1000
1.0
u
1.0
u
1.0
u
1.0
u
1 u
1
u
1.00
u
Ethylbenzene
Hg/L
700
1.0
u
1.0
u
1.0
u
1.0
u
1 u
1
u
1.00
u
Xylenes, Total
Mg/L
10000
1.0
u
1.0
u
2.0
u
2.0
u
3 U
3
u
3.00
u
PAHs
Acenaphthene
ra/L
914
2.4
U
2.7
U
2.5
U
2.3
U
0.13
U
0.049
U
0.0490
U
Acenaphthylene
M9/I-
362
1.2
U
1.4
U
1.3
U
1.2
U
0.17
U
0.085
U
0.0850
U
Anthracene
M9/L
...
0.048
u
0.0089
Ja
0.050
u
0.047
u
0.0093
U
0.01
U
0.0100
U
Benzo(a)anthracene
ng/i
0.13
0.12
u
0.14
U
0.13
u
0.12
u
0.019
U
0.003
U
0.0030
U
Benzo(a)pyrene
ug/L
0.2
0.12
u
0.14
U
0.13
u
0.12
u
0.019
U
0.032
U
0.0320
U
Benzo(b)fluoranthene
Mg/L
0.1
0.048
u .
0.055
U
0.050
u
0.047
u
0.037
U
0.013
U
0.0130
U
Benzo(ghi)perylene
^g/L
...
0.19
u
0.22
U
0.20
• u
0.19
u
0.032
U
0.009
U
0.00900
U
Benzo(k)fluoranthene
Mg/i-
0.14
0.048
u
0.055
U
0.050
u
0.047
u
0.023
U
0.015
U
0.0150
U
Chrysene
Mg/L
0.85
0.12
u
0.14
U
0.13
u
0.12
u
0.02
U
0.005
U
0.00500
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.29
u
0.33
U
0.30
u
0.28
u
0.033
U
0.01
U
0.0100
U
Fluoranthene
pg/L
...
0.12
u
0.14
U
0.13
u
0.12
u
0.032
U
0.01
U
0.0100
U
Fluorene
Mg/L
490
0.24
u
0.27
U
0.25
u
0.23
u
0.029
U
0.01
U
0.0100
U
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.12
u
0.14
U
0.13
u
0.12
u
0.038
U
0.007
U
0.00700
U
Naphthalene
Mg/L
1.1
1.2
u
1.4
U
1.3
u
1.2
u
0.1
U
0.054
U
0.0540
U
Phenanthrene
pg/L
294
0.095
u
0.048
Ja
• 0.10
u
0.093
u
0.015
U
0.007
U
0.00700
U
Pyrene
pg/L
...
0.24
u
0.27
U
0.25
u
0.23
u
0.036
U
0.019
U
0.0190
U
1-Methylnaphthalene
pg/L
...
na
na
na
na
na
na
na
2-Methylnaphthalene
Mg/L
61.2
na
na
na
na
na
0.052
U
0.0520
U
Inoraanics
Cyanide, Total
mg/L
...
0.0061
B
0.010
U
0.010
u
0.0019
B
0.01
U
0.01
U
0.0100
U
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.040
0.14
0.22
0.23
0.264
na
na
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
Nitrite
mg/L-
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
0.0084
B
0.044
0.19
0.25
0.249
na
na
Iron, Dissolved
mg/L
...
0.050
U
0.050
U
0.10
u
0.10
u
. 0.1
U
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na '
na
na
na
na
na
Methane
pg/L
...
na
na
na
na
na
na •
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na--'
na
na
na
na
na
icgp_gw_2013-10.xlsx
4 B-r^-ck Wells P,=~
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW35-GW-1007 MW35-GW-0408 MW35-GW-0410 MW35-GW-1010 MW35-GW-0411 MW35-GW-1011 MW35-GW-0412
Standard 09-0ct-2007 15-Apr-2008 08-Apr-2010 06-0ct-2010 11 -Apr-2011 24-Oct-2011 11-Apr-2012
DV
VOCs
Units
Benzene
ug/L
5
1.00
U
1.00
U.L1
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Toluene
ng/L
1000
1.00
U
1.00
U.L1
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethylbenzene
Hg/L
700
1.00
U
1.00
U,L1
1.00
u
1.00
(J
1.00
U
1.00
U
1.00
U
Xylenes, Total
pg/t-
10000
3.00
U
3.00
U.L1
6.00
u
3.00
u
3.00
U
3.0
U
3.0
U
PAHs
Acenaphthene
ng/L
914
0.057
U
0.0995
J
0.100
u
0.383
0.100
U
0.100
U
UJ
0.100
U
Acenaphthylene
ug/L
362
0.0988
U
0.0850
U
0.100
u
0.273
0.100
U
0.100
U
UJ
0.100
U
Anthracene
ug/L
...
0.0116
U
0.0351
J
0.100
u
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Benzo(a)anthracene
Hg/L.
0.13
0.00349
U
0.0030
U
0.100
u
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Benzo(a)pyrene
Mg/L
0.2
0.0372
U
0.0320
U
0.100
u
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Benzo(b)fluoranthene
pg/L
0.1
0.0151
U
0.0130
U
0.100
u
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Benzo(ghi)perylene
pg/L
...
0.0105
U
0.00900
U
0.100
u
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Benzo(k)fluoranthene
M9/L
0.14
0.0174
U
0.0150
U
0.100
u
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Chrysene
Mg/L
0.85
0.00581
U
0.00500
U
0.100
u
0.100
u
0.100
U
0.100
U
UJ
0.100
U
Dibenzo(a,h)anthracene
pg/L
0.033
0.0116
u
0.0100
U
0.0081
U,MDL
0.00810
U.MDL
0.0170
U,MDL
0.0170
U.MDL
UJ
0.0170
U.MDL
Fluoranthene
Mg/L
...
0.0116
u
0.0100
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
Fluorene
Mg/L
490
0.0116
u
0.249
0.100
U
0.180
0.100
U
0.100
U
UJ
0.100
U
lndeno(1,2,3-cd)pyrene
i^g/L
0.1
0.00814
u
0.00700
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
Naphthalene
ijg/L
1.1
0.0628
u
0.312
0.100
U
2.18
0.100
U
0.100
U
UJ
0.104
Phenanthrene
pg/L
294
0.00814
u
0.175
0.100
U
0.145
0.100
U
0.100
U
UJ
0.100
U
Pyrene
Mg/L
...
0.0221
u
0.0190
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
1-Methylnaphthalene
Mg/L
...
na
na
0.100
U
0.632
0.100
U
0.100
U
UJ
0.125
2-Methylnaphthalene
Mg/L
61.2
0.0605
u
0.0520
U
0.100
U
0.152
0.100
U
0.100
U
UJ
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
0.0100
u
0.0100
U
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
na
na
0.0100
U
0.0100
U
0.0100
U
0.0100
U
UJ
0.0100
U
"Manganese, Total
mg/L
0.775
na
na
0.354
0.355
0.326
0.358
0.325
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
na
Iron,. Dissolved
mg/L
...
na
na
na
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
Methane
ng/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gvv_2013-10.xlsx
2/11/2014
Bedrock Wells
Page 39 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW35-GW-1012 MW35-GW-0413 MW35-GW-1013 MW36-GW-1002 MW36-GW-0103 MW36-GW-1003 MW36-GW-0404
Standard 09-0ct-2012 11-Apr-2013 22-Oct-2013 29-Oct-2002 06-Jan-2003 21-0ct-2003 06-Apr-2004
DV DV DV
VOCs
Units
Benzene
Hg/L
5
1.00
U
0.500
U
0.500
u
110
120
150
120
Toluene
ng/L
1000
1.00
U
1.00
U
1.00
u
2.5
3.1
1.1
1.4
Ethylbenzene
mq/l
700
1.00
U
1.00
U
1.00
u
100
140
140
140
Xylenes, Total
ng/L
10000
3.00
U
3.00
U
3.00
U
58
87
38
54
PAHs
Acenaphthene
pg/L
914
0.100
U
UJ
0.100
u
0.100
U
60
0.5
U
35
44
¦
Acenaphthylene
ng/L
362
0.100
U
UJ
0.100
u
0.100
U
1.1
U
1.0
U
310
370
*
Anthracene
pg/L
...
0.100
U
UJ
0.100
u
0.100
U
0.24
0.31
J
0.61
0.76
Benzo(a)anthracene
^g/L
0.13
0.100
U
UJ
0.100
u
0.100
U
0.11
U
0.10
U
0.13
U
0.12
U
Benzo(a)pyrene
Mg/L
0.2
0.100
U
UJ
0.100
u
0.100
U
0.11
U
0.10
U
0.13
U
0.12
u
Benzo(b)fluoranthene
ijg/L
0.1
0.100
U
UJ
0.100
u
0.100
U
0.11
U
0.10
U
0.050
U
0.048
u
Benzo(ghi)perylene
Mg/L
...
0.100
U
UJ
0.100
u
0.100
U
0.11
U
0.10
U
0.20
U
0.19
u
Benzo(k)fluoranthene
M9/L
0.14
0.100
U
UJ
0.100
u
0.100
U
0.11
U
0.10
U
0.050
U
0.048
u
Chrysene
pg/L
0.85
0.100
U
UJ
0.100
u
0.100
U
0.11
U
0.10
U
0.13
U
0.12
u
Dibenzo(a,h)anthracene
Mg/L
0.033
0.0130
U.MDL
UJ
0.0185
u
0.0173
U
0.11
u
0.10
U
0.30
U
0.29
u
Fluoranthene
MQ/L
...
0.100
U
UJ
0.100
u
0.100
U
0.14
0.15
J
0.48
0.79
Fluorene
Mg/L
490
0.100
U
UJ
0.100
u
0.100
U
7
0.22
J
7.2
9.3
•
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.100
U
UJ
0.100
u
0.100
U
0.11
u
0.10
U
0.13
U
0.12
u
Naphthalene
Mg/L
1.1
0.100
U
UJ
1.11
B
0.12
54
u
26
J
14
30
'
Phenanthrene
ijg/L
294
0.100
U
UJ
0.100
u
0.100
U
1.7
2.1
J
4.4
6.8
*
Pyrene
Mg/L
...
0.100
U
UJ
0.100
u
0.100
U
0.11
u
0.10
U
0.25
Ua
0.24
u
1-Methylnaphlhalene
Mg/L
...
0.100
U
UJ
0.154
0.100
U
na
na
na
na
2-Methylnaphthalene
Mg/L
61.2
0.100
U
UJ
0.135
0.100
U
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
0.005
0.00500
U
0.010
U
0.010
u
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
u
0.0100
U
na
na
na
na
Manganese, Total
mg/L
0.775
0.361
0.371
0.313
0.146
0.166
0.18
0.17
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
0.151
0.158
0.16
0.16
Iron, Dissolved
mg/L
...
na
na
na
1.47
1.39
1.4
1.2
Sulfate
mg/L
...
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
Methane
W/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
¦ ...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
E^^pk Wells
ppji-v40 of 53
\
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW36-GW-1004 MW36-GW-0405 MW36-GW-1005 MW36-GW-0406 MW36-GW-1006 MW36-GW-0407 MW36-GW-1007 MW36-GW-0408
Standard 20-0ct-2004 13-Apr-2005 12-0ct-2005 12-Apr-2006 09-0ct-2006 18-Apr-2007 10-0ct-2007 16-Apr-2008
VOCs Units
Benzene
M9/L
5
140
120
120
91.6
60.7
30.8
82.9
1
U
Toluene
ng/L
1000
1.1
0.78
Ja
1.0
U
1
U
1.16
1
U
4.19
1
U
Ethylbenzene
ug/L
700
160
130
120
92.6
36
15.7
84
1
u
Xylenes, Total
ug/L
10000
51
39
19
10.2
11.6
3
U
7.06
3
u
PAHs
Acenaphthene
Mg/L
914
37
41
42
28.9
28.8
24.9
37.8
7.64
Acenaphthylene
ra'L
362
320
380
¦ 350
0.17
U
0.085
U
0.085
U
0.085
U
0.085
u
Anthracene
Mg/L
—
0.87
1.1
1.1
0.815
0.792
0.447
0.567
0.0809
J
Benzo(a)anthracene
Mg/L
0.13
0.13
U
0.12
U
0.12
U
0.019
U
0.003
U
0.003
U
0.003
U
0.003
u
Benzo(a)pyrene
pg/L
0.2
0.13
U
0.12
U
0.12
u
0.019
U
0.032
U
0.032
U
0.032
U
0.032
u
Benzo(b)fluoranthene
Mg/L
0.1
0.052
u
0.047
U
0.048
u
0.037
U
0.013
U
0.013
U
0.013
U
0.013
u
Benzo(ghi)perylene
Mg/L
...
0.21
u
0.19
U
0.19
u
0.032
U
0.009
U
0.009
U
0.009
U
0.009
u
Benzo(k)fluoranthene
pg/L
0.14
0.052
u
0.047
U
0.048
u
0.023
U
0.015
U
0.015
U
0.015
U
0.015
u
Chrysene
Mg/L
0.85
0.13
u
0.12
U
0.12
u
0.02
U
0.005
U
0.005
U
0.005
U
0.005
u
Dibenzo(a,h)anthracene
Mg/L
0.033
0.31
u
0.28
U
0.29
u
0.033
U
0.01
U
0.01
U
0.01
U
0.01
u
Fluoranthene
ijg/L
...
0.78
0:82
0.54
0.651
0.424
0.237
0.382
0.0648
J
Fluorene
pg/L
490
7.7
9.1
8.6
10.4
13.8
11
33.3
3.99
lndeno(1,2,3-cd)pyrene
Hg/L
0.1
0.13
u
0.12
U
0.12
u
0.038
U
0.007
U
0.007
U
0.007
U
0.007
u
Naphthalene
|jg/L
1.1
19
7.9
5.2
2.77
3.78
1.93
4.89
0.493
Phenanthrene
ng/L
294
5.7
6.6
5.9
6.2
4.67
3.05
5.61
0.706
Pyrene
ijg/L
...
0.29
0.099
Ja
0.28
2.69
1.7
0.964
1.21
0.0411
J
1-Methyl naphthalene
Mg/i-
—
na
na
na
na
na
na
na
na
2-Methylnaphthalene
ijg/L
61.2
na
na
na
na
0.052
U
0.29
0.052
U
0.0707
J
tnoraanics
Cyanide, Total
mg/L
...
0.010
u
0.010
U
0.0027
B
0.01
U
0.01
U
0.01
U
0.01
U
0.01
u
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.18
0.18
0.25
0.154
na
na
na
na
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na.
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
0.17
0.17
0.17
0.161
na
na
na
na
Iron, Dissolved
mg/L
...
1.2
1.3
1.6
1.44
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
na
na
na
na
na
na
na
na
Methane
pg/L
¦ —
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na'
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
• na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014
Bedrock Wells
Page 41 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW36-GW-0409 MW36-GW-1009 MW36-GW-0110 DP01-GW-0110 MW36-GW-0410 MW36-GW-0710 MW36-GW-1010
Standard 22-Apr-2009 14-0ct-2009 14-Jan-2010 14-Jan-2010 07-Apr-2010 07-Jul-2010 05-0ct-2010
DV
VOCs
Units
Benzene
mq/l
5
1
U
25.6
1.00
U
1.00
U
2.92
23.2
40.2
Toluene
Mg/L
1000
1
U
1
U
1.00
U
1.00
U
1.00
' U
1.00
U
1.00
U
Ethyl benzene
mq/l
700
1
U
7.13
1.00
U
1.00
U
1.00
U
4.68
20.8
Xylenes, Total
Mg/L
10000
3
U
3
U
3.00
U
3.00
U
6.00
u
4.35
4.48
PAHs
Acenaphthene
Mg/L
914
7.75
15.5
10.5
10.3
16.0
18.6
H2
J-
14.9
Acenaphthylene
M9/L
362
1.85
4.6
2.01
2.04
3.28
3.78
H2
J-
3.21
Anthracene
pg/L
...
0.0551
J
0.143
0.0487
J
0.0488
J
0.120
0.131
H2
J-
0.100
U
Benzo(a)anthracene
|jg/L
0.13
0.0250
J
0.0216
J
0.0125
J
0.0119
J
0.100
u
0.100
U,H2
UJ
0.100
U
Benzo(a)pyrene
0.2
.0.0186
J
0.016
U
0.0160
U
0.0160
U
0.100
u
0.100
U.H2
UJ
0.100
U
Benzo(b)fluoranthene
ng/L
0.1
0.0211
J
0.0158
J
0.00760
U
0.00760
U
0.100
u
0.100
U,H2
UJ
0.100
U
Benzo(ghi)peryiene
Mg/L
...
0.0121
J
0.00887
J
0.00810
U
0.00810
U
0.100
u
0.100
U,H2
UJ
0.100
U
Benzo(k)fluoranthene
fjg/L
0.14
0.00790
U
0.0077
U
0.00770
U
0.00770
U
0.100
u
0.100
U,H2
UJ
0.100
U
Chrysene
Mg/L
0.85
0.0136
J
0.0101
J
0.00700
U
0.00700
U
.0.100
u
0.100
U,H2
UJ
0.100
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.00760
U
0.0081
U
0.00810
U
0.00810
U
0.0081
U.MDL
0.00810
U,H2,MDL
UJ
0.00810
U,MDL
Fluoranthene
ijg/L
...
0.0727
J
0.107
0.0386
J
0.0434
J
0.100
U
0.100
U.H2
UJ
0.100
U
Fluorene
Mg/L
490
1.95
4.34
2.25
2.33
3.55
3.99
H2
J-
2.97
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.0101
J
0.011
U
0.0110
U
0.0110
u
0.100
U
0.100
U,H2
UJ
0.100
U
Naphthalene
ug/L
1.1
0.00590
u
0.488
0.0290
U
0.0290
u
0.184
0.889
H2
J-
1.32
Phenanthrene
ng/L
294
0.555
0.858
0.170
0.144
0.357
0.377
H2
J-
0.295
Pyrene
ng/L
...
0.068
J
0.111
0.0808
J
0.0831
J
0.100
U
0.100
U,H2
UJ
0.100
u
1-Methylnaphthalene
Mg/L
na
na
na
na
0.54
2.40
H2
J-
7.04
2-Methylnaphthalene
Mg/L
61.2
0.0195
J
0.0531
J
0.0310
U
0.0310
u
0.1
U
0.100
U,H2
UJ
0.100
u
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
na
na
0.0100
U
0.0100
u
0.0100
U
0.0100
U
0.0100
u
Manganese, Total
mg/L
0.775
na
na
0.120
0.120
0.125
0.144
0.123
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
na
Iron, Dissolved
mg/L
...
na
na
na
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
. na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
Methane
pg/L
...
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
—
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
4 Brs^sk Wells P?.^42 0f 53
^ ' \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW36-GW-0411 MW36-GW-1011 MW36-GW-1011-DUP-01 MW36-GW-0412 MW36-GW-1012 DP01-GW-1012
Standard 11 -Apr-2011 25-Oct-2011 25-Oct-2011 10-Apr-2012 09-0ct-2012 09-0ct-2012
¦ DV DV DV DV
VOCs
Units
Benzene
W/L
5
4.24
21.4
20.9
8.76
21.8
22.8
Toluene
MQ/L
1000
1.00
U
1.00
U
1.00
U
1.0
U
1.00
U
1.00
U
Ethyl benzene
hq/l
700
1.00
U
4.95
4.72
1.0
U
2.53
2.75
Xylenes, Total
w/L
10000
3.00
U
4.09
4.22
3.0
U
3.00
U
3.00
U
PAHs
Acenaphthene
hq/l
914
10.6
8.33
J-
7.57
J-
14.3
16.2
J-
15.7
J-
Aceriaphthylene
MQ/L
362
2.66
3.39
3.40
2.71
3.34
J-
3.48
J-
Anthracene
M9/L
...
0.100
U
0.100
U
0.100
U
0.100
U "
0.100
U
UJ
0.100
U
UJ
Benzo(a)anthracene
mq/l
0.13
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
Benzo(a)pyrene
|jg/L
0.2
0.100
U
0.100
U
0.100
u
0.100
U
0.100
U
UJ
0.100
U
UJ
Benzo(b)fluoranthene
mq/l
0.1
0.100
U
0.100
U
0.100
u
0.100
U
0.100
U
UJ
0.100
U
UJ
Benzo(ghi)perylene
W/L
...
0.100
U
0.100
U
0.100
u
0.100
U
0.100
U
UJ
0.100
U
UJ
Benzo(k)fluoranthene
Mg/L
0.14
0.100
U
0.100
U
0.100
u
0.100
U
0.100
U
UJ
0.100
U
UJ
Clirysene
Mg/L
0.85
0.100
U
0.100
U
0.100
u
0.100
U
0.100
U
UJ .
0.100
U
UJ
Dibenzo(a,h)anthracene
MQ/L
0.033
0.0170
U.MDL
0.0170
U.MDL
0.0170
U,MDL
0.0170
U,MDL
0.0130
U,MDL
UJ
0.0130
U.MDL
UJ
Fluoranthene
Mg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
Fluorene
Mg/L
490
2.88
3.49
3.53
2.63
3.28
J-
3.38
J-
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
Naphthalene
ijg/L
1.1
0.745
0.741
0.427
0.158
0.287
J-
0.246
J-
Phenanthrene
M9/L
294
0.162
0.178
0.167
0.132
0.164
J-
0.160
J-
Pyrene
ug'L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
1-Methylnaphthalene
fjg/L
...
1.33
6.47
6.25
0.435
1.58
J-
1.46
J-
2-Methylnaphthalene
w/l
61.2
0.100
U
0.100
u
0.100
U
0.100
U
0.100
U
UJ
0.100
U
UJ
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
u
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.127
0.159
0.147
0.12
0.141
0.144
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na .
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
na
na
Iron, Dissolved
mg/L
...
na
na
na
na
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
Methane
ug/L
...
na
na
na
na
na
na
¦Alkalinity, Total
mg/L
...
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
Total Organic Carbon
mg/L
—
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
icgp_gw_20l3-10.xlsx
2/11/2014
Bedrock Wells
Page 43 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW36-GW-0413 DP01-GW-0413 MW36-GW-1013 DP01-GW-1013 MW37-GW-1002 MW37-GW-0103 MW37-GW-1003 MW37-GW-0404
Standard 09-Apr-2013 09-Apr-2013 22-Oct-2013 22-Oct-2013 29-Oct-2002 06-Jan-2003 21-0ct-2003 06-Apr-2004
DV DV DV DV
VOCs
Units
Benzene
5
5.18
5.16
45.8
43.9
6.7
52
87
73
Toluene
IJg/L
1000
1.00
U
1.00
U
1.00
U
1.00
U
2
U
1.3
1.0
U
1.0
U
Ethylbenzene
mq/l
700
1.00
U
1.00
U
21.3
20.7
4.9
56
8.1
6.2
Xylenes, Total
Mg/L
10000
3.00
u
3.00
u
5.19
5.09
7
U
26
6.4
5.8
PAHs
Acenaphthene
|jg/L
914
22.4
21
22.6
24.6
3.4
17
15
19
*
Acenaphthylene
M9/L
362
3.51
J+
3.41
5.19
5.34
1.1
U
1.0
U
150
200
¦
Anthracene
—
0.100
u
0.100
u
0.16
0.149
0.053
U
0.051
U
0.14
0.17
Benzo(a)anthracene
|jg/L
0.13
0.100
u
0.100
u
0.100
U
0.100
U
0.11
U
0.10
u
0.13
U
0.13
U
Benzo(a)pyrene
(jg/L
0.2
0.100
u
0.100
u
0.100
U
0.100
U
0.11
U
0.10
u
0.13
U
0.13
U
Benzo(b)fluoranthene
mq/l
0.1
0.100
u
0.100
u
0.100
U
0.100
U
0.11
U
0.10
u
0.050
U
0.050
u
Benzo(ghi)perylene
M9"-
0.100
u
0.100
u
0.100
U
0.100
U
0.11
U
0.10
u
0.20
U
0.20
u
Benzo(k)fluoranthene
ms/l
0.14
0.100
u
0.100
u
0.100
U
0.100
U
0.11
U
0.10
u
0.050
U
0.050
u
Chrysene
ng/L
0.85
0.100
u
0.100
u
0.100
U
0.100
U
0.11
U
0.10
u.
0.13
U
0.13
u
Dibenzo(a,h)anthracene
Mg/L
0.033
0.0173
u
0.0173
u
0.0173
U
0.0175
U
0.11
U
0.10
u
0.30
U
0.30
u
Fluoranthene
ng/L
...
0.12
J+
0.113 ¦
0.125
0.118
0.11
U
0.10
u
0.074
Ja
0.12
Ja
Fluorene
|jg/L
490
4.13
J+
3.95
5.88
5.88
0.36
1.6
2.5
3.4
-
lndeno( 1,2,3-cd)pyrene
Mg/L
0.1
0.100
u
0.100
u
0.100
U
0.100
U
0.11
U
0.10
u
0.13
U
0.13
u
Naphthalene
Mg/L
1.1
0.136
J+
0.142
0.653
0.739
1.4
9.7
1.6
1.0
Ja*
Phenanthrene
i-ig/L
294
0.100
u
0.100
u
0.739
0.73
0.11
U
0.23
1.0
1.5
•
Pyrene
i^g/L
...
0.126
. J+
0.12
0.145
0.133
0.11
. U.
0.10
u
0.25
U
0.25
U
1-Methylnaphthalene
pg/L
...
0.305
J+
0.311
13.9
15.4
na
na
na
na
2-Methylnaphthalene
i-tg/L
61.2
0.100
u
0.100
u
0.100
U
0.100
U
na
na
na
na
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
0.005
U
0.00500
u
0.010
U
0.010
u
Cyanide, WAD
mg/L
0.2
0.0100
u
0.0100
u
0.0100
U
0.0100
U
na
na
na
na
Manganese, Total
mg/L
0.775
0.129
0.131
0.145
0.141
0.0435
0.0476
0.058
0.062
Natural Attenuation Parameters
Nitrate
mg/L
—
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
na
na
0.0381
0.0419
0.050
0.058
Iron, Dissolved
mg/L
...
na
na
na
na
1.89
2.03
2.3
2.3
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
na
Methane
ug/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
na
na
na
na
'na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
—
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2Wr'-iYoi4 Wells F^»«v44 of 53
( \ ( \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW37-GW-1004 MW37-GW-0405 MW37-GW-1005 MW37-GW-0406 MW37-GW-1006 MW37-GW-0407 MW37-GW-1007 MW37-GW-0408
Standard 19-0ct-2004 13-Apr-2005 12-0ct-2005 12-Apr-2006 09-0ct-2006 18-Apr-2007 09-0ct-2007 16-Apr-2008
VOCs
Units
Benzene
Mg/L
5
70
40
19
8.83
2.07
1
U
7.89
1
U
Toluene
mq/l
1000
1.0
U
1.0
U
1.0
U
1
U
1.00
U
1
U
1.11
1
U
Ethylbenzene
MQ/L
700
4.3
1.8
1.0
U
1
U
1.00
U
1
U
1
U
1
U
Xylenes, Total
ng/L
10000
4.3
2.0
J
2.0
U
3
U
3.00
U
3
U
3
U
3
U
PAHs
Acenaphthene
ng/L
914
18
23
24
20.6
19.6
16.8
25.3 ¦
13.8
Acenaphthylene
Mg/L
362
190
210
230
0.17
U
0.085
U
0.0944
U
0.085
U
0.085
U
Anthracene
Mg/L
...
0.24
0.31
0.32
0.24
0.205
0.133
J
0.486
0.0716
J
Benzo(a)anthracene
ng/L
0.13
0.12
U
0.054
Ja
0.12
u
0.019
U
0.003
U
0.00333
U
0.003
U
0.003
U
Benzo(a)pyrene
pg/L
0.2
0.12
U
0.044
Ja
0.12
u
0.019
U
0.032
U
0.0356
U
0.032
U
0.032
U
Benzo(b)fluoranlhene
pg/L
0.1
0.048
U
0.097
0.046
u
0.037
U
0.013
U
0.0144
U
0.013
U
0.013
U
Benzo(ghi)perylene
mq/l
—
0.19
U
0.079 "
Ja
0.19
u
0.032
U
0.009
U
0.01
U
0.009
U
0.009
U
Benzo(k)fluoranthene
pq/l
0.14
0.048
U
0.092
0.046
u
0.023
U
0.015
U
0.0167
U
0.015
U
0.015
U
Chrysene
mq/l
0.85
0.12
U
0.090
Ja
0.12
u
0.02
U
0.005
U
0.00556
U
0.005
U
0.005
U
Dibenzo(a,h)anthracene
ng/L
0.033
0.29
U
0.090
Ja
0.28
u
0.033
U
0.01
U
0.0111
U
0.01
U
0.01
U
Fluoranthene
Mg/L
...
0.15
0.22
0.18
0.182
J
0.133
J
0.0703
J
0.0418
J
0.01
U
Fluorene
Mg/L
490
3.2
4.1
3.9
6.11
7.43
5.88
16.7
6.28
lndeno(1,2,3-cd)pyrene
Mg/L
0.1
0.12
U
0.085
Ja
0.12
u
0.038
U
0.007
U
0.00778
U
0.007
U
0.007
U
Naphthalene
pg/L
1.1
1.2
U
0.45
Ja
1.2
u
0.438
0.385
0.44
0.534
0.297
Phenanthrene
Mg/L
294
1.4
1.6
1.5
1.62
1.27
0.741
1.93
0.442
Pyrene
Mg/L
...
0.24
U
0.24
U
0.23
u
0.036
U
0.339
0.202
J
0.457
0.019
U
1-Methylnaphthalene
pg/L
...
. na
na
na
na
na
na
na
na
2-Methylnaphthalene
pg/L
61.2
na
na
na
na
0.0715
J
0.103
J
0.052
U
0.052
U
Inoraanics
Cyanide, Total
mg/L
...
0.010
U
0.010
U
0.0032
B
0.01
U
0.01
U
0.01
U
0.01
U
0.01
U
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.074
0.073
0.070
0.07
na
na
na
na
Natural Attenuation Parameters
Nitrate-
mg/L
...
na
0.10
U
0.10 .
u
0.1
U
na
na
na
na
Nitrite
mg/L
...
na
0.020
U
0.0096
B
0.025
U
na
na
na
na
Ammonia
mg/L
...
na
0.67
0.50
0.622
U
na
na
na
na
Manganese, Dissolved
mg/L
...
0.062
0.069
0.068
0.0635
na
na
na
na
Iron, Dissolved
mg/L
...
2.4
2.3
2.6
.2.55
na
na
na
. na
Sulfate
mg/L
...
na
69
75
52.8
na
na
na
na
Sulfide
mg/L
...
na
1.0
U
1.0
U
1
u
na
na
na'
na
Methane
Mg/L
...
na
9.6
9.1
26
u
na
na
na
na
Alkalinity, Total
mg/L
...
na
410
400
480
na
na
na"
na
Total Kjeldahl Nitrogen
mg/L
...
na
0.56
0.80
1
u
na
na
na
na
Orthophosphate
mg/L
...
na
0.012
B
' '0.0090
B
0.1
U,M1
na
na
na
na
Total Organic Carbon
mg/L
...
na
1.8
1.9
1.67
na
na
na
na
Chloride
mg/L
...
na
na
na
61.7
M1
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Bedrock Wells Page 45 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW37-GW-0409 MW37-GW-1009 MW37-GW-0110 MW37-GW-0410 MW37-GW-0710 MW37-GW-1010 MW37-GW-0411
Standard 22-Apr-2009 14-0ct-2009 14-Jan-2010 07-Apr-2010 07-Jul-2010 05-0ct-2010 11 -Apr-2011
VOCs
Units
Benzene
Mg/L
5
1
U
1
U
1.00
U
1.00
U
1.00
U
3.37
1.00
U
Toluene
pg/L
1000
1
U
1
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethyl benzene
Hg/L
700
1
U
1
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Xylenes, Total
Hg/L
10000
3
U
3
U
3.00
U
6.00
U
3.00
U
3.00
U
3.00
U
PAHs
Acenaphthene
914
4.41
9.39
9.49
10.4
8.52
10.3
10.1
Acenaphthylene
Mg/L
362
0.313
0.709
0.834
0.843
0.577
0.867
0.591
Anthracene
Mg/L
...
0.00826
J
0.0364
J
0.0259
J
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)anthracene
MQ/L
0.13
0.00944
J
0.0134
J
0.0104
J
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)pyrene
pg/L
0.2
0.00850
U
0.016
U
0.0160
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(b)fluoranthene
ug/L
0.1
0.00990
U
0.0076
U
0.00760
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(ghi)perylene
ug/L
0.00550
U
0.0081
U
0.00810
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(k)fluoranthene
ng/L
0.14
0.00790
U
0.0077
U
0.00770
U
0.100
U
0.100
U
0.100
U
0.100
U
Chrysene
pg/i-
0.85
0.00530
U
0.007
U
0.00700
U
0.100
U
0.100
U
0.100
U
0.100
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.00760
U
0.0081
U
0.00810
U
0.00810
U,MDL
0.00810
U.MDL
0.00810
U.MDL
0.0170
U,MDL
Fluoranthene
ijg/L
...
0.0129
J
0.0285
J
0.0283
J
0.100
U
0.100
U
0.100
U
0.100
U
Fluorene
Mg/L
490
0.876
1.9
1.82
2.09
1.53
1.87
1.81
lndeno(1,2,3-cd)pyrene
ng/L
0.1
0.00690
U
0.011
U
0.0110
U
0.100
U
0.100
U
0.100
U
0.100
U
Naphthalene
Mg/L
1.1
0.00590
U
0.029
U
0.0290
U
0.100
U
0.100
U
0.100
U
0.112
Phenanthrene
ng/L
294
0.0337
J
0.113
0.0554
J
0.100
U
0.100
U
0.100
U
0.100
U
Pyrene
ijg/L
...
0.0134
J
0.0347
J
0.0546
J
0.100
U
0.100
U
0.100
U
0.100
U
1-Methylnaphthalene
tjg/L
...
na
na
0.223
0.239
0.734
0.234
2-Methylnaphthalene
Mg/L
61.2
0.00708
J
0.031
U
0.0310
U
0.100
U
0.100
U
0.100
U
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
. na
Cyanide, WAD
mg/L
0.2
na
na
0.0100
U
.0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
na
na
0.0619
0.0639
0.0718
0.0685
0.0696
Natural Attenuation Parameters
Nitrate
mg/L
na
na
na
0.10
U
na
0.10
U
0.10
U
Nitrite
mg/L
...
na
na
na
0.100
U
na
0.100
U
0.100
U
Ammonia
mg/L
...
na
na
na
0.627
na
0.560
0.698
Manganese, Dissolved
mg/L
...
na
na
na
0.065
na
0.0621
0.0546
Iron, Dissolved
mg/L
...
na
na
na
2.6
na
2.80
2.29
Sulfate
mg/L
...
na
na
na
41.8
na
44.3
43.5
Sulfide
mg/L
...
na
na
na
na
5.00
U
10
U
Methane
ng/L
...
na
na
na
48
na
46.3
15
Alkalinity, Total
mg/L
...
na
na
na
470
na
"433
424
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
1.00
U
na
1.00
U,M1
1.13
Orthophosphate
mg/L
...
na
na1
na
0.100
u
na
0.100
U
0.100
U
Total Organic Carbon
mg/L
...
na
na
na
1.00
u
na
1.00
U
na
Chloride
mg/L
...
na
na
na
30.7
na
38.8
na
icgp_gw_2013-10.xlsx
2/^-—4 Bp.—°ck Wells of 53
i ' ^
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW37-GW-1011 MW37-GW-0412 MW37-GW-1012 MW37-GW-0413 MW37-GW-1013 MW41-GW-1002 MW41-GW-0103
Standard 25-Oct-2011 10-Apr-2012 09-0ct-2012 09-Apr-2013 22-Oct-2013 31-0ct-2002 07-Jan-2003
DV DV DV DV DV
VOCs
Units
Benzene
5
1.03
1.00
U
1.48
0.500
U
9.11
2
U
1.0
U
Toluene
Mg/L
1000
1.00
U
1.00
U
1.00
U
1.00
U
.1.00
U
2
U
1.0
U
Ethylbenzene
US/L
700
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
2
U
1.0
u
Xylenes, Total
pg/L
10000
3.00
U
3.00
U
3.00
u
3.00
U
3.00
U
7
U
3.0
u
PAHs
Acenaphthene
^g/L
914
5.22
J-
12.4
J-
11.3
M1
J-
15.3
14.8
0.55
U
0.51
u
Acenaphthylene
Mg/L
362
0.696
0.823
1.07
1.22
2.02
1.1
U
1.0
u
Anthracene
[jg/i-
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.055
U
0.051
u
Benzo(a)anthracene
Mg/L
0.13
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
Benzo(a)pyrene
pg/L
0.2
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
Benzo(b)fluoranthene
ijg/L
.0.1
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
Benzo(ghi)perylene
W/L
...
0.100
U
0.100
U
0.100
U,M1
UJ
0.100
U
UJ
0J00
U
UJ
0.11
U
0.10
u
Benzo(k)fluoranthene
Mg/L
0.14
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
Chrysene
ng/L
0.85
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
Dibenzo(a,h)anthracene
Mg/L
0.033
0.0170
U,MDL
0.0170
U,MDL
0.0267
J, M1
J-
0.0173
U
UJ
0.0173
U
UJ
0.11
U
0.10
u.
Fluoranthene
MQ/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
Fluorene
ng/L
490
1.77
2.13
2.00
2.91
3.27
0.11
U
0.10
u
lndeno(1,2,3-cd)pyrene
Hg/L
0.1
0.100
U
0.100
U
0.100
U,M1
UJ
0.100
U
UJ
0.100
U
UJ
0.11
U
0.10
u
Naphthalene
ug/L
1.1
0.100.
U
0.100
U
0.119
0.100
U
0.244
0.55
U
0.51
u
Phenanthrene
ijg/L
294
0.100
U
0.-100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
Pyrene
^g/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.11
U
0.10
u
1-Methyl naphthalene
ug/L
...
0.623
0.126
0.345
0.164
2.48
na
na
2-Methyl naphthalene
t-tg/L
61.2
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
na
na
Inornanins
Cyanide, Total
mg/L
...
na
na
na
na
na
0.00592
0.00500
u
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
na
na
Manganese, Total
mg/L
0.775
0.0654
0.0606
0.0715
0.0685
0.0716
0.229
0.0488
Natural Attenuation Parameters
Nitrate
mg/L
...
0.10
U
0.10
U
0.100
U
0.100
U
na
na
na
Nitrite
mg/L
...
0.100
U
0.10
U
0.100
U
0.100
U
na
na
na
Ammonia
mg/L
...
0.647
0.623
0.579
M1
0.655
na
na
na
Manganese, Dissolved
mg/L
...
0.0649
0.0709
0.0715
0.0656
na
0.0372
0.0323
Iron, Dissolved
mg/L
...
2.88
3.08
3.16
3.130
na
0.985
1.4
Sulfate
mg/L
...
42.1
44.4
45.1
40.3
na
na
na
Sulfide
mg/L
...¦
10
U'-
10
U
10
U
11.1
na
na
na
Methane
Mg/L
...
17
42
41
29.7
na
na
na
Alkalinity, Total
mg/L
...
444
414
444
459
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
1.00
U
1.00
U
1.00
U
1.00
U
na
na
na
Orthophosphate
mg/L
...
0.100
U
0.100
U
0.100
U,M1
0.100
U
na
na
na
Total Organic Carbon
mg/L
...
1.00
na
na
na
na
na
na
Chloride
mg/L
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014 Bedrock Wells Page 47 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW41-GW-1003 MW41-GW-0404 MW41-GW-1004 MW41-GW-0405 MW41-GW-1005 MW41-GW-0406 MW41-GW-0410 MW41-GW-0411
Standard 20-0cl-2003 06-Apr-2004 19-0ct-2004 14-Apr-2005 13-0ct-2005 10-Apr-2006 07-Apr-2010 11-Apr-2011
VOCs
Units
Benzene
Mg/L
5
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.00
U
1.00
U
Toluene
.pg/L
1000
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.0
U
1.00
U
1.00
U
Ethyibenzene
Mg/L
700
1.0
U
1.0
U
1.0
U
1.0
U
0.53
J
1.0
U
1.00
u
1.00
u
Xylenes, Total
M9/L
10000
1.0
U
1.0
U
1.0
U
2.0
U
2.0
U
3.0
U
6.00
u
3.00
u
PAHs
Acenaphthene
Pg/L
914
2.5
U
2.4
ir
2.6
,U
2.3
U
2.5
U
0.13
U
0.100
u
0.100
u
Acenaphthylene
pg/L
362
1.3
U
1.2
U*
1.3
U
1.2
U
1.3
U
0.17
U
• 0.100
u
0.100
u
Anthracene
pg/L
...
0.050
LI-
0.048
U
0.051
U
0.047
U
0.049
u
0.0093
U
0.100
u
0.100
u
Benzo(a)anthracene
ng/L
0.13
0.13
LI
0.12
U
0.13
U
0.12
U
0.13
u
0.019
U
0.100
u
0.100
u
Benzo(a)pyrene
pg/L
0.2
.0.13
U
0.12
U
0.13
U
0.12
U
0.13
u
0.019
U
0.100
u
0.100
u
Benzo(b)fluoranthene
pg/L
0.1
0.050
U
0.048
U
0.051
U
0.047
U
0.049
u
0.037
U
0.100
u
0.100
u
Benzo(ghi)perylene
ug/L
...
0.20
U
0.19.
U
0.20
U
0.19
U
0.20
u
0.032
U
0.100
u
0.100
u
Benzo(k)fluoranthene
pg/L
0.14
0.050
U
0.048
U
0.051
U
0.047
U
0.049
u
0.023
U
0.100
u
0.100
u
Chrysene
pg/L
0.85
0.13
U
0.12
U
0.13
U
0.12
U
0.13
u
0.02
U
0.100
u
0.100
u
Dibenzo(a,h)anthracene
pg/L
0.033
0.30
U
0.29
U
0.31
U
0.28
U
0.29
u
0.033
U
0.0081
U,MDL
0.0170
U.MDL
Fluoranthene
pg/L
...
0.13
U
0.12
U
0.13
U
0.12
U
0.13
u
0.032
U
0.100
U
0.100
U
Fluorene
pg/L
490
0.25
U
0.24
U*
0.26
U
0.23
U
0.25
u
0.029
U
0.100
U
0.100
U
lndeno(1,2,3-cd)pyrene
s-tg/L
0.1
0.13
U
0.12
U
0.13
U
0.12
U
0.13
u
0.038
U
0.100
U
0.100
U
Naphthalene
M9/L
1.1
1.3
U
1.2
u*
1.3
U
1.2
u
1.3
u
0.1
U
0.100
U
0.100
U
Phenanthrene
ng/L
294
0.099
U
0.095
u*
0.10
U
0.093
u
0.098
u
0.015
U •
0.100
U
0.100
U
Pyrene
MQ/L
...
0.25
U
0.24
u
0.26
u
0.23
u
0.25
u
0.036
U
0.100
U
0.100
U
1 -Methylnaphthalene
MQ/L
...
na
na
na
na
na
na
0.100
U
0.100
U
2-Methylnaphthalene
pg/L
61.2
na
na
na
na
na
na
0.100
U
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
0.010
U
0.010
u
0.010
u
0.010
u
0.010
u
0.01
U
na
na
Cyanide, WAD
mg/L
0.2
na
na
na
na
na
na
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.045
0.027
0.053
0.032
0.046
0.08
0.0316
0.0428
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
na
Nitrite
mg/L
...
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
ria
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
0.028
0.027
0.027
0.027
0.026
0.0266
na
na
. Iron, Dissolved
mg/L
...
1.3
1.2
1.2
1.0
1.3
1.43
na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
...
na-
na
na
na
na
na
na
na
Methane
pg/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
—
na
na
na
na
na
na
na"
na
Total Kjeldahl Nitrogen
mg/L
—
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/-"™,,14 >sk Wells of 53
f ¦ ) ]
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW41-GW-0412 MW41-GW-0413 MW55-GW-1005 MW55-GW-0406 MW55-GW-1006 MW55-GW-0407 MW55-GW-1007 MW55-GW-0408
Standard 10-Apr-2012 09-Apr-2013 13-0ct-2005 11-Apr-2006 11-0ct-2006 17-Apr-2007 10-0ct-2007 15-Apr-2008
VOCs
Units
Benzene
M9/L
5
1.00
U
0.500
U
1.0
U
1
U
1
U
1
U
1
U
1
U.L1
Toluene
mq/l
1000
1.00
U
1.00
U
1.0
U
1
U
1
U
1
U
1
U
1
U,L1
Ethylbenzene
ng/L
700
1.00
U
1.00
U
1.0
U
1
U
1
U
1
u
1
U
1
U,L1
Xylenes, Total
Mg/L
10000
3.00
U
3.00
U
2.0
U
3
U
3
U
3
u
3
U
3
U,L1
PAHs
Acenaphthene
"E
r2
914
0.100
U
0.100
U
2.4
U
0.13
U
0.049
U
0.049
u
0.0557
U
0.049
U
Acenaphthylene
Mg/L
362
0.100
U
0.100
U
1.2
U
0.17
U
0.085
U
0.085
u
0.0966
U
0.085
u
Anthracene
...
0.100
U
0.100
U
0.047
U
0.0093
U
0.01
U
0.01
u
0.0114
u
0.01
u
Benzo(a)anthracene
Mg/L
0.13
0.100
U
0.100
U
0.12
U
0.019
U
0.003
U
0.003
U
0.00341
u
0.003
u
Benzo(a)pyrene
Mg/L
0.2
0.100
U
0.100
U
0.12
U
0.019
U
0.032
U
0.032
u
0.0364
u
0.032
u
Benzo(b)fluoranthene
pg/L
0.1
0.100
U
0.100
U
0.047
U
0.037
U
0.013
U
0.013
u
0.0148
u
0.013
u
Benzo(ghi)perylene
Mg/L
—
0.100
U
0.100
U
0.19
U
0.032
U
0.009
U
0.009
u
0.0102
u
0.009
u
Benzo(k)fluoranthene
(jg/L
0.14
0.100
U
0.100
U
0.047
U
0.023
U
0.015
u
0.015
u
0.017
u
0.015
u
Chrysene
0.85
0.100
U
0.100
U
0.12
U
0.02
U
0.005
u
0.005
u
0.00568
u
0.005
u
Dibenzo(a,h)anthracene
M9/L
0.033
0.0170
U,MDL
0.0172
U
0.28
U
0.033
U
0.01
u
0.01
u
0.0114
u
0.01
u
Fluoranthene
ng/L
...
0.100
U
0.100
U
0.12
U
0.032
U
0.01
u
0.01
u
0.0114
u
0.01
u
Fluorene
Mg/L
490
0.100
U
0.100
U
0.24
U
0.029
U
0.01
u
0.01
u
0.0114
u
0.01
u
lndeno(1,2,3-cd)pyrene
MQ/L
0.1
0.100
U
0.100
U
0.12
U
0.038
U
0.007
u
0.007
u
0.00795
u
0.007
u
Naphthalene
MQ/L
1.1
0.100
U
0.100
U
1.2
U
0.1
U
0.248
0.837
0.538
0.054
u
Phenanthrene
Mg/L
294
0.100
U
0.100
U
0.094
U
0.015
U
0.0262
J
0.007
u
0.0757
J
0.007
u
Pyrene
MQ/L
...
0.100
U
0.100
U
0.24
U
0.036
U
0.019
u
0.019
u
0.0504
J
0.019
u
1 -Methylnaphthalene
Mg/L
...
0.100
U
0.100
U
na
na
na
na
na
na
2-Methyl naphthalene
^g/L
61.2
0.100
U
0.100
U
na
na
0.052
(J
0.1
J
0.0591
u
0.052
u
Inoraanics
Cyanide, Total
mg/L
...
na
na
0.011
0.01
U
0.01
u
0.01
u
0.01
u
0.01
u
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
na
na
na
na
na
na
Manganese, Total
mg/L
0.775
0.193
0.204
0.046
0.0249
na
na
na
na
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
na
na
na
na
na
na
Nitrite
mg/L
—
na
na
na
na
na
na
na
na
Ammonia
mg/L
...
na
na
na
na
na
na
na
na
Manganese, Dissolved
mg/L
...
na
na
0.045
0.017
na
na
na
na
Iron, Dissolved
mg/L
—
na
na
0.042
B
0.1
U
na
na
¦ na
na
Sulfate
mg/L
...
na
na
na
na
na
na
na
na
Sulfide
mg/L
...
na
na
na
na
na
na
na
na
Methane
pg/L
...
na
na
na
na
na
na
na
na
Alkalinity, Total
mg/L
...
na
na
na
na
na
na
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
na
na
na
na
na
na
Orthophosphate
mg/L
...
na
na
na
na
na
na
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
na
icgp gw 2013-10.xlsx
2/11/2014
Bedrock Wells
Page 49 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance
Standard
MW55-GW-0410
08-Apr-2010
MW55-GW-1010
05-0ct-2010
MW55-GW-0411
12-Apr-2011
MW55-GW-1011
25-Oct-2011
MW55-GW-0412
11-Apr-2012
MW55-GW-1012
09-0ct-2012
MW55-GW-0413
10-Apr-2013
DV
MW55-GW-
22-Oct-2C
VOCs
Units
Benzene
[jg/L
5
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
0.500
U
UJ
0.500
U
Toluene
pg/L
1000
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethyl benzene
Mg/L
700
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Xylenes, Total
pg/L
10000
6.00
U
3.00
U
3.00
U
3.00
U
3.00
U
3.00
U
3.00
U
3.00
U
PAHs
Acenaphthene
|ig/L
914
0.100
U
0.202
0.422
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Acenaphthylene
Mg/L
362
0.100
U
0.100
U
0.608
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Anthracene
|jg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)anthracene
Mg/L
0.13
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(a)pyrene
pg/L
0.2
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(b)fluoranthene
ng/L
0.1
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(ghi)perylene
ng/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Benzo(k)fluoranthene
Mg/L
0.14
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100.
U
Chrysene
pg/L
0.85
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Dibenzo(a,h)anthracene
pg/L
0.033
0.100
U
0.00810
U,MDL
0.170
U.MDL
0.0170
U.MDL
0.0170
U,MDL
0.0130
U,MDL
0.0173
U
0.0173
U
Fluoranthene
pg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Fluorene
ug/L
490
0.0380
J,MDL
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
lndeno(1,2,3-cd)pyrene
M9/t-
0.1
¦ 0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Naphthalene
ug/L
1.1
0.100
U
0.672
1.20
0.100
U
0.172
0.100
U
0.113
J+
0.100
U
Phenanthrene
i-tg/t-
294
0.100
U
0.100
U
0.195
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Pyrene
pg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
1 -Methylnaphthalene
ug/L
...
0.100
U
0.704
2.91
U
0.100
U
0.100
U
0.100
U
0.131
J+
0.100
U
2-Methylnaphthalene
ug/L
61.2
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.0187
0.0100
U
0.0135
0.0103
0.0214
0.0128
0.0107
0.0100
U
Natural Attenuation Parameters
Nitrate
mg/L
...
0.10
U
0.10
U
0.10
U
0.10
U
0.100
U
0.100
u
0.100
U
na
Nitrite
mg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
u
0.100
U
na
Ammonia
mg/L
...
1.43
1.41
1.49
1.44
1.48
1.41
1.54
na
Manganese, Dissolved
mg/L
...
0.0184
0.0100
U
0.0129
0.0100
U
0.0130
R
0.0112
0.0100
U
na
Iron, Dissolved
mg/L
...
0.380
0.234
0.127
0.100
U
0.103
0.108
0.100
U
na
Sulfate
mg/L
...
89.5
36.2
89.6
86.7
90.3
94.8
87.2
na
Sulfide
mg/L
...
5.00
U
5.00
U
16
10
U
10
U
10
u
10.0
U
na
Methane
pg/L
...
26.0
U
26.0
U
1-.5
2.1
1.9
3.1
2.58
na
Alkalinity, Total
mg/L
...
432
402
393
390
385
375
410
na
Total Kjeldahl Nitrogen
mg/L
...
1.77
1.54
1.83
1.92
1.58
1.70
1.79
na
Orthophosphate
mg/L
...
0.100
U
0.100
U
0.100
U
0.100
U
0.100
U
0.100
u
0.100
U
na
Total Organic Carbon
mg/L
...
1.00
U
1.00
U
na
1.00
U
na
na
na
na
Chloride
mg/L
...
2.00
U,RL1
2.00
U,RL1 '
- na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2h~»wv|4 Bp^ck Wells Pp~~-50 of 53
/ > < \ ,
I
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW56-GW-1011 MW56-GW-1011 MW56-GW-0412 MW56-GW-1012 MW56-GW-0413 MW56-GW-1013 MW57-GW-1011
Standard 27-Jul-2011 24-Oct-2011 10-Apr-2012 09-0ct-2012 09-Apr-2013 22-Oct-2013 27-Jul-2011
DV DV DV DV DV
VOCs
Units
Benzene
Pg/L
5
1.00
U
1.00
U
1.00
U
1.00
U
0.500
U
UJ
0.500
U
1.00
u
Toluene
pg/L
1000
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
UJ
1.00
U
1.00
u
Ethylbenzene
Pg/L
700
1.00
u
1.00
U
1.00
U
1.00
U
1.00
U
UJ
1.00
U
1.00
u
Xylenes, Total
pg/L
10000
3.00
u
3.00
U
3.00
U
3.00
U
3.00
U
UJ
3.00
U
3.00
u
PAHs
Acenaphthene
ng/L
914
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Acena.phthylene
ug/L
362
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Anthracene
ug/L
...
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Benzo(a)anthracene
pg/L
0.13
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Benzo(a)pyrene
pg/L
0.2
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Benzo(b)fluoranthene
pg/L
0.1
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
u
UJ
0.100
U
0.100
U
0.100
u
Benzo(ghi)perylene
pg/L
...
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Benzo(k)fluoranthene
pg/L
0.14
0.100
u
. 0.100
U
UJ
0.100
U
UJ
0.100
u
UJ
0.100
U
0.100
U
0.100
u
Chrysene
pg/L
0.85
0.100
u
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Diben^o(a,h)anthracene
pg/L
0.033
0.0170
U.MDL
0.0170
U,MDL
UJ
0.0170
U,MDL
UJ
0.0130
U.MDL
UJ
0.0172
U
0.0173
U
0.0170
U.MDL
Fluoranthene
ng/L
...
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
u
Fluorene
pg/L
490
0.100
U
0.100
U-
UJ
. 0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
0.100
U
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
u
0.100
U
Naphthalene
pg/L
1.1
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
u
0.287
Phenanthrene
pg/L
294
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
u
0.100
U
Pyrene
pg/L
...
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
u
0.100
U
1 -Methylnaphthalene
pg/L
...
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
u
0.105
2-Methylnaphthalene
pg/L
61.2
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
u
0.112
Inoraanics
Cyanide, Total
mg/L
...
na
na
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U
0.0100
U
UJ
0.0100
U
0.0100
U
0.0100
U
0.0100
u
0.0100
U
Manganese, Total
mg/L
0.775
0.130
0.123
0.0673
J+
0.0875
0.0792
0.0713
0.605
Natural Attenuation Parameters
Nitrate
mg/L
...
na
na
0.100
U
0.100
U
0.100
U
na
na
Nitrite
mg/L
...
na
na
0.100
U
0.100
U
0.100
U
na
na
Ammonia
mg/L
...
na
na
1.1
1.04-
1.13
na
na
Manganese, Dissolved
mg/L
...
na
na
0.0821
0.0840
0.0764
na
na
Iron, Dissolved
mg/L
...
na
na
1.4
1.70
1.670
na
na
Sulfate
mg/L
...
na
na
66.9
67.4
60.5
na
na
Sulfide
mg/L
...
na
na
10
U
10
U
10.0
U
na
na
Methane
pg/L
...
na
na
11
10
9.84
na
na
Alkalinity, Total
mg/L
...
na
na
370
370
410
na
na
Total Kjeldahl Nitrogen
mg/L
...
na
na
1.33
1.22
1.11
na
na
Orthophosphate
mg/L
...
na
na
0.100
U
0.100 .
U
0.100
U
na
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
na
na
Chloride
mg/L
...
na
na
na
na
na
na
na
icgp_gw_2013-10.xlsx
2/11/2014
Bedrock Wells
Page 51 of 53
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Performance MW57-GW-1011 MW57-GW-0412 MW57-GW-1012 MW57-GW-0413 MW57-GW-1013
Standard 24-Oct-2011 10-Apr-2012 09-0ct-2012 09-Apr-2013 22-Oct-2013
DV DV DV
VOCs
Units
Benzene
pg/L
5
1.00
U
1.00
U
1.00
U
0.500
U
0.500
U
Toluene
pg/L
1000
1.00
U
1.00
U
1.00
U
1.00
U
1.00
U
Ethylbenzene
ng/L
700
1.00
u
1.00
u
1.00
U
1.00
U
1.00
U
Xylenes, Total
Mg/L
10000
3.00
u
3.00
u
3.00
U
3.00
U
3.00
U
PAHs
Acenaphthene
pg/L
914
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Acenaphthylene
pg/L
362
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Anthracene
pg/L
...
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Benzo(a)anthracene
pg/L
0.13
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Benzo(a)pyrene
|jg/L
0.2
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Benzo(b)fluoranthene
pg/L
0.1
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Benzo(ghi)perylene
pg/L
...
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Benzo(k)fluoranthene
pg/L
0.14
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Chrysene
fjg/L
0.85
0.100
u
0.100
u
UJ
0.100
U
UJ
0.100
U
0.100
U
Dibenzo(a,h)anthracene
Mg/L
0.033
0.0170
U.MDL
0.0170
U,MDL
UJ
0.0130
U.MDL
UJ
0.0173
U
0.0173
U
Fluoranthene
pg/L
...
0.100
U
0.100-
U
UJ
0.100
U
UJ
0.100
U
0.100
U
Fluorene
pg/L
490
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
lndeno(1,2,3-cd)pyrene
pg/L
0.1
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
Naphthalene
pg/L
1.1
0.126
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
Phenanthrene
ng/L
294
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
Pyrene
Hg/L
...
¦ 0.100
U
0.100
U
UJ
0.100
U
UJ ¦
0.100
U
0.100
U
1-Methylnaphthalene
pg/L
...
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
2-Methylnaphthalene
pg/L
61.2
0.100
U
0.100
U
UJ
0.100
U
UJ
0.100
U
0.100
U
Inoraanics
Cyanide, Total.
mg/L
...
na
na
na
na
na
Cyanide, WAD
mg/L
0.2
0.0100
U UJ.
0.0100
U
0.0100
U
0.0100
U
0.0100
U
Manganese, Total
mg/L
0.775
0.317
0.18
0.246
0.216
0.225
Natural Attenuation Parameters
Nitrate
mg/L
...
na
0.1
u
0.100
U
0.100
U
na
Nitrite
mg/L
...
na
0.1
u
0.100
U
0.100
U
na
Ammonia
mg/L
na
1.5
1.40
1.55
na
Manganese, Dissolved
mg/L
...
na
0.228
0.198
0.195
na
Iron, Dissolved
mg/L
...
na
1.28
1.37
1.520
na
Sulfate
mg/L
...
na
120
132
120
na
Sulfide
mg/L
...
na
10 ¦
u
10
U
28.3
na '
Methane
Mg/L
...
na
10
11
12.8
na
Alkalinity, Total
mg/L
...
na
355
360
376
na
Total Kjeldahl Nitrogen
mg/L
...
na
1.78
1.79
1.72
na
Orthophosphate
mg/L
...
na
0.1
U-
0.100
U
0.100
U
na
Total Organic Carbon
mg/L
...
na
na
na
na
na
Chloride
mg/L
...
na
•' na
na
na
na
icgp_gw_2013-10.xlsx
Bf—'k Wells P,~ "~»52 of 53
^ ( ') '' \
-------
Iowa City, Iowa Former Manufactured Gas Plant Site
MidAmerican Energy Company
Groundwater Analytical Results
Notes:
na = not analyzed.
ns = not sampled, insufficient water.
nc = RPD not calculated.
RPD = Relative Percent Difference.
mg/L = milligrams per liter.
|jg/L = microgram per liter.
Laboratory Qualifiers
* = Batch QC exceeds upper or lower control limits.
8 = Analyte was detected in the associated Method Blank.
B1 = Analyte was detected in the associated Method Blank. Analyte concentration in the sample is greater than 10x the concentration found in the Method Blank.
C9 = Calibration Verification recovery was outside the method control limits for this analyte. The LCS for this analyte met CCV acceptance criteria, and was used to validate the batch.
CN5 = Sample found to contain Sulfide. The sulfide was treated and removed prior to distillation.
ET = Matrix interference in sample is causing an endpoint timeout.
H = Sample analysis performed past method-specified holding time.
H2 = Initial analysis within holding time. Reanalysis verification was past holding time.
J = Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Ja = Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
L1 = Laboratory Control Sample and/or Laboratory Control Sample Duplicate recovery was outside control limits.
M1 = The MS and/or MSD were outside control limits.
MDL = Results calculated/entered to the method detection limit (MDL).
MHA = Due to high levels of analyte in the sample, the MS/MSD calculation does not provide useful spike recovery information.
P2 = Sample adjusted to method prescribed pH range prior to analysis.
R = Sample duplicate RPD exceeded the laboratory control limit.
RL1 = Reporting limit raised due to sample matrix effects.
S3 = Post digestion spike is out of acceptance limits for this analyte.
U = Indicates the analyte was analyzed for but not detected.
U* = Indicates the analyte was analyzed for but not detected. Batch QC exceeds the upper or lower control limits.
Ua = Analyte was not detected at or above the stated limit. Concentration is below the method reporting limit.
Z6 = Surrogate recovery was outside control limits.
ZX = Due to sample matrix effects, the surrogate recovery was outside the control limits.
Data Validation (DV) Qualifiers
B = The analyte was found in an associated blank, as well as in the sample at a concentration greater than 5 times (or 10 times for common laboratory contaminants) that detected in an associated blank.
J = The analyte was positively identified; the quantitation is an estimation.
J+ = The analyte was positively identified; the quantitation is an estimation with a potential high bias.
J- = The analyte was positively identified; the quantitation is an estimation with a potential low bias.
UB = The analyte is considered not detected; the concentration in the sample was less than 5 times (or 10 times for common laboratory contaminants) that detected in an associated blank.
UJ = The analyte was analyzed for, but not detected. Due to a QC deficiency identified during data validation, the value reported may not accurately reflect the sample quantitation limit.
Data collected as part of the Remedial Action qualified in accordance with the January 2009 Quality Assurance Project Plan.
icgp_gw_2013-10.xlsx
2/11/2014
Notes
Page 53 of 53
-------
ATTACHMENT 3
Sediment Sampling Results
-------
/*—\
TABLE 4-1
RALSTON CREEK - SEDIMENT ANALYTICAL RESULTS
MIDAMERICAN ENERGY COMPANY
FORMER MANUFACTURED GAS PLANT SITE - IOWA CITY, IOWA
RC04
RC04
RC04
RC04
RC04
RC04
RC04-RS
RC-04-RS DUP
RC04-SD-0410
RC04-SD-1010
DP01-SD-1010
RC04-SD-1111
Performance
9/17/2002
9/17/2002
4/8/2010
10/5/2010
10/5/2010
11/11/2011
Units
Standard
0-0.5 feet
0-0.5 feet
0-0.5 feet
0-0.5 feet
0-0.5 feet
0-0.5 feet
DV
Polynuclear Aromatic Hydrocarbons (PAHs)
Acenaphthene
mg/kg
—
0.021
<0.2
U
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1
Acenaphthylene
mg/kg
...
<0.04
U
<0.39
U
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1.M1
UJ
Anthracene
mg/kg
0.845
0.0071
<0.04
U
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U,RL1,M1
UJ
Benzo(a)anthracene
mg/kg
1.050
0.013
J
0.052
J
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1.M1
UJ
Benzo(a)pyrene
mg/kg
1.450
. 0.059
J
0.08
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1.M1
UJ
Benzo(b)fluoranthene
mg/kg
...
0.068
0.087
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
0.179
RL1.M1
J+.J-.J
Benzo(ghi)perylene
mg/kg
_
0.029
0.037
J
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1.M1
UJ
Benzo(k)fluoranthene
mg/kg
...
0.011
J
0.029
J
<0.353
U.RL1
<0.117
U,RL1
<0.117
U.RL1
<0.171
U.RL1
UJ
Chrysene
mg/kg
1.290
<0.0041
U
0.066
<0.353
U.RL1
<0.117
U,RL1
<0.117
U.RL1
<0.171
U.RL1.M1
UJ
Dibenzo(a,h)anthracene
mg/kg
...
0.017
<0.12
U
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1
UJ
Fluoranthene
mg/kg
2.230
0.041
J
0.21
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
0.291
RL1.M1
J+.J-.J
Fluorene
mg/kg
0.536
<0.018
U
<0.180
U
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1 ,M1
lndeno(1,2,3-cd)pyrene
mg/kg
...
0.015
0.014
J
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1.M1
UJ
Naphthalene
mg/kg
0.561
0.20
<0.59
U
11.3
RL1
0.259
RL1
0.161
RL1
<0.171
U.RL1
Phenathrene
mg/kg
1.170
0.056
0.14
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
<0.171
U.RL1.M1
UJ
Pyrene
mg/kg
1.520
0.059
0.14
<0.353
U.RL1
<0.117
U.RL1
<0.117
U.RL1
0.227
RL1.M1
J+.J-.J
2-Methylnaphthalene
mg/kg
na
na
0.363
RL1
0.363
RL1
0.363
RL1
<0.171
U.RL1
Total PAHs
mg/kg
22.8
0.435
0.687
11.300
0.259
0.161
0.518
Page 1 of 4
-------
TABLE 4-1
RALSTON CREEK - SEDIMENT ANALYTICAL RESULTS
MIDAMERICAN ENERGY COMPANY
FORMER MANUFACTURED GAS PLANT SITE - IOWA CITY, IOWA
RC04 RC04 RC04 RC05 RC05 RC05
DP01-SD-1111 RC04-SD-1112 RC04-SD-1013 RC05-RS RC05-SD-0410 DP01-SD-0410
Performance 11/11/2011 11/8/2012 10/24/2013 9/17/2002 4/8/2010 4/8/2010
Units Standard 0-0.5 feet 0-0.5 feet 0-0.5 feet DV 0-0.5 feet 0-0.5 feet DV 0-0.5 feet
Polynuclear Aromatic Hydrocarbons (PAHs)
Acenaphthene
mg/kg
—
<0.586
U.RL1
<0.516
U.RL1
<0.130
U
0.93
<0.128
U.RL1.M1
<0.135
U.RL1
Acenaphthylene
mg/kg
...
<0.586
U,RL1
<0.516
U.RL1
<0.130
U
<0.43
U
<0.128
U.RL1
<0.135
U.RL1
Anthracene
mg/kg
0.845
<0.586
U.RL1 ,M1
<0.516
U.RL1
<0.130
U
0.10
<0.128
U.RL1
<0.135
U.RL1
Benzo(a)anthracene
mg/kg
1.050
<0.586
U,RL1
<0.516
U.RL1
<0.130
U
0.18
<0.128
U.RL1
0.221
RL1
Benzo(a)pyrene
mg/kg
1.450
<0.586
U,RL1
<0.516
U.RL1
<0.130
U
0.19
<0.128
U.RL1
0.222
RL1
Benzo(b)fluoranthene
mg/kg
—
<0.58.6
U.RL1 ,M1
<0.516
U.RL1
<0.130
U
0.25
<0.128
U.RL1
0.271
RL1
Benzo(ghi)perylene
mg/kg
...
<0.586
U,RL1
<0.516
U.RL1
<0.130
U
0.055
J
<0.128
U.RL1
0.152
RL1
Benzo(k)fluoranthene
mg/kg
...
<0.586
U.RL1
<0.516
U.RL1
<0.130
U
0.088
<0.128
U.RL1
<0.135
U.RL1
Chrysene
mg/kg
1.290
<0.586
U.RL1
<0.516
U.RL1
<0.130
U
0.11
<0.128
U.RL1
0.196
RL1
Dibenzo(a,h)anthracene
mg/kg
...
<0.586
U.RL1
<0.516
U.RL1
<0.130
U
<0.13
U
<0.128
U.RL1
<0.135
U.RL1
Fluoranthene
mg/kg
2.230
<0.586
U.RL1.M1
<0.516
U.RL1
<0.130
U
0.35
0.176
RL1.M1 J+
0.544
RL1
Fluorene
mg/kg
0.536
<0.586
U.RL1
<0.516
U,RL1
<0.130
U
0.20
<0.128
U.RL1
<0.135
U,RL1
lndeno(1,2,3-cd)pyrene
mg/kg
...
<0.586
U.RL1
<0.516
U.RL1
<0.130
U
0.10
<0.128
U.RL1
<0.135
U.RL1
Naphthalene
mg/kg
0.561
<0.586
U.RL1
<0.516
U.RL1
0.421
J,J+
0.74
0.403
RL1.L1.M1 J-
0.233
RL1.L1
Phenathrene
mg/kg
1.170
<0.586
U,RL1
<0.516
U,RL1
<0.130
U
0.40
<0.128
U.RL1
0.236
RL1
Pyrene
mg/kg
1.520
<0.586
U.RL1.M1
<0.516
U.RL1
<0.130
U
0.38
0.136
RL1
0.407
RL1
2-Methylnaphthalene
mg/kg
...
<0.586
U.RL1
<0.516
U,RL1
<0.130
U
na
<0.128
U.RL1
<0.135
U,RL1
Total PAHs
mg/kg
22.8
0.000
0.000
0.421
2.650
0.715
2.059
-------
TABLE 4-1
RALSTON CREEK - SEDIMENT ANALYTICAL RESULTS
MIDAMERICAN ENERGY COMPANY
FORMER MANUFACTURED GAS PLANT SITE - IOWA CITY, IOWA
RC05 RC05 RC05 RC05 RC05 RC05
RC05-SD-1010 RC05-SD-1111 RC05-SD-1112 DP01-SD-1112 RC05-SD-1013 DP01-SD-1013
Performance 10/5/2010 11/11/2011 11/8/2012 11/8/2012 10/24/2013 10/24/2013
Units Standard 0-0.5 feet 0-0.5 feet DV 0-0.5 feet 0-0.5 feet 0-0.5 feet 0-0.5 feet
Polynuclear Aromatic Hydrocarbons (PAHs)
Acenaphthene
mg/kg
—
0.199
RL1.M1
<0.552
U.RL1
<0.580
U.RL1
0.663
RL1
<0.116
U
<0.116
U
Acenaphthylene
mg/kg
...
<0.117
U.RL1
<0.552
U.RL1
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Anthracene
mg/kg
0.845
0.118
RL1.M1
0.593
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Benzo(a)anthracene
mg/kg
1.050
<0.117
U.RL1.M1
1.60
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Benzo(a)pyrene
mg/kg
1.450
<0.117
U.RL1.M1
1.20
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Benzo(b)fluoranthene
mg/kg
<0.117
U.RL1 ,M1
1.70
RL1
J+
<0.580
U;RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Benzo(ghi)perylene
mg/kg
—
<0.117
U.RL1 ,M1
0.653
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Benzo(k)fluoranthene
mg/kg
...
<0.117
U.RL1
<0.552
U.RL1
<0.580
U,RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Chrysene
mg/kg
1.290
<0.117
U.RL1
1.38
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Dibenzo(a,h)anthracene
mg/kg
...
<0.117
U.RL1
<0.552
U.RL1
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Fluoranthene
mg/kg .
2.230
0.125
RL1.M1
3.14
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Fluorene
mg/kg
0.536
<0.117
U.RL1.M1
<0.552
U.RL1
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
lndeno(1,2,3-cd)pyrene
mg/kg
...
<0.117
U.RL1.M1
0.572
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Naphthalene
mg/kg
0.561
0.894
RL1.M1
1.57
RL1:
J+
3.94
RL1
4.47
RL1
0.204
0.277
Phenathrene
mg/kg
1.170
0.39
RL1.M1
2.37
RL1
J+
<0.580
U.RL1
<0.560 ¦
U.RL1
<0.116
u
<0.116
U
Pyrene
mg/kg
1.520
<0.117
U.RL1
2.26
RL1
J+
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
2-Methylnaphthalene
mg/kg
...
<0.117
U.RL1.M1
<0.552
U.RL1
<0.580
U.RL1
<0.560
U.RL1
<0.116
u
<0.116
U
Total PAHs
mg/kg
22.8
1.527
14.113
3.94
4.47
0.204
0.277
Page 3 of 4
-------
TABLE 4-1
RALSTON CREEK - SEDIMENT ANALYTICAL RESULTS
MIDAMERICAN ENERGY COMPANY
FORMER MANUFACTURED GAS PLANT SITE - IOWA CITY, IOWA
Notes:
< = Less than.
mg/kg = Milligram(s) per kilogram,
na = Constituent not analyzed.
Concentrations above Performance Standard in bold font.
PAH = Polynuclear aromatic hydrocarbon.
Laboratory Qualifiers
U = Compound not detected above reporting limit.
J = Estimated value below reporting limit.
L1 = Laboratory Control Sample and/or Laboratory Control Sample Duplicate recovery was outside control limits.
M1 = The matrix spike (MS) and/or matrix spike duplicate (MSD) were outside control limits.
RL1 = Reporting limit raised due to sample matrix effects.
Data Validation (DV) Qualifiers
J = The analyte was positively identified; the quantitation is an estimation.
J+ = The analyte was positively identified; the quantitation is an estimation with a potential high bias.
J- = The analyte was positively identified; the quantitation is an estimation with a potential low bias.
UJ = The analyte was analyzed for, but not detected. Due to a quality control (QC) deficiency identified during data validation, the value reported may not accurately reflect the sample quantitation
-------
Attachment 4
Groundwater Contaminants of Concern Trend Analysis Summary
-------
TABLE 3-2
STATISTICAL SUMMARY
MIDAMERICAN ENERGY COMPANY]
FORMER MANUFACTURED GAS PLANT SITE - IOWA CITY, IOWA
Performance Standard 5 1000 700 10000
914 362 0.13
0.14 0.85 0.033 490 0.1 1.1 294.0 61.2
775 0.200
Compliance Wells
MW-7 UCL <1
Trend NT
MW-29
MW-33
MW-35
MW-41
MW-56
MW-57
UCL <1
Trend NT
UCL <1
Trend NT
UCL <1
Trend NT
UCL <1
T rend NT
UCL <1
Trend NT
UCL
MW-12
MW-13
MW-16
MW-18
MW-19
MW-20
MW-23
MW-25
MW-31
MW-36
MW-37
MW-55
<1
Trend NT
7/ Zone Wells
MW-3 Trend D90
Trend NT
Trend D90
Trend NT
Trend NT
Trend D90
Trend 190
Trend NT
T rend 190
Trend 190
Trend 190
Trend 190
Trend NT
<1
NT
<1
NT
<1
NT
<1
NT
<1
NT
<1
NT
<1
NT
NT
NT
D90
NT
NT
NT
NT
NT
NT
190
NT
NT
NT
<1
NT
<1
NT
<1
NT
<1
NT
<1
NT
<1
NT
<1
NT
190
NT
D90
NT
NT
NT
NT
NT
NT
190
NT
NT
NT
<3
NT
<3
NT
<3
NT
<3
NT
<3
NT
<3
NT
<3
NT
NT
NT
D90
NT
NT
NT
NT
D90
NT
190
NT
NT
NT
<0.1 <0.1
NT NT
<0.1
NT
<0.1
NT
<0.1 <0.1
NT NT
0.149 <0.1
NT NT
<0.1 <0.1
NT NT
<0.1 <0.1
NT NT
<0.1 <0.1
NT NT
D90 190
NT NT
D90 D90
NT NT
NT NT
D90 D90
D90 D90
D90 D90
NT NT
NT NT
190 190
190 190
NT NT
<0.1
NT
<0.1
NT
<0.1
m
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
NT
NT
D90
NT
NT
NT
D90
NT
NT
NT
D90
190
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1 <0.017
NT NT
<0.1
NT
<0.1 <0.1 <0.017 <0.1
NT NT . NT NT
<0.1 <0.1 <0.017 <0.1
NT NT NT NT
NT NT
NT NT
D90 NT
190 190
NT NT
NT NT
NT NT
NT NT
NT NT
D90 D90
NT D90
NT NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1 <0.1
NT NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1 <0.1 <0.017 0.077 <0.1 0.495 0.055 0.092
NT NT NT NT NT 190 NT NT
<0.1
NT
<0.1
NT
<0.1
NT
<0.1 <0.017 <0.1
NT NT NT
<0.1 <0.017
NT NT
<0.1
NT
<0.1 <0.017 <0.1
NT NT NT
<0.1
NT
<0.1
NT
<0.1
NT
NT NT
NT NT
NT D90
190 190
NT NT
NT NT
NT NT
NT NT
NT NT
D90 D90
NT D90
NT NT
NT NT NT NT
NT
NT
NT
190
NT
NT
NT
NT
NT
D90
NT
NT
NT
NT NT
NT NT
D90 D90
D90 190
NT NT
D90 NT
D90 NT
D90 NT
D90 NT
NT D90
NT NT
190 NY
NT NT
<0.1
NT
<0.1
NT
0.215
D90
D90
| NT
D90
NT
190
D90
NT
D90
NT
NT
NT
190
NT
<0.1
NT
<0.1
NT
<0.1
NT
NT
NT
D90
D90
190
D90
NT
NT
NT
NT
D90
NT
NT
<0.1
NT
<0.1
NT
<0.1
NT
D90
NT
D90
D90
NT
D90
NT
NT
D90
190
NT
NT
NT
8764
D90
134 <0.01
D90 NT
426
D90
535 <0.01
190 NT
181
NT
115
D90
427
NT
D90
NT
D90
NT
D90
D90
D90
NT
D90
D90
NT
NT
D90
Notes:
NT = No statistically significant trend at greater than or equal to 90-percent confidence level.
D90 ss Decreasing trend at greater than or equal to 90-percent confidence level.
I90 - Increasing trend at greater than or equal to 90-percent confidence level.
All concentration units in micrograms per liter except for cyanide, which is in milligrams per liter.
Statistical summary based on samples collected through October 2013.
UCL = 95 Percent Upper Confidence Limit.
Calculated UCLs that exceed the respective Performance Standard and increasing trends are shown in red text.
PAHs - Polynuclear aromatic hydrocarbons.
Tl = Technical Impractibility.
VOCs = Volatile orga lie compounds.
Page 1 of 1
-------
ATTACHMENT 5
Five-Year Review Inspection Form
-------
Attachment 5
FIVE-YEAR REVIEW INSPECTION FORM
I. SITE INFORMATION
Site name: Iowa City FMGP
Date of inspection: July 7, 2014
Location: Iowa City, Iowa
EPA ID: IAD984591172
Agency, office, or company leading the five-year
review: EPA-Region 7
Weather/temperature: Sunny and mid-80s
Remedy Includes: (Check all that apply)
~ Landfill cover/containment
~ Access controls
IHI Institutional controls
~ Groundwater pump and treatment
~ Surface water collection and treatment
IE Other LNAPL recovery and air monitoring
IE! Monitored natural attenuation
~ Groundwater containment
~ Vertical barrier walls
Attachments: ~ Inspection team roster attached
~ Site map attached
II. INTERVIEWS (Check all that apply)
1. O&M site manager Kevin Armstrong
Name
Project Manager. MWH
Title
7-7-14
Date
Interviewed IE at site ~ at office ~ by phone Phone no. 515-251-1023
Problems, suggestions; ~ Report attached
Other interviews (optional) ~ Report attached.
Bryan Clark, Owner, Iowa-Illinois Square apartments-granter access to building crawlspace and discussed on-
going air monitoring in the building
Jennifer Mclvor, Environmental Manager, MidAmerican Energy Company-manages remedial action activities for
all actions except air monitoring in Iowa-Illinois Square
Ron Knoche, City Engineer, City of Iowa City-Engineering office oversees maintenance of Ralston Creek and
directs Public Works to conduct needed maintenance.
Ben Clark, Senior Civil Engineer, City of Iowa City
III. DOCUMENTS & RECORDS VERIFIED (Check all that apply)
1. O&M Documents
IE O&M manual
~ As-built drawings
~ Maintenance logs
Remarks
~ Readily available
~ Readily available
~ Readily available
IE Up to date ~ N/A
~ Up to date IS N/A
~ Up to date IE N/A
-------
2.
Site-Specific Health and Safety Plan IE] Readily available IEI Up to date
~ Contingency plan/emergency response plan ~ Readily available ~ Up to date
Remarks
~ N/A
~ N/A
3.
O&M and OSHA Training Records IEI Readily available Kl Up to date
Remarks
~ N/A
4.
Permits and Service Agreements
~ Air discharge permit ~ Readily available ~ Up to date
~ Effluent discharge ~ Readily available ~ Up to date
~ Waste disposal, POTW ~ Readily available ~ Up to date
~ Other permits ~ Readily available ~ Up to date
Remarks
IE N/A
IE N/A
IE N/A
IE N/A
5.
Groundwater Monitoring Records IEI Readily available IEI Up to date
Remarks
~ N/A
IV. O&M COSTS
1.
O&M Organization
~ State in-house ~ Contractor for State
~ PRP in-house IE Contractor for PRP
~ Federal Facility in-house ~ Contractor for Federal Facility
~ Other MidAmerican contracts with MWH for O&M work. Buildine owner contracts with Stanley
Consultants for O&M work.
2.
O&M Cost Records
IE Readily available IE Up to date
3.
Unanticipated or Unusually High O&M Costs During Review Period
Describe costs and reasons: See description in FYR Report.
V. ACCESS AND INSTITUTIONAL CONTROLS IE Applicable ~ N/A
A.
Fencing
1.
Fencing damaged ~ Location shown on site map ~ Gates secured IE N/A
Remarks
B.
Other Access Restrictions
1.
Signs and other security measures ~ Location shown on site map IE N/A
Remarks
-------
C. Institutional Controls (ICs)
1. Implementation and Enforcement
Site conditions imply ICs not properly implemented ~ Yes 13 No ~ N/A
Site conditions imply ICs not being fully enforced ~ Yes 13 No ~ N/A
Type of monitoring (e.g., self-reporting, drive by) self-reported
Frequency annually
Responsible party/agency City and owner of Iowa-Illinois Square
Reporting is up-to-date IE Yes ~ No ~ N/A
Reports are verified by the lead agency IE Yes ~ No ~ N/A
Specific requirements in deed or decision documents have been met IE Yes ~ No ~ N/A
Violations have been reported ~ Yes ~ No IE N/A
2. Adequacy IE ICs are adequate ~ ICs are inadequate . ~ N/A
Remarks
D. General
1. Vandalism/trespassing ~ Location shown on site map IE No vandalism evident
Remarks
2. Land use changes on site IE N/A
Remarks
3. Land use changes off site ~ N/A
Remarks One adjacent property and one near-bv property have changed from commercial uses to multi-
family dwellings.
VI. GENERAL SITE CONDITIONS
A. Roads ~ Applicable IE N/A
B. Other Site Conditions
Remarks _Apartment building and surroundings in good condition. Creek liner exhibiting some missing
tiles and creek banks have significant woody growth that the city has agreed to remove.
VII. LANDFILL COVERS ~ Applicable IE N/A
VIII. VERTICAL BARRIER WALLS
~ Applicable IE N/A
IX. GROUNDWATER/SURFACE WATER REMEDIES IE Applicable
~ N/A
A. Groundwater Extraction Wells, Pumps, and Pipelines
~ Applicable IE
N/A
B. Surface Water Collection Structures, Pumps, and Pipelines
~ Applicable IE
N/A
C. Treatment System ~ Applicable IE N/A
D. Monitored Natural Attenuation
1. Monitoring Wells (natural attenuation remedy)
IE Properly secured/locked IE Functioning IE Routinely sampled IE Good condition
IE All required wells located ~ Needs Maintenance ~ N/A
Remarks
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X. OTHER REMEDIES
A. LNAPL Recovery-Recovery occurs in designated monitoring wells and removal and replacement of absorbent
socks has been observed in the past but was not observed during this inspection. Monitoring wells were
observed to be in good condition.
B. Air Monitoring and Crawlspace Barrier and Passive Vent Inspection-Air monitoring occurs in the
apartment crawlspace. Crawlspace liner and gravel cover were observed to be in good condition. Vents were
not obstructed.
C. Creek Liner Inspection-Creek liner condition was reviewed with City Engineering staff and MidAmerican
Energy manager and consultant. City was requested to remove woody growth from eastern bank of creek
adjacent to site and consider more aggressive maintenance of the tile liner. Liner is missing in some areas,
most notably along freeze-thaw line.
XI. OVERALL OBSERVATIONS
A. Implementation of the Remedy
Describe issues and observations relating to whether the remedy is effective and functioning as designed.
Begin with a brief statement of what the remedy is to accomplish (i.e., to contain contaminant plume,
minimize infiltration and gas emission, etc.).
All aspects of the remedy appear to be functioning as intended and designed.
B. Adequacy of O&M
Describe issues and observations related to the implementation and scope of O&M procedures. In
particular, discuss their relationship to the current and long-term protectiveness of the remedy.
O&M appears to be effective except for maintenance of vegetation removal on the banks of Ralston
Creek. The city engineering office has committed to improving control of vegetation on the creek bank
near the site. Thev committed to investigating improved maintenance of the tile liner in the creek near
the site.
C. Early Indicators of Potential Remedy Problems
Describe issues and observations such as unexpected changes in the cost or scope of O&M or a high
frequency of unscheduled repairs that suggest that the protectiveness of the remedy may be compromised
in the future.
None
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