-------
To lessen the uncertainty regarding antimony emissions and risks calculated using the
ICR data, information regarding antimony emissions from Chaparral Steel baghouses
and antimony concentrations in EAF dusts is used to re-calculate risks associated with
theoretical human exposures to antimony in sir, water, and soil. These data are
discussed in detail below,
OBJECTIVES
The objective of this addendum is to respond to information regarding antimony
emissions from Chaparral Steel baghouses and antimony concentrations in EAF dusts
submitted by Chaparral Steel after the Midlothian Cumulative Risk Assessment was
finalized. This information slightly changes the conclusions of the report The
overall conclusion of die report—that cancer risks and the potential for noncancer
health effects are below regulatory levels of concern—remain unchanged. The
changes presented do not affect die EPA's decision about whether or not it should
effect some regulatoiy action above and beyond that undertaken by Texas in the State
peroiitting process.
EVALUATION OF NEW DATA CONCERNING CONCENTRATIONS OF
ANTIMONY IN FACILITY EMISSIONS
The best available information was used to estimate antimony emissions. These
emission estimates have been used in recalculating risks. Fugitive emissions were
calculated using total particulate fugitive emissions presented in die 1995 emissions
inventory estimates for the "A" and "B" furnaces, together with the 95% upper
confidence limit (95% UCL) of the arithmetic mean antimony concentration for
Chaparral EAF dust EAF dust antimony data used to calculated the 95% UCL are
presented in Tables 1 and 2. Additional EAF data not used in these calculations are
presented in Table 3J . The data from Tables 1 and 2 were subjected to quality
assurance-quality control procedures. The 95% UCL antimony concentration
calculated from these data was 84.0 ppm. This value was calculated in accordance
* EAF dttJt antimony data pnaentcd in TaMe I ire from six EAF dust samples obtained by Chaparral on January 28 Amfb
Februarys, 19%. The laboratory report! for these analyses are attached to this addendum (Attachment B).
Data presented h Tabic 2 aretheremtti of antimony analyses orthree EAF dust aampica obtained during the mm* etWHcm
aurvty conducted by METCOEnvirociniciital in Januaiy and February 1996. During this survey, one sample of EAF dust was
obtained from each of the "A»* "B," and "C" baghouses. The laboratory report! for these analyses are attached to 1his
addendum (Attachment C).
Table 3 present* the results of analyses perforated in February 1996 of EAF dust digestate iimples that had (Men retained as
part ofCbapml'i ongoing dust analyBa program. At the request of CHapamt, Maxim Technologies, Inc. analyzed archived
dtgerfafc samples for antimony. Since the request came afar initial sampte preparation, routine quality assurance/quality control
(QA/QC) analyse! could not be performed, These data do, however, provide an indication of the general range of antimony
concentration found in Chaparral'j EAF dost, md are coniitent with data used for the 95% UCL calculations.
-3-
-------
with USEPA guidance presented In Supplemental Guidance to RAGS: Calculating die
Concentration Term (USEPA, 1992).
Stack antimony emissions for Baghouses B and C used hi these revised risk
calculations were measured by METCO Environmental (METCO) daring stack
sampling conducted as part of a source emissions survey in January-February 1996.
Baghouse A antimony emissions were calculated using data also obtained by METCO
for inlet flow rates for Baghouse A, Baghouse B stack flow rates, and actual measured
Baghouse B antimony emissions. Stack emission rates for antimony are presented in.
Table 4.
The fugitive, stack, and total (i.e., fugitive + stack) antimony emissions -values 0k
g/sec) obtained in the manner described above are lower than those used by Region
6 in their January 1996 Midlothian Risk Assessment report A comparison of these
emissions values is presented in Table 4.
A more detailed description of the basis for antimony emissions used in this revised
risk assessment are presented below in Attachment A.
REVISED RISK CALCULATIONS FOR ANTIMONY EXPOSURE
Due to the disparity in the measured antimony emissions and antimony concentrations
in EAF dust versus the concentration assumed in the Midlothian Risk Assessment, the
risks posed by antimony exposure have been revised. With the exception of
Chaparral Steel's antimony emissions, all exposure and risk assessment assumptions
from the Midlothian Risk Assessment are used in the revised risk calculations. The
revised risk assessment calculations resulting from the use of more certain estimates
of antimony emissions and EAF concentrations from Chaparral Steel are presented,
in Table 5.
As presented in Table 5, the hazard indices re-calculated using the Chaparral Steef
antimony data are below one. This indicates that the hypothetical adult resident, child
resident, farmer, and fisherman in the SCS and Joe Pool Lake watersheds are not
predicted to experience any adverse health effects as a result of exposure to modeled
concentrations of antimony in air, water, and soil resulting from emissions from
Chaparral Steel, North Texas Cement Company, Texas Industries, and Holnam Texas,
-------
According to the revised calculations presented in this addendum, the conclusions
presented in Section 5 of the Midlothian Risk Assessment are revised to state that
Neither available site data or conservative theoretical models show
that there are cancer risks or the potential for non-cancer health
effects above regulatory levels of concern,
REFERENCE
USEPA (United States Environmental Protection Agency) 1992. Supplemental
Ouidance to RAGS: Calculating die Concentration Tenn. Office of Solid Waste and
Emergency Response. PB92-963373. May 1992,
-s-
-------
Table 1
Antimony Concentrations in Chaparral EAF Dust
Sampled on January 28 - February 8,1996
Antimony (mg/ke)
01A
64.6
02A
68.0
03A
50.5
04A
54.0
05A
50.7
06A
81.9
Table 2
Antimony Concentrations in Chaparral EAF Dust
Sampled by METCO in February, 1996
¦
Bagbouse A
BaghouseB
Baghoroe C
89.2
55.7
107.0
-------
Table 3
Antimony Concentrations in Chaparral Steel EAJF Dust
)btained from Arch
ived Digestate Samples
fl.mnl.Nfi.
59.1
43.2
03A
<20
04A
44.2
05A
39,7
06A
29.9
07A
44,2
08A
34.6
09A
32.7
10A
33.3
11A
<20
12A
33.4
13A
69.8
14A
<20
15A
<20
16A
<20
17A
<20
ISA
<20
19A
<20
20A
<20
21A
<20
22A
35.1
23A
33.5
24A
23.8
25A
30.9
26A
29,2
27A
30.5
28A
43.6
29A
47,5
30A
26.6
31A
43.8
T?A
11 7
.7.
-------
Table 4
Antimony Emissions for Chaparral Steel Company
:-^S^ioriifSoor«f;;vi
Fugitives
0,000061
0.0098
Bagliouse A
0.00021
0.0032
BaghouseB
0.00038
0.0081
BaghouseC
0.00038
0.0086
Total
0.0010
0.030
Tables
Revised Bisk Assessment Calculations for Antimony Exposure*
vf.'JCC^^ ijtOr?" • ; V:-'
Adult Resident
0.02 (3)
0.02 (3)
0.02 (3)
Child Resident
0.039 (6)
0.039 (6)
0.039 m
Farmer
0.02 (3)
0.02 0)
0.026 (4)
Fisherman, SCS
Lake Watershed
0.02 (3)
0.02 {3>
0.02 (3)
Fisherman, Joe Pool
Lake Watershed
0.02 (3)
0.02 (3)
0.02 (3)
* For comparison, the hazard index calculated in the January 31, 1996 USEPA risk
assessment is shown in parenthesis
-8-
-------
Attachment A
Antimony Emissions Calculations for Chaparral Steel Company
-------
Attachment A
Antimony Emissions Calculations for Chaparral Steel Company
1) Total Antimony (Sb) emissions *¦ total fugitive emissions + baghouse (BH) "A"
BH UB" emissions+BH "C" emissions
2) Fhy^jw*0.00021 gm/t
4)
5)
» 0.003 lbs/hr
**0,00038 gm/s
-0.003 lbs/hr
-0.00038 gm/s
6) Total Sh Emissions
- 0.000061 + 0,00021 + 0.00038 + 0.00038 gm/s
= 0.001 gm/i
References
1. Revised Chaparral Steel Emissions Inveotoiy for 1995.
2. METCO Environmental. Source Emissions Survey of Chaparral Stcei Company,
-1-
-------
Texas, Volume 1. Jamauy and Februwy, 1996.
-------
-------
Attachment B
Laboratory Report for Table 1 EAF Dust Analyses
-------
MAXIM
TECHNOLOGIES INC
2S7S Lane Stir Drive P.O. Box 224227 • Dallas, Texas 75222 * 21*-43t-270O
Client Jerry Balbo
Chaparral Steel
300 Ward Read
Midlothian, TX 76065
Client Bo. t54430r
¦eport Wa. D6-02-04T
Report Data 02/2U9& t5:Z»
Project EAF Dust
Phone: 214-299-5212 Fax: ZIW7S-2taZ
Date Sampled 01/28/96 02/08/96
Saaple Type Sol td
Sanpled By Client
Transported by Bob Barrett
P.O. # CT-145-96
Date Received 02/09/%
SPECIAL REPORT FOR ANTIMONY ONLY • REPORT FOR OTHER EAF DUST
METALS RESULTS U1LL F0LL0U WHEN COMPLETED.
Lab No.
D6-02-047-01
06-02-047-02
D6-02-047-03
D6-02-047-04
06-02-047-05
06-02-047-06
Saaole Identification
RC 301625
RC 301769
RC 301646
RC 301727
RC 301762
RC 301673
Our letters and reports are for the exclusive use of the
client to whoa they are addressed and shall not be reproduced
except in full without the approval of the testing laboratory.
The use of our name must receive our prior written approval.
MAXIM
. .lid ¦ I mi I !!!¦ ¦ I- i Til — .1
Reviewed' By r
Uilliaa J (Use, &4>ervii
-------
Order * D6-O2-047
02/21/96 15:21
Client: Chaparral Steel
•test results «t sample
MgtZori
Sample: 01* RC 30162S
PW
Antimony
Cadalua Oxide
Calcium Oxide
Digestfoo of Dust
Iron Oxide
Lead Oxide
Lots en Ignition
MagnetI ui Oxide
Zinc Oxide
Sample: 02A RC 301769
Teat Maw
Antimony
Cadaiua Oxide
Calciua Oxide
Digestion of Dust
Iron Oxide
Lead Oxide
Loss on Ignition
Hagnesiui Oxide
Zinc Oxide
Sample: 03A RC 301646
Teat Mame
Antianny
Cadaiua Oxide
Calciua Oxide
Digestion of Oust
Iron Oxide
Lead Oxide
Loss on Ignition
Magnesiia Oxide
Zinc Oxide
Collected* 01/28/96 tot«—ma S
vtiKtfm oek
Method
Result
units
Limit
Started-
SU844-6010A
64.6
¦a/kg
10'
02/15/96
TAH
SU844-7130
0.0608
X
a.at
02/20/96
TAW
SU846-7140
7.09
X
a. at
I
9
TAN
SU846-3050A
02/14/96
Oat* Cbb
cm
SU846-7380
40.0
X
aura
a&zo/M
TAN
SU846-7420
2.35
X
0.01
02/20/96
TAH
EPA 160.4
3.8
X
0.01
02/17/96
mi
SU846-7460
3.12
X
0.01
02/19/96
TAH
SU846-7950
22.9
X
a.at
02/20/96
tJM
Collected: 02/01/96 Category: S
Detection 2US
iisiM
Result
units
Hilt
SU846-6010A
68.0
ng/lcg
10
02/15/96
TAH
SU846-7130
0.0683
X
0.01
02/20/96
TAN
SU846-7140
5.67
X
0.01
02/13/96
TMt
SU846-3050A
02/14/96
Date Ccai
cm
SU846-7380
34.8
X
O.OT
ozyzom
TAH
SU846-7420
3.21
X
0.01
02/20/96
TW*
EPA 160.4
3.2
X
0.01
02/17/96
KU
SU846-7460
2.89
X
0.01
02/19/96
TAH
SU846-7950
29.4
X
0.01
02/20/96
TMt
Collected: 02/03/96 Category: S
Detection Detr
Method
Result
Uhits
Limit
s^rW
Analyst-
SU846-601QA
50.5
¦O/kg
10
02/15/96
TAH
SU846-7130
0.0625
X
0.01
02/20/96
TAH
SU846-7140
4.94
X
0.01
02/19/96
TAR
SU846-3050A
02/14/96
Date Coai
cm
SU846-7380
31.9
X
O.OT
0Z/20/96
TAR
SU846-7420
2.44
X
0.01
02/20/96
TAH
EPA 160.4
3.8
X
0.01
02/17/96
HOI
SU846-7460
2.71
X
0.01
02/19/96
TAR
SU846-7950
32.4
X
0.01
02/20/96
TAH
-------
order « 06-02-047
02/21/96 15:21
Ctfcnt: Chaparral Steel
Test HESJirS BY SAMPLE
¦DllrfS
Staple: 04A RC 301727
Collects*- 88/04/96
Cttagori
it r
TWt JBS
Method
Result Chits
LlalC
Analyst-
Antlaony
SU846-«10A
54.0 «g/k|
to
02/15/96
m
Cadalua Qxfdt
SU846*7!30
0.0682 X
0.0t
02/20/96
TW
Calclui Oxide
SU846-7140
4.10 X
OJIt
02/19/96
nm
Digestion of Dust
SU846-305M
02/16/96 Date Co*
OK
Iron Oxide
SUB46-7380
34.7 X
®.0t
02/20/96
TDK
Lead Oxide
SU846-7420
2.65 X
1.01
02/20/96
TM
Loss on Ignition
EPA 160.4
3.4 X
0.01
02/17/96
•ou
Magnesiui Oxide
SW846-7460
2.05 X
0.01
02/19/96
nw
Zinc Oxide
SU846-7950
32.4 X
0-01
02/20/96
TM»
Saaple: 05A RC 301762
Collected: 02/06/96
Category* t
Oeteetfen 0»t»
Test Mine
Method
Result Units
Lieii
Stirted-
tea teK
Antiaony
SU846-6010A
50.7 ag/kg
10
02/15/96
TAN.
Cadatua Oxide .
SU846-7130
0.0612 X
0.0T
02/20/96
TA*
Calciia Qxfdt
SU846-7140
3.67 X
0.01
•2/19/96
TUt
Digestion of Duet
SU846-3050A
02/14/96 Oate Com
CVM
Iron Oxide
SU846-7380
27.9 X
0.01
•2/20/96
rm
Lead Oxide
SU846-7420
2.24 X
0.01
02/20/96
TAM
Loss on Ignition
EPA 160.4
3.5 X
0.01
02/17/96
nou
Magnesiiai Oxide
SW8A6-7460
2.23 X
0.01
02/19/96
TAM
Zinc Oxide
SV8A6-7950
38.7 X
0.01
•2/20/96
IAN ~
Staple: 06A RC 301673 Collected: 02/08/96 Category: t
Detection Oat*
Teft »m
Method
Result
Units
Uaii
Started
Has
Antiaony
SU846-6010A
81.9
¦g/kg
10
02/15/96
TAN
Cadiiw Oxide
SU846-7130
0.0732
X
0.01
02/20/96
TAR
Calciui Oxide
SU846-7140
4.14
X
0.01
02/19/96
TAM
Digestion of Dust
SU846-3050A
02/14/96
Date Coa
cm
Iron Oxide
SU846-7380
34.1
X
0.01
02/20/96
TAM
Lead Oxide
SU846-7420
2.77
X
0.01
02/20/96
rm
Loss an Ignition
EPA 160.4
3.5
X
0.01
02/17/96
¦OU
Magnesiue Oxide
SU846-7460
2.24
X
0.01
02/19/96
tM
Zlne Oxide
SU846-79S0
31.1
X
0.01
02/20/96
rm
-------
QUALITY ASSURANCE / QUALITY CONTROL TOTAL KETALS
Report No. D60204?
ANALYSIS PARAMETER RESULTS
Cat blank 1 Antimony <0.1
Cat blank 2 Antimony <0.1
Prep blank Antlnony <0.1
ANALY8I8 PARAMETERS RESULTS %
ICC MiSwonr 100
ANALY81S PARAMETER RESULTS*
ICV Antimony 93
ICS 1 Antlncny 89
CCV Ant lawny 103
ICS 2 Antinony 102
ANALY3I3 PARAMETER RESULTS %
ICS Antimony 102
Antloony 105
tCV > Initial Calibration Verification ~ op - 10*
ICS -Interference Check Standard I CP OKJ.T ~ or - 20*
ICS -laboratory Control Standard ~ or - 20* and or • 30* Silver and Antlanny
ICC ¦ Initial Calibration Check ICP OHU ~ or - 5X
Blank • « Detection Liiatt RPD • Relative Percent Pifferene* <20*
r>s* i of i
-------
Attachment C
Laboratory Report for METCO Baghouse Dust Samples (Table 5)
-------
SOURCE EMISSIONS SURVEY
OF
CHAPARRAL STEEL COMPANY
MIDLOTHIAN, TEXAS
VOLUME II
JANUARY AND FEBRUARY 1996
FILE NUMBER 96-15
-------
Job #96-155
Client Chapanai Steel
Location Midlothian, IX
UNIT Baghouse Dust
DATE 2-16-86
Sample
A Baghouse Dust
B Baghouse Dust
m
I
N)
O
C Baghouse Dust
Sb As Cd
mg/Kg mg/Kg mg/Kg
692 146 734
55.7 108 556
107 134 735
Cr Cu Fe
mg/Kg mg/Kg mg/Kg
795 1,720 154,000
*
861 1530 133,000
1,710 2,700 213,000
Pb Mn Hg
mg/Kg mg/Kg mg/Kg
22,500 20,300 13.9
18,200 19,500 I5T.H
26,100 24,600 1.4
Mo Nl Zn
mg/Kg mg/Kg mg/Kg
<27.9 299 163,000
48 287 128,000
33.5 172 228,000
f
-------
m
Ross Analytical Services, Inc.
164.13 Foltz Industrial Parkway ' Slrongsvillc. Ohio 44136
016) 572-3200 • Fa* (216) 572-7620 • 1-800-325-7737
CKRTIFICATg OP ANALYSIS
Environmental' Work Order #: 96-02-036
Dooley Road Client Code: METCO
b, TX 75244 Report Date: 02/15/96
Work ID: Multi-metals Trains
Hanoch Toren Date Received: 02/08/96
I
SAMPLE IDENTIFICATION
Sample
Lab
Sample
DescriDtion
Number
Descriotion
Composite B Baghouse
Run
1
02
Composite B Baghouse Run 2
Composite B Baghouse
Run
3
04
Composite B Baghouse Blank
Composite C Baghouse
Run
1
06
Composite C Baghouse Run 2
Composite C Baghouse
Run
3
08
Composite C Baghouse Blank
Audit Filter
10
A Baghouse Dust
B Baghouse Dust
12
C Baghouse Dust
Data are reported on an as-received basis unless stated other-
wise. Estimated Quantitation Limits (EQL's) are listed £or
most analytes. EQL's are the lowest concentrations that can
be reliably measured under routine laboratory conditions.
Unless otherwise noted, method blanks had no targets found
above their EQL's and results were not corrected for blanks.
E-21
-------
Ross Analytical Services, Inc.
I MM Foliz Industrial Parkway • Sirongsvillc, Ohio 44136
(216) 572-320H' Eax. 1216) 572-7620 • I -800-323-7737
CERTIFICATE OP ANALYSIS
ent:
co Environmental
15 Dooley Road
las, TX 75244
n: Hanoch Toren
Work Order *: 96-02-037
Client Codei METCO
Report Date: 02/15/9S
Work 10: Multi-metals Trains
Date Received: 02/08/96
SAMPLE IDENTIFICATION
Sample
Description
Lab
Number
Sample
Description
KMn04
B
Baghouse
Run l
02
HCl
B Baghouse Run 1
KMn04
B
Baghouse
Run 2
Run 3,;
04
HCl
B Baghouse Run 2
KMn04
B
Baghouse
06
HCl
B Baghouse Run 3
KMn04
B
Baghouse
Blank
08
HCl
B Baghouse Blank
KMn04
C
Baghouse
Run l
10
HCl
C Baghouse Run 1
KMn04
C
Baghouse
Run 2
12
HCl
C Baghouse Run 2
KMO04
c
Baghouse
Run 3
14
HCl
C Baghouse Run 3
KMn04
c
Baghouse
Blank ¦*
16
HCl
C Baghouse Blank
Data are reported on an as-received basis unless stated other-
wise. Estimated Quantitation Limits (EQL's) are listed for
most analytes. EQL's are the lowest concentrations that can
be reliably measured under routine laboratory conditions.
Unless otherwise noted, method blanks had no targets found
above their BQL's and results were not corrected for blanks.
approved by
luler
E-22
-------
tfork Order * 96-02-036,037
Ross Analytical Serrieee, Insr
000004
aaported: 02/15/SS
103
/9G
TEST MKTHnnmf.nnTiB;
fercury was determined in aqueous samples and leachates by cold vapor atomic
ibsorption after acid/permanganate digestion as in EPA Methods 245.X and 7470A.
I single analysis was performed unless otherwise noted.
Multi-metals train" samples were prepared for analysis according to
'Methodology for the Determination of Metals Emissions in Exhaust Gases from
[azardous Waste Incineration and Similar Combustion Processes", 40 CFR 265,
tppendix IX, Section 3.1. Prepared samples were analyzed by Inductively Coupled
'lasma Emission Spectroscopy (XCP) as in EPA Method 6010A, unless otherwise
toted. /
ietals were determined in solid and non-aqueous liquid samples by digestion with
dtric acid, hydrogen peroxide, and hydrochloric acid as in EPA Method 3050A,
ollowed by Inductively Coupled Plasma Emission Spectroscopy as in EPA Method
010A, unless noted otherwise.
lercury was determined in solid and non-aqueous liquid samples by cold vapor
tomic absorption after acid/permanganate digestion as in EPA Methods 245.5 and
471A. A .single analysis was performed unless otherwise noted.
ercury was determined in aqueous samples and leachates by cold vapor atomic
bsorption after acid/permanganate digestion as in EPA Methods 245.1 and 7470A.
single analysis was performed unless otherwise noted.
E-24
E-23
-------
>rk Order # 96-02-036
Ross Analytical Services. Inc
000005
Reported: 02/15/SS
imple volume
ib
Ho. DascriDtion
tftilts
SOS
.D
HN03 FW B Baghouse Run 1
110
Total mL
5
LE
Imps. BH B Baghouse Run 1
463
Total nL
S
ID
HN03 FW B Baghouse Run 2
113
Total mli
5
!H
Imps. BH B Baghouse Run 2
455
Total mli
5
ID
HN03 FW B Baghouse Run 3
105
Total mli
5
IB
Imps. BH B Baghouse Run 3
445
Total mL
5
LD
HN03 FW B Baghouse Blank
110
Total ml>
5
LE
Imps. BH B Baghouse Blank
295
Total ml>
5
;d
HN03 FW C Baghouse Run 1
108
Total mL
5
;e
Imps. BH C Baghouse Run 1
445
Total ml>
5
>D
HN03 FW c Baghouse Run 2
88
Total ml>
5
>'E
Imps. BH C Baghouse Run 2
445
Total mL
5
7D
HN03 FW C Baghouse Run 3
107
Total mL
5
7B
Imps. BH C Baghouse Run 3
480
Total mL
5
3D
HN03 FW C Baghouse Blk
95
Total mL
5
)E
Imps. BH C Baghouse Blank
390
Total mL
5
E-2S
-------
>rk Order # 96-02-037
Robs Analytical Services. Znc
000006
Reportedt 02/15/9S"
mple volume
b No.
Smml« DescriDtion
Result
units
BOS
A
KMn04
B Baghouse Run 1
187
total
mL
5
A
HC1 B
Baghouse Run 1
415
Total
mL
5
A
KMn04
B Baghouse Run 2
390
Total
mL
5
A
HC1 B
Baghouse Run 2
225
Total
mL
5
KMn04
B Baghouse Run 3
387
Total
mL
5
HC1 B
Baghouse Run 3
218
Total
mL
S
KMn04
B Baghouse Blank
385
Total
mL
. 5
HC1 B
Baghouse Blank
220
Total
mL
5
I
KMn04
C Baghouse Run 1
385
Total
mL
5
I
HC1 C
Baghouse Run 1
225
Total
mT.
5
L
KMn04
C Baghouse Run 2
390
Total
mL
S
HC1 C
Baghouse Run 2
240
Total
mL
S
KMn04
C Baghouse Run 3
400
Total
mL
5
HC1 C
Baghouse Run 3
200
Total
mL
5
KMn04
C Baghouse Blank
* 380
Total
mL
5
HC1 C
Baghouse Blank
222
Total
mL
5
E-26
-------
U.S. EPA - CLP OOOOOY
COVER PAGE - INORGANIC ANALYSES DATA PACKAGE
lame: ROSS ANALYTICAL SERVICES
;ode: ROSS
to.
ILM03
Case No.
EPA Sample No.
ABAGDUST
ABAGDUSTD
—ABAGDUSTSC
"ABAGDUSTS
AUDIT
~BBAGBLK
BBAGDPST
BBAGELl
BBAGR2
BBAGR2P
BBAGR2SD
~BBAGR2S
~~BBAGR3
CBAGBLK
CBAGDUST
"CBAGRl
CBAGR2
CBAGR2D
CBAGR2SD
"CBAGR2S ~
Contract: METCO
SAS No.:
SDG No.:BAGHOa
Lab Sample ID
02-036-10A
~02-036-10A"^S
02-036-10A-SD
"02-036-10A-S
02-036-09A
02-036-04A
02-036-11A
"02-036-01A
"02-036-02A
"02-036-02A^15
"02-036-02A-SE
"02-036-02A-S
"02-036-03A
"02-036-08A
"02-036-12A
"02-036-05A
02-036-06A
"02-036-06A"=T5
"02-036-06A-SD
"02-036-06A-S
I CP interelement corrections applied ?
I CP background corrections applied ?
If yes - were raw data generated before
application of background corrections ?
Yes/No YES
Yes/No YES
Yes/No NO
snts:
tify that this data package is in compliance with the terms and
tions of the contract, both technically and for completeness, for
• than the conditions detailed above. Release of the data contained
Lis hardcopy data package and in the computer-readable data submitted
oppy diskette' has been authorized by the Laboratory Manager or the
er
ture:
the
following signature.
T7 <&ciuAjvr'
Name:
Title:
COVER PAGE - IN
ILM02.1
E-27
-------
U.S. EPA - CLP
000013
INORGANIC ANALYSES DATA SHEET
EPA SAMPLE NO.
Name: ROSS_ANALYTICAL_SERVICES
Code: ROSS Case No.:
rix (soil/water): S0IL_
il (low/med): LOW
>lids: 10 OUT
Contract: METCO
SAS No.:
SDG Mo.: BAGHOU
Lab Sample ID: 02-036-1QA.
Date Received: 02/08/96
Concentration Units (ug/L or mg/kg dry weight): MG/KC3
: Before:
r After:
CAS No.
Analyte
Concentration
C
Q
M
7429-90-5
Aluminum
E
MR
744CV-36-0
7440-38-2
Antimony
89.2
N
P
Arsenic
146
B
N
P
7440-39-3
Barium
Nft
7440-41-7
Beryllium
NR
7440-69-9
Bismuth
NR
7440-43-9
Cadmium
734
P
7440-70-2
Calcium
NR
7440-47-3
Chromium
fdS
P
7440-48-4
Cobalt
Nft
7440-50-8
Copper
1720
P
7439-89-6
Iron
154000
P
7439-92-1
Lead
22500
P
7439-93-2
Lithium
Nk
7439-95-4
Magnesium
NR
7439-96-5
Manganese
20300
P
7439-97-6
Mercury
13.9
CV
7439-98-7
Molybdenu
Nickel
27.9
0
P
7440-02-0
299
P
7440-09-7
Potassium
Nft
7782-49-2
Selenium
NR
7440-22-4
Silver
NR
7440-23-5
Sodium
NR
7440-28-0
Thallium
NR
7440-31-5
Tin .
NR
7440-62-2
Vanadium
NR
7440-66-6
Zinc
163000
P
Clarity Before:
Clarity After:
Texture:
Artifacts:
ints:
FORM I - IN ILM02.L
E-39
-------
000020
-------
000023.
U.S. EPA - CLP
i an* arnns no.
INORGANIC ANALYSES DATA SHEET
lame: ROSS_ANALYTICAL_SERVICES_ Contract: METOO
:ode: ROSS Case No. : SAS No.
CBAGDUST
SDG No.
.x (soil/water): S0IL_ Lab Sample ID: 02-036-12A
. (low/med): LOW Date Received: 02/08/96
.ids: 100.0
Concentration Units (ug/L or mg/kg dry weight) : MG/KG
CAS No.
Analyte
Concentration
C
Q
M
7429-90-5
Aluminum
5
tut
7440-56-0
Antimony
16?
H
p
7440-38-2
Arsenic
134
B
N
p
7440-39-3
Barium
Nfe
7440-41-7
Beryllium
NR
7440-69-9
Bismuth
MR
7440-43-9
Cadmium
735
P
7440-70-2
Calcium
Nft
7440-47-3
Chromium
1710
P
7440-48-4
Cobalt
nK
7440-50-8
Copper
2700
P
7439-89-6
Iron
213000
P
7439-92-1
Lead
26100
P
7439-93-2
Lithium
Nk
7439-95-4
Magnesium
NR
7439-96-5
Manganese
24800
P
7439-97-6
Mercury
1.4
5
CV
7439-98-7
Molybdenu
Nickel
33.5
P
7440-02-0
172
P
7440-09-7
Potassium
Nft
7782-49-2
Selenium
NR
7440-22-4
Silver
NR
7440-23-5
Sodium
NR
7440-28-0
Thallium
NR
7440-31-5
Tin
NR
7440-62-2
Vanadium
NR
7440-66-6
Zinc
228000
P
c Before: Clarity Be£ore: Texture:
c After: Clarity After: Artifacts:
ants:
FORM I - IN ILM02.L
E-41
-------
U.S. EPA - CLP 000038
2A
INITIAL AND CONTINUING CALIBRATION VERIFICATION
Fame: ROSS_ANALYTICAL_SERVICES_ Contracts METCO
tode: ROSS Case No.: SAS No.: SDG No.; BACaOH
al Calibration Source: PLASMA CHEM
nuing Calibration Source: PLASMA CHEM_
Concentration Units: ug/L
yte
Initial Calibration
True Found %R(1)
Continuing Calibration
True Found *R (1) Found
1 M
m
p
p~
m
NR
NR
P
m
p
m
p
p-
P~ :
Nff
NR
P
C?
P
P
MS
NR
NR
NR
NR
NR
NR
P
inum
mony_
nic
um
Ilium
uth
ium
ium
miura
It ~
er
5000.0
~5000.0
5342.31
_4965.36
106.8
_99.3
10000.0
_10000.0
10376.39
_9686.68
103.8
_96.9
10205.13
10158.67
102.1
101.6
500.0
S20.22
104.0
1000.0
JL011.54
101.2
995.47
_>5.5
1000.0
_1037.39
103.7
2000.0
_202d.6$
101.5
_1992.91
_99 .6
1000.0
"Toooo.o
~ 5000.0
1030.90
X0586.94
_5177.05
103.1
105.9
103.5
2000.0
"50000.0
JLOOOO.O
2012.S7
51065.06
10051.36
100.6
105.3
100.5
1965.08
50531.04
_9870.73
56.3
102.7
_98.7
ium
esium
anese
ury
bdenu
al^
9sium
ciium
5r
am
Lium_
500.0
2.0
512.81
2.06
102.6
103.0
104.9
105.2
1000 .0
5.0
1005.27
5.37
100.5
107.4
104.6
102.0
981.08
5.53
.1
110.6
102.2
_99.5
-1000.0
1000.0
1049.38
_1052.30
2000.0
2000.0
20dl.67
_2040.16
2044.09
"1990.92
iium_
1600.6
£6S.O2
2000.0
_1965.43
_96.3
_2050.28
102.5
Tontrol Limits: Mercury 80-120; Other Metals 90-110; Cyanide 85-115
FORM II (PART 1) - IN ILK02.1
E-58
-------
U.S. EPA - CLP 000039
2A
INITIAL AND CONTINUING CALIBRATION VERIFICATION
trae: ROSS ANALYTICAL SERVICES Contract: METCO
>de: ROSS Case No.: SAS No.: SDG No.r BAGHDU
il Calibration Source: PLASMA CHEM
luing Calibration Source: PLASMA CHEM,
Concentration Units: ug/L
yte
Initial! Calibration
True Found *R(1)
Continuing Calibration
True Found VR(1) Found *R(1)
M
mc
p
p~
UK
NR
NR
P
NR
P
nK
p
p"
p"~
m
NR
P
CST
P
P~
NR
NR
NR
NR
MR
MR
MR
P_
inum_
nony
nic
am
Ilium
uth
ium
ium
mium
It ~
er
10000.6
_10000.0
10237.21
_9963.17
102.4
_99.6
_9512.26
_95 .1
1000.0
994.67
_99.5
2000.6
_2009.29
100.5
2000.0
"50000.0
JLOOOO.O
1979.97
70714.26
_9889.37
99.0
103.6
_98.9
dura
esiutn
anese
:ury
-bdenu
:el^
issium
mium
rer
,um
.lium_
1666.6
5.0
984.0b
5.17
2053.87
_1998.19
98.4
T03.4
102.7
_99.9
2.0
2.10
105.0
5.31
106.2
2000.0
2000.0
idium_
«
•
•
2000.0
_1991.8b
__99.6
_1938.85
_96.9
Control Limits: Mercury 80-120; Other Metalii 30-110; Cyanide 85-115
FORM II (PART 1) - IN * 11*02.2.
E-59
-------
U.S. EPA - CLP
2A
INITIAL AND CONTINUING CALIBRATION VERIFICATION
000041. )
ame: ROSS_ANALYTICAL_SERVICES_
ode: ROSS Case No.:
al Calibration Source: PLASMA CHEM
Contract: METC0_
SAS No.:
SDG No.: BAGHOtT
nuing Calibration Source: PLASMA CHEM_ -
Concentration Units: ug/L
yte
Initial/ Calibration
True Found %R(1)
Continuing Calibration
True Found %R(1) Found %R(l)
M
UK
p
p~*
m
NR
NR
P
NR
P
NR
p
p"~
p-
MR
NR
P
IR
m
>
>
m
>
>~
iE
IR
>
»
iR
m
IR
JR
JR
SR
JR
?
.r
E-61
-------
U.S. EPA - CLP
U.S. EPA - CLP
000045
23
CRDL STANDARD FOR AA AND ICP
Name: ROSS_ANALYTICAL_SERVICES_
Code: ROSS Case No.:
RDL Standard Source:
Contract: METCO_
SAS No.:
SDG No. r BAGHOU
CRDL Standard Source: SOLUTIONS PL
Concentration Units: ug/L
CRDL Standard for AA
CRDL Standard for ICP
Initial
Final
lyte
True
Found
%R
True
Found
%R
Found
%R.
minum_
imony_
enic
ium
yllium
muth
mium
cium
omium_
alt
per
n
200.0
213.32
106.7
10.0
12.23
122.3
20.0
26.15
100.8
40.0
Zoo.o
100.0
4b.46
564.35
90.30
101.2
132.2
_90.3
d
•*
hiura
Ties ium
ganese
cury
ybdenu
kel^
assium
enium_
ver
ium
llium_
10.0
13.98
139.8
-
^iJw
oo
o o
14.39
41.91
72.6
T04.8
adium
c
aotr
VL
E
i
r
IK
IR
¦R
)
•R
i
R
R
R
R
R
R
El
R
R
El
FORM II (PART 2) - IN
ILMQ2.I.
E-62
-------
U.S. EPA - CLP
000046
2B
CRDL STANDARD FOR AA AND I CP
Name: ROSS_ANALYTICAL_SERVICES_
Code: ROSS Case No.:
:rDL Standard Source:
Contract: METC0_
SAS No.:
SDG No.: BAGHOtT
CRDL Standard Source: SOLUTIONS PL
Concentration Units: ug/L
lyte
minum
imony_
enic_
ium "
/Ilium
nuth_
nium_
2ium_
smium
ilt_
?er
1
I
lium
lesiurn
fanese
:ury
'bdenu
:el
is slum
:nium_
¦er
um
lium
dium
CRDL Standard for AA
True Found *R
True
CRDL Standard for ICP
Initial Final
Found %R Found VR
200.0
400.0
181.97
393.44
.91.0
~98 .4
10.0
10.51
106.1
20.0
^ 56.33
101.6
40.0
500.0
100.0
S2.45
131.1
112.8
114.8
225.62
114.84
O
•
o
H|
10.79
107.9
O O
OO
Tl
22.02
110.1
111.7
44.68
40.0
54.03
135.1
FORM II (PART 2) - IN
ILM02.X
E-66
-------
U.S. EPA - CLP
00004V
23
CRDL STANDARD FOR AA AND ICP
lame: ROSS_ANALYTI CAL_SERVICES_
:ode: ROSS Case No.:
IDL Standard Source:
Contract: METCO_
SAS No.:
SDG No.: BAGHDU"
;RDL Standard Source: SOLUTIONS PL
Concentration Units: ug/L
CRDL Standard for AA
CRDL Standard for ICP
Initial
Final
.yte
True
Found
%R
True
Found
%R
Found
ttt
iinum_
mony
mic
.uin
'Ilium
*uth
lium
:ium
>miura
tit ~
>er
L
400.0
466.41
102.1
I
iium_
lesium
ranese
mry
'bdenu
¦.el^
issium
snium
rer
um
lium_
clium_
40.0
42.89
107.2
FORM II (PART 2) - IN
ILM02-1
-------
U.S. EPA - CLP
000048
3
BLANKS
ame: ROSS_ANALYTICAL_SERVICES_
>de: ROSS Case No-:
Contract: METCO_
SAS No.:
SDG No.: BAGHOIT
ration Blank Matrix (soil/water): SOIL_
ration Blank Concentration Units (ug/L or rag/kg): MG/KG
te
Initial
Calib.
Blank
(ug/L)
/
C
Continuing
Blank
1 C
Calibration
(ug/L)
2 C 3
C
Prepa-
ration
Blank
C
M
nura
U
iAr
ony
8.5
0
8.5
8.5
U
8.5
U
0.850
u
p
ic
18.8
u
39.9
B
18.8
U
18.8
U
1.880
U
p
n
NR
Lium
NR
th
NR
am
0.6
tf
0.6
0
0.6
tt
0.6
D
0.060
u
P
am
S
0
NR
Lira
-3.1
6
-4.3
2.6
U
2.6
0.260
U
P
U
0
0
NR
r
14.0
14.0
14.0
14.6
1.466
0
P
71.7
u
71.7
U
71.7
U
71.7
u
7.170
u
P
-9.2
B
-10.5
B
8.0
U
8.0
u
0.800
u
P
im
NR
lium
0
NR
lese
0.8
u
0.8
0
0.8
tr
0.8
0
0.080
P
y
0.04
u
o.w
u
0.0V
u
0.015
u
cv
enu
5.8
u
5.8
u
5.8
u
5.6
t]f
-0.921
B
p
2.8
u
2.8
u
2.8
U
2.8
u
0.280
D
p
ium
tar
um
NR
NR
NR
am
NR
NR
um
5
U
0
NR
2.2
0
3.5
2.2
0
2.2
0.220
P
FORM III
IN
XLM02.X
E-68
-------
u s EPA CLP 000049
3
BLANKS
arae: ROSS ANALYTICAL SERVICES Contract: METCO
ode: ROSS Case No.: SAS No.: SDG No.: BAGHOO"
ration Blank Matrix (soil/water) : HATER
ration Blank Concentration Units (ug/L or mg/kg) : UG/L_
rte
Initial
Calib.
Blank /
(ug/L)
C
Continuing
Blank
1 C
Calibration
(ug/L)
2 C 3
C
Prepa-
ration
Blank
C
M
.num
E
5
5
sir
rany
11.5
8.5
U
14.4
10.3
8.500
0
p ~
lie
18.8
U
18.8
D
-24.6
B
18.800
U
p
ira
NR-
liura
NR~
ith
E
S
I
U
NR
um
0.8
l.i
6.$
1.0
0.666
P
um
0
U
I
NE~
ilum
2.6
U
2.6
2.6
4.9
2.600
a
P
t
cr
Nft
r
14.0
U
14.0
V
14.6
14.6
0
14.000
u
p
71.7
U
75.8
B
71.7
D
71.7
u
71.700
u
p
18.0
B
12.2
B
" 8.0
U
8.0
u
8.000
u
p"
um
NK~
slum
NR
nese
-1.6
B
0.8
U
0.8
0
0.8
0
0.800
P
ry
O.OH
U
0,0*
a
0.0V
B
0.0V
u
0.130
B
CV
denu
5.8
a
5.8
o
5.8
U
5.8
u
5.800
XT
P
1
2.8
u
5.5
B
7.2
B
2.8
u
2.800
U
P
sium
ne~
ium
m
r
NR
n
NR
Lum
NR
NR
ium
u
S
NR
2.2
tJ
2.2
2.2
ty
4 .460
P
Cam tyiSh*
FORM III - IN ILM02.r
-------
U.S. EPA - CLP
vuvuou
3
BLANKS
Name: ROSS_ANALYTICAL_SERVICES_
Code: ROSS Case No. :
Contract: METCO_
SAS No.:
SDG No.: BflGHDH
aration Blank Matrix {soil/water) •- HATER
aration Blank Concentration Units (ug/L or mg/kg): UG/L_
lyte
Initial
Calib.
Blank,
(ug/L)/
C
Continuing Calibration
Blank (ug/L)
1 C 2 C 3
C
Prepa-
ration
Blank
c
minum
1
5
5
5
imony
U
9.9
14.0
11.5
34.200
enic
18.8
28.2
B
18.8
u
28.6
B
29.110
B
Lum
allium
nuth
B
B
B
nium
1.2
1.6
0.6
0
0.750
;ium
S
5
jmium
-2.8
-S. 5
S.2
B
2.600
0
lit
U
U
Der
14.0
tl
14.0
14.0
14.000
0
i
71.7
U
71.7
U
92.6
B
71.700
u
i
13.5
B
15.0
B
9.2
B
15.030
B
lium
lesium
U
V
janese
6.6
0.8
V
6.6
0.800
0
:ury
O.Otf
U
0.0^-
u
0.0*
U
0.152
B
dbdenu
5.8
U
5.8
u
5.8
u
5.870
B
;el
4.1
B
2.8
XJ
3.8
B
5.090
B
issium
'.nium
rer
um
lium
dium
U
0
5
5
i m
2.2
2.2
2.6
4.3
2.530
C/rn -V i+tib
FORM III - IN
ICM02.X
E-70
-------
000055
U.S. EPA - CLP
4
ICP INTERFERENCE CHECK SAMPLE
ne: ROS S_ANALYT I CAL_S ERVI CES_ Contract: METCO
ie: ROSS Case No.; SAS No: SDG No.: BBGHEXT
Number: TJA 36 ICS Source: CPI
Concentration Units: ug/L
Tru£
Sol. Sol.
alyte A AB
.Initial Found
Sol. Sol.
A AB VR
Final Found
Sol. Sol.
A AB *R
ninum
irnony
enic
ium
/Ilium
muth
mium
cium
omium
alt
per
n
500000
500000
1000
1000
_493094
495083.8
1080.4
1067.2
99.0
108.0
106.7
_466533
473708.2
~ 1005.0
1193.1
94.7
TOO. 5
119.3
1000
TiJoooo
500
•J .
916.5
"475063.0
^ 441.3
91.6
"95.6
"88.3
883.7
459935.0
430.6
88.4
92.0
"86.1
500000
_4$6237
_468600
500
480.1
""177549.3
~ 897.6
96.0
"*88.8
"89.8
447.4
172159.0
~ 867.3
69.5
86.1
_86.7
200000
200000
1000
_181054
_174242
d
tiium
neeium
ganese
cury
ybdenu
fcel^
assium
enium
ver
ium
llium_
500000
500000
~~ 500
_48$757
489750.2
~ 484.3
98.0
"96.9
_464458
46978!). 6
468.3
94. 0
_93.7
-
1600
1000
903.8
850.4
90.4
"85.0
657.6
85.8
_82.6
826.3
adium
0
_10.00
906.3
_90.9
890.1
_89.0
1
FORM IV - IN .ILMQ2.1
E-7S
-------
U.S. EPA - CLP
oooo6i
5A
SPIKE SAMPLE RECOVERY
EPA SAMPLE BO.
fame: ROSS_ANALYTICAL_SERVICES_
Case No.:
Contract:METCO
'ode: ROSS
x: SOIL
ids-For Sample: 100.0
SAS No.:
ABAGDUSTS
SDG No.:
Level (low/med) :
BASHOtf
LOW
Concentration Units (ug/L or mg/kg dry weight): MG/KG
Control
Limit
%R
86-115
80-120"
80-120
60-110
80-120"
Spiked Sample
Result (SSR)
234.3204
"372.5728"
954.3204
1012.5728
1853.6893
159021.5048"
" 22572.3301"
20183.7864*-
15.1538
181.6019-
487.0388
163908.1068
Sample
Result (SR)
89.1827
146.4423
*34.0365
W5.1442
1724.4231
153704.9038
~ 22548.3654
26344.2*788
13.8824
27.8846
299.0865
163409.6154
Spike
Added (SA)
194.17
"194.17
194.17
194.17
194.17
"?883 .50
" 194.17
194.17
" 0.77
154.17
'194.17
194.17
*R
74.7
116.5
113.4
112.0
£6.6
136.9
" 12.3
-62.7
"165.1
" 93.5
96.8
ts:
FORM V (Part 1} - IN 113302.X
E-81
-------
U.S. EPA - CLP
OQ0062
5A
SPIKE SAMPLE RECOVERY
EPA SAMPLE NO.
dame: ROSS_ANALYTICAL_SERVICES_
Case No.
Contract:METCO
¦"ode: ROSS
Lx: SOIIi
Lids-For Sample: 100.0
SAS No.
ABAGDUSTSD
SD5~SoTT"
Level Clow/med) s
BAflHOO
COW
Concentration Units {ug/L or mg/kg dry weight) s MG/KG
ilyte
Control
Limit
*R
Spiked Sample
Result (SSR)
C
Sample
Result (SR)
C
Spike
Added (SA)
*R
Q
M
linum
5
MR
.mony
80-120
2^2.0588
&
89.1827
196.08
93.3
R
P
:nic
80-120
410.5392
B
146.4423
B
196.08
134.7
P
.um
NR
'Ilium
NR
tuth
MR
lium
ed-126
$26. Hit
734.0385
196.08
98.3
P
ium
NR
mium
963.6275
7SS.1442
196.08
85.9
P
It
MR
er
1772.3039
1724.4231
196.08
24.4
P
147620.5392
153704.9038
3921.57
-155.2
P
21915.0980
22548.3654
196.08
-323.0
P.
ium
MR
esium
MR
anese
19310.0000
20344.2788
196.OS
-527.5
P
ury
15.2941
13.8824
0.78
181.0
cv
bdenu
80-120
194.6569
27.8846
tJ
196.08
99.3
p
el
80-120
462.3529
299.0865
196.08
83.3
p
ssium
NR
niura
MR
er
MR
am
MR
Hum
MR
MR
lium
NR
156362.4020
163409.6154
196.08
-3594.1
P
,
its:
FORM V (Part 1) - IN
HH02.I.
E-82
-------
U.S. EPA - CLP
5B
POST DIGEST SPIKE SAMPLE RECOVERY
EPA SAMPLE NO.
dame: ROSS_ANALYTICAL_SERVICES_ Contract:
-ode: ROSS Case No. : SAS No. :
ix: SOIL
Concentration Units:
METCO
ABAGDUSTA.
SEXS No.: BAflHOO
Level (low/med): LOW_
ug/L
c
Sample
Result (SR)
C
Added (SA)
*R
Q
M
I
SB.
927.50
fan. turn
83.5
P
1523.00
B
Act* OOO
96.3
F
nR
NR
MR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
KR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
alyte
minum
imony|_
enic_
ium
/Ilium
muth_
mium_
cium_
omium
alt
per
n
d
hmm
nesium
ganese
curv
ybdenu
kel^
asslum
enium_
ver
ium
llium_
adium
Control
Limit
*R
Spiked Sample
/ Result (SSR)
84461.50
T94191.50"
ents:
2.X
E-95
-------
U.S. EPA - CLP
5B
POST DIGEST SPIKE SAMPLE RECOVERY
lame: ROSS_ANALYTICAL_SERVICES_ Contract: METCO.
;ode: ROSS Case No.: SAS No.:
.X: SOIL
000076
EPA SAMPLE NO.
ABAGDUSTAD
SDG i4o.: BAGHGU
Concentration Units:
Level (low/med): LOW_
ug/L
tlyte
Control
Limit
%R
Spiked Sample
/Result (SSR)
C
Sample
Result (SR)
C
Added (SA)
IR
Q
M
linum
6
HE
.mony
1009^5. SO
927.50
/on. oca
100.0
P
tnic
193341.50
1523.00
B
Ado oao
95.9
P~
.um
NR
'Ilium
NR
luth
rj*r\
NR
aum
MS J10
NR
:ium
NR
imium
NR
ilt
NR
•er
NR
i
NR
L
NR
aum
NR
lesiutn
¦»
NR
anese
NR
:ury
NR
txienu
NR
el
-
NR
ssium
NR
nium
NR
er
NR
um
.
NR
Hum
NR
NR
dium
NR
NR
nts:
2.r
E-96
-------
U.S. EPA
CLP
DUPLICATES
Name: ROSS_ANALYTICAL_SERVICES_
Code: ROSS Case No.:
ix (soil/water): SOIL_
lids for Sample: 100.0
Contract: METCO_
SAS No. :
000079
EC* SAMPLE NO.
ABAGDUSTD
SDG No.: BAGHOtf
Level (low/med): LOW
% Solids for Duplicate: _1Q0.Q
Concentration Units (ug/L or mg/kg dry weight) : HQ/KG
iVnalyte
Vlumlnum_
Vntimony_
irsenic
Sarium '
lerylliura
}ismuth_
:admium_
:alcium_
.'hromium
:obalt ]
topper
!ron
jead
.ithium
[agnesium
tanganese
lercury
iolybdenu
ickel^
otassium
elenium_
ilver
odium
hallium_
in
ouiadium_
Lnc
Control
Limit
Sample (S)
"5571527
146.4423
734.0385
795.1442
1724.4231
153704.9038
" 22548.3654
26344.2766
13.8824
27.8846
299.0865
163409.6154
U
Duplicate (D) C
"171.5686
715.2451
15773555
1«1.61S7
"153479.9020
" 21557.1078
"ttr/TTSJZ?
14.0769
28.4314
316.4216
156582.8431
U
RPD
13.4
"15.8"
~T7T
11.0
STT"
"* 17. 7~
4.5"
4.0
"1.4"
"375"
4.3
HE
P
P~
ME
MR
NR
P
ME
p
NE
p
p~
p~
ME
MR
P
CV
P
P~
ME
MR
MR
MR
MR
MR
MR
P
FORM VI - IN
ILK02.2.
E-99
-------
U.S. EPA - CLP
§PilC£ DUPLICATES
fame: ROSS_ANALYTICAL_SERVICES_
;ode: ROSS Case No.:
Lx (soil/water): SOIL_
Lids for Sample: 100.0
Contract: METCO_
SAS No.:
00008S
EPA SAMPLE NO.
ABAGDUSTSD
SDG No.: BAGHOU
Level (low/med)= LOW
V Solids for Duplicate; _100.O
Concentration Units (ug/L or mg/kg dry weight): MQ/KG
\nalyte
Vluminum_
\ntimony_
\rsenic_ ""
Barium "
3eryllium
3ismuth_
:admiura_
ralcium_
rhromium
Cobalt ]
Copper
Iron
Lead"
Ciithium'
4agnesium
Manganese
Mercury
tolybdenu
Nickel
Potassium
3elenium_
Silver
Sodium
Thallium
Tin
Vanadium
Sine
Control
Limit
Sample (S)
"372.5728
"15475254
10X2.5728
—IS53T5553"
159021.5048
" 22572.3301
20183.7864
15.1538
181.6019
487.0388
163908.1068
Duplicate (D) C
272.058&
"410.5392
725775T7
553.6275
—TTTTrSVSS
"177620.5392
" 21915.0980
15.2941
T94.S569
462.3529
156362.4020
RPD
14.9
" 9.7"
jmr
"37TT
"775"
"7.4"
"3.0"
4.4
"0.9"
"6.9"
"5.2"
"477"
M
RR
P.
P~
NR
NR
NR
P
NK
P .
NK
P
P~
P"~
nR
NR.
P
c!7
P
P~
nR
NR
NR
NR
NR
NR
NR
P
FORM VI
IN
ILM02.I.
E-108
-------
Name: ROSS_ANALYTICAL_SERVICES
Code: ROSS Case No.: _
ix (soil/water): SOIL_
lids for Sample: 100.0
U.S. EPA - CLP
Posi SPlKE DUPLICATES
Contract: METCO
000089
£CA. SAMPLE NO.
ABAGDUSTAD
SAS NO.:
SDG No.: BAGHOU
Level (low/med)r LOW
V Solids for Duplicate: _1Q0.<1
Concentration Units (ug/L or mg/kg dry weight} : MS/KG
ftoalyte
Muminum_
=intimony_
\rsenic ~~
3arium '
beryllium
3isimxth_
:admium_
:alcium_
;hromiuni
robalt '
ropper
Cron_
jead"
jithlum
lagnesium
(anganese
lercury
lolybdenu
ricKel__
'otassium
!elenium_
lilver
odium
halliura_
in
anadium_
inc
Control
Limit
Sample (S)
34.4615
"194.1915
Duplicate (D) C
160.9(555
*193.3415
RPD
17.8
" 0.4"
m
p
p*
m
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
NR
FORM VI - IN
ILM02.3.
E-109
-------
U.S. EPA - CLP 000094
7
LABORATORY CONTROL SAMPLE
ame: ROSS ANALYTICAL SERVICES Contract: METCO
ode: ROSS Case No.: SAS No.: SDG No.r BACHQU
LCS Source: ERA
as LCS Source: SOLUTIONS PL
yrte
Aqueous (ug/L)
True Found %R
Solid (mg/kg)
True Found C Limits %R
inum_
T»ony~
aic
lm
Llium
ith
Lum
Lum
alum
Lt ~
»r
I
1 II 1 1 1 1 II II 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 I I 1 1
1000.0
_1000.0
966.06
_1040.47
96.6
104.0_
116.0
95.3
96.2
23.2
316.0
146.0
82.9
I0S.7
100.7
46.7
_1000.0
_1031.09
103.1_
106.0
106.2
62.5
148.0
100.2
_1000.0
_1050.11
105.0_
82.3
81.4
48.6
114.0
1
HOH
ooo
o o o
ooo
• • •
OOO
950.34
51267.69
_1043.37
S5.6
106.3"
104.3_
94.9
102.6
¥371.1
86.3
57.5
IUJ
H-0H
MOGJ
mo*
ooo
108.1
67.4
"94.1
6490.0
91.7
4350.0
49.5
Lum
ssium
inese
SF"—
>denu
sl^
3Siura
lium
sr
im
.ium_
1000.0
~ 2.0
1049.84
~ 1.82
lOfe.O
91.0*"
T01.3
102.2_
138.0
10.0
129.2
11.0
95.2
186.0
15.6
149.0
142.0
93.6
T10.0
103.2
101.7
5.2
53.8
. 1(5(10.0
_1000.0
1013.21
_1021.52
94.4
99.5
97.4
T01.2
58.7
lium_
_1000.0
_1028.30
102.8_
dd.6
100.2
56.2
150.0
101.6
FORM VII - IN
ILM02.r
E-114
-------
U.S. EPA - CLP 000095
7
LABORATORY CONTROL SAMPLE
Name: ROSS ANALYTICAL SERVICES Contract: METCO
Code: ROSS Case No.: SAS No.: SDG No.: BAGHDTT
d LCS Source:
ous LCS Source: SOLUTIONS PL
lyte
nxnum_
Lmony_
jnic_
Lum "
allium
BUth
aium
;ium
>mium
lit ~
>er
i
I
iiium
lesium
fanese
:ury
bdenu
:el^
ssium
niura_
er
um
liura_
dium
Aqueous (ug/L)
True Found %R
1000.0
"1000.0
.1666.6
1666.6
1000.0
20000.0
1000.0
1000.0
2.0
TMo.o
"1000.0
1000.0
1120.01
"1020.24
1040.94
1666.57
SS<5.xi
31568.57
1049.75
1060 .31
1.37
1033.77
1038.61
1015.91
112.0
102.0"
104.1
106.7
99.6
107.8"
105.0"
106.0
68.5"
103.4"
103.9"
101.6
Solid (nog/kg)
True Found C Limits %&
FORM VII - IN
ILM02.L
E-11S
-------
U.S. EPA - CLP
10
Instrument Detection Limits (Quarterly)
000099
"fame: ROSS_ANALYTICAL SERVICES_
;ode: ROSS Case So.: ~
[D Number: TJA_36
»AA ID Number :
ice AA ID Number :
Contract: MBTCO
SAS No.:
Date: 01/03/96
fry J/trAtG AnA/tt/ff-
SDG No. : BAGHOtX
Analyte
Wave-
length
(nm)
Back-
ground
SQL-
CXCX71j
(ug/L)
XSir
(ug/L)
M
P
P
UK"
NR~
NR~
P ~
P
P
nK~
P ~
P
P
NE"
P ~
P
nir
p ~
p
HE"
NR~
NR
NR~
NR
NR
NR."
P ~
Aluminum
Antimony,
Arsenic
Barium
Beryllium
Bismuth
Cadmium
Calcium
Chromium
Cobalt
Copper
Iron
308.22
206.84
_193.70_
100
100
27.2
8.5
200
2
18.8
1
10
226.50
315.89"
_267.72~
5
0.6
200
10
148.0
2.6
5
324.75
"259.94"
_220.35T
20
14.0
71.7
loo
50
Lead
8.0
Lithium
Magnesium
Manganese
Mercury
Molybdenu
Nickel
Potassium
Selenium
Silver ~
Sodium
Thallium
Tin
100
279.08
"257.61_
100
5
23.0
0.8
6.2
202.00
J231.60"
10
5.8
20
2.8
200
5
5
560
5
10
Vanadium
Zinc
10
_il3.86_
20
2.2
*
FORM X - IN ILM02.X
E-119
-------
WVJLUU -
U.S. EPA - CLP
10 .
Instrument DeteU-6t0
-
rsm
20
200
5
5
500
5
10
Vanadium
Zinc
10
20
-
nts:
FORM X - IN .ILMQ2.X
E-120
-------
Ross Analytical Services, Inc.
1643] Folkz MaftidfMtway - Slroncsvillc, Qiio 44136
OOOOOl
CERTIFICATE OF ANALYSIS
client:
Metco Environmental
16115 Dooloy Road
Dallas, TX 75244
HOrk Order ft: 96-02-151
Client Coda: METCO
Report Dates 03/04/96
Work ID: Dust for reanalysia
Date Received: 02/0B/96
Attn: Hanoch Toren
/
Purchase Order: Chapparal Steel/96-15
SAMPLE IDENTIFICATION
Lab
Number
01
Sample
Description
B Baghouse Dust
Lab
number
Sample
Description
Data are reported on an as-received basis unless stated other-
wise. Estimated Quantitation Limits (EQL1 s) are listed for
most analytes. EQL's are the lowest concentrations that can
be reliably measured under routine laboratory conditions,
unless otherwise noted, method blanks bad no targets found
above their EQL's and results were not corrected for blanks.
Carol L. Turner
E-3S8
-------
000002
Work Order # 96-02-151 Ross Analytical Services, Ino Reported! 03/04/SC
REPORT COMMENTS
Target hits were found for arsenic and antimony but these results were below
the reported SQL and reported as (ng/Xg)
Antimony 01 55.7 B 500
Arsenic 01 108 B 500
A duplicate of
this sample
was analyzed.
Metal
Result
(mg/Kg)
Antimony
60.0
B
Arsenic
93.3
B
Cadmium
544
Chromium
882
Copper
1510
Iron
134,000
Lead
17,900
Manganese
19,000
Molybdenum
35.7
B _
Nickel
285
Zinc
126,000
Laboratory Control Sample
Metal % Recovery
Antimony 131
Arsenic ill
Cadmium 110
Chromium 108
Copper 120
Iron 79
Manganese 99
Molybdenum 116
Nickel 109
Zinc 107
E-389
-------
000004 .
ark Order # 96-02-151 Ross Analytical Services, Inc Reported! 03/Q4/9S
»mr>la DescriDtionr
B Baghouse Dust
Lab Ho.* 01
iialvt* DaacriDtion
Result
Obits
KOI.
atiroony by ICP.
g/Kg
25
hromium by ICP
861
ng/Kg
50
3pper by ICP
1530
mg/Kg
xoo
con by ICP
133,000
*>g/Kg
1000
sad by ICP 1
18,200
mg/Kg
250
anganese by ICP
19,500
mg/Kg
25
alybdenum by ICP
46
mg/Kg
50
Lckel by ICP
287
mg/Kg
100
Lnc by ICP
128,000
mg/Kg
100
E-391
-------