02/24/2009 US EPA

CHLORAMINES-RELATED RESEARCH

18) What does EPA see as the disadvantages of using monochloramine?

Water utilities work with local and state regulatory agencies to determine if
monochloramine is appropriate for their utility.

•	The appropriateness of monochloramine use varies with water types and
among water utilities.1

•	The appropriateness of monochloramine use varies with the amount of
organic matter in the source water, temperature, rainfall, distance from the
treatment plant, and other factors.

•	EPA guidance is available to help states and water utilities make informed
decisions as to whether monochloramine use is appropriate.2

Gaps in research on how monochloramine affects water should be filled.

•	There are few studies on how monochloramine affects human health.

•	There are few studies on the disinfection byproducts that form when
monochloramine reacts with natural organic matter in water.

•	Compared to chlorine, water treated with monochloramine may contain
higher concentrations of some unregulated disinfection byproducts.1

Utilities using monochloramine should monitor water quality for problems3
that may arise related to monochloramine use.

•	Utilities using monochloramine should monitor for lead and other regulated
contaminants from metal corrosion that may be caused by
monochloramine use.2

•	Water utilities that add substances to control for metal corrosion must
comply with all relevant regulations related to these substances.

•	Water utilities using monochloramine should monitor and control for
biofilm activity as well as nitrite and nitrate formation.3

Additional Supporting Information:

1.	Use of monochloramine with source waters with high bromide, high iodide or high
total organic matter may lead to bromo-, iodo-, and nitrosamine disinfection byproduct
formation, which are unregulated disinfection byproducts. EPA scientists are currently
studying the unregulated disinfection byproducts that form in water treated with
monochloramine. See Question 7 for additional information about disinfection
byproducts.

2.	The addition of monochloramine can make water more corrosive, which may lead to
pipe corrosion and increased levels of lead or other contaminants in the water.

However, utilities can test water for corrosiveness and make changes to the water
treatment process to address this problem. EPA requires that systems monitor lead and
copper levels in the distribution system under the Lead and Copper Rule. Monitoring for
other water quality issues are discussed in guidance manuals. Guidance manuals are
available at: http://www.epa.gov/safewater/disinfection/staqe2/compliance.html. Hard
copies are available by ordering publications through EPA's Water Resource Center
(phone: 202-566-1729). EPA's simultaneous compliance manual can be found at:
http://www.epa.qov/OGWDW/disinfection/staqe2/pdfs/quide st2 pws simultaneous-
compliance. pdf. .

3.	See questions 2 and 27 for more information on contaminant release, biofilms, and
nitrification. High levels of nitrates/nitrites can be especially harmful to infants; additional
health effect information can be found at:

http://www.epa.gov/oqwdw/contaminants/dw contamfs/nitrates.html.


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