Chesterfield, SC NATTS Network Assessment Review
Established 2004: Carbonyls, PMio Metals, and VOCs
o Chromium VI added in 2005; ended in in 2013
o PAHs added in 2008
For the NATTS Network Assessment (2004-2018):
o 6 of 18 Method Quality Objective (MQO) Core HAPs were included in the national trends
¦ Acetaldehvde. Bcnzo(a)pvrcnc. Formaldehyde, and Naphthalene: Completeness less than 75% for
2018.
¦ Benzene: Reported MDL to NATTS Target MDL ratio greater than 2.0
¦ 1.3-Butadiene. Carbon Tetrachloride. Manganese (PMm). Tetrachloroethvlene. Trichloroethvlene.
and Vinyl Chloride: Reported MDL to NATTS Target MDL ratio greater than 2.0, Bias %
Difference was outside of ±35%, and Precision PCT CV was greater than 25%.
¦ Chloroform: Bias % Difference was outside of ±35%
o 185 of 248 pollutant datasets were suitable for trends analysis.
o Annual Average and 3-Year Rolling Average Concentrations were generally flat over time, with the
exception of some pollutants (benzene and naphthalene)
o 100% Reporting of Datasets
Method Quality Objectives (MQO): 2004-2018
o Completeness: Met 85% completeness in 237 of 248 pollutant datasets
o Method Detection Limits: Met MDL Target Ratio of 1.00 in 174 of 256 pollutant datasets
o Bias: Met ±25% for 174 of 220 pollutant datasets
o Overall Method Precision: Met <15% CV for 51 of 157 pollutant datasets
o Analytical Method Precision: Met <15% CV for 20 of 98 pollutant datasets
Analytical Laboratories for 2018
VOC
Carbonyl
PMio Metals
Chromium VI
PAHs
SCDHEC
SCDHEC
SCDHEC
NA
SCDHEC
Equipment Year Deployed
Equipment Type
VOC
Carbonyl
PMio Metals
Chromium VI
PAHs
Sampler
2001
2018
1989
2008
2001
Analytical
2016
2003
2015
2001
2000
Preconcentrator
2015
NA
NA
NA
NA
Standards Preparation
2014
NA
NA
NA
NA
Canister Cleaning
2018
NA
NA
NA
NA
Extraction
NA
NA
2011
2011
2015
-------
National Summary: NATTS data were collected at 27 locations across the United States,
with sites beginning in 2003 or later (Figure 1) for 19 core HAPs. Over 528,000 concentrations
(primary, secondary, and replicate) were generated and analyzed for this assessment. Pollutant
datasets were scored to assess whether they were suitable for trends analysis. Each
pollutant dataset was evaluated against four MQOs: Completeness; Sensitivity; Bias; and
Precision. Datasets that were suitable (A- or B-rated) for six consecutive years were used for
national trends analysis (Table 1).
National trends were determined by comparing the most recent 3-year blocked averages
(e.g., 2013-2015 vs. 2016-2018) to determine if the NATTS Trends DQO was being met:
To be able to detect a al5percent difference (trend) between the annual mean
concentrations of successive 3-year periods within acceptable levels of decision error.
Of the 19 core HAPs. 18 were assessed for the NATTS Trends DQO. Due to sampling and
analytical issues, acrolein was not considered for trends analysis (Table 2). This assessment
showed that across the network, 15 of those 18 pollutants were decreasing between the
3-year blocks, while two of those pollutants were increasing between the 3-year blocks.
One pollutant did not exhibit a trend.
Table 1. NATTS Network Assessment: Count and Percentage of Suitable
Datasets by Pollutant Group
Pollutant Group
A-rated
B-rated
Does Not Meet
#
%
#
%
#
%
VOCs
1,452
53%
737
27%
555
20%
Carbonyls
523
67%
193
25%
66
8%
PM10 Metals
1,418
61%
685
30%
213
9%
Chromium VI
159
74%
29
13%
27
13%
PAHs
410
74%
124
22%
18
3%
Total = 6,609
3,962
60%
1,768
27%
879
13%
Table 2. Three-Year Block Averages for National Trends
Pollutant
Units
# Sites
Block 1
Block 2
% Difference
Acetaldehyde
Hg/m3
19
1.51
1.39
-7.7%
Arsenic (PM10)
ng/m
21
0.71
0.68
-3.2%
Benzene
Hg/m3
19
0.65
0.59
-10.2%
Figure 1. NATTS Site and Year Established
Benzo(a)pyrene
ng/m3
21
0.113
0.087
-23.2%
Seattle, ,
Beryllium (PM10)
ng/m3
20
0.012
0.009
-26.4%
Butadiene, 1,3-
Hg/m3
19
0.071
0.063
-10.9%
Portland (#1), OR* Portland (#2), OR _ ^ / \
• > ' \ ; " I I >
Cadmium (PM10)
ng/m3
21
0.170
0.097
-43.0%
* »•* l | - Underbill.Vt
/l_a Grande (#1), OR*-' '"•••JL. • _ _ j ,,l M/ i ' \ f
} /. a V«?i-7S»" I s ') H or icon.' Wit' \ \ "-Roxbury. MA
j... ¦ La Grande (#2), OR i f c-/ . * ] Rochester, NY \ I ...-S
) / ; I | May ville.Wr >f, \~ V
/ i ! I -->.#/ \ Detroit; Ml f
- — — ; I i J \ j X. Providence, Rl
f / Bountiful'UT | X — \ ^f- .Bronx (#1), NY"
\ 1 ™ . \ Chicago, IL ¦ ; _ j \ S
_ X \ ' . 1, , Washington^D.C. "w
SanJoBB.CA j [ ^
, Grand Junction. CO V St Louis MO Grayson Lake. KY J ' Bronit (#2), NV"
\ \ _ ' 1 v. U-.--.'1" . ,-.v * Richmond. -VA
S \ _ : i . \ i i*/ '
. . . \ ' v • - — -1 _ Vs Hazard, KY*--^-""?" / j
Los Angeles, CA \J ; j_ | _ J _ r - "[¦/
- Rubidoux, CA i / £' y-""" /
• X: / >' ' 1 / T \Chesterf ield, SC
NATTS Sites phoenix.AZ / ; —J / 1 j. /
; i Karnack, TX ) South DeKalb, GA y
~ Rural \ j | J , > /
O Urban X \ t ; \ ,r(
NATTS - Year Established Houston, ri ^\
| 2003 "^T.mp,.FL
¦ 2004 \ Pinellas County, FL, 'i
1 "> ./ 'i. 1
¦ 2007 1 >
"ft
¦ 2008
| | 2009
2010
2016
?ni7 * The Hazare|. Mayville, Wl, La Grande <#1), OR, Portland (#1), OR, sites were relocated in 2008, 2009, 2016, and 2017, respectively.
"The Bronx (#1), NY site temporarily moved to the Bronx (#2), NY site from mid-2010 to mid-2012.
Carbon Tetrachloride
Hg/m3
15
0.59
0.56
-4.7%
Chloroform
Hg/m3
20
0.256
0.255
-0.4%
Chromium VI
ng/m
18
0.029
0.026
-7.7%
Formaldehyde
Hg/m3
19
2.77
2.68
-3.3%
Lead (PM10)
ng/m
21
3.08
2.81
-8.9%
Manganese (PM10)
ng/m3
20
8.06
7.93
-1.6%
Naphthalene
ng/m3
20
66.70
51.08
-23.4%
Nickel (PM10)
ng/m3
19
1.28
1.05
-18.0%
T etracliloroethylene
ng/m3
19
0.149
0.174
17.2%
T ricliloroethylene
ng/m3
19
0.020
0.022
10.7%
Vinyl Cliloride
ng/m3
17
0.0051
0.0048
-5.5%
Page 1 of 25
-------
NATTS Monitoring Site Report: Chesterfield, SC
Site Information Figure 2. NATTS Site Location
NATTS Site Type Rural
AQS Site Code
45-025-0001
NATTS Operating Agency
SC Dept. Health & Env. Control
Longitude
-80.198789
AQS Land Use Forest
AQS Location Setting Rural
10-Mile Population 46,197
Region
County
Chesterfield
Latitude
34.615367
Pollutant Datasets Evaluation: Suitable for Trends (Y=yes; Y(T)=yes, and used for DQQ Trends; N=No; "=not rated
Final Pollutant Name
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
Acetaldehyde
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Na
Arsenic (PM10)
Nb
Y
Y
Y
Y
Y
Y
Y
Y
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Benzene
-
Nb
Nb
Nb
Nb
Nb
Nb
Y
Y
Y
Y
Y
Y
Nb
Nb
Benzo(a)pyrene
-
-
-
~
Y
Y
Y
Y
Y
Y
Nc'd
Y
Y
Y
Na
Beryllium (PM10)
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Butadiene, 1,3-
--
Y
Y
Y
Nb
Nb
Nb
Nc
nm
Nb'd
Nb,d
Nb'd
nm
Nb
nm
Cadmium (PM10)
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Carbon tetrachloride
--
Nb
Nb
Nb
Nb
Nb
Nb
Ne
Y
Y
Y
Y
Y
Nb
Nb,d
Chloroform
-
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Nc
Chromium VI
--
Y
Y
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
—
—
~
~
~
—
Formaldehyde
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Na
Lead (PM10)
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Manganese (PM10)
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Ne
Y
Y
Y
Y
Naphthalene
~
--
~
~
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Na
Nickel (PM10)
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
Y(T)
T etrachloroethylene
--
Nb
Nb
Nb
Nb
Nb
Nb
Y
Y
Y
Y
Y
Nc
Nb
Nb'd
T richloroethylene
-
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Y
Nb
Nb'd
Vinyl chloride
~
Nb
Nb
Nb
Nb
Nb
Nb
Y
Y
N°'d
Y
Y
Nc
Nb
Nbd
a: Completeness was less than 75% based on l-in-6 day sampling.
b: Reported MDL to NATTS Target Ratio greater than 2.0
c: Bias % Difference was outside ± 35%.
d: Bias % Difference was outside ± 35%; Precision PCT CV was greater than
e: Analytical precision data (required since 2012) was not reported to EPA or
25%.
AQS for this pollutant.
Page 2 of 25
-------
Table 3. NATTS Network Assessment Data (2003-2018) - National Distribution Statistics By Type3
Analyte
Units
Site Type
# Data
Records
%
Detections
Arithmetic
Meanb
Percentile Value0
5th
10th
25th
50th
75th
90th
95th
Acetaldehyde
ng/m3
Urban
15,704
100%
1.77 ± 0.02
0.50
0.66
0.97
1.45
2.19
3.24
4.04
ng/m3
Rural
4,930
100%
1.20 ± 0.04
0.36
0.46
0.65
0.93
1.38
2.02
2.76
ng/m3
All Sites
20,634
100%
1.63 ± 0.02
0.44
0.58
0.86
1.31
2.00
3.02
3.86
Arsenic (PM10)
ng/m3
Urban
14,968
97%
0.89 ± 0.04
0.10
0.19
0.34
0.58
0.99
1.70
2.41
ng/m3
Rural
4,622
96%
0.49 ± 0.02
0.04
0.08
0.17
0.35
0.59
0.94
1.28
ng/m3
All Sites
19,590
97%
0.79 ± 0.03
0.06
0.14
0.29
0.52
0.89
1.54
2.19
Benzene
Hg/m3
Urban
15,984
99%
0.86 ± 0.01
0.25
0.30
0.43
0.66
1.05
1.64
2.21
Hg/m3
Rural
2,494
95%
0.43 ± 0.02
0.04
0.13
0.21
0.33
0.52
0.78
1.01
Hg/m3
All Sites
18,478
99%
0.81 ± 0.01
0.19
0.26
0.39
0.61
0.98
1.55
2.09
Benzo(a)pyrene
ng/m3
Urban
12,336
70%
0.096 ± 0.004
ND
ND
ND
0.04
0.11
0.24
0.37
ng/m3
Rural
3,179
36%
0.067 ± 0.009
ND
ND
ND
ND
0.02
0.13
0.37
ng/m3
All Sites
15,515
63%
0.090 ± 0.004
ND
ND
ND
0.03
0.10
0.23
0.37
Beryllium (PM10)
ng/m3
Urban
15,783
75%
0.051 ± 0.006
ND
ND
0.00003
0.005
0.018
0.050
0.101
ng/m3
Rural
4,687
49%
0.023 ± 0.003
ND
ND
ND
ND
0.005
0.017
0.072
ng/m3
All Sites
20,470
69%
0.045 ± 0.005
ND
ND
ND
0.003
0.012
0.049
0.100
Butadiene, 1,3-
Hg/m3
Urban
15,388
81%
0.092 ± 0.002
ND
ND
0.025
0.058
0.114
0.215
0.302
ng/m3
Rural
2,185
29%
0.012 ± 0.001
ND
ND
ND
ND
0.017
0.046
0.059
ng/m3
All Sites
17,573
75%
0.082 ± 0.002
ND
ND
ND
0.049
0.104
0.199
0.287
Cadmium (PM10)
ng/m3
Urban
16,360
92%
0.21 ± 0.02
ND
0.01
0.05
0.09
0.17
0.42
0.63
ng/m3
Rural
4,684
87%
0.10 ± 0.01
ND
ND
0.03
0.06
0.11
0.20
0.29
ng/m3
All Sites
21,044
91%
0.18 ± 0.01
ND
0.01
0.04
0.08
0.16
0.35
0.56
Carbon Tetrachloride
ng/m3
Urban
14,713
99%
0.569 ± 0.003
0.361
0.433
0.496
0.562
0.651
0.737
0.798
ng/m3
Rural
2,189
92%
0.534 ± 0.016
ND
0.180
0.402
0.537
0.633
0.727
0.798
ng/m3
All Sites
16,902
98%
0.565 ± 0.003
0.304
0.408
0.490
0.559
0.649
0.736
0.798
Chloroform
ng/m3
Urban
16,068
87%
0.265 ± 0.022
ND
ND
0.093
0.132
0.217
0.420
0.668
ng/m3
Rural
3,802
43%
0.052 ± 0.003
ND
ND
ND
ND
0.095
0.144
0.230
ng/m3
All Sites
19,870
79%
0.224 ± 0.018
ND
ND
0.064
0.113
0.196
0.364
0.586
Chromium VI
ng/m3
Urban
8,414
74%
0.036 ± 0.002
ND
ND
ND
0.020
0.042
0.081
0.120
ng/m3
Rural
2,586
41%
0.018 ± 0.004
ND
ND
ND
ND
0.017
0.031
0.051
ng/m3
All Sites
11,000
66%
0.032 ± 0.001
ND
ND
ND
0.016
0.036
0.073
0.114
Page 3 of 25
-------
Table 3. NATTS Network Assessment Data (2003-2018) - National Distribution Statistics By Type3
Analyte
Units
Site Type
# Data
Records
%
Detections
Arithmetic
Meanb
Percentile Value0
5th
10th
25th
50th
75th
90th
95th
Formaldehyde
ng/m3
Urban
16,118
100%
3.11 ± 0.04
0.66
0.99
1.60
2.47
3.84
5.63
7.25
ng/m3
Rural
5,002
100%
2.22 ± 0.05
0.53
0.68
1.06
1.69
2.74
4.19
5.45
ng/m3
All Sites
21,120
100%
2.90 ± 0.04
0.61
0.86
1.43
2.29
3.59
5.38
6.96
Lead (PM10)
ng/m3
Urban
16,366
100%
4.21 ± 0.13
0.72
0.98
1.55
2.64
4.56
8.35
11.90
ng/m3
Rural
4,680
99%
2.10 ± 0.16
0.37
0.50
0.84
1.41
2.37
3.91
5.36
ng/m3
All Sites
21,046
99%
3.74 ± 0.11
0.55
0.80
1.31
2.31
4.04
7.41
10.56
Manganese (PM10)
ng/m3
Urban
16,141
100%
9.80 ± 0.32
1.09
1.51
2.52
4.92
10.21
20.10
30.08
ng/m3
Rural
4,627
99%
3.96 ± 0.14
0.46
0.73
1.36
2.57
4.75
8.54
12.13
ng/m3
All Sites
20,768
100%
8.50 ± 0.25
0.85
1.23
2.15
4.18
8.89
17.98
26.70
Naphthalene
ng/m3
Urban
12,332
100%
74.63 ± 1.14
15.62
21.27
33.55
55.89
94.64
150.05
196.16
ng/m3
Rural
3,301
100%
24.47 ± 1.38
3.74
4.73
7.74
13.86
26.25
50.88
79.17
ng/m3
All Sites
15,633
100%
64.04 ± 1.00
6.58
10.92
23.37
45.59
83.31
137.54
181.75
Nickel (PM10)
ng/m3
Urban
16,125
97%
1.85 ± 0.05
0.25
0.41
0.67
1.11
2.00
3.52
5.27
ng/m3
Rural
4,623
85%
0.65 ± 0.08
ND
ND
0.10
0.28
0.64
1.15
1.89
ng/m3
All Sites
20,748
94%
1.58 ± 0.04
ND
0.15
0.47
0.92
1.73
3.14
4.74
T etrachloroethylene
Hg/m3
Urban
15,612
86%
0.25 ± 0.01
ND
ND
0.06
0.13
0.25
0.48
0.74
Hg/m3
Rural
2,272
36%
0.09 ± 0.04
ND
ND
ND
ND
0.04
0.08
0.16
Hg/m3
All Sites
17,884
79%
0.23 ± 0.01
ND
ND
0.04
0.11
0.22
0.44
0.70
T richloroethylene
Hg/m3
Urban
15,843
41%
0.040 ± 0.002
ND
ND
ND
ND
0.051
0.107
0.164
ng/m3
Rural
3,388
13%
0.021 ± 0.003
ND
ND
ND
ND
ND
0.017
0.250
ng/m3
All Sites
19,231
36%
0.037 ± 0.002
ND
ND
ND
ND
0.041
0.105
0.167
Vinyl Chloride
ng/m3
Urban
14,778
19%
0.0044 ± 0.0003
ND
ND
ND
ND
ND
0.0137
0.0257
ng/m3
Rural
2,444
8%
0.0040 ± 0.0009
ND
ND
ND
ND
ND
ND
0.0156
ng/m3
All Sites
17,222
17%
0.0043 ± 0.0003
ND
ND
ND
ND
ND
0.0126
0.0254
3 Statistics presented are from pollutant datasets which were suitable for trends.
b The arithmetic mean is the average of all samples results which include actual measured values. If no chemical was registered, then a value of zero is
used when calculating the mean.
c ND: No results of this chemical were registered by the laboratory analytical equipment.
Page 4 of 25
-------
Table 4. Summary Statistics for Chesterfield, SC
Analyte
Units
# Data
Records
%
Detection
Arithmetic Mean3
Percentile Va
b
ue
5th
10th
25th
50th
75th
90th
95th
Acetaldehyde
(ig/m3
866
99%
2.02 ± 0.17
0.41
0.66
0.96
1.33
2.04
4.14
5.60
Arsenic (PM10)
ng/m3
886
92%
0.61 ± 0.09
ND
0.07
0.26
0.43
0.67
0.96
1.23
Benzene
(ig/m3
861
74%
0.35 ± 0.03
ND
ND
ND
0.23
0.43
0.78
1.30
Benzo(a)pyrene
ng/m3
602
12%
0.008 ± 0.003
ND
ND
ND
ND
ND
0.03
0.05
Beryllium (PM10)
ng/m3
886
36%
0.0074 ± 0.0023
ND
ND
ND
ND
0.003
0.023
0.031
Butadiene, 1,3-
l-tg/m3
857
8%
0.013 ± 0.004
ND
ND
ND
ND
ND
ND
0.109
Cadmium (PM10)
ng/m3
886
86%
0.13 ± 0.01
ND
ND
0.06
0.11
0.16
0.23
0.31
Carbon Tetrachloride
l-tg/m3
861
63%
0.51 ± 0.05
ND
ND
ND
0.39
0.52
1.22
2.45
Chloroform
l-tg/m3
861
15%
0.019 ± 0.004
ND
ND
ND
ND
ND
0.096
0.106
Chromium VI
ng/m3
490
32%
0.006 ± 0.001
ND
ND
ND
ND
0.008
0.019
0.025
Formaldehyde
l-tg/m3
866
100%
4.19 ± 0.20
1.22
1.52
2.19
3.30
5.09
8.50
11.42
Lead (PM10)
ng/m3
886
96%
2.48 ± 0.79
0.29
0.58
0.99
1.58
2.42
3.67
4.48
Manganese (PM10)
ng/m3
886
99%
4.61 ± 0.43
0.68
0.93
1.61
2.69
4.84
10.15
14.98
Naphthalene
ng/m3
602
99%
13.87 ± 1.39
3.53
4.31
6.27
10.18
16.10
25.84
35.04
Nickel (PM10)
ng/m3
886
69%
1.64 ± 0.43
ND
ND
ND
0.54
1.36
3.33
5.30
T etrachloroethylene
l-tg/m3
861
10%
0.121 ± 0.043
ND
ND
ND
ND
ND
ND
0.139
T richloroethylene
l-tg/m3
861
1%
0.009 ± 0.009
ND
ND
ND
ND
ND
ND
ND
Vinyl Chloride
l-tg/m3
861
1%
0.0014 ± 0.0019
ND
ND
ND
ND
ND
ND
ND
3 :The arithmetic mean is the average of all samples results which included actual measured values. If no chemical was registered, then a value of zero is used.
bND: No results of this chemical were registered by the laboratory analytical equipment.
Table 5. Analytical Labs Supporting this Site
Pollutant Group
2003
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
VOCs
--
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
Carbonyls
--
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
PM10 Metals
--
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
SCDHEC
Chromium VI
--
--
ERG
ERG
ERG
ERG
ERG
ERG
ERG
ERG
ERG
--
--
--
--
—
PAHs
--
--
--
--
--
ERG
ERG
ERG
ERG
ERG
ERG
ERG
SCDHEC
SCDHEC
SCDHEC
SCDHEC
—: Not Applicable
SCDHEC: South Carolina Department of Health and Environmental Control
ERG: Eastern Research Group, Inc.
Page 5 of 25
-------
Figure 3. Chesterfield, SC Annual Average Concentrations
8.0
6.0
lb
o
O
4.0
2.0
0.0
Chesterfield, SC
Annual Averages:
Acetaldehvde
T i
o
~
J 1 i
£ i * 5 * » « « *
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
3.0 -r
Ib
3 1.8
o
0
o
u
0.6
0.0
Chesterfield, SC
Annual Averages:
Arsenic (PM10)
~—~
~ *
i *
i 5
* *
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
"6b
1.0
0.8
0.6
!= 0.4
&
3 °-:
0.0
Chesterfield, SC
Annual Averages:
Benzene
i+1
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
0.05
0.04
lb
0.03
U 0.02
§
u
o
o o.oi
0.00
Chesterfield, SC
Annual Averages:
Benzo(a)pyrene
2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
Page 6 of 25
-------
0.05
0.04
*-*
¦¦—'
S3
0.03
0.02
0.01
0.00
Figure 3. Chesterfield, SC Annual Average Concentrations
Chesterfield, SC
Annual Averages:
Beryllium (PM10)
i
rr
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
0.20
0.16
"fci
0.12
_o
t® 0.08
0.04
0.00
Chesterfield, SC
Annual Averages:
1,3-Butadiene
-~—i—~—i—~—i 1 i 1 1 1 1 1 [ 1 1 1
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
o
O
0.5
0.4
0.3
0.1
0.0
Chesterfield, SC
Annual Averages:
Cadmium (PM10)
i i I
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
1.5
la*
.2 l.o
o 0.5
u
0.0
Chesterfield, SC
Annual Averages:
Carbon Tetrachloride
i
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
Page 7 of 25
-------
Figure 3. Chesterfield, SC Annual Average Concentrations
~CJj
o.io
0.08
0.06
g 0.04
G
8 0 02
0.00
Chesterfield, SC
Annual Averages:
Chloroform
~ i ~ i ~ i ~
~ I ~ I ~
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
Chesterfield, SC
Annual Averages:
Formaldehyde
10.0
8.0
6.0
CO
a 4.0
o
u
0.0
i *¦
i
M i x
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
'a
3
ta
0.025
0.020
0.015
0.010
Q 0.005
0.000
Chesterfield, SC
Annual Averages:
Hexavalent Chromium
*
2005 2006 2007 2008 2009 2010 2011 2012 2013
Year
20.0
16.0
a
SJJ 12.0
re 8.0
h
s
o
O
4.0
0.0
Chesterfield, SC
Annual Averages:
Lead (PM10)
» ~ ~ * ~
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
Page 8 of 25
-------
24.0
20.0
f—l
"Sj 16.0
¦ 2 12.0
cz
^ 8.0
4.0
0.0
o
U
Figure 3. Chesterfield, SC Annual Average Concentrations
Chesterfield, SC
Annual Averages:
Manganese (PM10)
1—
o
o
--
J * » * » , i ,
*
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
50.0
40.0
% 300
20.0
o
U
10.0
0.0
I
Chesterfield, SC
Annual Averages:
Naphthalene
f
I
2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
12.0
10.0
8.0
¦a 6.0
o
u
4.0
2.0
0.0
Chesterfield, SC
Annual Averages:
Nickel (PM10)
i .
1
1 1 1 1 1 1 1 1 *—i 1 « * 1 1 1 1
2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year'
2.0
1.6
I u
2 o.s
O 0.4
O
0.0
Chesterfield, SC
Annual Averages:
Tetrachloroethvlene
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
Page 9 of 25
-------
Figure 3. Chesterfield, SC Annual Average Concentrations
"St
0.15
0.12
0.09
0.06
§
o
6 0 03
0.00
Chesterfield, SC
Annual Averages:
Trichloroethylene
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
0.010
0.008
•—-
o
to
o
O
0.006
0.004
0.002
0.000
Chesterfield, SC
Annual Averages:
Vinyl Chloride
2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 2015 2016 2017 2018
Year
Does not meet MQO
Page 10 of 25
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
"Sk
11
u
O
u
5.0
4.0
3.0
1.0
0.0
Chesterfield, SC
3-Year Rolling Averages:
Acetaldehyde
i
I—
T
^ ^
"°06 -°0? "%> -°09 °J0 °Jj °/y °/j °/ 2o0s -?%, ^7/ ^ 4^ -?07j. ^/ff
Years
Page 11 of 25
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
1.0
0.8
etj
.2 06
ro
s
u
O 0.4
O
0.0
ii
Chesterfield, SC
3-Year Rolling Averages:
Benzene
f
4-4
1
f
i i
"V, "V,
°Jj -°/j °/j "/y °J6 -0/? "°/8
Years
Chesterfield, SC
3-Year Rolling Averages:
Benzo(a)pyrene
0.030
0.024
~Ob
.2 0.018
O 0.012
U
0.006
0.000
<
~
i
~
~
<
~
<~
i
~
<*%, ¦?(?/ -?Oy •?% -0/? -?«, -%/„ -?
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
"oil
D
a
0.030
0.024
0.018
° 0.012
0.006
0.000
f
Chesterfield, SC
3-Year Rolling Averages:
Beryllium (PM10)
* M .
^ -% *0; 10,2 2o, lo, *0, lOj
"% -%> -% -O/J -/s io,6 ?oJ? ?Ojs
Years
Chesterfield, SC
3-Year Rolling Averages:
1,3-Butadiene
0.5
0.4
"3b
.2 0.3
03
O 0.2
U
0.1
i
0.0
^
-°0} %> "°09 ^°J0 -O//
Years
"% ^ ^
Page 13 of 25
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
a
r—j
o
S
o
U
0.30
0.24
0.18
0.12
0.06
0.00
Chesterfield, SC
3-Year Rolling Averages:
Cadmium (PM10)
1
—1
i
<~
~
1
<
¦ , i I 1 H t .
~
—4
~
*
*°Os^ *°0? ioOg ^
-°// °/j ^°/ ^ ^ *5% ^
Years
Page 14 of 25
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
Sb
^
Years
Page 15 of 25
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
0.020
Chesterfield, SC
3-Year Rolling Averages:
Hexavalent Chromium
0.016
"fb
a
o 0.012
£3
8
o
U
0.008
0.004
4
t
i
i
4
0.000
'S-y,
O0y
% °Qs> %
Years
*>4
-°y.
a
'4?
-'ft
•? *&Ox> ^Oo i ^/j ^/, -'o/
X %, %, %, % % %, % X X X %»
Years
Page 16 of 25
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
"Sj
&
s
u
o
U
15.0
12.0
9.0
6.0
3.0
0.0
Chesterfield, SC
3-Year Rolling Averages:
Manganese (PM10)
j T
T
<> <>
I
T ^ ^ i
* * * * #
#
"V, ^ "V, "V, ^ ^/A, ^ ^ ^
*•% °0? *-°0$ *-°Og "0/0 ^0// 20/j 2oJ
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
"a
6.0
4.8
3.6
s
O 7
o
U
4
0.0
* *
Chesterfield, SC
3-Year Rolling Averages:
Nickel (PM10)
4
^ ^ lOj lOj 20, lOj 20/ ?Ot *>,
-%¦ ¦?% -% &// *o,3 ^ ?0js
-------
Figure 4. Chesterfield, SC - 3-Year Rolling Average Concentrations
Chesterfield, SC
3-Year Rolling Averages:
Trichloroethylene
~5fc
a
C
o
c
53
o
c
o
U
0.10
0.08
0.06
0.04
0.02
0.00
—* ~ A—,—~—,—
. . . I
*
2°o -?o0 2o0>
-------
Table 6. NATTS Network Assessment: MQO#l - Completeness Percentage at Chesterfield, SC
Pollutant Group
Year
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
Carbonyl
Acetaldehyde
92
95
97
100
100
100
95
95
95
98
92
95
98
98
72
Carbonyl
Formaldehyde
92
95
97
100
100
100
95
95
95
98
92
95
98
98
72
Chromium VI
Chromium VI
—
90
97
97
100
95
102
98
82
—
—
—
—
—
—
PAH
Benzo(a)pyrene
--
--
--
--
100
90
95
98
87
95
92
98
100
97
59
PAH
Naphthalene
—
—
—
—
100
90
95
98
87
95
92
98
100
97
59
PM10 Metals
Arsenic (PM10)
97
98
95
98
97
100
100
98
95
97
92
93
98
98
34
PM10 Metals
Beryllium (PM10)
97
98
95
98
97
100
100
98
95
97
92
93
98
98
34
PM10 Metals
Cadmium (PM10)
97
98
95
98
97
100
100
98
95
97
92
93
100
98
34
PM10 Metals
Lead (PM10)
97
98
95
98
97
100
100
98
95
97
92
93
98
98
34
PM10 Metals
Manganese (PM10)
97
98
95
98
97
100
100
98
95
97
92
93
98
98
34
PM10 Metals
Nickel (PM10)
97
98
95
98
97
100
100
98
95
97
92
93
98
98
34
voc
Benzene
--
100
98
100
100
100
100
100
97
100
97
87
100
100
87
voc
Butadiene, 1,3-
—
100
98
100
100
100
93
100
97
100
97
87
100
100
87
voc
Carbon tetrachloride
—
100
98
100
100
100
100
100
97
100
97
87
100
100
87
voc
Chloroform
—
100
98
100
100
100
100
100
97
100
97
87
100
100
87
voc
T etrachloroethylene
—
100
98
100
100
100
100
100
97
100
97
87
100
100
87
voc
T richloroethylene
—
100
98
100
100
100
100
100
97
100
97
87
100
100
87
voc
Vinyl chloride
--
100
98
100
100
100
100
100
97
100
97
87
100
100
87
A-rated: >85%
B-rated: Between 75% to 85%
Does not meet: <75%
No data available
a: Pollutant was expected, but not sampled at this site for this year.
Page 20 of 25
-------
Table 7. NATTS Network Assessment: MQO#2 - Reported Method Detection Limits (MDLs) at Chesterfield, SC
Pollutant
Group
Pollutant Name
Target
MDL
Units
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
Carbonyl
Acetaldehyde
0.45
pg/m3
0.36
0.38
0.38
0.40
0.38
0.44
0.44
0.50
0.50
0.44
0.22
0.18
0.38
0.39
0.06
Carbonyl
Formaldehyde
0.98/0.08a
US/m3
0.16
0.17
0.17
0.20
0.23
0.25
0.25
0.26
0.24
1.88
0.86
0.86
1.70
1.71
0.20
Chromium VI
Chromium VI
0.08
ng/m"
--
0.22
0.14
0.09
0.08
0.05
0.01
0.05
0.04
0.05
--
--
--
--
--
PAH
Benzo(a)pyrene
0.91
ng/m"
~
--
--
--
0.08
0.07
0.04
0.05
0.06
0.06
0.0003
0.03
0.07
0.00
0.07
PAH
Naphthalene
29.00
ng/m"
~
--
--
--
0.016
0.009
0.012
0.004
0.005
0.007
0.00001
0.00003
0.003
0.000
0.003
PM10 Metals
Arsenic (PM10)
0.23
ng/m"
6.09
0.13
0.13
0.13
0.13
0.13
0.01
0.12
0.12
0.12
0.12
0.12
0.12
0.12
0.09
PM10 Metals
Beryllium (PM10)
0.42
ng/m"
0.67
0.004
0.004
0.002
0.002
0.002
0.008
0.003
0.003
0.003
0.003
0.003
0.003
0.017
0.010
PM10 Metals
Cadmium (PM10)
0.56
ng/m"
0.03
0.002
0.002
0.002
0.002
0.002
0.003
0.002
0.002
0.002
0.002
0.002
0.002
0.002
0.020
PM10 Metals
Lead (PM10)
15.0
ng/m"
0.004
0.0002
0.0002
0.0002
0.0002
0.0002
0.000
0.0002
0.0002
0.0002
0.0002
0.0002
0.0002
0.0003
0.075
PM10 Metals
Manganese (PM10)
5.0
ng/m"
0.011
0.0005
0.0005
0.0004
0.0004
0.0004
0.001
0.0004
0.0004
0.0004
0.0004
0.0004
0.0004
0.0035
0.05
PM10 Metals
Nickel (PM10)
2.1
ng/m"
0.67
0.001
0.001
0.001
0.001
0.001
0.013
0.001
0.001
0.001
0.001
0.001
0.001
0.02
0.49
voc
Benzene
0.13
l-tg/m"
2.31
2.31
2.31
2.68
3.68
4.43
3.05
0.34
0.88
0.88
0.88
0.88
0.88
5.78
5.78
voc
Butadiene, 1,3-
0.10
l-tg/m"
2.00
2.00
2.00
1.91
4.11
5.32
3.67
1.68
2.21
2.21
2.21
2.21
2.21
3.85
3.85
voc
Carbon tetrachloride
0.17
l-tg/m"
3.53
3.53
3.53
5.55
7.59
6.31
6.96
1.15
1.33
1.33
1.33
1.33
1.33
8.51
8.51
voc
Chloroform
0.50
l-tg/m"
1.00
1.00
1.00
1.33
1.81
0.88
1.39
0.22
0.41
0.41
0.41
0.41
0.41
1.02
1.02
voc
Tetrachloroethylene
0.17
l-tg/m"
4.12
4.12
4.12
7.44
9.69
6.79
7.06
0.84
1.08
1.08
1.08
1.08
1.08
7.18
7.18
voc
Trichloroethylene
0.5/0.2a
l-tg/m"
1.00
1.00
1.00
1.93
1.92
1.94
1.98
0.28
0.39
0.97
0.97
0.97
0.97
5.35
5.35
voc
Vinyl chloride
0.11
l-tg/m"
2.73
2.73
2.73
2.68
3.81
3.73
3.81
0.81
1.32
1.32
1.32
1.32
1.32
2.05
2.05
A-rated: MDL to Target MDL ratio < 1
B-rated" MDL to Target MDL ratio between 1 and 2
Does Not Meet MDL to Target MDL ratio>2
No data available
a: For the 2012 sampling year, the Target MDL for this pollutant was reduced.
Page 21 of 25
-------
Table 8. NATTS Network Assessment: MQO#3 - Bias Percent Difference at Chesterfield, SC
Pollutant Group
Pollutant Name
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
Carbonyls
Acetaldehyde
7.0
11.9
-4.4
-5.8
6.3
-7.9
a
-1.0
b
9.2
9.4
b
-2.1
0.9
-5.0
Carbonyls
Formaldehyde
3.5
8.5
-13.9
-10.2
19.2
1.6
a
6.6
b
16.6
8.4
b
1.6
7.1
13.1
Chromium VI
Chromium VI
--
b
b
b
b
-5.6C
10.5C
b
19.5
-6.5
--
--
--
--
--
PAH
Benzo(a)pyrene
--
--
--
--
b
-1.7
-2.3
-2.1
25.2
-5.7
-42.9
0.4
-33.3
-27.1
-28.1
PAH
Naphthalene
--
--
--
--
b
-7.7
-17.1
-13.9
21.4
25.5
-33.0
-68.9
-14.2
-22.4
-22.6
PM10 Metals
Arsenic (PM10)
-15.4
d
-5.6
11.2
6.1
4.0
-32.6
-15.1
-11.7
-11.4
-14.4
b
6.0
23.6
-11.8
PM10 Metals
Beryllium (PM10)
-11.4
d
-2.2
12.4
-5.5
9.7
-19.2
-14.8
-4.5
-1.9
e
b
4.6
17.8
-7.5
PM10 Metals
Cadmium (PM10)
-0.5
d
-16.3
-6.7
-4.6
-0.5
-24.9
-8.0
3.9
-1.0
e
b
27.5
15.2
-11.9
PM10 Metals
Lead (PM10)
6.5
d
19.2
2.1
OO
00
-5.1
-28.4
13.7
21.8
18.3
3.3
b
0.6
10.7
-14.7
PM10 Metals
Manganese (PM10)
11.1
d
-1.2
-1.1
-16.0
0.8
-6.1
12.4
15.9
0.7
155.3
b
86.6
66.3
-7.7
PM10 Metals
Nickel (PM10)
3.6
d
-5.4
-3.5
4.2
-9.3
-5.2
3.0
-5.0
7.4
f
b
52.5
46.0
8.9
voc
Benzene
-24.0
7.5
7.4
-0.1
-7.7
-24.3
-18.7
-41.9
b
-22.7
-39.2
-20.6
-36.0
13.8
-16.5
voc
Butadiene, 1,3-
703.7
14.9
8.0
-17.1
-14.3
19.7
9.8
-42.1
b
83.8
-19.7
-7.2
-30.2
10.1
-28.3
voc
Carbon tetrachloride
0.0
-6.6
17.8
11.7
-13.2
-34.5
-24.5
-38.6
b
-25.0
-25.8
26.9
-12.8
23.8
-43.9
voc
Chloroform
-14.4
-12.9
1.2
-3.7
-11.6
-27.9
-24.7
-45.8
b
-20.1
-10.3
-16.0
-35.4
0.4
-42.2
voc
T etrachloroethylene
-23.1
2.1
-3.6
0.7
-16.7
-6.0
-16.1
-32.8
b
-27.6
-20.0
5.9
38.6
2.0
-24.3
voc
T richloroethylene
d
2.7
16.5
-7.6
-16.8
-8.6
-22.9
-38.7
b
-18.9
-10.6
26.1
-28.0
-7.6
-24.1
voc
Vinyl chloride
102.9
-18.0
-8.4
4.5
-31.0
-20.7
-23.5
-37.7
b
93.7
-6.5
34.6
-38.3
-7.9
-57.3
A-rated:±25%
B-rated: Between 25% to 35% or between -25% to -35%
Doesnotmeet:>35%or<35%
No data available
a: Although this pollutant was sampled for at this site and year, the laboratory equipment was not operating at the time the Proficiency Test sample was sent.
b: No Proficiency Test samples were sent for this pollutant and year.
c: Proficiency Test results are from the National Contract Lab for EPA's School Air Toxics Monitoring Program. The %Difference was -5.55% in 2009 and 10.53% in 2010.
d: Pollutant was sampled at this site and year, but no bias data were reported.
e: The Proficiency Test sample for this pollutant was 0; the site reported a concentration as "< MDL", rather than 0. EPA accepted this result.
f: Although a Proficiency Test sample was sent to the lab supporting this site and year, the results were nullified by EPA due to QA issues.
Page 22 of 25
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Table 9. NATTS Network Assessment: MQO#4 - Overall Method Precision %CV at Chesterfield, SC
Pollutant Group
Pollutant Name
Overall Method precision % CV
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
Carbonyls
Acetaldehyde
57.2
29.2
26.8
18.7
13.0
10.9
19.2
14.7
9.3
OO
*00
8.2
25.8
63.0
17.9
10.0
Carbonyls
Formaldehyde
57.2
12.4
21.0
17.6
12.5
10.4
14.0
14.6
6.7
11.2
12.0
35.4
64.0
17.5
15.0
Chromium VI
Chromium VI
--
49.8
a
a
13.0
26.5
33.8
8.9
9.7
a
—
--
—
--
—
PAH
Benzo(a)pyrene
--
--
--
--
--
--
—
--
—
--
a
a
a
a
a
PAH
Naphthalene
--
--
--
--
--
--
—
--
—
--
37.5
22.9
21.0
29.4
24.0
PM10 Metals
Arsenic (PM10)
4.4
15.0
20.0
19.0
11.6
25.8
24.8
35.3
19.4
31.7
40.4
18.1
22.4
19.9
10.9
PM10 Metals
Beryllium (PM10)
a
20.1
12.8
10.8
5.2
a
90.1
a
53.8
36.1
51.3
13.6
141.4
56.6
15.1
PM10 Metals
Cadmium (PM10)
36.5
32.3
29.4
40.1
22.3
45.7
62.9
37.9
31.4
37.5
41.4
47.8
60.8
43.3
41.0
PM10 Metals
Lead (PM10)
27.4
16.1
33.8
27.3
15.3
39.1
69.2
37.5
34.0
27.3
35.6
30.6
29.3
21.2
14.4
PM10 Metals
Manganese (PM10)
41.6
O©
*oo
20.8
27.4
15.6
14.4
44.4
32.7
34.8
28.4
25.5
29.3
22.3
10.7
9.4
PM10 Metals
Nickel (PM10)
81.0
31.8
52.1
72.2
63.8
66.6
74.4
57.7
65.6
94.1
89.6
28.9
24.2
35.3
a
voc
Benzene
23.0
20.9
22.8
OO
*00
32.3
a
6.2
8.5
7.6
13.6
15.5
10.4
15.4
3.9
32.9
voc
Butadiene, 1,3-
a
a
a
a
a
a
3.1
a
a
a
a
a
a
a
a
voc
Carbon tetrachloride
a
7.4
15.7
a
6.4
a
a
3.5
5.4
11.1
8.9
15.1
11.4
a
a
voc
Chloroform
a
a
a
a
a
a
a
a
a
a
a
61.7
12.9
a
a
voc
T etrachloroethylene
a
10.1
a
a
a
a
a
14.7
1.0
a
a
a
a
a
a
voc
T richloroethylene
a
a
a
a
a
a
a
0
a
a
a
a
a
a
a
voc
Vinyl chloride
a
a
a
a
a
a
a
a
a
a
a
a
a
a
a
A-rated:< 15% CV
B-rated: Between 15%CV to25% CV
Does Not Meet: >25% CV or did not report Precision (required in the NATTS Workplan Template since 2012)
No data available
a: Although both primary and secondary data were reported, both sets of values were less than the MDL. Thus no %CV was calculated.
Page 23 of 25
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Table 10. NATTS Network Assessment: MQO#4 - Analytical Precision %CV at Chesterfield, SC
Pollutant Group
Pollutant Name
Analytical Method precision % CV
2004
2005
2006
2007
2008
2009
2010
2011
2012
2013
2014
2015
2016
2017
2018
Carbonyls
Acetaldehyde
—
—
—
—
—
—
~
—
a
a
a
a
a
b
0.7
Carbonyls
Formaldehyde
—
—
—
—
—
—
~
—
a
a
a
a
a
b
0.7
Chromium VI
Chromium VI
--
~
4.0
13.2
10.2
15.5
10.9
6.7
4.1
a
--
--
--
--
--
PAH
Benzo(a)pyrene
—
—
—
—
—
—
--
—
a
a
a
a
a
a
b
PAH
Naphthalene
—
—
—
—
—
—
~
—
2.5
1.1
1.9
a
a
a
1.3
PM10 Metals
Arsenic (PM10)
--
--
--
--
--
--
~
--
a
a
a
a
b
b
b
PM10 Metals
Beryllium (PM10)
--
~
--
--
--
~
~
--
a
a
a
a
b
b
b
PM10 Metals
Cadmium (PM10)
--
~
~
~
~
--
~
~
a
a
a
a
b
b
b
PM10 Metals
Lead (PM10)
~
--
~
~
~
~
--
~
a
a
a
a
0.7
2.3
b
PM10 Metals
Manganese (PM10)
~
~
--
~
~
~
~
--
a
a
a
a
6.7
9.0
b
PM10 Metals
Nickel (PM10)
~
~
~
--
~
~
~
~
a
a
a
a
34.8
b
b
voc
Benzene
—
—
—
—
—
—
~
—
a
a
a
a
14.5
2.0
b
voc
Butadiene, 1,3-
—
—
—
—
—
—
~
—
a
a
a
a
a
b
a
voc
Carbon tetrachloride
—
—
—
—
—
—
--
—
a
a
a
a
5.9
b
b
voc
Chloroform
--
--
--
~
--
--
~
--
a
a
a
a
12.9
b
b
voc
T etrachloroethylene
—
—
—
—
—
—
~
—
a
a
a
a
b
b
a
voc
T richloroethylene
~
~
~
--
--
~
~
~
a
a
a
a
b
b
a
voc
Vinyl chloride
--
~
~
~
~
--
~
~
a
a
a
a
b
b
a
A-rated:< 15% CV
B-rated: Between 15%CV to25% CV
Does Not Meet: >25% CV or did not report Precision (required in the NATTS Workplan Template since 2012)
No data available
a: Per the NATTS Workplan template, analytical replicates were required to be reported to AQS for this sampling year
b: The primary and/or replicate value were less than the MDL, so no calculation could be made.
Page 24 of 25
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Appendix A: Equipment Inventory
Pollutant Type Year(s) Manufacturer/Model, Extraction Type, and Year
Sampling Equipment
Carbonyls
2004
ATEC model 100 (Year Deployed: 2001)
2005-2017
ATEC model 2200 (2 units) (Year Deployed: 2005)
2018
ATEC 2200 (Year Deployed: 2018)
Chormium VI
2005-2007
ERG Chromium VI sampler (Year Deployed: 2005)
2008-2013
ERG Chromium VI sampler (Year Deployed: 2008)
PAHs
2008-2010
Andersen GPS-1 PUF Sampler (Year Deployed: 1990)
2011-2011
Thermo Andersen GPS-1 PUF Sampler (Year Deployed: 2000)
2012-2018
General Metal Works Model No. PS-1 (2 Units) (Year Deployed: 2001)
PM10 Metals
2004-2011
Andersen Hi-Volume PM 10 Sampler (Year Deployed: 1989)
2012-2018
General Metal Works Hi-Vol Model UV15H (2 units) (Year Deployed: 1989)
VOCs
2004-2018
Thermo-Anderson AVOCs (Year Deployed: 2001)
Analytical Equipment
Carbonyls
2004-2018
Hitachi LaChrome Elite (Year Deployed: 2003)
Chormium VI
2005-2013
Dionex 300 ion chromatography system (Year Deployed: 2001)
PAHs
2008-2014
HP/Agilent 5890/5971 GC/MS (Year Deployed: 2008)
2015-2018
Agilent 6890/5973N GC/MS (Year Deployed: 2000)
PM10 Metals
2004-2013
PE Optima 2000 ICP-OES (Year Deployed: 2001)
2014-2018
PE ELAN 9000 ICP-MS (Year Deployed: 2015)
VOCs
2004-2015
HP/Agilent 6890/5973 GC/MS (Year Deployed: 2001)
2016-2018
HP/Agilent 7890/5977 GC/MS (Year Deployed: 2016)
Preconcentrator Equipment
VOCs
2004-2014
Entech 7100A (Year Deployed: 2004)
2015-2018
Entech7200 (Year Deployed: 2015)
Standards Preparation Equipment
VOCs
2004-2007
Ashe roll pressure gauge (Pressure Dilution) (Year Deployed: 1994)
2008-2013
Entech 4600A (Dynamic Dilution) (Year Deployed: 2007)
2014-2018
Entech 4700 (Static Dilution) (Year Deployed: 2014)
Canister Cleaning Equipment
VOCs
2004-2004
SIS Canister Cleaning System (Cold) (Year Deployed: unknown)
2005-2017
Entech 3100A (Hot) (Year Deployed: 2004)
2018
Entech 3100 (Hot) (Year Deployed: 2018)
PM10 Extraction Equipment
PM10 Metals
2004-2006
CAE Ultrasonics Model HT-1212-H (Year Deployed: 2006)
2007-2011
CAE Ultrasonics Model HT-1212-H (Year Deployed: 2000)
2012-2013
CAE Ultrasonics Model HT-1212-H (Year Deployed: 2004)
2014-2018
CAE Ultrasonics Model HT-1212-H (Year Deployed: 2011)
Chromium VI Extraction Equipment
Chormium VI
2005-2010
Branson 8510 (Sonicator) (Year Deployed: 2001)
2011-2011
Branson 8510 Sonicator/Branson Shaker (Year Deployed: 2001/2011)
2012-2013
Branson Shaker (Year Deployed: 2011)
PAHs Extraction Equipment
PAHs
2008-2014
Dionex -300 (ASE) (Year Deployed: 2004)
2015-2018
Unknown (Soxhlet) (Year Deployed: 2015)
Page 25 of 25
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