PEER REVIEW DRAFT DOCUMENT

- DO NOT CITE or QUOTE

xvEPA

United States	Office of Chemical Safety and

Environmental Protection Agency	Pollution Prevention

Draft Risk Evaluation for
Carbon Tetrachloride

Systematic Review Supplemental File:

Data Quality Evaluation of Physical-Chemical Properties Studies

CASRN: 56-23-5

CI

m

January 2020

1


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Peer Review Draft Document - Do Not Cite or Quote

Table of (on tents

Table 1. Physical Form Study Summary for Carbon Tetrachloride (1 of 2)	3

Table 2. Physical Form Study Summary for Carbon Tetrachloride (2 of 2)	4

Table 3. Melting Point Study Summary for Carbon Tetrachloride	5

Table 4. Boiling Point Study Summary for Carbon Tetrachloride	6

Table 5. Density Study Summary for Carbon Tetrachloride	7

Table 6. Vapor Pressure Study Summary for Carbon Tetrachloride	8

Table 7. Vapor Density Study Summary for Carbon Tetrachloride	9

Table 8. Water Solubility Study Summary for Carbon Tetrachloride	10

Table 9. Octanol-water Partition Coefficient Study Summary for Carbon Tetrachloride	11

Table 10. Henry's Law Constant Study Summary for Carbon Tetrachloride	12

Table 11. Flash Point Study Summary for Carbon Tetrachloride	13

Table 12. Viscosity Study Summary for Carbon Tetrachloride	14

Table 13. Refractive Index Study Summary for Carbon Tetrachloride	15

Table 14. Dielectric Constant Study Summary for Carbon Tetrachloride	16

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Peer Review Draft Document - Do Not Cite or Quote

Table 1. Physical Form Study Summary for Carbon Tetrachloride (1 of 2)

Study Reference:

CHRIS. (1984). CHRIS hazardous chemical data. US Coast Guard. Vol
2. Washington, DC.

HERO ID: 17566

Note:

CHRIS (1984) was not available for review. Data from CHRIS (June 1999)
was evaluated in its place.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

1 lie information or Jala
rellects the (.Uila and

Midi

Hie data was measured for
the substance of interest



chemical substance t\pe



Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.

:ilii;ilion/Rc\ iew

I he information or data
reported has reliable
re\ iew

1 ,o\\

The information or data is
from a recognized data
collection

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Medium

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

Reliability/Analytic
Method

The information or data
reported is from a

1 .OW

Data source does not pro\ ide
information reuardum the

reliable method.



analytical method

Overall Quality Level

Medium

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Peer Review Draft Document - Do Not Cite or Quote

Table 2. Physical Form Study Summary for Carbon Tetrachloride (2 of 2)

Study Reference:

O'Neil, M.J., ed. (1996). The Merck Index - An Encyclopedia of
Chemicals, Drugs, and Biologicals. 12th ed., Whitehouse Station, NJ:
Merck and Co., Inc., p. 1054.

HERO ID: 670297

Note:

O'Neil (1996) reported the physical form.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

The information or Jala
rellects llie data and
chemical substance l\|V

Midi

Hie data was measured for
the substance of interest

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

Data cited as found in the
literature.

:ilii;ilion/Rc\ iew

1 lie information or data
reported has reliable
re\ iew

Midi

The information or data is
from a recogni/.ed data
collection

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

Reliability/Analytic
Method

I he information or data
reported is from a
reliable method.

1 ,o\\

Data source does not |no\ ide
information regarding the
analytical method

Overall Quality Level

High

4


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Peer Review Draft Document - Do Not Cite or Quote

Table 3. Melting Point

Study Summary for Carbon Tetrachloride

Study Reference:

Lide DR. (1999). CRC handbook of chemistry and physics: A ready-
reference book of chemical and physical data. 80th ed. CRC Press, Boca
Raton, FL.

HERO ID: 3827230

Note:

Lide (1999) reported the melting point.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

1 lie informalion or dala
rellecls ihe (.Uila and
chemical substance l\|v

Midi

I he dala was measured for
ihe substance of mleresl

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.

aliialion/ke\ iew

I he informalion or dala
reported has reliable
rex iew

High

I he informalion is from a
recogni/.ed dala colleclion
where dala are peer-re\ lewed
b> e\|vrls in ihe lield and are
broadK available in ihe
public for review and use

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

Reliability/Analytic
Method

I he informalion or dala
recoiled is from a
reliable nielhod

1 ,o\\

Dala source does nol prn\ ide
informalion regarding ihe
anal\lical nielhod.

Overall Quality Level

High

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Peer Review Draft Document - Do Not Cite or Quote

Table 4. Boiling Point Study Summary for Carbon Tetrachloride

Study Reference:

Lide DR. (1999). CRC handbook of chemistry and physics: A ready-
reference book of chemical and physical data. 80th ed. CRC Press, Boca
Raton, FL.

HERO ID: 3827230

Note:

Lide (1999) reported the boiling point.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

1 lie inl'ormalion or dala
rellecls llie dala and
chemical substance l\|V

Midi

Hie dala was measured lor
I lie subslance of mleresl

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.

aliialion/ke\ iew

The inl'ormalion or dala
re|iorled has reliable
rex iew

High

The informalum is li'oni a
recogni/.ed dala colleclion
where dala are |ver-re\ lewed
b> experts in llie Held and are
broadK available In llie
public lor review and use

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

keliabililv/Aiialytic
Method

The inlormalion or dala
reported is from a
reliable melliod

1 ,o\\

Dala source does nol pro\ ide
information regarding llie
anal\lical melliod.

Overall Quality Level

High

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Peer Review Draft Document - Do Not Cite or Quote

Table 5. Density Study Summary for Carbon Tetrachloride

Study Reference:

Lide DR. (1999). CRC handbook of chemistry and physics: A ready-
reference book of chemical and physical data. 80th ed. CRC Press, Boca
Raton, FL.

HERO ID: 3827230

Note:

Lide (1999) reported density.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

1 lie inl'ormalion or dala
rellecls llie dala and
chemical substance l\|v

Midi

Hie dala was measured lor
I lie subslance of mleresl

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.

aliialion/ke\ iew

The inl'ormalion or dala
reported has reliable
rex iew

High

The informalum is li'oni a
recogni/.ed dala colleclion
where dala are peer-re\ lewed
b> experts in llie Held and are
broad l\ available in llie
public lor review and use

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

keliabililv/Aiialytic
Method

The inlormalion or data
reported is from a
reliable method

1 ,o\\

Dala source does nol prn\ ide
inToi'malion regarding llie
anal\lical melliod.

Overall Quality Level

High

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Peer Review Draft Document - Do Not Cite or Quote

Table 6. Vapor Pressure Study Summary for Carbon Tetrachloride

Study Reference:

Boublik T et al. 1984. The vapor pressures of pure substances: selected
values of the temperature dependence of the vapour pressures of some
pure substances in the normal and low pressure region. Vol. 17.
Amsterdam, Netherlands: Elsevier Sci. Publ.

HERO ID: 194873

Note:

Boublik et al. (1984) reported the vapor pressure.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Rcprcscntalncncss

The information or Jala
reflects the Jala aiul
chemical substance l\pe

iiigh

The dala was measured lor
llie substance of interest

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.

;ilii:ilion/Rc\ icw

1 lie information or data
reported has reliable
re\ lew.

Midi

The information is from a
recogni/.ed dala collection in
which results ha\e been
selected b\ experts based 011
their l|ual 11> and a\a 1 labi 111\
References to the original
sources are included

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

Reliability/Analytic
Method

I he information or data
reported is from a
reliable method

1 ,o\\

Dala source does not pro\ ide
information regarding I he
anal\ lical method

Overall Quality Level

High

8


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Peer Review Draft Document - Do Not Cite or Quote

Table 7. Vapor Density Study Summary for Carbon Tetrachloride

Study Reference:

Boublik T et al. 1984. The vapor pressures of pure substances: selected
values of the temperature dependence of the vapour pressures of some
pure substances in the normal and low-pressure region. Vol. 17.
Amsterdam, Netherlands: Elsevier Sci. Publ.



HERO ID: 194873





Note:

Vapor density was calculated from Boublik et al. (1984).

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represenlalixeness

The information or Jala
rellects llie data aiul

iiigh

The data xxas calculated for
the substance of interest



chemical substance txpe



Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.







The information is from a

Kx alualion/kex iew

The information or data
reported lias reliable
rex ie\x

High

recogni/.ed data collection
xx here data are peer-rex lexxed
b\ experts in the Held and are
broad l\ axailable to the
public for rex iexx and use

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated

Reliability/Analytic
Method

I he information or data
reported is from a
reliable method.

1 .oxx

Data source does not prox ide
information regarding the
analytical method

Overall Quality Level

High

9


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Peer Review Draft Document - Do Not Cite or Quote

Table 8. Water Solubi

ity Study Summary for Carbon Tetrachloride

Study Reference:

Horvath AL. (1982) Halogenated hydrocarbons: solubility-miscibility
with water. New York, NY: Marcel Dekker, Inc.

HERO ID: 194749

Note:

Horvath (1982) reported the water solubility.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

1 lie information or Jala
rellects llie data aiul
chemical substance t\pe.

Midi

Hie data was measured for
the substance of interest

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.

alualion/Ke\ iew

The informulion or data
reported has reliable
re\ iew.

High

The information is from a
data collection where data are
peer-re\ lewed b\ experts in
the lield and are broadK
available to the public for
re\ iew and use. Original
sources are also referenced

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

High

Methodology for producing
the information is designed to
answer a specific question,
and the methodology's
objective is clear.

Reliability/Analytic
Method

I he informulion or data
reported is from a
reliable method

High

Data are obtained b\ accepted
standard anaKlic methods

Overall Quality Level

High

10


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Peer Review Draft Document - Do Not Cite or Quote

Table 9. Octanol-wa

ter Partition Coefficient Study Summary for Carbon Tetrachloride

Study Reference:

Hansch, C., Leo, A., D. Hoekman. (1995). Exploring QSAR -
Hydrophobic, Electronic, and Steric Constants. Washington, DC:
American Chemical Society.

HERO ID: 51424

Note:

Hansch et al. (1995) reported the log Kow.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

keprcscntalixcncss

The information or
dala ivlleels ihe dula
and ehemical
substance Ix pe

Midi

The dala xxas measured lor I he
substance of inleresl

Appropriateness

The information or
data reflects
anticipated results
based on chemical
structural features or
behaviors.

High

The measured value is consistent
with the nature of the substance.

Kx aliialion/kcx ie\\

The information or
dala reported lias
re liable rex ie\x

Midi

The informalion is from a
recognized dala collection lhal has
been compiled bx experts and
includes references lo I he original
sources. The original source for this
xalue is a peer-rex lexxed journal

Reliability/Unbiased
(Method
Objectivity)

The method for
producing the
data/information is
not biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the domain/metric
was not rated.

Reliability/Analytic
Method

The informalion or
dala reported is from
a reliable method.

1 .oxx

Dala source does nol prox ide
informalion regarding lhe analytical
method

Overall Quality Level

High

11


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Peer Review Draft Document - Do Not Cite or Quote

Table 10. Henry's Law Constant Study Summary for Carbon Tetrachloride

Study Reference:

Leighton DT, Calo JM. (1981). Distribution coefficients of chlorinated
hydrocarbons in dilute air-water systems for groundwater contamination
applications. J Chem Eng Data. 26 (4): 382-85.

HERO ID: 194928

Note:

Leighton and Calo (1981) reported the Henry's Law constant as a
dimensionless value and it has been converted to atm-m3/mol.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Rcprcscnt:iti\cncss

The information or
dala iv ll eels llie da la
and chemical
substance l\ |V.

Midi

The xalue xxas measured for I he
subject chemical substance

Appropriateness

The information or
data reflects
anticipated results
based on chemical
structural features or
behaviors.

High

The measured value is consistent
with the nature of the substance.

:ilu;ition/Rc\ icw

The information or
dala reported has
reliable rex iexx

1 IiljIi

The source is a peer-rex lexxed
journal

Reliability/Unbiased
(Method
Objectivity)

The method for
producing the
data/information is
not biased towards a
particular product or
outcome.

High

The method for producing this
value is not biased towards a
particular outcome.

keliabililv/Analvtic
Method

The informalion or
dala reported is from
a reliable method

1 IiljIi

The analx lical method used to
measure this xalue is an accepted
standard method

Overall Quality Level

High

12


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Peer Review Draft Document - Do Not Cite or Quote

Table 11. Flash Point Study Summary for Carbon Tetrachloride

Study Reference:

CHRIS. (1984). CHRIS hazardous chemical data. US Coast Guard. Vol
2. Washington, DC.

HERO ID: 5348366

Note:

CHRIS (1984) was not available; however, a more recent version CHRIS
(1999) reporting flash point was reviewed.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

1 lie information or Jala
rellects the (.Uila and

Midi

Hie data was measured for
the substance of interest



chemical substance t\|V



Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

The measured value is
consistent with the nature of
the substance.

:ilii;ilion/Rc\ iew

I he information or data
reported has reliable
re\ iew

Midi

The information or data is
from a recognized data
collection

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

Reliability/Analytic
Method

The information or data
reported is from a

1 ,o\\

Data source does not |no\ ide
information retjarduitj the

reliable method.



analytical method

Overall Quality Level

High

13


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Peer Review Draft Document - Do Not Cite or Quote

Table 12. Viscosity Study Summary for Carbon Tetrachloride

Study Reference:

Daubert, T.E., R.P. Danner. (1989). Physical and Thermodynamic
Properties of Pure Chemicals Data Compilation. Washington, DC: Taylor
and Francis.

HERO ID: 3827242

Note:

Daubert and Danner (1989) reported the viscosity.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

keprcsciHalixencss

The information or
data ivlleels llie dula
and chemical
substance tx pe

Midi

Data are measured for lhe subject
chemical substance

Appropriateness

The information or
data reflects
anticipated results
based on chemical
structural features or
behaviors.

High

Measured data are consistent with
the subject chemical substance
structural features.

Kx alualion/kex icw

The information or
data reporled has
reliable rex ie\x.

1 IiljIi

The information or data is from a
recognized data collection
collection repository xxhere data are
peer-rex iexxed bx experts in the
field, are broadly axailable to the
public for rex iexx and use and
include references to the original
sources.

Reliability/Unbiased
(Method
Objectivity)

The method for
producing the
data/information is
not biased towards a
particular product or
outcome.

High

Methodology for producing the
information is designed to answer a
specific question, and the
methodology's objective is clear.

keliabilitv/Analylic
Method

The information or
data reporled is from
a reliable melhod

1 .oxx

Analytical method is not reporled

Overall Quality Level

High

14


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Peer Review Draft Document - Do Not Cite or Quote

Table 13. Refractive Index Study Summary for Carbon Tetrachloride

Study Reference:

O'Neil, M.J., ed. (1996). The Merck Index - An Encyclopedia of
Chemicals, Drugs, and Biologicals. 12th ed., Whitehouse Station, NJ:
Merck and Co., Inc., p. 1054.

HERO ID: 670297

Note:

O'Neil (1996) reported the refractive index.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at neness

The information or Jala
rellects the (Jala and
chemical substance l\|v

Midi

Hie data was measured for
the substance of interest

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

Data cited as found in the
literature.

:iliinlion/Rc\ iew

1 lie information or data
reported has reliable
re\ iew

Midi

The information or data is
from a recogni/.ed data
collection

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated.

Reliability/Analytic
Method

I he information or data
reported is from a
reliable method.

1 ,o\\

Data source does not |no\ ide
information regarding the
analytical method

Overall Quality Level

High

15


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Peer Review Draft Document - Do Not Cite or Quote

Table 14. Dielectric Constant Study Summary for Carbon Tetrachloride

Study Reference:

Norbert, AL; Dean, JA. (1967). Lange's Handbook of Chemistry.
McGraw-Hill NY, NY.

HERO ID: 3836460

Note:

Norbert and Dean (1967) reported the dielectric constant.

Domain/Metric

Description/
Definition

Qualitative
Determination

[i.e., High,
Medium, Low,
Unacceptable,
or Not rated]

Comment

Represent at ixeness

1 lie information or data
reflects llie dala and
chemical substance Ixpe.

Midi

Dala are measured lor the
subject chemical substance

Appropriateness

The information or data
reflects anticipated
results based on
chemical structural
features or behaviors.

High

Measured data are consistent
with the subject chemical
substance structural features.

Kx alualion/kex iew

I he informulion or dala
reported has reliable
rex iexx

Midi

The information or dala is
from a recognized dala
collection.

Reliability/Unbiased
(Method Objectivity)

The method for
producing the
data/information is not
biased towards a
particular product or
outcome.

Not rated

Data source does not provide
information to determine the
method objectivity (unbiased
method). Thus, the
domain/metric was not rated

Reliability/Analytic
Method

The information or dala
reported is from a
reliable method

1 .oxx

Dala source does nol prox ide
information regarding lhe
analx deal method.

Overall Quality Level

High

16


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