REMOVAL ACTION REPORT
REVISION NO. 4
REGARDING THE
ELLISVILLE SITE (RV007)
WILDWOOD, MISSOURI
Superfund Technical Assessment and Response Team (START)
Contract No. EP-S7-13-06, Task Order 0048
Prepared For:
U.S. Environmental Protection Agency
Region 7
Superfund Division
11201 Renner Boulevard
Lenexa, Kansas 66219
August 6, 2015
Prepared By:
Tetra Tech, Inc.
415 Oak Street
Kansas City, Missouri 64106
(816)412-1741
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H TETRATECH
August 6, 2015
Mr. Heath Smith
EPA On-Scene Coordinator
U.S. Environmental Protection Agency, Region 7
11201 Renner Boulevard
Lenexa, Kansas 66219
Subject: Removal Action Report, Revision No. 4
Ellisville Site (RV007), Wildwood, Missouri
U.S. EPA Region 7 START 4, Contract No. EP-S7-13-06, Task Order No. 0048
Task Monitor: Heath Smith, EPA On-Scene Coordinator
Dear Mr. Smith:
Tetra Tech. Inc. is submitting the attached revised Removal Action Report regarding the Ellisville site
(RV007) in Wildwood. Missouri. If you have any questions or comments, please contact the project
manager at (913) 908-4649.
Ted Faile, PG, CHMM
START Program Manager
Enclosures
cc: Debra Dorsey, START Project Officer (cover letter only)
Sincerely,
¦fe, S Rick Claytor, CHMM
START Project Manager
IIIIIIIIIl
40498463
X9025.14.0048.000
415 Oak Street, Kansas City. MO 64106
Tel 816.412.1741 Fax 816.410.1748 www.tetratech.com
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CONTENTS
Section Page
1.0 INTRODUCTION 1
2.0 SITE LOCATION 2
3.0 SITE DESCRIPTION 3
4.0 SITE HISTORY/PREVIOUS INVESTIGATIONS 4
5.0 REMOVAL ACTIVITIES 6
5.1 PRELIMINARY REMOVAL ACTIVITIES 6
5.2 SOIL EXCAVATION 7
5.2.1 Excavation Area 3 7
5.2.2 Excavation Area 2 9
5.2.3 Excavation Area 1 10
5.3 SAMPLING FOR DISPOSAL COORDINATION 12
5.4 ADDITIONAL SOIL SAMPLING 15
5.5 AIR MONITORING 16
5.6 SITE SURVEY AND CLOSURE OF STAGING AREAS AND ROADWAY 17
6.0 LABORATORY DATA REVIEW 18
7.0 SUMMARY 19
8.0 REFERENCES 20
APPENDICES
Appendix
A FIGURES
B PHOTOGRAPHIC DOCUMENTATION
C FIELD SHEETS (CD)
D CHAIN-OF-CUSTODY RECORDS AND LABORATORY DATA (CD)
E KM TEQ VALUES (CD)
F AIR MONITORING RECORDS (CD)
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CONTENTS (Continued)
TABLES
Table Page
1 POST-EXCAVATION SAMPLES AT EA 3 9
2 POST-EXCAVATION SAMPLES AT EA 2 10
3 POST-EXCAVATION SAMPLES AT EA 1 11
4 ROLL-OFF BOX SAMPLES 13
5 ADDITIONAL SOIL SAMPLES 16
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1.0 INTRODUCTION
The Tetra Tech, Inc. (Tetra Tech) Superfund Technical Assessment and Response Team (START) was
tasked by the U.S. Environmental Protection Agency (EPA) Region 7 Superfund Division to assist with a
removal action (RA) at the Ellisville site (RV007) in Wildwood, Missouri. Specific elements of this task
included (1) collection of post-excavation soil samples to confirm that site-specific removal action levels
(RAL) had been met, (2) sampling of excavated soils for disposal profiling analyses, (3) real-time air
monitoring during soil excavation, and (4) soil sampling adjacent to excavation areas to better define the
extent of contamination. START also assisted with analytical services procurement, sample management,
documentation of removal activities, and preparation of detailed maps and diagrams depicting excavated
and sampled areas. The START project managers (PM) were Dave Kinroth and Rick Claytor, and the
EPA Region 7 task monitor was On-scene Coordinator (OSC) Heath Smith.
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2.0 SITE LOCATION
The proposed Strecker Forest development includes three parcels of land encompassing 18.3 acres north
of Strecker Road in Wildwood, Saint Louis County, Missouri (see Appendix A, Figure 1). The three
parcels include the former Dozier property at 165 Strecker Road (approximately 5 acres), the former
Primm property at 173 Strecker Road (approximately 10 acres), and the former Schoessel property at
177 Strecker Road (approximately 3 acres). These three properties were purchased by Claymont
Development, LLC with intent to develop the area as a residential subdivision (Strecker Forest).
Geographic coordinates at the area are 38.597578 degrees north latitude and 90.605617 degrees west
longitude (see Appendix A, Figure 1). The proposed Strecker Forest subdivision is adjacent to (south and
west of) the Bliss-Ellisville subsite of the Ellisville site.
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3.0 SITE DESCRIPTION
The proposed subdivision area is mostly undeveloped, except for remnants of foundations remaining from
previously demolished structures (a garage and two abandoned homes) on the former Dozier and Primm
properties. The northern two-thirds of the area is covered mostly by hardwood forest. The property is
surrounded by suburban residential areas, except to the north and east, where a 12-acre tract hosts a
residence, horse arena, and stables. A portion of the Strecker Forest property includes some of the
Bliss-Ellisville subsite. Previous investigations had identified elevated dioxin concentrations in the
northeast portion of the proposed Strecker Forest residential development area, which overlaps the
western and southern boundaries of the Bliss-Ellisville subsite.
The terrain at the property slopes downward to the north from Strecker Road. Relatively steep slopes are
present that vary in elevation from approximately 720 feet above mean sea level (msl) at Strecker Road to
approximately 635 feet above msl along a tributary of Caulks Creek at the northeast perimeter of the site.
The intermittent Caulks Creek tributary flows to the north along a ravine in the central portion of the
property, and intersects another intermittent tributary crossing the northeast corner of the property. All
surface water and drainage pathways on the site flow in a northerly direction toward this area
(EPA 2013).
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4.0 SITE HISTORY/PREVIOUS INVESTIGATIONS
The following is a brief summary of the Bliss-Ellisville subsite immediately north and east of the
proposed Strecker Forest subdivision:
The Bliss-Ellisville subsite borders the proposed Strecker Forest development to the north and east,
and includes a small portion of a proposed preservation area at the northeast corner of the Strecker
Forest property. Investigative activities beginning on September 16, 1980, identified two waste
disposal areas northwest of a horse arena on the property. On June 2, 1981, trenching operations
guided by eyewitness accounts identified buried drums at the Bliss-Ellisville subsite. Several
followup geophysical surveys starting in June 1982 and continuing through August 1990 identified
buried waste at a number of locations at the Bliss-Ellisville subsite and contiguous properties. In
August 1985, the Missouri Department of Natural Resources (MDNR) placed a liner in the stream
bed of the Caulks Creek tributary to stabilize the stream banks, and constructed a berm to divert
overland flow from the eroding stream. EPA implemented a removal action (RA) in 1996, involving
excavation and management of soil impacted by dioxin and non-dioxin wastes, along with bulk
wastes in buried drums and other materials. During the RA, dioxin-contaminated materials were
transported to the Times Beach site for thermal treatment (incineration). All non-dioxin hazardous
wastes were managed off site at commercial Resource Conservation and Recovery Act (RCRA)
permitted hazardous waste facilities. Non-hazardous materials were disposed of at a sanitary landfill.
In all, 24,700 tons of dioxin-contaminated soil, 581 tons of soil contaminated with hazardous
substances other than dioxin, and 480 buried drums and other containers of wastes were removed
from the site. Soil samples were collected to confirm that cleanup goals had been achieved. Once
cleanup activities had been completed, excavated areas were backfilled, re-graded, and seeded. The
removal activities included a 0.15-acre area at the extreme northeast corner of the Strecker Forest
property (referred to as the "NPL Area" of Strecker Forest during past investigations). MDNR
continues to monitor groundwater and soil vapor conditions at the Bliss subsite (Tetra Tech
EM Inc. 2012).
Because of its proximity to the Bliss-Ellisville subsite, the proposed Strecker Forest residential
development property came under scrutiny related to environmental health concerns. From
September 2011 to spring 2012, EPA and START conducted soil sampling over the entire 18.3-acre
property to support an Expanded Site Review (ESR) to characterize potential impacts on human health
and the environment (Tetra Tech EM Inc. 2012).
The scope of the ESR included investigation of these previously sampled areas of the development
property, as well as several new areas. These included the southern portion of the Strecker Forest
property where 23 home sites have been proposed for development, and an undeveloped area designated
as the preservation area in the northern portion of the property. Sampling activities during the ESR
occurred between September 2011 and January 2012. Initially, 39 decision units (DU) were established
at the proposed Strecker Forest development site to characterize surface soils for a removal site evaluation
(RSE) by application of an incremental composite sampling (ICS) approach. Follow-up sampling was
conducted in July 2013, when six DUs were added (total of 45 DUs) (see Appendix A, Figure 2). Some
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of the DUs were divided into smaller sampling units (SU); physical features within the SUs sometimes
dictated further delineation of the SU areas for sampling purposes. These ICS activities are described in
the Removal Site Evaluation Report, Bliss-Ellisville Site - Strecker Forest Subsite, Wildwood, Missouri
(Tetra Tech 2014). The soil samples collected during the RSE were submitted to Cape Fear Analytical,
LLC (CFA) in Wilmington, North Carolina, for analysis for dioxin toxic equivalence (TEQ) compounds
via Method 1613B.
Elevated dioxin TEQ levels were limited to three areas covering a total of approximately 1.0 acre in the
northeast portion of the property proposed for residential development. By implementing the ICS
sampling methodology, it was determined that in seven of the SUs, dioxin TEQ concentrations exceeded
the Preliminary Remediation Goal (PRG) of 820 parts per trillion (ppt) for non-residential, undeveloped
areas of the site (see left side of Figure 2 in Appendix A). TEQ concentrations as high as 5,822 ppt were
detected in surface soils. Five subsurface samples collected within and near these areas contained dioxin
TEQ concentrations that exceeded the PRG of 2,460 ppt for depths greater than 1 foot. Dioxin TEQ
concentrations as high as 26,684 ppt were detected in subsurface soils. EPA Region 7 determined that
site conditions could pose a threat to public health and welfare, based on levels of dioxin-related
compounds (specifically 2,3,7,8-tetrachlorodibenzo-p-dioxin [TCDD]) above the site-specific PRGs. The
site qualified for RA consideration, based on National Contingency Plan (NCP) criteria in 40 Code of
Federal Regulations (CFR) 300.415(b).
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5.0 REMOVAL ACTIVITIES
Excavation to at least 3 feet below ground surface (bgs) at localized areas of the site was determined
necessary to achieve cleanup goals. The map on the right side of Figure 2 in Appendix A identifies the
areas addressed during removal activities (Excavation Areas [EA] 1, 2, and 3). Photos from the RA are in
Appendix B. Field sheets for all samples collected during this RA are in Appendix C (provided on
compact disk [CD]).
5.1 PRELIMINARY REMOVAL ACTIVITIES
On February 13, 2014, Mr. Kinroth collected samples of rock (SFRA-1 and SFRA-2) that would be used
to improve an on-site roadway for the RA. These samples were screened for metals by use of a portable
x-ray fluorescence (XRF) spectrometer, and for volatile organic compounds (VOC) by use of a MultiRAE
Plus with built-in photoionization detector (PID). No elevated concentrations of metals were detected,
and no VOC readings above background were observed. Mr. Kinroth also collected a composite sample
(SFRA-3) of proposed topsoil to be used as backfill for areas excavated during the RA. The sample was
submitted to GEL Laboratories in Charleston, South Carolina, for analysis for semivolatile organic
compounds (SVOC), VOCs, polychlorinated biphenyls (PCB), and metals regulated by the Resource
Conservation and Recovery Act (RCRA) (including mercury). Sample SFRA-3 did not contain
concentrations of contaminants above any level of concern (see Appendix D [on CD]). A portion of this
sample was also submitted to CFA for analysis for dioxins/furans (TEQ compounds) via Method 1613B.
This sample contained a dioxin TEQ concentration of 1.34 ppt. The proposed topsoil source was
subsequently deemed acceptable for use as backfill material for restoration of the site following
excavation activities. In addition, Mr. Kinroth collected a nine-aliquot soil sample from 0-1 foot bgs at
EA 1 (cells H and I) for disposal profiling analyses. This sample (SFRA-4) was provided to Clean
Harbors, the firm that would be handling disposal of the excavated soil. Based on the sample results
obtained by Clean Harbors (see Appendix D [on CD]), the proposed receiving facility—Lone Mountain
Landfill in Waynoka, Oklahoma—agreed to accept the waste from the site.
On March 24, 2014, EPA OSC Smith, START PM Kinroth, and personnel from the EPA Region 7
Emergency and Rapid Response Services (ERRS) contractor, Environmental Restoration, LLC (ER),
were on site to initiate the RA. Preliminary activities at that time included tree and brush removal, haul
road preparation, establishment of staging areas for an office trailer and 25-cubic-yard roll-off boxes that
would be used for off-site transportation of excavated soil, and background air monitoring (see
Appendix B).
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5.2 SOIL EXCAVATION
For this RA, removal action levels (RAL) for dioxin (TEQ) were as follows: 820 ppt in soil from the
surface to 12 inches bgs, and 2,460 ppt in soil at depths greater than 12 inches bgs. Throughout the
removal process, excavation activities depended on weather, pending sample results, and availability of
empty roll-off boxes. Dioxin-contaminated waste generated at this site was treated as F027
(dioxin-bearing) waste. The Universal Treatment Standard (UTS) for F027 waste is 1 part per billion
(ppb) for dioxin (40 CFR § 268.48). The alternative Land Disposal Restrictions (LDR) treatment
standard (40 CFR § 268.49) states that treatment to achieve a constituent concentration less than 10 times
the UTS is not required. Waste generated during the removal that contained up to 10 ppb of
2,3,7,8-TCDD was transported to the RCRA-permitted hazardous waste facility (Lone Mountain Landfill)
in Waynoka, Oklahoma, for proper management. Dioxin-contaminated materials with average
concentrations greater than 10 ppb were managed by Recupere Sol, Inc., in Saint-Ambroise, Quebec,
Canada, a facility capable of meeting the UTS for F027 waste via incineration/thermal treatment prior to
disposal.
After excavation of the cells to the depth that had been indicated during RSE activities, post-excavation
samples were collected. A nine-aliquot surface soil sample was collected from the floor of the excavated
cells. Additionally, a nine-aliquot soil sample was collected from each of the completed side wall faces.
Equal portions of each of the side wall samples were then homogenized into one ICS sample and
submitted with the floor sample to CFA for dioxin TEQ analysis. Laboratory data were typically
provided on a 72-hour turnaround basis. Additional excavation was conducted when the sample results
exceeded RALs. If a combined side wall sample for an excavation area exceeded the appropriate RAL,
archived samples from each of the individual walls (following ICS protocol) were submitted for analysis
to determine where additional excavation would be required.
5.2.1 Excavation Area 3
On April 7, 2014, after the roadway to the removal area had been established, excavation activities were
initiated at the south portion of EA 3 in cells H and I (see Appendix A, Figure 2). A Komatsu 200
excavator was used by ERRS to remove 1 foot of soil from those cells; the excavated soil was placed into
poly-lined, 25-cubic-yard, roll-off boxes. Post-excavation soil samples for dioxin TEQ analysis were
collected by START from the floor and side walls of the (combined) excavated cells. Laboratory data
confirmed that the RALs for those cells had been met. A representative sample of excavated soil was also
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collected for possible laboratory analysis for disposal profiling parameters, if determined necessary by the
osc.
The excavation process continued to the north, as cells F and G were excavated and sampled separately.
Post-excavation sampling in cells F and G confirmed that the RALs for those cells had been achieved.
The depth of excavation correlated with assessment projections until odorous stained soil containing
trash, debris, and metal drum fragments was exposed near the boundary between cells D and E.
Excavation was halted, and a soil sample (SFRA-25) was collected to identify potential contaminants
other than dioxins. The sample was submitted to Teklab in Collinsville, Illinois, for analysis for Code R
parameters and PCBs, and for Toxicity Characteristic Leaching Procedure (TCLP) analyses for metals,
pesticides, herbicides, SVOCs, and VOCs. The laboratory data, received on April 28, 2014, did not
indicate elevated contaminant concentrations that would result in additional disposal requirements. These
data are in Appendix D (provided on CD).
On April 29, 2014, additional excavation was conducted in EA 3 cells D and E, because previous post-
excavation sample results remained above the dioxin TEQ RAL. In the central portion of these cells,
additional odorous, stained soil and debris were exposed; excavation was again halted, and it was
determined that additional disposal profile sampling would occur. On May 6, 2014, three multi-aliquot
subsurface soil samples were collected by START and EPA from the stained portion of cells D and E.
The samples were collected at depths of 0 tol, 1 to 2, and 2 to 3 feet bgs. These samples (SFRA-34, 35,
and 36) were submitted to Test America Laboratory in Earth City, Missouri, for disposal profiling
analyses (VOCs, SVOCs, PCBs, and TCLP metals). The laboratory data, received on May 15, 2014, did
not indicate elevated contaminant concentrations that would result in additional disposal requirements.
These data are in Appendix D (provided on CD).
On May 7, 2014, excavation activities were conducted in EA 3 cells A, B, and C to 1 foot bgs. No further
excavation occurred in EA 3 until May 19, 2014, when approximately 5 feet of dark (stained) soil was
excavated from the eastern portion of cell F, along with stained soil in adjacent cell E. On May 21, 2014,
excavation in cells D and E continued until the stained soil had been removed (final depth of 5-6 feet
bgs). For post-excavation sampling, cells D and E were combined, and cells A, B, and C were combined.
Most of EA 3 had been excavated and backfilled by June 9, 2014. Completion of excavation at EA 3
occurred on June 27, 2014, when the final portion of contaminated soil was excavated from cell A.
Achievement of RALs was confirmed by post-excavation sample results. All excavated portions of EA 3
were backfilled after the laboratory data had been received. Table 1 below summarizes sampling
activities at EA 3.
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TABLE 1
POST-EXCAVATION SAMPLES AT EA 3
ELLISVILLE SITE - WILDWOOD, MISSOURI
Siimplo No.
Siimplo
Diilo
l'.\Cil\illO(l
( VI lis)
S;i in pie Description
l'.\Cii\iilioii
(din men l
l)io\in
no
ippii
SFRA-5
4/8/14
m.
Floor, 1-foot depth
Complete
13.09
SFRA-6
4/8/14
H/I
East, south, and west side walls, 1-foot depth
Complete
4.45
SFRA-10
4/10/14
G
Floor, 1- to 2-foot depth
Complete
6.88
SFRA-11
4/10/14
G
West and east side walls, 1- to 2-foot depth
Additional
required
4,953.87
SFRA-17
4/16/14
G
West side wall, 1- to 2-foot depth
Complete
<4.5
SFRA-18
4/16/14
G
East side wall, 1- to 2-foot depth
Additional
required
4,844.54
SFRA-21
4/21/14
F
Floor, 2-foot depth
Complete
1,507.99
SFRA-22
4/21/14
F
West and east side walls, 1- to 2-foot depth
Complete
296.93
SFRA-2 3
4/23/14
D/E
Floor, 1-foot depth
Additional
required
4,736.93
SFRA-24
4/23/14
D/E
West and east side walls, 1-foot depth
Complete
424.95
SFRA-2 8
4/30/14
G
East side wall, 4-foot depth
Complete
1,226.96
SFRA-2 9
4/30/14
D/E
Floor, 2-foot depth, light color
Complete
12.41
SFRA-30
4/30/14
D/E
Floor, 2-foot depth, dark color
Additional
required
11,100.02
SFRA-86
6/6/14
D/E
Floor, 3- to 5-foot depth, dark color
Complete
752.89
SFRA-87
6/6/14
D/E
East side wall, 5-foot depth
Complete
230.43
SFRA-88
6/6/14
B/C
East side wall, 6-foot depth
Complete
144.71
SFRA-89
6/6/14
A
North side wall, 7-foot depth
Complete
616.63
SFRA-123
6/26/14
A/B/C
North, east, and west side walls, top 0 to
12 inches
Complete
417.55
SFRA-124
6/27/14
A/B/C
Floor, 6- to 7-foot depth
Complete
69.79
SFRA-130
7/2/14
A
North and east side walls, 6- to 7-foot depth
Complete
528.06
Notes
ppt Parts per trillion
TEQ Toxic equivalence
< Less than
5.2.2 Excavation Area 2
On April 24 and 25, 2014, excavation activities were conducted at EA 2 (see Appendix A, Figure 2),
where 6 to 12 inches of soil was excavated by use of a Caterpillar 308 excavator. Confirmation samples
were collected from the floor of the area (SFRA-26) and from the side walls (SFRA-27). Laboratory data
confirmed that the RALs had been achieved. Table 2 summarizes the sampling activities at EA 2.
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TABLE 2
POST-EXCAVATION SAMPLES AT EA 2
ELLISVILLE SITE - WILDWOOD, MISSOURI
Siimplo No.
l);ilc
Siiinpk- Description
l-'.\c;i\iiliun ( <11111110111
l)io\in I I Q
(ppt)
SlRA-:o
4.:s 14
Floor, o- lo 12-inelidepili
Complete
^)~ id
SFRA-27
4/28/14
All side walls, 6- to 12-inch depth
Complete
184.69
Notes:
ppt Parts per trillion
TEQ Toxic equivalence
5.2.3 Excavation Area 1
Additional roadway construction and tree clearing were required before excavation at EA 1 to allow
movement of roll-off boxes to the area. On May 1 and 2, 2014, the contaminated area that had been
identified during assessment activities was excavated to 3 feet bgs. Post-excavation sampling results
exceeded the RALs, so additional excavation was required. On May 16, 2014, additional soil was
excavated from EA 1; the area was expanded in all directions, and an additional foot was excavated from
the floor of the area. Laboratory results from post-excavation samples collected from the floor and walls
(SFRA-46 through -51) were received on May 23, 2014, and all results still exceeded the RALs.
Excavation activities at EA 1 resumed June 11, 2014. At the southeast corner of EA 1, approximately
8 feet of debris and stained soil was excavated before the RAL was achieved (see Appendix B). A
composite sample (SFRA-128) was collected from two roll-off boxes containing soil excavated from the
southeast portion of EA 1. This sample was submitted to Test America in Earth City, Missouri, for
analysis for PCBs and SVOCs. The boxes were held until the laboratory results confirmed that
concentrations of those analytes were not elevated.
In the northwest portion of EA 1, no debris or discoloration was observed, but additional excavation was
still required before the RALs were reached. The north wall of EA 1 was excavated to the level of the
adjoining creek bed, approximately 4.5 feet below the initial surface level of EA 1. Samples SRFA-157
and -158 were collected from the north floor at the level of the creek. Excavation of EA 1 was completed
on July 21, 2014, and final confirmation samples were collected on July 23, 2014. Large gabion rock
(3 to 5 inches) was placed on the slope between the creek and EA 1 (after backfilling) to stabilize the
bank (see Appendix B). Table 3 summarizes results of post-excavation sampling at EA 1.
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TABLE 3
POST-EXCAVATION SAMPLES AT EA 1
ELLISVILLE SITE - WILDWOOD, MISSOURI
Sample
No.
Date
Sample Description
Excavation
Comment
Dioxin
TEQ
(ppt)
SFRA-31
5/2/14
Floor, 3-foot depth
Additional required
20,387.39
SFRA-32
5/2/14
All side walls, 3-foot depth
Additional required
3,210.59
SFRA-3 7
5/8/14
West side wall, 0- to 4-foot depth
Additional required
6,705.19
SFRA-3 8
5/8/14
South side wall, 0- to 4-foot depth
Additional required
2,575.89
SFRA-3 9
5/8/14
East and north side walls, 0- to 6-foot depth
Additional required
3,219.04
SFRA-46
5/16/14
East half of floor, 4-foot depth
Additional required
30,753.48
SFRA-47
5/16/14
West half of floor, 4-foot depth
Additional required
4,316.88
SFRA-48
5/16/14
West side wall, 0- to 4-foot depth
Additional required
7,336.55
SFRA-49
5/16/14
South side wall, 0- to 4-foot depth
Complete after sample
SFRA-159
1,420.36
SFRA-50
5/16/14
East side wall, 0- to 4-foot depth
Additional required
2,677.48
SFRA-51
5/16/14
North side wall, 0- to 4-foot depth
Additional required
4,399.71
SFRA-105
6/20/14
West half of floor, 4- to 6-foot depth
Complete
182.36
SFRA-106
6/20/14
All side walls in the northwest corner, 5- to 6-foot
depth
Additional required
13,949.15
SFRA-107
6/20/14
Southwest corner side walls, 4- to 6-foot depth
Complete after
samples SFRA-159
and -161
1,040.42
SFRA-113
6/23/14
East half of floor, 5- to 8-foot depth
Complete
181.03
SFRA-114
6/23/14
East side wall, 0- to 8-foot depth
Complete
355.94
SFRA-115
6/24/14
Southeast corner floor, 6- to 8-foot depth
Complete
416.97
SFRA-116
6/24/14
West side wall of the southeast corner, 0- to 6-foot
depth
Complete after sample
SFRA-125
868.81
SFRA-117
6/24/14
South side wall of the southeast corner, 0- to 6-foot
depth
Complete after
samples SFRA-134
and -135
1,199.16
SFRA-118
6/24/14
East side wall of the southeast corner, 0- to 8-foot
depth
Complete after
samples SFRA-134
and -135
1,160.06
SFRA-125
6/30/14
West side wall of the southeast corner, 0- to
12-inch depth
Complete
500.12
SFRA-126
6/30/14
East side wall, 0- to 12-inch depth
Additional required
924.55
SFRA-131
7/2/14
North side wall, 4- to 5-foot depth
Additional required
10,537.08
SFRA-132
7/2/14
Northwest corner side walls, 4-foot depth
Additional required
4,865.26
SFRA-134
7/8/14
Floor of all side walls of the southeast corner, at a
depth of 12 inches
Complete
846.71
SFRA-135
7/8/14
Southeast corner side walls, 0- to 12-inch depth
Complete
364.33
SFRA-138
7/10/14
Northwest corner floor, 4-foot depth
Complete
745.36
SFRA-139
7/10/14
South side wall of the northwest corner, 0- to
4-foot depth
Additional required
8,395.30
SFRA-140
7/10/14
West side wall of the northwest corner, 0- to 4-foot
depth
Additional required
8,251.49
SFRA-141
7/10/14
North side wall of the northwest corner, 0- to
4-foot depth
Additional required
3,470.36
X9025.14.0048.000
11
-------
TABLE 3 (Continued)
POST-EXCAVATION SAMPLES AT EA 1
ELLISVILLE SITE - WILDWOOD, MISSOURI
S;iill|)lo
No.
Diilc
Siiinplo Description
l'.\c;i\;ilion
( omiiKwil
Dioxin
HQ
(|)|)l)
SFRA-147
7/17/14
North and east side walls of the northwest corner,
0- to 4-foot depth
Complete
339.07
SFRA-157
7/22/14
North floor, east portion (creek level)
Nothing more
excavated
7,172.86
SFRA-158
7/22/14
North floor, west portion (creek level)
Nothing more
excavated
3,383.55
SFRA-159
7/22/14
South side wall of the northwest corner, 0- to
12-inch depth
Complete
289.59
SFRA-160
7/23/14
West side wall of the northwest corner, 1- to 4-foot
depth
Complete
2,371.78
SFRA-161
7/23/14
West side wall of the northwest corner, 0- to
12-inch depth
Complete
347.88
Notes:
ppt Parts per trillion
TEQ Toxic equivalence
Analytical data packages received from CFA were forwarded to Deanna Crumbling, sampling statistician
at EPA Headquarters (HQ) in Washington, D.C., for calculation of Kaplan-Meier TEQ values. These
TEQ values are listed in tables in Appendix E (provided on CD).
5.3 SAMPLING FOR DISPOSAL COORDINATION
As soil was excavated, it was loaded directly into poly-lined, 25-cubic-yard, roll-off boxes and sampled
for laboratory analysis for dioxin. Initially, samples from three roll-off boxes were combined into one
sample for analysis. In addition, soil from each roll-off box was held and analyzed individually if the
combined dioxin concentration exceeded 10,000 ppt (10 ppb) —the maximum concentration that could be
accepted by the Lone Mountain Landfill in Waynoka, Oklahoma. However, because of the time required
to receive follow-up data from samples from individual roll-off boxes if needed, combined roll-off box
sampling was later discontinued. The filled roll-off boxes were staged on site until all necessary
laboratory results for dioxin were received, allowing coordination of disposal arrangements. Excavated
dioxin-contaminated material found to contain concentrations greater than the alternative LDR treatment
standard (10 ppb) was trucked to the Recupere Sol, Inc., facility in Saint-Ambroise, Quebec, Canada, for
thermal treatment prior to disposal. During the project, 101 roll-off boxes were shipped off site for
disposal. Seventeen boxes, containing 267.06 tons of dioxin-contaminated soil, were shipped to the
Recupere Sol, Inc., facility in Canada for incineration. The remaining 84 boxes, containing 1,277.58 tons
of dioxin-contaminated soil, were trucked to the Lone Mountain Landfill in Oklahoma for disposal.
Table 4 summarizes results from samples of excavated soils in the roll-off boxes.
X9025.14.0048.000
12
-------
TABLE 4
ROLL-OFF BOX SAMPLES
ELLISVILLE SITE - WILDWOOD, MISSOURI
Siimplc No.
l.\c;i\;i(inn Aivii
Roll-olT lio\ IDs
l)io\iii I I Q
(|)|)l)
SFRA-7
EA 3, cells H/I
4, 5, and 6
1,084.49
SFRA-8
EA 3, cell G
7, 8, and 9
10,333.60
SFRA-9
EA 3, cell G
10, 11, and 12
3,592.32
SFRA-12
EA 3, cell G
13, 14, and 15
1,085.86
SFRA-13
EA 3, cell G
16, 17, and 18
3,092.32
SFRA-14
EA 3, cell G
7
5,681.17
SFRA-15
EA 3, cell G
8
17,455.32
SFRA-16
EA 3, cell G
9
3,720.36
SFRA-19
EA 3, cell G
19, 20, and 21
4,556.90
SFRA-20
EA 3, cell F
22, 23, and 24
5,870.79
SFRA-33
EA 1
39
24,434.89
SFRA-41
EA 1
41
13,355.69
SFRA-42
EA 1
42
6,189.20
SFRA-43
EA 1
44
20,743.61
SFRA-44
EA 1
45
14,092.96
SFRA-45
EA 1
46
10,626.04
SFRA-52
EA 3, cell F (dark)
47
2,413.04
SFRA-53
EA 3, cell F (dark)
48
42,642.51
SFRA-54
EA 3, cell E (dark)
49
19,731.13
SFRA-55
EA 1
38
13,865.29
SFRA-56
EA 3, cell E (dark)
50
15,742.86
SFRA-57
EA 3, cell E (dark)
51
360.06
SFRA-58
EA 3, cell E (dark)
52
26,048.09
SFRA-59
EA 3, cell E (dark)
53
3,907.01
SFRA-60
EA 3, cell E (dark)
54
5,548.15
SFRA-61
EA 3, cells D/E
55
2,504.09
SFRA-62
EA 3, cells D/E
56
1,476.54
SFRA-7 3
EA 3, cells D/E
57
3,121.50
SFRA-74
EA 3, cells D/E
58
12,056.80
SFRA-75
EA 3, cells D/E
59
4,735.13
SFRA-76
EA 3, cell C
60
949.66
SFRA-77
EA 3, cell C
61
1,040.53
SFRA-7 8
EA 3, cell C
62
2,469.24
SFRA-7 9
EA 3, cell C
63
1,518.06
SFRA-80
EA 3, cells A/B
64
757.17
SFRA-81
EA 3, cells A/B
65
247.25
SFRA-82
EA 3, cells A/B
66
702.66
SFRA-8 3
EA 3, cells A/B
67
914.29
SFRA-84
EA 3, cells A/B
68
445.52
SFRA-8 5
EA 3, cells A/B
69
1,272.33
SFRA-96
EA 3, cells A/B
70
980.29
SFRA-97
EA 3, cells A/B
71
151.62
X9025.14.0048.000
13
-------
TABLE 4 (Continued)
ROLL-OFF BOX SAMPLES
ELLISVILLE SITE - WILDWOOD, MISSOURI
Siimplc No.
l.\c;i\;i(inn Aivii
Roll-olT lio\ IDs
l)io\iii I I Q
(|)|)l)
Sl'RA-98
LA 1
-
; ¦>¦>;
SFRA-99
EA 1
73
3,963.41
SFRA-100
EA 1
74
13,840.16
SFRA-101
EA 1
75
3,050.08
SFRA-102
EA 1
76
3,952.01
SFRA-103
EA 1
77
3,108.85
SFRA-104
EA 1
78
615.78
SFRA-108
EA 1
79
962.47
SFRA-109
EA 1
80
14,230.69
SFRA-110
EA 1
81
2,811.13
SFRA-111
EA 1
82
1,556.76
SFRA-112
EA 1
83
7,721.91
SFRA-119
EA 1
84
597.46
SFRA-120
EA 1
85
677.38
SFRA-121
EA 1
86
1,577.75
SFRA-122
EA 3, cells A/B
87
257.91
SFRA-127
EA 3, cells A/B
88
164.00
SFRA-128
EA 1
87 and 88
PCBs and SVOCs only
SFRA-129
EA 3, cell A
89
386.18
SFRA-133
EA 1
90
5,750.93
SFRA-136
EA 1
91
320.81
SFRA-137
EA 1
92
272.42
SFRA-142
EA 1
93
4,10273
SFRA-143
EA 1, northwest corner
94
14,965.92
SFRA-144
EA 1, northwest corner
95
3,117.52
SFRA-145
EA 1, northwest corner
96
5,716.19
SFRA-146
EA 1, north wall
97
3,592.18
SFRA-148
EA 1, north wall
98
24,473.49
SFRA-149
EA 1, north wall
99
11,324.35
SFRA-150
EA 1, north wall
100
1,786.36
SFRA-162
EA 1, northwest corner
101
1,121.32
Notes:
PCB Polychlorinated biphenyl
ppt Parts per trillion
SVOC Semi volatile organic compound
TEQ Toxic equivalence
X9025.14.0048.000
14
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5.4 ADDITIONAL SOIL SAMPLING
Additional soil sampling activities occurred during the RA to confirm that no additional dioxin-
contaminated areas would have to be addressed. The area between EA 3 and EA 2 was divided into two
subareas: the south half was identified as EA 4, and the north half was designated as EA 5. The east
boundary of these areas was the horse arena, and the west boundary was the roadway next to the west side
of EA 3 and EA 2 (see Appendix A, Figure 3). Previous surface soil sampling had not identified elevated
concentrations of dioxin within these areas.
On May 29, 2014, EPA Geoprobe® direct push technology (DPT) equipment was used by EPA and
START to collect subsurface soil samples (SFRA-63 through -72) within EA 4 and EA 5, as well as
within EA 2 (see Appendix C [on CD]). Six, three-aliquot samples were collected within EA 4; three
samples were collected at 0 to 2 feet bgs, and three were collected at 2 to 4 feet bgs. Each sample
represented one-third of the area at the sampled depth. At EA 5, two composite samples were collected
within the central third of the area. The sample depths were the same as those at EA 4. Additionally, two
composite samples were collected in a ditch along the western edge of EA 2 at 2 to 4 feet bgs. EA 2 had
already been excavated to 1 foot bgs and backfilled. No dioxin concentrations exceeding the RAL were
identified in any of these samples; therefore, no further excavation occurred. Table 5 includes a summary
of these sample results.
On June 6, 2014, the EPA Geoprobe® DPT equipment was used by EPA and START to collect subsurface
soil samples to further define the extent and estimated volume of contaminated soil adjacent to the
southeast corner of EA 1. At one location southeast of EA 1, three grab samples were collected
(SFRA-93, -94, and -95): one at 0 to 2 feet bgs, a second at 2 to 4 feet bgs, and a third at 4 to 6 feet bgs.
Results from these samples indicated that at least 6 feet of soil would have to be excavated from EA 1 to
achieve the RAL (completed later in June 2014).
A retention pond was constructed to hold rainwater so that excavation could continue after rain events.
Previous surface soil sampling of this retention pond area, between EA 2 and EA 6, had not identified
elevated dioxin concentrations. Soil was pushed out to form a basin for the retention pond, with the soil
creating a 3-foot-high berm. A nine-aliquot surface soil sample was collected from the floor of the pond;
the dioxin TEQ result was less than the RAL. When rainwater collected in EA 3, it was pumped into the
retention pond, where it infiltrated and evaporated.
EA 6 was identified as the area between the retention pond and EA 1 (see Appendix A, Figure 3). Two
three-aliquot soil samples were collected from a ditch running through the middle of this area at 0 to
X9025.14.0048.000
15
-------
2 feet bgs (SFRA-90) and at 2 to 4 feet bgs (SFRA-91). Dioxin TEQs in these samples did not exceed
RALs. No removal activities were subsequently required at EA 6. These laboratory results are
summarized in Table 5, and the complete laboratory data are in Appendix D (provided on CD). The
retention pond area was re-graded, leveled, and seeded, as were the other excavated and backfilled areas.
TABLE 5
ADDITIONAL SOIL SAMPLES
ELLISVILLE SITE - WILDWOOD, MISSOURI
Siimplo
No.
Diilo
Siimplcd Arcii
Siimplo Deplli
( <1111 IllOIII
Dioxin 1 T.Q
(DDI)
SFRA-40
5/15/14
Retention pond floor
before use
0 to 2 inches
No excavation required
216.90
SFRA-63
5/29/14
EA 4, cell A
2 to 4 feet
No excavation required
5.41
SFRA-64
5/29/14
EA 4, cell A
2 to 4 feet
No excavation required
8.91
SFRA-65
5/29/14
EA 4, cell C
2 to 4 feet
No excavation required
44.71
SFRA-66
5/29/14
EA 4, cell C
0 to 2 feet
No excavation required
251.19
SFRA-67
5/29/14
EA 4, cell B
2 to 4 feet
No excavation required
<3.2
SFRA-68
5/29/14
EA 4, cell B
0 to 2 feet
No excavation required
148.94
SFRA-69
5/29/14
EA 5, cell B
2 to 4 feet
No excavation required
<2
SFRA-70
5/29/14
EA 5, cell B
0 to 2 feet
No excavation required
96.26
SFRA-71
5/29/14
EA 2, cell D
2 to 4 feet
No excavation required
<5
SFRA-72
5/29/14
EA 2, cell C
2 to 4 feet
No excavation required
874.17
SFRA-90
6/6/14
EA 6, cell B
0 to 2 feet
No excavation required
603.35
SFRA-91
6/6/14
EA 6, cell B
2 to 4 feet
No excavation required
811.14
SFRA-92
6/6/14
East of retention
pond
2 to 4 feet
No excavation required
5.43
SFRA-93
6/6/14
EA 1, southeast
corner
0 to 2 feet
Excavation required
919.68
SFRA-94
6/6/14
EA 1, southeast
corner
2 to 4 feet
Excavation required
2,995.55
SFRA-95
6/6/14
EA 1, southeast
corner
4 to 6 feet
Excavation required
16,343.59
SFRA-156
7/22/14
Retention pond floor
after use
0 to 2 inches
No excavation required
102.82
Notes:
ppt Parts per trillion
TEQ Toxic equivalence
5.5 AIR MONITORING
During soil excavation activities, real-time air monitoring was performed by START. Two monitoring
stations were established—one upwind and one downwind of the excavation area. At each station, an
MIE DataRAM 4™ aerosol monitor was used to measure concentrations of airborne particulate matter,
and a MultiRAE Plus multi-gas monitor with a built-in PID was used to monitor for VOCs. The
X9025.14.0048.000
16
-------
DataRAM 4™ was fitted with a size-selective impactor head to monitor only particulate matter
10 micrometers or less in size (PM-10). Data were logged by each unit and later downloaded and
tabulated. No concentrations that would pose health threats to site workers or nearby residents were
recorded. The air monitoring data are in Appendix F (provided on CD).
5.6 SITE SURVEY AND CLOSURE OF STAGING AREAS AND ROADWAY
START collected five multi-aliquot surface samples from the roadway and staging areas for dioxin TEQ
analysis on July 22, 2014. The samples (SFRA-151 through -155) were collected to confirm that
contaminated soil had not been transferred to the road and staging areas during the removal process. The
road was divided into three sections for sampling. The northern third—the section of the road adjacent to
the excavation areas—was found to contain a dioxin TEQ value of 17.07 ppt (SFRA-151). The samples
from the central and southern sections (SFRA-153 and -154) were found to contain dioxin TEQ results
less than 1.93 ppt. Two staging areas were sampled: (1) the north staging area, just south of the
excavation areas, and (2) the south staging area, near the EPA Command Post and site entrance. The
north staging area sample (SFRA-152) contained a dioxin TEQ value of 1.9 ppt, and the dioxin TEQ
value for the southern staging area sample (SFRA-155) was 1.46 ppt.
After discussions among EPA, the developer, and the property owner, it was determined that the rock that
had been used on the roadway and staging areas for the RA would be removed from the site. The rock
sample results obtained in July 2014 were submitted to the receiving facility for approval. The rock was
removed and transported to the Champ Landfill in Maryland Heights, Missouri, in late October 2014.
Restoration work was completed on October 31, 2014.
On August 1, 2014, The Sterling Company (Sterling) from St. Louis, Missouri, conducted land survey
activities at the site. The excavation areas, the roadway, and the Bliss-Ellisville site property line were
surveyed. The final survey information appears on Figures 2 and 3 in Appendix A.
X9025.14.0048.000
17
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6.0 LABORATORY DATA REVIEW
The EPA Region 7 Environmental Services Assistance Team (ESAT) was requested to review the CFA
data packages. Summary reports indicating that overall data quality and completeness were acceptable
are in Appendix D (provided on CD). The final data packages from CFA were sent to Deana Crumbling,
sampling statistician at EPA HQ in Washington, D.C., for review and calculation of Kaplan-Meier dioxin
TEQ concentrations. Those calculated values were used in the tables included in this report.
X9025.14.0048.000
18
-------
7.0 SUMMARY
Tetra Tech START was tasked by the EPA Region 7 Superfund Division to assist with an RA at the
Ellisville site in Wildwood, Missouri. Elevated dioxin concentrations had been identified at three areas
within a proposed residential development area (Strecker Forest) during previous assessments. These
soils were excavated during the RA for off-site disposal. For this RA, the site-specific RALs for dioxin
TEQ levels were as follows: 820 ppt in surface soil (less than 12 inches bgs); 2,460 ppt in soil at depths
greater than 12 inches bgs.
Specific elements of this task included (1) collection of post-excavation soil samples to confirm that site-
specific RALs had been met, (2) sampling of excavated soils for disposal profiling analyses, (3) real-time
air monitoring during soil excavation, and (4) soil sampling in the central and northern portions of the site
to better define the extent of contamination. START also assisted with analytical services procurement,
sample management, documentation of removal activities, and preparation of detailed maps and diagrams
depicting excavated and sampled areas.
Nineteen pre-removal site characterization samples were submitted for TEQ analysis (including samples
collected at the roadway, staging areas, and retention pond area). START also collected 63 post-
excavation samples to confirm that the site-specific RALs had been met. From the roll-off boxes
containing excavated soil, 72 samples were submitted for dioxin TEQ analysis. Another seven samples
were submitted for laboratory analysis for waste profiling purposes. Two of the samples (roadway rock)
collected during site activities were not submitted to the laboratory for analysis, but were screened by
START for metals and VOCs by use of an XRF and PID, respectively.
Removal activities began on March 24, 2014, and excavation was completed on July 21, 2014. During
the project, 101 roll-off boxes were filled and shipped off site for disposal. Seventeen boxes, containing
267.06 tons of dioxin-contaminated soil, were shipped to Canada for incineration. The remaining
84 boxes, containing 1,277.58 tons of dioxin-contaminated soil, were trucked to a RCRA-permitted
landfill in Oklahoma for disposal.
After the excavated areas (including the retention pond) had been backfilled with clean soil and graded,
they were seeded and mulched. Drainage pathways were covered with rock. Finally, rock was removed
from the roadway used during the RA. The roadway that was in the work area was covered with 3 to
6 inches of backfill soil, seeded, and mulched. The remainder of the road was seeded. Site restoration
activities were completed October 31, 2014.
X9025.14.0048.000
19
-------
8.0 REFERENCES
Tetra Tech EM Inc. 2012. Site Reassessment Report for an Expanded Site Review, Proposed Strecker
Forest Development Site, Wildwood, Missouri. Superfund Technical Assessment and Response
Team (START) Contract EP-S7-06-01, Task Order No. 0002.058. June 13.
Tetra Tech, Inc. (Tetra Tech). 2014. Removal Site Evaluation Report, Bliss-Ellisville Site - Strecker
Forest Subsite, Wildwood, Missouri. Superfund Technical Assessment and Response Team
(START) Contract EP-S7-06-01, Task Order No. 0014. April 24.
U.S. Environmental Protection Agency (EPA). 2013. Action Memorandum for a Removal Action at the
Ellisville Site, Wildwood, Missouri. September 26.
X9025.14.0048.000
20
-------
APPENDIX A
FIGURES
-------
-------
|Roadwa\
jSUl42D1
iiWjpptj
ISUI34DJ
l57Jfi]PPt\
[Sampiing Unit Pre-Excavation Results!
> " \
Excavation Area Post-Excavation Results!
|Bliss-Ellisville subsite boundary!
|Temporary retention pond|
mfSU£42AW
MsU:3e'Atm^iiMpRlr
iSB 14i„
\TT7lmB* lSB-47fl
r
@ ©0
JHHS @
Wnmpptm
wmm •_
DESCRIPTION
EXCAVATION AREA (EA) 3
EA2
EA 1
CELL
H/I
G
F
D/E
A/B/C
NA
NA
Floor, Post-Excavation TEQ
13.1
6.89
1,508
752.9
69.8
597.3
182.36
Excavation Depth
12 inches
24 inches
24 inches
3 to 4 feet
6 to 7 feet
12 inches
4 to 8 feet
Source: EPA Region 7, Strecker Forest GIS Data, 2012 - 2013; ESRI Basemap, Imagery, 2013; ESRI Basemap, National Geographic, 2013; ESRI Basemap, Topographic, 2013.
Legend
® Soil boring - below action level
® Soil boring - above action level
Decision / sampling unit boundary
~ Excavation area
Excavation sub-area
Pre-excavation sample results:
50 - 820 ppt
> 820 ppt
NA Not applicable
NS Not sampled
ppt Parts per trillion
TEQ Toxic equivalence (dioxin) in ppt
Ellisville Site
Wildwood, Missouri
Figure 2
Removal Activity Map
The Environmental Protection Agency does not guarantee
the accuracy, completeness, or timeliness of the information
shown, and shall not be liable for any injury or loss resulting
from the reliance upon the information shown.
Date: 11/20/2014 Drawn By: Colin Willits Path: X:\G\9025\0048\Projects\mxd\Figure2.mxd
-------
Legend
Exploratory area
Excavation area
~ Excavation sub-area
35
N
A
35
Feet
Source: EPA Region 7, Strecker Forest GIS Data, 2012 -2013; ESRI Basemap, Imagery, 2013
Eliisvilie Site
Wiidwood, Missouri
Figure 3
Exploratory Sampling Locations
TETRA TECH
Date: 11/4/2014
Drawn By: Gustavo Orozco
Project No: 103X9025140048.000
-------
APPENDIX B
PHOTOGRAPHIC DOCUMENTATION
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRATECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Northeast
DESCRIPTION
This photograph shows the site entrance driveway and upper support
zone prior to brush clearing in preparation for removal activities.
1
CLIENT
Environmental Protection Agency - Region 7
DATE:
3/24/14
PHOTOGRAPHER
Dave Kinroth
TETRA TECH
PROJECTNO.
X9025.14.0048.000
DIRECTION; Northeast
DESCRIPTION
This photograph shows the site entrance driveway and upper support
Zone area after brush clearing in preparation for removal activities.
2
CLIENT
Environmental Protection Agency - Region 7
DATE
3/25/14
PHOTOGRAPHER
Dave Kinroth
1
-------
Ellisville Site Removal Action
Wildwood, Missouri
V' r •• ft ' "
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Northwest
DESCRIPTION
This photograph shows Emergency and Rapid Response Services
(ERRS) personnel grinding tree stumps in the upper support zoiie
area in preparation for removal activities.
3
CLIENT
Environmental Protection Agency - Region 7
DATE
3/25/14
PHOTOGRAPHER
Dave Kinroth
TETRA TECH
PROJECT.NO.
X9025.14.0048.000
DIRECTION": North
DESCRIPTION
This photograph shows gabian stone being delivered to prepare site
access roads and support zones for the removal action.
4
CLIENT
Environmental Protection Agency - Region 7
DATE
3/26/14
PHOTOGRAPHER
Dave Kinroth
2
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRATECH
PROJECTNO.
X9025.14.0048.000
DIRECTION: Worth
description:
Tliis photograph shows ERRS personnel laying base fabric in the
area where gabian stone would be placed for a roadbed .
5
CLIENT
Environmental Protection Agency - Region 7
DATE:
3/26/14
PHOTOGRAPHER
Dave Kinroth
:;'2! 'J#?*
TETRA TECH
PROJECTNO.
X9025.14.0048.000
DIRECTION1; South
DESCRIPTION
This photograph shows gabian stone on the haul road at the site.
6
CLIENT
Environmental Protection Agency - Region 7
DATE
3/58/14
PHOTOGRAPHER
Dave Kinroth
3
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRATECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Worth
DESCRIPTION
This photograph shows the lower support zone and haul road (near
completion) to be used for the removal action.
7
CLIENT
Environmental Protection Agency - Region 7
DATE:
3/28/14
PHOTOGRAPHER
Dave Kinroth
TETRATECH
PROJECT NO.
X9025.14.0048.000
DIRECTION:
East/Northeast
DESCRIPTION
This photograph shows ERRS personnel beginning excavation of
dioxin-contaminated soil at the south end of Excavation Area (EA) 3.
8
CLIENT
Environmental Protection Agency - Region 7
DATE
4/7/14
PHOTOGRAPHER
Dave Kinroth
4
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRATECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: East
DESCRIPTION
This photograph shows ERRS loading dioxin-contaminated soil into
a roll-off box for transportto a disposal facility.
9
CLIENT
Environmental Protection Agency - Region 7
DATE
4/7/14
PHOTOGRAPHER
Dave Kinroth
3851 ' ' vu
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Southeast
DESCRIPTION
This photograph shows an air monitoring station operated by
Superfimd Technical Assessment and Response Team (START)
personnel during soil excavation activities.
10
client
Environmental Protection Agency - Region 7
DATE
4/7/14
PHOTOGRAPHER
Dave Kinroth
5
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Southeast
DESCRIPTION
This photograph shows the south end of EA 3 as soil excavation was
nearing completion.
11
CLIENT
Environmental Protection Agency - Region 7
DATE
4/8/14
PHOTOGRAPHER
Dave Kinroth
TETRA TECH
PROJECTNO.
X9025.14.0048.000
DIRECTION: East
DESCRIPTION
This photograph shows a roll-off box with excavated dioxin-
contaminated soil being moved for temporary staging on site.
12
CLIENT
Environmental Protection Agency - Region 7
DATE
4/7/14
PHOTOGRAPHER
Dave Kinroth
6
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRA TECH
PROJECT \<).
X9025.14.0048.000
DIRECTION: Northwest
DESCRIPTION
This photograph shows a roll-off box with excavated dioxin-
con laminated soil being removed for transport to an off-site disposal
facility.
13
CLIENT
Environmental Protection Agency - Region 7
DATE:
4/22/14
PHOTOGRAPHER
Dave Kinroth
TETRA TECH
PROJECT \<).
X9025.14.0048.000
DIRECTION; Northeast
DESCRIPTION
This photograph shows an overview of EA 3 with excavation in
progress.
14
CLIENT
Environmental Protection Agency - Region 7
DATE
4/23/14
PHOTOGRAPHER
Dave Kinroth
7
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRATECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Northeast
DESCRIPTION
This photograph shows excavation at EA 2.
15
CLIENT
Environmental Protection Agency - Region 7
DATE
4/25/14
PHOTOGRAPHER
Rick Claytor
TETRA TECH
PROJECT \<).
X9025.14.0048.000
DIRECTION: East
DESCRIPTION
Tliis photograph shows dark-stained soil encountered during
excavation at EA 3 (cells D and E).
16
CLIENT
Environmental Protection Agency - Region 7
DATE
4/30/14
PHOTOGRAPHER
Rick Claytor
8
-------
Ellisville Site Removal Action
Wildwood, Missouri
rWl"* *
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: East
DESCRIPTION
This photograph shows sampling of stained soil at EA 3.
17
CLIENT
Environmental Protection Agency - Region 7
DATE
5/6/14
PHOTOGRAPHER
Dave Kinroth
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Southeast
DESCRIPTION
This photograph shows the southeast portion of EA 1 after
excavation to approximately 8 feet below ground surface (bgs) had
been completed.
18
client
Environmental Protection Agency - Region 7
DATE
6/24/14
PHOTOGRAPHER
Rick Claytor
9
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Northeast
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Northwest
DESCRIPTION
CLIENT
PHOTOGRAPHER
This photograph shows ERRS excavating a vein of dark-stained soil
at EA 3.
Environmental Protection Agency - Region 7
Rick Claytor
DATE
6/28/14
DESCRIPTION
CLIENT
PHOTOGRAPHER
This photograph shows preparation for backfilling at:EA 1. along the
tributary to Caulks Creek on the north perimeter of the site.
Environmental Protection Agency - Region 7
Rick Claytor
DATE
7/10/14
10
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRATECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Southeast
description;
This photograph shows EA 3 after excavation had been completed,
and the area had been backfilled with clean topsoil.
21
CLIENT
Environmental Protection Agency - Region 7
DATE
7/14/14
PHOTOGRAPHER
Rick Claytor
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Southeast
DESCRIPTION
This photograph shows EA 2 after excavation had been completed,
and the area had been backfilled with clean topsoil.
22
client
Environmental Protection Agency - Region 7
DATE
5/5/14
PHOTOGRAPHER
Rick Claytor
11
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: South
DESCRIPTION
CLIENT
PHOTOGRAPHER
This photograph shows EA 1 after excavation had been completed,
the area had been backfilled with clean topsoil, and rip-rap had been
placed along the creek bank.
Environmental Protection Agency - Region 7
Rick Claytor
DATE
7/30/14
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: Northeast
DESCRIPTION
CLIENT
PHOTOGRAPHER
This photograph shows ERRS applying straw at EA 3 after the area
had been backfilled with clean topsoil and seeded.
Environmental Protection Agency - Region 7
Rick Claytor
DATE
8/1/14
12
-------
Ellisville Site Removal Action
Wildwood, Missouri
TETRATECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: North
DESCRIPTION!
This photograph shows EA 1 after excavation had been completed,
and seed and straw had been applied to clean topsoil backfill.
25
CLIENT
Environmental Protection Agency - Region 7
DATE
8/1/14
PHOTOGRAPHER
Rick Claytor
V~'
• k. s g
TETRA TECH
PROJECT NO.
X9025.14.0048.000
DIRECTION: South
DESCRIPTION
This photograph shows gabian stone taken from the site haul road to
line drainage pathways for erosion control at EA 3.
26
client
Environmental Protection Agency - Region 7
DATE
8/1/14
PHOTOGRAPHER
Rick Claytor
13
-------
APPENDIX C
FIELD SHEETS (CD)
APPENDIX D
CHAIN-OF-CUSTODY RECORDS AND LABORATORY DATA (CD)
APPENDIX E
KM TEQ VALUES (CD)
APPENDIX F
AIR MONITORING RECORDS (CD)
-------
gacfiF»i)
&vsuEi
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number:
sr+grH t | / ^ .
M*rix: su;3 8"-^M-b" sf/?A-
Project©; 5+«et-fet " Ptjrtsi- Ac+iW Project Manager £W~Bv
Location: fVW^jc^ State: v"Y\ O
Superfund Name: S-tv-GC ^ t^i" Site ID:
fckdii&tV-
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number: ^ ^ Matrix: 1 ^ Sample Number: 2
Project ID: f-i\ Project Manager: fjptKidCC^^""
Location: 3"f"i |~&Vl I S> State: IfV^O
Superfund Name:5(>^(j(^,r Site ID:
j(Ku£ vo. ( At'WoA
Location Description:
External Sample Number: A/
-MflVM /vcric>r\ - - \
Sfiv (yv pp,M Vv\ J
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sower IksK Oder
Project Number: Q 0^ Q 000 Matrix: So?/ Sample Number: S FRA~~3
Project ID:
Location: Uj)i \<^u30O^>
Superfund Name: tUVWi'l'if $» *ar-
jA¥i£
Analysis , I
i^i38 - ,
iWOCy
gcM^ek/S
V0/> f fTa^s
Property Owner information:
31 53 Hof&u>e\\ R^#
UJe^-te-vtll-e , wto 63MS"
Sample Comments:
1*1 Soi \ S^etkfi\^
4'fia
- S^%vf ^.aw-s +o vv^wti! ^ A
-ce^-r^/ j • _ r n.r '/ ^oIswIl.
^ C 5WiAi
,#iV
Sample Location Map:
Sample collected
bv: T~V'Clw<- ¦¦') Iff 6 ¦ -
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm/rr r^K of^er
Project Number: Q0H0 . Q>Q0
Matrix
Project ID: S F6
Location: u3il^U3006
Superfund Name: v»'||£ Si 4^ **" Site ID:
Soles IK-
:: <^Q fj Sample Number: snM-f
Project Manager:
State: yy-^ Q
Location Description: £x£gLi/y^'f~T t\(a ¦Sp^lo 1
External Sample Number:_
Latitude:
Sample Collection:
Longitude:,
r/V flK-
Time:
I 2-' 2-2-
Laboratory Analysis:
Container Preservative Holding Time Analysis
N h
2- X 32-02-
Klo v^L>
ma lysis
Disposal Pr»-ft !•& ^LjSeS
TO ,
C-Wvl YlasbccS-
Property Owner Information:
Sample Comments:
R Alr^ots > O -I
covwck^-^3 s;^
-- 40
WcWA vWHll W
vWVers
avA^s^ -£>r
^ *V " A. - 7^— A ^ ^
fenck-
Sampie collected by: 1&(X.s^ Ki\A(b'
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm-^rnsK o^tr
Project Number: 000
Matrix; $0'/ Sample Number: S FRAS
Project ID: Fb/C5^" ft A
Location: u3 i |ti us 0€» cl
Superfund Name: £||,'wi'li£ Sik? - Site ID:
S4^JCexF*/eSf~ SuUf/R^
Project Manager: He*M Smti'H /*iu/-£-.kVnf&tf
^ — _ & M i-mi
State, fVlO
Location Description:
External Sample Number:_
Latitude:
Lonaituda:
<;fh'A - T HAS Hj-t t=!r*".r
Sample Collection:
H-* (: - I Ll
Time:
/ <•
, ^
"2-5 I % ^ A f
^ L* ,A -I
I.*.! £
IA
r*-
1 11 Cu v uitOi i
' ^ -V _
& c 4 v v
r uiid-
I c {> V t ^
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr**rn«&K oder
Project Number; Q 0*-/ Q 000 Matrix; $Q*j Sample,Number; SFRA-io
Project©: S+»* titer IFfc/tSf" Project Manager: He^^h Smitfl
Location: u3t \ooci> State: q
Superfund Name: £||,W|)« - Site ID:
B/eSf- S^kf/R- . - , aL
Location Description: j cf a w iff if iv biUwU \W ^ J
External Sample Number: C» tUS't'
Latitude: Sample Collection: Time:
Longitude:
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
tft '2—
fC
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1 (" l"3 B
Property Owner information
owner information: ^ .
Si4e dW \-5i6tu_t\S
Sample Comments: Sample Location Map: .
q fi\^ eadv vlW -r; »«"W'
< \ ] ^ J ^ 5
\wQTcWiv^ .
I XOK^i ivi 'C l\
Sample collected by:_
l\ n\;Vli
1
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
O&tr
Project Number: q ^ Q}00 Matrix; Sample Number: sf/w-7"
Project ID: S+-r*cKoo&
Project Manager; Hi*H\ $m*Hl j
***• w\o
Superfund Name: fWwi'lif S»-* Site ID:
s-becKeyFi^t" So\pxiH-
LocattonDescription: ^Tf7)(n7 in. Ifl-L " ' > Sci I jk ft > ^ £'
Latitude:
Sample Collection;
Time:
Lonaitude:
'Laboratory Analysis:
Container Preservative
Holding Time
Analysis
i— y#£>
A
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Property Owner Information:
^7l4c. *~L \Lli\j U.K"1- "^uK-eS
v. V\
Sample Comments;
Sample Location Map:
ft, Ho tr'U-rt*hSjo
* ^ I #\
Cvifcr j-sxr/-
, \ w
Sample collected by: { \ 1 >\ '. <
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm-^rriSsK otAer
Project Number: 000 Matrix; Sample Number: 5 F^^V"
Project©:
Location: u3il^UJOO^
Superfund Name: £||,'wi||{ Si'te Site ID:
s-heiKerFj/esf SuWWK»
Project Manager: He*H $m*~H /
state: mo
Location Description:
External Sample Number:,
Latitude:
Pic M I¦ & '¦* - W -\4v 7, t 1° 1 S f" K * E
Longitude:,
Sample Collection:
f?~/7
Time:
Laboratory Analysis:
Container
Preservative
Holding Time
A. ^
Analysis
IbljB
Property Owner Information:
0 lx f n^vV 'a'A K
Sample Comments:
Sample Location Map:
go* 7
E-
\
26 it "5
\<
Sample collected oy
^ v'w.iV
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number;
snwrr oiier
0 040.0(20
Matrix
: $0*1 Sample Number;
Project ID; SWuM-tr
Location: tOt \c)ujoo&
Superfund Name: £||,W||f Site - Site ID:
s-betKerB/esf SohslH^
Project Manager: j fao-t-Mihoft
State: fVIO
Location Description:
External Sample Number:_
Latitude:
~~cl
O ,e uw I* t mU- V.»t 'K 10, li J'Z-
Longitude;,
Sample Collection;
/t k< °
Time:
'¦(-MY
Laboratory Analysis:
Container Preservative
I
(y,
'0
Holding Time
yiM
Analysis
\QI'-JP
Property Owner Information:
^ So\\ U\\o0S
Sample Comments: Sample Location Map:
feox. IP
V17 •
Sample collected by;_
v&t
AC
L_
'1
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAXTlkzK oier
Project Number: Q 0^ ft 0
Matrix:
Project ID; S4"r*cK-€/" F6/t5f" K A
Location: u3t \^u)0O^
Superfund Name: £||,'wt'ii£ Site" Site ID:
s-hfeUCef Finest" SohflH^
: 50'/ Sample Number: SH^^G
Project Manager: He*H Smt'H
State:
Location Description: pc S f ^Va^'llCiX >lI)l£ ll f 4 j ~ Q~
External Sample Number:,
Latitude:
Longitude:,
Sample Collection:
V- b 'H
Time:
fc: zC
Laboratory Analysis:
Container
Preservative
Holding Time
lio
yeC/
tJ-fr
Analysis
i6i 7 i3'
Property Owner information:
[ vv S, k £ ^ ^
Sample Comments:
Sample collected by._
4
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Sample Location Map:
I r. - r- -
"77
Q
t\ a; ,
(S: ci p
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£.* ^
"^-y, - I
SoWjlII
l.i :>
6r
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snw?rr75sK oder
Project Number. Q>Q0 *8trix: Se?|
Sample Number; £
Project ID: S+fdtltS' Fb*sf~ R A
Location: u3i
Superfund Name: £||,'wi'll€ Site — Site ID:
S4^,KfcrB/e-Sf- SobtlH*-
Project Manager H*tH\ -WM j
State: fVlQ
Location Description:
External Sample Number:_
Latitude:
Longitude:
¦*) * isri ' M ^ ^
t.Wki' s
fl.O
Sample Collection:
i - it -/
Sample Comments:
Sample collected by:_
<\
t?-£a?"'
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to
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JT -(yr
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Cy> A 3' /',J
•^oO
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r.; ai^
I V_
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm^TTisK oMer
Project Number. Q 0*-{ Q Q)Q@ Matrix: fj Sample Number: £ ^Rh"~ iZ
Project ID; SWuMtS FB/CSf" R A
Location; u3t \c^u>oo^
Superfund Name: £||,W|if S» - Site ID:
S-frtXftrF»/c-*f" Sul»WK-
Location Description; 1 a.
Project Manager: Sm,'j4\ Jllkj-t-Kt
state: mo
External Sample Number: /I, ^
Latitude:
Longitude:
¦I »
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Sample Collection:
H" I*-! ' J C/
Time:
Laboratory Analysis:
Container
V-%.
Preservative
*¦/ v.
Holding Time
/, >
Analysis
6
Property Owner Information:
• V.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAfcr T«sK oMer
Project Number: Q)Q0 Matrix; SO?! Sample Number: S FRA— ' '<
Project ID: S'4"*«(J(£/" FD/t5f" R A
Location: U3 i IcW&OCl
Superfund Name: £t|Vwi'|){ Si 4WK^
Project Manager: HeqM /fahL~Wi'h($
State:
Location Description: -•
External Sample Number: . ,
Latitude:
Longitude:
. L , ^
Sample Collection:
V'/V'/v"
Time:
Laboratory Analysis:
Container
^ tr
02
Preservative
7; l
Holding Time
Analysis
>
Property Owner Information:
i »¦- .Vf<-
¦n / A '* C {
Sample Comments:
Sample Location Map:
rx-\ /u
L N'-!
pvx /71
/r-
Sample collected bv: /
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1/
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number;
ST*ncr r*i,K orier
©04B.000
Matrix:
SO ?/ Sample Number; 5 /\ — fLj
Project ID; Fb/C.S'h R A
Location: U^i l!L ' > '<
Property Owner Information:
s,i, V.-
Sample Comments: Sample Location Map:
-
I. *"/ i i ^
Sample collected by: I ih
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swtr-feK oAtr
Projaet Number: g@4g> 000 "¦"U: Sof/
Sample Number p, ' ;
Project ID; Fb/tSf" I? A
Location: lOi i0u>0OO
Superfund Name: 5t"4#-" Site ID:
S4-^Ke/*Fi/esf- Sal9xjtf~
Project Manager $m~H j
state: mo
Location Description
External Samol® Number: \.
/."! t: 'Vu-.'.'Ia. N x
y
Latitude:
Lonoitude:
Sample Collection:
Time:
,
Laboratory Analysis:
Container Preservative
Holding Time
Analysis
-/ -
/ "
lb i ^
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Property Owner information:
L »• jr \
4 *~t ,
Sample Comments;
Sample Location Map:
K
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Sample collected by:_
-------
Sample Correction Field Sheet
US EPA Region 7
Kansas City, KS
sm^rmK ^er
Protect Numb»r: Q0HP) 000 Matrix: $Q*f Sample Number:
Project ID: SH*tK^T Fb/tsf" R A
Location: vOt \duJOOci
Superfund Name: £||»W!l£ Si 4^ *" Site ID:
S^^etKefB/g-Sf- SobslW-
Location Description: >f i i't /<-.
External Sample Number:
S FRb- lb
Project Manager: He*M Sm'H j fa+LMi'mfi
state: mo
Cf
Latitude:
Longitude:.
Sample Collection:
"/ hi
Time:
Laboratory" Analysis:
Container Preservative
J
L~i
Holding Time
A. i
Analysis
Property Owner information:
\u i M f ¦ ' V ' /'/ i )!'< i
t ' t *
Sample Comments:
Sample Location "Map:
hv °[* W33
Sample coftected by: Cllf c>! tua u
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKrT^K OfktT
Project Number: 00^0 Q)Q0 Matrix: Sotj
Sample Number; 5 F~ R — / "/
Project ID: S^lKc/" fb/tsi" (%A
Location: u3i |c)to©e€l
Superfund Name: £||,'wi'li£ Site-- Site ID:
S^kr/K-
Project Manager: He*H Sm"H jCoa+t-S
State: fVlO
Location Description:
External Sample Number:
Latitude:
r »
i. f i "> C'._ • *\ '
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, ICS
STAXTlteK Oder
Project Number: 0 0tf QQ® Matrix: So'l
Sample Number: 5 R A ~~~ fS
Project ID; S^Ut-e#*" Fb/tsi" R A
Location; u3 t It! to 00 k
Superfund Name: £(|,Wilt Si^e— Site ID:
s+^KerB/c-sfSukr/K-
Project Manager H*tH\ j (VfUftH
State:
Location Descriotion: ')fi< t1 / S ft1
' C 5 i . I t J 4' i
External Samole Number;
Latitude:
Sample Collection;
Time;
Lonaitude:
-/"¦a V
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Laboratory Analysts:
Container Preservative
Holding Time
Analysis
3 i ' ^
/ w V'c
/• '
/(, '
Property Owner Information:
(9^ S>~^ '
/} ,, ;1 1
U> » r' ~
Sample Comments:
Sample Location Map: /
i -?#¦-<' -
ev>3-
-f
Ir!
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Sample collected by. i.t, -
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm^TT^H o^er
Project Number: 0040 Q/10 Matrix: Sof/ Sample Number; 5FW*"fl
Project ID: S Fb/CSt~ R A
Location: u3i \^UJ6od
Superfund Name: £||^vi'|)f Si'4^ — Site ID:
S4-vfecKerF5/t,sf
Location Description: \ I i' /-4 - /
External Sample Number: 81 y ¦ ¦ ¦'.
Latitude:
Longitude:
Project Manager He*M f fo+C-W-tMbft
State:
P/Jyf,LL Sfitup(
i r -
¦'7, - *- ^
7
Sample Collection:
it j
Time:
/6- L
Laboratory Analysis:
Container Preservative
Holding Time
Analysis
H -f?. v
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Property Owner Information:
,/-/ •
Sample Comments:
Sample Location Map:
>, .. ,"///-•
1 'C '•
?/ -¦ W7/
Sample collected bv: h£MMIia
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAfiCT Oder
Project Number; Watrix: %Q*j
Project ID: SH«cK-€/" R A
Location; uJ5t I^us0o6
Superfund Name: £||,'wt'lS< St 4^ — Site ID:
s-HfctKe/*F»k*>f~ S^kr/K^
Sample Number: ^ ft ~~
Project Manager: He*W\ Swj4\
state: mo
Location Description:
External Sample Number:_
Latitude:
O.CJC^ &.* ¦>£, ffn Z-Z 7.^ 2y
1 / / *
Longitude:,
Sample Collection:
Y'2/'/y
Time:
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
V^z
y"cv
A) Pi
16133
Property Owner Information:
s«('|
Sample Comments:
Sample Location Map: , ^
\ * .
Z3
Ck."
F«"-J J-ft
w ¦*'w 5
Sample collected bv: / v l jv^
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swtr TisK oMer
Project Number: 0 0*-f 0 000 Matrix: Sotl
Sample Number; ^ f~~R — 2 I
Project ID; S fb*€Sf~ R A
Location: u3t \^U30O^
Superfund Name: £||»jvi'|5* S»te-~ Site ID:
s-becKerPi/esf s^kr/K-
Project Manager: -W'M j
State: ^ Q
Location Description:
External Sample Number:.
Latitude:
r-Or fK,i-r
I- 2 'ft!
Longitude:,
Sample Collection:
y-2/-/y
Time:
/£ ' ^
Laboratory Analysis:
Container
1c J
Preservative
76o
Holding Time
/J 4
Analysis
Property Owner Information:
On SrU ¦t-vcivdm'v '3 -
Sample Comments:
fxcHeo^
Sample Location Map:
A
r,.-{^ \^1'
BA3 ^
- , | ^ js?r ¦—
X
x
\ A
.v v
^ A.
\ ^
Ho ^
L J i\
Sample collected by: /) / f] < l ' ^
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snvrr ias.K oder
Project Number: Q)Q)@ Matrix: §©*| Sample Number: S
Project ID: 9&t*0kf" R A
Location: vOt IdwftO^
Superfund Name: £||,j>,r|jf Site — Site ID:
$>-h*tXtf F» (*-*> t~ SobsiH"
" ZrA 3 F ft, D.
Project Manager H&iM S*t*H /fo+€~Wi'h
Sample Comments:
1^; =
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srwfiCTT^K oiler
Project Number: Q)Q 0 MaMx: 5o ?/ Sample Number: S FRA"~ ^3
Project ID: I"S/tSf" Project Manager: -WM
Location: uit Idcoood State: f>/\Q
Superfund Name: CHtS.vs'Of S\'te — Site ID:
s-^ecKei" f S obslH-
Location Description: Past" £X <3x- id* Wl £" A "3 - Dy h- C
External Sample Number:
Latitude: Sample Collection: Time:
Longitude: ^ • I 3 ~ /& I-I1)
Laboratory Analysis:
Container Preservative Holding Time Analysis
H'l- 4*0 ft* it.il 13
Property Owner Information:
C n s
E °
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
ST7wrr Oder
Project Number: 00^0.000
Matrix:
: 5C;/ Sample Number: S
Project ID: SWte/" JFb^st RA
Location: uji Idtoood
Superfund Name: £||,'wi'iS£ Site — Site ID:
Project Manager: Htq+h
State: ^ Q
Location Description;
External Sample Number:,
Latitude:
ast rA-3-P.E ^/(JeuiiUs
Longitude:,
Sample Collection:
4-23-/1
Time:
fC '
Laboratory Analysis;
Container Preservative
Holding Time
Ho^-
A) A
Analysis
Ifcl^ B
Property Owner Information:
C"w d^sV
9
Sample collected by:_
f\HV^
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAXTThK odiT
Project Number; qQHQ Q&Q
Matrix:
: Sof/
Sample Number;
SF/M-^S
Project Manager; H&tM. j
State: ^ Q
Project ID: S-b* f" Su'ip.f/'K-- (
Location Description: UlfjsAO. P«'&h|4, -if)glAA Pl'V \V\ C A 3 £ N^Hk U)ftl\
External Sample Number:
Latitude: Sample Collection: Time:
Longitude:
fa'-iO
Laboratory Analysis:
Container
12*2 •
Preservative
Holding Time
Al^~
4-ituP fescue
Property Owner information:
Cvvte ^v-aW CtW 4 YW AV M'-'
Sample Comments:
0
/VMn Ljfrtt4
Sample Location Map:
f A ^
"0
A
Sample collected by:_ tV»\AK
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm/CTTasK oMer
Project Number; 00^0 Q&0 Matrix; 5o'l Sample Number; S
Project ID: R A Project Manager: He*Hi -WM j (Dbw-CMthCljfc
Location: uji |ciu>t>o^ State: f>f\Q
Superfund Name: £j|;wi'|»£ Site-" Site ID:
Location Descriotfon: C i Jo® r
It " 15-'
Extemal Samole Number:
Latitude:
Lonaitude:
Sample Collection:
l_|. J n. J
Time:
H2Z
Laboratory Analysis:
Container Preservative
Holding Time
Analysis
L*| Vi W C
tJi4
•V' V
5
Property Owner Information:
[tv (
\ ll (j " ^
A WjwV"t ^
( L
Sample Comments: Sample Location Map:
°\ > {yt3*a.
\, [\n-r
Sample collected by:. Ch-y 111 .11.1 ..(A.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
s-wrrr^K other
Project Number; 00^$ 000 Matrix: Se*|
Sample Numtar: 5 ft /{ — £ -J
Project®: S\r*+L&tT FS/eSf" I?A
Location: u3i!^u>00^
Superfund Name: £||»Wi}f Site- Site ID:
s-|->*c.Ke/*Fi/est" S i K-
Project Manager /Au-L^Ut'm^
State:
Location Description: \ [A L
External Sample Number:.
Latitude:
Longitude;,
Sample Collection:
Time:
m?
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
V <*2
4° c
t ~ 7 '
n
Property Owner Information:
IH v Lex. 1 (a
N .it* S
Sample Comments:
ICS °l /H-,wh &d sJdt
$
f) ' ."\,4W
.0 r i'j/ yl J
I ^
Sample Location Map:
«¦
1
CrM
S A^1 "
Sample collected by: I > ' \ A . *AA iAA* *¦
0
-------
Sample Collection Field Sheet
US EPA Region?
Kansas City, ICS
sower lisK oi&r
PnpetNumbmr. QX2)@ MmMx: $0*1 Sample Numb«¦; S S'
Project ID; fb/tsh R A
Location: vOi \ckiooo&
Superfund Name: £||v'wi'||< S»'4 _,i P
External Sample Number;.
Latitude:
Longitude:
Laboratory Analysis;
Container Preservative Holding Time
H f fo+cMtttfd
State: fY\Q
Time:
Analysis
MrjJS
Sample Location Map;
Sample Collection:
f
Sample collected bv: ( yi*l
/
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
oiktr
Profmet Kumbmr. 0 0^0 000 Matrix: SO'I Sample Numbw: S FRft— \
Project ID: fb/tS'b R A Pr^ect Manager Hi* Hi /jW^kVftfot
Location: tOi\^u>6od State: fy*\Q
Superfund Name: £||Vwi'lS< Site- Site ID:
&-b*cKerff
Location Description:.^ 7 J. j> ¦'Vv.y-' /^T"f »>- f
External Sample Number:
Latitude: Sample Collection: Time:
Longitude: -*s*'- 'S \
Laboratory Analysis:
Container Preservative Holding Time Analysis
Property Owner Information:
sc^-
Sample Comments:
/uy K
Sample Location Map:
t
7\
Sample collected bv: ^ ^ K/
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KB
srhfCTT^K otker
Proi*** Mumbmr; 00 0 Matrix: fj S«mpto Numbfr: £ f (( ft-— j(-
Project ID: RjiC-5"^ R ^
Location; vOi \^u>oo&
Superfund Name: £||v'jv»'|)tf St'k?— Site iD:
S^^KerFi/e-Sf- SobxiH-
Location Description: ^
External Sample Number:
Latitude:
Longitude:
Project Manager Hi* Hi VM
State: Q
Time:
///^
K /"
Sample Collection:
f-£2i /V
Laboratory Analysis:
Container Preservative Holding Time Analysis
^ , fc /V./f /crr^
Property Owner Information:
Sample Comments:
r.V...
at Q/crst- Jr-' f> { V
Sample Location Map:
f
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
S77wrTT4s.K otber
Project Number Q0l-fQ (fiQ 0 Matrix: §0fj Samp* Number: S FRA" if
Project ID: S\r*lXtr Fo/tSf~ RA Pn^ject Manager H**H\ $m*~H j fa+cMitioh
Location: y3i|^U30O^ • Stat®: «. £A ( /<-,-/£
Sample Comments; Sample Location Map:
Laboratory Analysis:
Container Preservative Holding Time
Ho e —"
/
Sample collected by:_
/
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number? Matrtx: $of/ Sample Numb«r: S FRA~~ JA
Project ID: RA Project Manager: H&*H\ S^t'H /iW^-kVftflt
Location: u3i \^U3©o^ State: fy~\Q
Superfund Name: £||»W||< S»'4«- Site ID:
s^vecK&rR/e-sf- ;
Location Description: / .Xvi- c.r: / j\ r A C D f /a.**-* ' j'J.
External Sample Number , •
Latitude; , Sample Collection: <- / c Time: • ,)
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
«7 &- — ^
Property Owner Information:
<£>*?• I" f v. k
Sample Comments:
" "7 '>
Qs^y4t J 4 CJ)
A-St-v
^ y
^ < ... _ V* T
/v .if- X
Sample Location Map:
/
Al
Sample collected by:_
T
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SThfcrr^K oMer
Project Number Q0LjQ 000 Matrix: Sample Number: S FRA~~-&
Project ID: S WK^ RA ProHwt Manager Sfift'H /jW-KW
Location: u3i\^UJ©0& State: yY\ Q
Superfund Name: £U,'wi'|)< Site- Site®;
S-VvfccKfc/" {tJs f- 5 wjjg/1
Location Description: 5 J \ , ,
External Sample Number: "i ^ < «*. 'y
Latitude: Sample Collection: 5-_ ^ -f H" Time: fta £
Longitude:
Laboratory Analysis:
Container Preservative
fa ^ ~~
Property Owner information:
C
-------
Simple Collection Field Sheet
US EPA Region 7
Kansas City, KS
Prefect Number 00^0 (&Q0 ¥,Wx: $0*1 8amptoNumber: S
Project ID: S+r«cK^ fh/tSb R A Project Manager. H**M Sttf'H I
Location: ujM^ioooC State: fsf\Q
Superfund Nam*: £|j»'wi'll< Si'^- Site ID:
s-b*cKe/*F»^t" S^kWH-
/*" ** v.* * - - '-V- 'J ?"> t. 1 3 <•
External Sample Number
Latitude: Sample Collection: <_¦ ¦• /*/ Time:
Lonartuda:
Laboratory Ariaivsis-
Wianil MmiFiMMflNn jp w^sMBtaj^wiiwa
Container Preservative Holding Time
^ • .-,c . * + -
Analysis
7"i' ^ + f , •
) ~ C * - :
U , y
yv
i,\ < ,
Property Owner Information:
,i ,,!r /!C <,'¦>' S«~y> <(. 'C'i
¦us
/
r/'
Samole Comnten^: Samole Location Mao:
liPBBN" if BbW^W' ¦ VfiP It %pMt"BllVrnP 4MI V livNM Vl^S
*-{' \« ^ - f >
/
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srxxmzK odtr
Project Number Q0H&.000 M*Mx: $6*1
Sample Numimr ^ P"$
Project®: Sf Sole?siH~
Project Manager Ht*Hl jikw4~M**§#
mo
Location Deeeription:
External Sample Number:_
Lwtttmfr*:
UHigictiae.
, /. j
JJ <&*<'
*Y
5V. c •
Property Owner Information:
7*
(e
/-A
« /-
~ /
Smtpio Comments: Sftiripki Location Mspr
v. x Ayf'C Lf .
Sample collected by:_ ^z. * ' .b' ^
7
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr**rr "TisK oiAer
Project Number: .000 MaMx: Soil
Sample Number: $ FRA~~-.l\-
Project ID: S R A
Location; u3i$U3©c>^
Superfund Name: £IKwi'llf Si'fc?- Site ID:
s-heiKerB/e^f S^kr/K->
Project Manager. HuM Sttf'H ffortJtCm
i: mo
Looation Description: -
External Sample Numbers
Latitude:_
Longitude:
J
D-s. e
Ji • oi>- u tv
Sample Collection: / y Time: ± y'f
LgfttMiMnBiCMfy J^ttsiiysis *
Container Preservative Holding Time
y A
t-r-
/
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Analysis
c "< ' '
Property Owner Information:
Z J
JL'S
r <7/,- -•
QMifTippp wOiTiiirBiltS.
J.
4'i.
Sample Location Map:
tzsfc:**- * ( 1 ^
Sample collected by:. /-¦'/A *
i
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sow^r "TisK oMer
Project Number; 00^0 QXZ0
Matrix: Sample Number; $ F~ ft A""""-* ^
Project©; SlrflXtT Fo/esf" ft A
Location; ujil^meo^
Superfund Name: £||,W|l£ S»'4tf — Site ID:
$-b*cKerR/e.sf- SukWR-
Project Manager Sttf/'H
State: yVAO
Location Description: :
External Sample Number:.
Latitude:
Longitude:
&)«t
Sample Collection: 5- y/y' Time: /fSS'
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
¦ ''*V 3
Property Owner Information: ^
O <%( i... ~~~
^44
Sample Comments:
Ko
fs" 4^ Z' © f *r>v
\ O.^f)
Sample Location Map:
-o >
fcr/ -J--*-// y ' j^,
Sample collected by:_ /C? UQurbt'%
7?^-
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
st**T74s.K oAer
Projmct Number 00^0 Q&Q) M8trlx: 5ofj Sample Number: S FRA""^
Project ID; S^lK^ Fb/eSf" R A
Location; u3t l^tae©^
Superfund Name: £||,W|jf Si*4^ — Site ID:
s-becKerR/c-^f S^kr/R-
Location Description: - • • '
External Sample Number:
Latitude:
Longitude:
Project Manager HmHl 3*tt'H /ifcu/^-kVnftt
State: fY\Q
Sample Collection
1 r-f'/i
Laboratory Analvsls*
Container Preservative Holding Time Analysis ^ - \
Property Owner Information:
—f
Sample Comments: Sample Location Map:
"^T ^ ^ ^ ** -I* t ^
r-^ynu,- *s r?~ *
/
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Sample collected far. —• ^ *
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swrnasK or^er
Project Number; Q)®0 Matrix: $©f| Sample Number: S FRA~~ Jf
Project ID: fbftsi" ft A
Location: uOildusdoA
Superfund Name: £f|;»vi'|lt Site — Site ID:
Project Manager. He*H\ Sw'fh /
state: mo
Location Description: /i :
External Sample Number:
Latitude:
-J «a
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srmrr^H o&tr
Project Number: 0040 , Q)Q0 Matrix: $0l/ Sample Number: S Ffi
Project ID: ShucKlS Fo/tSf" , Project Manager; HeqH\ SmftH /^k*€-kVnat
Location: LOt l^taoo^ State A ,/a a... rl
External Sample Number:
Latitude: Sample Collection: Time: CgS O
Longitude:
Laboratory Analysis;
Container Preservative Holding Time Analysis
i f* ^ W UfSd
Property Owner Information
r uwner inTormaoon; »
Sample Comments: Sample Location Map:
Sample collected by._
"ay
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, ICS
srT^crr^K oMer
Project Number; Q)Q0 Matrix: Sflf/ Sample Number: S FRA-~ h(
Project©: S-MtK-e/' Fo/tsf" RA
Location: u3t \buit>ob
Superfund Name: £||,'jvi||t Si k?— Site ID:
s-betKe/*F*^f" SojpslH-
Project Manager. He*Hi $W«H /iWt^kVnflt
State: iY\Q
Location Description: Ck Sj^stZ ¥f
External Sample Number: *^~
Latitude: , Sample Collection: Time:
Longitude: / < rf /'c '«£V
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAfTTT^K oder ¦
Project Number: Q01JQ 00 0 Matrix: * j Sample Number:
Project ID: SWuM-tT Fb&ft* RA
Location: UOilcWeo^
Superfund Name: £||»'wi'||-e Sj'te — Site ID:
s4>ecKSulfite-
Project Manager; He*H\ $m*H /iWC-kVftd
state: mo
Location Description:
External Sample Number:,
Latitude:
Longitude:,
*r y. J,
*f
Sample Collection:
s-fi-M
Time: Oy^o
Laboratory Analysis:
Container ,
Presereative
Holding Time
Analysis
/4/S&
Property Owner Information: •
-f.; ( h J I '
Sample Comments: • Sample Location Map:
IT
Sample collected bv: A-
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snvcriT&K o/Aer
Project Number 00tf g 000 Matrix: Sfiff Sample Number; S F/? A""~ Y%
Project ID: ShftKtr f?A Project Manager; -SwHl jIh*C.kV|M&i
Location: u3t l^usoo^ State: fV\Q
Superfund Name: £||»Wi'||* S»V- Site ID:
S-becKerFi/e^f SobflH-
Location Description: /y s { . t /i? X ^ i ^
External Sample Number:
Latitude: Sample Collection: Time: /•/2,5"""'
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis.
' ¦ '* 7/d-
Property Owner Information:
SI; (£* u. ^11 + ^' (
CfllA J
Sample Comments: Sample Location Map:
.&>k'
Sample collected by:,
-------
Samp)© Collection Field Sheet
US EPA Region 7
Kansas City, KS
STXXTT4S.K oder
Project Number;
iWfSitnx.
. fl Sample Number; S
Project©; Sbi+dfo/' FB/tS'b RA
Location: U3i \^u>00^
Superfund Name: £||»Jv»|)f Si*4^ — Site ID:
Project Manager. Smptft /iWC-kVflftl
State;
Location Description:
External Sample Number:,
Latitude:
Longitude:
rsX'v'A
^3/^1' IT
A'.
Sample Collection; Time:
Laboratory Analysis:
Container
Preservative
y ©X
Holding Time
Analysis
fits 6
Property Owner Information:
Sample Comments: Sample Location Map:
&>*
26&Z3
Sample collected bv: ^ ^
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr**rT7«s.K o^ir
Project Number: 00Hg 0X2)0 Matrix: So'l Sample Number: S
Project©: $br*tMtf FOASf" RA Project Manager; H&iHl Sttft'tfi / t\(b\
Location: UJ>i\^U300^ State: fV"\ Q
Superfund Name: £||i'wi'lk Site©:
s-becKer SobxiH-
Location Description: iDt'O JCtc*. Afz k < k g
External Sample Number: :
Latitude: . Sample Coltertton^/g-yY Time: ,
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
A/A , /kffA
Property Owner Information: r f n ^ A / » /
Sample Comments: Sample Location Map:
•A* JS ' £ t/JdO
Sample collected by:.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
smfiCT TisK odtr
Project Number 00<-f g Q)Q0 Matrix: Sample Number; 5
Project ID: S4i«Ut-€/" RA Project Manager; H&fH\ -WM / fau-t-Wi fi(bi
Location: vOi'l^uaftO^ State: O
Superfund Name; £(|tSvi'||f Site — Site ID;
s-hecKerFS/gusf S^kr/R-
Location Description: '7 f f &°/f /I
External Sample Number: ; , ,
Latitude; , Sample Collection:y - ^ , c[ Time; t >
Longitude:
Laboratory Analysis;
Container Preservative Holding Time Analysis
f oZ . ^<4 /«
Property Owner Information:
A-xf -SAc
V ^4/2
Sample Comments:
Sample Location Map:
Sample collected bv: A
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SfiMrr "TSsK Otker
Project Number: Q)Q0 Matrix: So'l Sample Number: S F"/? A"~ .
Sample Comments:
f
Sample Location Map:
Of /
^/cr^
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Sample collected bv: /' - (**%
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srAfcr oder
Project Number: 00ijg ^ MaWx,
:: $0fl ' Sample Number: S ^8
Project ID: S\r*LKtT R A , Project Manager; H&)H\ $Mft0t /
Location: UOil^lOdO^ State: f>f\ Q
Superfund Name: £||,'wi||f S»*4W/K- •
Location Description: / J ~y\« (( ¦ \
External Sample Number:_
Latitude:
Longitude:.
Sample Collection: Time:
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
Property Owner information:.
^ <*>.(( ^ r • *- ^
Sample Comments: .
i'
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm-KTM^Koder
Project Number: q @tf Q 0(2)0 MaWx: 5o'l Sample Number; S FRA~~
Project ID: S+rnXtT Fh/tst l?A
Location: u3i I^ujdo^
Project Manager: f fa+C-Wih(b\
State: fY\Q
Superfund Name: £||t'Wi'|)t S%\C^ Site ID:
s-t-^cKer F»/esf Su>k»//R- . •
' 4 f *:^ I* (( A Cc.3 ^ t
Location Description:
External Sample Number:.
Latitude:
Longitude:
Sample Collection: jf-(L~ ( A, Time:
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
Property Owner Information: . . ^ f , / 4
\ ' d ^
H V '
Sample Comments:
Sample Location Map:
zA
~~7C
f
£ /
Sample collected bv: '—*•»"**/
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snwcTTtzK oAer
Project Number: 00tfg Qffl0 Matrix: Sof/ Sample Number: S
Project©: S-b-clCer PoASf" RA Project Manager: $m*H /
Location: u3tl^uJOO^ State: Q
Superfund Name: £f|,'wi'|l<; S\\4- Site ID:
S4^tKerFS/rsf- s ul»WR* • \
Location Description: f fi J '
External Sample Number:
Latitude: Sample Collection: S"~ f£" f *{ Time: j ^ y (
Longitude:
Laboratory Analysis:
Container Preservative Holding Time , Analysis
• f
Pr°P'T~;tf;l^ u ^ ^({a
Sample Comments:
"f <*
¦f
Sample Location Map:
f
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Sample collected by: "y- »t
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snvcr~!*s.K oi^er
Project Number: (d(2>0 Matrix: 5©f| Sample Number: S f^RA'—
Project ID: S *mXtr RA Project Manager: H**M WM / fa+L~Wi't\(b\
Location: \jOi\bmmb State: fy*| Q
Superfund Name: £||ilW|if S»'k? — Site ID:
s-becKe/" F» /e,s t~ Su'loWfr*- v
Location Description: qfc f f -J9 CT
External Sample Number:_
Latitude: Sample Collection: _ - Time:
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
*(..Z <%rS&
Property Owner Information:
^'^yak f ^ /*«¦ CJ^ f( J)
Sample Comments: Sample Location Map:
m
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Sample collected bv: .**rt
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sowmisK Oder
Project Number Q0ifQ ,000
Matrix; Sample Number; ^ f-~ ft
Project ID; S+ftKtr RA
Location; U3i lc>ioooci
Superfund Name; £||,'iv»'||f Si4<3 — Site ID;
S+vecKe/" F* ^ f" SolpfiH-
Project Manager; /^tMt nd
State: ^ Q
Location Description:,
/!>,
«Q--
Y r
Latitude:
Sample Collection: <, Time:
Lonaitude:
Laboratory Analysis;
Container Preservative
Holding Time Analysis
Ci f ^
^ A; , / /'
Property Owner Information; s- f /£
J«x ( ft— ^^5.
Sample Comments: Sample Location Map;
i"-/¦? #?««
K . J <•
Sample collected-by:.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm*rCT4$>K®det
Project Number; QX2>0 MaWx: Sflf/ . Sample Number S
Project ID: S+yflXtf R A Project Manager Sm*Hi j
Location: lOil^nu mb State: fy*\Q
Superfund Name: £||»'tv»'|)< Site — Site ID:
s-becKerR/^sf- St^WK- .
Location Description:.
External Sample Number:
Latitude: Sample Collection: Time: ,»
Longitude: jf"***** ff ~/ 7
Laboratory Analysis:
Container Preservative Holding Time Analysis
Property Owner Information: - «^CJrji# , \
¦&&< ¥S ^^ ^£ ^Xk£fC¦'
jE
Sample Comments: Sample Location Map:
feJs £
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number q QLj Q Matrix: So f/ SamP,e Numb#r: S
j-f
Project©; S4tp*CF5/t5f" RA
Location: u3i l^iuooc^
Superfund Name: fUVtvt'll* — Site ID;
s^tferFii/csf"
Project Manager H&)H\ /(W^-kVnf&l
State:
Location Description: ? -3
.-ff
Sample collected bv: '
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sower 1%K od&r
Project Number: 00^0.000
Project ID: Fb/^st RA
Location: u3i \^U)0O^
Superfund Name: £||»wt'||£ S» 4t" So^iH-
Location Description: Jg. ss=... - ^ r4,
External Sample Number:
Latitude:
Longitude:
Matrix: Sample Number; S
Project Manager:
state:
/
Sample Collection: j"Z/yp. / ^ Time;
Laboratory Analysis:
Container
Preservative
Holding Time
i A
Analysis
o
Property Owner Information;
I i" rF Co
¦ af £^4 ( £~XC*?* fa
.(A
Sample Comments;
Ab-iv
Sample Location Map:
Sample collected by:_
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
smfiCT "HsK oder
Project Number. QQ0 mMx: $0*1 Sample Number: S
Project ID: Sk**lXtf R A Project Manager: He*H\ Smf»0l / kVfMbl
Location: u3i\^ujoo^ ' State:
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STTrfCr Tk$K Ol&eT
Project Number: Q0i-jQ 000 Matrix: Sample Number: S
Project©: Sbr*L,KV FBtSf~ R A Project Manager. He^M. /#U*4-kVnrt)1
Location: cOt \du3&0^ State: f\f \ Q
Superfund Name: £||& vi ||f Site Site ID:
• S-h*C.Kfc/" Fa /tlS f" Su\e>flH-~
Location Description: = -> f i 4 / /i o )(* ,s""g
External Sample Number:
Latitude: ; Sample Collection: ^ "• T,me:
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
Property Owner Information: „ _ ~ f * C-
_r,;r ^ fc
Sample Comments: Sample Location Map:
tt
Sample collected by:_
/ V v
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
ST7HTT 745.K o&er
Project Number: 00^0,00^ Matrix; Qtfj
Sample Number: 5 F~R -^7
Project ID: SH*lJCC/" R A
Location: U3t Ic^UJOO^ .
Superfund Name: £||,'w»'||£ Site — Site ID:
s-b*cKerR/g-sf Sukf/K-
•Project Manager: H&fHl Stfttft / f\(b\
State: fVlO,
Location Description: ^
External Sample Number:.
Latitude:
Longitude:
X? i )
i /e
-v>/e S^lCS'l
Sample Collection: z2- /H Time: //^ 0
Laboratory Analysis:
•
•
Container
Preservative
Holding Time
Analysis
^ s 2-
f ^ .
, />;7;
/V /J" ^5
Property Owner Information
U|iNfi l>y vWIIBI if If vl illuLIUI I. / y
Sample Comments:
'Sample Location Map:
Sample collected
by. /£. 4>
-------
Sample Collection Field Sheet
US EPA Region ?
Kansas City, KS
srmr TteKoder
Project Number 00*-f0 (&Q0 Matrix; Sample Number: 5 F"$
Project ID; 9br*0fcS RA
Location: u3i\duj©0^
Superfund Name: £||»'$\ri'|Jf S\\Q~- Site ID:
s-hecKerR/tsf- sjUr/R.
Project Manager. He*M $m*0l jCbu4Jt(ih(b\
State: fYXO- .
_ y
Location Description: ^0 ; v c
o / S~^-~
External Sample Number:
Latitude:
Lonaitude:
Sample Collection: s~-*z Time: /y- ?
Property Owner Information: ^ j /j- £
Sample Comments: Sample Location Map;
Sample collected by:.
11 rY^
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STfrKTlis.KoAtr ^
Project Number: Q0<-}Q Q>Q0 Matrix: $0fj Sample Number: S ^
Project ID: Sbr*lX*f Fo/tsf" RA Project Manager: / fahtM-Hitf!
Location: u3i State: fy~\ Q
Superfund Name: £||»svi'l!f Si'4«- Site ID:
s-v^iKerSt>Ur/R- ! ; __
Location Description: ^ I * <. » xi'oi.U «r/d i S 1
External Sample Number:
Latitude: i Sample Collection: ~/f Time: / 0
Longitude:
Laboratory Analysis:
Container Preservative
Holding Time
Analysis
f-i
MA
Property Owner Information:
-Sa>t f K' i e {**«•
-V. / / S J
Sample Comments: Sample Location Map:
S&Ar {/i//
Sample collected bv:, 'C
f-S
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srhfCT TisK o&et
Project Number QQ0 Matrix: Sfi?/
Sample Number; S F"$ A"—
«fO
Project ID; S+MtlfeS' Fo*t5f" R A
Location: cOi \^u>60^
Superfund Name: £||i(vi'|){ Site — Site ID:
s.-HeLKe,r Fa/e.sf" 5 Ug?// iHL-
Location Description: - <\ /%. . ;r r>
External Sample Number:
Latitude:
Longitude:
Project Manager H&lH. Sfit'tf* /flu>4-kVnfft1
State: fy^o
A'
.r^
Sample Collection: Time:
,"3
( *
Laboratory Analysis:
Container
Preservative
Holding Time
YA
Analysis
. ,• // n
Property Owner Information: ^ /c i J ^
Sample Comments: Sample Location Map:
/^f ^ A \ "Vs
Sample collected by: 1
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srmr TkK oiler
Project Number: q QLj Q qq 0 Matrix; $Q fj Sample Number: S FRA~~ ^
Project ID: SV^a-
External Sample Number:
Latitude: - Sample Collection: ^ Time:
Longitude: ¦
Laboratory Analysis:
Container
Container Preservative Holding Time Analysis
-o .
Property Owner Information: ' c"" , f ^ /"/"/-»
/ a , ,'c A V ,A £,-/ 3-
Sample Comments: Sample Location Map:
¦1' : * J, ^.yA ?
Sample collected by:. - -yt.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
staktt&K oA&t
Project Number; q QLj g ^ fyQ 0 Matrix: $Q */ Sample Number: 5 f $ ^— J-'>
External Sample Number: ;
Latitude: , Sample Collection: Time: tJS"
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
f.-j- yc r
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sowrriisK otAer
Project Number 0 Q'-j Q QX2)0 Matrix: 5 6*1 Sample Number: S
Project ID: S
Laboratory Analysis:
Container
Preservative
Holding Time
lino Tim
Analysis
J5
Property Owner Information:
Sample Comments:
V .. y>i *
Sample Location Map:
/V
Sample collected by:.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srmrr^K oder
Project Number 0040 QX2>0 MatrSx: $Oil Sample Number: S & V
Project ID; S+y+OfoT Fo/tsf" Project Manager / fau-L~Wil\(d
Location; Ujiit^Wd©^ State: fV\ Q
Superfund Name; £||»W||f Si'4<2 - Site ID:
s-H&cKer F» /e.s t~ SobxIH- __
Location Description: c' A 7) "c^% '
External Sample Number:
Latitude: Sample Collection: . Time: /0vj^
Longitude: ' S~'Z ? - / 7
Laboratory Analysis;
Container Preservative Holding Time Analysis
'/.? H° /
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, ICS
smm^^Koder
Project Number: Matrix: So'l Sample Number; S A""* &J
Project ID; S«b*C,Ke/" FS^tSf" RA Project Manager Ht*M SmffH, /iW^-kVnfot
Location: LOil^UiOO^ State: yV\ Q
Superfund Name: £||,l*vi'|)t S\\Q" Site ID:
S4mXe/* Finest" So\e>slH- ,
Location Description: J-) V G- ~ ,2 - C/' Jys f A
External Sample Number;,
Latitude: Sample Collection: jp-JL f -/^f Time: y
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
f* stH S-*
Property Owner Information: /•
J^fL
3 <*
Sample Comments: Sample Location Map;
•y V- - *•*
c * * v
7-
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Sample collected by:_
C
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STMCT T«sK other
Project Number 00*fg Q)Q0 Matrix; Sflf/ Sample Number: S ^Rh"~ <= •
Project ID: Sbr*lXW R A Project Manager: /#W-£_-kVnrt)t
Location: u3t l^loOO^ State: ecK&/"R/t-Sf~
Location Description: V CL €?
External Sample Number:
Latitude: - Sample Collection: Time: r/ £ £
Longitude: •
Laboratory Analysis:
Container Preservative Holding Time Analysis
f* s<)
Property Owner Information: / / / //
I <{(£*oTr O-JL' ^
Sample Comments:
L.J-'C/i.
Sample Location Map;
£
4
f'jr
U/
Sample collected by:_
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SThKT T*$K odlT
Project Number; q QLj £ # Q)Q0 Matrix: So f/ Sample Number: 5 f~ ft ^ J-
Project ID: S+r«cK*/" I? A
Location: u3t U3 oo ^
Sup«rfund Name: £||,W|]f Site— Site ID:
s-becKerR/e*>f- s^lyx/R-
Project Manager. He*H $mf«H f Cto+tJ<(i\(&
State:
Location Description:
External Sample Number:,
Latitude:
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number: , «Xj" ^ •<, t Matrix; j Sample Number: y ^
Project©: *_ c - Cc.*« * ^, f. Project Manager: f 4 **~». M / D f
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number: £ & en c
Matrix;
-S;-, f Sample Number:^ g y
Project ID: Sf Fores f ^.-*€
Location: fcfe&o*^
Superfund Name: £rftSv.tk J*;/e Site ID:
S"free fas r /ires"/ -fz
Project Manager: f{, Sm'ji/X).
State: JH$
Location Description: i ^4S~ ^
As- ¥r
External Samole Number:
Latitude:
Longitude:
Sample Collection: Time: ~
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Laboratory Analysis:
Container Preservative
y •
Holding Time Analysis
-< • ¦>
Property Owner Information: ^
a&{s
's. S'
Sample Comments:
• c- .-\sA-c
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Sample Location Map:
Sample collected by:_
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number:
SfMT To
&0<-fg.OOO
Matrix: ¦ { Sample Number: _$"' 70
Project ID: 5r
Location: it), (d
Superfund Name:^-f(z Site ID:
FH>f ' J^rf k
Location Description:
External Sample Number:_
Latitude:
Longitude:
£ As- A
Sample Collection: ./ ^ Time: ^5^3—
Laboratory Analysis:
Container
Preservative
cf=> I
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Holding Time
Analysis
- Jl'S
Property Owner Information:
o-Xy
Sample Comments:
y
/)/"_ A ^
Sample Location Map:
Xx v
Sample collected by:_
/
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
smcriisK filler
Project Number Q0HQ @@0 Matrix: $6*1
Sample Number: ^ ^
Project©: $«b*t,K-€/" R A
Location: U3i \<^UJOO^
Superfund Name: £||tSvi'||f Si'4
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr?rXT7*$K Oder
Project Number: gQtjQ Q&® Matrix: 5o'l Sample Number: S FRA"
Project ID: Rjitsf" R A Project Manager; He*H\
Location: UJt\^us60& State: fsf\Q
Superfund Name: £||,W||« S»'4tf- Site ID:
__ s^tKertnt/eSf- SjjexlH- .
Location Description: yf O *-3 " 5
External Sample Number:
Latitude: Sample Collection: ^ - 'y' Time: /Jf„3jr—
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
At f' K-4 /s/s G
Property Owner Information:
A <3 Cf *« Z5" ^^#4 CL
Sample Comments: . Sample Location Map:
—
v c-/4"c'
/ -iVy
, ¦ - ^ J I
f **! ' __L i H
.X' X
Sample collected by:_ /2
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swrr TSsX oMer
Project Number; 0040 Q)Q0 Matrix: So?/ Sample Number: S
Project©: S+t*lK^/" F5/e5f* f?A Project Manager: Ht*H\ f fa+tJtC*
Location: U3i \^u>00^ State: fV"\ 0
Superfund Name: £(|('jvi*|jf Si'te—• Site ID:
s-t->«€KerF»ir Su>kr/R>
Location Description: -<'¦*> /4» p, k Af * ?
External Sample Number:
Latitude: Sample Collection:^. Tltm: /SS*
-------
Sample Collection Field Sheet
US EPA Region 7 ,
Kansas City, ICS
sr*tfT7*s.K oder
Project Number QQ0
Matrix;
: SO 11 Sample Number: 5 F~$ ^ C(
Project©: Fb&fb R A
Location: M3tl^U3dO^
Superfund Name: £||^vi'|)f S»4tf-~ Site ID:
S^becKtrFi^f- Spy*IK-
Project Manager: He* Hi $m*H jCbu4-Mh(ti
State: fsp^Q
Location Description: . /) /-a ¦
External Sample Number:
Latitude:
33s"
Longitude:
Sample Collection-/"Lf Time: 0^~S~
Laboratory Analysis:
Container
y.
o tr
Preservative
¦fc
Holding Time
Analysis
o"
Property Owner Information:
_5i; (
Sample Comments: Sample Location Map:
ff
x*>*r
J?
Sample collected by:_j__
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srxxriizK o/Aer
Project Number Q)Q0 Matrix: $Gil Sample Number: S
Project ID: S\r*{XtT Fb/t5f~ RA Project Manager HeqHl Sm*Hk
Location: vOi |^U30O^ State: Q
Superfund Name: £||»w»'|l< Site-- Site ID:
S-becKe/'F»f~ SuiIpWK^
Location Description: • 3 U .< v
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sraxrtteK oder
Project Number; ,Q00 Matrix: Se?| Sample Number: S F~RA~~
Project ID: Slrt+OfcS fb/tst ftA
Location: u3t \^U30O^
Superfund Name: £||»W|lf Site - Site ID:
s+*tKerR/e.*f- sobxIH-
Project Manager: /£W4-.kVn
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Proje* Number Matrix:
Sample Number; S J |\ *- -
Project ID: ir«r*tKf« /'o J K r ^
Location:
'.O-u^OCK'
Superfund Name: c||,'j»vi'bf Si'k-' • Site ID:
s+ve<. s j,-e t» f S v bi" 1
Project Manager: -W, -h/fh&tl
State:
Location Description
External Sample Number;,
Latitude:
fee * feT"
Longitude:,
Property Owner Information:
Sample Collection:
6-5H1/
Time:
12 35
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
TO
V-
It <3 6
Sample Comments:
£eii fociA f A3 C--
* A? 171"
Sample Location Map:
Sample collected by: [Ul\ ,£
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr;iK'i Sf4*K^w<
Project Number , . ;t. ^ . Matrix:
Sample Number: 1 .v
Project ID: i> rrnKo f 6 ab 1 « *
Location: a." < 'iuujooo
Superfund Name: * U *c Site ID:
s-t-w?cKe* :>vk»/iH
Project Manager: 5mnf§t j ikubtMVft«»»«
State: A . ,
Location Description:,
External Sample Number:_
Latitude: ,
Longitude:
JBAaaIi. pre Ml K. 6~2-t
Sample Collection:
P-svy
Time:
/ZIP
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
He ^
1'C,
hr-
\UfiK
Property Owner Information:
Sample Comments: Sample Location Map:
£o\\
&9>c * 3lS"*x5
Sample collected bv: Kii/^pt'') lr\
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr4Ki O.L-r,
Project Number: ^ ^ Matrix: • :
Sample Number: ^
Project ID: % t»H K^. ) O * t> * « '
Location: U.' , \o*x>00i>
Superfund Name: ^ ^. a Nk Site ID:
Project Manager: Hetf > n J
State: A, }
r-i.of
J wiS'i I rv
Location Description:
External Sample Number:,
Latitude:
_P i c iRd A BB
Sample Comments:
fo,l
a jxill
Sample Location Map:
Sample collected by ' \
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm^tr Tm„H •
Project Number: ^ -
Matrix; : Sample Number; f, fiQ
Project ID; s tt-H Kf> 'O es» • « ¦"l-
Location: u ' , .uuioiH.
Superfund Name; v< * «<¦ Site ID;
S+wsiKei i'i.fbT i
Project Manager; />v < /> J > rfiuHL-kVliflii.
State: A ,
Location Description^
External Sample Number;.
Latitude;
Longitude:.
Sample Collection:
(e-5 N
Time;
mi
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
hr
Property Owner Information;
Sample Comments
-------
Sample Collection Field Sheet
US EPA Region ?
Kansas City, KS
Project Number: , , - Matrix: " Sample Number: -• j
Project ID: Xe» i 0f>! *<'"•
Location: a ;o u.'t>oo
Superfund Name: : ; iV,, « -t < Site ID:
sfwitKef w.( ir*'
Project Manager: r/W t * S»i«f
state: t\ 4, ;
tao-
k'metft
Location Description:
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
U'-'r. o.aer
Project Number: _ Matrix: <-[,*
Sample Number: ^ f- • l%! ,*¦; ~ f\ 2-
Project ID: S i Kt t fob! « *;-
Location: a "> > ",v u' 00 u
Superfund Name: tll.Wt'uf Si'-k-' Site ID:
S -yw> j Ke«' »'"» t s T i> ubi" ir< ¦
Project Manager: 5#;' /. ( *<*•> »./mK
State: A * ,
Location Description:
External Sample Number:,
Latitude:
Longitude:,
Sample Collection:
Time:
ife:"2-8
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
Hot-
r'o
hr-
Property Owner Information:
C>
Sample Comments: Sample Location Map:
a>i|W-«0lS A+R(k
& I
Sample collected by:.
KuyBv
-------
Sample Collection Field Sheet
US EPA Region T
Kansas CSty, KS
smxTTizK Oder
Project Number Q 0^ ft . 0
Matrix:
: 5q'| Sample Number: SP7?A"""$3
Project ID: S^lK*/ fb't>T~ (?A
Location: uDt |du>dod
Superfund Name: £||,'Wi'|)« S»4tf — Site ID:
s-hetKerB/csf- S^kr/R-
Project Manager: ' He*H\ $*fiH ,*
state: fvl O
Location Description:
External Sample Number:,
Latitude:
0 i c -£llt< D.».% 6>*"7.
Longitude:,
Sample Collection:
i-Hi
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
^0 L—
1ec,
\^r.
/< 35-
Property Owner Information:
Sample Comments:
si»k Wv £43 sjVctlU AjJ?
Sample Location Map:
Sample collected by:_
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srhKTT^K other
Project Number: qQHQ Q)Q0
Matrix
: 50*| Sample Number: S TRA" s1
Project ID: S 4t«lX-£/ Fb*sf~ R A
%
Location: tOi luuoOOO
Superfund Name: £||,'*vi|jtf Si tC— Site ID:
s-h*cKerF»/c-*f- Sob/iH-
fnh k, Bo ftC£t
Project Manager:
state: ^ q
Location Description:
External Sample Number:,
Latitude:
Longitude:,
Sample Collection:
6't'iy
Time:
/#¦'?*
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
fo
\Y-
I fell 6
Property Owner Information:
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
staktt^K Oder
Project Number: Q0M0 000
Project ID: S +t«lK-£/ Fb
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City. KS
sperms K od er
Project Number; Q 0^ ft Q)Q 0
Matrix:
: $0 •/ Sample Number: S
Project©: S-i-mJCer fbft. St" If A
Location: COi \0uiOod
Superfund Name: £||tWi'llt Site ID:
S-h®tKef B/eSf $j\psIK-
Project Manager: H&*H\ j t)bL+tJK*h($
state: mo
Location Description: *T & 3 -pjaetT 5Vbgl|\^ F) P
External Sample Number:
Latitude: Sample Collection: Time:
Longitude:,
6-fc'lV
It -
Laboratory Analysts:
Container
Preservative
Holding Time
Analysis
Ho^
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1 la \ U B
Property Owner Information:
Sample Comments: Sample Location Map:
*v g f\ |
pie uommenis;
f^e.Ar^ piV -Ploor
MVS _<=, tvec-x^
~xcs Ic-
Sample collected by: _K
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sowtT "RsK oiet
Project Number; Q01Q @@0
Matrix:
5o*/ Sample Number; ^ —
Project ID: S ft •'£$ t~ f? -A
Location: u3i Ic^uaood
Superfund Name: £||,'wi<|if S»'4tf — Site ID:
s-h*4Ke/*F5^.sf" So\e>slH^
Project Manager: HettfA Wf*
State; yV^O
Location Description: f A3 f»'V ^ C'
External Sample Number: -
Latitude: Sample Collection: Time:
Longitude:
Laboratory Analysis;
Container Preservative
He
fu
6~(s-11/
17: <0
Holding Time
V'
Analysis
lb 13 s
Property Owner Information;
Sample Comments:
Sample Location Map:
Sample collected by:_
i/\i I \
!vlm v
•V
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number:
Matrix:
So?/
Sample Number: ^
fra~$S
Project Manager: Hltit*
State: ^ Q
Project ID: S+*«lK-C/" Fb/tSf*" (K
Location: uj)t \c)u30od
Superfund Name: £||,'Jvi||f S»*4^ — Site ID:
s-^etKerB^sf- Sj^s/K-
Location Description: C A 3 pfruJCL 1U SiJk flUl » 01Q £u¥ atolls ^
External Sample Number:
Latitude: Sample Collection: Time:
Longitude:
Laboratory Analysis:
Container
l*| 0
Preservative
b-b-N
I to 3
Holding Time
Analysis
i&vm
Property Owner Information;
Sample Comments:
Sample Location Map:
Sample collected by:.
-------
Sample Collection Field Sheet
US EPA Region T
Kansas City, KS
SfMTlsK
Project Number: 0 Q 000 Matrix:
SOl'/ Sample Number: S FR^—S^
Project Manager: Htaffax 5*^//^
State:
Project ID: S 4T«LK-d/ Fb/ttSV f? A
Location: U3t \c)ua&0a.\\ 0^ ^er^K <<* Mfat h/^£l^ ^1 ^
External Sample Number:.
Latitude:
Sample Collection:
Longitude:_
-bVi
Time:
/ $*sr~
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
iDl
fU
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Property Owner Information:
Sample Comments:
ffS SoW fir
E?lacK/j^ '
Sample Location Map:
Sample collected by:
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Sample Collection Field Sheet
US EPA Region T
Kansas City, KS
STAfirr T4$.K otter
Project Number @00
Matrix:
$0*1 Sample Number: S JO
Project ID: S ft * T « A
Location: u3i \c)u>C>od
Superfuntl Name: £||^vi'|)f Site — Site ID:
s-hiKfcfB/efrf-
Project Manager: 5*t.~(Hh J tkj-t-Mi'hibft
state: nAO
Location Description:
External Sample Number:_
Latitude:
fc 4 C fii
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Longitude:,
~7^Z
Sample Collection: j~- *; - /
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number: s- . , y'
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Matrix:
Sample NumbenX/^y#- 7 I
Project ID: Sr 4,^
Location: •'
Superfund Name;» ,-( i / {&- Site ID:
_5 r A "<£<-a s / ^ f-vij. b
Project Manager: /fi^{l/LO, £nf J
State: Al C
Location DescriDtion: £Z io -C>
¦JL-Y'
External Samole Number:
Latitude:
Longitude:
Sample Collection: -7~ Time:
G>
Laboratory Analysis:
Container Preservative
y.*-
Holding Time
/ f*-
Analysis {4fS^8
Property Owner Information:
M yd r ^
'-jt . /\ f
J> '**(¦
Sample Comments:
Sample Location Map:
f\-.
-J ' v-
£jl
" * * [
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Sample collected by:_
^
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srn^cr TisK oAet
Project Number: QQijQ QQ0
Project©; SFD*sf" RA
Location: tOi \c)ujOO^
Superfund Name: £||,W||f Si'4« — Site ID:
s-h*tt(£rFinest- So^slX-
Matrix: ^§ff Sample Number: • ^ ^
Project Manager: H*iW\ $m*H jQBL+tJ<(*t\(b\
State': mD
Location Description:
External Sample Number:.
Latitude:
Longitude:
C«Sr
"sample Collection f
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Time:
Laboratory Analysis:
Container
Preservative
Holding Time
Analysis
Y«
«4-y/ °^"-r a
j-
¦t. 1/ ^
>7?
Sample Comments;
Sample Location Map;
(^e?
Sample collected by:,
: /£ 'tH.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm^T^Kodet
Project Number: 000 Matrix: 5fif/ Sample Number; S
Project©; S"
r o ZAfh
Sample Comments:
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US EPA Region 7
Kansas City, KS
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Project Number: Matrix: $0*/ Sample Number; S
Project ID: S\r*L^tT K»Asf" R A
Location: vOi \^mmb
Superfund Name: flh'jvt'llf Site ID:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
oi^er
Project Number: 000 Matrix: "$Q fj
Sample Number: 5 fR A~~
Project ID; S4t*C,K^ F6/tSf" RA
Location: vOi .
Superfund Name: £||»W||f Srk?-~ Site ID:
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Project Manager: $m*0l / fo+cMt noA
State: rsfXQ
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snwzr T5sK otktr
Project Number: 00^0.00$ Matrix: $0*1 Sample Number; S
Project ID: fb/tS'h R A Project Manager: H&fH\ KVnfll
Location: U3i\^U3©0^ State: fY\Q
Superfund Name: £||,W|lf S»'4« — Site ID:
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Location Description: s \' y2 £' '
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Latitude: Sample Collection: Time: J .
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Container Preservative Holding Time Analysis
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr**rr7«s,K oMer
Project Number; QXfi® "atrix: $0?| Sample Number; S V 7'
Project ID: S"b*LK*/" Fo/tsf" f? A Project Manager; H&iHi $m*0l jCbu+tJ((*h(b\
Location: u3i\^U30O^ State: Q
Superfund Name: Si'+tf —• Site ID:
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Property Owner Information: t S ji
Sample Comments; Sample Location Map;
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
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Project Number: 00^0 000 ' Matrix: 6o'l Sample Number; 5 F^RA^
Project©: $+*•(&/* FS^tSf" RA Project Manager: /ffcu/^-kVnftl
Location:, State: fY\Q
Superfund Name: £||»'wi'|)£ St'te- Site ID:
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/£ &/( TL
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKT T*c,K oder
Project Number; 00H0 , Q)Q@ Matrix: $0*1 Sample Number: S ^
Project©; S-hr*tK«/" RA ¦ Project Manager: Hi*Hi SiHttf* / A
Location: VOi\^UJOO& State: fy~| Q
Superfund Name: £||&vt Uf Si'4 y\:^
Property Owner Information:
/joa' 7-J $4'¦«<>* V-V«
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
stakt "Ta&K oi^er
Project Number: 00tf0 Q)@0 Matrix: So'l Sample Number; S F7?A~~/0i>
Project ID: fb/tsi" ft A Project Manager: S#ttf4l /jW^L-kVnftl
Location: U3i l^uaOO^ State: Q
Superfund Name: £||,'wi'||t Si'te— Site ID:
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Location Description: 73>a-v> *v A^T¦ I* /^S o \ / V . ~
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Property Owner Information:
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Sample Comments: Sample Location Map:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
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Project Number 0Q0 Matrix: Sof| Sample Number: S /#/'
Project ID: S+r*lXtr Fo/tSf" RA
Location: u3i\^U30O^
Superfund Name: £||»Jv«'||f Si'4«- Site ID:
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State: fY\Q
Location Description:..
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srAfCTTt&K oder
Project Number 000 Matrix: $0*/ Sample Number: S F~RA'~~ - ^
Project ID: SWuXtT Fb/CSf" f? A
Location: U3t\^ujoo&
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External Sample Number:,
Latitude:,
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Laboratory Analysis;
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Sample Comments:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKV OfktP
Project Number Q/20 Matrix: $Qij Sample Number: $ F"f?
Project ID: $4i*cK£/" R A
Location: U3i\ciuJOO^
Superfund Name: £||*Wi'||£ Site" Site ID:
S-b«cKt/" Fe /e.S f" S If£-
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State: yVAO
Location Description: J) "ia*»-C« ;e
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Latitude:
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Laboratory Analysis:
Container Preservative Holding Time Analysis
li'L Y' / y*. -y
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, ICS
snvcntzK oder
Project Number q 0<-f Q Q)Q0 Matrix: $0*1 Sample Number: S F~$ /of
Project ID: Fo*$f~ RA Project Manager: HmHk $m«~H /fa+€-Win(ti
Location: cOt I^ujoo^ State: fy^Q
Superfund Name: flK'ivi'Hf Si'4
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snucriizK oi&er
Project Number: Q0ifQ Q)Q0 Matrix: $©f| Sample Number; S F'RA'^ Jo5~
Project ID: S-W^cJCd/" F6/t5f" f?A Project Manager: H&iHt Smti0i kVnfl)
Location: U3t \c^U)0O^ State: fsf\Q
Superfund Name: £||»Wt'|)£ S»'4f-
Location Description: T* i ^g-s f
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Latitude; Sample Collection: Time; /Tff
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Container Preservative Holding Time Analysis
Property Owner Information:
1* J f rfn (A.
Sample Comments: Sample Location Map:
/A i
Sample collected by: A-
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKTVi^K O&lT
Project Number: Q01JQ 000 Matrix: $0fj Sample Number: S fRA"" A
Project ID; S+t^lK*/' F5/e5f" RA Project Manager, HfyHl
Location: U3i\^ujoo& State: fyf\0
Superfund Name: Si'4»- AT-Cr'.rf
Property Owner Information:
'Csji ^ M-fu/
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Sample Comments: Sample Location Map:
L
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Sample collected bv: / '*.//>£
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
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Project Number: q 0^ Q Q)Q0 Matrix: Sfif/ Sample Number; S / J r
Project ID: RA Prelect Manager. H&tW\
Location; LOi \^U56Q^ State: ± S 3
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Oder
Project Number Q)Q0 Matrix: $fif| Sample Number; S fRA~~ /&<&*
Project ID: RA
Location: tOil^usOO^
Superfund Name: £||,'wi'||£ S»'k?— Site ID:
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State: fVlQ
Hi Hi Sm'Ht /itu^t-kVixt
Location Description: 23 < j.; , - r1' • V -1~
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srtrKriizK ot&er
Project Number: 00^0 Q)@0 Matrix: $0*1 Sample Number; S / 0
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srhfCTT^K oiler
Project Number 00L/0 Q)Q0 Matrix: $0*1 Sample Number: S
Project ID: Fb/tSf" f? A Project Manager -WM /#W-£-kVnfl)t
Location: Uj>i \^u>60^ State: fs/\ Q
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number 00 0 Matrix; §0fj Sample Number; S FRft~~
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Project ID: S+r*OfoS Fo«5f" R A Project Manager: HmHl «WM /dW^-kVnflt
Location: u3t l^UJOOci State: O
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm^rmKoder
Project Number; Q^Q0 Matrix: §e• J Sample Number: 5 p$ //^
Project ID: S+t*(JC€/" R A
Location: yji \^u>oo^
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
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Project Number q Qij 0 Q^Q 0 Matrix: §e fj Sample Number: S FRA~~ '
Project ID: S\r*lXtr Fo/esf" RA
Location: u3t\^U30O^
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State: fY\Q
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Property Owner Information:
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Sample collected bv: ^ vf*
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SThKT "T5&K Oi^eT
Project Number Q&0 Matrix: Sflf/ ' Sample Number; S
Project ID: FB/ttSf" RA Project Manager -WM /iWt-kVnf&t
Location: lOi \^U>0O^ State: Q
Superfund Name: £||,'wi'|)f Si4<2-~ Site ID:
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Latitude: Sample Collection: £ y Time: f
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Container Preservative Holding Time Analysis
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srhfCVT^K oAtr
Project Number Q Q QQ 0 So'l
Sample Number; S ^ Rh"~ i ! ^
Project ID: S-h*cK*/" Fb/tsf~ RA
Location; yji \^mmb
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State: fsTiO
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Sample Comments:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snwrr t«s.K oder
Project Number: 0(20 ,toIrtx: Sflf / Sample Number: S F Rh~~ f (£
Project ID: S •W*cK00^ Stele; O
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKTTmK oder
Project Number; 0 g 0 Matrix: ^Qfj Sample Number: 5 fft ft — / / /
Project ID: s+r*dter RA
Location: U3i Ic^UJOO^
Superfund Name: £f|^vi'||^ Site" Site ID:
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state: mo
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Sample Comments:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
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Project Number: 00H&.000
Matrix: $0fj Sample Number; S ((%
Project ID:
Location: U3i \^UJOO^
Superfund Name: £||iWi'|)£ S» 4^ — Site ID:
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Project Manager: H*fbh SmH f fo+cMi'htot
State:
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External Sample Number:.
Latitude:
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Sample Collection: Time: ^
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Container Preservative Holding Time Analysis
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Property Owner Information:
T + At
Sample Comments: Sample Location Map:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
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Project Number: 00H0.000 Matrix: SOll Sample Number: $ FRA— //OOC^ State: fY"\ Q
Superfund Name: £(|«sv('tif Site*- Site ID:
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Property Owner Information:
sfc. V *£ X of
Sample Comments:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Project Number; 0@^0 (&Q0 Matrix; Sample Number: ^ p
Project ID: S+r«tKe/' FS/e5f" R A
Location: U3<\^U>60^
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Latitude:
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Container
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A/s
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
o&er
Project Number: 00^0 . 000 Matrix: $0l/ Sample Number; S -UI
Project ID: Sbt+OfoS Fb/tS^" RA Project Manager HtyHl S*tij4\ j fauJ-t-Mi
Location: U3i l^UJOOci State: fV\ Q
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Sample Comments:
j£
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr**T7*c.K oder
Project Number: 00^0 Q)Q 0 Matrix: $0*1 SamPle Number: S Fft A"~~
Project ID: F6/tSf" f? A
Location: u3a\^u>OOC&
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Project Manager. H&>H\ Sitfi'tfl /thu*e—W*mi
State: fY\Q
Location Description:,
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Latitude:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srhfcrr^K otktr
Project Number; 00fcf0 . Q)Q0 Matrix: $0*/ Sample Number: S F ft A ~~' ^ ^
Project ID: S-b^tKer Fb/tS'h RA Project Manager H&tH\ frC+'fifljl
Location: U3i\^uaoo^ State:
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Location Description: ^ , 3 si -O O "[
External Sample Number:
Latitude: Sample Collection: / f- fcf Time: . ;/ -o'
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
Property Owner Information:
^4 r-i r*«. ,"V > r,%~ * t-
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SWCTT4S.K oder
Project Number: 0 Matrix: 6o 11 SamPte Number: S
Project ID: S-br*cKd/" F6/t5f" RA
Location: VjOi\^UJ60^
Superfund Name: £||»Wf'||£ StSite ID:
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External Sample Number:.
Latitude:
Longitude:
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Sample Collection: f -/*{ Time; /JU |f
Laboratory Analysis:
Container
Preservative
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
Sn^Tl^KOfAeT
Project Number: Matrfc So*/ Sample Number: S FR/\—/jS~
Project ID: fib/CSf" R A Project Manage: H**Hl Sm*H j
Location: Uj)t IcIujooc^ State: Q
Superfund Name: £||,W||£ Si'4
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
y. V" ^ /sv-y <5
Pro >
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
snvtr lis-K oder
Project Number: 004Q 000 Matrix: Sof / Sample Number: S
Project ID; S h+lfaS' FB/tSf" R A
Location: u_)i l^iudo^
Superfund Name: £||,w»lif Si4
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swrr Us K
Project Number: 00^0 . Matrix: $0*1 Sample Number: S ^ Rh" ^7
Project ID: S W*0&tS Fo /C5 K A
Location: u3» l^uiooc^
Superfund Name: £|j»ivi'|)f S* 4 f~ Sujg//f€->
Project Manager. Hextih / $w-€—kVflftft
State: fsf\Q
Location Description: JDro tc> j&c T- /c -<^0 eP
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STkKV T*$K
Project Number.- ®Q0
'roject ID: S ¦fr^cX-d/' Fb/tsi"" R A
Location: cOi \^ujooci
Superfund Name: £||»'wi'||f S»*4tf Site ID:
Matrix: fj Sample Number: S
Project Manager: H&lH $m'H /ftu-L-Wthfo
s-^ecKe/~ S o\p/IH-
State: yVAO
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STA/rr T«S.K Ofier
Project Number: Q040 Q)Q0 Matrlx: So*/ Sample Number: S FRPt~//fC-
Project Manager: /A^.k'i'tntV
State:
Location Description:
External Sample Number:_
Latitude:
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Longitude:
Sample Collection: p. f. f >-[ Time: O f$Zf~
Laboratory Analysis:
Ocntainer
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Preservative
Holding Time
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Analysis
o ( J
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Property Owner Information:
a- ^ f j-» r7
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Sample collected by: A~ '^r
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STA/cr "RsK oMer
Proiect Number: 00^0 000 Matrix: Sof/ Sample Number: S ^
Project ID: S Hotter Fo/csf* R A
Location: u3i|titjO0O^
Superfund Name: £||»jv»|)'f Site ID:
S4neiKe/"F5/tsf" Solpx/H^
Project Manager: H&)Hl JW~M
State: fVIO
Location Description
External Sample Number:,
Latitude:
Lcngi:ucte:
: Atf-aJCC /} Af<£ su/
Sample Collection: 2 Time: 0*ff 0
Laboratory Analysis:
Container
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Holding Time
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Analysis
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Property Owner Information: / //
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Sample Comments: Sample Location Map:
Sample collected by:_ ^ u.j.hA
LyjltA
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SThKT oiit
Project Number: Q$0 Matrix; Sample Number; S FRA— /3l
Project®: Sfr-LlC^ Fo^sf" R A Project Manager; H&)H Smf'H
Location: u3t \ciuJOO^ State; f\T\Q
Superfund Name: vi'Uf Site Site ID:
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Location Description: f 5 It /¦*, { I
External Sample Number:
Latitude: SamoteCollection: -»?:>./<-/' Time;
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Laboratory Analysis;
Container Preservative
<-%¦ *f
Prrwrty Owner information:
r-'^-szrn
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Sample Comments:
Holding Time Analysis
Sample Location Map;
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Sample collected by. ^ t " rzJ!.,
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKT T4&K Oder
Project Number: 00^0 Q>Q0 MaWx: So'/ Sample Number: S ^ Rh"
Project ID: SbflK*/' ft A Project Manager: H&tH Smitfi
Location: UJ5» State: fy^\ Q
Sjperfund Name: £f|,W|J< Site- Site ID:
S-hecKtrFi/t-^l-
Location Description: ^ J i c/tVi * ^ S 'Al O f (
External Sample Number:
Latitude: Sanrmle Collection: 7 > Time: , '(-/So
Longitude:
Lafc oratory Analysis:
Container Preservative Holding Time Analysis
Y" / 4
Property Owner Information:
XjT K 7<*&
Sen pie Comments: Sample Location Map:
Sample collected by: v 'V 'r^
j
i by:_
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
smcr "u sff oAtr
Project Number: Q}Q0 Matrix: $Qfj Sample Number: 5 ^3
Project ID: S Fo/tsf" RA Project Manager: He$fh /#U/-£_kVnrt)tl
Location: U3i I^UJOOci State: fY\Q
Sjpe.-fund Name: £||»iv('|lf Site — Site ID:
_ S-HetKejfFi^sf SobtlX-
Location Description: ~/'J * a
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SWCT T4S>K oMeT
Project Number: QQQ) Matrix; $0fj
Sample Number: S F^RA~~~ (3^/
Project ID: S br+lX-tf <€$f"" ^ A
Location: Uj)t |tlt&350^
S.j;/2 cry^s c
Sample Comments:
Sample Location Map:
''if
/ V -fcr3/• K
Sample collected bv:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srhKT Tks.K
Project Number: Q 01Q 000 Matrix: So 'I Sampte Number: S f
Project ID: S^dCe/" Fo/tsf" RA Project Manager: H&lfh /#tv/-e_-KVnflf^
Location: uOiliiuomb State: O
Superfund Name: £j|,'Wi'i}( Site ID:
s+^ecKerB/tsf s^kr/fe
- — . , ft
Location Description: v f —3 Co r Wg O ~ <' X -f't
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SThKT ThzK Oder
Project Number: 000 M&trm; Sample Number: S f3 &
Project ID; Rjitsf" R A Project Manager. -WM
Location: Ut3f IcWdOtl State: fy^Q
Superfund Name: £||,'wi'ii£ Site— Site ID:
s-t*edCe/-Fi/esf Sobs IK-
Location Description: v^T"* ? 7 - -
External Sample Number:.
Sample Collection: j • ) • . ••* Time: /sZf^
Laboratory Analysis:
Container Preservative Holding Time Analysis
Property Owner Information:
f ^ /£t*
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swrr TisK oMer
Project Number: QQLjQ Q}Q0 MaMx: Sotj Sample Number: S f ^ ?
Project ID: S bt+Ofoj~ fwe$f" I^A Project Manager: t
Location: u3i \cWdOtl State: Q
Superfund Name: £||,'wiii£ Si'k?—' Site ID:
s+^tXerB/tsf s^fc>WK~
Location Description:
External Sample Number:
Latitude: Sample Collection: ~Time: /SZs* 2^-
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
/4-j r". ic xH 3 X ^
c
:/C a- c/ / /A. / ^
Property Owner Information: ^ ^
._0; | ^ f-* ^ f ^ A. ^ 25
Sample Comments: Sample Location Map:
./o|/iWf
Sample collected by:_
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
stakT 7*c.K oMer
Project Number: Q)Q0 Matrix: So'/ Sample Number: S / J f
Project ID: S FottS I? A
Location: cOi \clU)OOC^
Superfund Name: £||,'wi||f Site-- Site ID:
s-betK&rB^sf s^kf/K-
Location Description: <£ J~r / A/CnA'Vz**#- A"/b<€
External Sample Number:
Latitude:_
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
<¦/«> ^ y*. . -.
Property Owner Information:
*-*C ft
^c.
Sample Comments: Sample Location Map:
Project Manager: H&ith /#W-£_-kVnfl)H-
State: ^ q
Sample Collection: J - /o ~ f V Time: jp
Sample collected bv: ' ^
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKT T4sK Oder
Project Number: 0^ 0 Matrix: $0 •/ Sample Number: 5 f ft ^
Project ID: FB/e5f" RA Project Manager: Smrtfi /|W*_-kVnrt)t^
Location: vOt \du>t>oci State: /Y*\ O
Superfund Name: £||&vi'|!€ Si'te"" Site ID:
s-fr^KerFj/tsf- s^kr/fe>-
Location Description: ^ V / f* * V>. . /~A / i' <¦"
External Sample Number:
Latitude:
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
c/* £ //*- -V /V ^
Property Owner Information: t f\
4*4 ( // k? Corr^A J U/ V
<">_<(•. -zz-Y*
Sample Comments: Sample Location Map:
Sample Collection: «/*^ Time: y 2 «
Sample collected by: ra ~f,
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
ST/wcr T*c,K Oder
Project Number; q 0tj Q _ QQ 0 Matrix; $0«/ Sample Number; S / ^
Project ID: SKfe/" Fb/CSf" Project Manager; H&lM j
Location; u3i \dtooo6 State: Q
Superfund Name: £||,'wi'|)€ Site ID:
S-tmeiKe/* Fi ftA f~ Su" jQ f Si/ £ kJ & C (Jcs-f)
Sample Comments: Sample Location Map:
Sample collected by:.
/IVn^-o
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKT T^K oiet
Project Number,* 00^0 Matrix: Sotj Sample Number: S ?l
Project ID: Sbr*0foj F&«5f" KA Project Manager: Heqfh
Location: vOi \OuJOOci State: fy^Q
Superfund Name: £f|,Wile Si 4'!
Property Owner Information:
CS^/C -
Sample Comments: Sample Location Map:
Sample collected by:_
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKV oieT
Project Number; Matrix: $0f/ Sample Number: S
Project©; S-b*lX-er jrb5
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SfhKT T«sfC oMer
Project Number: q 0 tj Q
,000 Matrix: SOt I Sample Number: S '*^3
Project ID: S+n^tJC-Ci' ftitsf" K A Project Manager: JW~M jHho-L-Minoft
Location: U3i Itltioaod State: ft/"! 0
Superfund Name; £J|,l$,v»"Uf St Site ID:
S-f-fcetKei" F» /g-S f~ S u't?/ / ffi.
Location Descriptions A* r y/
External Sample Number:
Latitude: Sample Collection: ^7 Time:
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
y* / y* ayj-^
Property Owner Information
r information: ,, /
s-.t[ ^ c° '
Sample Comments: Sample Location Map:
^ I 7 a.. b
Sample collected by:_ Kim
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
stakt oder
Project Number; Q)00 MaMx: 5©?| Sample Number: S F'l'M""" • "/*/
Project ID: s-MiK-er Fbrtst R A
Location: " .C- * ,*¦>- ¦** ~ 9 ^
4^-sifl j£C5 J cr A - * r - ° K
Sample Comments: Sample Location Map:
jsf
Sample collected by: Ac
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
5mfCT TtzK oier
Project Number: 00*jQ^000 Matrix: ^0*j Sample Number: S F K 7^5"
Project©: fb oo State: fY"\ Q
Superfund Name: v.'lif Stte- Site ID:
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Location Description//"-•> v / : r. /l ; \ "? *>'
External Sample Number:
Latitude: . Sample Collection: J 1 Time:
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
i* f r /* •*((; J.*1-* A < - ^
Sample Comments: Sample Location Map:
A** "*^11
X
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Sample collected bv: ' ~ ^
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SThKT Oder
Project Number:
Matrix: 50'| Sample Number: S /V£*
Project ID: S Fb ti» K ' ^
Location: u3i \giju;l>oo
Superfund Name: £(|,'*vi'||£ Site1'" Site ID:
S4-vecl\e/*F^esf SuMR-
ProjectManager: j
State: fvlO
Location Description: c - -
External Sample Numbers
Latitude:
Longitude:,
Sample Collection: 2*.^^-, -y
Time:
Laboratory Analysis:
Container
y-» 4-
Preservative
'O
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Holding Time
Analysis
, . . j /?'
Property Owner Information: s
/i* \ • f j> • *,; j ivs ^ (
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srmv i«s K otter
Project Number; ^0^0 . Q)Q0 Matr1x; So'j SamP,e Number; S FfM""V > ^
Project ID; S Fb esf I\' A Project Manager; H&iHl Sm*0l j
Location: uOi louoeesj State: ^y\Q
Superfund Name: £.'||,'Wi'||f Si 4^ — Site ID:
S4-vetKei Fa/e*?!' 5*4?
Location Description:, - ^ / v, / /1' Ay s>/* >/ Time:
Longitude;
Laboratory Analysis:
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V' .f
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Holding Time
/f/t
Analysis
S A
Sample Comments:
Sample Location Map:
/T
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Sample collected bv: " *5^
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
S77VKT 7
Project Number: y yl & . 0
Matrix: cj0 J»| Sample Number; 5 'V~V ¦' >
Project ID: R A
Location: u3t Iducooo
Superfund Name: £||,'wt'||£ Si Site ID:
s+wcKe/'Fi/csl'" 5 t'ksf'If-C.
Project Manager: hj^tfh .5WM j
state: fvlO
Location Description:
External Sample Number:.
Latitude:
Longitude:,
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: A, * -y
Time
Laboratory Analysis:
Container
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Preservative
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Holding Time
. '>st
Analysis
, 'O >Ssf
Property Owner Information:
rsj (**K
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SfTKT T*$K Oder
Project Number: 0^0 (/)(£& Matrix: So*| Sample Number: 5 f i{ ft/*ff
Project©: S F6 .e* R A Project Manager: j
Location: uj i \du;t>oo State: ^y*|Q
Superfund Name: £||iW«'||f " Site ID:
S-t-vetKfcl ir* f S t/|p//f£ -
Location Description: r 1 'f? ~
External Sample Number:
Latitudes
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
y„* f° sr' ¦
Sample Collection: v. > . , Time: , jj :•
Property Owner Information: , iff / f
V ^ Afrr[k Cj^Ci t
-------
Sample Collection Field Sheet
US EPA Region ?
Kansas City, KS
sttwct T**K eder
Project Number: Q)00 Matrix: gej»| Sample Number: S ~~ - 5 ^
Project ID: S Fb K A
Location: u3i Iduaoo^
Superfund Name: £!j»wjfi£ Si te? - Site ID:
s^kr/K-
Location Description: „ c> , o?. .3 I .3 , :
External Sample Number:,
Latitude:
Longitude:
Project Manager: He*H S^tfl j
State: ^vlQ
Sample Collection: / . Time: 4
Laboratory Analysis:
Container Preservative Holding Time Analysis
f • 2 f f /<*- - J" ^
Property Owner Information:
- J ( %wr<< ^•' * i' - tfesy 4^j ^ -
Sample Comments: Sample Location Map:
A, v ¦¦
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Sample collected bv ^
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKr Thc>K odeT
Project Number; Q ft Qffi 0 «^rix: §ef| Sample Number: S FRft-
Project ID; S Wfe" F6-e$f RA Project Manager; Sm*Hi ZlW^kVnflfL
Location: u3» Idujood State: ^ Q
Superfund Name: fH.Wlif SjV- Site ID:
——___ ^ > 7- "3 —
Location Description: ^r,r«» j A^o yv^c •% /
External Sample Number:
Latitude: Sample Collection: J 2 / f Time: ,-'o, ,j"
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
f" /f*- , y
Property Owner Information:
O-Jl" r> x / . p
( -XV. •; •¦-//- • r-*-. ;»¦* ^ /C "
Sample Comments: Sample Location Map;
*
£=^!* 1 — ¦ it. ^.k. »
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Sample collected bv:
C. * .
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
stmt t*$>K odet
Project Number: 0 0 Q)Q0 Matrix: So r| ^mple Number: S FlM"- '/J*~^
Project©: Setter Fo^sf" ftA Project Manager: Htq^k
Location: u_2i \Ou>oo6 State: fO
Superfund Name: fffiiWlJf SikQ-- Site ID:
Si/U/R
Location Description: - i ^ ^ ^¦ v I
External Sample Number:,
Latitude: Sample Collection: ¦-<' - / ' 1 Time:, ; }
Longitude: _
Laboratory Analysis:
Container Preservative Holding Time Analysis
/,* /• /
Property Owner Information: ... - ^
.-x/L-k. S*. I J • *<¦ \ —f >. / -
A. .-i
V J x 1 "*¦) y^c--^ I , /• / -
Sample Comments: Sample Location Map:
Sample collected by:_ v '*»t
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKT l4$,K odet
Project Number; Q0tj^_Q)Q0 Matrix: $0fj Sample Number: S Flii"
Project ID: S 4t*(JC£/" F© i'6$ i~ R
Location: uJi \c>u>ooc>
Superfund Name: £||,W||f Stk?- Site ID:
Project Manager:
State: fY\0
H&tM $m*Hi /#w-€-kVn<()tV
Location Description: -V?« X-' „ ^
-r'^c ^ "X...
External Sample Number:
Latitude:
Longitude:
Sample Collection: >>* / *-j
Time: ^ 0 ^ '
Laboratory Analysis:
Container Preservative Holding Time Analysis
<•;» i- ; " , y'L ^
Property Owner Information: t A i t\ / /" " jt.>
^ 'r -C » -c ^ ^ ^
Sample Comments: Sample Location Map:
<•-?
jLJ-
P
S^.coll.c.edbv: -.WA"*
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sm^TTk^Koder
Project Number: 000 Matrix; $ef/ Sample Number; S
ProjectID: sWfc/' Fb/CSf R~A Project Manager: H&i-bh -WM / kVftftfi.
Location: uj>* |t)u>oo6 State: f\r"\ O
Superfund Name: £||»Wi3< Si'40-- Site ID:
s-hetKerB/esf- s>4?WK.-
Location Description: ¦ -> .-/-f; a. J
External Sample Number:_
Latitude: Sample Collection: y .j s - , ^ Time: , . . '
Longitude:
Laboratory Analysis;
Container Preservative Holding Time Analysis
^»* Y* //>£¦ - ^o'
v . ,S' v:<,^ T'i.jr4
„c/t 4
Sample Comments: Sample Location Map:
/'/
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A*-* J , j!/^h 3*
Sample collected by:.
v. /4 >.
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
o&er
Project Number; 000 Matrix: 5o'l Sample Number: S F li A
Project ID: S'ft/£$^
• **- \
Location: vOi ldu)t)o6
Superfund Name: £||,'wi'|)£ St 4v< -
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
SWCT O&lT
Project Number; Q0H^,Q)00 Matrix: §0?f
* S-hf*tK'tt~ Fb'tsr K A Project Manager; S^'H /
Sample Number: ^ p'K '"t """ '' ^
Project ID:
Location: uj> i \dujooo
Superfund Name: £||,'Wi'||<> Site — Site ID:
±+*cKeJ~ Fi K<>1r
Location Description:
External Sample Number:
Latitude:
Longitude;
state: #Y10
&a A'an ji r
Sample Collection: ^^ ^ > ;• 'V Time: /V ?' ^
Laboratory Analysis:
Container
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Preservative
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Analysis
r
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Property Owner Information:
_> l , j.,
7 y,., ^, ru -***«
Sample Comments:
Sample Location Map:
Sample collected bv:
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
srhKV ~R<>K oder
Project Number: Q)0Q) Matrix; ^C|#| Sample Number: ~f~
Project ID: S+r*lXt< Fbesf" K
Location: uJ5 i \c>ujoo6
Project Manager: Sm'H J
State: fVlO
Superfund Name: £||,'wi'!Sf Si +e — Site ID:
Location Description:
External Sample Number:.
Latitude:
Longitude:
Sample Collection: - Time: /SjFZ—
Laboratory Analysis:
Container
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Holding Time
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Property Owner Information:
/Kr-*«c
i--'" cr-oT^r,
Sample Comments: Sample Location Map:
* #1 <£> <
,3^ 4
Sample collected by:_
cA
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-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swcr thk
Project Number: 0*0^0 _ &Q0 MaWx: So'/ Sample Number: S F^ ^
Project ID: F©;vc
External Sample Number:
Latitu
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Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sttwCT Tk$>K oiit
Project Number: Matrix: So?| Sample Number: S F/M"" ' ^ ^
Project©: FweSf" Project Manager: H&iih Sw'Hl j th.xbL-W*n(t>]fc
Location: vOi \oix>oo6 State: f\f\0
Superfurid Name: £||v'w»'||£ S\te— Site ID:
s-t^tKei'Fa/esf SukWK--
Location Description: -"*-7/ ¦ \'ks ~h> -*t 1 »c >*A i i u '«( '
External Sample Number:
Latitude: Sample Collection: Time: ^ •» •-
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
\ e < f-- . 3
Property Owner Information:^
Sample Comments: Sample Location Map:
/
Sample collected by ¦ t > '
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STAKT las>K oder
Project Number: 0 0^0 &Q& Matrix: Sfi tj Sample Number: S 0 °
Project©: 5 +t*dfa~ f< A Project Manager: He(,H Sm>H j kVlM&tt
Location: UOilduaaotl State: fY\Q
Superfund Name: £||,'wi'|)t S» 4
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
sr*KT Us K
Project Number: Q)®0 Matrix
: SO *I Sample Number: S ^ ^
Project ID: S fo oo
Superfund Name: £'ij&vj'j'j£ Si <&> — Site ID:
s-HetKe/'B/esf SobsiK
Project Manager: Sm»H / tk^€^kVfM#
state: mo
Location Description: /' /V Us ^ i /
External Sample Number:
Latitude:
Longitude:
Sample Collection: -^V , > Time: ^ . f
Laboratory Analysis:
Container
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Preservative
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Analysis
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Sample Comments:
Sample Location Map:
f
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-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
swrr TisK oMer
Project Number: Q)Q0 Matrix: So?/ Sample Number: S i\ — J & ^
Project ID; S ^iK-Cr R A
Location: u3t \duiOOO
Superfund Name: S» V© Site ID:
S-l-MMttCer B /esf" S^t?/ /fc
Location Descriptions Ae-yjt
External Sample Number:
Latitude:
Longitude:
Project Manager: H&tth JW*M
state: rvlO
Sample Collection: /c| Time: ^ £/^
Laboratory Analysis:
Container
f'3f
Preservative
cfv
Holding Time
Analysis
...-i 4
Sample Comments:
Sample Location Map:
Sample collected by:_
J
-------
Sample Collection Field Sheet
US EPA Region 7
Kansas City, KS
STtrfiCT oiet
Project Number: Q)Q)W Matrix: Soil Sample Number: S Flirt " ]
Project ID: Fb»e$f~ RA Project Manager: H&tfh Smf'Hi /fciuA-£_.kVnflft
Location: u3t IOujooc) State: \f"y \ {_}
Superfund Name: £||»'wi'|)€ St4£ IK-
Location Description.A*rJ V;/( JZ.
External Sample Number:
Latitude: Sample Collection: jC.jQ -/"cf Time:
Longitude:
Laboratory Analysis:
Container Preservative Holding Time Analysis
<¦(,*¦ f ' ' - - ^
Property Owner Information: . f , . _ , ,/
A ,c Jekue*** y-ZT 4
Sample Comments: Sample Location Map;
/-
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*
ENVIRONMENTAL SERVICES ASSISTANCE TEAM
ESAT Region 7
300 Minnesota Ave
METI / Alion Science & Technology Kansas City, KS 66101
DATE: August 14, 2014
MEMORANDUM
TO: Barry Evans,
ESAT Task Order Contract Officer Representative, Region 7 EPA
FROM: Rebecca Estep,^*
ESAT, Region 7, Senior QA Chemist
THRU
Ronald A. Ross
ESAT, Region 7 Team Manager
SUBJECT: Review of dioxin data report from Cape Fear Analytical dated
2/20/14-6/24/14, for the Ellisville Site Strecker Forest
Development site in Wildwood, MO
Contract No:
TDF No.
TO No.:
Subtask:
ESAT Document Control No.:
EPA Activity Number:
Site ID/Operable Unit:
GPRA Code:
EP-W-13-027
T0421
02
4-10
0702-004-0006
RQA4 21
0708/OU00
303DD2
ESAT was requested to review 23 data packages for the Ellisville Strecker
Forest Development Dioxin Superfund Site Data Assessments dated 2/20/14-
6/24/14 from Wildwood, MO reports containing analytical results summary
forms. ESAT was requested to verify the reported analytical results
including proper qualification of data outliers, verify methods 1613B was
followed, confirm appropriate QC was performed at the expected
frequencies, and identify data from any samples that should be qualified
differently from that identified in the laboratory's report. The review
was conducted in accordance with EPA Region 7 SOP 2430.3H for validation
of organic Contract Laboratory Program (CLP) data packages. As the PRP
data were generated using Method lol3B method, some professional judgment
was required in evaluation of the data versus SOP (NFG) requirements.
Summary
The subject data were reviewed and validated based only on the summary
reports provided by Cape Fear Analytical LLC. Only minor discrepancies
were noted, as discussed below. Overall data quality and completeness
were acceptable based on the summary forms provided.
Appropriate samples and analyses were performed along with QC at the
expected frequency. The analytical method used was 1613B. A limited
amount of data were qualified as estimated (J), non-detect estimated (UJ),
or as non-detect (U).
-------
Samples that contain results between the EDL and the PQL were flagged with
"J". Typically, EPA Region 7 reports the associated PQL with a "U" code
and is considered a non-detect result.
Specific Comments
The ESAT review notes the following issues identified:
Samples included with Work Orders 6023 (7.2°C), 6086 (19.1°C), 6123
(10.1°C), and 6202 (9.4°C) were received at temperatures above control
limits, however, as noted in the data packages, to proceed with
analyses because temperature is not an issue on any of this material,
therefore, no data were qualified.
Matrix spike/matrix spike duplicates (MS/MSDs) are not required,
however, five MS/MSDs'were analyzed with the associated data with
outliers found (recoveries and relative percent differences) which
are suspected of being matrix interferences. Since the associated
LCS/LCSD results were within control limits, per the case narratives,
no data would be qualified.
Several surrogates were diluted out. One low surrogate outlier was
noted for 1,2,3,6,7,8-HxCDD (27.6% vs 28-130%) in sample SFRA-23 due
to possible matrix interference, therefore, 1,2,3,6,7,8-HxCDD and
1,2,3,7,8,9-HxCDD should be UJ-coded as estimated results.
As noted in the several case narratives, a lg extraction was
performed on several samples due to the high levels of target
analytes that may be present.
Several analytes were found below the PQL in several method blanks,
however, since associated data were non-detect or greater than ten
times the level found, no data were qualified.
1, 2, 3, 4, 6,7,8,9-OCDD in sample SFRA-5 was above calibration range (E-
coded) with no dilution found, therefore, should be qualified (J-
coded) to show estimated results.
Samples SFRA-7 (10X), -8 (50X), -9 (20X) , -11 (50X), -14 (5X) , -15
(10X), -18 (2X), -19 (2X), -20 (2X) , -30 (10X), -31 (10X), -33 (10X),
-37 (5X), -41 (10X), -42 (10X), -43 (10X), -44 (10X), -45 (10X), -46
(10X), -47 (2X), -48 (5X), -51 (5X), -53 (20X), -54 (10X), -55 (10X),
-56 (10X), -58 (10X), -60 (5X), -74 (10X), -75 (5X), -95 (5X), -99
(5X), -100 (10X), and -102 (5X) were analyzed at dilutions and have
elevated reporting limits.
1, 2, 3, 6, 7,8-HxCDD in samples SFRA-59, -82, -83, and -85, 1,2,3,4,7,8-
HxCDD, 1, 2,3,6,7,8-HxCDD, 1,2,3,7,8,9-HxCDD, and 1,2,3,5,8,9-HxCDF in
sample SFRA-72, 1,2,3,4,7,8-HxCDD and 1,2,3,6,7,8-HxCDD in samples
SFRA-74, -75, -78, -79, -81, -91, -96, and -97, 1,2,3,4,7,8-HxCDD,
1,2,3,6,7,8-HxCDD, and 1,2,3,7,8,9-HxCDD in sample SFRA-89 were
identified as quantitative interference (Q-code).
Several samples were reanalyzed for 2,3,7,8-TCDF for confirmation.
QA Document # Strecker Forest Removal Action Summer 2014-HS
-------
ENVIRONMENTAL SERVICES ASSISTANCE TEAM
ESAT Region 7
300 Minnesota Ave
METI / Alion Science & Technology Kansas City, KS 66101
DATE: September 2, 2014
MEMORANDUM
TO:
Barry Evans,
ESAT Task Order Contract Officer Representative, Region 7 EPA
FROM:
Rebecca Estep,^"
ESAT, Region 7, Senior QA Chemist
THRU
Ronald A. Ross,^^""3^
ESAT, Region 7 Team Manager
SUBJECT: Review of dioxin data report from Cape Fear Analytical dated
6/30/14-8/5/14, for the Ellisville Site Strecker Forest
Development site in Wildwood, MO
Contract No:
TDF No.
TO No.:
Subtask:
ESAT Document Control No.
EPA Activity Number:
Site ID/Operable Unit:
GPRA Code:
EP-W-13-027
TO 4 50
02
4-10
0702-004-0007
RQA4 50
0708/OU00
303DD2
ESAT was requested to review 12 data packages for the Ellisville Strecker
Forest Development Dioxin Superfund Site Data Assessments dated 6/30/14-
8/5/14 from Wildwood, MO reports containing analytical results summary
forms. ESAT was requested to verify the reported analytical results
including proper qualification of data outliers, verify methods 1613B was
followed, confirm appropriate QC was performed at the expected
frequencies, and identify data from any samples that should be qualified
differently from that identified in the laboratory's report. The review
was conducted in accordance with EPA Region 7 SOP 2430.3H for validation
of organic Contract Laboratory Program (CLP) data packages. As the PRP
data were generated using Method 1613B method, some professional judgment
was required in evaluation of the data versus SOP (NFG) requirements.
Summary
The subject data were reviewed and validated based only on the summary
reports provided by Cape Fear Analytical LLC. Only minor discrepancies
were noted, as discussed below. Overall data quality and completeness
were acceptable based on the summary forms provided.
Appropriate samples and analyses were performed along with QC at the
expected frequency. The analytical method used was 1613B. A limited
amount of data were qualified as estimated (J) or as non-detect (U).
-------
Samples that contain results between the EDL and the PQL were flagged with
"J". Typically, EPA Region 7 reports the associated PQL with a "U" code
and is considered a non-detect result.
Specific Comments
The ESAT review notes the following issues identified:
Samples included with Work Order 6361 (9.0°C) were received at
temperatures above control limits, however, as noted in previous data
packages, to proceed with analyses because temperature is not an
issue on any of this material, therefore, no data were qualified.
Matrix spike/matrix spike duplicates (MS/MSDs) are not required,
however, nine MS/MSDs were analyzed with the associated data with
outliers found (recoveries and/or relative percent differences) which
are suspected of being matrix interferences. Since the associated
LCS/LCSD results were within control limits, per the case narratives,
no data would be qualified.
Several surrogates were diluted out.
As noted in the 12 case narratives, a lg extraction was performed on
several samples due to the high levels of target analytes that may be
present.
Several analytes were found below the PQL in several method blanks,
however, since associated data were non-detect or greater than ten
times the level found, no data were qualified.
Samples SFRA-106 (5X), -109 (5X), -112 (5X), -131 (5X), -132 (5X),
-133 (5X), -139 (5X), -140 (5X), -141 (5X), -142 (5X), -143 (10X),
-144 (5X), -145 (5X), -146 (5X), -148 (10X), -149 (10X), -157 (5X),
and -158 (5X) were analyzed at dilutions and have elevated reporting
limits.
1,2,3,6,7,8-HxCDD in samples SFRA-129 and -130 was identified as
quantitative interference (Q-code).
Several samples were reanalyzed for 2,3,7,8-TCDF for confirmation.
QA Document # Strecker Forest Removal Action Summer 2014-HS
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
February 20, 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 5842
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on February 18, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Enclosures
Page 1 of 20
problem solved
-------
+
Page;
Project #:
CFA Quote ft:
COC Number'":
PO Number;
of
t
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: /
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone:(910)795-0421
Client Name:
TtrhmJTfe^ Jzyi c*
Phone #:
Sample Analysis Requested
(5)
(Fill in the number of containers for each test)
i9F
T
fa
OQ
K
O
H-t"
M
c
Project/Site Name:
h\ fou s/J rj*fcMc>
Address
: tp H Pnritrt ifA'vC^
Collected by:
! t ft
I I
Send Results To:
Sample ID
* For composites - indicate start and stop date/time
Field
Filtered
Sarnplt
Matrixt+)
£?¦-
V
<-- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
/ <96*V
5«il
IS
c~
et\rt,prtm f
¦*ftr drjj ia/K
TAT Requested: Normal: Rush: X Specify: X
Fax Results:
Yes
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
/SlovJL**
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2{7 Level 3_Jy Level 4
Sample Collection
Eastern Pacific
Sj^ntrlk Other _
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Date
Time
ir.fB
Received by (signed)
Date
Time
/IfuJjL Jb&tA' IbpbblA [OiO
CFA PM:
Method of Shipment:
Cm y\| g I -lit rtfi
nt: y^cJpy |pate Shipped:
-n-ij
Airbill #:
8~iso 8
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
cl,en,: -f£-rR_
Work Order:
Received Bv:
Date/Time Received: j
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 20
-------
Case Narrative
Page 5 of 20
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 5842
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25400
Clean Up Batch Number: 25398
Extraction Batch Number: 25397
Sample Analysis
The following samples were analyzed using the analytical protocol as established in :
Sample ID Client ID
5842001 SFRA-3
12009915 Method Blank (MB)
12009916 Laboratory Control Sample (LCS)
12009917 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of 20
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 25400.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Page 7 of 20
-------
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 20
-------
Sample Data Summary
Page 9 of 20
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 5842 CFA Work Order: 5842
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 03 MAR 2014 Title: Data Validator
Page 10 of 20
-------
Cape Fear Analytical LLC
Report Date:
March 3,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
5842
5842001
1613B Soil
SFRA-3
25400
02/23/2014 06:53
A22FEB14D 2-12
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
02/13/2014 10:02
02/18/2014 10:10
EPA Method 1613B
MJC
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
9.4
Dry Weight
HRP763
1
Prep Batch:
25397
Prep Method:
SW846 3540C
Prep Date:
20-FEB-14
Aliquot:
15.03 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.117
Pg/g
0.117
0.734
40321-76-4
1,2,3,7,8-PeCDD
u
.304
Pg/g
0.304
3.67
39227-28-6
1,2,3,4,7,8-HxCDD
J
0.508
Pg/g
0.372
3.67
57653-85-7
1,2,3,6,7,8-HxCDD
J
0.897
Pg/g
0.369
3.67
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.977
Pg/g
0.397
3.67
35822-46-9
1,2,3,4,6,7,8-HpCDD
41.2
Pg/g
0.702
3.67
3268-87-9
1,2,3,4,6,7,8,9-OCDD
853
Pg/g
1.56
7.34
51207-31-9
2,3,7,8-TCDF
u
.308
Pg/g
0.308
0.734
57117-41-6
1,2,3,7,8-PeCDF
u
.402
Pg/g
0.402
3.67
57117-31-4
2,3,4,7,8-PeCDF
J
0.435
Pg/g
0.388
3.67
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.530
Pg/g
0.405
3.67
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.476
Pg/g
0.476
3.67
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.574
Pg/g
0.430
3.67
72918-21-9
1,2,3,7,8,9-HxCDF
u
.587
Pg/g
0.587
3.67
67562-39-4
1,2,3,4,6,7,8-HpCDF
4.32
Pg/g
0.119
3.67
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
0.480
Pg/g
0.192
3.67
39001-02-0
1,2,3,4,6,7,8,9-OCDF
9.99
Pg/g
0.527
7.34
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
132
147
Pg/g
89.9
(25 %-164%)
13C-1,2,3,7,8-PeCDD
127
147
Pg/g
86.7
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
135
147
Pg/g
92.2
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
116
147
Pg/g
78.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
156
147
Pg/g
107
(23%-140%)
13C-OCDD
343
294
Pg/g
117
(17%-157%)
13C-2,3,7,8-TCDF
123
147
Pg/g
84.1
(24%-169%)
13C-1,2,3,7,8-PeCDF
115
147
Pg/g
78.4
(24%-185%)
13C-2,3,4,7,8-PeCDF
119
147
Pg/g
80.7
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
121
147
Pg/g
82.7
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
108
147
Pg/g
73.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
116
147
Pg/g
79.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
125
147
Pg/g
85.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
126
147
Pg/g
85.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
142
147
Pg/g
96.7
(26%-13 8%)
37Cl-2,3,7,8-TCDD
12.5
14.7
Pg/g
85.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 20
-------
Quality Control
Summary
Page 12 of 20
-------
( (ipc Fear Analytical LLC Report Date: March 3, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 5842
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12009916
LCS for batch 25397
12009917
LCSD for batch 25397
12009915
MB for batch 25397
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
87.7
91.1
94.4
85.7
118
110
86.2
81.8
84.4
88.5
84.2
91.0
93.1
97.9
109
86.3
82.5
82.5
92.7
79.8
110
104
80.3
75.2
77.7
83.9
75.8
86.0
85.5
88.8
97.2
82.7
80.5
77.6
85.1
76.5
104
101
78.0
72.3
73.2
80.3
70.9
78.9
81.5
84.9
95.1
87.6
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
5842001
SFRA-3
13C-2,3,7,8-TCDD
89.9
(25%-164%)
Page 13 of 20
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( (ipc Fear Analytical LLC Report Date: March 3, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 5842
Matrix Type: SOLID
Sample ID Client ID
5842001 SFRA-3
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
(%)
Limits
86.7
(25%-
¦181%)
92.2
(32%-
¦141%)
78.6
(28%-
¦130%)
107
(23%-
¦140%)
117
(17%-
¦157%)
84.1
(24%-
¦169%)
78.4
(24%-
¦185%)
80.7
(21%-
¦178%)
82.7
(26%-
¦152%)
73.5
(26%-
¦123%)
79.0
(28%-
¦136%)
85.1
(29%-
¦147%)
85.6
(28%-
¦143%)
96.7
(26%-
¦138%)
85.2
(35%-
¦197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 14 of 20
-------
Cape Fear Analytical LLC
Report Date: March 3, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 02/22/2014 22:55 Dilution: 1
Prep Batch ID:25397
Batch ID: 25400
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.1
101
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
101
101
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
99.9
99.9
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
101
101
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
103
103
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
210
105
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.6
98.1
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
104
104
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
103
103
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
99.1
99.1
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
99.5
99.5
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
99.4
99.4
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
102
102
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
103
103
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
194
97
63-170
SDG Number: 5842
Client ID: LCS for batch 25397
Lab Sample ID: 12009916
Instrument: HRP763
Analyst: MJC
Page
15 of 20
-------
Cape Fear Analytical LLC
Report Date: March 3, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 02/22/2014 23:43 Dilution: 1
Prep Batch ID:25397
Batch ID: 25400
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
19.9
99.5
67-158
1.19
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
99.7
99.7
70-142
1.44
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
97.7
97.7
70-164
2.21
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
108
108
76-134
6.47
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
109
109
64-162
6.12
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
96.2
96.2
70-140
4.59
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
199
99.5
78-144
5.31
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.2
95.8
75-158
2.34
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
102
102
80-134
2.41
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
97.7
97.7
68-160
5.13
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
100
100
72-134
0.948
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
102
102
84-130
2.15
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
101
101
70-156
2.00
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
102
102
78-130
0.161
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
104
104
82-122
2.71
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
102
102
78-138
1.35
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
190
94.8
63-170
2.27
0-20
SDG Number: 5842
Client ID: LCSD for batch 25397
Lab Sample ID: 12009917
Instrument: HRP763
Analyst: MJC
Page
16 of 20
-------
Cape Fear Analytical LLC
Report Date:
March 3,2014
SDG Number:
5842
Method Blank Summary
Client: TETR001
Page 1 of 1
Matrix:
SOLID
Client ID: MB for batch 25397
Instrument ID:
HRP763
Data File:
A22FEB14D 2-4
Lab Sample ID: 12009915
Column:
Prep Date:
20-FEB-14
Analyzed:
02/23/14 00:31
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01 LCS for batch 25397
12009916
A22FEB14D2-2
02/22/14
2255
02 LCSD for batch 25397
12009917
A22FEB14D2-3
02/22/14
2343
03 SFRA-3
5842001
A22FEB14D 2-12
02/23/14
0653
Page 17 of 20
-------
Cape Fear Analytical LLC
Report Date:
March 3,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5842
Lab Sample ID: 12009915
Client Sample: *or batch 25397
Client ID: MB for batch 25397
Batch ID: 25400
Run Date: 02/23/2014 00:31
Data File: A22FEB14D 2-4
Prep Batch: 25397
Prep Date: 20-FEB-14
Chent:
Method:
Analyst:
Prep Method:
Aliquot:
TETR001
EPA Method 1613B
MJC
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.155
Pg/g
0.155 1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.296
Pg/g
0.222 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.34
Pg/g
0.340 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.356
Pg/g
0.356 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.374
Pg/g
0.374 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.47
Pg/g
0.470 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
1.41
Pg/g
1.41 10.0
51207-31-9
2,3,7,8-TCDF
u
.174
Pg/g
0.174 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.286
Pg/g
0.286 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.268
Pg/g
0.268 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.384
Pg/g
0.384 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.386
Pg/g
0.386 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.398
Pg/g
0.398 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.576
Pg/g
0.576 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.56
Pg/g
0.560 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.926
Pg/g
0.926 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.544
Pg/g
0.544 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
161
200
Pg/g
80.5
(25 %-164%)
130-1,2,3,7,8-
PeCDD
155
200
Pg/g
77.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
170
200
Pg/g
85.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
153
200
Pg/g
76.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
209
200
Pg/g
104
(23%-140%)
13C-OCDD
404
400
Pg/g
101
(17%-157%)
13C-2,3,7,8-TCDF
156
200
Pg/g
78.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
145
200
Pg/g
72.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
146
200
Pg/g
73.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
161
200
Pg/g
80.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
142
200
Pg/g
70.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
158
200
Pg/g
78.9
(28%-136%)
130-1,2,3,7,8,9-HxCDF
163
200
Pg/g
81.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
170
200
Pg/g
84.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
190
200
Pg/g
95.1
(26%-13 8%)
3701-2,3,7,8-TCDD
17.5
20.0
Pg/g
87.6
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 18 of 20
-------
Cape Fear Analytical LLC
Report Date:
March 3,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
5842
12009916
QC for batch 25397
LCS for batch 25397
25400
02/22/2014 22:55
A22FEB14D 2-2
25397
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
MJC
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
20-FEB-14
Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.1
Pg/g
0.238
1.00
40321-76-4
1,2,3,7,8-PeCDD
101
Pg/g
0.398
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
99.9
Pg/g
0.880
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
101
Pg/g
0.918
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
103
Pg/g
0.964
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
0.980
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
210
Pg/g
2.78
10.0
51207-31-9
2,3,7,8-TCDF
19.6
Pg/g
0.260
1.00
57117-41-6
1,2,3,7,8-PeCDF
104
Pg/g
0.604
5.00
57117-31-4
2,3,4,7,8-PeCDF
103
Pg/g
0.550
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
99.1
Pg/g
1.20
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
99.5
Pg/g
1.14
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
99.4
Pg/g
1.16
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
102
Pg/g
1.69
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
0.476
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
103
Pg/g
0.770
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
194
Pg/g
1.75
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
175
200
Pg/g
87.7
(20%-175%)
13C-1,2,3,7,8-PeCDD
182
200
Pg/g
91.1
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
189
200
Pg/g
94.4
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
171
200
Pg/g
85.7
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
235
200
Pg/g
118
(22%-166%)
13C-OCDD
439
400
Pg/g
110
(13%-199%)
13C-2,3,7,8-TCDF
172
200
Pg/g
86.2
(22%-152%)
13C-1,2,3,7,8-PeCDF
164
200
Pg/g
81.8
(21%-192%)
13C-2,3,4,7,8-PeCDF
169
200
Pg/g
84.4
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
177
200
Pg/g
88.5
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
168
200
Pg/g
84.2
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
182
200
Pg/g
91.0
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
186
200
Pg/g
93.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
196
200
Pg/g
97.9
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
218
200
Pg/g
109
(20%-186%)
37Cl-2,3,7,8-TCDD
17.3
20.0
Pg/g
86.3
(31 %-191%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 20
-------
Cape Fear Analytical LLC
Report Date:
March 3,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
5842
12009917
QC for batch 25397
LCSD for batch 25397
25400
02/22/2014 23:43
A22FEB14D 2-3
25397
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
MJC
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
Prep Method: SW846 3540C
Prep Date:
20-FEB-14
Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
19.9
Pg/g
0.254 1.00
40321-76-4
1,2,3,7,8-PeCDD
99.7
Pg/g
0.450 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
97.7
Pg/g
0.962 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
108
Pg/g
0.982 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
109
Pg/g
1.04 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
96.2
Pg/g
1.22 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
199
Pg/g
2.24 10.0
51207-31-9
2,3,7,8-TCDF
19.2
Pg/g
0.206 1.00
57117-41-6
1,2,3,7,8-PeCDF
102
Pg/g
0.646 5.00
57117-31-4
2,3,4,7,8-PeCDF
97.7
Pg/g
0.604 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
100
Pg/g
1.33 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
102
Pg/g
1.35 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
101
Pg/g
1.26 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
102
Pg/g
2.04 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
104
Pg/g
1.82 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
102
Pg/g
2.96 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
190
Pg/g
1.53 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
165
200
Pg/g
82.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
165
200
Pg/g
82.5
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
185
200
Pg/g
92.7
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
160
200
Pg/g
79.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
220
200
Pg/g
110
(22%-166%)
13C-OCDD
417
400
Pg/g
104
(13%-199%)
13C-2,3,7,8-TCDF
161
200
Pg/g
80.3
(22%-152%)
13C-1,2,3,7,8-
PeCDF
150
200
Pg/g
75.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
155
200
Pg/g
77.7
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
168
200
Pg/g
83.9
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
152
200
Pg/g
75.8
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
172
200
Pg/g
86.0
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
171
200
Pg/g
85.5
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
178
200
Pg/g
88.8
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
194
200
Pg/g
97.2
(20%-186%)
3701-2,3,7,8-TCDD
16.5
20.0
Pg/g
82.7
(31 %-191%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 20 of 20
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 15. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 5973
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 10, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Enclosures
Page 1 of21
problem solved
-------
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CHAIN OF CUSTODY RECORD
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ACTIVITY LEADER(Print) .
m,H-v' IfiW-iA.
NAME OF SURVEY OR ACTIVITY
firrsrf ^
CONTENTS OF SHIPMENT
2^1
(5H5
DESCRIPTION OF SHIPMENT
MODE OF SHIPMENT
. PtECE(S) CONSISTING OF.
.ICE CHEST(S); OTHER
. BOX(ES)
—Commercial carrier;
COURIER
SAMPLER CONVEYED
NUMBER)
PERSONNEL CUSTODY RECORD
RELINQUISHED BY (SAMPLER)
UNSEALED
ijEALED
relinquished by
"~1 SEALED
^xwri
unsealed r
DATE
ioa^(
TIME
$0
IVtD tSY j -y
-~) SEALED UNSEALED T
TIME
iozO
RECEIVED BY,
receiver by /) I •
"QseaCeb ^ UNSEALED r
REASON for change qf custody
+Q lAp
4br 5
reason for change of custody
RELINQUISHED BY
DATE
TIME
RECEIVED BY
REASON FOR CHANGE OF CUSTODY
~1 SEALED UNSEALEdT"
7-EPA-9262
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client
Work Order: ^ ^ ^ 3
Received By:
Date/Time Received: f fo fcPfi^jlL J f) % 0
Suspected Hazard Information
Yes
NA
NO
DOE Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
Samples identified as Foreign Soil?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
c^
Circle Applicable:
seals broken damaged container leaking container otherEdestribe)
2
Chain of Custody documents included
with shipment?
3
Samples requiring cold preservation
within 0-6X?
I
Pmsgfitetion Method:
fee bags } blue ice dry ice none ether {describe)
^ 3. ers affected:
10
COC form is properly signed in
relinquished/received sections?
U
Comments:
i
Checklist performed by: Initials:
o,, (OAVflOr
Page 3 of21
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of21
-------
Case Narrative
Page 5 of21
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 5973
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25621
Clean Up Batch Number: 25618
Extraction Batch Number: 25617
Sample Analysis
The following samples were analyzed using the analytical protocol as established in :
Sample ID Client ID
5973001 SFRA-8
12010152 Method Blank (MB)
12010153 Laboratory Control Sample (LCS)
12010154 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of21
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
Due to the high levels of 2378-TCDD present in the sample, the associated clean up standard
produced a high recovery. 5973001 (SFRA-8)- Batch 25621.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 25621.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP. Per client request, a 5 gram aliquot was
used for dry weights and remaining grams were used for extraction. See enclosed logbook page
for exact weights.
Sample Dilutions
Sample 5973001 (SFRA-8)- Batch 25621 was diluted due to the presence of overrange target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 7 of21
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of21
-------
Sample Data Summary
Page 9 of21
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 5973 CFA Work Order: 5973
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 15 APR 2014 Title: Data Validator
Page 10 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 15, 2014
Hi-Res Dioxins/Furans
Page 1 i
Certificate of Analysis
Sample Summary
SDG Number: 5973
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 5973001
Date Collected:
04/09/2014 15:45
Matrix:
SOLID
Client Sample: 1613B Soil
Date Received:
04/10/2014 10:20
%Moisture:
19.6
Client ID:
SFRA-8
Prep Basis:
Dry Weight
Batch ID:
25621
Method:
EPA Method 1613B
Run Date:
04/14/2014 10:34
Analyst:
JTF
Instrument:
HRP763
Data File:
bl4aprl4a-3
Dilution:
50
Prep Batch:
25617
Prep Method:
SW846 3540C
Prep Date:
10-APR-14
Prep Aliquot:
15.72 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
10300
Pg/g
5.95
39.6
40321-76-4
1,2,3,7,8-PeCDD
U
5.7
Pg/g
5.70
198
39227-28-6
1,2,3,4,7,8-HxCDD
J
21.5
Pg/g
8.42
198
57653-85-7
1,2,3,6,7,8-HxCDD
J
73.2
Pg/g
8.47
198
19408-74-3
1,2,3,7,8,9-HxCDD
J
24.5
Pg/g
8.67
198
35822-46-9
1,2,3,4,6,7,8-HpCDD
550
Pg/g
17.9
198
3268-87-9
1,2,3,4,6,7,8,9-OCDD
6300
Pg/g
91.3
396
51207-31-9
2,3,7,8-TCDF
70.1
Pg/g
8.91
39.6
57117-41-6
1,2,3,7,8-PeCDF
u
6.92
Pg/g
6.92
198
57117-31-4
2,3,4,7,8-PeCDF
J
6.95
Pg/g
6.69
198
70648-26-9
1,2,3,4,7,8-HxCDF
u
11.7
Pg/g
11.7
198
57II7.44.9
1,2,3,6,7,8-HxCDF
J
6.44
Pg/g
5.51
198
60851-34-5
2,3,4,6,7,8-HxCDF
J
10.4
Pg/g
6.46
198
72918-21-9
1,2,3,7,8,9-HxCDF
u
8.36
Pg/g
8.36
198
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
127
Pg/g
4.72
198
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
11.3
Pg/g
7.85
198
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
229
Pg/g
25.8
396
Surrogate/Tracer recovery
Qual Result
Nominal Units
Recovery% Acceptable Limits
of 1
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
13C-1,2,3,6,7,8-HxCDD
13C-1,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-1,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-1,2,3,4,7,8-HxCDF
13C-1,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-1,2,3,7,8,9-HxCDF
13C-1,2,3,4,6,7,8-HpCDF
13C-1,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
153
134
129
151
126
227
141
136
138
127
130
132
118
121
103
60.4
158
158
158
158
158
317
158
158
158
158
158
158
158
158
158
15.8
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
96.6
84.9
81.3
95.1
79.3
71.7
88.9
85.9
87.0
80.4
81.9
83.7
74.8
76.2
64.8
382
(25%-164%
(25%-181%
(32%-141%
(28%-130%
(23%-140%
(17%-157%
(24%-169%
(24%-185%
(21%-178%
(26%-152%
(26%-123%
(28%-13 6%
(29%-147%
(28%-143%
(26%-13 8%
(35%-197%
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 15, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
5973
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
5973001
Date Collected:
04/09/2014 15:45
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/10/2014 10:20
%Moisture:
19.6
Client ID:
SFRA-8
Prep Basis:
Dry Weight
Batch ID:
25621
Method:
EPA Method 1613B
Run Date:
04/14/2014 11:49
Analyst:
JTF
Instrument:
HRP763
Data File:
A14APR14A-6
Dilution:
50
Prep Batch:
25617
Prep Method:
SW846 3540C
Prep Date:
10-APR-14
Prep Aliquot:
15.72 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
62.1
Pg/g
8.02
39.6
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 21
-------
Quality Control
Summary
Page 13 of 21
-------
( (ipc Fear Analytical LLC Report Date: April 15, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 5973
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010153
LCS for batch 25617
12010154
LCSD for batch 25617
12010152
MB for batch 25617
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
76.3
78.6
69.3
83.3
76.1
66.3
78.5
81.7
83.4
70.1
82.3
79.1
70.9
79.1
72.8
95.4
78.0
83.0
67.7
85.3
79.9
66.6
79.2
89.2
86.5
68.9
84.7
80.7
70.0
78.8
74.6
102
75.7
81.3
69.0
79.5
76.5
58.2
78.7
84.6
82.9
68.1
83.7
79.9
66.3
78.6
66.6
94.2
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
5973001
SFRA-8
13C-2,3,7,8-TCDD
96.6 D
(25%-164%)
Page 14 of 21
-------
Cape Fear Analytical LLC
Report Date: April 15, 2014
Hi-Res Dioxins/Furans
Surrogate Recovery Report
SDG Number: 5973
Matrix Type: SOLID
Page 2
of 2
Sample ID Client ID
Recovery Acceptance
Surrogate
QUAL (%)
Limits
13C-l,2,3,7,8-PeCDD
84.9
D
(25%-
¦181%)
13C-l,2,3,4,7,8-HxCDD
81.3
D
(32%-
¦141%)
13C-l,2,3,6,7,8-HxCDD
95.1
D
(28%-
¦130%)
13C-l,2,3,4,6,7,8-HpCDD
79.3
D
(23%-
¦140%)
13C-OCDD
71.7
D
(17%-
¦157%)
13C-2,3,7,8-TCDF
88.9
D
(24%-
¦169%)
13C-l,2,3,7,8-PeCDF
85.9
D
(24%-
¦185%)
13C-2,3,4,7,8-PeCDF
87.0
D
(21%-
¦178%)
13C-l,2,3,4,7,8-HxCDF
80.4
D
(26%-
¦152%)
13C-l,2,3,6,7,8-HxCDF
81.9
D
(26%-
¦123%)
13C-2,3,4,6,7,8-HxCDF
83.7
D
(28%-
¦136%)
13C-l,2,3,7,8,9-HxCDF
74.8
D
(29%-
¦147%)
13C-l,2,3,4,6,7,8-HpCDF
76.2
D
(28%-
¦143%)
13C-l,2,3,4,7,8,9-HpCDF
64.8
D
(26%-
¦138%)
37Cl-2,3,7,8-TCDD
382 *
D
(35%-
¦197%)
5973001
SFRA-8
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 15 of 21
-------
Cape Fear Analytical LLC
Report Date: April 15, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/11/2014 16:16 Dilution: 1
Prep Batch ID:25617
Batch ID: 25621
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.8
109
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
109
109
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
105
105
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
108
108
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
111
111
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
105
105
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
203
101
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.2
96.2
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
104
104
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
106
106
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
111
111
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
114
114
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
111
111
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
107
107
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
102
102
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
99.6
99.6
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
226
113
63-170
SDG Number: 5973
Client ID: LCS for batch 25617
Lab Sample ID: 12010153
Instrument: HRP763
Analyst: JTF
Page
16 of 21
-------
Cape Fear Analytical LLC
Report Date: April 15, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/11/2014 17:03 Dilution: 1
Prep Batch ID:25617
Batch ID: 25621
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.7
109
67-158
0.303
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
107
107
70-142
1.52
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
104
104
70-164
1.36
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
107
107
76-134
0.974
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
115
115
64-162
3.46
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
99.2
99.2
70-140
5.70
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
211
106
78-144
4.07
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
20.1
101
75-158
4.38
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
105
105
80-134
0.877
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
108
108
68-160
2.67
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
116
116
72-134
4.45
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
106
106
84-130
7.50
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
108
108
70-156
2.30
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
111
111
78-130
3.03
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
103
103
82-122
0.623
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
102
102
78-138
2.00
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
239
120
63-170
5.65
0-20
SDG Number: 5973
Client ID: LCSD for batch 25617
Lab Sample ID: 12010154
Instrument: HRP763
Analyst: JTF
Page
17 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 15, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 5973
Client ID: MB for batch 25617
Lab Sample ID: 12010152
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: 10-APR-14
Matrix: SOLID
Data File: bllaprl4a-6
Analyzed: 04/11/1417:51
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 25617
12010153
bllaprl4a-4
04/11/14
1616
02
LCSD for batch 25617
12010154
bllaprl4a-5
04/11/14
1703
03
SFRA-8
5973001
bl4aprl4a-3
04/14/14
1034
04
SFRA-8
5973001
A14APR14A-6
04/14/14
1149
Page 18 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 15, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5973
Lab Sample ID: 12010152
Client Sample: *or batch 25617
Client ID: MB for batch 25617
Batch ID: 25621
Run Date: 04/11/2014 17:51
Data File: bllaprl4a-6
Prep Batch: 25617
Prep Date: 10-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.342
Pg/g
0.342 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.4
Pg/g
0.400 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.462
Pg/g
0.462 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.432
Pg/g
0.432 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.458
Pg/g
0.458 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.856
Pg/g
0.856 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
1.16
Pg/g
1.16 10.0
51207-31-9
2,3,7,8-TCDF
u
.34
Pg/g
0.340 1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.216
Pg/g
0.212 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.21
Pg/g
0.210 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.276
Pg/g
0.276 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.268
Pg/g
0.268 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.288
Pg/g
0.288 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.514
Pg/g
0.514 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.27
Pg/g
0.270 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.5
Pg/g
0.500 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
1.66
Pg/g
1.66 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
151
200
Pg/g
75.7
(25 %-164%)
130-1,2,3,7,8-
PeCDD
163
200
Pg/g
81.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
138
200
Pg/g
69.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
159
200
Pg/g
79.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
153
200
Pg/g
76.5
(23%-140%)
13C-OCDD
233
400
Pg/g
58.2
(17%-157%)
13C-2,3,7,8-TCDF
157
200
Pg/g
78.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
169
200
Pg/g
84.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
166
200
Pg/g
82.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
136
200
Pg/g
68.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
167
200
Pg/g
83.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
160
200
Pg/g
79.9
(28%-136%)
130-1,2,3,7,8,9-HxCDF
133
200
Pg/g
66.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
157
200
Pg/g
78.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
133
200
Pg/g
66.6
(26%-13 8%)
3701-2,3,7,8-TCDD
18.8
20.0
Pg/g
94.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 15, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5973
Lab Sample ID: 12010153
Client Sample: *or batch 25617
Client ID: LCS for batch 25617
Batch ID: 25621
Run Date: 04/11/2014 16:16
Data File: bllaprl4a-4
Prep Batch: 25617
Prep Date: 10-APR-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.8
Pg/g
0.456 1.00
40321-76-4
1,2,3,7,8-PeCDD
109
Pg/g
0.762 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
105
Pg/g
1.59 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
108
Pg/g
1.54 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
111
Pg/g
1.60 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
105
Pg/g
2.96 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
203
Pg/g
7.66 10.0
51207-31-9
2,3,7,8-TCDF
19.2
Pg/g
0.468 1.00
57117-41-6
1,2,3,7,8-PeCDF
104
Pg/g
1.16 5.00
57117-31-4
2,3,4,7,8-PeCDF
106
Pg/g
1.13 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
111
Pg/g
1.44 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
114
Pg/g
1.35 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
111
Pg/g
1.43 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
107
Pg/g
2.38 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
102
Pg/g
1.61 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.6
Pg/g
2.98 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
226
Pg/g
5.54 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
153
200
Pg/g
76.3
(20%-175%)
13C-1,2,3,7,8-
PeCDD
157
200
Pg/g
78.6
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
139
200
Pg/g
69.3
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
167
200
Pg/g
83.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
152
200
Pg/g
76.1
(22%-166%)
13C-OCDD
265
400
Pg/g
66.3
(13%-199%)
13C-2,3,7,8-TCDF
157
200
Pg/g
78.5
(22%-152%)
13C-1,2,3,7,8-
PeCDF
163
200
Pg/g
81.7
(21%-192%)
130-2,3,4,7,8-
PeCDF
167
200
Pg/g
83.4
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
140
200
Pg/g
70.1
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
165
200
Pg/g
82.3
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
158
200
Pg/g
79.1
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
142
200
Pg/g
70.9
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
158
200
Pg/g
79.1
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
146
200
Pg/g
72.8
(20%-186%)
3701-2,3,7,8-TCDD
19.1
20.0
Pg/g
95.4
(31 %-191%)
Comments:
Page 20 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 15, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5973
Lab Sample ID: 12010154
Client Sample: *or batch 25617
Client ID: LCSD for batch 25617
Batch ID: 25621
Run Date: 04/11/2014 17:03
Data File: bllaprl4a-5
Prep Batch: 25617
Prep Date: 10-APR-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.7
Pg/g
0.388 1.00
40321-76-4
1,2,3,7,8-PeCDD
107
Pg/g
0.860 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
104
Pg/g
1.26 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
107
Pg/g
1.22 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
115
Pg/g
1.27 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.2
Pg/g
1.99 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
211
Pg/g
6.10 10.0
51207-31-9
2,3,7,8-TCDF
20.1
Pg/g
0.450 1.00
57117-41-6
1,2,3,7,8-PeCDF
105
Pg/g
0.798 5.00
57117-31-4
2,3,4,7,8-PeCDF
108
Pg/g
0.778 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
116
Pg/g
1.40 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
106
Pg/g
1.34 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
108
Pg/g
1.32 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
111
Pg/g
2.40 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
103
Pg/g
1.73 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
102
Pg/g
2.74 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
239
Pg/g
8.78 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
156
200
Pg/g
78.0
(20%-175%)
13C-1,2,3,7,8-
PeCDD
166
200
Pg/g
83.0
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
135
200
Pg/g
67.7
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
171
200
Pg/g
85.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
160
200
Pg/g
79.9
(22%-166%)
13C-OCDD
266
400
Pg/g
66.6
(13%-199%)
13C-2,3,7,8-TCDF
158
200
Pg/g
79.2
(22%-152%)
13C-1,2,3,7,8-
PeCDF
178
200
Pg/g
89.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
173
200
Pg/g
86.5
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
138
200
Pg/g
68.9
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
169
200
Pg/g
84.7
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
161
200
Pg/g
80.7
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
140
200
Pg/g
70.0
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
158
200
Pg/g
78.8
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
149
200
Pg/g
74.6
(20%-186%)
3701-2,3,7,8-TCDD
20.4
20.0
Pg/g
102
(31 %-191%)
Comments:
Page 21 of 21
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 14. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 5968
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 09, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Enclosures
Page 1 of25
problem solved
-------
Page: j_
Project #:
CFAQuote#;
COC Number (1>:_
PO Number:
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number:
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone:(910)795-0421
Client N—e: 5(1 (olVt
Sample Analysis Requested(S> (Fill in the number of containers for each test)
T
fa
0Q
K
O
Project/Site Name: ^ V*1 0 W
Address:
2& Aawif>s4tr
5a
3=.
iffl
^1i
(ttu)
TAT Requested: Normal: Rush: .Sfiecign
^Subject to Surcharge) Fax Results:
Yes /
Circle Deliverable: C of A / QC Summaty / Level 1 / Level 21! Level 3 / Bevel 4
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
?o%A>\fc- \ CovA^ec^S
Sample CollectiMcTime
Egstoi Pacific
Other _
Mwrataltr
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed) Date Time
I7t0b'
Received by (signed) Date
Time
fju^^Aduy^ MAP&U D1j|
CFA PM:
Method of Shipment:
Date Shipped:
Airbill #:
Airbill #:
1.) Chain of Custody Number — Client Determined
2.) QC Codes: M "Normal Sample, TB - Trip Blank, Fi> = Field Duplicate, KB = Equipment Blank, MS - Matrix Spike Sample, MSD = Matrix Spike Duplicate Sample, G - Grab, C = Composite
3.) Field Filtered- For liquid matrices, indicate with a-V - for yes the sample was field filtered or- N - for sample was not field filtered
4.) Matrix Codes: DW=Drmking Water,GWNjroundwater, SW-Surface Water. WW* Waste Water, W=Water. ML-Misc Liquid,SO-Soi!, SD-Sediraent, Sl.-Sludge, SS"Solid Waste, O=0il,F=Filter,P=Wipe, U-Urine, F-Fecal, N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.e82MB, l*6SB)and number of containers provided for each
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
Work Order: ^ fofS
Rece,ved By'
Date/T.me Received: Qq fif {H 3Q
* Notify RSO of any responses in this column immediately.
Page 3 of25
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 25
-------
Case Narrative
Page 5 of25
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 5968
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25608
Clean Up Batch Number: 25599
Extraction Batch Number: 25598
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
5968001 SFRA-5
5968002 SFRA-6
5968003 SFRA-7
12010139 Method Blank (MB)
12010140 Laboratory Control Sample (LCS)
12010141 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of 25
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 25608.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP. Per client request, a 5 gram aliquot was
used for dry weights and remaining grams were used for extraction. See enclosed logbook page
for exact weights.
Sample Dilutions
Sample 5968003 (SFRA-7)- Batch 25608 was diluted due to the presence of overrange target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 7 of25
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 25
-------
Sample Data Summary
Page 9 of 25
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 5968 CFA Work Order: 5968
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
E Value is estimated - Concentration of the target analyte exceeds the instrument calibration range
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 14 APR 2014 Title: Data Validator
Page 10 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
5968
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
5968001
Date Collected:
04/08/2014 14:25
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/09/2014 09:30
%Moisture:
21.6
Client ID:
SFRA-5
Prep Basis:
Dry Weight
Batch ID:
25608
Method:
EPA Method 1613B
Run Date:
04/11/2014 16:10
Analyst:
JTF
Instrument:
HRP750
Data File:
A11APR14A 2-9
Dilution:
1
Prep Batch:
25598
Prep Method:
SW846 3540C
Prep Date:
09-APR-14
Prep Aliquot:
19.86 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
J
0.419
Pg/g
0.401
0.642
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
E Value is estimated - Concentration of the target analyte exceeds the instrument calibration range
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5968
Lab Sample ID: 5968001
Client Sample: 1613B Soil
Client ID: SFRA-5
Batch ID: 25608
Run Date: 04/10/2014 23:47
Data File: bl0aprl4a_2-10
Prep Batch: 25598
Prep Date: 09-APR-14
Chent:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
04/08/2014 14:25
04/09/2014 09:30
EPA Method 1613B
JTF
SW846 3540C
19.86 g
Project: TETR00114
Matrix: SOLID
%Moisture: 21.6
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
8.06
Pg/g
0.281 0.642
40321-76-4
1,2,3,7,8-PeCDD
U
.682
Pg/g
0.682 3.21
39227-28-6
1,2,3,4,7,8-HxCDD
J
1.84
Pg/g
0.583 3.21
57653-85-7
1,2,3,6,7,8-HxCDD
u
4.24
Pg/g
4.24 3.21
19408-74-3
1,2,3,7,8,9-HxCDD
J
3.02
Pg/g
0.611 3.21
35822-46-9
1,2,3,4,6,7,8-HpCDD
155
Pg/g
1.76 3.21
3268-87-9
1,2,3,4,6,7,8,9-OCDD
E
4960
Pg/g
4.20 6.42
51207-31-9
2,3,7,8-TCDF
0.677
Pg/g
0.660 0.642
57117-41-6
1,2,3,7,8-PeCDF
J
3.06
Pg/g
0.605 3.21
57117-31-4
2,3,4,7,8-PeCDF
J
1.15
Pg/g
0.622 3.21
70648-26-9
1,2,3,4,7,8-HxCDF
J
3.04
Pg/g
0.438 3.21
57II7.44.9
1,2,3,6,7,8-HxCDF
U
.965
Pg/g
0.965 3.21
60851-34-5
2,3,4,6,7,8-HxCDF
J
1.03
Pg/g
0.448 3.21
72918-21-9
1,2,3,7,8,9-HxCDF
u
.678
Pg/g
0.678 3.21
67562-39-4
1,2,3,4,6,7,8-HpCDF
24.7
Pg/g
0.284 3.21
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
1.52
Pg/g
0.491 3.21
39001-02-0
1,2,3,4,6,7,8,9-OCDF
61.3
Pg/g
0.840 6.42
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
109
128
Pg/g
84.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
115
128
Pg/g
89.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
105
128
Pg/g
81.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
102
128
Pg/g
79.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
116
128
Pg/g
90.1
(23%-140%)
13C-OCDD
265
257
Pg/g
103
(17%-157%)
13C-2,3,7,8-TCDF
107
128
Pg/g
83.4
(24%-169%)
13C-1,2,3,7,8-
PeCDF
115
128
Pg/g
89.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
115
128
Pg/g
89.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
96.4
128
Pg/g
75.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
94.4
128
Pg/g
73.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
99.5
128
Pg/g
77.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
89.6
128
Pg/g
69.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
108
128
Pg/g
83.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
106
128
Pg/g
82.4
(26%-13 8%)
3701-2,3,7,8-TCDD
13.3
12.8
Pg/g
103
(35%-197%)
Comments:
E Value is estimated - Concentration of the target analyte exceeds the instrument calibration range
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5968
Lab Sample ID: 5968002
Client Sample: 1613B Soil
Client ID: SFRA-6
Batch ID: 25608
Run Date: 04/11/2014 00:34
Data File: bl0aprl4a_2-ll
Prep Batch: 25598
Prep Date: 09-APR-14
Chent:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
04/08/2014 15:39
04/09/2014 09:30
EPA Method 1613B
JTF
SW846 3540C
16.06 g
Project: TETR00114
Matrix: SOLID
%Moisture: 19.8
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3.12
Pg/g
0.356 0.776
40321-76-4
1,2,3,7,8-PeCDD
U
.391
Pg/g
0.391 3.88
39227-28-6
1,2,3,4,7,8-HxCDD
u
.716
Pg/g
0.716 3.88
57653-85-7
1,2,3,6,7,8-HxCDD
J
0.961
Pg/g
0.602 3.88
19408-74-3
1,2,3,7,8,9-HxCDD
J
1.12
Pg/g
0.573 3.88
35822-46-9
1,2,3,4,6,7,8-HpCDD
51.1
Pg/g
1.11 3.88
3268-87-9
1,2,3,4,6,7,8,9-OCDD
1800
Pg/g
4.57 7.76
51207-31-9
2,3,7,8-TCDF
u
.349
Pg/g
0.349 0.776
57117-41-6
1,2,3,7,8-PeCDF
u
.309
Pg/g
0.309 3.88
57117-31-4
2,3,4,7,8-PeCDF
u
.289
Pg/g
0.289 3.88
70648-26-9
1,2,3,4,7,8-HxCDF
u
.23
Pg/g
0.230 3.88
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.214
Pg/g
0.214 3.88
60851-34-5
2,3,4,6,7,8-HxCDF
u
.224
Pg/g
0.224 3.88
72918-21-9
1,2,3,7,8,9-HxCDF
u
.365
Pg/g
0.365 3.88
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
1.76
Pg/g
0.188 3.88
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.281
Pg/g
0.281 3.88
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
3.04
Pg/g
0.652 7.76
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
132
155
Pg/g
84.9
(25 %-164%)
130-1,2,3,7,8-
PeCDD
147
155
Pg/g
94.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
126
155
Pg/g
81.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
125
155
Pg/g
80.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
140
155
Pg/g
90.0
(23%-140%)
13C-OCDD
292
311
Pg/g
93.9
(17%-157%)
13C-2,3,7,8-TCDF
132
155
Pg/g
85.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
143
155
Pg/g
92.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
146
155
Pg/g
94.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
119
155
Pg/g
76.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
120
155
Pg/g
77.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
126
155
Pg/g
81.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
110
155
Pg/g
71.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
135
155
Pg/g
87.2
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
132
155
Pg/g
85.0
(26%-13 8%)
3701-2,3,7,8-TCDD
15.5
15.5
Pg/g
100
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
5968
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
5968003
Date Collected:
04/08/2014 16:07
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/09/2014 09:30
%Moisture:
20.6
Client ID:
SFRA-7
Prep Basis:
Dry Weight
Batch ID:
25608
Method:
EPA Method 1613B
Run Date:
04/14/2014 10:32
Analyst:
JTF
Instrument:
HRP750
Data File:
A14APR14A-4
Dilution:
10
Prep Batch:
25598
Prep Method:
SW846 3540C
Prep Date:
09-APR-14
Prep Aliquot:
15.71 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
J
7.29
Pg/g
2.04
8.02
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
5968
5968003
1613B Soil
SFRA-7
25608
04/11/201415:20
bllaprl4a-3
25598
09-APR-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
TETR001
Date Collected: 04/08/2014 16:07
Date Received: 04/09/2014 09:30
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
u
u
J
J
u
u
u
u
u
J
u
J
EPA Method 1613B
JTF
SW846 3540C
15.71 g
Result
1080
3.91
7.3
6.13
6.06
114
1870
6.08
8.18
2.97
3.13
2.89
3.43
5.71
20.1
11.2
40.7
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
4.67
3.91
7.30
6.13
6.06
17.6
68.5
5.37
3.19
2.97
3.13
2.89
3.43
5.71
5.13
11.2
16.2
TETR00114
SOLID
20.6
Dry Weight
HRP763
10
PQL
8.02
40.1
40.1
40.1
40.1
40.1
80.2
8.02
40.1
40.1
40.1
40.1
40.1
40.1
40.1
40.1
80.2
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
138
160
Pg/g
85.8
(25 %-164%)
13C-1,2,3,7,8-PeCDD
123
160
Pg/g
76.7
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
107
160
Pg/g
66.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
173
160
Pg/g
108
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
125
160
Pg/g
77.8
(23%-140%)
13C-OCDD
252
321
Pg/g
78.5
(17%-157%)
13C-2,3,7,8-TCDF
132
160
Pg/g
82.5
(24%-169%)
13C-1,2,3,7,8-PeCDF
130
160
Pg/g
81.2
(24%-185%)
13C-2,3,4,7,8-PeCDF
140
160
Pg/g
87.3
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
118
160
Pg/g
73.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
170
160
Pg/g
106
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
147
160
Pg/g
91.9
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
96.6
160
Pg/g
60.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
136
160
Pg/g
84.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
122
160
Pg/g
75.9
(26%-13 8%)
37Cl-2,3,7,8-TCDD
20.3
16.0
Pg/g
127
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 25
-------
Quality Control
Summary
Page 16 of 25
-------
( ape Fear \lltllytictll LLC Report Date: April 14, 2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 5968
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010140
LCS for batch 25598
12010141
LCSD for batch 25598
12010139
MB for batch 25598
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
76.7
85.3
69.1
81.3
76.7
72.2
79.4
87.0
84.6
66.9
75.1
75.4
65.9
76.9
74.5
97.6
80.7
84.8
82.3
88.2
92.6
94.9
84.5
86.5
85.6
81.2
86.3
85.1
76.3
91.4
88.6
103
79.3
80.5
76.4
85.1
87.8
82.0
81.5
85.3
83.7
73.0
80.9
82.4
69.7
83.3
82.5
94.9
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
5968001
SFRA-5
13C-2,3,7,8-TCDD
84.7
(25%-164%)
Page 17 of 25
-------
( ape Fear \lltllytictll LLC Report Date: April 14, 2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 5968
Matrix Type: SOLID
Sample ID Client ID
5968001 SFRA-5
5968002 SFRA-6
5968003 SFRA-7
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
89.6
(25%-181%)
81.6
(32%-141%)
79.2
(28%-130%)
90.1
(23%-140%)
103
(17%-15 7%)
83.4
(24%-169%)
89.5
(24%-185%)
89.2
(21%-178%)
75.1
(26%-152%)
73.5
(26%-123%)
77.4
(28%-13 6%)
69.7
(29%-147%)
83.8
(28%-143%)
82.4
(26%-13 8%)
103
(35%-197%)
84.9
(25%-164%)
94.6
(25%-181%)
81.2
(32%-141%)
80.5
(28%-130%)
90.0
(23%-140%)
93.9
(17%-15 7%)
85.0
(24%-169%)
92.2
(24%-185%)
94.1
(21%-178%)
76.8
(26%-152%)
77.3
(26%-123%)
81.0
(28%-13 6%)
71.0
(29%-147%)
87.2
(28%-143%)
85.0
(26%-13 8%)
100
(35%-197%)
85.8
D
(25%-164%)
76.7
D
(25%-181%)
66.7
D
(32%-141%)
108
D
(28%-130%)
77.8
D
(23%-140%)
78.5
D
(17%-15 7%)
82.5
D
(24%-169%)
81.2
D
(24%-185%)
87.3
D
(21%-178%)
73.8
D
(26%-152%)
106
D
(26%-123%)
91.9
D
(28%-13 6%)
60.2
D
(29%-147%)
84.7
D
(28%-143%)
75.9
D
(26%-13 8%)
127
D
(35%-197%)
* Recovery outside Acceptance Limits
Page 18 of 25
-------
Cape Fear Analytical LLC
Report Date: April 14, 2014
SDG Number: 5968
Matrix Type: SOLID
Hi-Res Dioxins/Furans
Surrogate Recovery Report
Page 3
of 3
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 19 of 25
-------
Cape Fear Analytical LLC
Report Date: April 14, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/10/2014 16:38 Dilution: 1
Prep Batch ID:25598
Batch ID: 25608
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.3
101
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
101
101
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
95.3
95.3
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
98.8
98.8
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
99.5
99.5
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
104
104
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
204
102
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
17.7
88.7
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
97.3
97.3
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
101
101
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
102
102
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
103
103
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
101
101
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
109
109
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
98.5
98.5
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
215
107
63-170
SDG Number: 5968
Client ID: LCS for batch 25598
Lab Sample ID: 12010140
Instrument: HRP763
Analyst: JTF
Page
20 of 25
-------
Cape Fear Analytical LLC
Report Date: April 14, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/10/2014 17:25 Dilution: 1
Prep Batch ID:25598
Batch ID: 25608
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.1
105
67-158
3.92
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
107
107
70-142
5.37
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
100
100
70-164
5.10
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
110
110
76-134
10.8
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
106
106
64-162
6.58
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
98.3
98.3
70-140
5.54
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
195
97.6
78-144
4.41
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.3
96.6
75-158
8.53
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
101
101
80-134
3.29
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
102
102
68-160
0.875
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
101
101
72-134
1.09
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
102
102
84-130
1.22
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
106
106
70-156
5.27
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
113
113
78-130
3.67
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
0.0889
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
101
101
78-138
2.76
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
207
104
63-170
3.56
0-20
SDG Number: 5968
Client ID: LCSD for batch 25598
Lab Sample ID: 12010141
Instrument: HRP763
Analyst: JTF
Page 21 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
Method Blank Summary
Page 1 of 1
SDG Number:
Client ID:
Lab Sample ID: 12010139
Column:
5968
MB for batch 25598
Client: TETR001
Instrument ID: HRP763
Prep Date: 09-APR-14
Matrix: SOLID
Data File: bl0aprl4a_2-3
Analyzed: 04/10/1418:12
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 25598
12010140
bl0aprl4a 2-1
04/10/14
1638
02
LCSD for batch 25598
12010141
bl0aprl4a 2-2
04/10/14
1725
03
SFRA-5
5968001
bl0aprl4a 2-10
04/10/14
2347
04
SFRA-6
5968002
bl0aprl4a_2-ll
04/11/14
0034
05
SFRA-7
5968003
bllaprl4a-3
04/11/14
1520
06
SFRA-5
5968001
A11APR14A2-9
04/11/14
1610
07
SFRA-7
5968003
A14APR14A-4
04/14/14
1032
Page 22 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 5968
Client:
TETR001
Project: TETR00114
Lab Sample ID: 12010139
Matrix: SOLID
Client Sample: ^or batch 25598
Client ID:
MB for batch 25598
Prep Basis: As Received
Batch ID:
25608
Method:
EPA Method 1613B
Run Date:
04/10/2014 18:12
Analyst:
JTF
Instrument: HRP763
Data File:
bl0aprl4a_2-3
Dilution: 1
Prep Batch:
25598
Prep Method:
SW846 3540C
Prep Date:
09-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.332
Pg/g
0.332 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.284
Pg/g
0.284 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.266
Pg/g
0.266 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.264
Pg/g
0.264 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.272
Pg/g
0.272 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.484
Pg/g
0.484 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.74
Pg/g
0.740 10.0
51207-31-9
2,3,7,8-TCDF
u
.274
Pg/g
0.274 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.21
Pg/g
0.210 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.214
Pg/g
0.214 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.292
Pg/g
0.292 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.276
Pg/g
0.276 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.284
Pg/g
0.284 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.464
Pg/g
0.464 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.202
Pg/g
0.202 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.332
Pg/g
0.332 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.85
Pg/g
0.850 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
159
200
Pg/g
79.3
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
161
200
Pg/g
80.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
153
200
Pg/g
76.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
170
200
Pg/g
85.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
176
200
Pg/g
87.8
(23%-140%)
13C-OCDD
328
400
Pg/g
82.0
(17%-157%)
13C-2,3,7,8-TCDF
163
200
Pg/g
81.5
(24%-169%)
13C-1,2,3,7,8-
PeCDF
171
200
Pg/g
85.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
167
200
Pg/g
83.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
146
200
Pg/g
73.0
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
162
200
Pg/g
80.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
165
200
Pg/g
82.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
139
200
Pg/g
69.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
167
200
Pg/g
83.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
165
200
Pg/g
82.5
(26%-13 8%)
3701-2,3,7,8-TCDD
19.0
20.0
Pg/g
94.9
(35%-197%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 23 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5968
Lab Sample ID: 12010140
Client Sample: ^or batch 25598
Client ID: LCS for batch 25598
Batch ID: 25608
Run Date: 04/10/2014 16:38
Data File: bl0aprl4a_2-l
Prep Batch: 25598
Prep Date: 09-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.3
Pg/g
0.252 1.00
40321-76-4
1,2,3,7,8-PeCDD
101
Pg/g
0.608 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
95.3
Pg/g
0.738 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.8
Pg/g
0.694 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
99.5
Pg/g
0.732 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
104
Pg/g
1.23 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
204
Pg/g
3.42 10.0
51207-31-9
2,3,7,8-TCDF
17.7
Pg/g
0.254 1.00
57117-41-6
1,2,3,7,8-PeCDF
97.3
Pg/g
0.750 5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.756 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
102
Pg/g
0.990 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
103
Pg/g
0.938 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
101
Pg/g
0.940 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
109
Pg/g
1.62 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
0.808 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
98.5
Pg/g
1.43 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
215
Pg/g
3.52 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
153
200
Pg/g
76.7
(20%-175%)
13C-1,2,3,7,8-
PeCDD
171
200
Pg/g
85.3
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
138
200
Pg/g
69.1
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
163
200
Pg/g
81.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
153
200
Pg/g
76.7
(22%-166%)
13C-OCDD
289
400
Pg/g
72.2
(13%-199%)
13C-2,3,7,8-TCDF
159
200
Pg/g
79.4
(22%-152%)
13C-1,2,3,7,8-
PeCDF
174
200
Pg/g
87.0
(21%-192%)
130-2,3,4,7,8-
PeCDF
169
200
Pg/g
84.6
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
134
200
Pg/g
66.9
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
150
200
Pg/g
75.1
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
151
200
Pg/g
75.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
132
200
Pg/g
65.9
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
154
200
Pg/g
76.9
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
149
200
Pg/g
74.5
(20%-186%)
3701-2,3,7,8-TCDD
19.5
20.0
Pg/g
97.6
(31 %-191%)
Comments:
Page 24 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 14, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
5968
12010141
QC for batch 25598
LCSD for batch 25598
25608
04/10/2014 17:25
bl0aprl4a_2-2
25598
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
09-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
21.1
Pg/g
0.276
1.00
40321-76-4
1,2,3,7,8-PeCDD
107
Pg/g
0.614
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
100
Pg/g
1.29
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
110
Pg/g
1.35
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
106
Pg/g
1.36
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
98.3
Pg/g
1.14
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
195
Pg/g
3.18
10.0
51207-31-9
2,3,7,8-TCDF
19.3
Pg/g
0.384
1.00
57117-41-6
1,2,3,7,8-PeCDF
101
Pg/g
0.788
5.00
57117-31-4
2,3,4,7,8-PeCDF
102
Pg/g
0.744
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
101
Pg/g
1.00
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
102
Pg/g
0.984
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
106
Pg/g
1.08
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
113
Pg/g
1.66
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
1.18
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
101
Pg/g
1.82
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
207
Pg/g
3.76
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
161
200
Pg/g
80.7
(20%-175%)
13C-1,2,3,7,8-PeCDD
170
200
Pg/g
84.8
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
165
200
Pg/g
82.3
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
176
200
Pg/g
88.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
185
200
Pg/g
92.6
(22%-166%)
13C-OCDD
380
400
Pg/g
94.9
(13%-199%)
13C-2,3,7,8-TCDF
169
200
Pg/g
84.5
(22%-152%)
13C-1,2,3,7,8-PeCDF
173
200
Pg/g
86.5
(21%-192%)
13C-2,3,4,7,8-PeCDF
171
200
Pg/g
85.6
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
162
200
Pg/g
81.2
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
173
200
Pg/g
86.3
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
170
200
Pg/g
85.1
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
153
200
Pg/g
76.3
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
183
200
Pg/g
91.4
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
177
200
Pg/g
88.6
(20%-186%)
37Cl-2,3,7,8-TCDD
20.6
20.0
Pg/g
103
(31 %-191%)
Comments:
Page 25 of 25
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 16. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 5983
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 11, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Enclosures
Page 1 of25
problem solved
-------
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(condition of samples upon receipt,
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-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
TErTd-
Work Order:
S
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 25
-------
Case Narrative
Page 5 of25
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 5983
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25651
Clean Up Batch Number: 25650
Extraction Batch Number: 25649
Sample Analysis
The following samples were analyzed using the analytical protocol as established in
Sample ID Client ID
5983001 SFRA-9
5983002 SFRA-10
5983003 SFRA-11
12010170 Method Blank (MB)
12010171 Laboratory Control Sample (LCS)
12010172 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of 25
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP.
Sample Dilutions
Samples 5983001 (SFRA-9) and 5983003 (SFRA-11)- Batch 25651 were diluted due to the
presence of overrange target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Page 7 of25
-------
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 25
-------
Sample Data Summary
Page 9 of 25
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 5983 CFA Work Order: 5983
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 16 APR 2014 Title: Data Validator
Page 10 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
5983
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
5983001
Date Collected:
04/10/2014 16:00
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/11/2014 10:20
%Moisture:
18.3
Client ID:
SFRA-9
Prep Basis:
Dry Weight
Batch ID:
25651
Method:
EPA Method 1613B
Run Date:
04/16/2014 09:54
Analyst:
JTF
Instrument:
HRP750
Data File:
A16APR14A-4
Dilution:
20
Prep Batch:
25649
Prep Method:
SW846 3540C
Prep Date:
ll-APR-14
Prep Aliquot:
15.92 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
23.9
Pg/g
3.46
15.4
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5983
Lab Sample ID: 5983001
Client Sample: 1613B Soil
Client ID: SFRA-9
Batch ID: 25651
Run Date: 04/15/2014 20:39
Data File: bl5aprl4b_2-6
Prep Batch: 25649
Prep Date: ll-APR-14
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
04/10/2014 16:00
04/11/201410:20
EPA Method 1613B
JTF
SW846 3540C
15.92 g
Project: TETR00114
Matrix: SOLID
%Moisture: 18.3
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 20
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3580
Pg/g
4.52 15.4
40321-76-4
1,2,3,7,8-PeCDD
U
3.12
Pg/g
3.12 76.9
39227-28-6
1,2,3,4,7,8-HxCDD
u
5.89
Pg/g
5.89 76.9
57653-85-7
1,2,3,6,7,8-HxCDD
J
18.3
Pg/g
6.15 76.9
19408-74-3
1,2,3,7,8,9-HxCDD
J
6.27
Pg/g
6.21 76.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
311
Pg/g
13.7 76.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5580
Pg/g
57.2 154
51207-31-9
2,3,7,8-TCDF
18.4
Pg/g
7.10 15.4
57117-41-6
1,2,3,7,8-PeCDF
J
3.33
Pg/g
3.15 76.9
57117-31-4
2,3,4,7,8-PeCDF
u
2.98
Pg/g
2.98 76.9
70648-26-9
1,2,3,4,7,8-HxCDF
J
4.89
Pg/g
3.61 76.9
57II7.44.9
1,2,3,6,7,8-HxCDF
u
3.12
Pg/g
3.12 76.9
60851-34-5
2,3,4,6,7,8-HxCDF
u
3.23
Pg/g
3.23 76.9
72918-21-9
1,2,3,7,8,9-HxCDF
u
5.34
Pg/g
5.34 76.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
53.0
Pg/g
5.60 76.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
9.33
Pg/g
9.33 76.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
131
Pg/g
11.3 154
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
142
154
Pg/g
92.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
129
154
Pg/g
84.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
133
154
Pg/g
86.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
138
154
Pg/g
89.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
126
154
Pg/g
82.2
(23%-140%)
13C-OCDD
266
308
Pg/g
86.6
(17%-157%)
13C-2,3,7,8-TCDF
134
154
Pg/g
87.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
125
154
Pg/g
81.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
126
154
Pg/g
82.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
117
154
Pg/g
76.0
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
140
154
Pg/g
91.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
120
154
Pg/g
78.3
(28%-136%)
130-1,2,3,7,8,9-HxCDF
95.3
154
Pg/g
62.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
124
154
Pg/g
80.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
109
154
Pg/g
70.7
(26%-13 8%)
3701-2,3,7,8-TCDD
32.7
15.4
Pg/g
213
* (35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5983
Lab Sample ID: 5983002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/10/2014 16:20
04/11/201410:20
Project: TETR00114
Matrix: SOLID
%Moisture: 18.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-10
25651
04/15/2014 19:51
bl5aprl4b_2-5
25649
ll-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
17.54 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
5.46
Pg/g
0.122 0.700
40321-76-4
1,2,3,7,8-PeCDD
U
.2
Pg/g
0.200 3.50
39227-28-6
1,2,3,4,7,8-HxCDD
J
0.514
Pg/g
0.318 3.50
57653-85-7
1,2,3,6,7,8-HxCDD
J
0.745
Pg/g
0.325 3.50
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.902
Pg/g
0.331 3.50
35822-46-9
1,2,3,4,6,7,8-HpCDD
52.5
Pg/g
0.944 3.50
3268-87-9
1,2,3,4,6,7,8,9-OCDD
2230
Pg/g
3.52 7.00
51207-31-9
2,3,7,8-TCDF
u
.131
Pg/g
0.131 0.700
57117-41-6
1,2,3,7,8-PeCDF
u
.0974
Pg/g
0.0974 3.50
57117-31-4
2,3,4,7,8-PeCDF
u
.0937
Pg/g
0.0937 3.50
70648-26-9
1,2,3,4,7,8-HxCDF
u
.0716
Pg/g
0.0716 3.50
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.0731
Pg/g
0.0731 3.50
60851-34-5
2,3,4,6,7,8-HxCDF
u
.0731
Pg/g
0.0731 3.50
72918-21-9
1,2,3,7,8,9-HxCDF
u
.115
Pg/g
0.115 3.50
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.273
Pg/g
0.273 3.50
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.135
Pg/g
0.135 3.50
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
0.761
Pg/g
0.453 7.00
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
106
140
Pg/g
75.9
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
108
140
Pg/g
76.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
95.6
140
Pg/g
68.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
105
140
Pg/g
75.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
108
140
Pg/g
76.9
(23%-140%)
13C-OCDD
243
280
Pg/g
86.7
(17%-157%)
13C-2,3,7,8-TCDF
112
140
Pg/g
79.8
(24%-169%)
13C-1,2,3,7,8-
PeCDF
113
140
Pg/g
80.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
111
140
Pg/g
79.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
90.7
140
Pg/g
64.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
99.0
140
Pg/g
70.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
99.7
140
Pg/g
71.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
92.5
140
Pg/g
66.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
105
140
Pg/g
74.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
105
140
Pg/g
74.9
(26%-13 8%)
3701-2,3,7,8-TCDD
13.0
14.0
Pg/g
92.5
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
5983
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
5983003
Date Collected:
04/10/2014 16:25
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/11/2014 10:20
%Moisture:
17.3
Client ID:
SFRA-11
Prep Basis:
Dry Weight
Batch ID:
25651
Method:
EPA Method 1613B
Run Date:
04/16/2014 10:14
Analyst:
JTF
Instrument:
HRP750
Data File:
A16APR14A-5
Dilution:
50
Prep Batch:
25649
Prep Method:
SW846 3540C
Prep Date:
ll-APR-14
Prep Aliquot:
15.81 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
J
36.0
Pg/g
6.33
38.2
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
5983
5983003
1613B Soil
SFRA-11
25651
04/15/2014 21:27
bl5aprl4b_2-7
25649
ll-APR-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
J
u
u
u
u
u
u
u
J
u
J
TETR001
04/10/2014 16:25
04/11/201410:20
EPA Method 1613B
JTF
SW846 3540C
15.81 g
Result
4940
4.98
10.3
20.3
11.7
316
3280
40.2
21.8
10.7
9.51
9.34
8.62
14.9
79.7
11.1
125
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
9.89
4.98
10.3
12.2
11.7
20.6
76.7
14.0
21.8
10.7
9.51
9.34
8.62
14.9
7.54
11.1
35.5
TETR00114
SOLID
17.3
Dry Weight
HRP763
50
PQL
38.2
191
191
191
191
191
382
38.2
191
191
191
191
191
191
191
191
382
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
126
153
Pg/g
82.4
(25 %-164%)
13C-1,2,3,7,8-PeCDD
122
153
Pg/g
79.8
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
121
153
Pg/g
79.3
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
149
153
Pg/g
97.5
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
121
153
Pg/g
79.1
(23%-140%)
13C-OCDD
241
306
Pg/g
78.9
(17%-157%)
13C-2,3,7,8-TCDF
121
153
Pg/g
79.4
(24%-169%)
13C-1,2,3,7,8-PeCDF
119
153
Pg/g
77.9
(24%-185%)
13C-2,3,4,7,8-PeCDF
115
153
Pg/g
75.2
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
106
153
Pg/g
69.1
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
141
153
Pg/g
92.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
127
153
Pg/g
83.2
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
94.7
153
Pg/g
61.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
120
153
Pg/g
78.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
109
153
Pg/g
71.2
(26%-13 8%)
37Cl-2,3,7,8-TCDD
33.2
15.3
Pg/g
217 *
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 25
-------
Quality Control
Summary
Page 16 of 25
-------
( (ipc Fear Analytical LLC Report Date: April 16, 2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 5983
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010171
LCS for batch 25649
12010172
LCSD for batch 25649
12010170
MB for batch 25649
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
82.1
79.0
76.7
79.8
77.2
74.5
81.1
78.4
77.7
71.2
74.7
75.3
69.1
74.2
69.9
104
82.5
82.1
76.2
81.1
80.8
77.7
84.2
79.7
80.9
72.2
74.6
77.8
69.7
76.6
71.6
100
82.2
79.9
73.7
80.0
75.7
69.4
83.8
80.2
79.6
68.5
73.3
74.2
67.0
71.8
66.8
102
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
5983002
SFRA-10
13C-2,3,7,8-TCDD
75.9
(25%-164%)
Page 17 of 25
-------
( (ipc Fear Analytical LLC Report Date: April 16, 2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 5983
Matrix Type: SOLID
Sample ID Client ID
5983002 SFRA-10
5983001 SFRA-9
5983003 SFRA-11
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
76.8
(25%-181%)
68.2
(32%-141%)
75.0
(28%-130%)
76.9
(23%-140%)
86.7
(17%-15 7%)
79.8
(24%-169%)
80.9
(24%-185%)
79.0
(21%-178%)
64.7
(26%-152%)
70.7
(26%-123%)
71.1
(28%-13 6%)
66.0
(29%-147%)
74.8
(28%-143%)
74.9
(26%-13 8%)
92.5
(35%-197%)
92.3
D
(25%-164%)
84.2
D
(25%-181%)
86.3
D
(32%-141%)
89.8
D
(28%-130%)
82.2
D
(23%-140%)
86.6
D
(17%-15 7%)
87.5
D
(24%-169%)
81.3
D
(24%-185%)
82.1
D
(21%-178%)
76.0
D
(26%-152%)
91.2
D
(26%-123%)
78.3
D
(28%-13 6%)
62.0
D
(29%-147%)
80.6
D
(28%-143%)
70.7
D
(26%-13 8%)
213 *
D
(35%-197%)
82.4
D
(25%-164%)
79.8
D
(25%-181%)
79.3
D
(32%-141%)
97.5
D
(28%-130%)
79.1
D
(23%-140%)
78.9
D
(17%-15 7%)
79.4
D
(24%-169%)
77.9
D
(24%-185%)
75.2
D
(21%-178%)
69.1
D
(26%-152%)
92.5
D
(26%-123%)
83.2
D
(28%-13 6%)
61.9
D
(29%-147%)
78.3
D
(28%-143%)
71.2
D
(26%-13 8%)
217*
D
(35%-197%)
* Recovery outside Acceptance Limits
Page 18 of 25
-------
Cape Fear Analytical LLC
Report Date: April 16, 2014
SDG Number: 5983
Matrix Type: SOLID
Hi-Res Dioxins/Furans
Surrogate Recovery Report
Page 3
of 3
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 19 of 25
-------
Cape Fear Analytical LLC
Report Date: April 16, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/14/2014 16:20 Dilution: 1
Prep Batch ID:25649
Batch ID: 25651
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.2
101
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
100
100
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
93.6
93.6
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
99.2
99.2
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
100
100
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
95.2
95.2
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
196
98.2
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
17.7
88.6
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
95.0
95
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
96.3
96.3
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
96.2
96.2
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
100
100
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
98.6
98.6
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
100
100
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
95.1
95.1
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
92.4
92.4
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
185
92.7
63-170
SDG Number: 5983
Client ID: LCS for batch 25649
Lab Sample ID: 12010171
Instrument: HRP750
Analyst: JTF
Page
20 of 25
-------
Cape Fear Analytical LLC
Report Date: April 16, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/14/2014 17:07 Dilution: 1
Prep Batch ID:25649
Batch ID: 25651
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.4
102
67-158
1.08
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
103
103
70-142
2.24
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
98.0
98
70-164
4.64
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
103
103
76-134
3.53
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
102
102
64-162
1.74
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
99.0
99
70-140
3.85
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
198
99.1
78-144
0.894
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
17.8
89
75-158
0.529
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
99.6
99.6
80-134
4.65
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
101
101
68-160
4.28
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
99.6
99.6
72-134
3.47
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
103
103
84-130
2.98
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
102
102
70-156
3.02
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
107
107
78-130
6.60
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
95.1
95.1
82-122
0.0526
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
95.5
95.5
78-138
3.28
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
189
94.5
63-170
1.90
0-20
SDG Number: 5983
Client ID: LCSD for batch 25649
Lab Sample ID: 12010172
Instrument: HRP750
Analyst: JTF
Page 21 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Method Blank Summary
Page 1 of 1
SDG Number:
Client ID:
Lab Sample ID: 12010170
Column:
5983
MB for batch 25649
Client: TETR001
Instrument ID: HRP750
Prep Date: ll-APR-14
Matrix: SOLID
Data File: bl4aprl4a-12
Analyzed: 04/14/1417:55
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 25649
12010171
bl4aprl4a-10
04/14/14
1620
02
LCSD for batch 25649
12010172
bl4aprl4a-ll
04/14/14
1707
03
SFRA-10
5983002
bl5aprl4b_2-5
04/15/14
1951
04
SFRA-9
5983001
bl5aprl4b_2-6
04/15/14
2039
05
SFRA-11
5983003
bl5aprl4b_2-7
04/15/14
2127
06
SFRA-9
5983001
A16APR14A-4
04/16/14
0954
07
SFRA-11
5983003
A16APR14A-5
04/16/14
1014
Page 22 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5983
Lab Sample ID: 12010170
Client Sample: *or batch 25649
Client ID: MB for batch 25649
Batch ID: 25651
Run Date: 04/14/2014 17:55
Data File: bl4aprl4a-12
Prep Batch: 25649
Prep Date: ll-APR-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.16
Pg/g
0.160 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.178
Pg/g
0.178 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.224
Pg/g
0.224 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.224
Pg/g
0.224 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.23
Pg/g
0.230 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.292
Pg/g
0.292 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.592
Pg/g
0.592 10.0
51207-31-9
2,3,7,8-TCDF
u
.175
Pg/g
0.175 1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.176
Pg/g
0.115 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.117
Pg/g
0.117 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.174
Pg/g
0.174 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.137
Pg/g
0.137 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.141
Pg/g
0.141 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.216
Pg/g
0.216 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.159
Pg/g
0.159 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.276
Pg/g
0.276 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.508
Pg/g
0.508 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
164
200
Pg/g
82.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
160
200
Pg/g
79.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
147
200
Pg/g
73.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
160
200
Pg/g
80.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
151
200
Pg/g
75.7
(23%-140%)
13C-OCDD
277
400
Pg/g
69.4
(17%-157%)
13C-2,3,7,8-TCDF
168
200
Pg/g
83.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
160
200
Pg/g
80.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
159
200
Pg/g
79.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
137
200
Pg/g
68.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
147
200
Pg/g
73.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
148
200
Pg/g
74.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
134
200
Pg/g
67.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
144
200
Pg/g
71.8
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
134
200
Pg/g
66.8
(26%-13 8%)
3701-2,3,7,8-TCDD
20.4
20.0
Pg/g
102
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 23 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5983
Lab Sample ID: 12010171
Client Sample: *or batch 25649
Client ID: LCS for batch 25649
Batch ID: 25651
Run Date: 04/14/2014 16:20
Data File: bl4aprl4a-10
Prep Batch: 25649
Prep Date: ll-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.2
Pg/g
0.200 1.00
40321-76-4
1,2,3,7,8-PeCDD
100
Pg/g
0.344 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
93.6
Pg/g
0.524 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
99.2
Pg/g
0.522 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
100
Pg/g
0.538 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.2
Pg/g
0.636 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
196
Pg/g
2.36 10.0
51207-31-9
2,3,7,8-TCDF
17.7
Pg/g
0.238 1.00
57117-41-6
1,2,3,7,8-PeCDF
95.0
Pg/g
0.570 5.00
57117-31-4
2,3,4,7,8-PeCDF
96.3
Pg/g
0.550 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
96.2
Pg/g
0.776 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
100
Pg/g
0.762 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
98.6
Pg/g
0.796 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
100
Pg/g
1.26 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
95.1
Pg/g
0.566 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
92.4
Pg/g
0.984 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
185
Pg/g
2.38 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
164
200
Pg/g
82.1
(20%-175%)
130-1,2,3,7,8-
PeCDD
158
200
Pg/g
79.0
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
153
200
Pg/g
76.7
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
160
200
Pg/g
79.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
154
200
Pg/g
77.2
(22%-166%)
13C-OCDD
298
400
Pg/g
74.5
(13%-199%)
13C-2,3,7,8-TCDF
162
200
Pg/g
81.1
(22%-152%)
130-1,2,3,7,8-
PeCDF
157
200
Pg/g
78.4
(21%-192%)
130-2,3,4,7,8-
PeCDF
155
200
Pg/g
77.7
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
142
200
Pg/g
71.2
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
149
200
Pg/g
74.7
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
151
200
Pg/g
75.3
(22%-176%)
130-1,2,3,7,8,9-HxCDF
138
200
Pg/g
69.1
(17%-205%)
130-1,2,3,4,6,7,8-HpCDF
148
200
Pg/g
74.2
(21%-15 8%)
130-1,2,3,4,7,8,9-HpCDF
140
200
Pg/g
69.9
(20%-186%)
3701-2,3,7,8-TCDD
20.7
20.0
Pg/g
104
(31 %-191%)
Comments:
K Estimated Maximum Possible Concentration
Page 24 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
5983
12010172
QC for batch 25649
LCSD for batch 25649
25651
04/14/2014 17:07
bl4aprl4a-ll
25649
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Method: SW846 3540C
Prep Date:
ll-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.4
Pg/g
0.238 1.00
40321-76-4
1,2,3,7,8-PeCDD
103
Pg/g
0.462 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.0
Pg/g
0.520 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
103
Pg/g
0.500 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
102
Pg/g
0.524 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.0
Pg/g
0.650 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
198
Pg/g
2.30 10.0
51207-31-9
2,3,7,8-TCDF
17.8
Pg/g
0.264 1.00
57117-41-6
1,2,3,7,8-PeCDF
99.6
Pg/g
0.488 5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.472 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
99.6
Pg/g
0.618 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
103
Pg/g
0.628 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
102
Pg/g
0.654 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
107
Pg/g
1.02 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
95.1
Pg/g
0.604 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
95.5
Pg/g
1.10 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
189
Pg/g
1.99 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
165
200
Pg/g
82.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
164
200
Pg/g
82.1
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
152
200
Pg/g
76.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
162
200
Pg/g
81.1
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
162
200
Pg/g
80.8
(22%-166%)
13C-OCDD
311
400
Pg/g
77.7
(13%-199%)
13C-2,3,7,8-TCDF
168
200
Pg/g
84.2
(22%-152%)
13C-1,2,3,7,8-
PeCDF
159
200
Pg/g
79.7
(21%-192%)
130-2,3,4,7,8-
PeCDF
162
200
Pg/g
80.9
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
144
200
Pg/g
72.2
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
149
200
Pg/g
74.6
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
156
200
Pg/g
77.8
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
139
200
Pg/g
69.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
153
200
Pg/g
76.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
143
200
Pg/g
71.6
(20%-186%)
3701-2,3,7,8-TCDD
20.0
20.0
Pg/g
100
(31 %-191%)
Comments:
K Estimated Maximum Possible Concentration
Page 25 of 25
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 18. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 5996
SDG: 5996 2
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 15, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Enclosures
Page 1 of27
problem solved
-------
Page: J
Project #:
CFAQuote#: _
COC Number(":
PO Number:
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: .
btl-tn-oiw—
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Name: ^ -j^
Phon **:%tL'2Z5-Z'Wl
Sample Analysis Requested(S) (Fill in the number of containers for each test)
£
Oc
a
Project/Site Name, fryjavh fjujAi/{a£ /4e^>
~Fax#:
)Adto; 7.P Pn\/JL
(Icollected bv: f
~-\ N b\
f
Send Results To
Sample ID
* For composites - indicate start and stop date/time
Amti k i a roMprkaAsr.
~Time- * ¦"
~Date Collected
(mm-dd-yy)
~Time
Collected
(Military)
(tihrnrn)
QC Code
a)
H/i
Field
Filtered m
Sample
Matrix m
cC
•51
<- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
- IX
j-iU'N
1155
Sii
2
Cock S&tullt /r
UlA i /
ii
1125.
/#8|
• List, f"-
i±
151°
'idflj
\d\
±5_
i&5
OimA f ew- ~fkr
ml
i/
v
TAT Requested: Normal:
Rush: Specify: <
;SubjKi to Surcharge) Fax Results:
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 /
Level 4
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
PaSSjbU- 'Pi O^MS"^F~W^<5ltf5 CoVJ~pQVL\*d$
Sample Collection TrnlFTone
Eastern Pacific
'tSntrJO Other _
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Date
Time
f/fW lhix>
Received by (signed)
Date
Time
iff 5
CFA PM:
Method of Shipment:
LorltiUS
Date
Shipped:
Airbill #i ?/q-7 /)?73
3
Airbill #:
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N = Normal Sample,TB - Trip Blank, FD - Field Duplicate, EB = Equipment Blank, MS = Matrix Spike Sample, MSD = Matrix Spike Duplicate Sample,© = Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered,
4.) Matrix Codes: DW-Drinkmg Water, GW^roundwater, SW=Surface Water, WW=Waste Water, W=Water, ML^Misc Liquid,SO=Soi!, SD-Sediroent, SL-Shidge, ^S—Solid Waste, OOil, F^Filter, P-Wipe, U-Urtne, F^Feeal, N^Nasai
5.) Sample Analysis Requested: Analytical method requested (i.e£290B» 1668B) and number of containers provided for each (i.e. 9290B -3,1668B - I ),
6.) Preservative Type: HA = Hydrochloric Acid, NI»» Nitric Acid, SH = Sodium Hydroxide, SA = Sulfuric Acid, AA = Ascorbic Acid, HX « Hexane, ST = Sodium Thiosulfate, If no preservative is added = leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intact?
YES NO
Cooler Temp:
IP* C
-------
SAMPLE RECEIPT CHECKLIST
Cope Fear Analytical
Client:
-Tfrri^
Work Order:
Received Bv
)^a
Date/Time Received:
\5A?$jik 111?
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
Samples identified as Foreign Soil?
DOE Site Sample Packages
Yes
NA
No*
Screened <0.5 mR/hr?
Samples < 2x background?
Notify RSO of any responses in this column immediately.
Page 3 of27
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 27
-------
Case Narrative
Page 5 of27
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 5996 2
Work Order 5996
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25687
Clean Up Batch Number: 25686
Extraction Batch Number: 25685
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
5996001
SFRA-12
5996002
SFRA-13
5996003
SFRA-14
5996004
SFRA-15
5996005
SFRA-16
12010198
Method Blank (MB)
12010199
Laboratory Control Sample (LCS)
12010200
Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Page 6 of 27
-------
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exception. A lg
extraction was performed on all samples in this work order due to the high levels of target
analytes.
Page 7 of27
-------
Sample Dilutions
Samples 5996003 (SFRA-14) and 5996004 (SFRA-15)- Batch 25687 were diluted due to the
presence of overrange target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 27
-------
Sample Data Summary
Page 9 of 27
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 5996 2 CFA Work Order: 5996
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 18 APR 2014 Title: Data Validator
Page 10 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
5996 2
5996001
1613B Soil
SFRA-12
25687
04/16/2014 20:32
bl5aprl4b_4-9
25685
15-APR-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
TETR001
Date Collected: 04/14/2014 11:55
Date Received: 04/15/201411:15
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
J
J
J
u
u
u
u
u
u
J
u
J
EPA Method 1613B
JTF
SW846 3540C
1.27 g
Result
1080
3.16
3.48
6.80
3.75
163
4260
7.82
4.32
2.59
3.03
3.14
3.12
5.03
20.8
3.16
49.4
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
2.87
3.16
3.48
3.71
3.71
9.55
28.7
0.998
4.32
2.59
3.03
3.14
3.12
5.03
2.08
3.16
8.74
TETR00114
SOLID
19.9
Dry Weight
HRP763
1
PQL
9.82
49.1
49.1
49.1
49.1
49.1
98.2
9.82
49.1
49.1
49.1
49.1
49.1
49.1
49.1
49.1
98.2
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1690
1960
Pg/g
85.9
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1820
1960
Pg/g
92.7
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1500
1960
Pg/g
76.5
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1580
1960
Pg/g
80.6
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
1650
1960
Pg/g
83.9
(23%-140%)
13C-OCDD
3230
3930
Pg/g
82.3
(17%-157%)
13C-2,3,7,8-TCDF
1740
1960
Pg/g
88.6
(24%-169%)
13C-1,2,3,7,8-PeCDF
1910
1960
Pg/g
97.1
(24%-185%)
13C-2,3,4,7,8-PeCDF
1900
1960
Pg/g
96.6
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1410
1960
Pg/g
72.0
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1480
1960
Pg/g
75.4
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1510
1960
Pg/g
76.6
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1360
1960
Pg/g
69.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1620
1960
Pg/g
82.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1540
1960
Pg/g
78.4
(26%-13 8%)
37Cl-2,3,7,8-TCDD
209
196
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
5996 2
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
5996002
Date Collected:
04/14/2014 11:25
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/15/201411:15
%Moisture:
16.7
Client ID:
SFRA-13
Prep Basis:
Dry Weight
Batch ID:
25687
Method:
EPA Method 1613B
Run Date:
04/17/2014 12:39
Analyst:
JTF
Instrument:
HRP750
Data File:
A17APR14A-5
Dilution:
1
Prep Batch:
25685
Prep Method:
SW846 3540C
Prep Date:
15-APR-14
Prep Aliquot:
1.05 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
20.7
Pg/g
3.50
11.4
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5996_2
Lab Sample ID: 5996002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/14/201411:25
04/15/201411:15
Project: TETR00114
Matrix: SOLID
%Moisture: 16.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-13
25687
04/16/2014 21:20
bl5aprl4b_4-10
25685
15-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.05 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3080
Pg/g
7.13 11.4
40321-76-4
1,2,3,7,8-PeCDD
U
6.1
Pg/g
6.10 57.1
39227-28-6
1,2,3,4,7,8-HxCDD
u
14.6
Pg/g
14.6 57.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
19.1
Pg/g
15.1 57.1
19408-74-3
1,2,3,7,8,9-HxCDD
u
15.3
Pg/g
15.3 57.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
367
Pg/g
18.9 57.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5030
Pg/g
63.3 114
51207-31-9
2,3,7,8-TCDF
21.0
Pg/g
5.71 11.4
57117-41-6
1,2,3,7,8-PeCDF
J
7.27
Pg/g
5.03 57.1
57117-31-4
2,3,4,7,8-PeCDF
u
5.44
Pg/g
5.44 57.1
70648-26-9
1,2,3,4,7,8-HxCDF
u
5.03
Pg/g
5.03 57.1
57II7.44.9
1,2,3,6,7,8-HxCDF
u
5.01
Pg/g
5.01 57.1
60851-34-5
2,3,4,6,7,8-HxCDF
u
5.19
Pg/g
5.19 57.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
8
Pg/g
8.00 57.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
66.3
Pg/g
6.99 57.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
11.3
Pg/g
11.3 57.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
213
Pg/g
33.6 114
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1870
2290
Pg/g
81.8
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2120
2290
Pg/g
92.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1840
2290
Pg/g
80.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2030
2290
Pg/g
88.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1970
2290
Pg/g
86.0
(23%-140%)
13C-OCDD
4310
4570
Pg/g
94.2
(17%-157%)
13C-2,3,7,8-TCDF
1930
2290
Pg/g
84.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2190
2290
Pg/g
95.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
2180
2290
Pg/g
95.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1790
2290
Pg/g
78.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1970
2290
Pg/g
86.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1950
2290
Pg/g
85.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1710
2290
Pg/g
74.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2020
2290
Pg/g
88.4
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2030
2290
Pg/g
89.0
(26%-13 8%)
3701-2,3,7,8-TCDD
241
229
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5996_2
Lab Sample ID: 5996003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/14/201413:10
04/15/201411:15
Project: TETR00114
Matrix: SOLID
%Moisture: 19.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-14
25687
04/17/201410:11
bl5aprl4b_5-12
25685
15-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.07 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
5670
Pg/g
22.5 57.9
40321-76-4
1,2,3,7,8-PeCDD
U
19.9
Pg/g
19.9 289
39227-28-6
1,2,3,4,7,8-HxCDD
u
25.9
Pg/g
25.9 289
57653-85-7
1,2,3,6,7,8-HxCDD
u
24.8
Pg/g
24.8 289
19408-74-3
1,2,3,7,8,9-HxCDD
u
25.9
Pg/g
25.9 289
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
216
Pg/g
42.6 289
3268-87-9
1,2,3,4,6,7,8,9-OCDD
2800
Pg/g
324 579
51207-31-9
2,3,7,8-TCDF
J
34.9
Pg/g
33.1 57.9
57117-41-6
1,2,3,7,8-PeCDF
u
14.5
Pg/g
14.5 289
57117-31-4
2,3,4,7,8-PeCDF
u
10.6
Pg/g
10.6 289
70648-26-9
1,2,3,4,7,8-HxCDF
u
13.4
Pg/g
13.4 289
57II7.44.9
1,2,3,6,7,8-HxCDF
u
11.9
Pg/g
11.9 289
60851-34-5
2,3,4,6,7,8-HxCDF
u
14.3
Pg/g
14.3 289
72918-21-9
1,2,3,7,8,9-HxCDF
u
23.8
Pg/g
23.8 289
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
53.4
Pg/g
18.9 289
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
35.2
Pg/g
35.2 289
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
90.6
Pg/g
57.4 579
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1860
2310
Pg/g
80.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2000
2310
Pg/g
86.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1750
2310
Pg/g
75.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2150
2310
Pg/g
92.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1970
2310
Pg/g
85.1
(23%-140%)
13C-OCDD
3550
4630
Pg/g
76.8
(17%-157%)
13C-2,3,7,8-TCDF
1880
2310
Pg/g
81.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2050
2310
Pg/g
88.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
2130
2310
Pg/g
91.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1630
2310
Pg/g
70.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1930
2310
Pg/g
83.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1860
2310
Pg/g
80.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1590
2310
Pg/g
68.5
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1880
2310
Pg/g
81.4
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1690
2310
Pg/g
73.0
(26%-13 8%)
3701-2,3,7,8-TCDD
298
231
Pg/g
129
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 5996_2
Lab Sample ID: 5996004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/14/2014 13:25
04/15/201411:15
Project: TETR00114
Matrix: SOLID
%Moisture: 18.1
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-15
25687
04/17/2014 14:01
bl5aprl4b_6-2
25685
15-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.02 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
17400
Pg/g
22.9 120
40321-76-4
1,2,3,7,8-PeCDD
U
23.5
Pg/g
23.5 598
39227-28-6
1,2,3,4,7,8-HxCDD
u
31.1
Pg/g
31.1 598
57653-85-7
1,2,3,6,7,8-HxCDD
J
150
Pg/g
32.8 598
19408-74-3
1,2,3,7,8,9-HxCDD
J
49.1
Pg/g
33.0 598
35822-46-9
1,2,3,4,6,7,8-HpCDD
1100
Pg/g
42.4 598
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7790
Pg/g
144 1200
51207-31-9
2,3,7,8-TCDF
J
106
Pg/g
35.7 120
57117-41-6
1,2,3,7,8-PeCDF
u
20
Pg/g
20.0 598
57117-31-4
2,3,4,7,8-PeCDF
u
21.2
Pg/g
21.2 598
70648-26-9
1,2,3,4,7,8-HxCDF
u
19
Pg/g
19.0 598
57II7.44.9
1,2,3,6,7,8-HxCDF
u
17.7
Pg/g
17.7 598
60851-34-5
2,3,4,6,7,8-HxCDF
J
20.2
Pg/g
18.9 598
72918-21-9
1,2,3,7,8,9-HxCDF
u
24.2
Pg/g
24.2 598
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
235
Pg/g
33.7 598
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
52.9
Pg/g
52.9 598
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
375
Pg/g
57.4 1200
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2220
2390
Pg/g
92.9
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2150
2390
Pg/g
89.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2080
2390
Pg/g
86.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1990
2390
Pg/g
83.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1940
2390
Pg/g
81.2
(23%-140%)
13C-OCDD
3810
4790
Pg/g
79.6
(17%-157%)
13C-2,3,7,8-TCDF
2170
2390
Pg/g
90.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
2180
2390
Pg/g
91.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
2200
2390
Pg/g
92.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1920
2390
Pg/g
80.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1920
2390
Pg/g
80.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1990
2390
Pg/g
83.3
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1780
2390
Pg/g
74.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1990
2390
Pg/g
83.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1850
2390
Pg/g
77.3
(26%-13 8%)
3701-2,3,7,8-TCDD
350
239
Pg/g
146
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
5996 2
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
5996005
Date Collected:
04/14/2014 13:35
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/15/201411:15
%Moisture:
20.1
Client ID:
SFRA-16
Prep Basis:
Dry Weight
Batch ID:
25687
Method:
EPA Method 1613B
Run Date:
04/17/2014 12:59
Analyst:
JTF
Instrument:
HRP750
Data File:
A17APR14A-6
Dilution:
1
Prep Batch:
25685
Prep Method:
SW846 3540C
Prep Date:
15-APR-14
Prep Aliquot:
1.25 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
24.0
Pg/g
2.50
10.0
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
5996 2
5996005
1613B Soil
SFRA-16
25687
04/17/2014 09:23
bl5aprl4b 5-11
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
04/14/2014 13:35
04/15/201411:15
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
20.1
Dry Weight
HRP763
1
Prep Batch:
25685
Prep Method:
SW846 3540C
Prep Date:
15-APR-14
Prep Aliquot:
1.25 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3710
Pg/g
3.46 10.0
40321-76-4
1,2,3,7,8-PeCDD
U
3.54
Pg/g
3.54 50.1
39227-28-6
1,2,3,4,7,8-HxCDD
u
11
Pg/g
11.0 50.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
15.0
Pg/g
11.4 50.1
19408-74-3
1,2,3,7,8,9-HxCDD
u
11.5
Pg/g
11.5 50.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
219
Pg/g
11.5 50.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
4430
Pg/g
72.5 100
51207-31-9
2,3,7,8-TCDF
24.3
Pg/g
5.83 10.0
57117-41-6
1,2,3,7,8-PeCDF
J
5.67
Pg/g
3.60 50.1
57117-31-4
2,3,4,7,8-PeCDF
u
3.56
Pg/g
3.56 50.1
70648-26-9
1,2,3,4,7,8-HxCDF
J
4.31
Pg/g
2.78 50.1
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.7
Pg/g
2.70 50.1
60851-34-5
2,3,4,6,7,8-HxCDF
J
4.16
Pg/g
2.72 50.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.88
Pg/g
3.88 50.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
44.1
Pg/g
5.37 50.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
9.25
Pg/g
9.25 50.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
77.8
Pg/g
8.43 100
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1860
2000
Pg/g
92.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1880
2000
Pg/g
93.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1510
2000
Pg/g
75.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1830
2000
Pg/g
91.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1690
2000
Pg/g
84.6
(23%-140%)
13C-OCDD
3440
4000
Pg/g
85.9
(17%-157%)
13C-2,3,7,8-TCDF
1780
2000
Pg/g
89.0
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1920
2000
Pg/g
95.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1850
2000
Pg/g
92.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1490
2000
Pg/g
74.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1640
2000
Pg/g
81.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1620
2000
Pg/g
81.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1460
2000
Pg/g
73.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1650
2000
Pg/g
82.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1620
2000
Pg/g
80.9
(26%-13 8%)
3701-2,3,7,8-TCDD
224
200
Pg/g
112
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 27
-------
Quality Control
Summary
Page 18 of 27
-------
( (ipc Fear Analytical LLC Report Date: April 18, 2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 5996_2
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010199
LCS for batch 25685
12010200
LCSD for batch 25685
12010198
MB for batch 25685
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
86.9
84.9
83.4
79.8
96.6
97.8
90.7
86.2
90.5
79.0
78.8
83.9
78.7
90.8
93.4
102
91.4
100
87.4
85.0
95.3
96.2
91.6
101
101
80.1
80.2
86.2
79.5
92.8
92.7
119
84.6
97.8
82.4
83.4
92.7
89.9
85.8
99.9
98.5
76.9
79.0
82.1
76.7
88.6
88.4
102
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
5996001
SFRA-12
13C-2,3,7,8-TCDD
85.9
(25%-164%)
Page 19 of 27
-------
( (ipc Fear Analytical LLC Report Date: April 18, 2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 5996_2
Matrix Type: SOLID
Sample ID Client ID
5996001 SFRA-12
5996002 SFRA-13
5996005 SFRA-16
5996003 SFRA-14
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
Recovery Acceptance
QUAL (%) Limits
92.7 (25%-181%)
76.5 (32%-141%)
80.6 (28%-130%)
83.9 (23%-140%)
82.3 (17%-15 7%)
88.6 (24%-169%)
97.1 (24%-185%)
96.6 (21%-178%)
72.0 (26%-152%)
75.4 (26%-123%)
76.6 (28%-13 6%)
69.1 (29%-147%)
82.3 (28%-143%)
78.4 (26%-13 8%)
106 (35%-197%)
81.8 (25%-164%)
92.6 (25%-181%)
80.6 (32%-141%)
88.9 (28%-130%)
86.0 (23%-140%)
94.2 (17%-15 7%)
84.3 (24%-169%)
95.9 (24%-185%)
95.4 (21%-178%)
78.3 (26%-152%)
86.3 (26%-123%)
85.1 (28%-13 6%)
74.8 (29%-147%)
88.4 (28%-143%)
89.0 (26%-13 8%)
106 (35%-197%)
92.7 (25%-164%)
93.8 (25%-181%)
75.3 (32%-141%)
91.2 (28%-130%)
84.6 (23%-140%)
85.9 (17%-15 7%)
89.0 (24%-169%)
95.7 (24%-185%)
92.2 (21%-178%)
74.5 (26%-152%)
81.9 (26%-123%)
81.0 (28%-13 6%)
73.2 (29%-147%)
82.2 (28%-143%)
80.9 (26%-13 8%)
112 (35%-197%)
80.6 D (25%-164%)
86.6 D (25%-181%)
Page 20 of 27
-------
Cape Fear Analytical LLC
Report Date: April 18, 2014
Hi-Res Dioxins/Furans
Surrogate Recovery Report
SDG Number: 5996_2
Matrix Type: SOLID
Page 3
of 3
Sample ID Client ID
Acceptance
Surrogate
QUAL (%)
Limits
13C-l,2,3,4,7,8-HxCDD
75.7
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
92.7
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
85.1
D
(23%-140%)
13C-OCDD
76.8
D
(17%-15 7%)
13C-2,3,7,8-TCDF
81.3
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
88.4
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
91.9
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
70.6
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
83.5
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
80.4
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
68.5
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
81.4
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
73.0
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
129
D
(35%-197%)
13C-2,3,7,8-TCDD
92.9
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
89.9
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
86.7
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
83.0
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
81.2
D
(23%-140%)
13C-OCDD
79.6
D
(17%-15 7%)
13C-2,3,7,8-TCDF
90.7
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
91.3
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
92.0
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
80.1
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
80.1
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
83.3
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
74.4
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
83.1
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
77.3
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
146
D
(35%-197%)
5996003
SFRA-14
5996004
SFRA-15
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 21 of 27
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Cape Fear Analytical LLC
Report Date: April 18, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/16/2014 18:09 Dilution: 1
Prep Batch ID:25685
Batch ID: 25687
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.1
105
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
107
107
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
100
100
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
106
106
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
108
108
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
104
104
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
206
103
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.9
94.5
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
102
102
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
101
101
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
103
103
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
106
106
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
105
105
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
111
111
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
102
102
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
204
102
63-170
SDG Number: 5996_2
Client ID: LCS for batch 25685
Lab Sample ID: 12010199
Instrument: HRP763
Analyst: JTF
Page
22 of 27
-------
Cape Fear Analytical LLC
Report Date: April 18, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/16/2014 18:56 Dilution: 1
Prep Batch ID:25685
Batch ID: 25687
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.4
107
67-158
1.40
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
104
104
70-142
2.79
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
95.7
95.7
70-164
4.58
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
102
102
76-134
3.46
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
102
102
64-162
5.73
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
99.3
99.3
70-140
4.57
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
201
101
78-144
2.22
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.0
89.8
75-158
5.15
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
104
104
80-134
2.15
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
101
101
68-160
0.292
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
103
103
72-134
0.265
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
106
106
84-130
0.285
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
103
103
70-156
2.14
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
112
112
78-130
0.511
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
97.1
97.1
82-122
4.26
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
99.1
99.1
78-138
3.36
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
201
100
63-170
1.79
0-20
SDG Number: 5996_2
Client ID: LCSD for batch 25685
Lab Sample ID: 12010200
Instrument: HRP763
Analyst: JTF
Page
23 of 27
-------
Cape Fear Analytical LLC
Report Date: April 18, 2014
Method Blank Summary Page ' °' '
SDG Number:
5996 2
Client:
TETR001
Matrix:
SOLID
Client ID:
MB for batch 25685
Instrument ID:
HRP763
Data File:
bl5aprl4b 4-8
Lab Sample ID:
Column:
12010198
Prep Date:
15-APR-14
Analyzed:
04/16/14 19:44
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01 LCS for batch 25685
12010199
bl5aprl4b 4-6
04/16/14
1809
02 LCSD for batch 25685
12010200
bl5aprl4b_4-7
04/16/14
1856
03 SFRA-12
5996001
bl5aprl4b_4-9
04/16/14
2032
04 SFRA-13
5996002
bl5aprl4b_4-10
04/16/14
2120
05 SFRA-16
5996005
bl5aprl4b_5-ll
04/17/14
0923
06 SFRA-14
5996003
bl5aprl4b_5-12
04/17/14
1011
07 SFRA-13
5996002
A17APR14A-5
04/17/14
1239
08 SFRA-16
5996005
A17APR14A-6
04/17/14
1259
09 SFRA-15
5996004
bl5aprl4b_6-2
04/17/14
1401
Page 24 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5996_2
Lab Sample ID: 12010198
Client Sample: ^or batch 25685
Client ID: MB for batch 25685
Batch ID: 25687
Run Date: 04/16/2014 19:44
Data File: bl5aprl4b_4-8
Prep Batch: 25685
Prep Date: 15-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.226
Pg/g
0.226 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.206
Pg/g
0.206 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.244
Pg/g
0.244 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.254
Pg/g
0.254 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.256
Pg/g
0.256 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.364
Pg/g
0.364 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
1.07
Pg/g
0.928 10.0
51207-31-9
2,3,7,8-TCDF
u
.254
Pg/g
0.254 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.157
Pg/g
0.157 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.145
Pg/g
0.145 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.143
Pg/g
0.143 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.142
Pg/g
0.142 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.149
Pg/g
0.149 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.208
Pg/g
0.208 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.191
Pg/g
0.191 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.312
Pg/g
0.312 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.546
Pg/g
0.546 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
169
200
Pg/g
84.6
(25 %-164%)
130-1,2,3,7,8-
PeCDD
196
200
Pg/g
97.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
165
200
Pg/g
82.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
167
200
Pg/g
83.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
185
200
Pg/g
92.7
(23%-140%)
13C-OCDD
359
400
Pg/g
89.9
(17%-157%)
13C-2,3,7,8-TCDF
172
200
Pg/g
85.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
200
200
Pg/g
99.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
197
200
Pg/g
98.5
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
154
200
Pg/g
76.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
158
200
Pg/g
79.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
164
200
Pg/g
82.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
153
200
Pg/g
76.7
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
177
200
Pg/g
88.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
177
200
Pg/g
88.4
(26%-13 8%)
3701-2,3,7,8-TCDD
20.4
20.0
Pg/g
102
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 25 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 5996_2
Lab Sample ID: 12010199
Client Sample: ^or batch 25685
Client ID: LCS for batch 25685
Batch ID: 25687
Run Date: 04/16/2014 18:09
Data File: bl5aprl4b_4-6
Prep Batch: 25685
Prep Date: 15-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.1
Pg/g
0.718 1.00
40321-76-4
1,2,3,7,8-PeCDD
107
Pg/g
0.748 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
100
Pg/g
0.750 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
106
Pg/g
0.770 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
108
Pg/g
0.784 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
104
Pg/g
1.05 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
206
Pg/g
2.10 10.0
51207-31-9
2,3,7,8-TCDF
18.9
Pg/g
0.908 1.00
57117-41-6
1,2,3,7,8-PeCDF
102
Pg/g
0.740 5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.734 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
103
Pg/g
0.762 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
106
Pg/g
0.730 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
105
Pg/g
0.742 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
111
Pg/g
1.07 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
0.760 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
102
Pg/g
1.14 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
204
Pg/g
1.95 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
174
200
Pg/g
86.9
(20%-175%)
13C-1,2,3,7,8-
PeCDD
170
200
Pg/g
84.9
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
167
200
Pg/g
83.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
160
200
Pg/g
79.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
193
200
Pg/g
96.6
(22%-166%)
13C-OCDD
391
400
Pg/g
97.8
(13%-199%)
13C-2,3,7,8-TCDF
181
200
Pg/g
90.7
(22%-152%)
13C-1,2,3,7,8-
PeCDF
172
200
Pg/g
86.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
181
200
Pg/g
90.5
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
158
200
Pg/g
79.0
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
158
200
Pg/g
78.8
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
168
200
Pg/g
83.9
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
157
200
Pg/g
78.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
182
200
Pg/g
90.8
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
187
200
Pg/g
93.4
(20%-186%)
3701-2,3,7,8-TCDD
20.4
20.0
Pg/g
102
(31 %-191%)
Comments:
Page 26 of 27
-------
Cape Fear Analytical LLC
Report Date:
April 18, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
5996 2
12010200
QC for batch 25685
LCSD for batch 25685
25687
04/16/2014 18:56
bl5aprl4b 4-7
25685
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
15-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
21.4
Pg/g
0.424
1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.616
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
95.7
Pg/g
0.580
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
0.594
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
102
Pg/g
0.606
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.3
Pg/g
0.946
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
201
Pg/g
2.32
10.0
51207-31-9
2,3,7,8-TCDF
18.0
Pg/g
0.390
1.00
57117-41-6
1,2,3,7,8-PeCDF
104
Pg/g
0.850
5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.814
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
103
Pg/g
0.658
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
106
Pg/g
0.650
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
103
Pg/g
0.672
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
112
Pg/g
0.964
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
97.1
Pg/g
0.862
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.1
Pg/g
1.48
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
201
Pg/g
1.91
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
183
200
Pg/g
91.4
(20%-175%)
13C-1,2,3,7,8-PeCDD
201
200
Pg/g
100
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
175
200
Pg/g
87.4
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
170
200
Pg/g
85.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
191
200
Pg/g
95.3
(22%-166%)
13C-OCDD
385
400
Pg/g
96.2
(13%-199%)
13C-2,3,7,8-TCDF
183
200
Pg/g
91.6
(22%-152%)
13C-1,2,3,7,8-PeCDF
202
200
Pg/g
101
(21%-192%)
13C-2,3,4,7,8-PeCDF
202
200
Pg/g
101
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
160
200
Pg/g
80.1
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
160
200
Pg/g
80.2
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
172
200
Pg/g
86.2
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
159
200
Pg/g
79.5
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
186
200
Pg/g
92.8
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
185
200
Pg/g
92.7
(20%-186%)
37Cl-2,3,7,8-TCDD
23.9
20.0
Pg/g
119
(31 %-191%)
Comments:
Page 27 of 27
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 22. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6005
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 17, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of22
problem solved
-------
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jjAjjL-
/
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
TT,tK
Work Order:
(o 005
Received By:
Date/Time Received:
{lAr-^.in IQ2-Q
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
u
V
Samples identified as Foreign Soil?
C"
DOE Site Sample Packages
Yes
NA
No*
Screened <0.5 mR/hr?
L^
Samples < 2x background? ;
* Notify RSO of any responses ih this column immediately.
Page 3 of22
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 22
-------
Case Narrative
Page 5 of22
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6005
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25708
Clean Up Batch Number: 25707
Extraction Batch Number: 25706
Sample Analysis
The following samples were analyzed using the analytical protocol as established in
Sample ID Client ID
6005001 SFRA-17
6005002 SFRA-18
12010223 Method Blank (MB)
12010224 Laboratory Control Sample (LCS)
12010225 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of 22
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed on all samples in this
work order due to the high levels of target analytes that may be present.
Sample Dilutions
Sample 6005002 (SFRA-18)- Batch 25708 was diluted due to the presence of over-range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Page 7 of22
-------
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 22
-------
Sample Data Summary
Page 9 of 22
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6005 CFA Work Order: 6005
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 22 APR 2014 Title: Data Validator
Page 10 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6005
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6005001
Date Collected:
04/16/2014 15:47
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
04/17/2014 10:20
%Moisture: 19.2
Client ID:
SFRA-17
Prep Basis: Dry Weight
Batch ID:
25708
Method:
EPA Method 1613B
Run Date:
04/19/2014 00:03
Analyst:
JTF
Instrument: HRP763
Data File:
bl5aprl4b_9-4
Dilution: 1
Prep Batch:
25706
Prep Method:
SW846 3540C
Prep Date:
17-APR-14
Prep Aliquot:
1.12 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
4.46
Pg/g
4.46 11.0
40321-76-4
1,2,3,7,8-PeCDD
u
2.98
Pg/g
2.98 55.2
39227-28-6
1,2,3,4,7,8-HxCDD
u
4.51
Pg/g
4.51 55.2
57653-85-7
1,2,3,6,7,8-HxCDD
u
4.75
Pg/g
4.75 55.2
19408-74-3
1,2,3,7,8,9-HxCDD
u
4.77
Pg/g
4.77 55.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
60.6
Pg/g
11.8 55.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
2810
Pg/g
33.8 110
51207-31-9
2,3,7,8-TCDF
u
1.91
Pg/g
1.91 11.0
57117-41-6
1,2,3,7,8-PeCDF
u
2.01
Pg/g
2.01 55.2
57117-31-4
2,3,4,7,8-PeCDF
u
2.04
Pg/g
2.04 55.2
70648-26-9
1,2,3,4,7,8-HxCDF
u
3.23
Pg/g
3.23 55.2
57II7.44.9
1,2,3,6,7,8-HxCDF
u
3.14
Pg/g
3.14 55.2
60851-34-5
2,3,4,6,7,8-HxCDF
u
3.27
Pg/g
3.27 55.2
72918-21-9
1,2,3,7,8,9-HxCDF
u
4.9
Pg/g
4.90 55.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
4.84
Pg/g
4.84 55.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
7.67
Pg/g
7.67 55.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
7.84
Pg/g
7.84 110
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1770
2210
Pg/g
80.2
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1870
2210
Pg/g
84.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1620
2210
Pg/g
73.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1810
2210
Pg/g
81.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1690
2210
Pg/g
76.5
(23%-140%)
13C-OCDD
3110
4420
Pg/g
70.3
(17%-157%)
13C-2,3,7,8-TCDF
1870
2210
Pg/g
84.7
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1930
2210
Pg/g
87.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1920
2210
Pg/g
86.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1500
2210
Pg/g
67.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1750
2210
Pg/g
79.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1700
2210
Pg/g
77.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1540
2210
Pg/g
69.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1690
2210
Pg/g
76.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1630
2210
Pg/g
73.6
(26%-13 8%)
3701-2,3,7,8-TCDD
214
221
Pg/g
96.6
(35%-197%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6005
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6005002
Date Collected:
04/16/2014 15:55
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/17/2014 10:20
%Moisture:
18.5
Client ID:
SFRA-18
Prep Basis:
Dry Weight
Batch ID:
25708
Method:
EPA Method 1613B
Run Date:
04/21/2014 11:02
Analyst:
JTF
Instrument:
HRP750
Data File:
A21APR14A-4
Dilution:
2
Prep Batch:
25706
Prep Method:
SW846 3540C
Prep Date:
17-APR-14
Prep Aliquot:
1.13 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
40.1
Pg/g
14.7
21.7
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6005
6005002
1613B Soil
SFRA-18
25708
04/21/2014 14:35
b21aprl4a-3
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
04/16/2014 15:55
04/17/2014 10:20
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
18.5
Dry Weight
HRP763
2
Prep Batch:
25706
Prep Method:
SW846 3540C
Prep Date:
17-APR-14
Prep Aliquot:
1.13 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
4830
Pg/g
10.1 21.7
40321-76-4
1,2,3,7,8-PeCDD
U
5.97
Pg/g
5.97 109
39227-28-6
1,2,3,4,7,8-HxCDD
u
13
Pg/g
13.0 109
57653-85-7
1,2,3,6,7,8-HxCDD
J
15.7
Pg/g
12.3 109
19408-74-3
1,2,3,7,8,9-HxCDD
u
12.9
Pg/g
12.9 109
35822-46-9
1,2,3,4,6,7,8-HpCDD
286
Pg/g
20.9 109
3268-87-9
1,2,3,4,6,7,8,9-OCDD
2890
Pg/g
121 217
51207-31-9
2,3,7,8-TCDF
35.7
Pg/g
11.9 21.7
57117-41-6
1,2,3,7,8-PeCDF
J
18.1
Pg/g
8.53 109
57117-31-4
2,3,4,7,8-PeCDF
u
8.79
Pg/g
8.79 109
70648-26-9
1,2,3,4,7,8-HxCDF
u
8.68
Pg/g
8.68 109
57II7.44.9
1,2,3,6,7,8-HxCDF
u
7.97
Pg/g
7.97 109
60851-34-5
2,3,4,6,7,8-HxCDF
u
8.92
Pg/g
8.92 109
72918-21-9
1,2,3,7,8,9-HxCDF
u
13.3
Pg/g
13.3 109
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
71.5
Pg/g
8.75 109
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
16.9
Pg/g
16.9 109
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
145
Pg/g
70.8 217
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1690
2170
Pg/g
77.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1780
2170
Pg/g
82.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1360
2170
Pg/g
62.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1800
2170
Pg/g
83.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1540
2170
Pg/g
70.9
(23%-140%)
13C-OCDD
2540
4340
Pg/g
58.5
(17%-157%)
13C-2,3,7,8-TCDF
1800
2170
Pg/g
83.0
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1900
2170
Pg/g
87.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1860
2170
Pg/g
85.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1340
2170
Pg/g
61.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1770
2170
Pg/g
81.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1680
2170
Pg/g
77.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1540
2170
Pg/g
71.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1670
2170
Pg/g
77.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1430
2170
Pg/g
65.8
(26%-13 8%)
3701-2,3,7,8-TCDD
215
217
Pg/g
98.9
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 22
-------
Quality Control
Summary
Page 14 of 22
-------
( (ipc Fear Analytical LLC Report Date: April 22, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6005
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010224
LCS for batch 25706
12010225
LCSD for batch 25706
12010223
MB for batch 25706
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
81.8
86.6
71.4
79.3
80.9
77.2
84.1
85.9
87.1
65.2
72.5
74.7
67.2
76.2
79.3
98.9
79.3
84.1
78.1
84.1
87.4
85.4
82.2
83.3
85.2
71.6
82.0
80.5
70.5
83.7
84.3
98.7
73.4
79.8
64.6
76.8
70.5
67.4
77.5
81.3
81.3
60.5
70.9
69.2
62.9
69.9
67.3
90.7
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6005001
SFRA-17
13C-2,3,7,8-TCDD
(25%-164%)
Page 15 of 22
-------
( (ipc Fear Analytical LLC Report Date: April 22, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6005
Matrix Type: SOLID
Sample ID Client ID
6005001 SFRA-17
6005002 SFRA-18
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
84.8
(25%-181%)
73.5
(32%-141%)
81.9
(28%-130%)
76.5
(23%-140%)
70.3
(17%-15 7%)
84.7
(24%-169%)
87.2
(24%-185%)
86.9
(21%-178%)
67.9
(26%-152%)
79.0
(26%-123%)
77.2
(28%-13 6%)
69.9
(29%-147%)
76.5
(28%-143%)
73.6
(26%-13 8%)
96.6
(35%-197%)
77.7
D
(25%-164%)
82.0
D
(25%-181%)
62.4
D
(32%-141%)
83.1
D
(28%-130%)
70.9
D
(23%-140%)
58.5
D
(17%-15 7%)
83.0
D
(24%-169%)
87.6
D
(24%-185%)
85.7
D
(21%-178%)
61.7
D
(26%-152%)
81.4
D
(26%-123%)
77.2
D
(28%-13 6%)
71.1
D
(29%-147%)
77.0
D
(28%-143%)
65.8
D
(26%-13 8%)
98.9
D
(35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 16 of 22
-------
Cape Fear Analytical LLC
Report Date: April 22, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/18/2014 21:41 Dilution: 1
Prep Batch ID:25706
Batch ID: 25708
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.0
99.9
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
103
103
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
96.3
96.3
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
102
102
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
106
106
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
99.1
99.1
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
201
101
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.0
95.2
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
103
103
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
104
104
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
105
105
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
108
108
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
105
105
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
112
112
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
103
103
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
99.0
99
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
207
103
63-170
SDG Number: 6005
Client ID: LCS for batch 25706
Lab Sample ID: 12010224
Instrument: HRP763
Analyst: JTF
Page 17 of 22
-------
Cape Fear Analytical LLC
Report Date: April 22, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/18/2014 22:28 Dilution: 1
Prep Batch ID:25706
Batch ID: 25708
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.2
106
67-158
5.81
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
104
104
70-142
0.729
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
96.0
96
70-164
0.287
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
104
104
76-134
1.91
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
104
104
64-162
2.27
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
102
102
70-140
3.24
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
198
98.8
78-144
1.97
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.7
93.6
75-158
1.62
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
102
102
80-134
1.00
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
105
105
68-160
0.722
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
104
104
72-134
1.25
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
105
105
84-130
2.71
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
106
106
70-156
1.26
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
113
113
78-130
1.00
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
102
102
82-122
0.327
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
100
100
78-138
1.45
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
208
104
63-170
0.494
0-20
SDG Number: 6005
Client ID: LCSD for batch 25706
Lab Sample ID: 12010225
Instrument: HRP763
Analyst: JTF
Page
18 of 22
-------
Cape Fear Analytical LLC
Report Date: April 22, 2014
Method Blank Summary Page ' °' '
SDG Number: 6005
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 25706
Instrument ID:
HRP763
Data File:
bl5aprl4b 9-3
Lab Sample ID: 12010223
Column:
Prep Date:
17-APR-14
Analyzed:
04/18/14 23:15
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01 LCS for batch 25706
12010224
bl5aprl4b_9-l
04/18/14
2141
02 LCSD for batch 25706
12010225
bl5aprl4b_9-2
04/18/14
2228
03 SFRA-17
6005001
bl5aprl4b_9-4
04/19/14
0003
04 SFRA-18
6005002
A21APR14A-4
04/21/14
1102
05 SFRA-18
6005002
b21aprl4a-3
04/21/14
1435
Page 19 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6005
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 12010223
Matrix:
SOLID
Client Sample: ^or batch 25706
Client ID:
MB for batch 25706
Prep Basis:
As Received
Batch ID:
25708
Method:
EPA Method 1613B
Run Date:
04/18/2014 23:15
Analyst:
JTF
Instrument:
HRP763
Data File:
bl5aprl4b_9-3
Dilution:
1
Prep Batch:
25706
Prep Method:
SW846 3540C
Prep Date:
17-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.188
Pg/g
0.188
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.266
Pg/g
0.266
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.372
Pg/g
0.372
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.392
Pg/g
0.392
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.392
Pg/g
0.392
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.65
Pg/g
0.650
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
3.65
Pg/g
0.864
10.0
51207-31-9
2,3,7,8-TCDF
u
.147
Pg/g
0.147
1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.202
Pg/g
0.202
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.196
Pg/g
0.196
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.264
Pg/g
0.264
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.264
Pg/g
0.264
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.266
Pg/g
0.266
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.398
Pg/g
0.398
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.536
Pg/g
0.468
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.8
Pg/g
0.800
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
0.968
Pg/g
0.768
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
147
200
Pg/g
73.4
(25 %-164%)
13C-1,2,3,7,8-PeCDD
160
200
Pg/g
79.8
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
129
200
Pg/g
64.6
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
154
200
Pg/g
76.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
141
200
Pg/g
70.5
(23%-140%)
13C-OCDD
270
400
Pg/g
67.4
(17%-157%)
13C-2,3,7,8-TCDF
155
200
Pg/g
77.5
(24%-169%)
13C-1,2,3,7,8-PeCDF
163
200
Pg/g
81.3
(24%-185%)
13C-2,3,4,7,8-PeCDF
163
200
Pg/g
81.3
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
121
200
Pg/g
60.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
142
200
Pg/g
70.9
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
138
200
Pg/g
69.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
126
200
Pg/g
62.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
140
200
Pg/g
69.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
135
200
Pg/g
67.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
18.1
20.0
Pg/g
90.7
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 20 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6005
Lab Sample ID: 12010224
Client Sample: ^or batch 25706
Client ID: LCS for batch 25706
Batch ID: 25708
Run Date: 04/18/2014 21:41
Data File: bl5aprl4b_9-l
Prep Batch: 25706
Prep Date: 17-APR-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.0
Pg/g
0.270 1.00
40321-76-4
1,2,3,7,8-PeCDD
103
Pg/g
0.464 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
96.3
Pg/g
0.608 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
0.624 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
106
Pg/g
0.634 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.1
Pg/g
0.874 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
201
Pg/g
2.14 10.0
51207-31-9
2,3,7,8-TCDF
19.0
Pg/g
0.244 1.00
57117-41-6
1,2,3,7,8-PeCDF
103
Pg/g
0.612 5.00
57117-31-4
2,3,4,7,8-PeCDF
104
Pg/g
0.618 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
105
Pg/g
0.778 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
108
Pg/g
0.726 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
105
Pg/g
0.744 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
112
Pg/g
1.16 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
103
Pg/g
0.742 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.0
Pg/g
1.10 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
207
Pg/g
2.82 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
164
200
Pg/g
81.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
173
200
Pg/g
86.6
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
143
200
Pg/g
71.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
159
200
Pg/g
79.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
162
200
Pg/g
80.9
(22%-166%)
13C-OCDD
309
400
Pg/g
77.2
(13%-199%)
13C-2,3,7,8-TCDF
168
200
Pg/g
84.1
(22%-152%)
13C-1,2,3,7,8-
PeCDF
172
200
Pg/g
85.9
(21%-192%)
130-2,3,4,7,8-
PeCDF
174
200
Pg/g
87.1
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
130
200
Pg/g
65.2
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
145
200
Pg/g
72.5
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
149
200
Pg/g
74.7
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
134
200
Pg/g
67.2
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
152
200
Pg/g
76.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
159
200
Pg/g
79.3
(20%-186%)
3701-2,3,7,8-TCDD
19.8
20.0
Pg/g
98.9
(31 %-191%)
Comments:
Page 21 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6005
12010225
QC for batch 25706
LCSD for batch 25706
25708
04/18/2014 22:28
bl5aprl4b 9-2
25706
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
17-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
21.2
Pg/g
0.258
1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.430
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
96.0
Pg/g
0.710
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
104
Pg/g
0.708
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
104
Pg/g
0.728
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
102
Pg/g
0.888
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
198
Pg/g
3.12
10.0
51207-31-9
2,3,7,8-TCDF
18.7
Pg/g
0.282
1.00
57117-41-6
1,2,3,7,8-PeCDF
102
Pg/g
0.480
5.00
57117-31-4
2,3,4,7,8-PeCDF
105
Pg/g
0.474
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
104
Pg/g
0.924
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
105
Pg/g
0.900
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
106
Pg/g
0.934
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
113
Pg/g
1.46
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
102
Pg/g
0.918
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
100
Pg/g
1.48
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
208
Pg/g
2.38
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
159
200
Pg/g
79.3
(20%-175%)
13C-1,2,3,7,8-PeCDD
168
200
Pg/g
84.1
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
156
200
Pg/g
78.1
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
168
200
Pg/g
84.1
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
175
200
Pg/g
87.4
(22%-166%)
13C-OCDD
342
400
Pg/g
85.4
(13%-199%)
13C-2,3,7,8-TCDF
164
200
Pg/g
82.2
(22%-152%)
13C-1,2,3,7,8-PeCDF
167
200
Pg/g
83.3
(21%-192%)
13C-2,3,4,7,8-PeCDF
170
200
Pg/g
85.2
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
143
200
Pg/g
71.6
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
164
200
Pg/g
82.0
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
161
200
Pg/g
80.5
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
141
200
Pg/g
70.5
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
167
200
Pg/g
83.7
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
169
200
Pg/g
84.3
(20%-186%)
37Cl-2,3,7,8-TCDD
19.7
20.0
Pg/g
98.7
(31 %-191%)
Comments:
Page 22 of 22
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 23. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6010
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 18, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of21
problem solved
-------
^Ti^wL TccA
CHAIN OF CUSTODY RECORD
ENVIRONMENTAL PROTECTION AGENCY REGION VII
ffaur Et^sL
ACTIVITY LEADER(Print) NAME OF SURVEY OR ACTIVITY
tftesi~k- Saitfij, Daya. Eifinsfk SlT'tefcir ~fpr/V/-
OK
CT^OF CO^ECTION f ij
DAY MONTH YEAR
"SSeET
uaz
CONTENTS OF SHIPMENT
SAMPLE
NUMBER
/ TYPE OF CONTAINERS
SAMPLED ME05A
RECEIVING LABORATORY
REMARKS/OTHER INFORMATION
(condition o) samples upon receipt,
other sample numbers, etc.)
GUB1TAINER
*4 9%r.
BOTTLE BOTTLE
BOTTLE
VOA SET
(2 VIALS EA)
water
o
as
E
T3
«
3
other
NUMBERS OF CONTAINERS PER SAMPLE NUMBER
SFRlW?
X
t
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PIECE(S) CONSISTING OF.
J_ ICE CHEST(S); OTHER
. BOX(ES)
Ji_COMMERCIAL CARRIER:. ,
—C0URIER 1 ?&it V57
-SAMPLER CONVEYED
(SHIPPING DOCUMENT NUMBER)
PERSONNEL CUSTODY RECORD
RELINQUISHED BY (SAMPLER)
DATE
h/h/h
TIME
W5
RECEIVED BY
""[SEALED . L
100-0
UNSEALED ["
REASON FOR CHANGE OF CUSTODY
RELINQUISHED BY
DATE
TIME
"~1 SEALED
UNSEALED r*
RECEIVED BY
SEALED
REASON FOR CHANGE OF CUSTODY
UNSEALED j~
RELINQUISHED BY
DATE
TIME
~
SEALED
UNSEALEC>[~
RECEIVED BY
*~I SEALED
REASON FOR CHANGE OF CUSTODY
UNSEALEDr
?-EPA-9262(RpapJ2/gp2l
•U.S. GPO: 2002-756-917/40053
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
Work Order: 1 (j?0| (~J
Received By: (aayj^l
Date/Time Received: ( Q
Suspected Hazard Information
| Yes
NA
No
DOE Site Sample Packages;
Yes
NA
No*
Shipped as DOT Hazardous? [
Screened <0.5 mR/hr?
o-'
Samples identified as Foreign Soil? |
Samples < 2x background?
* Notify RSO of any responsesiin this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and seated?
/
Circle Appiicsbte;
sesfe broken rfsmaged container ieaking contsinei otherfdesrifibe]
2
Chain of Custody documents included
with shipment?
3
Samples requiring cold preservation
within Q-6°C?
V
/
c
Method
ice bsgsf blue ke dry ice none other (describe)
3.i'C
4
Samples requiring chemical
preservation at proper pH?
Sample !0i, container* effected and pH observed:
H preservative added, Lot*
5
Samples requiring preservation have
no residua] chlorine?
/
Sample IDs, containers effected:
!f preservative added. lor*:
6
Samples received within holding time?
Sample ID*, tests affected:
7
Sample IDs on COC match IDs on
containers?
x/
Sarnple 10s, com sine r< effected: '
8
Date & time of COC match date & time
on containers?
t/
/uxf tndM &MiJL
9
Number of containers received match
number indicated on COC?
•
k/
Sample ID«, containers affected:
J
10
COC form is properly signed in
relinquished/received sections?
/
Comments:
Checklist performed by; initials: Date: ($
Page 3 of21
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of21
-------
Case Narrative
Page 5 of21
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6010
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25712
Clean Up Batch Number: 25711
Extraction Batch Number: 25710
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6010001 SFRA-19
12010227 Method Blank (MB)
12010228 Laboratory Control Sample (LCS)
12010229 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of21
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
Sample 6010001 (SFRA-19)- Batch 25712 was diluted due to the presence of over range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Page 7 of21
-------
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of21
-------
Sample Data Summary
Page 9 of21
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6010 CFA Work Order: 6010
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 23 APR 2014 Title: Data Validator
Page 10 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6010
Lab Sample ID: 6010001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/17/2014 16:20
04/18/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 19.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-19
25712
04/22/2014 10:41
b21aprl4a_2-13
25710
20-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.15 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 2
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
4540
Pg/g
9.75 21.7
40321-76-4
1,2,3,7,8-PeCDD
U
5.62
Pg/g
5.62 109
39227-28-6
1,2,3,4,7,8-HxCDD
u
8.73
Pg/g
8.73 109
57653-85-7
1,2,3,6,7,8-HxCDD
J
20.7
Pg/g
9.03 109
19408-74-3
1,2,3,7,8,9-HxCDD
u
9.12
Pg/g
9.12 109
35822-46-9
1,2,3,4,6,7,8-HpCDD
396
Pg/g
29.7 109
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5800
Pg/g
68.4 217
51207-31-9
2,3,7,8-TCDF
28.5
Pg/g
7.80 21.7
57117-41-6
1,2,3,7,8-PeCDF
J
10.8
Pg/g
6.23 109
57117-31-4
2,3,4,7,8-PeCDF
u
6.25
Pg/g
6.25 109
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.90
Pg/g
4.80 109
57II7.44.9
1,2,3,6,7,8-HxCDF
u
4.6
Pg/g
4.60 109
60851-34-5
2,3,4,6,7,8-HxCDF
J
5.34
Pg/g
4.95 109
72918-21-9
1,2,3,7,8,9-HxCDF
u
7.88
Pg/g
7.88 109
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
77.6
Pg/g
6.69 109
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
12.2
Pg/g
12.2 109
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
215
Pg/g
34.3 217
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1840
2170
Pg/g
84.9
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2020
2170
Pg/g
93.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1640
2170
Pg/g
75.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1940
2170
Pg/g
89.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1650
2170
Pg/g
75.8
(23%-140%)
13C-OCDD
2990
4340
Pg/g
68.8
(17%-157%)
13C-2,3,7,8-TCDF
1980
2170
Pg/g
91.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1960
2170
Pg/g
90.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
1910
2170
Pg/g
87.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1530
2170
Pg/g
70.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1830
2170
Pg/g
84.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1750
2170
Pg/g
80.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1520
2170
Pg/g
70.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1710
2170
Pg/g
78.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1550
2170
Pg/g
71.4
(26%-13 8%)
3701-2,3,7,8-TCDD
247
217
Pg/g
114
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6010
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6010001
Date Collected:
04/17/2014 16:20
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/18/2014 10:00
%Moisture:
19.9
Client ID:
SFRA-19
Prep Basis:
Dry Weight
Batch ID:
25712
Method:
EPA Method 1613B
Run Date:
04/22/2014 15:01
Analyst:
JTF
Instrument:
HRP763
Data File:
b22aprl4b4
Dilution:
2
Prep Batch:
25710
Prep Method:
SW846 3540C
Prep Date:
20-APR-14
Prep Aliquot:
1.15 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
38.6
Pg/g
11.4
21.7
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 21
-------
Quality Control
Summary
Page 13 of 21
-------
( (ipc Fear Analytical LLC Report Date: April 22, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6010
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010228
LCS for batch 25710
12010229
LCSD for batch 25710
12010227
MB for batch 25710
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
73.9
82.8
62.2
76.2
66.6
63.3
80.2
82.8
81.2
59.8
74.5
70.3
65.1
67.5
61.2
96.4
72.7
80.4
62.6
78.2
71.6
65.1
82.7
81.6
80.7
62.7
75.4
71.2
65.3
70.2
67.4
98.3
83.2
91.6
69.6
82.7
72.7
64.9
89.1
92.9
89.9
66.2
81.9
75.0
69.7
71.3
62.7
104
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6010001
SFRA-19
13C-2,3,7,8-TCDD
84.9 D
(25%-164%)
Page 14 of 21
-------
Cape Fear Analytical LLC
Report Date: April 22, 2014
Hi-Res Dioxins/Furans
Surrogate Recovery Report
SDG Number: 6010
Matrix Type: SOLID
Page 2
of 2
Sample ID Client ID
Recovery Acceptance
Surrogate
QUAL (%)
Limits
13C-l,2,3,7,8-PeCDD
93.2
D
(25%-
¦181%)
13C-l,2,3,4,7,8-HxCDD
75.7
D
(32%-
¦141%)
13C-l,2,3,6,7,8-HxCDD
89.3
D
(28%-
¦130%)
13C-l,2,3,4,6,7,8-HpCDD
75.8
D
(23%-
¦140%)
13C-OCDD
68.8
D
(17%-
¦157%)
13C-2,3,7,8-TCDF
91.3
D
(24%-
¦169%)
13C-l,2,3,7,8-PeCDF
90.1
D
(24%-
¦185%)
13C-2,3,4,7,8-PeCDF
87.9
D
(21%-
¦178%)
13C-l,2,3,4,7,8-HxCDF
70.3
D
(26%-
¦152%)
13C-l,2,3,6,7,8-HxCDF
84.3
D
(26%-
¦123%)
13C-2,3,4,6,7,8-HxCDF
80.7
D
(28%-
¦136%)
13C-l,2,3,7,8,9-HxCDF
70.2
D
(29%-
¦147%)
13C-l,2,3,4,6,7,8-HpCDF
78.9
D
(28%-
¦143%)
13C-l,2,3,4,7,8,9-HpCDF
71.4
D
(26%-
¦138%)
37Cl-2,3,7,8-TCDD
114
D
(35%-
¦197%)
6010001
SFRA-19
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 15 of 21
-------
Cape Fear Analytical LLC
Report Date: April 22, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/21/2014 15:28 Dilution: 1
Prep Batch ID:25710
Batch ID: 25712
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.6
108
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
99.8
99.8
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
95.3
95.3
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
104
104
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
103
103
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
103
103
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
194
97
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.4
92.1
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
104
104
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
105
105
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
104
104
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
105
105
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
103
103
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
107
107
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
106
106
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
105
105
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
207
104
63-170
SDG Number: 6010
Client ID: LCS for batch 25710
Lab Sample ID: 12010228
Instrument: HRP763
Analyst: JTF
Page
16 of 21
-------
Cape Fear Analytical LLC
Report Date: April 22, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/21/2014 16:15 Dilution: 1
Prep Batch ID:25710
Batch ID: 25712
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
22.4
112
67-158
3.85
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
111
111
70-142
10.3
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
104
104
70-164
8.38
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
109
109
76-134
5.29
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
116
116
64-162
11.5
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
102
102
70-140
0.654
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
213
106
78-144
9.15
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.7
98.7
75-158
6.94
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
107
107
80-134
3.27
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
110
110
68-160
4.55
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
108
108
72-134
4.43
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
111
111
84-130
5.89
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
110
110
70-156
6.73
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
110
110
78-130
2.58
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
112
112
82-122
4.74
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
105
105
78-138
0.245
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
220
110
63-170
5.81
0-20
SDG Number: 6010
Client ID: LCSD for batch 25710
Lab Sample ID: 12010229
Instrument: HRP763
Analyst: JTF
Page
17 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6010
Client ID: MB for batch 25710
Lab Sample ID: 12010227
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: 20-APR-14
Matrix: SOLID
Data File: b21aprl4a-6
Analyzed: 04/21/1417:03
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 25710
12010228
b21aprl4a-4
04/21/14
1528
02
LCSD for batch 25710
12010229
b21aprl4a-5
04/21/14
1615
03
SFRA-19
6010001
b21aprl4a_2-13
04/22/14
1041
04
SFRA-19
6010001
b22aprl4b4
04/22/14
1501
Page 18 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6010
Lab Sample ID: 12010227
Client Sample: *or batch 25710
Client ID: MB for batch 25710
Batch ID: 25712
Run Date: 04/21/2014 17:03
Data File: b21aprl4a-6
Prep Batch: 25710
Prep Date: 20-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.192
Pg/g
0.192 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.208
Pg/g
0.208 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.318
Pg/g
0.318 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.322
Pg/g
0.322 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.328
Pg/g
0.328 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.45
Pg/g
0.450 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.708
Pg/g
0.708 10.0
51207-31-9
2,3,7,8-TCDF
u
.22
Pg/g
0.220 1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.166
Pg/g
0.160 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.154
Pg/g
0.154 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.196
Pg/g
0.196 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.184
Pg/g
0.184 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.206
Pg/g
0.206 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.324
Pg/g
0.324 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.212
Pg/g
0.212 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.384
Pg/g
0.384 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.692
Pg/g
0.692 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
166
200
Pg/g
83.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
183
200
Pg/g
91.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
139
200
Pg/g
69.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
165
200
Pg/g
82.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
145
200
Pg/g
72.7
(23%-140%)
13C-OCDD
259
400
Pg/g
64.9
(17%-157%)
13C-2,3,7,8-TCDF
178
200
Pg/g
89.1
(24%-169%)
130-1,2,3,7,8-
PeCDF
186
200
Pg/g
92.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
180
200
Pg/g
89.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
132
200
Pg/g
66.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
164
200
Pg/g
81.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
150
200
Pg/g
75.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
139
200
Pg/g
69.7
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
143
200
Pg/g
71.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
125
200
Pg/g
62.7
(26%-13 8%)
3701-2,3,7,8-TCDD
20.7
20.0
Pg/g
104
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6010
Lab Sample ID: 12010228
Client Sample: *or batch 25710
Client ID: LCS for batch 25710
Batch ID: 25712
Run Date: 04/21/2014 15:28
Data File: b21aprl4a-4
Prep Batch: 25710
Prep Date: 20-APR-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.6
Pg/g
0.406 1.00
40321-76-4
1,2,3,7,8-PeCDD
99.8
Pg/g
0.520 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
95.3
Pg/g
0.932 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
104
Pg/g
0.918 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
103
Pg/g
0.948 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
103
Pg/g
1.33 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
194
Pg/g
4.30 10.0
51207-31-9
2,3,7,8-TCDF
18.4
Pg/g
0.368 1.00
57117-41-6
1,2,3,7,8-PeCDF
104
Pg/g
0.618 5.00
57117-31-4
2,3,4,7,8-PeCDF
105
Pg/g
0.628 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
104
Pg/g
1.15 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
105
Pg/g
1.10 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
103
Pg/g
1.17 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
107
Pg/g
1.85 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
106
Pg/g
0.938 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
105
Pg/g
1.70 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
207
Pg/g
3.50 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
148
200
Pg/g
73.9
(20%-175%)
13C-1,2,3,7,8-
PeCDD
166
200
Pg/g
82.8
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
124
200
Pg/g
62.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
152
200
Pg/g
76.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
133
200
Pg/g
66.6
(22%-166%)
13C-OCDD
253
400
Pg/g
63.3
(13%-199%)
13C-2,3,7,8-TCDF
160
200
Pg/g
80.2
(22%-152%)
13C-1,2,3,7,8-
PeCDF
166
200
Pg/g
82.8
(21%-192%)
130-2,3,4,7,8-
PeCDF
162
200
Pg/g
81.2
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
120
200
Pg/g
59.8
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
149
200
Pg/g
74.5
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
141
200
Pg/g
70.3
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
130
200
Pg/g
65.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
135
200
Pg/g
67.5
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
122
200
Pg/g
61.2
(20%-186%)
3701-2,3,7,8-TCDD
19.3
20.0
Pg/g
96.4
(31 %-191%)
Comments:
Page 20 of 21
-------
Cape Fear Analytical LLC
Report Date:
April 22, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6010
12010229
QC for batch 25710
LCSD for batch 25710
25712
04/21/2014 16:15
b21aprl4a-5
25710
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
20-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
22.4
Pg/g
0.230
1.00
40321-76-4
1,2,3,7,8-PeCDD
111
Pg/g
0.544
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
104
Pg/g
0.888
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
109
Pg/g
0.856
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
116
Pg/g
0.892
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
102
Pg/g
1.21
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
213
Pg/g
4.34
10.0
51207-31-9
2,3,7,8-TCDF
19.7
Pg/g
0.244
1.00
57117-41-6
1,2,3,7,8-PeCDF
107
Pg/g
0.580
5.00
57117-31-4
2,3,4,7,8-PeCDF
110
Pg/g
0.604
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
108
Pg/g
0.868
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
111
Pg/g
0.810
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
110
Pg/g
0.880
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
110
Pg/g
1.41
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
112
Pg/g
0.806
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
105
Pg/g
1.44
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
220
Pg/g
2.84
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
145
200
Pg/g
72.7
(20%-175%)
13C-1,2,3,7,8-PeCDD
161
200
Pg/g
80.4
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
125
200
Pg/g
62.6
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
156
200
Pg/g
78.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
143
200
Pg/g
71.6
(22%-166%)
13C-OCDD
260
400
Pg/g
65.1
(13%-199%)
13C-2,3,7,8-TCDF
165
200
Pg/g
82.7
(22%-152%)
13C-1,2,3,7,8-PeCDF
163
200
Pg/g
81.6
(21%-192%)
13C-2,3,4,7,8-PeCDF
161
200
Pg/g
80.7
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
125
200
Pg/g
62.7
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
151
200
Pg/g
75.4
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
142
200
Pg/g
71.2
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
131
200
Pg/g
65.3
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
140
200
Pg/g
70.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
135
200
Pg/g
67.4
(20%-186%)
37Cl-2,3,7,8-TCDD
19.7
20.0
Pg/g
98.3
(31 %-191%)
Comments:
Page 21 of 21
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 25. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6023
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 22, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of25
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-------
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9262(Repagfe^f25
REASON FOR CHANGE OF CUSTODY
*U,S. GPO: 2002-756-917/40053
-------
SAMPLE RECEIPT CHECKLIST
Cope Fear Analytical
Cliem Tn^Tcth
Work Order: ($Q
R"eivedByHar^
Date/Time Received; ^ 2. | ^ ® /5
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
Samples identified as Foreign Soil?
DOE Site Sample Packages
Yes
NA | No*
Screened <0.5 mR/hr?
Samples < 2x background? 1
1
* Notify RSO of any responses In this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers {required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
/
Circle Applicable;
sesii broken damaged container leaking container ©rher{deseiiibe)
2
Chain of Custody documents included
with shipment?
3
Samples requiring cold preservation
within 0-6°C?
Pwservstkm Method:
Itebagh blue tee dry tee none other (describe)
r - O
J .2-
4
Samples requiring chemical
preservation at proper pH?
Sample IDs, containers a fleeted and pH observed:
If preservative sdded. totB;
5
Samples requiring preservation have
no residual chlorine?
^'
Sample IDs, containers ejected:
If prtservative added, lot#: j
6
Samples received within holding time?
Sample IDs, tests affected >
7
Sample IDs on COC match IDs on
containers?
Sample IDs,
-------
RE: CFAreceipt 22-APR-14
Subject: RE: CFA receipt 22-APR-14
From: Dave Kinroth
Date: 4/22/2014 2:58 PM
To: Cynde Larkins
Please proceed with the extraction and analysis.
G. David Kinroth, CHMM
Regional Manager
EPA Reg. 7 START Haz. Waste Specialist
Seagull Environmental Technologies, Inc.
Woman-Owned8(a) Firm
Phone/Fax: (314) 395-3157
Mobile: (314) 517-6798
Emails: dkinrothPseaaullenviroteeh.com
davekinfothgeharter.net
On Tue, Apr 22, 2014 at 11:11 AM, Cynde Larkins wrote:
Mr. Kinroth,
The samples arrived today in good condition. They were measured at 7.2°C, however.
We will need your permission to continue with extraction and analysis since they were
out of the recommended temperature range upon receipt.
Thank you,
Cynde Larkins
Project Manager Assistant
Cape Fear Analytical
3306 Kitty Hawk Road
Suite 120
Wilmington., NC 28405
(910) 795-0421
How was your customer experience? Customer service is a high priority for us, so we
listen to what our customers have to say! Thank you for taking time to email us your
thoughts and opinions at feeclbaek(3ef
CONFIDENTIALITY NOTICE: This e-mail and any files transmitted
with it are the property of Cape Fear Analytical, LLC. All
rights,including without limitation copyright,are reserved. The
proprietary information contained in this e-mail message,
and any files transmitted with it, is intended for the use of the
recipient(s) named above. If the reader of this e-mail is not the
intended recipient, you are hereby notified that you have
received this e-mail in error and that any review, distribution
or copying of this e-mail or any files transmitted with it is
strictly prohibited. If you have received this e-mail in error,
please notify the sender immediately and delete the original
message and any files transmitted. The unauthorized use of
this e-mail or any files transmitted with it is prohibited and
disclaimed by Cape Fear Analytical, LLC.
Page 4 of 25
lofl
4/22/2014 2:59 PM
-------
High Resolution Dioxins
and Furans Analysis
Page 5 of25
-------
Case Narrative
Page 6 of 25
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6023
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25730
Clean Up Batch Number: 25729
Extraction Batch Number: 25728
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6023001 SFRA-20
6023002 SFRA-21
6023003 SFRA-22
12010243 Method Blank (MB)
12010244 Laboratory Control Sample (LCS)
12010245 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 7 of25
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
Sample 6023001 (SFRA-20)- Batch 25730 was diluted due to the presence of over-range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 8 of 25
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 9 of 25
-------
Sample Data Summary
Page 10 of 25
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6023 CFA Work Order: 6023
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 25 APR 2014 Title: Data Validator
Page 11 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 25, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6023
Lab Sample ID: 6023001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/21/2014 15:55
04/22/2014 10:15
Project: TETR00114
Matrix: SOLID
%Moisture: 21.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-20
25730
04/24/2014 16:22
A24APR14B-5
25728
22-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
ii §
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 2
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
5830
Pg/g
3.54 23.1
40321-76-4
1,2,3,7,8-PeCDD
J
8.79
Pg/g
3.12 116
39227-28-6
1,2,3,4,7,8-HxCDD
J
26.9
Pg/g
5.09 116
57653-85-7
1,2,3,6,7,8-HxCDD
J
40.9
Pg/g
5.67 116
19408-74-3
1,2,3,7,8,9-HxCDD
J
20.9
Pg/g
5.71 116
35822-46-9
1,2,3,4,6,7,8-HpCDD
708
Pg/g
11.1 116
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8980
Pg/g
32.4 231
51207-31-9
2,3,7,8-TCDF
39.6
Pg/g
6.31 23.1
57117-41-6
1,2,3,7,8-PeCDF
J
46.0
Pg/g
5.76 116
57117-31-4
2,3,4,7,8-PeCDF
J
6.50
Pg/g
5.41 116
70648-26-9
1,2,3,4,7,8-HxCDF
J
17.3
Pg/g
4.21 116
57II7.44.9
1,2,3,6,7,8-HxCDF
J
10.2
Pg/g
4.07 116
60851-34-5
2,3,4,6,7,8-HxCDF
J
10.6
Pg/g
4.07 116
72918-21-9
1,2,3,7,8,9-HxCDF
U
6.43
Pg/g
6.43 116
67562-39-4
1,2,3,4,6,7,8-HpCDF
158
Pg/g
3.26 116
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
13.2
Pg/g
5.23 116
39001-02-0
1,2,3,4,6,7,8,9-OCDF
430
Pg/g
8.33 231
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1540
2310
Pg/g
66.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1650
2310
Pg/g
71.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1640
2310
Pg/g
70.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1580
2310
Pg/g
68.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1760
2310
Pg/g
76.2
(23%-140%)
13C-OCDD
3260
4630
Pg/g
70.5
(17%-157%)
13C-2,3,7,8-TCDF
1530
2310
Pg/g
66.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1540
2310
Pg/g
66.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
1660
2310
Pg/g
71.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1610
2310
Pg/g
69.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1490
2310
Pg/g
64.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1590
2310
Pg/g
68.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1400
2310
Pg/g
60.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1610
2310
Pg/g
69.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1590
2310
Pg/g
68.8
(26%-13 8%)
3701-2,3,7,8-TCDD
209
231
Pg/g
90.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 25, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6023
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6023001
Date Collected:
04/21/2014 15:55
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/22/2014 10:15
%Moisture:
21.4
Client ID:
SFRA-20
Prep Basis:
Dry Weight
Batch ID:
25730
Method:
EPA Method 1613B
Run Date:
04/25/2014 13:03
Analyst:
JTF
Instrument:
HRP750
Data File:
A25APR14C-4
Dilution:
2
Prep Batch:
25728
Prep Method:
SW846 3540C
Prep Date:
22-APR-14
Prep Aliquot:
11 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
42.5
Pg/g
4.97
23.1
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 25, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6023
Lab Sample ID: 6023002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/21/2014 16:30
04/22/2014 10:15
Project: TETR00114
Matrix: SOLID
%Moisture: 15.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-21
25730
04/24/2014 17:09
A24APR14B-6
25728
22-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.16 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1500
Pg/g
1.48 10.2
40321-76-4
1,2,3,7,8-PeCDD
U
2.96
Pg/g
2.96 51.0
39227-28-6
1,2,3,4,7,8-HxCDD
u
3.57
Pg/g
3.57 51.0
57653-85-7
1,2,3,6,7,8-HxCDD
J
9.98
Pg/g
3.98 51.0
19408-74-3
1,2,3,7,8,9-HxCDD
J
5.78
Pg/g
4.02 51.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
202
Pg/g
6.41 51.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5260
Pg/g
9.02 102
51207-31-9
2,3,7,8-TCDF
J
9.15
Pg/g
2.35 10.2
57117-41-6
1,2,3,7,8-PeCDF
u
1.39
Pg/g
1.39 51.0
57117-31-4
2,3,4,7,8-PeCDF
u
2.61
Pg/g
2.61 51.0
70648-26-9
1,2,3,4,7,8-HxCDF
J
3.06
Pg/g
1.66 51.0
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.27
Pg/g
2.27 51.0
60851-34-5
2,3,4,6,7,8-HxCDF
J
3.59
Pg/g
1.76 51.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.57
Pg/g
2.57 51.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
32.5
Pg/g
1.29 51.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
3.08
Pg/g
2.12 51.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
67.0
Pg/g
2.90 102
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1500
2040
Pg/g
73.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1560
2040
Pg/g
76.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1590
2040
Pg/g
77.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1530
2040
Pg/g
74.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1720
2040
Pg/g
84.3
(23%-140%)
13C-OCDD
3320
4080
Pg/g
81.3
(17%-157%)
13C-2,3,7,8-TCDF
1440
2040
Pg/g
70.4
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1490
2040
Pg/g
73.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1470
2040
Pg/g
71.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1510
2040
Pg/g
73.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1400
2040
Pg/g
68.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1480
2040
Pg/g
72.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1320
2040
Pg/g
64.5
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1560
2040
Pg/g
76.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1510
2040
Pg/g
74.0
(26%-13 8%)
3701-2,3,7,8-TCDD
186
204
Pg/g
91.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 25, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6023
Lab Sample ID: 6023003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/21/2014 16:40
04/22/2014 10:15
Project: TETR00114
Matrix: SOLID
%Moisture: 20.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-22
25730
04/25/2014 10:52
A25APR14A-3
25728
22-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.03 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
218
Pg/g
1.86 12.2
40321-76-4
1,2,3,7,8-PeCDD
U
3.12
Pg/g
3.12 60.9
39227-28-6
1,2,3,4,7,8-HxCDD
J
11.3
Pg/g
7.57 60.9
57653-85-7
1,2,3,6,7,8-HxCDD
84.5
Pg/g
8.16 60.9
19408-74-3
1,2,3,7,8,9-HxCDD
J
18.2
Pg/g
8.37 60.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
4020
Pg/g
17.3 60.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
45100
Pg/g
17.2 122
51207-31-9
2,3,7,8-TCDF
u
3.36
Pg/g
3.36 12.2
57117-41-6
1,2,3,7,8-PeCDF
J
11.3
Pg/g
3.55 60.9
57117-31-4
2,3,4,7,8-PeCDF
u
3.68
Pg/g
3.68 60.9
70648-26-9
1,2,3,4,7,8-HxCDF
J
16.7
Pg/g
5.23 60.9
57II7.44.9
1,2,3,6,7,8-HxCDF
u
5.19
Pg/g
5.19 60.9
60851-34-5
2,3,4,6,7,8-HxCDF
J
9.35
Pg/g
5.11 60.9
72918-21-9
1,2,3,7,8,9-HxCDF
u
7.4
Pg/g
7.40 60.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
624
Pg/g
6.57 60.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
67.6
Pg/g
10.4 60.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
4870
Pg/g
10.3 122
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1910
2430
Pg/g
78.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2030
2430
Pg/g
83.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1960
2430
Pg/g
80.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1870
2430
Pg/g
76.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2100
2430
Pg/g
86.5
(23%-140%)
13C-OCDD
4370
4870
Pg/g
89.7
(17%-157%)
13C-2,3,7,8-TCDF
1830
2430
Pg/g
75.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1910
2430
Pg/g
78.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
1880
2430
Pg/g
77.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1850
2430
Pg/g
75.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1710
2430
Pg/g
70.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1800
2430
Pg/g
73.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1650
2430
Pg/g
67.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1840
2430
Pg/g
75.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1810
2430
Pg/g
74.2
(26%-13 8%)
3701-2,3,7,8-TCDD
225
243
Pg/g
92.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 25
-------
Quality Control
Summary
Page 16 of 25
-------
( (ipc Fear Analytical LLC Report Date: April 25, 2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6023
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010243
MB for batch 25728
12010244
LCS for batch 25728
12010245
LCSD for batch 25728
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
70.5
67.8
71.6
65.8
66.3
53.3
72.1
65.8
65.8
70.5
63.7
67.6
62.4
66.7
58.6
93.0
75.7
80.3
78.0
75.0
84.2
83.1
75.4
75.1
75.7
74.2
70.4
72.3
66.0
78.1
75.4
94.7
69.8
72.0
73.6
68.9
76.7
75.7
69.4
70.9
69.0
67.6
64.3
66.9
61.4
72.2
69.0
91.3
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
6023001
SFRA-20
13C-2,3,7,8-TCDD
66.5 D
(25%-164%)
Page 17 of 25
-------
( (ipc Fear Analytical LLC Report Date: April 25, 2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6023
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
71.4
D
(25%-181%)
70.8
D
(32%-141%)
68.5
D
(28%-130%)
76.2
D
(23%-140%)
70.5
D
(17%-15 7%)
66.3
D
(24%-169%)
66.4
D
(24%-185%)
71.7
D
(21%-178%)
69.5
D
(26%-152%)
64.2
D
(26%-123%)
68.8
D
(28%-13 6%)
60.4
D
(29%-147%)
69.5
D
(28%-143%)
68.8
D
(26%-13 8%)
90.3
D
(35%-197%)
6023001
SFRA-20
6023002
SFRA-21
6023003
SFRA-22
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
73.6
76.6
77.7
74.9
84.3
81.3
70.4
73.2
71.9
73.8
68.5
72.6
64.5
76.3
74.0
91.2
78.5
83.4
80.7
76.6
86.5
89.7
75.3
78.4
77.2
75.8
70.2
73.9
67.6
75.6
74.2
92.3
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
* Recovery outside Acceptance Limits
Page 18 of 25
-------
Cape Fear Analytical LLC
Report Date: April 25, 2014
SDG Number: 6023
Matrix Type: SOLID
Hi-Res Dioxins/Furans
Surrogate Recovery Report
Page 3
of 3
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 19 of 25
-------
Cape Fear Analytical LLC
Report Date: April 25, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/24/2014 14:46 Dilution: 1
Prep Batch ID:25728
Batch ID: 25730
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.6
103
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
97.9
97.9
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
98.4
98.4
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
101
101
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
106
106
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
100
100
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
208
104
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.1
95.3
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
102
102
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
100
100
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
102
102
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
103
103
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
103
103
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
108
108
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
101
101
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
193
96.7
63-170
SDG Number: 6023
Client ID: LCS for batch 25728
Lab Sample ID: 12010244
Instrument: HRP750
Analyst: JTF
Page
20 of 25
-------
Cape Fear Analytical LLC
Report Date: April 25, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/24/2014 15:34 Dilution: 1
Prep Batch ID:25728
Batch ID: 25730
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.9
104
67-158
1.28
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
101
101
70-142
2.63
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
98.7
98.7
70-164
0.343
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
102
102
76-134
0.942
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
107
107
64-162
0.186
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
1.21
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
207
104
78-144
0.597
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.3
96.3
75-158
1.06
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
102
102
80-134
0.405
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
101
101
68-160
0.949
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
105
105
72-134
3.11
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
105
105
84-130
2.11
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
104
104
70-156
0.455
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
110
110
78-130
1.27
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
102
102
82-122
1.09
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
103
103
78-138
1.96
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
193
96.5
63-170
0.137
0-20
SDG Number: 6023
Client ID: LCSD for batch 25728
Lab Sample ID: 12010245
Instrument: HRP750
Analyst: JTF
Page 21 of 25
-------
Cape Fear Analytical LLC
Report Date: April 25, 2014
Method Blank Summary Page ' °' '
SDG Number: 6023
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 25728
Instrument ID:
HRP750
Data File:
A24APR14A-2
Lab Sample ID: 12010243
Column:
Prep Date:
22-APR-14
Analyzed:
04/24/14 09:38
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 25728
12010244
A24APR14B-3
04/24/14
1446
02 LCSD for batch 25728
12010245
A24APR14B-4
04/24/14
1534
03 SFRA-20
6023001
A24APR14B-5
04/24/14
1622
04 SFRA-21
6023002
A24APR14B-6
04/24/14
1709
05 SFRA-22
6023003
A25APR14A-3
04/25/14
1052
06 SFRA-20
6023001
A25APR14C-4
04/25/14
1303
Page 22 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 25, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6023
12010243
QC for batch 25728
MB for batch 25728
25730
04/24/2014 09:38
A24APR14A-2
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
25728
Prep Method:
SW846 3540C
Prep Date:
22-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.0924
Pg/g
0.0924
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.167
Pg/g
0.167
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.352
Pg/g
0.352
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.402
Pg/g
0.402
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.4
Pg/g
0.400
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.36
Pg/g
0.360
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
0.778
Pg/g
0.264
10.0
51207-31-9
2,3,7,8-TCDF
u
.0684
Pg/g
0.0684
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.228
Pg/g
0.141
5.00
57117-31-4
2,3,4,7,8-PeCDF
J
0.246
Pg/g
0.134
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.276
Pg/g
0.276
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
J
0.332
Pg/g
0.278
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.368
Pg/g
0.368
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.408
Pg/g
0.408
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.314
Pg/g
0.086
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
0.312
Pg/g
0.151
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
0.404
Pg/g
0.248
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
141
200
Pg/g
70.5
(25 %-164%)
13C-1,2,3,7,8-PeCDD
136
200
Pg/g
67.8
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
143
200
Pg/g
71.6
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
132
200
Pg/g
65.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
133
200
Pg/g
66.3
(23%-140%)
13C-OCDD
213
400
Pg/g
53.3
(17%-157%)
13C-2,3,7,8-TCDF
144
200
Pg/g
72.1
(24%-169%)
13C-1,2,3,7,8-PeCDF
132
200
Pg/g
65.8
(24%-185%)
13C-2,3,4,7,8-PeCDF
132
200
Pg/g
65.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
141
200
Pg/g
70.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
127
200
Pg/g
63.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
135
200
Pg/g
67.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
125
200
Pg/g
62.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
133
200
Pg/g
66.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
117
200
Pg/g
58.6
(26%-13 8%)
37Cl-2,3,7,8-TCDD
18.6
20.0
Pg/g
93.0
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 23 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 25, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6023
Lab Sample ID: 12010244
Client Sample: *or batch 25728
Client ID: LCS for batch 25728
Batch ID: 25730
Run Date: 04/24/2014 14:46
Data File: A24APR14B-3
Prep Batch: 25728
Prep Date: 22-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.6
Pg/g
0.099 1.00
40321-76-4
1,2,3,7,8-PeCDD
97.9
Pg/g
0.165 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.4
Pg/g
0.404 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
101
Pg/g
0.448 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
106
Pg/g
0.454 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
100
Pg/g
0.454 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
208
Pg/g
0.820 10.0
51207-31-9
2,3,7,8-TCDF
19.1
Pg/g
0.112 1.00
57117-41-6
1,2,3,7,8-PeCDF
102
Pg/g
0.177 5.00
57117-31-4
2,3,4,7,8-PeCDF
100
Pg/g
0.178 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
102
Pg/g
0.542 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
103
Pg/g
0.512 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
103
Pg/g
0.536 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
108
Pg/g
0.790 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
0.216 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
101
Pg/g
0.358 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
193
Pg/g
0.604 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
151
200
Pg/g
75.7
(20%-175%)
13C-1,2,3,7,8-
PeCDD
161
200
Pg/g
80.3
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
156
200
Pg/g
78.0
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
150
200
Pg/g
75.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
168
200
Pg/g
84.2
(22%-166%)
13C-OCDD
333
400
Pg/g
83.1
(13%-199%)
13C-2,3,7,8-TCDF
151
200
Pg/g
75.4
(22%-152%)
13C-1,2,3,7,8-
PeCDF
150
200
Pg/g
75.1
(21%-192%)
130-2,3,4,7,8-
PeCDF
151
200
Pg/g
75.7
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
148
200
Pg/g
74.2
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
141
200
Pg/g
70.4
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
145
200
Pg/g
72.3
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
132
200
Pg/g
66.0
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
156
200
Pg/g
78.1
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
151
200
Pg/g
75.4
(20%-186%)
3701-2,3,7,8-TCDD
18.9
20.0
Pg/g
94.7
(31 %-191%)
Comments:
Page 24 of 25
-------
Cape Fear Analytical LLC
Report Date:
April 25, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6023
12010245
QC for batch 25728
LCSD for batch 25728
25730
04/24/2014 15:34
A24APR14B-4
25728
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
22-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.9
Pg/g
0.108
1.00
40321-76-4
1,2,3,7,8-PeCDD
101
Pg/g
0.256
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.7
Pg/g
0.262
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
0.286
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
107
Pg/g
0.290
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
0.428
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
207
Pg/g
0.792
10.0
51207-31-9
2,3,7,8-TCDF
19.3
Pg/g
0.123
1.00
57117-41-6
1,2,3,7,8-PeCDF
102
Pg/g
0.236
5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.240
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
105
Pg/g
0.350
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
105
Pg/g
0.326
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
104
Pg/g
0.356
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
110
Pg/g
0.496
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
102
Pg/g
0.288
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
103
Pg/g
0.470
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
193
Pg/g
0.410
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
140
200
Pg/g
69.8
(20%-175%)
13C-1,2,3,7,8-PeCDD
144
200
Pg/g
72.0
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
147
200
Pg/g
73.6
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
138
200
Pg/g
68.9
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
153
200
Pg/g
76.7
(22%-166%)
13C-OCDD
303
400
Pg/g
75.7
(13%-199%)
13C-2,3,7,8-TCDF
139
200
Pg/g
69.4
(22%-152%)
13C-1,2,3,7,8-PeCDF
142
200
Pg/g
70.9
(21%-192%)
13C-2,3,4,7,8-PeCDF
138
200
Pg/g
69.0
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
135
200
Pg/g
67.6
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
129
200
Pg/g
64.3
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
134
200
Pg/g
66.9
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
123
200
Pg/g
61.4
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
144
200
Pg/g
72.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
138
200
Pg/g
69.0
(20%-186%)
37Cl-2,3,7,8-TCDD
18.3
20.0
Pg/g
91.3
(31 %-191%)
Comments:
Page 25 of 25
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
April 29. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6049
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 24, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of22
problem solved
-------
CHAIN OF CUSTODY RECORD
ENVIRONMENTAL PROTECTION AGENCY REGION VII
iff -far/lcuml
-km.
ACTIVITY LEAOER(Print) , NAME OF SURVEY OR ACTIVITY a IDATEOF COLLKTION/W lajhfci
H&M* Shi% / ftu>i K\ w(oHI h>r F*nȣf" R
oat!
4-^
•TIME
RECEIVED BY
IT."5,
Cuvdi
~| Sealed unsealed f
I R
JN FOR CHAIfGf Of CUfcTOJbY
°bPiv
dS
relinquished by
SEALED-
DATE
TIME
UNSEALED P
RECEIVED BY
~1 SEALED
REASON FOR CHANQJE OF CUSTODY
UNSEALED T
RELINQUISHED BY
DATE
TIME
~1 SEALED
UN sealed!
RECEIVED BY
n sealed
reason for change of custody
UNSEALED r
7-EPA-
¦9262(Rf>ggii:^f22
*U.S. GPO: 2002-756-917/40053
-------
SAMPLE RECEIPT CHECKLIST
Cope Feor Analytical
Client: "T^T"
Work Order:
R""VM fv
Date/Time Received: 4 *5^0
Suspected Hazard Information
Yes
NA
No |
DOE Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
Samples identified as Foreign Soil?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received intact
arid sealed?
Circle Applicable:
seals broken damaged conlsir
leaking container ©Tbertdescribe)
Chain of Custody documents included
with shipment?
i/
S
Samples requiring cold preservation
within 0-6'C?
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 22
-------
Case Narrative
Page 5 of22
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6049
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25767
Clean Up Batch Number: 25766
Extraction Batch Number: 25765
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6049001 SFRA-23
6049002 SFRA-24
12010287 Method Blank (MB)
12010288 Laboratory Control Sample (LCS)
12010289 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of 22
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
One extraction standard recovered below acceptance criteria within 1% of the lower control
limit. This low recovery is due to matrix interference which caused a lock mass dip below 13C-
123678-HxCDD. 6049001 (SFRA-23)- Batch 25767.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 7 of22
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
The following NCR was generated for this SDG: 644460 6049001 (SFRA-23)- Batch 25767.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 22
-------
Sample Data Summary
Page 9 of 22
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6049 CFA Work Order: 6049
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 29 APR 2014 Title: Data Validator
Page 10 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6049
Lab Sample ID: 6049001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/23/2014 16:15
04/24/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 19.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-23
25767
04/26/2014 00:28
A25APR14B-12
25765
24-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.03 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
4710
Pg/g
2.21 12.1
40321-76-4
1,2,3,7,8-PeCDD
J
3.29
Pg/g
2.66 60.4
39227-28-6
1,2,3,4,7,8-HxCDD
J
5.63
Pg/g
4.69 60.4
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
59.7
Pg/g
14.6 60.4
19408-74-3
1,2,3,7,8,9-HxCDD
JQ
23.3
Pg/g
8.07 60.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
547
Pg/g
6.31 60.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7320
Pg/g
18.5 121
51207-31-9
2,3,7,8-TCDF
25.0
Pg/g
2.61 12.1
57117-41-6
1,2,3,7,8-PeCDF
J
6.38
Pg/g
1.93 60.4
57117-31-4
2,3,4,7,8-PeCDF
J
4.40
Pg/g
2.12 60.4
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.26
Pg/g
3.67 60.4
57II7.44.9
1,2,3,6,7,8-HxCDF
J
4.64
Pg/g
3.77 60.4
60851-34-5
2,3,4,6,7,8-HxCDF
J
7.27
Pg/g
4.57 60.4
72918-21-9
1,2,3,7,8,9-HxCDF
U
6.5
Pg/g
6.50 60.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
97.0
Pg/g
0.466 60.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
7.90
Pg/g
0.788 60.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
237
Pg/g
3.87 121
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1700
2420
Pg/g
70.4
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1550
2420
Pg/g
64.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1760
2420
Pg/g
72.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 668
2420
Pg/g
27.6
* (28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2720
2420
Pg/g
112
(23%-140%)
13C-OCDD
5880
4830
Pg/g
122
(17%-157%)
13C-2,3,7,8-TCDF
1820
2420
Pg/g
75.1
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1560
2420
Pg/g
64.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1480
2420
Pg/g
61.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2130
2420
Pg/g
88.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2050
2420
Pg/g
85.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2420
Pg/g
79.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2010
2420
Pg/g
83.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2310
2420
Pg/g
95.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2420
2420
Pg/g
100
(26%-13 8%)
3701-2,3,7,8-TCDD
215
242
Pg/g
89.1
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 29, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6049
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6049001
Date Collected:
04/23/2014 16:15
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
04/24/2014 09:50
%Moisture:
19.6
Client ID:
SFRA-23
Prep Basis:
Dry Weight
Batch ID:
25767
Method:
EPA Method 1613B
Run Date:
04/28/2014 15:12
Analyst:
JTF
Instrument:
HRP750
Data File:
A28APR14A-5
Dilution:
1
Prep Batch:
25765
Prep Method:
SW846 3540C
Prep Date:
24-APR-14
Prep Aliquot:
1.03 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
23.4
Pg/g
5.15
12.1
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6049
Lab Sample ID: 6049002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/23/2014 16:25
04/24/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 20.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-24
25767
04/26/2014 01:16
A25APR14B-13
25765
24-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.34 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
416
Pg/g
1.11 9.36
40321-76-4
1,2,3,7,8-PeCDD
U
1.45
Pg/g
1.45 46.8
39227-28-6
1,2,3,4,7,8-HxCDD
J
3.09
Pg/g
2.32 46.8
57653-85-7
1,2,3,6,7,8-HxCDD
J
7.54
Pg/g
2.38 46.8
19408-74-3
1,2,3,7,8,9-HxCDD
J
4.77
Pg/g
2.51 46.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
308
Pg/g
5.39 46.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7700
Pg/g
13.0 93.6
51207-31-9
2,3,7,8-TCDF
J
3.59
Pg/g
1.73 9.36
57117-41-6
1,2,3,7,8-PeCDF
J
6.23
Pg/g
1.76 46.8
57117-31-4
2,3,4,7,8-PeCDF
u
1.84
Pg/g
1.84 46.8
70648-26-9
1,2,3,4,7,8-HxCDF
u
3.26
Pg/g
3.26 46.8
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.41
Pg/g
1.41 46.8
60851-34-5
2,3,4,6,7,8-HxCDF
J
1.59
Pg/g
1.36 46.8
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.97
Pg/g
1.97 46.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
45.9
Pg/g
0.460 46.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
3.97
Pg/g
0.711 46.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
231
Pg/g
4.10 93.6
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1320
1870
Pg/g
70.3
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1350
1870
Pg/g
72.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1370
1870
Pg/g
73.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1330
1870
Pg/g
70.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1530
1870
Pg/g
81.5
(23%-140%)
13C-OCDD
3150
3740
Pg/g
84.1
(17%-157%)
13C-2,3,7,8-TCDF
1380
1870
Pg/g
73.7
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1330
1870
Pg/g
71.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
1260
1870
Pg/g
67.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1330
1870
Pg/g
70.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1290
1870
Pg/g
69.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1300
1870
Pg/g
69.5
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1250
1870
Pg/g
66.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1400
1870
Pg/g
75.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1410
1870
Pg/g
75.6
(26%-13 8%)
3701-2,3,7,8-TCDD
154
187
Pg/g
82.4
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 22
-------
Quality Control
Summary
Page 14 of 22
-------
( (ipc Fear Analytical LLC Report Date: April 28, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6049
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010288
LCS for batch 25765
12010289
LCSD for batch 25765
12010287
MB for batch 25765
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
55.8
59.4
56.2
56.0
63.6
56.5
59.7
57.3
57.3
55.9
54.5
56.4
50.8
58.3
57.4
84.0
71.2
79.4
73.9
71.6
77.6
68.8
75.2
77.1
79.9
73.5
70.3
73.0
65.4
74.4
71.8
83.8
70.2
77.0
71.5
73.7
81.9
74.5
73.6
72.1
76.3
73.0
71.5
75.1
65.3
77.3
74.4
83.7
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6049001
SFRA-23
13C-2,3,7,8-TCDD
70.4
(25%-164%)
Page 15 of 22
-------
( (ipc Fear Analytical LLC Report Date: April 28, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6049
Matrix Type: SOLID
Sample ID Client ID
6049001 SFRA-23
6049002 SFRA-24
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
64.2 (25%-181%)
72.8 (32%-141%)
27.6 * (28%-130%)
112 (23%-140%)
122 (17%-15 7%)
75.1 (24%-169%)
64.5 (24%-185%)
61.2 (21%-178%)
88.2 (26%-152%)
85.0 (26%-123%)
79.1 (28%-13 6%)
83.4 (29%-147%)
95.5 (28%-143%)
100 (26%-13 8%)
89.1 (35%-197%)
70.3 (25%-164%)
72.1 (25%-181%)
73.0 (32%-141%)
70.8 (28%-130%)
81.5 (23%-140%)
84.1 (17%-15 7%)
73.7 (24%-169%)
71.1 (24%-185%)
67.2 (21%-178%)
70.9 (26%-152%)
69.1 (26%-123%)
69.5 (28%-13 6%)
66.8 (29%-147%)
75.0 (28%-143%)
75.6 (26%-13 8%)
82.4 (35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 16 of 22
-------
Cape Fear Analytical LLC
Report Date: April 28, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/25/2014 22:04 Dilution: 1
Prep Batch ID:25765
Batch ID: 25767
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.7
104
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
99.7
99.7
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
98.0
98
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
102
102
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
109
109
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
100
100
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
203
102
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.5
97.7
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
101
101
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
99.7
99.7
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
100
100
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
100
100
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
101
101
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
108
108
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
99.2
99.2
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
200
100
63-170
SDG Number: 6049
Client ID: LCS for batch 25765
Lab Sample ID: 12010288
Instrument: HRP750
Analyst: JTF
Page
17 of 22
-------
Cape Fear Analytical LLC
Report Date: April 28, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 04/25/2014 22:52 Dilution: 1
Prep Batch ID:25765
Batch ID: 25767
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.0
105
67-158
1.02
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
102
102
70-142
1.78
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
97.6
97.6
70-164
0.362
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
104
104
76-134
1.80
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
103
103
64-162
5.34
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
99.8
99.8
70-140
0.669
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
204
102
78-144
0.323
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.9
94.3
75-158
3.53
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
98.5
98.5
80-134
2.40
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
99.1
99.1
68-160
0.668
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
99.5
99.5
72-134
0.538
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
103
103
84-130
2.75
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
101
101
70-156
0.599
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
107
107
78-130
0.352
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
99.4
99.4
82-122
1.16
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
99.3
99.3
78-138
0.0927
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
197
98.4
63-170
1.71
0-20
SDG Number: 6049
Client ID: LCSD for batch 25765
Lab Sample ID: 12010289
Instrument: HRP750
Analyst: JTF
Page
18 of 22
-------
Cape Fear Analytical LLC
Report Date: April 28, 2014
Method Blank Summary Page ' °' '
SDG Number: 6049
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 25765
Instrument ID:
HRP750
Data File:
A25APR14B-11
Lab Sample ID: 12010287
Column:
Prep Date:
24-APR-14
Analyzed:
04/25/14 23:40
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 25765
12010288
A25APR14B-9
04/25/14
2204
02 LCSD for batch 25765
12010289
A25APR14B-10
04/25/14
2252
03 SFRA-23
6049001
A25APR14B-12
04/26/14
0028
04 SFRA-24
6049002
A25APR14B-13
04/26/14
0116
05 SFRA-23
6049001
A28APR14A-5
04/28/14
1512
Page 19 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 28, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6049
12010287
QC for batch 25765
MB for batch 25765
25767
04/25/2014 23:40
A25APR14B-11
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
25765
Prep Method:
SW846 3540C
Prep Date:
24-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.0926
Pg/g
0.0926
1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.132
Pg/g
0.100
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.153
Pg/g
0.153
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.158
Pg/g
0.158
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.165
Pg/g
0.165
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.248
Pg/g
0.248
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
0.864
Pg/g
0.366
10.0
51207-31-9
2,3,7,8-TCDF
u
.106
Pg/g
0.106
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.134
Pg/g
0.0708
5.00
57117-31-4
2,3,4,7,8-PeCDF
J
0.112
Pg/g
0.0728
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.142
Pg/g
0.142
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.142
Pg/g
0.142
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.15
Pg/g
0.150
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.226
Pg/g
0.226
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.106
Pg/g
0.0292
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.174
Pg/g
0.174
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.336
Pg/g
0.336
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
140
200
Pg/g
70.2
(25 %-164%)
13C-1,2,3,7,8-PeCDD
154
200
Pg/g
77.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
143
200
Pg/g
71.5
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
147
200
Pg/g
73.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
164
200
Pg/g
81.9
(23%-140%)
13C-OCDD
298
400
Pg/g
74.5
(17%-157%)
13C-2,3,7,8-TCDF
147
200
Pg/g
73.6
(24%-169%)
13C-1,2,3,7,8-PeCDF
144
200
Pg/g
72.1
(24%-185%)
13C-2,3,4,7,8-PeCDF
153
200
Pg/g
76.3
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
146
200
Pg/g
73.0
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
143
200
Pg/g
71.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
150
200
Pg/g
75.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
131
200
Pg/g
65.3
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
155
200
Pg/g
77.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
149
200
Pg/g
74.4
(26%-13 8%)
37Cl-2,3,7,8-TCDD
16.7
20.0
Pg/g
83.7
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 20 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 28, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6049
Lab Sample ID: 12010288
Client Sample: ^or batch 25765
Client ID: LCS for batch 25765
Batch ID: 25767
Run Date: 04/25/2014 22:04
Data File: A25APR14B-9
Prep Batch: 25765
Prep Date: 24-APR-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.7
Pg/g
0.119 1.00
40321-76-4
1,2,3,7,8-PeCDD
99.7
Pg/g
0.204 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.0
Pg/g
0.304 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
0.326 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
109
Pg/g
0.334 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
100
Pg/g
0.470 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
203
Pg/g
0.810 10.0
51207-31-9
2,3,7,8-TCDF
19.5
Pg/g
0.126 1.00
57117-41-6
1,2,3,7,8-PeCDF
101
Pg/g
0.236 5.00
57117-31-4
2,3,4,7,8-PeCDF
99.7
Pg/g
0.232 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
100
Pg/g
0.374 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
100
Pg/g
0.374 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
101
Pg/g
0.376 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
108
Pg/g
0.570 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
0.530 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.2
Pg/g
0.842 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
200
Pg/g
0.952 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
112
200
Pg/g
55.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
119
200
Pg/g
59.4
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
112
200
Pg/g
56.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
112
200
Pg/g
56.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
127
200
Pg/g
63.6
(22%-166%)
13C-OCDD
226
400
Pg/g
56.5
(13%-199%)
13C-2,3,7,8-TCDF
119
200
Pg/g
59.7
(22%-152%)
13C-1,2,3,7,8-
PeCDF
115
200
Pg/g
57.3
(21%-192%)
130-2,3,4,7,8-
PeCDF
115
200
Pg/g
57.3
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
112
200
Pg/g
55.9
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
109
200
Pg/g
54.5
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
113
200
Pg/g
56.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
102
200
Pg/g
50.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
117
200
Pg/g
58.3
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
115
200
Pg/g
57.4
(20%-186%)
3701-2,3,7,8-TCDD
16.8
20.0
Pg/g
84.0
(31 %-191%)
Comments:
Page 21 of 22
-------
Cape Fear Analytical LLC
Report Date:
April 28, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6049
12010289
QC for batch 25765
LCSD for batch 25765
25767
04/25/2014 22:52
A25APR14B-10
25765
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
24-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
21.0
Pg/g
0.0984
1.00
40321-76-4
1,2,3,7,8-PeCDD
102
Pg/g
0.178
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
97.6
Pg/g
0.378
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
104
Pg/g
0.418
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
103
Pg/g
0.424
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.8
Pg/g
0.424
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
204
Pg/g
0.718
10.0
51207-31-9
2,3,7,8-TCDF
18.9
Pg/g
0.136
1.00
57117-41-6
1,2,3,7,8-PeCDF
98.5
Pg/g
0.248
5.00
57117-31-4
2,3,4,7,8-PeCDF
99.1
Pg/g
0.234
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
99.5
Pg/g
0.382
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
103
Pg/g
0.382
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
101
Pg/g
0.390
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
107
Pg/g
0.602
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
99.4
Pg/g
0.434
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.3
Pg/g
0.714
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
197
Pg/g
1.01
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
142
200
Pg/g
71.2
(20%-175%)
13C-1,2,3,7,8-PeCDD
159
200
Pg/g
79.4
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
148
200
Pg/g
73.9
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
143
200
Pg/g
71.6
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
155
200
Pg/g
77.6
(22%-166%)
13C-OCDD
275
400
Pg/g
68.8
(13%-199%)
13C-2,3,7,8-TCDF
150
200
Pg/g
75.2
(22%-152%)
13C-1,2,3,7,8-PeCDF
154
200
Pg/g
77.1
(21%-192%)
13C-2,3,4,7,8-PeCDF
160
200
Pg/g
79.9
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
147
200
Pg/g
73.5
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
141
200
Pg/g
70.3
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
146
200
Pg/g
73.0
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
131
200
Pg/g
65.4
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
149
200
Pg/g
74.4
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
144
200
Pg/g
71.8
(20%-186%)
37Cl-2,3,7,8-TCDD
16.8
20.0
Pg/g
83.8
(31 %-191%)
Comments:
Page 22 of 22
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
May 01. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6066
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on April 29, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of21
problem solved
-------
of
Project #:
CFAQuote#: _
COC Number0':
PO Number:
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: [g 0(# G?
:m-2zs- z^i
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client
N"c: 1Ir l 3k,
Phone #:
Sample Analysis Requested (Fill in the number of containers for each test)
5\r*i*.r f5r*vf gwA AV?
OkAl\ ~Tt
Fax#:
±Ss£Si
<- Preservative Type (6)
r , .fiiJtnilthLk,
Collected by: Q
Remarks; Are there any known hazards applicable to these samples? If so, please list the hazards
£W'bU S^'*0^5 jfUrm-5 CsvAA-pe
Sample Collection Time Zone
Eastern Pacific
I Uenirsp Other _
"WSfintain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed) Date
'"L f
Time
Date
Time
Received by (signed)
Atik.W 2AM>gj\ t03 2.
CFAPM:CtyAjL U»r tinS
Method of Shipment:
: f«KGc
Date Shipped:
Airbill #:
mi. .^51 bW
3
Airbill
1.) Chain of Custody Number ** C lient Determined
2.) QC Codes: N = Normal Sample, TB = Trip Blank, FD = Field Duplicate, EB = Equipment Blank, MS » Matrix Spike Sample, MSD = Matrix Spike Duplicate Sample, G = Grab, C « Composite
3.) Field Filtered: For liquid matrices, indicate with a- ¥ - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes; DW==Drinking Water, GW=Groundwater, SW=Surface Water, \VW=Waste Water, W=Water, ML~Mlsc Liquid,SO~So31, SD^Sediment, Sl>Studge, SS-Solid Waste, 0=051, F-Filier, P=Wipe, U=Urine> F=Fecai, N=Nasal
5.) Sample Analysis Requested; Analytical method requested (i.eJ»290B, 1668B) and number of containers provided for each (i.e. 8290B - 3,1668B -1).
6.) Preservative Type: HA = Hydrochloric Acid, NI = Nitric Acid, SH - Sodium Hydroxide, SA = Sulfuric Acid, AA = Ascorbic Acid, HX = Hexane, ST = Sodium Thiosulfate, Jf no preservative Is added = leave field blank
WHITE = LABORATORY YELLOW-FILE PINK-CLIENT
For Lab Receiving Use Only
PS
Seal Intact?
NO
Temp:
C
-------
SAMPLE RECEIPT CHECKLIST
Cope Fear Analytical
Client:
i£t£L
Worlt Order:
Received By:
Date/Time Received: f 0 "L
Suspected Hazard information
Yes
NA
No
Shipped as DOT Hazardous?
Samples identified as Foreign Soil?
DOE Site Sample Packages
Yes
NA
No*
Screened <0.5 mR/hr?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
L*
O'rde Applicable:
seals broken damaged container leaking container other{describe)
2
Chain of Custody documents included
with shipment?
Ls
3
Samples requiring cold preservation
within 0-6°C?
-
/-
c
Pre salvation Method:
ice bags) blue ice dry ice none other (describe)
-¦ 3.re
4
Samples requiring chemical
preservation at proper pH?
L
Sample IDs, containers affected and pH observed;
If preservative added, Lot#:
5
Samples requiring preservation have
no residual chlorine?
Sample IDs, containers affected:
If preservative added, Lot#-.
6
Samples received within holding time?
Sample 1 Ds, tests affected:
7
Sample IDs on COC match IDs on
containers?
Ls
Sample IDs, containers affected:
8
Date & time of COC match date & time
on containers?
/
Sample IDs, containers affected:
9
Number of containers received match
number indicated on COC?
/
Sample IDs,containers affected:
10
COC form is properly signed in
relinquished/received sections?
is
Comments:
Checklist performed by: Initials: _ L_ Date:
zq/H^iq
Page 3 of 21
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of21
-------
Case Narrative
Page 5 of21
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6066
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25813
Clean Up Batch Number: 25812
Extraction Batch Number: 25811
Sample Analysis
The following samples were analyzed using the analytical protocol as established in
Sample ID Client ID
6066001 SFRA-26
6066002 SFRA-27
12010323 Method Blank (MB)
12010324 Laboratory Control Sample (LCS)
12010325 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of21
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Page 7 of21
-------
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of21
-------
Sample Data Summary
Page 9 of21
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6066 CFA Work Order: 6066
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 01 MAY 2014 Title: Data Validator
Page 10 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 1, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6066
Lab Sample ID: 6066001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/28/2014 14:22
04/29/2014 10:32
Project: TETR00114
Matrix: SOLID
%Moisture: 17
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-26
25813
05/01/2014 01:40
A30APR14B-12
25811
29-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.08 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
530
Pg/g
1.71 11.2
40321-76-4
1,2,3,7,8-PeCDD
U
3.5
Pg/g
3.50 55.8
39227-28-6
1,2,3,4,7,8-HxCDD
J
24.5
Pg/g
5.98 55.8
57653-85-7
1,2,3,6,7,8-HxCDD
123
Pg/g
6.27 55.8
19408-74-3
1,2,3,7,8,9-HxCDD
J
48.0
Pg/g
6.51 55.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
2930
Pg/g
12.8 55.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
20100
Pg/g
38.2 112
51207-31-9
2,3,7,8-TCDF
J
6.45
Pg/g
4.17 11.2
57117-41-6
1,2,3,7,8-PeCDF
J
6.20
Pg/g
3.35 55.8
57117-31-4
2,3,4,7,8-PeCDF
J
6.74
Pg/g
3.32 55.8
70648-26-9
1,2,3,4,7,8-HxCDF
J
23.2
Pg/g
3.46 55.8
57II7.44.9
1,2,3,6,7,8-HxCDF
J
9.71
Pg/g
3.39 55.8
60851-34-5
2,3,4,6,7,8-HxCDF
J
14.5
Pg/g
3.39 55.8
72918-21-9
1,2,3,7,8,9-HxCDF
u
9.21
Pg/g
9.21 55.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
284
Pg/g
3.57 55.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
26.8
Pg/g
6.05 55.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
549
Pg/g
7.32 112
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1730
2230
Pg/g
77.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1820
2230
Pg/g
81.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1730
2230
Pg/g
77.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1710
2230
Pg/g
76.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1860
2230
Pg/g
83.5
(23%-140%)
13C-OCDD
3950
4460
Pg/g
88.4
(17%-157%)
13C-2,3,7,8-TCDF
1710
2230
Pg/g
76.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
1730
2230
Pg/g
77.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1780
2230
Pg/g
79.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1610
2230
Pg/g
72.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1590
2230
Pg/g
71.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1610
2230
Pg/g
72.3
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1440
2230
Pg/g
64.6
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1720
2230
Pg/g
76.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1600
2230
Pg/g
71.8
(26%-13 8%)
3701-2,3,7,8-TCDD
205
223
Pg/g
91.7
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 1, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6066
Lab Sample ID: 6066002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/28/2014 14:39
04/29/2014 10:32
Project: TETR00114
Matrix: SOLID
%Moisture: 15.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-27
25813
05/01/2014 02:27
A30APR14B-13
25811
29-APR-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.12 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
161
Pg/g
1.76 10.5
40321-76-4
1,2,3,7,8-PeCDD
U
2.93
Pg/g
2.93 52.7
39227-28-6
1,2,3,4,7,8-HxCDD
J
6.62
Pg/g
3.54 52.7
57653-85-7
1,2,3,6,7,8-HxCDD
J
35.2
Pg/g
3.84 52.7
19408-74-3
1,2,3,7,8,9-HxCDD
J
14.9
Pg/g
3.92 52.7
35822-46-9
1,2,3,4,6,7,8-HpCDD
920
Pg/g
9.29 52.7
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11200
Pg/g
19.1 105
51207-31-9
2,3,7,8-TCDF
u
2.38
Pg/g
2.38 10.5
57117-41-6
1,2,3,7,8-PeCDF
u
2.05
Pg/g
2.05 52.7
57117-31-4
2,3,4,7,8-PeCDF
u
3.03
Pg/g
3.03 52.7
70648-26-9
1,2,3,4,7,8-HxCDF
J
9.19
Pg/g
2.82 52.7
57II7.44.9
1,2,3,6,7,8-HxCDF
J
5.63
Pg/g
2.93 52.7
60851-34-5
2,3,4,6,7,8-HxCDF
J
7.71
Pg/g
3.06 52.7
72918-21-9
1,2,3,7,8,9-HxCDF
u
4.51
Pg/g
4.51 52.7
67562-39-4
1,2,3,4,6,7,8-HpCDF
163
Pg/g
1.62 52.7
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
15.2
Pg/g
2.74 52.7
39001-02-0
1,2,3,4,6,7,8,9-OCDF
611
Pg/g
8.20 105
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1710
2110
Pg/g
81.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1890
2110
Pg/g
89.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1820
2110
Pg/g
86.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1760
2110
Pg/g
83.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1870
2110
Pg/g
88.8
(23%-140%)
13C-OCDD
3860
4210
Pg/g
91.6
(17%-157%)
13C-2,3,7,8-TCDF
1710
2110
Pg/g
81.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
1800
2110
Pg/g
85.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1820
2110
Pg/g
86.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1730
2110
Pg/g
82.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1620
2110
Pg/g
77.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1700
2110
Pg/g
80.6
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1510
2110
Pg/g
71.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1770
2110
Pg/g
84.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1630
2110
Pg/g
77.3
(26%-13 8%)
3701-2,3,7,8-TCDD
180
211
Pg/g
85.6
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 21
-------
Quality Control
Summary
Page 13 of 21
-------
Cape Fear Analytical LLC Report Date: May 1,2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6066
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010324
LCS for batch 25811
12010325
LCSDforbatch 25811
12010323
MB for batch 25811
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
75.0
82.7
79.4
77.2
85.0
83.1
75.2
77.2
79.5
75.4
73.0
73.2
65.0
78.6
73.4
87.7
79.4
88.8
82.9
81.2
88.7
85.4
79.6
82.6
84.6
77.0
75.2
77.4
67.7
80.7
75.1
85.5
81.4
88.8
84.9
80.2
88.4
83.5
82.5
85.2
87.2
77.2
76.9
78.0
66.7
81.8
74.3
82.3
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6066001
SFRA-26
13C-2,3,7,8-TCDD
77.4
(25%-164%)
Page 14 of 21
-------
Cape Fear Analytical LLC Report Date: May 1,2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6066
Matrix Type: SOLID
Sample ID Client ID
6066001 SFRA-26
6066002 SFRA-27
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
81.6 (25%-181%)
77.7 (32%-141%)
76.7 (28%-130%)
83.5 (23%-140%)
88.4 (17%-15 7%)
76.5 (24%-169%)
77.6 (24%-185%)
79.7 (21%-178%)
72.1 (26%-152%)
71.4 (26%-123%)
72.3 (28%-13 6%)
64.6 (29%-147%)
76.9 (28%-143%)
71.8 (26%-13 8%)
91.7 (35%-197%)
81.4 (25%-164%)
89.9 (25%-181%)
86.5 (32%-141%)
83.7 (28%-130%)
88.8 (23%-140%)
91.6 (17%-15 7%)
81.2 (24%-169%)
85.3 (24%-185%)
86.4 (21%-178%)
82.1 (26%-152%)
77.0 (26%-123%)
80.6 (28%-13 6%)
71.8 (29%-147%)
84.0 (28%-143%)
77.3 (26%-13 8%)
85.6 (35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 15 of 21
-------
Cape Fear Analytical LLC
Report Date: May 1,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 04/30/2014 23:16 Dilution: 1
Prep Batch ID:25811
Batch ID: 25813
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
19.5
97.6
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
95.9
95.9
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
98.7
98.7
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
98.7
98.7
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
101
101
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
201
100
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.9
94.4
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
96.9
96.9
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
95.9
95.9
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
99.3
99.3
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
96.2
96.2
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
100
100
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
104
104
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
98.6
98.6
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
101
101
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
174
86.8
63-170
SDG Number: 6066
Client ID: LCS for batch 25811
Lab Sample ID: 12010324
Instrument: HRP750
Analyst: JTF
Page
16 of 21
-------
Cape Fear Analytical LLC
Report Date: May 1,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 05/01/2014 00:04 Dilution: 1
Prep Batch ID:25811
Batch ID: 25813
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
19.9
99.4
67-158
1.86
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
96.5
96.5
70-142
0.561
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
96.1
96.1
70-164
2.69
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
100
100
76-134
1.35
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
99.6
99.6
64-162
1.54
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
0.175
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
196
97.9
78-144
2.43
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.7
93.7
75-158
0.713
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
97.0
97
80-134
0.177
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
95.3
95.3
68-160
0.611
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
101
101
72-134
1.75
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
101
101
84-130
4.43
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
99.1
99.1
70-156
1.20
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
105
105
78-130
1.01
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
99.9
99.9
82-122
1.26
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
99.6
99.6
78-138
1.03
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
176
87.9
63-170
1.21
0-20
SDG Number: 6066
Client ID: LCSD for batch 25811
Lab Sample ID: 12010325
Instrument: HRP750
Analyst: JTF
Page
17 of 21
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Cape Fear Analytical LLC
Report Date:
May 1, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6066
Client ID: MB for batch 25811
Lab Sample ID: 12010323
Column:
Client: TETR001
Instrument ID: HRP750
Prep Date: 29-APR-14
Matrix: SOLID
Data File: A30APR14B-11
Analyzed: 05/01/14 00:52
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 25811
12010324
A30APR14B-9
04/30/14
2316
02
LCSDforbatch 25811
12010325
A30APR14B-10
05/01/14
0004
03
SFRA-26
6066001
A30APR14B-12
05/01/14
0140
04
SFRA-27
6066002
A30APR14B-13
05/01/14
0227
Page 18 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 1, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6066
12010323
QC for batch 25811
MB for batch 25811
25813
05/01/2014 00:52
A30APR14B-11
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
25811
Prep Method:
SW846 3540C
Prep Date:
29-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.124
Pg/g
0.124
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.274
Pg/g
0.274
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.179
Pg/g
0.179
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.188
Pg/g
0.188
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.314
Pg/g
0.314
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.366
Pg/g
0.238
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
1.26
Pg/g
0.512
10.0
51207-31-9
2,3,7,8-TCDF
u
.138
Pg/g
0.138
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.254
Pg/g
0.0684
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.184
Pg/g
0.184
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.174
Pg/g
0.136
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
J
0.266
Pg/g
0.135
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.216
Pg/g
0.216
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.360
Pg/g
0.216
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.234
Pg/g
0.164
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.3
Pg/g
0.300
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.472
Pg/g
0.472
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
163
200
Pg/g
81.4
(25 %-164%)
13C-1,2,3,7,8-PeCDD
178
200
Pg/g
88.8
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
170
200
Pg/g
84.9
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
160
200
Pg/g
80.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
177
200
Pg/g
88.4
(23%-140%)
13C-OCDD
334
400
Pg/g
83.5
(17%-157%)
13C-2,3,7,8-TCDF
165
200
Pg/g
82.5
(24%-169%)
13C-1,2,3,7,8-PeCDF
170
200
Pg/g
85.2
(24%-185%)
13C-2,3,4,7,8-PeCDF
174
200
Pg/g
87.2
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
154
200
Pg/g
77.2
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
154
200
Pg/g
76.9
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
156
200
Pg/g
78.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
133
200
Pg/g
66.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
164
200
Pg/g
81.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
149
200
Pg/g
74.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
16.5
20.0
Pg/g
82.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 1, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6066
Lab Sample ID: 12010324
Client Sample: *or batch 25811
Client ID: LCS for batch 25811
Batch ID: 25813
Run Date: 04/30/2014 23:16
Data File: A30APR14B-9
Prep Batch: 25811
Prep Date: 29-APR-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
19.5
Pg/g
0.166 1.00
40321-76-4
1,2,3,7,8-PeCDD
95.9
Pg/g
0.314 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.7
Pg/g
0.434 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.7
Pg/g
0.426 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
101
Pg/g
0.458 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
0.638 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
201
Pg/g
1.01 10.0
51207-31-9
2,3,7,8-TCDF
18.9
Pg/g
0.193 1.00
57117-41-6
1,2,3,7,8-PeCDF
96.9
Pg/g
0.286 5.00
57117-31-4
2,3,4,7,8-PeCDF
95.9
Pg/g
0.276 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
99.3
Pg/g
0.534 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
96.2
Pg/g
0.538 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
100
Pg/g
0.534 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
104
Pg/g
0.844 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
98.6
Pg/g
0.244 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
101
Pg/g
0.394 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
174
Pg/g
0.818 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
150
200
Pg/g
75.0
(20%-175%)
13C-1,2,3,7,8-
PeCDD
165
200
Pg/g
82.7
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
159
200
Pg/g
79.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
154
200
Pg/g
77.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
170
200
Pg/g
85.0
(22%-166%)
13C-OCDD
332
400
Pg/g
83.1
(13%-199%)
13C-2,3,7,8-TCDF
150
200
Pg/g
75.2
(22%-152%)
13C-1,2,3,7,8-
PeCDF
154
200
Pg/g
77.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
159
200
Pg/g
79.5
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
151
200
Pg/g
75.4
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
146
200
Pg/g
73.0
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
146
200
Pg/g
73.2
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
130
200
Pg/g
65.0
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
157
200
Pg/g
78.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
147
200
Pg/g
73.4
(20%-186%)
3701-2,3,7,8-TCDD
17.5
20.0
Pg/g
87.7
(31 %-191%)
Comments:
Page 20 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 1, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6066
12010325
QC for batch 25811
LCSD for batch 25811
25813
05/01/2014 00:04
A30APR14B-10
25811
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
29-APR-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
19.9
Pg/g
0.185
1.00
40321-76-4
1,2,3,7,8-PeCDD
96.5
Pg/g
0.252
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
96.1
Pg/g
0.500
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
100
Pg/g
0.550
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
99.6
Pg/g
0.558
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
0.554
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
196
Pg/g
1.27
10.0
51207-31-9
2,3,7,8-TCDF
18.7
Pg/g
0.167
1.00
57117-41-6
1,2,3,7,8-PeCDF
97.0
Pg/g
0.340
5.00
57117-31-4
2,3,4,7,8-PeCDF
95.3
Pg/g
0.330
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
101
Pg/g
0.482
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
101
Pg/g
0.488
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
99.1
Pg/g
0.518
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
105
Pg/g
0.750
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
99.9
Pg/g
0.480
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.6
Pg/g
0.810
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
176
Pg/g
0.694
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
159
200
Pg/g
79.4
(20%-175%)
13C-1,2,3,7,8-PeCDD
178
200
Pg/g
88.8
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
166
200
Pg/g
82.9
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
162
200
Pg/g
81.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
177
200
Pg/g
88.7
(22%-166%)
13C-OCDD
342
400
Pg/g
85.4
(13%-199%)
13C-2,3,7,8-TCDF
159
200
Pg/g
79.6
(22%-152%)
13C-1,2,3,7,8-PeCDF
165
200
Pg/g
82.6
(21%-192%)
13C-2,3,4,7,8-PeCDF
169
200
Pg/g
84.6
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
154
200
Pg/g
77.0
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
150
200
Pg/g
75.2
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
155
200
Pg/g
77.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
135
200
Pg/g
67.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
161
200
Pg/g
80.7
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
150
200
Pg/g
75.1
(20%-186%)
37Cl-2,3,7,8-TCDD
17.1
20.0
Pg/g
85.5
(31 %-191%)
Comments:
Page 21 of 21
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
May 05. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6074
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on May 01, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of23
problem solved
-------
T
Page:
Project #:
CFA Quote#:
COC Number(l):
PO Number:
of
Client Name^g-^
Cape Fear Analytical, LLC
Chain of Custody anc^ Analytical Request
CFA Work Order Number:
!ustody andi
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Sample Analysis Requested<5) (Fill in the number of containers for each test)
jj jftrojeet/SiteName: &*cs(
Fax#:
a>it
Address:
ci
i Collected by: ^
Send Results To:
idfci Ml
^4 Hrfut/i KfitWfzC #ej
Sample ID
* For composites - indicate start and stop date/time
•Date Collected
(mm-dd-yy)
•Thne
Collected
(Military)
(hhmm)
QCCode
m
Field
Filtered(3>
Sample
Matrix™
ft
5
Vi
<- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
£!£.
fx
€nSv> JT'Qif'JrY *¦//
4%ss4
-Jg
/fejf
d/A
K
i: Specify: ^Subject to Surcharge)
TAT Requested: Normal:
Rush:
Fax Results:
Yes
No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 /yj^evel 3/ / Level 4
Remarks; Are there any known hazards applicable to these samples? If so, please list the hazards
Sample Collection Time Zone
Eastern Pacific
Central- Other _
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Date
Time
fee-/*! (j(o
Received by (signed) Date
Time
DiHlflV/4 33
CFA PM: Cy Ack
Method of Shipment:
¦yU<*T/C
Date Shipped:
Airbill#: feva,?xr^- ott/r
Airbill #:
1.) Chain of Custody Number - Client Determined
2.) QC Codes: N - Normal Sample, TO - Trip Blank, FD - Field Duplicate, EB - Equipment Blank, MS - Matrix Spike Sample, MSD = Matrix Spike Duplicate Sample, G - Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with »¦ Y - for yes the sample was field filtered or- N - for sample ox not field filtered,
4.) Matrix Codes: DW=Drinking Water,GW=Groundwater, SW=Surface Water, WW=Waste Water, W-Water, ML-Misc Liquid, SO"Soil. SD-Sediment, SL"S!udge, SS-Solid Waste, O-Oil, Wilier, P=Wipe, U-Urfaw, F-Fecal, N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.e£29#B, ltfSB) and number of containers provided for each (ix.S299B -3,1M8B-1),
6.) Preservative Type: HA = Hydrochloric Acid,NI = Nitric Acid, SH = Sodium Hydroxide, SA = Sulfuric Acid, AA " Ascorbic Acid,HX - Hexane. ST - Sodium Thtoailfate, If no preservative is added - leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intact?
YES NO
Coi
emp:
' C
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
Work Order: Q '
Received By:
Date/Time Received: ^ 0^3^
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
Samples identified as Foreign Soil?
DOE Site Sample Packages
Yes
NA
No*
Screened <0.5 mR/hr?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received intact
and sealed?
Circle Applicable:
seais broken damaged container leaking container other(describe)
Chain of Custody documents included
with shipment?
Samples requiring cold preservation
within 0-6°C?
at ion Method:
blue ice dry ice none other (describe}
Samples requiring chemical
preservation at proper pH?
Sample IDs, containers affected and pH observed:
If preservative added, Lot#:
Samples requiring preservation have
no residual chlorine?
Sample SDs, containers affected:
If preservative added, Lot#:
Sample IDs, tests affected;
Samples received within holding time?
Sample IDs on COC match IDs on
containers?
Sample IDs, containers affected:
lS
Date & time of COC match date & time
on containers?
Sample IDs, containers affected:
Number of containers received match
number indicated on COC?
L/
/
Sample IDs, containers affected:
T
10
COC form is properly signed in
relinquished/received sections?
Comments;
Checklist performed by: Initials:
it
Date:
Page 3 of23
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 23
-------
Case Narrative
Page 5 of23
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6074
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25847
Clean Up Batch Number: 25846
Extraction Batch Number: 25845
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6074001 SFRA-28
6074002 SFRA-29
6074003 SFRA-30
12010349 Method Blank (MB)
12010350 Laboratory Control Sample (LCS)
12010351 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Page 6 of 23
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
Sample 6074003 (SFRA-30)- Batch 25847 was diluted due to the presence of over-range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 7 of23
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 23
-------
Sample Data Summary
Page 9 of 23
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6074 CFA Work Order: 6074
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 05 MAY 2014 Title: Data Validator
Page 10 of 23
-------
Cape Fear Analytical LLC
Report Date:
May 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6074
Lab Sample ID: 6074001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/29/2014 16:38
05/01/2014 09:33
Project: TETR00114
Matrix: SOLID
%Moisture: 17.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-28
25847
05/02/2014 23:41
A02MAY14B2-4
25845
01-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.01 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1220
Pg/g
1.98 12.1
40321-76-4
1,2,3,7,8-PeCDD
U
2.51
Pg/g
2.51 60.3
39227-28-6
1,2,3,4,7,8-HxCDD
u
3.66
Pg/g
3.66 60.3
57653-85-7
1,2,3,6,7,8-HxCDD
u
7.96
Pg/g
7.96 60.3
19408-74-3
1,2,3,7,8,9-HxCDD
J
4.48
Pg/g
3.93 60.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
147
Pg/g
6.32 60.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
3870
Pg/g
18.0 121
51207-31-9
2,3,7,8-TCDF
J
11.2
Pg/g
3.50 12.1
57117-41-6
1,2,3,7,8-PeCDF
J
21.0
Pg/g
2.80 60.3
57117-31-4
2,3,4,7,8-PeCDF
u
2.72
Pg/g
2.72 60.3
70648-26-9
1,2,3,4,7,8-HxCDF
u
7.98
Pg/g
7.98 60.3
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.6
Pg/g
2.60 60.3
60851-34-5
2,3,4,6,7,8-HxCDF
J
4.07
Pg/g
2.84 60.3
72918-21-9
1,2,3,7,8,9-HxCDF
u
4.34
Pg/g
4.34 60.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
28.4
Pg/g
0.504 60.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
3.30
Pg/g
0.916 60.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
69.2
Pg/g
6.53 121
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1660
2410
Pg/g
68.8
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1730
2410
Pg/g
71.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1730
2410
Pg/g
71.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1810
2410
Pg/g
75.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1790
2410
Pg/g
74.0
(23%-140%)
13C-OCDD
3110
4820
Pg/g
64.5
(17%-157%)
13C-2,3,7,8-TCDF
1720
2410
Pg/g
71.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
1730
2410
Pg/g
71.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1680
2410
Pg/g
69.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1720
2410
Pg/g
71.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1720
2410
Pg/g
71.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1700
2410
Pg/g
70.5
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1460
2410
Pg/g
60.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1770
2410
Pg/g
73.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1490
2410
Pg/g
61.8
(26%-13 8%)
3701-2,3,7,8-TCDD
199
241
Pg/g
82.4
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 23
-------
Cape Fear Analytical LLC
Report Date:
May 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6074
Lab Sample ID: 6074002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/30/2014 11:05
05/01/2014 09:33
Project: TETR00114
Matrix: SOLID
%Moisture: 20.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-29
25847
05/03/2014 00:29
A02MAY14B2-5
25845
01-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.33 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
J
7.92
Pg/g
1.17 9.46
40321-76-4
1,2,3,7,8-PeCDD
U
1.47
Pg/g
1.47 47.3
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.38
Pg/g
2.38 47.3
57653-85-7
1,2,3,6,7,8-HxCDD
J
2.70
Pg/g
2.57 47.3
19408-74-3
1,2,3,7,8,9-HxCDD
u
2.63
Pg/g
2.63 47.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
149
Pg/g
7.45 47.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8210
Pg/g
21.4 94.6
51207-31-9
2,3,7,8-TCDF
u
1.21
Pg/g
1.21 9.46
57117-41-6
1,2,3,7,8-PeCDF
u
1.08
Pg/g
1.08 47.3
57117-31-4
2,3,4,7,8-PeCDF
u
.842
Pg/g
0.842 47.3
70648-26-9
1,2,3,4,7,8-HxCDF
u
1.16
Pg/g
1.16 47.3
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.11
Pg/g
1.11 47.3
60851-34-5
2,3,4,6,7,8-HxCDF
u
1.22
Pg/g
1.22 47.3
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.95
Pg/g
1.95 47.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
5.96
Pg/g
0.318 47.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.579
Pg/g
0.579 47.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
22.4
Pg/g
4.61 94.6
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1400
1890
Pg/g
74.1
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1400
1890
Pg/g
74.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1450
1890
Pg/g
76.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1470
1890
Pg/g
77.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1530
1890
Pg/g
80.7
(23%-140%)
13C-OCDD
2900
3780
Pg/g
76.7
(17%-157%)
13C-2,3,7,8-TCDF
1450
1890
Pg/g
76.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1400
1890
Pg/g
73.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
1340
1890
Pg/g
70.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1440
1890
Pg/g
76.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1460
1890
Pg/g
77.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1430
1890
Pg/g
75.7
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1240
1890
Pg/g
65.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1530
1890
Pg/g
81.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1330
1890
Pg/g
70.4
(26%-13 8%)
3701-2,3,7,8-TCDD
172
189
Pg/g
91.2
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 23
-------
Cape Fear Analytical LLC
Report Date:
May 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6074
Lab Sample ID: 6074003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
04/30/201411:12
05/01/2014 09:33
Project: TETR00114
Matrix: SOLID
%Moisture: 31.8
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-30
25847
05/05/2014 15:10
A05MA Y14C-3
25845
01-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.08 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
11000
Pg/g
25.5 136
40321-76-4
1,2,3,7,8-PeCDD
U
42.3
Pg/g
42.3 678
39227-28-6
1,2,3,4,7,8-HxCDD
u
61.3
Pg/g
61.3 678
57653-85-7
1,2,3,6,7,8-HxCDD
J
268
Pg/g
105 678
19408-74-3
1,2,3,7,8,9-HxCDD
J
90.2
Pg/g
86.6 678
35822-46-9
1,2,3,4,6,7,8-HpCDD
2040
Pg/g
96.3 678
3268-87-9
1,2,3,4,6,7,8,9-OCDD
16500
Pg/g
339 1360
51207-31-9
2,3,7,8-TCDF
J
74.5
Pg/g
36.4 136
57117-41-6
1,2,3,7,8-PeCDF
J
31.9
Pg/g
29.0 678
57117-31-4
2,3,4,7,8-PeCDF
u
26.6
Pg/g
26.6 678
70648-26-9
1,2,3,4,7,8-HxCDF
u
54.6
Pg/g
54.6 678
57II7.44.9
1,2,3,6,7,8-HxCDF
u
47.1
Pg/g
47.1 678
60851-34-5
2,3,4,6,7,8-HxCDF
J
45.9
Pg/g
34.2 678
72918-21-9
1,2,3,7,8,9-HxCDF
u
88.5
Pg/g
88.5 678
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
537
Pg/g
22.5 678
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
68.9
Pg/g
26.0 678
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
1150
Pg/g
84.1 1360
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1700
2710
Pg/g
62.6
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1520
2710
Pg/g
56.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2280
2710
Pg/g
83.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1830
2710
Pg/g
67.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2030
2710
Pg/g
75.0
(23%-140%)
13C-OCDD
5210
5430
Pg/g
96.0
(17%-157%)
13C-2,3,7,8-TCDF
1760
2710
Pg/g
65.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
1530
2710
Pg/g
56.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1600
2710
Pg/g
59.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2270
2710
Pg/g
83.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2450
2710
Pg/g
90.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2530
2710
Pg/g
93.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1570
2710
Pg/g
58.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1920
2710
Pg/g
70.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2590
2710
Pg/g
95.4
(26%-13 8%)
3701-2,3,7,8-TCDD
228
271
Pg/g
84.0
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 23
-------
Quality Control
Summary
Page 14 of 23
-------
Cape Fear Analytical LLC Report Date: May 5,2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6074
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010350
LCS for batch 25845
12010351
LCSD for batch 25845
12010349
MB for batch 25845
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
70.4
75.6
74.2
74.2
76.1
67.9
70.1
75.9
74.1
73.4
73.2
73.7
60.8
75.8
65.9
88.3
73.1
77.3
75.4
77.8
80.3
73.5
71.4
75.4
71.2
78.6
76.8
75.6
63.5
75.9
69.5
89.3
74.2
78.7
77.9
80.8
83.7
72.9
73.7
78.2
76.2
77.4
78.4
78.4
67.8
80.6
71.0
93.0
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6074001
SFRA-28
13C-2,3,7,8-TCDD
(25%-164%)
Page 15 of 23
-------
Cape Fear Analytical LLC Report Date: May 5,2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6074
Matrix Type: SOLID
Sample ID Client ID
6074001 SFRA-28
6074002 SFRA-29
6074003 SFRA-30
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
71.9
(25%-181%)
71.7
(32%-141%)
75.1
(28%-130%)
74.0
(23%-140%)
64.5
(17%-15 7%)
71.5
(24%-169%)
71.6
(24%-185%)
69.7
(21%-178%)
71.3
(26%-152%)
71.5
(26%-123%)
70.5
(28%-13 6%)
60.5
(29%-147%)
73.3
(28%-143%)
61.8
(26%-13 8%)
82.4
(35%-197%)
74.1
(25%-164%)
74.2
(25%-181%)
76.5
(32%-141%)
77.8
(28%-130%)
80.7
(23%-140%)
76.7
(17%-15 7%)
76.7
(24%-169%)
73.9
(24%-185%)
70.7
(21%-178%)
76.3
(26%-152%)
77.3
(26%-123%)
75.7
(28%-13 6%)
65.4
(29%-147%)
81.0
(28%-143%)
70.4
(26%-13 8%)
91.2
(35%-197%)
62.6
D
(25%-164%)
56.2
D
(25%-181%)
83.9
D
(32%-141%)
67.3
D
(28%-130%)
75.0
D
(23%-140%)
96.0
D
(17%-15 7%)
65.0
D
(24%-169%)
56.2
D
(24%-185%)
59.1
D
(21%-178%)
83.8
D
(26%-152%)
90.2
D
(26%-123%)
93.1
D
(28%-13 6%)
58.0
D
(29%-147%)
70.7
D
(28%-143%)
95.4
D
(26%-13 8%)
84.0
D
(35%-197%)
* Recovery outside Acceptance Limits
Page 16 of 23
-------
Cape Fear Analytical LLC Report Date: May 5,2014
Hi-Res Dioxins/Furans Page 3 of 3
Surrogate Recovery Report
SDG Number: 6074
Matrix Type: SOLID
Recovery Acceptance
Sample ID Client ID Surrogate qual l imits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 17 of 23
-------
Cape Fear Analytical LLC
Report Date: May 5,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 05/02/2014 21:19 Dilution: 1
Prep Batch ID:25845
Batch ID: 25847
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
19.9
99.6
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
96.2
96.2
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
93.8
93.8
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
98.1
98.1
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
99.8
99.8
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
91.2
91.2
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
190
95.2
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.7
93.5
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
96.2
96.2
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
96.6
96.6
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
95.8
95.8
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
99.4
99.4
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
97.9
97.9
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
100
100
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
93.0
93
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
98.0
98
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
177
88.6
63-170
SDG Number: 6074
Client ID: LCS for batch 25845
Lab Sample ID: 12010350
Instrument: HRP750
Analyst: JTF
Page
18 of 23
-------
Cape Fear Analytical LLC
Report Date: May 5,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 05/02/2014 22:05 Dilution: 1
Prep Batch ID:25845
Batch ID: 25847
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
19.2
95.9
67-158
3.72
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
92.8
92.8
70-142
3.60
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
93.4
93.4
70-164
0.406
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
94.9
94.9
76-134
3.25
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
95.6
95.6
64-162
4.36
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
92.5
92.5
70-140
1.37
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
190
95.2
78-144
0.0252
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.5
92.4
75-158
1.18
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
93.4
93.4
80-134
3.04
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
96.4
96.4
68-160
0.236
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
96.1
96.1
72-134
0.258
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
99.8
99.8
84-130
0.444
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
95.4
95.4
70-156
2.58
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
102
102
78-130
1.48
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
94.7
94.7
82-122
1.81
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
96.8
96.8
78-138
1.16
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
175
87.4
63-170
1.36
0-20
SDG Number: 6074
Client ID: LCSD for batch 25845
Lab Sample ID: 12010351
Instrument: HRP750
Analyst: JTF
Page
19 of 23
-------
Cape Fear Analytical LLC
Report Date: May 5, 2014
Method Blank Summary Page ' °' '
SDG Number: 6074
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 25845
Instrument ID:
HRP750
Data File:
A02MAY14B 2-3
Lab Sample ID: 12010349
Column:
Prep Date:
01-MAY-14
Analyzed:
05/02/14 22:53
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 25845
12010350
A02M AY 14B2-1
05/02/14
2119
02 LCSD for batch 25845
12010351
A02M AY 14B2-2
05/02/14
2205
03 SFRA-28
6074001
A02M AY 14B2-4
05/02/14
2341
04 SFRA-29
6074002
A02MAY14B2-5
05/03/14
0029
05 SFRA-30
6074003
A05MAY14C-3
05/05/14
1510
Page 20 of 23
-------
Cape Fear Analytical LLC
Report Date:
May 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6074
Lab Sample ID: 12010349
Client Sample: ^or batch 25845
Client ID: MB for batch 25845
Batch ID: 25847
Run Date: 05/02/2014 22:53
Data File: A02MAY14B 2-3
Prep Batch: 25845
Prep Date: 01-MAY-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.11
Pg/g
0.110 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.33
Pg/g
0.330 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.173
Pg/g
0.173 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.179
Pg/g
0.179 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.352
Pg/g
0.352 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.258
Pg/g
0.230 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
0.724
Pg/g
0.570 10.0
51207-31-9
2,3,7,8-TCDF
u
.133
Pg/g
0.133 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.22
Pg/g
0.220 5.00
57117-31-4
2,3,4,7,8-PeCDF
J
0.242
Pg/g
0.0814 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.224
Pg/g
0.224 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.21
Pg/g
0.210 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.224
Pg/g
0.189 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.41
Pg/g
0.410 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.168
Pg/g
0.0746 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
0.288
Pg/g
0.137 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.476
Pg/g
0.476 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
148
200
Pg/g
74.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
157
200
Pg/g
78.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
156
200
Pg/g
77.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
162
200
Pg/g
80.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
167
200
Pg/g
83.7
(23%-140%)
13C-OCDD
292
400
Pg/g
72.9
(17%-157%)
13C-2,3,7,8-TCDF
147
200
Pg/g
73.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
156
200
Pg/g
78.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
152
200
Pg/g
76.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
155
200
Pg/g
77.4
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
157
200
Pg/g
78.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
157
200
Pg/g
78.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
136
200
Pg/g
67.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
161
200
Pg/g
80.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
142
200
Pg/g
71.0
(26%-13 8%)
3701-2,3,7,8-TCDD
18.6
20.0
Pg/g
93.0
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 21 of 23
-------
Cape Fear Analytical LLC
Report Date:
May 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6074
Lab Sample ID: 12010350
Client Sample: ^or batch 25845
Client ID: LCS for batch 25845
Batch ID: 25847
Run Date: 05/02/2014 21:19
Data File: A02MAY14B 2-1
Prep Batch: 25845
Prep Date: 01-MAY-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
19.9
Pg/g
0.161 1.00
40321-76-4
1,2,3,7,8-PeCDD
96.2
Pg/g
0.342 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
93.8
Pg/g
0.458 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.1
Pg/g
0.464 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
99.8
Pg/g
0.490 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
91.2
Pg/g
0.662 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
190
Pg/g
1.23 10.0
51207-31-9
2,3,7,8-TCDF
18.7
Pg/g
0.177 1.00
57117-41-6
1,2,3,7,8-PeCDF
96.2
Pg/g
0.298 5.00
57117-31-4
2,3,4,7,8-PeCDF
96.6
Pg/g
0.304 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
95.8
Pg/g
0.382 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
99.4
Pg/g
0.380 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
97.9
Pg/g
0.400 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
100
Pg/g
0.652 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
93.0
Pg/g
0.262 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
98.0
Pg/g
0.464 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
177
Pg/g
1.17 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
141
200
Pg/g
70.4
(20%-175%)
13C-1,2,3,7,8-
PeCDD
151
200
Pg/g
75.6
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
148
200
Pg/g
74.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
148
200
Pg/g
74.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
152
200
Pg/g
76.1
(22%-166%)
13C-OCDD
271
400
Pg/g
67.9
(13%-199%)
13C-2,3,7,8-TCDF
140
200
Pg/g
70.1
(22%-152%)
13C-1,2,3,7,8-
PeCDF
152
200
Pg/g
75.9
(21%-192%)
130-2,3,4,7,8-
PeCDF
148
200
Pg/g
74.1
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
147
200
Pg/g
73.4
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
146
200
Pg/g
73.2
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
147
200
Pg/g
73.7
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
122
200
Pg/g
60.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
152
200
Pg/g
75.8
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
132
200
Pg/g
65.9
(20%-186%)
3701-2,3,7,8-TCDD
17.7
20.0
Pg/g
88.3
(31 %-191%)
Comments:
Page 22 of 23
-------
Cape Fear Analytical LLC
Report Date:
May 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6074
Lab Sample ID: 12010351
Client Sample: ^or batch 25845
Client ID: LCSD for batch 25845
Batch ID: 25847
Run Date: 05/02/2014 22:05
Data File: A02MAY14B 2-2
Prep Batch: 25845
Prep Date: 01-MAY-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
19.2
Pg/g
0.132 1.00
40321-76-4
1,2,3,7,8-PeCDD
92.8
Pg/g
0.316 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
93.4
Pg/g
0.550 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
94.9
Pg/g
0.602 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
95.6
Pg/g
0.612 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
92.5
Pg/g
0.646 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
190
Pg/g
1.44 10.0
51207-31-9
2,3,7,8-TCDF
18.5
Pg/g
0.177 1.00
57117-41-6
1,2,3,7,8-PeCDF
93.4
Pg/g
0.272 5.00
57117-31-4
2,3,4,7,8-PeCDF
96.4
Pg/g
0.274 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
96.1
Pg/g
0.494 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
99.8
Pg/g
0.480 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
95.4
Pg/g
0.524 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
102
Pg/g
0.788 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
94.7
Pg/g
0.252 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
96.8
Pg/g
0.424 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
175
Pg/g
1.16 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
146
200
Pg/g
73.1
(20%-175%)
130-1,2,3,7,8-
PeCDD
155
200
Pg/g
77.3
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
151
200
Pg/g
75.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
156
200
Pg/g
77.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
161
200
Pg/g
80.3
(22%-166%)
13C-OCDD
294
400
Pg/g
73.5
(13%-199%)
13C-2,3,7,8-TCDF
143
200
Pg/g
71.4
(22%-152%)
130-1,2,3,7,8-
PeCDF
151
200
Pg/g
75.4
(21%-192%)
130-2,3,4,7,8-
PeCDF
142
200
Pg/g
71.2
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
157
200
Pg/g
78.6
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
154
200
Pg/g
76.8
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
151
200
Pg/g
75.6
(22%-176%)
130-1,2,3,7,8,9-HxCDF
127
200
Pg/g
63.5
(17%-205%)
130-1,2,3,4,6,7,8-HpCDF
152
200
Pg/g
75.9
(21%-15 8%)
130-1,2,3,4,7,8,9-HpCDF
139
200
Pg/g
69.5
(20%-186%)
3701-2,3,7,8-TCDD
17.9
20.0
Pg/g
89.3
(31 %-191%)
Comments:
Page 23 of 23
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
May 08. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6086
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on May 05, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 26
problem solved
-------
Page;
Project #:
CFA Quote #: ___
COC Number
PO Number:
-L
.of L
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number; (g? 0) Q?
TJrf^Tf^W
Cape Few Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Name: ^ ^ ^ ,
Phone #
Sample Analysis Requested (Fill in the number of containers for each test)
SWoject^iteName^,^ Xk.ufe/ JcL»
Fax#:
t- Address. fo J) r ] „
b fcolleeted by: £
Send Results
To: v
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client: f £-T
work Order:
Received By:
Date/Time Received: QSO/l^H Q^OO
Suspected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
Mo*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
Samples identified as Foreign Soil?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
i—-
'¦
Circle Applicable:
seals broken damaged container leaking container other(describe)
2
Chain of Custody documents included
with shipment?
3
Samples requiring cold preservation
within 0-6"C?
Preservation Method:
ice bags blue ice dry ice pone j other (describe)
H.pc
4
Samples requiring chemical
preservation at proper pH?
v/
Sample IDs, containers affected and pH observed:
If preservative added, tot#:
5
Samples requiring preservation have
no residual chlorine?
Sample IDs, containers affected:
If preservative added, Lot#:
6
Samples received within holding time?
.y
Sample IDs, tests affected:
7
Sample IDs on COC match IDs on
containers?
v/
/'*
Sample IDs, containers affected:
8
Date & time of COC match date & time
on containers?
Sample IDs, containers affected:
9
Number of containers received match
number indicated on COC?
y
Sample IDs, containers affected:
10
COC form is properly signed in
relinquished/received sections?
V
y\
Comments:
_ Date:,
Checklist performed by: Initials:.
Page 3 of 26
-------
Seewald Samples
Subject: Seewald Samples
From: Valerie Davis
Date: 5/2/2014 5:16 PM
To: Cynde Larkins , Chris Cornwell
, Mike Larkins , Heather
Patterson
We will receive three dioxin samples on Monday for 72 hour TAT. The samples will not be
shipped on ice. Please document the nonconformance on the SRR and proceed with the
analysis. Please contact Dave Kinroth with questions.
Have a great weekend!
Valerie Davis
Project Manager
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd.
Suite 120
Wilmington, NC 28405
Phone: 910-795-0421
E-mail: /is(3ef< ;om
lofl
Page 4 of 26
5/5/2014 9:24 AM
-------
High Resolution Dioxins
and Furans Analysis
Page 5 of 26
-------
Case Narrative
Page 6 of 26
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6086
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25868
Clean Up Batch Number: 25867
Extraction Batch Number: 25866
Sample Analysis
The following samples were analyzed using the analytical protocol as established in :
Sample ID Client ID
6086001 SFRA-31
6086002 SFRA-32
6086003 SFRA-33
12010370 Method Blank (MB)
12010371 Laboratory Control Sample (LCS)
12010372 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 7 of 26
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
Samples 6086001 (SFRA-31) and 6086003 (SFRA-33)- Batch 25868 were diluted due to the
presence of over-range target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Page 8 of 26
-------
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 9 of 26
-------
Sample Data Summary
Page 10 of 26
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6086 CFA Work Order: 6086
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 08 MAY 2014 Title: Data Validator
Page 11 of 26
-------
Cape Fear Analytical LLC
Report Date:
May 8, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6086
Lab Sample ID: 6086001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/02/2014 10:53
05/05/2014 09:00
Project: TETR00114
Matrix: SOLID
%Moisture: 24.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-31
25868
05/07/2014 12:32
A07MAY14A-6
25866
05-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.02 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20300
Pg/g
19.1 131
40321-76-4
1,2,3,7,8-PeCDD
U
32.4
Pg/g
32.4 653
39227-28-6
1,2,3,4,7,8-HxCDD
J
36.5
Pg/g
22.0 653
57653-85-7
1,2,3,6,7,8-HxCDD
J
190
Pg/g
21.9 653
19408-74-3
1,2,3,7,8,9-HxCDD
J
62.0
Pg/g
23.3 653
35822-46-9
1,2,3,4,6,7,8-HpCDD
1560
Pg/g
45.5 653
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13900
Pg/g
103 1310
51207-31-9
2,3,7,8-TCDF
J
101
Pg/g
28.0 131
57117-41-6
1,2,3,7,8-PeCDF
u
11.2
Pg/g
11.2 653
57117-31-4
2,3,4,7,8-PeCDF
J
17.5
Pg/g
10.6 653
70648-26-9
1,2,3,4,7,8-HxCDF
J
44.3
Pg/g
13.1 653
57II7.44.9
1,2,3,6,7,8-HxCDF
J
28.3
Pg/g
12.0 653
60851-34-5
2,3,4,6,7,8-HxCDF
J
36.5
Pg/g
12.3 653
72918-21-9
1,2,3,7,8,9-HxCDF
u
22.5
Pg/g
22.5 653
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
645
Pg/g
4.00 653
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
31.9
Pg/g
31.9 653
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
501
Pg/g
34.2 1310
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2130
2610
Pg/g
81.7
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2320
2610
Pg/g
88.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2260
2610
Pg/g
86.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2380
2610
Pg/g
91.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2330
2610
Pg/g
89.3
(23%-140%)
13C-OCDD
4290
5220
Pg/g
82.2
(17%-157%)
13C-2,3,7,8-TCDF
2120
2610
Pg/g
81.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
2160
2610
Pg/g
82.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
2230
2610
Pg/g
85.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2050
2610
Pg/g
78.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2160
2610
Pg/g
82.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2130
2610
Pg/g
81.5
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1760
2610
Pg/g
67.6
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2210
2610
Pg/g
84.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1930
2610
Pg/g
74.0
(26%-13 8%)
3701-2,3,7,8-TCDD
317
261
Pg/g
121
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 26
-------
Cape Fear Analytical LLC
Report Date:
May 8, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6086
Lab Sample ID: 6086002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/02/2014 11:00
05/05/2014 09:00
Project: TETR00114
Matrix: SOLID
%Moisture: 20.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-32
25868
05/07/2014 11:44
A07MAY14A-5
25866
05-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
ii §
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3190
Pg/g
4.44 11.4
40321-76-4
1,2,3,7,8-PeCDD
U
5.04
Pg/g
5.04 57.2
39227-28-6
1,2,3,4,7,8-HxCDD
J
12.5
Pg/g
4.60 57.2
57653-85-7
1,2,3,6,7,8-HxCDD
J
29.7
Pg/g
4.35 57.2
19408-74-3
1,2,3,7,8,9-HxCDD
J
12.5
Pg/g
4.74 57.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
510
Pg/g
13.1 57.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
10900
Pg/g
19.8 114
51207-31-9
2,3,7,8-TCDF
20.8
Pg/g
4.81 11.4
57117-41-6
1,2,3,7,8-PeCDF
J
17.8
Pg/g
4.14 57.2
57117-31-4
2,3,4,7,8-PeCDF
u
4.03
Pg/g
4.03 57.2
70648-26-9
1,2,3,4,7,8-HxCDF
u
11.2
Pg/g
11.2 57.2
57II7.44.9
1,2,3,6,7,8-HxCDF
J
5.20
Pg/g
3.46 57.2
60851-34-5
2,3,4,6,7,8-HxCDF
u
6.98
Pg/g
6.98 57.2
72918-21-9
1,2,3,7,8,9-HxCDF
u
5.91
Pg/g
5.91 57.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
92.9
Pg/g
0.957 57.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
8.49
Pg/g
1.68 57.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
137
Pg/g
7.83 114
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1850
2290
Pg/g
81.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1880
2290
Pg/g
82.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1890
2290
Pg/g
82.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1980
2290
Pg/g
86.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1980
2290
Pg/g
86.3
(23%-140%)
13C-OCDD
3970
4580
Pg/g
86.7
(17%-157%)
13C-2,3,7,8-TCDF
1860
2290
Pg/g
81.3
(24%-169%)
130-1,2,3,7,8-
PeCDF
1780
2290
Pg/g
77.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1810
2290
Pg/g
79.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1780
2290
Pg/g
77.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1800
2290
Pg/g
78.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1830
2290
Pg/g
79.8
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1560
2290
Pg/g
68.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1880
2290
Pg/g
82.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1670
2290
Pg/g
73.0
(26%-13 8%)
3701-2,3,7,8-TCDD
222
229
Pg/g
97.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 26
-------
Cape Fear Analytical LLC
Report Date: May 8, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6086
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6086002
Date Collected:
05/02/2014 11:00
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
05/05/2014 09:00
%Moisture:
20.6
Client ID:
SFRA-32
Prep Basis:
Dry Weight
Batch ID:
25868
Method:
EPA Method 1613B
Run Date:
05/07/2014 20:13
Analyst:
JTF
Instrument:
HRP763
Data File:
b07mayl4f 2-3
Dilution:
1
Prep Batch:
25866
Prep Method:
SW846 3540C
Prep Date:
05-MAY-14
Prep Aliquot:
11 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
22.5
Pg/g
2.22
11.4
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 26
-------
Cape Fear Analytical LLC
Report Date:
May 8, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6086
6086003
1613B Soil
SFRA-33
25868
05/07/2014 13:19
A07MAY14A-7
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
05/02/2014 10:00
05/05/2014 09:00
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
22.1
Dry Weight
HRP750
10
Prep Batch:
25866
Prep Method:
SW846 3540C
Prep Date:
05-MAY-14
Prep Aliquot:
1.14 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
24400
Pg/g
51.3 113
40321-76-4
1,2,3,7,8-PeCDD
U
16.4
Pg/g
16.4 563
39227-28-6
1,2,3,4,7,8-HxCDD
u
52.7
Pg/g
52.7 563
57653-85-7
1,2,3,6,7,8-HxCDD
u
49.3
Pg/g
49.3 563
19408-74-3
1,2,3,7,8,9-HxCDD
u
53.8
Pg/g
53.8 563
35822-46-9
1,2,3,4,6,7,8-HpCDD
704
Pg/g
81.3 563
3268-87-9
1,2,3,4,6,7,8,9-OCDD
10700
Pg/g
175 1130
51207-31-9
2,3,7,8-TCDF
147
Pg/g
38.5 113
57117-41-6
1,2,3,7,8-PeCDF
u
14.6
Pg/g
14.6 563
57117-31-4
2,3,4,7,8-PeCDF
u
14
Pg/g
14.0 563
70648-26-9
1,2,3,4,7,8-HxCDF
u
24.5
Pg/g
24.5 563
57II7.44.9
1,2,3,6,7,8-HxCDF
u
24.5
Pg/g
24.5 563
60851-34-5
2,3,4,6,7,8-HxCDF
u
27.9
Pg/g
27.9 563
72918-21-9
1,2,3,7,8,9-HxCDF
u
47
Pg/g
47.0 563
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
158
Pg/g
12.9 563
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
22.5
Pg/g
22.5 563
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
220
Pg/g
74.5 1130
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1850
2250
Pg/g
82.0
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1850
2250
Pg/g
82.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1700
2250
Pg/g
75.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1940
2250
Pg/g
86.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1800
2250
Pg/g
80.0
(23%-140%)
13C-OCDD
3440
4500
Pg/g
76.3
(17%-157%)
13C-2,3,7,8-TCDF
1790
2250
Pg/g
79.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1780
2250
Pg/g
79.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1820
2250
Pg/g
80.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1650
2250
Pg/g
73.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1710
2250
Pg/g
76.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1750
2250
Pg/g
77.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1390
2250
Pg/g
61.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1810
2250
Pg/g
80.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1610
2250
Pg/g
71.3
(26%-13 8%)
3701-2,3,7,8-TCDD
286
225
Pg/g
127
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 26
-------
Cape Fear Analytical LLC
Report Date: May 8, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6086
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6086003
Date Collected:
05/02/2014 10:00
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
05/05/2014 09:00
%Moisture:
22.1
Client ID:
SFRA-33
Prep Basis:
Dry Weight
Batch ID:
25868
Method:
EPA Method 1613B
Run Date:
05/07/2014 20:52
Analyst:
JTF
Instrument:
HRP763
Data File:
b07mayl4f 2-5
Dilution:
10
Prep Batch:
25866
Prep Method:
SW846 3540C
Prep Date:
05-MAY-14
Prep Aliquot:
1.14 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
154
Pg/g
14.4
113
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 26
-------
Quality Control
Summary
Page 17 of 26
-------
Cape Fear Analytical LLC Report Date: May 8,2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6086
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010371
LCS for batch 25866
12010372
LCSD for batch 25866
12010370
MB for batch 25866
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
74.2
77.5
77.0
82.0
80.3
74.0
75.4
70.8
73.5
72.8
73.6
75.9
61.9
77.9
68.7
86.3
71.4
78.3
77.5
78.3
81.3
75.8
72.8
77.4
75.1
72.7
72.5
72.9
61.7
76.6
66.9
79.6
82.2
86.4
84.5
83.7
87.9
85.4
82.4
81.7
81.7
78.5
77.6
79.2
68.5
83.4
74.9
92.1
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6086002
SFRA-32
13C-2,3,7,8-TCDD
81.0
(25%-164%)
Page 18 of 26
-------
Cape Fear Analytical LLC Report Date: May 8,2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6086
Matrix Type: SOLID
Sample ID Client ID
6086002 SFRA-32
6086001 SFRA-31
6086003 SFRA-33
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
82.0
(25%-181%)
82.4
(32%-141%)
86.5
(28%-130%)
86.3
(23%-140%)
86.7
(17%-15 7%)
81.3
(24%-169%)
77.7
(24%-185%)
79.0
(21%-178%)
77.8
(26%-152%)
78.7
(26%-123%)
79.8
(28%-13 6%)
68.0
(29%-147%)
82.1
(28%-143%)
73.0
(26%-13 8%)
97.2
(35%-197%)
81.7
D
(25%-164%)
88.8
D
(25%-181%)
86.4
D
(32%-141%)
91.2
D
(28%-130%)
89.3
D
(23%-140%)
82.2
D
(17%-15 7%)
81.2
D
(24%-169%)
82.7
D
(24%-185%)
85.2
D
(21%-178%)
78.5
D
(26%-152%)
82.7
D
(26%-123%)
81.5
D
(28%-13 6%)
67.6
D
(29%-147%)
84.7
D
(28%-143%)
74.0
D
(26%-13 8%)
121
D
(35%-197%)
82.0
D
(25%-164%)
82.2
D
(25%-181%)
75.5
D
(32%-141%)
86.4
D
(28%-130%)
80.0
D
(23%-140%)
76.3
D
(17%-15 7%)
79.6
D
(24%-169%)
79.2
D
(24%-185%)
80.7
D
(21%-178%)
73.2
D
(26%-152%)
76.1
D
(26%-123%)
77.9
D
(28%-13 6%)
61.8
D
(29%-147%)
80.5
D
(28%-143%)
71.3
D
(26%-13 8%)
127
D
(35%-197%)
* Recovery outside Acceptance Limits
Page 19 of 26
-------
Cape Fear Analytical LLC Report Date: May 8,2014
Hi-Res Dioxins/Furans Page 3 of 3
Surrogate Recovery Report
SDG Number: 6086
Matrix Type: SOLID
Recovery Acceptance
Sample ID Client ID Surrogate qual l imits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 20 of 26
-------
Cape Fear Analytical LLC
Report Date: May 8,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 05/07/2014 09:22 Dilution: 1
Prep Batch ID:25866
Batch ID: 25868
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.9
109
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
98.9
98.9
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
96.7
96.7
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
101
101
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
103
103
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
100
100
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
204
102
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.2
90.9
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
101
101
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
96.4
96.4
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
101
101
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
97.9
97.9
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
101
101
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
104
104
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
98.2
98.2
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
99.1
99.1
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
184
91.8
63-170
SDG Number: 6086
Client ID: LCS for batch 25866
Lab Sample ID: 12010371
Instrument: HRP750
Analyst: JTF
Page 21 of 26
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Cape Fear Analytical LLC
Report Date: May 8,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 05/07/2014 10:09 Dilution: 1
Prep Batch ID:25866
Batch ID: 25868
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.9
104
67-158
4.69
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
99.9
99.9
70-142
0.970
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
97.1
97.1
70-164
0.469
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
105
105
76-134
4.40
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
107
107
64-162
3.77
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
97.8
97.8
70-140
2.30
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
201
101
78-144
1.33
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.7
93.6
75-158
2.94
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
96.2
96.2
80-134
5.20
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
98.0
98
68-160
1.63
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
97.7
97.7
72-134
3.06
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
100
100
84-130
2.19
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
104
104
70-156
2.85
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
104
104
78-130
0.434
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
102
102
82-122
4.19
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
99.8
99.8
78-138
0.756
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
179
89.4
63-170
2.67
0-20
SDG Number: 6086
Client ID: LCSD for batch 25866
Lab Sample ID: 12010372
Instrument: HRP750
Analyst: JTF
Page
22 of 26
-------
Cape Fear Analytical LLC
Report Date: May 8, 2014
Method Blank Summary Page ' °' '
SDG Number: 6086
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 25866
Instrument ID:
HRP750
Data File:
A07MA Y14A-4
Lab Sample ID: 12010370
Column:
Prep Date:
05-MAY-14
Analyzed:
05/07/14 10:56
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 25866
12010371
A07MAY14A-2
05/07/14
0922
02 LCSD for batch 25866
12010372
A07MAY14A-3
05/07/14
1009
03 SFRA-32
6086002
A07MAY14A-5
05/07/14
1144
04 SFRA-31
6086001
A07MAY14A-6
05/07/14
1232
05 SFRA-33
6086003
A07MAY14A-7
05/07/14
1319
06 SFRA-32
6086002
b07mayl4f_2-3
05/07/14
2013
07 SFRA-33
6086003
b07mayl4f_2-5
05/07/14
2052
Page 23 of 26
-------
Cape Fear Analytical LLC
Report Date:
May 8, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6086
12010370
QC for batch 25866
MB for batch 25866
25868
05/07/2014 10:56
A07MAY14A-4
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
25866
Prep Method:
SW846 3540C
Prep Date:
05-MAY-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
J
0.274
Pg/g
0.132
1.00
40321-76-4
1,2,3,7,8-PeCDD
U
.264
Pg/g
0.264
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.188
Pg/g
0.188
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.195
Pg/g
0.195
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.322
Pg/g
0.204
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.430
Pg/g
0.308
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
1.65
Pg/g
0.542
10.0
51207-31-9
2,3,7,8-TCDF
u
.142
Pg/g
0.142
1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.266
Pg/g
0.266
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.258
Pg/g
0.258
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.314
Pg/g
0.155
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.31
Pg/g
0.310
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.250
Pg/g
0.150
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.452
Pg/g
0.248
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.336
Pg/g
0.336
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.282
Pg/g
0.282
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
0.564
Pg/g
0.522
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
164
200
Pg/g
82.2
(25 %-164%)
13C-1,2,3,7,8-PeCDD
173
200
Pg/g
86.4
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
169
200
Pg/g
84.5
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
167
200
Pg/g
83.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
176
200
Pg/g
87.9
(23%-140%)
13C-OCDD
341
400
Pg/g
85.4
(17%-157%)
13C-2,3,7,8-TCDF
165
200
Pg/g
82.4
(24%-169%)
13C-1,2,3,7,8-PeCDF
163
200
Pg/g
81.7
(24%-185%)
13C-2,3,4,7,8-PeCDF
163
200
Pg/g
81.7
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
157
200
Pg/g
78.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
155
200
Pg/g
77.6
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
158
200
Pg/g
79.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
137
200
Pg/g
68.5
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
167
200
Pg/g
83.4
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
150
200
Pg/g
74.9
(26%-13 8%)
37Cl-2,3,7,8-TCDD
18.4
20.0
Pg/g
92.1
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 24 of 26
-------
Cape Fear Analytical LLC
Report Date:
May 8, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6086
Lab Sample ID: 12010371
Client Sample: ^or batch 25866
Client ID: LCS for batch 25866
Batch ID: 25868
Run Date: 05/07/2014 09:22
Data File: A07MAY14A-2
Prep Batch: 25866
Prep Date: 05-MAY-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.9
Pg/g
0.143 1.00
40321-76-4
1,2,3,7,8-PeCDD
98.9
Pg/g
0.308 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
96.7
Pg/g
0.400 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
101
Pg/g
0.426 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
103
Pg/g
0.440 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
100
Pg/g
0.770 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
204
Pg/g
1.37 10.0
51207-31-9
2,3,7,8-TCDF
18.2
Pg/g
0.200 1.00
57117-41-6
1,2,3,7,8-PeCDF
101
Pg/g
0.378 5.00
57117-31-4
2,3,4,7,8-PeCDF
96.4
Pg/g
0.358 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
101
Pg/g
0.552 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
97.9
Pg/g
0.526 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
101
Pg/g
0.506 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
104
Pg/g
0.930 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
98.2
Pg/g
0.212 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.1
Pg/g
0.394 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
184
Pg/g
1.39 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
148
200
Pg/g
74.2
(20%-175%)
13C-1,2,3,7,8-
PeCDD
155
200
Pg/g
77.5
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
154
200
Pg/g
77.0
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
164
200
Pg/g
82.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
161
200
Pg/g
80.3
(22%-166%)
13C-OCDD
296
400
Pg/g
74.0
(13%-199%)
13C-2,3,7,8-TCDF
151
200
Pg/g
75.4
(22%-152%)
13C-1,2,3,7,8-
PeCDF
142
200
Pg/g
70.8
(21%-192%)
130-2,3,4,7,8-
PeCDF
147
200
Pg/g
73.5
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
146
200
Pg/g
72.8
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
147
200
Pg/g
73.6
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
152
200
Pg/g
75.9
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
124
200
Pg/g
61.9
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
156
200
Pg/g
77.9
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
137
200
Pg/g
68.7
(20%-186%)
3701-2,3,7,8-TCDD
17.3
20.0
Pg/g
86.3
(31 %-191%)
Comments:
Page 25 of 26
-------
Cape Fear Analytical LLC
Report Date:
May 8, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6086
12010372
QC for batch 25866
LCSD for batch 25866
25868
05/07/2014 10:09
A07MAY14A-3
25866
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
05-MAY-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.9
Pg/g
0.165
1.00
40321-76-4
1,2,3,7,8-PeCDD
99.9
Pg/g
0.210
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
97.1
Pg/g
0.746
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
105
Pg/g
0.806
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
107
Pg/g
0.826
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
97.8
Pg/g
0.752
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
201
Pg/g
1.21
10.0
51207-31-9
2,3,7,8-TCDF
18.7
Pg/g
0.206
1.00
57117-41-6
1,2,3,7,8-PeCDF
96.2
Pg/g
0.308
5.00
57117-31-4
2,3,4,7,8-PeCDF
98.0
Pg/g
0.292
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
97.7
Pg/g
0.670
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
100
Pg/g
0.650
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
104
Pg/g
0.708
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
104
Pg/g
1.09
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
102
Pg/g
0.234
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.8
Pg/g
0.446
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
179
Pg/g
1.35
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
143
200
Pg/g
71.4
(20%-175%)
13C-1,2,3,7,8-PeCDD
157
200
Pg/g
78.3
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
155
200
Pg/g
77.5
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
157
200
Pg/g
78.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
163
200
Pg/g
81.3
(22%-166%)
13C-OCDD
303
400
Pg/g
75.8
(13%-199%)
13C-2,3,7,8-TCDF
146
200
Pg/g
72.8
(22%-152%)
13C-1,2,3,7,8-PeCDF
155
200
Pg/g
77.4
(21%-192%)
13C-2,3,4,7,8-PeCDF
150
200
Pg/g
75.1
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
145
200
Pg/g
72.7
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
145
200
Pg/g
72.5
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
146
200
Pg/g
72.9
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
123
200
Pg/g
61.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
153
200
Pg/g
76.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
134
200
Pg/g
66.9
(20%-186%)
37Cl-2,3,7,8-TCDD
15.9
20.0
Pg/g
79.6
(31 %-191%)
Comments:
Page 26 of 26
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
May 14. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6106
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on May 09, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of25
problem solved
-------
Page;
Project #:
CFA Quote #:
COC Number (l,:_
PO Number:
-A
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number:
01 ou?
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
cite,, N,™; Jgr,
Phone #: iri-m-erig
Sample Analysts Requested<5! (Fill in the number of containers for each test)
J'Project/SiteName^roc/e<
Fax#:
1^ Address: ft* ^
is Collected by:
U I
f
Send Results To: F**Fiiter, P^Wipe, U-Urine, F=Fecal, N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.eS290B, 1668B) and number of containers provided for each (Lc.8290B -3,1668B- 1)
6.) Preservative Type: HA *= Hydrochloric Acid, NI - Nitric Acid, SH = Sodium Hydroxide, SA = Sulfuric Acid, AA = Ascorbic Acid, HX = Hexane, ST = Sodium Thiosuifate, If no preservative is added - leave field Wank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
r Seal Intact?
'YESJ NO
holer Temp:
C
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
clien,: TBtI^
Work Order: (^}(Q(p
Received B»:
¦BSte/Time Received: Qq ^ fOH'O
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
Samples identified as Foreign Soil?
DOE Site Sample Packages
Yes
NA
No*
Screened <0.5 mR/hr?
Samples < 2x background?
O"
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes
NA
/No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
L
/
Circte Applicable:
seals broken damaged container leaking container ather(describe)
2
Chain of Custody documents included
with shipment?
3
Samples requiring cold preservation
within 0-6T?
X
Prpflfyntinn Method:
rce bags J blue ice dry ice none other (describe)
(t'C-
4
Samples requiring chemical
preservation at proper pH?
C_
Sample IDs, containers affected and pH observed:
ff preservative added, Lot#:
5
Samples requiring preservation have
no residual chlorine?
Sample IDs, containers affected:
If preservative added, Lot#:
6
Samples received within holding time?
LS
X
Sample IDs, tests affected;
7
Sample IDs on COC match IDs on
containers?
<—'
/
Sample fDs, containers affected:
8
Date & time of COC match date & time
on containers?
IS
/
Sample IDs, containers affected:
9
Number of containers received match
number indicated on COC?
y
Sample IDs, containers affected:
10
COC form is properly signed in
relinquished/received sections?
/
Comments:
— Date: t) ^ ^A- Yf V
Checklist performed by: Initials:
Page 3 of25
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 25
-------
Case Narrative
Page 5 of25
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6106
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25908
Clean Up Batch Number: 25901
Extraction Batch Number: 25900
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6106001 SFRA-37
6106002 SFRA-38
6106003 SFRA-39
12010394 Method Blank (MB)
12010395 Laboratory Control Sample (LCS)
12010396 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of 25
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 25908.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
Sample 6106001 (SFRA-37)- Batch 25908 was diluted due to the presence of over-range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 7 of25
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 25
-------
Sample Data Summary
Page 9 of 25
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6106 CFA Work Order: 6106
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 14 MAY 2014 Title: Data Validator
Page 10 of 25
-------
Cape Fear Analytical LLC
Report Date:
May 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6106
Lab Sample ID: 6106001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/08/2014 13:35
05/09/2014 10:40
Project: TETR00114
Matrix: SOLID
%Moisture: 21.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-37
25908
05/13/2014 19:56
A13MAY14D-5
25900
09-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.05 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
6680
Pg/g
9.17 60.5
40321-76-4
1,2,3,7,8-PeCDD
U
7.84
Pg/g
7.84 302
39227-28-6
1,2,3,4,7,8-HxCDD
u
15
Pg/g
15.0 302
57653-85-7
1,2,3,6,7,8-HxCDD
J
30.6
Pg/g
15.4 302
19408-74-3
1,2,3,7,8,9-HxCDD
J
17.4
Pg/g
16.1 302
35822-46-9
1,2,3,4,6,7,8-HpCDD
754
Pg/g
24.2 302
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11900
Pg/g
74.5 605
51207-31-9
2,3,7,8-TCDF
J
35.4
Pg/g
12.2 60.5
57117-41-6
1,2,3,7,8-PeCDF
u
5.73
Pg/g
5.73 302
57117-31-4
2,3,4,7,8-PeCDF
u
6.02
Pg/g
6.02 302
70648-26-9
1,2,3,4,7,8-HxCDF
u
14
Pg/g
14.0 302
57II7.44.9
1,2,3,6,7,8-HxCDF
u
7.77
Pg/g
7.77 302
60851-34-5
2,3,4,6,7,8-HxCDF
J
11.0
Pg/g
7.19 302
72918-21-9
1,2,3,7,8,9-HxCDF
u
12
Pg/g
12.0 302
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
110
Pg/g
0.121 302
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
5.93
Pg/g
0.226 302
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
175
Pg/g
35.1 605
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1680
2420
Pg/g
69.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1760
2420
Pg/g
72.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1800
2420
Pg/g
74.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2010
2420
Pg/g
83.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1590
2420
Pg/g
65.6
(23%-140%)
13C-OCDD
2680
4840
Pg/g
55.5
(17%-157%)
13C-2,3,7,8-TCDF
1780
2420
Pg/g
73.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1920
2420
Pg/g
79.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
1640
2420
Pg/g
67.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1760
2420
Pg/g
72.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1830
2420
Pg/g
75.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1800
2420
Pg/g
74.3
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1450
2420
Pg/g
60.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1560
2420
Pg/g
64.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1290
2420
Pg/g
53.4
(26%-13 8%)
3701-2,3,7,8-TCDD
230
242
Pg/g
95.2
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 25
-------
Cape Fear Analytical LLC
Report Date:
May 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6106
Lab Sample ID: 6106002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/08/2014 13:40
05/09/2014 10:40
Project: TETR00114
Matrix: SOLID
%Moisture: 21.8
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-38
25908
05/13/2014 20:44
A13MAY14D-6
25900
09-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.19 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2560
Pg/g
2.02 10.7
40321-76-4
1,2,3,7,8-PeCDD
U
2.21
Pg/g
2.21 53.7
39227-28-6
1,2,3,4,7,8-HxCDD
J
5.13
Pg/g
4.08 53.7
57653-85-7
1,2,3,6,7,8-HxCDD
J
21.6
Pg/g
4.19 53.7
19408-74-3
1,2,3,7,8,9-HxCDD
J
10.7
Pg/g
4.38 53.7
35822-46-9
1,2,3,4,6,7,8-HpCDD
382
Pg/g
7.22 53.7
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9700
Pg/g
19.6 107
51207-31-9
2,3,7,8-TCDF
15.2
Pg/g
2.73 10.7
57117-41-6
1,2,3,7,8-PeCDF
J
5.43
Pg/g
1.65 53.7
57117-31-4
2,3,4,7,8-PeCDF
J
2.99
Pg/g
1.45 53.7
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.29
Pg/g
1.74 53.7
57II7.44.9
1,2,3,6,7,8-HxCDF
J
3.27
Pg/g
1.82 53.7
60851-34-5
2,3,4,6,7,8-HxCDF
J
4.36
Pg/g
1.89 53.7
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.92
Pg/g
2.92 53.7
67562-39-4
1,2,3,4,6,7,8-HpCDF
63.7
Pg/g
0.425 53.7
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
5.13
Pg/g
0.765 53.7
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
97.0
Pg/g
13.9 107
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1810
2150
Pg/g
84.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1710
2150
Pg/g
79.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1770
2150
Pg/g
82.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1920
2150
Pg/g
89.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1720
2150
Pg/g
79.9
(23%-140%)
13C-OCDD
3250
4300
Pg/g
75.7
(17%-157%)
13C-2,3,7,8-TCDF
1740
2150
Pg/g
81.1
(24%-169%)
130-1,2,3,7,8-
PeCDF
1630
2150
Pg/g
75.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1710
2150
Pg/g
79.5
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1750
2150
Pg/g
81.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1770
2150
Pg/g
82.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1830
2150
Pg/g
85.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1650
2150
Pg/g
76.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1620
2150
Pg/g
75.2
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1400
2150
Pg/g
65.2
(26%-13 8%)
3701-2,3,7,8-TCDD
227
215
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 25
-------
Cape Fear Analytical LLC
Report Date: May 14, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6106
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6106002
Date Collected:
05/08/2014 13:40
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
05/09/2014 10:40
%Moisture:
21.8
Client ID:
SFRA-38
Prep Basis:
Dry Weight
Batch ID:
25908
Method:
EPA Method 1613B
Run Date:
05/13/2014 12:06
Analyst:
JTF
Instrument:
HRP763
Data File:
bl3mayl4a-5
Dilution:
1
Prep Batch:
25900
Prep Method:
SW846 3540C
Prep Date:
09-MAY-14
Prep Aliquot:
1.19 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
15.1
Pg/g
5.69
10.7
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 25
-------
Cape Fear Analytical LLC
Report Date:
May 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6106
Lab Sample ID: 6106003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/08/2014 13:44
05/09/2014 10:40
Project: TETR00114
Matrix: SOLID
%Moisture: 20.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-39
25908
05/13/2014 21:32
A13MAY14D-7
25900
09-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.02 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3200
Pg/g
2.02 12.3
40321-76-4
1,2,3,7,8-PeCDD
U
2.57
Pg/g
2.57 61.7
39227-28-6
1,2,3,4,7,8-HxCDD
J
4.59
Pg/g
3.43 61.7
57653-85-7
1,2,3,6,7,8-HxCDD
J
27.9
Pg/g
3.50 61.7
19408-74-3
1,2,3,7,8,9-HxCDD
J
10.4
Pg/g
3.70 61.7
35822-46-9
1,2,3,4,6,7,8-HpCDD
482
Pg/g
7.16 61.7
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11300
Pg/g
15.1 123
51207-31-9
2,3,7,8-TCDF
21.2
Pg/g
2.67 12.3
57117-41-6
1,2,3,7,8-PeCDF
J
6.17
Pg/g
1.82 61.7
57117-31-4
2,3,4,7,8-PeCDF
J
3.33
Pg/g
1.94 61.7
70648-26-9
1,2,3,4,7,8-HxCDF
J
9.58
Pg/g
1.94 61.7
57II7.44.9
1,2,3,6,7,8-HxCDF
u
4.52
Pg/g
4.52 61.7
60851-34-5
2,3,4,6,7,8-HxCDF
u
5.82
Pg/g
5.82 61.7
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.99
Pg/g
2.99 61.7
67562-39-4
1,2,3,4,6,7,8-HpCDF
79.1
Pg/g
1.04 61.7
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
5.65
Pg/g
5.65 61.7
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
121
Pg/g
5.26 123
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1880
2470
Pg/g
76.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1800
2470
Pg/g
72.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2080
2470
Pg/g
84.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2040
2470
Pg/g
82.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1950
2470
Pg/g
79.1
(23%-140%)
13C-OCDD
3570
4940
Pg/g
72.4
(17%-157%)
13C-2,3,7,8-TCDF
2020
2470
Pg/g
81.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1910
2470
Pg/g
77.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1720
2470
Pg/g
69.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1960
2470
Pg/g
79.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1980
2470
Pg/g
80.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2060
2470
Pg/g
83.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1790
2470
Pg/g
72.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1750
2470
Pg/g
71.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1560
2470
Pg/g
63.3
(26%-13 8%)
3701-2,3,7,8-TCDD
243
247
Pg/g
98.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 25
-------
Cape Fear Analytical LLC
Report Date: May 14, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6106
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6106003
Date Collected:
05/08/2014 13:44
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
05/09/2014 10:40
%Moisture:
20.6
Client ID:
SFRA-39
Prep Basis:
Dry Weight
Batch ID:
25908
Method:
EPA Method 1613B
Run Date:
05/13/2014 12:25
Analyst:
JTF
Instrument:
HRP763
Data File:
bl3mayl4a-6
Dilution:
1
Prep Batch:
25900
Prep Method:
SW846 3540C
Prep Date:
09-MAY-14
Prep Aliquot:
1.02 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
27.8
Pg/g
6.22
12.3
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 25
-------
Quality Control
Summary
Page 16 of 25
-------
( ape Fear \lltllytictll LLC Report Date: May 14, 2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6106
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010395
LCS for batch 25900
12010396
LCSD for batch 25900
12010394
MB for batch 25900
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
79.8
72.8
86.6
85.9
77.0
63.3
83.5
75.0
70.4
83.1
80.7
84.3
70.4
72.1
61.6
98.4
65.6
60.3
74.5
75.0
68.5
61.0
75.7
63.6
59.0
71.1
72.3
71.0
62.8
64.2
56.8
79.5
65.2
60.0
67.9
69.7
61.0
52.2
67.5
60.0
58.3
66.1
65.6
66.2
58.5
58.5
49.7
101
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6106001
SFRA-37
13C-2,3,7,8-TCDD
69.2 D
(25%-164%)
Page 17 of 25
-------
( ape Fear \lltllytictll LLC Report Date: May 14, 2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6106
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
72.8
D
(25%-181%)
74.5
D
(32%-141%)
83.2
D
(28%-130%)
65.6
D
(23%-140%)
55.5
D
(17%-15 7%)
73.7
D
(24%-169%)
79.4
D
(24%-185%)
67.9
D
(21%-178%)
72.9
D
(26%-152%)
75.7
D
(26%-123%)
74.3
D
(28%-13 6%)
60.0
D
(29%-147%)
64.3
D
(28%-143%)
53.4
D
(26%-13 8%)
95.2
D
(35%-197%)
6106001
SFRA-37
6106002
SFRA-38
6106003
SFRA-39
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
84.4
79.5
82.5
89.3
79.9
75.7
81.1
75.7
79.5
81.6
82.4
85.1
76.8
75.2
65.2
106
76.0
72.9
84.4
82.6
79.1
72.4
81.7
77.5
69.9
79.5
80.4
83.4
72.4
71.1
63.3
98.3
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
* Recovery outside Acceptance Limits
Page 18 of 25
-------
Cape Fear Analytical LLC
Report Date: May 14, 2014
SDG Number: 6106
Matrix Type: SOLID
Hi-Res Dioxins/Furans
Surrogate Recovery Report
Page 3
of 3
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 19 of 25
-------
Cape Fear Analytical LLC
Report Date: May 14, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 05/13/2014 17:33 Dilution: 1
Prep Batch ID:25900
Batch ID: 25908
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.9
105
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
98.3
98.3
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
95.7
95.7
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
102
102
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
103
103
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
95.2
95.2
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
190
95.1
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
17.7
88.4
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
91.2
91.2
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
92.3
92.3
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
94.6
94.6
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
97.6
97.6
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
90.9
90.9
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
99.0
99
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
94.2
94.2
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
96.0
96
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
173
86.4
63-170
SDG Number: 6106
Client ID: LCS for batch 25900
Lab Sample ID: 12010395
Instrument: HRP750
Analyst: JTF
Page
20 of 25
-------
Cape Fear Analytical LLC
Report Date: May 14, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 05/13/2014 18:21 Dilution: 1
Prep Batch ID:25900
Batch ID: 25908
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.6
103
67-158
1.46
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
99.3
99.3
70-142
1.10
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
95.8
95.8
70-164
0.102
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
103
103
76-134
1.70
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
106
106
64-162
2.95
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
96.8
96.8
70-140
1.70
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
197
98.5
78-144
3.49
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
17.4
86.9
75-158
1.73
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
91.2
91.2
80-134
0.0329
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
91.3
91.3
68-160
1.10
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
94.1
94.1
72-134
0.466
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
96.8
96.8
84-130
0.801
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
96.9
96.9
70-156
6.36
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
99.9
99.9
78-130
0.871
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
96.2
96.2
82-122
2.12
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
95.9
95.9
78-138
0.125
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
173
86.6
63-170
0.257
0-20
SDG Number: 6106
Client ID: LCSD for batch 25900
Lab Sample ID: 12010396
Instrument: HRP750
Analyst: JTF
Page 21 of 25
-------
Cape Fear Analytical LLC
Report Date: May 14,2014
Method Blank Summary Page ' °' '
SDG Number: 6106
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 25900
Instrument ID:
HRP750
Data File:
A13MAY14D-4
Lab Sample ID: 12010394
Column:
Prep Date:
09-MAY-14
Analyzed:
05/13/14 19:09
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 SFRA-38
6106002
bl3mayl4a-5
05/13/14
1206
02 SFRA-39
6106003
bl3mayl4a-6
05/13/14
1225
03 LCS for batch 25900
12010395
A13MAY14D-2
05/13/14
1733
04 LCSD for batch 25900
12010396
A13MAY14D-3
05/13/14
1821
05 SFRA-37
6106001
A13MAY14D-5
05/13/14
1956
06 SFRA-38
6106002
A13MAY14D-6
05/13/14
2044
07 SFRA-39
6106003
A13MAY14D-7
05/13/14
2132
Page 22 of 25
-------
Cape Fear Analytical LLC
Report Date:
May 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6106
Lab Sample ID: 12010394
Client Sample: ^or batch 25900
Client ID: MB for batch 25900
Batch ID: 25908
Run Date: 05/13/2014 19:09
Data File: A13MAY14D-4
Prep Batch: 25900
Prep Date: 09-MAY-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.172
Pg/g
0.172 1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.214
Pg/g
0.127 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.19
Pg/g
0.190 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.228
Pg/g
0.228 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.2
Pg/g
0.200 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.2
Pg/g
0.200 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
0.822
Pg/g
0.352 10.0
51207-31-9
2,3,7,8-TCDF
u
.0998
Pg/g
0.0998 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.228
Pg/g
0.228 5.00
57117-31-4
2,3,4,7,8-PeCDF
J
0.184
Pg/g
0.0764 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.184
Pg/g
0.184 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.16
Pg/g
0.160 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.138
Pg/g
0.138 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.284
Pg/g
0.178 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.130
Pg/g
0.0085 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
0.082
Pg/g
0.0164 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.36
Pg/g
0.360 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
130
200
Pg/g
65.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
120
200
Pg/g
60.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
136
200
Pg/g
67.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
139
200
Pg/g
69.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
122
200
Pg/g
61.0
(23%-140%)
13C-OCDD
209
400
Pg/g
52.2
(17%-157%)
13C-2,3,7,8-TCDF
135
200
Pg/g
67.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
120
200
Pg/g
60.0
(24%-185%)
130-2,3,4,7,8-
PeCDF
117
200
Pg/g
58.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
132
200
Pg/g
66.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
131
200
Pg/g
65.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
132
200
Pg/g
66.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
117
200
Pg/g
58.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
117
200
Pg/g
58.5
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
99.3
200
Pg/g
49.7
(26%-13 8%)
3701-2,3,7,8-TCDD
20.2
20.0
Pg/g
101
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 23 of 25
-------
Cape Fear Analytical LLC
Report Date:
May 14, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6106
Lab Sample ID: 12010395
Client Sample: ^or batch 25900
Client ID: LCS for batch 25900
Batch ID: 25908
Run Date: 05/13/2014 17:33
Data File: A13MAY14D-2
Prep Batch: 25900
Prep Date: 09-MAY-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.9
Pg/g
0.113 1.00
40321-76-4
1,2,3,7,8-PeCDD
98.3
Pg/g
0.254 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
95.7
Pg/g
0.418 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
0.430 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
103
Pg/g
0.450 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.2
Pg/g
0.530 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
190
Pg/g
1.23 10.0
51207-31-9
2,3,7,8-TCDF
17.7
Pg/g
0.130 1.00
57117-41-6
1,2,3,7,8-PeCDF
91.2
Pg/g
0.220 5.00
57117-31-4
2,3,4,7,8-PeCDF
92.3
Pg/g
0.238 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
94.6
Pg/g
0.434 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
97.6
Pg/g
0.456 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
90.9
Pg/g
0.446 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
99.0
Pg/g
0.722 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
94.2
Pg/g
0.378 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
96.0
Pg/g
0.702 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
173
Pg/g
1.05 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
160
200
Pg/g
79.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
146
200
Pg/g
72.8
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
173
200
Pg/g
86.6
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
172
200
Pg/g
85.9
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
154
200
Pg/g
77.0
(22%-166%)
13C-OCDD
253
400
Pg/g
63.3
(13%-199%)
13C-2,3,7,8-TCDF
167
200
Pg/g
83.5
(22%-152%)
13C-1,2,3,7,8-
PeCDF
150
200
Pg/g
75.0
(21%-192%)
130-2,3,4,7,8-
PeCDF
141
200
Pg/g
70.4
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
166
200
Pg/g
83.1
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
161
200
Pg/g
80.7
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
169
200
Pg/g
84.3
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
141
200
Pg/g
70.4
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
144
200
Pg/g
72.1
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
123
200
Pg/g
61.6
(20%-186%)
3701-2,3,7,8-TCDD
19.7
20.0
Pg/g
98.4
(31 %-191%)
Comments:
Page 24 of 25
-------
Cape Fear Analytical LLC
Report Date:
May 14, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6106
12010396
QC for batch 25900
LCSD for batch 25900
25908
05/13/2014 18:21
A13MAY14D-3
25900
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
09-MAY-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.6
Pg/g
0.0952
1.00
40321-76-4
1,2,3,7,8-PeCDD
99.3
Pg/g
0.216
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
95.8
Pg/g
0.356
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
103
Pg/g
0.358
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
106
Pg/g
0.378
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
96.8
Pg/g
0.456
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
197
Pg/g
0.988
10.0
51207-31-9
2,3,7,8-TCDF
17.4
Pg/g
0.107
1.00
57117-41-6
1,2,3,7,8-PeCDF
91.2
Pg/g
0.216
5.00
57117-31-4
2,3,4,7,8-PeCDF
91.3
Pg/g
0.246
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
94.1
Pg/g
0.506
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
96.8
Pg/g
0.474
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
96.9
Pg/g
0.506
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
99.9
Pg/g
0.766
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
96.2
Pg/g
0.174
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
95.9
Pg/g
0.318
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
173
Pg/g
0.824
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
131
200
Pg/g
65.6
(20%-175%)
13C-1,2,3,7,8-PeCDD
121
200
Pg/g
60.3
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
149
200
Pg/g
74.5
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
150
200
Pg/g
75.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
137
200
Pg/g
68.5
(22%-166%)
13C-OCDD
244
400
Pg/g
61.0
(13%-199%)
13C-2,3,7,8-TCDF
151
200
Pg/g
75.7
(22%-152%)
13C-1,2,3,7,8-PeCDF
127
200
Pg/g
63.6
(21%-192%)
13C-2,3,4,7,8-PeCDF
118
200
Pg/g
59.0
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
142
200
Pg/g
71.1
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
145
200
Pg/g
72.3
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
142
200
Pg/g
71.0
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
126
200
Pg/g
62.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
128
200
Pg/g
64.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
114
200
Pg/g
56.8
(20%-186%)
37Cl-2,3,7,8-TCDD
15.9
20.0
Pg/g
79.5
(31 %-191%)
Comments:
Page 25 of 25
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
May 21. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6123
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on May 16, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of21
problem solved
-------
Page;
Project #:
CFA Quote#;
COC Number
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number; / r\ I 1
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone; (910) 795-0421
ClientName: Phone#:J/fj?/-<^7<
f Sample Analysis Requested
i
><
SFA^ -
4;f
1
>
1 ' " ""
TAT Requested: Normal: Rush: Specify
Ibject (o Surcharge)
Fax Results:
Yes
No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 / Level 4
Remarks; Are there any known hazards applicable to these samples? If so, please list the hazards
Sample Collection Time Zone
Eastern Pacific
Central Other _
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Date
Tirae
fYSij /&>&
Received by (signed) Date
Time
/QoO
CFA PM;
Method of Shipment: /gr [pate Shipped: s-Ys-H
Airbill »:
3(sy ogf^
Airbill#:
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N - Normal Sample, TB - Trip Blank, FD » Field Duplicate. EB = Equipment Blank, MS = Matrix Spike Sample,MSD - Matrix Spike Duplicate Sample,G = Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: BW-Drinking Water, GW=Gimindwa!er, SW-Stirfaee Water, WW-Waste Water, "W=Water, ML-Misc Liquid, SO=Soil» SD=Sedimetif, SL=Sludge5 SS=SoSid Waste, 0=Oil, F=Fitter, P^Wlpe, Urine, F^Fecal, N-Nasal
5.) Sample Analysis Requested: Analytical method requested (i.e<8290B, 1668B] and number of containers provided for each (U.S290B - 3,166SB -1). -
6.) Preservative Type: HA = Hydrochloric Acid, NI« Nitric Acid, SH - Sodium Hydroxide, SA = Sulfuric Acid, AA = Ascorbic Acid, HX = Hexane, ST •-= Sodium Thiosulfate, If no preservative is added = leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intact?
YES NO
Cooler Temp:
to. I c
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of21
-------
SAMPLE RECEIPT CHECKLIST
Cope Fear Analytical
Client:
Work Order: ^
Shipping Company: ^>c-
Date/TimeReceived: j ^ ^ / 0 0O
Suspected Hazard information
Yes
NA
No
DOi Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
V'
Screened <0.5 mR/hr?
Samples identified as Foreign Soil?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Air Sample Receipt Specifics
Yes
NA
No j
Air Witness:
Air sample in shipment?
V'
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
y
Circle Applicable:
sesls.broken damaged container leaking container other(describe)
2
Chain of Custody documents included
with shipment?
y
s
3
Samples requiring cold preservation
within 0-6°C?
Preservation Method:
ice bags^lue ice dry ice none other ^describe)
O
10- 1
4
Aqueous samples found to have visible
solids?
Sample IDs, containers affected:
5
Samples requiring chemical
preservation at proper pH?
s/
Sample IDs, containers affected and pH observed:
If preservative added. Lot#:
6
Samples requiring preservation have
no residual chlorine?
/
Sample IDs, containers affected:
If preservative added, lotjf;
7
Samples received within holding time?
S-- .
Sample IDs, tests affected:
8
Sample IDs on COC match IDs on
containers?
/¦¦¦-.
Sample IDs, containers affected:
9
Date & time of COC match date & time
on containers?
v/
y
Sample IDs, containers a ffected;
10
Number of containers received match
number indicated on COC?
v/
¦/-
Sample IDs, containers affected:
11
COC form is properly signed in
relinquished/received sections?
s.
Comments:
"72 hr TAT
Checklist performed by: Date: IGm/Wf*j
Page 3 of21
-------
Case Narrative
Page 5 of21
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6123
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25941
Clean Up Batch Number: 25938
Extraction Batch Number: 25937
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6123001 SFRA-40
6123002 SFRA-41
12010433 Method Blank (MB)
12010434 Laboratory Control Sample (LCS)
12010435 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of21
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Sample Dilutions
Sample 6123002 (SFRA-41)- Batch 25941 was diluted due to the presence of over-range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Preparation/Analytical Method Verification
A lg aliquot was used for extraction based on known high levels of target analytes from this site.
-Batch 25941.
Miscellaneous Information
Nonconformance (NCR) Documentation
Page 7 of21
-------
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of21
-------
Sample Data Summary
Page 9 of21
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6123 CFA Work Order: 6123
Name: Heather Patterson
Date: 21 MAY 2014
Title: Data Validator
Page 10 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 21,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6123
Lab Sample ID: 6123001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/15/2014 08:30
05/16/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 29.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-40
25941
05/19/2014 22:36
A19MAY14B-11
25937
16-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.03 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
163
Pg/g
2.01 13.8
40321-76-4
1,2,3,7,8-PeCDD
U
3.72
Pg/g
3.72 68.9
39227-28-6
1,2,3,4,7,8-HxCDD
J
56.3
Pg/g
7.80 68.9
57653-85-7
1,2,3,6,7,8-HxCDD
87.8
Pg/g
8.08 68.9
19408-74-3
1,2,3,7,8,9-HxCDD
J
23.5
Pg/g
8.41 68.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
1880
Pg/g
25.6 68.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
21500
Pg/g
51.8 138
51207-31-9
2,3,7,8-TCDF
J
4.93
Pg/g
3.25 13.8
57117-41-6
1,2,3,7,8-PeCDF
u
3.06
Pg/g
3.06 68.9
57117-31-4
2,3,4,7,8-PeCDF
J
7.39
Pg/g
2.92 68.9
70648-26-9
1,2,3,4,7,8-HxCDF
J
24.9
Pg/g
4.82 68.9
57II7.44.9
1,2,3,6,7,8-HxCDF
u
8.46
Pg/g
8.46 68.9
60851-34-5
2,3,4,6,7,8-HxCDF
J
17.1
Pg/g
4.82 68.9
72918-21-9
1,2,3,7,8,9-HxCDF
u
8.13
Pg/g
8.13 68.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
269
Pg/g
6.70 68.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
29.5
Pg/g
10.7 68.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
624
Pg/g
14.9 138
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1960
2760
Pg/g
71.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2180
2760
Pg/g
79.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1730
2760
Pg/g
62.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2150
2760
Pg/g
78.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1990
2760
Pg/g
72.2
(23%-140%)
13C-OCDD
3600
5510
Pg/g
65.3
(17%-157%)
13C-2,3,7,8-TCDF
2040
2760
Pg/g
74.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
2210
2760
Pg/g
80.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
2140
2760
Pg/g
77.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1920
2760
Pg/g
69.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2110
2760
Pg/g
76.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2040
2760
Pg/g
74.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1720
2760
Pg/g
62.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1990
2760
Pg/g
72.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1870
2760
Pg/g
67.7
(26%-13 8%)
3701-2,3,7,8-TCDD
259
276
Pg/g
93.8
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 21,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6123
Lab Sample ID: 6123002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/15/2014 14:50
05/16/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 21.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-41
25941
05/21/201411:30
A20MA Y14B4-6
25937
16-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.32 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
13300
Pg/g
9.74 96.4
40321-76-4
1,2,3,7,8-PeCDD
U
13.1
Pg/g
13.1 482
39227-28-6
1,2,3,4,7,8-HxCDD
J
23.7
Pg/g
12.6 482
57653-85-7
1,2,3,6,7,8-HxCDD
J
88.5
Pg/g
11.9 482
19408-74-3
1,2,3,7,8,9-HxCDD
J
28.5
Pg/g
13.0 482
35822-46-9
1,2,3,4,6,7,8-HpCDD
1280
Pg/g
21.6 482
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14500
Pg/g
49.4 964
51207-31-9
2,3,7,8-TCDF
J
69.1
Pg/g
10.0 96.4
57117-41-6
1,2,3,7,8-PeCDF
u
9.26
Pg/g
9.26 482
57117-31-4
2,3,4,7,8-PeCDF
u
8.83
Pg/g
8.83 482
70648-26-9
1,2,3,4,7,8-HxCDF
J
44.7
Pg/g
9.74 482
57II7.44.9
1,2,3,6,7,8-HxCDF
J
16.9
Pg/g
9.41 482
60851-34-5
2,3,4,6,7,8-HxCDF
J
21.4
Pg/g
10.2 482
72918-21-9
1,2,3,7,8,9-HxCDF
u
16.2
Pg/g
16.2 482
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
376
Pg/g
9.47 482
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
40.5
Pg/g
15.9 482
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
567
Pg/g
20.8 964
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1430
1930
Pg/g
74.1
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1460
1930
Pg/g
75.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1340
1930
Pg/g
69.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1350
1930
Pg/g
70.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1440
1930
Pg/g
74.4
(23%-140%)
13C-OCDD
2700
3860
Pg/g
70.0
(17%-157%)
13C-2,3,7,8-TCDF
1600
1930
Pg/g
83.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
1500
1930
Pg/g
77.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1520
1930
Pg/g
79.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1400
1930
Pg/g
72.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1340
1930
Pg/g
69.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1390
1930
Pg/g
72.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1240
1930
Pg/g
64.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1460
1930
Pg/g
75.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1430
1930
Pg/g
73.9
(26%-13 8%)
3701-2,3,7,8-TCDD
201
193
Pg/g
104
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 21
-------
Quality Control
Summary
Page 13 of 21
-------
( ape Fear \lltllytictll LLC Report Date: May 21, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6123
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010434
LCS for batch 25937
12010435
LCSD for batch 25937
12010433
MB for batch 25937
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
75.8
75.1
69.0
87.6
69.1
51.7
79.3
78.5
77.4
71.6
84.0
75.8
65.1
73.4
63.6
92.2
77.4
76.4
68.4
89.4
72.4
57.6
81.6
80.0
79.6
73.2
81.2
77.3
66.7
75.3
65.5
88.2
68.1
67.9
60.7
75.8
62.7
51.6
74.7
70.9
68.1
66.0
78.3
71.3
59.3
67.1
57.5
80.5
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6123001
SFRA-40
13C-2,3,7,8-TCDD
71.0
(25%-164%)
Page 14 of 21
-------
( ape Fear \lltllytictll LLC Report Date: May 21, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6123
Matrix Type: SOLID
Sample ID Client ID
6123001 SFRA-40
6123002 SFRA-41
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
79.3
(25%-181%)
62.8
(32%-141%)
78.1
(28%-130%)
72.2
(23%-140%)
65.3
(17%-15 7%)
74.2
(24%-169%)
80.4
(24%-185%)
77.7
(21%-178%)
69.6
(26%-152%)
76.4
(26%-123%)
74.1
(28%-13 6%)
62.5
(29%-147%)
72.3
(28%-143%)
67.7
(26%-13 8%)
93.8
(35%-197%)
74.1
D
(25%-164%)
75.8
D
(25%-181%)
69.3
D
(32%-141%)
70.2
D
(28%-130%)
74.4
D
(23%-140%)
70.0
D
(17%-15 7%)
83.0
D
(24%-169%)
77.7
D
(24%-185%)
79.0
D
(21%-178%)
72.6
D
(26%-152%)
69.5
D
(26%-123%)
72.0
D
(28%-13 6%)
64.3
D
(29%-147%)
75.9
D
(28%-143%)
73.9
D
(26%-13 8%)
104
D
(35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 15 of 21
-------
Cape Fear Analytical LLC
Report Date: May 21, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 05/19/2014 16:15 Dilution: 1
Prep Batch ID:25937
Batch ID: 25941
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.6
103
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
98.5
98.5
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
93.6
93.6
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
102
102
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
100
100
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
94.5
94.5
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
199
99.7
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.6
92.9
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
97.4
97.4
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
97.7
97.7
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
101
101
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
101
101
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
100
100
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
104
104
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
94.0
94
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
97.8
97.8
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
204
102
63-170
SDG Number: 6123
Client ID: LCS for batch 25937
Lab Sample ID: 12010434
Instrument: HRP750
Analyst: JTF
Page
16 of 21
-------
Cape Fear Analytical LLC
Report Date: May 21, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 05/19/2014 17:02 Dilution: 1
Prep Batch ID:25937
Batch ID: 25941
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.4
102
67-158
1.10
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
102
102
70-142
4.01
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
101
101
70-164
7.26
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
98.7
98.7
76-134
3.20
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
103
103
64-162
2.33
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
95.9
95.9
70-140
1.47
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
198
99.2
78-144
0.461
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.2
91.2
75-158
1.86
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
98.9
98.9
80-134
1.54
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
98.6
98.6
68-160
0.966
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
97.9
97.9
72-134
2.69
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
101
101
84-130
0.427
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
99.0
99
70-156
1.21
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
105
105
78-130
0.779
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
97.8
97.8
82-122
3.90
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
99.0
99
78-138
1.20
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
213
106
63-170
4.19
0-20
SDG Number: 6123
Client ID: LCSD for batch 25937
Lab Sample ID: 12010435
Instrument: HRP750
Analyst: JTF
Page
17 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 21,2014
Method Blank Summary
Page 1 of 1
SDG Number: 6123
Client ID: MB for batch 25937
Lab Sample ID: 12010433
Column:
Client: TETR001
Instrument ID: HRP750
Prep Date: 16-MAY-14
Matrix: SOLID
Data File: A19MAY14B-5
Analyzed: 05/19/1417:50
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 25937
12010434
A19MAY14B-3
05/19/14
1615
02
LCSD for batch 25937
12010435
A19MAY14B-4
05/19/14
1702
03
SFRA-40
6123001
A19MAY14B-11
05/19/14
2236
04
SFRA-41
6123002
A20MAY14B 4-6
05/21/14
1130
Page 18 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 21, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6123
12010433
QC for batch 25937
MB for batch 25937
25941
05/19/2014 17:50
A19MAY14B-5
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
25937
Prep Method:
SW846 3540C
Prep Date:
16-MAY-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.122
Pg/g
0.122
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.262
Pg/g
0.262
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.29
Pg/g
0.290
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
J
0.280
Pg/g
0.208
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.356
Pg/g
0.216
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.328
Pg/g
0.328
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
1.47
Pg/g
0.634
10.0
51207-31-9
2,3,7,8-TCDF
J
0.132
Pg/g
0.106
1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.324
Pg/g
0.324
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.26
Pg/g
0.260
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.308
Pg/g
0.308
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
J
0.206
Pg/g
0.114
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.206
Pg/g
0.206
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.314
Pg/g
0.230
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.268
Pg/g
0.268
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
0.242
Pg/g
0.184
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.558
Pg/g
0.558
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
136
200
Pg/g
68.1
(25 %-164%)
13C-1,2,3,7,8-PeCDD
136
200
Pg/g
67.9
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
121
200
Pg/g
60.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
152
200
Pg/g
75.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
125
200
Pg/g
62.7
(23%-140%)
13C-OCDD
206
400
Pg/g
51.6
(17%-157%)
13C-2,3,7,8-TCDF
149
200
Pg/g
74.7
(24%-169%)
13C-1,2,3,7,8-PeCDF
142
200
Pg/g
70.9
(24%-185%)
13C-2,3,4,7,8-PeCDF
136
200
Pg/g
68.1
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
132
200
Pg/g
66.0
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
157
200
Pg/g
78.3
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
143
200
Pg/g
71.3
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
119
200
Pg/g
59.3
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
134
200
Pg/g
67.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
115
200
Pg/g
57.5
(26%-13 8%)
37Cl-2,3,7,8-TCDD
16.1
20.0
Pg/g
80.5
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 21,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6123
Lab Sample ID: 12010434
Client Sample: *or batch 25937
Client ID: LCS for batch 25937
Batch ID: 25941
Run Date: 05/19/2014 16:15
Data File: A19MAY14B-3
Prep Batch: 25937
Prep Date: 16-MAY-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.6
Pg/g
0.132 1.00
40321-76-4
1,2,3,7,8-PeCDD
98.5
Pg/g
0.304 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
93.6
Pg/g
0.662 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
0.682 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
100
Pg/g
0.712 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
94.5
Pg/g
1.03 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
199
Pg/g
2.46 10.0
51207-31-9
2,3,7,8-TCDF
18.6
Pg/g
0.150 1.00
57117-41-6
1,2,3,7,8-PeCDF
97.4
Pg/g
0.436 5.00
57117-31-4
2,3,4,7,8-PeCDF
97.7
Pg/g
0.434 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
101
Pg/g
0.788 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
101
Pg/g
0.742 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
100
Pg/g
0.808 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
104
Pg/g
1.38 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
94.0
Pg/g
0.860 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
97.8
Pg/g
1.50 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
204
Pg/g
2.32 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
152
200
Pg/g
75.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
150
200
Pg/g
75.1
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
138
200
Pg/g
69.0
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
175
200
Pg/g
87.6
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
138
200
Pg/g
69.1
(22%-166%)
13C-OCDD
207
400
Pg/g
51.7
(13%-199%)
13C-2,3,7,8-TCDF
159
200
Pg/g
79.3
(22%-152%)
13C-1,2,3,7,8-
PeCDF
157
200
Pg/g
78.5
(21%-192%)
130-2,3,4,7,8-
PeCDF
155
200
Pg/g
77.4
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
143
200
Pg/g
71.6
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
168
200
Pg/g
84.0
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
152
200
Pg/g
75.8
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
130
200
Pg/g
65.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
147
200
Pg/g
73.4
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
127
200
Pg/g
63.6
(20%-186%)
3701-2,3,7,8-TCDD
18.4
20.0
Pg/g
92.2
(31 %-191%)
Comments:
Page 20 of 21
-------
Cape Fear Analytical LLC
Report Date:
May 21, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6123
12010435
QC for batch 25937
LCSD for batch 25937
25941
05/19/2014 17:02
A19MAY14B-4
25937
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
16-MAY-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.4
Pg/g
0.145
1.00
40321-76-4
1,2,3,7,8-PeCDD
102
Pg/g
0.484
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
101
Pg/g
0.662
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.7
Pg/g
0.662
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
103
Pg/g
0.700
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.9
Pg/g
1.15
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
198
Pg/g
2.38
10.0
51207-31-9
2,3,7,8-TCDF
18.2
Pg/g
0.160
1.00
57117-41-6
1,2,3,7,8-PeCDF
98.9
Pg/g
0.410
5.00
57117-31-4
2,3,4,7,8-PeCDF
98.6
Pg/g
0.408
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
97.9
Pg/g
0.876
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
101
Pg/g
0.860
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
99.0
Pg/g
0.926
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
105
Pg/g
1.49
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
97.8
Pg/g
0.688
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.0
Pg/g
1.30
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
213
Pg/g
2.20
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
155
200
Pg/g
77.4
(20%-175%)
13C-1,2,3,7,8-PeCDD
153
200
Pg/g
76.4
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
137
200
Pg/g
68.4
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
179
200
Pg/g
89.4
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
145
200
Pg/g
72.4
(22%-166%)
13C-OCDD
230
400
Pg/g
57.6
(13%-199%)
13C-2,3,7,8-TCDF
163
200
Pg/g
81.6
(22%-152%)
13C-1,2,3,7,8-PeCDF
160
200
Pg/g
80.0
(21%-192%)
13C-2,3,4,7,8-PeCDF
159
200
Pg/g
79.6
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
146
200
Pg/g
73.2
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
162
200
Pg/g
81.2
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
155
200
Pg/g
77.3
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
133
200
Pg/g
66.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
151
200
Pg/g
75.3
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
131
200
Pg/g
65.5
(20%-186%)
37Cl-2,3,7,8-TCDD
17.6
20.0
Pg/g
88.2
(31 %-191%)
Comments:
Page 21 of 21
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
May 23. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6130
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on May 20, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 47
problem solved
-------
Page; (
Project #:
CFA Quote #:
COC Number'0:
PO Number:
of
JSL.
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: / | 7 Q
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client ^
Phone #: J/ f-
Projeet/SiteName: S+ rec^ /bf*s( A->+(M*. FaX#:
Total ii amber of containers
Preservative Type (6)
Address: ^ A ^ P{»f,SS^{Ao
*
Comments
Note: extra sample is
required for sample
specific QC
Collected by: £ Cfa.Send Results To: dzeetiiroftug, o(v*r-fbC ne+
/
Sample ID
* For composites - indicate start and stop date/time
•Dale Collected
(mm-dd-yy)
*Time
Collected
(Military)
(hbiiiin)
QC Code
Field
Filtered m
Sample
Matrix0*
SPAA- fx
o?Ao
S
{
X
s FA 4 - fj
(
(/AT
J
I
>r
s?/?/)- yy
\
urs"
S
1
SFA^ - Yj-
)
(¦?<>£
3
1
r
sfAA -
5
I
*
s
C
k
sf/14-
s
kT
sf/W-HI
s
I
K
5
i
X
jsFM -s~(
s
V
X
Sample Analysis Requested(S) (Fill in the number of containers for each test)
TAT Requested: Normal: Rush: Specify: 3 AffhTc
ibjeh to Surcharge)
Fax Results:
Yes
No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 /(Level 3j / Level 4
Remarks; Are there any known hazards applicable to these samples? If so, please list the hazards
Sample Collection Time Zone
Eastern Pacific
Central Other _
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Sigjjpd) Date
w
Received by (signed)
Date
Time
mo
CFA PM: (Jjfndc /s
Method of Shipment:
/Vgcf ^^
Date Shipped:
Airbill #:
Jf£T E>gm
Airbill#:
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N = Normal Sample, TB = Trip Blank, FD = Field Duplicate, EB - Equipment Blank, MS = Matrix Spike Sample, MSB = Matrix Spike Duplicate Sample, G = Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes; DW=Drinktag Water, GW=Groundwater, SW=Surface Water, WW=Waste Water, W-Water, Ml.-Misc Liquid,SO-Soil,SD-Sediment, SL-Sludge, SS-Sotid Waste, O-Oil,F-Filter, P»Wipe, IMJrtne, F-Fecal,N-Nasal
5.) Sample Analysis Requested: Analytical method requested (i.eS29#B, IM8B)andnumberofcontainersprovidedforeach(i.e.MM« -3,16681! -1). *
6.) Preservative Type: HA - Hydrochloric Acid.NI = Nitric Acid.SH - Sodium Hydroxide, SA - Sulfuric Acid, A A - Ascorbic Acid.HX - Hexane, ST - Sodium Thiosulfate, If no preservative is added - leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seat Intact?
YES NO
Cooler Temp:
-------
"s:
Page
Project #:
CFA Quote#:
COC Number0':.
PO Number:
* of wjL^
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: LI f)
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910)795-0421
Client Namer^Tc. . phone f tf
Sample Analysis Requested
I668B) and number of containers provided for each (i.e. 8290B - 3,1668B - i).
6.) Preservative Type: HA - Hydrochloric Acid»NI = Nitric Acid, SH = Sodium Hydroxide, SA - Sulfuric Acid, AA = Ascorbic Acid, HX = Hexane, ST = Sodium Thiosulfate, If no preservative is added = leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intact?
YES NO
-------
SAMPLE RECEIPT CHECKLIST
Client:
Work Order; jg ^ ^ £)
Shipping Company: |-C$C
Date/Time Received: \^\ (fiO
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
Samples identified as Foreign Soil?
6^
DOE Site Sample Packages
Yes
NA
No*
Screened <0.5 rnR/hr?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Air Sample Receipt Specifics
Yes
NA
No
Air Witness:
Air sample in shipment?
~
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers {required for Non-Conforming Items}
1
Shipping containers received intact
and sealed?
i/
X
Circle Applicable;
seals broken damaged container leaking container otherfriesct'be'
2
Chain of Custody documents included
with shipment?
/ '
3
Samples requiring cold preservation
within 0-6°C?
o
/
Presjgcwaiiijfi Method:
v(bags^ctue ice dry ice none other (describe)
4
Aqueous samples found to have visible
solids?
Sample IDs, containers affected:
5
Samples requiring chemical
preservation at proper pH?
L*
X
Sample IDs, containers affected and pH observed:
If preservative added, LotS:
6
Samples requiring preservation have
no residual chlorine?
Sample IDs, containers affected;
If preservative added. Lot#:
7
Samples received within holding time?
V
S"'
Sample IDs, tests affected;
8
Sample IDs on COC match IDs on
containers?
V/
Sample IDs, containers affected:
9
Date & time of COC match date & time
on containers?
\J
Sample IDs, containers affected: r
10
Number of containers received match
number indicated on COC?
S •
Sample IDs, containers affected;
11
COC form is properly signed in
relinquished/received sections?
Comments: «
6'o^U- ivJM ih> CO(_ tn £MU- : Si-M- 4-lo, 17,
4-s-l.
— 5 z HfiJoMJLw iZ-Sh, Coo
CgM&cM&yx ci&M. 5 ^ Z -(T-H, c-
d'T 4(s -/ H .
Date: %Q I ^
Checklist performed by: Initials:
Page 4 of 47
-------
correct information for samples from Strecker Forest site
Subject: correct information for samples from Strecker Forest site
From: "rclaytor@seagullenvirotech.com"
Date: 5/21/2014 6:56 PM
To: cynde.larkins@cfanalytical.com
I have provided the information you requested, I am sorry for any inconvenience it might have
caused.
CFA received your soil samples for the Strecker Forest project and
> there are a few discrepancies to bring to your attention.
>
> 1. Sample SFRA-42 has a collection date on the label of 5/15/14 while
> the COC has 05-16-14. Will you please verify the correct date? The correct date is
5/16/14
>
> 2. Sample SFRA-52 has a collection time on the label of 12:58 while The correct time is 1258
> the COC has 10:49. Will you please verify the correct time?
>
> 3. The following samples do not have collection times on the COC or
> the labels: SFRA-46, 47, 48, 49, 50 and 51. Please send the
> collection times.
>#46 @1819, #47 @ 1823, #48 @ 1826, #49 @ 1828, #50@ 1831,
and #51 @ 1835
> Let me know if there are any questions. The COC is attached for your
> review.
>
> Thank you,
>
Cynde Larkins
Project Manager Assistant
Cape Fear Analytical
3306 Kitty Hawk Road
Suite 120
Wilmington, NC 28405
(910) 795-0421
Rick Claytor, CHMM
Sr. Environmental Scientist
Seagull Environmental Technologies, Inc.
Woman-Owned, 8(a) Firm
email: rclaytor@seagullenvirotech.com
lofl
Page 5 of 47
5/22/2014 8:53 AM
-------
High Resolution Dioxins
and Furans Analysis
Page 6 of 47
-------
Case Narrative
Page 7 of 47
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6130
Method/Analysis Information
Product:
Analytical Method:
Extraction Method:
Dioxins/Furans by EPA Method 1613B in Solids
EPA Method 1613B
SW846 3540C
Analytical Batch Number: 25962
Clean Up Batch Number: 25961
Extraction Batch Number: 25960
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6130001 SFRA-42
6130002 SFRA-43
6130003 SFRA-44
6130004 SFRA-45
6130005 SFRA-46
6130006 SFRA-47
6130007 SFRA-48
6130008 SFRA-49
6130009 SFRA-50
6130010 SFRA-51
6130011 SFRA-52
6130012 SFRA-53
6130013 SFRA-54
6130014 SFRA-55
12010459 Method Blank (MB)
12010460 Laboratory Control Sample (LCS)
12010461 Laboratory Control Sample Duplicate (LCSD)
12010462 6130001 (SFRA-42) Matrix Spike (MS)
12010463 6130001 (SFRA-42) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Page 8 of 47
-------
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6130001 (SFRA-42)- Batch 25962 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike/Duplicate (MS/MSD) Recovery Statement
The MS recoveries for this SDG were not within the acceptance limits. The failures confirm in
the matrix spike duplicate and are attributed to matrix interference. 12010462 (SFRA-42) and
12010463 (SFRA-42)- Batch 25962.
MS/MSD Relative Percent Difference (RPD) Statement
Page 9 of 47
-------
The relative percent differences (RPD) between each MS and MSD were not within the required
acceptance limits. Sample data is validated based on acceptable LCS/LCSD results. 12010462
(SFRA-42) and 12010463 (SFRA-42)- Batch 25962.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A lg aliquot was used for extraction due to known high levels of target analytes from this site.
Batch 25962.
Sample Dilutions
Samples 12010462 (SFRA-42), 12010463 (SFRA-42), 6130001 (SFRA-42), 6130002 (SFRA-
43), 6130003 (SFRA-44), 6130004 (SFRA-45), 6130005 (SFRA-46), 6130006 (SFRA-47),
6130007 (SFRA-48), 6130010 (SFRA-51), 6130012 (SFRA-53), 6130013 (SFRA-54) and
6130014 (SFRA-55)- Batch 25962 were diluted due to the presence of overrange target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
The following NCR was generated for this SDG: 644524 12010463 (SFRA-42)- Batch 25962.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
Page 10 of 47
-------
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 11 of 47
-------
Sample Data Summary
Page 12 of 47
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6130 CFA Work Order: 6130
Name: Heather Patterson
Date: 23 MAY 2014
Title: Data Validator
Page 13 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 6130001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 09:20
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 19.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-42
25962
05/22/2014 12:13
A20MAY14B7-2
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.33 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
6160
Pg/g
14.9 93.3
40321-76-4
1,2,3,7,8-PeCDD
U
13.3
Pg/g
13.3 466
39227-28-6
1,2,3,4,7,8-HxCDD
u
24.2
Pg/g
24.2 466
57653-85-7
1,2,3,6,7,8-HxCDD
J
40.5
Pg/g
25.9 466
19408-74-3
1,2,3,7,8,9-HxCDD
u
26.7
Pg/g
26.7 466
35822-46-9
1,2,3,4,6,7,8-HpCDD
766
Pg/g
33.9 466
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13900
Pg/g
141 933
51207-31-9
2,3,7,8-TCDF
J
33.6
Pg/g
16.6 93.3
57117-41-6
1,2,3,7,8-PeCDF
u
12.7
Pg/g
12.7 466
57117-31-4
2,3,4,7,8-PeCDF
u
13.2
Pg/g
13.2 466
70648-26-9
1,2,3,4,7,8-HxCDF
J
20.9
Pg/g
9.94 466
57II7.44.9
1,2,3,6,7,8-HxCDF
u
9.64
Pg/g
9.64 466
60851-34-5
2,3,4,6,7,8-HxCDF
J
14.6
Pg/g
10.3 466
72918-21-9
1,2,3,7,8,9-HxCDF
u
20.1
Pg/g
20.1 466
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
140
Pg/g
10.9 466
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
19.2
Pg/g
19.2 466
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
226
Pg/g
46.4 933
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1440
1870
Pg/g
77.1
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1460
1870
Pg/g
78.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1650
1870
Pg/g
88.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1820
1870
Pg/g
97.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1620
1870
Pg/g
86.8
(23%-140%)
13C-OCDD
3050
3730
Pg/g
81.7
(17%-157%)
13C-2,3,7,8-TCDF
1600
1870
Pg/g
85.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
1460
1870
Pg/g
78.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1500
1870
Pg/g
80.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1680
1870
Pg/g
89.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1820
1870
Pg/g
97.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1750
1870
Pg/g
93.7
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1370
1870
Pg/g
73.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1720
1870
Pg/g
92.5
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1460
1870
Pg/g
78.5
(26%-13 8%)
3701-2,3,7,8-TCDD
197
187
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6130
Lab Sample ID: 6130002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/16/201411:25
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 21.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-43
25962
05/22/2014 14:36
A20MAY14B7-5
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.15 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20700
Pg/g
23.3 111
40321-76-4
1,2,3,7,8-PeCDD
U
20.5
Pg/g
20.5 554
39227-28-6
1,2,3,4,7,8-HxCDD
J
31.6
Pg/g
25.3 554
57653-85-7
1,2,3,6,7,8-HxCDD
J
57.2
Pg/g
25.1 554
19408-74-3
1,2,3,7,8,9-HxCDD
u
29.7
Pg/g
29.7 554
35822-46-9
1,2,3,4,6,7,8-HpCDD
952
Pg/g
49.0 554
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13400
Pg/g
203 1110
51207-31-9
2,3,7,8-TCDF
J
94.0
Pg/g
29.5 111
57117-41-6
1,2,3,7,8-PeCDF
u
17
Pg/g
17.0 554
57117-31-4
2,3,4,7,8-PeCDF
u
16.3
Pg/g
16.3 554
70648-26-9
1,2,3,4,7,8-HxCDF
J
29.1
Pg/g
21.6 554
57II7.44.9
1,2,3,6,7,8-HxCDF
u
21.8
Pg/g
21.8 554
60851-34-5
2,3,4,6,7,8-HxCDF
u
21.5
Pg/g
21.5 554
72918-21-9
1,2,3,7,8,9-HxCDF
u
36.8
Pg/g
36.8 554
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
244
Pg/g
17.6 554
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
36.6
Pg/g
36.6 554
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
301
Pg/g
70.5 1110
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1830
2220
Pg/g
82.7
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1870
2220
Pg/g
84.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1760
2220
Pg/g
79.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2040
2220
Pg/g
92.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1850
2220
Pg/g
83.3
(23%-140%)
13C-OCDD
3220
4430
Pg/g
72.6
(17%-157%)
13C-2,3,7,8-TCDF
2020
2220
Pg/g
91.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
1910
2220
Pg/g
86.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
1970
2220
Pg/g
88.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1800
2220
Pg/g
81.4
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1890
2220
Pg/g
85.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1920
2220
Pg/g
86.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1470
2220
Pg/g
66.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1920
2220
Pg/g
86.5
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1610
2220
Pg/g
72.8
(26%-13 8%)
3701-2,3,7,8-TCDD
276
222
Pg/g
124
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6130
6130003
1613B Soil
SFRA-44
25962
05/22/2014 15:24
A20MAY14B_7-6
25960
20-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
J
J
J
J
u
J
J
u
J
u
u
J
TETR001
05/16/2014 13:55
05/20/201411:10
EPA Method 1613B
JTF
SW846 3540C
1.05 g
Result
14000
13.2
31.2
233
72.1
2160
15500
86.4
9.89
12.0
53.2
22.6
37.4
26.4
736
38.3
661
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
8.87
13.2
24.9
25.4
26.6
36.4
103
16.1
9.89
9.31
15.2
22.6
14.8
26.4
14.1
38.3
64.7
TETR00114
SOLID
22
Dry Weight
HRP750
10
PQL
122
611
611
611
611
611
1220
122
61
61
61
61
61
61
61
61
1220
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2070
2440
Pg/g
84.7
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2040
2440
Pg/g
83.6
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1780
2440
Pg/g
73.0
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
2220
2440
Pg/g
91.0
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2050
2440
Pg/g
84.0
(23%-140%)
13C-OCDD
3900
4890
Pg/g
79.8
(17%-157%)
13C-2,3,7,8-TCDF
2210
2440
Pg/g
90.3
(24%-169%)
13C-1,2,3,7,8-PeCDF
2130
2440
Pg/g
87.3
(24%-185%)
13C-2,3,4,7,8-PeCDF
2160
2440
Pg/g
88.3
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1870
2440
Pg/g
76.6
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2100
2440
Pg/g
86.0
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2040
2440
Pg/g
83.4
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1680
2440
Pg/g
68.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2080
2440
Pg/g
84.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1820
2440
Pg/g
74.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
311
244
Pg/g
127
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6130
6130004
1613B Soil
SFRA-45
25962
05/22/2014 16:19
A20MAY14B 7-7
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
05/16/2014 17:06
05/20/2014 11:10
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
20.4
Dry Weight
HRP750
10
Prep Batch:
25960
Prep Method:
SW846 3540C
Prep Date:
20-MAY-14
Prep Aliquot:
1.16 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
10600
Pg/g
17.9 108
40321-76-4
1,2,3,7,8-PeCDD
U
15.3
Pg/g
15.3 541
39227-28-6
1,2,3,4,7,8-HxCDD
u
28.4
Pg/g
28.4 541
57653-85-7
1,2,3,6,7,8-HxCDD
J
40.2
Pg/g
28.4 541
19408-74-3
1,2,3,7,8,9-HxCDD
u
30.1
Pg/g
30.1 541
35822-46-9
1,2,3,4,6,7,8-HpCDD
605
Pg/g
36.8 541
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11800
Pg/g
141 1080
51207-31-9
2,3,7,8-TCDF
J
56.6
Pg/g
25.1 108
57117-41-6
1,2,3,7,8-PeCDF
u
12.6
Pg/g
12.6 541
57117-31-4
2,3,4,7,8-PeCDF
u
11.8
Pg/g
11.8 541
70648-26-9
1,2,3,4,7,8-HxCDF
u
16.6
Pg/g
16.6 541
57II7.44.9
1,2,3,6,7,8-HxCDF
u
16.6
Pg/g
16.6 541
60851-34-5
2,3,4,6,7,8-HxCDF
u
17.4
Pg/g
17.4 541
72918-21-9
1,2,3,7,8,9-HxCDF
u
32.5
Pg/g
32.5 541
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
158
Pg/g
21.1 541
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
37.9
Pg/g
37.9 541
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
209
Pg/g
55.9 1080
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1690
2170
Pg/g
77.8
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1750
2170
Pg/g
81.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1640
2170
Pg/g
75.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2040
2170
Pg/g
94.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1900
2170
Pg/g
87.6
(23%-140%)
13C-OCDD
3240
4330
Pg/g
74.7
(17%-157%)
13C-2,3,7,8-TCDF
1850
2170
Pg/g
85.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1820
2170
Pg/g
84.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
1840
2170
Pg/g
85.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1660
2170
Pg/g
76.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1910
2170
Pg/g
88.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1850
2170
Pg/g
85.5
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1500
2170
Pg/g
69.3
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1840
2170
Pg/g
85.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1600
2170
Pg/g
74.1
(26%-13 8%)
3701-2,3,7,8-TCDD
252
217
Pg/g
116
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6130
6130005
1613B Soil
SFRA-46
25962
05/22/2014 17:06
A20MAY14B 7-8
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
05/16/2014 18:19
05/20/2014 11:10
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
28.1
Dry Weight
HRP750
10
Prep Batch:
25960
Prep Method:
SW846 3540C
Prep Date:
20-MAY-14
Prep Aliquot:
1.01 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
30700
Pg/g
20.1 138
40321-76-4
1,2,3,7,8-PeCDD
U
17.2
Pg/g
17.2 688
39227-28-6
1,2,3,4,7,8-HxCDD
u
77.3
Pg/g
77.3 688
57653-85-7
1,2,3,6,7,8-HxCDD
J
100
Pg/g
72.4 688
19408-74-3
1,2,3,7,8,9-HxCDD
u
79
Pg/g
79.0 688
35822-46-9
1,2,3,4,6,7,8-HpCDD
1060
Pg/g
53.7 688
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13000
Pg/g
162 1380
51207-31-9
2,3,7,8-TCDF
J
137
Pg/g
23.2 138
57117-41-6
1,2,3,7,8-PeCDF
u
13.3
Pg/g
13.3 688
57117-31-4
2,3,4,7,8-PeCDF
u
13.2
Pg/g
13.2 688
70648-26-9
1,2,3,4,7,8-HxCDF
J
30.4
Pg/g
18.0 688
57II7.44.9
1,2,3,6,7,8-HxCDF
u
17.6
Pg/g
17.6 688
60851-34-5
2,3,4,6,7,8-HxCDF
u
22
Pg/g
22.0 688
72918-21-9
1,2,3,7,8,9-HxCDF
u
28.1
Pg/g
28.1 688
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
426
Pg/g
14.1 688
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
26
Pg/g
26.0 688
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
559
Pg/g
61.4 1380
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2190
2750
Pg/g
79.4
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2130
2750
Pg/g
77.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2040
2750
Pg/g
74.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2340
2750
Pg/g
84.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2320
2750
Pg/g
84.3
(23%-140%)
13C-OCDD
4010
5500
Pg/g
72.8
(17%-157%)
13C-2,3,7,8-TCDF
2390
2750
Pg/g
87.0
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2160
2750
Pg/g
78.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
2250
2750
Pg/g
81.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2080
2750
Pg/g
75.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2300
2750
Pg/g
83.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2250
2750
Pg/g
81.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1830
2750
Pg/g
66.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2390
2750
Pg/g
86.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2000
2750
Pg/g
72.5
(26%-13 8%)
3701-2,3,7,8-TCDD
354
275
Pg/g
129
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 18 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 6130006
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 18:23
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 22
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-47
25962
05/22/2014 09:33
A20MA Y14B6-10
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.19 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 2
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
4310
Pg/g
4.35 21.5
40321-76-4
1,2,3,7,8-PeCDD
U
2.89
Pg/g
2.89 108
39227-28-6
1,2,3,4,7,8-HxCDD
u
5.93
Pg/g
5.93 108
57653-85-7
1,2,3,6,7,8-HxCDD
u
6.06
Pg/g
6.06 108
19408-74-3
1,2,3,7,8,9-HxCDD
u
6.36
Pg/g
6.36 108
35822-46-9
1,2,3,4,6,7,8-HpCDD
153
Pg/g
7.56 108
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7910
Pg/g
27.2 215
51207-31-9
2,3,7,8-TCDF
J
19.7
Pg/g
4.70 21.5
57117-41-6
1,2,3,7,8-PeCDF
u
1.77
Pg/g
1.77 108
57117-31-4
2,3,4,7,8-PeCDF
u
1.69
Pg/g
1.69 108
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.31
Pg/g
2.31 108
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.18
Pg/g
2.18 108
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.35
Pg/g
2.35 108
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.81
Pg/g
3.81 108
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
16.9
Pg/g
1.85 108
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
3.08
Pg/g
3.08 108
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
28.9
Pg/g
6.87 215
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1790
2150
Pg/g
82.8
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1890
2150
Pg/g
87.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1690
2150
Pg/g
78.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1850
2150
Pg/g
86.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1920
2150
Pg/g
88.9
(23%-140%)
13C-OCDD
3850
4310
Pg/g
89.4
(17%-157%)
13C-2,3,7,8-TCDF
1920
2150
Pg/g
89.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
1930
2150
Pg/g
89.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1910
2150
Pg/g
88.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1710
2150
Pg/g
79.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1800
2150
Pg/g
83.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1830
2150
Pg/g
85.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1550
2150
Pg/g
71.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1850
2150
Pg/g
85.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1810
2150
Pg/g
84.1
(26%-13 8%)
3701-2,3,7,8-TCDD
224
215
Pg/g
104
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 6130007
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 18:26
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 19.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-48
25962
05/22/2014 17:54
A20MAY14B7-9
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.13 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
7320
Pg/g
10.5 55.0
40321-76-4
1,2,3,7,8-PeCDD
U
8.22
Pg/g
8.22 275
39227-28-6
1,2,3,4,7,8-HxCDD
u
16.2
Pg/g
16.2 275
57653-85-7
1,2,3,6,7,8-HxCDD
u
27.3
Pg/g
27.3 275
19408-74-3
1,2,3,7,8,9-HxCDD
u
16.2
Pg/g
16.2 275
35822-46-9
1,2,3,4,6,7,8-HpCDD
408
Pg/g
35.6 275
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9930
Pg/g
100 550
51207-31-9
2,3,7,8-TCDF
J
51.6
Pg/g
13.4 55.0
57117-41-6
1,2,3,7,8-PeCDF
u
5.83
Pg/g
5.83 275
57117-31-4
2,3,4,7,8-PeCDF
u
5.85
Pg/g
5.85 275
70648-26-9
1,2,3,4,7,8-HxCDF
u
10.8
Pg/g
10.8 275
57II7.44.9
1,2,3,6,7,8-HxCDF
u
10.5
Pg/g
10.5 275
60851-34-5
2,3,4,6,7,8-HxCDF
u
11
Pg/g
11.0 275
72918-21-9
1,2,3,7,8,9-HxCDF
u
20.2
Pg/g
20.2 275
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
101
Pg/g
7.45 275
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
15.3
Pg/g
15.3 275
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
101
Pg/g
24.6 550
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1860
2200
Pg/g
84.7
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1840
2200
Pg/g
83.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1760
2200
Pg/g
80.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2090
2200
Pg/g
94.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1900
2200
Pg/g
86.6
(23%-140%)
13C-OCDD
3500
4400
Pg/g
79.6
(17%-157%)
13C-2,3,7,8-TCDF
1930
2200
Pg/g
87.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
1980
2200
Pg/g
89.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
1920
2200
Pg/g
87.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1800
2200
Pg/g
81.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1980
2200
Pg/g
90.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1980
2200
Pg/g
89.9
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1600
2200
Pg/g
72.9
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2000
2200
Pg/g
90.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1730
2200
Pg/g
78.5
(26%-13 8%)
3701-2,3,7,8-TCDD
228
220
Pg/g
104
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 20 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 6130008
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 18:28
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 20.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-49
25962
05/22/2014 08:43
A20MA Y14B6-9
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.29 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1410
Pg/g
1.22 9.80
40321-76-4
1,2,3,7,8-PeCDD
U
1.78
Pg/g
1.78 49.0
39227-28-6
1,2,3,4,7,8-HxCDD
J
7.61
Pg/g
3.00 49.0
57653-85-7
1,2,3,6,7,8-HxCDD
J
11.5
Pg/g
3.12 49.0
19408-74-3
1,2,3,7,8,9-HxCDD
J
5.39
Pg/g
3.25 49.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
270
Pg/g
5.27 49.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8070
Pg/g
14.3 98.0
51207-31-9
2,3,7,8-TCDF
J
8.80
Pg/g
2.12 9.80
57117-41-6
1,2,3,7,8-PeCDF
u
2.22
Pg/g
2.22 49.0
57117-31-4
2,3,4,7,8-PeCDF
u
2.02
Pg/g
2.02 49.0
70648-26-9
1,2,3,4,7,8-HxCDF
J
5.00
Pg/g
1.47 49.0
57II7.44.9
1,2,3,6,7,8-HxCDF
J
1.84
Pg/g
1.51 49.0
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.41
Pg/g
2.41 49.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.31
Pg/g
2.31 49.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
43.1
Pg/g
1.46 49.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
3.41
Pg/g
2.45 49.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
75.9
Pg/g
3.69 98.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1570
1960
Pg/g
80.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1710
1960
Pg/g
87.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1470
1960
Pg/g
75.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1640
1960
Pg/g
83.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1700
1960
Pg/g
86.8
(23%-140%)
13C-OCDD
3530
3920
Pg/g
90.0
(17%-157%)
13C-2,3,7,8-TCDF
1680
1960
Pg/g
85.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
1660
1960
Pg/g
84.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
1670
1960
Pg/g
85.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1460
1960
Pg/g
74.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1530
1960
Pg/g
78.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1560
1960
Pg/g
79.6
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1380
1960
Pg/g
70.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1650
1960
Pg/g
84.2
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1610
1960
Pg/g
81.9
(26%-13 8%)
3701-2,3,7,8-TCDD
199
196
Pg/g
101
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 21 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 6130009
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 18:31
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 22
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-50
25962
05/22/2014 03:11
A20MA Y14B6-2
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.27 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2650
Pg/g
1.69 10.1
40321-76-4
1,2,3,7,8-PeCDD
U
3.51
Pg/g
3.51 50.4
39227-28-6
1,2,3,4,7,8-HxCDD
J
17.8
Pg/g
3.41 50.4
57653-85-7
1,2,3,6,7,8-HxCDD
57.7
Pg/g
3.47 50.4
19408-74-3
1,2,3,7,8,9-HxCDD
J
17.9
Pg/g
3.65 50.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
642
Pg/g
5.81 50.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12100
Pg/g
15.9 101
51207-31-9
2,3,7,8-TCDF
17.3
Pg/g
2.50 10.1
57117-41-6
1,2,3,7,8-PeCDF
J
14.9
Pg/g
2.42 50.4
57117-31-4
2,3,4,7,8-PeCDF
J
3.21
Pg/g
2.36 50.4
70648-26-9
1,2,3,4,7,8-HxCDF
J
13.1
Pg/g
1.85 50.4
57II7.44.9
1,2,3,6,7,8-HxCDF
J
5.45
Pg/g
1.83 50.4
60851-34-5
2,3,4,6,7,8-HxCDF
J
7.39
Pg/g
1.76 50.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.93
Pg/g
2.93 50.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
106
Pg/g
1.80 50.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
9.14
Pg/g
3.05 50.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
190
Pg/g
2.24 101
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1660
2020
Pg/g
82.5
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1740
2020
Pg/g
86.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1610
2020
Pg/g
79.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1750
2020
Pg/g
86.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1910
2020
Pg/g
94.9
(23%-140%)
13C-OCDD
3980
4040
Pg/g
98.6
(17%-157%)
13C-2,3,7,8-TCDF
1800
2020
Pg/g
89.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
1810
2020
Pg/g
89.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
1780
2020
Pg/g
88.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1640
2020
Pg/g
81.4
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1710
2020
Pg/g
84.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1740
2020
Pg/g
86.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1530
2020
Pg/g
75.7
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1820
2020
Pg/g
90.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1740
2020
Pg/g
86.2
(26%-13 8%)
3701-2,3,7,8-TCDD
212
202
Pg/g
105
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 22 of 47
-------
Cape Fear Analytical LLC
Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6130
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6130009
Date Collected:
05/16/2014 18:31
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
05/20/2014 11:10
%Moisture:
22
Client ID:
SFRA-50
Prep Basis:
Dry Weight
Batch ID:
25962
Method:
EPA Method 1613B
Run Date:
05/22/2014 11:11
Analyst:
JTF
Instrument:
HRP763
Data File:
b22mayl4a-4
Dilution:
1
Prep Batch:
25960
Prep Method:
SW846 3540C
Prep Date:
20-MAY-14
Prep Aliquot:
1.27 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
19.1
Pg/g
2.36
10.1
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 23 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 6130010
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 18:35
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 18.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-51
25962
05/22/2014 18:42
A20MA Y14B7-10
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.16 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
4380
Pg/g
9.02 53.0
40321-76-4
1,2,3,7,8-PeCDD
U
7.73
Pg/g
7.73 265
39227-28-6
1,2,3,4,7,8-HxCDD
J
15.6
Pg/g
12.4 265
57653-85-7
1,2,3,6,7,8-HxCDD
J
29.3
Pg/g
12.6 265
19408-74-3
1,2,3,7,8,9-HxCDD
u
13.2
Pg/g
13.2 265
35822-46-9
1,2,3,4,6,7,8-HpCDD
533
Pg/g
19.0 265
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12500
Pg/g
92.6 530
51207-31-9
2,3,7,8-TCDF
J
26.2
Pg/g
10.5 53.0
57117-41-6
1,2,3,7,8-PeCDF
u
9.77
Pg/g
9.77 265
57117-31-4
2,3,4,7,8-PeCDF
u
9.51
Pg/g
9.51 265
70648-26-9
1,2,3,4,7,8-HxCDF
u
13.2
Pg/g
13.2 265
57II7.44.9
1,2,3,6,7,8-HxCDF
u
7.71
Pg/g
7.71 265
60851-34-5
2,3,4,6,7,8-HxCDF
u
8.01
Pg/g
8.01 265
72918-21-9
1,2,3,7,8,9-HxCDF
u
14
Pg/g
14.0 265
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
96.7
Pg/g
5.72 265
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
11.5
Pg/g
11.5 265
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
136
Pg/g
33.3 530
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1660
2120
Pg/g
78.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1680
2120
Pg/g
79.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1510
2120
Pg/g
71.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1950
2120
Pg/g
92.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1710
2120
Pg/g
80.8
(23%-140%)
13C-OCDD
3290
4240
Pg/g
77.8
(17%-157%)
13C-2,3,7,8-TCDF
1840
2120
Pg/g
86.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1730
2120
Pg/g
81.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1750
2120
Pg/g
82.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1590
2120
Pg/g
75.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1790
2120
Pg/g
84.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1780
2120
Pg/g
84.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1380
2120
Pg/g
65.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1740
2120
Pg/g
82.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1560
2120
Pg/g
73.7
(26%-13 8%)
3701-2,3,7,8-TCDD
211
212
Pg/g
99.5
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 24 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6130
6130011
1613B Soil
SFRA-52
25962
05/22/2014 04:46
A20MA Y14B6-4
25960
20-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
J
J
J
J
u
J
u
J
TETR001
05/19/2014 12:58
05/20/201411:10
EPA Method 1613B
JTF
SW846 3540C
1.06 g
Result
2400
2.31
3.20
13.0
6.06
262
7840
13.3
1.39
2.53
2.91
1.90
2.91
2.04
45.0
2.89
120
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
1.37
1.78
2.79
2.89
3.01
5.08
13.9
2.77
1.39
1.37
1.37
1.37
1.40
2.04
1.37
2.89
3.54
TETR00114
SOLID
21.6
Dry Weight
HRP750
1
PQL
12.0
60.1
60.1
60.1
60.1
60.1
120
12.0
60.1
60.1
60.1
60.1
60.1
60.1
60.1
60.1
120
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2070
2410
Pg/g
86.2
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2150
2410
Pg/g
89.3
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1920
2410
Pg/g
79.8
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
2070
2410
Pg/g
86.1
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2320
2410
Pg/g
96.6
(23%-140%)
13C-OCDD
4690
4810
Pg/g
97.5
(17%-157%)
13C-2,3,7,8-TCDF
2190
2410
Pg/g
91.2
(24%-169%)
13C-1,2,3,7,8-PeCDF
2190
2410
Pg/g
91.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
2160
2410
Pg/g
89.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1920
2410
Pg/g
79.7
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2020
2410
Pg/g
83.8
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2040
2410
Pg/g
84.6
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1860
2410
Pg/g
77.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2190
2410
Pg/g
91.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2150
2410
Pg/g
89.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
255
241
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 25 of 47
-------
Cape Fear Analytical LLC
Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6130
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6130011
Date Collected:
05/19/2014 12:58
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
05/20/2014 11:10
%Moisture:
21.6
Client ID:
SFRA-52
Prep Basis:
Dry Weight
Batch ID:
25962
Method:
EPA Method 1613B
Run Date:
05/22/2014 11:30
Analyst:
JTF
Instrument:
HRP763
Data File:
b22mayl4a-5
Dilution:
1
Prep Batch:
25960
Prep Method:
SW846 3540C
Prep Date:
20-MAY-14
Prep Aliquot:
1.06 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
13.9
Pg/g
3.39
12.0
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 26 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6130
6130012
1613B Soil
SFRA-53
25962
05/22/2014 19:30
A20MAY14B 7-11
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
05/19/2014 13:05
05/20/2014 11:10
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
22.8
Dry Weight
HRP750
20
Prep Batch:
25960
Prep Method:
SW846 3540C
Prep Date:
20-MAY-14
Prep Aliquot:
1.05 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
42600
Pg/g
37.0 247
40321-76-4
1,2,3,7,8-PeCDD
U
26.9
Pg/g
26.9 1230
39227-28-6
1,2,3,4,7,8-HxCDD
u
48.4
Pg/g
48.4 1230
57653-85-7
1,2,3,6,7,8-HxCDD
u
45.4
Pg/g
45.4 1230
19408-74-3
1,2,3,7,8,9-HxCDD
u
49.4
Pg/g
49.4 1230
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
904
Pg/g
102 1230
3268-87-9
1,2,3,4,6,7,8,9-OCDD
15700
Pg/g
291 2470
51207-31-9
2,3,7,8-TCDF
J
186
Pg/g
33.3 247
57117-41-6
1,2,3,7,8-PeCDF
u
19.4
Pg/g
19.4 1230
57117-31-4
2,3,4,7,8-PeCDF
u
19.2
Pg/g
19.2 1230
70648-26-9
1,2,3,4,7,8-HxCDF
u
22
Pg/g
22.0 1230
57II7.44.9
1,2,3,6,7,8-HxCDF
u
21.5
Pg/g
21.5 1230
60851-34-5
2,3,4,6,7,8-HxCDF
u
24.2
Pg/g
24.2 1230
72918-21-9
1,2,3,7,8,9-HxCDF
u
42
Pg/g
42.0 1230
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
156
Pg/g
24.9 1230
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
41
Pg/g
41.0 1230
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
581
Pg/g
110 2470
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1690
2470
Pg/g
68.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1750
2470
Pg/g
70.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1610
2470
Pg/g
65.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2000
2470
Pg/g
81.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1760
2470
Pg/g
71.4
(23%-140%)
13C-OCDD
3020
4940
Pg/g
61.1
(17%-157%)
13C-2,3,7,8-TCDF
1890
2470
Pg/g
76.4
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1780
2470
Pg/g
72.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1780
2470
Pg/g
72.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1690
2470
Pg/g
68.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1920
2470
Pg/g
77.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1820
2470
Pg/g
73.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1410
2470
Pg/g
57.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1770
2470
Pg/g
71.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1640
2470
Pg/g
66.3
(26%-13 8%)
3701-2,3,7,8-TCDD
342
247
Pg/g
139
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 27 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6130
6130013
1613B Soil
SFRA-54
25962
05/22/2014 20:17
A20MAY14B 7-12
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
05/19/2014 15:40
05/20/2014 11:10
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
23.9
Dry Weight
HRP750
10
Prep Batch:
25960
Prep Method:
SW846 3540C
Prep Date:
20-MAY-14
Prep Aliquot:
1.16 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
19700
Pg/g
17.0 113
40321-76-4
1,2,3,7,8-PeCDD
U
8.16
Pg/g
8.16 567
39227-28-6
1,2,3,4,7,8-HxCDD
u
21.1
Pg/g
21.1 567
57653-85-7
1,2,3,6,7,8-HxCDD
J
23.3
Pg/g
19.8 567
19408-74-3
1,2,3,7,8,9-HxCDD
u
21.5
Pg/g
21.5 567
35822-46-9
1,2,3,4,6,7,8-HpCDD
848
Pg/g
56.9 567
3268-87-9
1,2,3,4,6,7,8,9-OCDD
23700
Pg/g
148 1130
51207-31-9
2,3,7,8-TCDF
J
81.4
Pg/g
12.4 113
57117-41-6
1,2,3,7,8-PeCDF
u
5.12
Pg/g
5.12 567
57117-31-4
2,3,4,7,8-PeCDF
u
4.87
Pg/g
4.87 567
70648-26-9
1,2,3,4,7,8-HxCDF
u
6.1
Pg/g
6.10 567
57II7.44.9
1,2,3,6,7,8-HxCDF
u
6.55
Pg/g
6.55 567
60851-34-5
2,3,4,6,7,8-HxCDF
u
6.48
Pg/g
6.48 567
72918-21-9
1,2,3,7,8,9-HxCDF
u
11.1
Pg/g
11.1 567
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
140
Pg/g
11.7 567
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
21.6
Pg/g
21.6 567
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
622
Pg/g
56.4 1130
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1880
2270
Pg/g
83.0
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1900
2270
Pg/g
83.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1810
2270
Pg/g
79.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2250
2270
Pg/g
99.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2010
2270
Pg/g
88.7
(23%-140%)
13C-OCDD
3980
4530
Pg/g
87.7
(17%-157%)
13C-2,3,7,8-TCDF
2020
2270
Pg/g
89.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1940
2270
Pg/g
85.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
2040
2270
Pg/g
89.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1970
2270
Pg/g
86.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2150
2270
Pg/g
94.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2060
2270
Pg/g
90.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1680
2270
Pg/g
73.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2080
2270
Pg/g
91.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1920
2270
Pg/g
84.6
(26%-13 8%)
3701-2,3,7,8-TCDD
300
227
Pg/g
132
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 28 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6130
Lab Sample ID: 6130014
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/19/2014 16:50
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 22.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-55
25962
05/22/2014 21:05
A20MAY14B7-13
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.25 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
13800
Pg/g
19.0 103
40321-76-4
1,2,3,7,8-PeCDD
U
16.6
Pg/g
16.6 517
39227-28-6
1,2,3,4,7,8-HxCDD
J
36.7
Pg/g
34.8 517
57653-85-7
1,2,3,6,7,8-HxCDD
J
150
Pg/g
32.5 517
19408-74-3
1,2,3,7,8,9-HxCDD
J
54.8
Pg/g
35.4 517
35822-46-9
1,2,3,4,6,7,8-HpCDD
1430
Pg/g
66.0 517
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14000
Pg/g
185 1030
51207-31-9
2,3,7,8-TCDF
J
78.6
Pg/g
35.6 103
57117-41-6
1,2,3,7,8-PeCDF
u
16.1
Pg/g
16.1 517
57117-31-4
2,3,4,7,8-PeCDF
u
16
Pg/g
16.0 517
70648-26-9
1,2,3,4,7,8-HxCDF
u
33.2
Pg/g
33.2 517
57II7.44.9
1,2,3,6,7,8-HxCDF
J
19.3
Pg/g
19.2 517
60851-34-5
2,3,4,6,7,8-HxCDF
u
22.1
Pg/g
22.1 517
72918-21-9
1,2,3,7,8,9-HxCDF
u
37.5
Pg/g
37.5 517
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
453
Pg/g
21.5 517
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
38.7
Pg/g
38.7 517
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
423
Pg/g
79.1 1030
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1620
2070
Pg/g
78.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1730
2070
Pg/g
83.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1480
2070
Pg/g
71.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1910
2070
Pg/g
92.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1730
2070
Pg/g
83.8
(23%-140%)
13C-OCDD
3190
4140
Pg/g
77.0
(17%-157%)
13C-2,3,7,8-TCDF
1840
2070
Pg/g
89.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
1730
2070
Pg/g
83.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1770
2070
Pg/g
85.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1540
2070
Pg/g
74.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1870
2070
Pg/g
90.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1760
2070
Pg/g
85.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1380
2070
Pg/g
66.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1630
2070
Pg/g
79.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1400
2070
Pg/g
67.7
(26%-13 8%)
3701-2,3,7,8-TCDD
216
207
Pg/g
104
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 29 of 47
-------
Quality Control
Summary
Page 30 of 47
-------
( ape Fear \lltllytictll LLC Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 1 of 7
Surrogate Recovery Report
SDG Number: 6130
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010460
LCS for batch 25960
12010461
LCSD for batch 25960
12010459
MB for batch 25960
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
77.0
82.5
81.4
84.3
87.9
81.4
85.8
83.2
81.9
80.4
83.0
84.2
71.1
83.0
77.3
94.0
84.7
92.6
85.1
87.3
95.6
93.5
92.7
90.7
90.8
83.4
83.3
85.1
75.6
89.5
88.8
97.8
82.8
89.0
87.9
90.0
96.9
92.5
89.4
87.0
86.6
85.3
86.7
89.1
76.2
92.4
87.8
99.3
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6130009
SFRA-50
13C-2,3,7,8-TCDD
82.5
(25%-164%)
Page 31 of 47
-------
( ape Fear \lltllytictll LLC Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 2 of 7
Surrogate Recovery Report
SDG Number: 6130
Matrix Type: SOLID
Sample ID Client ID
6130009 SFRA-50
6130011 SFRA-52
6130008 SFRA-49
6130006 SFRA-47
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
Recovery Acceptance
QUAL (%) Limits
86.3 (25%-181%)
79.6 (32%-141%)
86.8 (28%-130%)
94.9 (23%-140%)
98.6 (17%-15 7%)
89.0 (24%-169%)
89.8 (24%-185%)
88.2 (21%-178%)
81.4 (26%-152%)
84.7 (26%-123%)
86.1 (28%-13 6%)
75.7 (29%-147%)
90.0 (28%-143%)
86.2 (26%-13 8%)
105 (35%-197%)
86.2 (25%-164%)
89.3 (25%-181%)
79.8 (32%-141%)
86.1 (28%-130%)
96.6 (23%-140%)
97.5 (17%-15 7%)
91.2 (24%-169%)
91.0 (24%-185%)
89.8 (21%-178%)
79.7 (26%-152%)
83.8 (26%-123%)
84.6 (28%-13 6%)
77.4 (29%-147%)
91.0 (28%-143%)
89.3 (26%-13 8%)
106 (35%-197%)
80.3 (25%-164%)
87.0 (25%-181%)
75.1 (32%-141%)
83.9 (28%-130%)
86.8 (23%-140%)
90.0 (17%-15 7%)
85.8 (24%-169%)
84.9 (24%-185%)
85.2 (21%-178%)
74.5 (26%-152%)
78.0 (26%-123%)
79.6 (28%-13 6%)
70.3 (29%-147%)
84.2 (28%-143%)
81.9 (26%-13 8%)
101 (35%-197%)
82.8 D (25%-164%)
87.8 D (25%-181%)
Page 32 of 47
-------
( ape Fear \lltllytictll LLC Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 3 of 7
Surrogate Recovery Report
SDG Number: 6130
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6130006
SFRA-47
6130001
SFRA-42
12010462
SFRA-42(6130001MS)
12010463
SFRA-42(6130001MSD)
13C-l,2,3,4,7,8-HxCDD
78.6
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
86.0
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
88.9
D
(23%-140%)
13C-OCDD
89.4
D
(17%-15 7%)
13C-2,3,7,8-TCDF
89.2
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
89.5
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
88.8
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
79.3
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
83.7
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
85.0
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
71.8
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
85.9
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
84.1
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
104
D
(35%-197%)
13C-2,3,7,8-TCDD
77.1
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
78.1
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
88.3
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
97.6
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
86.8
D
(23%-140%)
13C-OCDD
81.7
D
(17%-15 7%)
13C-2,3,7,8-TCDF
85.8
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
78.5
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
80.3
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
89.9
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
97.7
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
93.7
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
73.5
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
92.5
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
78.5
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
106
D
(35%-197%)
13C-2,3,7,8-TCDD
83.6
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
85.8
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
80.1
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
97.0
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
88.1
D
(23%-140%)
13C-OCDD
82.0
D
(17%-15 7%)
13C-2,3,7,8-TCDF
91.5
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
87.0
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
90.7
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
83.9
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
90.2
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
90.6
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
76.9
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
91.8
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
79.7
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
103
D
(35%-197%)
13C-2,3,7,8-TCDD
80.5
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
84.5
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
80.5
D
(32%-141%)
Page 33 of 47
-------
( ape Fear \lltllytictll LLC Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 4 of 7
Surrogate Recovery Report
SDG Number: 6130
Matrix Type: SOLID
Recovery Acceptance
Sample ID Client ID Surrogate qual l imits
12010463 SFRA-42(6130001MSD)
13C-l,2,3,6,7,8-HxCDD
91.5
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
80.9
D
(23%-140%)
13C-OCDD
76.0
D
(17%-15 7%)
13C-2,3,7,8-TCDF
90.3
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
83.9
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
86.4
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
78.7
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
82.3
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
84.3
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
70.7
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
84.9
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
74.9
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
104
D
(35%-197%)
6130002 SFRA-43
13C-2,3,7,8-TCDD
82.7
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
84.4
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
79.3
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
92.1
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
83.3
D
(23%-140%)
13C-OCDD
72.6
D
(17%-15 7%)
13C-2,3,7,8-TCDF
91.0
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
86.1
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
88.7
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
81.4
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
85.1
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
86.4
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
66.4
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
86.5
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
72.8
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
124
D
(35%-197%)
6130003 SFRA-44
13C-2,3,7,8-TCDD
84.7
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
83.6
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
73.0
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
91.0
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
84.0
D
(23%-140%)
13C-OCDD
79.8
D
(17%-15 7%)
13C-2,3,7,8-TCDF
90.3
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
87.3
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
88.3
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
76.6
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
86.0
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
83.4
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
68.6
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
84.9
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
74.3
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
127
D
(35%-197%)
6130004 SFRA-45
13C-2,3,7,8-TCDD
77.8
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
81.0
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
75.5
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
94.0
D
(28%-130%)
Page 34 of 47
-------
( ape Fear \lltllytictll LLC Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 5 of 7
Surrogate Recovery Report
SDG Number: 6130
Matrix Type: SOLID
Sample ID Client ID
6130004 SFRA-45
6130005 SFRA-46
6130007 SFRA-48
6130010 SFRA-51
Surrogate
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
Recovery Acceptance
QUAL (%) Limits
87.6
D
(23%-140%)
74.7
D
(17%-15 7%)
85.6
D
(24%-169%)
84.1
D
(24%-185%)
85.0
D
(21%-178%)
76.8
D
(26%-152%)
88.3
D
(26%-123%)
85.5
D
(28%-13 6%)
69.3
D
(29%-147%)
85.0
D
(28%-143%)
74.1
D
(26%-13 8%)
116
D
(35%-197%)
79.4
D
(25%-164%)
77.3
D
(25%-181%)
74.1
D
(32%-141%)
84.8
D
(28%-130%)
84.3
D
(23%-140%)
72.8
D
(17%-15 7%)
87.0
D
(24%-169%)
78.4
D
(24%-185%)
81.7
D
(21%-178%)
75.5
D
(26%-152%)
83.7
D
(26%-123%)
81.6
D
(28%-13 6%)
66.4
D
(29%-147%)
86.7
D
(28%-143%)
72.5
D
(26%-13 8%)
129
D
(35%-197%)
84.7
D
(25%-164%)
83.5
D
(25%-181%)
80.3
D
(32%-141%)
94.9
D
(28%-130%)
86.6
D
(23%-140%)
79.6
D
(17%-15 7%)
87.8
D
(24%-169%)
89.9
D
(24%-185%)
87.2
D
(21%-178%)
81.9
D
(26%-152%)
90.1
D
(26%-123%)
89.9
D
(28%-13 6%)
72.9
D
(29%-147%)
90.9
D
(28%-143%)
78.5
D
(26%-13 8%)
104
D
(35%-197%)
78.3
D
(25%-164%)
79.5
D
(25%-181%)
71.5
D
(32%-141%)
92.1
D
(28%-130%)
80.8
D
(23%-140%)
Page 35 of 47
-------
( ape Fear \lltllytictll LLC Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 6 of 7
Surrogate Recovery Report
SDG Number: 6130
Matrix Type: SOLID
Sample ID Client ID
6130010 SFRA-51
6130012 SFRA-53
6130013 SFRA-54
6130014 SFRA-55
Surrogate
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
Recovery Acceptance
QUAL (%) Limits
77.8
D
(17%-15 7%)
86.7
D
(24%-169%)
81.7
D
(24%-185%)
82.7
D
(21%-178%)
75.1
D
(26%-152%)
84.7
D
(26%-123%)
84.1
D
(28%-13 6%)
65.3
D
(29%-147%)
82.1
D
(28%-143%)
73.7
D
(26%-13 8%)
99.5
D
(35%-197%)
68.6
D
(25%-164%)
70.8
D
(25%-181%)
65.2
D
(32%-141%)
81.1
D
(28%-130%)
71.4
D
(23%-140%)
61.1
D
(17%-15 7%)
76.4
D
(24%-169%)
72.2
D
(24%-185%)
72.0
D
(21%-178%)
68.6
D
(26%-152%)
77.8
D
(26%-123%)
73.9
D
(28%-13 6%)
57.1
D
(29%-147%)
71.8
D
(28%-143%)
66.3
D
(26%-13 8%)
139
D
(35%-197%)
83.0
D
(25%-164%)
83.9
D
(25%-181%)
79.9
D
(32%-141%)
99.1
D
(28%-130%)
88.7
D
(23%-140%)
87.7
D
(17%-15 7%)
89.2
D
(24%-169%)
85.8
D
(24%-185%)
89.9
D
(21%-178%)
86.7
D
(26%-152%)
94.9
D
(26%-123%)
90.7
D
(28%-13 6%)
73.9
D
(29%-147%)
91.6
D
(28%-143%)
84.6
D
(26%-13 8%)
132
D
(35%-197%)
78.2
D
(25%-164%)
83.4
D
(25%-181%)
71.7
D
(32%-141%)
92.1
D
(28%-130%)
83.8
D
(23%-140%)
77.0
D
(17%-15 7%)
Page 36 of 47
-------
Cape Fear Analytical LLC
Report Date: May 23, 2014
Hi-Res Dioxins/Furans
Surrogate Recovery Report
SDG Number: 6130
Matrix Type: SOLID
of 7
Sample ID Client ID
Recovery Acceptance
Surrogate
QUAL (%)
Limits
13C-2,3,7,8-TCDF
89.0
D
(24%-
169%
13C-l,2,3,7,8-PeCDF
83.5
D
(24%-
185%
13C-2,3,4,7,8-PeCDF
85.3
D
(21%-
178%
13C-l,2,3,4,7,8-HxCDF
74.3
D
(26%-
152%
13C-l,2,3,6,7,8-HxCDF
90.2
D
(26%-
123%
13C-2,3,4,6,7,8-HxCDF
85.0
D
(28%-
136%
13C-l,2,3,7,8,9-HxCDF
66.8
D
(29%-
147%
13C-l,2,3,4,6,7,8-HpCDF
79.0
D
(28%-
143%
13C-l,2,3,4,7,8,9-HpCDF
67.7
D
(26%-
138%
37Cl-2,3,7,8-TCDD
104
D
(35%-
197%
6130014
SFRA-55
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 37 of 47
-------
Cape Fear Analytical LLC
Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 05/21/2014 15:08 Dilution: 1
Prep Batch ID:25960
Batch ID: 25962
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
22.5
112
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
102
102
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
103
103
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
108
108
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
107
107
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
102
102
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
210
105
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.6
93.1
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
98.4
98.4
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
99.9
99.9
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
102
102
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
101
101
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
98.5
98.5
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
103
103
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
99.6
99.6
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
187
93.4
63-170
SDG Number: 6130
Client ID: LCS for batch 25960
Lab Sample ID: 12010460
Instrument: HRP750
Analyst: JTF
Page
38 of 47
-------
Cape Fear Analytical LLC
Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 05/21/2014 15:55 Dilution: 1
Prep Batch ID:25960
Batch ID: 25962
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.4
107
67-158
5.08
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
99.9
99.9
70-142
2.39
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
100
100
70-164
3.09
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
107
107
76-134
0.524
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
110
110
64-162
2.42
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
102
102
70-140
0.385
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
205
103
78-144
2.44
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.4
92
75-158
1.29
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
96.9
96.9
80-134
1.50
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
98.2
98.2
68-160
1.74
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
100
100
72-134
1.97
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
102
102
84-130
0.849
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
100
100
70-156
1.67
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
105
105
78-130
2.46
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
97.1
97.1
82-122
3.86
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
96.5
96.5
78-138
3.11
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
187
93.6
63-170
0.221
0-20
SDG Number: 6130
Client ID: LCSD for batch 25960
Lab Sample ID: 12010461
Instrument: HRP750
Analyst: JTF
Page
39 of 47
-------
Cape Fear Analytical LLC
Report Date: May 23, 2014
Page 1 of 2
Dilution: 10
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
200
7050
444 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1000
u
1070
107
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1000
u
1050
105
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1000
J
1050
101
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1000
u
1080
108
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1000
1730
96.7
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2000
13700
-10.1 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
200
J
237
102
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1000
u
949
94.9
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1000
u
910
91
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1000
J
954
93.2
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1000
u
976
97.6
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1000
J
971
95.7
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1000
u
979
97.8
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1000
J
1070
92.5
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1000
u
904
90.4
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2000
J
2100
93.7
70-130
SDG Number: 6130
Client ID: SFRA-42(6130001MS)
Lab Sample ID: 12010462
Instrument: HRP750
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 19.4
Analysis Date: 05/22/2014 13:00
Prep Batch ID:25960
Batch ID: 25962
Page 40 of 47
-------
Cape Fear Analytical LLC
Report Date: May 23, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 19.4
Analysis Date: 05/22/2014 13:48 Dilution: 10
Prep Batch ID:25960
Batch ID: 25962
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
198
5530
-320 *
70-130
24.2 *
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
992
U
1060
107
70-130
0.0925
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
992
U
1010
101
70-130
4.13
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
992
J
1040
100
70-130
1.32
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
992
u
1020
103
70-130
4.93
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
992
1810
105
70-130
4.19
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
1980
13200
-36.6 *
70-130
3.90
0-20
51207-31-9
MSD
2,3,7,8-TCDF
198
J
219
93.5
70-130
7.77
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
992
u
981
98.9
70-130
3.34
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
992
u
921
92.9
70-130
1.19
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
992
J
1000
99.1
70-130
5.20
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
992
u
1080
109
70-130
9.85
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
992
J
983
97.6
70-130
1.16
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
992
u
1010
102
70-130
3.04
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
992
J
1050
91.9
70-130
1.25
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
992
u
927
93.5
70-130
2.55
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
1980
J
2190
99.2
70-130
4.41
0-20
SDG Number: 6130
Client ID: SFRA-42(6130001MSD)
Lab Sample ID: 12010463
Instrument: HRP750
Analyst: JTF
Page 41 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23,2014
SDG Number: 6130
Client ID: MB for batch 25960
Lab Sample ID: 12010459
Column:
Method Blank Summary
Client: TETR001
Instrument ID: HRP750
Prep Date: 20-MAY-14
Page 1 of 1
Matrix: SOLID
Data File: A20MAY14B 5-3
Analyzed: 05/21/1416:42
Client Sample ID
This method blank applies to the following samples and quality control samples:
Lab Sample ID File ID Date Analyzed Time Analyzed
01 LCS for batch 25960
02 LCSD for batch 25960
03 SFRA-50
04 SFRA-52
05 SFRA-49
06 SFRA-47
07 SFRA-50
08 SFRA-52
09 SFRA-42
10 SFRA-42(6130001MS)
11 SFRA-42(6130001MSD)
12 SFRA-43
13 SFRA-44
14 SFRA-45
15 SFRA-46
16 SFRA-48
17 SFRA-51
18 SFRA-53
19 SFRA-54
20 SFRA-55
12010460
12010461
6130009
6130011
6130008
6130006
6130009
6130011
6130001
12010462
12010463
6130002
6130003
6130004
6130005
6130007
6130010
6130012
6130013
6130014
A20MAY14B5-1
A20MAY14B5-2
A20M AY 14B6-2
A20M AY 14B6-4
A20M AY 14B 6-9
A20MAY14B6-10
b22mayl4a-4
b22mayl4a-5
A20MAY14B7-2
A20MAY14B7-3
A20MAY14B7-4
A20MAY14B7-5
A20MAY14B7-6
A20MAY14B7-7
A20MAY14B7-8
A20MAY14B7-9
A20MAY14B7-10
A20MAY14B7-11
A20MAY14B7-12
A20MAY14B 7-13
05/21/14
05/21/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
05/22/14
1508
1555
0311
0446
0843
0933
1111
1130
1213
1300
1348
1436
1524
1619
1706
1754
1842
1930
2017
2105
Page 42 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6130
12010459
QC for batch 25960
MB for batch 25960
25962
05/21/2014 16:42
A20MAY14B 5-3
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
25960
Prep Method:
SW846 3540C
Prep Date:
20-MAY-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
J
0.130
Pg/g
0.0916
1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.314
Pg/g
0.145
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
U
.244
Pg/g
0.244
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.234
Pg/g
0.234
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.344
Pg/g
0.226
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.424
Pg/g
0.258
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
2.10
Pg/g
0.582
10.0
51207-31-9
2,3,7,8-TCDF
u
.106
Pg/g
0.106
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.232
Pg/g
0.088
5.00
57117-31-4
2,3,4,7,8-PeCDF
J
0.192
Pg/g
0.0856
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.212
Pg/g
0.212
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.198
Pg/g
0.198
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.184
Pg/g
0.129
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.406
Pg/g
0.406
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.258
Pg/g
0.158
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.278
Pg/g
0.278
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
0.490
Pg/g
0.380
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
166
200
Pg/g
82.8
(25 %-164%)
13C-1,2,3,7,8-PeCDD
178
200
Pg/g
89.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
176
200
Pg/g
87.9
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
180
200
Pg/g
90.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
194
200
Pg/g
96.9
(23%-140%)
13C-OCDD
370
400
Pg/g
92.5
(17%-157%)
13C-2,3,7,8-TCDF
179
200
Pg/g
89.4
(24%-169%)
13C-1,2,3,7,8-PeCDF
174
200
Pg/g
87.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
173
200
Pg/g
86.6
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
171
200
Pg/g
85.3
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
173
200
Pg/g
86.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
178
200
Pg/g
89.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
152
200
Pg/g
76.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
185
200
Pg/g
92.4
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
176
200
Pg/g
87.8
(26%-13 8%)
37Cl-2,3,7,8-TCDD
19.9
20.0
Pg/g
99.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 43 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 12010460
Client Sample: ^or batch 25960
Client ID: LCS for batch 25960
Batch ID: 25962
Run Date: 05/21/2014 15:08
Data File: A20MAY14B 5-1
Prep Batch: 25960
Prep Date: 20-MAY-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
22.5
Pg/g
0.192 1.00
40321-76-4
1,2,3,7,8-PeCDD
102
Pg/g
0.372 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
103
Pg/g
0.560 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
108
Pg/g
0.540 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
107
Pg/g
0.584 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
102
Pg/g
0.694 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
210
Pg/g
1.46 10.0
51207-31-9
2,3,7,8-TCDF
18.6
Pg/g
0.163 1.00
57117-41-6
1,2,3,7,8-PeCDF
98.4
Pg/g
0.432 5.00
57117-31-4
2,3,4,7,8-PeCDF
99.9
Pg/g
0.412 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
102
Pg/g
0.504 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
101
Pg/g
0.458 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
98.5
Pg/g
0.498 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
103
Pg/g
0.816 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
0.622 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.6
Pg/g
1.06 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
187
Pg/g
0.890 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
154
200
Pg/g
77.0
(20%-175%)
13C-1,2,3,7,8-
PeCDD
165
200
Pg/g
82.5
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
163
200
Pg/g
81.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
169
200
Pg/g
84.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
176
200
Pg/g
87.9
(22%-166%)
13C-OCDD
325
400
Pg/g
81.4
(13%-199%)
13C-2,3,7,8-TCDF
172
200
Pg/g
85.8
(22%-152%)
13C-1,2,3,7,8-
PeCDF
166
200
Pg/g
83.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
164
200
Pg/g
81.9
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
161
200
Pg/g
80.4
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
166
200
Pg/g
83.0
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
168
200
Pg/g
84.2
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
142
200
Pg/g
71.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
166
200
Pg/g
83.0
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
155
200
Pg/g
77.3
(20%-186%)
3701-2,3,7,8-TCDD
18.8
20.0
Pg/g
94.0
(31 %-191%)
Comments:
Page 44 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 12010461
Client Sample: ^or batch 25960
Client ID: LCSD for batch 25960
Batch ID: 25962
Run Date: 05/21/2014 15:55
Data File: A20MAY14B 5-2
Prep Batch: 25960
Prep Date: 20-MAY-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.4
Pg/g
0.107 1.00
40321-76-4
1,2,3,7,8-PeCDD
99.9
Pg/g
0.222 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
100
Pg/g
0.376 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
107
Pg/g
0.394 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
110
Pg/g
0.408 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
102
Pg/g
0.356 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
205
Pg/g
0.712 10.0
51207-31-9
2,3,7,8-TCDF
18.4
Pg/g
0.117 1.00
57117-41-6
1,2,3,7,8-PeCDF
96.9
Pg/g
0.226 5.00
57117-31-4
2,3,4,7,8-PeCDF
98.2
Pg/g
0.224 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
100
Pg/g
0.388 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
102
Pg/g
0.372 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
100
Pg/g
0.372 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
105
Pg/g
0.570 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
97.1
Pg/g
0.280 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
96.5
Pg/g
0.460 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
187
Pg/g
0.648 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
169
200
Pg/g
84.7
(20%-175%)
130-1,2,3,7,8-
PeCDD
185
200
Pg/g
92.6
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
170
200
Pg/g
85.1
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
175
200
Pg/g
87.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
191
200
Pg/g
95.6
(22%-166%)
13C-OCDD
374
400
Pg/g
93.5
(13%-199%)
13C-2,3,7,8-TCDF
185
200
Pg/g
92.7
(22%-152%)
130-1,2,3,7,8-
PeCDF
181
200
Pg/g
90.7
(21%-192%)
130-2,3,4,7,8-
PeCDF
182
200
Pg/g
90.8
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
167
200
Pg/g
83.4
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
167
200
Pg/g
83.3
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
170
200
Pg/g
85.1
(22%-176%)
130-1,2,3,7,8,9-HxCDF
151
200
Pg/g
75.6
(17%-205%)
130-1,2,3,4,6,7,8-HpCDF
179
200
Pg/g
89.5
(21%-15 8%)
130-1,2,3,4,7,8,9-HpCDF
178
200
Pg/g
88.8
(20%-186%)
3701-2,3,7,8-TCDD
19.6
20.0
Pg/g
97.8
(31 %-191%)
Comments:
Page 45 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 12010462
Client Sample: ^or batch 25960
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 09:20
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 19.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-42(6130001MS)
25962
05/22/2014 13:00
A20MAY14B7-3
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.24 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
7050
Pg/g
10.7 100
40321-76-4
1,2,3,7,8-PeCDD
1070
Pg/g
13.0 500
39227-28-6
1,2,3,4,7,8-HxCDD
1050
Pg/g
30.4 500
57653-85-7
1,2,3,6,7,8-HxCDD
1050
Pg/g
32.8 500
19408-74-3
1,2,3,7,8,9-HxCDD
1080
Pg/g
33.6 500
35822-46-9
1,2,3,4,6,7,8-HpCDD
1730
Pg/g
43.6 500
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13700
Pg/g
138 1000
51207-31-9
2,3,7,8-TCDF
237
Pg/g
12.5 100
57117-41-6
1,2,3,7,8-PeCDF
949
Pg/g
20.6 500
57117-31-4
2,3,4,7,8-PeCDF
910
Pg/g
19.7 500
70648-26-9
1,2,3,4,7,8-HxCDF
954
Pg/g
28.6 500
57II7.44.9
1,2,3,6,7,8-HxCDF
976
Pg/g
28.6 500
60851-34-5
2,3,4,6,7,8-HxCDF
971
Pg/g
29.8 500
72918-21-9
1,2,3,7,8,9-HxCDF
979
Pg/g
53.6 500
67562-39-4
1,2,3,4,6,7,8-HpCDF
1070
Pg/g
19.2 500
55673-89-7
1,2,3,4,7,8,9-HpCDF
904
Pg/g
35.8 500
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2100
Pg/g
74.2 1000
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1670
2000
Pg/g
83.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1720
2000
Pg/g
85.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1600
2000
Pg/g
80.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1940
2000
Pg/g
97.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1760
2000
Pg/g
88.1
(23%-140%)
13C-OCDD
3280
4000
Pg/g
82.0
(17%-157%)
13C-2,3,7,8-TCDF
1830
2000
Pg/g
91.5
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1740
2000
Pg/g
87.0
(24%-185%)
130-2,3,4,7,8-
PeCDF
1810
2000
Pg/g
90.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1680
2000
Pg/g
83.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1800
2000
Pg/g
90.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1810
2000
Pg/g
90.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1540
2000
Pg/g
76.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1840
2000
Pg/g
91.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1590
2000
Pg/g
79.7
(26%-13 8%)
3701-2,3,7,8-TCDD
205
200
Pg/g
103
(35%-197%)
Comments:
Page 46 of 47
-------
Cape Fear Analytical LLC
Report Date:
May 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6130
Lab Sample ID: 12010463
Client Sample: ^or batch 25960
Client:
Date Collected:
Date Received:
TETR001
05/16/2014 09:20
05/20/201411:10
Project: TETR00114
Matrix: SOLID
%Moisture: 19.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-42(6130001MSD)
25962
05/22/2014 13:48
A20MAY14B7-4
25960
20-MAY-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.25 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
5530
Pg/g
24.2 99.2
40321-76-4
1,2,3,7,8-PeCDD
1060
Pg/g
21.4 496
39227-28-6
1,2,3,4,7,8-HxCDD
1010
Pg/g
48.4 496
57653-85-7
1,2,3,6,7,8-HxCDD
1040
Pg/g
49.0 496
19408-74-3
1,2,3,7,8,9-HxCDD
1020
Pg/g
51.6 496
35822-46-9
1,2,3,4,6,7,8-HpCDD
1810
Pg/g
59.1 496
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13200
Pg/g
224 992
51207-31-9
2,3,7,8-TCDF
219
Pg/g
28.6 99.2
57117-41-6
1,2,3,7,8-PeCDF
981
Pg/g
25.6 496
57117-31-4
2,3,4,7,8-PeCDF
921
Pg/g
26.2 496
70648-26-9
1,2,3,4,7,8-HxCDF
1000
Pg/g
46.2 496
57II7.44.9
1,2,3,6,7,8-HxCDF
1080
Pg/g
50.4 496
60851-34-5
2,3,4,6,7,8-HxCDF
983
Pg/g
45.2 496
72918-21-9
1,2,3,7,8,9-HxCDF
1010
Pg/g
75.2 496
67562-39-4
1,2,3,4,6,7,8-HpCDF
1050
Pg/g
27.6 496
55673-89-7
1,2,3,4,7,8,9-HpCDF
927
Pg/g
48.4 496
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2190
Pg/g
159 992
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1600
1980
Pg/g
80.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1680
1980
Pg/g
84.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1600
1980
Pg/g
80.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1820
1980
Pg/g
91.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1610
1980
Pg/g
80.9
(23%-140%)
13C-OCDD
3020
3970
Pg/g
76.0
(17%-157%)
13C-2,3,7,8-TCDF
1790
1980
Pg/g
90.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1670
1980
Pg/g
83.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
1720
1980
Pg/g
86.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1560
1980
Pg/g
78.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1630
1980
Pg/g
82.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1670
1980
Pg/g
84.3
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1400
1980
Pg/g
70.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1690
1980
Pg/g
84.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1490
1980
Pg/g
74.9
(26%-13 8%)
3701-2,3,7,8-TCDD
205
198
Pg/g
104
(35%-197%)
Comments:
Page 47 of 47
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 02. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6160
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on May 23, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Enclosures
Page 1 of27
problem solved
-------
Page: /
Project #:
CFAQuote#: _
COC Number'":
PO Number;
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: (j? I (j? &
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Name: 7^^ , *£kC ' Phone £ TO
Sample Analysis Requestedt5) (Fill in the number of containers for each test)
Project/Site Name: ^ ( J,hk
|T©taI number of containers
r<
<-- Preservative Type (6)
Address. ^ 0 3 K /-(* ~ t_«a n/ sH?) fO
*
Comments
Note: extra sample is
required for sample
specific QC
Collected by. /( Semi Results
r»Vet n. c •»
Sample ID
* For composites - indicate start ami stop date/time
/
•Dale Collected
(mm-dd-yy)
*Time
Collected
(Military)
(hhram)
QCCode
m
Field
Filtered®
Sample
Matrix m
SST-
' JL*
//JiQ
ftfjT
s
(
X
S fAJ -SS
s-zt-M
rS
I
%
S-A(~ M
/ojts-
s
I
X
!?3l o
3
t
SFAA - ff o
/SJ-o
{
/
TAT Requested: Normal:
Rush; )£ Specify: ^^bji
iect to Surcharge)
Fax Results:
Yes
/
No
Circle Deliverabie: Cof A / QC Summary ! Level 1 / Level 2 /(''Level 3 / Level 4
Sample Collection TwBt-gOfie
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
Eastern Pacific
Central Other _
~ Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed) Dale Time
ived by (signed)
Dite
13
Time
m lot &
CFA PM: Cynfo /
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Ciiem: Te W jwork Crder: -fo ( (p Q
Shipping Company: ft/)c
Date/Time Received: |
Suspected Hazard Information
Yes
NA
No
DOE Site SamplePackages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
S
Samples identified as Foreign Soil?
Samples < 2x background?
I*-*"
* Notify RSO of any responses in this column immediately.
Air Sample Receipt Specifics
Yes
NA
No
Air sample in shipment?
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming items)
1
Shipping containers received intact
arid sealed?
Circle Applicable:
seals broken damaged container leaking container oiherfdescribe)
2
Chain of Custody documents included
with shipment?
3
Samples requiring cold preservation
within 0-6°C?
Preservation Method:
ice bags bjLe fee dry ice none other {describe)
3,3
4
Aqueous samples found to have visible
solids?
Sample !0s, containers affected:
5
Samples requiring chemical
preservation at proper pH?
Sample IDs, containers affected and pH observed:
Jf preservative added, lot#:
6
Samples requiring preservation have
no residual chlorine?
--
Sample IDs, containers affected:
If preservative added, lot#:
7
Samples received within holding time?
SampJe IDs, tests affected;
8
Sample IDs on COC match IDs on
containers?
-¦
Sample IDs, containers affected;
9
Date & time of COC match date & time
on containers?
X'
Sample IDs, containers affected:
10
Number of containers received match
number indicated on COC?
Sample IDs, containers affected:
11
COC form is properly signed in
relinquished/received sections?
Comments;
Checklist performed by: Initials:, Date: _
Page 3 of27
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 27
-------
Case Narrative
Page 5 of27
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6160
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 25980
Clean Up Batch Number: 25979
Extraction Batch Number: 26012
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6160001
SFRA-57
6160002
SFRA-58
6160003
SFRA-56
6160004
SFRA-59
6160005
SFRA-60
12010505
Method Blank (MB)
12010506
Laboratory Control Sample (LCS)
12010507
Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Page 6 of 27
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 25980.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
Samples 6160002 (SFRA-58), 6160003 (SFRA-56) and 6160005 (SFRA-60)- Batch 25980 were
diluted due to the presence of over-range target analytes.
Page 7 of27
-------
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 27
-------
Sample Data Summary
Page 9 of 27
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6160 CFA Work Order: 6160
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 02JUN2014 Title: Data Validator
Page 10 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
6160001
1613B Soil
SFRA-57
25980
05/28/2014 18:51
A27MAY14D3-6
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
J
u
u
J
u
u
J
u
J
u
TETR001
05/22/2014 11:20
05/23/2014 10:10
EPA Method 1613B
JTF
SW846 3540C
1.13 g
Result
344
1.96
3.86
25
9.11
705
13400
3.82
1.49
1.65
4.35
2.66
4.02
3.66
148
11.3
1040
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
1.79
1.96
3.35
25.0
9.11
7.48
13.0
2.20
1.49
1.65
2.63
2.66
2.66
3.66
2.32
3.35
7.21
TETR00114
SOIL
20.7
Dry Weight
HRP750
1
PQL
11.2
55.8
55.8
55.8
55.8
55.8
112
11.2
55.8
55.8
55.8
55.8
55.8
55.8
55.8
55.8
112
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1830
2230
Pg/g
81.8
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2000
2230
Pg/g
89.6
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1860
2230
Pg/g
83.1
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1740
2230
Pg/g
77.9
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2190
2230
Pg/g
98.0
(23%-140%)
13C-OCDD
4600
4470
Pg/g
103
(17%-157%)
13C-2,3,7,8-TCDF
1940
2230
Pg/g
87.0
(24%-169%)
13C-1,2,3,7,8-PeCDF
1880
2230
Pg/g
84.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
2000
2230
Pg/g
89.4
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1830
2230
Pg/g
82.2
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1780
2230
Pg/g
79.6
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1830
2230
Pg/g
82.2
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1740
2230
Pg/g
78.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1950
2230
Pg/g
87.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2030
2230
Pg/g
90.8
(26%-13 8%)
37Cl-2,3,7,8-TCDD
212
223
Pg/g
95.0
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
6160002
1613B Soil
SFRA-58
25980
05/30/2014 11:02
A30MAY14A-3
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
J
J
u
u
u
u
J
u
J
J
J
TETR001
05/22/2014 13:45
05/23/2014 10:10
EPA Method 1613B
JTF
SW846 3540C
1.18 g
Result
26000
11.8
16.2
102
32.7
901
10900
132
7.89
12.9
13.1
13.3
19.8
18.5
251
21.3
450
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
8.39
11.8
16.2
17.2
17.7
15.6
33.9
10.3
7.89
12.9
13.1
13.3
13.1
18.5
6.27
9.68
30.8
TETR00114
SOIL
22.5
Dry Weight
HRP750
10
PQL
109
547
547
547
547
547
1090
109
547
547
547
547
547
547
547
547
1090
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1870
2190
Pg/g
85.6
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1930
2190
Pg/g
88.3
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1890
2190
Pg/g
86.3
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1710
2190
Pg/g
78.3
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2010
2190
Pg/g
92.0
(23%-140%)
13C-OCDD
3930
4370
Pg/g
89.9
(17%-157%)
13C-2,3,7,8-TCDF
1980
2190
Pg/g
90.8
(24%-169%)
13C-1,2,3,7,8-PeCDF
1910
2190
Pg/g
87.2
(24%-185%)
13C-2,3,4,7,8-PeCDF
1920
2190
Pg/g
88.0
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1810
2190
Pg/g
83.0
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1650
2190
Pg/g
75.6
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1770
2190
Pg/g
81.1
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1720
2190
Pg/g
78.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1860
2190
Pg/g
85.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1880
2190
Pg/g
86.1
(26%-13 8%)
37Cl-2,3,7,8-TCDD
310
219
Pg/g
142
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 27
-------
Cape Fear Analytical LLC
Report Date: June 2, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6160
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6160002
Date Collected:
05/22/2014 13:45
Matrix:
SOIL
Client Sample:
1613B Soil
Date Received:
05/23/2014 10:10
%Moisture:
22.5
Client ID:
SFRA-58
Prep Basis:
Dry Weight
Batch ID:
25980
Method:
EPA Method 1613B
Run Date:
05/29/2014 10:40
Analyst:
JTF
Instrument:
HRP763
Data File:
b29mayl4b-4
Dilution:
10
Prep Batch:
26012
Prep Method:
SW846 3540C
Prep Date:
27-MAY-14
Prep Aliquot:
1.18 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
131
Pg/g
15.3
109
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
6160003
1613B Soil
SFRA-56
25980
05/30/2014 11:50
A30MA Y14 A-4
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
J
U
J
J
J
u
u
J
u
J
u
TETR001
05/21/2014 10:55
05/23/2014 10:10
EPA Method 1613B
JTF
SW846 3540C
1.16 g
Result
15600
21.4
25.8
256
81.2
4360
38000
88.6
11.1
23.6
39.2
30.6
40.3
36.7
937
95.0
3970
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
16.3
18.8
25.8
34.1
31.4
45.9
55.8
18.6
11.1
23.6
24.9
30.6
26.1
36.7
19.6
32.1
37.6
TETR00114
SOIL
25.2
Dry Weight
HRP750
10
PQL
115
577
577
577
577
577
1150
115
577
577
577
577
577
577
577
577
1150
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1990
2310
Pg/g
86.5
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1980
2310
Pg/g
86.1
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
2030
2310
Pg/g
88.2
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1500
2310
Pg/g
64.9
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2170
2310
Pg/g
94.3
(23%-140%)
13C-OCDD
4380
4610
Pg/g
95.0
(17%-157%)
13C-2,3,7,8-TCDF
2110
2310
Pg/g
91.5
(24%-169%)
13C-1,2,3,7,8-PeCDF
2000
2310
Pg/g
86.6
(24%-185%)
13C-2,3,4,7,8-PeCDF
1990
2310
Pg/g
86.2
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
2050
2310
Pg/g
88.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1820
2310
Pg/g
79.1
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1970
2310
Pg/g
85.6
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1800
2310
Pg/g
77.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2040
2310
Pg/g
88.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2090
2310
Pg/g
90.6
(26%-13 8%)
37Cl-2,3,7,8-TCDD
291
231
Pg/g
126
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
6160004
1613B Soil
SFRA-59
25980
05/30/2014 12:39
A30MA Y14 A-5
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
J
J
JQ
J
J
J
U
U
u
u
TETR001
05/22/2014 14:20
05/23/2014 10:10
EPA Method 1613B
JTF
SW846 3540C
1.06 g
Result
3890
1.54
3.05
28.6
12.2
392
9570
21.1
1.25
3.14
3.53
3
4.51
1.55
81.9
4.97
201
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
0.996
1.30
1.36
2.14
1.79
4.01
4.61
1.18
0.753
0.777
3.53
3.00
4.51
1.55
0.746
1.06
1.41
TETR00114
SOIL
21.4
Dry Weight
HRP750
1
PQL
12.0
60.0
60.0
60.0
60.0
60.0
120
12.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
60.0
120
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1960
2400
Pg/g
81.7
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1900
2400
Pg/g
79.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1950
2400
Pg/g
81.3
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
Q 1280
2400
Pg/g
53.1
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2280
2400
Pg/g
95.1
(23%-140%)
13C-OCDD
5040
4800
Pg/g
105
(17%-157%)
13C-2,3,7,8-TCDF
1970
2400
Pg/g
82.0
(24%-169%)
13C-1,2,3,7,8-PeCDF
1870
2400
Pg/g
77.8
(24%-185%)
13C-2,3,4,7,8-PeCDF
1870
2400
Pg/g
77.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1890
2400
Pg/g
78.9
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1750
2400
Pg/g
73.1
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1860
2400
Pg/g
77.5
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1840
2400
Pg/g
76.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2000
2400
Pg/g
83.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2190
2400
Pg/g
91.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
223
240
Pg/g
92.9
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 27
-------
Cape Fear Analytical LLC
Report Date: June 2, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6160
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6160004
Date Collected:
05/22/2014 14:20
Matrix:
SOIL
Client Sample:
1613B Soil
Date Received:
05/23/2014 10:10
%Moisture:
21.4
Client ID:
SFRA-59
Prep Basis:
Dry Weight
Batch ID:
25980
Method:
EPA Method 1613B
Run Date:
05/29/2014 11:19
Analyst:
JTF
Instrument:
HRP763
Data File:
b29mayl4b-6
Dilution:
1
Prep Batch:
26012
Prep Method:
SW846 3540C
Prep Date:
27-MAY-14
Prep Aliquot:
1.06 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
21.1
Pg/g
2.45
12.0
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
6160005
1613B Soil
SFRA-60
25980
05/30/2014 13:27
A30MA Y14 A-6
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
J
U
J
u
J
u
J
u
u
u
u
J
J
J
TETR001
05/22/2014 15:50
05/23/2014 10:10
EPA Method 1613B
JTF
SW846 3540C
1.13 g
Result
5520
6.16
13
47.1
13.6
600
12900
29.4
4.62
6.34
5.41
5.61
5.94
8.56
123
12.0
386
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
7.68
5.61
13.0
12.6
13.6
11.7
25.5
9.33
4.62
4.97
5.41
5.61
5.94
8.56
5.48
8.23
12.3
TETR00114
SOIL
19.6
Dry Weight
HRP750
5
PQL
55.0
275
275
275
275
275
550
55.0
275
275
275
275
275
275
275
275
550
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1470
2200
Pg/g
66.9
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1550
2200
Pg/g
70.5
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1440
2200
Pg/g
65.6
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1290
2200
Pg/g
58.7
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
1560
2200
Pg/g
71.0
(23%-140%)
13C-OCDD
3070
4400
Pg/g
69.7
(17%-157%)
13C-2,3,7,8-TCDF
1460
2200
Pg/g
66.1
(24%-169%)
13C-1,2,3,7,8-PeCDF
1510
2200
Pg/g
68.7
(24%-185%)
13C-2,3,4,7,8-PeCDF
1550
2200
Pg/g
70.3
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1430
2200
Pg/g
65.1
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1290
2200
Pg/g
58.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1370
2200
Pg/g
62.3
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1280
2200
Pg/g
58.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1430
2200
Pg/g
65.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1510
2200
Pg/g
68.4
(26%-13 8%)
37Cl-2,3,7,8-TCDD
225
220
Pg/g
102
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 27
-------
Quality Control
Summary
Page 18 of 27
-------
Cape Fear Analytical LLC Report Date: June 2, 2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6160
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010506
LCS for batch 26012
12010507
LCSD for batch 26012
12010505
MB for batch 26012
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
79.1
88.5
85.9
73.5
95.3
95.9
87.0
86.4
87.5
82.3
79.0
82.6
75.5
88.6
87.3
89.3
82.2
100
85.5
82.4
95.3
96.4
92.8
85.1
98.7
86.7
80.9
84.5
80.6
89.9
92.0
93.6
76.0
89.0
82.1
78.1
88.0
83.4
86.9
89.7
91.8
82.5
76.9
80.2
72.9
83.0
83.0
84.7
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6160001
SFRA-57
13C-2,3,7,8-TCDD
81.8
(25%-164%)
Page 19 of 27
-------
Cape Fear Analytical LLC Report Date: June 2, 2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6160
Matrix Type: SOLID
Sample ID Client ID
6160001 SFRA-57
6160002 SFRA-58
6160003 SFRA-56
6160004 SFRA-59
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
Recovery Acceptance
QUAL (%) Limits
89.6
(25%-181%)
83.1
(32%-141%)
77.9
(28%-130%)
98.0
(23%-140%)
103
(17%-15 7%)
87.0
(24%-169%)
84.0
(24%-185%)
89.4
(21%-178%)
82.2
(26%-152%)
79.6
(26%-123%)
82.2
(28%-13 6%)
78.1
(29%-147%)
87.2
(28%-143%)
90.8
(26%-13 8%)
95.0
(35%-197%)
85.6
D
(25%-164%)
88.3
D
(25%-181%)
86.3
D
(32%-141%)
78.3
D
(28%-130%)
92.0
D
(23%-140%)
89.9
D
(17%-15 7%)
90.8
D
(24%-169%)
87.2
D
(24%-185%)
88.0
D
(21%-178%)
83.0
D
(26%-152%)
75.6
D
(26%-123%)
81.1
D
(28%-13 6%)
78.8
D
(29%-147%)
85.3
D
(28%-143%)
86.1
D
(26%-13 8%)
142
D
(35%-197%)
86.5
D
(25%-164%)
86.1
D
(25%-181%)
88.2
D
(32%-141%)
64.9
D
(28%-130%)
94.3
D
(23%-140%)
95.0
D
(17%-15 7%)
91.5
D
(24%-169%)
86.6
D
(24%-185%)
86.2
D
(21%-178%)
88.8
D
(26%-152%)
79.1
D
(26%-123%)
85.6
D
(28%-13 6%)
77.9
D
(29%-147%)
88.3
D
(28%-143%)
90.6
D
(26%-13 8%)
126
D
(35%-197%)
81.7
(25%-164%)
79.0
(25%-181%)
Page 20 of 27
-------
Cape Fear Analytical LLC Report Date: June 2, 2014
Hi-Res Dioxins/Furans Page 3 of 3
Surrogate Recovery Report
SDG Number: 6160
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6160004
SFRA-59
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
81.3
53.1
95.1
105
82.0
77.8
77.8
78.9
73.1
77.5
76.7
83.5
91.3
92.9
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21%-178%)
(26%-152%)
(26%-123%)
(28%-13 6%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
6160005
SFRA-60
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
66.9
70.5
65.6
58.7
71.0
69.7
66.1
68.7
70.3
65.1
58.5
62.3
58.4
65.1
68.4
102
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%)
181%)
141%)
130%)
140%)
157%)
169%)
185%)
178%)
152%)
123%)
136%)
147%)
143%)
138%)
197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 21 of 27
-------
Cape Fear Analytical LLC
Report Date: June 2, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOIL
Analysis Date: 05/28/2014 16:27 Dilution: 1
Prep Batch ID:26012
Batch ID: 25980
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.4
102
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
98.4
98.4
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
94.5
94.5
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
104
104
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
105
105
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
96.4
96.4
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
194
97
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.4
92
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
97.2
97.2
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
96.0
96
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
95.7
95.7
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
93.5
93.5
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
97.2
97.2
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
103
103
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
92.7
92.7
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
96.1
96.1
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
187
93.5
63-170
SDG Number: 6160
Client ID: LCS for batch 26012
Lab Sample ID: 12010506
Instrument: HRP750
Analyst: JTF
Page
22 of 27
-------
Cape Fear Analytical LLC
Report Date: June 2, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOIL
Analysis Date: 05/28/2014 17:15 Dilution: 1
Prep Batch ID:26012
Batch ID: 25980
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.1
106
67-158
3.56
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
97.5
97.5
70-142
0.931
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
96.6
96.6
70-164
2.18
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
101
101
76-134
2.58
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
103
103
64-162
2.25
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
100
100
70-140
3.67
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
197
98.6
78-144
1.58
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.4
92.1
75-158
0.120
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
97.9
97.9
80-134
0.781
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
97.8
97.8
68-160
1.80
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
95.1
95.1
72-134
0.661
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
98.0
98
84-130
4.71
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
98.2
98.2
70-156
1.02
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
101
101
78-130
1.78
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
95.0
95
82-122
2.44
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
95.6
95.6
78-138
0.474
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
188
94
63-170
0.608
0-20
SDG Number: 6160
Client ID: LCSD for batch 26012
Lab Sample ID: 12010507
Instrument: HRP750
Analyst: JTF
Page 23 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
Method Blank Summary Page ' °' '
SDG Number:
6160
Client:
TETR001
Matrix:
SOIL
Client ID:
MB for batch 26012
Instrument ID:
HRP750
Data File:
A27MAY14D 3-5
Lab Sample ID:
Column:
12010505
Prep Date:
27-MAY-14
Analyzed:
05/28/14 18:03
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 26012
12010506
A27MAY14D3-3
05/28/14
1627
02 LCSD for batch 26012
12010507
A27MAY14D3-4
05/28/14
1715
03 SFRA-57
6160001
A27MAY14D3-6
05/28/14
1851
04 SFRA-58
6160002
b29mayl4b-4
05/29/14
1040
05 SFRA-59
6160004
b29mayl4b-6
05/29/14
1119
06 SFRA-58
6160002
A30MAY14A-3
05/30/14
1102
07 SFRA-56
6160003
A30MAY14A-4
05/30/14
1150
08 SFRA-59
6160004
A30MAY14A-5
05/30/14
1239
09 SFRA-60
6160005
A30MAY14A-6
05/30/14
1327
Page 24 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
12010505
QC for batch 26012
MB for batch 26012
25980
05/28/2014 18:03
A27MAY14D3-5
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
u
J
u
J
J
u
J
J
J
J
J
J
J
J
J
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Result
Tl5
.222
.242
0.204
.204
0.480
5.27
.0996
0.158
0.172
0.156
0.206
0.208
0.332
0.308
0.180
1.02
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
EDL
0.115
0.222
0.242
0.195
0.204
0.224
0.796
0.0996
0.0916
0.0894
0.098
0.102
0.102
0.149
0.0804
0.127
0.460
TETR00114
SOIL
As Received
HRP750
1
PQL
1.00
5.00
5.00
5.00
5.00
5.00
10.0
1.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
152
200
Pg/g
76.0
(25 %-164%)
13C-1,2,3,7,8-PeCDD
178
200
Pg/g
89.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
164
200
Pg/g
82.1
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
156
200
Pg/g
78.1
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
176
200
Pg/g
88.0
(23%-140%)
13C-OCDD
333
400
Pg/g
83.4
(17%-157%)
13C-2,3,7,8-TCDF
174
200
Pg/g
86.9
(24%-169%)
13C-1,2,3,7,8-PeCDF
179
200
Pg/g
89.7
(24%-185%)
13C-2,3,4,7,8-PeCDF
184
200
Pg/g
91.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
165
200
Pg/g
82.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
154
200
Pg/g
76.9
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
160
200
Pg/g
80.2
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
146
200
Pg/g
72.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
166
200
Pg/g
83.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
166
200
Pg/g
83.0
(26%-13 8%)
37Cl-2,3,7,8-TCDD
16.9
20.0
Pg/g
84.7
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 25 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
12010506
QC for batch 26012
LCS for batch 26012
25980
05/28/2014 16:27
A27MAY14D3-3
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Result
204
98.4
94.5
104
105
96.4
194
18.4
97.2
96.0
95.7
93.5
97.2
103
92.7
96.1
187
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
EDL
0.140
0.189
0.414
0.426
0.448
0.512
1.05
0.170
0.228
0.234
0.348
0.362
0.350
0.512
0.350
0.578
0.574
TETR00114
SOIL
As Received
HRP750
1
PQL
1.00
5.00
5.00
5.00
5.00
5.00
10.0
1.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
158
200
Pg/g
79.1
(20%-175%)
13C-1,2,3,7,8-PeCDD
177
200
Pg/g
88.5
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
172
200
Pg/g
85.9
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
147
200
Pg/g
73.5
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
191
200
Pg/g
95.3
(22%-166%)
13C-OCDD
384
400
Pg/g
95.9
(13%-199%)
13C-2,3,7,8-TCDF
174
200
Pg/g
87.0
(22%-152%)
13C-1,2,3,7,8-PeCDF
173
200
Pg/g
86.4
(21%-192%)
13C-2,3,4,7,8-PeCDF
175
200
Pg/g
87.5
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
165
200
Pg/g
82.3
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
158
200
Pg/g
79.0
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
165
200
Pg/g
82.6
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
151
200
Pg/g
75.5
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
177
200
Pg/g
88.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
175
200
Pg/g
87.3
(20%-186%)
37Cl-2,3,7,8-TCDD
17.9
20.0
Pg/g
89.3
(31 %-191%)
Comments:
Page 26 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 2, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6160
12010507
QC for batch 26012
LCSD for batch 26012
25980
05/28/2014 17:15
A27MAY14D3-4
26012
27-MAY-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Result
2LI
97.5
96.6
101
103
100
197
18.4
97.9
97.8
95.1
98.0
98.2
101
95.0
95.6
188
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
EDL
0.140
0.194
0.268
0.282
0.292
0.482
0.722
0.113
0.232
0.189
0.384
0.396
0.400
0.548
0.362
0.538
0.614
TETR00114
SOIL
As Received
HRP750
1
PQL
1.00
5.00
5.00
5.00
5.00
5.00
10.0
1.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
164
200
Pg/g
82.2
(20%-175%)
13C-1,2,3,7,8-PeCDD
200
200
Pg/g
100
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
171
200
Pg/g
85.5
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
165
200
Pg/g
82.4
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
191
200
Pg/g
95.3
(22%-166%)
13C-OCDD
386
400
Pg/g
96.4
(13%-199%)
13C-2,3,7,8-TCDF
186
200
Pg/g
92.8
(22%-152%)
13C-1,2,3,7,8-PeCDF
170
200
Pg/g
85.1
(21%-192%)
13C-2,3,4,7,8-PeCDF
197
200
Pg/g
98.7
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
173
200
Pg/g
86.7
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
162
200
Pg/g
80.9
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
169
200
Pg/g
84.5
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.6
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
180
200
Pg/g
89.9
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
184
200
Pg/g
92.0
(20%-186%)
37Cl-2,3,7,8-TCDD
18.7
20.0
Pg/g
93.6
(31 %-191%)
Comments:
Page 27 of 27
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number: 6176
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6176001
Date Collected:
05/28/2014 14:20
Matrix:
SOLID
Client Sample: 1613 Soil
Date Received:
05/30/2014 10:40
%Moisture:
22.5
Client ID:
SFRA-61
Prep Basis:
Dry Weight
Batch ID:
26065
Method:
EPA Method 1613B
Run Date:
06/03/2014 13:16
Analyst:
JTF
Instrument:
IIRP750
Data File:
A02.JI N14B 3 4
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.04 g
CAS No.
Parnmame
Qual
Result
Units
EDI.
PQL
1746-* >1-6
2,3,7,8-TCDD
2400
pg e
1.67
12.4
40321-70-4
1,2,3,7,8-PeODD
i J
2.22
pg/g
62.0
39227-28-6
1,2,3,4,7,8-HxCDD
J
2.95
pg/g
1.96
62.0
57653-85-7
1,2,3,6,7,8-HxODD
J
25.7
pg/g
2.06
62.0
19408-74-3
1,2,3,7,8,9-IIxCDD
J
8.90
pg'g
2.14
62.0
35822-46-9
1,2,3,4,6,7,8-IIpODD
387
pg'g
4.69
62.0
3268-87-9
1,2,3,4,6,7,8.9-001)])
12200
pg«
14.4
124
51207-31-9
2,3,7,8-TODF
j
12.1
1.85
12.4
57117-41-6
1,2,3,7,8-PeODF
U
.881
Pg/e
0.881
62.0
57117-31-4
2,3,4,7,8-PeODF
u
1.98
Pg'g
1.98
62.0
70648-26-9
57117-44-9
1,2,3,4,7,8-IIxCDF
1,2,3,6,7,8-"
u
u
2.3
2.4
Pg;'g
Pg-'g
2.73
62.0
62.0
60851-34-5
2,3,4,6,7,8-
u
3.1
Pg/g
3.10
62.0
72918-21-9
1,2,3,7,8,9-
u
3.72
Pg-'g
3.72
62.0
67562-39-4
l,"\3,4,6,7.8-IIpODF
88.3
Pg;'g
1.53
62.0
55673-89-7
1,2,3,4,7,8,9-IIpCDF
u
4.22
177
Pg'g
4.22
62.0
39001-02-0
1,2,3,4,6,7.8.9-OODF
Pg/g
3.89
124
Surrogate/'!racer recovery
Recoverv% Acceptable Limits
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PeODD
] 30-] ,2,3,4,7.8-HxODD
130-1,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpCDI)
130-001)1)
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpCDF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
81.9
88.1
82.6
76.5
92.0
90.9
86.0
85.2
86.6
80.5
75.6
79.5
70.5
80.1
77.5
102
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
Surrogate/I racer recovery
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PeODD
] 3C-] ,2,3,4,7.8-HxODD
13C-l,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
130-OODD
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpODF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analytewas analyzed for,
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number: 6176
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6176002
Date Collected:
05/28/2014 16:45
Matrix:
SOLID
Client Sample: 1613 Soil
Date Received:
05/30/2014 10:40
%Moisture:
21.3
Client ID:
SFRA-62
Prep Basis:
Dry Weight
Batch ID:
26065
Method:
EPA Method 1613B
Run Date:
06/03/2014 15:41
Analyst:
JTF
Instrument:
IIRP750
Data File:
A02.JI N14B 3 7
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.08 g
CAS No.
Parnmame
Qual
Result
Units
EDI.
PQL
1746-* >1-6
2,3,7,8-TCDD
1460
Pg g
1.62
11.8
40321-76-4
1,2,3,7,8-PeODD
j
4.33
Pg/g
1.90
58.8
39227-28-6
1,2,3,4,7,8-HxCDD
J
4.85
Pg/g
3.27
58.8
57653-85-7
1,2,3,6,7,8-HxODD
U
24.7
Pg/g
24.7
58.8
19408-74-3
1,2,3,7,8,9-IIxCDD
J
12.0
Pg'g
3.70
58.8
35822-46-9
1,2,3,4,6,7,8-IIpODD
304
pg;'g
4.52
58.8
3268-87-9
1,2,3,4,6,7,8.9-001)])
9040
pg«
13.2
118
51207-31-9
2,3,7,8-TODF
J
7.84
2 21
11.8
57117-41-6
1,2,3,7,8-PeODF
j
2.87
Pg/e
2.14
58.8
57117-31-4
2,3,4,7,8-PeODF
J
4.73
Pg'g
2.07
58.8
70648-26-9
57117-44-9
1,2,3,4,7,8-IIxCDF
1,2,3,6,7,8-"
u
j
"
4.61
Pg;'g
Pg/g
5.30
2.68
58.8
58.8
60851-34-5
2,3,4,6,7,8-
j
5.25
Pg/g
2.80
58.8
72918-21-9
1,2,3,7,8,9-
u
4.31
Pg/g
4.31
58.8
67562-39-4
l,"\3,4,6,7.8-IIpODF
61.8
Pg;'g
1.67
58.8
55673-89-7
1,2,3,4,7,8,9-IIpCDF
I..J
?J1
143
Pg'g
7.81
58.8
39001-02-0
1,2,3,4,6,7.8.9-OODF
Pg/g
4.33
118
Recovery% Acceptable Limits
81.3
86.3
79.7
64.3
95.2
95.8
84.8
80.4
84.6
78.3
77.4
80.5
70.4
81.6
77.9
100
(25%-164%)
(25%-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
174o-')l-o 2,3,7
40321-76-4 1,2,3:
39227-28-6 1,2,3.
57653-85-7 1,2,3:
19408-74-3 1,2,3,
35822-46-9 1,2,3:
3268-87-9 1,2,3.
51207-31-9 2,3,7.
57117-41-6 1,2,3.
57117-31-4 2,3,4.
70648-26-9 1,2,3r
57117-44-9 1,2,3.
60851-34-5 2,3,4.
72918-21-9 1,2,3.
67562-39-4 l,2,3r
55673-89-7 1,2,3:
39001-02-0 1,2,3.
6176
6176003
1613 Soil
SFRA-63
26065
06/03/2014 16:29
A02.JI N14B 3 8
26063
30-MAY-14
Parainame
,8-TCDD
,7,8-PeODD
,4,7,8-HxCDD
,6,7,8-HxOl )D
,7,8,9-IIxODD
,4,6,7,8-IIpODD
,4,6,7,8,9-OODl)
,8-TCDF
,7,8-PeODF
,7,8-PeODF
,4,7,8-IIxODF
,6,7,8-
,6,7,8-
,7,8,9-
,4,6,7,8-IIpODF
,4,7,8,9-IIpCDF
,4,6,7.8.9-OODF
Surrogate/'! racer recovery
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Client: TETR001
Date Collected: 05/29/2014 10:10
Date Received: 05/30/2014 10:40
Page 1 of 1
Method:
Analyst:
EPA Method 1613B
JT1
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
16.4
Dry Weight
IIRP750
1
Prep Method: SW846 3540C
Prep Aliquot: 1.32 g
Qual Result
1 30-2,3,7,8-TODl)
1 30-1,2,3,7,8-PeODD
1 3C-1,2,3,4,7,8-HxODD
1 3C-l,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
130-OODD
1 3C-2,3,7,8-TCDF
1 30-l,2,3,7,8-.Pe0DF
130-2,3,4,7,8-PeODF
1 30-1,2,3,4,7,8-HxOl )F
1 30-1,2,3,6,7,8-HxODF"
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8,9-IIxCDF
130-1,2,3,4,6,7,8-IIpODF
130-1,2,3,4,7,8,9-FIpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Units
EDL
PQL
pge
0 910
(M<7
pg/g
1.12
45.3
pg-;g
1.25
45.3
pg/g
1.33
45.3
pg'g
1 37
45.3
pg;'g
3.06
45.3
Pg/g
14.3
90.7
*
0.887
9.07
Pg/e
0.562
45.3
Pg'g
0.522
45.3
Pg'g
0.649
45.3
Pg-'g
0.645
45.3
Pg/g
0.667
45.3
Pg-'g
1.01
45.3
Pg;'g
0.624
45.3
Pg'g
1.00
45.3
Pg/g
2 92
90.7
Units Recovery% Acceptable Limits
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
SDG Number: 6176
Lab Sample ID: 6176004
Client Sample: 1613 Soil
Client ID:
SFRA-64
Batch ID:
26065
Run Date:
06/03/2014 17:17
Data File:
A02.JI N14B 3 9
Prep Batch:
26063
Prep Date:
30 MAY 14
CAS No.
Parmn
1746-* >1-6
2,3,7,8-TCDD
40321-76-4
1,2,3,7,8-PeODD
39227-28-6
1,2,3,4,7,8-HxCDD
57653-85-7
1,2,3,6,7,8-HxODD
19408-74-3
1,2,3,7,8,9-IIxCDD
35822-46-9
1,2,3,4,6,7,8-IIpODD
3268-87-9
1,2,3,4,6,7,8.9-001)])
51207-31-9
2,3,7,8-TODF
57117-41-6
1,2,3,7,8-PeODF
57117-31-4
2,3,4,7,8-PeODF
70648-26-9
1,2,3,4,7,8-IIxCDF
57117-44-9
1,2,3,6,7,8-"
60851-34-5
2,3,4,6,7,8-
72918-21-9
1,2,3,7,8,9-
67562-39-4
l,"\3,4,6,7.8-IIpODF
55673-89-7
1,2,3,4,7,8,9-IIpCDF
39001-02-0
1,2,3,4,6,7.8.9-OODF
Surrogate/I racer recovery
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PeODD
] 3C-] ,2,3,4,7.8-HxODD
13C-l,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
130-OODD
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpODF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analytewas analyzed for,
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Client: TETR001
Date Collected: 05/29/2014 10:50
Date Received: 05/30/2014 10:40
Page 1 of 1
Method:
Analyst:
EPA Method 1613B
JT1
Prep Method: SW846 3540C
Prep Aliquot:
Qual
Project:
TETR00114
Matrix:
SOLID
%Moisture:
17.3
Prep Basis:
Dry Weight
Instrument:
I1RP750
Dilution:
1
Units
EDI.
PQL
Pg g
1.07
10.3
Pg/g
1.55
51.3
Pg-;g
1.75
51.3
Pg/g
1.85
51.3
Pg'g
1.86
51.3
pg;'g
3.36
51.3
PB«
19.5
103
1.06
10.3
Pg/e
0.818
51.3
Pg'g
n.759
51.3
Pg''g
1.11
51.3
Pg-'g
0.919
51.3
Pg/g
0.966
51.3
Pg-'g
1.45
51.3
Pg;'g
0.779
51.3
Pg'g
1.24
51.3
pg/g
5.39
103
:ecovery% Acceptable Limits
84.5
94.7
80.5
84.0
91.7
88.9
89.6
96.2
94.9
79.6
80.0
80.8
71.5
82.0
76.4
97.7
(25%-164%)
(25%-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
hut not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
Surrogate/I racer recovery
1 30-2,3,7,8-TCDl)
130-1,2,3,7,8-PeODD
] 3C-] ,2,3,4,7.8-HxODD
13C-l,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
130-0001)
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeOOF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpCDF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analytewas analyzed for,
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number: 6176
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6176005
Date Collected:
05/29/201411:07
Matrix:
SOLID
Client Sample: 1613 Soil
Date Received:
05/30/2014 10:40
%Moisture:
23
Client ID:
SFRA-65
Prep Basis:
Dry Weight
Batch ID:
26065
Method:
EPA Method 1613B
Run Date:
06/03/2014 18:05
Analyst:
JTF
Instrument:
HRP750
Data File:
A02JI N14B 3 10
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.46 g
CAS No.
Parnmame
Qual
Result
Units
EDI.
PQL
1746-* >1-6
2,3,7,8-TCDD
32.6
pg e
1.11
8 90
40321-76-4
1,2,3,7,8-PeODD
U
1.74
pg/g
1.74
44.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.38
pg/g
2.38
44.5
57653-85-7
1,2,3,6,7,8-HxODD
u
4.38
pg/g
4.38
44.5
19408-74-3
1,2,3,7,8,9-IIxCDD
u
2.49
pg'g
2.49
44.5
35822-46-9
1,2,3,4,6,7,8-IIpODD
186
pg;'g
6.24
44.5
3268-87-9
1,2,3,4,6,7,8.9-001)])
32700
pg«
15.7
89.0
51207-31-9
2,3,7,8-TODF
TJ
1.05
1.05
8.90
57117-41-6
1,2,3,7,8-PeODF
u
.722
Pg/e
0.722
44.5
57117-31-4
2,3,4,7,8-PeODF
u
.724
Pg'g
0.724
44.5
70648-26-9
57117-44-9
1,2,3,4,7,8-IIxCDF
1,2,3,6,7,8-"
u
u
151
1.43
Pg;'g
Pg/g
1.51
1.43
44.5
44.5
60851-34-5
2,3,4,6,7,8-
u
1.43
Pg/g
1.43
44.5
72918-21-9
1,2,3,7,8,9-
u
2.22
Pg/g
2 22
44.5
67562-39-4
l,"\3,4,6,7.8-IIpODF
J
9.79
Pg;'g
1.85
44.5
55673-89-7
1,2,3,4,7,8,9-IIpCDF
u
2.99
31.1
Pg'g
2.99
44.5
39001-02-0
1,2,3,4,6,7.8.9-OODF
J
Pg/g
4.45
89.0
Recovery% Acceptable Limits
84.7
94.8
84.7
84.7
95.6
1 05
90.6
97.1
97.9
84.1
81.7
86.4
74.9
87.7
82.5
94.2
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(1 7%-157%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
6176
6176006
1613 Soil
SFRA-66
26065
06/03/2014 18:53
Surrogate/'!racer recovery
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
05/29/2014 11:26
05/30/2014 10:40
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
TETR00114
SOLID
21.6
Dry Weight
IIRP750
Data File:
A02.JI N14B 3 11
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.08 g
CAS No.
Parmname
Qual
Result
Units
EDI.
PQL
1746-^1-6
2,3,7,8-TCDD
238
pg e
2 23
11.8
40321-76-4
1,2,3,7,8-PeODD
i J
2.88
pg/g
2.88
59.1
39227-28-6
1,2,3,4,7,8-HxCDD
j
3.43
pg/g
3.00
59.1
57653-85-7
1,2,3,6,7,8-HxODD
j
13.4
pg/g
2.83
59.1
19408-74-3
1,2,3,7,8,9-IIxCDD
J
5.81
pg'g
3.09
59.1
35822-46-9
1,2,3,4,6,7,8-IIpODD
363
pg;'g
6.73
59.1
3268-87-9
1,2,3,4,6,7,8.9-001)])
19300
pg«
23.0
118
51207-31-9
2,3,7,8-TODF
j
2.55
2.13
11.8
57117-41-6
1,2,3,7,8-PeODF
U
1.44
Pg/e
1.44
59.1
57117-31-4
2,3,4,7,8-PeODF
U
1.42
Pg'g
1.42
59.1
70648-26-9
57117-44-9
1,2,3,4,7,8-IIxCDF
1,2,3,6,7,8-"
u
u
143
2.02
Pg;'g
Pg/g
3.43
2.02
59.1
59.1
60851-34-5
2,3,4,6,7,8-
u
2.43
Pg/g
2.43
59.1
72918-21-9
1,2,3,7,8,9-
u
3.28
Pg/g
3.28
59.1
67562-39-4
l,"\3,4,6,7.8-IIpODF
J
51.9
Pg;'g
1.95
59.1
55673-89-7
1,2,3,4,7,8,9-IIpCDF
J
Pg'g
3.07
59.1
39001-02-0
1,2,3,4,6,7.8.9-OODF
161
Pg/g
5 22
118
Recovery% Acceptable Limits
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PeODD
] 3C-] ,2,3,4,7.8-HxODD
130-1,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
1 30-001 )I)
1 30-2,3,7,8-TO/DF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-Pe01)K
130-1,2,3,4,7,8-HxODK
1 30-1,2,3,6,7,8-HxODF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpODF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Conunents:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
82.5
94.5
82.7
85.6
92.6
96.0
90.8
98.4
95.0
81.0
81.8
83.6
73.6
83.5
79.7
96.6
(25%-164%)
(25%-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
Surrogate/I racer recovery
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number: 6176
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6176007
Date Collected:
05/29/201411:40
Matrix:
SOLID
Client Sample: 1613 Soil
Date Received:
05/30/2014 10:40
%Moisture:
19.4
Client ID:
SFRA-67
Prep Basis:
Dry Weight
Batch ID:
26065
Method:
EPA Method 1613B
Run Date:
06/03/2014 19:41
Analyst:
JTF
Instrument:
IIRP750
Data File:
A02.JI N14B 3 12
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.19 g
CAS No.
Parnmame
Qual
Result
Units
EDI.
PQL
1746-* >1-6
2,3,7,8-TCDD
U
3.15
pg e
3.15
10.4
40321-70-4
1,2,3,7,8-PeODD
IJ
1.69
pg/g
1.69
52.1
39227-28-6
1,2,3,4,7,8-HxCDD
u
1.75
pg/g
1.75
52.1
57653-85-7
1,2,3,6,7,8-HxODD
u
1.8
pg/g
1.80
52.1
19408-74-3
1,2,3,7,8,9-IIxCDD
u
1.89
pg'g
1.89
52.1
35822-46-9
1,2,3,4,6,7,8-IIpODD
J
23.0
pg;'g
3.73
52.1
3268-87-9
1,2,3,4,6,7,8.9-001)])
1900
pg«
15.1
104
51207-31-9
2,3,7,8-TODF
TJ
.915
D.915
10.4
57117-41-6
1,2,3,7,8-PeODF
u
.75
Pg/e
0.750
52.1
57117-31-4
2,3,4,7,8-PeODF
u
.761
Pg'g
i ).761
52.1
70648-26-9
1,2,3,4,7,8-IIxCDF
u
.803
Pg;'g
0.803
52.1
57117-44-9
1,2,3,6,7,8-"
u
767
Pg/g
0.767
52.1
60851-34-5
2,3,4,6,7,8-
u
.786
Pg/g
0.786
52.1
72918-21-9
1,2,3,7,8,9-
u
1.19
Pg/g
1.19
52.1
67562-39-4
1,2,3,4,6,7.8-IIpODF
u
.892
Pg;'g
0.892
52.1
55673-89-7
1,2,3,4,7,8,9-IIpCDF
u
1.37
4.59
Pg'g
1 37
52.1
39001-02-0
1,2,3,4,6,7.8.9-OODF
u
Pg/g
4.59
104
Recoverv% Acceptable Limits
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PcODI)
] 30-] ,2,3,4,7.8-HxODD
130-1,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpCDI)
130-001)1)
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpCDF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
82.0
90.8
82.4
86.1
89.3
85.2
94.8
95.9
91.7
82.9
82.2
84.8
74.6
84.3
78.2
92.9
(25%-164%)
(25%-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number: 6176
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6176008
Date Collected:
05/29/2014 12:00
Matrix:
SOLID
Client Sample: 1613 Soil
Date Received:
05/30/2014 10:40
%Moisture:
22.7
Client ID:
SFRA-68
Prep Basis:
Dry Weight
Batch ID:
26065
Method:
EPA Method 1613B
Run Date:
06/03/2014 20:30
Analyst:
JTF
Instrument:
IIRP750
Data File:
A02JI N14B 3 13
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.07 g
CAS No.
Parnmame
Qual
Result
Units
EDI.
PQL
1746-* >1-6
2,3,7,8-TCDD
141
pg e
1.72
12.1
40321-70-4
1,2,3,7,8-PeODD
i J
2.83
pg/g
2.83
60.4
39227-28-6
1,2,3,4,7,8-HxCDD
U
3.14
pg/g
3.14
60.4
57653-85-7
1,2,3,6,7,8-HxODD
J
9.53
pg/g
3.31
60.4
19408-74-3
1,2,3,7,8,9-IIxCDD
J
5.59
pg'g
3.43
60.4
35822-46-9
1,2,3,4,6,7,8-IIpODD
271
pg'g
7.23
60.4
3268-87-9
1,2,3,4,6,7,8.9-001)])
8220
pg«
23.0
121
51207-31-9
2,3,7,8-TCDF
TJ
2.59
2.59
12.1
57117-41-6
1,2,3,7,8-PeODF
J
1.84
Pg/e
1.76
60.4
57117-31-4
2,3,4,7,8-PeODF
u
1.68
Pg'g
1.68
60.4
70648-26-9
57117-44-9
1,2,3,4,7,8-IIxCDF
1,2,3,6,7,8-"
u
u
2,!
2.9
Pg;'g
Pg/g
2.85
2.90
60.4
60.4
60851-34-5
2,3,4,6,7,8-
u
2.83
Pg/g
2.83
60.4
72918-21-9
1,2,3,7,8,9-
u
4.21
Pg-'g
4.21
60.4
67562-39-4
l,"\3,4,6,7.8-IIpCDF
J
31.5
Pg;'g
2.08
60.4
55673-89-7
1,2,3,4,7,8,9-IIpCDF
u
3.48
99.6
Pg'g
3.48
60.4
39001-02-0
1,2,3,4,6,7.8.9-OODF
J
Pg/g
6.63
121
Surrogate/'!racer recovery
Recoverv% Acceptable Limits
1 30-2,3,7,8-TCDl)
130-1,2,3,7,8-PeODD
] 30-] ,2,3,4,7.8-HxODD
130-1,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
130-001)1)
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxCDF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpCDF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
84.1
91.8
79.1
81.3
87.3
87.7
90.2
94.4
93.6
80.0
79.3
82.1
73.2
84.1
77.3
95.2
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(1 7%-157%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
6176
6176009
1613 Soil
SFRA-69
26065
06/03/2014 23:02
A02.JI N14B 4 2
26063
30 MAY 14
Parmname
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PeODD
] 3C-] ,2,3,4,7.8-HxODD
13C-l,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
13O-O0DD
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxODF"
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpCDF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analytewas analyzed for,
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Quul
TETR001
05/29/2014 12:35
05/30/2014 10:40
EPA Method H.I.Hi
JTF
SW846 3540C
1.08 g
Result
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
19.1
Dry Weight
I1RP750
1
1746-i 11-6
2,3,7,8-TCDD
U
1.25
40321-76-4
1,2,3,7,8-PeODD
U
1.75
39227-28-6
1,2,3,4,7,8-HxCDD
U
2.36
57653-85-7
1,2,3,6,7,8-HxODD
u
2.31
19408-74-3
1,2,3,7,8,9-IIxCDD
u
2.47
35822-46-9
1,2,3,4,6,7,8-IIpODD
J
20.8
3268-87-9
1,2,3,4,6,7,8.9-001)])
3360
51207-31-9
2,3,7,8-TODF
TJ
1.15
57117-41-6
1,2,3,7,8-PeODF
u
.783
57117-31-4
2,3,4,7,8-PeODF
u
.753
70648-26-9
1,2,3,4,7,8-IIxCDF
u
1.14
57117-44-9
1,2,3,6,7,8-"
u
1.13
60851-34-5
2,3,4,6,7,8-
u
1.15
72918-21-9
1,2,3,7,8,9-
u
1.85
67562-39-4
l,"\3,4,6,7.8-IIpODF
I..J
1.35
55673-89-7
1,2,3,4,7,8,9-IIpCDF
I..J
39001-02-0
1,2,3,4,6,7.8.9-OODF
I..J
4.67
Surrogate/'!racer recovery
Units
EDL
PQL
pge
1.25
11.4
pg-;g
1.75
57.2
pg-;g
2.36
57.2
pg/g
2.31
57.2
pg'g
2.47
57.2
pg;'g
4.17
57.2
PB«
22.2
114
1*
1.15
11.4
Pg/e
0.783
57.2
Pg'g
0.753
57.2
Pg''g
1.14
57.2
Pg-'g
1.13
57.2
Pg/g
1.15
57.2
Pg-'g
1.85
57.2
Pg;'g
1.35
57.2
Pg'g
2.03
57.2
Pg/g
4.67
114
Recovery% Acceptable Limits
82.1
83.0
82.1
92.4
88.7
81.8
87.3
88.5
84.5
82.6
88.4
89.0
75.2
74.5
76.3
93.6
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(1 7%-157%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
6176
6176010
1613 Soil
SFRA-70
26065
06/03/2014 23:50
A02.JI N14B 4 3
26063
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57117-44-9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
Surrogate/I racer recovery
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
05/29/2014 12:55
05/30/2014 10:40
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
20.4
Dry Weight
I1RP750
1
Prep Method: SW846 3540C
30-MAY-14
Prep Aliquot:
1.43 g
Parmname
Qual
Result
Units
EDI,
PQL
2,3,7,8-TCDD
89. 1
Pgg
[.3D
S 7c
1,2,3,7,8-PeODD
U
1.9
Pg/g
1.90
43.9
1,2,3,4,7,8-HxCDD
u
2.97
Pg/g
2.97
43.9
1,2,3,6,7,8-HxODD
J
6.54
Pg/g
2.95
43.9
1,2,3,7,8,9-IIxCDD
J
3.53
Pg'g
3.15
43.9
1,2,3,4,6,7,8-IIpODD
184
Pg;'g
5.82
43.9
1,2,3,4,6,7,8.9-001)])
11100
pg«
32.2
87.9
2,3,7,8-TODF
TJ
1.6
1.60
8.79
1,2,3,7,8-PeODK
u
1.56
Pg/e
1.56
43.9
2,3,4,7,8-PeODF
u
1.57
Pg'g
1.57
43.9
1,2,3,4,7,8~IIxCDF
1,2,3,6,7,8-"
J
u
1.65
,55
Pg;'g
Pg/g
1.60
1.55
43.9
43.9
2,3,4,6,7,8-
u
1.61
Pg/g
1.61
43.9
1,2,3,7,8,9-
u
2.43
Pg/g
2.43
43.9
l,"\3,4,6,7.8-IIpODF
J
23.6
Pg;'g
1.75
43.9
1,2,3,4,7,8,9-IIpCDF
I..J
Pg'g
2.97
43.9
1,2,3,4,6,7.8.9-OODF
J
64.1
Pg/g
5.31
87.9
Recovery% Acceptable Limits
130-2,3,7,8-TODD
130-1 ,2,3,7,8-PcOl )l)
130-1,2,3,4,7.8-HxODD
1 3C-l,2,3,6,7.8-HxCDD
1 30-1,2,3,4,6,7,8-HpOl)[)
130-001)1)
1 3C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODK
130-1,2,3,4,7,8-HxODK
1 3C-1,2,3,6,7.8-HxODF
13C-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8,9-IIxCDF
130-1,2,3,4,6,7,8-IIpCDF
130-1,2,3,4,7,8,9-FIpCDF
3 7Cl-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
74.9
79.2
72.4
77.6
75.8
77.2
81.2
85.1
82.6
71.5
76.1
76.1
66.4
73.1
67.8
98.2
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number: 6176
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6176011
Date Collected:
05/29/2014 13:13
Matrix:
SOLID
Client Sample: 1613 Soil
Date Received:
05/30/2014 10:40
%Moisture:
20.6
Client ID:
SFRA-71
Prep Basis:
Dry Weight
Batch ID:
26065
Method:
EPA Method 1613B
Run Date:
06/04/2014 00:38
Analyst:
JTF
Instrument:
IIRP750
Data File:
A02JI N14B 4 4
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.24 g
CAS No.
Parmname
Qual
Result
Units
EDI.
PQL
1746-* >1-6
2,3,7,8-TCDD
U
1.27
pg e
1.27
10.2
40321-76-4
1,2,3,7,8-PeODD
u
1.52
pg-;g
1.52
50.8
39227-28-6
1,2,3,4,7,8-HxCDD
u
2 21
pg/g
2.21
50.8
57653-85-7
1,2,3,6,7,8-HxODD
u
2.26
pg/g
2.26
50.8
19408-74-3
1,2,3,7,8,9-IIxCDD
u
2.38
pg'g
2.38
50.8
35822-46-9
1,2,3,4,6,7,8-IIpODD
84.3
pg;'g
6.26
50.8
3268-87-9
1,2,3,4,6,7,8.9-001)])
10800
pg«
26.2
102
51207-31-9
2,3,7,8-TODF
TJ
1.32
1.32
10.2
57117-41-6
1,2,3,7,8-PeODF
u
.908
Pg/e
0.908
50.8
57117-31-4
2,3,4,7,8-PeODF
u
.888
Pg'g
i s.888
50.8
70648-26-9
57117-44-9
1,2,3,4,7,8-IIxCDF
1,2,3,6,7,8-"
u
u
.668
Pg;'g
Pg-'g
0.725
0.668
50.8
50.8
60851-34-5
2,3,4,6,7,8-
u
¦701
Pg/g
0.701
50.8
72918-21-9
1,2,3,7,8,9-
u
1.13
Pg-'g
1.13
50.8
67562-39-4
l,"\3,4,6,7.8-IIpODF
u
.975
Pg;'g
0.975
50.8
55673-89-7
1,2,3,4,7,8,9-IIpCDF
u
1.58
4.41
Pg'g
1.58
50.8
39001-02-0
1,2,3,4,6,7.8.9-OODF
u
Pg/g
4.41
102
Surrogate/'!racer recovery
Recoverv% Acceptable Limits
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PeODD
] 30-] ,2,3,4,7.8-HxODD
130-1,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpCDI)
130-001)1)
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpCDF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
I Analvte was analyzed for, but not detected above the specified detection limit.
78.0
83.8
77.0
85.5
86.9
84.9
85.7
89.2
89.1
80.2
84.7
82.7
74.2
83.0
74.7
87.0
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date: June 4, 2014
SIX. Number:
Lab Sample II):
Client Sample:
Client 11):
Batch II):
Run Date:
Data File:
Prep Batch:
Prep Date:
6X76
6176012
1613 Soil
SFMA-72
26065
06/04/2014 01:26
Alt2.II M4H 4 5
26063
30-MAY-14
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
05/29/2014 13:25
05/30/2014 10:40
EPA Method 1613B
JT1
SW846 3540C
1.18 g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
47
Dry Weight
HRP750
1
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-* >1-6
2,3,7,8-TODD
573
Pg'g
3.97
lot.
40321-76-4
1,2,3,7,8-PeODD
j
9.06
Pg/g
4.00
80.0
39227-28-6
1,2,3,4,7,8-HxCDD
QU
54.1
Pg/g
54.1
80.0
57653-85-7
1,2,3,6,7,8-HxODD
Q
964
Pg/g
77.5
80.0
19408-74-3
1,2,3,7,8,9-IIxCDD
Q
405
Pg'g
68.2
80.0
35822-46-9
1,2,3,4,6,7.8-IIpCDD
9020
pg;'g
17 1
80.0
3268-87-9
1,2,3,4,6,7,8,9-001)])
52500
pg«
36.5
160
51207-31-9
2,3,7,8-TCDF
j
12.2
5.38
16.0
57117-41-6
1,2,3,7,8-PeODK
j
6.15
Pg/e
2.71
80.0
57117-31-4
2,3,4,7,8-PeCDF
J
19.7
Pg'g
2.80
80.0
70648-26-9
1,2,3,4,7,8~IIxCDF
Q
117
Pg'g
15.9
80.0
57117-44-9
1,2,3,6,7,8-''
j
55.5
Pg/g
10.3
80.0
60851-34-5
2,3,4,6,7,8-
92.4
Pg/g
11.2
80.0
72918-21-9
1,2,3,7,8,9-
u
17.3
Pg/g
17.3
80.0
67562-39-4
l,"\3,4,6,7.8-IIpCDF
1200
Pg'g
8.32
80.0
55673-89-7
1,2,3,4,7,8,9-IIpCDF
Pg'g
16.6
80.0
39001-02-0
1,2,3,4,6,7.8.9-OCDF
2260
Pg/g
14.4
160
Surrogate/Tracer recovery
I nits
Recovery%
Acceptable Limits
130-2,3,7,8-TODD
2340
Pg'g
73.1
(25%-164%)
1 30-1,2,3,7,8-PeOl )D
3200
Pg'g
70.6
(25°/b-181%)
1 30-1,2,3,4,7,8-HxODD
Q
1880
3200
Pg'g
58.8
(32%-141%)
1 30-1,2,3,6,7.8-HxCDD
Q
1320
3200
pg''g
41.4
(28%-130%)
130-1,2,3,4,6.7,8-HpODD
3200
Pg'g
136
(23%-140%)
130-00])!)
9650
6400
Pg'g
151
(17%-15 7%)
130-2,3,7,8-TCDF
2570
3200
Pg'g
80.2
(24%-169%)
130-1,2,3,7,8-PeODF
2250
3200
pg''g
70.2
(24%-185%)
130-2,3,4,7,8-PeODK
2260
3200
Pg'g
70.6
(21 %-178%)
1 30-1,2,3,4,7,8-HxOl )F
Q
2700
3200
Pg'g
84.5
(26%-152%)
1 30-1,2,3,6,7,8-HxODF"
3120
3200
Pg'g
97.5
(26%-123%)
13C-2,3,4,6,7,8-IIxCDF
3220
3200
pg/g
101
(28%-136%)
13C-l,2,3,7,8.9-IIxCDF
2230
3200
pg/g
69.8
(29%-147%)
13C-l,2,3,4,6.7.8-IIpCDF
3590
3200
pg/g
112
(28%-143%)
13C-l,2,3,4,7.8.9-HpCDF
3540
3200
pg/g
111
(26%-13 8%)
3701-2,3,7,8-TCDD
279
320
Pg/g
87.2
(35%-197%)
Conunents:
J Value is estimated
Q Quantitative Interference
I Analyte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
June 4, 2014
Surrogate/I racer recovery
1 30-2,3,7,8-TODl)
130-1,2,3,7,8-PeODD
] 3C-] ,2,3,4,7.8-HxODD
13C-l,2,3,6,7.8-HxCDD
130-1,2,3,4,6.7,8-HpODD
130-OODD
13C-2,3,7,8-TCDF
130-1,2,3,7,8-PeODF
130-2,3,4,7,8-PeODF
130-1,2,3,4,7,8-HxODF
1 30-1,2,3,6,7,8-HxCDF
130-2,3,4,6,7,8-IIxCDF
130-1,2,3,7,8.9~IIxCDF
130-1,2,3,4,6,7,8-IIpODF
130-1,2,3,4,7,8,9-HpCDF
3701-2,3,7,8-TCDD
Comments:
J Value is estimated
U Analytewas analyzed for,
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number: 6176
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6176013
Date Collected:
05/29/2014 13:38
Matrix:
SOLID
Client Sample: 1613 Soil
Date Received:
05/30/2014 10:40
%Moisture:
22.9
Client ID:
SFRA-73
Prep Basis:
Dry Weight
Batch ID:
26065
Method:
EPA Method 1613B
Run Date:
06/04/2014 02:15
Analyst:
JTF
Instrument:
HRP750
Data File:
A02JI N14B 4 6
Dilution:
1
Prep Batch:
26063
Prep Method:
SW846 3540C
Prep Date:
30 MAY 14
Prep Aliquot:
1.05 g
CAS No.
Parnmame
Qual
Result
Units
EDI.
PQL
1746-* >1-6
2,3,7,8-TCDD
3()()0
pg e
3.19
12.4
40321-76-4
1,2,3,7,8-PeODD
U
4.57
pg/g
4.57
61.8
39227-28-6
1,2,3,4,7,8-HxCDD
u
5.88
pg/g
5.88
61.8
57653-85-7
1,2,3,6,7,8-HxODD
65.0
pg/g
7.49
61.8
19408-74-3
1,2,3,7,8,9-IIxCDD
J
24.7
pg'g
7.07
61.8
35822-46-9
1,2,3,4,6,7,8-IIpODD
896
pg;'g
6.52
61.8
3268-87-9
1,2,3,4,6,7,8.9-001)])
14000
Pg/g
24.5
124
51207-31-9
2,3,7,8-TODF
18.9
4.20
12.4
57117-41-6
1,2,3,7,8-PeODF
u
2.92
pg/e
2.92
61.8
57117-31-4
2,3,4,7,8-PeODF
J
4.18
pg'g
2.42
61.8
70648-26-9
57117-44-9
1,2,3,4,7,8-IIxCDF
1,2,3,6,7,8-"
J
J
7.56
6.08
pg;,g
pg/g
3.21
3.31
61.8
61.8
60851-34-5
2,3,4,6,7,8-
J
8.08
pg/g
3.26
61.8
72918-21-9
1,2,3,7,8,9-
u
4.72
pg/g
4.72
61.8
67562-39-4
l,"\3,4,6,7.8-IIpODF
204
pg'g
3.36
61.8
55673-89-7
1,2,3,4,7,8,9-IIpCDF
J
13.1
586
pg'g
5.49
61.8
39001-02-0
1,2,3,4,6,7.8.9-OODF
pg/g
7.27
124
Recovery% Acceptable Limits
81.8
83.4
74.1
61.8
105
104
90.4
68.7
79.8
81.4
76.3
83.0
77.7
89.7
86.4
99.3
(25%-164%)
(25°/b-181%)
(32%-141%)
(28%-130%)
(23%-140%)
(1 7%-157%)
(24%-169%)
(24%-185%)
(21 %-178%)
(26%-152%)
(26%-123%)
(28%-136%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
but not detected above the specified detection limit.
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 09. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6191
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 03, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of21
problem solved
-------
Page; /.
Project #:
CFAQuote#: _
COC Number0':
PO Number:
of
±
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number; Ifll C
Cape Fear Analytical, LLC
3306 Kilty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Name: L ~ Phone#:
Sample Analysis Requested(5) (Fill in the number of containers for each test)
Wojeet/SiteN^e^^^
1
Total number of containers
fc
<- Preservative Type (6)
Address: *ZM -JQMf $4oWD
pa
£2
Comments
"Note: extra sample is
required for sample
specific QC
touted by: (^(Xu+O C Send Results To; tMe/, rt#+
vj
Sample ID
• For composites - indicate start and stop date/time
*Date Collected
(mm-dd-yy)
~Time
Collected
(Military)
(bhram)
QCCode
(2)
Field
Filtered<3>
Sample
Matrix
S-To-H
$6440
CFA PM:
Method of Shipment:
ftclex
Date Shipped:
** ffOV2- J 1^1 Ofoctf
3
Airbill #:
Airbill #:
1.) Chain ofCustody Number- Client Determined
2.) QC Codes: N - Normal Sample. TB - Trip Blank, FD = Field Duplicate,IB " Equipment Blank, MS - Matrix Spike Sample, MSB - Matrix Spike Duplicate Sample, G = Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: DW-Drinkitig Water, GW Groundwater. SW~Sutfa« Water, WW=Waste Water, W-Waler, ML-Misc Liquid,SO-Soil, SD-Sediment,SL-Sludge, SS=SoIid Waste, O=0il,F^Filter,P-Wipe, IHJrine, F=F«al, N Nasal
5.) Sample Analysis Requested: Analytical method requested (i.eS290B, 1668B) and number of containers provided for each (3,e 82MB -3, MSB -1).
6.) Preservative Type: HA - Hydrochloric Acid,NI - Nitric Acid, SH - Sodium Hydroxide, SA - Sulfuric Acid, AA - Ascorbic Acid, TIX - Hexane, ST - Sodium Thlosulfate, If no preservative is added - leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Seal Intact?,
NO
'ooler Temp:
fv, c
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
Work Order: [fll 1
Shipping Company:
Date/Time Received: (j f\J ( t( Qtf L[Q
Suspected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0,5 mR/hr?
Samples identified as Foreign Soil?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Air Sample Receipt Specifics
Yes 1 NA
No
Air Witness:
Air sample in shipment?
1
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
1/
x-
Grde Applicable:
seals broken damaged container Seaking container cther(describe)
2
Chain of Custody documents included
with shipment?
s_x--
3
Samples requiring cold preservation
within 0-6°C?
(/
X"
(
PteSPTwition Method:
fee bags 1 blue ice dry ice none other (describe)
5>1C-
4
Aqueous samples found to have visible
solids?
/
Sample IDs, containers affected;
5
Samples requiring chemical
preservation at proper pH?
/
~
Sample IDs, containers affected and pn observed;
If preservative added, Lot#:
6
Samples requiring preservation have
no residual chlorine?
Sample IDs, containers affected:
If preservative added, let#:
7
Samples received within holding time?
l/
/: ¦
Sample !Ds, tests affected:
8
Sample IDs on COC match IDs on
containers?
y
/ ¦¦
Sample IDs, containers affected:
9
Date & time of COC match date & time
on containers?
L/
/
Sample IDs, containers affected:
10
Number of containers received match
number indicated on COC?
/
Sample IDs, containers affected:
11
COC form is properly signed in
relinquished/received sections?
1/
Comments:
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of21
-------
Case Narrative
Page 5 of21
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG6191
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26082
Clean Up Batch Number: 26081
Extraction Batch Number: 26080
Sample Analysis
The following samples were analyzed using the analytical protocol as established in
Sample ID Client ID
6191001 SFRA-74
6191002 SFRA-75
12010581 Method Blank (MB)
12010582 Laboratory Control Sample (LCS)
12010583 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of21
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. 6191001 and 6191002.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP with the following exceptions. A 5g dry
weight was performed per client request and a lg extraction was performed due to the high levels
of target analytes that may be present.
Sample Dilutions
Samples 6191001 (SFRA-74) and 6191002 (SFRA-75)- Batch 26082 were diluted due to the
presence of over range target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 7 of21
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of21
-------
Sample Data Summary
Page 9 of21
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6191 CFA Work Order: 6191
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 09JUN2014 Title: Data Validator
Page 10 of 21
-------
Cape Fear Analytical LLC
Report Date:
June 9, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6191
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6191001
Date Collected:
05/30/2014 09:55
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
06/03/2014 09:40
%Moisture: 22.1
Client ID:
SFRA-74
Prep Basis: Dry Weight
Batch ID:
26082
Method:
EPA Method 1613B
Run Date:
06/06/2014 13:21
Analyst:
JTF
Instrument: HRP750
Data File:
A06JUN14A-5
Dilution: 10
Prep Batch:
26080
Prep Method:
SW846 3540C
Prep Date:
04-JUN-14
Prep Aliquot:
1.12 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
12000
Pg/g
12.7 115
40321-76-4
1,2,3,7,8-PeCDD
U
13.4
Pg/g
13.4 573
39227-28-6
1,2,3,4,7,8-HxCDD
QU
22.8
Pg/g
22.8 573
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
171
Pg/g
32.3 573
19408-74-3
1,2,3,7,8,9-HxCDD
J
51.6
Pg/g
28.9 573
35822-46-9
1,2,3,4,6,7,8-HpCDD
1260
Pg/g
32.1 573
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13600
Pg/g
117 1150
51207-31-9
2,3,7,8-TCDF
J
64.4
Pg/g
22.8 115
57117-41-6
1,2,3,7,8-PeCDF
U
11.9
Pg/g
11.9 573
57117-31-4
2,3,4,7,8-PeCDF
u
11.8
Pg/g
11.8 573
70648-26-9
1,2,3,4,7,8-HxCDF
u
20.9
Pg/g
20.9 573
57II7.44.9
1,2,3,6,7,8-HxCDF
u
22
Pg/g
22.0 573
60851-34-5
2,3,4,6,7,8-HxCDF
J
17.6
Pg/g
13.2 573
72918-21-9
1,2,3,7,8,9-HxCDF
u
18.8
Pg/g
18.8 573
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
330
Pg/g
12.4 573
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
24.4
Pg/g
24.4 573
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
602
Pg/g
66.7 1150
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1720
2290
Pg/g
74.9
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1870
2290
Pg/g
81.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1730
2290
Pg/g
75.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1320
2290
Pg/g
57.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2020
2290
Pg/g
88.1
(23%-140%)
13C-OCDD
3940
4580
Pg/g
86.1
(17%-157%)
13C-2,3,7,8-TCDF
1840
2290
Pg/g
80.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1900
2290
Pg/g
82.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1910
2290
Pg/g
83.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1710
2290
Pg/g
74.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1730
2290
Pg/g
75.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1730
2290
Pg/g
75.3
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1640
2290
Pg/g
71.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1850
2290
Pg/g
80.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1910
2290
Pg/g
83.4
(26%-13 8%)
3701-2,3,7,8-TCDD
250
229
Pg/g
109
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 21
-------
Cape Fear Analytical LLC
Report Date:
June 9, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6191
Lab Sample ID: 6191002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
05/30/201411:10
06/03/2014 09:40
Project: TETR00114
Matrix: SOLID
%Moisture: 20.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-75
26082
06/06/2014 14:08
A06JUN14A-6
26080
04-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.35 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
4690
Pg/g
3.77 46.4
40321-76-4
1,2,3,7,8-PeCDD
U
6.24
Pg/g
6.24 232
39227-28-6
1,2,3,4,7,8-HxCDD
QU
10.5
Pg/g
10.5 232
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
125
Pg/g
22.5 232
19408-74-3
1,2,3,7,8,9-HxCDD
J
35.1
Pg/g
16.1 232
35822-46-9
1,2,3,4,6,7,8-HpCDD
1300
Pg/g
11.7 232
3268-87-9
1,2,3,4,6,7,8,9-OCDD
18800
Pg/g
44.6 464
51207-31-9
2,3,7,8-TCDF
J
30.1
Pg/g
9.45 46.4
57117-41-6
1,2,3,7,8-PeCDF
U
4.05
Pg/g
4.05 232
57117-31-4
2,3,4,7,8-PeCDF
u
7.69
Pg/g
7.69 232
70648-26-9
1,2,3,4,7,8-HxCDF
u
12.1
Pg/g
12.1 232
57II7.44.9
1,2,3,6,7,8-HxCDF
u
9.47
Pg/g
9.47 232
60851-34-5
2,3,4,6,7,8-HxCDF
J
11.9
Pg/g
7.35 232
72918-21-9
1,2,3,7,8,9-HxCDF
u
10.8
Pg/g
10.8 232
67562-39-4
1,2,3,4,6,7,8-HpCDF
286
Pg/g
5.68 232
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
20.4
Pg/g
9.86 232
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1090
Pg/g
15.8 464
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1530
1860
Pg/g
82.2
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1620
1860
Pg/g
87.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1430
1860
Pg/g
76.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 842
1860
Pg/g
45.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1750
1860
Pg/g
94.0
(23%-140%)
13C-OCDD
3450
3710
Pg/g
92.8
(17%-157%)
13C-2,3,7,8-TCDF
1590
1860
Pg/g
85.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1660
1860
Pg/g
89.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1650
1860
Pg/g
89.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1450
1860
Pg/g
78.0
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1380
1860
Pg/g
74.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1470
1860
Pg/g
79.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1370
1860
Pg/g
74.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1550
1860
Pg/g
83.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1630
1860
Pg/g
87.5
(26%-13 8%)
3701-2,3,7,8-TCDD
192
186
Pg/g
103
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 21
-------
Quality Control
Summary
Page 13 of 21
-------
( ape Fear \lltllytictll LLC Report Date: June 9, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6191
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010582
LCS for batch 26080
12010583
LCSD for batch 26080
12010581
MB for batch 26080
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
77.4
88.5
77.1
72.9
86.9
81.5
81.8
91.8
89.2
75.0
73.5
74.7
68.8
77.1
80.6
92.7
77.1
84.5
78.0
76.3
89.2
86.8
86.5
85.2
85.3
77.9
74.5
78.1
72.8
81.3
82.7
91.1
74.1
80.8
72.1
70.9
78.3
70.6
77.2
87.3
83.0
71.7
69.6
71.7
65.4
72.8
70.6
82.5
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6191001
SFRA-74
13C-2,3,7,8-TCDD
74.9 D
(25%-164%)
Page 14 of 21
-------
( ape Fear \lltllytictll LLC Report Date: June 9, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6191
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
81.7
D
(25%-
¦181%)
75.4
D
(32%-
¦141%)
57.5
D
(28%-
¦130%)
88.1
D
(23%-
¦140%)
86.1
D
(17%-
¦157%)
80.2
D
(24%-
¦169%)
82.7
D
(24%-
¦185%)
83.4
D
(21%-
¦178%)
74.7
D
(26%-
¦152%)
75.5
D
(26%-
¦123%)
75.3
D
(28%-
¦136%)
71.6
D
(29%-
¦147%)
80.9
D
(28%-
¦143%)
83.4
D
(26%-
¦138%)
109
D
(35%-
¦197%)
6191001
SFRA-74
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
6191002
SFRA-75
13C-2,3,7,8-TCDD
82.2
D
(25%-
¦164%)
13C-1,2,3,7,8-PeCDD
87.3
D
(25%-
¦181%)
13C-1,2,3,4,7,8-HxCDD
Q 76.8
D
(32%-
¦141%)
13C-1,2,3,6,7,8-HxCDD
Q 45.3
D
(28%-
¦130%)
13C-1,2,3,4,6,7,8-HpCDD
94.0
D
(23%-
¦140%)
13C-OCDD
92.8
D
(17%-
¦157%)
13C-2,3,7,8-TCDF
85.6
D
(24%-
¦169%)
13C-1,2,3,7,8-PeCDF
89.3
D
(24%-
¦185%)
13C-2,3,4,7,8-PeCDF
89.1
D
(21%-
¦178%)
13C-1,2,3,4,7,8-HxCDF
78.0
D
(26%-
¦152%)
13C-1,2,3,6,7,8-HxCDF
74.2
D
(26%-
¦123%)
13C-2,3,4,6,7,8-HxCDF
79.2
D
(28%-
¦136%)
13C-1,2,3,7,8,9-HxCDF
74.0
D
(29%-
¦147%)
13C-1,2,3,4,6,7,8-HpCDF
83.3
D
(28%-
¦143%)
13C-1,2,3,4,7,8,9-HpCDF
87.5
D
(26%-
¦138%)
37Cl-2,3,7,8-TCDD
103
D
(35%-
¦197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 15 of 21
-------
Cape Fear Analytical LLC
Report Date: June 9, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/06/2014 10:47 Dilution: 1
Prep Batch ID:26080
Batch ID: 26082
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.3
107
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
104
104
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
101
101
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
107
107
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
110
110
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
102
102
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
217
108
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.7
98.7
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
100
100
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
101
101
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
102
102
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
101
101
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
102
102
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
109
109
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
99.7
99.7
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
98.1
98.1
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
198
99.1
63-170
SDG Number: 6191
Client ID: LCS for batch 26080
Lab Sample ID: 12010582
Instrument: HRP750
Analyst: JTF
Page 16 of 21
-------
Cape Fear Analytical LLC
Report Date: June 9, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/06/2014 11:35 Dilution: 1
Prep Batch ID:26080
Batch ID: 26082
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.2
106
67-158
0.639
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
106
106
70-142
1.77
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
102
102
70-164
0.501
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
109
109
76-134
1.67
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
115
115
64-162
3.67
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
103
103
70-140
0.788
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
206
103
78-144
4.92
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.8
94.1
75-158
4.78
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
99.8
99.8
80-134
0.623
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
101
101
68-160
0.369
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
101
101
72-134
1.15
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
102
102
84-130
1.49
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
101
101
70-156
1.22
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
107
107
78-130
1.91
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
99.5
99.5
82-122
0.183
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
99.8
99.8
78-138
1.73
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
196
98.2
63-170
0.896
0-20
SDG Number: 6191
Client ID: LCSD for batch 26080
Lab Sample ID: 12010583
Instrument: HRP750
Analyst: JTF
Page
17 of 21
-------
Cape Fear Analytical LLC
Report Date:
June 9, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6191
Client ID: MB for batch 26080
Lab Sample ID: 12010581
Column:
Client: TETR001
Instrument ID: HRP750
Prep Date: 04-JUN-14
Matrix: SOLID
Data File: A06JUN14A-4
Analyzed: 06/06/1412:23
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26080
12010582
A06JUN14A-2
06/06/14
1047
02
LCSD for batch 26080
12010583
A06JUN14A-3
06/06/14
1135
03
SFRA-74
6191001
A06JUN14A-5
06/06/14
1321
04
SFRA-75
6191002
A06JUN14A-6
06/06/14
1408
Page 18 of 21
-------
Cape Fear Analytical LLC
Report Date:
June 9, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6191
12010581
QC for batch 26080
MB for batch 26080
26082
06/06/2014 12:23
A06JUN14A-4
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
26080
Prep Method:
SW846 3540C
Prep Date:
04-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.0958
Pg/g
0.0958
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.274
Pg/g
0.274
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
J
0.318
Pg/g
0.176
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.384
Pg/g
0.384
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.332
Pg/g
0.332
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.590
Pg/g
0.218
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
3.35
Pg/g
0.394
10.0
51207-31-9
2,3,7,8-TCDF
u
.146
Pg/g
0.146
1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.314
Pg/g
0.314
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.34
Pg/g
0.340
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.352
Pg/g
0.187
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.304
Pg/g
0.304
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.286
Pg/g
0.198
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.448
Pg/g
0.296
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.394
Pg/g
0.116
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
0.282
Pg/g
0.185
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
0.692
Pg/g
0.470
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
148
200
Pg/g
74.1
(25 %-164%)
13C-1,2,3,7,8-PeCDD
162
200
Pg/g
80.8
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
144
200
Pg/g
72.1
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
142
200
Pg/g
70.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
157
200
Pg/g
78.3
(23%-140%)
13C-OCDD
282
400
Pg/g
70.6
(17%-157%)
13C-2,3,7,8-TCDF
154
200
Pg/g
77.2
(24%-169%)
13C-1,2,3,7,8-PeCDF
175
200
Pg/g
87.3
(24%-185%)
13C-2,3,4,7,8-PeCDF
166
200
Pg/g
83.0
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
143
200
Pg/g
71.7
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
139
200
Pg/g
69.6
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
143
200
Pg/g
71.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
131
200
Pg/g
65.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
146
200
Pg/g
72.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
141
200
Pg/g
70.6
(26%-13 8%)
37Cl-2,3,7,8-TCDD
16.5
20.0
Pg/g
82.5
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 21
-------
Cape Fear Analytical LLC
Report Date:
June 9, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6191
Lab Sample ID: 12010582
Client Sample: ^or batch 26080
Client ID: LCS for batch 26080
Batch ID: 26082
Run Date: 06/06/2014 10:47
Data File: A06JUN14A-2
Prep Batch: 26080
Prep Date: 04-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.3
Pg/g
0.092 1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.238 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
101
Pg/g
0.364 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
107
Pg/g
0.390 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
110
Pg/g
0.402 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
102
Pg/g
0.396 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
217
Pg/g
1.15 10.0
51207-31-9
2,3,7,8-TCDF
19.7
Pg/g
0.115 1.00
57117-41-6
1,2,3,7,8-PeCDF
100
Pg/g
0.260 5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.258 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
102
Pg/g
0.426 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
101
Pg/g
0.408 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
102
Pg/g
0.438 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
109
Pg/g
0.634 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
99.7
Pg/g
0.306 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
98.1
Pg/g
0.466 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
198
Pg/g
0.978 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
155
200
Pg/g
77.4
(20%-175%)
13C-1,2,3,7,8-
PeCDD
177
200
Pg/g
88.5
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
154
200
Pg/g
77.1
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
146
200
Pg/g
72.9
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
174
200
Pg/g
86.9
(22%-166%)
13C-OCDD
326
400
Pg/g
81.5
(13%-199%)
13C-2,3,7,8-TCDF
164
200
Pg/g
81.8
(22%-152%)
13C-1,2,3,7,8-
PeCDF
184
200
Pg/g
91.8
(21%-192%)
130-2,3,4,7,8-
PeCDF
178
200
Pg/g
89.2
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
150
200
Pg/g
75.0
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
147
200
Pg/g
73.5
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
149
200
Pg/g
74.7
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
138
200
Pg/g
68.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
154
200
Pg/g
77.1
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
161
200
Pg/g
80.6
(20%-186%)
3701-2,3,7,8-TCDD
18.5
20.0
Pg/g
92.7
(31 %-191%)
Comments:
Page 20 of 21
-------
Cape Fear Analytical LLC
Report Date:
June 9, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6191
12010583
QC for batch 26080
LCSD for batch 26080
26082
06/06/2014 11:35
A06JUN14A-3
26080
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
04-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
21.2
Pg/g
0.104
1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.193
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
102
Pg/g
0.370
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
109
Pg/g
0.404
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
115
Pg/g
0.412
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
103
Pg/g
0.434
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
206
Pg/g
1.21
10.0
51207-31-9
2,3,7,8-TCDF
18.8
Pg/g
0.0794
1.00
57117-41-6
1,2,3,7,8-PeCDF
99.8
Pg/g
0.222
5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.232
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
101
Pg/g
0.408
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
102
Pg/g
0.406
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
101
Pg/g
0.422
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
107
Pg/g
0.600
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
99.5
Pg/g
0.342
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.8
Pg/g
0.498
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
196
Pg/g
0.940
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
154
200
Pg/g
77.1
(20%-175%)
13C-1,2,3,7,8-PeCDD
169
200
Pg/g
84.5
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
156
200
Pg/g
78.0
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
153
200
Pg/g
76.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
178
200
Pg/g
89.2
(22%-166%)
13C-OCDD
347
400
Pg/g
86.8
(13%-199%)
13C-2,3,7,8-TCDF
173
200
Pg/g
86.5
(22%-152%)
13C-1,2,3,7,8-PeCDF
170
200
Pg/g
85.2
(21%-192%)
13C-2,3,4,7,8-PeCDF
171
200
Pg/g
85.3
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
156
200
Pg/g
77.9
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
149
200
Pg/g
74.5
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
156
200
Pg/g
78.1
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
146
200
Pg/g
72.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
163
200
Pg/g
81.3
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
165
200
Pg/g
82.7
(20%-186%)
37Cl-2,3,7,8-TCDD
18.2
20.0
Pg/g
91.1
(31 %-191%)
Comments:
Page 21 of 21
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 11.2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6202
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 06, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 30
problem solved
-------
Page:
Project #:
CFA Quote #:
CO^Number ',r:.
PO Number:
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number
of Custody an<
—f—/H —>*s——
; b io 2-
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Client Name, -fofr^ "£v^<
Phone #:
31V 5I76T9A
Sample Analysis Requested m (Fill in the number of containers for each test)
Woject/SiteName: -Tts'ce*#'
.Address: 2*0 ^
I|*>
<— Preservative Type (6)
Collected by: P' KiviipT^ Send Results To;
Sample ID
* For composites - indicate start and stop date/time
Field
Filtered m
Sample
Matrix w
Comments
Note: extra sample is
required for sample
specific QC
5 FA fir
11
i'Z- W
Ul~?
Wo
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed) _ i lulm ,
Time
Received by (signed)
Date
Time
CFA PM:
. ^4 ^
Method of Shipment:
SzK
Airbill #:
goy?. if?i p<
Airbill #:
1.) Chain of Custody Number= Client Determined
2.) QC Codes: M = Normal Sample, TB = Trip Blank, FD - Field Duplieate.EB « Equipment Blank, MS = Matrix Spike Sample,MSB = Matrix Spike Duplicate Sample,G = Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- ¥ - for yes the sample was field filtered or- N - for sample was not field filtered,
4.) Matrix Codes: DW=Drinking Water, GW«Groundwater, SW-Surface Water, WW-Wasie Water, W=Water, ML-Misc Liquid, SO=Soil, SD=Sediment, SL=Sludge, SS=Solid Waste, 0=0 il,F=Fi Iter, P-Wipe, U=Urtae, I^Fecal, N«Nasat
5.) Sample Analysis Requested: Analytical method requested (i.e£290B, 1668B) atid number of containers provided for each {i.e.8290B -3,1668B -1>,
6.) Preservative Type: HA = Hydrochloric Acid, NI - Nitric Acid, SH = Sodium Hydroxide, SA = Sulfuric Acid, AA ~ Ascorbic Acid, HX = Hexane, ST ~ Sodium Thiosulfate, If no preservative is added = leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
t Seal Intact?
NO
-------
SAMPLE RECEIPT CHECKLIST
C ape Ff or Anciylicol
Ym:
Clien
rf^rtfL
Work Order:
Shipp
ng Company:
Dale/Time Received:
0cl 4^
Susp
;cted Hazard Information
Ves
NA | No
Shipi^
ed as DOT Haicideui?
Samf
iles identified as Foreign Soil*'
DOE Site Sample Packages
Yes
NA
No*
Screened <0-5 rnR/hr?
Samples < 2x background?
ir-^
[Air S
3mple Receipt Specifics
Yes j NA
No
Air Witness
|Air s;
smple in shipment"?
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes NA No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received intact
and sealed?
coth Method'
Tct bags) blue ice csfy't* none other (describe}
Aqueous samples found to have visible
Solids?
Sample 10s, containers sHecteS:
Samples requiring chemical
preservation at proper pH?
Sample IDs, tcf>teir>en effected ar,d pK observed:
>f preservative edded, leu*:
Samples requiring preservation have
no residual chlorine?
Ssmple IDs. containers. eHecied:
tf preservative added, lot*:
Sample IOi. tests affected:
Samples received within holding time?
Sample IDs on COC match IDs on
containers?
Sample IDs. torilsin&fs effected:
Date & time of COC match date & time
on containers?
Sampte IDs. torrtsmeis sotted.
10
Number of containers received match
number indicated on COC?
A
Sarr.plp iDi, contjine"?
11
COC form is properly signed in
relinquished/received sections"
v/
/
Cofpmenls:
^ 7)&Jum4
-------
RE: CFATETR receipt 6-JUN-14
Subject: RE: CFA TETR receipt 6-JUN-14
From: Dave Kinroth
Date: 6/6/2014 1:20 PM
To: Cynde Larkins
Please go ahead and run these samples. Temperature is not an issue for us on any of
this material.
Thanks!
Dave
G. David Kinroth, CHMM
Regional Manager
EPA Reg. 7 START Haz. Waste Specialist
Seagull Environmental Technologies, Inc.
Woman-Owned8(a) Firm
Phone/Fax: (314) 395-3157
Mobile: (314) 517-6798
Emails: dkinrothPseaaullenviroteeh.com
davekinrothPcharter.net
On Frij Dun 6, 2014 at 11:06 AM, Cynde Larkins wrote:
Mr. Kinrothj
The samples arrived at CFA today in good condition but out of temperature. They were
at 9.4°C upon receipt. Our policy is to get your permission to proceed with analysis
with out of temperature samples.
Please advise.
Thank you.
Cynde Larkins
Project Manager Assistant
Cape Fear Analytical
3306 Kitty Hawk Road
Suite 120
Wilmington., NC 28405
(910) 795-0421
How was your customer experience? Customer service is a high priority for us, so we
listen to what our customers have to say! Thank you for taking time to email us your
thoughts and opinions at feeclbaekffef
CONFIDENTIALITY NOTICE: This e-mail and any files transmitted
with it are the property of Cape Fear Analytical, LLC. All
rights,including without limitation copyright,are reserved. The
proprietary information contained in this e-mail message,
and any files transmitted with it, is intended for the use of the
Page 4 of 30
1 of 2
6/6/2014 2:22 PM
-------
RE: CFATETR receipt 6-JUN-14
recipient(s) named above. If the reader of this e-mail is not the
intended recipient, you are hereby notified that you have
received this e-mail in error and that any review, distribution
or copying of this e-mail or any files transmitted with it is
strictly prohibited. If you have received this e-mail in error,
please notify the sender immediately and delete the original
message and any files transmitted. The unauthorized use of
this e-mail or any files transmitted with it is prohibited and
disclaimed by Cape Fear Analytical, LLC.
2 of 2
Page 5 of 30
6/6/2014 2:22 PM
-------
High Resolution Dioxins
and Furans Analysis
Page 6 of 30
-------
Case Narrative
Page 7 of 30
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6202
Method/Analysis Information
Product:
Analytical Method:
Extraction Method:
Dioxins/Furans by EPA Method 1613B in Solids
EPA Method 1613B
SW846 3540C
Analytical Batch Number: 26107
Clean Up Batch Number: 26106
Extraction Batch Number: 26105
Sample Analysis
The following samples were analyzed using the analytical protocol as established in Method
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Page 8 of 30
1613B:
Sample ID Client ID
6202001 SFRA-76
6202002 SFRA-77
6202003 SFRA-78
6202004 SFRA-79
6202005 SFRA-80
6202006 SFRA-81
12010610 Method Blank (MB)
12010611 Laboratory Control Sample (LCS)
12010612 Laboratory Control Sample Duplicate (LCSD)
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A matrix spike and matrix spike duplicate analysis was not required for this SDG.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A lg aliquot was used for extraction based on high concentrations of previous samples from this
site. Batch 26107.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 9 of 30
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 10 of 30
-------
Sample Data Summary
Page 11 of 30
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6202 CFA Work Order: 6202
Name: Heather Patterson
Date: 11JUN2014
Title: Data Validator
Page 12 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6202
Lab Sample ID: 6202001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/05/2014 12:30
06/06/2014 10:25
Project: TETR00114
Matrix: SOLID
%Moisture: 21.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-76
26107
06/09/2014 18:39
A09JUN14B-5
26105
06-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
l.ii g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
941
Pg/g
2.74 11.5
40321-76-4
1,2,3,7,8-PeCDD
U
2.65
Pg/g
2.65 57.6
39227-28-6
1,2,3,4,7,8-HxCDD
u
6.09
Pg/g
6.09 57.6
57653-85-7
1,2,3,6,7,8-HxCDD
u
12.5
Pg/g
12.5 57.6
19408-74-3
1,2,3,7,8,9-HxCDD
u
6.55
Pg/g
6.55 57.6
35822-46-9
1,2,3,4,6,7,8-HpCDD
172
Pg/g
18.7 57.6
3268-87-9
1,2,3,4,6,7,8,9-OCDD
17400
Pg/g
69.6 115
51207-31-9
2,3,7,8-TCDF
J
6.18
Pg/g
3.37 11.5
57117-41-6
1,2,3,7,8-PeCDF
u
2.26
Pg/g
2.26 57.6
57117-31-4
2,3,4,7,8-PeCDF
u
2.13
Pg/g
2.13 57.6
70648-26-9
1,2,3,4,7,8-HxCDF
u
3.02
Pg/g
3.02 57.6
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.95
Pg/g
2.95 57.6
60851-34-5
2,3,4,6,7,8-HxCDF
u
3.04
Pg/g
3.04 57.6
72918-21-9
1,2,3,7,8,9-HxCDF
u
5.1
Pg/g
5.10 57.6
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
31.0
Pg/g
3.41 57.6
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
5.6
Pg/g
5.60 57.6
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
58.1
Pg/g
11.5 115
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1900
2310
Pg/g
82.5
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2020
2310
Pg/g
87.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1560
2310
Pg/g
67.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1910
2310
Pg/g
83.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1860
2310
Pg/g
80.6
(23%-140%)
13C-OCDD
3670
4610
Pg/g
79.7
(17%-157%)
13C-2,3,7,8-TCDF
1970
2310
Pg/g
85.4
(24%-169%)
130-1,2,3,7,8-
PeCDF
2110
2310
Pg/g
91.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
2090
2310
Pg/g
90.5
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1610
2310
Pg/g
69.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1920
2310
Pg/g
83.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1810
2310
Pg/g
78.3
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1620
2310
Pg/g
70.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1910
2310
Pg/g
82.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1740
2310
Pg/g
75.5
(26%-13 8%)
3701-2,3,7,8-TCDD
212
231
Pg/g
91.8
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6202
Lab Sample ID: 6202002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/05/2014 12:35
06/06/2014 10:25
Project: TETR00114
Matrix: SOLID
%Moisture: 22.8
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-77
26107
06/09/2014 19:28
A09JUN14B-6
26105
06-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.07 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1020
Pg/g
3.78 12.1
40321-76-4
1,2,3,7,8-PeCDD
U
4.79
Pg/g
4.79 60.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
8.93
Pg/g
8.93 60.5
57653-85-7
1,2,3,6,7,8-HxCDD
J
28.9
Pg/g
8.37 60.5
19408-74-3
1,2,3,7,8,9-HxCDD
J
10.1
Pg/g
9.15 60.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
485
Pg/g
18.0 60.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
23800
Pg/g
64.1 121
51207-31-9
2,3,7,8-TCDF
J
10.0
Pg/g
3.00 12.1
57117-41-6
1,2,3,7,8-PeCDF
u
3.03
Pg/g
3.03 60.5
57117-31-4
2,3,4,7,8-PeCDF
u
2.98
Pg/g
2.98 60.5
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.44
Pg/g
3.80 60.5
57II7.44.9
1,2,3,6,7,8-HxCDF
J
4.96
Pg/g
3.61 60.5
60851-34-5
2,3,4,6,7,8-HxCDF
u
3.75
Pg/g
3.75 60.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
5.93
Pg/g
5.93 60.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
98.4
Pg/g
5.01 60.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
7.99
Pg/g
7.99 60.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
246
Pg/g
21.1 121
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1720
2420
Pg/g
71.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1910
2420
Pg/g
78.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1580
2420
Pg/g
65.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1800
2420
Pg/g
74.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1960
2420
Pg/g
81.1
(23%-140%)
13C-OCDD
4040
4840
Pg/g
83.5
(17%-157%)
13C-2,3,7,8-TCDF
1840
2420
Pg/g
76.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
1940
2420
Pg/g
80.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1890
2420
Pg/g
78.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1620
2420
Pg/g
67.0
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1780
2420
Pg/g
73.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1710
2420
Pg/g
70.5
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1560
2420
Pg/g
64.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1810
2420
Pg/g
75.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1800
2420
Pg/g
74.2
(26%-13 8%)
3701-2,3,7,8-TCDD
224
242
Pg/g
92.7
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6202
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6202003
Date Collected:
06/05/2014 12:40
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
06/06/2014 10:25
%Moisture: 22.8
Client ID:
SFRA-78
Prep Basis: Dry Weight
Batch ID:
26107
Method:
EPA Method 1613B
Run Date:
06/09/2014 20:16
Analyst:
JTF
Instrument: HRP750
Data File:
A09JUN14B-7
Dilution: 1
Prep Batch:
26105
Prep Method:
SW846 3540C
Prep Date:
06-JUN-14
Prep Aliquot:
1.66 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2430
Pg/g
2.48 7.81
40321-76-4
1,2,3,7,8-PeCDD
J
3.90
Pg/g
2.86 39.0
39227-28-6
1,2,3,4,7,8-HxCDD
QU
9.23
Pg/g
9.23 39.0
57653-85-7
1,2,3,6,7,8-HxCDD
Q
124
Pg/g
9.96 39.0
19408-74-3
1,2,3,7,8,9-HxCDD
J
36.7
Pg/g
10.2 39.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
821
Pg/g
7.34 39.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8100
Pg/g
31.1 78.1
51207-31-9
2,3,7,8-TCDF
14.7
Pg/g
2.69 7.81
57117-41-6
1,2,3,7,8-PeCDF
J
2.45
Pg/g
1.37 39.0
57117-31-4
2,3,4,7,8-PeCDF
J
5.93
Pg/g
1.36 39.0
70648-26-9
1,2,3,4,7,8-HxCDF
J
8.82
Pg/g
3.97 39.0
57II7.44.9
1,2,3,6,7,8-HxCDF
J
5.78
Pg/g
4.20 39.0
60851-34-5
2,3,4,6,7,8-HxCDF
J
13.0
Pg/g
3.68 39.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
5.4
Pg/g
5.40 39.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
194
Pg/g
3.36 39.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
13.0
Pg/g
5.81 39.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
353
Pg/g
13.7 78.1
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1210
1560
Pg/g
77.8
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1290
1560
Pg/g
82.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1020
1560
Pg/g
65.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 823
1560
Pg/g
52.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1610
1560
Pg/g
103
(23%-140%)
13C-OCDD
3300
3120
Pg/g
106
(17%-157%)
13C-2,3,7,8-TCDF
1270
1560
Pg/g
81.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1290
1560
Pg/g
82.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1300
1560
Pg/g
83.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1170
1560
Pg/g
74.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1190
1560
Pg/g
76.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1240
1560
Pg/g
79.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1070
1560
Pg/g
68.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1400
1560
Pg/g
89.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1470
1560
Pg/g
94.0
(26%-13 8%)
3701-2,3,7,8-TCDD
146
156
Pg/g
93.3
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 30
-------
Cape Fear Analytical LLC
Report Date: June 11,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6202
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6202003
Date Collected:
06/05/2014 12:40
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/06/2014 10:25
%Moisture:
22.8
Client ID:
SFRA-78
Prep Basis:
Dry Weight
Batch ID:
26107
Method:
EPA Method 1613B
Run Date:
06/10/2014 12:00
Analyst:
JTF
Instrument:
HRP763
Data File:
bl0junl4b-4
Dilution:
1
Prep Batch:
26105
Prep Method:
SW846 3540C
Prep Date:
06-JUN-14
Prep Aliquot:
1.66 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
14.3
Pg/g
3.22
7.81
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6202
Lab Sample ID: 6202004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/05/2014 14:35
06/06/2014 10:25
Project: TETR00114
Matrix: SOLID
%Moisture: 20
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-79
26107
06/09/2014 21:04
A09JUN14B-8
26105
06-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.13 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1500
Pg/g
3.18 11.1
40321-76-4
1,2,3,7,8-PeCDD
U
4.09
Pg/g
4.09 55.3
39227-28-6
1,2,3,4,7,8-HxCDD
QU
11.7
Pg/g
11.7 55.3
57653-85-7
1,2,3,6,7,8-HxCDD
Q
69.8
Pg/g
13.9 55.3
19408-74-3
1,2,3,7,8,9-HxCDD
J
16.8
Pg/g
13.6 55.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
449
Pg/g
10.8 55.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5060
Pg/g
31.8 111
51207-31-9
2,3,7,8-TCDF
J
9.31
Pg/g
3.78 11.1
57117-41-6
1,2,3,7,8-PeCDF
u
4.2
Pg/g
4.20 55.3
57117-31-4
2,3,4,7,8-PeCDF
u
4.09
Pg/g
4.09 55.3
70648-26-9
1,2,3,4,7,8-HxCDF
u
5.28
Pg/g
5.28 55.3
57II7.44.9
1,2,3,6,7,8-HxCDF
u
4.93
Pg/g
4.93 55.3
60851-34-5
2,3,4,6,7,8-HxCDF
u
4.84
Pg/g
4.84 55.3
72918-21-9
1,2,3,7,8,9-HxCDF
u
5.17
Pg/g
5.17 55.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
105
Pg/g
3.23 55.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
7.54
Pg/g
5.66 55.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
145
Pg/g
12.2 111
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1850
2210
Pg/g
83.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1900
2210
Pg/g
86.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1800
2210
Pg/g
81.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1520
2210
Pg/g
68.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2280
2210
Pg/g
103
(23%-140%)
13C-OCDD
4570
4420
Pg/g
103
(17%-157%)
13C-2,3,7,8-TCDF
1930
2210
Pg/g
87.4
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1860
2210
Pg/g
84.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1910
2210
Pg/g
86.5
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1770
2210
Pg/g
80.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1690
2210
Pg/g
76.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2210
Pg/g
86.3
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1740
2210
Pg/g
78.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2050
2210
Pg/g
92.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1970
2210
Pg/g
89.1
(26%-13 8%)
3701-2,3,7,8-TCDD
213
221
Pg/g
96.3
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6202
Lab Sample ID: 6202005
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/05/2014 14:47
06/06/2014 10:25
Project: TETR00114
Matrix: SOLID
%Moisture: 22.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-80
26107
06/09/2014 21:52
A09JUN14B-9
26105
06-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.09 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
745
Pg/g
3.19 11.9
40321-76-4
1,2,3,7,8-PeCDD
U
3.45
Pg/g
3.45 59.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
7.73
Pg/g
7.73 59.5
57653-85-7
1,2,3,6,7,8-HxCDD
J
28.4
Pg/g
7.78 59.5
19408-74-3
1,2,3,7,8,9-HxCDD
u
8.23
Pg/g
8.23 59.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
391
Pg/g
10.8 59.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8240
Pg/g
44.3 119
51207-31-9
2,3,7,8-TCDF
J
4.21
Pg/g
3.26 11.9
57117-41-6
1,2,3,7,8-PeCDF
u
2.69
Pg/g
2.69 59.5
57117-31-4
2,3,4,7,8-PeCDF
u
2.55
Pg/g
2.55 59.5
70648-26-9
1,2,3,4,7,8-HxCDF
u
4.31
Pg/g
4.31 59.5
57II7.44.9
1,2,3,6,7,8-HxCDF
u
3.81
Pg/g
3.81 59.5
60851-34-5
2,3,4,6,7,8-HxCDF
u
4.55
Pg/g
4.55 59.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
6.38
Pg/g
6.38 59.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
97.9
Pg/g
4.16 59.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
7.26
Pg/g
7.26 59.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
189
Pg/g
16.3 119
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1890
2380
Pg/g
79.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1980
2380
Pg/g
83.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1890
2380
Pg/g
79.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1970
2380
Pg/g
82.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2310
2380
Pg/g
97.1
(23%-140%)
13C-OCDD
4310
4760
Pg/g
90.6
(17%-157%)
13C-2,3,7,8-TCDF
1920
2380
Pg/g
80.9
(24%-169%)
130-1,2,3,7,8-
PeCDF
1910
2380
Pg/g
80.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1970
2380
Pg/g
82.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1880
2380
Pg/g
78.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1910
2380
Pg/g
80.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1940
2380
Pg/g
81.7
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1740
2380
Pg/g
73.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2080
2380
Pg/g
87.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1980
2380
Pg/g
83.0
(26%-13 8%)
3701-2,3,7,8-TCDD
223
238
Pg/g
93.7
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 18 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6202
Lab Sample ID: 6202006
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/05/2014 15:50
06/06/2014 10:25
Project: TETR00114
Matrix: SOLID
%Moisture: 22.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-81
26107
06/09/2014 22:40
A09JUN14B-10
26105
06-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.52 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
240
Pg/g
1.40 8.48
40321-76-4
1,2,3,7,8-PeCDD
U
1.76
Pg/g
1.76 42.4
39227-28-6
1,2,3,4,7,8-HxCDD
QU
4.12
Pg/g
4.12 42.4
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
13.2
Pg/g
4.12 42.4
19408-74-3
1,2,3,7,8,9-HxCDD
U
4.37
Pg/g
4.37 42.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
145
Pg/g
5.92 42.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7740
Pg/g
21.0 84.8
51207-31-9
2,3,7,8-TCDF
J
5.17
Pg/g
2.20 8.48
57117-41-6
1,2,3,7,8-PeCDF
J
3.80
Pg/g
1.08 42.4
57117-31-4
2,3,4,7,8-PeCDF
u
1.09
Pg/g
1.09 42.4
70648-26-9
1,2,3,4,7,8-HxCDF
J
4.64
Pg/g
1.88 42.4
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.93
Pg/g
1.93 42.4
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.02
Pg/g
2.02 42.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.03
Pg/g
3.03 42.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
33.9
Pg/g
1.73 42.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
3
Pg/g
3.00 42.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
55.1
Pg/g
7.78 84.8
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1340
1700
Pg/g
79.3
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1480
1700
Pg/g
87.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1190
1700
Pg/g
70.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1260
1700
Pg/g
74.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1460
1700
Pg/g
86.0
(23%-140%)
13C-OCDD
2940
3390
Pg/g
86.7
(17%-157%)
13C-2,3,7,8-TCDF
1340
1700
Pg/g
79.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1480
1700
Pg/g
87.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
1470
1700
Pg/g
86.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1210
1700
Pg/g
71.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1270
1700
Pg/g
74.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1260
1700
Pg/g
74.5
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1190
1700
Pg/g
70.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1340
1700
Pg/g
79.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1340
1700
Pg/g
79.2
(26%-13 8%)
3701-2,3,7,8-TCDD
152
170
Pg/g
89.8
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 30
-------
Quality Control
Summary
Page 20 of 30
-------
( ape Fear \lltllytictll LLC Report Date: June 11, 2014
Hi-Res Dioxins/Furans Page 1 of 4
Surrogate Recovery Report
SDG Number: 6202
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010611
LCS for batch 26105
12010612
LCSD for batch 26105
12010610
MB for batch 26105
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
84.7
87.3
75.2
96.2
86.4
75.5
90.6
94.9
91.1
80.1
95.1
86.0
73.2
93.0
79.2
96.7
65.8
64.1
63.3
78.5
62.9
55.0
76.7
70.9
68.0
66.1
80.4
72.3
61.0
68.6
58.5
86.0
76.0
84.5
67.1
89.2
72.7
62.0
85.9
93.2
88.7
72.2
86.5
78.6
67.4
78.4
65.8
86.9
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6202001
SFRA-76
13C-2,3,7,8-TCDD
82.5
(25%-164%)
Page 21 of 30
-------
( ape Fear \lltllytictll LLC Report Date: June 11, 2014
Hi-Res Dioxins/Furans Page 2 of 4
Surrogate Recovery Report
SDG Number: 6202
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6202001
SFRA-76
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
87.6
67.8
83.0
80.6
79.7
85.4
91.6
90.5
69.6
83.2
78.3
70.3
82.9
75.5
91.8
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6202002
SFRA-77
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
71.0
78.7
65.3
74.2
81.1
83.5
76.2
80.2
78.1
67.0
73.7
70.5
64.3
75.0
74.2
92.7
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6202003
SFRA-78
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
77.8
82.5
65.5
52.7
103
106
81.2
82.6
83.1
74.8
76.3
79.6
68.2
89.5
94.0
93.3
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6202004
SFRA-79
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
83.6
86.0
(25%-
(25%-
64%)
81%)
Page 22 of 30
-------
( ape Fear \lltllytictll LLC Report Date: June 11, 2014
Hi-Res Dioxins/Furans Page 3 of 4
Surrogate Recovery Report
SDG Number: 6202
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6202004
SFRA-79
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
81.3
68.7
103
103
87.4
84.3
86.5
80.2
76.5
86.3
78.7
92.8
89.1
96.3
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6202005
SFRA-80
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
79.3
83.4
79.5
82.7
97.1
90.6
80.9
80.2
82.9
78.9
80.2
81.7
73.3
87.3
83.0
93.7
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6202006
SFRA-81
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
79.3
87.3
70.2
74.2
86.0
86.7
79.2
87.1
86.7
71.2
74.9
74.5
70.2
79.0
79.2
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
Page 23 of 30
-------
Cape Fear Analytical LLC
Report Date: June 11, 2014
SDG Number: 6202
Matrix Type: SOLID
Hi-Res Dioxins/Furans
Surrogate Recovery Report
Page 4
of 4
Sample ID Client ID
Surrogate
QUAL
Recovery Acceptance
(%)
Limits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 24 of 30
-------
Cape Fear Analytical LLC
Report Date: June 11, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/09/2014 16:16 Dilution: 1
Prep Batch ID:26105
Batch ID: 26107
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.6
103
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
102
102
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
100
100
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
101
101
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
95.0
95
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
96.2
96.2
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
210
105
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.4
91.9
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
94.1
94.1
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
97.4
97.4
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
96.6
96.6
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
97.7
97.7
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
99.6
99.6
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
102
102
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
91.8
91.8
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
96.7
96.7
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
194
97
63-170
SDG Number: 6202
Client ID: LCS for batch 26105
Lab Sample ID: 12010611
Instrument: HRP750
Analyst: JTF
Page 25 of 30
-------
Cape Fear Analytical LLC
Report Date: June 11, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/09/2014 17:03 Dilution: 1
Prep Batch ID:26105
Batch ID: 26107
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.9
105
67-158
1.56
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
104
104
70-142
1.62
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
98.2
98.2
70-164
1.86
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
107
107
76-134
5.20
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
105
105
64-162
9.71
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
95.7
95.7
70-140
0.479
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
208
104
78-144
0.997
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.7
93.4
75-158
1.65
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
95.5
95.5
80-134
1.43
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
98.3
98.3
68-160
0.881
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
103
103
72-134
5.97
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
98.4
98.4
84-130
0.744
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
99.8
99.8
70-156
0.225
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
107
107
78-130
4.83
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
98.3
98.3
82-122
6.86
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
101
101
78-138
4.80
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
211
106
63-170
8.38
0-20
SDG Number: 6202
Client ID: LCSD for batch 26105
Lab Sample ID: 12010612
Instrument: HRP750
Analyst: JTF
Page
26 of 30
-------
Cape Fear Analytical LLC
Report Date: June 11,2014
Method Blank Summary Page ' °' '
SDG Number:
6202
Client:
TETR001
Matrix:
SOLID
Client ID:
MB for batch 26105
Instrument ID:
HRP750
Data File:
A09JUN14B-4
Lab Sample ID:
Column:
12010610
Prep Date:
06-JUN-14
Analyzed:
06/09/14 17:51
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 26105
12010611
A09JUN14B-2
06/09/14
1616
02 LCSD for batch 26105
12010612
A09JUN14B-3
06/09/14
1703
03 SFRA-76
6202001
A09JUN14B-5
06/09/14
1839
04 SFRA-77
6202002
A09JUN14B-6
06/09/14
1928
05 SFRA-78
6202003
A09JUN14B-7
06/09/14
2016
06 SFRA-79
6202004
A09JUN14B-8
06/09/14
2104
07 SFRA-80
6202005
A09JUN14B-9
06/09/14
2152
08 SFRA-81
6202006
A09JUN14B-10
06/09/14
2240
09 SFRA-78
6202003
bl0junl4b-4
06/10/14
1200
Page 27 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6202
Lab Sample ID: 12010610
Client Sample: ^or batch 26105
Client ID: MB for batch 26105
Batch ID: 26107
Run Date: 06/09/2014 17:51
Data File: A09JUN14B-4
Prep Batch: 26105
Prep Date: 06-JUN-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.15
Pg/g
0.150 1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.284
Pg/g
0.180 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.338
Pg/g
0.338 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.342
Pg/g
0.342 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.36
Pg/g
0.360 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.684
Pg/g
0.684 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
1.41
Pg/g
0.832 10.0
51207-31-9
2,3,7,8-TCDF
u
.162
Pg/g
0.162 1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.226
Pg/g
0.171 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.165
Pg/g
0.165 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.298
Pg/g
0.298 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.304
Pg/g
0.304 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.342
Pg/g
0.342 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.556
Pg/g
0.556 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.26
Pg/g
0.260 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.392
Pg/g
0.392 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.866
Pg/g
0.866 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
152
200
Pg/g
76.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
169
200
Pg/g
84.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
134
200
Pg/g
67.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
178
200
Pg/g
89.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
145
200
Pg/g
72.7
(23%-140%)
13C-OCDD
248
400
Pg/g
62.0
(17%-157%)
13C-2,3,7,8-TCDF
172
200
Pg/g
85.9
(24%-169%)
130-1,2,3,7,8-
PeCDF
186
200
Pg/g
93.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
177
200
Pg/g
88.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
144
200
Pg/g
72.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
173
200
Pg/g
86.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
157
200
Pg/g
78.6
(28%-136%)
130-1,2,3,7,8,9-HxCDF
135
200
Pg/g
67.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
157
200
Pg/g
78.4
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
132
200
Pg/g
65.8
(26%-13 8%)
3701-2,3,7,8-TCDD
17.4
20.0
Pg/g
86.9
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 28 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6202
Lab Sample ID: 12010611
Client Sample: ^or batch 26105
Client ID: LCS for batch 26105
Batch ID: 26107
Run Date: 06/09/2014 16:16
Data File: A09JUN14B-2
Prep Batch: 26105
Prep Date: 06-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.6
Pg/g
0.246 1.00
40321-76-4
1,2,3,7,8-PeCDD
102
Pg/g
0.664 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
100
Pg/g
1.26 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
101
Pg/g
1.28 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
95.0
Pg/g
1.34 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
96.2
Pg/g
1.78 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
210
Pg/g
4.36 10.0
51207-31-9
2,3,7,8-TCDF
18.4
Pg/g
0.274 1.00
57117-41-6
1,2,3,7,8-PeCDF
94.1
Pg/g
0.554 5.00
57117-31-4
2,3,4,7,8-PeCDF
97.4
Pg/g
0.554 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
96.6
Pg/g
1.48 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
97.7
Pg/g
1.41 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
99.6
Pg/g
1.48 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
102
Pg/g
2.50 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
91.8
Pg/g
1.24 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
96.7
Pg/g
2.26 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
194
Pg/g
3.10 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
169
200
Pg/g
84.7
(20%-175%)
13C-1,2,3,7,8-
PeCDD
175
200
Pg/g
87.3
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
150
200
Pg/g
75.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
192
200
Pg/g
96.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
173
200
Pg/g
86.4
(22%-166%)
13C-OCDD
302
400
Pg/g
75.5
(13%-199%)
13C-2,3,7,8-TCDF
181
200
Pg/g
90.6
(22%-152%)
13C-1,2,3,7,8-
PeCDF
190
200
Pg/g
94.9
(21%-192%)
130-2,3,4,7,8-
PeCDF
182
200
Pg/g
91.1
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
160
200
Pg/g
80.1
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
190
200
Pg/g
95.1
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
172
200
Pg/g
86.0
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
146
200
Pg/g
73.2
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
186
200
Pg/g
93.0
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
158
200
Pg/g
79.2
(20%-186%)
3701-2,3,7,8-TCDD
19.3
20.0
Pg/g
96.7
(31 %-191%)
Comments:
Page 29 of 30
-------
Cape Fear Analytical LLC
Report Date:
June 11,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6202
12010612
QC for batch 26105
LCSD for batch 26105
26107
06/09/2014 17:03
A09JUN14B-3
26105
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
06-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.9
Pg/g
0.282
1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.886
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.2
Pg/g
1.32
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
107
Pg/g
1.24
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
105
Pg/g
1.35
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.7
Pg/g
1.97
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
208
Pg/g
4.38
10.0
51207-31-9
2,3,7,8-TCDF
18.7
Pg/g
0.226
1.00
57117-41-6
1,2,3,7,8-PeCDF
95.5
Pg/g
0.850
5.00
57117-31-4
2,3,4,7,8-PeCDF
98.3
Pg/g
0.826
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
103
Pg/g
1.60
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
98.4
Pg/g
1.45
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
99.8
Pg/g
1.60
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
107
Pg/g
2.58
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
98.3
Pg/g
1.71
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
101
Pg/g
3.16
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
211
Pg/g
3.08
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
132
200
Pg/g
65.8
(20%-175%)
13C-1,2,3,7,8-PeCDD
128
200
Pg/g
64.1
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
127
200
Pg/g
63.3
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
157
200
Pg/g
78.5
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
126
200
Pg/g
62.9
(22%-166%)
13C-OCDD
220
400
Pg/g
55.0
(13%-199%)
13C-2,3,7,8-TCDF
153
200
Pg/g
76.7
(22%-152%)
13C-1,2,3,7,8-PeCDF
142
200
Pg/g
70.9
(21%-192%)
13C-2,3,4,7,8-PeCDF
136
200
Pg/g
68.0
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
132
200
Pg/g
66.1
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
161
200
Pg/g
80.4
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
145
200
Pg/g
72.3
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
122
200
Pg/g
61.0
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
137
200
Pg/g
68.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
117
200
Pg/g
58.5
(20%-186%)
37Cl-2,3,7,8-TCDD
17.2
20.0
Pg/g
86.0
(31 %-191%)
Comments:
Page 30 of 30
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 16. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6222
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 09, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 36
problem solved
-------
Project #:
CPA Quote#: _
COC Number'":.
PO Number:
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: LI 1
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone:(910)795-0421
Client Name:
p
ac
a
Phone #:
3IHsnc$R
Project/Site Name: SWfef 1 ASM»\ .
l^ J"Fhswi fkisJl—
oC.ltattlby: p| Kittfe4L-
Sample ID
* Far composites - indicate start and stop date/time
•Date Collected
(mm-dd-yy)
~Time
Collected
(Military)
(hhmm)
QCCode
m
Field
Filtered,Jl
Sample
Matrixf4>
*5
Sample Analysis Requested(s' (Fill in the number of containers for each test)
ift
«5
Ci
vsl
<- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
WEhm.1% I II I 1 < ¦ I
fbi>2>
x
Mi
ML
t&8
11(0
V
v
EVP
tmr
TAT Requested: Normal:
Rush:
sPeci
-------
SAMPLE RECEIPT CHECKLIST
Cope Feor Anolyticoi
o,m, -jr- a
|work Order:
Is)J] s
Shipping Company:
Date/Time Received
[QIO
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
u
Samples identified as foreign Soil7
DOE Site Sample Packages (Yes
IMA
No*
Screened <0.5 mR/hr? |
Samples < 2x background? j
Air Sample Receipt Specifics
[ Yes | NA No
Air sample in shipment?
* Notify RSO of any responses in this column immediately-
Air Witness:
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
U*"
CticSe Applicable:
&ea!s b*c^e»> e'airtggtdcontainer liking fpnieinc'i oti-if-r(dFibej
2
Chain of Custody documents included
with shipment?
cx
3
Samples requiring cold preservation
within 0-6"C?
IvCsefvarton Method'
See bags /blsjc ic£ dr.- ite tNcif hti (describe)
Stf'O
4
Aqueous samples found to have visible
solids?
Ssmplf !Os, containers affected:
5
Samples requiring chemical
preservation at proper pH?
Sample IDs, tonteiners effected snd pH observed:
H pfeservelive added. Lotft;
6
Samples requiring preservation have
no residual chlorine?
SgrrvpU? IDs, contsineis effected:
if preservative added, lotfi:
7
Samples received within holding time?
Sample tDs, tests affected:
8
Sample IDs on COC match IDs on
containers?
/
Safnple IDs, containers Ejected:
9
Date & time of COC match date & time
on containers?
/
Sempie tDs, containers stfected:
10
Number of containers received match
number indicated on COC?
u
s
Sample iDi. cont2ine?< effected'
11
COC form is properly signed in
relinquished/received sections?
w
/
Comments:
Checklist performed by: Initials:
Page 3 of 36
Date
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 36
-------
Case Narrative
Page 5 of 36
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6222
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26124
Clean Up Batch Number: 26123
Extraction Batch Number: 26122
Sample Analysis
The following samples were analyzed using the analytical protocol as established in :
Sample ID Client ID
6222001 SFRA-82
6222002 SFRA-83
6222003 SFRA-84
6222004 SFRA-85
6222005 SFRA-86
6222006 SFRA-87
6222007 SFRA-88
6222008 SFRA-89
12010628 Method Blank (MB)
12010629 Laboratory Control Sample (LCS)
12010630 Laboratory Control Sample Duplicate (LCSD)
12010631 6222001 (SFRA-82) Matrix Spike (MS)
12010632 6222001 (SFRA-82) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Page 6 of 36
-------
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6222001 (SFRA-82)- Batch 26124 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
One MS recovery was above the acceptance limits due to matrix interference. 12010631 (SFRA-
82)-Batch 26124.
Matrix Spike Duplicate (MSD) Recovery Statement
Two MSD recoveries for this SDG were above the acceptance limits due to matrix interference.
12010632 (SFRA-82) - Batch 26124.
MS/MSD Relative Percent Difference (RPD) Statement
One relative percent difference (RPD) between each MS and MSD was not within the required
acceptance limits. 12010631 (SFRA-82) and 12010632 (SFRA-82) - Batch 26124.
Page 7 of 36
-------
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26124.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
The following NCR was generated for this SDG: 644563 12010632 (SFRA-82)- Batch 26124.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 36
-------
Sample Data Summary
Page 9 of 36
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6222 CFA Work Order: 6222
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 16JUN2014 Title: Data Validator
Page 10 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 16:28
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 24.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-82
26124
06/11/2014 21:07
blljunl4b_2-4
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.12 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
677
Pg/g
3.46 11.8
40321-76-4
1,2,3,7,8-PeCDD
J
5.12
Pg/g
3.41 59.2
39227-28-6
1,2,3,4,7,8-HxCDD
U
5.43
Pg/g
5.43 59.2
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
38.4
Pg/g
4.15 59.2
19408-74-3
1,2,3,7,8,9-HxCDD
J
15.0
Pg/g
3.93 59.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
377
Pg/g
5.54 59.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
15100
Pg/g
10.8 118
51207-31-9
2,3,7,8-TCDF
J
9.19
Pg/g
3.01 11.8
57117-41-6
1,2,3,7,8-PeCDF
J
11.2
Pg/g
2.22 59.2
57117-31-4
2,3,4,7,8-PeCDF
U
5.95
Pg/g
5.95 59.2
70648-26-9
1,2,3,4,7,8-HxCDF
J
15.3
Pg/g
1.90 59.2
57II7.44.9
1,2,3,6,7,8-HxCDF
J
8.06
Pg/g
1.85 59.2
60851-34-5
2,3,4,6,7,8-HxCDF
J
6.92
Pg/g
1.93 59.2
72918-21-9
1,2,3,7,8,9-HxCDF
J
6.97
Pg/g
2.72 59.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
86.6
Pg/g
2.29 59.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
12.3
Pg/g
3.89 59.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
200
Pg/g
5.00 118
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1960
2370
Pg/g
82.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2070
2370
Pg/g
87.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1980
2370
Pg/g
83.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1630
2370
Pg/g
69.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2230
2370
Pg/g
94.2
(23%-140%)
13C-OCDD
4380
4740
Pg/g
92.5
(17%-157%)
13C-2,3,7,8-TCDF
2180
2370
Pg/g
92.0
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2080
2370
Pg/g
87.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
2170
2370
Pg/g
91.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2030
2370
Pg/g
85.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1970
2370
Pg/g
83.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2040
2370
Pg/g
86.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2030
2370
Pg/g
85.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2080
2370
Pg/g
88.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2160
2370
Pg/g
91.2
(26%-13 8%)
3701-2,3,7,8-TCDD
239
237
Pg/g
101
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 16:35
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 19.1
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-83
26124
06/11/2014 21:54
blljunl4b_2-5
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.08 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
887
Pg/g
2.84 11.5
40321-76-4
1,2,3,7,8-PeCDD
J
4.67
Pg/g
2.19 57.3
39227-28-6
1,2,3,4,7,8-HxCDD
J
4.08
Pg/g
3.98 57.3
57653-85-7
1,2,3,6,7,8-HxCDD
Q
57.7
Pg/g
5.82 57.3
19408-74-3
1,2,3,7,8,9-HxCDD
J
24.1
Pg/g
5.11 57.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
502
Pg/g
6.02 57.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11900
Pg/g
8.18 115
51207-31-9
2,3,7,8-TCDF
J
6.11
Pg/g
3.27 11.5
57117-41-6
1,2,3,7,8-PeCDF
J
4.01
Pg/g
1.84 57.3
57117-31-4
2,3,4,7,8-PeCDF
J
3.07
Pg/g
1.83 57.3
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.69
Pg/g
2.04 57.3
57II7.44.9
1,2,3,6,7,8-HxCDF
J
5.38
Pg/g
2.06 57.3
60851-34-5
2,3,4,6,7,8-HxCDF
J
7.15
Pg/g
2.09 57.3
72918-21-9
1,2,3,7,8,9-HxCDF
J
4.74
Pg/g
3.25 57.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
123
Pg/g
2.17 57.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
10.4
Pg/g
4.35 57.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
220
Pg/g
4.40 115
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2010
2290
Pg/g
87.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2080
2290
Pg/g
90.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1940
2290
Pg/g
84.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1310
2290
Pg/g
57.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2260
2290
Pg/g
98.9
(23%-140%)
13C-OCDD
4390
4580
Pg/g
95.9
(17%-157%)
13C-2,3,7,8-TCDF
2160
2290
Pg/g
94.4
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2050
2290
Pg/g
89.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
2170
2290
Pg/g
94.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2010
2290
Pg/g
87.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1860
2290
Pg/g
81.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1990
2290
Pg/g
86.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1960
2290
Pg/g
85.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2060
2290
Pg/g
90.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2170
2290
Pg/g
94.8
(26%-13 8%)
3701-2,3,7,8-TCDD
245
229
Pg/g
107
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
Page 12 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 16:39
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 22
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-84
26124
06/11/2014 22:42
blljunl4b_2-6
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.09 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
421
Pg/g
3.01 11.8
40321-76-4
1,2,3,7,8-PeCDD
J
3.81
Pg/g
2.14 58.8
39227-28-6
1,2,3,4,7,8-HxCDD
U
6.11
Pg/g
6.11 58.8
57653-85-7
1,2,3,6,7,8-HxCDD
J
24.4
Pg/g
6.77 58.8
19408-74-3
1,2,3,7,8,9-HxCDD
J
11.6
Pg/g
6.87 58.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
400
Pg/g
6.35 58.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12400
Pg/g
10.7 118
51207-31-9
2,3,7,8-TCDF
17.2
Pg/g
4.21 11.8
57117-41-6
1,2,3,7,8-PeCDF
J
17.9
Pg/g
1.92 58.8
57117-31-4
2,3,4,7,8-PeCDF
J
6.70
Pg/g
1.79 58.8
70648-26-9
1,2,3,4,7,8-HxCDF
J
24.7
Pg/g
2.33 58.8
57II7.44.9
1,2,3,6,7,8-HxCDF
u
7.88
Pg/g
7.88 58.8
60851-34-5
2,3,4,6,7,8-HxCDF
J
6.87
Pg/g
2.54 58.8
72918-21-9
1,2,3,7,8,9-HxCDF
u
8.98
Pg/g
8.98 58.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
86.3
Pg/g
2.17 58.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
16.0
Pg/g
3.67 58.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
183
Pg/g
8.04 118
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1990
2350
Pg/g
84.5
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2140
2350
Pg/g
91.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1960
2350
Pg/g
83.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1780
2350
Pg/g
75.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2190
2350
Pg/g
93.1
(23%-140%)
13C-OCDD
4220
4700
Pg/g
89.7
(17%-157%)
13C-2,3,7,8-TCDF
2140
2350
Pg/g
90.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
2100
2350
Pg/g
89.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
2200
2350
Pg/g
93.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2100
2350
Pg/g
89.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1890
2350
Pg/g
80.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2010
2350
Pg/g
85.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1930
2350
Pg/g
82.1
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2040
2350
Pg/g
86.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2090
2350
Pg/g
88.8
(26%-13 8%)
3701-2,3,7,8-TCDD
240
235
Pg/g
102
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 36
-------
Cape Fear Analytical LLC
Report Date: June 16,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6222
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6222003
Date Collected:
06/06/2014 16:39
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/09/2014 10:20
%Moisture:
22
Client ID:
SFRA-84
Prep Basis:
Dry Weight
Batch ID:
26124
Method:
EPA Method 1613B
Run Date:
06/12/2014 13:02
Analyst:
JTF
Instrument:
HRP763
Data File:
bl2junl4a-5
Dilution:
1
Prep Batch:
26122
Prep Method:
SW846 3540C
Prep Date:
10-JUN-14
Prep Aliquot:
1.09 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
16.1
Pg/g
7.74
11.8
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 17:27
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 26.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-85
26124
06/11/2014 23:30
blljunl4b_2-7
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.16 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1250
Pg/g
3.14 11.7
40321-76-4
1,2,3,7,8-PeCDD
U
3.94
Pg/g
3.94 58.6
39227-28-6
1,2,3,4,7,8-HxCDD
u
6.56
Pg/g
6.56 58.6
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
56.2
Pg/g
13.1 58.6
19408-74-3
1,2,3,7,8,9-HxCDD
J
21.6
Pg/g
9.23 58.6
35822-46-9
1,2,3,4,6,7,8-HpCDD
465
Pg/g
6.02 58.6
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11500
Pg/g
6.82 117
51207-31-9
2,3,7,8-TCDF
13.6
Pg/g
3.40 11.7
57117-41-6
1,2,3,7,8-PeCDF
J
5.95
Pg/g
1.51 58.6
57117-31-4
2,3,4,7,8-PeCDF
U
5.32
Pg/g
5.32 58.6
70648-26-9
1,2,3,4,7,8-HxCDF
J
9.56
Pg/g
1.73 58.6
57II7.44.9
1,2,3,6,7,8-HxCDF
u
5.97
Pg/g
5.97 58.6
60851-34-5
2,3,4,6,7,8-HxCDF
J
6.61
Pg/g
1.71 58.6
72918-21-9
1,2,3,7,8,9-HxCDF
J
4.66
Pg/g
2.69 58.6
67562-39-4
1,2,3,4,6,7,8-HpCDF
104
Pg/g
1.61 58.6
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
8.97
Pg/g
3.77 58.6
39001-02-0
1,2,3,4,6,7,8,9-OCDF
194
Pg/g
4.05 117
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2080
2340
Pg/g
88.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2160
2340
Pg/g
92.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2190
2340
Pg/g
93.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 832
2340
Pg/g
35.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2410
2340
Pg/g
103
(23%-140%)
13C-OCDD
4600
4690
Pg/g
98.1
(17%-157%)
13C-2,3,7,8-TCDF
2190
2340
Pg/g
93.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2100
2340
Pg/g
89.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
2230
2340
Pg/g
95.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2090
2340
Pg/g
89.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1950
2340
Pg/g
83.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2090
2340
Pg/g
89.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2030
2340
Pg/g
86.5
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2150
2340
Pg/g
91.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2290
2340
Pg/g
97.9
(26%-13 8%)
3701-2,3,7,8-TCDD
248
234
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 36
-------
Cape Fear Analytical LLC
Report Date: June 16,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6222
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6222004
Date Collected:
06/06/2014 17:27
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/09/2014 10:20
%Moisture:
26.4
Client ID:
SFRA-85
Prep Basis:
Dry Weight
Batch ID:
26124
Method:
EPA Method 1613B
Run Date:
06/12/2014 13:22
Analyst:
JTF
Instrument:
HRP763
Data File:
bl2junl4a-6
Dilution:
1
Prep Batch:
26122
Prep Method:
SW846 3540C
Prep Date:
10-JUN-14
Prep Aliquot:
1.16 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
12.4
Pg/g
3.80
11.7
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222005
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 16:58
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 21.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-86
26124
06/12/2014 00:18
blljunl4b_2-8
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.12 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
745
Pg/g
2.61 11.3
40321-76-4
1,2,3,7,8-PeCDD
U
1.57
Pg/g
1.57 56.7
39227-28-6
1,2,3,4,7,8-HxCDD
J
3.11
Pg/g
3.04 56.7
57653-85-7
1,2,3,6,7,8-HxCDD
J
9.82
Pg/g
3.20 56.7
19408-74-3
1,2,3,7,8,9-HxCDD
J
6.10
Pg/g
3.31 56.7
35822-46-9
1,2,3,4,6,7,8-HpCDD
219
Pg/g
3.58 56.7
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8390
Pg/g
6.64 113
51207-31-9
2,3,7,8-TCDF
u
4.56
Pg/g
4.56 11.3
57117-41-6
1,2,3,7,8-PeCDF
u
1.97
Pg/g
1.97 56.7
57117-31-4
2,3,4,7,8-PeCDF
u
2.45
Pg/g
2.45 56.7
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.43
Pg/g
2.43 56.7
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.31
Pg/g
2.31 56.7
60851-34-5
2,3,4,6,7,8-HxCDF
J
2.49
Pg/g
1.41 56.7
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.9
Pg/g
1.90 56.7
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
35.3
Pg/g
1.38 56.7
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
2.36
Pg/g
2.11 56.7
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
112
Pg/g
3.67 113
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2000
2270
Pg/g
88.1
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2330
2270
Pg/g
103
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2050
2270
Pg/g
90.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1840
2270
Pg/g
81.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2080
2270
Pg/g
91.8
(23%-140%)
13C-OCDD
4020
4540
Pg/g
88.6
(17%-157%)
13C-2,3,7,8-TCDF
2150
2270
Pg/g
94.9
(24%-169%)
130-1,2,3,7,8-
PeCDF
2270
2270
Pg/g
99.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
2360
2270
Pg/g
104
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1950
2270
Pg/g
86.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1810
2270
Pg/g
80.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1960
2270
Pg/g
86.6
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1900
2270
Pg/g
83.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1890
2270
Pg/g
83.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1960
2270
Pg/g
86.6
(26%-13 8%)
3701-2,3,7,8-TCDD
243
227
Pg/g
107
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222006
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 17:10
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 11-7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-87
26124
06/12/2014 01:05
blljunl4b_2-9
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.08 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
226
Pg/g
2.20 10.5
40321-76-4
1,2,3,7,8-PeCDD
U
1.45
Pg/g
1.45 52.4
39227-28-6
1,2,3,4,7,8-HxCDD
u
1.99
Pg/g
1.99 52.4
57653-85-7
1,2,3,6,7,8-HxCDD
J
6.12
Pg/g
1.95 52.4
19408-74-3
1,2,3,7,8,9-HxCDD
u
2.09
Pg/g
2.09 52.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
112
Pg/g
3.84 52.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5020
Pg/g
5.93 105
51207-31-9
2,3,7,8-TCDF
J
3.58
Pg/g
2.02 10.5
57117-41-6
1,2,3,7,8-PeCDF
J
0.964
Pg/g
0.855 52.4
57117-31-4
2,3,4,7,8-PeCDF
J
0.859
Pg/g
0.759 52.4
70648-26-9
1,2,3,4,7,8-HxCDF
u
1.19
Pg/g
1.19 52.4
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.11
Pg/g
1.11 52.4
60851-34-5
2,3,4,6,7,8-HxCDF
u
1.15
Pg/g
1.15 52.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.65
Pg/g
1.65 52.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
16.4
Pg/g
1.64 52.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
2.2
Pg/g
2.20 52.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
38.6
Pg/g
4.97 105
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1780
2100
Pg/g
84.8
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1950
2100
Pg/g
93.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1810
2100
Pg/g
86.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1730
2100
Pg/g
82.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1870
2100
Pg/g
89.3
(23%-140%)
13C-OCDD
3620
4190
Pg/g
86.3
(17%-157%)
13C-2,3,7,8-TCDF
1960
2100
Pg/g
93.4
(24%-169%)
130-1,2,3,7,8-
PeCDF
1820
2100
Pg/g
86.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
2070
2100
Pg/g
98.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1710
2100
Pg/g
81.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1640
2100
Pg/g
78.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1810
2100
Pg/g
86.5
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1730
2100
Pg/g
82.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1700
2100
Pg/g
81.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1880
2100
Pg/g
89.8
(26%-13 8%)
3701-2,3,7,8-TCDD
217
210
Pg/g
103
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 18 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222007
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 18:03
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 17.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-88
26124
06/12/2014 01:53
blljunl4b_2-10
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.22 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
139
Pg/g
2.06 9.91
40321-76-4
1,2,3,7,8-PeCDD
U
1.47
Pg/g
1.47 49.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
4.38
Pg/g
4.38 49.5
57653-85-7
1,2,3,6,7,8-HxCDD
J
5.39
Pg/g
4.10 49.5
19408-74-3
1,2,3,7,8,9-HxCDD
u
4.5
Pg/g
4.50 49.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
161
Pg/g
4.16 49.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7160
Pg/g
7.93 99.1
51207-31-9
2,3,7,8-TCDF
u
2.26
Pg/g
2.26 9.91
57117-41-6
1,2,3,7,8-PeCDF
J
1.76
Pg/g
1.01 49.5
57117-31-4
2,3,4,7,8-PeCDF
u
.933
Pg/g
0.933 49.5
70648-26-9
1,2,3,4,7,8-HxCDF
J
1.98
Pg/g
1.53 49.5
57II7.44.9
1,2,3,6,7,8-HxCDF
J
2.04
Pg/g
1.48 49.5
60851-34-5
2,3,4,6,7,8-HxCDF
u
1.51
Pg/g
1.51 49.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.1
Pg/g
2.10 49.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
21.0
Pg/g
1.69 49.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
2.5
Pg/g
2.50 49.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
76.8
Pg/g
4.02 99.1
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1570
1980
Pg/g
79.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1620
1980
Pg/g
81.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1590
1980
Pg/g
80.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1560
1980
Pg/g
78.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1690
1980
Pg/g
85.2
(23%-140%)
13C-OCDD
3330
3960
Pg/g
84.0
(17%-157%)
13C-2,3,7,8-TCDF
1800
1980
Pg/g
91.0
(24%-169%)
130-1,2,3,7,8-
PeCDF
1600
1980
Pg/g
80.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
1690
1980
Pg/g
85.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1560
1980
Pg/g
78.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1500
1980
Pg/g
75.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1590
1980
Pg/g
80.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1550
1980
Pg/g
78.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1560
1980
Pg/g
78.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1620
1980
Pg/g
81.6
(26%-13 8%)
3701-2,3,7,8-TCDD
200
198
Pg/g
101
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 6222008
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 18:05
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 29.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-89
26124
06/12/2014 02:41
blljunl4b_2-ll
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.08 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
595
Pg/g
4.36 13.2
40321-76-4
1,2,3,7,8-PeCDD
U
2.82
Pg/g
2.82 66.0
39227-28-6
1,2,3,4,7,8-HxCDD
QU
8.42
Pg/g
8.42 66.0
57653-85-7
1,2,3,6,7,8-HxCDD
Q
69.9
Pg/g
18.7 66.0
19408-74-3
1,2,3,7,8,9-HxCDD
QU
12.2
Pg/g
12.2 66.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
358
Pg/g
6.23 66.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14400
Pg/g
12.1 132
51207-31-9
2,3,7,8-TCDF
J
9.13
Pg/g
4.73 13.2
57117-41-6
1,2,3,7,8-PeCDF
J
2.90
Pg/g
2.13 66.0
57117-31-4
2,3,4,7,8-PeCDF
J
6.36
Pg/g
2.04 66.0
70648-26-9
1,2,3,4,7,8-HxCDF
J
5.94
Pg/g
3.06 66.0
57II7.44.9
1,2,3,6,7,8-HxCDF
J
6.52
Pg/g
2.80 66.0
60851-34-5
2,3,4,6,7,8-HxCDF
J
4.80
Pg/g
3.19 66.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
4.36
Pg/g
4.36 66.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
78.8
Pg/g
2.69 66.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
4.86
Pg/g
4.86 66.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
63.4
Pg/g
7.55 132
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2210
2640
Pg/g
83.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2200
2640
Pg/g
83.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 2300
2640
Pg/g
87.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 753
2640
Pg/g
28.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2610
2640
Pg/g
99.0
(23%-140%)
13C-OCDD
5460
5280
Pg/g
103
(17%-157%)
13C-2,3,7,8-TCDF
2360
2640
Pg/g
89.5
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2200
2640
Pg/g
83.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
2360
2640
Pg/g
89.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2460
2640
Pg/g
93.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2250
2640
Pg/g
85.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2430
2640
Pg/g
92.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1870
2640
Pg/g
70.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2450
2640
Pg/g
92.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2540
2640
Pg/g
96.3
(26%-13 8%)
3701-2,3,7,8-TCDD
281
264
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 20 of 3 6
-------
Quality Control
Summary
Page 21 of 36
-------
( (ipc Fear Analytical LLC Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 1 of 5
Surrogate Recovery Report
SDG Number: 6222
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010629
LCS for batch 26122
12010630
LCSD for batch 26122
12010628
MB for batch 26122
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
85.6
89.4
88.3
83.7
83.8
75.1
96.5
88.2
96.8
86.7
84.8
87.3
84.8
83.8
81.8
102
85.0
88.6
89.4
85.3
87.5
78.2
96.1
87.5
96.0
89.9
87.8
89.8
83.2
86.3
83.1
100
78.7
83.0
80.6
79.4
81.8
72.2
86.6
82.3
88.7
79.8
78.3
81.8
79.9
78.1
78.9
91.1
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6222001
SFRA-82
13C-2,3,7,8-TCDD
82.6
(25%-164%)
Page 22 of 3 6
-------
( (ipc Fear Analytical LLC Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 2 of 5
Surrogate Recovery Report
SDG Number: 6222
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6222001
SFRA-82
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
87.4
83.6
69.0
94.2
92.5
92.0
87.7
91.7
85.7
83.1
86.1
85.6
88.0
91.2
101
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6222002
SFRA-83
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
87.6
90.7
84.8
57.0
98.9
95.9
94.4
89.5
94.7
87.9
81.3
86.8
85.7
90.1
94.8
107
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6222003
SFRA-84
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
84.5
91.1
83.2
75.7
93.1
89.7
90.8
89.4
93.7
89.3
80.3
85.4
82.1
86.7
88.8
102
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6222004
SFRA-85
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
88.7
92.4
(25%-
(25%-
64%)
81%)
Page 23 of 36
-------
( (ipc Fear Analytical LLC Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 3 of 5
Surrogate Recovery Report
SDG Number: 6222
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6222004
SFRA-85
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
93.4
35.5
103
98.1
93.6
89.7
95.2
89.1
83.3
89.0
86.5
91.9
97.9
106
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6222005
SFRA-86
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
88.1
103
90.3
81.2
91.8
88.6
94.9
99.9
104
86.2
80.0
86.6
83.8
83.3
86.6
107
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6222006
SFRA-87
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
84.8
93.0
86.2
82.3
89.3
86.3
93.4
86.9
98.7
81.5
78.1
86.5
82.3
81.0
89.8
103
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6222007
SFRA-88
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
79.0
81.6
80.1
(25%-
(25%-
(32%-
64%)
81%)
41%)
Page 24 of 3 6
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( (ipc Fear Analytical LLC Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 4 of 5
Surrogate Recovery Report
SDG Number: 6222
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6222007
SFRA-88
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
78.7
85.2
84.0
91.0
80.8
85.1
78.6
75.6
80.4
78.0
78.6
81.6
101
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6222008
SFRA-89
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
83.7
83.4
87.1
28.5
99.0
103
89.5
83.3
89.3
93.2
85.2
92.0
70.7
92.7
96.3
106
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010631
SFRA-82(6222001MS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
83.4
84.0
83.2
63.0
92.5
89.1
87.6
80.0
83.8
81.2
78.1
82.6
78.7
82.0
85.3
106
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010632
SFRA-82(6222001MSD)
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
13C-1,2,3,6,7,8-HxCDD
87.9
90.9
91.1
65.9
(25%-
(25%-
(32%-
(28%-
64%)
81%)
41%)
30%)
Page 25 of 36
-------
( (ipc Fear Analytical LLC Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 5 of 5
Surrogate Recovery Report
SDG Number: 6222
Matrix Type: SOLID
Sample ID Client ID
Recovery Acceptance
Surrogate
QUAL (%)
Limits
13C-l,2,3,4,6,7,8-HpCDD
100
(23%-
140%
13C-OCDD
98.1
(17%-
157%
13C-2,3,7,8-TCDF
94.5
(24%-
169%
13C-l,2,3,7,8-PeCDF
89.3
(24%-
185%
13C-2,3,4,7,8-PeCDF
93.6
(21%-
178%
13C-l,2,3,4,7,8-HxCDF
88.8
(26%-
152%
13C-l,2,3,6,7,8-HxCDF
80.8
(26%-
123%
13C-2,3,4,6,7,8-HxCDF
86.9
(28%-
136%
13C-l,2,3,7,8,9-HxCDF
83.7
(29%-
147%
13C-l,2,3,4,6,7,8-HpCDF
87.4
(28%-
143%
13C-l,2,3,4,7,8,9-HpCDF
90.8
(26%-
138%
37Cl-2,3,7,8-TCDD
109
(35%-
197%
12010632
SFRA-82(6222001MSD)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 26 of 3 6
-------
Cape Fear Analytical LLC
Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/11/2014 18:44 Dilution: 1
Prep Batch ID:26122
Batch ID: 26124
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.1
106
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
99.2
99.2
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
99.3
99.3
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
98.5
98.5
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
101
101
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
192
95.8
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.9
99.5
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
99.6
99.6
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
98.1
98.1
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
99.1
99.1
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
98.6
98.6
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
99.2
99.2
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
105
105
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
96.6
96.6
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
99.7
99.7
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
196
98
63-170
SDG Number: 6222
Client ID: LCS for batch 26122
Lab Sample ID: 12010629
Instrument: HRP763
Analyst: JTF
Page
27 of 36
-------
Cape Fear Analytical LLC
Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/11/2014 19:31 Dilution: 1
Prep Batch ID:26122
Batch ID: 26124
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.3
106
67-158
0.783
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
97.5
97.5
70-142
1.71
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
100
100
70-164
0.793
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
98.0
98
76-134
0.493
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
102
102
64-162
1.34
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
99.2
99.2
70-140
1.61
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
190
94.9
78-144
0.864
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
20.4
102
75-158
2.21
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
101
101
80-134
1.87
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
98.5
98.5
68-160
0.405
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
98.1
98.1
72-134
1.02
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
98.1
98.1
84-130
0.488
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
98.0
98
70-156
1.19
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
105
105
78-130
0.682
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
98.1
98.1
82-122
1.53
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
102
102
78-138
1.76
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
201
101
63-170
2.58
0-20
SDG Number: 6222
Client ID: LCSD for batch 26122
Lab Sample ID: 12010630
Instrument: HRP763
Analyst: JTF
Page
28 of 36
-------
Cape Fear Analytical LLC
Report Date: June 16, 2014
Page 1 of 2
Dilution: 1
Amount
Spike
Added
Cone.
Recovery Acceptance
CAS No.
Parmname
Pg/g
Pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
233
1020
145 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1160 J
1140
97.7
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1160 U
1140
98.2
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1160 JQ
1200
99.5
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1160 J
1380
117
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1160
1590
105
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2330
18600
152 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
233 J
231
95.2
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1160 J
1140
96.8
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1160 U
1120
95.9
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1160 J
1130
95.6
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1160 J
1140
97.1
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1160 J
1100
94
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1160 J
1190
101
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1160
1220
97.4
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1160 J
1140
97.3
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2330
2400
94.7
70-130
SDG Number: 6222
Client ID: SFRA-82(6222001MS)
Lab Sample ID: 12010631
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 24.6
Analysis Date: 06/12/2014 08:29
Prep Batch ID:26122
Batch ID: 26124
Page 29 of 3 6
-------
Cape Fear Analytical LLC
Report Date: June 16, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 24.6
Analysis Date: 06/12/2014 09:20 Dilution: 1
Prep Batch ID:26122
Batch ID: 26124
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
239
924
103
70-130
9.47
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1200
J
1190
99.4
70-130
4.46
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1200
U
1190
99.9
70-130
4.46
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1200
JQ
1260
102
70-130
4.86
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1200
J
1400
116
70-130
1.46
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1200
1510
94.5
70-130
5.70
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2390
15100
-1.15 *
70-130
21.1 *
0-20
51207-31-9
MSD
2,3,7,8-TCDF
239
J
243
98
70-130
5.29
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1200
J
1160
96.3
70-130
2.14
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1200
U
1130
94.4
70-130
1.11
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1200
J
1150
94.6
70-130
1.57
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1200
J
1130
94
70-130
0.553
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1200
J
1150
95.4
70-130
4.09
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1200
J
1230
103
70-130
3.77
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1200
1200
92.8
70-130
2.10
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1200
J
1150
95.6
70-130
0.868
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2390
2420
92.9
70-130
0.664
0-20
SDG Number: 6222
Client ID: SFRA-82(6222001MSD)
Lab Sample ID: 12010632
Instrument: HRP763
Analyst: JTF
Page
30 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Method Blank Summary
Page 1 of 1
SDG Number: 6222
Client ID: MB for batch 26122
Lab Sample ID: 12010628
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: 10-JUN-14
Matrix: SOLID
Data File: blljunl4b 2-3
Analyzed: 06/11/14 20:19
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26122
12010629
bl ljunl4b_2-l
06/11/14
1844
02
LCSD for batch 26122
12010630
bl ljunl4b_2-2
06/11/14
1931
03
SFRA-82
6222001
bl ljunl4b_2-4
06/11/14
2107
04
SFRA-83
6222002
bl ljunl4b_2-5
06/11/14
2154
05
SFRA-84
6222003
bl ljunl4b_2-6
06/11/14
2242
06
SFRA-85
6222004
bl ljunl4b_2-7
06/11/14
2330
07
SFRA-86
6222005
bl ljunl4b_2-8
06/12/14
0018
08
SFRA-87
6222006
bl ljunl4b_2-9
06/12/14
0105
09
SFRA-88
6222007
bl ljunl4b_2-10
06/12/14
0153
10
SFRA-89
6222008
blljunl4b_2-ll
06/12/14
0241
11
SFRA-82(6222001MS)
12010631
bl ljunl4b_3-2
06/12/14
0829
12
SFRA-82(6222001MSD)
12010632
bl ljunl4b_3-3
06/12/14
0920
13
SFRA-84
6222003
bl2junl4a-5
06/12/14
1302
14
SFRA-85
6222004
bl2junl4a-6
06/12/14
1322
Page 31 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6222
12010628
QC for batch 26122
MB for batch 26122
26124
06/11/2014 20:19
blljunl4b 2-3
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
Prep Batch:
26122
Prep Method:
SW846 3540C
Prep Date:
10-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.189
Pg/g
0.189
1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.196
Pg/g
0.125
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.236
Pg/g
0.236
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.23
Pg/g
0.230
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.292
Pg/g
0.246
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.392
Pg/g
0.356
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.612
Pg/g
0.612
10.0
51207-31-9
2,3,7,8-TCDF
u
.118
Pg/g
0.118
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.354
Pg/g
0.0746
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.21
Pg/g
0.210
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.338
Pg/g
0.122
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.288
Pg/g
0.288
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.222
Pg/g
0.122
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.300
Pg/g
0.169
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.264
Pg/g
0.156
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.272
Pg/g
0.272
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.494
Pg/g
0.494
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
157
200
Pg/g
78.7
(25 %-164%)
13C-1,2,3,7,8-PeCDD
166
200
Pg/g
83.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
161
200
Pg/g
80.6
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
159
200
Pg/g
79.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
164
200
Pg/g
81.8
(23%-140%)
13C-OCDD
289
400
Pg/g
72.2
(17%-157%)
13C-2,3,7,8-TCDF
173
200
Pg/g
86.6
(24%-169%)
13C-1,2,3,7,8-PeCDF
165
200
Pg/g
82.3
(24%-185%)
13C-2,3,4,7,8-PeCDF
177
200
Pg/g
88.7
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
160
200
Pg/g
79.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
157
200
Pg/g
78.3
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
164
200
Pg/g
81.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
160
200
Pg/g
79.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
156
200
Pg/g
78.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
158
200
Pg/g
78.9
(26%-13 8%)
37Cl-2,3,7,8-TCDD
18.2
20.0
Pg/g
91.1
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 32 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6222
Lab Sample ID: 12010629
Client Sample: *or batch 26122
Client ID: LCS for batch 26122
Batch ID: 26124
Run Date: 06/11/2014 18:44
Data File: blljunl4b_2-l
Prep Batch: 26122
Prep Date: 10-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.1
Pg/g
0.264 1.00
40321-76-4
1,2,3,7,8-PeCDD
99.2
Pg/g
0.220 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
99.3
Pg/g
0.416 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.5
Pg/g
0.422 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
101
Pg/g
0.444 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
0.422 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
192
Pg/g
0.756 10.0
51207-31-9
2,3,7,8-TCDF
19.9
Pg/g
0.157 1.00
57117-41-6
1,2,3,7,8-PeCDF
99.6
Pg/g
0.214 5.00
57117-31-4
2,3,4,7,8-PeCDF
98.1
Pg/g
0.197 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
99.1
Pg/g
0.434 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
98.6
Pg/g
0.410 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
99.2
Pg/g
0.426 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
105
Pg/g
0.626 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
96.6
Pg/g
0.356 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.7
Pg/g
0.608 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
196
Pg/g
0.688 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
171
200
Pg/g
85.6
(20%-175%)
13C-1,2,3,7,8-
PeCDD
179
200
Pg/g
89.4
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
177
200
Pg/g
88.3
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
167
200
Pg/g
83.7
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
168
200
Pg/g
83.8
(22%-166%)
13C-OCDD
300
400
Pg/g
75.1
(13%-199%)
13C-2,3,7,8-TCDF
193
200
Pg/g
96.5
(22%-152%)
13C-1,2,3,7,8-
PeCDF
176
200
Pg/g
88.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
194
200
Pg/g
96.8
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
173
200
Pg/g
86.7
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
170
200
Pg/g
84.8
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
175
200
Pg/g
87.3
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
170
200
Pg/g
84.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
168
200
Pg/g
83.8
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
164
200
Pg/g
81.8
(20%-186%)
3701-2,3,7,8-TCDD
20.4
20.0
Pg/g
102
(31 %-191%)
Comments:
Page 33 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6222
12010630
QC for batch 26122
LCSD for batch 26122
26124
06/11/2014 19:31
blljunl4b 2-2
26122
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
10-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
21.3
Pg/g
0.258
1.00
40321-76-4
1,2,3,7,8-PeCDD
97.5
Pg/g
0.236
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
100
Pg/g
0.390
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.0
Pg/g
0.392
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
102
Pg/g
0.414
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.2
Pg/g
0.728
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
190
Pg/g
0.990
10.0
51207-31-9
2,3,7,8-TCDF
20.4
Pg/g
0.177
1.00
57117-41-6
1,2,3,7,8-PeCDF
101
Pg/g
0.206
5.00
57117-31-4
2,3,4,7,8-PeCDF
98.5
Pg/g
0.194
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
98.1
Pg/g
0.450
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
98.1
Pg/g
0.418
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
98.0
Pg/g
0.468
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
105
Pg/g
0.672
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
98.1
Pg/g
0.410
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
102
Pg/g
0.654
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
201
Pg/g
1.03
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
170
200
Pg/g
85.0
(20%-175%)
13C-1,2,3,7,8-PeCDD
177
200
Pg/g
88.6
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
179
200
Pg/g
89.4
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
171
200
Pg/g
85.3
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
175
200
Pg/g
87.5
(22%-166%)
13C-OCDD
313
400
Pg/g
78.2
(13%-199%)
13C-2,3,7,8-TCDF
192
200
Pg/g
96.1
(22%-152%)
13C-1,2,3,7,8-PeCDF
175
200
Pg/g
87.5
(21%-192%)
13C-2,3,4,7,8-PeCDF
192
200
Pg/g
96.0
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
180
200
Pg/g
89.9
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
176
200
Pg/g
87.8
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
180
200
Pg/g
89.8
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
166
200
Pg/g
83.2
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
173
200
Pg/g
86.3
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
166
200
Pg/g
83.1
(20%-186%)
37Cl-2,3,7,8-TCDD
20.0
20.0
Pg/g
100
(31 %-191%)
Comments:
Page 34 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6222
Lab Sample ID: 12010631
Client Sample: *or batch 26122
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 16:28
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 24.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-82(6222001MS)
26124
06/12/2014 08:29
blljunl4b_3-2
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.14 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1020
Pg/g
2.86 11.6
40321-76-4
1,2,3,7,8-PeCDD
1140
Pg/g
3.35 58.2
39227-28-6
1,2,3,4,7,8-HxCDD
1140
Pg/g
5.84 58.2
57653-85-7
1,2,3,6,7,8-HxCDD
Q
1200
Pg/g
7.59 58.2
19408-74-3
1,2,3,7,8,9-HxCDD
1380
Pg/g
7.10 58.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
1590
Pg/g
6.94 58.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
18600
Pg/g
12.3 116
51207-31-9
2,3,7,8-TCDF
231
Pg/g
2.93 11.6
57117-41-6
1,2,3,7,8-PeCDF
1140
Pg/g
2.49 58.2
57117-31-4
2,3,4,7,8-PeCDF
1120
Pg/g
2.47 58.2
70648-26-9
1,2,3,4,7,8-HxCDF
1130
Pg/g
4.33 58.2
57II7.44.9
1,2,3,6,7,8-HxCDF
1140
Pg/g
4.17 58.2
60851-34-5
2,3,4,6,7,8-HxCDF
1100
Pg/g
4.59 58.2
72918-21-9
1,2,3,7,8,9-HxCDF
1190
Pg/g
6.40 58.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
1220
Pg/g
3.21 58.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
1140
Pg/g
5.80 58.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2400
Pg/g
6.10 116
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1940
2330
Pg/g
83.4
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1960
2330
Pg/g
84.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1940
2330
Pg/g
83.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1470
2330
Pg/g
63.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2150
2330
Pg/g
92.5
(23%-140%)
13C-OCDD
4150
4660
Pg/g
89.1
(17%-157%)
13C-2,3,7,8-TCDF
2040
2330
Pg/g
87.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1860
2330
Pg/g
80.0
(24%-185%)
130-2,3,4,7,8-
PeCDF
1950
2330
Pg/g
83.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1890
2330
Pg/g
81.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1820
2330
Pg/g
78.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1920
2330
Pg/g
82.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1830
2330
Pg/g
78.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1910
2330
Pg/g
82.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1980
2330
Pg/g
85.3
(26%-13 8%)
3701-2,3,7,8-TCDD
247
233
Pg/g
106
(35%-197%)
Comments:
Q Quantitative Interference
Page 35 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 16,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6222
Lab Sample ID: 12010632
Client Sample: *or batch 26122
Client:
Date Collected:
Date Received:
TETR001
06/06/2014 16:28
06/09/2014 10:20
Project: TETR00114
Matrix: SOLID
%Moisture: 24.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-82(6222001MSD)
26124
06/12/2014 09:20
blljunl4b_3-3
26122
10-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
l.ii g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
924
Pg/g
3.16 12.0
40321-76-4
1,2,3,7,8-PeCDD
1190
Pg/g
2.18 59.8
39227-28-6
1,2,3,4,7,8-HxCDD
1190
Pg/g
3.75 59.8
57653-85-7
1,2,3,6,7,8-HxCDD
Q
1260
Pg/g
4.71 59.8
19408-74-3
1,2,3,7,8,9-HxCDD
1400
Pg/g
4.47 59.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
1510
Pg/g
4.73 59.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
15100
Pg/g
9.30 120
51207-31-9
2,3,7,8-TCDF
243
Pg/g
3.16 12.0
57117-41-6
1,2,3,7,8-PeCDF
1160
Pg/g
3.04 59.8
57117-31-4
2,3,4,7,8-PeCDF
1130
Pg/g
2.84 59.8
70648-26-9
1,2,3,4,7,8-HxCDF
1150
Pg/g
3.80 59.8
57II7.44.9
1,2,3,6,7,8-HxCDF
1130
Pg/g
3.78 59.8
60851-34-5
2,3,4,6,7,8-HxCDF
1150
Pg/g
4.06 59.8
72918-21-9
1,2,3,7,8,9-HxCDF
1230
Pg/g
6.19 59.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
1200
Pg/g
2.41 59.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
1150
Pg/g
4.59 59.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2420
Pg/g
6.55 120
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2100
2390
Pg/g
87.9
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2170
2390
Pg/g
90.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2180
2390
Pg/g
91.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1570
2390
Pg/g
65.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2400
2390
Pg/g
100
(23%-140%)
13C-OCDD
4690
4780
Pg/g
98.1
(17%-157%)
13C-2,3,7,8-TCDF
2260
2390
Pg/g
94.5
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2130
2390
Pg/g
89.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
2240
2390
Pg/g
93.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2120
2390
Pg/g
88.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1930
2390
Pg/g
80.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2080
2390
Pg/g
86.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2000
2390
Pg/g
83.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2090
2390
Pg/g
87.4
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2170
2390
Pg/g
90.8
(26%-13 8%)
3701-2,3,7,8-TCDD
260
239
Pg/g
109
(35%-197%)
Comments:
Q Quantitative Interference
Page 36 of 36
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 23. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6223
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 10, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 36
problem solved
-------
Page;
Project #:
CFA Quote #:
COC Number0';
PO Number:
J-
of
cu.„,Nmc ;/ 2"^-
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: 3
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910)795-0421
Phone
Sample Analysis Requested(S) (Fill in the number of containers for each test)
p:
OS
CD
Is Address;
o
Project/Site Name; <*./ / r~ _ L A t i A
Anfacfc* Acf,«-
Fax#:
L» '
o
rl:rine, F=Fecal, N«Nasat
5.) Sample Analysis Requested: Analytical method requested (i.eJKWB, 1(688) and number of containers provided for each (i.e. S290B -3,16688-1),
6.) Preservative Type: HA - Hydrochloric Acid, M = Nitric Acid, SH = Sodium Hydroxide, SA - Sulfuric Acid, AA - Ascorbic Acid, HX - Hexane, ST - Sodium Thiosulfate, If no preservative is added - leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intact?
YES NO
Cooler Temp:
SI
-------
SAMPLE RECEIPT CHECKLIST
Cope Fear Analytical
CI. em: T%TP^
Work Order: 2,2-3
Shipping Company: P". tC
Date/Time Received: | (//O I ^ { Q [
Suspected Hazard Information
Yes | NA | No
Shipped 6E COT Hcitrciouj?
Samples identified es Foreign Soil?
1 1 iS
DOE Site Sample Packages
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NA
No*
Screened <0.5 mR/hr?
Samples < 2x background?
Air Sample Receipt Specifics
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Air sample
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Sample Receipt Criteria
Ves NA No
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Circle Applicable:
broken dsms-ged tonteiner it? *ing comaine!' othgr(describe}
Chain o- Custody documents included
with shipment?
Samples requiring cold preservation
within 0-6°C?
reservfljlion Method:
!C€ fcagij blue itfc dry kf-
r {describeJ
fT.~7»0
Aqueous samples found to have visible
solids?
Sample IDs, containers sffecied,
Samples requiring chemical
preservation at proper pH?
J
f
7
jiL
Sample IDs, ccntsinefs etfecled end pH observed.
f preservetive added, lots;
Samples requiring preservation have
no residual chlorine?
1/
Sample IDs. containers effected
IJ preservative added. Lot#:
Sample IDs, tests aft?
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 36
-------
Case Narrative
Page 5 of 36
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6223
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26130
Clean Up Batch Number: 26129
Extraction Batch Number: 26128
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6223001 SFRA-90
6223002 SFRA-91
6223003 SFRA-92
6223004 SFRA-93
6223005 SFRA-94
6223006 SFRA-95
6223007 SFRA-96
6223008 SFRA-97
12010636 Method Blank (MB)
12010637 Laboratory Control Sample (LCS)
12010638 Laboratory Control Sample Duplicate (LCSD)
12010639 6223001 (SFRA-90) Matrix Spike (MS)
12010640 6223001 (SFRA-90) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Page 6 of 36
-------
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6223001 (SFRA-90)- Batch 26130 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
Two MS recoveries were above the acceptance limits due to matrix interference. 12010639
(SFRA-90) - Batch 26130.
Matrix Spike Duplicate (MSD) Recovery Statement
One MSD recovery for this SDG was not within the acceptance limits. The failure confirms in
the MS and can be attributed to matrix interference. 12010640 (SFRA-90) - Batch 26130.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Page 7 of 36
-------
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26130.
Sample Dilutions
Sample 6223006 (SFRA-95)- Batch 26130 was diluted due to the presence of over-range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 36
-------
Sample Data Summary
Page 9 of 36
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6223 CFA Work Order: 6223
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 23JUN2014 Title: Data Validator
Page 10 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6223
Lab Sample ID: 6223001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/09/2014 15:45
06/10/201410:15
Project: TETR00114
Matrix: SOLID
%Moisture: 22.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-90
26130
06/12/2014 17:41
A11JUN14A3-6
26128
ll-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.02 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
543
Pg/g
1.54 12.6
40321-76-4
1,2,3,7,8-PeCDD
U
4.1
Pg/g
4.10 63.2
39227-28-6
1,2,3,4,7,8-HxCDD
u
6.04
Pg/g
6.04 63.2
57653-85-7
1,2,3,6,7,8-HxCDD
107
Pg/g
6.47 63.2
19408-74-3
1,2,3,7,8,9-HxCDD
J
31.3
Pg/g
6.68 63.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
2210
Pg/g
10.0 63.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
27800
Pg/g
21.1 126
51207-31-9
2,3,7,8-TCDF
J
8.24
Pg/g
3.01 12.6
57117-41-6
1,2,3,7,8-PeCDF
J
3.01
Pg/g
2.43 63.2
57117-31-4
2,3,4,7,8-PeCDF
J
7.59
Pg/g
2.48 63.2
70648-26-9
1,2,3,4,7,8-HxCDF
J
31.7
Pg/g
2.76 63.2
57II7.44.9
1,2,3,6,7,8-HxCDF
J
11.9
Pg/g
2.88 63.2
60851-34-5
2,3,4,6,7,8-HxCDF
J
19.8
Pg/g
3.11 63.2
72918-21-9
1,2,3,7,8,9-HxCDF
J
9.64
Pg/g
3.03 63.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
333
Pg/g
2.78 63.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
29.4
Pg/g
4.40 63.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
899
Pg/g
5.39 126
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2270
2530
Pg/g
89.7
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2480
2530
Pg/g
98.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2360
2530
Pg/g
93.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1870
2530
Pg/g
73.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2350
2530
Pg/g
93.0
(23%-140%)
13C-OCDD
4800
5060
Pg/g
95.0
(17%-157%)
13C-2,3,7,8-TCDF
2390
2530
Pg/g
94.6
(24%-169%)
130-1,2,3,7,8-
PeCDF
2700
2530
Pg/g
107
(24%-185%)
130-2,3,4,7,8-
PeCDF
2630
2530
Pg/g
104
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2230
2530
Pg/g
88.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2110
2530
Pg/g
83.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2180
2530
Pg/g
86.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
2080
2530
Pg/g
82.1
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2280
2530
Pg/g
90.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2300
2530
Pg/g
90.9
(26%-13 8%)
3701-2,3,7,8-TCDD
267
253
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6223
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6223002
Date Collected:
06/09/2014 15:50
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
06/10/201410:15
%Moisture: 26.5
Client ID:
SFRA-91
Prep Basis: Dry Weight
Batch ID:
26130
Method:
EPA Method 1613B
Run Date:
06/12/2014 18:30
Analyst:
JTF
Instrument: HRP750
Data File:
A11JUN14A3-7
Dilution: 1
Prep Batch:
26128
Prep Method:
SW846 3540C
Prep Date:
ll-JUN-14
Prep Aliquot:
1.55 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
778
Pg/g
1.32 8.78
40321-76-4
1,2,3,7,8-PeCDD
U
2.44
Pg/g
2.44 43.9
39227-28-6
1,2,3,4,7,8-HxCDD
JQ
14.8
Pg/g
3.32 43.9
57653-85-7
1,2,3,6,7,8-HxCDD
Q
72.4
Pg/g
4.46 43.9
19408-74-3
1,2,3,7,8,9-HxCDD
J
21.6
Pg/g
4.07 43.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
1010
Pg/g
6.27 43.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14300
Pg/g
14.1 87.8
51207-31-9
2,3,7,8-TCDF
J
6.70
Pg/g
2.11 8.78
57117-41-6
1,2,3,7,8-PeCDF
J
1.56
Pg/g
1.40 43.9
57117-31-4
2,3,4,7,8-PeCDF
J
4.02
Pg/g
1.41 43.9
70648-26-9
1,2,3,4,7,8-HxCDF
J
14.2
Pg/g
1.54 43.9
57II7.44.9
1,2,3,6,7,8-HxCDF
J
6.04
Pg/g
1.54 43.9
60851-34-5
2,3,4,6,7,8-HxCDF
J
9.37
Pg/g
1.52 43.9
72918-21-9
1,2,3,7,8,9-HxCDF
J
2.88
Pg/g
2.46 43.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
160
Pg/g
2.16 43.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
12.9
Pg/g
3.46 43.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
286
Pg/g
3.93 87.8
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1430
1760
Pg/g
81.3
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1520
1760
Pg/g
86.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1450
1760
Pg/g
82.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1000
1760
Pg/g
57.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1780
1760
Pg/g
101
(23%-140%)
13C-OCDD
3450
3510
Pg/g
98.2
(17%-157%)
13C-2,3,7,8-TCDF
1580
1760
Pg/g
90.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1620
1760
Pg/g
92.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1610
1760
Pg/g
91.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1630
1760
Pg/g
93.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1530
1760
Pg/g
87.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1620
1760
Pg/g
92.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1450
1760
Pg/g
82.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1670
1760
Pg/g
95.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1720
1760
Pg/g
97.9
(26%-13 8%)
3701-2,3,7,8-TCDD
169
176
Pg/g
96.5
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6223
Lab Sample ID: 6223003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/09/2014 16:05
06/10/201410:15
Project: TETR00114
Matrix: SOLID
%Moisture: 15.1
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-92
26130
06/12/2014 19:18
A11JUN14A3-8
26128
ll-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.13 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
J
2.92
Pg/g
0.975 10.4
40321-76-4
1,2,3,7,8-PeCDD
U
1.01
Pg/g
1.01 52.1
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.31
Pg/g
2.31 52.1
57653-85-7
1,2,3,6,7,8-HxCDD
u
2.25
Pg/g
2.25 52.1
19408-74-3
1,2,3,7,8,9-HxCDD
u
2.42
Pg/g
2.42 52.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
64.9
Pg/g
3.08 52.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
4650
Pg/g
10.8 104
51207-31-9
2,3,7,8-TCDF
J
1.46
Pg/g
1.07 10.4
57117-41-6
1,2,3,7,8-PeCDF
u
1.06
Pg/g
1.06 52.1
57117-31-4
2,3,4,7,8-PeCDF
u
1.03
Pg/g
1.03 52.1
70648-26-9
1,2,3,4,7,8-HxCDF
u
1.13
Pg/g
1.13 52.1
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.04
Pg/g
1.04 52.1
60851-34-5
2,3,4,6,7,8-HxCDF
u
1.11
Pg/g
1.11 52.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.64
Pg/g
1.64 52.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
4.77
Pg/g
1.39 52.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
2.11
Pg/g
2.11 52.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
8.67
Pg/g
8.67 104
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1790
2080
Pg/g
85.9
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1940
2080
Pg/g
93.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1820
2080
Pg/g
87.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1790
2080
Pg/g
86.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1960
2080
Pg/g
94.2
(23%-140%)
13C-OCDD
3560
4170
Pg/g
85.3
(17%-157%)
13C-2,3,7,8-TCDF
1970
2080
Pg/g
94.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
2020
2080
Pg/g
97.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
2040
2080
Pg/g
98.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1860
2080
Pg/g
89.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1870
2080
Pg/g
89.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1880
2080
Pg/g
90.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1750
2080
Pg/g
84.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1890
2080
Pg/g
90.8
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1920
2080
Pg/g
91.9
(26%-13 8%)
3701-2,3,7,8-TCDD
207
208
Pg/g
99.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6223
Lab Sample ID: 6223004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/09/2014 16:23
06/10/201410:15
Project: TETR00114
Matrix: SOLID
%Moisture: 20.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-93
26130
06/12/2014 20:06
A11JUN14A3-9
26128
ll-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.03 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
895
Pg/g
1.53 12.2
40321-76-4
1,2,3,7,8-PeCDD
U
2.49
Pg/g
2.49 61.1
39227-28-6
1,2,3,4,7,8-HxCDD
J
11.4
Pg/g
2.61 61.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
32.9
Pg/g
2.78 61.1
19408-74-3
1,2,3,7,8,9-HxCDD
J
14.3
Pg/g
2.86 61.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
757
Pg/g
7.45 61.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12300
Pg/g
18.0 122
51207-31-9
2,3,7,8-TCDF
J
9.96
Pg/g
2.76 12.2
57117-41-6
1,2,3,7,8-PeCDF
u
2.14
Pg/g
2.14 61.1
57117-31-4
2,3,4,7,8-PeCDF
J
3.93
Pg/g
2.13 61.1
70648-26-9
1,2,3,4,7,8-HxCDF
J
13.1
Pg/g
2.22 61.1
57II7.44.9
1,2,3,6,7,8-HxCDF
J
6.11
Pg/g
2.26 61.1
60851-34-5
2,3,4,6,7,8-HxCDF
J
7.89
Pg/g
2.26 61.1
72918-21-9
1,2,3,7,8,9-HxCDF
J
3.81
Pg/g
3.03 61.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
127
Pg/g
2.76 61.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
9.77
Pg/g
4.47 61.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
301
Pg/g
5.52 122
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2190
2440
Pg/g
89.5
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2390
2440
Pg/g
97.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2100
2440
Pg/g
85.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2060
2440
Pg/g
84.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2220
2440
Pg/g
90.9
(23%-140%)
13C-OCDD
4230
4880
Pg/g
86.5
(17%-157%)
13C-2,3,7,8-TCDF
2330
2440
Pg/g
95.4
(24%-169%)
130-1,2,3,7,8-
PeCDF
2530
2440
Pg/g
104
(24%-185%)
130-2,3,4,7,8-
PeCDF
2510
2440
Pg/g
103
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2060
2440
Pg/g
84.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2060
2440
Pg/g
84.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2050
2440
Pg/g
83.9
(28%-136%)
130-1,2,3,7,8,9-HxCDF
2000
2440
Pg/g
82.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2180
2440
Pg/g
89.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2100
2440
Pg/g
86.2
(26%-13 8%)
3701-2,3,7,8-TCDD
251
244
Pg/g
103
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6223
Lab Sample ID: 6223005
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/09/2014 16:18
06/10/201410:15
Project: TETR00114
Matrix: SOLID
%Moisture: 18.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-94
26130
06/12/2014 20:54
A11JUN14A3-10
26128
ll-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.01 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2980
Pg/g
1.66 12.2
40321-76-4
1,2,3,7,8-PeCDD
U
13.7
Pg/g
13.7 60.9
39227-28-6
1,2,3,4,7,8-HxCDD
J
5.53
Pg/g
3.43 60.9
57653-85-7
1,2,3,6,7,8-HxCDD
J
19.8
Pg/g
3.43 60.9
19408-74-3
1,2,3,7,8,9-HxCDD
J
7.94
Pg/g
3.65 60.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
355
Pg/g
6.89 60.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11000
Pg/g
19.3 122
51207-31-9
2,3,7,8-TCDF
16.1
Pg/g
2.41 12.2
57117-41-6
1,2,3,7,8-PeCDF
J
1.70
Pg/g
1.22 60.9
57117-31-4
2,3,4,7,8-PeCDF
J
2.26
Pg/g
1.18 60.9
70648-26-9
1,2,3,4,7,8-HxCDF
J
5.31
Pg/g
1.76 60.9
57II7.44.9
1,2,3,6,7,8-HxCDF
J
2.58
Pg/g
1.77 60.9
60851-34-5
2,3,4,6,7,8-HxCDF
J
3.34
Pg/g
1.83 60.9
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.56
Pg/g
2.56 60.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
55.9
Pg/g
1.36 60.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
4.94
Pg/g
2.14 60.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
89.0
Pg/g
4.14 122
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2070
2430
Pg/g
84.8
(25 %-164%)
130-1,2,3,7,8-
PeCDD
2410
2430
Pg/g
99.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2030
2430
Pg/g
83.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2000
2430
Pg/g
82.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2260
2430
Pg/g
93.0
(23%-140%)
13C-OCDD
4260
4870
Pg/g
87.6
(17%-157%)
13C-2,3,7,8-TCDF
2310
2430
Pg/g
94.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
2080
2430
Pg/g
85.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
2520
2430
Pg/g
103
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2080
2430
Pg/g
85.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2060
2430
Pg/g
84.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2100
2430
Pg/g
86.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1910
2430
Pg/g
78.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2150
2430
Pg/g
88.4
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2160
2430
Pg/g
88.9
(26%-13 8%)
3701-2,3,7,8-TCDD
250
243
Pg/g
103
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 36
-------
Cape Fear Analytical LLC
Report Date: June 23,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6223
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6223005
Date Collected:
06/09/2014 16:18
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/10/2014 10:15
%Moisture:
18.7
Client ID:
SFRA-94
Prep Basis:
Dry Weight
Batch ID:
26130
Method:
EPA Method 1613B
Run Date:
06/17/2014 09:44
Analyst:
JTF
Instrument:
HRP763
Data File:
bl6junl4a-6
Dilution:
1
Prep Batch:
26128
Prep Method:
SW846 3540C
Prep Date:
ll-JUN-14
Prep Aliquot:
1.01 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
18.8
Pg/g
4.67
12.2
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6223
6223006
1613B Soil
SFRA-95
26130
06/18/2014 00:27
A17JUN14C-10
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
06/09/2014 17:00
06/10/2014 10:15
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
22
Dry Weight
HRP750
5
Prep Batch:
26128
Prep Method:
SW846 3540C
Prep Date:
ll-JUN-14
Prep Aliquot:
1.08 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
16300
Pg/g
14.6 59.3
40321-76-4
1,2,3,7,8-PeCDD
U
8.47
Pg/g
8.47 297
39227-28-6
1,2,3,4,7,8-HxCDD
u
28
Pg/g
28.0 297
57653-85-7
1,2,3,6,7,8-HxCDD
J
110
Pg/g
28.2 297
19408-74-3
1,2,3,7,8,9-HxCDD
u
29.9
Pg/g
29.9 297
35822-46-9
1,2,3,4,6,7,8-HpCDD
1050
Pg/g
48.9 297
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13300
Pg/g
159 593
51207-31-9
2,3,7,8-TCDF
91.2
Pg/g
18.4 59.3
57117-41-6
1,2,3,7,8-PeCDF
u
9.85
Pg/g
9.85 297
57117-31-4
2,3,4,7,8-PeCDF
u
9.64
Pg/g
9.64 297
70648-26-9
1,2,3,4,7,8-HxCDF
u
23.3
Pg/g
23.3 297
57II7.44.9
1,2,3,6,7,8-HxCDF
u
13.9
Pg/g
13.9 297
60851-34-5
2,3,4,6,7,8-HxCDF
u
23.5
Pg/g
23.5 297
72918-21-9
1,2,3,7,8,9-HxCDF
u
23.5
Pg/g
23.5 297
67562-39-4
1,2,3,4,6,7,8-HpCDF
575
Pg/g
17.7 297
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
33.2
Pg/g
33.2 297
39001-02-0
1,2,3,4,6,7,8,9-OCDF
745
Pg/g
117 593
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2030
2370
Pg/g
85.4
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2070
2370
Pg/g
87.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2090
2370
Pg/g
87.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2160
2370
Pg/g
91.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1860
2370
Pg/g
78.2
(23%-140%)
13C-OCDD
2530
4750
Pg/g
53.3
(17%-157%)
13C-2,3,7,8-TCDF
2260
2370
Pg/g
95.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2150
2370
Pg/g
90.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
2130
2370
Pg/g
89.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2220
2370
Pg/g
93.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2270
2370
Pg/g
95.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2200
2370
Pg/g
92.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1850
2370
Pg/g
78.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1840
2370
Pg/g
77.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1680
2370
Pg/g
70.7
(26%-13 8%)
3701-2,3,7,8-TCDD
290
237
Pg/g
122
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 36
-------
Cape Fear Analytical LLC
Report Date: June 23,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6223
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6223006
Date Collected:
06/09/2014 17:00
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/10/2014 10:15
%Moisture:
22
Client ID:
SFRA-95
Prep Basis:
Dry Weight
Batch ID:
26130
Method:
EPA Method 1613B
Run Date:
06/17/2014 10:04
Analyst:
JTF
Instrument:
HRP763
Data File:
bl6junl4a-7
Dilution:
5
Prep Batch:
26128
Prep Method:
SW846 3540C
Prep Date:
ll-JUN-14
Prep Aliquot:
1.08 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
88.3
Pg/g
18.8
59.3
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 18 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6223
Lab Sample ID: 6223007
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/09/2014 17:02
06/10/201410:15
Project: TETR00114
Matrix: SOLID
%Moisture: 22.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-96
26130
06/17/2014 10:57
A17JUN14A-4
26128
ll-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.24 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
964
Pg/g
3.00 10.4
40321-76-4
1,2,3,7,8-PeCDD
U
4.12
Pg/g
4.12 52.1
39227-28-6
1,2,3,4,7,8-HxCDD
QU
11.1
Pg/g
11.1 52.1
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
34.7
Pg/g
12.2 52.1
19408-74-3
1,2,3,7,8,9-HxCDD
U
12.3
Pg/g
12.3 52.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
376
Pg/g
12.8 52.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9070
Pg/g
69.1 104
51207-31-9
2,3,7,8-TCDF
J
8.31
Pg/g
3.67 10.4
57117-41-6
1,2,3,7,8-PeCDF
J
3.79
Pg/g
3.58 52.1
57117-31-4
2,3,4,7,8-PeCDF
J
3.85
Pg/g
3.54 52.1
70648-26-9
1,2,3,4,7,8-HxCDF
J
7.52
Pg/g
7.04 52.1
57II7.44.9
1,2,3,6,7,8-HxCDF
u
7.56
Pg/g
7.56 52.1
60851-34-5
2,3,4,6,7,8-HxCDF
u
7.14
Pg/g
7.14 52.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
10.9
Pg/g
10.9 52.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
74.7
Pg/g
4.06 52.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
7.98
Pg/g
7.02 52.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
220
Pg/g
30.6 104
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1690
2080
Pg/g
81.3
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1800
2080
Pg/g
86.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1630
2080
Pg/g
78.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1680
2080
Pg/g
80.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1810
2080
Pg/g
86.9
(23%-140%)
13C-OCDD
3140
4160
Pg/g
75.4
(17%-157%)
13C-2,3,7,8-TCDF
1740
2080
Pg/g
83.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1750
2080
Pg/g
84.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1700
2080
Pg/g
81.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1580
2080
Pg/g
76.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1600
2080
Pg/g
76.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1590
2080
Pg/g
76.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1460
2080
Pg/g
70.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1680
2080
Pg/g
80.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1610
2080
Pg/g
77.2
(26%-13 8%)
3701-2,3,7,8-TCDD
193
208
Pg/g
92.7
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6223
Lab Sample ID: 6223008
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/09/2014 17:05
06/10/201410:15
Project: TETR00114
Matrix: SOLID
%Moisture: 20
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-97
26130
06/17/2014 23:38
A17JUN14C-9
26128
ll-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.05 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
145
Pg/g
1.43 11.9
40321-76-4
1,2,3,7,8-PeCDD
U
1.86
Pg/g
1.86 59.6
39227-28-6
1,2,3,4,7,8-HxCDD
QU
4.48
Pg/g
4.48 59.6
57653-85-7
1,2,3,6,7,8-HxCDD
JQ
7.55
Pg/g
5.27 59.6
19408-74-3
1,2,3,7,8,9-HxCDD
U
5.19
Pg/g
5.19 59.6
35822-46-9
1,2,3,4,6,7,8-HpCDD
116
Pg/g
5.48 59.6
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7400
Pg/g
22.0 119
51207-31-9
2,3,7,8-TCDF
J
2.74
Pg/g
1.85 11.9
57117-41-6
1,2,3,7,8-PeCDF
J
2.81
Pg/g
1.18 59.6
57117-31-4
2,3,4,7,8-PeCDF
u
1.11
Pg/g
1.11 59.6
70648-26-9
1,2,3,4,7,8-HxCDF
J
4.31
Pg/g
1.45 59.6
57II7.44.9
1,2,3,6,7,8-HxCDF
J
1.74
Pg/g
1.54 59.6
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.33
Pg/g
2.33 59.6
72918-21-9
1,2,3,7,8,9-HxCDF
J
2.62
Pg/g
2.45 59.6
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
29.9
Pg/g
1.60 59.6
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
4.84
Pg/g
2.93 59.6
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
70.4
Pg/g
4.84 119
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2000
2380
Pg/g
84.2
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2090
2380
Pg/g
87.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
Q 1830
2380
Pg/g
76.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
Q 1750
2380
Pg/g
73.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2020
2380
Pg/g
84.9
(23%-140%)
13C-OCDD
3290
4760
Pg/g
69.0
(17%-157%)
13C-2,3,7,8-TCDF
2290
2380
Pg/g
96.0
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2170
2380
Pg/g
90.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
2200
2380
Pg/g
92.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2060
2380
Pg/g
86.4
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1970
2380
Pg/g
82.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2070
2380
Pg/g
86.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1840
2380
Pg/g
77.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2020
2380
Pg/g
84.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1850
2380
Pg/g
77.6
(26%-13 8%)
3701-2,3,7,8-TCDD
243
238
Pg/g
102
(35%-197%)
Comments:
J Value is estimated
Q Quantitative Interference
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 20 of 3 6
-------
Quality Control
Summary
Page 21 of 36
-------
( ape Fear \lltllytictll LLC Report Date: June 23, 2014
Hi-Res Dioxins/Furans Page 1 of 5
Surrogate Recovery Report
SDG Number: 6223
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010638
LCSD for batch 26128
12010636
MB for batch 26128
6223001
SFRA-90
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
102
111
104
103
114
101
115
118
116
111
105
108
102
112
108
124
74.2
82.4
74.2
71.5
81.8
72.8
81.8
88.8
85.6
78.5
75.3
77.5
70.3
80.2
78.2
93.7
89.7
98.2
93.3
73.7
93.0
95.0
94.6
107
104
88.3
83.4
86.1
82.1
90.1
90.9
106
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6223002
SFRA-91
13C-2,3,7,8-TCDD
81.3
(25%-164%)
Page 22 of 3 6
-------
( ape Fear \lltllytictll LLC Report Date: June 23, 2014
Hi-Res Dioxins/Furans Page 2 of 5
Surrogate Recovery Report
SDG Number: 6223
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6223002
SFRA-91
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
86.7
82.5
57.2
101
98.2
90.2
92.3
91.6
93.1
87.4
92.1
82.8
95.1
97.9
96.5
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6223003
SFRA-92
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
85.9
93.0
87.4
86.1
94.2
85.3
94.5
97.1
98.0
89.5
89.7
90.2
84.0
90.8
91.9
99.2
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6223004
SFRA-93
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
89.5
97.9
85.8
84.3
90.9
86.5
95.4
104
103
84.5
84.3
83.9
82.0
89.1
86.2
103
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6223005
SFRA-94
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
84.8
99.1
(25%-
(25%-
64%)
81%)
Page 23 of 36
-------
( ape Fear \lltllytictll LLC Report Date: June 23, 2014
Hi-Res Dioxins/Furans Page 3 of 5
Surrogate Recovery Report
SDG Number: 6223
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6223005
SFRA-94
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
83.3
82.2
93.0
87.6
94.7
85.3
103
85.6
84.6
86.2
78.3
88.4
88.9
103
(32%-141%)
(28%-130%)
(23%-140%)
(17%-15 7%)
(24%-169%)
(24%-185%)
(21%-178%)
(26%-152%)
(26%-123%)
(28%-13 6%)
(29%-147%)
(28%-143%)
(26%-13 8%)
(35%-197%)
12010639
SFRA-90(6223001MS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
88.0
95.3
94.7
63.2
86.1
85.4
90.9
101
98.4
81.1
78.1
80.1
71.4
84.1
83.9
101
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%)
181%)
141%)
130%)
140%)
157%)
169%)
185%)
178%)
152%)
123%)
136%)
147%)
143%)
138%)
197%)
12010640
SFRA-90(6223001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
80.5
92.2
78.1
74.1
80.4
81.8
85.0
93.0
91.3
75.8
76.3
76.6
71.8
79.6
78.6
95.1
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%)
181%)
141%)
130%)
140%)
157%)
169%)
185%)
178%)
152%)
123%)
136%)
147%)
143%)
138%)
197%)
12010637
LCS for batch 26128
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
67.8
69.7
64.8
(20%-175%)
(21%-227%)
(21%-193%)
Page 24 of 3 6
-------
( ape Fear \lltllytictll LLC Report Date: June 23, 2014
Hi-Res Dioxins/Furans Page 4 of 5
Surrogate Recovery Report
SDG Number: 6223
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010637
LCS for batch 26128
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
73.0
60.2
50.8
67.0
69.5
66.5
61.2
67.0
62.7
54.1
60.1
53.1
91.0
(25%-163%)
(22%-166%)
(13%-199%)
(22%-152%)
(21%-192%)
(13%-328%)
(19%-202%)
(21%-159%)
(22%-176%)
(17%-205%)
(21%-15 8%)
(20%-186%)
(31%-191%)
6223007
SFRA-96
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
81.3
86.5
78.3
80.9
86.9
75.4
83.6
84.2
81.7
76.1
76.9
76.4
70.0
80.7
77.2
92.7
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%)
181%)
141%)
130%)
140%)
157%)
169%)
185%)
178%)
152%)
123%)
136%)
147%)
143%)
138%)
197%)
6223008
SFRA-97
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
Q
Q
84.2
87.7
76.9
73.3
84.9
69.0
96.0
90.9
92.1
86.4
82.6
86.9
77.2
84.9
77.6
102
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%)
181%)
141%)
130%)
140%)
157%)
169%)
185%)
178%)
152%)
123%)
136%)
147%)
143%)
138%)
197%)
6223006
SFRA-95
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
13C-1,2,3,6,7,8-HxCDD
85.4 D
87.3 D
87.9 D
91.2 D
(25%-164%)
(25%-181%)
(32%-141%)
(28%-130%)
Page 25 of 36
-------
Cape Fear Analytical LLC
Report Date: June 23, 2014
Hi-Res Dioxins/Furans
Surrogate Recovery Report
SDG Number: 6223
Matrix Type: SOLID
of 5
Sample ID Client ID
Recovery Acceptance
Surrogate
QUAL (%)
Limits
13C-l,2,3,4,6,7,8-HpCDD
78.2
D
(23%-
140%
13C-OCDD
53.3
D
(17%-
157%
13C-2,3,7,8-TCDF
95.3
D
(24%-
169%
13C-l,2,3,7,8-PeCDF
90.6
D
(24%-
185%
13C-2,3,4,7,8-PeCDF
89.8
D
(21%-
178%
13C-l,2,3,4,7,8-HxCDF
93.3
D
(26%-
152%
13C-l,2,3,6,7,8-HxCDF
95.5
D
(26%-
123%
13C-2,3,4,6,7,8-HxCDF
92.8
D
(28%-
136%
13C-l,2,3,7,8,9-HxCDF
78.1
D
(29%-
147%
13C-l,2,3,4,6,7,8-HpCDF
77.5
D
(28%-
143%
13C-l,2,3,4,7,8,9-HpCDF
70.7
D
(26%-
138%
37Cl-2,3,7,8-TCDD
122
D
(35%-
197%
6223006
SFRA-95
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 26 of 3 6
-------
Cape Fear Analytical LLC
Report Date: June 23, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/17/2014 10:09 Dilution: 1
Prep Batch ID:26128
Batch ID: 26130
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
19.1
95.3
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
96.8
96.8
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
94.4
94.4
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
97.8
97.8
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
97.0
97
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
95.8
95.8
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
203
101
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
18.2
91
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
95.8
95.8
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
93.7
93.7
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
101
101
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
93.6
93.6
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
96.5
96.5
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
105
105
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
97.6
97.6
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
94.2
94.2
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
178
89.1
63-170
SDG Number: 6223
Client ID: LCS for batch 26128
Lab Sample ID: 12010637
Instrument: HRP750
Analyst: JTF
Page
27 of 36
-------
Cape Fear Analytical LLC
Report Date: June 23, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/12/2014 16:05 Dilution: 1
Prep Batch ID:26128
Batch ID: 26130
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
22.7
113
67-158
17.4
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
108
108
70-142
11.3
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
108
108
70-164
13.5
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
106
106
76-134
8.24
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
114
114
64-162
15.9
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
106
106
70-140
9.85
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
213
107
78-144
5.05
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
20.0
99.8
75-158
9.27
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
106
106
80-134
10.5
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
106
106
68-160
11.9
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
103
103
72-134
2.11
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
105
105
84-130
11.6
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
104
104
70-156
7.91
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
108
108
78-130
2.87
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
101
101
82-122
3.50
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
103
103
78-138
9.22
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
207
103
63-170
14.8
0-20
SDG Number: 6223
Client ID: LCSD for batch 26128
Lab Sample ID: 12010638
Instrument: HRP750
Analyst: JTF
Page
28 of 36
-------
Cape Fear Analytical LLC
Report Date: June 23, 2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
255
764
86.4
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1280
U
1310
103
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1280
U
1280
100
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1280
1400
101
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1280
J
1440
110
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1280
3950
136 *
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2550
35100
283 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
255
J
249
94.4
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1280
J
1240
96.7
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1280
J
1260
98.2
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1280
J
1250
95
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1280
J
1260
98.1
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1280
J
1250
96.5
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1280
J
1260
98.1
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1280
1580
97.4
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1280
J
1250
95.7
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2550
3550
104
70-130
SDG Number: 6223
Client ID: SFRA-90(6223001MS)
Lab Sample ID: 12010639
Instrument: HRP750
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 22.5
Analysis Date: 06/13/2014 04:15
Prep Batch ID:26128
Batch ID: 26130
Page 29 of 3 6
-------
Cape Fear Analytical LLC
Report Date: June 23, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 22.5
Analysis Date: 06/13/2014 05:04 Dilution: 1
Prep Batch ID:26128
Batch ID: 26130
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
249
819
111
70-130
6.93
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1240
U
1220
98
70-130
7.45
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1240
U
1280
103
70-130
0.184
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1240
1330
97.9
70-130
5.63
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1240
J
1370
108
70-130
4.68
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1240
3370
92.4
70-130
16.1
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2490
31900
163 *
70-130
9.43
0-20
51207-31-9
MSD
2,3,7,8-TCDF
249
J
252
97.7
70-130
0.942
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1240
J
1240
99
70-130
0.217
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1240
J
1260
100
70-130
0.282
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1240
J
1250
98
70-130
0.503
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1240
J
1260
99.9
70-130
0.663
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1240
J
1250
98.5
70-130
0.481
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1240
J
1290
103
70-130
2.54
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1240
1500
94
70-130
4.73
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1240
J
1220
95.4
70-130
2.74
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2490
3420
101
70-130
3.85
0-20
SDG Number: 6223
Client ID: SFRA-90(6223001MSD)
Lab Sample ID: 12010640
Instrument: HRP750
Analyst: JTF
Page
30 of 36
-------
Cape Fear Analytical LLC
Report Date: June 23,2014
Method Blank Summary Page ' °' '
SDG Number: 6223
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 26128
Instrument ID:
HRP750
Data File:
A11JUN14A 3-5
Lab Sample ID: 12010636
Column:
Prep Date:
ll-JUN-14
Analyzed:
06/12/14 16:53
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCSD for batch 26128
12010638
A11JUN14A3-4
06/12/14
1605
02 SFRA-90
6223001
A11JUN14A3-6
06/12/14
1741
03 SFRA-91
6223002
A11JUN14A3-7
06/12/14
1830
04 SFRA-92
6223003
A11JUN14A3-8
06/12/14
1918
05 SFRA-93
6223004
A11JUN14A3-9
06/12/14
2006
06 SFRA-94
6223005
A11JUN14A3-10
06/12/14
2054
07 SFRA-90(6223001MS)
12010639
A11JUN14A4-5
06/13/14
0415
08 SFRA-90(6223001MSD)
12010640
A11JUN14A4-6
06/13/14
0504
09 SFRA-94
6223005
bl6junl4a-6
06/17/14
0944
10 SFRA-95
6223006
bl6junl4a-7
06/17/14
1004
11 LCS for batch 26128
12010637
A17JUN14A-3
06/17/14
1009
12 SFRA-96
6223007
A17JUN14A-4
06/17/14
1057
13 SFRA-97
6223008
A17JUN14C-9
06/17/14
2338
14 SFRA-95
6223006
A17JUN14C-10
06/18/14
0027
Page 31 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6223
12010636
QC for batch 26128
MB for batch 26128
26130
06/12/2014 16:53
A11JUN14A 3-5
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
26128
Prep Method:
SW846 3540C
Prep Date:
ll-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.168
Pg/g
0.168
1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.372
Pg/g
0.130
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
J
0.466
Pg/g
0.358
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.498
Pg/g
0.498
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.596
Pg/g
0.382
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.638
Pg/g
0.270
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
2.40
Pg/g
0.534
10.0
51207-31-9
2,3,7,8-TCDF
J
0.162
Pg/g
0.140
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.462
Pg/g
0.131
5.00
57117-31-4
2,3,4,7,8-PeCDF
J
0.428
Pg/g
0.135
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.614
Pg/g
0.216
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
J
0.464
Pg/g
0.218
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.584
Pg/g
0.584
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.744
Pg/g
0.310
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.710
Pg/g
0.188
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.618
Pg/g
0.618
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
1.42
Pg/g
0.490
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
148
200
Pg/g
74.2
(25 %-164%)
13C-1,2,3,7,8-PeCDD
165
200
Pg/g
82.4
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
148
200
Pg/g
74.2
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
143
200
Pg/g
71.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
164
200
Pg/g
81.8
(23%-140%)
13C-OCDD
291
400
Pg/g
72.8
(17%-157%)
13C-2,3,7,8-TCDF
164
200
Pg/g
81.8
(24%-169%)
13C-1,2,3,7,8-PeCDF
178
200
Pg/g
88.8
(24%-185%)
13C-2,3,4,7,8-PeCDF
171
200
Pg/g
85.6
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
157
200
Pg/g
78.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
151
200
Pg/g
75.3
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
155
200
Pg/g
77.5
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
141
200
Pg/g
70.3
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
160
200
Pg/g
80.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
156
200
Pg/g
78.2
(26%-13 8%)
37Cl-2,3,7,8-TCDD
18.7
20.0
Pg/g
93.7
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 32 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6223
Lab Sample ID: 12010637
Client Sample: *or batch 26128
Client ID: LCS for batch 26128
Batch ID: 26130
Run Date: 06/17/2014 10:09
Data File: A17JUN14A-3
Prep Batch: 26128
Prep Date: ll-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
19.1
Pg/g
0.248 1.00
40321-76-4
1,2,3,7,8-PeCDD
96.8
Pg/g
0.374 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
94.4
Pg/g
1.18 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
97.8
Pg/g
1.19 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
97.0
Pg/g
1.26 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.8
Pg/g
1.46 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
203
Pg/g
3.88 10.0
51207-31-9
2,3,7,8-TCDF
18.2
Pg/g
0.260 1.00
57117-41-6
1,2,3,7,8-PeCDF
95.8
Pg/g
0.684 5.00
57117-31-4
2,3,4,7,8-PeCDF
93.7
Pg/g
0.656 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
101
Pg/g
1.33 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
93.6
Pg/g
1.24 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
96.5
Pg/g
1.33 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
105
Pg/g
2.08 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
97.6
Pg/g
1.20 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
94.2
Pg/g
2.04 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
178
Pg/g
3.16 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
136
200
Pg/g
67.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
139
200
Pg/g
69.7
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
130
200
Pg/g
64.8
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
146
200
Pg/g
73.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
120
200
Pg/g
60.2
(22%-166%)
13C-OCDD
203
400
Pg/g
50.8
(13%-199%)
13C-2,3,7,8-TCDF
134
200
Pg/g
67.0
(22%-152%)
13C-1,2,3,7,8-
PeCDF
139
200
Pg/g
69.5
(21%-192%)
130-2,3,4,7,8-
PeCDF
133
200
Pg/g
66.5
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
122
200
Pg/g
61.2
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
134
200
Pg/g
67.0
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
125
200
Pg/g
62.7
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
108
200
Pg/g
54.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
120
200
Pg/g
60.1
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
106
200
Pg/g
53.1
(20%-186%)
3701-2,3,7,8-TCDD
18.2
20.0
Pg/g
91.0
(31 %-191%)
Comments:
Page 33 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6223
12010638
QC for batch 26128
LCSD for batch 26128
26130
06/12/2014 16:05
A11JUN14A 3-4
26128
ll-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
22.7
Pg/g
0.0904 1.00
40321-76-4
1,2,3,7,8-PeCDD
108
Pg/g
0.200 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
108
Pg/g
0.312 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
106
Pg/g
0.326 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
114
Pg/g
0.340 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
106
Pg/g
0.416 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
213
Pg/g
0.682 10.0
51207-31-9
2,3,7,8-TCDF
20.0
Pg/g
0.0948 1.00
57117-41-6
1,2,3,7,8-PeCDF
106
Pg/g
0.196 5.00
57117-31-4
2,3,4,7,8-PeCDF
106
Pg/g
0.197 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
103
Pg/g
0.312 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
105
Pg/g
0.312 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
104
Pg/g
0.324 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
108
Pg/g
0.464 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
0.262 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
103
Pg/g
0.432 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
207
Pg/g
0.576 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
204
200
Pg/g
102
(20%-175%)
13C-1,2,3,7,8-
PeCDD
221
200
Pg/g
111
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
208
200
Pg/g
104
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
207
200
Pg/g
103
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
228
200
Pg/g
114
(22%-166%)
13C-OCDD
403
400
Pg/g
101
(13%-199%)
13C-2,3,7,8-TCDF
230
200
Pg/g
115
(22%-152%)
13C-1,2,3,7,8-
PeCDF
236
200
Pg/g
118
(21%-192%)
130-2,3,4,7,8-
PeCDF
233
200
Pg/g
116
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
222
200
Pg/g
111
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
210
200
Pg/g
105
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
216
200
Pg/g
108
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
205
200
Pg/g
102
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
224
200
Pg/g
112
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
216
200
Pg/g
108
(20%-186%)
3701-2,3,7,8-TCDD
24.8
20.0
Pg/g
124
(31 %-191%)
Conunents:
Page 34 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6223
12010639
QC for batch 26128
SFRA-90(6223001MS)
26130
06/13/2014 04:15
A11JUN14A 4-5
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
06/09/2014 15:45
06/10/2014 10:15
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
22.5
Dry Weight
HRP750
1
Prep Batch:
26128
Prep Method:
SW846 3540C
Prep Date:
ll-JUN-14
Prep Aliquot:
1.01 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
764
Pg/g
1.98
12.8
40321-76-4
1,2,3,7,8-PeCDD
1310
Pg/g
4.24
63.9
39227-28-6
1,2,3,4,7,8-HxCDD
1280
Pg/g
12.2
63.9
57653-85-7
1,2,3,6,7,8-HxCDD
1400
Pg/g
12.9
63.9
19408-74-3
1,2,3,7,8,9-HxCDD
1440
Pg/g
13.4
63.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
3950
Pg/g
16.5
63.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
35100
Pg/g
33.2
128
51207-31-9
2,3,7,8-TCDF
249
Pg/g
2.91
12.8
57117-41-6
1,2,3,7,8-PeCDF
1240
Pg/g
3.58
63.9
57117-31-4
2,3,4,7,8-PeCDF
1260
Pg/g
3.50
63.9
70648-26-9
1,2,3,4,7,8-HxCDF
1250
Pg/g
8.61
63.9
57II7.44.9
1,2,3,6,7,8-HxCDF
1260
Pg/g
8.71
63.9
60851-34-5
2,3,4,6,7,8-HxCDF
1250
Pg/g
10.7
63.9
72918-21-9
1,2,3,7,8,9-HxCDF
1260
Pg/g
8.66
63.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
1580
Pg/g
5.85
63.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
1250
Pg/g
9.94
63.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
3550
Pg/g
15.8
128
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2250
2550
Pg/g
88.0
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2430
2550
Pg/g
95.3
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
2420
2550
Pg/g
94.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1610
2550
Pg/g
63.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2200
2550
Pg/g
86.1
(23%-140%)
13C-OCDD
4360
5110
Pg/g
85.4
(17%-157%)
13C-2,3,7,8-TCDF
2320
2550
Pg/g
90.9
(24%-169%)
13C-1,2,3,7,8-PeCDF
2580
2550
Pg/g
101
(24%-185%)
13C-2,3,4,7,8-PeCDF
2510
2550
Pg/g
98.4
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
2070
2550
Pg/g
81.1
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2000
2550
Pg/g
78.1
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2040
2550
Pg/g
80.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1820
2550
Pg/g
71.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2150
2550
Pg/g
84.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2140
2550
Pg/g
83.9
(26%-13 8%)
37Cl-2,3,7,8-TCDD
258
255
Pg/g
101
(35%-197%)
Comments:
Page 35 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 23,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6223
12010640
QC for batch 26128
SFRA-90(6223001MSD)
26130
06/13/2014 05:04
A11JUN14A 4-6
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
06/09/2014 15:45
06/10/2014 10:15
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
22.5
Dry Weight
HRP750
1
Prep Batch:
26128
Prep Method:
SW846 3540C
Prep Date:
ll-JUN-14
Prep Aliquot:
1.036 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
819
Pg/g
1.48
12.4
40321-76-4
1,2,3,7,8-PeCDD
1220
Pg/g
3.91
62.2
39227-28-6
1,2,3,4,7,8-HxCDD
1280
Pg/g
7.62
62.2
57653-85-7
1,2,3,6,7,8-HxCDD
1330
Pg/g
8.07
62.2
19408-74-3
1,2,3,7,8,9-HxCDD
1370
Pg/g
8.34
62.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
3370
Pg/g
14.8
62.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
31900
Pg/g
34.1
124
51207-31-9
2,3,7,8-TCDF
252
Pg/g
2.76
12.4
57117-41-6
1,2,3,7,8-PeCDF
1240
Pg/g
3.88
62.2
57117-31-4
2,3,4,7,8-PeCDF
1260
Pg/g
4.06
62.2
70648-26-9
1,2,3,4,7,8-HxCDF
1250
Pg/g
8.09
62.2
57II7.44.9
1,2,3,6,7,8-HxCDF
1260
Pg/g
8.34
62.2
60851-34-5
2,3,4,6,7,8-HxCDF
1250
Pg/g
9.01
62.2
72918-21-9
1,2,3,7,8,9-HxCDF
1290
Pg/g
9.51
62.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
1500
Pg/g
5.30
62.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
1220
Pg/g
8.14
62.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
3420
Pg/g
16.1
124
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2000
2490
Pg/g
80.5
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2300
2490
Pg/g
92.2
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1950
2490
Pg/g
78.1
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1850
2490
Pg/g
74.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2000
2490
Pg/g
80.4
(23%-140%)
13C-OCDD
4070
4980
Pg/g
81.8
(17%-157%)
13C-2,3,7,8-TCDF
2120
2490
Pg/g
85.0
(24%-169%)
13C-1,2,3,7,8-PeCDF
2310
2490
Pg/g
93.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
2270
2490
Pg/g
91.3
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1890
2490
Pg/g
75.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1900
2490
Pg/g
76.3
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1910
2490
Pg/g
76.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1790
2490
Pg/g
71.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1980
2490
Pg/g
79.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1960
2490
Pg/g
78.6
(26%-13 8%)
37Cl-2,3,7,8-TCDD
237
249
Pg/g
95.1
(35%-197%)
Comments:
Page 36 of 36
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 17. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6228
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 12, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of22
problem solved
-------
Page;.
Project #:
CFAQuote#:
COC Number(,):
PO Number:
~T_
of
Cflpc Fear -/Vniily LLC
Chain of Custody and Analytical Request
CFA Work Order Number: ~) ^7
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910)795-0421
1
.Client Name: -^1 (l ?-£??$¦
Sample Analysis Requested(5) (Fill in the number of containers for each test)
Project/Site Name: <£ J. £, C £¦ -
In
Collected by: jt> ,JL J Send Results To:
> /X Ktei/r*'*- v*l«wTte
Sample ID
* For composites - indicate start and stop date/time
•Date Collected
(mm-dd-yy)
~Time*
Collected
(Military)
(hhmio)
QC Code
m
Field
Filtered *3!
Sample
Matrix w
_jr/vd'f ~ 7r
/SbS"
5
t
*
"TT
*(.-({-N
tS*(o
£»
(
TAT Requested: Normal:
Rush:
^ Specify: %£
¦ubject to Surcharge)
Fax Results:
Yes
No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 i\. Level j>/ Level 4
Remarks; Are there any known hazards applicable to these samples? If so, please list the hazards
Sample Collection Time Zone
Eastern Pacific
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Mountain
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Sample Shipping and Delivery Details
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Ct^>JLud%£ut%4' fUkfiJi*! fQOQ
CFA PM:
4i
Method of Shipment:
KlU L
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
-f"Ex
Work Order: (j)2Jb%
Shipping Company. (^L ^
Date/Time Received: / '2-J ft/U/4 | OOD
Suspected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
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Screened <0.5 mR/hr?
Samples identified as Foreign Soil?
Samples < 2k background?
* Notify R50 of any responses in this column immediately.
Air Sample Receipt Specifics
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NA
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Air sennple in shipment7
Page 3 of22
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 22
-------
Case Narrative
Page 5 of22
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6228
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26174
Clean Up Batch Number: 26173
Extraction Batch Number: 26172
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6228001 SFRA-98
6228002 SFRA-99
12010679 Method Blank (MB)
12010680 Laboratory Control Sample (LCS)
12010681 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of 22
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 26174.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. 6228001 (SFRA-98) and 6228002 (SFRA-99)
-Batch 26174.
Sample Dilutions
Sample 6228002 (SFRA-99)- Batch 26174 was diluted due to the presence of over-range target
analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Page 7 of22
-------
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 22
-------
Sample Data Summary
Page 9 of 22
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6228 CFA Work Order: 6228
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 17 JUN 2014 Title: Data Validator
Page 10 of 22
-------
Cape Fear Analytical LLC
Report Date:
June 17,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6228
Lab Sample ID: 6228001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/11/2014 15:05
06/12/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 20.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-98
26174
06/16/2014 13:56
A16JUN14A-3
26172
12-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.03 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3190
Pg/g
1.40 12.2
40321-76-4
1,2,3,7,8-PeCDD
J
4.21
Pg/g
1.35 61.1
39227-28-6
1,2,3,4,7,8-HxCDD
U
3.38
Pg/g
3.38 61.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
43.9
Pg/g
3.47 61.1
19408-74-3
1,2,3,7,8,9-HxCDD
J
15.7
Pg/g
3.64 61.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
801
Pg/g
6.48 61.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
20400
Pg/g
31.8 122
51207-31-9
2,3,7,8-TCDF
20.1
Pg/g
1.78 12.2
57117-41-6
1,2,3,7,8-PeCDF
J
3.30
Pg/g
1.76 61.1
57117-31-4
2,3,4,7,8-PeCDF
J
5.53
Pg/g
1.72 61.1
70648-26-9
1,2,3,4,7,8-HxCDF
J
11.3
Pg/g
1.97 61.1
57II7.44.9
1,2,3,6,7,8-HxCDF
J
7.36
Pg/g
2.01 61.1
60851-34-5
2,3,4,6,7,8-HxCDF
J
10.1
Pg/g
2.06 61.1
72918-21-9
1,2,3,7,8,9-HxCDF
J
4.94
Pg/g
3.03 61.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
163
Pg/g
2.33 61.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
15.9
Pg/g
3.89 61.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
377
Pg/g
4.55 122
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1840
2450
Pg/g
75.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1910
2450
Pg/g
78.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1930
2450
Pg/g
78.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1870
2450
Pg/g
76.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1980
2450
Pg/g
81.0
(23%-140%)
13C-OCDD
3760
4890
Pg/g
76.9
(17%-157%)
13C-2,3,7,8-TCDF
1950
2450
Pg/g
79.9
(24%-169%)
130-1,2,3,7,8-
PeCDF
1960
2450
Pg/g
80.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1960
2450
Pg/g
80.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1920
2450
Pg/g
78.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1920
2450
Pg/g
78.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2450
Pg/g
78.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1750
2450
Pg/g
71.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1880
2450
Pg/g
76.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1750
2450
Pg/g
71.4
(26%-13 8%)
3701-2,3,7,8-TCDD
207
245
Pg/g
84.5
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 22
-------
Cape Fear Analytical LLC
Report Date: June 17,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6228
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6228001
Date Collected:
06/11/2014 15:05
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/12/2014 10:00
%Moisture:
20.6
Client ID:
SFRA-98
Prep Basis:
Dry Weight
Batch ID:
26174
Method:
EPA Method 1613B
Run Date:
06/17/2014 09:06
Analyst:
JTF
Instrument:
HRP763
Data File:
bl6junl4a-4
Dilution:
1
Prep Batch:
26172
Prep Method:
SW846 3540C
Prep Date:
12-JUN-14
Prep Aliquot:
1.03 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
19.0
Pg/g
3.28
12.2
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 22
-------
Cape Fear Analytical LLC
Report Date:
June 17,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6228
Lab Sample ID: 6228002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/11/201415:10
06/12/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 23.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-99
26174
06/16/2014 15:41
A16JUN14A-5
26172
12-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.47 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3940
Pg/g
7.17 44.5
40321-76-4
1,2,3,7,8-PeCDD
U
7.83
Pg/g
7.83 222
39227-28-6
1,2,3,4,7,8-HxCDD
u
17.3
Pg/g
17.3 222
57653-85-7
1,2,3,6,7,8-HxCDD
J
44.8
Pg/g
17.7 222
19408-74-3
1,2,3,7,8,9-HxCDD
J
21.1
Pg/g
18.7 222
35822-46-9
1,2,3,4,6,7,8-HpCDD
539
Pg/g
19.6 222
3268-87-9
1,2,3,4,6,7,8,9-OCDD
10600
Pg/g
93.4 445
51207-31-9
2,3,7,8-TCDF
J
28.0
Pg/g
6.83 44.5
57117-41-6
1,2,3,7,8-PeCDF
u
6.6
Pg/g
6.60 222
57117-31-4
2,3,4,7,8-PeCDF
u
6.65
Pg/g
6.65 222
70648-26-9
1,2,3,4,7,8-HxCDF
J
11.3
Pg/g
6.23 222
57II7.44.9
1,2,3,6,7,8-HxCDF
u
6.64
Pg/g
6.64 222
60851-34-5
2,3,4,6,7,8-HxCDF
u
8.29
Pg/g
8.29 222
72918-21-9
1,2,3,7,8,9-HxCDF
u
10.4
Pg/g
10.4 222
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
150
Pg/g
6.73 222
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
12.4
Pg/g
11.4 222
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
212
Pg/g
22.6 445
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1380
1780
Pg/g
77.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1490
1780
Pg/g
83.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1410
1780
Pg/g
79.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1460
1780
Pg/g
81.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1320
1780
Pg/g
74.4
(23%-140%)
13C-OCDD
2270
3560
Pg/g
63.7
(17%-157%)
13C-2,3,7,8-TCDF
1460
1780
Pg/g
81.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
1550
1780
Pg/g
86.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
1520
1780
Pg/g
85.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1430
1780
Pg/g
80.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1390
1780
Pg/g
78.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1370
1780
Pg/g
77.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1190
1780
Pg/g
66.6
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1310
1780
Pg/g
73.8
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1180
1780
Pg/g
66.4
(26%-13 8%)
3701-2,3,7,8-TCDD
164
178
Pg/g
92.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 22
-------
Quality Control
Summary
Page 14 of 22
-------
( ape Fear \lltllytictll LLC Report Date: June 17, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6228
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010680
LCS for batch 26172
12010681
LCSD for batch 26172
12010679
MB for batch 26172
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
77.2
83.4
78.5
83.6
82.7
71.7
83.8
88.1
85.5
81.6
84.2
82.3
72.8
80.1
74.4
83.1
73.1
79.1
73.0
80.0
80.7
70.3
81.0
81.2
79.0
77.4
77.9
76.6
71.0
79.7
72.1
80.7
72.9
83.9
73.8
78.7
80.7
73.4
79.0
84.3
84.0
78.0
77.7
78.4
70.7
78.0
77.1
77.4
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6228001
SFRA-98
13C-2,3,7,8-TCDD
75.3
(25%-164%)
Page 15 of 22
-------
( ape Fear \lltllytictll LLC Report Date: June 17, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6228
Matrix Type: SOLID
Sample ID Client ID
6228001 SFRA-98
6228002 SFRA-99
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
78.1
(25%-181%)
78.7
(32%-141%)
76.3
(28%-130%)
81.0
(23%-140%)
76.9
(17%-15 7%)
79.9
(24%-169%)
80.3
(24%-185%)
80.2
(21%-178%)
78.6
(26%-152%)
78.7
(26%-123%)
78.0
(28%-13 6%)
71.4
(29%-147%)
76.7
(28%-143%)
71.4
(26%-13 8%)
84.5
(35%-197%)
77.4
D
(25%-164%)
83.8
D
(25%-181%)
79.3
D
(32%-141%)
81.9
D
(28%-130%)
74.4
D
(23%-140%)
63.7
D
(17%-15 7%)
81.8
D
(24%-169%)
86.9
D
(24%-185%)
85.6
D
(21%-178%)
80.1
D
(26%-152%)
78.2
D
(26%-123%)
77.2
D
(28%-13 6%)
66.6
D
(29%-147%)
73.8
D
(28%-143%)
66.4
D
(26%-13 8%)
92.3
D
(35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 16 of 22
-------
Cape Fear Analytical LLC
Report Date: June 17, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/13/2014 19:06 Dilution: 1
Prep Batch ID:26172
Batch ID: 26174
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.8
109
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
106
106
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
104
104
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
105
105
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
109
109
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
99.6
99.6
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
204
102
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.3
96.7
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
102
102
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
101
101
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
100
100
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
101
101
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
102
102
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
106
106
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
98.8
98.8
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
98.1
98.1
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
191
95.3
63-170
SDG Number: 6228
Client ID: LCS for batch 26172
Lab Sample ID: 12010680
Instrument: HRP750
Analyst: JTF
Page 17 of 22
-------
Cape Fear Analytical LLC
Report Date: June 17, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/13/2014 19:54 Dilution: 1
Prep Batch ID:26172
Batch ID: 26174
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.4
107
67-158
1.95
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
102
102
70-142
3.60
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
99.1
99.1
70-164
5.18
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
106
106
76-134
0.686
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
105
105
64-162
3.74
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
96.8
96.8
70-140
2.89
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
201
101
78-144
1.23
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
18.5
92.6
75-158
4.38
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
97.8
97.8
80-134
4.15
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
100
100
68-160
1.33
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
97.1
97.1
72-134
3.09
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
103
103
84-130
1.43
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
101
101
70-156
1.47
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
102
102
78-130
4.06
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
97.0
97
82-122
1.76
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
99.5
99.5
78-138
1.41
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
193
96.3
63-170
0.984
0-20
SDG Number: 6228
Client ID: LCSD for batch 26172
Lab Sample ID: 12010681
Instrument: HRP750
Analyst: JTF
Page
18 of 22
-------
Cape Fear Analytical LLC
Report Date: June 17,2014
Method Blank Summary Page ' °' '
SDG Number: 6228
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 26172
Instrument ID:
HRP750
Data File:
A11JUN14A 6-3
Lab Sample ID: 12010679
Column:
Prep Date:
12-JUN-14
Analyzed:
06/13/14 20:42
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 26172
12010680
A11JUN14A6-1
06/13/14
1906
02 LCSD for batch 26172
12010681
A11JUN14A6-2
06/13/14
1954
03 SFRA-98
6228001
A16JUN14A-3
06/16/14
1356
04 SFRA-99
6228002
A16JUN14A-5
06/16/14
1541
05 SFRA-98
6228001
bl6junl4a-4
06/17/14
0906
Page 19 of 22
-------
Cape Fear Analytical LLC
Report Date:
June 17,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6228
12010679
QC for batch 26172
MB for batch 26172
26174
06/13/2014 20:42
A11JUN14A 6-3
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
26172
Prep Method:
SW846 3540C
Prep Date:
12-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.0984
Pg/g
0.0984
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.342
Pg/g
0.342
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.464
Pg/g
0.464
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.29
Pg/g
0.290
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.408
Pg/g
0.408
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.470
Pg/g
0.288
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
1.83
Pg/g
1.83
10.0
51207-31-9
2,3,7,8-TCDF
u
.092
Pg/g
0.092
1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.332
Pg/g
0.332
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.312
Pg/g
0.312
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.358
Pg/g
0.358
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.322
Pg/g
0.322
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.39
Pg/g
0.390
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.408
Pg/g
0.236
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.388
Pg/g
0.153
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.462
Pg/g
0.462
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
0.942
Pg/g
0.570
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
146
200
Pg/g
72.9
(25 %-164%)
13C-1,2,3,7,8-PeCDD
168
200
Pg/g
83.9
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
148
200
Pg/g
73.8
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
157
200
Pg/g
78.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
161
200
Pg/g
80.7
(23%-140%)
13C-OCDD
294
400
Pg/g
73.4
(17%-157%)
13C-2,3,7,8-TCDF
158
200
Pg/g
79.0
(24%-169%)
13C-1,2,3,7,8-PeCDF
169
200
Pg/g
84.3
(24%-185%)
13C-2,3,4,7,8-PeCDF
168
200
Pg/g
84.0
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
156
200
Pg/g
78.0
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
155
200
Pg/g
77.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
157
200
Pg/g
78.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
141
200
Pg/g
70.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
156
200
Pg/g
78.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
154
200
Pg/g
77.1
(26%-13 8%)
37Cl-2,3,7,8-TCDD
15.5
20.0
Pg/g
77.4
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 20 of 22
-------
Cape Fear Analytical LLC
Report Date:
June 17,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6228
Lab Sample ID: 12010680
Client Sample: *or batch 26172
Client ID: LCS for batch 26172
Batch ID: 26174
Run Date: 06/13/2014 19:06
Data File: A11JUN14A6-1
Prep Batch: 26172
Prep Date: 12-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.8
Pg/g
0.108 1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.284 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
104
Pg/g
0.660 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
105
Pg/g
0.636 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
109
Pg/g
0.688 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.6
Pg/g
0.582 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
204
Pg/g
1.62 10.0
51207-31-9
2,3,7,8-TCDF
19.3
Pg/g
0.107 1.00
57117-41-6
1,2,3,7,8-PeCDF
102
Pg/g
0.300 5.00
57117-31-4
2,3,4,7,8-PeCDF
101
Pg/g
0.296 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
100
Pg/g
0.682 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
101
Pg/g
0.694 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
102
Pg/g
0.734 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
106
Pg/g
1.13 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
98.8
Pg/g
0.406 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
98.1
Pg/g
0.704 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
191
Pg/g
1.43 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
154
200
Pg/g
77.2
(20%-175%)
130-1,2,3,7,8-
PeCDD
167
200
Pg/g
83.4
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
157
200
Pg/g
78.5
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
167
200
Pg/g
83.6
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
165
200
Pg/g
82.7
(22%-166%)
13C-OCDD
287
400
Pg/g
71.7
(13%-199%)
13C-2,3,7,8-TCDF
168
200
Pg/g
83.8
(22%-152%)
130-1,2,3,7,8-
PeCDF
176
200
Pg/g
88.1
(21%-192%)
130-2,3,4,7,8-
PeCDF
171
200
Pg/g
85.5
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
163
200
Pg/g
81.6
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
168
200
Pg/g
84.2
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
165
200
Pg/g
82.3
(22%-176%)
130-1,2,3,7,8,9-HxCDF
146
200
Pg/g
72.8
(17%-205%)
130-1,2,3,4,6,7,8-HpCDF
160
200
Pg/g
80.1
(21%-15 8%)
130-1,2,3,4,7,8,9-HpCDF
149
200
Pg/g
74.4
(20%-186%)
3701-2,3,7,8-TCDD
16.6
20.0
Pg/g
83.1
(31 %-191%)
Comments:
K Estimated Maximum Possible Concentration
Page 21 of 22
-------
Cape Fear Analytical LLC
Report Date:
June 17,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6228
Lab Sample ID: 12010681
Client Sample: *or batch 26172
Client ID: LCSD for batch 26172
Batch ID: 26174
Run Date: 06/13/2014 19:54
Data File: A11JUN14A 6-2
Prep Batch: 26172
Prep Date: 12-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.4
Pg/g
0.111 1.00
40321-76-4
1,2,3,7,8-PeCDD
102
Pg/g
0.208 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
99.1
Pg/g
0.334 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
106
Pg/g
0.366 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
105
Pg/g
0.372 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
96.8
Pg/g
0.564 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
201
Pg/g
1.16 10.0
51207-31-9
2,3,7,8-TCDF
18.5
Pg/g
0.0912 1.00
57117-41-6
1,2,3,7,8-PeCDF
97.8
Pg/g
0.254 5.00
57117-31-4
2,3,4,7,8-PeCDF
100
Pg/g
0.246 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
97.1
Pg/g
0.420 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
103
Pg/g
0.436 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
101
Pg/g
0.440 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
102
Pg/g
0.704 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
97.0
Pg/g
0.486 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
99.5
Pg/g
0.848 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
193
Pg/g
0.988 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
146
200
Pg/g
73.1
(20%-175%)
13C-1,2,3,7,8-
PeCDD
158
200
Pg/g
79.1
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
146
200
Pg/g
73.0
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
160
200
Pg/g
80.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
161
200
Pg/g
80.7
(22%-166%)
13C-OCDD
281
400
Pg/g
70.3
(13%-199%)
13C-2,3,7,8-TCDF
162
200
Pg/g
81.0
(22%-152%)
13C-1,2,3,7,8-
PeCDF
162
200
Pg/g
81.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
158
200
Pg/g
79.0
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
155
200
Pg/g
77.4
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
156
200
Pg/g
77.9
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
153
200
Pg/g
76.6
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
142
200
Pg/g
71.0
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
159
200
Pg/g
79.7
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
144
200
Pg/g
72.1
(20%-186%)
3701-2,3,7,8-TCDD
16.1
20.0
Pg/g
80.7
(31 %-191%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 22 of 22
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 24. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6255
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 19, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 36
problem solved
-------
Page :.
Project #:
CFAQuote#: _
COC Number0':
PO Number:
T
of
Client Nam'Tgf/P
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: (s\ O ^
Llt n.n,
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd, Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Phone II:
' 3/*{~S"f -f~ £ 7, Sample Analysis Requested(' (Fill in the number of containers for each test)
g Project/Site Name: Sfccs/ <^u f
ro C*.
Address:
ID A, ft* tr lss<* m /,S{o £ JvS *-(
^Collected by: C^stCa.
Send Results To:
ftth, •-»f- <;(g> <
*•<
C.%r/n
Sample ID
* For composites - indicate start and stop date/time
fU
*Date Collected
(mm-dd-yy)
•Time
Collected
(Military)
(tiJimm)
Ik
n> c«
QC Code
9)
Field
Filtered®
Sample
Matrix w
s
a
s
1
f
*
X
- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
s - /oo
SFXJ - /o I
14*1_
/
/ox.
6 -»-(H
efgS
K
/o3
6-fg-rH
v^/s-
/&£>
3
TAT Requested: Normal:
Rush:
^ Specify ^4s uhji
iuhject to Surcharge)
Fax Results:
Yes
No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 /cLevel 3ji Level 4
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
Sample Collection Time Zone
Eastern
Central
Pacific
Other
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Time
5^ 6-fr/i /00^"
CFA PM: C/fide. Ja* /t *S
Method of Shipment:
f*S J. j£jW=Driiikmg Water, GW^roundwater, SW=Surface Water, WW-Waste Water, W^Water, ML~Misc Liquid, $0~Soit4 SD=Sediment, SL^Studge, SS^Solid Waste, 0=Oii, F=Filter, P=Wipe, L'=Urine, F^Fecal. N=Nasal
5.) Sample Analysts Requested: Analytical method requested (i.eJ8290B, 1668B) and number of containers provided for each (Le.8290B -3? 1668B -1), *
6.) Preservative Type; HA = Hydrochloric Acid, NI = Nitric Acid, SII = Sodium Hydroxide, SA = Sulfuric Acid, A A = Ascorbic Acidf HX = Mexane, ST = Sodium Thlosulfate, if no preservative is added = leave field blank
WHITE - LABORATORY YELLOW « FILE PINK = CLIENT
For Lab Receiving Use Only
-------
SAMPLE RECEIPT CHECKLIST
Cope f ear Analytical
1qZ5^
Client:
T&rR-
Work Order:
Shipping Company;
-PejLL^y:
Dste/Time Received
;^=r itjuvit foo^r
Suspected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
No*!
Shipped bs DOT HoJferdous:
Screened <0.5 mR/br?
Samples identified as Foreign Soii7
Samples < 2x background?
"" 1
Air Sample Receipt Specifics | Yes
NA 1 Mo
Air sample in shipment ? (
1
4 Notify RSO of any responses in this column immediately.
s.ir Witness:
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received iniact
and sealed'
Cbcte Applicable.
.efl; biphtn- dsm?ged {Dnumef Jeifcrng tomainei otherldescobt]
Chain of Custody documents included
with shipment?
Samples requiring cold preservation
within G-6"C?
n Method;
6 beg:l blue kt dry ict
oth^j Idfjciibe)
Aqueous samples found to have visible
solids?
Sample iDi. for>l2i/)
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 36
-------
Case Narrative
Page 5 of 36
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6255
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26229
Clean Up Batch Number: 26228
Extraction Batch Number: 26227
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6255001
SFRA-100
6255002
SFRA-101
6255003
SFRA-102
6255004
SFRA-103
6255005
SFRA-104
12010730
Method Blank (MB)
12010731
Laboratory Control Sample (LCS)
12010732
Laboratory Control Sample Duplicate (LCSD)
12010733
6255002(SFRA-101) Matrix Spike (MS)
12010734
6255002(SFRA-101) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Page 6 of 36
-------
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6255002 (SFRA-101) - Batch 26229 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike/Duplicate (MS/MSD) Recovery Statement
One MS recovery for this SDG was not within the acceptance limits. The failure confirms in the
matrix spike duplicate and can be attributed to matrix interference. 12010733 (SFRA-101) and
12010734 (SFRA-101) - Batch 26229.
MS/MSD Relative Percent Difference (RPD) Statement
One relative percent difference (RPD) between the MS and MSD was not within the required
acceptance limits. Sample data is validated based on acceptable LCS/LCSD results. 12010733
(SFRA-101) and 12010734 (SFRA-101) - Batch 26229.
Technical Information
Page 7 of 36
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Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26229.
Sample Dilutions
Samples 6255001 (SFRA-100) and 6255003 (SFRA-102)- Batch 26229 were diluted due to the
presence of over-range target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
The following NCR was generated for this SDG: 644596 12010734 (SFRA-101)- Batch 26229.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 36
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Sample Data Summary
Page 9 of 36
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Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6255 CFA Work Order: 6255
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 24JUN2014 Title: Data Validator
Page 10 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6255
Lab Sample ID: 6255001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/17/2014 14:50
06/19/2014 10:05
Project: TETR00114
Matrix: SOLID
%Moisture: 24.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-100
26229
06/23/2014 10:41
A23JUN14A-3
26227
19-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.47 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
13800
Pg/g
9.42 90.2
40321-76-4
1,2,3,7,8-PeCDD
U
11.4
Pg/g
11.4 451
39227-28-6
1,2,3,4,7,8-HxCDD
u
19.9
Pg/g
19.9 451
57653-85-7
1,2,3,6,7,8-HxCDD
J
66.1
Pg/g
20.0 451
19408-74-3
1,2,3,7,8,9-HxCDD
J
30.5
Pg/g
21.1 451
35822-46-9
1,2,3,4,6,7,8-HpCDD
702
Pg/g
16.9 451
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11200
Pg/g
60.5 902
51207-31-9
2,3,7,8-TCDF
J
73.8
Pg/g
13.6 90.2
57117-41-6
1,2,3,7,8-PeCDF
u
6.33
Pg/g
6.33 451
57117-31-4
2,3,4,7,8-PeCDF
u
12.8
Pg/g
12.8 451
70648-26-9
1,2,3,4,7,8-HxCDF
J
18.8
Pg/g
8.34 451
57II7.44.9
1,2,3,6,7,8-HxCDF
J
11.0
Pg/g
7.98 451
60851-34-5
2,3,4,6,7,8-HxCDF
u
17.7
Pg/g
17.7 451
72918-21-9
1,2,3,7,8,9-HxCDF
J
15.1
Pg/g
14.7 451
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
250
Pg/g
8.88 451
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
25.6
Pg/g
18.4 451
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
324
Pg/g
42.4 902
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1200
1800
Pg/g
66.6
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1120
1800
Pg/g
62.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1240
1800
Pg/g
68.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1240
1800
Pg/g
68.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1130
1800
Pg/g
62.8
(23%-140%)
13C-OCDD
1360
3610
Pg/g
37.6
(17%-157%)
13C-2,3,7,8-TCDF
1370
1800
Pg/g
76.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
1320
1800
Pg/g
73.0
(24%-185%)
130-2,3,4,7,8-
PeCDF
1270
1800
Pg/g
70.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1380
1800
Pg/g
76.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1260
1800
Pg/g
69.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1250
1800
Pg/g
69.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1010
1800
Pg/g
56.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1240
1800
Pg/g
68.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
975
1800
Pg/g
54.0
(26%-13 8%)
3701-2,3,7,8-TCDD
181
180
Pg/g
100
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 36
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Cape Fear Analytical LLC
Report Date: June 24,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number: 6255
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6255002
Date Collected:
06/17/2014 15:00
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
06/19/2014 10:05
%Moisture: 22.2
Client ID:
SFRA-101
Prep Basis: Dry Weight
Batch ID:
26229
Method:
EPA Method 1613B
Run Date:
06/23/2014 12:22
Analyst:
JTF
Instrument: HRP750
Data File:
A23JUN14A-5
Dilution: 1
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.02 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3030
Pg/g
1.89 12.6
40321-76-4
1,2,3,7,8-PeCDD
J
2.09
Pg/g
1.50 63.0
39227-28-6
1,2,3,4,7,8-HxCDD
J
6.30
Pg/g
2.87 63.0
57653-85-7
1,2,3,6,7,8-HxCDD
J
33.2
Pg/g
2.95 63.0
19408-74-3
1,2,3,7,8,9-HxCDD
J
11.4
Pg/g
3.10 63.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
421
Pg/g
4.79 63.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8830
Pg/g
20.7 126
51207-31-9
2,3,7,8-TCDF
18.1
Pg/g
2.09 12.6
57117-41-6
1,2,3,7,8-PeCDF
J
2.65
Pg/g
1.68 63.0
57117-31-4
2,3,4,7,8-PeCDF
J
4.16
Pg/g
1.78 63.0
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.63
Pg/g
1.37 63.0
57II7.44.9
1,2,3,6,7,8-HxCDF
J
4.46
Pg/g
1.39 63.0
60851-34-5
2,3,4,6,7,8-HxCDF
U
6.83
Pg/g
6.83 63.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.32
Pg/g
2.32 63.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
121
Pg/g
1.85 63.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
7.36
Pg/g
7.36 63.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
175
Pg/g
6.70 126
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1750
2520
Pg/g
69.5
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1710
2520
Pg/g
67.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1810
2520
Pg/g
72.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1710
2520
Pg/g
67.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1720
2520
Pg/g
68.2
(23%-140%)
13C-OCDD
2230
5040
Pg/g
44.2
(17%-157%)
13C-2,3,7,8-TCDF
1910
2520
Pg/g
75.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1780
2520
Pg/g
70.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
1760
2520
Pg/g
70.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1870
2520
Pg/g
74.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1740
2520
Pg/g
69.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1750
2520
Pg/g
69.5
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1520
2520
Pg/g
60.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1750
2520
Pg/g
69.4
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1440
2520
Pg/g
57.0
(26%-13 8%)
3701-2,3,7,8-TCDD
216
252
Pg/g
85.7
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6255
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6255002
Date Collected:
06/17/2014 15:00
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/19/2014 10:05
%Moisture:
22.2
Client ID:
SFRA-101
Prep Basis:
Dry Weight
Batch ID:
26229
Method:
EPA Method 1613B
Run Date:
06/23/2014 16:20
Analyst:
JTF
Instrument:
HRP763
Data File:
b23junl4a-4
Dilution:
1
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.02 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
19.4
Pg/g
2.62
12.6
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number: 6255
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6255003
Date Collected:
06/18/2014 09:05
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
06/19/2014 10:05
%Moisture: 22.8
Client ID:
SFRA-102
Prep Basis: Dry Weight
Batch ID:
26229
Method:
EPA Method 1613B
Run Date:
06/23/2014 14:50
Analyst:
JTF
Instrument: HRP750
Data File:
A23JUN14A-8
Dilution: 5
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.59 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3920
Pg/g
4.66 40.8
40321-76-4
1,2,3,7,8-PeCDD
J
10.7
Pg/g
5.07 204
39227-28-6
1,2,3,4,7,8-HxCDD
J
10.5
Pg/g
6.72 204
57653-85-7
1,2,3,6,7,8-HxCDD
J
24.8
Pg/g
6.94 204
19408-74-3
1,2,3,7,8,9-HxCDD
J
16.9
Pg/g
7.25 204
35822-46-9
1,2,3,4,6,7,8-HpCDD
263
Pg/g
11.3 204
3268-87-9
1,2,3,4,6,7,8,9-OCDD
6660
Pg/g
143 408
51207-31-9
2,3,7,8-TCDF
J
22.6
Pg/g
4.42 40.8
57117-41-6
1,2,3,7,8-PeCDF
J
6.81
Pg/g
3.36 204
57117-31-4
2,3,4,7,8-PeCDF
J
10.5
Pg/g
3.46 204
70648-26-9
1,2,3,4,7,8-HxCDF
J
13.3
Pg/g
6.46 204
57II7.44.9
1,2,3,6,7,8-HxCDF
J
9.24
Pg/g
6.54 204
60851-34-5
2,3,4,6,7,8-HxCDF
J
11.5
Pg/g
7.21 204
72918-21-9
1,2,3,7,8,9-HxCDF
J
15.1
Pg/g
12.2 204
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
76.4
Pg/g
4.39 204
55673-89-7
1,2,3,4,7,8,9-HpCDF
U
24.6
Pg/g
24.6 204
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
142
Pg/g
28.2 408
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1390
1630
Pg/g
85.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1390
1630
Pg/g
85.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1450
1630
Pg/g
88.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1460
1630
Pg/g
89.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1120
1630
Pg/g
68.5
(23%-140%)
13C-OCDD
1020
3260
Pg/g
31.3
(17%-157%)
13C-2,3,7,8-TCDF
1550
1630
Pg/g
95.1
(24%-169%)
130-1,2,3,7,8-
PeCDF
1520
1630
Pg/g
93.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1500
1630
Pg/g
92.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1640
1630
Pg/g
101
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1530
1630
Pg/g
93.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1460
1630
Pg/g
89.8
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1180
1630
Pg/g
72.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1290
1630
Pg/g
78.8
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
839
1630
Pg/g
51.4
(26%-13 8%)
3701-2,3,7,8-TCDD
176
163
Pg/g
108
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6255
Lab Sample ID: 6255004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/18/2014 09:15
06/19/2014 10:05
Project: TETR00114
Matrix: SOLID
%Moisture: 21.8
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-103
26229
06/23/2014 15:38
A23JUN14A-9
26227
19-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.12 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3090
Pg/g
1.48 11.4
40321-76-4
1,2,3,7,8-PeCDD
U
3.63
Pg/g
3.63 57.1
39227-28-6
1,2,3,4,7,8-HxCDD
J
5.85
Pg/g
2.06 57.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
34.2
Pg/g
2.12 57.1
19408-74-3
1,2,3,7,8,9-HxCDD
J
11.8
Pg/g
2.22 57.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
332
Pg/g
3.52 57.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7750
Pg/g
15.2 114
51207-31-9
2,3,7,8-TCDF
15.7
Pg/g
1.63 11.4
57117-41-6
1,2,3,7,8-PeCDF
J
2.56
Pg/g
1.02 57.1
57117-31-4
2,3,4,7,8-PeCDF
J
4.11
Pg/g
1.01 57.1
70648-26-9
1,2,3,4,7,8-HxCDF
J
7.54
Pg/g
1.35 57.1
57II7.44.9
1,2,3,6,7,8-HxCDF
J
6.14
Pg/g
1.42 57.1
60851-34-5
2,3,4,6,7,8-HxCDF
J
8.22
Pg/g
1.42 57.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.91
Pg/g
3.91 57.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
115
Pg/g
1.53 57.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
5.12
Pg/g
5.12 57.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
109
Pg/g
8.77 114
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1960
2280
Pg/g
86.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1950
2280
Pg/g
85.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1980
2280
Pg/g
86.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1890
2280
Pg/g
83.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1800
2280
Pg/g
78.8
(23%-140%)
13C-OCDD
2520
4570
Pg/g
55.2
(17%-157%)
13C-2,3,7,8-TCDF
2140
2280
Pg/g
93.9
(24%-169%)
130-1,2,3,7,8-
PeCDF
2030
2280
Pg/g
88.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1980
2280
Pg/g
86.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1990
2280
Pg/g
87.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1910
2280
Pg/g
83.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2280
Pg/g
83.8
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1680
2280
Pg/g
73.6
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1840
2280
Pg/g
80.8
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1580
2280
Pg/g
69.3
(26%-13 8%)
3701-2,3,7,8-TCDD
247
228
Pg/g
108
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6255
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6255004
Date Collected:
06/18/2014 09:15
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/19/2014 10:05
%Moisture:
21.8
Client ID:
SFRA-103
Prep Basis:
Dry Weight
Batch ID:
26229
Method:
EPA Method 1613B
Run Date:
06/23/2014 17:18
Analyst:
JTF
Instrument:
HRP763
Data File:
b23junl4a-7
Dilution:
1
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.12 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
20.8
Pg/g
3.22
11.4
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6255
Lab Sample ID: 6255005
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/18/2014 14:00
06/19/2014 10:05
Project: TETR00114
Matrix: SOLID
%Moisture: 20.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-104
26229
06/23/2014 16:26
A23JUN14A-10
26227
19-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.14 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
610
Pg/g
1.98 11.1
40321-76-4
1,2,3,7,8-PeCDD
U
2.16
Pg/g
2.16 55.4
39227-28-6
1,2,3,4,7,8-HxCDD
u
4.39
Pg/g
4.39 55.4
57653-85-7
1,2,3,6,7,8-HxCDD
J
7.87
Pg/g
3.52 55.4
19408-74-3
1,2,3,7,8,9-HxCDD
u
4.57
Pg/g
4.57 55.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
164
Pg/g
7.20 55.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
6410
Pg/g
57.4 111
51207-31-9
2,3,7,8-TCDF
J
3.77
Pg/g
2.75 11.1
57117-41-6
1,2,3,7,8-PeCDF
u
2.46
Pg/g
2.46 55.4
57117-31-4
2,3,4,7,8-PeCDF
u
2.53
Pg/g
2.53 55.4
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.15
Pg/g
2.15 55.4
57II7.44.9
1,2,3,6,7,8-HxCDF
J
2.06
Pg/g
1.63 55.4
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.04
Pg/g
2.04 55.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.39
Pg/g
3.39 55.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
21.3
Pg/g
21.3 55.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
6.05
Pg/g
6.05 55.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
50.6
Pg/g
31.5 111
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1770
2220
Pg/g
79.8
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1760
2220
Pg/g
79.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1840
2220
Pg/g
83.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1860
2220
Pg/g
84.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1300
2220
Pg/g
58.7
(23%-140%)
13C-OCDD
1810
4430
Pg/g
40.9
(17%-157%)
13C-2,3,7,8-TCDF
1980
2220
Pg/g
89.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
1950
2220
Pg/g
87.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
1940
2220
Pg/g
87.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2190
2220
Pg/g
98.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2070
2220
Pg/g
93.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2220
Pg/g
86.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1550
2220
Pg/g
70.0
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1450
2220
Pg/g
65.2
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1170
2220
Pg/g
52.7
(26%-13 8%)
3701-2,3,7,8-TCDD
230
222
Pg/g
104
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 36
-------
Quality Control
Summary
Page 18 of 36
-------
( ape Fear \lltllytictll LLC Report Date: June 24, 2014
Hi-Res Dioxins/Furans Page 1 of 4
Surrogate Recovery Report
SDG Number: 6255
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010731
LCS for batch 26227
12010732
LCSD for batch 26227
12010730
MB for batch 26227
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
70.8
75.1
61.2
76.1
70.0
43.0
77.9
81.5
81.9
62.7
74.0
64.7
53.0
75.2
53.0
86.9
67.7
75.5
62.5
83.0
58.9
44.7
77.0
83.2
79.0
68.4
81.1
72.4
56.1
65.4
47.3
84.1
71.2
79.1
66.1
77.8
56.7
31.1
77.5
85.0
81.7
70.3
83.0
73.1
55.6
65.3
44.4
87.9
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6255001
SFRA-100
13C-2,3,7,8-TCDD
66.6 D
(25%-164%)
Page 19 of 36
-------
( ape Fear \lltllytictll LLC Report Date: June 24, 2014
Hi-Res Dioxins/Furans Page 2 of 4
Surrogate Recovery Report
SDG Number: 6255
Matrix Type: SOLID
Sample ID Client ID
Recovery Acceptance
Surrogate
QUAL (%)
Limits
13C-l,2,3,7,8-PeCDD
62.3
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
68.7
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
68.6
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
62.8
D
(23%-140%)
13C-OCDD
37.6
D
(17%-15 7%)
13C-2,3,7,8-TCDF
76.2
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
73.0
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
70.3
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
76.2
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
69.8
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
69.4
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
56.0
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
68.7
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
54.0
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
100
D
(35%-197%)
13C-2,3,7,8-TCDD
69.5
(25%-164%)
13C-l,2,3,7,8-PeCDD
67.9
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
72.0
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
67.8
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
68.2
(23%-140%)
13C-OCDD
44.2
(17%-15 7%)
13C-2,3,7,8-TCDF
75.7
(24%-169%)
13C-l,2,3,7,8-PeCDF
70.8
(24%-185%)
13C-2,3,4,7,8-PeCDF
70.0
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
74.1
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
69.1
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
69.5
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
60.5
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
69.4
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
57.0
(26%-13 8%)
37Cl-2,3,7,8-TCDD
85.7
(35%-197%)
13C-2,3,7,8-TCDD
70.0
(25%-164%)
13C-l,2,3,7,8-PeCDD
71.4
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
70.7
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
69.7
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
66.1
(23%-140%)
13C-OCDD
43.2
(17%-15 7%)
13C-2,3,7,8-TCDF
75.7
(24%-169%)
13C-l,2,3,7,8-PeCDF
74.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
73.9
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
74.0
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
68.0
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
70.9
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
60.6
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
68.8
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
56.5
(26%-13 8%)
37Cl-2,3,7,8-TCDD
85.5
(35%-197%)
13C-2,3,7,8-TCDD
86.7
(25%-164%)
13C-l,2,3,7,8-PeCDD
92.0
(25%-181%)
6255001
SFRA-100
6255002
SFRA-101
12010733
SFRA-101(6255002MS)
12010734
SFRA-101(6255002MSD)
Page 20 of 3 6
-------
( ape Fear \lltllytictll LLC Report Date: June 24, 2014
Hi-Res Dioxins/Furans Page 3 of 4
Surrogate Recovery Report
SDG Number: 6255
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010734
SFRA-101(6255002MSD)
6255003
SFRA-102
6255004
SFRA-103
6255005
SFRA-104
13C-l,2,3,4,7,8-HxCDD
85.9
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
83.8
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
82.8
(23%-140%)
13C-OCDD
56.3
(17%-15 7%)
13C-2,3,7,8-TCDF
94.5
(24%-169%)
13C-l,2,3,7,8-PeCDF
94.6
(24%-185%)
13C-2,3,4,7,8-PeCDF
93.8
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
89.8
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
83.2
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
84.8
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
75.3
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
82.1
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
73.7
(26%-13 8%)
37Cl-2,3,7,8-TCDD
109
(35%-197%)
13C-2,3,7,8-TCDD
85.3
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
85.5
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
88.6
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
89.4
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
68.5
D
(23%-140%)
13C-OCDD
31.3
D
(17%-15 7%)
13C-2,3,7,8-TCDF
95.1
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
93.3
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
92.0
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
101
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
93.9
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
89.8
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
72.3
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
78.8
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
51.4
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
108
D
(35%-197%)
13C-2,3,7,8-TCDD
86.0
(25%-164%)
13C-l,2,3,7,8-PeCDD
85.4
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
86.8
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
83.0
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
78.8
(23%-140%)
13C-OCDD
55.2
(17%-15 7%)
13C-2,3,7,8-TCDF
93.9
(24%-169%)
13C-l,2,3,7,8-PeCDF
88.7
(24%-185%)
13C-2,3,4,7,8-PeCDF
86.8
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
87.2
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
83.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
83.8
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
73.6
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
80.8
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
69.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
108
(35%-197%)
13C-2,3,7,8-TCDD
79.8
(25%-164%)
13C-l,2,3,7,8-PeCDD
79.5
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
83.2
(32%-141%)
Page 21 of 36
-------
( ape Fear \lltllytictll LLC Report Date: June 24, 2014
Hi-Res Dioxins/Furans Page 4 of 4
Surrogate Recovery Report
SDG Number: 6255
Matrix Type: SOLID
Sample ID Client ID
6255005 SFRA-104
Surrogate
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
(%)
Limits
84.1
(28%-
¦130%)
58.7
(23%-
¦140%)
40.9
(17%-
¦157%)
89.5
(24%-
¦169%)
87.9
(24%-
¦185%)
87.6
(21%-
¦178%)
98.8
(26%-
¦152%)
93.4
(26%-
¦123%)
86.1
(28%-
¦136%)
70.0
(29%-
¦147%)
65.2
(28%-
¦143%)
52.7
(26%-
¦138%)
104
(35%-
¦197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 22 of 3 6
-------
Cape Fear Analytical LLC
Report Date: June 24, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/20/2014 15:31 Dilution: 1
Prep Batch ID:26227
Batch ID: 26229
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
23.4
117
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
107
107
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
104
104
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
104
104
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
100
100
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
217
109
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.5
97.3
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
97.1
97.1
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
97.2
97.2
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
105
105
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
106
106
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
104
104
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
111
111
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
96.0
96
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
104
104
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
181
90.6
63-170
SDG Number: 6255
Client ID: LCS for batch 26227
Lab Sample ID: 12010731
Instrument: HRP750
Analyst: JTF
Page
23 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/20/2014 16:19 Dilution: 1
Prep Batch ID:26227
Batch ID: 26229
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
22.9
114
67-158
2.04
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
102
102
70-142
4.31
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
108
108
70-164
3.99
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
105
105
76-134
1.18
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
106
106
64-162
5.67
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
99.3
99.3
70-140
1.48
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
203
101
78-144
7.04
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.6
97.9
75-158
0.615
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
93.8
93.8
80-134
3.49
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
98.1
98.1
68-160
0.993
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
103
103
72-134
2.73
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
101
101
84-130
4.24
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
99.3
99.3
70-156
4.30
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
101
101
78-130
9.38
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
100
100
82-122
4.48
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
94.9
94.9
78-138
9.01
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
180
90.2
63-170
0.485
0-20
SDG Number: 6255
Client ID: LCSD for batch 26227
Lab Sample ID: 12010732
Instrument: HRP750
Analyst: JTF
Page
24 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24, 2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
254
1920
-439 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1270
J
1370
108
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1270
J
1390
109
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1270
J
1350
103
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1270
J
1350
105
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1270
1770
106
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2540
11600
109
70-130
51207-31-9
MS
2,3,7,8-TCDF
254
260
95
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1270
J
1350
106
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1270
J
1350
106
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1270
J
1350
106
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1270
J
1400
110
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1270
U
1350
106
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1270
u
1440
113
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1270
1440
104
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1270
u
1340
105
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2540
2660
97.7
70-130
SDG Number: 6255
Client ID: SFRA-101(6255002MS)
Lab Sample ID: 12010733
Instrument: HRP750
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 22.2
Analysis Date: 06/23/2014 13:09
Prep Batch ID:26227
Batch ID: 26229
Page 25 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 22.2
Analysis Date: 06/23/2014 13:58 Dilution: 1
Prep Batch ID:26227
Batch ID: 26229
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
247
977
-832 *
70-130
65.0 *
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1240
J
1320
107
70-130
3.90
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1240
J
1310
105
70-130
6.23
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1240
J
1370
109
70-130
1.95
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1240
J
1360
109
70-130
0.700
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1240
1790
110
70-130
0.872
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2470
11300
100
70-130
2.51
0-20
51207-31-9
MSD
2,3,7,8-TCDF
247
255
95.8
70-130
1.92
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1240
J
1350
109
70-130
0.189
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1240
J
1320
106
70-130
2.37
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1240
J
1320
106
70-130
2.45
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1240
J
1370
110
70-130
2.52
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1240
U
1350
109
70-130
0.168
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1240
u
1400
114
70-130
2.80
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1240
1400
104
70-130
2.89
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1240
u
1300
105
70-130
3.27
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2470
2720
103
70-130
2.34
0-20
SDG Number: 6255
Client ID: SFRA-101(6255002MSD)
Lab Sample ID: 12010734
Instrument: HRP750
Analyst: JTF
Page
26 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24, 2014
SDG Number:
Client ID:
Lab Sample ID:
Instrument:
Analyst:
6255
SFRA-101(6255002MS)
12010733
HRP763
JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Page 1 of 2
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 22.2
Analysis Date: 06/23/2014 16:39
Prep Batch ID:26227
Batch ID: 26229
Dilution: 1
CAS No.
Parmname
Amount
Added
Pg/g
Spike
Cone.
Pg/g
Recovery Acceptance
o/0 Limits
2,3,7,8-TCDF
Page 27 of 3 6
-------
Cape Fear Analytical LLC
Report Date:
June 24, 2014
SDG Number: 6255
Client ID: SFRA-101(6255002MSD)
Lab Sample ID: 12010734
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Page 2 of 2
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 22.2
Analysis Date: 06/23/2014 16:59
Prep Batch ID:26227
Batch ID: 26229
Dilution: 1
CAS No.
Parmname
Amount
Added
Pg/g
Spike
Cone.
Pg/g
Recovery Acceptance RPD Acceptance
o/0 Limits o/0 Limits
MSD 2,3,7,8-TCDF
Page 28 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24,2014
Method Blank Summary Page ' °' '
SDG Number: 6255
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 26227
Instrument ID:
HRP750
Data File:
A17JUN14C 8-5
Lab Sample ID: 12010730
Column:
Prep Date:
19-JUN-14
Analyzed:
06/20/14 17:07
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
1 Time Analyzed
01 LCS for batch 26227
12010731
A17JUN14C8-3
06/20/14
1531
02 LCSD for batch 26227
12010732
A17JUN14C8-4
06/20/14
1619
03 SFRA-100
6255001
A23JUN14A-3
06/23/14
1041
04 SFRA-101
6255002
A23JUN14A-5
06/23/14
1222
05 SFRA-101(6255002MS)
12010733
A23JUN14A-6
06/23/14
1309
06 SFRA-101(6255002MSD)
12010734
A23JUN14A-7
06/23/14
1358
07 SFRA-102
6255003
A23JUN14A-8
06/23/14
1450
08 SFRA-103
6255004
A23JUN14A-9
06/23/14
1538
09 SFRA-101
6255002
b23junl4a-4
06/23/14
1620
10 SFRA-104
6255005
A23JUN14A-10
06/23/14
1626
11 SFRA-101(6255002MS)
12010733
b23junl4a-5
06/23/14
1639
12 SFRA-101(6255002MSD)
12010734
b23junl4a-6
06/23/14
1659
13 SFRA-103
6255004
b23junl4a-7
06/23/14
1718
Page 29 of 3 6
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6255
Lab Sample ID: 12010730
Client Sample: *or batch 26227
Client ID: MB for batch 26227
Batch ID: 26229
Run Date: 06/20/2014 17:07
Data File: A17JUN14C 8-5
Prep Batch: 26227
Prep Date: 19-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.198
Pg/g
0.198 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.29
Pg/g
0.290 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.36
Pg/g
0.360 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.398
Pg/g
0.398 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
J
0.480
Pg/g
0.382 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.64
Pg/g
0.640 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
2.46
Pg/g
2.46 10.0
51207-31-9
2,3,7,8-TCDF
u
.266
Pg/g
0.266 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.228
Pg/g
0.228 5.00
57117-31-4
2,3,4,7,8-PeCDF
J
0.244
Pg/g
0.198 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.394
Pg/g
0.394 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.364
Pg/g
0.364 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.432
Pg/g
0.432 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.784
Pg/g
0.784 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.354
Pg/g
0.354 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.686
Pg/g
0.686 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
1.82
Pg/g
1.82 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
142
200
Pg/g
71.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
158
200
Pg/g
79.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
132
200
Pg/g
66.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
156
200
Pg/g
77.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
113
200
Pg/g
56.7
(23%-140%)
13C-OCDD
125
400
Pg/g
31.1
(17%-157%)
13C-2,3,7,8-TCDF
155
200
Pg/g
77.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
170
200
Pg/g
85.0
(24%-185%)
130-2,3,4,7,8-
PeCDF
163
200
Pg/g
81.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
141
200
Pg/g
70.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
166
200
Pg/g
83.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
146
200
Pg/g
73.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
111
200
Pg/g
55.6
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
131
200
Pg/g
65.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
88.8
200
Pg/g
44.4
(26%-13 8%)
3701-2,3,7,8-TCDD
17.6
20.0
Pg/g
87.9
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 30 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6255
Lab Sample ID: 12010731
Client Sample: *or batch 26227
Client ID: LCS for batch 26227
Batch ID: 26229
Run Date: 06/20/2014 15:31
Data File: A17JUN14C_8-3
Prep Batch: 26227
Prep Date: 19-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
23.4
Pg/g
0.272 1.00
40321-76-4
1,2,3,7,8-PeCDD
107
Pg/g
0.756 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
104
Pg/g
1.13 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
104
Pg/g
1.07 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
100
Pg/g
1.16 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
2.36 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
217
Pg/g
9.08 10.0
51207-31-9
2,3,7,8-TCDF
19.5
Pg/g
0.332 1.00
57117-41-6
1,2,3,7,8-PeCDF
97.1
Pg/g
0.660 5.00
57117-31-4
2,3,4,7,8-PeCDF
97.2
Pg/g
0.622 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
105
Pg/g
1.42 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
106
Pg/g
1.25 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
104
Pg/g
1.51 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
111
Pg/g
2.58 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
96.0
Pg/g
1.39 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
104
Pg/g
2.94 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
181
Pg/g
6.82 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
142
200
Pg/g
70.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
150
200
Pg/g
75.1
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
122
200
Pg/g
61.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
152
200
Pg/g
76.1
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
140
200
Pg/g
70.0
(22%-166%)
13C-OCDD
172
400
Pg/g
43.0
(13%-199%)
13C-2,3,7,8-TCDF
156
200
Pg/g
77.9
(22%-152%)
13C-1,2,3,7,8-
PeCDF
163
200
Pg/g
81.5
(21%-192%)
130-2,3,4,7,8-
PeCDF
164
200
Pg/g
81.9
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
125
200
Pg/g
62.7
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
148
200
Pg/g
74.0
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
129
200
Pg/g
64.7
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
106
200
Pg/g
53.0
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
150
200
Pg/g
75.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
106
200
Pg/g
53.0
(20%-186%)
3701-2,3,7,8-TCDD
17.4
20.0
Pg/g
86.9
(31 %-191%)
Comments:
Page 31 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6255
12010732
QC for batch 26227
LCSD for batch 26227
26229
06/20/2014 16:19
A17JUN14C 8-4
26227
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
19-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
22.9
Pg/g
0.314
1.00
40321-76-4
1,2,3,7,8-PeCDD
102
Pg/g
0.762
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
108
Pg/g
1.59
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
105
Pg/g
1.61
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
106
Pg/g
1.69
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
99.3
Pg/g
1.90
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
203
Pg/g
6.28
10.0
51207-31-9
2,3,7,8-TCDF
19.6
Pg/g
0.332
1.00
57117-41-6
1,2,3,7,8-PeCDF
93.8
Pg/g
0.644
5.00
57117-31-4
2,3,4,7,8-PeCDF
98.1
Pg/g
0.646
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
103
Pg/g
1.63
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
101
Pg/g
1.59
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
99.3
Pg/g
1.83
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
101
Pg/g
3.58
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
100
Pg/g
1.48
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
94.9
Pg/g
2.76
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
180
Pg/g
5.24
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
135
200
Pg/g
67.7
(20%-175%)
13C-1,2,3,7,8-PeCDD
151
200
Pg/g
75.5
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
125
200
Pg/g
62.5
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
166
200
Pg/g
83.0
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
118
200
Pg/g
58.9
(22%-166%)
13C-OCDD
179
400
Pg/g
44.7
(13%-199%)
13C-2,3,7,8-TCDF
154
200
Pg/g
77.0
(22%-152%)
13C-1,2,3,7,8-PeCDF
166
200
Pg/g
83.2
(21%-192%)
13C-2,3,4,7,8-PeCDF
158
200
Pg/g
79.0
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
137
200
Pg/g
68.4
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
162
200
Pg/g
81.1
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
145
200
Pg/g
72.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
112
200
Pg/g
56.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
131
200
Pg/g
65.4
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
94.5
200
Pg/g
47.3
(20%-186%)
37Cl-2,3,7,8-TCDD
16.8
20.0
Pg/g
84.1
(31 %-191%)
Comments:
Page 32 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6255
12010733
QC for batch 26227
SFRA-101(6255002MS)
26229
06/23/2014 13:09
A23JUN14A-6
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
TETR001
Date Collected: 06/17/2014 15:00
Date Received: 06/19/2014 10:05
Method:
Analyst:
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
22.2
Dry Weight
HRP750
1
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.01 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
1920
Pg/g
1.55
12.7
40321-76-4
1,2,3,7,8-PeCDD
1370
Pg/g
2.47
63.6
39227-28-6
1,2,3,4,7,8-HxCDD
1390
Pg/g
3.51
63.6
57653-85-7
1,2,3,6,7,8-HxCDD
1350
Pg/g
3.66
63.6
19408-74-3
1,2,3,7,8,9-HxCDD
1350
Pg/g
3.82
63.6
35822-46-9
1,2,3,4,6,7,8-HpCDD
1770
Pg/g
6.34
63.6
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11600
Pg/g
20.5
127
51207-31-9
2,3,7,8-TCDF
260
Pg/g
2.75
12.7
57117-41-6
1,2,3,7,8-PeCDF
1350
Pg/g
2.70
63.6
57117-31-4
2,3,4,7,8-PeCDF
1350
Pg/g
2.80
63.6
70648-26-9
1,2,3,4,7,8-HxCDF
1350
Pg/g
4.63
63.6
57II7.44.9
1,2,3,6,7,8-HxCDF
1400
Pg/g
4.53
63.6
60851-34-5
2,3,4,6,7,8-HxCDF
1350
Pg/g
4.78
63.6
72918-21-9
1,2,3,7,8,9-HxCDF
1440
Pg/g
7.79
63.6
67562-39-4
1,2,3,4,6,7,8-HpCDF
1440
Pg/g
4.25
63.6
55673-89-7
1,2,3,4,7,8,9-HpCDF
1340
Pg/g
8.52
63.6
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2660
Pg/g
12.8
127
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1780
2540
Pg/g
70.0
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1820
2540
Pg/g
71.4
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1800
2540
Pg/g
70.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1770
2540
Pg/g
69.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1680
2540
Pg/g
66.1
(23%-140%)
13C-OCDD
2200
5090
Pg/g
43.2
(17%-157%)
13C-2,3,7,8-TCDF
1930
2540
Pg/g
75.7
(24%-169%)
13C-1,2,3,7,8-PeCDF
1880
2540
Pg/g
74.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
1880
2540
Pg/g
73.9
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1880
2540
Pg/g
74.0
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1730
2540
Pg/g
68.0
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1800
2540
Pg/g
70.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1540
2540
Pg/g
60.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1750
2540
Pg/g
68.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1440
2540
Pg/g
56.5
(26%-13 8%)
37Cl-2,3,7,8-TCDD
217
254
Pg/g
85.5
(35%-197%)
Comments:
Page 33 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6255
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
12010733
Date Collected:
06/17/2014 15:00
Matrix:
SOLID
Client Sample:
QC for batch 26227
Date Received:
06/19/2014 10:05
%Moisture:
22.2
Client ID:
SFRA-101(6255002MS)
Prep Basis:
Dry Weight
Batch ID:
26229
Method:
EPA Method 1613B
Run Date:
06/23/2014 16:39
Analyst:
JTF
Instrument:
HRP763
Data File:
b23junl4a-5
Dilution:
1
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.01 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
295
Pg/g
2.67
12.7
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
Page 34 of 36
-------
Cape Fear Analytical LLC
Report Date:
June 24,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6255
12010734
QC for batch 26227
SFRA-101(6255002MSD)
26229
06/23/2014 13:58
A23JUN14A-7
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
TETR001
Date Collected: 06/17/2014 15:00
Date Received: 06/19/2014 10:05
Method:
Analyst:
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
22.2
Dry Weight
HRP750
1
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.04 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
977
Pg/g
1.21
12.4
40321-76-4
1,2,3,7,8-PeCDD
1320
Pg/g
1.93
61.8
39227-28-6
1,2,3,4,7,8-HxCDD
1310
Pg/g
3.29
61.8
57653-85-7
1,2,3,6,7,8-HxCDD
1370
Pg/g
3.43
61.8
19408-74-3
1,2,3,7,8,9-HxCDD
1360
Pg/g
3.56
61.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
1790
Pg/g
4.92
61.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11300
Pg/g
15.3
124
51207-31-9
2,3,7,8-TCDF
255
Pg/g
2.69
12.4
57117-41-6
1,2,3,7,8-PeCDF
1350
Pg/g
2.77
61.8
57117-31-4
2,3,4,7,8-PeCDF
1320
Pg/g
2.87
61.8
70648-26-9
1,2,3,4,7,8-HxCDF
1320
Pg/g
3.88
61.8
57II7.44.9
1,2,3,6,7,8-HxCDF
1370
Pg/g
3.98
61.8
60851-34-5
2,3,4,6,7,8-HxCDF
1350
Pg/g
4.27
61.8
72918-21-9
1,2,3,7,8,9-HxCDF
1400
Pg/g
6.45
61.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
1400
Pg/g
2.46
61.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
1300
Pg/g
4.30
61.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2720
Pg/g
8.92
124
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2140
2470
Pg/g
86.7
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2270
2470
Pg/g
92.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
2120
2470
Pg/g
85.9
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
2070
2470
Pg/g
83.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2050
2470
Pg/g
82.8
(23%-140%)
13C-OCDD
2780
4940
Pg/g
56.3
(17%-157%)
13C-2,3,7,8-TCDF
2330
2470
Pg/g
94.5
(24%-169%)
13C-1,2,3,7,8-PeCDF
2340
2470
Pg/g
94.6
(24%-185%)
13C-2,3,4,7,8-PeCDF
2320
2470
Pg/g
93.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
2220
2470
Pg/g
89.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2050
2470
Pg/g
83.2
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2090
2470
Pg/g
84.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1860
2470
Pg/g
75.3
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2030
2470
Pg/g
82.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1820
2470
Pg/g
73.7
(26%-13 8%)
37Cl-2,3,7,8-TCDD
270
247
Pg/g
109
(35%-197%)
Comments:
Page 35 of 36
-------
Cape Fear Analytical LLC
Report Date: June 24,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6255
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
12010734
Date Collected:
06/17/2014 15:00
Matrix:
SOLID
Client Sample:
QC for batch 26227
Date Received:
06/19/2014 10:05
%Moisture:
22.2
Client ID:
SFRA-101(6255002MSD)
Prep Basis:
Dry Weight
Batch ID:
26229
Method:
EPA Method 1613B
Run Date:
06/23/2014 16:59
Analyst:
JTF
Instrument:
HRP763
Data File:
b23junl4a-6
Dilution:
1
Prep Batch:
26227
Prep Method:
SW846 3540C
Prep Date:
19-JUN-14
Prep Aliquot:
1.04 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
273
Pg/g
2.52
12.4
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
Page 36 of 36
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 30. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6275
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 24, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 42
problem solved
-------
Page: J_
Project #;
CFA Quote#:
COC Number
PO Number:
of
Client Name: ^
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: f
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: {910)795-0421
Phone
Sample Analysis Requested(5> {Fill in the number of containers for each test)
Project/Site Name^*^Cc £.4 f
Total number of containers
<-- Preservative Type (6)
$
Comments
Note: extra sample is
required for sample
specific QC
fcol.ectedby: / c/£. Send Results To: /¦' f T.\
Sample ID
• For composites - indicate start and stop date/time
i
~Date Collected
(mm-dd-yy)
~Time
Collected
(Military)
(bhiBRi)
QC Code
(2)
Field
Filtered"1
Sample
Matrix'*1
ffw
5 '
1
~A>£
ۥ*0 Vi
ffft
s
f
v/
' /a/
s
(
«/
fox
mi
-S
1
J
/o?
J*
1
t/
£ 'Ao
s
I
Sf/iJ- t(i
€-AS-fi
tSH*
-S
t
r/^L
s
(
-//,?
m
s
r
3F£4-/Il(
6-xi-M
5
i
TAT Requested: Nonnal: Rush: )C Specify: Abject to SuidniEe) FaxResults: Yes / No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 /^Lcvcl^i' Level 4
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
Sample Collection Time Zone
Eastern Pacific
Central . Other _
"Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
11/e /£. a r *t3
Relinquished By (Signed)
Date
Time
Received by (signed)
Date
Time
CFA PM:
Method of Shipment;
Date Shipped:
Airbill #:
Chain of Custody Number = Client Determined
QC Codes: N = Normal Sample, TB = Trip Blank, FD = Field Duplicate, EB = Equipment Blank, MS = Matrix Spike Sample, MSB = Matrix Spike Duplicate Sample,G = Grab, C - Composite
Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was fie!d filtered or- N - for sample was not field filtered.
Matrix Codes: DW=Drinking Water, GW=Groiindwater> SW=Surface Water, WW=Waste Water, W-Water, ML-Mise LiqukJ,SO=Soi!v 8D»SedimenU SL=Sludge, SS=Solid Waste, CNOil, F=Fitter, P»Wipe, UHJrine, I^Fecal, N=Nasal
Sample Analysis Requested: Analytical method requested (i.e32W)B, 1668B) and number of containers provided for each (i .e. 8290B -3,1668B - i).
Preservative Type: HA = Hydrochloric Acid, NI = Nitric Acid, SH = Sodium Hydroxide, SA ~ Sulfuric Acid, AA ~ Ascorbic Acid, HX - Hexane, ST - Sodium Thiosulfate, If no preservative is added = leave field Wank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For tab Receiving Use Only
Custody Seal Intact?
YES NO
Cot
jimp.
> C
-------
SAMPLE RECEIPT CHECKLIST
Client;
Work Order:
Shipping Company: JL t—X
Date/Time Received; 2-4j LY/0) ^ 5" O
shipped as DOT Hazardous7
Samples identified as Foreign Soil?
Screened <0.S rnR/hr?
Samples < 2x background?
Notify RSO of any responses in this column immediately.
Air Sample Receipt Specifics
Yes
NA 1 No
Air sample in shipment?
' Air Witness;
Sample Receipt Criteria
Shipping containers received intact
and sealed?
Chain of Custody documents included
with shipment?
Yes
NA
Samples requiring cold preservation
within 0~6°C?
Aqueous samples found to have visible
solids?
JO
11
Samples requiring chemical
preservation at proper pH?
Samples requiring preservation have
no residual chlorine?
Samples received within holding time?
Sample IDs on COC match IDs on
containers?
Date & time of COC match date & time
on containers?
Number of containers received match
number indicated on COC?
COC form is properly signed in
relinquished/received sections'
Comments:
(oS
(Ob
(on
to%_
nj_
i( i
No
it Applicifbtf.
jrah b'Ofceo i?2nicg*tf cof?
7^
Blion MetK&di
biuskt dry its n.OAt
Sample iDi. containeis affected:
Sample iOs, corUBiners itfecled and pH observed:
v/
Itjkiog COfMei
4- 3*C
If preservative added, lei#:
Sample IDs, containers 2 Netted:
H preservative added. lotE:
Sample IDs, test* aHetted;
Sample JOs. contsiners Ertpcied:
Sample TDs. l, * Fin
5«mp1e- IDs. containers itfetif'
CjoC
ii-OO
((a
tui
it / y
u (ia
(/2-t
ll z
t fo
13 Ho
4:0-5
1 3 HO
Ched'.list performed
Page 3 of 42
litillBlS:
lAjujoli
-------
Re: Collection time verifications
Subject: Re: Collection time verifications
From: "rclaytor@seagullenvirotech.com"
Date: 6/24/2014 5:13 PM
To: Cynde Larkins
lhave indicated the correct sample time for the requested samples. Thank you.
On June 24, 2014 at 2:40 PM Cynde Larkins wrote:
Mr. Kinroth,
CFA received the 10 soil samples today for rush turnaround in good condition and within
temperature. There are several collection time discrepancies I am hoping you can let me know
which times to use.
Sample ID
Collection time on COC
Collection time on Label
SFRA-105
1400
1111 Correct
SFRA-106
1111
1116 Correct
SFRA-107
1116
1121 Correct
SFRA-108
1121
1210 Correct
SFRA-111
1340
1338 1335 Corect
SFRA-112
1405
1340 Correct
Thank you,
Cynde Larkins
Project Manager Assistant
Cape Fear Analytical
3306 Kitty Hawk Road
Suite 120
Wilmington, NC 28405
(910) 795-0421
How was your customer experience? Customer service is a high
priority for us, so we listen to what our customers have to say!
Thank you for taking time to email us your thoughts and opinions at
feedback@cfanalytical.com
CONFIDENTIALITY NOTICE: This e-mail and any files transmitted
with it are the property of Cape Fear Analytical, LLC. All
rights,including without limitation copyright,are reserved. The
proprietary information contained in this e-mail message,
and any files transmitted with it, is intended for the use of the
recipient(s) named above. If the reader of this e-mail is not the
intended recipient, you are hereby notified that you have
received this e-mail in error and that any review, distribution
or copying of this e-mail or any files transmitted with it is
1 of 2
Page 4 of 42
6/24/2014 5:18 PM
-------
Re: Collection time verifications
strictly prohibited. If you have received this e-mail in error,
please notify the sender immediately and delete the original
message and any files transmitted. The unauthorized use of
this e-mail or any files transmitted with it is prohibited and
disclaimed by Cape Fear Analytical, LLC.
Rick Claytor, CHMM
Sr. Environmental Scientist
Seagull Environmental Technologies, Inc.
Woman-Owned, 8(a) Firm
email: rclaytor@seagullenvirotech.com
2 of 2
Page 5 of 42
6/24/2014 5:18 PM
-------
High Resolution Dioxins
and Furans Analysis
Page 6 of 42
-------
Case Narrative
Page 7 of 42
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6275
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26279
Clean Up Batch Number: 26278
Extraction Batch Number: 26277
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6275001
SFRA-105
6275002
SFRA-106
6275003
SFRA-107
6275004
SFRA-108
6275005
SFRA-109
6275006
SFRA-110
6275007
SFRA-111
6275008
SFRA-112
6275009
SFRA-113
6275010
SFRA-114
12010785
Method Blank (MB)
12010786
Laboratory Control Sample (LCS)
12010787
Laboratory Control Sample Duplicate (LCSD)
12010788
6275001 (SFRA-105) Matrix Spike (MS)
12010789
6275001 (SFRA-105) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Page 8 of 42
-------
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6275001 (SFRA-105)- Batch 26279 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Recovery Statement
One MS recovery for this SDG was not within the acceptance limits. The failure confirms in the
matrix spike duplicate and can be attributed to matrix interference. 12010788 (SFRA-105) and
12010789 (SFRA-105) - Batch 26279.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Page 9 of 42
-------
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Sample Dilutions
Samples 6275002 (SFRA-106), 6275005 (SFRA-109) and 6275008 (SFRA-112) - Batch 26279
were diluted due to the presence of over-range target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present.
Miscellaneous Information
Nonconformance (NCR) Documentation
The following NCR was generated for this SDG: 644608 12010788 (SFRA-105) and 12010789
(SFRA-105)- Batch 26279.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 10 of 42
-------
Sample Data Summary
Page 11 of 42
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6275 CFA Work Order: 6275
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 30JUN2014 Title: Data Validator
Page 12 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 6275001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/18/201411:11
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 19.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-105
26279
06/25/2014 18:50
b25junl4a-5
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.5 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
179
Pg/g
1.64 8.27
40321-76-4
1,2,3,7,8-PeCDD
U
1.02
Pg/g
1.02 41.4
39227-28-6
1,2,3,4,7,8-HxCDD
u
1.85
Pg/g
1.85 41.4
57653-85-7
1,2,3,6,7,8-HxCDD
J
2.43
Pg/g
1.84 41.4
19408-74-3
1,2,3,7,8,9-HxCDD
J
2.07
Pg/g
1.95 41.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
76.3
Pg/g
3.44 41.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5550
Pg/g
6.35 82.7
51207-31-9
2,3,7,8-TCDF
J
1.72
Pg/g
1.39 8.27
57117-41-6
1,2,3,7,8-PeCDF
u
.877
Pg/g
0.877 41.4
57117-31-4
2,3,4,7,8-PeCDF
u
.678
Pg/g
0.678 41.4
70648-26-9
1,2,3,4,7,8-HxCDF
u
1.07
Pg/g
1.07 41.4
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.06
Pg/g
1.06 41.4
60851-34-5
2,3,4,6,7,8-HxCDF
u
1.16
Pg/g
1.16 41.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.6
Pg/g
1.60 41.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
5.86
Pg/g
1.21 41.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
2.04
Pg/g
2.04 41.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
8.60
Pg/g
4.20 82.7
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1200
1650
Pg/g
72.8
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1290
1650
Pg/g
77.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1230
1650
Pg/g
74.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1210
1650
Pg/g
72.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1320
1650
Pg/g
79.7
(23%-140%)
13C-OCDD
2370
3310
Pg/g
71.7
(17%-157%)
13C-2,3,7,8-TCDF
1350
1650
Pg/g
81.6
(24%-169%)
130-1,2,3,7,8-
PeCDF
1280
1650
Pg/g
77.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1370
1650
Pg/g
82.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1350
1650
Pg/g
81.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1250
1650
Pg/g
75.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1310
1650
Pg/g
79.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1270
1650
Pg/g
76.9
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1270
1650
Pg/g
76.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1270
1650
Pg/g
77.0
(26%-13 8%)
3701-2,3,7,8-TCDD
156
165
Pg/g
94.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 42
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Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6275
Lab Sample ID: 6275002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/20/201411:16
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 16.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-106
26279
06/26/2014 18:40
b26junl4a-5
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.04 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
13900
Pg/g
18.6 57.5
40321-76-4
1,2,3,7,8-PeCDD
U
15.9
Pg/g
15.9 287
39227-28-6
1,2,3,4,7,8-HxCDD
u
17.1
Pg/g
17.1 287
57653-85-7
1,2,3,6,7,8-HxCDD
J
90.0
Pg/g
17.4 287
19408-74-3
1,2,3,7,8,9-HxCDD
J
39.2
Pg/g
18.2 287
35822-46-9
1,2,3,4,6,7,8-HpCDD
929
Pg/g
31.7 287
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13300
Pg/g
77.9 575
51207-31-9
2,3,7,8-TCDF
75.5
Pg/g
13.0 57.5
57117-41-6
1,2,3,7,8-PeCDF
u
10
Pg/g
10.0 287
57117-31-4
2,3,4,7,8-PeCDF
J
16.9
Pg/g
6.80 287
70648-26-9
1,2,3,4,7,8-HxCDF
u
23.8
Pg/g
23.8 287
57II7.44.9
1,2,3,6,7,8-HxCDF
J
19.8
Pg/g
8.64 287
60851-34-5
2,3,4,6,7,8-HxCDF
u
27.3
Pg/g
27.3 287
72918-21-9
1,2,3,7,8,9-HxCDF
u
15.6
Pg/g
15.6 287
67562-39-4
1,2,3,4,6,7,8-HpCDF
317
Pg/g
10.9 287
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
25.1
Pg/g
19.4 287
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
371
Pg/g
47.8 575
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1490
2300
Pg/g
64.8
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1370
2300
Pg/g
59.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1450
2300
Pg/g
63.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1540
2300
Pg/g
66.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1480
2300
Pg/g
64.3
(23%-140%)
13C-OCDD
2480
4600
Pg/g
53.9
(17%-157%)
13C-2,3,7,8-TCDF
1640
2300
Pg/g
71.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
1430
2300
Pg/g
62.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1500
2300
Pg/g
65.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1600
2300
Pg/g
69.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1570
2300
Pg/g
68.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1560
2300
Pg/g
68.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1390
2300
Pg/g
60.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1500
2300
Pg/g
65.4
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1370
2300
Pg/g
59.7
(26%-13 8%)
3701-2,3,7,8-TCDD
248
230
Pg/g
108
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6275
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6275002
Date Collected:
06/20/2014 11:16
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/24/2014 14:50
%Moisture:
16.3
Client ID:
SFRA-106
Prep Basis:
Dry Weight
Batch ID:
26279
Method:
EPA Method 1613B
Run Date:
06/27/2014 11:22
Analyst:
JTF
Instrument:
HRP763
Data File:
A27JUN14A-6
Dilution:
5
Prep Batch:
26277
Prep Method:
SW846 3540C
Prep Date:
24-JUN-14
Prep Aliquot:
1.04 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
77.9
Pg/g
14.8
57.5
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 6275003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/20/2014 11:21
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 19.9
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-107
26279
06/26/2014 10:17
b25junl4a_2-9
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.02 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1030
Pg/g
3.16 12.2
40321-76-4
1,2,3,7,8-PeCDD
U
2.64
Pg/g
2.64 61.2
39227-28-6
1,2,3,4,7,8-HxCDD
u
4.33
Pg/g
4.33 61.2
57653-85-7
1,2,3,6,7,8-HxCDD
J
15.1
Pg/g
4.14 61.2
19408-74-3
1,2,3,7,8,9-HxCDD
J
5.48
Pg/g
4.48 61.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
319
Pg/g
9.13 61.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
6530
Pg/g
13.7 122
51207-31-9
2,3,7,8-TCDF
J
6.00
Pg/g
2.29 12.2
57117-41-6
1,2,3,7,8-PeCDF
u
1.94
Pg/g
1.94 61.2
57117-31-4
2,3,4,7,8-PeCDF
u
2.6
Pg/g
2.60 61.2
70648-26-9
1,2,3,4,7,8-HxCDF
J
5.83
Pg/g
2.43 61.2
57II7.44.9
1,2,3,6,7,8-HxCDF
u
3.84
Pg/g
3.84 61.2
60851-34-5
2,3,4,6,7,8-HxCDF
J
3.87
Pg/g
2.60 61.2
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.65
Pg/g
3.65 61.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
58.4
Pg/g
4.36 61.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
7.79
Pg/g
7.79 61.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
138
Pg/g
7.42 122
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1970
2450
Pg/g
80.6
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1970
2450
Pg/g
80.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2110
2450
Pg/g
86.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2060
2450
Pg/g
84.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2060
2450
Pg/g
84.2
(23%-140%)
13C-OCDD
3510
4900
Pg/g
71.6
(17%-157%)
13C-2,3,7,8-TCDF
2070
2450
Pg/g
84.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1990
2450
Pg/g
81.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
2200
2450
Pg/g
89.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2250
2450
Pg/g
92.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2170
2450
Pg/g
88.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2180
2450
Pg/g
89.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
2040
2450
Pg/g
83.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2080
2450
Pg/g
84.8
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1930
2450
Pg/g
79.0
(26%-13 8%)
3701-2,3,7,8-TCDD
236
245
Pg/g
96.6
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 6275004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/20/2014 12:10
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 19.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-108
26279
06/25/2014 22:49
b25junl4a-10
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.4 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
956
Pg/g
1.89 8.90
40321-76-4
1,2,3,7,8-PeCDD
U
1.61
Pg/g
1.61 44.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.26
Pg/g
2.26 44.5
57653-85-7
1,2,3,6,7,8-HxCDD
J
7.40
Pg/g
2.30 44.5
19408-74-3
1,2,3,7,8,9-HxCDD
J
3.03
Pg/g
2.42 44.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
149
Pg/g
4.13 44.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
6320
Pg/g
8.65 89.0
51207-31-9
2,3,7,8-TCDF
J
6.27
Pg/g
1.69 8.90
57117-41-6
1,2,3,7,8-PeCDF
u
.7
Pg/g
0.700 44.5
57117-31-4
2,3,4,7,8-PeCDF
J
1.30
Pg/g
0.666 44.5
70648-26-9
1,2,3,4,7,8-HxCDF
J
1.60
Pg/g
1.18 44.5
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.14
Pg/g
1.14 44.5
60851-34-5
2,3,4,6,7,8-HxCDF
J
1.53
Pg/g
1.27 44.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.8
Pg/g
1.80 44.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
21.4
Pg/g
2.39 44.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
4.18
Pg/g
4.18 44.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
44.4
Pg/g
4.22 89.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1550
1780
Pg/g
87.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1530
1780
Pg/g
85.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1580
1780
Pg/g
88.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1470
1780
Pg/g
82.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1540
1780
Pg/g
86.4
(23%-140%)
13C-OCDD
2710
3560
Pg/g
76.1
(17%-157%)
13C-2,3,7,8-TCDF
1660
1780
Pg/g
93.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
1580
1780
Pg/g
88.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1670
1780
Pg/g
93.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1650
1780
Pg/g
92.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1600
1780
Pg/g
89.9
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1610
1780
Pg/g
90.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1520
1780
Pg/g
85.6
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1540
1780
Pg/g
86.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1440
1780
Pg/g
81.1
(26%-13 8%)
3701-2,3,7,8-TCDD
180
178
Pg/g
101
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6275
Lab Sample ID: 6275005
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/20/2014 13:05
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 31.8
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-109
26279
06/26/2014 19:28
b26junl4a-6
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.17 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
14200
Pg/g
16.3 62.7
40321-76-4
1,2,3,7,8-PeCDD
U
8.05
Pg/g
8.05 313
39227-28-6
1,2,3,4,7,8-HxCDD
u
14.2
Pg/g
14.2 313
57653-85-7
1,2,3,6,7,8-HxCDD
u
30.1
Pg/g
30.1 313
19408-74-3
1,2,3,7,8,9-HxCDD
u
20.5
Pg/g
20.5 313
35822-46-9
1,2,3,4,6,7,8-HpCDD
612
Pg/g
24.6 313
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13400
Pg/g
62.4 627
51207-31-9
2,3,7,8-TCDF
74.0
Pg/g
10.2 62.7
57117-41-6
1,2,3,7,8-PeCDF
u
4.79
Pg/g
4.79 313
57117-31-4
2,3,4,7,8-PeCDF
J
10.7
Pg/g
4.61 313
70648-26-9
1,2,3,4,7,8-HxCDF
J
19.4
Pg/g
7.55 313
57II7.44.9
1,2,3,6,7,8-HxCDF
u
10.8
Pg/g
10.8 313
60851-34-5
2,3,4,6,7,8-HxCDF
J
18.3
Pg/g
8.70 313
72918-21-9
1,2,3,7,8,9-HxCDF
u
13.7
Pg/g
13.7 313
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
188
Pg/g
11.1 313
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
21.2
Pg/g
21.2 313
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
307
Pg/g
58.4 627
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1990
2510
Pg/g
79.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1850
2510
Pg/g
74.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2040
2510
Pg/g
81.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1990
2510
Pg/g
79.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1910
2510
Pg/g
76.3
(23%-140%)
13C-OCDD
3010
5010
Pg/g
60.1
(17%-157%)
13C-2,3,7,8-TCDF
2070
2510
Pg/g
82.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
1910
2510
Pg/g
76.0
(24%-185%)
130-2,3,4,7,8-
PeCDF
1980
2510
Pg/g
78.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2100
2510
Pg/g
83.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2150
2510
Pg/g
85.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2070
2510
Pg/g
82.6
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1840
2510
Pg/g
73.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1950
2510
Pg/g
77.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1760
2510
Pg/g
70.1
(26%-13 8%)
3701-2,3,7,8-TCDD
290
251
Pg/g
116
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 18 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6275
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6275005
Date Collected:
06/20/2014 13:05
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/24/2014 14:50
%Moisture:
31.8
Client ID:
SFRA-109
Prep Basis:
Dry Weight
Batch ID:
26279
Method:
EPA Method 1613B
Run Date:
06/27/2014 11:41
Analyst:
JTF
Instrument:
HRP763
Data File:
A27JUN14A-7
Dilution:
5
Prep Batch:
26277
Prep Method:
SW846 3540C
Prep Date:
24-JUN-14
Prep Aliquot:
1.17 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
82.6
Pg/g
14.2
62.7
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number: 6275
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6275006
Date Collected:
06/20/2014 15:25
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
06/24/2014 14:50
%Moisture: 23.3
Client ID:
SFRA-110
Prep Basis: Dry Weight
Batch ID:
26279
Method:
EPA Method 1613B
Run Date:
06/26/2014 11:07
Analyst:
JTF
Instrument: HRP763
Data File:
b25junl4a_2-10
Dilution: 1
Prep Batch:
26277
Prep Method:
SW846 3540C
Prep Date:
24-JUN-14
Prep Aliquot:
1.51 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2720
Pg/g
2.88 8.63
40321-76-4
1,2,3,7,8-PeCDD
J
5.57
Pg/g
3.56 43.1
39227-28-6
1,2,3,4,7,8-HxCDD
J
7.68
Pg/g
3.85 43.1
57653-85-7
1,2,3,6,7,8-HxCDD
129
Pg/g
3.97 43.1
19408-74-3
1,2,3,7,8,9-HxCDD
J
27.6
Pg/g
4.16 43.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
1790
Pg/g
11.3 43.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
18600
Pg/g
26.1 86.3
51207-31-9
2,3,7,8-TCDF
19.0
Pg/g
2.73 8.63
57117-41-6
1,2,3,7,8-PeCDF
J
6.80
Pg/g
1.67 43.1
57117-31-4
2,3,4,7,8-PeCDF
J
21.2
Pg/g
1.50 43.1
70648-26-9
1,2,3,4,7,8-HxCDF
145
Pg/g
2.57 43.1
57II7.44.9
1,2,3,6,7,8-HxCDF
J
39.3
Pg/g
2.57 43.1
60851-34-5
2,3,4,6,7,8-HxCDF
52.3
Pg/g
2.76 43.1
72918-21-9
1,2,3,7,8,9-HxCDF
52.8
Pg/g
4.14 43.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
655
Pg/g
4.09 43.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
144
Pg/g
7.51 43.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1190
Pg/g
11.4 86.3
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1380
1730
Pg/g
80.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1400
1730
Pg/g
81.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1570
1730
Pg/g
90.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1440
1730
Pg/g
83.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1530
1730
Pg/g
88.4
(23%-140%)
13C-OCDD
2510
3450
Pg/g
72.7
(17%-157%)
13C-2,3,7,8-TCDF
1470
1730
Pg/g
85.3
(24%-169%)
130-1,2,3,7,8-
PeCDF
1450
1730
Pg/g
83.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
1540
1730
Pg/g
89.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1640
1730
Pg/g
94.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1600
1730
Pg/g
92.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1620
1730
Pg/g
94.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1480
1730
Pg/g
85.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1530
1730
Pg/g
88.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1410
1730
Pg/g
81.7
(26%-13 8%)
3701-2,3,7,8-TCDD
172
173
Pg/g
99.6
(35%-197%)
Comments:
J Value is estimated
Page 20 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6275
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6275006
Date Collected:
06/20/2014 15:25
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/24/2014 14:50
%Moisture:
23.3
Client ID:
SFRA-110
Prep Basis:
Dry Weight
Batch ID:
26279
Method:
EPA Method 1613B
Run Date:
06/27/2014 10:19
Analyst:
JTF
Instrument:
HRP763
Data File:
A27JUN14A-4
Dilution:
1
Prep Batch:
26277
Prep Method:
SW846 3540C
Prep Date:
24-JUN-14
Prep Aliquot:
1.51 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
18.0
Pg/g
2.21
8.63
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
Page 21 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number: 6275
Client:
TETR001
Project: TETR00114
Lab Sample ID: 6275007
Date Collected:
06/23/2014 13:35
Matrix: SOLID
Client Sample: 1613B Soil
Date Received:
06/24/2014 14:50
%Moisture: 19.2
Client ID:
SFRA-111
Prep Basis: Dry Weight
Batch ID:
26279
Method:
EPA Method 1613B
Run Date:
06/26/2014 01:12
Analyst:
JTF
Instrument: HRP763
Data File:
b25junl4a-13
Dilution: 1
Prep Batch:
26277
Prep Method:
SW846 3540C
Prep Date:
24-JUN-14
Prep Aliquot:
ii §
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1520
Pg/g
3.29 11.3
40321-76-4
1,2,3,7,8-PeCDD
J
3.96
Pg/g
2.68 56.3
39227-28-6
1,2,3,4,7,8-HxCDD
J
6.08
Pg/g
3.89 56.3
57653-85-7
1,2,3,6,7,8-HxCDD
J
46.4
Pg/g
3.89 56.3
19408-74-3
1,2,3,7,8,9-HxCDD
J
17.3
Pg/g
4.12 56.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
1120
Pg/g
9.18 56.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
16600
Pg/g
12.2 113
51207-31-9
2,3,7,8-TCDF
J
10.9
Pg/g
3.24 11.3
57117-41-6
1,2,3,7,8-PeCDF
J
3.67
Pg/g
2.16 56.3
57117-31-4
2,3,4,7,8-PeCDF
J
5.92
Pg/g
1.98 56.3
70648-26-9
1,2,3,4,7,8-HxCDF
J
19.5
Pg/g
2.59 56.3
57II7.44.9
1,2,3,6,7,8-HxCDF
J
7.47
Pg/g
2.39 56.3
60851-34-5
2,3,4,6,7,8-HxCDF
J
11.9
Pg/g
2.77 56.3
72918-21-9
1,2,3,7,8,9-HxCDF
J
6.19
Pg/g
4.05 56.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
187
Pg/g
2.45 56.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
U
19.5
Pg/g
19.5 56.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
511
Pg/g
5.47 113
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1800
2250
Pg/g
80.2
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1920
2250
Pg/g
85.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1920
2250
Pg/g
85.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1880
2250
Pg/g
83.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1910
2250
Pg/g
84.8
(23%-140%)
13C-OCDD
3310
4500
Pg/g
73.6
(17%-157%)
13C-2,3,7,8-TCDF
1950
2250
Pg/g
86.6
(24%-169%)
130-1,2,3,7,8-
PeCDF
1950
2250
Pg/g
86.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
2070
2250
Pg/g
92.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2050
2250
Pg/g
90.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1980
2250
Pg/g
88.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2000
2250
Pg/g
89.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1840
2250
Pg/g
81.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1930
2250
Pg/g
85.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1740
2250
Pg/g
77.4
(26%-13 8%)
3701-2,3,7,8-TCDD
224
225
Pg/g
99.5
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 22 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 6275008
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/23/2014 13:40
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 23.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-112
26279
06/26/2014 13:30
b25junl4a_2-13
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.54 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
7690
Pg/g
9.07 42.5
40321-76-4
1,2,3,7,8-PeCDD
U
8.76
Pg/g
8.76 212
39227-28-6
1,2,3,4,7,8-HxCDD
u
10.1
Pg/g
10.1 212
57653-85-7
1,2,3,6,7,8-HxCDD
u
81.4
Pg/g
81.4 212
19408-74-3
1,2,3,7,8,9-HxCDD
J
25.1
Pg/g
11.0 212
35822-46-9
1,2,3,4,6,7,8-HpCDD
993
Pg/g
26.8 212
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13900
Pg/g
48.6 425
51207-31-9
2,3,7,8-TCDF
45.9
Pg/g
13.1 42.5
57117-41-6
1,2,3,7,8-PeCDF
u
4.52
Pg/g
4.52 212
57117-31-4
2,3,4,7,8-PeCDF
J
4.88
Pg/g
4.40 212
70648-26-9
1,2,3,4,7,8-HxCDF
J
21.5
Pg/g
8.93 212
57II7.44.9
1,2,3,6,7,8-HxCDF
u
11.4
Pg/g
11.4 212
60851-34-5
2,3,4,6,7,8-HxCDF
u
19.2
Pg/g
19.2 212
72918-21-9
1,2,3,7,8,9-HxCDF
u
14.4
Pg/g
14.4 212
67562-39-4
1,2,3,4,6,7,8-HpCDF
292
Pg/g
14.4 212
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
23.6
Pg/g
23.6 212
39001-02-0
1,2,3,4,6,7,8,9-OCDF
451
Pg/g
42.1 425
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1410
1700
Pg/g
83.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1360
1700
Pg/g
80.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1470
1700
Pg/g
86.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1410
1700
Pg/g
82.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1420
1700
Pg/g
83.5
(23%-140%)
13C-OCDD
2360
3400
Pg/g
69.6
(17%-157%)
13C-2,3,7,8-TCDF
1450
1700
Pg/g
85.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
1400
1700
Pg/g
82.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1470
1700
Pg/g
86.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1550
1700
Pg/g
91.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1530
1700
Pg/g
90.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1500
1700
Pg/g
88.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1310
1700
Pg/g
77.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1410
1700
Pg/g
83.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1330
1700
Pg/g
78.3
(26%-13 8%)
3701-2,3,7,8-TCDD
191
170
Pg/g
112
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 23 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30,2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6275
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6275008
Date Collected:
06/23/2014 13:40
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
06/24/2014 14:50
%Moisture:
23.5
Client ID:
SFRA-112
Prep Basis:
Dry Weight
Batch ID:
26279
Method:
EPA Method 1613B
Run Date:
06/27/2014 11:03
Analyst:
JTF
Instrument:
HRP763
Data File:
A27JUN14A-5
Dilution:
5
Prep Batch:
26277
Prep Method:
SW846 3540C
Prep Date:
24-JUN-14
Prep Aliquot:
1.54 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
47.0
Pg/g
8.76
42.5
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 24 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 6275009
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/23/2014 17:34
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 18.5
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-113
26279
06/26/2014 14:18
b25junl4a_2-14
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.89 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
179
Pg/g
1.31 6.49
40321-76-4
1,2,3,7,8-PeCDD
U
.948
Pg/g
0.948 32.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
1.96
Pg/g
1.96 32.5
57653-85-7
1,2,3,6,7,8-HxCDD
u
2.09
Pg/g
2.09 32.5
19408-74-3
1,2,3,7,8,9-HxCDD
u
2.16
Pg/g
2.16 32.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
53.7
Pg/g
3.34 32.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
3010
Pg/g
8.39 64.9
51207-31-9
2,3,7,8-TCDF
J
1.73
Pg/g
0.957 6.49
57117-41-6
1,2,3,7,8-PeCDF
u
.495
Pg/g
0.495 32.5
57117-31-4
2,3,4,7,8-PeCDF
u
.452
Pg/g
0.452 32.5
70648-26-9
1,2,3,4,7,8-HxCDF
u
1.12
Pg/g
1.12 32.5
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.11
Pg/g
1.11 32.5
60851-34-5
2,3,4,6,7,8-HxCDF
u
1.17
Pg/g
1.17 32.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
1.8
Pg/g
1.80 32.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
6.09
Pg/g
1.35 32.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
2.45
Pg/g
2.45 32.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
15.2
Pg/g
3.90 64.9
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1060
1300
Pg/g
81.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1060
1300
Pg/g
81.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1190
1300
Pg/g
91.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1060
1300
Pg/g
81.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1100
1300
Pg/g
84.9
(23%-140%)
13C-OCDD
1840
2600
Pg/g
70.7
(17%-157%)
13C-2,3,7,8-TCDF
1130
1300
Pg/g
86.8
(24%-169%)
130-1,2,3,7,8-
PeCDF
1090
1300
Pg/g
84.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
1160
1300
Pg/g
89.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1220
1300
Pg/g
94.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1180
1300
Pg/g
90.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1180
1300
Pg/g
90.8
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1040
1300
Pg/g
80.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1120
1300
Pg/g
86.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1020
1300
Pg/g
78.6
(26%-13 8%)
3701-2,3,7,8-TCDD
122
130
Pg/g
94.1
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 25 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 6275010
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/23/2014 17:40
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 14.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-114
26279
06/26/2014 05:18
b25junl4a_2-3
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.22 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
352
Pg/g
2.09 9.59
40321-76-4
1,2,3,7,8-PeCDD
U
1.35
Pg/g
1.35 48.0
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.21
Pg/g
2.21 48.0
57653-85-7
1,2,3,6,7,8-HxCDD
J
5.66
Pg/g
2.25 48.0
19408-74-3
1,2,3,7,8,9-HxCDD
u
2.69
Pg/g
2.69 48.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
116
Pg/g
4.57 48.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
4130
Pg/g
7.58 95.9
51207-31-9
2,3,7,8-TCDF
J
2.59
Pg/g
1.79 9.59
57117-41-6
1,2,3,7,8-PeCDF
u
1.17
Pg/g
1.17 48.0
57117-31-4
2,3,4,7,8-PeCDF
u
1.06
Pg/g
1.06 48.0
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.55
Pg/g
2.55 48.0
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.41
Pg/g
1.41 48.0
60851-34-5
2,3,4,6,7,8-HxCDF
u
1.48
Pg/g
1.48 48.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.36
Pg/g
2.36 48.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
18.7
Pg/g
2.26 48.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
3.93
Pg/g
3.93 48.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
28.6
Pg/g
6.39 95.9
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1590
1920
Pg/g
82.9
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1570
1920
Pg/g
81.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1740
1920
Pg/g
90.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1630
1920
Pg/g
84.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1600
1920
Pg/g
83.4
(23%-140%)
13C-OCDD
2710
3840
Pg/g
70.6
(17%-157%)
13C-2,3,7,8-TCDF
1710
1920
Pg/g
88.9
(24%-169%)
130-1,2,3,7,8-
PeCDF
1620
1920
Pg/g
84.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1720
1920
Pg/g
89.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1800
1920
Pg/g
93.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1740
1920
Pg/g
90.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1760
1920
Pg/g
92.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1540
1920
Pg/g
80.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1630
1920
Pg/g
85.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1490
1920
Pg/g
77.4
(26%-13 8%)
3701-2,3,7,8-TCDD
181
192
Pg/g
94.4
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 26 of 42
-------
Quality Control
Summary
Page 27 of 42
-------
( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 1 of 5
Surrogate Recovery Report
SDG Number: 6275
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010786
LCS for batch 26277
12010787
LCSD for batch 26277
12010785
MB for batch 26277
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
85.8
84.8
92.4
90.7
96.4
81.4
92.8
85.5
89.2
103
96.0
98.0
89.1
94.5
90.0
97.6
68.5
71.5
69.0
67.2
73.1
66.3
74.7
73.5
77.8
72.2
71.1
71.7
69.8
71.3
70.9
99.8
86.9
90.4
90.9
89.7
91.7
81.6
94.0
92.3
96.4
99.1
91.7
94.6
88.6
92.8
89.3
96.4
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6275001
SFRA-105
13C-2,3,7,8-TCDD
72.8
(25%-164%)
Page 28 of 42
-------
( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 2 of 5
Surrogate Recovery Report
SDG Number: 6275
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6275001
SFRA-105
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
77.9
74.2
72.9
79.7
71.7
81.6
77.3
82.8
81.5
75.7
79.2
76.9
76.9
77.0
94.3
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010788
SFRA-105(627500 IMS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
81.6
85.9
85.1
80.4
85.5
85.4
88.2
86.3
92.8
89.2
87.8
88.3
85.1
86.0
84.0
102
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010789
SFRA-105(6275001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
82.5
86.7
88.8
77.7
84.8
75.8
89.1
85.8
94.2
90.0
86.4
87.1
83.9
85.4
82.5
99.4
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6275004
SFRA-108
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
87.3
85.8
(25%-
(25%-
64%)
81%)
Page 29 of 42
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( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 3 of 5
Surrogate Recovery Report
SDG Number: 6275
Matrix Type: SOLID
Sample ID Client ID
6275004 SFRA-108
6275007 SFRA-111
6275010 SFRA-114
6275003 SFRA-107
Surrogate
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
Recovery Acceptance
QUAL (%) Limits
88.7 (32%-141%)
82.7 (28%-130%)
86.4 (23%-140%)
76.1 (17%-15 7%)
93.5 (24%-169%)
88.5 (24%-185%)
93.9 (21%-178%)
92.7 (26%-152%)
89.9 (26%-123%)
90.2 (28%-13 6%)
85.6 (29%-147%)
86.7 (28%-143%)
81.1 (26%-13 8%)
101 (35%-197%)
80.2 (25%-164%)
85.1 (25%-181%)
85.3 (32%-141%)
83.6 (28%-130%)
84.8 (23%-140%)
73.6 (17%-15 7%)
86.6 (24%-169%)
86.7 (24%-185%)
92.2 (21%-178%)
90.9 (26%-152%)
88.0 (26%-123%)
89.0 (28%-13 6%)
81.8 (29%-147%)
85.9 (28%-143%)
77.4 (26%-13 8%)
99.5 (35%-197%)
82.9 (25%-164%)
81.7 (25%-181%)
90.9 (32%-141%)
84.9 (28%-130%)
83.4 (23%-140%)
70.6 (17%-15 7%)
88.9 (24%-169%)
84.6 (24%-185%)
89.6 (21%-178%)
93.6 (26%-152%)
90.6 (26%-123%)
92.0 (28%-13 6%)
80.3 (29%-147%)
85.1 (28%-143%)
77.4 (26%-13 8%)
94.4 (35%-197%)
80.6 (25%-164%)
80.3 (25%-181%)
86.1 (32%-141%)
Page 30 of 42
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( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 4 of 5
Surrogate Recovery Report
SDG Number: 6275
Matrix Type: SOLID
Sample ID Client ID
6275003 SFRA-107
6275006 SFRA-110
6275008 SFRA-112
6275009 SFRA-113
Surrogate
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
Recovery Acceptance
QUAL (%) Limits
84.2
(28%-130%)
84.2
(23%-140%)
71.6
(17%-15 7%)
84.7
(24%-169%)
81.4
(24%-185%)
89.8
(21%-178%)
92.1
(26%-152%)
88.8
(26%-123%)
89.1
(28%-13 6%)
83.5
(29%-147%)
84.8
(28%-143%)
79.0
(26%-13 8%)
96.6
(35%-197%)
80.2
(25%-164%)
81.3
(25%-181%)
90.7
(32%-141%)
83.7
(28%-130%)
88.4
(23%-140%)
72.7
(17%-15 7%)
85.3
(24%-169%)
83.8
(24%-185%)
89.4
(21%-178%)
94.9
(26%-152%)
92.7
(26%-123%)
94.1
(28%-13 6%)
85.5
(29%-147%)
88.7
(28%-143%)
81.7
(26%-13 8%)
99.6
(35%-197%)
83.0
D
(25%-164%)
80.1
D
(25%-181%)
86.5
D
(32%-141%)
82.8
D
(28%-130%)
83.5
D
(23%-140%)
69.6
D
(17%-15 7%)
85.2
D
(24%-169%)
82.3
D
(24%-185%)
86.6
D
(21%-178%)
91.2
D
(26%-152%)
90.1
D
(26%-123%)
88.1
D
(28%-13 6%)
77.3
D
(29%-147%)
83.0
D
(28%-143%)
78.3
D
(26%-13 8%)
112
D
(35%-197%)
81.4 (25%-164%)
81.7 (25%-181%)
91.3 (32%-141%)
81.4 (28%-130%)
Page 31 of 42
-------
( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 5 of 5
Surrogate Recovery Report
SDG Number: 6275
Matrix Type: SOLID
Sample ID Client ID
6275009 SFRA-113
6275002 SFRA-106
6275005 SFRA-109
Surrogate
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
84.9
(23%-140%)
70.7
(17%-15 7%)
86.8
(24%-169%)
84.1
(24%-185%)
89.6
(21%-178%)
94.1
(26%-152%)
90.7
(26%-123%)
90.8
(28%-13 6%)
80.4
(29%-147%)
86.6
(28%-143%)
78.6
(26%-13 8%)
94.1
(35%-197%)
64.8
D
(25%-164%)
59.7
D
(25%-181%)
63.2
D
(32%-141%)
66.9
D
(28%-130%)
64.3
D
(23%-140%)
53.9
D
(17%-15 7%)
71.2
D
(24%-169%)
62.3
D
(24%-185%)
65.2
D
(21%-178%)
69.7
D
(26%-152%)
68.5
D
(26%-123%)
68.0
D
(28%-13 6%)
60.3
D
(29%-147%)
65.4
D
(28%-143%)
59.7
D
(26%-13 8%)
108
D
(35%-197%)
79.3
D
(25%-164%)
74.0
D
(25%-181%)
81.5
D
(32%-141%)
79.4
D
(28%-130%)
76.3
D
(23%-140%)
60.1
D
(17%-15 7%)
82.5
D
(24%-169%)
76.0
D
(24%-185%)
78.9
D
(21%-178%)
83.7
D
(26%-152%)
85.8
D
(26%-123%)
82.6
D
(28%-13 6%)
73.4
D
(29%-147%)
77.6
D
(28%-143%)
70.1
D
(26%-13 8%)
116
D
(35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 32 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/25/2014 16:28 Dilution: 1
Prep Batch ID:26277
Batch ID: 26279
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.4
107
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
105
105
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
109
109
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
112
112
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
110
110
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
106
106
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
212
106
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
21.5
107
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
109
109
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
107
107
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
108
108
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
107
107
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
107
107
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
116
116
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
105
105
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
107
107
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
222
111
63-170
SDG Number: 6275
Client ID: LCS for batch 26277
Lab Sample ID: 12010786
Instrument: HRP763
Analyst: JTF
Page
33 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/25/2014 17:15 Dilution: 1
Prep Batch ID:26277
Batch ID: 26279
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.9
110
67-158
2.51
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
106
106
70-142
0.409
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
106
106
70-164
2.59
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
105
105
76-134
5.79
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
108
108
64-162
1.65
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
106
106
70-140
0.0809
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
206
103
78-144
2.69
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
21.6
108
75-158
0.585
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
107
107
80-134
2.04
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
104
104
68-160
2.99
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
107
107
72-134
0.777
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
103
103
84-130
3.64
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
105
105
70-156
1.25
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
113
113
78-130
2.99
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
104
104
82-122
0.915
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
105
105
78-138
1.38
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
226
113
63-170
1.98
0-20
SDG Number: 6275
Client ID: LCSD for batch 26277
Lab Sample ID: 12010787
Instrument: HRP763
Analyst: JTF
Page
34 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
174
232
30.1 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
868
U
884
102
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
868
U
912
105
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
868
J
925
106
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
868
J
934
107
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
868
967
103
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
1740
6960
81.3
70-130
51207-31-9
MS
2,3,7,8-TCDF
174
J
189
108
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
868
U
908
105
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
868
u
895
103
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
868
u
909
105
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
868
u
891
103
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
868
u
908
105
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
868
u
956
110
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
868
J
886
101
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
868
u
892
103
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
1740
J
1850
106
70-130
SDG Number: 6275
Client ID: SFRA-105(6275001MS)
Lab Sample ID: 12010788
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 19.4
Analysis Date: 06/25/2014 19:38
Prep Batch ID:26277
Batch ID: 26279
Page 35 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 19.4
Analysis Date: 06/25/2014 20:26 Dilution: 1
Prep Batch ID:26277
Batch ID: 26279
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
164
270
55.3 *
70-130
15.4
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
822
U
878
107
70-130
0.624
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
822
U
887
108
70-130
2.69
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
822
J
894
109
70-130
3.37
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
822
J
890
108
70-130
4.82
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
822
961
108
70-130
0.639
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
1640
7160
97.6
70-130
2.74
0-20
51207-31-9
MSD
2,3,7,8-TCDF
164
J
185
112
70-130
1.88
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
822
U
928
113
70-130
2.20
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
822
u
891
108
70-130
0.444
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
822
u
890
108
70-130
2.11
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
822
u
894
109
70-130
0.357
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
822
u
905
110
70-130
0.379
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
822
u
948
115
70-130
0.817
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
822
J
860
104
70-130
2.90
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
822
u
888
108
70-130
0.446
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
1640
J
1860
113
70-130
0.838
0-20
SDG Number: 6275
Client ID: SFRA-105(6275001MSD)
Lab Sample ID: 12010789
Instrument: HRP763
Analyst: JTF
Page
36 of 42
-------
Cape Fear Analytical LLC
Report Date: June 30,2014
Method Blank Summary Page ' °' '
SDG Number:
6275
Client:
TETR001
Matrix:
SOLID
Client ID:
MB for batch 26277
Instrument ID:
HRP763
Data File:
b25junl4a-4
Lab Sample ID:
Column:
12010785
Prep Date:
24-JUN-14
Analyzed:
06/25/14 18:03
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01 LCS for batch 26277
12010786
b25junl4a-2
06/25/14
1628
02 LCSD for batch 26277
12010787
b25junl4a-3
06/25/14
1715
03 SFRA-105
6275001
b25junl4a-5
06/25/14
1850
04 SFRA-105(627500IMS)
12010788
b25junl4a-6
06/25/14
1938
05 SFRA-105(6275001MSD)
12010789
b25junl4a-7
06/25/14
2026
06 SFRA-108
6275004
b25junl4a-10
06/25/14
2249
07 SFRA- 111
6275007
b25junl4a-13
06/26/14
0112
08 SFRA-114
6275010
b25junl4a_2-3
06/26/14
0518
09 SFRA-107
6275003
b25junl4a_2-9
06/26/14
1017
10 SFRA-110
6275006
b25junl4a_2-10
06/26/14
1107
11 SFRA-112
6275008
b25junl4a_2-13
06/26/14
1330
12 SFRA-113
6275009
b25junl4a_2-14
06/26/14
1418
13 SFRA-106
6275002
b26junl4a-5
06/26/14
1840
14 SFRA-109
6275005
b26junl4a-6
06/26/14
1928
15 SFRA-110
6275006
A27JUN14A-4
06/27/14
1019
16 SFRA-112
6275008
A27JUN14A-5
06/27/14
1103
17 SFRA-106
6275002
A27JUN14A-6
06/27/14
1122
18 SFRA-109
6275005
A27JUN14A-7
06/27/14
1141
Page 37 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6275
12010785
QC for batch 26277
MB for batch 26277
26279
06/25/2014 18:03
b25junl4a-4
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
Prep Batch:
26277
Prep Method:
SW846 3540C
Prep Date:
24-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.192
Pg/g
0.192
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.156
Pg/g
0.156
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.192
Pg/g
0.192
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.189
Pg/g
0.189
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.202
Pg/g
0.202
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.358
Pg/g
0.300
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
1.19
Pg/g
0.374
10.0
51207-31-9
2,3,7,8-TCDF
u
.128
Pg/g
0.128
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.134
Pg/g
0.0744
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.0726
Pg/g
0.0726
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.152
Pg/g
0.120
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
J
0.140
Pg/g
0.116
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.152
Pg/g
0.132
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.19
Pg/g
0.190
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.248
Pg/g
0.125
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.206
Pg/g
0.206
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.536
Pg/g
0.536
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
174
200
Pg/g
86.9
(25 %-164%)
13C-1,2,3,7,8-PeCDD
181
200
Pg/g
90.4
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
182
200
Pg/g
90.9
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
179
200
Pg/g
89.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
183
200
Pg/g
91.7
(23%-140%)
13C-OCDD
326
400
Pg/g
81.6
(17%-157%)
13C-2,3,7,8-TCDF
188
200
Pg/g
94.0
(24%-169%)
13C-1,2,3,7,8-PeCDF
185
200
Pg/g
92.3
(24%-185%)
13C-2,3,4,7,8-PeCDF
193
200
Pg/g
96.4
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
198
200
Pg/g
99.1
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
183
200
Pg/g
91.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
189
200
Pg/g
94.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
177
200
Pg/g
88.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
186
200
Pg/g
92.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
179
200
Pg/g
89.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
19.3
20.0
Pg/g
96.4
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 38 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 12010786
Client Sample: *or batch 26277
Client ID: LCS for batch 26277
Batch ID: 26279
Run Date: 06/25/2014 16:28
Data File: b25junl4a-2
Prep Batch: 26277
Prep Date: 24-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.4
Pg/g
0.173 1.00
40321-76-4
1,2,3,7,8-PeCDD
105
Pg/g
0.165 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
109
Pg/g
0.286 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
112
Pg/g
0.268 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
110
Pg/g
0.294 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
106
Pg/g
0.380 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
212
Pg/g
0.566 10.0
51207-31-9
2,3,7,8-TCDF
21.5
Pg/g
0.122 1.00
57117-41-6
1,2,3,7,8-PeCDF
109
Pg/g
0.171 5.00
57117-31-4
2,3,4,7,8-PeCDF
107
Pg/g
0.168 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
108
Pg/g
0.272 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
107
Pg/g
0.260 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
107
Pg/g
0.296 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
116
Pg/g
0.450 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
105
Pg/g
0.262 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
107
Pg/g
0.452 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
222
Pg/g
0.814 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
172
200
Pg/g
85.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
170
200
Pg/g
84.8
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
185
200
Pg/g
92.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
181
200
Pg/g
90.7
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
193
200
Pg/g
96.4
(22%-166%)
13C-OCDD
326
400
Pg/g
81.4
(13%-199%)
13C-2,3,7,8-TCDF
186
200
Pg/g
92.8
(22%-152%)
13C-1,2,3,7,8-
PeCDF
171
200
Pg/g
85.5
(21%-192%)
130-2,3,4,7,8-
PeCDF
178
200
Pg/g
89.2
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
206
200
Pg/g
103
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
192
200
Pg/g
96.0
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
196
200
Pg/g
98.0
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
178
200
Pg/g
89.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
189
200
Pg/g
94.5
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
180
200
Pg/g
90.0
(20%-186%)
3701-2,3,7,8-TCDD
19.5
20.0
Pg/g
97.6
(31 %-191%)
Comments:
Page 39 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6275
12010787
QC for batch 26277
LCSD for batch 26277
26279
06/25/2014 17:15
b25junl4a-3
26277
24-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.9
Pg/g
0.282 1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.194 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
106
Pg/g
0.312 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
105
Pg/g
0.312 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
108
Pg/g
0.332 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
106
Pg/g
0.546 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
206
Pg/g
0.622 10.0
51207-31-9
2,3,7,8-TCDF
21.6
Pg/g
0.174 1.00
57117-41-6
1,2,3,7,8-PeCDF
107
Pg/g
0.167 5.00
57117-31-4
2,3,4,7,8-PeCDF
104
Pg/g
0.157 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
107
Pg/g
0.434 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
103
Pg/g
0.394 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
105
Pg/g
0.448 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
113
Pg/g
0.610 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
104
Pg/g
0.254 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
105
Pg/g
0.424 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
226
Pg/g
0.802 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
137
200
Pg/g
68.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
143
200
Pg/g
71.5
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
138
200
Pg/g
69.0
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
134
200
Pg/g
67.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
146
200
Pg/g
73.1
(22%-166%)
13C-OCDD
265
400
Pg/g
66.3
(13%-199%)
13C-2,3,7,8-TCDF
149
200
Pg/g
74.7
(22%-152%)
13C-1,2,3,7,8-
PeCDF
147
200
Pg/g
73.5
(21%-192%)
130-2,3,4,7,8-
PeCDF
156
200
Pg/g
77.8
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
144
200
Pg/g
72.2
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
142
200
Pg/g
71.1
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
143
200
Pg/g
71.7
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
140
200
Pg/g
69.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
143
200
Pg/g
71.3
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
142
200
Pg/g
70.9
(20%-186%)
3701-2,3,7,8-TCDD
20.0
20.0
Pg/g
99.8
(31 %-191%)
Comments:
Page 40 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 12010788
Client Sample: *or batch 26277
Chent:
Date Collected:
Date Received:
TETR001
06/18/201411:11
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 19.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-105(6275001MS)
26279
06/25/2014 19:38
b25junl4a-6
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.43 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
232
Pg/g
2.03 8.68
40321-76-4
1,2,3,7,8-PeCDD
884
Pg/g
1.66 43.4
39227-28-6
1,2,3,4,7,8-HxCDD
912
Pg/g
2.88 43.4
57653-85-7
1,2,3,6,7,8-HxCDD
925
Pg/g
2.86 43.4
19408-74-3
1,2,3,7,8,9-HxCDD
934
Pg/g
3.05 43.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
967
Pg/g
4.65 43.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
6960
Pg/g
8.12 86.8
51207-31-9
2,3,7,8-TCDF
189
Pg/g
1.51 8.68
57117-41-6
1,2,3,7,8-PeCDF
908
Pg/g
1.50 43.4
57117-31-4
2,3,4,7,8-PeCDF
895
Pg/g
1.42 43.4
70648-26-9
1,2,3,4,7,8-HxCDF
909
Pg/g
2.40 43.4
57II7.44.9
1,2,3,6,7,8-HxCDF
891
Pg/g
2.43 43.4
60851-34-5
2,3,4,6,7,8-HxCDF
908
Pg/g
2.66 43.4
72918-21-9
1,2,3,7,8,9-HxCDF
956
Pg/g
3.77 43.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
886
Pg/g
2.52 43.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
892
Pg/g
4.22 43.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1850
Pg/g
7.17 86.8
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1420
1740
Pg/g
81.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1490
1740
Pg/g
85.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1480
1740
Pg/g
85.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1400
1740
Pg/g
80.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1480
1740
Pg/g
85.5
(23%-140%)
13C-OCDD
2970
3470
Pg/g
85.4
(17%-157%)
13C-2,3,7,8-TCDF
1530
1740
Pg/g
88.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1500
1740
Pg/g
86.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1610
1740
Pg/g
92.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1550
1740
Pg/g
89.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1520
1740
Pg/g
87.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1530
1740
Pg/g
88.3
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1480
1740
Pg/g
85.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1490
1740
Pg/g
86.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1460
1740
Pg/g
84.0
(26%-13 8%)
3701-2,3,7,8-TCDD
177
174
Pg/g
102
(35%-197%)
Comments:
Page 41 of 42
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6275
Lab Sample ID: 12010789
Client Sample: *or batch 26277
Chent:
Date Collected:
Date Received:
TETR001
06/18/201411:11
06/24/2014 14:50
Project: TETR00114
Matrix: SOLID
%Moisture: 19.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-105(6275001MSD)
26279
06/25/2014 20:26
b25junl4a-7
26277
24-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.51 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
270
Pg/g
1.84 8.22
40321-76-4
1,2,3,7,8-PeCDD
878
Pg/g
1.35 41.1
39227-28-6
1,2,3,4,7,8-HxCDD
887
Pg/g
2.56 41.1
57653-85-7
1,2,3,6,7,8-HxCDD
894
Pg/g
2.65 41.1
19408-74-3
1,2,3,7,8,9-HxCDD
890
Pg/g
2.76 41.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
961
Pg/g
4.19 41.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
7160
Pg/g
7.12 82.2
51207-31-9
2,3,7,8-TCDF
185
Pg/g
1.40 8.22
57117-41-6
1,2,3,7,8-PeCDF
928
Pg/g
1.57 41.1
57117-31-4
2,3,4,7,8-PeCDF
891
Pg/g
1.38 41.1
70648-26-9
1,2,3,4,7,8-HxCDF
890
Pg/g
2.83 41.1
57II7.44.9
1,2,3,6,7,8-HxCDF
894
Pg/g
2.73 41.1
60851-34-5
2,3,4,6,7,8-HxCDF
905
Pg/g
2.83 41.1
72918-21-9
1,2,3,7,8,9-HxCDF
948
Pg/g
4.27 41.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
860
Pg/g
2.53 41.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
888
Pg/g
4.27 41.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1860
Pg/g
5.03 82.2
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1360
1640
Pg/g
82.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1430
1640
Pg/g
86.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1460
1640
Pg/g
88.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1280
1640
Pg/g
77.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1390
1640
Pg/g
84.8
(23%-140%)
13C-OCDD
2490
3290
Pg/g
75.8
(17%-157%)
13C-2,3,7,8-TCDF
1460
1640
Pg/g
89.1
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1410
1640
Pg/g
85.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
1550
1640
Pg/g
94.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1480
1640
Pg/g
90.0
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1420
1640
Pg/g
86.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1430
1640
Pg/g
87.1
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1380
1640
Pg/g
83.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1400
1640
Pg/g
85.4
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1360
1640
Pg/g
82.5
(26%-13 8%)
3701-2,3,7,8-TCDD
163
164
Pg/g
99.4
(35%-197%)
Comments:
Page 42 of 42
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
June 30. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6277
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 25, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 32
problem solved
-------
of
Project #:
CFA Quote#:
COC Number"':.
PO Number:
X~M
Cape Fear Analytical, LLC
Chain of Custody and,
CFA Work Order Number:
istody andAnalytical Request
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Name:
Phone #i
Sample Analysis Requested(S) (Fill in the number of containers for each test)
Jkject/SiteName.J1^gg/4r &•«»*!( JLb* Fax#:
Address:
i Collected by
aj/zsTbtti t<
3r fC
Send Results
Jected _ '!!
Sample ID
* For composites - indicate start and stop date/time
~Date Colldeied
(mm-dd-yy)
if ""To j&ptf'f.
•Time
Collected
(Military)
(hhrnm)
QCCode
(2)
Field
Filtered m
Sample
Matrix w
$
*51
<— Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
jrp^sP - /yr
C-if-'i
UoQ
sfA4 ~/f£
/**+
_sa?
6-&ri
f(g
seAJ -fn
4-^-M
??*o
v
Sfr4J~/JL&
£•21-ri
s
fx t
Rush: K Specify: 7*^
TAT Requested: Normal:
ubjcct to Surcharge)
Fax Results:
Yes
No
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 tLevel 3 ] / Level 4
Sample Collection' unie Zone
Eastern Pacific
Central Other _
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Time
-/Lf /Vfe?
Received by (signed) Date Time
uud^miatu^ 2Sjuup\ lOQO
CFA PM:
Method of Shipment:
jA. . .
Date Shipped;
Airbill #;
Airbill #:
ojrr
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N = Normal Sample, TB = Trip Blank, FD - Field Duplicate, IB - Equipment Blank, MS - Matrix Spike Sample, M8D = Matrix Spike Duplicate Sample,G - Grab, C = Composite
3.) Field Filtered: For liquid matrices. Indicate with a- V - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: DW-Drinking Water, GW=Groundwater, SW-Surface Water, WW-Waste Water, W Water. ML-Misc Liquid, SO=Soil, SD Sediment, SL-Sludge, SS-Solid Waste, O-Oil, Ff Filter, P=Wipe, U-Urine, F=Fecal, N-Nasal
5.) Sample Analysis Requested: Analytical method requested (i.e^SDOB, 1668B) and number ofcontainpra provided ior each ii.e.8290B -3,1668B-1).
6.) Preservative Type: HA = Hydrochloric Acid,NI = Nitric Acid, SH - Sodium Hydroxide, SA » Sulfuric Acid, AA = Ascorbic Acid, HX - Hexane, ST - Sodium Thiosul&te, If no preservative is added = leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intaff?
YES (m)
Cot
-------
SAMPLE RECEIPT CHECKLIST
Cope Feet Analytical
Client: T^2
jwork Order: (q
Shipping Company; ¦ C~
Date/Time Received v/WfOl4 (QOO
Suspected Hazard Information
Yes
NA
No
Shipped ss DOi Hsisroous- i j
Samples identified as Foreign Soil7
DOE Site Sample Packages
Ves j NA
NO*
Screened <0.5 rnR/hr?
. w^"
Samples < 2x background?
1 <-*
Air Sample Receipt Specific;
NA No
Air sample in shipment7
* Notify RSO of any responses in this column immediately.
Air Witness;
Sampie Receipt Criteria
Yes NA No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received im ad
and sealed?
Citdf Apptkgbit:
ie«t< brpfcgn.
Jking coriEcinfi otherj describe]
Chain of Custody documents included
with shipment?
Samples requiring cold preservation
within 0-6°C?
PreyyajjMion Method:
Ice bagi/ blue i« tir» ice r-or,t eth*. tdeicr&sj
Aqueous samples found to have visible
solids?
Sample IDs, containers zfitrteef.
Samples requiring chemical
preservation at proper pH?
Sample IDs. containers atlectetf and pH observed:
If preservative sriced, lots:
Samples requiring preservation have
no residual chlorine?
Sample IDs. container's sHtriee
If preservative added, lot*.
Samples received within holding time?
4/
Sample IDs, ?esii aflecied;
Sample IDs on COC match IDs on
containers?
U
Sample IDs, contsinerj sHetied:
Date & time of COC match date & time
on containers?
Sample iDi. conj5i*e
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 32
-------
Case Narrative
Page 5 of 32
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6277
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26287
Clean Up Batch Number: 26286
Extraction Batch Number: 26285
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6277001
SFRA-115
6277002
SFRA-116
6277003
SFRA-117
6277004
SFRA-118
6277005
SFRA-119
6277006
SFRA-120
6277007
SFRA-121
12010796
Method Blank (MB)
12010797
Laboratory Control Sample (LCS)
12010798
Laboratory Control Sample Duplicate (LCSD)
12010799
6277001(SFRA-115) Matrix Spike (MS)
12010800
6277001(SFRA-115) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Page 6 of 32
-------
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6277001 (SFRA-115) - Batch 26287 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Recovery Statement
Two MS recoveries for this SDG were not within the acceptance limits. The failures confirm in
the matrix spike duplicate and are attributed to matrix interference. 12010799 (SFRA-115) and
12010800 (SFRA-115) - Batch 26287.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
Page 7 of 32
-------
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26287.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 32
-------
Sample Data Summary
Page 9 of 32
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Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6277 CFA Work Order: 6277
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 30JUN2014 Title: Data Validator
Page 10 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 6277001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/24/2014 12:00
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 14.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-115
26287
06/26/2014 20:24
b26junl4a-7
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
l.ii g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
413
Pg/g
2.36 10.6
40321-76-4
1,2,3,7,8-PeCDD
U
1.57
Pg/g
1.57 52.8
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.77
Pg/g
2.77 52.8
57653-85-7
1,2,3,6,7,8-HxCDD
J
6.48
Pg/g
2.72 52.8
19408-74-3
1,2,3,7,8,9-HxCDD
J
3.10
Pg/g
2.91 52.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
85.7
Pg/g
4.77 52.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
1520
Pg/g
9.99 106
51207-31-9
2,3,7,8-TCDF
J
5.30
Pg/g
2.07 10.6
57117-41-6
1,2,3,7,8-PeCDF
u
1.22
Pg/g
1.22 52.8
57117-31-4
2,3,4,7,8-PeCDF
u
1.14
Pg/g
1.14 52.8
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.01
Pg/g
2.01 52.8
57II7.44.9
1,2,3,6,7,8-HxCDF
J
3.40
Pg/g
1.95 52.8
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.08
Pg/g
2.08 52.8
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.27
Pg/g
3.27 52.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
28.5
Pg/g
1.97 52.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
3.67
Pg/g
3.67 52.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
54.9
Pg/g
8.17 106
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1840
2110
Pg/g
86.9
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1780
2110
Pg/g
84.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1880
2110
Pg/g
89.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1820
2110
Pg/g
86.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1770
2110
Pg/g
84.1
(23%-140%)
13C-OCDD
2990
4220
Pg/g
70.8
(17%-157%)
13C-2,3,7,8-TCDF
1960
2110
Pg/g
92.9
(24%-169%)
130-1,2,3,7,8-
PeCDF
1840
2110
Pg/g
87.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1920
2110
Pg/g
90.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1940
2110
Pg/g
91.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1950
2110
Pg/g
92.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1900
2110
Pg/g
90.0
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1740
2110
Pg/g
82.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1810
2110
Pg/g
85.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1660
2110
Pg/g
78.7
(26%-13 8%)
3701-2,3,7,8-TCDD
216
211
Pg/g
102
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 32
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Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 6277002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/24/2014 12:07
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 17.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-116
26287
06/26/2014 21:11
b26junl4a-8
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.07 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
851
Pg/g
2.87 11.3
40321-76-4
1,2,3,7,8-PeCDD
J
3.00
Pg/g
2.06 56.5
39227-28-6
1,2,3,4,7,8-HxCDD
J
3.48
Pg/g
2.96 56.5
57653-85-7
1,2,3,6,7,8-HxCDD
J
30.0
Pg/g
2.80 56.5
19408-74-3
1,2,3,7,8,9-HxCDD
J
9.06
Pg/g
3.05 56.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
364
Pg/g
5.94 56.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9110
Pg/g
12.7 113
51207-31-9
2,3,7,8-TCDF
J
8.24
Pg/g
2.44 11.3
57117-41-6
1,2,3,7,8-PeCDF
J
1.51
Pg/g
1.20 56.5
57117-31-4
2,3,4,7,8-PeCDF
J
2.98
Pg/g
1.09 56.5
70648-26-9
1,2,3,4,7,8-HxCDF
U
7.27
Pg/g
7.27 56.5
57II7.44.9
1,2,3,6,7,8-HxCDF
J
4.74
Pg/g
1.93 56.5
60851-34-5
2,3,4,6,7,8-HxCDF
J
6.32
Pg/g
2.01 56.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.23
Pg/g
3.23 56.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
93.8
Pg/g
2.26 56.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
5.40
Pg/g
3.73 56.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
132
Pg/g
6.46 113
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1950
2260
Pg/g
86.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1950
2260
Pg/g
86.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2160
2260
Pg/g
95.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2170
2260
Pg/g
96.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2110
2260
Pg/g
93.5
(23%-140%)
13C-OCDD
3950
4520
Pg/g
87.5
(17%-157%)
13C-2,3,7,8-TCDF
2120
2260
Pg/g
93.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1990
2260
Pg/g
88.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
2140
2260
Pg/g
94.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2240
2260
Pg/g
99.0
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2250
2260
Pg/g
99.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2260
2260
Pg/g
100
(28%-136%)
130-1,2,3,7,8,9-HxCDF
2020
2260
Pg/g
89.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2160
2260
Pg/g
95.5
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2030
2260
Pg/g
89.7
(26%-13 8%)
3701-2,3,7,8-TCDD
215
226
Pg/g
95.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 6277003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/24/2014 12:12
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 21.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-117
26287
06/26/2014 21:59
b26junl4a-9
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.04 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1160
Pg/g
2.53 12.3
40321-76-4
1,2,3,7,8-PeCDD
J
4.81
Pg/g
2.60 61.3
39227-28-6
1,2,3,4,7,8-HxCDD
U
5.99
Pg/g
5.99 61.3
57653-85-7
1,2,3,6,7,8-HxCDD
J
57.8
Pg/g
6.11 61.3
19408-74-3
1,2,3,7,8,9-HxCDD
J
16.7
Pg/g
6.43 61.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
1150
Pg/g
8.95 61.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
18100
Pg/g
17.7 123
51207-31-9
2,3,7,8-TCDF
J
10.4
Pg/g
3.61 12.3
57117-41-6
1,2,3,7,8-PeCDF
J
2.40
Pg/g
1.51 61.3
57117-31-4
2,3,4,7,8-PeCDF
J
5.10
Pg/g
1.38 61.3
70648-26-9
1,2,3,4,7,8-HxCDF
J
18.8
Pg/g
2.75 61.3
57II7.44.9
1,2,3,6,7,8-HxCDF
J
7.95
Pg/g
2.70 61.3
60851-34-5
2,3,4,6,7,8-HxCDF
J
12.4
Pg/g
2.75 61.3
72918-21-9
1,2,3,7,8,9-HxCDF
J
5.96
Pg/g
4.27 61.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
224
Pg/g
3.41 61.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
18.7
Pg/g
5.99 61.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
474
Pg/g
8.88 123
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1950
2450
Pg/g
79.3
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1990
2450
Pg/g
81.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2190
2450
Pg/g
89.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2060
2450
Pg/g
83.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2060
2450
Pg/g
84.1
(23%-140%)
13C-OCDD
4020
4910
Pg/g
82.0
(17%-157%)
13C-2,3,7,8-TCDF
2100
2450
Pg/g
85.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
2030
2450
Pg/g
82.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
2110
2450
Pg/g
86.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2160
2450
Pg/g
88.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2090
2450
Pg/g
85.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2220
2450
Pg/g
90.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1930
2450
Pg/g
78.5
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2070
2450
Pg/g
84.2
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1940
2450
Pg/g
79.1
(26%-13 8%)
3701-2,3,7,8-TCDD
237
245
Pg/g
96.8
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 6277004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/24/2014 12:17
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 19.1
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-118
26287
06/26/2014 22:47
b26junl4a-10
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.04 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1140
Pg/g
2.92 11.9
40321-76-4
1,2,3,7,8-PeCDD
U
2.33
Pg/g
2.33 59.4
39227-28-6
1,2,3,4,7,8-HxCDD
u
4.14
Pg/g
4.14 59.4
57653-85-7
1,2,3,6,7,8-HxCDD
J
27.9
Pg/g
3.83 59.4
19408-74-3
1,2,3,7,8,9-HxCDD
J
8.56
Pg/g
4.07 59.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
628
Pg/g
8.27 59.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
15900
Pg/g
20.3 119
51207-31-9
2,3,7,8-TCDF
J
8.30
Pg/g
3.26 11.9
57117-41-6
1,2,3,7,8-PeCDF
J
2.26
Pg/g
1.89 59.4
57117-31-4
2,3,4,7,8-PeCDF
J
3.02
Pg/g
1.79 59.4
70648-26-9
1,2,3,4,7,8-HxCDF
J
8.51
Pg/g
2.02 59.4
57II7.44.9
1,2,3,6,7,8-HxCDF
J
3.78
Pg/g
2.01 59.4
60851-34-5
2,3,4,6,7,8-HxCDF
J
5.04
Pg/g
2.03 59.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.38
Pg/g
3.38 59.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
101
Pg/g
2.73 59.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
6.30
Pg/g
4.92 59.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
255
Pg/g
7.32 119
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1990
2380
Pg/g
83.6
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1950
2380
Pg/g
82.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
2370
2380
Pg/g
99.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2070
2380
Pg/g
87.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2260
2380
Pg/g
95.0
(23%-140%)
13C-OCDD
4110
4750
Pg/g
86.4
(17%-157%)
13C-2,3,7,8-TCDF
2130
2380
Pg/g
89.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
1990
2380
Pg/g
83.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
2110
2380
Pg/g
88.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2420
2380
Pg/g
102
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2310
2380
Pg/g
97.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2440
2380
Pg/g
103
(28%-136%)
130-1,2,3,7,8,9-HxCDF
2100
2380
Pg/g
88.2
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
2280
2380
Pg/g
96.0
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2110
2380
Pg/g
88.6
(26%-13 8%)
3701-2,3,7,8-TCDD
239
238
Pg/g
101
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 6277005
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/23/2014 17:00
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 19.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-119
26287
06/26/2014 23:34
b26junl4a-ll
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.19 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
590
Pg/g
1.99 10.5
40321-76-4
1,2,3,7,8-PeCDD
U
1.83
Pg/g
1.83 52.3
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.76
Pg/g
2.76 52.3
57653-85-7
1,2,3,6,7,8-HxCDD
J
10.2
Pg/g
2.89 52.3
19408-74-3
1,2,3,7,8,9-HxCDD
J
3.79
Pg/g
3.01 52.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
201
Pg/g
7.20 52.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
6610
Pg/g
11.7 105
51207-31-9
2,3,7,8-TCDF
J
5.25
Pg/g
2.30 10.5
57117-41-6
1,2,3,7,8-PeCDF
u
1.1
Pg/g
1.10 52.3
57117-31-4
2,3,4,7,8-PeCDF
u
1.17
Pg/g
1.17 52.3
70648-26-9
1,2,3,4,7,8-HxCDF
J
3.41
Pg/g
1.61 52.3
57II7.44.9
1,2,3,6,7,8-HxCDF
J
2.26
Pg/g
1.58 52.3
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.05
Pg/g
2.05 52.3
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.68
Pg/g
2.68 52.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
34.2
Pg/g
1.83 52.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
4.56
Pg/g
3.31 52.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
75.4
Pg/g
6.03 105
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1710
2090
Pg/g
81.5
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1640
2090
Pg/g
78.3
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1890
2090
Pg/g
90.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1760
2090
Pg/g
84.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1870
2090
Pg/g
89.5
(23%-140%)
13C-OCDD
3300
4190
Pg/g
78.8
(17%-157%)
13C-2,3,7,8-TCDF
1830
2090
Pg/g
87.3
(24%-169%)
130-1,2,3,7,8-
PeCDF
1640
2090
Pg/g
78.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1730
2090
Pg/g
82.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1980
2090
Pg/g
94.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1890
2090
Pg/g
90.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1940
2090
Pg/g
92.5
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1730
2090
Pg/g
82.8
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1870
2090
Pg/g
89.2
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1730
2090
Pg/g
82.6
(26%-13 8%)
3701-2,3,7,8-TCDD
202
209
Pg/g
96.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 6277006
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/24/2014 16:45
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 16.4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-120
26287
06/27/2014 00:22
b26junl4a-12
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.27 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
669
Pg/g
2.30 9.42
40321-76-4
1,2,3,7,8-PeCDD
U
1.8
Pg/g
1.80 47.1
39227-28-6
1,2,3,4,7,8-HxCDD
u
2.34
Pg/g
2.34 47.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
12.8
Pg/g
2.39 47.1
19408-74-3
1,2,3,7,8,9-HxCDD
J
4.20
Pg/g
2.51 47.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
270
Pg/g
5.18 47.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5710
Pg/g
10.2 94.2
51207-31-9
2,3,7,8-TCDF
J
4.61
Pg/g
1.81 9.42
57117-41-6
1,2,3,7,8-PeCDF
u
.955
Pg/g
0.955 47.1
57117-31-4
2,3,4,7,8-PeCDF
J
0.942
Pg/g
0.902 47.1
70648-26-9
1,2,3,4,7,8-HxCDF
u
3.86
Pg/g
3.86 47.1
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.22
Pg/g
2.22 47.1
60851-34-5
2,3,4,6,7,8-HxCDF
J
2.96
Pg/g
1.86 47.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.96
Pg/g
2.96 47.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
47.9
Pg/g
1.63 47.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
4.58
Pg/g
2.90 47.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
119
Pg/g
12.0 94.2
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1630
1880
Pg/g
86.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1540
1880
Pg/g
82.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1790
1880
Pg/g
94.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1580
1880
Pg/g
84.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1720
1880
Pg/g
91.3
(23%-140%)
13C-OCDD
3080
3770
Pg/g
81.8
(17%-157%)
13C-2,3,7,8-TCDF
1760
1880
Pg/g
93.7
(24%-169%)
130-1,2,3,7,8-
PeCDF
1610
1880
Pg/g
85.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
1670
1880
Pg/g
88.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1830
1880
Pg/g
97.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1760
1880
Pg/g
93.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1800
1880
Pg/g
95.8
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1640
1880
Pg/g
87.3
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1760
1880
Pg/g
93.4
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1630
1880
Pg/g
86.4
(26%-13 8%)
3701-2,3,7,8-TCDD
193
188
Pg/g
102
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 6277007
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/24/2014 16:50
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 18.8
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-121
26287
06/27/2014 01:10
b26junl4a-13
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.26 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1560
Pg/g
3.13 9.77
40321-76-4
1,2,3,7,8-PeCDD
U
2.78
Pg/g
2.78 48.9
39227-28-6
1,2,3,4,7,8-HxCDD
u
4.24
Pg/g
4.24 48.9
57653-85-7
1,2,3,6,7,8-HxCDD
J
35.9
Pg/g
4.16 48.9
19408-74-3
1,2,3,7,8,9-HxCDD
J
10.5
Pg/g
4.46 48.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
493
Pg/g
7.54 48.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
10100
Pg/g
14.5 97.7
51207-31-9
2,3,7,8-TCDF
J
9.46
Pg/g
2.81 9.77
57117-41-6
1,2,3,7,8-PeCDF
u
1.66
Pg/g
1.66 48.9
57117-31-4
2,3,4,7,8-PeCDF
u
2.62
Pg/g
2.62 48.9
70648-26-9
1,2,3,4,7,8-HxCDF
J
7.68
Pg/g
2.09 48.9
57II7.44.9
1,2,3,6,7,8-HxCDF
J
5.10
Pg/g
1.94 48.9
60851-34-5
2,3,4,6,7,8-HxCDF
J
6.90
Pg/g
2.07 48.9
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.28
Pg/g
3.28 48.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
114
Pg/g
2.31 48.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
8.68
Pg/g
4.16 48.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
204
Pg/g
9.83 97.7
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1640
1950
Pg/g
84.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1550
1950
Pg/g
79.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1820
1950
Pg/g
93.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1680
1950
Pg/g
86.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1780
1950
Pg/g
91.2
(23%-140%)
13C-OCDD
3250
3910
Pg/g
83.0
(17%-157%)
13C-2,3,7,8-TCDF
1740
1950
Pg/g
89.2
(24%-169%)
130-1,2,3,7,8-
PeCDF
1580
1950
Pg/g
80.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1660
1950
Pg/g
84.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1900
1950
Pg/g
97.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1800
1950
Pg/g
92.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1840
1950
Pg/g
94.3
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1680
1950
Pg/g
85.7
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1790
1950
Pg/g
91.5
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1630
1950
Pg/g
83.4
(26%-13 8%)
3701-2,3,7,8-TCDD
197
195
Pg/g
101
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 32
-------
Quality Control
Summary
Page 18 of 32
-------
( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 1 of 4
Surrogate Recovery Report
SDG Number: 6277
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010797
LCS for batch 26285
12010798
LCSD for batch 26285
12010796
MB for batch 26285
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
80.3
77.9
90.7
87.8
85.4
68.9
88.1
79.4
86.0
94.9
93.5
92.4
81.3
87.6
77.9
93.7
85.5
84.3
89.3
86.1
90.4
78.3
91.9
85.7
91.9
91.8
91.8
93.2
86.7
90.8
85.5
100
85.1
83.7
92.9
83.8
90.3
77.6
91.1
84.2
92.1
94.1
92.7
92.6
85.9
89.8
83.1
103
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6277001
SFRA-115
13C-2,3,7,8-TCDD
86.9
(25%-164%)
Page 19 of 32
-------
( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 2 of 4
Surrogate Recovery Report
SDG Number: 6277
Matrix Type: SOLID
Sample ID Client ID
6277001 SFRA-115
6277002 SFRA-116
6277003 SFRA-117
6277004 SFRA-118
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
Recovery Acceptance
QUAL (%) Limits
84.2 (25%-181%)
89.0 (32%-141%)
86.4 (28%-130%)
84.1 (23%-140%)
70.8 (17%-15 7%)
92.9 (24%-169%)
87.2 (24%-185%)
90.8 (21%-178%)
91.9 (26%-152%)
92.4 (26%-123%)
90.0 (28%-13 6%)
82.4 (29%-147%)
85.6 (28%-143%)
78.7 (26%-13 8%)
102 (35%-197%)
86.3 (25%-164%)
86.3 (25%-181%)
95.6 (32%-141%)
96.1 (28%-130%)
93.5 (23%-140%)
87.5 (17%-15 7%)
93.7 (24%-169%)
88.2 (24%-185%)
94.7 (21%-178%)
99.0 (26%-152%)
99.6 (26%-123%)
100 (28%-13 6%)
89.3 (29%-147%)
95.5 (28%-143%)
89.7 (26%-13 8%)
95.2 (35%-197%)
79.3 (25%-164%)
81.3 (25%-181%)
89.1 (32%-141%)
83.9 (28%-130%)
84.1 (23%-140%)
82.0 (17%-15 7%)
85.7 (24%-169%)
82.5 (24%-185%)
86.0 (21%-178%)
88.1 (26%-152%)
85.3 (26%-123%)
90.4 (28%-13 6%)
78.5 (29%-147%)
84.2 (28%-143%)
79.1 (26%-13 8%)
96.8 (35%-197%)
83.6 (25%-164%)
82.1 (25%-181%)
Page 20 of 32
-------
( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 3 of 4
Surrogate Recovery Report
SDG Number: 6277
Matrix Type: SOLID
Sample ID Client ID
6277004 SFRA-118
6277005 SFRA-119
6277006 SFRA-120
6277007 SFRA-121
Surrogate
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
Recovery Acceptance
QUAL (%) Limits
99.8 (32%-141%)
87.1 (28%-130%)
95.0 (23%-140%)
86.4 (17%-15 7%)
89.5 (24%-169%)
83.7 (24%-185%)
88.7 (21%-178%)
102 (26%-152%)
97.2 (26%-123%)
103 (28%-13 6%)
88.2 (29%-147%)
96.0 (28%-143%)
88.6 (26%-13 8%)
101 (35%-197%)
81.5 (25%-164%)
78.3 (25%-181%)
90.3 (32%-141%)
84.2 (28%-130%)
89.5 (23%-140%)
78.8 (17%-15 7%)
87.3 (24%-169%)
78.5 (24%-185%)
82.8 (21%-178%)
94.6 (26%-152%)
90.5 (26%-123%)
92.5 (28%-13 6%)
82.8 (29%-147%)
89.2 (28%-143%)
82.6 (26%-13 8%)
96.3 (35%-197%)
86.4 (25%-164%)
82.0 (25%-181%)
94.8 (32%-141%)
84.1 (28%-130%)
91.3 (23%-140%)
81.8 (17%-15 7%)
93.7 (24%-169%)
85.4 (24%-185%)
88.8 (21%-178%)
97.3 (26%-152%)
93.6 (26%-123%)
95.8 (28%-13 6%)
87.3 (29%-147%)
93.4 (28%-143%)
86.4 (26%-13 8%)
102 (35%-197%)
84.0 (25%-164%)
79.1 (25%-181%)
93.3 (32%-141%)
Page 21 of 32
-------
( (ipc Fear Analytical LLC Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 4 of 4
Surrogate Recovery Report
SDG Number: 6277
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6277007
SFRA-121
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
86.1
91.2
83.0
89.2
80.7
84.9
97.3
92.3
94.3
85.7
91.5
83.4
101
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010799
SFRA-115(6277001MS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
84.6
82.3
94.6
90.4
90.6
77.8
90.8
86.0
89.7
98.9
98.1
96.7
85.6
92.3
84.6
102
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010800
SFRA-115(6277001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
86.1
86.7
93.0
88.1
94.1
79.9
93.4
84.9
94.9
97.5
95.1
94.4
87.1
93.7
86.4
97.2
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 22 of 32
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/26/2014 16:18 Dilution: 1
Prep Batch ID:26285
Batch ID: 26287
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.2
106
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
104
104
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
108
108
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
105
105
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
106
106
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
102
102
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
215
107
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
20.8
104
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
104
104
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
102
102
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
106
106
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
106
106
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
108
108
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
114
114
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
104
104
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
108
108
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
208
104
63-170
SDG Number: 6277
Client ID: LCS for batch 26285
Lab Sample ID: 12010797
Instrument: HRP763
Analyst: JTF
Page 23 of 32
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/26/2014 17:05 Dilution: 1
Prep Batch ID:26285
Batch ID: 26287
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.8
109
67-158
2.64
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
104
104
70-142
0.756
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
109
109
70-164
1.37
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
109
109
76-134
4.58
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
112
112
64-162
5.60
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
103
103
70-140
1.43
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
211
105
78-144
2.03
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
21.0
105
75-158
0.815
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
107
107
80-134
2.09
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
106
106
68-160
3.94
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
109
109
72-134
2.45
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
110
110
84-130
4.17
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
109
109
70-156
1.15
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
116
116
78-130
1.13
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
106
106
82-122
2.59
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
109
109
78-138
1.70
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
212
106
63-170
2.00
0-20
SDG Number: 6277
Client ID: LCSD for batch 26285
Lab Sample ID: 12010798
Instrument: HRP763
Analyst: JTF
Page
24 of 32
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
223
349
-28.7 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1120
U
1170
105
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1120
U
1210
108
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1120
J
1220
109
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1120
J
1230
110
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1120
1200
99.6
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2230
2950
64 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
223
J
236
103
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1120
U
1180
106
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1120
u
1180
106
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1120
u
1250
112
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1120
J
1180
105
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1120
u
1210
108
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1120
u
1310
118
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1120
J
1200
105
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1120
u
1230
110
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2230
J
2370
104
70-130
SDG Number: 6277
Client ID: SFRA-115(6277001MS)
Lab Sample ID: 12010799
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 14.7
Analysis Date: 06/27/2014 05:16
Prep Batch ID:26285
Batch ID: 26287
Page 25 of 32
-------
Cape Fear Analytical LLC
Report Date: June 30, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 14.7
Analysis Date: 06/27/2014 06:04 Dilution: 1
Prep Batch ID:26285
Batch ID: 26287
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
202
288
-61.7 *
70-130
19.0
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1010
U
1060
104
70-130
10.5
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1010
U
1090
108
70-130
10.6
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1010
J
1020
101
70-130
18.1
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1010
J
1050
103
70-130
16.5
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1010
1010
91.4
70-130
17.1
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2020
2650
56.1 *
70-130
10.5
0-20
51207-31-9
MSD
2,3,7,8-TCDF
202
J
211
102
70-130
11.4
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1010
u
1090
108
70-130
7.94
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1010
u
1030
102
70-130
13.3
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1010
u
1060
104
70-130
17.3
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1010
J
1060
105
70-130
10.2
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1010
u
1060
105
70-130
12.5
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1010
u
1150
114
70-130
13.2
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1010
J
1040
101
70-130
14.2
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1010
u
1070
106
70-130
13.1
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2020
J
2120
102
70-130
11.2
0-20
SDG Number: 6277
Client ID: SFRA-115(6277001MSD)
Lab Sample ID: 12010800
Instrument: HRP763
Analyst: JTF
Page 26 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Method Blank Summary
Page 1 of 1
SDG Number: 6277
Client ID: MB for batch 26285
Lab Sample ID: 12010796
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: 25-JUN-14
Matrix: SOLID
Data File: b26junl4a-4
Analyzed: 06/26/1417:53
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26285
12010797
b26junl4a-2
06/26/14
1618
02
LCSD for batch 26285
12010798
b26junl4a-3
06/26/14
1705
03
SFRA-115
6277001
b26junl4a-7
06/26/14
2024
04
SFRA-116
6277002
b26junl4a-8
06/26/14
2111
05
SFRA-117
6277003
b26junl4a-9
06/26/14
2159
06
SFRA-118
6277004
b26junl4a-10
06/26/14
2247
07
SFRA-119
6277005
b26junl4a-ll
06/26/14
2334
08
SFRA-120
6277006
b26junl4a-12
06/27/14
0022
09
SFRA-121
6277007
b26junl4a-13
06/27/14
0110
10
SFRA-115(6277001MS)
12010799
b26junl4a 2-4
06/27/14
0516
11
SFRA-115(6277001MSD)
12010800
b26junl4a 2-5
06/27/14
0604
Page 27 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6277
12010796
QC for batch 26285
MB for batch 26285
26287
06/26/2014 17:53
b26junl4a-4
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
Prep Batch:
26285
Prep Method:
SW846 3540C
Prep Date:
25-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.196
Pg/g
0.196
1.00
40321-76-4
1,2,3,7,8-PeCDD
J
0.170
Pg/g
0.120
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.208
Pg/g
0.208
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.266
Pg/g
0.266
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.226
Pg/g
0.226
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
J
0.790
Pg/g
0.522
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
5.60
Pg/g
0.632
10.0
51207-31-9
2,3,7,8-TCDF
J
0.378
Pg/g
0.141
1.00
57117-41-6
1,2,3,7,8-PeCDF
J
0.186
Pg/g
0.0738
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.172
Pg/g
0.172
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
J
0.212
Pg/g
0.136
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
J
0.184
Pg/g
0.133
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
J
0.200
Pg/g
0.143
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.22
Pg/g
0.220
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.386
Pg/g
0.150
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.242
Pg/g
0.242
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.546
Pg/g
0.546
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
170
200
Pg/g
85.1
(25 %-164%)
13C-1,2,3,7,8-PeCDD
167
200
Pg/g
83.7
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
186
200
Pg/g
92.9
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
168
200
Pg/g
83.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
181
200
Pg/g
90.3
(23%-140%)
13C-OCDD
310
400
Pg/g
77.6
(17%-157%)
13C-2,3,7,8-TCDF
182
200
Pg/g
91.1
(24%-169%)
13C-1,2,3,7,8-PeCDF
168
200
Pg/g
84.2
(24%-185%)
13C-2,3,4,7,8-PeCDF
184
200
Pg/g
92.1
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
188
200
Pg/g
94.1
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
185
200
Pg/g
92.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
185
200
Pg/g
92.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
172
200
Pg/g
85.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
180
200
Pg/g
89.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
166
200
Pg/g
83.1
(26%-13 8%)
37Cl-2,3,7,8-TCDD
20.7
20.0
Pg/g
103
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 28 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6277
12010797
QC for batch 26285
LCS for batch 26285
26287
06/26/2014 16:18
b26junl4a-2
26285
25-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.2
Pg/g
0.238 1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.240 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
108
Pg/g
0.422 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
105
Pg/g
0.410 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
106
Pg/g
0.442 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
102
Pg/g
0.722 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
215
Pg/g
1.15 10.0
51207-31-9
2,3,7,8-TCDF
20.8
Pg/g
0.181 1.00
57117-41-6
1,2,3,7,8-PeCDF
104
Pg/g
0.232 5.00
57117-31-4
2,3,4,7,8-PeCDF
102
Pg/g
0.220 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
106
Pg/g
0.460 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
106
Pg/g
0.442 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
108
Pg/g
0.488 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
114
Pg/g
0.764 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
104
Pg/g
0.358 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
108
Pg/g
0.682 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
208
Pg/g
1.18 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
161
200
Pg/g
80.3
(20%-175%)
13C-1,2,3,7,8-
PeCDD
156
200
Pg/g
77.9
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
181
200
Pg/g
90.7
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
176
200
Pg/g
87.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
171
200
Pg/g
85.4
(22%-166%)
13C-OCDD
276
400
Pg/g
68.9
(13%-199%)
13C-2,3,7,8-TCDF
176
200
Pg/g
88.1
(22%-152%)
13C-1,2,3,7,8-
PeCDF
159
200
Pg/g
79.4
(21%-192%)
130-2,3,4,7,8-
PeCDF
172
200
Pg/g
86.0
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
190
200
Pg/g
94.9
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
187
200
Pg/g
93.5
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
185
200
Pg/g
92.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
163
200
Pg/g
81.3
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
175
200
Pg/g
87.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
156
200
Pg/g
77.9
(20%-186%)
3701-2,3,7,8-TCDD
18.7
20.0
Pg/g
93.7
(31 %-191%)
Comments:
Page 29 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6277
12010798
QC for batch 26285
LCSD for batch 26285
26287
06/26/2014 17:05
b26junl4a-3
26285
25-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.8
Pg/g
0.190 1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.198 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
109
Pg/g
0.304 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
109
Pg/g
0.302 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
112
Pg/g
0.322 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
103
Pg/g
0.404 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
211
Pg/g
0.810 10.0
51207-31-9
2,3,7,8-TCDF
21.0
Pg/g
0.137 1.00
57117-41-6
1,2,3,7,8-PeCDF
107
Pg/g
0.143 5.00
57117-31-4
2,3,4,7,8-PeCDF
106
Pg/g
0.132 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
109
Pg/g
0.382 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
110
Pg/g
0.376 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
109
Pg/g
0.392 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
116
Pg/g
0.600 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
106
Pg/g
0.394 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
109
Pg/g
0.702 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
212
Pg/g
0.790 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
171
200
Pg/g
85.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
169
200
Pg/g
84.3
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
179
200
Pg/g
89.3
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
172
200
Pg/g
86.1
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
181
200
Pg/g
90.4
(22%-166%)
13C-OCDD
313
400
Pg/g
78.3
(13%-199%)
13C-2,3,7,8-TCDF
184
200
Pg/g
91.9
(22%-152%)
13C-1,2,3,7,8-
PeCDF
171
200
Pg/g
85.7
(21%-192%)
130-2,3,4,7,8-
PeCDF
184
200
Pg/g
91.9
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
184
200
Pg/g
91.8
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
184
200
Pg/g
91.8
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
186
200
Pg/g
93.2
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
173
200
Pg/g
86.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
182
200
Pg/g
90.8
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
171
200
Pg/g
85.5
(20%-186%)
3701-2,3,7,8-TCDD
20.0
20.0
Pg/g
100
(31 %-191%)
Comments:
Page 30 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6277
12010799
QC for batch 26285
SFRA-115(6277001MS)
26287
06/27/2014 05:16
b26junl4a_2-4
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
TETR001
Date Collected: 06/24/2014 12:00
Date Received: 06/25/2014 10:00
Method:
Analyst:
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
14.7
Dry Weight
HRP763
1
Prep Batch:
26285
Prep Method:
SW846 3540C
Prep Date:
25-JUN-14
Prep Aliquot:
1.05 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
349
Pg/g
2.30
11.2
40321-76-4
1,2,3,7,8-PeCDD
1170
Pg/g
2.06
55.8
39227-28-6
1,2,3,4,7,8-HxCDD
1210
Pg/g
5.56
55.8
57653-85-7
1,2,3,6,7,8-HxCDD
1220
Pg/g
5.38
55.8
19408-74-3
1,2,3,7,8,9-HxCDD
1230
Pg/g
5.78
55.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
1200
Pg/g
5.38
55.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
2950
Pg/g
9.49
112
51207-31-9
2,3,7,8-TCDF
236
Pg/g
1.75
11.2
57117-41-6
1,2,3,7,8-PeCDF
1180
Pg/g
2.12
55.8
57117-31-4
2,3,4,7,8-PeCDF
1180
Pg/g
2.00
55.8
70648-26-9
1,2,3,4,7,8-HxCDF
1250
Pg/g
5.16
55.8
57II7.44.9
1,2,3,6,7,8-HxCDF
1180
Pg/g
4.98
55.8
60851-34-5
2,3,4,6,7,8-HxCDF
1210
Pg/g
5.58
55.8
72918-21-9
1,2,3,7,8,9-HxCDF
1310
Pg/g
8.62
55.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
1200
Pg/g
4.44
55.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
1230
Pg/g
8.28
55.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2370
Pg/g
10.4
112
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1890
2230
Pg/g
84.6
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1840
2230
Pg/g
82.3
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
2110
2230
Pg/g
94.6
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
2020
2230
Pg/g
90.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2020
2230
Pg/g
90.6
(23%-140%)
13C-OCDD
3470
4460
Pg/g
77.8
(17%-157%)
13C-2,3,7,8-TCDF
2030
2230
Pg/g
90.8
(24%-169%)
13C-1,2,3,7,8-PeCDF
1920
2230
Pg/g
86.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
2000
2230
Pg/g
89.7
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
2210
2230
Pg/g
98.9
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2190
2230
Pg/g
98.1
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2160
2230
Pg/g
96.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1910
2230
Pg/g
85.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2060
2230
Pg/g
92.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1890
2230
Pg/g
84.6
(26%-13 8%)
37Cl-2,3,7,8-TCDD
228
223
Pg/g
102
(35%-197%)
Comments:
Page 31 of 32
-------
Cape Fear Analytical LLC
Report Date:
June 30,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6277
Lab Sample ID: 12010800
Client Sample: ^or batch 26285
Chent:
Date Collected:
Date Received:
TETR001
06/24/2014 12:00
06/25/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 14.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-115(6277001MSD)
26287
06/27/2014 06:04
b26junl4a_2-5
26285
25-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.16 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
288
Pg/g
1.76 10.1
40321-76-4
1,2,3,7,8-PeCDD
1060
Pg/g
1.65 50.5
39227-28-6
1,2,3,4,7,8-HxCDD
1090
Pg/g
4.00 50.5
57653-85-7
1,2,3,6,7,8-HxCDD
1020
Pg/g
3.76 50.5
19408-74-3
1,2,3,7,8,9-HxCDD
1050
Pg/g
4.10 50.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
1010
Pg/g
4.10 50.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
2650
Pg/g
8.51 101
51207-31-9
2,3,7,8-TCDF
211
Pg/g
1.48 10.1
57117-41-6
1,2,3,7,8-PeCDF
1090
Pg/g
1.41 50.5
57117-31-4
2,3,4,7,8-PeCDF
1030
Pg/g
1.33 50.5
70648-26-9
1,2,3,4,7,8-HxCDF
1060
Pg/g
3.52 50.5
57II7.44.9
1,2,3,6,7,8-HxCDF
1060
Pg/g
3.29 50.5
60851-34-5
2,3,4,6,7,8-HxCDF
1060
Pg/g
3.58 50.5
72918-21-9
1,2,3,7,8,9-HxCDF
1150
Pg/g
5.47 50.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
1040
Pg/g
3.29 50.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
1070
Pg/g
5.84 50.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2120
Pg/g
8.61 101
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1740
2020
Pg/g
86.1
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1750
2020
Pg/g
86.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1880
2020
Pg/g
93.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1780
2020
Pg/g
88.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1900
2020
Pg/g
94.1
(23%-140%)
13C-OCDD
3230
4040
Pg/g
79.9
(17%-157%)
13C-2,3,7,8-TCDF
1890
2020
Pg/g
93.4
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1720
2020
Pg/g
84.9
(24%-185%)
130-2,3,4,7,8-
PeCDF
1920
2020
Pg/g
94.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1970
2020
Pg/g
97.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1920
2020
Pg/g
95.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2020
Pg/g
94.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1760
2020
Pg/g
87.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1890
2020
Pg/g
93.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1740
2020
Pg/g
86.4
(26%-13 8%)
3701-2,3,7,8-TCDD
196
202
Pg/g
97.2
(35%-197%)
Comments:
Page 32 of 32
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
July 02. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Development 1613B
Work Order: 6287
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on June 27, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Valerie Davis
Project Manager
Enclosures
Page 1 of 26
problem solved
-------
Page: /
Project#:
CFA Quote #:
COC Number(l):.
PO Number.
.of /
Cape Fear Analytical, LLC OOcrft k &Y3-
Chain of Custody and Analytical Request
CFA Work Order Number:
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Namer
Phone #:
Sample Analysis Requested(5) (Fill in the number of containers for each test)
Project/Site Name^^^
Address. t) ftjAw 73 ^ ^3^^
Collected by: £
Send Results To: * U^.n4
Sample ID
* For composites - indicate start and stop date/time
*Date Collected
(mro-dd-yy)
•Time
Collected
(Military)
(hhmm)
QC Code
O)
Field
Filtered w
2*1
Sample
Matrix(4}
f
- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
5'/=&?- /XL A
Msh
.5
K
JTFstJ- £23
/J?S-
<5
L
A.
3"
T
TAT Requested: Normal:
Rush: Specify.'^? ^tta
Method of Shipment:
Date Shipped:
Airbill #
Airbill M:
1.) Chain of Custody Number - Client Determined
2.) QC Codes: N = Normal Sample, TB = Trip Blank, FD = Field Duplicate, EB = Equipment Blank, MS = Matrix Spike Sample, MSD = Matrix Spike Duplicate Sample. G *¦ Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: DW=Drinking Water, GW=Gxvnndwatcr, SW-Surface Water. WW=Waste Water, W=Water, ML=Misc Liquid,SO=Soil, SD= Sediment, SL=Sludge, SS=Solid Waste, 0=0il, F-Filter, P=Wipe, U=Urine, F^Fecal, N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.cJ5290B, 166SB) and number of containers provided for each (L C.8290B - 3,1668B - 1).
6.) Preservative Type: HA = Hydrochloric Acid, NJ » Nitric Acid, SH = Sodium Hydroxide, SA * Sulfuric Acid, AA - Ascorbic Acid, HX = Hexane, ST = Sodium Thiosulfate, If no preservative is added = leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Rec?Mng Use Only
Custody Seal Intact?
YES NO
Cooler Temp:
*)C c
-------
SAMPLE RECEIPT CHECKLIST
cliM: TtW,,T..k
Work Order:
Shipping Company:
Date/Time Received:
TA
M
Suspected Hazard Information
Shipped as-DQ-T Hazardous?
Samples identified as Foreign-Soil?-
Yes NA No
!3i
DOE Site Sample Packages
Screened <0.S mR/hr?
Samples < 2x background?
Yes NA No*
jg.
Air Sample Receipt Specifics
Yes
NA
No
Air sample in shipment?
Air Witness:
* Notify RSO of any responses in this column immediately.
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
s
Circle Applic«bif:
VPJll broken damigfd container Ifcjking container other|d1 preservative added. lot#:
7
Samples received within holding time?
Sample IDs, teits affected:
8
Sample IDs on COC match IDs on
containers?
Sample IDs, containers affected.
9
Date & time of COC match date & time
on containers?
Sample IDs, container; affected;
30
Number of containers received match
number indicated on COC?
X
Sample IDs, containeis effected;
11
COC form is properly'signed in
relinquished/received sections?
r
Comments:
Checklist perfoi med by: initials:
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 26
-------
Case Narrative
Page 5 of 26
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6287
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26313
Clean Up Batch Number: 26312
Extraction Batch Number: 26311
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6287001
SFRA-122
6287002
SFRA-123
12010825
Method Blank (MB)
12010826
Laboratory Control Sample (LCS)
12010827
Laboratory Control Sample Duplicate (LCSD)
12010828
6287001 (SFRA-122) Matrix Spike (MS)
12010829
6287001 (SFRA-122) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Page 6 of 26
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6287001 (SFRA-122) - Batch 26313 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
Two MS recoveries for this SDG were not within the acceptance limits and can be attributed to
matrix interference. 12010828 (SFRA-122) - Batch 26313.
Matrix Spike Duplicate (MSD) Recovery Statement
One MSD recovery for this SDG was not within the acceptance limits. The failure confirms in
the MS and can be attributed to matrix interference. 12010829 (SFRA-122) - Batch 26313.
MS/MSD Relative Percent Difference (RPD) Statement
Two relative percent differences (RPDs) between the MS and MSD were not within the required
acceptance limits. Sample data is validated based on acceptable LCS/LCSD results. 12010828
(SFRA-122) and 12010829 (SFRA-122) - Batch 26313.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
Page 7 of 26
-------
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26313.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
The following NCR was generated for this SDG: 644621 12010828 (SFRA-122) and 12010829
(SFRA-122)-Batch 26313.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 26
-------
Sample Data Summary
Page 9 of 26
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6287 CFA Work Order: 6287
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 02 JUL 2014 Title: Data Validator
Page 10 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6287
6287001
1613B Soil
SFRA-122
26313
06/30/2014 18:49
b30junl4b-5
26311
27-JUN-14
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
06/25/2014 14:50
06/27/2014 10:10
EPA Method 1613B
JTF
SW846 3540C
1 g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00111
SOLID
23.1
Dry Weight
HRP763
1
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
248
Pg/g
3.46
13.0
40321-76-4
1,2,3,7,8-PeCDD
u
2.53
Pg/g
2.53
65.1
39227-28-6
1,2,3,4,7,8-HxCDD
u
3.98
Pg/g
3.98
65.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
10.8
Pg/g
4.03
65.1
19408-74-3
1,2,3,7,8,9-HxCDD
u
4.4
Pg/g
4.40
65.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
290
Pg/g
10.9
65.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
16400
Pg/g
27.8
130
51207-31-9
2,3,7,8-TCDF
u
3.3
Pg/g
3.30
13.0
57117-41-6
1,2,3,7,8-PeCDF
u
1.9
Pg/g
1.90
65.1
57117-31-4
2,3,4,7,8-PeCDF
u
1.64
Pg/g
1.64
65.1
70648-26-9
1,2,3,4,7,8-HxCDF
u
3.77
Pg/g
3.77
65.1
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.06
Pg/g
2.06
65.1
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.24
Pg/g
2.24
65.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.2
Pg/g
3.20
65.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
42.1
Pg/g
4.22
65.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
6.69
Pg/g
6.69
65.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
111
Pg/g
11.2
130
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2190
2600
Pg/g
84.1
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2230
2600
Pg/g
85.8
(25%-181
/o)
130-1,2,3,4,7,
8-HxCDD
2080
2600
Pg/g
79.8
(32%-141
/o)
130-1,2,3,6,7,
8-HxCDD
2230
2600
Pg/g
85.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2370
2600
Pg/g
90.9
(23%-140%)
13C-OCDD
4870
5200
Pg/g
93.5
(17%-157%)
13C-2,3,7,8-TCDF
2400
2600
Pg/g
92.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2180
2600
Pg/g
83.8
(24%-185
/o)
130-2,3,4,7,8-
PeCDF
2260
2600
Pg/g
86.8
(21%-178
/o)
130-1,2,3,4,7,
8-HxCDF
2040
2600
Pg/g
78.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2140
2600
Pg/g
82.2
(26%-123
/o)
130-2,3,4,6,7,
8-HxCDF
2150
2600
Pg/g
82.5
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2190
2600
Pg/g
84.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2140
2600
Pg/g
82.2
(28%-143
/o)
13C-1,2,3,4,7,8,9-HpCDF
2310
2600
Pg/g
88.9
(26%-138
/o)
3701-2,3,7,8-TCDD
236
260
Pg/g
90.6
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6287
Lab Sample ID: 6287002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
06/25/2014 13:45
06/27/2014 10:10
Project: TETR00111
Matrix: SOLID
%Moisture: 14.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-123
26313
06/30/2014 21:12
b30junl4b-8
26311
27-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.05 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
411
Pg/g
3.44 11.1
40321-76-4
1,2,3,7,8-PeCDD
U
2.35
Pg/g
2.35 55.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
5.13
Pg/g
5.13 55.5
57653-85-7
1,2,3,6,7,8-HxCDD
J
6.42
Pg/g
4.93 55.5
19408-74-3
1,2,3,7,8,9-HxCDD
u
5.33
Pg/g
5.33 55.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
155
Pg/g
9.06 55.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11000
Pg/g
27.1 111
51207-31-9
2,3,7,8-TCDF
u
3.44
Pg/g
3.44 11.1
57117-41-6
1,2,3,7,8-PeCDF
u
1.61
Pg/g
1.61 55.5
57117-31-4
2,3,4,7,8-PeCDF
u
1.43
Pg/g
1.43 55.5
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.35
Pg/g
2.35 55.5
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.42
Pg/g
2.42 55.5
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.51
Pg/g
2.51 55.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.58
Pg/g
3.58 55.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
22.3
Pg/g
2.55 55.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
3.93
Pg/g
3.93 55.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
66.7
Pg/g
8.86 111
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1440
2220
Pg/g
65.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1520
2220
Pg/g
68.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1490
2220
Pg/g
67.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1600
2220
Pg/g
72.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1700
2220
Pg/g
76.4
(23%-140%)
13C-OCDD
3240
4440
Pg/g
72.9
(17%-157%)
13C-2,3,7,8-TCDF
1540
2220
Pg/g
69.4
(24%-169%)
130-1,2,3,7,8-
PeCDF
1440
2220
Pg/g
65.0
(24%-185%)
130-2,3,4,7,8-
PeCDF
1550
2220
Pg/g
69.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1490
2220
Pg/g
66.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1440
2220
Pg/g
64.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1530
2220
Pg/g
69.1
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1490
2220
Pg/g
66.9
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1480
2220
Pg/g
66.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1630
2220
Pg/g
73.4
(26%-13 8%)
3701-2,3,7,8-TCDD
166
222
Pg/g
74.9
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 26
-------
Quality Control
Summary
Page 13 of 26
-------
Cape Fear Analytical LLC Report Date: July 1,2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6287
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010826
LCS for batch 26311
12010827
LCSD for batch 26311
12010825
MB for batch 26311
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
78.4
78.8
78.6
78.4
85.3
78.4
85.9
74.6
81.3
78.9
79.9
81.2
80.6
77.4
81.5
90.9
79.8
77.3
83.4
80.2
87.0
80.1
91.3
78.9
82.5
78.1
80.6
83.4
81.0
79.5
82.2
93.8
76.7
71.6
84.0
80.6
85.4
74.8
88.3
71.6
75.2
83.2
85.5
85.4
80.3
81.6
78.5
90.0
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6287001
SFRA-122
13C-2,3,7,8-TCDD
84.1
(25%-164%)
Page 14 of 26
-------
Cape Fear Analytical LLC Report Date: July 1,2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6287
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6287001
SFRA-122
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
85.8
79.8
85.6
90.9
93.5
92.2
83.8
86.8
78.5
82.2
82.5
84.0
82.2
88.9
90.6
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010828
SFRA-122(628700 IMS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
83.5
88.5
75.7
78.3
90.1
92.1
89.5
84.8
87.6
73.2
76.1
80.7
80.8
76.9
84.4
104
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010829
SFRA-122(6287001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
82.2
87.1
82.7
87.1
91.9
93.1
85.9
83.7
90.5
82.8
81.2
84.3
81.9
79.9
86.8
96.1
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6287002
SFRA-123
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
65.0
68.5
(25%-
(25%-
64%)
81%)
Page 15 of 26
-------
Cape Fear Analytical LLC Report Date: July 1,2014
Hi-Res Dioxins/Furans Page 3 of 3
Surrogate Recovery Report
SDG Number: 6287
Matrix Type: SOLID
Sample ID Client ID
6287002 SFRA-123
Surrogate
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
(%)
Limits
67.0
(32%-
¦141%)
72.2
(28%-
¦130%)
76.4
(23%-
¦140%)
72.9
(17%-
¦157%)
69.4
(24%-
¦169%)
65.0
(24%-
¦185%)
69.7
(21%-
¦178%)
66.9
(26%-
¦152%)
64.8
(26%-
¦123%)
69.1
(28%-
¦136%)
66.9
(29%-
¦147%)
66.6
(28%-
¦143%)
73.4
(26%-
¦138%)
74.9
(35%-
¦197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 16 of 26
-------
Cape Fear Analytical LLC
Report Date: July 1, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 06/30/2014 16:26 Dilution: 1
Prep Batch ID:26311
Batch ID: 26313
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.3
101
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
98.8
98.8
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
103
103
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
98.2
98.2
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
110
110
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
100
100
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
194
97.2
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.4
97
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
97.2
97.2
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
93.4
93.4
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
104
104
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
105
105
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
104
104
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
110
110
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
102
102
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
106
106
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
209
104
63-170
SDG Number: 6287
Client ID: LCS for batch 26311
Lab Sample ID: 12010826
Instrument: HRP763
Analyst: JTF
Page
17 of 26
-------
Cape Fear Analytical LLC
Report Date: July 1, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 06/30/2014 17:14 Dilution: 1
Prep Batch ID:26311
Batch ID: 26313
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.3
101
67-158
0.0592
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
101
101
70-142
2.69
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
97.7
97.7
70-164
5.35
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
98.8
98.8
76-134
0.593
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
109
109
64-162
0.930
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
96.3
96.3
70-140
4.13
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
189
94.6
78-144
2.69
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.6
98
75-158
1.01
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
95.7
95.7
80-134
1.58
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
94.2
94.2
68-160
0.863
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
104
104
72-134
0.835
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
106
106
84-130
0.915
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
104
104
70-156
0.351
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
111
111
78-130
0.342
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
98.9
98.9
82-122
3.36
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
105
105
78-138
0.789
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
212
106
63-170
1.64
0-20
SDG Number: 6287
Client ID: LCSD for batch 26311
Lab Sample ID: 12010827
Instrument: HRP763
Analyst: JTF
Page
18 of 26
-------
Cape Fear Analytical LLC
Report Date: July 1, 2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
248
1030
316 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1240
U
1180
95.4
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1240
U
1220
98.4
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1240
J
1240
98.9
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1240
U
1320
107
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1240
1520
99.6
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2480
14900
-56.8 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
248
u
246
99.4
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1240
u
1210
97.8
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1240
u
1170
94.2
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1240
u
1340
108
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1240
u
1230
99.4
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1240
u
1230
99.6
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1240
u
1340
108
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1240
J
1330
104
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1240
u
1290
104
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2480
J
2740
106
70-130
SDG Number: 6287
Client ID: SFRA-122(6287001MS)
Lab Sample ID: 12010828
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 23.1
Analysis Date: 06/30/2014 19:37
Prep Batch ID:26311
Batch ID: 26313
Page 19 of 26
-------
Cape Fear Analytical LLC
Report Date: July 1, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 23.1
Analysis Date: 06/30/2014 20:25 Dilution: 1
Prep Batch ID:26311
Batch ID: 26313
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
237
500
107
70-130
69.4 *
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1180
U
1140
96.7
70-130
3.38
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1180
U
1120
94.7
70-130
8.52
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1180
J
1150
96.3
70-130
7.24
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1180
U
1090
92.5
70-130
19.0
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1180
1490
101
70-130
2.37
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2370
30500
600 *
70-130
68.6 *
0-20
51207-31-9
MSD
2,3,7,8-TCDF
237
u
232
97.9
70-130
6.17
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1180
u
1110
94.2
70-130
8.40
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1180
u
1080
91.2
70-130
7.94
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1180
u
1220
103
70-130
9.28
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1180
u
1200
102
70-130
2.44
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1180
u
1210
102
70-130
1.84
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1180
u
1250
105
70-130
7.36
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1180
J
1230
100
70-130
8.17
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1180
u
1180
99.8
70-130
8.62
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2370
J
2540
103
70-130
7.64
0-20
SDG Number: 6287
Client ID: SFRA-122(6287001MSD)
Lab Sample ID: 12010829
Instrument: HRP763
Analyst: JTF
Page
20 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6287
Client ID: MB for batch 26311
Lab Sample ID: 12010825
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: 27-JUN-14
Matrix: SOLID
Data File: b30junl4b-4
Analyzed: 06/30/1418:01
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26311
12010826
b30junl4b-2
06/30/14
1626
02
LCSD for batch 26311
12010827
b30junl4b-3
06/30/14
1714
03
SFRA-122
6287001
b30junl4b-5
06/30/14
1849
04
SFRA-122(628700 IMS)
12010828
b30junl4b-6
06/30/14
1937
05
SFRA-122(6287001MSD)
12010829
b30junl4b-7
06/30/14
2025
06
SFRA-123
6287002
b30junl4b-8
06/30/14
2112
Page 21 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6287
Client:
TETR001
Project: TETR00111
Lab Sample ID: 12010825
Matrix: SOLID
Client Sample: *or batch 26311
Client ID:
MB for batch 26311
Prep Basis: As Received
Batch ID:
26313
Method:
EPA Method 1613B
Run Date:
06/30/2014 18:01
Analyst:
JTF
Instrument: HRP763
Data File:
b30junl4b-4
Dilution: 1
Prep Batch:
26311
Prep Method:
SW846 3540C
Prep Date:
27-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.234
Pg/g
0.234 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.157
Pg/g
0.157 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.22
Pg/g
0.220 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.204
Pg/g
0.204 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.224
Pg/g
0.224 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.294
Pg/g
0.294 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.654
Pg/g
0.654 10.0
51207-31-9
2,3,7,8-TCDF
u
.151
Pg/g
0.151 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.14
Pg/g
0.140 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.133
Pg/g
0.133 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.146
Pg/g
0.146 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.139
Pg/g
0.139 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.145
Pg/g
0.145 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.228
Pg/g
0.228 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.232
Pg/g
0.232 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.398
Pg/g
0.398 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.722
Pg/g
0.722 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
153
200
Pg/g
76.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
143
200
Pg/g
71.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
168
200
Pg/g
84.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
161
200
Pg/g
80.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
171
200
Pg/g
85.4
(23%-140%)
13C-OCDD
299
400
Pg/g
74.8
(17%-157%)
13C-2,3,7,8-TCDF
177
200
Pg/g
88.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
143
200
Pg/g
71.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
150
200
Pg/g
75.2
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
166
200
Pg/g
83.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
171
200
Pg/g
85.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
171
200
Pg/g
85.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.3
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
163
200
Pg/g
81.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
157
200
Pg/g
78.5
(26%-13 8%)
3701-2,3,7,8-TCDD
18.0
20.0
Pg/g
90.0
(35%-197%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 22 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6287
Lab Sample ID: 12010826
Client Sample: *or batch 26311
Client ID: LCS for batch 26311
Batch ID: 26313
Run Date: 06/30/2014 16:26
Data File: b30junl4b-2
Prep Batch: 26311
Prep Date: 27-JUN-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00111
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.3
Pg/g
0.274 1.00
40321-76-4
1,2,3,7,8-PeCDD
98.8
Pg/g
0.350 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
103
Pg/g
0.826 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.2
Pg/g
0.734 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
110
Pg/g
0.822 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
100
Pg/g
0.812 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
194
Pg/g
1.36 10.0
51207-31-9
2,3,7,8-TCDF
19.4
Pg/g
0.238 1.00
57117-41-6
1,2,3,7,8-PeCDF
97.2
Pg/g
0.420 5.00
57117-31-4
2,3,4,7,8-PeCDF
93.4
Pg/g
0.390 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
104
Pg/g
0.678 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
105
Pg/g
0.650 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
104
Pg/g
0.670 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
110
Pg/g
1.02 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
102
Pg/g
0.728 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
106
Pg/g
1.11 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
209
Pg/g
1.18 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
157
200
Pg/g
78.4
(20%-175%)
130-1,2,3,7,8-
PeCDD
158
200
Pg/g
78.8
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
157
200
Pg/g
78.6
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
157
200
Pg/g
78.4
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
171
200
Pg/g
85.3
(22%-166%)
13C-OCDD
314
400
Pg/g
78.4
(13%-199%)
13C-2,3,7,8-TCDF
172
200
Pg/g
85.9
(22%-152%)
130-1,2,3,7,8-
PeCDF
149
200
Pg/g
74.6
(21%-192%)
130-2,3,4,7,8-
PeCDF
163
200
Pg/g
81.3
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
158
200
Pg/g
78.9
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
160
200
Pg/g
79.9
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
162
200
Pg/g
81.2
(22%-176%)
130-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.6
(17%-205%)
130-1,2,3,4,6,7,8-HpCDF
155
200
Pg/g
77.4
(21%-15 8%)
130-1,2,3,4,7,8,9-HpCDF
163
200
Pg/g
81.5
(20%-186%)
3701-2,3,7,8-TCDD
18.2
20.0
Pg/g
90.9
(31 %-191%)
Comments:
K Estimated Maximum Possible Concentration
Page 23 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6287
12010827
QC for batch 26311
LCSD for batch 26311
26313
06/30/2014 17:14
b30junl4b-3
26311
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00111
SOLID
As Received
HRP763
1
Prep Method: SW846 3540C
Prep Date:
27-JUN-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.3
Pg/g
0.254 1.00
40321-76-4
1,2,3,7,8-PeCDD
101
Pg/g
0.334 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
97.7
Pg/g
0.640 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
98.8
Pg/g
0.656 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
109
Pg/g
0.688 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
96.3
Pg/g
0.960 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
189
Pg/g
1.15 10.0
51207-31-9
2,3,7,8-TCDF
19.6
Pg/g
0.216 1.00
57117-41-6
1,2,3,7,8-PeCDF
95.7
Pg/g
0.306 5.00
57117-31-4
2,3,4,7,8-PeCDF
94.2
Pg/g
0.290 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
104
Pg/g
0.758 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
106
Pg/g
0.724 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
104
Pg/g
0.734 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
111
Pg/g
1.10 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
98.9
Pg/g
0.590 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
105
Pg/g
0.932 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
212
Pg/g
1.48 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
160
200
Pg/g
79.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
155
200
Pg/g
77.3
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
167
200
Pg/g
83.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
160
200
Pg/g
80.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
174
200
Pg/g
87.0
(22%-166%)
13C-OCDD
320
400
Pg/g
80.1
(13%-199%)
13C-2,3,7,8-TCDF
183
200
Pg/g
91.3
(22%-152%)
13C-1,2,3,7,8-
PeCDF
158
200
Pg/g
78.9
(21%-192%)
130-2,3,4,7,8-
PeCDF
165
200
Pg/g
82.5
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
156
200
Pg/g
78.1
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
161
200
Pg/g
80.6
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
167
200
Pg/g
83.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
162
200
Pg/g
81.0
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
159
200
Pg/g
79.5
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
164
200
Pg/g
82.2
(20%-186%)
3701-2,3,7,8-TCDD
18.8
20.0
Pg/g
93.8
(31 %-191%)
Comments:
K Estimated Maximum Possible Concentration
Page 24 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1,2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6287
Lab Sample ID: 12010828
Client Sample: *or batch 26311
Client:
Date Collected:
Date Received:
TETR001
06/25/2014 14:50
06/27/2014 10:10
Project: TETR00111
Matrix: SOLID
%Moisture: 23.1
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-122(6287001MS)
26313
06/30/2014 19:37
b30junl4b-6
26311
27-JUN-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.05 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1030
Pg/g
3.72 12.4
40321-76-4
1,2,3,7,8-PeCDD
1180
Pg/g
4.36 62.0
39227-28-6
1,2,3,4,7,8-HxCDD
1220
Pg/g
7.46 62.0
57653-85-7
1,2,3,6,7,8-HxCDD
1240
Pg/g
7.16 62.0
19408-74-3
1,2,3,7,8,9-HxCDD
1320
Pg/g
7.73 62.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
1520
Pg/g
11.7 62.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14900
Pg/g
23.4 124
51207-31-9
2,3,7,8-TCDF
246
Pg/g
3.82 12.4
57117-41-6
1,2,3,7,8-PeCDF
1210
Pg/g
4.71 62.0
57117-31-4
2,3,4,7,8-PeCDF
1170
Pg/g
4.44 62.0
70648-26-9
1,2,3,4,7,8-HxCDF
1340
Pg/g
7.56 62.0
57II7.44.9
1,2,3,6,7,8-HxCDF
1230
Pg/g
6.72 62.0
60851-34-5
2,3,4,6,7,8-HxCDF
1230
Pg/g
7.44 62.0
72918-21-9
1,2,3,7,8,9-HxCDF
1340
Pg/g
9.99 62.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
1330
Pg/g
6.59 62.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
1290
Pg/g
10.2 62.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2740
Pg/g
11.7 124
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
2070
2480
Pg/g
83.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2190
2480
Pg/g
88.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1880
2480
Pg/g
75.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1940
2480
Pg/g
78.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2230
2480
Pg/g
90.1
(23%-140%)
13C-OCDD
4570
4960
Pg/g
92.1
(17%-157%)
13C-2,3,7,8-TCDF
2220
2480
Pg/g
89.5
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2100
2480
Pg/g
84.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
2170
2480
Pg/g
87.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1810
2480
Pg/g
73.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1890
2480
Pg/g
76.1
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2000
2480
Pg/g
80.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2000
2480
Pg/g
80.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1900
2480
Pg/g
76.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2090
2480
Pg/g
84.4
(26%-13 8%)
3701-2,3,7,8-TCDD
257
248
Pg/g
104
(35%-197%)
Comments:
K Estimated Maximum Possible Concentration
Page 25 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 1,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6287
12010829
QC for batch 26311
SFRA-122(6287001MSD)
26313
06/30/2014 20:25
b30junl4b-7
26311
27-JUN-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
TETR001
Date Collected: 06/25/2014 14:50
Date Received: 06/27/2014 10:10
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
EPA Method 1613B
JTF
SW846 3540C
11 g
Result
500
1140
1120
1150
1090
1490
30500
232
1110
1080
1220
1200
1210
1250
1230
1180
2540
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
3.76
4.59
5.77
5.58
6.01
12.7
38.1
4.83
5.32
4.61
8.37
8.49
9.18
13.2
8.26
12.3
14.3
TETR00111
SOLID
23.1
Dry Weight
HRP763
1
PQL
11.8
59.1
59.1
59.1
59.1
59.1
118
11.8
59.1
59.1
59.1
59.1
59.1
59.1
59.1
59.1
118
Surrogate/Tracer recovery
Qual
Result
Nominal Units Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1940
2370
Pg/g
82.2
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2060
2370
Pg/g
87.1
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1960
2370
Pg/g
82.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
2060
2370
Pg/g
87.1
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2170
2370
Pg/g
91.9
(23%-140%)
13C-OCDD
4410
4730
Pg/g
93.1
(17%-157%)
13C-2,3,7,8-TCDF
2030
2370
Pg/g
85.9
(24%-169%)
13C-1,2,3,7,8-PeCDF
1980
2370
Pg/g
83.7
(24%-185%)
13C-2,3,4,7,8-PeCDF
2140
2370
Pg/g
90.5
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1960
2370
Pg/g
82.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1920
2370
Pg/g
81.2
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1990
2370
Pg/g
84.3
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1940
2370
Pg/g
81.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1890
2370
Pg/g
79.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2050
2370
Pg/g
86.8
(26%-13 8%)
37Cl-2,3,7,8-TCDD
227
237
Pg/g
96.1
(35%-197%)
Comments:
K Estimated Maximum Possible Concentration
Page 26 of 26
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
July 07. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Development 1613B
Work Order: 6293
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 01, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Valerie Davis
Project Manager
Enclosures
Page 1 of 29
problem solved
-------
Paee: / of /
Project #:
CFA Quote #:
COC Number0':
PO Number:
Cape Fear Analytical, LLC u_>cr& G273
Chain of Custody and Analytical Request
CFA Work Order Number:
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone:(910)795-0421
Client /( Ph°ne#:
Sample Analysis Requested(5) (Fill in the number of containers for each test)
Project/Site Name^^ ^
Total number of containers
Y°
<-- Preservative Type (6)
Address. -£¦ —
*5
Comments
Note: extra sample is
required for sample
specific QC
Collected by: Send RcSulK T°
cl
rfi c/Wfc'c.A
Sample ID
* For composites - indicate start and stop date/time
~Date Collected
(mm-dd-yy)
•at.
Collected
(Military)
(hhmra)
QC Code
Field
Filtered w
Sample
Matrix w
/2*f
c-xrf
/Jz£
5
(
S
I
*
- r^c
--To-/1/
ffso
S
(
f
—
5
c
TAT Requested: Normal: Rush: Specify: cS Surcharge) Fax Results: Yes / No
Circle Deliverable: C of A / QC Summary / Level 1
/ Level 2(^7^Leveip* / Level 4
Eastern Pacific
Central Other _
"Mountain'
Chain of Custody Signatures
Sample Shipping and Delivery Details
Date
Time
Date
CFA PM:
Method of Shipment:
Date Shipped:
Airbill #:
Airbill #:
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N ¦ Norma! Sample3 TB = Trip Blank, FD ¦ Field Duplicate, EB - Equipment Blank, MS = Matrix Spike Sample, MSD = Matrix Spike Duplicate Sample, G ~ Grab, C = Composite
3.) Field Filtered; For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: DW=Drinking Water, GW=Groundwater. SW-Surface Water, WW-Waste Water, W-Water, ML=Misc Liquid,SO=Soil, SD=Sediment, SL=Sludge, SS=Solid Waste, 0=0il, F=Filter, P=Wipe, IMJrine, F=Fecsl, N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.eJ8290B, I668B) and number of containers provided for each (i.e. 8290B - 3,1668B -1).
6.) Preservative Type: HA ~ Hydrochloric Acid, NI - Nitric Acid, SH = Sodium Hydroxide, SA = Sulfuric Acid, A A = Ascorbic Acid, HX = Hexane, ST = Sodium Thiosulfate, If no preservative is added = leave field blank
WHITE - LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intact ?
YES NO
Cooler Temp:
2>-
-------
SAMPLE RECEIPT CHECKLIST
Work Order:
Shipping Company:
Date/Time Received:
.1
iiM \ob
Suspected Hazard Information
Shipped 3S DOT Haie'rdoos?
Samples identified as Foreign Soil?-
Yes
NA
No
DOE Site Sample Packages
Yes
NA
No*
Samples <-2x background? _
Air Sample Receipt Specifics
Air sample in shipment?
NA
No
* Notify RSO of any responses in this column immediately.
Air Witness:
Sample Receipt Criteria
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received intact
and sealed?
Circle Applicable:
leak broken damaged container leaving container other) describe)
Chain of Custody documents included
with shipment?
Samples requiring cold preservation
within 0-6'C?
f PVner^Xjon Method:
( k.e bag*''blue ict dry He non» citier (describe)
ih
Aqueous samples found to have visible
solids?
Sample IDs. containers fHecled;
Samples requiring chemical
preservation at proper pH?
Sample IDs, containers affected and pH observed:
II preservative added, lot#:
Samples requiring preservation have
no residual chlorine?
Sample 10s, containers affected:
If preservative added, lot#.
Sample 10s, tests affected:
Samples received within holding time?
Sample IDs on COC match IDs on
containers?
Sample IDs. containers affected;
Date & time of COC match date & time
on containers?
Sample 10s. tontelnerj affected:
JO
Number of containers received match
number indicated on COC?
Sample IDs, containers affected:
A
COC form is properly'signed in
relinquished/received sections?
Comments:
Checklist performed by
nitisls:
Dale:
¦^r
Li
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 29
-------
Case Narrative
Page 5 of 29
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6293
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26338
Clean Up Batch Number: 26337
Extraction Batch Number: 26336
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6293001
SFRA-124
6293002
SFRA-125
6293003
SFRA-126
6293004
SFRA-127
12010846
Method Blank (MB)
12010847
Laboratory Control Sample (LCS)
12010848
Laboratory Control Sample Duplicate (LCSD)
12010849
6293001 (SFRA-124) Matrix Spike (MS)
12010850
6293001 (SFRA-124) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Page 6 of 29
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6293001 (SFRA-124) - Batch 26338 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
The MS recoveries were within the established acceptance limits.
Matrix Spike Duplicate (MSD) Recovery Statement
The MSD recoveries were within the established acceptance limits.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Page 7 of 29
-------
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 29
-------
Sample Data Summary
Page 9 of 29
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6293 CFA Work Order: 6293
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 07 JUL 2014 Title: Data Validator
Page 10 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
6293001
1613B Soil
SFRA-124
26338
07/05/2014 14:24
b04jull4b_3-4
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
J
u
u
u
u
u
u
u
u
J
u
J
TETR001
06/26/2014 13:26
07/01/2014 10:30
EPA Method 1613B
JTF
SW846 3540C
1.09 g
Result
674
1.79
3.22
7.58
3.55
57.0
1430
2.44
1.3
1.15
1.76
1.73
1.87
2.64
26.3
3.91
30.7
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
3.01
I.79
3.22
3.44
3.55
5.06
II.1
2.44
1.30
1.15
1.76
1.73
1.87
2.64
2.73
3.91
6.42
TETR00111
SOIL
10.5
Dry Weight
HRP763
1
PQL
10.2
51.2
51.2
51.2
51.2
51.2
102
10.2
51.2
51.2
51.2
51.2
51.2
51.2
51.2
51.2
102
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1810
2050
Pg/g
88.5
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1950
2050
Pg/g
95.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1570
2050
Pg/g
76.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1580
2050
Pg/g
77.2
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
1900
2050
Pg/g
92.8
(23%-140%)
13C-OCDD
3650
4100
Pg/g
89.1
(17%-157%)
13C-2,3,7,8-TCDF
1920
2050
Pg/g
93.7
(24%-169%)
13C-1,2,3,7,8-PeCDF
1840
2050
Pg/g
89.8
(24%-185%)
13C-2,3,4,7,8-PeCDF
1990
2050
Pg/g
97.2
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1640
2050
Pg/g
80.0
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1650
2050
Pg/g
80.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1730
2050
Pg/g
84.2
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1730
2050
Pg/g
84.3
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1740
2050
Pg/g
84.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1970
2050
Pg/g
96.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
202
205
Pg/g
98.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
6293002
1613B Soil
SFRA-125
26338
07/05/2014 16:48
b04jull4b_3-7
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
J
J
J
u
J
u
J
u
J
u
TETR001
06/30/2014 14:20
07/01/2014 10:30
EPA Method 1613B
JTF
SW846 3540C
1.23 g
Result
476
4.43
12.5
43.1
15.3
772
11100
7.33
8.30
4.33
12.2
5.38
6.91
7.31
134
10.7
385
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
7.22
4.43
9.40
9.29
9.91
17.3
29.0
7.33
4.78
4.33
5.28
5.38
5.51
7.31
5.71
8.13
18.6
TETR00111
SOIL
21.4
Dry Weight
HRP763
1
PQL
10.3
51.7
51.7
51.7
51.7
51.7
103
10.3
51.7
51.7
51.7
51.7
51.7
51.7
51.7
51.7
103
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1470
2070
Pg/g
70.9
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1620
2070
Pg/g
78.4
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1330
2070
Pg/g
64.5
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1330
2070
Pg/g
64.3
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
1650
2070
Pg/g
79.6
(23%-140%)
13C-OCDD
3330
4140
Pg/g
80.3
(17%-157%)
13C-2,3,7,8-TCDF
1580
2070
Pg/g
76.5
(24%-169%)
13C-1,2,3,7,8-PeCDF
1530
2070
Pg/g
74.1
(24%-185%)
13C-2,3,4,7,8-PeCDF
1710
2070
Pg/g
82.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1380
2070
Pg/g
66.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1370
2070
Pg/g
66.1
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1420
2070
Pg/g
68.6
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1440
2070
Pg/g
69.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1450
2070
Pg/g
70.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1620
2070
Pg/g
78.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
196
207
Pg/g
94.8
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
6293003
1613B Soil
SFRA-126
26338
07/05/2014 17:35
b04jull4b_3-8
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
J
J
J
u
J
u
J
u
J
u
TETR001
06/30/2014 14:30
07/01/2014 10:30
EPA Method 1613B
JTF
SW846 3540C
1.23 g
Result
897
3.6
12.1
35.7
11.2
870
10900
7.91
16.6
5.85
21.6
8.28
8.77
8.65
284
28.2
689
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
7.42
3.60
7.50
7.19
7.77
17.4
34.2
7.91
6.57
5.85
6.16
8.28
6.57
8.65
10.3
15.5
13.1
TETR00111
SOIL
16.3
Dry Weight
HRP763
1
PQL
9.72
48.6
48.6
48.6
48.6
48.6
97.2
9.72
48.6
48.6
48.6
48.6
48.6
48.6
48.6
48.6
97.2
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1680
1940
Pg/g
86.3
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1910
1940
Pg/g
98.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1500
1940
Pg/g
77.4
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1600
1940
Pg/g
82.1
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
1780
1940
Pg/g
91.3
(23%-140%)
13C-OCDD
3770
3890
Pg/g
96.9
(17%-157%)
13C-2,3,7,8-TCDF
1820
1940
Pg/g
93.5
(24%-169%)
13C-1,2,3,7,8-PeCDF
1840
1940
Pg/g
94.8
(24%-185%)
13C-2,3,4,7,8-PeCDF
1970
1940
Pg/g
101
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1570
1940
Pg/g
80.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1640
1940
Pg/g
84.6
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1660
1940
Pg/g
85.3
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1740
1940
Pg/g
89.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1620
1940
Pg/g
83.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1840
1940
Pg/g
94.7
(26%-13 8%)
37Cl-2,3,7,8-TCDD
190
194
Pg/g
98.0
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
6293004
1613B Soil
SFRA-127
26338
07/05/2014 18:23
b04jull4b_3-9
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
TETR001
Date Collected: 06/30/2014 14:55
Date Received: 07/01/201410:30
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
J
u
u
u
u
u
u
u
u
J
u
J
EPA Method 1613B
JTF
SW846 3540C
1.06 g
Result
158
3.99
6.56
11.6
6.97
149
6720
4.32
2.7
2.39
3.91
3.99
3.96
5.99
46.8
16.2
82.6
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
10.7
3.99
6.56
6.56
6.97
11.1
21.9
4.32
2.70
2.39
3.91
3.99
3.96
5.99
10.4
16.2
12.1
TETR00111
SOIL
20.9
Dry Weight
HRP763
1
PQL
11.9
59.7
59.7
59.7
59.7
59.7
119
11.9
59.7
59.7
59.7
59.7
59.7
59.7
59.7
59.7
119
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2170
2390
Pg/g
91.0
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2360
2390
Pg/g
98.8
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1960
2390
Pg/g
82.2
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1970
2390
Pg/g
82.5
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2480
2390
Pg/g
104
(23%-140%)
13C-OCDD
5290
4770
Pg/g
111
(17%-157%)
13C-2,3,7,8-TCDF
2270
2390
Pg/g
95.1
(24%-169%)
13C-1,2,3,7,8-PeCDF
2210
2390
Pg/g
92.7
(24%-185%)
13C-2,3,4,7,8-PeCDF
2330
2390
Pg/g
97.5
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
2030
2390
Pg/g
85.2
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1990
2390
Pg/g
83.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2110
2390
Pg/g
88.4
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
2140
2390
Pg/g
89.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2170
2390
Pg/g
91.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2450
2390
Pg/g
103
(26%-13 8%)
37Cl-2,3,7,8-TCDD
253
239
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 29
-------
Quality Control
Summary
Page 15 of 29
-------
Cape Fear Analytical LLC Report Date: July 7, 2014
Hi-Res Dioxins/Furans Page 1 of 4
Surrogate Recovery Report
SDG Number: 6293
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010847
LCS for batch 26336
12010848
LCSD for batch 26336
12010846
MB for batch 26336
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
76.3
82.9
72.4
70.8
84.6
76.9
84.2
79.7
87.8
72.0
77.4
76.5
78.4
80.2
85.3
91.6
59.3
61.8
54.9
60.5
62.3
56.8
69.0
59.8
65.6
57.7
62.5
61.9
60.8
60.6
63.1
83.6
88.0
73.7
78.1
89.1
86.8
87.2
84.3
91.7
77.5
80.3
80.4
80.7
84.3
91.0
95.3
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6293001
SFRA-124
13C-2,3,7,8-TCDD
(25%-164%)
Page 16 of 29
-------
Cape Fear Analytical LLC Report Date: July 7, 2014
Hi-Res Dioxins/Furans Page 2 of 4
Surrogate Recovery Report
SDG Number: 6293
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6293001
SFRA-124
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
95.0
76.7
77.2
92.8
89.1
93.7
89.8
97.2
80.0
80.5
84.2
84.3
84.7
96.3
98.3
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010849
SFRA-124(629300 IMS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
86.0
92.1
76.0
77.3
101
95.2
88.9
91.0
94.8
80.7
80.2
84.6
83.7
84.3
103
103
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010850
SFRA-124(6293001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
86.6
93.9
81.7
73.4
93.7
89.2
92.3
89.4
97.1
79.5
81.7
81.5
81.9
86.1
92.9
99.9
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6293002
SFRA-125
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
70.9
78.4
(25%-
(25%-
64%)
81%)
Page 17 of 29
-------
Cape Fear Analytical LLC Report Date: July 7, 2014
Hi-Res Dioxins/Furans Page 3 of 4
Surrogate Recovery Report
SDG Number: 6293
Matrix Type: SOLID
Sample ID Client ID
6293002 SFRA-125
6293003 SFRA-126
6293004 SFRA-127
Surrogate
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
64.5 (32%-141%)
64.3 (28%-130%)
79.6 (23%-140%)
80.3 (17%-15 7%)
76.5 (24%-169%)
74.1 (24%-185%)
82.8 (21%-178%)
66.8 (26%-152%)
66.1 (26%-123%)
68.6 (28%-13 6%)
69.7 (29%-147%)
70.0 (28%-143%)
78.3 (26%-13 8%)
94.8 (35%-197%)
86.3 (25%-164%)
98.0 (25%-181%)
77.4 (32%-141%)
82.1 (28%-130%)
91.3 (23%-140%)
96.9 (17%-15 7%)
93.5 (24%-169%)
94.8 (24%-185%)
101 (21%-178%)
80.5 (26%-152%)
84.6 (26%-123%)
85.3 (28%-13 6%)
89.4 (29%-147%)
83.2 (28%-143%)
94.7 (26%-13 8%)
98.0 (35%-197%)
91.0 (25%-164%)
98.8 (25%-181%)
82.2 (32%-141%)
82.5 (28%-130%)
104 (23%-140%)
111 (17%-15 7%)
95.1 (24%-169%)
92.7 (24%-185%)
97.5 (21%-178%)
85.2 (26%-152%)
83.5 (26%-123%)
88.4 (28%-13 6%)
89.8 (29%-147%)
91.0 (28%-143%)
103 (26%-13 8%)
106 (35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
Page 18 of 29
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Cape Fear Analytical LLC Report Date: July 7, 2014
Hi-Res Dioxins/Furans Page 4 of 4
Surrogate Recovery Report
SDG Number: 6293
Matrix Type: SOLID
Recovery Acceptance
Sample ID Client ID Surrogate qual l imits
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 19 of 29
-------
Cape Fear Analytical LLC
Report Date: July 7, 2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOIL
Analysis Date: 07/05/2014 12:02 Dilution: 1
Prep Batch ID:26336
Batch ID: 26338
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.0
105
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
95.6
95.6
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
99.8
99.8
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
101
101
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
115
115
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
95.5
95.5
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
199
99.4
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
21.0
105
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
106
106
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
103
103
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
112
112
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
106
106
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
108
108
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
115
115
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
99.7
99.7
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
105
105
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
228
114
63-170
SDG Number: 6293
Client ID: LCS for batch 26336
Lab Sample ID: 12010847
Instrument: HRP763
Analyst: JTF
Page
20 of 29
-------
Cape Fear Analytical LLC
Report Date: July 7, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOIL
Analysis Date: 07/05/2014 12:49 Dilution: 1
Prep Batch ID:26336
Batch ID: 26338
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.8
109
67-158
3.76
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
95.3
95.3
70-142
0.316
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
101
101
70-164
1.31
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
99.6
99.6
76-134
1.59
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
108
108
64-162
6.18
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
97.2
97.2
70-140
1.72
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
205
102
78-144
3.06
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.4
96.8
75-158
7.97
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
105
105
80-134
0.273
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
102
102
68-160
1.28
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
106
106
72-134
5.76
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
104
104
84-130
2.27
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
108
108
70-156
0.157
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
109
109
78-130
4.58
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
103
103
82-122
2.92
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
103
103
78-138
1.86
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
234
117
63-170
2.46
0-20
SDG Number: 6293
Client ID: LCSD for batch 26336
Lab Sample ID: 12010848
Instrument: HRP763
Analyst: JTF
Page 21 of 29
-------
Cape Fear Analytical LLC
Report Date: July 7, 2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
207
284
105
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1030
U
1000
96.8
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1030
U
1100
106
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1030
J
1030
98.6
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1030
u
1190
115
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1030
1090
100
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2070
2900
71.1
70-130
51207-31-9
MS
2,3,7,8-TCDF
207
u
217
105
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1030
u
1080
104
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1030
u
1080
104
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1030
u
1140
110
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1030
u
1160
113
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1030
u
1120
108
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1030
u
1200
116
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1030
J
1070
101
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1030
u
1100
106
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2070
J
2450
117
70-130
SDG Number: 6293
Client ID: SFRA-124(6293001MS)
Lab Sample ID: 12010849
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOIL
%Moisture: 10.5
Analysis Date: 07/05/2014 15:12
Prep Batch ID:26336
Batch ID: 26338
Page 22 of 29
-------
Cape Fear Analytical LLC
Report Date: July 7, 2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOIL
%Moisture: 10.5
Analysis Date: 07/05/2014 16:00 Dilution: 1
Prep Batch ID:26336
Batch ID: 26338
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
215
297
107
70-130
4.19
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1070
U
1060
98.6
70-130
5.56
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1070
U
1090
102
70-130
0.690
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1070
J
1090
101
70-130
6.00
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1070
U
1210
112
70-130
1.46
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1070
1150
101
70-130
4.69
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2150
3070
76.3
70-130
5.61
0-20
51207-31-9
MSD
2,3,7,8-TCDF
215
u
220
102
70-130
1.42
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1070
u
1150
107
70-130
6.72
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1070
u
1120
104
70-130
3.57
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1070
u
1240
115
70-130
8.32
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1070
u
1150
107
70-130
0.820
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1070
u
1200
111
70-130
6.48
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1070
u
1280
119
70-130
6.25
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1070
J
1110
101
70-130
4.14
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1070
u
1120
104
70-130
1.62
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2150
J
2450
112
70-130
0.0393
0-20
SDG Number: 6293
Client ID: SFRA-124(6293001MSD)
Lab Sample ID: 12010850
Instrument: HRP763
Analyst: JTF
Page
23 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7, 2014
Method Blank Summary
Page 1 of 1
SDG Number:
Client ID:
Lab Sample ID: 12010846
Column:
6293
MB for batch 26336
Client: TETR001
Instrument ID: HRP763
Prep Date: 01-JUL-14
Matrix: SOIL
Data File: b04jull4b_3-3
Analyzed: 07/05/1413:37
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26336
12010847
b04jull4b_3-l
07/05/14
1202
02
LCSD for batch 26336
12010848
b04jull4b_3-2
07/05/14
1249
03
SFRA-124
6293001
b04jull4b_3-4
07/05/14
1424
04
SFRA-124(629300 IMS)
12010849
b04jull4b_3-5
07/05/14
1512
05
SFRA-124(6293001MSD)
12010850
b04jull4b_3-6
07/05/14
1600
06
SFRA-125
6293002
b04jull4b_3-7
07/05/14
1648
07
SFRA-126
6293003
b04jull4b_3-8
07/05/14
1735
08
SFRA-127
6293004
b04jull4b_3-9
07/05/14
1823
Page 24 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
12010846
QC for batch 26336
MB for batch 26336
26338
07/05/2014 13:37
b04jull4b_3-3
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
U
u
u
u
u
u
J
u
u
u
u
u
u
u
u
u
u
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Result
^568
.302
.442
.44
.466
.654
1.37
.414
.222
.184
.242
.226
.226
.338
.38
.57
1.13
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
EDL
0.568
0.302
0.442
0.440
0.466
0.654
1.27
0.414
0.222
0.184
0.242
0.226
0.226
0.338
0.380
0.570
1.13
TETR00111
SOIL
As Received
HRP763
1
PQL
1.00
5.00
5.00
5.00
5.00
5.00
10.0
1.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
167
200
Pg/g
83.6
(25 %-164%)
13C-1,2,3,7,8-PeCDD
176
200
Pg/g
88.0
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
147
200
Pg/g
73.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
156
200
Pg/g
78.1
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
178
200
Pg/g
89.1
(23%-140%)
13C-OCDD
347
400
Pg/g
86.8
(17%-157%)
13C-2,3,7,8-TCDF
174
200
Pg/g
87.2
(24%-169%)
13C-1,2,3,7,8-PeCDF
169
200
Pg/g
84.3
(24%-185%)
13C-2,3,4,7,8-PeCDF
183
200
Pg/g
91.7
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
155
200
Pg/g
77.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
161
200
Pg/g
80.3
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
161
200
Pg/g
80.4
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
169
200
Pg/g
84.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
182
200
Pg/g
91.0
(26%-13 8%)
37Cl-2,3,7,8-TCDD
19.1
20.0
Pg/g
95.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 25 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
12010847
QC for batch 26336
LCS for batch 26336
26338
07/05/2014 12:02
b04jull4b_3-l
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Result
217)
95.6
99.8
101
115
95.5
199
21.0
106
103
112
106
108
115
99.7
105
228
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
EDL
0.562
0.526
0.796
0.834
0.866
1.32
2.20
0.464
0.532
0.460
1.15
1.02
1.11
1.66
0.942
1.52
2.54
TETR00111
SOIL
As Received
HRP763
1
PQL
1.00
5.00
5.00
5.00
5.00
5.00
10.0
1.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
153
200
Pg/g
76.3
(20%-175%)
13C-1,2,3,7,8-PeCDD
166
200
Pg/g
82.9
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
145
200
Pg/g
72.4
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
142
200
Pg/g
70.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
169
200
Pg/g
84.6
(22%-166%)
13C-OCDD
308
400
Pg/g
76.9
(13%-199%)
13C-2,3,7,8-TCDF
168
200
Pg/g
84.2
(22%-152%)
13C-1,2,3,7,8-PeCDF
159
200
Pg/g
79.7
(21%-192%)
13C-2,3,4,7,8-PeCDF
176
200
Pg/g
87.8
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
144
200
Pg/g
72.0
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
155
200
Pg/g
77.4
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
153
200
Pg/g
76.5
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
157
200
Pg/g
78.4
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
160
200
Pg/g
80.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
171
200
Pg/g
85.3
(20%-186%)
37Cl-2,3,7,8-TCDD
18.3
20.0
Pg/g
91.6
(31 %-191%)
Comments:
Page 26 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
12010848
QC for batch 26336
LCSD for batch 26336
26338
07/05/2014 12:49
b04jull4b_3-2
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Result
2L8
95.3
101
99.6
108
97.2
205
19.4
105
102
106
104
108
109
103
103
234
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
EDL
0.662
0.856
1.00
0.920
1.01
1.73
2.64
0.530
0.706
0.666
1.51
1.40
1.60
2.28
1.14
1.85
3.48
TETR00111
SOIL
As Received
HRP763
1
PQL
1.00
5.00
5.00
5.00
5.00
5.00
10.0
1.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
5.00
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
119
200
Pg/g
59.3
(20%-175%)
13C-1,2,3,7,8-PeCDD
124
200
Pg/g
61.8
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
110
200
Pg/g
54.9
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
121
200
Pg/g
60.5
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
125
200
Pg/g
62.3
(22%-166%)
13C-OCDD
227
400
Pg/g
56.8
(13%-199%)
13C-2,3,7,8-TCDF
138
200
Pg/g
69.0
(22%-152%)
13C-1,2,3,7,8-PeCDF
120
200
Pg/g
59.8
(21%-192%)
13C-2,3,4,7,8-PeCDF
131
200
Pg/g
65.6
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
115
200
Pg/g
57.7
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
125
200
Pg/g
62.5
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
124
200
Pg/g
61.9
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
122
200
Pg/g
60.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
121
200
Pg/g
60.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
126
200
Pg/g
63.1
(20%-186%)
37Cl-2,3,7,8-TCDD
18.0
20.0
Pg/g
89.8
(31 %-191%)
Comments:
Page 27 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
12010849
QC for batch 26336
SFRA-124(6293001MS)
26338
07/05/2014 15:12
b04jull4b_3-5
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
TETR001
06/26/2014 13:26
07/01/2014 10:30
EPA Method 1613B
JTF
SW846 3540C
1.08 g
Result
284
1000
1100
1030
1190
1090
2900
217
1080
1080
1140
1160
1120
1200
1070
1100
2450
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
4.20
4.82
10.2
10.6
11.0
8.96
15.1
3.76
6.27
6.14
9.97
9.95
10.1
15.0
6.99
9.04
16.3
TETR00111
SOIL
10.5
Dry Weight
HRP763
1
PQL
10.3
51.7
51.7
51.7
51.7
51.7
103
10.3
51.7
51.7
51.7
51.7
51.7
51.7
51.7
51.7
103
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1780
2070
Pg/g
86.0
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1900
2070
Pg/g
92.1
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1570
2070
Pg/g
76.0
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1600
2070
Pg/g
77.3
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2090
2070
Pg/g
101
(23%-140%)
13C-OCDD
3940
4140
Pg/g
95.2
(17%-157%)
13C-2,3,7,8-TCDF
1840
2070
Pg/g
88.9
(24%-169%)
13C-1,2,3,7,8-PeCDF
1880
2070
Pg/g
91.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
1960
2070
Pg/g
94.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1670
2070
Pg/g
80.7
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1660
2070
Pg/g
80.2
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1750
2070
Pg/g
84.6
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1730
2070
Pg/g
83.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1740
2070
Pg/g
84.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2140
2070
Pg/g
103
(26%-13 8%)
37Cl-2,3,7,8-TCDD
212
207
Pg/g
103
(35%-197%)
Comments:
Page 28 of 29
-------
Cape Fear Analytical LLC
Report Date:
July 7,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-01-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
57117-41-6
57117-31-4
70648-26-9
57II7.44.9
60851-34-5
72918-21-9
67562-39-4
55673-89-7
39001-02-0
2,3:
1,2.
1,2.
1,2.
1,2.
1,2.
1.2.
2.3.
1.2.
2.3.
1,2.
1.2.
2.3.
1,2.
1,2.
1,2.
1,2.
6293
12010850
QC for batch 26336
SFRA-124(6293001MSD)
26338
07/05/2014 16:00
b04jull4b_3-6
26336
01-JUL-14
Parmname
,7,8-TCDD
,3,7,8-PeCDD
,3,4,7,8-HxCDD
,3,6,7,8-HxCDD
,3,7,8,9-HxCDD
,3,4,6,7,8-HpCDD
,3,4,6,7,8,9-OCDD
,7,8-TCDF
,3,7,8-PeCDF
,4,7,8-PeCDF
,3,4,7,8-HxCDF
,3,6,7,8-HxCDF
,4,6,7,8-HxCDF
,3,7,8,9-HxCDF
,3,4,6,7,8-HpCDF
,3,4,7,8,9-HpCDF
,3,4,6,7,8,9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
TETR001
06/26/2014 13:26
07/01/2014 10:30
EPA Method 1613B
JTF
SW846 3540C
1.04 g
Result
297
1060
1090
1090
1210
1150
3070
220
1150
1120
1240
1150
1200
1280
1110
1120
2450
Units
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
5.13
4.27
10.4
11.2
11.5
10.4
18.9
3.91
5.91
5.31
10.7
10.6
11.3
16.8
9.26
14.2
19.6
TETR00111
SOIL
10.5
Dry Weight
HRP763
1
PQL
10.7
53.7
53.7
53.7
53.7
53.7
107
10.7
53.7
53.7
53.7
53.7
53.7
53.7
53.7
53.7
107
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1860
2150
Pg/g
86.6
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2020
2150
Pg/g
93.9
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1750
2150
Pg/g
81.7
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1580
2150
Pg/g
73.4
(2 8 %-13 0%)
13C-1,2,3,4,6,7,8-HpCDD
2010
2150
Pg/g
93.7
(23%-140%)
13C-OCDD
3830
4300
Pg/g
89.2
(17%-157%)
13C-2,3,7,8-TCDF
1980
2150
Pg/g
92.3
(24%-169%)
13C-1,2,3,7,8-PeCDF
1920
2150
Pg/g
89.4
(24%-185%)
13C-2,3,4,7,8-PeCDF
2080
2150
Pg/g
97.1
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1710
2150
Pg/g
79.5
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1760
2150
Pg/g
81.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1750
2150
Pg/g
81.5
(2 8 %-13 6%)
13C-1,2,3,7,8,9-HxCDF
1760
2150
Pg/g
81.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1850
2150
Pg/g
86.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1990
2150
Pg/g
92.9
(26%-13 8%)
37Cl-2,3,7,8-TCDD
215
215
Pg/g
99.9
(35%-197%)
Comments:
Page 29 of 29
-------
Cape Fear Analytical LLC
Report Date:
July % 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-* >1-6
40321-70-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
5711 7-4i
57117-31-
70648-26-
57117-44.
60851-34-
72918-21-'
67562-39-4
55673-89-7
39001-02-0
6302
6302001
161311 Soil
SFRA-129
26346
07/08/2014 18:29
b07jull4a_3-9
26344
07-JUL-14
Paramame
,7,8-TCDD
,3,7,8-PeO])[)
,3,4,7,8-HxCDD
,3,6,7,8-HxODD
,3,7,8,9-IIxCDD
, 3,4,6,7,8 -I Ip ODD
,3,4,6,7,8,9-001)1)
,7,8-TCDF
,3,7,8-PeODF
,4,7,8-PeODF
,3,4,7,8-IIxODF
,3,6,7,8-" """"
,4,6,7,8-
,3,7,8,9-
, 3,4,6,7,8 -I Ip CDF
,3,4,7,8,9-IIpODF
,3,4,6,7.8.9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Suinniary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
Qual
TETR001
07/01/2014 09:55
07/03/2014 10:50
EPA Method 1613B
JTF
SW846 3540C
1 g
Result
Units
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
TETR00114
SOIL
25.9
Dry Weight
IIRP763
1
PQL
13.5
67.5
67.5
67.5
67.5
67.5
135
13.5
67.5
67.5
67.5
67.5
67.5
67.5
67.5
67.5
Surrogate/'!racer recovery
Qual Result
Units
Recoverv%
Acceptable Limits
130-2,3,7,8-TODD
2240
2700
Pg'g
82.9
(25%-164%)
1 30-1,2,3,7,8-PeOl )D
2630
2700
Pg'g
97.5
(25°/b-181%)
1 30-1,2,3,4,7,8-HxODD
1910
2700
pg/g
70.7
(32%-141%)
1 30-1,2,3,6,7.8-HxCDD
2380
2700
Pg'g
88.2
(28%-130%)
130-1,2,3,4,6.7,8-HpODD
2500
2700
Pg'g
92.8
(23%-140%)
130-00])!)
5010
5400
Pg'g
92.8
(17%-15 7%)
130-2,3,7,8-TCDF
2360
2700
pg.'g
87.5
(24%-169%)
130-1,2,3,7,8-PeODF
2540
2700
pg'g
94.2
(24%-185%)
130-2,3,4,7,8-PeODK
2780
2700
Pg'g
103
(21%-178%)
1 30-1,2,3,4,7,8-HxOl )F
2050
2700
Pg'g
75.9
(26%-152%)
1 30-1,2,3,6,7,8-HxODF"
2240
2700
pg.'g
83.0
(26%-123%)
13C-2,3,4,6,7,8-IIxCDF
2230
2700
pg/g
82.8
(28%-136%)
130-1,2,3,7,8,9-IIxCDF
2320
2700
pg/g
86.1
(29%-147%)
13C-1,2,3,4,6,7,8-IIpCDF
2430
2700
pg/g
90.1
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2590
2700
pg/g
96.1
(26%-13 8%)
3701-2,3,7,8-TCDD
262
270
Pg/g
97.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
July % 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
CAS No.
1746-* >1-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
5711 7-4i
57117-31-
70648-26-
57117-44.
60851-34-
72918-21-'
67562-39-4
55673-89-7
39001-02-0
6302
6302002
161311 Soil
SFRA-130
26346
07/08/2014 19:17
b07jull4a_3 10
26344
07-JUL-14
Paramame
,7,8-TCDD
,3,7,8-PeO])[)
,3,4,7,8-HxCDD
,3,6,7,8-HxODD
,3,7,8,9-IIxCDD
, 3,4,6,7,8 -I Ip ODD
,3,4,6,7,8,9-001)1)
,7,8-TCDF
,3,7,8-PeODF
,4,7,8-PeODF
,3,4,7,8-IIxCDF
,3,6,7,8-" """"
,4,6,7,8-
,3,7,8,9-
, 3,4,6,7,8 -I Ip CDF
,3,4,7,8,9-IIpODF
,3,4,6,7.8.9-OCDF
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
07/02/2014 09:10
07/03/2014 10:50
EPA Method 1613B
JTF
SW846 3540C
1.15 g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOIL
23.1
Dry Weight
IIRP763
1
PQL
11.3
56.5
56.5
56.5
56.5
56.5
113
11.3
56.5
56.5
56.5
56.5
56.5
56.5
56.5
56.5
113
Surrogate/'!racer recovery
Qual Result
Units
Recoverv%
Acceptable Limits
130-2,3,7,8-TODD
1850
2260
Pg'g
81.6
(25%-164%)
1 30-1,2,3,7,8-PeOl )D
2060
2260
Pg'g
91.1
(25°/b-181%)
1 30-1,2,3,4,7,8-HxODD
1560
2260
pg/g
69.1
(32%-141%)
1 30-1,2,3,6,7.8-HxCDD
1960
2260
Pg'g
86.8
(28%-130%)
130-1,2,3,4,6.7,8-HpODD
2000
2260
Pg'g
88.3
(23%-140%)
130-00])!)
4200
4520
Pg'g
92.9
(17%-15 7%)
1 30-2,3,7,8-TC/DF
1930
2260
pg.'g
85.6
(24%-169%)
130-1,2,3,7,8-PeODF
1970
2260
pg'g
87.2
(24%-185%)
130-2,3,4,7,8-PeODK
2250
2260
Pg'g
99.4
(21%-178%)
1 30-1,2,3,4,7,8-HxOl )F
1690
2260
Pg'g
74.6
(26%-152%)
1 30-1,2,3,6,7,8-HxODF"
1920
2260
pg.'g
84.9
(26%-123%)
13C-2,3,4,6,7,8-IIxCDF
1880
2260
pg/g
83.3
(28%-136%)
130-1,2,3,7,8,9-IIxCDF
1970
2260
pg/g
87.0
(29%-147%)
13C-l,2,3,4,6,7,8-IIpCDF
1970
2260
pg/g
87.3
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
2090
2260
pg/g
92.7
(26%-13 8%)
3701-2,3,7,8-TCDD
210
226
Pg/g
93.0
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
July % 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6302
6302003
161311 Soil
SFRA-131
26346
07/08/2014 20:05
b07jull4a_3 11
26344
07-JUL-14
CAS No.
1746-* >1-6
40321-76-4
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
5711 7-4i
57117-31-
70648-26-
57117_44_
60851-34-
72918-21-'
67562-39-4
55673-89-7
39001-02-0
Parmname
3,7,8-TCDD
2,3,7,8-PeODD
2,3,4,7,8-HxCDD
2.3.6.7.8-HxCl )D
2.3.7.8.9-IIxCDD
2,3,4,6,7,8-IIpCDD
2,3,4,6,7,8,9-OODl)
3,7,8-TCDF
2,3,7,8-PeODF
3,4,7,8-PeCDF
2,3,4,7,8-IIxCDF
2,3,6,7,8-''
3.4.6.7.8-
2.3.7.8.9-
2.3.4.6.7.8-IIpCDF
2.3.4.7.8.9-IIpCDF
2,3,4,6,7.8.9-OCDF
Surrogate/'! racer recovery
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
07/02/2014 14:35
07/03/2014 10:50
EPA Method 1613B
JTF
SW846 3540C
1.19 g
Units
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
EDL
Comments:
E Value is estimated - Concentration of the target analyte exceeds the instrument calibration range
J Value is estimated
I Analyte was analyzed for, but not detected above the specified detection limit.
TETR00114
SOIL
27.5
Dry Weight
IIRP763
1
PQL
11.6
57.9
57.9
57.9
57.9
57.9
116
11.6
57.9
57.
57.
57.
57.
57.
57.
57.
116
Recovery% Acceptable Limits
13C-2,3,7,8-TODD
2(170
2320
Pg'g
89.3
(25%-164%)
1 30-1,2,3,7,8-PeODD
2*0
2320
Pg'g
97.5
(25°/b-181%)
1 30-1,2,3,4,7,8-HxCDD
1870
2320
pg.'g
80.7
(32%-141%)
1 30-1,2,3,6,7.8-HxCDD
1920
2320
Pg'g
83.0
(28%-130%)
130-1,2,3,4,6.7,8-HpCDD
2180
2320
Pg'g
94.2
(23%-140%)
13C-OODD
4370
4640
Pg'g
94.3
(17%-15 7%)
130-2,3,7,8-TCDF
2210
2320
pg.'g
95.5
(24%-169%)
1 30-1,2,3,7,8-PeODF
2200
2320
Pg'g
94.9
(24%-185%)
130-2,3,4,7,8-PeODK
2310
2320
Pg'g
99.8
(21%-178%)
130-1,2,3,4,7,8-HxCDK
1980
2320
Pg'g
85.6
(26%-152%)
1 30-1,2,3,6,7,8-HxCDF"
2080
2320
pg.'g
89.6
(26%-123%)
13C-2,3,4,6,7,8-ILxCDF
2110
2320
Pg/g
90.8
(28%-136%)
13C-l,2,3,7,8,9-IIxCDF
2090
2320
Pg/g
90.0
(29%-147%)
13C-l,2,3,4,6,7,8-IIpCDF
2140
2320
pg/g
92 3
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
2230
2320
Pg/g
96.0
(26%-13 8%)
37C1-2,3,7,8-TCDD
285
232
Pg/g
123
(35%-197%)
-------
Cape Fear Analytical LLC
Report Date:
July % 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6302
6302004
161311 Soil
SFRA-132
26346
07/08/2014 20:53
b07jull4a_3 12
26344
07-JUL-14
CAS No.
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
5711 7-4i
57117-31-
70648-26-
57117_44_
60851-34-
72918-21-'
67562-39-4
55673-89-7
39001-02-0
Paramame
3,7,8-TCDD
2,3,7,8-PeODD
2,3,4,7,8-HxCDD
2.3.6.7.8-HxCl )D
2.3.7.8.9-IIxCDD
2,3,4,6,7,8-IIpCDD
2,3,4,6,7,8,9-OODI)
3,7,8-TCDF
2,3,7,8-PeODK
3,4,7,8-PeCDF
2,3,4,7,8-IIxCDF
2,3,6,7,8-''
3.4.6.7.8-
2.3.7.8.9-
2.3.4.6.7.8-IIpCDF
2.3.4.7.8.9-IIpCDF
2,3,4,6,7.8.9-OCDF
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
07/02/2014 14:30
07/03/2014 10:50
EPA Method 1613B
JTF
SW846 3540C
1.39 g
Project:
Matrix:
%Moisturc:
Prep Basis:
Instrumeiit:
Dilution:
TETR00114
SOIL
13.2
Dry Weight
HRP763
I
PQL
S 2°
41.4
41.4
41.4
41.4
82.9
8.29
41.4
41.4
41.4
41.4
41.4
41.4
41.4
41.4
82.9
Surrogate/'!racer recovery
Qual Result
Units
Recoverv%
Acceptable Limits
130-2,3,7,8-TODD
1470
1660
Pg'g
88.6
(25%-164%)
1 30-1,2,3,7,8-PeODD
1S40
1660
Pg'g
93 2
(25°/b-181%)
1 30-1,2,3,4,7,8-HxODD
1270
1660
pg/g
76.6
(32%-141%)
1 30-1,2,3,6,7.8-HxCDD
1290
1660
Pg'g
77.9
(28%-130%)
130-1,2,3,4,6.7,8-HpCDD
1550
1660
Pg'g
93.7
(23%-140%)
1 3O-O0DD
2870
3310
Pg'g
86.5
(17%-15 7%)
130-2,3,7,8-TCDF
1530
1660
pg.'g
92.4
(24%-169%)
130-1,2,3,7,8-PeCDF
1490
1660
pg'g
89.7
(24%-185%)
130-2,3,4,7,8-PeODK
1700
1660
Pg'g
103
(21%-178%)
1 30-1,2,3,4,7,8-HxCl )F
1310
1660
Pg'g
79.1
(26%-152%)
1 30-1,2,3,6,7,8-HxODF"
1420
1660
pg.'g
85.4
(26%-123%)
13C-2,3,4,6,7,8-IIxCDF
1400
1660
pg/g
84.5
(28%-136%)
130-1,2,3,7,8,9-IIxCDF
1410
660
pg/g
85.3
(29%-147%)
130-1,2,3,4,6,7,8-IIpCDF
1450
660
pg/g
87 7
(28%-143%)
130-1,2,3,4,7,8.9-HpCDF
1520
1660
pg/g
91.7
(26%-13 8%)
3 701-2,3,7,8-TCDD
187
166
Pg/g
113
(35%-197%)
Comments:
E Value is estimated - Concentration of the target analyte exceeds the instrument calibration range
J Value is estimated
I Analyte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date: July 9,2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch
Prep Date:
CAS No.
39227-28-6
57653-85-7
19408-74-3
35822-46-9
3268-87-9
51207-31-9
5711 7-4i
57117-31-
70648-26-
57117-44.
60851-34-
72918-21-'
67562-39-4
55673-89-7
39001-02-0
6302
6302005
161311 Soil
SFRA-133
26346
07/08/2014 21:40
b07jull4a_3 13
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/02/2014 14:55
07/03/2014 10:50
EPA Method H.I.Hi
JTF
Project:
Matrix:
%Moisturc:
Prep Basis:
Instrumeiit:
Dilution:
TETR00114
SOIL
14.4
l>ry Weight
HRP763
I
26344
Prep Method:
SW846 3540C
07-JUL-14
Prep Aliquot:
1.19 g
Parmname
Qual
Result
Units
EDI.
PQL
3,7,8-TCDD
K
5670
Pgg
9.37
9.82
2,3,7,8-PeODD
i J
Pg-'g
o::
49.1
2,3,4,7,8-HxCDD
U
7.54
Pg/g
7.54
49.1
2,3,6,7,8-HxODD
J
40.2
Pg/g
7.54
49.1
2,3,7,8,9-IIxCDD
J
10.9
Pg'g
7.97
49.1
3,4,6,7.8 -I Ip ODD
612
pg;'g
14.7
49.1
2,3,4,6,7,8,9-OODl
11400
Pg/g
39.5
98.2
3,7,8-TCDF
36.4
pg/g
8.03
9.82
2,3,7,8-PeODK
u
4.58
pg«
4.58
49.1
3,4,7,8-PeCDF
J
6.48
Pg'g
3.87
49.1
2,3,4,7,8-IIxCDF
J
13.3
Pg;'g
5.18
49.1
2,3,6,7,8-''
J
6.76
Pg/g
4.99
49.1
3,4,6,7,8-
J
11.0
Pg/g
5.24
49.1
2,3,7,8,9-
u
7.09
Pg/g
7.09
49.1
3,4,6,7.8 -I Ip CDF
189
pg;'g
5.36
49.1
2,3,4,7,8,9-IIpCDF
1
,51
Pg'g
8.86
49.1
2,3,4,6,7,8,9-OCDF
243
Pg/g
21.6
98.2
Surrogate/'!racer recovery
Qual Result
Units
Recoverv%
Acceptable Limits
130-2,3,7,8-TODD
1830
1960
Pg'g
93.3
(25%-164%)
1 30-1,2,3,7,8-PeODD
2060
1960
Pg'g
105
(25°/b-181%)
1 30-1,2,3,4,7.8-HxODD
1490
I960
pg/g
76.1
(32%-141%)
1 30-1,2,3,6,7.8-HxCDD
1720
I960
pg'g
87.5
(28%-130%)
1 30-1,2,3,4,6,7,8-HpOl )D
1960
I960
Pg'g
99.7
(23%-140%)
130-OODD
3780
3930
Pg'g
96.1
(17%-15 7%)
130-2,3,7,8-TCDF
1900
I960
pg/g
96.9
(24%-169%)
130-1,2,3,7,8-PeODF
1980
I960
pg'g
101
(24%-185%)
130-2,3,4,7,8-PeODK
2240
I960
Pg'g
114
(21 %-178%)
1 30-1,2,3,4,7,8-HxOl )F
1650
I960
Pg'g
83.8
(26%-152%)
1 30-1,2,3,6,7,8-HxODF"
1 790
I960
pg/g
91.2
(26%-123%)
13C-2,3,4,6,7,8-IIxCDF
1760
1960
pg/g
89.7
(28%-136%)
13C-l,2,3,7,8,9-IIxCDF
1900
1960
pg/g
97.0
(29%-147%)
13C-1,2,3,4,6.7.8-IIpCDF
1880
1960
pg/g
95.8
(28%-143%)
130-1,2,3,4,7,8,9-IIpCDF
1990
1960
pg/g
101
(26%-13 8%)
3 701-2,3,7,8-TCDD
227
196
pg/g
116
(35%-197%)
Comments:
E Value is estimated - Concentration of the target analvte exceeds the instrument calibration
range
J Value is estimated
I Analvte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
July 11. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6315
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 09, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 26
problem solved
-------
of
Project #:
CFAQuote#:
COC Number (l>:_
PO Number:
Cape Fear Analytical, LLC
Chain of Custody and Analytic#! Request
CFA Work Order Number; / O /A.
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 195-0421
Client Name: t <3-Clu <
Phone#. ffffy
Sample Analysis Requested(5) (Fill in the number of containers for each test)
fa
OQ
K
O
p'°"°jsi'cN"e.^ftcKtr I A&iotsy
Address
: ZX>CT4wA-€CxhsuJi^ Fu/w jPnxrtLo'
'Collected by: ^^ Send Results To: JU&l tffcWft/, fid"
00 \
Sample ID
• For composites - indicate start and stop date/time
•Date Collected
(min-dd-yy)
Time
Collected
(Military)
(hhmm)
QC Code
a
Field
Filtered
gfP S~Ffi A- - 13 ^ * 7^7?" i-Stft ejl
Sample
Matrix (4)
1.0
<- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
*
J2X
13 (o
^7
1557^.
IS30
I
3Z
~7Umvc 4%tffipv*-
J2^.
13^4 I3~7
y.ta/l- Q/&tS it'Z-
'•U—inr
fatErjcf'
T7
A. Specify: A-
1
t
TAT Requested: Normal:
Rush:
Fax Results:
Yes
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
Di^V/ fu/HViS
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 ifH^vel jj/' Level 4
Sample Collection nine-gone
-MCtfmain
Pacific
Other
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Date
Time
ifr.is
Received by (signed) Date
Time
\£tt/mjuuh oHSo
CFA PM:
Method of Shipment:
FecfeX
Date Shipped:
Wit
Airbill #:
3IS1 n®S~i
3
Airbill#:
1.) Chain nlCustody Number ~ Client Determined
2.) QC Codes: N = Normal Sample, TB 1 rip Blank, FD = Field Duplicate, IB - Equipment Blank, MS - Matrix Spike Sample, MSD - Matrix Spike Duplicate Sample, G - Grab, C - Composite
3.) Field Filtered; For liquid matrices, indicate with a-Y - for yes the sample was field filtered or-N - for sample was not field filtered.
4.) Matrix Codes: DW Drinking Water, GW=Oroundwater, SW=Surface Water, WW-Waste Water, W-Water, ML-Misc Liquid, SO«Soii, SB-Sediment, SL=Sludge, SS-Solid Waste, O-Oil, F^Filter, P- Wipe. IMJrine, F Kecal. N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.e,B290B, l«8B)iuidnumberofco«ataersprovidedforeach(i.e.S2MB -3, M68B-1),
6.) Preservative Type: HA - Hydrochloric Acid.NI = Nitric Acid, SH - Sodium Hydroxide, SA - Sulfuric Acid, A A *• Ascorbic Acid, MX = Hexane, ST - Sodium TMosulfate, If no preservative is added = leave field Wank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
mfy Seal intact?
IKES NO
zboler Temp:
S3jl
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
Work Order: A, / ET
Shipping Company:
Date/Time Received: (/L jL\ 5~0
Suspiected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
s'
Samples identified as Foreign Soil?
U-
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Air Sample Receipt Specifics
Yes
NA
No
Air sample in shipment?
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
Circle Applicable:
seals broken damaged container leaking container other(describe)
2
Chain of Custody documents included
with shipment?
3
Samples requiring cold preservation
within 0-6°C?
V"'
Praggjvation Method:
pe bagsS blue ice dry ice none other {describe}
4
Aqueous samples found to have visible
solids?
,W-
X
Sample IDs, containers affected:
5
Samples requiring chemical
preservation at proper pH?
C—'
X
Sample IDs, containers affected and pH observed:
If preservative added, Lot#;
6
Samples requiring preservation have
no residual chlorine?
/
Sample IDs, containers affected:
if preservative added, Lot#:
7
Samples received within holding time?
Sample IDs, tests affected:
8
Sample IDs on COC match IDs on
containers?
~
Sample IDs, containers affected:
9
Date & time of COC match date & time
on containers?
Sample IDs, containers affected:
10
Number of containers received match
number indicated on COC?
/
Sample IDs, containers affected:
11
COC form is properly signed in
relinquished/received sections?
Comments:
Checklist performed by: Initials: I ,-ff Date:
Page 3 of 26
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 26
-------
Case Narrative
Page 5 of 26
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6315
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26378
Clean Up Batch Number: 26377
Extraction Batch Number: 26376
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6315001
SFRA-134
6315002
SFRA-135
12010882
Method Blank (MB)
12010883
Laboratory Control Sample (LCS)
12010884
Laboratory Control Sample Duplicate (LCSD)
12010885
6315001(SFRA-134) Matrix Spike (MS)
12010886
6315001(SFRA-134) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Page 6 of 26
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6315001 (SFRA-134) - Batch 26378 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
Three MS recoveries for this SDG were not within the acceptance limits and can be attributed to
matrix interference. 12010885 (SFRA-134) - Batch 26378.
Matrix Spike Duplicate (MSD) Recovery Statement
One MSD recovery for this SDG were not within the acceptance limits. The failure confirms in
the MS and can be attributed to matrix interference. 12010886 (SFRA-134) - Batch 26378.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Page 7 of 26
-------
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26378.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 26
-------
Sample Data Summary
Page 9 of 26
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6315 CFA Work Order: 6315
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 11 JUL 2014 Title: Data Validator
Page 10 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6315
6315001
1613 Soil
SFRA-134
26378
07/10/2014 17:41
b09jull4a 4-4
26376
09-JUL-14
Client:
Date Collected:
Date Received:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
07/08/2014 15:48
07/09/2014 09:50
EPA Method 1613B
JTF
SW846 3540C
1 g
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
12.3
Dry Weight
HRP763
1
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
812
Pg/g
8.01
11.4
40321-76-4
1,2,3,7,8-PeCDD
u
6.39
Pg/g
6.39
57.0
39227-28-6
1,2,3,4,7,8-HxCDD
J
16.8
Pg/g
12.5
57.0
57653-85-7
1,2,3,6,7,8-HxCDD
J
40.8
Pg/g
9.83
57.0
19408-74-3
1,2,3,7,8,9-HxCDD
J
13.1
Pg/g
11.5
57.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
1170
Pg/g
24.6
57.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14100
Pg/g
76.9
114
51207-31-9
2,3,7,8-TCDF
u
6.73
Pg/g
6.73
11.4
57117-41-6
1,2,3,7,8-PeCDF
J
10.3
Pg/g
5.00
57.0
57117-31-4
2,3,4,7,8-PeCDF
J
6.39
Pg/g
4.24
57.0
70648-26-9
1,2,3,4,7,8-HxCDF
J
27.9
Pg/g
7.94
57.0
57II7.44.9
1,2,3,6,7,8-HxCDF
J
10.3
Pg/g
7.30
57.0
60851-34-5
2,3,4,6,7,8-HxCDF
J
10.5
Pg/g
8.08
57.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
11.7
Pg/g
11.7
57.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
203
Pg/g
9.79
57.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
18.8
Pg/g
17.0
57.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
522
Pg/g
34.9
114
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1960
2280
Pg/g
86.0
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1990
2280
Pg/g
87.2
(25%-181
/o)
130-1,2,3,4,7,
8-HxCDD
1490
2280
Pg/g
65.4
(32%-141
/o)
130-1,2,3,6,7,
8-HxCDD
1960
2280
Pg/g
85.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1960
2280
Pg/g
86.1
(23%-140%)
13C-OCDD
3330
4560
Pg/g
73.0
(17%-157%)
13C-2,3,7,8-TCDF
2310
2280
Pg/g
101
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2090
2280
Pg/g
91.6
(24%-185
/o)
130-2,3,4,7,8-
PeCDF
2300
2280
Pg/g
101
(21%-178
/o)
130-1,2,3,4,7,
8-HxCDF
1760
2280
Pg/g
77.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2350
2280
Pg/g
103
(26%-123
/o)
130-2,3,4,6,7,
8-HxCDF
2020
2280
Pg/g
88.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2070
2280
Pg/g
90.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2090
2280
Pg/g
91.6
(28%-143
/o)
13C-1,2,3,4,7,8,9-HpCDF
2100
2280
Pg/g
91.9
(26%-138
/o)
3701-2,3,7,8-TCDD
206
228
Pg/g
90.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6315
Lab Sample ID: 6315002
Client Sample: 1613 Soil
Client:
Date Collected:
Date Received:
TETR001
07/08/2014 15:52
07/09/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 15.6
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-135
26378
07/10/2014 20:04
b09jull4a_4-7
26376
09-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.16 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
332
Pg/g
4.66 10.2
40321-76-4
1,2,3,7,8-PeCDD
U
3.33
Pg/g
3.33 51.1
39227-28-6
1,2,3,4,7,8-HxCDD
J
29.7
Pg/g
7.33 51.1
57653-85-7
1,2,3,6,7,8-HxCDD
J
39.8
Pg/g
6.66 51.1
19408-74-3
1,2,3,7,8,9-HxCDD
J
11.0
Pg/g
7.33 51.1
35822-46-9
1,2,3,4,6,7,8-HpCDD
998
Pg/g
29.0 51.1
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12500
Pg/g
70.2 102
51207-31-9
2,3,7,8-TCDF
u
4.86
Pg/g
4.86 10.2
57117-41-6
1,2,3,7,8-PeCDF
J
12.0
Pg/g
4.64 51.1
57117-31-4
2,3,4,7,8-PeCDF
J
6.21
Pg/g
4.13 51.1
70648-26-9
1,2,3,4,7,8-HxCDF
J
28.6
Pg/g
5.47 51.1
57II7.44.9
1,2,3,6,7,8-HxCDF
u
6.43
Pg/g
6.43 51.1
60851-34-5
2,3,4,6,7,8-HxCDF
J
12.8
Pg/g
5.23 51.1
72918-21-9
1,2,3,7,8,9-HxCDF
u
8.45
Pg/g
8.45 51.1
67562-39-4
1,2,3,4,6,7,8-HpCDF
201
Pg/g
6.70 51.1
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
18.5
Pg/g
11.0 51.1
39001-02-0
1,2,3,4,6,7,8,9-OCDF
539
Pg/g
24.1 102
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1630
2040
Pg/g
80.0
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1730
2040
Pg/g
84.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1390
2040
Pg/g
68.0
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1730
2040
Pg/g
84.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1730
2040
Pg/g
84.6
(23%-140%)
13C-OCDD
2750
4080
Pg/g
67.3
(17%-157%)
13C-2,3,7,8-TCDF
1950
2040
Pg/g
95.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1800
2040
Pg/g
88.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1890
2040
Pg/g
92.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1670
2040
Pg/g
81.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1980
2040
Pg/g
97.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2040
Pg/g
93.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1820
2040
Pg/g
89.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1810
2040
Pg/g
88.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1820
2040
Pg/g
89.1
(26%-13 8%)
3701-2,3,7,8-TCDD
173
204
Pg/g
84.6
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 26
-------
Quality Control
Summary
Page 13 of 26
-------
Cape Fear Analytical LLC Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6315
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010883
LCS for batch 26376
12010884
LCSD for batch 26376
12010882
MB for batch 26376
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
81.3
81.2
70.2
78.5
80.6
61.2
99.7
87.8
96.9
78.6
98.4
88.4
85.7
85.9
84.1
87.5
78.0
74.4
60.2
79.2
74.7
56.9
92.5
79.6
87.2
70.8
92.0
82.5
80.3
80.6
77.8
77.3
77.1
78.9
65.5
85.6
78.5
63.1
94.6
85.1
95.0
80.5
102
95.8
87.8
89.8
89.4
81.2
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6315001
SFRA-134
13C-2,3,7,8-TCDD
86.0
(25%-164%)
Page 14 of 26
-------
Cape Fear Analytical LLC Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6315
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6315001
SFRA-134
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
87.2
65.4
85.7
86.1
73.0
101
91.6
101
77.3
103
88.4
90.9
91.6
91.9
90.2
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010885
SFRA-134(631500 IMS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
83.5
86.1
65.2
89.4
81.4
68.5
97.7
89.8
100
76.4
98.6
93.0
93.0
90.4
89.6
87.5
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010886
SFRA-134(6315001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
82.5
89.3
65.3
79.0
82.4
64.1
98.1
94.7
102
78.4
92.3
87.8
86.9
84.6
84.2
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6315002
SFRA-135
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
80.0
84.6
(25%-
(25%-
64%)
81%)
Page 15 of 26
-------
Cape Fear Analytical LLC Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 3 of 3
Surrogate Recovery Report
SDG Number: 6315
Matrix Type: SOLID
Sample ID Client ID
6315002 SFRA-135
Surrogate
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
(%)
Limits
68.0
(32%-
¦141%)
84.5
(28%-
¦130%)
84.6
(23%-
¦140%)
67.3
(17%-
¦157%)
95.6
(24%-
¦169%)
88.2
(24%-
¦185%)
92.3
(21%-
¦178%)
81.7
(26%-
¦152%)
97.0
(26%-
¦123%)
93.4
(28%-
¦136%)
89.4
(29%-
¦147%)
88.6
(28%-
¦143%)
89.1
(26%-
¦138%)
84.6
(35%-
¦197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 16 of 26
-------
Cape Fear Analytical LLC
Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 07/10/2014 15:19 Dilution: 1
Prep Batch ID:26376
Batch ID: 26378
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.1
100
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
104
104
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
106
106
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
108
108
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
120
120
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
97.0
97
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
192
96
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
20.2
101
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
105
105
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
102
102
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
114
114
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
108
108
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
111
111
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
120
120
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
110
110
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
115
115
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
248
124
63-170
SDG Number: 6315
Client ID: LCS for batch 26376
Lab Sample ID: 12010883
Instrument: HRP763
Analyst: JTF
Page 17 of 26
-------
Cape Fear Analytical LLC
Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 07/10/2014 16:06 Dilution: 1
Prep Batch ID:26376
Batch ID: 26378
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.9
105
67-158
4.07
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
106
106
70-142
1.90
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
104
104
70-164
1.56
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
109
109
76-134
0.556
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
120
120
64-162
0.225
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
95.0
95
70-140
2.05
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
191
95.3
78-144
0.709
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.9
99.4
75-158
1.35
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
104
104
80-134
0.954
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
107
107
68-160
5.20
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
112
112
72-134
1.12
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
112
112
84-130
3.90
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
111
111
70-156
0.281
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
120
120
78-130
0.102
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
106
106
82-122
4.02
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
109
109
78-138
5.13
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
247
124
63-170
0.234
0-20
SDG Number: 6315
Client ID: LCSD for batch 26376
Lab Sample ID: 12010884
Instrument: HRP763
Analyst: JTF
Page
18 of 26
-------
Cape Fear Analytical LLC
Report Date: July 11,2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
211
936
59 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1060
U
1150
109
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1060
J
1130
105
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1060
J
1170
107
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1060
J
1220
115
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1060
2460
122
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2110
18700
220 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
211
u
232
110
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1060
J
1110
104
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1060
J
1080
102
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1060
J
1210
112
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1060
J
1170
109
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1060
J
1180
110
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1060
u
1210
115
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1060
1320
106
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1060
J
1180
110
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2110
3360
134 *
70-130
SDG Number: 6315
Client ID: SFRA-134(6315001MS)
Lab Sample ID: 12010885
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 12.3
Analysis Date: 07/10/2014 18:29
Prep Batch ID:26376
Batch ID: 26378
Page 19 of 26
-------
Cape Fear Analytical LLC
Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 12.3
Analysis Date: 07/10/2014 19:17 Dilution: 1
Prep Batch ID:26376
Batch ID: 26378
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
226
1010
89.3
70-130
7.91
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1130
U
1210
107
70-130
5.60
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1130
J
1200
105
70-130
6.13
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1130
J
1230
106
70-130
5.31
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1130
J
1450
127
70-130
16.9
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1130
2240
95.3
70-130
9.03
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2260
17300
143 *
70-130
7.95
0-20
51207-31-9
MSD
2,3,7,8-TCDF
226
U
247
109
70-130
6.29
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1130
J
1180
103
70-130
5.52
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1130
J
1150
101
70-130
5.91
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1130
J
1230
106
70-130
1.88
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1130
J
1290
113
70-130
9.90
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1130
J
1240
109
70-130
5.53
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1130
u
1340
119
70-130
9.79
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1130
1470
112
70-130
10.7
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1130
J
1210
106
70-130
2.76
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2260
3400
127
70-130
1.12
0-20
SDG Number: 6315
Client ID: SFRA-134(6315001MSD)
Lab Sample ID: 12010886
Instrument: HRP763
Analyst: JTF
Page
20 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Method Blank Summary Page ' °' '
SDG Number: 6315
Client:
TETR001
Matrix:
SOLID
Client ID: MB for batch 26376
Instrument ID:
HRP763
Data File:
b09jull4a 4-3
Lab Sample ID: 12010882
Column:
Prep Date:
09-JUL-14
Analyzed:
07/10/14 16:54
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01 LCS for batch 26376
12010883
b09jull4a_4-l
07/10/14
1519
02 LCSD for batch 26376
12010884
b09jull4a_4-2
07/10/14
1606
03 SFRA-134
6315001
b09jull4a_4-4
07/10/14
1741
04 SFRA-134(631500IMS)
12010885
b09jull4a_4-5
07/10/14
1829
05 SFRA-134(6315001MSD)
12010886
b09jull4a_4-6
07/10/14
1917
06 SFRA-135
6315002
b09jull4a_4-7
07/10/14
2004
Page 21 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6315
Client:
TETR001
Project: TETR00114
Lab Sample ID: 12010882
Matrix: SOLID
Client Sample: ^or batch 26376
Client ID:
MB for batch 26376
Prep Basis: As Received
Batch ID:
26378
Method:
EPA Method 1613B
Run Date:
07/10/2014 16:54
Analyst:
JTF
Instrument: HRP763
Data File:
b09jull4a_4-3
Dilution: 1
Prep Batch:
26376
Prep Method:
SW846 3540C
Prep Date:
09-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.638
Pg/g
0.638 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.31
Pg/g
0.310 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.472
Pg/g
0.472 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.442
Pg/g
0.442 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.48
Pg/g
0.480 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.866
Pg/g
0.866 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
1.25
Pg/g
1.25 10.0
51207-31-9
2,3,7,8-TCDF
u
.482
Pg/g
0.482 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.254
Pg/g
0.254 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.21
Pg/g
0.210 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.286
Pg/g
0.286 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.244
Pg/g
0.244 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.296
Pg/g
0.296 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.446
Pg/g
0.446 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.354
Pg/g
0.354 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.562
Pg/g
0.562 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
1.99
Pg/g
1.99 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
154
200
Pg/g
77.1
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
158
200
Pg/g
78.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
131
200
Pg/g
65.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
171
200
Pg/g
85.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
157
200
Pg/g
78.5
(23%-140%)
13C-OCDD
252
400
Pg/g
63.1
(17%-157%)
13C-2,3,7,8-TCDF
189
200
Pg/g
94.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
170
200
Pg/g
85.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
190
200
Pg/g
95.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
161
200
Pg/g
80.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
205
200
Pg/g
102
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
192
200
Pg/g
95.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
176
200
Pg/g
87.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
180
200
Pg/g
89.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
179
200
Pg/g
89.4
(26%-13 8%)
3701-2,3,7,8-TCDD
16.2
20.0
Pg/g
81.2
(35%-197%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 22 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6315
Lab Sample ID: 12010883
Client Sample: ^or batch 26376
Client ID: LCS for batch 26376
Batch ID: 26378
Run Date: 07/10/2014 15:19
Data File: b09jull4a_4-l
Prep Batch: 26376
Prep Date: 09-JUL-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.1
Pg/g
0.606 1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.576 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
106
Pg/g
1.12 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
108
Pg/g
1.07 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
120
Pg/g
1.16 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
97.0
Pg/g
1.74 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
192
Pg/g
3.88 10.0
51207-31-9
2,3,7,8-TCDF
20.2
Pg/g
0.368 1.00
57117-41-6
1,2,3,7,8-PeCDF
105
Pg/g
0.758 5.00
57117-31-4
2,3,4,7,8-PeCDF
102
Pg/g
0.686 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
114
Pg/g
1.18 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
108
Pg/g
0.998 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
111
Pg/g
1.16 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
120
Pg/g
1.85 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
110
Pg/g
1.30 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
115
Pg/g
2.22 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
248
Pg/g
3.16 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
163
200
Pg/g
81.3
(20%-175%)
13C-1,2,3,7,8-
PeCDD
162
200
Pg/g
81.2
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
140
200
Pg/g
70.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
157
200
Pg/g
78.5
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
161
200
Pg/g
80.6
(22%-166%)
13C-OCDD
245
400
Pg/g
61.2
(13%-199%)
13C-2,3,7,8-TCDF
199
200
Pg/g
99.7
(22%-152%)
13C-1,2,3,7,8-
PeCDF
176
200
Pg/g
87.8
(21%-192%)
130-2,3,4,7,8-
PeCDF
194
200
Pg/g
96.9
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
157
200
Pg/g
78.6
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
197
200
Pg/g
98.4
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
177
200
Pg/g
88.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
171
200
Pg/g
85.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
172
200
Pg/g
85.9
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
168
200
Pg/g
84.1
(20%-186%)
3701-2,3,7,8-TCDD
17.5
20.0
Pg/g
87.5
(31 %-191%)
Comments:
Page 23 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6315
12010884
QC for batch 26376
LCSD for batch 26376
26378
07/10/2014 16:06
b09jull4a 4-2
26376
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
09-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.9
Pg/g
0.612
1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.534
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
104
Pg/g
1.46
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
109
Pg/g
1.41
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
120
Pg/g
1.51
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.0
Pg/g
1.98
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
191
Pg/g
5.70
10.0
51207-31-9
2,3,7,8-TCDF
19.9
Pg/g
0.472
1.00
57117-41-6
1,2,3,7,8-PeCDF
104
Pg/g
0.972
5.00
57117-31-4
2,3,4,7,8-PeCDF
107
Pg/g
0.804
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
112
Pg/g
2.28
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
112
Pg/g
2.16
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
111
Pg/g
2.34
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
120
Pg/g
3.94
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
106
Pg/g
1.34
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
109
Pg/g
2.26
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
247
Pg/g
5.92
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
156
200
Pg/g
78.0
(20%-175%)
13C-1,2,3,7,8-PeCDD
149
200
Pg/g
74.4
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
120
200
Pg/g
60.2
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
158
200
Pg/g
79.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
149
200
Pg/g
74.7
(22%-166%)
13C-OCDD
228
400
Pg/g
56.9
(13%-199%)
13C-2,3,7,8-TCDF
185
200
Pg/g
92.5
(22%-152%)
13C-1,2,3,7,8-PeCDF
159
200
Pg/g
79.6
(21%-192%)
13C-2,3,4,7,8-PeCDF
174
200
Pg/g
87.2
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
142
200
Pg/g
70.8
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
184
200
Pg/g
92.0
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
165
200
Pg/g
82.5
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.3
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
161
200
Pg/g
80.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
156
200
Pg/g
77.8
(20%-186%)
37Cl-2,3,7,8-TCDD
15.5
20.0
Pg/g
77.3
(31 %-191%)
Comments:
Page 24 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6315
12010885
QC for batch 26376
SFRA-134(6315001MS)
26378
07/10/2014 18:29
b09jull4a 4-5
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/08/2014 15:48
07/09/2014 09:50
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
12.3
Dry Weight
HRP763
1
Prep Batch:
26376
Prep Method:
SW846 3540C
Prep Date:
09-JUL-14
Prep Aliquot:
1.08 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
936
Pg/g
7.94
10.6
40321-76-4
1,2,3,7,8-PeCDD
1150
Pg/g
8.20
52.8
39227-28-6
1,2,3,4,7,8-HxCDD
1130
Pg/g
14.7
52.8
57653-85-7
1,2,3,6,7,8-HxCDD
1170
Pg/g
14.2
52.8
19408-74-3
1,2,3,7,8,9-HxCDD
1220
Pg/g
15.2
52.8
35822-46-9
1,2,3,4,6,7,8-HpCDD
2460
Pg/g
26.0
52.8
3268-87-9
1,2,3,4,6,7,8,9-OCDD
18700
Pg/g
81.8
106
51207-31-9
2,3,7,8-TCDF
232
Pg/g
6.44
10.6
57117-41-6
1,2,3,7,8-PeCDF
1110
Pg/g
11.3
52.8
57117-31-4
2,3,4,7,8-PeCDF
1080
Pg/g
9.86
52.8
70648-26-9
1,2,3,4,7,8-HxCDF
1210
Pg/g
17.6
52.8
57II7.44.9
1,2,3,6,7,8-HxCDF
1170
Pg/g
15.4
52.8
60851-34-5
2,3,4,6,7,8-HxCDF
1180
Pg/g
17.4
52.8
72918-21-9
1,2,3,7,8,9-HxCDF
1210
Pg/g
24.9
52.8
67562-39-4
1,2,3,4,6,7,8-HpCDF
1320
Pg/g
15.0
52.8
55673-89-7
1,2,3,4,7,8,9-HpCDF
1180
Pg/g
25.3
52.8
39001-02-0
1,2,3,4,6,7,8,9-OCDF
3360
Pg/g
44.4
106
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1760
2110
Pg/g
83.5
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1820
2110
Pg/g
86.1
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1380
2110
Pg/g
65.2
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1890
2110
Pg/g
89.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1720
2110
Pg/g
81.4
(23%-140%)
13C-OCDD
2890
4220
Pg/g
68.5
(17%-157%)
13C-2,3,7,8-TCDF
2060
2110
Pg/g
97.7
(24%-169%)
13C-1,2,3,7,8-PeCDF
1900
2110
Pg/g
89.8
(24%-185%)
13C-2,3,4,7,8-PeCDF
2110
2110
Pg/g
100
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1610
2110
Pg/g
76.4
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2080
2110
Pg/g
98.6
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1970
2110
Pg/g
93.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1960
2110
Pg/g
93.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1910
2110
Pg/g
90.4
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1890
2110
Pg/g
89.6
(26%-13 8%)
37Cl-2,3,7,8-TCDD
185
211
Pg/g
87.5
(35%-197%)
Comments:
Page 25 of 26
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6315
12010886
QC for batch 26376
SFRA-134(6315001MSD)
26378
07/10/2014 19:17
b09jull4a 4-6
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/08/2014 15:48
07/09/2014 09:50
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
12.3
Dry Weight
HRP763
1
Prep Batch:
26376
Prep Method:
SW846 3540C
Prep Date:
09-JUL-14
Prep Aliquot:
1.01 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
1010
Pg/g
7.34
11.3
40321-76-4
1,2,3,7,8-PeCDD
1210
Pg/g
7.14
56.5
39227-28-6
1,2,3,4,7,8-HxCDD
1200
Pg/g
18.9
56.5
57653-85-7
1,2,3,6,7,8-HxCDD
1230
Pg/g
18.9
56.5
19408-74-3
1,2,3,7,8,9-HxCDD
1450
Pg/g
19.9
56.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
2240
Pg/g
31.6
56.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
17300
Pg/g
80.4
113
51207-31-9
2,3,7,8-TCDF
247
Pg/g
6.19
11.3
57117-41-6
1,2,3,7,8-PeCDF
1180
Pg/g
9.08
56.5
57117-31-4
2,3,4,7,8-PeCDF
1150
Pg/g
8.15
56.5
70648-26-9
1,2,3,4,7,8-HxCDF
1230
Pg/g
13.5
56.5
57II7.44.9
1,2,3,6,7,8-HxCDF
1290
Pg/g
11.8
56.5
60851-34-5
2,3,4,6,7,8-HxCDF
1240
Pg/g
14.3
56.5
72918-21-9
1,2,3,7,8,9-HxCDF
1340
Pg/g
20.1
56.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
1470
Pg/g
12.7
56.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
1210
Pg/g
20.9
56.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
3400
Pg/g
32.8
113
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1860
2260
Pg/g
82.5
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2020
2260
Pg/g
89.3
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1470
2260
Pg/g
65.3
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1780
2260
Pg/g
79.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1860
2260
Pg/g
82.4
(23%-140%)
13C-OCDD
2900
4520
Pg/g
64.1
(17%-157%)
13C-2,3,7,8-TCDF
2220
2260
Pg/g
98.1
(24%-169%)
13C-1,2,3,7,8-PeCDF
2140
2260
Pg/g
94.7
(24%-185%)
13C-2,3,4,7,8-PeCDF
2310
2260
Pg/g
102
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1770
2260
Pg/g
78.4
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2080
2260
Pg/g
92.3
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1980
2260
Pg/g
87.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1960
2260
Pg/g
86.9
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1910
2260
Pg/g
84.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1900
2260
Pg/g
84.2
(26%-13 8%)
37Cl-2,3,7,8-TCDD
203
226
Pg/g
89.8
(35%-197%)
Comments:
Page 26 of 26
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
July 11. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6316
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 09, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of21
problem solved
-------
Page: |_
Project #:
CFA Quote #: __
C'OC'Nurnber
PO Number: ,
Of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: J/j o) Ifi f
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
'Client Nanre:
*
Phone §:
~sn an
Sample Analysis Requested l5' (Fill in the number of containers for each test)
3
p
Ot
(1"
c
Address:
Collected by:
Send Results To,
K
t>6t
5ft
•sgsfi;
Uty
m
Sample ID
* For composites - indicate start and stop date/time
*Date Collected
(mm-dd-yy)
*Time
Collected
(Military)
(hhmm)
QC Code
(«
Field
Filtered01
Pf hr - 13 ^ '^fS
Sample
Matrixw
vs>
<— Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC ^ .
A <\fV Ta I
JJlSL
1557-
mmmrnessstSmm HE
V
,S30
xZ
3^ y ISrni.wtm
~7l~.Ueyt 4vCh£iV
1S3*2-"-
1
I?fe4 131 -fa
/
I a/ft
i1ljL?L^^ZEE
taof
Zi
~Z/~~ UjL
f \ Specify: vpfi>bteit&SttR?iiarge)
TAT Requested: Normal:
Rush:
Fax Results:
Yes
I
Circle Deliverable: CofA / QC Summary / Level 1 / Level 2 S\
V Level 4
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
Ca\A^ft^Mxis
Sample, Collection Twne*Zone
EasterTPX Pacific
"ventral^ Other _
-MStfntain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Date
Time
IfclS
Received by (signed)
Date
Time
MUtiH 0C{50
CFA PM;
Method of Shipment:
F&kj(
Date Shipped: *" /
Airbill #;
3 IS7 Qgs
3
Airbill it:
],) Chain of Custody Number*5 Client Determined r..^
2.) QC Codes; N = Normal Sample, TB - Trip Blank, FtT» Field Duplicate, IB = Equipment Blank, MS - Matrix Spike Sample, MSI) - Matrix Spike Duplicate Sample, G - Grab, C - Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: DW=Drinking Water. G W-Grmindwater. SW=Surface Water, WW=Was!e "Waterf W=Water, ML-Misc Liquid,SO=Soil, SD=Sediment, SL=Siudge, SS=Soiid Waste, 0=Oii, F=Fiiter, P=Wip», lJ=Urine, F=Fecai, N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.e<8290B, 1668B) and number of containers provided for each (Le.8290B - 3, NS6SB -1).
6.) Preservative Type: H A = Hydrochloric Acid, Nl - Nitric Acid, Sfl | Sodium Hydroxide, SA - Sulfuric Acid, AA = Ascorbic Acid, HX - Hexane, ST - Sodium Thiosulfaie, If no preservative is added - leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
pdy Seal Intact?
VESi, NO
Zboler Temp:
5-Tc
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
diet: -"TEITR_
Work Order: £
Shipping Company: L^i
Date/Time Received: Lf Q^Q
Suspected Hazard Information
Yes
NA
No
Shipped as DOT Hazardous?
Samples identified as Foreign Soil?
Air Sample Receipt Specifics
Yes
NA
No
Air sample in shipment?
DOE Site Sample Packages
Yes
NA
No*
Screened <0.5 mR/hr?
Samples < 2x background?
* Notify RSO of any responses in this column Immediately.
Air Witness:
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and seated?
Circle Applicable:
seals broken damaged container leaking container other{describe)
2
Chain of Custody documents included
with shipment?
/
3
Samples requiring cold preservation
within 0-6°C?
I
/
Ei€S?Pvation Method:
ice bags blue ice dry ice none other (describe)
4
Aqueous samples found to have visible
solids?
Sample IDs, containers affected;
5
Samples requiring chemical
preservation at proper pH?
/
Sample IDs, containers affected and pH observed:
If preservative added, Lot#;
6
Samples requiring preservation have
no residual chlorine?
V*
/
Sample IDs,containers affected:
If preservative added, lot#:
7
Samples received within holding time?
X"
Sample IDs, tests affected:
8
Sample IDs on COC match IDs on
containers?
/
Sample IDs, containers affected:
9
Date & time of COC match date & time
on containers?
W
/
Sample IDs, containers affected:
10
Number of containers received match
number indicated on COC?
Sample IDs, containers affected:
11
COC form is properly signed in
relinquished/received sections?
i/
Comments:
Checklist performed by: Initials: — Date: U l\J lA-l— '
Page 3 of21
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of21
-------
Case Narrative
Page 5 of21
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6316
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26378
Clean Up Batch Number: 26377
Extraction Batch Number: 26376
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6316001 SFRA-136
6316002 SFRA-137
12010882 Method Blank (MB)
12010883 Laboratory Control Sample (LCS)
12010884 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of21
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 26378.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26378.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Page 7 of21
-------
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of21
-------
Sample Data Summary
Page 9 of21
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6316 CFA Work Order: 6316
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 11 JUL 2014 Title: Data Validator
Page 10 of 21
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6316
Lab Sample ID: 6316001
Client Sample: 1613 Soil
Client:
Date Collected:
Date Received:
TETR001
07/08/2014 15:30
07/09/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 16.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-136
26378
07/10/2014 20:52
b09jull4a_4-8
26376
09-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.15 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
294
Pg/g
4.55 10.4
40321-76-4
1,2,3,7,8-PeCDD
J
4.26
Pg/g
3.43 52.2
39227-28-6
1,2,3,4,7,8-HxCDD
J
11.7
Pg/g
7.23 52.2
57653-85-7
1,2,3,6,7,8-HxCDD
J
26.2
Pg/g
6.50 52.2
19408-74-3
1,2,3,7,8,9-HxCDD
J
13.2
Pg/g
7.19 52.2
35822-46-9
1,2,3,4,6,7,8-HpCDD
697
Pg/g
29.9 52.2
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9870
Pg/g
61.2 104
51207-31-9
2,3,7,8-TCDF
U
4.53
Pg/g
4.53 10.4
57117-41-6
1,2,3,7,8-PeCDF
J
10.9
Pg/g
3.78 52.2
57117-31-4
2,3,4,7,8-PeCDF
J
4.12
Pg/g
3.20 52.2
70648-26-9
1,2,3,4,7,8-HxCDF
J
21.2
Pg/g
4.03 52.2
57II7.44.9
1,2,3,6,7,8-HxCDF
J
6.79
Pg/g
3.66 52.2
60851-34-5
2,3,4,6,7,8-HxCDF
J
7.62
Pg/g
4.14 52.2
72918-21-9
1,2,3,7,8,9-HxCDF
u
6.43
Pg/g
6.43 52.2
67562-39-4
1,2,3,4,6,7,8-HpCDF
164
Pg/g
6.58 52.2
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
16.5
Pg/g
10.0 52.2
39001-02-0
1,2,3,4,6,7,8,9-OCDF
495
Pg/g
17.8 104
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1790
2090
Pg/g
85.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1800
2090
Pg/g
86.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1390
2090
Pg/g
66.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1780
2090
Pg/g
85.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1870
2090
Pg/g
89.4
(23%-140%)
13C-OCDD
3040
4180
Pg/g
72.7
(17%-157%)
13C-2,3,7,8-TCDF
2200
2090
Pg/g
105
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1910
2090
Pg/g
91.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
2020
2090
Pg/g
96.9
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1660
2090
Pg/g
79.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2110
2090
Pg/g
101
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1980
2090
Pg/g
94.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1900
2090
Pg/g
90.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1880
2090
Pg/g
90.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1980
2090
Pg/g
94.9
(26%-13 8%)
3701-2,3,7,8-TCDD
203
209
Pg/g
97.0
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 21
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6316
Lab Sample ID: 6316002
Client Sample: 1613 Soil
Client:
Date Collected:
Date Received:
TETR001
07/08/2014 15:32
07/09/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 15.8
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-137
26378
07/10/2014 21:40
b09jull4a_4-9
26376
09-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.19 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
238
Pg/g
4.97 9.98
40321-76-4
1,2,3,7,8-PeCDD
U
4.27
Pg/g
4.27 49.9
39227-28-6
1,2,3,4,7,8-HxCDD
J
22.7
Pg/g
6.98 49.9
57653-85-7
1,2,3,6,7,8-HxCDD
J
37.7
Pg/g
6.31 49.9
19408-74-3
1,2,3,7,8,9-HxCDD
J
13.9
Pg/g
6.94 49.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
1110
Pg/g
22.7 49.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14300
Pg/g
62.5 99.8
51207-31-9
2,3,7,8-TCDF
u
5.49
Pg/g
5.49 9.98
57117-41-6
1,2,3,7,8-PeCDF
J
11.2
Pg/g
4.27 49.9
57117-31-4
2,3,4,7,8-PeCDF
J
6.35
Pg/g
3.57 49.9
70648-26-9
1,2,3,4,7,8-HxCDF
J
27.7
Pg/g
6.80 49.9
57II7.44.9
1,2,3,6,7,8-HxCDF
J
8.20
Pg/g
6.25 49.9
60851-34-5
2,3,4,6,7,8-HxCDF
J
11.2
Pg/g
6.68 49.9
72918-21-9
1,2,3,7,8,9-HxCDF
u
10.1
Pg/g
10.1 49.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
224
Pg/g
8.08 49.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
17.7
Pg/g
12.5 49.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
839
Pg/g
24.7 99.8
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1450
2000
Pg/g
72.8
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1430
2000
Pg/g
71.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1150
2000
Pg/g
57.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1460
2000
Pg/g
73.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1530
2000
Pg/g
76.5
(23%-140%)
13C-OCDD
2450
3990
Pg/g
61.3
(17%-157%)
13C-2,3,7,8-TCDF
1730
2000
Pg/g
86.5
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1510
2000
Pg/g
75.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
1620
2000
Pg/g
81.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1400
2000
Pg/g
70.4
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1730
2000
Pg/g
86.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1660
2000
Pg/g
83.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1640
2000
Pg/g
82.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1590
2000
Pg/g
79.7
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1570
2000
Pg/g
78.6
(26%-13 8%)
3701-2,3,7,8-TCDD
156
200
Pg/g
78.2
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 21
-------
Quality Control
Summary
Page 13 of 21
-------
Cape Fear Analytical LLC Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6316
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010883
LCS for batch 26376
12010884
LCSD for batch 26376
12010882
MB for batch 26376
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
81.3
81.2
70.2
78.5
80.6
61.2
99.7
87.8
96.9
78.6
98.4
88.4
85.7
85.9
84.1
87.5
78.0
74.4
60.2
79.2
74.7
56.9
92.5
79.6
87.2
70.8
92.0
82.5
80.3
80.6
77.8
77.3
77.1
78.9
65.5
85.6
78.5
63.1
94.6
85.1
95.0
80.5
102
95.8
87.8
89.8
89.4
81.2
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6316001
SFRA-136
13C-2,3,7,8-TCDD
85.5
(25%-164%)
Page 14 of 21
-------
Cape Fear Analytical LLC Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6316
Matrix Type: SOLID
Sample ID Client ID
6316001 SFRA-136
6316002 SFRA-137
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
86.4 (25%-181%)
66.4 (32%-141%)
85.1 (28%-130%)
89.4 (23%-140%)
72.7 (17%-15 7%)
105 (24%-169%)
91.2 (24%-185%)
96.9 (21%-178%)
79.3 (26%-152%)
101 (26%-123%)
94.8 (28%-13 6%)
90.8 (29%-147%)
90.0 (28%-143%)
94.9 (26%-13 8%)
97.0 (35%-197%)
72.8 (25%-164%)
71.4 (25%-181%)
57.9 (32%-141%)
73.0 (28%-130%)
76.5 (23%-140%)
61.3 (17%-15 7%)
86.5 (24%-169%)
75.8 (24%-185%)
81.3 (21%-178%)
70.4 (26%-152%)
86.7 (26%-123%)
83.4 (28%-13 6%)
82.4 (29%-147%)
79.7 (28%-143%)
78.6 (26%-13 8%)
78.2 (35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 15 of 21
-------
Cape Fear Analytical LLC
Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 07/10/2014 15:19 Dilution: 1
Prep Batch ID:26376
Batch ID: 26378
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.1
100
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
104
104
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
106
106
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
108
108
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
120
120
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
97.0
97
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
192
96
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
20.2
101
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
105
105
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
102
102
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
114
114
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
108
108
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
111
111
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
120
120
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
110
110
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
115
115
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
248
124
63-170
SDG Number: 6316
Client ID: LCS for batch 26376
Lab Sample ID: 12010883
Instrument: HRP763
Analyst: JTF
Page 16 of 21
-------
Cape Fear Analytical LLC
Report Date: July 11,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 07/10/2014 16:06 Dilution: 1
Prep Batch ID:26376
Batch ID: 26378
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.9
105
67-158
4.07
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
106
106
70-142
1.90
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
104
104
70-164
1.56
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
109
109
76-134
0.556
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
120
120
64-162
0.225
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
95.0
95
70-140
2.05
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
191
95.3
78-144
0.709
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
19.9
99.4
75-158
1.35
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
104
104
80-134
0.954
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
107
107
68-160
5.20
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
112
112
72-134
1.12
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
112
112
84-130
3.90
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
111
111
70-156
0.281
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
120
120
78-130
0.102
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
106
106
82-122
4.02
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
109
109
78-138
5.13
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
247
124
63-170
0.234
0-20
SDG Number: 6316
Client ID: LCSD for batch 26376
Lab Sample ID: 12010884
Instrument: HRP763
Analyst: JTF
Page
17 of 21
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Method Blank Summary
Page 1 of 1
SDG Number:
Client ID:
Lab Sample ID: 12010882
Column:
6316
MB for batch 26376
Client: TETR001
Instrument ID: HRP763
Prep Date: 09-JUL-14
Matrix: SOLID
Data File: b09jull4a 4-3
Analyzed: 07/10/1416:54
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26376
12010883
b09jull4a_4-l
07/10/14
1519
02
LCSD for batch 26376
12010884
b09jull4a_4-2
07/10/14
1606
03
SFRA-136
6316001
b09jull4a_4-8
07/10/14
2052
04
SFRA-137
6316002
b09jull4a_4-9
07/10/14
2140
Page 18 of 21
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number: 6316
Client:
TETR001
Project: TETR00114
Lab Sample ID: 12010882
Matrix: SOLID
Client Sample: ^or batch 26376
Client ID:
MB for batch 26376
Prep Basis: As Received
Batch ID:
26378
Method:
EPA Method 1613B
Run Date:
07/10/2014 16:54
Analyst:
JTF
Instrument: HRP763
Data File:
b09jull4a_4-3
Dilution: 1
Prep Batch:
26376
Prep Method:
SW846 3540C
Prep Date:
09-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.638
Pg/g
0.638 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.31
Pg/g
0.310 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.472
Pg/g
0.472 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.442
Pg/g
0.442 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.48
Pg/g
0.480 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.866
Pg/g
0.866 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
1.25
Pg/g
1.25 10.0
51207-31-9
2,3,7,8-TCDF
u
.482
Pg/g
0.482 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.254
Pg/g
0.254 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.21
Pg/g
0.210 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.286
Pg/g
0.286 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.244
Pg/g
0.244 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.296
Pg/g
0.296 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.446
Pg/g
0.446 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.354
Pg/g
0.354 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.562
Pg/g
0.562 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
1.99
Pg/g
1.99 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
154
200
Pg/g
77.1
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
158
200
Pg/g
78.9
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
131
200
Pg/g
65.5
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
171
200
Pg/g
85.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
157
200
Pg/g
78.5
(23%-140%)
13C-OCDD
252
400
Pg/g
63.1
(17%-157%)
13C-2,3,7,8-TCDF
189
200
Pg/g
94.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
170
200
Pg/g
85.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
190
200
Pg/g
95.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
161
200
Pg/g
80.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
205
200
Pg/g
102
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
192
200
Pg/g
95.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
176
200
Pg/g
87.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
180
200
Pg/g
89.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
179
200
Pg/g
89.4
(26%-13 8%)
3701-2,3,7,8-TCDD
16.2
20.0
Pg/g
81.2
(35%-197%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 21
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6316
Lab Sample ID: 12010883
Client Sample: ^or batch 26376
Client ID: LCS for batch 26376
Batch ID: 26378
Run Date: 07/10/2014 15:19
Data File: b09jull4a_4-l
Prep Batch: 26376
Prep Date: 09-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.1
Pg/g
0.606 1.00
40321-76-4
1,2,3,7,8-PeCDD
104
Pg/g
0.576 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
106
Pg/g
1.12 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
108
Pg/g
1.07 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
120
Pg/g
1.16 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
97.0
Pg/g
1.74 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
192
Pg/g
3.88 10.0
51207-31-9
2,3,7,8-TCDF
20.2
Pg/g
0.368 1.00
57117-41-6
1,2,3,7,8-PeCDF
105
Pg/g
0.758 5.00
57117-31-4
2,3,4,7,8-PeCDF
102
Pg/g
0.686 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
114
Pg/g
1.18 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
108
Pg/g
0.998 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
111
Pg/g
1.16 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
120
Pg/g
1.85 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
110
Pg/g
1.30 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
115
Pg/g
2.22 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
248
Pg/g
3.16 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
163
200
Pg/g
81.3
(20%-175%)
13C-1,2,3,7,8-
PeCDD
162
200
Pg/g
81.2
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
140
200
Pg/g
70.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
157
200
Pg/g
78.5
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
161
200
Pg/g
80.6
(22%-166%)
13C-OCDD
245
400
Pg/g
61.2
(13%-199%)
13C-2,3,7,8-TCDF
199
200
Pg/g
99.7
(22%-152%)
13C-1,2,3,7,8-
PeCDF
176
200
Pg/g
87.8
(21%-192%)
130-2,3,4,7,8-
PeCDF
194
200
Pg/g
96.9
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
157
200
Pg/g
78.6
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
197
200
Pg/g
98.4
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
177
200
Pg/g
88.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
171
200
Pg/g
85.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
172
200
Pg/g
85.9
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
168
200
Pg/g
84.1
(20%-186%)
3701-2,3,7,8-TCDD
17.5
20.0
Pg/g
87.5
(31 %-191%)
Comments:
Page 20 of 21
-------
Cape Fear Analytical LLC
Report Date:
July 11, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6316
12010884
QC for batch 26376
LCSD for batch 26376
26378
07/10/2014 16:06
b09jull4a 4-2
26376
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
09-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.9
Pg/g
0.612
1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.534
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
104
Pg/g
1.46
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
109
Pg/g
1.41
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
120
Pg/g
1.51
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.0
Pg/g
1.98
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
191
Pg/g
5.70
10.0
51207-31-9
2,3,7,8-TCDF
19.9
Pg/g
0.472
1.00
57117-41-6
1,2,3,7,8-PeCDF
104
Pg/g
0.972
5.00
57117-31-4
2,3,4,7,8-PeCDF
107
Pg/g
0.804
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
112
Pg/g
2.28
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
112
Pg/g
2.16
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
111
Pg/g
2.34
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
120
Pg/g
3.94
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
106
Pg/g
1.34
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
109
Pg/g
2.26
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
247
Pg/g
5.92
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
156
200
Pg/g
78.0
(20%-175%)
13C-1,2,3,7,8-PeCDD
149
200
Pg/g
74.4
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
120
200
Pg/g
60.2
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
158
200
Pg/g
79.2
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
149
200
Pg/g
74.7
(22%-166%)
13C-OCDD
228
400
Pg/g
56.9
(13%-199%)
13C-2,3,7,8-TCDF
185
200
Pg/g
92.5
(22%-152%)
13C-1,2,3,7,8-PeCDF
159
200
Pg/g
79.6
(21%-192%)
13C-2,3,4,7,8-PeCDF
174
200
Pg/g
87.2
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
142
200
Pg/g
70.8
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
184
200
Pg/g
92.0
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
165
200
Pg/g
82.5
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.3
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
161
200
Pg/g
80.6
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
156
200
Pg/g
77.8
(20%-186%)
37Cl-2,3,7,8-TCDD
15.5
20.0
Pg/g
77.3
(31 %-191%)
Comments:
Page 21 of 21
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
July 16. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6328
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 11, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 33
problem solved
-------
Page; I
Project #:
CFA Quote U:
COC Number"': _
PD Number;
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number:
Cape Fear Analytical, LLC
3306 Kitty Hawk RA Suite 120
Wilmington, NC 28405
Phone:(910)795-0421
Client Name:
l eckr
Phone #:
3/¥ S77
Sample Analysis Requested (Fill in the number of containers for each test)
'°Jea/steN»»e: ^ /4-#An/i
Preservative Type (6)
is 'Address:
*2-5 Fosm
kj Collected by :
u»
Send Results To:
Sample ID
* For composites - indicate start and stop date/time
*Date Collected
(mm-dd-yy)
~Time
Collected
(Military)
(hhmm)
QC Code
(2}
Fteld
Filtered,3)
Sample
Matrix14*
M-
m*-
55
A.
Comments
Note: extra sample is
required for sample
specific QC
v/
Jt.
t~rCA-
TAT Requested: Normal:
Rush:
Specify
¦ubject to Surcharge)
Fax Results:
Yes
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
^ ^Po $S tW"£—
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2
Sample Collection'
/ Level 4
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed) Date Time
'SM. i-tb-H J*?6
Received by (signed) Date
Time
\CtpJ&- (yuuM' b%0
CFA PM:
Method of Shipment:
Pate Shipped:
~7-/ 6-/V
Atun, 0
Airbill #:
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N = Normal Sample, TB - Trip Blank, FD = Field Duplicate, KB = Equipment Blank, MS = Matrix Spike Sample, MSD = Matrix Spike Duplicate Sample,G - Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- V - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: DW Drinking Water, GW-Groundwater, SW Surface Water, WW=Waste Water, W=Water, ML-Misc Liquid,SO-Soil, SD-Sediment, SL-Sludge, SS-Soiid Waste, O-Oil, F-Filter, P Wipe. C=Uriiw, F=Fecal, N=Nasa!
5-) Sample Analysis Requested: Analytical method requested (LeB290B, 1668B) and number of containers provided for each (i.e. 8200S -3,1668B-1),
6.) Preservative Type: HA = Hydrochloric Acid, NI = Nitric Acid, SH - Sodium Hydroxide, SA - Sulfuric Acid, AA = Ascorbic Acid.HX = Hexane, ST - Sodium Thiosulfate, If no preservative is added - leave field Wank
WHITE - LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
CuHlbdy Seal Intact?
(res) no
ooler Temp:
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client: "^E^Ttf
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 33
-------
Case Narrative
Page 5 of 33
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6328
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26395
Clean Up Batch Number: 26394
Extraction Batch Number: 26393
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6328001
SFRA-138
6328002
SFRA-139
6328003
SFRA-140
6328004
SFRA-141
6328005
SFRA-142
6328006
SFRA-143
12010900
Method Blank (MB)
12010901
Laboratory Control Sample (LCS)
12010902
Laboratory Control Sample Duplicate (LCSD)
12010903
6328001 (SFRA-138) Matrix Spike (MS)
12010904
6328001 (SFRA-138) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Page 6 of 33
-------
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6328001 (SFRA-138) - Batch 26395 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Recovery Statement
Two MS recoveries for this SDG were not within the acceptance limits. The failures confirm in
the matrix spike duplicate and can be attributed to matrix interference. 12010903 (SFRA-138)
and 12010904 (SFRA-138) - Batch 26395.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Page 7 of 33
-------
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26395.
Sample Dilutions
Samples 6328002 (SFRA-139), 6328003 (SFRA-140), 6328004 (SFRA-141), 6328005 (SFRA-
142) and 6328006 (SFRA-143)- Batch 26395 were diluted due to the presence of over-range
target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 33
-------
Sample Data Summary
Page 9 of 33
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6328 CFA Work Order: 6328
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 16 JUL 2014 Title: Data Validator
Page 10 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6328
Lab Sample ID: 6328001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/10/2014 14:23
07/11/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 10
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-138
26395
07/14/2014 21:43
bl4jull4a-ll
26393
ll-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.09 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
731
Pg/g
5.10 10.2
40321-76-4
1,2,3,7,8-PeCDD
U
3.43
Pg/g
3.43 51.0
39227-28-6
1,2,3,4,7,8-HxCDD
J
7.46
Pg/g
6.10 51.0
57653-85-7
1,2,3,6,7,8-HxCDD
J
10.0
Pg/g
6.44 51.0
19408-74-3
1,2,3,7,8,9-HxCDD
u
11.6
Pg/g
11.6 51.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
429
Pg/g
11.1 51.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
21600
Pg/g
3850 102
51207-31-9
2,3,7,8-TCDF
J
6.08
Pg/g
3.89 10.2
57117-41-6
1,2,3,7,8-PeCDF
J
1.33
Pg/g
0.512 51.0
57117-31-4
2,3,4,7,8-PeCDF
J
1.45
Pg/g
0.477 51.0
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.06
Pg/g
2.06 51.0
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.99
Pg/g
1.99 51.0
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.1
Pg/g
2.10 51.0
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.16
Pg/g
3.16 51.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
7.26
Pg/g
3.22 51.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
5.16
Pg/g
5.16 51.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
21.9
Pg/g
21.9 102
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1760
2040
Pg/g
86.3
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
2190
2040
Pg/g
108
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1790
2040
Pg/g
87.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1860
2040
Pg/g
91.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2260
2040
Pg/g
111
(23%-140%)
13C-OCDD
1660
4080
Pg/g
40.7
(17%-157%)
13C-2,3,7,8-TCDF
2100
2040
Pg/g
103
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2060
2040
Pg/g
101
(24%-185%)
130-2,3,4,7,8-
PeCDF
2190
2040
Pg/g
107
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2070
2040
Pg/g
101
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2050
2040
Pg/g
101
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
2070
2040
Pg/g
102
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2020
2040
Pg/g
99.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2140
2040
Pg/g
105
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2170
2040
Pg/g
106
(26%-13 8%)
3701-2,3,7,8-TCDD
214
204
Pg/g
105
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 33
-------
Cape Fear Analytical LLC
Report Date: July 16, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6328
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6328002
Date Collected:
07/10/2014 14:26
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
07/11/2014 09:50
%Moisture:
9.3
Client ID:
SFRA-139
Prep Basis:
Dry Weight
Batch ID:
26395
Method:
EPA Method 1613B
Run Date:
07/16/2014 09:09
Analyst:
JTF
Instrument:
HRP750
Data File:
A16JUL14A-4
Dilution:
5
Prep Batch:
26393
Prep Method:
SW846 3540C
Prep Date:
ll-JUL-14
Prep Aliquot:
1.65 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
51.3
Pg/g
9.30
33.4
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6328
Lab Sample ID: 6328002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/10/2014 14:26
07/11/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 9.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-139
26395
07/15/201413:11
bl4jull4a_3-2
26393
ll-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.65 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
8340
Pg/g
16.3 33.4
40321-76-4
1,2,3,7,8-PeCDD
J
12.2
Pg/g
7.65 167
39227-28-6
1,2,3,4,7,8-HxCDD
U
17.4
Pg/g
17.4 167
57653-85-7
1,2,3,6,7,8-HxCDD
J
60.1
Pg/g
17.1 167
19408-74-3
1,2,3,7,8,9-HxCDD
J
34.2
Pg/g
18.2 167
35822-46-9
1,2,3,4,6,7,8-HpCDD
1070
Pg/g
20.0 167
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14100
Pg/g
66.3 334
51207-31-9
2,3,7,8-TCDF
63.2
Pg/g
18.7 33.4
57117-41-6
1,2,3,7,8-PeCDF
u
7.92
Pg/g
7.92 167
57117-31-4
2,3,4,7,8-PeCDF
J
9.77
Pg/g
7.83 167
70648-26-9
1,2,3,4,7,8-HxCDF
J
16.7
Pg/g
8.84 167
57II7.44.9
1,2,3,6,7,8-HxCDF
J
41.2
Pg/g
8.48 167
60851-34-5
2,3,4,6,7,8-HxCDF
J
17.8
Pg/g
9.41 167
72918-21-9
1,2,3,7,8,9-HxCDF
u
13.9
Pg/g
13.9 167
67562-39-4
1,2,3,4,6,7,8-HpCDF
231
Pg/g
22.4 167
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
37
Pg/g
37.0 167
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
323
Pg/g
26.2 334
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1150
1340
Pg/g
86.2
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1210
1340
Pg/g
90.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1090
1340
Pg/g
81.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1120
1340
Pg/g
84.0
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1280
1340
Pg/g
96.2
(23%-140%)
13C-OCDD
2010
2670
Pg/g
75.1
(17%-157%)
13C-2,3,7,8-TCDF
1260
1340
Pg/g
94.7
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1200
1340
Pg/g
89.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1300
1340
Pg/g
97.5
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1190
1340
Pg/g
89.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1170
1340
Pg/g
87.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1220
1340
Pg/g
91.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1110
1340
Pg/g
82.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1160
1340
Pg/g
86.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1180
1340
Pg/g
88.3
(26%-13 8%)
3701-2,3,7,8-TCDD
153
134
Pg/g
115
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 33
-------
Cape Fear Analytical LLC
Report Date: July 16, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6328
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6328003
Date Collected:
07/10/2014 14:29
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
07/11/2014 09:50
%Moisture:
8.7
Client ID:
SFRA-140
Prep Basis:
Dry Weight
Batch ID:
26395
Method:
EPA Method 1613B
Run Date:
07/16/2014 09:28
Analyst:
JTF
Instrument:
HRP750
Data File:
A16JUL14A-5
Dilution:
5
Prep Batch:
26393
Prep Method:
SW846 3540C
Prep Date:
ll-JUL-14
Prep Aliquot:
1.35 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
42.8
Pg/g
9.65
40.6
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6328
Lab Sample ID: 6328003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/10/2014 14:29
07/11/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 8.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-140
26395
07/15/2014 13:59
bl4jull4a_3-3
26393
ll-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.35 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
8200
Pg/g
19.1 40.6
40321-76-4
1,2,3,7,8-PeCDD
U
11.1
Pg/g
11.1 203
39227-28-6
1,2,3,4,7,8-HxCDD
u
16.5
Pg/g
16.5 203
57653-85-7
1,2,3,6,7,8-HxCDD
J
90.7
Pg/g
16.2 203
19408-74-3
1,2,3,7,8,9-HxCDD
J
46.5
Pg/g
17.4 203
35822-46-9
1,2,3,4,6,7,8-HpCDD
897
Pg/g
19.5 203
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11700
Pg/g
68.6 406
51207-31-9
2,3,7,8-TCDF
41.3
Pg/g
12.0 40.6
57117-41-6
1,2,3,7,8-PeCDF
u
8.34
Pg/g
8.34 203
57117-31-4
2,3,4,7,8-PeCDF
J
10.8
Pg/g
7.35 203
70648-26-9
1,2,3,4,7,8-HxCDF
J
19.7
Pg/g
10.9 203
57II7.44.9
1,2,3,6,7,8-HxCDF
J
65.1
Pg/g
9.17 203
60851-34-5
2,3,4,6,7,8-HxCDF
J
15.7
Pg/g
10.4 203
72918-21-9
1,2,3,7,8,9-HxCDF
u
15.9
Pg/g
15.9 203
67562-39-4
1,2,3,4,6,7,8-HpCDF
324
Pg/g
10.5 203
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
19.8
Pg/g
19.8 203
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
350
Pg/g
27.9 406
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1190
1620
Pg/g
73.4
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1200
1620
Pg/g
73.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1350
1620
Pg/g
83.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1320
1620
Pg/g
81.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1600
1620
Pg/g
98.9
(23%-140%)
13C-OCDD
2350
3240
Pg/g
72.3
(17%-157%)
13C-2,3,7,8-TCDF
1500
1620
Pg/g
92.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1240
1620
Pg/g
76.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
1320
1620
Pg/g
81.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1370
1620
Pg/g
84.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1510
1620
Pg/g
92.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1470
1620
Pg/g
90.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1310
1620
Pg/g
80.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1430
1620
Pg/g
88.0
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1400
1620
Pg/g
86.3
(26%-13 8%)
3701-2,3,7,8-TCDD
170
162
Pg/g
105
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6328
Lab Sample ID: 6328004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/10/2014 14:33
07/11/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 6.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-141
26395
07/15/2014 14:47
bl4jull4a_3-4
26393
ll-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.28 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3450
Pg/g
16.3 41.6
40321-76-4
1,2,3,7,8-PeCDD
U
7.68
Pg/g
7.68 208
39227-28-6
1,2,3,4,7,8-HxCDD
u
10.7
Pg/g
10.7 208
57653-85-7
1,2,3,6,7,8-HxCDD
J
35.4
Pg/g
10.3 208
19408-74-3
1,2,3,7,8,9-HxCDD
J
14.0
Pg/g
11.1 208
35822-46-9
1,2,3,4,6,7,8-HpCDD
526
Pg/g
18.5 208
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8530
Pg/g
47.6 416
51207-31-9
2,3,7,8-TCDF
J
22.9
Pg/g
9.26 41.6
57117-41-6
1,2,3,7,8-PeCDF
u
5.46
Pg/g
5.46 208
57117-31-4
2,3,4,7,8-PeCDF
u
4.93
Pg/g
4.93 208
70648-26-9
1,2,3,4,7,8-HxCDF
u
7.63
Pg/g
7.63 208
57II7.44.9
1,2,3,6,7,8-HxCDF
J
17.7
Pg/g
6.59 208
60851-34-5
2,3,4,6,7,8-HxCDF
u
7.48
Pg/g
7.48 208
72918-21-9
1,2,3,7,8,9-HxCDF
u
10.3
Pg/g
10.3 208
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
159
Pg/g
8.08 208
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
11.7
Pg/g
11.7 208
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
214
Pg/g
27.3 416
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1310
1670
Pg/g
78.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1390
1670
Pg/g
83.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1350
1670
Pg/g
81.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1350
1670
Pg/g
80.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1640
1670
Pg/g
98.4
(23%-140%)
13C-OCDD
2670
3330
Pg/g
80.3
(17%-157%)
13C-2,3,7,8-TCDF
1730
1670
Pg/g
104
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1450
1670
Pg/g
87.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1520
1670
Pg/g
91.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1410
1670
Pg/g
84.4
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1470
1670
Pg/g
88.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1460
1670
Pg/g
87.8
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1500
1670
Pg/g
90.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1390
1670
Pg/g
83.8
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1510
1670
Pg/g
90.7
(26%-13 8%)
3701-2,3,7,8-TCDD
173
167
Pg/g
104
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6328
Lab Sample ID: 6328005
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/10/2014 14:36
07/11/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 8.1
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-142
26395
07/15/2014 15:34
bl4jull4a_3-5
26393
ll-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.08 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
4070
Pg/g
24.0 50.4
40321-76-4
1,2,3,7,8-PeCDD
U
11.9
Pg/g
11.9 252
39227-28-6
1,2,3,4,7,8-HxCDD
u
26.4
Pg/g
26.4 252
57653-85-7
1,2,3,6,7,8-HxCDD
J
50.7
Pg/g
26.2 252
19408-74-3
1,2,3,7,8,9-HxCDD
u
27.8
Pg/g
27.8 252
35822-46-9
1,2,3,4,6,7,8-HpCDD
759
Pg/g
25.6 252
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11400
Pg/g
67.9 504
51207-31-9
2,3,7,8-TCDF
J
27.4
Pg/g
17.5 50.4
57117-41-6
1,2,3,7,8-PeCDF
u
9.83
Pg/g
9.83 252
57117-31-4
2,3,4,7,8-PeCDF
u
9.45
Pg/g
9.45 252
70648-26-9
1,2,3,4,7,8-HxCDF
J
20.5
Pg/g
8.62 252
57II7.44.9
1,2,3,6,7,8-HxCDF
J
32.9
Pg/g
8.12 252
60851-34-5
2,3,4,6,7,8-HxCDF
J
15.3
Pg/g
9.13 252
72918-21-9
1,2,3,7,8,9-HxCDF
u
13.6
Pg/g
13.6 252
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
181
Pg/g
12.3 252
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
20.4
Pg/g
20.4 252
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
259
Pg/g
36.5 504
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1730
2010
Pg/g
85.9
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1840
2010
Pg/g
91.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1800
2010
Pg/g
89.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1680
2010
Pg/g
83.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2070
2010
Pg/g
103
(23%-140%)
13C-OCDD
3410
4030
Pg/g
84.7
(17%-157%)
13C-2,3,7,8-TCDF
2060
2010
Pg/g
102
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1900
2010
Pg/g
94.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
2000
2010
Pg/g
99.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1810
2010
Pg/g
90.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1930
2010
Pg/g
95.8
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1910
2010
Pg/g
94.5
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1800
2010
Pg/g
89.4
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1870
2010
Pg/g
92.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1930
2010
Pg/g
95.6
(26%-13 8%)
3701-2,3,7,8-TCDD
218
201
Pg/g
108
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 17 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
SDG Number: 6328
Lab Sample ID: 6328006
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/10/2014 14:38
07/11/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 9.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-143
26395
07/15/2014 16:22
bl4jull4a_3-6
26393
ll-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.14 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 10
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
14900
Pg/g
46.2 96.6
40321-76-4
1,2,3,7,8-PeCDD
U
20.5
Pg/g
20.5 483
39227-28-6
1,2,3,4,7,8-HxCDD
u
35.5
Pg/g
35.5 483
57653-85-7
1,2,3,6,7,8-HxCDD
J
105
Pg/g
35.2 483
19408-74-3
1,2,3,7,8,9-HxCDD
J
42.5
Pg/g
37.5 483
35822-46-9
1,2,3,4,6,7,8-HpCDD
1370
Pg/g
40.4 483
3268-87-9
1,2,3,4,6,7,8,9-OCDD
14800
Pg/g
115 966
51207-31-9
2,3,7,8-TCDF
J
90.1
Pg/g
41.9 96.6
57117-41-6
1,2,3,7,8-PeCDF
u
18.6
Pg/g
18.6 483
57117-31-4
2,3,4,7,8-PeCDF
u
16.2
Pg/g
16.2 483
70648-26-9
1,2,3,4,7,8-HxCDF
J
29.4
Pg/g
23.8 483
57II7.44.9
1,2,3,6,7,8-HxCDF
J
58.5
Pg/g
22.2 483
60851-34-5
2,3,4,6,7,8-HxCDF
u
23.4
Pg/g
23.4 483
72918-21-9
1,2,3,7,8,9-HxCDF
u
37.9
Pg/g
37.9 483
67562-39-4
1,2,3,4,6,7,8-HpCDF
671
Pg/g
33.2 483
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
46.9
Pg/g
46.9 483
39001-02-0
1,2,3,4,6,7,8,9-OCDF
966
Pg/g
54.5 966
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1670
1930
Pg/g
86.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
1710
1930
Pg/g
88.6
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1560
1930
Pg/g
80.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1690
1930
Pg/g
87.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1910
1930
Pg/g
98.7
(23%-140%)
13C-OCDD
2920
3860
Pg/g
75.4
(17%-157%)
13C-2,3,7,8-TCDF
1960
1930
Pg/g
101
(24%-169%)
130-1,2,3,7,8-
PeCDF
1770
1930
Pg/g
91.7
(24%-185%)
130-2,3,4,7,8-
PeCDF
1900
1930
Pg/g
98.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1690
1930
Pg/g
87.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1840
1930
Pg/g
95.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1810
1930
Pg/g
93.9
(28%-136%)
130-1,2,3,7,8,9-HxCDF
1690
1930
Pg/g
87.7
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
1760
1930
Pg/g
90.9
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
1840
1930
Pg/g
95.5
(26%-13 8%)
3701-2,3,7,8-TCDD
256
193
Pg/g
133
(35%-197%)
Comments:
J Value is estimated
of 1
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 18 of 33
-------
Quality Control
Summary
Page 19 of 33
-------
Cape Fear Analytical LLC Report Date: July 16,2014
Hi-Res Dioxins/Furans Page 1 of 4
Surrogate Recovery Report
SDG Number: 6328
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010901
LCS for batch 26393
12010902
LCSD for batch 26393
12010900
MB for batch 26393
6328001
SFRA-138
13C-2,3,7,8-TCDD
94.5
13C-l,2,3,7,8-PeCDD
116
13C-l,2,3,4,7,8-HxCDD
91.4
13C-l,2,3,6,7,8-HxCDD
86.8
13C-l,2,3,4,6,7,8-HpCDD
110
13C-OCDD
91.4
13C-2,3,7,8-TCDF
109
13C-l,2,3,7,8-PeCDF
112
13C-2,3,4,7,8-PeCDF
119
13C-l,2,3,4,7,8-HxCDF
99.6
13C-l,2,3,6,7,8-HxCDF
101
13C-2,3,4,6,7,8-HxCDF
102
13C-l,2,3,7,8,9-HxCDF
98.8
13C-l,2,3,4,6,7,8-HpCDF
101
13C-l,2,3,4,7,8,9-HpCDF
108
37Cl-2,3,7,8-TCDD
104
13C-2,3,7,8-TCDD
88.5
13C-l,2,3,7,8-PeCDD
107
13C-l,2,3,4,7,8-HxCDD
96.5
13C-l,2,3,6,7,8-HxCDD
86.1
13C-l,2,3,4,6,7,8-HpCDD
114
13C-OCDD
112
13C-2,3,7,8-TCDF
108
13C-l,2,3,7,8-PeCDF
106
13C-2,3,4,7,8-PeCDF
111
13C-l,2,3,4,7,8-HxCDF
99.3
13C-l,2,3,6,7,8-HxCDF
99.8
13C-2,3,4,6,7,8-HxCDF
101
13C-l,2,3,7,8,9-HxCDF
100
13C-l,2,3,4,6,7,8-HpCDF
107
13C-l,2,3,4,7,8,9-HpCDF
120
37Cl-2,3,7,8-TCDD
98.2
13C-2,3,7,8-TCDD
83.4
13C-l,2,3,7,8-PeCDD
104
13C-l,2,3,4,7,8-HxCDD
83.3
13C-l,2,3,6,7,8-HxCDD
79.1
13C-l,2,3,4,6,7,8-HpCDD
102
13C-OCDD
86.5
13C-2,3,7,8-TCDF
98.3
13C-l,2,3,7,8-PeCDF
97.8
13C-2,3,4,7,8-PeCDF
107
13C-l,2,3,4,7,8-HxCDF
89.2
13C-l,2,3,6,7,8-HxCDF
87.0
13C-2,3,4,6,7,8-HxCDF
90.4
13C-l,2,3,7,8,9-HxCDF
87.9
13C-l,2,3,4,6,7,8-HpCDF
93.7
13C-l,2,3,4,7,8,9-HpCDF
101
37Cl-2,3,7,8-TCDD
100
13C-2,3,7,8-TCDD
86.3
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
(25%-164%)
Page 20 of 3 3
-------
Cape Fear Analytical LLC Report Date: July 16,2014
Hi-Res Dioxins/Furans Page 2 of 4
Surrogate Recovery Report
SDG Number: 6328
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6328001
SFRA-138
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
108
87.6
91.4
111
40.7
103
101
107
101
101
102
99.0
105
106
105
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010903
SFRA-138(632800 IMS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
91.3
112
89.4
85.6
117
108
109
108
116
101
95.5
100
103
109
119
108
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12010904
SFRA-138(6328001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
88.0
115
92.5
82.5
110
98.0
98.0
107
115
95.6
95.5
96.2
96.1
100
109
99.0
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6328002
SFRA-139
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
86.2 D
90.4 D
(25%-
(25%-
64%)
81%)
Page 21 of 33
-------
Cape Fear Analytical LLC Report Date: July 16,2014
Hi-Res Dioxins/Furans Page 3 of 4
Surrogate Recovery Report
SDG Number: 6328
Matrix Type: SOLID
Sample ID
Client ID
Surrogate
Recovery
QUAL (%)
Acceptance
Limits
6328002
SFRA-139
13C-l,2,3,4,7,8-HxCDD
81.7
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
84.0
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
96.2
D
(23%-140%)
13C-OCDD
75.1
D
(17%-15 7%)
13C-2,3,7,8-TCDF
94.7
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
89.6
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
97.5
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
89.1
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
87.5
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
91.6
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
82.8
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
86.9
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
88.3
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
115
D
(35%-197%)
6328003
SFRA-140
13C-2,3,7,8-TCDD
73.4
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
73.8
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
83.3
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
81.3
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
98.9
D
(23%-140%)
13C-OCDD
72.3
D
(17%-15 7%)
13C-2,3,7,8-TCDF
92.3
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
76.4
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
81.6
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
84.5
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
92.8
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
90.7
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
80.7
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
88.0
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
86.3
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
105
D
(35%-197%)
6328004
SFRA-141
13C-2,3,7,8-TCDD
78.5
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
83.4
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
81.2
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
80.8
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
98.4
D
(23%-140%)
13C-OCDD
80.3
D
(17%-15 7%)
13C-2,3,7,8-TCDF
104
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
87.3
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
91.4
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
84.4
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
88.4
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
87.8
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
90.1
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
83.8
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
90.7
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
104
D
(35%-197%)
6328005
SFRA-142
13C-2,3,7,8-TCDD
85.9
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
91.1
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
89.2
D
(32%-141%)
Page 22 of 3 3
-------
Cape Fear Analytical LLC Report Date: July 16,2014
Hi-Res Dioxins/Furans Page 4 of 4
Surrogate Recovery Report
SDG Number: 6328
Matrix Type: SOLID
Sample ID Client ID
6328005 SFRA-142
6328006 SFRA-143
Surrogate
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
83.4
D
(28%-130%)
103
D
(23%-140%)
84.7
D
(17%-15 7%)
102
D
(24%-169%)
94.1
D
(24%-185%)
99.1
D
(21%-178%)
90.1
D
(26%-152%)
95.8
D
(26%-123%)
94.5
D
(28%-13 6%)
89.4
D
(29%-147%)
92.6
D
(28%-143%)
95.6
D
(26%-13 8%)
108
D
(35%-197%)
86.4
D
(25%-164%)
88.6
D
(25%-181%)
80.6
D
(32%-141%)
87.6
D
(28%-130%)
98.7
D
(23%-140%)
75.4
D
(17%-15 7%)
101
D
(24%-169%)
91.7
D
(24%-185%)
98.4
D
(21%-178%)
87.5
D
(26%-152%)
95.4
D
(26%-123%)
93.9
D
(28%-13 6%)
87.7
D
(29%-147%)
90.9
D
(28%-143%)
95.5
D
(26%-13 8%)
133
D
(35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 23 of 33
-------
Cape Fear Analytical LLC
Report Date: July 16,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 07/14/2014 19:20 Dilution: 1
Prep Batch ID:26393
Batch ID: 26395
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
22.2
111
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
103
103
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
111
111
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
112
112
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
118
118
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
111
111
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
209
105
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
23.9
119
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
114
114
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
109
109
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
121
121
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
114
114
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
118
118
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
124
124
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
119
119
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
123
123
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
253
126
63-170
SDG Number: 6328
Client ID: LCS for batch 26393
Lab Sample ID: 12010901
Instrument: HRP763
Analyst: JTF
Page 24 of 3 3
-------
Cape Fear Analytical LLC
Report Date: July 16,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 07/14/2014 20:07 Dilution: 1
Prep Batch ID:26393
Batch ID: 26395
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
22.3
112
67-158
0.431
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
106
106
70-142
3.46
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
113
113
70-164
1.67
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
110
110
76-134
1.61
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
117
117
64-162
1.33
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
113
113
70-140
2.34
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
212
106
78-144
1.18
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
24.3
121
75-158
1.68
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
110
110
80-134
3.80
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
110
110
68-160
0.758
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
119
119
72-134
1.72
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
117
117
84-130
2.83
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
119
119
70-156
1.47
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
125
125
78-130
0.756
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
113
113
82-122
5.35
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
119
119
78-138
2.91
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
259
130
63-170
2.68
0-20
SDG Number: 6328
Client ID: LCSD for batch 26393
Lab Sample ID: 12010902
Instrument: HRP763
Analyst: JTF
Page
25 of 33
-------
Cape Fear Analytical LLC
Report Date: July 16,2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
220
869
62.7 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
1100
U
1180
107
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
1100
J
1340
121
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
1100
J
1240
112
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
1100
u
1420
129
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
1100
1480
95.6
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
2200
12400
-414 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
220
J
281
125
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
1100
J
1200
109
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
1100
J
1160
105
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
1100
u
1300
118
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
1100
u
1300
118
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
1100
u
1320
120
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
1100
u
1350
122
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
1100
J
1280
116
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
1100
u
1310
119
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
2200
u
2740
124
70-130
Page 26 of 3 3
SDG Number: 6328
Client ID: SFRA-138(6328001MS)
Lab Sample ID: 12010903
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 10
Analysis Date: 07/14/2014 22:31
Prep Batch ID:26393
Batch ID: 26395
-------
Cape Fear Analytical LLC
Report Date: July 16,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 10
Analysis Date: 07/14/2014 23:18 Dilution: 1
Prep Batch ID:26393
Batch ID: 26395
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
214
1030
140 *
70-130
17.1
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
1070
U
1120
105
70-130
5.03
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
1070
J
1210
112
70-130
10.5
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
1070
J
1220
113
70-130
1.96
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
1070
U
1330
125
70-130
6.31
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
1070
1480
98.7
70-130
0.239
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
2140
12100
-441 *
70-130
2.54
0-20
51207-31-9
MSD
2,3,7,8-TCDF
214
J
257
117
70-130
8.78
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
1070
J
1180
111
70-130
1.30
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
1070
J
1160
108
70-130
0.396
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
1070
u
1270
119
70-130
2.21
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
1070
u
1260
118
70-130
3.08
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
1070
u
1300
122
70-130
1.22
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
1070
u
1370
128
70-130
1.44
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
1070
J
1300
121
70-130
1.08
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
1070
u
1300
122
70-130
0.368
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
2140
u
2680
126
70-130
2.00
0-20
SDG Number: 6328
Client ID: SFRA-138(6328001MSD)
Lab Sample ID: 12010904
Instrument: HRP763
Analyst: JTF
Page 27 of 3 3
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6328
Client ID: MB for batch 26393
Lab Sample ID: 12010900
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: ll-JUL-14
Matrix: SOLID
Data File: bl4jull4a-10
Analyzed: 07/14/14 20:55
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26393
12010901
bl4jull4a-8
07/14/14
1920
02
LCSD for batch 26393
12010902
bl4jull4a-9
07/14/14
2007
03
SFRA-138
6328001
bl4jull4a-l 1
07/14/14
2143
04
SFRA-138(632800 IMS)
12010903
bl4jull4a-12
07/14/14
2231
05
SFRA-138(6328001MSD)
12010904
bl4jull4a-13
07/14/14
2318
06
SFRA-139
6328002
bl4jull4a_3-2
07/15/14
1311
07
SFRA-140
6328003
bl4jull4a_3-3
07/15/14
1359
08
SFRA-141
6328004
bl4jull4a_3-4
07/15/14
1447
09
SFRA-142
6328005
bl4jull4a_3-5
07/15/14
1534
10
SFRA-143
6328006
bl4jull4a_3-6
07/15/14
1622
11
SFRA-139
6328002
A16JUL14A-4
07/16/14
0909
12
SFRA-140
6328003
A16JUL14A-5
07/16/14
0928
Page 28 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6328
Lab Sample ID: 12010900
Client Sample: ^or batch 26393
Client ID: MB for batch 26393
Batch ID: 26395
Run Date: 07/14/2014 20:55
Data File: bl4jull4a-10
Prep Batch: 26393
Prep Date: ll-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.404
Pg/g
0.404 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.238
Pg/g
0.238 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.308
Pg/g
0.308 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.262
Pg/g
0.262 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.3
Pg/g
0.300 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.352
Pg/g
0.352 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.624
Pg/g
0.624 10.0
51207-31-9
2,3,7,8-TCDF
u
.236
Pg/g
0.236 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.157
Pg/g
0.157 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.155
Pg/g
0.155 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.196
Pg/g
0.196 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
J
0.226
Pg/g
0.193 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.204
Pg/g
0.204 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.29
Pg/g
0.290 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
0.310
Pg/g
0.246 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.374
Pg/g
0.374 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.754
Pg/g
0.754 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
167
200
Pg/g
83.4
(25 %-164%)
130-1,2,3,7,8-
PeCDD
208
200
Pg/g
104
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
167
200
Pg/g
83.3
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
158
200
Pg/g
79.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
204
200
Pg/g
102
(23%-140%)
13C-OCDD
346
400
Pg/g
86.5
(17%-157%)
13C-2,3,7,8-TCDF
197
200
Pg/g
98.3
(24%-169%)
130-1,2,3,7,8-
PeCDF
196
200
Pg/g
97.8
(24%-185%)
130-2,3,4,7,8-
PeCDF
214
200
Pg/g
107
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
178
200
Pg/g
89.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
174
200
Pg/g
87.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
181
200
Pg/g
90.4
(28%-136%)
130-1,2,3,7,8,9-HxCDF
176
200
Pg/g
87.9
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
187
200
Pg/g
93.7
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
203
200
Pg/g
101
(26%-13 8%)
3701-2,3,7,8-TCDD
20.0
20.0
Pg/g
100
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 29 of 3 3
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6328
Lab Sample ID: 12010901
Client Sample: ^or batch 26393
Client ID: LCS for batch 26393
Batch ID: 26395
Run Date: 07/14/2014 19:20
Data File: bl4jull4a-8
Prep Batch: 26393
Prep Date: ll-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
22.2
Pg/g
0.408 1.00
40321-76-4
1,2,3,7,8-PeCDD
103
Pg/g
0.422 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
111
Pg/g
0.680 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
112
Pg/g
0.682 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
118
Pg/g
0.724 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
111
Pg/g
0.858 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
209
Pg/g
1.63 10.0
51207-31-9
2,3,7,8-TCDF
23.9
Pg/g
0.336 1.00
57117-41-6
1,2,3,7,8-PeCDF
114
Pg/g
0.690 5.00
57117-31-4
2,3,4,7,8-PeCDF
109
Pg/g
0.622 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
121
Pg/g
0.948 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
114
Pg/g
0.824 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
118
Pg/g
0.904 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
124
Pg/g
1.36 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
119
Pg/g
0.656 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
123
Pg/g
1.07 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
253
Pg/g
1.53 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
189
200
Pg/g
94.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
233
200
Pg/g
116
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
183
200
Pg/g
91.4
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
174
200
Pg/g
86.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
219
200
Pg/g
110
(22%-166%)
13C-OCDD
366
400
Pg/g
91.4
(13%-199%)
13C-2,3,7,8-TCDF
218
200
Pg/g
109
(22%-152%)
13C-1,2,3,7,8-
PeCDF
225
200
Pg/g
112
(21%-192%)
130-2,3,4,7,8-
PeCDF
239
200
Pg/g
119
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
199
200
Pg/g
99.6
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
202
200
Pg/g
101
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
204
200
Pg/g
102
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
198
200
Pg/g
98.8
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
202
200
Pg/g
101
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
216
200
Pg/g
108
(20%-186%)
3701-2,3,7,8-TCDD
20.9
20.0
Pg/g
104
(31 %-191%)
Comments:
Page 30 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6328
12010902
QC for batch 26393
LCSD for batch 26393
26395
07/14/2014 20:07
bl4jull4a-9
26393
ll-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
22.3
Pg/g
0.638 1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.326 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
113
Pg/g
0.766 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
110
Pg/g
0.770 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
117
Pg/g
0.814 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
113
Pg/g
0.892 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
212
Pg/g
1.50 10.0
51207-31-9
2,3,7,8-TCDF
24.3
Pg/g
0.378 1.00
57117-41-6
1,2,3,7,8-PeCDF
110
Pg/g
0.660 5.00
57117-31-4
2,3,4,7,8-PeCDF
110
Pg/g
0.580 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
119
Pg/g
0.980 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
117
Pg/g
0.884 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
119
Pg/g
1.00 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
125
Pg/g
1.40 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
113
Pg/g
0.842 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
119
Pg/g
1.25 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
259
Pg/g
1.39 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
177
200
Pg/g
88.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
214
200
Pg/g
107
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
193
200
Pg/g
96.5
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
172
200
Pg/g
86.1
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
228
200
Pg/g
114
(22%-166%)
13C-OCDD
447
400
Pg/g
112
(13%-199%)
13C-2,3,7,8-TCDF
215
200
Pg/g
108
(22%-152%)
13C-1,2,3,7,8-
PeCDF
211
200
Pg/g
106
(21%-192%)
130-2,3,4,7,8-
PeCDF
223
200
Pg/g
111
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
199
200
Pg/g
99.3
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
200
200
Pg/g
99.8
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
201
200
Pg/g
101
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
200
200
Pg/g
100
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
215
200
Pg/g
107
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
240
200
Pg/g
120
(20%-186%)
3701-2,3,7,8-TCDD
19.6
20.0
Pg/g
98.2
(31 %-191%)
Comments:
Page 31 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6328
12010903
QC for batch 26393
SFRA-138(6328001MS)
26395
07/14/2014 22:31
bl4jull4a-12
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/10/2014 14:23
07/11/2014 09:50
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
10
Dry Weight
HRP763
1
Prep Batch:
26393
Prep Method:
SW846 3540C
Prep Date:
ll-JUL-14
Prep Aliquot:
1.01 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
869
Pg/g
6.03
11.0
40321-76-4
1,2,3,7,8-PeCDD
1180
Pg/g
5.10
55.0
39227-28-6
1,2,3,4,7,8-HxCDD
1340
Pg/g
9.42
55.0
57653-85-7
1,2,3,6,7,8-HxCDD
1240
Pg/g
9.57
55.0
19408-74-3
1,2,3,7,8,9-HxCDD
1420
Pg/g
10.1
55.0
35822-46-9
1,2,3,4,6,7,8-HpCDD
1480
Pg/g
15.5
55.0
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12400
Pg/g
26.4
110
51207-31-9
2,3,7,8-TCDF
281
Pg/g
4.18
11.0
57117-41-6
1,2,3,7,8-PeCDF
1200
Pg/g
1.55
55.0
57117-31-4
2,3,4,7,8-PeCDF
1160
Pg/g
1.43
55.0
70648-26-9
1,2,3,4,7,8-HxCDF
1300
Pg/g
11.6
55.0
57II7.44.9
1,2,3,6,7,8-HxCDF
1300
Pg/g
11.0
55.0
60851-34-5
2,3,4,6,7,8-HxCDF
1320
Pg/g
11.5
55.0
72918-21-9
1,2,3,7,8,9-HxCDF
1350
Pg/g
16.0
55.0
67562-39-4
1,2,3,4,6,7,8-HpCDF
1280
Pg/g
7.19
55.0
55673-89-7
1,2,3,4,7,8,9-HpCDF
1310
Pg/g
11.2
55.0
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2740
Pg/g
15.1
110
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2010
2200
Pg/g
91.3
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2470
2200
Pg/g
112
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1970
2200
Pg/g
89.4
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1880
2200
Pg/g
85.6
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2570
2200
Pg/g
117
(23%-140%)
13C-OCDD
4750
4400
Pg/g
108
(17%-157%)
13C-2,3,7,8-TCDF
2400
2200
Pg/g
109
(24%-169%)
13C-1,2,3,7,8-PeCDF
2370
2200
Pg/g
108
(24%-185%)
13C-2,3,4,7,8-PeCDF
2550
2200
Pg/g
116
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
2210
2200
Pg/g
101
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2100
2200
Pg/g
95.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2210
2200
Pg/g
100
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2270
2200
Pg/g
103
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2400
2200
Pg/g
109
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2620
2200
Pg/g
119
(26%-13 8%)
37Cl-2,3,7,8-TCDD
239
220
Pg/g
108
(35%-197%)
Comments:
Page 32 of 33
-------
Cape Fear Analytical LLC
Report Date:
July 16, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6328
12010904
QC for batch 26393
SFRA-138(6328001MSD)
26395
07/14/2014 23:18
bl4jull4a-13
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/10/2014 14:23
07/11/2014 09:50
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
10
Dry Weight
HRP763
1
Prep Batch:
26393
Prep Method:
SW846 3540C
Prep Date:
ll-JUL-14
Prep Aliquot:
1.04 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
1030
Pg/g
6.43
10.7
40321-76-4
1,2,3,7,8-PeCDD
1120
Pg/g
5.00
53.4
39227-28-6
1,2,3,4,7,8-HxCDD
1210
Pg/g
11.3
53.4
57653-85-7
1,2,3,6,7,8-HxCDD
1220
Pg/g
11.4
53.4
19408-74-3
1,2,3,7,8,9-HxCDD
1330
Pg/g
12.1
53.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
1480
Pg/g
12.3
53.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12100
Pg/g
25.2
107
51207-31-9
2,3,7,8-TCDF
257
Pg/g
7.52
10.7
57117-41-6
1,2,3,7,8-PeCDF
1180
Pg/g
2.33
53.4
57117-31-4
2,3,4,7,8-PeCDF
1160
Pg/g
2.16
53.4
70648-26-9
1,2,3,4,7,8-HxCDF
1270
Pg/g
10.1
53.4
57II7.44.9
1,2,3,6,7,8-HxCDF
1260
Pg/g
9.94
53.4
60851-34-5
2,3,4,6,7,8-HxCDF
1300
Pg/g
10.2
53.4
72918-21-9
1,2,3,7,8,9-HxCDF
1370
Pg/g
14.4
53.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
1300
Pg/g
6.97
53.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
1300
Pg/g
11.8
53.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2680
Pg/g
16.5
107
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1880
2140
Pg/g
88.0
(25 %-164%)
13C-1,2,3,7,8-PeCDD
2450
2140
Pg/g
115
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1980
2140
Pg/g
92.5
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1760
2140
Pg/g
82.5
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2340
2140
Pg/g
110
(23%-140%)
13C-OCDD
4190
4270
Pg/g
98.0
(17%-157%)
13C-2,3,7,8-TCDF
2090
2140
Pg/g
98.0
(24%-169%)
13C-1,2,3,7,8-PeCDF
2280
2140
Pg/g
107
(24%-185%)
13C-2,3,4,7,8-PeCDF
2460
2140
Pg/g
115
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
2040
2140
Pg/g
95.6
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
2040
2140
Pg/g
95.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
2060
2140
Pg/g
96.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2050
2140
Pg/g
96.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2140
2140
Pg/g
100
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
2320
2140
Pg/g
109
(26%-13 8%)
37Cl-2,3,7,8-TCDD
211
214
Pg/g
99.0
(35%-197%)
Comments:
Page 33 of 33
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
July 23. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6361
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 18, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of 31
problem solved
-------
Page.:
Project #:
CFAQuote#: __
CQC Number'-''i
PO Number:
of
Client
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CPA Work Order Number: (j 3 ^ (
!Cape Fear Analytical, LLC
13306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone:(910)795-0421
Phone #:
Sample Analysis Requested <5) (Fill in the number of containers for each test)
£
0c
a
In1,
C
>-
Kj
Project/SiteN.mcfyycc^
<-- Preservative Type (6)
— i J « ar •» w f ff r^vii # fT f Ti„, ¦ ~ t
Address: £ q S^^s-fa//
m
-------
c"ent: Tckf& Tr,
)r\
Work Order: Q ^ (p I
Shipping Company: \(jrl
Ev
Date/Time Received: j j ^
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Suspected Hazard Informal
m
Yes
NA
No
Shipped as DOT Hazardous?
V"
Samples identified as Foreig
Soil?
DOE Site Sample Packages
Yes
NA
jsk>*
Screened <0.5 mR/hr?
Samples < 2x background?
Air Sample Receipt Specific
Air sample in shipment?
Yes
NA
No
^1
* Notify RSO of any responses in this column immediately.
Air Witness:
Sample Receipt Cr
eria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received intact
and sealed?
Circie Applicable:
seals broken damaged container leaking container otheHdescribe)
7^
Chain of Custody docum
with shipment?
ants included
Samples requiring cold preservation
within Q-6°C?
Pr^f^rvation Method:
"Te bags ^blue ice dry ice none other (describe)
9-0
Aqueous samples found
solids?
to have visible
Sample IDs, containers affected:
Samples requiring chemi;al
preservation at proper pH?
Sample IDs, containers affected and pH observed:
If preservative added, Lot#;
Samples requiring preset^
no residual chlorine?
ation have
Sample iOs, containers affected:
If preservative added, tot#:
Samples received within
olding time?
SampJe IDs. tests affected:
Sample IDs on COC matqt
containers?
IDs on
Sample fDs, containers affected'-
Date & time of COC mate
on containers?
date & time
Sample ID*, containers effected:
10
sNumber of containers received match
number indicated on COC
Sample tOs, containers affected:
11
COC form is properly signed In
relinquished/received sections?
Comments:
Checklist
Page 3 of 31
performed by: Initials:
Date
: l&Ll IH
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 31
-------
Case Narrative
Page 5 of 31
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6361
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26460
Clean Up Batch Number: 26459
Extraction Batch Number: 26458
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6361001
SFRA-144
6361002
SFRA-145
6361003
SFRA-146
6361004
SFRA-147
6361005
SFRA-148
12010964
Method Blank (MB)
12010965
Laboratory Control Sample (LCS)
12010966
Laboratory Control Sample Duplicate (LCSD)
12010967
6361001 (SFRA-144) Matrix Spike (MS)
12010968
6361001 (SFRA-144) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Page 6 of 31
-------
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6361001 (SFRA-144) - Batch 26460 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike/Matrix Spike Duplicate (MS/MSD) Recovery Statement
One MS recovery for this SDG was not within the acceptance limits. The failure confirms in the
matrix spike duplicate and can be attributed to matrix interference. 12010967 (SFRA-144) and
12010968 (SFRA-144) - Batch 26460.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
Page 7 of 31
-------
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26460.
Sample Dilutions
Samples 12010967 (SFRA-144), 12010968 (SFRA-144), 6361001 (SFRA-144), 6361002
(SFRA-145), 6361003 (SFRA-146) and 6361005 (SFRA-148)- Batch 26460 were diluted due to
the presence of over-range target analytes.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 31
-------
Sample Data Summary
Page 9 of 31
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6361 CFA Work Order: 6361
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 23 JUL 2014 Title: Data Validator
Page 10 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6361
Lab Sample ID: 6361001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/17/2014 09:00
07/18/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 10*4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-144
26460
07/22/2014 13:08
b22jull4a-6
26458
18-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.65 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3100
Pg/g
23.9 33.8
40321-76-4
1,2,3,7,8-PeCDD
U
9.55
Pg/g
9.55 169
39227-28-6
1,2,3,4,7,8-HxCDD
u
14.2
Pg/g
14.2 169
57653-85-7
1,2,3,6,7,8-HxCDD
J
44.3
Pg/g
14.6 169
19408-74-3
1,2,3,7,8,9-HxCDD
u
15.3
Pg/g
15.3 169
35822-46-9
1,2,3,4,6,7,8-HpCDD
448
Pg/g
30.3 169
3268-87-9
1,2,3,4,6,7,8,9-OCDD
10000
Pg/g
62.9 338
51207-31-9
2,3,7,8-TCDF
J
21.5
Pg/g
13.9 33.8
57117-41-6
1,2,3,7,8-PeCDF
u
9.54
Pg/g
9.54 169
57117-31-4
2,3,4,7,8-PeCDF
u
8.09
Pg/g
8.09 169
70648-26-9
1,2,3,4,7,8-HxCDF
u
9.74
Pg/g
9.74 169
57II7.44.9
1,2,3,6,7,8-HxCDF
u
8.98
Pg/g
8.98 169
60851-34-5
2,3,4,6,7,8-HxCDF
u
10.3
Pg/g
10.3 169
72918-21-9
1,2,3,7,8,9-HxCDF
u
14.2
Pg/g
14.2 169
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
117
Pg/g
9.27 169
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
14.6
Pg/g
14.6 169
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
122
Pg/g
33.3 338
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1140
1350
Pg/g
84.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1210
1350
Pg/g
89.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1020
1350
Pg/g
75.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1180
1350
Pg/g
87.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1270
1350
Pg/g
93.9
(23%-140%)
13C-OCDD
2110
2710
Pg/g
78.0
(17%-157%)
13C-2,3,7,8-TCDF
1250
1350
Pg/g
92.6
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1160
1350
Pg/g
85.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1260
1350
Pg/g
93.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1110
1350
Pg/g
82.0
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1220
1350
Pg/g
90.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1170
1350
Pg/g
86.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1120
1350
Pg/g
83.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1210
1350
Pg/g
89.3
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1180
1350
Pg/g
87.5
(26%-13 8%)
3701-2,3,7,8-TCDD
147
135
Pg/g
108
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6361
6361002
1613B Soil
SFRA-145
26460
07/22/2014 15:31
b22jull4a-9
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/17/2014 09:10
07/18/2014 10:00
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
15.7
Dry Weight
HRP763
5
Prep Batch:
26458
Prep Method:
SW846 3540C
Prep Date:
18-JUL-14
Prep Aliquot:
1.23 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
5690
Pg/g
39.5
48.2
40321-76-4
1,2,3,7,8-PeCDD
U
13
Pg/g
13.0
241
39227-28-6
1,2,3,4,7,8-HxCDD
u
21.4
Pg/g
21.4
241
57653-85-7
1,2,3,6,7,8-HxCDD
J
46.1
Pg/g
21.4
241
19408-74-3
1,2,3,7,8,9-HxCDD
u
22.6
Pg/g
22.6
241
35822-46-9
1,2,3,4,6,7,8-HpCDD
814
Pg/g
83.1
241
3268-87-9
1,2,3,4,6,7,8,9-OCDD
13600
Pg/g
178
482
51207-31-9
2,3,7,8-TCDF
J
34.0
Pg/g
21.6
48.2
57117-41-6
1,2,3,7,8-PeCDF
u
13
Pg/g
13.0
241
57117-31-4
2,3,4,7,8-PeCDF
u
12.4
Pg/g
12.4
241
70648-26-9
1,2,3,4,7,8-HxCDF
u
18.5
Pg/g
18.5
241
57II7.44.9
1,2,3,6,7,8-HxCDF
u
17
Pg/g
17.0
241
60851-34-5
2,3,4,6,7,8-HxCDF
u
19.7
Pg/g
19.7
241
72918-21-9
1,2,3,7,8,9-HxCDF
u
32
Pg/g
32.0
241
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
203
Pg/g
44.9
241
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
79.6
Pg/g
79.6
241
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
302
Pg/g
74.2
482
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1590
1930
Pg/g
82.3
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1530
1930
Pg/g
79.4
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1320
1930
Pg/g
68.3
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1690
1930
Pg/g
87.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1640
1930
Pg/g
85.0
(23%-140%)
13C-OCDD
2620
3860
Pg/g
67.9
(17%-157%)
13C-2,3,7,8-TCDF
1750
1930
Pg/g
90.6
(24%-169%)
13C-1,2,3,7,8-PeCDF
1580
1930
Pg/g
82.0
(24%-185%)
13C-2,3,4,7,8-PeCDF
1610
1930
Pg/g
83.5
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1520
1930
Pg/g
78.7
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1790
1930
Pg/g
92.7
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1710
1930
Pg/g
88.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1610
1930
Pg/g
83.5
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1580
1930
Pg/g
82.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1540
1930
Pg/g
79.7
(26%-13 8%)
37Cl-2,3,7,8-TCDD
205
193
Pg/g
106
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6361
Lab Sample ID: 6361003
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/17/2014 14:55
07/18/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 14.7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-146
26460
07/22/2014 16:19
b22jull4a-10
26458
18-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.56 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
3570
Pg/g
24.8 37.6
40321-76-4
1,2,3,7,8-PeCDD
U
13.6
Pg/g
13.6 188
39227-28-6
1,2,3,4,7,8-HxCDD
u
33.2
Pg/g
33.2 188
57653-85-7
1,2,3,6,7,8-HxCDD
J
40.1
Pg/g
31.0 188
19408-74-3
1,2,3,7,8,9-HxCDD
u
33.8
Pg/g
33.8 188
35822-46-9
1,2,3,4,6,7,8-HpCDD
643
Pg/g
42.2 188
3268-87-9
1,2,3,4,6,7,8,9-OCDD
10800
Pg/g
125 376
51207-31-9
2,3,7,8-TCDF
J
26.6
Pg/g
16.5 37.6
57117-41-6
1,2,3,7,8-PeCDF
u
15.9
Pg/g
15.9 188
57117-31-4
2,3,4,7,8-PeCDF
u
9.65
Pg/g
9.65 188
70648-26-9
1,2,3,4,7,8-HxCDF
u
13.3
Pg/g
13.3 188
57II7.44.9
1,2,3,6,7,8-HxCDF
u
10
Pg/g
10.0 188
60851-34-5
2,3,4,6,7,8-HxCDF
u
10.9
Pg/g
10.9 188
72918-21-9
1,2,3,7,8,9-HxCDF
u
16.2
Pg/g
16.2 188
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
146
Pg/g
19.5 188
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
30.8
Pg/g
30.8 188
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
307
Pg/g
83.4 376
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1310
1500
Pg/g
87.3
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1270
1500
Pg/g
84.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1050
1500
Pg/g
70.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1220
1500
Pg/g
81.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1130
1500
Pg/g
75.4
(23%-140%)
13C-OCDD
1890
3010
Pg/g
62.7
(17%-157%)
13C-2,3,7,8-TCDF
1360
1500
Pg/g
90.3
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1210
1500
Pg/g
80.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1310
1500
Pg/g
87.1
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1130
1500
Pg/g
75.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1250
1500
Pg/g
83.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1210
1500
Pg/g
80.3
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1230
1500
Pg/g
81.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1170
1500
Pg/g
77.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1170
1500
Pg/g
78.2
(26%-13 8%)
3701-2,3,7,8-TCDD
158
150
Pg/g
105
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6361
Lab Sample ID: 6361004
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/17/201415:15
07/18/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 17
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-147
26460
07/22/2014 17:07
b22jull4a-ll
26458
18-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.33 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
335
Pg/g
4.46 9.06
40321-76-4
1,2,3,7,8-PeCDD
U
2.14
Pg/g
2.14 45.3
39227-28-6
1,2,3,4,7,8-HxCDD
u
4.47
Pg/g
4.47 45.3
57653-85-7
1,2,3,6,7,8-HxCDD
u
7.03
Pg/g
7.03 45.3
19408-74-3
1,2,3,7,8,9-HxCDD
u
4.53
Pg/g
4.53 45.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
106
Pg/g
7.43 45.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
4940
Pg/g
27.7 90.6
51207-31-9
2,3,7,8-TCDF
J
3.93
Pg/g
3.26 9.06
57117-41-6
1,2,3,7,8-PeCDF
u
4.24
Pg/g
4.24 45.3
57117-31-4
2,3,4,7,8-PeCDF
u
1.81
Pg/g
1.81 45.3
70648-26-9
1,2,3,4,7,8-HxCDF
u
2.32
Pg/g
2.32 45.3
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.19
Pg/g
2.19 45.3
60851-34-5
2,3,4,6,7,8-HxCDF
u
2.37
Pg/g
2.37 45.3
72918-21-9
1,2,3,7,8,9-HxCDF
u
3.71
Pg/g
3.71 45.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
21.5
Pg/g
3.84 45.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
6.79
Pg/g
6.79 45.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
32.6
Pg/g
9.89 90.6
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1580
1810
Pg/g
87.0
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1570
1810
Pg/g
86.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1450
1810
Pg/g
79.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1510
1810
Pg/g
83.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1590
1810
Pg/g
87.8
(23%-140%)
13C-OCDD
2780
3620
Pg/g
76.7
(17%-157%)
13C-2,3,7,8-TCDF
1700
1810
Pg/g
94.1
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1510
1810
Pg/g
83.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1660
1810
Pg/g
91.7
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1450
1810
Pg/g
80.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1600
1810
Pg/g
88.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1600
1810
Pg/g
88.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1500
1810
Pg/g
82.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1600
1810
Pg/g
88.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1540
1810
Pg/g
84.8
(26%-13 8%)
3701-2,3,7,8-TCDD
187
181
Pg/g
103
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 14 of 31
-------
Cape Fear Analytical LLC
Report Date: July 23, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6361
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6361005
Date Collected:
07/17/2014 15:30
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
07/18/2014 10:00
%Moisture:
21.7
Client ID:
SFRA-148
Prep Basis:
Dry Weight
Batch ID:
26460
Method:
EPA Method 1613B
Run Date:
07/23/2014 09:50
Analyst:
JTF
Instrument:
HRP750
Data File:
A23JUL14A-4
Dilution:
10
Prep Batch:
26458
Prep Method:
SW846 3540C
Prep Date:
18-JUL-14
Prep Aliquot:
1.13 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
163
Pg/g
33.2
113
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 15 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6361
6361005
1613B Soil
SFRA-148
26460
07/22/2014 17:55
b22jull4a-12
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/17/2014 15:30
07/18/2014 10:00
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
21.7
Dry Weight
HRP763
10
Prep Batch:
26458
Prep Method:
SW846 3540C
Prep Date:
18-JUL-14
Prep Aliquot:
1.13 g
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
24400
Pg/g
58.3 113
40321-76-4
1,2,3,7,8-PeCDD
U
32.5
Pg/g
32.5 565
39227-28-6
1,2,3,4,7,8-HxCDD
u
62.6
Pg/g
62.6 565
57653-85-7
1,2,3,6,7,8-HxCDD
J
139
Pg/g
55.6 565
19408-74-3
1,2,3,7,8,9-HxCDD
u
62.1
Pg/g
62.1 565
35822-46-9
1,2,3,4,6,7,8-HpCDD
1420
Pg/g
156 565
3268-87-9
1,2,3,4,6,7,8,9-OCDD
16000
Pg/g
319 1130
51207-31-9
2,3,7,8-TCDF
160
Pg/g
51.5 113
57117-41-6
1,2,3,7,8-PeCDF
u
22.5
Pg/g
22.5 565
57117-31-4
2,3,4,7,8-PeCDF
u
20.8
Pg/g
20.8 565
70648-26-9
1,2,3,4,7,8-HxCDF
J
39.3
Pg/g
24.6 565
57II7.44.9
1,2,3,6,7,8-HxCDF
u
25.1
Pg/g
25.1 565
60851-34-5
2,3,4,6,7,8-HxCDF
J
33.2
Pg/g
24.6 565
72918-21-9
1,2,3,7,8,9-HxCDF
u
34.1
Pg/g
34.1 565
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
491
Pg/g
41.6 565
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
91.5
Pg/g
91.5 565
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
521
Pg/g
145 1130
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
2020
2260
Pg/g
89.4
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1900
2260
Pg/g
84.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1830
2260
Pg/g
81.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
2080
2260
Pg/g
91.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
2090
2260
Pg/g
92.3
(23%-140%)
13C-OCDD
3190
4520
Pg/g
70.7
(17%-157%)
13C-2,3,7,8-TCDF
2050
2260
Pg/g
90.8
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1970
2260
Pg/g
87.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
2060
2260
Pg/g
91.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
2000
2260
Pg/g
88.7
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
2080
2260
Pg/g
92.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1990
2260
Pg/g
88.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
2050
2260
Pg/g
90.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
2210
2260
Pg/g
97.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1960
2260
Pg/g
86.7
(26%-13 8%)
3701-2,3,7,8-TCDD
333
226
Pg/g
147
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 16 of 31
-------
Quality Control
Summary
Page 17 of 31
-------
Cape Fear Analytical LLC Report Date: July 23,2014
Hi-Res Dioxins/Furans Page 1 of 4
Surrogate Recovery Report
SDG Number: 6361
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12010965
LCS for batch 26458
12010966
LCSD for batch 26458
12010964
MB for batch 26458
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
90.6
95.4
84.8
84.8
97.9
87.4
96.5
90.3
97.2
85.3
85.9
88.3
85.9
88.7
92.1
107
83.5
84.4
74.8
77.7
88.7
76.5
90.5
84.5
88.6
77.6
78.4
79.1
79.1
81.9
84.9
104
90.0
90.7
85.2
81.9
94.6
81.9
95.5
90.1
95.6
87.5
84.7
87.2
85.4
90.6
91.1
102
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6361001
SFRA-144
13C-2,3,7,8-TCDD
84.6 D
(25%-164%)
Page 18 of 31
-------
Cape Fear Analytical LLC Report Date: July 23,2014
Hi-Res Dioxins/Furans Page 2 of 4
Surrogate Recovery Report
SDG Number: 6361
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6361001
SFRA-144
12010967
SFRA-144(6361001 MS)
12010968
SFRA-144(6361001MSD)
6361002
SFRA-145
13C-l,2,3,7,8-PeCDD
89.5
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
75.7
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
87.4
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
93.9
D
(23%-140%)
13C-OCDD
78.0
D
(17%-15 7%)
13C-2,3,7,8-TCDF
92.6
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
85.6
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
93.0
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
82.0
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
90.2
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
86.7
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
83.0
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
89.3
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
87.5
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
108
D
(35%-197%)
13C-2,3,7,8-TCDD
85.5
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
86.2
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
82.6
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
85.1
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
92.8
D
(23%-140%)
13C-OCDD
80.3
D
(17%-15 7%)
13C-2,3,7,8-TCDF
92.1
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
84.4
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
89.4
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
84.5
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
91.7
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
88.9
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
87.0
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
91.5
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
83.6
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
106
D
(35%-197%)
13C-2,3,7,8-TCDD
90.6
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
83.1
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
86.9
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
88.9
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
101
D
(23%-140%)
13C-OCDD
86.9
D
(17%-15 7%)
13C-2,3,7,8-TCDF
94.2
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
86.2
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
93.3
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
91.6
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
100
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
94.7
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
88.1
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
96.6
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
93.4
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
113
D
(35%-197%)
13C-2,3,7,8-TCDD
82.3
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
79.4
D
(25%-181%)
Page 19 of 31
-------
Cape Fear Analytical LLC Report Date: July 23,2014
Hi-Res Dioxins/Furans Page 3 of 4
Surrogate Recovery Report
SDG Number: 6361
Matrix Type: SOLID
Sample ID
Client ID
Surrogate
Recovery
QUAL (%)
Acceptance
Limits
6361002
SFRA-145
13C-l,2,3,4,7,8-HxCDD
68.3
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
87.9
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
85.0
D
(23%-140%)
13C-OCDD
67.9
D
(17%-15 7%)
13C-2,3,7,8-TCDF
90.6
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
82.0
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
83.5
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
78.7
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
92.7
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
88.6
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
83.5
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
82.2
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
79.7
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
106
D
(35%-197%)
6361003
SFRA-146
13C-2,3,7,8-TCDD
87.3
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
84.7
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
70.1
D
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
81.1
D
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
75.4
D
(23%-140%)
13C-OCDD
62.7
D
(17%-15 7%)
13C-2,3,7,8-TCDF
90.3
D
(24%-169%)
13C-l,2,3,7,8-PeCDF
80.3
D
(24%-185%)
13C-2,3,4,7,8-PeCDF
87.1
D
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
75.2
D
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
83.4
D
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
80.3
D
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
81.6
D
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
77.9
D
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
78.2
D
(26%-13 8%)
37Cl-2,3,7,8-TCDD
105
D
(35%-197%)
6361004
SFRA-147
13C-2,3,7,8-TCDD
87.0
(25%-164%)
13C-l,2,3,7,8-PeCDD
86.4
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
79.9
(32%-141%)
13C-l,2,3,6,7,8-HxCDD
83.2
(28%-130%)
13C-l,2,3,4,6,7,8-HpCDD
87.8
(23%-140%)
13C-OCDD
76.7
(17%-15 7%)
13C-2,3,7,8-TCDF
94.1
(24%-169%)
13C-l,2,3,7,8-PeCDF
83.2
(24%-185%)
13C-2,3,4,7,8-PeCDF
91.7
(21%-178%)
13C-l,2,3,4,7,8-HxCDF
80.2
(26%-152%)
13C-l,2,3,6,7,8-HxCDF
88.3
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
88.2
(28%-13 6%)
13C-l,2,3,7,8,9-HxCDF
82.7
(29%-147%)
13C-l,2,3,4,6,7,8-HpCDF
88.6
(28%-143%)
13C-l,2,3,4,7,8,9-HpCDF
84.8
(26%-13 8%)
37Cl-2,3,7,8-TCDD
103
(35%-197%)
6361005
SFRA-148
13C-2,3,7,8-TCDD
89.4
D
(25%-164%)
13C-l,2,3,7,8-PeCDD
84.2
D
(25%-181%)
13C-l,2,3,4,7,8-HxCDD
81.2
D
(32%-141%)
Page 20 of 31
-------
Cape Fear Analytical LLC
Report Date: July 23,2014
Hi-Res Dioxins/Furans
Surrogate Recovery Report
SDG Number: 6361
Matrix Type: SOLID
Page 4
of 4
Sample ID Client ID
Recovery Acceptance
Surrogate
QUAL (%)
Limits
13C-l,2,3,6,7,8-HxCDD
91.9
D
(28%-
¦130%)
13C-l,2,3,4,6,7,8-HpCDD
92.3
D
(23%-
¦140%)
13C-OCDD
70.7
D
(17%-
¦157%)
13C-2,3,7,8-TCDF
90.8
D
(24%-
¦169%)
13C-l,2,3,7,8-PeCDF
87.2
D
(24%-
¦185%)
13C-2,3,4,7,8-PeCDF
91.0
D
(21%-
¦178%)
13C-l,2,3,4,7,8-HxCDF
88.7
D
(26%-
¦152%)
13C-l,2,3,6,7,8-HxCDF
92.2
D
(26%-
¦123%)
13C-2,3,4,6,7,8-HxCDF
88.0
D
(28%-
¦136%)
13C-l,2,3,7,8,9-HxCDF
90.7
D
(29%-
¦147%)
13C-l,2,3,4,6,7,8-HpCDF
97.6
D
(28%-
¦143%)
13C-l,2,3,4,7,8,9-HpCDF
86.7
D
(26%-
¦138%)
37Cl-2,3,7,8-TCDD
147
D
(35%-
¦197%)
6361005
SFRA-148
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 21 of 31
-------
Cape Fear Analytical LLC
Report Date: July 23,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 07/22/2014 10:46 Dilution: 1
Prep Batch ID:26458
Batch ID: 26460
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.2
106
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
103
103
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
105
105
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
103
103
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
109
109
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
102
102
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
206
103
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
21.2
106
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
111
111
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
109
109
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
116
116
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
117
117
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
114
114
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
125
125
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
115
115
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
118
118
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
225
112
63-170
SDG Number: 6361
Client ID: LCS for batch 26458
Lab Sample ID: 12010965
Instrument: HRP763
Analyst: JTF
Page 22 of 31
-------
Cape Fear Analytical LLC
Report Date: July 23,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 07/22/2014 11:33 Dilution: 1
Prep Batch ID:26458
Batch ID: 26460
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
21.4
107
67-158
0.769
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
106
106
70-142
3.21
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
109
109
70-164
3.31
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
107
107
76-134
3.66
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
118
118
64-162
8.31
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
106
106
70-140
3.45
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
232
116
78-144
12.2
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
21.3
107
75-158
0.310
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
111
111
80-134
0.0631
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
109
109
68-160
0.278
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
117
117
72-134
0.926
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
118
118
84-130
0.799
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
114
114
70-156
0.529
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
123
123
78-130
1.98
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
113
113
82-122
1.76
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
118
118
78-138
0.376
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
235
118
63-170
4.46
0-20
SDG Number: 6361
Client ID: LCSD for batch 26458
Lab Sample ID: 12010966
Instrument: HRP763
Analyst: JTF
Page
23 of 31
-------
Cape Fear Analytical LLC
Report Date: July 23,2014
Page 1 of 2
Dilution: 5
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
143
2870
-161 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
715
U
721
101
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
715
U
734
103
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
715
J
813
107
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
715
U
810
113
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
715
1160
100
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
1430
11300
88.9
70-130
51207-31-9
MS
2,3,7,8-TCDF
143
J
166
101
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
715
u
759
106
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
715
u
776
108
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
715
u
778
109
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
715
u
805
113
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
715
u
810
113
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
715
u
856
120
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
715
J
956
117
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
715
u
894
125
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
1430
J
1680
109
70-130
SDG Number: 6361
Client ID: SFRA-144(6361001MS)
Lab Sample ID: 12010967
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 10.4
Analysis Date: 07/22/2014 13:56
Prep Batch ID:26458
Batch ID: 26460
Page 24 of 31
-------
Cape Fear Analytical LLC
Report Date: July 23,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 10.4
Analysis Date: 07/22/2014 14:44 Dilution: 5
Prep Batch ID:26458
Batch ID: 26460
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
138
2880
-162 *
70-130
0.240
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
689
U
788
114
70-130
8.80
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
689
U
728
106
70-130
0.736
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
689
J
778
107
70-130
4.34
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
689
u
707
103
70-130
13.5
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
689
1180
106
70-130
1.32
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
1380
11500
108
70-130
1.86
0-20
51207-31-9
MSD
2,3,7,8-TCDF
138
J
174
111
70-130
4.43
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
689
u
764
111
70-130
0.642
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
689
u
734
107
70-130
5.63
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
689
u
803
117
70-130
3.15
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
689
u
794
115
70-130
1.45
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
689
u
812
118
70-130
0.169
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
689
u
864
125
70-130
0.944
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
689
J
908
115
70-130
5.14
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
689
u
819
119
70-130
8.73
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
1380
J
1830
124
70-130
8.20
0-20
SDG Number: 6361
Client ID: SFRA-144(6361001MSD)
Lab Sample ID: 12010968
Instrument: HRP763
Analyst: JTF
Page 25 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6361
Client ID: MB for batch 26458
Lab Sample ID: 12010964
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: 18-JUL-14
Matrix: SOLID
Data File: b22jull4a-5
Analyzed: 07/22/1412:20
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26458
12010965
b22jull4a-3
07/22/14
1046
02
LCSD for batch 26458
12010966
b22jull4a-4
07/22/14
1133
03
SFRA-144
6361001
b22jull4a-6
07/22/14
1308
04
SFRA-144(6361001 MS)
12010967
b22jull4a-7
07/22/14
1356
05
SFRA-144(6361001MSD)
12010968
b22jull4a-8
07/22/14
1444
06
SFRA-145
6361002
b22jull4a-9
07/22/14
1531
07
SFRA-146
6361003
b22jull4a-10
07/22/14
1619
08
SFRA-147
6361004
b22jull4a-l 1
07/22/14
1707
09
SFRA-148
6361005
b22jull4a-12
07/22/14
1755
10
SFRA-148
6361005
A23JUL14A-4
07/23/14
0950
Page 26 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6361
Lab Sample ID: 12010964
Client Sample: ^or batch 26458
Client ID: MB for batch 26458
Batch ID: 26460
Run Date: 07/22/2014 12:20
Data File: b22jull4a-5
Prep Batch: 26458
Prep Date: 18-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.328
Pg/g
0.328 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.14
Pg/g
0.140 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.226
Pg/g
0.226 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.236
Pg/g
0.236 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.246
Pg/g
0.246 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.328
Pg/g
0.328 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.89
Pg/g
0.890 10.0
51207-31-9
2,3,7,8-TCDF
u
.216
Pg/g
0.216 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.121
Pg/g
0.121 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.117
Pg/g
0.117 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.16
Pg/g
0.160 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.152
Pg/g
0.152 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.174
Pg/g
0.174 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.246
Pg/g
0.246 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.187
Pg/g
0.187 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.314
Pg/g
0.314 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.796
Pg/g
0.796 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
180
200
Pg/g
90.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
181
200
Pg/g
90.7
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
170
200
Pg/g
85.2
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
164
200
Pg/g
81.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
189
200
Pg/g
94.6
(23%-140%)
13C-OCDD
327
400
Pg/g
81.9
(17%-157%)
13C-2,3,7,8-TCDF
191
200
Pg/g
95.5
(24%-169%)
130-1,2,3,7,8-
PeCDF
180
200
Pg/g
90.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
191
200
Pg/g
95.6
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
175
200
Pg/g
87.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
169
200
Pg/g
84.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
174
200
Pg/g
87.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
171
200
Pg/g
85.4
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
181
200
Pg/g
90.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
182
200
Pg/g
91.1
(26%-13 8%)
3701-2,3,7,8-TCDD
20.3
20.0
Pg/g
102
(35%-197%)
Comments:
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 27 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6361
Lab Sample ID: 12010965
Client Sample: ^or batch 26458
Client ID: LCS for batch 26458
Batch ID: 26460
Run Date: 07/22/2014 10:46
Data File: b22jull4a-3
Prep Batch: 26458
Prep Date: 18-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.2
Pg/g
0.360 1.00
40321-76-4
1,2,3,7,8-PeCDD
103
Pg/g
0.268 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
105
Pg/g
0.526 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
103
Pg/g
0.496 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
109
Pg/g
0.540 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
102
Pg/g
0.724 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
206
Pg/g
1.10 10.0
51207-31-9
2,3,7,8-TCDF
21.2
Pg/g
0.256 1.00
57117-41-6
1,2,3,7,8-PeCDF
111
Pg/g
0.520 5.00
57117-31-4
2,3,4,7,8-PeCDF
109
Pg/g
0.424 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
116
Pg/g
0.662 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
117
Pg/g
0.610 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
114
Pg/g
0.678 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
125
Pg/g
0.962 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
115
Pg/g
0.710 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
118
Pg/g
1.23 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
225
Pg/g
1.44 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
181
200
Pg/g
90.6
(20%-175%)
13C-1,2,3,7,8-
PeCDD
191
200
Pg/g
95.4
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
170
200
Pg/g
84.8
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
170
200
Pg/g
84.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
196
200
Pg/g
97.9
(22%-166%)
13C-OCDD
350
400
Pg/g
87.4
(13%-199%)
13C-2,3,7,8-TCDF
193
200
Pg/g
96.5
(22%-152%)
13C-1,2,3,7,8-
PeCDF
181
200
Pg/g
90.3
(21%-192%)
130-2,3,4,7,8-
PeCDF
194
200
Pg/g
97.2
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
171
200
Pg/g
85.3
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
172
200
Pg/g
85.9
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
177
200
Pg/g
88.3
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
172
200
Pg/g
85.9
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
177
200
Pg/g
88.7
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
184
200
Pg/g
92.1
(20%-186%)
3701-2,3,7,8-TCDD
21.5
20.0
Pg/g
107
(31 %-191%)
Comments:
Page 28 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
6361
12010966
QC for batch 26458
LCSD for batch 26458
26460
07/22/2014 11:33
b22jull4a-4
26458
18-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP763
1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.4
Pg/g
0.408 1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.406 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
109
Pg/g
0.556 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
107
Pg/g
0.554 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
118
Pg/g
0.588 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
106
Pg/g
0.814 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
232
Pg/g
1.82 10.0
51207-31-9
2,3,7,8-TCDF
21.3
Pg/g
0.290 1.00
57117-41-6
1,2,3,7,8-PeCDF
111
Pg/g
0.388 5.00
57117-31-4
2,3,4,7,8-PeCDF
109
Pg/g
0.348 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
117
Pg/g
0.836 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
118
Pg/g
0.772 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
114
Pg/g
0.896 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
123
Pg/g
1.24 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
113
Pg/g
0.568 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
118
Pg/g
0.956 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
235
Pg/g
1.70 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
167
200
Pg/g
83.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
169
200
Pg/g
84.4
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
150
200
Pg/g
74.8
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
155
200
Pg/g
77.7
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
177
200
Pg/g
88.7
(22%-166%)
13C-OCDD
306
400
Pg/g
76.5
(13%-199%)
13C-2,3,7,8-TCDF
181
200
Pg/g
90.5
(22%-152%)
13C-1,2,3,7,8-
PeCDF
169
200
Pg/g
84.5
(21%-192%)
130-2,3,4,7,8-
PeCDF
177
200
Pg/g
88.6
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
155
200
Pg/g
77.6
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
157
200
Pg/g
78.4
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
158
200
Pg/g
79.1
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
158
200
Pg/g
79.1
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
164
200
Pg/g
81.9
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
170
200
Pg/g
84.9
(20%-186%)
3701-2,3,7,8-TCDD
20.7
20.0
Pg/g
104
(31 %-191%)
Comments:
Page 29 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6361
Lab Sample ID: 12010967
Client Sample: ^or batch 26458
Chent:
Date Collected:
Date Received:
TETR001
07/17/2014 09:00
07/18/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 10*4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-144(6361001MS)
26460
07/22/2014 13:56
b22jull4a-7
26458
18-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.56 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2870
Pg/g
21.2 35.8
40321-76-4
1,2,3,7,8-PeCDD
721
Pg/g
12.7 179
39227-28-6
1,2,3,4,7,8-HxCDD
734
Pg/g
27.3 179
57653-85-7
1,2,3,6,7,8-HxCDD
813
Pg/g
28.0 179
19408-74-3
1,2,3,7,8,9-HxCDD
810
Pg/g
29.3 179
35822-46-9
1,2,3,4,6,7,8-HpCDD
1160
Pg/g
40.2 179
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11300
Pg/g
88.6 358
51207-31-9
2,3,7,8-TCDF
166
Pg/g
17.2 35.8
57117-41-6
1,2,3,7,8-PeCDF
759
Pg/g
18.2 179
57117-31-4
2,3,4,7,8-PeCDF
776
Pg/g
16.3 179
70648-26-9
1,2,3,4,7,8-HxCDF
778
Pg/g
24.8 179
57II7.44.9
1,2,3,6,7,8-HxCDF
805
Pg/g
22.2 179
60851-34-5
2,3,4,6,7,8-HxCDF
810
Pg/g
26.5 179
72918-21-9
1,2,3,7,8,9-HxCDF
856
Pg/g
42.8 179
67562-39-4
1,2,3,4,6,7,8-HpCDF
956
Pg/g
20.0 179
55673-89-7
1,2,3,4,7,8,9-HpCDF
894
Pg/g
40.8 179
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1680
Pg/g
51.4 358
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1220
1430
Pg/g
85.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1230
1430
Pg/g
86.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1180
1430
Pg/g
82.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1220
1430
Pg/g
85.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1330
1430
Pg/g
92.8
(23%-140%)
13C-OCDD
2300
2860
Pg/g
80.3
(17%-157%)
13C-2,3,7,8-TCDF
1320
1430
Pg/g
92.1
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1210
1430
Pg/g
84.4
(24%-185%)
130-2,3,4,7,8-
PeCDF
1280
1430
Pg/g
89.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1210
1430
Pg/g
84.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1310
1430
Pg/g
91.7
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1270
1430
Pg/g
88.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1240
1430
Pg/g
87.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1310
1430
Pg/g
91.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1200
1430
Pg/g
83.6
(26%-13 8%)
3701-2,3,7,8-TCDD
152
143
Pg/g
106
(35%-197%)
Comments:
Page 30 of 31
-------
Cape Fear Analytical LLC
Report Date:
July 23, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6361
Lab Sample ID: 12010968
Client Sample: ^or batch 26458
Chent:
Date Collected:
Date Received:
TETR001
07/17/2014 09:00
07/18/2014 10:00
Project: TETR00114
Matrix: SOLID
%Moisture: 10*4
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-144(6361001MSD)
26460
07/22/2014 14:44
b22jull4a-8
26458
18-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.62 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 5
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2880
Pg/g
19.4 34.4
40321-76-4
1,2,3,7,8-PeCDD
788
Pg/g
10.5 172
39227-28-6
1,2,3,4,7,8-HxCDD
728
Pg/g
19.7 172
57653-85-7
1,2,3,6,7,8-HxCDD
778
Pg/g
20.0 172
19408-74-3
1,2,3,7,8,9-HxCDD
707
Pg/g
21.1 172
35822-46-9
1,2,3,4,6,7,8-HpCDD
1180
Pg/g
28.0 172
3268-87-9
1,2,3,4,6,7,8,9-OCDD
11500
Pg/g
90.0 344
51207-31-9
2,3,7,8-TCDF
174
Pg/g
13.7 34.4
57117-41-6
1,2,3,7,8-PeCDF
764
Pg/g
15.3 172
57117-31-4
2,3,4,7,8-PeCDF
734
Pg/g
14.3 172
70648-26-9
1,2,3,4,7,8-HxCDF
803
Pg/g
28.8 172
57II7.44.9
1,2,3,6,7,8-HxCDF
794
Pg/g
28.5 172
60851-34-5
2,3,4,6,7,8-HxCDF
812
Pg/g
30.3 172
72918-21-9
1,2,3,7,8,9-HxCDF
864
Pg/g
42.0 172
67562-39-4
1,2,3,4,6,7,8-HpCDF
908
Pg/g
20.0 172
55673-89-7
1,2,3,4,7,8,9-HpCDF
819
Pg/g
39.0 172
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1830
Pg/g
47.0 344
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1250
1380
Pg/g
90.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1140
1380
Pg/g
83.1
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1200
1380
Pg/g
86.9
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1220
1380
Pg/g
88.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1400
1380
Pg/g
101
(23%-140%)
13C-OCDD
2390
2760
Pg/g
86.9
(17%-157%)
13C-2,3,7,8-TCDF
1300
1380
Pg/g
94.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1190
1380
Pg/g
86.2
(24%-185%)
130-2,3,4,7,8-
PeCDF
1280
1380
Pg/g
93.3
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1260
1380
Pg/g
91.6
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1380
1380
Pg/g
100
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1310
1380
Pg/g
94.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1210
1380
Pg/g
88.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1330
1380
Pg/g
96.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1290
1380
Pg/g
93.4
(26%-13 8%)
3701-2,3,7,8-TCDD
155
138
Pg/g
113
(35%-197%)
Comments:
Page 31 of 31
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
August 05, 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6398
Dear Mr. Kinroth:
Cape Fear Analytical, LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 24, 2014. This revised data report has been prepared and reviewed in accordance with CFA's standard operating procedures. Refer to
the fractional case narrative for revision details.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at (910)
795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
problem solved
-------
Page:
Project #:
CFA Quote ft
COC Number'":
PO Number:
T
of
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number:
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Namer^^. ^ ^ Phone J/S-
Sample Analysis Requested<5) (Fill in the number of containers for each test)
Project/SiteName;jr^^
E
-*- f£t
¦3
f
Specify: 7^
TAT Requested: Normal:
Rush:
Subject to Surcharge)
Fax Results:
Yes
No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 f Level 3 / Level 4
Remarks; Are there any known hazards applicable to these samples? If so, please list the hazards
Sample ColleetioifPaMfZorie
Eastern Pacific
Central Other
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
sample is [tip
2^
Relinquished By (Signed)
Time
Received by (signed)
Date
Time
CFA PM
Method of Shipment:
' SZ*L<£Y
*ns
Date Shipped:
Airbill #:
3.<£tf JT7P?
Airbill #:
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N = Normal Sample, TB = Trip Blank, FD^ Field Duplicate,EB = Equipment Blank, MS = Matrix Spike Sample, MSD - Matrix Spike Duplicate Sample,G - Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was riot field filtered,
4.) Matrix Codes: DW=Drinking Water, GW-Groundwater, SW=Surface Water, WW=Waste Water, W=Water, ML=Misc Liquid, SO=Soil, SB=Sediment, SL=Sludge, SS=Solid Waste, O=0il, F-Filter, P^Wipe, U-Urwe, F=Fecal, N-Nasal
5.) Sample Analysis Requested: Analytical method requested (i.eJ8290B, 1668B) and number of containers provided for each (i.e. 8290B -3,1668B -1).
6.) Preservative Type: HA = Hydrochloric Acid,NI = Nitric Acid,SH = Sodium Hydroxide> SA « Sulfuric Acid, AA « Ascorbic Acid, HX = Hexane, ST «¦ Sodium Thiosulfote, If no preservative is added = leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only-
Custody Seal Intqet?
yes m)
Cooler Temp"
S'Tc
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client:
Work Order: ^
Shipping Company: ^
Date/Time Received: 2 4 JUL \4 64S O
Suspected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
•r
Samples identified as Foreign Soil?
Samples < 2x background?
us
Air Sample Receipt Specifics
Yes
NA
No
Air sample in shipment?
Air Witness
Notify RSO of any responses in this column immediately,
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
Shipping containers received intact
and sealed?
Circle Applicable:
seals broken damaged container leaking container other{describe}
Chain of Custody documents included
with shipment?
Samples requiring cold preservation
within 0-6°C?
/
F^se-h^ation Method:
;e bags) blue ice dry ice none otter (describe)
5.7'C
Aqueous samples found to have visible
solids?
Sample IDs, containers affected:
Samples requiring chemical
preservation at proper pH?
/
f-
Sample IDs, containers affected and pH observed:
If preservative added, Lot#:
Samples requiring preservation have
no residual chlorine?
Sample IDs, containers affected:
If preservative added, Lot#:
Sample IDs, tests affected:
Samples received within holding time?
Sample IDs on COC match IDs on
containers?
Sample IDs, containers affected:
Date & time of COC match date & time
on containers?
\y
/
Sample IDs, containers affected:
10
Number of containers received match
number indicated on COC?
Sample IDs, containers affected:
11
COC form is properly signed in
relinquished/received sections?
Comments:
Checklist performed by: Initials: _
: Date: _
-------
High Resolution Dioxins
and Furans Analysis
-------
Case Narrative
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6398
Revision 1
This revised report includes the confirmation data for the associated MS/MSD, which was not
included in the original report. The sample results originally reported have not changed.
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26528
Clean Up Batch Number: 26527
Extraction Batch Number: 26526
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6398001 SFRA-160
6398002 SFRA-161
12011028 Method Blank (MB)
12011029 Laboratory Control Sample (LCS)
12011030 Laboratory Control Sample Duplicate (LCSD)
12011031 6398001 (SFRA-160) Matrix Spike (MS)
12011032 6398001 (SFRA-160) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6398001 (SFRA-160) - Batch 26528 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
Two MS recoveries for this SDG were not within the acceptance limits. The failures can be
attributed to matrix interference. 12011031 (SFRA-160) - Batch 26528.
Matrix Spike Duplicate (MSD) Recovery Statement
The MSD recoveries were within the established acceptance limits.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
-------
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
-------
Sample Data Summary
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6398 CFA Work Order: 6398
Name: Erin Suhrie
Date: 05 AUG 2014
Title: Data Validator
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6398
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6398001
Date Collected:
07/23/2014 16:20
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
07/24/2014 09:50
%Moisture:
5.3
Client ID:
SFRA-160
Prep Basis:
Dry Weight
Batch ID:
26528
Method:
EPA Method 1613B
Run Date:
07/28/2014 16:07
Analyst:
JTF
Instrument:
HRP750
Data File:
A28JUL14A-4
Dilution:
1
Prep Batch:
26526
Prep Method:
SW846 3540C
Prep Date:
24-JUL-14
Prep Aliquot:
1.19 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
14.5
Pg/g
1.15
8.87
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans
Page 1 i
Certificate of Analysis
Sample Summary
SDG Number: 6398
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6398001
Date Collected:
07/23/2014 16:20
Matrix:
SOLID
Client Sample: 1613B Soil
Date Received:
07/24/2014 09:50
%Moisture:
5.3
Client ID:
SFRA-160
Prep Basis:
Dry Weight
Batch ID:
26528
Method:
EPA Method 1613B
Run Date:
07/26/2014 20:16
Analyst:
JTF
Instrument:
HRP763
Data File:
b25jull4a_4-4
Dilution:
1
Prep Batch:
26526
Prep Method:
SW846 3540C
Prep Date:
24-JUL-14
Prep Aliquot:
1.19 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
2360
Pg/g
6.30
8.87
40321-76-4
1,2,3,7,8-PeCDD
U
3.03
Pg/g
3.03
44.3
39227-28-6
1,2,3,4,7,8-HxCDD
u
7.4
Pg/g
7.40
44.3
57653-85-7
1,2,3,6,7,8-HxCDD
J
14.2
Pg/g
6.47
44.3
19408-74-3
1,2,3,7,8,9-HxCDD
u
7.24
Pg/g
7.24
44.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
291
Pg/g
16.2
44.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8300
Pg/g
50.6
88.7
51207-31-9
2,3,7,8-TCDF
16.5
Pg/g
4.79
8.87
57117-41-6
1,2,3,7,8-PeCDF
u
2.31
Pg/g
2.31
44.3
57117-31-4
2,3,4,7,8-PeCDF
J
3.02
Pg/g
2.09
44.3
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.00
Pg/g
4.45
44.3
57II7.44.9
1,2,3,6,7,8-HxCDF
u
4.06
Pg/g
4.06
44.3
60851-34-5
2,3,4,6,7,8-HxCDF
u
4.49
Pg/g
4.49
44.3
72918-21-9
1,2,3,7,8,9-HxCDF
u
7.34
Pg/g
7.34
44.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
59.6
Pg/g
7.56
44.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
15.3
Pg/g
15.3
44.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
76.3
Pg/g
13.7
88.7
Surrogate/Tracer recovery
Qual Result
Nominal Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
13C-1,2,3,6,7,8-HxCDD
13C-1,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-1,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-1,2,3,4,7,8-HxCDF
13C-1,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-1,2,3,7,8,9-HxCDF
13C-1,2,3,4,6,7,8-HpCDF
13C-1,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
1150
1210
942
1160
1080
1930
1240
1190
1300
1020
1270
1190
1070
1120
1050
187
1770
1770
1770
1770
1770
3550
1770
1770
1770
1770
1770
1770
1770
1770
1770
177
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
64.6
68.5
53.1
65.3
60.7
54.4
69.9
67.3
73.4
57.3
71.6
67.0
60.1
63.2
59.4
105
(25%-164%
(25%-181%
(32%-141%
(28%-130%
(23%-140%
(17%-157%
(24%-169%
(24%-185%
(21%-178%
(26%-152%
(26%-123%
(28%-13 6%
(29%-147%
(28%-143%
(26%-13 8%
(35%-197%
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans
Page 1 i
Certificate of Analysis
Sample Summary
SDG Number: 6398
Client:
TETR001
Project:
TETR00114
Lab Sample ID: 6398002
Date Collected:
07/23/2014 16:30
Matrix:
SOLID
Client Sample: 1613B Soil
Date Received:
07/24/2014 09:50
%Moisture:
5.2
Client ID:
SFRA-161
Prep Basis:
Dry Weight
Batch ID:
26528
Method:
EPA Method 1613B
Run Date:
07/26/2014 22:39
Analyst:
JTF
Instrument:
HRP763
Data File:
b25jull4a_4-7
Dilution:
1
Prep Batch:
26526
Prep Method:
SW846 3540C
Prep Date:
24-JUL-14
Prep Aliquot:
1.09 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
340
Pg/g
3.66
9.68
40321-76-4
1,2,3,7,8-PeCDD
U
2.05
Pg/g
2.05
48.4
39227-28-6
1,2,3,4,7,8-HxCDD
u
5.67
Pg/g
5.67
48.4
57653-85-7
1,2,3,6,7,8-HxCDD
J
9.51
Pg/g
5.30
48.4
19408-74-3
1,2,3,7,8,9-HxCDD
u
5.79
Pg/g
5.79
48.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
267
Pg/g
12.4
48.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5920
Pg/g
46.1
96.8
51207-31-9
2,3,7,8-TCDF
J
6.20
Pg/g
3.25
9.68
57117-41-6
1,2,3,7,8-PeCDF
u
2.13
Pg/g
2.13
48.4
57117-31-4
2,3,4,7,8-PeCDF
u
1.93
Pg/g
1.93
48.4
70648-26-9
1,2,3,4,7,8-HxCDF
J
3.79
Pg/g
2.63
48.4
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.36
Pg/g
2.36
48.4
60851-34-5
2,3,4,6,7,8-HxCDF
u
3.37
Pg/g
3.37
48.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
4.32
Pg/g
4.32
48.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
45.9
Pg/g
4.30
48.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
8
Pg/g
8.00
48.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
114
Pg/g
15.7
96.8
Surrogate/Tracer recovery
Qual Result
Nominal Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
13C-1,2,3,4,7,8-HxCDD
13C-1,2,3,6,7,8-HxCDD
13C-1,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-1,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-1,2,3,4,7,8-HxCDF
13C-1,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-1,2,3,7,8,9-HxCDF
13C-1,2,3,4,6,7,8-HpCDF
13C-1,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
1650
1720
1400
1650
1620
3000
1780
1670
1780
1500
1790
1670
1590
1710
1550
192
1940
1940
1940
1940
1940
3870
1940
1940
1940
1940
1940
1940
1940
1940
1940
194
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
Pg/g
85.2
89.0
72.4
85.4
83.9
77.4
92.2
86.3
92.0
77.5
92.4
86.0
82.0
88.5
80.0
99.3
(25%-164%
(25%-181%
(32%-141%
(28%-130%
(23%-140%
(17%-157%
(24%-169%
(24%-185%
(21%-178%
(26%-152%
(26%-123%
(28%-13 6%
(29%-147%
(28%-143%
(26%-13 8%
(35%-197%
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
-------
Quality Control
Summary
-------
( (ipc Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6398
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12011029
LCS for batch 26526
12011030
LCSD for batch 26526
12011028
MB for batch 26526
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
59.5
53.2
43.2
53.9
42.7
27.9
66.3
54.2
57.8
50.1
57.3
53.5
44.5
48.2
35.1
99.5
85.8
87.7
71.6
91.6
84.1
71.8
92.8
84.6
94.4
77.1
98.9
91.6
82.6
88.2
78.5
91.0
86.0
87.2
67.6
89.1
79.8
63.8
94.4
87.1
94.8
81.9
93.5
88.2
80.7
84.6
75.8
93.6
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6398001
SFRA-160
13C-2,3,7,8-TCDD
64.6
(25%-164%)
-------
( (ipc Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6398
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6398001
SFRA-160
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
68.5
53.1
65.3
60.7
54.4
69.9
67.3
73.4
57.3
71.6
67.0
60.1
63.2
59.4
105
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12011031
SFRA-160(639800 IMS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
85.7
92.4
77.8
88.7
87.5
83.9
91.8
87.5
96.8
80.8
96.0
90.4
84.2
91.9
85.5
104
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12011032
SFRA-160(6398001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
91.1
95.8
81.1
90.8
92.9
85.8
94.8
92.6
103
84.1
98.2
91.6
84.7
98.1
85.3
108
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6398002
SFRA-161
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
85.2
89.0
(25%-
(25%-
64%)
81%)
-------
( (ipc Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 3 of 3
Surrogate Recovery Report
SDG Number: 6398
Matrix Type: SOLID
Sample ID Client ID
6398002 SFRA-161
Surrogate
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
(%)
Limits
72.4
(32%-
¦141%)
85.4
(28%-
¦130%)
83.9
(23%-
¦140%)
77.4
(17%-
¦157%)
92.2
(24%-
¦169%)
86.3
(24%-
¦185%)
92.0
(21%-
¦178%)
77.5
(26%-
¦152%)
92.4
(26%-
¦123%)
86.0
(28%-
¦136%)
82.0
(29%-
¦147%)
88.5
(28%-
¦143%)
80.0
(26%-
¦138%)
99.3
(35%-
¦197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
-------
Cape Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 07/26/2014 17:53 Dilution: 1
Prep Batch ID:26526
Batch ID: 26528
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.7
103
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
98.8
98.8
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
103
103
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
94.3
94.3
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
102
102
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
95.0
95
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
192
96
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
20.5
102
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
108
108
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
111
111
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
116
116
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
115
115
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
113
113
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
115
115
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
108
108
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
120
120
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
222
111
63-170
SDG Number: 6398
Client ID: LCS for batch 26526
Lab Sample ID: 12011029
Instrument: HRP763
Analyst: JTF
-------
Cape Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 07/26/2014 18:40 Dilution: 1
Prep Batch ID:26526
Batch ID: 26528
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.3
101
67-158
1.89
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
103
103
70-142
4.12
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
98.8
98.8
70-164
3.76
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
102
102
76-134
7.60
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
108
108
64-162
5.11
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
6.12
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
189
94.5
78-144
1.49
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
21.3
106
75-158
3.85
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
109
109
80-134
0.665
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
107
107
68-160
3.72
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
114
114
72-134
1.53
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
114
114
84-130
1.12
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
110
110
70-156
2.44
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
119
119
78-130
3.29
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
115
115
82-122
6.76
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
115
115
78-138
4.24
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
233
116
63-170
4.80
0-20
SDG Number: 6398
Client ID: LCSD for batch 26526
Lab Sample ID: 12011030
Instrument: HRP763
Analyst: JTF
-------
Cape Fear Analytical LLC
Report Date: August 5,2014
SDG Number:
Client ID:
Lab Sample ID:
Instrument:
Analyst:
6398
SFRA-160(6398001MS)
12011031
HRP750
JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Page 1 of 2
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 5.3
Analysis Date: 07/29/2014 18:15
Prep Batch ID:26526
Batch ID: 26528
Dilution: 1
CAS No.
Parmname
Amount
Added
Pg/g
Spike
Cone.
Pg/g
Recovery Acceptance
o/0 Limits
2,3,7,8-TCDF
-------
Cape Fear Analytical LLC
Report Date: August 5,2014
SDG Number: 6398
Client ID: SFRA-160(6398001MSD)
Lab Sample ID: 12011032
Instrument: HRP750
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Page 2 of 2
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 5.3
Analysis Date: 07/29/2014 18:34
Prep Batch ID:26526
Batch ID: 26528
Dilution: 1
CAS No.
Parmname
Amount
Added
Pg/g
Spike
Cone.
Pg/g
Recovery Acceptance RPD Acceptance
o/0 Limits o/0 Limits
MSD 2,3,7,8-TCDF
-------
Cape Fear Analytical LLC
Report Date: August 5,2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
164
2150
-132 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
818
U
816
99.8
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
818
U
768
93.9
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
818
J
881
106
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
818
U
885
108
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
818
1120
102
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
1640
9320
62 *
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
818
u
898
110
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
818
J
877
107
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
818
J
936
114
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
818
u
923
113
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
818
u
905
111
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
818
u
962
118
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
818
971
111
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
818
u
947
116
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
1640
J
1910
112
70-130
SDG Number: 6398
Client ID: SFRA-160(6398001MS)
Lab Sample ID: 12011031
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 5.3
Analysis Date: 07/26/2014 21:03
Prep Batch ID:26526
Batch ID: 26528
-------
Cape Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 5.3
Analysis Date: 07/26/2014 21:51 Dilution: 1
Prep Batch ID:26526
Batch ID: 26528
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
174
2540
102
70-130
16.8
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
872
U
866
99.2
70-130
5.87
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
872
U
858
98.4
70-130
11.1
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
872
J
891
101
70-130
1.10
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
872
U
932
107
70-130
5.12
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
872
1300
116
70-130
14.8
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
1740
9730
81.9
70-130
4.35
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
872
u
933
107
70-130
3.84
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
872
J
903
103
70-130
2.86
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
872
J
1000
114
70-130
6.72
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
872
u
973
112
70-130
5.25
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
872
u
996
114
70-130
9.49
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
872
u
1020
117
70-130
6.01
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
872
1060
115
70-130
8.67
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
872
u
1040
119
70-130
8.91
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
1740
J
2110
117
70-130
9.85
0-20
SDG Number: 6398
Client ID: SFRA-160(6398001MSD)
Lab Sample ID: 12011032
Instrument: HRP763
Analyst: JTF
-------
Cape Fear Analytical LLC
Report Date: August 5, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6398
Client ID: MB for batch 26526
Lab Sample ID: 12011028
Column:
Client: TETR001
Instrument ID: HRP763
Prep Date: 24-JUL-14
Matrix: SOLID
Data File: b25jull4a 4-3
Analyzed: 07/26/1419:28
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26526
12011029
b25jull4a_4-l
07/26/14
1753
02
LCSD for batch 26526
12011030
b25jull4a_4-2
07/26/14
1840
03
SFRA-160
6398001
b25jull4a_4-4
07/26/14
2016
04
SFRA-160(639800 IMS)
12011031
b25jull4a_4-5
07/26/14
2103
05
SFRA-160(6398001MSD)
12011032
b25jull4a_4-6
07/26/14
2151
06
SFRA-161
6398002
b25jull4a_4-7
07/26/14
2239
07
SFRA-160
6398001
A28JUL14A-4
07/28/14
1607
08
SFRA-160(639800 IMS)
12011031
A29JUL14A-13
07/29/14
1815
09
SFRA-160(6398001MSD)
12011032
A29JUL14A-14
07/29/14
1834
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6398
12011028
QC for batch 26526
MB for batch 26526
26528
07/26/2014 19:28
b25jull4a 4-3
26526
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
24-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.254
Pg/g
0.254
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.149
Pg/g
0.149
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.224
Pg/g
0.224
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.198
Pg/g
0.198
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.22
Pg/g
0.220
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.408
Pg/g
0.408
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.89
Pg/g
0.890
10.0
51207-31-9
2,3,7,8-TCDF
J
0.332
Pg/g
0.220
1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.14
Pg/g
0.140
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.116
Pg/g
0.116
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.208
Pg/g
0.208
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.195
Pg/g
0.195
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.214
Pg/g
0.214
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.378
Pg/g
0.378
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.246
Pg/g
0.246
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.484
Pg/g
0.484
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
1.1
Pg/g
1.10
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
172
200
Pg/g
86.0
(25 %-164%)
13C-1,2,3,7,8-PeCDD
174
200
Pg/g
87.2
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
135
200
Pg/g
67.6
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
178
200
Pg/g
89.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
160
200
Pg/g
79.8
(23%-140%)
13C-OCDD
255
400
Pg/g
63.8
(17%-157%)
13C-2,3,7,8-TCDF
189
200
Pg/g
94.4
(24%-169%)
13C-1,2,3,7,8-PeCDF
174
200
Pg/g
87.1
(24%-185%)
13C-2,3,4,7,8-PeCDF
190
200
Pg/g
94.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
164
200
Pg/g
81.9
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
187
200
Pg/g
93.5
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
176
200
Pg/g
88.2
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
169
200
Pg/g
84.6
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
152
200
Pg/g
75.8
(26%-13 8%)
37Cl-2,3,7,8-TCDD
18.7
20.0
Pg/g
93.6
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6398
12011029
QC for batch 26526
LCS for batch 26526
26528
07/26/2014 17:53
b25jull4a 4-1
26526
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
24-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.7
Pg/g
0.468
1.00
40321-76-4
1,2,3,7,8-PeCDD
98.8
Pg/g
0.712
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
103
Pg/g
1.99
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
94.3
Pg/g
1.75
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
102
Pg/g
1.96
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.0
Pg/g
3.00
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
192
Pg/g
4.50
10.0
51207-31-9
2,3,7,8-TCDF
20.5
Pg/g
0.380
1.00
57117-41-6
1,2,3,7,8-PeCDF
108
Pg/g
0.896
5.00
57117-31-4
2,3,4,7,8-PeCDF
111
Pg/g
0.790
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
116
Pg/g
2.00
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
115
Pg/g
1.83
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
113
Pg/g
2.12
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
115
Pg/g
4.00
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
108
Pg/g
1.77
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
120
Pg/g
3.68
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
222
Pg/g
6.94
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
119
200
Pg/g
59.5
(20%-175%)
13C-1,2,3,7,8-PeCDD
106
200
Pg/g
53.2
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
86.5
200
Pg/g
43.2
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
108
200
Pg/g
53.9
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
85.5
200
Pg/g
42.7
(22%-166%)
13C-OCDD
112
400
Pg/g
27.9
(13%-199%)
13C-2,3,7,8-TCDF
133
200
Pg/g
66.3
(22%-152%)
13C-1,2,3,7,8-PeCDF
108
200
Pg/g
54.2
(21%-192%)
13C-2,3,4,7,8-PeCDF
116
200
Pg/g
57.8
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
100
200
Pg/g
50.1
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
115
200
Pg/g
57.3
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
107
200
Pg/g
53.5
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
89.0
200
Pg/g
44.5
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
96.3
200
Pg/g
48.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
70.3
200
Pg/g
35.1
(20%-186%)
37Cl-2,3,7,8-TCDD
19.9
20.0
Pg/g
99.5
(31 %-191%)
Comments:
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6398
12011030
QC for batch 26526
LCSD for batch 26526
26528
07/26/2014 18:40
b25jull4a 4-2
26526
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
24-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.3
Pg/g
0.374
1.00
40321-76-4
1,2,3,7,8-PeCDD
103
Pg/g
0.452
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.8
Pg/g
1.15
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
1.04
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
108
Pg/g
1.15
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
1.78
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
189
Pg/g
2.64
10.0
51207-31-9
2,3,7,8-TCDF
21.3
Pg/g
0.286
1.00
57117-41-6
1,2,3,7,8-PeCDF
109
Pg/g
0.512
5.00
57117-31-4
2,3,4,7,8-PeCDF
107
Pg/g
0.444
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
114
Pg/g
1.24
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
114
Pg/g
1.08
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
110
Pg/g
1.25
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
119
Pg/g
2.10
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
115
Pg/g
1.16
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
115
Pg/g
2.24
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
233
Pg/g
3.20
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
172
200
Pg/g
85.8
(20%-175%)
13C-1,2,3,7,8-PeCDD
175
200
Pg/g
87.7
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
143
200
Pg/g
71.6
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
183
200
Pg/g
91.6
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
168
200
Pg/g
84.1
(22%-166%)
13C-OCDD
287
400
Pg/g
71.8
(13%-199%)
13C-2,3,7,8-TCDF
186
200
Pg/g
92.8
(22%-152%)
13C-1,2,3,7,8-PeCDF
169
200
Pg/g
84.6
(21%-192%)
13C-2,3,4,7,8-PeCDF
189
200
Pg/g
94.4
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
154
200
Pg/g
77.1
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
198
200
Pg/g
98.9
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
183
200
Pg/g
91.6
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
165
200
Pg/g
82.6
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
176
200
Pg/g
88.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
157
200
Pg/g
78.5
(20%-186%)
37Cl-2,3,7,8-TCDD
18.2
20.0
Pg/g
91.0
(31 %-191%)
Comments:
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6398
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
12011031
Date Collected:
07/23/2014 16:20
Matrix:
SOLID
Client Sample:
QC for batch 26526
Date Received:
07/24/2014 09:50
%Moisture:
5.3
Client ID:
SFRA-160(6398001MS)
Prep Basis:
Dry Weight
Batch ID:
26528
Method:
EPA Method 1613B
Run Date:
07/29/2014 18:15
Analyst:
JTF
Instrument:
HRP750
Data File:
A29JUL14A-13
Dilution:
1
Prep Batch:
26526
Prep Method:
SW846 3540C
Prep Date:
24-JUL-14
Prep Aliquot:
1.29 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
168
Pg/g
3.40
8.18
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6398
12011031
QC for batch 26526
SFRA-160(6398001MS)
26528
07/26/2014 21:03
b25jull4a 4-5
26526
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/23/2014 16:20
07/24/2014 09:50
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
5.3
Dry Weight
HRP763
1
Prep Date:
24-JUL-14
Prep Aliquot:
1.29 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
2150
Pg/g
5.63
8.18
40321-76-4
1,2,3,7,8-PeCDD
816
Pg/g
5.60
40.9
39227-28-6
1,2,3,4,7,8-HxCDD
768
Pg/g
9.15
40.9
57653-85-7
1,2,3,6,7,8-HxCDD
881
Pg/g
9.11
40.9
19408-74-3
1,2,3,7,8,9-HxCDD
885
Pg/g
9.67
40.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
1120
Pg/g
15.3
40.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9320
Pg/g
43.4
81.8
57117-41-6
1,2,3,7,8-PeCDF
898
Pg/g
5.01
40.9
57117-31-4
2,3,4,7,8-PeCDF
877
Pg/g
4.16
40.9
70648-26-9
1,2,3,4,7,8-HxCDF
936
Pg/g
13.3
40.9
57II7.44.9
1,2,3,6,7,8-HxCDF
923
Pg/g
11.3
40.9
60851-34-5
2,3,4,6,7,8-HxCDF
905
Pg/g
13.5
40.9
72918-21-9
1,2,3,7,8,9-HxCDF
962
Pg/g
22.6
40.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
971
Pg/g
11.3
40.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
947
Pg/g
19.1
40.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1910
Pg/g
37.0
81.8
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1400
1640
Pg/g
85.7
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1510
1640
Pg/g
92.4
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1270
1640
Pg/g
77.8
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1450
1640
Pg/g
88.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1430
1640
Pg/g
87.5
(23%-140%)
13C-OCDD
2750
3270
Pg/g
83.9
(17%-157%)
13C-2,3,7,8-TCDF
1500
1640
Pg/g
91.8
(24%-169%)
13C-1,2,3,7,8-PeCDF
1430
1640
Pg/g
87.5
(24%-185%)
13C-2,3,4,7,8-PeCDF
1580
1640
Pg/g
96.8
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1320
1640
Pg/g
80.8
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1570
1640
Pg/g
96.0
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1480
1640
Pg/g
90.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1380
1640
Pg/g
84.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1500
1640
Pg/g
91.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1400
1640
Pg/g
85.5
(26%-13 8%)
37Cl-2,3,7,8-TCDD
171
164
Pg/g
104
(35%-197%)
Comments:
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6398
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
12011032
Date Collected:
07/23/2014 16:20
Matrix:
SOLID
Client Sample:
QC for batch 26526
Date Received:
07/24/2014 09:50
%Moisture:
5.3
Client ID:
SFRA-160(6398001MSD)
Prep Basis:
Dry Weight
Batch ID:
26528
Method:
EPA Method 1613B
Run Date:
07/29/2014 18:34
Analyst:
JTF
Instrument:
HRP750
Data File:
A29JUL14A-14
Dilution:
1
Prep Batch:
26526
Prep Method:
SW846 3540C
Prep Date:
24-JUL-14
Prep Aliquot:
1.21 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
181
Pg/g
3.84
8.72
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6398
12011032
QC for batch 26526
SFRA-160(6398001MSD)
26528
07/26/2014 21:51
b25jull4a 4-6
26526
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Date Collected:
Date Received:
Method:
Analyst:
TETR001
07/23/2014 16:20
07/24/2014 09:50
EPA Method 1613B
JTF
Project:
Matrix:
%Moisture:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
5.3
Dry Weight
HRP763
1
Prep Date:
24-JUL-14
Prep Aliquot:
1.21 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
2540
Pg/g
7.10
8.72
40321-76-4
1,2,3,7,8-PeCDD
866
Pg/g
5.81
43.6
39227-28-6
1,2,3,4,7,8-HxCDD
858
Pg/g
8.93
43.6
57653-85-7
1,2,3,6,7,8-HxCDD
891
Pg/g
8.83
43.6
19408-74-3
1,2,3,7,8,9-HxCDD
932
Pg/g
9.39
43.6
35822-46-9
1,2,3,4,6,7,8-HpCDD
1300
Pg/g
16.3
43.6
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9730
Pg/g
50.9
87.2
57117-41-6
1,2,3,7,8-PeCDF
933
Pg/g
4.54
43.6
57117-31-4
2,3,4,7,8-PeCDF
903
Pg/g
4.01
43.6
70648-26-9
1,2,3,4,7,8-HxCDF
1000
Pg/g
13.4
43.6
57II7.44.9
1,2,3,6,7,8-HxCDF
973
Pg/g
12.0
43.6
60851-34-5
2,3,4,6,7,8-HxCDF
996
Pg/g
13.2
43.6
72918-21-9
1,2,3,7,8,9-HxCDF
1020
Pg/g
22.2
43.6
67562-39-4
1,2,3,4,6,7,8-HpCDF
1060
Pg/g
8.95
43.6
55673-89-7
1,2,3,4,7,8,9-HpCDF
1040
Pg/g
19.2
43.6
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2110
Pg/g
26.0
87.2
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
1590
1740
Pg/g
91.1
(25 %-164%)
13C-1,2,3,7,8-PeCDD
1670
1740
Pg/g
95.8
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
1410
1740
Pg/g
81.1
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
1580
1740
Pg/g
90.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1620
1740
Pg/g
92.9
(23%-140%)
13C-OCDD
2990
3490
Pg/g
85.8
(17%-157%)
13C-2,3,7,8-TCDF
1650
1740
Pg/g
94.8
(24%-169%)
13C-1,2,3,7,8-PeCDF
1620
1740
Pg/g
92.6
(24%-185%)
13C-2,3,4,7,8-PeCDF
1800
1740
Pg/g
103
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
1470
1740
Pg/g
84.1
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
1710
1740
Pg/g
98.2
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
1600
1740
Pg/g
91.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1480
1740
Pg/g
84.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1710
1740
Pg/g
98.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1490
1740
Pg/g
85.3
(26%-13 8%)
37Cl-2,3,7,8-TCDD
188
174
Pg/g
108
(35%-197%)
Comments:
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
July 29. 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6398
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 24, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of27
problem solved
-------
Page; _
Project #:
CFA Quote #:
COC Number0':.
PO Number:
T
of
Client Namer^fe, ^ ly
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number:
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
project/Site &*&{/£+»**( Jrfc
Phone
Sample Analysis Requested(5) (Fill in the number of containers for each test)
Ctc
a
^Fax#;
is Address:
[IjCoHectedby: £ C&^A.
Send Results To;
' ?»• «j«^r ~ fa ^ u-j I _/
(tin r%H6«%T
Sample ID
* For composites - indicate start and stop date/time
1 l £
rck/h
*Da!e Co] leered
(mm-dd-yy)
~Time
Collected
(Military)
(hhmm)
/f4a^ir»4e^.ci
QC Code
(i>
Field
Filtered®
Sample
Matrix w
85
s
\
<-- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
S /jCo
i/
f£f
wf
f£3t>
X- Specify: HI
TAT Requested: Normal:
Rush:
Subject to Surcharge)
Fax Results:
Yes
No
Circle Deliverable: C of A I QC Summary / Level 1 / Level 2 f Level 3 / Level 4
Remarks: Are there arty known hazards applicable to these samples? If so, please list the hazards
Sample C"»"~*'"iTyJjL. 4$Au Ms UkJ KitM (A:T0
CFA PM:
Method of Shipment:
CWafe r
'
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Cient:
Work Order:
Shipping Company: ^ ^
Date/Time Received: 2 4 JUL t <4 64S O
Suspected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
r-"
Samples identified as Foreign Soil?
Samples < 2x background?
* Notify RSO of any responses in this column immediateiy.
Air Sample Receipt Specifics
Yes
NA
No
Air sample in shipment?
Sample Receipt Criteria
Yes
ISTA
No
Comments/Qualifiers {required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
/
Circie Applicable:
seals broken damaged container leaking container otherfdeseribe)
2
Chain of Custody documents included
with shipment?
/
3
Samples requiring cold preservation
within 0-6°C?
/
R^s§t^ation Method:
fce bagsj blue ice dry ice none other (describe)
^ 5.TC
4
Aqueous samples found to have visible
solids?
Sample iDs, containers affected:
5
Samples requiring chemical
preservation at proper pH?
c/
/
/ ¦
Sample IDs, containers affected and pH observed:
If preservative added, Lot#:
6
Samples requiring preservation have
no residual chlorine?
0
/
Sample IDs, containers affected:
If preservative added, lot#:
7
Samples received within holding time?
/ -
Sample IDs, tests affected:
8
Sample IDs on COC match IDs on
containers?
/ :
Sample IDs, containers affected:
9
Date & time of COC match date & time
on containers?
KS
X
Sample IDs, containers affected:
10
Number of containers received match
number indicated on COC?
Sample IDs, containers affected:
11
COC form Is properly signed in
relinquished/received sections?
Comments:
Checklist performed by: Initials:
Page 3 of27
_ Date: _
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of 27
-------
Case Narrative
Page 5 of27
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6398
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26528
Clean Up Batch Number: 26527
Extraction Batch Number: 26526
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID
Client ID
6398001
SFRA-160
6398002
SFRA-161
12011028
Method Blank (MB)
12011029
Laboratory Control Sample (LCS)
12011030
Laboratory Control Sample Duplicate (LCSD)
12011031
6398001 (SFRA-160) Matrix Spike (MS)
12011032
6398001 (SFRA-160) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Page 6 of 27
-------
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
Sample 6398001 (SFRA-160) - Batch 26528 was selected for analysis as the matrix spike and
matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
Two MS recoveries for this SDG were not within the acceptance limits. The failures can be
attributed to matrix interference. 12011031 (SFRA-160) - Batch 26528.
Matrix Spike Duplicate (MSD) Recovery Statement
The MSD recoveries were within the established acceptance limits.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD(s) between the MS and MSD met the acceptance limits.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Page 7 of27
-------
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present.
Miscellaneous Information
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of 27
-------
Sample Data Summary
Page 9 of 27
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6398 CFA Work Order: 6398
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 29 JUL 2014 Title: Data Validator
Page 10 of 27
-------
Cape Fear Analytical LLC
Report Date: July 29, 2014
Hi-Res Dioxins/Furans Page 1 of 1
Certificate of Analysis
Sample Summary
SDG Number:
6398
Client:
TETR001
Project:
TETR00114
Lab Sample ID:
6398001
Date Collected:
07/23/2014 16:20
Matrix:
SOLID
Client Sample:
1613B Soil
Date Received:
07/24/2014 09:50
%Moisture:
5.3
Client ID:
SFRA-160
Prep Basis:
Dry Weight
Batch ID:
26528
Method:
EPA Method 1613B
Run Date:
07/28/2014 16:07
Analyst:
JTF
Instrument:
HRP750
Data File:
A28JUL14A-4
Dilution:
1
Prep Batch:
26526
Prep Method:
SW846 3540C
Prep Date:
24-JUL-14
Prep Aliquot:
1.19 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
51207-31-9 2,3,7,8-TCDF
14.5
Pg/g
1.15
8.87
Surrogate/Tracer recovery Qual Result Nominal Units Recovery % Acceptable Limits
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6398
Lab Sample ID: 6398001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/23/2014 16:20
07/24/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 5.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-160
26528
07/26/2014 20:16
b25jull4a_4-4
26526
24-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.19 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2360
Pg/g
6.30 8.87
40321-76-4
1,2,3,7,8-PeCDD
U
3.03
Pg/g
3.03 44.3
39227-28-6
1,2,3,4,7,8-HxCDD
u
7.4
Pg/g
7.40 44.3
57653-85-7
1,2,3,6,7,8-HxCDD
J
14.2
Pg/g
6.47 44.3
19408-74-3
1,2,3,7,8,9-HxCDD
u
7.24
Pg/g
7.24 44.3
35822-46-9
1,2,3,4,6,7,8-HpCDD
291
Pg/g
16.2 44.3
3268-87-9
1,2,3,4,6,7,8,9-OCDD
8300
Pg/g
50.6 88.7
51207-31-9
2,3,7,8-TCDF
16.5
Pg/g
4.79 8.87
57117-41-6
1,2,3,7,8-PeCDF
u
2.31
Pg/g
2.31 44.3
57117-31-4
2,3,4,7,8-PeCDF
J
3.02
Pg/g
2.09 44.3
70648-26-9
1,2,3,4,7,8-HxCDF
J
6.00
Pg/g
4.45 44.3
57II7.44.9
1,2,3,6,7,8-HxCDF
u
4.06
Pg/g
4.06 44.3
60851-34-5
2,3,4,6,7,8-HxCDF
u
4.49
Pg/g
4.49 44.3
72918-21-9
1,2,3,7,8,9-HxCDF
u
7.34
Pg/g
7.34 44.3
67562-39-4
1,2,3,4,6,7,8-HpCDF
59.6
Pg/g
7.56 44.3
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
15.3
Pg/g
15.3 44.3
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
76.3
Pg/g
13.7 88.7
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1150
1770
Pg/g
64.6
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1210
1770
Pg/g
68.5
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
942
1770
Pg/g
53.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1160
1770
Pg/g
65.3
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1080
1770
Pg/g
60.7
(23%-140%)
13C-OCDD
1930
3550
Pg/g
54.4
(17%-157%)
13C-2,3,7,8-TCDF
1240
1770
Pg/g
69.9
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1190
1770
Pg/g
67.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1300
1770
Pg/g
73.4
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1020
1770
Pg/g
57.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1270
1770
Pg/g
71.6
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1190
1770
Pg/g
67.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1070
1770
Pg/g
60.1
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1120
1770
Pg/g
63.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1050
1770
Pg/g
59.4
(26%-13 8%)
3701-2,3,7,8-TCDD
187
177
Pg/g
105
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6398
Lab Sample ID: 6398002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/23/2014 16:30
07/24/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 5.2
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-161
26528
07/26/2014 22:39
b25jull4a_4-7
26526
24-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.09 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
340
Pg/g
3.66 9.68
40321-76-4
1,2,3,7,8-PeCDD
U
2.05
Pg/g
2.05 48.4
39227-28-6
1,2,3,4,7,8-HxCDD
u
5.67
Pg/g
5.67 48.4
57653-85-7
1,2,3,6,7,8-HxCDD
J
9.51
Pg/g
5.30 48.4
19408-74-3
1,2,3,7,8,9-HxCDD
u
5.79
Pg/g
5.79 48.4
35822-46-9
1,2,3,4,6,7,8-HpCDD
267
Pg/g
12.4 48.4
3268-87-9
1,2,3,4,6,7,8,9-OCDD
5920
Pg/g
46.1 96.8
51207-31-9
2,3,7,8-TCDF
J
6.20
Pg/g
3.25 9.68
57117-41-6
1,2,3,7,8-PeCDF
u
2.13
Pg/g
2.13 48.4
57117-31-4
2,3,4,7,8-PeCDF
u
1.93
Pg/g
1.93 48.4
70648-26-9
1,2,3,4,7,8-HxCDF
J
3.79
Pg/g
2.63 48.4
57II7.44.9
1,2,3,6,7,8-HxCDF
u
2.36
Pg/g
2.36 48.4
60851-34-5
2,3,4,6,7,8-HxCDF
u
3.37
Pg/g
3.37 48.4
72918-21-9
1,2,3,7,8,9-HxCDF
u
4.32
Pg/g
4.32 48.4
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
45.9
Pg/g
4.30 48.4
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
8
Pg/g
8.00 48.4
39001-02-0
1,2,3,4,6,7,8,9-OCDF
114
Pg/g
15.7 96.8
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1650
1940
Pg/g
85.2
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1720
1940
Pg/g
89.0
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1400
1940
Pg/g
72.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1650
1940
Pg/g
85.4
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1620
1940
Pg/g
83.9
(23%-140%)
13C-OCDD
3000
3870
Pg/g
77.4
(17%-157%)
13C-2,3,7,8-TCDF
1780
1940
Pg/g
92.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1670
1940
Pg/g
86.3
(24%-185%)
130-2,3,4,7,8-
PeCDF
1780
1940
Pg/g
92.0
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1500
1940
Pg/g
77.5
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1790
1940
Pg/g
92.4
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1670
1940
Pg/g
86.0
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1590
1940
Pg/g
82.0
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1710
1940
Pg/g
88.5
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1550
1940
Pg/g
80.0
(26%-13 8%)
3701-2,3,7,8-TCDD
192
194
Pg/g
99.3
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 13 of 27
-------
Quality Control
Summary
Page 14 of 27
-------
( ape Fear \lltllytictll LLC Report Date: July 29,2014
Hi-Res Dioxins/Furans Page 1 of 3
Surrogate Recovery Report
SDG Number: 6398
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12011029
LCS for batch 26526
12011030
LCSD for batch 26526
12011028
MB for batch 26526
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
59.5
53.2
43.2
53.9
42.7
27.9
66.3
54.2
57.8
50.1
57.3
53.5
44.5
48.2
35.1
99.5
85.8
87.7
71.6
91.6
84.1
71.8
92.8
84.6
94.4
77.1
98.9
91.6
82.6
88.2
78.5
91.0
86.0
87.2
67.6
89.1
79.8
63.8
94.4
87.1
94.8
81.9
93.5
88.2
80.7
84.6
75.8
93.6
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6398001
SFRA-160
13C-2,3,7,8-TCDD
64.6
(25%-164%)
Page 15 of 27
-------
( ape Fear \lltllytictll LLC Report Date: July 29,2014
Hi-Res Dioxins/Furans Page 2 of 3
Surrogate Recovery Report
SDG Number: 6398
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
6398001
SFRA-160
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
68.5
53.1
65.3
60.7
54.4
69.9
67.3
73.4
57.3
71.6
67.0
60.1
63.2
59.4
105
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12011031
SFRA-160(639800 IMS)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
85.7
92.4
77.8
88.7
87.5
83.9
91.8
87.5
96.8
80.8
96.0
90.4
84.2
91.9
85.5
104
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
12011032
SFRA-160(6398001MSD)
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
91.1
95.8
81.1
90.8
92.9
85.8
94.8
92.6
103
84.1
98.2
91.6
84.7
98.1
85.3
108
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
64%)
81%)
41%)
30%)
40%)
57%)
69%)
85%)
78%)
52%)
23%)
36%)
47%)
43%)
38%)
97%)
6398002
SFRA-161
13C-2,3,7,8-TCDD
13C-1,2,3,7,8-PeCDD
85.2
89.0
(25%-
(25%-
64%)
81%)
Page 16 of 27
-------
( ape Fear \lltllytictll LLC Report Date: July 29,2014
Hi-Res Dioxins/Furans Page 3 of 3
Surrogate Recovery Report
SDG Number: 6398
Matrix Type: SOLID
Sample ID Client ID
6398002 SFRA-161
Surrogate
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
(%)
Limits
72.4
(32%-
¦141%)
85.4
(28%-
¦130%)
83.9
(23%-
¦140%)
77.4
(17%-
¦157%)
92.2
(24%-
¦169%)
86.3
(24%-
¦185%)
92.0
(21%-
¦178%)
77.5
(26%-
¦152%)
92.4
(26%-
¦123%)
86.0
(28%-
¦136%)
82.0
(29%-
¦147%)
88.5
(28%-
¦143%)
80.0
(26%-
¦138%)
99.3
(35%-
¦197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 17 of 27
-------
Cape Fear Analytical LLC
Report Date: July 29,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 07/26/2014 17:53 Dilution: 1
Prep Batch ID:26526
Batch ID: 26528
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
20.7
103
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
98.8
98.8
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
103
103
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
94.3
94.3
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
102
102
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
95.0
95
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
192
96
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
20.5
102
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
108
108
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
111
111
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
116
116
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
115
115
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
113
113
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
115
115
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
108
108
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
120
120
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
222
111
63-170
SDG Number: 6398
Client ID: LCS for batch 26526
Lab Sample ID: 12011029
Instrument: HRP763
Analyst: JTF
Page 18 of 27
-------
Cape Fear Analytical LLC
Report Date: July 29,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 07/26/2014 18:40 Dilution: 1
Prep Batch ID:26526
Batch ID: 26528
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
20.3
101
67-158
1.89
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
103
103
70-142
4.12
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
98.8
98.8
70-164
3.76
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
102
102
76-134
7.60
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
108
108
64-162
5.11
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
101
101
70-140
6.12
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
189
94.5
78-144
1.49
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
21.3
106
75-158
3.85
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
109
109
80-134
0.665
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
107
107
68-160
3.72
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
114
114
72-134
1.53
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
114
114
84-130
1.12
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
110
110
70-156
2.44
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
119
119
78-130
3.29
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
115
115
82-122
6.76
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
115
115
78-138
4.24
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
233
116
63-170
4.80
0-20
SDG Number: 6398
Client ID: LCSD for batch 26526
Lab Sample ID: 12011030
Instrument: HRP763
Analyst: JTF
Page
19 of 27
-------
Cape Fear Analytical LLC
Report Date: July 29,2014
Page 1 of 2
Dilution: 1
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
1746-01-6
MS
2,3,7,8-TCDD
164
2150
-132 *
70-130
40321-76-4
MS
1,2,3,7,8-PeCDD
CO
CO
u
816
99.8
70-130
39227-28-6
MS
1,2,3,4,7,8-HxCDD
CO
CO
u
768
93.9
70-130
57653-85-7
MS
1,2,3,6,7,8-HxCDD
CO
CO
J
881
106
70-130
19408-74-3
MS
1,2,3,7,8,9-HxCDD
CO
CO
u
885
108
70-130
35822-46-9
MS
1,2,3,4,6,7,8 -HpCDD
CO
CO
1120
102
70-130
3268-87-9
MS
1,2,3,4,6,7,8,9-OCDD
1640
9320
62 *
70-130
51207-31-9
MS
2,3,7,8-TCDF
164
186
103
70-130
57117-41-6
MS
1,2,3,7,8-PeCDF
CO
CO
u
898
110
70-130
57117-31-4
MS
2,3,4,7,8-PeCDF
CO
CO
J
877
107
70-130
70648-26-9
MS
1,2,3,4,7,8-HxCDF
CO
CO
J
936
114
70-130
57II7.44.9
MS
1,2,3,6,7,8-HxCDF
CO
CO
u
923
113
70-130
60851-34-5
MS
2,3,4,6,7,8-HxCDF
CO
CO
u
905
111
70-130
72918-21-9
MS
1,2,3,7,8,9-HxCDF
CO
CO
u
962
118
70-130
67562-39-4
MS
1,2,3,4,6,7,8 -HpCDF
CO
CO
971
111
70-130
55673-89-7
MS
1,2,3,4,7,8,9-HpCDF
CO
CO
u
947
116
70-130
39001-02-0
MS
1,2,3,4,6,7,8,9-OCDF
1640
J
1910
112
70-130
SDG Number: 6398
Client ID: SFRA-160(6398001MS)
Lab Sample ID: 12011031
Instrument: HRP763
Analyst: JTF
Hi-Res Dioxins/Furans
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike
Matrix: SOLID
%Moisture: 5.3
Analysis Date: 07/26/2014 21:03
Prep Batch ID:26526
Batch ID: 26528
Page 20 of 27
-------
Cape Fear Analytical LLC
Report Date: July 29,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Matrix Spike Duplicate
Matrix: SOLID
%Moisture: 5.3
Analysis Date: 07/26/2014 21:51 Dilution: 1
Prep Batch ID:26526
Batch ID: 26528
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
pg/g
%
Limits
%
Limits
1746-01-6
MSD
2,3,7,8-TCDD
174
2540
102
70-130
16.8
0-20
40321-76-4
MSD
1,2,3,7,8-PeCDD
872
U
866
99.2
70-130
5.87
0-20
39227-28-6
MSD
1,2,3,4,7,8-HxCDD
872
U
858
98.4
70-130
11.1
0-20
57653-85-7
MSD
1,2,3,6,7,8-HxCDD
872
J
891
101
70-130
1.10
0-20
19408-74-3
MSD
1,2,3,7,8,9-HxCDD
872
U
932
107
70-130
5.12
0-20
35822-46-9
MSD
1,2,3,4,6,7,8 -HpCDD
872
1300
116
70-130
14.8
0-20
3268-87-9
MSD
1,2,3,4,6,7,8,9-OCDD
1740
9730
81.9
70-130
4.35
0-20
51207-31-9
MSD
2,3,7,8-TCDF
174
195
103
70-130
5.08
0-20
57117-41-6
MSD
1,2,3,7,8-PeCDF
872
u
933
107
70-130
3.84
0-20
57117-31-4
MSD
2,3,4,7,8-PeCDF
872
J
903
103
70-130
2.86
0-20
70648-26-9
MSD
1,2,3,4,7,8-HxCDF
872
J
1000
114
70-130
6.72
0-20
57II7.44.9
MSD
1,2,3,6,7,8-HxCDF
872
u
973
112
70-130
5.25
0-20
60851-34-5
MSD
2,3,4,6,7,8-HxCDF
872
u
996
114
70-130
9.49
0-20
72918-21-9
MSD
1,2,3,7,8,9-HxCDF
872
u
1020
117
70-130
6.01
0-20
67562-39-4
MSD
1,2,3,4,6,7,8 -HpCDF
872
1060
115
70-130
8.67
0-20
55673-89-7
MSD
1,2,3,4,7,8,9-HpCDF
872
u
1040
119
70-130
8.91
0-20
39001-02-0
MSD
1,2,3,4,6,7,8,9-OCDF
1740
J
2110
117
70-130
9.85
0-20
SDG Number: 6398
Client ID: SFRA-160(6398001MSD)
Lab Sample ID: 12011032
Instrument: HRP763
Analyst: JTF
Page 21 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
Method Blank Summary
Page 1 of 1
SDG Number:
Client ID:
Lab Sample ID: 12011028
Column:
6398
MB for batch 26526
Client: TETR001
Instrument ID: HRP763
Prep Date: 24-JUL-14
Matrix: SOLID
Data File: b25jull4a 4-3
Analyzed: 07/26/1419:28
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26526
12011029
b25jull4a_4-l
07/26/14
1753
02
LCSD for batch 26526
12011030
b25jull4a_4-2
07/26/14
1840
03
SFRA-160
6398001
b25jull4a_4-4
07/26/14
2016
04
SFRA-160(639800 IMS)
12011031
b25jull4a_4-5
07/26/14
2103
05
SFRA-160(6398001MSD)
12011032
b25jull4a_4-6
07/26/14
2151
06
SFRA-161
6398002
b25jull4a_4-7
07/26/14
2239
07
SFRA-160
6398001
A28JUL14A-4
07/28/14
1607
Page 22 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6398
Lab Sample ID: 12011028
Client Sample: ^or batch 26526
Client ID: MB for batch 26526
Batch ID: 26528
Run Date: 07/26/2014 19:28
Data File: b25jull4a_4-3
Prep Batch: 26526
Prep Date: 24-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.254
Pg/g
0.254 1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.149
Pg/g
0.149 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.224
Pg/g
0.224 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.198
Pg/g
0.198 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.22
Pg/g
0.220 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.408
Pg/g
0.408 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
u
.89
Pg/g
0.890 10.0
51207-31-9
2,3,7,8-TCDF
J
0.332
Pg/g
0.220 1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.14
Pg/g
0.140 5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.116
Pg/g
0.116 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.208
Pg/g
0.208 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.195
Pg/g
0.195 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.214
Pg/g
0.214 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
u
.378
Pg/g
0.378 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.246
Pg/g
0.246 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.484
Pg/g
0.484 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
1.1
Pg/g
1.10 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
172
200
Pg/g
86.0
(25 %-164%)
130-1,2,3,7,8-
PeCDD
174
200
Pg/g
87.2
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
135
200
Pg/g
67.6
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
178
200
Pg/g
89.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
160
200
Pg/g
79.8
(23%-140%)
13C-OCDD
255
400
Pg/g
63.8
(17%-157%)
13C-2,3,7,8-TCDF
189
200
Pg/g
94.4
(24%-169%)
130-1,2,3,7,8-
PeCDF
174
200
Pg/g
87.1
(24%-185%)
130-2,3,4,7,8-
PeCDF
190
200
Pg/g
94.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
164
200
Pg/g
81.9
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
187
200
Pg/g
93.5
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
176
200
Pg/g
88.2
(28%-136%)
130-1,2,3,7,8,9-HxCDF
161
200
Pg/g
80.7
(29%-147%)
130-1,2,3,4,6,7,8-HpCDF
169
200
Pg/g
84.6
(28%-143%)
130-1,2,3,4,7,8,9-HpCDF
152
200
Pg/g
75.8
(26%-13 8%)
3701-2,3,7,8-TCDD
18.7
20.0
Pg/g
93.6
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 23 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6398
Lab Sample ID: 12011029
Client Sample: ^or batch 26526
Client ID: LCS for batch 26526
Batch ID: 26528
Run Date: 07/26/2014 17:53
Data File: b25jull4a_4-l
Prep Batch: 26526
Prep Date: 24-JUL-14
Chent:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
20.7
Pg/g
0.468 1.00
40321-76-4
1,2,3,7,8-PeCDD
98.8
Pg/g
0.712 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
103
Pg/g
1.99 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
94.3
Pg/g
1.75 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
102
Pg/g
1.96 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
95.0
Pg/g
3.00 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
192
Pg/g
4.50 10.0
51207-31-9
2,3,7,8-TCDF
20.5
Pg/g
0.380 1.00
57117-41-6
1,2,3,7,8-PeCDF
108
Pg/g
0.896 5.00
57117-31-4
2,3,4,7,8-PeCDF
111
Pg/g
0.790 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
116
Pg/g
2.00 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
115
Pg/g
1.83 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
113
Pg/g
2.12 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
115
Pg/g
4.00 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
108
Pg/g
1.77 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
120
Pg/g
3.68 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
222
Pg/g
6.94 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
119
200
Pg/g
59.5
(20%-175%)
13C-1,2,3,7,8-
PeCDD
106
200
Pg/g
53.2
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
86.5
200
Pg/g
43.2
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
108
200
Pg/g
53.9
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
85.5
200
Pg/g
42.7
(22%-166%)
13C-OCDD
112
400
Pg/g
27.9
(13%-199%)
13C-2,3,7,8-TCDF
133
200
Pg/g
66.3
(22%-152%)
13C-1,2,3,7,8-
PeCDF
108
200
Pg/g
54.2
(21%-192%)
130-2,3,4,7,8-
PeCDF
116
200
Pg/g
57.8
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
100
200
Pg/g
50.1
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
115
200
Pg/g
57.3
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
107
200
Pg/g
53.5
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
89.0
200
Pg/g
44.5
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
96.3
200
Pg/g
48.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
70.3
200
Pg/g
35.1
(20%-186%)
3701-2,3,7,8-TCDD
19.9
20.0
Pg/g
99.5
(31 %-191%)
Comments:
Page 24 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6398
12011030
QC for batch 26526
LCSD for batch 26526
26528
07/26/2014 18:40
b25jull4a 4-2
26526
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP763
1
Prep Date:
24-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
20.3
Pg/g
0.374
1.00
40321-76-4
1,2,3,7,8-PeCDD
103
Pg/g
0.452
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
98.8
Pg/g
1.15
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
102
Pg/g
1.04
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
108
Pg/g
1.15
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
101
Pg/g
1.78
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
189
Pg/g
2.64
10.0
51207-31-9
2,3,7,8-TCDF
21.3
Pg/g
0.286
1.00
57117-41-6
1,2,3,7,8-PeCDF
109
Pg/g
0.512
5.00
57117-31-4
2,3,4,7,8-PeCDF
107
Pg/g
0.444
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
114
Pg/g
1.24
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
114
Pg/g
1.08
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
110
Pg/g
1.25
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
119
Pg/g
2.10
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
115
Pg/g
1.16
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
115
Pg/g
2.24
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
233
Pg/g
3.20
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
172
200
Pg/g
85.8
(20%-175%)
13C-1,2,3,7,8-PeCDD
175
200
Pg/g
87.7
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
143
200
Pg/g
71.6
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
183
200
Pg/g
91.6
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
168
200
Pg/g
84.1
(22%-166%)
13C-OCDD
287
400
Pg/g
71.8
(13%-199%)
13C-2,3,7,8-TCDF
186
200
Pg/g
92.8
(22%-152%)
13C-1,2,3,7,8-PeCDF
169
200
Pg/g
84.6
(21%-192%)
13C-2,3,4,7,8-PeCDF
189
200
Pg/g
94.4
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
154
200
Pg/g
77.1
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
198
200
Pg/g
98.9
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
183
200
Pg/g
91.6
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
165
200
Pg/g
82.6
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
176
200
Pg/g
88.2
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
157
200
Pg/g
78.5
(20%-186%)
37Cl-2,3,7,8-TCDD
18.2
20.0
Pg/g
91.0
(31 %-191%)
Comments:
Page 25 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6398
Lab Sample ID: 12011031
Client Sample: ^or batch 26526
Chent:
Date Collected:
Date Received:
TETR001
07/23/2014 16:20
07/24/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 5.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-160(6398001MS)
26528
07/26/2014 21:03
b25jull4a_4-5
26526
24-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.29 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2150
Pg/g
5.63 8.18
40321-76-4
1,2,3,7,8-PeCDD
816
Pg/g
5.60 40.9
39227-28-6
1,2,3,4,7,8-HxCDD
768
Pg/g
9.15 40.9
57653-85-7
1,2,3,6,7,8-HxCDD
881
Pg/g
9.11 40.9
19408-74-3
1,2,3,7,8,9-HxCDD
885
Pg/g
9.67 40.9
35822-46-9
1,2,3,4,6,7,8-HpCDD
1120
Pg/g
15.3 40.9
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9320
Pg/g
43.4 81.8
51207-31-9
2,3,7,8-TCDF
186
Pg/g
3.55 8.18
57117-41-6
1,2,3,7,8-PeCDF
898
Pg/g
5.01 40.9
57117-31-4
2,3,4,7,8-PeCDF
877
Pg/g
4.16 40.9
70648-26-9
1,2,3,4,7,8-HxCDF
936
Pg/g
13.3 40.9
57II7.44.9
1,2,3,6,7,8-HxCDF
923
Pg/g
11.3 40.9
60851-34-5
2,3,4,6,7,8-HxCDF
905
Pg/g
13.5 40.9
72918-21-9
1,2,3,7,8,9-HxCDF
962
Pg/g
22.6 40.9
67562-39-4
1,2,3,4,6,7,8-HpCDF
971
Pg/g
11.3 40.9
55673-89-7
1,2,3,4,7,8,9-HpCDF
947
Pg/g
19.1 40.9
39001-02-0
1,2,3,4,6,7,8,9-OCDF
1910
Pg/g
37.0 81.8
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1400
1640
Pg/g
85.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1510
1640
Pg/g
92.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1270
1640
Pg/g
77.8
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1450
1640
Pg/g
88.7
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1430
1640
Pg/g
87.5
(23%-140%)
13C-OCDD
2750
3270
Pg/g
83.9
(17%-157%)
13C-2,3,7,8-TCDF
1500
1640
Pg/g
91.8
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1430
1640
Pg/g
87.5
(24%-185%)
130-2,3,4,7,8-
PeCDF
1580
1640
Pg/g
96.8
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1320
1640
Pg/g
80.8
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1570
1640
Pg/g
96.0
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1480
1640
Pg/g
90.4
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1380
1640
Pg/g
84.2
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1500
1640
Pg/g
91.9
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1400
1640
Pg/g
85.5
(26%-13 8%)
3701-2,3,7,8-TCDD
171
164
Pg/g
104
(35%-197%)
Comments:
Page 26 of 27
-------
Cape Fear Analytical LLC
Report Date:
July 29, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6398
Lab Sample ID: 12011032
Client Sample: ^or batch 26526
Chent:
Date Collected:
Date Received:
TETR001
07/23/2014 16:20
07/24/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 5.3
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-160(6398001MSD)
26528
07/26/2014 21:51
b25jull4a_4-6
26526
24-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.21 g
Prep Basis: Dry Weight
Instrument: HRP763
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
2540
Pg/g
7.10 8.72
40321-76-4
1,2,3,7,8-PeCDD
866
Pg/g
5.81 43.6
39227-28-6
1,2,3,4,7,8-HxCDD
858
Pg/g
8.93 43.6
57653-85-7
1,2,3,6,7,8-HxCDD
891
Pg/g
8.83 43.6
19408-74-3
1,2,3,7,8,9-HxCDD
932
Pg/g
9.39 43.6
35822-46-9
1,2,3,4,6,7,8-HpCDD
1300
Pg/g
16.3 43.6
3268-87-9
1,2,3,4,6,7,8,9-OCDD
9730
Pg/g
50.9 87.2
51207-31-9
2,3,7,8-TCDF
195
Pg/g
4.62 8.72
57117-41-6
1,2,3,7,8-PeCDF
933
Pg/g
4.54 43.6
57117-31-4
2,3,4,7,8-PeCDF
903
Pg/g
4.01 43.6
70648-26-9
1,2,3,4,7,8-HxCDF
1000
Pg/g
13.4 43.6
57II7.44.9
1,2,3,6,7,8-HxCDF
973
Pg/g
12.0 43.6
60851-34-5
2,3,4,6,7,8-HxCDF
996
Pg/g
13.2 43.6
72918-21-9
1,2,3,7,8,9-HxCDF
1020
Pg/g
22.2 43.6
67562-39-4
1,2,3,4,6,7,8-HpCDF
1060
Pg/g
8.95 43.6
55673-89-7
1,2,3,4,7,8,9-HpCDF
1040
Pg/g
19.2 43.6
39001-02-0
1,2,3,4,6,7,8,9-OCDF
2110
Pg/g
26.0 87.2
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1590
1740
Pg/g
91.1
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1670
1740
Pg/g
95.8
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1410
1740
Pg/g
81.1
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1580
1740
Pg/g
90.8
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1620
1740
Pg/g
92.9
(23%-140%)
13C-OCDD
2990
3490
Pg/g
85.8
(17%-157%)
13C-2,3,7,8-TCDF
1650
1740
Pg/g
94.8
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1620
1740
Pg/g
92.6
(24%-185%)
130-2,3,4,7,8-
PeCDF
1800
1740
Pg/g
103
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1470
1740
Pg/g
84.1
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1710
1740
Pg/g
98.2
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1600
1740
Pg/g
91.6
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1480
1740
Pg/g
84.7
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1710
1740
Pg/g
98.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1490
1740
Pg/g
85.3
(26%-13 8%)
3701-2,3,7,8-TCDD
188
174
Pg/g
108
(35%-197%)
Comments:
Page 27 of 27
-------
Cape Fear Analytical llc
3306 Kitty Hawk Road, Suite 120 Wilmington, NC 28405
P 910.795.0421
an affiliate of The GEL Group INC
www.capefearanalytical.com
August 05, 2014
Mr. David Kinroth
Seagull Environmental Technologies, Incorporated
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal Action
Work Order: 6430
Dear Mr. Kinroth:
Cape Fear Analytical LLC (CFA) appreciates the opportunity to provide the enclosed analytical results for the sample(s) we received
on July 31, 2014. This original data report has been prepared and reviewed in accordance with CFA's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs on time every time.
We trust that you will find everything in order and to your satisfaction. If you have any questions, please do not hesitate to call me at
910-795-0421 Ext. 4485.
Sincerely,
Cynthia Larkins
Project Manager
Purchase Order: 109644
Enclosures
Page 1 of21
problem solved
-------
Page: f
Project #:
CFA Quote #:
COC Number"1:
PO Number;
of
X" t
Cape Fear Analytical, LLC
Chain of Custody and Analytical Request
CFA Work Order Number: (_Q L-|- 2? O
Cape Fear Analytical, LLC
3306 Kitty Hawk Rd. Suite 120
Wilmington, NC 28405
Phone: (910) 795-0421
Client Name:
Phone #,
Sample Analysis Requested(5> (Fill in the number of containers for each test)
gWc./SteN.mnS^
(JC
a
is Address:
is /Collected by: ^ Send Results
/*('»% < A«*.
Sample ID
* For composites - indicate start and stop date/time
*Date Collected
(mm-dd-yy)
•Time
Collected
(Miliary)
(hhrnm)
QC Code
»
vlrtkcb
Field
Filtered(3>
Sample
Matrix,4>
<- Preservative Type (6)
Comments
Note: extra sample is
required for sample
specific QC
J> FA/£x
eS3Q
JtFM- /&3
?-¦!*>-/j
airs'
TAT Requested: Normal: Rush: )f Specify:
jject to Surcharge)
Fax Results:
Yes
/
No
Circle Deliverable: C of A / QC Summary / Level 1 / Level 2 / Q,evcl 3)/ Level 4
Remarks: Are there any known hazards applicable to these samples? If so, please list the hazards
Sample Collection Time Zon
Eastern Pacific
Central Other _
Mountain
Chain of Custody Signatures
Sample Shipping and Delivery Details
Relinquished By (Signed)
Date
Time
?.&>•/¥
Received by (signed)
Date
Time
/jtpcU-3UUMM 0^ So
CFAPM: cy*«fg
Method of Shipment:
Date Shipped:
Airbill #: *$>9t
Airbill #:
1.) Chain of Custody Number = Client Determined
2.) QC Codes: N = Normal Sample,TB = Trip Blank, FD - Field Duplicate,EB = Equipment Blank, MS - Matrix Spike Sample,MSD - Matrix Spike Duplicate Sample,G = Grab, C = Composite
3.) Field Filtered: For liquid matrices, indicate with a- Y - for yes the sample was field filtered or- N - for sample was not field filtered.
4.) Matrix Codes: DW=DrtnMng Water, GW=Groundwater, SW-Surface Water, WW=Waste Water, W-Water, ML-Mise Liquid,SO Soil, SB-Sediment, SL-Sludge, SS-Solid Waste, 0=Oii, F-Filter, P=Wipe, IMJrine, F-Fecal, N=Nasal
5.) Sample Analysis Requested: Analytical method requested (i.e8290B, lt68B)andnumberofcontaineKpro»idedforeach(i.e.#2SffiB-3, M6SB-1).
6.) Preservative Type: HA - Hydrochloric Acid,NI - Nitric Acid, SH - Sodium Hydroxide, SA « Sulfuric Acid, AA - Ascorbic Acid, HX - Hexane, ST « Sodium Thiosulfate, If no preservative is added - leave field blank
WHITE = LABORATORY YELLOW = FILE PINK = CLIENT
For Lab Receiving Use Only
Custody Seal Intact?
YES
Cooler Temp:
•5,3 c
-------
SAMPLE RECEIPT CHECKLIST
Cape Fear Analytical
Client: -f
Work Order: ^^ ^
Shipping Company: £7^ p(_
Date/Time Received: 3 ( J CU ( ^ Q
Suspected Hazard Information
Yes
NA
No
DOE Site Sample Packages
Yes
NA
No*
Shipped as DOT Hazardous?
Screened <0.5 mR/hr?
"
Samples identified as Foreign Soil?
Samples < 2x background?
* Notify RSO of any responses in this column immediately.
Air Sample Receipt Specifics
Yes
NA
No
y'
Air sample in shipment?
w/
Air Witness:
Sample Receipt Criteria
Yes
NA
No
Comments/Qualifiers (required for Non-Conforming Items)
1
Shipping containers received intact
and sealed?
y
Circle Applicable:
seals broken damaged container leaking container other^escribe)
2
Chain of Custody documents included
with shipment?
«/
/
3
Samples requiring cold preservation
within Q-6°C?
O
/
<
Method:
ice bags! blue ice dry ice none other (describe)
4
Aqueous samples found to have visible
solids?
Sample IDs, containers affected:
5
Samples requiring chemical
preservation at proper pH?
/
Sample IDs, containers affected and pH observed:
If preservative added, lot#:
6
Samples requiring preservation have
no residual chlorine?
y
/
Sample IDs, containers affected:
If preservative added, tot#:
7
Samples received within holding time?
Sample IDs, tests affected:
8
Sample IDs on COC match IDs on
containers?
iS
/
Sample IDs, containers affected:
9
Date & time of COC match date & time
on containers?
S
/
Sample IDs, containers affected;
10
Number of containers received match
number indicated on COC?
u
/
/ •»
Sample IDs, containers affected:
11
COC form is properly signed in
relinquished/received sections?
/
Comments:
Page 3 of21
Checklist performed by: Initials: ( y7f" — Date: S-~ ' ' '
^4
-------
High Resolution Dioxins
and Furans Analysis
Page 4 of21
-------
Case Narrative
Page 5 of21
-------
HDOX Case Narrative
Tetra Tech EM Incorporated (TETR)
SDG 6430
Method/Analysis Information
Product: Dioxins/Furans by EPA Method 1613B in Solids
Analytical Method: EPA Method 1613B
Extraction Method: SW846 3540C
Analytical Batch Number: 26580
Clean Up Batch Number: 26579
Extraction Batch Number: 26578
Sample Analysis
The following samples were analyzed using the analytical protocol as established in EPA
Method 1613B:
Sample ID Client ID
6430001 SFRA-162
6430002 SFRA-163
12011085 Method Blank (MB)
12011086 Laboratory Control Sample (LCS)
12011087 Laboratory Control Sample Duplicate (LCSD)
The samples in this SDG were analyzed on a "dry weight" basis.
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by Cape Fear
Analytical LLC (CFA) as Standard Operating Procedure (SOP). The data discussed in this
narrative has been analyzed in accordance with CF-OA-E-002 REV# 13.
Raw data reports are processed and reviewed by the analyst using the TargetLynx software
package.
Calibration Information
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Page 6 of21
-------
Quality Control (OC) Information
Certification Statement
The test results presented in this document are certified to meet all requirements of the 2003
NELAC Standard.
Method Blank (MB) Statement
The MB(s) analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for this SDG.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Laboratory Control Sample Duplicate (LCSD) Recovery
The LCSD spike recoveries met the acceptance limits.
LCS/LCSD Relative Percent Difference (RPD) Statement
The RPD(s) between the LCS and LCSD met the acceptance limits.
QC Sample Designation
A sample of similar matrix, not associated with this SDG, was selected for analysis as the matrix
spike and matrix spike duplicate. Batch 26580.
Technical Information
Holding Time Specifications
CFA assigns holding times based on the associated methodology, which assigns the date and
time from sample collection. Those holding times expressed in hours are calculated in the
AlphaLIMS system. Those holding times expressed as days expire at midnight on the day of
expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
A 5g dry weight was performed per client request and a lg extraction was performed due to the
high levels of target analytes that may be present. Batch 26580.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG.
Miscellaneous Information
Page 7 of21
-------
Nonconformance (NCR) Documentation
A NCR was not required for this SDG.
Manual Integrations
Certain standards and QC samples required manual integrations to correctly position the baseline
as set in the calibration standard injections. Where manual integrations were performed, copies
of all manual integration peak profiles are included in the raw data section of this fraction.
Manual integrations were required for data files in this SDG.
Sample Preparation
No difficulties were encountered during sample preparation.
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
systems to generate all data packages electronically. The following change from traditional
packages should be noted: Analyst/peer reviewer initials and dates are not present on the
electronic data files. Presently, all initials and dates are present on the original raw data. These
hard copies are temporarily stored in the laboratory. An electronic signature page inserted after
the case narrative will include the data validator's signature and title. The signature page also
includes the data qualifiers used in the fractional package. Data that are not generated
electronically, such as hand written pages, will be scanned and inserted into the electronic
package.
Page 8 of21
-------
Sample Data Summary
Page 9 of21
-------
Cape Fear Analytical, LLC
3306 Kitty Hawk Road Suite 120, Wilmington, NC 28405 - (910) 795-0421 -www.capefearanalytical.com
Certificate of Analysis Report
for
TETR001 Tetra Tech EM Incorporated
Client SDG: 6430 CFA Work Order: 6430
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Review /V alidation
Cape Fear Analytical requires all analytical data to be verified by a qualified data reviewer.
The following data validator verified the information presented in this case narrative:
Signature: Name: Erin Suhrie
Date: 05 AUG 2014 Title: Data Validator
Page 10 of 21
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6430
Lab Sample ID: 6430001
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/30/2014 08:30
07/31/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 10*7
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-162
26580
08/04/2014 14:22
A04AUG14A-5
26578
31-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.15 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
1110
Pg/g
2.36 9.74
40321-76-4
1,2,3,7,8-PeCDD
U
1.66
Pg/g
1.66 48.7
39227-28-6
1,2,3,4,7,8-HxCDD
u
3.7
Pg/g
3.70 48.7
57653-85-7
1,2,3,6,7,8-HxCDD
J
12.1
Pg/g
3.80 48.7
19408-74-3
1,2,3,7,8,9-HxCDD
J
4.87
Pg/g
3.99 48.7
35822-46-9
1,2,3,4,6,7,8-HpCDD
249
Pg/g
8.06 48.7
3268-87-9
1,2,3,4,6,7,8,9-OCDD
15200
Pg/g
21.6 97.4
51207-31-9
2,3,7,8-TCDF
J
9.35
Pg/g
3.49 9.74
57117-41-6
1,2,3,7,8-PeCDF
u
1.22
Pg/g
1.22 48.7
57117-31-4
2,3,4,7,8-PeCDF
u
1.52
Pg/g
1.52 48.7
70648-26-9
1,2,3,4,7,8-HxCDF
J
3.02
Pg/g
1.72 48.7
57II7.44.9
1,2,3,6,7,8-HxCDF
u
1.75
Pg/g
1.75 48.7
60851-34-5
2,3,4,6,7,8-HxCDF
J
2.34
Pg/g
1.87 48.7
72918-21-9
1,2,3,7,8,9-HxCDF
u
2.26
Pg/g
2.26 48.7
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
44.9
Pg/g
1.44 48.7
55673-89-7
1,2,3,4,7,8,9-HpCDF
J
2.77
Pg/g
2.10 48.7
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
68.9
Pg/g
3.06 97.4
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1790
1950
Pg/g
91.7
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1990
1950
Pg/g
102
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1650
1950
Pg/g
84.7
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1600
1950
Pg/g
81.9
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1930
1950
Pg/g
99.2
(23%-140%)
13C-OCDD
4280
3890
Pg/g
110
(17%-157%)
13C-2,3,7,8-TCDF
1870
1950
Pg/g
96.2
(24%-169%)
13C-1,2,3,7,8-
PeCDF
1970
1950
Pg/g
101
(24%-185%)
130-2,3,4,7,8-
PeCDF
1990
1950
Pg/g
102
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1580
1950
Pg/g
81.3
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1580
1950
Pg/g
81.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1590
1950
Pg/g
81.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1650
1950
Pg/g
84.5
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1750
1950
Pg/g
90.1
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1870
1950
Pg/g
96.2
(26%-13 8%)
3701-2,3,7,8-TCDD
212
195
Pg/g
109
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 11 of 21
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6430
Lab Sample ID: 6430002
Client Sample: 1613B Soil
Client:
Date Collected:
Date Received:
TETR001
07/30/2014 09:55
07/31/2014 09:50
Project: TETR00114
Matrix: SOLID
%Moisture: 13
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
Prep Date:
SFRA-163
26580
08/04/2014 15:10
A04AUG14A-6
26578
31-JUL-14
Method:
Analyst:
Prep Method:
Prep Aliquot:
EPA Method 1613B
JTF
SW846 3540C
1.21 g
Prep Basis: Dry Weight
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
U
.76
Pg/g
0.760 9.49
40321-76-4
1,2,3,7,8-PeCDD
u
.775
Pg/g
0.775 47.5
39227-28-6
1,2,3,4,7,8-HxCDD
u
1.29
Pg/g
1.29 47.5
57653-85-7
1,2,3,6,7,8-HxCDD
u
1.34
Pg/g
1.34 47.5
19408-74-3
1,2,3,7,8,9-HxCDD
J
1.58
Pg/g
1.40 47.5
35822-46-9
1,2,3,4,6,7,8-HpCDD
71.4
Pg/g
4.82 47.5
3268-87-9
1,2,3,4,6,7,8,9-OCDD
12100
Pg/g
8.79 94.9
51207-31-9
2,3,7,8-TCDF
J
2.98
Pg/g
0.967 9.49
57117-41-6
1,2,3,7,8-PeCDF
u
.752
Pg/g
0.752 47.5
57117-31-4
2,3,4,7,8-PeCDF
u
.737
Pg/g
0.737 47.5
70648-26-9
1,2,3,4,7,8-HxCDF
u
.737
Pg/g
0.737 47.5
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.725
Pg/g
0.725 47.5
60851-34-5
2,3,4,6,7,8-HxCDF
u
.758
Pg/g
0.758 47.5
72918-21-9
1,2,3,7,8,9-HxCDF
u
.9
Pg/g
0.900 47.5
67562-39-4
1,2,3,4,6,7,8-HpCDF
J
2.66
Pg/g
1.10 47.5
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
1.7
Pg/g
1.70 47.5
39001-02-0
1,2,3,4,6,7,8,9-OCDF
J
8.09
Pg/g
1.26 94.9
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
1740
1900
Pg/g
91.5
(25 %-164%)
13C-1,2,3,7,8-
PeCDD
1870
1900
Pg/g
98.4
(25%-181%)
130-1,2,3,4,7,
8-HxCDD
1570
1900
Pg/g
82.4
(32%-141%)
130-1,2,3,6,7,
8-HxCDD
1620
1900
Pg/g
85.2
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
1830
1900
Pg/g
96.2
(23%-140%)
13C-OCDD
3760
3800
Pg/g
98.9
(17%-157%)
13C-2,3,7,8-TCDF
1920
1900
Pg/g
101
(24%-169%)
13C-1,2,3,7,8-
PeCDF
2010
1900
Pg/g
106
(24%-185%)
130-2,3,4,7,8-
PeCDF
1990
1900
Pg/g
105
(21%-178%)
130-1,2,3,4,7,
8-HxCDF
1620
1900
Pg/g
85.2
(26%-152%)
130-1,2,3,6,7,
8-HxCDF
1680
1900
Pg/g
88.3
(26%-123%)
130-2,3,4,6,7,
8-HxCDF
1670
1900
Pg/g
87.9
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
1780
1900
Pg/g
93.8
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
1770
1900
Pg/g
93.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
1860
1900
Pg/g
98.0
(26%-13 8%)
3701-2,3,7,8-TCDD
204
190
Pg/g
107
(35%-197%)
Comments:
J Value is estimated
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 12 of 21
-------
Quality Control
Summary
Page 13 of 21
-------
( (ipc Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 1 of 2
Surrogate Recovery Report
SDG Number: 6430
Matrix Type: SOLID
Sample ID Client ID
Surrogate
QUAL
Recovery
(%)
Acceptance
Limits
12011086
LCS for batch 26578
12011087
LCSD for batch 26578
12011085
MB for batch 26578
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
13C-2,3,7,8-
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-1,2,3,4,
13C-OCDD
13C-2,3,7,8-
13C-1,2,3,7,
13C-2,3,4,7,
13C-1,2,3,4,
13C-1,2,3,6,
13C-2,3,4,6,
13C-1,2,3,7,
13C-1,2,3,4,
13C-1,2,3,4,
37Cl-2,3,7,8'
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
TCDD
¦TCDD
8-PeCDD
7,8-HxCDD
7,8-HxCDD
6,7,8-HpCDD
¦TCDF
8-PeCDF
8-PeCDF
7,8-HxCDF
7,8-HxCDF
7.8-HxCDF
8.9-HxCDF
6.7.8-HpCDF
7.8.9-HpCDF
-TCDD
82.8
96.3
77.8
81.1
85.7
84.3
91.3
99.8
99.9
80.4
79.5
82.4
81.7
84.5
87.5
100
87.6
95.0
81.3
79.8
90.3
89.0
98.9
100
103
83.5
82.0
84.8
86.5
87.1
93.4
104
96.8
108
88.3
86.1
104
104
101
109
110
85.2
82.8
87.7
88.6
92.2
102
109
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(20%-175%
(21%-227%
(21%-193%
(25%-163%
(22%-166%
(13%-199%
(22%-152%
(21%-192%
(13%-328%
(19%-202%
(21%-159%
(22%-176%
(17%-205%
(21%-15 8%
(20%-186%
(31%-191%
(25%-
(25%-
(32%-
(28%-
(23%-
(17%-
(24%-
(24%-
(21%-
(26%-
(26%-
(28%-
(29%-
(28%-
(26%-
(35%-
164%
181%
141%
130%
140%
157%
169%
185%
178%
152%
123%
136%
147%
143%
138%
197%
6430001
SFRA-162
13C-2,3,7,8-TCDD
91.7
(25%-164%)
Page 14 of 21
-------
( (ipc Fear Analytical LLC Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 2 of 2
Surrogate Recovery Report
SDG Number: 6430
Matrix Type: SOLID
Sample ID Client ID
6430001 SFRA-162
6430002 SFRA-163
Surrogate
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
13C-2,3,7,8-TCDD
13C-l,2,3,7,8-PeCDD
13C-l,2,3,4,7,8-HxCDD
13C-l,2,3,6,7,8-HxCDD
13C-l,2,3,4,6,7,8-HpCDD
13C-OCDD
13C-2,3,7,8-TCDF
13C-l,2,3,7,8-PeCDF
13C-2,3,4,7,8-PeCDF
13C-l,2,3,4,7,8-HxCDF
13C-l,2,3,6,7,8-HxCDF
13C-2,3,4,6,7,8-HxCDF
13C-l,2,3,7,8,9-HxCDF
13C-l,2,3,4,6,7,8-HpCDF
13C-l,2,3,4,7,8,9-HpCDF
37Cl-2,3,7,8-TCDD
Recovery Acceptance
QUAL (%) Limits
102 (25%-181%)
84.7 (32%-141%)
81.9 (28%-130%)
99.2 (23%-140%)
110 (17%-15 7%)
96.2 (24%-169%)
101 (24%-185%)
102 (21%-178%)
81.3 (26%-152%)
81.3 (26%-123%)
81.9 (28%-13 6%)
84.5 (29%-147%)
90.1 (28%-143%)
96.2 (26%-13 8%)
109 (35%-197%)
91.5 (25%-164%)
98.4 (25%-181%)
82.4 (32%-141%)
85.2 (28%-130%)
96.2 (23%-140%)
98.9 (17%-15 7%)
101 (24%-169%)
106 (24%-185%)
105 (21%-178%)
85.2 (26%-152%)
88.3 (26%-123%)
87.9 (28%-13 6%)
93.8 (29%-147%)
93.2 (28%-143%)
98.0 (26%-13 8%)
107 (35%-197%)
* Recovery outside Acceptance Limits
# Column to be used to flag recovery values
D Sample Diluted
Page 15 of 21
-------
Cape Fear Analytical LLC
Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 1 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample
Matrix: SOLID
Analysis Date: 08/04/2014 11:57 Dilution: 1
Prep Batch ID:26578
Batch ID: 26580
Amount Spike
Added Cone. Recovery Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
1746-01-6
LCS
2,3,7,8-TCDD
20.0
21.7
108
67-158
40321-76-4
LCS
1,2,3,7,8-PeCDD
100
105
105
70-142
39227-28-6
LCS
1,2,3,4,7,8-HxCDD
100
107
107
70-164
57653-85-7
LCS
1,2,3,6,7,8-HxCDD
100
97.8
97.8
76-134
19408-74-3
LCS
1,2,3,7,8,9-HxCDD
100
108
108
64-162
35822-46-9
LCS
1,2,3,4,6,7,8 -HpCDD
100
104
104
70-140
3268-87-9
LCS
1,2,3,4,6,7,8,9-OCDD
200
207
104
78-144
51207-31-9
LCS
2,3,7,8-TCDF
20.0
19.9
99.4
75-158
57117-41-6
LCS
1,2,3,7,8-PeCDF
100
98.5
98.5
80-134
57117-31-4
LCS
2,3,4,7,8-PeCDF
100
100
100
68-160
70648-26-9
LCS
1,2,3,4,7,8-HxCDF
100
102
102
72-134
57II7.44.9
LCS
1,2,3,6,7,8-HxCDF
100
105
105
84-130
60851-34-5
LCS
2,3,4,6,7,8-HxCDF
100
103
103
70-156
72918-21-9
LCS
1,2,3,7,8,9-HxCDF
100
109
109
78-130
67562-39-4
LCS
1,2,3,4,6,7,8 -HpCDF
100
105
105
82-122
55673-89-7
LCS
1,2,3,4,7,8,9-HpCDF
100
103
103
78-138
39001-02-0
LCS
1,2,3,4,6,7,8,9-OCDF
200
210
105
63-170
SDG Number: 6430
Client ID: LCS for batch 26578
Lab Sample ID: 12011086
Instrument: HRP750
Analyst: JTF
Page 16 of 21
-------
Cape Fear Analytical LLC
Report Date: August 5,2014
Hi-Res Dioxins/Furans Page 2 of 2
Quality Control Summary
Spike Recovery Report
Sample Type: Laboratory Control Sample Duplicate
Matrix: SOLID
Analysis Date: 08/04/2014 12:44 Dilution: 1
Prep Batch ID:26578
Batch ID: 26580
Amount Spike
Added Cone. Recovery Acceptance RPD Acceptance
CAS No.
Parmname
pg/g
Pg/g
%
Limits
%
Limits
1746-01-6
LCSD
2,3,7,8-TCDD
20.0
22.3
111
67-158
2.79
0-20
40321-76-4
LCSD
1,2,3,7,8-PeCDD
100
106
106
70-142
0.569
0-20
39227-28-6
LCSD
1,2,3,4,7,8-HxCDD
100
105
105
70-164
1.75
0-20
57653-85-7
LCSD
1,2,3,6,7,8-HxCDD
100
104
104
76-134
6.62
0-20
19408-74-3
LCSD
1,2,3,7,8,9-HxCDD
100
115
115
64-162
5.92
0-20
35822-46-9
LCSD
1,2,3,4,6,7,8 -HpCDD
100
104
104
70-140
0.804
0-20
3268-87-9
LCSD
1,2,3,4,6,7,8,9-OCDD
200
206
103
78-144
0.689
0-20
51207-31-9
LCSD
2,3,7,8-TCDF
20.0
20.2
101
75-158
1.57
0-20
57117-41-6
LCSD
1,2,3,7,8-PeCDF
100
101
101
80-134
2.06
0-20
57117-31-4
LCSD
2,3,4,7,8-PeCDF
100
103
103
68-160
2.75
0-20
70648-26-9
LCSD
1,2,3,4,7,8-HxCDF
100
103
103
72-134
1.73
0-20
57II7.44.9
LCSD
1,2,3,6,7,8-HxCDF
100
110
110
84-130
4.22
0-20
60851-34-5
LCSD
2,3,4,6,7,8-HxCDF
100
105
105
70-156
2.18
0-20
72918-21-9
LCSD
1,2,3,7,8,9-HxCDF
100
108
108
78-130
1.04
0-20
67562-39-4
LCSD
1,2,3,4,6,7,8 -HpCDF
100
105
105
82-122
0.080
0-20
55673-89-7
LCSD
1,2,3,4,7,8,9-HpCDF
100
103
103
78-138
0.00777
0-20
39001-02-0
LCSD
1,2,3,4,6,7,8,9-OCDF
200
208
104
63-170
0.760
0-20
SDG Number: 6430
Client ID: LCSD for batch 26578
Lab Sample ID: 12011087
Instrument: HRP750
Analyst: JTF
Page
17 of 21
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Method Blank Summary
Page 1 of 1
SDG Number: 6430
Client ID: MB for batch 26578
Lab Sample ID: 12011085
Column:
Client: TETR001
Instrument ID: HRP750
Prep Date: 31-JUL-14
Matrix: SOLID
Data File: A04AUG14A-4
Analyzed: 08/04/1413:33
This method blank applies to the following samples and quality control samples:
Client Sample ID
Lab Sample ID
File ID
Date Analyzed
Time Analyzed
01
LCS for batch 26578
12011086
A04AUG14A-2
08/04/14
1157
02
LCSD for batch 26578
12011087
A04AUG14A-3
08/04/14
1244
03
SFRA-162
6430001
A04AUG14A-5
08/04/14
1422
04
SFRA-163
6430002
A04AUG14A-6
08/04/14
1510
Page 18 of 21
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
6430
12011085
QC for batch 26578
MB for batch 26578
26580
08/04/2014 13:33
A04AUG14A-4
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
TETR00114
SOLID
As Received
HRP750
1
Prep Batch:
26578
Prep Method:
SW846 3540C
Prep Date:
31-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
U
.0916
Pg/g
0.0916
1.00
40321-76-4
1,2,3,7,8-PeCDD
u
.0776
Pg/g
0.0776
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
u
.105
Pg/g
0.105
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
u
.101
Pg/g
0.101
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
u
.109
Pg/g
0.109
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
u
.173
Pg/g
0.173
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
J
0.916
Pg/g
0.226
10.0
51207-31-9
2,3,7,8-TCDF
J
0.220
Pg/g
0.152
1.00
57117-41-6
1,2,3,7,8-PeCDF
u
.0688
Pg/g
0.0688
5.00
57117-31-4
2,3,4,7,8-PeCDF
u
.0678
Pg/g
0.0678
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
u
.0558
Pg/g
0.0558
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
u
.057
Pg/g
0.057
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
u
.0548
Pg/g
0.0548
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
J
0.110
Pg/g
0.077
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
u
.0688
Pg/g
0.0688
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
u
.0982
Pg/g
0.0982
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
u
.24
Pg/g
0.240
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
194
200
Pg/g
96.8
(25 %-164%)
13C-1,2,3,7,8-PeCDD
216
200
Pg/g
108
(25%-181%)
13C-1,2,3,4,7,8-HxCDD
177
200
Pg/g
88.3
(32%-141%)
13C-1,2,3,6,7,8-HxCDD
172
200
Pg/g
86.1
(28%-130%)
13C-1,2,3,4,6,7,8-HpCDD
208
200
Pg/g
104
(23%-140%)
13C-OCDD
415
400
Pg/g
104
(17%-157%)
13C-2,3,7,8-TCDF
203
200
Pg/g
101
(24%-169%)
13C-1,2,3,7,8-PeCDF
219
200
Pg/g
109
(24%-185%)
13C-2,3,4,7,8-PeCDF
220
200
Pg/g
110
(21%-178%)
13C-1,2,3,4,7,8-HxCDF
170
200
Pg/g
85.2
(26%-152%)
13C-1,2,3,6,7,8-HxCDF
166
200
Pg/g
82.8
(26%-123%)
13C-2,3,4,6,7,8-HxCDF
175
200
Pg/g
87.7
(28%-136%)
13C-1,2,3,7,8,9-HxCDF
177
200
Pg/g
88.6
(29%-147%)
13C-1,2,3,4,6,7,8-HpCDF
184
200
Pg/g
92.2
(28%-143%)
13C-1,2,3,4,7,8,9-HpCDF
204
200
Pg/g
102
(26%-13 8%)
37Cl-2,3,7,8-TCDD
21.7
20.0
Pg/g
109
(35%-197%)
Comments:
J Value is estimated
K Estimated Maximum Possible Concentration
U Analyte was analyzed for, but not detected above the specified detection limit.
Page 19 of 21
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
Page 1
of 1
SDG Number: 6430
Lab Sample ID: 12011086
Client Sample: ^or batch 26578
Client ID: LCS for batch 26578
Batch ID: 26580
Run Date: 08/04/2014 11:57
Data File: A04AUG14A-2
Prep Batch: 26578
Prep Date: 31-JUL-14
Client:
Method:
Analyst:
Prep Method:
Prep Aliquot:
TETR001
EPA Method 1613B
JTF
SW846 3540C
10 g
Project: TETR00114
Matrix: SOLID
Prep Basis: As Received
Instrument: HRP750
Dilution: 1
CAS No.
Parmname
Qual
Result
Units
EDL PQL
1746-01-6
2,3,7,8-TCDD
21.7
Pg/g
0.105 1.00
40321-76-4
1,2,3,7,8-PeCDD
105
Pg/g
0.186 5.00
39227-28-6
1,2,3,4,7,8-HxCDD
107
Pg/g
0.362 5.00
57653-85-7
1,2,3,6,7,8-HxCDD
97.8
Pg/g
0.380 5.00
19408-74-3
1,2,3,7,8,9-HxCDD
108
Pg/g
0.394 5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
104
Pg/g
0.636 5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
207
Pg/g
0.918 10.0
51207-31-9
2,3,7,8-TCDF
19.9
Pg/g
0.140 1.00
57117-41-6
1,2,3,7,8-PeCDF
98.5
Pg/g
0.188 5.00
57117-31-4
2,3,4,7,8-PeCDF
100
Pg/g
0.181 5.00
70648-26-9
1,2,3,4,7,8-HxCDF
102
Pg/g
0.340 5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
105
Pg/g
0.338 5.00
60851-34-5
2,3,4,6,7,8-HxCDF
103
Pg/g
0.348 5.00
72918-21-9
1,2,3,7,8,9-HxCDF
109
Pg/g
0.480 5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
105
Pg/g
0.422 5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
103
Pg/g
0.662 5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
210
Pg/g
0.576 10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery% Acceptable Limits
13C-2,3,7,8-TCDD
166
200
Pg/g
82.8
(20%-175%)
13C-1,2,3,7,8-
PeCDD
193
200
Pg/g
96.3
(21 %-227%)
130-1,2,3,4,7,
8-HxCDD
156
200
Pg/g
77.8
(21%-193%)
130-1,2,3,6,7,
8-HxCDD
162
200
Pg/g
81.1
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
171
200
Pg/g
85.7
(22%-166%)
13C-OCDD
337
400
Pg/g
84.3
(13%-199%)
13C-2,3,7,8-TCDF
183
200
Pg/g
91.3
(22%-152%)
13C-1,2,3,7,8-
PeCDF
200
200
Pg/g
99.8
(21%-192%)
130-2,3,4,7,8-
PeCDF
200
200
Pg/g
99.9
(13%-328%)
130-1,2,3,4,7,
8-HxCDF
161
200
Pg/g
80.4
(19%-202%)
130-1,2,3,6,7,
8-HxCDF
159
200
Pg/g
79.5
(21 %-159%)
130-2,3,4,6,7,
8-HxCDF
165
200
Pg/g
82.4
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
163
200
Pg/g
81.7
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
169
200
Pg/g
84.5
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
175
200
Pg/g
87.5
(20%-186%)
3701-2,3,7,8-TCDD
20.0
20.0
Pg/g
100
(31 %-191%)
Comments:
Page 20 of 21
-------
Cape Fear Analytical LLC
Report Date:
August 5, 2014
SDG Number:
Lab Sample ID:
Client Sample:
Client ID:
Batch ID:
Run Date:
Data File:
Prep Batch:
6430
12011087
QC for batch 26578
LCSD for batch 26578
26580
08/04/2014 12:44
A04AUG14A-3
26578
Hi-Res Dioxins/Furans
Certificate of Analysis
Sample Summary
1 of 1
Client:
Method:
Analyst:
TETR001
EPA Method 1613B
JTF
Project:
Matrix:
Prep Basis:
Instrument:
Dilution:
Prep Method: SW846 3540C
TETR00114
SOLID
As Received
HRP750
1
Prep Date:
31-JUL-14
Prep Aliquot:
10 g
CAS No.
Parmname
Qual
Result
Units
EDL
PQL
1746-01-6
2,3,7,8-TCDD
22.3
Pg/g
0.108
1.00
40321-76-4
1,2,3,7,8-PeCDD
106
Pg/g
0.210
5.00
39227-28-6
1,2,3,4,7,8-HxCDD
105
Pg/g
0.422
5.00
57653-85-7
1,2,3,6,7,8-HxCDD
104
Pg/g
0.402
5.00
19408-74-3
1,2,3,7,8,9-HxCDD
115
Pg/g
0.438
5.00
35822-46-9
1,2,3,4,6,7,8-HpCDD
104
Pg/g
0.482
5.00
3268-87-9
1,2,3,4,6,7,8,9-OCDD
206
Pg/g
0.706
10.0
51207-31-9
2,3,7,8-TCDF
20.2
Pg/g
0.115
1.00
57117-41-6
1,2,3,7,8-PeCDF
101
Pg/g
0.246
5.00
57117-31-4
2,3,4,7,8-PeCDF
103
Pg/g
0.232
5.00
70648-26-9
1,2,3,4,7,8-HxCDF
103
Pg/g
0.392
5.00
57II7.44.9
1,2,3,6,7,8-HxCDF
110
Pg/g
0.382
5.00
60851-34-5
2,3,4,6,7,8-HxCDF
105
Pg/g
0.402
5.00
72918-21-9
1,2,3,7,8,9-HxCDF
108
Pg/g
0.556
5.00
67562-39-4
1,2,3,4,6,7,8-HpCDF
105
Pg/g
0.442
5.00
55673-89-7
1,2,3,4,7,8,9-HpCDF
103
Pg/g
0.640
5.00
39001-02-0
1,2,3,4,6,7,8,9-OCDF
208
Pg/g
0.744
10.0
Surrogate/Tracer recovery
Qual Result
Nominal
Units
Recovery%
Acceptable Limits
13C-2,3,7,8-TCDD
175
200
Pg/g
87.6
(20%-175%)
13C-1,2,3,7,8-PeCDD
190
200
Pg/g
95.0
(21 %-227%)
13C-1,2,3,4,7,8-HxCDD
163
200
Pg/g
81.3
(21%-193%)
13C-1,2,3,6,7,8-HxCDD
160
200
Pg/g
79.8
(25%-163%)
13C-1,2,3,4,6,7,8-HpCDD
181
200
Pg/g
90.3
(22%-166%)
13C-OCDD
356
400
Pg/g
89.0
(13%-199%)
13C-2,3,7,8-TCDF
198
200
Pg/g
98.9
(22%-152%)
13C-1,2,3,7,8-PeCDF
201
200
Pg/g
100
(21%-192%)
13C-2,3,4,7,8-PeCDF
206
200
Pg/g
103
(13%-328%)
13C-1,2,3,4,7,8-HxCDF
167
200
Pg/g
83.5
(19%-202%)
13C-1,2,3,6,7,8-HxCDF
164
200
Pg/g
82.0
(21 %-159%)
13C-2,3,4,6,7,8-HxCDF
170
200
Pg/g
84.8
(22%-176%)
13C-1,2,3,7,8,9-HxCDF
173
200
Pg/g
86.5
(17%-205%)
13C-1,2,3,4,6,7,8-HpCDF
174
200
Pg/g
87.1
(21%-15 8%)
13C-1,2,3,4,7,8,9-HpCDF
187
200
Pg/g
93.4
(20%-186%)
37Cl-2,3,7,8-TCDD
20.7
20.0
Pg/g
104
(31 %-191%)
Comments:
Page 21 of 21
-------
GEL
Laboratories llc
a member of The GEL Group inc.
m,
PO Box 30712
2040 Savage Road
P 843.556.8171 F 843.766.1178
Charleston, SC 29417
Charleston, SC 29407
www.gel.com
March 06, 2014
Mr. Dave Kinroth
Seagull Environmental Technologies, Inc.
20 James Town Farm Drive
Florissant, Missouri 63034
Re: Strecker Forest Removal
Work Order: 343609
Dear Mr. Kinroth:
GEL Laboratories, LLC (GEL) appreciates the opportunity to provide the enclosed analytical results for the
sample(s) we received on February 18, 2014. This original data report lias been prepared and reviewed in
accordance with GEL's standard operating procedures.
Our policy is to provide high quality, personalized analytical services to enable you to meet your analytical needs
on time every time. We trust that you will find everything in order and to your satisfaction. If you have any
questions, please do not hesitate to call me at (843) 556-8171, ext. 4485.
Sincerely,
oo>
Hope Taylor for
Valerie Davis
Project Manager
Purchase Order: 1096441
Enclosures
-------
Table of Contents
Case Narrative 1
Chain of Custody and Supporting Documentation 4
Laboratory Certifications 7
Volatile Analysis 9
Case Narrative 10
Sample Data Summary 15
Quality Control Summary 18
Miscellaneous 31
Semi-Volatile Analysis 33
Case Narrative 34
Sample Data Summary 40
Quality Control Summary 44
Miscellaneous 60
PCB Analysis 62
Case Narrative 63
Sample Data Summary 68
Quality Control Summary 70
Metals Analysis 74
Case Narrative 75
Sample Data Summary 80
-------
Quality Control Summary
-------
Case Narrative
Page 1 of 86
-------
Tetra Tech, Inc. (Contract#)
Strecker Forest Removal
SDG: 343609
Page 2 of 86
-------
Receipt Narrative
for
Tetra Tech, Inc. (Contract#)
SDG: 343609
March 06,2014
Laboratory Identification:
GEL Laboratories LLC
2040 Savage Road
Charleston, South Carolina 29407
(843) 556-8171
Summary:
Sample receipt: The sample arrived at GEL Laboratories LLC, Charleston, South Carolina on February 18,
2014 for analysis. The sample was delivered with proper chain of custody documentation and signatures. All
sample containers arrived without any visible signs of tampering or breakage. There are no additional comments
concerning sample receipt.
Sample Identification: The laboratory received the following sample:
Case Narrative:
Sample analyses were conducted using methodology as outlined in GEL's Standard Operating Procedures. Any
technical or administrative problems during analysis, data review, and reduction are contained in the analytical
case narratives in the enclosed data package.
The enclosed data package contains the following sections: Case Narrative, Chain of Custody, Cooler Receipt
Checklist, Data Package Qualifier Definitions and data from the following fractions: GC Semivolatile PCB,
GC/MS Semivolatile, GC/MS Volatile and Metals.
Laboratory ID Client ID
343609001 SFRA-3
Hope Taylor tor
Valerie Davis
Project Manager
Page 3 of 86
-------
Chain of Custody and
Supporting
Documentation
Page 4 of 86
-------
i VoJeA -*Wr
Cell
CHAIN OF CUSTODY RECORD
ENVIRONMENTAL PROTECTION AGENCY REGION VII
3&&
ACTIVITY LEADERjtPrint) 14 3W-ST1-
DERiPrint) . 1
KuArfm/v-
fcT? ft
NAME OF SURVEY OR ACTIVITY
A dh\ey\
DAJ^OF COLLECTION
" m MONT
MONTH YEAS
TheeT
of
CONTENTS OF SHIPMENT
SAMPLE
NUMBER
TYPE OF CONTAINERS
SAMPLED MEDIA
RECEIVING LABORATORY
REMARKS/OTHER INFORMATION
(condition of samples upon receipt,
other sample numbers, etc )
Q>ctl<
BOTTLE
rVOA SET
J^VIALS EA)
water
o
sediment
"O
other
CUBITAINER
BOTTLE
BOnLE
NUMBERS OF CONTAINERS PER SAMPLE NUMBER
S^A-3
,1
/
X
AvvflWj'ZX- VOCS>
1>/gCa
tCAXAAb
|ff>^
DESCRIPTION OF SHIPMENT
MODE OF SHIPMENT
ftdp.'A
IE
/ ir.F CHEST(S); OTHER
. PIECE(S) CONSISTING OF.
. BOX(ES)
_X_ COMMERCIAL CARRIER:.
COURIER
SAMPLER CONVEYED
sim ffloft
(SHIPPING DOCUMENT NUMBER)
PERSONNEL CUSTODY RECORD
RELINQUISHED BY^AMPLER)
u
I SEALED
UNSEALED
JZ
DATE
P
n
TIME
M'.di
ZL
RECEIVED BY
SEALED
UNSEALED f"
REASON FOR CHANGE. OF CUSTODY
P&s Avuilyfr
rCUSTO
RELINQUISHED BY
SEALED
DATE
UNSEALED[
TIME
RECEIVED BY
•P' IvS aA-CT
REASON FOR CHANGE OFTUSTODY
RELINQUISHED BY
DATE
TIME
ZL SEALED
UNSEALED
RECEIVED BY
REASON FOR CHANGE OF CUSTODY
Q
SEALED
unsealed}
[ SEALED
UNSEALED [~
7-EPA-9262 (Revised 5/85)
'U.S. GPO: 2002-756-917/40053 gj)
-------
GEL
Client:
Laboratories llc
SAMPLE RECEIPT & REVIEW FORM
fi, llQlUtfr'
SDG/AR/COC/Worki Order:
Received By:
Date Received:
[£>M
Suspected Hazard Information
~If Net Counts > lOOcpm on samples not marked "radioactive", contact the Radiation Safety Group for further
investigation.
Counts Observed^ (Observed Counts - Area Background Counts):
COC/Samples marked as radioactive?
Maximum Net
Classified Radioactive 11 or 111 by RSO?
V
If yes, Were swipes taken of sample contatiners < action levels?
COC/Samples marked containing PCBs?
Package, COC, and/or Samples marked as
beryllium or asbestos containing?
If yes, samples are to be segregeated as Safety Controlled Samples, and opened by the GEL Safety Group.
Shipped as a DOT Hazardous?
Hazard Class Shipped:
UN#:
Samples identified as Foreign Soil?
Sample Receipt Criteria
Comments/Qualifiers (Required for Non-Conforming Items)
Shipping containers received intact
and sealed?
X
Circle Applicable:
Seals broken Damaged container Leaking container Other (describe)
na^dcguair
Samples requiring cold preservation
within (0 < 6 deg. C)?*
Preservation Method: kebags Blue ice Dry ice None Other (describe)
*all temperatures are recorded in Celsius
2a
Daily check performed and passed on
IR temperature gun?
Temperature Device Serial #:
Secondary Temperature Device Serial # (If Applicable):
l
Chain of custody documents included
with shipment?
Sample containers intact and sealed?
Circle Applicable:
Seals broken Damaged container Leaking container Other (describe)
Samples requiring chemical
preservation at proper pH?
1.
Sample ID's, containers affected and observed pH:
if Preserviiiipn added, ui#:
VOA vials free of headspace (defined
as < 6mm bubble)?
Sample ID's and containers affected:
Are Encore containers present?
Samples received within holding
time?
Sample ID's on COC match ID's on
bottles?
(If yes, immediately deliver to Volatiles laboratory)
ID's and tests affected:
Sample ID's and containers affected:
10
Date & time on COC match date &
time on bottles?
Sample ID's affected:
11
Number of containers received match
number indicated on COC?
Sample ID's affected:
12
Are sample containers identifiable as
GEL provided?
Yl QiievHS
13
COC form is properly signed in
relinquished/received sections?
Circle Applicable:
FedEx Air FedEx Ground UPS Field Services Courier Other
14
Carrier and tracking number.
Comments (Use Continuation Form if needed):
A
PM (or PMA) review: Initials .
Date
Page _
of
-------
Laboratory
Certifications
Page 7 of 86
-------
List of current GEL Certifications as of 06 March 2014
State
Certification
Alaska
UST-110
Arkansas
88-0651
CLIA
42D0904046
California NELAP
01151CA
Colorado
SC00012
Connecticut
PH-0169
Delaware
SC000122013-10
DoD ELAP/ ISO17025 A2LA
2567.01
Florida NELAP
E87156
Foreign Soils Permit
P330-12-00283, P330-12-00284
Georgia
SC00012
Georgia SDWA
967
Flawaii
SC000122013-10
Idaho Chemistry
SC00012
Idaho Radiochemistry
SC00012
Illinois NELAP
200029
Indiana
c-sc-oi
Kansas NELAP
E-10332
Kentucky
90129
Louisiana NELAP
03046 (AI33904)
Louisiana SDWA
LA 130005
Maryland
270
Massachusetts
M-SC012
Michigan
9976
Mississippi
SC000122013-10
Nebraska
NE-OS-26-13
Nevada
SC000122014-1
New Hampshire NELAP
2054
New Jersey NELAP
SC002
New Mexico
SC00012
New York NELAP
11501
North Carolina
233
North Carolina SDWA
45709
Oklahoma
9904
Pennsylvania NELAP
68-00485
Plant Material Permit
PDEP-12-00260
South Carolina Chemistry
10120001
South Carolina GVL
23611001
South Carolina Radiochemi
10120002
Tennessee
TN 02934
Texas NELAP
T104704235-14-9
Utah NELAP
SC000122013-11
Vermont
VT87156
Virginia NELAP
460202
Washington
C780-12
Wisconsin
999887790
Page 8 of 86
-------
Volatile Analysis
Page 9 of 86
-------
Case Narrative
Page 10 of 86
-------
ChemStation Case Narrative
Tetra Tech, Inc. (TETR)
SDG 343609
Method/Analvsis Information
Procedure:
Volatile Organic Compounds (VOC) by Gas Chromatograph/Mass
Spectrometer
Analytical Method:
Prep Method:
SW846 8260B
SW846 5030
Analytical Batch
Number:
1369457
Prep Batch Number:
1369456
Sample Analysis
The following client and quality control samples were analyzed to complete this SDG using the methods
referenced in the Analysis Information section:
NOTE: For volatile organic analyses the matrix spike designations may be indicated as "PS" or "PSD". The "PS"
designation (post spike) indicates that the matrix was fortified prior to analysis but after applying any prep
factors, such as a dilution. The laboratory considers the MS/MSD and PS/PSD designations interchangeable.
The samples in this SDG were analyzed on a "dry weight" basis.
Preparation/Analytical Method Verification
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as
Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with
GL-OA-E-038 REV# 21.
Raw data reports are processed and reviewed by the analyst using the Chemstation software package. False
positives have been removed from the quantitation reports per standard operating procedures (SOP) section
19.1.2. False positive analytes are designated on the quantitation report with a'd' qualifier.
Calibration Information
Sample ID Client ID
343609001 SFRA-3
1203042665 Method Blank (MB)
1203042666 343609001(SFRA-3) Post Spike (PS)
1203042667 343609001(SFRA-3) Post Spike Duplicate (PSD)
1203042668 Laboratory Control Sample (LCS)
1203042669 Laboratory Control Sample (LCS)
1203042797 343609001(SFRA-3) Post Spike (PS)
1203042798 343609001(SFRA-3) Post Spike Duplicate (PSD)
Page 11 of 86
-------
A complete list of the initial calibration data files with the correct dates and times of analysis are shown in the
Calibration History report located in the Standard Data section of the data package.
The surrogate compounds were calibrated using a minimum five-point calibration curve. The surrogates were
added by the auto sampler at a concentration of 50 ug/L or 20 ug/L for low level analyses. GEL Laboratories
LLC will not have surrogate recoveries reported for Dibromofluoromethane. This is due to increased regulations
for this analyte and an industry shortage.
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification Requirements
All associated calibration verification standard(s) (CCV) met the acceptance criteria.
Quality Control (OC) Information
Blank (MB) Statement
Target analytes were detected in the blank 1203042665 (MB) above the reporting limit. Acetone, a known lab
contaminant, was detected in the blank above the reporting limit; however, it was not detected in the client
sample. The sample was analyzed on the last day of holding; therefore, the data were reported.
Surrogate Recoveries
Surrogate recoveries in samples 1203042666(SFRA-3), 1203042667(SFRA-3), 203042797,
1203042798(SFRA-3) and 343609001(SFRA-3) were biased high outside of the acceptance limits. All of the
results confirmed each; therefore, the data were reported.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
QC Sample Designation
Sample 343609001 (SFRA-3) was designated for spike analysis.
Matrix Spike (PS) Recovery Statement
The spike 1203042666 (SFRA-3) recoveries were not all within the acceptance limits. See the Data Exception
Report in the miscellaneous section of the data package.
Matrix Spike Duplicate (PSD) Recovery Statement
The spike duplicate 1203042667 (SFRA-3) recoveries were not all within the acceptance limits. See the Data
Exception Report in the miscellaneous section of the data package.
Relative Percent Difference (RPD) Statement
The RPDs between the matrix spike pair met the acceptance limits.
Internal Standard (ISTD) Acceptance
Internal standard responses were outside of the acceptance criteria and very similar to those of the MS/MSD
pairs. The data were reported. 343609001 (SFRA-3).
Technical Information
Holding Time Specifications
GEL assigns holding times based on the associated methodology, which assigns the date and time from sample
collection or sample receipt. Those holding times expressed in hours are calculated in the ALPHALIMS system.
Those holding times expressed as days expire at midnight on the day of expiration. All samples in this SDG met
the specified holding time.
Page 12 of 86
-------
Sample Preservation and Integrity
All samples met the sample preservation and integrity requirements.
Sample Dilutions/Methanol Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-analyses were not required for samples in this SDG.
Miscellaneous Information
Data Exception (DER) Documentation
The following DER was generated for this SDG: 1271096 1203042665 (MB), 1203042666 (SFRA-3),
1203042667 (SFRA-3), 1203042797 (SFRA-3), 1203042798 (SFRA-3) and 343609001 (SFRA-3).
Manual Integrations
Data files associated with the initial calibration, continuing calibration check, and samples did not require
manual integrations.
TIC Comment
Tentatively identified compounds (TIC) were not required for this SDG.
Additional Comments
Additional comments were not required for this SDG.
Residual Chlorine
Residual Chlorine was not detected in any of the samples in this SDG.
System Configuration
The Volatile-GC/MS analysis was performed on the following instrument configuration:
Instrument
ID
VOA9.I
Instrument
Agilent 6890/5973
GC/MS w/ OI
Eclipse/Archon
Autosampler
System Column
Configuration ID
HP6890/HP5973 DB-624
Column
Description
J&W, 60m x
0.25mm x
1.4um
P&T
Trap
Trap
10
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 13 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Qualifier Definition Report
for
TETR055 Tetra Tech, Inc. (Contract#)
Client SDG: 343609 GEL Work Order: 343609
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
B The target analyte was detected in the associated blank.
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
DL Indicates that sample is diluted.
RA Indicates that sample is re-analyzed without re-extraction.
RE Indicates that sample is re-extracted.
Review /V alidation
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverables
receive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
Signature:
Name: Erin Haubert
Date: 05 MAR 2014
Title: Data Validator
Page 14 of 86
-------
Sample Data Summary
Page 15 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Certificate of Analysis
Company : Seagull Environmental Technologies, Inc.
Address : 20 James Town Farm Drive
Report Date: March 5, 2014
Contact:
Project:
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
Moisture:
Florissant, Missouri 63034
Mr. Dave Kinroth
Strecker Forest Removal
SFRA-3
343609001
Soil
13-FEB-14 10:02
18-FEB-14
Client
9.06%
Project:
Client ID:
TETR00055
TETR055
Parameter
Qualifier
Result
DL
RL
Units
DF Analyst Date
Time Batch Method
Volatile Organics
Volatiles "Dry Weight Corrected"
1,1,1 -Trichloroethane
u
ND
0.330
1.10
ug/kg
1 RXYl 02/27/14
1541 1369457 1
1,1,2,2-Tetrachloroethane
u
ND
0.330
1.10
ug/kg
1
1,1,2-Trichloroethane
u
ND
0.330
1.10
ug/kg
1
1,1 -Dichloroethane
u
ND
0.330
1.10
ug/kg
1
1,1 -Dichloroethylene
u
ND
0.330
1.10
ug/kg
1
1,2,3-Trichlorobenzene
u
ND
0.440
1.10
ug/kg
1
1,2,4-Trichlorobenzene
J
0.484
0.330
1.10
ug/kg
1
l,2-Dibromo-3-chloropropane
u
ND
0.550
1.10
ug/kg
1
1,2-Dibromoethane
u
ND
0.330
1.10
ug/kg
1
1,2-Dichlorobenzene
u
ND
0.330
1.10
ug/kg
1
1,2-Dichloroethane
u
ND
0.330
1.10
ug/kg
1
1,2-Dichloropropane
u
ND
0.330
1.10
ug/kg
1
1,3-Dichlorobenzene
u
ND
0.330
1.10
ug/kg
1
1,4-Dichlorobenzene
u
ND
0.330
1.10
ug/kg
1
2-Butanone
u
ND
1.65
5.50
ug/kg
1
2-Hexanone
u
ND
1.65
5.50
ug/kg
1
4-Methyl-2-pentanone
u
ND
1.65
5.50
ug/kg
1
Acetone
u
ND
1.65
5.50
ug/kg
1
Benzene
u
ND
0.330
1.10
ug/kg
1
Bromochloromethane
u
ND
0.330
1.10
ug/kg
1
Bromodichloromethane
u
ND
0.330
1.10
ug/kg
1
Bromoform
u
ND
0.330
1.10
ug/kg
1
Bromomethane
u
ND
0.330
1.10
ug/kg
1
Carbon disulfide
u
ND
1.65
5.50
ug/kg
1
Carbon tetrachloride
u
ND
0.330
1.10
ug/kg
1
Chlorobenzene
u
ND
0.330
1.10
ug/kg
1
Chloroethane
u
ND
0.330
1.10
ug/kg
1
Chloroform
u
ND
0.330
1.10
ug/kg
1
Chloromethane
u
ND
0.330
1.10
ug/kg
1
Cyclohexane
u
ND
0.330
1.10
ug/kg
1
Dibromochloromethane
u
ND
0.330
1.10
ug/kg
1
Dichlorodifluoromethane
u
ND
0.330
1.10
ug/kg
1
Ethylbenzene
u
ND
0.330
1.10
ug/kg
1
Isopropylbenzene
u
ND
0.330
1.10
ug/kg
1
Methyl acetate
u
ND
1.65
5.50
ug/kg
1
Methylcyclohexane
u
ND
0.440
1.10
ug/kg
1
Page 16 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Certificate of Analysis
Company : Seagull Environmental Technologies, Inc.
Address : 20 James Town Farm Drive
Report Date: March 5, 2014
Contact:
Project:
Client Sample ID:
Sample ID:
Florissant, Missouri 63034
Mr. Dave Kinroth
Strecker Forest Removal
SFRA-3
343609001
Project:
Client ID:
TETR00055
TETR055
Volatile Organics
Volatiles "Dry Weight Corrected"
Methylene chloride
U
ND
2.20
5.50
ug/kg
1
Styrene
U
ND
0.330
1.10
ug/kg
1
Tetrachloroethylene
u
ND
0.330
1.10
ug/kg
1
Toluene
u
ND
0.330
1.10
ug/kg
1
Trichloroethylene
u
ND
0.330
1.10
ug/kg
1
Trichlorofluoromethane
u
ND
0.330
1.10
ug/kg
1
1,1,2-Trichloro-1,2,2-
u
ND
1.65
5.50
ug/kg
1
trifluoroethane
Vinyl chloride
u
ND
0.330
1.10
ug/kg
1
cis-1,2-Dichloroethylene
u
ND
0.330
1.10
ug/kg
1
cis-1,3-Dichloropropylene
u
ND
0.330
1.10
ug/kg
1
m,p-Xylenes
u
ND
0.330
2.20
ug/kg
1
o-Xylene
u
ND
0.330
1.10
ug/kg
1
tert-Butyl methyl ether
u
ND
0.330
1.10
ug/kg
1
trans-1,2-Dichloroethylene
u
ND
0.330
1.10
ug/kg
1
trans-1,3-Dichloropropylene
u
ND
0.330
1.10
ug/kg
1
The following Prep Methods were performed:
Method
Description
Analyst
Date
Time Prep Batch
SW846 5030
Volatile 5030 Solid Prep
RXYl
02/27/14
1330 1369456
The following Analytical Methods were performed:
Method
Description
Analyst Comments
l
SW846 8260B
Surrogate/Tracer Recovery Test
Result
Nominal Recovery% Acceptable Limits
l,2-Dichloroethane-d4
Volatiles
'Dry Weight Corrected"
52.5
ug/kg
50.0 95.5 (76%-122%)
Bromofluorobenzene
Volatiles
'Dry Weight Corrected"
71.5
ug/kg
50.0 130* (80%-120%)
Toluene-d8
Volatiles
'Dry Weight Corrected"
63.8
ug/kg
50.0 116 (80%-120%)
Notes:
Page 17 of 86
-------
Quality Control
Summary
Page 18 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Contact:
Workorder:
Seagull Environmental Technologies, Inc.
20 James Town Farm Drive
Florissant, Missouri
Mr. Dave Kinroth
343609
Report Date: March 5, 2014
Page 1 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
QC1203042668 LCS
1,1,1 -T richloroethane
1,1,2,2-Tetrachloroethane
1.1.2-Trichloroethane
1,1 -Dichloroethane
1,1 -Dichloroethy lene
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1.2-Dichloropropane
1.3-Dichlorobenzene
1.4-Dichlorobenzene
2-Butanone
2-Hexanone
4-Methyl-2-pentanone
Acetone
Benzene
Bromochloromethane
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
250
250
250
50.0
50.0
B
48.3
51.0
49.2
47.8
45.4
52.3
53.1
42.9
50.4
50.5
45.1
47.1
49.4
49.0
221
262
246
238
45.5
46.5
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
96.7 (79%-125%) RXY1 02/27/14 09:06
102 (77%-120%)
98.4 (77%-120%)
95.5 (75%-120%)
90.8 (77%-125%)
105 (62%-129%)
106 (67%-126%)
85.9 (62%i-133%i)
101 (80%-120%)
101 (77%-120%)
90.1 (69%-120%)
94.2 (75%-120%)
98.8 (76%-120%)
98 (77%-120%)
88.3 (57%-149%)
105 (69%-145%)
98.4 (79%-129%)
95.4 (55%-146%)
90.9 (74%-120%)
92.9 (80%-120%)
Page 19 of 86
-------
Workorder: 343609
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 2 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
Methyl acetate
Methylcyclohexane
Methylene chloride
Styrene
T etrachloroethy lene
Toluene
Trichloroethylene
50.0
50.0
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
48.5
44.3
44.2
256
50.4
49.1
46.0
46.0
46.3
50.0
51.2
52.5
49.5
52.1
257
50.4
42.0
52.2
49.2
48.5
46.8
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
97 (77%-121%) RXY1 02/27/14 09:06
88.6 (62%-132%)
88.4 (67%-120%)
103 (78%-136%)
101 (80%-127%)
98.2 (78%-120%)
91.9 (70%-120%)
91.9 (75%-120%)
92.6 (59%-124%)
100 (75%-123%)
102 (72%-123%)
105 (58%-126%)
98.9 (77%-120%)
104 (78%-120%)
103 (65%-129%)
101 (77%-121%)
83.9 (73%-120%)
104 (80%-120%)
98.5 (77%-120%)
97.1 (75%-120%)
93.5 (80%-120%)
Page 20 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 3 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
Trichlorofluoromethane
Vinyl chloride
cis-1,2-Dichloroethylene
cis-1,3-Dichloropropylene
m,p-Xylenes
o-Xylene
tert-Butyl methyl ether
trans-1,2-Dichloroethylene
trans-1,3-Dichloropropylene
* * 1,2-Dichloroethane-d4
* *Bromofluorobenzene
**Toluene-d8
QC1203042669 LCS
1,1,2-Trichloro-1,2,2-
trifluoroethane
* * 1,2-Dichloroethane-d4
* *Bromofluorobenzene
**Toluene-d8
QC1203042665 MB
1,1,1 -T richloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloro-1,2,2-
trifluoroethane
1,1,2-Trichloroethane
1,1 -Dichloroethane
1,1 -Dichloroethy lene
50.0
50.0
50.0
50.0
100
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
U
U
U
U
U
U
45.1
46.3
48.1
43.5
101
51.6
47.9
45.9
53.6
47.8
51.4
50.9
211
48.0
52.3
49.8
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/L
ug/L
ug/L
ug/kg
ug/L
ug/L
ug/L
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
90.3 (71%-120%)
92.5 (58%-122%) RXY1 02/27/14 09:06
96.1 (76%-120%)
87 (79%-121%)
101 (79%-120%)
103 (78%-120%)
95.7 (78%-120%)
91.7 (76%-120%)
107 (75%-120%)
95.5 (76%-122%)
103 (80%-120%)
102 (80%-120%)
84.4 (76%-130%)
96 (76%-122%)
105 (80%-120%)
99.7 (80%-120%)
02/27/14 14:45
02/27/14 15:13
Page 21 of 86
-------
Workorder: 343609
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 4 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1.2-Dichloropropane
1.3-Dichlorobenzene
1.4-Dichlorobenzene
2-Butanone
2-Hexanone
4-Methyl-2-pentanone
Acetone
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
6.76
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
RXY1 02/27/14 15:13
Page 22 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 5 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
Methyl acetate
Methylcyclohexane
Methylene chloride
Styrene
T etrachloroethy lene
Toluene
Trichloroethylene
Trichlorofluoromethane
Vinyl chloride
cis-1,2-Dichloroethylene
cis-1,3-Dichloropropylene
m,p-Xylenes
o-Xylene
tert-Butyl methyl ether
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
RXY1 02/27/14 15:13
Page 23 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 6 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
trans-1,2-Dichloroethy lene
trans-1,3-Dichloropropylene
* 1,2-Dichloroethane-d4
*Bromofluorobenzene
*Toluene-d8
QC1203042666 343609001 PS
1,1,1 -T richloroethane
1,1,2,2-Tetrachloroethane
1.1.2-Trichloroethane
1,1 -Dichloroethane
1,1 -Dichloroethy lene
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1.2-Dichloropropane
1.3-Dichlorobenzene
1.4-Dichlorobenzene
2-Butanone
2-Hexanone
4-Methyl-2-pentanone
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
250
250
U
U
U
U
U
U
J
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
0.440
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
47.7
49.6
50.9
41.7
62.3
47.2
42.0
39.5
21.0
23.8
43.5
46.5
42.3
38.9
39.9
43.2
42.2
178
220
228
ug/kg
ug/kg
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
RXY1 02/27/14 15:13
95.3 (76%-122%)
99.3 (80%-120%)
102 (80%-120%)
83.4 (71%-128%)
125 (68%-132%)
94.4 (73%-121%)
84 (70%-125%)
78.9 (67%i-135%i)
42* (50%-136%)
46.8* (49%)-138%))
87.1 (54%-133%)
92.9 (73%-125%)
84.5 (63%-123%)
77.7 (67%-119%)
79.7 (69%-122%)
86.3 (62%-125%)
84.4 (62%-122%)
71.1 (44%-145%)
88.1 (47%-147%)
91.2 (71%-133%)
02/27/14 16:10
-------
Workorder: 343609
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 7 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
Acetone
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
Methyl acetate
Methylcyclohexane
Methylene chloride
Styrene
250
50.0
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
u
u
u
ND B
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
198
40.0
40.7
41.1
51.7
45.3
202
41.0
42.3
50.1
41.3
51.1
35.2
45.7
56.8
42.7
58.5
233
26.5
37.8
39.9
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
79.1 (42%-147%) RXY1 02/27/14 16:10
80.1 (67%-124%)
81.4 (73%-123%)
82.2 (67%-124%)
103 (54%-131%)
90.6 (47%o-135%i)
80.7 (64%-147%)
82 (70%-129%)
84.6 (68%-120%)
100 (52%-129%)
82.6 (70%-123%)
102 (54%-139%)
70.3 (64%-130%)
91.5 (66%-122%)
114 (46%-134%)
85.5 (63%-122%)
117 (64%-132%)
93.3 (59%)-137%))
52.9* (63%)-130%))
75.6 (68%-123%)
79.7 (70%-126%)
Page 25 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 8 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
Tetrachloroethylene 50.0 U ND
Toluene 50.0 U ND
Trichloroethylene 50.0 U ND
Trichlorofluoromethane 50.0 U ND
Vinyl chloride 50.0 U ND
cis-l,2-Dichloroethylene 50.0 U ND
cis-l,3-Dichloropropylene 50.0 U ND
m,p-Xylenes 100 U ND
o-Xylene 50.0 U ND
tert-Butyl methyl ether 50.0 U ND
trans-1,2-Dichloroethylene 50.0 U ND
trans-l,3-Dichloropropylene 50.0 U ND
**l,2-Dichloroethane-d4 50.0 47.8
**Bromofluorobenzene 50.0 65.0
**Toluene-d8 50.0 58.0
QC1203042797 343609001 PS
1,1,2-Trichloro-1,2,2- 250 U ND
trifluoroethane
**l,2-Dichloroethane-d4 50.0 47.8
**Bromofluorobenzene 50.0 65.0
**Toluene-d8 50.0 58.0
QC1203042667 343609001 PSD
1.1.1-Trichloroethane 50.0 U ND
1,1,2,2-Tetrachloroethane 50.0 U ND
1.1.2-Trichloroethane 50.0 U ND
42.2
47.6
39.9
47.6
49.5
41.2
32.8
84.1
42.1
40.2
39.0
46.6
46.3
65.0
55.9
220
48.2
65.4
56.5
41.5
62.7
46.9
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L 0.481
84.3 (64%-123%)
95.2 (64%-124%) RXY1 02/27/14 16:10
79.7 (68%-130%)
95.1 (61%-126%)
98.9 (47%-141%)
82.3 (70%-125%)
65.6* (67%-127%)
84.1 (62%-124%)
84.1 (64%-122%)
80.5 (72%-118%)
77.9 (67%-129%)
93.2 (68%-122%)
92.6 (76%-122%)
130* (80%-120%)
112 (80%-120%)
88.1 (68%-146%)
96.4 (76%-122%)
131* (80%-120%)
113 (80%-120%)
83 (0%-20%)
02/27/14 17:07
02/27/14 16:38
ug/L 0.576 125 (0%-20%)
ug/L 0.702 93.7 (0%-20%)
Page 26 of 86
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Workorder: 343609
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 9 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
1,1 -Dichloroethane
1,1 -Dichloroethy lene
1.2.3-Trichlorobenzene
1.2.4-Trichlorobenzene
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane
1,2-Dichlorobenzene
1,2-Dichloroethane
1.2-Dichloropropane
1.3-Dichlorobenzene
1.4-Dichlorobenzene
2-Butanone
2-Hexanone
4-Methyl-2-pentanone
Acetone
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
50.0 U ND 41.7 ug/L 0.741 83.4 (0%-20%) RXY1 02/27/14 16:38
50.0 U ND 40.0 ug/L 1.43 80.1 (0%-20%)
50.0 U ND 19.3 ug/L 8.55 38.5* (0%-20%)
50.0 J 0.440 22.8 ug/L 4.37 44.8* (0%-20%)
50.0 U ND 42.1 ug/L 3.41 84.2 (0%-20%)
50.0 U ND 46.2 ug/L 0.475 92.5 (0%-20%)
50.0 U ND 41.6 ug/L 1.57 83.2 (0%-20%)
50.0 U ND 39.4 ug/L 1.35 78.8 (0%-20%)
50.0 U ND 41.0 ug/L 2.80 82 (0%-20%)
50.0 U ND 42.8 ug/L 0.931 85.5 (0%-20%)
50.0 U ND 42.9 ug/L 1.69 85.8 (0%-20%)
250 U ND 182 ug/L 2.15 72.6 (0%-20%)
250 U ND 215 ug/L 2.39 86 (0%-20%)
250 U ND 223 ug/L 2.13 89.3 (0%-20%)
250 U ND B 197 ug/L 0.624 78.6 (0%-20%)
50.0 U ND 40.4 ug/L 1.02 80.9 (0%-20%)
50.0 U ND 39.9 ug/L 1.93 79.9 (0%-20%)
50.0 U ND 42.1 ug/L 2.52 84.3 (0%-20%)
50.0 U ND 52.3 ug/L 0.981 105 (0%-20%)
50.0 U ND 41.0 ug/L 9.92 82 (0%-20%)
250 U ND 196 ug/L 2.86 78.4 (0%-20%)
Page 27 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 10 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
Cyclohexane
Dibromochloromethane
Dichlorodifluoromethane
Ethylbenzene
Isopropylbenzene
Methyl acetate
Methylcyclohexane
Methylene chloride
Styrene
T etrachloroethy lene
Toluene
Trichloroethylene
Trichlorofluoromethane
Vinyl chloride
cis-1,2-Dichloroethylene
cis-1,3-Dichloropropylene
m,p-Xylenes
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
250
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
50.0
100
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
u
u
u
u
u
u
u
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
41.6 ug/L 1.31 83.1 (0%-20%)
43.2 ug/L 2.17 86.5 (0%-20%) RXY1 02/27/14 16:38
44.9 ug/L 10.9 89.9 (0%-20%)
40.5 ug/L 2.05 80.9 (0%-20%)
46.3 ug/L 9.87 92.5 (0%-20%)
36.1 ug/L 2.58 72.1 (0%-20%)
45.9 ug/L 0.306 91.7 (0%-20%)
52.4 ug/L 8.21 105 (0%-20%)
43.4 ug/L 1.53 86.8 (0%-20%)
59.5 ug/L 1.66 119 (0%-20%)
207 ug/L 12.1 82.7 (0%-20%)
28.2 ug/L 6.40 56.4* (0%-20%)
37.7 ug/L 0.238 75.4 (0%-20%)
41.5 ug/L 3.91 82.9 (0%-20%)
42.4 ug/L 0.686 84.9 (0%-20%)
47.0 ug/L 1.20 94.1 (0%-20%)
40.1 ug/L 0.675 80.3 (0%-20%)
43.2 ug/L 9.56 86.4 (0%-20%)
45.5 ug/L 8.27 91.1 (0%-20%)
40.9 ug/L 0.732 81.7 (0%-20%)
33.1 ug/L 0.971 66.2* (0%-20%)
86.3 ug/L 2.52 86.3 (0%-20%)
Page 28 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 11 of 12
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
V olatile-GC/MS
Batch 1369457
o-Xylene 50.0 U ND
tert-Butyl methyl ether 50.0 U ND
trans-1,2-Dichloroethylene 50.0 U ND
trans-l,3-Dichloropropylene 50.0 U ND
**l,2-Dichloroethane-d4 50.0 47.8
**Bromofluorobenzene 50.0 65.0
**Toluene-d8 50.0 58.0
QC1203042798 343609001 PSD
1,1,2-Trichloro-1,2,2- 250 U ND
trifluoroethane
**l,2-Dichloroethane-d4 50.0 47.8
**Bromofluorobenzene 50.0 65.0
**Toluene-d8 50.0 58.0
42.6
40.6
39.5
45.6
46.5
66.0
55.1
198
47.1
65.9
56.6
ug/L 1.16
ug/L 0.792
ug/L 1.30
ug/L 2.19
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
85.1 (0%-20%)
81.1 (0%-20%) RXY1 02/27/14 16:38
79 (0%-20%)
91.2 (0%-20%)
92.9 (76%-122%)
132* (80%-120%)
110 (80%-120%)
79.3 * (0%-20%)
94.2 (76%-122%)
132* (80%-120%)
113 (80%-120%)
02/27/14 17:35
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a surrogate compound
< Result is less than value reported
> Result is greater than value reported
A The TIC is a suspected aldol-condensation product
B The target analyte was detected in the associated blank.
C Analyte has been confirmed by GC/MS analysis
D Results are reported from a diluted aliquot of the sample
E Concentration of the target analyte exceeds the instrument calibration range
H Analytical holding time was exceeded
J Value is estimated
JNX Non Calibrated Compound
N Organics—Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based
on nearest internal standard response factor
N Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based on nearest
internal standard response factor
Page 29 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 12 of 12
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
P Organics—The concentrations between the primary and confirmation columns/detectors is >40% different. For HPLC, the difference is >70%.
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UJ Compound cannot be extracted
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y QC Samples were not spiked with this compound
A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 30 of 86
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Miscellaneous
Page 31 of 86
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GEL Laboratories LLC
Form GEL-DER
DER Report No.: 1271096
Revision No.:
DATA EXCEPTION REPORT
Mo.Day Yr.
28-FEB-14
Division:
Industrial
Quality Criteria:
Specifications
Type:
Process
Instrument Type:
VOA GC/MS
Test / Method:
SW846 8260 B
Matrix Type:
Solid
Client Code:
TETR 343609
Batch ID:
1369457
Sample Numbers:
343609001, 1203042665, 1203042666, 1203042667, 1203042797, 1203042798
Potentially affected work order(s)(SDG): 343609
Application Issues:
Failed Recovery for MS/PS
Method Blank contamination
Other
Failed Yield for Surrogates
Failed Recovery for MSD/PSD
Specification and Requirements
Exception Description:
DER Disposition:
1. Samples 343609001, 1203042666/2667, 1203042797/2798 did not
meet the acceptable recovery criteria for several of the target
compounds.
2. Samples 343609001, 1203042666/2667, 1203042797/2798 did not
meet the acceptable recovery criteria for surrogate recoveries.
3. Sample 343609001 did not meet the acceptable recovery criteria for
the internal standards.
4. QC sample MB 1203042665 contained a result for Acetone at 6.76
ug/kg.
1/2/3. The samples recovered in a very similar manner; therefore,
indicating the presence of matrix interference. The samples were analyzed
and reported on the last day of holding.
4. Acetone, a known lab contaminant, was not detected insample
343609001; therefore, the data were narrated and reported on the last day
of holding.
Originator's Name: Data Validator/Group Leader:
Ramona Yarbrough 28-FEB-14 Erin Haubert 05-MAR-14
Page 32 of 86
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Semi-Volatile Analysis
Page 33 of 86
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Case Narrative
Page 34 of 86
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Semi-Volatile Case Narrative
Tetra Tech, Inc. (TETR)
SDG 343609
Method/Analvsis Information
Procedure:
Analysis of Semivolatile Organic Compounds by Gas Chromatography/Mass
Spectrometry
Analytical Method: SW846 3541/8270D
Prep Method:
SW846 3541
Analytical Batch
Number:
1369009
Prep Batch Number: 1369008
Sample Analysis
The following samples were analyzed using the analytical protocol as established in SW846 3541/8270D:
The samples in this SDG were analyzed on a "dry weight" basis.
Preparation/Analytical Method Verification
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as
Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with
GL-OA-E-009 REV# 32.
Raw data reports are processed and reviewed by the analyst using the data analysis software package. False
positives have been removed from the quantitation reports per standard operating procedures (SOP).
Calibration Information
A complete list of the initial calibration data files are shown in the Calibration History report located in the
Standard Data section of the data package. The various calibration mixes may not be calibrated using all of the
calibration levels. In addition, not all of the mixes are calibrated using the same levels.
Diphenylamine has now superseded N-Nitroso-diphenylamine on Quantitation Reports, Initial Calibration
Reports, Calibration Check Standard Reports, etc. Previous versions of EPA Methodologies referenced
N-Nitroso-diphenylamine. However, as stated in EPA Methodology, "N-Nitroso-diphenylamine decomposes in
the gas chromatographic inlet and cannot be separated from Diphenylamine." Studies of these two compounds at
Sample ID Client ID
343609001 SFRA-3
1203041530 Method Blank (MB)
1203041531 Laboratory Control Sample (LCS)
1203041532 34360900l(SFRA-3) Matrix Spike (MS)
1203041533 34360900l(SFRA-3) Matrix Spike Duplicate (MSD)
Page 35 of 86
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GEL, both independent of each other and together, showed that they not only co-elute, but also have similar
mass spectra. N-Nitroso-diphenylamine and Diphenylamine will be reported as Diphenylamine on all reports and
forms.
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG) in this batch. A second
source initial calibration verification (ICV) was included in the standard section directly behind the initial
calibration.
CCV Requirements
All associated calibration verification standard(s) (ICV or CCV) met the acceptance criteria.
Quality Control (OC) Information
Method Blank (MB) Statement
The MB analyzed with this SDG in this batch met the acceptance criteria.
Surrogate Recoveries
All the surrogate recoveries were within the established acceptance criteria for this SDG in this batch.
Laboratory Control Sample (LCS) Recovery
The LCS(1203041531) recovered Hexachlorocyclopentadiene at 22.8%. The limits are 24%-84%.
Hexachlorocyclopentadiene is known to be a poor responding analyte that is subject to thermal decomposition as
stated in the Method. This may account for the low recovery of the analyte in the LCS, as well as the zero
percent recoveries in the MS and MSD. The data results have been reported.
QC Sample Designation
Sample 343609001 (SFRA-3) was selected for analysis as the matrix spike and matrix spike duplicate.
Matrix Spike (MS) Recovery Statement
The MS(1203041532(SFRA-3)) recovered Hexachlorocyclopentadiene at 0% (limits are 12%-106%) and
N-Nitrosodipropylamine at 0% (limits are 23%-117%). Hexachlorocyclopentadiene is known to be a poor
responding analyte that is subject to thermal decomposition as stated in the Method. This may account for the
zero percent recoveries in the MS and MSD, as well as the low recovery of the analyte in the LCS. Since both
the MS and MSD displayed failures and the sample data chromatograms displayed excessive matrix interference,
the failures were attributed to sample matrix interference and the data results have been reported.
Matrix Spike Duplicate (MSD) Recovery Statement
The MSD(1203041533) recovered Hexachlorocyclopentadiene at 0% (limits are 12%-106%) and
2,4-Dinitrophenol at 12.5% (limits are 19%-101%). Hexachlorocyclopentadiene is known to be a poor
responding analyte that is subject to thermal decomposition as stated in the Method. This may account for the
zero percent recoveries in the MS and MSD, as well as the low recovery of the analyte in the LCS. Since both
the MS and MSD displayed failures and the sample data chromatograms displayed excessive matrix interference,
the failures were attributed to sample matrix interference and the data results have been reported. 1203041533
(SFRA-3) and All.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD values between the MS and MSD met the acceptance limits.
Internal Standard (ISTD) Acceptance
The internal standard responses used to quantitate the requested target analytes were within the required
acceptance criteria for the SDG associated samples in this batch.
Technical Information:
Holding Time Specifications
Page 36 of 86
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All samples in this SDG met the specified holding time. GEL assigns holding times based on the associated
methodology that assigns the date and time from sample collection or sample receipt. Those holding times
expressed in hours are calculated in the ALPHALIMS system. Those holding times expressed as days expire at
midnight on the day of expiration.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP. All reported compound mass spectra met the detection
specifications in the method.
Sample Dilutions
The samples in this SDG in this batch did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG in this analytical batch unless confirmations or
dilutions were required.
Miscellaneous Information:
Data Exception (DER) Documentation
Data exception report 1271086 was generated for the samples in this batch for this SDG.
Manual Integrations
Some initial calibration standards, continuing calibration standards, and/or samples may require manual
integrations due to software limitations. Manual integrations, if any, are included with the raw data.
TIC Comment
Tentatively identified compounds (TIC) were not required for the samples in this SDG for this batch.
Additional Comments
Additional comments were not required for the SDG associated samples in this batch.
Electronic Package Comment
The following package was generated using an electronic data processing program referred to as "virtual
packaging". In an effort to increase quality and efficiency, the laboratory is developing systems to eventually
generate all data packages electronically. The following change from "traditional" packages should be noted:
Analyst/peer reviewer initials and dates are not present on the electronic data files. Presently, all initials and
dates are present on the original raw data. These hard copies are temporarily stored in the laboratory. An
electronic signature page inserted after the case narrative of each electronic package will indicate the reviewer
name associated with the generation of the data and package. The data validator will always sign and date the
case narrative. Data that are not generated electronically, such as hand written pages, will be scanned and
inserted into the electronic package.
System Configuration
The Semi-Volatile-GC/MS analysis was performed on the following instrument configuration:
Instrument
ID
Instrument
System
Configuration
Column
ID
Column Description
Agilent 6890/5973
MSD5.I GC/MSw/7683 HP6890/HP5973 DB-5MS
25m x 0.2mm, 0.33um (5%
Phenylmethylpolysiloxane)
Autosampler
Page 37 of 86
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Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 38 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Qualifier Definition Report
for
TETR055 Tetra Tech, Inc. (Contract#)
Client SDG: 343609 GEL Work Order: 343609
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
DL Indicates that sample is diluted.
RA Indicates that sample is re-analyzed without re-extraction.
RE Indicates that sample is re-extracted.
Review /V alidation
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverables
receive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
Signature:
Name: Barbara Bailey
Date: 06 MAR 2014
Title: Data Validator
Page 39 of 86
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Sample Data Summary
Page 40 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Certificate of Analysis
Company : Seagull Environmental Technologies, Inc.
Address : 20 James Town Farm Drive
Report Date: February 28, 2014
Contact:
Project:
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
Moisture:
Florissant, Missouri 63034
Mr. Dave Kinroth
Strecker Forest Removal
SFRA-3
343609001
Soil
13-FEB-14 10:02
18-FEB-14
Client
9.06%
Project:
Client ID:
TETR00055
TETR055
Parameter
Qualifier
Result
DL
RL
Units
DF Analyst Date
Time Batch Method
Semi-Volatile-GC/MS
8270D/3541 BNA Soil Automated Soxhlet "Dry Weight Corrected"
l,l'-Biphenyl
u
ND
133
443
ug/kg
1 RMB 02/27/14
1434 1369009 1
1,2,4,5-
u
ND
133
443
ug/kg
1
TETRACHLOROBENZENE
2,4,5-Trichlorophenol
u
ND
133
443
ug/kg
1
2,4,6-Trichlorophenol
u
ND
133
443
ug/kg
1
2,4-Dichlorophenol
u
ND
133
443
ug/kg
1
2,4-Dimethylphenol
u
ND
133
443
ug/kg
1
2,4-Dinitrophenol
u
ND
133
886
ug/kg
1
2,4-Dinitrotoluene
u
ND
133
443
ug/kg
1
2,6-Dinitrotoluene
u
ND
133
443
ug/kg
1
2-Chloronaphthalene
u
ND
13.3
44.3
ug/kg
1
2-Chlorophenol
u
ND
133
443
ug/kg
1
4,6-Dinitro-2-methylphenol
u
ND
133
443
ug/kg
1
2-Methylnaphthalene
u
ND
13.3
44.3
ug/kg
1
2-Nitrophenol
u
ND
133
443
ug/kg
1
3,3'-Dichlorobenzidine
u
ND
133
443
ug/kg
1
4-Bromophenyl-phenylether
u
ND
133
443
ug/kg
1
4-Chloro-3-methylphenol
u
ND
177
443
ug/kg
1
4-Chloroaniline
u
ND
133
443
ug/kg
1
4-Chlorophenyl-phenylether
u
ND
133
443
ug/kg
1
4-Nitrophenol
u
ND
133
443
ug/kg
1
Acenaphthene
u
ND
13.3
44.3
ug/kg
1
Acenaphthylene
u
ND
13.3
44.3
ug/kg
1
Acetophenone
u
ND
133
443
ug/kg
1
Anthracene
u
ND
13.3
44.3
ug/kg
1
Atrazine
u
ND
177
443
ug/kg
1
Benzaldehyde
u
ND
133
443
ug/kg
1
B enz o( a)anthrac ene
J
30.1
13.3
44.3
ug/kg
1
Benzo(a)pyrene
J
19.9
13.3
44.3
ug/kg
1
Benzo(b)fluoranthene
J
34.1
13.3
44.3
ug/kg
1
Benzo(ghi)perylene
u
ND
13.3
44.3
ug/kg
1
Benzo(k)fluoranthene
J
18.6
13.3
44.3
ug/kg
1
Butylbenzylphthalate
u
ND
133
443
ug/kg
1
Caprolactam
u
ND
133
443
ug/kg
1
Carbazole
u
ND
13.3
44.3
ug/kg
1
Chrysene
J
20.8
13.3
44.3
ug/kg
1
Page 41 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Certificate of Analysis
Company : Seagull Environmental Technologies, Inc.
Address : 20 James Town Farm Drive
Report Date: February 28, 2014
Contact:
Project:
Client Sample ID:
Sample ID:
Florissant, Missouri 63034
Mr. Dave Kinroth
Strecker Forest Removal
SFRA-3
343609001
Project:
Client ID:
TETR00055
TETR055
Semi-Volatile-GC/MS
8270D/3541 BNA Soil Automated Soxhlet "Dry Weight Corrected"
Di-n-butylphthalate
u
ND
133
443
ug/kg
l
Di-n-octylphthalate
u
ND
133
443
ug/kg
l
Dibenz(a,h) anthracene
u
ND
13.3
44.3
ug/kg
l
Dibenzofuran
u
ND
133
443
ug/kg
l
Diethylphthalate
u
ND
133
443
ug/kg
l
Dimethylphthalate
u
ND
133
443
ug/kg
l
Diphenylamine
u
ND
133
443
ug/kg
l
Fluoranthene
J
43.0
13.3
44.3
ug/kg
l
Fluorene
u
ND
13.3
44.3
ug/kg
l
Hexachlorobenzene
u
ND
133
443
ug/kg
l
Hexachlorobutadiene
u
ND
133
443
ug/kg
l
Hexachlorocyclopentadiene
u
ND
133
443
ug/kg
l
Hexachloroethane
u
ND
133
443
ug/kg
l
Indeno( 1,2,3-cd)pyrene
u
ND
13.3
44.3
ug/kg
l
Isophorone
u
ND
133
443
ug/kg
l
N-Nitroso-di-n-propylamine
u
ND
133
443
ug/kg
l
Naphthalene
u
ND
13.3
44.3
ug/kg
l
Nitrobenzene
u
ND
133
443
ug/kg
l
Pentachlorophenol
u
ND
133
443
ug/kg
l
Phenanthrene
J
19.5
13.3
44.3
ug/kg
l
Phenol
u
ND
133
443
ug/kg
l
Pyrene
49.2
13.3
44.3
ug/kg
l
bis(2-Chloroethoxy)methane
u
ND
133
443
ug/kg
l
bis(2-Chloroethyl) ether
u
ND
133
443
ug/kg
l
bis(2-Ethylhexyl)phthalate
J
370
133
443
ug/kg
l
CRESOLS, M & P
u
ND
133
443
ug/kg
l
3-Nitroaniline
u
ND
133
443
ug/kg
l
2-Methylphenol
u
ND
133
443
ug/kg
l
2-Nitroaniline
u
ND
146
443
ug/kg
l
4-Nitroaniline
u
ND
133
443
ug/kg
l
The following Prep Methods were performed:
Method
Description
Analyst
Date
Time Prep Batch
SW846 3541
Prep Method 3541 8270D BNA for Soil
SXW3
02/26/14
1715
1369008
Page 42 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Certificate of Analysis
Company : Seagull Environmental Technologies, Inc.
Address : 20 James Town Farm Drive
Report Date: February 28, 2014
Contact:
Project:
Client Sample ID:
Sample ID:
Florissant, Missouri 63034
Mr. Dave Kinroth
Strecker Forest Removal
SFRA-3
343609001
Project:
Client ID:
TETR00055
TETR055
The following Analytical Methods were performed:
Method Description Analyst Comments
1 SW846 3541/8270D
Surrogate/Tracer Recovery Test Result Nominal Recovery% Acceptable Limits
2-Fluorobiphenyl
8270D/3541 BNA Soil Automated Soxhlet
Weight Corrected"
"Dry
1150
ug/kg
1830
62.8
(25%-
¦100%)
Nitrobenzene-d5
8270D/3541 BNA Soil Automated Soxhlet
Weight Corrected"
"Dry
1090
ug/kg
1830
59.3
(21%-
¦103%)
Terphenyl-dl4
8270D/3541 BNA Soil Automated Soxhlet
Weight Corrected"
"Dry
1840
ug/kg
1830
100
(31%-
¦124%)
2,4,6-Tribromophenol
8270D/3541 BNA Soil Automated Soxhlet
Weight Corrected"
"Dry
2940
ug/kg
3660
80.2
(20%-
¦122%)
2-Fluorophenol
8270D/3541 BNA Soil Automated Soxhlet
Weight Corrected"
"Dry
2040
ug/kg
3660
55.7
(23%-
¦107%)
PHENOL-D6
8270D/3541 BNA Soil Automated Soxhlet
"Dry
2110
ug/kg
3660
57.7
(25%-
¦108%)
Weight Corrected"
Notes:
Page 43 of 86
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Quality Control
Summary
Page 44 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Contact:
Workorder:
Seagull Environmental Technologies, Inc.
20 James Town Farm Drive
Florissant, Missouri
Mr. Dave Kinroth
343609
Report Date: February 28, 2014
Page 1 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
QC1203041531 LCS
l,l'-Biphenyl
1,2,4,5-
TETRACHLOROBENZENE
2,4,5 ¦-T richlorophenol
2,4,6-T richlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Nitroaniline
2-Nitrophenol
3,3' -Dichlorobenzidine
3-Nitroaniline
4,6-Dinitro-2-methylphenol
4-Bromophenyl-phenylether
4-Chloro-3-methylphenol
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
955
927
1050
1030
986
903
384
1080
1030
979
920
1000
953
1030
1010
847
977
707
1070
1000
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
57.4 (42%-100%) RMB 02/27/14 12:29
55.7 (34%- 111 %)
62.8 (41%-103%)
62.2 (36%-98%)
59.3 (35%-l 10%)
54.3 (35%o-102%i)
23.1 (22%-83%)
64.6 (43%o-109%o)
61.7 (41%-103%)
58.9 (39%-101%)
55.3 (38%o-100%o)
60.4 (36%o-107%o)
57.3 (37%-97%)
62.1 (34%-116%)
60.5 (35%o-106%o)
50.9 (32%-lll%)
58.7 (32%o-113%o)
42.5 (33%o-103%o)
64.6 (42%-110%)
60.4 (35%o-104%o)
Page 45 of 86
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Workorder: 343609
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 2 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
4-Chloroaniline
4-Chlorophenyl-phenylether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Anthracene
Atrazine
Benzaldehyde
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Butylbenzylphthalate
CRESOLS, M & P
Caprolactam
Carbazole
Chrysene
Di-n-butylphthalate
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
866
1010
1150
796
973
993
930
986
984
396
964
934
979
762
965
1050
1070
950
1230
966
1090
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
52 (32%-106%) RMB 02/27/14 12:29
60.8 (41%-104%)
69.1 (35%o-150%i)
47.8 (23%-l 14%)
58.5 (36%o-105%o)
59.7 (38%o-103%o)
55.9 (37%o-104%o)
59.3 (43%o-104%o)
59.1 (32%o-104%o)
23.8 (10%-130%)
58 (46%-108%)
56.2 (45%o-109%o)
58.9 (42%-lll%)
45.8 (43%o-115%o)
58 (43%-103%)
63 (37%-107%)
64.3 (39%o-115%o)
57.1 (39%-114%)
74.1 (53%o-118%o)
58.1 (47%-107%)
65.8 (46%-112%)
Page 46 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 3 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
Di-n-octylphthalate
Dibenz(a,h) anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Diphenylamine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno( 1,2,3-cd)pyrene
Isophorone
N-Nitroso-di-n-propylamine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
bis(2-Chloroethoxy)methane
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1660
1040
829
1010
1070
1030
1070
994
957
1030
981
379
913
955
1100
1020
969
1060
524
998
933
989
1060
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
62.6 (41%-110%)
49.8 (39%-128%) RMB 02/27/14 12:29
60.5 (38%o-104%i)
64.1 (42%-109%)
62.2 (41%-105%)
64.1 (40%-101%)
59.7 (44%-106%)
57.5 (39%)-102%))
62.2 (41%-108%)
59 (32%-104%)
22.8 * (24%-84%)
54.9 (34%-98%)
57.4 (45%-115%)
66.2 (36%-98%)
61.1 (34%-106%)
58.2 (38%o-106%o)
63.6 (35%-99%)
31.5 (31%-93%)
60 (43%-105%)
56.1 (38%-98%)
59.4 (33%-99%)
63.8 (37%-98%)
Page 47 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 4 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
* *2,4,6-Tribromophenol
* *2-Fluorobipheny 1
**2-Fluorophenol
* *Nitrobenzene-d5
**PHENOL-D6
**Terphenyl-dl4
QC1203041530 MB
l,l'-Biphenyl
1,2,4,5-
TETRACHLOROBENZENE
2,4,5 ¦-T richlorophenol
2,4,6-T richlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Nitroaniline
1660
1660
3330
1660
3330
1660
3330
1660
U
U
U
U
U
U
U
U
U
U
U
U
U
U
959
1040
2030
963
1870
1040
1880
1010
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
57.7 (35%-96%)
62.5 (41%-104%) RMB 02/27/14 12:29
61.1 (20%-122%)
57.9 (25%o-100%i)
56.2 (23%o-107%o)
62.4 (21%-103%)
56.4 (25%o-108%o)
60.7 (31%-124%)
02/27/14 11:57
Page 48 of 86
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Workorder: 343609
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 5 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
2-Nitrophenol
3,3' -Dichlorobenzidine
3-Nitroaniline
4,6-Dinitro-2-methylphenol
4-Bromophenyl-phenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl-phenylether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Anthracene
Atrazine
Benzaldehyde
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
RMB 02/27/14 11:57
Page 49 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 6 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
Butylbenzylphthalate
CRESOLS, M & P
Caprolactam
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenz(a,h) anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Diphenylamine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno( 1,2,3-cd)pyrene
Isophorone
N-Nitroso-di-n-propylamine
Naphthalene
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
RMB 02/27/14 11:57
Page 50 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 7 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
**2,4,6-Tribromophenol 3330
**2-Fluorobiphenyl 1670
**2-Fluorophenol 3330
**Nitrobenzene-d5 1670
**PHENOL-D6 3330
**Terphenyl-dl4 1670
QC1203041532 343609001 MS
l,l'-Biphenyl 1830
1,2,4,5- 1830
TETRACHLOROBENZENE
2.4.5-Trichlorophenol 1830
2.4.6-Trichlorophenol 1830
2,4-Dichlorophenol 1830
2,4-Dimethylphenol 1830
2,4-Dinitrophenol 1830
2,4-Dinitrotoluene 1830
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND J
ND
ND
ND
ND
ND
ND
ND
ND
ND
2030
1160
2100
1220
2130
1250
1120
1010
1430
1330
1240
1110
484
1500
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
RMB 02/27/14 11:57
60.9 (20%-122%)
69.8 (25%o-100%i)
63 (23%-107%)
73.4 (21%-103%)
63.8 (25%o-108%o)
75.3 (31%-124%)
61.2 (27%-lll%)
55.2 (24%o-115%o)
78.3 (38%o-109%o)
72.6 (32%o-103%o)
67.7 (31%-103%)
60.6 (30%o-109%o)
26.4 (19%-101%)
81.6 (36%-115%)
02/27/14 15:05
Page 51 of 86
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Workorder: 343609
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 8 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Nitroaniline
2-Nitrophenol
3,3' -Dichlorobenzidine
3-Nitroaniline
4,6-Dinitro-2-methylphenol
4-Bromophenyl-phenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl-phenylether
4-Nitroaniline
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Anthracene
Atrazine
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1320
1160
1100
1190
1120
1400
1180
783
1150
996
1500
1440
1030
1300
1630
1360
1170
1230
1070
1460
1470
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
71.9 (36%-107%) RMB 02/27/14 15:05
63.5 (27%-109%)
59.8 (28%-108%)
64.9 (23%i-107%i)
61 (27%)-105%))
76.5 (37%-l 14%)
64.2 (24%-106%)
42.7 (28%o-105%o)
62.8 (31%-110%)
54.4 (14%-116%)
81.8 (37%-l 12%)
78.4 (32%-l 12%)
56.5 (27%-100%)
71.1 (37%-l 10%)
89.1 (36%-141%)
74.3 (12%-128%)
64.1 (28%-102%)
67.4 (32%-103%)
58.2 (27%-110%)
79.6 (36%o-104%o)
80.1 (28%-107%)
Page 52 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 9 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
Benzaldehyde
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Butylbenzylphthalate
CRESOLS, M & P
Caprolactam
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenz(a,h) anthracene
Dibenzofuran
Diethylphthalate
Dimethylphthalate
Diphenylamine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
U
J
J
J
U
J
U
U
U
U
J
U
U
U
U
U
U
U
J
U
U
U
ND
30.1
19.9
34.1
ND
18.6
ND
ND
ND
ND
20.8
ND
ND
ND
ND
ND
ND
ND
43.0
ND
ND
ND
1130
1530
1500
1650
1050
1560
1680
1260
1490
1830
1540
1570
1610
1190
1260
1410
1260
1570
1360
1250
1400
872
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
62 (17%-101%)
81.9 (27%-120%) RMB 02/27/14 15:05
80.6 (31%-116%)
88.5 (30%i-119%i)
57.3 (30%o-109%o)
84.3 (31%-125%)
91.8 (33%-121%)
69 (32%-123%)
81.6 (29%-126%)
100 (40%-133%)
82.8 (33%o-114%o)
85.5 (42%-119%)
87.7 (36%-115%)
65.1 (26%-128%)
69 (28%-117%)
77.1 (40%-113%)
68.8 (38%-l 10%)
85.6 (34%-l 11%)
72 (32%-115%)
68.5 (30%o-115%))
76.6 (34%-l 11%)
47.6 (24%-105%)
Page 53 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 10 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
Hexachlorocyclopentadiene 1830 U
Hexachloroethane 1830 U
Indeno(l,2,3-cd)pyrene 1830 U
Isophorone 1830 U
N-Nitroso-di-n-propylamine 1830 U
Naphthalene 1830 U
Nitrobenzene 1830 U
Pentachlorophenol 1830 U
Phenanthrene 1830 J
Phenol 1830 U
Pyrene 1830
bis(2-Chloroethoxy)methane 1830 U
bis(2-Chloroethyl) ether 1830 U
bis(2-Ethylhexyl)phthalate 1830 J
**2,4,6-Tribromophenol 3660
**2-Fluorobiphenyl 1830
**2-Fluorophenol 3660
**Nitrobenzene-d5 1830
"PHENOL-D6 3660
**Terphenyl-dl4 1830
QC1203041533 343609001 MSD
l,l'-Biphenyl 1830 U
1,2,4,5- 1830 U
TETRACHLOROBENZENE
ND U
ND
ND
ND
ND U
ND
ND
ND
19.5
ND
49.2
ND
ND
370
2940
1150
2040
1090
2110
1840
ND
ND
ND
505
1380
1280
ND
1090
1230
1210
1470
1230
1640
1240
1010
1950
3030
1110
2170
1130
2200
1640
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
0* (12%-106%)
27.5 (24%-102%) RMB 02/27/14 15:05
75.3 (29%-117%)
69.7 (24%-108%)
0* (23%-l 17%)
59.6 (21%-107%)
67.1 (25%-104%)
66.1 (22%-108%)
79.1 (28%-119%)
67.2 (28%-108%)
86.8 (25%i-119%i)
67.8 (27%-104%)
55.4 (25%)-102%))
86 (33%-124%)
82.7 (20%-122%)
60.8 (25%)-100%))
59.2 (23%)-107%))
61.7 (21%-103%)
59.9 (25%)-108%))
89.7 (31 %-124%)
1160 ug/kg 3.15 63.2 (0%-30%)
1030 ug/kg 1.74 56.2 (0%-30%)
02/27/14 15:37
Page 54 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Page 11 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
2,4,5 -T richlorophenol
2,4,6-T richlorophenol
2,4-Dichlorophenol
2,4-Dimethylphenol
2,4-Dinitrophenol
2,4-Dinitrotoluene
2,6-Dinitrotoluene
2-Chloronaphthalene
2-Chlorophenol
2-Methylnaphthalene
2-Methylphenol
2-Nitroaniline
2-Nitrophenol
3,3' -Dichlorobenzidine
3-Nitroaniline
4,6-Dinitro-2-methylphenol
4-Bromophenyl-phenylether
4-Chloro-3-methylphenol
4-Chloroaniline
4-Chlorophenyl-phenylether
4-Nitroaniline
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
U
ND
ND
ND
ND
ND J
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
ND
1400
1330
1180
1130
229
1470
1280
1160
1140
1240
1160
1390
1080
1150
1370
543
1500
1360
1110
1320
1740
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
2.64
0.0815
4.51
1.85
71.6*
1.59
2.99
0.0427
4.01
4.62
4.09
0.657
8.61
38.3*
17.1
58.9*
0.375
5.15
6.98
1.54
6.22
76.3 (0%-30%) RMB 02/27/14 15:37
72.5 (0%-30%)
64.7 (0%-30%)
61.8 (0%-30%)
12.5 * (0%-30%)
80.4 (0%-30%)
69.8 (0%-30%)
63.5 (0%-30%)
62.3 (0%-30%)
68 (0%-30%)
63.6 (0%-30%)
76 (0%-30%)
58.9 (0%-30%)
63.1 (0%-30%)
74.6 (0%-30%)
29.6 (0%-30%)
82.2 (0%-30%)
74.5 (0%-30%)
60.6 (0%-30%)
72.3 (0%-30%)
94.8 (0%-30%)
Page 55 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 12 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
4-Nitrophenol
Acenaphthene
Acenaphthylene
Acetophenone
Anthracene
Atrazine
Benzaldehyde
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(ghi)perylene
Benzo(k)fluoranthene
Butylbenzylphthalate
CRESOLS, M & P
Caprolactam
Carbazole
Chrysene
Di-n-butylphthalate
Di-n-octylphthalate
Dibenz(a,h) anthracene
Dibenzofuran
Diethylphthalate
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
U
U
U
U
U
U
U
J
J
J
U
J
U
U
U
U
J
U
U
U
U
U
ND
ND
ND
ND
ND
ND
ND
30.1
19.9
34.1
ND
18.6
ND
ND
ND
ND
20.8
ND
ND
ND
ND
ND
1170 ug/kg 15.3 63.7 (0%-30%)
1190 ug/kg 1.20 64.8 (0%-30%) RMB 02/27/14 15:37
1230 ug/kg 0.508 67.1 (0%-30%)
1120 ug/kg 5.08 61.3 (0%-30%)
1520 ug/kg 3.89 82.8 (0%-30%)
1550 ug/kg 5.53 84.7 (0%-30%)
1220 ug/kg 6.91 66.4 (0%-30%)
1580 ug/kg 3.50 84.9 (0%-30%)
1550 ug/kg 3.58 83.6 (0%-30%)
1720 ug/kg 3.69 91.9 (0%-30%)
1090 ug/kg 3.45 59.3 (0%-30%)
1580 ug/kg 1.34 85.5 (0%-30%)
1790 ug/kg 6.39 97.9 (0%-30%)
1340 ug/kg 5.68 73.1 (0%-30%)
1490 ug/kg 0.431 81.3 (0%-30%)
1850 ug/kg 0.665 101 (0%-30%)
1600 ug/kg 3.65 86 (0%-30%)
1640 ug/kg 4.41 89.4 (0%-30%)
1630 ug/kg 1.47 89 (0%-30%)
1300 ug/kg 8.87 71.1 (0%-30%)
1280 ug/kg 1.47 70 (0%-30%)
1460 ug/kg 3.40 79.7 (0%-30%)
Page 56 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 13 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
Dimethylphthalate
Diphenylamine
Fluoranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno( 1,2,3-cd)pyrene
Isophorone
N-Nitroso-di-n-propylamine
Naphthalene
Nitrobenzene
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
bis(2-Ethylhexyl)phthalate
*2,4,6-Tribromophenol
*2-Fluorobiphenyl
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
1830
3660
1830
U
U
J
U
U
U
U
U
U
U
U
U
U
U
J
U
U
U
J
ND
ND
43.0
ND
ND
ND
ND U
ND
ND
ND
ND
ND
ND
ND
19.5
ND
49.2
ND
ND
370
2940
1150
1280 ug/kg 1.76 70.1 (0%-30%)
1580 ug/kg 0.806 86.4 (0%-30%) RMB 02/27/14 15:37
1420 ug/kg 4.22 75.2 (0%-30%)
1270 ug/kg 1.04 69.2 (0%-30%)
1470 ug/kg 4.93 80.5 (0%-30%)
919 ug/kg 5.24 50.2 (0%-30%)
ND ug/kg N/A 0* (0%-30%)
591 ug/kg 15.7 32.3 (0%-30%)
1500 ug/kg 8.68 82.2 (0%-30%)
1290 ug/kg 0.793 70.3 (0%-30%)
1250 ug/kg 200* 68.2 (0%-30%)
1110 ug/kg 2.07 60.8 (0%-30%)
1240 ug/kg 0.823 67.7 (0%-30%)
849 ug/kg 35.1* 46.4 (0%-30%)
1570 ug/kg 6.84 84.8 (0%-30%)
1270 ug/kg 2.95 69.3 (0%-30%)
2020 ug/kg 20.6 107 (0%-30%)
1230 ug/kg 0.597 67.4 (0%-30%)
1110 ug/kg 8.73 60.5 (0%-30%)
2040 ug/kg 4.89 91.3 (0%-30%)
2940 ug/kg 80.3 (20%-122%)
1120 ug/kg 61.3 (25%o-100%i)
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 14 of 15
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatile-GC/MS
Batch 1369009
**2-Fluorophenol
* *Nitrobenzene-d5
"PHENOL-D6
**Terphenyl-dl4
3660
1830
3660
1830
2040
1090
2110
1840
2210
1170
2270
1910
ug/kg
ug/kg
ug/kg
ug/kg
60.3 (23%-107%)
63.7 (21%-103%) RMB 02/27/14 15:37
62 (25%-108%)
104 (31%-124%)
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a surrogate compound
< Result is less than value reported
> Result is greater than value reported
A The TIC is a suspected aldol-condensation product
B The target analyte was detected in the associated blank.
C Analyte has been confirmed by GC/MS analysis
D Results are reported from a diluted aliquot of the sample
E Concentration of the target analyte exceeds the instrument calibration range
H Analytical holding time was exceeded
J Value is estimated
JNX Non Calibrated Compound
N Organics—Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based
on nearest internal standard response factor
N Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based on nearest
internal standard response factor
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
P Organics—The concentrations between the primary and confirmation columns/detectors is >40% different. For HPLC, the difference is >70%.
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UJ Compound cannot be extracted
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y QC Samples were not spiked with this compound
A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
Page 58 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Workorder: 343609 Page 15 of 15
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 59 of 86
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Miscellaneous
Page 60 of 86
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GEL Laboratories LLC
Form GEL-DER
DER Report No.: 1271086
Revision No.: 3
Mo.Day Yr.
28-FEB-14
Instrument Type:
SEMIVOA GC/MS
Batch ID:
1369009
Division:
Industrial
DATA EXCEPTION REPORT
Quality Criteria:
Specifications
Test / Method:
SW846 3541/8270D
Sample Numbers:
See Below
Matrix Type:
Solid
Type:
Process
Client Code:
TETR
Potentially affected work order(s)(SDG): 343609
Application Issues:
Failed Recovery for MS/PS
Failed RPD for MS/MSD, or PS/PSD
Failed Recovery for LCS/LCSD
Failed Recovery for MSD/PSD
Specification and Requirements
Exception Description:
DER Disposition:
1. The LCS(1203041531) recovered Hexachlorocyclopentadiene at
22.8%. The limits are 24%-84%.
2. The MS(1203041532) recovered Hexachlorocyclopentadiene at 0%
(limits are 12%-106%) and N-Nitrosodipropylamine at 0% (limits are
23%-117%).
3. The MSD(1203041533) recovered Hexachlorocyclopentadiene at 0%
(limits are 12%-106%) and 2,4-Dinitrophenol at 12.5% (limits are 19%-
101%).
4. The MS(1203041532)/MSD(1203041533) RPD values for 2,4-
Dinitrophenol, 2-Methyl-4,6-dinitrophenol, 3,3'-Dichlorobenzidine, N-
Nitrosodipropylamine and Pentachlorophenol were outside of the
acceptance criteria. Please see the QC Summary report for specific
failures.
1. Hexachlorocyclopentadiene is known to be a poor responding analyte
that is subject to thermal decomposition as stated in the Method. This may
account for the low recovery of the analyte in the LCS, as well as the zero
percent recoveries in the MS and MSD. The data results have been
reported.
2., 3. Hexachlorocyclopentadiene is known to be a poor responding
analyte that is subject to thermal decomposition as stated in the Method.
This may account for the zero percent recoveries in the MS and MSD, as
well as the low recovery of the analyte in the LCS. Since both the MS and
MSD displayed failures and the sample data chromatograms displayed
excessive matrix interference, the failures were attributed to sample matrix
interference and the data results have been reported.
4. The failures were attributed to matrix interference and the data results
have been reported.
Originator's Name:
Richard Bomar
28-FEB-14
Data Validator/Group Leader:
Barbara Bailey 06-MAR-14
Page 61 of 86
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PCB Analysis
Page 62 of 86
-------
Case Narrative
Page 63 of 86
-------
PCB Case Narrative
Tetra Tech, Inc. (TETR)
SDG 343609
Method/Analvsis Information
Procedure: Analysis of Polychlorinated Biphenyls by ECD
Analytical Method: SW846 3 541/8082A
Prep Method: SW846 3541
Analytical Batch Number: 1369224
Prep Batch Number: 1369223
Sample Analysis
The following samples were analyzed using the analytical protocol as established in SW846 3 541/8082A:
Sample ID Client ID
343609001 SFRA-3
1203042000 Method Blank (MB)
1203042001 Laboratory Control Sample (LCS)
1203042002 343614001(EWLCP2TV2) Matrix Spike (MS)
1203042003 343614001(EWLCP2TV2) Matrix Spike Duplicate (MSD)
The samples in this SDG were analyzed on a "dry weight" basis.
Preparation/Analytical Method Verification
SOP Reference
Procedure for preparation, analysis and reporting of analytical data are controlled by GEL Laboratories LLC as
Standard Operating Procedure (SOP). The data discussed in this narrative has been analyzed in accordance with
GL-OA-E-040 REV# 20.
Raw data reports are processed and reviewed by the analyst using the Chemstation software package. False
positives have been removed from the quantitation reports per standard operating procedures (SOP).
Calibration Information
A complete list of the initial calibration data files are shown in the Calibration History report located in the
Standard Data section of the data package.
Initial Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
Continuing Calibration Verification (CCV) Requirements
All associated calibration verification standards (ICV or CCV) met the acceptance criteria. All analytes were
within the established retention time windows for this method.
Page 64 of 86
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Quality Control (OO Information
Method Blank (MB) Statement
The MB analyzed with this SDG met the acceptance criteria.
Surrogate Recoveries
All surrogate recoveries were within the established acceptance criteria for the samples in this SDG in this batch.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
QC Sample Designation
A non TETR sample of similar matrix was selected for the matrix spike and matrix spike duplicate analysis for
this batch of the samples.
Matrix Spike (MS) Recovery Statement
The MS recoveries were not within the established acceptance limits due to dilution and multiple Aroclors in the
parent sample, which interfered with spiked Aroclors.
Matrix Spike Duplicate (MSD) Recovery Statement
The MSD recoveries were not within the established acceptance limits due to dilution and multiple Aroclors in
the parent sample, which interfered with spiked Aroclors.
MS/MSD Relative Percent Difference (RPD) Statement
The RPD between the MS and MSD did not meet the acceptance limits due to dilution and multiple Aroclors
detected in the parent sample.
Technical Information
Holding Time Specifications
GEL assigns holding times based on the associated methodology, which assigns the date and time from sample
collection of sample receipt. Those holding times expressed in hours are calculated in the AlphaLIMS system.
Those holding times expressed as days expire at midnight on the day of expiration. All samples in this SDG met
the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP. All reported analyte detections in client and quality control
samples were within the established retention time windows. Reported analyte concentrations were confirmed on
dissimilar columns. All sample extracts were cleaned using alumina. Additionally, copper was added to all
sample extracts to remove sulfur.
Sample Dilutions
The samples in this SDG did not require dilutions.
Sample Re-extraction/Re-analysis
Re-extractions or re-analyses were not required in this SDG in this batch.
Miscellaneous Information
Electronic Package Comment
The following package was generated using an electronic data processing program referred to as "virtual
packaging". In an effort to increase quality and efficiency, the laboratory is developing systems to eventually
generate all data packages electronically. The following change from "traditional" packages should be noted:
Page 65 of 86
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Analyst/peer reviewer initials and dates are not present on the electronic data files. Presently, all initials and
dates are present on the original raw data. These hard copies are temporarily stored in the laboratory. The data
validator will always sign and date the case narrative. Data that are not generated electronically, such as hand
written pages, will be scanned and inserted into the electronic package.
Data Exception (DER) Documentation
Data exception report (DER) is generated to document procedural anomalies that may deviate from referenced
SOP or contractual documents. A DER was not required for the samples in this SDG in this batch.
Manual Integrations
Certain standards and samples may have required manual integration to correctly position the baseline as set in
the calibration standard injections.
Additional Comments
The additional comments field is used to address special issues associated with each analysis, clarify
method/contractual issues pertaining to the analysis, and to list any report documents generated as a result of
sample analysis or review. The following additional comments were required:
The front column has been chosen as the primary column. The data are reported from the front column for all
samples in this batch.
System Configuration
The Semi-Volatiles-PCB analysis was performed on the following instrument configuration:
Instrument
ID
ECD9A.I 1
ECD9A.I 2
Instrument
Agilent 7890A Gas
Chromatograph/Dual ECD w/
7693 Autosampler
Agilent 7890A Gas
Chromatograph/Dual ECD w/
7693 Autosampler
System
Configuration
7890A GC/ECD
7890A GC/ECD
Column ID
Restek
Rtx-CLPest 1
Restek
Rtx-CLPest 2
Column
Description
30m x
0.25mm,
0.25um
30m x
0.25mm,
0.20um
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless otherwise noted in the analytical case narrative.
Page 66 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Qualifier Definition Report
for
TETR055 Tetra Tech, Inc. (Contract#)
Client SDG: 343609 GEL Work Order: 343609
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
** Analyte is a surrogate compound
P Organics~The concentrations between the primary and confirmation columns/detectors is >40% different. For
HPLC, the difference is >70%.
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
DL Indicates that sample is diluted.
RA Indicates that sample is re-analyzed without re-extraction.
RE Indicates that sample is re-extracted.
Review /V alidation
GEL requires all analytical data to be verified by a qualified data reviewer. In addition, all CLP-like deliverables
receive a third level review of the fractional data package.
The following data validator verified the information presented in this data report:
Name: Jimin Cao
Date: 04 MAR 2014
Title: Data Validator
Page 67 of 86
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Sample Data Summary
Page 68 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Certificate of Analysis
Company : Seagull Environmental Technologies, Inc.
Address : 20 James Town Farm Drive
Report Date: March 3,2014
Contact:
Project:
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
Moisture:
Florissant, Missouri 63034
Mr. Dave Kinroth
Strecker Forest Removal
SFRA-3
343609001
Soil
13-FEB-14 10:02
18-FEB-14
Client
9.06%
Project:
Client ID:
TETR00055
TETR055
Parameter
Qualifier Result
DL
RL
Units
DF Analyst Date Time Batch Method
Semi-Volatiles-PCB
SW846 3541/8082A PCB Solid Automated Soxhlet "Dry Weight Corrected"
Aroclor-1016
U ND
1.21
3.63
ug/kg
1 YSl 02/28/14 0742 1369224 1
Aroclor-1221
U ND
1.21
3.63
ug/kg
1
Aroclor-1232
U ND
1.21
3.63
ug/kg
1
Aroclor-1242
6.07
1.21
3.63
ug/kg
1
Aroclor-1248
U ND
1.21
3.63
ug/kg
1
Aroclor-1254
P 5.81
1.21
3.63
ug/kg
1
Aroclor-1260
U ND
1.21
3.63
ug/kg
1
Aroclor-1262
U ND
1.21
3.63
ug/kg
1
Aroclor-1268
U ND
1.21
3.63
ug/kg
1
The following Prep Methods were performed:
Method
Description
Analyst
Date
Time Prep Batch
SW846 3541
Prep Method 3541 PCB Prep Soil
CXR2
02/27/14
1030 1369223
The following Analytical Methods were performed:
Method
Description
Analyst Comments
l
SW846 3541/8082A
Surrogate/Tracer Recovery Test
Result
Nominal Recovery% Acceptable Limits
4cmx
SW846 3541/8082A PCB Solid Automated
"Dry Weight Corrected"
Soxhlet
5.33 ug/kg
7.26 73.4 (44%-106%)
DECACHLOROBIPHENYL
SW846 3541/8082A PCB Solid Automated Soxhlet
"Dry Weight Corrected"
5.95 ug/kg
7.26
82.0
(35%-119%)
Notes:
Page 69 of 86
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Quality Control
Summary
Page 70 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Contact:
Workorder:
Seagull Environmental Technologies, Inc.
20 James Town Farm Drive
Florissant, Missouri
Mr. Dave Kinroth
343609
Report Date: March 3, 2014
Page 1 of 3
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatiles-PCB
Batch 1369224
QC1203042001 LCS
Aroclor-1016
Aroclor-1260
**4cmx
* *DECACHLOROBIPHENYL
QC1203042000 MB
Aroclor-1016
Aroclor-1221
Aroclor-1232
Aroclor-1242
Aroclor-1248
Aroclor-1254
Aroclor-1260
Aroclor-1262
Aroclor-1268
**4cmx
* *DECACHLOROBIPHENYL
QC1203042002 343614001 MS
Aroclor-1016
Aroclor-1260
**4cmx
* *DECACHLOROBIPHENYL
33.2
33.2
6.63
6.63
6.64
6.64
43.0
43.0
8.59
8.59
U
U
U
U
U
U
U
U
U
U
ND
110
5.19
7.06
27.1
29.7
5.89
6.19
ND
ND
ND
ND
ND
ND
ND
ND
ND
5.18
5.74
722
262
7.71
7.19
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
81.7 (39%-120%) YS1 02/28/14 07:30
89.6 (50%-l 16%)
88.8 (44%-106%)
93.3 (35%o-119%i)
02/28/14 07:19
78.1 (44%-106%)
86.5 (35%o-119%o)
1680* (25%-125%)
353* (28%-127%)
89.7 (44%-106%)
83.7 (35%-119%)
02/28/14 08:10
Page 71 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
Workorder: 343609
QC Summary
Page 2 of 3
Parmname
NOM
Sample Qual
QC Units RPD% REC% Range Anlst Date Time
Semi-V olatiles-PCB
Batch 1369224
QC1203042003 343614001 MSD
Aroclor-1016 42.9 U ND
Aroclor-1260 42.9 110
**4cmx 8.57 5.19
* *DECACHLOROBIPHENYL 8.57 7.06
190 ug/kg 117* 442
126 ug/kg 70.1* 36.4
6.11
7.55
ug/kg
ug/kg
(0%-30%) YS1 02/28/14 08:25
(0%-30%)
71.2 (44%-106%)
88 (35%-119%)
Notes:
The Qualifiers in this report are defined as follows:
** Analyte is a surrogate compound
< Result is less than value reported
> Result is greater than value reported
A The TIC is a suspected aldol-condensation product
B The target analyte was detected in the associated blank.
C Analyte has been confirmed by GC/MS analysis
D Results are reported from a diluted aliquot of the sample
E Concentration of the target analyte exceeds the instrument calibration range
H Analytical holding time was exceeded
J Value is estimated
JNX Non Calibrated Compound
N Organics—Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based
on nearest internal standard response factor
N Presumptive evidence based on mass spectral library search to make a tentative identification of the analyte (TIC). Quantitation is based on nearest
internal standard response factor
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
P Organics—The concentrations between the primary and confirmation columns/detectors is >40% different. For HPLC, the difference is >70%.
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
UJ Compound cannot be extracted
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y QC Samples were not spiked with this compound
Page 72 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 -www.gel.com
QC Summary
Workorder: 343609 Page 3 of 3
Parmname NOM Sample Qual QC Units RPD% REC% Range Anlst Date Time
A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 73 of 86
-------
Metals Analysis
Page 74 of 86
-------
Case Narrative
Page 75 of 86
-------
Metals Fractional Narrative
Tetra Tech, Inc. (TETR)
SDG 343609
Sample Analysis
Sample ID Client ID
343609001 SFRA-3
1203041859 Method Blank (MB) ICP
1203041860 Laboratory Control Sample (LCS)
1203041863 343609001(SFRA-3L) Serial Dilution (SD)
1203041861 343609001 (SFRA-3D) Sample Duplicate (DUP)
1203041862 343609001(SFRA-3S) Matrix Spike (MS)
1203041463 Method Blank (MB) CVAA
1203041464 Laboratory Control Sample (LCS)
1203041467 342966001(WST36-14-54961L) Serial Dilution (SD)
1203041465 342966001(WST36-14-54961D) Sample Duplicate (DUP)
1203041466 342966001(WST36-14-54961S) Matrix Spike (MS)
The samples in this SDG were analyzed on a "dry weight" basis.
Method/Analysis Information
Analytical Batch:
Prep Batch :
Standard Operating
Procedures:
Analytical Method:
Prep Method :
1369156 and 1368984
1369155 and 1368982
GL-MA-E-013 REV# 22, GL-MA-E-009 REV# 22 and GL-MA-
E-010 REV# 27
SW846 3050B/6010C and SW846 7471A
SW846 3050B and SW846 7471A Prep
Preparation/Analytical Method Verification
The SOP stated above has been prepared based on technical research and testing conducted by
GEL Laboratories, LLC and with guidance from the regulatory documents listed in this
"Method/Analysis Information" section.
Page 76 of 86
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System Configuration
The Metals analysis-ICP was performed on a PE 7300 Optima radial/axial-viewing inductively
coupled plasma atomic emission spectrometer. The instrument is equipped with a Burgener
nebulizer, cyclonic spray chamber, and yttrium or scandium internal standard. Operating
conditions for the ICP are set at a power level of 1500 watts. The instrument has a peristaltic
pump flow rate of 1.4L/min, argon gas flows of 15 L/min and 0.2 L/min for the torch and
auxiliary gases, and a flow setting of 0.65L/min for the nebulizer.
The Metals analysis-Mercury was performed on a Perkin-Elmer Flow Injection Mercury System
(FIMS-100) automated mercury analyzer. The instrument consists of a cold vapor atomic
absorption spectrometer set to detect mercury at a wavelength of 253.7 nm. Sample introduction
through the flow injection system is performed via a peristaltic pump at 9 mL/min and nitrogen
carrier gas rate of 80 mL/min.
Calibration Information
Instrument Calibration
All initial calibration requirements have been met for this sample delivery group (SDG).
CRDL Requirements
The CRDL standard recoveries met the referenced advisory control limits.
ICSA/ICSAB Statement
All interference check samples (ICSA and ICSAB) associated with this SDG met the established
acceptance criteria.
Continuing Calibration Blank (CCB) Requirements
All continuing calibration blanks (CCB) bracketing this batch met the established acceptance
criteria.
Continuing Calibration Verification (CCV) Requirements
All continuing calibration verifications (CCV) bracketing this SDG met the acceptance criteria.
Quality Control (OC) Information
Method Blank (MB) Statement
The MBs analyzed with this SDG met the acceptance criteria.
Laboratory Control Sample (LCS) Recovery
The LCS spike recoveries met the acceptance limits.
Quality Control (QC) Sample Statement
The following samples were selected as the quality control (QC) samples for this SDG:
343609001 (SFRA-3)-ICP and 342966001 (WST36-14-54961)-CVAA.
Page 77 of 86
-------
Matrix Spike (MS) Recovery Statement
The percent recoveries (%R) obtained from the MS analyses are evaluated when the sample
concentration is less than four times (4X) the spike concentration added. All applicable elements
met the acceptance criteria.
Duplicate Relative Percent Difference (RPD) Statement
The RPD obtained from the designated sample duplicate (DUP) is evaluated based on acceptance
criteria of 20% when the sample is >5X the contract required reporting limit (RL). In cases
where either the sample or duplicate value is less than 5X the RL, a control of +/-RL is used to
evaluate the DUP results. All applicable analytes met these requirements.
Serial Dilution % Difference Statement
The serial dilution is used to assess matrix suppression or enhancement. Raw element
concentrations that are 25X the IDL/MDL for CVAA, 50X the IDL/MDL for ICP, and 100X the
IDL/MDL for ICP-MS analyses are applicable for serial dilution assessment. All applicable
analytes met the established acceptance criteria.
Technical Information
Holding Time Specifications
GEL assigns holding times based on the associated methodology, which assigns the date and
time from sample collection of sample receipt. Those holding times expressed in hours are
calculated in the AlphaLIMS system. Those holding times expressed as days expire at midnight
on the day of expiration. All samples in this SDG met the specified holding time.
Preparation/Analytical Method Verification
All procedures were performed as stated in the SOP. Method SW-846 3050B is not a total
digestion technique for most samples. It is a very strong acid digestion that will dissolve almost
all elements that could become environmentally available. By design, elements bound in silicate
structures are not normally dissolved by this procedure as they are not usually mobile in the
environment.
Sample Dilutions
Dilutions are performed to minimize matrix interferences resulting from elevated mineral
element concentrations present in solid samples and/or to bring over range target analyte
concentrations into the linear calibration range of the instrument. . Dilutions were required for
this SDG in order to minimize silver suppression due to matrix interferences.
Preparation Information
The samples in this SDG were prepared exactly according to the cited SOP.
Miscellaneous Information
Electronic Packaging Comment
This data package was generated using an electronic data processing program referred to as
virtual packaging. In an effort to increase quality and efficiency, the laboratory has developed
Page 78 of 86
-------
systems to generate all data packages electronically. The following change from traditional
packages should be noted:
Analyst/peer reviewer initials and dates are not present on the electronic data files. Presently, all
initials and dates are present on the original raw data. These hard copies are temporarily stored in
the laboratory. An electronic signature page inserted after the case narrative will include the data
validator's signature and title. The signature page also includes the data qualifiers used in the
fractional package. Data that are not generated electronically, such as hand written pages, will be
scanned and inserted into the electronic package.
Data Exception (DER) Documentation
Data exception reports (DERs) are generated to document procedural anomalies that may deviate
from referenced SOP or contractual documents. A data exception report was not required for this
Additional Comments
Additional comments were not required for this SDG.
Certification Statement
Where the analytical method has been performed under NELAP certification, the analysis has
met all of the requirements of the NELAC standard unless otherwise noted in the analytical case
narrative.
Review Validation:
GEL requires all analytical data to be verified by a qualified data validator. In addition, all data
designated for CLP or CLP-like packaging will receive a third level validation upon completion
of the data package.
The following data validator verified the information presented in this case narrative:
SDG.
Reviewer:
Page 79 of 86
-------
Sample Data Summary
Page 80 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 -www.gel.com
Qualifier Definition Report
for
TETR055 Tetra Tech, Inc. (Contract#)
Client SDG: 343609 GEL Work Order: 343609
The Qualifiers in this report are defined as follows:
* A quality control analyte recovery is outside of specified acceptance criteria
B Either presence of analyte detected in the associated blank, or MDL/IDL < sample value < PQL
J Value is estimated
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the Certificate of Analysis.
The designation ND, if present, appears in the result column when the analyte concentration is not detected above
the limit as defined in the 'U' qualifier above.
This data report has been prepared and reviewed in accordance with GEL Laboratories LLC
standard operating procedures. Please direct any questions to your Project Manager, Valerie Davis.
Reviewed by
Page 81 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston SC 29407 - (843) 556-8171 - www.gel.com
Certificate of Analysis
Report Date: March 6, 2014
Company : Seagull Environmental Technologies, Inc.
Address : 20 James Town Farm Drive
Contact:
Project:
Client Sample ID:
Sample ID:
Matrix:
Collect Date:
Receive Date:
Collector:
Moisture:
Florissant, Missouri 63034
Mr. Dave Kinroth
Strecker Forest Removal
SFRA-3
343609001
Soil
13-FEB-14 10:02
18-FEB-14
Client
9.06%
Project:
Client ID:
TETR00055
TETR055
Parameter Qualifier Result
DL
RL
Units
DF Analyst Date Time Batch
Method
Mercury Analysis-CVAA
7471 Cold Vapor Hg in Solid "Dry Weight Corrected"
Mercury 28.7
3.89
11.6
ug/kg
1 NOR1 02/27/14 1436 1368984
l
Metals Analysis-ICP
SW846 3050B/6010C Solid "Dry Weight Corrected"
Arsenic 4330
549
3290
ug/kg
1 JWJ 03/05/14 2155 1369156
2
Barium 68300
110
549
ug/kg
1
Cadmium J 267
110
549
ug/kg
1
Chromium 9830
165
549
ug/kg
1
Lead 13000
362
1100
ug/kg
1
Selenium J 1240
549
3290
ug/kg
1
Silver U ND
549
2740
ug/kg
5 JWJ 03/06/14 1155 1369156
3
The following Prep Methods were performed:
Method Description
Analyst
Date
Time Prep Batch
SW846 3050B SW846 3050B Prep for 6010C
MTM1
02/28/14
0930 1369155
SW846 7471A Prep EPA 7471A Mercury Prep Soil
AXS5
02/26/14
1430 1368982
The following Analytical Methods were performed:
Method
Description
Analyst Comments
SW846 7471A
SW846 3050B/6010C
SW846 3050B/6010C
Notes:
Page 82 of 86
-------
Quality Control
Summary
Page 83 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
QC Summary
Contact:
Workorder:
Seagull Environmental Technologies, Inc.
20 James Town Farm Drive
Florissant, Missouri
Mr. Dave Kinroth
343609
Report Date: March 6, 2014
Page 1 of 3
Parmname
NOM
Sample Qual
QC Units RPD/D% REC% Range Anlst Date Time
Metals Analysis-ICP
Batch 1369156
QC1203041861 343609001 DUP
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
QC1203041860 LCS
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
QC1203041859 MB
Arsenic
Barium
Cadmium
Chromium
Lead
48700
48700
48700
48700
48700
48700
48700
J
U
4330
68300
267 J
9830
13000
1240 J
ND U
U
u
u
u
u
4060
77400
261
10400
12800
1780
ND
48000
48800
49300
47800
48500
50600
48700
ND
ND
ND
ND
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
6.37
12.5
2.14
5.57
1.03
35.6
N/A
(+/-3290) JWJ 03/05/14 21:58
(0%-20%)
(+/-549)
(0%-20%)
(0%-20%)
(+/-3290)
03/06/14 11:59
98.4 (80%-120%)
100 (80%-120%)
101 (80%-120%)
98 (80%-120%)
99.6 (80%-120%)
104 (80%-120%)
99.8 (80%-120%)
03/05/14 21:52
03/05/14 21:48
Page 84 of 86
-------
GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
Workorder: 343609
QC Summary
Page 2 of 3
Parmname
NOM
Sample Qual
QC Units RPD/D% REC% Range Anlst Date Time
Metals Analysis-ICP
Batch 1369156
Selenium
Silver
QC1203041862 343609001 MS
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
QC1203041863 343609001 SDILT
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Silver
Metals Analysis-Mercury
Batch 1368984
QC1203041465 342966001 DUP
Mercury
QC1203041464 LCS
Mercury
54200
54200
54200 J
54200
54200
54200 J
54200 U
7690
J
U
J
J
4330
68300
267
9830
13000
1240
ND
39.5 J
622
2.43 U
89.6
118
11.3 J
ND U
17.9
550 ug/kg
115 ug/kg
55900
125000
50300
62000
63200
52900
54200
10.6
119
ND
16.2
23.7
7.91
ND
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/kg
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
34.2
4.09
N/A
9.41
.546
250
N/A
95 (75%-125%)
104 (75%-125%)
92.2 (75%-125%)
96.2 (75%-125%)
92.7 (75%-125%)
95.3 (75%-125%)
99.9 (75%-125%)
(0%-10%)
(0%-10%)
(0%-10%)
(0%-10%)
(0%-10%)
(0%-10%)
(0%-10%)
JWJ 03/05/14 21:48
03/05/14 22:01
03/06/14 12:03
03/05/14 22:03
03/06/14 12:05
13.6 ug/kg 27.2
6650 ug/kg
(+/-13.6) NOR1 02/27/14 14:29
86.4 (80%-120%)
QC1203041463
Mercury
MB
U
ND ug/kg
02/27/14 14:26
02/27/14 14:24
QC1203041466 342966001 MS
Page 85 of 86
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GEL LABORATORIES LLC
2040 Savage Road Charleston, SC 29407 - (843) 556-8171 - www.gel.com
QC Summary
Workorder: 343609
Page 3 of 3
Parmname
NOM
Sample Qual QC Units RPD/D% REC% Range Anlst Date Time
Metals Analysis-Mercury
Batch
1368984
Mercury
134
17.9
152 ug/kg
101 (80%-120%)
02/27/14 14:31
QC1203041467 342966001 SDILT
Mercury
0.264 U
ND ug/L N/A
(0%-10%) NOR1 02/27/14 14:32
Notes:
The Qualifiers in this report are defined as follows:
< Result is less than value reported
> Result is greater than value reported
E %difference of sample and SD is >10%. Sample concentration must meet flagging criteria
FB Mercury was found present at quantifiable concentrations in field blanks received with these samples. Data associated with the blank are deemed
invalid for reporting to regulatory agencies
H Analytical holding time was exceeded
J Value is estimated
N Metals—The Matrix spike sample recovery is not within specified control limits
N/A RPD or %Recovery limits do not apply.
N1 See case narrative
ND Analyte concentration is not detected above the detection limit
NJ Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Q One or more quality control criteria have not been met. Refer to the applicable narrative or DER.
R Sample results are rejected
U Analyte was analyzed for, but not detected above the MDL, MDA, or LOD.
X Consult Case Narrative, Data Summary package, or Project Manager concerning this qualifier
Y Other specific qualifiers were required to properly define the results. Consult case narrative.
A RPD of sample and duplicate evaluated using +/-RL. Concentrations are <5X the RL. Qualifier Not Applicable for Radiochemistry.
h Preparation or preservation holding time was exceeded
N/A indicates that spike recovery limits do not apply when sample concentration exceeds spike conc. by a factor of 4 or more.
A The Relative Percent Difference (RPD) obtained from the sample duplicate (DUP) is evaluated against the acceptance criteria when the sample is greater than
five times (5X) the contract required detection limit (RL). In cases where either the sample or duplicate value is less than 5X the RL, a control limit of +/- the
RL is used to evaluate the DUP result.
* Indicates that a Quality Control parameter was not within specifications.
For PS, PSD, and SDILT results, the values listed are the measured amounts, not final concentrations.
Where the analytical method has been performed under NELAP certification, the analysis has met all of the
requirements of the NELAC standard unless qualified on the QC Summary.
Page 86 of 86
-------
fleanHarbors'
Clean Harbors, Inc.
Laboratory Test Report
Client ID LM14-0126 Lab Sample ID KEJ473894 SDG J566
lest "Dioxins/FuransNWW UTS (solids)
Aiiah tioal Method: EPA 8280A
Pren Method: F.l'A 8280A
TCLP Batch TO: NA
Prep Batch 11): t02;.9-040214
Data Entered By: RoylanccR
Sampling Date:
3/31/2014
Cleanup Batch ID:
Peer Reviewed By: DickersonD
Analysis Dale:
4/3/2014
Analysis Batch ID: E0419-040314
Parameter
CAS Nbr
DF
Result
Flag LOQ
LOD
Test
Units
Project
Limits
1 2,3,4,6,7,8,9-Octachlorodi beiiz.ofurari
(OCDF)
39001-02-0
1.0
Nl>
0.250
0.250
ug/kg
0.005 mg/kg
1,2,3,4 A 7,8,9- Octac hi orodibe uzo-p-
dioxin (OCDD)
3268-87-9
1.0
3.13
0.250
0.250
ug/kg
0.005 mg/kg
1,2,3,4,6.7, t! -Heptac h 1 orod i bcn7oturan
(HpCDI;)
67562-39-4
10
ND
0.250
0.250
ug/kg
0.0025 mg/kg
1,2,3,4,6,7,8-1 Icptachlorodiheiizo-p-
dioxin (HpCDD)
35822-46-9
1.0
ND
0.250
0.250
ug/kg
0,0025 mg/kg
1 .J i.- T .\v-l:l.'|'(.I'.hlorodibenzofuran
(HpCDI;)
55673-89-7
1.0
ND
0.250
0.250
ug/kg
0.0025 mg/Kg
Total Hcxaclilorodibenzofuran l H>1'
li/a
T.O
ND
0.250
0.250
ug/kg
0.001 mg/kg
Total llcxachloroditenzo-p^iioxm
(HxCDD)
n/a
1.0
ND
0.250
0.250
ug/kg
0,001 nsg/kg
Total Pen tachl orod ibciizofuran (PeCDF)
n/a
1.0
ND
0250
0.250
ug.'kg
0,00? mg/kg
Total Pcntadilorodibenzo-p-dioxiri
(PeCDD)
it/a
1.0
ND
0.250
0.250
ug/kg
0.001 mg/kg
Total Tctradilorodiben^ofurari (TC'DF)
n/a
1.0
ND
0.250
0,250
ug/kg
0.001 mg/kg
Total Tetrac h I orod i betiai- p-d io x i ti n/a 1.0 N! > 0.250 0.250 ug/kg 0,001 mg/kg
fl'CDD)
Report ID
20140404123?
r jidav, April 04,2014
Ail remits are reported on a wes-weishf baits unless otherwise noted
t ab Manager Kimball Laboratory Quality Manager
Richard Roy la nee 2247 South Highway 71 * Kimball * NE 69145 US Robert Waife
(308) 235-8222 Test Report Page 3 of 5 (308)235-8204
-------
Accutest Laboratories
Report of Analysis Page 1 of 3
Client Sample ID: LM14-0126
Lab Sample ID: FA13771-1
Date Sampled:
03/31/14
Matrix:
SO - Solid
Date Received:
04/01/14
Method:
SW846 8270D
SW846 3550C
Percent Solids:
78.0
Project:
LDR
File ID DF
Analyzed
By
Prep Date
Prep Batch Analytical Batch
Run #1
X034128.D I
04/04/14
FS
04/02/14
OP510S5
SX1601
Run #2
Initial Weight
Final Volume
Run #1
30.5 g
1.0 ml
Run #2
ABN Full List
CAS No.
Compound
Result
RL
MDL
Units Q
65-85-0
Benzoic Acid
ND
1100
210
ug/kg
95-57-8
2-Chlorophenol
ND
210
21
ug/kg
59-50-7
4-Cbloro-3-me thyl phenol
ND
210
21
ug/kg
120-83-2
2,4 -D ichlorophenol
ND
210
22
ug/kg
105-67-9
2,4-D imethylphenol
ND
210
23
ug/kg
51-28-5
2,4-Dinitrophenol
ND
1100
210
ug/kg
534-52-1
4,6- D initro- o -cresol
ND
420
84
ug/kg
95-48-7
2-Methylphenol
ND
210
21
ug/kg
3 & 4 -Methy lphenol
ND
210
42
ug/kg
88-75-5
2-Nitrophenol
ND
; 210
21
ug/kg
100-02-7
4-Nitrophenol
ND
1100
170
ug/kg
87-86 5
Pontaehlorophenol3
ND
1100
170
ug/kg
108-95-2
Phenol
ND
210
21
ug/kg
95-95-4
2,4,5 -T richlorophenol
ND
210
27
ng/kg
88-06-2
2,4,6-T richlorophenol
ND
210
21
ug/kg
83-32-9
Acenaphthene
ND
210
27
ug/kg
208-96-8
Acenaphthylene
ND
210
21
ug/kg
62-53-3
Aniline
¦ND
210
21
ug/kg
120-12-7
Anthracene
ND
210
21
ug/kg
92-87-5
Benzidine
ND .
2100
420
ug/kg
56-55-3
Benzo (a)anthracene
ND
1; 210
21
ug/kg
50-32-8
Benzo(a)pyrene
NI)
"' 210
21
»tg%
205-99-2
Benzo (b)fluoranthene
ND
210
21
ug/kg
191-24-2
Benzo (g, h,i)perylene
ND
210
21
ng/kg
207-08-9
Benzo (k) fluoranthene
ND
210
23
ug/kg
101-55-3
4-BromophenyI phenyl ether
Nl)
210
21
ug/kg
85-68-7
Butyl benzyl phthalate
ND
210
42
ug/kg
100-51-6
Benzyl Alcohol
ND
210
21
ug/kg
91-58-7
2-Chloronaphthalene
ND
210
25
ug/kg
106-47-8
4-Chloroaniline
ND
210
21
ug/kg
86-74-8
Carbazole
ND
210
21
ug/kg
218-01-9
Chrysene
ND
r,,, 210
21
ug/kg
ND = Not detected MDL = Method Detection Limit
RL = Reporting Limit
E = Indicates value exceeds calibration range
J = Indicates an estimated value
B = Indicates analyte found in associated method blank
N = Indicates presumptive evidence of a compound
HS 6 of 22
H accutest:
PA13771 -
-------
Accutest Laboratories
Report of Analysis Page 2 of 3
Client Sample ID: LM14-0126
Lab Sample ID: FA13771-1
Date Sampled:
03/31/14
Matrix:
SO - Solid
Date Received:
04/01/14
Method:
SW846 8270D SW846 3550C
Percent ScJids:
78.0
Project:
LDR
ABN Full List
CAS No.
Compound
Result
RL
MDL
Units Q
111-91-1
bis {2 - Chloroe thoxy)methane
ND
¦' 210
21
ug/kg
111-44-4
bis {2 - C hloroethyl)ether
ND
210
21
ug/kg
108 60-1
bis (2-ChloroisopropyI) ether
ND ¦ ;:;:-
210
22
ug/kg
7005-72-3
4-Chlorophenyl phenyl ether
ND
S 210
31
ug/kg
95-50-1
1,2-Dichlorobenzene
ND
210
21
ug/kg
122-6G-7
1,2-DiphenyIhydrazine
ND
, 210
24
ug/kg
541-73-1
1,3-D ichlorobenzene
ND
' 210
21
ug/kg
106-46-7
1 ,4-Dichlorobenzene
ND
210
21
ug/kg
121-14-2
2,4-Dinitrotoluene
ND
210
24
ug/kg
606-20-2
2,6-Dinitrotoluene
ND
210
23
ug/kg
91-94 1
3,3' -Dichlorobenzidine
ND
210
21
ug/kg
53-70-3
Dibenzo(a ,h)anthracene
Nl)
210
21
ug/kg
132-64-9
Dibenzofuran
® 210
21
ug/kg
84-74-2
Di-n-butyl phthalate
ND
A 420
42
ug/kg
117-84-0
Di-n-octyl phthalate
ND
210
42
ug/kg
84-66-2
Diethyl phthalate
ND
420
42
ug/kg
131-11-3
Dimethyl phthalate
ND
210
42
ug/kg
117-81-7
bis(2-Ethylhexyl)phthalate
137
420
42
ug/kg J
206-44-0
Fluoranthene
ND
210
21
ug/kg
86-73-7
Fluorene
ND
210
21
ug/kg
118-74-1
Hexachlorobenzene
ND
210
21
ug/kg
87-68-3
Hexachlorobutadiene
ND
210
21
ug/kg
77-47-4
Hexachlorocyclopentadiene
ND
210
21
ug/kg
67-72-1
Hexachloroethane
ND
210
21
ug/kg
193-39-5
Indeno(l,2,3-cd)pyrene
ND
210
21
ug/kg
78-59-1
lsophorone
ND
210
21
ug/kg
90-12-0
1 - M ethylnaphthalene
ND"
210
21
ug/kg
91-57-6
2- Me thy lnaphthaiene
ND
210
21
ug/kg
88-74-4
2-Nitroaniline
ND
210
42
ug/kg
99-09-2
3-Nitroaniline
ND
210
42
ug/kg
100-01-6
4-Nitroaniline
ND
210
42
ug/kg
91-20-3
Naphthalene
ND
210
21
ug/kg
98-95-3
Nitrobenzene
ND
210
21
ug/kg
62-75-9
N-N itrosodimethy lamine
ND
" 210
Z4
ug/kg
621-64-7
N - Nitroso - di - n-propy lamine
210
21
ug/kg
86-30-6
N - N itrosodipheny lamin e
ND
210
21
ug/kg
85-01-8
Phenanthrene
ND
'210
21
ug/kg
129-00-0
Pyrene
ND
210
21
ug/kg
110-86-1
Pyridine
ND
¦N 420
42
ug/kg
120 82 1
1,2,4-TrichIorobenzene
nd
J 210
21
ug/kg
ND = Not detected MDL = Method Detection Limit J = Indicates an estimated value
RL = Reporting Limit B = Indicates analyte fouid in associated method blank
E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound
mm 7 of 22
¦ ACCUTEST
FA13TT1
-------
Accutest Laboratories
Report of Analysis
Client Sample ID: LM14-0128
Lab Sample ID: FA1377I-1
Matrix: SO - Solid
Method: SW846 8270D SW846 3550C
Project: LDR
Page 3 of 3
Date Sampled: 03/31/14
Date Received: 04/01/14
Percent Solids: 78,0
ABN Full List
CAS No. Surrogate Recoveries
367-12-4 2-Fluorophenol
4165-62-2 Phenol-d5
118-79-6 2,4, 6 T ribromophenol
4165-60-0 Nitrobenzene-d5
321-60-8 2-FluorobiphenyI
1718-51-0 Terphenyl-dl4
CAS No.
123-42-2
Run# 1
84% ,i|
91% -4
100%
108%
Tentatively Identified Compounds
2-Pentanone, 4-hydroxy-4-methyl-
Total Iff -. Semi-Volatile :;i®-
Run# 2 Limits
40-102%
41-100%
42-108%
40-105%
43-107%
45-119%
R-T. Est. Cone. Units Q
2.44 3700 ug/kg JN
3700 «Rr ug/kg J
(a) Associated BS recovery outside control limits.
ND = Not delected MDL = Method Detection Limit
RL = Reporting Limit
E = Indicates value exceeds calibration range
J = Indicates an estimated value
B = Indicates analyte found in associated method blank
N = Indicates presumptive evidence of a compound
Smi &
-------
jeMabinc.
' Environmental Laboratory
http://www.teklabinc.com/
April 28, 2014
Emily Fisher
Tetra Tech
415 Oak Street
Kansas City, MO 64106
TEL: (816)412-1755
FAX:
RE: Strecker Forest RA
Dear Emily Fisher:
TEKLAB, INC received 1 sample on 4/23/2014 7:26:00 PM for the analysis presented in the
following report.
Samples are analyzed on an as received basis unless otherwise requested and documented. The
sample results contained in this report relate only to the requested analytes of interest as
directed on the chain of custody. NELAP accredited fields of testing are indicated by the letters
NELAP under the Certification column. Unless otherwise documented within this report,
Teklab Inc. analyzes samples utilizing the most current methods in compliance with 40CFR.
All tests are performed in the Collinsville, IL laboratory unless otherwise noted in the Case
Narrative.
All quality control criteria applicable to the test methods employed for this project have been
satisfactorily met and are in accordance with NELAP except where noted. The following report
shall not be reproduced, except in full, without the written approval of Teklab, Inc.
If you have any questions regarding these tests results, please feel free to call.
Sincerely,
WorkOrder: 14041303
Michael L. Austin
Project Manager
(618)344-1004 ex 16
MAustin@teklabinc.com
Page 1 of 23
-------
eMabinc.
Environmental Laboratory
Report Contents
http: / / www.teklabinc.com /
Client: Tetra Tech
Client Project: Strecker Forest RA
Work Order: 14041303
Report Date: 28-Apr-14
This reporting package includes the following:
Cover Letter 1
Report Contents 2
Definitions 3
Case Narrative 4
Laboratory Results 5
Sample Summary 8
Dates Report 9
Quality Control Results 10
Receiving Check List 23
Chain of Custody Appended
Page 2 of 23
-------
eMabinc.
Environmental Laboratory
Definitions
http: / / www.teklabinc.com /
Client: Tetra Tech
Client Project: Strecker Forest RA
Work Order: 14041303
Report Date: 28-Apr-14
Abbr Definition
CCV Continuing calibration verification is a check of a standard to determine the state of calibration of an instrument between recalibration.
DF Dilution factor is the dilution performed during analysis only and does not take into account any dilutions made during sample preparation. The
reported result is final and includes all dilutions factors.
DNI Did not ignite
DUP Laboratory duplicate is an aliquot of a sample taken from the same container under laboratory conditions for independent processing and analysis
independently of the original aliquot.
ICV Initial calibration verification is a check of a standard to determine the state of calibration of an instrument before sample analysis is initiated.
IDPH IL Dept. of Public Health
LCS Laboratory control sample, spiked with verified known amounts of analytes, is analyzed exactly like a sample to establish intra-laboratory or analyst
specific precision and bias or to assess the performance of all or a portion of the measurement system. The acceptable recovery range is in the QC
Package (provided upon request).
LCSD Laboratory control sample duplicate is a replicate laboratory control sample that is prepared and analyzed in order to determine the precision of the
approved test method. The acceptable recovery range is listed in the QC Package (provided upon request).
MB Method blank is a sample of a matrix similar to the batch of associated sample (when available) that is free from the analytes of interest and is
processed simultaneously with and under the same conditions as samples through all steps of the analytical procedures, and in which no target
analytes or interferences should present at concentrations that impact the analytical results for sample analyses.
MDL Method detection limit means the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte
concentration is greater than zero and is determined from analysis of a sample in a given matrix type containing the analyte.
MS Matrix spike is an aliquot of matrix fortified (spiked) with known quantities of specific analytes that is subjected to the entire analytical procedures in
order to determine the effect of the matrix on an approved test method's recovery system. The acceptable recovery range is listed in the QC Package
(provided upon request).
MSD Matrix spike duplicate means a replicate matrix spike that is prepared and analyzed in order to determine the precision of the approved test method.
The acceptable recovery range is listed in the QC Package (provided upon request).
MW Molecular weight
ND Not Detected at the Reporting Limit
NELAP NELAP Accredited
PQL Practical quantitation limit means the lowest level that can be reliably achieved within specified limits of precision and accuracy during routine
laboratory operation conditions. The acceptable recovery range is listed in the QC Package (provided upon request).
RL The reporting limit the lowest level that the data is displayed in the final report. The reporting limit may vary according to customer request or sample
dilution. The reporting limit may not be less than the MDL.
RPD Relative percent difference is a calculated difference between two recoveries (ie. MS/MSD). The acceptable recovery limit is listed in the QC Package
(provided upon request).
SPK The spike is a known mass of target analyte added to a blank sample or sub-sample; used to determine recovery deficiency or for other quality
control purposes.
Surr Surrogates are compounds which are similar to the analytes of interest in chemical composition and behavior in the analytical process, but which are
not normally found in environmental samples.
TNTC Too numerous to count ( > 200 CFU )
Qualifiers
# - Unknown hydrocarbon
E - Value above quantitation range
J - Analyte detected below quantitation limits
ND - Not Detected at the Reporting Limit
S - Spike Recovery outside recovery limits
B - Analyte detected in associated Method Blank
H - Holding times exceeded
M - Manual Integration used to determine area response
R - RPD outside accepted recovery limits
X - Value exceeds Maximum Contaminant Level
Page 3 of 23
-------
eMab. inc. Case Narrative
I Environmental Laboratory http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
Cooler Receipt Temp: 18.4 °C
Locations and Accreditations
Collinsville
Springfield
Kansas City
Collinsville Air
Address
Phone
Fax
Email
5445 Horseshoe Lake Road
Collinsville. IL 62234-7425
(618)344-1004
(618)344-1005
jhriley<7 teklabinc.com
3920 Pintail Dr
Springfield. IL 62711-9415
(217) 698-1004
(217) 698-1005
KKlostermannMteklabinc.com
8421 Nieman Road
Lenexa. KS 66214
(913)541-1998
(913)541-1998
dthompsonMteklabinc.i
5445 Horseshoe Lake Road
Collinsville. IL 62234-7425
(618)344-1004
(618)344-1005
EHurleyMteklabinc.com
State
Dept
Cert #
NELAP
Exp Date
Lab
Illinois
IEPA
100226
NELAP
1/31/2015
Collinsville
Kansas
KDHE
E-10374
NELAP
4/30/2014
Collinsville
Louisiana
LDEQ
166493
NELAP
6/30/2014
Collinsville
Louisiana
LDEQ
166578
NELAP
6/30/2014
Springfield
Texas
TCEQ
T104704515-12-1
NELAP
7/31/2014
Collinsville
Arkansas
ADEQ
88-0966
3/14/2015
Collinsville
Illinois
IDPH
17584
5/31/2015
Collinsville
Kentucky
LIST
0073
1/31/2015
Collinsville
Missouri
MDNR
00930
5/31/2015
Collinsville
Oklahoma
ODEQ
9978
8/31/2014
Collinsville
Page 4 of 23
-------
eklalunc.
1 Environmental Laboratory
Laboratory Results
http://www.teklabinc.com/
Client:
Tetra Tech
Work Order:
14041303
Client Project:
Strecker Forest RA
Report Date:
28-Apr-14
Lab ID:
14041303-001
Client Sample ID: SFRA-25
Matrix:
SOLID
Collection Date: 04/23/2014 0:00
Analyses
Certification
RL
Qual
Result
Units
DF
Date Analyzed
Batch
ASTM D4979-95
Color
0
Brown
1
04/24/2014 9:47
R189911
Layering
0
None
1
04/24/2014 9:47
R189911
Odor
0
Solvent
1
04/24/2014 9:47
R189911
Physical State
0
Soil
1
04/24/2014 9:47
R189911
Turbidity
0
None
1
04/24/2014 9:47
R189911
Viscosity
0
None
1
04/24/2014 9:47
R189911
ASTM D5058-90
Water Reactivity
0
None
1
04/24/2014 9:47
R189911
Miscibility
0
Immiscible
1
04/24/2014 9:47
R189911
Apparent Density
0
> Water
1
04/24/2014 9:47
R189911
ASTM D92
Ignitability, Open Cup
60
>200
°F
1
04/25/2014 8
42
R189940
STANDARD METHODS 2540 G
Total Solids
0.1
72.1
%
1
04/25/2014 11:30
R190003
SW-846 9014 (REACTIVE)
Cyanide, Reactive
NELAP
2.44
< 2.44
mg/Kg
1
04/28/2014 11
15
98233
SW-846 9034 (REACTIVE)
Sulfide, Reactive
NELAP
10
< 10
mg/Kg
1
04/25/2014 14:27
98199
SW-846 9045C
pH (1:1)
NELAP
1
6.59
1
04/24/2014 17:54
R189865
SW-846 9065
Phenols
NELAP
14.1
s
17.2
mg/Kg
5
04/28/2014 14:52
98235
MS and/or MSD did not recover within control limits due to matrix interference.
SW-846 9095
Paint Filter
NELAP
0
Pass
Pass/Fail
1
04/24/2014 9:59
R189910
SW-846 1311, 301 OA, 6010B, METALS IN TCLP EXTRACT BY ICP
Arsenic
NELAP
0.25
< 0.25
mg/L
1
04/28/2014 11
01
98187
Barium
NELAP
0.05
1.49
mg/L
1
04/28/2014 11
01
98187
Cadmium
NELAP
0.02
0.109
mg/L
1
04/28/2014 11
01
98187
Chromium
NELAP
0.1
< 0.1
mg/L
1
04/28/2014 11
01
98187
Lead
NELAP
0.4
j
0.17
mg/L
1
04/28/2014 11
01
98187
Selenium
NELAP
0.5
< 0.5
mg/L
1
04/28/2014 11
01
98187
Silver
NELAP
0.1
< 0.1
mg/L
1
04/28/2014 11
01
98187
SW-846 1311, 7470A IN TCLP EXTRACT
Mercury
NELAP
0.0002
< 0.0002
mg/L
1
04/25/2014 13:52
98185
SW-846 1311, 3510C, 8081B, CHLORINATED PESTICIDES IN TCLP EXTRACT BY GC/ECD
alpha-Chlordane
NELAP
0.0005
ND
mg/L
1
04/26/2014 20:59
98186
Chlordane
NELAP
0.005
ND
mg/L
1
04/26/2014 20:59
98186
Endrin
NELAP
0.0005
ND
mg/L
1
04/26/2014 20:59
98186
gamma-BHC
NELAP
0.0005
ND
mg/L
1
04/26/2014 20:59
98186
gamma-Chlordane
NELAP
0.0005
ND
mg/L
1
04/26/2014 20:59
98186
Heptachlor
NELAP
0.0005
ND
mg/L
1
04/26/2014 20:59
98186
Heptachlor epoxide
NELAP
0.0005
ND
mg/L
1
04/26/2014 20:59
98186
Methoxychlor
NELAP
0.0005
ND
mg/L
1
04/26/2014 20:59
98186
Toxaphene
NELAP
0.005
ND
mg/L
1
04/26/2014 20:59
98186
Surr: Decachlorobiphenyl
10-148
87.9
%REC
1
04/26/2014 20:59
98186
Page 5 of 23
-------
eMabinc.
Environmental Laboratory
Laboratory Results
http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
Lab ID: 14041303-001 Client Sample ID: SFRA-25
Matrix: SOLID Collection Date: 04/23/2014 0:00
Analyses Certification RL Qual Result Units
DF
Date Analyzed Batch
SW-846 1311, 3510C, 8081B, CHLORINATED PESTICIDES IN TCLP EXTRACT BY GC/ECD
Surr: Tetrachloro-m-xylene 20.9-124 74.5 %REC
1
04/26/2014 20:59 98186
SW-846 1311, 3510C, 8151A, CHLORINATED HERBICIDES IN TCLP EXTRACT BY GC/ECD
2,4,5-TP (Silvex)
NELAP
0.02
ND
mg/L 1
04/26/201415:11
98188
2,4-D
NELAP
0.02
ND
mg/L 1
04/26/201415:11
98188
Surr: 2,4-Dichlorophenylacetic acid
30.7-120
74
%REC 1
04/26/201415:11
98188
SW-846 1311, 3510C, 8270C, SEMI-VOLATILES IN TCLP EXTRACT BY GC/MS
2,4,5-Trichlorophenol
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
2,4,6-Trichlorophenol
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
2,4-Dinitrotoluene
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
Hexachlorobenzene
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
Hexachlorobutadiene
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
Hexachloroethane
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
m,p-Cresol
NELAP
0.1
J
0.023
mg/L 1
04/28/2014 11
00
98169
Nitrobenzene
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
o-Cresol
NELAP
0.1
ND
mg/L 1
04/28/2014 11
00
98169
Pentachiorophenoi
NELAP
0.2
ND
mg/L 1
04/28/2014 11
00
98169
Pyridine
NELAP
0.2
ND
mg/L 1
04/28/2014 11
00
98169
Cresols, Total
NELAP
0.1
J
0.023
mg/L 1
04/28/2014 11
00
98169
Surr: 2,4,6-Tribromophenol
26.4-130
99.7
%REC 1
04/28/2014 11
00
98169
Surr: 2-Fluorobiphenyl
38.3-115
70.9
%REC 1
04/28/2014 11
00
98169
Surr: 2-Fluorophenol
16.5-65
49.6
%REC 1
04/28/2014 11
00
98169
Surr: Nitrobenzene-d5
47.6-107
67.9
%REC 1
04/28/2014 11
00
98169
Surr: Phenol-d5
9.94-41.7
33
%REC 1
04/28/2014 11
00
98169
Surr: p-Terphenyi-d14
65.6-127
86.4
%REC 1
04/28/2014 11
00
98169
SW-846 3550B, 8082, POLYCHLORINATED BIPHENYLS (PCBS) BY GC/ECD
Aroclor 1016
NELAP
37.2
S
211
Mg/Kg 1
04/26/2014 11
59
98118
Aroclor 1221
NELAP
37.2
ND
Mg/Kg 1
04/26/2014 11
59
98118
Aroclor 1232
NELAP
37.2
ND
Mg/Kg 1
04/26/2014 11
59
98118
Aroclor 1242
NELAP
37.2
ND
Mg/Kg 1
04/26/2014 11
59
98118
Aroclor 1248
NELAP
37.2
ND
Mg/Kg 1
04/26/2014 11
59
98118
Aroclor 1254
NELAP
37.2
ND
Mg/Kg 1
04/26/2014 11
59
98118
Aroclor 1260
NELAP
37.2
157
Mg/Kg 1
04/26/2014 11
59
98118
Surr: Decachlorobiphenyl
5-156
70.4
%REC 1
04/26/2014 11
59
98118
Surr: Tetrachloro-meta-xylene
7.35-123
94
%REC 1
04/26/2014 11
59
98118
MS did not recover within control limits due to matrix interference.
SW-846 9023
Extractable Organic Halogens (EOX)
NELAP
49.5
S
150
mg/Kg 1
04/28/2014 10:44
98217
MS did not recover within control limits due to matrix interference.
SW-846 1311, 5030, 8260B, VOLATILE ORGANIC COMPOUNDS IN TCLP EXTRACT BY GC/MS
1,1-Dichloroethene
NELAP
0.5
ND
mg/L 100 04/25/201414:52
98238
1,2-Dichloroethane
NELAP
0.5
ND
mg/L 100 04/25/201414:52
98238
1,4-Dichlorobenzene
NELAP
0.5
ND
mg/L 100 04/25/201414:52
98238
2-Butanone
NELAP
5
ND
mg/L 100 04/25/201414:52
98238
Benzene
NELAP
0.2
ND
mg/L 100 04/25/201414:52
98238
Carbon tetrachloride
NELAP
0.5
ND
mg/L 100 04/25/201414:52
98238
Chlorobenzene
NELAP
0.5
ND
mg/L 100 04/25/201414:52
98238
Chloroform
NELAP
0.5
ND
mg/L 100 04/25/201414:52
98238
Page 6 of 23
-------
eklalunc.
1 Environmental Laboratory
Laboratory Results
http://www.teklabinc.com/
Client: Tetra Tech
Client Project: Strecker Forest RA
Lab ID: 14041303-001
Matrix: SOLID
Work Order: 14041303
Report Date: 28-Apr-14
Client Sample ID: SFRA-25
Collection Date: 04/23/2014 0:00
Analyses Certification
RL Qual
Result
Units
DF
Date Analyzed
Batch
SW-846 1311, 5030, 8260B, VOLATILE ORGANIC COMPOUNDS IN TCLP EXTRACT BY GC/MS
Tetrachloroethene NELAP
0.5
ND
mg/L
100
04/25/2014 14:52
98238
Trichloroethene NELAP
0.5
ND
mg/L
100
04/25/2014 14:52
98238
Vinyl chloride NELAP
0.2
ND
mg/L
100
04/25/2014 14:52
98238
Surr: 1,2-Dichloroethane-d4
74.7-129
97.6
%REC
100
04/25/2014 14:52
98238
Surr: 4-Bromofluorobenzene
86-119
99.7
%REC
100
04/25/2014 14:52
98238
Surr: Dibromofluoromethane
81.7-123
99.3
%REC
100
04/25/2014 14:52
98238
Surr: Toluene-d8
84.3-114
100.4
%REC
100
04/25/2014 14:52
98238
Page 7 of 23
-------
eklablnc.
' Environmental Laboratory
Sample Summary
http://www.teklabinc.com/
Client: Tetra Tech
Client Project: Strecker Forest RA
Work Order: 14041303
Report Date: 28-Apr-14
Lab Sample ID Client Sample ID
Matrix
Fractions Collection Date
14041303-001
SFRA-25
Solid
04/23/2014 0:00
Page 8 of 23
-------
leMabinc.
' Environmental Laboratory
Dates Report
http: / / www.teklabinc.com /
Client: Tetra Tech
Work Order: 14041303
Client Project: Strecker Forest RA
Report Date: 28-Apr-14
Sample ID Client Sample ID
Collection Date
Received Date
Test Name
Prep Date/Time Analysis Date/Time
14041303-001A SFRA-25
04/23/2014 0:00
04/23/2014 19:26
ASTM D4979-95
04/24/2014 9:47
ASTM D5058-90
04/24/2014 9:47
ASTM D92
04/25/2014 8:42
Standard Methods 2540 G
04/25/2014 11:30
SW-846 1311. 301 OA, 6010B. Metals in TCLP Extract by ICP
04/25/2014 10:20
04/28/2014 11:01
SW-846 1311. 3510C. 8081B. Chlorinated Pesticides in TCLP Extract by GC/ECD
04/25/2014 10:16
04/26/2014 20:59
SW-846 1311. 3510C. 8151A Chlorinated Herbicides in TCLP Extract by GC/ECD
04/25/2014 10:30
04/26/2014 15:11
SW-846 1311. 3510C. 8270C. Semi-Volatiles in TCLP Extract by GC/MS
04/25/2014 9:50
04/28/2014 11:00
SW-846 1311. 5030. 8260B. Volatile Organic Compounds in TCLP Extract by GC/MS
04/25/2014 14:52
SW-846 1311. 7470A in TCLP Extract
04/25/2014 10:10
04/25/2014 13:52
SW-846 3550B. 8082. PolyChlorinated Biphenyls (PCBs) by GC/ECD
04/24/2014 10:34
04/26/2014 11:59
SW-846 9014 (Reactive)
04/28/2014 8:45
04/28/2014 11:15
SW-846 9023
04/28/2014 8:26
04/28/2014 10:44
SW-846 9034 (Reactive)
04/25/2014 10:35
04/25/2014 14:27
SW-846 9045C
04/24/2014 17:54
SW-846 9065
04/28/2014 11:15
04/28/2014 14:52
SW-846 9095
04/24/2014 9:59
Page 9 of 23
-------
eMabinc.
Environmental Laboratory
Quality Control Results
http://www.teklabinc.com/
Client: Tetra Tech
Client Project: Strecker Forest RA
Work Order: 14041303
Report Date: 28-Apr-14
ASTM D92
Batch R189940 SampType:
SampID: 14041303-001ADUP
Analyses
DUP
RL
Units °F
Oual
Result Spike
SPKRefVal
%REC
RPD Limit 5
RPDRefVal %RPD
Date
Analyzed
Ignitability, Open Cup
60
>200
0 0.00
04/25/2014
STANDARD METHODS 2540 G
Batch R189935
SampID: LCS
Analyses
SampType:
LCS
RL
Units %
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Total Solids
0.1
1 1
0
100
90 110
04/24/2014
Batch R189935
SampID: LCSQC
Analyses
SampType:
LCSQC
RL
Units %
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Total Solids
0.1
1 1
0
100
90 110
04/24/2014
Batch R190003
SampID: LCS
Analyses
SampType:
LCS
RL
Units %
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Total Solids
0.1
1 1
0
99
90 110
04/25/2014
Batch R190003
SampID: LCSQC
Analyses
SampType:
LCSQC
RL
Units %
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Total Solids
0.1
1 1
0
99
90 110
04/25/2014
Batch R190003 SampType:
SampID: 14041303-001A DUP
Analyses
DUP
RL
Units %
Oual
Result Spike
SPKRefVal
%REC
RPD Limit 15
RPDRefVal %RPD
Date
Analyzed
Total Solids
0.1
71
72.11 1.52
04/25/2014
SW-846 9014 (REACTIVE)
Batch 98233 SampType:
SampID: MBLK 140428 RCN1
Analyses
MBLK
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Cyanide, Reactive
2.5
<2.5
04/28/2014
Batch 98233 SampType:
SampID: LCS 140428 RCN1
Analyses
LCS
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Cyanide, Reactive 5 J 4 10 0 39.5 38.7 116 04/28/2014
Page lO of 23
-------
eMabinc.
Environmental Laboratory
Quality Control Results
http://www.teklabinc.com/
Client: Tetra Tech
Client Project: Strecker Forest RA
Work Order: 14041303
Report Date: 28-Apr-14
SW-846 9014 (REACTIVE)
Batch 98233 SampType:
SampID: 14041303-001ADUP
Analyses
DUP
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
RPD Limit 15
RPDRefVal %RPD
Date
Analyzed
Cyanide, Reactive
2.51
< 2.51
0 0.00
04/28/2014
SW-846 9034 (REACTIVE)
Batch 98199 SampType:
SampID: MBLK 140425 RSUL1
Analyses
MBLK
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Sulfide, Reactive
10
< 10
04/25/2014
Batch 98199 SampType:
SampID: LCS 140425 RSUL1
Analyses
LCS
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Sulfide, Reactive
10
84 98.4
0
85.4
47.3 109
04/25/2014
Batch 98199 SampType:
SampID: 14041303-001 ADUP
Analyses
DUP
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
RPD Limit 10
RPDRefVal %RPD
Date
Analyzed
Sulfide, Reactive
9.9
<9.9
0 0.00
04/25/2014
SW-846 9045C
Batch R189865 SampType:
SampID: LCS-R189865
Analyses
LCS
RL
Units
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
pH (1:1)
1
6.96 7
0
99.4
99.1 100.8
04/23/2014
Batch R189865 SampType:
SampID: 14041303-001A
Analyses
DUP
RL
Units
Oual
Result Spike
SPKRefVal
%REC
RPD Limit 10
RPDRefVal %RPD
Date
Analyzed
pH (1:1)
1
6.59
6.59 0.00
04/24/2014
SW-846 9065
Batch 98235 SampType:
SampID: MBLK 140428 OOH
Analyses
MBLK
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Phenols
2.78
< 2.78 0.05
0
0
0 0
04/28/2014
Batch 98235 SampType:
SampID: LCS 140428 OOH
Analyses
LCS
RL
Units mg/Kg
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Date
Analyzed
Phenols
2.63
10.4 10
0
103.6
90 110
04/28/2014
Page 11 of 23
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eMabinc.
Environmental Laboratory
Quality Control Results
http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 9065
Batch 98235 SampType:
MS
Units mg/Kg
SampID: 14041303-001AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Phenols
12.8
S
21 9.894
17.19
38.1
85
115
04/28/2014
Batch 98235 SampType:
MSD
Units mg/Kg
RPD Limit 15
SampID: 14041303-001AMSD
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
Phenols
11.9
S
21.2 9.236
17.19
43.3
20.96
1.09
04/28/2014
SW-846 9095
Batch R189910 SampType:
DUP
Units Pass/Fail
RPD Limit 0
SampID: 14041303-001ADUP
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
Paint Filter
0
Pass
0
0.00
04/24/2014
SW-846 1311, 301 OA, 6010B, METALS IN TCLP EXTRACT BY ICP
Batch 98187 SampType:
MBLK
Units mg/L
SampID: MBLK-98187
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Arsenic
0.25
< 0.25 0.25
0
0
-100
100
04/28/2014
Barium
0.5
< 0.5 0.5
0
0
-100
100
04/28/2014
Cadmium
0.02
< 0.02 0.02
0
0
-100
100
04/28/2014
Chromium
0.1
<0.1 0.1
0
0
-100
100
04/28/2014
Lead
0.4
< 0.4 0.4
0
0
-100
100
04/28/2014
Selenium
0.5
<0.5 0.5
0
0
-100
100
04/28/2014
Silver
0.1
<0.1 0.1
0
0
-100
100
04/28/2014
Batch 98187 SampType:
LCS
Units mg/L
SampID: LCS-98187
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Arsenic
0.25
20.2 20
0
100.9
85
115
04/28/2014
Barium
0.5
19.7 20
0
98.3
85
115
04/28/2014
Cadmium
0.02
0.495 0.5
0
99
85
115
04/28/2014
Chromium
0.1
1.98 2
0
99
85
115
04/28/2014
Lead
0.4
4.95 5
0
99.1
85
115
04/28/2014
Selenium
0.5
20.1 20
0
100.4
85
115
04/28/2014
Silver
0.1
0.477 0.5
0
95.4
85
115
04/28/2014
Page 12 of 23
-------
eklablnc. Quality Control Results
Environmental Laboratory http://www.teklabinc.com/
Client: Tetra Tech
Work Order: 14041303
Client Project: Strecker Forest RA
Report Date: 28-Apr-14
SW-846 1311, 301 OA, 6010B, METALS IN TCLP EXTRACT BY ICP
Batch 98187 SampType:
MS
Units mg/L
SampID: 14041303-001AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Arsenic
0.25
19.7 20
0
98.6
75
125
04/28/2014
Barium
0.5
20.7 20
1.492
96.2
75
125
04/28/2014
Cadmium
0.02
0.594 0.5
0.109
97
75
125
04/28/2014
Chromium
0.1
1.94 2
0
97
75
125
04/28/2014
Lead
0.4
5 5
0.169
96.7
75
125
04/28/2014
Selenium
0.5
19.5 20
0
97.4
75
125
04/28/2014
Silver
0.1
0.464 0.5
0
92.8
75
125
04/28/2014
Batch 98187 SampType:
MSD
Units mg/L
RPD Limit 20
SampID: 14041303-001AMSD
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
Arsenic
0.25
20 20
0
100
19.72
1.36
04/28/2014
Barium
0.5
21 20
1.492
97.7
20.74
1.44
04/28/2014
Cadmium
0.02
0.6 0.5
0.109
98.2
0.594
1.01
04/28/2014
Chromium
0.1
1.97 2
0
98.4
1.94
1.38
04/28/2014
Lead
0.4
5.06 5
0.169
97.9
5.004
1.17
04/28/2014
Selenium
0.5
19.8 20
0
99
19.49
1.63
04/28/2014
Silver
0.1
0.473 0.5
0
94.6
0.464
1.92
04/28/2014
SW-846 1311, 7470A IN TCLP EXTRACT
Batch 98185 SampType:
MBLK
Units mg/L
SampID: MBLK-98185
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Mercury
0.0002
< 0.0002 0.0002
0
0
-100
100
04/25/2014
Batch 98185 SampType:
LCS
Units mg/L
SampID: LCS-98185
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Mercury
0.0002
0.00495 0.005
0
99
85
115
04/25/2014
Batch 98185 SampType:
MS
Units mg/L
SampID: 14041303-001 AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Mercury
0.0002
0.00508 0.005
0
101.6
75
125
04/25/2014
Batch 98185 SampType:
MSD
Units mg/L
RPD Limit 15
SampID: 14041303-001 AMSD
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
Mercury
0.0002
0.00516 0.005
0
103.3
0.005081
1.61
04/25/2014
Page 13 of 23
-------
eklalunc. Quality Control Results
Environmental Laboratory http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 1311, 3510C, 8081B, CHLORINATED PESTICIDES IN TCLP EXTRACT BY GC/ECD
Batch 98186 SampType: MBLK Units [jg/L
SampID: MBLK-98186
Analyses RL Oual Result Spike SPKRefVal %REC
Low Limit High Limit
Date
Analyzed
alpha-Chlordane
0.05
ND
04/26/2014
Endrin
0.05
ND
04/26/2014
gamma-BHC
0.05
ND
04/26/2014
gamma-Chlordane
0.05
ND
04/26/2014
Heptachlor
0.05
ND
04/26/2014
Heptachlor epoxide
0.05
ND
04/26/2014
Methoxychlor
0.05
ND
04/26/2014
Toxaphene
0.5
ND
04/26/2014
Chlordane
0.5
ND
04/26/2014
Surr: Decachlorobiphenyl
0.18
0.25
71.1
11.3 138
04/26/2014
Surr: Tetrachloro-m-xylene
0.19
0.25
76.4
13 114
04/26/2014
Batch 98186 SampType: MBLK
Units mg/L
SampID: MBLKTCLP-98159
Date
Analyses RL
Oual
Result Spike SPKRefVal %REC
Low Limit High Limit
Analyzed
alpha-Chlordane
0.0005
ND
04/26/2014
Endrin
0.0005
ND
04/26/2014
gamma-BHC
0.0005
ND
04/26/2014
gamma-Chlordane
0.0005
ND
04/26/2014
Heptachlor
0.0005
ND
04/26/2014
Heptachlor epoxide
0.0005
ND
04/26/2014
Methoxychlor
0.0005
ND
04/26/2014
Toxaphene
0.005
ND
04/26/2014
Chlordane
0.005
ND
04/26/2014
Surr: Decachlorobiphenyl
0.00204 0.0025
81.7
25.9
140
04/26/2014
Surr: Tetrachloro-m-xylene
0.00205 0.0025
82
23.7
93
04/26/2014
Batch 98186
SampType: LCS
Units [jg/L
SampID: LCSPST-98186
Date
Analyses
RL
Oual
Result Spike SPKRefVal %REC
Low Limit High Limit
Analyzed
alpha-Chlordane
0.05
0.17
0.25
0
68.2
50.5
137
04/26/2014
Endrin
0.05
0.21
0.25
0
84.4
47.6
139
04/26/2014
gamma-BHC
0.05
0.19
0.25
0
74.4
47.6
127
04/26/2014
gamma-Chlordane
0.05
0.17
0.25
0
67.3
48.3
138
04/26/2014
Heptachlor
0.05
0.19
0.25
0
75.6
47.8
117
04/26/2014
Heptachlor epoxide
0.05
0.2
0.25
0
78.7
52.6
136
04/26/2014
Methoxychlor
0.05
0.19
0.25
0
75.5
45.3
140
04/26/2014
Surr: Decachlorobiphenyl
0.13
0.25
51.8
9.42
147
04/26/2014
Surr: Tetrachloro-m-xylene
0.17
0.25
69.1
13
114
04/26/2014
Page 14 of 23
-------
eklablnc. Quality Control Results
Environmental Laboratory http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 1311, 3510C, 8081B, CHLORINATED PESTICIDES IN TCLP EXTRACT BY GC/ECD
Batch 98186 SampType:
LCSD
Units [jg/L
RPD Limit 30
SampID: LCSPSTD-98186
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
alpha-Chlordane
0.05
0.13 0.25
0
51.3
0.1706
28.32
04/26/2014
Endrin
0.05
0.16 0.25
0
64.1
0.2109
27.36
04/26/2014
gamma-BHC
0.05
0.16 0.25
0
62.5
0.1861
17.45
04/26/2014
gamma-Chlordane
0.05
0.13 0.25
0
50.4
0.1683
28.74
04/26/2014
Heptachlor
0.05
R
0.12 0.25
0
49.3
0.189
42.03
04/26/2014
Heptachlor epoxide
0.05
0.15 0.25
0
61.8
0.1967
24.02
04/26/2014
Methoxychlor
0.05
0.15 0.25
0
59.1
0.1888
24.37
04/26/2014
Surr: Decachlorobiphenyl
0.11 0.25
44.9
04/26/2014
Surr: Tetrachloro-m-xylene
0.15 0.25
58.5
04/26/2014
Batch 98186 SampType:
MS
Units mg/L
SampID: 14041303-001AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
alpha-Chlordane
0.0005
0.00207 0.0025
0
83
51.6
128
04/26/2014
Endrin
0.0005
0.00256 0.0025
0
102.3
63.7
142
04/26/2014
gamma-BHC
0.0005
0.00188 0.0025
0
75.4
53.4
131
04/26/2014
gamma-Chlordane
0.0005
0.00203 0.0025
0
81.3
43.2
137
04/26/2014
Heptachlor
0.0005
0.00218 0.0025
0
87.4
40.9
121
04/26/2014
Heptachlor epoxide
0.0005
0.00218 0.0025
0
87.4
56.9
126
04/26/2014
Methoxychlor
0.0005
0.00243 0.0025
0
97.2
67.4
129
04/26/2014
Surr: Decachlorobiphenyl
0.00223 0.0025
89.4
10
148
04/26/2014
Surr: Tetrachloro-m-xylene
0.00187 0.0025
74.8
20.9
124
04/26/2014
Batch 98186 SampType:
MSD
Units mg/L
RPD Limit 30
SampID: 14041303-001AMSD
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
alpha-Chlordane
0.0005
0.00212 0.0025
0
84.8
0.002075
2.18
04/26/2014
Endrin
0.0005
0.00258 0.0025
0
103.3
0.002559
0.95
04/26/2014
gamma-BHC
0.0005
0.00187 0.0025
0
74.7
0.001885
0.94
04/26/2014
gamma-Chlordane
0.0005
0.00208 0.0025
0
83
0.002032
2.14
04/26/2014
Heptachlor
0.0005
0.00221 0.0025
0
88.4
0.002184
1.16
04/26/2014
Heptachlor epoxide
0.0005
0.00219 0.0025
0
87.7
0.002185
0.34
04/26/2014
Methoxychlor
0.0005
0.00246 0.0025
0
98.5
0.002429
1.37
04/26/2014
Surr: Decachlorobiphenyl
0.00239 0.0025
95.5
04/26/2014
Surr: Tetrachloro-m-xylene
0.00176 0.0025
70.5
04/26/2014
SW-846 1311, 3510C, 8151A, CHLORINATED HERBICIDES IN TCLP EXTRACT BY GC/ECD
Batch 98188 SampType:
MBLK
Units [jg/L
SampID: MBLK-98188
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
2,4,5-TP (Silvex)
0.4
ND
04/26/2014
2,4-D
0.4
ND
04/26/2014
Surr: 2,4-Dichlorophenylacetic acid
0.542 0.8
67.8
15.1
96.2
04/26/2014
Page IS of 23
-------
eklablnc. Quality Control Results
Environmental Laboratory http://www.teklabinc.com/
Client: Tetra Tech
Work Order: 14041303
Client Project: Strecker Forest RA
Report Date: 28-Apr-14
SW-846 1311, 3510C, 8151A, CHLORINATED HERBICIDES IN TCLP EXTRACT BY GC/ECD
Batch 98188 SampType: MBLK
Units mg/L
SampID: MBLK-TCLP98159
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Analyzed
2,4,5-TP (Silvex)
0.02
ND
04/26/2014
2,4-D
0.02
ND
04/26/2014
Surr: 2,4-Dichlorophenylacetic acid
0.033 0.04
82.6
28.8 107
04/26/2014
Batch 98188 SampType: LCS
Units [jg/L
SampID: LCS-98188
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Analyzed
2,4,5-TP (Silvex)
0.4
0.618 0.8
0
77.3
42.5 119
04/26/2014
2,4-D
0.4
0.547 0.8
0
68.4
17.3 139
04/26/2014
Surr: 2,4-Dichlorophenylacetic acid
0.572 0.8
71.5
9.8 103
04/26/2014
Batch 98188 SampType: LCSD
Units |jg/L
RPD Limit 30
SampID: LCSD-98188
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
2,4,5-TP (Silvex)
0.4
0.672 0.8
0
84
0.6182 8.37
04/26/2014
2,4-D
0.4
0.588 0.8
0
73.5
0.547 7.24
04/26/2014
Surr: 2,4-Dichlorophenylacetic acid
0.601 0.8
75.2
04/26/2014
Batch 98188 SampType: MS
Units mg/L
SampID: 14041303-001AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit High Limit
Analyzed
2,4,5-TP (Silvex)
0.02
0.031 0.04
0
77.3
40 160
04/26/2014
2,4-D
0.02
0.027 0.04
0
67.7
40 160
04/26/2014
Surr: 2,4-Dichlorophenylacetic acid
0.025 0.04
63.7
40 160
04/26/2014
Batch 98188 SampType: MSD
Units mg/L
RPD Limit 30
SampID: 14041303-001AMSD
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
2,4,5-TP (Silvex)
0.02
0.035 0.04
0
86.6
0.0309 11.45
04/26/2014
2,4-D
0.02
0.031 0.04
0
76.9
0.02706 12.82
04/26/2014
Surr: 2,4-Dichlorophenylacetic acid
0.03 0.04
74.1
04/26/2014
Page 16 of 23
-------
eklalunc. Quality Control Results
Environmental Laboratory http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 1311, 3510C, 8270C, SEMI-VOLATILES IN TCLP EXTRACT BY GC/MS
Batch 98169 SampType: MBLK Units mg/L
SampID: MBLK-98169
Analyses RL Oual Result Spike SPKRefVal %REC
Low Limit High Limit
Date
Analyzed
2,4,5-Trichlorophenol
0.01
ND
04/25/2014
2,4,6-Trichiorophenoi
0.01
ND
04/25/2014
2,4-Dinitrotoiuene
0.01
ND
04/25/2014
Hexachlorobenzene
0.01
ND
04/25/2014
Hexachlorobutadiene
0.01
ND
04/25/2014
Hexachloroethane
0.01
ND
04/25/2014
m,p-Cresol
0.01
ND
04/25/2014
Nitrobenzene
0.01
ND
04/25/2014
o-Cresol
0.01
ND
04/25/2014
Pentachlorophenol
0.02
ND
04/25/2014
Pyridine
0.02
ND
04/25/2014
Surr: 2,4,6-Tribromophenol
0.052
0.05
104.5
36.9
125
04/25/2014
Surr: 2-Fluorobiphenyl
0.02
0.025
78.4
36.7
114
04/25/2014
Surr: 2-Fiuorophenoi
0.029
0.05
57.7
23.9
78.3
04/25/2014
Surr: Nitrobenzene-d5
0.018
0.025
71.2
36.6
119
04/25/2014
Surr: Phenoi-d5
0.018
0.05
36.4
14.1
51.6
04/25/2014
Surr: p-Terphenyi-d14
0.024
0.025
95.7
41.6
133
04/25/2014
Batch 98169 SampType: LCS
Units mg/L
SampID: LCS-98169
Date
Analyses RL
Oual
Result Spike SPKRefVal %REC
Low Limit High Limit
Analyzed
2,4,5-Trichlorophenol
0.01
0.082
0.1
0
82
64.1
118
04/25/2014
2,4,6-Trichlorophenol
0.01
0.077
0.1
0
76.6
57.9
120
04/25/2014
2,4-Dinitrotoluene
0.01
0.045
0.05
0
90.1
58.7
120
04/25/2014
Hexachlorobenzene
0.01
0.085
0.1
0
85
60.2
118
04/25/2014
Hexachlorobutadiene
0.01
0.064
0.1
0
63.5
36.9
99.5
04/25/2014
Hexachloroethane
0.01
0.055
0.1
0
55
31.8
92.6
04/25/2014
m,p-Cresol
0.01
0.027
0.05
0
54.6
45.3
88.8
04/25/2014
Nitrobenzene
0.01
0.064
0.1
0
64.2
54.1
102
04/25/2014
o-Cresol
0.01
0.027
0.05
0
54.1
47.6
98.3
04/25/2014
Pentachlorophenol
0.02
0.084
0.1
0
84.4
53.1
133
04/25/2014
Pyridine
0.02
0.031
0.1
0
31.4
21.6
66.2
04/25/2014
Surr: 2,4,6-Tribromophenol
0.049
0.05
98.6
52.6
124
04/25/2014
Surr: 2-Fluorobiphenyl
0.016
0.025
63.5
57.8
101
04/25/2014
Surr: 2-Fluorophenol
0.018
0.05
36.9
34.6
64.5
04/25/2014
Surr: Nitrobenzene-d5
0.018
0.025
72.7
49.9
124
04/25/2014
Surr: Phenol-d5
0.013
0.05
25.2
19.4
43.4
04/25/2014
Surr: p-Terphenyl-d14
0.022
0.025
88.2
46.3
115
04/25/2014
Page 17 of 23
-------
eMabinc.
Environmental Laboratory
Quality Control Results
http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 1311, 3510C, 8270C, SEMI-VOLATILES IN TCLP EXTRACT BY GC/MS
Batch 98169 SampType:
LCSD
Units mg/L
RPD Limit 40
SampID: LCSD-98169
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
2,4,5-Trichlorophenol
0.01
0.09
0.1
0
90.1
0.082
9.44
04/25/2014
2,4,6-Trichlorophenol
0.01
0.084
0.1
0
83.7
0.07662
8.78
04/25/2014
2,4-Dinitrotoluene
0.01
0.046
0.05
0
92.4
0.04504
2.53
04/25/2014
Hexachlorobenzene
0.01
0.088
0.1
0
87.8
0.08504
3.16
04/25/2014
Hexachlorobutadiene
0.01
0.072
0.1
0
72.4
0.06354
13.01
04/25/2014
Hexachloroethane
0.01
0.065
0.1
0
65.2
0.05498
17.02
04/25/2014
m,p-Cresol
0.01
0.034
0.05
0
67.3
0.02728
20.88
04/25/2014
Nitrobenzene
0.01
0.073
0.1
0
73.3
0.0642
13.25
04/25/2014
o-Cresol
0.01
0.033
0.05
0
66.9
0.02703
21.26
04/25/2014
Pentachlorophenol
0.02
0.091
0.1
0
91.4
0.08438
7.93
04/25/2014
Pyridine
0.02
0.034
0.1
0
34.3
0.03142
8.69
04/25/2014
Surr: 2,4,6-Tribromophenol
0.051
0.05
102.1
04/25/2014
Surr: 2-Fluorobiphenyl
0.017
0.025
69
04/25/2014
Surr: 2-Fluorophenol
0.024
0.05
47.2
04/25/2014
Surr: Nitrobenzene-d5
0.021
0.025
85.4
04/25/2014
Surr: Phenol-d5
0.016
0.05
31.4
04/25/2014
Surr: p-Terphenyl-d14
0.022
0.025
89.2
04/25/2014
Batch 98169 SampType:
MS
Units mg/L
SampID: 14041303-001AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
2,4,5-Trichlorophenol
0.1
0.843
1
0
84.3
38.6
123
04/28/2014
2,4,6-Trichlorophenol
0.1
0.794
1
0
79.4
35.9
123
04/28/2014
2,4-Dinitrotoluene
0.1
0.811
1
0
81.1
60
108
04/28/2014
Hexachlorobenzene
0.1
0.843
1
0
84.3
55.9
106
04/28/2014
Hexachlorobutadiene
0.1
0.725
1
0
72.5
35.7
100
04/28/2014
Hexachloroethane
0.1
0.725
1
0
72.5
38.9
89.9
04/28/2014
m,p-Cresol
0.1
1.12
2
0.02255
54.7
37.6
93.7
04/28/2014
Nitrobenzene
0.1
0.775
1
0
77.5
51.8
104
04/28/2014
o-Cresol
0.1
0.624
1
0
62.4
43
101
04/28/2014
Pentachlorophenol
0.2
0.866
1
0
86.6
26.8
134
04/28/2014
Pyridine
0.2
0.468
1
0
46.8
3.61
74.3
04/28/2014
Cresols, Total
0.1
1.74
3
0.02255
57.2
43
101
04/28/2014
Surr: 2,4,6-Tribromophenol
0.5
0.5
100
26.4
130
04/28/2014
Surr: 2-Fluorobiphenyl
0.179
0.25
71.6
38.3
115
04/28/2014
Surr: 2-Fluorophenol
0.244
0.5
48.8
16.5
65
04/28/2014
Surr: Nitrobenzene-d5
0.249
0.25
99.6
47.6
107
04/28/2014
Surr: Phenol-d5
0.162
0.5
32.3
9.94
41.7
04/28/2014
Surr: p-Terphenyl-d14
0.214
0.25
85.4
63.4
122
04/28/2014
Page 18 of 23
-------
eMabinc.
Environmental Laboratory
Quality Control Results
http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 1311, 3510C, 8270C, SEMI-VOLATILES IN TCLP EXTRACT BY GC/MS
Batch 98169 SampType:
MSD
Units mg/L
RPD Limit 29.2
SampID: 14041303-001AMSD
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
2,4,5-Trichlorophenol
0.1
0.908
1
0
90.8
0.8427
7.50
04/28/2014
2,4,6-Trichlorophenol
0.1
0.848
1
0
84.8
0.7935
6.66
04/28/2014
2,4-Dinitrotoluene
0.1
0.871
1
0
87.1
0.8111
7.16
04/28/2014
Hexachlorobenzene
0.1
0.918
1
0
91.8
0.8432
8.52
04/28/2014
Hexachlorobutadiene
0.1
0.751
1
0
75.1
0.7246
3.62
04/28/2014
Hexachloroethane
0.1
0.746
1
0
74.6
0.7247
2.84
04/28/2014
m,p-Cresol
0.1
1.2
0.02255
58.9
1.116
7.32
04/28/2014
Nitrobenzene
0.1
0.847
1
0
84.7
0.7746
8.92
04/28/2014
o-Cresol
0.1
0.68
1
0
68
0.6236
8.65
04/28/2014
Pentachlorophenol
0.2
0.932
1
0
93.2
0.8661
7.30
04/28/2014
Pyridine
0.2
0.43
1
0
43
0.4684
8.48
04/28/2014
Cresols, Total
0.1
1.88
3
0.02255
61.9
1.739
7.80
04/28/2014
Surr: 2,4,6-Tribromophenol
0.504
0.5
100.8
04/28/2014
Surr: 2-Fluorobiphenyl
0.181
0.25
72.3
04/28/2014
Surr: 2-Fluorophenol
0.246
0.5
49.3
04/28/2014
Surr: Nitrobenzene-d5
0.255
0.25
102.1
04/28/2014
Surr: Phenol-d5
0.167
0.5
33.3
04/28/2014
Surr: p-Terphenyl-d14
0.219
0.25
87.5
04/28/2014
SW-846 3550B, 8082, POLYCHLORINATED BIPHENYLS (PCBS) BY GC/ECD
Batch 98118 SampType:
MBLK
Units |jg/Kg
SampID: MBLK-98118
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Aroclor 1016
37.5
ND
04/23/2014
Aroclor 1221
37.5
ND
04/23/2014
Aroclor 1232
37.5
ND
04/23/2014
Aroclor 1242
37.5
ND
04/23/2014
Aroclor 1248
37.5
ND
04/23/2014
Aroclor 1254
37.5
ND
04/23/2014
Aroclor 1260
37.5
ND
04/23/2014
Surr: Decachlorobiphenyl
7.6
8.3
91.6
59
160
04/23/2014
Surr: Tetrachloro-meta-xylene
6.8
8.3
82
31.6
114
04/23/2014
Batch 98118 SampType:
LCS
Units M9/Kg
SampID: LCSPCB-98118
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Aroclor 1016
37.5
135
166.7
0
80.9
54.9
121
04/23/2014
Aroclor 1260
37.5
156
166.7
0
93.4
65.5
133
04/23/2014
Surr: Decachlorobiphenyl
9
8.3
108.7
79.1
132
04/23/2014
Surr: Tetrachloro-meta-xylene
6.8
8.3
82.3
31.6
114
04/23/2014
Page 19 of 23
-------
eMabinc.
Environmental Laboratory
Quality Control Results
http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 3550B, 8082, POLYCHLORINATED BIPHENYLS (PCBS) BY GC/ECD
Batch 98118 SampType: MS
Units |jg/Kg
SampID: 14041303-001AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Aroclor 1016
37.4
S
233 166.1
211.2
13.1
35.8
143
04/26/2014
Aroclor 1260
37.4
209 166.1
157.2
31.2
22.3
152
04/26/2014
Surr: Decachlorobiphenyl
5.6 8.272
67.9
5
156
04/26/2014
Surr: Tetrachloro-meta-xylene
6.2 8.272
75.1
7.35
123
04/26/2014
Batch 98118 SampType: MSD
Units |jg/Kg
RPD Limit 40
SampID: 14041303-001AMSD
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
RPDRefVal %RPD
Analyzed
Aroclor 1016
37.3
271 166
211.2
36.1
232.9
15.14
04/26/2014
Aroclor 1260
37.3
226 166
157.2
41.2
209.1
7.60
04/26/2014
Surr: Decachlorobiphenyl
5.2 8.264
63.1
04/26/2014
Surr: Tetrachloro-meta-xylene
6.8 8.264
82.5
04/26/2014
SW-846 9023
Batch 98217 SampType: MBLK
Units mg/Kg
SampID: 140428MBLK
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Extractable Organic Halogens (EOX)
250
< 250
04/28/2014
Batch 98217 SampType: LCS
Units mg/Kg
SampID: 1404282LCS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Extractable Organic Halogens (EOX)
250
J
230 250
0
92.4
70
130
04/28/2014
Batch 98217 SampType: LCS
Units mg/Kg
SampID: 140428LCS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Extractable Organic Halogens (EOX)
250
J
250 250
0
99
70
130
04/28/2014
Batch 98217 SampType: MS
Units mg/Kg
SampID: 14041303-001 AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
Extractable Organic Halogens (EOX)
50
S
534 250
150
153.6
70
130
04/28/2014
Page 20 of 23
-------
eklalunc. Quality Control Results
Environmental Laboratory http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 1311, 5030, 8260B, VOLATILE ORGANIC COMPOUNDS IN TCLP EXTRACT BY GC/MS
Batch 98238 SampType: MBLK Units [jg/L
SampID: MBLK-R140425-1
Analyses RL Qual Result Spike SPKRefVal %REC
Low Limit High Limit
Date
Analyzed
1,1-Dichloroethene
5
ND
04/25/2014
1,2-Dichloroethane
5
ND
04/25/2014
1,4-Dichlorobenzene
5
ND
04/25/2014
2-Butanone
25
ND
04/25/2014
Benzene
2
ND
04/25/2014
Carbon tetrachloride
5
ND
04/25/2014
Chlorobenzene
5
ND
04/25/2014
Chloroform
5
ND
04/25/2014
Tetrachloroethene
5
ND
04/25/2014
Trichloroethene
5
ND
04/25/2014
Vinyl chloride
2
ND
04/25/2014
Surr: 1,2-Dichloroethane-d4
Surr: 4-Bromofluorobenzene
Surr: Dibromofluoromethane
Surr: Toluene-d8
48.8
49.9
50
50.4
50
97.6
74.7
129
50
99.8
86
119
50
100.1
81.7
123
50
100.9
84.3
114
04/25/2014
04/25/2014
04/25/2014
04/25/2014
Batch 98238 SampType: LCSD
Units [jg/L
RPD Limit 40
SampID: LCSD-R140425-1
Date
Analyses RL
Qual
Result Spike SPKRefVal %REC
RPDRefVal %RPD
Analyzed
1,1-Dichloroethene
5
47.5
50
0
95
47.59
0.17
04/25/2014
1,2-Dichloroethane
5
47
50
0
94
45.95
2.22
04/25/2014
1,4-Dichlorobenzene
5
48.1
50
0
96.2
47.95
0.35
04/25/2014
2-Butanone
25
123
125
0
98.1
123.4
0.62
04/25/2014
Benzene
2
46.7
50
0
93.4
46.08
1.32
04/25/2014
Carbon tetrachloride
5
53.1
50
0
106.2
51.64
2.83
04/25/2014
Chlorobenzene
5
49.4
50
0
98.8
49.1
0.63
04/25/2014
Chloroform
5
48.2
50
0
96.4
47.13
2.22
04/25/2014
Tetrachloroethene
5
49.2
50
0
98.3
48.43
1.52
04/25/2014
Trichloroethene
5
48.3
50
0
96.5
47.44
1.71
04/25/2014
Vinyl chloride
2
53.9
50
0
107.9
52.59
2.52
04/25/2014
Surr: 1,2-Dichloroethane-d4
48.8
50
97.6
04/25/2014
Surr: 4-Bromofluorobenzene
48.1
50
96.2
04/25/2014
Surr: Dibromofluoromethane
50.5
50
101
04/25/2014
Surr: Toluene-d8
49.5
50
99
04/25/2014
Page 21 of 23
-------
eMabinc.
Environmental Laboratory
Quality Control Results
http://www.teklabinc.com/
Client: Tetra Tech Work Order: 14041303
Client Project: Strecker Forest RA Report Date: 28-Apr-14
SW-846 1311, 5030, 8260B, VOLATILE ORGANIC COMPOUNDS IN TCLP EXTRACT BY GC/MS
Batch 98238 SampType:
LCS
Units [jg/L
SampID: LCS-R140425-1
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
1,1-Dichloroethene
5
47.6
50
0
95.2
74.1
117
04/25/2014
1,2-Dichloroethane
5
46
50
0
91.9
70.6
118
04/25/2014
1,4-Dichlorobenzene
5
48
50
0
95.9
77.8
114
04/25/2014
2-Butanone
25
123
125
0
98.7
70.7
136
04/25/2014
Benzene
2
46.1
50
0
92.2
80
114
04/25/2014
Carbon tetrachloride
5
51.6
50
0
103.3
79.4
130
04/25/2014
Chlorobenzene
5
49.1
50
0
98.2
81.4
110
04/25/2014
Chloroform
5
47.1
50
0
94.3
82.7
116
04/25/2014
Tetrachloroethene
5
48.4
50
0
96.9
72.5
125
04/25/2014
Trichloroethene
5
47.4
50
0
94.9
84.4
114
04/25/2014
Vinyl chloride
2
52.6
50
0
105.2
58
134
04/25/2014
Surr: 1,2-Dichloroethane-d4
48.7
50
97.4
74.7
129
04/25/2014
Surr: 4-Bromofluorobenzene
47.8
50
95.7
86
119
04/25/2014
Surr: Dibromofluoromethane
49.7
50
99.5
81.7
123
04/25/2014
Surr: Toluene-d8
49.2
50
98.4
84.1
114
04/25/2014
Batch 98238 SampType:
MS
Units mg/L
SampID: 14041303-001AMS
Date
Analyses
RL
Oual
Result Spike
SPKRefVal
%REC
Low Limit
High Limit
Analyzed
1,1-Dichloroethene
0.5
4.61
5
0
92.2
61.3
123
04/25/2014
1,2-Dichloroethane
0.5
4.68
5
0
93.5
71.5
116
04/25/2014
1,4-Dichlorobenzene
0.5
4.96
5
0
99.2
76.9
113
04/25/2014
2-Butanone
2.5
5.11
5
0
102.3
64.1
132
04/25/2014
Benzene
0.2
4.55
5
0
91
81.5
113
04/25/2014
Carbon tetrachloride
0.5
4.72
5
0
94.4
55.5
125
04/25/2014
Chlorobenzene
0.5
4.94
5
0
98.7
81.8
111
04/25/2014
Chloroform
0.5
4.81
5
0
96.3
81
115
04/25/2014
Tetrachloroethene
0.5
4.46
5
0
89.2
61.7
114
04/25/2014
Trichloroethene
0.5
4.66
5
0
93.3
74.4
117
04/25/2014
Vinyl chloride
0.2
4.55
5
0
91.1
45.7
130
04/25/2014
Surr: 1,2-Dichloroethane-d4
4.9
5
97.9
74.7
129
04/25/2014
Surr: 4-Bromofluorobenzene
5.02
5
100.5
86
119
04/25/2014
Surr: Dibromofluoromethane
4.99
5
99.8
81.7
123
04/25/2014
Surr: Toluene-d8
5.01
5
100.2
84.3
114
04/25/2014
Page 22 of 23
-------
eklablnc.
1 Environmental Laboratory
Receiving Check List
http://www.teklabinc.com/
Client: Tetra Tech
Client Project: Strecker Forest RA
Work Order: 14041303
Report Date: 28-Apr-14
Carrier: Dave Kinroth
Completed by:
On:
24-Apr-14
ft
Emily E. Polilman
Received By: ML
Reviewed by:
On:
24-Apr-14
Michael L. Austin
Pages to follow: Chain of custody 1
Extra pages included 0
Shipping container/cooler in good condition?
Yes
0
No ~
Not Present
~
Type of thermal preservation?
None
0
Ice ~
Blue Ice
~
Chain of custody present?
Yes
0
No ~
Chain of custody signed when relinquished and received?
Yes
0
No ~
Chain of custody agrees with sample labels?
Yes
0
No ~
Samples in proper container/bottle?
Yes
0
No ~
Sample containers intact?
Yes
0
No ~
Sufficient sample volume for indicated test?
Yes
0
No ~
All samples received within holding time?
Yes
0
No ~
Reported field parameters measured:
Field
~
Lab ~
NA
0
Container/Temp Blank temperature in compliance?
Yes
~
No 0
When thermal preservation is required, samples are compliant with a temperature between
0.1°C - 6.0°C, or when samples are received on ice the same day as collected.
Temp °C
Dry Ice
18.4
~
Water - at least one vial per sample has zero headspace?
Yes
u
No U
No VOA vials 0
Water - TOX containers have zero headspace?
Yes
~
No ~
No TOX containers 0
Water - pH acceptable upon receipt?
Yes
~
No ~
NA 0
NPDES/CWA TCN interferences checked/treated in the field?
Yes
~
No ~
NA 0
Any No responses must be detailed below or on the COC.
The samples were out of temperature compliance upon receipt. Client notified via workorder summary.
Page 23 of 23
-------
7pt\a^Teck !CuC,-= (404Ud2> J Ycy- a?,*»vu)
_ ,_A ,—_ —7 A jL^ /ti- CHAIN OF CUSTODY RECORD i „ , n, /w«. J
^TA-fc-X ' CoVyj^CT ENVIRONMENTAL PROTECTION AGENCY REGION VII ^ ^ ^ ^ 7 ^ ^ 1
ACTIVITY LEADER(Print)
RfM^MJ-hh
CONTENTS OF SHIPMENT
|DAI£-af COLI FfJJON fsTT SHEET "
! DAY MONTH YEAR 1 / 0< /
gfaM .» .1 I IUI !¦)¦¦. | | ¦¦ . ."I'1-.!.!'1* | | ' "flB iff | Ml' I llirftll
SAMPLE
NUMBER
CUBITAINER
TYPI
TYPE OF CONTAINERS
BOnLE
BOTTLE
BOTTLE
VOA SET
(2 VIALS EA)
NUMBERS OF CONTAINERS PER SAMPLE NUMBER
SAMPLED MEDIA
RECEIVING LABORATORY
REMARKS/OTHER INFORMATION
(condition of samples upon receipt,
other sample numbers, etc)
59
Cv3p Ui ^4- 6-P
Ai/Jfji\ fh rci'hf$
/
-fee
Pfb-Pih
rh% -TCuP Peqf.g^
Qyu)
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7
till
^7"
h
DESCRIPTION OF SHIPMENT
. PIECE(S) CONSISTING OF.
.ICE CHEST(S): OTHER
BOX(ES)
MODE OF SHIPMENT
COMMERCIAL CARRIER:
COURIER
X
SAMPLER CONVEYED
(SHIPPING DOCUMENT NUMBER)
PERSONNEL CUSTODY RECORD
FiELINQUISHED BY (SAMPER)
—I SEALED UNSEALED^
"date
TIME
RECEIVED BY
—\ sealed CAisealed r
REASON FOR CHANGE OF CUSTODY
P?.| "V© L A.
/U udn S« S
[relinquished by f
I | SEALED UNSEALEDf-
DATE
TIME
RECEIVED BY
"Isealed unsealed F
REASON FOR 3HANGE OF CUSTODY ^
T
1
Irelinquished by
I Isealed unsealed|
DATE
TIME
RECEIVED BY
| SEALED UNSEALEDf-
REASON FOR CHANGE OF CUSTODY
S
7-EPA-9262(Revised 5/85)
"U.S. GPO: 2002-756-917/400.'
-------
CODER
Standard analytical required at all our landfills with the exceptions shown below
State of Illinois Permit
pH
Paint Filter (Free Liquids)
Reactive Cyanide
Reactive Sulfide
Total Phenolics
Flash Point (Open Cup)
PCB's (if suspect or unknown)
F-Code Solvent Scan (if suspect or unknown)
TOX (required only for Five Oaks, Milam, Tazewell, and Cottonwood Hills for liquids
for solidification)
TCLP Organics
Benzene
Carbon Tetrachloride
Chlorobenzene
Chloroform
o-Cresol
m-Cresol
p-Cresol
1,4-Dichlorobenzene
1,2-Dichlorethane
1,1-Dichloroethene
2,4-Dinitrotoluene
Hexachlorobenzene
Hexachloro-1,3 butadiene
Hexachloroethane
Methyl Ethyl Ketone
Nitrobenzene
Pentachlorophenol
Pyridine
Tetrachloroethylene
Trichloroethylene
2.4.5-Trichlorophenol
2.4.6-Trichlorophenol
Vinyl Chloride
TCLP Metals
Arsenic
Barium
Cadmium
Chromium
Lead
Mercury
Selenium
Silver
EXCEPTIONS
Not required for UST petroleum fuel product
contamination. What is required for UST petroleum
fuel product contamination is pH, paint filter, flash
point, and TCLP lead. Not required for wood
material contaminated with creosol. For creosol
contamination, if the waste is over 10 years old and
is weathered, no analytical is required. If less than
10 years and/or not weathered, TCLP Arsenic,
TCLP Creosol, and TCLP Pentachlorophenol are
required.
;n aiiAfk-vv TCt-P Plaits
T6M5 \\abicAdt-S
-------
Links
Review your project
results through
Told Access
TestAmerica
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica St. Louis
13715 Rider Trail North
Earth City, MO 63045
Tel: (314)298-8566
TestAmerica Job ID; 160-7273-1
Client Project/Site: Strecker Forest Site, Wildwood, MO
For:
Tetra Tech EM Inc.
415 Oak Street
Kansas City, Missouri 64106
Attn: Ms. Emily Fisher
Authorized for release by:
7/7/2014 2:07:14 PM
Erika Gish, Project Manager II
(314)298-8566
erika.gish@testamericainc.com
Have a Question?
r\ Ask—
u /The
^ Expert
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
Visit us at:
www.testamericainc.com
-------
Client: TetraTech EM Inc. TestAmerica Job ID: 160-7273-1
Project/Site: Strecker Forest Site, Wildwood, MO
Table of Contents
Cover Page.............................................. 1
Table of Contents ......................................... 2
Case Narrative ........................................... 3
Chain of Custody .......................................... 5
Receipt Checklists......................................... 6
Definitions/Glossary....................................... 7
Method Summary ......................................... 8
Sample Summary ......................................... 9
Detection Summary ........................................ 10
Client Sample Results ...................................... 11
QC Sample Results ........................................ 13
QC Association Summary ................................... 18
Surrogate Summary ....................................... 19
Page 2 of 19
TestAmerica St. Louis
7/7/2014
-------
Case Narrative
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
TestAmerica Job ID: 160-7273-1
Job ID: 160-7273-1
Laboratory: TestAmerica St. Louis
Narrative
CASE NARRATIVE
Client: Tetra Tech EM Inc.
Project: Strecker Forest Site, Wildwood, MO
Report Number: 160-7273-1
With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no
problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control
limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of
the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples,
the reporting limits are adjusted relative to the dilution required.
TestAmerica St. Louis attests to the validity of the laboratory data generated by TestAmerica facilities reported herein. All analyses
performed by TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures described in the
application methods. TestAmerica's operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data
have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions
to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written
approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the
individual sections below.
All solid sample results for Chemistry analyses are reported on an "as received" basis unless otherwise indicated by the presence of a %
solids value in the method header. All soil/sediment sample results for radiochemistry analyses are based upon sample as dried and
disaggregated with the exception of tritium, carbon-14, and iodine-129 by gamma spectroscopy unless requested as wet weight by the
client."
This laboratory report is confidential and is intended for the sole use of TestAmerica and its client.
RECEIPT
The sample was received on 6/30/2014 4:51 PM; the sample arrived in good condition and properly preserved. The temperature of the
cooler at receipt was 22.4° C.
Except: The sample was received on the day of sampling. Proceed out of temperature.
SEMIVOLATILE ORGANIC COMPOUNDS (GC/MS)
Sample SFRA-128 (160-7273-1) was analyzed for Semivolatile Organic Compounds (GC/MS) in accordance with EPA SW-846 Method
8270D. The samples were prepared on 07/01/2014 and analyzed on 07/02/2014.
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
POLYCHLORINATED BIPHENYLS (PCBS)
Sample SFRA-128 (160-7273-1) was analyzed for polychlorinated biphenyls (PCBs) in accordance with EPA SW-846 Method 8082. The
samples were prepared on 07/01/2014 and analyzed on 07/02/2014.
Page 3 of 19
TestAmerica St. Louis
7/7/2014
-------
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
Case Narrative
TestAmerica Job ID: 160-7273-1
Laboratory: TestAmerica St. Louis (Continued)
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
PERCENT SOUPS
Sample SFRA-128 (160-7273-1) was analyzed for percent solids in accordance with EPA Method 160 3 MOD. The samples were analyzed
on 07/01/2014.
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Page 4 of 19
TestAmerica St. Louis
7/7/2014
-------
CHAIN OF CUSTODY RECORD
ENVIRONMENTAL PROTECTION AGENCY REGION VII
AC^ffY^DEglP^'
CONTENTS OF SHIPMENT
NAME OF SURVEYOR ACJMTY f
DAJS.F c^TI0^y
DAY MONTH YEAR
"""SHEET
(
Of
SAMPLE
NUMBER
CUBITAINER
, / TYPE OF CONTAINERS
"fetM—^*—
BOmLE
BOTTLE
BOTTLE
VOA SET
(2 VIALS EA)
NUMBERS OF CONTAINERS PER SAMPLE NUMBER
SAMPLED MEDIA
J-
t
other
RECEIVING LABORATORY
REMARKS/OTHER INFORMATION
(condition o( samples upon receipt,
other sample numbers, etc.)
0
htrtb:
'Thmi
M^ktid-
160-7273 Chain of Custody
DESCRIPTION OF SHIPMENT
. PIECE(S) CONSISTING OF.
. ICE CHEST'S). OTHER „
BOX(ES)
MODE OF SHIPMENT
-COMMERCIAL CARRIER:.
-COURIER
-SAMPLER CONVEYED
(SHIPPING DOCUMENT NUMBER)
PERSONNEL CUSTODY RECORD
F#fSAMM?f=«t'~ DATE
*<41 " 4
^SEALED' jy UNSEALED
RELINQUISHED BY
zf
l^-/f
~1 SEALED
RELINQUISHED BY
UNSEALED r
"1 SEALED
UNSEALEDf"
DATE
DATE
TIME
/^J"(
111
TIME
TIME
RECEIVED BY
SEALED
UNSEALED
RECEIVED BY
| SEALED
UNSEALED P"
RECEIVED BY
a
SEALED
UNSEALEDf~
REASON FOR CHANGE OF CUSTODY
30/^1
REASON FOR CHANGE OF CUSTODY
REASON FOR CHANGE OF CUSTODY
7-EPA-9262(Revised 5/85)
Page 5 of 19
7/7/2014
-------
Login Sample Receipt Checklist
Client: Tetra Tech EM Inc.
Job Number: 160-7273-1
Login Number: 7273
List Number: 1
Creator: Clarke, Jill C
Question
List Source: TestAmerica St. Louis
Answer
Comment
Radioactivity wasn't checked or is
-------
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
Definitions/Glossary
TestAmerica Job ID: 160-7273-1
GC/M5 Semi VOA
Qualifier Qualifier Description
J Result is iess than the RL but greater than or equal to the MDL and the concentration is an approximate value.
GC Semi VOA
Qualifier Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Abbreviation These commonly used abbreviations may or may not be present in this report.
n Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains no Free Liquid
DER Duplicate error ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision level concentration
MDA Minimum detectable activity
EDL Estimated Detection Limit
MDC Minimum detectable concentration
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative error ratio
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Page 7 of 19
TestAmerica St. Louis
7/7/2014
-------
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
Method Summary
Test Am erica Job ID: 160-7273-1
Method
Method Description
Protocol
Laboratory
8270D
Semivoiatiie Organic Compounds (GC/MS)
Poiychiorinated Biphenyis (PCBs) by Gas Chromatography
Percent Moisture
SW846
TALSL
TALSL
TALSL
8082A
SW846
Moisture
EPA
Protocol References:
EPA = US Environmental Protection Agency
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL SL = TestAmerica St. Louis, 13715 Rider Trail North, Earth City, MO 63045, TEL (314)298-8566
TestAmerica St. Louis
Page 8 of 19
7/7/2014
-------
Sample Summary
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
TestAmerica Job ID: 160-7273-1
Lab Sample ID
160-7273-1
Client Sample ID
SFRA-128
Matrix
Solid
Collected
06/30/14 15:15
Received
06/30/14 16:51
Page 9 of 19
TestAmerica St. Louis
7/7/2014
-------
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
Detection Summary
TestAmerica Job ID: 160-7273-1
Analyte
Result
Qualifier
RL
MOL
Unit
Dil Fac
D
Method
Prep Type
Bis(2-ethylhexyl) phthalate
1700
420
57
ug/Kg
1
a
8270D
Total/NA
2-Methylnaphthalene
240
J
420
42
ug/Kg
1
a
8270D
Total/NA
Naphthalene
910
420
42
ug/Kg
1
a
8270D
Total/NA
PCB-1260
19
J
41
6 9
ug/Kg
1
a
8082A
Total/NA
This Detection Summary does not include radiochemical test results.
TestAmerica St. Louis
Page 10 of 19
7/7/2014
-------
Client Sample Results
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
TestAmerica Job ID: 160-7273-1
Client Sample ID: SFRA-128
Date Collected: 06/30/14 15:15
Date Received: 06/30/14 16:51
Lab Sample ID: 160-7273-1
Matrix: Solid
Percent Solids: 79.1
Method: 8270D - Semivolatile Organic Compounds (GC/MS)
Analyte Result Qualifier
RL
MDL
Unit
D
Prepared
Analyzed
Acenaphthene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Acenaphthylene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Anthracene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Benzo[a]anthracene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Benzo[b]fluoranthene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Benzo[k]fluoranthene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Benzo[g,h,i]perylene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Benzo[a]pyrene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Bis(2-chloroethoxy)methane
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Bis(2-chloroethyl)ether
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Bis(2-ethylhexyl) phthalate
1700
420
57
ug/Kg
07/01/14
10:27
07/02/14 21
01
4-Bromophenyl phenyl ether
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Butyl benzyl phthalate
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Carbazole
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
4-Chloroaniline
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
4-Chloro-3-methylphenol
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
2-Chloronaphthalene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
2-Chlorophenol
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
4-Chlorophenyl phenyl ether
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Chrysene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Dibenz(a,h)anthracene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Dibenzofuran
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Di-n-butyl phthalate
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
1,2-Dichlorobenzene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
1,3-Dichlorobenzene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
1,4-Dichlorobenzene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
3,3'-Dichlorobenzidine
ND
2000
420
ug/Kg
07/01/14
10:27
07/02/14 21
01
2,4-Dichlorophenol
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Diethyl phthalate
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
2,4-Dimethylphenol
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Dimethyl phthalate
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
4,6-Dinitro-2-methylphenol
ND
2000
420
ug/Kg
07/01/14
10:27
07/02/14 21
01
2,4-Dinitrophenol
ND
2000
420
ug/Kg
07/01/14
10:27
07/02/14 21
01
2,4-Dinitrotoluene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
2,6-Dinitrotoluene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Di-n-octyl phthalate
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Fluoranthene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Fluorene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Hexachloro benzene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Hexachlorobutadiene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Hexachloro cy elope ntadiene
ND
2000
420
ug/Kg
07/01/14
10:27
07/02/14 21
01
Hexachloroethane
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
lndeno[1,2,3-cd]pyrene
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Isophorone
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
2-Methylnaphthalene
240
J
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
2-Methylphenol
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
3 & 4 Methylphenol
ND
830
84
ug/Kg
07/01/14
10:27
07/02/14 21
01
Naphthalene
910
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
2-Nitroaniline
ND
420
42
ug/Kg
07/01/14
10:27
07/02/14 21
01
Dil Fac
TestAmerica St. Louis
Page 11 of 19
7/7/2014
-------
Client Sample Results
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
Date Received: 08/30/14 16:51
TestAmerica Job ID: 160-7273-1
1
J
Percent Solids: 79.1
Dil Fac
Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)
Analyte Result Qualifier RL
MDL
Unit
D
Prepared
Analyzed
3-Nitroaniiine
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
4-Nitroaniiine
ND
2000
420
ug/Kg
07/01/14 10:27
07/02/14 21
01
Nitrobenzene
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
2-Nitrophenoi
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
4-Nitrophenoi
ND
2000
420
ug/Kg
07/01/14 10:27
07/02/14 21
01
N-Nitrosodiphenylamine
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
N-Nitrosodi-n-propyiamine
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
bis (2-chioroisopropyi) ether
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
Pentachiorophenoi
ND
830
420
ug/Kg
07/01/14 10:27
07/02/14 21
01
Phenanthrene
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
Phenoi
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
Pyrene
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
1,2,4-Trichiorobenzene
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
2,4,5-Trichiorophenoi
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
2,4,6-Trichiorophenoi
ND
420
42
ug/Kg
07/01/14 10:27
07/02/14 21
01
Surrogate
"/bRecovery Qualifier
Limits
Prepared
Analyzed
2-Fluorophenol (Surr)
86
53.97
07/01/14 10:27
07/02/14 21:01
2,4,6- Tribromophenol (Surr)
81
46-111
07/01/14 10:27
07/02/14 21:01
Nitrobenzene-d5 (Surr)
82
55.98
07/01/14 10:27
07/02/14 21:01
Phenol-d5 (Surr)
85
54-101
07/01/14 10:27
07/02/14 21:01
Terpheny{-d14 (Surr)
76
58 - 123
07/01/14 10:27
07/02/14 21:01
2-Fluorobiphenyl (Surr)
83
56 . 97
07/01/14 10:27
07/02/14 21:01
Method: 8082A - Polychlorinated Biphenyls (PCBs) by Gas Chromatography
Analyte Result Qualifier RL
MDL
Unit
D
Prepared
Analyzed
PCB-1016
ND
41
11
ug/Kg
07/01/14 10:51
07/02/14 11
10
PCB-1221
ND
41
11
ug/Kg
07/01/14 10:51
07/02/14 11
10
PC B-1232
ND
41
11
ug/Kg
07/01/14 10:51
07/02/14 11
10
PCB-1242
ND
41
11
ug/Kg
07/01/14 10:51
07/02/14 11
10
PC B-1248
ND
41
11
ug/Kg
07/01/14 10:51
07/02/14 11
10
PC B-1254
ND
41
6 9
ug/Kg
07/01/14 10:51
07/02/14 11
10
PCB-1280
19 J
41
6 9
ug/Kg
07/01/14 10:51
07/02/14 11
10
Surrogate
"/bRecovery Qualifier
Limits
Prepared
Analyzed
DCB Decachforobiphenyl (Surr)
77
44.150
07/01/14 10:51
07/02/14 11:10
Dil Fac
Dil Fac
Page 12 of 19
TestAmerica St. Louis
7/7/2014
-------
QC Sample Results
Client: Tetra Tech EM Inc. TestAmerica Job ID: 160-7273-1
Project/Site: Strecker Forest Site, Wildwood, MO
Method: 8270D - Semivolatile Organic Compounds (GC/MS)
Lab Sample ID: MB 160-129145/1-A
Matrix: Solid
Analysis Batch: 129448
Client Sample ID: Method Blank
Prep Type: Total/NA
Prep Batch: 129145
MB MB
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Acenaphthene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Acenaphthylene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Anthracene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Benzo[a]anthracene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Benzo[b]fluoranthene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Benzo[k]fluoranthene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Benzo[g,h,i]perylene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Benzo[a]pyrene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Bis(2-chloroethoxy)methane
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Bis(2-chloroethyl)ether
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Bis(2-ethylhexyl) phthalate
ND
330
45
ug/Kg
07/01/14 10:27
07/02/14 18:21
4-Bromophenyl phenyl ether
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Butyl benzyl phthalate
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Carbazole
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
4-Chloroaniline
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
4-Chloro-3-methylphenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
2-Chloronaphthalene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
2-Chlorophenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
4-Chlorophenyl phenyl ether
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Chrysene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Dibenz(a,h)anthracene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Dibenzofuran
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Di-n-butyl phthalate
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1,2-Dichlorobenzene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1,3-Dichlorobenzene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1,4-Dichlorobenzene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
3,3'-Dichlorobenzidine
ND
1600
330
ug/Kg
07/01/14 10:27
07/02/14 18:21
2,4-Dichlorophenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Diethyl phthalate
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
2,4-Dimethylphenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Dimethyl phthalate
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
4,6-Dinitro-2-methylphenol
ND
1600
330
ug/Kg
07/01/14 10:27
07/02/14 18:21
2,4-Dinitrophenol
ND
1600
330
ug/Kg
07/01/14 10:27
07/02/14 18:21
2,4-Dinitrotoluene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
2,6-Dinitrotoluene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Di-n-octyl phthalate
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Fluoranthene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Fluorene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Hexachloro benzene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Hexachlorobutadiene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Hexachloro cy elope ntadiene
ND
1600
330
ug/Kg
07/01/14 10:27
07/02/14 18:21
Hexachloroethane
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
lndeno[1,2,3-cd]pyrene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Isophorone
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
2-Methylnaphthalene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
2-Methylphenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
3 & 4 Methylphenol
ND
660
67
ug/Kg
07/01/14 10:27
07/02/14 18:21
Naphthalene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
Dil Fac
TestAmerica St. Louis
Page 13 of 19
7/7/2014
-------
QC Sample Results
Client: Tetra Tech EM Inc. TestAmerica Job ID: 160-7273-1
Project/Site: Strecker Forest Site, Wildwood, MO
Method: 8270D - Semivolatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: MB 160-129145/1-A
Client Sample ID: Method Blank
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 129448
Prep Batch:
129145
MB MB
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
2-Nitroaniline
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
3-Nitroaniline
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
"" 1
4-Nitroaniline
ND
1600
330
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
Nitrobenzene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
"" 1
2-Nitrophenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
4-Nitrophenol
ND
1600
330
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
N-Nitrosodiphenylamine
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
"" 1
N-Nitrosodi-n-propylamine
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
bis (2-chloroisopropyl) ether
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
Pentachlorophenol
ND
660
330
ug/Kg
07/01/14 10:27
07/02/14 18:21
"" 1
Phenanthrene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
Phenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
Pyrene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
"" 1
1,2,4-Trichlorobenzene
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
2,4,5-Trichlorophenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
1
2,4,6-Trichlorophenol
ND
330
33
ug/Kg
07/01/14 10:27
07/02/14 18:21
"" 1
MB MB
Surrogate %Recovery Qualifier Limits
Prepared
Analyzed
Dil Fac
2-Fluorophenol (Surr)
87 53-
97
07/01/14 10:27
07/02/14 18:21
1
2,4,6- Tribromophenol (Surr)
87 46-
111
07/01/14 10:27
07/02/14 18:21
1
Nitrobenzene-d5 (Surr)
86 55-
98
07/01/14 10:27
07/02/14 18:21
1
Phenol-d5 (Surr)
86 54-
101
07/01/14 10:27
07/02/14 18:21
1
Terphenyl-d14 (Surr)
79 58-
123
07/01/14 10:27
07/02/14 18:21
1
2-Fluorobiphenyl (Surr)
87 56-
97
07/01/14 10:27
07/02/14 18:21
1
Lab Sample ID: LCS 160-129145/2-A
Client Sample ID: Lab Control Sample
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 129448
Prep Batch:
129145
Spike
LCS
LCS
%Rec.
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
Acenaphthene
6670
5300
ug/Kg
79
63.95
Acenaphthylene
6670
5290
ug/Kg
79
62 .98
Anthracene
6680
5110
ug/Kg
77
63.100
Benzo[a]anthracene
6670
5350
ug/Kg
80
74-114
Benzo[b]fluoranthene
6670
5270
ug/Kg
79
68-109
Benzo[k]fluoranthene
6680
5220
ug/Kg
78
69 -111
Benzo[g,h,i]perylene
6670
5790
ug/Kg
87
67-121
Benzo[a]pyrene
6670
5230
ug/Kg
78
63-103
Bis(2-chloroethoxy)methane
6680
5330
ug/Kg
80
62-91
Bis(2-chloroethyl)ether
6670
5060
ug/Kg
76
58-92
Bis(2-ethylhexyl) phthalate
6670
5300
ug/Kg
79
63-112
4-Bromophenyl phenyl ether
6670
5320
ug/Kg
80
63-106
Butyl benzyl phthalate
6670
5260
ug/Kg
79
59 -111
Carbazole
6690
5050
ug/Kg
75
64-101
4-Chloroaniline
6670
4250
ug/Kg
64
43-70
4-Chloro-3-methylphenol
6670
5400
ug/Kg
81
58.95
2-Chloronaphthalene
6670
5400
ug/Kg
81
61 .94
2-Chlorophenol
6670
5330
ug/Kg
80
60.91
TestAmerica St. Louis
Page 14 of 19
7/7/2014
-------
QC Sample Results
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
TestAmerica Job ID: 160-7273-1
Lab Sample ID: LCS 160-129145/2-A
Matrix: Solid
Analysis Batch: 129448
Analyte
4-Chiorophenyi phenyl ether
Chrysene
Dibenz(a,h)anthracene
Dibenzofuran
Di-n-butyi phthaiate
1.2-Dichiorobenzene
1.3-Dichlorobenzene
1.4-Dichiorobenzene
3,3'-Dichiorobenzidine
2,4-Dichlorophenol
Diethyl phthaiate
2,4-Dimethyiphenoi
Dimethyl phthaiate
4,6-Dinitro-2-methyiphenoi
2,4-Dinitrophenoi
2,4-Dinitrotoiuene
2,6-Dinitrotoiuene
Di-n-octyi phthaiate
Fiuoranthene
Fiuorene
Hexachioro benzene
Hexachiorobutadiene
Hexachiorocyciopentadiene
Hexachioroethane
indeno[1,2,3-cd]pyrene
isophorone
2-Methyinaphthaiene
2-Methyiphenoi
3 & 4 Methyiphenoi
Naphthalene
2-Nitroaniline
3-Nitroaniiine
4-Nitroaniiine
Nitrobenzene
2-Nitrophenoi
4-Nitrophenoi
N-Nitrosodiphenylamine
N-Nitrosodi-n-propy famine
bis (2-chioroisopropyi) ether
Pentachlorophenol
Phenanthrene
Phenol
Pyrene
1.2.4-Trichiorobenzene
2.4.5-Trichiorophenol
2.4.6-Trichlorophenol
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 129145
Spike
LCS
LCS
%Rec.
Added
Result
Qualifier
Unit
D %Rec
Limits
6680
5370
ug/Kg
80
61 -96
6670
5270
ug/Kg
79
66 .100
6670
5630
ug/Kg
84
67 .114
6670
5280
ug/Kg
79
58-95
6670
4990
ug/Kg
75
62 -104
6670
5170
ug/Kg
78
59-90
6670
5170
ug/Kg
78
57 .88
6670
5330
ug/Kg
80
58-88
6670
5280
ug/Kg
79
50-90
6670
5310
ug/Kg
80
59-90
6670
5160
ug/Kg
77
62-97
6670
5490
ug/Kg
82
54 - 108
6670
5340
ug/Kg
80
63 .98
6670
5680
ug/Kg
85
31 .112
6670
4870
ug/Kg
73
20 . 100
6680
5480
ug/Kg
82
61 .103
6670
5150
ug/Kg
77
63.99
6670
5320
ug/Kg
80
61.111
6670
5110
ug/Kg
77
63-101
6670
5310
ug/Kg
80
62-96
6670
5240
ug/Kg
79
62 -106
6670
5510
ug/Kg
83
57 .94
6670
5340
ug/Kg
80
40-115
6670
5340
ug/Kg
80
59-93
6670
5850
ug/Kg
88
65 -120
6670
4860
ug/Kg
73
57.86
6650
5260
ug/Kg
79
59-90
6680
5420
ug/Kg
81
58 .96
6670
5930
ug/Kg
89
47.113
6670
5270
ug/Kg
79
60.90
6690
5220
ug/Kg
78
58 .105
6670
5000
ug/Kg
75
55.91
6690
5410
ug/Kg
81
57.94
6670
5330
ug/Kg
80
58-95
6680
5460
ug/Kg
82
60-93
6680
5540
ug/Kg
83
54 - 101
6670
5970
ug/Kg
90
78-133
6670
5100
ug/Kg
77
60 - 104
6670
5240
ug/Kg
79
47 . 105
6670
5260
ug/Kg
79
50 -100
6680
5260
ug/Kg
79
63-99
6670
5280
ug/Kg
79
53-89
6670
5440
ug/Kg
82
64 .102
6710
5450
ug/Kg
81
60.91
6670
5670
ug/Kg
85
59.94
6670
5490
ug/Kg
82
59 .95
TestAmerica St. Louis
Page 15 of 19 7/7/2014
-------
QC Sample Results
Client: Tetra Tech EM Inc. TestAmerica Job ID: 160-7273-1
Project/Site: Strecker Forest Site, Wildwood, MO
Lab Sample ID: LCS 160-129145/2-A
Matrix: Solid
Analysis Batch: 129448
LCS LCS
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 129145
Surrogate
%Reco very Qualifie.
r Limits
2-Fluorophenol (Surr)
81
53.97
2,4,6-Tribromophenol (Surr)
86
46.111
Nitrobenzene-d5 (Surr)
79
55 .98
Phenol-d5 (Surr)
81
54.101
Terphenyl-d14 (Surr)
78
58. 123
2-Fluorobiphenyl (Surr)
81
56 . 97
Lab Sample ID: MB 160-129153/1-A
Client Sample ID: Method Blank
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 129357
Prep Batch: 129153
MB MB
Analyte
Result Qualifier
RL
MDL Unit
D Prepared
Analyzed Dil Fac
PCB-1016
ND
33
8 7 ug/Kg
07/01/14 10:51
07/02/14 10:38 1
PCB-1221
ND
33
8 7 ug/Kg
07/01/14 10:51
07/02/14 10:38 1
PC B-1232
ND
33
8 7 ug/Kg
07/01/14 10:51
07/02/14 10:38 1
PCB-1242
ND
33
8.7 ug/Kg
07/01/14 10:51
07/02/14 10:38 1
PC B-1248
ND
33
8 7 ug/Kg
07/01/14 10:51
07/02/14 10:38 1
PC B-1254
ND
33
5 5 ug/Kg
07/01/14 10:51
07/02/14 10:38 1
PCB-1260
ND
33
5 5 ug/Kg
07/01/14 10:51
07/02/14 10:38 1
MB MB
Surrogate
"/bRecovery Qualifier
Limits
Prepared
Analyzed Dil Fac
DCB Decachforobiphenyl (Surr)
88
44.
150
07/01/14 10:51
07/02/14 10:38 1
Lab Sample ID: LCS 180-129153/2-A
Client Sample ID: Lab Control Sample
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 129357
Prep Batch: 129153
Spike
LCS
LCS
%Rec.
Analyte
Added
Result
Qualifier
Unit
D %Rec
Limits
PCB-1016
167
158
ug/Kg
95
69.128
PCB-1260
167
178
ug/Kg
107
74.133
LCS LCS
Surrogate
%Reco very Qualifier
Limits
DCB Decachforobiphenyl (Surr)
89
44.150
Lab Sample ID: 160-7273-1 MS
Client Sample ID: SFRA-128
Matrix: Solid
Prep Type: Total/NA
Analysis Batch: 129357
Prep Batch: 129153
Sample Sample
Spike
MS
MS
%Rec.
Analyte
Result Qualifier
Added
Result
Qualifier
Unit
D %Rec
Limits
PCB-1016
ND
209
174
ug/Kg
« 83
29-150
PCB-1260
19 J
209
214
ug/Kg
« 93
22-150
MS MS
Surrogate
%Reco very Qualifier
Limits
DCB Decachforobiphenyl (Surr)
85
44.150
TestAmerica St. Louis
Page 16 of 19
7/7/2014
-------
QC Sample Results
Client: Tetra Tech EM Inc. TestAmerica Job ID: 160-7273-1
Project/Site: Strecker Forest Site, Wildwood, MO
Lab Sample ID: 160-7273-1 MSD
Matrix: Solid
Analysis Batch: 129357
Client Sample ID: SFRA-128
Prep Type: Total/NA
Prep Batch: 129153
RPD
Limit
Sample
Sample
Spike
MSD
MSD
%Rec.
Analyte
Result
Qualifier
Added
Result
Qualifier Unit
D
%Rec
Limits
RPD
PCB-1016
ND
209
190
ug/Kg
a
91
29-150
9
PC B-1260
19
J
209
212
ug/Kg
a
92
22 -150
1
MSD
MSD
Surrogate
%Reco very
Qualifier
Limits
DCB Decachforobiphenyl (Surr)
81
44-150
30
30
Page 17 of 19
TestAmerica St. Louis
7/7/2014
-------
QC Association Summary
Client: Tetra Tech EM Inc. TestAmerica Job ID: 160-7273-1
Project/Site: Strecker Forest Site, Wildwood, MO
Prep Batch: 129145
Lab Sample ID
160-7273-1
LCS 160-129145/2-A
MB 160-129145/1-A
Analysis Batch: 129448
Lab Sample ID
160-7273-1
LCS 160-129145/2-A
MB 160-129145/1-A
Client Sample ID
SFRA-128
Lab Control Sample
Method Blank
Client Sample ID
SFRA-128
Lab Control Sample
Method Blank
Prep Type
Total/NA
Total/NA
Total/NA
Prep Type
Total/NA
Total/NA
Total/NA
Matrix
Solid
Solid
Solid
Matrix
Solid
Solid
Solid
Method
3550C
3550C
3550C
Method
8270D
8270D
8270D
Prep Batch
Prep Batch
129145
129145
129145
Prep Batch: 129153
Lab Sample ID
160-7273-1
160-7273-1 MS
160-7273-1 MSD
LCS 160-129153/2-A
MB 160-129153/1-A
Analysis Batch: 129357
Lab Sample ID
160-7273-1
160-7273-1 MS
160-7273-1 MSD
LCS 160-129153/2-A
MB 160-129153/1-A
Client Sample ID
SFRA-128
SFRA-128
SFRA-128
Lab Control Sample
Method Blank
Client Sample ID
SFRA-128
SFRA-128
SFRA-128
Lab Control Sample
Method Blank
Prep Type
Total/NA
Total/NA
Total/NA
Total/NA
Total/NA
Prep Type
Total/NA
Total/NA
Total/NA
Total/NA
Total/NA
Matrix
Solid
Solid
Solid
Solid
Solid
Matrix
Solid
Solid
Solid
Solid
Solid
Method
3550C
3550C
3550C
3550C
3550C
Method
8082A
8082A
8082A
8082A
8082A
Prep Batch
Prep Batch
129153
129153
129153
129153
129153
Analysis Batch: 129130
Lab Sample ID
160-7273-1
160-7273-1 DU
Client Sample ID
SFRA-128
SFRA-128
Prep Type
Total/NA
Total/NA
Matrix
Solid
Solid
Method
Moisture
Moisture
Prep Batch
Page 18 of 19
TestAmerica St. Louis
7/7/2014
-------
Client: Tetra Tech EM Inc.
Project/Site: Strecker Forest Site, Wildwood, MO
Surrogate Summary
TestAmerica Job ID: 160-7273-1
Matrix; Solid
Lab Sample ID
160-7273-1
LCS 160-129145/2-A
MB 160-129145/1-A
Prop Type: Total/NA
Client Sample ID
SFRA-128
Lab Control Sample
Method Blank
Surrogate Legend
2FP = 2-Fluorophenol (Surr)
TBP = 2,4,6-Tribromophenol (Surr)
NBZ = Nitrobenzene-d5 (Surr)
PHL = Phenol-d5 (Surr)
TPH = Terphenyl-d14 (Surr)
FBP = 2-Fluorobiphenyl (Surr)
2FP TBP
(53-97) (46-111)
86 81
81 86
87 87
Percent Surrogate Recovery (Acceptance Limits)
NBZ PHL TPH FBP
(55-98) (54-101) (58-123) (56-97)
82 85 76 83
79 81 78 81
86 86 79 87
Solid
Lab Sample ID
160-7273-1
160-7273-1 MS
160-7273-1 MSD
LCS 160-129153/2-A
MB 160-129153/1-A
Prop Type;
Client Sample ID
SFRA-128
SFRA-128
SFRA-128
Lab Control Sample
Method Blank
Surrogate Legend
DCB = DCB Decachlorobiphenyl (Surr)
DCB1
(44-150)
77
85
81
89
Percent Surrogate Recovery (Acceptance Limits)
Page 19 of 19
TestAmerica St. Louis
7/7/2014
-------
EPA Advanced KM TEQ Calculator
General Instructions |passwoid to proteet/unpioteet worksheets - "dioxln"
These instructions apply to this Advanced Kaplan-Meier (KM) Toxicity Equivalence (TEQ) calculator, which includes calculations that support a simple, quasi-
sensitivity analysis that examines the effect of various ways of handling nondetected (ND) or rejected (R-flagged) analytical data results within a sample's
congener profile. A Basic version of this calculator is also available for TEQ analyses uncomplicated by high-toxicity equivalence factor (TEF) non-detected
congeners or rejected data, therefore it is easier to learn. Also, the Basic version is structured to assist TEQ analysis and upper confidence limit (UCL)
calculations for incremental samples. Both tools are intended for use by practitioners familiar with the calculation and use of TEQ concentrations for dioxins,
furans and dioxin-like PCBs.
Please read the discussion about handling nondetected and rejected congeners on the KM
Discussion worksheet (green tab)!
Individual statisticians vary in their acceptance of Helsel's adaptation of the Kaplan-Meier (KM) technique to estimate sample TEQs when nondetected congeners are
BE present (Helsel 2009). (More details of this technique are covered in the "KM Discussion" worksheet.) Other methods to avoid simple substitution for nondetects
AWARE were suggested by peer reviewers of this calculator, and they may be incorporated into future updates of this calculator. The user is advised to seek input from a
qualified statistician if important project or site decisions are dependent upon the choice of TEQ calculation method.
Although the calculator provides estimates of specific KM TEQ results, the intent of the Advanced calculator is to provide the user with a tool for sensitivity analysis,
rather than a single "answer" for the KM TEQ. The project team should consider the full range of KM TEQ results for each sample to determine whether additional
sample collection is warranted to support decisions to be made based on the data.
Inserting
more sample
rows
The quasi-sensitivity analysis is performed by calculating the TEQ in various ways to estimate the consequences of using or not using ND or rejected (R) data values.
Data entered into the calculator should be reviewed and validated in accordance with all project quality requirements prior to performing the sensitivity analysis.
This workbook can be used to document the approach used to calculate and choose TEQ values. It records TEQs calculated using substitution methods for NDs (0,
1/2-DL, and DL) and the KM method. It also records when R data are used at face value to assess whether the rejected congeners have a significant effect on the
reported TEQ. This helps determine whether reanalysis of the sample is necessary. See discussion of ND and R data on the "KM Discussion" worksheet.
The workbook uses an automated macro that performs the calculations and provides error messages if necessary, allowing the user to correct and repeat the
process until the data are correctly entered.
The "Data Entry & Output" sheet (blue tab) is designed to accommodate up to 50 samples. It is not necessary to delete blank sample rows if the data set is
comprised of less than 50 samples. However, if desired, the user can remove unneeded rows using the "Remove Samples" macro button (see cells P3 to R5 of the
"Data Entry & Output" sheet). If more than 50 samples are required, samples can be added using the "Add Samples" macro button (see cells R3 to T5 of the "Data
Entry & Output" sheet). When run, both of these macros will prompt the user for the number of samples to be added or deleted. An error message will be provided if
too many samples are to be added or removed. At least one sample must be left in the calculator to prevent errors. A maximum of 2,000 total samples is enforced
based on limits to the size of an Excel 2007 worksheet.
"List" for TEQ To facilitate transfer of the TEQ results to another spreadsheet, each sample ID, its TEQ result, and any qualifier are reproduced in an uninterrupted list that is
output located below the data input rows in Columns Al though AM.
Note that the calculator workbook is saved in Excel 97-2003 Workbook format (*.xls). The workbook should work properly in Excel 2007 and Excel 2010, and may be
Excel format saved in Excel Macro-Enabled Workbook format (*.xlsm). In Excel 2007 and 2010 versions, the Excel Workbook format (*.xlsx) will not allow the macros in the
calculator to operate properly, and should not be used to save the workbook unless all data processing is complete.
Unprotecting
worksheets
To make some changes to worksheets, the user will need to unprotect the worksheet. Unprotecting the sheet can be performed using the
Home/Format/Protection/Unprotect Sheet option. The password is "dioxin". The protection will be re-enabled automatically each time the macro is run, so it is
not necessary for the user to manually reenable protection.
Step r
Instructions for Using the TEQ Calculator
-------
Enabling
macros
Note: Prior to their use, macros will first need to be enabled. In Excel 2007, this can be performed by selecting 'Options' on the Security Warning bar that appears
below the Excel menu bars when the workbook is opened, and selecting the 'Enable this content' button, then selecting the 'OK' button. For other versions of Excel,
consult Excel HELP to determine how to enable macros.
Once macros are enabled, follow the steps below.
Automated
data entry
Note: The "Data Import" sheet (purple tab) provides a way to enter data quickly and accurately using a flat-file format from a database, comma-separated-value file
or text file. See specific instructions on the "Data Import" worksheet. In this case, Steps 1, 2 and 3 below will be performed automatically by the automated data entry
macro, and the user may proceed to Step 4 immediately after the data has been imported.
1
Hiding
columns
Informational
data entry
Enter the sample numbers in column B of the "Data Entry & Output" sheet (blue tab). The sample numbers should be entered in the top row (Row A) of each five-
row grouping. If a sample number in any Row A is left blank, the macro will stop operation after the previous sample and will not execute for any samples after this
blank sample number. Note that this step will be performed automatically if the automated data entrv macro is used.
If data are not present for all congeners, the user may leave these columns blank and may hide columns without data. As with deleting and adding rows, the user will
have to unprotect the worksheet to hide or unhide columns. Columns should not be deleted from the worksheet. Hide columns using the "Home" menu:
Format/Visibility/Hide & Unhide/Hide Columns.
Cells D2 to J4 of the "Data Entry & Output" sheet (blue tab) allow the user to enter a project name, matrix (soil, groundwater, etc.), concentration units, person
entering the data, and the date of the analysis. It is recommended that these be entered to assist with data interpretation. The workbook should be used for a single
sampling matrix with the same concentration units. Data for other matrices should be entered into separate copies of the workbook.
2
Reorder
congeners to
match lab
report
Note: Step 2 is optional, but mav help increase the ease, speed and accuracy of data input. Note that this step will be performed automatically if the automated data
entrv macro is used.
Check the order of the chemical names to ensure they are listed in the same order as the source data reports that will be used for data input. If they are not in the
same order, change numbers in row 6 so that they correspond to the order on the project data reports. Then, click the beige button labeled "Sort Chemicals", which
will run a macro to sort the analytes into the order specified in row 6.
Note that the "Congener Abbreviations" sheet ( range ta ) contains a table listing the IUPAC names, CAS numbers, and common abbreviations. This sheet may
be useful in matching the analyte names on the data reports to those in the data entry worksheet.
After the sort is complete, check the order of the chemicals again to ensure they are listed in the correct order. This step can be repeated as many times as
necessary.
3
Entering data
Qualifier entry
location
Pasting
data
Combining
cells in the
source file
In the "Data Entry & Output" worksheet, enter the congener data into Row A for each sample, along with any analytical qualifiers that have been assigned to the
congener result. Enter the qualifier after the numeric value in the same cell. For non-detected results (including EMPC or EDL results), the detection limit should be
entered for the numeric result alona with the aualifiers as indicated below. Note that this step will be performed automatically if the automated data entrv macro is
used.
The Calculator recognizes the following qualifiers:
• J, E, or A: qualifiers used to indicate the congener result is considered estimated.
• U or ND: indicates the congener was not detected in the sample.
• Results flagged as "UJ" should be entered with a "U" qualifier.
• R: indicates the sample result for the congener result was rejected.
The numeric portion of the result should be entered first, followed by the qualifier in the same cell. The qualifiers listed above are the only ones that should be used. It
is not necessary to enter a space between the number and qualifier, but entering a space is also acceptable if the user prefers that approach.
If the user wishes to copy and paste data into the "Data Entry & Output" worksheet, the Paste Values option should be used. To paste values, select "Paste" on the
Excel ribbon, then "Paste Special", then "Paste As Values". Note that Row B will be automatically populated by the macro. The user should not make any entries into
this row.
The source file (an electronic database or spreadsheet file) from which the data are copied for pasting into the "Data Entry & Output" worksheet will usually have the
numerical value in one column and any qualifier for that data value in the next column. In the TEQ calculator, the qualifier must follow the numerical result in the
same column. To reduce manual data entry effort, use the Excel CONCATENATE function or the (ampersand) operator to consolidate the numerical and
qualifier cells of the source file into a single cell which can then be pasted directly into the calculator.
-------
EMPC or
EDL
qualifiers
Note that if values qualified as "estimated maximum possible concentration" (EMPC) or "estimated detection limit" (EDL) are present, these values should be entered
into the TEQ calculator as nondetects (using a U or ND qualifier) with the numerical EMPC or EDL value as the detection limit. This will ensure that these values are
subjected to the full sensitivity analysis as nondetects with a maximum value of the EMPC or EDL. See the EMPC discussion in the "KM Discussion" sheet for more
information.
Coeluting
analytes
If coeluting analytes are present in the sampling results, the user will need to adjust the data entry accordingly. One common coeluting pair is PCB-156 and PCB-157.
In this specific case, the two congeners have the same TEF. Therefore, the data can be entered in the column for PCB-156, and the column for PCB-157 can be left
blank. If coeluting analytes are reported which have different TEFs, it is suggested that the results be entered for the congener with the higher TEF. However, the
user can perform a sensitivity analysis by entering the sample twice, once with the coeluting analyte result entered in each column. The project team should decide
how to handle such situations.
4
Running the
Calculate
TEQ macro
Run the macro by clicking on the beige box button labeled "Calculate TEQs" (see cells R1 through T1 of the sheet "Data Entry & Output" worksheet). The macro will
calculate the toxicity equivalence concentration (TEC) for each congener (in Row C) and then transfer the TECs into the "KM intermediate auto-calc" worksheet
(red tab) to calculate the TEQ. The macro will then transfer the TEQ result back to the "Data Entry & Output" worksheet. After the macro run is completed, examine
Row D for each sample. If there are any samples with congeners that are outlined with a border, these are results for which the user will have the option to enter
substitute ("donor") values from a comparable sample (follow the instructions below). If there are no samples with congeners outlined with a border, continue with
Step 6.
• Values should not be entered for any cell that is not outlined with a border. The outlined cells will fall into two categories. One category is a ND result that is the
highest TEC in the sample. The other is a rejected result.
• Two options are available; option 2 is preferred over option 1. Option 1 should only be used if option 2 is not possible because an analytical result for that
congener from another sample cannot be defensibly substituted.
• OPTION 1:
- Enter the same value from Row B into the boxed cell in Row D.
- Enter "not possible" in column BD, Row C for the sample.
• OPTION 2:
- Examine the rest of the data set and look for samples with a congener profile and concentrations very similar to the sample in question.
- Confirm that the problem congener is detected in that sample. If so, evaluate whether a substitution of the detected value from that sample (a "donor"
sample) can defensibly be made for the U/ND. If there is more than one value that could be substituted for the U/ND, use the most conservative (i.e., highest)
value. Note that the detected value should be less than or equal to the ND value.
- If there is a value from another sample that can be substituted defensibly, enter that value into the boxed cell in Row D.
- If there are no values from other samples that can be substituted defensibly, OR the user prefers to not use substituted ("donor") values, enter the same
value from the Row B into the cell outlined with a border in Row D.
Repeat the substitution process for anv other conaeners in this sample that are outlined with a border, but DO NOT select substitute ("donor") values from more than
1 sample for each specific sample.
In column BD, Row C for the sample, enter the sample ID used for substitute ("donor") values for this sample. Note that this is not necessary if Option 1 above was
selected, since in this case, the "donor" value comes from the same sample. However, it will be required if Option 2 is used.
"Donor"
values
Repeat the congener substitution substeps of Step 4 for all samples.
5
Click on the box labeled "Calculate TEQs" (see cells R1 through T1 of the worksheet "Data Entry & Output"). This will initiate a macro that will copy the entered data
to the "KM intermediate auto-calc" worksheet and display the returned results.
6
If any error messages are displayed to the user, examine column AN to see which samples have data entry errors, and correct them (see instructions 1 through 4).
7
"Select KM
TEQ" box
The macro will automatically populate the method for calculating the KM TEQ in column AN "Select KM TEQ" in the uppermost gray cell. As a default, the method
that provides the highest KM TEQ will be selected. The user may override this selection and choose another method for calculating the KM TEQ. When the user
chooses another method for calculating the KM TEQ in column AM for a sample, the following will be automatically updated: the sample KM TEQ and the qualifiers in
columns AL and AM.
-------
Sensitivity
Analysis
Summary
Column AG provides a "Summary of the Sensitivity Analysis" for a single sample by calculating the relative percent difference (RPD) between the highest and the
lowest TEQ results for that sample. This gives a sense of the "spread" of TEQ results obtained from the different ways ND congeners can be handled. When there
are no ND congeners, all values will be exactly the same, and Column AG reports "no difference." If ND congeners are present in the sample, the highest result will
be the value obtained by substituting congener DLs for NDs, and the lowest will come from substituting zero for the NDs. If these two results are very close, the RPD may
round down to 0%. If the TEQ results are near a decision threshold and a non-zero %RPD is reported, closer examination of that sample is recommended. The equation
used to calculate the relative percent difference is RPD = ((HIGHEST TEQ - LOWEST TEQ)/AVERAGE OF HIGHEST & LOWEST TEQs) x 100, and rounded to an integer.
"Locked"
feature
There is another gray box directly below the gray KM TEQ selection box discussed above. Here the user has the option to select "Locked", or leave the cell blank
(i.e., unlocked). If "Locked" is selected, the selected KM TEQ option will not be changed when the macro is run again. This can be useful if the user wants to process
a few samples at a time, but not lose their selected options for previously processed data. Unlocking: although a blank cell cannot be selected by the drop-down box,
the "Locked" option can be removed by deleting the cell contents with the keyboard's DELETE button.
If no rejected data are present and no samples have a non-detect for the highest TEC, the macro will select "Section 1" in column AN for all samples.
If no rejected data are present and a sample does have a non-detect for the highest TEC, the macro will select either "Section 2 Treatment 1" or "Section 2
Treatment 2" in column AN, whichever is most conservative (highest KM TEQ). The other treatment should be selected if appropriate and justified (for example, if
Section 2 Treatment 1 is selected by the macro, the user may select Section 2 Treatment 2 if it is appropriate and justified).
Rejected data
If rejected data are present, the macro will select "Section 3" followed by "Treatment 1", "Treatment 2", "Treatment 3", or "Treatment 4" in column AN, whichever is
most conservative (highest KM TEQ). The most appropriate and justified TEQ should be selected, using the following considerations:
The results of the different treatments for handling "R" data should be compared to the decision threshold or used to calculate risk using appropriate risk assessment
methods.
• If the choice of treatment (from more to less conservative) significantly changes the decision outcome, sample reanalysis is advisable. To avoid repeated
generation of problematic data, ask the laboratory to take corrective action in the reanalysis.
Note 1
Note regarding TEQs in column AH:
Note that the result for the "TEQs from Substitution" in column AH (where NDs are counted as zero) should be the same as the Total TEQ value that is reported on
Contract Laboratory Program (CLP) forms (l-HR CDD-2).
Note 2
Note regarding sample qualifiers for KM TEQ results:
J-qualified
TEQ
All KM calculations include a determination of the TEC contribution to the TEQ from congener results that are qualified as non-detect, estimated or rejected.
If the contribution of these "qualified" TECs to the TEQ is greater than 50 percent, the KM TEQ result is qualified as "estimated, J". The qualifier is determined by the
macro, and is shown in a cell in the appropriate Section and Treatment(s), along with the fraction of the TEQ from "qualified" TECs. If a "J" is not needed, that cell will
be populated with "none".
Note 3
Note regarding TEFs:
Adjusting
TEFs
The TEFs used in the calculator are from the World Health Organization (WHO) 2005 report (Van den Berg 2006). If necessary, the user can change the TEF values
to earlier values, or to updated values when they become available. The TEFs can also be adjusted for additional sensitivity analysis if desired.
To update the TEFs, the user should unprotect the workbook, change the TEFs of concern and then rerun the macro.
Note 4
Note regarding minimum number of detected congeners:
Minimum
number of
congeners
There must be at least 3 detected congeners for the methodology in the KM TEQ calculator to be meaningful. If fewer than three detected congeners are present in
the results for a sample entered into the calculator, an error message will be displayed to the user. No KM TEQ calculations will be conducted for that sample. "Not
calculated" will be displayed in column AN, and a note will be displayed in column BE stating that fewer than three detected results were present. For discussion,
refer to the worksheet "KM Discussion" under "Treatment of Nondetected Congeners."
Note 5
Note regarding dioxin/furan contributions to sample TEQ:
D/F vs PCB
contributions to
total TEQ
In column AO, the "Dioxin/Furan" label on the third line for each sample refers to the percentage of TEQ contributed from dioxins and furans (the number is reported
in column AP). The remaining percentage (obtained by subtracting the D/F contribution from 100) is contributed from dioxin-like PCBs.
References
Helsel, D.R. 2009. "Summing Nondetects: Incorporating Low-Level Contaminants in Risk Assessment." Integrated Environmental Assessment and Management. Volume 6,
Number 3. Pages 361 through 366.
-------
Van den Berg, M. and others. 2006. "The 2005 World Health Organization Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-Like
Compounds." Toxicological Sciences. Volume 93, Number 2. Pages 223 through 241.
On-Line Address: http://epa-prgs.ornl.gov/chemicals/help/documents/vandenberg2006.pdf
For questions or suggestions about this Calculator, contact Deana Crumbling at USEPA, crumbling.deana@epa.gov, (703) 603-0643.
-------
EPA Advanced KM TEQ Calculator
Discussion: Calculation of Total Dioxin TEQs with Nondetect
and Rejected Congeners
Helsel's Kaplan-Meier Approach
Calculation of sums or totals for multi-constituent chemicals [e.g.; total dioxin TEQs,
total PC'Bs, total poly cyclic aromatic hydrocarbons (FAHs), etc.] has typically involved
simple substitution of zero, one-half the detection limit (DL), or the DL for left-censored
(nondetect or less-than values) congeners. Because this practice introduces bias to
estimates used in statistical calculations, however, many sources now strongly
recommend against the use of arbitrary surrogate values fornondetects (Helsel 1990,
2005a, 2005b, 2009: EPA 2006, 2009a, 2009b).
Helsel (2009) describes an approach for calculating totals using the KM product limit
estimator, which is based on the following relationship between the "mean" of the toxic
equivalence concentrations (TECs) and total TEQ for samples containing multiple
congeners:
total concentration = "mean" TEC x n (where n is the number of congeners)
Note that this "mean" TEC is an intermediate value in the calculation that has no
relationship to a mean TEQ for replicate DU samples. The KM estimator is a
nonparametric maximum likelihood estimator that has been widely used in survival and
failure analysis for more than 5 0 years (Kaplan and Meier 1958, Klein and Moeschberger
2003, Me eker and Es c ob ar 1998). Hi e KM e stim ator h as only re cently c am e into us e in
environmental assessment studies (Helsel 2005a), and is currently a default method used in
EPA's ProUCL software for calculating the 95% UCL of the mean for data with one or
more censored re suits (EPA 2009a, 2009b).
Treatment of Nondefected Congeners
For the purposes of this dioxinreassessmentUFP-QAPPtemplate,the intermediate KM
"mean" is recommended for use in calculating total dioxin TEQs, using the general
equation presented above, in all cases where a) some fraction of the congeners are
nondetect, and b) there are at least three detected congeners. Additional guidelines for
calculating the KM intermediate "mean" are provided below. If all congeners are detected,
then the intermediate "mean" calculatedbythe equationis the arithmetic average of all the
congeners' TECs.
How mam1 detected congeners are needed to calculate a TEQ?
If only one or two congeners are detected, then th ere is no statistically satisfactory method
for calculating the dioxin TEQ that adequately accounts for the uncertainty introduced by
nondetect congener results. In this case, the intermediate "mean" should be calculated as
Page 1 of 6
the congener in question, substitution of a value (straight substitution, an average of
several, or a maximum) from the other DUs may be made. Fortunately, many lab oratories
have lower detection limits for TCDD and TCDF than for the congeners with lower
TEFs, and this somewhat mitigates this problem.
the arithmetical average, where simple substitution is used fornondetects. A quasi-
sensitivity analysis approach is recommended, wherein substitution of both zero and the
DL are used to calculate lower- and upper-bound estimates for the total TEQ. Compare die
TEQs from both approaches to assess whether they have the same decision outcome.
Substitution of one-half the DL can be used to calculate a "middle-of-the-road" value,
although it should be acknowledged that the uncertainty of this estimate maybe
unacceptable for decisionmaking.
In cases where critical decisions hinge on total TEQ estimates with mostly nondetect
results, project teams are advised to consider
• consulting personnel with expertise in statistics,
• reanalyzing existing samples (if archived samples are available and meet holding
times),
• comparing with the results from nearby similar DUs and the CSM, or
• collecting additional samples.
The stepwise KM approach for calculating the total dioxin TEQ for individual samples is
described below:
Step 1. Calculate the TEC for each congener by multiplying the results for individual
congeners by their congener-specific TEF (van den Berg and others 2006). For
nondetect congeners, the reporting limit or DL should be multiplied by the TEF.
Step 2. Calculate the intermediate "mean" TEC for each sample using a KM calculator
spre a d sh eet. If all th e c ongen ers are d etecte cL th en c al cul ate th e interm edi ate
value as the arithmetic mean. If nondetects are present and at least three results
are detected, cal cul ate the KM interm edi ate using one of the options described
below. If only'one or two congeners are detected, use simple substitution and a
quasi-sensitivityanalysis approach, as discussed above.
Step 3. Calculate the total dioxin TEQ using: Total TEQ = interm edi ate "mean" TEC x
n, where n is the number of congeners in the calculation.
Helsel (2009) discusses several potential contraindications for calculation ofthe KM
mean. The first concerns cases where only a single DL is used for all nondetect
congeners. This is not expected to occur for calculation of total dioxin TEQs, since
results for individual congeners are first multiplied by congener-specific TEFs. The
second contraindication is when the maximum reported result is a nondetect, high-
toxicity (i.e., TEF close to 1) congener. This is problematic, as the KM method will
effectively ignore maximum results that are censored. Helsel (2009) suggests that the DL
be substituted in tliese cases, but that it should be acknowledged that this represents a
worst-case scenario. Another option is to compare the congener concentration and
congener profile ofthe sample with a high TEF nondetect to results from similar (per the
CSM) DUs. If the congener profiles are similar, but the other DUs have a detection for
Page 2 of 6
(3) Commercial or other statistical software. The KM model is included in many*
mainstream statistical software packages, as well as public domain (including the R
language) programs. Helsel (2005 a) discusses an approach for "flipping" data for
-------
Helsei (2009) does not discuss the minimum number of detected results required to
estimate the KM mean, but a practical minimum of three detected results is
recommended. Cases where only one or two congeners are detected are discussed above.
Lastly, Helsel (2009) recommends that for left-censored environmental data, Eiron's
method should always be used This simply requires that the minimum result always be
treated as a detected result The manner in which Efraf s method is incorporated in
calculations of the KM mean depends on the specific software or approach used. For
example, for programs that require a "flag" to distinguish between detected and nondetect
data, one only needs to use the appropriate flag for detected data to qualify the minimum
result(s).
Three options are described below for calculation of the KM mean:
(1) HelseTs KM Excel spreadsheet model (available from www.practicalstat5.com).
This spreadsheet has been built into a workbook designed specifically for calculating
the TEQ from raw data congener concentration data. Raw data are entered into one
spreadsheet, which automatically calculates the toxic equivalent concentration
(TEC) for each congener. The TECs are copied and pasted by a macro into a second
spreadsheet in the workbook that performs the KM calculation. This produces an
intermediate value (the KM "mean7") which is transferred by the macro back to the
first spreadsheet. The intermediate result is then automatically multiplied by the
number of congeners to produce the total TEQ for the sample. Detailed instructions
for using the spreadsheets are included in the Excel workbook s spreadsheets.
(2) Alternatively, EPA's ProUCL software maybe used Before estimates of the KM
intermediate "mean" TEC" can be calculated., the congener concentration, results (in
ppt) must be converted to congener TECs by multiplying each congener by its TEF.
This must be done independently before the TECs are put into ProUCL for the KM
calculation. (ProUCL cannot do the TEC calculation.) The TEC's are then entered
into ProUCL and the KM intermediate "mean" is automatically calculated for data
sets with one or more nondetect results. EPA (2009a, 2009b) should be consulted
for instructions for entering data into ProUCL, since a coding procedure must be
used in ProUCL to "tell it" which congener TECs were fromXD values. Note that
in order to use Efron's method, the minimum result should be coded as a detected
result. If intermediate "means" are required for multiple samples, then each sample
needs to be identified using a "grouping" variable (see EPA 2009a). For each
sample, the KM intermediate "mean" will need to be extracted from the ProUCL
report, and manually multiplied by the number of congeners to produce the total
TEQ result for that sample.
Page 3 of 6
Treatment ofEMPC values and qualified dara
EPA's Contract Laboratory Program Statement of Work (CLP SOW) for dioxin analysis
specifies the reporting of detected congeners as "EMPC" values ("estimated maximum
possible concentration" • when a congener peak is present at an acceptable signal-to-noise
ratio, but ion abundance criteria are not met for definitive identification of that congener.
The CLP SOW excludes these values from the calculation of TEQ. EPA Method 8290A
also specifies the reporting ofEMPC values butmakesno recommendations concerning
their use in TEQ calculations. EMPC values are generally qualified as estimated
concentrations ("J") or nondetect values ("U") during data validation in accordance with
EPA Functional Guidelines. When qualified "J", EMPC values can be applied along
.—t Trn — ri
use in commercial packages, which emphasize treatment of right-censored data
Experienced users may elect to use alternative approaches for calculation of the KM
intermediate "mean," but must use methods employing Efrori s method, and must
demonstrate that results are comparable to the intermediate "means" calculated using
Options (1) or (2) above.
Treatment of R-Quatifled Congeners
One additional component for assesang the uncertainty of estimates of the intermediate
KM "mean" and total TEQ, concerns treatment of rej ected(Unqualified) data. It is
possible to reject individual congener analytes based on ion abundance, the signal-to-
noise ratio, relative retention time, a low laboratory control sample result, gross blank
contamination, or other analyte-specific criteria. For non-dioxin individual chemicals
with multiple-sample sample sets (i.e., sufficient sample-sizes to support calculations),
rejected data are always excluded from calculations in environmental assessments.
However, for calculation of the "mean" (and total) for a set of congeners, there is concern
that exclusion of rejected data may bias estimates low or create a need for replacement
data (resampling or re analysis). The magnitude (and importance) of this bias will of
course depend on the values reported for R-qualified data and the overall dioxin
concentration in relation to decision-making thresholds, as well as the congener-specific
TEFs.
Although rejected data shouldnotbe included in final calculations of TEQ for a given
sampling or decision unit, rej ected data values (concentrations or detection limits) can be
included in KM ""mean" and total TEQ calculations early in the data evaluation process.
These TEQs can be compared to TEQs calculated with the rejected values removed. This
quasi-sensitivity approach, similar to that recommended above for nondetect values, will
assist project teams in assessing the magnitude of impacts fromrejected data and the need
for replacement data (Replacement data may require re analysis of samples at the
laboratory, with laboratory corrective actions or method refinements as needed, or the
collection of additional samples from the site). Rejected data can be further evaluated
through professional judgment, such as whether a rej ected congener may be present at a
concentration that could affect the TEQ based on historical site information or data from
surrounding decision units. For example, project teams could use the KM calculator to
further assess how high the concentration of a rejected congener would have to be to
affect the TEQ, andthen compare this estimate to concentrations for this congener that
are present in other decision units, or in comparable historical data sets.
(continued)
Page 4 of 6
Kaplan, E.L., and P. Meier. 195S. "Nonparametric Estimator from Incomplete
Observations." Journal of the American Statistical Association. Volume 53. Pages
457 through 481.
Klein, J.P., and MX. Moeschberger. 2003. Survival Analysis— Techniques for
Censored and Truncated Data. 2nd Edition. Statistics for Biology and Health,
Springer Verlag. 5 60 pages.
Meeker, W.Q.. and L.A. Escobar. 1998. Statistical Methods fear Reliability Data. Wiley
Series in Probability and Statistics. John Wiley & Sons, Inc. New York, New
"V71"} T\a fT^ac
-------
mm oiner j-quaimea congener results in ity caicuiauon anansjc assessment i. j-
qualified data are generally applied like unqualified data under EPA risk assessment
protocols)- EMPC values qualified "XT' can be treated as other nondetect values using
the KM approach described above. Given that use of EMPC values may overestimate die
TEQ and associated dioxinrisk, project teams may again elect to perform a quasi-
sensitivity analysis by calculating TEQ without the EMPC values. As for rejected data,
significant effects from EMPC values may require corrective action to improve data
quality (such as sample reanalysis).
Therefore, for congeners that are influential (high-toxicity, TEF close to 1, or high
concentration) in calculations of the intermediate "mean" and total TEQ, rejected and
qualified data may re quire further evaluation by project teams. The uncertainty of
calculating total TEQs, as can be demonstrated through sensitivity analyses, shouldbe
addressed in the uncertainty section of assessment documents, and taken into account in
decision making.
References
HelseL D.R. 1990. Less than obvious, statistical treatment of data below the detection
limit. Environmental Science and Technology. Volume 24, Number 12. Pages
1767 through 1774.
HelseL D.R. 2005 a. Nondetecte and Dam Analysis. Statistics for Censored
Environmental Data. John Wiley and Sons, Inc. Hoboken, NJ. 250pages.
HelseL D.R 2005b. "More than Obvious: Better Methods for InterpretingNondetect
Data."' Environmental Science and Technology. Volume 39, Number 20. Pages
419 A throu gh 423A.
Helsel, D.R. 2009. "Summing Nondelects Incorporating Low-Level Contaminants in
Risk Assessment." Integrated Environmental Assessment and Management.
Volume 6, Number 3. Pages 361 through 366.
Page 5 of 6
I UIA. f l.t, pd.gC3w
U.S. Environmental Protection Agency (EPA). 2006. "On the Computation of a 95%
Upper Confidence Limit of the Unknown Population Mean Based Upon Data Sets
with Below Detection Limit Observations." Singh, A., Maichle, R., and S.E. Lee.
EPA 600 R-06 022. March.
EPA. 2009a. "ProUCL Version 4.00.04 Technical Guide (Draft)." Prepared by A. Singh
and A.K. Singh. EPA 600 R-07 041. February.
EPA. 2009b. "ProUCL Version 4.00.04 User Guide (Draft)." Singh, A., R_ Maichle,
A.K. Singh, S.E. Lee, andN. Armbya. Office of Research and Development,
National Exposure Research Liberators'. EPA 600 R-07 03S. February.
Van den Berg, M. and others. (2006). "The 2005 World Health Organization
Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and
Dioxin-Like Compounds." ToxicologicalSciences. Volume 93, Number 2. Pages
223 through 241. On-Line Address: http: epa-
prgs.oml.gov chemicals help documents vandenberg2006.pdf
Page 6 of 6
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
protect/unprotect sheet password = dioxin
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
8/7/2014
SITE DATA
performing quasi-sensitivity analyses
Chemical Sort Order: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
WHO 2005 TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
Sample notes
Sample ID:
(must enter on Row A)
/
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
protect/unprotect sheet password = dioxin
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
8/7/2014
SITE DATA
performing quasi-sensitivity analyses
Chemical Sort Order: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
WHO 2005 TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
Sample notes
Sample ID:
(must enter on Row A)
/
"
N-1
~
/
/
/
/
.°r
/
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Chemical Sort Order:
Sample notes
23
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
0.0003
0.1
,9°
"
*
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Chemical Sort Order:
WHO 2005
TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
Sample ID:
(must enter on Row A)
/
<>"
/
/
t."
N-1
~
SFRA-131: Row A
10500
14.6 U
32.9 U
121 U
47.2 J
1140
16400
64.8
value to use:
Row B
10500
14.6
32.9
121
47.2
1140
16400
64.8
congener TEC:
Row C
10500
14.6
3.29
12.1
4.72
11.4
4.92
6.48
donor value to use:
Row D
donor TEC:
Row E
SFRA-132: Row A
4850
6.58 U
10.8 U
13.2 J
11.1 U
434
10800
29.7 J
value to use:
Row B
4850
6.58
10.8
13.2
11.1
434
10800
29.7
congener TEC:
Row C
4850
6.58
1.08
1.32
1.11
4.34
3.24
2.97
donor value to use:
Row D
donor TEC:
Row E
SFRA-133: Row A
5730
7.46 U
13.3 U
44 J
13.9 U
588
11500
30.7 J
value to use:
Row B
5730
7.46
13.3
44
13.9
588
11500
30.7
congener TEC:
Row C
5730
7.46
1.33
4.4
1.39
5.88
3.45
3.07
donor value to use:
Row D
donor TEC:
Row E
SFRA-134: Row A
812
6.39 U
16.8 J
40.8 J
13.1 J
1170
14100
6.73 U
value to use:
Row B
812
6.39
16.8
40.8
13.1
1170
14100
6.73
congener TEC:
Row C
812
6.39
1.68
4.08
1.31
11.7
4.23
0.673
donor value to use:
Row D
donor TEC:
Row E
SFRA-135: Row A
332
3.33 U
29.7 J
39.8 J
11 J
998
12500
4.86 U
value to use:
Row B
332
3.33
29.7
39.8
11
998
12500
4.86
congener TEC:
Row C
332
3.33
2.97
3.98
1.1
9.98
3.75
0.486
donor value to use:
Row D
donor TEC:
Row E
SFRA-136: Row A
294
4.26 J
11.7 J
26.2 J
13.2 J
697
9870
4.53 U
value to use:
Row B
294
4.26
11.7
26.2
13.2
697
9870
4.53
congener TEC:
Row C
294
4.26
1.17
2.62
1.32
6.97
2.961
0.453
donor value to use:
Row D
donor TEC:
Row E
SFRA-137: Row A
238
4.27 U
22.7 J
37.7 J
13.9 J
1110
14300
5.49 U
value to use:
Row B
238
4.27
22.7
37.7
13.9
1110
14300
5.49
congener TEC:
Row C
238
4.27
2.27
3.77
1.39
11.1
4.29
0.549
donor value to use:
Row D
donor TEC:
Row E
SFRA-138: Row A
731
3.43 U
7.46 J
10 J
11.6 U
429
21600
6.08 J
value to use:
Row B
731
3.43
7.46
10
11.6
429
21600
6.08
congener TEC:
Row C
731
3.43
0.746
1
1.16
4.29
6.48
0.608
donor value to use:
Row D
donor TEC:
Row E
Sample notes
31
32
33
34
35
36
37
38
protect/unprotect sheet password = dioxin
SITE DATA
0.03
10
0.3
11
0.1
12
0.1
13
0.1
14
0.1
15
0.01
16
0.01
J**
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Chemical Sort Order:
Sample notes
39
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
0.0003
0.1
,9°
/
<>"
.°r
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
protect/unprotect sheet password = dioxin
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
8/7/2014
SITE DATA
performing quasi-sensitivity analyses
Chemical Sort Order: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
WHO 2005 TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
Sample notes
Sample ID:
(must enter on Row A)
/
"
N-1
~
./
/
/
/
/
.°r
/
"
J
47
SFRA-147: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
335
335
335
2.14 U
2.14
2.14
4.47 U
4.47
0.447
7.03 U
7.03
0.703
4.53 U
4.53
0.453
106
106
1.06
4940
4940
1.482
3.93 J
3.93
0.393
4.24 U
4.24
0.1272
1.81 U
1.81
0.543
2.32 U
2.32
0.232
2.19 U
2.19
0.219
3.71 U
3.71
0.371
2.37 U
2.37
0.237
21.5 J
21.5
0.215
6.79 U
6.79
0.0679
48
SFRA-148: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
24400
24400
24400
32.5 U
32.5
32.5
62.6 U
62.6
6.26
139 J
139
13.9
62.1 U
62.1
6.21
1420
1420
14.2
16000
16000
4.8
163
163
16.3
22.5 U
22.5
0.675
20.8 U
20.8
6.24
39.3 J
39.3
3.93
25.1 U
25.1
2.51
34.1 U
34.1
3.41
33.2 J
33.2
3.32
491 J
491
4.91
91.5 U
91.5
0.915
49
SFRA-149: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
11300
11300
11300
14.8 U
14.8
14.8
24 U
24
2.4
25.1 J
25.1
2.51
24.2 U
24.2
2.42
562
562
5.62
8990
8990
2.697
73.6 J
73.6
7.36
13.2 U
13.2
0.396
11.7 U
11.7
3.51
16.5 U
16.5
1.65
14 U
14
1.4
25.4 U
25.4
2.54
17.9 U
17.9
1.79
160 J
160
1.6
44.4 U
44.4
0.444
50
SFRA-150: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
1770
1770
1770
1.72 J
1.72
1.72
2.4 U
2.4
0.24
21.2 J
21.2
2.12
7.93 J
7.93
0.793
411
411
4.11
7850
7850
2.355
15.8
15.8
1.58
3.83 J
3.83
0.1149
2.32 J
2.32
0.696
9.11 J
9.11
0.911
3.06 J
3.06
0.306
3.29 U
3.29
0.329
4.74 J
4.74
0.474
86.9
86.9
0.869
6.44 J
6.44
0.0644
51
SFRA-151: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
15.8
15.8
15.8
1.12 U
1.12
1.12
1.77 U
1.77
0.177
1.6 U
1.6
0.16
1.75 U
1.75
0.175
32.8 J
32.8
0.328
2290
2290
0.687
1.28 U
1.28
0.128
0.745 U
0.745
0.02235
0.645 U
0.645
0.1935
0.953 U
0.953
0.0953
0.863 U
0.863
0.0863
1.48 U
1.48
0.148
0.963 U
0.963
0.0963
4.73 J
4.73
0.0473
2.43 U
2.43
0.0243
52
SFRA-152: Row A
value to use: Row B
congener TEC: Row C
1.6 U
1.6
1.6
0.99 U
0.99
0.99
1.55 U
1.55
0.155
1.46 U
1.46
0.146
1.58 U
1.58
0.158
9.72 J
9.72
0.0972
329
329
0.0987
1.15 U
1.15
0.115
0.632 U
0.632
0.01896
0.597 U
0.597
0.1791
0.922 U
0.922
0.0922
0.875 U
0.875
0.0875
1.58 U
1.58
0.158
0.971 U
0.971
0.0971
1.6 J
1.6
0.016
2.52 U
2.52
0.0252
donor value to use: Row D
53
donor TEC: Row E
SFRA-153: Row A
value to use: Row B
congener TEC: Row C
1.62 U
1.62
1.62
1.15 U
1.15
1.15
1.49 U
1.49
0.149
1.43 U
1.43
0.143
1.54 U
1.54
0.154
6.58 J
6.58
0.0658
414
414
0.1242
1.23 U
1.23
0.123
0.569 J
0.569
0.01707
0.482 U
0.482
0.1446
0.874 U
0.874
0.0874
0.783 U
0.783
0.0783
1.38 U
1.38
0.138
0.927 U
0.927
0.0927
1.2 U
1.2
0.012
1.96 U
1.96
0.0196
donor value to use: Row D
donor TEC: Row E
54
SFRA-154: Row A
value to use: Row B
congener TEC: Row C
1.11 U
1.11
1.11
0.769 U
0.769
0.769
1.33 U
1.33
0.133
1.24 U
1.24
0.124
1.35 U
1.35
0.135
21.3 J
21.3
0.213
755
755
0.2265
1.05 U
1.05
0.105
0.533 U
0.533
0.01599
0.483 U
0.483
0.1449
0.629 U
0.629
0.0629
0.607 U
0.607
0.0607
1.04 U
1.04
0.104
0.636 U
0.636
0.0636
1.88 J
1.88
0.0188
1.67 U
1.67
0.0167
donor value to use: Row D
donor TEC: Row E
SFRA-155: Row A
value to use: Row B
0.75 U
0.75
0.857 U
0.857
1.37 U
1.37
1.29 U
1.29
1.41 U
1.41
7.01 J
7.01
161
161
1.62 J
1.62
0.843 J
0.843
0.726 U
0.726
0.837 U
0.837
0.801 U
0.801
1.3 U
1.3
0.879 U
0.879
2.42 J
2.42
1.86 U
1.86
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
/
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
/
0.1 0.1 0.1 0.01 0.0003
0.1
^ ^ ^ _
o?- oc*- ^r cs< cs< cs< cs< ($
c<$ J? J? 4$ 4$
fc*
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Sample notes
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
/
0.1 0.1 0.1 0.01 0.0003
0.1
^ ^ ^ _
o?- oc*- ^r cs< cs< cs< cs< ($
c<$ J? J? 4$ 4$
fc* N?
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
8/7/2014
Sample notes
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
/
0.1 0.1 0.1 0.01 0.0003
0.1
^ ^ ^ _
o?- oc*- ^r cs< cs< cs< cs< ($
c<$ J? J? 4$ 4$
fc* N?
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
17
WHO 2005 TEFs = 0.0003
Sample ID:
(must enter on Row A)
4**
SFRA-100: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-101: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-102: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-103: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-104: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-105: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-106: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
324 J
324
0.0972
175
175
0.0525
142 J
142
0.0426
109 J
109
0.0327
50.6 J
50.6
0.01518
8.6 J
8.6
0.00258
371 J
371
0.1113
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
0%
0%
0%
0%
1%
1%
0%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
13834.7632 13844.3582 13853.9531
3049.6780 3050.1723 3050.6666
3951.8829 3952.0059 3952.1289
3107.5925 3109.6286 3111.6647
614.94818 617.40833 619.86848
182.11118 183.083235 184.05529
13944.5723 13956.8623 13969.1523
KM Method
Sample KM
TEQ Qualifier
13840.1627 none
Select KM TEQ
Section 1
3050.0756 none
Section 1
3952.0064 none
Section 1
3108.8508 none
Section 1
615.7831 none
Section 1
182.3636 none
Section 1
13949.1495 none
Section 1
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
13840.1627
Qualified
Dioxin/Furan
3050.0756
Qualified
Dioxin/Furan
3952.0064
Qualified
Dioxin/Furan
3108.8508
Qualified
Dioxin/Furan
615.7831
Qualified
Dioxin/Furan
182.3636
Qualified
Dioxin/Furan
13949.1495
Qualified
Dioxin/Furan
none
0%
100%
none
0%
100%
none
1%
100%
none
0%
100%
none
1%
100%
none
1%
100%
none
0%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
17
0.0003
/
138
138
0.0414
44.4 J
44.4
0.01332
307 J
307
0.0921
1190
1190
0.357
511
511
0.1533
451
451
0.1353
15.2 J
15.2
0.00456
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
0%
0%
0%
0%
0%
1%
No difference
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
1039.4024 1041.7715 1044.1405
961.9863 963.0827 964.1791
14227.3521 14236.0200 14244.6878
2811.1290 2811.1290 2811.1290
1556.6234 1556.7209 1556.8184
7717.9793 7729.3701 7740.7609
180.67846 181.810435 182.94241
KM Method
Sample KM
TEQ Qualifier
1040.4226 none
962.4726 none
14230.6860 none
2811.1290 none
1556.7551 none
7721.9118 none
181.0324 none
Select KM TEQ
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
1040.4226
Qualified
Dioxin/Furan
962.4726
Qualified
Dioxin/Furan
14230.6860
Qualified
Dioxin/Furan
2811.1290
Qualified
Dioxin/Furan
1556.7551
Qualified
Dioxin/Furan
7721.9118
Qualified
Dioxin/Furan
181.0324
Qualified
Dioxin/Furan
none
1%
100%
none
0%
100%
none
0%
100%
none
1%
100%
none
1%
100%
none
0%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
15
16
17
18
19
20
21
22
17
WHO 2005 TEFs = 0.0003
Sample ID:
(must enter on Row A)
4**
SFRA-114: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-115: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-116: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-117: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-118: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-119: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-120: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-121: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
28.6 J
28.6
0.00858
54.9 J
54.9
0.01647
132
132
0.0396
474
474
0.1422
255
255
0.0765
75.4 J
75.4
0.02262
119
119
0.0357
204
204
0.0612
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
1%
1%
0%
0%
0%
0%
0%
0%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
355.4196 356.9258 358.4320
416.4425 417.9416 419.4408
868.5279 869.0529 869.5779
1198.9122 1199.2117 1199.5112
1159.3823 1160.9233 1162.4643
596.8942 598.3757 599.8572
676.7131 678.196425 679.67975
1576.802 1578.9859 1581.1698
KM Method
Sample KM
TEQ Qualifier
355.9356 none
Select KM TEQ
Section 1
416.9718 none
Section 1
868.8084 none
Section 1
1199.1615 none
Section 1
1160.0608 none
Section 1
597.4638 none
Section 1
677.3763 none
Section 1
1577.7476 none
Section 1
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
355.9356
Qualified
Dioxin/Furan
416.9718
Qualified
Dioxin/Furan
868.8084
Qualified
Dioxin/Furan
1199.1615
Qualified
Dioxin/Furan
1160.0608
Qualified
Dioxin/Furan
597.4638
Qualified
Dioxin/Furan
677.3763
Qualified
Dioxin/Furan
1577.7476
Qualified
Dioxin/Furan
none
1%
100%
none
1%
100%
none
1%
100%
none
2%
100%
none
1%
100%
none
1%
100%
none
1%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
23
24
25
26
27
28
29
30
17
WHO 2005 TEFs = 0.0003
Sample ID:
(must enter on Row A)
4**
SFRA-122: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-123: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-124: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-125: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-126: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-127: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-129: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-130: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
111 J
111
0.0333
66.7 J
66.7
0.02001
30.7 J
30.7
0.00921
385
385
0.1155
689
689
0.2067
82.6 J
82.6
0.02478
116 J
116
0.0348
91.7 J
91.7
0.02751
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
2%
1%
6%
2%
1%
5%
2%
1%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
257.3543 260.0748 262.7952
416.7350 419.4063 422.0776
69.4292 71.3963 73.3633
497.8625 501.7280 505.5935
921.7337 925.6532 929.5727
163.1588 167.4188 171.6788
384.9798 388.12445 391.2691
527.38151 529.75281 532.12411
KM Method
Sample KM
TEQ Qualifier
257.9144 none
Select KM TEQ
Section 1
417.5583 none
Section 1
69.7981 none
Section 1
500.1206 none
Section 1
924.5529 none
Section 1
164.0034 none
Section 1
386.1815 none
Section 1
528.0573 none
Section 1
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
257.9144
Qualified
Dioxin/Furan
417.5583
Qualified
Dioxin/Furan
69.7981
Qualified
Dioxin/Furan
500.1206
Qualified
Dioxin/Furan
924.5529
Qualified
Dioxin/Furan
164.0034
Qualified
Dioxin/Furan
386.1815
Qualified
Dioxin/Furan
528.0573
Qualified
Dioxin/Furan
none
3%
100%
none
1%
100%
none
7%
100%
none
3%
100%
none
2%
100%
none
6%
100%
none
2%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
17
0.0003
/
470 J
470
0.141
312 J
312
0.0936
259 J
259
0.0777
522
522
0.1566
539
539
0.1617
495
495
0.1485
839
839
0.2517
21.9 U
21.9
0.00657
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
0%
0%
0%
1%
1%
0%
2%
1%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
10531.3210 10552.7450 10574.1690
4862.7716 4870.0376 4877.3035
5748.7477 5757.2013 5765.6549
844.4706 848.5871 852.7036
362.4997 365.1517 367.8037
320.3785 320.9265 321.4745
270.4397 273.3542 276.2687
744.6715 747.461085 750.25067
KM Method
Sample KM
TEQ Qualifier
10537.0846 none
4865.2640 none
5750.9346 none
846.7147 none
364.3311 none
320.8055 none
272.4219 none
745.3559 none
Select KM TEQ
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
10537.0846
Qualified
Dioxin/Furan
4865.2640
Qualified
Dioxin/Furan
5750.9346
Qualified
Dioxin/Furan
846.7147
Qualified
Dioxin/Furan
364.3311
Qualified
Dioxin/Furan
320.8055
Qualified
Dioxin/Furan
272.4219
Qualified
Dioxin/Furan
745.3559
Qualified
Dioxin/Furan
none
0%
100%
none
0%
100%
none
0%
100%
none
3%
100%
none
5%
100%
none
5%
100%
none
7%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
17
0.0003
323 J
323
0.0969
350 J
350
0.105
214 J
214
0.0642
259 J
259
0.0777
966
966
0.2898
122 J
122
0.0366
302 J
302
0.0906
307 J
307
0.0921
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
0%
0%
0%
1%
0%
1%
1%
1%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
8394.5979 8396.4667 8398.3355
8247.1150 8254.5091 8261.9032
3468.4732 3474.9986 3481.5240
4097.5777 4108.5847 4119.5916
14957.6898 14975.7233 14993.7568
3115.2666 3125.1072 3134.9478
5712.3506 5727.8636 5743.3766
3587.8921 3602.4021 3616.9121
KM Method
Sample KM
TEQ Qualifier
8395.3001 none
8251.4853 none
3470.3622 none
4102.7274 none
14965.9222 none
3117.5158 none
5716.1866 none
3592.1679 none
Select KM TEQ
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
Section 1
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
8395.3001
Qualified
Dioxin/Furan
8251.4853
Qualified
Dioxin/Furan
3470.3622
Qualified
Dioxin/Furan
4102.7274
Qualified
Dioxin/Furan
14965.9222
Qualified
Dioxin/Furan
3117.5158
Qualified
Dioxin/Furan
5716.1866
Qualified
Dioxin/Furan
3592.1679
Qualified
Dioxin/Furan
none
0%
100%
none
1%
100%
none
1%
100%
none
1%
100%
none
0%
100%
none
1%
100%
none
1%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
47
48
49
50
51
52
53
54
17
WHO 2005 TEFs = 0.0003
Sample ID:
(must enter on Row A)
4**
SFRA-147: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-148: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-149: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-150: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-151: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-152: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-153: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-154: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-155: Row A
value to use: Row B
32.6 J
32.6
0.00978
521 J
521
0.1563
194 J
194
0.0582
164
164
0.0492
8.65 J
8.65
0.002595
6.52 U
6.52
0.001956
5.42 U
5.42
0.001626
4.04 U
4.04
0.001212
4.47 J
4.47
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
2%
0%
0%
0%
13%
180%
181%
151%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
338.1598 340.9298 343.6999
24461.5163 24490.8763 24520.2363
11319.8452 11335.5202 11351.1952
1786.1625 1786.4470 1786.7315
16.8649 18.0779 19.2909
0.2119 2.1239 4.0359
0.2071 2.1637 4.1203
0.4583
1.8813
3.3043
KM Method
Sample KM
TEQ Qualifier
339.0699 none
Select KM TEQ
Section 1
24473.4923 none
Section 1
11324.3458 none
Section 1
1786.3608 none
Section 1
17.0736
none
Section 1
1.9025
J Section 2, Treatment 1
1.9307
J Section 2, Treatment 1
1.5490
Section 2, Treatment 1
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
339.0699
Qualified
Dioxin/Furan
24473.4923
Qualified
Dioxin/Furan
11324.3458
Qualified
Dioxin/Furan
1786.3608
Qualified
Dioxin/Furan
17.0736
Qualified
Dioxin/Furan
none
2%
100%
none
0%
100%
none
0%
100%
none
0%
100%
none
15%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
1.9025
Qualified
Dioxin/Furan
1.9307
Qualified
Dioxin/Furan
1.5490
Qualified
Dioxin/Furan
J
98%
100%
J
97%
100%
J
93%
100%
-------
EPA Advanced KM
1 cw OdlUUIdlUI
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
17
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Sample notes
Chemical Sort Order:
Treatment 1
Treatment 1:
Make highest U value a D
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.0003
<
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
KM Method
U = 0 &
sum
U = 1/2 DL
& sum
U = DL &
sum
Sample KM
TEQ
Qualifier
Select KM TEQ
KM TEQ
Qualifier and Qualifier
Fractions
Qualifier and
KM TEQ Qualifier Fractions
55
congener TEC: Row C
0.001341
160%
0.3312
1.6473
2.9633
1.4645
J
Section 2, Treatment 1
1.4645 J
donor value to use: Row D
Qualified 98%
donor TEC: Row E
Dioxin/Furan 100%
SFRA-156: Row A
405
value to use: Row B
405
56
congener TEC: Row C
0.1215
4%
101.3365
103.4613
105.5861
102.8185
none
Section 1
102.8185
none
donor value to use: Row D
Qualified
12%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-157: Row A
351 J
value to use: Row B
351
57
congener TEC: Row C
0.1053
0%
7168.9053
7180.1504
7191.3955
7172.8649
none
Section 1
7172.8649
none
donor value to use: Row D
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-158: Row A
177 J
value to use: Row B
177
58
congener TEC: Row C
0.0531
0%
3381.5391
3389.1599
3396.7806
3383.5496
none
Section 1
3383.5496
none
donor value to use: Row D
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-159: Row A
208
value to use: Row B
208
59
congener TEC: Row C
0.0624
1%
288.3710
290.5019
292.6328
289.5876
none
Section 1
289.5876
none
donor value to use: Row D
Qualified
3%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-160: Row A
76.3 J
value to use: Row B
76.3
60
congener TEC: Row C
0.02289
0%
2370.3949
2373.5475
2376.7002
2371.7846
none
Section 1
2371.7846
none
donor value to use: Row D
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-161: Row A
114
value to use: Row B
114
61
congener TEC: Row C
0.0342
1%
346.8892
349.3512
351.8131
347.8776
none
Section 1
347.8776
none
donor value to use: Row D
Qualified
2%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-162: Row A
68.9 J
value to use: Row B
68.9
62
congener TEC: Row C
0.02067
0%
1120.7154
1122.1772
1123.6390
1121.3201
none
Section 1
1121.3201
none
donor value to use: Row D
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-163: Row A
8.09 J
value to use: Row B
8.09
63
congener TEC: Row C
0.002427
39%
4.8290
6.0144
7.1997
5.0892
none
Section 1
5.0892
none
donor value to use: Row D
Qualified
40%
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
17
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Sample notes
WHO 2005 TEFs = 0.0003
Sample ID:
(must enter on Row A)
4**
donor TEC: Row E
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
KM Method
Sample KM
TEQ Qualifier
Select KM TEQ
Treatment 1
Qualifier and Qualifier
KM TEQ Fractions
Dioxin/Furan
100%
Treatment 1:
Make highest U value a D
Qualifier and
KM TEQ Qualifier Fractions
value to use: Row B
64 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
65 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
66 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
67 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
68 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
69 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
70 congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
DATA LIST
List of TEQ results to copy and paste into
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
17
Sample notes
WHO 2005 TEFs =
0.0003
bummary ot
Sensitivity
<
Analysis
(relative
Sample ID:
percent
(must enter on Row A)
o
difference)
TEQs from Substitution
KM Method
U = 0 & U = 1/2 DL U = DL& Sample KM
sum & sum sum TEQ Qualifier
other spreadsheets, such as ProLICL
CAUTION: double-check entries and gray cells for
anomalous entries
Select KM TEQ
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Treatment 1
Treatment 1:
Make highest U value a D
Qualifier and Qualifier
KM TEQ Fractions
Qualifier and
KM TEQ Qualifier Fractions
Line
Sample ID
TEQ Result
Qualifier
L
ne #1
SFRA-100
13840.1627
L
ne #2
SFRA-101
3050.0756
L
ne #3
SFRA-102
3952.0064
L
ne #4
SFRA-103
3108.8508
L
ne #5
SFRA-104
615.7831
L
ne #6
SFRA-105
182.3636
L
ne #7
SFRA-106
13949.1495
L
ne #8
SFRA-107
1040.4226
L
ne #9
SFRA-108
962.4726
L
ne #10
SFRA-109
14230.6860
L
ne #11
SFRA-110
2811.1290
L
ne #12
SFRA-111
1556.7551
L
ne #13
SFRA-112
7721.9118
L
ne #14
SFRA-113
181.0324
L
ne #15
SFRA-114
355.9356
L
ne #16
SFRA-115
416.9718
L
ne #17
SFRA-116
868.8084
L
ne #18
SFRA-117
1199.1615
L
ne #19
SFRA-118
1160.0608
L
ne #20
SFRA-119
597.4638
L
ne #21
SFRA-120
677.376285
L
ne #22
SFRA-121
1577.74761
L
ne #23
SFRA-122
257.914443
L
ne #24
SFRA-123
417.558311
L
ne #25
SFRA-124
69.7980853
L
ne #26
SFRA-125
500.120635
L
ne #27
SFRA-126
924.552857
L
ne #28
SFRA-127
164.003403
L
ne #29
SFRA-129
386.181536
L
ne #30
SFRA-130
528.057292
L
ne #31
SFRA-131
10537.0846
L
ne #32
SFRA-132
4865.264
L
ne #33
SFRA-133
5750.93465
L
ne #34
SFRA-134
846.71469
L
ne #35
SFRA-135
364.3311
L
ne #36
SFRA-136
320.8055
L
ne #37
SFRA-137
272.421945
L
ne #38
SFRA-138
745.355878
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
17
Sample notes
WHO 2005 TEFs =
0.0003
bummary ot
Sensitivity
<
Analysis
(relative
Sample ID:
percent
(must enter on Row A)
o
difference)
TEQs from Substitution
U = 0 &
sum
U = 1/2 DL
& sum
U = DL &
sum
Line #39
SFRA-139
8395.30012
Line #40
SFRA-140
8251.48533
Line #41
SFRA-141
3470.36221
Line #42
SFRA-142
4102.72737
Line #43
SFRA-143
14965.9222
Line #44
SFRA-144
3117.5158
Line #45
SFRA-145
5716.18656
Line #46
SFRA-146
3592.16786
Line #47
SFRA-147
339.069907
Line #48
SFRA-148
24473.4923
Line #49
SFRA-149
11324.3458
Line #50
SFRA-150
1786.3608
Line #51
SFRA-151
17.073628
Line #52
SFRA-152
1.90251773
J
Line #53
SFRA-153
1.9306743
J
Line #54
SFRA-154
1.54899292
J
Line #55
SFRA-155
1.46451162
J
Line #56
SFRA-156
102.818532
Line #57
SFRA-157
7172.86489
Line #58
SFRA-158
3383.5496
Line #59
SFRA-159
289.587585
Line #60
SFRA-160
2371.78461
Line #61
SFRA-161
347.877589
Line #62
SFRA-162
1121.32009
Line #63
SFRA-163
5.08916156
KM Method
Sample KM
TEQ
Qualifier
Select KM TEQ
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Treatment 1
Treatment 1:
Make highest U value a D
Qualifier and Qualifier
KM TEQ Fractions
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
Substitute comparable "donor"
value for highest U
Sample notes
1
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
SFRA-100: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
2
SFRA-101: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-102: Row A
value to use: Row B
3 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
4
5
SFRA-103: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-104: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
6
SFRA-105: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
7
SFRA-106: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
8
SFRA-107: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
9
SFRA-108: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
10
SFRA-109: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
11
SFRA-110: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
12
13
SFRA-111: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-112: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
14
SFRA-113: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
15
SFRA-114: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
16
SFRA-115: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
17
SFRA-116: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
18
SFRA-117: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
19
SFRA-118: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
20
21
SFRA-119: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-120: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
22
SFRA-121: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
23
SFRA-122: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
24
SFRA-123: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
25
SFRA-124: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
26
SFRA-125: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
27
SFRA-126: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
28
29
SFRA-127: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-129: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
30
SFRA-130: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
31
SFRA-131: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
32
SFRA-132: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
33
SFRA-133: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
34
SFRA-134: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
35
SFRA-135: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
36
37
SFRA-136: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-137: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
38
SFRA-138: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
39
SFRA-139: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
40
SFRA-140: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
41
SFRA-141: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
42
SFRA-142: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
43
SFRA-143: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
44
45
SFRA-144: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-145: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
46
SFRA-146: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
47
SFRA-147: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
48
SFRA-148: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
49
SFRA-149: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
50
SFRA-150: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
51
SFRA-151: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
52
53
SFRA-152: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-153: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
1.9025 J
Qualified 98%
Dioxin/Furan 100%
1.9307 J
Qualified 97%
Dioxin/Furan 100%
54
SFRA-154: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
1.5490 J
Qualified 93%
Dioxin/Furan 100%
SFRA-155: Row A
value to use: Row B
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
55
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
1.4645 J
Qualified 98%
Dioxin/Furan 100%
56
SFRA-156: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
57
SFRA-157: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
58
SFRA-158: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
59
SFRA-159: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
60
61
SFRA-160: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-161: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
62
SFRA-162: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
63
SFRA-163: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
donor TEC: Row E
64
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
65
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
66
value to use: Row B
congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
67
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
68
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
69
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
70
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
Substitute comparable "donor"
value for highest U
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
Substitute comparable "donor"
value for highest U
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-100: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-101: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-102: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-103: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-104: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-105: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-106: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-107: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-108: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-109: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-110: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-111: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-112: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-113: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
10
11
12
13
14
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
15
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-114: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-115: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-116: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-117: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-118: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-119: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-120: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-121: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
16
17
18
19
20
21
22
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
23
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-122: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-123: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-124: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-125: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-126: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-127: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-129: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-130: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
24
25
26
27
28
29
30
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
31
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-131: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-132: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-133: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-134: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-135: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-136: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-137: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-138: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
32
33
34
35
36
37
38
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
39
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-139: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-140: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-141: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-142: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-143: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-144: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-145: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-146: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
40
41
42
43
44
45
46
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
47
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-147: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-148: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-149: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-150: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-151: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-152: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-153: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-154: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-155: Row A
value to use: Row B
48
49
50
51
52
53
54
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
55
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-156: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-157: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-158: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-159: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-160: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-161: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-162: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-163: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
56
57
58
59
60
61
62
63
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
KM TEQ
Qualifier and
Qualifier Fractions
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
KM TEQ
Qualifier and
Qualifier Fractions
Treatment 3:
Used if "donor" value is available
for R values
KM TEQ
Qualifier and
Qualifier Fractions
Treatment 4:
Used if "donor" values are
available for R and U values
KM TEQ
Qualifier and
Qualifier Fractions
Will sample
reanalysis be
requested?
Sample ID
used for
"donor"
values
donor TEC: Row E
value to use: Row B
64 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
65 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
66 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
67 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
68 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
69 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
70 congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
(Quasi) Sensitivity Analysis SECTION 3
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
(Quasi) Sensitivity Analysis SECTION 3
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
1
SFRA-100: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
2
SFRA-101: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
3
SFRA-102: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
4
5
SFRA-103: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-104: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
6
SFRA-105: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
7
SFRA-106: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
8
SFRA-107: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
9
SFRA-108: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
10
SFRA-109: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
11
SFRA-110: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
12
13
SFRA-111: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-112: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
14
SFRA-113: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
15
SFRA-114: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
16
SFRA-115: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
17
SFRA-116: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
18
SFRA-117: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
19
SFRA-118: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
20
21
SFRA-119: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-120: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
22
SFRA-121: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
23
SFRA-122: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
24
SFRA-123: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
25
SFRA-124: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
26
SFRA-125: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
27
SFRA-126: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
28
29
SFRA-127: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-129: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
30
SFRA-130: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
31
SFRA-131: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
32
SFRA-132: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
33
SFRA-133: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
34
SFRA-134: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
35
SFRA-135: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
36
37
SFRA-136: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-137: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
38
SFRA-138: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
39
SFRA-139: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
40
SFRA-140: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
41
SFRA-141: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
42
SFRA-142: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
43
SFRA-143: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
44
45
SFRA-144: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-145: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
46
SFRA-146: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
47
SFRA-147: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
48
SFRA-148: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
49
SFRA-149: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
50
SFRA-150: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
51
SFRA-151: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
52
53
SFRA-152: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-153: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
54
SFRA-154: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-155: Row A
value to use: Row B
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
55
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
56
SFRA-156: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
57
SFRA-157: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
58
SFRA-158: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
59
SFRA-159: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
60
61
SFRA-160: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-161: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
62
SFRA-162: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
63
SFRA-163: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
donor TEC: Row E
64
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
65
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
66
value to use: Row B
congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
67
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
68
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
69
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
70
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
-------
EPA Advanced KM TEQ Calculator
Automated Data Entry Worksheet
This worksheet is the data entry point for data sets that the user wants to automatically import into the "Data Entry and Output" worksheet. Users should copy data from a comma-
delimited file or other text file, Excel worksheet, or other output from a database query and paste it into the table below, then click the "Transfer Data" button above to transfer the
formatted data to the "Data Entry & Output" worksheet. The source data should be arranged in columns identical to the order of columns shown below before copying the data into the
table. Excel's "Paste Values" tool can also be used to preserve the formatting of the table.
The fields designated as "required" must be included in the data query. The fields designated as "optional" should either contain the data specified, or may be left blank. The fields in
Columns G and H will be automatically populated by the macro. The data query may include a field that specifies the order that the samples will appear in the "Data Entry & Output"
worksheet. If this field is left blank, the importation macro will sort on the sample ID instead. Note that if the sample order is omitted, the sample IDs will be sorted as text values, and
may not sort samples in numerical order as expected (for example; 1, 10, 11, 2, 3, 4, 5, 6, 7, 8, 9 instead of 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11). Note that the user should ensure that the
"Data Entry & Output" worksheet has enough samples for the sample data set being imported. See the "Instructions" worksheet for guidance on adding samples.
The "Congener Name" field in Column C is intended to be the name used by the project team in order to preserve project sample nomenclature. The "Congener Abbreviation" in
Column G is the abbreviation used by this Calculator. These fields may not be identical, but should refer to the same congeners (see the "Congener Abbreviations" worksheets for
examples of dioxin and PCB congener naming schemes).
Note that all samples to be imported into the calculator must have the same number of congeners and that only one result should be entered for each congener/sample. Otherwise, an
error message will be displayed, and the data transfer routine will be terminated. If multiple results for the same congener are present in the data set, the user should choose the
appropriate result and remove the other result(s). An example is forTCDF, which may be confirmed using a second column analysis when it is detected in the initial analysis. In this
case, the confirmation sample result should be retained, and the initial result should be discarded. If possible, selection of the correct results should be performed in the database prior
to copying the data into this worksheet.
The user should be aware that soil and water samples are often reported within the same laboratory-provided spreadsheet or database output. Since soil and water results have
different reporting units, it is best to use different Calculator files for different matrices so that water results will not be confused with soil results (or results from any other matrix). Be
sure to enter the matrix and reporting units information at the top of the "Data Entry & Output" worksheet.
After the "Transfer Data" button is pressed, data importation will begin. This importation process may take as long as approximately one minute, depending on the processing speed of
the user's computer.
Congener
Sample Order
Congener Name
CAS Number
Result
Qualifier
Abbreviation
Congener Order
Sample ID (required)
(optional)
(optional)
(required)
(required)
(required)
(auto-entered)
(auto-entered)
SFRA-100
SFRA-100
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
13800
TCDD
1
SFRA-100
SFRA-100
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
11.4
U
PeCDD
2
SFRA-100
SFRA-100
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
19.9
U
1,4-HxCDD
3
SFRA-100
SFRA-100
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
66.1
J
1,6-HxCDD
4
SFRA-100
SFRA-100
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
30.5
J
1,9-HxCDD
5
SFRA-100
SFRA-100
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
702
1,4,6-HpCDD
6
SFRA-100
SFRA-100
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
11200
OCDD
7
SFRA-100
SFRA-100
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
73.8
J
TCDF
8
SFRA-100
SFRA-100
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.33
u
1-PeCDF
9
SFRA-100
SFRA-100
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
12.8
u
4-PeCDF
10
SFRA-100
SFRA-100
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
18.8
J
1,4-HxCDF
11
SFRA-100
SFRA-100
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
11
J
1,6-HxCDF
12
SFRA-100
SFRA-100
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
15.1
J
1,9-HxCDF
13
SFRA-100
SFRA-100
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
17.7
u
4,6-HxCDF
14
SFRA-100
SFRA-100
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
250
J
1,4,6-HpCDF
15
SFRA-100
SFRA-100
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
25.6
J
1,4,9-HpCDF
16
SFRA-100
SFRA-100
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
324
J
OCDF
17
SFRA-101
SFRA-101
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3030
TCDD
1
SFRA-101
SFRA-101
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.09
J
PeCDD
2
SFRA-101
SFRA-101
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
6.3
J
1,4-HxCDD
3
SFRA-101
SFRA-101
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
33.2
J
1,6-HxCDD
4
-------
SFRA-101
SFRA-101
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
11.4
J
1,9-HxCDD
5
SFRA-101
SFRA-101
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
421
1,4,6-HpCDD
6
SFRA-101
SFRA-101
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
8830
OCDD
7
SFRA-101
SFRA-101
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
19.4
TCDF
8
SFRA-101
SFRA-101
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.65
J
1-PeCDF
9
SFRA-101
SFRA-101
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.16
J
4-PeCDF
10
SFRA-101
SFRA-101
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.63
J
1,4-HxCDF
11
SFRA-101
SFRA-101
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.46
J
1,6-HxCDF
12
SFRA-101
SFRA-101
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
2.32
U
1,9-HxCDF
13
SFRA-101
SFRA-101
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
6.83
U
4,6-HxCDF
14
SFRA-101
SFRA-101
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
121
1,4,6-HpCDF
15
SFRA-101
SFRA-101
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
7.36
U
1,4,9-HpCDF
16
SFRA-101
SFRA-101
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
175
OCDF
17
SFRA-102
SFRA-102
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3920
TCDD
1
SFRA-102
SFRA-102
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
10.7
J
PeCDD
2
SFRA-102
SFRA-102
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
10.5
J
1,4-HxCDD
3
SFRA-102
SFRA-102
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
24.8
J
1,6-HxCDD
4
SFRA-102
SFRA-102
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
16.9
J
1,9-HxCDD
5
SFRA-102
SFRA-102
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
263
1,4,6-HpCDD
6
SFRA-102
SFRA-102
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
6660
OCDD
7
SFRA-102
SFRA-102
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
22.6
J
TCDF
8
SFRA-102
SFRA-102
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.81
J
1-PeCDF
9
SFRA-102
SFRA-102
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
10.5
J
4-PeCDF
10
SFRA-102
SFRA-102
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
13.3
J
1,4-HxCDF
11
SFRA-102
SFRA-102
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
9.24
J
1,6-HxCDF
12
SFRA-102
SFRA-102
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
15.1
J
1,9-HxCDF
13
SFRA-102
SFRA-102
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
11.5
J
4,6-HxCDF
14
SFRA-102
SFRA-102
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
76.4
J
1,4,6-HpCDF
15
SFRA-102
SFRA-102
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
24.6
U
1,4,9-HpCDF
16
SFRA-102
SFRA-102
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
142
J
OCDF
17
SFRA-103
SFRA-103
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3090
TCDD
1
SFRA-103
SFRA-103
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
3.63
U
PeCDD
2
SFRA-103
SFRA-103
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
5.85
J
1,4-HxCDD
3
SFRA-103
SFRA-103
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
34.2
J
1,6-HxCDD
4
SFRA-103
SFRA-103
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
11.8
J
1,9-HxCDD
5
SFRA-103
SFRA-103
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
332
1,4,6-HpCDD
6
SFRA-103
SFRA-103
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
7750
OCDD
7
SFRA-103
SFRA-103
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
20.8
TCDF
8
SFRA-103
SFRA-103
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.56
J
1-PeCDF
9
SFRA-103
SFRA-103
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.11
J
4-PeCDF
10
SFRA-103
SFRA-103
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
7.54
J
1,4-HxCDF
11
SFRA-103
SFRA-103
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.14
J
1,6-HxCDF
12
SFRA-103
SFRA-103
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.91
U
1,9-HxCDF
13
SFRA-103
SFRA-103
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
8.22
J
4,6-HxCDF
14
SFRA-103
SFRA-103
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
115
1,4,6-HpCDF
15
SFRA-103
SFRA-103
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
5.12
U
1,4,9-HpCDF
16
SFRA-103
SFRA-103
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
109
J
OCDF
17
SFRA-104
SFRA-104
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
610
TCDD
1
SFRA-104
SFRA-104
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.16
U
PeCDD
2
SFRA-104
SFRA-104
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
4.39
U
1,4-HxCDD
3
SFRA-104
SFRA-104
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
7.87
J
1,6-HxCDD
4
SFRA-104
SFRA-104
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
4.57
U
1,9-HxCDD
5
SFRA-104
SFRA-104
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
164
1,4,6-HpCDD
6
SFRA-104
SFRA-104
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
6410
OCDD
7
SFRA-104
SFRA-104
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.77
J
TCDF
8
-------
SFRA-104
SFRA-104
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.46
U
1-PeCDF
9
SFRA-104
SFRA-104
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.53
U
4-PeCDF
10
SFRA-104
SFRA-104
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.15
U
1,4-HxCDF
11
SFRA-104
SFRA-104
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.06
J
1,6-HxCDF
12
SFRA-104
SFRA-104
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.39
U
1,9-HxCDF
13
SFRA-104
SFRA-104
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.04
U
4,6-HxCDF
14
SFRA-104
SFRA-104
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
21.3
U
1,4,6-HpCDF
15
SFRA-104
SFRA-104
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
6.05
U
1,4,9-HpCDF
16
SFRA-104
SFRA-104
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
50.6
J
OCDF
17
SFRA-105
SFRA-105
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
179
TCDD
1
SFRA-105
SFRA-105
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.02
U
PeCDD
2
SFRA-105
SFRA-105
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
1.85
U
1,4-HxCDD
3
SFRA-105
SFRA-105
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
2.43
J
1,6-HxCDD
4
SFRA-105
SFRA-105
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
2.07
J
1,9-HxCDD
5
SFRA-105
SFRA-105
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
76.3
1,4,6-HpCDD
6
SFRA-105
SFRA-105
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
5550
OCDD
7
SFRA-105
SFRA-105
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.72
J
TCDF
8
SFRA-105
SFRA-105
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.877
U
1-PeCDF
9
SFRA-105
SFRA-105
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.678
U
4-PeCDF
10
SFRA-105
SFRA-105
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.07
U
1,4-HxCDF
11
SFRA-105
SFRA-105
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.06
U
1,6-HxCDF
12
SFRA-105
SFRA-105
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.6
U
1,9-HxCDF
13
SFRA-105
SFRA-105
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
1.16
U
4,6-HxCDF
14
SFRA-105
SFRA-105
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
5.86
J
1,4,6-HpCDF
15
SFRA-105
SFRA-105
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
2.04
U
1,4,9-HpCDF
16
SFRA-105
SFRA-105
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
8.6
J
OCDF
17
SFRA-106
SFRA-106
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
13900
TCDD
1
SFRA-106
SFRA-106
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
15.9
U
PeCDD
2
SFRA-106
SFRA-106
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
17.1
U
1,4-HxCDD
3
SFRA-106
SFRA-106
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
90
J
1,6-HxCDD
4
SFRA-106
SFRA-106
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
39.2
J
1,9-HxCDD
5
SFRA-106
SFRA-106
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
929
1,4,6-HpCDD
6
SFRA-106
SFRA-106
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
13300
OCDD
7
SFRA-106
SFRA-106
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
77.9
TCDF
8
SFRA-106
SFRA-106
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
10
U
1-PeCDF
9
SFRA-106
SFRA-106
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
16.9
J
4-PeCDF
10
SFRA-106
SFRA-106
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
23.8
U
1,4-HxCDF
11
SFRA-106
SFRA-106
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
19.8
J
1,6-HxCDF
12
SFRA-106
SFRA-106
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
15.6
U
1,9-HxCDF
13
SFRA-106
SFRA-106
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
27.3
U
4,6-HxCDF
14
SFRA-106
SFRA-106
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
317
1,4,6-HpCDF
15
SFRA-106
SFRA-106
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
25.1
J
1,4,9-HpCDF
16
SFRA-106
SFRA-106
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
371
J
OCDF
17
SFRA-107
SFRA-107
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1030
TCDD
1
SFRA-107
SFRA-107
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.64
U
PeCDD
2
SFRA-107
SFRA-107
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
4.33
U
1,4-HxCDD
3
SFRA-107
SFRA-107
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
15.1
J
1,6-HxCDD
4
SFRA-107
SFRA-107
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
5.48
J
1,9-HxCDD
5
SFRA-107
SFRA-107
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
319
1,4,6-HpCDD
6
SFRA-107
SFRA-107
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
6530
OCDD
7
SFRA-107
SFRA-107
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6
J
TCDF
8
SFRA-107
SFRA-107
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.94
U
1-PeCDF
9
SFRA-107
SFRA-107
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.6
U
4-PeCDF
10
SFRA-107
SFRA-107
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5.83
J
1,4-HxCDF
11
SFRA-107
SFRA-107
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.84
U
1,6-HxCDF
12
-------
SFRA-107
SFRA-107
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.65
U
1,9-HxCDF
13
SFRA-107
SFRA-107
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
3.87
J
4,6-HxCDF
14
SFRA-107
SFRA-107
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
58.4
J
1,4,6-HpCDF
15
SFRA-107
SFRA-107
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
7.79
U
1,4,9-HpCDF
16
SFRA-107
SFRA-107
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
138
OCDF
17
SFRA-108
SFRA-108
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
956
TCDD
1
SFRA-108
SFRA-108
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.61
U
PeCDD
2
SFRA-108
SFRA-108
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
2.26
U
1,4-HxCDD
3
SFRA-108
SFRA-108
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
7.4
J
1,6-HxCDD
4
SFRA-108
SFRA-108
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
3.03
J
1,9-HxCDD
5
SFRA-108
SFRA-108
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
149
1,4,6-HpCDD
6
SFRA-108
SFRA-108
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
6320
OCDD
7
SFRA-108
SFRA-108
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.27
J
TCDF
8
SFRA-108
SFRA-108
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.7
U
1-PeCDF
9
SFRA-108
SFRA-108
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.3
J
4-PeCDF
10
SFRA-108
SFRA-108
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.6
J
1,4-HxCDF
11
SFRA-108
SFRA-108
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.14
U
1,6-HxCDF
12
SFRA-108
SFRA-108
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.8
U
1,9-HxCDF
13
SFRA-108
SFRA-108
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
1.53
J
4,6-HxCDF
14
SFRA-108
SFRA-108
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
21.4
J
1,4,6-HpCDF
15
SFRA-108
SFRA-108
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
4.18
U
1,4,9-HpCDF
16
SFRA-108
SFRA-108
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
44.4
J
OCDF
17
SFRA-109
SFRA-109
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
14200
TCDD
1
SFRA-109
SFRA-109
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
8.05
U
PeCDD
2
SFRA-109
SFRA-109
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
14.2
U
1,4-HxCDD
3
SFRA-109
SFRA-109
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
30.1
U
1,6-HxCDD
4
SFRA-109
SFRA-109
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
20.5
U
1,9-HxCDD
5
SFRA-109
SFRA-109
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
612
1,4,6-HpCDD
6
SFRA-109
SFRA-109
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
13400
OCDD
7
SFRA-109
SFRA-109
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
82.6
TCDF
8
SFRA-109
SFRA-109
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.79
U
1-PeCDF
9
SFRA-109
SFRA-109
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
10.7
J
4-PeCDF
10
SFRA-109
SFRA-109
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
19.4
J
1,4-HxCDF
11
SFRA-109
SFRA-109
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
10.8
U
1,6-HxCDF
12
SFRA-109
SFRA-109
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
13.7
U
1,9-HxCDF
13
SFRA-109
SFRA-109
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
18.3
J
4,6-HxCDF
14
SFRA-109
SFRA-109
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
188
J
1,4,6-HpCDF
15
SFRA-109
SFRA-109
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
21.2
U
1,4,9-HpCDF
16
SFRA-109
SFRA-109
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
307
J
OCDF
17
SFRA-110
SFRA-110
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2720
TCDD
1
SFRA-110
SFRA-110
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
5.57
J
PeCDD
2
SFRA-110
SFRA-110
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
7.68
J
1,4-HxCDD
3
SFRA-110
SFRA-110
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
129
1,6-HxCDD
4
SFRA-110
SFRA-110
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
27.6
J
1,9-HxCDD
5
SFRA-110
SFRA-110
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
1790
1,4,6-HpCDD
6
SFRA-110
SFRA-110
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
18600
OCDD
7
SFRA-110
SFRA-110
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
18
TCDF
8
SFRA-110
SFRA-110
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.8
J
1-PeCDF
9
SFRA-110
SFRA-110
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
21.2
J
4-PeCDF
10
SFRA-110
SFRA-110
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
145
1,4-HxCDF
11
SFRA-110
SFRA-110
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
39.3
J
1,6-HxCDF
12
SFRA-110
SFRA-110
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
52.8
1,9-HxCDF
13
SFRA-110
SFRA-110
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
52.3
4,6-HxCDF
14
SFRA-110
SFRA-110
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
655
1,4,6-HpCDF
15
SFRA-110
SFRA-110
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
144
1,4,9-HpCDF
16
-------
1£
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
11
12
11
12
12
12
12
12
12
12
12
12
12
12
12
12
12
12
li
11
li
li
li
li
li
li
li
li
li
li
li
li
li
li
li
14
14
14
SFRA-110
1,2,3,4,6,7,8,9-Octachlorodibenzofur
2,3,7,8-Tetrachlorodibenzo-p-dioxin
39001-02-0
1190
OCDF
17
SFRA-11
2,3,7,8-Pentachlorodibenzo-p-dioxi
1746-01-6
1520
TCDD
SFRA-11
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
40321-76-4
3.96
PeCDD
SFRA-11
39227-28-6
6.08
1,4-HxCDD
SFRA-11
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
46.4
1,6-HxCDD
SFRA-11
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
17.3
1,9-HxCDD
SFRA-11
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
1120
1,4,6-HpCDD
SFRA-11
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
16600
OCDD
SFRA-11
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
10.9
TCDF
SFRA-11
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.67
1-PeCDF
SFRA-11
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.92
4-PeCDF
10
SFRA-11
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
19.5
1,4-HxCDF
11
SFRA-11
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.47
1,6-HxCDF
12
SFRA-11
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
6.19
1,9-HxCDF
13
SFRA-11
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
11.9
4,6-HxCDF
14
SFRA-11
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
187
1,4,6-HpCDF
15
SFRA-11
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
19.5
U
1,4,9-HpCDF
16
SFRA-11
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
511
OCDF
17
SFRA-112
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
7690
TCDD
SFRA-112
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
8.76
U
PeCDD
SFRA-112
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
10.1
U
1,4-HxCDD
SFRA-112
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
81.4
U
1,6-HxCDD
SFRA-112
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
25.1
1,9-HxCDD
SFRA-112
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
993
1,4,6-HpCDD
SFRA-112
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
13900
OCDD
SFRA-112
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
47
TCDF
SFRA-112
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.52
U
1-PeCDF
SFRA-112
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.88
4-PeCDF
10
SFRA-112
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
21.5
1,4-HxCDF
11
SFRA-112
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
11.4
U
1,6-HxCDF
12
SFRA-112
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
14.4
U
1,9-HxCDF
13
SFRA-112
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
19.2
U
4,6-HxCDF
14
SFRA-112
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
292
1,4,6-HpCDF
15
SFRA-112
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
23.6
U
1,4,9-HpCDF
16
SFRA-112
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
451
OCDF
17
SFRA-113
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
179
TCDD
SFRA-113
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
0.948
U
PeCDD
SFRA-113
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
1.96
U
1,4-HxCDD
SFRA-113
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
2.09
U
1,6-HxCDD
SFRA-113
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
2.16
U
1,9-HxCDD
SFRA-113
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
53.7
1,4,6-HpCDD
SFRA-113
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
3010
OCDD
SFRA-113
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.73
TCDF
SFRA-113
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.495
U
1-PeCDF
SFRA-113
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.452
U
4-PeCDF
10
SFRA-113
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.12
U
1,4-HxCDF
11
SFRA-113
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.11
U
1,6-HxCDF
12
SFRA-113
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.8
U
1,9-HxCDF
13
SFRA-113
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
1.17
U
4,6-HxCDF
14
SFRA-113
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
6.09
1,4,6-HpCDF
15
SFRA-113
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
2.45
U
1,4,9-HpCDF
16
SFRA-113
2,3,4,6,7,8,9-Octachlorodibenzofur
,3,7,8-Tetrachlorodibenzo-p-dioxin
39001-02-0
15.2
OCDF
17
SFRA-114
2,3,7,8-Pentachlorodibenzo-p-dioxi
1746-01-6
352
TCDD
SFRA-114
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
40321-76-4
1.35
U
PeCDD
SFRA-114
39227-28-6
2.21
U
1,4-HxCDD
-------
114
114
114
114
114
114
114
114
114
114
114
114
114
114
115
115
115
115
115
115
115
115
115
115
115
115
115
115
115
115
115
116
116
116
116
116
116
116
116
116
116
116
116
116
116
116
116
116
117
117
117
117
117
117
117
SFRA-114
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
5.66
1,6-HxCDD
SFRA-114
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
2.69
U
1,9-HxCDD
SFRA-114
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
116
1,4,6-HpCDD
SFRA-114
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
4130
OCDD
SFRA-114
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.59
TCDF
SFRA-114
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.17
U
1-PeCDF
SFRA-114
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.06
U
4-PeCDF
10
SFRA-114
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.55
U
1,4-HxCDF
11
SFRA-114
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.41
U
1,6-HxCDF
12
SFRA-114
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
2.36
U
1,9-HxCDF
13
SFRA-114
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
1.48
U
4,6-HxCDF
14
SFRA-114
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
18.7
1,4,6-HpCDF
15
SFRA-114
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
3.93
U
1,4,9-HpCDF
16
SFRA-114
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
28.6
OCDF
17
SFRA-115
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
413
TCDD
SFRA-115
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
1.57
U
PeCDD
SFRA-115
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
2.77
U
1,4-HxCDD
SFRA-115
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
6.48
1,6-HxCDD
SFRA-115
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
3.1
1,9-HxCDD
SFRA-115
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
85.7
1,4,6-HpCDD
SFRA-115
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
1520
OCDD
SFRA-115
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
5.3
TCDF
SFRA-115
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.22
U
1-PeCDF
SFRA-115
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.14
U
4-PeCDF
10
SFRA-115
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.01
U
1,4-HxCDF
11
SFRA-115
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.4
1,6-HxCDF
12
SFRA-115
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.27
U
1,9-HxCDF
13
SFRA-115
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.08
U
4,6-HxCDF
14
SFRA-115
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
28.5
1,4,6-HpCDF
15
SFRA-115
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
3.67
U
1,4,9-HpCDF
16
SFRA-115
2,3,4,6,7,8,9-Octachlorodibenzofur
,3,7,8-Tetrachlorodibenzo-p-dioxin
39001-02-0
54.9
OCDF
17
SFRA-116
2,3,7,8-Pentachlorodibenzo-p-diox
1746-01-6
851
TCDD
SFRA-116
,2,3,4,7,8-Hexachlorodibenzo-p-dio
40321-76-4
PeCDD
SFRA-116
39227-28-6
3.48
1,4-HxCDD
SFRA-116
2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
30
1,6-HxCDD
SFRA-116
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
9.06
1,9-HxCDD
SFRA-116
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
364
1,4,6-HpCDD
SFRA-116
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
9110
OCDD
SFRA-116
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
8.24
TCDF
SFRA-116
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.51
1-PeCDF
SFRA-116
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.98
4-PeCDF
10
SFRA-116
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
7.27
U
1,4-HxCDF
11
SFRA-116
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.74
1,6-HxCDF
12
SFRA-116
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.23
U
1,9-HxCDF
13
SFRA-116
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
6.32
4,6-HxCDF
14
SFRA-116
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
93.8
1,4,6-HpCDF
15
SFRA-116
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
5.4
1,4,9-HpCDF
16
SFRA-116
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
132
OCDF
17
SFRA-117
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1160
TCDD
SFRA-117
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
4.81
PeCDD
SFRA-117
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
5.99
U
1,4-HxCDD
SFRA-117
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
57.8
1,6-HxCDD
SFRA-117
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
16.7
1,9-HxCDD
SFRA-117
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
1150
1,4,6-HpCDD
SFRA-117
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
18100
OCDD
-------
SFRA-117
SFRA-117
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
10.4
J
TCDF
8
SFRA-117
SFRA-117
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.4
J
1-PeCDF
9
SFRA-117
SFRA-117
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.1
J
4-PeCDF
10
SFRA-117
SFRA-117
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
18.8
J
1,4-HxCDF
11
SFRA-117
SFRA-117
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.95
J
1,6-HxCDF
12
SFRA-117
SFRA-117
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
5.96
J
1,9-HxCDF
13
SFRA-117
SFRA-117
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
12.4
J
4,6-HxCDF
14
SFRA-117
SFRA-117
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
224
1,4,6-HpCDF
15
SFRA-117
SFRA-117
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
18.7
J
1,4,9-HpCDF
16
SFRA-117
SFRA-117
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
474
OCDF
17
SFRA-118
SFRA-118
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1140
TCDD
1
SFRA-118
SFRA-118
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.33
U
PeCDD
2
SFRA-118
SFRA-118
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
4.14
U
1,4-HxCDD
3
SFRA-118
SFRA-118
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
27.9
J
1,6-HxCDD
4
SFRA-118
SFRA-118
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
8.56
J
1,9-HxCDD
5
SFRA-118
SFRA-118
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
628
1,4,6-HpCDD
6
SFRA-118
SFRA-118
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
15900
OCDD
7
SFRA-118
SFRA-118
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
8.3
J
TCDF
8
SFRA-118
SFRA-118
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.26
J
1-PeCDF
9
SFRA-118
SFRA-118
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.02
J
4-PeCDF
10
SFRA-118
SFRA-118
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
8.51
J
1,4-HxCDF
11
SFRA-118
SFRA-118
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.78
J
1,6-HxCDF
12
SFRA-118
SFRA-118
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.38
U
1,9-HxCDF
13
SFRA-118
SFRA-118
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
5.04
J
4,6-HxCDF
14
SFRA-118
SFRA-118
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
101
1,4,6-HpCDF
15
SFRA-118
SFRA-118
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
6.3
J
1,4,9-HpCDF
16
SFRA-118
SFRA-118
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
255
OCDF
17
SFRA-119
SFRA-119
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
590
TCDD
1
SFRA-119
SFRA-119
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.83
U
PeCDD
2
SFRA-119
SFRA-119
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
2.76
U
1,4-HxCDD
3
SFRA-119
SFRA-119
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
10.2
J
1,6-HxCDD
4
SFRA-119
SFRA-119
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
3.79
J
1,9-HxCDD
5
SFRA-119
SFRA-119
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
201
1,4,6-HpCDD
6
SFRA-119
SFRA-119
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
6610
OCDD
7
SFRA-119
SFRA-119
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
5.25
J
TCDF
8
SFRA-119
SFRA-119
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.1
U
1-PeCDF
9
SFRA-119
SFRA-119
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.17
U
4-PeCDF
10
SFRA-119
SFRA-119
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.41
J
1,4-HxCDF
11
SFRA-119
SFRA-119
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.26
J
1,6-HxCDF
12
SFRA-119
SFRA-119
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
2.68
U
1,9-HxCDF
13
SFRA-119
SFRA-119
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.05
U
4,6-HxCDF
14
SFRA-119
SFRA-119
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
34.2
J
1,4,6-HpCDF
15
SFRA-119
SFRA-119
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
4.56
J
1,4,9-HpCDF
16
SFRA-119
SFRA-119
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
75.4
J
OCDF
17
SFRA-120
SFRA-120
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
669
TCDD
1
SFRA-120
SFRA-120
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.8
U
PeCDD
2
SFRA-120
SFRA-120
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
2.34
U
1,4-HxCDD
3
SFRA-120
SFRA-120
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
12.8
J
1,6-HxCDD
4
SFRA-120
SFRA-120
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
4.2
J
1,9-HxCDD
5
SFRA-120
SFRA-120
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
270
1,4,6-HpCDD
6
SFRA-120
SFRA-120
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
5710
OCDD
7
SFRA-120
SFRA-120
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
4.61
J
TCDF
8
SFRA-120
SFRA-120
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.955
U
1-PeCDF
9
SFRA-120
SFRA-120
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.942
J
4-PeCDF
10
SFRA-120
SFRA-120
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.86
U
1,4-HxCDF
11
-------
SFRA-120
SFRA-120
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.22
U
1,6-HxCDF
12
SFRA-120
SFRA-120
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
2.96
U
1,9-HxCDF
13
SFRA-120
SFRA-120
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.96
J
4,6-HxCDF
14
SFRA-120
SFRA-120
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
47.9
1,4,6-HpCDF
15
SFRA-120
SFRA-120
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
4.58
J
1,4,9-HpCDF
16
SFRA-120
SFRA-120
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
119
OCDF
17
SFRA-121
SFRA-121
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1560
TCDD
1
SFRA-121
SFRA-121
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.78
U
PeCDD
2
SFRA-121
SFRA-121
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
4.24
U
1,4-HxCDD
3
SFRA-121
SFRA-121
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
35.9
J
1,6-HxCDD
4
SFRA-121
SFRA-121
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
10.5
J
1,9-HxCDD
5
SFRA-121
SFRA-121
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
493
1,4,6-HpCDD
6
SFRA-121
SFRA-121
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
10100
OCDD
7
SFRA-121
SFRA-121
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
9.46
J
TCDF
8
SFRA-121
SFRA-121
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.66
U
1-PeCDF
9
SFRA-121
SFRA-121
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.62
U
4-PeCDF
10
SFRA-121
SFRA-121
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
7.68
J
1,4-HxCDF
11
SFRA-121
SFRA-121
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.1
J
1,6-HxCDF
12
SFRA-121
SFRA-121
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.28
U
1,9-HxCDF
13
SFRA-121
SFRA-121
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
6.9
J
4,6-HxCDF
14
SFRA-121
SFRA-121
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
114
1,4,6-HpCDF
15
SFRA-121
SFRA-121
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
8.68
J
1,4,9-HpCDF
16
SFRA-121
SFRA-121
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
204
OCDF
17
SFRA-122
SFRA-122
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
248
TCDD
1
SFRA-122
SFRA-122
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.53
U
PeCDD
2
SFRA-122
SFRA-122
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
3.98
U
1,4-HxCDD
3
SFRA-122
SFRA-122
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
10.8
J
1,6-HxCDD
4
SFRA-122
SFRA-122
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
4.4
U
1,9-HxCDD
5
SFRA-122
SFRA-122
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
290
1,4,6-HpCDD
6
SFRA-122
SFRA-122
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
16400
OCDD
7
SFRA-122
SFRA-122
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.3
U
TCDF
8
SFRA-122
SFRA-122
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.9
U
1-PeCDF
9
SFRA-122
SFRA-122
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.64
U
4-PeCDF
10
SFRA-122
SFRA-122
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.77
U
1,4-HxCDF
11
SFRA-122
SFRA-122
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.06
U
1,6-HxCDF
12
SFRA-122
SFRA-122
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.2
U
1,9-HxCDF
13
SFRA-122
SFRA-122
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.24
U
4,6-HxCDF
14
SFRA-122
SFRA-122
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
42.1
J
1,4,6-HpCDF
15
SFRA-122
SFRA-122
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
6.69
U
1,4,9-HpCDF
16
SFRA-122
SFRA-122
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
111
J
OCDF
17
SFRA-123
SFRA-123
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
411
TCDD
1
SFRA-123
SFRA-123
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.35
U
PeCDD
2
SFRA-123
SFRA-123
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
5.13
U
1,4-HxCDD
3
SFRA-123
SFRA-123
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
6.42
J
1,6-HxCDD
4
SFRA-123
SFRA-123
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
5.33
U
1,9-HxCDD
5
SFRA-123
SFRA-123
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
155
1,4,6-HpCDD
6
SFRA-123
SFRA-123
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
11000
OCDD
7
SFRA-123
SFRA-123
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.44
U
TCDF
8
SFRA-123
SFRA-123
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.61
U
1-PeCDF
9
SFRA-123
SFRA-123
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.43
U
4-PeCDF
10
SFRA-123
SFRA-123
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.35
U
1,4-HxCDF
11
SFRA-123
SFRA-123
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.42
U
1,6-HxCDF
12
SFRA-123
SFRA-123
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.58
U
1,9-HxCDF
13
SFRA-123
SFRA-123
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.51
u
4,6-HxCDF
14
SFRA-123
SFRA-123
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
22.3
J
1,4,6-HpCDF
15
-------
SFRA-123
SFRA-123
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
3.93
U
1,4,9-HpCDF
16
SFRA-123
SFRA-123
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
66.7
J
OCDF
17
SFRA-124
SFRA-124
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
67.4
TCDD
1
SFRA-124
SFRA-124
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.79
U
PeCDD
2
SFRA-124
SFRA-124
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
3.22
U
1,4-HxCDD
3
SFRA-124
SFRA-124
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
7.58
J
1,6-HxCDD
4
SFRA-124
SFRA-124
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
3.55
U
1,9-HxCDD
5
SFRA-124
SFRA-124
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
57
1,4,6-HpCDD
6
SFRA-124
SFRA-124
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
1430
OCDD
7
SFRA-124
SFRA-124
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.44
U
TCDF
8
SFRA-124
SFRA-124
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.3
U
1-PeCDF
9
SFRA-124
SFRA-124
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.15
U
4-PeCDF
10
SFRA-124
SFRA-124
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.76
U
1,4-HxCDF
11
SFRA-124
SFRA-124
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.73
U
1,6-HxCDF
12
SFRA-124
SFRA-124
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
2.64
U
1,9-HxCDF
13
SFRA-124
SFRA-124
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
1.87
U
4,6-HxCDF
14
SFRA-124
SFRA-124
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
26.3
J
1,4,6-HpCDF
15
SFRA-124
SFRA-124
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
3.91
U
1,4,9-HpCDF
16
SFRA-124
SFRA-124
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
30.7
J
OCDF
17
SFRA-125
SFRA-125
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
476
TCDD
1
SFRA-125
SFRA-125
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
4.43
U
PeCDD
2
SFRA-125
SFRA-125
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
12.5
J
1,4-HxCDD
3
SFRA-125
SFRA-125
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
43.1
J
1,6-HxCDD
4
SFRA-125
SFRA-125
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
15.3
J
1,9-HxCDD
5
SFRA-125
SFRA-125
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
772
1,4,6-HpCDD
6
SFRA-125
SFRA-125
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
11100
OCDD
7
SFRA-125
SFRA-125
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
7.33
U
TCDF
8
SFRA-125
SFRA-125
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
8.3
J
1-PeCDF
9
SFRA-125
SFRA-125
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.33
U
4-PeCDF
10
SFRA-125
SFRA-125
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
12.2
J
1,4-HxCDF
11
SFRA-125
SFRA-125
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.38
U
1,6-HxCDF
12
SFRA-125
SFRA-125
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
7.31
U
1,9-HxCDF
13
SFRA-125
SFRA-125
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
6.91
J
4,6-HxCDF
14
SFRA-125
SFRA-125
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
134
1,4,6-HpCDF
15
SFRA-125
SFRA-125
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
10.7
J
1,4,9-HpCDF
16
SFRA-125
SFRA-125
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
385
OCDF
17
SFRA-126
SFRA-126
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
897
TCDD
1
SFRA-126
SFRA-126
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
3.6
U
PeCDD
2
SFRA-126
SFRA-126
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
12.1
J
1,4-HxCDD
3
SFRA-126
SFRA-126
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
35.7
J
1,6-HxCDD
4
SFRA-126
SFRA-126
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
11.2
J
1,9-HxCDD
5
SFRA-126
SFRA-126
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
870
1,4,6-HpCDD
6
SFRA-126
SFRA-126
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
10900
OCDD
7
SFRA-126
SFRA-126
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
7.91
U
TCDF
8
SFRA-126
SFRA-126
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
16.6
J
1-PeCDF
9
SFRA-126
SFRA-126
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.85
U
4-PeCDF
10
SFRA-126
SFRA-126
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
21.6
J
1,4-HxCDF
11
SFRA-126
SFRA-126
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
8.28
U
1,6-HxCDF
12
SFRA-126
SFRA-126
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
8.65
U
1,9-HxCDF
13
SFRA-126
SFRA-126
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
8.77
J
4,6-HxCDF
14
SFRA-126
SFRA-126
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
284
1,4,6-HpCDF
15
SFRA-126
SFRA-126
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
28.2
J
1,4,9-HpCDF
16
SFRA-126
SFRA-126
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
689
OCDF
17
SFRA-127
SFRA-127
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
158
TCDD
1
SFRA-127
SFRA-127
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
3.99
U
PeCDD
2
-------
SFRA-127
SFRA-127
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
6.56
U
1,4-HxCDD
3
SFRA-127
SFRA-127
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
11.6
J
1,6-HxCDD
4
SFRA-127
SFRA-127
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
6.97
U
1,9-HxCDD
5
SFRA-127
SFRA-127
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
149
1,4,6-HpCDD
6
SFRA-127
SFRA-127
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
6720
OCDD
7
SFRA-127
SFRA-127
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
4.32
U
TCDF
8
SFRA-127
SFRA-127
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.7
U
1-PeCDF
9
SFRA-127
SFRA-127
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.39
U
4-PeCDF
10
SFRA-127
SFRA-127
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.91
U
1,4-HxCDF
11
SFRA-127
SFRA-127
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.99
U
1,6-HxCDF
12
SFRA-127
SFRA-127
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
5.99
U
1,9-HxCDF
13
SFRA-127
SFRA-127
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
3.96
U
4,6-HxCDF
14
SFRA-127
SFRA-127
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
46.8
J
1,4,6-HpCDF
15
SFRA-127
SFRA-127
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
16.2
U
1,4,9-HpCDF
16
SFRA-127
SFRA-127
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
82.6
J
OCDF
17
SFRA-129
SFRA-129
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
375
TCDD
1
SFRA-129
SFRA-129
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.86
U
PeCDD
2
SFRA-129
SFRA-129
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
7.02
U
1,4-HxCDD
3
SFRA-129
SFRA-129
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
13.9
JQ
1,6-HxCDD
4
SFRA-129
SFRA-129
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
9.12
U
1,9-HxCDD
5
SFRA-129
SFRA-129
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
249
1,4,6-HpCDD
6
SFRA-129
SFRA-129
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
17200
OCDD
7
SFRA-129
SFRA-129
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.62
U
TCDF
8
SFRA-129
SFRA-129
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.89
U
1-PeCDF
9
SFRA-129
SFRA-129
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.55
U
4-PeCDF
10
SFRA-129
SFRA-129
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.97
J
1,4-HxCDF
11
SFRA-129
SFRA-129
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.12
U
1,6-HxCDF
12
SFRA-129
SFRA-129
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.48
U
1,9-HxCDF
13
SFRA-129
SFRA-129
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.59
J
4,6-HxCDF
14
SFRA-129
SFRA-129
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
34.9
J
1,4,6-HpCDF
15
SFRA-129
SFRA-129
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
4.16
U
1,4,9-HpCDF
16
SFRA-129
SFRA-129
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
116
J
OCDF
17
SFRA-130
SFRA-130
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
514
TCDD
1
SFRA-130
SFRA-130
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.53
U
PeCDD
2
SFRA-130
SFRA-130
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
4.57
U
1,4-HxCDD
3
SFRA-130
SFRA-130
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
13.3
JQ
1,6-HxCDD
4
SFRA-130
SFRA-130
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
5.77
U
1,9-HxCDD
5
SFRA-130
SFRA-130
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
277
1,4,6-HpCDD
6
SFRA-130
SFRA-130
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
26900
OCDD
7
SFRA-130
SFRA-130
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.1
J
TCDF
8
SFRA-130
SFRA-130
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.6
U
1-PeCDF
9
SFRA-130
SFRA-130
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.65
J
4-PeCDF
10
SFRA-130
SFRA-130
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.42
U
1,4-HxCDF
11
SFRA-130
SFRA-130
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.28
U
1,6-HxCDF
12
SFRA-130
SFRA-130
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.62
U
1,9-HxCDF
13
SFRA-130
SFRA-130
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.62
U
4,6-HxCDF
14
SFRA-130
SFRA-130
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
37.9
J
1,4,6-HpCDF
15
SFRA-130
SFRA-130
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
3.66
U
1,4,9-HpCDF
16
SFRA-130
SFRA-130
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
91.7
J
OCDF
17
SFRA-131
SFRA-131
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
10500
TCDD
1
SFRA-131
SFRA-131
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
14.6
U
PeCDD
2
SFRA-131
SFRA-131
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
32.9
U
1,4-HxCDD
3
SFRA-131
SFRA-131
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
121
U
1,6-HxCDD
4
SFRA-131
SFRA-131
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
47.2
J
1,9-HxCDD
5
SFRA-131
SFRA-131
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
1140
1,4,6-HpCDD
6
-------
SFRA-131
SFRA-131
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
16400
OCDD
7
SFRA-131
SFRA-131
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
64.8
TCDF
8
SFRA-131
SFRA-131
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
12.9
U
1-PeCDF
9
SFRA-131
SFRA-131
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
10.8
U
4-PeCDF
10
SFRA-131
SFRA-131
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
25.6
U
1,4-HxCDF
11
SFRA-131
SFRA-131
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
17.5
U
1,6-HxCDF
12
SFRA-131
SFRA-131
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
27.8
U
1,9-HxCDF
13
SFRA-131
SFRA-131
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
18.7
U
4,6-HxCDF
14
SFRA-131
SFRA-131
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
366
1,4,6-HpCDF
15
SFRA-131
SFRA-131
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
27.1
U
1,4,9-HpCDF
16
SFRA-131
SFRA-131
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
470
J
OCDF
17
SFRA-132
SFRA-132
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4850
TCDD
1
SFRA-132
SFRA-132
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
6.58
U
PeCDD
2
SFRA-132
SFRA-132
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
10.8
U
1,4-HxCDD
3
SFRA-132
SFRA-132
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
13.2
J
1,6-HxCDD
4
SFRA-132
SFRA-132
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
11.1
U
1,9-HxCDD
5
SFRA-132
SFRA-132
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
434
1,4,6-HpCDD
6
SFRA-132
SFRA-132
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
10800
OCDD
7
SFRA-132
SFRA-132
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
29.7
J
TCDF
8
SFRA-132
SFRA-132
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.93
U
1-PeCDF
9
SFRA-132
SFRA-132
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.65
U
4-PeCDF
10
SFRA-132
SFRA-132
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
10.2
U
1,4-HxCDF
11
SFRA-132
SFRA-132
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.77
U
1,6-HxCDF
12
SFRA-132
SFRA-132
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
11.7
U
1,9-HxCDF
13
SFRA-132
SFRA-132
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
7.36
U
4,6-HxCDF
14
SFRA-132
SFRA-132
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
80.8
J
1,4,6-HpCDF
15
SFRA-132
SFRA-132
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
18.6
U
1,4,9-HpCDF
16
SFRA-132
SFRA-132
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
312
J
OCDF
17
SFRA-133
SFRA-133
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
5730
TCDD
1
SFRA-133
SFRA-133
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
7.46
U
PeCDD
2
SFRA-133
SFRA-133
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
13.3
U
1,4-HxCDD
3
SFRA-133
SFRA-133
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
44
J
1,6-HxCDD
4
SFRA-133
SFRA-133
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
13.9
U
1,9-HxCDD
5
SFRA-133
SFRA-133
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
588
1,4,6-HpCDD
6
SFRA-133
SFRA-133
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
11500
OCDD
7
SFRA-133
SFRA-133
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
30.7
J
TCDF
8
SFRA-133
SFRA-133
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
7.64
U
1-PeCDF
9
SFRA-133
SFRA-133
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.48
U
4-PeCDF
10
SFRA-133
SFRA-133
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
11.5
U
1,4-HxCDF
11
SFRA-133
SFRA-133
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
8.27
U
1,6-HxCDF
12
SFRA-133
SFRA-133
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
13.7
U
1,9-HxCDF
13
SFRA-133
SFRA-133
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
10.2
u
4,6-HxCDF
14
SFRA-133
SFRA-133
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
187
J
1,4,6-HpCDF
15
SFRA-133
SFRA-133
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
18.7
u
1,4,9-HpCDF
16
SFRA-133
SFRA-133
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
259
J
OCDF
17
SFRA-134
SFRA-134
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
812
TCDD
1
SFRA-134
SFRA-134
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
6.39
u
PeCDD
2
SFRA-134
SFRA-134
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
16.8
J
1,4-HxCDD
3
SFRA-134
SFRA-134
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
40.8
J
1,6-HxCDD
4
SFRA-134
SFRA-134
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
13.1
J
1,9-HxCDD
5
SFRA-134
SFRA-134
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
1170
1,4,6-HpCDD
6
SFRA-134
SFRA-134
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
14100
OCDD
7
SFRA-134
SFRA-134
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.73
u
TCDF
8
SFRA-134
SFRA-134
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
10.3
J
1-PeCDF
9
SFRA-134
SFRA-134
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.39
J
4-PeCDF
10
-------
134
134
134
134
134
134
134
135
135
135
135
135
135
135
135
135
135
135
135
135
135
135
135
135
136
136
136
136
136
136
136
136
136
136
136
136
136
136
136
136
136
137
137
137
137
137
137
137
137
137
137
137
137
137
137
SFRA-134
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
27.9
1,4-HxCDF
11
12
SFRA-134
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
10.3
1,6-HxCDF
SFRA-134
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
11.7
U
1,9-HxCDF
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
SFRA-134
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
10.5
4,6-HxCDF
SFRA-134
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
203
1,4,6-HpCDF
SFRA-134
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
18.8
1,4,9-HpCDF
SFRA-134
,2,3,4,6,7,8,9-Octachlorodibenzofur
,3,7,8-Tetrachlorodibenzo-p-dioxin
39001-02-0
522
OCDF
SFRA-135
,2,3,7,8-Pentachlorodibenzo-p-dioxi
1746-01-6
332
TCDD
SFRA-135
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
40321-76-4
3.33
U
PeCDD
SFRA-135
39227-28-6
29.7
1,4-HxCDD
SFRA-135
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
39.8
1,6-HxCDD
SFRA-135
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
11
1,9-HxCDD
SFRA-135
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
998
1,4,6-HpCDD
SFRA-135
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
12500
OCDD
SFRA-135
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
4.86
U
TCDF
SFRA-135
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
12
1-PeCDF
SFRA-135
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.21
4-PeCDF
SFRA-135
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
28.6
1,4-HxCDF
SFRA-135
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.43
U
1,6-HxCDF
SFRA-135
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
8.45
U
1,9-HxCDF
SFRA-135
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
12.8
4,6-HxCDF
SFRA-135
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
201
1,4,6-HpCDF
SFRA-135
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
18.5
1,4,9-HpCDF
SFRA-135
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
539
OCDF
SFRA-136
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
294
TCDD
SFRA-136
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
4.26
PeCDD
SFRA-136
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
11.7
1,4-HxCDD
SFRA-136
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
26.2
1,6-HxCDD
SFRA-136
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
13.2
1,9-HxCDD
SFRA-136
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
697
1,4,6-HpCDD
SFRA-136
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
9870
OCDD
SFRA-136
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
4.53
U
TCDF
SFRA-136
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
10.9
1-PeCDF
SFRA-136
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.12
4-PeCDF
SFRA-136
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
21.2
1,4-HxCDF
SFRA-136
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.79
1,6-HxCDF
SFRA-136
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
6.43
U
1,9-HxCDF
SFRA-136
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
7.62
4,6-HxCDF
SFRA-136
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
164
1,4,6-HpCDF
SFRA-136
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
16.5
1,4,9-HpCDF
SFRA-136
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
495
OCDF
SFRA-137
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
238
TCDD
SFRA-137
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
4.27
U
PeCDD
SFRA-137
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
22.7
1,4-HxCDD
SFRA-137
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
37.7
1,6-HxCDD
SFRA-137
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
13.9
1,9-HxCDD
SFRA-137
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
1110
1,4,6-HpCDD
SFRA-137
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
14300
OCDD
SFRA-137
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
5.49
U
TCDF
SFRA-137
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
11.2
1-PeCDF
SFRA-137
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.35
4-PeCDF
SFRA-137
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
27.7
1,4-HxCDF
SFRA-137
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
8.2
1,6-HxCDF
SFRA-137
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
10.1
U
1,9-HxCDF
SFRA-137
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
11.2
4,6-HxCDF
-------
SFRA-137
SFRA-137
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
224
1,4,6-HpCDF
15
SFRA-137
SFRA-137
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
17.7
J
1,4,9-HpCDF
16
SFRA-137
SFRA-137
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
839
OCDF
17
SFRA-138
SFRA-138
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
731
TCDD
1
SFRA-138
SFRA-138
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
3.43
U
PeCDD
2
SFRA-138
SFRA-138
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
7.46
J
1,4-HxCDD
3
SFRA-138
SFRA-138
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
10
J
1,6-HxCDD
4
SFRA-138
SFRA-138
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
11.6
U
1,9-HxCDD
5
SFRA-138
SFRA-138
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
429
1,4,6-HpCDD
6
SFRA-138
SFRA-138
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
21600
OCDD
7
SFRA-138
SFRA-138
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.08
J
TCDF
8
SFRA-138
SFRA-138
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.33
J
1-PeCDF
9
SFRA-138
SFRA-138
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.45
J
4-PeCDF
10
SFRA-138
SFRA-138
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.06
U
1,4-HxCDF
11
SFRA-138
SFRA-138
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.99
U
1,6-HxCDF
12
SFRA-138
SFRA-138
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.16
U
1,9-HxCDF
13
SFRA-138
SFRA-138
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.1
U
4,6-HxCDF
14
SFRA-138
SFRA-138
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
7.26
J
1,4,6-HpCDF
15
SFRA-138
SFRA-138
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
5.16
U
1,4,9-HpCDF
16
SFRA-138
SFRA-138
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
21.9
U
OCDF
17
SFRA-139
SFRA-139
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
8340
TCDD
1
SFRA-139
SFRA-139
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
12.2
J
PeCDD
2
SFRA-139
SFRA-139
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
17.4
U
1,4-HxCDD
3
SFRA-139
SFRA-139
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
60.1
J
1,6-HxCDD
4
SFRA-139
SFRA-139
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
34.2
J
1,9-HxCDD
5
SFRA-139
SFRA-139
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
1070
1,4,6-HpCDD
6
SFRA-139
SFRA-139
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
14100
OCDD
7
SFRA-139
SFRA-139
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
51.3
TCDF
8
SFRA-139
SFRA-139
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
7.92
U
1-PeCDF
9
SFRA-139
SFRA-139
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
9.77
J
4-PeCDF
10
SFRA-139
SFRA-139
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
16.7
J
1,4-HxCDF
11
SFRA-139
SFRA-139
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
41.2
J
1,6-HxCDF
12
SFRA-139
SFRA-139
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
13.9
U
1,9-HxCDF
13
SFRA-139
SFRA-139
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
17.8
J
4,6-HxCDF
14
SFRA-139
SFRA-139
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
231
1,4,6-HpCDF
15
SFRA-139
SFRA-139
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
37
U
1,4,9-HpCDF
16
SFRA-139
SFRA-139
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
323
J
OCDF
17
SFRA-140
SFRA-140
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
8200
TCDD
1
SFRA-140
SFRA-140
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
11.1
U
PeCDD
2
SFRA-140
SFRA-140
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
16.5
U
1,4-HxCDD
3
SFRA-140
SFRA-140
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
90.7
J
1,6-HxCDD
4
SFRA-140
SFRA-140
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
46.5
J
1,9-HxCDD
5
SFRA-140
SFRA-140
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
897
1,4,6-HpCDD
6
SFRA-140
SFRA-140
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
11700
OCDD
7
SFRA-140
SFRA-140
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
42.8
TCDF
8
SFRA-140
SFRA-140
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
8.34
U
1-PeCDF
9
SFRA-140
SFRA-140
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
10.8
J
4-PeCDF
10
SFRA-140
SFRA-140
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
19.7
J
1,4-HxCDF
11
SFRA-140
SFRA-140
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
65.1
J
1,6-HxCDF
12
SFRA-140
SFRA-140
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
15.9
U
1,9-HxCDF
13
SFRA-140
SFRA-140
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
15.7
J
4,6-HxCDF
14
SFRA-140
SFRA-140
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
324
1,4,6-HpCDF
15
SFRA-140
SFRA-140
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
19.8
U
1,4,9-HpCDF
16
SFRA-140
SFRA-140
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
350
J
OCDF
17
SFRA-141
SFRA-141
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3450
TCDD
1
-------
SFRA-141
SFRA-141
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
7.68
U
PeCDD
2
SFRA-141
SFRA-141
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
10.7
U
1,4-HxCDD
3
SFRA-141
SFRA-141
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
35.4
J
1,6-HxCDD
4
SFRA-141
SFRA-141
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
14
J
1,9-HxCDD
5
SFRA-141
SFRA-141
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
526
1,4,6-HpCDD
6
SFRA-141
SFRA-141
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
8530
OCDD
7
SFRA-141
SFRA-141
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
22.9
J
TCDF
8
SFRA-141
SFRA-141
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.46
U
1-PeCDF
9
SFRA-141
SFRA-141
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.93
U
4-PeCDF
10
SFRA-141
SFRA-141
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
7.63
U
1,4-HxCDF
11
SFRA-141
SFRA-141
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
17.7
J
1,6-HxCDF
12
SFRA-141
SFRA-141
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
10.3
U
1,9-HxCDF
13
SFRA-141
SFRA-141
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
7.48
U
4,6-HxCDF
14
SFRA-141
SFRA-141
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
159
J
1,4,6-HpCDF
15
SFRA-141
SFRA-141
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
11.7
U
1,4,9-HpCDF
16
SFRA-141
SFRA-141
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
214
J
OCDF
17
SFRA-142
SFRA-142
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4070
TCDD
1
SFRA-142
SFRA-142
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
11.9
U
PeCDD
2
SFRA-142
SFRA-142
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
26.4
U
1,4-HxCDD
3
SFRA-142
SFRA-142
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
50.7
J
1,6-HxCDD
4
SFRA-142
SFRA-142
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
27.8
U
1,9-HxCDD
5
SFRA-142
SFRA-142
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
759
1,4,6-HpCDD
6
SFRA-142
SFRA-142
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
11400
OCDD
7
SFRA-142
SFRA-142
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
27.4
J
TCDF
8
SFRA-142
SFRA-142
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
9.83
U
1-PeCDF
9
SFRA-142
SFRA-142
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
9.45
U
4-PeCDF
10
SFRA-142
SFRA-142
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
20.5
J
1,4-HxCDF
11
SFRA-142
SFRA-142
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
32.9
J
1,6-HxCDF
12
SFRA-142
SFRA-142
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
13.6
U
1,9-HxCDF
13
SFRA-142
SFRA-142
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
15.3
J
4,6-HxCDF
14
SFRA-142
SFRA-142
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
181
J
1,4,6-HpCDF
15
SFRA-142
SFRA-142
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
20.4
U
1,4,9-HpCDF
16
SFRA-142
SFRA-142
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
259
J
OCDF
17
SFRA-143
SFRA-143
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
14900
TCDD
1
SFRA-143
SFRA-143
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
20.5
U
PeCDD
2
SFRA-143
SFRA-143
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
35.5
U
1,4-HxCDD
3
SFRA-143
SFRA-143
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
105
J
1,6-HxCDD
4
SFRA-143
SFRA-143
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
42.5
J
1,9-HxCDD
5
SFRA-143
SFRA-143
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
1370
1,4,6-HpCDD
6
SFRA-143
SFRA-143
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
14800
OCDD
7
SFRA-143
SFRA-143
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
90.1
J
TCDF
8
SFRA-143
SFRA-143
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
18.6
U
1-PeCDF
9
SFRA-143
SFRA-143
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
16.2
U
4-PeCDF
10
SFRA-143
SFRA-143
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
29.4
J
1,4-HxCDF
11
SFRA-143
SFRA-143
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
58.5
J
1,6-HxCDF
12
SFRA-143
SFRA-143
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
37.9
U
1,9-HxCDF
13
SFRA-143
SFRA-143
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
23.4
U
4,6-HxCDF
14
SFRA-143
SFRA-143
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
671
1,4,6-HpCDF
15
SFRA-143
SFRA-143
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
46.9
U
1,4,9-HpCDF
16
SFRA-143
SFRA-143
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
966
OCDF
17
SFRA-144
SFRA-144
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3100
TCDD
1
SFRA-144
SFRA-144
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
9.55
U
PeCDD
2
SFRA-144
SFRA-144
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
14.2
U
1,4-HxCDD
3
SFRA-144
SFRA-144
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
44.3
J
1,6-HxCDD
4
SFRA-144
SFRA-144
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
15.3
U
1,9-HxCDD
5
-------
SFRA-144
SFRA-144
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
448
1,4,6-HpCDD
6
SFRA-144
SFRA-144
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
10000
OCDD
7
SFRA-144
SFRA-144
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
21.5
J
TCDF
8
SFRA-144
SFRA-144
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
9.54
U
1-PeCDF
9
SFRA-144
SFRA-144
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
8.09
U
4-PeCDF
10
SFRA-144
SFRA-144
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
9.74
U
1,4-HxCDF
11
SFRA-144
SFRA-144
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
8.98
U
1,6-HxCDF
12
SFRA-144
SFRA-144
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
14.2
U
1,9-HxCDF
13
SFRA-144
SFRA-144
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
10.3
U
4,6-HxCDF
14
SFRA-144
SFRA-144
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
117
J
1,4,6-HpCDF
15
SFRA-144
SFRA-144
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
14.6
U
1,4,9-HpCDF
16
SFRA-144
SFRA-144
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
122
J
OCDF
17
SFRA-145
SFRA-145
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
5690
TCDD
1
SFRA-145
SFRA-145
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
13
U
PeCDD
2
SFRA-145
SFRA-145
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
21.4
U
1,4-HxCDD
3
SFRA-145
SFRA-145
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
46.1
J
1,6-HxCDD
4
SFRA-145
SFRA-145
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
22.6
U
1,9-HxCDD
5
SFRA-145
SFRA-145
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
814
1,4,6-HpCDD
6
SFRA-145
SFRA-145
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
13600
OCDD
7
SFRA-145
SFRA-145
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
34
J
TCDF
8
SFRA-145
SFRA-145
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
13
U
1-PeCDF
9
SFRA-145
SFRA-145
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
12.4
U
4-PeCDF
10
SFRA-145
SFRA-145
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
18.5
U
1,4-HxCDF
11
SFRA-145
SFRA-145
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
17
U
1,6-HxCDF
12
SFRA-145
SFRA-145
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
32
U
1,9-HxCDF
13
SFRA-145
SFRA-145
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
19.7
U
4,6-HxCDF
14
SFRA-145
SFRA-145
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
203
J
1,4,6-HpCDF
15
SFRA-145
SFRA-145
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
79.6
U
1,4,9-HpCDF
16
SFRA-145
SFRA-145
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
302
J
OCDF
17
SFRA-146
SFRA-146
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3570
TCDD
1
SFRA-146
SFRA-146
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
13.6
U
PeCDD
2
SFRA-146
SFRA-146
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
33.2
U
1,4-HxCDD
3
SFRA-146
SFRA-146
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
40.1
J
1,6-HxCDD
4
SFRA-146
SFRA-146
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
33.8
U
1,9-HxCDD
5
SFRA-146
SFRA-146
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
643
1,4,6-HpCDD
6
SFRA-146
SFRA-146
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
10800
OCDD
7
SFRA-146
SFRA-146
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
26.6
J
TCDF
8
SFRA-146
SFRA-146
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
15.9
U
1-PeCDF
9
SFRA-146
SFRA-146
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
9.65
U
4-PeCDF
10
SFRA-146
SFRA-146
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
13.3
U
1,4-HxCDF
11
SFRA-146
SFRA-146
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
10
U
1,6-HxCDF
12
SFRA-146
SFRA-146
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
16.2
U
1,9-HxCDF
13
SFRA-146
SFRA-146
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
10.9
U
4,6-HxCDF
14
SFRA-146
SFRA-146
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
146
J
1,4,6-HpCDF
15
SFRA-146
SFRA-146
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
30.8
u
1,4,9-HpCDF
16
SFRA-146
SFRA-146
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
307
J
OCDF
17
SFRA-147
SFRA-147
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
335
TCDD
1
SFRA-147
SFRA-147
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.14
u
PeCDD
2
SFRA-147
SFRA-147
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
4.47
u
1,4-HxCDD
3
SFRA-147
SFRA-147
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
7.03
u
1,6-HxCDD
4
SFRA-147
SFRA-147
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
4.53
u
1,9-HxCDD
5
SFRA-147
SFRA-147
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
106
1,4,6-HpCDD
6
SFRA-147
SFRA-147
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
4940
OCDD
7
SFRA-147
SFRA-147
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.93
J
TCDF
8
SFRA-147
SFRA-147
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.24
u
1-PeCDF
9
-------
SFRA-147
SFRA-147
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.81
U
4-PeCDF
10
SFRA-147
SFRA-147
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.32
U
1,4-HxCDF
11
SFRA-147
SFRA-147
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.19
U
1,6-HxCDF
12
SFRA-147
SFRA-147
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.71
U
1,9-HxCDF
13
SFRA-147
SFRA-147
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.37
U
4,6-HxCDF
14
SFRA-147
SFRA-147
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
21.5
J
1,4,6-HpCDF
15
SFRA-147
SFRA-147
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
6.79
U
1,4,9-HpCDF
16
SFRA-147
SFRA-147
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
32.6
J
OCDF
17
SFRA-148
SFRA-148
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
24400
TCDD
1
SFRA-148
SFRA-148
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
32.5
U
PeCDD
2
SFRA-148
SFRA-148
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
62.6
U
1,4-HxCDD
3
SFRA-148
SFRA-148
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
139
J
1,6-HxCDD
4
SFRA-148
SFRA-148
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
62.1
U
1,9-HxCDD
5
SFRA-148
SFRA-148
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
1420
1,4,6-HpCDD
6
SFRA-148
SFRA-148
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
16000
OCDD
7
SFRA-148
SFRA-148
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
163
TCDF
8
SFRA-148
SFRA-148
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
22.5
U
1-PeCDF
9
SFRA-148
SFRA-148
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
20.8
U
4-PeCDF
10
SFRA-148
SFRA-148
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
39.3
J
1,4-HxCDF
11
SFRA-148
SFRA-148
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
25.1
U
1,6-HxCDF
12
SFRA-148
SFRA-148
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
34.1
U
1,9-HxCDF
13
SFRA-148
SFRA-148
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
33.2
J
4,6-HxCDF
14
SFRA-148
SFRA-148
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
491
J
1,4,6-HpCDF
15
SFRA-148
SFRA-148
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
91.5
U
1,4,9-HpCDF
16
SFRA-148
SFRA-148
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
521
J
OCDF
17
SFRA-149
SFRA-149
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
11300
TCDD
1
SFRA-149
SFRA-149
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
14.8
U
PeCDD
2
SFRA-149
SFRA-149
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
24
U
1,4-HxCDD
3
SFRA-149
SFRA-149
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
25.1
J
1,6-HxCDD
4
SFRA-149
SFRA-149
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
24.2
U
1,9-HxCDD
5
SFRA-149
SFRA-149
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
562
1,4,6-HpCDD
6
SFRA-149
SFRA-149
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
8990
OCDD
7
SFRA-149
SFRA-149
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
73.6
J
TCDF
8
SFRA-149
SFRA-149
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
13.2
U
1-PeCDF
9
SFRA-149
SFRA-149
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
11.7
U
4-PeCDF
10
SFRA-149
SFRA-149
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
16.5
U
1,4-HxCDF
11
SFRA-149
SFRA-149
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
14
U
1,6-HxCDF
12
SFRA-149
SFRA-149
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
25.4
U
1,9-HxCDF
13
SFRA-149
SFRA-149
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
17.9
U
4,6-HxCDF
14
SFRA-149
SFRA-149
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
160
J
1,4,6-HpCDF
15
SFRA-149
SFRA-149
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
44.4
U
1,4,9-HpCDF
16
SFRA-149
SFRA-149
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
194
J
OCDF
17
SFRA-150
SFRA-150
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1770
TCDD
1
SFRA-150
SFRA-150
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.72
J
PeCDD
2
SFRA-150
SFRA-150
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
2.4
U
1,4-HxCDD
3
SFRA-150
SFRA-150
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
21.2
J
1,6-HxCDD
4
SFRA-150
SFRA-150
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
7.93
J
1,9-HxCDD
5
SFRA-150
SFRA-150
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
411
1,4,6-HpCDD
6
SFRA-150
SFRA-150
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
7850
OCDD
7
SFRA-150
SFRA-150
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
15.8
TCDF
8
SFRA-150
SFRA-150
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.83
J
1-PeCDF
9
SFRA-150
SFRA-150
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.32
J
4-PeCDF
10
SFRA-150
SFRA-150
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
9.11
J
1,4-HxCDF
11
SFRA-150
SFRA-150
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.06
J
1,6-HxCDF
12
SFRA-150
SFRA-150
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
3.29
U
1,9-HxCDF
13
-------
SFRA-150
SFRA-150
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
4.74
J
4,6-HxCDF
14
SFRA-150
SFRA-150
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
86.9
1,4,6-HpCDF
15
SFRA-150
SFRA-150
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
6.44
J
1,4,9-HpCDF
16
SFRA-150
SFRA-150
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
164
OCDF
17
SFRA-151
SFRA-151
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
15.8
TCDD
1
SFRA-151
SFRA-151
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.12
U
PeCDD
2
SFRA-151
SFRA-151
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
1.77
U
1,4-HxCDD
3
SFRA-151
SFRA-151
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
1.6
U
1,6-HxCDD
4
SFRA-151
SFRA-151
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
1.75
U
1,9-HxCDD
5
SFRA-151
SFRA-151
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
32.8
J
1,4,6-HpCDD
6
SFRA-151
SFRA-151
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
2290
OCDD
7
SFRA-151
SFRA-151
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.28
U
TCDF
8
SFRA-151
SFRA-151
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.745
U
1-PeCDF
9
SFRA-151
SFRA-151
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.645
U
4-PeCDF
10
SFRA-151
SFRA-151
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.953
U
1,4-HxCDF
11
SFRA-151
SFRA-151
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.863
U
1,6-HxCDF
12
SFRA-151
SFRA-151
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.48
U
1,9-HxCDF
13
SFRA-151
SFRA-151
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
0.963
U
4,6-HxCDF
14
SFRA-151
SFRA-151
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
4.73
J
1,4,6-HpCDF
15
SFRA-151
SFRA-151
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
2.43
U
1,4,9-HpCDF
16
SFRA-151
SFRA-151
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
8.65
J
OCDF
17
SFRA-152
SFRA-152
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1.6
U
TCDD
1
SFRA-152
SFRA-152
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
0.99
U
PeCDD
2
SFRA-152
SFRA-152
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
1.55
U
1,4-HxCDD
3
SFRA-152
SFRA-152
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
1.46
U
1,6-HxCDD
4
SFRA-152
SFRA-152
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
1.58
U
1,9-HxCDD
5
SFRA-152
SFRA-152
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
9.72
J
1,4,6-HpCDD
6
SFRA-152
SFRA-152
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
329
OCDD
7
SFRA-152
SFRA-152
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.15
U
TCDF
8
SFRA-152
SFRA-152
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.632
U
1-PeCDF
9
SFRA-152
SFRA-152
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.597
U
4-PeCDF
10
SFRA-152
SFRA-152
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.922
U
1,4-HxCDF
11
SFRA-152
SFRA-152
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.875
U
1,6-HxCDF
12
SFRA-152
SFRA-152
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.58
U
1,9-HxCDF
13
SFRA-152
SFRA-152
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
0.971
U
4,6-HxCDF
14
SFRA-152
SFRA-152
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
1.6
J
1,4,6-HpCDF
15
SFRA-152
SFRA-152
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
2.52
U
1,4,9-HpCDF
16
SFRA-152
SFRA-152
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
6.52
U
OCDF
17
SFRA-153
SFRA-153
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1.62
u
TCDD
1
SFRA-153
SFRA-153
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.15
u
PeCDD
2
SFRA-153
SFRA-153
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
1.49
u
1,4-HxCDD
3
SFRA-153
SFRA-153
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
1.43
u
1,6-HxCDD
4
SFRA-153
SFRA-153
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
1.54
u
1,9-HxCDD
5
SFRA-153
SFRA-153
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
6.58
J
1,4,6-HpCDD
6
SFRA-153
SFRA-153
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
414
OCDD
7
SFRA-153
SFRA-153
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.23
u
TCDF
8
SFRA-153
SFRA-153
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.569
J
1-PeCDF
9
SFRA-153
SFRA-153
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.482
u
4-PeCDF
10
SFRA-153
SFRA-153
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.874
u
1,4-HxCDF
11
SFRA-153
SFRA-153
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.783
u
1,6-HxCDF
12
SFRA-153
SFRA-153
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.38
u
1,9-HxCDF
13
SFRA-153
SFRA-153
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
0.927
u
4,6-HxCDF
14
SFRA-153
SFRA-153
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
1.2
u
1,4,6-HpCDF
15
SFRA-153
SFRA-153
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
1.96
u
1,4,9-HpCDF
16
SFRA-153
SFRA-153
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
5.42
u
OCDF
17
-------
154
154
154
154
154
154
154
154
154
154
154
154
154
154
154
154
154
155
155
155
155
155
155
155
155
155
155
155
155
155
155
155
155
155
156
156
156
156
156
156
156
156
156
156
156
156
156
156
156
156
156
157
157
157
157
SFRA-154
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1.11
U
TCDD
2
SFRA-154
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
0.769
U
PeCDD
SFRA-154
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
1.33
U
1,4-HxCDD
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
SFRA-154
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
1.24
U
1,6-HxCDD
SFRA-154
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
1.35
U
1,9-HxCDD
SFRA-154
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
21.3
1,4,6-HpCDD
SFRA-154
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
755
OCDD
SFRA-154
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.05
U
TCDF
SFRA-154
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.533
U
1-PeCDF
SFRA-154
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.483
U
4-PeCDF
SFRA-154
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.629
U
1,4-HxCDF
SFRA-154
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.607
U
1,6-HxCDF
SFRA-154
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.04
U
1,9-HxCDF
SFRA-154
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
0.636
U
4,6-HxCDF
SFRA-154
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
1.88
1,4,6-HpCDF
SFRA-154
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
1.67
U
1,4,9-HpCDF
SFRA-154
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
4.04
U
OCDF
SFRA-155
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
0.75
U
TCDD
SFRA-155
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
0.857
U
PeCDD
SFRA-155
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
1.37
U
1,4-HxCDD
SFRA-155
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
1.29
U
1,6-HxCDD
SFRA-155
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
1.41
U
1,9-HxCDD
SFRA-155
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
7.01
1,4,6-HpCDD
SFRA-155
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
161
OCDD
SFRA-155
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.62
TCDF
SFRA-155
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.843
1-PeCDF
SFRA-155
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.726
U
4-PeCDF
SFRA-155
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.837
U
1,4-HxCDF
SFRA-155
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.801
U
1,6-HxCDF
SFRA-155
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
1.3
U
1,9-HxCDF
SFRA-155
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
0.879
U
4,6-HxCDF
SFRA-155
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
2.42
1,4,6-HpCDF
SFRA-155
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
1.86
U
1,4,9-HpCDF
SFRA-155
2,3,4,6,7,8,9-Octachlorodibenzofur
,3,7,8-Tetrachlorodibenzo-p-dioxin
39001-02-0
4.47
OCDF
SFRA-156
2,3,7,8-Pentachlorodibenzo-p-diox
1746-01-6
79.3
TCDD
SFRA-156
2,3,4,7,8-Hexachlorodibenzo-p-dio:
40321-76-4
2.04
U
PeCDD
SFRA-156
39227-28-6
3.86
1,4-HxCDD
SFRA-156
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
41.6
1,6-HxCDD
SFRA-156
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
14.4
U
1,9-HxCDD
SFRA-156
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
879
1,4,6-HpCDD
SFRA-156
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
10700
OCDD
SFRA-156
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.86
TCDF
SFRA-156
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.52
U
1-PeCDF
SFRA-156
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.42
4-PeCDF
SFRA-156
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
10.2
1,4-HxCDF
SFRA-156
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.46
1,6-HxCDF
SFRA-156
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
6.94
U
1,9-HxCDF
SFRA-156
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
8.3
4,6-HxCDF
SFRA-156
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
143
1,4,6-HpCDF
SFRA-156
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
13.1
1,4,9-HpCDF
SFRA-156
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
405
OCDF
SFRA-157
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
7140
TCDD
SFRA-157
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
12.1
U
PeCDD
SFRA-157
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
17.6
U
1,4-HxCDD
SFRA-157
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
79.1
1,6-HxCDD
-------
157
157
157
157
157
157
157
157
157
157
157
157
157
158
158
158
158
158
158
158
158
158
158
158
158
158
158
158
158
158
159
159
159
159
159
159
159
159
159
159
159
159
159
159
159
159
159
160
160
160
160
160
160
160
160
SFRA-157
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
18.8
U
1,9-HxCDD
_5
6
SFRA-157
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
877
1,4,6-HpCDD
SFRA-157
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
11500
OCDD
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
1
2
3
4
5
6
7
8
SFRA-157
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
44.4
TCDF
SFRA-157
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
7.64
U
1-PeCDF
SFRA-157
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.84
U
4-PeCDF
SFRA-157
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
17
1,4-HxCDF
SFRA-157
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
11.6
U
1,6-HxCDF
SFRA-157
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
18.1
U
1,9-HxCDF
SFRA-157
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
12.4
U
4,6-HxCDF
SFRA-157
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
253
1,4,6-HpCDF
SFRA-157
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
25.9
U
1,4,9-HpCDF
SFRA-157
,2,3,4,6,7,8,9-Octachlorodibenzofur
,3,7,8-Tetrachlorodibenzo-p-dioxin
39001-02-0
351
OCDF
SFRA-158
,2,3,7,8-Pentachlorodibenzo-p-dioxi
1746-01-6
3370
TCDD
SFRA-158
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
40321-76-4
6.83
U
PeCDD
SFRA-158
39227-28-6
12.7
U
1,4-HxCDD
SFRA-158
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
20.7
1,6-HxCDD
SFRA-158
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
12.8
U
1,9-HxCDD
SFRA-158
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
419
1,4,6-HpCDD
SFRA-158
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
7500
OCDD
SFRA-158
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
21
TCDF
SFRA-158
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.45
U
1-PeCDF
SFRA-158
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.21
U
4-PeCDF
SFRA-158
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
9.7
U
1,4-HxCDF
SFRA-158
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.29
U
1,6-HxCDF
SFRA-158
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
13.8
U
1,9-HxCDF
SFRA-158
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
8.22
U
4,6-HxCDF
SFRA-158
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
87.6
1,4,6-HpCDF
SFRA-158
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
20.4
U
1,4,9-HpCDF
SFRA-158
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
177
OCDF
SFRA-159
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
276
TCDD
SFRA-159
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
2.63
U
PeCDD
SFRA-159
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
4.51
U
1,4-HxCDD
SFRA-159
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
18.6
1,6-HxCDD
SFRA-159
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
6.82
1,9-HxCDD
SFRA-159
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
424
1,4,6-HpCDD
SFRA-159
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
8140
OCDD
SFRA-159
,3,7,8-Tetrachlorodibenzofuran
51207-31-9
5.84
TCDF
SFRA-159
,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.96
U
1-PeCDF
SFRA-159
,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.69
U
4-PeCDF
SFRA-159
,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.74
1,4-HxCDF
SFRA-159
,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.74
1,6-HxCDF
SFRA-159
,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
6.15
U
1,9-HxCDF
SFRA-159
,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
5.37
4,6-HxCDF
SFRA-159
,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
83.7
1,4,6-HpCDF
SFRA-159
,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
7.86
1,4,9-HpCDF
SFRA-159
,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
208
OCDF
SFRA-160
,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2360
TCDD
SFRA-160
,2,3,7,8-Pentachlorodibenzo-p-dioxi
40321-76-4
3.03
U
PeCDD
SFRA-160
,2,3,4,7,8-Hexachlorodibenzo-p-dio:
39227-28-6
7.4
U
1,4-HxCDD
SFRA-160
,2,3,6,7,8-Hexachlorodibenzo-p-dio:
57653-85-7
14.2
1,6-HxCDD
SFRA-160
,2,3,7,8,9-Hexachlorodibenzo-p-dio:
19408-74-3
7.24
U
1,9-HxCDD
SFRA-160
,2,3,4,6,7,8-Heptachlorodibenzo-p-(
35822-46-9
291
1,4,6-HpCDD
SFRA-160
,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
8300
OCDD
SFRA-160
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
14.5
TCDF
-------
SFRA-160
SFRA-160
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.31
U
1-PeCDF
9
SFRA-160
SFRA-160
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.02
J
4-PeCDF
10
SFRA-160
SFRA-160
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6
J
1,4-HxCDF
11
SFRA-160
SFRA-160
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.06
U
1,6-HxCDF
12
SFRA-160
SFRA-160
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
7.34
U
1,9-HxCDF
13
SFRA-160
SFRA-160
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
4.49
U
4,6-HxCDF
14
SFRA-160
SFRA-160
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
59.6
1,4,6-HpCDF
15
SFRA-160
SFRA-160
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
15.3
U
1,4,9-HpCDF
16
SFRA-160
SFRA-160
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
76.3
J
OCDF
17
SFRA-161
SFRA-161
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
340
TCDD
1
SFRA-161
SFRA-161
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
2.05
U
PeCDD
2
SFRA-161
SFRA-161
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
5.67
U
1,4-HxCDD
3
SFRA-161
SFRA-161
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
9.51
J
1,6-HxCDD
4
SFRA-161
SFRA-161
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
5.79
U
1,9-HxCDD
5
SFRA-161
SFRA-161
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
267
1,4,6-HpCDD
6
SFRA-161
SFRA-161
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
5920
OCDD
7
SFRA-161
SFRA-161
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.2
J
TCDF
8
SFRA-161
SFRA-161
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.13
U
1-PeCDF
9
SFRA-161
SFRA-161
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.93
U
4-PeCDF
10
SFRA-161
SFRA-161
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.79
J
1,4-HxCDF
11
SFRA-161
SFRA-161
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.36
U
1,6-HxCDF
12
SFRA-161
SFRA-161
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
4.32
U
1,9-HxCDF
13
SFRA-161
SFRA-161
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
3.37
U
4,6-HxCDF
14
SFRA-161
SFRA-161
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
45.9
J
1,4,6-HpCDF
15
SFRA-161
SFRA-161
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
8
U
1,4,9-HpCDF
16
SFRA-161
SFRA-161
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
114
OCDF
17
SFRA-162
SFRA-162
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1110
TCDD
1
SFRA-162
SFRA-162
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
1.66
U
PeCDD
2
SFRA-162
SFRA-162
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
3.7
U
1,4-HxCDD
3
SFRA-162
SFRA-162
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
12.1
J
1,6-HxCDD
4
SFRA-162
SFRA-162
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
4.87
J
1,9-HxCDD
5
SFRA-162
SFRA-162
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
249
1,4,6-HpCDD
6
SFRA-162
SFRA-162
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
15200
OCDD
7
SFRA-162
SFRA-162
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
9.35
J
TCDF
8
SFRA-162
SFRA-162
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.22
U
1-PeCDF
9
SFRA-162
SFRA-162
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.52
U
4-PeCDF
10
SFRA-162
SFRA-162
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.02
J
1,4-HxCDF
11
SFRA-162
SFRA-162
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.75
U
1,6-HxCDF
12
SFRA-162
SFRA-162
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
2.26
U
1,9-HxCDF
13
SFRA-162
SFRA-162
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
2.34
J
4,6-HxCDF
14
SFRA-162
SFRA-162
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
44.9
J
1,4,6-HpCDF
15
SFRA-162
SFRA-162
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
2.77
J
1,4,9-HpCDF
16
SFRA-162
SFRA-162
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
68.9
J
OCDF
17
SFRA-163
SFRA-163
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
0.76
U
TCDD
1
SFRA-163
SFRA-163
1,2,3,7,8-Pentachlorodibenzo-p-diox
40321-76-4
0.775
U
PeCDD
2
SFRA-163
SFRA-163
1,2,3,4,7,8-Hexachlorodibenzo-p-dio
39227-28-6
1.29
U
1,4-HxCDD
3
SFRA-163
SFRA-163
1,2,3,6,7,8-Hexachlorodibenzo-p-dio
57653-85-7
1.34
U
1,6-HxCDD
4
SFRA-163
SFRA-163
1,2,3,7,8,9-Hexachlorodibenzo-p-dio
19408-74-3
1.58
J
1,9-HxCDD
5
SFRA-163
SFRA-163
1,2,3,4,6,7,8-Heptachlorodibenzo-p-c
35822-46-9
71.4
1,4,6-HpCDD
6
SFRA-163
SFRA-163
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-
3268-87-9
12100
OCDD
7
SFRA-163
SFRA-163
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.98
J
TCDF
8
SFRA-163
SFRA-163
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.752
U
1-PeCDF
9
SFRA-163
SFRA-163
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.737
u
4-PeCDF
10
SFRA-163
SFRA-163
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.737
u
1,4-HxCDF
11
SFRA-163
SFRA-163
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.725
u
1,6-HxCDF
12
-------
SFRA-163
SFRA-163
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
0.9
U
1,9-HxCDF
13
SFRA-163
SFRA-163
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
0.758
U
4,6-HxCDF
14
SFRA-163
SFRA-163
1,2,3,4,6,7,8-Heptachlorodibenzofurc
67562-39-4
2.66
J
1,4,6-HpCDF
15
SFRA-163
SFRA-163
1,2,3,4,7,8,9-Heptachlorodibenzofurc
55673-89-7
1.7
U
1,4,9-HpCDF
16
SFRA-163
SFRA-163
1,2,3,4,6,7,8,9-Octachlorodibenzofur
39001-02-0
8.09
J
OCDF
17
-------
EPA Advanced KM TEQ Calculator
congener TEC
# Detects
# Nondetects
Quantiles
KMStats v 1.4 Practical Stats
3.63
1
0
0.941
Input data to the blue cells, then sort from highest to lowest
3.63
0.775
0
1
0.000
concentration. Concentrations and detection limits in Col A.
0.775
0.76
0
1
0.000
Number of detects at each concentration in Col B.
0.76
0.714
1
0
0.874
Number of nondetects at each DL in Col C.
0.714
0.298
1
0
0.807
0.298
0.2211
0
1
0.000
0.2211
0.158
1
0
0.733
0.158
0.134
0
1
0.000
0.134
0.129
0
1
0.000
0.129
0.09
0
1
0.000
0.09
0.0758
0
1
0.000
0.0758
0.0737
0
1
0.000
0.0737
0.0725
0
1
0.000
KM intermediate "mean"
0.0725
0.0266
1
0
0.550
0.2994
0.0266
0.02256
0
1
0.000
0.02256
0.017
0
1
0.000
KM TEQ
0.017
0.002427
1
0
0.000
5.0892
0.002427
0.000
0
0.000
For details on the Kaplan-Meier method, see
0
0.000
Helsel, D.R. (2012), Statistics for Censored Environmental Data Using Minitab and R, 2nd ed. Wiley and Sons. 324
0
0.000
pp.
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
protect/unprotect sheet password = dioxin
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
-------
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
Constant
Flip Cone rank
ranksum
at risk
partial prob
s
3.63
4.63
1
1
1
17
0.94117647
0.94117647
0.775
3.855
1
0
0
0
0.94117647
0.76
3.87
2
0
0
0
0.94117647
0.714
3.916
4
4
14
0.92857143
0.87394958
0.298 #Rows with h
4.332
5
5
13
0.92307692
0.80672269
0.2211
0
4.4089
5
0
0
0
0.80672269
0.158
1
4.472
7
7
11
0.90909091
0.73338426
0.134
1
4.496
7
0
0
0
0.73338426
0.129
4.501
8
0
0
0
0.73338426
0.09
4.54
9
0
0
0
0.73338426
0.0758
4.5542
10
0
0
0
0.73338426
0.0737
4.5563
11
0
0
0
0.73338426
0.0725
4.5575
12
0
0
0
0.73338426
0.0266
4.6034
14
14
4
0.75
0.5500382
0.02256
4.60744
14
0
0
0
0.5500382
0.017
4.613
15
0
0
0
0.5500382
0.002427
4.627573
17
17
1
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
Max50
Row50
For P25
Max25
Row25
For P75
0
0
18
0
0
18 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
16
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
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lean
Rectangles
DiffC
LagP
Cum Area
Ar
Ar2
3.63
1
1
1
4.33063756
3.33063756
0.04078363
0
2.68705882
2.855
0.94117647
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0.58616697
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0.298
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0.87394958
0.58616697
0.22260394
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-------
Abbreviation 1
Abbreviation 2
IUPAC name
CAS#
Type
TCDD
2,3,7,8-TCDD
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
Dioxin
PeCDD
1,2,3,7,8-PeCDD
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
Dioxin
1,4-HxCDD
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
Dioxin
1,6-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
Dioxin
1,9-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
Dioxin
1,4,6-HpCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
Dioxin
OCDD
1,2,3,4,6,7,8,9-OCDD
Octachlorodibenzo-p-dioxin
3268-87-9
Dioxin
TCDF
2,3,7,8-TCDF
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
Furan
1-PeCDF
1,2,3,7,8-PeCDF
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
Furan
4-PeCDF
2,3,4,7,8-PeCDF
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
Furan
1,4-HxCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
Furan
1,6-HxCDF
1,2,3,6,7,8-HxCDF
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
Furan
1,9-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
Furan
4,6-HxCDF
2,3,4,6,7,8-HxCDF
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
Furan
1,4,6-HpCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
Furan
1,4,9-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
Furan
OCDF
1,2,3,4,6,7,8,9-OCDF
Octachlorodibenzofuran
39001-02-0
Furan
PCB 77
3,3',4,4'-TCB
3,3',4,4'-Tetrachlorobiphenyl
32598-13-3
Dioxin-like PCB
PCB81
3,4,4',5-TCB
3,4,4',5-Tetrachlorobiphenyl
70362-50-4
Dioxin-like PCB
PCB 105
2,3,3',4,4'-PeCB
2,3,3',4,4'-Pentachlorobiphenyl
32598-14-4
Dioxin-like PCB
PCB 114
2,3,4,4',5-PeCB
2,3,4,4',5-Pentachlorobiphenyl
74472-37-0
Dioxin-like PCB
PCB 118
2,3',4,4',5-PeCB
2,3',4,4',5-Pentachlorobiphenyl
31508-00-6
Dioxin-like PCB
PCB 123
2,3',4,4',5'-PeCB
2,3',4,4',5'-Pentachlorobiphenyl
65510-44-3
Dioxin-like PCB
PCB 126
3,3',4,4',5-PeCB
3,3',4,4',5-Pentachlorobiphenyl
57465-28-8
Dioxin-like PCB
PCB 156
2,3,3',4,4',5-HxCB
2,3,3',4,4',5-Hexachlorobiphenyl
38380-08-4
Dioxin-like PCB
PCB 157
2,3,3',4,4',5'-HxCB
2,3,3',4,4',5'-Hexachlorobiphenyl
69782-90-7
Dioxin-like PCB
PCB 167
2,3',4,4',5,5'-HxCB
2,3',4,4',5,5'-Hexachlorobiphenyl
52663-72-6
Dioxin-like PCB
PCB 169
3,3',4,4',5,5'-HxCB
3,3',4,4',5,5'-Hexachlorobiphenyl
32774-16-6
Dioxin-like PCB
PCB 189
2,3,3',4,4',5,5'-HpCB
2,3,3',4,4',5,5'-Heptachlorobiphenyl
39635-31-9
Dioxin-like PCB
-------
lAcronym
A
CAS
CLP
CSM
CV
DL
DU
E
EDL
EMPC
EPA
HpCDD
HpCDF
HxCDD
HxCDF
ICS
ISM
ITRC
IUPAC
J
KM
ND
OCDD
OCDF
PCB
PeCDD
PeCDF
QC
R
RSD
SD
SOW
TCDD
TCDF
TEC
TEF
TEQ
U
UCL
WHO
Data qualifier used to indicate an estimated result.
Chemical abstracts service
Contract Laboratory Program
Conceptual site model
Coefficient of variation
Detection limit
Decision unit
Data qualifier used to indicate an estimated result. This qualifier indicates that the concentration
exceeded the instrument calibration range, but did not saturate the detector.
Estimated detection limit
Estimated maximum possible concentration
U.S. Environmental Protection Agency
Heptachlorodibenzo(p)dioxin
Heptachlorodibenzofuran
Hexachlorodibenzo(p)dioxin
Hexachlorodibenzofuran
Incremental composite sample
Incremental sampling methodology
Interstate Technology and Regulatory Council
International Union of Pure and Applied Chemistry
Data qualifier used to indicate an estimated result. This qualifier indicates either: (1) a
concentration between the detection limit and quantitation limit or (2) a concentration qualified as
estimated because of some other quality control failure.
Kaplan-Meier
Nondetect
Octachlorodibenzo(p)dioxin
Octachlorodibenzofuran
Polychlorinated biphenyl
Pentachlorodibenzo(p)dioxin
Pentachlorodibenzofuran
Quality control
Data qualifier used to indicate a rejected result.
Relative standard deviation
Standard deviation
Scope of work
Tetrachlorodibenzo(p)dioxin
Tetrachlorodibenzofuran
Toxicity equivalence concentration
Toxicity equivalence factor
Toxicity equivalence
Data qualifier used to indicate a nondetected result.
Upper confidence limit
World Health Organization
-------
EPA Advanced KM TEQ Calculator
General Instructions |passwoid to proteet/unpioteet worksheets - "dioxln"
These instructions apply to this Advanced Kaplan-Meier (KM) Toxicity Equivalence (TEQ) calculator, which includes calculations that support a simple, quasi-
sensitivity analysis that examines the effect of various ways of handling nondetected (ND) or rejected (R-flagged) analytical data results within a sample's
congener profile. A Basic version of this calculator is also available for TEQ analyses uncomplicated by high-toxicity equivalence factor (TEF) non-detected
congeners or rejected data, therefore it is easier to learn. Also, the Basic version is structured to assist TEQ analysis and upper confidence limit (UCL)
calculations for incremental samples. Both tools are intended for use by practitioners familiar with the calculation and use of TEQ concentrations for dioxins,
furans and dioxin-like PCBs.
Please read the discussion about handling nondetected and rejected congeners on the KM
Discussion worksheet (green tab)!
Individual statisticians vary in their acceptance of Helsel's adaptation of the Kaplan-Meier (KM) technique to estimate sample TEQs when nondetected congeners are
BE present (Helsel 2009). (More details of this technique are covered in the "KM Discussion" worksheet.) Other methods to avoid simple substitution for nondetects
AWARE were suggested by peer reviewers of this calculator, and they may be incorporated into future updates of this calculator. The user is advised to seek input from a
qualified statistician if important project or site decisions are dependent upon the choice of TEQ calculation method.
Although the calculator provides estimates of specific KM TEQ results, the intent of the Advanced calculator is to provide the user with a tool for sensitivity analysis,
rather than a single "answer" for the KM TEQ. The project team should consider the full range of KM TEQ results for each sample to determine whether additional
sample collection is warranted to support decisions to be made based on the data.
Inserting
more sample
rows
The quasi-sensitivity analysis is performed by calculating the TEQ in various ways to estimate the consequences of using or not using ND or rejected (R) data values.
Data entered into the calculator should be reviewed and validated in accordance with all project quality requirements prior to performing the sensitivity analysis.
This workbook can be used to document the approach used to calculate and choose TEQ values. It records TEQs calculated using substitution methods for NDs (0,
1/2-DL, and DL) and the KM method. It also records when R data are used at face value to assess whether the rejected congeners have a significant effect on the
reported TEQ. This helps determine whether reanalysis of the sample is necessary. See discussion of ND and R data on the "KM Discussion" worksheet.
The workbook uses an automated macro that performs the calculations and provides error messages if necessary, allowing the user to correct and repeat the
process until the data are correctly entered.
The "Data Entry & Output" sheet (blue tab) is designed to accommodate up to 50 samples. It is not necessary to delete blank sample rows if the data set is
comprised of less than 50 samples. However, if desired, the user can remove unneeded rows using the "Remove Samples" macro button (see cells P3 to R5 of the
"Data Entry & Output" sheet). If more than 50 samples are required, samples can be added using the "Add Samples" macro button (see cells R3 to T5 of the "Data
Entry & Output" sheet). When run, both of these macros will prompt the user for the number of samples to be added or deleted. An error message will be provided if
too many samples are to be added or removed. At least one sample must be left in the calculator to prevent errors. A maximum of 2,000 total samples is enforced
based on limits to the size of an Excel 2007 worksheet.
"List" for TEQ To facilitate transfer of the TEQ results to another spreadsheet, each sample ID, its TEQ result, and any qualifier are reproduced in an uninterrupted list that is
output located below the data input rows in Columns Al though AM.
Note that the calculator workbook is saved in Excel 97-2003 Workbook format (*.xls). The workbook should work properly in Excel 2007 and Excel 2010, and may be
Excel format saved in Excel Macro-Enabled Workbook format (*.xlsm). In Excel 2007 and 2010 versions, the Excel Workbook format (*.xlsx) will not allow the macros in the
calculator to operate properly, and should not be used to save the workbook unless all data processing is complete.
Unprotecting
worksheets
To make some changes to worksheets, the user will need to unprotect the worksheet. Unprotecting the sheet can be performed using the
Home/Format/Protection/Unprotect Sheet option. The password is "dioxin". The protection will be re-enabled automatically each time the macro is run, so it is
not necessary for the user to manually reenable protection.
Step r
Instructions for Using the TEQ Calculator
-------
Enabling
macros
Note: Prior to their use, macros will first need to be enabled. In Excel 2007, this can be performed by selecting 'Options' on the Security Warning bar that appears
below the Excel menu bars when the workbook is opened, and selecting the 'Enable this content' button, then selecting the 'OK' button. For other versions of Excel,
consult Excel HELP to determine how to enable macros.
Once macros are enabled, follow the steps below.
Automated
data entry
Note: The "Data Import" sheet (purple tab) provides a way to enter data quickly and accurately using a flat-file format from a database, comma-separated-value file
or text file. See specific instructions on the "Data Import" worksheet. In this case, Steps 1, 2 and 3 below will be performed automatically by the automated data entry
macro, and the user may proceed to Step 4 immediately after the data has been imported.
1
Hiding
columns
Informational
data entry
Enter the sample numbers in column B of the "Data Entry & Output" sheet (blue tab). The sample numbers should be entered in the top row (Row A) of each five-
row grouping. If a sample number in any Row A is left blank, the macro will stop operation after the previous sample and will not execute for any samples after this
blank sample number. Note that this step will be performed automatically if the automated data entrv macro is used.
If data are not present for all congeners, the user may leave these columns blank and may hide columns without data. As with deleting and adding rows, the user will
have to unprotect the worksheet to hide or unhide columns. Columns should not be deleted from the worksheet. Hide columns using the "Home" menu:
Format/Visibility/Hide & Unhide/Hide Columns.
Cells D2 to J4 of the "Data Entry & Output" sheet (blue tab) allow the user to enter a project name, matrix (soil, groundwater, etc.), concentration units, person
entering the data, and the date of the analysis. It is recommended that these be entered to assist with data interpretation. The workbook should be used for a single
sampling matrix with the same concentration units. Data for other matrices should be entered into separate copies of the workbook.
2
Reorder
congeners to
match lab
report
Note: Step 2 is optional, but mav help increase the ease, speed and accuracy of data input. Note that this step will be performed automatically if the automated data
entrv macro is used.
Check the order of the chemical names to ensure they are listed in the same order as the source data reports that will be used for data input. If they are not in the
same order, change numbers in row 6 so that they correspond to the order on the project data reports. Then, click the beige button labeled "Sort Chemicals", which
will run a macro to sort the analytes into the order specified in row 6.
Note that the "Congener Abbreviations" sheet ( range ta ) contains a table listing the IUPAC names, CAS numbers, and common abbreviations. This sheet may
be useful in matching the analyte names on the data reports to those in the data entry worksheet.
After the sort is complete, check the order of the chemicals again to ensure they are listed in the correct order. This step can be repeated as many times as
necessary.
3
Entering data
Qualifier entry
location
Pasting
data
Combining
cells in the
source file
In the "Data Entry & Output" worksheet, enter the congener data into Row A for each sample, along with any analytical qualifiers that have been assigned to the
congener result. Enter the qualifier after the numeric value in the same cell. For non-detected results (including EMPC or EDL results), the detection limit should be
entered for the numeric result alona with the aualifiers as indicated below. Note that this step will be performed automatically if the automated data entrv macro is
used.
The Calculator recognizes the following qualifiers:
• J, E, or A: qualifiers used to indicate the congener result is considered estimated.
• U or ND: indicates the congener was not detected in the sample.
• Results flagged as "UJ" should be entered with a "U" qualifier.
• R: indicates the sample result for the congener result was rejected.
The numeric portion of the result should be entered first, followed by the qualifier in the same cell. The qualifiers listed above are the only ones that should be used. It
is not necessary to enter a space between the number and qualifier, but entering a space is also acceptable if the user prefers that approach.
If the user wishes to copy and paste data into the "Data Entry & Output" worksheet, the Paste Values option should be used. To paste values, select "Paste" on the
Excel ribbon, then "Paste Special", then "Paste As Values". Note that Row B will be automatically populated by the macro. The user should not make any entries into
this row.
The source file (an electronic database or spreadsheet file) from which the data are copied for pasting into the "Data Entry & Output" worksheet will usually have the
numerical value in one column and any qualifier for that data value in the next column. In the TEQ calculator, the qualifier must follow the numerical result in the
same column. To reduce manual data entry effort, use the Excel CONCATENATE function or the (ampersand) operator to consolidate the numerical and
qualifier cells of the source file into a single cell which can then be pasted directly into the calculator.
-------
EMPC or
EDL
qualifiers
Note that if values qualified as "estimated maximum possible concentration" (EMPC) or "estimated detection limit" (EDL) are present, these values should be entered
into the TEQ calculator as nondetects (using a U or ND qualifier) with the numerical EMPC or EDL value as the detection limit. This will ensure that these values are
subjected to the full sensitivity analysis as nondetects with a maximum value of the EMPC or EDL. See the EMPC discussion in the "KM Discussion" sheet for more
information.
Coeluting
analytes
If coeluting analytes are present in the sampling results, the user will need to adjust the data entry accordingly. One common coeluting pair is PCB-156 and PCB-157.
In this specific case, the two congeners have the same TEF. Therefore, the data can be entered in the column for PCB-156, and the column for PCB-157 can be left
blank. If coeluting analytes are reported which have different TEFs, it is suggested that the results be entered for the congener with the higher TEF. However, the
user can perform a sensitivity analysis by entering the sample twice, once with the coeluting analyte result entered in each column. The project team should decide
how to handle such situations.
4
Running the
Calculate
TEQ macro
Run the macro by clicking on the beige box button labeled "Calculate TEQs" (see cells R1 through T1 of the sheet "Data Entry & Output" worksheet). The macro will
calculate the toxicity equivalence concentration (TEC) for each congener (in Row C) and then transfer the TECs into the "KM intermediate auto-calc" worksheet
(red tab) to calculate the TEQ. The macro will then transfer the TEQ result back to the "Data Entry & Output" worksheet. After the macro run is completed, examine
Row D for each sample. If there are any samples with congeners that are outlined with a border, these are results for which the user will have the option to enter
substitute ("donor") values from a comparable sample (follow the instructions below). If there are no samples with congeners outlined with a border, continue with
Step 6.
• Values should not be entered for any cell that is not outlined with a border. The outlined cells will fall into two categories. One category is a ND result that is the
highest TEC in the sample. The other is a rejected result.
• Two options are available; option 2 is preferred over option 1. Option 1 should only be used if option 2 is not possible because an analytical result for that
congener from another sample cannot be defensibly substituted.
• OPTION 1:
- Enter the same value from Row B into the boxed cell in Row D.
- Enter "not possible" in column BD, Row C for the sample.
• OPTION 2:
- Examine the rest of the data set and look for samples with a congener profile and concentrations very similar to the sample in question.
- Confirm that the problem congener is detected in that sample. If so, evaluate whether a substitution of the detected value from that sample (a "donor"
sample) can defensibly be made for the U/ND. If there is more than one value that could be substituted for the U/ND, use the most conservative (i.e., highest)
value. Note that the detected value should be less than or equal to the ND value.
- If there is a value from another sample that can be substituted defensibly, enter that value into the boxed cell in Row D.
- If there are no values from other samples that can be substituted defensibly, OR the user prefers to not use substituted ("donor") values, enter the same
value from the Row B into the cell outlined with a border in Row D.
Repeat the substitution process for anv other conaeners in this sample that are outlined with a border, but DO NOT select substitute ("donor") values from more than
1 sample for each specific sample.
In column BD, Row C for the sample, enter the sample ID used for substitute ("donor") values for this sample. Note that this is not necessary if Option 1 above was
selected, since in this case, the "donor" value comes from the same sample. However, it will be required if Option 2 is used.
"Donor"
values
Repeat the congener substitution substeps of Step 4 for all samples.
5
Click on the box labeled "Calculate TEQs" (see cells R1 through T1 of the worksheet "Data Entry & Output"). This will initiate a macro that will copy the entered data
to the "KM intermediate auto-calc" worksheet and display the returned results.
6
If any error messages are displayed to the user, examine column AN to see which samples have data entry errors, and correct them (see instructions 1 through 4).
7
"Select KM
TEQ" box
The macro will automatically populate the method for calculating the KM TEQ in column AN "Select KM TEQ" in the uppermost gray cell. As a default, the method
that provides the highest KM TEQ will be selected. The user may override this selection and choose another method for calculating the KM TEQ. When the user
chooses another method for calculating the KM TEQ in column AM for a sample, the following will be automatically updated: the sample KM TEQ and the qualifiers in
columns AL and AM.
-------
Sensitivity
Analysis
Summary
Column AG provides a "Summary of the Sensitivity Analysis" for a single sample by calculating the relative percent difference (RPD) between the highest and the
lowest TEQ results for that sample. This gives a sense of the "spread" of TEQ results obtained from the different ways ND congeners can be handled. When there
are no ND congeners, all values will be exactly the same, and Column AG reports "no difference." If ND congeners are present in the sample, the highest result will
be the value obtained by substituting congener DLs for NDs, and the lowest will come from substituting zero for the NDs. If these two results are very close, the RPD may
round down to 0%. If the TEQ results are near a decision threshold and a non-zero %RPD is reported, closer examination of that sample is recommended. The equation
used to calculate the relative percent difference is RPD = ((HIGHEST TEQ - LOWEST TEQ)/AVERAGE OF HIGHEST & LOWEST TEQs) x 100, and rounded to an integer.
"Locked"
feature
There is another gray box directly below the gray KM TEQ selection box discussed above. Here the user has the option to select "Locked", or leave the cell blank
(i.e., unlocked). If "Locked" is selected, the selected KM TEQ option will not be changed when the macro is run again. This can be useful if the user wants to process
a few samples at a time, but not lose their selected options for previously processed data. Unlocking: although a blank cell cannot be selected by the drop-down box,
the "Locked" option can be removed by deleting the cell contents with the keyboard's DELETE button.
If no rejected data are present and no samples have a non-detect for the highest TEC, the macro will select "Section 1" in column AN for all samples.
If no rejected data are present and a sample does have a non-detect for the highest TEC, the macro will select either "Section 2 Treatment 1" or "Section 2
Treatment 2" in column AN, whichever is most conservative (highest KM TEQ). The other treatment should be selected if appropriate and justified (for example, if
Section 2 Treatment 1 is selected by the macro, the user may select Section 2 Treatment 2 if it is appropriate and justified).
Rejected data
If rejected data are present, the macro will select "Section 3" followed by "Treatment 1", "Treatment 2", "Treatment 3", or "Treatment 4" in column AN, whichever is
most conservative (highest KM TEQ). The most appropriate and justified TEQ should be selected, using the following considerations:
The results of the different treatments for handling "R" data should be compared to the decision threshold or used to calculate risk using appropriate risk assessment
methods.
• If the choice of treatment (from more to less conservative) significantly changes the decision outcome, sample reanalysis is advisable. To avoid repeated
generation of problematic data, ask the laboratory to take corrective action in the reanalysis.
Note 1
Note regarding TEQs in column AH:
Note that the result for the "TEQs from Substitution" in column AH (where NDs are counted as zero) should be the same as the Total TEQ value that is reported on
Contract Laboratory Program (CLP) forms (l-HR CDD-2).
Note 2
Note regarding sample qualifiers for KM TEQ results:
J-qualified
TEQ
All KM calculations include a determination of the TEC contribution to the TEQ from congener results that are qualified as non-detect, estimated or rejected.
If the contribution of these "qualified" TECs to the TEQ is greater than 50 percent, the KM TEQ result is qualified as "estimated, J". The qualifier is determined by the
macro, and is shown in a cell in the appropriate Section and Treatment(s), along with the fraction of the TEQ from "qualified" TECs. If a "J" is not needed, that cell will
be populated with "none".
Note 3
Note regarding TEFs:
Adjusting
TEFs
The TEFs used in the calculator are from the World Health Organization (WHO) 2005 report (Van den Berg 2006). If necessary, the user can change the TEF values
to earlier values, or to updated values when they become available. The TEFs can also be adjusted for additional sensitivity analysis if desired.
To update the TEFs, the user should unprotect the workbook, change the TEFs of concern and then rerun the macro.
Note 4
Note regarding minimum number of detected congeners:
Minimum
number of
congeners
There must be at least 3 detected congeners for the methodology in the KM TEQ calculator to be meaningful. If fewer than three detected congeners are present in
the results for a sample entered into the calculator, an error message will be displayed to the user. No KM TEQ calculations will be conducted for that sample. "Not
calculated" will be displayed in column AN, and a note will be displayed in column BE stating that fewer than three detected results were present. For discussion,
refer to the worksheet "KM Discussion" under "Treatment of Nondetected Congeners."
Note 5
Note regarding dioxin/furan contributions to sample TEQ:
D/F vs PCB
contributions to
total TEQ
In column AO, the "Dioxin/Furan" label on the third line for each sample refers to the percentage of TEQ contributed from dioxins and furans (the number is reported
in column AP). The remaining percentage (obtained by subtracting the D/F contribution from 100) is contributed from dioxin-like PCBs.
References
Helsel, D.R. 2009. "Summing Nondetects: Incorporating Low-Level Contaminants in Risk Assessment." Integrated Environmental Assessment and Management. Volume 6,
Number 3. Pages 361 through 366.
-------
Van den Berg, M. and others. 2006. "The 2005 World Health Organization Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and Dioxin-Like
Compounds." Toxicological Sciences. Volume 93, Number 2. Pages 223 through 241.
On-Line Address: http://epa-prgs.ornl.gov/chemicals/help/documents/vandenberg2006.pdf
For questions or suggestions about this Calculator, contact Deana Crumbling at USEPA, crumbling.deana@epa.gov, (703) 603-0643.
-------
EPA Advanced KM TEQ Calculator
Discussion: Calculation of Total Dioxin TEQs with Nondetect
and Rejected Congeners
Helsel's Kaplan-Meier Approach
Calculation of sums or totals for multi-constituent chemicals [e.g.; total dioxin TEQs,
total PC'Bs, total poly cyclic aromatic hydrocarbons (FAHs), etc.] has typically involved
simple substitution of zero, one-half the detection limit (DL), or the DL for left-censored
(nondetect or less-than values) congeners. Because this practice introduces bias to
estimates used in statistical calculations, however, many sources now strongly
recommend against the use of arbitrary surrogate values fornondetects (Helsel 1990,
2005a, 2005b, 2009: EPA 2006, 2009a, 2009b).
Helsel (2009) describes an approach for calculating totals using the KM product limit
estimator, which is based on the following relationship between the "mean" of the toxic
equivalence concentrations (TECs) and total TEQ for samples containing multiple
congeners:
total concentration = "mean" TEC x n (where n is the number of congeners)
Note that this "mean" TEC is an intermediate value in the calculation that has no
relationship to a mean TEQ for replicate DU samples. The KM estimator is a
nonparametric maximum likelihood estimator that has been widely used in survival and
failure analysis for more than 5 0 years (Kaplan and Meier 1958, Klein and Moeschberger
2003, Me eker and Es c ob ar 1998). Hi e KM e stim ator h as only re cently c am e into us e in
environmental assessment studies (Helsel 2005a), and is currently a default method used in
EPA's ProUCL software for calculating the 95% UCL of the mean for data with one or
more censored re suits (EPA 2009a, 2009b).
Treatment of Nondefected Congeners
For the purposes of this dioxinreassessmentUFP-QAPPtemplate,the intermediate KM
"mean" is recommended for use in calculating total dioxin TEQs, using the general
equation presented above, in all cases where a) some fraction of the congeners are
nondetect, and b) there are at least three detected congeners. Additional guidelines for
calculating the KM intermediate "mean" are provided below. If all congeners are detected,
then the intermediate "mean" calculatedbythe equationis the arithmetic average of all the
congeners' TECs.
How mam1 detected congeners are needed to calculate a TEQ?
If only one or two congeners are detected, then th ere is no statistically satisfactory method
for calculating the dioxin TEQ that adequately accounts for the uncertainty introduced by
nondetect congener results. In this case, the intermediate "mean" should be calculated as
Page 1 of 6
the congener in question, substitution of a value (straight substitution, an average of
several, or a maximum) from the other DUs may be made. Fortunately, many lab oratories
have lower detection limits for TCDD and TCDF than for the congeners with lower
TEFs, and this somewhat mitigates this problem.
the arithmetical average, where simple substitution is used fornondetects. A quasi-
sensitivity analysis approach is recommended, wherein substitution of both zero and the
DL are used to calculate lower- and upper-bound estimates for the total TEQ. Compare die
TEQs from both approaches to assess whether they have the same decision outcome.
Substitution of one-half the DL can be used to calculate a "middle-of-the-road" value,
although it should be acknowledged that the uncertainty of this estimate maybe
unacceptable for decisionmaking.
In cases where critical decisions hinge on total TEQ estimates with mostly nondetect
results, project teams are advised to consider
• consulting personnel with expertise in statistics,
• reanalyzing existing samples (if archived samples are available and meet holding
times),
• comparing with the results from nearby similar DUs and the CSM, or
• collecting additional samples.
The stepwise KM approach for calculating the total dioxin TEQ for individual samples is
described below:
Step 1. Calculate the TEC for each congener by multiplying the results for individual
congeners by their congener-specific TEF (van den Berg and others 2006). For
nondetect congeners, the reporting limit or DL should be multiplied by the TEF.
Step 2. Calculate the intermediate "mean" TEC for each sample using a KM calculator
spre a d sh eet. If all th e c ongen ers are d etecte cL th en c al cul ate th e interm edi ate
value as the arithmetic mean. If nondetects are present and at least three results
are detected, cal cul ate the KM interm edi ate using one of the options described
below. If only'one or two congeners are detected, use simple substitution and a
quasi-sensitivityanalysis approach, as discussed above.
Step 3. Calculate the total dioxin TEQ using: Total TEQ = interm edi ate "mean" TEC x
n, where n is the number of congeners in the calculation.
Helsel (2009) discusses several potential contraindications for calculation ofthe KM
mean. The first concerns cases where only a single DL is used for all nondetect
congeners. This is not expected to occur for calculation of total dioxin TEQs, since
results for individual congeners are first multiplied by congener-specific TEFs. The
second contraindication is when the maximum reported result is a nondetect, high-
toxicity (i.e., TEF close to 1) congener. This is problematic, as the KM method will
effectively ignore maximum results that are censored. Helsel (2009) suggests that the DL
be substituted in tliese cases, but that it should be acknowledged that this represents a
worst-case scenario. Another option is to compare the congener concentration and
congener profile ofthe sample with a high TEF nondetect to results from similar (per the
CSM) DUs. If the congener profiles are similar, but the other DUs have a detection for
Page 2 of 6
(3) Commercial or other statistical software. The KM model is included in many*
mainstream statistical software packages, as well as public domain (including the R
language) programs. Helsel (2005 a) discusses an approach for "flipping" data for
-------
Helsei (2009) does not discuss the minimum number of detected results required to
estimate the KM mean, but a practical minimum of three detected results is
recommended. Cases where only one or two congeners are detected are discussed above.
Lastly, Helsel (2009) recommends that for left-censored environmental data, Eiron's
method should always be used This simply requires that the minimum result always be
treated as a detected result The manner in which Efraf s method is incorporated in
calculations of the KM mean depends on the specific software or approach used. For
example, for programs that require a "flag" to distinguish between detected and nondetect
data, one only needs to use the appropriate flag for detected data to qualify the minimum
result(s).
Three options are described below for calculation of the KM mean:
(1) HelseTs KM Excel spreadsheet model (available from www.practicalstat5.com).
This spreadsheet has been built into a workbook designed specifically for calculating
the TEQ from raw data congener concentration data. Raw data are entered into one
spreadsheet, which automatically calculates the toxic equivalent concentration
(TEC) for each congener. The TECs are copied and pasted by a macro into a second
spreadsheet in the workbook that performs the KM calculation. This produces an
intermediate value (the KM "mean7") which is transferred by the macro back to the
first spreadsheet. The intermediate result is then automatically multiplied by the
number of congeners to produce the total TEQ for the sample. Detailed instructions
for using the spreadsheets are included in the Excel workbook s spreadsheets.
(2) Alternatively, EPA's ProUCL software maybe used Before estimates of the KM
intermediate "mean" TEC" can be calculated., the congener concentration, results (in
ppt) must be converted to congener TECs by multiplying each congener by its TEF.
This must be done independently before the TECs are put into ProUCL for the KM
calculation. (ProUCL cannot do the TEC calculation.) The TEC's are then entered
into ProUCL and the KM intermediate "mean" is automatically calculated for data
sets with one or more nondetect results. EPA (2009a, 2009b) should be consulted
for instructions for entering data into ProUCL, since a coding procedure must be
used in ProUCL to "tell it" which congener TECs were fromXD values. Note that
in order to use Efron's method, the minimum result should be coded as a detected
result. If intermediate "means" are required for multiple samples, then each sample
needs to be identified using a "grouping" variable (see EPA 2009a). For each
sample, the KM intermediate "mean" will need to be extracted from the ProUCL
report, and manually multiplied by the number of congeners to produce the total
TEQ result for that sample.
Page 3 of 6
Treatment ofEMPC values and qualified dara
EPA's Contract Laboratory Program Statement of Work (CLP SOW) for dioxin analysis
specifies the reporting of detected congeners as "EMPC" values ("estimated maximum
possible concentration" • when a congener peak is present at an acceptable signal-to-noise
ratio, but ion abundance criteria are not met for definitive identification of that congener.
The CLP SOW excludes these values from the calculation of TEQ. EPA Method 8290A
also specifies the reporting ofEMPC values butmakesno recommendations concerning
their use in TEQ calculations. EMPC values are generally qualified as estimated
concentrations ("J") or nondetect values ("U") during data validation in accordance with
EPA Functional Guidelines. When qualified "J", EMPC values can be applied along
.—t Trn — ri
use in commercial packages, which emphasize treatment of right-censored data
Experienced users may elect to use alternative approaches for calculation of the KM
intermediate "mean," but must use methods employing Efrori s method, and must
demonstrate that results are comparable to the intermediate "means" calculated using
Options (1) or (2) above.
Treatment of R-Quatifled Congeners
One additional component for assesang the uncertainty of estimates of the intermediate
KM "mean" and total TEQ, concerns treatment of rej ected(Unqualified) data. It is
possible to reject individual congener analytes based on ion abundance, the signal-to-
noise ratio, relative retention time, a low laboratory control sample result, gross blank
contamination, or other analyte-specific criteria. For non-dioxin individual chemicals
with multiple-sample sample sets (i.e., sufficient sample-sizes to support calculations),
rejected data are always excluded from calculations in environmental assessments.
However, for calculation of the "mean" (and total) for a set of congeners, there is concern
that exclusion of rejected data may bias estimates low or create a need for replacement
data (resampling or re analysis). The magnitude (and importance) of this bias will of
course depend on the values reported for R-qualified data and the overall dioxin
concentration in relation to decision-making thresholds, as well as the congener-specific
TEFs.
Although rejected data shouldnotbe included in final calculations of TEQ for a given
sampling or decision unit, rej ected data values (concentrations or detection limits) can be
included in KM ""mean" and total TEQ calculations early in the data evaluation process.
These TEQs can be compared to TEQs calculated with the rejected values removed. This
quasi-sensitivity approach, similar to that recommended above for nondetect values, will
assist project teams in assessing the magnitude of impacts fromrejected data and the need
for replacement data (Replacement data may require re analysis of samples at the
laboratory, with laboratory corrective actions or method refinements as needed, or the
collection of additional samples from the site). Rejected data can be further evaluated
through professional judgment, such as whether a rej ected congener may be present at a
concentration that could affect the TEQ based on historical site information or data from
surrounding decision units. For example, project teams could use the KM calculator to
further assess how high the concentration of a rejected congener would have to be to
affect the TEQ, andthen compare this estimate to concentrations for this congener that
are present in other decision units, or in comparable historical data sets.
(continued)
Page 4 of 6
Kaplan, E.L., and P. Meier. 195S. "Nonparametric Estimator from Incomplete
Observations." Journal of the American Statistical Association. Volume 53. Pages
457 through 481.
Klein, J.P., and MX. Moeschberger. 2003. Survival Analysis— Techniques for
Censored and Truncated Data. 2nd Edition. Statistics for Biology and Health,
Springer Verlag. 5 60 pages.
Meeker, W.Q.. and L.A. Escobar. 1998. Statistical Methods fear Reliability Data. Wiley
Series in Probability and Statistics. John Wiley & Sons, Inc. New York, New
"V71"} T\a fT^ac
-------
mm oiner j-quaimea congener results in ity caicuiauon anansjc assessment i. j-
qualified data are generally applied like unqualified data under EPA risk assessment
protocols)- EMPC values qualified "XT' can be treated as other nondetect values using
the KM approach described above. Given that use of EMPC values may overestimate die
TEQ and associated dioxinrisk, project teams may again elect to perform a quasi-
sensitivity analysis by calculating TEQ without the EMPC values. As for rejected data,
significant effects from EMPC values may require corrective action to improve data
quality (such as sample reanalysis).
Therefore, for congeners that are influential (high-toxicity, TEF close to 1, or high
concentration) in calculations of the intermediate "mean" and total TEQ, rejected and
qualified data may re quire further evaluation by project teams. The uncertainty of
calculating total TEQs, as can be demonstrated through sensitivity analyses, shouldbe
addressed in the uncertainty section of assessment documents, and taken into account in
decision making.
References
HelseL D.R. 1990. Less than obvious, statistical treatment of data below the detection
limit. Environmental Science and Technology. Volume 24, Number 12. Pages
1767 through 1774.
HelseL D.R. 2005 a. Nondetecte and Dam Analysis. Statistics for Censored
Environmental Data. John Wiley and Sons, Inc. Hoboken, NJ. 250pages.
HelseL D.R 2005b. "More than Obvious: Better Methods for InterpretingNondetect
Data."' Environmental Science and Technology. Volume 39, Number 20. Pages
419 A throu gh 423A.
Helsel, D.R. 2009. "Summing Nondelects Incorporating Low-Level Contaminants in
Risk Assessment." Integrated Environmental Assessment and Management.
Volume 6, Number 3. Pages 361 through 366.
Page 5 of 6
I UIA. f l.t, pd.gC3w
U.S. Environmental Protection Agency (EPA). 2006. "On the Computation of a 95%
Upper Confidence Limit of the Unknown Population Mean Based Upon Data Sets
with Below Detection Limit Observations." Singh, A., Maichle, R., and S.E. Lee.
EPA 600 R-06 022. March.
EPA. 2009a. "ProUCL Version 4.00.04 Technical Guide (Draft)." Prepared by A. Singh
and A.K. Singh. EPA 600 R-07 041. February.
EPA. 2009b. "ProUCL Version 4.00.04 User Guide (Draft)." Singh, A., R_ Maichle,
A.K. Singh, S.E. Lee, andN. Armbya. Office of Research and Development,
National Exposure Research Liberators'. EPA 600 R-07 03S. February.
Van den Berg, M. and others. (2006). "The 2005 World Health Organization
Reevaluation of Human and Mammalian Toxic Equivalency Factors for Dioxins and
Dioxin-Like Compounds." ToxicologicalSciences. Volume 93, Number 2. Pages
223 through 241. On-Line Address: http: epa-
prgs.oml.gov chemicals help documents vandenberg2006.pdf
Page 6 of 6
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
7/17/2014
Chemical Sort Order:
WHO 2005 TEFs =
0.1
0.1
0.1
0.01
0.0003
0.1
Sample notes
Sample ID:
(must enter on Row A)
/
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
protect/unprotect sheet password = dioxin
Matrix:
Soil
Data entered by:
R. Tisdale
ch'd by DMC 30Jul14
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
SITE DATA
performing quasi-sensitivity analyses
Chemical Sort Order: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
WHO 2005 TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
Sample notes
Sample ID:
(must enter on Row A)
/
"
J
SFRA-12: Row A
1080
3.16 U
3.48 U
6.8 J
3.75 J
163
4260
7.82 J
4.32 U
2.59 U
3.03 U
3.14 U
5.03 U
3.12 U
20.8 J
3.16 U
value to use: Row B
1080
3.16
3.48
6.8
3.75
163
4260
7.82
4.32
2.59
3.03
3.14
5.03
3.12
20.8
3.16
8
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
1080
3.16
0.348
0.68
0.375
1.63
1.278
0.782
0.1296
0.777
0.303
0.314
0.503
0.312
0.208
0.0316
SFRA-13: Row A
3080
6.1 U
14.6 U
19.1 J
15.3 U
367
5030
20.7
7.27 J
5.44 U
5.03 U
5.01 U
8 U
5.19 U
66.3
11.3 U
value to use: Row B
3080
6.1
14.6
19.1
15.3
367
5030
20.7
7.27
5.44
5.03
5.01
8
5.19
66.3
11.3
9
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
3080
6.1
1.46
1.91
1.53
3.67
1.509
2.07
0.2181
1.632
0.503
0.501
0.8
0.519
0.663
0.113
SFRA-14: Row A
5670
19.9 U
25.9 U
24.8 U
25.9 U
216 J
2800
34.9 J
14.5 U
10.6 U
13.4 U
11.9 U
23.8 U
14.3 U
53.4 J
35.2 U
value to use: Row B
5670
19.9
25.9
24.8
25.9
216
2800
34.9
14.5
10.6
13.4
11.9
23.8
14.3
53.4
35.2
10
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
5670
19.9
2.59
2.48
2.59
2.16
0.84
3.49
0.435
3.18
1.34
1.19
2.38
1.43
0.534
0.352
SFRA-15: Row A
17400
23.5 U
31.1 U
150 J
49.1 J
1100
7790
106 J
20 U
21.2 U
19 U
17.7 U
24.2 U
20.2 J
235 J
52.9 U
value to use: Row B
17400
23.5
31.1
150
49.1
1100
7790
106
20
21.2
19
17.7
24.2
20.2
235
52.9
11
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
17400
23.5
3.11
15
4.91
11
2.337
10.6
0.6
6.36
1.9
1.77
2.42
2.02
2.35
0.529
SFRA-16: Row A
3710
3.54 U
11 U
15 J
11.5 U
219
4430
24.3
5.67 J
3.56 U
4.31 J
2.7 U
3.88 U
4.16 J
44.1 J
9.25 U
value to use: Row B
3710
3.54
11
15
11.5
219
4430
24.3
5.67
3.56
4.31
2.7
3.88
4.16
44.1
9.25
12
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
3710
3.54
1.1
1.5
1.15
2.19
1.329
2.43
0.1701
1.068
0.431
0.27
0.388
0.416
0.441
0.0925
SFRA-17: Row A
4.46 U
2.98 U
4.51 U
4.75 U
4.77 U
60.6
2810
1.91 U
2.01 U
2.04 U
3.23 U
3.14 U
4.9 U
3.27 U
4.84 U
7.67 U
value to use: Row B
4.46
2.98
4.51
4.75
4.77
60.6
2810
1.91
2.01
2.04
3.23
3.14
4.9
3.27
4.84
7.67
13
congener TEC: Row C
4.46
2.98
0.451
0.475
0.477
0.606
0.843
0.191
0.0603
0.612
0.323
0.314
0.49
0.327
0.0484
0.0767
donor value to use: Row D
donor TEC: Row E
14
SFRA-18: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
4830
4830
4830
5.97 U
5.97
5.97
13 U
13
1.3
15.7 J
15.7
1.57
12.9 U
12.9
1.29
286
286
2.86
2890
2890
0.867
40.1
40.1
4.01
18.1 J
18.1
0.543
8.79 U
8.79
2.637
8.68 U
8.68
0.868
7.97 U
7.97
0.797
13.3 U
13.3
1.33
8.92 U
8.92
0.892
71.5 J
71.5
0.715
16.9 U
16.9
0.169
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
performing quasi-sensitivity analyses
Chemical Sort Order:
1
2
3
4
5
h-
(O
8
1
1
0.1
0.1
0.1
0.01 0.0003
0.1
/
3200
3200
3200
2.57 U
2.57
2.57
4.59 J
4.59
0.459
27.9 J
27.9
2.79
10.4 J
10.4
1.04
482 11300
482 11300
4.82 3.39
27.8
27.8
2.78
Sample notes
31
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
32
33
34
35
36
37
38
SFRA-39: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-40: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-41: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-42: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-43: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-44: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-45: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-46: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
163
3.72 U
56.3 J
87.8
23.5 J
1880
21500
4.93 J
163
3.72
56.3
87.8
23.5
1880
21500
4.93
163
3.72
5.63
8.78
2.35
18.8
6.45
0.493
13300
13300
13300
6160
6160
6160
20700
20700
20700
14000
14000
14000
10600
10600
10600
30700
30700
30700
13.1 U
13.1
13.1
13.3 U
13.3
13.3
20.5 U
20.5
20.5
13.2 U
13.2
13.2
15.3 U
15.3
15.3
17.2 U
17.2
17.2
23.7 J
23.7
2.37
24.2 U
24.2
2.42
31.6 J
31.6
3.16
31.2 J
31.2
3.12
28.4 U
28.4
2.84
77.3 U
77.3
7.73
88.5 J
88.5
8.85
40.5 J
40.5
4.05
57.2 J
57.2
5.72
233 J
233
23.3
40.2 J
40.2
4.02
100 J
100
10
28.5 J
28.5
2.85
26.7 U
26.7
2.67
29.7 U
29.7
2.97
72.1 J
72.1
7.21
30.1 U
30.1
3.01
79 U
79
7.9
1280
1280
12.8
766
766
7.66
952
952
9.52
2160
2160
21.6
605
605
6.05
1060
1060
10.6
14500
14500
4.35
13900
13900
4.17
13400
13400
4.02
15500
15500
4.65
11800
11800
3.54
13000
13000
3.9
69.1 J
69.1
6.91
33.6 J
33.6
3.36
94 J
94
9.4
86.4 J
86.4
8.64
56.6 J
56.6
5.66
137 J
137
13.7
protect/unprotect sheet password = dioxin
ch'd by DMC 30Jul14
SITE DATA
9
10
11
12
13
14
15
16
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
/
/
/
.°r
/
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
protect/unprotect sheet password = dioxin
Matrix:
Soil
Data entered by:
R. Tisdale
ch'd by DMC 30Jul14
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
SITE DATA
performing quasi-sensitivity analyses
Chemical Sort Order: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
WHO 2005 TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
Sample notes
Sample ID:
(must enter on Row A)
/
"
J
39
SFRA-47: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
4310
4310
4310
2.89 U
2.89
2.89
5.93 U
5.93
0.593
6.06 U
6.06
0.606
6.36 U
6.36
0.636
153
153
1.53
7910
7910
2.373
19.7 J
19.7
1.97
1.77 U
1.77
0.0531
1.69 U
1.69
0.507
2.31 U
2.31
0.231
2.18 U
2.18
0.218
3.81 U
3.81
0.381
2.35 U
2.35
0.235
16.9 J
16.9
0.169
3.08 U
3.08
0.0308
40
SFRA-48: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
7320
7320
7320
8.22 U
8.22
8.22
16.2 U
16.2
1.62
27.3 U
27.3
2.73
16.2 U
16.2
1.62
408
408
4.08
9930
9930
2.979
51.6 J
51.6
5.16
5.83 U
5.83
0.1749
5.85 U
5.85
1.755
10.8 U
10.8
1.08
10.5 U
10.5
1.05
20.2 U
20.2
2.02
11 U
11
1.1
101 J
101
1.01
15.3 U
15.3
0.153
41
SFRA-49: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
1410
1410
1410
1.78 U
1.78
1.78
7.61 J
7.61
0.761
11.5 J
11.5
1.15
5.39 J
5.39
0.539
270
270
2.7
8070
8070
2.421
8.8 J
8.8
0.88
2.22 U
2.22
0.0666
2.02 U
2.02
0.606
5 J
5
0.5
1.84 J
1.84
0.184
2.31 U
2.31
0.231
2.41 U
2.41
0.241
43.1 J
43.1
0.431
3.41 J
3.41
0.0341
42
SFRA-50: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
2650
2650
2650
3.51 U
3.51
3.51
17.8 J
17.8
1.78
57.7
57.7
5.77
17.9 J
17.9
1.79
642
642
6.42
12100
12100
3.63
19.1
19.1
1.91
14.9 J
14.9
0.447
3.21 J
3.21
0.963
13.1 J
13.1
1.31
5.45 J
5.45
0.545
2.93 U
2.93
0.293
7.39 J
7.39
0.739
106
106
1.06
9.14 J
9.14
0.0914
SFRA-51: Row A 4380 7.73 U 15.6J 29.3 J 13.2U 533 12500 26.2 J 9.77 U 9.51 U 13.2U 7.71 U 14U 8.01 U 96.7 J 11.5U
value to use: Row B 4380 7.73 15.6 29.3 13.2 533 12500 26.2 9.77 9.51 13.2 7.71 14 8.01 96.7 11.5
43 congener TEC: RowC 4380 7.73 1.56 2.93 1.32 5.33 3.75 2.62 0.2931 2.853 1.32 0.771 1.4 0.801 0.967 0.115
donor value to use: Row D
donor TEC: Row E
SFRA-52: Row A
2400
2.31 J
3.2 J
13 J
6.06 J
262
7840
13.9
1.39 U
2.53 J
2.91 J
1.9 J
2.04 U
2.91 J
45 J
2.89 U
value to use: Row B
2400
2.31
3.2
13
6.06
262
7840
13.9
1.39
2.53
2.91
1.9
2.04
2.91
45
2.89
44
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
2400
2.31
0.32
1.3
0.606
2.62
2.352
1.39
0.0417
0.759
0.291
0.19
0.204
0.291
0.45
0.0289
SFRA-53: Row A
42600
26.9 U
48.4 U
45.4 U
49.4 U
904 J
15700
186 J
19.4 U
19.2 U
22 U
21.5 U
42 U
24.2 U
156 J
41 U
value to use: Row B
42600
26.9
48.4
45.4
49.4
904
15700
186
19.4
19.2
22
21.5
42
24.2
156
41
45
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
42600
26.9
4.84
4.54
4.94
9.04
4.71
18.6
0.582
5.76
2.2
2.15
4.2
2.42
1.56
0.41
SFRA-54: Row A
19700
8.16 U
21.1 U
23.3 J
21.5 U
848
23700
81.4 J
5.12 U
4.87 U
6.1 U
6.55 U
11.1 U
6.48 U
140 J
21.6 U
value to use: Row B
19700
8.16
21.1
23.3
21.5
848
23700
81.4
5.12
4.87
6.1
6.55
11.1
6.48
140
21.6
46
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
19700
8.16
2.11
2.33
2.15
8.48
7.11
8.14
0.1536
1.461
0.61
0.655
1.11
0.648
1.4
0.216
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
Data entered by:
Date entered:
R. Tisdale
PG/G
7/17/2014
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
Jo' ^ ^
16.1 U
16 U
33.2 U
19.3 J
37.5 U
22.1 U
453 J
38.7 U
16.1
16
33.2
19.3
37.5
22.1
453
38.7
0.483
4.8
3.32
1.93
3.75
2.21
4.53
0.387
11.1 U
23.6 U
39.2 J
30.6 U
36.7 U
40.3 J
937
95 J
11.1
23.6
39.2
30.6
36.7
40.3
937
95
0.333
7.08
3.92
3.06
3.67
4.03
9.37
0.95
1.49 U
1.65 U
4.35 J
2.66 U
3.66 U
4.02 J
148
11.3 J
1.49
1.65
4.35
2.66
3.66
4.02
148
11.3
0.0447
0.495
0.435
0.266
0.366
0.402
1.48
0.113
7.89 U
12.9 U
13.1 U
13.3 U
18.5 U
19.8 J
251 J
21.3 J
7.89
12.9
13.1
13.3
18.5
19.8
251
21.3
0.2367
3.87
1.31
1.33
1.85
1.98
2.51
0.213
1.25 J
3.14 J
3.53 U
3 U
1.55 U
4.51 U
81.9
4.97 J
1.25
3.14
3.53
3
1.55
4.51
81.9
4.97
0.0375
0.942
0.353
0.3
0.155
0.451
0.819
0.0497
4.62 U
6.34 J
5.41 U
5.61 U
8.56 U
5.94 U
123 J
12 J
4.62
6.34
5.41
5.61
8.56
5.94
123
12
0.1386
1.902
0.541
0.561
0.856
0.594
1.23
0.12
0.881 U
1.98 U
2.73 U
2.4 U
3.72 U
3.1 U
88.3
4.22 U
0.881
1.98
2.73
2.4
3.72
3.1
88.3
4.22
0.02643
0.594
0.273
0.24
0.372
0.31
0.883
0.0422
2.87 J
4.73 J
5.3 U
4.61 J
4.31 U
5.25 J
61.8
7.81 U
2.87
4.73
5.3
4.61
4.31
5.25
61.8
7.81
0.0861
1.419
0.53
0.461
0.431
0.525
0.618
0.0781
0.562 U 0.522 U 0.649 U 0.645 U 1.01 U 0.667 U 0.798 J 1 U
0.562 0.522 0.649 0.645 1.01 0.667 0.798 1
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
protect/unprotect sheet password = dioxin
Matrix:
Soil
Data entered by:
R. Tisdale
ch'd by DMC 30Jul14
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
SITE DATA
performing quasi-sensitivity analyses
Chemical Sort Order: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
WHO 2005 TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
Sample notes
Sample ID:
(must enter on Row A)
/
"
J
55
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
2.72
1.12
0.125
0.133
0.137
0.203
2.415
0.0887
0.01686
0.1566
0.0649
0.0645
0.101
0.0667
0.00798
0.01
56
SFRA-64: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
5.86 J
5.86
5.86
1.55 U
1.55
1.55
1.75 U
1.75
0.175
1.85 U
1.85
0.185
1.86 U
1.86
0.186
69.5
69.5
0.695
6700
6700
2.01
1.06 U
1.06
0.106
0.818 U
0.818
0.02454
0.759 U
0.759
0.2277
1.11 U
1.11
0.111
0.919 U
0.919
0.0919
1.45 U
1.45
0.145
0.966 U
0.966
0.0966
7.36 J
7.36
0.0736
1.24 U
1.24
0.0124
57
SFRA-65: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
32.6
32.6
32.6
1.74 U
1.74
1.74
2.38 U
2.38
0.238
4.38 U
4.38
0.438
2.49 U
2.49
0.249
186
186
1.86
32700
32700
9.81
1.05 U
1.05
0.105
0.722 U
0.722
0.02166
0.724 U
0.724
0.2172
1.51 U
1.51
0.151
1.43 U
1.43
0.143
2.22 U
2.22
0.222
1.43 U
1.43
0.143
9.79 J
9.79
0.0979
2.99 U
2.99
0.0299
58
SFRA-66: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
238
238
238
2.88 U
2.88
2.88
3.43 J
3.43
0.343
13.4 J
13.4
1.34
5.81 J
5.81
0.581
363
363
3.63
19300
19300
5.79
2.55 J
2.55
0.255
1.44 U
1.44
0.0432
1.42 U
1.42
0.426
3.43 U
3.43
0.343
2.02 U
2.02
0.202
3.28 U
3.28
0.328
2.43 U
2.43
0.243
51.9 J
51.9
0.519
3.73 J
3.73
0.0373
59
SFRA-67: Row A
value to use: Row B
congener TEC: Row C
3.15 U
3.15
3.15
1.69 U
1.69
1.69
1.75 U
1.75
0.175
1.8 U
1.8
0.18
1.89 U
1.89
0.189
23 J
23
0.23
1900
1900
0.57
0.915 U
0.915
0.0915
0.75 U
0.75
0.0225
0.761 U
0.761
0.2283
0.803 U
0.803
0.0803
0.767 U
0.767
0.0767
1.19 U
1.19
0.119
0.786 U
0.786
0.0786
0.892 U
0.892
0.00892
1.37 U
1.37
0.0137
donor value to use: Row D
donor TEC: Row E
60
61
SFRA-68: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-69: Row A
value to use: Row B
congener TEC: Row C
141
141
141
1.25 U
1.25
1.25
2.83 U
2.83
2.83
1.75 U
1.75
1.75
3.14 U
3.14
0.314
2.36 U
2.36
0.236
9.53 J
9.53
0.953
2.31 U
2.31
0.231
5.59 J
5.59
0.559
2.47 U
2.47
0.247
271
271
2.71
20.8 J
20.8
0.208
8220
8220
2.466
3360
3360
1.008
2.59 U
2.59
0.259
1.15 U
1.15
0.115
1.84 J
1.84
0.0552
0.783 U
0.783
0.02349
1.68 U
1.68
0.504
0.753 U
0.753
0.2259
2.85 U
2.85
0.285
1.14 U
1.14
0.114
2.9 U
2.9
0.29
1.13 U
1.13
0.113
4.21 U
4.21
0.421
1.85 U
1.85
0.185
2.83 U
2.83
0.283
1.15 U
1.15
0.115
31.5 J
31.5
0.315
1.35 U
1.35
0.0135
3.48 U
3.48
0.0348
2.03 U
2.03
0.0203
donor value to use: Row D
donor TEC: Row E
62
SFRA-70: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
89.1
89.1
89.1
1.9 U
1.9
1.9
2.97 U
2.97
0.297
6.54 J
6.54
0.654
3.53 J
3.53
0.353
184
184
1.84
11100
11100
3.33
1.6 U
1.6
0.16
1.56 U
1.56
0.0468
1.57 U
1.57
0.471
1.65 J
1.65
0.165
1.55 U
1.55
0.155
2.43 U
2.43
0.243
1.61 U
1.61
0.161
23.6 J
23.6
0.236
2.97 U
2.97
0.0297
63
SFRA-71: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
1.27 U
1.27
1.27
1.52 U
1.52
1.52
2.21 U
2.21
0.221
2.26 U
2.26
0.226
2.38 U
2.38
0.238
84.3
84.3
0.843
10800
10800
3.24
1.32 U
1.32
0.132
0.908 U
0.908
0.02724
0.888 U
0.888
0.2664
0.725 U
0.725
0.0725
0.668 U
0.668
0.0668
1.13 U
1.13
0.113
0.701 U
0.701
0.0701
0.975 U
0.975
0.00975
1.58 U
1.58
0.0158
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
64
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
K*r
/
0.01 0.0003 0.1
/
N*" 0°
65
66
67
68
69
70
71
donor TEC: Row E
SFRA-72: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-73: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-74: Row A
value to use: Row B
congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
SFRA-75: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-76: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-77: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-78: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-79: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-80: Row A
573
9.06 J
54.1 QU
964 Q
405 Q
9020
52500
12.2 J
573
9.06
54.1
964
405
9020
52500
12.2
573
9.06
5.41
96.4
40.5
90.2
15.75
1.22
3090
4.57 U
5.88 U
65
24.7 J
896
14000
21.1
3090
4.57
5.88
65
24.7
896
14000
21.1
3090
4.57
0.588
6.5
2.47
8.96
4.2
2.11
12000
13.4 U
22.8 QU
171 JQ
51.6 J
1260
13600
64.4 J
12000
13.4
22.8
171
51.6
1260
13600
64.4
12000
13.4
2.28
17.1
5.16
12.6
4.08
6.44
4690
6.24 U
10.5 QU
125 JQ
35.1 J
1300
18800
30.1 J
4690
6.24
10.5
125
35.1
1300
18800
30.1
4690
6.24
1.05
12.5
3.51
13
5.64
3.01
941
2.65 U
6.09 U
12.5 U
6.55 U
172
17400
6.18 J
941
2.65
6.09
12.5
6.55
172
17400
6.18
941
2.65
0.609
1.25
0.655
1.72
5.22
0.618
1020
4.79 U
8.93 U
28.9 J
10.1 J
485
23800
10 J
1020
4.79
8.93
28.9
10.1
485
23800
10
1020
4.79
0.893
2.89
1.01
4.85
7.14
1
2430
3.9 J
9.23 QU
124 Q
36.7 J
821
8100
14.3
2430
3.9
9.23
124
36.7
821
8100
14.3
2430
3.9
0.923
12.4
3.67
8.21
2.43
1.43
1500
4.09 U
11.7 QU
69.8 Q
16.8 J
449
5060
9.31 J
1500
4.09
11.7
69.8
16.8
449
5060
9.31
1500
4.09
1.17
6.98
1.68
4.49
1.518
0.931
745
3.45 U
7.73 U
28.4 J
8.23 U
391
8240
4.21 J
protect/unprotect sheet password = dioxin
ch'd by DMC 30Jul14
SITE DATA
0.03
J**
10
0.3
'
/
14
0.1
/
J*
15
16
0.01 0.01
OS
.1sr °r
c?
6.15 J 19.7 J 117 Q 55.5 J 17.3 U 92.4 1200 116
6.15 19.7 117 55.5 17.3 92.4 1200 116
0.1845 5.91 11.7 5.55 1.73 9.24 12 1.16
2.92 U 4.18 J
2.92 4.18
0.0876 1.254
7.56 J 6.08 J
7.56 6.08
0.756 0.608
4.72 U 8.08 J
4.72 8.08
0.472 0.808
204 13.1 J
204 13.1
2.04 0.131
11.9 U 11.8 U
11.9 11.8
0.357 3.54
20.9 U 22 U
20.9 22
2.09 2.2
18.8 U 17.6 J
18.8 17.6
1.88 1.76
330 J 24.4 U
330 24.4
3.3 0.244
4.05 U 7.69 U
4.05 7.69
0.1215 2.307
12.1 U 9.47 U
12.1 9.47
1.21 0.947
10.8 U 11.9 J
10.8 11.9
1.08 1.19
286 20.4 J
286 20.4
2.86 0.204
2.26 U 2.13 U
2.26 2.13
0.0678 0.639
3.02 U 2.95 U
3.02 2.95
0.302 0.295
5.1 U 3.04 U
5.1 3.04
0.51 0.304
31 J 5.6 U
31 5.6
0.31 0.056
3.03 U 2.98 U
3.03 2.98
0.0909 0.894
6.44 J 4.96 J
6.44 4.96
0.644 0.496
5.93 U 3.75 U
5.93 3.75
0.593 0.375
98.4 7.99 U
98.4 7.99
0.984 0.0799
2.45 J 5.93 J
2.45 5.93
0.0735 1.779
8.82 J 5.78 J
8.82 5.78
0.882 0.578
5.4 U 13 J
5.4 13
0.54 1.3
194 13 J
194 13
1.94 0.13
4.2 U 4.09 U
4.2 4.09
0.126 1.227
5.28 U 4.93 U
5.28 4.93
0.528 0.493
5.17 U 4.84 U
5.17 4.84
0.517 0.484
105 7.54 J
105 7.54
1.05 0.0754
2.69 U 2.55 U 4.31 U 3.81 U 6.38 U 4.55 U 97.9 7.26 U
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.1
0.1
0.1
0.01
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
protect/unprotect sheet password = dioxin
Matrix:
Soil
Data entered by:
R. Tisdale
ch'd by DMC 30Jul14
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
SITE DATA
performing quasi-sensitivity analyses
Chemical Sort Order: 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16
WHO 2005 TEFs =
1
1
0.1
0.1
0.1
0.01
0.0003
0.1
0.03
0.3
0.1
0.1
0.1
0.1
0.01
0.01
Sample notes
Sample ID:
(must enter on Row A)
/
-------
EPA Advanced KM
TEQ Calculator
Project Name:
Strecker Forest Remedial Action
Matrix:
Soil
Data entered by:
R. Tisdale
Advanced KM TEQ calculator for
Units:
PG/G
Date entered:
7/17/2014
performing quasi-sensitivity analyses
Chemical Sort Order:
WHO 2005 TEFs =
0.1
0.1
0.1
0.01
0.0003
0.1
Sample notes
89
Sample ID:
(must enter on Row A)
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
PG/G
Data entered by:
Date entered:
R. Tisdale
7/17/2014
Sample notes
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
/
0.1 0.1 0.1 0.01 0.0003
0.1
^ ^ ^ _
o?- oc*- ^r
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Project Name:
Matrix:
Units:
Strecker Forest Remedial Action
Soil
PG/G
Data entered by:
Date entered:
R. Tisdale
7/17/2014
Sample notes
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
/
0.1 0.1 0.1 0.01 0.0003
0.1
^ ^ ^ _
o?- oc*- ^r
-------
EPA Advanced KM
1 cw OdlUUIdlUI
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
17
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Sample notes
Chemical Sort Order:
Treatment 1
Treatment 1:
Make highest U value a D
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.0003
<
/
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
KM Method
U = 0 &
sum
U = 1/2 DL
& sum
U = DL &
sum
Sample KM
TEQ
Qualifier
Select KM TEQ
KM TEQ
Qualifier and Qualifier
Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-5: Row A
61.3
value to use: Row B
61.3
1
congener TEC: Row C
0.01839
9%
12.7503
13.3854
14.0206
13.0999
none
Section 1
13.0999
none
donor value to use: Row D
Locked
Qualified
30%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-6: Row A
3.04 J
value to use: Row B
3.04
2
congener TEC: Row C
0.000912
15%
4.3976
4.7474
5.0972
4.4553
none
Section 1
4.4553
none
donor value to use: Row D
Locked
Qualified
18%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-7: Row A
40.7 J
value to use: Row B
40.7
3
congener TEC: Row C
0.01221
1%
1082.8886
1087.0776
1091.2666
1084.4930
none
Section 1
1084.4930
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-8: Row A
229 J
value to use: Row B
229
4
congener TEC: Row C
0.0687
0%
10331.5407
10335.4975
10339.4543
10333.6015
none
Section 1
10333.6015
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-9: Row A
131 J
value to use: Row B
131
5
congener TEC: Row C
0.0393
0%
3590.7892
3593.72185
3596.6545
3592.3260
none
Section 1
3592.3260
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-10: Row A
0.761 J
value to use: Row B
0.761
6
congener TEC: Row C
0.0002283
4%
6.8703283
7.0110743
7.1518203
6.8892
none
Section 1
6.8892
none
donor value to use: Row D
Locked
Qualified
7%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-11: Row A
125 J
value to use: Row B
125
7
congener TEC: Row C
0.0375
0%
4950.6085
4958.3045
4966.0005
4953.8700
none
Section 1
4953.8700
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
10
11
12
13
14
17
WHO 2005 TEFs =
0.0003
bummary ot
Sensitivity
TEQs from Substitution
KM Method
Treatment 1
i iccmiiciii i.
Make highest U value a D
<
Analysis
(relative
Sample ID:
00«
percent
U = 0 &
U = 1/2 DL
U = DL &
Sample KM
Qualifier and Qualifier
Qualifier and
(must enter on Row A)
o
difference)
sum
& sum
sum
TEQ
Qualifier Select KM TEQ
KM TEQ
Fractions
KM TEQ Qualifier Fractions
SFRA-12: Row A
49.4 J
value to use: Row B
49.4
congener TEC: Row C
0.01482
1%
1084.9678
1087.9069
1090.8460
1085.8649
none Section 1
1085.8649
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-13: Row A
213
value to use: Row B
213
congener TEC: Row C
0.0639
0%
3090.1040
3096.6830
3103.2620
3092.3211
none Section 1
3092.3211
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-14: Row A
90.6 J
value to use: Row B
90.6
congener TEC: Row C
0.02718
1%
5677.0512
5695.9847
5714.9182
5681.1709
none Section 1
5681.1709
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-15: Row A
375 J
value to use: Row B
375
congener TEC: Row C
0.1125
0%
17448.3295
17468.4240
17488.5185
17455.3273
none Section 1
17455.3273
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-16: Row A
77.8 J
value to use: Row B
77.8
congener TEC: Row C
0.02334
0%
3718.9304
3722.7347
3726.5389
3720.3646
none Section 1
3720.3646
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-17: Row A
7.84 U
value to use: Row B
7.84
congener TEC: Row C
0.002352
159%
1.449
7.092876
12.736752
slot calculatec
Insufficient Data
<4.5 ppt TEQ
donor value to use: Row D
<3 congeners were detects, so
donor TEC: Row E
KM TEQ can't be calculated.
SFRA-18: Row A
145 J
value to use: Row B
145
congener TEC: Row C
0.0435
0%
4840.6085
4848.235
4855.8615
4844.5407
none Section 1
4844.5407
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
-------
17
0.0003
215 J
215
0.0645
430
430
0.129
67 J
67
0.0201
4870
4870
1.461
237
237
0.0711
231
231
0.0693
549
549
0.1647
611
611
0.1833
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
4554.0185 4559.3435 4564.6685
5870.6650 5870.9865 5871.3080
1507.1299 1509.4428 1511.7556
294.4510 297.3605 300.2700
4736.6075 4736.9325 4737.2575
424.2029 425.5359 426.8689
595.7467 597.9572 600.1677
183.4503 185.74505 188.0398
KM Method
Sample KM
TEQ Qualifier
4556.9028 none
5870.7955 none
1507.9946 none
296.9301 none
4736.9399 none
424.9590 none
597.3020 none
184.6942 none
Select KM TEQ
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
4556.9028
Qualified
Dioxin/Furan
5870.7955
Qualified
Dioxin/Furan
1507.9946
Qualified
Dioxin/Furan
296.9301
Qualified
Dioxin/Furan
4736.9399
Qualified
Dioxin/Furan
424.9590
Qualified
Dioxin/Furan
597.3020
Qualified
Dioxin/Furan
184.6942
Qualified
Dioxin/Furan
none
0%
100%
none
0%
100%
none
1%
100%
none
4%
100%
none
0%
100%
none
1%
100%
none
3%
100%
none
7%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
EPA Advanced KM
1 cw OdlUUIdlUI
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
17
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Sample notes
Chemical Sort Order:
Treatment 1
Treatment 1:
Make highest U value a D
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.0003
<
/
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
KM Method
U = 0 &
sum
U = 1/2 DL
& sum
U = DL &
sum
Sample KM
TEQ
Qualifier
Select KM TEQ
KM TEQ
Qualifier and Qualifier
Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-28: Row A
69.2 J
value to use: Row B
69.2
23
congener TEC: Row C
0.02076
0%
1225.5738
1228.5638
1231.5538
1226.9658
none
Section 1
1226.9658
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-29: Row A
22.4 J
value to use: Row B
22.4
24
congener TEC: Row C
0.00672
21%
12.2093
13.6727
15.1361
12.4169
J
Section 1
12.4169
J
donor value to use: Row D
Locked
Qualified
74%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-30: Row A
1150 J
value to use: Row B
1150
25
congener TEC: Row C
0.345
1%
11080.5710
11118.2860
11156.0010
11100.0258
none
Section 1
11100.0258
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-31: Row A
501 J
value to use: Row B
501
26
congener TEC: Row C
0.1503
0%
20381.4803
20399.1328
20416.7853
20387.3933
none
Section 1
20387.3933
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-32: Row A
137
value to use: Row B
137
27
congener TEC: Row C
0.0411
0%
3208.1990
3212.5280
3216.8570
3210.5930
none
Section 1
3210.5930
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-33: Row A
220 J
value to use: Row B
220
28
congener TEC: Row C
0.066
0%
24427.2960
24451.9125
24476.5290
24434.8933
none
Section 1
24434.8933
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-37: Row A
175 J
value to use: Row B
175
29
congener TEC: Row C
0.0525
0%
6701.7618
6709.10925
6716.4567
6705.1978
none
Section 1
6705.1978
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-38: Row A
97 J
value to use: Row B
97
30
congener TEC: Row C
0.0291
0%
2575.1623
2576.4133
2577.6643
2575.8983
none
Section 1
2575.8983
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
-------
17
0.0003
121 J
121
0.0363
624
624
0.1872
567 J
567
0.1701
226 J
226
0.0678
301 J
301
0.0903
661 J
661
0.1983
209 J
209
0.0627
559 J
559
0.1677
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
0%
3%
0%
0%
0%
0%
0%
0%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
3218.2484 3220.2282 3222.2079
215.0922 217.8276 220.5630
13350.7651 13359.5885 13368.4119
6184.2578 6197.2063 6210.1548
20737.2603 20755.8833 20774.5063
14088.7383 14098.1282 14107.5180
10620.9127 10637.7912 10654.6697
30745.6677 30767.7772 30789.8867
KM Method
Sample KM
TEQ Qualifier
3219.0432 none
216.9045 none
13355.6920 none
6189.2020 none
20743.6186 none
14092.9647 none
10626.0415 none
30753.4820 none
Select KM TEQ
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
3219.0432
Qualified
Dioxin/Furan
216.9045
Qualified
Dioxin/Furan
13355.6920
Qualified
Dioxin/Furan
6189.2020
Qualified
Dioxin/Furan
20743.6186
Qualified
Dioxin/Furan
14092.9647
Qualified
Dioxin/Furan
10626.0415
Qualified
Dioxin/Furan
30753.4820
Qualified
Dioxin/Furan
none
0%
100%
none
9%
100%
none
0%
100%
none
1%
100%
none
0%
100%
none
1%
100%
none
0%
100%
none
0%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
EPA Advanced KM
1 cw OdlUUIdlUI
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
17
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Sample notes
Chemical Sort Order:
Treatment 1
Treatment 1:
Make highest U value a D
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.0003
<
/
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
KM Method
U = 0 &
sum
U = 1/2 DL
& sum
U = DL &
sum
Sample KM
TEQ
Qualifier
Select KM TEQ
KM TEQ
Qualifier and Qualifier
Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-47: Row A
28.9 J
value to use: Row B
28.9
39
congener TEC: Row C
0.00867
0%
4316.0507
4319.2411
4322.4316
4316.8886
none
Section 1
4316.8886
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-48: Row A
101 J
value to use: Row B
101
40
congener TEC: Row C
0.0303
0%
7333.2593
7344.0208
7354.7822
7336.5565
none
Section 1
7336.5565
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-49: Row A
75.9 J
value to use: Row B
75.9
41
congener TEC: Row C
0.02277
0%
1419.6229
1421.0852
1422.5475
1420.3690
none
Section 1
1420.3690
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-50: Row A
190
value to use: Row B
190
42
congener TEC: Row C
0.057
0%
2676.5124
2678.4139
2680.3154
2677.4838
none
Section 1
2677.4838
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-51: Row A
136 J
value to use: Row B
136
43
congener TEC: Row C
0.0408
0%
4397.1978
4405.4994
4413.8009
4399.7186
none
Section 1
4399.7186
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-52: Row A
120 J
value to use: Row B
120
44
congener TEC: Row C
0.036
0%
2412.9150
2413.0523
2413.1896
2413.0482
none
Section 1
2413.0482
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-53: Row A
581 J
value to use: Row B
581
45
congener TEC: Row C
0.1743
0%
42634.0843
42663.5553
42693.0263
42642.5125
none
Section 1
42642.5125
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-54: Row A
622 J
value to use: Row B
622
46
congener TEC: Row C
0.1866
0%
19727.6466
19736.2834
19744.9202
19731.1324
none
Section 1
19731.1324
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
-------
17
0.0003
423 J
423
0.1269
3970
3970
1.191
1040
1040
0.312
450 J
450
0.135
201
201
0.0603
386 J
386
0.1158
177
177
0.0531
143
143
0.0429
2.92 U
2.92
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
0%
0%
2%
0%
0%
0%
0%
0%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
13857.0969 13872.8719 13888.6469
15738.4410 15746.8025 15755.1640
358.5800 361.8514 365.1227
26043.7880 26054.7964 26065.8047
3906.7345 3907.3640 3907.9935
5547.0478 5549.7231 5552.3984
2503.4311 2505.4699 2507.5087
1475.7030 1477.4576 1479.2121
KM Method
Sample KM
TEQ Qualifier
13865.2950 none
15742.8603 none
360.0630 none
26048.0980 none
3907.0164 none
5548.1511 none
2504.0979 none
1476.5431 none
Select KM TEQ
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
13865.2950
Qualified
Dioxin/Furan
15742.8603
Qualified
Dioxin/Furan
360.0630
Qualified
Dioxin/Furan
26048.0980
Qualified
Dioxin/Furan
3907.0164
Qualified
Dioxin/Furan
5548.1511
Qualified
Dioxin/Furan
2504.0979
Qualified
Dioxin/Furan
1476.5431
Qualified
Dioxin/Furan
none
1%
100%
none
1%
100%
none
2%
100%
none
0%
100%
none
0%
100%
none
0%
100%
none
0%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
EPA Advanced KM
1 cw OdlUUIdlUI
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
17
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Sample notes
Chemical Sort Order:
Treatment 1
Treatment 1:
Make highest U value a D
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.0003
<
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
KM Method
U = 0 &
sum
U = 1/2 DL
& sum
U = DL &
sum
Sample KM
TEQ
Qualifier
Select KM TEQ
KM TEQ
Qualifier and Qualifier
Fractions
Qualifier and
KM TEQ Qualifier Fractions
55
congener TEC: Row C
0.000876
33%
5.3460
6.3885
7.4311
5.4142
J
Section 1
5.4142
J
donor value to use: Row D
Locked
Qualified
68%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-64: Row A
15.4 J
value to use: Row B
15.4
56
congener TEC: Row C
0.00462
29%
8.6432
10.0988
11.5544
8.9192
J
Section 1
8.9192
J
donor value to use: Row D
Locked
Qualified
77%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-65: Row A
31.1 J
value to use: Row B
31.1
57
congener TEC: Row C
0.00933
8%
44.3772
46.2261
48.0750
44.7106
none
Section 1
44.7106
none
donor value to use: Row D
Locked
Qualified
8%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-66: Row A
161
value to use: Row B
161
58
congener TEC: Row C
0.0483
2%
250.5436
252.7762
255.0088
251.1918
none
Section 1
251.1918
none
donor value to use: Row D
Locked
Qualified
3%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-67: Row A
4.59 U
value to use: Row B
4.59
59
congener TEC: Row C
0.001377
158%
0.8000
3.8524
6.9049
slot calculatec
Insufficient Data
<3.2 ppt TEQ
donor value to use: Row D
Locked
<3 congeners were detects, so
donor TEC: Row E
KM TEQ can't be calculated.
SFRA-68: Row A
99.6 J
value to use: Row B
99.6
60
congener TEC: Row C
0.02988
3%
148.0881
150.6985
153.3089
148.9442
none
Section 1
148.9442
none
donor value to use: Row D
Locked
Qualified
5%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-69: Row A
4.67 U
value to use: Row B
4.67
61
congener TEC: Row C
0.001401
131%
1.2160
3.5363
5.8566
slot calculatec
Insufficient Data
<2 ppt TEQ
donor value to use: Row D
Locked
<3 congeners were detects, so
donor TEC: Row E
KM TEQ can't be calculated.
SFRA-70: Row A
64.1 J
value to use: Row B
64.1
62
congener TEC: Row C
0.01923
4%
95.6972
97.4290
99.1607
96.2692
none
Section 1
96.2692
none
donor value to use: Row D
Locked
Qualified
5%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-71: Row A
4.41 U
value to use: Row B
4.41
63
congener TEC: Row C
0.001323
68%
4.0830
6.2080
8.3329
slot calculatec
Insufficient Data
<5 ppt TEQ
donor value to use: Row D
<3 congeners were detects, so
-------
17
0.0003
/
2260
2260
0.678
586
586
0.1758
602 J
602
0.1806
1090
1090
0.327
58.1 J
58.1
0.01743
246
246
0.0738
353
353
0.1059
145
145
0.0435
189
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
872.5525 876.1225 879.6925
3120.0128 3122.8716 3125.7304
12050.6206 12063.6161 12076.6116
4732.2410 4738.7188 4745.1965
948.8854 952.5543 956.2232
1039.0878 1042.9457 1046.8036
2468.8284 2469.5599 2470.2914
1516.7679 1521.0854 1525.4029
KM Method
Sample KM
TEQ Qualifier
874.1738 none
3121.5097 none
12056.8090 none
4735.1300 none
949.6661 none
1040.5329 none
2469.2436 none
1518.0692 none
Select KM TEQ
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
Section 1
Locked
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
KM TEQ can't be calculated.
874.1738
Qualified
Dioxin/Furan
3121.5097
Qualified
Dioxin/Furan
12056.8090
Qualified
Dioxin/Furan
4735.1300
Qualified
Dioxin/Furan
949.6661
Qualified
Dioxin/Furan
1040.5329
Qualified
Dioxin/Furan
2469.2436
Qualified
Dioxin/Furan
1518.0692
Qualified
Dioxin/Furan
none
3%
100%
none
0%
100%
none
0%
100%
none
1%
100%
none
1%
100%
none
1%
100%
none
1%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
-------
EPA Advanced KM
1 cw OdlUUIdlUI
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
17
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Sample notes
Chemical Sort Order:
Treatment 1
Treatment 1:
Make highest U value a D
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
0.0003
<
/
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
TEQs from Substitution
KM Method
U = 0 &
sum
U = 1/2 DL
& sum
U = DL &
sum
Sample KM
TEQ
Qualifier
Select KM TEQ
KM TEQ
Qualifier and Qualifier
Fractions
Qualifier and
KM TEQ Qualifier Fractions
value to use: Row B
189
72
congener TEC: Row C
0.0567
1%
755.6787
759.6134
763.5480
757.1773
none
Section 1
757.1773
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-81: Row A
55.1 J
value to use: Row B
55.1
73
congener TEC: Row C
0.01653
1%
246.5425
248.3745
250.2065
247.2545
none
Section 1
247.2545
none
donor value to use: Row D
Locked
Qualified
3%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-82: Row A
200
value to use: Row B
200
74
congener TEC: Row C
0.06
0%
701.7890
702.9530
704.1170
702.6622
none
Section 1
702.6622
none
donor value to use: Row D
Locked
Qualified
3%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-83: Row A
220
value to use: Row B
220
75
congener TEC: Row C
0.066
No difference
914.2963
914.2963
914.2963
914.2963
none
Section 1
914.2963
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-84: Row A
183
value to use: Row B
183
76
congener TEC: Row C
0.0549
1%
444.5219
445.6704
446.8189
445.5234
none
Section 1
445.5234
none
donor value to use: Row D
Locked
Qualified
3%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-85: Row A
194
value to use: Row B
194
77
congener TEC: Row C
0.0582
1%
1270.5694
1273.9639
1277.3584
1272.3360
none
Section 1
1272.3360
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-86: Row A
112 J
value to use: Row B
112
78
congener TEC: Row C
0.0336
0%
752.2692
754.0113
755.7533
752.8970
none
Section 1
752.8970
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-87: Row A
38.6 J
value to use: Row B
38.6
79
congener TEC: Row C
0.01158
1%
230.0582
231.2532
232.4482
230.4318
none
Section 1
230.4318
none
donor value to use: Row D
Locked
Qualified
2%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-88: Row A
76.8 J
value to use: Row B
76.8
80
congener TEC: Row C
0.02304
2%
143.9848
145.6098
147.2347
144.7117
none
Section 1
144.7117
none
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
17
WHO 2005 TEFs =
0.0003
bummary ot
Treatment 1
1 1 CCUMICI 11 I .
Make highest U value a D
Sensitivity
TEQs from Substitution
KM Method
<
Analysis
(relative
Sample ID:
00«
percent
U = 0 & U = 1/2 DL U = DL&
Sample KM
Qualifier and Qualifier
Qualifier and
Sample notes
(must enter on Row A)
o
difference)
sum & sum sum
TEQ
Qualifier
Select KM TEQ
KM TEQ
Fractions
KM TEQ Qualifier Fractions
donor value to use: Row D
Locked
Qualified
3%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-89: Row A
63.4 J
value to use: Row B
63.4
81
congener TEC: Row C
0.01902
1%
615.3310 618.0143 620.6976
616.6388
none
Section 1
616.6388
none
donor value to use: Row D
Locked
Qualified
2%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-90: Row A
899
value to use: Row B
899
82
congener TEC: Row C
0.2697
1%
601.6590 604.0110 606.3630
603.3551
none
Section 1
603.3551
none
donor value to use: Row D
Locked
Qualified
3%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-91: Row A
286
value to use: Row B
286
83
congener TEC: Row C
0.0858
0%
810.2566 811.4766 812.6966
811.1422
none
Section 1
811.1422
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-92: Row A
8.67 U
value to use: Row B
8.67
84
congener TEC: Row C
0.002601
40%
5.1577 6.4400 7.7222
5.4337
J
Section 1
5.4337
J
donor value to use: Row D
Locked
Qualified
74%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-93: Row A
301
value to use: Row B
301
85
congener TEC: Row C
0.0903
0%
918.8440 920.1211 921.3982
919.6881
none
Section 1
919.6881
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-94: Row A
89 J
value to use: Row B
89
86
congener TEC: Row C
0.0267
0%
2994.5441 3001.5221 3008.5001
2995.5589
none
Section 1
2995.5589
none
donor value to use: Row D
Locked
Qualified
1%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-95: Row A
745
value to use: Row B
745
87
congener TEC: Row C
0.2235
0%
16340.5835 16353.6833 16366.7830
16343.5929
none
Section 1
16343.5929
none
donor value to use: Row D
Locked
Qualified
0%
donor TEC: Row E
Dioxin/Furan
100%
SFRA-96: Row A
220
value to use: Row B
220
88
congener TEC: Row C
0.066
1%
977.6955 982.2055 986.7155
980.2980
none
Section 1
980.2980
none
donor value to use: Row D
Locked
Qualified
2%
donor TEC: Row E
Dioxin/Furan
100%
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
89
90
91
17
WHO 2005 TEFs = 0.0003
Sample ID:
(must enter on Row A)
4**
SFRA-97: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-98: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-99: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
70.4 J
70.4
0.02112
377
377
0.1131
212 J
212
0.0636
bummary ot
Sensitivity
Analysis
(relative
percent
difference)
2%
0%
0%
TEQs from Substitution
U = 0 & U = 1/2 DL U = DL&
sum & sum sum
150.7288 152.4253 154.1218
3223.2301 3223.3991 3223.5681
3960.7776 3967.9206 3975.0636
KM Method
Sample KM
TEQ Qualifier
151.6264 none
3223.3538
none
3963.4144
none
Select KM TEQ
Section 1
Locked
Section 1
Locked
Section 1
Locked
(Quasi) Sensitivity Analysis
SECTION 1
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Treatment 1
KM TEQ
Qualifier and Qualifier
Fractions
151.6264
Qualified
Dioxin/Furan
3223.3538
Qualified
Dioxin/Furan
3963.4144
Qualified
Dioxin/Furan
none
4%
100%
none
0%
100%
none
1%
100%
(Quasi) Sensitivity >
Highest TEC value is a NONDETE
rejected ("
Treatment 1:
Make highest U value a D
KM TEQ
Qualifier and
Qualifier Fractions
value to use: Row B
92 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
DATA LIST
List of TEQ results to copy and paste into
other spreadsheets, such as ProLICL
CAUTION: double-check entries and gray cells for
anomalous entries
Line
Sample ID
TEQ Result
Qualifier
Line #1
SFRA-5
13.0999
Line #2
SFRA-6
4.4553
Line #3
SFRA-7
1084.4930
Line #4
SFRA-8
10333.6015
Line #5
SFRA-9
3592.3260
Line #6
SFRA-10
6.8892
Line #7
SFRA-11
4953.8700
Line #8
SFRA-12
1085.8649
Line #9
SFRA-13
3092.3211
Line #10
SFRA-14
5681.1709
Line #11
SFRA-15
17455.3273
Line #12
SFRA-16
3720.3646
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
17
Sample notes
WHO 2005 TEFs =
0.0003
bummary ot
Sensitivity
<
Analysis
(relative
Sample ID:
percent
(must enter on Row A)
o
difference)
TEQs from Substitution
U = 0 &
sum
U = 1/2 DL
U = DL &
Sample KM
& sum
sum
TEQ
Qualifier
L
ne #13
SFRA-17
<4.5 ppt
<3 congen
L
ne #14
SFRA-18
4844.5407
L
ne #15
SFRA-19
4556.9028
L
ne #16
SFRA-20
5870.7955
L
ne #17
SFRA-21
1507.9946
L
ne #18
SFRA-22
296.9301
L
ne #19
SFRA-23
4736.9399
L
ne #20
SFRA-24
424.9590
L
ne #21
SFRA-26
597.301955
L
ne #22
SFRA-27
184.694208
L
ne #23
SFRA-28
1226.96583
L
ne #24
SFRA-29
12.4169485
J
L
ne #25
SFRA-30
11100.0258
L
ne #26
SFRA-31
20387.3933
L
ne #27
SFRA-32
3210.59301
L
ne #28
SFRA-33
24434.8933
L
ne #29
SFRA-37
6705.1978
L
ne #30
SFRA-38
2575.89828
L
ne #31
SFRA-39
3219.04318
L
ne #32
SFRA-40
216.904545
L
ne #33
SFRA-41
13355.692
L
ne #34
SFRA-42
6189.20204
L
ne #35
SFRA-43
20743.6186
L
ne #36
SFRA-44
14092.9647
L
ne #37
SFRA-45
10626.0415
L
ne #38
SFRA-46
30753.482
L
ne #39
SFRA-47
4316.88857
L
ne #40
SFRA-48
7336.55648
L
ne #41
SFRA-49
1420.36903
L
ne #42
SFRA-50
2677.48382
L
ne #43
SFRA-51
4399.71859
L
ne #44
SFRA-52
2413.04819
L
ne #45
SFRA-53
42642.5125
L
ne #46
SFRA-54
19731.1324
L
ne #47
SFRA-55
13865.295
L
ne #48
SFRA-56
15742.8603
L
ne #49
SFRA-57
360.063017
L
ne #50
SFRA-58
26048.098
L
ne #51
SFRA-59
3907.01644
L
ne #52
SFRA-60
5548.15112
L
ne #53
SFRA-61
2504.09793
L
ne #54
SFRA-62
1476.54309
KM Method
Select KM TEQ
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Treatment 1
Treatment 1:
Make highest U value a D
Qualifier and Qualifier
KM TEQ Fractions
Qualifier and
KM TEQ Qualifier Fractions
<3 congeners were detects, so KM TEQ can't be calculated.
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
17
Sample notes
WHO 2005 TEFs =
0.0003
bummary ot
Sensitivity
<
Analysis
(relative
Sample ID:
percent
(must enter on Row A)
o
difference)
TEQs from Substitution
U = 0 &
sum
U = 1/2 DL
& sum
ne #55
ne #56
ne #57
ne #58
ne #59
ne #60
ne #61
ne #62
ne #63
ne #64
ne #65
ne #66
ne #67
ne #68
ne #69
ne #70
ne #71
ne #72
ne #73
ne #74
ne #75
ne #76
ne #77
ne #78
ne #79
ne #80
ne #81
ne #82
ne #83
ne #84
ne #85
ne #86
ne #87
ne #88
ne #89
ne #90
ne #91
U = DL &
sum
SFRA-63
SFRA-64
SFRA-65
SFRA-66
SFRA-67
SFRA-68
SFRA-69
SFRA-70
SFRA-71
SFRA-72
SFRA-73
SFRA-74
SFRA-75
SFRA-76
SFRA-77
SFRA-78
SFRA-79
SFRA-80
SFRA-81
SFRA-82
SFRA-83
SFRA-84
SFRA-85
SFRA-86
SFRA-87
SFRA-88
SFRA-89
SFRA-90
SFRA-91
SFRA-92
SFRA-93
SFRA-94
SFRA-95
SFRA-96
SFRA-97
SFRA-98
SFRA-99
KM Method
Sample KM
TEQ
Qualifier
Select KM TEQ
5.41417571
8.91919107
44.710615
251.191757
<3.2 ppt
148.944197
<2 PPt
96.2691916
<5 ppt
874.17375
3121.50974
12056.809
4735.13
949.666079
1040.53292
2469.24362
1518.06922
757.177314
247.254509
702.662182
914.2963
445.52336
1272.33602
752.896977
230.431842
144.711705
616.638832
603.355083
811.14215
5.43366427
919.68805
2995.5589
16343.5929
980.298036
151.626407
3223.3538
3963.4144
(Quasi) Sensitivity Analysis
SECTION 1
(Quasi) Sensitivity >
Highest TEC value is a DETECT, and
there are no rejected ("R") values
Highest TEC value is a NONDETE
rejected ("
Treatment 1
Treatment 1:
Make highest U value a D
Qualifier and Qualifier
KM TEQ Fractions
Qualifier and
KM TEQ Qualifier Fractions
<3 congeners were detects, so KM TEQ can't be calculated.
<3 congeners were detects, so KM TEQ can't be calculated.
<3 congeners were detects, so KM TEQ can't be calculated.
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
Substitute comparable "donor"
value for highest U
Sample notes
1
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
SFRA-5: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
2
SFRA-6: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-7: Row A
value to use: Row B
3 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
4
5
SFRA-8: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-9: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
6
SFRA-10: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
7
SFRA-11: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
8
SFRA-12: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
9
SFRA-13: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
10
SFRA-14: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
11
SFRA-15: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
12
13
SFRA-16: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-17: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
14
SFRA-18: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
15
SFRA-19: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
16
SFRA-20: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
17
SFRA-21: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
18
SFRA-22: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
19
SFRA-23: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
20
21
SFRA-24: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-26: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
22
SFRA-27: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
23
SFRA-28: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
24
SFRA-29: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
25
SFRA-30: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
26
SFRA-31: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
27
SFRA-32: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
28
29
SFRA-33: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-37: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
30
SFRA-38: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
31
SFRA-39: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
32
SFRA-40: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
33
SFRA-41: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
34
SFRA-42: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
35
SFRA-43: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
36
37
SFRA-44: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-45: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
38
SFRA-46: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
39
SFRA-47: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
40
SFRA-48: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
41
SFRA-49: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
42
SFRA-50: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
43
SFRA-51: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
44
45
SFRA-52: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-53: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
46
SFRA-54: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
47
SFRA-55: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
48
SFRA-56: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
49
SFRA-57: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
50
SFRA-58: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
51
SFRA-59: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
52
53
SFRA-60: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-61: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
54
SFRA-62: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-63: Row A
value to use: Row B
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
55
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
56
SFRA-64: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
57
SFRA-65: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
58
SFRA-66: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
59
SFRA-67: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
60
61
SFRA-68: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-69: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
62
SFRA-70: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
63
SFRA-71: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
donor TEC: Row E
64
SFRA-72: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
65
SFRA-73: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
66
SFRA-74: Row A
value to use: Row B
congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
67
SFRA-75: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
68
69
SFRA-76: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-77: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
70
SFRA-78: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
71
SFRA-79: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-80: Row A
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
72
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
73
SFRA-81: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
74
SFRA-82: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
75
SFRA-83: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
76
77
SFRA-84: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-85: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
78
SFRA-86: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
79
SFRA-87: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
80
SFRA-88: Row A
value to use: Row B
congener TEC: Row C
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
donor value to use: Row D
donor TEC: Row E
81
SFRA-89: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
82
SFRA-90: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
83
SFRA-91: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
84
85
SFRA-92: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-93: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
86
SFRA-94: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
87
SFRA-95: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
88
SFRA-96: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
WHO 2005 TEFs =
Substitute comparable "donor"
value for highest U
Sample notes
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
89
SFRA-97: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
90
SFRA-98: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
91
SFRA-99: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
92
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
Substitute comparable "donor"
value for highest U
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Analysis SECTION 2
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
CT ("U" or "ND"), and there are no
R") values
Chemical Sort Order:
Treatment 2:
Substitute comparable "donor"
value for highest U
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-5: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-6: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-7: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-8: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-9: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-10: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-11: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-12: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-13: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-14: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-15: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-16: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-17: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-18: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
10
11
12
13
14
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
15
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-19: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-20: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-21: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-22: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-23: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-24: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-26: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-27: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
16
17
18
19
20
21
22
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
23
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-28: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-29: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-30: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-31: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-32: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-33: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-37: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-38: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
24
25
26
27
28
29
30
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
31
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-39: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-40: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-41: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-42: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-43: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-44: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-45: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-46: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
32
33
34
35
36
37
38
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
39
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-47: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-48: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-49: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-50: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-51: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-52: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-53: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-54: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
40
41
42
43
44
45
46
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
47
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-55: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-56: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-57: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-58: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-59: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-60: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-61: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-62: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-63: Row A
value to use: Row B
48
49
50
51
52
53
54
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
55
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-64: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-65: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-66: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-67: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-68: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-69: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-70: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-71: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
56
57
58
59
60
61
62
63
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
(Quasi) Sensitivity Analysis SECTION 3
performing quasi-sensitivity analyses
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Sample notes
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
donor TEC: Row E
64
SFRA-72: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
65
SFRA-73: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
66
SFRA-74: Row A
value to use: Row B
congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
SFRA-75: Row A
value to use: Row B
67 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
68
69
SFRA-76: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-77: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
70
SFRA-78: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
71
SFRA-79: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-80: Row A
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
72
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-81: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-82: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-83: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-84: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-85: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-86: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-87: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-88: Row A
value to use: Row B
congener TEC: Row C
73
74
75
76
77
78
79
80
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
(Quasi) Sensitivity Analysis SECTION 3
performing quasi-sensitivity analyses
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Sample notes
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
donor value to use: Row D
donor TEC: Row E
81
SFRA-89: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
82
SFRA-90: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-91: Row A
value to use: Row B
83 congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
84
85
SFRA-92: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-93: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
86
SFRA-94: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
87
SFRA-95: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
88
SFRA-96: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
(Quasi) Sensitivity Analysis SECTION 3
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Sample notes
89
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
SFRA-97: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-98: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-99: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
90
91
92
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
(Quasi) Sensitivity Analysis SECTION 3
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
Chemical Sort Order:
Sample notes
WHO 2005 TEFs =
Sample ID:
(must enter on Row A)
(Quasi) Sensitivity Analysis SECTION 3
Rejected ("R") value(s) are present; nondetected values ("U" or "ND") may or may not be present, and the highest TEC may or may not be a nondetectec
Treatment 1:
TEQ as simple sum when R & U
treated as 0 (minimum)
Treatment 2:
TEQ as simple sum when R & U
treated as normal detects
Treatment 3:
Used if "donor" value is available
for R values
Treatment 4:
Used if "donor" values are
available for R and U values
Sample ID
Will sample used for
reanalysis be "donor"
requested? values
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
Qualifier and
KM TEQ Qualifier Fractions
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
1
SFRA-5: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
2
SFRA-6: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
3
SFRA-7: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
4
5
SFRA-8: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-9: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
6
SFRA-10: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
7
SFRA-11: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TCn f ^ O 1 ^ 1 I 1 I1 y
\ tu oaicuiaior
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
Sample notes
(must enter on Row A)
Comment
SFRA-12: Row A
value to use: Row B
8
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-13: Row A
value to use: Row B
9
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-14: Row A
value to use: Row B
10
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-15: Row A
value to use: Row B
11
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-16: Row A
value to use: Row B
12
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-17: Row A
value to use: Row B
Fewer than 3 detected results.
13
congener TEC: Row C
Refer to KM Discussion
donor value to use: Row D
worksheet for discussion.
donor TEC: Row E
SFRA-18: Row A
value to use: Row B
14
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
15
SFRA-19: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
16
SFRA-20: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
17
SFRA-21: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
18
SFRA-22: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
19
SFRA-23: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
20
21
SFRA-24: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-26: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
22
SFRA-27: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
23
SFRA-28: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
24
SFRA-29: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
25
SFRA-30: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
26
SFRA-31: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
27
SFRA-32: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
28
29
SFRA-33: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-37: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
30
SFRA-38: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
31
SFRA-39: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
32
SFRA-40: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
33
SFRA-41: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
34
SFRA-42: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
35
SFRA-43: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
36
37
SFRA-44: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-45: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
38
SFRA-46: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
39
SFRA-47: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
40
SFRA-48: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
41
SFRA-49: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
42
SFRA-50: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
43
SFRA-51: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
44
45
SFRA-52: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-53: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
46
SFRA-54: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
47
SFRA-55: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
48
SFRA-56: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
49
SFRA-57: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
50
SFRA-58: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
51
SFRA-59: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
52
53
SFRA-60: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-61: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
54
SFRA-62: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-63: Row A
value to use: Row B
-------
EPA Advanced KM
TCn f ^ O 1 ^ 1 I 1 I1 y
\ tu oaicuiaior
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample ID:
Sample notes
(must enter on Row A)
Comment
55
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-64: Row A
value to use: Row B
56
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-65: Row A
value to use: Row B
57
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-66: Row A
value to use: Row B
58
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-67: Row A
value to use: Row B
Fewer than 3 detected results.
59
congener TEC: Row C
Refer to KM Discussion
donor value to use: Row D
worksheet for discussion.
donor TEC: Row E
SFRA-68: Row A
value to use: Row B
60
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-69: Row A
value to use: Row B
Fewer than 3 detected results.
61
congener TEC: Row C
Refer to KM Discussion
donor value to use: Row D
worksheet for discussion.
donor TEC: Row E
SFRA-70: Row A
value to use: Row B
62
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-71: Row A
value to use: Row B
Fewer than 3 detected results.
63
congener TEC: Row C
Refer to KM Discussion
donor value to use: Row D
worksheet for discussion.
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
donor TEC: Row E
64
SFRA-72: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
65
SFRA-73: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
66
SFRA-74: Row A
value to use: Row B
congener TEC: RowC
donor value to use: Row D
donor TEC: Row E
67
SFRA-75: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
68
69
SFRA-76: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-77: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
70
SFRA-78: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
71
SFRA-79: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-80: Row A
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
72
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
73
SFRA-81: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
74
SFRA-82: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
75
SFRA-83: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
76
77
SFRA-84: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-85: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
78
SFRA-86: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
79
SFRA-87: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
80
SFRA-88: Row A
value to use: Row B
congener TEC: Row C
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
donor value to use: Row D
donor TEC: Row E
81
SFRA-89: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
82
SFRA-90: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
83
SFRA-91: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
84
85
SFRA-92: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
SFRA-93: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
86
SFRA-94: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
87
SFRA-95: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
88
SFRA-96: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
89
SFRA-97: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
90
SFRA-98: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
91
SFRA-99: Row A
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
92
value to use: Row B
congener TEC: Row C
donor value to use: Row D
donor TEC: Row E
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
-------
EPA Advanced KM
TEQ Calculator
Advanced KM TEQ calculator for
performing quasi-sensitivity analyses
result.
Chemical Sort Order:
WHO 2005 TEFs =
Sample notes
Sample ID:
(must enter on Row A)
Comment
-------
EPA Advanced KM TEQ Calculator
Automated Data Entry Worksheet
This worksheet is the data entry point for data sets that the user wants to automatically import into the "Data Entry and Output" worksheet. Users should copy data from a comma-delimited file
or other text file, Excel worksheet, or other output from a database query and paste it into the table below, then click the "Transfer Data" button above to transfer the formatted data to the "Data
Entry & Output" worksheet. The source data should be arranged in columns identical to the order of columns shown below before copying the data into the table. Excel's "Paste Values" tool can
also be used to preserve the formatting of the table.
The fields designated as "required" must be included in the data query. The fields designated as "optional" should either contain the data specified, or may be left blank. The fields in Columns G
and H will be automatically populated by the macro. The data query may include a field that specifies the order that the samples will appear in the "Data Entry & Output" worksheet. If this field is
left blank, the importation macro will sort on the sample ID instead. Note that if the sample order is omitted, the sample IDs will be sorted as text values, and may not sort samples in numerical
order as expected (for example; 1, 10, 11, 2, 3, 4, 5, 6, 7, 8, 9 instead of 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11). Note that the user should ensure that the "Data Entry & Output" worksheet has enough
samples for the sample data set being imported. See the "Instructions" worksheet for guidance on adding samples.
The "Congener Name" field in Column C is intended to be the name used by the project team in order to preserve project sample nomenclature. The "Congener Abbreviation" in Column G is the
abbreviation used by this Calculator. These fields may not be identical, but should refer to the same congeners (see the "Congener Abbreviations" worksheets for examples of dioxin and PCB
congener naming schemes).
Note that all samples to be imported into the calculator must have the same number of congeners and that only one result should be entered for each congener/sample. Otherwise, an error
message will be displayed, and the data transfer routine will be terminated. If multiple results for the same congener are present in the data set, the user should choose the appropriate result and
remove the other result(s). An example is for TCDF, which may be confirmed using a second column analysis when it is detected in the initial analysis. In this case, the confirmation sample result
should be retained, and the initial result should be discarded. If possible, selection of the correct results should be performed in the database prior to copying the data into this worksheet.
The user should be aware that soil and water samples are often reported within the same laboratory-provided spreadsheet or database output. Since soil and water results have different
reporting units, it is best to use different Calculator files for different matrices so that water results will not be confused with soil results (or results from any other matrix). Be sure to enter the
matrix and reporting units information at the top of the "Data Entry & Output" worksheet.
After the "Transfer Data" button is pressed, data importation will begin. This importation process may take as long as approximately one minute, depending on the processing speed of the user's
computer.
Congener
Sample Order
Congener Name
CAS Number
Result
Qualifier
Abbreviation
Congener Order
Sample ID (required)
(optional)
(optional)
(required)
(required)
(required)
(auto-entered)
(auto-entered)
SFRA-5
5
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
8.06
TCDD
1
SFRA-5
5
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
0.682
U
PeCDD
2
SFRA-5
5
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
1.84
J
1,4-HxCDD
3
SFRA-5
5
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
4.24
U
1,6-HxCDD
4
SFRA-5
5
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
3.02
J
1,9-HxCDD
5
SFRA-5
5
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
155
1,4,6-HpCDD
6
SFRA-5
5
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
4960
E
OCDD
7
SFRA-5
5
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
0.419
J
TCDF
8
SFRA-5
5
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.06
J
1-PeCDF
9
SFRA-5
5
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.15
J
4-PeCDF
10
SFRA-5
5
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.04
J
1,4-HxCDF
11
SFRA-5
5
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.965
U
1,6-HxCDF
12
SFRA-5
5
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
0.678
U
1,9-HxCDF
13
SFRA-5
5
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.03
J
4,6-HxCDF
14
SFRA-5
5
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
24.7
1,4,6-HpCDF
15
SFRA-5
5
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
1.52
J
1,4,9-HpCDF
16
SFRA-5
5
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
61.3
OCDF
17
SFRA-6
6
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3.12
TCDD
1
SFRA-6
6
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
0.391
u
PeCDD
2
SFRA-6
6
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
0.716
u
1,4-HxCDD
3
SFRA-6
6
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
0.961
J
1,6-HxCDD
4
-------
SFRA-6
6
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
1.12
J
1,9-HxCDD
5
SFRA-6
6
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
51.1
1,4,6-HpCDD
6
SFRA-6
6
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
1800
OCDD
7
SFRA-6
6
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
0.349
U
TCDF
8
SFRA-6
6
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.309
U
1-PeCDF
9
SFRA-6
6
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.289
U
4-PeCDF
10
SFRA-6
6
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.23
U
1,4-HxCDF
11
SFRA-6
6
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.214
U
1,6-HxCDF
12
SFRA-6
6
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
0.365
U
1,9-HxCDF
13
SFRA-6
6
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
0.224
U
4,6-HxCDF
14
SFRA-6
6
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
1.76
J
1,4,6-HpCDF
15
SFRA-6
6
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
0.281
U
1,4,9-HpCDF
16
SFRA-6
6
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
3.04
J
OCDF
17
SFRA-7
7
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1080
TCDD
1
SFRA-7
7
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.91
U
PeCDD
2
SFRA-7
7
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
7.3
U
1,4-HxCDD
3
SFRA-7
7
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
6.13
U
1,6-HxCDD
4
SFRA-7
7
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
6.06
U
1,9-HxCDD
5
SFRA-7
7
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
114
1,4,6-HpCDD
6
SFRA-7
7
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
1870
OCDD
7
SFRA-7
7
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
7.29
J
TCDF
8
SFRA-7
7
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
8.18
J
1-PeCDF
9
SFRA-7
7
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.97
U
4-PeCDF
10
SFRA-7
7
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.13
U
1,4-HxCDF
11
SFRA-7
7
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.89
U
1,6-HxCDF
12
SFRA-7
7
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.71
U
1,9-HxCDF
13
SFRA-7
7
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.43
U
4,6-HxCDF
14
SFRA-7
7
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
20.1
J
1,4,6-HpCDF
15
SFRA-7
7
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
11.2
U
1,4,9-HpCDF
16
SFRA-7
7
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
40.7
J
OCDF
17
SFRA-8
8
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
10300
TCDD
1
SFRA-8
8
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
5.7
U
PeCDD
2
SFRA-8
8
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
21.5
J
1,4-HxCDD
3
SFRA-8
8
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
73.2
J
1,6-HxCDD
4
SFRA-8
8
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
24.5
J
1,9-HxCDD
5
SFRA-8
8
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
550
1,4,6-HpCDD
6
SFRA-8
8
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
6300
OCDD
7
SFRA-8
8
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
70.1
TCDF
8
SFRA-8
8
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.92
U
1-PeCDF
9
SFRA-8
8
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.95
J
4-PeCDF
10
SFRA-8
8
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
11.7
U
1,4-HxCDF
11
SFRA-8
8
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.44
J
1,6-HxCDF
12
SFRA-8
8
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
8.36
U
1,9-HxCDF
13
SFRA-8
8
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
10.4
J
4,6-HxCDF
14
SFRA-8
8
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
127
J
1,4,6-HpCDF
15
SFRA-8
8
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
11.3
J
1,4,9-HpCDF
16
SFRA-8
8
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
229
J
OCDF
17
SFRA-9
9
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3580
TCDD
1
SFRA-9
9
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.12
U
PeCDD
2
SFRA-9
9
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
5.89
U
1,4-HxCDD
3
SFRA-9
9
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
18.3
J
1,6-HxCDD
4
SFRA-9
9
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
6.27
J
1,9-HxCDD
5
SFRA-9
9
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
311
1,4,6-HpCDD
6
SFRA-9
9
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
5580
OCDD
7
SFRA-9
9
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
23.9
TCDF
8
-------
SFRA-9
9
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.33
J
1-PeCDF
9
SFRA-9
9
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.98
U
4-PeCDF
10
SFRA-9
9
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
4.89
J
1,4-HxCDF
11
SFRA-9
9
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.12
U
1,6-HxCDF
12
SFRA-9
9
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.34
U
1,9-HxCDF
13
SFRA-9
9
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.23
U
4,6-HxCDF
14
SFRA-9
9
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
53
J
1,4,6-HpCDF
15
SFRA-9
9
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
9.33
U
1,4,9-HpCDF
16
SFRA-9
9
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
131
J
OCDF
17
SFRA-10
10
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
5.46
TCDD
1
SFRA-10
10
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
0.2
U
PeCDD
2
SFRA-10
10
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
0.514
J
1,4-HxCDD
3
SFRA-10
10
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
0.745
J
1,6-HxCDD
4
SFRA-10
10
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
0.902
J
1,9-HxCDD
5
SFRA-10
10
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
52.5
1,4,6-HpCDD
6
SFRA-10
10
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
2230
OCDD
7
SFRA-10
10
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
0.131
U
TCDF
8
SFRA-10
10
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.0974
U
1-PeCDF
9
SFRA-10
10
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.0937
U
4-PeCDF
10
SFRA-10
10
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.0716
U
1,4-HxCDF
11
SFRA-10
10
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.0731
U
1,6-HxCDF
12
SFRA-10
10
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
0.115
U
1,9-HxCDF
13
SFRA-10
10
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
0.0731
U
4,6-HxCDF
14
SFRA-10
10
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
0.273
U
1,4,6-HpCDF
15
SFRA-10
10
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
0.135
U
1,4,9-HpCDF
16
SFRA-10
10
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
0.761
J
OCDF
17
SFRA-11
11
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4940
TCDD
1
SFRA-11
11
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.98
U
PeCDD
2
SFRA-11
11
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
10.3
U
1,4-HxCDD
3
SFRA-11
11
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
20.3
J
1,6-HxCDD
4
SFRA-11
11
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
11.7
U
1,9-HxCDD
5
SFRA-11
11
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
316
1,4,6-HpCDD
6
SFRA-11
11
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
3280
OCDD
7
SFRA-11
11
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
36
J
TCDF
8
SFRA-11
11
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
21.8
U
1-PeCDF
9
SFRA-11
11
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
10.7
U
4-PeCDF
10
SFRA-11
11
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
9.51
U
1,4-HxCDF
11
SFRA-11
11
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
9.34
U
1,6-HxCDF
12
SFRA-11
11
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
14.9
U
1,9-HxCDF
13
SFRA-11
11
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
8.62
U
4,6-HxCDF
14
SFRA-11
11
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
79.7
J
1,4,6-HpCDF
15
SFRA-11
11
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
11.1
U
1,4,9-HpCDF
16
SFRA-11
11
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
125
J
OCDF
17
SFRA-12
12
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1080
TCDD
1
SFRA-12
12
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.16
U
PeCDD
2
SFRA-12
12
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.48
u
1,4-HxCDD
3
SFRA-12
12
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
6.8
J
1,6-HxCDD
4
SFRA-12
12
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
3.75
J
1,9-HxCDD
5
SFRA-12
12
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
163
1,4,6-HpCDD
6
SFRA-12
12
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
4260
OCDD
7
SFRA-12
12
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
7.82
J
TCDF
8
SFRA-12
12
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.32
u
1-PeCDF
9
SFRA-12
12
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.59
u
4-PeCDF
10
SFRA-12
12
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.03
u
1,4-HxCDF
11
SFRA-12
12
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.14
u
1,6-HxCDF
12
-------
SFRA-12
12
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.03
U
1,9-HxCDF
13
SFRA-12
12
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.12
U
4,6-HxCDF
14
SFRA-12
12
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
20.8
J
1,4,6-HpCDF
15
SFRA-12
12
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.16
U
1,4,9-HpCDF
16
SFRA-12
12
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
49.4
J
OCDF
17
SFRA-13
13
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3080
TCDD
1
SFRA-13
13
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
6.1
U
PeCDD
2
SFRA-13
13
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
14.6
U
1,4-HxCDD
3
SFRA-13
13
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
19.1
J
1,6-HxCDD
4
SFRA-13
13
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
15.3
U
1,9-HxCDD
5
SFRA-13
13
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
367
1,4,6-HpCDD
6
SFRA-13
13
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
5030
OCDD
7
SFRA-13
13
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
20.7
TCDF
8
SFRA-13
13
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
7.27
J
1-PeCDF
9
SFRA-13
13
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.44
U
4-PeCDF
10
SFRA-13
13
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5.03
U
1,4-HxCDF
11
SFRA-13
13
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.01
U
1,6-HxCDF
12
SFRA-13
13
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
8
U
1,9-HxCDF
13
SFRA-13
13
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
5.19
U
4,6-HxCDF
14
SFRA-13
13
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
66.3
1,4,6-HpCDF
15
SFRA-13
13
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
11.3
U
1,4,9-HpCDF
16
SFRA-13
13
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
213
OCDF
17
SFRA-14
14
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
5670
TCDD
1
SFRA-14
14
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
19.9
U
PeCDD
2
SFRA-14
14
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
25.9
U
1,4-HxCDD
3
SFRA-14
14
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
24.8
U
1,6-HxCDD
4
SFRA-14
14
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
25.9
U
1,9-HxCDD
5
SFRA-14
14
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
216
J
1,4,6-HpCDD
6
SFRA-14
14
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
2800
OCDD
7
SFRA-14
14
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
34.9
J
TCDF
8
SFRA-14
14
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
14.5
U
1-PeCDF
9
SFRA-14
14
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
10.6
U
4-PeCDF
10
SFRA-14
14
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
13.4
U
1,4-HxCDF
11
SFRA-14
14
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
11.9
U
1,6-HxCDF
12
SFRA-14
14
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
23.8
U
1,9-HxCDF
13
SFRA-14
14
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
14.3
U
4,6-HxCDF
14
SFRA-14
14
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
53.4
J
1,4,6-HpCDF
15
SFRA-14
14
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
35.2
U
1,4,9-HpCDF
16
SFRA-14
14
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
90.6
J
OCDF
17
SFRA-15
15
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
17400
TCDD
1
SFRA-15
15
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
23.5
U
PeCDD
2
SFRA-15
15
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
31.1
U
1,4-HxCDD
3
SFRA-15
15
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
150
J
1,6-HxCDD
4
SFRA-15
15
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
49.1
J
1,9-HxCDD
5
SFRA-15
15
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1100
1,4,6-HpCDD
6
SFRA-15
15
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7790
OCDD
7
SFRA-15
15
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
106
J
TCDF
8
SFRA-15
15
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
20
U
1-PeCDF
9
SFRA-15
15
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
21.2
u
4-PeCDF
10
SFRA-15
15
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
19
u
1,4-HxCDF
11
SFRA-15
15
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
17.7
u
1,6-HxCDF
12
SFRA-15
15
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
24.2
u
1,9-HxCDF
13
SFRA-15
15
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
20.2
J
4,6-HxCDF
14
SFRA-15
15
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
235
J
1,4,6-HpCDF
15
SFRA-15
15
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
52.9
u
1,4,9-HpCDF
16
-------
SFRA-15
15
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
375
J
OCDF
17
SFRA-16
16
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3710
TCDD
1
SFRA-16
16
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.54
U
PeCDD
2
SFRA-16
16
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
11
U
1,4-HxCDD
3
SFRA-16
16
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
15
J
1,6-HxCDD
4
SFRA-16
16
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
11.5
U
1,9-HxCDD
5
SFRA-16
16
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
219
1,4,6-HpCDD
6
SFRA-16
16
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
4430
OCDD
7
SFRA-16
16
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
24.3
TCDF
8
SFRA-16
16
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.67
J
1-PeCDF
9
SFRA-16
16
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.56
U
4-PeCDF
10
SFRA-16
16
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
4.31
J
1,4-HxCDF
11
SFRA-16
16
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.7
U
1,6-HxCDF
12
SFRA-16
16
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
3.88
U
1,9-HxCDF
13
SFRA-16
16
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.16
J
4,6-HxCDF
14
SFRA-16
16
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
44.1
J
1,4,6-HpCDF
15
SFRA-16
16
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
9.25
U
1,4,9-HpCDF
16
SFRA-16
16
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
77.8
J
OCDF
17
SFRA-17
17
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4.46
U
TCDD
1
SFRA-17
17
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.98
U
PeCDD
2
SFRA-17
17
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
4.51
U
1,4-HxCDD
3
SFRA-17
17
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
4.75
U
1,6-HxCDD
4
SFRA-17
17
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
4.77
U
1,9-HxCDD
5
SFRA-17
17
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
60.6
1,4,6-HpCDD
6
SFRA-17
17
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
2810
OCDD
7
SFRA-17
17
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.91
U
TCDF
8
SFRA-17
17
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.01
U
1-PeCDF
9
SFRA-17
17
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.04
U
4-PeCDF
10
SFRA-17
17
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.23
U
1,4-HxCDF
11
SFRA-17
17
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.14
U
1,6-HxCDF
12
SFRA-17
17
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.9
U
1,9-HxCDF
13
SFRA-17
17
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.27
U
4,6-HxCDF
14
SFRA-17
17
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
4.84
U
1,4,6-HpCDF
15
SFRA-17
17
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
7.67
U
1,4,9-HpCDF
16
SFRA-17
17
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
7.84
U
OCDF
17
SFRA-18
18
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4830
TCDD
1
SFRA-18
18
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
5.97
U
PeCDD
2
SFRA-18
18
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
13
U
1,4-HxCDD
3
SFRA-18
18
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
15.7
J
1,6-HxCDD
4
SFRA-18
18
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
12.9
U
1,9-HxCDD
5
SFRA-18
18
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
286
1,4,6-HpCDD
6
SFRA-18
18
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
2890
OCDD
7
SFRA-18
18
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
40.1
TCDF
8
SFRA-18
18
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
18.1
J
1-PeCDF
9
SFRA-18
18
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
8.79
U
4-PeCDF
10
SFRA-18
18
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
8.68
U
1,4-HxCDF
11
SFRA-18
18
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.97
u
1,6-HxCDF
12
SFRA-18
18
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
13.3
u
1,9-HxCDF
13
SFRA-18
18
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
8.92
u
4,6-HxCDF
14
SFRA-18
18
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
71.5
J
1,4,6-HpCDF
15
SFRA-18
18
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
16.9
u
1,4,9-HpCDF
16
SFRA-18
18
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
145
J
OCDF
17
SFRA-19
19
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4540
TCDD
1
SFRA-19
19
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
5.62
u
PeCDD
2
SFRA-19
19
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
8.73
u
1,4-HxCDD
3
-------
SFRA-19
19
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
20.7
J
1,6-HxCDD
4
SFRA-19
19
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
9.12
U
1,9-HxCDD
5
SFRA-19
19
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
396
1,4,6-HpCDD
6
SFRA-19
19
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
5800
OCDD
7
SFRA-19
19
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
38.6
TCDF
8
SFRA-19
19
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
10.8
J
1-PeCDF
9
SFRA-19
19
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.25
U
4-PeCDF
10
SFRA-19
19
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.9
J
1,4-HxCDF
11
SFRA-19
19
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.6
U
1,6-HxCDF
12
SFRA-19
19
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
7.88
U
1,9-HxCDF
13
SFRA-19
19
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
5.34
J
4,6-HxCDF
14
SFRA-19
19
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
77.6
J
1,4,6-HpCDF
15
SFRA-19
19
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
12.2
U
1,4,9-HpCDF
16
SFRA-19
19
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
215
J
OCDF
17
SFRA-20
20
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
5830
TCDD
1
SFRA-20
20
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
8.79
J
PeCDD
2
SFRA-20
20
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
26.9
J
1,4-HxCDD
3
SFRA-20
20
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
40.9
J
1,6-HxCDD
4
SFRA-20
20
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
20.9
J
1,9-HxCDD
5
SFRA-20
20
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
708
1,4,6-HpCDD
6
SFRA-20
20
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8980
OCDD
7
SFRA-20
20
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
42.5
TCDF
8
SFRA-20
20
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
46
J
1-PeCDF
9
SFRA-20
20
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.5
J
4-PeCDF
10
SFRA-20
20
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
17.3
J
1,4-HxCDF
11
SFRA-20
20
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
10.2
J
1,6-HxCDF
12
SFRA-20
20
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
6.43
U
1,9-HxCDF
13
SFRA-20
20
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
10.6
J
4,6-HxCDF
14
SFRA-20
20
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
158
1,4,6-HpCDF
15
SFRA-20
20
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
13.2
J
1,4,9-HpCDF
16
SFRA-20
20
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
430
OCDF
17
SFRA-21
21
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1500
TCDD
1
SFRA-21
21
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.96
U
PeCDD
2
SFRA-21
21
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.57
U
1,4-HxCDD
3
SFRA-21
21
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
9.98
J
1,6-HxCDD
4
SFRA-21
21
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
5.78
J
1,9-HxCDD
5
SFRA-21
21
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
202
1,4,6-HpCDD
6
SFRA-21
21
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
5260
OCDD
7
SFRA-21
21
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
9.15
J
TCDF
8
SFRA-21
21
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.39
U
1-PeCDF
9
SFRA-21
21
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.61
U
4-PeCDF
10
SFRA-21
21
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.06
J
1,4-HxCDF
11
SFRA-21
21
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.27
U
1,6-HxCDF
12
SFRA-21
21
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.57
U
1,9-HxCDF
13
SFRA-21
21
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.59
J
4,6-HxCDF
14
SFRA-21
21
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
32.5
J
1,4,6-HpCDF
15
SFRA-21
21
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.08
J
1,4,9-HpCDF
16
SFRA-21
21
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
67
J
OCDF
17
SFRA-22
22
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
218
TCDD
1
SFRA-22
22
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.12
U
PeCDD
2
SFRA-22
22
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
11.3
J
1,4-HxCDD
3
SFRA-22
22
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
84.5
1,6-HxCDD
4
SFRA-22
22
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
18.2
J
1,9-HxCDD
5
SFRA-22
22
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
4020
1,4,6-HpCDD
6
SFRA-22
22
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
45100
OCDD
7
-------
SFRA-22
22
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.36
U
TCDF
8
SFRA-22
22
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
11.3
J
1-PeCDF
9
SFRA-22
22
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.68
U
4-PeCDF
10
SFRA-22
22
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
16.7
J
1,4-HxCDF
11
SFRA-22
22
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.19
U
1,6-HxCDF
12
SFRA-22
22
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
7.4
U
1,9-HxCDF
13
SFRA-22
22
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
9.35
J
4,6-HxCDF
14
SFRA-22
22
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
624
1,4,6-HpCDF
15
SFRA-22
22
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
67.6
1,4,9-HpCDF
16
SFRA-22
22
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
4870
OCDF
17
SFRA-23
23
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4710
TCDD
1
SFRA-23
23
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.29
J
PeCDD
2
SFRA-23
23
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
5.63
J
1,4-HxCDD
3
SFRA-23
23
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
59.7
JQ
1,6-HxCDD
4
SFRA-23
23
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
23.3
JQ
1,9-HxCDD
5
SFRA-23
23
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
547
1,4,6-HpCDD
6
SFRA-23
23
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7320
OCDD
7
SFRA-23
23
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
23.4
TCDF
8
SFRA-23
23
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.38
J
1-PeCDF
9
SFRA-23
23
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.4
J
4-PeCDF
10
SFRA-23
23
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.26
J
1,4-HxCDF
11
SFRA-23
23
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.64
J
1,6-HxCDF
12
SFRA-23
23
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
6.5
U
1,9-HxCDF
13
SFRA-23
23
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
7.27
J
4,6-HxCDF
14
SFRA-23
23
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
97
1,4,6-HpCDF
15
SFRA-23
23
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
7.9
J
1,4,9-HpCDF
16
SFRA-23
23
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
237
OCDF
17
SFRA-24
24
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
416
TCDD
1
SFRA-24
24
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.45
U
PeCDD
2
SFRA-24
24
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.09
J
1,4-HxCDD
3
SFRA-24
24
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
7.54
J
1,6-HxCDD
4
SFRA-24
24
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
4.77
J
1,9-HxCDD
5
SFRA-24
24
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
308
1,4,6-HpCDD
6
SFRA-24
24
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7700
OCDD
7
SFRA-24
24
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.59
J
TCDF
8
SFRA-24
24
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.23
J
1-PeCDF
9
SFRA-24
24
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.84
U
4-PeCDF
10
SFRA-24
24
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.26
U
1,4-HxCDF
11
SFRA-24
24
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.41
U
1,6-HxCDF
12
SFRA-24
24
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.97
U
1,9-HxCDF
13
SFRA-24
24
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.59
J
4,6-HxCDF
14
SFRA-24
24
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
45.9
J
1,4,6-HpCDF
15
SFRA-24
24
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.97
J
1,4,9-HpCDF
16
SFRA-24
24
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
231
OCDF
17
SFRA-26
26
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
530
TCDD
1
SFRA-26
26
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.5
U
PeCDD
2
SFRA-26
26
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
24.5
J
1,4-HxCDD
3
SFRA-26
26
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
123
1,6-HxCDD
4
SFRA-26
26
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
48
J
1,9-HxCDD
5
SFRA-26
26
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
2930
1,4,6-HpCDD
6
SFRA-26
26
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
20100
OCDD
7
SFRA-26
26
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.45
J
TCDF
8
SFRA-26
26
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.2
J
1-PeCDF
9
SFRA-26
26
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.74
J
4-PeCDF
10
SFRA-26
26
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
23.2
J
1,4-HxCDF
11
-------
SFRA-26
26
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
9.71
J
1,6-HxCDF
12
SFRA-26
26
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
9.21
U
1,9-HxCDF
13
SFRA-26
26
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
14.5
J
4,6-HxCDF
14
SFRA-26
26
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
284
1,4,6-HpCDF
15
SFRA-26
26
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
26.8
J
1,4,9-HpCDF
16
SFRA-26
26
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
549
OCDF
17
SFRA-27
27
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
161
TCDD
1
SFRA-27
27
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.93
U
PeCDD
2
SFRA-27
27
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
6.62
J
1,4-HxCDD
3
SFRA-27
27
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
35.2
J
1,6-HxCDD
4
SFRA-27
27
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
14.9
J
1,9-HxCDD
5
SFRA-27
27
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
920
1,4,6-HpCDD
6
SFRA-27
27
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11200
OCDD
7
SFRA-27
27
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.38
U
TCDF
8
SFRA-27
27
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.05
U
1-PeCDF
9
SFRA-27
27
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.03
U
4-PeCDF
10
SFRA-27
27
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
9.19
J
1,4-HxCDF
11
SFRA-27
27
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.63
J
1,6-HxCDF
12
SFRA-27
27
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.51
U
1,9-HxCDF
13
SFRA-27
27
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
7.71
J
4,6-HxCDF
14
SFRA-27
27
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
163
1,4,6-HpCDF
15
SFRA-27
27
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
15.2
J
1,4,9-HpCDF
16
SFRA-27
27
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
611
OCDF
17
SFRA-28
28
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1220
TCDD
1
SFRA-28
28
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.51
U
PeCDD
2
SFRA-28
28
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.66
U
1,4-HxCDD
3
SFRA-28
28
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
7.96
U
1,6-HxCDD
4
SFRA-28
28
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
4.48
J
1,9-HxCDD
5
SFRA-28
28
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
147
1,4,6-HpCDD
6
SFRA-28
28
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
3870
OCDD
7
SFRA-28
28
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
11.2
J
TCDF
8
SFRA-28
28
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
21
J
1-PeCDF
9
SFRA-28
28
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.72
U
4-PeCDF
10
SFRA-28
28
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
7.98
U
1,4-HxCDF
11
SFRA-28
28
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.6
U
1,6-HxCDF
12
SFRA-28
28
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.34
U
1,9-HxCDF
13
SFRA-28
28
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.07
J
4,6-HxCDF
14
SFRA-28
28
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
28.4
J
1,4,6-HpCDF
15
SFRA-28
28
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.3
J
1,4,9-HpCDF
16
SFRA-28
28
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
69.2
J
OCDF
17
SFRA-29
29
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
7.92
J
TCDD
1
SFRA-29
29
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.47
U
PeCDD
2
SFRA-29
29
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
2.38
U
1,4-HxCDD
3
SFRA-29
29
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
2.7
J
1,6-HxCDD
4
SFRA-29
29
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
2.63
U
1,9-HxCDD
5
SFRA-29
29
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
149
1,4,6-HpCDD
6
SFRA-29
29
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8210
OCDD
7
SFRA-29
29
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.21
U
TCDF
8
SFRA-29
29
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.08
U
1-PeCDF
9
SFRA-29
29
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.842
U
4-PeCDF
10
SFRA-29
29
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.16
U
1,4-HxCDF
11
SFRA-29
29
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.11
U
1,6-HxCDF
12
SFRA-29
29
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.95
U
1,9-HxCDF
13
SFRA-29
29
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.22
U
4,6-HxCDF
14
SFRA-29
29
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
5.96
J
1,4,6-HpCDF
15
-------
SFRA-29
29
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
0.579
U
1,4,9-HpCDF
16
SFRA-29
29
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
22.4
J
OCDF
17
SFRA-30
30
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
11000
TCDD
1
SFRA-30
30
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
42.3
U
PeCDD
2
SFRA-30
30
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
61.3
U
1,4-HxCDD
3
SFRA-30
30
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
268
J
1,6-HxCDD
4
SFRA-30
30
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
90.2
J
1,9-HxCDD
5
SFRA-30
30
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
2040
1,4,6-HpCDD
6
SFRA-30
30
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
16500
OCDD
7
SFRA-30
30
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
74.5
J
TCDF
8
SFRA-30
30
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
31.9
J
1-PeCDF
9
SFRA-30
30
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
26.6
U
4-PeCDF
10
SFRA-30
30
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
54.6
U
1,4-HxCDF
11
SFRA-30
30
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
47.1
U
1,6-HxCDF
12
SFRA-30
30
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
88.5
U
1,9-HxCDF
13
SFRA-30
30
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
45.9
J
4,6-HxCDF
14
SFRA-30
30
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
537
J
1,4,6-HpCDF
15
SFRA-30
30
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
68.9
J
1,4,9-HpCDF
16
SFRA-30
30
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
1150
J
OCDF
17
SFRA-31
31
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
20300
TCDD
1
SFRA-31
31
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
32.4
U
PeCDD
2
SFRA-31
31
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
36.5
J
1,4-HxCDD
3
SFRA-31
31
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
190
J
1,6-HxCDD
4
SFRA-31
31
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
62
J
1,9-HxCDD
5
SFRA-31
31
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1560
1,4,6-HpCDD
6
SFRA-31
31
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
13900
OCDD
7
SFRA-31
31
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
101
J
TCDF
8
SFRA-31
31
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
11.2
U
1-PeCDF
9
SFRA-31
31
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
17.5
J
4-PeCDF
10
SFRA-31
31
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
44.3
J
1,4-HxCDF
11
SFRA-31
31
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
28.3
J
1,6-HxCDF
12
SFRA-31
31
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
22.5
U
1,9-HxCDF
13
SFRA-31
31
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
36.5
J
4,6-HxCDF
14
SFRA-31
31
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
645
J
1,4,6-HpCDF
15
SFRA-31
31
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
31.9
U
1,4,9-HpCDF
16
SFRA-31
31
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
501
J
OCDF
17
SFRA-32
32
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3190
TCDD
1
SFRA-32
32
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
5.04
U
PeCDD
2
SFRA-32
32
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
12.5
J
1,4-HxCDD
3
SFRA-32
32
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
29.7
J
1,6-HxCDD
4
SFRA-32
32
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
12.5
J
1,9-HxCDD
5
SFRA-32
32
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
510
1,4,6-HpCDD
6
SFRA-32
32
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
10900
OCDD
7
SFRA-32
32
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
22.5
TCDF
8
SFRA-32
32
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
17.8
J
1-PeCDF
9
SFRA-32
32
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.03
U
4-PeCDF
10
SFRA-32
32
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
11.2
U
1,4-HxCDF
11
SFRA-32
32
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.2
J
1,6-HxCDF
12
SFRA-32
32
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.91
U
1,9-HxCDF
13
SFRA-32
32
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
6.98
U
4,6-HxCDF
14
SFRA-32
32
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
92.9
1,4,6-HpCDF
15
SFRA-32
32
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
8.49
J
1,4,9-HpCDF
16
SFRA-32
32
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
137
OCDF
17
SFRA-33
33
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
24400
TCDD
1
SFRA-33
33
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
16.4
U
PeCDD
2
-------
SFRA-33
33
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
52.7
U
1,4-HxCDD
3
SFRA-33
33
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
49.3
U
1,6-HxCDD
4
SFRA-33
33
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
53.8
U
1,9-HxCDD
5
SFRA-33
33
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
704
1,4,6-HpCDD
6
SFRA-33
33
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
10700
OCDD
7
SFRA-33
33
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
154
TCDF
8
SFRA-33
33
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
14.6
U
1-PeCDF
9
SFRA-33
33
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
14
U
4-PeCDF
10
SFRA-33
33
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
24.5
U
1,4-HxCDF
11
SFRA-33
33
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
24.5
U
1,6-HxCDF
12
SFRA-33
33
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
47
U
1,9-HxCDF
13
SFRA-33
33
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
27.9
U
4,6-HxCDF
14
SFRA-33
33
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
158
J
1,4,6-HpCDF
15
SFRA-33
33
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
22.5
U
1,4,9-HpCDF
16
SFRA-33
33
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
220
J
OCDF
17
SFRA-37
37
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
6680
TCDD
1
SFRA-37
37
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
7.84
U
PeCDD
2
SFRA-37
37
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
15
U
1,4-HxCDD
3
SFRA-37
37
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
30.6
J
1,6-HxCDD
4
SFRA-37
37
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
17.4
J
1,9-HxCDD
5
SFRA-37
37
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
754
1,4,6-HpCDD
6
SFRA-37
37
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11900
OCDD
7
SFRA-37
37
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
35.4
J
TCDF
8
SFRA-37
37
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.73
U
1-PeCDF
9
SFRA-37
37
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.02
U
4-PeCDF
10
SFRA-37
37
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
14
U
1,4-HxCDF
11
SFRA-37
37
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.77
U
1,6-HxCDF
12
SFRA-37
37
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
12
U
1,9-HxCDF
13
SFRA-37
37
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
11
J
4,6-HxCDF
14
SFRA-37
37
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
110
J
1,4,6-HpCDF
15
SFRA-37
37
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
5.93
J
1,4,9-HpCDF
16
SFRA-37
37
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
175
J
OCDF
17
SFRA-38
38
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2560
TCDD
1
SFRA-38
38
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.21
U
PeCDD
2
SFRA-38
38
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
5.13
J
1,4-HxCDD
3
SFRA-38
38
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
21.6
J
1,6-HxCDD
4
SFRA-38
38
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
10.7
J
1,9-HxCDD
5
SFRA-38
38
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
382
1,4,6-HpCDD
6
SFRA-38
38
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
9700
OCDD
7
SFRA-38
38
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
15.2
TCDF
8
SFRA-38
38
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.43
J
1-PeCDF
9
SFRA-38
38
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.99
J
4-PeCDF
10
SFRA-38
38
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.29
J
1,4-HxCDF
11
SFRA-38
38
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.27
J
1,6-HxCDF
12
SFRA-38
38
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.92
U
1,9-HxCDF
13
SFRA-38
38
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.36
J
4,6-HxCDF
14
SFRA-38
38
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
63.7
1,4,6-HpCDF
15
SFRA-38
38
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
5.13
J
1,4,9-HpCDF
16
SFRA-38
38
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
97
J
OCDF
17
SFRA-39
39
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3200
TCDD
1
SFRA-39
39
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.57
U
PeCDD
2
SFRA-39
39
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
4.59
J
1,4-HxCDD
3
SFRA-39
39
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
27.9
J
1,6-HxCDD
4
SFRA-39
39
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
10.4
J
1,9-HxCDD
5
SFRA-39
39
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
482
1,4,6-HpCDD
6
-------
SFRA-39
39
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11300
OCDD
7
SFRA-39
39
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
27.8
TCDF
8
SFRA-39
39
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.17
J
1-PeCDF
9
SFRA-39
39
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.33
J
4-PeCDF
10
SFRA-39
39
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
9.58
J
1,4-HxCDF
11
SFRA-39
39
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.52
U
1,6-HxCDF
12
SFRA-39
39
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.99
U
1,9-HxCDF
13
SFRA-39
39
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
5.82
U
4,6-HxCDF
14
SFRA-39
39
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
79.1
1,4,6-HpCDF
15
SFRA-39
39
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
5.65
U
1,4,9-HpCDF
16
SFRA-39
39
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
121
J
OCDF
17
SFRA-40
40
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
163
TCDD
1
SFRA-40
40
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.72
U
PeCDD
2
SFRA-40
40
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
56.3
J
1,4-HxCDD
3
SFRA-40
40
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
87.8
1,6-HxCDD
4
SFRA-40
40
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
23.5
J
1,9-HxCDD
5
SFRA-40
40
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1880
1,4,6-HpCDD
6
SFRA-40
40
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
21500
OCDD
7
SFRA-40
40
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
4.93
J
TCDF
8
SFRA-40
40
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.06
U
1-PeCDF
9
SFRA-40
40
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
7.39
J
4-PeCDF
10
SFRA-40
40
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
24.9
J
1,4-HxCDF
11
SFRA-40
40
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
8.46
U
1,6-HxCDF
12
SFRA-40
40
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
8.13
U
1,9-HxCDF
13
SFRA-40
40
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
17.1
J
4,6-HxCDF
14
SFRA-40
40
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
269
1,4,6-HpCDF
15
SFRA-40
40
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
29.5
J
1,4,9-HpCDF
16
SFRA-40
40
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
624
OCDF
17
SFRA-41
41
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
13300
TCDD
1
SFRA-41
41
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
13.1
U
PeCDD
2
SFRA-41
41
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
23.7
J
1,4-HxCDD
3
SFRA-41
41
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
88.5
J
1,6-HxCDD
4
SFRA-41
41
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
28.5
J
1,9-HxCDD
5
SFRA-41
41
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1280
1,4,6-HpCDD
6
SFRA-41
41
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
14500
OCDD
7
SFRA-41
41
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
69.1
J
TCDF
8
SFRA-41
41
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
9.26
U
1-PeCDF
9
SFRA-41
41
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
8.83
U
4-PeCDF
10
SFRA-41
41
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
44.7
J
1,4-HxCDF
11
SFRA-41
41
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
16.9
J
1,6-HxCDF
12
SFRA-41
41
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
16.2
U
1,9-HxCDF
13
SFRA-41
41
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
21.4
J
4,6-HxCDF
14
SFRA-41
41
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
376
J
1,4,6-HpCDF
15
SFRA-41
41
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
40.5
J
1,4,9-HpCDF
16
SFRA-41
41
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
567
J
OCDF
17
SFRA-42
42
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
6160
TCDD
1
SFRA-42
42
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
13.3
U
PeCDD
2
SFRA-42
42
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
24.2
U
1,4-HxCDD
3
SFRA-42
42
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
40.5
J
1,6-HxCDD
4
SFRA-42
42
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
26.7
U
1,9-HxCDD
5
SFRA-42
42
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
766
1,4,6-HpCDD
6
SFRA-42
42
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
13900
OCDD
7
SFRA-42
42
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
33.6
J
TCDF
8
SFRA-42
42
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
12.7
U
1-PeCDF
9
SFRA-42
42
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
13.2
U
4-PeCDF
10
-------
SFRA-42
42
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
20.9
J
1,4-HxCDF
11
SFRA-42
42
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
9.64
U
1,6-HxCDF
12
SFRA-42
42
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
20.1
U
1,9-HxCDF
13
SFRA-42
42
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
14.6
J
4,6-HxCDF
14
SFRA-42
42
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
140
J
1,4,6-HpCDF
15
SFRA-42
42
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
19.2
U
1,4,9-HpCDF
16
SFRA-42
42
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
226
J
OCDF
17
SFRA-43
43
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
20700
TCDD
1
SFRA-43
43
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
20.5
U
PeCDD
2
SFRA-43
43
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
31.6
J
1,4-HxCDD
3
SFRA-43
43
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
57.2
J
1,6-HxCDD
4
SFRA-43
43
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
29.7
U
1,9-HxCDD
5
SFRA-43
43
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
952
1,4,6-HpCDD
6
SFRA-43
43
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
13400
OCDD
7
SFRA-43
43
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
94
J
TCDF
8
SFRA-43
43
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
17
U
1-PeCDF
9
SFRA-43
43
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
16.3
U
4-PeCDF
10
SFRA-43
43
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
29.1
J
1,4-HxCDF
11
SFRA-43
43
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
21.8
U
1,6-HxCDF
12
SFRA-43
43
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
36.8
U
1,9-HxCDF
13
SFRA-43
43
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
21.5
U
4,6-HxCDF
14
SFRA-43
43
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
244
J
1,4,6-HpCDF
15
SFRA-43
43
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
36.6
U
1,4,9-HpCDF
16
SFRA-43
43
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
301
J
OCDF
17
SFRA-44
44
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
14000
TCDD
1
SFRA-44
44
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
13.2
U
PeCDD
2
SFRA-44
44
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
31.2
J
1,4-HxCDD
3
SFRA-44
44
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
233
J
1,6-HxCDD
4
SFRA-44
44
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
72.1
J
1,9-HxCDD
5
SFRA-44
44
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
2160
1,4,6-HpCDD
6
SFRA-44
44
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
15500
OCDD
7
SFRA-44
44
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
86.4
J
TCDF
8
SFRA-44
44
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
9.89
U
1-PeCDF
9
SFRA-44
44
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
12
J
4-PeCDF
10
SFRA-44
44
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
53.2
J
1,4-HxCDF
11
SFRA-44
44
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
22.6
U
1,6-HxCDF
12
SFRA-44
44
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
26.4
U
1,9-HxCDF
13
SFRA-44
44
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
37.4
J
4,6-HxCDF
14
SFRA-44
44
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
736
1,4,6-HpCDF
15
SFRA-44
44
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
38.3
U
1,4,9-HpCDF
16
SFRA-44
44
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
661
J
OCDF
17
SFRA-45
45
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
10600
TCDD
1
SFRA-45
45
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
15.3
U
PeCDD
2
SFRA-45
45
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
28.4
U
1,4-HxCDD
3
SFRA-45
45
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
40.2
J
1,6-HxCDD
4
SFRA-45
45
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
30.1
U
1,9-HxCDD
5
SFRA-45
45
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
605
1,4,6-HpCDD
6
SFRA-45
45
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11800
OCDD
7
SFRA-45
45
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
56.6
J
TCDF
8
SFRA-45
45
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
12.6
U
1-PeCDF
9
SFRA-45
45
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
11.8
U
4-PeCDF
10
SFRA-45
45
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
16.6
U
1,4-HxCDF
11
SFRA-45
45
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
16.6
U
1,6-HxCDF
12
SFRA-45
45
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
32.5
U
1,9-HxCDF
13
SFRA-45
45
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
17.4
U
4,6-HxCDF
14
-------
SFRA-45
45
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
158
J
1,4,6-HpCDF
15
SFRA-45
45
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
37.9
U
1,4,9-HpCDF
16
SFRA-45
45
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
209
J
OCDF
17
SFRA-46
46
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
30700
TCDD
1
SFRA-46
46
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
17.2
U
PeCDD
2
SFRA-46
46
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
77.3
U
1,4-HxCDD
3
SFRA-46
46
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
100
J
1,6-HxCDD
4
SFRA-46
46
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
79
U
1,9-HxCDD
5
SFRA-46
46
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1060
1,4,6-HpCDD
6
SFRA-46
46
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
13000
OCDD
7
SFRA-46
46
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
137
J
TCDF
8
SFRA-46
46
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
13.3
U
1-PeCDF
9
SFRA-46
46
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
13.2
U
4-PeCDF
10
SFRA-46
46
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
30.4
J
1,4-HxCDF
11
SFRA-46
46
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
17.6
U
1,6-HxCDF
12
SFRA-46
46
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
28.1
U
1,9-HxCDF
13
SFRA-46
46
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
22
U
4,6-HxCDF
14
SFRA-46
46
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
426
J
1,4,6-HpCDF
15
SFRA-46
46
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
26
U
1,4,9-HpCDF
16
SFRA-46
46
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
559
J
OCDF
17
SFRA-47
47
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4310
TCDD
1
SFRA-47
47
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.89
U
PeCDD
2
SFRA-47
47
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
5.93
U
1,4-HxCDD
3
SFRA-47
47
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
6.06
U
1,6-HxCDD
4
SFRA-47
47
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
6.36
U
1,9-HxCDD
5
SFRA-47
47
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
153
1,4,6-HpCDD
6
SFRA-47
47
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7910
OCDD
7
SFRA-47
47
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
19.7
J
TCDF
8
SFRA-47
47
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.77
U
1-PeCDF
9
SFRA-47
47
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.69
U
4-PeCDF
10
SFRA-47
47
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.31
U
1,4-HxCDF
11
SFRA-47
47
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.18
U
1,6-HxCDF
12
SFRA-47
47
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
3.81
U
1,9-HxCDF
13
SFRA-47
47
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.35
U
4,6-HxCDF
14
SFRA-47
47
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
16.9
J
1,4,6-HpCDF
15
SFRA-47
47
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.08
U
1,4,9-HpCDF
16
SFRA-47
47
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
28.9
J
OCDF
17
SFRA-48
48
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
7320
TCDD
1
SFRA-48
48
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
8.22
U
PeCDD
2
SFRA-48
48
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
16.2
U
1,4-HxCDD
3
SFRA-48
48
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
27.3
u
1,6-HxCDD
4
SFRA-48
48
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
16.2
u
1,9-HxCDD
5
SFRA-48
48
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
408
1,4,6-HpCDD
6
SFRA-48
48
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
9930
OCDD
7
SFRA-48
48
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
51.6
J
TCDF
8
SFRA-48
48
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.83
u
1-PeCDF
9
SFRA-48
48
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.85
u
4-PeCDF
10
SFRA-48
48
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
10.8
u
1,4-HxCDF
11
SFRA-48
48
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
10.5
u
1,6-HxCDF
12
SFRA-48
48
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
20.2
u
1,9-HxCDF
13
SFRA-48
48
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
11
u
4,6-HxCDF
14
SFRA-48
48
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
101
J
1,4,6-HpCDF
15
SFRA-48
48
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
15.3
u
1,4,9-HpCDF
16
SFRA-48
48
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
101
J
OCDF
17
SFRA-49
49
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1410
TCDD
1
-------
SFRA-49
49
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.78
U
PeCDD
2
SFRA-49
49
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
7.61
J
1,4-HxCDD
3
SFRA-49
49
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
11.5
J
1,6-HxCDD
4
SFRA-49
49
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
5.39
J
1,9-HxCDD
5
SFRA-49
49
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
270
1,4,6-HpCDD
6
SFRA-49
49
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8070
OCDD
7
SFRA-49
49
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
8.8
J
TCDF
8
SFRA-49
49
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.22
U
1-PeCDF
9
SFRA-49
49
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.02
U
4-PeCDF
10
SFRA-49
49
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5
J
1,4-HxCDF
11
SFRA-49
49
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.84
J
1,6-HxCDF
12
SFRA-49
49
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.31
U
1,9-HxCDF
13
SFRA-49
49
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.41
U
4,6-HxCDF
14
SFRA-49
49
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
43.1
J
1,4,6-HpCDF
15
SFRA-49
49
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.41
J
1,4,9-HpCDF
16
SFRA-49
49
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
75.9
J
OCDF
17
SFRA-50
50
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2650
TCDD
1
SFRA-50
50
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.51
U
PeCDD
2
SFRA-50
50
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
17.8
J
1,4-HxCDD
3
SFRA-50
50
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
57.7
1,6-HxCDD
4
SFRA-50
50
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
17.9
J
1,9-HxCDD
5
SFRA-50
50
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
642
1,4,6-HpCDD
6
SFRA-50
50
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
12100
OCDD
7
SFRA-50
50
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
19.1
TCDF
8
SFRA-50
50
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
14.9
J
1-PeCDF
9
SFRA-50
50
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.21
J
4-PeCDF
10
SFRA-50
50
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
13.1
J
1,4-HxCDF
11
SFRA-50
50
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.45
J
1,6-HxCDF
12
SFRA-50
50
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.93
U
1,9-HxCDF
13
SFRA-50
50
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
7.39
J
4,6-HxCDF
14
SFRA-50
50
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
106
1,4,6-HpCDF
15
SFRA-50
50
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
9.14
J
1,4,9-HpCDF
16
SFRA-50
50
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
190
OCDF
17
SFRA-51
51
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4380
TCDD
1
SFRA-51
51
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
7.73
U
PeCDD
2
SFRA-51
51
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
15.6
J
1,4-HxCDD
3
SFRA-51
51
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
29.3
J
1,6-HxCDD
4
SFRA-51
51
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
13.2
U
1,9-HxCDD
5
SFRA-51
51
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
533
1,4,6-HpCDD
6
SFRA-51
51
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
12500
OCDD
7
SFRA-51
51
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
26.2
J
TCDF
8
SFRA-51
51
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
9.77
U
1-PeCDF
9
SFRA-51
51
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
9.51
U
4-PeCDF
10
SFRA-51
51
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
13.2
U
1,4-HxCDF
11
SFRA-51
51
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.71
U
1,6-HxCDF
12
SFRA-51
51
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
14
U
1,9-HxCDF
13
SFRA-51
51
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
8.01
U
4,6-HxCDF
14
SFRA-51
51
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
96.7
J
1,4,6-HpCDF
15
SFRA-51
51
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
11.5
U
1,4,9-HpCDF
16
SFRA-51
51
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
136
J
OCDF
17
SFRA-52
52
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2400
TCDD
1
SFRA-52
52
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.31
J
PeCDD
2
SFRA-52
52
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.2
J
1,4-HxCDD
3
SFRA-52
52
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
13
J
1,6-HxCDD
4
SFRA-52
52
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
6.06
J
1,9-HxCDD
5
-------
SFRA-52
52
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
262
1,4,6-HpCDD
6
SFRA-52
52
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7840
OCDD
7
SFRA-52
52
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
13.9
TCDF
8
SFRA-52
52
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.39
U
1-PeCDF
9
SFRA-52
52
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.53
J
4-PeCDF
10
SFRA-52
52
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.91
J
1,4-HxCDF
11
SFRA-52
52
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.9
J
1,6-HxCDF
12
SFRA-52
52
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.04
U
1,9-HxCDF
13
SFRA-52
52
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.91
J
4,6-HxCDF
14
SFRA-52
52
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
45
J
1,4,6-HpCDF
15
SFRA-52
52
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.89
U
1,4,9-HpCDF
16
SFRA-52
52
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
120
J
OCDF
17
SFRA-53
53
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
42600
TCDD
1
SFRA-53
53
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
26.9
U
PeCDD
2
SFRA-53
53
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
48.4
U
1,4-HxCDD
3
SFRA-53
53
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
45.4
U
1,6-HxCDD
4
SFRA-53
53
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
49.4
U
1,9-HxCDD
5
SFRA-53
53
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
904
J
1,4,6-HpCDD
6
SFRA-53
53
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
15700
OCDD
7
SFRA-53
53
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
186
J
TCDF
8
SFRA-53
53
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
19.4
U
1-PeCDF
9
SFRA-53
53
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
19.2
U
4-PeCDF
10
SFRA-53
53
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
22
U
1,4-HxCDF
11
SFRA-53
53
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
21.5
U
1,6-HxCDF
12
SFRA-53
53
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
42
U
1,9-HxCDF
13
SFRA-53
53
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
24.2
U
4,6-HxCDF
14
SFRA-53
53
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
156
J
1,4,6-HpCDF
15
SFRA-53
53
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
41
U
1,4,9-HpCDF
16
SFRA-53
53
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
581
J
OCDF
17
SFRA-54
54
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
19700
TCDD
1
SFRA-54
54
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
8.16
U
PeCDD
2
SFRA-54
54
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
21.1
U
1,4-HxCDD
3
SFRA-54
54
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
23.3
J
1,6-HxCDD
4
SFRA-54
54
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
21.5
U
1,9-HxCDD
5
SFRA-54
54
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
848
1,4,6-HpCDD
6
SFRA-54
54
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
23700
OCDD
7
SFRA-54
54
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
81.4
J
TCDF
8
SFRA-54
54
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.12
U
1-PeCDF
9
SFRA-54
54
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.87
U
4-PeCDF
10
SFRA-54
54
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.1
U
1,4-HxCDF
11
SFRA-54
54
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.55
U
1,6-HxCDF
12
SFRA-54
54
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
11.1
U
1,9-HxCDF
13
SFRA-54
54
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
6.48
U
4,6-HxCDF
14
SFRA-54
54
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
140
J
1,4,6-HpCDF
15
SFRA-54
54
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
21.6
U
1,4,9-HpCDF
16
SFRA-54
54
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
622
J
OCDF
17
SFRA-55
55
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
13800
TCDD
1
SFRA-55
55
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
16.6
U
PeCDD
2
SFRA-55
55
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
36.7
J
1,4-HxCDD
3
SFRA-55
55
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
150
J
1,6-HxCDD
4
SFRA-55
55
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
54.8
J
1,9-HxCDD
5
SFRA-55
55
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1430
1,4,6-HpCDD
6
SFRA-55
55
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
14000
OCDD
7
SFRA-55
55
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
78.6
J
TCDF
8
SFRA-55
55
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
16.1
u
1-PeCDF
9
-------
SFRA-55
55
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
16
U
4-PeCDF
10
SFRA-55
55
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
33.2
U
1,4-HxCDF
11
SFRA-55
55
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
19.3
J
1,6-HxCDF
12
SFRA-55
55
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
37.5
U
1,9-HxCDF
13
SFRA-55
55
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
22.1
U
4,6-HxCDF
14
SFRA-55
55
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
453
J
1,4,6-HpCDF
15
SFRA-55
55
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
38.7
U
1,4,9-HpCDF
16
SFRA-55
55
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
423
J
OCDF
17
SFRA-56
56
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
15600
TCDD
1
SFRA-56
56
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
21.4
J
PeCDD
2
SFRA-56
56
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
25.8
U
1,4-HxCDD
3
SFRA-56
56
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
256
J
1,6-HxCDD
4
SFRA-56
56
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
81.2
J
1,9-HxCDD
5
SFRA-56
56
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
4360
1,4,6-HpCDD
6
SFRA-56
56
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
38000
OCDD
7
SFRA-56
56
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
88.6
J
TCDF
8
SFRA-56
56
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
11.1
U
1-PeCDF
9
SFRA-56
56
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
23.6
U
4-PeCDF
10
SFRA-56
56
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
39.2
J
1,4-HxCDF
11
SFRA-56
56
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
30.6
U
1,6-HxCDF
12
SFRA-56
56
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
36.7
U
1,9-HxCDF
13
SFRA-56
56
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
40.3
J
4,6-HxCDF
14
SFRA-56
56
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
937
1,4,6-HpCDF
15
SFRA-56
56
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
95
J
1,4,9-HpCDF
16
SFRA-56
56
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
3970
OCDF
17
SFRA-57
57
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
344
TCDD
1
SFRA-57
57
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.96
U
PeCDD
2
SFRA-57
57
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.86
J
1,4-HxCDD
3
SFRA-57
57
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
25
U
1,6-HxCDD
4
SFRA-57
57
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
9.11
U
1,9-HxCDD
5
SFRA-57
57
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
705
1,4,6-HpCDD
6
SFRA-57
57
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
13400
OCDD
7
SFRA-57
57
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.82
J
TCDF
8
SFRA-57
57
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.49
U
1-PeCDF
9
SFRA-57
57
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.65
U
4-PeCDF
10
SFRA-57
57
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
4.35
J
1,4-HxCDF
11
SFRA-57
57
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.66
U
1,6-HxCDF
12
SFRA-57
57
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
3.66
U
1,9-HxCDF
13
SFRA-57
57
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.02
J
4,6-HxCDF
14
SFRA-57
57
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
148
1,4,6-HpCDF
15
SFRA-57
57
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
11.3
J
1,4,9-HpCDF
16
SFRA-57
57
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
1040
OCDF
17
SFRA-58
58
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
26000
TCDD
1
SFRA-58
58
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
11.8
U
PeCDD
2
SFRA-58
58
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
16.2
U
1,4-HxCDD
3
SFRA-58
58
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
102
J
1,6-HxCDD
4
SFRA-58
58
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
32.7
J
1,9-HxCDD
5
SFRA-58
58
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
901
1,4,6-HpCDD
6
SFRA-58
58
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
10900
OCDD
7
SFRA-58
58
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
132
TCDF
8
SFRA-58
58
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
7.89
U
1-PeCDF
9
SFRA-58
58
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
12.9
U
4-PeCDF
10
SFRA-58
58
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
13.1
U
1,4-HxCDF
11
SFRA-58
58
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
13.3
U
1,6-HxCDF
12
SFRA-58
58
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
18.5
U
1,9-HxCDF
13
-------
SFRA-58
58
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
19.8
J
4,6-HxCDF
14
SFRA-58
58
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
251
J
1,4,6-HpCDF
15
SFRA-58
58
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
21.3
J
1,4,9-HpCDF
16
SFRA-58
58
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
450
J
OCDF
17
SFRA-59
59
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3890
TCDD
1
SFRA-59
59
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.54
J
PeCDD
2
SFRA-59
59
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.05
J
1,4-HxCDD
3
SFRA-59
59
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
28.6
JQ
1,6-HxCDD
4
SFRA-59
59
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
12.2
J
1,9-HxCDD
5
SFRA-59
59
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
392
1,4,6-HpCDD
6
SFRA-59
59
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
9570
OCDD
7
SFRA-59
59
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
21.1
TCDF
8
SFRA-59
59
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.25
J
1-PeCDF
9
SFRA-59
59
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.14
J
4-PeCDF
10
SFRA-59
59
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.53
U
1,4-HxCDF
11
SFRA-59
59
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3
U
1,6-HxCDF
12
SFRA-59
59
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.55
U
1,9-HxCDF
13
SFRA-59
59
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.51
U
4,6-HxCDF
14
SFRA-59
59
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
81.9
1,4,6-HpCDF
15
SFRA-59
59
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
4.97
J
1,4,9-HpCDF
16
SFRA-59
59
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
201
OCDF
17
SFRA-60
60
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
5520
TCDD
1
SFRA-60
60
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
6.16
J
PeCDD
2
SFRA-60
60
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
13
U
1,4-HxCDD
3
SFRA-60
60
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
47.1
J
1,6-HxCDD
4
SFRA-60
60
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
13.6
U
1,9-HxCDD
5
SFRA-60
60
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
600
1,4,6-HpCDD
6
SFRA-60
60
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
12900
OCDD
7
SFRA-60
60
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
29.4
J
TCDF
8
SFRA-60
60
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.62
U
1-PeCDF
9
SFRA-60
60
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.34
J
4-PeCDF
10
SFRA-60
60
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5.41
U
1,4-HxCDF
11
SFRA-60
60
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.61
U
1,6-HxCDF
12
SFRA-60
60
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
8.56
U
1,9-HxCDF
13
SFRA-60
60
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
5.94
U
4,6-HxCDF
14
SFRA-60
60
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
123
J
1,4,6-HpCDF
15
SFRA-60
60
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
12
J
1,4,9-HpCDF
16
SFRA-60
60
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
386
J
OCDF
17
SFRA-61
61
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2490
TCDD
1
SFRA-61
61
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.22
U
PeCDD
2
SFRA-61
61
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
2.95
J
1,4-HxCDD
3
SFRA-61
61
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
25.7
J
1,6-HxCDD
4
SFRA-61
61
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
8.9
J
1,9-HxCDD
5
SFRA-61
61
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
387
1,4,6-HpCDD
6
SFRA-61
61
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
12200
OCDD
7
SFRA-61
61
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
12.1
J
TCDF
8
SFRA-61
61
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.881
U
1-PeCDF
9
SFRA-61
61
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.98
U
4-PeCDF
10
SFRA-61
61
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.73
U
1,4-HxCDF
11
SFRA-61
61
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.4
U
1,6-HxCDF
12
SFRA-61
61
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
3.72
U
1,9-HxCDF
13
SFRA-61
61
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.1
U
4,6-HxCDF
14
SFRA-61
61
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
88.3
1,4,6-HpCDF
15
SFRA-61
61
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
4.22
U
1,4,9-HpCDF
16
SFRA-61
61
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
177
OCDF
17
-------
SFRA-62
62
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1460
TCDD
1
SFRA-62
62
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.33
J
PeCDD
2
SFRA-62
62
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
4.85
J
1,4-HxCDD
3
SFRA-62
62
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
24.7
U
1,6-HxCDD
4
SFRA-62
62
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
12
J
1,9-HxCDD
5
SFRA-62
62
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
304
1,4,6-HpCDD
6
SFRA-62
62
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
9040
OCDD
7
SFRA-62
62
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
7.84
J
TCDF
8
SFRA-62
62
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.87
J
1-PeCDF
9
SFRA-62
62
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.73
J
4-PeCDF
10
SFRA-62
62
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5.3
U
1,4-HxCDF
11
SFRA-62
62
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.61
J
1,6-HxCDF
12
SFRA-62
62
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.31
U
1,9-HxCDF
13
SFRA-62
62
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
5.25
J
4,6-HxCDF
14
SFRA-62
62
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
61.8
1,4,6-HpCDF
15
SFRA-62
62
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
7.81
U
1,4,9-HpCDF
16
SFRA-62
62
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
143
OCDF
17
SFRA-63
63
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2.72
J
TCDD
1
SFRA-63
63
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.12
U
PeCDD
2
SFRA-63
63
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
1.25
U
1,4-HxCDD
3
SFRA-63
63
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
1.33
U
1,6-HxCDD
4
SFRA-63
63
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
1.37
U
1,9-HxCDD
5
SFRA-63
63
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
20.3
J
1,4,6-HpCDD
6
SFRA-63
63
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8050
OCDD
7
SFRA-63
63
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
0.887
U
TCDF
8
SFRA-63
63
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.562
U
1-PeCDF
9
SFRA-63
63
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.522
U
4-PeCDF
10
SFRA-63
63
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.649
U
1,4-HxCDF
11
SFRA-63
63
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.645
U
1,6-HxCDF
12
SFRA-63
63
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.01
U
1,9-HxCDF
13
SFRA-63
63
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
0.667
U
4,6-HxCDF
14
SFRA-63
63
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
0.798
J
1,4,6-HpCDF
15
SFRA-63
63
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
1
U
1,4,9-HpCDF
16
SFRA-63
63
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
2.92
U
OCDF
17
SFRA-64
64
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
5.86
J
TCDD
1
SFRA-64
64
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.55
U
PeCDD
2
SFRA-64
64
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
1.75
U
1,4-HxCDD
3
SFRA-64
64
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
1.85
U
1,6-HxCDD
4
SFRA-64
64
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
1.86
U
1,9-HxCDD
5
SFRA-64
64
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
69.5
1,4,6-HpCDD
6
SFRA-64
64
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
6700
OCDD
7
SFRA-64
64
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.06
U
TCDF
8
SFRA-64
64
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.818
U
1-PeCDF
9
SFRA-64
64
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.759
U
4-PeCDF
10
SFRA-64
64
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.11
U
1,4-HxCDF
11
SFRA-64
64
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.919
U
1,6-HxCDF
12
SFRA-64
64
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.45
U
1,9-HxCDF
13
SFRA-64
64
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
0.966
u
4,6-HxCDF
14
SFRA-64
64
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
7.36
J
1,4,6-HpCDF
15
SFRA-64
64
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
1.24
u
1,4,9-HpCDF
16
SFRA-64
64
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
15.4
J
OCDF
17
SFRA-65
65
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
32.6
TCDD
1
SFRA-65
65
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.74
u
PeCDD
2
SFRA-65
65
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
2.38
u
1,4-HxCDD
3
SFRA-65
65
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
4.38
u
1,6-HxCDD
4
-------
SFRA-65
65
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
2.49
U
1,9-HxCDD
5
SFRA-65
65
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
186
1,4,6-HpCDD
6
SFRA-65
65
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
32700
OCDD
7
SFRA-65
65
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.05
U
TCDF
8
SFRA-65
65
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.722
U
1-PeCDF
9
SFRA-65
65
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.724
U
4-PeCDF
10
SFRA-65
65
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.51
U
1,4-HxCDF
11
SFRA-65
65
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.43
U
1,6-HxCDF
12
SFRA-65
65
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.22
U
1,9-HxCDF
13
SFRA-65
65
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.43
U
4,6-HxCDF
14
SFRA-65
65
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
9.79
J
1,4,6-HpCDF
15
SFRA-65
65
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.99
U
1,4,9-HpCDF
16
SFRA-65
65
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
31.1
J
OCDF
17
SFRA-66
66
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
238
TCDD
1
SFRA-66
66
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.88
U
PeCDD
2
SFRA-66
66
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.43
J
1,4-HxCDD
3
SFRA-66
66
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
13.4
J
1,6-HxCDD
4
SFRA-66
66
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
5.81
J
1,9-HxCDD
5
SFRA-66
66
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
363
1,4,6-HpCDD
6
SFRA-66
66
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
19300
OCDD
7
SFRA-66
66
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.55
J
TCDF
8
SFRA-66
66
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.44
U
1-PeCDF
9
SFRA-66
66
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.42
U
4-PeCDF
10
SFRA-66
66
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.43
U
1,4-HxCDF
11
SFRA-66
66
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.02
U
1,6-HxCDF
12
SFRA-66
66
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
3.28
U
1,9-HxCDF
13
SFRA-66
66
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.43
U
4,6-HxCDF
14
SFRA-66
66
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
51.9
J
1,4,6-HpCDF
15
SFRA-66
66
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.73
J
1,4,9-HpCDF
16
SFRA-66
66
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
161
OCDF
17
SFRA-67
67
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3.15
U
TCDD
1
SFRA-67
67
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.69
U
PeCDD
2
SFRA-67
67
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
1.75
U
1,4-HxCDD
3
SFRA-67
67
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
1.8
U
1,6-HxCDD
4
SFRA-67
67
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
1.89
U
1,9-HxCDD
5
SFRA-67
67
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
23
J
1,4,6-HpCDD
6
SFRA-67
67
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
1900
OCDD
7
SFRA-67
67
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
0.915
U
TCDF
8
SFRA-67
67
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.75
U
1-PeCDF
9
SFRA-67
67
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.761
U
4-PeCDF
10
SFRA-67
67
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.803
U
1,4-HxCDF
11
SFRA-67
67
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.767
U
1,6-HxCDF
12
SFRA-67
67
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.19
U
1,9-HxCDF
13
SFRA-67
67
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
0.786
u
4,6-HxCDF
14
SFRA-67
67
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
0.892
u
1,4,6-HpCDF
15
SFRA-67
67
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
1.37
u
1,4,9-HpCDF
16
SFRA-67
67
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
4.59
u
OCDF
17
SFRA-68
68
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
141
TCDD
1
SFRA-68
68
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.83
u
PeCDD
2
SFRA-68
68
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.14
u
1,4-HxCDD
3
SFRA-68
68
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
9.53
J
1,6-HxCDD
4
SFRA-68
68
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
5.59
J
1,9-HxCDD
5
SFRA-68
68
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
271
1,4,6-HpCDD
6
SFRA-68
68
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8220
OCDD
7
SFRA-68
68
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.59
u
TCDF
8
-------
SFRA-68
68
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.84
J
1-PeCDF
9
SFRA-68
68
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.68
U
4-PeCDF
10
SFRA-68
68
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.85
U
1,4-HxCDF
11
SFRA-68
68
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.9
U
1,6-HxCDF
12
SFRA-68
68
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.21
U
1,9-HxCDF
13
SFRA-68
68
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.83
U
4,6-HxCDF
14
SFRA-68
68
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
31.5
J
1,4,6-HpCDF
15
SFRA-68
68
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3.48
U
1,4,9-HpCDF
16
SFRA-68
68
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
99.6
J
OCDF
17
SFRA-69
69
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1.25
U
TCDD
1
SFRA-69
69
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.75
U
PeCDD
2
SFRA-69
69
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
2.36
U
1,4-HxCDD
3
SFRA-69
69
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
2.31
U
1,6-HxCDD
4
SFRA-69
69
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
2.47
U
1,9-HxCDD
5
SFRA-69
69
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
20.8
J
1,4,6-HpCDD
6
SFRA-69
69
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
3360
OCDD
7
SFRA-69
69
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.15
U
TCDF
8
SFRA-69
69
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.783
U
1-PeCDF
9
SFRA-69
69
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.753
U
4-PeCDF
10
SFRA-69
69
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.14
U
1,4-HxCDF
11
SFRA-69
69
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.13
U
1,6-HxCDF
12
SFRA-69
69
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.85
U
1,9-HxCDF
13
SFRA-69
69
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.15
U
4,6-HxCDF
14
SFRA-69
69
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
1.35
U
1,4,6-HpCDF
15
SFRA-69
69
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.03
U
1,4,9-HpCDF
16
SFRA-69
69
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
4.67
U
OCDF
17
SFRA-70
70
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
89.1
TCDD
1
SFRA-70
70
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.9
U
PeCDD
2
SFRA-70
70
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
2.97
U
1,4-HxCDD
3
SFRA-70
70
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
6.54
J
1,6-HxCDD
4
SFRA-70
70
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
3.53
J
1,9-HxCDD
5
SFRA-70
70
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
184
1,4,6-HpCDD
6
SFRA-70
70
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11100
OCDD
7
SFRA-70
70
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.6
U
TCDF
8
SFRA-70
70
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.56
U
1-PeCDF
9
SFRA-70
70
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.57
u
4-PeCDF
10
SFRA-70
70
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.65
J
1,4-HxCDF
11
SFRA-70
70
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.55
u
1,6-HxCDF
12
SFRA-70
70
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.43
u
1,9-HxCDF
13
SFRA-70
70
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.61
u
4,6-HxCDF
14
SFRA-70
70
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
23.6
J
1,4,6-HpCDF
15
SFRA-70
70
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.97
u
1,4,9-HpCDF
16
SFRA-70
70
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
64.1
J
OCDF
17
SFRA-71
71
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1.27
u
TCDD
1
SFRA-71
71
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.52
u
PeCDD
2
SFRA-71
71
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
2.21
u
1,4-HxCDD
3
SFRA-71
71
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
2.26
u
1,6-HxCDD
4
SFRA-71
71
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
2.38
u
1,9-HxCDD
5
SFRA-71
71
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
84.3
1,4,6-HpCDD
6
SFRA-71
71
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
10800
OCDD
7
SFRA-71
71
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.32
u
TCDF
8
SFRA-71
71
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.908
u
1-PeCDF
9
SFRA-71
71
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.888
u
4-PeCDF
10
SFRA-71
71
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
0.725
u
1,4-HxCDF
11
SFRA-71
71
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
0.668
u
1,6-HxCDF
12
-------
SFRA-71
71
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.13
U
1,9-HxCDF
13
SFRA-71
71
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
0.701
U
4,6-HxCDF
14
SFRA-71
71
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
0.975
U
1,4,6-HpCDF
15
SFRA-71
71
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
1.58
U
1,4,9-HpCDF
16
SFRA-71
71
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
4.41
U
OCDF
17
SFRA-72
72
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
573
TCDD
1
SFRA-72
72
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
9.06
J
PeCDD
2
SFRA-72
72
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
54.1
QU
1,4-HxCDD
3
SFRA-72
72
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
964
Q
1,6-HxCDD
4
SFRA-72
72
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
405
Q
1,9-HxCDD
5
SFRA-72
72
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
9020
1,4,6-HpCDD
6
SFRA-72
72
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
52500
OCDD
7
SFRA-72
72
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
12.2
J
TCDF
8
SFRA-72
72
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.15
J
1-PeCDF
9
SFRA-72
72
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
19.7
J
4-PeCDF
10
SFRA-72
72
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
117
Q
1,4-HxCDF
11
SFRA-72
72
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
55.5
J
1,6-HxCDF
12
SFRA-72
72
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
17.3
U
1,9-HxCDF
13
SFRA-72
72
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
92.4
4,6-HxCDF
14
SFRA-72
72
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
1200
1,4,6-HpCDF
15
SFRA-72
72
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
116
1,4,9-HpCDF
16
SFRA-72
72
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
2260
OCDF
17
SFRA-73
73
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3090
TCDD
1
SFRA-73
73
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.57
U
PeCDD
2
SFRA-73
73
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
5.88
U
1,4-HxCDD
3
SFRA-73
73
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
65
1,6-HxCDD
4
SFRA-73
73
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
24.7
J
1,9-HxCDD
5
SFRA-73
73
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
896
1,4,6-HpCDD
6
SFRA-73
73
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
14000
OCDD
7
SFRA-73
73
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
21.1
TCDF
8
SFRA-73
73
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.92
U
1-PeCDF
9
SFRA-73
73
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.18
J
4-PeCDF
10
SFRA-73
73
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
7.56
J
1,4-HxCDF
11
SFRA-73
73
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.08
J
1,6-HxCDF
12
SFRA-73
73
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.72
U
1,9-HxCDF
13
SFRA-73
73
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
8.08
J
4,6-HxCDF
14
SFRA-73
73
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
204
1,4,6-HpCDF
15
SFRA-73
73
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
13.1
J
1,4,9-HpCDF
16
SFRA-73
73
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
586
OCDF
17
SFRA-74
74
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
12000
TCDD
1
SFRA-74
74
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
13.4
U
PeCDD
2
SFRA-74
74
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
22.8
QU
1,4-HxCDD
3
SFRA-74
74
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
171
JQ
1,6-HxCDD
4
SFRA-74
74
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
51.6
J
1,9-HxCDD
5
SFRA-74
74
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1260
1,4,6-HpCDD
6
SFRA-74
74
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
13600
OCDD
7
SFRA-74
74
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
64.4
J
TCDF
8
SFRA-74
74
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
11.9
U
1-PeCDF
9
SFRA-74
74
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
11.8
U
4-PeCDF
10
SFRA-74
74
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
20.9
U
1,4-HxCDF
11
SFRA-74
74
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
22
U
1,6-HxCDF
12
SFRA-74
74
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
18.8
U
1,9-HxCDF
13
SFRA-74
74
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
17.6
J
4,6-HxCDF
14
SFRA-74
74
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
330
J
1,4,6-HpCDF
15
SFRA-74
74
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
24.4
U
1,4,9-HpCDF
16
-------
SFRA-74
74
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
602
J
OCDF
17
SFRA-75
75
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
4690
TCDD
1
SFRA-75
75
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
6.24
U
PeCDD
2
SFRA-75
75
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
10.5
QU
1,4-HxCDD
3
SFRA-75
75
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
125
JQ
1,6-HxCDD
4
SFRA-75
75
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
35.1
J
1,9-HxCDD
5
SFRA-75
75
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1300
1,4,6-HpCDD
6
SFRA-75
75
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
18800
OCDD
7
SFRA-75
75
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
30.1
J
TCDF
8
SFRA-75
75
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.05
U
1-PeCDF
9
SFRA-75
75
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
7.69
U
4-PeCDF
10
SFRA-75
75
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
12.1
U
1,4-HxCDF
11
SFRA-75
75
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
9.47
U
1,6-HxCDF
12
SFRA-75
75
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
10.8
U
1,9-HxCDF
13
SFRA-75
75
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
11.9
J
4,6-HxCDF
14
SFRA-75
75
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
286
1,4,6-HpCDF
15
SFRA-75
75
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
20.4
J
1,4,9-HpCDF
16
SFRA-75
75
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
1090
OCDF
17
SFRA-76
76
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
941
TCDD
1
SFRA-76
76
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.65
U
PeCDD
2
SFRA-76
76
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
6.09
U
1,4-HxCDD
3
SFRA-76
76
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
12.5
U
1,6-HxCDD
4
SFRA-76
76
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
6.55
U
1,9-HxCDD
5
SFRA-76
76
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
172
1,4,6-HpCDD
6
SFRA-76
76
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
17400
OCDD
7
SFRA-76
76
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.18
J
TCDF
8
SFRA-76
76
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.26
U
1-PeCDF
9
SFRA-76
76
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.13
U
4-PeCDF
10
SFRA-76
76
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
3.02
U
1,4-HxCDF
11
SFRA-76
76
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.95
U
1,6-HxCDF
12
SFRA-76
76
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.1
U
1,9-HxCDF
13
SFRA-76
76
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.04
U
4,6-HxCDF
14
SFRA-76
76
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
31
J
1,4,6-HpCDF
15
SFRA-76
76
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
5.6
U
1,4,9-HpCDF
16
SFRA-76
76
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
58.1
J
OCDF
17
SFRA-77
77
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1020
TCDD
1
SFRA-77
77
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.79
U
PeCDD
2
SFRA-77
77
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
8.93
U
1,4-HxCDD
3
SFRA-77
77
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
28.9
J
1,6-HxCDD
4
SFRA-77
77
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
10.1
J
1,9-HxCDD
5
SFRA-77
77
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
485
1,4,6-HpCDD
6
SFRA-77
77
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
23800
OCDD
7
SFRA-77
77
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
10
J
TCDF
8
SFRA-77
77
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.03
U
1-PeCDF
9
SFRA-77
77
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.98
U
4-PeCDF
10
SFRA-77
77
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.44
J
1,4-HxCDF
11
SFRA-77
77
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.96
J
1,6-HxCDF
12
SFRA-77
77
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.93
U
1,9-HxCDF
13
SFRA-77
77
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.75
U
4,6-HxCDF
14
SFRA-77
77
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
98.4
1,4,6-HpCDF
15
SFRA-77
77
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
7.99
U
1,4,9-HpCDF
16
SFRA-77
77
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
246
OCDF
17
SFRA-78
78
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2430
TCDD
1
SFRA-78
78
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.9
J
PeCDD
2
SFRA-78
78
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
9.23
QU
1,4-HxCDD
3
-------
SFRA-78
78
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
124
Q
1,6-HxCDD
4
SFRA-78
78
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
36.7
J
1,9-HxCDD
5
SFRA-78
78
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
821
1,4,6-HpCDD
6
SFRA-78
78
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8100
OCDD
7
SFRA-78
78
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
14.3
TCDF
8
SFRA-78
78
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.45
J
1-PeCDF
9
SFRA-78
78
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.93
J
4-PeCDF
10
SFRA-78
78
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
8.82
J
1,4-HxCDF
11
SFRA-78
78
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.78
J
1,6-HxCDF
12
SFRA-78
78
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.4
U
1,9-HxCDF
13
SFRA-78
78
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
13
J
4,6-HxCDF
14
SFRA-78
78
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
194
1,4,6-HpCDF
15
SFRA-78
78
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
13
J
1,4,9-HpCDF
16
SFRA-78
78
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
353
OCDF
17
SFRA-79
79
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1500
TCDD
1
SFRA-79
79
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.09
U
PeCDD
2
SFRA-79
79
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
11.7
QU
1,4-HxCDD
3
SFRA-79
79
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
69.8
Q
1,6-HxCDD
4
SFRA-79
79
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
16.8
J
1,9-HxCDD
5
SFRA-79
79
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
449
1,4,6-HpCDD
6
SFRA-79
79
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
5060
OCDD
7
SFRA-79
79
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
9.31
J
TCDF
8
SFRA-79
79
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.2
U
1-PeCDF
9
SFRA-79
79
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.09
U
4-PeCDF
10
SFRA-79
79
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5.28
U
1,4-HxCDF
11
SFRA-79
79
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
4.93
U
1,6-HxCDF
12
SFRA-79
79
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
5.17
U
1,9-HxCDF
13
SFRA-79
79
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.84
U
4,6-HxCDF
14
SFRA-79
79
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
105
1,4,6-HpCDF
15
SFRA-79
79
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
7.54
J
1,4,9-HpCDF
16
SFRA-79
79
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
145
OCDF
17
SFRA-80
80
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
745
TCDD
1
SFRA-80
80
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.45
U
PeCDD
2
SFRA-80
80
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
7.73
U
1,4-HxCDD
3
SFRA-80
80
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
28.4
J
1,6-HxCDD
4
SFRA-80
80
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
8.23
U
1,9-HxCDD
5
SFRA-80
80
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
391
1,4,6-HpCDD
6
SFRA-80
80
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8240
OCDD
7
SFRA-80
80
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
4.21
J
TCDF
8
SFRA-80
80
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.69
U
1-PeCDF
9
SFRA-80
80
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.55
U
4-PeCDF
10
SFRA-80
80
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
4.31
U
1,4-HxCDF
11
SFRA-80
80
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
3.81
U
1,6-HxCDF
12
SFRA-80
80
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
6.38
U
1,9-HxCDF
13
SFRA-80
80
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.55
U
4,6-HxCDF
14
SFRA-80
80
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
97.9
1,4,6-HpCDF
15
SFRA-80
80
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
7.26
U
1,4,9-HpCDF
16
SFRA-80
80
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
189
OCDF
17
SFRA-81
81
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
240
TCDD
1
SFRA-81
81
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.76
U
PeCDD
2
SFRA-81
81
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
4.12
QU
1,4-HxCDD
3
SFRA-81
81
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
13.2
JQ
1,6-HxCDD
4
SFRA-81
81
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
4.37
U
1,9-HxCDD
5
SFRA-81
81
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
145
1,4,6-HpCDD
6
SFRA-81
81
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7740
OCDD
7
-------
SFRA-81
81
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
5.17
J
TCDF
8
SFRA-81
81
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.8
J
1-PeCDF
9
SFRA-81
81
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.09
U
4-PeCDF
10
SFRA-81
81
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
4.64
J
1,4-HxCDF
11
SFRA-81
81
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.93
U
1,6-HxCDF
12
SFRA-81
81
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
3.03
U
1,9-HxCDF
13
SFRA-81
81
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.02
U
4,6-HxCDF
14
SFRA-81
81
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
33.9
J
1,4,6-HpCDF
15
SFRA-81
81
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
3
U
1,4,9-HpCDF
16
SFRA-81
81
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
55.1
J
OCDF
17
SFRA-82
82
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
677
TCDD
1
SFRA-82
82
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
5.12
J
PeCDD
2
SFRA-82
82
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
5.43
U
1,4-HxCDD
3
SFRA-82
82
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
38.4
JQ
1,6-HxCDD
4
SFRA-82
82
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
15
J
1,9-HxCDD
5
SFRA-82
82
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
377
1,4,6-HpCDD
6
SFRA-82
82
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
15100
OCDD
7
SFRA-82
82
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
9.19
J
TCDF
8
SFRA-82
82
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
11.2
J
1-PeCDF
9
SFRA-82
82
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.95
U
4-PeCDF
10
SFRA-82
82
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
15.3
J
1,4-HxCDF
11
SFRA-82
82
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
8.06
J
1,6-HxCDF
12
SFRA-82
82
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
6.97
J
1,9-HxCDF
13
SFRA-82
82
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
6.92
J
4,6-HxCDF
14
SFRA-82
82
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
86.6
1,4,6-HpCDF
15
SFRA-82
82
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
12.3
J
1,4,9-HpCDF
16
SFRA-82
82
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
200
OCDF
17
SFRA-83
83
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
887
TCDD
1
SFRA-83
83
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.67
J
PeCDD
2
SFRA-83
83
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
4.08
J
1,4-HxCDD
3
SFRA-83
83
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
57.7
Q
1,6-HxCDD
4
SFRA-83
83
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
24.1
J
1,9-HxCDD
5
SFRA-83
83
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
502
1,4,6-HpCDD
6
SFRA-83
83
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11900
OCDD
7
SFRA-83
83
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.11
J
TCDF
8
SFRA-83
83
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
4.01
J
1-PeCDF
9
SFRA-83
83
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.07
J
4-PeCDF
10
SFRA-83
83
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
6.69
J
1,4-HxCDF
11
SFRA-83
83
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.38
J
1,6-HxCDF
12
SFRA-83
83
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.74
J
1,9-HxCDF
13
SFRA-83
83
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
7.15
J
4,6-HxCDF
14
SFRA-83
83
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
123
1,4,6-HpCDF
15
SFRA-83
83
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
10.4
J
1,4,9-HpCDF
16
SFRA-83
83
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
220
OCDF
17
SFRA-84
84
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
421
TCDD
1
SFRA-84
84
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.81
J
PeCDD
2
SFRA-84
84
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
6.11
U
1,4-HxCDD
3
SFRA-84
84
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
24.4
J
1,6-HxCDD
4
SFRA-84
84
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
11.6
J
1,9-HxCDD
5
SFRA-84
84
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
400
1,4,6-HpCDD
6
SFRA-84
84
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
12400
OCDD
7
SFRA-84
84
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
16.1
TCDF
8
SFRA-84
84
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
17.9
J
1-PeCDF
9
SFRA-84
84
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.7
J
4-PeCDF
10
SFRA-84
84
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
24.7
J
1,4-HxCDF
11
-------
SFRA-84
84
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.88
U
1,6-HxCDF
12
SFRA-84
84
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
8.98
U
1,9-HxCDF
13
SFRA-84
84
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
6.87
J
4,6-HxCDF
14
SFRA-84
84
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
86.3
1,4,6-HpCDF
15
SFRA-84
84
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
16
J
1,4,9-HpCDF
16
SFRA-84
84
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
183
OCDF
17
SFRA-85
85
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
1250
TCDD
1
SFRA-85
85
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
3.94
U
PeCDD
2
SFRA-85
85
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
6.56
U
1,4-HxCDD
3
SFRA-85
85
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
56.2
JQ
1,6-HxCDD
4
SFRA-85
85
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
21.6
J
1,9-HxCDD
5
SFRA-85
85
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
465
1,4,6-HpCDD
6
SFRA-85
85
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11500
OCDD
7
SFRA-85
85
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
12.4
TCDF
8
SFRA-85
85
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
5.95
J
1-PeCDF
9
SFRA-85
85
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.32
U
4-PeCDF
10
SFRA-85
85
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
9.56
J
1,4-HxCDF
11
SFRA-85
85
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
5.97
U
1,6-HxCDF
12
SFRA-85
85
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.66
J
1,9-HxCDF
13
SFRA-85
85
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
6.61
J
4,6-HxCDF
14
SFRA-85
85
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
104
1,4,6-HpCDF
15
SFRA-85
85
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
8.97
J
1,4,9-HpCDF
16
SFRA-85
85
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
194
OCDF
17
SFRA-86
86
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
745
TCDD
1
SFRA-86
86
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.57
U
PeCDD
2
SFRA-86
86
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.11
J
1,4-HxCDD
3
SFRA-86
86
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
9.82
J
1,6-HxCDD
4
SFRA-86
86
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
6.1
J
1,9-HxCDD
5
SFRA-86
86
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
219
1,4,6-HpCDD
6
SFRA-86
86
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
8390
OCDD
7
SFRA-86
86
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
4.56
U
TCDF
8
SFRA-86
86
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.97
U
1-PeCDF
9
SFRA-86
86
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.45
U
4-PeCDF
10
SFRA-86
86
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
2.43
U
1,4-HxCDF
11
SFRA-86
86
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.31
U
1,6-HxCDF
12
SFRA-86
86
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.9
U
1,9-HxCDF
13
SFRA-86
86
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.49
J
4,6-HxCDF
14
SFRA-86
86
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
35.3
J
1,4,6-HpCDF
15
SFRA-86
86
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.36
J
1,4,9-HpCDF
16
SFRA-86
86
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
112
J
OCDF
17
SFRA-87
87
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
226
TCDD
1
SFRA-87
87
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.45
U
PeCDD
2
SFRA-87
87
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
1.99
U
1,4-HxCDD
3
SFRA-87
87
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
6.12
J
1,6-HxCDD
4
SFRA-87
87
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
2.09
U
1,9-HxCDD
5
SFRA-87
87
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
112
1,4,6-HpCDD
6
SFRA-87
87
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
5020
OCDD
7
SFRA-87
87
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
3.58
J
TCDF
8
SFRA-87
87
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
0.964
J
1-PeCDF
9
SFRA-87
87
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.859
J
4-PeCDF
10
SFRA-87
87
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.19
U
1,4-HxCDF
11
SFRA-87
87
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.11
U
1,6-HxCDF
12
SFRA-87
87
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.65
U
1,9-HxCDF
13
SFRA-87
87
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.15
U
4,6-HxCDF
14
SFRA-87
87
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
16.4
J
1,4,6-HpCDF
15
-------
SFRA-87
87
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.2
U
1,4,9-HpCDF
16
SFRA-87
87
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
38.6
J
OCDF
17
SFRA-88
88
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
139
TCDD
1
SFRA-88
88
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.47
U
PeCDD
2
SFRA-88
88
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
4.38
U
1,4-HxCDD
3
SFRA-88
88
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
5.39
J
1,6-HxCDD
4
SFRA-88
88
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
4.5
U
1,9-HxCDD
5
SFRA-88
88
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
161
1,4,6-HpCDD
6
SFRA-88
88
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7160
OCDD
7
SFRA-88
88
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.26
U
TCDF
8
SFRA-88
88
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.76
J
1-PeCDF
9
SFRA-88
88
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
0.933
U
4-PeCDF
10
SFRA-88
88
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.98
J
1,4-HxCDF
11
SFRA-88
88
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.04
J
1,6-HxCDF
12
SFRA-88
88
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.1
U
1,9-HxCDF
13
SFRA-88
88
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.51
U
4,6-HxCDF
14
SFRA-88
88
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
21
J
1,4,6-HpCDF
15
SFRA-88
88
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.5
U
1,4,9-HpCDF
16
SFRA-88
88
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
76.8
J
OCDF
17
SFRA-89
89
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
595
TCDD
1
SFRA-89
89
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.82
U
PeCDD
2
SFRA-89
89
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
8.42
QU
1,4-HxCDD
3
SFRA-89
89
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
69.9
Q
1,6-HxCDD
4
SFRA-89
89
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
12.2
QU
1,9-HxCDD
5
SFRA-89
89
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
358
1,4,6-HpCDD
6
SFRA-89
89
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
14400
OCDD
7
SFRA-89
89
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
9.13
J
TCDF
8
SFRA-89
89
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.9
J
1-PeCDF
9
SFRA-89
89
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.36
J
4-PeCDF
10
SFRA-89
89
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5.94
J
1,4-HxCDF
11
SFRA-89
89
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.52
J
1,6-HxCDF
12
SFRA-89
89
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.36
U
1,9-HxCDF
13
SFRA-89
89
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
4.8
J
4,6-HxCDF
14
SFRA-89
89
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
78.8
1,4,6-HpCDF
15
SFRA-89
89
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
4.86
U
1,4,9-HpCDF
16
SFRA-89
89
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
63.4
J
OCDF
17
SFRA-90
90
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
543
TCDD
1
SFRA-90
90
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.1
U
PeCDD
2
SFRA-90
90
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
6.04
U
1,4-HxCDD
3
SFRA-90
90
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
107
1,6-HxCDD
4
SFRA-90
90
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
31.3
J
1,9-HxCDD
5
SFRA-90
90
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
2210
1,4,6-HpCDD
6
SFRA-90
90
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
27800
OCDD
7
SFRA-90
90
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
8.24
J
TCDF
8
SFRA-90
90
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.01
J
1-PeCDF
9
SFRA-90
90
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
7.59
J
4-PeCDF
10
SFRA-90
90
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
31.7
J
1,4-HxCDF
11
SFRA-90
90
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
11.9
J
1,6-HxCDF
12
SFRA-90
90
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
9.64
J
1,9-HxCDF
13
SFRA-90
90
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
19.8
J
4,6-HxCDF
14
SFRA-90
90
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
333
1,4,6-HpCDF
15
SFRA-90
90
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
29.4
J
1,4,9-HpCDF
16
SFRA-90
90
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
899
OCDF
17
SFRA-91
91
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
778
TCDD
1
SFRA-91
91
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.44
U
PeCDD
2
-------
SFRA-91
91
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
14.8
JQ
1,4-HxCDD
3
SFRA-91
91
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
72.4
Q
1,6-HxCDD
4
SFRA-91
91
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
21.6
J
1,9-HxCDD
5
SFRA-91
91
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1010
1,4,6-HpCDD
6
SFRA-91
91
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
14300
OCDD
7
SFRA-91
91
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
6.7
J
TCDF
8
SFRA-91
91
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.56
J
1-PeCDF
9
SFRA-91
91
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
4.02
J
4-PeCDF
10
SFRA-91
91
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
14.2
J
1,4-HxCDF
11
SFRA-91
91
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.04
J
1,6-HxCDF
12
SFRA-91
91
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.88
J
1,9-HxCDF
13
SFRA-91
91
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
9.37
J
4,6-HxCDF
14
SFRA-91
91
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
160
1,4,6-HpCDF
15
SFRA-91
91
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
12.9
J
1,4,9-HpCDF
16
SFRA-91
91
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
286
OCDF
17
SFRA-92
92
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2.92
J
TCDD
1
SFRA-92
92
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.01
U
PeCDD
2
SFRA-92
92
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
2.31
U
1,4-HxCDD
3
SFRA-92
92
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
2.25
U
1,6-HxCDD
4
SFRA-92
92
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
2.42
U
1,9-HxCDD
5
SFRA-92
92
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
64.9
1,4,6-HpCDD
6
SFRA-92
92
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
4650
OCDD
7
SFRA-92
92
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
1.46
J
TCDF
8
SFRA-92
92
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.06
U
1-PeCDF
9
SFRA-92
92
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.03
U
4-PeCDF
10
SFRA-92
92
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
1.13
U
1,4-HxCDF
11
SFRA-92
92
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.04
U
1,6-HxCDF
12
SFRA-92
92
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
1.64
U
1,9-HxCDF
13
SFRA-92
92
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
1.11
U
4,6-HxCDF
14
SFRA-92
92
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
4.77
J
1,4,6-HpCDF
15
SFRA-92
92
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
2.11
U
1,4,9-HpCDF
16
SFRA-92
92
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
8.67
U
OCDF
17
SFRA-93
93
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
895
TCDD
1
SFRA-93
93
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
2.49
U
PeCDD
2
SFRA-93
93
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
11.4
J
1,4-HxCDD
3
SFRA-93
93
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
32.9
J
1,6-HxCDD
4
SFRA-93
93
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
14.3
J
1,9-HxCDD
5
SFRA-93
93
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
757
1,4,6-HpCDD
6
SFRA-93
93
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
12300
OCDD
7
SFRA-93
93
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
9.96
J
TCDF
8
SFRA-93
93
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.14
U
1-PeCDF
9
SFRA-93
93
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.93
J
4-PeCDF
10
SFRA-93
93
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
13.1
J
1,4-HxCDF
11
SFRA-93
93
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.11
J
1,6-HxCDF
12
SFRA-93
93
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
3.81
J
1,9-HxCDF
13
SFRA-93
93
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
7.89
J
4,6-HxCDF
14
SFRA-93
93
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
127
1,4,6-HpCDF
15
SFRA-93
93
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
9.77
J
1,4,9-HpCDF
16
SFRA-93
93
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
301
OCDF
17
SFRA-94
94
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
2980
TCDD
1
SFRA-94
94
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
13.7
U
PeCDD
2
SFRA-94
94
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
5.53
J
1,4-HxCDD
3
SFRA-94
94
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
19.8
J
1,6-HxCDD
4
SFRA-94
94
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
7.94
J
1,9-HxCDD
5
SFRA-94
94
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
355
1,4,6-HpCDD
6
-------
SFRA-94
94
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
11000
OCDD
7
SFRA-94
94
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
18.8
TCDF
8
SFRA-94
94
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
1.7
J
1-PeCDF
9
SFRA-94
94
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
2.26
J
4-PeCDF
10
SFRA-94
94
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
5.31
J
1,4-HxCDF
11
SFRA-94
94
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
2.58
J
1,6-HxCDF
12
SFRA-94
94
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.56
U
1,9-HxCDF
13
SFRA-94
94
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
3.34
J
4,6-HxCDF
14
SFRA-94
94
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
55.9
J
1,4,6-HpCDF
15
SFRA-94
94
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
4.94
J
1,4,9-HpCDF
16
SFRA-94
94
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
89
J
OCDF
17
SFRA-95
95
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
16300
TCDD
1
SFRA-95
95
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
8.47
U
PeCDD
2
SFRA-95
95
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
28
U
1,4-HxCDD
3
SFRA-95
95
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
110
J
1,6-HxCDD
4
SFRA-95
95
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
29.9
U
1,9-HxCDD
5
SFRA-95
95
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
1050
1,4,6-HpCDD
6
SFRA-95
95
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
13300
OCDD
7
SFRA-95
95
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
91.2
TCDF
8
SFRA-95
95
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
9.85
U
1-PeCDF
9
SFRA-95
95
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
9.64
U
4-PeCDF
10
SFRA-95
95
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
23.3
U
1,4-HxCDF
11
SFRA-95
95
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
13.9
U
1,6-HxCDF
12
SFRA-95
95
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
23.5
U
1,9-HxCDF
13
SFRA-95
95
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
23.5
U
4,6-HxCDF
14
SFRA-95
95
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
575
1,4,6-HpCDF
15
SFRA-95
95
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
33.2
U
1,4,9-HpCDF
16
SFRA-95
95
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
745
OCDF
17
SFRA-96
96
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
964
TCDD
1
SFRA-96
96
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.12
U
PeCDD
2
SFRA-96
96
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
11.1
QU
1,4-HxCDD
3
SFRA-96
96
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
34.7
JQ
1,6-HxCDD
4
SFRA-96
96
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
12.3
U
1,9-HxCDD
5
SFRA-96
96
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
376
1,4,6-HpCDD
6
SFRA-96
96
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
9070
OCDD
7
SFRA-96
96
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
8.31
J
TCDF
8
SFRA-96
96
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.79
J
1-PeCDF
9
SFRA-96
96
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
3.85
J
4-PeCDF
10
SFRA-96
96
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
7.52
J
1,4-HxCDF
11
SFRA-96
96
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.56
U
1,6-HxCDF
12
SFRA-96
96
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
10.9
U
1,9-HxCDF
13
SFRA-96
96
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
7.14
U
4,6-HxCDF
14
SFRA-96
96
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
74.7
1,4,6-HpCDF
15
SFRA-96
96
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
7.98
J
1,4,9-HpCDF
16
SFRA-96
96
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
220
OCDF
17
SFRA-97
97
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
145
TCDD
1
SFRA-97
97
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
1.86
U
PeCDD
2
SFRA-97
97
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
4.48
QU
1,4-HxCDD
3
SFRA-97
97
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
7.55
JQ
1,6-HxCDD
4
SFRA-97
97
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
5.19
U
1,9-HxCDD
5
SFRA-97
97
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
116
1,4,6-HpCDD
6
SFRA-97
97
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
7400
OCDD
7
SFRA-97
97
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
2.74
J
TCDF
8
SFRA-97
97
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
2.81
J
1-PeCDF
9
SFRA-97
97
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
1.11
U
4-PeCDF
10
-------
SFRA-97
97
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
4.31
J
1,4-HxCDF
11
SFRA-97
97
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
1.74
J
1,6-HxCDF
12
SFRA-97
97
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
2.62
J
1,9-HxCDF
13
SFRA-97
97
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
2.33
U
4,6-HxCDF
14
SFRA-97
97
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
29.9
J
1,4,6-HpCDF
15
SFRA-97
97
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
4.84
J
1,4,9-HpCDF
16
SFRA-97
97
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
70.4
J
OCDF
17
SFRA-98
98
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3190
TCDD
1
SFRA-98
98
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
4.21
J
PeCDD
2
SFRA-98
98
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
3.38
U
1,4-HxCDD
3
SFRA-98
98
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
43.9
J
1,6-HxCDD
4
SFRA-98
98
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
15.7
J
1,9-HxCDD
5
SFRA-98
98
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
801
1,4,6-HpCDD
6
SFRA-98
98
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
20400
OCDD
7
SFRA-98
98
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
19
TCDF
8
SFRA-98
98
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
3.3
J
1-PeCDF
9
SFRA-98
98
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
5.53
J
4-PeCDF
10
SFRA-98
98
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
11.3
J
1,4-HxCDF
11
SFRA-98
98
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
7.36
J
1,6-HxCDF
12
SFRA-98
98
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
4.94
J
1,9-HxCDF
13
SFRA-98
98
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
10.1
J
4,6-HxCDF
14
SFRA-98
98
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
163
1,4,6-HpCDF
15
SFRA-98
98
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
15.9
J
1,4,9-HpCDF
16
SFRA-98
98
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
377
OCDF
17
SFRA-99
99
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
3940
TCDD
1
SFRA-99
99
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
7.83
U
PeCDD
2
SFRA-99
99
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
17.3
U
1,4-HxCDD
3
SFRA-99
99
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
44.8
J
1,6-HxCDD
4
SFRA-99
99
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
21.1
J
1,9-HxCDD
5
SFRA-99
99
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
539
1,4,6-HpCDD
6
SFRA-99
99
1,2,3,4,6,7,8,9-Octachlorodibenzo-p-dioxin
3268-87-9
10600
OCDD
7
SFRA-99
99
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
28
J
TCDF
8
SFRA-99
99
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
6.6
U
1-PeCDF
9
SFRA-99
99
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
6.65
U
4-PeCDF
10
SFRA-99
99
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
11.3
J
1,4-HxCDF
11
SFRA-99
99
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
6.64
U
1,6-HxCDF
12
SFRA-99
99
2,3,4,6,7,8-Hexachlorodibenzofuran
72918-21-9
10.4
U
1,9-HxCDF
13
SFRA-99
99
1,2,3,7,8,9-Hexachlorodibenzofuran
60851-34-5
8.29
U
4,6-HxCDF
14
SFRA-99
99
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
150
J
1,4,6-HpCDF
15
SFRA-99
99
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
12.4
J
1,4,9-HpCDF
16
SFRA-99
99
1,2,3,4,6,7,8,9-Octachlorodibenzofuran
39001-02-0
212
J
OCDF
17
-------
EPA Advanced KM TEQ Calculator
congener TEC
# Detects
# Nondetects
Quantiles
KMStats v 1.4 Practical Stats
3940
1
0
0.941
Input data to the blue cells, then sort from highest to lowest
3940
7.83
0
1
0.000
concentration. Concentrations and detection limits in Col A.
7.83
5.39
1
0
0.878
Number of detects at each concentration in Col B.
5.39
4.48
1
0
0.816
Number of nondetects at each DL in Col C.
4.48
3.18
1
0
0.753
3.18
2.8
1
0
0.690
2.8
2.11
1
0
0.627
2.11
1.995
0
1
0.000
1.995
1.73
0
1
0.000
1.73
1.5
1
0
0.549
1.5
1.13
1
0
0.471
1.13
1.04
0
1
0.000
1.04
0.829
0
1
0.000
KM intermediate "mean"
0.829
0.664
0
1
0.000
233.1420
0.664
0.198
0
1
0.000
0.198
0.124
1
0
0.235
KM TEQ
0.124
0.0636
1
0
0.000
3963.4144
0.0636
0.000
0
0.000
For details on the Kaplan-Meier method, see
0
0.000
Helsel, D.R. (2012), Statistics for Censored Environmental Data Using Minitab and R, 2nd ed. Wiley and Sons. 324
0
0.000
pp.
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
protect/unprotect sheet password = dioxin
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
0.000
0
-------
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0.000
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
Constant
Flip Cone rank
ranksum
at risk
partial prob
s
3940
3941
1
1
1
17
0.94117647
0.94117647
7.83
3933.17
1
0
0
0
0.94117647
5.39
3935.61
3
3
15
0.93333333
0.87843137
4.48
3936.52
4
4
14
0.92857143
0.81568627
3.18
#Rows with h
3937.82
5
5
13
0.92307692
0.75294118
2.8
0
3938.2
6
6
12
0.91666667
0.69019608
2.11
1
3938.89
7
7
11
0.90909091
0.62745098
1.995
1
3939.005
7
0
0
0
0.62745098
1.73
3939.27
8
0
0
0
0.62745098
1.5
3939.5
10
10
8
0.875
0.54901961
1.13
3939.87
11
11
7
0.85714286
0.47058824
1.04
3939.96
11
0
0
0
0.47058824
0.829
3940.171
12
0
0
0
0.47058824
0.664
3940.336
13
0
0
0
0.47058824
0.198
3940.802
14
0
0
0
0.47058824
0.124
3940.876
16
16
2
0.5
0.23529412
0.0636
3940.9364
17
17
1
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
Max50
Row50
For P25 Max25
Row25
For P75
0
0
14 0
0
18 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
8
0
0
0
0
9
0
0
0
0
0
0
0
0
0
0
0
0
0
0
12
13
4
0
0
13
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
18
-1
19
-2
18
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
17
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
0
0
0
0
0
9
8
0
0
5
4
0
0
0
0
1
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
ean
Rectangles
DiffC
LagP
Cum Area
Ar
Ar2
3940
1
1
1
3707.85798
3706.85798
50517.6326
0
3700.86588
3932.17
0.94117647
3706.85798
0
0
5.39
2.29647059
2.44
0.94117647
5.99209412
3.69562353
0.06503635
4.48
0.79937255
0.91
0.87843137
3.69562353
2.89625098
0.04608939
3.18
1.06039216
1.3
0.81568627
2.89625098
1.83585882
0.02160498
2.8
0.28611765
0.38
0.75294118
1.83585882
1.54974118
0.01819468
2.11
0.47623529
0.69
0.69019608
1.54974118
1.07350588
0.0104765
0
0.07215686
0.115
0.62745098
1.07350588
0
0
0
0.16627451
0.265
0.62745098
1.00134902
0
0
1.5
0.14431373
0.23
0.62745098
0.83507451
0.69076078
0.00852054
1.13
0.20313725
0.37
0.54901961
0.69076078
0.48762353
0.00566135
0
0.04235294
0.09
0.47058824
0.48762353
0
0
0
0.09929412
0.211
0.47058824
0.44527059
0
0
0
0.07764706
0.165
0.47058824
0.34597647
0
0
0
0.21929412
0.466
0.47058824
0.26832941
0
0
0.124
0.03482353
0.074
0.47058824
0.04903529
0.01421176
0.00010099
0.0636
0.01421176
0.0604
0.23529412
0.01421176
0
0
0
0
0.0636
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
0
0
0
0
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0
0
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0
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0
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0
0
0
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0
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0
0
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0
0
0
0
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0
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0
0
0
0
0
0
0
0
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0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
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0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
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0
0
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0
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0
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0
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0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
-------
Abbreviation 1
Abbreviation 2
IUPAC name
CAS#
Type
TCDD
2,3,7,8-TCDD
2,3,7,8-Tetrachlorodibenzo-p-dioxin
1746-01-6
Dioxin
PeCDD
1,2,3,7,8-PeCDD
1,2,3,7,8-Pentachlorodibenzo-p-dioxin
40321-76-4
Dioxin
1,4-HxCDD
1,2,3,4,7,8-HxCDD
1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin
39227-28-6
Dioxin
1,6-HxCDD
1,2,3,6,7,8-HxCDD
1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin
57653-85-7
Dioxin
1,9-HxCDD
1,2,3,7,8,9-HxCDD
1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin
19408-74-3
Dioxin
1,4,6-HpCDD
1,2,3,4,6,7,8-HpCDD
1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin
35822-46-9
Dioxin
OCDD
1,2,3,4,5,6,7,8-OCDD
Octachlorodibenzo-p-dioxin
3268-87-9
Dioxin
TCDF
2,3,7,8-TCDF
2,3,7,8-Tetrachlorodibenzofuran
51207-31-9
Furan
1-PeCDF
1,2,3,7,8-PeCDF
1,2,3,7,8-Pentachlorodibenzofuran
57117-41-6
Furan
4-PeCDF
2,3,4,7,8-PeCDF
2,3,4,7,8-Pentachlorodibenzofuran
57117-31-4
Furan
1,4-HxCDF
1,2,3,4,7,8-HxCDF
1,2,3,4,7,8-Hexachlorodibenzofuran
70648-26-9
Furan
1,6-HxCDF
1,2,3,6,7,8-HxCDF
1,2,3,6,7,8-Hexachlorodibenzofuran
57117-44-9
Furan
1,9-HxCDF
1,2,3,7,8,9-HxCDF
1,2,3,7,8,9-Hexachlorodibenzofuran
72918-21-9
Furan
4,6-HxCDF
2,3,4,6,7,8-HxCDF
2,3,4,6,7,8-Hexachlorodibenzofuran
60851-34-5
Furan
1,4,6-HpCDF
1,2,3,4,6,7,8-HpCDF
1,2,3,4,6,7,8-Heptachlorodibenzofuran
67562-39-4
Furan
1,4,9-HpCDF
1,2,3,4,7,8,9-HpCDF
1,2,3,4,7,8,9-Heptachlorodibenzofuran
55673-89-7
Furan
OCDF
1,2,3,4,5,6,7,8-OCDF
Octachlorodibenzofuran
39001-02-0
Furan
PCB 77
3,3',4,4'-TCB
3,3',4,4'-Tetrachlorobiphenyl
32598-13-3
Dioxin-like PCB
PCB81
3,4,4',5-TCB
3,4,4',5-Tetrachlorobiphenyl
70362-50-4
Dioxin-like PCB
PCB 105
2,3,3',4,4'-PeCB
2,3,3',4,4'-Pentachlorobiphenyl
32598-14-4
Dioxin-like PCB
PCB 114
2,3,4,4',5-PeCB
2,3,4,4',5-Pentachlorobiphenyl
74472-37-0
Dioxin-like PCB
PCB 118
2,3',4,4',5-PeCB
2,3',4,4',5-Pentachlorobiphenyl
31508-00-6
Dioxin-like PCB
PCB 123
2,3',4,4',5'-PeCB
2,3',4,4',5'-Pentachlorobiphenyl
65510-44-3
Dioxin-like PCB
PCB 126
3,3',4,4',5-PeCB
3,3',4,4',5-Pentachlorobiphenyl
57465-28-8
Dioxin-like PCB
PCB 156
2,3,3',4,4',5-HxCB
2,3,3',4,4',5-Hexachlorobiphenyl
38380-08-4
Dioxin-like PCB
PCB 157
2,3,3',4,4',5'-HxCB
2,3,3',4,4',5'-Hexachlorobiphenyl
69782-90-7
Dioxin-like PCB
PCB 167
2,3',4,4',5,5'-HxCB
2,3',4,4',5,5'-Hexachlorobiphenyl
52663-72-6
Dioxin-like PCB
PCB 169
3,3',4,4',5,5'-HxCB
3,3',4,4',5,5'-Hexachlorobiphenyl
32774-16-6
Dioxin-like PCB
PCB 189
2,3,3',4,4',5,5'-HpCB
2,3,3',4,4',5,5'-Heptachlorobiphenyl
39635-31-9
Dioxin-like PCB
-------
lAcronym
A
CAS
CLP
CSM
CV
DL
DU
E
EDL
EMPC
EPA
HpCDD
HpCDF
HxCDD
HxCDF
ICS
ISM
ITRC
IUPAC
J
KM
ND
OCDD
OCDF
PCB
PeCDD
PeCDF
QC
R
RSD
SD
SOW
TCDD
TCDF
TEC
TEF
TEQ
U
UCL
WHO
Data qualifier used to indicate an estimated result.
Chemical abstracts service
Contract Laboratory Program
Conceptual site model
Coefficient of variation
Detection limit
Decision unit
Data qualifier used to indicate an estimated result. This qualifier indicates that the concentration
exceeded the instrument calibration range, but did not saturate the detector.
Estimated detection limit
Estimated maximum possible concentration
U.S. Environmental Protection Agency
Heptachlorodibenzo(p)dioxin
Heptachlorodibenzofuran
Hexachlorodibenzo(p)dioxin
Hexachlorodibenzofuran
Incremental composite sample
Incremental sampling methodology
Interstate Technology and Regulatory Council
International Union of Pure and Applied Chemistry
Data qualifier used to indicate an estimated result. This qualifier indicates either: (1) a
concentration between the detection limit and quantitation limit or (2) a concentration qualified as
estimated because of some other quality control failure.
Kaplan-Meier
Nondetect
Octachlorodibenzo(p)dioxin
Octachlorodibenzofuran
Polychlorinated biphenyl
Pentachlorodibenzo(p)dioxin
Pentachlorodibenzofuran
Quality control
Data qualifier used to indicate a rejected result.
Relative standard deviation
Standard deviation
Scope of work
Tetrachlorodibenzo(p)dioxin
Tetrachlorodibenzofuran
Toxicity equivalence concentration
Toxicity equivalence factor
Toxicity equivalence
Data qualifier used to indicate a nondetected result.
Upper confidence limit
World Health Organization
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 7, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Upwind (Background) Particulate Data EA3 UW April 7, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
24.7
9.5
62
1.1653
14:36:23
7-Apr-14
2
22.7
10
71
1.1529
14:51:23
7-Apr-14
3
23.1
10.2
73
1.2323
15:06:23
7-Apr-14
4
24.8
10.3
75
1.3985
15:21:23
7-Apr-14
5
53.2
10.5
77
1.0917
15:36:23
7-Apr-14
6
23.1
10.8
77
1.2122
15:51:23
7-Apr-14
7
18.9
11.1
76
1.1309
16:06:23
7-Apr-14
8
17.5
11.3
74
1.0236
16:21:23
7-Apr-14
9
19.4
11.5
75
1.0623
16:36:23
7-Apr-14
10
20.8
11.6
75
1.125
16:51:23
7-Apr-14
Ellisville
(RV007) Downwind Particulate Data EA3 DW April 7, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
2.1
11
59
0.7554
14:43
11
7-Apr-14
2
15.9
11.2
67
4.1239
14:58
11
7-Apr-14
3
20.5
11.3
70
2.9514
15:13
11
7-Apr-14
4
22.5
11.5
72
2.0618
15:28
11
7-Apr-14
5
21.1
11.7
73
1.6725
15:43
11
7-Apr-14
6
18.2
12.1
73
1.5644
15:58
11
7-Apr-14
7
18.6
12.3
72
1.7096
16:13
11
7-Apr-14
8
17.5
12.5
71
1.2119
16:28
11
7-Apr-14
9
19.7
12.6
72
1.235
16:43
11
7-Apr-14
-------
PID (VOC) results Ellisville (RV007)
April 7, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive l imit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind (Background) PID Data EA3 UW April 7, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 4/7/2014 14:35 0.2 0 0 0 20.9
2 4/7/2014 14:50 0.3 0 0 0 20.9
3 4/7/2014 15:05 0.1 0 0 0 20.9
Ellisville (RV007) Down wind PID Data EA3 DW April 7, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 4/7/2014 14:30 0.2 0 0.1 0 20.9
2 4/7/2014 14:45 0.2 0 0.1 0 20.9
3 4/7/2014 15:00 0.3 0 0.1 0 20.9
4 4/7/2014 15:15 0.3 0 0.1 0 20.9
5 4/7/2014 15:30 0.3 0 0.1 0 20.9
6 4/7/2014 15:45 0.4 0 0.1 0 20.9
7 4/7/2014 16:00 0.4 0 0.1 0 20.9
8 4/7/2014 16:15 0.4 0 0.1 0 20.9
9 4/7/2014 16:30 0.5 0 0.1 0 20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 8, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 8, 2014
Ellisville (RV007) Down wind PM-10 Data EA3 April 8, 2014
record (MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
18.6
18.2
41
0.4307
8:19:00
8-Ap
2
18.5
16.5
46
0.4562
8:34:00
8-Ap
3
20.4
15.6
49
0.4503
8:49:00
8-Ap
4
20.6
15.2
51
0.5044
9:04:00
8-Ap
5
21.3
15.3
52
0.5102
9:19:00
8-Ap
6
22.2
15.2
52
0.5118
9:34:00
8-Ap
7
22.4
15.1
52
0.5049
9:49:00
8-Ap
8
19.8
15.1
52
0.5226
10:04:00
8-Ap
9
15.5
15.4
51
0.5149
10:19:00
8-Ap
10
15.1
15.6
49
0.5218
10:34:00
8-Ap
11
14.6
15.8
49
0.5043
10:49:00
8-Ap
12
10.9
16
47
0.4782
11:04:00
8-Ap
13
8.4
16
45
0.5135
11:19:00
8-Ap
14
6
16.2
44
0.419
11:34:00
8-Ap
15
5.5
16.6
42
0.4008
11:49:00
8-Ap
16
5.4
16.7
41
0.3763
12:04:00
8-Ap
17
5.3
17.1
41
0.3919
12:19:00
8-Ap
18
4.6
17.5
39
0.3599
12:34:00
8-Ap
19
4.9
17.7
38
0.3613
12:49:00
8-Ap
20
5.1
18.1
37
0.3637
13:04:00
8-Ap
21
6.8
18.6
35
0.4076
13:19:00
8-Ap
22
6.5
19.5
33
0.4184
13:34:00
8-Ap
23
5.2
20.7
31
0.3703
13:49:00
8-Ap
24
3.7
21.3
30
0.3788
14:04:00
8-Ap
25
3.7
21.1
29
0.4423
14:19:00
8-Ap
26
5.5
21
29
0.4418
14:34:00
8-Ap
27
4.3
21.1
28
0.468
14:49:00
8-Ap
28
5.5
22.4
27
0.528
15:04:00
8-Ap
29
4.7
23
25
0.5262
15:19:00
8-Ap
30
5.3
22.3
27
0.5177
15:34:00
8-Ap
31
3.5
22.2
28
0.458
15:49:00
8-Ap
32
4
21.3
28
0.4684
16:04:00
8-Ap
33
4.8
20.8
29
0.4285
16:19:00
8-Ap
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
2
-------
Particulate Air Monitoring Date Ellisville RV007
April 8, 2014
Ellisville (RV007) Up wind PM-10 Data April8, 2014
(MASS )ug Temp
RHumidit
Diameter time
date
1
17.1
14
44
0.4993
8:25:34
8-Ap
2
15.9
14.1
53
0.5358
8:40:34
8-Ap
3
15.3
14.5
54
0.5249
8:55:34
8-Ap
4
14.2
15.4
53
0.5546
9:10:34
8-Ap
5
14.2
16.7
50
0.5392
9:25:34
8-Ap
6
15.3
18.5
46
0.5235
9:40:34
8-Ap
7
13.7
19.7
43
0.5634
9:55:34
8-Ap
8
10.4
21.1
39
0.528
10:10:34
8-Ap
9
8.8
21.7
36
0.5465
10:25:34
8-Ap
10
10.1
22
35
0.55
10:40:34
8-Ap
11
8.8
21.7
34
0.5565
10:55:34
8-Ap
12
5.7
21.4
33
0.4784
11:10:34
8-Ap
13
4.4
21.1
33
0.4568
11:25:34
8-Ap
14
4
22.5
32
0.4633
11:40:34
8-Ap
15
4.3
23.6
29
0.5321
11:55:34
8-Ap
16
3.4
24.5
27
0.4281
12:10:34
8-Ap
17
3.4
23.7
27
0.4124
12:25:34
8-Ap
18
3.5
22.7
27
0.4267
12:40:34
8-Ap
19
3.7
22.4
28
0.4181
12:55:34
8-Ap
20
4.1
21.6
28
0.4091
13:10:34
8-Ap
21
4.5
21.2
28
0.4718
13:25:34
8-Ap
22
4.3
21.1
28
0.4569
13:40:34
8-Ap
23
3.3
21.2
28
0.4539
13:55:34
8-Ap
24
3
21.7
27
0.4522
14:10:34
8-Ap
25
2.9
21.9
26
0.4689
14:25:34
8-Ap
26
2.8
22.6
25
0.5172
14:40:34
8-Ap
27
2.5
24
24
0.5031
14:55:34
8-Ap
28
3
25.4
22
0.7106
15:10:34
8-Ap
29
2.5
25.5
22
0.5146
15:25:34
8-Ap
30
2.3
25.4
23
0.4222
15:40:34
8-Ap
31
1.9
25.5
21
0.376
15:55:34
8-Ap
32
3.3
24.1
22
0.5336
16:10:34
8-Ap
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
-------
PID (VOC) results Ellisville (RV007)
April 8, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
The Upwind PID was not ran on April 8, 2014.
1
-------
PID (VOC) results Ellisville RV007
April 8, 2014
Ellisville (RV007) Downwind PID Data EA3 UW April 8, 2014
Line#
Date Time
CO VOC H2S
(ppm) Alarm (ppm) Alarm (ppm) Alarm
LEL
(°L\
Alarm
OXY
(°L\
Alarm
1
4/8/2014 8:02
0.3
0
0.8
0
20.9
2
4/8/2014 8:17
0
0
0.3
0
20.9
3
4/8/2014 8:32
0
0
0
0
20.9
4
4/8/2014 8:47
0
0
0
0
20.9
5
4/8/2014 9:02
0
0
0
0
20.9
6
4/8/2014 9:17
0
0
0
0
20.9
7
4/8/2014 9:32
0
0
0
0
20.9
8
4/8/2014 9:47
0
0
0
0
20.9
9
4/8/2014
10:02
0
0
0
0
20.9
10
4/8/2014
10:17
0
0
0
0
20.9
11
4/8/2014
10:32
0
0
0
0
20.9
12
4/8/2014
10:47
0
0
0
0
20.9
13
4/8/2014
11:02
0
0
0
0
20.9
14
4/8/2014
11:17
0
0
0
0
20.9
15
4/8/2014
11:32
0
0
0
0
20.9
16
4/8/2014
11:47
0
0
0
0
20.9
17
4/8/2014
12:02
0
0
0
0
20.9
18
4/8/2014
12:17
0
0
0
0
20.9
19
4/8/2014
12:32
0
0
0
0
20.9
20
4/8/2014
12:47
0
0
0
0
20.9
21
4/8/2014
13:02
0
0
0
0
20.9
22
4/8/2014
13:17
0
0
0
0
20.9
23
4/8/2014
13:32
0
0
0
0
20.9
24
4/8/2014
13:47
0
0
0
0
20.9
25
4/8/2014
14:02
0
0
0
0
20.9
26
4/8/2014
14:17
0
0
0
0
20.9
27
4/8/2014
14:32
0
0
0
0
20.9
28
4/8/2014
14:47
0
0
0.1
0
20.9
29
4/8/2014
15:02
0
0
0.1
0
20.9
30
4/8/2014
15:17
0
0
0
0
20.9
31
4/8/2014
15:32
0
0
0
0
20.9
32
4/8/2014
15:47
0
0
0
0
20.9
33
4/8/2014
16:02
0
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 9, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 9, 2014
Ellisville (RV007) Up wind PM-10 Data April 9, 2014
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
8.6
12.6
60
0.6608
9:34
11
9-Apr-14
2
16.5
16
46
0.61
9:49
11
9-Apr-14
3
4.4
18.7
37
0.4886
10:04
11
9-Apr-14
4
3.5
20.8
30
0.5114
10:19
11
9-Apr-14
5
7.4
22.4
27
0.905
10:34
11
9-Apr-14
6
6.6
23.7
24
1.0837
10:49
11
9-Apr-14
7
5.3
24.5
22
0.9407
11:04
11
9-Apr-14
8
6.4
25.3
21
1.1098
11:19
11
9-Apr-14
9
2.6
26
20
0.3791
11:34
11
9-Apr-14
10
2.6
26.9
19
0.4175
11:49
11
9-Apr-14
11
2.9
27.6
18
0.559
12:04
11
9-Apr-14
12
2.6
27.4
17
0.5685
12:19
11
9-Apr-14
13
3.7
25.6
18
0.6366
12:34
11
9-Apr-14
14
4
24.6
19
0.5394
12:49
11
9-Apr-14
15
6.6
23.2
19
0.751
13:04
11
9-Apr-14
16
10.8
21.8
21
0.8783
13:19
11
9-Apr-14
17
7.5
20.8
22
0.6683
13:34
11
9-Apr-14
18
5.1
20.1
23
0.487
13:49
11
9-Apr-14
19
7.4
20.1
23
0.5153
14:04
11
9-Apr-14
20
6
21.2
22
0.5673
14:19
11
9-Apr-14
21
5
23.6
20
0.619
14:34
11
9-Apr-14
22
5
25.8
18
0.6766
14:49
11
9-Apr-14
23
4.9
27.6
16
0.7057
15:04
11
9-Apr-14
24
3.5
28.7
15
0.5752
15:19
11
9-Apr-14
25
3.9
29.4
14
0.9214
15:34
11
9-Apr-14
26
7.3
29.9
13
1.1621
15:49
11
9-Apr-14
27
1.8
30.2
13
0.4603
16:04
11
9-Apr-14
28
2.4
30.1
12
0.6182
16:19
11
9-Apr-14
29
5
29.5
13
0.9067
16:34
11
9-Apr-14
2
-------
Particulate Air Monitoring Date Ellisville RV007
April 9, 2014
Ellisville (RV007) Down wind PM-10 Data EA3 April 9, 2014
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
10.3
14.7
56
1.2361
9:33:24
9-Ap
2
13
14.6
49
1.1968
9:48:24
9-Ap
3
8.8
14.5
47
1.2113
10:03:24
9-Ap
4
8.1
14.6
44
1.1786
10:18:24
9-Ap
5
8.8
14.8
43
1.2191
10:33:24
9-Ap
6
9
15.1
42
1.2739
10:48:24
9-Ap
7
7.4
15.4
41
1.2667
11:03:24
9-Ap
8
7.6
15.9
39
1.2063
11:18:24
9-Ap
9
8.5
16.3
38
1.3292
11:33:24
9-Ap
10
7.6
16.8
37
0.9897
11:48:24
9-Ap
11
7.9
17.2
37
1.1734
12:03:24
9-Ap
12
7.4
17.7
35
1.1545
12:18:24
9-Ap
13
7.8
18.4
34
1.0275
12:33:24
9-Ap
14
8.2
19
32
1.1046
12:48:24
9-Ap
15
8.9
19.4
31
0.9713
13:03:24
9-Ap
16
8.8
19.9
30
1.0048
13:18:24
9-Ap
17
9.9
20.4
30
1.1282
13:33:24
9-Ap
18
8.4
21
28
0.8678
13:48:24
9-Ap
19
9.4
21.6
27
1.0103
14:03:24
9-Ap
20
9.2
22.4
26
1.0005
14:18:24
9-Ap
21
8.2
23.5
25
1.1228
14:33:24
9-Ap
22
9.9
24.5
24
1.7368
14:48:24
9-Ap
23
7.1
26.1
23
0.9764
15:03:24
9-Ap
24
7.4
27.5
21
1.2349
15:18:24
9-Ap
25
7.4
27.2
20
1.6856
15:33:24
9-Ap
26
11
27
20
0.9265
15:48:24
9-Ap
27
7.2
26.5
20
1.2097
16:03:24
9-Ap
28
5.9
25.8
20
1.3094
16:18:24
9-Ap
29
5.4
26
20
0.9084
16:33:24
9-Ap
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
-------
PID (VOC) results Ellisville (RV007)
April 9, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
1
-------
PID (VOC) results Ellisville RV007
April 9, 2014
Ellisville (RV007) Downwind PID Data EA3 UW April 9, 2014
CO VOC H2S
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm LEL (%) Alarm OXY (%) Alarm
1
4/9/2014 9:17
0.3
0
0
0
20.9
2
4/9/2014 9:32
0.1
0
0
0
20.9
3
4/9/2014 9:47
0
0
0
0
20.9
4
4/9/2014
10:02
0
0
0
0
20.9
5
4/9/2014
10:17
0.1
0
0
0
21.1
6
4/9/2014
10:32
0
0
0
0
21.2
7
4/9/2014
10:47
0
0
0
0
21.2
8
4/9/2014
11:02
0.1
0
0
0
21.2
9
4/9/2014
11:17
0.1
0
0
0
21.1
10
4/9/2014
11:32
0
0
0
0
21.1
11
4/9/2014
11:47
0
0
0
0
21.1
12
4/9/2014
12:02
0
0
0
0
21.1
13
4/9/2014
12:17
0
0
0
0
21.1
14
4/9/2014
12:32
0
0
0
0
21.1
15
4/9/2014
12:47
0
0
0
0
21.1
16
4/9/2014
13:02
0
0
0
0
21.1
17
4/9/2014
13:17
0
0
0
0
21.1
18
4/9/2014
13:32
0.1
0
0
0
21.1
19
4/9/2014
13:47
0.1
0
0
0
21.1
20
4/9/2014
14:02
0.1
0
0
0
20.9
21
4/9/2014
14:17
0.2
0
0
0
20.9
22
4/9/2014
14:32
0.2
0
0
0
20.9
23
4/9/2014
14:47
0.3
0
0
0
20.9
24
4/9/2014
15:02
0.3
0
0
0
20.9
25
4/9/2014
15:17
0.5
0
0
0
21
26
4/9/2014
15:32
0.4
0
0
0
21.3
27
4/9/2014
15:47
0.3
0
0
0
21.2
28
4/9/2014
16:02
0.2
0
0
0
21.2
29
4/9/2014
16:17
0.2
0
0
0
21.2
2
-------
PID (VOC) results Ellisville RV007
April 9, 2014
Ellisville (RV007) Upwind PID Data EA3 UW April 9, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
4/9/2014 9:19
0.3
0
0
0
20.9
2
4/9/2014 9:34
0.1
0
0
0
21.2
3
4/9/2014 9:49
0
0
0
0
21.2
4
4/9/2014 11:57
0
0
0
0
21.5
5
4/9/2014 12:12
0
0
0
0
21.5
6
4/9/2014 12:27
0
0
0
0
21.4
9
4/9/2014 15:11
0.1
0
0
0
21.8
10
4/9/2014 15:26
0.1
0
0
0
21.8
11
4/9/2014 15:41
0.1
0
0
0
21.8
Alarm
3
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 10, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 10, 2014
Ellisville (RV007) Up wind PM-10 Data April 10, 2014
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
8.5
32.8
24
0.5729
13:19:23
10-Apr-14
2
11.2
34.6
21
0.7713
13:34:23
10-Apr-14
3
12.2
35.8
19
0.6787
13:49:23
10-Apr-14
4
12.2
36
19
0.8234
14:04:23
10-Apr-14
5
11.7
36.7
19
0.8263
14:19:23
10-Apr-14
6
9.1
37.4
18
0.6058
14:34:23
10-Apr-14
7
9.5
37.4
18
0.7144
14:49:23
10-Apr-14
8
15.3
37.1
19
0.7995
15:04:23
10-Apr-14
9
7.7
37.9
18
0.6033
15:19:23
10-Apr-14
10
7.9
37.8
18
0.5898
15:34:23
10-Apr-14
11
8.3
36.3
20
0.5905
15:49:23
10-Apr-14
12
9.4
34.4
22
0.6631
16:04:23
10-Apr-14
13
9.7
32.7
24
0.6264
16:19:23
10-Apr-14
14
10.8
31.4
26
0.6101
16:34:23
10-Apr-14
15
12.8
30.1
27
0.5205
16:49:23
10-Apr-14
record
s (RV007) Down wind PM-10 Data EA3 April
10, 2014
(MASS )ug/m3
Temp
RHumidity Diameter
time
date
1
10.2
32.8
21
0.7296
13:43:45
10-Apr-14
2
6.8
32.9
19
0.8252
13:58:45
10-Apr-14
3
6.8
33.2
19
0.8334
14:13:45
10-Apr-14
4
6.8
33.7
19
0.779
14:28:45
10-Apr-14
5
13.6
33.9
19
1.2866
14:43:45
10-Apr-14
6
8.9
33.9
19
1.0126
14:58:45
10-Apr-14
7
8.2
34.5
19
0.9344
15:13:45
10-Apr-14
8
21.9
34.7
18
1.6743
15:28:45
10-Apr-14
9
9.6
33.8
19
1.0194
15:43:45
10-Apr-14
10
8.8
32.4
21
0.8479
15:58:45
10-Apr-14
11
9.6
30.8
23
0.9436
16:13:45
10-Apr-14
12
14
29.6
25
1.2783
16:28:45
10-Apr-14
13
12
29.1
26
0.6921
16:43:45
10-Apr-14
2
-------
PID (VOC) results Ellisville (RV007)
April 10, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
1
-------
PID (VOC) results Ellisville RV007
April 10, 2014
Ellisville (RV007) Upwind PID Data EA3 UW April 10, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
4/10/2014 13:30
0.8
0
5.8
0
20.9
2
4/10/2014 13:45
0.7
0
5.8
0
20.9
3
4/10/2014 14:00
0.8
0
5.5
0
20.9
4
4/10/2014 14:15
0.7
0
5.3
0
20.9
5
4/10/2014 14:30
0.7
0
5
0
20.9
6
4/10/2014 14:45
0.6
0
4.7
0
20.9
7
4/10/2014 15:00
0.6
0
4.9
0
20.9
8
4/10/2014 15:15
0.6
0
4.3
0
21.2
9
4/10/2014 15:30
0.3
0
3
0
21.2
10
4/10/2014 15:45
0.1
0
1.4
0
21.3
11
4/10/2014 16:00
0
0
0.4
0
21.2
12
4/10/2014 16:15
0
0
0.1
0
21.2
13
4/10/2014 16:30
0
0
0
0
21.1
Ellisville (RV007) Downwind PID Data EA3 DW April 10, 2014
CO
VOC
H2S LEL OXY
Line#
Date Time
(ppm)
Alarm (ppm) Alarm
(ppm) Alarm (%) Alarm (%) Alarm
1
4/10/2014
13:04
0.9
0
0.3
0
20.9
2
4/10/2014
13:19
1.8
0
0.3
0
20.9
3
4/10/2014
13:34
2.4
0
0.2
0
21
4
4/10/2014
13:49
2.5
0
0.2
0
21.2
5
4/10/2014
14:04
2.7
0
0.2
0
21.2
6
4/10/2014
14:19
3
0
0.2
0
21.3
7
4/10/2014
14:34
3.6
0
0.2
0
21.3
8
4/10/2014
14:49
3.1
0
0.2
0
21.3
9
4/10/2014
15:04
3.9
0
0.2
0
21.3
10
4/10/2014
15:19
4.5
0
0.1
0
21.3
11
4/10/2014
15:34
3.3
0
0
0
21.4
12
4/10/2014
15:49
2.2
0
0
0
21.3
13
4/10/2014
16:04
1.4
0
0
0
21.3
14
4/10/2014
16:19
0.8
0
0
0
21.3
15
4/10/2014
16:34
0.5
0
0
0
21.3
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 11, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 11, 2014
Ellisville (RV007) Upwind PM-10 Data April 11, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
10.1
16.7
30
3.7309
8:54:44
11-Ap
2
9.6
17.9
31
4.0576
9:09:44
11-Ap
3
9.1
19.8
29
3.9625
9:24:44
11-Ap
4
8.7
21.1
27
3.7234
9:39:44
11-Ap
5
8.6
22.4
25
3.6134
9:54:44
11-Ap
6
7.8
23.6
24
3.8985
10:09:44
11-Ap
7
7.8
25.1
22
3.3637
10:24:44
11-Ap
8
7.9
26
21
3.3936
10:39:44
11-Ap
9
8.6
27.3
20
3.59
10:54:44
11-Ap
10
9.7
27.8
19
2.9971
11:09:44
11-Ap
11
10.2
27.4
19
3.1759
11:24:44
11-Ap
12
8.6
27.2
19
3.5195
11:39:44
11-Ap
13
8.2
27.2
19
3.42
11:54:44
11-Ap
14
7.9
27.1
19
3.3366
12:09:44
11-Ap
15
7.9
27.4
19
3.3078
12:24:44
11-Ap
16
7.8
27.8
18
2.9827
12:39:44
11-Ap
17
8.3
28.2
18
3.196
12:54:44
11-Ap
18
14.1
27.8
18
3.509
13:09:44
11-Ap
19
7.4
27.3
18
2.8621
13:24:44
11-Ap
20
9
27.6
19
3.0799
13:39:44
11-Ap
21
8.9
29.2
18
3.0165
13:54:44
11-Ap
22
7.4
31.2
17
2.558
14:09:44
11-Ap
23
8
32.6
16
3.1941
14:24:44
11-Ap
24
7.6
33.5
15
3.4554
14:39:44
11-Ap
25
6.7
33.6
15
3.2116
14:54:44
11-Ap
26
7.1
34.4
15
3.5311
15:09:44
11-Ap
27
6.2
34.7
15
2.8525
15:24:44
11-Ap
28
6
34.6
14
2.7022
15:39:44
11-Ap
29
6.1
34.3
14
2.8571
15:54:44
11-Ap
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
-------
Particulate Air Monitoring Date Ellisville RV007
April 11, 2014
Ellisville (RV007) Down wind PM-10 Data EA3 April 11, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
8
15.6
25
1.2596
0:15:33
25-Jan-00
2
8.3
16.7
28
1.4923
0:30:33
25-Jan-00
3
5.2
17.5
28
0.9116
0:45:33
25-Jan-00
4
6.1
18.1
27
1.3173
1:00:33
25-Jan-00
5
9.1
18.5
25
1.7828
1:15:33
25-Jan-00
6
6.5
18.7
25
1.7181
1:30:33
25-Jan-00
7
7.5
19.4
24
1.9368
1:45:33
25-Jan-00
8
4.9
19.7
23
0.9064
2:00:33
25-Jan-00
9
5.8
20
23
1.168
2:15:33
25-Jan-00
10
6
20.3
22
1.1193
2:30:33
25-Jan-00
11
5.7
20.6
22
1.3109
2:45:33
25-Jan-00
12
4.9
20.9
22
1.2979
3:00:33
25-Jan-00
13
5
21.3
21
1.3148
3:15:33
25-Jan-00
14
4.5
21.5
21
1.2347
3:30:33
25-Jan-00
15
5
22
20
1.3056
3:45:33
25-Jan-00
16
5.2
22.5
20
1.4554
4:00:33
25-Jan-00
17
11.6
23
20
2.0122
4:15:33
25-Jan-00
18
12.2
23.2
19
1.79
4:30:33
25-Jan-00
3
-------
PID (VOC) results Ellisville (RV007)
April 11, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
1
-------
PID (VOC) results Ellisville RV007
April 11, 2014
Ellisville (RV007) Upwind PID Data EA3 UW April 11, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
4/11/2014 8:40
0.1
0
0
0
20.9
2
4/11/2014 8:55
0.1
0
0
0
20.9
3
4/11/2014 9:10
0.1
0
0
0
20.9
4
4/11/2014 9:25
0.2
0
0
0
20.9
5
4/11/2014 9:40
0.2
0
0
0
20.9
6
4/11/2014 9:55
0.2
0
0
0
20.9
7
4/11/2014 10:10
0.3
0
0
0
20.9
8
4/11/2014 10:25
0.3
0
0
0
20.9
9
4/11/2014 10:40
0.5
0
0
0
20.9
10
4/11/2014 10:55
0.5
0
0
0
20.9
11
4/11/2014 11:10
0.4
0
0
0
21.2
12
4/11/2014 11:25
0.2
0
0
0
21.2
13
4/11/2014 11:40
0.2
0
0
0
21.2
14
4/11/2014 11:55
0.2
0
0
0
21.2
15
4/11/2014 12:10
0.2
0
0
0
21.2
16
4/11/2014 12:25
0.2
0
0
0
21.2
17
4/11/2014 12:40
0.3
0
0
0
21.2
18
4/11/2014 12:55
0.3
0
0
0
21.3
19
4/11/2014 13:10
0.2
0
0
0
21.3
20
4/11/2014 13:25
0.1
0
0
0
21.2
21
4/11/2014 13:40
0.1
0
0
0
21.2
22
4/11/2014 13:55
0.3
0
0
0
21.2
23
4/11/2014 14:10
0.5
0
0
0
21.2
24
4/11/2014 14:25
1.2
0
0
0
21.3
25
4/11/2014 14:40
1.1
0
0
0
21.3
26
4/11/2014 14:55
1.6
0
0
0
21.3
27
4/11/2014 15:10
2.1
0
0
0
21.3
28
4/11/2014 15:25
2.4
0
0.1
0
21.4
29
4/11/2014 15:40
3.1
0
0.1
0
21.4
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 17, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 17, 2014
Ellisville (RV007) Up Wind PM-10 Data April 17, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
12.1
27.7
26
0.4689
14:36
10
17-Apr-14
2
11.1
28.3
24
0.4273
14:51
10
17-Apr-14
3
10.9
28.6
23
0.4457
15:06
10
17-Apr-14
4
10.1
29.3
22
0.4276
15:21
10
17-Apr-14
5
11
28.9
22
0.4806
15:36
10
17-Apr-14
6
9.7
29.5
22
0.4119
15:51
10
17-Apr-14
7
9.2
28.9
22
0.3994
16:06
10
17-Apr-14
8
9.6
28
23
0.4134
16:21
10
17-Apr-14
9
9.1
27.3
24
0.4236
16:36
10
17-Apr-14
Ellisville (RV007) Down Wind PM-10 Data April 17, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
10.6
26.4
25
0.5257
14:45:40
17-Apr-14
2
9.5
26.6
22
0.5181
15:00:40
17-Apr-14
3
9.1
27
21
0.4856
15:15:40
17-Apr-14
4
8.6
26.8
21
0.5
15:30:40
17-Apr-14
5
8.2
26.5
21
0.4762
15:45:40
17-Apr-14
6
9.4
26.2
22
0.534
16:00:40
17-Apr-14
7
8.3
25.7
23
0.4941
16:15:40
17-Apr-14
8
8.9
25.2
23
0.5107
16:30:40
17-Apr-14
2
-------
PID (VOC) results Ellisville (RV007)
April 17, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
1
-------
PID (VOC) results Ellisville RV007
April 17, 2014
Ellisville (RV007) Upwind PID Data EA3 UW April 17, 2014
Line#
Date Time
CO
(ppm) Alarm
VOC
(ppm) Alarm
H2S
(ppm) Alarm
LEL (%) Alarm
OXY (%)
1
4/17/2014
14:20
0
0
0.2
0
20.9
2
4/17/2014
14:35
0.1
0
0.1
0
20.9
3
4/17/2014
14:50
0.1
0
0.1
0
20.9
4
4/17/2014
15:05
0.2
0
0
0
20.9
5
4/17/2014
15:20
0.1
0
0
0
20.9
6
4/17/2014
15:35
0.1
0
0
0
20.9
7
4/17/2014
15:50
0.1
0
0
0
20.9
8
4/17/2014
16:05
0
0
0
0
20.9
9
4/17/2014
16:20
0
0
0
0
20.9
Ellisville (RV007) Downwind PID Data EA3 DW April 17, 2014
CO
VOC
H2S
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
LEL (%) Alarm
OXY (%)
1
4/17/2014 14:30
0.6
0
0
0
20.9
2
4/17/2014 14:45
0.5
0
0
0
20.9
3
4/17/2014 15:00
0.5
0
0
0
20.9
4
4/17/2014 15:15
0.4
0
0
0
20.9
5
4/17/2014 15:30
0.2
0
0
0
20.9
6
4/17/2014 15:45
0.1
0
0
0
20.9
7
4/17/2014 16:00
0
0
0
0
20.9
8
4/17/2014 16:15
0
0
0
0
20.9
9
4/17/2014 16:30
0
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 21, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 21, 2014
Ellisville (RV007) Up wind PM-10 Data April 21, 2014
record (MASS)ug/m3 Temp RHumidity Diameter time date
1
24.1
22.7
45
0.4549
11:44:07 21-Apr-14
2
22.9
23.6
53
0.4631
11:59:07 21-Apr-14
3
22.4
24.8
50
0.4615
12:14:07 21-Apr-14
4
22.6
25.6
48
0.4595
12:29:07 21-Apr-14
5
21.8
26.2
46
0.4681
12:44:07 21-Apr-14
6
20.4
26.9
44
0.448
12:59:07 21-Apr-14
7
19.9
27.6
42
0.4574
13:14:07 21-Apr-14
8
19
27.9
41
0.4415
13:29:07 21-Apr-14
9
17.2
28.3
39
0.4502
13:44:07 21-Apr-14
10
17.9
28.7
38
0.4585
13:59:07 21-Apr-14
11
15.6
29.2
37
0.4752
14:14:07 21-Apr-14
12
14.6
29.3
37
0.4339
14:29:07 21-Apr-14
13
14.7
29
37
0.4356
14:44:07 21-Apr-14
14
16.3
29.1
37
0.4831
14:59:07 21-Apr-14
15
13.7
29.1
36
0.442
15:14:07 21-Apr-14
16
14
28.6
37
0.4377
15:29:07 21-Apr-14
17
14.6
27.8
39
0.4478
15:44:07 21-Apr-14
18
15.3
26.9
41
0.4435
15:59:07 21-Apr-14
19
20.8
26
45
0.5388
16:14:07 21-Apr-14
20
18.5
25.3
48
0.4775
16:29:07 21-Apr-14
21
16.8
25
48
0.4457
16:44:07 21-Apr-14
22
15.3
25.2
47
0.438
16:59:07 21-Apr-14
Ellisville (RV007) Down Wind PM-10 Data April 21, 2014
rd
(MASS )ug/m3
Temp
RHumidity
Diameter
time date
1
24.5
22.2
48
0.5448
11:41:48 21-Apr-
2
23.8
22.2
55
0.547
11:56:48 21-Apr-
3
23.4
22.6
55
0.5374
12:11:48 21-Apr-
4
24.2
23
53
0.5659
12:26:48 21-Apr-
5
23.1
23.4
53
0.5544
12:41:48 21-Apr-
6
23.3
23.9
51
0.554
12:56:48 21-Apr-
7
20.7
24.4
49
0.5439
13:11:48 21-Apr-
8
17.8
24.9
47
0.4932
13:26:48 21-Apr-
9
18.4
25.3
45
0.582
13:41:48 21-Apr-
10
17.9
25.6
44
0.532
13:56:48 21-Apr-
11
16
25.9
43
0.5173
14:11:48 21-Apr-
12
14.5
26.1
42
0.51
14:26:48 21-Apr-
13
14.2
26.1
42
0.5149
14:41:48 21-Apr-
14
15.3
26.2
42
0.4743
14:56:48 21-Apr-
15
12.8
26.3
41
0.4548
15:12:25 21-Apr-
16
14.5
26.2
42
0.5916
15:27:25 21-Apr-
17
13.8
25.8
44
0.4926
15:42:25 21-Apr-
18
15.5
25.2
47
0.5466
15:57:25 21-Apr-
19
16.3
24.6
52
0.5163
16:12:25 21-Apr-
20
18.7
23.9
55
0.5693
16:27:25 21-Apr-
21
18.2
23.5
55
0.5596
16:42:25 21-Apr-
22
15.8
23.6
52
0.5258
16:57:25 21-Apr-
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
2
-------
PID (VOC) results Ellisville (RV007)
April 21, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
1
-------
PID (VOC) results Ellisville RV007
April 21, 2014
Ellisville (RV007) Upwind PID Data EA3 UW April 21, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
4/21/2014
11:28
0.4
0
0
0
20.9
2
4/21/2014
11:43
0.1
0
0
0
20.9
3
4/21/2014
11:58
0.2
0
0
0
20.9
4
4/21/2014
12:13
0.2
0
0
0
20.9
5
4/21/2014
12:28
0.1
0
0
0
20.9
6
4/21/2014
12:43
0
0
0
0
20.9
7
4/21/2014
12:58
0.1
0
0
0
20.9
8
4/21/2014
13:13
0.1
0
0
0
20.9
9
4/21/2014
13:28
0.1
0
0
0
20.9
10
4/21/2014
13:43
0.1
0
0
0
20.9
11
4/21/2014
13:58
0.1
0
0
0
20.9
12
4/21/2014
14:13
0.1
0
0
0
20.9
13
4/21/2014
14:28
0.1
0
0
0
20.9
14
4/21/2014
14:43
0.1
0
0
0
20.9
15
4/21/2014
14:58
0.1
0
0
0
20.9
16
4/21/2014
15:13
0.1
0
0
0
20.9
17
4/21/2014
15:28
0
0
0
0
20.9
18
4/21/2014
15:43
0
0
0
0
20.9
19
4/21/2014
15:58
0
0
0
0
20.9
20
4/21/2014
16:13
0
0
0
0
20.9
21
4/21/2014
16:28
0
0
0
0
20.9
22
4/21/2014
16:43
0
0
0
0
20.9
2
-------
PID (VOC) results Ellisville RV007
April 21, 2014
Ellisville (RV007) Downwind PID Data EA3 UW April 21, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
4/21/2014
11:31
2.1
0
0
0
20.9
2
4/21/2014
11:46
1.4
0
0
0
20.9
3
4/21/2014
12:01
1.2
0
0
0
20.9
4
4/21/2014
12:16
1
0
0
0
20.9
5
4/21/2014
12:31
0.8
0
0
0
20.9
6
4/21/2014
12:46
0.7
0
0
0
20.9
7
4/21/2014
13:01
0.6
0
0
0
20.9
8
4/21/2014
13:16
0.5
0
0
0
20.9
9
4/21/2014
13:31
0.5
0
0
0
20.9
10
4/21/2014
13:46
0.4
0
0
0
20.9
11
4/21/2014
14:01
0.3
0
0
0
20.9
12
4/21/2014
14:16
0.3
0
0
0
20.9
13
4/21/2014
14:31
0.1
0
0
0
20.9
14
4/21/2014
14:46
0.1
0
0
0
20.9
15
4/21/2014
15:01
0.1
0
0
0
20.9
16
4/21/2014
15:16
0.1
0
0
0
20.9
17
4/21/2014
15:31
0.1
0
0
0
20.9
18
4/21/2014
15:46
0.1
0
0
0
20.9
19
4/21/2014
16:01
0
0
0
0
20.9
20
4/21/2014
16:16
0.1
0
0
0
20.9
21
4/21/2014
16:31
0
0
0
0
20.9
3
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 23, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 23, 2014
Ellisville (RV007) Up wind PM-10 Data April 23, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
17.8
16.1
39
0.9489
9:54:05
23-Apr-14
2
17.5
15.9
42
0.8997
10:09:05
23-Apr-14
3
18
15.8
43
0.929
10:24:05
23-Apr-14
4
18.5
16
44
0.9505
10:39:05
23-Apr-14
5
19.1
16.1
44
0.9173
10:54:05
23-Apr-14
6
18.9
16.3
44
0.9291
11:09:05
23-Apr-14
7
17.3
16.7
44
0.8397
11:24:05
23-Apr-14
8
16.9
17.2
43
0.8149
11:39:05
23-Apr-14
9
17
17.6
42
0.7918
11:54:05
23-Apr-14
10
17
17.9
42
0.8164
12:09:05
23-Apr-14
11
16.7
18.3
41
0.7946
12:24:05
23-Apr-14
12
16.1
18.8
40
0.8301
12:39:05
23-Apr-14
13
15.7
19.5
39
0.7993
12:54:05
23-Apr-14
14
16.6
19.8
37
0.7536
13:09:05
23-Apr-14
15
16.8
20.5
37
0.7453
13:24:05
23-Apr-14
16
16.3
20.9
36
0.7089
13:39:05
23-Apr-14
17
16.1
21
36
0.6967
13:54:05
23-Apr-14
18
14.8
21.3
35
0.8184
14:09:05
23-Apr-14
19
13.5
21.5
33
0.7415
14:24:05
23-Apr-14
20
13.7
21.4
33
0.7941
14:39:05
23-Apr-14
21
14.2
21.1
33
0.798
14:54:05
23-Apr-14
22
14
21
33
0.8422
15:09:05
23-Apr-14
23
13.7
20.8
34
0.8183
15:24:05
23-Apr-14
24
13.4
20.3
34
0.823
15:39:05
23-Apr-14
25
16.2
19.8
35
1.0099
15:54:05
23-Apr-14
26
14.4
19.7
36
0.8381
16:09:05
23-Apr-14
27
13
19.6
36
0.8693
16:24:05
23-Apr-14
28
12.6
19.4
36
0.8803
16:39:05
23-Apr-14
29
15
19.2
36
0.7909
16:54:05
23-Apr-14
30
10.3
19.1
36
0.7256
17:09:05
23-Apr-14
2
-------
Particulate Air Monitoring Date
Ellisville RV007
April 23, 2014
Ellisville (RV007) Down Wind PM-10 Data April 23, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
22.7
16.8
38
0.9905
10:00:34
23-Apr-14
2
21.8
19.4
37
0.9316
10:15:34
23-Apr-14
3
23.4
21.6
33
0.8541
10:30:34
23-Apr-14
4
27.5
23
31
0.9945
10:45:34
23-Apr-14
5
24.8
23.9
30
0.8304
11:00:34
23-Apr-14
6
23.9
24.5
29
0.9201
11:15:34
23-Apr-14
7
20.3
24.8
28
0.8038
11:30:34
23-Apr-14
8
20.2
24
28
0.806
11:45:34
23-Apr-14
9
20.7
22.9
30
0.8263
12:00:34
23-Apr-14
10
20.9
22.5
31
0.8128
12:15:34
23-Apr-14
11
22.4
22.8
30
0.7897
12:30:34
23-Apr-14
12
23.4
23.7
29
0.7686
12:45:34
23-Apr-14
13
29.9
24.5
28
0.7394
13:00:34
23-Apr-14
14
21.5
25.1
27
0.7572
13:15:34
23-Apr-14
15
21.5
26.8
26
0.7134
13:30:34
23-Apr-14
16
23.2
28.2
25
0.7216
13:45:34
23-Apr-14
17
18.6
29.1
24
0.7097
14:00:34
23-Apr-14
18
17.4
28.4
23
0.6917
14:15:34
23-Apr-14
19
19.6
27.5
23
0.8499
14:30:34
23-Apr-14
20
23.5
26
24
0.76
14:45:34
23-Apr-14
21
24.6
24.5
26
1.1145
15:00:34
23-Apr-14
22
19.4
23.6
27
0.865
15:15:34
23-Apr-14
23
26.7
22.7
28
0.9387
15:30:34
23-Apr-14
24
26.9
21.6
30
0.77
15:45:34
23-Apr-14
25
21.2
21
31
0.8283
16:00:34
23-Apr-14
26
22.2
20.8
32
0.8999
16:15:34
23-Apr-14
27
19.5
20.6
32
0.8484
16:30:34
23-Apr-14
28
16.8
20.3
32
0.8041
16:45:34
23-Apr-14
29
18.1
20.1
33
1.0012
17:00:34
23-Apr-14
3
-------
PID (VOC) results Ellisville (RV007)
April 23, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
1
-------
PID (VOC) results Ellisville RV007
April 23, 2014
Ellisville (RV007) Upwind PID Data EA3 UW April 23, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
4/23/2014 9:38
0
0
0
0
20.4
2
4/23/2014 9:53
0
0
0
0
20.5
3
4/23/2014
10:08
0
0
0
0
20.5
4
4/23/2014
10:23
0
0
0
0
20.5
5
4/23/2014
10:38
0
0
0
0
20.6
6
4/23/2014
10:53
0
0
0
0
20.6
7
4/23/2014
11:08
0
0
0
0
20.6
8
4/23/2014
11:23
0
0
0
0
20.6
9
4/23/2014
11:38
0
0
0
0
20.6
10
4/23/2014
11:53
0
0
0
0
20.6
11
4/23/2014
12:08
0
0
0
0
20.6
12
4/23/2014
12:23
0
0
0
0
20.6
13
4/23/2014
12:38
0
0
0
0
20.7
14
4/23/2014
12:53
0
0
0
0
20.9
15
4/23/2014
13:08
0
0
0
0
20.9
16
4/23/2014
13:23
0
0
0
0
20.9
17
4/23/2014
13:38
0
0
0
0
20.9
18
4/23/2014
13:53
0
0
0
0
20.9
19
4/23/2014
14:08
0
0
0
0
20.9
20
4/23/2014
14:23
0
0
0
0
20.9
21
4/23/2014
14:38
0
0
0
0
20.9
22
4/23/2014
14:53
0
0
0
0
20.9
23
4/23/2014
15:08
0
0
0
0
20.9
24
4/23/2014
15:23
0
0
0
0
20.9
25
4/23/2014
15:38
0
0
0
0
20.9
26
4/23/2014
15:53
0
0
0
0
20.9
Alarm
2
-------
PID (VOC) results Ellisville RV007
April 23, 2014
Ellisville (RV007) Downwind PID Data EA3 UW April 23, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
4/23/2014 9:44
1.1
0.3
0.1
0
20.3
2
4/23/2014 9:59
1.1
0.2
0.9
0
20.4
3
4/23/2014
10:14
1.1
0.1
1.3
0
20.5
4
4/23/2014
10:29
1.2
0
1.2
0
20.5
5
4/23/2014
10:44
1.2
0
0.7
0
20.6
6
4/23/2014
10:59
0.9
0
0.2
0
20.8
7
4/23/2014
11:14
0.7
0
0
0
20.9
8
4/23/2014
11:29
0.4
0
0
0
20.9
9
4/23/2014
11:44
0.2
0
0
0
20.9
10
4/23/2014
11:59
0.1
0
0
0
20.9
11
4/23/2014
12:14
0.1
0
0
0
20.9
12
4/23/2014
12:29
0.1
0
0
0
20.9
13
4/23/2014
12:44
0.2
0
0
0
20.9
14
4/23/2014
12:59
0.1
0
0
0
20.9
15
4/23/2014
13:14
0.2
0
0
0
20.9
16
4/23/2014
13:29
0.3
0
0
0
20.9
17
4/23/2014
13:44
0.4
0
0
0
20.9
18
4/23/2014
13:59
0.3
0
0
0
20.9
19
4/23/2014
14:14
0.2
0
0
0
20.9
20
4/23/2014
14:29
0.2
0
0
0
20.9
21
4/23/2014
14:44
0.1
0
0
0
20.9
22
4/23/2014
14:59
0
0
0
0
20.9
23
4/23/2014
15:14
0.1
0
0
0
20.9
24
4/23/2014
15:29
0.1
0
0
0
20.9
25
4/23/2014
15:44
0.1
0
0
0
20.9
26
4/23/2014
15:59
0.1
0.1
0
0
20.9
27
4/23/2014
16:14
0.1
0.1
0
0
20.9
28
4/23/2014
16:29
0.1
0.1
0
0
20.9
29
4/23/2014
16:44
0.1
0.1
0
0
20.9
3
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 24, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up wind PM-10 Data April 24, 2014
record (MASS )ug/m3 Temp RHumidity Diameter time date
1 15.6 27.3 35 0.4978 16:25:36 24-Apr-14
2 14.2 27.2 34 0.4534 16:40:36 24-Apr-14
Ellisville (RV007) Down Wind PM-10 Data April 24, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
16.1
26.8
35
0.6341
16:01:19
24-Apr-14
2
14.5
27.2
33
0.6111
16:16:19
24-Apr-14
3
14.1
27
33
0.5549
16:31:19
24-Apr-14
4
15.6
26.6
33
0.5841
16:46:19
24-Apr-14
1
-------
PID (VOC) results Ellisville (RV007)
April 24, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data EA3 UW April 24, 2014
Line# Date Time
CO VOC H2S LEL
(ppm) Alarm (ppm) Alarm (ppm) Alarm <0L
OXY
Alarm l°L
Alarm
1 4/24/2014 15:42 2.4
2 4/24/2014 15:57 2.3
3 4/24/2014 16:12 2.1
4 4/24/2014 16:27 1.9
0
0
0
0
0.5
1
0.8
0.4
0
0
0
0
20.5
20.6
20.6
20.8
Ellisville (RV007) Downwind PID Data EA3 UW April 24, 2014
CO
VOC
H2S
LEL
OXY
Line# Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1 4/24/2014 15:57
0.3
0
0.2
0
20.9
2 4/24/2014 16:12
0.4
0
0.1
0
20.9
3 4/24/2014 16:27
0.2
0
0
0
20.9
1
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 25, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up wind PM-10 Data April 25, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
4.6
23.3
33
0.6825
12:46:21
25-Apr-14
2
4
23.9
33
0.6228
13:01:21
25-Apr-14
3
3.9
24.4
32
0.5384
13:16:21
25-Apr-14
4
10.4
24.9
31
0.9956
13:31:21
25-Apr-14
5
5.8
25.4
30
1.0847
13:46:21
25-Apr-14
6
2.2
25.7
28
0.5155
14:01:21
25-Apr-14
7
4.7
26
28
0.6245
14:16:21
25-Apr-14
8
9.2
26.5
26
1.295
14:31:21
25-Apr-14
9
4.5
26.9
26
1.0247
14:46:21
25-Apr-14
10
6.2
27.2
25
1.1063
15:01:21
25-Apr-14
11
3
27.6
24
0.5061
15:16:21
25-Apr-14
12
3.9
27.9
22
0.8601
15:31:21
25-Apr-14
13
1.7
28.1
21
0.5028
15:46:21
25-Apr-14
14
3.5
28.3
21
0.564
16:01:21
25-Apr-14
15
1.5
28.4
22
0.6291
16:16:21
25-Apr-14
16
3
28.5
21
0.738
16:31:21
25-Apr-14
17
1.4
28.6
22
0.486
16:46:21
25-Apr-14
18
2.5
28.5
22
1.0794
17:01:21
25-Apr-14
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 25, 2014
Ellisville (RV007) Down Wind PM-10 Data April 25, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
date
1
4.1
23
33
0.5702
12:50:32
25-Apr-14
2
2.1
23.6
32
0.6639
13:05:32
25-Apr-14
3
1.9
23.9
31
0.7231
13:20:32
25-Apr-14
4
1.6
24.2
31
0.6949
13:35:32
25-Apr-14
5
1.5
24.4
29
0.4547
13:50:32
25-Apr-14
6
1.5
24.5
27
0.5078
14:05:32
25-Apr-14
7
1.6
24.7
28
0.5176
14:20:32
25-Apr-14
8
1.5
25
27
0.5364
14:35:32
25-Apr-14
9
0.7
25.3
27
0.3721
14:50:32
25-Apr-14
10
0.3
25.6
25
0.3427
15:05:32
25-Apr-14
11
0.5
26
24
0.3541
15:20:32
25-Apr-14
12
0.5
26.4
23
0.368
15:35:32
25-Apr-14
13
0.6
26.7
21
0.4048
15:50:32
25-Apr-14
14
0.7
27
22
0.423
16:05:32
25-Apr-14
15
0.5
27.3
22
0.4342
16:20:32
25-Apr-14
16
0.4
27.8
21
0.3753
16:35:32
25-Apr-14
17
0.6
28.6
21
0.4792
16:50:32
25-Apr-14
18
0.2
29.7
20
0.351
17:05:32
25-Apr-14
2
-------
PID (VOC) results Ellisville (RV007)
April 25, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data EA3 UW April 25, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
4/25/2014
12:36
0
0
0
0
20.9
2
4/25/2014
12:51
0
0
0
0
20.9
3
4/25/2014
13:06
0
0
0
0
20.9
4
4/25/2014
13:21
0
0
0
0
20.9
5
4/25/2014
13:36
0
0
0
0
20.9
6
4/25/2014
13:51
0
0
0
0
20.9
7
4/25/2014
14:06
0
0
0
0
20.9
8
4/25/2014
14:21
0
0
0
0
20.9
9
4/25/2014
14:36
0
0
0
0
20.9
10
4/25/2014
14:51
0
0
0
0
20.9
11
4/25/2014
15:06
0
0
0
0
20.9
12
4/25/2014
15:21
0
0
0
0
20.9
13
4/25/2014
15:36
0
0
0
0
20.9
14
4/25/2014
15:51
0
0
0
0
20.9
15
4/25/2014
16:06
0
0
0
0
20.9
16
4/25/2014
16:21
0
0
0
0
20.9
17
4/25/2014
16:36
0
0
0
0
20.9
18
4/25/2014
16:51
0
0
0
0
20.9
1
-------
PID (VOC) results Ellisville RV007
April 25, 2014
Ellisville (RV007) Downwind PID Data EA3 UW April 25, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%) Alarm
1
4/25/2014
12:35
2.5
0
0.9
0
20.5
2
4/25/2014
12:50
2.3
0
0.8
0
20.6
3
4/25/2014
13:05
1.9
0
0.4
0
20.6
4
4/25/2014
13:20
1.5
0
0.1
0
20.6
5
4/25/2014
13:35
1.3
0
0
0
20.6
6
4/25/2014
13:50
1.1
0
0
0
20.6
7
4/25/2014
14:05
0.9
0
0
0
20.6
8
4/25/2014
14:20
0.8
0
0
0
20.6
9
4/25/2014
14:35
0.7
0
0
0
20.8
10
4/25/2014
14:50
0.6
0
0
0
20.9
11
4/25/2014
15:05
0.6
0
0
0
20.9
12
4/25/2014
15:20
0.5
0
0
0
20.9
13
4/25/2014
15:35
0.4
0
0
0
20.9
14
4/25/2014
15:50
0.4
0
0
0
20.9
15
4/25/2014
16:05
0.3
0
0
0
20.9
16
4/25/2014
16:20
0.5
0
0.1
0
20.9
17
4/25/2014
16:35
0.7
0
0.2
0
20.9
18
4/25/2014
16:50
0.9
0
0.3
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
April 29, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data April 29, 2014
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
1.7
18.5
41
0.4341
11:24:25
29-Apr-14
2
1.3
19
40
0.4649
11:39:25
29-Apr-14
3
1.9
19.7
39
0.6533
11:54:25
29-Apr-14
4
1.2
20.5
38
0.6907
12:09:25
29-Apr-14
5
1.3
21.4
36
0.6481
12:24:25
29-Apr-14
6
1.6
21.5
36
0.6857
12:39:25
29-Apr-14
7
1.9
23
34
0.646
12:54:25
29-Apr-14
8
1.7
24.7
31
0.5847
13:09:25
29-Apr-14
9
1.4
25.7
29
0.4484
13:24:25
29-Apr-14
10
0.9
26.6
28
0.3725
13:39:25
29-Apr-14
11
0.6
27.5
26
0.4011
13:54:25
29-Apr-14
12
0.7
27.9
25
0.4595
14:09:25
29-Apr-14
13
0.9
28
25
0.4517
14:24:25
29-Apr-14
14
1.4
27.1
25
0.631
14:39:25
29-Apr-14
15
0.4
26.6
25
0.4563
14:54:25
29-Apr-14
16
0.5
25.8
26
0.3376
15:09:25
29-Apr-14
17
0.6
24.6
27
0.3879
15:24:25
29-Apr-14
18
1.3
23.5
29
0.4121
15:39:25
29-Apr-14
19
2.4
22.3
31
0.5225
15:54:25
29-Apr-14
20
2
20.9
35
0.7284
16:09:25
29-Apr-14
1
-------
Particulate Air Monitoring Date Ellisville RV007
April 29, 2014
Ellisville (RV007) Down Wind PM-10 Data April 29, 2014
record
(MASS) ug/m3
Temp
RHumidity
Diameter
Time
Date
1
2.6
19.4
41
0.4782
11:28
15
29-Apr-14
2
2
19.6
42
0.4924
11:43
15
29-Apr-14
3
1.7
20.1
42
0.4297
11:58
15
29-Apr-14
4
1.7
20.7
42
0.4601
12:13
15
29-Apr-14
5
2
21.4
40
0.547
12:28
15
29-Apr-14
6
2.5
21.6
40
0.4948
12:43
15
29-Apr-14
7
2.6
23.1
39
0.5346
12:58
15
29-Apr-14
8
2.4
24.5
36
0.4943
13:13
15
29-Apr-14
9
3
25.7
34
0.595
13:28
15
29-Apr-14
10
2.6
27.1
32
0.4511
13:43
15
29-Apr-14
11
1.8
28.6
29
0.4508
13:58
15
29-Apr-14
12
2.2
30.1
27
0.5075
14:13
15
29-Apr-14
13
2
30.5
25
0.43
14:28
15
29-Apr-14
14
1.9
29.1
25
0.446
14:43
15
29-Apr-14
15
1.1
27.7
26
0.4702
14:58
15
29-Apr-14
16
1.2
25.8
28
0.3614
15:13
15
29-Apr-14
17
1.7
24.1
30
0.5485
15:28
15
29-Apr-14
18
2
22.8
32
0.4808
15:43
15
29-Apr-14
19
3.1
21.6
34
0.5657
15:58
15
29-Apr-14
20
3.2
20.3
37
0.4851
16:13
15
29-Apr-14
2
-------
PID (VOC) results Ellisville (RV007)
April 29, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data EA3 UW April 29, 2014
CO
VOC
H2S
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
LEL (%) Alarm
OXY (%)
1
4/29/2014 11:14
0
0
0.2
0
20.9
2
4/29/2014 11:29
0
0
0.3
0
20.9
3
4/29/2014 11:44
0
0
0.5
0
20.9
4
4/29/2014 11:59
0
0
0.5
0
20.9
5
4/29/2014 12:14
0
0
0.2
0
20.9
6
4/29/2014 12:29
0
0
0.1
0
20.9
7
4/29/2014 12:44
0
0
0.2
0
20.9
8
4/29/2014 12:59
0
0
0.4
0
20.9
9
4/29/2014 13:14
0
0
0.7
0
20.9
10
4/29/2014 13:29
0
0
1.3
0
20.9
11
4/29/2014 13:44
0
0
2
0
20.9
12
4/29/2014 13:59
0
0
3
0
20.9
13
4/29/2014 14:14
0
0
2.2
0
21.2
14
4/29/2014 14:29
0
0
0.3
0
21.2
15
4/29/2014 14:44
0
0
0
0
21.2
16
4/29/2014 14:59
0
0
0
0
21.1
17
4/29/2014 15:14
0
0
0
0
21.1
18
4/29/2014 15:29
0
0
0
0
21.1
19
4/29/2014 15:44
0
0
0
0
20.9
20
4/29/2014 15:59
0
0
0
0
21.1
Alarm
1
-------
PID (VOC) results Ellisville RV007
April 29, 2014
Ellisville (RV007) Downwind PID Data EA3 UW April 29, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
4/29/2014
11:08
0
0
0
0
20.9
2
4/29/2014
11:23
0
0
0
0
20.9
3
4/29/2014
11:38
0
0
0
0
20.9
4
4/29/2014
11:53
0
0
0
0
20.9
5
4/29/2014
12:08
0.1
0
0
0
20.9
6
4/29/2014
12:23
0
0
0
0
20.9
7
4/29/2014
12:38
0
0
0
0
20.9
8
4/29/2014
12:53
0.2
0
0
0
20.9
9
4/29/2014
13:08
0.2
0
0
0
20.9
10
4/29/2014
13:23
0.3
0
0
0
20.9
11
4/29/2014
13:38
0.7
0
0
0
20.9
12
4/29/2014
13:53
0.7
0
0
0
20.9
13
4/29/2014
14:08
0.8
0
0
0
21
14
4/29/2014
14:23
0.4
0
0
0
21.1
15
4/29/2014
14:38
0.4
0
0
0
21.1
16
4/29/2014
14:53
0.2
0
0
0
21.1
17
4/29/2014
15:08
0.2
0
0
0
21.1
18
4/29/2014
15:23
0.1
0
0
0
21
19
4/29/2014
15:38
0.1
0
0
0
20.9
20
4/29/2014
15:53
0.1
0
0
0
20.9
21
4/29/2014
16:08
0
0
0
0
21
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 1, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) UpWind PM-10 Data May 1, 2014
record (MASS)ug/m3 Temp RHumidity Diameter Time Date
1 5.1 16.1 39 0.517 15:50:04 1-May-14
2 3.8 15 42 0.492 16:05:04 1-May-14
3 3.6 14.4 44 0.4001 16:20:04 1-May-14
4 3.1 14.4 46 0.5069 16:35:04 1-May-14
Ellisville
(RV007) Down Wind PM-10 Data May 1, 2014
record
(MASS )ug/m3
Temp
RHumidity Diameter
Time
Date
1
5.1
16.1
39 0.517
15:50:04
1-May-14
2
3.8
15
42 0.492
16:05:04
1-May-14
3
3.6
14.4
44 0.4001
16:20:04
1-May-14
4
3.1
14.4
46 0.5069
16:35:04
1-May-14
1
-------
PID (VOC) results Ellisville (RV007)
May 1, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data EA3 UW May 1, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 5/1/2014 15:32 0 0 0 0 20.9
2 5/1/2014 15:47 0 0 0 0 20.9
3 5/1/2014 16:02 0 0 0 0 20.9
Ellisville (RV007) Downwind PID Data EA3 UW May 1, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 5/1/2014 15:36 0 0 0.1 0 20.9
2 5/1/2014 15:51 0 0 0 0 20.9
3 5/1/2014 16:06 0 0 0 0 20.9
4 5/1/2014 16:21 0 0 0 0 20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 2, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Down Wind PM-10 Data May 2, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
6.5
14
47
0.4978
9:02:11
2-May-14
2
7.2
13.4
50
0.5693
9:17:11
2-May-14
3
7.1
13
52
0.5663
9:32:11
2-May-14
4
8
12.8
52
0.6492
9:47:11
2-May-14
5
7.4
12.8
53
0.6188
10:02:11
2-May-14
**NOTE** Upwind data not available for 5/2/2014
1
-------
PID (VOC) results Ellisville (RV007)
May 2, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data EA3 UW May 2, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
5/2/2014 8:48
0
0
0
0
20.9
2
5/2/2014 9:03
0
0
0
0
20.9
3
5/2/2014 9:18
0
0
0
0
20.9
4
5/2/2014 9:33
0
0
0
0
20.9
5
5/2/2014 9:48
0
0
0
0
20.9
Ellisville (RV007) Downwind PID Data EA3 UW May 2, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
5/2/2014 8:44
0
0
0
0
20.9
2
5/2/2014 8:59
0
0
0
0
20.9
3
5/2/2014 9:14
0
0
0
0
20.9
4
5/2/2014 9:29
0.1
0
0
0
20.9
5
5/2/2014 9:44
0.1
0
0
0
20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 7, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data May 7, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
24.8
30.2
51
0.5725
9:15:10
7-May-14
2
25.7
30.1
51
0.5134
9:30:10
7-May-14
3
26.2
29.3
50
0.5535
9:45:15
7-May-14
4
26.6
28.9
50
0.5554
10:00:10
7-May-14
5
26.9
28.2
50
0.5775
10:15:10
7-May-14
Ellisville (RV007) Down Wind PM-10 Data May 7, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
24.2
30.2
43
0.37
9:20:15
i
CO
1
h-
2
25.8
30.1
43
0.36
9:35:15
1
CO
1
h-
3
26
29.3
45
0.38
9:50:15
1
CO
1
h-
4
27.8
28.9
46
0.4
10:05:15
1
CO
1
h-
5
24.9
28.2
47
0.38
10:20:15
1
CO
1
1
-------
PID (VOC) results Ellisville (RV007)
May 7, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data May 7, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
5/7/2014 8:59
1.4
0
0.6
0
20.9
2
5/7/2014 9:14
1.5
0
0.5
0
20.9
3
5/7/2014 9:29
1.3
0
0.4
0
20.9
4
5/7/2014 9:44
1.2
0
0.4
0
20.9
5
5/7/2014 9:59
1.2
0
0.3
0
20.9
Ellisville (RV007) Downwind PID Data May 7, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
5/7/2014 9:05
1.1
0
1.1
0
20.9
2
5/7/2014 9:20
1.1
0
1.3
0
20.9
3
5/7/2014 9:35
0.8
0
0.4
0
20.9
4
5/7/2014 9:50
0.6
0
0
0
20.9
5
5/7/2014 10:05
0.3
0
0
0
20.9
1
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 16, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
1
-------
Ellisville (RV007) Up Wind PM-10 Data May 16, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
32.5
12.8
54
0.3127
9:04
11
16-May-14
2
32.3
13.6
53
0.3061
9:19
11
16-May-14
3
32.8
14.3
50
0.3105
9:34
11
16-May-14
4
32.1
15
48
0.3075
9:49
11
16-May-14
5
31.3
15.5
46
0.3081
10:04
11
16-May-14
6
32.1
15.2
45
0.3137
10:19
11
16-May-14
7
31.1
15.4
45
0.3074
10:34
11
16-May-14
8
30.8
15.6
43
0.3067
10:49
11
16-May-14
9
30.7
15.5
42
0.3041
11:04
11
16-May-14
10
30.9
15.6
42
0.3007
11:19
11
16-May-14
11
30.9
15.6
41
0.3149
11:34
11
16-May-14
12
29.4
15.8
41
0.2938
11:49
11
16-May-14
13
29.2
15.7
40
0.2867
12:04
11
16-May-14
14
29.8
15.6
40
0.2861
12:19
11
16-May-14
15
28.7
15.6
40
0.2725
12:34
11
16-May-14
16
29.9
15.6
40
0.2798
12:49
11
16-May-14
17
29.6
15.6
40
0.2757
13:04
11
16-May-14
18
30.1
15.8
40
0.2826
13:19
11
16-May-14
19
29.2
15.8
40
0.2746
13:34
11
16-May-14
20
29.3
15.8
39
0.2716
13:49
11
16-May-14
21
29.5
16
39
0.2892
14:04
11
16-May-14
22
29.8
16.2
39
0.2886
14:19
11
16-May-14
23
29.2
16.3
39
0.2873
14:34
11
16-May-14
24
30.5
16.5
39
0.2855
14:49
11
16-May-14
25
29.2
16.5
38
0.2905
15:04
11
16-May-14
26
28.3
16.5
38
0.2774
15:19
11
16-May-14
27
29.2
16.5
39
0.2872
15:34
11
16-May-14
28
28.4
16.7
39
0.2706
15:49
11
16-May-14
29
30.4
16.7
37
0.2927
16:04
11
16-May-14
30
28.7
16.7
38
0.2733
16:19
11
16-May-14
31
28.5
16.8
37
0.2775
16:34
11
16-May-14
32
28.8
16.6
38
0.2806
16:49
11
16-May-14
33
28.3
16.5
38
0.2758
17:04
11
16-May-14
34
28.7
16.3
38
0.2833
17:19
11
16-May-14
35
29.4
16.3
38
0.2881
17:34
11
16-May-14
36
29.1
16.2
38
0.2833
17:49
11
16-May-14
37
28.9
16.1
38
0.2861
18:04
11
16-May-14
2
-------
Ellisville (RV007) Down Wind PM-10 Data May 16, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
8.6
17.1
47
0.5651
9:13
16
16-May-
2
8.8
17.5
43
0.5844
9:28
16
16-May-
3
8.2
17.5
42
0.5898
9:43
16
16-May-
4
8.3
17
42
0.7216
9:58
16
16-May-
5
7.9
15.9
43
0.6656
10:13
16
16-May-
6
7.9
15.1
43
0.7827
10:28
16
16-May-
7
7.7
14.7
44
0.7196
10:43
16
16-May-
8
7.1
14.5
43
0.7271
10:58
16
16-May-
9
6.8
14.3
43
0.6271
11:13
16
16-May-
10
6.6
14.4
42
0.6014
11:28
16
16-May-
11
7
14.8
43
0.7488
11:43
16
16-May-
12
6.1
15.1
42
0.6791
11:58
16
16-May-
13
5.5
15.2
42
0.6472
12:13
16
16-May-
14
4.9
15.3
40
0.5172
12:28
16
16-May-
15
5.1
15.3
41
0.4801
12:43
16
16-May-
16
5.2
15.3
41
0.4807
12:58
16
16-May-
17
5.2
15.6
40
0.514
13:13
16
16-May-
18
5.3
15.7
40
0.5147
13:28
16
16-May-
19
5.1
15.8
39
0.4592
13:43
16
16-May-
20
5.2
15.9
39
0.4491
13:58
16
16-May-
21
5
16.1
38
0.4889
14:13
16
16-May-
22
4.8
16.3
39
0.443
14:28
16
16-May-
23
4.8
16.5
39
0.4517
14:43
16
16-May-
24
4.8
16.6
38
0.5182
14:58
16
16-May-
25
4.2
16.6
39
0.4634
15:13
16
16-May-
26
4.6
16.7
38
0.4237
15:28
16
16-May-
27
4.6
18.4
37
0.4149
15:43
16
16-May-
28
4
21.4
33
0.4131
15:58
16
16-May-
29
3.6
22.5
31
0.3765
16:13
16
16-May-
30
3.4
23.3
29
0.3842
16:28
16
16-May-
31
3.7
22.3
29
0.4134
16:43
16
16-May-
32
3.6
22.1
30
0.4375
16:58
16
16-May-
33
3.4
21.2
31
0.3915
17:13
16
16-May-
34
3.3
20.1
31
0.4161
17:28
16
16-May-
35
3.5
19.3
32
0.4068
17:43
16
16-May-
36
3.5
18.7
33
0.4191
17:58
16
16-May-
37
3.5
17.9
34
0.4228
18:13
16
16-May-
38
3.6
17.2
36
0.4036
18:28
16
16-May-
39
3.7
16.8
38
0.3982
18:43
16
16-May-
40
3.8
16.3
43
0.3771
18:58
16
16-May-
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
3
-------
PID (VOC) results Ellisville (RV007)
May 16, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data May 16, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%)
1 5/16/2014 8:49 0
2 5/16/2014 9:04 0
3 5/16/2014 9:19 0
4 5/16/2014 9:34 0
5 5/16/2014 9:49 0
6 5/16/2014 10:04 0
7 5/16/2014 10:19 0
8 5/16/2014 10:34 0
9 5/16/2014 10:49 0
10 5/16/2014 11:04 0
11 5/16/2014 11:19 0
12 5/16/2014 11:34 0
13 5/16/2014 11:49 0
14 5/16/2014 12:04 0
15 5/16/2014 12:19 0
16 5/16/2014 12:34 0
17 5/16/2014 12:49 0
18 5/16/2014 13:04 0
19 5/16/2014 13:19 0
20 5/16/2014 13:34 0
21 5/16/2014 13:49 0
22 5/16/2014 14:04 0
23 5/16/2014 14:19 0
24 5/16/2014 14:34 0
25 5/16/2014 14:49 0
26 5/16/2014 15:04 0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
20.9
1
-------
PID (VOC) results Ellisville RV007
May 16, 2014
Ellisville (RV007) Downwind PID Data May 16, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%) Alarm
1
5/16/2014 9:02
0.8
0
0.5
0
20.9
2
5/16/2014 9:17
0.6
0
0.1
0
20.9
3
5/16/2014 9:32
0.4
0
0
0
20.9
4
5/16/2014 9:47
0.3
0
0
0
20.9
5
5/16/2014
10:02
0.2
0
0
0
20.9
6
5/16/2014
10:17
0.2
0
0
0
20.9
7
5/16/2014
10:32
0.2
0
0
0
20.9
8
5/16/2014
10:47
0.2
0
0
0
20.9
9
5/16/2014
11:02
0.2
0
0
0
20.9
10
5/16/2014
11:17
0.2
0
0
0
20.9
11
5/16/2014
11:32
0.3
0
0
0
20.9
12
5/16/2014
11:47
0.3
0
0
0
20.9
13
5/16/2014
12:02
0.3
0
0
0
20.9
14
5/16/2014
12:17
0.3
0
0
0
20.9
15
5/16/2014
12:32
0.3
0
0
0
20.9
16
5/16/2014
12:47
0.3
0
0
0
20.9
17
5/16/2014
13:02
0.3
0
0
0
20.9
18
5/16/2014
13:17
0.3
0
0
0
20.9
19
5/16/2014
13:32
0.3
0
0
0
20.9
20
5/16/2014
13:47
0.3
0
0
0
20.9
21
5/16/2014
14:02
0.3
0
0
0
20.9
22
5/16/2014
14:17
0.4
0
0
0
20.9
23
5/16/2014
14:32
0.4
0
0
0
20.9
24
5/16/2014
14:47
0.4
0
0
0
20.9
25
5/16/2014
15:02
0.4
0
0
0
20.9
26
5/16/2014
15:17
0.5
0
0
0
20.9
27
5/16/2014
15:32
0.6
0
0.1
0
20.9
28
5/16/2014
15:47
0.8
0
1
0
20.9
29
5/16/2014
16:02
0.8
0
1
0
21.1
30
5/16/2014
16:17
0.7
0
0.4
0
21.2
31
5/16/2014
16:32
0.7
0
0.1
0
21.2
32
5/16/2014
16:47
0.6
0
0
0
21.2
33
5/16/2014
17:02
0.4
0
0
0
21.1
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 19, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville
record
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
30
31
32
33
(RV007) Up Wind PM-1
(MASS )ug/m3 Temp
0.3
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
0
14.4
16.3
17.9
18.8
19.2
19.6
20.3
20.9
21.2
21.5
21.9
22.1
22.6
23.1
23.9
24.4
25.4
26.4
27.8
28.8
29.8
30.3
30.3
30.1
30
30
30
29.7
29.7
30
29.9
29.9
31.1
0 Data May 1
RHumidity
47
48
48
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
49
48
48
48
48
9, 2014
Diameter
0.3357
0.3372
0.3374
0.3374
0.3374
0.3373
0.3374
0.3374
0.3374
0.3374
0.3374
0.3375
0.3374
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3375
0.3374
0.3375
0.3375
0.3375
0.3375
Time
8:39
8:54
9:09
9:24
9:39
9:54
10:09
10:24
10:39
10:54
11:09
11:24
11:39
11:54
12:09
12:24
12:39
12:54
13:09
13:24
13:39
13:54
14:09
14:24
14:39
14:54
15:09
15:24
15:39
15:54
16:09
16:24
16:39
Date
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
19-May-14
1
-------
Particulate Air Monitoring Date Ellisville RV007
May 19, 2014
Ellisville (RV007) Down Wind PM-10 Data May 19, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
17.2
14.1
53
0.5594
8:41:37
19-May-14
2
12.5
16
52
0.4836
8:56:37
19-May-14
3
14.1
17.3
49
0.4841
9:11:37
19-May-14
4
12
18.1
47
0.4776
9:26:37
19-May-14
5
13.6
18.6
45
0.4616
9:41:37
19-May-14
6
12.6
19.6
43
0.5049
9:56:37
19-May-14
7
9.7
20.7
41
0.4154
10:11:37
19-May-14
8
9.7
21.7
40
0.4219
10:26:37
19-May-14
9
8.8
22.7
39
0.4037
10:41:37
19-May-14
10
8.9
23.6
38
0.3987
10:56:37
19-May-14
11
9.3
25.2
36
0.4255
11:11:37
19-May-14
12
8.9
26.6
34
0.4226
11:26:37
19-May-14
13
9.1
27.6
33
0.4088
11:41:37
19-May-14
14
8.7
28.1
33
0.4149
11:56:37
19-May-14
15
18.7
28.5
33
0.4876
12:11:37
19-May-14
16
13.6
28.3
34
0.5671
12:26:37
19-May-14
17
19.2
28.3
36
0.7351
12:41:37
19-May-14
18
14.1
28.2
37
0.6262
12:56:37
19-May-14
19
12.9
28.3
38
0.7697
13:11:37
19-May-14
20
11.4
28.7
38
0.5429
13:26:37
19-May-14
21
11.9
29.3
38
0.5622
13:41:37
19-May-14
22
12.2
29.7
37
0.7363
13:56:37
19-May-14
23
10.1
30
37
0.5404
14:11:37
19-May-14
24
10
30.4
37
0.512
14:26:37
19-May-14
25
10.3
30.3
37
0.4761
14:41:37
19-May-14
26
10
30.2
38
0.444
14:56:37
19-May-14
27
10.5
30.1
38
0.4807
15:11:37
19-May-14
28
11
29.8
39
0.4589
15:26:37
19-May-14
29
13.2
30.4
38
0.4929
15:41:37
19-May-14
30
11.2
30.8
37
0.4577
15:56:37
19-May-14
31
20.6
30.3
38
0.5123
16:11:37
19-May-14
32
12.1
30.3
39
0.6177
16:26:37
19-May-14
2
-------
PID (VOC) results Ellisville (RV007)
May 19, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
1
-------
PID (VOC) results Ellisville RV007
May 19, 2014
Ellisville (RV007) Upwind PID Data May 19, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
5/19/2014 8:23
0.3
0
0
0
20.9
2
5/19/2014 8:38
0.3
0
0.1
0
20.9
3
5/19/2014 8:53
0.5
0
0
0
20.9
4
5/19/2014 9:08
0.6
0
0
0
21
5
5/19/2014 9:23
0.6
0
0
0
21.2
6
5/19/2014 9:38
0.6
0
0
0
21.2
7
5/19/2014 9:53
0.6
0
0
0
21.2
8
5/19/2014
10:08
0.7
0
0
0
21.2
9
5/19/2014
10:23
0.7
0
0
0
21.2
10
5/19/2014
10:38
0.7
0
0
0
21.2
11
5/19/2014
10:53
0.7
0
0
0
21.2
12
5/19/2014
11:08
0.8
0
0
0
21.2
13
5/19/2014
11:23
0.8
0
0.1
0
21.2
14
5/19/2014
11:38
0.8
0
0.1
0
21.2
15
5/19/2014
11:53
0.8
0
0.1
0
21.2
16
5/19/2014
12:08
1
0
0.1
0
21.2
17
5/19/2014
12:23
0.9
0
0.1
0
21.1
18
5/19/2014
12:38
1
0
0.1
0
21.1
19
5/19/2014
12:53
1.1
0
0.2
0
21.2
20
5/19/2014
13:08
1.3
0
0.2
0
21.2
21
5/19/2014
13:23
1.4
0
0.3
0
21.1
22
5/19/2014
13:38
1.7
0
0.2
0
21.2
23
5/19/2014
13:53
1.8
0
0.2
0
21.2
24
5/19/2014
14:08
1.7
0
0.2
0
21.2
25
5/19/2014
14:23
1.6
0
0.2
0
21.2
26
5/19/2014
14:38
1.6
0
0.2
0
21.2
27
5/19/2014
14:53
1.7
0
0.2
0
21.2
28
5/19/2014
15:08
1.5
0
0.2
0
21.2
29
5/19/2014
15:23
1.6
0
0.2
0
21.2
30
5/19/2014
15:38
1.6
0
0.2
0
21.2
31
5/19/2014
15:53
1.7
0
0.2
0
21.2
32
5/19/2014
16:08
1.4
0
0.2
0
21.2
2
-------
PID (VOC) results Ellisville RV007
May 19, 2014
Ellisville (RV007) Downwind PID Data May 19, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
5/19/2014 8:28
0.1
0
0.1
0
20.9
2
5/19/2014 8:43
0.1
0
0.2
0
20.9
3
5/19/2014 8:58
0.1
0
0.2
0
21.1
4
5/19/2014 9:13
0.1
0
0.1
0
21.2
5
5/19/2014 9:28
0.1
0
0
0
21.2
6
5/19/2014 9:43
0
0
0
0
21.2
7
5/19/2014 9:58
0
0
0
0
21.2
8
5/19/2014
10:13
0
0
0
0
21.3
9
5/19/2014
10:28
0
0
0
0
21.2
10
5/19/2014
10:43
0
0
0
0
21.2
11
5/19/2014
10:58
0.1
0
0.8
0
21.2
12
5/19/2014
11:13
0.1
0
1.9
0
21.3
13
5/19/2014
11:28
0.2
0
2
0
21.4
14
5/19/2014
11:43
0.2
0
1.7
0
21.4
15
5/19/2014
11:58
0.3
0
0.8
0
21.4
16
5/19/2014
12:13
0.1
0
0.2
0
21.5
17
5/19/2014
12:28
0.1
0
0
0
21.4
18
5/19/2014
12:43
0
0
0
0
21.5
19
5/19/2014
12:58
0
0
0
0
21.4
20
5/19/2014
13:13
0
0
0
0
21.4
21
5/19/2014
13:28
0
0
0
0
21.4
22
5/19/2014
13:43
0
0
0
0
21.4
23
5/19/2014
13:58
0
0
0
0
21.4
24
5/19/2014
14:13
0
0
0
0
21.4
25
5/19/2014
14:28
0
0
0
0
21.4
26
5/19/2014
14:43
0
0
0
0
21.4
27
5/19/2014
14:58
0
0
0
0
21.4
28
5/19/2014
15:13
0
0
0
0
21.4
29
5/19/2014
15:28
0
0
0
0
21.4
30
5/19/2014
15:43
0
0
0
0
21.4
31
5/19/2014
15:58
0
0
0
0
21.4
32
5/19/2014
16:13
0
0
0
0
21.4
3
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 21, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data May 21, 2014
record (MASS)ug/m3 Temp RHumidity Diameter Time
1 3.2 27.1 57 0.353 9:24
2 0 29.2 55 0.3412 9:39
3 0.1 31.9 50 0.3599 9:54
4 0 34.1 45 0.3412 10:09
5 0 35.2 42 0.3375 10:24
6 0.2 36.1 40 0.3581 10:39
7 0.3 36.8 39 0.4825 10:54
8 0.2 37.9 37 0.4195 11:09
9 0.1 38.7 36 0.3573 11:24
10 0.3 38.8 35 0.3952 11:39
11 0 38.6 35 0.3467 11:54
12 0.4 38.9 36 0.4327 12:09
13 0 39.1 35 0.3547 12:24
14 0.4 38.5 36 0.3712 12:39
15 0.1 37.3 37 0.3728 12:54
16 0.2 36.6 38 0.3508 13:09
17 0.1 36.6 39 0.3599 13:24
18 0 36.7 39 0.3412 13:39
Date
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
21-May-14
1
-------
Particulate Air Monitoring Date Ellisville RV007
May 21, 2014
Ellisville (RV007) Down Wind PM-10 Data May 21, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
77.2
26.3
59
0.6644
9:25:39
21-May-
2
76.9
27.2
61
0.6356
9:40:39
21-May-
3
77
28.3
60
0.6477
9:55:39
21-May-
4
76.8
29.6
57
0.6344
10:10:39
21-May-
5
76.8
30
55
0.6234
10:25:39
21-May-
6
77
30.2
54
0.6341
10:40:39
21-May-
7
76.4
30.5
54
0.62
10:55:39
21-May-
8
77.1
30.9
53
0.6281
11:10:39
21-May-
9
76.3
31.2
52
0.6206
11:25:39
21-May-
10
76.6
31.4
51
0.6249
11:40:39
21-May-
11
76.5
31.8
50
0.6153
11:55:39
21-May-
12
76.9
32.2
49
0.6211
12:10:39
21-May-
13
77
32.5
49
0.6166
12:25:39
21-May-
14
76.7
33
48
0.614
12:40:39
21-May-
15
83.5
33.7
46
0.6751
12:55:39
21-May-
16
76.2
34
45
0.6205
13:10:39
21-May-
17
76.6
34.2
45
0.6174
13:25:39
21-May-
18
75.8
34.9
44
0.6129
13:40:39
21-May-
2
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
14
-------
PID (VOC) results Ellisville (RV007)
May 21, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data May 21, 2014
CO
VOC
H2S LEL OXY
Line# Date Time
(PPm)
Alarm (ppm) Alarm
(ppm) Alarm (%) Alarm (%)
1
5/21/2014 9:10
0
0
0.3
0
20.9
2
5/21/2014 9:25
0
0
0.3
0
20.9
3
5/21/2014 9:40
0
0
0.3
0
20.9
4
5/21/2014 9:55
0
0
0.3
0
20.9
5
5/21/2014
10:10
0.1
0
0.2
0
20.9
6
5/21/2014
10:25
0
0
0.2
0
20.9
7
5/21/2014
10:40
0
0
0.1
0
20.9
8
5/21/2014
10:55
0
0
0.1
0
20.9
9
5/21/2014
11:10
0
0
0.1
0
20.9
10
5/21/2014
11:25
0
0
0.1
0
20.9
11
5/21/2014
11:40
0
0
0.1
0
20.9
12
5/21/2014
11:55
0
0
0.1
0
20.9
13
5/21/2014
12:10
0
0
0.1
0
20.9
14
5/21/2014
12:25
0
0
0.1
0
20.9
15
5/21/2014
12:40
0
0
0.1
0
20.9
16
5/21/2014
12:55
0
0
0.1
0
20.9
17
5/21/2014
13:10
0
0
0.1
0
20.9
18
5/21/2014
13:25
0.1
0
0.2
0
20.9
1
-------
PID (VOC) results Ellisville RV007
May 21, 2014
Ellisville (RV007) Down Wind PID Data May 21, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
5/21/2014 9:08
0.6
0
0.7
0
20.9
2
5/21/2014 9:23
0.6
0
2.1
0
20.9
3
5/21/2014 9:38
0.8
0
3.6
0
20.9
4
5/21/2014 9:53
1.1
0
4.9
0
20.9
5
5/21/2014
10:08
1.1
0
4.8
0
20.9
6
5/21/2014
10:23
1.3
0
4.6
0
20.9
7
5/21/2014
10:38
1.2
0
4.5
0
20.9
8
5/21/2014
10:53
1.3
0
5.3
0
20.9
9
5/21/2014
11:08
1.5
0
5.9
0
20.9
10
5/21/2014
11:23
1.4
0
5.2
0
20.9
11
5/21/2014
11:38
1.3
0
4.4
0
20.9
12
5/21/2014
11:53
1
0
3.8
0
20.9
13
5/21/2014
12:08
0.9
0
3.4
0
20.9
14
5/21/2014
12:23
0.7
0
2.8
0
20.9
15
5/21/2014
12:38
0.4
0
1.3
0
20.9
16
5/21/2014
12:53
0.1
0
0.1
0
20.9
17
5/21/2014
13:08
0.1
0
0
0
20.9
18
5/21/2014
13:23
0
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 28, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data May 28, 2014
Record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
16.7
30.3
52
0.5633
14:02:22
28-May-14
2
14.7
30.7
49
0.5213
14:17:22
28-May-14
3
16.7
31
48
0.5116
14:32:22
28-May-14
4
17.6
32
49
0.5008
14:47:22
28-May-14
5
17.1
34
43
0.4568
15:02:22
28-May-14
6
17
35.1
40
0.4465
15:17:22
28-May-14
7
18.4
34.6
43
0.4533
15:32:22
28-May-14
8
18.8
33.6
45
0.4767
15:47:22
28-May-14
9
20.4
32.6
48
0.5013
16:02:22
28-May-14
10
17.5
31.8
50
0.5773
16:17:22
28-May-14
11
14.2
31.1
52
0.6407
16:32:22
28-May-14
12
13.7
30.7
55
0.6135
16:47:22
28-May-14
Ellisville
(RV007) Down Wind PM-10 Data May
28, 2014
record
(MASS )ug/m3
Temp
RHumidity Diameter
Time
Date
1
15.6
34.2
43
0.4683
14:05:49
28-May-14
2
14.7
35.5
38
0.4161
14:20:49
28-May-14
3
14.1
37.1
35
0.41
14:35:49
28-May-14
4
14.6
38.1
33
0.3814
14:50:49
28-May-14
5
14.8
38.9
31
0.3771
15:05:49
28-May-14
6
16.5
39
31
0.3834
15:20:49
28-May-14
7
15.6
38.5
32
0.3713
15:35:49
28-May-14
8
16.4
37.2
35
0.3904
15:50:49
28-May-14
9
16.6
36.1
38
0.4243
16:05:49
28-May-14
10
12.6
34.9
40
0.4412
16:20:49
28-May-14
11
12.2
33.9
42
0.4647
16:35:49
28-May-14
12
12.8
33.1
45
0.4714
16:50:49
28-May-14
-------
PID (VOC) results Ellisville (RV007)
May 28, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data May 28, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
5/28/2014
13:50
0.3
0.1
1.2
0
20.6
2
5/28/2014
14:05
0.3
0
2.5
0
20.7
3
5/28/2014
14:20
0.3
0
2.5
0
20.8
4
5/28/2014
14:35
0.3
0
2.8
0
20.7
5
5/28/2014
14:50
0.7
0
4
0
20.8
6
5/28/2014
15:05
0.9
0
4.3
0
20.9
7
5/28/2014
15:20
0.7
0
3.2
0
20.9
8
5/28/2014
15:35
0.3
0
1.9
0
20.9
9
5/28/2014
15:50
0.1
0
1.1
0
20.9
10
5/28/2014
16:05
0
0
0.3
0
20.9
11
5/28/2014
16:20
0
0
0
0
20.9
12
5/28/2014
16:35
0
0
0
0
20.9
1
-------
PID (VOC) results Ellisville RV007
May 28, 2014
Ellisville (RV007) Down Wind PID Data May 28, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
5/28/2014
13:52
1.6
0
0.7
0
20.9
2
5/28/2014
14:07
1.7
0
0.8
0
20.9
3
5/28/2014
14:22
1.7
0
0.7
0
20.9
4
5/28/2014
14:37
1.8
0
0.7
0
20.9
5
5/28/2014
14:52
1.8
0
0.6
0
20.9
6
5/28/2014
15:07
1.7
0
0.5
0
20.9
7
5/28/2014
15:22
1.6
0
0.5
0
20.9
8
5/28/2014
15:37
1.4
0
0.4
0
20.9
9
5/28/2014
15:52
1.2
0
0.3
0
20.9
10
5/28/2014
16:07
1
0
0.3
0
20.9
11
5/28/2014
16:22
0.8
0
0.2
0
20.9
12
5/28/2014
16:37
0.6
0
0.2
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
May 30, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data May 30, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
14.2
25.3
59
0.5016
9:10:44
30-May-14
2
14.3
26.7
61
0.4951
9:25:44
30-May-14
3
13.2
28.3
58
0.471
9:40:44
30-May-14
4
13.9
31.5
51
0.4908
9:55:44
30-May-14
5
11.6
34.1
42
0.4523
10:10:44
30-May-14
6
10.6
34.7
40
0.4505
10:25:44
30-May-14
7
10.9
34.9
40
0.4444
10:40:44
30-May-14
8
12.1
37.3
37
0.466
10:55:44
30-May-14
Ellisville (RV007) Down
Wind PM-10 Data May 30, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
time
Date
1
17
25.1
64
0.6811
9:07:07
30-May-14
2
12.5
28.1
58
0.6607
9:22:07
30-May-14
3
12.1
29.3
54
0.6327
9:37:07
30-May-14
4
11.9
30
52
0.597
9:52:07
30-May-14
5
10
31.3
49
0.5999
10:07:07
30-May-14
6
10.7
31.8
47
0.5499
10:22:07
30-May-14
7
11
31.2
48
0.5586
10:37:07
30-May-14
8
11.5
31
49
0.5573
10:52:07
30-May-14
9
10.3
31.1
47
0.5076
11:07:07
30-May-14
-------
PID (VOC) results Ellisville (RV007)
May 30, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data May 30, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 5/30/2014 8:55 0.2 0 0 0 20.9
2 5/30/2014 9:10 0.2 0 0 0 20.9
3 5/30/2014 9:25 0.3 0 0 0 20.9
4 5/30/2014 9:40 0.5 0 0.1 0 20.9
5 5/30/2014 9:55 0.7 0 0.1 0 20.9
6 5/30/2014 10:10 0.8 0 0.1 0 20.9
7 5/30/2014 10:25 0.7 0 0 0 20.9
8 5/30/2014 10:40 0.8 0 0.1 0 20.9
Ellisville (RV007) Down Wind PID Data May 30, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 5/30/2014 9:20 1.7 0 0.2 0 20.9
2 5/30/2014 9:35 1.6 0 0 0 20.9
3 5/30/2014 9:50 1.3 0 0 0 20.8
4 5/30/2014 10:05 1.6 0 0 0 20.8
5 5/30/2014 10:20 1.2 0 0 0 20.9
6 5/30/2014 10:35 0.9 0 0 0 20.9
7 5/30/2014 10:50 0.8 0 0 0 20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 5, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data June 5, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
14.4
23.1
70
0.0283
8:48:57
5-Jun-14
2
14.8
23.7
68
0.028
9:03:57
5-Jun-14
3
15.4
24
66
0.0285
9:18:57
5-Jun-14
4
15.5
24.6
65
0.028
9:33:57
5-Jun-14
5
13.3
25.3
64
0.028
9:48:57
5-Jun-14
6
14.1
25.8
62
0.0282
10:03:57
5-Jun-14
7
11.6
26.1
60
0.028
10:18:57
5-Jun-14
8
9.9
26.2
61
0.028
10:33:57
5-Jun-14
9
10.6
26.1
60
0.028
10:48:57
5-Jun-14
10
10.8
25.8
60
0.028
11:03:57
5-Jun-14
11
11.6
25.3
62
0.028
11:18:57
5-Jun-14
12
12
25.2
63
0.028
11:33:57
5-Jun-14
13
12.4
25.1
62
0.028
11:48:57
5-Jun-14
14
13.1
25.2
62
0.028
12:03:57
5-Jun-14
15
13.6
25.1
62
0.028
12:18:57
5-Jun-14
16
16.3
25.1
63
0.028
12:33:57
5-Jun-14
17
20.8
25.3
62
0.0295
12:48:57
5-Jun-14
18
26.3
25.6
61
0.0413
13:03:57
5-Jun-14
19
22.8
25.8
61
0.028
13:18:57
5-Jun-14
20
26.6
25.9
60
0.0367
13:33:57
5-Jun-14
21
28.5
26.2
60
0.0431
13:48:57
5-Jun-14
22
31.4
27.3
59
0.057
14:03:57
5-Jun-14
23
37.7
27.7
57
0.084
14:18:57
5-Jun-14
24
36.1
28
55
0.0764
14:33:57
5-Jun-14
25
36.9
28
55
0.0802
14:48:57
5-Jun-14
26
36.1
29.4
54
0.0768
15:03:57
5-Jun-14
27
37.1
31.2
49
0.08
15:18:57
5-Jun-14
1
-------
Particulate Air Monitoring Date Ellisville RV007
June 5, 2014
Ellisville (RV007) Down Wind PM-10 Data June 5, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
9.5
21.7
71
1.8143
9:10:52
5-Jun-
2
14.3
21.8
69
0.8507
9:25:52
5-Jun-
3
15.1
21.7
69
0.7671
9:40:52
5-Jun-
4
14.6
21.9
69
0.6706
9:55:52
5-Jun-
5
14.8
22.2
68
0.7066
10:10:52
5-Jun-
6
14.3
22.5
67
0.6582
10:25:52
5-Jun-
7
13.7
23
66
0.6593
10:40:52
5-Jun-
8
11.1
23.1
65
0.6045
10:55:52
5-Jun-
9
10.9
23.1
65
0.5413
11:10:52
5-Jun-
10
12
22.9
65
0.5059
11:25:52
5-Jun-
11
13.1
22.7
65
0.4982
11:40:52
5-Jun-
12
13.8
22.5
65
0.4976
11:55:52
5-Jun-
13
14
22.5
65
0.4921
12:10:52
5-Jun-
14
14.8
22.6
66
0.4851
12:25:52
5-Jun-
15
15.9
22.6
66
0.5044
12:40:52
5-Jun-
16
18.5
22.5
66
0.5267
12:55:52
5-Jun-
17
21.2
22.6
67
0.5351
13:10:52
5-Jun-
18
24.3
23
67
0.5631
13:25:52
5-Jun-
19
25
23.2
67
0.5508
13:40:52
5-Jun-
20
27
23.3
66
0.5387
13:55:52
5-Jun-
21
29.6
23.5
66
0.5166
14:10:52
5-Jun-
22
31.9
23.8
66
0.5147
14:25:52
5-Jun-
23
36.2
24.2
64
0.517
14:40:52
5-Jun-
24
36.3
24.7
63
0.5071
14:55:52
5-Jun-
25
36.4
25
63
0.5034
15:10:52
5-Jun-
26
37.9
25.3
60
0.5134
15:25:52
5-Jun-
27
38.3
25.7
60
0.5306
15:40:52
5-Jun-
28
37.4
26.3
59
0.5358
15:55:52
5-Jun-
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
2
-------
PID (VOC) results Ellisville (RV007)
June 5, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 5, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/5/2014 8:57
0
0
0
0
20.9
2
6/5/2014 9:12
0
0
0
0
20.9
3
6/5/2014 9:27
0
0
0
0
20.9
4
6/5/2014 9:42
0
0
0
0
20.9
5
6/5/2014 9:57
0
0
0
0
20.9
6
6/5/2014
10:12
0
0
0
0
20.9
7
6/5/2014
10:27
0
0
0
0
20.9
8
6/5/2014
10:42
0
0
0
0
20.9
9
6/5/2014
10:57
0
0
0
0
20.9
10
6/5/2014
11:12
0
0
0
0
20.9
11
6/5/2014
11:27
0
0
0
0
20.9
12
6/5/2014
11:42
0
0
0
0
20.9
13
6/5/2014
11:57
0
0
0
0
20.9
14
6/5/2014
12:12
0
0
0
0
20.9
15
6/5/2014
12:27
0
0
0
0
20.9
16
6/5/2014
12:42
0
0
0
0
20.9
17
6/5/2014
12:57
0
0
0
0
20.9
18
6/5/2014
13:12
0
0
0
0
20.9
19
6/5/2014
13:27
0
0
0
0
20.9
20
6/5/2014
13:42
0
0
0
0
20.9
21
6/5/2014
13:57
0
0
0
0
20.9
22
6/5/2014
14:12
0
0
0
0
20.9
23
6/5/2014
14:27
0
0
0
0
20.9
24
6/5/2014
14:42
0
0
0
0
20.9
25
6/5/2014
14:57
0
0
0
0
20.9
26
6/5/2014
15:12
0
0
0
0
20.9
27
6/5/2014
15:27
0
0
0
0
20.9
28
6/5/2014
15:42
0
0
0
0
20.9
1
-------
PID (VOC) results Ellisville RV007
June 5, 2014
Ellisville (RV007) Down Wind PID Data June 5, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/5/2014 8:58
0.8
0
1
0
20.9
2
6/5/2014 9:13
0.6
0
0.8
0
20.9
3
6/5/2014 9:28
0.4
0
0.6
0
20.9
4
6/5/2014 9:43
0.3
0
0.4
0
20.9
5
6/5/2014 9:58
0.2
0
0.4
0
20.9
6
6/5/2014
10:13
0.2
0
0.3
0
20.9
7
6/5/2014
10:28
0.1
0
0.3
0
20.9
8
6/5/2014
10:43
0.1
0
0.1
0
20.9
9
6/5/2014
10:58
0.4
0
0
0
20.9
10
6/5/2014
11:13
0.2
0
0
0
20.9
11
6/5/2014
11:28
0
0
0
0
20.9
12
6/5/2014
11:43
0
0
0
0
20.9
13
6/5/2014
11:58
0
0
0
0
20.9
14
6/5/2014
12:13
0
0
0
0
20.9
15
6/5/2014
12:28
0
0
0
0
20.9
16
6/5/2014
12:43
0
0
0
0
20.9
17
6/5/2014
12:58
0
0
0
0
20.9
18
6/5/2014
13:13
0
0
0
0
20.9
19
6/5/2014
13:28
0
0
0
0
20.9
20
6/5/2014
13:43
0
0
0
0
20.9
21
6/5/2014
13:58
0
0
0
0
20.9
22
6/5/2014
14:13
0
0
0
0
20.9
23
6/5/2014
14:28
0
0
0
0
20.9
24
6/5/2014
14:43
0
0
0
0
20.9
25
6/5/2014
14:58
0
0
0
0
21
26
6/5/2014
15:13
0
0
0.3
0
20.9
27
6/5/2014
15:28
0
0
2.5
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 6, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-1
record (MASS)ug/m3 Temp
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
29
33.1
33.2
32.7
32
32.2
32.2
32.9
33.6
30.5
30.2
30.5
28.7
29.6
28.2
26.2
25.4
25.3
27.6
26
25
25.3
24
23
26.2
25.6
27.6
34.4
28.7
29.3
30.3
31.2
32.2
33
33.6
34.1
33.7
33.4
33.9
34.4
34.2
34.1
34.7
35.7
36.6
36.2
35.7
35.6
36.6
36.3
35.4
34.8
34.6
34.1
33.2
32.5
32
31.4
30.8
0 Data June
RHumidity
49
47
47
44
43
42
43
43
41
40
40
41
40
39
37
37
37
39
38
39
41
41
42
46
49
50
53
54
56
6,2014
Diameter
0.066
0.0688
0.0649
0.0649
0.0671
0.0654
0.0689
0.0723
0.0519
0.0508
0.0504
0.0419
0.0509
0.0419
0.0309
0.0291
0.0281
0.0413
0.0306
0.0287
0.0304
0.0286
0.028
0.0352
0.0327
0.0467
0.0812
0.054
0.0602
Time
11:15
11:30
11:45
12:00
12:15
12:30
12:45
13:00
13:15
13:30
13:45
14:00
14:15
14:30
14:45
15:00
15:15
15:30
15:45
16:00
16:15
16:30
16:45
17:00
17:15
17:30
17:45
18:00
18:15
Date
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
6-Jun-
1
-------
Particulate Air Monitoring Date Ellisville RV007
June 6, 2014
Ellisville (RV007) Down Wind PM-10 Data June 6, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
27.9
30.5
54
0.49
11:09:02
6-Jun-
2
30.6
30.1
53
0.5515
11:24:02
6-Jun-
3
32.2
29.9
54
0.5483
11:39:02
6-Jun-
4
33.3
29.8
54
0.5684
11:54:02
6-Jun-
5
34.6
29.8
54
0.5863
12:09:02
6-Jun-
6
35
29.9
53
0.5753
12:24:02
6-Jun-
7
35.7
29.8
54
0.5709
12:39:02
6-Jun-
8
35.5
29.8
53
0.5679
12:54:02
6-Jun-
9
31.7
29.9
52
0.5096
13:09:02
6-Jun-
10
31.9
30.2
50
0.5204
13:24:02
6-Jun-
11
31.8
30.5
49
0.5026
13:39:02
6-Jun-
12
30.6
30.4
50
0.509
13:54:02
6-Jun-
13
31.4
30.7
52
0.534
14:09:02
6-Jun-
14
31
31
52
0.5398
14:24:02
6-Jun-
15
30.3
31.2
52
0.5277
14:39:02
6-Jun-
16
29.5
31.4
52
0.5205
14:54:02
6-Jun-
17
28.3
31.7
51
0.5091
15:09:02
6-Jun-
18
28.9
31.7
52
0.513
15:24:02
6-Jun-
19
28.7
31.8
51
0.5121
15:39:02
6-Jun-
20
28.6
31.7
52
0.5165
15:54:02
6-Jun-
21
28.9
31.2
53
0.5229
16:09:02
6-Jun-
22
29.1
30.8
55
0.5429
16:24:02
6-Jun-
23
29
30.7
57
0.5661
16:39:02
6-Jun-
24
27
30.6
56
0.5355
16:54:02
6-Jun-
25
27.9
30
57
0.5866
17:09:02
6-Jun-
26
28.9
29.6
60
0.6244
17:24:02
6-Jun-
27
28.9
29.2
61
0.6277
17:39:02
6-Jun-
28
28.6
28.9
61
0.609
17:54:02
6-Jun-
29
29.5
28.5
62
0.6431
18:09:02
6-Jun-
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
2
-------
PID (VOC) results Ellisville (RV007)
June 6, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 6, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/6/2014
10:52
0
0
0
0
20.9
2
6/6/2014
11:07
0
0
0
0
20.9
3
6/6/2014
11:22
0
0
0
0
20.9
4
6/6/2014
11:37
0
0
0
0
20.9
5
6/6/2014
11:52
0
0
0
0
20.9
6
6/6/2014
12:07
0
0
0
0
20.9
7
6/6/2014
12:22
0
0
0
0
20.9
8
6/6/2014
12:37
0
0
0
0
20.9
9
6/6/2014
12:52
0
0
0
0
20.9
10
6/6/2014
13:07
0
0
0
0
20.9
11
6/6/2014
13:22
0
0
0
0
20.9
12
6/6/2014
13:37
0
0
0
0
20.9
13
6/6/2014
13:52
0
0
0
0
20.9
14
6/6/2014
14:07
0
0
0
0
20.9
15
6/6/2014
14:22
0
0
0
0
20.9
16
6/6/2014
14:37
0
0
0
0
20.9
17
6/6/2014
14:52
0
0
0
0
20.9
18
6/6/2014
15:07
0
0
0
0
20.9
19
6/6/2014
15:22
0
0
0
0
20.9
20
6/6/2014
15:37
0
0
0
0
20.9
21
6/6/2014
15:52
0
0
0
0
20.9
22
6/6/2014
16:07
0
0
0
0
20.9
23
6/6/2014
16:22
0
0
0
0
20.9
24
6/6/2014
16:37
0
0
0
0
20.9
25
6/6/2014
16:52
0
0
0
0
20.9
26
6/6/2014
17:07
0
0
0
0
20.9
27
6/6/2014
17:22
0
0
0
0
20.9
28
6/6/2014
17:37
0
0
0
0
20.9
29
6/6/2014
17:52
0
0
0
0
20.9
1
-------
PID (VOC) results Ellisville RV007
June 6, 2014
Ellisville (RV007) Down Wind PID Data June 6, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/6/2014
10:59
0.9
0
2.3
0
20.9
2
6/6/2014
11:14
1
0
2.9
0
20.9
3
6/6/2014
11:29
0.9
0
4.3
0
20.9
4
6/6/2014
11:44
0.9
0
5.1
0
20.9
5
6/6/2014
11:59
0.8
0
6.1
0
20.9
6
6/6/2014
12:14
0.8
0
4.2
0
21.2
7
6/6/2014
12:29
0.6
0
3.2
0
21.2
8
6/6/2014
12:44
0.4
0
2.6
0
21.1
9
6/6/2014
12:59
0.4
0
2.5
0
21.1
10
6/6/2014
13:14
0.4
0
2.5
0
21.2
11
6/6/2014
13:29
0.3
0
2
0
21.2
12
6/6/2014
13:44
0.2
0
1.8
0
21.2
13
6/6/2014
13:59
0.2
0
1.8
0
21.2
14
6/6/2014
14:14
0.2
0
1.8
0
21
15
6/6/2014
14:29
0.4
0
1.9
0
21.2
16
6/6/2014
14:44
0.3
0
1.2
0
21.2
17
6/6/2014
14:59
0.2
0
0.8
0
21.2
18
6/6/2014
15:14
0
0
0.9
0
21.2
19
6/6/2014
15:29
0.3
0
1.3
0
21.2
20
6/6/2014
15:44
0.2
0
0.5
0
21.2
21
6/6/2014
15:59
0.1
0
0.1
0
21.2
22
6/6/2014
16:14
0
0
0
0
21.2
23
6/6/2014
16:29
0
0
0
0
21.2
24
6/6/2014
16:44
0
0
0
0
21.2
25
6/6/2014
16:59
0
0
0
0
21.2
26
6/6/2014
17:14
0
0
0
0
21.1
27
6/6/2014
17:29
0
0
0
0
20.9
28
6/6/2014
17:44
0
0
0
0
20.9
29
6/6/2014
17:59
0
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 9, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-1
record (MASS)ug/m3 Temp
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
21
22
23
24
25
26
27
28
13.6
14.1
13.7
12.9
12.3
11.9
11.9
13.4
12.1
12
12.5
12.2
12.6
13.7
14.8
16.1
19.5
18.3
16.5
18.1
16.6
14.1
14.1
14.6
15.3
15.6
15.9
17.2
26
25.7
26.4
28.2
30.7
31.6
31
30.2
30.1
30.1
29.8
30.2
30.5
30.2
28.7
27.5
26.7
26.3
26.2
26.8
27
26.6
26.3
26.2
26.4
26.5
26.6
26.1
0 Data June
RHumidity
54
56
57
54
48
45
45
46
47
46
45
45
45
45
48
52
54
56
56
54
53
53
54
55
55
56
55
54
9,2014
Diameter
0.0284
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.028
0.0282
0.0295
0.028
0.028
0.0282
0.028
0.028
0.028
0.028
0.028
0.028
0.0307
Time
9:30
9:45
10:00
10:15
10:30
10:45
11:00
11:15
11:30
11:45
12:00
12:15
12:30
12:45
13:00
13:15
13:30
13:45
14:00
14:15
14:30
14:45
15:00
15:15
15:30
15:45
16:00
16:15
Date
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
9-Jun-
1
-------
Particulate Air Monitoring Date Ellisville RV007
June 9, 2014
Ellisville (RV007) Down Wind PM-10 Data June 9, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
14.4
25.6
57
0.5327
9:26:33
9-Jun-14
2
14.5
26.6
57
0.5672
9:41:33
9-Jun-14
3
14.3
27
56
0.512
9:56:33
9-Jun-14
4
14.6
27.2
56
0.5003
10:11:33
9-Jun-14
5
14.6
27.5
55
0.4977
10:26:33
9-Jun-14
6
14.2
27.5
56
0.4707
10:41:33
9-Jun-14
7
14
27.6
56
0.4615
10:56:33
9-Jun-14
8
14
27.6
55
0.4589
11:11:33
9-Jun-14
9
14
27.6
55
0.4585
11:26:33
9-Jun-14
10
13.5
27.6
53
0.4177
11:41:33
9-Jun-14
11
13.9
27.7
53
0.3905
11:56:33
9-Jun-14
12
14.5
28
53
0.4088
12:11:33
9-Jun-14
13
14.7
28.1
53
0.3821
12:26:33
9-Jun-14
14
15.9
27.9
53
0.3707
12:41:33
9-Jun-14
15
17.3
27.1
55
0.3762
12:56:33
9-Jun-14
16
18.1
26.2
59
0.3653
13:11:33
9-Jun-14
17
17.7
25.5
60
0.3726
13:26:33
9-Jun-14
18
17.4
25.1
60
0.3863
13:41:33
9-Jun-14
19
16.6
25
60
0.401
13:56:33
9-Jun-14
20
15.9
25.4
59
0.4042
14:11:33
9-Jun-14
21
15.8
25.5
58
0.3845
14:26:33
9-Jun-14
22
15.7
25.4
58
0.3836
14:41:33
9-Jun-14
23
16
25.2
58
0.3813
14:56:33
9-Jun-14
24
16.9
25.2
60
0.3789
15:11:33
9-Jun-14
25
17.7
25.2
61
0.382
15:26:33
9-Jun-14
26
17.8
25.3
60
0.3612
15:41:33
9-Jun-14
27
17.5
25.2
60
0.3622
15:56:33
9-Jun-14
28
16.9
24.9
57
0.3691
16:11:33
9-Jun-14
29
17.3
24.7
57
0.362
16:26:33
9-Jun-14
30
18.1
24.6
57
0.3504
16:41:33
9-Jun-14
2
-------
PID (VOC) results Ellisville (RV007)
June 9, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 9, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/9/2014 9:09
0
0
0
0
20.9
2
6/9/2014 9:24
0
0
0
0
20.9
3
6/9/2014 9:39
0
0
0
0
20.9
4
6/9/2014 9:54
0
0
0
0
20.9
5
6/9/2014
10:09
0
0
0
0
20.9
6
6/9/2014
10:24
0
0
0
0
20.9
7
6/9/2014
10:39
0
0
0
0
20.9
8
6/9/2014
10:54
0
0
0
0
20.9
9
6/9/2014
11:09
0
0
0
0
20.9
10
6/9/2014
11:24
0
0
0
0
20.9
11
6/9/2014
11:39
0
0
0
0
20.9
12
6/9/2014
11:54
0
0
0
0
20.9
13
6/9/2014
12:09
0
0
0
0
20.9
14
6/9/2014
12:24
0
0
0
0
20.9
15
6/9/2014
12:39
0
0
0
0
20.9
16
6/9/2014
12:54
0
0
0
0
20.9
17
6/9/2014
13:09
0
0
0
0
20.9
18
6/9/2014
13:24
0
0
0
0
20.9
19
6/9/2014
13:39
0
0
0
0
20.9
20
6/9/2014
13:54
0
0
0
0
20.9
21
6/9/2014
14:09
0
0
0
0
20.9
22
6/9/2014
14:24
0
0
0
0
20.9
23
6/9/2014
14:39
0
0
0
0
20.9
24
6/9/2014
14:54
0
0
0
0
20.9
25
6/9/2014
15:09
0
0
0
0
20.9
26
6/9/2014
15:24
0
0
0
0
20.9
27
6/9/2014
15:39
0
0
0
0
20.9
28
6/9/2014
15:54
0
0
0
0
20.9
29
6/9/2014
16:09
0
0
0
0
20.9
30
6/9/2014
16:24
0
0
0
0
20.9
1
-------
PID (VOC) results Ellisville RV007
June 9, 2014
Ellisville (RV007) Down Wind PID Data June 9, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/9/2014 9:07
0.9
0
1.1
0
20.7
2
6/9/2014 9:22
1.9
0
1.4
0
20.8
3
6/9/2014 9:37
0.5
0
1.8
0
20.8
4
6/9/2014 9:52
1.5
0
2.6
0
20.8
5
6/9/2014
10:07
1.8
0
4
0
20.8
6
6/9/2014
10:22
0.6
0
3.4
0
20.9
7
6/9/2014
10:37
0.3
0
2.1
0
20.9
8
6/9/2014
10:52
0.3
0
1.1
0
20.9
9
6/9/2014
11:07
0.1
0
0.6
0
20.9
10
6/9/2014
11:22
0.1
0
0.3
0
20.9
11
6/9/2014
11:37
0.1
0
0.1
0
20.9
12
6/9/2014
11:52
0
0
0.1
0
20.9
13
6/9/2014
12:07
0
0
0
0
20.9
14
6/9/2014
12:22
0
0
0
0
20.9
15
6/9/2014
12:37
0
0
0
0
20.9
16
6/9/2014
12:52
0
0
0
0
20.9
17
6/9/2014
13:07
0
0
0
0
20.9
18
6/9/2014
13:22
0
0
0
0
20.9
19
6/9/2014
13:37
0
0
0
0
20.9
20
6/9/2014
13:52
0
0
0
0
20.9
21
6/9/2014
14:07
0
0
0
0
20.9
22
6/9/2014
14:22
0
0
0
0
20.9
23
6/9/2014
14:37
0
0
0
0
20.9
24
6/9/2014
14:52
0
0
0
0
20.8
25
6/9/2014
15:07
0
0
0
0
20.8
26
6/9/2014
15:22
0
0
0
0
20.8
27
6/9/2014
15:37
0
0
0
0
20.9
28
6/9/2014
15:52
0
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 11, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data June 11, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
8.6
24.6
67
3.778
14:21:01
AM
11-Jun-14
2
8.9
25.1
67
3.9239
14:36:01
AM
11-Jun-14
3
6.4
25.2
66
3.698
14:51:01
AM
11-Jun-14
4
6.1
24.9
67
3.3233
15:06:01
AM
11-Jun-14
Ellisville (RV007) Down Wind PM-10 Data June 11, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
14.8
23.3
65
0.3609
13:51:53
11-Jun-14
2
18.5
22.9
69
0.3796
14:06:53
11-Jun-14
3
20
22.9
70
0.388
14:21:53
11-Jun-14
4
19.5
23.1
71
0.379
14:36:53
11-Jun-14
5
18.4
23.2
71
0.3734
14:51:53
11-Jun-14
6
17.7
23
71
0.3606
15:06:53
11-Jun-14
7
16.9
22.8
71
0.3482
15:21:53
11-Jun-14
-------
PID (VOC) results Ellisville (RV007)
June 11, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 11, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 6/11/2014 13:41 0 0.5 0 0 20.8
2 6/11/2014 13:56 0 0.4 0 0 21.1
3 6/11/2014 14:11 0 0.4 0 0 20.9
4 6/11/2014 14:26 0 0.3 0 0 20.9
5 6/11/2014 14:41 0 0.3 0 0 20.9
6 6/11/2014 14:56 0 0.3 0 0 20.9
7 6/11/2014 15:11 0 0.3 0 0 20.9
Ellisville (RV007) Down Wind PID Data June 11, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1 6/11/2014 13:34 0.4 0 0.1 0 20.9
2 6/11/2014 13:49 0.3 0 0 0 20.9
3 6/11/2014 14:04 0.2 0 0 0 20.9
4 6/11/2014 14:19 0.1 0 0 0 20.9
5 6/11/2014 14:34 0.1 0 0 0 20.9
6 6/11/2014 14:49 0.1 0 0 0 20.9
7 6/11/2014 15:04 0 0 0 0 20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 17, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
No upwind data due to equipment malfunction.
Ellisville (RV007) Down
Wind PM-10 Data June 17, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
104
25.8
71
2.034
13:13:47
17-Jun-14
2
107.6
27.8
72
1.8236
13:28:47
17-Jun-14
3
107.7
29.2
69
1.8094
13:43:47
17-Jun-14
4
106.7
30.6
65
1.7244
13:58:47
17-Jun-14
5
106
31.6
62
1.7314
14:13:47
17-Jun-14
6
107.9
32.1
59
1.7522
14:28:47
17-Jun-14
7
106.9
32.6
58
1.7883
14:43:47
17-Jun-14
8
106.4
32.9
56
1.6731
14:58:47
17-Jun-14
9
106.7
33.2
55
1.6412
15:13:47
17-Jun-14
10
106.8
33.2
54
1.6446
15:28:47
17-Jun-14
11
106.8
33.1
54
1.6466
15:43:47
17-Jun-14
12
107.1
33
54
1.6223
15:58:47
17-Jun-14
13
110
32.8
55
1.777
16:13:47
17-Jun-14
14
106.5
32.6
54
1.6646
16:28:47
17-Jun-14
-------
PID (VOC) results Ellisville (RV007)
June 17, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 17, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/17/2014
13:06
0.3
0
0
0
21
2
6/17/2014
13:21
0.2
0
0
0
21.2
3
6/17/2014
13:36
0.3
0
0
0
21.2
4
6/17/2014
13:51
0.2
0
0
0
21.2
5
6/17/2014
14:06
0.3
0
0
0
21.3
6
6/17/2014
14:21
0.3
0
0
0
21.3
7
6/17/2014
14:36
0.2
0
0
0
21.3
8
6/17/2014
14:51
0.2
0
0
0
21.4
9
6/17/2014
15:06
0.2
0
0
0
21.4
10
6/17/2014
15:21
0.1
0
0
0
21.4
11
6/17/2014
15:36
0.1
0
0
0
21.4
12
6/17/2014
15:51
0
0
0
0
21.4
13
6/17/2014
16:06
0
0
0
0
21.4
14
6/17/2014
16:21
0
0
0
0
21.4
Ellisville (RV007) Down Wind PID Data June 17, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/17/2014
12:59
0
0
0
0
20.9
2
6/17/2014
13:14
0
0
0
0
20.9
3
6/17/2014
13:29
0
0
0
0
20.9
4
6/17/2014
13:44
0
0
0
0
20.9
5
6/17/2014
13:59
0.1
0
0
0
20.9
6
6/17/2014
14:14
0.1
0
0
0
20.9
7
6/17/2014
14:29
0.1
0
0
0
20.9
8
6/17/2014
14:44
0.1
0
0
0
20.9
9
6/17/2014
14:59
0.1
0
0
0
20.9
10
6/17/2014
15:14
0.1
0
0
0
20.9
11
6/17/2014
15:29
0.1
0
0
0
20.9
12
6/17/2014
15:44
0
0
0
0
20.9
13
6/17/2014
15:59
0
0
0
0
20.9
14
6/17/2014
16:14
0
0
0
0
20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 18, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) UpWind PM-10 Data June 18, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
28.2
29.1
62
1.1087
13:24:03
18-Jun-14
2
27.9
30.8
63
1.0638
13:39:03
18-Jun-14
3
25.3
31.9
60
1.0223
13:54:03
18-Jun-14
4
36
32.6
59
1.0794
14:09:03
18-Jun-14
5
24.1
33.4
56
2.0458
14:24:03
18-Jun-14
6
36.9
33.8
54
1.3904
14:39:03
18-Jun-14
7
26.1
34.1
54
1.4371
14:54:03
18-Jun-14
8
18.4
34.5
52
0.8112
15:09:03
18-Jun-14
9
34.2
34.7
51
1.6171
15:24:03
18-Jun-14
10
21.2
34.7
50
1.0006
15:39:03
18-Jun-14
11
21.2
34.7
51
1.0085
15:54:03
18-Jun-14
Ellisville (RV007) Down Wind PM-10 Data June 18, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
28.2
29.1
62
1.1087
13:24:03
18-Jun-14
2
27.9
30.8
63
1.0638
13:39:03
18-Jun-14
3
25.3
31.9
60
1.0223
13:54:03
18-Jun-14
4
36
32.6
59
1.0794
14:09:03
18-Jun-14
5
24.1
33.4
56
2.0458
14:24:03
18-Jun-14
6
36.9
33.8
54
1.3904
14:39:03
18-Jun-14
7
26.1
34.1
54
1.4371
14:54:03
18-Jun-14
8
18.4
34.5
52
0.8112
15:09:03
18-Jun-14
9
34.2
34.7
51
1.6171
15:24:03
18-Jun-14
10
21.2
34.7
50
1.0006
15:39:03
18-Jun-14
11
21.2
34.7
51
1.0085
15:54:03
18-Jun-14
12
96.9
34.7
49
1.5521
16:07:54
18-Jun-14
-------
PID (VOC) results Ellisville (RV007)
June 18, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 18, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/18/2014 13:12
0
0
0.2
0
20.8
2
6/18/2014 13:27
0
0
0.7
0
20.8
3
6/18/2014 13:42
0
0
0.8
0
20.9
4
6/18/2014 13:57
0
0
0.7
0
20.9
5
6/18/2014 14:12
0
0
0.6
0
20.9
6
6/18/2014 14:27
0
0
0.4
0
20.9
7
6/18/2014 14:42
0
0
0.3
0
20.9
8
6/18/2014 14:57
0
0
0.1
0
20.9
9
6/18/2014 15:12
0
0
0
0
20.9
10
6/18/2014 15:27
0
0
0
0
20.9
11
6/18/2014 15:42
0
0
0
0
20.9
Ellisville (RV007) Down Wind PID Data June 18, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
6/18/2014 13:05
0
0
0
0
20.8
2
6/18/2014 13:20
0
0
0
0
20.9
3
6/18/2014 13:35
0.1
0
0
0
20.9
4
6/18/2014 13:50
0.1
0
0
0
20.9
5
6/18/2014 14:05
0.2
0
0
0
20.9
6
6/18/2014 14:20
0.2
0
0
0
20.9
7
6/18/2014 14:35
0.1
0
0
0
20.9
8
6/18/2014 14:50
0.1
0
0
0
20.9
9
6/18/2014 15:05
0.1
0
0
0
20.9
10
6/18/2014 15:20
0.1
0
0
0
20.9
11
6/18/2014 15:35
0.1
0
0
0
20.9
12
6/18/2014 15:50
0.1
0
0
0
20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 19, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) UpWind PM-10 Data June 19, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
28.2
29.1
62
1.1087
13:24:03
18-Jun-14
2
27.9
30.8
63
1.0638
13:39:03
18-Jun-14
3
25.3
31.9
60
1.0223
13:54:03
18-Jun-14
4
36
32.6
59
1.0794
14:09:03
18-Jun-14
5
24.1
33.4
56
2.0458
14:24:03
18-Jun-14
6
36.9
33.8
54
1.3904
14:39:03
18-Jun-14
7
26.1
34.1
54
1.4371
14:54:03
18-Jun-14
8
18.4
34.5
52
0.8112
15:09:03
18-Jun-14
9
34.2
34.7
51
1.6171
15:24:03
18-Jun-14
10
21.2
34.7
50
1.0006
15:39:03
18-Jun-14
11
21.2
34.7
51
1.0085
15:54:03
18-Jun-14
Ellisville (RV007) Down Wind PM-10 Data June 19, 2014
record (MASS )ug/m3 Temp RHumidity Diameter time Date
1 75 25.3 64 2.5041 16:33:09 19-Jun-14
2 102.8 27.6 65 2.0529 16:48:09 19-Jun-14
3 90.5 29.1 63 1.5434 17:03:09 19-Jun-14
4 91.7 30 63 1.5568 17:18:09 19-Jun-14
-------
PID (VOC) results Ellisville (RV007)
June 19, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
No up-wind data due to equipment malfunction.
Ellisville (RV007) Down Wind PID Data June 19, 2014
CO
VOC
H2S LEL OXY
Line# Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm (%) Alarm (%)
1 6/19/2014 16:21 0 0 0 0 20.9
2 6/19/2014 16:36 0 0 0 0 20.9
3 6/19/2014 16:51 0 0 0 0 20.9
4 6/19/2014 17:06 0 0 0 0 20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 20, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 20, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
6/20/2014 12:51
0
0
0
0
20.9
2
6/20/2014 13:06
0
0
0
0
20.9
3
6/20/2014 13:21
0
0
0
0
20.9
4
6/20/2014 13:36
0
0
0
0
20.9
5
6/20/2014 13:51
0
0
0
0
20.9
6
6/20/2014 14:06
0
0
0
0
20.9
7
6/20/2014 14:21
0
0
0
0
20.9
8
6/20/2014 14:36
0
0
0
0
20.9
9
6/20/2014 14:51
0
0
0
0
20.9
10
6/20/2014 15:06
0
0
0
0
20.9
11
6/20/2014 15:21
0
0
0
0
20.9
12
6/20/2014 15:36
0
0
0
0
20.9
13
6/20/2014 15:51
0
0
0
0
20.9
14
6/20/2014 16:06
0
0
0
0
20.9
15
6/20/2014 16:21
0
0
0
0
20.9
16
6/20/2014 16:36
0
0
0
0
20.9
17
6/20/2014 16:51
0
0
0
0
20.9
1
-------
Particulate Air Monitoring Date Ellisville RV007
June 20, 2014
Ellisville (RV007) Down Wind PID Data June 20, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
6/20/2014 12:58
0
0
0
0
20.8
2
6/20/2014 13:13
0
0
0
0
20.9
3
6/20/2014 13:28
0
0
0
0
20.9
4
6/20/2014 13:43
0
0
0
0
20.9
5
6/20/2014 13:58
0
0
0
0
20.9
6
6/20/2014 14:13
0
0
0
0
20.9
7
6/20/2014 14:28
0
0
0
0
20.9
8
6/20/2014 14:43
0
0
0
0
20.9
9
6/20/2014 14:58
0
0
0
0
20.9
10
6/20/2014 15:13
0
0
0
0
20.9
11
6/20/2014 15:28
0
0
0
0
20.9
12
6/20/2014 15:43
0
0
0
0
20.9
13
6/20/2014 15:58
0
0
0
0
20.9
14
6/20/2014 16:13
0
0
0
0
20.9
15
6/20/2014 16:28
0
0
0
0
20.9
16
6/20/2014 16:43
0
0
0
0
20.9
17
6/20/2014 16:58
0
0
0
0
20.9
2
-------
PID (VOC) results Ellisville (RV007)
June 20, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 20, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
6/20/2014 12:51
0
0
0
0
20.9
2
6/20/2014 13:06
0
0
0
0
20.9
3
6/20/2014 13:21
0
0
0
0
20.9
4
6/20/2014 13:36
0
0
0
0
20.9
5
6/20/2014 13:51
0
0
0
0
20.9
6
6/20/2014 14:06
0
0
0
0
20.9
7
6/20/2014 14:21
0
0
0
0
20.9
8
6/20/2014 14:36
0
0
0
0
20.9
9
6/20/2014 14:51
0
0
0
0
20.9
10
6/20/2014 15:06
0
0
0
0
20.9
11
6/20/2014 15:21
0
0
0
0
20.9
12
6/20/2014 15:36
0
0
0
0
20.9
13
6/20/2014 15:51
0
0
0
0
20.9
14
6/20/2014 16:06
0
0
0
0
20.9
15
6/20/2014 16:21
0
0
0
0
20.9
16
6/20/2014 16:36
0
0
0
0
20.9
17
6/20/2014 16:51
0
0
0
0
20.9
1
-------
PID (VOC) results Ellisville RV007
June 20, 2014
Ellisville (RV007) Down Wind PID Data June 20, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
6/20/2014 12:58
0
0
0
0
20.8
2
6/20/2014 13:13
0
0
0
0
20.9
3
6/20/2014 13:28
0
0
0
0
20.9
4
6/20/2014 13:43
0
0
0
0
20.9
5
6/20/2014 13:58
0
0
0
0
20.9
6
6/20/2014 14:13
0
0
0
0
20.9
7
6/20/2014 14:28
0
0
0
0
20.9
8
6/20/2014 14:43
0
0
0
0
20.9
9
6/20/2014 14:58
0
0
0
0
20.9
10
6/20/2014 15:13
0
0
0
0
20.9
11
6/20/2014 15:28
0
0
0
0
20.9
12
6/20/2014 15:43
0
0
0
0
20.9
13
6/20/2014 15:58
0
0
0
0
20.9
14
6/20/2014 16:13
0
0
0
0
20.9
15
6/20/2014 16:28
0
0
0
0
20.9
16
6/20/2014 16:43
0
0
0
0
20.9
17
6/20/2014 16:58
0
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
June 24, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
No Upwind Data Captured
Ellisville (RV007) Down
record (MASS )ug/m3
1
2
3
4
5
6
7
8
9
10
11
12
13
14
15
16
17
18
19
20
19
28.9
29.4
29.2
29.1
28.8
27.6
27.4
27.1
26.4
26.6
26.6
26.6
26.1
25.7
24.8
24.6
23.9
24
23.6
wind Wind PM-10 Data June 24
Temp RHumidity Diameter
69
25.8
26.3
26.6
27.2
27.5
27.9
28.2
28.6
28.8
29.1
29.4
29.5
29.3
29.4
29.7
29.9
30.1
30.3
30.5
30.5
72
72
71
69
69
67
65
63
62
61
62
62
62
62
58
56
55
53
53
0.5203
0.433
0.4346
0.4299
0.4255
0.4201
0.4108
0.41
0.4065
0.393
0.401
0.3848
0.3941
0.3901
0.3877
0.3847
0.3798
0.3779
0.3883
0.378
, 2014
Time
10:28
10:43
10:58
11:13
11:28
11:43
11:58
12:13
12:28
12:43
12:58
13:13
13:28
13:43
13:58
14:13
14:28
14:43
14:58
15:13
Date
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
24-Jun-14
-------
PID (VOC) results Ellisville (RV007)
June 24, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data June 24, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
6/24/2014 10:11
0
0
0
0
20.9
2
6/24/2014 10:26
0
0
0.1
0
20.9
3
6/24/2014 10:41
0
0
0
0
20.9
4
6/24/2014 10:56
0
0
0
0
21
5
6/24/2014 11:11
0
0
0
0
21.1
6
6/24/2014 11:26
0
0
0
0
21.2
7
6/24/2014 11:41
0
0
0
0
21.1
8
6/24/2014 11:56
0
0
0
0
20.9
9
6/24/2014 12:11
0
0
0
0
20.9
10
6/24/2014 12:26
0
0
0
0
21.1
11
6/24/2014 12:41
0
0
0
0
21.1
12
6/24/2014 12:56
0
0
0
0
21.1
13
6/24/2014 13:11
0
0
0
0
21.1
14
6/24/2014 13:26
0
0
0
0
21.1
15
6/24/2014 13:41
0
0
0
0
21.1
16
6/24/2014 13:56
0
0
0
0
21.1
17
6/24/2014 14:11
0
0
0
0
21.1
18
6/24/2014 14:26
0
0
0
0
21.1
19
6/24/2014 14:41
0
0
0
0
21.2
20
6/24/2014 14:56
0
0
0
0
21.2
21
6/24/2014 15:11
0
0
0
0
21.2
1
-------
PID (VOC) results Ellisville RV007
June 24, 2014
Ellisville (RV007) Down Wind PID Data June 24, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%)
1
6/24/2014 10:10
0.3
0
0
0
20.9
2
6/24/2014 10:25
0.2
0
0
0
20.9
3
6/24/2014 10:40
0.2
0
0
0
20.9
4
6/24/2014 10:55
0.1
0
0
0
20.9
5
6/24/2014 11:10
0.1
0
0
0
20.9
6
6/24/2014 11:25
0.1
0
0
0
20.9
7
6/24/2014 11:40
0
0
0
0
20.9
8
6/24/2014 11:55
0
0
0
0
20.9
9
6/24/2014 12:10
0
0
0
0
20.9
10
6/24/2014 12:25
0
0
0
0
20.9
11
6/24/2014 12:40
0
0
0
0
20.9
12
6/24/2014 12:55
0
0
0
0
20.9
13
6/24/2014 13:10
0
0
0
0
20.9
14
6/24/2014 13:25
0.1
0
0
0
20.9
15
6/24/2014 13:40
0.1
0
0
0
20.9
16
6/24/2014 13:55
0.1
0
0
0
20.9
17
6/24/2014 14:10
0.1
0
0
0
20.9
18
6/24/2014 14:25
0.1
0
0
0
20.9
19
6/24/2014 14:40
0.1
0
0
0
20.9
20
6/24/2014 14:55
0.1
0
0
0
20.9
21
6/24/2014 15:10
0.1
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
July 8, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data July 8, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
1
21.8
26
67
0.321
11:04:26
8-Jul-14
2
27.2
26.9
67
0.3386
11:19:26
8-Jul-14
3
29.3
28.1
65
0.3374
11:34:26
8-Jul-14
4
29.7
29
62
0.3337
11:49:26
8-Jul-14
5
30
29.4
61
0.3295
12:04:26
8-Jul-14
6
30.3
29.7
60
0.3265
12:19:26
8-Jul-14
7
30.9
29.7
59
0.3305
12:34:26
8-Jul-14
8
34
29.8
58
0.3394
12:49:26
8-Jul-14
9
31.7
30
58
0.3333
13:04:26
8-Jul-14
10
30.7
30.1
56
0.3254
13:19:26
8-Jul-14
11
30.5
30.2
55
0.3214
13:34:26
8-Jul-14
12
30.4
30.2
52
0.3242
13:49:26
8-Jul-14
13
30.4
30
52
0.3196
14:04:26
8-Jul-14
14
30.4
30
52
0.3167
14:19:26
8-Jul-14
15
30.4
30.1
51
0.3157
14:34:26
8-Jul-14
16
30.3
30.2
52
0.3153
14:49:26
8-Jul-14
17
30.7
30.3
51
0.3133
15:04:26
8-Jul-14
18
31.2
30.3
51
0.3157
15:19:26
8-Jul-14
19
31.2
30.3
51
0.3111
15:34:26
8-Jul-14
1
-------
Particulate Air Monitoring Date Ellisville RV007
July 8, 2014
Ellisville (RV007) Down wind Wind PM-10 Data July 8, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
1
4.8
25.8
66
0.4353
10:51:07
8-Jul
2
5.5
27.9
65
0.5805
11:06:07
8-Jul
3
4.5
30.3
61
0.4036
11:21:07
8-Jul
4
4.7
33.2
54
0.4157
11:36:07
8-Jul
5
4.1
34.3
50
0.3909
11:51:07
8-Jul
6
4.4
34.4
49
0.3888
12:06:07
8-Jul
7
4.6
34.3
48
0.3868
12:21:07
8-Jul
8
4.9
33.7
49
0.386
12:36:07
8-Jul
9
7.7
33.6
49
0.4288
12:51:07
8-Jul
10
5.7
33
49
0.4192
13:06:07
8-Jul
11
4.9
32.5
50
0.3684
13:21:07
8-Jul
12
4.5
32
50
0.3649
13:36:07
8-Jul
13
5
31.6
49
0.3797
13:51:07
8-Jul
14
4.7
31.4
49
0.3655
14:06:07
8-Jul
15
4.6
31.3
50
0.3662
14:21:07
8-Jul
16
4.8
31.3
50
0.3506
14:36:07
8-Jul
17
4.7
31.4
50
0.3533
14:51:07
8-Jul
18
5.9
31.3
50
0.3631
15:06:07
8-Jul
19
5.4
31.2
50
0.3183
15:21:07
8-Jul
20
5.4
31.4
50
0.3224
15:36:07
8-Jul
2
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
4
-------
PID (VOC) results Ellisville (RV007)
July 8, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data July 8, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%) Alarm
1
7/8/2014
10:38
0
0
0
0
20.9
2
7/8/2014
10:53
0
0
0
0
20.9
3
7/8/2014
11:08
0
0
0
0
20.9
4
7/8/2014
11:23
0
0
0
0
20.9
5
7/8/2014
11:38
0
0
0
0
20.9
6
7/8/2014
11:53
0
0
0
0
20.9
7
7/8/2014
12:08
0
0
0
0
20.9
8
7/8/2014
12:23
0
0
0
0
20.9
9
7/8/2014
12:38
0
0
0
0
20.9
10
7/8/2014
12:53
0
0
0
0
20.9
11
7/8/2014
13:08
0
0
0
0
20.9
12
7/8/2014
13:23
0
0
0
0
20.9
13
7/8/2014
13:38
0
0
0
0
20.9
14
7/8/2014
13:53
0
0
0
0
20.9
15
7/8/2014
14:08
0
0
0
0
20.9
16
7/8/2014
14:23
0
0
0
0
20.9
17
7/8/2014
14:38
0
0
0
0
20.9
18
7/8/2014
14:53
0
0
0
0
20.9
19
7/8/2014
15:08
0
0
0
0
20.9
20
7/8/2014
15:23
0
0
0
0
20.9
1
-------
PID (VOC) results Ellisville RV007
July 8, 2014
Ellisville (RV007) Down Wind PID Data July 8, 2014
CO
VOC
H2S
LEL
OXY
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
(%) Alarm
1
7/8/2014
10:56
0
0.2
0
0
20.9
2
7/8/2014
11:11
0
0
0
0
20.8
3
7/8/2014
11:26
0
0
0.7
0
20.8
4
7/8/2014
11:41
0
0
0.5
0
20.9
5
7/8/2014
11:56
0
0
0.1
0
20.9
6
7/8/2014
12:11
0
0
0
0
21
7
7/8/2014
12:26
0
0
0
0
21
8
7/8/2014
12:41
0
0
0
0
21.1
9
7/8/2014
12:56
0
0
0
0
21
10
7/8/2014
13:11
0
0
0
0
20.9
11
7/8/2014
13:26
0
0
0
0
20.9
12
7/8/2014
13:41
0
0
0
0
20.9
13
7/8/2014
13:56
0
0
0
0
20.9
14
7/8/2014
14:11
0
0
0
0
20.9
15
7/8/2014
14:26
0
0
0
0
20.9
16
7/8/2014
14:41
0
0
0
0
20.9
17
7/8/2014
14:56
0
0
0
0
20.9
18
7/8/2014
15:11
0
0
0
0
20.9
19
7/8/2014
15:26
0
0
0
0
20.9
2
-------
Particulate Air Monitoring Data Ellisville (RV007)
July 16, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data July 16, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
25.1
25.6
44
0.773
13:15
15
16-Jul-14
2
25.6
25.7
42
0.7551
13:30
15
16-Jul-14
3
23.8
25.8
42
0.7915
13:45
15
16-Jul-14
4
22.2
25.7
41
0.7496
14:00
15
16-Jul-14
5
22.1
25.7
42
0.6885
14:15
15
16-Jul-14
6
21.2
25.7
42
0.6865
14:30
15
16-Jul-14
7
25.1
25.7
42
0.7915
14:45
15
16-Jul-14
8
24.8
26
41
0.7107
15:00
15
16-Jul-14
9
22.4
25.8
42
0.6842
15:15
15
16-Jul-14
10
23.8
25.6
41
0.6978
15:30
15
16-Jul-14
11
21
25.5
42
0.6687
15:45
15
16-Jul-14
12
21.6
25.7
42
0.6864
16:00
15
16-Jul-14
13
21.7
25.7
42
0.6787
16:15
15
16-Jul-14
14
22.1
25.6
42
0.7157
16:30
15
16-Jul-14
Ellisville (RV007) Down Wind PM-10 Data July 16, 2014
record (MASS )ug/m3 Temp RHumidity Diameter
1
2
3
4
5
6
7
8
9
10
11
12
13
14
5.9
5.7
5.4
7.5
5.8
5.6
6
6.6
5.8
5.1
5.2
5.4
5.5
5.2
27
27.2
27.4
27.5
27.7
27.7
27.8
27.9
27.7
27.7
27.7
27.9
28.1
28.3
44
42
42
41
41
41
41
41
41
40
41
42
41
40
0.5604
0.5213
0.4861
0.7905
0.6216
0.5524
0.5809
0.5658
0.5592
0.4696
0.4658
0.5307
0.5518
0.5156
Time
13:17
13:32
13:47
14:02
14:17
14:32
14:47
15:02
15:17
15:32
15:47
16:02
16:17
16:32
Date
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
16-Jul-14
-------
PID (VOC) results Ellisville (RV007)
July 16, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data July 16, 2014
CO VOC H2S LEL
Line#
Date Time
(ppm) Alarm
(ppm) Alarm
(ppm) Alarm
(%) Alarm
OXY (%)
1
7/16/2014 12:58
0
0
0
0
20.9
2
7/16/2014 13:13
0
0
0
0
20.9
3
7/16/2014 13:28
0
0
0
0
20.9
4
7/16/2014 13:43
0
0
0
0
20.9
5
7/16/2014 13:58
0
0
0
0
20.9
6
7/16/2014 14:13
0
0
0
0
20.9
7
7/16/2014 14:28
0
0
0
0
20.9
8
7/16/2014 14:43
0
0
0
0
20.9
9
7/16/2014 14:58
0
0
0
0
20.9
10
7/16/2014 15:13
0
0
0
0
20.9
11
7/16/2014 15:28
0
0
0
0
20.9
12
7/16/2014 15:43
0
0
0
0
20.9
13
7/16/2014 15:58
0
0
0
0
20.9
14
7/16/2014 16:13
0
0
0
0
20.9
Ellisville (RV007) Down Wind PID Data July 16, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
7/16/2014 13:07
0
0.3
0
0
20.9
2
7/16/2014 13:22
0
0.2
0
0
20.9
3
7/16/2014 13:37
0
0.2
0
0
20.9
4
7/16/2014 13:52
0
0.1
0
0
20.9
5
7/16/2014 14:07
0
0.1
0
0
20.9
6
7/16/2014 14:22
0
0.1
0
0
20.9
7
7/16/2014 14:37
0
0.1
0
0
20.9
8
7/16/2014 14:52
0
0.1
0
0
20.9
9
7/16/2014 15:07
0
0.1
0
0
20.9
10
7/16/2014 15:22
0
0.1
0
0
20.9
11
7/16/2014 15:37
0
0.1
0
0
20.9
12
7/16/2014 15:52
0
0.1
0
0
20.9
13
7/16/2014 16:07
0
0.1
0
0
20.9
-------
Particulate Air Monitoring Data Ellisville (RV007)
July 17, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data July 17, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
6.4
-13.2
36
0.3912
14:03:00
17-Jul-14
2
6.3
-13.2
35
0.3989
14:18:00
17-Jul-14
3
8
-13.2
35
0.5277
14:33:00
17-Jul-14
4
11.9
-13.1
35
0.9344
14:48:00
17-Jul-14
5
6.2
-13.2
35
0.3771
15:03:00
17-Jul-14
6
7.6
-13.2
36
0.4877
15:18:00
17-Jul-14
7
7.9
-13.2
37
0.568
15:33:00
17-Jul-14
8
6.7
-13.2
37
0.4235
15:48:00
17-Jul-14
9
24.6
-12.6
37
1.1943
16:03:00
17-Jul-14
10
35.6
-12
37
1.3054
16:18:00
17-Jul-14
11
22.2
-12.7
37
0.8499
16:33:00
17-Jul-14
Ellisville (RV007) Down
Wind PM-10 Data July 17, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
23.1
25.7
43
0.6309
13:50
10
17-Jul-14
2
24
26.6
42
0.6184
14:05
10
17-Jul-14
3
69
27.1
41
1.3042
14:20
10
17-Jul-14
4
29.2
27.3
42
0.8993
14:35
10
17-Jul-14
5
22.5
27.5
41
0.6111
14:50
10
17-Jul-14
6
22
27.6
40
0.5955
15:05
10
17-Jul-14
7
22.2
27.6
42
0.59
15:20
10
17-Jul-14
8
22
27.5
42
0.6044
15:35
10
17-Jul-14
9
22.1
27.5
42
0.6008
15:50
10
17-Jul-14
10
21.9
27.5
42
0.5913
16:05
10
17-Jul-14
11
22.2
27.5
42
0.6065
16:20
10
17-Jul-14
12
22.4
27.5
43
0.749
16:35
10
17-Jul-14
-------
PID (VOC) results Ellisville (RV007)
July 17, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data July 17, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
7/17/2014 13:41
0.7
0.2
0
0
20.9
2
7/17/2014 13:56
0.7
0.1
0.1
0
20.9
3
7/17/2014 14:11
0.5
0.1
0.1
0
20.9
4
7/17/2014 14:26
0.4
0.1
0
0
20.9
5
7/17/2014 14:41
0.2
0.1
0
0
20.9
6
7/17/2014 14:56
0.1
0
0
0
20.9
7
7/17/2014 15:11
0.1
0
0
0
20.9
8
7/17/2014 15:26
0
0
0
0
20.9
9
7/17/2014 15:41
0
0
0
0
20.9
10
7/17/2014 15:56
0
0
0
0
20.9
11
7/17/2014 16:11
0
0
0
0
20.9
Ellisville (RV007) Down Wind PID Data July 17, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
7/17/2014 13:33
0.1
0
0
0
20.9
2
7/17/2014 13:48
0.1
0
0
0
20.9
3
7/17/2014 14:03
0.1
0
0
0
20.9
4
7/17/2014 14:18
0
0
0
0
20.9
5
7/17/2014 14:33
0
0
0
0
21.1
6
7/17/2014 14:48
0
0
0
0
21.1
7
7/17/2014 15:03
0
0
0
0
21.2
8
7/17/2014 15:18
0
0
0
0
21.2
9
7/17/2014 15:33
0
0
0
0
21.2
10
7/17/2014 15:48
0
0
0
0
21.2
11
7/17/2014 16:03
0
0
0
0
21.2
12
7/17/2014 16:18
0
0
0
0
21.2
-------
Particulate Air Monitoring Data Ellisville (RV007)
July 21, 2014
The data provided in the following tables is raw data downloaded from particulate air
monitoring instruments positioned near the work zone at Ellisville (RV007). The
instruments measure PM10 or particulate matter of 10 micrometers or less which is
considered respirable (able to be taken in the body by breathing). A potential source of
PM10 at the site is dust from construction activities. Other sources include diesel
emissions from equipment operating at the site, mold spores, smoke, smog, soot, etc.
Air monitoring stations are set up-wind of the work zone to record background
particulate data and down-wind of the work zone to record particulate data influenced by
work activities. Data is collected while crews are active in the work zone.
Ellisville (RV007) Up Wind PM-10 Data July 21, 2014
record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
35.4
27.7
54
2.1258
13:54:48
21 -Jul-14
2
39.5
29.6
51
0.3848
14:09:48
21 -Jul-14
3
39.6
30.9
48
0.3964
14:24:48
21 -Jul-14
4
38.6
31.6
47
0.3931
14:39:48
21 -Jul-14
5
39
32.1
45
0.4032
14:54:48
21 -Jul-14
6
38.6
32.3
45
0.3943
15:09:48
21 -Jul-14
7
38.4
32.4
44
0.3874
15:24:48
21 -Jul-14
8
40.3
32.5
43
0.4135
15:39:48
21 -Jul-14
9
39.3
32.6
43
0.3945
15:54:48
21 -Jul-14
10
39.5
32.8
43
0.3953
16:09:48
21 -Jul-14
11
46.4
33
43
0.5016
16:24:48
21 -Jul-14
12
39.3
33
43
0.3972
16:39:48
21 -Jul-14
Ellisville (RV007) Down Wind PM-10 Data July
21, 2014
Record
(MASS )ug/m3
Temp
RHumidity
Diameter
Time
Date
1
40.5
27.8
55
0.3615
13:50:24
21 -Jul-14
2
33.1
30
52
0.3127
14:05:24
21 -Jul-14
3
78.4
31.4
48
0.617
14:20:24
21 -Jul-14
4
30.8
32.2
47
0.3248
14:35:24
21 -Jul-14
5
59.4
32.8
45
0.6796
14:50:24
21 -Jul-14
6
449
33.3
44
1.7173
15:05:24
21 -Jul-14
7
42.1
33.4
43
0.4481
15:20:24
21 -Jul-14
8
97.4
33.5
43
0.7167
15:35:24
21 -Jul-14
9
53
33.5
43
0.6017
15:50:24
21 -Jul-14
10
38.1
33.4
43
0.351
16:05:24
21 -Jul-14
11
227.9
33.4
44
1.6586
16:20:24
21 -Jul-14
12
40.4
33.4
43
0.4612
16:35:24
21 -Jul-14
-------
PID (VOC) results Ellisville (RV007)
July 21, 2014
The data provided in the following tables is raw data downloaded from photo-ionization
detectors or PID's positioned near the work zone at Ellisville (RV007). The PID's are
being used at the site to monitor for volatile substances (VOC's), or substances that easily
evaporate at normal temperatures. In addition these instruments have sensors that detect
Oxygen, Carbon Monoxide, Hydrogen Sulfide and Lower Explosive Limit (LEL).
There are no known sources of contamination at the site that would result in volatile off-
gassing. Construction activities will result in variability of this data. For example when
diesel exhaust is present, VOC levels will temporarily elevate and Oxygen levels will
temporarily decrease.
Air monitoring stations are set up-wind of the work zone to record background VOC data
and down-wind of the work zone to record VOC data after it has passed through the work
zone. Air monitoring is conducted wile crews are active in the work zone.
Ellisville (RV007) Upwind PID Data July 21, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
7/21/2014 13:37
0
0
0.4
0
20.9
2
7/21/2014 13:52
0
0
0.4
0
20.9
3
7/21/2014 14:07
0
0
0.3
0
20.9
4
7/21/2014 14:22
0
0
0.3
0
20.9
5
7/21/2014 14:37
0
0
0.2
0
20.9
6
7/21/2014 14:52
0
0
0.2
0
20.9
7
7/21/2014 15:07
0
0
0.1
0
20.9
8
7/21/2014 15:22
0
0
0.1
0
20.9
9
7/21/2014 15:37
0
0
0.1
0
20.9
10
7/21/2014 15:52
0
0
0.1
0
20.9
11
7/21/2014 16:07
0
0
0.1
0
20.9
12
7/21/2014 16:22
0
0
0
0
20.9
Ellisville (RV007) Down Wind PID Data July 21, 2014
CO VOC H2S LEL OXY
Line# Date Time (ppm) Alarm (ppm) Alarm (ppm) Alarm (%) Alarm (%) Alarm
1
7/21/2014 13:39
0
0.1
0
0
20.9
2
7/21/2014 13:54
0
0
0
0
20.9
3
7/21/2014 14:09
0
0
0
0
20.9
4
7/21/2014 14:24
0
0
0
0
20.9
5
7/21/2014 14:39
0
0
0
0
20.9
6
7/21/2014 14:54
0
0
0
0
20.9
7
7/21/2014 15:09
0
0
0
0
20.9
8
7/21/2014 15:24
0
0
0
0
20.9
9
7/21/2014 15:39
0
0
0
0
20.9
10
7/21/2014 15:54
0
0
0
0
20.9
11
7/21/2014 16:09
0
0
0
0
20.9
12
7/21/2014 16:24
0
0
0
0
20.9
-------
MEMORANDUM
SUBJECT: Ellisville (RV007) Air Monitoring Data SSID:0708
FROM: J. Heath Smith, OSC
ERSB/SUPR
TO: Site File
RE: Air Monitoring Data
This document consists of air monitoring data packages generated during the 2014
Ellisville removal action (RV007). The data packages were generated from real time
insturments and provided at http://www.epaosc.net/ellisville for public awareness.
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