-------
LIST OF ACRONYMS (CONTINUED)

Acronym	1 Definition

Sis	site inspections

SOPs	standard operating procedures

SQAP	sampling and quality assurance plan

SQL	sample quantitation limit

SVOCs	semivolatile organic compounds

START	Superfund Technical Assessment and Response Team

TAL	target analyte list

TDD	Technical Direction Document

TM	Task Monitor

TOC	total organic carbon

USFS	United States Forest Service

Weston	Roy F. Weston, Inc.

XRF	X-ray fluorescence

10:START-2\01080009NS714

xii

-------
0012

LOWER PEND OREILLE RIVER
MINES AND MILLS
PRELIMINARY ASSESSMENTS AND SITE INVESTIGATIONS REPORT
PEND OREILLE COUNTY, WASHINGTON

1. INTRODUCTION

The United States Environmental Protection Agency (EPA) has tasked Ecology and
Environment, Inc. (E & E) to provide technical support in investigating potential contaminant sources to
the lower reach of the Pend Oreille River. Comprehensive Environmental Response, Compensation and
Liability Act (CERCLA) activities included preliminary assessments (PAs) and site investigations (Sis)
for 21 mines/mills located near the lower reach of the Pend Oreille River in Pend Oreille County,
Washington. The PAs and Sis were conducted under the authority of CERCLA of 1980 as amended by
the Superfund Amendments and Reauthorization Act of 1986. Of the 21 mines and mills investigated,
those identified by The Confederated Tribes of the Colville Indian Reservation to the EPA for assessment
under CERCLA include the Pend Oreille Mine/Mill, Grandview Mine/Mill, Josephine Mine, Blue
Bucket Mine, Bella May Mine, West Contact Mine and Metaline Mine (Cawston 1999; Passmore 2000).
The remaining 16 mines visited were identified by EPA based on the mine/mill location relative to
tributaries to the Pend Oreille River and available information regarding volume of or produced. A list
of the 21 mines and mills visited as part of this field event are presented in Table 1-1. The lower reach of
the Pend Oreille River is defined for this assessment as the segment of the river beginning at
approximately Metaline and ending at Boundary Dam near the International Border (Figures 1-1 and 1-
2).

CERCLA PA and SI activities were conducted at 21 mine/mill facilities and tributaries (e.g.,
creeks and streams) near these facilities that empty into the lower reach (as defined above) of the Pend
Oreille River.

The PA and SI are phases in the site assessment process of determining whether a site is
releasing, or has the potential to release, hazardous substances, pollutants, or contaminants into the
environment and whether it requires further detailed investigations and/or response action that is
authorized by CERCLA. The assessment process does not include extensive or complete site
characterization, contaminant fate determination, or quantitative risk assessment.'

10:START-2\01080009\S714

1-1

-------
0013

The objectives of the PAs and Sis are to:

*	Identify potential contaminant sources to the lower reach of the Pend Oreille River;

*	Determine whether the mine or mill is releasing, or has the potential to release hazardous
constituents into the environment;

*	Document a threat or potential threat to public health or the environment posed by the
mine or mill;

*	Assess the need for additional detailed investigation and/or response action at the mine
or mill; and

*	Determine the potential for placement of the mine or mill on the National Priorities List.

U-

The PA and SI field activities were conducted through a combined effort involving Superfund
Technical Assessment and Response Team (START) -2 contractor firms, E & E and Roy F, Weston, Inc.
(Weston). E & E conducted sampling activities along the lower reach of the Pend Oreille River, a
number of its tributaries, and mines and mills where potential contaminant sources were identified.
E & E activities were conducted under START-2 contract No. 68-SO-Ol-Ol and Technical Direction
Document (TDD) No. 01-02-0028. Weston collected mine/mill-specific background samples as
determined necessary by the EPA. Weston activities were conducted under START-2 contract No.

68-S0-O1-O2 and TDD No. 01-02-0001-A.

Activities conducted as part of this assessment include reviewing existing mine/mili-specific
information, regional characteristics, collecting receptor information within the mine or mill's range of

i

influence, conducting mine/mill visits, executing the sampling plan, and producing this report.

In accordance with the SQAP, attempts were made to conduct in-situ field screening of metals
concentrations at potential contaminant sources using X-Ray Fluorescence (XRF) equipment. Due to
field conditions, the instruments exceeded operating temperatures on several occasions. It was
determined that the equipment was not able to function properly in a high temperature environment and
its use was discontinued. A memo presenting the results of the limited XRF screening conducted is
included in Appendix D.

Section 2 of this document includes a discussion of the area and regional characteristics. Section
3 provides a description of the PA and SI field activities conducted by the START-2 E & E and Weston
in coordination with Washington State Department of Ecology (Ecology), Bureau of Land Management
(BLM), and the United States Forest Service (USFS) staff. Quality assurance/quality control (QA/QC)
criteria are included in Section 4. Reporting criteria, reporting methods, and background sample
analytical results are discussed in Section 5. Mine and mill locations, descriptions, and START-2 visits

10:START-2\01080009VS714

1-2

-------
0014

are discussed in Section 6, Section 7 provides a discussion of the potential sources, surface water
migration pathways, targets, and corresponding EPA Contract Laboratory Program (CLP) and
subcontracted laboratory sampling results. PA and SI findings and recommendations are summarized in
Section 5. Photographic documentation are provided in Appendix A. Global positioning system (GPS)
coordinates are provided in Appendix B. Copies of the START-2 logbooks are provided in Appendix C,
Data quality assurance review memorandums and analytical data forms are provided in Appendix D. The
data for the samples collected at Myers Dam and the Metaline Falls municipal water intake are provided
in Appendices E and F, respectively. The trip report prepared by Weston is provided in Appendix G.

10:START-2\01080009\S714

1-3

-------
Table 1-1

MINES AND MILLS

LOWER PEND OREILLE RIVER MINES AND MILLS PRELIMINARY ASSESSMENTS AND SITE

PEND OREILLE COUNTY, WASHINGTON

Mine/Mill Name

Mine/Mill

LAT

LONG

S

T

R

River System(s)

Red Top

Mine

48

59

52.08

117

11 .

02.76

1,2

40N

44E

Overland, Lead Creek, Canada

King Tut

Mine

48

59

21.48

117

11

28.32

2,11

40N

44E

Overland, Unnamed Tributary, Canada

Lead Hill

Mine

48

58

12.72

117

11

49.56

11, 12,13,14,
22,23,27

40N

44E

Slate Creek, Pend Oreille River (5 miles south of B

Lead Queen

Mine

48

58

46.56

117

19

37.20

11

40N

43 E

Overland (1 mile), Pend Oreille River (1,000 ft nort

Z Canyon

Mine

48

58

41.52

117

20

34.08

11

40N

43E

Overland (1,400 ft), Pend Oreille River (2,500 ft no

Lead King

Mine

48

56

16.44

117

21

13.32

27

40N

43E

Lower Lead King Lake, Everett Creek

Lucky Strike

Mine

48

55

49.80

117

19

51.24

35

40N

43E

Overland (800 ft), Pend Oreille River (4 miles south

Hoage

Mine

48

56

57.48

117

21

18.00

22

40N

43E

Upper Lead King Lake, Lower Lead King Lake, Ev<

Yellowhead

Mine

48

52

59.88

117

22

14,16

16

39N

43E

Overland (1,000 ft), Pend Oreille River (8 miles sou

Grand view

Mine/Mill

48

52

22.04

117

21

26.16

14,15,22,30

39N

43E

Overland, Pend Oreille River (9 miles south fo Bou

Pend Oreille

Mine/Mill

48

52

54.12

117

21

36.00

10,11,14,15

39N

43E

Overland, Pend Oreille River (9 miles south fo Bou

Josephine

Mine

48

52

48.00

117

22

15.96

16

39N

43E

Overland, Pend Oreille River (9 miles south fo Bou

Oriole

Mine

48

51

36.72

117

24

46.44

19

39N

43E

Linton Creek, Pend Oreille River at River Mile 29

Lehigh No. 2

Mine

48

51

31.68

117

24

52.20

30

39N

43E

Linton Creek, Pend Oreille River at River Mile 29.S

West Contact

Mine

48

51

07.92

117

24

56.88

30

39N

43E

Linton Creek, Pend Oreille River at River Mile 29.S

Lehigh No. 1

Mine

48

51

02,52

117

24

14.04

29

39N

43E

Unnamed Creek, through Metaline, Pend Oreille Ri

Diamond R.

Mine

48

51

12.60

117

25

19.20

30

39N

43E

Unnamed Creek, through Metaline, Pend Oreille Ri

Bella May

Mine

48

50

53.16

117

24

16,20

29

39N

43E

Unnamed Creek, through Metaline, Pend Oreille Ri

Blue Bucket

Mine

48

50

37.68

117

23

53.52

32

39N

43E

Overland (1,700 ft), Pend Oreille River at River Mi

Metaline

Mine

48

50

32.64

117

23

24.00

32

39N

43E

Overland (1,700 ft), Pend Oreille River at River Mi

Sterling

Mine I48 50

10.32

117 |23 129.04

32

39N

43E

Overland (1,700 ft), Pend Oreille River at River Mi

Key:

E	= East,

ft	= feet.

Lat	= Latitude.

Long	= Longitude.

N	= North.

R	= Range.

S	= Section.

T	= Township.

-------
Source: EPA 1993.

tis

A

Not to Scale

Albeni Falsi
Dam

Canada

ecology and environment, inc.

International Specialists In tha Environment

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 1-1

CLARK FORK - PEND OREILLE BASIN

Date:
2-28-02

Drawn by:
AES

10:START-2\01080009\S714\fig 1-1

1-5

-------
Source: Maptcch, Inc. 200)

K



Vj ¦TT**»





» ^ f V" '.^'jt' 4 ' .AAT.- y- >1



! . »kJ' p : ' '\1!| ¦ ,':

KjnZSk'^

*5>f* H0- 1-. 1 :" }f"-i

frfpit

* v ?iftv



PwJ/->r3V. i^r-y i

Tfc» f,isf









•%yi

gayy* tfjh*ac -Lfw ,'j»3!te^4E38#

V twMBg iT&Ai	i\;«;

fc-fc'S •••<

iPili

^i;f ,

Trimble Creek J -Jl™

—¦Waj^^as^i

-------
0018

2. BACKGROUND

2.1	REGIONAL CHARACTERISTICS AND DESCRIPTIONS

The lower reach of the Pend Oreille River (as defined in Section 1) is located in Pend Oreille
County, Washington. Pend Oreille County is located in the northeast corner of Washington State.
Bordered on the north by Canada, the east by Idaho, the south by Spokane County, and the west by
Stevens County, Pend Oreille County is roughly 66 miles long and 22 miles wide. Within the county, the
Pend Oreille River, the second largest river in Washington, flows north into Canada (Pend Oreille
County 2001).

The Clark-Fork/Pend Oreille Basin system flows from Montana as the Clark Fork River into
Lake Pend Oreille in Idaho (Figure 1-1). The Pend Oreille River, originating as the outflow from Lake
Pend Oreille, enters Washington flowing north through the northeast corner of the state into Canada,
where it drains to the Columbia River just above the Internationa] Border (Figures 1-2 and 7-1; Ecology
1991). The Columbia River in Canada flows south into Washington State. The Clark-Fork/Pend Oreille
Watershed covers approximately 26,000 square miles in Montana, Idaho, and Washington (USGS 2000).

The area, as defined for this project, includes: 21 mine/mill facilities identified as potential
sources of contaminants, and tributaries (e.g., creeks and streams) near these facilities that empty into the
lower reach (as defined in Section 1) of the Pend Oreille River (Tables 1-1 and 2-1).

2.2	OWNERSHIP INFORMATION

The majority of lands in the upper reaches of the project area are public lands managed by the
BLM and federal lands managed by USFS. Privately held or leased lands are scattered throughout the
project area. Livestock grazing occurs on privately held lands and through grazing leases on publicly
held lands.

Much of the river basin's land within Pend Oreille County falls within the boundaries of the
Kaniksu and Colville national forests. Two-thirds of the northern and central parts of the county are
government owned; the southern portion of the study area is mostly privately owned. (EPA 1993)
Owners/contact persons for the mines/mills visited are included in Section 6. Owners of tributaries
visited as part of this field event are identified in Table 2-1.

10:START-2\01080009\S714

2-1

-------
0019

2.3 REGIONAL OPERATIONS AND WASTE CHARACTERISTICS
23.1 Historic Mining

The Metaline mining district surrounding the town of Metaline in Pend Oreille County is one of
the oldest in the state, predating statehood. Mining in the vicinity of the Pend Oreille River dates back to
1855 (Barlee 1932). Commercial development of the Metaline district can be traced to Lewis P. Larsen
and Jens Jensen. During 1904, they began prospecting the area around Metaline Falls and initiated
development of the Lehigh Cement Co. Plant and quarries. This was followed by the opening of several
lead-zinc mines. (Barlee 1932)

The north and south ends of the county proved to contain some of the richest deposits of lead and
zinc in the Pacific Northwest. However, through the turn of the century, the Metaline area languished in
virtual isolation. Access was limited to steamers plying the Pend Oreille River from Newport to only as
far downstream as south lone. In 1906, the channel at Box Canyon was dynamited making the river
navigable all the way downstream to Metaline Falls. This cleared the way for commercial drilling and
mining, which expanded rapidly through the 1930s. Large quantities of another mineral, limestone, was
discovered and comprised the backbone of the country's cement industry, at that time the largest in the
state. (Economic History 2001)

The lead-zinc ores of the Metaline district are of low grade and contain only minor amounts qf
silver. The average grade of the 19.3 million tons of ore mined from 1906 to 1977 in the district was
1.14 percent lead and 2.25 percent zinc (Lasmanis 1995).	i

Historically, metal extraction and processing were relatively inefficient, yielding large volumes
of metal-rich tailings that were deposited in and near nearby streams (USGS 2000). Mine tailings in the
study area typically contain elevated levels of arsenic, cadmium, copper, lead, mercury, and zinc. These
tailings and mines continue to provide a source of metals to streams, lakes, and reservoirs as surface
water meanders through and erodes tailings deposits and transports these metals downstream or directly
to the Pend Oreille River. (USGS 2000)

In 1963, the Metaline mining district was the 12* largest lead and zinc producer in the Nation
(USDA 1992).

2-2

-------
0020





Table 2-1



TRIBUTARY OWNERS
LOWER PEND OREILLE RIVER MINES AND MILLS
PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS
PEND OREILLE COUNTY, WASHINGTON

Tributary

County

Owner

Contact Information

Pewee Creek

Pend Oreille County, WA

Seattle City Light

Harris Martin
Seattle City light
700 Fifth Avenue, Suite 3300
Seattle, WA 98104-5031
(206) 386-4577

Everett Creek

Pend Oreille County, WA

Seattle City Light

Harris Martin
Seattle City Light
700 Fifth Avenue, Suite 3300
Seattle, WA 98104-5031
(206) 386-4577

Sullivan Creek

Pend Oreille County, WA

Lafarge Corp,

David Carroll
Lafarge Corp.

12950 Worldgate Drive, Suite 500
Hemdon, VA

Lime Creek

Pend Oreille County, WA

U.S. Forest Service

Nora Rasure
U.S. Forest Service
765 South Main
Colville.WA 99114
(509) 684-7000

i * _i„ rs	,i.

i-cuyuiw v*icciv

n	j n	:ii_ o		 u; a

rcnu oxciiic isuumj,

rrc innj

U.fcJ)., pUUMV IU11U



Slate Creek

Pend Oreille County, WA

U.S. Fbrest Service

Nora Rasure
U.S. Forest Service
765 South Main
ColvUle, WA 99114
(509) 684-7000

Beaver Creek

Pend Oreille County, WA

U.S., public land



Hume Creek

Pend Oreille County, WA

Bureau of Land Management

Elaine Zielinski
Bureau of Land Management
1515 SW Fifth Avenue
Portland, OR 97201

Lintoo creek

Pend Oreille County, WA

City of Metaline

Kelly Curtiss
Town of Metaline
P.O. Box 33
Metaline, WA 99152

2-3

-------
0021

3. FIELD ACTIVITIES AND ANALYTICAL PROTOCOL

A sampling quality assurance plan (SQAP) for the Lower Pend Oreille River Mines and Mills PA
and SI activities WAS developed by the START-2 prior to performing the field sampling (E&E 2001a).
The SQAP was based on background information collected by E & E, The SQAP describes the sampling
strategy, sampling methodology, and analytical program to identify potential hazardous substance source
areas and impacts to potential targets. With few exceptions, field activities were conducted in
accordance with the approved SQAP. Deviations from the SQAP are described when applicable. Field
activities were conducted in coordination with BLM, USFS, and Ecology staff.

The field event was conducted from June 17 to 30,2001. Sampling was conducted at 5 of the 21
mines/mills visited. Rationale applied by field personnel in determining whether to conduct sampling at
a mine/mill include observations of potential contaminant sources and the potential for contaminants
originating from potential sources to migrate and impact possible receptors via the surface water
overland flow pathway.

Locations considered possible receptors of contamination originating from potential sources
were also identified and sampled. As described in the SQAP, potential contaminant sources include
tailings piles/ponds, waste rock piles, adits, and stained soil areas surrounding improperly stored or
disposed drums and containers. Potential receptors/targets may include wetland areas, fisheries, surface
water intakes, sensitive environments, etc. as defined in the EPA Harzard Ranking System (HRS); Final
Rule. The contaminants of concern are Target Analyte List (TAL) metals, pesticides/polychlorinated
biphenyls (pest/PCBs), and semivolatie organic compounds (SVOCs). Total organic carbon (TOC) data
was also collected.

A total of 48 soil/sediment samples and 16 surface water samples were collected and analyzed
under the EPA CLP for TAL metals. A portion, 34 sediment samples were also analyzed under the EPA
CLP for pesticides/PCBs. One sediment sample was analyzed for SVOCs. A total of 34 sediment
samples were submitted to a commercial laboratory for TOC analysis.

Sample types and the methods of collection are described below. A list of all samples collected
for laboratory analysis under the PA and SI activities are contained in Table 3-1 at the end of this section.

10:START-2\01080Q09\S714

3-1

-------
0022

A discussion of sample results is contained in Sections 6 and 7. Photographic documentation of the PA
and SI field activities are contained in Appendix A.

Information provided to E & E regarding the Weston sampling event is included in Appendix G.

3.1 SAMPLING METHODOLOGY

Sampling for surface soil, surface water, and sediment followed the standard operating
procedures (SOPs) contained in Appendix A of the SQAP (E & E 2001a). Grass, leaves and other
vegetative material, rocks and other debris unsuitable for analysis were removed from soil samples before
being placed into the sampling containers. Surface soil and sediment samples were homogenized in
dedicated plastic bowls (except for pest/PCB analysis) prior to containerization in sample jars.

Dedicated plastic spoons and scoops were used to extract, homogenize, and place sample material into
sample containers (except for pest/PCB analysis). Dedicated steel bowls and steel spoons were used for
the collection and homogenization of pest/PCB samples.

Water samples were collected by hand-dipping a 1-liter poly bottle sample containers into the
water at well-mixed locations within the stream, or by using an unused sample container as a scoop to
obtain water samples in areas of low flow. An aliquot of each sample was tested in the field for
temperature and pH. After preservation, pH was again checked to ensure that the appropriate pH level

ho/1 Vuian	'

»««*%* ihtvwa uvmviw<

All samples were stored on ice in coolers continuously maintained under chain of custody.
Vehicles were locked if the sampling team had to walk out of visual range of the 4 x 4 vehicles. Sample
coolers from all teams were moved into a single occupied location (motel room) each evening to ensure
custody control and to re-ice as needed.

3.1.1	EPA CLP Surface Soil Samples

A total of 14 surface soil samples, including two background samples, were collected. Soil
samples were discrete grab samples collected from potential source and background areas. Surface soil
samples were collected from 0 to 6 inches below ground surface (bgs). Samples were analyzed for TAL
metals. •

3.1.2	EPA CLP Sediment Samples

Sediment samples were collected as outlined in the text of the SQAP (E&E 2001a). Sediment
samples were collected from below the apparent water line from 0 to 8 inches below the sediment surface

lQ:START*2\01Q8OOO5ftS7l4

3-2

-------
0023

in order from most downstream locations to most upstream locations. Samples were analyzed for TAL
metals, pesticides/PCBs, and TOC. MDSB01SD was additionally analyzed for SVOCs.

3.13 EPA CLP Surface Water Samples

Surface water samples were collected prior to collecting co-located sediment samples and from
the most downstream locations to the most upstream locations. Water samples were analyzed for TAL
metals.

3.2 ANALYTICAL PROTOCOLS

All samples collected were shipped off-site for chemical analysis, with the exception of field
measurement for pH. Analytical methods applied to E & E samples consisted of: EPA CLP TAL metals,
EPA CLP pesticides/PCBs, EPA CLP SVOCs, and EPA SW-846 TOC. These analyses were applied to
samples collected from suspected sources or targets in varying combinations based on the SQAP.

Laboratories performing the analyses were Sentinel, Inc., in Huntsville, Alabama (EPA CLP TAL
metals); Envirosystems Inc., in Columbia, Maryland (EPA CLP pesticides/PCBs and EPA CLP SVOCs);
and Analytical Services Center, E & E, Lancaster, New York (EPA SW-846 TOC). Analytical methods
applied to Weston samples are noted in Section 4.

33 GLOBAL POSITIONING SYSTEM

Trimble™ Pathfinder Professional XL global positioning system (GPS) survey units and data
loggers were used by the START-2 to approximate the horizontal location coordinates of sample points.

Except as noted for specific sample locations, the units provided three dimensional differentially
corrected sample coordinates with ± 1 meter accuracy. Due to the combination of the mountainous
terrain and limited satellite coverage over this area, the GPS units were often operating in no more than
two dimensional mode.

Sample coordinates were plotted onto a digitized map and then incorporated into Geographic
Information System databases to develop a station/sample location map. The START-2 was not able to
obtain accurate GPS coordinates at some locations due to mountainous terrain. These station locations
were estimated on the sample location map based on field observations. GPS coordinates by sample
point are provided in Appendix B. Weston GPS coordinates are found in Appendix G.

10:START-2\01080009\S714

3-3

-------
0024

3.4 INVESTIGATION-DERIVED WASTE

Investigation-derived waste (IDW) generated during the sampling effort consisted of used
personal protective clothing and disposable sampling equipment, IDW was disposed of as non-hazardous
solid waste at a municipal landfill. No IDW generated by the START-2 remains in the project area.

10:START-2\0I080009\S714

3-4

-------
Table 3-1

SAMPLE COLLECTION AND ANALYTICAL SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS PRELIMINARY ASSESSMENTS AND SITE I]





PE]

ND OREILLE COUNTY. WASHINGTON



EPA Sample
ID

E&E
Sample ID

Station
Location ID

CLP
Organic
No.

CLP
Inorganic
No.

Matrix

Depth

Sampler

Date

Time

TAL
Metals

Pesticdes/
PCBs

u
o

H

SVOCs



Blue Bucket Mine

01264268

NU

BBPP01SW

NU

MJ0F13

SW

-

AJ

06/26/01

13:00

X







Clear water, no odo

01264267

01050280

BBPP01SD

J0F16

MJ0F16

SD

0-6

AJ

06/26/01

13:00

X

X

X



Very sandy, multicc

01264270

NU

BBPP02SW

NU

MJ0F15

SW

-

AJ

06/26/01

13:05

X







Clear water, no odo

01264269

01050279

BBPP02SD

J0F14

MJ0F14

SD

0-6

AJ

06/26/01

13:05

X

X

X



Gray and dark brow

Joesphine Mine

01264356 1 NU

JOSP01SW

NU

MJ0FK9

SW

-

TK

06/26/01

15:10

X







Clear, no odor.

01264423 | 01050247

JOPP01SD

J0GN2

MJ0GN2

SD

0-8

RN

06/28/01

09:35

X

X

X



Gray, fine to course

Oriole Mine •

01264271

NU

ORSP01SW

NU

MJ0F17

SW

-

NA

06/27/01

12:35

X







Clear, no odor.

01264272

01050274

ORSP01SD

J0F18

MJ0F18

SD

0-8

NA

06/27/01

12:40

X

X

X



Light gray to light t

01264273

01050273

ORSP02SD

J0F19

MJ0F19

SD

0-8

NA

06/27/01

14:05

X

X

X



Brown, moist fine s

Pend Oreille Mine

101264266

NU

POCK01SW

NU

MJ0F11

SW

-

AJ

06/25/01

16:20

X







Clear water, no odo

01264263

01050277

POCK01SD

J0F08

MJ0F08

SD

0-8

AJ

06/25/01

16:28

X

X

X



Dark, sandy materia

01264401

NU

POPP01SW

NU

MJ0GL0

SW

-

CG

06/25/01

08:45

X







Clear water, no odo

01264410

NU

POPP02SW

NU

MJ0GL9

SW

-

DW

06/26/01

13:35

X







Clear, no odor, colt

01264411

01050239

POPP02SD

J0GM0

MJ0GM0

SD

0-8

DW

06/26/01

13:40

X

X

X



Brown fine to medi

01264412

NU

POPP03SW

NU

MJ0GM1

SW

-

DW

06/26/01

14:20

X







Clear water, no odo

01264413

01050240

POPP03SD

J0GM2

MJ0GM2

SD

0-8

DW

06/26/01

14:25

X

X

X



Brown fine to medi

01264351

01050260

POSP01SD

J0FK4

MJ0FK4

SD

0-8

TK

06/26/01

09:11

X

X

X



Dark gray, lots of v

01264352

01050261

POSP02SD

J0FK5

MJ0FK5

SD

0-8

TK

06/26/01

09:35

X

X

X



Gray, almost all cla

01264252

NU

POTP01SS

NU

MJ0EZ7

SS

0-6

AJ

06/25/01

09:35

X







Moist, gray, clayey

01264253

NU

POTP02SS

NU

MJ0EZ8

SS

0-6

AJ

06/25/01

10:25

X







Moist brown/dark b

01264254

NU

POTP03SS

NU

MJ0EZ9

SS

0-6

AJ

06/25/01

10:45

X







Brown and light br<

01264255

NU

POTP04SS

NU

MJ0F00

SS

0-6

AJ

06/25/01

11:25

X







Mixture of sand an<

01264256

NU

POTP05SS

NU

MJ0F01

SS

0-6

AJ

06/25/01

11:45

X







Mixture of sand am

01264257

NU

POTP06SS

NU

MJ0FO2

SS

0-6

AJ

06/25/01

12:00

X







Brown/dark brown,
matter.

-------
Table 3-1

SAMPLE COLLECTION AND ANALYTICAL SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS PRELIMINARY ASSESSMENTS AND SITE

-PEI

TO OREILLE COUNTY. WA

iSHINGTON



EPA Sample
ID

Sample ID

Station
Location ID

CLP
Organic
No.

CLP
Inorganic
No.

Matrix

Depth

Sampler

Date

Time

d i

2 7,

1

M "5

18

roc 1

w

u
o
>

..S£L.



01264258

NU

POTF07SS

NU

MI0F03

SS

0-6

AJ

06/25/01

14:05

X







Brown, fine, mix
dry.

01264259

NU

POTP08SS

NU

MI0F04

SS

0-6

AJ

06/25/01

14:12

X







Fine gray and bro

01264260

NU

POTP09SS

NU

MI0F05

SS

0-6

AJ

06/25/01

14:22

X







Brown and gray.

01264353

NU

POWP01SS

NU

MJ0FK6

SS

0-6

TK

06/26/01

10:20

X







Dark gray, lots of

01264354

NU

POWP02SS

NU

MJ0FK7

SS

0-6

TK

06/26/01

10:35

X







Gray, lots of rock

01264355

NU

POWP03SS

NU

MJ0FK8

SS

0-6

TK

06/26/01

10:45

X







Brown and gray,

01264264

01050278

TCBK01SD

J0F09

MJ0F09

SD

0-8

AJ

06/25/01

15:50

X

X

X



Large beige sand

01264265

NU

TCBK01SW

NU

MJ0F10

SW

-

AJ

06/25/01

15:55

X







Clear water, no o

Pend Oreille River

01264402

01050231

PRRS01SD

J0GL1

MJ0GL1

SD

0-8

DW

06/25/01

11:00

X

X

X



Medium brown,
clay 20%.

01264404

01050233

PRRS02SD

J0GL3

MJ0GL3

SD

0-8

DW

06/25/01

12:30

X

X

X



Medium brown,
clay 10-20%.

01264409

01050238

PRRS03SD

J0GL8

MJ0GL8

SD

0-8

DW

06/26/01

11:40

X

X

X



Brown, fine sand

01264414

01050241

PRRS04SD

J0GM3

MJ0GM3

SD

0-8

DW

06/27/01

11:45

X

X

X



Dark brown, silt

01264403

01050232

FRTB01SD

J0GL2

MJ0GL2

SD

0-8

DW

j 06/25/01

12:00

X

X

X



Light gray to bro

01264405

01050234

PRTB02SD

J0GL4

MJ0GL4

SD

0-8

DW

06/25/01

13:45

X

X

X



Dark brown, fine

101264406

01050235

PRTB03SD

J0GL5

MJ0GL5

SD

0-8

DW

06/25/01

14:15

X

X

X



bark brown, silt

[01264407

01050236

PRTB04SD

J0GL6

MJ0GL6

SD

0-8

DW

06/26/01

10:10

X

X

X



Light gray to bro

b1264408

01050237

PRTB05SD

J0GL7

MJ0GL7

SD

0-8

DW

06/26/01

10:45

X

X

X



Gray to black fir

01264421

01050245

PRTB06SD

I0GN0

MJ0GN0

SD

0-8

DW

06/27/01

17:15

X

X

X



Brown, fine to m

pi264422

01050246

PRTB07SD

J0GN1

MJ0GN1

SD

0-8

DW

06/27/01

18:05

X

X

X



Dark to medium

pi264424

01050248

PRTB08SD

J0GN3

MJ0GN3

SD

0-8

RN

06/28/01

12:35

X

X

X



Brown, fine to c

bl264425

01050249

PRTB09SD

J0GN4

MJ0GN4

SD

0-8

RN

06/28/01

13:10

X

X

X



Brown, fine to n

5%.

-------














Table 3-1













SAMPLE <

LOWER PEND OREILLE RIVER MIN

PE1

COLLECTION AND ANALYTICAL SUM
ES AND MILLS PRELIMINARY ASSES
SD OREILLE COUNTY. WASHINGTON

[MARY

SMENTS AND SITE

EPA Sample
ID

E&E
Sample ID

Station
Location ID

CLP
Organic
No.

CLP
Inorganic
No.

Matrix

Depth

Sampler

Date

Time

S

J s

M £

Pesticdes/
PCBs

roc

SVOCs



Metaline Falls Municipal Water Intake

01264429

NU

MF01SW

NU

MJ0GN8

SW

0

LD

06/28/01

11:50

X







Clear, no odor, 64

01264430

NU

MF02SW

NU

MJ0GN9

sw

0

LD

06/28/01

12:00

X







Clear, no odor, 48

Grandview Mine*

01264415

NU

GMPP04SW

NU

MJ0GM4

SW

0

DW

06/27/01

12:05

X







Clear, no odor, co

01264416

01050242

GMPP04SD

J0GM5

MI0GM5

SD

0-8

DW

06/27/01

12:10

X

X

X



Gray, multicolor®
0-5%.

01264417

NU

GMPP05SW

NU .

MJ0GM6

SW

0

DW

06/27/01

12:30

X







Clear, no odor, co

01264418

01050243

GMPP05SD

J0GM7

MI0GM7

SD

0-8

DW

06/27/01

12:35

X

X

X



Medium brown, si
30-40%.

Background Samples

01264358

NU

BK02SS

NU

MJ0FL1

SS

0-6

AJ

06/27/01

10:40

X







Dark brown, clay-

01264274

NU

BK03SS

NU

MJ0F20

SS

0-6

NA

06/27/01

13:30

X







Dark brown, siigh

01264419

NU

POBK01SW

NU

MI0GM8

SW

0

DW

06/27/01

12:55

X







Dark brown, sligh

01264420

01050244

POBK01SD

J0GM9

MJ0GM9

SD

0-8

DW

06/27/01

13:00

X

X

X



Brown clay and si

01264426

01050250

PRBK01SD

J0GN5

MJ0GN5

SD

0-8

RN

06/28/01

13:55

X

X

X



Brown fine to mei

01264427

01050251

PRBK02SD

J0GN6

MJ0GN6

SD

0-8

RN

06/28/01

14:05

X

X

X



Brown silt and ch

01264428

01050252

PRBK03SD

J0GN7

MJ0GN7

SD

0-8

RN

06/28/01

14:15

X

X

X



Brown fine to ver

Meyers Dam

01374222

| 01090441

|MDSB01SD

| J0KK8

[ MJ0KK8

| SD

1

| MT

109/12/01

09:38

1 X

1 X

X

|x

Gray sandy silt.

-------
Table 3-1

SAMPLE COLLECTION AND ANALYTICAL SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS PRELIMINARY ASSESSMENTS AND SITE



PE1

SD OREILLE

BOUNTY. WASHIN

GTON

EPA Sample
ID

E&E
Sample ID

Station
Location ID

CLP
Organic
No.

CLP
Inorganic
No.

Matrix

Depth

Sampler

Date

Time

TAL
Vfetals

1

¦s „

"S «

I y

BL 0.

roc

a

o



Weston Samples

01264070

NU

US002SD

JX829

MI0BQ3

SD

0-2

KB

06/28/01

09:30

X

X

X



Brown, fine to co

01264067

NU

UW002SW

NU

MJ0BQ0

SW

0

yn

06/28/01

09:45

X







No description pr

01264073

NU

US003SD

JX831

MJ0BQ5

SD

0-4

vn

06/28/01

10:45

X

X

X



Gray/brown, fine

01264074

NU

UW003SW

NU

MJ0BQ6

SW

0

KB

06/28/01

10:55

X







No description pi

01264075

NU

US004SD

JX832

MJ0BQ7

SD

0-2

KB

06/28/01

13:00

X

X

X



Dark brown, fine

~ Samples were also collected during the Grandview Mine Site Inspection. A complete description of this site inspection can be requested from the EPA.

Key:

AJ	= A) Johnson.	PCBs	= Polychlorinatcd biphenyls.

BB	= Blue Bucket Mine.	PO	= Pend Oreille Mine.

BK	= background sample.	PP	= probable point of entry.

CO	= Charles Gregory.	PR	= Pend Oreille River.

¦CX	= Creek 1.	RN	= Renee Nordeen.

CLP	= Contract Laboratory Program.	RS	= river sediment.

DW	= Dan Weiss.	SD	= sediment

E & E	= Ecology & Environment, Inc.	SP	= spring.

EPA	= United States Environmental Protection Agency.	SS	= surface soil.

GM	= Grandview Mine.	SVOCs	= Semivoiatile Organic Compounds.

ID	= Identificiation.	SW	= surface water.

JO	= Josephine Mine.	TAL	= Target Analyte List.

KB	= Kevin Brown.	TB	= tributary.

LD	= Leatta Dahlhoff.	TC	= Threcmile Creek.

MF	= Metaline Falls municipal water intake.	TK	= Tare Kara mas.

MT	= Monica Tonel.	_	TOC	= Total Organic Compound.

NA	= Neil Amick.	TP	= tailings pile.

No.	= Number.	US	= Tributary sediment/soil (upstream/upland sampling lex

NU	= Not utilized.	UW	= Upland surface water.

OR	= Oriole Mine.	Weston	= Roy F. Weston, Inc.

WP	= waste rock pile.

-------
0029

4. QUALITY ASSURANCE/QUALITY CONTROL

QA/QC data are necessary to determine precision and accuracy and to demonstrate the absence
of interferences and/or contamination of sampling equipment, glassware, and reagents. Specific QC
requirements for laboratory analyses are incorporated in the Contract Laboratory Program Statement of
Work for Organic Analyses (EPA 1999a) and in the Contract Laboratory Program Statement of Work for
Inorganic Analyses (EPA 2000a). These QC requirements or equivalent requirements were followed for
analytical work on the Lower Pend Oreille River project. This section describes the QA/QC measures
taken and provides an evaluation of the usability of data presented in this report.

Some of the field work for this project was performed in conjunction with Weston. Unless
otherwise noted, QA/QC information applies to all samples collected for the project. All samples were
collected following the guidance of the SQAPs (E & E 2001a; Weston 2001) for the field activities.
E & E soil and water inorganic analyses were performed at Sentinel, Inc., Huntsviile, Alabama, a CLP
laboratory, following the CLP Statement of Work for Inorganic Analyses (EPA 2000a), Weston soil and
water inorganic analyses were performed at Datachem Laboratories, Inc., Salt Lake City, Utah, and ,
Sentinel, Inc., Huntsviile, Alabama, CLP laboratories, following the CLP Statement of Work for
Inorganic Analyses (EPA 2000a). E & E soil and water organic analyses were perfonned at
Envirosystems, Inc., Columbia, Maryland, a CLP laboratory, following the CLP Statement of Work for
Organic Analyses (EPA 1999). Weston soil organic analyses were performed by the Mitkem
Corporation, Warwick, Rhode Island, and Laucks Testing Laboratory, Seattle, Washington, CLP
laboratories, following the CLP Statement of Work for Organic Analyses (EPA 1999). E & E TOC
analyses were performed at the Ecology and Environment, Inc., Analytical Services Center, Lancaster,
New York, a START-2 subcontracted commercial laboratory, following the Lloyd Kahn Method.

Weston TOC analyses were performed by North Creek Analytical Laboratory, Inc., Bothell, Washington,
a subcontracted commercial laboratory, following modified EPA Method 9060.

All data from analyses performed by the CLP laboratories were reviewed and validated by EPA
and/or Environmental Services Assistance Team chemists. Data from the subcontracted commercial
laboratories were reviewed and validated by E & E and/or Weston chemists. Data qualifiers were
applied as necessary according to the following guidance:

10:START-2\01080009\S7I4

4-1

-------
0030

•	EPA (1994) Contract Laboratory Program National Functional Guidelines for
Inorganic Data Review; and

•	EPA (1999) Contract Laboratory Program National Functional Guidelines for Organic
Data Review.

In the absence of other QC guidance, method-specific QC limits were also utilized to apply
qualifiers to the data. Copies of the data QA memoranda are included in Appendix D.

4.1	SATISFACTION OF DATA QUALITY OBJECTIVES

The following EPA (1994b) guidance document was used to establish data quality objectives
(DQOs) for this project:

•	Guidance for the Data Quality Objectives Process, EPA /600/R-96/055.

The EPA Task Monitors (TMs) determined that definitive data without error and bias
determination would be used for the sampling and analyses conducted during the field activities. The
data quality achieved during the field work produced sufficient data thai meet the data objectives stated
in the SQAPs (E & E 2001a; Weston 2001).

! '

A detailed discussion of the project data quality objectives that were accomplished is presented
in the following sections.

4.2	QUALITY ASSURANCE/QUALITY CONTROL SAMPLES

QA samples (rinsate blanks and trip blanks) were not required for this project. Trip blank
samples are only required for Volatile Organic Compound samples, which were not collected for this
project. Rinsate blank samples are required for non-dedicated sampling equipment; all sampling
equipment for this project was dedicated, therefore rinsate blank samples were not collected. QC
samples'included matrix spike/matrix spike duplicate (MS/MSD) samples for organic analyses or
MS/duplicate samples for inorganic analyses at a rate of one MS/MSD or one MS/duplicate per 20
samples per matrix, excluding QA samples; these QC analyses are not applicable for QA samples.
Temperature blanks were included in each sample cooler to ensure that temperature requirements were

10:START-2\01080009\S714

4-2

-------
0031

met. Some of the Weston TOC samples were received at temperatures greater than that specified in the
method; no action was taken based on these discrepancies,

4.3 PROJECT-SPECIFIC DATA QUALITY OBJECTIVES

The laboratory data were reviewed to ensure that data quality objectives (DQOs) for the project
were met. The following describes the laboratories* abilities to meet project DQOs for precision,
accuracy, and completeness and the field team's ability to meet project DQOs for representativeness and
comparability. The laboratories and the field team were able to meet DQOs for the project.

43.1	Precision

Precision measures the reproducibility of the sampling and analytical methodology. Laboratory
and field precision is defined as the relative percent difference (RPD) between duplicate sample analyses.
The laboratory duplicate samples or MS/MSD samples measure the precision of the analytical method.

The RPD values were reviewed for all laboratory samples. Twenty five sample results
(approximately 1.2%) were qualified as estimated quantities (J) based on laboratory duplicate QC
outliers. The DQO for precision of 85% was met

43.2	Accuracy

Accuracy measures the reproducibility of the sampling and analytical methodology. Laboratory
accuracy is defined as the surrogate spike percent recovery (% R) for each pesticide/PCBs analysis or the
MS % Rs for all analyses. The surrogate % R values were reviewed for all appropriate sample analyses.
No results were qualified based on surrogate QC outliers.

The MS % R values were reviewed for all MS/MSD analyses. Sixty results (approximately
2.8%) were qualified as estimated quantities (J or UJ) based spike QC outliers. Overall, the project DQO
for accuracy of 85% was met.

433 Completeness

Data completeness is defined as the percentage of usable data (usable data divided by the total
possible data). All laboratory data were reviewed for data validation and usability. None of the data
were rejected, therefore the project DQO for completeness of 90% was met.

1Q:START-2\O1O80OO9\S714

4-3

-------
0032

4.3.4 Representativeness

Data representativeness expresses the degree to which sample data accurately and precisely
represent a characteristic of a population, parameter variations at a sampling point, or environmental
condition. The number and selection of samples were determined in the field to account accurately for
site variations and sample matrices. The DQO for representativeness of 85% was met.

43.5 Comparability

Comparability is a qualitative parameter expressing the confidence with which one data set can
be compared to another. Data produced for this study followed applicable field sampling techniques and
specific analytical methodology. The DQO for comparability was met.

4.4 LABORATORY QUALITY ASSURANCE/QUALITY CONTROL PARAMETERS

The laboratory data also were reviewed for holding times and laboratory blank samples. These
QA/QC parameters are summarized below. In general, the QA/QC parameters were considered
acceptable.

4.4.1	Holding Times

All samples were analyzed within holding time limits, therefore no results were qualified based
on holding time QC outliers.

4.4.2	Laboratory Blanks

Al| laboratory blanks met the frequency criteria. The following contaminants of concern were
detected in the laboratory blanks:

*	Pesticides:	none*,

*	SVOCs:	bis(2-ethylhexyl)phthalate; and

*	TAL Inorganics: aluminum, antimony, arsenic, barium, beryllium, cadmium, calcium,

chromium, copper, iron, lead, magnesium, manganese, potassium,
sodium, silver, selenium, thallium, and zinc.

Any associated sample result less than five times the positive blank contamination (10 times for

common laboratory contaminants) were qualified as not detected (U). Associated sample results less

than five times the absolute value of negative inorganic blank contamination were qualified as estimated

quantities (I or UJ). A total of 126 inorganic results (approximately 5.9 %) were qualified as not

detected (U) or as estimated quantities (J or UJ) based on laboratory blank contamination. See Appendix

D for results that were qualified based on blank contamination.

10:START-2\01080009\S714

4-4

-------
0033

5. ANALYTICAL RESULTS REPORTING AND BACKGROUND SAMPLES

This section describes the reporting criteria and reporting methods applied to EPA CLP
analytical results presented in Sections 6 and 7 of this report. A discussion of background sample
locations and results also is provided. A list of all samples collected for laboratory analysis is presented
in Table 3-1.

5.1 ANALYTICAL RESULTS EVALUATION CRITERIA

Analytical results presented in the summary tables in Sections 6 and 7 show all analytes detected
above laboratory detection limits in bold type. Analytical results indicating significant concentrations of
contaminants in source samples (Section 6) with respect to background concentrations are shown
underlined and in bold type. Similarly, analytical results indicating elevated concentrations of
contaminants in target samples (Section 7) with respect to background concentrations also are underlined
and in bold type. For the purposes of this investigation, significant/elevated concentrations are defined,
using Table 2-3 of the EPA HRS model criteria for observed release (significant or elevated
concentrations) as follows.

•	Equal to or greater than the sample's contract required quantitation limit/contract required
detection limit (CRQL/CRDL) or the sample quantitation limit (SQL) when a non-CLP

. laboratory was used; and

•	' Equal to or greater than the background sample's CRQL/CRDL or SQL when the

background concentration is below detection limits; or

•	At least three times greater than the background concentration when the
background concentration equals or exceeds the detection limit.

Specifically for this report, elevated concentrations in the surface water samples for the Blue
Bucket and Oriole mines are defined as equal to or greater than the EPA National Recommended Water
Quality Criteria - Correction, April 1999 or EPA Ecotox Screening Thresholds (EPA 1999b).

The analytical summary tables present all detected analytes, but only those detected analytes at
potential sources or in targets meeting the significant/elevated concentration criteria are discussed in the
report text. All detected concentrations are discussed for background samples, including those
concentrations which were qualified as estimated because they were detected below the SQL (JB).

10:START-2\01080009\S714

5-1

-------
0034

Because both tailings and waste rock are unique soil waste matrices placed on surface soil, analytical
results of the tailings and waste rock samples collected were compared to the results for background
surface soil. The background surface soil samples consisted of native soil.

For analytical results qualified as estimated, the sample concentration was adjusted as described
in Using Qualified Data to Document an Observed Release and Observed Contamination (EPA 1996)
before determination of whether the concentration was significant/elevated. Analytical results are
qualified as estimated (flagged "J") when the analyte is positively identified as either present or absent
and based on the quality control data provided by the laboratory. The associated numerical value is the
approximate concentration of the analyte in the sample. Additional qualifiers were applied when
necessary to indicate potential bias of estimated quantities including low, unknown, high, or the result
was estimated because it was below the sample quantitation limit:

•	B = The detected concentration is below the method reporting limit/CRDL, but is

above the instrument detection limit;

•	H =	The numerical result is likely biased high, above the actual concentration;

•	L =	The numerical result is likely biased low, below the actual concentration;

•	K =	The bias of the numerical value is unknown; and

•	Q=	The detected concentration is below the method reoortine limit/CROL. but is

					"	" " "	A	W	-

above the method detection limit.

The tables in Section 6 and 7 provide adjusted concentrations (AC) in parenthesis when the
adjusted result is elevated with respect to background. For comparison purposes, the CRQL/CRDL is
provided in parenthesis for background results that are qualified because they are below the
CRQL/CRDL when the analyte is present in target samples at elevated concentrations. When samples
were diluted for reanalysis at a laboratory, the dilution results were considered for evaluation and are
provided in the tables. For target locations, only those analytes that also were detected in a source at the
mine/mill were evaluated to determine whether their concentrations were elevated. All hazardous
substances detected using EPA CLP results at target locations and meeting evaluation criteria can be used
to document an observed release from the source at the mines/mills to the target.

5,1.1 Sample Results Reporting

When a given analyte was detected at significant/elevated concentrations in four or more
samples, the number of samples and the concentration ranges are reported. When an analyte was
detected at significant/elevated concentrations in three or fewer samples, the concentration of the analyte

10:START-2\01080009\S714

5-2

-------
0035

in each sample is reported. Analytical results summary tables in each section list detected analytes and
concentrations.

Based on EPA Region 10 policy, evaluation of the common earth crust elements aluminum,
calcium, iron, magnesium, potassium, and sodium generally is employed only in water mass tracing,
which is beyond the scope of this report.

5.2 BACKGROUND SAMPLES

Background samples were collected for each of the naturally occurring medium from which
samples were collected. Those media are surface soil, surface water and sediment. Background samples
were collected for comparison to downstream sample results as defined in Section 5.1. Results for the
appropriate background sample(s) appear as the first column(s) in the analytical results summary tables
in Sections 6 and 7 for comparison against source or target results.

5.2.1 Background Surface Soil

5.2.1.1	Sample Locations

Two upgradient background locations (BK02SS and BK03SS) were sampled within the project
area. Sample locations are listed in Table 3-1. BK02SS was located north of the Circle Motel in
Metaline Falls and was upgradient of any mining activity and reflects background concentrations for •
surface soil samples collected at mines/mills located on the east side of the Pend Oreille River in the
project area (Figure 7-1). BK03SS was located approximately 650 feet northwest from the adit/shaft at
the Oriole Mine and upgradient of any mining activity (Figures 6-3 and 7-1).

The surface soil samples were collected from 0 to 6 inches bgs. The matrix of the samples
appeared similar to that of the native soil observed at the mines.

To determine if analyte concentrations are significant/elevated, source/target sample data were
compared to the highest background concentrations for each analyte.

In this report, background concentrations of TAL metals will be compared to source and target
sample concentrations, as described in sections 6 and 7, which have been analyzed by the same method
(i.e., CLP).

5.2.1.2	Sample Results

Nine TAL metals were detected, ranging from a concentration of 3.5 milligrams per kilogram
(mg/kg) arsenic to 989 mg/kg manganese in sample BK02SS (Table 6-9). Nine TAL metals were

10:START-2\D1080009VS714

5-3

-------
w Vi U u

detected, ranging from a concentration of 6.7 mg/kg arsenic to 4,050 mg/kg manganese in sample
BK03SS (Table 6-9).

5.2.2 Background Surface Water

5.2.2.1	Sample Locations

Two upgradient background locations (TCBK01SW and POBKOISW) were sampled within the
project area. Sample locations are listed in Table 3-1. TCBK01SW was located on Threemile Creek
upgradient of any mining activity and reflects background concentrations for the Creek 1 sampled at the
Pend Oreille Mine/Mill (Figure 6-12). The sample location was co-located with sediment sample
TCBK01SD.

POBKOISW was located on the Pend Oreille River upgradient of the Josephine Mine,
Grandview Mine/Mill, and Pend Oreille Mine/Mill and reflects background concentrations for the Pend
Oreille River and the Josephine Mine, Grandview Mine/Mill, and Pend Oreille Mine/Mill (Figure 6-12).
The sample location was co-located with sediment sample POBKOISD.

To determine if analyte concentrations are significant/elevated, source/target sample data were
compared to the highest background concentrations for each analyte.

5.2.2.2	Sampie Results

No TAL metals were detected in TCBK01SW (Table 7-3). No TAL metals were detected in
POBKOISW (Tables 6-5,6-7, and 6-10).

5.2.3 Background Sediment
5.23.1 Sample Locations

Six upgradient background locations (PRBK01SD, PRBK02SD, PRBK03SD, TCBK01SD,
POBKOISD, and USO04SD) were sampled within the project area. Sample locations are listed in
Table 3-1.

PRBK01SD, PRBK02SD, and PRBK03SD were collected on the west side of the Pend Oreille
River downgradient of the Box Canyon Dam and upgradient of the mines/mills investigated as part of
this project. These data reflect background concentrations for Blue Bucket and Oriole mines
(Figure 7-1). To determine if analyte concentrations are significant/elevated, source/target sample data
were compared to the highest background concentrations for each analyte.

10:START-2\01080009NS714

5-4

-------
0037

TCBK01SD was located on Threemile Creek upgradient of mining activity and reflects
background concentrations for the Creek 1 sampled at the Pend Oreille Mine/Mill (Figure 6-12). The
sample location was co-located with TCBK01SW.

POBKG1SD was located on the Pend Oreille River upgradient of the Josephine Mine, Grandview
Mine/Mill, and Pend Oreille Mine/Mill and reflects background concentrations for the Pend Oreille
River, and the Josephine Mine, Grandview Mine/Mill, and Pend Oreille Mine/Mill (Figure 6-12). The
sample location was co-located with POBKOISW.

US004 was located on Linton Creek upgradient of the Oriole Mine and reflects background
concentrations for the Oriole Mine (Figure 7-1).

To determine if analyte concentrations are significant/elevated, source/target sample data were
compared to the highest background concentrations for each analyte.

5.23.2 Sample Results

Nine TAL metals were detected, ranging from a concentration of 5.2 mg/kg arsenic to 243 mg/kg
manganese in sample PRBK01SD (Tables 6-2 and 6-4). Nine TAL metals were detected, ranging from a
concentration of 5.3 mg/kg arsenic to 429 mg/kg manganese in sample PRBK02SD (Tables 6-2and 6-4).
Nine TAL metals were detected, ranging from a concentration of 5.3 mg/kg arsenic to 345 mg/kg
manganese in sample PRBK03SD (Tables 6-2 and 6-4). Six TAL metals were detected, ranging from a
concentration of 5.7 mg/kg chromium to 211 mg/kg manganese in sample TCBK01SD (Table 7-4). Nine
TAL metals were detected, ranging from a concentration of 16.3 mg/kg arsenic to 921 mg/kg manganese
in sample POBKOISD (Tables 6-6,6-8, and 6-11). Eight TAL metals were detected, ranging from a
concentration of 2.6 mg/kg arsenic to 699 mg/kg manganese in sample US004SD (Table 6-4).

10:START-2\Q1080009VS714

5-5

-------
0038

6. MINES AND MILLS, LOCATIONS/DESCRIPTIONS, START-2 VISITS

This section identifies the mines and mills visited by EPA and the START-2 personnel as part of
this field event. Mine/mill location, historical information, description, and ownership information are
presented for each mine/mill. This section also presents field observations for the START-2 contractor
and/or EPA personnel during the visits. For the five mines and mills where sampling was conducted,
analytical results are presented in this section (Figures 6-1 through 6-12).

6.1 STERLING MINE
6.1.1 Mine Location

Latitude:

Longitude:

Legal Description:
CERCLIS ID:
County:

Mine Owner/Contact:

48° 50* 10.32"N
117° 23' 29.04"W

EVi Section 32, Township 39N, Range 43E

WAN001002331

Pend Oreiiie

Bureau of Land Management
Contact: Joe Buesing
1103 North Fancher Road
Spokane, Washington 99212-1275
(509) 536-1221

Shoshone Tree Farms/Riley Creek Lumber

Contact: Bob Boeh

69 Riley Creek Park Drive

Laclede, Idaho 83841

(208) 263-7574

6.1.2 Historical Information

The Sterling Mine is a former lead, zinc, and silver mine located in the Metaline mining district
(Derkey 1990). The mine is reported to have produced in 1918 and 1926 (Derkey 1990). Historical
ownership from the time of patent to the present is unknown.

10: START-2\01080009\S714

6-1

-------
0039

6.1.3	Mine Description/Features

The Sterling Mine is located approximately 100 to 200 yards south of the Metaline Mine, along
an unnamed tributary, approximately 150 feet west of the Pend Oreille River. The mine is located in the
Yellowhead horizon (Derkey 1990). Mineralization occurs in the Metaline Formation (Derkey 1990).

6.1.4	START-2 Mine Visit

On June 26,2001, the START-2 visited the Sterling Mine and conducted a visual inspection of
the property and surrounding area (Appendix C; Team 2, Pages 17 and 18). The mine area consisted of a
shaft measuring approximately 30 feet by 60 feet by 25 feet deep (Appendix A; Photo 11-16), wood
debris, and a partial concrete foundation (Appendix A; Photo 11-17). The START-2 observed a creek
flowing an estimated 60 to 80 gallons per minute (gpm) approximately 100 feet south of the mine area.
The mine is approximately 150 feet west of the Pend Oreille River. The mine area is in a low point
geographically; potential overland drainage routes flow to the southeast. No residents were observed on
the property. No potential sources, such as tailings or waste rock, or targets were observed at the
property. Therefore, based on EPA TM guidance, no samples were collected.

6.2 METALINE MINE

6.2.1	Mine Location

Latitude:	48° 50'32.64"W

Longitude:	117° 23' 24.00"N

Legal Description: NE'/i Section 32, Township 39N, Range 43E
CERCLIS ID:	WAN001002328

County:	Pend Oreille

Mine Owner/Contact: Shoshone Tree Tarms/Riley Creek Lumber

Contact: Bob Boeh
69 Riley Creek Park Drive
PO Box 220
Laclede, Idaho 83841
(208)263-7574

6.2.2	Historical Information

The Metaline Mine is a former lead, zinc, and silver mine located in the Metaline mining district
(Derkey 1990). The Metaline Mine was the name given to an adit for mining the combined ore bodies of
the Bella May, Blue Bucket, and West Contact deposits (Derkey 1990). The mine is reported to have
produced 410,724 tons of ore valued at $2,573,294 from 1938 to 1947 (Derkey 1990). The mine came

10:START-2\Q1080009\S714

6-2

-------
0040

under the ownership of Pend Oreille Properties in 1949 (Battien 1998). Additional historical ownership
information from the time reported to the present is unknown.

6.2.3	Mine Description/Features

The Metaline Mine is located six miles from Metaline Falls (Battien 1998). Mineralization is in
the dolomitic limestone and is in the Josephine horizon of the Metaline Formation (Derkey 1990). Ore at
the various properties of the Metaline Mine occurs in the upper part of the Metaline Formation, within
approximately 200 feet of its contact with the Ledbetter Slate (Derkey 1990).

6.2.4	START-2 Mine Visit

On June 26,2001, the START-2 visited the Metaline Mine and conducted a visual inspection of
the property and surrounding area (Appendix C; Team 2, Page 17). The mine area consisted of two
shafts and two waste rock piles. The upper shaft measured 4 feet by 6 feet with unknown depth
(Appendix A; Photos 11-13 through 11-15). The lower shaft, located approximately 50 feet
downgradient from the upper shaft, measured 6 feet by 6 feet, and appears to connect with the upper
shaft approximately 3 feet bgs (Appendix A; Photo 11-13). The upper waste rock pile measured 10 feet
by 15 feet by 5 feet deep. The lower waste rock pile measured 50 feet by 15 feet by 5 feet deep
(Appendix A; Photo 11-14). The START-2 did not observe an overland drainage route from the waste
rock piles to the Pend Oreille River. No residents were observed on the property. No potential targets
were observed on the property. Therefore, based on EPA TM guidance, no samples were collected.

6.3 BLUE BUCKET MINE
6.3.1 Mine Location

Latitude:
Longitude:

Legal Description:

Ni4 Section 32, Township 39N, Range 43E

48° 50' 37.68"N
117° 23' 53.52"W

CERCLIS ID:
County:

WAN0010G2319
Pend Oreille

Mine Owner/Contact: Shoshone Tree Farms/Riley Creek Lumber

Contact: Bob Boeh
69 Riley Creek Park Drive
P.O. Box 220
Laclede, Idaho 83841
(208) 263-7574

10:START-2\01080Q09NS714

6-3

-------
0041

6.3.2 Historical Information

The Blue Bucket Mine is a former zinc, lead, and silver mine located in the Metaline mining
district (Derkey 1990). The Blue Bucket Mine was the name given to an adit used to access the
combined ore bodies of the Metaline, Bella May, and West Contact (Derkey 1990). The mine is reported
to have produced in 1906,1907,1916 to 1918,1922 to 1926, and 1937 to 1950 (Derkey 1990). Total
production was 175,000 tons by 1942, with production at a rate of 200 ton/day (Derkey 1990). The total
ore produced between 1937 and 1943 was 56,131 tons (Derkey 1990). Ownership history from the time
of patent to the present is unknown.

633 Mine Description/Features

The Blue Bucket Mine is accessed from an unmarked forest service road. Ore bodies of various
sizes tend to lie along bedding zones, probably within the upper 350 feet of the Metaline Formation, and
contain sphalerite and galena associated with silicified dolomite and calcite (Derkey 1990). Ore at the
Blue Bucket and adjacent mines occurs within the upper 350 feet of the Metaline Formation
(Derkey 1990).

63.4	START-2 Mine Visit

On June 26, 2001, the START-2 visited the Blue Bucket Mine and conducted a visual inspection

of the property and surrounding area (Figure 6-1; Appendix C; Team 2, Pages 19 and 20). The mine area

!

consisted of a shaft measuring 15 feet by 15 feet with unknown depth (Appendix A; Photos 12-1 through
12-3). There could be potential flow from the shaft to the unnamed creek (probable point of entry
[PPE] 2).- Below the unmarked forest service road a culvert (PPE 1) leads to an unnamed creek which
flows through the mine shaft area and past a waste rock pile for approximately 80 feet. There could be
potential overland flow from the waste rock pile to the unnamed creek (PPE 3). The START-2 estimated
the flow of the creek to be 20 gpm. The culvert appeared to be galvanized metal. At the time of the visit,
there was minimal (approximately 1 gpm) flow from the culvert. The waste rock pile measured 60 feet
long by 50 feet wide by 15 feet deep. The START-2 did not observe any areas of obvious staining at the
mine arda.

63.5	Sampling Locations

Two co-located sediment and surface water samples were collected at the mine (Figure 6-2).
Samples BBPP01SW and BBPP01SD were collected downgradient of the waste rock pile in an observed
overland drainage area (PPE 3). The sediments at this sample location were sandy and multi-colored.

10:START-2V01080009\S714

6-4

-------
0042

Samples BBPP02SW and BBPP02SD were collected near the culvert and south of the mine shaft
(PPE 1). The sediments at this sample location were gray, dark brown and fine grained.

6.3.6 Analytical Results

63.6.1 Surface Water Sample Results

Sample results are summarized in Table 6-1. No analytes were detected above the Ecotox
Screening Thresholds or Federal AWQC Protection of Aquatic Organisms benchmarks.

6.3.6.2 Sediment Sample Results

Sample results are summarized in Table 6-2. Cadmium was detected at significant
concentrations in BBPP01SD and BBPP02SD at 1.7 mg/kg and 2.8 mg/kg, respectively. Lead was
detected at significant concentrations in BBPP01SD and BBPP02SD at 59.9 mg/kg and 72.5 mg/kg,
respectively. Zinc was detected at a significant concentration in BBPP02SD at an adjusted concentration
of 373 mg/kg.

6.4 BELLA MAY MINE
6.4.1 Mine Location

Latitude:	48" 50! 53.i6"N

Contact: Joe Buesing
1103 North Fancher Road
Spokane, Washington 99212-1275
(509) 536-1221

Shoshone Tree Farms/Riley Creek Lumber

Contact: Bob Boeh

69 Riley Creek Park Drive

P.O. Box 220

Laclede, Idaho 83841

(208) 263-7574

Longitude:

Legal Description:
CERCLIS ID:
County:

117° 24' 16.20"W

SWV4 Section 29, Township 39N, Range 43E

WAN001002318

Pend Oreille

Mine Owners/Contact: Bureau of Land Management

10:START-2\01080009\S7I4

6-5

-------
0043

6.4.2	Historical Information

The Bella May Mine is a former zinc, lead, silver, and cadmium mine located in the Metaline
mining district (Derkey 1990). The Bella May Mine was the name given to an adit used to access the
combined ore bodies of the Blue Bucket, West Contact, and Metaline deposits (Derkey 1990). The mine
was reported to have produced 208,678 tons of ore between 1937 to 1943 (Derkey 1990). From 1923 to
1924, over 250 tons of practically pure galena made up the shipment put together by the then owners,
Oscar DeCamp and Associates (Battien 1998). Further ownership history from the time reported to the
present is unknown.

6.4.3	Mine Description/Features

One adit at the mine was 6,400 feet long and there were a reported 12,000 feet of underground
workings by 1956 (Battien 1998). At least two ore bodies were found in hydrothermally altered Metaline
Formation about 150 feet below the Ledbetter Slate - Metaline Formation contact (Derkey 1990). Ore at
the Bella May and adjacent mines occurs near the upper contact of the Metaline Formation, within about
300 feet of the contact with the Ledbetter Slate (Derkey 1990).

6.4.4	START-2 Mine Visit

On June 26, 2001, the START-2 visited the Bella May Mine and conducted a visual inspection of
the property and surrounding area (Appendix C; Team 2, Pages 20 and 21). The mine area consisted of
an upper adit measuring 6 feet by 6 feet by 30 feet deep; a lower adit measuring 5 feet by 6 feet by 50
feet deep; and a shaft measuring 5 feet by 5 feet by 30 feet deep (Appendix A; Photos 12-7 through
12-9). A waste rock pile measuring 100 feet by 50 feet by 5 feet deep was observed. The waste rock pile
is adjacent to the lower adit and extends in a triangular shape to the south for approximately 100 feet
(Appendix A; Photo 12-10). The START-2 did not observe any surface water features in the area and
any overland drainage routes appear to end at the mine access road. No residents were observed on the
property. No potential targets were observed on the property. Therefore, based on EPA TM guidance,
no samples were collected.

10:START-2\01080009\S714

6-6

-------
0044

6.5 DIAMOND R. MINE
6.5.1 Mine Location

Latitude;
Longitude:

Legal Description:
CERCLIS ID:
County:

WANOO1002320
Pend Oreille

Near center, Section 30, Township 39N, Range 43E

48° 51' 12.60"N
117° 25' 19.20"W

Mine Owner/Contact: Shoshone Tree Farms/Riley Creek Lumber

Contact: Bob Boeh
69 Riley Creek Park Drive
P.O. Box 220
Laclede, Idaho 83841
(208) 263-7574

6.5.2 Historical Information

The Diamond R. Mine is a former lead and zinc mine located in the Metaline mining district
(Derkey 1990). It is reported that one carload of ore was shipped in 1918 (Battien 1998; Derkey 1990).
In 1932 the mine came under the ownership of the Metaline Mining and Leasing Company
(Battien 1998). Further ownership history from the time reported to the present is unknown.

6.53 Mine Description/Features

Mineralization at the mine occurs as small irregular streaks of galena in brecciated dolomitic
limestone (Derkey 1990). Mineralization occurs at the Josephine horizon, 35 to 150 feet below contact
of the Metaline Formation with the overlying Ledbetter Slate (Derkey 1990).

6.5.4 START-2 Mine Visit

On June 26, 2001, the START-2 visited the Diamond R. Mine and conducted a visual inspection
of the property and surrounding area (Appendix C; Team 2, Page 19). The mine area includes a partially
collapsed shaft and two waste rock piles (Appendix A; Photos 11-20 through 11-24). The shaft measures
approximately 60 feet by 10 feet wide by 15 feet deep. The upper waste rock pile measures
approximately 10 feet by 8 feet by 2 feet deep. The lower waste rock pile is covered with vegetation and
measures approximately 40 feet by 30 feet by 10 feet deep. The START-2 team located another, mine
area approximately 500 feet to the east of the mine. It was unclear at the time of the visit if the two areas
were related. The START-2 assumes that the adjacent area is a portion of the Diamond R. Mine. The

10:START-2\01080009XS714	6-7

-------
0045

adjacent area consisted of three waste rock piles. The upper waste rock pile measures 5 feet by 5 feet by
2 feet deep. The middle waste rock pile measures 50 feet by 20 feet by 10 feet deep. The lower waste
rock pile measures 60 feet by 40 feet by 10 feet deep. The START-2 did not observe any surface water
features at the mine area. No residents were observed on the property. No potential targets were
observed on the property. Therefore, based on EPA TM guidance, no samples were collected.

6.6 LEHIGH NO. 1 MINE

6.6.1	Mine Location

Latitude;	48°51'2.52"N

Longitude;	117° 24'14.09"W

Legal Description: NE'4 NEVi Section 29, Township 39N, Range 43E
CERCLIS ID:	WAN001002325

County:	Pend Oreille

Mine Owner/Contact: Shoshone Tree Farms/Riley Creek Lumber

Contact: Bob Boeh
69 Riley Creek Park Drive
Laclede, Idaho 83841
(208) 263-7574

6.6.2	Historical Information

The Lehigh No. 1 Mine is a former iron and lead mine located in the Metaline mining district
(Derkey 1990). It is reported that the mine produced 800 tons of ore prior to 1941 (Derkey 1990).
Historical ownership information for the Lehigh No. 1 Mine from the time of patent to the present is
unknown. \ ,

6.63 Mine Description/Features

Mississippi Valley-type deposits are found in lower Paleozoic miogeoclinal rocks. Ore control
included oxidation of pyrite bodies. The iron oxide was used in the manufacture of cement requiring a
low amount of sulfide and aluminum-bearing clays. (Derkey 1990)

6.6.4 START-2 Mine Visit

On June 26, 2001 the START-2 visited the Lehigh No. 1 Mine and conducted a visual inspection

of the property and surrounding area (Appendix C; Team 2, Page 21). The mine area consisted of two
shafts; the horizontal shaft (shaft 1-connects with the Bella May Mine) measured approximately 15 feet

1O:START-2\0108QOO5RS714

6-8

-------
0046

by 15 feet by 100 feet deep and the nearby vertical shaft measured approximately 5 feet by 5 feet by 30
feet deep (Appendix A; Photos 12-11 through 12-15). A waste rock pile located downgradient from both
shafts measured approximately 100 feet by 67 feet by 5 feet deep. The START-2 did not observe any
surface water features at the mine including overland drainage routes. No residents were observed on the
property. No potential targets were observed on the property. Therefore, based on EPA TM guidance,
no samples were collected.

6.7 WEST CONTACT MINE

6.7.1	Mine Location

Latitude:	48°51'7.92"N

Longitude:	117°24'56.88"W

Legal Description: EVi Section 30, Township 39N, Range 43E

CERCLIS ID:	WAN001002332

County:	Pend Oreille

Mine Owner/Contact: Shoshone Tree Farms/Riley Creek Lumber

Contact: Bob Boeh
69 Riley Creek Park Drive
Laclede, Idaho 83841
(208) 263-7574

6.7.2	Historical Information

The West Contact Mine is a former zinc, lead, and silver mine located in the Metaline mining
district (Derkey 1990). The West Contact was the name given to an adit that was used to access the
combined ore bodies of the Bella May, Blue Bucket, and Metaline deposits (Derkey 1990). The
production of this mine is reported along with that of the Metaline Mine (Derkey 1990). Historical
ownership information for the West Contact Mine from the time of patent to the present is unknown.

6.73 Mine Description/Features

Ore bodies lie along bedding zones near the upper contact with the Metaline Formation (Derkey
1990). Mineralization consists of sphalerite and galena associated with silicifled dolomite and calcite
(Derkey 1990). Ore at the West Contact and Bella May and Blue Bucket mines occurs near the contact
of the Metaline Formation with the overlying Ledbetter Slate (Derkey 1990).

10:START-2\01080009\S714

6-9

-------
0047

6.7.4 START-2 Mine Visit

On June 26, 2001, the START-2 visited the West Contact Mine and conducted a visual
inspection of the property and surrounding area (Appendix C; Team 2, Page 18). The mine area
consisted of a shaft measuring 10 feet by 10 feet with unknown depth (Appendix A; Photos 11-18 and
11-19). The START-2 did not observe any surface water features at the mine including overland
drainage routes. The START-2 did not observe any additional sources such as waste rock or tailings at
the mine. No residents were observed on the property. No potential targets were observed on the
property. Therefore, based on EPA TM guidance, no samples were collected.

6.8 LEHIGH NO. 2 MINE

6.8.1	Mine Location

Latitude:	48° 51'31.68"N

Longitude:	117° 24' 52.20"W

Legal Description: W'/i Section 30, Township 39N, Range 43E

CERCLIS ED:	WAN001002326

County:	Pend Oreille

Mine Owner/Contact: Shoshone Tree Farms/Riley Creek Lumber

Contact: Bob Boeh
69 Riley Creek Park Drive
Laclede, Idaho 83841
(208) 263-7574

6.8.2	Historical Information

The Lehigh No. 2 Mine is a former iron mine located in the Metaline mining district (Derkey
1990). It is reported that the mine produced in 1936 (Derkey 1990). Historical ownership information
for the Lehigh No. 2 Mine from the time of patent to the present is unknown.

6.83 Mine Description/Features

Mississippi Valley-type deposits are found in lower Paleozoic miogeoclinal rocks. Ore control
included oxidation of pyrite bodies. The iron oxide was used in the manufacture of cement requiring a
low amount of sulfide and aluminum-bearing clays. (Derkey 1990)

10:START-2\01080009\S714

6-10

-------
0048

6.8.4 START-2 Mine Visit

On June 26,2001, the START-2 visited the Lehigh No, 2 Mine and conducted a visual inspection
of the property and surrounding area (Appendix C; Team 2, Page 23). The mine area consisted of a
horizontal shaft that measured approximately 5 feet by 5 feet by 20 feet deep (Appendix A; Photos 13-3
through 13-5). The waste rock pile associated with this mine is mixed with the Lehigh No. 1 waste rock
pile and measured approximately 100 feet by 67 feet by 5 feet deep. The START-2 did not observe any
surface water features at the mine including overland drainage routes. No residents were observed on the
property. No potential targets were observed on the property. Therefore, based on EPA TM guidance,
no samples were collected.

63 ORIOLE MINE

6.9.1	Mine Location

Latitude:	48° 51'36.72"N

Longitude:	117°24' 46.44"W

Legal Description:	SE corner, Section 19, Township 39N, Range 43E

CERCLISID:	WAN001002330

County:	Pend Oreille

Mine Owner/Contact: United States Forest Service

Contact: Nora Rasure
765 South Main
Colville, Washington 99114
(509) 684-7000

6.9.2	Historical Information

The Oriole Mine is a former zinc, lead, silver, copper, and gold mine located in the Metaline
mining district (Derkey 1990). The mine is reported to have produced in 1911,1912,1925,1926, (total
of 2,000 tons by 1942), and in 1953 (Derkey 1990). Smelter returns on a carload of handpicked ore were
42.1 ounces/ton silver, 21.9% zinc, 15.3% lead, and 1.12% copper (Derkey 1990). Historical ownership
information for the Oriole Mine from the time of patent to the present is unknown.

6.9 J Mine Description/Features

The Oriole Mine is accessed by the Oriole Road; a dirt road approximately 2 miles south of the
town of Metaline, Ore is localized in a northwest-trending gouge-breccia seam (Derkey 1990). Ore
bodies are a series of elongated-down-dip lenses along the fault plane; they are connected by a narrow

IO;START-2«I080009^S714

6-11

-------
0049

quartz stringers (Derkey 1990). Mineralization occurs in the Proterozoic Monk Formation of the
Windermere Group (Derkey 1990).

6.9.4	START-2 Mine Visit

On June 27,2001, the START-2 visited the Oriole Mine and conducted a visual inspection of the
property and surrounding area (Figure 6-3; Appendix C; Team 2, Pages 23 and 24). The mine consisted
of an upper adit which has been gated approximately 15 feet from the opening (Appendix A; Photos
12-16 through 12-23,13-2, and 13-10). Five waste rock piles were present. The largest waste rock pile
measured 25 feet long by 15 feet wide by 4 feet deep. A spring begins 20 feet from the adit (PPE 1) and
flows approximately 75 feet where it reaches the waste rock pile (PPE 2) and continues into a muddy
area with no outflow. PPE 3 is a potential overland flow from the muddy area to Linton Geek. The
START-2 estimated spring flow at 32 gpm. The northern portion of the mine consisted of a waste rock
pile covered with soil. The covered waste rock pile measured 35 feet by 55 feet by 2 feet deep.

6.9.5	Sample Locations

A co-located surface water and sediment sample (ORSPOISW and ORSP01SD) was collected
approximately 13 feet downstream from where the spring flows to the surface. Another sediment sample
(ORSP02SD) was collected below the covered waste rock pile in the northern portion of the mine.

Sample locations are depicted in Figure 6-4.

i

6.9.6	Analytical Results

6.9.6.1	Surface Water Sample Results

Sample results are summarized in Table 6-3. Zinc was detected above the Ecotox Screening
Threshold benchmark at 102 micrograms per liter 0*g/L).

6.9.6.2	Sediment Sample Results

Sample results are summarized in Table 6-4. Cadmium was detected at significant
concentrations in ORSP01SD and ORSP02SD at 8.5 mg/kg and 27 mg/kg, respectively. Lead was
detected at significant concentrations in ORSP01SD and ORSP02SD at 301 mg/kg and 714 mg/kg,
respectively. Manganese was detected at significant concentrations in ORSP01SD and ORSP02SD at
4,210 mg/kg and 2,230 mg/kg, respectively. Silver was detected at significant concentrations in

10:START-2\Q1080009\S714

6-12

-------
0050

ORSPOISD and ORSP02SD at 2.8 rng/kg and 5.6 mg/kg, respectively. Zinc was detected at significant
concentrations in ORSPOISD and ORSP02SD at 784 mg/kg and 5,740 mg/kg, respectively.

6.10 JOSEPHINE MINE

6.10.1 Mine Location

Latitude:

Longitude;

Legal Description:

pEiin to ttv
L-ilrKL/LIj JUL).

County:

Mine Owner/Contact:

6.10.2 Historical Information

' The Josephine Mine is a former zinc, lead, silver, and cadmium mine located in the Metaline
mining district (Derkey 1990). Reported alternative names for the Josephine Mine include Clark Mine
and Hortense Mine (Derkey 1990). The mine is reported to have produced 40,000 tons of ore valued at
$275,000 prior to 1919,243,000 tons between 1920 and 1935, and from 1936 through 1955
(Derkey 1990). Production was 187,000 tons in 1948 and 273,520 tons in 1951 (Derkey 1990).
Historical ownership information for the Josephine Mine from the time of patent to the present is
unknown. Currently, Teck Cominco American Inc. maintains a prospecting lease for the Josephine Mine
property through 2005 (Godlewski 2001).

6.103 Mine Description/Features

The Josephine Mine is part of the mining properties of Pend Oreille Mines, and information is
sometimes combined for these two deposits (Derkey 1990). The portal for the Pend Oreille Mine/Mill is
located on the east side of the Pend Oreille River and for the Josephine Mine on the west side of the river
(Derkey 1990). Ore occurs as irregular bodies of sphalerite and galena in a zone 35 to 150 feet below the
upper contact of the Metaline Formation (Derkey 1990). Ore minerals (sphalerite is generally dominant)
are most commonly in brec dated dolomite gangue (Derkey 1990). The ore is disseminated in silicified
dolomite, especially in brecciated zones cemented by calcite (Derkey 1990). Known ore bodies are

48° 52' 48.00"N
117° 22' 15.96"W

NV4SEV4 Section 16, Township 39N, Range 43E
WAN001002322
Pend Oreille

Teck Cominco American Inc.

Contact: David Godlewski
15918 East Euclid Avenue
Spokane, Washington 99216-1816
(509) 892-2584

10:START-2\01080009\S714

6-13

-------
0051

similar in size to those at the Pend Oreille Mine/Mill and range up to 5,000 feet long, 700 feet wide, and
100 feet thick (Derkey 1990). Ore at the Josephine Mine and adjacent deposits occurs in the
carbonaceous and locally siliceous breccia called the Josephine horizon of the Metaline Formation
(Derkey 1990). The horizon occurs within about 35 to 200 feet of the top of the Middle Cambrian to
Middle Ordovician Metaline Formation beneath the Ledbetter Slate (Derkey 1990).

6.10.4	START-2 Mine Visit

On June 26, 2001, the START-2 visited the Josephine Mine and conducted a visual inspection of
the property and surrounding area (Figure 6-5; Appendix C; Team 3, Page 28). The mine area consisted
of a shaft, a waste rock pile, a small building, and a collapsing wood structure (Appendix A; Photos 7-10
through 8-3). The mine is located directly across the Pend Oreille River from the waste rock at the Pend
Oreille Mine/Mill. The shaft is surrounded by an 8 foot barbed-wire-topped chain-link fence. The shaft
was filled with water approximately 25 feet from the surface. The shaft also contained wood debris that
resembled rail lines. Approximately 2 feet southwest of the collapsing wood structure a spring was
observed (PPE 1). The spring was estimated to be flowing at 2 to 3 gpm. The waste rock pile measured
60 feet long by 10 feet high by 2 feet deep. The waste rock pile extended into the Pend Oreille River
(PPE 2).

6.10.5	Sample Locations

i

A sediment sample (JOPP01SD) was collected at the PPE 2 of the waste rock into the Pend
Oreille River (Figure 6-6). A surface water sample, JOSP01SW, was collected at the mouth of the spring
which originates approximately 2 feet south of the wooden structure and feeds into the Pend Oreille
River. A co-located sediment sample was not collected due to lack of sediment.

6.10.6	Analytical Results

6.10.6.1 Surface Water Sample Results

Sample results are summarized in Table 6-5. Lead (21.5 /ig/L) and zinc (117 ftg/L) were detected
at significant concentrations in sample JOSP01SW.

10:START-2\Q108Q009\S714

6-14

-------
0052

6.10.6.2 Sediment Sample Results

Sample results are summarized in Table 6-6. Cadmium (9.6 mg/kg), lead (17,400 mg/kg),
mercury (0.16 mg/kg), silver (2.3 mg/kg), and zinc (2,040 mg/kg) were detected at significant
concentrations in JOPPOISD.

6.11 GRAND VIEW MINE/MILL
6.11.1 Mine/Mill Location

Latitude:	48° 52' 22.04"N

Longitude:	117° 21'26.16"W

, Legal Description:	Sections 14,15,22, and 30, Township 39N, Range 43E

CERCLIS ID:	WASFN1002165

County:	Pend Oreille

Owner/Contact:	Mr. Arlen Looney

Washington Resources
P.O. Box 69
Greenacres, WA 99016
(509) 534-0266

The inactive Grandview lead-zinc mine/mill is located in the lower Pend Oreille River Valley
approximately 0.75 mile from the east bank of the Pend Oreille River, approximately 2 miles northeast of
Metaline Falls, Washington (Figure 6-7).

In October 2000, E & E conducted field sampling activities at the Grandview Mine/Mill. The
combined PA/SI activities were conducted under TDD Nos. 00-06-0001 and 01-01-0015 issued under
EPA Region 10 START Contract Nos. 68-W6-0008 and 68-S0-01-01, respectively.

The PA/SI involved collection of samples from potential hazardous substance sources on the

«

property and from target areas potentially impacted through contaminant migration. Forty-one samples
were collected for the Grandview Mine PA/SI, including background and QA samples (one rinsate).
Samples were analyzed for TAL metals, SVOCs, PCBs and the Gamma spectroscopy method was
applied.

Analytical results of samples collected during the October 2000 field event can be found in the
Grandview Mine PA/SI report prepared by E & E for EPA, dated June 2001. The Grandview Mine
PA/SI report also includes facility background information, a discussion of field sampling activities and
analytical protocols, analytical results and background sampling, QA/QC criteria, potential sources,
migration/exposure pathways and targets.

10:START-2\01080009\S714

6-15

-------
0053

In summary, samples were collected from three soil source areas including the tailings pile,
waste rock piles, and the abandoned container and drum area on the property (Figure 6-8). The soil
sources contained significant concentrations of TAL metals. The tailings pile samples contained
significant concentrations of cadmium (58.4 mg/kg), copper (91.5 mg/kg), lead (2,260 mg/kg), mercury
(1.7 mg/kg JL), selenium (1.1 mg/kg), and zinc (19,100 mg/kg).

The waste rock samples contained significant concentrations of arsenic (44.0 mg/kg), cadmium
(23.3 mg/kg), lead (4,930 mg/kg) mercury (1.5 mg/kg) selenium (1.5 mg/kg), and zinc (7,420 mg/kg).

The abandoned container and drum area soil contained significant concentrations of arsenic (64.9
mg/kg), cadmium (99.5 mg/kg), copper (236 mg/kg), lead (14,600 mg/kg), mercury (6.0 mg/kg), selenium
(3.0 mg/kg), and zinc (36,200 mg/kg).

Samples were collected from suspected targets along potential groundwater migration, surface
water migration, and soil exposure pathways including groundwater wells, Pend Oreille River, an
unnamed spring, and a former wastewater drainage ditch (Figures 6-9 and 6-10).

Elevated concentrations were detected in the Pend Oreille Village groundwater samples,
including arsenic (23.4 /xg/L), manganese (245 /ig/L), selenium (5.1 /ig/L), and zinc (125 fig/L).

No elevated concentrations were detected in the Pend Oreille River surface water samples.
Cadmium (1.4 mg/kg), copper (28.2 mg/kg), lead (827 mg/kg), and zinc (1,090 mg/kg) were detected at
elevated concentrations in the Pend Oreille River sediment samples.

Elevated concentrations were detected in the unnamed spring surface water samples, including
arsenic (10.4 /ig/L), lead (1,340 fig/L), manganese (101 /xg/L), selenium (6.7 /ig/L), and zinc (547 /ig/L).
Elevated concentrations were detected in the unnamed spring co-located sediment samples including
cadmium (63.9 mg/kg), chromium (25.2 mg/kg), copper (120 mg/kg), lead (11,800 mg/kg) selenium (2.4
mg/kg), thallium (4.9 mg/kg), and zinc (19,800 mg/kg).

Elevated concentrations were detected in the former wastewater drainage ditch surface soil
samples including arsenic (31.2 mg/kg), cadmium (41.8 mg/kg), chromium (133 mg/kg), copper (3,730
mg/kg), lead (43,000 mg/kg), mercury (3.9 mg/kg), selenium (6.4 mg/kg), silver (7.4 mg/kg), and zinc
(12,100 mg/kg).

Radionuclide data were evaluated with respect to measured background concentrations. For
radionuclide data, results normally are considered elevated or significant when the sample concentration
exceeds the value of two standard deviations above the mean site-specific background concentration for
that radionuclide. However, only one background sample was required to meet the DQOs identified for
the Grandview Mine PA/SL Further, additional background samples are necessary to define the

10:START-2\01080009\S714

6-16

-------
0054

variability of the background population to accurately determine if radionuclides from the Grandview
Mine/Mill are impacting identified targets. To date, there is no conclusive evidence suggesting off-site
contamination from radionuclides present at Grandview Mine/Mill. The data collected previously for the
Grandview Mine/Mill site can be found in the Grandview Mine PA/SI report prepared by E & E for EPA,
dated June 2001.

6.11.2 Sample Locations

During the June 2001 field event, two co-located surface water and sediment samples were
collected at the PPEs of Grandview Mine/Mill (GMPP04SW/SD [PPE 1] and GMPP05SW/SD [PPE 2])
in between the Pend Oreille Mine/Mill and the co-located background sample POBKOISW/SD
(Figure 6-12).

6.11 J Analytical Results

6.11.3.1	Surface Water Sample Results

Sample results are summarized in Table 6-7. Lead was detected at a significant concentration in
GMPP05SW at 4.1 /xg/L, Manganese was detected at a significant concentration in GMPP05SW at

v	'

25.5 ngfL. Zinc was detected at a significant concentration in GMPP05SW at 20.6 fJ-g/L.

6.11.3.2	Sediment Sample Results

Sample results are summarized in Table 6-8. Cadmium was detected at a significant
concentration in GMPP05SD at 1.6 mg/kg. Lead was detected at a significant concentration in
GMPP05SD at 449 mg/kg. Zinc was detected at a significant concentration in GMPP05SD at 864 mg/kg.

6.12 PEND OREILLE MINE/MILL

6.12,1 Mine/Mill Location

Latitude:
Longitude:

Legal Description:
CERCLIS ID:
County:

WASFN1002160
Pend Oreille

NVi Sections 10,11,14, and 15, Township 39N, Range 43E

48° 52* 54.12"N
117° 21'36.00"W

10:START-2\01080009\S714

6-17

-------
0055

Owner/Contact:	Teck Cominco American Inc.

Contact: David Godlewski
15918 East Euclid Avenue
Spokane, Washington 99216-1816
(509) 892-2584

6.12,2 Historical Information

The Pend Oreille is an active zinc, lead, silver, and cadmium mine/mill located in the Metaline
mining district (Derkey 1990). The Pend Oreille Mine/Mill is a collective name for several properties
(Derkey 1990). Production in 1915 was 3,111 tons valued at $8.76 per ton from the Clark Property
(Derkey 1990). The mine produced 123,751 tons of ore in 1948 and 186,955 tons were produced in 1949
(Derkey 1990). Yield from 186,197 tons of ore in 1950 was 9,580,731 pounds of zinc, 6,336,653 pounds
of lead, 18,000 ounces of silver, and 30,000 pounds of cadmium (Derkey 1990). Yield from 273,580
tons of ore in 1951 was 12,950,584 pounds of zinc, 6,045,914 pounds of lead, and 16,041 ounces of
silver (Derkey 1990). The Pend Oreille Mine/Mill produced 5,451,328 tons of ore through 1956 (Derkey
1990). Drilling for ore in the Yellowhead horizon began in the late 1960s and the mine produced from
both the Josephine and Yellowhead horizons until it closed in the late 1970s (Derkey 1990). The focus
for reopening the mine (1990) is mineralization from the Yellowhead horizon, which is rich in zinc and
contains more pyrite than Josephine horizon ores (Derkey 1990).

The Pend Oreille Mine/Mill is located about 2 miles north of the town of Metaline Falls and
approximately 80 miles north of Spokane in northeastern Washington State. The mine is about 11 miles
south of the International Border and about 15 miles west of the Idaho border. The property is located
within portions of Sections 10,11, 14, and 15; Township 39N; Range 43E (Ecology 2000).

Ownership of the Pend Oreille Mine/Mill dates back to 1904, when L.P. Larsen began
prospecting in this location. In 1906, Pend Oreille Mines & Metals Company was incoiporated and L.P.
larsen became the president (Lasmanis 1995). The Pend Oreille Mine/Mill was owned and operated by
Pend Oreille Mines & Metals Company until 1974, when the Bunker Hill Company acquired the property
and operations. The Bunker Hill Company operated the mine and mill until September 1977, when the
property was acquired by Pintlar Corporation (Pintlar), a wholly-owned subsidiary of Gulf Resources &
Chemical Corporation (GRC). In 1988, Resource Finance Corporation (RFC) obtained an
option-purchase agreement from Pintlar, de-watered the mine, and commissioned a feasibility study for
mining and milling the East Side Yellowhead deposit. In May 1990, RFC purchased the mine and mill
along with 13,000 acres of contiguous mineral holdings in the district (Ecology 2000). In 1996, Cominco
American, Inc. (Cominco) acquired a portion of this property, including the Pend Oreille Mine/Mill, from

lQ*.START-mi080Q09\S7U

6-18

-------
0056

RFC (Ecology 2000). Cominco American Inc. was bought out by Teck Cominco American Inc.

(Hallinan 2001).

The Perid Oreille Mine/Mill property is included in the 580 acres of Teck Cominco American
Inc.-owned or leased surface lands (including mineral rights) and 980 additional acres of mineral rights in
this area (Ecology 2000). The Pend Oreille Mine/Mill is bounded on the west by Pend Oreille River, on
the north and northeast corner by Colville National Forest lands, on the east by privately-owned lands,
and on the south by State Route 31 and the Grandview Mine/Mill property (USGS 1992a, 1992b).

6.123 Mine/Mill Description/Features

Information for several deposits is combined into this single mine record (Derkey 1990).
Properties are on the east and west sides of the Pend Oreille River (Derkey 1990). Most production at
the Pend Oreille Mine/Mill was from irregularly shaped bodies of sphalerite and galena in a zone called
the Josephine horizon, 35 to 200 feet below the contact of the Metaline Formation with the overlying
Ledbetter Slate (Derkey 1990). The Yellowhead ores occur about 1,000 feet below the upper contact of
the Metaline Formation (Derkey 1990). Ore minerals (sphalerite generally dominant) are most
commonly in brecciated dolomite gangue (Derkey 1990). Ore bodies range up to 5,000 feet long, 700
feet wide, and 100 feet thick (Derkey 1990). Ore at the Pend Oreille Mine/Mill and adjacent mines
occurs in a carbonaceous and locally siliceous breccia called the Josephine horizon of the Metaiine
Formation (Derkey 1990). The horizon lies within 35 to 200 feet of the top of the Middle Cambrian to
Middle Ordovician Metaline Formation beneath the Ledbetter Slate (Derkey 1990).

The Pend Oreille Mine/Mill was one of the earliest, largest, and most productive mines in the
Metaline mining district, accounting for over 50% of the lead and zinc production in the area
(Ecology 2000).

Two ore horizons are present at the Pend Oreille Mine/Mill, the Josephine and the Yellowhead.
The Josephine Horizon is found in the upper 500 feet of the Metaline Limestone, or about 1,600 feet
below the surface. The Yellowhead Horizon is beneath the Josephine Horizon and is generally found
from 1,000 to 2,400 feet beneath the top of the Metaline Limestone (Ecology 2000).

The primary method for extracting ore in the Metaline Mining District, including the Pend
Oreille Mine/Mill, has been underground mining. Historically, most ore extraction was from the
Josephine Horizon, which is exposed at the surface at Pend Oreille River. This horizon has been mostly
mined out. (Ecology 2000)

10:START-2\01080009\S714

6-19

-------
0057

Mining in the area by the Pend Oreille Mines & Metals Company was on a small scale during the
early years, beginning on the Josephine claim with near-surface deposits on the west side of Pend Oreille
River; mining continued here intermittently from 1904 until 1917 (Dings and Whitebread 1965). In
1917, a table concentration mill was constructed and operated for a few months, but was shut down
during World War I. There was little activity for the next 10 years. (Ecology 2000)

In 1927, the old table mill was remodeled to a flotation plant which operated on surface ores at
150 tons per day for approximately six months. In 1928, Pend Oreille Mines & Metals Company began
additional deeper development of the area; a program of extensive diamond drilling from 1928 to 1930
disclosed promising ore bodies. With a 300-ton flotation mill completed in anticipation of treating this
ore, mining resumed in November 1930 and continued intermittently until 1937. The underground
workings were developed, with ore hauled to the surface through a network of track haulage drifts and
inclined shafts. In September 1937, a power plant on the Pend Oreille River was completed, the mill was
overhauled, and production was increased to approximately 600 tons per day (Lambly 1941;

Zeigler 1949; Dings and Whitebread 1965).

Subsequent workings on the Josephine Horizon were conducted eastward and downward,
crossing under the river in the 1940s. Approximately 14.4 million tons of ore at 1.2% lead and % zinc
were removed from this horizon between 1938 and 1977 (RFC 1993).

Mining of the Yellowhead Horizon on the east side of the river began in 1972 at an elevation
about 650 to 900 feet below the Josephine workings. Only 387,000 tons of ore containing 0.5% lead and

i

4.0% zinc were removed from this horizon prior to closure of the mine in 1977. Since 1977, there have
been no mining operations other than a development program (Lasmanis 1995; Godlewski 2000).

Prior to 1967, tailings from the milling operation—the finely ground sand and silt material
remaining after the target minerals have been separated during beneficiation—were disposed of directly
into Pend Oreille River. Beneficiation includes those activities that serve to separate and concentrate the
mineral values from waste material, remove impurities, or prepare the ores for further refinement
(EPA 2000b). An estimated 3,000 tons of tailings were discharged to Pend Oreille River each day of
milling operations in 1962 (Neale 1962). After 1967, three upland tailings disposal facilities (TDFs)
were used to dispose of the tailings. TDF No. 1 (TDF-1), which is located 2,400 feet northeast of the
mill and west of the Metaline Falls Golf Course and Gun Club, covers approximately 24 acres. This
facility was used from 1967 through 1974. TDF No. 2 (TDF-2), which is located between the golf course
and TDF-1, covers approximately 25 acres; this facility was used during 1974 and 1975. Tailings in
these two TDFs are comprised of material from the Josephine Horizon workings (Ecology 2000).

10;START-2\fl IQ8Q009V5714

6-20

-------
0058

TDF No. 3 (TDF-3) is located south of the golf course and covers approximately 20 acres.
TDF-3 was operated from 1975 until the mine closed in 1977. The tailings in this facility are
approximately 40 feet deep at the deepest point and are comprised primarily of material from the
Yellowhead Horizon workings (Ecology 2000). Pend Oreille River is approximately 3,500 feet west of
TDF-3.

Historically, waste rock—the waste material consisting of non-mineralized and low-grade
mineralized rock removed from, around, or within the orebody during extraction activities—was stored
underground during early operations. From 1950 to 1977, waste rock from both the Josephine and
Yellowhead horizons, as well as Ledbetter Slate, was removed from the mine by conveyors from the
Josephine Horizon to the surface, and stored in the waste rock pile located 150 feet south and west of the
mill. Most of the waste rock has a low pyrite content and consists of carbonate material (limestone and
dolomite) removed from above and below the ore horizons that were mined. Some of the waste rock
brought to the surface was sold and used locally as road material or in construction from at least the
mid-1970s until the early 1990s (Ecology 2000). The waste rock was used as a road construction base,
subbase, and surface material; for private driveways; as parking lot material at Gardner Cave State Park;
and as backfill by the county (Ecology 2000). The total amount of waste rock used for these purposes is
unknown. The waste rock pile currently consists of approximately 386,000 cubic yards of waste rock,

		 1	a. 1 e	rr>	i 		aaaa\

aim wvcia auuui u acres (.ccuiugy zuwj.

Between 1977 and 1986, Bunker Hill Company, Pintlar, and GRC continued exploration in the
area and operated pumps to prevent flooding of the mine by underground water. The mine water was
discharged into Pend Oreille River. The mine was allowed to flood between 1986 and 1988, at which

time development ceased (Ecology 2000).

\

After purchasing the property in 1990, RFC submitted a proposal to Ecology in 1992 to reopen
the mine, and submitted a State Environmental Policy Act (SEPA) checklist for the proposed project in
February 1993. Ecology reviewed the SEPA checklist and issued a "Determination of Non-Significance"
in April 1993. RFC then submitted several applications to Ecology to obtain permits required to reopen
the mine. By 1994, RFC had obtained four permits (stormwater discharge, dam safety, septic system,
and air quality) and was close to receiving two others (National Pollutant Discharge Elimination System
[NPDES] and waste discharge) when RFC decided to cancel the project. The following permits are
maintained: NPDES, Waste Identification, Stormwater General, Ground Water, State Dangerous Waste
Conditional Exemption, and Dam Safety (Godlewski 2001).

10:START-2\01080009\S714	' 6-21

-------
0053

Hazardous materials used during earlier mining operations and stored on the Pend Oreille
Mine/Mill property were removed from the site during RFC's tenure in 1992. These wastes included
PCB oil-cooled transformers and capacitors, as well as soils containing PCBs (Ecology 2000). The data
reviewed did not specify waste quantities or disposal locations. Oil, lubricants, light fuels, antifreeze,
and herbicides are reportedly the only hazardous materials currently stored on site. The materials are
stored in a shed located between the administrative office and the machine shop.

Having acquired the property in 1996, Cominco submitted a Statement of Proposal Pend Oreille
Mine, Pend Oreille County, Washington, to Ecology on January 29, 1998, in order to reopen the mine.
Based on the proposal, Ecology determined that an Environmental Impact Statement (EIS) would be
required before the mine could be reopened (Ecology 2000). The EIS was finalized on July 12, 2000
(Hallinan 2002).

The Pend Oreille Mine/Mill owner, Teck Cominco American Inc., has finished earthwork for its
tailings disposal facility this past year. Teck and Cominco merged in mid year 2001 forming Teck
Cominco American Inc. This includes the basin floor, construction of the tailings embankment to form a
closed basin and contouring the side slopes to a uniform grade. The work has been completed under
permit from Ecology. The liner system for the TDF will be constructed in 2002 or 2003. Two raises, or
small shafts, have been constructed to surface for air control of the mine. These are located between the
mine and the lower road as per the EIS. The foundation for the concentrate load-out building along the
west side of the mill has been constructed. The new powerline from Highway 31 has been installed and
electrical service upgraded to specifications. Fencing and gates have been installed to limit access to the
TDFs and the mine. The company plans to re-start mining and milling operations in January 2004. Teck
Cominco American Inc. is continuing to dewater the mine workings, under their NPDES permit. There is
exploration occurring underground in the mine shaft to the ore body. (Hallinan 2001, Godlewski 2001).
The onsite well is being used by the mine. It has been permitted for use by the Washington Department
of Health as a Group B Water System identification number 08269Y, under Department of Health
identification number 01-0804.

6.12.4 START-2 Mine Visit

On June 25 and 26,2001, the START-2 visited the Pend Oreille Mine/Mill and conducted a
visual inspection of the property and the surrounding area (Figure 6-11; Appendix C; Team 2, Pages 15
and 16; Team 3, Page 27; Project Management, Logbook 15, Pages 6 through 19; Boat Team, Pages 4
through 11)

10:START-2\0!080009\S714

6-22

-------
0060

Existing Pend Oreille Mine/Mill facilities on the east side of the river include the mine office
building, maintenance shop/blacksmith shop/surface conveyor/portal, coarse and fine ore storage silos,
mill, assay office building, and storage facilities (Figure 6-12).

The mine office building is a two-story reinforced concrete frame structure with concrete block
walls. The building has 5,500 square feet per floor. The lower floor is used for offices, accounting, and
lab facilities; the upper floor is used for storage, a training room, and two offices.

The maintenance shop/blacksmith shop is a 10,500-square-foot, 30-foot-high, reinforced concrete
building with a flat roof. The conveyor that carries the ore to the coarse ore storage silo is an elevated,
steel-frame, integral truss structure supported on steel bents. The shop contains machinery, tools,
welding equipment, electrical equipment, lubricants, and chemicals.

Two coarse ore and three fine ore storage silos are on the property. The capacity of each ore silo
is approximately 1,000 tons.

The mill is a four-story concrete block building with steel interior framework. Mill equipment
includes three primary head ball mills, two regrind ball mills, flotation cells, lead and zinc thickeners,
stock tanks, a water filter, and a concentrate storage area. The assay office building consists of a lower
story used for storage, and an upper story containing laboratory facilities.

Other buildings on the mine property include storage sheds; a powder magazine; a make-up
house; a car baWearpenLer shop; a core storage shed; a crusher building; an upper, main, and miii
substation; and a compressor house.

A waste rock pile from historic mining activities is located just southeast of the ore storage silos
and mine office (Appendix A; Photos 1-22 through 2-5). Three TDFs from historic mining activities are
located on the mine property. The Metaline Falls Golf Course and Gun Club is also located within the
property boundary, just east of TDF-2 (Ecology 2000).

6.12 J Sample Locations

Samples were collected at sources, including the waste rock pile and three tailings piles, targets
discussed in Section 7 of this report, and four PPEs (Figure 6-12).

Three waste rock samples (POWP01SS through POWP03SS) were collected from the waste rock
pile located adjacent to the Pend Oreille River on the south end of the property. The samples were
collected within the overland surface water drainage routes identified by the START-2. The samples
were collected to determine potential contamination associated with this source. The samples appeared
to consist of dark gray and brown rocks. No odor or staining was noted during the sample collection.

10:START-2\Q1080Q0?WS714

6-23

-------
0061

Three surface soil samples were collected at each tailings pile for a total of 9 surface soil
samples. Three surface soil samples (POTPOISS through POTP03SS) were collected at TDF-1, three
surface soil samples (POTP04SS through POTP06SS) were collected at TDF-3, and three surface soil
samples (POTP07SS through POTP09SS) were collected at TDF-2. Soil from TDF-1 was uniform and
appeared to consist of moist, gray clay with waste rock. No soil odor or staining was noted during the
sample collection. Soil from TDF-3 was uniform and appeared to consist of dry, white and dark brown
sand and tailings. No soil odor or staining was noted during the sample collection. Soil from TDF-2 was
uniform and appeared to consist of dry, fine gray and dark brown sand and tailings. No soil odor or
staining was noted during the sample collection.

PPE 1 (POPPOISW) was collected at the ventilation shaft which flows approximately 1,260 feet
in a northwest direction towards the Pend Oreille River.

PPE 2 (POPP02SW and POPP02SD) was collected from the Pend Oreille River near two seep
areas located by TDF-2 and TDF-3. The water in these seeps appears to originate from hill slopes and
from TDF-2. This seepage is collected in diversion channels and routed around and to the base of
TDF-1, where it meets with natural seepage. This water then flows downslope (Creek 2) and drains into
Pend Oreille River (PPE 2). Surface water runoff from TDF-1 and TDF-2 drains into installed diversion
ditches which drain into Pend Oreille River. (Ecology 2000)

PPE 3 (POPP03SW and POPP03SD) was collected in the surface water drainage runoff from the

waste rock which drains by sheet flow into the confluence of Flume Creek and the Pend Oreille River.

!

Potential PPE 4 was identified at the confluence of Creek 1 to the Pend Oreille River where

tailings and other contaminants potentially drained in historic operations.

!

6.12.6 Analytical Results
6.12.6.1 Surface Soil Sample Results

Sample results are summarized in Table 6-9. In the waste rock pile, arsenic was detected at
significant concentrations in POWP02SS and POWP03SS at 21.8 mg/kg and 35.1 mg/kg, respectively.
Cadmium was detected in the waste rock pile at significant concentrations in POWPOISS, POWP02SS,
and POWP03SS at 4.0 mg/kg, 34.2 mg/kg, and 44.1 mg/kg, respectively. Lead was detected in the waste
rock pile at significant concentrations in POWPOISS, POWP02SS, and POWP03SS at adjusted
concentrations of 2,090 mg/kg, 5,625 mg/kg, and 4,188 mg/kg, respectively. Mercury was detected in the
waste rock pile at significant concentrations in POWP02SS and POWP03SS at 0.16 mg/kg and 0.19
mg/kg, respectively. Selenium was detected in the waste rock pile at significant concentrations in

10: START-2N01080009XS7 ] 4

6-24

-------
u woe

POWPOISS and POWP03SS at 3.1 mg/kg and 1.7 mg/kg, respectively. Zinc was detected in the waste
rock pile at significant concentrations in POWPOISS, POWP02SS, and POWP03SS at 890 mg/kg, 7,420

I

mg/kg, and 9,300 mg/kg, respectively.

In TDF-1, arsenic was detected at a significant concentration in POTPOISS at 20.6 mg/kg.
Cadmium was detected in TDF-1 at significant concentrations in POTPOISS and POTP03SS at 15.0
mg/kg and 9.2 mg/kg, respectively. Copper was detected in TDF-1 at a significant concentration in
POTPOISS at an estimated 176 mg/kg JL. Lead was detected in TDF-1 at significant concentrations in
POTPOISS and POTP03SS at 680 mg/kg and 467 mg/kg, respectively. Mercury was detected in TDF-1
at significant concentrations in POTPOISS and POTP03SS at 0.25 mg/kg and 0.16 mg/kg, respectively.
Zinc was detected in TDF-1 at significant concentrations in POTPOISS and POTP03SS at adjusted
concentrations of 2,753 mg/kg and 1,460 mg/kg, respectively.

In TDF-3', arsenic was detected at significant concentrations in POTP05SS and POTP06SS at
40.0 mg/kg and 20.8 mg/kg, respectively. Cadmium was detected in TDF-3 at significant concentrations
in POTP04SS, POTP05SS, and POTP06SS at 8.5 mg/kg, 8.2 mg/kg, and 11.9 mg/kg, respectively.

Copper was detected in TDF-3 at significant concentrations in POTP04SS and POTP06SS at estimated
concentrations of 90.0 mg/kg JL and 178 mg/kg JL, respectively. Lead was detected in TDF-3 at
significant concentrations in POTP04SS, POTP05SS, and POTP06SS at 666 mg/kg, 1,650 mg/kg, and
8i8 mg/kg, respectively. Mercury was detected in TDF-3 at significant concentrations in POTF04SS,
POTP05SS, and POTP06SS at 0.15 mg/kg, 0.10 mg/kg, and 0.18 mg/kg, respectively. Silver was
detected in TDF-3 at a significant concentration in POTP05SS at 2.3 mg/kg. Zinc was detected in TDF-3
at significant concentrations in POTP04SS, POTP05SS, and POTP06SS at adjusted concentrations of
1,060 mg/kg, 1,667 mg/kg, and 1,680 mg/kg, respectively.

In TDF-2, arsenic was detected at significant concentrations in POTP07SS, POTP08SS, and
POTP09SS at 26.4 mg/kg, 22.4 mg/kg, and 21.1 mg/kg, respectively. Cadmium was detected in TDF-2 at
significant concentrations in POTP07SS, POTP08SS, and POTP09SS at 30.4 mg/kg, 20.1 mg/kg, and
10.4 mg/kg, respectively. Copper was detected in TDF-2 at significant concentrations in POTP07SS,
POTP08SS, and POTP09SS at estimated concentrations of 242 mg/kg JL, 113 mg/kg JL, and 88.0 mg/kg
JL, respectively. Lead was detected in TDF-2 at significant concentrations in POTP07SS, POTP08SS,
and POTP09SS at 1,760 mg/kg, 1,000 mg/kg, and 919 mg/kg, respectively. Mercury was detected in
TDF-2 at significant concentrations in POTP07SS, POTP08SS, and POTP09SS at 0.58 mg/kg, 0.25
mg/kg, and 0.16 mg/kg, respectively. Zinc was detected in TDF-2 at significant concentrations in

10:START-2\01080009\S714

6-25

-------
0063

POTP07SS, POTP08SS, and POTP09SS at adjusted concentrations of 4,360 rag/kg, 3,027 rag/kg, and
1,513 rag/kg, respectively.

6.12.6.2	Surface Water Sample Results

Sample results are summarized in Table 6-10. Barium was detected at a significant concentration
in POPP03SW at 62.6 /ig/L. Lead was detected at significant concentrations in POPP01SW and
POPP02SW at 8.7 ng/L and 9.3 ng/L, respectively. Manganese was detected at a significant
concentration in POPP02SW at 33.0 /ig/L. Zinc was detected at significant concentrations in
POPP01SW and POPP02SW at 212 /ig/L and 62.5 ngfL, respectively.

6.12.6.3	Sediment Sample Results

Sample results are summarized in Table 6-11. Cadmium was detected at a significant
concentration in POPP02SD at 6.1 mg/kg. Lead was detected at a significant concentration in
POPP02SD at 346 mg/kg. Zinc was detected at a significant concentration in POPP02SD at
2,370 mg/kg.

6.13 YELLOWHEAD MINE

6.13.1	Mine Location

Latitude:	48° 52* 59.88"N

Longitude:	117° 22'14.16"W

Legal Description: NE'/i Section 16, Township 39N, Range 43E

CERCLIS ID:	WAN001002333

County:	Pend Oreille

Mine Owner/Contact: Teck Cominco American Inc.

Contact: David Godlewski
15918 East Euclid Avenue
Spokane, Washington 99216-1816
(509)892-2584

6.13.2	Historical Information

The Yellowhead Mine is a former zinc, lead, and silver mine located in the Metaline mining
district (Derkey 1990). The mine is reported to have produced prior to 1956 with a total production of
approximately 12,000 tons (Derkey 1990). Historical ownership information for the Yellowhead Mine
from the time of patent to the present is unknown.

10:START-2\01080009\S714

6-26

-------
0064

6.13.3	Mine Description/Features

Unlike mineralization oh the Josephine horizon at the adjacent Josephine deposit, mineralization
at the Yellowhead mine occurs on the Yellowhead horizon, about 1,000 feet from the upper contact of
the Metaline Formation (Derkey 1990), The mineralogy is the same as that at the Josephine; however,
the proportions are quite different (Derkey 1990). Pyrite arid sphalerite are the dominant minerals, and
galena is subordinate in the Yellowhead horizon ores (Derkey 1990).

6.13.4	START-2 Mine Visit

On June 26,2001, the START-2 visited the Yellowhead Mine and conducted a visual inspection
of the property and surrounding area (Appendix C; Team 3, Page 28). The mine area consisted of one
waste rock pile and a collapsed wood structure (Appendix A; Photos 8-4 and 8-5). The waste rock pile
measures 33 feet long by 25 feet high by 2 feet deep. An area of approximately 1,000 square feet behind
the collapsed wood structure was also covered with waste rock in a scattered formation. Samples were
not collected at this location because the origin of the waste rock could not be positively associated with
the Yellowhead Mine or the Gold Hill Mine located 0.1 mile west of the Yellowhead mine, which is not
a part of this field effort. The overland drainage route flowed approximately 600 feet into the Pend
Oreille River from the waste rock area. No residents were observed on the property.

6.14 HOAGE MINE
6.14.1 Mine Location

Latitude:	48° 56'57.48"N

Longitude:	117° 21' 18.00"W

Legal Description:	center S?4 Section 22, Township 40N, Range 43E

CERCLIS ID:	WAN001002321

County:	Pend Oreille

Mine Owner/Contact: United States Forest Service

Contact: Nora Rasure
765 South Main
Colville, Washington 99114
(509) 684-7000

10:START-2\01080009\S714

6-27

-------
0065

6.14.2 Historical Information

The Hoage Mine is a former zinc and lead mine located in the Metaline mining district (Derkey
1990). The reported alternative name for the Hoage Mine is the Dreadnaught-Emily Mine (Derkey
1990). Thirty tons of hand-sorted ore was piled at the mine portal in 1945, and 200 tons of lower grade
ore was stockpiled in 1951 (Derkey 1990). About 50 tons of hand-sorted ore was reportedly shipped to
the Pend Oreille Smelter (Derkey 1990). Historical ownership information for the Hoage Mine from the
time of patent to the present is unknown.

6.143 Mine Description/Features

Ore minerals are disseminated in silicified dolomite (Derkey 1990). Mineralized outcrops are
exposed in several places along a 1,200-foot strike length (Derkey 1990). Mineralization at the Hoage,
unlike that at the nearby Lead King deposit, occurs in gray limestone at a considerable distance
stratigraphically below the Josephine horizon (Derkey 1990).

6.14.4 START-2 Mine Visit

On June 28, 2001, the START-2 visited the Hoage Mine and conducted a visual inspection of the
property and the surrounding area (Appendix C; Team 3, Page 34). The mine area consisted of one waste
rock pile and one shaft (Appendix A; Photos 8-21 and 8-22). The shaft measured 6 feet across by 8 feet
wide with unknown depth (Appendix A; Photo 8-22). Water was present in the shaft 15 feet bgs. The

i

waste rock pile measured 30 feet by 30 feet by 1 foot deep. The START-2 did not observe any additional
surface water features at the mine including overland drainage routes. No residents were observed on the
property. No potential targets were observed on the property. Therefore, based on EPA TM guidance,
no samples were collected.

6.15 LUCKY STRIKE MINE

6.15.1 Mine Location

Latitude:
Longitude:

Legal Description:

48° 55' 49.80"N
117° 19'51.24"W

NW'/4 NEW Section 35, Township 40N, Range 43E

CERCLIS ID:
County:

WAN001002327
Pend Oreille

10:START-2»1080009\S714

6-28

-------
0066

Mine Owner/Contact: United States Forest Service

Contact: Nora Rasure
765 South Main
Colville, Washington 99114
(509) 684-7000

Bureau of Land Management
Contact: Joe Buesing
1103 North Fancher Road
Spokane, Washington 9921201275
(509) 536-1221

Teck Cominco American Inc.

Contact: David Godlewski
15918 East Euclid Avenue
Spokane, Washington 99216-1815
(509) 892-2584

6.15.2	Historical Information

The Lucky Strike Mine is a former zinc, lead, and iron mine located in the Metaline mining
district (Derkey 1990). A reported alternative name for the Lucky Strike Mine is the Buzzell Mine
(Derkey 1990). The mine is reported to have produced in 1922 and in 1925 (Derkey 1990). Historical
ownership information from the time of patent to the present is unknown.

6.15.3	Mine Description/Features

Mineralization occurs in a breccia zone as much as four feet in width (Derkey 1990). Parts of the
zone are nearly solid pyrite (Derkey 1990). Mineralization at the Lucky Strike Mine occurs in the
Yellowhead horizon, about 1,000 feet from the contact of the Metaline Formation with the overlying
Ledbetter Slate (Derkey 1990). The mineralogy of the Yellowhead horizon ore is the same as that of the
Josephine; however, the proportions are quite different, in the Yellowhead pyrite is dominant along with
galena and subordinate sphalerite (Derkey 1990). Ore samples indicate sulfide mineralization occurs in
the matrix of a dolomite breccia (Derkey 1990).

6.15.4	START-2 Mine Visit

On June 27, 2001, the START-2 visited the Lucky Strike Mine and conducted a visual inspection
of the property and surrounding area (Appendix C; Team 3, Page 30). The mine area consisted of one
dry adit and a shaft approximately 80 feet apart from each other (Appendix A; Photos 8-10

10:START-2\D1080009\S714

6-29

-------
0067

through 8-12). The shaft measured 6 feet in width by 8 feet in length by unknown depth. Less than a
1,000 cubic yards of waste rock was present surrounding the adit. The START-2 did not observe any
surface water features at the mine including overland drainage routes. Ho residents were observed on the
property. No potential targets were observed on the property. Therefore, based on EPA TM guidance,
no samples were collected.

6.16 LEAD KING MINE

6.16.1	Mine Location

Latitude:	48° 56* 16.44"N

Longitude:	117° 21'13.32"W

Legal Description:	Near center, Section 27, Township 40N, Range 43E

CERCLIS ID:	WANOO1002324

County:	Pend Oreille

Mine Owner/Contact: United States Forest Service

Contact: Nora Rasure
765 South Main
Colville, Washington 99114

(509) 684-7000

6.16.2	Historical Information

The Lead King Mine is a former lead, zinc, and silver mine located in the Metaline mining
district (Derkey 1990). A reported alternative name for the Lead King Mine is the D. Aldrich Mine
(Derkey 1990). It is reported that small quantities of shipments were made in 1917 to 1918 and in 1925
to 1926 0erkey 1990). On the Boundary Road north of Metaline Falls, and one mile west of the Pend
Oreille River, the Lead King Mine was one of the first locations on the west side of the Pend Oreille
River (Battien 1998). The mine had six claims and was up to ten when it became a Pend Oreille holding
(Battien 1998). Additional historical ownership information from the time reported to the present is
unknown.

6.163 Mine Description/Features

Mineralization occurs in quartz and dolomite breccia, is of low grade, and is confined to the
upper 100 feet of the Metaline Formation (Derkey 1990). Ore is irregularly distributed galena and
sphalerite associated with jasperoid, dolomite, and calcite in breccia zones (Derkey 1990).

10:START-Z\01080009\S714

6-30

-------
0068

Mineralization is from the Josephine horizon, 35 to 150 feet below the contact of the Metaline Formation
with the overlying Ledbetter Slate (Derkey 1990). At the Lead King Mine, the country rocks are
fine-grained gray limestone and large irregular bodies of gray to black crystalline dolomite
(Derkey 1990).

6.16.4 START-2 Mine Visit

On June 28,2001, the START-2 visited the Lead King Mine and conducted a visual inspection
of the property and surrounding area (Appendix C; Team 3, Page 35). The mine area consisted of two
adits with ponded water (Appendix A; Photos 8-23 and 8-24). Although ponded water existed at each
adit, neither adit was flowing at the time of the visit. Both of the adits are associated with waste rock
piles. The waste rock pile at adit 1 measured 30 feet by 30 feet by 1 foot deep (Appendix A; Photo 9-1).
The waste rpck pile at adit 2 measured 30 feet by 60 feet by 1 foot deep (Appendix A; Photo 8-25). The
START-2 did not observe any overland drainage routes from the adits to a water body. No residents
were observed on the property. No potential targets were observed on the property. Therefore, based on
EPA TM guidance, no samples were collected.

6.17 Z CANYON MINE

a 1^ t	¥	4*		1 n			'

/•! iTxiuc ijutauuu aiiu iscsci ipuuii

The Z Canyon Mine is a former lead, zinc, and gold mine located in the Metaline mining district
(Derkey 1990). The mine is located on the east side of the Pend Oreille River (Derkey 1990). The legal
description of the property is NWVi NWV4 Section 11, Township. 40N, Range 43E, Pend Oreille County,
Washington. The mine is reported to have produced a small amount of ore in 1926 (Derkey 1990). The
mineralized zone has been exposed for a length of 800 feet on the surface (Derkey 1990). The mine is in
coarse-grained dolomite, dolomite limestone, and strongly sheared limestone that is probably within the
upper 200 to 400 feet of the Metaline Formation (Derkey 1990).

6.17.2 START-2 Mine Visit

One June 27, 2001, the START-2 attempted to locate the Z Canyon Mine (Appendix C; Team 3,
Page 31). The START-2 followed directions given by a local resident who described where the mine
was located. Upon arrival, there were no visible signs of the Z Canyon Mine. It is possible the former
mine is now underwater from the creation of the Boundary Dam (Appendix A; Photo 8-13). No samples
were collected.

10:START-2\01080009\S714

6-31

-------
0063

6.18 LEAD QUEEN MINE

6.18.1	Mine Location and Description

The Lead Queen Mine is a former lead and zinc mine located in the Metaline mining district
(Derkey 1990). The legal description of the property is SE!4 Section 11, Township 40N, Rnage 43E,
Pend Oreille County, Washington. Most of the prospecting at the Lead Queen Mine was in a zone of
dolomite within 150 feet of an overlying gray limestone (Derkey 1990). Mineralization occurs in quartz
and dolomite breccia, is of low grade, and is confined to the upper 100 feet of the Metaline Formation
(Derkey 1990). Ore is irregularly distributed galena and sphalerite associated with jasperoid, dolomite,
and calcite in breccia zones (Derkey 1990).

6.18.2	START-2 Mine Visit

One June 27,2001, the START-2 attempted to locate the Lead Queen Mine (Appendix C; Team
3, Page 31). The START-2 followed directions given by a local resident who described where the mine
was located. Upon arrival, there were no visible signs of the Lead Queen Mine, other than a collapsed
wood structure (Appendix A; Photo 8-14). The START-2 did not observe any surface water features at
the property including overland drainage routes. No residents were observed on the property. No
potential targets were observed on the property. No samples were collected.

6.19 LEAD HILL MINE

6.19.1 Mine Location	!

Latitude:	48° 58* 12.72"N

Longitude:	117° 11'49.56"W

Legal Description: Sections 11,12,13, 22,23, 27, and SV2 NEVi Section 14, Township

CERCLIS ID:

40N, Range 44E
WAN001002323

County:

Mine Owner/Contact:

Pend Oreille

United States Forest Service
Contact: Nora Rasure
7665 South Main
Colville, Washington 99114
(509) 684-7000

10:START-2\01080009\S714

6-32

-------
0070

6.19.2 Historical Information

The Lead Hill Mine is a former lead, zinc, and silver mine located in the Metaline mining district
(Derkey 1990).1A reported alternative name for the Lead Hill Mine is the Bunker Hill Mine (Derkey
1990). The mine is reported to have produced one small carload of hand-picked galena that was shipped
in 1937 (Derkey 1990). The mine also milled 1,230 tons of ore in 1951 and 9,570 tons in 1952 (Battien
1998; Derkey 1990). By 1945, the Lead Hill Mine came under American Zinc holdings (Battien 1998).
Historical ownership information from the time reported to the present is unknown.

6.193 Mine Description/Features

The Lead Hill Mine is located on the upper portion of Slate Creek (Derkey 1990). The mine
consisted of 50 claims and had development including a compressor, shop buildings, and 100-ton ore
bins (Battien 1998). The ore zones at the Lead Hill Mine are horizontal and gently dipping (Derkey
1990). The countiy rock is chiefly Metaline Formation and minor Ledbetter Slate, indicating the mine is
near the Metaline-Ledbetter contact (Derkey 1990). The host dolomite is brecciated (Derkey 1990).

6.19.4 START-2 Mine Visit

On June 28,2001, the START-2 visited the Lead Hill Mine and conducted a visual inspection of
the property and surrounding area (Appendix C; Team 3, Page 33). The mine area consisted of three
adits with associated waste rock, one shaft, a concrete slab, and a collapsed wood structure (Appendix A;
Photos 8-15 through 8-18). The adits were dry and were located along Forest Service Road 300 with
waste rock on the hillside below the road. The waste rock was spread thinly over the entire property.
The waste rock was not sampled due to a lack of fine-grained material. Both adits and the shaft have
been contained with gates, which were installed by the USFS in 2000. The distance between adit 1 to
adit 2 is 300 feet. The distance between adit 2 and adit 3 is 20 feet. The distance from adit 3 to the shaft
is 225 feet. Adit 1 has a diameter of 10 feet and adit 2 and adit 3 both have a diameter of 5 feet. The
START-2 did not observe any overland drainage routes from the adits to a surface water body. No
residents were observed on the property. No potential targets were observed on the property. Therefore,
based on EPA TM guidance, no samples were collected.

10:START-2\01080009\S714

6-33

-------
0071

6.20	KING TUT MINE

6.20.1	Mine Location and Description

The King Tut Mine is a former lead, zinc, and silver mine located in the Metaline mining district
(Derkey 1990). The legal description of the property is Sections 2 and 11, Township 40N, Range 44E,
Pend Oreille County, Washington. It is reported that crude lead ore was shipped which yielded 83.4%
lead and 2.3 ounces/ton of silver (Derkey 1990). The deposit occurs in silicified limestone and has been
traced by open cuts for a length of 500 feet and a width of 8 feet (Derkey 1990).

6.20.2	START-2 Mine Visit

One June 28,2001, the START-2 attempted to locate the King Tut Mine (Appendix C; Team 3,
Page 34). The START-2 followed the Forest Service Road where the mine was located on a topographic
map. Upon arrival, there were no visible signs of the King Tut Mine (Appendix A; Photo 8-19). No
samples were collected.

6.21	RED TOP MINE

6.21.1	Mine Location and Descriptions

The Red Top Mine is a former lead and zinc mine located in the Metaline mining district
(Derkey 1990). The legal description of the property is Sections 1 and 2, Township 40N, Range 44E,
Pend Oreille County, Washington. The mine is reported to have produced 5 tons of crude lead ore
(Derkey 1990). The deposit is in silicified dolomite and has been exposed in open cuts for 1,500 feet
along the strike (Derkey 1990).

6.21.2	START-2 Mine Visit

One June 28,2001, the START-2 attempted to locate the Red Top Mine (Appendix C; Team 3,
Page 34). The START-2 followed the Forest Service Road where the mine was located on a topographic
map. Upon arrival, there were no visible signs of the Red Top Mine (Appendix A; Photo 8-20). No
samples were collected.

10:START-2\01080009\S714

6-34

-------




Table 6-1





BLUE BUCKET MINE SURFACE WATER SAMPLES

ANALYTICAL RESULTS SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS
PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS
PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

Ecotox Screening
Thresholds

Federal AWQC
Protection of

Aquatic
Organisms

01264268

01264270

CLP Inorganic ID





MJ0F13

MJ0F15

CLP Organic ID





NU

NU

E&E Sample ID





NU

NU

Station Location





BBPP01SW

BBPP02SW

Description

Background

Source



Calcium

NU

NU

84400 1

84800

Iron

NU

1000

54,6'U

125

Magnesium

NU

NU

15600 1

14500

Source: EPA 1996; Ecology 1997.

Note:	Bold type indicates the sample concentration is above the detection limit.

Key:

AWQC	= Ambient Water Quality Criteria.

BB	= Blue Bucket Mine.

CLP	= Contract Laboratory Program.

E&E	= Ecology and Environment, Inc.

EPA	= United States Environmental Protection Agency.

ID	= Identification.

Hg/L	= micrograms per liter.

NU	= Not utilized.

PP	b probable point of entry.

SW	= surface water,

TAL	= target analyte list

U	s The analyte was not detected. The associated numerical value is the contract required
detection limit

6-35

-------




Table 6-2







BLUE BUCKET MINE SEDIMENT SAMPLES





ANALYTICAL RESULTS SUMMARY



LOWER PEND OREILLE RIVER MINES AND MILLS

PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS



PEND OREILLE COUNTY, WASHINGTON



EPA Sample ID

01264426

01264427

01264428

01264267

01264269

CLP Inorganic ID

MJ0GN5

MJ0GN6

MJ0GN7

MJ0F16

MJ0F14

CLP Organic ID

J0GN5

J0GN6

J0GN7 ,

J0F16

J0F14

E&E Sample ID

01050250

01050251 ,

01050252

01050280

01050279

Station Location

PRBK01SD

PRBK02SD

PRBK03SD

BBPP01SD

BBPP02SD

Depth (in. bgs)

0-8

0-8

0-8

0-8

0-8

Description

Background

Source











Aluminum

6020

8350

6770

3640

6760

Arsenic

5.2

S3

S3

3.6 U

9.1 U

Barium

59.9

102

72.4

59.0

114

Cadmium

0.20 U

0.25 JB

0.26 JB

1.7

2.8





(0.25 SQL)

(0.26 SQL)





Calcium

17500

15900

20400

70500

35400

Chromium

13.2

17.9

16.4

6.5

11.9

Copper

17.5 JL

22.4 JL

19.3 JL

8.9 JL

23.0 JL



(21.4 AC)

(27.3 AC)

(23.5 AC)





Iron

12500

17000

14200

9540

12000

Lead

7 J

10.5

8.7

59.9

72.5

Magnesium

9100

9180

9450

32200

8730

Manganese

243

429

345

341

194

Nickel

13.3

16.8

15.0

17 3

44.9

Potassium

1260 JB

1600

1260

392 JB

915 JB

Vandium

29.5

32.5

30.8

11.4 JB

19.7 JB

Zinc

49.7

74.1

53.4

329 JH

560 JH









(219 AC)

(373 AC)













TOC ~|

2570 I

7090

4550 |

3530 |

56300

0073

Note:

Key.

AC

B

BB

bgs

BK

CLP

E&E

EPA

H

ID

in.

J

L

mg/kg

PP

PR

SD

SQL

TAL

TOC

U

Bold type indicates the sample concentration is above the detection limit.
Underline type indicates tbe sample result is significant as defined in Section 5.

= Adjusted concentration.

= Tbe reported concentration is between tbe instrument detection limit and the contract required detection limit
= Blue Bucket Mine.

= below ground surface.

= Background.'

= Contract Laboratory Program.

= Ecology and Environment, Inc.

= United States Environmental Protection Agency.

= High bias.

= Identification.

= inches.

= The analyte was positively identified. The associated numerical value is an estimate.

= Low bias.

= milligrams per kilogram.

= probable point of entry.

= Pend Oreille River.

= sediment.

= sample quantitation limit
= target analyte list
= Total organic carbon.

= The analyte was not detected. The associated numerical value is the contract required detection limit.

6-36

-------


Table 6-3



ORIOLE MINE SURFACE WATER SAMPLES

ANALYTICAL RESULTS SUMMARY

LOWER PEND OREILLE RIVER MINES AND MILLS

PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS

PEN

D OREILLE COUNTY, WASHINGTON





Federal AWQC





Ecotox Screening

Protection of



EPA Sample ID

Thresholds

Aquatic Organisms

01264271

CLP Inorganic ID





MJ0F17

CLP Organic ID





NU

E&E Sample ID





NU

Station Location





ORSPOISW

Description

Background

Source









Calcium

NU

NU

18900

Magnesium

NU

NU

9530

Zinc

100 1

no2

102

Source: EPA 1996; Ecology 1997.

1 Value is Hardness Dependent (100 mg/L as CaCoj).

1 Value must be calculated based on characteristics of the specific surface water body.

Note: Bold type indicates the sample concentration is above the detection limit.

Key:

AWQC
CLP
E&E
EPA
ID
Hg/L
NU
OR
SP
SW
TAL

= Ambient Water Quality Criteria.

— OcSu uCt LubcTutGiy PiC^iouii

= Ecology and Environment, Inc.

= United States Environmental Protection Agency.
= Identification.

= micrograms per liter.

= Not utilized.

= Oriole Mine.

= Spring.

= Surface water.

= target analyte list

6-37

-------






Table 6-4







ORIOLE MINE SEDIMENT SAMPLES
ANALYTICAL RESULTS SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS
PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS
PEND OREILLE COUNTY, WASHINGTON



EPA Sample ID '

01264426

01264427

01264428

01264075

01264272

01264273

CLP Inorganic ID

MJ0GN5

MJ0GN6

MJ0GN7

MJ0BQ7

MJ0F18

MJ0F19

CLP Organic ID

J0GN5

J0GN6

J0GN7

JX832

J0F18

J0F19

E&E Sample ID

01050250

01050251

01050252

NU

01050274

01050273

Station Location

PRBK01SD

PRBK02SD

PRBK03SD

US004SD

ORSF01SD

ORSPQ2SD

Depth (in. bgs)

0-8

0-8

0-8

0-2

0-8

0-8

[Description

Background

Source



SSHSSlSSi8i

SlillSSilif





ISKlSlllSfllS;

Aluminum

6020

8350

6770

7950

5190

9280

Arsenic

5.2

53

53

24

4,6

13.8

Barium

59.9

102

72A

684

234

123

Beryllium

0.18 JB
(0.18 SQL)

0.27 JB
(0.27 SQL)

0.2 JB
(0.2 SQL)

0.36 U

0,24 JB

0.38 JB

Cadmium

0.2 U

0.25 JB
(0.25 SQL)

0.26 JB
(0.26 SQL)

0.38 JBK
(0.54 SQL)

85 .

IZ

Calcium

17500

15900

20400

1520 JK

65000

51900

Chromium

132

17.9

16.4

144

14J

14.8

Cobalt

4.8 JB

(4.8 SQL)

7.6 JB
(7.6 SQL)

6.8 JB
(6.8 SQL)

93 JB
(9.3 SQL)

9,6 JB

9.8 JB

Copper

173 JL
(21.4 AC)

22.4 JL
(273 AC)

193 JL

(235 AC)

12.7JK
(155 AC)

323 JL

71.7 JL

Iron

12500

17000

14200

13600

7680

20900

Lead

73

105

8.7

14.8

301

714

Magnesium

9100

9180

9450

3290

36400

33200

Manganese '

243

429

345

699

4210

2230

Nickel

133

16.8

15

203

15.7

21.1

Potassium

1260 JB

1600

1260

556 JB

249 JB

531 JB

Silver

0.56 U

0.83 U

0.64 U

0.60 UJL
(1.0 U AC)

M

&£

Vanadium

29.S

323

30.8

10.9 JB
(10.9 SQL)

10.5 JB

17.1 JB

Zinc

49.7

74.1

53.4

54.7

784

5740







'rin1 '¦T.1' ,v!iJ





[TOC |

2570

7090

4550

19000 |

19500 |

19200

0075

Note:

Key;

AC

B

bgs

BK

CLP

E&E

EPA

ID

in.

J

L

mg/kg

NU

OR

PR

SD

SP

SQL

TAL

US

Bold type indicates tbe sample concentration is above the detection limit
Underline type indicates die sample results is significant as defteod in Section 5,

= Adjusted concentration.

= Tbe reported concentration is between the instrument detection limit and tbe contract requited detection limit
= below ground surface.

= background.

= Contract Laboratory Program.

= Ecology and Eisvironinent, Inc.

= United States Environmental Protection Agency.

= Identification.

= inches.

s Tbe analyse was positively identified. Hie associated numerical value is an estimate.

= Low bias.

= milligrams per kilogram.

= Not utilized.

= Oriole Mine.

: Pend Oreille River.

• spring.

; Sample quantitation limit
= target analyte list
s tributary sediment/soil (upstream/upland sampling location.

6-38

-------


Table 6-5



JOSEPHINE MINE SURFACE WATER SAMPLES

ANALYTICAL RESULTS SUMMARY

LOWER PEND OREILLE RTVER

MINES AND MILLS



PRELIMINARY ASSESSMENTS AND

SITE INSPECTIONS



PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264419

01264356

CLP Inorganic ID

MJ0GM8

MJ0FK9

CLP Organic ID

NU

NU

E&E Sample ID

NU

NU

Station Location

POBKOISW

JQSP01SW

Description

Background

Source



Calcium

18700

137000

Lead

2.8 U

21.5

Magnesium

4950 IB

46400

Zinc

2.8 JB

112



(20 SQL)



Note:	Bold type indicates the sample concentration Is above the detection limit.

Underline type indicates the sample result is significant as defined in Section 5.

Key:

B	= The reported concentration is between the instrument detection limit and me contract required detection limit

BK	= background.

CLP	= Contract Laboratory Program.

E&E	» Ecology and Environment, Inc.

EPA	= United States Environmental Protection Agency.

ID	= identification.

J	= The analyte was positively identified. The associated numerical value is an estimate.

JO	= Josephine Mine.

tig/L	= micrograms per liter.

NU	= Not utilized.

PO	= Pend Oreille Mine/Mill.

SP	m spring.

SQL	' = sample quantitation limit.

SW	ss surface water.

TAL	s target analyte list

U	s The analyte was not detected. The associated numerical value is the contract required detection limit

6-39

-------


Table 6-6



JOSEPHINE MINE SEDIMENT SAMPLES
ANALYTICAL RESULTS SUMMARY

LOWER PEND OREILLE RIVER
MINES AND MILLS

PRELIMINARY ASSESSMENTS AND
SITE INSPECTIONS

PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264420

01264423

CLP Inorganic ID

MJ0GM9

MJ0GN2

CLP Organic ID

J0GM9

J0GN2

E&E Sample ID

01050244

01050247

Station Location

POBK01SD

JOPP01SD

Depth (in. bgs)

0-8

0-8

(Description

Background

Source







Aluminum

11100

' 213

Aiseoic

163

47

Barium

183

31.611

Cadmium

0.57 JB
(057 SQL)

M

Calcium

21500

290000

Chromium

17.6

0.86 U

Copper

255 JL
(31.6 AC)

6.6 JL

Iron

27000

807

Lead

35.7

17400

Magnesium

8910

10800

Manganese

921

793

Mercury

0.10 U

0.16

Nickel

20.9

5.0 JB

GUver

1.4 U

M

[Vanadium

283

8.6 JB

[Zinc

287

2040





[TOC I 13700 I 36100

0077

Note

Bald type indicates the sample concentration is above the detection limit
Underline type indicates the sample result is significant as defined in Section 5.

Key.

AC

B

bgs

BK

CLP

E&E

EPA

ID

in.

I

JO

L

mg/kg

FO

PP

SD

SQL

TAL

TOC

U

= Adjusted concentration.

= The reported concentration is between the instrument detection limit and the contract required detection limit.
•* below ground surface.

« background.

= Contract Laboratory Program.

*	Ecology and Environment, Inc.

¦	United States Environmental Protection Agency.

= Identification.

m irtrh+ft

= Tic analyte was positively Identified. The associated numerical value is an estimate.

•» JosejiuneMioe.

= Low bias.

= milligrams per kilogram.

¦= Pend Oreille Mine/MiU.

*	probable point of entry,
c sediment.

s Sample quantitation limit.

= Target analyte list

*	Total organic carbon.

¦	The analyte was not detected. The associated numerical value is the contract required detection limit

6-40

-------
0078



Table 6-7



GRANDVIEW MINE/MILL SURFACE WATER SAMPLES

ANALYTICAL RESULTS SUMMARY



LOWER PEND OREILLE RIVER





MINES AND MILLS



PRELIMINARY ASSESSMENTS AND



SITE INSPECTIONS



PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264419

01264415

01264417

CLP Inorganic ID

MJ0GM8

MJ0GM4

MJ0GM6

CLP Organic ID

NU

NU

NU

E&E Sample ID

NU

NU

NU

Station Location

POBKOISW

GMPP04SW

GMPP05SW

Description

Background

Source









Aluminum

104 JB

156 JB

245

Calcium

18700

18300

18800

Iron

53.7 U

103

273

Lead

2.8 U

2.8 U

4.1

Magnesium

4950 JB

4840 JB

5020

Manganese

7.7 JB

11.1 JB

25J

<

(15 SQL)





Zinc

2.8 JB

5.5 JB

20.6

i	1

nn 90i i



	il

Note;

Bold type indicates the sample concentration is above the detection Emit
Underline type indicates the sample result is significant as defined in Section 5.

Key:
B

BK

CLP

E&E

EPA

GM

ID

J

Hg/L

NU

FO

PP

SQL

sw

TAL

U

= The reported concentration is between the instrument detection limit and the contract required detection limit
= background.

= Contract Laboratory Program.

= Ecology and Environment, Inc.

= United States Environmental Protection Agency.

= Grandview Mine/Mill.

= ldentificaiton.

- The analyte was positively identified. The associated numerical value is an estimate.

= micrograms per liter.

= Not utilized.

= Pend Oreille Mine/Mill.

= probable point of entry.

= sample quantitation limit
= surface water.

= Target analyte list

=The ansslyve was not detected. The associated numerical value is the contract required detection limit

6-41

-------
.

Table 6-8



GRANDV1EW MINE/MILL SEDIMENT SAMPLES
ANALYTICAL RESULTS SUMMARY



LOWER PEND OREILLE RIVER
MINES AND MILLS



PRELIMINARY ASSESSMENTS AND
! SITE INSPECTIONS

PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264420

01264416

01264418

CLP Inorganic ID

MJ0GM9

MJ0GM5

MJ0GM7

CLP Organic ID

J0GM9

J0GM5

JOGM7

E&E Sample ID

01050244

01050242

01050243

Station Location

POBK01SD

GMPP04SD

GMPPQ5SD

Depth (in. bgs)

0-8

o
»

00

0-8

Description

Background

Source

BSpM&d's:(mgfltg)a;







Aluminum

11100

3160

8400

Arsenic

16J

4.5

52

Barium

183

44.6

110

Cadmium

0.57 JB
(0.57 SQL)

0.34 U

M

Calcium

21500

27500 JL

14600

Chromium

17.6

7.1

25.5

Copper

25.9 JL
(31.6 AC)

8.1

84.0 JL

Iron

27000

7810

16600

Lead

35.7

43.5

449

Magnesium

8910

15000 JL

10400

Manganese

921

209 JH

(169 AC)

313

Nickel

20.9

5.9 JB

12J

Potassium

2020JB

427 JB

1560

Vanadium

283

9.3 JB

20.1

Zinc

287

152

864

isg®gfgffi^rtph



.

froc

18800

8670

10200

0079

Now:

Underline type indicates the sample results is significant as defined to Section 5.

Key.

AC

B

bgs

BK

CLP

E&E

EPA

GM

H

ID

in.

J

L

mg/kg

PO

PP

SD

SQL

TAL

TOC

U

= adjusted concentration.

¦ The reported concentration is between the instrument detection limit and the contract required detection limit.
* below ground surface.

= background.

= Contract Laboratory Program.

= Ecology and Environment, Inc.

= United States Environmental Protection Agency.

= Grand view Mine/Mill.

= high bias.

= Identification.

"inches.

= The analyte was positively identified. The associated numerical value is an estimate.

= low bias.

= milligrams per kilogram.

= Pend Oreille Mine/Mill.

= probable point of enuy.

= sediment.

= sample quantitation limit
= Target analyte list
= Total organic carbon.

= The analyte was not detected. The associated numerical value is the contract required detection limit

6-42

-------
Tab le 6-9

PEND OREILLE MINE/MILL SURFACE SOIL SAMPLES ANALYTICAL RESULTS SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS PRELIMINARY ASSESSMENTS AND SITE INSP]

PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264358

01264274

01264252

01264253

01264254

01264255

01264256

01264257

01264258

01264259

01264260



CLP Inorganic ID

MJOFLl

MJ0F20

MJ0EZ7

MJ0EZ8

MJ0EZ9

MJ0F00

MJ0F01

MJ0F02

MJ0F03

MJ0F04

MJ0F05



CLP Organic ID

NU

NU

NU

NU

NU

NU

NU

NU

NU

NU

NU



E&E Sample ID

NU

NU

NU

NU

NU

NU

NU

NU

NU

NU

NU



Station Location

BK02SS

BK03SS

POTPOISS

POTP02SS

POTP03SS

POTP04SS

POTT05SS

POTP06SS

POTO07SS

POTP08SS

POTP09SS

F

Depth (in. bgs)

0-6

0-6

0-6

0-6

0-6

0-6

0-6

0-6

0-6

0-6

0-6



Description

Backg

round

TDF-l/Source

TDF-3/Source

TDF-2/Source





1

Aluminum

13500

12900

325

8080

4680

146

312

243

614

293

222



Arsenic

3.5

6.7

20.6

5.1 U

18.9

19.8

40.0

20.8

26.4

22,4

21.1



Barium

296

374

20.3 JB

71.1

70.4

8.7 JB

7.8 JB

10.0 JB

15.7 JB

10.2 JB

8.9 JB



Cadmium

0.86 JB

(0.86 SQL)

1.2 JB
(1,2 SQL)

15.0

0.08 U

M

M

M

11.9

30.4

20.1

10.4

; Calcium

19100 JL

2460

182000

16900

94100

152000

117000

148000

159000

156000

158000



! Chromium

22.6

12.9

10.4

19.2

13.9

3.9

2.7

7.1

143

8.0

7.2



Copper

17.0 JL
(20.7 AC)

19.7 JL
(24.0 AC)

176.IL

27.6 JL

583 JL

90.0 JL

403 JL

178 JL

242 JL

113 JL

88.0 JL



Iron

18100

16700

32000

15900

37800

62700

171000

60800

61800

61100

56000



Lead

47.2 JK
(68 AC)

223

680

9.5

467

666

1650

818

1760

IfiOfi

919



Magnesium

3870 JK

4360

74300

8460

42300

97400

70800

91800

69200

81800

73300



Manganese

989

4050

228

310

279

220

214

236

217

208

184



Mercury

0.06 U

0.06 U

0.25

0.07 U

0.16

0.15

0.10

0.18

0.58

0.25

0.16



Nickel

18.9

19.4

9.6 JB

18.9

15.1

20.0

21.4

16.6

16.1

13.7

13.7



Potassium

2250

644 JB

195 JB

1340 JB

665 JB

74.3 JB

tin jb

134 JB

336 JB

156 JB

145 JB



Selenium

0.84 U

0.83 U

0.83 U

0.94 U

0.9 U

0.78 U

0.71 U

0.87 U

0.90 U

0.82 U

0.80 U



Silver

0.68 JB
(0.68 SQL)

0.92 JB
(0.92 SQL)

0.65 JB

0.68 JB

1,1 JB

0.98 JB

M

13 JB

1.3 JB

1.1 JB

0.92 JB



Vanadium

35.2

17.9

7.2 JB

363

24.0

3.7 JB

5.1 JB

9.0 JB

11.0 JB

7.6 JB

7.6 JB



Zinc

201

115

4130 .IH

67.6 JH
(45.1 AC)

2190 .IH

1590 JH

250® JH

2520 JH

6540 JH

4540 JH

2270 JH



C2753 AC)

(1460 AC)

(1060 AC)

(1667 AO

(1680 AC)

(4360 AC)

(3027 AC)

(1513 AC)

Note:	Bold type indicates the sample concentration is above the detection limit.

Underline type indicates the sample result is significant as defiend in Section 5.

-------
Key;

AC	= Adjsuted concentration.

B	s The reported concentration is between the instrument detection limit and the contract required detection Unit

bgs	= below ground surface.

BK	= background.

CLP	= Contract Laboratory Program.

E&E	= Ecology and Environment, Inc.

EPA	= United States Environmental Protection Agency.

H	= High bias.

ID	o Identification.

in.	= inches.

J	= The analyte was positively identified. The associated numerical value is an estimate.

K	= Unknown bias.

L	= Low bias,

mg/kg	= milligrams per kilogram.

NU	= Not utilized.

PO	= Pend Oreille Mine/Mill.

SQL	= sample quantitation limit.

SS	= surface soil.

^ TAL	= Target analyte list.

^ TDF	= Tailings disposal fecility.

4> TP	= tailings pile.

U	= The analyte was not detected. The associated numerical value is the contract required detection limit.

WP	= waste rock pile.

-------




Table 6-10





PEND OREILLE MINE/MILL SURFACE WATER SAMPLES

ANALYTICAL RESULTS SUMMARY





LOWER PEND OREILLE RIVER





MINES AND MILLS



PRELIMINARY ASSESSMENTS AND





SITE INSPECTIONS



PEN

D OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264419

01264401

01264410

01264412

CLP Inorganic ID

MJ0GM8

MJOGLO

MJ0GL9

MJ0GM1

CLP Organic ID

NU

NU

NU

NU

E & E Sample ID

NU

NU

NU

NU

Station Location

POBKOISW

POPP01SW

POPP02SW

POPP03SW

Description

Background

Source



¦*







Barium

57.3 JB

71.6 JB

58.5 JB

62.6



(200 SQL)







Calcium

18700

48500

89400

20100

Iron

53.7 U

71.3 U

409

107

Lead

2.8 U

8,7

93

2.8 IF

Magnesium

4950 JB

30200

29000

' 523®

Manganese

7.7 JB

0.43 JB

33.0

10 JB



(15 SQL)







Zinc

2.8 JB

212

62.S

4.4 JB

	

/1A CAT \







Note;	Bold type indicates the sample concentration is above (he detection limit

Underline type indicates the sample results is significant as defined in Section 5.

Key:

B	= The reported concentration is between the instrument detection limit and the contract required detection limit

BK	= Background.

CLP	= Contract Laboratory Program.

B&E	s Ecology and Environment Inc.

EPA	= United States Environmental Protection Agency.

ID	= Identification.

J	- The analyte was positively identified. The associated numerical value is an estimate.

jig/L	m micrograms per liter.

NU	= Not utilized.

PO	= Pend Oreille Mine/Mill.

PP	= probable point of entry.

SQL	= sample quantitation limit

SW	a surface water.

TAL	e Target analyte list

U	= The analyte was not detected. The associated numerical value is the contract required detection limit

6-45

-------
'

Table 6-11



PEND OREILLE MINE/MILL SEDIMENT SAMPLES
ANALYTICAL RESULTS SUMMARY



LOWER PEND OREILLE RIVER
MINES AND MILLS



PRELIMNARY ASSESSMENTS AND
SITE INSPECTIONS

PEP

ID OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264420

01264411

01264413

CLP Inorganic ID

MJ0GM9

MJ0GM0

MJ0GM2

CLP Organic ID

J0GM9

J0GM0

J0GM2

E & E Sample ID

01050244

01050239

01050240

Station Location

POBK01SD

POPP02SD

POPP03SD

Depth (in. bgs)

0-8

0-8

0-8

(Description

Background

Source





-;w i



Aluminum

11100

3310

4250

Arsenic

163

13.1

3.2

Barium

183

250

44.7 JB

Cadmium

0.57 IB
(0.57 SQL)

M

0.27 U

Calcium

21500

209000 JL

8600 JL

Chromium

17.6

9.2

6.0

Copper

25.9 JL
(31.6 AC)

2&4

24A

Iron

27000

31100

9160

Lead

35.7

346

23.6

Magnesium

8910

42200 JL

5930 JL

Manganese

921

1970 JH
(1589 AC)

160 JH

(129 AC)

Nickel

20.9

404

7.8 JB

Vanadium

283

12.2 JB

15.4

Zinc

287

2370

160







TOC |

18800

46100

541J |

Bold type indicates the sample concentration is above the detection limit
Underline type indicates the sample result is significant as defined in Section S.

Key.

AC	= adjusted concentration.

B	= The repotted concentration is between the instrument detection limit and the contract required detection limit

bgs	= below ground surface.

BK	= background.

CLP	a Contract Laboratory Program.

E&E	= Ecology and Environment, Inc.

'	= United States Environmental Protection Agency.

H	= High bias.

ID	ss Identification.

ul	— inches.

¦I	= The analyte was positively identified- The associated numerical value is an estimate.

I-	= Low bias.

mg/kg	= milligrams per kilogram.

= Pend Oreille Mine/MilL

PP	= probable point of entry.

SD	= sediment

SQL	— sample quantitation limit.

TAL	= Target analyte list

TOC	= Total organic carbon.

U	= The analyte was not detected The associated numerical value is the contract required detection limit

6-46

-------
Source: E&E 2001b.	Note: D

R

ar
dj

4

Si

o====|g__40
Approximate Scale in Feet

I p ecology and environment, inc.

1 ||n International Specialists In tha Environment
I Mp Seattle, Washington

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

F

dt ire t
~LUc Jt

s

Date:
2-28-02

Drawn by:
AES

10

-------
Source: E&E2001b.

4

o==ass^^o

Approximate Scale in Feet

Note; D
R:

-*	Forest Road

a*

¦e-

00

PPE 1

Culvert

Blown Out
Shaft

Downgradient S ample -
BBPP01SW/SD

Flow

-Upgradient Sample
BBPP02 SW/SD

ecology and environment, inc.

International Specialists In the Environment
Seattle, Washington

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Fi

BLUEB
SAMPLE]

Date:
2-28-02

Drawn by;
AES

10:STi

-------
G08&

Approximate Scale in Feet

I

Mud Area
No Outflow
Noted

ecology and environment, Inc.

Intamasonal SpedaSsts In the Eiwlrwtfflwrt
S«8fe. WMNngttti

I nwDD Dtxrn adutt t 13 t>nrci>
LUWHK rllliU UKhliKiVcK

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 6-3

ORIOLE MINE
SITEMAP

Date:
2-28-02

Drawn by:
AES

10: START-2\01080009\S714\fig 6-3

6-49

-------
0087

BK03SS
• (650ft from
adit/shaft)

Waste Rock
Piles

GT~

^-imORSP01SW/SD

Source: E&E 2001b

Approximate Scale in Feet

Old Log Structure

Key:

BK

Background Sample

OR

Oriole Mine

PPE

Probable Point of Entry

SD

Sediment

SP

Spring

sw

Surface Water

Mud Area
No Outflow
Noted

9

ecology and environment, inc.

international Specialists In tha Environment

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 6-4

ORIOLE MINE
SAMPLE LOCATION MAP

Date:
2-28-02

Drawn by;
AES

10:START-2\010B0009\S714\fig 6-4

6-50

-------
Ul/OU

Note: Pend Oreille River and Flume Creek are not drawn to scale.

III]] ecology and environment, inc.

rlr&n International Specialists In the Environment
1 Np Sastlh, Washington

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 6-5

JOSEPHINE MINE
SITEMAP

Date:
2-28-02

Drawn by:
AES

10:START-2\0108009\S714\fig 6-5

6-51

-------
0089

Source: E & E 2001 b.

Key:

A

10

20

JO	Josephine Mine

PP	PPE Sample

PPE	Probable Point of Entry

SD	Sediment

SP	Spring

SW	Surface Water

Approximate Scale in Feet

Collapsing
Wood Structure

Small Building

JOSP01SW
Spring—

Flume Creek
Flow	

Chain Link Fence
(topped with
barbed wire)

Waste Rock Pile

Note: Pend Oreille River and Flume Creek are not drawn to scale.

ecology and environment, inc.

International Specialists in the Environment
Sato*. Wtthington

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 6-6

JOSEPHINE MINE
SAMPLE LOCATION MAP

Date:
2-28-02

Drawn by.
AES

10:START-2\0108009\S714\fig 6-6

6-52

-------


Sourct: DcLormu I99S.

'salmo:



Site Location

0090

WASHINGTON

Approximate Scslc m Miles
V	«l w,>

Figure 6-7

GRAND VIEW MINE/MILL
SITE V1CINTTY MAP

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pcnd Oreille, Washington

ecology arid environment, inc.

Intararanal Sp*x*Wfci in lu EsivtnyuT*rt

SmAi, mjk ¦ i.

Drawn by;
AES

Dale:
3-1-02

10: START-2\01080009\S 7 [ 4\fig 6-7

6-53

-------
0091

6-54

-------
0092

KEY:	

PPfc, Probable Point of Entry

• Co-Located Surface and Subsurface
Soil Sample Location

~ Surface Soil Sample Location

A Co-Located Surface Water and
Sediment Sample Location

A Background Co-Located Surface
Water and Sediment Sample Location



Flow



FDOlt^]

0 100 200
Approximate Scale in Feet

W	Former Wastewater

I
/

Drainage Ditch

FD02

I

Xf}FD03

TP01 (Five-Point Composite Sample)

TP02 (Five-Point Composite Sample)

Suspected Tailings Pile

Pend Oreille Village

Wellheads

Suspected

Surface Water Pathway to
Pend Oreille River (PPE 1)

¦o-

Riverside Bluff

FD09

APROi :

Note; Base map features are not to scale;

300 Feet to
Pend Oreille River

Power
Station
BK0& ~

PR02A

Pend Oreitte River

ecology and environment, inc.

International Specialists tn tha Enwanmenl
SMtOft, VMuthington

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 6-9

GRAND VIEW MINE/MILL
SAMPLE LOCATION MAP
PPE TO PEND OREILLE RIVER

Date:
3-1-02

Drawn by:
AES

10;START-2\01080Q09\S714\fig 6-9

6-55

-------
Legend	Figure 6-10

		GRANDVIEWIKINEMU. ~L.

GROUNDWATER SAMPLE LOCATION MAP
October 2000 E & E Sampling Event *

m	a u n

'	6-57 Metaline Falls, Washington

™	Pend Oreille County

-------
Sourer: Comiaco Amencain lac.

Note: M«p fcmrurci beyood main Budy ma irr not drawn to Kile.

Highway 31

TDF-3

ecology and environment, Inc.

International Bpfiahafi in ha Em%onmart



500	1000

Approximate Scale in Fool

-------
6-61

-------
0096

7. EPA CLP ANALYTICAL RESULTS, SURFACE WATER
MIGRATION/EXPOSURE PATHWAYS, AND TARGETS

The following sections describe the surface water migration pathway for the 5 mines/mills that
were sampled; namely Blue Bucket Mine, Oriole Mine, Josephine Mine, Grandview Mine/Mill, and Pend
Oreille Mine/Mill; tributaries that were sampled; potential targets within the range of influence of these
mines/mills (Figures 7-2 through 7-11); and a discussion of sample results evaluated in accordance with
criteria described in Section 5.1.2. Analytical data forms from laboratory analyses are provided in
Appendix D.

An evaluation of the groundwater migration, soil exposure and air migration pathways for the
Blue Bucket Mine, Oriole Mine, Josephine Mine, and Pend Oreille Mine/Mill was not conducted as part
of this investigation. An evaluation of these pathways for the Grandview Mine/Mill site can be found in
the Grandview Mine PA/SI report prepared by E & E for EPA, dated June 2001.

A description of the groundwater migration, soil exposure and air migration pathways for the Pend
Oreille Mine/Mill with site conditions observed as of May 2000, can be found in the Pend Oreille Mine
Preliminary Assessment report prepared by E & E for EPA, dated November 2000.

Refer to Table 7-1 for PPEs of each sampled mine/mill.

7.1 BLUE BUCKET MINE

! '

7.1.1 Surface Water Pathway Description

The potential source area at the Blue Bucket Mine to an unnamed creek includes a waste rock pile
measuring approximately 60 feet long by 50 feet wide by 15 feet deep. The distance from the waste rock
pile to the unnamed creek is approximately 30 feet. Potential flow from a shaft on the property to the
unnamed creek is approximately 5 feet (Figure 6-2, Table 7-1).

The START-2 estimated the flow of the unnamed creek to be 20 gpm. The average annual flow rate
recorded for Pend Oreille River near Metaline Falls is 24,580 cubic feet per second (USGS 1992).

The average annual precipitation is 27.38 inches in Metaline Falls, Washington (WRCC 2001). The
2-year, 24-hour rainfall event for the area ranges from 1.8 to 2.4 inches (WRCC 2001).

10:START-2\01080009SS714

7-1

-------
0097

Soils in the area of Blue Bucket Mine were mapped as Belzar silt loam, high precipitation, 20 to 40
percent slopes. This moderately deep, well drained soil is on the foot slopes and ridgetops of foothills and
mountains. It formed in a mantle of volcanic ash and loess over residuum and colluvium derived dominantly
from calcareous rock and limestone. Slopes are convex and generally have north and east aspects.

Typically, the surface is covered with a mat of organic material about 1 inch thick. The surface layer is
brown silt loam about 7 inches thick. The upper 6 inches of the subsoil also is brown silt loam. The lower 7
inches is brown channeiy loam. The substratum is pale brown very channery loam about 15 inches thick.
Fractured limestone is at a depth of about 35 inches. The depth to bedrock ranges from 20 to 40 inches.
Included in this unit are small areas of Belzar silt loam that has a slope of less than 20 percent or more than
40 percent, Ahren loam, Aits loam, Boundary silt loam, Hartill silt loam, and Waits loam. Also included are
Rock outcrop on ridges and knobs and poorly drained soils in draws and adjacent to seeps and springs.
Permeability is moderate in Belzar soil. Available water capacity is low. The effective rooting depth is to
20 to 40 inches. Runoff is rapid, and the hazard of water erosion is severe. (USDA 1992)

Approximately 23 upgradient acres of land is expected to drain through the source area at the mine
(USGS 1992b). The drainage area of sources is approximately 80 acres (USGS 1992b).

Mines/mills adjacent and/or near the Pend Oreille River are assumed to flood at least every two
years (USGS 1998a).

No containment such as run off controls exist at the mine.

7.2 ORIOLE MINE

7.2.1 Surface Water Pathway Description

Potential source areas at the Oriole Mine to Linton Creek include waste rock piles described in
Section 6. The largest waste rock pile measured approximately 25 feet long by 15 feet wide by 4 feet deep.
Flow from a nearby spring reaches the waste rock pile and continues into a muddy area with no flow. The
START-2 estimated spring flow at 32 gpm. There is a potential for overland flow from the muddy area to
Linton Creek during periods of heavy rainfall or snowmelt, and floods (Figure 6-4, Table 7-1). Linton
Creek, a tributary to the Pend Oreille River, is located north of Metaline Falls. It is located on the west side
of the Pend Oreille River approximately 1 mile upstream from Metaline Falls and 11 miles upstream from
Boundary Dam with an estimated flow of 2 cubic feet per second (cfs; Ecology 2001b).

The average annual flow rate recorded for Pend Oreille River near Metaline Falls is 24,580 cubic
feet per second (USGS 1992).

10:START-2\01080009W 14

7-2

-------
0098

The average annual precipitation is 27.38 inches in Metaline Falls, Washington (WRCC 2001). The
2-year, 24-hour rainfall event for the area ranges from 1.8 to 2.4 inches (WRCC 2001).

Soils in the vicinity of Oriole Mine were mapped as Belzar, high precipitation-Rock outcrop
complex, 5 to 40 percent slopes. This map unit is on the toe slopes, foot slopes, and ridgetops of foothills
and mountains. Slopes are convex and generally have north and east aspects. This unit is about 65 percent
Belzar silt loam, high precipitation, 5 to 40 percent slopes, and 20 percent Rock outcrop. The components
of this unit occur as areas so intricately intermingled that mapping them separately is not practical at the
scale used by USD A. Included in this unit are small areas of Belzar silt loam that has a slope of less than 5
percent or more than 40 percent, Ahren loam, Aits loam, Boundary silt loam, Hartill silt loam, and Waits
loam. Also included are very stony and very shallow soils near the Rock outcrop and poorly drained soils in
draws and adjacent to seeps and springs. The Belzar soil is moderately deep and well drained. It formed in
a mantle of volcanic ash and loess over residuum and colluvium derived dominantly from calcareous rock
and limestone. Typically, the surface is covered with a mat or organic material about 1 inch thick. The
surface layer is brown silt loam about 7 inches thick. The upper 6 inches of the subsoil also is brown silt
loam. The lower 7 inches is brown channery loam. The substratum is pale brown very channery loam about
15 inches thick. Fractured limestone is at a depth of about 35 inches. The depth to bedrock ranges from 20
to 40 inches. Permeability is moderate in the Belzar soil. Available water capacity is low. The effective
rooting depth is 20 to 40 inches. Runoff is rapid, and the hazard of water erosion is severe. The Rock
outcrop consists mainly of exposed calcareous shale or limestone. (USDA 1992)

Approximately 80 upgradient acres of land is expected to drain through the source area at the mine
(USGS 1984). The drainage area of sources is approximately 43 acres (USG8 1984).

Mines/mills adjacent and/or near the Pend Oreille River are assumed to flood at least every two
years (USGS 1998a).

No containment such as run off controls exist at the mine.

73 JOSEPHINE MINE

7-3.1 Surface Water Pathway Description

The potential source area at the Josephine Mine to the Pend Oreille River is a waste rock pile
measuring approximately 60 feet long by 10 feet high by 2 feet deep. The entire length of the waste rock
pile extends into the Pend Oreille River (Figure 6-6, Table 7-1).

The average annual flow rate recorded for Pend Oreille River near Metaline Falls is 24,580 cubic
feet per second (USGS 1992).

10:START-2\01080009\S714

7-3

-------
0099

The average annual precipitation is 27.38 inches in Metaline Falls, Washington (WRCC 2001). The
2-year, 24-hour rainfall event for the area ranges from 1.8 to 2.4 inches (WRCC 2001).

Soils in the vicinity of Josephine Mine were mapped as Belzar silt loam, high precipitation, 20 to 40
percent slopes as described previously for Blue Bucket Mine. (USDA 1992)

Approximately 4 upgradient acres of land is expected to drain through the source area at the mine
(USGS 1992a). The drainage area of sources is approximately 23 acres (USGS 1992a).

Mines/mills adjacent and/or near the Pend Oreille River are assumed to flood at least every two
years (USGS 1998a).

No containment such as run off controls exist at the mine.

7.4 GRAND VIEW MINE/MILL
7.4.1 Surface Water Pathway Description

The site is located approximately 0.75 mile east of Pend Oreille River. Site topography slopes
gently toward Pend Oreille River. The two main levels are relatively flat with a slope between them. There
is another slope between the lower level and the suspected tailings pile, which slopes gently toward Pend
Oreille River. The nearest potential source area at the site to the river is the suspected tailings pile. From
this source area, it is approximately 300 feet overland to Pend Oreille River (Figure 6-12, Table 7-1). From
this FFE) in Pend Oreiiie River, it is approximately 8 miies to Boundary Dam.

The average annual flow rate recorded for Pend Oreille River near Metaline Falls is 24,580 cubic
feet per second (USGS 1992).

The average annual precipitation is 27.38 inches in Metaline Falls, Washington (WRCC 2001). The
2-year, 24-hour rainfall event for the area ranges from 1.8 to 2.4 inches (WRCC 2001).

Soils in the vicinity of Grandview Mine/Mill were mapped as Belzar, high precipitation-Rock
outcrop complex, 40 to 65% slopes; and Dufort silt loam, 0 to 15% slopes. Belzar, high precipitation-Rock
outcrop complex, 40 to 65% slopes was mapped on the back slopes and ridgetops of foothills and mountains.
Slopes are convex and generally have north and east aspects. This unit is about 65% Belzar silt loam, high
precipitation, 40 to 65% slopes, and 20 percent Rock outcrop. The components of this unit occur as areas so
intricately intermingled that mapping them separately is not practical at the scale used by USDA. Included
in this unit are small areas of Belzar silt loam that has a slope of less than 40% or more than 65%, Ahren
loam, Aits loam, Boundary silt loam, Hartill silt loam, and Waits loam. Also included are very stony and
very shallow soils near the Rock outcrop and poorly drained soils in draws and adjacent to seeps and
springs. The Belzar soil is moderately deep and well drained. It formed in a mantle of volcanic ash and

10: START-2\01080009\S714

7-4

-------
0100

loess over residuum and colluvium derived dominantly from calcareous rock and limestone. Typically, the
surface is covered with a mat of organic material about 1 inch thick. The surface layer is brown silt loam
about 7 inches thick. The upper 6 inches of the subsoil also is brown silt loam. The lower 7 inches is brown
channery loam. The substratum is pale brown very channery loam about 15 inches thick. Fractured
limestone is at a depth of about 35 inches. The depth to bedrock ranges from 20 to 40 inches. Permeablity
is moderate in the Belzar soil. Available water capacity is low. The effective rooting depth is 20 to 40
inches. Runoff is very rapid, and the hazard of water erosion is very severe. The Rock outcrop consists
mainly of exposed calcareous shale or limestone. (USDA 1992)

Dufort silt loam, 0 to 15% slopes are very deep, well drained soil on foothills. It formed in a thick
mantle of volcanic ash and loess over glacial drift of mixed mineralogy. Slopes are convex. Typically, the
surface is covered with a mat of organic material about 1 inch thick. When mixed to a depth of about 5
inches, the surface layer is light yellowish brown silt loam. The upper part of the subsoil also is light
yellowish brown silt loam. It is about 13 inches thick. The lower part is pale brown gravelly loam about 12
inches thick. The substratum to a depth of 60 inches or more is pale brown very gravelly sandy loam.
Included in this unit are small areas of Dufort silt loam that has a slope of more than 15%, Dufort very stony
silt loam, Aits loam, Bonner silt loam, Martella silt loam, Newbell silt loam, and Scrabblers silt loam.
Permeability is moderate to a depth of 30 inches in this Dufort soil and moderately rapid below that depth.
Available water capacity is moderate. The effective rooting depth is 60 inches or more. Runoff is medium,
and the hazard of water erosion is moderate. (USDA 1992)

Approximately 4 upgradient acres of land are expected to drain through a source area at the site
(USGS 1992a). The drainage area of sources is approximately 33 acres (USGS 1992a).

Mines/mills adjacent and/or near the Pend Oreille River are assumed to flood at least every two
years (USGS 1998a).

No source area at the site has any flood containment mechanisms.

7.5 Pend Oreille Mine/Mill

7.5.1 Surface Water Pathway Description

The Pend Oreille Mine/Mill site is located approximately 0.75 mile east of Pend Oreille River. Site
topography slopes gently toward Pend Oreille River. The two main levels are relatively flat with a slope
between them. There is another slope between the lower level and the suspected tailings pile, which slopes
gently toward Pend Oreille River. Potential source areas at the site include mine water discharge into the

10:START-2\01080009\S714	7-5

-------
01

Pend Oreille River, three TDFs, and one waste rock pile. A description of overland flow from source areas
at the site to associated PPEs is provided in Table 7-1. PPE locations are shown in Figure 6-12.

Surface1 water flows are generated from precipitation in the form of rainfall or snowfall, and where
groundwater is exposed at the surface.

Several creeks transect the site. Threemile Creek, which flows year-round and has flow rates of a
few hundred gallons per minute or higher depending on the time of year, is located near the northern border
of the mine and adjacent to USFS-managed lands. Threemile Creek is primarily confined to a single channel
along most of its length within the mine area, and dorms a large forested wetland used by beavers near the
northeastern boundary of the mine. (Ecology 2000)

Two creeks are found near the TDF-1. One creek (Creek 1) originates to the east of the mine, near
the golf course. Water flows within a well-defined channel along most of its length during most of the year
and empties into Pend Oreille River. (Figure 6-12; Ecology 2000)

Two seep areas are located by TDF-2 and TDF-3. The water in these seeps appear to originate from
hill slopes and from TDF-2. This seepage is collected in diversion channels and routed around and to the
base of TDF-1, where it meets with natural seepage. This water then flows downslope (Creek 2) and drains
into Pend Oreille River (PPE 2). Surface water runoff from TDF-1 and TDF-2 drains into installed
diversion ditches which drain into Pend Oreille River. (Figure 6-12, Ecology 2000)

A ihriu uuuaiiieu Creek (Creek 3) originates off the property east of die Siii/'loui far! way of the
Metaline Falls Golf Course. It flows approximately 160 feet through a wetland on the edge of the fairway,
and for an additional 150 feet on the fairway before flowing underground. (Ecology 2000)

Frog Creek originates approximately 900 feet downslope from TDF-3 as a groundwater spring and
seep. Frog Creek derives its water from groundwater flowing beneath the kettle basin that holds TDF-3 and
from precipitation; it has a perennial flow. Initially, water from the spring flows into several channels,
which then join into a single channel approximately 400 feet downstream from the source. This channel
flows downhill until it intersects an access road that leads to TDF-1, then flows northerly along this road,
and then westerly under the road into a small pond. The flow rate is estimated by Ecology to be 40 gpm.
The creek flows from the pond in a northwesterly direction until surface flow termiates approximately 100
feet downslope from the pond. The creek resurfaces approximately 50 feet downslope from the southern
mine access road that parallels Pend Oreille River. The water collects into two chanels and eventually flows
into Pend Oreille River. (Figure 6-12, Ecology 2000)

10;START-a0108000WS714

7-6

-------
0102

Flume and Beaver creeks are important tributaries of Pend Oreille River that drain into the river
from the west and are also near the site. Surface water runoff from the staged waste rock may drain by sheet
flow into Flume Creek which drains into Pend Oreille River.

Each of the PPEs described in this report are located along the Pend Oreille River. Approximately 8
miles of the 15-mile TDL are on the Pend Oreille River between the PPEs on site and Boundary Dam; 1 mile
covers the final section of the Pend Oreille River from Boundary Dam to the Canadian border; and the
remaining 6 miles are on the Pend Oreille River in Canada (Figure 7-11).

The average annual flow rate recorded for Pend Oreille River near Metaline Falls is 24,580 cubic
feet per second (USGS 1992).

The average annual precipitation is 27.38 inches in Metaline Falls, Washington (WRCC 2001). The
2-year, 24-hour rainfall event for the area ranges from 1.8 to 2.4 inches (WRCC 2001).

Soils in the vicinity of Pend Oreille Mine/Mill were mapped as Dufort silt loam, 0 to 15% slopes;
Dufort very stony silt loam, 0 to 40% slopes; Hartill silt loam, 0 to 15% slopes; Hartill silt loam, 40 to 65%
slopes; Kaniksu sandy loam, 0 to 15% slopes; Kaniksu sandy loam, 15 to 40% slopes; Sacheen loamy fine
sand, 5 to 15% slopes; and Threemile silt loam, 25 to 40% slopes. (USDS 1992)

Dufort silt loam, 0 to 15% slopes are described previously for Grandview Mine/Mill (USDA 1992).

Dufort very stony silt loam, 0 to 40% slopes are very deep, well drained soil on the toe slopes and
foot slopes of foothills. It formed in a mantle of volcanic ash and loess over glacial drift or mixed
mineralogy. Slopes are convex. Typically, the surface is covered with a mat of organic material about 1
inch thick. The surface layer is light yellowish brown very stony silt loam about 12 inches thick. The
subsoil is pale brown gravelly loam about 14 inches thick. The substratum to a depth of 60 inches or more is
pale brown very gravelly sandy loam. Included in this unit are small areas of Dufort very stony silt loam
that has a slope of more than 40%, Dufort silt loam, Aits stony loam, Bonner gravelly silt loam, Martella silt
loam, Newbel] stony silt loam, and Scrabblers silt loam. Permeability is moderate to a depth of 26 inches in
this Dufort soil and moderately rapid below that depth. Available water capacity is low. The effective

I

rooting depth is 60 inches or more. Runoff is rapid, and the hazard of water erosion is severe. (USDA
1992)

Hartill silt loam, 0 to 15% slopes are moderately deep, well drained soil on the toe slopes and
ridgetops of foothills and mountains. It formed in a mantle of volcanic ash and loess over residuum and
colluvium derived dominantly from phyllite and quartzite. Slopes are convex and generally have north and
east aspects at the lower elevations and south and west aspects at the higher elevations. Typically, the
surface is covered with a mat of organic material about 1 Vi inches thick. When mixed to a depth of about 8

10:START-2\01080009\S714

7-7

-------
0103

inches, the surface layer is pale brown silt loam. The upper part of the subsoil also is pale brown silt loam.
It is about 4 inches thick. The lower part is light yellowish brown channery loam about 6 inches thick. The
upper part of the substratum is light yellowish brown very channery loam about 9 inches thick. The lower
part is very pale brown very channery loam about 9 inches thick. Phyllite is at a depth of about 36 inches.
The depth to bedrock ranges from 20 to 40 inches. Included in this unit are small areas of Hartill silt loam
that has a slope of more than 15%, Aits loam, and Newbell silt loam. Also included are Raisio channery
loam on south- and west-facing slopes and Rock outcrop on ridges and knobs. Permeability is moderate in
this Hartill soil. Available water capacity is low. The effective rooting depth is 20 to 40 inches. Runoff is
medium, and the hazard of water erosion is moderate. (USDA 1992)

Hartill silt loam, 40 to 65% slopes are moderately deep, well drained soil on the back slopes of
foothills and mountains. It formed in a mantle of volcanic ash and loess over residuum and colluvium
derived dominantly from phyllite and quartzite. Slopes are convex and generally have north and east aspects
at the lower elevations and south and east aspects at the higher elevations. Typically, the surface is covered
with a mat of organic material about 1 Vi inches thick. When mixed to a depth of about 8 inches, the surface
layer is pale brown silt loam. The upper part of the subsoil also is pale brown silt loam. It is about 4 inches
thick. The lower part is light yellowish brown channery loam about 6 inches thick. The upper part of the
substratum is light yellowish brown very channery loam about 9 inches thick. The lower part is very pale
brown very channsry loam about 9 inches thick. Phyllite is at a depth of about 36 inches. The depth Jo
bedrock ranges from 20 to 40 inches. Included in this unit are small areas of Hartill silt loam that has a
slope of less than 40% or more than 65%, Aits loam, and Newbell silt loam. Also included are Raisio
channery loam on south- and west-facing slopes, Rock outcrop on ridges and knobs, and poorly drained soils
in draws and adjacent to seeps and springs. Permeability is moderate in this Hartill soil. Available water
capacity is low. The effective rooting depth is 20 to 40 inches. Runoff is very rapid, and the hazard of
water erosion is very severe. (USDA 1992)

Kaniksu sandy loam, 0 to 15% slopes is very deep, well drained soil on terraces. It formed in sandy
glacial outwash of mixed mineralogy. The outwash has a mixture of volcanic ash and loess in the upper
part Typically, the surface is covered with a mat of organic material about 1 inch thick. The surface layer
is brown sandy loam about 7 inches thick. The subsoil is light yellowish brown sandy loam about 23 inches
thick. The substratum to a depth of 60 inches or more is pale brown gravelly loamy sand. Included in this
unit are small areas of Kaniksu sandy loam that has a slope of more than 15%, Bonner silt loam, Dalkena
fine sandy loam, Sacheen loamy fine sand, and Scotia fine sandy loam. Permeability is moderately rapid to
a depth of 30 inches in this Kanisku soil and rapid below that depth. Available water capacity is low. The

10:START-2\01080009\S714

7-8

-------
0104

\

effective rooting depth is 60 inches or more. Runoff is medium, and the hazard of water erosion is
moderate. (USDA 1992)

Kaniksu sandy loam, 15 to 40% slopes is very deep, well drained soil on terraces. It formed in
sandy glacial outwash of mixed mineralogy. Typically, the surface is covered with a mat of organic material
about 1 inch thick. The surface layer is brown sandy loam about 7 inches thick. The subsoil is light
yellowish brown sandy loam about 23 inches thick. The substratum to a depth of 60 inches or more is pale
brown gravelly loamy sand. Included in this unit are small areas of Kaniksu sandy loam that has a slope of
less than 15% or more than 40%, Dalkena fine sandy loam, Orwig sandy loam, Sacheen loamy fine sand,
and Scotia fine sandy loam. Permeability is moderately rapid to a depth of 30 inches in this Kanisku soil
and rapid below that depth. Available water capacity is low. The effective rooting depth is 60 inches or
more. Runoff is medium, and the hazard of water erosion is moderate. (USDA 1992)

Sacheen loamy fine sand, 5 to 15% slopes are very deep, somewhat excessively drained soil on
terraces and old alluvial fans. It formed in sandy glaciofluvial material of mixed mineralogy. Typically, the
surface is covered with a mat of partially decomposed organic material about 1 inch thick. The surface layer
is dark brown loamy fine sand about 6 inches thick. The upper 6 inches of the subsoil also is dark brown
loamy fine sand. The lower 12 inches is yellowish brown loamy sand. The upper 6 inches of the substratum
is light yellowish brown loamy coarse sand. The lower part to a depth of 60 inches or more is light
yellowish brown sand. Included in this unit are small areas of Sacheen loamy fine sand that has a slope of
less than 5% or more than 15%, Dalkena fine sandy loam, Dufort silt loam, Kaniksu sandy loam, and Scotia
fine sandy loam. Also included are Rathdrum veiy fine sandy loam in depressions and poorly drained soils
in draws. Permeability is rapid to a depth of 24 inches in this Sacheen soil and very rapid below that depth.
Available water capacity is low. The effective rooting depth is 60 inches ore more. Runoff is slow, and the

s

hazard of water erosion is slight. (USDA 1992)

Threemile silt loam, 25 to 40% slopes are deep, well drained soil on the foot slopes of foothills and
mountains. It formed in a mantle of volcanic ash and loess over calcareous glacial till. Slopes are convex.
Typically, the surface is covered with a mat of organic material about 1 Vi inches thick. The surface layer is
yellowish brown silt loam about 4 inches thick. The upper 6 inches of the subsoil is yellowish brown loam.
The lower 5 inches is brown gravelly loam. The upper 17 inches of the substratum is pale brown very
gravelly loam. The lower 20 inches is light brownish gray extremely gravelly loam. Limestone is at a depth
of about 52 inches. The depth of bedrock ranges from 40 to 60 inches. Included in this unit are small areas
of Threemile silt loam that has a slope of less than 25% or more than 40%, Ahren loam, Boundary silt loam,
and Newbell silt loam. Also included are Anglen silt loam, Kaniksu sandy loam, and Kiehl gravelly loam on

10:START-2\01080009\S714

7-9

-------
I

0105

terrace remnants; Belzar silt loam on the upper parts of the slopes; Rock outcrop on knobs; and poorly
drained soils in draws and adjacent to seeps and springs. Permeability is moderate in this Threemile soil.
Available water capacity is low. The effective rooting depth is 40 to 60 inches. Runoff is rapid, and the
hazard of water erosion is severe. (USDA 1992)

The Pend Oreille Mine/Mill and surrounding area is underlain by Metaline Limestone, which is
overlain by Ledbetter Slate. On the surface above the mine workings, a very large part of the Ledbetter and
some of the Metaline is concealed beneath Quaternary lake deposits that range in thickness from a thin
veneer to 200 feet or more. This glacial covering is especially extensive east of Pend Oreille River, Most of
the carbonate rock is medium-to-dark-gray crystalline dolomite, commonly having a medium- to
coarse-grained texture, but some very fine-grained, gray limestone is exposed at many places in both the
eastern and western mine workings. Some dolomite is creamy, light gray, or black, and locally the grain size
is very fine. (Ecology 2000)

The uppermost 25 feet of the Metaline commonly contains irregular zones of dark-gray to Mack
crystalline limestone, although at other places all rock in this position is dark crystalline dolomite. Black
shaley partings and some shale lenses a few inches thick are locally present in these upper rocks. At many
places altered rock is in the form of irregularly-shaped masses of dolomite breccia that range widely in size

i

and grade imperceptibly into non-brecciated dolomite. As a very general statement it can be said that the
uppcniiusi 150 feet of Metaline Limestone in the Fend Oreiiie Mine/Mili and surrounding area is crystalline
dolomite that overlies gray limestone, although at places gray massive limestone is found 50 feet or less
below the slate. (Ecology 2000)

Approximately 13,698 upgradient acres of land are expected to drain through a source area at the
site (USGS various dates). The drainage area for the waste rock pile at the site is estimated to be 64 acres
(USGS various dates).

Mines/mills adjacent and/or near the Pend Oreille River are assumed to flood at least every two
years (USGS 1998a).

7,6 Tributaries

Tributaries to the lower Pend Oreille River that were sampled as part of this field effort include
Linton Creek, Sullivan Creek, Hume Creek, Beaver Creek, Slate Creek, Ledbetter Creek, Everett Creek,
unnamed tributary, Lime Creek, and Pewee Creek (Figure 7-12). Sample results are summarized in Tables
7-5 and 7-6.

1Q:START-2\01O8OOO9\S714

7-10

-------
0106

Linton Creek is located on the west side of the Pend Oreille River 1 mile upstream from Metaline
Falls and approximately 11 miles upstream from Boundary Dam with an estimated flow of 2 cfs (Ecology
2001b). Sullivan Creek is located on the east side of the Pend Oreille River approximately Vz mile
downstream from Metaline Falls and 9 miles upstream from Boundary Dam with an estimated flow less than
10 cfs on the North Fork of Sullivan Creek and an estimated flow between 30 and 170 cfs on Sullivan Creek
(Ecology 2001b). Flume Creek is located on the west side, of the Pend Oreille River approximately 1 mile
downstream from Metaline Falls and 8 miles upstream from Boundary Dam with an estimated flow between
5 and 35 cfs (Ecology 2001b). Beaver Creek is located on the west side of the Pend Oreille River
approximately 2 miles downstream from Metaline Falls and 7 miles upstream from Boundary Dam. Slate
Creek is located on the east side of the Pend Oreille River approximately 4 miles downstream from Metaline
Falls and 5 miles upstream from Boundary Dam. Ledbetter Creek is located on the west side of the Pend
Oreille River approximately 5 miles downstream from Metaline Falls and 4 miles upstream from Boundary
Dam. Everett Creek is located on the west side of the Pend Oreille River approximately 5 miles downstream
from Metaline Falls and 4 miles upstream from Boundary Dam. The unnamed tributary is located on the
east side of the Pend Oreille River approximately 7 miles downstream from Metaline Falls and 3 miles
upstream from Boundary Dam. Lime Creek is located on the east side of the Pend Oreille River
approximately 7 miles downstream from Metaline Falls and 1 mile upstream from Boundary Dam. Pewee
Creek is located on the west side of the Pend Oreille River approximately 9 miles downstream from'

Metaline Falls and 1 mile upstream from Boundary Dam.

7.7 Targets

This section discusses potential target information for the 5 mines that were sampled; namely, Blue
Bucket Mine, Oriole Mine, Josephine Mine, Grandview Mine/Mill, and the Pend Oreille Mine/Mill.

The Clark-Fork/Pend Oreille Basin is characterized by highly valued recreational and economic
resources and is the central focus of nearly every major urban, industrial and agricultural activity in the
region. Vast resources of minerals, timber, fish, wildlife, water, rangeland, and croplands support a variety
of human uses, ranging from mining and agriculture to recreational fishing and boating. (EPA 1993)

Surface water intakes are reported to He within the surface water target distance limit (TDL) for
each of the mines/mills sampled. Refer to Table 7-2 for surface water intakes for each mine/mill. The
average number of persons per household in Pend Oreille County is 2.51; therefore, the START-2 estimates
the following:

10;START-2\01080009\S714

7-11

-------
0107

•	There are 112.95 persons using surface water for drinking water within a 4-mile radius of
Blue Bucket Mine;

•	There are 112.95 persons using surface water for drinking water within a 4-mile radius of
Oriole Mine;

•	There are 92.87 persons using surface water for drinking water within a 4-mile radius of
Josephine Mine;

•	There are 143.07 persons using surface water for drinking water within a 4-mile radius of
Grandview Mine/Mill; and

•	There are 130.52 persons using surface water for drinking water within a 4-mile radius of
Pend Oreille Mine/Mill. (Ecology 2001a)

The START-2 expects that surface water will be used within the TDL for irrigation of commercial
food or forage crops or for watering of commercial livestock-

Fishing occurs on Pend Oreille River; however, the river is relatively underutilized with respect to
fisheries (BLM 2001). Boundary Dam notes that visitors can fish for rainbow trout as they drift down the
river in a raft or boat (BLM 2001). Seattle City Light is promoting tourism with
www.cityofseattle.net/light/tours/boundary (Baker 2001). Fishing around Box Canyon Dam has been
documented; however, fish catch data are not available. The area contains trout, perch, catfish, but no
steelhead or salmon (Owens 2001).

Most of the fishing that occurs on the Pend Oreille River is by local residents, and is concentrated at
the mouth of major tributaries such as Flume, Sullivan, and Slate creeks. Some boating occurs on the river
adjacent to the mine/mill areas. Rafting, innertubing, swimming, jetskiing, and waterskiing occur
predominantly upstream from the 5 mines/mills that were sampled between Box Canyon Dam and Metaline
Falls. A privately-conducted jet-boat tour of the Pend Oreille River from Box Canyon to Boundary Dam
passes by the 5 mines/mills that were sampled approximately four days each week during late spring,
summer, and early fall tourist season. At present, the only boat launches along this stretch of the Pend
Oreille River are in Metaline and at the Boundary Dam (Ecology 2000).

One fish species present in the lower Pend Oreille River has been listed as threatened by the federal
government; bull trout (Salvelinus confluentus), a Federal listed threatened species found in the Columbia
River basin distinct population segment, was listed as a threatened species by the United States Fish and
Wildlife Service on June 10, 1998. One bird species present in the lower Pend Oreille River has been listed
as threatened or endangered by the state or federal government. The American peregrine falcon (Falco
peregrinus cmatum; a State listed endangered species) typically lives along mountain ranges, river valleys,

10:START-2\01080009\S714

7-12

-------
0108

and coastlines. Peregrine falcons may occasionally fly along Pend Oreille River near the 5 mines/mills that
were sampled. (Ecology 2000)

Five mammal species in the vicinity of the 5 mines/mills that were sampled have been listed as
threatened or endangered by the state or federal government. Gray wolves (Canis lupus-, a Federal listed
endangered species) have been sighted and their presence confirmed in the Colville National Forest,
although these are likely lone dispersing wolves. Camera surveillance has not detected wolves, and no
systematic surveys for wolves have been conducted. Grizzly bears (Ursus arctos; a Federal listed threatened
and State listed endangered species) are present throughout the Colville National Forest, although the
number of bears is lower near Lake Sullivan and the 5 mines/mills that were sampled. A grizzly bear den
has been found on the Colville National Forest, east of the Pend Oreille Mine/Mill near the Idaho border,
and grizzly bears have been radio-located on both sides of the Pend Oreille River. The Pend Oreille
Mine/Mill is adjacent to a designated grizzly bear recovery area, which begins east of State Route 31. The
North American (Canada) lynx (Lynx canadensis-, a proposed Federal listed threatened or endangered and
State listed threatened species) may travel through the 5 mines/mills areas that were sampled; tracks of lynx
were found in the Slate Creek drainage in 1978. The Pacific fisher (Martes pennanti pacifica-, a Federal
listed species of concern and State listed endangered species) is a large, weasel-like animal. There have
been unconfirmed sightings in the 5 mine/mill areas that were sampled, and it is believed that the fisher may
be present around Sullivan and Slate creeks, as well as Sullivan Lake. The woodland (mountain) caribou
(Rangifer tarandus caribou-, a Federal and State listed endangered species) could potentially enter the 5
mine/mill areas that were sampled, but all woodland caribou that have been previously signted on or near the
Pend Oreille Mine/Mill were transplanted animals that had been released nearby and were returning to the
release site. There is a woodland caribou recoveiy area which includes mostly wilderness area east of the
Pend Oreille Mine/Mill, within 25 miles south of the International Border, and further east into Idaho.

(Ecology 2000)

Recreational activities that occur in the nearby Colville National Forest include hiking, camping,
fishing, picnicking, mountain biking, cross-country skiing, snow shoeing, snowmobiling, horseback riding,
wildlife viewing, motorized travel, and recreational gold panning and dredging. Hunting is not allowed on
lands owned by Teck Cominco American Inc. (Ecology 2000).

The Salmo-Priest Wilderness Area is located approximately 3 miles east of the Pend Oreille
Mine/Mill. The Wilderness Area covers 39,940 acres and is within the Colville and the Idaho Panhandle
National Forests. Recreational use in this wilderness area is limited compared to other wilderness areas
within the state because of its distance from large population centers. Recreational activities that occur

10: START-2\01080009\S714

7-13

-------
0109

within the wilderness area include hunting, fishing, camping, mountain biking, wildlife viewing, and winter
sports (Ecology 2000).

Farms and rural residential development are found to the east and south of the 5 mine/mill areas that
were sampled. The main crops raised on agricultural lands along the Pend Oreille River are small grains and
hay. Most of the agricultural land in the area originated from 160-acre plots that were homesteaded at the
turn of the century. A few privately-owned farms occur in the vicinity of the Pend Oreille Mine/Mill and
the other four mines/mills that were sampled. They are operated primarily for growing hay and raising
cattle. Such farms are located north of the Pend Oreille Mine/Mill along Threemile Creek, east of State
Route 31 opposite the mine entrance, and across the Pend Oreille River north of Flume Creek. These
operators also lease USFS-managed lands in close proximity to their base properties for use as summer
pasture. The closest relatively high-density residential area is Pend Oreille Village, located along the river
approximately 1.5 miles south of the Pend Oreille Mine/Mill. At present, the village has approximately 30
residents. The town of Metaline Falls, population 230, is located approximately 2 miles southwest of the
Pend Oreille Mine/Mill. To the east of Metaline Falls is the community of Lehigh Hill, with a population of
45. Metaline is located across the river from Metaline Falls and has a population of 172. USFS-managed
lands are located to the north of the 5 mine/mill areas sampled. Boating activities are common on the Pend
Oreille River, especially on weekends, from the spring through the fall. (Ecology 2000)

There are no schools or day-care facilities within 200 feet of the 5 mine/miii areas that were
sampled.

According to National Wetland Inventory maps:

•	0.47 linear miles of wetland frontage exists along the Pend Oreille River to the International
Border for Blue Bucket Mine;

•	0.47 linear miles of wetland frontage exists along the Pend Oreille River to the International
Border for Oriole Mine;

•	0.03 linear miles of wetland frontage exists along the Pend Oreille River to the International
¦ Border for Josephine Mine;

•	0.430 linear miles of wetland frontage exists along the Pend Oreille River to the International
Border for Grandview Mine/Mill;

•	0.03 linear miles of wetland frontage exists along the Pend Oreille River to the International
Border for Pend Oreille Mine/Mill. Wetlands were identified by Ecology at five additional
locations on site:

•	1.5 acres of wetland area exists along Threemile Creek near the northeastern corner of the site,
2 acres of artificially-created wetland area exists along the eastern side of TDF-1,

10:START-2\Q1080009\S714

7-14

-------
0110

•	0.01 acre of wetland area exists between TDF-2 and TDF-1 at the base of the TDF-2
embankment,

•	0.1 acre of wetland area exists along Creek 3,

•	1,5 acres of wetland area is associated with the upper portions of Frog Creek (Figure 6-12).
Wetlands are located throughout the watershed, interspersed along the Pend Oreille River (USFWS 1987).

7.8 Sample Locations

Four surface water and 20 sediment samples, including three representative background samples
were collected from the lower Pend Oreille River and its tributaries and were submitted for EPA CLP
analysis by E & E (Figure 7-1). This includes one sediment sample collected at the sand bar at Myers Dam
and two surface water samples collected at the Metaline Falls Municipal Water Intake. The data for the
aforementioned sediment and two surface water samples are found in Appendices F and G, respectively.

Two surface water samples, which includes a background, were collected on the Pend Oreille
Mine/Mill property to determine whether contaminants from the tailings at the Pend Oreille Mine/Mill have
impacted the unnamed creek and the lower Pend Oreille River. POCKOISW was collected north of TDF-1
and TDF-2 on the unnamed creek identified as Creek 1. This surface water sample was co-located with
sediment sample POCKOISD.

Two sediment samples were collected on the Pend Oreille Mine/Mill at two springs flowing through
wetlands located adjacent to TDF-1( POSP01SD and POSP02SD; Figure 6-12). The water from both
springs flowed into intervention trenches which feeds Into the Pend Oreille River.

Four sediment samples were collected from upstream reaches of the Pend Oreille River to determine
whether contaminants from any upgradient mining sources have impacted the lower Pend Oreille River.
Samples were collected at the following locations (Figure 7-1):

•	The northern most point of the Pend Oreille River below the Boundary Dam (PRRS01SD);
Upstream of Lime Creek (PRRS02SD);

,• Downstream of the Pend Oreille Mine/Mill and upstream of Threemile Creek (PRRS03SD);
and

•	Upstream of the Pend Oreille Mine/Mill and downstream of Grandview Mine/Mill at the
confluence of Flume Creek and the Pend Oreille River (PRRS04SD).

lfcSTART-2\01Q80009\S714

7-15

-------
0111

Nine sediment samples were collected from the tributaries of the Perid Oreille River, to document
the distance contaminants have migrated and whether targets, such as wetlands, communities, and
reservoir/lakes have been impacted. Samples were collected at the following locations (Figure 7-1):

•	Upstream of the confluence of Lime Creek with the Pend Oreille River (PRTB01SD);

•	Upstream of the confluence of Everett Creek with the Pend Oreille River (PRTB02SD);

•	Upstream of the confluence of Ledbetter Creek with the Pend Oreille River (PRTB03SD);

•	Downstream of PRTB02SD and upstream of PRTB01SD at an unnamed creek (PRTB04SD);

•	Upstream of the confluence of Slate Creek with the Pend Oreille River (PRTB05SD);

•	Upstream of the confluence of Pewee Creek with the Pend Oreille River (PRTB06SD);

•	Upstream of the confluence of Beaver Creek with the Pend Oreille River (PRTB07SD);

•	Upstream of the confluence of Sullivan Creek with the Pend Oreille River (PRTB08SD); and

•	Upstream of the confluence of Linton Creek with the Pend Oreille River (PRTBG9SD).
Two	surface water and sediment samples were collected by Weston upstream of the confluence of

Flume Creek with the Pend Oreille River (UW002SW, UW003SW, US002SD, and US003SD, respectively;
Figure 7-1).

7.9 Sample Results

Pend Oreille Mine/Mill. Sample results are summarized in Table 7-3 and 7-4. Zinc was detected
at an elevated concentration in POCKOISW at an estimated low 63.2 figfL JL. Cadmium was detected at an
elevated concentration in POCKOISD at 3.5 mg/kg. Lead was detected at an elevated concentration in
POCKOISD at 180 mg/kg. Nickel was detected at an elevated concentration in POCKOISD at 44.8 mg/kg.
Vanadium was detected at an elevated concentration in POCKOISD at 26.8 mg/kg. Zinc was detected at an
elevated concentration in POCKOISD at an adjusted concentration of 217 mg/kg AC.

Arsenic was detected at elevated concentrations in POSPOISD and POSP02SD at 17.2 nag/kg and
11.8 mg/kg, respectively. Cadmium was detected at elevated concentrations in POSPOISD and POSP02SD
at 9,8 mg/kg and 14.6 mg/kg, respectively. Copper was detected at an elevated concentration in POSP02SD
at an estimated low concentrations of 165 mg/kg JL. Lead was detected at elevated concentrations in
POSPOISD and POSP02SD at 351 mg/kg and 1,960 mg/kg, respectively. Mercury was detected at an
elevated concentration in POSP02SD at 0.39 mg/kg. Vanadium was detected at an elevated concentration in
POSP02SD at 20.8 mg/kg. Zinc was detected at elevated concentrations in POSPOISD and POSP02SD at
3,320 mg/kg and 2,610 mg/kg, respectively.

10:START-2\01080009\S714

7-16

-------
0112

Pend Oreille River. Sample results are summarized in Table 7-5. No analytes were detected at an
elevated concentration in the sediment samples collected in the Pend Oreille River.

Flume Creek. Sample results are summarized in Tables 7-5 and 7-6. No analytes were detected at
an elevated concentration in the sediment and surface water samples collected on Flume Creek.

Linton Creek. Sample results are summarized in Table 7-5. No analytes were detected at an
elevated concentration in the sediment sample collected in Linton Creek.

Sullivan Creek. Sample results are summarized in Table 7-5. No analytes were detected at an
elevated concentration in the sediment sample collected in Sullivan Creek.

Beaver Creek. Sample results are summarized in Table 7-5. No analytes were detected at an
elevated concentration in the sediment sample collected in Beaver Creek.

Slate Creek. Sample results are summarized in Table 7-5. No analytes were detected at an elevated
concentration in the sediment samples collected in Slate Creek.

Ledbetter Creek. Sample results are summarized in Table 7-5. "4,4'-DDT" was detected at an
elevated concentration in PRTB03SD at 10 mg/kg.

Everett Creek. Sample results are summarized in Table 7-5. Cadmium was detected at an elevated
concentration in PRTB02SD at 6.1 mg/kg. Chromium was detected at an elevated concentration in
PRTB02SD at 86.2 mg/kg.

Unnamed Tributary. Sample results are summarized in Table 7-5. No analytes were detected at
an elevated concentration in the sediment sample collected in the unnamed tributary.

Lime Creek. Sample results are summarized in Table 7-5. Chromium was detected at an elevated
concentration in PRTB01SD at 57.7 mg/kg. Selenium was detected at an elevated concentration in
PRTBOISD at an estimated low 4.9 mg/kg JL.

Pewee Creek. Sample results are summarized in Table 7-5. No analytes were detected at an
elevated concentration in the sediment sample collected in Pewee Creek.

Myers Dam. Refer to Appendix E. One sediment sample was collected from the sand bar
(MDSB01SD).

Metaline Falls Domestic Drinking Water Intake. Refer to Appendix F. Two surface water
samples were collected from the Metaline Falls domestic drinking water intake (MF01SW and MF02SW).
MF01SW was collected at the confluence of the intake to Linton Creek. MF02SW was collected at the
origin of the spring.

10:START-2\01080009\S714

7-17

-------
Table 7-1

MINE AND MILL PPE LOCATIONS
LOWER PEND OREILLE RIVER MINES AND MILLS
PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS
PEND OREILLE COUNTY, WASHINGTON

MINE

PPE

LOCATION

Blue Bucket
(Figure 6-2)

PPE1

Galvanized metal culvert under forest service road
entering unnamed creek.

PPE2

Potential flow from shaft to unnamed creek
approximately 5 feet.

PPE 3

Waste rock pile to unnamed creek approximately 30
feet.

Oriole
(Figure 6-4)

PPE 1

20 feet southeast of shaft a spring originates and
flows approximately 75 feet before coming into
contact with the waste rock pile. The spring then
flows adjacent to the waste rock pile. At the base of
the waste rock pile is PPE1.

PPE2

Located approximately 160 feet southeast of PPE 1,
where the waste rock pile comes into contact with
the spring.

PPE3

Potential overland pathway to Linton Creek.

Josephine Mine
(Figure 6-6)

PPE1

Approximately 2 feet southeast of the collapsing
wood structure a spring originates and flows
approximately 40 feet and joins the Pend Oreille
River.

PPE2

PPE2 is 60 feet long and is the entire length of the
waste rock pile which enters the Pend Oreille River.

Grandview Mine/Mill
(Figure 6-12)

GMPP04

PPE1 is the overland flow from the mine workings
on the upper level to the Pend Oreille River.

GMPP05

PPE2 is the overland flow west from the tailings pile
approximately 300 feet to the Pend Oreille River,

Pend Oreille Mine/Mill
(Figure 6-12)

PPE1

The ventilation shaft at the mine is flowing
approximately 1,260 feet in a northwest direction
towards the Pend Oreille River.

PPE2

PPE2 is the overland flow in a northwestern
direction fromTDF-1 through Creek 2
approximately 1,585 feet to the Pend Oreille River

PPE3

PPE3 is approximately 882 feet long and is the
entire length of the waste rock pile that is contacting
the Pend Oreille River.

Potential
PPE4

Potential PPE4 is the overland flow in a northern
direction from TDF-2 (for approximately 1,260 feet)
through Creek lfor approximately 3,906 feet to the
Pend Oreille River.

0113

7-18

-------
01







Table 7-2









SURFACE WATER INTAKE WITHIN A 4-MILE RADIUS





LOWER PEND OREILLE RIVER MINES AND MILLS







PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS





PEND OREILLE COUNTY. WASHINGTON





Mine

1/4 Mile

1/2 Mile

1 Mile

2 M ile

3 Mile

4 Mile

Total

Blue Bucket Mine

0

3

0

¦ 18

14

10

45

Oriole Mine

0

0

• 5

6

16

18

45

Josephine Mine

1

1

0

19

8

8

37

Grandview Mine/Mill

0

0

4

20

8

25

57

Pend Oreille Mine/Mil

0

0

3

16

10

23

52

Source: Ecology 2001a

7-19

-------


Table 7-3



PEND OREILLE MINE/MILL SURFACE WATER



SAMPLES



LOWER PEND OREILLE RIVER

MINES AND MILLS



PRELIMINARY ASSESSMENTS AND

SITE INSPECTIONS



PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264265

01264266

CLP Inorganic ID

MJ0F10

MJ0F11

CLP Organic ID

NU

NU

E&E Sample ID

NU

NU

Station Location

TCBK01SW

POCK01SW

Description

Background

Release



Calcium

68300

130000

Magnesium

11900

31200

Zinc

2.5 UJK

63.2 .TL



(3.2 U AC)



Note:	Bold type indicates the sample concentration is above the detection limit

Underline type indicates the sample results is elevated as defined in Section 5.

Key:

AC	= adjusted concentration.

DV	-		I

wti	— uawKgiwuuu<

CK	= Creek 1.

CLP	= Contract Laboratory Program.

E&E	= Ecology and Environment, Inc.

EPA	= United States Environmental Protection Agency.

ID	= Identification.

J	= The analyte was positively identified. The associated numerical value is an estimate.

K	= Unknown bias.

L	= Low bias.

(ig/L	= micrograms per liter.

NU	= Not utilized.

PO	= Pend Oreille Mine/Mill.

SW	= surface water.

TAL	= Target analyte list

TC.	= Threemile Creek.

U	= The analyte was not detected. The associated numerical value is the contract required detection limit

7-20

-------






Table 7-4







PEND ORELLE MINE/MILL SEDIMENT SAMPLES







ANALYTICAL RESULTS SUMMARY





LOWER PEND OREILLE RIVER MINES AND MILLS





PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS





PEND OREILLE COUNTY, WAS

HINGTON



EPA Sample ID

01264264

01264263

01264351

01264352

CLP Inorganic ID

MJ0F09

MJ0F08

MJ0FK4

MJ0FK5

CLP Organic ID

J0F09

J0F08

J0FK4

J0FK5

E&E Sample ID

01050278

01050277

01050260

01050261

Station Location

TCBK01SD

POCK01SD

POSP01SD

POSP02SD

Depth (in. bgs)

0-8

0-8

0-8

0-8

Description

Background

Release

WHS®











Aluminum

2960

2100

476

1430

Arsenic

4.7 U

7.6 U

17J

11J

Cadmium

1.4 IB
(1.4 SQL)

M

21

14.6

Calcium

202000

115000

142000

175000

Chromium

5.7

93,

3.0

123

Copper

9.2 JL

(11 AC)

22.5 JL

23 JL

165.IL

Iron

8120

6130

56800

17000

Lead

6.8

180

351

1960

Magnesium

7090

35500

63400

57800

Manganese

211

455

202

254

Mercury

0.07 U

0.11 JB

0.09 JB

0.39

Nickel

13.8

44.8

10.3 JB

9.0 JB

Vanadium

11.9 JB
(11.9 SQL)

26.8

9.0 JB

20.8

Zinc

65.2 JH

326 JH
(217 AO

3320

2610

MSMssISSIffl

.(mm









TOC

1

18800 |

36100 |

62000

36100

Note:

Key;

AC

B

bgs

BK

CK

CLP

E&E

EPA

H

ID

ia

J

L

mg/kg

PO

SD

SQL

TAL

TC

U

Bold type indicates the sample concentration is above the detection limit
¦Underline type indicates the sample result is elevated as defined in Section 5,

« adjusted concentration.

= The reported concentration is between the instrument detection limit and the contract required detection limit,
= below ground surface.

= background.

= creek. ¦

= Contract Laboratory Program.

= Ecology and Environment, Inc.
a United States Environmental Protection Agency.

* High bias.

= Identification.

= inches.

= The analyte was positively identified. The associated numerical value is an estimate.

= Low Mas.

= milligrams per kilogram.

» tad Oreille Mine/Mill.

= sediment.,

= sample quantitation limit.

= Target analyte list
« TfareemUe Creek.

= The analyte was not detected. The associated numerical value is the contract requited detection limit

0116

7-21

-------














Table 7-5

~~







	





PEND OREILLE RIVER AND TRIBUTARY SEDIMENT SAMPLES ANALYTICAL RESULTS SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS PRELIMINARY ASSESSMENTS AND SITE INSPECTION!

PEND OREILLE COUNTY, WASHINGTON

EPA Sample ID

01264420

01264402

01264404

01264409

01264414

01264403

01264405

01264406

01264407

01264408

01264421

01264422

on

CLP Inorganic ID

MJ0GM9

MJ0GL1

MJ0GL3

MJ0GL8

MJOGM3

MJOGL2

MJ0GL4

MJ0GL5

MJ0GL6

MJ0GL7

MJ0GN0

MJ0GN1

MJ

CLP Organic ID

J0GM9

J0GL1

J0GL3

J0GL8

J0GM3.

J0GL2

J0GL4

J0GL5

J0GL6

J0GL7

J0GN0

J0GNI

JC

E & E Sample ID

01050244

01050231

01050233

01050238

01050241-

01050232

01050234

01050235

01050236

01050237

01050245

01050246

OH

Station Location

POBK01SD

PRRS0ISD

PRRS02SD

PRRS03SD

PRRS04SD

PRTB01SD

PRTBOIISD

PRTB03SD

PRTB04SD

PRTB05SD

PRTB06SD

PRTB07SD

PR!

Depth (in. bgs)

0-8

0-8

0-8

0-8

0-8

0-8

0-8

0-8

0-8

0-8

0-8

0-8

{

Location

Pend Oreille River

Lime
Creek

Everett

Creel;

Ledbetter
Creek

Unnamed
Tributary

Slate
• Creek

Peewee
Creek

Beaver
Creek

flu

	C

Description
I-AUMetaltfoiS/fcgJfr













*&?***>*£}

Release



ifSiiig

pup

n

Aluminum

11100

10709

8410

6950

7660

2470

3810

6610

2220

3530

5720

2620

1

Arsenic

It J

5,8

4.9

5.0

3.0 JB

2.4 U

5.6

16.2

33 U

83

2.8 JB

2.3 JB



Barium

183

123

85.6

443 JB

89.7

105 JB

91.0

99.7 JB

109 JB

48.1 JB

57.8 JB

44.2 JB

—I

Cadmium

0.57 JB
(0.37 SQL)

031 JB

0.09 U

0.11 U

0.88 JB

1.3 JB

U

1.0 JB

1.8 JB

0.40 JB

0.19 JB

0.98 JB

0.

Calcium

21500

24400 JL

2350 JL

3400 JL

12100 JL

206000 JL

59800 JL

14700 JL

342000 JL

49100 JL

1390 JB

3610

-

Chromium

17.6

23.9

19.7

17.1

17.1

57.7

m

13.8

8.2

7.0

10.1

6.2



Copper

25.9 JL
(31.6 AO

32.1

215

21.8

19.7

203

17.7

163

15.8 JB

12.0

8.1 JB

4.3 JB



Iron

27000

21700

14400

14200

14500

3240

9400

16200

4170

14200

15900

6700

2

Lead

35.7

28.1

9.4

8.3

383

7.1

38.7

23.2

12.7

13.6

7.6

4.6



Magnesium

mo

11200 JL

4660 JL

4450 JL

7540 JL

3060 JL

12100JL

7580 JL

5680 JL

27100 JL

2410

1200 JB



Manganese

921

429 JH
(346 AC)

217 JH
(17S AO

209 JH
(10 AQ

188 JH
(152 AO

93.7 JH
(7S.6 AO

246 JH
(198 AQ

517 JH
(417 AO

217 JH
(175 AO

209 JH
(167 AO

198

107



Nickel

20.9

19-2

1S4

14.1

143

8.0 JB

35.2

22.7

S.6JB

20.7

17.4

123



Potassium

2020 JB

1730

1340

978 JB

1180 JB

333 JB

938 JB

1170 JB

533 JB

990 JB

760 JB

405 JB

-

Selenium

13 U

0.87 UJK
(0.37 U AQ

0.88 UJK
(0.37 UAQ

0.90 UJK
(038 U AC)

1.1 UJK

(0.46 UAQ

49 JL

1.2 UJK
(0.50 UAQ

1.7 UJK
(0.71 O AQ

2.4 UJK
<1.0 UAQ

0.84 UJK
(036 U AQ

1.1 U

1.4U

0

Vanadium

283

41.6

3X8

313

11A

6.4 JB

42.9

33.0

8.6 IB

9.0 JB

15.6 JB

17.4



Zinc

287

130

54

43.8

205

58.2

342

163

493

107

60.9

59.8



|ftsuaifc«ingftg)B8!























f^-DDT"

| ' "a'u .

| ' 43 U

4.2 U

43 0

| 5.7 U | 10 U

__

I IS

| iiu

4.6 U

5 U

5.2 U

r







JT*«3B{iaW







¦is?*"F-W2S



1311111



Ifroc

1 13700

1 7610

1

i a»j

I 45600

[ 74800 J

r28900

1 48200

1 77300

1 14100

1 5490

| 38100

n

Note	Bold type indicates the simple cooccstratioo is above (be detection limh.

Underline type hwttrBfm the tangle results ia elevated as defined m Scctkm 5.

-------
Key:

AC	o Adjusted concentration.

B	o The reported concentration is between the instrument detection limit and the contraa required detection limit.

• bgs	" below ground surface.

BK	b Background.

CLP	a Contract Laboratory Program.

E&E	m Ecology and Environment, Inc.

EPA	a United States Environmental Protection Agency.

H	a High bias.

ID	¦ Identification,

in	a inches.

J	a TTie analyte was positively Identified. The associated numerical value is an estimate.

K	• Unknown Mas.

L	o Low bias.

mg/kg	s milligrams per kilogram.

KU	m Not

PO	a Pcnd Oreille Mine/Mill

PR	a Fend Oreille River.

RS	a river sediment

SD	a sediment

SQL	8 Sample quantitation limit

TAL	a Target analyte list

TB	a tributary.

TOC	a Total Organic Carbon.

U	= The analyte was sot detected The associated numerical value is the contract required detection limit.

US	= Tributary sedimentAoil (upstreamAipiand sampling location).

•vj

I

ro

LO

-------




Table 7-6







FLUME CREEK SURFACE WATER SAMPLES
ANALYTICAL RESULTS SUMMARY
LOWER PEND OREILLE RIVER MINES AND MILLS
PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS
PEND OREILLE COUNTY, WASHINGTON



EPA Sample ID

Ecotox Screening
Thresholds

Federal AWQC
Protection of
Aquatic Organisms

01264067

01264074

CLP Inorganic ID





MJOBOO

MJ0BQ6

CLP Organic ID





NU

NU

E & E Sample ID





NU

NU

Station Location





UW002SW

UW003SW

Description

Background

Release

Miaaasffiisi®







UK

@a§gi!«g^

Calcium |

NU

NU |

48.6 U j



12500

Source: EPA 1996; Ecology 1997.

1 Value is Hardness Dependent (100 mg/L as CaCoj).

' Value must be calculated based on characteristics of the specific surface water body.

Bold type indicates the sample concentration is above the detection limit

Note:

Key:

AWQC	= Ambient Water Quality Criteria.

CLP	= Contract Laboratory Program.

PAP.	— Byrtjftwy jm/J Cnirirnnmpwt lw>»

EPA	= United States Environmental Protection Agency.

ID	= Identification.

= micrograms per liter.	1 >

NU	= Not utilized.

TAL	= target analyte list

U	= The analyte was not detected. The associated numerical value is the contract required deed on limit

UW	= Upland surface water.

7-24

-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION 10

1200 SIXTH AVENUE
SEATTLE, WA 98101

TARGET SHEET

The following document was not imaged.

This is due to the Original being:

^ Oversized

CD Rom

Computer Disk
Video Tape
Other:

**A copy of the document may be requested from the Superfund Records Center.

*Document Information*

*1307153*

1.6.1-6

Upper Columbia (UCRSF)

Pend Oreille Mini /Mill, River, and Tributaries Sample Location Map Pend Oreille County

Washington

Document ID #:
File #:
Site Name:

-------
ecology and environment, inc.

Intomavrul SpecUBib in to En«Won™M

LOWER PEND ORJEILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 7-2

BLUE BUCKET MINE
4-MILE MAP

Dole:
2-28-02

Drawn by;
AES

10:START-2y01080009\S714\fig 7-2

7-27

-------
Source: DcLoroc 1998; USGS 1971.

Approximate Scale in Miles

j Target Distance Limit





fmcv *trr~ fx ^

Blue Bucket Mine |

ecology and environment, inc.

»ir> •* ErMranmarri

LOWER PEND OREILLE RTVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 7-3

BLUE BUCKET MINE
15-MILE MAP

Date:

2-28-02

Drawn by:

AJES

10;STAKT-2^DI080009\S714\fig 7-3

7-28

-------
Sourct:

Approximate Scale m Miles Sg

Oriole Mine

7-29

ecology and environment, Inc.

IntoTtuom Ifun.tm « m Enmnrart

LOWER PEND ORE FILE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

Figure 7-4

ORIOLE MJNE
4-MILE MAP

Ditc:
2-28-02

Drawn by:

AES

10: START -2V0108Q009\S714Uig 7-4

-------
Source: Maptcch. 2001

15 Mile Target Distance Limit
(approx. 1.8 miles beyond border)

Approximate Scale in Miles



Oriole Mine

ecology and environment, inc..

h+mmrrml ^niutoli ji r» Drtmwl

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Perad Oreille, Washington

Figure 7-5

ORIOLE MINE
15-MILE MAP

Dale:
2-28-02

Drawn by;
AES

(D-^TART-2VOI080Q09VS714\fig 7-5

7-30

-------
0125

ecology and environment, inc.

ImnmafionaJ Spocuujti if* lha Eflmyvrwnl
SmIM. Itahngibn

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Petid Oreille, Washington

Figure 7-6

JOSEPHINE MINE
4-MILE MAP

Daw:
2-28-02

Drawn by:
AES

10:START-2\01080009\S714tfig 1-6

7—3 L

-------
0126

,*ar .'yn

lost

m tn

et Distance Limit

pftnr *r-

Josephine Mine

7-32

ecology and environment, inc.

to t»£nvtag»7w*

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Peod Oreilte, Washington

Date:,

2-28-02

Drawn by;

AES

IO:STAKT-2\O10tS00(B\S714\fi>! 7-7

Figure 7-7

JOSEPHINE MINE
15-MILE MAP

-------
Source; DcLonmc 1998.

Approximate ScjIc in Miles

- 4 Miles}

¦rctomblo
Mtn /

3 Miles

2 Miles

•V/ /
1 Mile

f'r'\ s.JHrifrO'}
[O.SMileU y

0.25Mi)eiW»

itnes

¦Linton h rtn

•w> "V

IV

A&SJ , ' 7. - • jr-r

Site Locatioa

Pocah&nrcrs

\X^/M^yQeek

Figure 7-8
GRAND VIEW MINE/MILL
4-MILE MAP

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

ecology and environment, inc,

tntomaboftAl Spodjebnti « 
-------
Stiurce: DcLonne 1998; USGS 197). srS

^/s .. ¦. ? ¦'» w *r J?/

Approximate Scale In Miles

\Z03*

,Ud>$T
¦ MTN

Target Distance Limit

.¦>.7 . - '		

• Pi

if i" ¦ »			-i ¦ xr.

Grand view Mine

Figure 7-9

GRAND VTEW MINE/MILL
15-MILE MAP

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington

ecology and environment, Inc.

Drawn by:
AHS

10: START-2\£l 1080009\S714VCg 7-9

7-34

-------
Source: Msptcch, 2001

Appfoxim.nn Scale in Miles

4 Miles



3 Miles

2 Miles

WE

CJ0.5 MilctCZ
rptzz^zznX ,
^025 Mileffig

f i\A^m

Pcnd Oreille Mine

0129

ecology and environment, Inc.

Innw;l

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
Pend Oreille, Washington





Figure 7-10



PEND OREILLE MINE/MILL



4-MILE MAP

Date:

Drawn by:



3-1-02

AES

[0:START-2\OI080009\S714\fig 7-10

7-35

-------
Source: DcLormc 1998; USGS 197!

^V/' ,	•» WK »i*.i

m.~. I . HM.>TT ' I f »lT.

Approximate Scale in Miles

WTN

Target Distance Limit

jwrr

PIXD ON I .'LI J 00,

Pend Oreille Mine |

ecology a ad environment, inc.

hWMhul^'r'OlitiN&iwmrrt

LOWER PEND OREILLE RIVER

MINES AND MILLS
PRELIMINARY ASSESSMENTS
AND SITE INSPECTIONS
pL-nd Oreille, Washington

Figure 7-11

PEND OREILLE MINE/MILL
15-MILE MAP

Dale:

3-1-02

Drawn by:

AES

IO:START-2\01080009\S714\fig 7-11

7-36

-------
UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION 10

1200 SIXTH AVENUE
SEATTLE, WA 98101

TARGET SHEET

The following document was not imaged.

This is due to the Original being:

v Oversized
A

CD Rom

Computer Disk
Video Tape
Other:

**A copy of the document may be requested from the Superfund Records Center.

*Document Information*

*1307153*

1.6.1-6

Upper Columbia (UCRSF)

Document ID #:
File #:
Site Name:

Pend Oreille Mini /Mill, River, and Tributaries Project Area Tributaries Pend Oreille County

Washington Figure 7-12

-------
01

8. SUMMARY AND CONCLUSIONS

In June 2001, the START-2 visited 21 mines/mills located near the lower reaches of the Pend
Oreille River in Pend Oreille County, Washington. The purpose of the visits was to identify potential
contaminant source areas that may be impacting or have the potential to impact possible receptors/targets by
migration of contaminants via the surface water overland flow pathway. Of the 21 properties visited,
sampling was conducted at 5 mines/mills.

The Clark-Fork/Pend Oreille River system flows from Montana as the Clark Fork River into Lake
Pend Oreille in Idaho. The Pend Oreille River, originating as the outflow from Lake Pend Oreille, enters
Washington flowing north through the northeast corner of the state into Canada, where it drains to the
Columbia River just above the International Border (Figure 7-1; Ecology 1991). The Clark-Fork/Pend
Oreille Basin covers approximately 26,000 square miles in Montana, Idaho, and Washington (USGS 2000).

The PA and SI activities involved the collection of samples from potential hazardous substance
source areas and from target areas potentially impacted through contaminant migration. A total of 64
samples submitted for EPA CLP methods of analysis were collected, including background samples but
excluding QA samples. Samples were collected from potential hazardous substance source areas and from
potential target areas (Table 3-1). The media sampled included: surface soil, tailings, waste rock, sediment,
and surface water. Section 8.1 summarizes the findings and conclusions for each mine/mill sampled. For
the purposes of this investigation, significant/elevated concentrations are defined using Table 2-3 of the EPA
HRS model criteria for observed release. Refer to Section 5.1 for further discussion of the HRS model
criteria.

For those mines visited but not sampled due to no contaminant source observed or no surface water
overland flow migration pathway identified, no further action under CERCLA is recommended. A list of
those mines is presented in Table 8-1.

8.1 FINDINGS AND CONCLUSIONS
8.1.1 BLUE BUCKET MINE

Two co-located sediment and surface water samples were collected at the Blue Bucket Mine (Figure
6-2). Sample results are summarized in Tables 6-1 and 6-2. The PPE sediment samples contained

10:START-2W108Q009W714

8-1

-------
0133

significant concentrations of TAL metals including cadmium (2.8 mg/kg), lead (72,5 mg/kg), and zinc (373
mg/kg AC).

Migration of contaminants from the waste rock pile to the nearby unnamed creek may occur via
overland flow of runoff water with suspended sediments.

Analytical results of samples collected indicate that hazardous substances are migrating to targets
that include the unnamed creek, the Pend Oreille River, and habitat used by threatened and endangered
species.

Based on the findings of this investigation, further action under CERCLA or other authorities is
recommended.

8.1.2 ORIOLE MIME

One surface water and,two sediment samples were collected at the Oriole Mine (Figure 6-4).
Sample results are summarized in Tables 6-3 and 6-4. The PPE sediment samples contained significant
concentrations of TAL metals including cadmium (27 mg/kg), lead (714 mg/kg), manganese (4,120 mg/kg),
silver (5.6 mg/kg), and zinc (5,740 mg/kg).

Migration of contaminants from the waste rock piles to Linton Creek may occur via overland flow
of runoff water with suspended sediments.

Analytical results of samples collected indicate that hazardous substances are migrating to targets
that include Linton Creek, the Pend Oreille River, and habitat used by threatened and endangered species.]

Based on the findings of this investigation, further action under CERCLA or other authorities is
recommended.

8.13 JOSEPHINE MINE

One sediment sample was collected at the ppe of the waste rock pile into the Pend Oreille River.
One surface water sample was collected at the mouth of a spring originating from a collapsed wooden
structure on the property. The spring feeds into the Pend Oreille River (Figure 6-6). Sample results are
summarized in Tables 6-5 and 6-6.

The PPE sediment sample contained significant concentrations of TAL metals including cadmium
(9.6 mg/kg), lead (17,400), mercury (0.16 mg/kg), silver (2.3 mg/kg), and zinc (2,040 mg/kg). The spring
surface water sample contained significant concentrations of TAL metals including lead (21.5 Mg/L) and
zinc (117 jig/L).

10:START-2\01080009\S714

8-2

-------
0134

Migration of contaminants from the waste rock pile to the Pend Oreille River is occuring via direct
overland flow. The START-2 observed that the waste rock pile extends into the Pend Oreille River,
Migration of contaminants via an onsite spring that feeds into the Pend Oreille River may occur.

Analytical results of samples collected indicate that hazardous substances are migrating to targets
that include Flume Creek, the Pend Oreille River, and habitat used by threatened and endangered species.

Based on the findings of this investigation, further action under CERCLA or other authorities is
recommended.

8.1.4 GRANDVIEW MINE/MILL

In October 2000, EPA conducted sampling at the Grandview Mine/Mill. The field event included
the collection of samples from three on-site soil source areas including waste rock piles, a suspected tailings
pile, and an abandoned container area (Figures 6-8 and 6-9). Samples collected from the waste rock piles
contained significant concentrations of arsenic (44.0 mg/kg), cadmium (23.3 mg/kg), lead (4,930 mg/kg),
mercury (1.5 mg/kg), selenium (1.5 mg/kg) and zinc (7,420 mg/kg).

Samples collected from the suspected tailings pile contained significant concentrations of cadmium
(58.4 mg/kg), copper (91.5 mg/kg), lead (2,260 mg/kg), mercury (1.7 mg/kg; JL), selenium (1,1 mg/kg), and
zinc (19,100 mg/kg).

The abandoned container and drum area contained significant concentrations of arsenic (64.9
mg/kg), cadmium (99.5 mg/kg), copper (236 mg/kg), lead (14,600 mg/kg), mercury (6,0 mg/kg), selenium
(3,0 mg/kg), and zinc (36,200 mg/kg).

In June 2001, EPA collected PPE surface water and sediment samples. The PPE surface water and
sediment samples contained significant concentrations of TAL metals including cadmium (1.6 mg/kg), lead
(449 mg/kg), manganese (25.5 /xg/L), and zinc (864 mg/kg).

The October 2000 field event included the collection of samples from potential targets along the
groundwater migration, surface water migration, and soil exposure pathways including groundwater wells,
an unnamed spring, a former waste water drainage ditch, and the Pend Oreille River.

Elevated levels of TAL metals were detected in the Pend Oreille Village groundwater samples, the
unnamed spring co-located surface water and sediment samples, the Pend Oreille River sediment samples,
and the former wastewater drainage ditch surface soil samples.

Results of the October 2000 and June 2001 sampling events indicate that the Grandview Mine is a
source of hazardous substance contamination, including TAL metals. Analytical results of samples
collected indicate that hazardous substances are migrating to targets that include groundwater drinking water

10:START-2\01080009\S714

8-3

-------
0135

wells, the unnamed spring, the former wastewater drainage ditch, the Pend Oreille River and habitat used by
threatened and endangered species.

Further action under CERCLA or other authorities is recommended at this site,

8.1.5 PEND OREILLE MINE/MILL

Samples were collected from potential contaminant source areas at the Pend Oreille Mine/Mill
including three TDFs and one waste rock pile. Three PPE co-located sediment and surface water samples
were also collected. Sample locations are shown in Figure 6-12 and analytical results are summarized in
Tables 6-9,6-10, and 6-11.

Soil samples collected from source areas contained significant concentrations of TAL metals
including arsenic (40.0 mg/kg), cadmium (44.1 mg/kg), copper (242 mg/kg JL), lead (5,625 mg/kg AO,
mercury (0.58 mg/kg), selenium (3.1 mg/kg), silver (2.3 mg/kg), and zinc (9,300 mg/kg).

The PPE samples contained significant concentrations of TAL metals including barium (62.6 ug/L),
cadmium (6.1 mg/kg), lead (346 mg/kg), manganese (33.0 mg/kg) and zinc (2,370 mg/kg).

Analytical results of samples collected indicate that hazardous substances are migrating to targets
that include wetlands, the Pend Oreille River and habitat used by threatened and endangered species
Further action under CERCLA or other authorities is recommended at this site.

10:START-2\01Q8Q00mS714

8-4

-------
0136

Table 8-1

CIRCLA RECOMMENDATIONS AT MINES NOT SAMPLED
LOWER PEND OREILLE RIVER MINES AND MILLS
PRELIMINARY ASSESSMENTS AND SITE INSPECTIONS
PEND OREILLE COUNTY, WASHINGTON

EPA CERCLIS ED Number

Mine

CERCLA Activity Type

Recommendation

WANOO1002331

Sterling

Preliminary Assessment

No further action under CERCLA

WANOO1002328

Metaline

Preliminary Assessment

No further action under CERCLA

WANOO1002318

Bella May

Preliminary Assessment

No further action under CERCLA

WANOO 1002320

Diamond R,

Preliminaiy Assessment

No further action under CERCLA

WAN001002325

Lehigh No.l

Preliminaiy Assessment

No further action under CERCLA

WAN001002332

West Contact

Preliminary Assessment

No further action under CERCLA |

WAN001002326

Lehigh No.2

Preliminaiy Assessment

No further action under CERCLA I

WAN001002321

Hoage

Preliminaiy Assessment

No further action under CERCLA I

WAN001002327

Lucky Strike

Preliminaiy Assessment

No further action under CERCLA

WAN001002324

Lead King

Preliminary Assessment

No further action under CERCLA

to be provided

Z Canyon

Preliminary Assessment

No further action under CERCLA

to be provided

Lead Queen

Preliminary Assessment

No further action under CERCLA

WAN001002323

Lead Hill

Preliminary Assessment

No further action under CERCLA

to be provided

King Tut

Preliminary Assessment

No further action under CERCLA

1 to be provided

Red Top

Preliminary Assessment

No further action under CERCLA

8-5

-------
0137

9. REFERENCES

Baker, Lori, November 20, 2001, Recreation Specialist, Bureau of Land Management, Spokane,

Washington, telephone conversation regarding fishing at Boundary Dam with Renee Nordeen,
Ecology and Environment Inc., Seattle Washington.

Barlee, N.L., 1932, Gold Creeks and Ghost Towns of Northeastern Washington, Hancock House Publishers,
Blaine, Washington.

Battien, Pauline, 1998 fifth printing, The Gold Seekers...a 200 Year History of Mining in Washington, Idaho,
Montana, and Lower British Columbia, Eastern Washington University Libraries,
Statesman-Examiner, Inc., Colville, Washington.

Cawston, Colleen, August 2,1999, Chair, Colville Business Council, The Confederated Tribes of the
Colville Reservation, Nespelem, Washington, correspondence to Chuck Clark, Regional
Administrator, U.S. Environmental Protection Agency, Seattle, Washington.

Derky, Robert E.;Joseph, Nancy L.; Lasmanis, Raymond; November 1990, Metal Mines of Washington,

Preliminary Report, Washington Division of Geology and Earth Resources, Open File Report 90-18,
Washington State Department of Natural Resources.

Dings, M.G., and D.H. Whitebread, 1965, Geology and Ore Deposits of the Metaline Lead-Zinc District,
Pend Oreille County, Washington, United States Geological Survey Professional Paper No. 489,
Denver, Colorado.

Ecology and Environment, Inc., (E & E), 2001a, Sampling Quality Assurance Plan, Upper Columbia River
ESI.

	, 2001b, Field Logbooks for the Pend Oreille River ESI site.

Economic History, November 2001, Pend Oreille County,

http://www.wa.gov/pub/employinent_security/lmea/Jabnnrkt/eco/pendeco.htm

Godlewski, David, April 2001, environmental manager, Cominco American, Inc., Spokane, Washington,
telephone conversation regarding finalization of EIS, workers on the property, and valid permits
with Leatta Dahlhoff, Ecology and Environment, Inc., Seattle, Washington.

	June 2000, environmental manager, Cominco American, Inc., Spokane, Washington, telephone

conversation regarding amounts and measurements of sources on site with Leatta Dahlhoff, Ecology
and Environment, Inc., Seattle, Washington.

Hallinan, Patrick, January 22,2002, Washington State Department of Ecology (Ecology), Spokane,

Washington, email regarding update on finalization of Environmental Impact Statement few the Pend
Oreille Mine/Mill to Leatta Dahlhoff, Ecology and Environment, Inc., Seattle, Washington.

	, December 13,2001, Washington State Department of Ecology (Ecology), Spokane, Washington,

email regarding update on Pend Oreille Mine/Mill activities to Leatta Dahlhoff, Ecology and
Environment, Inc., Seattle, Washington.

10:START-2\01080009\S714

9-1

-------
0138

Lambly, Charles, April 1941, Methods and Costs of Mining Zinc-Lead Ores at the Pend Oreille Mines and
Metals Co., Northwest Mining News, Vol. 7, No. 8, pp. 4-11.

Lasmanis, R., 1995, History of the Metaline Mining District and the Pend Oreille Mine, Pend Oreille
County, Washington, Washington Geology, Vol. 23, No. 1, pp. 24-29.

Neale, Alfred, July 1962, acting director, Washington State Pollution Control Commission, Olympia,

Washington, letter to Marshall Huntting regarding the daily load of tailings discharged to the Pend
Oreille River during milling operations, Division of Mines and Geology, Olympia, Washington.

Owens, Mary, November 20, 2001, Pend Oreille County Public Utility District, Pend Oreille County,

Washington, telephone conversation regarding fishing at Box Canyon Dam with Renee Nordeen,
Ecology and Environment, Inc., Seattle, Washington.

Passmore, Gary, August 2,2000, Director, Office of Environmental Trust, The Confederated Tribes of the
Colville Reservation, Nespelem, Washington, correspondence to Monica Tonel, U.S. Environmental
Protection Agency, Seattle, Washington.

Pend Oreille County, October 2001, Profile, http://pendoreille.org/Pages/County%20Proflle.html.

Resource Finance Corporation (RFC), 1993, Feasibility Study Pend Oreille Project, Metaline Falls,
Washington.

Roy F Weston, Inc. (Weston), 2001, Upper Columbia River/Lake Roosevelt Expanded Site Inspection

Sampling and Quality Assurance Plan, TDD: 01-02-0001-A, EPA Contract: 68-S0-01-02. Prepared
for the EPA May 2001.

United States Bureau of Land Management (BLM), November 20, 2001, Recreation.Gov search for
Bounday Dam, http://www.recreation.gov/detail.cfm?ID=1771.

United States Department of Agriculture (USDA), 1992, Soil Survey of Pend Oreille County Area,
Washington.

United States Department of Commerce, Bureau of the Census (USBC), 2000 US Census Data, General
Housing Characteristics, Pend Oreille County, Metaline, Metaline Falls, http://www.census.gov.

United States Environmental Protection Agency (EPA), November 9, 2001, Clark Fork-Pend Oreille
Watershed, http://www.epa.gOv/a:oplaces/pait2/region0/site3.html.

	,2000a, Contract Laboratory Program Statement of Work for Inorganic Analyses.

	, August 2000b, EPA Abandoned Mine Site Characterization and Cleanup Handbook, EPA

910-B-00-001, Regions 8,9, and 10.

	, 1999a, Contract Laboratory Program Statement of Work for Organic Analyses.

	, April 1999b, National Recommended Water Quality Criteria-Correction Benchmarks.

	, 1996, Using Qualified Data to Document an Observed Release and Observed Contamination.

	, February 1994a, USEPA Contract Laboratory Program National Functional Guidelines for

Inorganic Data Review, OSWER 9240.1-05-01, PB 94-963502, EPA 540/R-94/013.

	, September 1994, Guidance for the Data Quality Objectives Process, EPA QA/G-4, Office of

Research and Development, Washington, D.C., EPA /600/R-96/055.

	, February 1993, Clark Fork-Pend Oreille Basin Water Quality Study, EPA 910/R-93-006.

10;START-2\Q1080009\S714

9-2

-------
0139

United States Fish and Wildlife Service (USFWS), 1987, National Wetlands Inventory Maps, Abercrombie
Mountain, Aladdin Mountain, Boundary Dam, Deep Lake, Gypsy Peak, lone, Metaline, Metaline
Falls, Monumental Mountain, Pass Creek, and Scotchman Lake Quadrangles; 1:24,000 scale.

United States Geologic Survey (USGS), 2000, Concentrations of Selected Trace Elements in Fish Tissue
and Streambed Sediment in the Clark Fork-Pend Oreille and Spokane River Basins, Washington,
Idaho, and Montana, 1998, Water-Resources Investigations Report 00-4159, Boise, Idaho.

	, 1998a, Magnitude and Frequency of Floods in Washington, Water-Resources Investigations Report

97-4277, Tacoma, Washington.

	, 1998b, Determination of Upstream Boundary Points on Northeastern Washington Streams and

Rivers Under the Requirements of the Shoreline Management Act of 1971, Water-Resources
Investigations Report 98-4160, Tacoma, Washington.

	,1992a, 1:24,000 Scale Topographic Map, Boundary Dam, Washington.

	,1992b, 1:24,000 Scale Topographic Map, Metaline, Washington.

	,1992c, 1:24,000 Scale Topographic Map, Metaline Falls, Washington.

	,1992d, 1:24,000 Scale Topographic Map, Gypsy Peak, Washington.

	, 1984,1:100,000 Scale Topopgraphic Map, Colville, Washington.

	, 1967,1:24,000 Scale Topographic Map, Pass Creek, Washington, Revised 1986.

	, 1964, Drainage-Area Data for Eastern Washington, Open File Release.

Washington Department of Ecology (Ecology), December 2001a, Water Rights Application Tracking
Certificates, Pend Oreille County, Washington.

	, January 2001b, Request for Public Record of streamflow rates of tributaries on the Pend Oreille

River, Pend Oreille County, Washington.

—;	.February 2000, Draft Environmental Impact Statement: Pend Oreille Mine Project, Pend Oreille

County, Washington.

	July 1992, Draft Pend Oreille River Management Plan, Water Body No. WA-62-1020, Segment No.

23-j62-05.

	.November 1991, Pend Oreille River Primary Productivity and Water Quality of Selected Tributaries,

Water Body No. WA-62-1020, Segment No. 23-62-05, Report 91-e08.

Western Regional Climate Center (WRCC), November 2001, Precipitation Records for Metaline Falls,
Washington, http:Wwww.wrcc.dri.edu.climsum.html.

Zeigler, W.L., June 1949, Pend Oreille, New Development, Mining World, Vol. 11, No. 7, pp. 14-17.

10:START-2\01080009\S714

9-3

-------
0140

a*&''	ftt-Sf'v

j£i* *W§gii£rZi''-

Vr££ J~^~-, ' n
^/"Tv-7 A,

V£

^APPENDIX A

J®..- V

^ jr	jgp^'

PHOTOGRAPHieDOCUMENTATION

Mi M*

iT«C3Si-t

m*

mS-



V-tf< ^,VS^S~«1

-s?

Jf'

10:START-2\01080009\S714

-------
0141





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No.

Date

Time

By

Direction

Description

1-1

6/26/01

0845

LD

N

View of empty copper sulfate storage tanks that used to be
surrounded by berms at Pend Oreille Mine. The tanks are
scheduled to be removed off site.

1-2

6/26/01

0846

LD

NW

View of staged soil at Pend Oreille Mine where plastic tanks
resided when PA was conducted in May 1999. The soil is
scheduled to be shipped to Arlington.

1-3

6/26/01

0850

LD

NE

Panoramic view of tailings pile No. 3 at Pend Oreille Mine.

1-4

6/26/01

0851

LD

E

Panoramic view of tailings pile No. 3 at Pend Oreille Mine.

1-5

6/26/01

0852

LD

E

Panoramic view of tailings pile No. 3 at Pend Oreille Mine.

1-6

6/26/01

0853

LD

S

Panoramic view of tailings pile No. 3 at Pend Oreille Mine.

1-7

6/26/01

0914

LD

S

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-8

6/26/01

0915

LD

SW

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-9

6/26/01

0916

LD

W

Panoramic view of tailings pile No. 1 from grave) road through
center of pile/pond at Pend Oreille Mine.

1-10

6/26/01

0917

LD

W

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-11

6/26/01

0918

LD

NW

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-12

6/26/01

0919

LD

N

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-13

6/26/01

0920

LD

N

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-14

6/26/01

0921

LD

NE

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-15

6/26/01

0922

LD

E

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-16

6/26/01

0923

LD

SE

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-17

6/26/01

0924

LD

E

Panoramic view of tailings pile No. 1 from gravel road through
center of pile/pond at Pend Oreille Mine.

1-18

6/26/01

0934

LD

NE

View of intercept trench at Pend Oreille Mine which connects
to another trench which then discharges into Pend Oreille
River.

1-19

6/26/01

1016

LD

S

View of guard office/entry gate construction at Pend Oreille
Mine.

1-20

6/26/01

1020

LD

S

View of upper level tailings pond No. 1 with vegetation at Pend
Oreille Mine.

1-21

6/26/01

1021

LD

N

View of lower level tailings pond No. 1 with vegetation at Pend
Oreille Mine.

1-22

6/26/01

1030

LD

E

Panoramic view of waste rock pile at Pend Oreille Mine.

-------
0142





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No.

Date

Time

By

Direction

Description

1-23

6/26/01

1031

LD

SE

Panoramic view of waste rock pile at Pend Oreille Mine.

1-24

6/26/01

1032

LD

SE

Panoramic view of waste rock pile at Pend Oreille Mine.

1-25

6/26/01

1033

LD

S

Panoramic view of waste rock pile at Pend Oreille Mine.

2-1

6/26/01

1034

LD

SW

Panoramic view of waste rock pile at Pend Oreille Mine.

2-2

6/26/01

1035

LD

SW

Panoramic view of waste rock pile at Pend Oreille Mine.

2-3

6/26/01

1036

LD

NW

Panoramic view of waste rock pile at Pend Oreille Mine.

2-4

6/26/01

1037

LD

N

Panoramic view of waste rock pile at Pend Oreille Mine.

2-5

6/26/01

1038

LD

NE

Panoramic view of waste rock pile at Pend Oreille Mine.

2-6

6/26/01

1039

LD

NW

View of field team collecting sample POWP02SS at lower level
of waste rock pile at Pend Oreille Mine.

2-7

6/26/01

1040

LD

S

View of lower level of waste rock pile at Pend Oreille Mine.

2-8

6/26/01

1041

LD

W

View of surface water drainage routes from the upper level of
the waste rock pile to the lower level at Pend Oreille Mine.

2-9

6/26/01

1042

LD

W

View of field team heading down to lower level of the Pend
Oreille Mine waste rock pile, which abuts Pend Oreille River.

2-10

6/26/01

1045

LD

NE

View of waste rock pile base at Pend Oreille Mine.

2-11

6/26/01

1046

LD

SW

View of surface water drainage from base of waste rock pile at
Pend Oreille Mine to Pend Oreille River.

2-12

6/26/01

1052

LD

E

View of waste rock pile at Pend Oreille Mine and edge of bank
and pool of water on Pend Oreille River.

2-13

6/26/01

1053

LD

E

View of surface water runoff drainage route from Pend Oreille
Mine into Pend Oreille River.

2-14

6/28/01

1153

MT

E

View of domestic water supply after confluence of Linton
Creek and Metaline domestic drinking water supply.

2-15

6/28/01

1155

LD

SW

Close-up view of sample collected at confluence.

2-16

6/28/01

1200

MT

N

Sample location upgradient from Metaline domestic drinking
water supply and confluence with Linton Creek.

2-17

6/28/01

1205

LD

SW

Close-up view of upgradient Metaline water supply
spring/intake sample.

2-18

6/28/01

1206

LD

sw

Close-up view of upgradient Metaline water supply
spring/intake sample.

3-1

6/25/01

0845

LD

down

View of adit water discharge at Pend Oreille Mine.

3-2

6/25/01

1100

CG

NE

Sample location PRRS01SD along Pend Oreille River.

3-3

6/25/01

1100

CG

NE

Sample PRRS01SD collected along Pend Oreille River.

3-4

6/25/01

1140

CG

sw

View of Pewee Creek (tributary to Pend Oreille River).

3-5

6/25/01

1205

CG

SE

Sample location PRTB01SD at Lime Creek.

-------
0143





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No.

Date

Time

By

Direction

Description

3-6

6/25/01

1205

CG

SE

Sample PRTB01SD.

3-7

6/25/01

1210

CG

SE

View of Lime Creek (tributary to Pend Oreille River) from
Pend Oreille River.

3-8

6/25/01

1230

CG

N

Sample location PRRS02SD.

3-9

6/25/01

1230

CG

N

Sample PRRS02SD.

3-10

6/25/01

1345

CG

NW

Sample location PRTB02SD.

3-11

6/25/01

1345

CG

NW

Sample PRTB02SD.

3-12

6/25/01

1355

CG

NW

View of Everett Creek (tributary to Pend Oreille River) from
Pend Oreille River.

3-13

6/25/01

1415

CG

W

Sample location PRTR03SD.

3-14

6/25/01

1415

CG

W

Sample PRTR03SD.

3-15

6/25/01

1425

CG

SW

View of Ledbetter Creek (tributary to Pend Orielle River) from
Pend Oreille River.

3-16

6/26/01

1010

CG

NW

Sample location PRTB04SD.

3-17

6/26/01

1010

CG

SE

Sample PRTB04SD.

3-18

6/26/01

1020

CG

NW

View of unnamed tributary to Pend Oreille River (from Pend
Oreille River).

3-19

6/26/01

1035

CG

NE

View of Slate Creek (tributary to Pend Oreille River) from
Pend Oreille River. 1

3-20

6/26/01

1036

CG

NE

View of Slate Creek (tributary to Pend Oreille River) from
Pend Oreille River.

3-21

6/26/01

1045

CG

NE

Sample location PRTB05SD on Slate Creek.

3-22

6/26/01

1047

CG

NW

Sample PRTB05SD on Slate Creek.

3-23

6/26/01

1140

CG

SW

Sample location PRRS03SD.

3-24

6/26/01

1140

CG

NW

Sample PRRS03SD.

3-25

6/26/01

1335

CG

N

Sample POPP02SW and its location.

3-26

6/26/01

1340

CG

NE

Sample POPP02SD and its location.

4-1'

6/26/01

1350

CG

E

Sample location of POPP02 from Pend Oreille River.

4-2

6/26/01

1350

CG

E

Sample location of POPP02 from Pend Oreille River.

4-3

6/26/01

1400

CG

E

View of sample location POPP01 from Pend Oreille River.
Note pipe originating underground from Pend Oreille Mine.

4-4

6/26/01

1400

CG

E

View of sample location POPP01 from Pend Oreille River.
Note that no sediment was obtainable.

4-5

6/26/01

1405

CG

SE

View of waste rock pile at Pend Oreille Mine from Pend Oreille
River.

-------
0144





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type; 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No.

Date

Time

By

Direction

Description

4-6

6/26/01

1420

CG

S

View of sample POPPG3SW from shore.

4-7

6/26/01

1425

CG

S

View of sample POPPG3SD from shore.

4-8

6/26/01

1435

CG

SE

View of POPP03 sample location.

4-9

6/26/01

1530

CG

SE

View of waste rock pile at Pend Oreille Mine (from across Pend
Oreille River near Josephine Mine).

4-10

6/26/01

1545

CG

E

Another view of the discharge from Pend Oreille Mine.

4-11

6/27/01

1110

CG

W

View of Flume Creek at its farthest accessible upstream point

4-12

6/27/01

1115

CG

W

View of confluence of Flume Creek and Pend Oreille River.

4-13

6/27/01

1145

CG

SE

PRRS04SD sample location.

4-14

6/27/01

1146

CG

SE

Sample PRRS04SD.

4-15

6/27/01

1205

CG

SW

Sample POPP04SW from Pend Oreille River.

4-16

, 6/27/01

1210

CG

SW

View of co-located sample location POPP04.

4-17

6/27/01

1210

CG

SW

Sample POPP04SD.

4-10

6/27/01

1230

CG

N

POPP05SW sample location.

A »»}

-T~ i /

^ m/n i

i tin
IIJU



N

o	»_ nrvnrwf rm r

oojupic rr.

4-20

6/27/01

1235

CG

N

Sample POPP05SD.

4-21

, 6/27/01

1255

CG

SW

POBK01SW sample location.

4-22

6/27/01

1256

CG

E

Sample POBK01SW.

4-23

6/27/01

1300

CG

N

Sample POBK01SD.

4-24

6/27/01

1715

CG

NW

PRTB06SD sample location.

4-25

6/27/01

1715

CG

W

Sample PRTB06SD.

5-1

6/27/01

1800

CG

NW

PRTB07SD sample location at Beaver Creek.

5-2

6/27/01

1805

CG

NW

Sample PRTB07SD.

5-3

6/28/01

0935

CG

N

JOPP01SD sample location at Josephine Mine.

5-4

6/28/01

0935

CG

N

Sample JOPP01SD,

' 5-5

6/28/01

0950

CG

W

View of Flume Creek.

5-6

6/28/01

1233

CG

E

PRTB08SD sample location at Sullivan Creek.

5-7

6/28/01

1235

CG

E

Sample PRTBQ8SD.

5-8

6/28/01

1245

CG

E

View of PRTB08SD sample location from boat

5-9

6/28/01

1310

CG

W

PRTB09SD sample location on Linton Creek.

5-10

6/28/01

1312

CG

W

Sample PRTB09SD on Linton Creek.

5-11

6/28/01

1355

CG

SE

Sample PRBK0ISD.

-------
OJ 45





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No.

Date

Time

By

Direction

Description

5-12

6/28/01

1405

CG

SE

Sample PRBK02SD.

5^-13

6/28/01

1415

CG

SE

Sample PRBK03SD.

5-14

6/28/01

1420

CG

NW

View of hillside upstream from background sample locations
PRBK01SD through PRBK03SD.

5-15

6/28/01

1421

CG

SW

View of hillside upstream from background sample locations
PRBK01SD through PRBK03SD.

1 5-16

6/28/01

1440

CG

NW

View of hillside upstream from background sample locations
PRBK01SD through PRBK03SD.

No Roll 6

7-1

6/26/01

0919

RN

down

View of Pend Oreille Mine sample POSP01SD.

7-2

6/26/01

0938

RN

down

View of Pend Oreille Mine sample POSP02SD.

7-3

6/26/01

1020

RN

SE

View of Pend Oreille Mine sample location POSP01SS.

7-4

6/26/01

1025

RN

down

View of Pend Oreille Mine sample POWP01SS.

7-5

6/26/01

1035

RN

N

View of Pend Oreille Mine sample location POWP02SS.

7-6

6/26/01

1037

RN

down

View of Pend Oreille Mine sample POWP02SS.

7-7

6/26/01

1040

RN

. NE

View of Pend Oreille Mine drainage route into lower level of
waste rock pile.

7-8

6/26/01

1045

RN

E

View of Pend Oreille Mine drainage route in background.
Sample location POWP03SS.

7-9

6/26/01

1047

RN

down

View of Pend Oreille Mine sample POWP03SS.

7-10 •;

.6/26/01

1510

RN

S

View of Josephine Mine in background. Sample JOSP01SW.
Note fence.

7-11

6/26/01

1520

RN

NW

View of collapsed wooden stnicture at Josephine Mine.

8-1

6/26/01

1520

RN

NW

View of Josephine Mine shaft.

8-2

6/26/01

1525

RN

down

View of Josephine Mine sample JOPP01SD which was not sent
in for analysis as the sample was recollected by the boat team.

8-3

6/26/01

1535

TK

W

View of Josephine Mine. Sample JOPP01SD was collected to
the right of the wood piling and waste rock and was resampled
by the boat team.

8-4

6/26/01

1410

RN

E

View of possible adit at Yellowhead Mine.

8-5

6/26/01

1410

RN

E

View of Yellowhead Mine waste rock pile and collapsed
building.

8-6

6/27/01

1040

AJ

down

View of background sample BK02SS behind the Circle Motel.

8-7

6/27/01

1045

AJ

SW

View of background sample location BK02SS. Note blue roof
of the Circle Motel.

-------
0146





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No.

Date

Time

By

Direction

Description

8-8

6/27/01

1150

TK

NE

View of closed Forest Service road to King Tut Mine, Red Top
Mine, and Lead Hill Mine.

8-9

6/27/01

1151

TK

NE

View of closed Forest Service Road 3155 (Slate Creek Road).

8-10

6/27/01

1327

TK

E

View of Lucky Strike Mine adit.

8-11

6/27/01

1330

TK

E

View of Lucky Strike Mine shaft.

8-12

6/27/01

1330

TK

down

Downward view of Lucky Strike Mine shaft.

8-13

6/27/01

1545

TK

NW

View of Z Canyon Mine. Note end of road and the Boundary
Dam.

8-14

6/27/01

1645

TK

NW

View of collapsed house at Lead Queen Mine.

8-15

6/28/01

0910

TK

NW

View of Lead Hill Mine adit No. 1.

8-16

6/28/01

0915

TK

NW

View of Lead Hill Mine adit No. 2. '

8-17

6/28/01

0916

TK

NW

View of Lead Hill Mine adit No. 3.

8-18

6/28/01

0918

TK

SW

View of Lead Hill Mine shaft.

8-19

6/28/01

1000

TK

NW

View of King Tut Mine on Forest Service Road 203.

8-20

6/28/01

1030

DW

SW

View of Red Top Mine on trail.

8-21

6/28/01

1225

TK

NE

View of Hoage Mine waste rock pile.

8-22

6/28/01

1230

TK

down

View of Hoage Mine shaft

8-23

6/28/01

1257

TK

NE

View of Lead King Mine adit No. 1.

8-24

6/28/01

1300

TK

NE

View of Lead King Mine adit No. 2.

8-25

6/28/01

1302

TK

NE

View of Lead King Mine waste rock pile No. 2.

9-1

6/28/01

1305

DW

E

View of Lead King Mine waste rock pile No. 1.

9-2

6/28/01

1457

TK

S

View of Flume Creek (tributary to Pend Orielle River) sample
location PRTB10SD.

9-3

6/28/01

1500

TK

down

View of Flume Creek (tributary to Pend Orielle River) sample
PRTB10SD.

9-4

6/28/01

1530

TK

N

View of Washington Mine at the bottom of Washington Hill.

10-1

6/25/01

0935

LD

SE

View of sample location POSP01SD on tailings pile No. 1 at
Pend Oreille Mine.

10-2

6/25/01

0938

LD

down

Close-up view of sample POSP01SD at Pend Oreille Mine.

10-3

6/25/01

0950

LD

S

View of sample location POTP01SS on tailings pile No. 1 at
Pend Oreille Mine.

10-4

6/25/01

0955

LD

down

Close-up view of sample POTP01SS on tailings pile No. 1 at
Pend Oreille Mine.

10-5

6/25/01

1007

LD

S

View of sample location POSP02SD at tailings pile No. 1 at
Pend Oreille Mine.

-------
0147





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No,

Dale

Time

By

Direction

Description

10-6

6/25/01

1015

LD

down

Close-up view of sample POSP02SD at tailings pile No. 1 at
Pend Oreille Mine.

10-7

6/25/01

1025

LD

E

View of sample location POTP02SS at tailings pile No. 1 at
Pend Oreille Mine.

10-8

6/25/01

1027

LD

B

Close-up view of sample POTP02SS at tailings pile No, 1 at
Pend Oreille Mine.

10-9

6/25/01

1045

LD

S

View of sample location POTP03SS at tailings pile No. 1 at
Pend Oreille Mine.

10-10

6/25/01

1047

LD

S

Close-up view of sample POTP03SS at tailings pile No, 1 at
Pend Oreille Mine.

10-11

6/25/01

1125

LD

N

View of sample location POTP04SS at tailings pile No. 3 at
Pend Oreille Mine.

10-12

6/25/01

1126

LD

N

Close-up view of sample POTP04SS at tailings pile No. 3 at
Pend Oreille Mine.

10-13

6/25/01

1145

LD

sw

View of sample POTP05SS at sample location PTP05SS at
tailings pile No. 3 at Pend Oreille Mine.

10-14

6/25/01

1146

LD

sw

Close-up view of sample POTF05SS at tailings pile No. 3.

11-1

6/25/01

1200

LD

w

View of sample location POTP06SS at tailings pile No. 3 at
Pend Oreille Mine.

11-2

6/25/01

1201

LD

w

Close-up view of sample POTP06SS at tailings pile No. 3 at
Pend Oreille Mine.

11-3

6/25/01

1405

MW

down

View of sample POTP07SS at Pend Oreille Mine.

11-4 ''

6/25/01

1406

MW

w

Sample location POTP07SS at Pend Oreille Mine.

11-5

6/25/01

1412

MW

down

Close-up view of sample PQTP08SS at Pend Oreille Mine.

11-6

6/25/01

1413

MW

W

Sample location POTP08SS at Pend Oreille Mine.

11-7

6/25/01

1422

MW

down

Close-up view of sample POTP09SS at Pend Oreille Mine.

11-8

6/25/01

1423

MW

E

Sample location POTP09SS at Pend Oreille Mine.

11-9

6/25/01

1555

MW

down

View of sample POBG01SD at Pend Oreille Mine.

11-10

6/25/01

1600

AJ

N

View of sample POCR01SW and creek at Pend Oreille Mine.

11-11

6/25/01

1628

MW

W

View of POCR01SD sampling at Pend Oreille Mine.

11-12

6/25/01

1638

DG

W

View of sample POCR01SD at Pend Oreille Mine.

11-13

6/26/01

0920

MW

down

View of Metaline Mine lower shaft.

11-14

. 6/26/01

0920

MW

W

View of Metaline Mine lower waste rock pile.

11-15

6/26/01

0920

MW

down

View of Metaline Mine upper shaft.

11-16

6/26/01

0940

AJ

W

View of Sterling Mine upper shaft.

11-17

6/26/01

0940

AJ

W

View of Sterling Mine lower area.

-------
0148





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo
No.

Date

Time

By

Direction

Description

11-18

6/26/01

1030

MW

W

View of West Contact Mine area.

11-19

6/26/01

1030

MW

down

View of West Contact Mine shaft.

11-20

6/26/01

1103

MW

W

View of Diamond R Mine shaft

11-21

6/26/01

1106

MW

W

View of Diamond R Mine waste rock pile.

11-22

6/26/01

1130

MW

W

View of Diamond R Mine shaft No. 2.

11-23

6/26/01

1130

MW

W

View of Diamond R Mine shaft No. 2.

11-24

6/26/01

1130

MW

W

View of Diamond R Mine waste rock pile.

12-1

6/26/01

1200

MW

W

View of Blue Bucket Mine shaft area.

12-2

6/26/01

1200

MW

N

View of Blue Bucket Mine shaft area.

12-3

6/26/01

1200

MW

W

View of Blue Bucket Mine creek and shaft area.

12-4

6/26/01

1300

MW

down

View of Blue Bucket Mine sample BBPP01SD.

12-5

6/26/01

.1305

MW

down

View of Blue Bucket Mine sample BBPP02SD.

12-6

6/26/01

1315

MW

W

View of sample location BBPP02SD at Blue Bucket Mine.

12-7

6/26/01

1330

MW

S

View of Bella May Mine lower shaft.

12-8

6/26/01

1340

MW

S

View of Bella May Mine upper shaft.

12-9

6/26/01

1340

MW

S

View of third Bella May Mine shaft.

12-10

, 6/26/01

1344

MW

N

View of waste rock pile at Bella May Mine.

12-11

6/26/01

1400

MW

down

View of Lehigh Mine 1 shaft 1 (vertical).

12-12

6/26/01

1400

MW

E

View of Lehigh Mine 1 shaft 2 (horizontal).

12-13

6/26/01

1400

MW

down

View of Lehigh Mine 1 shaft 3 (vertical).

12-14

6/26/01

1410

MW

N

View of Lehigh Mine 1 waste rock area with owner in picture.

12-15

6/26/01

1415

MW

N

View of Lehigh Mine 1 waste rock area. Note lack of rock in
the middle of the pile.

12-16

6/26/01

1540

MW

NW

View of Oriole Mine former shaft.

12-17

6/26/01

1540

MW

NW

View of Oriole Mine waste rock pile and shaft.

12-18

6/26/01

1540

MW

N

View of Oriole Mine lower waste rock pile.

12-19

6/26/01

1550

MW

NW

View of Oriole Mine area.

12-20

6/26/01

1555

MW

NW

View of Oriole Mine timber structure at lower level.

12-21

6/26/01

1555

MW

N

View of Oriole Mine waste rock pile.

12-22

6/27/01

1230

RN

NW

View of Oriole Mine shaft. Note gate across shaft entrance.

12-23

6/27/01

1230

RN

NW

View of Oriole Mine shaft with fallen rock above pipe.

12-24

6/27/01

1235

RN

N

View of Oriole Mine sample location ORSP01SW.

-------
0149





PHOTOGRAPH IDENTIFICATION SHEET

Camera Serial No. 6279466
Lens Type: 35-70 mm zoom



TDD No. 01-08-0009
Pend Oreille River ESI

Photo

No.

Date

Time

By

Direction

Description

13-1

6/27/01

1240

RN

N

View of Oriole Mine sample location ORSPOISD.

13-2

6/27/01

1242

RN

W

View of Oriole Mine adit (at right), small waste rock pile and
wood on upper level, and overflowing debris (at left).

13-3

. 6/27/01

1310

RN

NW

View of Lehigh Mine 2 adit.

13-4

6/27/01

1310

RN

NW

Close-up view of Lehigh Mine 2 adit. Note gate.

13-5

6/27/01

1312

RN

NW

View of waste rock pile at Lehigh Mine 2.

13-6

6/27/01

1330

RN

E

Collection of sample BK03SS.

13-7

6/27/01

1332

RN

down

Close-up view of sample BK03SS.

13-8

6/27/01

1405

RN

NW

View of Oriole Mine sample location ORSPQ2SD. Note
drainage route in background.

13-9

6/27/01

1405

RN

down

Close-up view of sample ORSP02SD at Oriole Mine.

13-10

6/27/01

1410

RN

NW

View of collapsed wooden structure covered with dirt at Oriole
Mine.

He,:

AJ	= Alan Johnson.

CG	= Charles Gregory.

DG	= Dave Godlewski,

DW	= Daniel Weiss.

E	= East.

ESI	= Expanded site inspection.

LD	= Leatta Dahlhoff.

MT	= Monica Tonel.

MW	= Mark Woodke.

N	m Siorth.

NE	= Northeast

No.	= Number.

NW	= Northwest.

PA	= Preliminary asessmem.

RN	= Renee Nordeen.

S	= South.

SE	= Southeast.

SW	= Southwest

TK	= Taxa Karamas.

W	= West.

-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
I

' vv.jl

{jff'zf	"V*.

C- .37 CSS,

Diafew/r
PoPPoVi, u)

GW at

¦ • ;.A'.SV-',;v



5/"" .

A |fl



BH t-ar-^N Kg



di atw/v

llS^ip. ¦

fi&$crt££> ,



|(M5 °''9 ^JEjj

jKt%'"''1^1' Q 1 flMf'

ntpRI



' 'iok'

1 4-Z4



L^

-------
-------
' ¦	* Sh* -=s J*-*

1.

l5r/

w

V

$r

-------


*>-

>MZ

¦- a -v
HWBmwHH|



G>"-2

is v L. i'Vr ^

e^Ssr

^ „ g^qO. \

po^e-c^1
I?

0^

w^'„'Sj£53T- 7Ii';'." ;r.- -.*: r

t-«?	& ';•¦ IP

SflKNg >r;"!-'i -'tr ¦" '; 1 y.

v. . ...:^;.,„v ,.
-••'s=i«rw.Jwssw®'. '• • •

-------
-------
fW^/t /?

r e°«+

Oix$it u

Pf< TBspgKrg

RN

\o-r



SMl^—Ld W1 V^r?1

0)1C ^ H 2-
PRTG4"]

-u ..

-. ..?•. -V"' ; ?
• '

-V • '«« "I 5 «®

sSHHHSSPSndi

-------
utrgjpSJ"

OYxm'-)

0V 13-5-b



t







5-1L

-------
-------
-------
-------
-------
lUpf^CoWj*^

1 Ol-01-00^s

:

- '

-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
-------
'*"< dr^r ''-

' 'K

\ i ¦ t"?

-------
-------
-------
-------
-------
-------
-------
-------
0206

10:START-2\01080009\S714

-------


0207

il'i u£ v.* ,T.





ecology and
environment, inc.

International Specialists in the Environment

., v'...
- • ,

S:r . • * .

v

!: ,

- • ¦



Job Number . ffor

'-•V-* ••

.'%&:¦¦
?.¦ 'ft-

rp

lipp/ M umfaA Kkxw/foiALh	

SWb And JpJAd rvdlii. fAufeK&
I			

•'¦gtelUv, ,

:v~£ -

h x

-------
Site Name U p'pOV Cfi\li /yJo\o, Vjtvtv' SOliALb	

ftf/vi DHt/I 1j

City/State

,

Jy.	iy-i?

' * 2
***

TDD 01' 05- 0C£3

pan --rioiagl. ntm oiae.

SS1D		

, *-

* ^ -J* £ i

, : -vv.:^

i

<*i %

Start/Finish Date

Book

3

of

E & E Emergency Response Center: (716) 684-8940
E & E Corporate Center: (716) 684-8060
MEDTOX Hotline: (501) 370-8263
E & E Safety Director (Home): (716) 655-1260



aMSW^raiwwHaiiwaii!	s

-------
0209

v>V-

201- OZ^OO 2%

fo-/M Oft® Zbu c~Qs/A	aL^^zA-

0>j>r-4L ^fCrtO Ixvn AZ

/O^T Mis*

^]"tt» jJ^T" ,-p -v

¦ -	w"

L?vjo.

3



¦nc

JOS*

iSsac*.



C« ijMa

w



			W*?. r '"**	-/^ J*	f/*/		—	 -^-.^'-:v: '*£Xjfr':£-,- k

//¥$T AsrtU? /g/ AOri&MJ' //y? 6* J3h^^ , ~~lC< & '«-

Jl

£5	A-y <^<9*

Is/ult/S	/rLu,^(-UM

jr^hj

£-$"/lW2j.

>*J '$*

cj	/&7?/y} <-?£,<£ ts Ai&

-M



(jtCAmL.

UcJk tec**- j>£<'> ¦ 37 y»-s	O^/J?ltl\

'3

aasat



y\A d ^ fcxur

ye. tS-

fort.	/*V

,h-nr£i0>.*&'%, \



jJL

•PiJ?	,^>, ¦	\Jy>»-v.

6"^> "yp- - V fa \	y?jp7B-& fa -rf~ *&

17 1 "' ** /mJ*K d£ -7*C /fc>//

^ _	£m ... . 1	Z"5 i2«-	_ '// /*\ >•-» yr^. J.	/ C i/^Z/

f^d&—/kfr-./tSj^ I	C>yt%?SCAS—4T • ~^ e-P S^lpS.



-------
0210

k-j-flfiirittkitrtl.-ifiltTri n -i

D(- £>Z-6DZ%	GL^ bo

«sui^	tproL^Hy

lejl ef,

ef y^/X< **y jrcx^l

ML

$ ffltkjh ,f )y

[Q/\lfr>\

12Jio Lu^ /hj tfair:

Njo	- /{//? ^,0



^>-fl

K

	/A** utrcJ^

MZ/s/pg^

fy	ft

/S~D /as Le/jl^ X

V^V'5-^/' ~~

ldX
-------
Wls/ffJ

. C&7Z-Ot^R

C&~h<^(Zs*c. jCotA^X 0211

k)o Q1S cLr^isCixT isSZ^.	-flrz*y^ r —v. . ,^> ,-j^,.t*,.m*	w —	sj-

Dnc^xbG&rrt Sg ,/^> /frsr Zzw?£r.	ljiz-

f^l./f Jx (olGc-f^i T>



—7—*p-	y /r ^	w*	¦ 		—-i 1.-;—	. _ ,. _.	V.. . \^— ¦¦¦¦"¦¦ '.	tr t n	ii 			.

/#&> Jkj /M r^w^i -JNc* VyoVeSl	i^*g~



2c

<

OJgPUVgiO og:



Vss^o«: -No c<^5«=Jertg^

So/brAn W" /?U/rdS£	Y)s>± Pfe

yykt-. e>\s €> j	gg2>j



J*u_

^ ****£¦•& Cooses

%*£ ^ ^ ccA.

AJC*v*£ ^ &£>~1^> /?&&

vJScAAl^g

IaJ 'J&- ^§Ax*. "TfHire. /% /*£. y g>uv^s

"Pfln

-------


wmmMmm

ysw

it#*









5-

Bsk

^sgp-jC t „
£, ,

§3§§gH

Su<' '

Bgfeffe -u J 4

«. "*§

f— ' «-> *

PiisK. **& ^



Sfes ^

-s*i

P • ^

££*^'f3s?

r^cferS*-
*

JillifiSll



-------
0213







082n ZiUJ A)A (&^sr -/S^ O^'

d ?Qc> £k
-------




- i

''J



-------
0215









:'-s :- -

Hf

A



]¦ ij;

6-r?-*/

ItypgA •

r^rawgoas?

£>//%?>?- Ad S* jg^yg- /.S ftya,,

¦ /fog



Zfi



7* * <13erc.

&*-

fa? oZ-rf^

Y^r.

*£2£

.£2.



Z=£i

zZ



TV/

~&/VTC-

!1

(^»4r 1 Ka)sJ '(*> C-Q A ZCi

^ VA/v^r (1>UX- 
-------
0216



'6o2t

ikpffty CM

^Sftvty4r vj~g^ 	 	 	

a/ hjittf CC\\- CjU <^L. &qc x-Z<

£*/Ua

co'th	/&as

C^>i>

c 1 /

/L< fAhrWoc	,7^a-



W.

is

; • ?

rf>

• *~t

-------
0217

i' ,'if.-vj;;'-i;«ir's£*li;



—^-'' —^

: '¦I--'"*'

10

Qr&-0\

if felll/hW^ forf<^.

Q 1*

AJo/-

^ r—' /(Jtrs-/^!,

j*r^-

ic^r

1f*st

/G^D /kstcx	/&>zMC /flttJe

^0

/O rsztfs	- c?y,0OO Cxj y/S^

<^<=L j£&S,t«£L /??///,[c$TC./zfw%Z~ ¦

*JSL

Ci/S# fffA

cJfS- rz*&.	/s

kr gsa^ /lk-sfie^ +h

c5o rfhx>A~ fi3n J



v	7H^ /¦? s^rvr&tcj?=:0

rs

Gccxjs^ c,-/~  ^ /^yi;

,	^ ,fy ; ;

%~er^!^\ 1&C	^Se*ylf^-

& f*/bs/cn V/^///	jZr* / <>

&srrfc spi/p	\^^c/A>

	 	

C£ oS SJ&As 76iSA
-------
0218

..oi- rg-ooag_

tijfpir Cjolurtdbia., YlJsrty	^

11

fe

y - c

:
:

-X &

-------
02 J 9







ii 6*r jZ,A

, -¦ vr.	. •--..

. , - ••<•
/ '

¦'.»t n r~ • ., t „ A*. ¥<
-J ' - - > V -'* V

yv ¦?;*&¦¦ i'/A-'.'.svS.i"



/£*«. tf-az-cezg-	-^V

/fig!

^-•-4pV.

'/X/-



Ai



a

ls3o

fWf>,

1 <** A » ¦S-ts^X> cXWf._

6s3.?g.



.^VaJN/rK-a^- "]g.U*W>			I p> 				

" 3a CsWJp^S	 • S^-oi^v QiVXVJ^*^-*Q&-  -g1

	Q/Ni-J

\y /SMe ;



1 e& j£-

' V SKA^lf"

¦-¦'4^- ..= -.¦ ...• .,



	*	

—^—



-------
jjfeUp^W Cdliry&xc^	D&- ~ZjQ-£>y

'^P feo ASs-,LAe- d	C[/^iA iSZ? r\n !^c ji Lit e.t ~J

Juu.

if



&-

gytSO A~,,^ CL <-—^ M.„.



(v\>.iy





'cro

g-	»j ff- (fiPPAkosSi .Pa	/£**- 4 /Qrmo^rt	rtv//

W:-
m

_ _	Js»&t£i\ *	ft/Sror^UEQ	£s/*-ryi

<^g i ^ assume? /£Z- trs&eJtZ /Zr/^s^- SJA



„ _ 0Sp^|p£&  -CL>rv 	

¦	~ <-*vi ^ z? :

# #ii/;

0?^	^ ^J^rv ^r¥*-.6?£> *£	*J) #4

J7^ /V/^/xX	

h& jK /v '/// /Jo wcQwg



'f-jS TU^/r^t «3" i/tZ (fM YS ^^/Xf^cArO. f^/Le^ 6JT	c/

~f£c "Zz/r 6*. £>te) ^ 6~>ft ^	/<~» 'A* & Air /OAs* 	

Mc,/)f y^> n. O^y /ryc,/^y^

lA^L jT^tL / «=^/ rZjCcJbu&Z^ ^	^ &- O^T

7^3 <^- /^. /jD,„~hz> L.. fi \r Sg/Gf !t& W



LCfipnM'S^ /s>

jyie&L, tJ/s ^ (^< y^V-

Z.c TT^o^s" /^ ^

/2eo SArt' /nfc,<^

A	-kctz) IM A^P>

/s *W	firj. ,>^3

l7	6JR

^ ' (^F<; ^ /3oi4^U-yV

Ja^s	^

^ 7—C ^<3/1 '

,/^Wi	/^y^T

^ oCr- /oca ftyj-

7^

M~ fb/.

/5^0 ' GaW U^cU ^ ^ lcc>^-^n/
/7fl°



¦j""

-------
0221



mf: ' ¦
;' '

rr^f'-i"1 l- -»'• *'t Vv*. ¦ '^•¦i f v	fl~VTfVrr'''tf*rf ¦	Tiyj^'i'Tij'"*''''^"'" ''"Mints r'irr l n hir'V- iri  (^/-6/-
-------
0222



sha.

fs GLd*^ %!>&&.. 'r)\-rt7~ooig DG--z\-o\

15





U? «=^Ov-H s^-hk SOV-J4

o/f ^cltMS^g.'-.. yrf-y' //f&jJ?, rj^JZ. ^

/3aJe. c*s : ( a/UosJ ' t>Jtw .-*£? <^/2fT"l"N>

»xt,'-i_C!)^QGa--:''^a..-:'Q.-Q^-

^ ^fA"	Q	.^£..\.:C:...^=:i;L-.... .

J

,oC«C. Q

fffoc	bpi&i^. -r



]0®d(&$ Ajo ^^(r tQfo-ov
#0yjj.

/s lV ^ rk J? c~ r Sc^p^

P m '.

iii—i

'Qa-J



J^sa

Mo ffig f Ae& ki'S-fc* S*.

Of*.

%K " A-gOass	rWvS

;

y i§	^SccjoA&-., .&'/&.Mm . "T^- (j$42S''/y?c; ' 'f ^ Cfhs&t/a *Otk.	c^t/Z „

LvlUc5>x_jA^	+__j&7(L cMJL		S~yst

<5?	hdjzS <=jS^gg;f e^kjb. -o	• ' -

•u-i

y~>,i\

-1 -

M f * t ^V:



j?8£t

V";

Lh"#^ . ¦' - 1 ^

~i--2 - i- -» -j .* - -







n£arx*r

M

-------
0223



ISf

CXcr^ZK -O^

Uf$y CoLwbtQ^ $*->&£ o/~ 6D2~S

^ -P^(^->Q<:. C	tfr&Pi AJS k&$ CCC, Vf ^cro^W^ Ny^

y	H4Q*r£) k io<^ '' "/A

/«-„<•> ^	^ 	^ ~) l/L .

U1A&^

-------
.,. «:>/?





-------
-------
0225

m



GLm(<»^. ulA. Co-lJ-O i

-£=V-

19



_S2d

*C~ &¦
CiO>

EE

it.

T

>» ajc, I a^<, ^ v JW<^	^ \ -Kv Av {Vv->g ^UPl-.

&fe;C^ -/l-fe	c^r-

• <4*T fl^S <5 &N	fe*c> f^SSfVZ-JzC/rxr'

7A* (nrrp^LO /W /a- ^





x.



^ c.r-r&yj^, s--^ ^7?*335 sihe#z£y

' ,* *' J ^2-' *¦ l'-* ~'.r*"v~'..-. •'

r^^.NjWgjL m\| -

-lu*





/?

I 
-------
.S'v"

0227

U



imk

- 20	*

	Qfps (oCmIx* nuitez: .	Ot^OZ'OQSlg

{Q &> 4rr~c<^r g/	/V r& /ur£r^

:/fl(AFZ, ¦	rt>sJ5£ ( Q>TS "CP#,

	^"."

{} ^auu£ iacic./	/#Ua<

-L.	

		1	—

	2li__

,r^;ii:--.'

•¦¦ >, ' '.¦*:... / . ..r-J
'--	- ^ - 1	:	:	:	:	:

:..f-.'!-i.r..yi;.-.A!?>.



snAi^r :

v,

¥





jial

'¦; -V>.^'-'a:-'-1-'r''-v"-^



"i

^iE.

&-Z2^l

-------
0228



2

(cLi/Ubtcfc	Crzz^a\ OL-og^g^

jr5T	<^h £c**fr**.	/vi'iAjsr , 'TjX ..'±0 ,



.£zk$/h

i

£s_





ffiD -Ctuuf.

y- ^Vcs:. r*y

rL Afruf



rflOAA/

Isr

Z'£i-"\

C,,—Cg.sfi^r?.,—,, L«^S^ ;t* jsSff.	,/	y(Ni-

f-

~f~ibttlf.L



^jac^—£f*.



^OvS —

?

jpQf/Y)iii;;.

AJa si4Zs>fii9	o/^ (ykeUQ hr Q/^. q^lld^^

(Aj C%/<^ /ffl 	*'?.	¦ /% //- ^	¦ jf3ts*A-'£y m

,:K Q?y3r^S

'A#?

^a/ gijiavJO? /y^i
¦Sac/

$ /fcL

'^rggaOf

® ¦: •
-

c^i:,-/"^y^-.'v.;:

%-'5->-i ."i.'

^^:.?-'-.x.;:v

;-;•>/: y,r-,-; ¦.-..
'*-jv' .-

;/p, '



' '".i • ^ '

,;: ?.S

:#

¦;.i^

-;:H

"... ¦;"»

:- --s-i'l



-------
0229 \

-------
0230



23

Ah*wiyys^s,	„	fl(- lp ^ >fS^75vJ*t f>i\w3S 0»V-C>ea

		-...V*^-F^	~ ^K&TD^			

u>y	?^ ^s-itirv^Q-^ V>TL ^^6?gu>>

//-QgJ- -->i - .-f	7^^	jjj <*.€&- iA-i/}f<-rjy=S-ccsn^J

¦ ' ^	"	Ol'





~/U.¦« ¦*r f

*3*jfe ,4^Qf>^j-^4-^r... fiWr;.:. eA> H' ^

fajLPtZ /V&t fa cct-fers	s*/a e

cfo

&^TzxJvyL&r<>	: ^ yfj£«*y'/y-	*z &rr\ct,//

gt/-~

—..~vr, ' ^ 		¦—•— 	£	,	 ^ u^rcr	«^-	.gy			

/Mec'^K/ Jl)-b a kvM> //v^ ^/vrtr /f)fJ&YT$\



ife-/7k& -fZvjwA/ Jr. i&&A

0'-	^ .

XT

•#> Z&rtj/JL









. ¦ •: ... ., . . •• ^->.' -:
:; •. .'•. },v,.;.-5»_.



* &ec4«( p6f^4
**? *>&&

*rkcu^ff?£xZ

a—		- -«-	nff^^	*illll^

MjJL

c> 	£.

'/ ^Mj

ts^y^X <~Srhh^>C hstSZ^ 	

Qrjj

Mh j^p#- 0rj ,

pi n /mo/ /oc

¦6~/j(L

- U^n -h-^J- ~ /7)%*cfco s/A

>/?•>

MjPIWIgpilWpyilg^^

v::C-:--:5;#f

¦>.. >- : ¦ •••^u1:;-

:".;.1X--V:.?'i '

¦ ¦'.:. _ ¦¦¦¦'.

:....' - --'^
- - : \ ;	" . ' MS

¦ >i; ¦¦¦••• .¦¦¦¦¦ -fW
'¦ ¦' •.' - •".¦• ''.•¦•'• • -'.

¦m

¦,;/->:'• x^'-^::-:.M-

'SM-iW3m:9

S4|--

l§

ns>^:s..v}.,a.w- . . /:.v-.:;,\tiisf

'-.".:'v '>/?«

. ^	V ' - * 3 ' .	- -	- * .

y ': s

y't:-\'
iV-

¦~ •.

-------
0231

1 ftr, i

„ il-K I \

M

¦Th



24





Cn-ca^zs?	(q-%Z^

•\T^ rj~ y ,yv	^ ^ ^	1—- q	—;		

Ote>l#ng

(pdL. /a ^2ggsa<,

¦p^ 	-	 ,_...

Savf/A fsJlM dlftcw&f-)

Vvi&C x/?p~

'cs.ult Ce&cd tS /JXL

<^ag^ <*&y

—	.	w	*

(&b /Iks (j&. ij)(Caek i	/>/*/&	°^

£aj$/ -fczZ/L k*io	. dve

0	/o-^ '^y/y—-yr ^— tf' "%¦—'nr -- - - 'WW j—^-

1	1//fe4 - ^ VV''

~\f+ i	s~ V3 of TYVji^; 7>/^

arc**- eTn^i*	. .,

o2m-





<£«-*fe» yo^rtJUs



\JSC ^f^-C>QSS> ^	-Ww U^TZ,

r3/y*.noi/0 <\a. A\ b^Ac^'

rtn^jyJiJCD 1VJL. i\av\\ Q(,AC^^.	QfP .• >gva&w.

Q^Cfce^ t,W-\r<^ -<¦¦»->;=$?	1/10$ |g^s/ 6,r3) ^,ft



	l/l<~^ l^^s/ J^Jl U. /X, / 		,	

^  b^cra oa-> *&*=' rr^h

^-*0* i ^u/<&j£r7 (yitt

rtf ~~j&- tW//f (j/fisefr'

fZ&Jlhz ¦

m*L

^s>6*d£~	<^>^V





'*-£>frSS /5 ^7/ty

imaAt

Jj.



c ^ -- "

-------


UirwIkic^^HiuaZ- Ot-axrssTW <^-Z3-^i

25



rv . nn3 4^ ~j . t 0Os^

Q/Pyp'/ijL ^foj<^-^- A	A

~)C» I

i>ejtA^

o*jg_/1

515	^g^ 	\tia*^ltr

29 i/-	^-l'

«%-" -. • 	,	....

\f^L^j£~ \ Z^ S> S	/^tK Ug

¦^nr* I ^ ^7~g —.

7/#X	/^S" y«*-^ <> /jgfe*	«-&<,_

l//Vr> 1%^-Tx . &u^7^. /^^k/ ZJur^i ^/yCs
'^Jo^. \^J	 ' . . . ¦.	. 	

r ^	1 VWcL^g

-------


sjMM

0233

ft i



. . 		

26

.r



¦VSjC/

Oe~C^Z-c^cr^J	V }	-V	>—		 >

/¦A.c-Ui'- c/' disr.rJ?a^J /yL>o	^	

.{b/^ ^V 7tyt/CJL- . ~fz^i. If r-ju^z	/xfevgl Gd-eLch^Z^

/Wi xVX-

Icuc4/C ,

<£& to*<%

I

-------
ecology and
environment, inc.

International Specialists in the Environment

'Vi': _

/ '

Job Number n|;

Mm/ falu/Hkft favWrvuiii*

v. >i~



•• "... . t
... *¦ r.......

¦M



>tf/\s nAd PP/vl Om'JIt Qminto
U^HiftgtOX	

>u/> frfUL



¦v^SKiSfj



-------
E & E Job Number

Telephone Code Number

Site Name U|?p/ CtAlHUkff fe//m,lTULS

54f*rm\ aA/i lor\A Hm'UiL Aoii/lto

City/State Ji

TDD 01' P9-0CQR

PAN nrnasi ocra ^

ssid	

Start /Finish Date

Book	 of

E & E Emergency Response Center: (716) 684-8940
E & E Corporate Center: (716) 684-8060
MEDTOX Hotline: (501) 370-8263
E & E Safety Director (Home): (716) 655-1260

-------


-------


'	: . :-:"v

f#?.;



023?









, rwhf< ykafn 5



*r :

c "* '

s>

,JW-

:->y-

;: "&

Slit



~j,'

-7

.tr





' ?
V -

mrntmtB

.<« - v * - • ¦ •

fg£

;.;S •'

msmmm

f;, * '
-"^'4 »





-------




-5-*; ' ' ', ^

-*sri -, %	p-

X^f"¥

-------
0 VP 2	\ 'jj'Jp / ('d i uMch fx V Ar^X

^-UA9rfhwi^\ ^^Iffcjfmegjk

.	^ru?s i&jWaE y^gj^fe^ifes.

UffrvMa tG.	f;



W*  •
f i-'i

r-
•£v

j. ¦-

-¦•¦A-ft

-:m.

-CV

!•



.. i

' .?,
,>5

» V

-------
-------


-S J

:
t



-------
0242









y-A?

£ahk>M4uJiiHL



-------


-------
0244

ir':

::v. ,'

.•r." :'S.'- .





* Ti~ v"Z"Z„% -f . •' '' «. . -'	__ -

-------
11

oas
"T(el ,s<

-ram

_3kJk.

I /$

;^Sl£5 fefbl
iiT -KgJ^P ~pfti

ma

_di





f\>Av

4%
,g ftafiOfefc-

''6j&)vJ:.£\ \djfrn Jtottf Kd

1ftfllfr,		_

-He 'rp\rhfc[ .area gn-^njfer j"A
m /H&r k jbfelfA fk?nre4,

tr^3'

iMto

o V55^)^. [S ji]&l jrrtfi -/6 ^/rui'te./^r
s 4s awffo VttOyby. 7Ti ^ArreKfe/lrfor%<
Wu 6	asjftafe uM Vifyfef W

!s_si



"±w

^^A(T



^~K«nQ
-------
024 S

-------
0247





M Jfeoi*,	ailer

(g hdej ^rf-.	

V ~Cc i^)fSach k:_

"Z ¦•¦ -fx C

^ 'f-y
*"*''?!

•hSj.

'tiSi
- C4



'i <.;s>

wwsm

: ¦<<¦ ¦;* -





-------
-------
*	-si

*	*

W1

A

{ CK

' A

-------
w

V T.

%V: ^: A'Cf	. , . -. ,

--^o- £.^;?• ... - ¦
-J«3a£*J. * * Jl/	," - -¦

HMra9H8

-------
0251

-------
/

0252

-------
-------
-/

0254

-------


-------
-------


0257

. •	V*5. I

23 -1

Noydeen CZN)	hotri -to cx^de Hinv I

II	t ^tl, Vf V i*%-^ >» m v^i ~~f ^ -*	A^ i^ r i ¦ * -1 f *-¦* H.f « —• — * - * f "mr—

Obrfi^ Od~ Od mirtfs \cra-hnn cnr^fe cf 1 ori/t"

mns_

pn ifris.

" , :' £MkdceLS

p-H /Trf g^LmpU : lf»lflirfrt fS

¦MA. The Spn rrj

iaff6.,ir/?l icC^fj^pprf^

^ t>y, Alnraffi

i Oigyc j-K^, %^>%0&n?a6 dO.gt^fc not MUf "to	^ ^ Mji

ffodvcuym

tCirn fioiix? G-pprrrmto^ueU^^6f^ be^rr^ corona irrir;>^ ^uffo

ffLm -Hn/i> e^fiinry-iVyj o+>^QpnT

iwg^/nr^, ^)U . OPSPOKSP) Anllrr^p@ta^.Q h^| nA m -f-Jno ffxxysQ

p^hCDl aSjJri^^M Sar^le^--/[0nt'0yau 1Q llQfrf-
pri to	, rc&-/PC&p

tomu^n

OP Kl^j^JCO^-^nT^ba/£gvmijid ery4	^pyrt-i-yr

fd&W/Xbf&_ r£ _ °fhi rmjyt, i5>	^;bP- /PlotQ^ hin Q ~Thu

tic. (vr^ripn^%i^mYthi^	hfffcl • Thgyyviffi rflnSEfo ^Of ?t

if i) acU-^ 4JaQ^ h pp KPwjtYI

Ml

•the,

•ftfiyiflj

J2_



lOiSfe vcmpili. ^,|nffltepl-^i9 frovn-tm cid/t.

-------


11 ppff c n^u rn^1

M-OZ-C&Tl

,If \^£> gKt^KJAarn^.^ boO^yOu/vA iDtation ¦ WhtfJo iST^O

111 dvS\x<^rJra \j%^ mn a (SP<;	tM4^F>l'%4 A4

loncy \\1°M Hp.11 A\±RT&Gin .garnplf: R>k^O.^SS rn\\rck-pl

igd:-

AnQly^V^TAl rhfiMlP> /^nUj

|4O0 gjjof yfe nrKivr n-f- tPU3C4^	trOCJCSirte, htte SfuiX/rt

Hnnfr.r^i -Hta	mrj^pi lc; I -Wj mf/# Aarvy/s ^>iU

¦-k

|y>frv.,f4^p 'i^s^v.^j/-.-|ojrr^ ~tu* trv.yy |^t/rJ r^:-Hnf nWf°J;f MiW. fr^c^ste - - \
^fn.npi <-> nrtltapeycf t*TYrt^^	QPS /^iVrkvv ¦

'•""	V / • •' -•	¦%.:'. •- -	•"'«'••	.i~. .. "* . -V ".	• ..Jt\. .... rt

iar' -'¦'^¦¦•^•'r-'-Ji

-------
-------
0260



-------
0261

i U ¦"»"»« WI

¦OkBLr&ia

27



X -K

s'l

-------


<£ly3..'

-------
0263



V -

' 'j

-------
J	_	1	

' i - •*"" ''''''	•"

. - -..r -

v-\:	V-.-

->Jv;K§sy^:>../. ..-v

-------
—-—:";;J''':	t :	:' ¦ -^;-;:'y.j

! i

o











*L























"2

r



$£;



& *

Wo

SV



%»¦

,































































2

<1





£€

\

7*

*/

5*

<*c

>



, *»



























f











































• tt





/"

M

V

*T3h>Ji

<2/

4

3h

JO

-

W

' r

r.

a,	;







1—

fc—"n























9:

q



H

5S(

fr

1*

*>



5

«u



-

0*







rf—-



1—r

























-5

?



H





*

&.

.S'



P



-c.







































ft

|



/-







fr

s*

JO

darJ





1





































*»





„ /-















f

~













H

h.













3



/4

W



"



m

«"

*

- .i :





u

(*/















\







>v.

'





V" ;S •

•; S:'

	^4-61^-



''y ' i.



' -"
. • -

W':0-



"©.j- f5'/5

fjE£

i	3H*.. .	/ —	,

	¦ '			

-------
Si??: „•



!















T







E?

s.





















4-

V-



(9/

A



? jr





p\









; =























0*



L

.1









;

dl













































-JP

















'-...k:-'".'--"--	>V".	'

.¦ • ¦ V		 •	¦ >¦¦¦ ¦¦



::

....

, . ->:.v ••	- ;¦ -

,	!¦'¦¦ '-V 'M:r'	"•'-.'{f.-'.,

¦' V-' ; •' - ' '•••	"v': ¦¦'y't'\v'' !•

¦ • ¦ •¦:•¦¦¦• • • ....

-------
• ':':-y;'---vV; >;	v.- /-;•;?" ""'I'v:;:, .

'.:-0-	¦••-'•;- _^_	^	^__	••-" : ;'i'-^-.	,; *-¦¦•	¦	.	'	.	':*-•< ... -	•.. .• ¦• .-	- — . .

a

u

Q
0



































0

* {

m







{,6

































































'J

i



r?



<&





5"f

31

ei

P*-4

0*-»



Ji



—f—













1.

»

ifI











































/

5"

i







t





? '

kJ,



/L



/ 5

JL









I





4-

Tl













%

















i













































"4*>«



C<"?



fa

^3





Xv



, /

b-1

d



hz

Li/

fir"

















	f	

/



V

t

f







tl



7

*> *





\

fu* i ,

"f

(jfl

^ (





,5"«

*//





T t













ft





.y

t Cj













\?



7

I

Tp\

""P

c(

/» 1.



s

{_^i

* ,

k #

r»

















p1



ffj



111 ll»



/









11





Is





U





'/*-v



?rtj









{*¦

n»









r





T

7

£

5«



7f>













*



1

>4.

¦%

<



















i





I '



/'









7

A

h

,/j,

T

1

~h

!j







v









«»•







J





17







r



















































-



















.v.---

¦p . ' .



-------
0268

ecology and
environment, inc

International Specialists in the Environment

-------
02S9

E & E Job Number

Telephone Code Number	~h

Site Name

UppJ>/ m 11 n H a. rf // jfVu ajA

.%Aftn	 of

E & E Emergency Response Center: (716) 684-8940
E & E Corporate Center: (716) 684-8060
MEDTOX Hotline: (501)370-8263
E & E Safety Director (Home): (716) 655-1260

-------
-------
	/\	

\



T

cP**

up	0271

js®m0	iXfpe/	Oi-L

Mb Icx^a kru-am:^ nV), Qmtr Nordcrn f&N) anri	

~ -i&rflfa CahlhrfdLD) cAc^cxn frnrn \nr&e I -fn .Spnmria le ~fc>

	vi&rhnagM££L.Hrnf,^

1-09.30 7?c K.KJ I en ^

——			4» ».S^-	—-Z7- -f»- ' M.	I y,

	-e^? souie, ~h) CJp\/pJanrf nflryipsr-\ i, QL-H .dj\JtA.^cJ	^°-

44-*—

— *. *,'	wu>ly»'!r'.f, * ' ¦	* mjr '*¦**->* nt/'V *		 nu ^ t .» '-»* ¦.*,...«		— — ....» * ¦ ¦ " *

rA- -tcO M n^r.s hm p (sitic^M (A SfM. fa, -pic/lO ^S*rf/vji=

i~zL^ hincaS,—(hL-H \ n^-h-jlAirl c* 44*Utncj ptjfifi i n

"¦ ItL/4 in\in.lii(L rr.mn e-he, «5/uxfe. -fa k*lp



	T	»	f I JQ 4l>1 fV/l...<,tr V	*- 1/1 f 1 - T ' mint	f *¦ ¦	UUS J.

/Umoff -fdiAA) tn iv .Cb^a^vt. t pAJtsJenJ-		

-•^¦ill hinged trI )QWj ¦-fa*Uityj$ ckxm^wJ m ca oe)c. he

m-: - ^ ' i „	, I _

f^H ^ipniA'&d.. -hxjt)f\Oj$ -PrrmA ^Wta. r^~ bil(AAD pjQfmh.

_ 					p?Aad~7Cm rvJj*	

	IxTJUn^ pT-e^r-ff	ogs._.pn\]q4e.

~7hxrrXshn - mjll hulrUna - Aila fdAn&(i rj\)t/\ SjrpgJt,
	tA3(l/^C- AticJL- pnijL. ClAmrv^ pAPAfpjd- alh -t-VtAj q.jjX-

Ao p—^c^cu.-—o^- uDos-^f	Sr^y_)L. p4 b..-	

ftV^- r.	j hit.	^GfXerl QCre.ss	.

l030	fAg~tr.

'rr

—		rtL	Si^ilxd -. ...			- - -	

fitO/nc hcXoA p* JUa±' +i pHi lc.0.-t7Mt-p\c1bunL.-

¦Ad*\ $1}-.. vA)a^-ty>—PiL/u05 -M^icAiah Q-,- rtyif- bridft*-• 		

	-4-rUA- a ppg-%. /' 4.^ n^arl(ftcr^0£ 4 Dmv^in<^

JDQ 6Lrr)^ cdt,apsn„pdt. wa^t wrZ, ta>Q-rea. Tk: take:
—~ K-unnram reed ugs n rpu nri pyimeMr. ferclirg;
or> vJeronn^ a re (p rfflrltrv)^ nn rvnipnmnn p>^- ^	

-------
otm/or

'.low*: xhihfrw&:u-vty.

(J970 Ry"

*oi-63^oaaft

41

Act)i~ 1 A>"ru

I^Qf) - CKTPOlfft lOf^-hAr> r^pn^AjrYYxiPlA^fiiP rfjnfrtJi, nP>K\o. jnu^e, p\¥, 4

fier. phrfrm 1-1 -hnrii , {- (ryg-finn rnilfr^ot ja-K-48cOc*>' 9R.5(gl	

Jjyg'. uffoi'aian Att: &M .4c*			:		- 	i

/PaO-CNTPo3SS jnra-Hnv).	,vf	 UWi-l1/;;

~ ¦ s" ,4 !^J 5 '' • at^u'crr, nu	-

/*" '/"KL \	1 *	,i L ^ J

	loccttion Co ct&i

inna :	M*'- 3399. 7/

J330 T ^ "^gAi	IdnfJo Hrf CL^

'300 TV KfSarr^ LeavV ca-nr^J-xrvl Hjnp^Formex Milhfr,

Tic coltrr±^, rtesnrw. OjtxcX MmWom rro/ltrQS. rfflflttny nrr.nlt
AI1 -t/i/L+ rPAYiins c^-f-Knc, building IS rmotmii 'XtcrntLQOrL-a/U* burnt
WtXrUOrrirvlj/71M)I fhP p^ryyKtii AlOtw^ Hirrvvd-ftiP. q^vur>hi^r, m*fhp. flqOft

LlA-OlOncr^)

mrnpr. r.MTPn?,RSa^[i ky rnir^felpjfUi^^	P,\p. L\ €fe+	

	'fall, Q-S hnm^ars/jf uitUi fx	msaSu fe--	

£2£S_ hxar\n no pnl I ect(T:.

'ob'Sl* 1$V-

WQVhc.im"	A#: 33f-

-------
Uy

JLyri&OQ^H	Ut,

t' f "f-5r; f*

... v..\>iS$

-------
6

ieliaJoL

v. QUIA1,

it '¦



0274

c?«^ !

orOX-qBV,

i	IM3 A rr) vt. M» If fzidfy .**•£.. pi I p to QE c>P- -Prx i < ej bail.ctoi:^Q-

appcn rs -fn Vr. LOasir roott -teu Urns fefri ma r:

QiZ€ -to mO

jam

FQ44 iViris 4 g-

hign

¦Ihc. £ree^. f Q

ibt LOQfif/° rory pib am	Hnrn rinuyn nCXprrnriy jtfc-fryymr

Mill huidLTYj. Ty atJerm^yy-Ql prfS&noZ Of- tm
^ream -pinuy ncj nvrr-iJrv, urn*ft-. wry, pi i r, ~thf, pi) o ^hrni IrA i rf,		

od . lnj-.4%p0T Ql.fflo" long )'l86OI*AA.telO" AH~- .3333.4 S-fih

£CMr\pL

IfJQS -ry.fg.Nj rfhAfn -ho IYlt .QnJCexj's SuMJwrhMt ±> pnrv.cljL.

		hrm uj>i -Hv. _	xfjg-c^ p+ -fey ^rxjupieJi.	

10 TL<-gM hP^yn -fe W.oe. rlk\)eArx rfl	Sinp -f-n-ialL

-to 3r^( ~h	iV^. 	

f)£- -1 mj p wf IC\ i {?\/p.\/i t-A yvr>nft

Is	(~nenl c£$	%A "2-.S" -fe yunnoLmc^ rpir<^ ) n ^uAcJn hjf

GrolA	/-vi	~7/>p o-£ rDa rA— - frnAJid-	i-\ti - /o£>

fu"^^ /r 1 I '	r locuhtA^

CiXJrl jLA>fet/fcM

i^Q.	)W: 4n m^ui itad^H/p^^T, h lime Sam

jdy

i/lpg) punrf IfODP. rWrpr>h ^iTt fvyhrrr. f^nl^ gn,v

Pan not-funa jorritmn^ of Nftx^	or mi nr^tr

Ihpn mif incdr^	Ohgi<)/j br adjxoejnf'^'tJhf j

Ciucsion CrecX Omhnf Y?x\C goad - Mo 9vQrt 6 of- mini ne\		

^	,y

-------
c91



&SBu

im.

ulcLuX*

)0(.APS OvfV
Yfampr

^ ()£ -t-Jia

.1 ciAj&	

^.45-

to p(\N



Jz£L-

-^iT£ Y\SrVeM Cleveland M,/rv>. and ml tnr^nt | knd^rntxrvi;	

3*tp."iLi'jn0^ pi lr^ nrrl ) uyA-tr mry^pilft lrl Ear- M.imp-AH moA^ ir\ rh^
drect h K^Qrw?5. PhOtCft us^rr- \txVjfjn nt-iTX- ioCOhP

I— Em^TTE- a Mr^p-tedL-to Irrrtfei 4r fJejt>o I ecxfW\ 1 lr; A $ Cf (Lryl/° Scxno
. mi Qoti I
-------
kMl&L

ikppJL>'' CfiurAhi^ i'Jxrts

0276

01--CC? -OQ3%

Did

¥5 KLivi iet-?- rrY^-^rr^ uvrVV-- Oai-p\ci^t:OS£i.s -fr^-nr-f rx^iStonr/^

locating Mao Leodl/nK^.S-"^

A P

cmo KtffT\C?'iJj±ct&

st/xf? (TY\ WxxCL.nr-A -to	

Fki^tCTv rSf/in/iQ h0j kJ x jn€> ~th rwrt ftJharUS -cSHgl-cO fCSJ-

, ,,		 	:_JL^ XJ u a	\^a fv~-i	rw u j if

j iA-0"TV j /-...D.M Qh\ Clj'v i VP Ot Fr i.
tr)f. D.m^¦ "•

s,, sco^Ao.Qdo^
M	"S^taxl ft

\jr) 'U l -TjUl	'-¦ ¦|"J>-^IV JjT

A/o  9 ;Tfirm^

isrirTfk&s)ofik:' Irni O^ir^



4-VJ

u^cis4\.1<;-'» '¦

¦t^;r-TCiXm.';,f

t- — -vv.T

,.f :1



a 10 E»h to\\efHna ni-ltWd fvi/uUna no 1pp of ~ta^UV>

x_

^e. -^SVOfial -	4i to TrfiS, (n?.S[f \ofafoor\

inV.	WAn'T.fe'Ma.Lil

!>-. ^ni,7b4 ^

?£¦

GP5 krcthrrviK srjh hrrfjrJYijL- /yf 4-kju. ujqJt- fxi (JL,
pnlr.kf^Ut

(i)5£f<4" 4rtX!L *<^S f^cdujiJjL. *• 3*, ^^ rLlLf)

B& D yfl&h o pti^? /^ pt^f at th)<=> IfrCCcho n
Therefore no tnopa^J-Q/xyn kr aJitsihuM^ -bvmfnr^, no	,

JSs

Simp LeS ujcrr. cb I \CcJftf at Fvis ra ftto nol&s,ci M > n&- NoftZ,
rf Hnpj]pm=A)olr, an! it/frHorfo-ft L&j^£\nioirtfc±x*\1? pilr i l\A^€£rg.K , >0nU^	c?f

'	iyviyva , \s rx. dk\aQ]Ao^ed KcMSi'tna <*burht.rt.si nrk

4

2t

71-

^ « - -i

^33

i. I * v—yu-s—-|.,y\ \i| & I	" py|r	wi i r.\,^—v»tv^

\3 o~* di\ap\(UdeJ ho^s'i^ shv.chi-re a nek

C&Q	HirV.	nc 
-------
0-0038

al>i5tLliX£z



u

(iliKrtY"

0277

OhCQ-CQ^

uV

r—<—

z£-

*



VOcX. p\Ks «So £4 uovU, 1 Xo £egj- -toJil t

'j'r (pA^ma-Wi -fig/wi. fop efl ^-n 4a. iqp_aV 0^-Vki, okgri^Sign.S C/Yl>
rsKiJ "bctngj# ''	S^rui r n loandcrYled YYLinx_ haZnrrJ

	Sign (Pw-AiQ. Sgn cty\ ,5W " tup (/id Pu/c Lud^-

	(Y\'iA in ms-bi-

Att-rfClph* Lmw.-to fcaJm Qjxecvt.W Minr, cmXCkin.

1.50^ Nt

AAaA inskprl r\-\ TTly,#l?ih fYVl nl- \xta<^ nOf

.fe

^V^vOVrvcy

if) HO

TV » -kt/n nrr\o fv (ri3-J~\jpxj

^	. .j-	 	I . i_ r. ...U ~ . *4. L"'

-p.

^sloA-e. Klo	yurtA rwirb . Vr^ CcayH C\i gp^



;f | n	pxHOriJk^ fTViA [In (V-PS or' =p^cJr» >( AAA Vjl^/1 i

-toio.ot tagcciiiA-p. 4-W^ Yvjxjricr^ rjMr

4t? ^>c- nA\V^3 Q	COwA lQCft/j(yy\m,	



DumiyzLA

¦*

; T'

T?C7

jii&aa

-•t ^ leave. 4o loQxt-c ^(jmiraJ3

! lias ghj-fm Qm\/p q-h LOLteVLUQ LUn^ "Tbf QrpQ IA

, uoH^r " ' r ' ' '' * "	^ ' " "r"

\fiM has^f/ri clcfl^cu^",

I -^Kjl.

j \JX\	ftPlbl

(11° ^ 4ie.CAnrAt+ 3mt;4J5„

«5*-

i^L-

11 7SO fit* 1L\\!rtisfc^p-ferf jrf lnr/iJt-€Mrk'Lucflel f^uni

JX

jWk sW/uM hctw jr\ rw~\ ^g, nvxd Vt'





fc44\i,S	ft)o^
-------
10

slFiJOi
\£f jl,i"tjL<

?C		I.'J JTvi i-A...ii....,- ..i' j V\ I'	

xho^reuibS or (-r^S \D8/ul. collfc^-ed

0278

Qhoa

	tV.f iM,/U		Mi	w \.„„w:	UiA/.V^	^ 	V.						

11.^1 ilL * U-Kl yv^ • 6^ feaA^Tx'inL -to fni.WrTT

(^"PS ¦

i/gcQ VU^Tt ajxyuvt, rxf~ GM. Par u me, \rrr.\JTvn. pM?nyi^h6
' lAyyr. tny/v> gn Cpl(%joi. Onl^t fip5 ^topffiffl irrka-joyfaoS\A

fo fl5 mi.	fnnopjrmn/^£.pfvrryi^

..ftlifi ~~K^£n .apAi rnin hnrJ-	:	enkhrrz,	.

tr;•> U ^C)ypyi/\Pa 2>	;			.	.					

LP go, io Fk>scd Stxrciorci M nwnr fJwfps

(idi'tf'chct-pt

vw mt, coflrctot d n t ~b hefr of1 rerqpfrK*).

;40Q d^fhfj^S

-[?M/rK lora-f Myccrrjh H* ~rt iJXOpLm currf^Hj!) cpr&?£3
of 1 col lapsed, dnj Qrt'rt \crg-xri' ir0dc a ntifxl gro, fond

2 %m 11 wi$t„ ynrY, pi I da. Pfrmpi &> u-&r '.nm: mi&tod
Wfr mwvfwM3 wc,rf,rxJt- irkt* .Cuhjirtr, op	;



fturrt nfjf, M.i/ii n0 QCu'm

- ffM/Tk' 1 QCCtifd ii m ffiOt "fKCfl Su.re- 1, occthcm Q ppvw) rr&tfJjj

0£M5  _ # . - —¦. r m- >¦	.	-

"AffwW- \rfrxH°, (Znrfr.vrJ-h M.irr A\\ rCp&& in \ACjn)tXj
mnr\/fd. "Privntp." " Klo bre^pya ^unf "

- IjnJtfj/tou} Munrr-gjea rvfi rx. hffa/iUj imgf^ n rpa

i uCn\e. ktrs.'Orxiirj n°rt. n<^ryfaiy^.\rra±nn tnrmufir vrnnl

W/&, \tq\Mm ¦farcztfzk.

(gold So r M j rt, - a timopM cO 1 lent" €1P3

L C: i'

-------
laiOQaS:

~C.

Itta..

iLcoh

hu5]h

AywcL



$

fhmfkS-



i i

i I'TffoA***-



)XXj

hLi

m

iippCrQo\\xyy)kD\(X

0H79

—jp.l:

TL r l2\\j W0p. mfdr) fir\ nndr. WnYt- A *C ;

	 s^< m-/?", rin/i ftp a) i ^ v"\ iW j <3/^1 d 1 r/W /u.,	

\^)c\f < QO (fl^loj	^'QA' - ^30 TK. . l6	

4 uVvA-U	U.sfs rl/l.^rjuL^C r\A( nes On	

JpaU£* Sin; lie, tQun<$. ~rt-t T^1, Mmd\}zaj?A	-ffrx—

-iri'i he	ioca-f-fcl' or*	W/^ Os Un \jrfrl tT^QlSuft \O06—

ncA- -Mil nf-hJa. I	iocaHc^ o-f UnHc4s ~ffiL$SlLrt. IZ-OQ—

locfr^gcl 4-U. ruing.

•fo access i4- "T^f

cM- rv\ap ^ cM/)Onk^ci hcyO
P+) toil! ^AchJt^Un tf-eri -fwasurt

(M i rv -Mn/ft (/ Tl^ f £M /^Ufx rvw	4ha+	(filial IcrnA

SJV

„	——- CL Ljt	..._.		-- -_-¦— -. f - 		f~.	»—~

—		cct II erf itrrKM -nr?t%^j y-^ fs pa^i Q~P	fYJjrfs

-19)0 Amvr r>f pr^&ihlt A/kA. lorrx^itrr, Gol farfinfj-f^Pf>-\n .

-^defarmunp, r%acf loaifion ¦	:	:	,

-£P\S5 PmtK ejcpicrc pmsi^ip locations (Zfftvonrdim^S rrffi

-Sim) \0ur -hi n prygftitolf* V\Qlr mnn r>p^~firM ?j4otr Wa.vVacrjo	

-A 1(fTt \y^ faudt ypfr>nr?.nts Of wistr, yttY aixryr^jpnl n rfD				

¦.	m.	. \	_	*,

-^lDl^}.4^J«f~ry rye rung Y^^qI to-Unrir- py^-y^ AiTp.Sfig-,nrHns

-ijf)fftCHffc r oh MriA") J jnri.vi) le.-Kdine .pn4hri
-------
N- 12

I

0280

\X ppr.f Cnl limb-Jin i?jv-f/	

()%T

jQL

III Mi

&frr>VP. Aj i? f N ED r\.i^on^mnY c&- |d Shfn JU/J bp.	

V yy	/ I/ ) /X1 f I	fKf V)M-Tl>F * .¦"¦* ^ l^.X.WC.}	l llAASA I.

rcri&k-rntxheti 40wJ(£5hXSrtp

I tR*), AI~th&UQb pLUL	\j^sMrncx^ccA. get IjLetpjp yd? |r3C^ 0£HC Y2$\4-83

-------
wfeolc.

Ujp.frrC'o\ urn)o\CX Qivpf

0281

1;



i/\ 'AT>

I/-*' t ,.JU

IJnp.rip^np>? l^--Pmrv-i uTarlj-frs i^_p -^^lQ-3 ID

	1 .ulx)c^ LaT	FAf? P.

IP.CxPS

£hfr<

~L OfXZxrt InmJinn .

J u?D4 gAiV-Tln nrr^e, o-h J?CT Minf, . ICG^ho^ rnnRftS pF j-flOiOinr?

.ck.L:tj^u Luy pil-p(gp). wa^tr vocjb y?iU. XnStdQ^ftClit)5pK&J

pdxnKsign trd igi-h\f\C\" E-u tei/ci S i>uy?riSo Q£-MC
Joi/Tp OiJlry'r^vp op-EPii<; r.ir?jm is u nKno^n . i_P) /i jwy^rfl

J2AL

»hangjI (CQllat GiR5 rriod^nQ^ tout do hnt	

0 8.141 Lona ill052' 40.(^4" Att. ftQ25.r7-Pt.
ioa*-y if, hf'irva rtl ra med hii P^C,piping /Art H-\n i^nAtr. tryY^ff,

_ (Try) TliL -in _

_J50m pU • U*h4fi'

hij PVQ pi f?i

^	M	v^x^fVLrlimmin |onHr)rnr>f- Wfj.^-irrnrJA pU in n-Urnnf

-/rvfi nri nr> H- /i J.^rWi ^ jofl+hnVi j ^ d yra rat-thg.

fWfrYTw/y; pn^

hrfomr,

urr^grfouryjU v^Qf-ttifrOn 13

rrw^Vinr^ nn+hp. oW /TTT pi )f^

Q\uo^hr>n Tyfcdr- <* fre-eKJ2d ,

Ipmo nn+hp. t .Ti^tr. tDTr pi ir^

J tpi<4nncrAOmnrii^ vmdaif)

rl	1

j- /(a *50 Tk'N- J2N rop/?^ krjr/: -7h rnlVllte hcrfcl io pvp-fnye.

T? t^^ioo pli°, ^ I ^9 -^VIP-rrf-

I. t-U I J a

f tAIIH

Mxrvt- roi irrtrrl pr>i [-tr^oir pH^trgm

f	inrfnf \rxx

|—& PS col Kcfrgf ? phofogm^ft toi

:1"- Lin f hVX ly^a^LLr^ -t^nnY)^ yymAfr. r^i:

nn ^ri^nptc^, -Hxyrjri

^,¦ ¦ w.n uma nonnfr wn6f> vttXpr 1a?Ii-rQf> present
tin So mfic5 ifkYcr)j Gj noficc^ci, phofcy^r^T5 "TT
H/nre.- pTfiioiOrer^hioixinQg. 
-------
-------
u.

Upper (Jolurnfria fc-m

uH 83

Y.TZt-

	Q.g;r

(M3p,, IhCKi^ ]'V, rteptijrr. f'nlvt)^ -fhr 1 \ini If c%y~uZi Afi mmGl' ACtriA,.^
[JML !':'K] 5 TV. OJVuvr:,- RX: i j O if. 1-4 i'rV'-. u'i re. QpnSfc^Oh 1

Qd,f-

XJ^iEscYrri

nai_p-ib . Hirr is joratdoh

.p£L Poo a- 3 iK _	wrrri rirV)Y^ Ct I r-n Py	£S4t-m£irr1

lrfpjfrl.C 'SQCjC pslL Cxjr 6O0H'	. (pfiiQsjd? C^rry-tyi •	

tr, h.^-.S rnnrrm Y'eCCAfn jna ^rp^tfprv^ cir-tbo h^), Q)\]	

JefcifcrmtreS if is m
-------
16

0284

oi&WL

¦.v

ii'5() ^ ko 0crm a if& iin\.irr.tfr

n-

• ' AciC-;

v-i-	— \

y~y I OS ¦ '¦

inrvk (Xl° 53' '7. I(n5 A H- ;&&inA £h Urc?,nrrvrf (Ar^yl'
[ad'^'-ka F6 @oari ^ifS. (irihrlrd IM 16.^ u^^Sfv^mb

: r£ i uyx mfct vmri	rind revDi i 6.	) j'n o, gm Lh irv _ >?f;

I i I°\ IS " ^C@'(tn'lon m -fn FBRI-a	¦

•}|0FS Tfc$g>U (	Pflm Ififrr-hnn HtxaYTjtis Ai-mirpft

	1 TV# ¦	» ¦	1	^ 			'		m	*	w—lihP I ¦	T v J ¦ 'V -™TT»	

13H "fhi nrrnH a4- 4W. ap3~-e o£ Admins 0

	frf^'vW • *^M,e, -W \i\c\L- rofe n creQS^ (^S WrvV-'j--

fordncy a pV\ it ^ ^ 0 c olUolrrl cx-h 4-W On^tL 1

VnL<; sl_ * Ktn

4*\ an C\&A- -fc> ~r*v

p: yvps cr-v^aj-cs: U4 4r^"^r w^: inmmm

jr_	 >Uf: a 33 5>.	•"- -	. ¦ jAf}^ -A

'M:BO ¦TU.rfcrt ^fo.Nl€ -to mti	n,nmLr r^P^ic^r

PN'tYNl ~	 ¦	:	

gXi >ViW/r3rr?6|i^> in tn-G^v^ Yusm~ttn& TE^>PK)

j.^ -T-. « in,c ^frrin j	Urt^,rr £ uy r. *yv

^Qfn ngio Tpf^ i

fampiP^My (inff/i YFCfiij.^drfiYTt.rrfdtr be SPnfrfoKuri (wi-jaMiw
Wat: Bam^Ub hQd Hr.n CtiliPQJk&L,	,	

IAG5 f?n-(571Larr\VP.rU--T^nuV)^ t^u' ns.n >nrt YivraJL-fry jiunpjn„
'• ^ i0i=, . v-t-' u- „ ¦ —" "— /OL r/7 Ki; i /i/jLj4-

4emn4lx-

j -i 1 .

O/O

s- i IC. Ota,in. ^

v-'y. \t3akA ,JLun im)

P^cioy 1 • (D)nS&/\l f

, — —	go^> c^'A/i^lca^rd—			

I:- ./ond (u^na wigd^), 0 fVifX. K	rvg tfpccte;

-^1

K	4p ci/4Ji4 U^i4^fL .'~TU.4i>inL-k>t

XA.uP<;	fi W\\\-	1		IWJ	3M

1^	p.»j. • ~YKa , nrvcfmi	/^UngC	/i^?'-:

ayAM- MxddU. xf<£f+ pyor^j^^ IQ-M-

qjnd~ix~4^L*^ roll a

I
-------
	ji j yv i ( r.l.LAj-)\J>( cl- I^7 iKA^

.A
-------
18

(rJ/'Z-lol

0286

[A /?/>;-')	(¦ <-> I i-<- M ^		OhO

¦d'

)U)C> Sbi^splc^ ciJZP^&K(a)iCh49c5 il OS . SrSV '

lOA

(j-py roller-f^d -

in°te'2£,nr" »!*-¦ a

^2^ 17A") roil frfed Sr* CW pJ<_ J- RAfcfe&o , -pluio

"\.^ ^4im fj tl

6- I -I pi fa. f-iPJ intdjm-kK mlltcfcd
laf:4r,io"

M:	&¦ w ;

1^5 f-iP-S colWr-to^ -fof <>i m pie, J~P I ,i ")P01.S.S

\nJi-. W5-l'Cb.-r7.pk&. U~yi/ytf (irz: p?(i

Mfv? (pP^ fn|kr4f<4 ^yijApie. ;X/£.loPfiC^SS.

i	u • v r>o_- — I	i»	, / < /< t—, a -i^vi *->i c,—1/2 "

I of: 4«Vn're. S-3.C



,f/f: a-}1t.Lr>&

l.'Vl'S TViHuWl	yiVl.Aft'. folk '5

lAJn^V



i.-s	rx4-

"bp ."	CTfto	rxr-rnTC	-U(2£ nMv4

	mp;	.1^ -\ I )> s r~i?) TTmyi , Tl J \TPr

I f^3h) -h)rn4j? nhCAxy! &=ftdvc{n nMf-t io ^

MfAtl'b	<>n tu fie.? ruruk ff/v^pllbk. Sci/vipU ride,

f"7//S	1201 Tt r
-------
0287

19

	U ppxA (ol vnibiA. ill vat.	fit -cV -601$¦

(¦ ,f v1' £ W/ Z ~L f c 11

~f\u jlKJ locft+c- I a a tilLb. Kjidn\rh (cmSisiS d-P

(~o\\ripU>d rln^ fjifUtfind	( iA)aXk , nr\c~ nj U [U,

~X\h~\ to W.^s r ,/VAC	SmriAAu^r^ sV?^pAKtQ-f p'.lc^

	IfJ rkkjrnMrmd if- \tf&s on^f-C -to roillt-h rwpUi.

7%, £, «J A p.S f in Jo pfr,h) aJt -H-t, CJf'^ ^ ArimrmJ-
fiii/bP, ty.. Ho \acL r)£ QC.Ce^ no

fPCCPA-

UYlS n fpmpAj/lk.

"TL/ i2-iJ	'i\nnM /->P	IYUM-	ctnd		

ppfQfkLeJL fv 4-lnbfc4 &(AxyeA \ 7rs$JLAqAmprsd rund AjSChcjAcLtd

- . ¦ ¦	:				—ye -				

\f\ g , n,	r/yy 4^ nJJ^x	z>irLg 0+	Ana.^.	

Anf^ 2 5rt a* pin, ^ ix3*44<,	fhfJc spjU.

^ c/xxxatj -4^ 5^i ^ ^	hmA sSLu fA NtA. I. ()00 yd 3 ^ppe/>b/v

(Aa. u)h^C^l (LipH— W^LartlAQ/Y\U,f pOdUP LU2tj/, .Si -frf
U- -A(^ny//i fyr/YW 17TiQ x



cnw /,^ . ej4(4 jPirf\A /J Jl -Pic/lO j		

yUAH(?ff Jnds in M-z- -fi eld y \(AM 41£.

-------
20

MiniI

Oppts) Colu,mJ?i£- fU\ nA

'• sXiLpa^&cl rvln-ir'i ^ ,^-a-to \h

0288

Oi-Q I ' CO r r^rvl -WqICs-(?.-r ^(auj f-b rnljpri-
ffy S^rwpW^ ,&-nr\ r^OAprinrj ^Vrru^es/pD3.SibLcj^)

[0^50 Tt ^ ft-U

infU-t W)3—a cross	olvpt- ro^ ^rA. in^	vQckQ"^

\S\jl oy^oppQSr^ , c^nW-

¦fir^

cwncAjs^ id	n?,6xA is	)gv*r0c?

a M \y r f iv-c^xa r\_5

r>V'kjLA^-

		—r J —www^v^i—	m.t . I r ' Wficv	—^.>-

-UOfiAV. n¥]f.	'hK £W£-. nh$dr&€ri 3

	 PVC	p) piS	lr\ J^krrnn q-V-Vola < . nyJC* piU*

PfyTI>^A ^nXond \ Ser>:* ¦ Vfr> vxifiior ujcxS

Cb'v? AVS.d.			

[05O RihJ colie/ihs v-$U) StL-MpL, ppr(A/y {qy~ ScLmp/*
	bu-i no ^AJmj}.n±x iay*/u . p^JUUJuf- - a Ik rudSJ

W^T

n r\rJlv(L~ iAXsh WnJ^CL rf)rJC- (c\o±?a h n)aA\

SUJ

Sn/rviph, cpjlpr-lrcJ t~Y)/J-*- A)£ loofah.	

(0  -feoi Ptzma: ,.-
	cJV^Cyvtvjr111- o$r Sp^Urfi.T4- inot Stt^ i> fiU lL Poly

6 PS: 1*1 4*> UC U4.b>/r if iuv^ v //7°	fc// "

^EZEhEMM.

	^ ^/Q is 1^ ^/?pw-	

ll(X	"Tt^t (Z4O Ay(AJivJP. /teT ^ytk£.ht4p

P P^". S^i Wv Pi\ € -f P mA T D\ (Af/" i /

yir;J i_i nn^trngd r/ c?pA -Pasr^ dX

-------
rit zkj

•L0_

If / n\ .hi a.

0289

J /

Qt'Od-OOT#

i....- iPr k-iv on	rn'ini priori/us i

"L	M Collects ^p-kS <&UK rlr, • 3c) Sj? (3	

"TAL rsxi^nX^ ^c-$t A Xn, r*ric f r,\\p A-.

Jtij \>Qa-~kA ho If.	

-fv -f~i H 11. pdtj , DnL (j

	)2l\) collirfc	.Sajyi^l/A

ftpSmlW^l for \/s

I Anna mad caqqJC-

Qm (k*kr mi" n//l ^hflt n m

11

ps+yrarr)	# -frnrvn tiu

PPE wmi/fi nrrr ta°, o-fjr.thinG+m>, iirvLmad nrcm-CLm ,-)<=,

•bhmu^-Uao. u^orr rtr^plt pxsfca ^nrfp ploro -fn nga^ a&i?*&
. ,,f^ crer^-			,	

iS	r

Wir}fi&n'~ftr &{sj **k\-K^A -TDC? . U k nrU		

_/;i?H T Tf.r P. kJ t rw\({ UnCtS ££-)

u w

Tf r-fFhJ (jc,
\A*\ e .ns_s(\QJ^s(_. c,

-4oX_^£43J^k£C,

-XO£L

^PC VSTPpto »kM.^

•MJU.

ff t~ (Z^ fZ((h-\ OA Aj PP&S

\L%x"\pa ~tiKP?.

Mf

rr 	—	1 i — 	i » ¦	m	i	in ¦ 	—		

l/^ST 7t-.i- iZfQ A	. fi-*-	!.'/¦» QL^" 5lO	Wi\A ' e-A

.	-Vrt^Ufx^K tv	^(A [krsnfl m opl cappa.	 ha,i n-H aQ

	1...~J,,,^	UJU

t CnVS fr-h

i-rkc

: -AXC Afi'.ltJ.lbS' ion<-, - in5^' 3X.I&,

! Aw - ^)o

v,. J~S> \fp-i .

j lH 1Q Tic t TZ ts) Uixpg. \(^j3qa -\txAao /y; cvrw^ • &f"imt>jrjr of
l/_rsi )0 A 4n A Un^ <, p/ri/Z HfI V	IaXU	Q< 3 m J-g. >	

.J^,Q3	C")^	u h nr^Wfi! cX: AV^'^U.^12	

\n°^'IC.U6Q" M:

Colhckd-

L A-XV^ '

-¥yl-^p_ Cnc',Cndp

KViV v>r\na^nA rAOr.t [nnaAn nr>Wn-hnS. ^PF rv-'d

U/a
-------


\a pfusi (cId m bio. fOlK/C ^^ %\ '0,3 -0Q2&

\ rv~!' -\^ (•", cLi'^i i /



a, Fw: rv?;

nO-V 1 ?:¦	A P.N 4 h(L u pp/t >7( Or'prf. n.A t. f.s Po

U-. ^

\'n.U*r-or

Ifj^in Hpuu... f/ro.i-t* £t,ma. snhnnoL. nf \Jnn .\-kjyi



'/'2_ rA'ii-



'/*.M

^ > - vS" h Oil. si,s >- i	4-ii.n AYg

dr f np i ,.-njr f 0 i j nAeA mvi ,/ rfi c
. o l >i „ J ~1 7L ~ r i. . --V\^ i ^ „T7

,l ' - 'J,r-	"

I /mi., 4Wiri/uvg



;j±J_

dkOQ	Tt *- £-t0	^QrwIP. Van.S-}rw\o "TrUiM, n.nd Konrl

Wc.K \Q	wsoVA. Yd polV-ta rx g_	cincb .	

	fcTYYVpi fl-ln" . y?jn\p\o /VrY"..0			.

-Qy.iZA u'l-g (x.?' ~Tfc, (?M ^m.plect	\/<*s\ £>jr/vw. "73^/v^ •

		3 5io So.ry.fk.6., tJcw colledfd -Cti/m a sfuJncj iphtcA

	cnACying-k'fl t  rojlff-kJ pfp/DX -35" -fee 4 AlfmYLQ-frPri M oC

Ar\e. 

v/u"\JZ.

——			"'Trnirir * ^ ^	^•

~ 1 Vr?l	i^V roiioc-kg -Pyi/yv) cly\qWjaPP£ (orated

U/.lr/u7	iMA^y? -\-aJ,Ur\q$ pr/y\(J /7a tp* .			

- GPS/phcdb lma/ (oltec-krl nf o4^a po-ffn/ia& dramnqJs
cajul^ coK^c^	opirf rv3-f

-YLzaj> capo LA p-Am-hallij r$AnJ7\ pen Jims Q-f- >U^/ Ut-/e~
h_p^-f?CLfu PP£s r/n.J^U^c CAOcJca utesui^ nol a rr P£

Mqh,Vfr/Yu. fH/iA^ ^rrbntocc. 'i^	JOo (Q-;7z^Srkuui)

('/z-\ m\\i - tThwAA&o)

Z7'



-------
¦ '¦o

u^yi

tL|o fK-r 0 nl i /X lc J. Vf f

(_-'i OgZCt,.

^ p-^-1	v	I J\ K^-A 1 |J^ I	'. » \ A	*-- •	 			

-—&8£i") - Tk 4 (2 Ki mrr.r Ln -mrflpi -fro uoorP cm	rioc cmr

M|ffepcxrn thmos -for shi ftp iky* -	

LI&30 Q.k\nnj>p t3nn UTLiry, P(RPfl -( )nnkr[ ijn MHra I isv EriU^~X\L ^ i2.f jJ H'i_n

o*

refer "fr?

iff^Tn'1^>UjL \A.Dv V pr\ SCLt-y-)p(jp A hi p mp rrh p Kr.pH rQ-jTi vn6

:;0 f^rr-In r oLLn rvvr- - Kr m /ncu^nder rf

H ( £>	rnnnniiCfiYyrrt- InaHnftf.			

j		KJpiAD'-fcrfvl^-fr^iuecfc: moi -to (Pizojoi

QlQLA-301 -to /oQ(p44CQ, El QT*rnnCc,

CLPnumMrs to rerm jn-ttu £.

-l^V^uaASsW

-------
24

029?

Upper C-C'lumioicL £iVe..i

01 -oa -OC&ft

HfirP Prnri (WpUlr M,lnc. ^cxPp.-h <			

^vj _c£p\orA)Vfhi%' One He KCn& n hmo\ YnQt

-fn f.irA.^i^xwi U iiy, W-Pi.rtw/	/ /v* rx.s very m^rl

1 nn V(\nr)\mTr>YVi,	.	r	_	_.._	_

hwo glM 'apgfcf*- uOibi &m m&try j (60^1 &^-057to) tifcAOitrnnft
, -y—Ti/ /Ts	^ 'rrfeiu '- " ^	^ "T^'""

iZM ^Y.t& Ccrtax Lett?  (4a) torlzW	^i6ft(Q^<^t'

M inf. Tld dgfoayr. QVkdLp MOwi to h^odL -for CUu^i&nd

t/"W^ rti i. t—n/ fi>n, „ ^TS IN./v^-1'«i. r> i/i k->ic . , ..Tsi^. _L*v.>' \/s-> v, CS4*j>nJ~* *3?

IOTP gRH-nv qfr^gurnv)^ Printer ij jr*o-frw Vexjn

"ftjprsvk. r>fTT nbnoyrtolrri. EKf+Tk wil lV HaSTtxS

m -fiyrth^rp^^pio (nfO-fmrft rpc^no-af it lOQS
\pfAfXOrcjis nrt ettf i mpnji-nnd gau-^qt upcuejr	uyyuXr:

r\r/xi: fa\0CG)\\rP}fg
ypmprlAJf,	inrQjhb-y^ l iPl -Ho ^-hh/L, W, flrrviftfm

aid ltKTK.QJ



>mr

-tE4

4gM Pb^LT-t. lor^rrn * ^HLJ-n"fc)

uf/c hffitep^ffl(

^ivfltnh hnn^Pun

^	i-fe^u	s			

IASQ-ff-K!m ola Mi/	forrmpJ5(ft-U>%4"C%7'(p)*rr}

hisPfill john/wr r/Tffl	infrTKKvo hiM 4-hlt~Tfrof-£A/

u^re- 0 fy/TD(?Ki.r\q Qol^ille t^jif ha^.io # op y mppt W/ GtbQtMr

" - -

aj"	

rum i

Vp Hr. lojf^moWijtyifip^D^niiJviy^lr

i	Pnrrif^ Adopter? u p vt?nftton^ VgfCTt£>

[ i^^T^^RKrtopn^	mft&t Mr.

Matryxj

X^rjnZ^

mr ma frm^ rxt	La^c bco& txunrio.^e

l^gDT^^KJ^gnvi

Wr,yxj\* od-3a£M^an Mw&,

fyfDYVUsmt) ^-M/th£, laALhzd pffM

'UIAHa^s Y

i^kdtLf Ihi fAverA, ^ArrirundWw, my k>^ nas

kixartbsl

itnn»U

jbsi

nPthi. to/5

i^M ktri hp iaIXS

fl/eo A svmUmloiil ffi

Mmm

^tesfm



-------


02 3.1

¦LLpfrr-rniiu'Yihin iZivfY	1!	0l-0£hCGZ

^rri Vffl -rh c. fTiia n u Ya^ b'1 ^	^ Q ('YCuri

~&	n

tD hp. uSfrt inhfn i iTTV ^natnc fiui too . (?M rA>&. TY\c ,-Tn.nrJkry

fn>ng^ rp£ I rA rrc nm- -finuDinr^n U-lmuQfri t2H 9-hair

Ahf- -tD Cabin -7D-R- POtem i/S-Ph Wjc Bfh vV

-fcL



-ojuXkmt



IQ-Pt.

nrft: npv\ ix> . Kif^o -fil i "~T~rQ± »-< J^1* Cr+nJeiesL CnllrQi

j nvini -fo^.^fPeST^Oia' / r»ng /17Q M} 1Q4M A th.35D5. SH -	

g MV/	r*\g,fYiW •p^ntrrj^n^ m'jI LtnP-6 Lnadi. ti-iia/ijt.	

I -Rh	4^o 4nrvi^ii^ ar|U> fY(rUATi>cLj>ixniah

j tpfaifill tiu ttuhmfr ciflim ^iUYew/tt^ • 			-

LLm£ GtmAG GM CsXtuf UC a/ecue/i 4o-mna p occti

j—ft leftt-to oyiQnffi ^nha^mnjc <* I jno, ggn^hjr.-fmrruTM -frkt-ft	

rvAmje <».*, 4o RangUj 7x41/4
_i»—,—borvt-1		

LnOOYfPh &fj n rrivZ-C m#- Rrxmitu vVl ?f/< /'S Ur/ifirfi^h,OriSLPo£

\jatn> f^Dirv. ~YV\ i^g) -/n -f-t-fajLrm* nUn^n/m/nf . IMo rani.
iflQ-S horrid',  ri an-fL*

2^_

<¦/?kJ itnxitL lZnn4(j nKWler*^ mu^e_ fe



^OQ 1^,»-[Zi)	m ^d4?i^(^L -QXl'?

rhittuD^rvifiil

CTari^n M ay*, - Inrn^ri um Hn Pm (Dinnerl aiWcckd



-------
26

flOQ A

(ola5l&/	 LLppr ffiliLmbin QSw	J ' Ol-OO-OCSft

Ol'Pi'ViQ ir, ( f'Dn f).				

JM - phiThffirriphic. (M^Cumocrrtll.fiCrnJ Linear? gahJ6'fC7r r~OQ£|	

¦Icrn^rm .			'	

C\tsff\sxtij-cjfimppgr cm.. Meari ^cyrymx 0^,00 iqpfl-S

-frrr ftym nvmlnHo .	!	

W)n ^fe*nQ - fT-hirrwi Ar>cixyr^	QnnrU^ Mi 1 le^ CQitMy^v) .

-------
27

	.U-

4cgUo

LLp,^r Clc\ ix mbicx t2 i v? r-		fM~;D^--OQ^

V ^ RhJ n rrwt, c>Jr RO. H'^'/ rrgc^- [ Q1 An/l^i.0	

,-£E^ejAH) to^X^crii'P^OfVK i CPO Minf.)

....Cf\w Tk. coital PDSf^lSD h-pm xvx^ryn^ in ^\\ffp Pp\

dp

fend

dat-l

¦ Cfl3F) Til. n^i|r/^t5 PriSPmfin frrw ,^pr\r\r^Qi in -ffrj I irvy>

on\\rf ieri on tcfi5\b\ hij mw -texm . 		 	^	

& ubte : LAft-^mn phAtviR -for- 3 oiaftyr, .yimnlftD-faEm btj MW -torn •
«.Xi> T£»gM, Up, AB.-t Wl dswos-t Ta\iuYf> Pond ^ keiU2Ho

»pMd					:			

l|DHp A)|/»r+ *> yyxc*s ni- mycnis .	

fncjuwn^ 5ri>y>pi/ft up) 11 fcr iri.kj>^ndr-mp. toar. of tfi^.stry^s.

]6>vPo lofx? hrm I n4- 52' fAS&lp Lnnj(CP 3/' 44,;Sf7 Aft- AlSf
J/056- c »mOU.	WP&38S P/)l Jr.r-tezl on northenn *nlQK^e^£nri -tatfer

Ui^ia^ai



Lm0

.Qmnbfr.

SompU «t (ntoeK-fvivtr) \rvr\ nf ivoe^r, wyjg-pib cnlkyJrrfrij-norin
_ Pt k Ha<. dL*$inr*-txoJer run off ptifm -forf1 tori a ri'trerMo i*?
pn fcW CiFS cplfa^tol	B5.464- ln^in°^l'SI.'

J AVh;a0ft3.7*£h

J 1103 " Ocliivy Aifito rf- vyflftlf ynrJr yflfc to bfc^ nrvi rlfprtrt, IftflQ-hftW'
-| *TV.)gJJ, LT>, AH Yrihi/yvfo JvrtfcJ -hpyola n 5ft*. yiftlto frrTK ^B-M. 	

-4 T%%Cdfrri, AH, riYY\\r,f^r \nrArl				 - _

_i !3g>D~tK. (2.M. OjLpgj'-t Hrvh-J .-fc? Inc^fr* rfeBPp^mr. HinP .		

_ 1400 iu; d?xi ar r 1 vp, aJ~ Yd tol^vqd Irr/xinmo rn^i^ pf ra Aw^rie^
£\oh>jPl m$4r/?L iAyyhjur^jncruf^ rc^jx 1 prrvntj. arm nny. imuif; dj n j

-I \4l5Tk cotton Pf^ qed^^ryyir, FVXKvyd ^ Orrna^ h'^^ ru/VRibb

0. InvrB 1"fine . ytmpb YMPPO^n nrtifri^ ni-

, Qp7 r^lia^-ld-yea'm.t€d i^. in0^ x.o.si

?
-------
1 a ppry rr/iijmv^fc4£iv€i-'"
1 ' . ( Uyrrrt/"^

0295

- fY> -*f

[44^- Amw 6) ,"Ttyfy>ht/Tfr via Vr

consfe of gIL-&-r-rpt

-?-

0A| yi pF-i tecyyj s&vt irfr j rr.. "Tvy m; .i a ri s * p ni±^i ar-,r -fhr,. PD
-(yn>vH->T, wnse gnrx r^ pr> Minft. The ^
ftn 5V ho/H u^^tnppr^ rWim Unl/ -4n6i5,.Thf> Irrvr.  hmrvp^ »r^ jrn, p^pjyi) aCfrffc Ty^fthfrfy- Wsg wetted
nym/ltCU^	fiLu^/'.IVTg,	1raf. rAH)

hftfl rirVonS ^f.gur>-i n\A y?i i\ 1 / ."The si-b n.lsn rnnststs cf c
I ^pr'irYj •## onQtryjlr % f^.irtxte:			:	

330^L-pC-:-*^4rk* in X p riiDo p o. ay%jt£X taMtAr^.Tfc/i(L CrMnfttfi	^

' ^fyyi CjkYti&wf, i b nddj kmodJx\ ajv&fd 11 M±h uXSiL YcckL

M	

fccpfp) .Thfe	, wftp? nnfrpcurijfxgrt krca^

WQgk Kftry -prmn	j	IfytL^d.

mi- yvf^oF^YH \cxmm. PhgKQraphs-cmc^
Gjfecpl 	QfyQ^&uu^JJtlauiloi*--



-------
* 0 2 9 7	:

, iolaic I Qi	Upper caumt?xx gj vtf 	'rH-m-Cc-SH

---|i£- 3. o h P jNj	/-eiQ i M Ljp\t!olO UijurJ	fQ rnpt'eJl-	

—tU 5-p—7X- < f? n) cl/otN f art vwH&.,		:	

-NDfc: Cto.fr entvijl .0.) mi. wpP Fk^y> Oy.4:  -tfoPft	mi r ^ ^sffris i&U^;Tjy	

¦Mill H|>V>; IS hCfr^irirjOfifijCl cm tr^ tnttvU Q^V-of5r-k-^m<-r>e^> -fo

yiftHr bij t^X^lkiile"t'inri>Qh"TKtts&-

-------
u>faifoi

0298

C-nlnrnhiCx^ £f ivtf

Ol -G2~£Cm

i *7^/ -j A,} Uv r\ r^
v_/ fjw	iji- T ,/ri % a ii » t an

A__i,

fAJ) I g&0-£_ iVM^fcA fa loraftL

	lOa^W'iacv^rw > fUjng.		

ions' AP-Vr hVi(inA op K:-jis^- ~f*" 'It hcnxj^ a rvJ
-Qsonrl -hrW'g ^ f)-C pn.inp^ HCr A T i/rnj^

^ 		X ,^. A	i J, ^ .% 1 Kk.	•. rJ/5 4tn

O Ainjr^d n.s^d \n cq cl/d ck/ypn.. ross'ib/e jp

access a\ui~ ^iGkJLa	ufipm /xoad. ¦¦¦)•-£

nn£^ p rnrvifa ^ a -kp rvt m*> LA nUeJM pj-	fo

O-tCtlS tOc^Kt n^fc/K

l/i Q^~ VfftM ^teq#

J03o Tt <- A~\ np -teMr n f l^-K b^£^ rl/V(A^n^ ^'" I

r^m-pif, behind OnkiL ,MoW-



| /ny Ti- > ,-n ftrrRXL n-H ?^h, pi.. l(Vpfit/v^ (\m#2S?

•icvri aes foiUr^ <r zrtiucU^i Ml a

A'r\ d P cki

dkckd ifciauflftc/icf -fidd a)

^ pnnW 5o -Unrt^~ "TIL



Shifm.ani' if.W

1%*- AZ jpaiK, ra? lU'r^Tu-f, fee/ Tcpj *$M£l Ufll.

ArriVts nHt FStfryirl ^>^ rtrxf	W\i

'4?w Tt«- A7 -fruit io fS ^ 5j[lfa^n ^

5^4-1 o^n f IWj - pe^rbfrw \ a f	^ ^: :g

\kuy~K, Shi?.	<^rk?r
-------
^ 117 / 0 i.

I	(^£S collgc-kr

UppL-L LQ[&r>\bia^l^AU^^ 029 &/<>

^tSS^BAdll

w- ih-iq'^.^.v ..4#- ,Q\m.\rM^-

	MMA .

/T^5l\)o pngale iprQfxC-hj ^>>^S niajna TS axud •

M a ns ? rv-l i fn-/- ^ vf/i /s

09/	/X

!fw"^,r/ ¦&. n/i

CI—

prop.4~K^ . T? ioa ue^ L/rjc/ \4-f'/Ki in r7s>j-t&< -rb SiitOun

(. jCX J(Ar	O f{

£2

f? CkOC^A , ^>

Ttr yfl nrruR m> \UkT)0^K Shzh'f/V\ . UjlU, .*+hj~ pei^S

iPho /.s	in change,. £$¦ tfyS lO'> H	fcfc-in fotfttinrw,

mitfnA ng , *n<- ia)t 11 pntej /vi n

-OO-

qf T5oa..^ Mso,

	kua—Mc6^er>4(~') S-fa-M *H"ki4 Lud(i/ PU /I Z

JH2cl

J-X

n f

ndi^j cm fS	proper /m • 			

	f Q-(^\	A ^

7 C/l n (i

l.*S2Q—Tt f Al n-k ^ppr\A CXjJ

VC&O

	i	

7-QQ4,.	=^A-

ArWAJZx

- "W - \ev:o-Wrf . K]p
^ ^ i H er -VWi-b 44v^

hxcf siC	,M22/

Idpck

M{ ¦	3na~i.*s<-)-&¦

,^Q.

i^sn ~n r Ki 1c"j— Hn ric mx-f- r./^A

TLt A5 ba(\C n-|- Oxa"	4o

'^1	V ^ Y\



On	V"5 3^ ^ uOVi^aX, PL lor^c £ 4m<4 ^hccF

L-co...d	\ jj-Pci- K^g s\c^n,f

Vcaam- on Ho ^	X4 (S rto^Q

-------
! 32

—jp,}	LLppzC Cc-bxfak/a Joivff

D 3 C 0 _ ^

6=	u-i& <££>*-

I.U50	c r>[\p c-ff-S

>£laf4- \nrro4nOr^'i4~	pfyf n ppgAA^f^ gXfuj:-

^.pii r^s; LQ-01 U<*; Ars^Mu.gp,

\ofa y^or n -b tv^-ki

	DQq

1 "7 nth TlLt A.'b nurr^\bt^ p

I; r--

	-	 AY^	

/\

&X x





' f -¦ ' _ 0;;

: / " ' '	 -'••• •" •--':

!-;';-v5 / __ .: ?

Sf;S • • - • /

fe ¦ ' /

ft-"- ' /



i

£•;' ' /

?£i		—J 	

" %¦'•*;• - : • - --' 1
'	---	:—¦—,. . ,.;"	

•

__^4-



-* -4i S&jyX1*

-------
0301

—^IU/oi		:			

Q130	Ytl	tOtUS T ( htO') np -h-	La \lI [/ fXJ~\CjA -	

	SVrxJA r.XO -Vn	^ pf/lfYwf-*- Yoej T .JrH 44j^	C'AjlSJ-

(9goo	Wd Ifixuv-? jfir^e/l /OWiirrvN j/u S\f n)hc, fn

Lfixdi UUl) wune.

j 0 ?SD		"txO	gA/\ AhL 	^.Qrxc\	WL\ll	fVLwu>

?) ruiiK ^ I sKa-C4j LOri,-rV fl)r)L fv\ e Zt? fd~. /ihn gn f		

0.fj\"ts	C' ^ ^ ^p-Q\*^0 	N*VW^&_ o^K-A"b->	(XA..JL.	*5>|Ci-A.eft ri	cA^3" dAjvrvPj

Anari boWW_ udel/yW fCiciL n,n h i IKjfj* hpJ(f).<



y^On{4. Cf	Slah^pAiMrtdr- U ~)noJ -hrr*~ rlsJxJ r

h illside	,4-pppfl/tS -fn an offidu {possj £>(<-{) pf tenxd buj/d^

q-paw

iQCjQ^ {,?$	fnibrW nf	/ +4-f&+-'*' lltisi ML

 #c^'ia7.r"

innji inuvm.m

u

414'. t-\ %~to -P4-.

O3J0—M? sosKfUo of tAXbM-ju ,AocJ(- collected, lA^aizk rvcJc- (S

<^oa tad 4Ajnl^ fNM^ nrthAJx L ^ }f ^ -¦ Q ** fSA*

.j>Jnm)*/L . Y/ . tAyjbpk. mrJc. -fn	.	(^jXAAfA. UntLtA

ulanksu	\rf.			;			

cD^I ^ Pnmn ¦ n cL'4- *1	\o - \CO 411 sba-Pte * fxcU4;s riogp^r i>o/'4h Ux-i- -fri/ndkj	^

an beS . TK-fl^	Se-rv ^	4-K^ M i n 2000.	

m'	/

^]|





Jlo'



fsW'.ct-

-------
34

ylOs)o\

Gp/X-V CuLuJX'h-ic;^ t-XMtfi-

03

n p

w C

~£D3J>r

¦) r- TT
•LLiOv	iA

r>/,

^ w	>J & 'J £. "f?j

_(A2j

-r /D nn Tu-f -
tAn^l'/x^r /S InloehA r*S" pTOSperf-1' rh\ 4-kji h)pO Map.

nrn

H>'\ " ¦

¦3

rx ^i; no- -4-hn4-	p/\p rp/r4~ 1 ")	DaqTU^"-

(YI60 GP?> rxXt0 m (tod. rrv\ i^SrpnA ^03 Ma sijn.f n-C
4^0- pA^psr*-. f5 fbrtfLlX fr\ti>Aa^triOA. S^rLf#
	q£	fOQ-c^	cv^j? , -M^ulClxj	-frnfs/yi~efk,	

lim I -P=h Ttint -	CfrKfjjng-hss rvuu-	

yv)o) i i/wr *¦ i I	!	I A— r~*. . I/I\^	UJ,	[/ u t-yi^ii/i^ « ¦	

H-k. fifiiN.A ^ikm ijjj-TIL -Wifl/I Iruyin/-. n<-^ri^r

•il.	A 00.	0 J	

rso _r..j.../ '-m	qy^q'^o./V

	lO i

	-~Utv-i ¦•	1.	.

/0.V) OSRS rnfUr*f-.pp/

I	. I	A	I



	\poft I 111"

^P^aI w f-,P^ =gjJ-n-ip')	

hw h) Km hacJt dc/iA>n jri r ha.

/OHO Hlf "DLO (i7avK . ok\ ^.n 0 .

12 Zd	T>(Q <1+ WoaQf. U^o ,	1 v*.ocia4c (Qck~ p' U

cur\&.	1	*5hf,pl L>Pr	CXc	^ ftcJc unAc..

c^(Aon is \	P\\-e. IQqJj ^

* \J8&trk
C> -ogpp^X loO Lid

l??S (3v5 cp\\/.rVe rfa

["A	——

-------
u

2% lev

LoU

)	c~—	030 30J - (

'O'Or-jC

_jZL

^/0 -fll*TXO Arriyj-c

tA.JtnjL . 2nsUh

piwU'd iv

no\

j \ r\

Pile

nt0'n . fi~c^-|-^ 1 Kg<^ \ p]\p . a ppTOK l(Y)i[ci5-	



|Q ^A. a lOijfl X- \ fi^V~Wu.f/iL

ISS	(? PS fpi/ert-ed. non^ 1^	LnJ'

^ in\gr*tf.(*3o-&-.



\aJ$

-------
36

1/ \i-rSi_

^ppA ( pi UiViip/4, (Cp/t jl

Ol-Qc

J=Lt

0304

I3Q5 (apt- I±nrL }Ciix £luvoi CaooX

430 11c t ]v,) n

djU\K.

~t lorrx4-i(7Yu- CA^Plomg (XcoJC

jSfci,

-fa cnf/de^: -z=>cLMsi O"^	

	 I^oshrncjiy\.r ffjH, yt+ XxO sL£CWL+ ^j.pp(A caam)l>	

—X^f c\{y <; nn+ a ppon^ 4haf H\ sac ,( sn r% t y 1 <4(Pum 4>Au

fybuft UiAKxkim^ide , J .»rctiechJ dJ bMm f£-4ht h.'fl

(lOashUvfr^ I git :

: n v.az1 an. 8UT" Mr. 3oiz ». 61U -W «>

CD.

jYvio-f hill - pg/a/- b-a^L^t. -kJVg- rjmsing

^jry)t Qfpq l\ ^ yO-.

;c:;5 .i :•

;y>y^

IcEiftsr



-------
0305



ecology and
environment, inc

International Specialists in the Environment







¦m ; y *

J- *



Number , ftl-fta-nr>ax

\l Oi>Ui/Yvbi-fr . ¦ftixrft' /hint %



ftAfi fioAfi DwiUc. TouMw.S

	••• • ^ •--* ;<¦ ¦ 		#|g|

>vfA;-

-------
I



\A^pdr		0306 fri-^nOcSy

ufaMi- Uorn- clv m Mad ^ mi>y -H h^mx, ^amplo,h. ir?

J „ 1 lS> - 1 ft .u \	1 > \	~ » i . *

iLtkyuS	n1AuU\ lVulJ 1/ "fx-.	IcCtLyxL

hi s Qffh.-

"U

firutsnQkiJlJL



>ni

PiT)- LP flan^iA Oullc^/i/vf Keads;W^ mo^P

im 1 ruxu

TOv ii) amtfts at	M n/m> ax „	 up/iafin*^

Q fXd . %ChoAiih r\o -frflmSf

,a - i- .: • ' .	-It ft

fl/\d ft)ft ajtv-b^Vn^	£J\3/l/vflTY

h5U J htftd WiL-fc MmiacuL^ r&iWtf 0ddjh6W$

&i. ftU)sfonj uL^p

y* A il w\'* iW. -Maa^	i .lj»=-r '- . r-	. W. *¦

aaj

gA^ tniUs 4W	' a v/'&ifivf, ^ cru/>^

"	CkftAfc>-	t; ./•;, ,.-	,,, . -f ^\Tr ' y

" fllDT)? \.n cm nod . nmirA-x rifldJtt&dL M;7ta/g5^'

pif.hbi* frnril Y^'::rgrafrfrr

$r >-
,:V





fX/Yl \Pftl , .JITfe w.	mO U1

b&fMity^LfiA Stdivwjyw- coLrnpioA ^

Er"\ mhi CjoUujf

nr>i^«L. \at\ i I Qfli i C(t ^

(Mm CrtiV -stMM	^ ^dl^Qyvi home	

Q- \xpXJ?frg^		

jftyffQd prt&tidfisis. \	. *$Ms\ %\Us'&££

v^$V V-niv^ a rsMtW* -fc>r ^Yi )

JfVVi ajl



Cf)W#. \av qqii

IL

o}1>P:-		YfiCOi

i2g_

-j •=
\

s ?t'

-------


I(hfai/vdiU- EW*	if/;?4

-S-

-rr~

J-

.;



; Site Name:, »X*
_t Date: (J/3H/0j Job No:

SSIDNo:

Proposed Wortt:	rtAni.iMfijs

i	.,

(VA Mb ¦ ;"¦ - 			5

Laft/Start •.

ujd2>m^A3



| All activities charged to a job while in the field (e.g.
j off-site activity) must be recorded in log book.





—

fWp*'h§4oXi o%.



.irftgn- cp< ty

TW -\iiun

4*

-• <

S&OH



t- '



-------
(p/ai/cn





IcpH !rf\- \Q?^ - UP failed VQJv^O\uiiL< and
			W- \~/A3, m\jo'^D,f\A^ \D \3	juk

ftV -VW. \w_ok > Ytst^nn/A^

ioAn/a\ - (olZfflfti

- loyv \r> ra^d, m^u-o^ Tnmjp ay\ W cuu pwvf

		£)°|5-5^^ (xrvpi ki4 a, mfli&guy. 9ft7avr^

\£ /M ~~krtKr^vv- \s

\£0Uigj Tfr ^7LL\
j ^-VWi fir VrrV Y\ooriort .

"VW

UA£i^_

-lSl3r	l^;T\UpD Ko^y\j "hs\xyi^ (Y^frUju^s, fitJLtes-

-IMiSr	A-(fl/w- miMvfx . i*> \f\\ttaWji fttJLk Ad- vW^	iftvnki

		"X.Ppim UnA^njk	nmVex ri/yj





A/vx^|i ixO/i^tAP W-	pjjyj :

4 if	V.fir) ziA/i, Mi/i rWiw) (k^/u&th

n ¦VyNrdA	^ '¦ ^~l - VVwsU 0	-



- HO A- Qi^va Vra- Pa ~rle m&kJP.

^AAv^o .' tVYinftho/

JAfrS-

\ - nrtloCftfi) - nlQbM^O

&

-TnflMQ- DIQIoM^hl - Q\3bM ?m



m.

PaA-t-i^rnftffl M - 013 (pH H 01 - (*>1 a( nL



Tnc Sfimpb.fe-far ton-fr 4ffl/y) M(feD530- OlQSr^d'

Or nAri A3e•• --•"*«•	ffi

\^HST- A5v|wo6 oumw. nJt YV\t^r J?.

Ml 4eanag> \ooddh7u	W l^sfovCI

liYtftm t\i o "IAN mluVx^-^iWrYito,

I"'

I:

l:

If
I

I

I	•••" •

II

-------
jLCvi:

Mi ;:-HL

{juffk/ (j<\kUWA^ tins

0309

U/WM/'U-1 i



_hi2 Al^

Mioa^W

y^r\aj>

iki.

A-

<7

tibx&Alj CjALcstTrM

CiJXCk KS rijj^ 'X-^ £vi\Vk^'--W.	t^rlJiV<- ••

VCrKuyuAs m*jm riuc.^ -V\vw,	A^\i

CU-rVf m

^ rt^nmPAJr. 1-foM iTTluV3> riVi- Hfo.

SiaJcfk, i>vu^ lsVL\ dnVL 1v> \n/)iih> \
^Vinsui^ ^\!fYhCj6\iS\hy hyti 4ft?/H ff&rJtf/L

A /» i— "T~*.!/¦*.* 0 lrt/> v

iJ>\^ 'faforto/iL %xjypi/pi^\\^j(fi .~Thr\o\ Yvu>

do^iL io W v!a/\ Shw, k')AL ^ SWW
i^L ..m&ns wprfb.	jfl/vipuy yidod4o

W.-A'ri. S?din\g/vf sq/^a Cd.it/-j3cL Qfr \/fln fev/

be OWid, \dimf\~r $&jrj)t,L

f>UAjL	ttdr PiXXlftidL Tftf, ^rtyyiiLk TVfc: ftrf >

^Vam U)fjf, nri- axon*, in nrtitsj ^ampiL:
Mto/ Iwftktifc, 4Wa, MiW s^iTKM^ aJavq ^ ^t/Mi i^lJjL
fow W^.io. "WJP OAdLTnuTi Vi/amter t nt/aL rvtft W,*fo ^ ba/i^v Vla/\9tet nr- VW ^vt-jL \^Vtw, ^dimp/wz Lrfre, r^MrteaL/tcH



vf/Sfrod	nyii,Yi^jAA-

SfluT^iLA I.tiu h>, n/Kliyt/l;^ TBI . Ckrikk. Ocrt/Prfc.

fxnd Ttr

ID-ia 
-------
-------


/>V>S

1 A z* <--•

\ijflf Ct^U/Kht.^ ^liT/

0311

U IcJ^ /u

"rmm/ ir

'ivIa Uo NfX >/'r\frO\x

!. C

I \

fl*EA Y^;

jj-iM ; ¦"

J_Ri.

WiVj- 'xVVj ts-

lk5i AJs ( ''.\-

s<.y\ii? A/id SU.

U\; -l&jti CAst/" fV^-x-ia#ir\j ft AO 'iulKAJ -fr>> 'ftr: Tcvnnxts
h~MS~ #11 •Afa.ms il/vIC fef 'fey OrtJli IVu^ Qfsd^mir	

DoAftL. CredW*W1J<)^\

JD&

uf /h-



	uQ&'jd.	>:&*-	f). ft':Vii>€>; [)A. Si'V.V l-i) UfifJ-

CtoV fwikkm ahto 91 mftivu /^rts\iWi>

•'"Era

rft.lji-v	Q-ftW

I ¦ I H- > w WW - **- »	' " *"w" n		—-- ¦»»*» 		i_j	- —	« ¦ . —

fkAT	IAnIj.- m /;yr?df,^ iyikidr

fk^.	f)w

ik

n. fKyiii/)/ aM	Vzu.O Ku -j

"Alik^4i	/!nZl mill. Lii/Mfi inni^s

ftP/ywj-t foflw c(t\nfys' \& *V( ^ Jr

vypnM/i iii-

Qtmi



\a \-\wu±? Vb \OL YfAM,OL4

Courts %	4- £ ^

^ ^ »A-

ng frW

\fi\fe/i b'hxW*	^ ; ^

(i/Aimki	toK nuuu	ax c-i4£.

"•>j'	^ r>-	w	* ¦	¦ ¦ ¦— *	t, t	*¦ ~

ftW.. m^lx-hTi4a gv^SS OS.

-f-
or

0*6 u Uvf ln.Al/.

Oon

A fiii	t!A, p>v>p/> \yM fQ OiUV riA^i
V\§.a4 ^ CAv.sit jjV-i

lu^r Aw. -^i	y^cp





4e&m nsois jt>



-------
8

1444^:

( ' f" U 1 / *,N-

L' l i./U l\ Js?\ ? i. \> *

0^ « r*

^ 4-';f*-r-,3~uQ.r

[p/^N/dl

\ ,0 f..vT

n \

vx,* l:

p®&



'Z- r"
J?. A\V



I^N



xOax-X\ Wn.-isiSw, Toa/n un

LLL



3 ,SS Iru lings d/zurng^. iTTuto rtAO*>-

'W^AtvCa. 6Yv£,

u)i)l cqtt^

%ogji(Vf.	\aAVms ^-Usn±#<^-

^ xR9 1,-^1/'

nck/d At a/"	\ bS ifa ti Ayr ASU^

/*/-^ „ „ _ 1	-1— ' ¦'— " .~J, . I sr^

o^Al

ss -to i UfU J ilOiP. curruMjua ^i/v^ cA °rV« sda
T.ftMfl CSfthftrnfm^b ftrtUiHh OUYv^IflS'-frtyYv, -biili/l^

KiiWun

(XML

KS (yApa -\(K^Aeh	) o uYx^'v^^.jri

arkcL aMlfiVYXQj SampLm rtAqv-Pta^yif	Hp111 fvarKo

TP* a	1 .	0 ^ 	__^_Z

' 10S^-"To/1ia hmfe "b If ^3-

A\\»faj>n>:<

*< v'-a



JL

un to i>t/

W tw>

4d3=



	(JlUA riLA/i (VaUfl (Y\aAL	"foam am/rA'ia/fol ^

		\vus  \bCalCi . 'ST&r&iurL ok MlWmS nAd- fWJ-^rC <5mP. .

o	i

^rs«?ii

7^
—

Mft -fa)u

)uaa .?xy wr!a^>i % \ sttort tyav>
-fpy. \a'	u

- KW

.&&:' -;i.: .:;-Ar-. •

.-cl^ •	.' >•"

- mn- ao °iiq

rK '/!lr(t

JitlO Wifflfl-



-------
0313

i W-fc"

IjS/ Us uriU?'^- \v ^

iriv-'

>S7DS" fC\ PHiU^rs/V -t/jjiiAiK SS sampiiA. flVj ))tj^^5uyYv;^D-/

		Sei-. j.-V fosio fee? A, vo/^ho^m>v/'vff;,fTx/mb Uoa cmju^o/\^,

lofLl hi Vyiri!. f\s	AACfha/ ^ KoW'.k tOA- "to nftUJbC*-.



ft

¦s

Jfc-

-#¦-
i

iiu-

8j.

K) i^y <7^ orrV

LP i J o?) . Do*

ft1¥

UM$- W Qm^ fti TP3

" Davt- (Jbd^^G V>g^

3H

flrCl;^ -V&pflfr.

U?* """jWim

IMr \\mm^ vyzri-pd ydAAj, fonW\ Sroii
- Ml i rmfl AiKi n hi* \kso<.

gM

fops- \umsl ^3 i rncHw

£M

\93b- ID tfrrk& rd GrrXe OfY>kl ^ rm.k* yhavj.
133S- ID an-JiM ffd-fcx Qjod ^htdidLid (I

IOTP*

Ci/cAi, \YM -W- loldh/nl
LP QUM, UUjutl.

mi/nbi/ 5?.

[fl/01. VvfJ^iJLp
a\\i otDlo - n

52z



ahiub -fe oMhcwJ} ?foumd Kxr-fw.. m&?

OrtJerfiJ Otf \hfl Sfrm OUajl IttHrcuUiVp.

ferua t*> s/-« ^ ftwifoflator OflA, toiylJLi A: -:sti

\cyA >a/VL IjJ\U eUjU flUAt LP uitM ff^-: \0ir^tw:
'ikt^sflu irvwerm^ prt fiEfo'to foi/c.	^

4k  rjrUi^ 'Aa.!/**

>, M, f\5



/d dm
-------
firm

Mmo:

liii/BOult

\hfsfjir C?\hifi)oLa~ 'feArc/-

0314

Os-tj.D-giCiS§>

l*3?x*>- UmrT, CkihaWs r&JULfraL lO /^.StZLhrgL iOWl£/l£*k.

r'

A J

f\J

l-l



-b "teuc4. j/iMw

<\\i¥hx>-

p&ir/f03s for	Z"(j\J) aA \ k/\ .Sltfr£-,

blkrtu LsUi OalJL UP YWk, XtoJCOL

\b n>v rm£U -fc 

ulUJ fa. pblc ih sflup fli J"/W Df	

"-VW yrftlb. \Qnr& . AcodLs -fc»

01 is OhojQAL. \4-	vk Cfc

M£&

fWvm e

JSkA,

QfVXVv£^-j	rtSOt ofi^	1 j	j_

lAdOifjuD Quas,. iD 3fafaJ w> sampU^

liAlJ bL CMkdod ajh 4ft Aiy fti j . a4-
focoMflPia AnLai.	^

\gjuLrti CoaforMt	and IaH-

QflJ 1 Kor

—M(V in OatkodL\otisZL CjL&h\\iO{\j ta-rvuM^

ftqtisy\i U) usui pah. bt/lr, raftiTi
"MS- \ Jp Vk > lnjl 5^Xtf	fvv- (y/Hx|^v9-

^rtvfiA^ >flEJrVttnc

wfovwfrW

\ -4 I fl Vl A _ -J - /V A —I \k «

»*V	UMQ IHL

(UiniaEA fir Qfltfaflf*

:\M30 IP OQllodb fy\fvutA. TarmP A4 Mk ftjrfJLi

¦>ft CtMIW MJ W44- W ft,. IMfeflftKh CoJLL. LP

Wv.mivi -W* "fcHte. ¥Wh|?nfr

Simiii-jr/ Vto ba/1 /kAitdu





-------


...Gb.l/2 -



- jHHO- todLj

ILppff ('i-iurrihA^ Cuvc

0315

-Li

C |7J 10 cL Lf) g.rxd -fa tt&Z* g bK\ rt-

ruWm	c£.fYi\i(3 c^ Qf\/foC:cMk

\H4lp

Q/*m

\f> ?ftn-hiCi -fo coiu QfXswiro^ To^vci r/l-VW (VVMl-o
Co/vf\\4 W and cyu^ Vu/^ 4Vo. f\i>AJc£^-
LjO ra Hod. , \ qul/z^ (\*W\i\I flifYL \ teiva;
fey\A^<-c U3cv^& ft/V)l4iw^ \c. a_ A,je>\c>-i<: ^~tY7^hd.

V-e.prsW \n ?Vm\ \\ U-k W i^AjChcx^- f)tfrrv'kinAe
Alerts \	J1 ai L>^ Ac fldg> 1	^ viral LiQ

tM> nds \ COp^v Add^<,-VW, ^ruprv^- -to

Sfl m^vU Cu sTvtti&y	IjiusT^ flwkyYL fifty

c>5vw_ sa/v^ja ^Vuf&tL jg# "TVUAi^bit ij^rf /.
•\dLA-i>is^d AA uyiMi,, \X) sfrrtbJ "

.	^ .. ¦•	-r.

ix^iirtL r\Tj^ ^4lLi)i

rN a >1 VAa aAt *^4* « .• i .aI A \^Ui i rL.A^s/j /) A :lf\43k A> J(va . /I..

nLA^ -Wxftdfr "-VW^ urilJ Vy. \rioiatSf\Pd mo avt;

					¦¦¦ ^ .'v'"-' ;¦ -

- ISE9- fWiA VkjEWhjy CdJlIaiL AjC) (\AA \*& YVoi^Qy -Hs
>oW Vuyv^TOuaiL

- \SfrV LP Co, Hj dU AyvJ

r^—

UftD W

/1A^L>

T>mvx	pYvrcu- fodi> hMimtkM

&Daji. n/Ul^ l^fl A , AM,

y^jyO -^Va i7v> jt>YUj?0^

ay.

-ffilV LP (W W

-1U)00-1jQ tftu/mdL-fo m&D am caviid rv&^?^&4to%fl/n
- \U>ntS- PfWiia Wd Mil lo^Jfama^ vM/vpcl&t. :'•;

SO (w \Jan Shsw. fthAi, iihf. aJx>

\tJr l£> V/)uJ Aw fori
Wca ^ Vul tiorik Pmtu^

PA.- frf's	U)^J\JLP (&U

4ki 4jmh M t>ark. -h> W4 W

uvif^ Mikrih) (& X^r)Lm\ \r\

flywit ft rxAd WStfW W^.M

to

		—wwi-

WW

3®«3gf«S5'V

-------
12

<" ( tAii\2ivf /!_

0316 v

.iGHia-an^

(C'P^lD) ~fMD \y95- c\rr in fWfaj 1 at -falls "i>\ ftMri Ofjlk

rmtmiu, pxrup/catYu M/kpiiA

±DM

fjw. i^tou-tTiy^ toftrti/i-

djk£jtt

W mC/ma a/vtM^ rnxOs,

fftwvu/Q. InAiJ mUiLd ajO AM	ftkir3,

^raii'jL^ ldVHv,	%moi4€^ Arft- lwv*-

£*•£. o?v Vvis p^pe^j. ifXt-Frtaui/ vfrfttra^



i/3(3Jjh—S4



gp^iS /Tiao

QVuVW jy><	ViMA_ bA -7#-* 5' -

\\m14-K , fflisyuyri^ usufl o/xflp y~ /1---
Sgfl, {-f gL

^uSAifKfcm	^r>

\ VL 4W.	0* " " ^	~:"J

nc£- {\msiA, caunL LP ofd(SfaMrt
aWnaAjfi y\ i P m# Qtf )t^rM3 wHV



:^,^: is «\i=t- rvfc

	Vywis	-tkM mrf ftf u/lU..

_	aecfj^s svhvflm ¦ a#vM- ;) LP Vaso |/"

	^	!yyk)	\k^4fli$A,'	—;—		

' H\Q- fM )	QM^ M/ V.nd- mfki fwLb^a,	

		Kiu^fiQjCJuLA^ s^/v^ay n/i^f. irirsfcr^j

lA ffAflt

:	>km. n/nvt-^ A-i- nfmk



sfcv;

^h^jOMMsrf l>&

p.R3Qr	^

-p|fl*Q (YVnO-te. Tmii .j^.

	¦•* CJdildL^d fV^AJL. VVVbAAyft- UiM ^4ir

::; a^Otfatefo* hMjfJis dJewX Addj-hS^ih



-------
pi-oa-poas

0317

Upp/ f'tfUirrv>y^ UX\sT/~	.	Ijl

WMm

. mgYu^ TfflrxoJp QAilcd j

:\oqQ6\' (Kiajl, uyi'-vl.- fharm^,

i'/^-fo -faQi^ it) Ph)	rn iyip,^ ho. uiV1ki?G

Sk^rAs a/v^'-ttv, am-tiafc oc itifohTisf&s.
\ fi \,<\U .ffosyrrt>U>rihi ru Sflyftpfa* (ij-4i&£iA(tj		

titctiJ p. nxuu. U)Wu ^ht nxd , pt 'VP aarL.M:tLrfim
aa/JL 9L:> utfU AyfehrujuL-	nVti^j

m VQ y\l:l )r#w\ £&»r

Mjm \^s\SJ fe

... .... .:" ., • ••••,. , ¦' '

USTCSUI

and,

\^$rid Of^Ci x ^		^}:

YD ffi-mm;is C6- )Q.			

]M ^> fo.f , fe/ii

oaa'TV/ iM)

'-.. ....,C '

-------
14

iwaWDl

	fyUirnhi^ OjW— 0318	£ArQ2lX^l_

Srt* Nome;.

-U£=El.

Date: 1 ulQlfj/nl Job No;
.Proposed Work; rVUAt.

location: U)Pr
		SSID No:	

|Shipp{^d camptiK

Weather;

Teem & Dutiee: PHUl. 10ft . ftlV SforrinflM W^»r*S
4	Pir- Yx-y74-4tasin

POf\d Olrf ilAjf CfSjJSjL^ (Uu ffif ~ smif> ^/xpti?a
! Instrument Calibration: (iPS , \llpVspSj /irSyaftiOf^ H^h^X

- Other Partlee onsite: fh*£-	j - ftifuJ CVrfilV fWj.

Safety Meeting: Time:



( Content:	IK ; W

j	Y)ttt\} -\\rtA ft, in liift/k ¦ Wild		

-J-Won-i & E Attendees: T>L, lift . AlS

Time (24-hr oloek):
Left Hotel
On-elte

Itinoli

Returned to Hotel

Left/Start

cms:

Airive/End

.All Activities charged to a job while in the field (e.g.
.off-site activity) must be recorded in log book.

h aMQsUid. ^/H- rto&mM& (kZtitkntLdrft)

aim

- \W Avocdtrs

Or

bin	j

Qd tetta MttPfr

D^O

TiM f\-\ tltO fihrt !Xl

AjtL, t	(L/Y\vf	jO	£>f

caw*

!

•Cr;^V«V!tt v"
'• » * . -¦•-• ¦«»(",

;¦.. ^SWSiMe "

-------
::0^-or^2.

Uffit/ CtA-i i mhn (i M/

0319



oAH- 0<^- If) OAd ftvriu WiWiM fuW (M -fortl O^Jif OUap,:
		fr\cM (W,	lA r\t»As

(\Ad	QAd

LP cvu-r, (%/&&m£YY

c^ mm tu

3l*JU

UJ Ov'



Js

jdbL--^r> AcCoisaM ~fo pbdr i n \, Y 

1- j-ClH^Qi^M	UVPlO nf .cmftV^ raop^.

V, Mi

^ ¦ 9piv. iVliMm			—	*¦ ---w-; .-..

- ct^-.r^MU - Cfiv Mu) \y & \1,p.u^M ?smRjfi  r-KYviiijCjkri. m ftvija

SdP SOMorl^ilid -fc bo H-mtsvft/U



iQ-r AU	phttfr6 n4 ;.r|

¦&iy:%•

f h.ynv " .,
f. W\lt>-

±B

- '• = • ' ¦ 11	" "¦' S-

ia.

. A i



¦%\£m

jj^airtLr^ ftfoi^^Uwvy	fo£g

fond Orn\k, flu A£i.

¦¦¦-ivg,«

pgOD- MTTY.n/vsvn* a& ?s/\d Oro\ie .



-TMm aJ ^\i% pi..	VtiiflJji-r* gPSflaVsO

5^41 -ftysfttsk ob -fouli m> &U. *M. -.-^'

#)IK ftf





MfcV") - cam, o./S. p^.tiumW ,mu> rA-Vu



-gnwtj rswl.^ura^ CtAJt^ 'fr jk

	

Pkfo HP - t*»~) fry b>f uo

...1/ r-1 •

?•••*.

•I

#1

-J-

i--' ¦	*.V... / .' 
-------
16

H |.S" f > bu\.o
	\- lU Dtv" Sr . Wia iT)

LppPr



£>*-V
ft

H

c^3Q

M

CM" hi

LD_

J2fl3t±

H") 0i/"5 Wa.

ftolL YfyrrtYiA ,fiv. sampio; iortk^ Wxrf Q \rA\co^ (TTYi\pi^KV ? mkd	cur^ Vm m>/)

HAi in d Aia. dj-u-.m	izu\iVy piSft/i * \. \ki^

hou.-f, rphteA wsd ok

qWa V\o^ tx'-AinUi^ mMsuir&M H.S

fVr

Tifl/n tt/nvre 04- PrfeftQ&O. ptt b-1

i«5Vwt\ fts

^Wv" rti

-to osiMIms -Wr*A.<.Wj^

a» irxfrb 4V Pe/v^ Cvtikxc giver.

kW lyuio/vc \tr\^ oV yjcmfris 'k? Sa \4- %Q

"¦	II	• ¦^¦^—¦	» ¦"'¦ ^	. — ¦¦¦¦¦-¦ *	— —¦		-	r	»¦- .......

sa/hfU \S vmjuty.Tfc cmforvjdL* to	,SDfr

dJ8tru\/iL oV	^ .\ huAjl - no — - -l -

Y«tyi juries rtittf4edsQQTl/

SCUhp^.

Q^f)lg-l{flL/n hoAfl jAc	Vtffy pjjg

-Ruxjufa^

OrtyA# /l/i-^Aj

W bft?/l he/v\8uC4t.

JfYU/Vii "* WfflYV—gUfl^ 0fr)(J2.^
Mr TotLm numsir^ at utiW, Kfk^ plU.. LP dui

/ipl jyfrtd ,

:-0f
-Jptfr

HniJ]
—Is?*r



'Phtjfts U* -CAW Biv-Mt. 
-------


[JLQpj/l	iMtimtoiu

¦/aw- f\m Vofc- m3 ^



M



'.I

msfo 5-1 - ioaM $w bu \ >o

fhsfo d-A -^5s- ftv 8u) tri^io

hi

MP 3'b -u~V3U pi/ M^ W lQ

a-H • '.csi Oiy io

11

3-5,&r Kfe

1(

~ Kffi 9>y MO yQ M&uc nf -boliL. ^kziyr)

esjjtM

1 ofrQiSS Tfch IdUjcr kurd*.

ilWS

10MQ:-ir5M'a>Vii!)0' of lew km<$ Ud

¦ -¦ ^ -'¦¦'¦¦' :-- ' ^ -
&%-: IfoMlrt)y\idhA I A- \Jtfibfet- 9siS$&cWslD-

%	uviaAi ;wyk: pLb

P.paM Qytj\k

J*

S?

3-\0 s- teMS - &iy- ^ \X>- U^in f* fagkpl1.rt&

	•¦•¦¦,' ,, j; . vw*n pj.b,. ' ¦ - •¦•"¦>.; • . ..f,- •_ .';*;

¦^W	(kky WA in' VJVio &S- Sii/faa. kkMt

MMM prm ha\t ftf nvisU, ny-ligj^:
*k PcjM >1hxU&, n^r.'	i ^

» V&o nfr una#.

o*ak tor

a/\aL -pripj-nf

,.-V

.¦;;,> •

'Wnrits 3-W\QSl>- CWf, \xa1D- \)wi^ r^ rim

ry^f# VVfc

m

mm

1''Ak%\Ttnti

1

:%;a

TT-^

.,Ai|V'' v ":

=S^Mm===

;"• H"..- *

is

-------
18

'M/piV	l-vli i A\J ji.i,	k-ilfC*;

wd?/ c-\	

. ^L^LQLz nl'S- grO C&KXjui, SggAfrx	¦

( 'i

0322

, , ^



JDOjC,

fltflr ^rktid up ~\W Rdfcx flfis-fr i.s

Shipped	-4-Kp iTu^ei'-

.U./7o ffwi KJ^5y\dlc<-^

-193D- ttiO^PL WflLf m^	yD

JM-DMLk

pysuAd

V'f »(N 1 /\A

\om%xr&jjn Storfr

oj\A YOAd rvfiLbiUtom-Hta, \D rxttids fo^LP

WUMACA . VhAjl# jp \r€V\fru W . QXi OaJ
IUmVsa u^. r,Must^^OM Wkysuud ^Uj

CcAd n ft/vd Sftrtfad a raJLt'
	ro^vxiL \ Ai\^ A-W *?PA M/ur&i' At./K>^x-

4c.ft/vn



K.-sjv\c4eH

-v*»



-Uft~ IS V-f

^ ^Tft±gr LP

^rrcAiJ ^Vc borJc X(a/r\ toe^ gpVj ^ Chojriu

	by.,)

fmy\A D . fcaiird -

' ':*'v

Ov*Jr

x-tvx^

-------
f::s

d2:0C98

±JXuIbJjA^

I o VT/

0323 LIC

. ''¦! i .• /i/rfi ~ IbflO- HAM TV (1uV\Vo r\-j- m5k.P

¦WS~ ^, e ir	OmV, AT fyyfl-cff (IM. h« ^ A ,, g ft*

doc.	. UP Prhr^WAxAj

iA^(W (ira^ gcarzl (xMMto-~VW. Y)Co^ 4tixm uh

mi/M .jl>C U>VH^-	Q&irti fxAd ^kd W-

Wr	y^WonvKp Aiam W-VV^ faiu^ a^//f

rm- -4W, Po/vd bw'UjL (Ltvtr	

UOftxlXstL iUn \VujjLftfo-&2?- IQISzlM nppYKPdL
?LUu 4kir 4^ fined- -fo/n chtdndl \k. -Wms mami ftt

ato -^Uj4 ^Vk, ftauAdayu tkm hMtHi rvC?

Ofik&A oftwir. "TW h-vi^JffnLm iai)\ O\o£k i n
«, .v' 	. ,o*.~ •-> .u. d	 .J- . r

JUrfyu mpyniyM tcftvtn nonf

- \XaiT-	n/il IW CAimV . aa vri^ n^-4k

JkzL

m

4fa/rts ,0/aeianfl	da&L iVtfe fivms IHl-kL

,	oaqL hfRt^riTTyis	vtAi/ia uM*u_ .fojiiftyM

"gm~ OiMo^					

- 913Q TjflM bacv.. pj WokJt			:	

		nvswka TftAti) OodlsuL. (k Pcupti ft(- jvry^ D

	c*s\tt TV f%ru(A, Ayyi (j\g,\teA lKAJ mos4- i D tsn

	AAd	fYuruJ^^

	CAJU ^ ^Wjx,	DadW OuAt. i^-riif

	4Vpft^	H -inblrMAA s&zwpli .	

\0 p ( flAl \fl , YYM Q. fluj I3; f	1*9

-------
2U

Tjjisl.



' J '' A/- >

0324

Sit# Name: Li C M

, Location: i'&y'n U li?
	SSID No:	

Date:	/0\ Job No:	

Proposed Work:  ^

Weather:	^Vl CU\ri n(t Sn/Xofi^

Teem & Duties: fi/U

1 n -*T\c- -sr^L

(¦¦ L-j 001 l\ \s.!n:v>n hvi-} 4? ,* *n

Instrument Calibration:

Other Parties on site:

Safety Meeting: Time:	Bv: (ZJVJ

Content: iSc .VjS / <*1X p , h-S p -fe I !<.

Non-E & E Attendees: TV--f ^

Time (24-hr dock):
Left Hotel
On-site
Lunch

Returned to Hotel

Left/Start

Arrive/End

All activities charged to a job while in the field (e.g.
off-site activity) must be recorded in log book.

-m*
-*»•-



d Sfi/OML C\^n\&+uS as*ic\nc, j tb fit

At-

m

fig&b- Afl	^ nn&\fc$. ~\W.



A QjiA \ct -Mm. so/wp^s

oq.frv ftrflcfr -UiXnn ieaur> -fP A

- - —				- — ~'i -'in *~r	»- »¦« ^	,

_iOiV (\3divA TK Wq\xi Vr, Ted os+

r	Wv..M ^ (u/rlirriofoP		

-—ytyc 		

-p"

4*

-------


od- %

IP/ i'rtiirr\irv. ^ i 0 jAnV

0325



U/20/c

fMv nvi. rvu:".- prtpQ/ifls cX\tr^A t\ 1\--, XYu^pjioL 1iyA2a

	~TV^ SO	rifl.iihr/cL	7Xn'>o phi ah. CKum	^

	nctdb V^. w -crt.UistooL^.TKc.	un'U W,	

PA us Tool bu toyidt- 4c a An -fW ^TYH , mo-frnl^ pafr/fifj
	QAflL, lt>C.	P&O photic \^51 QJ Mkf -fo taL	

W\.			

-	\\9Q- CX) j HUjJ ,T\L> s ^dcLhi		

	OsUcAkd n+^lrir) Stmvg. and PoaW Ov-fjuLi ftu^ .	

~ W5D- \?1M » lOA- head To fondle Ow -Vo

"TW -kam lAjii r/YOird- a, rk^J^r^wtzL ^ar^ph

_ ¦ r	r ¦ ¦» - i 1 M —	1^1,1 W	IT n ^Mg . 1

l/0q>ShTi \^U	m) taapk

iCMSUAd

tfbL

Qo/YipU -Wrv^vnx^ >T>*fo/' ^TDPieA Uu

-iixii^yu/ iviimiint^. " i [LJ	.-^ v AA^r^i ->	ujt nj	U»W	

sftupprtLxim Gjdfa totojA. I£> uriP t CaOQ lcUj^
Gu^tl; fA&r 4Jm. CDth& (W, p>/^ ^

U£-

aUi_	

lOWu\ -Wc, hrvidh -kojin \Qcu	\vULf1

pn'-pw, flu -VUo	"\^j V\ft^ Cfilu4id

W shiftnMA*

^uvplaa mo/t*--

- \*bOS"- V2-K) -* TO A qyv\v<^

WioH^

Up13- toj- 4&/n ft/vwta a*rwkl QA/i RrC uM^Vj^^Uv^

	bhr>^	-W\V ^	-'-

- nvs -TV . CM AJ omvf . cdr

-fi\5YV\ iTVu^v VfyrtS

\13o-

\>0 Qodxnd^ CYULTk^ CifluL^ssn	^TIm- fV\Qi7iJliAu

U^^-v-Spaaip^ Oppv
r^gfrgyirc- ^mLp>UAA lirv^sn
r. 0lQi^5^

^rprik^ LoyH^ YVo^

xAoj^rrkii^c
X^iAi 0.^Sfii

o/vA ho.



mi
W

^l^Ll

£

\0Cqi^vSV\ 

-------
1



131/0)

XLpfkY CpUi/n&u

0326

a^L

isl3-i/o)- div) ri/rfv^. tft OnKu miry. Qj\d, i rb^fitcL

U/-<

i MiAiL OjK£Jl&> ¦ fo*bru ode A. ^ir-iv'iW nu/U-.

Kfi\ \S	-fTdii A5 Da/'ii.tD

JW

Ja/vJecJll

ms-0\MW

{£) Y^l PlU) 19, Cir l^/( QfUj) )'7^/ fK$£f\yr\ \Q

-------
• ?>-¦

to)- &3* TOfi

0327

PfiljioJbiiL OlVff/^	 fi?/3ft/0l

23

Site Name; UC&

. Location: r>vWt\ A,1 >Aoy\ LV.A

SSID No:

Date: tDlrdfs/C) I Job No:

Proposed Work: Vm4 Una* rtillef*
b^kOYfwv^ c.r>A\pl«-K w\ SWa\V^uA1^	

Weather Cfc) "foPfe. . *>00 4Jf h* ,i WVfryyS
Team & Dutiea: flJ&J i	Cfe" i '"HCt f&O

10 iV	rWlO-KrOA 	

Instrument Calibration:	lPJ^ . \V3,	^"$^2 ¦

		' J 0

Other Parties on slta:

Safety Meeting: Time: rOt?O By: SAJ

Content: ^\<\X<&\ T\\'l S)\<^r^>

Non-E & E Attendees: IVA >TlL

Time (24-hr elock):

Left Hotel
On-site
_| Lunch
I Returned to Hotel

Left/Start

QlcMS"

Arrive/End

All activities charged to a job while in the field (e.g.
off-site activity) must be recorded in log book. .

J) Ot/vivul,		

ASiro- litaftfin am«(L (inL cm* umvU. m	/nA

-LftTg 0MTRV~ Tb Arfoo Wm frwi 		

^	ftnnrf 4fa/n<;	PvMli** fowl OhmUi (Urf^SQ
-------
24

i«mo\

-

vy.f-£v {



U-pp^ CHunMou , (?wt£	Ai-AO-zvOfrgog

a Ad

'^PiSVKV g/flt 4tuO ncUs<*FiC >Q >a. <^-y

-—T •. ..• .. : •; a . - .*. .

uin/o\- \H.

2m-

r~—~~ 4

yg/UVr y\^ fUmi pk o4 lOCtffr.

U)k\Kx \oc^ LoaXigAfl stored "tA."

• /"N *	. . t »	m n—* r j-v	^ »

Oru-Y.^	kP.	uxxs

1|5S"

HrW	t vi yuAz*. mVrVh&J-

M^C^uc^ or ft_ V\x/v\sisvn
jflfrUf f ¦ frUflcl CQ£

WfeaL.kXbk^_

	£±H	

*/>• 115h	ft h Mt

cii£££jtc c^iiAkjng tia£?

	lifac O^A" "Wu 	

)\S$ phok&-}& ^ *-P	

i 0*~\ «>•

d{rUM(ry\ '• 'SouH' Wifc				•

C\osry^4y fe-9
	» tooftu-eMig i4 I'mhyi CrceK

vaos	i% Nt>o

dlrerfinn • 5QutiruttJr

-wt>

uiaAy	y^/1	

Vfoft) - \i)i WCftAd IkMwn

	-OrtL^ fc> CjW> ftw VA

AuO w?Vc\

-------
IF%"

E.

I;

m-

r-i- r\^>'!v/)OS

iv rV-\;.iA^bw

(Iwt-"" AQOo ' b>3$Afi

¦' , iO $ - : -

- \ .'*• ; V -y • /. ^ •.'-•• •-• ." • -s i- /-

\J \J • n '.-



L¦"'1 ¦ i "•" '¦ .'^V.\ ^ ¦¦"•' 1

. A;^ ;; - if)



-Ss- N r' ; VN A --~~T , f Ji- C '« -- •-'*1 / •

\ v- : •, . J 's-'-. 1 .' frC

..¦ SrX/VoOi^ A Lt \x. "•

N- ' ' -1

^ l'U'.yy>''' t —• . "

1 ' c,... „, . .

I	Kt.KU, Or J

£jig-	Oor) )

ftvwjL iQyyj-i ;)C^- fooV \ igi?>

{'f) i-i!l /u . iVu.y y. ' /D a - (51 U'M - ai *Q

VflnrtL.. ^41 d ¦ .\X- y^mp'ws fl/r. -rfh; ^ . /w_p

fA^d;)M m.Vj "'A y <\i j MiVyv' Cki\(X \d hiVfljC-

rfnvi-TA ,4W,

_U?_	uMK. n't r.;\1	isa P',,i/u^

Mr'V^W

(a %?..o o^bpN;, r-)cfi\< '. i%rV

_&a.

	Vac^rLLuu. ric^y^uir. s1s\aj(laj [jMts nxtnJcz..

		. aniL Efjrv? -<¦-/ rv^ttonjCc	h/tjao C^Jc.

- herd kfif^ bi:^ Qr C(-rM ¦'.' IT ¦t.Ui -W .VSV)

n"J '-VuiL if Tin 4Tii/^ .

I "V ,

pK-'v~. r'JC



•:>,aJ SQjrQljl

U-.c^W, rir/-u.j^/\jt:4 -\

Li	T;'

/s -U-'; /¦¦. f'AiDrtr

fri-*'	tetoAr .	;., U rr&r.v. .iV, in4rv vUws>

, i: > ¦-( A i /M i (uAVU?/

'V' j- 	r- A 4'V\:ijT:





^ A.-l

IS

0 ¦.';DwVva^ f^Y^V

JLL



JL^





VVjtv?Xu up^rr^-! i/iv^ orv- nvLmurir i,.yv-UV c

T•

JT



" i")Co \Y^ fijvo, Hq n m'irC ^ uU-k.* . Uflnv-
	''jVs;T'-PU";,	V-^"	¦; i 'jr.	



P)VU>- iXl/rr 6'rnvtL



nnc-kA. 1 ^n r-fid

- i^K 1 i-	Mu-

TV &\fi \XC -f\ ,\ i^Ko, )

iisQ	~A V«-i- \ \ Cw'Y	LS2l	\ t \ V i. ^ "^\n \/ v \ \ .	

^ • > ¦ -> -



! J- ,'\n •

OJ

.yl,\

Li_

r- \,

• ' 1?



g

-------


~T~T~

* I

PsW	r'-r

	'*

I ,-.,- J 'A

• <~s A.

• V U •• i t_

:\AlK- >K

-Q33(T -'

r/fc	r'u~ r/ri'\ -?> *

"T\	Dw	,-i iW-a^	"X(.r»A'iK



=£gj«&5-

ngjt .an <=-,s m pi,- % -for- -vvcn •

jtSTAOArgi.-

i"*.

YJi&foh	y^vi	!	W\..p^-r .y. v-r vu Jj-s A/id

•rr.-

\&«3.6fA- ^AirV. M\	vAi? f Wvi^f. -fa-

¦	

¦S{r, <£dtu , Smrhx^.-tz-i^ mvYu aa,. (Oft iAlt

kftJLrf.-

O

A

VJ

yT-:

V

\

\

-------


a- co-nras







\kfpbr rd^ndouL, £±rts

£g&A3S~
0331 h/gj/fri-

efl

27

Sit® Nam*: V-AP|S\

D«b: (g/ffl/lt1 Job No
Proposed Woite rtf/rrfoj

. location*. (Vv^Wi'jT&Vyi U3A-
	SSIO No:		



ft)JVl DirrilV/, Wny *yi Aipl. \ rrt H .M-. *1

Weather. *?A)

tlfr>S

- Team & Duties-.^Tfc -VflfVT^	ftfrA-V^wA-

_' A-*Wrt, LP, TV., ft, v				

yvwiwnn) p^z-Wifli <^/v|>Uk	

Instrument Calibration:.

Other Parte* on site:,

Safety Meeting: Time: CMP Br-Jl&L

Content: Cn^0 pay-k,	psxen*-

n Non»E & E Attendee*;	MT fKA

I
!

-4 —

Time (24-hr clock):
Left Hotel
Oifrita

Lunch

Returned to Hotel

Left/Start

ftlMS

Arrive/End

All activities charged to a job while in the field (e.g.
off-site activity) must be recorded in log book.

jr mac- ijQ -huki d uVv^ tVtTfi/vd tV, Y\

1YC uivii -frUu. r£r f

oyi^AW t&nrh





oi3*v tfa4 bariL a* mAd?	^ rhmtfo.

Nfc /?pf. "Tt olmvflW
Ahdr c&/\ Ql

4Vi, r-h-fs %c>

fii\4 Kofl^jl Vwr, ^ Spft-y4P

T¥ pemHfirtfirt ^Vx*. -^r V t'm -Hflff?" Ha-

A4ftT \A&

jo\

%w)U4>y uaus. mr.

i§jsfl/rfl

-------
28

ta<\/oi

-V :.l ..: .5.J .	:

ULppP/" Crf\yxrr)r* QsSrtS

o\-co- &yp<

&

332

S0

fit

UldPi/OY \m- (Vr?"f4^Vl6A^AsPD ,&0) p^pasiH* bfy,4 -fiy-
	tanai rw Pe/W Onr'j JULa.	^	

" P^^ToftANS f^--, i 1 0*



-\9C)S- I A fflllori Ph:

^Vu^cri	^c-far c'pftyAirv

3g\p'ZS3-0Sai

jjiais

—vohaJ- <^a/Kp(x3, An*

—3&P&4 £tf Jg&.:iy/

" ftoMrt VaV faille M	fyuyyi^



- 13#)-	Cjoft.. TV	W*_P-to

^QyMCU\j_CW- ^JiX>>£u)-^QS*~f>k. joCMbtUifl^.

-	DEO- A lam Qyv\vff9. \vlt> . od DOOki.

-	\8X) - D^tXAav



fl/vi. fifwiizr di/nrl?6r>^LiLg^fW"
\jy irt, 0\^j- \gj fv\v *v q 0M- \a (ft- o a Vw) 12

ja,

_aid^ia^S-

to\

¦ jflflNLr ^

-------
I





03^



*>.•

u r> f>

Sita Name:

'Data:	Job No:

, Location:	t: 'P

	SSID No: '

Proposed Woik: <1 urAC-r>	^ aMH„

Weather: 1J p- I?Q*^

T»em & Outiee: Vll^ ^'Sm.

Instrument Calibration:

Other Parti ee on alto:

Safety Moating: Time: QH5D- ¦ Bv: flM
Content:		]	

Non-i & E Attendees: TV , , TV\T

Time (24-hr dock):
Laft Hotal
On-aite
Luneh

Returned to Hotal

Left/Start

Arrive/End

Alt activities charged to a job while in the field (e.g.
off-site activity) must be recorded in log book.

	i	

fkv, -^fLiTfe V^ariir\i Qlxiv-b;

Ki', -tw , 0.1Y/4M -Wl &cJl





"tM'WC. . Ho. ;\ri xf: . . .

\y,nd v^; A£(J rVJ r\(





'• I ? J



1 j--





f





•

	1









•

*

" 		

-------
n/S/r

' III- -V.

•p.

>1L

r\

±J_

; if"

> 1 -

V\r 0/







--'.rrft ri 3:



-1_L-

iU

tK

,"U.

I/V

bC;

•i T'-f C'y\

1/5/0 i-

r>.v,Q



'¦¦0 "9.:

f <\

10 j I .-Tv fafoVA : '',6 6- '-'¦ ^'3 0 Ad

\X 4^

A v\vAv;i t,, S^ty,\'

iv;

CyLl

H

U &JS	Hi (j- *&->-£

.\U

v-cn"i.r ^

HrM- Xr.aAnf, hjhu? mil* A. i f) dfUL a^hA	

	YcJjrmSr i/lMW 9~f\v4W	

	flPA/j PVrt'llf iTVvlrvt rfrvAiriiAJ:	fliJi^AjgU

IV mdi^ar^vy uvifrb v\rU

t&jAnrt.-\L*e . m^4fvvaK

-\M^S- \D HkklcrU ?stoA*t l/aAaxJ SSh-aOSflM

aM trfldi U(/" gy\t

(/Oq^.m^ it-brtJ\SJLA \\*krt.

ZlAaiLAj

cu^-emrixj>

	UP 5^/Vj .imfriD "fo TWaaj /^Auo

m nAi/v>^r-

7/in/m- C&3TV mfivu'/fl; \DfMtP (YiXUd. ijO-nsaLi/vg-fav'

	nC Pmabs g/vi am IK nrA \crahLd iv InnuniAg no

	:	:	pa-W\xpftAA<^	\ f) .^rahd	VVxa^ ry^		

	(XM /i^rSry> v c	of n nr\ i a;- Aw.u pr-^A-h

" UHn)- ),Q (MULidL fhsv\i^^ VoAgi' QAd W-H-^ nu&xay

/fiistev

i^ac- uo

vty^ri/Aa pwftcs /t/W ^Lf.wi^-KftTS fnsm

-O raLULZt^	bam/MLS	4W

rtw --VWl (Myw£/zla imri, rii ur\

ss

a ajC

rfiPXd Jl tf/\+

-\aUI- m,vf\i'ta. U-v\fl 9 Cam A. \jn



PnrvJi OvfaAjL. rv\I rtt, nA/jU nV/ S/R/Ty>(o> uSJW b/

-gAriAni. ^jtsvo ffX ^pnufr. tVW/L

Sfox*Ml \Ao.ytfy\A p>v
-------
7/tO/ffi-

/—* '

: ti 3 I

		—;T-"		-(ft

(Vigwira-. \CYA.-p f.iiUd I C AjAsI stated ^Ki^r



fM:

\J\U V*. i\.

^SJO

jcL^i

:/K

Ov* vf.p&A /i i 3 mi'At \ / wu'>u\

v»Mr> -VW.._ ChUxAJsdj^- A./V^	Qfa.

1

ywi All>//YUJLK AV\^ -^.^O iYY^T> v-VV^
&>rc>^ WQ" U>u\ Vn>VW_/TWi ^ fMuru

VOpA- A f\fj 7Ww\r\o lojftflu^ \>SSU \pj

'fer 4i^	fonrt QyrllU

~\/bn^ dnma'/c . raiJ r 4, un and stinted Zhc
-tivx	-fty

A KfMYfr. ^^(rr^\ "^i 1 ^

n/WiO\- \SsCj-	v'eweV filled. 1 jQ flrtd yto fllfKirf rtiMlfA

(Mft	dajij* Gf\ot cmplfbw'GfcfZL

for ft-U 9 K\ a i/tit) ,2t5D3

7/l3/i)i- LP CgwlUk-L fV\iSVuu-/i wvmjP nod Vfc&- a : r': --

rf^duxi d^if lnpidif A bridal mo/nr*

W fed ^rfm^fliwr	m&fe.' cOoad-

ii

rA /rt::... QAd (jV^te jjP fotori"V
:	IX frrMfofA. ufc 		S~ ^

l/W!)'{-}]' (y\5C>- \A\-\vlc^ \h\ : QVlUd i_0 r\f\d ^Modi^d

	:			ftvpcffip^ ir-4"	9 ¦ offset ~W~ ~~V Pi/t>\ \D?D,

"7/O/fr- \oBfr- 1.0 fv\Lt Ycv4iv.	1r>riitsfAjLVS PH/isp l\

irvA ^Wve VMAY.-.i/f 1 )"-Vko- fou^oXdr



\?'.^.r frSV' }dyiuf rTlblln Wirt JiAtf Ai ^-hs/i uli.
covdx»Vaftvfr>> \. 1 x'£ .^TM N; a r^L vt _mvi vk i aj
M)ju"> iVu r\a>, miflL mi UA	t c&/ , OmoJuP



Awi^ fa#lr W\a 1 f) 7H~1/&)

^Ajnv,W) /12uoj_ Wociftn

•7/l%/D)~oft3iV !\>ar\rLhr\crran^	fy^lr^ raJUd \ f)

3U-n-^--irn- iil>40 ^trxnrrib^rfA)MiA
-------
JOO-1

i r> <•/ n jsl..

M/'\n •

f r" 1, fn* S.-Wy^

J£ac£i



Rjin

'x±.

p% '
h,o\

.•Hwl c&xifd i n - hib1- im^D hffijjfj

¦¦

¦ 3 rf>E3>«5 3

W*p-,f-UV'V fccii>y- $n-k

J#B!p

J/2

2,/rM.
ZLLLL

J_•ZJj2±jZ-



~^D

; (Yv /''"TvvU id	uD.	("if*i-£-ff~ V^y?v!L9J

s.1'

m

TsW. W.du r . nY&yfnjCf. c-r.J 1 i QfU-itV

'Tn^ a^j Yyh^ 3> ga'4^

¦a,7y?^a^-^-"Si

	\]	ml

U

2»r

na ffi^yru \}k. DW^pC*



uasj(5\ - map-1D Ipaaks Spn+rkL. M



frfirmA iA	moM- lusMw

io	^i4g -fites of ixon

VTO- ID ^gxjf^ &Mnon.A U) ndhv Y*o*tim\,A Up

[&fc

foriHj ASUQ

rl/kn/\le, B^/n'S ^f-HS\o- oT75l rvii



n£- IU\D AJJaus. {

0031 Aft 1
J&£r, C

^ z>QJr u p ^ mflfiilAa 4n vex )\to J fitogfegflF

QAd firJufliglb%V

2/awpv- nap- mr cru^a Mp AAzJ VfeB- A . nrV) ^Q^' - aftTKBf

(-HvO- mop-jnVu^ ioaj frh'j j rtvivfev-'-Wfl^
-map- \p oojj^T'^VxaaLp >ka/vr<>•¦ to<4^	v
	 Slffi- MsS\^- RIS] ci/ti Wr (L

Ms.

QSkiJK* \Q- V)/ft\ CL

»-V"	t/MQ\ ^ am? /Mi^

iVaAiL. ID tood ^m-tvivniJ



r'jT

u)i44w tllO| fo>	f/r>

u)y^v txfe

M-Vkdl aM ^AM/j



—-¦ ¦' »	—- 1 w> T ¦ —'¦ t ¦ ¦ ' *¦'»¦¦— >	"' 1 *'t- . ^	¦/ ->.lJ

OJXk	fV\T nrvi TVVi-n	Jf PPtZ

_	- .	,~--^fc- 4.—*T~

umteA s q-V\.p
o^ng un'JU	Q^f kS$\K, \vsti

, <»

4^0. •%Vk>u^\



_U2JLL





-------


1

NAP-x.a,^-	-1: :t^-

1 . iT -i- rtT/c^-.iV—:A CXTTft

'537

~  nvr^-rn fnf.

- A,da Uy:v.i w S



--WPS rifirxc, M\. frpppryij X



- /r.-lrUutV.-ia	.\k^U^

^ rry ?. A~K



- <3,

'/"' A'V^p-l 1;

f ¦'•./j i;' !-£a

phvfr>\l7X
W\,o v-r/vdA

JL



-•Vip vrfr

l\o.-B- tSVtafobfr. flvA ft' g^.irJr 10 Tfr-VW f-c^ tt&JinftflnB

«~.l. Ao-»-. f)	AlV . , i • ..-k-(--o^/> A\,i.A; idj . . -L >. ,./i',l/7%-V

lu

'¦ p un'j I ^¦¦,h>i"^ ra\ rfp^	">ujf;ks.	W£ fln±i

O^fAltiu v'Al IfU-k .' i toa Tifo	V'-^ bp la uroint^	V,T\'£P

OrVA * -ba.fi Vj£_J X' 1-, TmIlT ArV^cr pi^-^

txv^ mjy\c. ivf.&Ah.^o -Jovd ycrwi a-r	f x°/^

" ' ^ ' f	s" irfyi/rJ W mb>>f

^ .\fimg\{V. fiyy^. \a'Q	!Yflr. -'¦?	LLlXi	Co j'^oUl

mviU^YoJ ri/i^inftsiv flU *¦• • •¦fHwrv* rv\aAt_ ifaUs unA^Vp
(V ^y*0 uTvH^ d. U rfe-Ujff/vi//t1S	\M 'fttaH- frufrfeg.

¦\lkb\t ^ kfcVi. i

vYp^tW ¦•.•1.C;V.o /

:-fovwTis	/hvpyfr

qAVA Aftfri^MfrV-fynVfliu

oMv in (Tmxrfa, \n Sp

VfjKnXi. firJ (Wy.iVi

—>i> i ^	,t »	—	¦ ¦¦ >j	* ¦¦¦^.. ¦ *» -¦ \j	¦ i<

•fe VyrM. \fl vijjli ovot-h uscVU

	*-*	1 |M »,• »	Hy	 l^t^'	¦	¦«.¦¦¦			¦>-¦¦¦!¦

frite
-------
VI

1 '1-J.I /fA 1	. >

XM\/nl' QftOiV LP dEh/tfuf \VimS Qfr ffiftlt

K.vt^oir^. Ua) aUou^ )s&aS, o

fWT ClXaas (j- I^O	fiflLJ	LQ-



id U

Cciu/ik.

-toSS"> MT

'"jO Kj J 1*1x^3

sllM



n	¦ J

£_

mj	lAJ	tu	ru^w>—-

9k>uJ^Y ftoiQhpbtfr ^rm^A k.

>44yi

-VW prtM\i%& 3 ^V_s



nvFRvniio- i d /y\o+ 11"),-Hi 6vt.

uj uvtyvu

S'lt-f- rii KH^Tl'

svn mm. tott-mm

(AK.	rxJnw cAxi^Ti-i jutnds (Qd'r^m

1 &r%y~ n A/d fl)u) ri Urti is la, ndditiM feiy;'

Anpa 5W .^k p r, m x-r °um oi \ ic ?rik\ ntvi PrfftP^A'Wi

Lka

wvfcie. ,(4- V-ma^. fljhfvi-A- V\i.s i>/ii/yfe4ir»ijpyFM

^nsu,,id jzxAp. rwt^ %vy.. cutp^fo lar^^-f
g^- frfliHAu fag* (kaijvM	"

4k <%\¥	i7u4JsHj't^. <^/i5fe3g;

ACh4n/yo;r^h^v\ c.MroAirTVtfid, ds\hAj^si1n6fi?Mt



IV . \S V^Poil rJ i A ; /O / '-(Hooj ^ lSK *OSvi
Aivort • V4n

k)\o rLUnt J5=>; S-ko. a^\r\i %s (oiouvf) n\ a/& iky'ir^
,x^ (^^yLff^eJiA 3 mpA^t\s. tM
\5 0^\t\AHi^ y^Wv. 0Y\. 4ii ^\mjp

irfeor

U6q/" (wuMramK^



-^m

-------
£1W

SL



Ujjl!



I * v *

f"-,-fv»"t" S,f<

•L'i-^X-.I')/' i.oKkK >.c,- ^pfofrmK



•t <• ^-v-:

or^

rrtetouviMiXE />f ft^YWrTv • infill

tgt£s

IVA 1\U*V ¦ tVvaCh . LCJ. . C&T ) . fx



fkbj j^TeMt's f-U/inop

vTV/ __ ;_»* v: rt — i •»*^. /

\Vvs, fy^AAo

*L



ri-fX-s-vi . n mi' /1/rfl ,of- 41a; re .mod 1/jJm.Iu^ pl/iA, ) ^>P9nbQ

__	.	.	T	: y,^	¦ J- - ¦ _ .

. i .",-u ":• >T iIsJXj. / u/1 "y wRl

UrL iCsVlujU'

/I/mL AMfi/m/, ih mmii^ &3 fe

uJi £r-ma/tra u*a^ /gw tina v cjuiusi-. omucm run

KCCffT:^ rjnv^ife BJc ^W.	riVifriV. iJUjuta** '¦

ui&K n4Aur .-&r\o P 0)£%tisC

fU^r&tfi/vi. u^iyfr [iy^/f'.^vm ur/-lc/) .nto-U*. fohlte.

mMMAg ga/w^ic5, hm-r, nd- .MMidsLaL
vMs ~Uf)cvfrin-jaftf} adlnro/Yi -fo; (SY ckbtiMjMboA*^

rk i	rr^i^Mtp 0(5y#y?»t /m^k/drUM GmpM*\

c/w,i-ky ) f-^AA litfy.w ffiafryfj 4V rhfli/b frtm/nk r^c	^

rhv^Ms ^ U'4 tj/xpn&ix. W 4W. sIm tJK^te,	;	

p\} p\&^iWlSs pf> nth Vfrsfcwft Uxa,Mto, i,s iXHW	

..\,j- is v >. u\i mcA , imp" m\h\m}d-br loVi^	



Yt^nfmVjl? iy. tori,-* Zh^hin'-'\mM .tvrxUe	

m: oth . n ^iTg.A hpauc Wi>/, jpppn \iifryrfsedfrW

]f\ ; fl.





nj

pul-p-Mr o m\frd | rur\>TSA



1, qM

¦'mofi.te>\vtiA n^- HfUc. GlYmM. fe:H jHi.gY&i.. faix^ 6
mw_rwAH>if , is fx ,	a/d Sjskiso

-------




u j4 u

y$/o\~ ; ,p n-M, (](\) ^.ocM^U rkaj.A a* 4^. Ski/Z/iK f>%

*> ft *¦"" 1	[1

-- "2c*	"

fY^i/iivay \vv '^W A^Rfccfcy^rffifP. .4W, SkrtAs

(M, Vrtmu

U t ( fl ¦ .nil 1 rl .«
¦, U~VI ^ LA-/

1r.

b\s	fVl^f*, irwiL^Pf fKJ IDks	^

-r



2i3J£t



i

\£) awL {IAS- fmp yfs.dr mirj Ss^s. irr Phi ^ Daa£L> do-Mfflfikf&'&i

r			7		7r r> \

A-Vw-ri A. W-^ \.s noV	~fo .>/> yWa^Sik- OA/i. h^ufln

Qm&ytAM, on ti loifW. fhaxg. CoUW/vv^

i-f%'

t^lls

MfajLfs ma/uy

KXaI fliJfMAS>

f.O.frn ^57

ia)>v foiol-nnS

-------
W J1 1 -l>-

' s&'



-'.'rUl / iTA £r^ i'lLf'T'Cj.	f> itf T". P.ai a :^jA	Cx!\(X	LP ¦ Of)4	A.. ^

- \D CfiDSsi (v'T i^M §cj-urXj.xi rk n. a^sitsac ~fy S/IJCs1
Vj rh5/-i i^vHrw \xa;vvt>-m: Vxsri/r. ..

rLQQipM^ OW^'-n?>up pfrore	1&4X i6 ~fo

Wo?. .jjr Smbd 4W \'Afr~. >-	£MfY\/3ii /u/f-fv-

.SZiiLl

jpqlI am\fe>fAi f>l . w»\tx- U"?\S %^iM3Saa.. A-

Tv\f) rfDe^A- •..?. .



St^Al;1,'' ,ti^.'li/-ih^-	Af/Lrtuirl.^ i.aVW twU/S

JJMl	\. 0 \M I '. fc-^A WC» &> 1ft£.Mc/V*



q^Lu'NDtlf

uvHkc iVy V^ilV^ T'C:
0/Y.1 h,V-) > mcrU/a cta ¦

\Ya

...-.i. „.¦;.^ ni

_^il

HxL^a

i/\d ¦' i ij-v^'.VV'l r.r.n

¦ X	% *

p\; v J	l". ,1.-/)^	Qj '^1	,*.	I_.j3	U...ijn'.^i	)} \cA'.i—L1-* —pO^C/V^V-vU-*.,

C' fiLvk-rrf-



K';,.\**' \ V\a£xrvf-''i-i-ni. . I D u}) u> \))j oaJ

'.i/ifcU'J:.--		juL"'	Ex&u

kyu , inl ~h'X-K'n

/i •'.'

	1. 	„



ciiLAr.

lltlQLrll

, OAotCh.f W ROJ^plz.
"AT \ i'i"i a i -tlti-V.- Tr-..	iM^k



lO ru 'd,' iVir



Qi-Ao.flA .a d Qt. r;v¥ 'tfrn^rxQ.
u'vli p'rCUili	f.rj^fAxA ^-.'3^ Otc T\--, 	£M



f

i

-------
...UM,iUl	l...;	'-.a-h	;;—» '-v ' •

3/n/Zr rs^YtHisK CCf J~0 - r\r	4*A	p&a£«#AS ~v nr

¦; .'"rK :. ' -ft" 0"-!T '^lAj i ;1	c f H }^i:A-f- ^.OSK^J ( %



m

+

be. Ortic-srh d ' n+- ~Hn' p;AT	-fK^- fotftf flA

Ajo Pruiaiz;. nr\d 04- 4 Kg fltii'H w^V-iOr '^kc. UJfl#
CoA(Kdr.J i/Ufc -ru t.)c, fKTa^U9

1m

jli±L-aL

a i V- j i ,v s< d , iufi y e of a j -tftyis hcvr k. p-nyy^ AJ -'/*

bi\d Crf,!.Ui. (Ijftt/ fSL

\"vcr r-oj W. fetti cStow

-It- fljfo. rJQa.d" )Vli7Ty(M^?W-&SUMS Ifliv
(v\iAg>s Ofljvi ml v^- /I. 'mhs/ififi.. mr -rtrsV .



yAe ak' -fiwx fi,tmng ijfH, ¦ irffni dw^l.-< S»ntI4fs
MMtifliBfr frwMfrmiK fins (ViT Mift'-jrv

¦iil'y.

Vu&i Ufl/tr^

% Tb 1ft SEP. if	r-q.A. uv

S4/Y\pto. OXj	L0 ttA:/e.w

fe mJ 'M

J ^ scMjtMkt, 1uk fei/ ..'-

9 fi/\d	a , fiixd 4iw-j- mi4*i 5 £>£ md 4)

£Pfi	rtppyf^majf-UA H/jfcuS. uOun'QJ Hi&.

4^u, %nd Of(Dwr	H--ftf*?

fKT Ortuv UTtfiit . lO Uf\l J .O.^AL flu fWj' ^ adQiJLAJjw-

Md	rjp'jiA^ia, fuwr' ft-T. W/fyjtt htKj3 >jjgJis.	_£!_

ti3 CfMA , iYG OAri n^{>A. Uflflfr nnoJ/A^ u>trf

.t^Om Sfuvptcs f'Plu.Hf .-i %•?¦ - l/QflKrVMH- Cykth'/vL

\iYrm%W)t.	~]		

farts x^r-^ mi.ui, \r> ,v,ri ^rdiri ^ ^

w, V/ (^xu3uyt\ n*.4- Pt,sv-: \tu^Tr Vl^

-to 'Al'v?- m \Q q>\td	\tu^ m*iiM

jtm



,r.,i.	,., n	n. -^zPr Thrift,

•^- (Wiy^ r>.'nr\ Vs kwdtH \>A^b

CoVy.Vtf, ^V^-T fnW. ^Tw> iY\\^ is r^nf-g^d ¦ &b0bd4K^. Arte-
-\y, f~\ l a q-w tA|?RWfrxm qp^./'Ki^

/i fi AA	UW Q-Wf-W A A At A ! * l Aii"\ S yJ	f-*: aCwi I /! aJ-1 iJ	. A

• I ,

dfliY1.0itTt ^d-D^ %AA\pUx fij\)/l VaP OiriJir-fi^ -fnlV^^U
-PrvilM vtiid. fi Wri Is narr nRiiiJ iD Miiai ajsuuy^

• < ^ ' \	L^Ad.^	U	nil A J ?	L-Cti	I			LuVf:	L>^tVvP-

ftH)4nD (114^. '^VU-"

^Qovdlr n/>d «arvc, d . axtik, \s aoAftjfa&'?M

—1	i





-------
jjrCO-flfrfri.

Ufp/	Ojvt/

034



fift/fl- \33"> QwflV SiTxk H /xroi -s	W (Mead* "<

f&tfi bp]j i f ir€S>	cu Vml D -"fo VaY\ \ V, (W'^VWrf u^r*

¦ir^f

•"-¦ - 'vm\



-V 'AW,; Wil*	, Pntri >f, \ \?m4e4 ;

jjVt

Sai/'facE. sriJP .S/Vav^xiA -fa ter. cgUaafe/'

316AC SNl

1M

lus-_c>Li_A\^l. \'^\a fetfi \,^1? nvM^v, i^u &/

Cft-U . AJD..... . 	___

un iPy& Jb ^ rwi :



^£9_- Ji)

_ \

pr'- 1 P rffn. l rw-:ui^ 1v. >.? WVnrxJ frith	aa.i

^ ^ y-' . > -w

hm to*x fyj

OpA- -uff -J Hfo&	f.lft flVflLP ^u/k-dp^LcLi

llfl ^ - -XQ-iirriLL'.a^-j va d. Lai14 Kr	fofc-tKifo U?m1

•r

\x

±c

xnAm^s^-s

i-huv



%IM~ CCHOr- \-/) r-A n c cL. iWi /iVva if * vrt?lVY*j\ . (JhfK> 6CCL {30K - - ")S^|

Pftj MV ft.	^M£dilIP LYumfi/ftfru-/? tb P^H ^

mj lis >rui.u1 ^. I'M MI <&r )if/7iC'lWs vn< &	.

JQP. (fl.Hr -VW.	tAAiJ

V\gr YMSfrflfigA,

uat

kL^ldhflZL

^1Q50- \jQ.iftxgL.Avbl

JW - 31H-^3Ti ^ ¦ iP_kaA_£B.

u>VW, Wo.^ai. c^aj uO iM yy. Wwtt tw4» \>sV(

Sft/gl- Mig.



V-- - ¦¦

fe,:^

f\M rn t 1 \-T> Mtjl, UaVV^ fmdl4--pn a-4 L-yf-

		__	

fhj	lD > jla>* i^/\h

¦ OvA)rmrrlt \\L% aa j I'lif/, 0

fV\jAj> a/^4 min fiiAiioAn/r\f)^ riAd i^'/ j br		

1-Q	\o\4W aou^ ^^f.l-.^rrUAis

&?•

W^T -VriOVo^ IavH^ fixtix 5^r^L KMrTinvj-
(77u4Utf ViOAf	farK	-4W /? ij )\

OflA, tot- Ct?od.uoi-c) wH'hgvd cc-VtYd- arri

odii-hmjaJP v^vH aaH pr^/iteoJ srmph'Ap c&^
3/^'tfl &jb 		J

Jql

-------


u ^.ll T N P - ^

0344

flvtyp-nrv^

i/°l/g1 - Offi>8- CSrmD- pg-rfRvrnj)^^. a-^- /VffaYis	nad- f

-fKiL S/a/w> /izuj fa^rri tin'/1 -Pr^

Qa/vu 4t> 4X). I JO iin'/o ^p/^L \i.p^U

j

Mfc

_5Vu

-Cci

jUAvW/a

K?Jvr/- fftT biAdQP+ cvvL addpn/LuA^

."h? fVu aa/x4 Vjftfoy

-C>^M£~ #mi	Pq uo4. I>T) r\nA synVg n )n\s\jJr '&tif\tdjudj*j
	Auf/vfr <7^ PartS Cy> a	v-fW.

	4Cfl/^ -fe Vvp I |Q i a> rtffcx^i

	fc*~ Vi-^ QamiS oaa

SQwrinlpflL -Vs caw uV 1 -to £uj)pV<\ |nfivntfc/w

1Q1-

yy.«frsiAg £fuy\jti£*~i 0C&4)<>&

¦ (W ck . &

-^0

loin-

-CQJJQul,\f> rr,

iMnua % Yn9 Hft>feL (V\T -fc> C.f^Li-£xA>'^°n ctrJ

jf

0\qrjLtfQ£X\!jvr		\jQ_&jhl^a^_.a^....

'(DUo- V^r fnii./l IJfS'^Ad	Ot>/\-H\r4 /Q-t ffjqrflVl^Q UYL



St

Uld^i.

~loQ - Up crujULcuJgr .^B-Vfe.

-W> mx CP.AAi.du .Ul._0LZ\d^Sl2?d^ AQt..jA*_J3ki>\tociL_.U^^^--

.jk	cifficer

it? Qfc\n *rt-' 'TDLLz .hSitt^wm^. (VX	

» nc

fr

_uj

_&L

mrir- k

-1335

totfc IHoJl •

-

jO^

d \jO -k> "aft	tiML \A. A, Spirz3P

-yah\f.

lmcK>dlxjck,

.^-(^x\fyvfc^y_

10 caiXaA. ftCT ClaJ	Hki OUruW

W it urxa nft bc*i^^aiA£UJ> vqjj 	

QaA,^[> a , Cl^

"W. fa>tAlmAi>	-V) <2,00 \£



\D5^-	OQHod. \D r>M ^tVq^ SYyd utcls to

pftMtjm rxMi/^ HrU. photos c£ ftwp

^ wjeoiirp^ \ p^rhix^
w ^ CUvL ctuTM^i p^, hos \ms\s

P-Mi





QjOCull P -ffeL fofti	_.

-k ^ ho/- l/MA H





3/WI HD

ft

-------


.QS- TY\T ca 1 xo d. if) arvi Ca^YqcX	pV^vm, tAJLifvbf^-f\'

•VL



n\-oa-ty-m



0345

41

73";|

•)vorMLKb - Pix/ti\L rtP.d .fturr.H Ukblfl.

• 1Q~>- AO CoXUz^- \Xi ,ifvi ry.vnL V\&^- -VW>^ h-fimsViJ



^0-

.QuAAL_. ClA- (^M-g^lOl

Dand rrffv u^\--

5Y \%y [Vy^JeW_$. Cx\js_j^ uO ryictL inf\v/r;,ir^v n:a/^/vfl
	hldi^ Kibi^L.. Q\}(UC, livu is Qcuvl , ri\>- (\na s\\\ •)

r..-; .A /'.;.•.Iw V-.,. . , u -	' '-T

Ai: A > JC—'^ia'JfviL

iryVtflT- 15^5—QXT-Co^ULiL.. 1>P rca/A/7iij\s Cic^Akjd, \)Wr •* Wiu
			 Cud cMx^.^ v-ir.	hflk (-DWsjrrf C'U , f>lfi, orJ

	DL	U; rMA n\^ua r^7iVv:ilJ AwtttU.

»hJ

._--vv^atw_B±z6cinLd	S3\-	And teH-

-._._ £L	k> Zq.uAvi<:. ^£Jl^ £dxi4 Jr:jCtiu^

	„	. intern yrvfiYi vk,Kft\^A nu^J-t

Qt^ hui4fi stated CL pio rv~ 3orl oi-Jnard 1tsf	

	lCf^yXd Vx. u Ai \c >-f n-*- -to f pa .W c 4 SS :v - n< tc a c scPh

•Vkt xVia btvlLS (a4 h^crl Svvvi-kki^ Phv^ iV^/\^C.i\C d CL

		tai\C.Vv.AI'gd LJiQ)	L. pMO^JLUjL)-.^^ .CvwAfiziX_

i_.^	"Vi- r)j\Y >^- r>) L>fr.	fiifK ic\\l WvW VrtH-t \lyjr.^

OTsd, /iv\

Jm.

StUV~p.U_. -LC.W.£foflM.

h*t. ofonna forWuM. g. i
C^JT^aJ

ft-h d JJr \«s & ^nYan Qfiiw, \\^rcr

_l^„..bCd£^r„ V.CU\\v^r	p^'r Vxuur iXfi.rk.,

\AhTY nru>jriv3vu rifiQjTi 1 svj	foi\eu'JA i S UjirJl

grici	Irf	f^Q/CP. ^C^c

\xiVi>7LiJ\g fi)\oilk S>J>i6^ ^V?p+ 4V(2^-

v^tg.

U-i	1 \ ~jXJ}T\ijJ\^r	IUUL—j^iJA V 		^lsU/pli

-Wntw, V,	ITa^>.^>. v^. (k. VW^i- Ai

V ri^es \-v">V ppb6Krr ^V- syv^j4t^ ^-rfr

W YciXikrt* ~AVu± ^ \oc^J> \ou>V\-'-W-
°(Vvy\	f\r^- YhAX^

-------
a

Upfpr Pr	^ -\W> hwvi fefr-	

lT) rrrojiff <£ ~f^* ffSru - ftltfi filW



xa-'dany&s

jJmL&DiJj

SVvo

\S Wliilu-.u



-15V)r?- fVfl" Pfll^ i.r) rvryj ^-hfi
	WdQrt fWrnmry,

UP Yaiu.ci TV. A/W VP-jj a , yrw^Y	id

			C'AjZArrl n f\fL l^iAt sx/ii'-A	g/\d 6I'-V',.; .

•'1-.SS3- YKT pftUod 1/) nrd ftalto/ol kjO CaJj QriX u.» .'-?«•,
	P-ffv/4^AaC -AVy.'rr 1;? <;e/fr XaA'f	

-	s	^ ^ VW^ruAo A Ad! UA t V wvn 1 \-V tN\ LO	

-KoC>%- rv\T	liH/vi ^Tifrtri fVi.'V

	WtoJS ¦ ,Y\ttta-4 -ftv Wf)M l^Tp^-P ^rr -j^o KvXV	

	to axrf)7iacjol U p Kes -k IQrfr. JjA <*iV f^l/5i^vN)'h^

1^.%(Y>-	t>. pcu.ti\v

-i n>

iciiw/rt iwuui/iJ f\y	^ /tPS u/h'-i.

- n-xc

- UflW 1 -

xj ax^rfiacjA up tus -to bony. ,r.o rn t vw^rev
Wr-s fta AM ijO rr- khurrd 5 S^. a WV>*S

l&L*

x\nVs^ iqfoto>s. LT) frifr \H Ka Wa 4u
'buAftg* AfV) fil S,~DT^> I f) VAt up Jte t-f/)i'^	



liLL

l)3t/Dl- W\H



fl\Q]Y\p M^Ou (JjTVU I'

*/\U>/Pl~ 13PQ- maliW. IrgjYiflhQ/i OHlUJt (A flAdl tfm-hd -^v.
		rtjCfi\rrA 4w 4W ^PAT*- 1ti I O nM, UTitP ^

?/3f)/f?1-

\Q (toN,

o^fict, ap8-3SH- fia

/V)jUS jn^vu- HVc



r/tos

'\FOl'(ra oaiiort \iO ar\A VJA fi WtteaML 5?hi^A. tin

—	U^l^n^^sYV u^l\ -(WtWT n~ IvhV cA CcsA^aXD:  >^i^r r\m*Sffln S/iS7S\ O^lT
V/0,i^^-hd Vv^ (\orfod \ -hiJLk \\ls			

		y	'.flap



-------


11

! i/h/m- \m rmffn - ^



ppv QfttiA(li\/?,

0347

43

prf.v)

	*rQ

 .W V.*~ \3

.^. i\UAt	iAfc ^VWn (kDyrrdl-

4V. rlnfru

r_DDS^Jjtni_

ivrftt-Cw

—CkLS&—	_ _ ... _

JjciLhu^A	r\b \a^d

Ml

ilStilJLG-

sta- [c&m - sbi)



.6K„.^Nl. rxvjurx Orop^i
CC-U'-i.

JCl^XhLCM_VvJ AW. flirrik. M	b y-1 V. Kthr/

\wVt> Aw. OS W Cib\fl^ oriHjfit Ir^h-mts.

W	'-S>	CM-/ VT\JU9S c^Aw.	uu4^u

1 3)a)/Dl- ffliM



(&U£^.U> Ani U-H- g^

Sg^cll/^ pTfy pArlM/i/ o{	. fnw^tri/VA-



Wwc diz-iAii

ckfrc^ mak&.

reu^i^ a-( ^

¦fe Soaj-c		

ti\vtrtui	^rVt, t5F ^Azi ch\Vl*s ft\. -Us*

i£Ad_l^D.ilt.	nmpr^/t Vx^ £tf.

¦£/^a/(?1- U2-C£L\JUA._.(Kr Omjl*uA^Db\dL

WtA. r^Qunuti

-CM**

LP CftJlf HL fYYT  frvflutwir rftllli. HQ ftfld Stated ^he. uiil tafy
		K^QvfiuiM	r\n Sht CfrfrjjilflS i'V

-Cw_

-------
CdMSYLtk £U ftjrts

_QJ

0348
-fp-ooaa



C^n- flno^H^L- farr^hoA. 1a3i4^ fe%Jh(&djt^(&UML.(J2~.
		/l-ft a . moasa a 0^ ^t7rhV\i sW. hx>> hmM-^kd

	ttL Wp>

	 ^ A^~* - o/ittL%£> jp ptfyyyhA	iMi Vbi_Z^.SP0). tu^i-

C^\u Q&itvi 6t.

. Cfp&jJt oM yV>a^L_SAt..iY)A m idiiAi>-wAc> *a*£_ i-b
-QoiJJ a*	iY^u/VW6,_ 0u0. ^ gpjc ^tu fWnt&~

__. tCL_^m3Ld_jkl_..&X^4d^i#lJftsYvu_nE^ - 	

_ fbvid Dx - -C OU_4
_Vw Wc^u _. ,.cAw~ Aa|?.. o/ua  (I tolYd ^ 4V\fi)n Vl>~tWu4W

^l\lc



—_^nN^-.6l>> .&L^^ai>NULu^ . it \^cVt OK. bAAX*£>r~.
_LQ.. ¦•CflAJjLd— Tver nrsd> Vfcfrfr n^	.MUTUTtiLSllTjJ^

JY&M\aa_. $4y>^„x^xa^	U3. iofonr***\

-liUl

—	Jtyr	be^-^K. .Aftjuo foiM;. (>{_.Qtftita£L_

i/aWI- 013V to		feU ^Lmi^ w^iicoJht^

	fe v^imrc 4i^ Wuaju t/isvu.	LP lAii se^

	tAf -HfW- £0 ctrfri/\a*i_ mtkp% -b ml.uac^JM	j& sstytft.

\S5

JD331-	SatQljS3-jMd.

	CL fY\£3£0fljL> Vyftj^tlA^ QrdlC. Sa/K£it3-.-M^O_---

			reKltLfjTcQ CtH CAMrCA/X-/vL fKu\x ~lVr> .^fljliplf	

M

!~

WUtiSK flWV ^VQ	WOf.

f^Mh/hJ -huAWf UJttv'ftziijxd And -tW/1 dhit\y\ -

Mil

\ypuc^?M ~CVvt ejtfeiiiuSNs^	"tM-

Um toiy&fikd \Qetofe'4t<. Co-toCftW Sv^.

¦#isB-&£

-------
fci



0349

45



ilasfcw tytea- VuiA.



4W 5fl



^af.ofy



UXStHU raUuj LQ aaJ \/tsif\ed

£ S»^D,	\SO) uof CxrUt^kJ	

M	CMmxAmJ	jhiis* bA)u

bM TY, \jMiP /Lfyj k)fy fll i^HHn."Bm-

WOC %^r ^ fMhCrtrJlO

OQCft.

f^iiiHciLQ fe^VcJf; LXV

_U) cgkAj TV fmd Q&UiiLShiiJy^ ^j^^kdiidcL



£\

so

L



Lfl&LJUli&O. &vL

yMsA	\xfifc8 rtiataL ft/v^, fodUfltefc.

\fo

_Ll

-0*

_\lt£>- Cftlkij 10 VWo

ALi^ VmyCPjlAfli OKil\f (24

¦— GJLtelr 7?jlfl,Vus\Ajs mD^	(Mwa/ii

IaVijOTMO tYU/r&ft.. 0/>d ttlfc*W.V€o

OaA itAU- ^ML

UflDrS"^ 1 <0 PjiilefL YVYT (if\A	\-f IQfSTDYJ k/O

CAcvd/iiidu	Wtr viul PdiJi lygTKvu

r>^ fi

fyfr ^r)Lx-K yWA ¦	

rcL 1KT flrvji oaM j4^Vuc

/m- mi- \ n onii

ifiH bp. a £Vh^£>

-ftjiH 

Ovl^n

la J? -FtlH ^koe^-

-------
46

0350

AifPf/ CUtiMJcn.AsV.lrc/'	$££&.-. .__

^\sr, ml rfrv
^LOLr&u^ £juxl Okj I 1c diVfr buplyHt g^jWr. tVvJ

.BmiisKil. .CuJKW		\fei4^S.- toIlicA--

kUHL AT>V	'tVSYYl	~}p H^KrS DwS ..

JJ281D:

$vd +o P ^ik^.x.5^y ^4c^5i>Vve>	

_A & / SlVuc/ "S14C ^ 				

- ID (djjsA iVCT Cvj\d sUtoft. %W wv-p Cvi a, Sc/tfa/ucc
-%r_. JLaCK- vc4uyvn£JI^i^	.cLit-.

-Tte- ^-VuL i y\W"f )L\U vJ . ^Cfli&UfcL 0- dl/'bfi^-CLL'r4>__.
^-L>lC_Ctba,d r\Wi J&fejo&L. cc,0JTvpiju5f_ U9 6Jbv^
.. rmcU. a_ pii\d 1o SY^rOsS	ODWm\sL.{' Ti»)u_

oMuo ^uutLd ,.1>.. sc pa^-zrU

—'i/tf&._~iv?D ^ac£- ot\U_i.co(M O^MPjfA&Ab

-Oo^S.-^TW 'bHc pr^e(^Six^v\- c^, & nao "tan sp'^ o^--^rc€^i.. wiKl ^
—Lp^p v\^-,Ai-^pg.v.	(bp\lu^lQLt^lAfLr^ £sfe__ai^L-^l^



—- OUWC Cu^ tHl,	..S^c

_IDDQjfe_^VjL Qvo\h (U^ i^.WB .AbV
-a «QA-.. \9{5U1U#-. ID '^.Ci^a^NL

	"f\y 4vt PaM OrtilV. Sbw:..ZX£- okd_h^

	M Jcm oMl 4t>... beo^ d^

	1^._.5W>£_ S. ^VU\t^...0i^.„.Cf\)\\^,	_	

MLi^ayi^„ v£L Oi^-.uxAl o^i_i'tuu 4imaU^AM_Sfeki,i

A^JV^LCrcKLu^ MKi	11 Sn^S

JXC^L^jUud... s^t		G5Ws>

	iuSLkitrtftfltuj...

-o&sLdctf^^ +o.	.

U M^sutoj

	 \ Q usiSLL tMufarmiM-W

QMS - \D fau„m fv3" Odd *# W Ufo ^

00)9 ^

l^'l/Dl:. 023

lex?1

IS

un/pi- PS

u;

JUCS.1

~oM'

o%Q

^AacT...
<&flO 8/<£1 j/(~£J~

-------
a	cfc oa-n>av

0351



47_

m v%5§t|

	 ?jgH/Pl-0433- IWT r/»llod IQ AaH ffr,V1 <41* -' Poid rWill^» fii*^ ^Ady*-

nwyic? and n%\Lnd iV- ^ hW/K/^	nuLj&L

'-.>7'% I

- IPCM

10. I/) omQi ifafiJ? 4VM?u

J!g£±_

	 	__	_ _	f.CvdSADKfrJF

' ~Gv* SPPl-qn-STS) uMu

l/T^S 'nrVp TY\

iw

fc> (jfllLxfojOkqi, QjAi_ydxfld_U2__u?

JCyUAiL- i£)	n\o^

ruS-j1	







~ Wb - mn AhA . Vc/nriVYLyv Ot k i p

o/>d IfcH- a. rrus&o^.

rvrJ

	.	—-	y	-

C*L_OYi. Qjfm/J3d-J3zJw^U/U^

-ULV^.j^v5Yiiid--fto{
fldr. IflAc SVr^t-d

vAV/ mjh4. 4^\j*AJrs -\W. yvuyvirf^/i^ bar^ic^

jpskiiC

'\/\. *-VW. CLrfgL. KVA IJ/7*S\l

. I	ti 		: - •	c* v.. . I



\ ^VflAj . I.Q j/r^.iUd tout A A\j]ferYpH- ¦

	SvV (V. l^u^.0no^L-_

- cfljV LOo^i^ (YwiW Uy^Jv. foO-55> ffiO in



¦U- Vm? ow^_d	CO^iii



rvvr. Ujr^Lh
4^,0 mjua^	.	

-Q&lS - VP rnilliH nm-*Mrws~ flr\ir>v?t>jp LupnrJn ^P>-3S7-M&3

	Qa^	RM

	IVwhflu

_/U^ch
ftmkr> <

/ii^ no+ Uvc

pjP LuyvtJo
»7>\qO
o^ h4ua OnUix^S>-

rh'h ttvttfW"

TKg tivWfriT) <=^±o A ~Wy& 41re, WW-Ja/j p Q

IxkvJv^

i ^WfrV nn,

iLm^ rloes. mV- qu?a a oaTa*. (Aflmcri ^kfhVnn
OSD- \jT>coJJi*Ji i/^~liii-0			—		

v/v Vyj ^-Qinrt ilu ^Ylpd fki^iA Wi\i

-------
48



CciiLnibiA . UlXTfr Cn-c&ooax .

g iQ~)jv\- O&Q^OflJTQ - Bt^jus) 4-hCb*- UiUlp/^

	*tmim£^_a/\3L_h^ un'U larthw- Kar'pstii cjMJ

		 H _3Wil„(xms>._ Odu&a ftw\L. \£Me& W m	

-DM

.-Otast^ iQ.taxUid 3oasl$" Dc^u ia/wuii. oj\d oMmLl-. .
	Hjsk,_ dum4 ... \kXiMJ	.. h^Sm/uu^^A

_* ¦•wOl ~

	: iu^vmi

sta-kd sv^ aons .dS/dwvQL.aM .oi-irtffe'brt
... ftOiC \0M i/L10 4)n(L kftlA^^Sk* d^^JrpJ^J

6:am ct)w	dwyux^. l\to.

-. sfekd_-b Ok-U Wout/^ta 1V^_Stoku. uVid U&US
--- £U OUWS

I>wMU-.iO ^Y\aiM- [Y^MoiZIamS. "W ei$c&e#	

-. *(W. ^L5t,. UO uriU se/\jl.a/u ouCJx^S-kMcr:	

	OAs!	vwt

t ./"\ A A I I . A jT\I « , A /*I

vu cwAAJia i&uj'_

. 50°l- 43S^-2d3SI

U>l-r^_YXJ\CV7P3-

_4rw^uoctac

. fKX GXLUuC'tO a/\d kjft. &uor\L&L«A&_fi£UAj U).Hl
uX*t^ CoUjlcXLpL "4htr.	Un noA ol no cn*y>y

n
-------
0353

10:START-2\01080009\S714

-------
Table C-l

GLOBAL POSITIONING SYSTEM DATA
LOWER PEND OREILLE RIVER EXPANDED SITE INSPECTION
FEND OREILLE COUNTY. WASHINGTON

sample

station id in













Longitude

Longitude

Longitude

Lat

number

field info

station id on map

pdop

date

time

long

lat

Degrees

Minutes

Seconds

Degrees

01264268

BBPP01SW

BBPP01SW/SD

6.9

6/26/2001

!2:55:43P

-117.406

48.847

-117

24

21.6

48

01264270

BBPP02SW

BBPP02SW/SD

7.7

6/26/2001

12:57:55P

-117.407

48.847

-117

24

25.2

48

01264358

BK02SS

BK02SS

4.6

6/27/2001

I0:43:07A

-117.357

48.866

-117

21

25.2

48

01264274

BK03SS

BK03SS

7

6/27/2001

0l:2i:42P

-117.416

48.86

-117

24

57.6

48

01264416

GMPOPP04SD

GMPOPP04SW/SD

3.1

6/27/2001

12:17:30P

-117.367

48.87

-117

22

1.2

48

01264417

GMPOPP05SD

GMPOPP05SW/SD

5.3

6/27/2001

12:37:54P

-117.367

48.87

-117

22

1.2

48

01264271

ORSPG1SW

ORSPOISW/SD

5.4

6/27/2001

12:30:25P

-117.414

48.86

-117

24

50.4

48

01264273

ORSP02SD

ORSP02SD

4.4

6/27/2001

01:59:19P

-117.413

48.86

-117

24

46.8

48

01264263

POCK01SD

POCKOISW/SD

4.8

6/25/2001

04-.25-.58P

-117.35

48.893

-117

21

0

48

01264401

POPP01SW

POPP01SW

5.2

6/26/2001

01:53:26P

-117.359

48.886

-117

21

32.4

48

01264411

POPP02SD

POPP02SW/SD

4.5

6/26/2001

01:38:27P

-117.352

48.892

-117

21

7.2

48

01264351

POSPOISD

POSPOISD

3.2

6/25/2001

09:37:11 A

-117.352

48.888

-117

21

7.2

48

01264261

POSP01SD

POSPOISD

3.2

6/25/2001

09:37:11 A

-117.352

48.888

-117

21

7.2

48

01264352

POSP02SD

POSP02SD

5.3

6/25/2001

10:00:31 A

-117.35

48.889

. -117

21

0

48

01264262

POSP02SD

POSP02SD

5.3

6/25/2001

10:00:31A

-117.35

48.889

-117

21

0

48

01264252

POTP01SS

POTP01SS

4.1

6/25/2001

09:43:56A

-117.351

48.888

-117

21

3.6

48

01264253

POTP02SS

POTP02SS

5.4

6/25/2001

10:02:05A

-117.35

48.889

-117

21

0

48

01264254

POTP03SS

POTP03SS

5

6/25/2001

10:44:46A

-117.348

48.891

-117

20

52.8

48

01264255

POTP04SS

POTP04SS

3.1

6/25/2001

11:40:33A

-117.35

48.882

-117

21

0

48

01264256

POTP05SS

POTP05SS

2.2

6/25/2001

U:48:38A

-117.351

48.883

-117

21

3.6

48

01264258

POTP07SS

POTP07SS

4.2

6/25/2001

02:09:1 IP

-117.349

48.888

-117

20

56.4

48

01264259

POTP08SS

POTP08SS

3.1

6/25/2001

02.10-.55P

-117.349

48.887

-117

20

56.4

48

01264260

POTP09SS

POTP09SS

5.4

6/25/2001

10:01:41A

-117.35

48.889

-117

21

0

. 48

pi264354

POWP02SS

POWP02SS

3

6/26/2001

10:39:15A

-117.362

48.882

-117

21

43.2

48

01264426

PRBK01SD

PRBK01SD

4.8

6/28/2001

01:54:02P

-117.393

48.829

-117

23

34.8

48

01264427

PRBK02SD

PRBK02SD

3.7

6/28/2001

01:55:23P

-117.393

48.828

-117

23

34.8

48

01264428

PRBK03SD

PRBK03SD

3.9

6/28/2001

02:03:33P-

-117.393

48.828

-117

23

34.8

48

01264402

PRRS01SD

PRRS01SD

4.6

6/25/2001

H:00:33A

-117.344

48.986

-117

20

38.4

48

01264404

PRRS02SD

PRRS02SD

5.3

6/25/2001

12:25:02P

-117.33

48.957

-117

19

48

48

01264409

PRRS03SD

PRRS03SD

5.7

6/26/2001

11:50:51 A

-117.35

48.895

-117

21

0

48

01264414

PRRS04SD

PRRS04SD

3.4

6/27/2001

1 l:41:18A

-117.369

48.878

-117

22

8.4

4f

01264403

PRTB0ISD

PRTB01SD

5.5

6/25/2001

11:57:59A

-117.333

48.963

-117

19

58.8

4f

01264405

PRTB02SD

PRTB02SD

6.1

6/25/2001

01:52:20P

-117.342

48.92«

-117

2C

31.2

41

01264406

PRTB03SD

PRTB03SD

4.2

6/25/2001

02:22:12P

-117.341

48.924

-117

2C

27.6

41

01264407

PRTB04SD

PRTB04SD

3.€

6/26/2001

10:03:02A

-117.331

48,9f

-117

19

51.6

41

01264408

PRTB05SD

PRTB05SD

9.f

6/26/2001

10:54:37A

-117.325

48.92-

-117

IS

44.4

41

01264421

PRTB06SD

PRTB06SD

5

6/27/2001

05:11:22P

-117.365

48.961

-111

22

8.4

41

-------
Table C-l

GLOBAL POSITIONING SYSTEM DATA
LOWER PEND OREILLE RIVER EXPANDED SITE INSPECTION

BENI

) OREILLE COUP

«JTY. WASHINGTON

sample
number

station id in
field info

station id on map

pdop

date

time

long

lat

Longitude
Degrees

Longitude
Minutes

Longitude
Seconds

Lat
Degra

01264422

PRTB07SD

PRTB07SD

3.6

6/27/2001

06:00:08P

-117.373

48.901

-117

22

22.8

C

01264424

PRTB08SD

PRTB08SD

3.6

6/28/2001

12:36:06P

-117.369

48.864

-117

22

8.4

¦ £

01264425

PRTB09SD

PRTB09SD

3.1

6/28/2001

01:00:09P

-117.386

48.853

-117

23

9.6

I

01264265

TCBK01SW

TCBK01SW/SD

3.6

6/25/2001

03:56:46P

-117.348

48.897

-117

20

52.8

t







1 station-old

station-new .

pdop | date time long

lat | deg min | sec deg



BELLA MAY

BELLA MAY

5.1

6/26/2001

01:34:14P

-117.406

48.847

-117

24

21.6

i



BLUE BUCK

BLUE BUCKET

5.5

6/26/2001

12:06:23P

-117.407

48.847

-117

24

25.2

i



DIAMOND R

DIAMOND

2.4

6/26/2001

11:27:12A

-117.42

48.854

-117

25

12

i



FLUME CRE

FLUME CREEK

4.6

6/28/2001

02:42:01P

-117.376

48.876

-117

22

33.6

i



JOPPOISD

JOPPOISD

3.1

6/28/2001

09:33:33A

-117.368

48.883

-117

22

4.8





JOSPOl

JOSPOISW

4.4

6/26/2001

03:09:52P

-117.368

48.883

-117

22

4.8





LEHIGH Ml

LEHIGH #1

6.7

6/26/2001

01:59:39P

-117.406

48.848

-117

24

21.6





LEHIGH TW

LEHIGH #2

2.9

6/26/2001

10:41:55A

-117.417

48.852

-117

25

1.2





METAL1NE

METALINE

4.1

6/26/2001

10:15;07A

-117.392

48.838

-117

23

31.2





ORIOLE Ml

ORIOLE MINE

5.1

6/26/2001

02:45:49P

-117.413

48.86

-117

24

46.8





POBKOl

POBKOISW/SD

3.2

6/27/2001

0l:16:55P

-117.368

48.868

-117

22

4.8





PSTP06SS

PSTP06SS

2.2

6/25/2001

11:52:42A

-117.351

48.881

-117

21

3.6





WASH1NGTO

WASHINGTON

5

6/28/2001

03:10:22P

-117.374

48.866

-117

22

26.4





WEST CONT

WEST CONTACT

4.5

6/26/2001

10:46:33A

-117.417

48.852

-117

25

1.2





YH01

YELLOW HEAD

3.8

6/26/2001

03:58:50P

-117.371

48.877

-117

22

15.6





HOAGEMIN

HOAGE

3.4

6/28/2001

12:24:14P

-117.355

48.938

-117

21

18





KING TUT

KING TUT

5.2

6/28/2001

09:47;33A

-117.188

48.989

-117

11

16.8





LEAD HILL

LEAD HILL

2.9

6/28/2001

09:05:22A

-117.197

48.971

-117

11

49.2





lead king

LEAD KING

3.7

6/28/2001

12:48:48P

-117.36

48.95

-117

21

36





LQ01

LEAD QUEEN

4.6

6/27/2001

04:37:12P

-117.331

48.979

-117

19

51.6





LS01

LUCKY STRIKE

7.1

6/27/2001

0I:lt:47P

-117.332

48.93

-in

19

55.2





RED TOP

RED TOP

4.8

6/28/2001

10:23:36A

-117.181

48.994| -in

1C

51.«



-------
*"*	r ~~

I"•* jG>T,

'k-

APPENDIX D

-1	Si	-g?

t-'S"'"

DATA oijalITY ASSURANCE PJEVIEW MEMORANDUMS

AND ANALYTICAL DAT#FORMS



t^u-

JSffe*



^g|';



10:START-2\01080009\S714

-------
Environmental Services Assistance Team

0357

ESAT Region 10
7411 Beach Drive East
Port Orchard, WA 98366
Phone (360) 871-8723

DELIVERABLE NARRATIVE

August 6,2001

Ginna Grepo-Grove, TOPO, USEPA, Region 10
Dave Dobb, Team Manager, ESAT Region 10 W*

Chris Pace, Data Validation Task Lead, ESAT Region 10 ^

Data Validation Report for the Inorganic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites, Case: 29440 SDG: MJ0ES7

Date:

To;

Through:
From:

SUBJECT:

Account Code: 01T10P50102D106XLA00

Doc.#:	ESI 0-0-1124

TDN:	1048

Task Order:	001

Contract:	68-W-01-027

CC:	Gerald Dodo, PO, USEPA, Region 10

Project File

The quality assurance (QA) review of 18 soil samples collected from the above referenced site has been completed.
These samples were analyzed for total metals by Sentinel, Inc. of Huntsville, AL. The following samples were
reviewed in this validation report:

MJ0ES7	MJ0ET3

MJ0ES8	MJ0ET4

MJ0ES9	MJ0ET5

MJ0ET0	MJ0ET6

MJ0ET1	MJ0ET7

DATA QUALIFICATIONS

MI0ET8

MJ0ET9

MJ0EW0

MJ0EW1

MJ0EW2

MJ0EW3
MJ0EW4
MJ0EW5

The following comments refer to the laboratory performance in meeting the Quality Control Specifications outlined
in the Contract Laboratory Program (CLP) Statement of Work (SOW) for Inorganic Analysis (ILM04.1) and the
USEPA CLP Functional Guidelines for Inorganic Data Review, 2/94.

The conclusions presented herein are based on the information provided for the review.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJ0ES7
ESI0-0-1124 Page 2 of 4

0358

Holding Time - Acceptable

The suggested holding time for mercury is 28 days from the date of sample collection and the holding time for the
rest of the metals is 180 days. The samples were collected on 6/21/01. The samples were analyzed for mercury
within 15 days and all other metals within 19 days of the sample collection date. None of the data were qualified on
this basis.

Sample Preparation - Acceptable

The samples were prepared in accordance with the methods used. None of the data were qualified on this basis.
Initial Calibration - Acceptable

All of the samples were analyzed for total mercury using Cold Vapor Atomic Absorption Spectroscopy (CVAAS).
The initial calibration for mercuiy met the frequency of analysis and the linearity criteria (correlation coefficients,
r=>0.995).

The rest of the target analytes were analyzed using Inductively Coupled Plasma-Atomic Emission Spectroscopy
(ICP-AES). The initial calibration for ICP-AES met the frequency of analysis and the linearity criteria (correlation
coefficients, i=>0.995).	1

None of the data were qualified on this basis.

Calibration Verification - Acceptable

The initial and continuing calibration verifications met the criteria for frequency of analysis and recovery criteria of
90-110% and 80-120% for mercury. The recoveries ranged from 92-109% for ICP-AES and from 82-93% for
mercuiy. None of the data were qualified on this basis.	1

Detection Limits - Acceptable

All of the target analytes met the project required quantitation limits. All of the Contract Required Detection Limit
(CRDL) checks met the frequency of analysis and recovery criteria.

Blanks

Procedural blanks were prepared with the samples to indicate potential contamination from the digestion or
analytical procedure. If an analyte was found in the associated blank, the sample results were qualified as non-
detects, "U", if the analyte concentration is less than five times the analytical value in the blank.

The frequency of analysis of blanks was met. Based on the target analytes detected in the procedural, initial and
continuing calibration blanks, the following results were qualified as non-detects, "U":

Analyte

Associated Samples

sodium

MJ0ET6, MJ0ET9, MJ0EW0, MJ0EW2

thallium

MJ0ES9, MJ0ET0, MJ0ET1, MJ0ET3, MJ0ET4, MJ0ET6,
MJ0ET7, MJ0ET8, MJ0EW0, MJ0EW2, MJ0EW5

Zinc was detected above the CRDL in the preparation blank. None of the sample results were affected.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJ0ES7
ES10-0-1124 Page 3 of 4

ICP-AES Interference Check Sample - Acceptable	0 3

The ICP-AES interference check samples (ICS) were analyzed to verify inter-element and background correction
factors. The frequency of analysis (beginning and end of sequence) and recoveiy criteria (80-120%) were met. The
recoveries ranged from 93-114%. None of the data were qualified on this basis.

ICP-AES Serial Dilution Analysis

Sample MJ0ET9 was analyzed for serial dilution. AH of the analytes which exceeded the minimum concentration
criterion (50 times the IDL) agreed within 10% difference with the exception of potassium. Results for potassium in
all samples were qualified as estimated, "J". The "E" qualifiers applied by the laboratory were crossed-out by the
reviewer.

Laboratory Control Sample - Acceptable

The frequency of analysis and the recoveiy criteria for the laboratory control sample was met The recoveries
ranged from 59-108%. None of the data were qualified on this basis.

Duplicate Sample Analysis - Acceptable

Sample MJ0ET9 was utilized for duplicate analysis. The duplicate results met the frequency of analysis and method
control limit criteria (±20% RPD or ± CRDL) for all target analytes with the exception of copper. Copper did meet
the suggested technical control limit criteria (±35% RPD or ± 2X CRDL) for soils. The qualifiers applied by the
laboratoiy were crossed-out by the reviewer. None of the data were qualified on this basis.

Matrix Spike Analysis

Sample MJ0ET9 was used for the spike analysis. The frequency of analysis and recovery criteria were met with the
exception of antimony (68%), arsenic (171%), copper (243%), mercury (-61%) and selenium (64%) in the spike
sample.MJ0ET9S. Due to possible bias, the detected and non-detected antimony and selenium results in all samples
were qualified as estimated, "J/UJ". Due to possible bias, the detected arsenic and copper results in all samples were
qualified as estimated, "J". Due to possible bias, the detected mercuiy results in all samples were qualified as
estimated, "J". Mercury was detected in all samples. The "N" qualifiers applied by the laboratoiy were crossed-out
by the reviewer. The recoveries for lead and zinc could not be accurately determined because the concentrations
native to the sample were greater than 4 times the amount of spike added to the sample. All of the other spike
recoveries were acceptable and ranged from 94-119%.

Laboratory Contact

The laboratoiy was not contacted for this review.

Overall Assessment

The total number of data points was 414. Fifteen (3.6%) were qualified as non-detected due to blank contamination.
One hundred eight (26%) were qualified as estimated due to ICP serial dilution and spike analyses.

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJ0ES7
ESI 0-0-1124 Page 4 of 4
#¦

DATA QUALIFIERS	0360

U	-	The analyte was not detected at or above the reported result

J	-	The analyte was positively identified. The associated numerical result is an estimate.

R	-	The data are unusable for all purposes

N	-	There is evidence the analyte is present in this sample.

NJ	-	There is evidence that the analyte is present. The associated numerical result is an estimate.

UJ - The analyte was not detected at or above the reported estimated result The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

H - High bias.

Q - The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

K • Unknown Bias.

-------
0381

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	case No.: 2 944 0 SAS No.:	SDG No.: MJ0FK6

Matrix (soil/water): SOIL	Lab Sample ID: 39295S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	94.0

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

Analyte

Cone ent ra t i on

C

Q

M

7429-90-5

Aluminum

1570





p

7440-36-0

Antimony

2.5

3B"

P

7440-38-2

Arsenic

18 .4



p

7440-39-3

Barium

47.1

JB



p

7440-41-7

Beryllium

0.14



p

7440-43-9

Cadmium

4.0





p

7440-70-2

Calcium

262000



f 1L

p

7440-47-3

Chromium

3.9



p

7440-48-4

Cobalt

2.5





p

7440-50-8

Copper

• 21.2

p

7439-89-6

Iron

4220



f Jk

p

7439-92-1

Lead

3010



p

7439-95-4

Magnesium

31000



f TK

p

7439-96-5

Manganese

105





p

7439-97-6

Mercury

0.05

U



CV

7440-02-0

Nickel

73 .9





P

7440-09-7

Potassium

985

%



p

7782-49-2

Selenium

3.1





P

7440-22-4

Silver

0.54

$



p

7440-23-5

Sodium

287





p

7440-28-0

Thallium

1.1

u



P

7440-62-2

Vanadium

43 .8



*1

p

7440-66-6

Zinc

890



p



Cyanide





NR











(/ O't



Color Before: BROWN

Color After:

Comments:

YELLOW

Clarity Before:
Clarity After:

Texture:

Artifacts:

MEDIUM

FORM I

IN

ILM04.1

3

-------
0362

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FK6

Matrix (soil/water) : SOIL	Lab Sample ID: 39296S

Level (low/med) :	LOW	Date Received: 06/30/01

% Solids:	97.3

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

¦

Concentration

C

Q

M

7429-90-5

Aluminum

750





V

7440-36-0

Antimony

1.3

3B"

P

7440-38-2

Arsenic

21.8



P

7440-39-3

Barium

20.2

3B



P

7440-41-7

Beryllium

0. 05

©



P

7440-43-9

Cadmium

34 .2



i _

P

7440-70-2

Calcium

190000



f JL

P

7440-47-3

Chromium

2.0

Mi



P

7440-48-4

Cobalt

1.1

J*



P

7440-50-8

Copper

9.2

t JL

P

7439-89-6

Iron

12400



/ JK

p

7439-92-1

Lead

8100



P

7439-95-4

Magnesium

68500



P

7439-96-5

Manganese

194





P

7439-97-6

Mercury

0.16





CV

7440-02-0

Nickel

20.9

%



p

7440-09-7

Potassium

303 :



p

7782-49-2

Selenium

0.70

u



p

7440-22-4

Silver

0.93





p

7440-23-5

Sodium

364





p

7440-28-0

Thallium

1.1

1?=

a

p

7440-62-2

Vanadium

18.4



ft

p

7440-66-6

Zinc

7420



p



Cyanide





NR















Color Before; BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

Texture:

Artifacts:

MEDIUM

Comments:

FORM I - IN

ILM04.1

-------
0363

EPA' SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract:" 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FK6

Matrix (soil/water): SOIL	Lab Sample ID: 39297S

Level (low/med):	LOW	Date Received: 06/3 0/01

% Solids:	96 . 5

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS NO.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

848





P

7440-36-0

Antimony

2.5



p

7440-38-2

Arsenic

35.1



p

7440-39-3

Barium

29.5

IS



p

7440-41-7

Beryllium

0.05

S"



p

7440-43-9

Cadmium

44 .1



1, _

p

7440-70-2

Calcium

195000



^ JL

p

7440-47-3

Chromium.

. 2.8





p

7440-48-4

Cobalt

1.4 "

%

yrL

p

7440-50-8

Copper

.10.8



p

7439-89-6

Iron

8510



/J a

p

7439-92-1

Lead

6030



p

7439-95-4

Magnesium

62400





p '

7439-96-5

Manganese

196





p

7439-97-6

Mercury

0.19





CV

.7440-02-0

Nickel

33 .6

%



p .

7440-09-7

Potassium

505 :



p

7782-49-2

Selenium

1.7





p

7440-22-4

Silver

0.73"

B



p

7440-23-5

Sodium

397

&

u

p

7440-28-0

Thallium

1.1

&

p

7440-62-2

Vanadium

36. 0



n

p

7440-66-6

Zinc

9300



p

—;—

Cyanide





NR

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

\f f

*

.dl

Texture:

MEDIUM

Artifacts:

Comments:

FORM I - IN

ILM04.1

5

-------
U.S. EPA
1

CLP

INORGANIC ANALYSIS DATA SHEET

0564

EPA SAMPLE NO.

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FK6

Matrix (soil/water): SOIL	Lab Sample ID: 39299S

Level (low/medj: LOW	Date Received: 06/30/01

% Solids:	79.8

Concentration Units (ug/L or mg/Kg dry weight) .* MG/KG

CAS No.

7429

7440

7440

7440

7440

7440

7440

7440

7440

7440

7439

7439

7439

7439

7439

7440-

7440-

7782-

7440-

7440-

7440-

7440-

7440-

-90-5

-36-0

-38-2

-39-3

-41-7

-43-9

-70-2

-47-3

-48-4

-50-8

-89-6

-92-1

-95-4

-96-5

-97-6

-02-0

-09-7

-49-2

•22-4

¦-23-5

•28-0

-62-2

-66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

u

13500

0.71
3.5
296

0.42'}C
0.86p
19100

Q

6
0

22
8

17.0
18100
47.2
3870
989
0
18
2250
0

06
9



84

0.68"®.
386

3
2

1
35
201

U

U

%

u

K

f JL

j* JL

j-Sl
f Tic

M

n

p
p
p
p
p
p
p
p
p
p

p

p
p
p

cv

p
p
p

p
p
p
p
p

NR

Color Before: BROWN
Color After: YELLOW

Clarity Before
Clarity After:



¦ a I

Texture:

Artifacts;

MEDIUM

Comments:

FORM I - IN	ILM04.1

1

-------
Environmental Services Assistance Team q 3 6 5

ESAT Region 10
7411 Beach Drive East
Port Orchard, WA 98366
Phone (360) 871-8723

Date:

To:

Through:

From:

Subject:

deliverable narrative

August 7,2001

Ginna Grepo-Grove, TOPO, USEPA, Region 10

Dave Dobb, Team Manager, ESAT Region 10

Chris Pace, Data Validation Task Lead, ESAT Region 10

Data Validation Report for the Inorganic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites. Case: 29440 SDG: MJ0EN5

Account Code: 01T10P50102D106XLA00

Doc. U:	ESI 0-0-1129

TDN:	1052

Task Order	001

Contract:	68-W-01-027

CC:	Gerald Dodo, PO, USEPA, Region 10

Project File

The quality assurance (QA) review of 20 soil samples collected from the above referenced site has been completed.
These samples were analyzed for total metals by Sentinel, Inc. of Huntsville, AL. The following samples were
reviewed in this validation report:

MJ0EN5
MJ0EN6
MJ0EN7
MJ0EN8
MJ0EN9

MJ0EP0
MJ0EP1
MJ0EP2

MJ0EP3
MJ0EP4

MJ0EP5
MJ0EP6
MJ0EP7
MJ0EP8
MJ0EP9

MJ0EQ0
MJ0EQ1
MJ0EQ2
MJ0EQ3
MJ0EQ4

DATA QUALIFICATIONS

The following comments refer to the laboratory performance in meeting the Quality Control Specifications outlined
in the Contract Laboratory Program (CLP) Statement of Work (SOW) for Inorganic Analysis (ILM04.1) and the
USEPA CLP Functional Guidelines for Inorganic Data Review, 2/94.

The conclusions presented herein are based on the information provided for the review.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJ0EN5
ESI0-0-1129 Page 2 of 4

Holding Time - Acceptable

The suggested holding time for mercury is 28 days from the date of sample collection and the holding time for the
rest of the metals is 180 days. The samples were collected on 6/20/01. The samples were analyzed for mercury
within 7 days and all other metals within 9 days of the sample collection date. None of the data were qualified on
this basis.

Sample Preparation - Acceptable

The samples were prepared in accordance with the methods used. None of the data were qualified on this basis.
Initial Calibration - Acceptable

All of the samples were analyzed for total mercury using Cold Vapor Atomic Absorption Spectroscopy (CVAAS).
The initial calibration for mercury met the frequency of analysis and the linearity criteria (correlation coefficients,
r=>0.995).

The rest of the target analytes were analyzed using Inductively Coupled Plasma-Atomic Emission Spectroscopy
(ICP-AES). The initial calibration for ICP-AES met the frequency of analysis and the linearity criteria (correlation
coefficients, r=>0.995).

None of the data were qualified on this basis.

Calibration Verification - Acceptable

The initial and continuing calibration verifications met the criteria for frequency of analysis and recovery criteria of
90-110% and 80-120% for mercury. The recoveries ranged from 96-110% for ICP-AES and from 82-98% for
mercury. None of the data were qualified on this basis.

Detection Limits • Acceptable

-All of the target analytes met the project required quantitation limits. All of the Contract Required Detection Limit
(CRDL) checks met the frequency of analysis and recovery criteria.

Blanks

Procedural blanks were prepared with the samples to indicate potential contamination from'the digestion or
analytical procedure. If an analyte was found in the associated blank, the sample results were qualified as non-
detects, "U", if the analyte concentration is less than five times the analytical value in the blank.

The frequency of analysis of blanks was met. Based on the target analytes detected in the procedural, initial and
continuing calibration blanks, the following results were qualified as non-detects, "U":

Analyte

Associated Samples

barium

MJ0EN5, MJ0EQ1

chromium

MJ0EN5, MJ0EQ1, MJ0EQ3

nickel

MJ0EN5

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJ0EN5
ESI 0-0-1129 PagQ3^4,

Analytes which yielded a negative response in the preparation blank and/or continuing calibration blank(s) at
concentrations comparable to or less than the absolute value of the blank(s) were qualified as estimated, "JAJJ", due
to possible low bias. The following samples were qualified:

Analyte

Associated Samples

thallium

All

ICP-AES Interference Check Sample - Acceptable

The ICP-AES interference check samples (ICS) were analyzed to verify inter-element and background correction
factors. The frequency of analysis (beginning and end of sequence) and recovery criteria (80-120%) were met. The
recoveries ranged from 89-117%. None of the data were qualified on this basis.

ICP-AES Serial Dilution Analysis

Sample MJ0EP5 was analyzed for serial dilution. All of the analytes which exceeded the minimum concentration
criterion (50 times the IDL) agreed within 10% difference with the exception of copper. Results for copper in all
samples were qualified as estimated, "J". The "E" qualifiers applied by the laboratory were crossed-out by the
reviewer.

Laboratory Control Sample - Acceptable

The frequency of analysis and the recovery criteria for the laboratory control sample was met The recoveries
ranged from 65-117%. None of the data were qualified on this basis.

Duplicate Sample Analysis - Acceptable

Sample MJ0EP5 was utilized for duplicate analysis. The duplicate results met the frequency of analysis and method
control limit criteria for all target analytes. None of the data were qualified on this basis.

Matrix Spike Analysis

Sample MJ0EP5 was used for the spike analysis. The frequency of analysis and recovery criteria were met with the
exception of antimony (46%) in the spike sample MJ0EP5S. Due to possible bias, the detected and non-detected
antimony results in all samples were qualified as estimated, "JAJJ". The "N" qualifiers applied by the laboratory
were crossed-out by the reviewer. The recoveries for lead and zinc could not be accurately determined because the
concentrations native to the sample were greater than 4 times the amount of spike added to the sample. All of the '
other spike recoveries were acceptable and ranged from 93-120%.

Laboratory Contact

The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 460. Six (1.3%) were qualified as non-detected due to blank contamination.
Sixty (17%) were qualified as estimated due to negative blanks, ICP serial dilution and spike analyses.

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

-------
uaia yaiiaauon nepuri - upper ^uiumuiu jumt	uuu

Case No.: 29440 SDG: MJ0EN5
ES10-0-1129 Page 4 of 4

.' .0388

DATA QUALIFIERS

U	-	' The analyte was not detected at or above the reported result,

J	-	The analyte was positively identified. The associated numerical result is an estimate.

R	-	The data are unusable for all purposes.

N	-	There is evidence the analyte is present in this sample.

NJ	-	There is evidence that the analyte is present. The associated numerical result is an estimate.

UJ - The analyte was not detected at or above the reported estimated result. The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

H - High bias.

Q - The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

K - Unknown Bias.

-------
0369

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EQ5

Matrix (soil/water): WATER	Lab Sample ID: 39143S

Level (low/med)	LOW	•	Date Received: 06/29/01

% Solids:	0.0

Concentration Units (ug/L or mg/Kg dry weight) : UG/L

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

168

U



p

7440-36-0

Antimony

3.0

u



p

7440-38.-2

Arsenic

4.0

u



P

7440-39-3

Barium

27.1

5®



p

7440-41-7

Beryllium

0.20

u



p

7440-43-9

Cadmium

0.30

u



p

7440-70-2

Calcium

68300





p

7440-47-3

Chromium

0.70

u



p

7440-48-4

Cobalt

1.1

u



p

7440-50-8

Copper

0.70

u



p

7439-89-6

Iron

54.6

u



p

7439-92-1

Lead

1.5

u



p

7439-95-4

Magnesium

11900

Jb



p

7439-96-5

Manganese

• 1.5



p

7439-97-6

Mercury

0.10

u



cv

7440-02-0

Nickel

1.5

u



p

7440-09-7

Potassium

1410 :

TB

/taTK

p

7782-49-2

Selenium

3.4

u

p

7440-22-4

Silver

0.80

u

p

7440-23-5

Sodium

2300

J£f



p

7440-28-0

Thallium

3.9

u



p

7440-62-2

Vanadium

0.90

u

if

p

7440-66-6

Zinc

2.5

&

p



Cyanide





NR

¦











o I

Color Before,: COLORLESS
Color After: COLORLESS

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts:

Comments

FORM I - IN

ILM04.1

(p

-------
0370

EPA SAMPLE NO,

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract; 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.;	SDG No.: MJ0EQ5

Matrix (soil/water): WATER	Lab Sample ID: 39144S

.Level (low/med) : LOW	Date Received: 06/29/01

% Solids:	0.0

Concentration Units (ug/L or mg/Kg dry weight) : UG/L

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

168

U



p

7440-36-0

Antimony

3.0

U



p

7440-38-2

Arsenic

4.0

U



p

7440-39-3

Barium

69.5

IB



p

7440-41-7

Beryllium

0.20

U



p

7440-43-9

Caidmium

0.36

JF



p

7440-70-2

Calcium

130000





p

7440-47-3

Chromium

0.70

U



p

7440-48-4

Cobalt

1.1

U



p

7440-50-8

Copper

u. 70

u



fl

r

7439-89-6

Iron

54.6

u

u

p

7439-92-1

Lead

1.5

-£1

p

7439-95-4

Magnesium

31200

%



p

7439-96-5

Manganese'

1.2



p

7439-97-6

Mercury

0.10

u



cv

7440-02-0

Nickel

7.9 ;

3B



p

7440-09-7

Potassium

2910

IT

jiuSH

p

7782-49-2

Selenium

3.4

u

p

7440-22-4

Silver

0.80

u

p

7440-23-5

Sodium

3330

*



p

7440-28-0

Thallium

3.9

U



p

7440-62-2

Vanadium

0.90

u



p

7440-66-6

Zinc ¦

63.2



jfr JL

p



Cyanide





NR

Color Before: COLORLESS



-QI

Color After:

COLORLESS

Clarity Before: CLEAR
Clarity After: CLEAR

Texture

Artifacts

Comments:

FORM I - IN	ILM04.1

^f"

-------
0371

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EQ5

Matrix (soil/water): WATER	Lab Sample ID: 39145S

Level (low/med) :	LOW	.	Date Received: 06/29/01

% Solids:	0.0

Concentration Units (ug/L or mg/Kg dry weight) : UG/L

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

168

U



p

7440-36-0

Antimony

3.0

u



p

7440-38-2

Arsenic

4.0

u



p

7440-39-3

Barium

50.1

W



p

7440-41-7

Beryllium

0.20

u



p

7440-43-9

Cadmium

0.30

u



p

7440-70-2

Calcium

84400





p

7440-47-3

Chromium

0. 70

u



p

7440-48-4

Cobalt

1.1

u



p

7440-50-8

Copper

0.70

u



p

7439-89-6

Iron

54.6

u



p

7439-92-1

Lead

1.5

u



p

7439-95-4

Magnesium

15600





p

7439-96-5

Manganese

0.40

u



p 1

7439-97-6

Mercury

0.10

u



CV

7440-02-0

Nickel

1.7 '

IS



p

7440-09-7

Potassium

1740

Jf



p

7782-49-2

Selenium

3.4

u

p

7440-22-4

Silver

0.80

u

p

7440-23-5

Sodium

. 1580

%



p

7440-28-0

Thallium

3.9

u



p

7440-62-2

Vanadium

0.90

u

^ 5L

p

7440-66-6

Zinc

30.6



p .

,

Cyanide





NR















Color Before1: COLORLESS
Color After: COLORLESS
Comments:

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts

FORM I - IN

ILM04.1

-------
U.S. EPA
1

CLP

0372

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract; 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EQ5

Matrix (soil/water) : WATER	,	Lab Sample ID: 39146S

.Level (low/med) : ' LOW	Date Received: 06/29/01 .

% Solids:	o.O

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

195

B



P

7440-36-0

Antimony

3.0

U



P

7440-38-2

Arsenic

4.0

U



P

7440-39-3

Barium

48.5

"o

¦ Jt »



P

7440-41-7

Beryllium

0.20

U



P

7440-43-9

Cadmium

0.30

u



P

7440-70-2

Calcium

84 800





P

7440-47-3

Chromium

0.70

u



P

7440-48-4

Cobalt

1.1

u

..

P

7440-50-8

Copper

0.70

u

P

7439-89-6

Iron

125





P

7439-92-1

Lead

3.2

V



P

7439-95-4

Magnesium

14500



P '

7439-96-5

Manganese

4.5

3S"



P

7439-97-6

Mercury

0.10

u



CV

7440-02-0

Nickel

1.6 '

%



p

7440-09-7

Potassium

1720

js

fulK

p

7782-49-2

Selenium

3.4

u

p

7440-22-4

Silver

0.80

S

p

7440-23-5

Sodium

1520





p

7440-28-0

Thallium

3.9

u



p

7440-62-2

Vanadium

0.90

u

^ JL

p

744 0-66-6

Zinc

36.5



p



Cyanide





NR

_

W F'1

Color Before: COLORLESS
Color After: COLORLESS

Clarity Before:
Clarity After:

CLEAR

CLEAR

' Texture;

Artifacts;

Comments

FORM I - IN

ILM04.1

-------
U.S. EPA
1

CLP

0373

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EQ5

Matrix (soil/water) WATER	Lab Sample ID: 38900S

Level (low/med) : LOW	Date Received: 06/27/01

% Solids:	O.o

Concentration Units (ug/L or mg/Kg dry weight) .» UG/L

CAS No.

Analyte

Concentration

C

Q

M



7429-90-5

Aluminum

168

U



p



7440-36-0

Antimony

3.0

u



p



7440-38-2

Arsenic .

4.0

u



p



7440-39-3

Barium

41.0

3§



p



7440-41-7

Beryllium

0.20

u



p



7440-43-9

Cadmium

0.30

u



p



7440-70-2

Calcium

65600





p



7440-47-3

Chromium

0.70

u



p



7440-48-4 •

Cobalt

1.1

u



p



7440-50-8

Copper

0.70

u



p



7439-89-6

Iron

54.6

u



p



7439-92-1

Lead

2.9



a

p



7439-95-4

Magnesium

35700





p



7439-96-5

Manganese

0.40

u



p



7439-97-6

Mercury

0.10

u



CV



7440-02-0

Nickel

1.6

3B



p



7440-09-7

Potassium

1790

JB



p



7782-49-2

Selenium

3.4

u

p



7440-22-4

Silver'

0.80

u

/

p



7440-23-5

Sodium

1890

¦0



p .



7440-28-0

Thallium

3.9

u



p



7440-62-2

Vanadium

0.90

u

J '

p



7440-66-6

Zinc

575



p





Cyanide





I

NR















I

Color Before: COLORLESS

Iff-*

Color After:

Comments:

COLORLESS

Clarity Before: CLEAR
Clarity After: CLEAR

Texture;

Artifacts:

FORM I - IN

ILM04.1

lcj>

-------
Environmental Services Assistance Team

0574

ESAT Region 10
7411 Beach Drive East
Port Orchard, WA 98366
Phone (360) 871-8723

Date:

To:

Through:

From:

Subject:

DELIVERABLE NARRATIVE

July 31, 2001

Ginna Grepo-Grove, TOPO, USEPA, Region 10

Dave Dobb, Team Manager, ESAT Region 10

Chris Pace, Data Validation Task Lead, ESAT Region 10

Data Validation Report for the Inorganic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites, Case: 29440 SDG: MJ0GM7

Account Code: 01T10P50102D106XLA00

Doc.#:	ES10-0-1116

TDN:	1048

Task Order:	001

Contract:	68-W-01-027

CC:	Gerald Dodo, PO, USEPA, Region 10

Project File

The quality assurance (QA) review of 20 soil samples collected from the above referenced site has been completed.
These samples were analyzed for total metals by Sentinel, Inc. of Huntsville, AL. The following samples were
reviewed in this validation report:

MJ0F18,	MJ0F25

MJ0F19	MJ0F26

MJ0F20	MJ0F27

' MJ0F21	MJ0FK4

MJ0F22	MJ0FK5

DATA QUALIFICATIONS

MJ0GM7

MJ0GM9

MJ0GN0

MJ0GN1

MJ0GN2

MJ0GN3
MJ0GN4
MJ0GN5
MJ0GN6
MJ0GN7

The following comments refer to the laboratory performance in meeting the Quality Control Specifications outlined
in the Contract Laboratory Program (CLP) Statement of Work (SOW) for Inorganic Analysis (ILM04.1) and the
USEPA CLP Functional Guidelines for Inorganic Data Review, 2/94.

The conclusions presented herein are based on the information provided for the review.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJ0GM7
ESI0-0-1116 Page 2 of 4

0375

Holding Time - Acceptable

The suggested holding time for mercury is 28 days from the date of sample collection and the holding time for the
rest of the metals is 180 days. The samples were collected on 6/26, 6/27 and 6/28/01. The samples were analyzed
for mercuiy within 20 days and all other metals within 20 days of the sample collection date. None of the data were
qualified on this basis.

Sample Preparation - Acceptable

The samples were prepared in accordance with the methods used. None of the data were qualified on this basis. .
Initial Calibration - Acceptable

All of the samples were analyzed for total mercuiy using Cold Vapor Atomic Absorption Spectroscopy (CVAAS).
The initial calibration for mercury met the frequency of analysis and the linearity criteria (correlation coefficients,
r=>0.995).

The rest of the target analytes were analyzed using Inductively Coupled Plasma-Atomic Emission Spectroscopy
(1CP-AES). The initial calibration for ICP-AES met the frequency of analysis and the linearity criteria (correlation
coefficients, r=N).995).

None of the data were qualified on this basis.

Calibration Verification - Acceptable

The initial and continuing calibration verifications met the criteria for frequency of analysis and recovery criteria of
90-110% and 80-120% for mercury. The recoveries ranged from 90-107% for ICP-AES and from 84-95% for
mercuiy. None of the data were qualified on this basis.

Detection Limits - Acceptable

All of the target analytes met the project required quantitation limits. All of the Contract Required Detection Limit

(CRDL) checks met the frequency of analysis and recovery criteria.

\

Blanks

Procedural blanks were prepared with the samples to indicate potential contamination from the digestion or
analytical procedure. If an analyte was found in the associated blank, the sample results were qualified as non-
detects, "IP, if the analyte concentration is less than five times the analytical value in the blank.

The frequency of analysis of blanks was met. Based on the target analytes detected in the procedural, initial and
continuing calibration blanks, the following results were qualified as non-detects, "U";

Analyte

Associated Samples

antimony

All except MJ0F19, MJ0GN2

cadmium

MJ0GN5

chromium

MJ0GN2

cobalt

MJ0GN2

selenium

MJ0F21, MJ0GN1, MJ0GN2

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJ0GM7
ES10-0-1116 Page 3 of 4

0 ,75

silver

MJ0F22, MJ0GM7, MJ0GM9 MJOGNO, MJ0GN1, MJ0GN3,
MJ0GN4, MJ0GN5, MJ0GN6, MJ0GN7

ICP-AES Interference Check Sample - Acceptable

The ICP-AES interference check samples (ICS) were analyzed to verify inter-element and background correction
factors. The frequency of analysis (beginning and end of sequence) and recovery criteria (80-120%) were met by all
of the ICS analyzed. The recoveries ranged from 94-119%. None of the data were qualified on this basis.

ICP-AES Serial Dilution Analysis

Sample MJ0GN5 was analyzed for serial dilution. All of the analytes which exceeded the minimum concentration
criterion (50 times the IDL) agreed within 10% difference with the exception of copper. Results for copper in all
samples were qualified as estimated, "J". The "E" qualifiers applied by the laboratory were crossed-out by the
reviewer.

Laboratory Control Sample - Acceptable

The frequency of analysis and the recovery criteria for the laboratory control sample was met The recoveries
ranged from 63-132%. None of the data were qualified on this basis.

Duplicate Sample Analysis - Acceptable

Sample MJ0QN5 was utilized for duplicate analysis. The duplicate results met the frequency of analysis and
method control limit criteria for all target analytes. None of the data were qualified on this basis.

Matrix Spike Analysis - Acceptable

Sample MJ0GN5 was used for the spike analysis. The frequency of analysis and recovery criteria were met All of
the spike recoveries were acceptable and ranged from 76-107%. None of the data were qualified on this basis.

Laboratory Contact

The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 460. Thirty four (7.4%) were qualified as non-detected due to blank
contamination. Twenty (4.3%) were qualified as estimated due to ICP serial dilution analysis.

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

-------
Data Validation Report -

Upper Columbia River Lake Roosevelt/Mines Sites
Case No.: 29440 SDG: MJ0GM7
ES10-0-1116 Page 4 of 4

DATA OUAITFTF.RS

U	-	The analyte was not detected at or above the reported result.

J	-	The analyte was positively identified. The associated numerical result is an estimate.

R	-	The data are unusable for all purposes.

N	-	There is evidence the analyte is present in this sample.

NJ	-	There is evidence that the analyte is present. The associated numerical result is an estimate.

UJ	The analyte was not detected at or above the reported estimated result The associated

numerical value is an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

H - High bias.

Q - The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

K - Unknown Bias.

-------
U.S. EPA - CLP

1

INORGANIC ANALYSIS DATA SHEET

0378

EPA SAMPLE NO.

Lab Name: Sentinel, Inc.
Lab Code: SENTIN	Case No.

Matrix (soil/water): SOIL
Level (low/med);	LOW

% Solids:	83.9

Contract: 68-W-00-085
29440 SAS No.:	SDG No.: MJ0GM7

Lab Sample ID: 39283S
Date Received: 06/30/01

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

7429'
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

•90-5
¦36-0
¦38-2
¦39-3
41-7
¦43-9
70-2

47-3

48-4
50-6
89-6
92-1

95-4

96-5

97-6
02-0
09-7

49-2

22-4

23-5
28-0
62-2
66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

,2
,6

5190
4.1
4.6
234
0.24'
8.5
65000
14
9

7680
301
36400
4210
0,
15,
249
0.

"is



V /i

a

06

7

79

255
1.

10,
784

U

iff

U
U,

4 T /

r - -

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

M

P
P
P
P
P
P
P
P
P

p

P
P
P
P

CV

p

p

p

p

p

p •

p

p

NR



¦V

Texture:

Artifacts:

0

MEDIUM

Comments:

FORM I - IN

ILM04.1

3

-------
0379

EPA SAMPLE NO.

U.S. EPA - CLP

1

INORGANIC ANALYSIS DATA SHEET

Lab Name; Sentinel, Inc.	Contract: 68-W-00-085

Lab Code; SENTIN	Case No.: 29440 SAS No,:	SDG No.: MJQGM7

Matrix (soil/water): SOIL	Lab Sample ID: 39284S

Level (low/med): LOW	Date Received: 06/30/01

% Solids:	58.3

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

9280

tb



P

7440-36-0

Antimony

12.7



P

7440-38-2

Arsenic

13 .8





P

7440-39-3

Barium

123

%



P

7440-41-7

Beryllium

0.38"



P

7440-43-9

Cadmium

27.0





P

7440-70-2

Calcium

51900





P

7440-47-3

Chromium

14 .8





P

7440-48-4

Cobalt

9.8



P

7440-50-8

Copper

71.7



P

7439-89-6

Iron

20900





P

7439-92-1

Lead

714





P

7439-95-4

Magnesium

33200





P «

7439-96-5

Manganese

2230





P

7439-97-6

Mercury

0.09

u



CV

7440-02-0

Nickel

21.1

%



P

7440-09-7

Potassium

531 ' ;



P

7782-49-2

Selenium

1.2

u



P

7440-22-4

Silver

5.6





P

7440-23-5

Sodium

364 "

1&



P

7440-28-0

Thallium

1.7

U



P

7440-62-2

Vanadium

17.1 ;

JB



P

7440-66-6

Zinc

5740





P



Cyanide







NR











Color Before': BROWN
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

Texture: MEDIUM
Artifacts:

FORM I - IN

ILM04.1

4

-------
U.S. EPA
i

CLP

0330

EPS SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	' Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 2944 0 SAS No.:	SDG No.: MJ0GM7

Matrix (soil/water) : SOIL	Lab Sample ID: 39285S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	81,7

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

12900

42



P

7440-36-0

Antimony

1.1

P

7440-38-2

Arsenic

6.7





P

7440-39-3

Barium

374





P

7440-41-7

Beryllium

0.49

B



P

7440-43-9

Cadmium

1.2

10"



P

7440-70-2

Calcium

2460





P.

7440-47-3

Chromium

12.9





P

7440-48-4

Cobalt

12 .0

&

si.TL

P

744Q_5Q_g

Crvrvrsc&ir

wwrrw.

19 = 7



P

7439-89-6

Iron

16700



/

P

7439-92-1

Lead

.22.3





P

7439-95-4

Magnesium

4360





P

7439-96-5

Manganese

4050





P

7439-97-6

Mercury

0.06

u



CV

7440-02-0

Nickel

19.4

3^



p

7440-09-7

Potassium

644



p

7782-49-2

Selenium

0.83

U



p

7440-22-4

Silver

0.92

5



p

7440-23-5

Sodium

251

JB



p

7440-28-0

Thallium

1.2

U



p

7440-62-2

Vanadium

17.9





p

7440-66-6

Zinc

115





p



Cyanide







NR

tf.V

Texture: MEDIUM
Artifacts:

Comments:

FORM I - IN

ILM04.1

-------
U.S. EPA

1

CLP

0331

EPA SAMPLE NO,

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJQGM7

Matrix (soil/water): SOIL	Lab Sample ID: 39291S

Level (low/med): LOW	Date Received: 06/30/01

% Solids:	70.6

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BLACK

Color After;

YELLOW

Clarity Before:
Clarity After:

CAS No.

, Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

476





p

7440-36-0

Antimony

1.8



u

p

7440-38-2

Arsenic .

17.2





p

7440-39-3

Barium

14 .5

r



p

7440-41-7

Beryllium

0.03

u



p

7440-43-9

Cadmium

9.8





p

7440-70-2

Calcium

142000





p

7440-47-3

Chromium

3.0





p

7440-48-4

Cobalt

0.31

u

. jf3 L

p

7440-50-8

Copper

23 ,0



p

7439-89-6

Iron

56800





p

7439-92-1

Lead

351





p

7439-95-4

Magnesium

63400





p i

7439-96-5

Manganese

202

%



p

7439-97-6

Mercury

0.09"



CV

7440-02-0

Nickel

10.3

B



p

7440-09-7

Potassium

164

I



p

7782-49-2

Selenium

0.94

U



p

7440-22-4

Silver

1.7 :

%



p

7440-23-5

Sodium

287

B



p

7440-28-0

Thallium

2.2

r



p

7440-62-2

Vanadium

9.0





p

7440-66-6

Zinc

3320





p



Cyanide







NR

y.

.3>*

-f

Texture:

MEDIUM

Artifacts:

Comments:

FORM I - IN

ILM04.1

l(

-------
U.S. EPA - CLP

1

INORGANIC ANALYSIS DATA SHEET

0382

EPA SAMPLE NO.

MJ0FK5

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GM7

Matrix (soil/water) : SOIL	Lab Sample ID: 39292S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	72.7

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: GREY
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

1430

*



P

7440-36-0

Antimony

1.7



P

7440-38-2

Arsenic

11.8





P

7440-39-3

Barium

25.5

Tfi

J*3



P

7440-41-7

Beryllium

0.10

Jb



P

7440-43-9

Cadmium

14.6





P

7440-70-2

Calcium

175000





P

7440-47-3

Chromium

12 .5

IB-



P

7440-48-4

Cobalt

0.75

t"$L

t

P

7440-50-8

Copper

165



P

7439-89-6

Iron

17000



P

7439-92-1

Lead

1960





P

7439-95-4

Magnesium

57800





P,

7439-96-5

Manganese

254





P

7439-97-6

Mercury

0.39





CV

7440-02-0

Nickel

9.0

IS



p

7440-09-7

Potassium

510

»



p

7782-49-2

Selenium

0.93

U



p

7440-22-4

Silver

0.72

®



p

7440-23-5

Sodium

310

%



p

7440-28-0

Thallium

1.4

U



p

7440-62-2

Vanadium

20.8





p

7440-66-6

Zinc

2610





p



Cyanide







NR

Texture: MEDIUM

Artifacts:

Comments:

FORM I - IN

ILM04.1

IQ

-------
0383

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN Case No.:	29440 . SAS No.: SDG No.: MJ0GM7

Matrix (soil/water): SOIL	Lab Sample ID: 39273S

Level (low/med): LOW	Date Received: 06/3 0/01

% Solids:

70.4

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BROWN
Color After: YELLOW

Clarity Before
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

8400





P

7440-36-0

Antimony

1.1



M

P

7440-38-2

Arsenic

5.2





P

7440-39-3

Barium

110





P

7440-41-7

Beryllium

0.36

TB



P

7440-43-9

Cadmium

1.6





P

7440-70-2

Calcium

14600





P

7440-47-3

Chromium

25.5





P

7440-48-4

Cobalt

5.5 ;

56"

L

P

7440-50-8

Copper

84 . 0

P

7439-89-6

Iron

16600



P

7439-92-1

Lead

449





P

7439-95-4

Magnesium

10400





P

7439-96-5

Manganese

313





P ,

7439-97-6

Mercury

0.07

u



cv

7440-02-0

Nickel

12 .3





p

7440-09-7

Potassium

1560





p

7782-49-2

Selenium

0.97

u

U

p

7440-22-4 .

Silver

0.72



p

7440-23-5

Sodium

393

&



p

7440-28-0

Thallium

1.4

u



p

'7440-62-2

Vanadium

20.1





p

7440-66-6

Zinc

864





p



Cyanide







NR





Texture:

Artifacts:

MEDIUM

Comment s:

FORM I - IN

ILM04.1

-------
U.S. EPA
1

CLP

0384

EPA SAMPLE NO

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GM7

Matrix (soil/water) : SOIL	Lab Sample ID: 39274S

Level (low/med) : LOW	•	Date Received: 06/30/01

% Solids:	45.9

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before': BROWN
Color After: YELLOW

Clarity Before
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

11100





P

7440-36-0

Antimony

2.3

u

P

7440-38-2

Arsenic

16 .3





P

7440-39-3

Barium

183





P

7440-41-7

Beryllium

0.53

%



P

7440-43-9

Cadmium

0.57"





P

7440-70-2

Calcium

21500





P

7440-47-3

Chromium

17.6





P

7440-48-4

Cobalt

8.2

%



P

7440-50-8

Copper

25 .9



P

7439-89-6

Iron

27000



P

7439-92-1

Lead

35.7





P

7439-95-4

Magnesium

8910





P

7439-96-5

Manganese

921





P '

7439-97-6

Mercury

0.10

U



cv

7440-02-0

Nickel

20.9





p

7440-09-7

Potassium

2020



p

7782-49-2

Selenium

1.5

u



p

7440-22-4

Silver

1.4



U

p

7440-23-5

Sodium

548





p

7440-28-0

Thallium

2.2

U



p

7440-62-2

Vanadium

28 .3





p

7440-66-6

Zinc

287





p

¦

Cyanide







NR



-i

Texture:

MEDIUM

Artifacts

Comments:

FORM I - IN

ILM04.1

-------
U.S. EPA - CLP
1-

INORGANIC ANALYSIS DATA SHEET

0585

EPA' SAMPLE NO.

Lab Name: Sentinel, Inc.

Lab Code: SENTIN	Case No.: 29440

Matrix (soil/water): SOIL

Level (low/med); LOW

% Solids:	61.0

Contract: 68-W-00-085

SAS No.:	SDG No.: MJ0GM7

Lab Sample ID: 39275S
Date Received: 06/30/01

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

7429-90-5

Aluminum

7440-36-0

Antimony

7440-38-2

Arsenic

7440-39-3

Barium

7440-41-7

Beryllium

7440-43-9

Cadmium

7440-70-2

Calcium

7440-47-3

Chromium

7440-48-4

Cobalt

7440-50-8

Copper

7439-89-6

Iron

7439-92-1

Lead-

7439-95-4

Magnesium

7439-96-5

Manganese

7439-97-6

Mercury

7440-02-0

Nickel

,7440-09-7

Potassium

7782-49-2

Selenium

7440-22-4

Silver

7440-23-5

Sodium

7440-28-0

Thallium

7440-62-2

Vanadium

7440-66-6

Zinc



Cyanide

Cone ent rat i on

5720
1.4

#

2.8 W
57.8
0.15
19

.1
5
1

0

1390
10

6
8

15900

7

2.410
198
0
17
760
1.1
0.71
284
1.7
15.6
60.9

.08
.4

fl

M

14



u

u
IA

t®

p
p
p
p
p
p
p
p
p

p
p
p

cv

p

p

p

p

p

p

p

p

NR

Color Before; BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

Texture; MEDIUM

Artifacts:

Comments

FORM I - IN	ILM04.1

!5~

-------
U.S. EPA
1

"CLP

0386

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GM7

Matrix (soil/water) : SOIL	Lab Sample ID: 39276S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	67.2

Concentration Units {ug/L or mg/Kg dry weight) : MG/KG

CAS No.

7429-
7440-
7440*
7440-
7440-
7440-
7440-
7440-
7440-

n a a n _

/ n w -

7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5
•36-0
-38-2
•39-3
•41-7
-43-9
•70-2
•47-3
-48-4

. c n _ o

mJ ~

89-6
-92-1

95-4

96-5

97-6
02-0
09-7
49-2

22-4

23-5
28-0
62-2
66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Concentration

Iron
Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

2620
0.99
2.3
44 ,2
0.10
0.98
3610

6.2

2.3
4 , 3

6700

4 .6
1200
107
0.07
12.5
405

1.4
0.40

360

1.5
17.4
59.8

¦3

m

IB

%

U

-]6~

u



M



u

p
p
p
p
p
p
p
p
p
B

P
P
P

CV

P

P

P

p

p

p

p

p

NR

1/



Color Before: BLACK
Color After: YELLOW
Comments:



Clarity Before:
Clarity After:

Texture:

Artifacts;

MEDIUM

FORM I - IN	ILM04.1

i(j

-------
U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

0387

EPA SAMPLE NO.

MJ0GN2

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GM7

Matrix (soil/water): SOIL	Lab Sample ID: 39277S

Level (low/med); LOW	Date Received: 06/30/01

% Solids:	90.8

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: GREY
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum•

213

Jb



P

7440-36-0

Ant imony

5.2



P

7440-38-2

Arsenic

6.7





P

7440-39-3

Barium

31.6

JB



P

7440-41-7

Beryllium

0.02

U



P

7440-43-9

Cadmium

9.6





P

7440-70-2

Calcium

290000





P

7440-47-3

Chromium

0.86

te

¦H

P '

7440-48-4

Cobalt

0.29



4

¥ 52-

P

7440-50-8

Copper

6.6

*

P

7439-89-6

Iron

807





P

7439-92-1

Lead

17400





P

7439-95-4

Magnesium

10800





P

7439-96-5

Manganese

79.3





P

7439-97-6

Mercury

0.16





CV

7440-02-0

Nickel

5.0

SB



P

7440-09-7

Potassium

98.1 '

jB



P

7782-49-2

Selenium

1.3



u

P

7440-22-4

Silver

2.3





P

7440-23-5

Sodium

250

JB



P

7440-28-0

Thallium

1.1

U



P

7440-62-2

Vanadium

8.6

JB



P

7440-66-6

line

2040





P



Cyanide







NR

u



Texture:

Artifacts:

COARSE

Comment s:

FORM I - IN

ILM04.1

n•

-------
U.S. EPA - CLP
1 .

0388

lj r~.rv

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GM7

Matrix (soil/water) : SOIL	Lab Sample ID: 39278S

Level Uow/med) :	LOW	Date Received: 06/30/01

% Solids:	79.0

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

8950





P

7440-36-0

Antimony

0.98

IA

P

7440-38-2

Arsenic

4.8





P

7440-39-3

Barium

33 .2

£



P

7440-41-7

Beryllium

0.16

B



P

7440-43-9

Cadmium

0 . 94

©



P

7440-70-2

Calcium

42400





P

7440-47-3

Chromium

18.3

tb



P

7440-48-4

Cobalt

9.2

i "SL

P

7440-50-8

rnnnp.r .

-Tf	

17.5



P

7439-89-6

Iron

25900



f

P

7439-92-1

Lead

19.0





P

7439-95-4

Magnesium

8510





Pi

7439-96-5

Manganese

437





P

7439-97-6

Mercury

0.06

u



CV

7440-02-0

Nickel

26.3

%



p

7440-09-7

Potassium

403



p

7782-49-2

Selenium

0.86

u

IA

p

7440-22-4

Silver

0.84



p

7440-23-5

Sodium

249





p

7440-28-0

Thallium

1.3

u



p

7440-62-2

Vanadium

12.2

JB



p

7440-66-6

Zinc

263





p



Cyanide







NR

tfr

Texture:

Artifacts:

MEDIUM

Comment s:

FORM I - IN	ILM04.1

id

-------
0389

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GM7

Matrix (soil/water): SOIL	Lab Sample ID: 39279S

Level (low/med):	LOW	Date Received: 06/30/01

% Solids:	79.8

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before': BROWN

Color After

YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

5930





p

7440-36-0

Antimony

1.7

M

p

7440-38-2

Arsenic

6.0





p

7440-39-3

Barium

49.7 "

JB



p

7440-41-7

Beryllium

0.17

IB



p

7440-43-9

Cadmium

0 . 80





p

7440-70-2

Calcium

30500





p

7440-47-3

Chromium

14 .4

5B"



p

7440-48-4

Cobalt

5.5 "

yj7-

p

7440-50-8

Copper

16.0



p

7439-89-6

Iron

13600



p

7439-92-1

Lead

86.8





p

7439-95-4

Magnesium

18700





p 1

7439-96-5

Manganese

427





p

7439-97-6

Mercury

0.06

U



cv

7440-02-0

Nickel

14 .2

%



p

7440-09-7

Potassium

985



p

7782-49-2

Selenium

0.85

u



p

7440-22-4

Silver

0.57



a

p

7440-23-5

Sodium

314





p

7440-28-0

Thallium

1.3.

u



p

7440-62-2

Vanadium

25 .4





p

7440-66-6

Zinc

261





p



Cyanide







NR



.01

Texture:

Artifacts:

MEDIUM

Comment s:

FORM I - IN

ILM04.1

-------
0390

Ed& csmdt.i? wn

i. ri uni ii	.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No".: MJ0GM7

Matrix (soil/water) : SOIL	Lab Sample ID: 39280S

Level (low/med) :	LOW	Date Received: 06/30/01

% Solids:	77.1

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

,Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

6020





p

7440-36-0

Antimony

1.0

p

7440-38-2

Arsenic

5.2





p

7440-39-3

Barium

59.9

36"



p

7440-41-7

Beryllium

0.18



p

7440-43-9

Cadmium

0.20



U

p

7440-70-2

Calcium

17500





p

7440-47-3

Chromium

13 .2





p

7440-48-4

Cobalt

4.8

%

i? l

p

7440-50-8

Copper

17.5



p

7439-89-6

Iron

12500



p

7439-92-1

Lead

7.3





p

7439-95-4

Magnesium

9100





P-,

11

7439-96-5

Manganese

243





p

7439-97-6

Mercury

0.07

u



CV

7440-02-0

Nickel

13.3

%



p

7440-09-7

Potassium

1260



p

7782-49-2

Selenium

0.88

u



p

7440-22-4

Silver

0.56

3

p

7440-23-5

Sodium

372





p

7440-28-0

Thallium

1.3

u



p

7440-62-2

Vanadium

29.5





p

7440-66-6

Zinc

49.7





p



Cyanide







NR

(/

1

.y

'ol

Texture:

Artifacts

MEDIUM

Comments:

FORM I - IN	ILM04.1

<30

-------
U.S. EPA
1

'CLP

0391

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, .Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GM7

_ Matrix (soil/water): SOIL	Lab Sample ID: 39281S

Level (low/med): LOW	Date Received: 06/30/01

% Solids:	76.6

Concentration Units (ug/L or mg/Kg dry weight); MG/KG

CAS No.

7429-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5
•36-0
¦38-2
39-3
-41-7
43-9
70-2

47-3

48-4
50-8
89-6
92-1

95-4

96-5

97-6
02-0
09-^

49-2

22-4

23-5
28-0
62-2
66-6

Analyte

Concentration

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide



8350
1.0
5.3
102

0.27tB
0 .25pEf
15900
17.9
7.6

22.4
17000

10.5
9180

429

0.06 U
16.8
1600

0.88 U
0.83
328

1.3 U
32.5
74 .1

-------
U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

0S92

EPA SAMPLE NO,

MJ0GN7

.Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG NO.: MJ0GM7

Matrix (soil/water) : SOIL	Lab Sample ID: 39282S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	84.2

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

7429-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

•90-5
•36-0
•38-2
•39-3
-41-7
•43-9
70-2

47-3

48-4
50 = 8
89-6
92-1

95-4

96-5

97-6
02-0
09-7

49-2

22-4

23-5
28-0
62-2
66-6

Analyte

Aluminum
Antimony
Arsenic
Barium
Beryllium
Cadmium
Calcium
Chromium
Cobalt
	

Iron
Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

6770

0.911®,
5.3
72.4
0.20JJB
0.26 fpr
20400

.4
.8
.3

16
6
19
14200
8.7
9450
345
0.05
15.0
1260
0.81
0.64
336
1.2
30.8
53.4

:]T

u

u

u

Q

u

is L

M

H

p
p
p
p
p
p
p
p
p
p
p
p
p
p

cv

p
p
p
p
p
p
p
p

NR

¦W

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

Texture:
Artifacts:

.y-

ol

MEDIUM

Comments:

FORM I - IN

ILM04.1

-------
Environmental Services Assistance Team

ESAT Region 10
7411 Beach Drive East
Port Orchard, WA 98366
Phone (360)871-8723

DELIVERABLE NARRATIVE

Date:	July 30,2001

To:	Ginna Grepo-Grove, TOPO, USEPA, Region 10

Through: Dave Dobb, Team Manager, ESAT Region 10

FROM:	Chris Pace, Data Validation Task Lead, ESAT Region 10

SUBJECT: Data Validation Report for the Inorganic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites. Case: 29440 SDG: MJ0FJ0

Account Code: 01T10P50102D106XLA00

Doc.#:	ES10-0-1114

TDN:	1048

Task Order:	001

Contract:	68-W-01-027

CC:	Gerald Dodo, PO, USEPA, Region 10

Project File

The quality assurance (QA) review of 19 soil samples collected from the above referenced site has been completed.
These samples were analyzed for total metals by Sentinel, Inc. of Huntsville, AL. The following samples were
reviewed in this validation report:

MJ0EZ6	MJ0F0I	MJ0F08	MJ0FJ1

MJ0EZ7	MJ0F02	MJ0F09	MJ0FJ2

MJ0EZ8	MJ0F03	MJ0F14	MJ0FJ3

\ MJ0EZ9	MJ0F04	MJ0F16	MJ0FJ4

MJ0F00	MJ0F05	MJ0FJ0

DATA QUALIFICATIONS

The following comments refer to the laboratory performance in meeting the Quality Control Specifications outlined'
in the Contract Laboratory Program (CLP) Statement of Work (SOW) for Inorganic Analysis (ILM04.1) and the
USEPA CLP Functional Guidelines for Inorganic Data Review, 2/94.

The conclusions presented herein are based on the information provided for the review.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJOFJO
ES10-0-1114 Page 2 of 4

^ f\ <

U a 3 l

Holding Time - Acceptable

The suggested holding time for mercury is 28 days from the date of sample collection and the holding time for the
rest of the metals is 180 days. The samples were collected on 6/18, 6/24, 6/25, 6/26 and 6/27/01. The samples were
analyzed for mercury within 18 days and all other metals within 22 days of the sample collection date. None of the
data were qualified on this basis.

Sample Preparation - Acceptable

The samples were prepared in accordance with the methods used. None of the data were qualified on this basis.
Initial Calibration - Acceptable

All of the samples were analyzed for total mercuiy using Cold Vapor Atomic Absorption Spectroscopy (CVAAS).
The initial calibration for mercuiy met the frequency of analysis and the linearity criteria (correlation coefficients,
r=>0.995).

The rest of the target analytes were analyzed using Inductively Coupled Plasma-Atomic Emission Spectroscopy
(ICP-AES). The initial calibration for ICP-AES met the frequency of analysis and the linearity criteria (correlation
coefficients, r=>0.995).

None of the data were qualified on this basis.

Calibration Verification - Acceptable

The initial anH! continuing C3!ibr3tion vsriflcsticns rsct the criteria for frequency of smslysis sud recovery cntsns of
90-110% and 80-120% for mercury. The recoveries ranged from 91-109% for ICP-AES and from 81-89% for
mercury. None of the data were qualified on this basis.

Detection Limits - Acceptable

All of the target analytes met the project required quantitation limits. All of the Contract Required Detection Limit
(CRDL) checks met the frequency of analysis and recoveiy criteria.

Blanks

Procedural blanks were prepared with the samples to indicate potential contamination from the digestion or
analytical procedure. If an analyte was found in the associated blank, the sample results were qualified as non-
detects, "U", if the analyte concentration is less than five times the analytical value in the blank.

The frequency of analysis of blanks was met. Based on the target analytes detected in the procedural, initial and
continuing calibration blanks, the following results were qualified as non-detects, "U":

Analyte

Associated Samples

arsenic

MJ0EZ8, MJ0F08, MJ0F09, MJ0F14, MJ0F16

sodium

MJ0EZ7, MJ0EZ9, MJ0F00, MJ0F02, MJ0F03, MJ0F04,
MJ0F05, MJ0F08, MJ0F09, MJ0F14, MJ0F16, MJ0J2, MJ0J3

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJOFJO
ESI0-0-1114 Page 3 of4

0335

Analytes which yielded a negative response in the preparation blank and/or continuing calibration blank(s) at
concentrations comparable to or less than the absolute value of the blank(s) were qualified as estimated, "J/UJ", due
to possible low bias. The following samples were qualified:

Analyte

Associated Samples

thallium

All except MJ0FJ2

ICP-AES Interference Check Sample - Acceptable

The ICP-AES interference check samples (ICS) were analyzed to verily inter-element and background correction
factors. The frequency of analysis (beginning and end of sequence) and recovery criteria (80-120%) were met by all
of the ICS analyzed. The recoveries ranged from 86-116%, None of the data were qualified on this basis.

ICP-AES Serial Dilution Analysis

Sample MJ0E26 was analyzed for serial dilution. All of the analytes which exceeded the minimum concentration
criterion (50 times the DDL) agreed within 10% difference with the exception of copper. Results for copper in all
samples were qualified as estimated, "J". The "E" qualifiers applied by the laboratory were crossed-out by the
reviewer.

Laboratory Control Sample - Acceptable

The frequency of analysis and the recovery criteria for the laboratory control sample was met The recoveries . .
ranged from 70-154%. None of the data were qualified on this basis.

Duplicate Sample Analysis - Acceptable

Sample MJ0EZ6 was utilized for duplicate analysis. The duplicate results met the frequency of analysis and method
control limit criteria (±20% RPD or ± CRDL) for all target analytes with the exception of lead. Lead did meet the
suggested technical control limit criteria (±35% RPD or ± 2X CRDL) for soils. The qualifiers applied by the
laboratory were crossed-out by the reviewer. None of the data were qualified on this basis.

Matrix Spike Analysis

Sample MJ0EZ6 was used for the spike analysis. The frequency of analysis and recovery criteria were met with the
exception of antimony (45%) and zinc (142%) in the spike sample MJ0EZ6S. Due to possible bias, the detected and
non-detected antimony results in all samples were qualified as estimated, "J/UJ". Due to possible bias, the detected
zinc results in all samples were qualified as estimated, "J". The "N" qualifiers applied by the laboratory were
crossed-out by the reviewer. The recoveries for lead and manganese could not be accurately determined because the
concentrations native to the sample were greater than 4 times the amount of spike added to the sample. All of the
other spike recoveries were acceptable and ranged from 77-105%.

-------
Data Validation Report • Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDC: MJOFJO
ESI0-0-] 114 Page4 of4

Laboratory Contact	0 6 9 6

The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 437. Eighteen (4.1%) were qualified as non-detected due to blank
contamination. Seventy five (17%) were qualified as estimated due to negative blanks, ICP serial dilution and spike
analyses.

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

DATA QUALIFIERS

The analyte was not detected at or above the reported result
The analyte was positively identified. The associated numerical result is an estimate.

The data are unusable for all purposes.

There is evidence the analyte is present in this sample.

There is evidence that the analyte is present. The associated numerical result is an estimate.

The analyte was not detected at or above the reported estimated result. The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

Low bias.

High bias.

The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

Unknown Bias.

U
J
R
N

NJ -
UJ

L

H ?
\ Q

K

-------
U.S. EPA
1

CLP

0397

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water) : SOIL	Lab Sample ID: 39148S

Level (low/med) :	LOW	Date Received: 06/29/01

% Solids:	82.3

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

325





p

7440-36-0

Antimony

2.5

M

p

7440-38-2

Arsenic

20.6

SB

p

7440-39-3

Barium

20.3 C



p

7440-41-7

Beryllium

0.05

U



p

7440-43-9

Cadmium

15.0





p

7440-70-2

Calcium

182000





p

7440-47-3

Chromium

10.4

IB



p

7440-48-4

Cobalt

0.65'

fJL

p

7440-50-8

Copper

176



p

7439-89-6

Iron

32000



p

7439-92-1

Lead

680



4

p

7439-95-4

Magnesium

74300





p1

7439-96-5

Manganese

228





p

7439-97-6

Mercury

0.25

W



CV

7440-02-0

Nickel

9.6



p

7440-09-7

Potassium

195

%



p

7782-49-2

Selenium

0.83

u



p

7440-22-4

Silver

0.65

ir



p

7440-23-5

Sodium

129





p

7440-28-0

Thallium

0.95

u

uSK

p

7440-62-2

Vanadium

7.2

13

ft ~SH

p

7440-66-6

Zinc

4130



p



Cyanide





NR

Color Before: GREY
Color After: YELLOW

Clarity Before:
Clarity After:

-------
0338

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	case No.: 2944 0 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water) : SOIL	Lab Sample ID: 39149S

Level (low/med).: LOW	Date Received: 06/29/01

% Solids:	71.3

Concentration Units (ug/L or mg/Kg dry weight) r MG/KG

CAS No.

7429-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440r
7440-
7440-

-90-5
-36-0
-38-2
-39-3
•41-7
•43-9
•70-2

47-3

48-4
50-8
89-6
92-1

95-4

96-5

97-6
02-0
09-7

49-2

22-4

23-5
28-0
62-2
66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

8080
0

•' 5,
71.
0,
0.

16900
19.

8.
27.

15900

9.
8460

310
0.
18.
1340
0.

0.
250

1.
36.
67.

.1
,1
26
08

2
0
6

07
9

94

c

Q

M





P

u

pJk

P



a

P





P





P

u



P





P





P

'36"



P



dSL

P



#

P



/

P





P .





P

u



CV





P

*



P

u



P

s



P

1b



P

u

iatk

P,





P
P



NR

Color Before: BROWN
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

Pi

Texture:
Artifacts:

MEDIUM

FORM I - IN

1LM04.1

-------
U.S. EPA
1

CLP

0399

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN Case No.:	29440 SAS No.: SDG No.: MJ0FJ0

Matrix (soil/water) : SOIL .	Lab Sample ID: 3915OS

Level (low/med) : LOW	Date Received: 06/29/01
% Solids: 75.4

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

7429
7440'
7440'
744 0 ¦
7440-
7440-
7440-
7440-
7440-
7440-
7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5
-36-0
-38-2
-39-3
-41-7
-43-9
¦70-2
-47-3
•48-4
•50-8
89-6
•92-1
•¦95-4

96-5

97-6
02-0
09-7
49-2

22-4

23-5
28-0
62-2
€6-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

^ Jr Xr w

Iron
Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

"JT

4680

1.1
18.9
70.4

0.14^

9.2
94100

13
3

58.
37800
467
42300
279

0.
15.

665
0 .

1.
193

1.
24.
2190

9
3
3



16
1

90
1

0
0

w

u

;5B"
?&¦'
u



M

/

WTK
$TH

p

p
p
p
p
p
p
p
p
p
p
p
p
p

cv

p
p
p
p
p
p
p
p

NR

>/ •

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

f

Texture:

Artifacts;

MEDIUM

Comments:

FORM I - IN	ILM04.1

-------
0400

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJOFJO

Matrix (soil/water): SOIL	Lab Sample ID: 39151S

Level (low/med) :	LOW	Date Received: 06/29/01

% Solids:	86.7

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

¦ Analyte

Concentration

C

9

M



7429-90-5

Aluminum

146





P



7440-36-0

Antimony

1.5

36-

P



7440-38-2

Arsenic

19.8



P



7440-39-3

Barium

8.7

%



P



7440-41-7

Beryl Hum

0.05

U



P



7440-43-9

Cadmium

8.5





P



7440-70-2

Calcium

152000





P



7440-47-3

Chromium

3.9





P



7440-48-4

Cobalt

0.25

U

"d XL

T "

P



n ii u a r a a

/11U-3V-O

Ccpp€ir

on n

^ V • V



p



7439-89-6

Iron

62700





P



7439-92-1

Lead

666



i

P



7439-95-4

Magnesium

97400





P'



7439-96-5

Manganese

220





P



7439-97-6

Mercury

0.15





cv



7440-02-0

Nickel

20.0





p



7440-09-7

Potassium

74 .3

%



p



7782-49-2

Selenium

0 .78

u



p



7440-22-4

Silver

0.98

)B



p



7440-23-5

Sodium

95.3



U

p



7440-28-0

Thallium

0.89

U

MTK

p



7440-62-2

Vanadium

3.7 .

%



p



7440-66-6

Zinc

1590

p



—	

Cyanide





NR



Of

Color Before: GREY
Color After: YELLOW

Clarity Before:
Clarity After:

?

,3"

.0

Texture:

Artifacts:

MEDIUM

Comments:

FORM I - IN

ILM04.1

Tr

-------
U.S. EPA
1

CLP

0401

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJOFJO

Matrix (soil/water): SOIL	Lab Sample ID: 39152S

Level (low/med):	LOW	Date Received: 06/29/01

% Solids: .	94.4

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BLACK
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concent ra t i on

C

Q

M

7429-90-5

Aluminum

312





p~

7440-36-0

Antimony

2.1

n

p

7440-38-2

Arsenic

40.0

JB

p

7440-39-3

Barium

7.8"



p

7440-41-7

Beryllium

0.04

U



p

7440-43-9

Cadmium

8.2





p

7440-70-2

Calcium

117000





p

7440-47-3

Chromium

2.7





p

7440-48-4

Cobalt

0.23

U

4 J L

p

7440-50-8

Copper

40.3



p

7439-89-6

Iron

171000





p

7439-92-1

Lead

1650



i

p

7439-95-4

Magnesium

70800





p

7439-96-5

Manganese

214





p

7439-97-6

Mercury

0.10





CV

7440-02-0

Nickel

21.4

%



p

,7440-09-7

Potassium

87.7 ;



p

7782-49-2

Selenium

0.71

U



p

7440-22-4

Silver

2.3





p

7440-23-5

Sodium

27.5

u

.utK

p

7440-28-0

Thallium

0.82

U

p

7440-62-2

Vanadium

5.1 ;

p

tijtf

p

7440-66-6

Zinc

2500

p

¦

Cyanide





1

NR

(/-V

„-5c'

Texture:

Artifacts:

MEDIUM

Comments:

FORM I - IN

ILM04.1

-------
U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

0402

EPA SAMPLE NO.

MJ0F02

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water): SOIL	Lab Sample ID: 39153S

Level (low/med) : LOW	Date Received: 06/29/01

% Solids:	78.6

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

, Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

243





p

7440-36-0

Antimony

1.6

%

p

7440-38-2

Arsenic

20.8

TS



p

7440-39-3

Barium

10.0



p

7440-41-7

Beryllium

0.05

u



p

7440-43-9

Cadmium

11.9.





p

7440-70-2

Calcium

148000





p •

7440-47-3

Chromium

7.1





p

7440-48-4

Cobalt

0.28

u

iJL

t

p

7440-50-8

Copper

178



p

7439-89-6

Iron

60800



p

7439-92-1

Lead

818



1

p

7439-95-4

Magnesium

91800





Pi

7439-96-5

Manganese

236





p

7439-97-6

Mercury

0.18





cv

7440-02-0.

Nickel

16.6





p

7440-09-7

Potassium

134 :

)B



p

7782-49-2

Selenium

0.87

U



p

7440-22-4

Silver

1.3 :

IS



p

7440-23-5

Sodium

146



U .

p

7440-28-0

Thallium

0.99

u

utK

p

7440-62-2

Vanadium

9.0

r



p

7440-66-6

Zinc

2520



p

1

Cyanide





NR













J&{

Color Before: BROWN
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

Texture:

Artifacts;

MEDIUM

FORM I - IN

ILM04.1

-------
0403

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water): SOIL	Lab Sample ID: 39326S

Level (low/med):	LOW	Date Received: 06/29/01

% Solids:	75.4

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

7429
7440
7440
7440
7440
7440
7440
7440
7440
7440
7439
7439
7439
7439

7439

7440
7440
7782'
7440-
7440-
7440-
7440-
7440-

-90-5
-36-0
-38-2
-39-3
-41-7
-43-9
-70-2
-47-3
-48-4
-50-8
-89-6
-92-1
-95-4
-96-5
-97-6
-02-0
-09-7
-49-2
-22-4
-23-5
-28-0
-62-2
-66-6

Color Before: BROWN
Color After: YELLOW

Analyte

Aluminum

Ant imony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Cone ent rat i on

if

?

,30'

Clarity Before:
Clarity After:

Texture:

MEDIUM

Artifacts:

Comment s:

FORM I - IN

ILM04.1

-------
U.S. EPA
1

CLP

INORGANIC ANALYSIS DATA SHEET

0404

EPA SAMPLE NO.
MJ0F04

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJOFJO

Matrix (soil/water): SOIL	Lab Sample ID: 39154S

Level (low/med) :	LOW	Date Received: 06/29/01

% Solids:.	81.8

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

,Analyte

Cone ent ra t i on

C

Q

M

7429-90-5

Aluminum

293



^-3'ijfr

P

7440-36-0

Antimony

1.5

%

P

7440-38-2

Arsenic

22.4

%

P

7440-39-3

Barium

10.2



P

7440-41-7

Beryllium

0.05

U



P

7440-43-9

Cadmium

20.1





P

7440-70-2

Calcium

156000





P

7440-47-3

Chromium

8.0





P

7440-48-4

Cobalt

0.27

u

/

P

7440-50-8

Copper

113



P

7439-89-6

Iron

61100



P

7439-92-1

Lead

1000



/

P

7439-95-4

Magnesium

81800





P

7439-96-5

Manganese

208





P

7439-97-6

Mercury

0.25





CV

7440-02-0

Nickel

13 .7





P

7440-09-7

Potassium

156

Tb



P

7782-49-2

Selenium

0.82

u



P

7440-22-4

Silver

1.1 :

0



P

7440-23-5

Sodium

' 82.6



usK

P

7440-28-0

Thallium

0.94

U

P

7440-62-2

Vanadium

7.6

&

ySH

P

7440-66-6

Zinc

4540



P



Cyanide





NR











Color Before: BROWN

Color After;

YELLOW

Clarity Before;
Clarity After:

3®

.D/

Texture;

MEDIUM

Artifacts,*

Comments

FORM I - IN

ILM04.1

n

-------
0405

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 6 8-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water): SOIL	Lab Sample ID: 39155S

Level (low/med):	LOW	Date Received: 06/29/01

% Solids:	83.4

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

222

%



P

7440-36-0

Antimony

1.5 "

P

7440-38-2

Arsenic

21.1

IB

P

7440-39-3

Barium

8.9



P

7440-41-7

Beryllium

0.05

U



P

7440-43-9

Cadmium

10.4





P

7440-70-2

Calcium

158000





P

7440-47-3

Chromium

7.2





P

7440-48-4

Cobalt

0 .26

U

4 JL

i

P

7440-50-8

Copper

88 . 0



P

7439-89-6

Iron

56000



P

7439-92-1

Lead

919



/

P

7439-95-4

Magnesium

.73300





P

7439-96-5

Manganese

184





P

7439-97-6

Mercury

0.16





CV

7440-02-0

Nickel

13 .7





P

7440-09-7

Potassium

145 '

JB



P

7782-49-2

Selenium

0.80

U



P

7440-22-4

Silver

0.92:

5b



P

7440-23-5

Sodium

108

in

M

P

,7440-28-0

Thallium

0.92

u



P

7440-62-2

Vanadium

7.6

JB



P

7440-66-6

Zinc

2270



P



Cyanide





NR
	

Color Before: BROWN
Color After: YELLOW



.3'

>0/

Clarity Before
Clarity After:

Texture:

Artifacts:

MEDIUM

Comments:

FORM I - IN

ILM04.1

ia

-------
U.S. EPA
1

CLP

0406

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 2944 0 SAS No..-	SDG No.: MJOFJO

Matrix (soil/water) : SOIL	Lab Sample ID: 39156S

Level (low/med) : LOW	Date Received: 06/29/01

% Solids:	57,1

Concentration Units (ug/L or nig/Kg dry weight) : MG/KG

CAS No.

, Analyte

Concentration

C

Q

M.

7429-90-5

Aluminum

2100





P

7440-36-0

Antimony

1.0

U

P

7440-38-2

Arsenic

7.6



4

P

7440-39-3

Barium

44.2

&



P

7440-41-7

Beryllium

0.10

JB



P

7440-43-9

Cadmium

3.5





P

7440-70-2

Calcium

115000





P

7440-47-3

Chromium

9.2





P

7440-48-4

Cobalt

1.7 '

%

HL

(

i

P

7440-50-8

Pftrmer

— —-jrxr	

22.5

P

7439-89-6

Iron

613 0



P

7439-92-1

Lead

180



/

P

7439-95-4

Magnesium

35500





Pi

7439-96-5

Manganese

455





P

7439-97-6

Mercury

0.11

JB



cv

7440-02-0

Nickel

44 .8





p

7440-09-7

Potassium

373

JB-



p

7782-49-2

Selenium

1.2

U



p

7440-22-4

Silver

0.28

U



p

7440-23-5

Sodium

177



W

p

7440-28-0

Thallium

1.4

u



p

7440-62-2

Vanadium

26 .8





p

7440-66-6

Zinc

326



p



Cyanide





NR



.»/

Color Before.* BLACK
Color After: YELLOW

Clarity Before;
Clarity After:

Texture .-
Artifacts:

MEDIUM

Comments:

FORM I - IN

ILM04.1

-------
0407

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water): SOIL	Lab Sample ID: 39157S

Level (low/med):	LOW	Date Received: 06/29/01

% Solids:	69.7

Concentration Units (ug/L or mg/.Kg dry weight) : MG/KG

CAS No.

Analyte

Concentration

c

Q

M

7429-90-5

Aluminum

2960



tfuJK

P

7440-36-0

Antimony

0.86

U

P

7440-38-2

Arsenic

4.7



U

P

7440-39-3

Barium

48.6

f



P

7440-41-7

Beryllium

0 .10





P

7440-43-9

Cadmium

1.4

%



P

7440-70-2

Calcium

202000





P

7440-47-3

Chromium

5.7

Jb



P

7440-48-4

Cobalt

2.8 "

tSL

P

7440-50-8

Copper

9.2



P

7439-89-6

Iron

8120





P

7439-92-1

Lead

6.8



i

P

7439-95-4

Magnesium

7090





P

7439-96-5

Manganese

211





P

7439-97-6

Mercury

0.07

u



CV

7440-02-0

Nickel

13 .8





P

7440-09-7

Potassium

293 :

3B



P

7782-49-2

Selenium

0.98

U



P

7440-22-4

Silver

0.23

U



P

7440-23-5

Sodium

152



U .

P

7440-28-0

Thallium

1.1



u yk

P

7440-62-2

Vanadium

11.9

JB



P

7440-66-6

Zinc

65.2



P



Cyanide





NR

'









Color Before:, GREY
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

l/C t

-T

f

Texture:

MEDIUM

Artifacts

FORM I - IN	ILM04.1

W

-------
U.S. EPA

1

CLP

0408

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 2 944 0 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water): SOIL	Lab Sample ID: 39158S

Level (low/med) :	LOW	Date Received: 06/29/01

% Solids:	38.7

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

Analyte

Concentrat ion

C

7429-90-5

Aluminum

6760



7440-36-0

Antimony

1.5

u

7440-38-2 .

Arsenic

9.1



7440-39-3

Barium

114

%

7440-41-7

Beryllium

0.28'

7440-43-9

Cadmium

2.8



7440-70-2

Calcium

35400



7440-47-3

Chromium

11.9



7440-48-4

Cobalt

4.5 :

%

7440-50-0

Copper

23.0



7439-89-6

Iron

12000



7439-92-1

Lead

72.5



7439-95-4

Magnesium

8730



7439-96-5

Manganese

194



7439-97-6

Mercury

0.13

u

7440-02-0

Nickel

44.9

&

7440-09-7

Potassium

915

7782-49-2

Selenium

1.7

u

7440-22-4

Silver

0.65'

it"

7440-23-5

Sodium

231



7440-28-0

Thallium

2.0



7440-62-2

Vanadium

19.7



7440-66-6

Zinc

560



¦

Cyanide





Color Before: BLACK
Color After: YELLOW

Clarity Before.-
Clarity After:

i>l

MEDIUM

Artifacts:

Comments:

FORM I - IN

ILM04.1

-------
0409

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0FJ0

Matrix (soil/water): SOIL	Lab Sample ID: 39159S

Level (low/med):	LOW	Date Received: 06/29/01

% Solids:	84.9

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

7429

7440

7440-

7440-

7440-

7440-

7440-

7440-

7440-

7440-

7439-

7439-

.7439-

7439-

7439-

7440-
7440-
7.782-
7440-
7440-
7440-
7440-
7440-

-90-5
-36-0
-38-2
-39-3
-41-7
-43-9
-70-2
-47-3
-48-4
-50-8
-89-6
-92-1
-95-4
-96-5
-97-6
-02-0
-09-7
-49-2
-22-4
-23-5
-28-0
-62-2
66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium
Manganese
Mercury
Nickel
Potassium
Selenium
Silver
Sodium
Thallium
Vanadium
Zinc
Cyanide

Concentration C

3640

0.70 u jrtuJK

3.6	U
59'° X—1

0 .13T5B

1.7

B

70500
6.5,

4.4
8.9
9540
59.9
32200
341
0.05

17.3
392

0.79
0.30$f
106

0.93. U.

11.4	JjB
329

jtSL

1

u

'IB
U

M

a?K



M

P
P
P
P
P
P
P
P
P
P
P
P

P 1
P

CV

P

P

P

P

P

P

P

P

NR

Color Before: BROWN
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

(fr

D/

Texture:

Artifacts:

MEDIUM

FORM I - IN	ILM04.1

ICJ)

-------
Environmental Services Assistance Team

0410

ESAT Region 10
7411 Beach Drive East
Port Orchard, WA 98366
Phone(360) 871-8723

Date:

To:

Through:

From:

Subject:

DELIVERABLE NARRATIVE

August 3,2001

Ginna Grepo-Grove, TOPO, USEPA, Region 10

DaveDobb, Team Manager, ESAT Region 10

Chris Pace, Data Validation Task Lead, ESAT Region 10

Data Validation Report for the Inorganic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites. Case: 29440 SDG: MJ0GL0

Account Code: 01T10P50102D106XLA00

Doc.#:	ES10-0-II2I

TDN:	1048

Task Order.	001

Contract:	68-W-01-027

CC:	Gerald Dodo, PO, USEPA Region 10

Project File

The quality assurance (QA) review of 10 water samples collected from the above referenced site has been
completed. These samples were analyzed for total metals by Sentinel, Inc. of Huntsville, AL.' The following
samples were reviewed in this validation report:

MJOFll	MJ0GM4

MJ0FKS*	MJ0GM6

MJ0GL0	MJ0GM8

\ MJ0GL9	MJ0GN8

MJ0GM1	MJ0GN9

DATA QUALIFICATIONS

The following comments refer to the laboratory performance in meeting the Quality Control Specifications outlined
in the Contract Laboratoiy Program (CLP) Statement of Work (SOW) for Inorganic Analysis (ILM04.1) and the
USEPA CLP Functional Guidelines for Inorganic Data Review, 2/94.

The conclusions presented herein are based on the information provided for the review.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJOGLO
ES10-0-1121 Page 2 of 4

04H

Holding Time - Acceptable

The suggested holding time for mercury is 28 days from the date of sample collection and the holding time for the
rest of the metals is 180 days. The samples were collected on 6/25,6/26, 6/27 and 6/28/01, The samples were
analyzed for mercury within 16 days and all other metals within 17 days of the sample collection date. None of the
data were qualified on this basis.

Sample Preparation - Acceptable

The samples were prepared in accordance with the methods used. None of the data were qualified on this basis.

Initial Calibration - Acceptable

All of the samples were analyzed for total mercury using Cold Vapor Atomic Absorption Spectroscopy (CVAAS).
The initial calibration for mercury met the frequency of analysis and the linearity criteria (correlation coefficients,
r^>0.995).

The rest of the target analytes were analyzed using Inductively Coupled Plasma-Atomic Emission Spectroscopy
(ICP-AES). The initial calibration for ICP-AES met the frequency of analysis and the linearity criteria (correlation
coefficients, r=>0.995).

None of the data were qualified on this basis.

Calibration Verification - Acceptable

The initial and continuing calibration verifications met the criteria for frequency of analysis and recovery criteria of
90-110% and 80-120% for mercury. The recoveries ranged from 94-110% for ICP-AES and from 92-103% for
mercury. None of the data were qualified on this basis.	1

Detection Limits - Acceptable

!

All of the target analytes met the project required quantitation limits. All of the Contract Required Detection Limit
(CRDL) checks met the frequency of analysis and recovery criteria.

Blanks

Procedural blanks were prepared with the samples to indicate potential contamination from the digestion or
analytical procedure. If an analyte was found in the associated blank, the sample results were qualified as non-
detects, "U", if the analyte concentration is less than five times the analytical value in the blank.

The frequency of analysis of blanks was met. Based on the target analytes detected in the procedural, initial and
continuing calibration blanks, the following results were qualified as non-detects, "U":

Analyte

Associated Samples

iron

MJ0FK9, MJOGLO, MJ0GM8, MJ0GN9

sodium

All

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: MJOGLO
ES10-0-1121 Page 3 of 4

04

Analytes which yielded a negative response in the preparation blank and/or continuing calibration blank(s) at
concentrations comparable to or less than the absolute value of the blank(s) were qualified as estimated, "J/UJ", due
to possible low bias. The following samples were qualified:

Analyte

Associated Samples

silver

All

copper

MJ0F17, MJ0FK9, MJ0GN9 f

ICP-AES Interference Check Sample - Acceptable

The ICP-AES interference check samples (ICS) were analyzed to verify inter-element and background correction
factors. The frequency of analysis (beginning and end of sequence) and recovery criteria (80-120%) were met by all
of the ICS analyzed. The recoveries ranged from 82-119%. None of the data were qualified on this basis.

ICP-AES Serial Dilution Analysis

Sample MJOGLO was analyzed for serial dilution. All of the analytes which exceeded the minimum concentration
criterion (50 times the IDL) agreed within 10% difference with the exception of potassium. Results for potassium in
all samples were qualified as estimated, "J". The "E" qualifiers applied by the laboratory were crossed-out by the
reviewer.

Laboratory Control Sample - Acceptable

The frequency of analysis and the recovery criteria for the laboratory control sample was met. The recoveries
ranged from 98-114%. None of the data were qualified on this basis.

i

Duplicate Sample Analysis - Acceptable

Sample MJOGLO was utilized for duplicate analysis. The duplicate results met the frequency of analysis and method
control limit criteria for all target analytes. None of the data were qualified on this basis.

Matrix Spike Analysis - Acceptable

Sample MJOGLO was used for the spike analysis. The frequency of analysis and recovery criteria were met. All of
the spike recoveries were acceptable and ranged from 90-103%. None of the data were qualified on this basis.

Laboratory Contact

The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 230. Fifteen (6.5%) were qualified as non-detect due to blank contamination.
Twenty three (10%) were qualified as estimated due to negative blanks and ICP serial dilution analysis.

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

-------
Data Validation Report -

Upper Columbia River Lake Roosevelt/Mines Sites
Case No.: 29440 SDG: MJOGLO
ES10-0-1121 Page 4 of 4

DATA QUALIFIERS	0413

U	-	The analyte was not detected at or above the reported result.

J	-	The analyte was positively identified. The associated numerical result is an estimate.

R	-	The data are unusable for all purposes.

N	-	There is evidence the analyte is present in this sample.

NJ	-	There is evidence that the analyte is present. The associated numerical result is an estimate.

UJ - The analyte was not detected at or above the reported estimated result. The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

H - High bias.

Q - The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

K - Unknown Bias.

-------
U.S. EPA - CLP

0414

10

INSTRUMENT DETECTION LIMITS (QUARTERLY)

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJOGLO

ICP ID Number:	P3	Date: 04/15/01

Flame AA ID Number:

Furnace AA ID Number:



Wave-













length

Back-

CRDL

IDL





Analyte

1 (nm)

ground

(ug/L)

(ug/L)

M



Aluminum

308.20



200

68.2

P



Antimony

206.80



60

2.5

P



Arsenic

189.00



10

2.6

P



Barium

493.40



200

0.7

P



Beryllium

313.00



5

0.3

P



Cadmium

226.50



5

0.6

P



Calcium

317.90



5000

25.6

P



Chromium

267.70



10

0.6

P



Cobalt

228.60



50

1.0

P



Copper

324.70



« f

*1

. X . \J ¦

T"* .

r*



Iron

271.40



100

14 .6

p



Lead

220.30



3

2.8

p



Magnesium

279.00



5000

27.0

p



Manganese

257.60



15

0.3

p



Mercury





0.2



NR



Nickel

231.60



40

1.1

P



Potassium

766.40



5000

11.7

P



Selenium

196.00



5

2.0

P



Silver

328.00



10

0.5

P



Sodium

330.20



5000

474.3

P



Thallium

190.80



10

3.4

P



Vanadium

292.40



50

1.0

P



Zinc

206.20



20

0.6

P



Cyanide





10



NR



Comments:

P3: THERMO JARRELL ASH

FORM X - IN

ILM04.1

-------
U.S. EPA - CLP	04i5

10

INSTRUMENT DETECTION LIMITS (QUARTERLY)

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN '	Case No.: 29440 SAS No.:	SDG No.: MJ0GL0

ICP ID Number:	Date: 04/15/01

Flame AA ID Number: C5
Furnace AA ID Number:

Analyte

Wave-
length
(nm)

Back-
ground

CRDL
(ug/L)

IDL
(ug/L)

M



Aluminum





200



NR



Antimony





60



NR



Arsenic





10



NR



Barium





200



NR



Beryllium





5



NR



Cadmium





5



NR



Calcium





5000



NR



Chromium





10



NR



Cobalt





50



NR



Copper





25



NR



Iron





100



NR



Lead





3



NR



Magnesium





5000



NR



Manganese





15



NR



Mercury

253 .70



0.2

0.1

CV



Nickel





40



NR



Potassium





5000



NR



Selenium





5



NR



Silver





10



NR



Sodium





5000



NR



Thallium





10



NR



Vanadium





50



NR



Zinc





20



NR



Cyanide





10



NR



Comments:

C5: CETAC M6000

FORM X - IN

ILM04.1

-------
U.S. EPA- CLP

0416

13

PREPARATION LOG

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GL0

Method: P

i

EPA
Sample No.

Preparation
Date

Weight
(gram)

Volume
(mL)

LCSW

MJ0FI7

MJ0FK9

MJ0GL0

MJ0GL0D

MJ0GL0S

MJ0GL9

MJOGMI

MJ0GM4

MJ0GM6

MJ0GM8

MJ0GN8

MJ0GN9

PBW

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01



50

SO

50

50

50

50

50

50

50

50

50

50

50

50

















































" "







"



































































































•



FORM XIII - IN		ILM04 .1

2>(

-------
U.S. EPA - 'CLP

13	, 0 411

PREPARATION LOG

Lab Name: Sentinel, Inc.	Contract; 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GL0

Method: CV

EPA
Sample No.

Preparation
Date

Weight
(gram)

Volume
(mL)

MJ0F17

MJ0FK9

MJ0GL0

MJ0GL0D

MJ0GL0S

MJ0GL9

MJ0GM1

MJ0GM4

MJ0GM6

MJ0GM8

MJ0GN8

MJ0GN9

PBW

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01

07/10/01



100
100
100
100
100
100
100
100
100
100
100
100
100















































'

















« '







%















































'





,



































¦





FORM XIII - IN

ILM04.1

35

-------
0413

EPA SAMPLE NO,

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name; Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	- SDG No.: MJ0GL0

Matrix (soil/water): WATER	Lab Sample ID: 39293S

Level (low/med) : LOW •	•	Date Received: 06/30/01

% Solids:	0.0

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

7429'
7440 ¦
7440-
7440'
7440-
7440-
7440-
7440-
7440-
7440-
7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

•90-5
-36-0
¦38-2
•39-3
¦41-7
43-9
70-2

47-3

48-4
50-8
89-6
92-1

95-4

96-5

97-6
02-0
09-7

49-2

22-4

23-5
28-0
62-2
66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Pnnnpr

	XT C	¦

Iron
Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium ,

Thallium

Vanadium

Zinc

Cyanide

Concentration

114
2 .

'• 2,

20.8 j)B*
30
3

U

0.

1.

18900

0.60
1.0

1.0
14.6

3.0
9530

0.75:p"
0.10

1.1
740

2.0
0.50
3000
3.4
1.0
102

Q

M

ksk

u

u ulK
&14,

U

u

p
p
P

p

p
p
p

p

p
p

p
p

p,

p

cv

p
MP
p
p
p
p
p
p

NR



ol

Color Before: COLORLESS
Color After: COLORLESS

Clarity Before: CLEAR
Clarity After: CLEAR

Texture;

Artifacts:

Comments;

FORM I - IN	ILM04.1

3

-------
0419

EPA SAMPLE NO.

U.S. EPA - 'CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GL0

Matrix (soil/water) : WATER	Lab Sample ID: 39294S

Level (low/med) :	LOW	Date Received: 06/30/01

% Solids:	0.0

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

7429-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7440-
7439-
7439-
7439-
7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5
•36-0
•38-2
¦39-3
•41-7
•43-9
70-2

47-3

48-4
50-8
89-6
92-1

95-4

96-5

97-6
02-0
09-7

49-2

22-4

23-5
28-0
62-2
66-6

Color Before- COLORLESS
Color After: COLORLESS

Analyte

Aluminum

Ant imony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration C

134

2.5

2.6
54.3

0.30
0.87

137000

0

1
1

82
21
46400

1
0
8

2290

2
0

2990
3.4
1.0
117

JB
U

¦f

u,
p

60

0
2

1
5

U
U

:ib



l
10
4

0

50

u

u
u

p$H
u
u



M

P
P
P
P
P
P
P
P
P
P
P
P

P ;
P

CV

P

P

P

P

P

P

P

P

NR

l/ ^

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts:

Comments:

FORM I - IN

ILM04.1

1

-------
U.S. EPA
1

'CLP

INORGANIC ANALYSIS DATA SHEET

0420

EPA SAMPLE NO.

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab code: SENTIN	Case No.: 2 944 0 SAS No.:	SDG No.: MJOGLO

Matrix (soil/water): WATER	Lab Sample ID: 3 9253S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	0.0

Concentration Units (ug/L or mg/Kg dry weight) : UG/L

CAS No.

7429
7440
7440
7440
7440
7440
7440
7440
7440
7440
7439
7439
7439
7439'
7439'
7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5

-36-0

-38-2

-39-3

-41-7

-43-9

-70-2

-47-3

-48-4

-50-8

-89-6

-92-1

-95-4

-96-5

-97-6

-02-0

-09-7

-49-2

-22-4

-23-5

-28-0

-62-2

-66-6

Color Before': COLORLESS
Color After: COLORLESS

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts:

Comments

FORM I - IN

ILM04.1

-------
0421

EPA SAMPLE NO.

U.S. EPA - 'CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, inc.	Contract: 68-W-0Q-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GL0

Matrix (soil/water): WATER	Lab Sample ID: 39254S

Level (low/med) : LOW	,	Date Received:. 06/30/01

% Solids :	O.'O

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

125 ;

51"



P

7440-36-0

Antimony

2.5

u



P

7440-38-2

Arsenic

' 2.6

u



P

7440-39-3

Barium

58.5 :

0



P

7440-41-7

Beryllium

0.30

u



P

7440-43-9

Cadmium

0.60

u



P

7440-70-2

Calcium

89400





P

7440-47-3

Chromium

0.60

V



P

7440-48-4

Cobalt

1.0

V



P

7440-50-8

Copper

1.2 '

%



P

7439-89-6

Iron

409





P

7439-92-1

Lead

9.3





P

7439-95-4

Magnesium

29000





P ,

7439-96-5

Manganese

33 . 0





P

7439-97-6

Mercury

0.10

u



cv

7440-02-0

Nickel

1.1

u



p

'7440-09-7

Potassium

2540 '

]B



p

7782-49-2

Selenium

2.0

U

p

7440-22-4

Silver

0.50

U

UlJK

p

7440-23-5

Sodium

2570 <

W

u

p

7440-28-0

Thallium

3-.4 :

m



p

7440-62-2

Vanadium

1.0

u



p

7440-66-6

Zinc

62.5





p



Cyanide







NR

Color Before- COLORLESS
Color After: COLORLESS

(ff.-i

,f>\

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts:

Comments:

FORM I - IN

ILM04.1

fcP

-------
U.S. EPA
1

'CLP

INORGANIC ANALYSIS DATA SHEET

0422

EPA SAMPLE NO.
MJOGM1

Lab Name: Sentinel, inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJOGLO

Matrix (soil/water): WATER	Lab Sample ID: 392S6S

Level (low/med) : LOW	.	Date Received: 06/30/01

% Solids;	,0.0

Concentration Units (ug/L or mg/Kg dry weight) : UG/L

1

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

150

%



p

7440-36-0

Antimony

2.5

U



p

7440-38-2

Arsenic

2.6

IL



p

7440-39-3

Barium

62.6.

%



p

7440-41-7

Beryllium

0.30

U



p

7440-43-9

Cadmium

0.60

u



p

7440-70-2

Calcium

20100





p

7440-47-3

Chromium

0 .60

u



p

7440-48-4

Cobalt

1.0

u



p

.7440-50-8

Copper

1.0

u



p

7439-89-6

Iron

107





p

7439-92-1

Lead

2.8

u



p

7439-95-4

Magnesium

5230





p

7439-96-5

Manganese

10 ;

IS



p

7439-97-6

Mercury

0.10

u



CV

7440-02-0

Nickel,

1.1

u

$-3

p

7440-09-7

Potassium

873



p

7782-49-2

Selenium

2.0

u

p

7440-22-4

Silver

0.50

u

uTK

p

7440-23-5

Sodium

4340



'U

p

7440-28-0

Thallium

3.4

u



p

7440-62-2

Vanadium

1.0

u



p

7440-66-6

Zinc

4.4 '

r



p



Cyanide





NR

Cf-

."5



Color Before: COLORLESS

Color After:

COLORLESS

Clarity Before: CLEAR
Clarity After: CLEAR

Texture;

Artifacts:

Comments:

FORM I - IN

ILM04.1

-------
0423

EPA- SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN Case No.: 29440 SAS No.:	SDG No.: MJ0GL0

Matrix (soil/water): WATER	Lab Sample ID: 39257S

Level (low/med) : LOW	Date Repeived: 06/30/01

% Solids:

0.0

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

• Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

156 :

iS



P

7440-36-0

Antimony

2.5 v

u



P

7440-38-2

Arsenic

2.6

u



P

7440-39-3

Barium

58.2





P

7440-41-7

Beryllium

0.30

u



P

7440-43-9

Cadmium

0.60

u



P

7440-70-2

Calcium

18300





P

7440-47-3

Chromium

0.60

u



P

7440-48-4

Cobalt

1.0

u



P

7440-50-8

Copper

1.0

u



P

7439-89-6

Iron

103





P

7439-92-1

Lead

2.8

u



P

7439-95-4

Magnesium

4840

P



P .

j

7439-96-5

Manganese

11.1 "

56



P

7439-97-6

Mercury

0 .10

u



cv

7440-02-0

Nickel

1.1

u



p

7440-09-7

Potassium

799 ;

F

p

7782-49-2

Selenium

2.0

u

p

7440-22-4

Silver

0.50

u

U.TK

p

7440-23-5

Sodium

2730

&

'U

p

7440-28-0

Thallium

3.4

u



p

7440-62-2

Vanadium

1.0

U



p

7440-66-6

Zinc

5.5 C

%



p

'

Cyanide







NR

Color Before: COLORLESS
Color After: COLORLESS

e/f

.%¦



Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts:

Comments:

FORM I - IN

ILM04.1

8

-------
U.S. EPA - CLP
1

INORGANIC, ANALYSIS DATA SHEET

0424

EPA' SAMPLE NO.

MJ0GM6

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No. : 29440 SAS No.:	SDG No.; MJ0GL0

Matrix (soil/water): WATER	Lab Sample ID: 39255S

Level (low/med) : LOW	'	Date Received: 06/30/01

% Solids:	o.O

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

7429

7440

7440

7440

7440

7440

7440

7440

7440

7440

7439'

7439'

7439'

7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5

-36-0

-38-2

-39-3

-41-7

-43-9

-70-2

-47-3

-48-4

-50-8

-89-6

-92-1

-95-4

-96-5

-97-6

-02-0

-09-7

-49-2

-22-4

•23-5

-28-0

•62-2

•66-6

Color Before: COLORLESS
Color After: COLORLESS

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts;

Comments:

ILM04.1

-------
U.S. EPA - "CLP
1

¦ 04?K

¦ c. o

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN Case No.:	29440 SAS No.: SDG No.: MJ0GL0

Matrix (soil/water): WATER	Lab Sample ID: 39258S

Level (low/med) : LOW	Date Received: 06/3 0/01

% Solids:

0.0

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

7429

7440

7440

7440

7440

7440

7440

7440

7440

7440

7439

7439

7439

7439

7439'

7440'

7440'

7782-

7440-

7440-

7440-

7440-

7440-

-90-5
-36-0
-38-2
-39-3
-41-7
-43-9
-70-2
-47-3
-48-4
-50-8
-89-6
-92-1
-95-4
-96-5
-97-6
-02-0
-09-7
-49-2
-22-4
-23-5
-28-0
-62-2
-66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

104

2.5

2.6

57.3 'W
0.30 U
0.60 U
18700

0 .60

1.0

1.3
53 .7

2.8
4950

7.7	$3"
0.10

1.1
792

2.0
0.50
4160

3.4

1.0 la

2.8	'jB

U

U

u

¥\
u

u

M

U

u

aSK

U

k.

p
p
p
p
p
p
p
p
p
p
p
p
p

p :

cv

p
'p
p
p
p
p
p
p

NR

¦Cf

y

Color Before: COLORLESS
Color After: COLORLESS
Comments:

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts:

FORM I - IN

ILM04.1

\
-------
042 G

U.S. EPA -'CLP
1

INORGANIC ANALYSIS DATA SHEET

EPA SAMPLE NO.

MJ0GN8

Lab Name: Sentinel, Inc.	Contract; 68-W-00-085.

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0GL0

Matrix {soil/water) : WATER	Lab Sample ID: 39259S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	0.0

Concentration Units (ug/L or mg/Kg dry weight): UG/L

CAS No.

7429

7440

7440

7440'

7440-

7440-

7440-

7440-

7440-

7440-

7439-

7439-

7439-

7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5
-36-0
-38-2
-39-3
-41-7
¦43-9
70-2
•47-3

48-4
i>0-8
89-6
•92-1

95-4

96-5

97-6
02-0
09-7

49-2

22-4

23-5
28-0
62-2
66-6

Analyte

Aluminum
Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

112

2.5

2.6
13.2

0.30
0.60
24500

0.60
1.0

0b

u
u

w

u
u

u
u

Tt

M

44 .4
2.8
8900

6.0	"JjB
0.10

1.1
792

2.0
0.50
2200
3 .4
1.0

1^<4

U

U
U

W

u
u

u

ii

MTK

pu
u

3.9 ;0"

P
P
P
P
P
P
P
P
P

p

P
P
P
P

cv

p

p

p

p

p

p

p

p

NR

(/ r

y

Color Before: COLORLESS
Color After: COLORLESS
Comments:

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:
Artifacts;

FORM I - IN	ILM04.1

-------
U.S. EPA
1

"CLP

0428

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.
Lab Code: SENTIN	Case No.

Matrix (soil/water): WATER
Level (low/med):	LOW

% Solids:	0.0

Contract: 68-W-00-085
29440 SAS No.:	SDG No

MJ0GL0
Lab Sample ID: 39260S
Date Received: 06/30/01

Concentration Units (ug/L or nig/Kg dry weight) ; UG/L

CAS No.

Analyte

Concentration

C

0

M

7429-90-5

Aluminum

149 :

)B



P

7440-36-0

Antimony

2.5

U



P

7440-38-2

Arsenic .

2.6

U



P

7440-39-3

Barium

14.7 *

%



P

7440-41-7

Beryllium

0.30

u



P

7440-43-9

Cadmium

0.60

u



P

7440-70-2

Calcium

27300





P

7440-47-3

Chromium

0.60

u



P

7440-48-4

Cobalt

1.0

u

ulK

P

7440-50-8

Copper

1.0

u

P

7439-89-6

Iron

34.8

)®fc



P

7439-92-1

Lead

2.8

u

P

7439-95-4

Magnesium

9560





P 1

7439-96-5

Manganese

3.7 •

JS



P

7439-97-6

Mercury

o.io'

u



CV

7440-02-0

Nickel

1.1

u



P

7440-09-7

Potassium

889

IB

KP

7782-49-2

Selenium

2.0

u

P

7440-22-4

Silver

0.50

u

UTK

P

7440-23-5

Sodium

2790

p



P

7440-28-0

Thallium

3.4

u



p

7440-62-2

Vanadium

1.6 v





P

7440-66-6

Zinc

0.65

m



P



Cyanide







NR



Color Before: COLORLESS
Color After: COLORLESS

Comments:

Clarity Before: CLEAR
Clarity After: CLEAR

Texture:

Artifacts:

FORM I - IN	ILM04.1

-------
i

• 0429

MEMORANDUM

DATE: November 6, 2001

TO: Leatta Dahiboff, Project Manager, E & E, Seattle, WA
FROM:	Mark Woodke, Chemist, E & E, Seattle, WA

SUBJ: Inorganic Data Summary Check, Upper Columbia River Mines/Mills ESI,
Stevens and Pend Oreille Counties, Washington

REF: TDD: 01-02-0028 PAN: 001281.0073.01SR

The data quality summary check of 3 water and 11 solid samples collected from the
Upper Columbia River Mines/Mills ESI, Stevens and Pend Oreille Counties, Washington has
been completed. Target Analyte List metals analysis (EPA CLP SOW ILM04.1) was performed
by Sentinel, Inc., Huntsville, Alabama.

¦	The samples were numbered:

MJ0KD3 MJ0KK0 MJ0KK3 MJ0KK6 MJ0KK9 MJQKH!
MJ0KK1 MJ0KK4 MJ0KK7 MJ0KL0	MJ0KH6 MJ0KK2

MJ0KK5 MJ0KK8

The following discrepancy was noted:

Sample MJ0KK6 was identified as MJ0KK4 in the last section of the memorandum;
sample qualifications were applied correctly,, therefore no action was taken.

All sample results originally qualified "B" by the laboratory to indicate a result less than
the CRDL were changed to "JBK" by the secondary reviewer to indicate an estimated quantity
less than the CRDL with an unknown bias.

-------
¦JSL'v	0130

AXi72 I	UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

~	REGION 10

.	1200 Sixth Avenue

Seattle, Washington 98101

IN REPLY

REFER TO: OEA-0 95	November 1, 2 0 01

MEMORANDUM

SUBJECT: Upper Columbia River/ESI Mines and Mills, CLP Metals
Analysis, Data Validation
Case: 29730
SDG: MJ0KD3

FROM:	Laura Castrilli, Chemist

Quality Assurance and Data Unit, OEA

TO:	Monica Tonel, Site Assessment Manager

Office of Environmental Cleanup

CC:	Bruce Woods, Region 10 CLP TPO

Mark Woodke, Ecology and Environment Inc.

The following is a validation of ICP-AES and mercury analyses of
eleven soil/sediment and three water samples from the Upper Columbia
River/ESI Mines and Mills site. The analyses were performed following
the USEPA Contract Laboratory Program Statement of Work for Inorganics
Analysis Multi-media, Multi-Concentration, ILM04.1. Analyses were
conducted by Sentinel, Inc., Huntsville, Alabama. This validation was
conducted for the following samples:

MJ0KD3 \ MJ0KK0 MJ0KK3 MJ0KK6 MJ0KK9
MJ0KH1 MJ0KK1 MJ0KK4 MJ0KK7 MJOKLO
MJ0KH6 MJ0KK2 MJ0KK5 MJ0KK8

Data Qualifications

The following comments refer to the Sentinel Laboratory's performance
in meeting quality control specifications outlined in the CLP
Statement of Work (CLP-SOW) for Inorganic Analysis, rev. ILM04.1. The
comments presented herein are based on the information provided for
the review.

1.0	Timeliness - Acceptable

The technical (40 CFR part 136) holding time from the date of
collection for mercury in water is 28 days. The holding time for the
remaining metals in water is 180 days. The samples were collected
between 09/10/01 and 09/13/01. ICP-AES analyses were completed

Printed on Recycled Paper

-------
UCRJESI Mines & Mills, Case 29730, SDG MJOKD3

Page 2 of 6
November 1, 2001

between 09/27/01 and 10/02/01. Mercury analyses were completed on
09/25/01.

All analyses were conducted within the technical water holding times,
therefore no qualification was made based on holding time.

2.0 Sample Preparation - Acceptable

The samples were prepared for mercury and ICP-AES analyses on
09/25/01. No qualification was made based on sample preparation.

3.0 Calibrations/Calibration Verifications -

The samples were analyzed for mercury by CVAAS on 09/25/01. The
initial calibration included one blank and six standards. The curve,
was linear with a correlation coefficient greater than 0.995.

The samples were analyzed by ICP-AES on 09/27/01 (most analytes),
09/28/01 (re-analysis for copper and/or lead for samples affected by
poor continuing calibration verification recovery or interference
check sample recovery) and 10/02/01 (dilution analysis for copper in
sample MJ0KK1). The instruments were standardized each day of
analysis according to the analytical method using one blank and a
single calibration standard for each element.

All ICP-AES and CVAAS (mercury) calibrations were performed as 1
required and met the acceptance criteria; therefore, no qualification
was made on this basis.

Calibration verification samples are required before and after sample
analysis and after every 10 samples during analysis. Mercury
recoveries must be within 80-120%. Other metal recoveries must be
within 90-110%.

All ICP-AES and CVAAS (mercury) calibration verification (initial and
continuing) samples bracketing reported sample results met the
frequency and recovery criteria'; with the exception of sodium and
silver in the final CCV for the primary 09/28/01 analysis. Since both
recoveries (each were 89.7%R), were so close to the acceptance
criteria, no qualification was made based on ICP-AES or CVAAS
calibration verification.

There was one instance of a calibration verification (CCV)/calibration
blank (CCB) pair being ran after a 1.5 hour break in analysis. Since
the only affected sample analyses were for the duplicate, matrix spike
and post spike analyses for soil/sediment sample MJ0KK3 (the results
of which compared favorably with the earlier native analysis for this
sample), and since the affected analyses were immediately preceded by
an acceptable CCV/CCB pair, no qualification was made based on.the
break in analysis/long time between CCV/CCBs.

-------
UCR/ESIMines & Mills, Case 29730, SDG MJ0KD3 Narrative

Page 3 of 6
November 1, 2001

4.0 Laboratory Control Samples - Acceptable

Laboratory Control samples (LCS) are digested and analyzed along with
the samples to verify the efficiency of laboratory procedures (LCS
analyses are not required for mercury in water). All recoveries
associated with reported sample results met the acceptance criteria
for control samples, therefore no qualification was made based on LCS
results.

5 . 0 Blanks -

Procedural blanks were prepared with the samples to show potential
contamination from the digestion or analytical procedure. If an
analyte was found in the associated blank, the sample results were
qualified if the analyte concentration was less than five times the
analytical value in the blank.

Aluminum, barium, calcium, copper, iron, magnesium, manganese,
potassium, silver, and zinc were detected in the water preparation
blank. Calcium and potassium were detected in the soil/sediment
preparation blank. Aluminum, barium, calcium, chromium, iron,
magnesium, manganese, and silver were detected in one or more
continuing calibration blanks (CCBs). Beryllium, magnesium, and
sodium in one or more CCBs had negative values with absolute values
greater than the detection limits.

Based on blank contamination, the following qualifications were made:

~	aluminum in sample MJ0KH6 was qualified 'U', undetected

~	beryllium in samples MJ0KK4 and MJ0KL0 was qualified 'J',
estimated

~	chromium in sample MJ0KH1 was qualified 'U', undetected

~	copper in sample MJ0KH6 was qualified 'U', undetected

~	manganese in sample MJ0KH6 was qualified 'U', undetected

~	silver in samples MJ0KH1 and MJ0KK5 was qualified 'U', undetected,

The remaining sample results were greater than five times the
associated blank levels (or were already undetected) and were not
qualified on this basis.

6.0 ICP-AES Interference Check Sample -

The interference check sample (ICS) is analyzed by ICP-AES to verify
interelement and background correction factors. Analysis is required
at the beginning and end of each sample analysis run and recoveries
must be between 80% and 120%. All ICS recoveries associated with

-------
UCRJESIMines & Mills, Case 29730, SDG MJ0KD3 Narrative

Page 4 of 6
November 1, 2001

reported sample results were within the recovery criterion.	0433

The raw data for a number of samples had interfering levels of
calcium, magnesium, and/or iron. Analytes for which iron is an
interferent were qualified as follows:

~ Cadmium in sample MJ0KD3 was qualified 'UJ' estimated detection
limit (possible false negative).•

7.0 Duplicate Analysis -

Duplicate analysis was. done on water sample MJ0KH6. Water duplicate
results were within the +20% Relative Percent Difference (RPD) or
±CRDL criteria for water results < 5 times the CRDL criteria; with the
exception of iron (outside the CRDL criteria) . All water iron results
were qualified 'J' estimated.

Duplicate analysis was done on soil/sediment sample MJ0KK3.
Soil/sediment duplicate results were within the ±35% Relative Percent
Difference (RPD) or ±2xCRDL criteria for soil/sediment results < 5
times the CRDL criteria; therefore no qualification was made on this
basis.

Laboratory ' qualifiers were removed from soil/sediment arsenic
results as the laboratory used the stricter water criteria to qualify

n-i 1 / i-io«!	V v>a i 1 ^ n

OVPSAXUIC11U XCOUXUO .

8.0 Matrix Spike Analysis -

Matrix spike sample analyses are done to provide information about the
effect of the sample matrix on digestion and measurement methods.

Matrix spike recovery must be within the limits of 75 - 125%.

Matrix spike analysis was done on water sample MJ0KH6. All
soil/sediment matrix spike recoveries were within the required QC
limits; therefore water results were not qualified based on matrix
spike recovery.

Matrix spike analysis was done on soil/sediment sample MJ0KK3. All
soil/sediment matrix spike recoveries were within the required QC
limits;1 with the exception of antimony (64%R) and arsenic (45.2%).
All antimony and arsenic soil/sediment results were qualified 'J',
estimated (low bias suspected for samples not qualified for other
reasons).

9.0 ICP-AES Serial Dilution -

Water sample MJ0KH6 and soil/sediment sample MJ0KK3 were analyzed by
ICP-AES serial dilution to check for potential interferences. All of
the analytes which exceeded the minimum concentration criterion (50
times the IDL) were within the 10%D criteria; with the exception of

-------
UCR/ESI Mines & Mills, Case 29730, SDG MJ0KD3 Narrative

Page 5 of 6
November 1, ^

potassium in water (2 7.7%D) and calcium in soil/sediment (11.7%D).
All water potassium results were qualified xJ', estimated. All
soil/sediment calcium results were qualified *J', estimated (unknown
bias).

10.0 Detection Limits - Acceptable

Sample results which fall below the instrument detection limit (IDL)
are assigned the value of the instrument detection limit and the 'U'
qualifier is attached.

Contract Required Detection Limit (CRDL) standards are required for
most analytes to demonstrate a linear calibration curve near the CRDL.
CRDL standards were run at the required frequency.

11.0'Overall Assessment of the Data

This validation of the data is based on the criteria outlined in the
National Functional Guidelines for Inorganic Data Review (02/94).

The sample cooler(s) had a temperature upon receipt of 9°C. According
to the sample receipt log book, all applicable pHs were within
specific guidelines. Properly preserved water metals samples (pH<2)
do not require cooling (40 CFR 136.2, Table II) . In the reviewer'"s
judgement, it is unlikely that the elevated temperature for
soil/sediment would cause appreciable loss of metals, therefore no
action was taken based on the elevated cooler temperature.

Soil/sediment sample MJ0KK4 had a very low percent solids - 19.1. The
raw data was checked to make sure there wasn't a calculation error.

There was no calculation error.

For soil/sediment the amount of each sample analyzed for mercury is
0.2 g, wet weight, while the amount of each sample analyzed for other
metals is 1.0 gram, wet weight. With 19.1%, this means only
approximately 0.038 g of solid material was analyzed for mercury and
approximately 0.191 g of solid material was analyzed for the other
metals. Since mercury was not detected in this sample and since such
a minute amount of material was digested, the undetected mercury
result for samples MJ0KK6 was qualified %R' , unusable. There were a
number of detects for the ICP-AES analysis, indicating that at least
some ICP analytes were measurable in the small sample aliquot. All
ICP-AES analytes, including non-detects, in samples MJ0KK6 was
qualified 'J', estimated (unknown bias).

There were 322 data points reported: 8 results were qualified due to.
blank contamination; 22 results were estimated due to matrix spike
recovery; 3 results were estimated due to duplicate precision,- 14
results were estimated due to serial dilution; 1 result was suspected
to be a possible false negative due to high iron; 22 results were
estimated due to reduced sample aliquot size; 1 result was rejected

-------
UCR/ESI Mines 
-------
U.S. EPA
1

CLP

0436

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29730 SAS No.:	SDG No.: MJ0KD3

Matrix (soil/water): SOIL	Lab Sample ID: 40930S

Level (low/med):	LOW	Date Received: 09/19/01

% Solids:	54.3

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

Concent r a t i on

C

Q

M

7429-90-5

Aluminum

7980





P~

7440-36-0

Antimony

1.1

U

ff JU

P

7440-38-2

Arsenic

3.5 ¦

It



P

7440-39-3

Barium

114

, J



P

7440-41-7

Beryllium

0.27.

fil



P

7440-43-9

Cadmium

0.07

u



P

7440-70-2

Calcium

11900



P

7440-47-3

Chromium

11.0





P

7440-48-4

Cobalt

5.0 '

161

\

P

7440-50-8

Copper

10.2





P

7439-89-6

Iron

13500





P

7439-92-1

Lead

12.9





P

7439-95-4

Magnesium

6010





P

7439-96-5

Manganese

252





P

7439-97-6

Mercury

0.09

u



CV

7440-02-0

Nickel

10.8 -

351

\

p

7440-09-7

Potassium

1370

F

\

p

7782-49-2

Selenium

1.3

U



p

7440-22-4

Silver

0.83:

E&



p

7440-23-5

Sodium

272 ;

If



p

7440-28-0

Thallium

1.9

U
»



p

7440-62-2

Vanadium

17.4 "



\

p

7440-66-6

Zinc

52.5



p



Cyanide







NR



Color Before: BROWN
Color After: YELLOW
Comments:

Clarity Before:
Clarity-After:

Texture: MEDIUM
Artifacts:

FORM I - IN

ILM04.1 ^

-------


ecology &im environment

International Specialists in the Environment

r £i-

i<. v.-- #

2101 Fourth Avenue, Suite 1900, Seattle, WA 98121
Tel: (206) 624-9537, Fax: (206) 621-9832

MEMORANDUM

DATE:	August 22, 2001

TO: Leatta Dahlhoff, Project Manager, E & E, Seattle, WA

^FROM: Mark Woodke, Chemist, E & E, Seattle, WA

SUBJ: inorganic Data Quality Assurance Summary Check,

Upper Columbia River Stevens and Pend Oreille Counties, Washington

REF: TDD: 01-02-0028 PAN: 001281.0073.01SR

The data quality assurance summary review of 211 soil and 24 water samples collected from the
Upper Columbia River in Stevens and Pend Oreiiie Counties, Washington, has been completed. These
samples were analyzed for inorganic target elements and cyanide in accordance with the USEPA
Contract Laboratory Program (CLP) Statement of Work (SOW) for Inorganic Analyses (ILM04.0) by
Sentinel, Inc. of Huntsville, AL.

The.following discrepancies were noted:

In case number 29440, sample delivery group MJ0EQ5, lead was not qualified as "U" on the
Forms Is as listed in the memo in the blanks section. The secondary reviewer added the "U"
qualifier.

In case number 29440, sample delivery group MJ0GL0, sample MJ0GN9 was listed twice for
iron in the blank section. The primary reviewer corrected the memo to list MJ0GN8 and
MJ0GN9. Only the narrative requires editing.

The "B" flag indicates that the reported concentration is between the instrument detection limit
(IDL) and contract required detection limit (CRDL).

All discrepancies were reported to Ms. Gina Grepo-Grove, TOPO, USEPA, Region 10 on August
22,2001. The narrative was corrected by the primary reviewer.

recycled paper

-------


0438

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION 10

1200 Sixth Avenue
Seattle, Washington 98101

Reply To

Attn Of: OEA-095
MEMORANDUM

August 15, 2001

Subject:

From:

To;

Data Validation Report for the Total Inorganic Analyses
of Samples from Upper Columbia River/Lake Roosevelt
Expanded Site Assessment

case: 29440 SDGs: MJ0GL0, MJ0EQ5, MJ0GG6, MJ0ES7,
MJ0FK6, MJ0FJ0, MJ0EW6, MJ0GE0, MJ0GJ5, MJ0GM7, MJ0EQ6,

MJ0EN5, MJ0EY7,

1st
Data Unit,

OEA

CC:	Bruce Woods, Region 10 CLP TPO

Leatta Dahlhoff, Ecology & Environment

The quality assurance (OA) review of 211 soil and 24 water
samples collected from the above referenced site has been
completed. These samples were analyzed for full inorganic target
compounds in accordance with the USEPA Contract Laboratory
Program (CLP) Statement of Work (SOW) for Inorganic Analyses
(revision ILM04.1). The analyses were performed by Sentinel, Inc
of Huntsville, AL. The data validations were performed by the
Environmental Services Assistance Team (ESAT) of the USEPA
Manchester Environmental Laboratory, Port Orchard, WA.

There were no significant problems encountered with the data. A
total of 5405 data points were reviewed and evaluated.
Approximately 0.35% of the total data points were qualified as
unusable due to extremely low matrix recoveries. Approximately
17% of the total data points were qualified as estimated due to
serial dilution results, contamination in the blanks and/or poor
matrix spike recoveries. Additional 2.9% of the total data
points were qualified as non-detects due to contamination in the
blank. All of the samples were analyzed in accordance with the
technical requirements specified in the SOW. Data as qualified
can be used for all purposes.

Attached are the validation memos for the above mentioned case
and sample delivery groups (SDGs).

Pri7itm3onR»cycl»
-------
Environmental Services Assistance Team

ESAT Region 10
74 i i Beach Drive East
Port Orchard, WA 98366
Phone (360) 871-8723

0439

DELIVERABLE NARRATIVE

Date:	August 6,2001

To:	Ginna Grepo-Grove, TOPO, USEPA, Region 10

THROUGH: Dave Dobb,- Team Manager, ESAT Region 10	W ^;

FROM:	Chris Pace, Data Validation Task Lead, ESAT Region 10

SUBJECT: Data Validation Report for the Inorganic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites. Case: 29440 SDG: MJ0EY7

Account Code: 01T10P50102D106XLA00

Doc.#:	ESI 0-0-1127

TDN:	1048
Task Order 001

Contract:	68-W-01-027

cc: , Gerald Dodo, PO, USEPA Region 10
Project File

The quality assurance (QA) review of 20 soil samples collected from the above referenced site has been completed.
These samples were analyzed for total metals by Sentinel, Inc. of Huntsville, AL. The following samples were
reviewed in this, validation report:

MJ0EY7	MJ0EZ2

MJ0EY8	MJ0EZ3

MJ0EY9	MJ0F12

MJ0EZ0	MJ0GL1

MJ0E21	MJ0GL2

DATA QUALIFICATIONS

MJ0GL3
MJ0GL4
MJ0GL5
MJ0GL6
MJ0GL7

MJ0GL8

MJ0GM0

MJ0GM2

MJ0GM3

MJ0GM5

The following comments refer to the laboratory performance in meeting the Quality Control Specifications outlined,
in the Contract Laboratory Program (CLP) Statement of Work (SOW) for Inorganic Analysis (ILM04.1) and the
USEPA CLP Functional Guidelines for Inorganic Data Review, 2/94.

The conclusions presented herein are based on the information provided for the review.

-------
ESlO-O-1127 Page 2 of 4

Holding Time - Acceptable

The suggested holding time for mercury is 28 days from the date of sample collection and the holding time for the
rest of the metals is 180 days. The samples were collected on 6/23, 6/25, 6/26 and 6/27/01. The samples were
analyzed for mercury within 19 days and all other metals within 24 days of the sample collection date. None of the
data were qualified on this basis.

Sample Preparation - Acceptable

The samples were prepared in accordance with the methods used. None of the data were qualified on this basis.
Initial Calibration - Acceptable

AH of the samples were analyzed for total mercury using Cold Vapor Atomic Absorption Spectroscopy (CVAAS).
The initial calibration for mercury met the frequency of analysis and the linearity criteria (correlation coefficients,
i=>0.995).

The rest of the target analytes were analyzed using Inductively Coupled Plasma-Atomic Emission Spectroscopy
(ICP-AES). The initial calibration for ICP-AES met the frequency of analysis and the linearity criteria (correlation
coefficients, r=>0.995).

None of the data were qualified on this basis.

Calibration Verification - Acceptable

The initial and continuing calibration verifications met the criteria for frequency of analysis and recovery criteria of
90-110% and 80-120% for mercury. The recoveries ranged from 92-107% for ICP-AES and from 85-97% for
mercury. None of the data were qualified on this basis.

Detection Limits - Acceptable

All of the target analytes met the project required quantitation limits.

(CRDL) checks met the frequency of analysis and recovery criteria.

Blanks

Procedural blanks were prepared with the samples to indicate potential contamination from the digestion or
analytical procedure. If an analyte was found in the associated blank, the sample results were qualified as non-
detects, "U", if the analyte concentration is less than five times the analytical value in the blank.

The frequency of analysis of blanks was met. Based on the target analytes detected in the procedural, initial and
continuing calibration blanks, the following results were qualified as non-detects, "U":

0440

All of the Contract Required Detection Limit

Analyte

Associated Samples

cadmium

MJ0EY9, MJ0GL3, MJ0GL8, MJ0GM2, MJ0GM5

sodium

MJ0EY8

silver

MJ0EY7, MJ0EY8, MJ0EY9, MJ0EZ0, MJ0EZ1, MJ0EZ2,
MJ0EZ3, MJ0GL8, MJ0GM0, MJ0GM2, MJ0GM3, MJ0GM5

-------
Data Validation Report -

Upper Columbia River Lake Roosevelt/Mines Sites
Case No.: 29440 SDG: MJ0EY7
ESI0-0-1127 Page 3 of 4

Analytes which yielded a negative response in the preparation blank and/or continuing calibration blank(s) at 0441
concentrations comparable to or less than the absolute value of the blank(s) were qualified as estimated, "JAJJ", due
to possible low bias. The following samples were qualified:

Analyte

Associated Samples

selenium

All

ICP-AES Interference Check Sample - Acceptable

The ICP-AES interference check samples (ICS) were analyzed to verify inter-element and background correction
factors. The frequency of analysis (beginning and end of sequence) and recovery criteria (80-120%) were met The
recoveries ranged from 91-118%. None of the data were qualified on this basis.

ICP-AES Serial Dilution Analysis

Sample MJ0EY9 was analyzed for serial dilution. All of the analytes which exceeded the minimum concentration
criterion (50 times the DDL) agreed within 10% difference with the exception of calcium and magnesium. Results
for calcium and magnesium in all samples were qualified as estimated, "J". The "E" qualifiers applied by the
laboratory were crossed-out by the reviewer.

Laboratory Control Sample - Acceptable

The frequency of analysis and the recovery criteria for the laboratory control sample was met. The recoveries
ranged from 64-172%. None of the data were qualified on this basis.

Duplicate Sample Analysis - Acceptable

Sample MJ0EY9 was utilized for duplicate analysis. The duplicate results met the frequency of analysis and method
control limit criteria (±20% RPD or ± CRDL) for all target analytes with the exception of zinc. Zinc did meet the
-suggested technical control limit criteria (±35% RPD or ± 2X CRDL) for soils. The qualifiers applied by the
laboratory were crossed-out by the reviewer. None of the data were qualified on this basis.

Matrix Spike Analysis

Sample MJ0EY9 was used for the spike analysis. The frequency of analysis and recovery criteria were met with the
exception of manganese (126%) and selenium (67%) in the spike sample MJ0EY9S. Due to possible bias, the
detected and non-detected selenium results in all samples were qualified as estimated, "JAJJ". Due to possible bias,
the detected manganese results in all samples were qualified as estimated, "J". The "N" qualifiers applied by the
laboratory were crossed-out by the reviewer. All of the other spike recoveries were acceptable and ranged from
80-104%.

-------
Case No.: 29440 SDG: MJ0EY7
ESI0-0-1127 Page 4 of 4

Laboratory Contact

The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 460. Eighteen (3.9%) were qualified as non-detected due to blank
contamination. Eighty (17%) were qualified as estimated due to negative blanks, ICP serial dilution and spike
analyses.

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

DATA OTJAITFTE'RS

The analyte was not detected at or above the reported result.

The analyte was positively identified. The associated numerical result is an estimate.
The data are unusable for all purposes.

There is evidence the analyte is present in this sample.

There is evidence that the analyte is present. The associated numerical result is an estimate.

The analyte was not detected at or above the reported estimated result. The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

Low bias.

High bias.

The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

Unknown Bias.

0442

u

j
R
N

NJ . -
UJ

L
H
Q

K

-------
U.S. EPA

1

CLP

0443

EPA SAMPLE NO,

INORGANIC ANALYSIS DATA SHEET

MJ0GL1

Lab Name; Sentinel, Inc.	Contract; 68-W-00-085

Lab code; SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water) : SOIL	Lab Sample ID: 39261S

Level (low/med) ;, LOW	Date Received: 06/30/01

% Solids: .78.5

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

, Analyte

Cone ent rat i on

C

7429-90-5

Aluminum

10700



7440-36-0

Antimony

1.2

P

7440-38-2

Arsenic

5.8



7440-39-3

Barium

123



7440-41-7

Beryllium

0.30

m

7440-43-9

Cadmium

0.51

m

7440-70-2

Calcium

24400



7440-47-3

Chromium

23.9



7440-48-4

Cobalt

8.5

m

7440-50-8

Copper

32.1



7439-89-6

Iron

21700



7439-92-1

Lead

28.1



7439-95-4

Magnesium

11200



7439-96-5

Manganese

429



7439-97-6 -

Mercury

0.06

u

7440-02-0

Nickel

19.2



7440-09-7

Potassium

1730



7782-49-2

Selenium

0.87

u

7440-22-4

Silver

0.75

IB

7440-23-5

Sodium ,

358

fB

7440-28-0

Thallium

1.3

U

7440-62-2

Vanadium

41.6



7440-66-6

Zinc

130





Cyanide





Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:



tsL
Jrf



i

M

P
P
P
P
P
P
P

P .

P

P

P

P

P,

P

cv

p
p
p
p
p
p
p
p

NR

Texture:

Artifacts:

o\

MEDIUM

Comments

FORM I - IN

ILM04.1

-------
0444

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water): SOIL	Lab Sample ID: 39262S

Level (low/med):	LOW	Date Received: 06/30/01

% Solids:	37.9

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

2470





P

7440-36-0

Ant imony

2.4

®



P

7440-38-2

Arsenic

2.4

U



P

7440-39-3

Barium

105





P

7440-41-7

Beryllium

0.07

B



P

7440-43-9

Cadmium

1.3

1b

fSL

P

7440-70-2

Calcium

206000



P

7440-47-3

Chromium

57.7



P

7440-48-4

Cobalt

1.3

©



P

7440-50-8

Copper

20.3





P

7439-89-6

Iron

3240





P

7439-92-1

Lead

7.1





P

7439-95-4

Magnesium

3060



P

7439-96-5

Manganese

93 .7



p 1H

P

7439-97-6

Mercury

0.13

U

CV

7440-02-0

Nickel.

8.0

3B



p

7440-09-7

Potassium

333

3B



p

7782-49-2

Selenium

4.9



p

7440-22-4

Silver

0.39

1B

p

7440-23-5

Sodium

763

ffl



p

7440-28-0

Thallium

2.7

U



p

7440-62-2

Vanadium

6.4

B

/

p

7440-66-6

Zinc

58.2



p



Cyanide







NR













¦ol ¦

Texture: MEDIUM

Artifacts:

Comments:

FORM I - IN

ILM04.1

-------
U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Q4 4 5

EPA SAMPLE NO.

MJ0GL3

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085 	

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water): SOIL	Lab Sample ID: 39263S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	76.1

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

7429

7440

7440'

7440-

7440'

7440-

7440-

7440-

744Q-

7440-

7439-

7439-

7439-

7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

Color Before: BROWN
Color After: YELLOW

Analyte

-90-5
-36-0
-38-2
-39-3
•41-7
¦43-9
•70-2
¦47.-3
•48-4
•50-8
89-6
•92-1

95-4

96-5

97-6
02-0
09-7
49-2

22-4

23-5
28-0
62-2
66-6

Aluminum

Ant imony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium

Zinc

Cyanide

Concentration

6-

ol

Clarity Before:
Clarity After:

Texture:

MEDIUM

Artifacts:

Comments:

FORM I - IN	ILM04.1



-------
0446

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name.- Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water): SOIL	Lab Sample ID: 39264S

Level (low/med):	LOW	Date Received: 06/30/01

% Solids:	56.9

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

Concent ra t i on

C

Q

M

7429-90-5

Aluminum

3850





P

7440-36-0

Antimony

2.4





P

7440-38-2

Arsenic

5.6





P

7440-39-3

Barium

91.0





P

7440-41-7

Beryllium

0.21.





P

7440-43-9

Cadmium

6.1



f 1L

P

7440-70-2

Calcium

59800



P

7440-47-3

Chromium

86,2



P

7440-48-4

Cobalt

4.0

B



P

7440-50-8

Copper

17.7





P

7439-89-6

Iron

9400





P

7439-92-1

Lead

38 .7





P

7439-95-4

Magnesium

12100



P

7439-96-5

Manganese

246





P

7439-97-6

Mercury

0.09

U

CV

7440-02-0

Nickel

35.2





P

7440-09-7

Potassium

938

JB

TflU5&

P

7782-49-2

Selenium

1.2

U

P

7440-22-4

Silver

0.52

®

P

7440-23-5

Sodium

462

3



P

7440-28-0

Thallium

1.8

U



P

7440-62-2

Vanadium

42.9





P

7440-66-6

Zinc

342





P



Cyanide







NR

_

If ?



dl

Color Before: BLACK
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

Texture:

MEDIUM

Artifacts

FORM I - IN	ILM04.1

\4

-------
U.S.

EPA
1

CLP

0447

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name; Sentinel, ¦ Inc.

Lab Code: SENTIN	Case No.

Matrix (soil/water); SOIL
Level (low/med): LOW
% Solids;	39.3

Concentration Units (ug/L or rag/Kg dry weight

Contract: 68-W-00-085 	

29440 SAS No.:	SDG No.: MJ0EY7

Lab Sample ID: 39265S
Date Received: 06/30/01

MG/KG

Color Before: BROWN

Color After:

Comments:

YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

6610





P

7440-36-0

Antimony

2.3

©



P

7440-38-2

Arsenic .

16.2





P

7440-39-3

Barium

99.7

SB



P

7440-41-7

Beryllium

0.23

iB



P

7440-43-9

Cadmium

1.0

5B

yf 3L

P

7440-70-2

Calcium

14700



P

7440-47-3

Chromium

13.8



P

7440-48-4

Cobalt

6,1

ffl



P

7440-50-8

Copper

IS. 3





p

7439-89-6

Iron

16200





P

7439-92-1

Lead

23.2



rfTL

P

7439-95-4

Magnesium

7580



P

7439-96-5

Manganese

517



ft 5H"

P

7439-97-6

Mercury

0.12

U



cv

7440-02-0

Nickel

22.7





p

7440-09-7

Potassium

1170

m



p

7782-49-2

Selenium

1.7

u

p

7440-22-4

Silver

0.75

5B

p

7440-23-5

Sodium

669

JB



p

7440-28-0

Thallium

2.6

U



p

7440-62-2

Vanadium

33.0





p

7440-66-6

Zinc

163



f

p



Cyanide





#

NR

tf t-

Texture s MEDIUM
Artifacts:

FORM I - IN

ILM04.I

t>

-------
04 48

EPA SAMPLE NO.

U.S. EPA -'CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water): SOIL	Lab Sample ID: 39266S

Level (low/med): LOW	Date Received: 06/30/01

% Solids:	2.8.1

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

Analyte

Concentration

C

Q

M



7429-90-5

Aluminum

2220





P



7440-36-0

Antimony

2.1

U



P



7440-38-2

Arsenic

3.3

U



P



7440-39-3

Barium

109

IB



P



7440-41-7

Beryllium

0.07

U



P



7440-43-9

Cadmium

1.8

IB

jSIL

P



7440-70-2

Calcium

342000



P



7440-47-3

Chromium

8.2



P



7440-48-4

Cobalt

1.4

JB



P



7440-50-8

Copper

15.8

%



P



7439-89-6

Iron

4170





P



7439-92-1

Lead

12.7



1!5L

P



7439-95-4

Magnesium

5680



P,



7439-96-5

Manganese

217



7H

P



7439-97-6..

Mercury

0.18

U



cv



7440-02-0

Nickel

5.6

£



p



7440-09-7

Potassium

533

%



p



7782-49-2

Selenium

2.4



p



7440-22-4

Silver

0.21

P

p



7440-23-5

Sodium

975

)B



p



7440-28-0

Thallium

3.6

U



p



7440-62-2

Vanadium

8.6

%



p



7440-66-6

Zinc

49.3

p





Cyanide







NR





Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

(f t

Texture:
Artifacts:

MEDIUM

Comments:

FORM I - IN	ILM04.1



-------
U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

0449

EPA SAMPLE NO.

MJ0GL7

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water): SOIL	Lab Sample ID: 39267S

Level (low/med) :	LOW	Date Received: 06/30/01

% Solids:

79.3

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BROWN
Color After: YELLOW

Clarity Before:
Clarity After:

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

3530





P

7440-36-0

Antimony

0,72

U



P

7440-38-2

Arsenic

8.3





P

7440-39-3

Barium

48.1

TB



P

7440-41-7

Beryllium

0.18

jB



P

7440-43-9

Cadmium

0.40

JB

Ef3L

P

7440-70-2

Calcium

49100



P

7440-47-3

Chromium

7,0



l

P

7440-48-4

Cobalt

4.6

IB



P

a a f\ rr a ^ o

/II w -JWU

pAnnav
w*.

12 = 0





P

7439-89-6

Iron

14200





P

7439-92-1

Lead

13 .6





P

7439-95-4

Magnesium

27100



P;

7439-96-5

Manganese

209



ftJH

P

7439-97-6

Mercury

0.06

U



cv

7440-02-0

Nickel

20.7





p

7440-09-7

Potassium

990

0

jfcnK

p

7782-49-2

Selenium

0.84

U

p

7440-22-4

Silver

0.38

3B

p

7440-23-5

Sodium

318

5B



p

7440-28-0 .

Thallium

1.3

U



p

7440-62-2

Vanadium.

9.0

JB



p

7440-66-6

Zinc

107



i

p



Cyanide







NR











(/?¦

>6

¦Dl

Texture:

Artifacts:

MEDIUM

Comments:

FORM I - IN

ILM04.1

-------
0450

EPA SAMPLE NO.

U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 2944 0 SAS No.:	SDG No.: MJ01Y7

Matrix (soil/water): SOIL	Lab Sample ID: 39268S

Level (low/med): LOW	Date Received: 06/30/01

% Solids:	75.2	» .

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

6950





P

7440-36-0

Antimony

1.4

3B



P

7440-38-2

Arsenic

5.0





P

7440-39-3

Barium

44.5

30



P

7440-41-7

Beryllium

0.17

IB

U

P

7440-43-9

Cadmium

0.11



P

7440-70-2

Calcium ,

3400





P

7440-47-3

Chromium

17.1



f

P

7440-48-4

Cobalt

6.5

m



P

7440-50-8

Copper

21.8





P

7439-89-6

Iron

14200





P,

7439-92-1

Lead

8.3



MIL

P

7439-95-4

Magnesium

4450



P

7439-96-5

Manganese

209



PSH

P'

7439-97-6

Mercury

0.06

u



CV

7440-02-0

Nickel

14.1





p

7440-09-7

Potassium

978

B



p

7782-49-2

Selenium

0.90

u

p

7440-22-4

Silver.

0.57

-a*



p

7440-23-5

Sodium

392





p

7440-28-0

Thallium

1.4

U



p

7440-62-2

Vanadium.

31.5





p

7440-66-6

Zinc

43.8



f

p



Cyanide







NR

Color Before: BROWN
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

Cf t*

U-0

Texture:

Artifacts;

MEDIUM

FORM I - IN	ILM04.1

-------
U.S. EPA - CLP
1

INORGANIC ANALYSIS DATA SHEET

0451

EPA SAMPLE NO.

MJOGMO

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 2944 0 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water): SOIL	Lab Sample ID: 39269S

Level (low/med) : LOW	Date Received: 06/3 0/01

% Solids:	41.'1

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

3310





P

7440-36-0

Antimony

2.1

JB



P

7440-38-2

Arsenic

13 .1





P

7440-39-3

Barium

250

%



P

7440-41-7

Beryllium

0 .13



P

7440-43-9

Cadmium

6.1





P

7440-70-2

Calcium

209000



P

7440-47-3

Chromium

9.2



P

7440-48-4

Cobalt

5.7

13



P

7440-50-8



28 = 4





P

7439-89-6

Iron

31100





P

7439-92-1

Lead

346



fSL

P

7439-95-4

Magnesium

42200



P

7439-96-5

Manganese

1970



J H

P

7439-97-6

Mercury

0.11

U

CV

7440-02-0

Nickel

40.4





P

7440-09-7

Potassium

2410

%

Xl/'SK

P

7782-49-2

Selenium

1.6

u

P

7440-22-4

Silver

0.74

*!

U

P

7440-23-5

Sodium

578

5B



P

.7440-28-0

Thallium

2.5

5



P

7440-62-2

Vanadium

12.2

5b

/

P

7440-66-6

Zinc

2370



/

P



Cyanide







NR

Color Before: BROWN
Color After: YELLOW
Comments:

/ r

4-Dl

Clarity Before:
Clarity After:

Texture:

Artifacts:

MEDIUM

FORM I - IN

ILM04.1

-------
0452

EPA SAMPLE NO.

U.S. EPA -'CLP
1

INORGANIC ANALYSIS DATA'SHEET

Lab Name: Sentinel, inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No. : 29440 SAS No. :	SDG No. : MJ0EY7

Matrix (soil/water)': SOIL	Lab Sample ID: 39270S

Level (low/med): LOW	Date Received: 06/30/01

% Solids:	85.3

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

CAS No.

7429

7440-

7440-

7440-

7440-

7440-

7440-

7440-

7440-

7440-

7439-

7439-

7439-

7439-

7439-

7440-
7440-
7782-
7440-
7440-
7440-
7440-
7440-

-90-5
-36-0
-38-2
-39-3
-41-7
-43-9
-70-2
-47-3
-48-4
-50-8
-89-6
-92-1
-95-4
-96-5
-97-6
-02-0
-09-7
-49-2
-22-4
-23-5
-28-0
-62-2
66-6

Analyte

Aluminum

Antimony

Arsenic

Barium

Beryllium

Cadmium

Calcium

Chromium

Cobalt

Copper

Iron

Lead

Magnesium

Manganese

Mercury

Nickel

Potassium

Selenium

Silver

Sodium

Thallium

Vanadium,

Zinc

Cyanide

Color Before: BROWN
Color After: YELLOW

e-hM

Clarity Before
Clarity After:

Texture: MEDIUM
Artifacts:

Comments:

FORM I - IN

ILM04.1

-------
U.S. EPA
1

CLP

0451

EPA SAMPLE NO-

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract: 68-W-00-085

Lab Code: SENTIN	Case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water) : SOIL	Lab Sample ID: 39271S

Level (low/med) : LOW	Date Received: 06/30/01

% Solids:	60.9

Concentration Units (ug/L or mg/Kg dry weight) : MG/KG

CAS No.

Analyte

Concentration

C

Q

M

7429-90-5

Aluminum

7660





P

7440-36-0

Antimony

1.2





P

7440-38-2

Arsenic

3.0





P

7440-39-3

Barium

89.7





P

7440-41-7

Beryllium

0.27

IB



P

7440-43-9

Cadmium

0.88

SB

f 7L

P

7440-70-2

Calcium

12100

P

7440-47-3

Chromium

17.1

%

P

7440-48-4

Cobalt

5.6



P

7440-50-3

Ponnpr

19.7





P

¦ 7439-89-6

Iron

14500





P

7439-92-1

Lead

38.5





P

7439-95-4

Magnesium

7540



P

7439-96-5

Manganese

188



y jN

P

7439-97-6

Mercury

0.08

U



CV

¦7,440-02-0

Nickel

14.5





P

7440-09-7

Potassium

1180



jmi

P

7782-49-2

Selenium

1.1

U

P

7440-22-4

Silver

0.46

-#

u

P

7440-23-5

Sodium

418

If

P

7440-28-0

Thallium

1.7

U



P

7440-62-2

Vanadium

21.4





P

7440-66-6

Zinc

205



f

P



Cyanide





t

NR



,ol

Color Before: BLACK
Color After: YELLOW
Comments:

Clarity Before:
Clarity After:

Texture:

Artifacts:

MEDIUM

FORM I - IN

ILM04.1

-------
U.S. EPA

1

CLP

. 045 4

EPA SAMPLE NO.

INORGANIC ANALYSIS DATA SHEET

Lab Name: Sentinel, Inc.	Contract; 68-W-00-Q85

Lab Code: SENTIN	case No.: 29440 SAS No.:	SDG No.: MJ0EY7

Matrix (soil/water): SOIL	Lab Sample ID: 39272S

Level (low/med): LOW	Date Received: 06/30/01

% Solids:	89.3

Concentration Units (ug/L or mg/Kg dry weight): MG/KG

Color Before: BROWN
Color After: YELLOW

Clarity Before;
Clarity After:

CAS No.

Analyte

fTvn r an t~ tmsn t~ *? f*iY%

C

Q

M

7429-90-5

Aluminum

3160





P

7440-36-0

Antimony

0.64

u



P

7440-38-2

Arsenic

4.5





P

7440-39-3

Barium

44 .6

%



P

7440-41-7

Beryllium

0.11

' .

P

7440-43-9

Cadmium

0.34

V

u _

P

7440-70-2

Calcium

27500

$11

P

7440-47-3

Chromium

7.1



P

7440-48-4

Cobalt

2.5

5B



P

7440-50-8

Copper

8.1





P

7439-89-6

Iron

7810





P

7439-92-1

Lead

43 .5



Ifx

P

7439-95-4

Magnesium

15000



P

7439-96-5

Manganese

209



j<~SH

P

7439-97-6

Mercury

0.05

U



CV

7440-02-0

Nickel

5.9





p

7440-09-7

Potassium

427

In



p

7782-49-2

Selenium

0.75

U

p

7440-22-4

Silver

0.20

0



p

7440-23-5

Sodium

244

53

p

7440-28-0

Thallium

¦ 1.1

U



p

7440-62-2

Vanadium

9.3

tST
o

f

p

7440-66-6

Zinc

152



p

.. ¦

Cyanide





NR

(ft



Texture -.

COARSE

Artifacts:

Comments

FORM I - IN	ILM04.1



-------
Environmental Services Assistance Team

ESAT Region 10
7411 Beach Drive East
Port Orchard, WA 98366
Phone(360) 871-8723

DELIVERABLE NARRATIVE

Date:

To:

Through:

From:

SUBJECT:

Account Code:

Doc. #:

TDN:

Task Order:
Contract:

CC:

The quality assurance (QA) review of 20 soil samples collected from the above referenced site has been completed.
The samples were analyzed for Pest/PCB in accordance with the USEPA Contract Laboratory Program (CLP)
Statement of Work (SOW) for Organic Analyses (OLM04.2) by Envirosystems, Inc. of Columbia, MD.

DATA QUALIFICATIONS

The following,comments refer to the laboratory performance in meeting the Quality Control Specifications outlined
in the USEPA CLP SOW for Organic Analysis (OLM04.2), the USEPA CLP National Functional Guidelines for
Organic Data Review (10/99) and the Region 10 Guidelines for CLP Data Review.

The conclusions presented herein are based on the information provided for the review.

Holding Time - Acceptable

All of the samples met the method and technical (40 CFR 136) required holding times with the exception of samples
J0ET3, J0ET4 and J0ET5. These samples were extracted 15 days from the sample collection date which only
slightly exceeded the suggested technical holding time of 14 days for soils. None of the data were qualified on this
basis. The Holding Times Summary listing the pertinent collection, extraction, and analysis dates is attached at the
end of this validation report

Instrument Performance - Acceptable

The GC system met the SOW specified technical acceptance criteria prior to sample analyses, i.e., GC performance
checks, retention times, and calibrations. The "system remained stable throughout the course of analyses. Instrument
blanks were all clean and there were no indications of cany-over.

August 13,2001

Ginna Grepo-Grove, TOPO, USEPA, Region 10

Dave Dobb, Team Manager, ESAT Region 10 PP n

Chris Pace, Data Validation Task Lead, ESAT Region 10

Data Validation Report for the Organic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites. Case: 29440 SDG: J0EQ6

01T10P5 0102D106XLA00

ES10-0-1138

1050

001

68-W-01-027

Gerald Dodo, PO, USEPA, Region 10
Project File

-------
JSL41L4 r UllUUlll- KJjJjJZ.1 V-^L/1 44/HUIC4 JVI KC / XjUSVC i VC/C/J C KC11/iY± 1(1 US OlltZCi

Case No.: 29440 SDG: J0EQ6 " ;
ES10-0-1138 Page 2 of 4 t

»	W

Initial Calibrations - Acceptable	0456

One Pest/PCB initial calibration was performed. The initial calibration met the SOW technical acceptance criteria.
Continuing Calibration Verification (CCVs) Standards - Acceptable

All of the CCVs met the criteria for frequency of analysis, the retention time and the percent differences (%Ds)
criteria.

Compound Quantitation and Detection Limits - Acceptable

All of the samples were analyzed at the contract required quantitation limits (CRQLs). Target compounds that were
detected at concentrations less than the CRQLs were qualified as estimated, "J". All of the reported results were
adjusted for sample amounts analyzed.

Blanks - Acceptable

No target analytes were detected in any of the method or instrument blanks.

Analytical Sequence - Acceptable

All of the standards, blanks, samples, and QC samples were analyzed in accordance with the SOW specified
analytical sequence.

Surrogate Spikes - Acceptable

All of the Pest/PCB surrogate spike recoveries met the applicable QC criteria (30-150%).

Matrix Spike/Matrix Spike Duplicate (MS/MSD) - Acceptable

Pest/PCB sample J0EQ6 was utilized for MS/MSD analyses. The criteria for frequency of analysis, recoveries and
-RPDs were met

Sample Clean-up - Acceptable

The pesticide florisil cartridge and GPC calibration checks met the criteria for frequency of analysis and recovery
with the following exception:

Endrin had a recovery of 117% in one of the GPC calibration checks which was above the upper QC limit of 110%.

Sample results were not affected and therefore, none of the data were qualified on this basis.

Compound Identification

Single component pesticides and aroclors were qualified as follows: where %Ds (between two column
concentrations) >30% but <60% - detected results were qualified as estimated, "J"; %Ds >60% with concentrations
>CRQL - results were qualified as tentatively identified at the estimated concentration , "JN"; %Ds >60% with
concentrations 400% - results were
qualified as non-detects with raised quantitation limit if >CRQL.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: J0EQ6
ES10-0-1138 Page 3 of 4

Laboratory Contact	• 0457

The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 560. All data points were qualified as non-detected, "U".

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

Data Qualifiers

U -	The analyte was not detected at or above the reported result.

J -	The analyte was positively identified. The associated numerical result is an estimate.

R -	The data are unusable for all purposes.

N -	There is evidence the analyte is present in this sample.

JN -	There is evidence that the analyte is present. The associated numerical result is an estimate.

UJ - The analyte was not detected at or above the reported estimated result The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

I

H - High bias.

Q , - The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

K - Unknown Bias.

-------
Data Validation Report -Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: J0EQ6
ESI0-0-1138 Page 4 of 4

Holding Time Summary-Case 29440	SDG: J0EQ6

Sample
Number

Collection
Date

VTSR*

Pest/PCB
Extraction

Pest/PCB
Analysis

I0EQ6

6/20/01

6/22/01

6/27/01

7/19/01

. J0ET3

6/21/01

6/28/01

7/6/01

7/18/01

J0ET4

6/21/01

6/28/01

7/6/01

, 7/18/01

J0ET5

6/21/01

6/28/01

7/6/01

7/19/01

J0EW5

6/21/01

6/28/01

7/6/01

7/19/01

J0EZ4

6/23/01

6/28/01

7/6/01

7/19/01

J0EZ5

6/23/01

6/28/01

7/6/01

7/19/01

J0EZ6

6/24/01

6/28/01

7/6/01

7/19/01

J0F08

6/25/01

6/28/01

7/6/01

7/19/01

J0F09

6/25/01

6/28/01

7/6/01

7/19/01

J0F14

6/26/01

6/30/01

7/6/01

7/19/01

J0F16

6/26/01

6/30/01

7/6/01

7/19/01

J0F18

6/27/01

6/30/01

7/6/01

7/19/01

J0F19

6/27/01

6/30/01

7/6/01

7/19/01

I0FJ1

6/23/01

6/28/01

7/6/01

7/19/01

' J0FJ2

6/23/01

6/28/01

7/6/01

7/19/01

J0FK0 ,

6/23/01

6/28/01

7/6/01

7/19/01

J 0FK4 '

6/26/01

6/28/01

7/6/01

7/19/01

J0FK5

6/26/01

6/28/01

7/6/01

7/19/01

; J0FL2

6/28/01

6/30/01

7/6/01

7/19/01

*VTSR - Verified time of sample receipt in the laboratory.

-------
0459

IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE

NO.

Lab Name: ENVIROSYSTEMS 'Contract

1
i

I J0F08
: 68W99023 |



Lab Code; ENVSYS Case No,: 29440 SAS No.

:

SDG No.: J0EQ6



Matrix: (soil/water) SOIL-

Lab

Sample ID: 01061682



Sample wt/vol: 30.0 (g/mL) G

Lab

File ID:



% Moisture: 53 decanted: (Y/N) N

Date

Received: 06/28/01



Extraction: (Type) SONC

Date

Extracted: 07/06/01



Concentrated Extract Volume: 5000 (uL)

Date Analyzed: 07/19/01



Injection Volume: 2.00 (uL)

Dilution Factor: 1.00



GPC Cleanup: (Y/N) Y, pH: 7.7

Sulfur Cleanup; (Y/N) N



CONCENTRATION UNITS:

CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q



1

1 319-84-6	alpha-BHC



1 1 I
I 3.61U |



1 319-85-7	beta-BHC



1 3.6IU |



I 319-86-8	delta-BHC



1 3.61U I



1 58-89-9	gamma-BHC (Lindane)



1 3.. 610 I



1 76-44-8	Heptachlor



1 . 3.6IU |



1 309-00-2	Aldrin



1 3. 61 0 |



I • n r* *¦» j r «¦» -» ri	j	_li J-

i j,u4i-3rj—	neptachlor epoxide



! 3. 6! U j '



1 959-98-8			Endosulfan 1



1 3.6IU I



1 60-57-1	Dieldrin



1 7.0IU |



1 72-55-9	4, 4'-DDE



1 7.. 010 1



1 72-20-8	Endrin



I 7.010 1



- 1 33213-65-9			Endosulfan II



1 7.0|0 1



( 72-54-8			4,4'-DDD



1 7.0|0 |



1 /,'1031-07-8		—Endosulfan sulfate



1 7.0|0 |



1 50-29-3	4, 4'-DDT



1 7.0|0 |



1 72-43-5	Methoxychlor



1 36 |0 ,|



1 534 94-70-5	Endrin ketone



1 7.010 |



1 7421-93-4	Endrin aldehyde ¦



1 7.010 I



1 5103-71-9—		alpha-Chlordane



1 3.610 |



1 5103-74-2	gamma-Chlordane



1 3.6IU |



I 8001-35-2	Toxaphene



1 360 10 |



1 12674-11-2	Aroclor-1016



1 70 |0 I



1 11104-28-2	Aroclor-1221



I 140 |0 |



,1 11141-16-5	Aroclor-1232



1 70 |0 i



1 53469-21-9	Aroclor-1242 .



1 70 |0 I



1 12672-29-6	Aroclor-1248



i 70 |0 |



1 11097-69-1	Aroclor-1254



I 70 |0 |



1 11096-82-5	Aroclor-1260



1 70 10 |







1 1 1











FORM I PEST.



OLM04.2

o

\

i .if j

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET
Lab Name: ENVIRQSYSTEMS	Contract: 68W99023

EPA SAMPLE NO.

J0FO9

Lab Code; ENVSYS

Case No.: 29440

SAS No.

SDG No.

J0EQ6

Matrix: (soil/water) SOIL

Sample wt/vol:
% Moisture: 27

30.0 (g/mL) G
decanted: (Y/N) N

Lab Sample ID: 01061683
Lab File ID:

Date Received: 06/28/01

Extraction: (Type) SONC
Concentrated Extract Volume:

Injection Volume: 2.00 (uL)
GPC Cleanup: (Y/N) Y •	pH: 8.5

CAS NO.

COMPOUND

Date Extracted: 07/06/01

5000 (uL) Date Analyzed: 07/19/01

Dilution Factor: 1.00

Sulfur Cleanup: (Y/N) N

CONCENTRATION UNITS:

(ug/L or ug/Kg) UG/KG	Q

0460

319-84-6	alpha-BHC	

319-85-7	—beta-BHC	

319-86-8	delta-BHC	

58-89-9	gamma-BHC (Lindane)

76-4.4-8		—Heptachlor_	

309-00-2	Aldrin	

1024-57-3	Heptachlor epoxide_

959-98-8"	-Endosulfan I	

60-57-1	Dieldrin

72-55-9—	4,4 ' -DDE

72-20-8—	Endrin	

33213-65-9	Endosulfan II

72-54-8	4, 4' -DDD	

1031-07-8	-Endosulfan sulfate

50-29-3	4, 4 ' -DDT	~

72-4 3-5	-Methoxychlor	

534 94-70-5	Endrin ketone	

7421-93-4	Endrin aldehyde		

5103-71-9	alpha-Chiordane	

5103-7 4 -2		giamma-Chlordane	

8 0,01 - 3 5 - 2	Toxaphene	

12674-11-2	Aroclor-1016	

11104-28-2	Aroclor-1221	

¦ 11141-16-5	Aroclor-1232		

53469-21- 9	Aroclor-12 4 2	

12672-29-6™--—Aroclor-124 8	

11097-69-1	Aroclor-1254	

11096-82-5	Aroclor-1260

2.310
2.3|0
2.3IU
2.3 iU
2.3IU
2.31U
2.310
2.3IU
4 .5 |U
4.510
41.5 |U
4.5IU
4.5|U
4 . 5 | U
4.5IU
23 |U
4 .5 |U
4.510
3 | U
3 | U
IU

2

2

230
45
.92
45
45
45
45
45

IU

IU
IU
IU
IU
IU
IU



s\

FORM I PEST

OLM04.2

uu72

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

Lab Name: ENVIROSYSTEMS Contract

i

I J0F14
: 68W99023 |

Lab Code: ENVSYS Case No.: 29440 SAS No.



SDG No.: J0EQ6

Matrix: (soil/water) SOIL .

Lab

Sample ID: 01061719

Sample wt/vol: 30.0 (g/mL) G

Lab

File ID:

% Moisture: 47 decanted: (Y/N) N

Date

Received: 06/30/01

Extraction: (Type) SONC

Date

Extracted: 07/06/01

Concentrated Extract Volume: 5000 (uL)

Date

Analyzed: 07/19/01

Injection Volume: 2.00 (uL)

Dilution Factor: 1.00

GPC Cleanup: (Y/N) Y pH: 7.8

Sulfur Cleanup: (Y/N) N

CONCENTRATION UNITS:

CAS NO. COMPOUND (ug/L or ug/Kg) UG/KG Q

1 319-84-6	alpha-BHC



1 1 1
1 3.2IU 1

1 319-85-7	beta-BHC



1 3.2IU |

1 319-86-8	delta-BHC



1 3.2IU |

1 58-89-9	qamma-BHC (Lindane)



1 3.2IU 1

1 7 6-44-8	Heptachlor



1 .3.21U |

1 309-00-2	Aldrin



1 3.2IU |

1 1024-57-3	=—Heptachlor epoxide



1 3.210 1

1 959-98-8	Endosulfan I



i 3.2iu i

1 60-57-1	Dieldrin



1 6.2IU |

1 72-55-9	4, 4' -DDE



1 6.2IU I

1 72-20-8	Endrin



1 6.2IU |

1 33213-65-9	Endosulfan II



1 6.2IU |

1 72-54-8	4, 4' -DDD



1 6.2IU |

1 ,1031-07-8	Endosulfan sulfate



1 6.2IU |

. 1'.50-29-3	4, 4' - DDT



1 6.2IU 1

1 72-43-5	Methoxychlor



1 32 |U |

1 534 94-70-5	Endrin ketone



1 6.2 | U . |

1 7421-93-4	Endrin aldehyde



1 6.2|U |

1 5103-71-9	alpha-Chlordane



1 3.2IU |

1 5103-74-2:	-gamma-Chlordane



1 3.2IU |

1 8001-35-2	Toxaphene



1 320 |U |

1 12674,-11-2	Aroclor-1016



1 62 |U |

1 11104-28-2	Aroclor-1221



1 130 |U |

1 11141-16-5	Aroclor-1232



1 62 |U |

I 53469-21-9	Aroclor-1242



1 62 |U |

1 12672-29-6	Aroclor-1248



1 62 |U |

1 11097-69-1	Aroclor-1254



1 62 |U I

1 11096-82-5	Aroclor-1260



1 62 |U |

1



1 1 1

0481

A

FORM I PEST.

tf /

OLM04.2

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

J0F16

Lab Name: ENVIROSYSTEMS

Contract: 68W99023

Lab Code: ENVSYS

Case No.: 29440

SAS No.

SDG No.: J0EQ6

Matrix: (soil/water) SOIL .

Sample wt/vol:	30.0 (g/mL) G

% Moisture: 17	decanted: (Y/N) N

Extraction: (Type) SONC
Concentrated Extract Volume:
Injection Volume: 2.00 (uL)
GPC Cleanup: (Y/N) Y	pH:

5000 (uL)

8.0

CAS NO.

COMPOUND

Lab Sample ID:	01061720
Lab File ID:

Date Received:	06/30/01

Date Extracted:	07/06/01

Date Analyzed:	07/19/01
Dilution Factor: 1.00

Sulfur Cleanup:	{Y/N} N

CONCENTRATION UNITS:
{ug/L or ug/Kg) UG/KG

319-84-6	-alpha-BHC	

319-85-7—	beta-BHC	¦

319-86-8	delta-BHC	

58-89-9	gamma-BHC (Lindane)

7 6-44-8	Heptachlor_.	•

"309-00-2—	Aldrin 	

1024-57-3			Heptachlor epoxide_

959-98-8			Endosulfan I_	

60-57-1	Dieldrin_	

72-55-9	4,4 '-DDE	

72-20-8			Endrin	

33213-65-9	Endosulfan II	

72-54-8	4,4' -DDD	

1031-07-8	Endosulfan sulfate	

'50-29-3	'	4, 4 '-DDT	

¦ ,72-43-5	Methoxychlor		

53494-70-5	Endrin ketone	

7421-93-4		—Endrin aldehyde		

5103-71-9	r	alpha-Chlordane		

5103-74 -2	gamma-Chi ordane	

8001-35-2	Toxaphene	

12 67 4-11-2	Aroclor-1016	

11104-28-2	Aroclor-1221	

11141-16-5—		Aroclor-1232	

534 69-21-9—		Aroclor-1242	

12672-2 9-6	Aroclor-1248_	

11097-69-1	Aroclor-1254	

11096-82-5	Aroclor-1260

I

2.0| 0
2.0IU
2.0IU
2 . 0 | U
2.0IU
2 .01U
2 . 01 U
2.0IU
4 .0 I U
4 .0 | U
4®. 0 | U
4l. 0 I U
4.0IU
4 .0 | U
4 . 0 | CJ
20 |U
4 .0 I U
4 .01 U

2.

2.

200
40
81
40
40
40
40
40

G|U
0|U

IU

iu

IU
IU

IU
10
IU
IU

0462



i

5

.0



A

FORM I PEST.

OLM04.2

V, Olid 5

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

0463

Lab Name: ENVIROSYSTEMS

Contract: 68W99023

I J0F18
I

Lab Code: ENVSYS

Case No.

29440

SAS No.:

SDG No.: J0EQ6

Matrix: (soil/water) SOIL .

Sample wt/vol:	30.0 (g/raL) G

% Moisture: 17	decanted: (Y/N) N

Extraction: (Type) SONC

Concentrated Extract Volume:	5000 (uL)

Injection Volume: 2.00 (uL)

GPC Cleanup: (Y/N) Y	pH: 8.1

Lab Sample ID:	01061721
Lab File ID:

Date Received:	06/30/01

Date Extracted:	07/06/01

Date Analyzed:	07/19/01
Dilution Factor: 1.00

Sulfur Cleanup:	(Y/N) N

CAS NO.

COMPOUND

CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/KG

319-84-6	

319-85-7	

319-86-8	delta-BHC

58-89-9	

76-44-8	

309-00-2		

1024-57-3	Heptachlor epoxide

—alpha-BHC
—beta-BHC

-gamma-BHC (Lindane)
-Heptachlor
-Aldrin

I	60-57-1 —

I 72-55-9	

I 72-20-8	

I	33213-65-9

I	72-54-8 —

I	1031-07-8-

I	'50-29-3—

I 72-43-5	

I	53494-70-5

I	7421-93-4-

I	5103-71-9-

I	5103-74-2-

I	8001-35-2-

I	12674-11-2

I	11104-28-2

I	11141-16-5

l<	53469-21-9

I	12672-29-6

I	11097-69-1

I	11096-82-5

—tnaOsUii'an x
—Dieldrin
— 4, 4 '-DDE
--Endrin
—Endosulfan II
—4,4'-DDD
--Endosulfan sulfate
—4,4'-DDT

	Methoxychlor

	Endrin ketone

	Endrin aldehyde

	alpha-Chlordane

	gamma-Chiordane

	Toxaphene

	Aroclor-1016

	Aroclor-1221

	Aroclor-1232

	Aroclor-1242

	Aroclor-1248

	Aroclor-1254

	Aroclor-1260

FORM I PEST

OLM04.2

0U94

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

J0F19

Lab Name: ENVIROSYSTEMS	Contract: 68W99023	|	

Lab Code: ENVSYS Case No.: 2 9440 SAS No.:	SDG No.: J0EQ6

Matrix: (soil/water)	SOIL .

Sample wt/vol:	30.0 (g/mL) G

% Moisture: 44	decanted: (Y/N) N
Extraction: (Type) SONC

Concentrated Extract	Volume:	5000 (uL)

..Injection Volume: 2.00 (uL)

GPC Cleanup: (Y/N)	Y	pH: 7.6

Lab Sample ID:	01061722
Lab File ID:

Date Received:	06/30/01

Date Extracted:	07/06/01

Date Analyzed:	07/19/01
Dilution Factor: 1.00

Sulfur Cleanup:	(Y/N) N

CAS NO.

COMPOUND

CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/KG

319-84-6	

319-85-7	

319-86-8	

58-89-9	

76-44-8	

309-00-2—	

1024-57-3	

959-98-8	

60-57-1	

72-55-9	

72-20-8	

33213-65-9	

72-54-8	

1031-07-8	

,50-2 9-3	'¦

7l2-4 3-5	

I 53494-70-5—

	alpha-BHC

	beta-BHC_J

	delta-BHC

-gamma-BHC (Lindane)

-Heptachlor	

-Aldrin

-Heptachlor epoxide_

-Endosulfan I	

-Dieldrin	

-4,4'-DDE	

-Endrin

-Endosulfan II
-4,4' -DDD	~

-Endosulfan sulfate_
-4,4' -DDT		"

	Methoxychlor	

	Endrin ketone

I 7421-93-4	—

I 5103-71-9	

I 5103-74-2	

I 8001-35-2	

I 12674-11-2	

I 11104-28-2	

I 11141-16-5	

I, 53469-21-9	

I 12672-29-6	

I '11097-69-1	

I 11096-82-5	

Endrin aldehyde_
alpha-Chlordane_
gamma-Chlordane_
Toxaphene	

-Aroclor-1016_
-Aroclor-1221_
-Aroclor-1232_
-Aroclor-1242_
-Aroclor-1248_
-Aroclor-1254_
-Aroclor-1260

I

3.0IU
3.0|U
3.0IU
3. 01 U
3 . 0 | U
3. 0 | U
3.0IU
3. 0 | U
5. 9 | U
5 . 9 | U
5 L 9 | U

5
5
5
5
30
5.9
5.9
3.0
3.0
300
59
120
59
59
59
59
59

9 I U

9 I U
9 I U
9 | U

IU
IU
IU
IU
IU
IU
IU
IU
IU
IU
IU
IU
IU
I

0464

FORM I PEST

OLM04.2

0u93

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO

0465

!

I J0FK4

Lab Name: ENVIROSYSTEMS	Contract: 68W99023	|	

Lab Code: ENVSYS Case No.: 29440 SAS No.:	SDG No.: J0EQ6

Matrix: (soil/water) SOIL

Sample wt/vol:	30.0 (g/mL) G

% Moisture: 27	decanted: (Y/N) N

Extraction: (Type) SONC

Concentrated Extract Volume:	5000 (uL)

Injection Volume:, 2.00 (uL)

GPC Cleanup: (Y/N) Y,	pH: 7.6

Lab Sample ID:	01061687
Lab File ID:

Date Received:	06/28/01

Date Extracted:	07/06/01

Date Analyzed:	07/19/01
Dilution Factor: 1.00

Sulfur Cleanup:	(Y/N) N

CAS NO.	COMPOUND

CONCENTRATION UNITS:
(ug/L or ug/Kg) UG/KG

I

I 319-84-6—
I 319-85-7 —
I 319-86-8 —
I 58-89-9—
I 76-44-8 —
I 309-00-2 —
J 1024-57-3-
I 959-98-8—

I 60-57-1	

I 72-55-9	

I 72-20-8	

I 33213-65-9

I 72-54-8	

I. '1031-07-8 —

I 50-29-3	

I 72-43-5	

I 53494-70-5
I 7421-93-4-
I 5103-71-9-
I 5103-74-2-
I 8001-35-2-
I 12674-11-2
I 11104-28-2
,1 11141-16-5
I 53469-21-9
I 12672-29-6
I 11097-69-1
I 11096-82-5

	alpha-BHC

	beta-BHC_~

	delta-BHC_

	gamma-BHC (Lindane)

	Heptachlor

	Aldrin_

	Heptachlor epoxide

	Endosulfan I

	—Dieldrin

	4,4'-DDE

	Endrin

	Endosulfan II

	-4,4'-DDD

	Endosulfan sulfate

	4,4'-DDT

	Methoxychlor

	Endrin ketone

	Endrin aldehyde

	alpha-Chlordane

	gamma-Chlordane

	Toxaphene

	Aroclor-1016

	Aroclor-1221

	Aroclor-1232

	Aroclor-1242

	Aroclor-1248

-¦—Aroclor-1254
	Aroclor-1260

FORM I PEST

OLM04.2

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO.

J0FK5

Lab Name: ENVIROSYSTEMS

Contract: 68W99023

Lab Code: ENVSYS

Case No.: 29440

SAS No.:

SDG No.: J0EQ6

Matrix: (soil/water) SOIL .

Sample wt/vol: '	30.0 (g/mL) G

% Moisture: 28	decanted: (Y/N) N

Lab Sample ID: 01061688
Lab File ID:

Date Received: 06/28/01

Extraction: (Type) SONC
Concentrated Extract Volume:
Injection Volume: 2.00 (uL)

GPC Cleanup:

(Y/N) Y

CAS NO.

COMPOUND

Date Extracted: 07/06/01

5000 (uL). Date Analyzed: 07/19/01

Dilution Factor: 1.00

pH: 8.2	Sulfur Cleanup: (Y/N) N

CONCENTRATION UNITS:

(ug/L or ug/Kg) UG/KG	Q

I 319-84-6—
I 319-85-7 —
I 319-86-8—
I 58-89-9—

I 76-44-8	

I 309-00-2—
I 1024-57-3-
I 959-98-8—

I 60-57-1	

I 72-55-9	

I 72-20-8	

I 33213-65-9

1 72-54-8	

I 10,31-07-8-

I '50-29-3	

I 72-43-5	

I 53494-70-5
I 7421-93-4-
I 5103-71-9-
I 5103-74-2-
I 8001-35-2-
I 12674-11-2
I 11104-28-2
I 11141-16-5
I' 53469-21-9
I 12672-29-6
I 11097-69-1
I 11096-82-5

	alpha-BHC_

	beta-BHC	

	delta-BHC

-gamma-BHC (Lindane)

-Heptachlor		

-Aldrin

-Heptachlor epoxide_

-Endosulfan I	

-Dieldrin	

-4,4'-DDE	

-Endrin

-Endosulfan II
-4,4' -DDD	~

-Endosulfan sulfate
-4, 4 1 -DDT	"

	Methoxychlor	

	Endrin ketone

-Endrin aldehyde_
-alpha-Chlordane_
-gamma-Chlordane_

-Toxaphene	

-Aroclor-1016	

-Aroblor-1221_	

-Aroclor-1232	

-Aroclor-1242	

-Aroclor-1248	

-Aroclor-1254	

-Aroclor-1260

0466

A



5

FORM I PEST

OLM04.2

-------
Environmental Services Assistance Team

ESAT Region 10	04B7

7411 Beach Drive East
Port Orchard, WA 98366
Phone(360) 871-8723

DELIVERABLE NARRATIVE

Date:

August 14,2001

Ginna Grepo-Grove, TOPO, USEPA, Region 10
Dave Dobb, Team Manager, ESAT Region 10
Chris Pace, Data Validation Task Lead, ESAT

From:

through:

SUBJECT:. Data Validation Report for the Organic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites. Case: 29440 SDG: J0GN6

Account Code: 01T10P50102D106XLA00

Task Order: 001
Contract: 68-W-01-027

cc:	Gerald Dodo, PO, USEPA, Region 10

Project File

The quality assurance (QA) review of 2 soil samples collected from the above referenced site has been completed.
The samples were analyzed for Pest/PCB in accordance with the USEPA Contract Laboratory Program (CLP)
Statement of Work (SOW) for Organic Analyses (OLM04.2) by Envirosystems, Inc. of Columbia, MD.

DATA QUALIFICATIONS

The following-comments refer to the laboratory performance in meeting the Quality Control Specifications outlined
in the USEPA CLP SOW for Organic Analysis (OLM04.2), the USEPA CLP National Functional Guidelines for
Organic Data Review (10/99) and the Region 10 Guidelines for CLP Data Review.

The conclusions presented herein are based on the information provided for the review.

Holding Time - Acceptable

All of the samples met the method and technical (40 CFR 136) required holding times. The Holding Times
Summary listing the pertinent collection, extraction, and analysis dates is attached at the end of this validation
report.

Instrument Performance - Acceptable

The GC system met the SOW specified technical acceptance criteria prior to sample analyses, i.e., GC performance
checks, retention times, and calibrations. The system remained stable throughout the course of analyses. Instrument
blanks were all clean and there were no indications of carry-over.

Doc. #:
TDN:

ES10-0-1142
1050

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: J0GN6
ESI 0-0-1142 Page 2 of 3

0468

Initial Calibrations - Acceptable

One Pest/PCB initial calibration was performed. The initial calibration met the SOW technical acceptance criteria.
Continuing Calibration Verification (CCVs) Standards - Acceptable

All of the CCVs met the criteria for frequency of analysis, the retention time and the percent differences (%Ds)
criteria.

Compound Quantitation and Detection Limits - Acceptable

All of the samples were analyzed at the contract required quantitation limits (CRQLs). Target compounds that were
detected at concentrations less than the CRQLs were qualified as estimated, *T\ All of the reported results were
adjusted for sample amounts analyzed.

Blanks - Acceptable

No target analytes were detected in any of the method or instrument blanks.

Analytical Sequence - Acceptable

All of the standards, blanks, samples, and QC samples were analyzed in accordance with the SOW specified
analytical sequence.

Surrogate Spikes - Acceptable

All of the Pest/PCB surrogate spike recoveries met the applicable QC criteria (30-150%).

i

Matrix Spike/Matrix Spike Duplicate (MS/MSD) - Acceptable

Pest/PCB sample J0GN6 was utilized for MS/MSD analyses. The criteria for frequency of analysis, recoveries and
-RPDs were ijqet.

t	«	'

Sample Clean-np - Acceptable

The pesticide florisil cartridge and GPC calibration checks met the criteria for frequency of analysis and recovery.
Compound Identification

Single component pesticides and aroclors were qualified as follows: where %Ds (between two column
concentrations) >30% but <60% - detected results were qualified as estimated, 'T'; %Ds >60% with concentrations
>CRQL - results were qualified as tentatively identified at the estimated concentration, "JN"; %Ds >60% with
concentrations 400% - results were
qualified as non-detects with raised quantitation limit if >CRQL.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: J0GN6
ESI0-0-1142 Page 3 of 3

0469

Laboratory Contact

The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 56. All data points were qualified as non-detected, "U".

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

Data Qualifiers

U -	The analyte was not detected at or above the reported result.

J -	The analyte was positively identified. The associated numerical result is an estimate.

R -	The data are unusable for all purposes.

N -	There is evidence the analyte is present in this sample.

JN -	There is evidence that the analyte is present. The associated numerical result is an estimate.

UJ - The analyte was not detected at or above the reported estimated result. The associated
numerical valueis an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

I

H - High bias.

Q - The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

\

K - Unknown Bias.

Holding Time Summary - Case 29440	SDG: J0GN6

Sample
Number

Collection
Date

VTSR*

Pest/PCB
Extraction

Pest/PCB
Analysis

J0GN6

6/28/01

6/30/01

7/10/01

7/20/01

J0GN7

6/28/01

6/30/01

7/10/01

7/20/01

*VTSR - Verified time of sample receipt in the laboratory.

-------
IE

PESTICIDE ORGAN"ICS ANALYSIS DATA SHEET

EPA SAMPLE

nO.470

J0GN6

Lab Name: ENVIROSYSTEMS
Lab Code: ENVSYS Case No.: 29440 SAS No
Matrix: (soil/water) SOIL ¦

Sample wt/vol:	30.0 ' (g/mL) G

I Moisture: 32	decanted: (Y/N) N

Extraction: (Type) SONC
Concentrated Extract Volume:	5000 
-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET
Lab Name: ENVIROSYSTEMS

EPA SAMPLE NO.

J0GN7

Contract; 68W99023

Lab Code: ENVSYS

Case No.: 29440

SAS No.

SDG No.

J0GN6

Matrix: (soil/water) SOIL

Sample wt/vol: • , 30.0 (g/mL) G

I Moisture: 23	decanted: (Y/N) N

Lab Sample ID: 01061745
Lab File ID:

Date Received: 06/30/01

Extraction: (Type) SONC
Concentrated Extract Volume:

Injection Volume: 2.00 (uL)
GPC Cleanup: (Y/N) Y	pH: 8.0

CAS NO.

COMPOUND

Date Extracted: 07/10/01

5000 (uL) Date Analyzed: 07/20/01

Dilution Factor: 1.00

Sulfur Cleanup: (Y/N) N

CONCENTRATION UNITS:

(ug/L or ug/Kg) UG/KG	Q

0471

I 319-84-6-
i 319-85-7-
319-86-8 —

58-89-9	

76-44-8	

309-00-2—
1024-57-3-
| 959-98-8—
I 60-57-1—

I 72-55-9	

I 72-20-8	

I 33213-65-9

I 72-54-8	

I 1031-07-8-

I '5,0-29-3	

I 72-43-5	

I 53494-70-5
I 7421-93-4-
I 5103-71-9-
I 5103-74-2-
I 8001-35-2-
I 12674-.11-2
i 11104-28-2
I 11141-16-5
I' 53469-21-9
I 12672-29-6
i 11097-69-1
I 11096-82-5

	alpha-BHC_

	beta-BHC	

'	delta-BHC

-gamma-BHC (Lindane)

-Heptachlor		

-Aldrin

-Heptachlor epoxide_

-Endosulfan I	

-Dieldrin	

-4, 4 »-DDE		

-Endrin

-Endosulfan II_
-4,4'-DDD

-Endosulfan sulfate
-4,4'-DDT

-Methoxychlor	

-Endrin ketone	

-Endrin aldehyde_
-alpha-Chlordane_
-gamma-Chlordane_

-Toxaphene	

-Aroclor-1016	

-Aroclor-1221	

-Aroclor-1232	

-Aroclor-1242	

-Aroclor-1248	

-Aroclor-1254	

-Aroclor-1260

22
4
4
2
2

220
43
87
43
43
43
43
43

2.2IU
2 .2 I U
2.2IU
2.2 |U
2.2 |U
2.2 |U
2.2IU
2.2IU
4 .3 IU
4 .3(0
4 1' 3 I U
4.310
4.310
4.310
4.310
I U
3(0
3 10
210
2|0
10

10
10
I u
I u
10
10
10



I

FORM I PEST,

OLM04.2

-------
Environmental Services Assistance Team

ESAT Region 10
7411 Beach Drive East
Port Orchard, WA 98366
Phone (360) 871-8723

0472

Date:

.To:

Through:

From:

Subject.*

deliverable narrative

August 14,2001

Ginna Grepo-Grove, TOPO, USEPA, Region 10

Dave Dobb, Team Manager, ESAT Region 10

Chris Pace, Data Validation Task Lead, ESAT Region 10

tf

Data Validation Report for the Organic Analysis of Samples from the Upper Columbia River Lake
Roosevelt/Mines Sites. Case: 29440 SDG: J0GL1

Account Code: 01T10P50102D106XLA00

Doc.#:	ESI 0-0-1141

TDN:	1050

Task Order:	001

Contract:	68-W-01-027

CC;	Gerald Dodo, PO, USEPA, Region 10

1 Project File

The quality assurance (QA) review of 20 soil samples collected from the above referenced site has been completed.
The samples were analyzed for Pest/PCB in accordance with the USEPA Contract Laboratory Program (CLP)
Statement of Work (SOW) for Organic Analyses (OLM04.2) by Envirosystems, Inc. of Columbia, MD.

DATA QUALIFICATIONS

The following comments refer to the laboratory performance in meeting the Quality Control Specifications outlined
in the USEPA CLP SOW for Organic Analysis (OLM04.2), the USEPA CLP National Functional Guidelines for
Organic Data Review (10/99) and the Region 10 Guidelines for CLP Data Review.

The conclusions presented herein are based on the information provided for the review.

Holding Time - Acceptable

All of the samples met the method and technical (40 CFR 136) required holding times with the exception of samples
J0GL1, J0GL2, J0GL3, J0GL4 and J0GL5. These samples were extracted 15 days from the sample collection date
which only slightly exceeded the suggested technical holding time of 14 days for soils. None of the data were
qualified on this basis. The Holding Times Summary listing the pertinent collection, extraction, and analysis dates is
attached at the end of this validation report.

Instrument Performance - Acceptable

The GC system met the SOW specified technical acceptance criteria prior to sample analyses, i.e., GC performance
checks, retention times, and calibrations. The system remained stable throughout the course of analyses. Instrument
blanks were all clean and there were no indications of cany-over.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: J0GL1
ES10-0-1141 Page 2 of 4

ru 71

VI • u

Initial Calibrations - Acceptable

One Pest/PCB initial calibration was performed. The initial calibration met the SOW technical acceptance criteria.
Continuing Calibration Verification (CCVs) Standards - Acceptable

All of the CCVs met the criteria for frequency of analysis, the retention time and the percent differences (%Ds)
criteria.

Compound Quantitation and Detection Limits - Acceptable

All of the samples were analyzed at the contract required quantitation limits (CRQLs). Target compounds that were
detected at concentrations less than the CRQLs were qualified as estimated, "J". Ail of the reported results were
adjusted for sample amounts analyzed.

Blanks - Acceptable

No target analytes were detected in any of the method or instrument blanks.

Analytical Sequence - Acceptable

All of the standards, blanks, samples, and QC samples were analyzed in accordance with the SOW specified
analytical sequence.

Surrogate Spikes - Acceptable

All of the Pest/PCB surrogate spike recoveries met the applicable QC criteria (30-150%). i
Matrix Spike/Matrix Spike Duplicate (MS/MSD) - Acceptable

-Pest/PCB sample J0GN5 was utilized for MS/MSD analyses. The criteria for frequency of analysis, recoveries and

RPDs were met.

\

Sample Oean-up - Acceptable

The pesticide florisil cartridge and GPC calibration checks met the criteria for frequency of analysis and recovery.
Compound Identification

Single component pesticides and aroclors were qualified as follows: where %Ds (between two column
concentrations) >30% but <60% - detected results were qualified as estimated, "J"; %Ds >60% with concentrations
>CRQL - results were qualified as tentatively identified at the estimated concentration, "JN"; %Ds >60% with
concentrations 400% - results were
qualified as non-detects with raised quantitation limit if >CRQL.

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: J0GL1
ESI0-0-1141 Page 3 of 4

Laboratory Contact
The laboratory was not contacted for this review.

Overall Assessment

The total number of data points was 560. One (0.18%) was qualified as estimated and tentatively identified because
the percent difference between the two analytical columns exceeded 60%. One data point was detected 4,4-DDT in
sample J0GL5 slightly above the CRQL. All other data points were qualified as non-detected, "U".

All of the samples were analyzed in accordance with technical specifications outlined in the SOW. The data, as
qualified, are acceptable and can be used for all purposes.

Data Qualifiers

U	-	The analyte was not detected at or above the reported result.

J	-	The analyte was positively identified. The associated numerical result is an estimate.

R	-	The data are unusable for all purposes.

N	-	There is evidence the analyte is present in this sample.

JN	-	There is evidence that the analyte is present. The associated numerical result is an estimate.

UJ - The analyte was not detected at or above the reported estimated result. The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

H - High bias.

Q - The result is estimated because the concentration is below the Contract Required
Quantitation Limits (CRQLs).

K - Unknown Bias.

0474

-------
Data Validation Report - Upper Columbia River Lake Roosevelt/Mines Sites

Case No.: 29440 SDG: J0GL1
ESI0-0-1141 Page 4 of 4

047*i

Holding Time Summary - Case 29440	SDG: J0GL1

Sample
Number

Collection
Date

VTSR*

Pest/PCB
Extraction

Pest/PCB
Analysis

J0GL1

6/25/01

6/30/01

7/10/01

7/19/01 .

J0GL2

6/25/01

6/30/01

7/10/01

,7/19/01

J0GL3

6/25/01

6/30/01

7/10/01

7/19/01

J0GL4

6/25/01

6/30/01

7/10/01

7/19/01

J0GL5

6/25/01

6/30/01

7/10/01

7/19/01

J0GL6

6/26/01

6/30/01

7/10/01

7/19/01

J0GL7

6/26/01

6/30/01

7/10/01

7/19/01

J0GL8

6/26/01

6/30/01

7/10/01

7/19/01

J0GM0

6/26/01

6/30/01

7/10/01

7/19/01

J0GM2

6/26/01

6/30/01

7/10/01

7/19/01

J0GM3

6/27/01

6/30/01

7/10/01

7/19/01

J0GM5

6/27/01

6/30/01

7/10/01

7/19/01

J0GM7

6/27/01

6/30/01

7/10/01

7/19/01

J0GM9

6/27/01

6/30/01

7/10/01

7/20/01

J0GN0

6/27/01

6/30/01

7/10/01

7/20/01

J0GN1

6/27/01

6/30/01

7/10/01

7/20/01

J0GN2 ,,

6/28/01

6/30/01

7/10/01

7/20/01

J0GN3 '

6/28/01

6/30/01

7/10/01

7/20/01

J0GN4

6/28/01

6/30/01

7/10/01

7/20/01

J0GN5

6/28/01

6/30/01

7/10/01

7/20/01

*VTSR - Verified time of sample receipt in the laboratory.

-------
IE

PESTICIDE ORGANICS ANALYSIS DATA SHEET

EPA SAMPLE NO. 0476

i

J0GL1

Lab Name: ENVIROSYSTEMS	Contract: 68W99023	|	

Lab Code: ENVSYS Case No.: 29440 SAS No.:	SDG No.: J0GL1

Matrix: (soil/water) SOIL

Sample wt/vol:	30.0 (g/mL) G

% Moisture: .2.4.'.	decanted: (Y/N) N

Extraction: (Type)

SONC

Lab Sample ID:	01061724
Lab File ID:

'•Date. Received:	06/30701

Date Extracted:	07/10/01

Concentrated Extract Volume:

Injection Volume: 2.00 (uL)

5000 (uL) Date Analyzed: 07/19/01

Dilution Factor:

1.00

GPC Cleanup:

CAS NO.

(Y/N) Y

pH:

COMPOUND

Sulfur Cleanup: (Y/N) N

CONCENTRATION UNITS:

(ug/L or ug/Kg) UG/KG	Q

I

319-84-6—

319-85-7—
319-86-8—

56-89-9	

76-44-8	

309-00-2—
1024-57-3-
959-98-8 —

60-57-1	

72-55-9—

72-20-8	

332-13-65-9

72-54-8	

1031-07-8-
50-29-3—
72-43-5—
53494-70-5
7421-93-4-
5103-71-9-
5103-74-2-
8001-35-2-
12674-11-2
11104-28-2
11141-16-5
53469-21-9
12672-29-6
11097-69-1
11096-82-5

—alpha-BHC_

	beta-BHC_^

	delta-BHC

-gamma-BHC (Lindane}_

-Heptachlor_	

-Aldrin

-Heptachlor epoxide_

-Endosulfan I	

-Dieldrin	

-4,4'-DDE
-Endrin

-Endosulfan II
-4,4'-DDD

-Endosulfan sulfate
-4,4'-DDT	~

	Methoxychlor	

	Endrin ketone

-Endrin aldehyde_
-alpha-Chlordane_
-gamma-Chlordane_

-Toxaphene	

-Aroclor-1016	

-Aroclor-1221	

-Aroclor-12 32	

-Aroclor-1242	

-Aroclor-1248	

-Aroclor-1254	

-Aroclor-1260

2
4
4

4
4
4
4
4
22
4
4
2
2

220
43
88
43
43
43
43
43

2 I 0
2 I U
2 IU
2 | 0
2.2|0
2.2 10
2.2 |U

2	| U

3	I U
3 | U
3 | U
a I u

3 | U

3 | U
3 IU
IU
31U
3 |U
210
210
10

IU
10

IU.
IU
IU
IU

FORM I PEST.

OLM04.2

Ouio

-------
MEMORANDUM

DATE; November 6, 2001

TO: Leatta Dahlhoff, Project Manager, E & E, Seattle, WA
FROM: Mark Woodke, Chemist, E & E, Seattle, WA

SUBJ: Organic Data Summary Check, Upper Columbia River Mines/Mills ESI,
Stevens and Pend OreilJe Counties, Washington

REF: TDD: 01-02-0028 PAN: 001281.0073.01SR

The data quality summary check of 28 solid samples collected from the Upper Colum-
bia River Mines/Mills ESI, Stevens and Pend Oreille Counties, Washington has been completed.
Semivoiatile Organic Compound and Chlorinated Pesticide/Polychlorinated Biphenyl compound
analysis (EPA CLP SOW OLM04.2) was performed by Laucks Testing Laboratory, Seattle,
Washington,

,, The samples were numbered:

JOKC'l
J0KC7
J0KD4
J0KH5
J0KJ4

J0KC2
J0KC8
J0KH0
J0KH6
J0KK8

J0KC3
J0KC9
J0KH1
J0KH7
J0KK9

J0KC4

J0KD1

J0KH2

J0KJ1

J0KL0

J0KC5
J0KD2
J0KH3
J0KJ2

J0KC6
J0KD3
J0KH4
J0KJ3

No.discrepancies were noted.

All sample results originally qualified "JQ" by the laboratory to indicate a result less"
than the CRQL were changed to "JQK" by the secondary reviewer to indicate an estimated
quantity less than the CRQL with an unknown bias.

-------
$ A x>

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY

REGION 10

1200 Sixth Avenue
Seattle, WA 98101

0478

October 30, 2001

Reply To

Attn Of: OEA-095
MEMORANDUM

SUBJECT:

FROM:

Data validation report for the semi-volatile organic compound (SVOC) and
pesticide/polychlorinated biphenyl (Pest/PCB) analysis of samples from the Upper Columbia
River/Mines Sites ESI. Case: 29730 SDGs: J0KC1, J0KH1

Chris Pace, Chemist, OEA

TO:

CC:

Monica Tonel, SAM, OEC

Mark Woodke, Ecology and Environment, Inc.

Bruce Woods, CLP PO, OEA
Ginna Grepo-Grove, Chemist, OEA

\

The quality assurance (QA) review of 28 soil samples collected from the above referenced site has been
completed. Six samples were analyzed for SVOCs (all in SDG J0KH1) and twenty three for Pest/PCBs in
accordance with the US EPA Contract Laboratory Program (CLP) Statement of Work (SOW) for Organic
Analyses (OLM04.2) by Laucks Testing Laboratory of Seattle, WA.

The following sample numbers were validated in this report:	1

SDG: J0KC1

J0KC1	J0KC3	J0KC5	J0KC7	J0KC9	J0KD2	J0KD4

J0KC2 \ J0KC4	J0KC6	J0KC8	J0KD1	J0KD3	J0KH0

SDG: J0KH1

J0KH1*

J0KH2*

J0KH3
J0KH4

J0KH5
J0KH6*

J0KH7*
J0KJ1

J0KJ2
J0KJ3

J0KJ4*
J0KK8*

J0KK9
J0KL0

* Analyzed for SVOCs.
DATA QUALIFICATIONS

The following comments refer to the laboratory performance in meeting the Quality Control (QC) Specifications
outlined in the USEPA CLP SOW for Organic Analysis (OLM04.2) and the USEPA CLP National Functional
Guidelines for Organic Data Review (10/99).

The conclusions presented herein are based on the information provided for the review.

Printed on Recycled Paper

-------
Data Validation Report - Upper Columbia River
Case: 29730 SDG: J0KC1, J0KH1

Page 2 of5

Holding Time - Acceptable	"	0479

The samples were collected between 9/10 and 9/13/01. All samples extracted within 9 days of sample collection
and analyzed within 12 days of extraction. All of the samples met the technical required holding times for all
analyses.

Instrument Performance Check - Acceptable

All of the GC/MS instrument performance checks met the ion abundance criteria. All of the GC instrument
performance checks met the resolution, percent differences (%Ds) and percent breakdown criteria.

Initial Calibrations - Acceptable

One SVOC and one Pest/PCB initial calibration was performed. The initial calibrations met the SOW acceptance
criteria for the percent relative standard deviations (%RSDs) and response factors for all target compounds and
surrogates.

Continuing Calibration Verification (CCV)

All of the SVOC and Pest/PCB CCV checks met the criteria for frequency of analysis, minimum response factors
and %Ds with the following exceptions;

* The %Ds for the following SVOC compounds exceeded the QC limits:

Date^Time

Compound

%t>

n..alifW

of Analysis





Detect/Non-detect

9/26/01

benz aldehyde

-36

J/UJ

(0935)

2,2*-oxybis( 1 -chloroprop ane)

-37

J/UJ



hexachlorobntadiene

-27

J/UJ



hexachlorocyclopentadiene

-61

J/UJ



atrazine

-55

J/UJ

'

benzo(k)fluoranlhene

27

J/none



2,4,6-tribromophenol (suit.)

43

none

Quantitation Limits

SVOC samples J0KH1, J0KH2, J0KH6 and J0KH7 required medium level preparation due to sample matrix.
The quantitation limits (QLs) were based on the lowest standard concentration analyzed in the initial calibrations.
Target compounds that were detected at concentrations less than the contract required quantitation limits
(CRQLs) were qualified as estimated, "J". All of the reported results were adjusted for sample amounts
analyzed.

Blanks

Bis(2-cthylhexyl)phthalate was detected below the CRQL in the SVOC blanks SBLKL3and SBLKL4. Bis(2-
ethylhexyl)phthalate detected in the samples at concentrations less than ten times the value in their associated
blank were qualified as non-detects, "U".

No target Pest/PCBs were detected in the method or instrument blanks.

-------
4

Data Validation Report - Upper Columbia River
Case: 29730 SDG: J0KC1, J0KH1

Page 3 of 5

Analytical Sequence - Acceptable	0480

All of the standards, blanks, samples, and QC samples were analyzed in accordance with the SOW specified
analytical sequence.

Surrogate Spikes - Acceptable

All of the SVOC and Pest/PC B surrogate spike recoveries met the applicable QC criteria.

Matrix Spike/Matrix Spike Duplicate (MS/MSD) - Acceptable

SVOC samples J0KJ4 (low level preparation) and J0KH7 (medium level preparation) were utilized for MS/MSD
analyses. The criteria for frequency of analysis, recoveries and relative percent differences (RPDs) were met.

Pest/PCB samples J0KD2 (SDG J0KC1) and J0KH3 (SDG J0KH1) were utilized for MS/MSD analyses. The
criteria for frequency of analysis, recoveries and relative percent differences (RPDs) were met.

Internal Standards - Acceptable

The acceptance criteria for internal standards (IS) are ±30 seconds for retention time (RT) shifts and

-50% to +100% of the IS area as compared to the IS RT and area of the daily continuing calibration standard. All

of the SVOC GC/MS analyses met the IS area and RT shift criteria.

Compound Identification

All of the compounds detected in the SVOC GC/MS analyses were within the retention time windows, met the
US EPA spectral matching criteria and were judged to be acceptable.

Single component pesticides and Aroclors are qualified as follows: where %Ds (between two column
concentrations) >30% but <60% - detected results were qualified as estimated, "J"; %Ds >60% with
concentrations >CRQL - results were qualified as tentatively identified at the estimated concentration, "JN";
%Ds >60% with concentrations 400% - results were
qualified as non-detects with raised quantitation limit if >CRQL. In cases where target compounds were less
than the CRQL and the result of chromatographic "noise-" or interference the results are qualified as non-
detected, "U". ,

Tentatively Identified. Compounds

Peaks that were detected in the samples at areas >10% of the internal standards and were not part of the target
compound lists were identified as tentatively identified confounds (TICs). TlCs that were both found in the
sample and in the associated method blank(s) were qualified as unusable, "R." Peaks that were identified as
common laboratory contaminants, solvent preservatives, column bleed or aldol condensation products were
qualified as unusable, "R". The rest of the peaks identified as TICs were qualified "NJ", tentatively identified at
an estimated concentration.

SVOC samples J0KH1, J0KH2, J0KH6 and J0KH7 had chromatographic peaks present that were unaccounted
for on the Form IHC and/or reported as alkanes. See laboratory contact.

-------
Data Validaiioji Report
Case: 29730

Laboratory Contact

The laboratory was contacted concerning the following:

SVOC samples J0KH1, J0KH2, J0KH6 and J0KH7 had chromatographic peaks present that were unaccounted
for on the Form I TIC and/or reported as alkanes. Each of these samples had chromatograms displaying
hydrocarbon type patterns. The reported TICs failed to account for many of the later eluting peaks on the
hydrocarbon "hump". It was requested that the laboratory provide resubmitted raw data and CLP Forms
concerning this issue.

Resolution: The laboratory responded by FAX (hard copy to follow) stating the HP Chemstation software
appears to have problems with samples that have severe matrix problems and the only solution is to manually
integrate and process. They then state that Lauck's purchased software for CLP inhibits them from manually
processing and producing the actual CLP Forms and EDD.

I

Overall Assessment

The total number of SVOC data points was 390. Four (1.0%) were qualified as non-detected due to blank
contamination. Thirty three (8.5%) were qualified as estimated due to values reported below the CRQL and
continuing calibrations. The total number of Pest/PCB data points was 644. Two (0.3%) were qualified as non-
detected due values reported above the CRQL with high %Ds between analytical columns and chromatographic
interference.

All of the samples were analyzed in accordance with technical specifications-outlined in the SOW (with the
exception of the TIC reporting difficulties discussed above). The data, as qualified, are acceptable and can be
used for all purposes.

0481

- Upper Columbia River
SDG: J0KC1, JOKHl
Pase 4 of 5

i

-------
0482

Data Validation Report - Upper Columbia River
Case: 29730 SDG: JOKC1, JOKH1

Page 5 of 5

Data Qualifiers

U - The analyte was not detected at or above the reported result.

J - The analyte was positively identified. The associated numerical result is an estimate.
R - The data are unusable for all purposes.

N - There is evidence the analyte is present in this sample.

JN - There is evidence that the analyte is present The associated numerical result is an
estimate.

UJ - The analyte was not detected at or above the reported estimated result. The associated
numerical value is an estimate of the quantitation limit of the analyte in this sample.

L - Low bias.

H - High bias.

Q - The result is estimated because the concentration is below the Contract Required

Quantitation Limits (CRQLs).
K - Unknown Bias.

-------
1C

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET

Lab Name: LAUCKS TESTING LABORATORIES	Contract: 68-W-00-075

EPA SAMPLE NO.

0483

Lab Code: LAUCKS

Case No.

29730

SAS No.:

SDG No.

J0KH1

Matrix: (soil/water) SOIL

Sample wt/vol:	30	(g/mL) G

Level: (low/med! LOW

% Moisture: 35 Decanted:(Y/N) Y
Concentrated Extract Volume: 500 ifih}
Injection Volume: 2 (/iL)
GPC Cleanup: (Y/N) Y	pH: 7.0

CAS NO. COMPOUND

Lab Sample ID: 0109281-12
Lab File ID: L0926015.D
Date Received: 09/17/01

Date Extracted: 09/19/01
Date Analyzed: 09/26/01
Dilution Factor: 1.0
Extraction: (Type) FFEX
CONCENTRATION UNITS:

100-52-7

Benzaldehyde

13C

Jfl h

108-95-2

Phenol

51C

U '

111-44-4

biB (2-Chloroethyl)ether

51C

u

95-57-8

2-Chiorophenol

510

u

95-48-7

2-Methylphenol

510

V

108-60-1

2,2"-oxybis(1-Chloropropane)

510

vjK

98-86-2

Acetophenone

60

J Wf

106-44-5

4-Methylphenol

81

5 <£>Y

621-64-7

N-Nitroso-di-n-propylamine

510

v *

67-72-1

Hexachloroethane

510

u

98-95-3

Nitrobenzene

510

u

78-59-1

Isophorone

510

u

88-75-5

2-Ni t ropheno1

510

u

105-67-9

2,4-Dimethylphenol

510

u

111-91-1

Bis(2-Chioroethoxy)methane

510

u

120-83-2

2,4-Diehlorophenol

510

u

91-?0-3

Naphthalene

510

u

106-47-8

4-Chloroaniline

510

u

87-68-3

Hexachlorobutadiene

510

UTK

105-60-2

Caprolactam

510

u

59-50-7

4-Chloro-3-methylphenol

510

u •

91-57-6

2-Methylnaphthalene

510

u

77-47-4

Hexaehlorocyelopentadiene

510

u JK

88-06-2

2,4,6-Trichlorophenol

510

u

95-95-4

2,4,5-Trichlorophenol

1300

V

92-52-4

1,1'-Biphenyl

510

u

91-58-7

2-Chloronaphthalene

510

V

88-74-4

2-Nitroaniline

1300

V

131-11-3

Dimethylphthalate

510

u

606-20-2

2,6-Dinitrotoluene

510

V

20.8-96-8

Acenaphthylene

510

V

99-09-2

3-Nitroaniline

1300

u

83-32-9

Acenaphthene ¦

510

u



FORM I SV- 1

OLM04.2

/»'

308

-------
ID

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
Lab Name: LAUCKS TESTING LABORATORIES	Contract: 6 8-W-00-075

EPA SAMPLE NO.

0484

Lab Code: LAUCKS

Case No.: 29730

Matrix: (soil/water) SOIL

Sample wt/vol:	30	(g/mL) G

Level: (low/med) LOW

% Moisture: 35 Decanted:(Y/N) Y
Concentrated Extract Volume: 500 <^L)
Injection Volume:	2 (/iL)

GPC Cleanup: (Y/N) Y	pH: jM)

CAS NO.

COMPOUND

SAS No. :	SDGNO.: J0KH1

Lab Sample ID; 0109281-12"
Lab File ID: L0926015.P
Date Received: 09/17/01

Date Extracted: 09/19/01
Date Analyzed: 09/26/01
Dilution Factor: 1. 0
Extraction: (Type) PFEX

CONCENTRATION UNITS:

(^g/L or fig/Kg) UG/KG

51-28-5

2,4-Dinitrophenol

130C

U

100-02-7

4-Nitropbenol

1300

u

132-64-9

Dibenzofuran

510

U

121-14-2

2,4-Dinitrotoluene

510

u Lc

84-66-2

Diethylphthalate

190

J C K

86-73-7

Fluorene

510

u

7005-72-3

4-Chlorophenyl-phenylether

510

u

100-01-6

4-Nitroaniline

1300

u

534-52-1

4,6-Dinitro-2-methylphenol

1300

u

86-30-6

N-Nitrosodiphenylamine (1)

510

u

101-55-3

4-Bromophenyl-phenylether ¦

510

u

118-74-1

Hexachlorobenzene

510

u

1912-24-9

Atrazine

510

uJK

87-86-5

Pentachlorophenol

1300

u

85-01-8

Phenanthrene

510

u

120-12-7

Anthracene

510

u

86-74-8

Carbazole

510

u

84-74-2

Di-n-butylphthalate

510

u

206-44-0

Fluoranthene

510

V

129-00-0

Pyrene

510

u

8S-68-7

Butylbenzylphthalate

510

u

91-94-1

3,3"-Dichlorobenzidine

510

u

56-55-3

Benzo(a)anthracene

510

u

218-01-9

Chrysene

510

u

117-81-7

Bis(2-Ethylhexyl)phthalate

r/O -W



117-84-0

Di-n-octylphthalate

510

u

205-99-2

Benzo{b)fluoranthene

510

u

¦ 207-08-9

Benzo{k)fluoranthene

510

u

50-32-8

Benzo(a)pyrene

510

u

193-39-5

Indeno(1,2,3-cd)pyrene

510

u

53-70-3

Dibenzo(a,h)anthracene

510

u

191-24-2

Benzo 
-------
1G

SEMIVOLATILE ORGANICS ANALYSIS DATA SHEET
TENTATIVELY IDENTIFIED COMPOUNDS

EPA SAMPLE NO.

0485

J0KK8

Lab Name:. LAUCKS TESTING LABORATORIES
Lab Code: LAUCKS	Case No.: 29730

Contract: 68-W-00-Q75

SAS No.:

SDG No.

J0KH1

Matrix: (soil/water) SOIL	Lab Sample ID: 0109281-12

Sample wt/vol:	30	(g/mL) G	Lab Pile ID: L0926015.D

Level: (low/med) LOW	Date Received: 09/17/01

% Moisture:

35

Decanted:(Y/N) Y

Concentrated Extract	Volume: 500 (pL)
Injection Volume: 2 (/xL)
GPC Cleanup: (Y/N) Y pH: 7.0

Number TICs found:	30

Date Extracted: 09/19/01

Date Analyzed: 09/26/01

Dilution Factor: 1. 0

Extraction: (Type) PFSX

CONCENTRATION UNITS:

(fig/h or fig/Kg) UG/KG

CAS NUMBER

COMPOUND NAME

RT

EST.CONC.

G

1.

unknown organic acid

9.56

430

a*/

2.

120-40-1

Dodecanamide, N,N-bis(2-hydr

11.10

520

JN

3.

112-72-1

1-Tetradecanol

11.21

590

jn

4 .

- 544-63-8

Tetradecanoic acid

¦ 12.55

1200

JN

5.

1002-84-2

Pentadecanoic acid

13.22

1000

JN

6.

112-39-0

Hexadecanoic acid, methyl es

13.61

430

ON

7.

, 2091-29-4

9-Hexadecenoic acid'

13 .81

7600

JN

8.

57-10-3

Hexadecanoic acid

13.92

4500

JN

9.

unknown

14 .37

550

T J/

«/«

	

10.

unknown

14 .49

870



11.

112-80-1

Oleic Acid

14 .98

2200

JN

12.

unknown

15.93

2200

JM

13 .

57-11-4

Octadecanoic acid

16.16

440

JN

14 .

unknown

16.67

690

J4/

I5-

unknown

17.20

640

J/l/

16.

18435-45-5

1-Nonadecene

17.96

780

JN

17.

112-85-6

Docosanoic acid

18.43

540

JN

18.

638-66-4

Octadecanal

18.87

1000

JN

19.

629-96-9

1-Eicosanol

19.23

2000

JN

20.

unknown

19.56

1800

aft/

21,

unknown

19.56

580



22.

77899-10-6

(Z)14-Tricosenyl formate

20.03

1000

m

23.

10-Heneicosene (c,t)

20.41

1000

JN

24.

57-88-5

Cholesterol

20.91

1600

JN

25.

474-67-9

Ergosta-5,22-dien-3-ol, <3,b

21.22

510

JN

26.

83-47-6

.gamma.-Sitosterol

22.41

1300

JN

27.

unknown

22.94

520

1ft

28.

22611-26-3

D:C-Friedoolean-8-en-3-one

23 .09

1100

JN

29.

1058-61-3

Stigmast-4-en-3-one K

23.70

480

JN

3P i



"M 91

COO

jn U_













<¦>

0'

FORM I SV-TIC

bliM04 2 3 1 0

-------
IE

PESTICIDE ORGAN-ICS ANALYSIS DATA SHEET

EPA SAMPLE NO

.0486

J0KK8

Lab Name: LAUCKS,TESTING LABORATORIES
Lab Code: LAUCKS Case No.: 29730
Matrix: (soil/water) SOIL
Sample wt/vol: 30	(g/mL) G

% Moisture: 36	Decanted:(Y/N) Y

Extraction: (Type) PFEX
Concentrated Extract Volume: 5000 (uL)
Injection Volume: 1 (uL)

GPC Cleanup: (Y/N) Y pH: 7.0

Contract: 68-W-00-075

SAS No.:	SDG No.: J0KH1

Lab Sample ID: 0109281-12
Lab File ID: A930120.d
Date Received: 09/17/01
Date Extracted: 09/19/01
Date Analyzed: 10/01/01
Dilution Factor 1^

Sulfur Cleanup: (Y/N)N

CONCENTRATION UNITS:

CAS NO.

COMPOUND

(uq/L or uq./Kq) UG/KG Q

319-84-6

alpha-BHC

2.7

U

319-85-7

beta-BHC

2.7

U

319-86-8

delta-BHC

2.7

U

58-89-9

gamma-BHC (Lindane)

2.7

U

, 76-44-8

Heptachlor

2.7

U

309-00-2

Aldrin

2.7

U

1024-57-3

Heptachlor epoxide

2.7

U

959-98-8

Endosulfan I

2.7

U

60-57-1

Dieldrin

5.2

U

72-55-9

4,4'-DDE

5.2

U

72-20-8

Endrin

5.2

U

33213-65-9

Endosulfan II

5.2

U

72-54-0

4,4'-DDD

5.2

U

1031-07-8

Endosulfan sulfate

5.2

U

,150-29-3

4,4'-DDT

5.2

U

'72-43-5

Methoxychlor

27

u

53494-70-5

Endrin ketone

5.2

u

7421-93-4

Endrin aldehyde

5.2

u

5103-71-9

alpha-Chlordane

2.7

u

5103-74-2

gamma-Chlordane

2.7

u

8001-35-2

Toxaphene

270

u

12674-ll-r2

Aroclor-1016

52

u

11104-28-2

Aroclor-1221

100

u

11141-16-5

Aroclor-1232

52

u

53469-21-9

Aroclor-1242

52

u

12672-29-6

Aroclor-1248

52

u

11097-69-1

Aroclor-1254

52

u

11096-82-5

Aroclor-1260

52

u

OP

I0'



o

FORM I PEST

OLM04

5 61

-------
0487

^ p- PfttiffGX'- *5 V-!. H a n v; i r •¦"} Vr jr.i- r.i

»f!" International Specialists in the Environment

v : v c

2101 Fourth Avenue, Suite 1900, Seattle, WA 98121
Tel: (206) 624-9537, Fax: (206) 621 -9832

MEMORANDUM

DATE:
TO:
FROM:
SUB J:

REF:

July 24, 2001

Leatta Dahlhoff, Project Manager, E & E, Seattle, WA
Mark Woodke, START-Chemist, E & E, Seattle, WA/ ^

Organic Data Quality Assurance Review, Upper Columbia River Mines Site,
Northeast Washington

TDD: 01-02-0028

The data quality assurance review of 33 soil samples collected from the Upper Columbia River
Mines site located in Northeast Washington has been completed. Analysis for Total Organic Carbon
(Lloyd Kahn Method) was performed by the Ecology and Environment, Inc., Analytical Services Center,
Lancaster, New York.

The samnles were numbered:

ORSP01SD
VSPP01SD
PRTB03SD
POSP02SD
^
-------
0488

3.	Blanks: Acceptable.

A method, blank was analyzed at the required frequency of every 20 samples. There were no
detections in the method blanks above the method reporting limit.

4.	Laboratory Control Samples (LCS): Acceptable.

All LCS recoveries were within QC limits of 71% to 125%.

5.	Quadruplicate Analysis: Satisfactory.

All method quadruplicate results were within QC limits except the analysis of sample POBKOISD;
this outlier was due to matrix interferences. No action was taken based on the quadruplicate outlier
alone.

6.	Quantitation: Acceptable

TOC concentrations were correctly calculated.

7.	Laboratory Contact: Not Required
No laboratory contact was required.

8.	, Overall Assessment

The overall usefulness of the data is based on the criteria outlined in the analytical method. Based
upon the information provided, the data are acceptable for use with the above stated data qualifications.

Data Qualifiers and Definitions

J - The associated numerical value is an estimated quantity because the reported concentrations were
less than the sample quantitation limits or because quality control criteria limits were not met.

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue

0489

Laboratory Results

NYSELAPID#: 10486

Lancaster,

New York 14086-

Phone: (716)685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
: 0107001

Upper Columbia River Phase I
0107001 -01A Sample Type: SAMP

Client Sample ID: ORSP01SD
Alt. Client ID: ORSP01SD
Collection Date: 6/27/01 12:40:00 PM

Matrix: SOIL % Moist: 17.40

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

19500

2410 mg/Kg-dry

7/9/01

TOC 5050A SSM 010709

RLG

1. y

'ft

>0-



leflnitions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H • Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

IMS VenloD #: 3.1.1.9 - 7/6/01 2KXHJ0 PM



22

-------
0490

Ecology and Environment, Inc.	Laboratory Results

Analytical Services Center

4493 Walden Avenue	NYS ELAP ID#: 10486

Lancaster, New York 14086-	Phone:(716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: ORSP02SD



Lab Order:

0107001

Alt. Client ID: ORSP02SD



Project:

Upper Columbia River Phase I

Collection Date: 6/27/01 2:05:00 PM



Lab ID:

0107001-02A Sample Type: SAMP

Matrix: SOIL

% Moist: 32.70

Analyte	Result Q	Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon		19200	2850 mg/Kg-dry 1	7/9/01	TOC 5050A_SSM_010709 RLG

/

nh!\ \j\/

s~\

X^Jo\

Jeflnitions:

ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* • Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Sun - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

.IMS Version ft 3.1.1.9 - 7/6/01 2MM PM

iiiiav. Jiih 2fi. Kill	;'M

Pi

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0491

Laboratory Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: BBPP01SD



Lab Order:

0107001

Alt. Client ID: BBPP01SD



Project:

Upper Columbia River Phase I

Collection Date: 6/26/01 1:00:00 PM



Lab ID:

0107001-03A Sample Type: SAMP

Matrix: SOIL

% Moist: 11.40

Analyte Result Q

Limit Units

DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN







1_LK_TOC_S







Total Organic Carbon

3530

2160 mg/Kg-dry

7/8/01

TOC 5050A SSM 010709

RLG

1

efinltiont: ND - Not Detected at the Reporting Limit	*-Recovery outside limits	M -Matrix Spike recovery outside limits

J -Analyte detected below Reporting limits	R - RPD outside recovery limits	Q-Qualifier A -Result by Method of Std. Addition

B - Analyte detected in the associated Method Blank	E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

IMS VmlOQ ft 3.1.1.9 - 7/6/01 2AOOO PM

24

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0492

Laboratory Results

NYSELAPID#: 10486
Phone: (716) 685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-04A Sample Type: SAMP

Client Sample ID: BBPP02SD
Alt. Client ID: BBPP02SD
Collection Date: 6/26/01 1:05:00 PM

Matrix: SOIL % Moist: 51.20

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

56300

3930 mg/Kg-dry 1 7/9/01 TOC 5050A_SSM_010709 RLG

/ I V i

4 l/liIIV

^ \

~\ --i i \s A,

ednitions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

IMS VcnioD #: 3.1.1.9 - 7/6/01 2:00:00 PM

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

25

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0493

Laboratory Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
01070Q1-05A Sample Type: SAMP

Client Sample ID: P8DK01SD ~ 6 K O'l S£)

Alt. Client ID: POBK01SD
Collection Date: 6/25/01 3:50:00 PM

Matrix: SOIL % Moist: 40.90

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon		18800	3330 mg/Kg-dry 1	7/9/01	TOC 5050A_SSM_010709 RLG

HW

1-1 (L /II



itflnitfom: ND - Not Detected at the Reporting Limit	* - Recovery outside limits	M -Matrix Spite recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	q . Qualifier A -Result by Method of Std, Addition

B - Analyte detected in the associated Method Blank	E - Value above quantitation range	0. Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

IMS Vtnlon tk 3.1.1 J - 7/6/01 2:0030 PM

k'iiisv !»(y >1. KHH	«.*•

28

-------
• 0494

Ecology and Environment, Inc.	Laboratory Results

Analytical Services Center

4493 Walden Avenue
Lancaster, New York 14086-

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-06A Sample Type: SAMP

Client Sample ID: I'OCBOISR. f&CfcOiSij
Alt. Client ID: POCR01SD
Collection Date: 6/25/01 4:28:00 PM

Matrix: SOIL % Moist: 37.90

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon	36100	3100 mg/Kg-dry 1	7/9/01	TOC 5050A_SSM_010709 RLG

lnitions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method ofStd. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

S Version ft 3.1.1.9 - 7/&01 2:00:00 PM

'iVjl

27

-------
0495

Ecology and Environment, Inc.	Laboratory Results

Analytical Services Center

4493 Walden Avenue



NYSELAPID#: 10486

Lancaster,

New York 14086-



Phoire: {716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ED:

MJ0GL0

Lab Order:

0107001

Alt. Client ED:

PRRS01SD

Project:

Upper Columbia River Phase I

Collection Date:

6/25/01 11:00:00 AM

Lab ID:

0107001-09A Sample Type: SAMP

Matrix;

SOIL % Moist: 23.10

Analyte

Result Q

Limit Units DF

Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN





1_LK_TOC_S







Total Organic Carbon		7610	2500 mg/Kg-
-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

LaboratorjMffl&ults

NYS ELAP ID#: 10486
Phone: (716) 685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-10A Sample Type: SAMP

Client Sample ID: M J0GL1
Alt. Client ID: PRTB01SD
Collection Date: 6/25/01 12:00:00 PM

Matrix: SOIL % Moist: 64.50

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

74800O

11000 mg/Kg-dry 1 7/10/01 TOC 5050A_SSM_010710 RLG

I

/V'»A f

/	i

w



-Xk®

nitions; ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E • Value above quantitation range
Suit - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

¦ Venioo #: 3.1.1.9-7/6/01 2KXM0FM

:ou-

,31

-------
Ecology and Environment, Inc.

Analytical Services Ceuter
4493 Walden Avenue
Lancaster, New York 14086-

** Q497
Laboratory Results

NYSELAFID#: 10486
Phone:(716)685-8080

CL1ENT:
Lab Order;
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001 -11A Sample Type: SAMP

Client Sample ID: MJ0GL3
Alt. Client ID: PRRS02SD
Collection Date: 6/25/01 12:30:00 PM

Matrix: SOIL % Moist: 22.70

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

-

Total Organic Carbon

595 J

2520 mg/Kg-dry

7/1001

TOC 5050A_SSM_010?10

RLG

/Ma \ /

n\ic"tv. iu!- !!c>

.32

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0498

Laboratory Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: M J0GL4



Lab Order:

0107001

Alt. Client ID: PRTB02SD



Project:

Upper Columbia River Phase I

Collection Date: 6/25/01 1:45:00 PM



Lab ID:

0107001-12A Sample Type: SAMP

Matrix: SOIL

% Moist: 43.20

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
I LK TOC S

Total Organic Carbon

28900

3490 mg/Kg-dry

7/9/01

TOC5050A SSM 010709

RLG

/>

!\a

! Vv



I U

nltlons: ND - Not Detected at the Reporting Limit
i - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

3 Version*: 3.1.1.9-7/6/01 2:0000PM

.33

-------
Ecology and Environment, Inc.

Analytical' Services Center
4493 Walden Avenue
Lancaster, New York 14086-

" 0499
Laboratory Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:	E and E Seattle Office

Lab Order:	0107001

Project:	Upper Columbia River Phase I

Lab ID:	0107001-13A Sample Type: SAMP

Client Sample ID: MJ0GL5
Alt. Client ID: PRTB03SD
Collection Date: 6/25/01 2:15:00 PM
Matrix: SOIL

% Moist: 55.60

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

48200

4370 mg/Kg-dry

7/9/01

TOC 5050A SSM 010709

RLG

/l P ; /'

/ ' j i I I I

¦

^ "i

• ! y v ^ \

eflnltions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
6 - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E • Value above quantitation range
Sutt • Denotes Surrogate Compound

IMS Venton #: 3.1.1.9 - 7/6/01 2KXM0 PM

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

.34

:i*Ol

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0500

Laboratory Results

NYSELAPHM; 10486
Phone: (716) 685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-14A Sample Type: SAMP

Client Sample ID: MJ0GL6
Alt. Client ID: PRTB04SD
Collection Date: 6/26/01 10:10:00 AM

Matrix: SOIL % Moist: 63.30

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon	77300	5350 mg/Kg-dry 1	7/9/01	TOC S050A_SSM_010709 RLG

/~ j M.

' k!





initions: ND - Not Detected at the Reporting Limit	*-Recovery outside limits	M-Matrix Spike recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	Q-Qualifier A-Result by Method of Std. Addition

B - Analyte detected in the associated Method Blank E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

S Version #: 3.1.1.9 - 7/6® J 2:0000 PM

• riiifiv.; t'.lv y.),	2 : 'tv[

.35

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York J 4086-

Laboratory

Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: MJ0GL7



Lab Order:

0107001

Alt. Client ID: PRTB05SD



Project:

Upper Columbia River Phase I

Collection Date: 6/26/01 10:45:00 AM



Lab ID:

0107001-15A Sample Type: SAMP

Matrix: SOIL

% Moist: 22.30

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Cartoon

14100

2440 mg/Kg-dry

7/9/01

TOC 5050A SSM 010709

RLG

( wiv/

V

(

ifinitions: ND - Nol Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level ¦

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit • Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

MS Vent loo ft 3.1.1.9 - 7/6/01 2:00:00 PM

Vridsv. ;.;h "

*36

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

Laboratory

ts

NYS ELAP ID#: 10486
Phone: (716) 685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: M J0GL8



Lab Order:

0107001

Alt. Client ID: PRRS03SD



Project:

Upper Columbia River Phase 1

Collection Date: 6/26/01 11:40:00 AM



Lab ID:

0107001-16A Sample Type: SAMP

Matrix: SOIL

% Moist: 22.60

Analyte Result Q

Limit Units

DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN







1_LK_TOC_S







Total Organic Carbon

581 J

2450 mg/Kg-dry

7/9/01

TOC 505QA SSM 010709

RLG

r

/!/• i

I a

t \

^ I

finltions: ND - Not Delected at the Reporting Limit	* - Recovery outside limits	M -Matrix Spike recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	Q - Qualifier A -Result by Method of Std. Addition

B - Analyte detected in the associated Method Blank	E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H • Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

US Version fc 1.1,1.9 - 7/6/01 2.iXK» PM



-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0503

Laboratory Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-17A Sample Type: SAMP

Client Sample ID: MJ0GM0
Alt. Client ID: POPP02SD
Collection Date: 6/26/01 1:40:00 PM

Matrix: SOIL % Moist: 53.50

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

1 46100

4120 mg/Kg-dry 1 7/W01 TOC 5050A_SSM_01070S RLG

^ A

/If

w /

-n

^M\

eflnltions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

IMS Vtrtkra U: 3.1.1.9 - 7/6/01 2:00:00 PM

M-hiav. -u'v	.VitfoK ;-|vj.

738

-------
Ecology and Environment, Inc.

Analytical Services Center

< 0504
Laboratory Results

4493 Walden Avenue
Lancaster, New York 14086-



NTS ELAP ID#: 10486
Phone: (716) 685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-18A Sample Type: SAMP

Client Sample ID: MJ0GM2

Alt. Client ID: POPP03SD
Collection Date: 6/26/01 2:25:00 PM
Matrix: SOIL

% Moist: 16.80

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

541 J

2300 mg/Kg-dry

7/W01

TOC 5050A SSM 010709

RLG

ffjW

"Cr 1

Tnitions: ND - Not Detected at the Reporting Limit	• - Recovery outside limits	M -Matrix Spike recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	Q-Qualifier A-Result by Method of Std. Addition

B - Analyte detected in the associated Method Blank	E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

IS Veroion (fe 3.1.1,9 - 716/0} 2KKMO PM

39

-------
Ecology and Environment, Inc.

AiiSlyiiCd 1 Services Center
4493 Waiden Avenue
Lancaster, New York 14086-

0505

Laboratory Results

NYSELAPID#: 10486
Phone: (716) 685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-19A Sample Type: SAMP

Client Sample ID: MJ0FK5
Alt. Client ID: POSP02SD
Collection Date: 6/26/01 9:35:00 AM

Matrix: SOIL % Moist: 26.20

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Cartoon

36100

2600 mg/Kg-dry 1 7/3/01 TOC 5050A_SSM_010709 RIG

j

definitions: ND - No! Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

.IMS Version #: 3.1.1.9 - 7/6/01 2.-OOK10 PM

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std, Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

Vriiiay.

Ov 2rV. ?:07:Oi :1M*"

40

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

CLIENT:
Lab Order:
-Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-20A Sample Type: SAMP

0506

Laboratory Results

NYSELAPID#: 10486
Phone: (716) 685-8080

Client Sample ID: MJ0FL7
Alt. Client ID: POSPOlSD
Collection Date: 6/26/01 9:11 ;OG AM
Matrix: SOIL

% Moist: 25.00

Analyte Result Q

Limit Units

DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN







1_LK_TOC_S







Fotal Organic Cart>on 62000

5100 mg/Kg-dry

1 7/10/01 TOO 5Q5QA_SSM_010710

RIG

f flft \il /

r U 11/

i



flnitiont: ND - Not Detected at the Reporting limit
1 - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

• - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D • Diluted due to matrix or extended target compounds
N - Single Column Analysis

4S Vcriion *; 3.1,1.9 - 7/6/01 2:0000 PM

> ndav. .1 ui-: '-**11	,

.41

-------
0507

Ecology and Environment, Inc.	Laboratory Results

Analytical Services Center

4493 Walden Avenue	NYSELAPED#: 10486

Lancaster, New York 14086-	Phone:(716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: PRTB10SD

-

Lab Order:

0107001

Alt. Client ID: PRTB10SD



Project:

Upper Columbia River Phase I

Collection Date: 6/28/01 2:55:00 PM



Lab ID:

0107001-21A Sample Type: SAMP

Matrix: SOIL

% Moist: 25.90

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon	 1520 J	2630 mg/Kg-dry 1	7/10/01	TOC 5050A_SSM_010?10 RLG

!

py

leflnitions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Repotting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis w

IMS Vereion #: 3.1.1.9 - VS/01 2GOXK) PM



42

r Pu£v :>>h- W<;-.s5 • -*• ^

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

. - 0508
Laboratory Results

NYS ELAP ID#: 10486
Phone: (716) 685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: JOPP01SD



Lab Order:

0107001

Alt. Client ID: JOPP01SD



Project:

Upper Columbia River Phase I

Collection Date: 6/28/01 9:35:00 AM



Lab ID:

0107001-22A Sample Type: SAMP

Matrix: SOIL

% Moist: 11.40

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

1050 J

4420 mg/Kg-dry

7/10/01

TOC 5050A SSM 010710

RLG

flnltioDs:

ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

IS Veriton th 3.1.1.9 -116/01 2MW0 PM

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds

N - Single Column Analysis



"43

-------
*

Ecology and Environment, Inc.	Laboratory Results

Analytical Services Center

4493 Walden Avenue	NYS ELAP ID#: 10486

Lancaster, New York 14086-	Phone:(716) 685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: POBK01SD



Lab Order:

0107001

Alt. Client ID: POBK01SD



Project:

Upper Columbia River Phase I

Collection Date: 6/27/01 1:00:00 PM



Lab ID:

0107001-23A Sample Type: SAMP

Matrix: SOIL

% Moist: 27.80

Analyte			Result Q	Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon	 13700	4780 mg/Kg-dry 1	7/10/01	TOC5050A_SSM_010710 RLG

Definitions:

ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D • Diluted due to matrix or extended target compounds
N - Single Column Analysis

.IMS Veriion #: 3.1.1.9 - 7/6/01 2.0030 PM

rHJgv. July J--'. I:i'H; J:ii?:»!i-S i'fvl



-------
Ecology and Environment, Inc.
Analytical Services Center

0510

Laboratory Results

4493 Walden Avenue

NYS ELAP ID#: 10486

Lancaster,

New York 14086-

Phone: (716) 685-8080

CLIENT:
Lab Order:

E and E Seattle Office
0107001

Client Sample ID: P0PPWSD" Crrf

Alt. Client ID: POPP04SD ^

Project:

Upper Columbia River Phase I

Collection Date: 6/27/01 12:10:00 PM

Lab ID:

0107001-24A Sample Type: SAMP

Matrix: SOIL % Moist: 29.30

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN



1_LK_TOC_S



Total Organic Carbon		8670	4560 mg/Kg-dry 1	7/10/01	TOC 5050A_SSM_010710 RLG

! / ! : i r

;/ m
/¦/'; 1a .

j ""i t y ¦



finliions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denote Suirogate Compound

IS Vcnkn #: 3,1.1.9 - 7/6/01 2KXhO0 FM

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds

N - Single Column Analysis



l-j ;fv1

.45

-------




* 0511

Ecology and Environment, Inc.

Laboratory Results

Analytical Services Center

4493 Walden Avenue

NYS ELAP ID#: 10486

Lancaster, New York 14086-

Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: PQPP059D

Lab Order:

0107001

Alt. Client ID: POPP05SD

Project:

Upper Columbia River Phase I

Collection Date: 6/27/01 12:35:00 PM

Lab ID:

0107001-25A Sample Type: SAMP

Matrix: SOIL % Moist: 14.10

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN



1_LK_TOC_S





Total Organic Carbon	10200	2320 mg/Kg-dry 1	7/10/01	TOC 5050A_SSM_010710 RLG

nw

LOU

A
0 »

jfinltforu: ND- Not Detected at the Reporting Limit	*- Recovery outside limits	M -Matrix Spike recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	Q. Qualifier A -Result by Method of Std. Addition

B - Analyte detected in the associated Method Blank	E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

CLIENT:

E and E Seattle Office

Client Sample ID: PRBK01SD

Lab Order:

' 0107001

Alt. Client ID: PRBK01SD

Project:

Upper Columbia River Phase I

Collection Date: 6/28/01 l;55:OOPM

Lab ID:

0107001-26A Sample Type: SAMP

Matrix: SOIL % Moist: 15,30

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

FOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
!_LKTOC_S

Total Organic Carbon	2570	2300 mg/Kg-dry 1	7/10/01	TOC 5050a_SSm_Q10710	RIG

0512

Laboratory Results

NYS ELAP ID#: 10486
Phone: (716)685-8080

W

initiom: ND - Not Detected at the Reporting Limit
J - Analyse detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denotes Surrogate Compound

M •Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

-4nh

S Verfton #: 3.1.1.9 - 7/63H 2.-0Q30 PM

i rkiay, Ji«?; :;ii.

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0513

Laboratory Results

NYSELAFID#: 10486
Phone; (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: PRBK02SD



Lab Order:

0107001

Alt. Client ID: PRBK02SD



Project:

Upper Columbia River Phase 1

Collection Date: 6/28/01 2:05:00 PM



Lab ID:

0107001-27A Sample Type: SAMP

Matrix: SOIL

% Moist: 27.50

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

7090

2760 mg/Kg-dry

7/10/01

TOC 5050A SSM 010710

RLG

qoif0

>efinltlon»: ND - Not Detected at the Reporting Limit
J»Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

.IMS VeniOB ft 3.1.1.9 - 7/6/01 2.00:00 PM

. ;tik "/fit:!	I-J !'M

48

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

* 0514

Laboratory Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:
Lab Order:
Project:
Lab ID:

E and E Seattle Office
0107001

Upper Columbia River Phase I
0107001-28A Sample Type: SAMP

Client Sample ID: PRBK03SD
Alt. Client ID: PRBK03SD
Collection Date: 6/28/01 2:15:00 PM

Matrix: SOIL

% Moist: 20.90

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LKTOC_S

Total Organic Carbon

4550

2470 mg/Kg-dry

7/10/01

TOC 5050A SSM 010710

RLG

)eflnltions: ND - Not Detected at the Reporting Limit	*-Recovery outside limits	M-Matrix Spike recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	Q-Qualifier A-Result.by Method of Std. Addition

B - Analyte detected in the associated Method Blank	E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

IMS Version #: 3.1.1.9 - 7/6/01 2MOO PM

I riuAv. Jul*- 21 ^?fi I'M

-------
Ecology and Environment, Inc.	LaboratoP^ttesults

A nnln^inril CmniiAnx 	^ _

¦ ft /¦ l k l II jj ¦ ¦— - -1 : . Sm S A K Ta S*

4493 Walden Avenue	NYS ELAP ID#: 10486

Lancaster, New York 14086-	Phone:(716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: PRRS04SD



Lab Order:

0107001

Alt. Client ID: PRRS04SD



Project:

Upper Columbia River Phase I

Collection Date: 6/27/01 11:45:00 AM



Lab ID:

0107001-29A Sample Type: SAMP

Matrix: SOIL

% Moist: 43.30

\

Analyte	Result Q	Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon		45600	3530 mg/Kg-dry 1 ' 7/10/01	TOC 5050A_SSM_010710 RLG

i

q>%,|

>eflnltlons: ND - Not Detected at the Reporting Limit	• - Recovery outside limits	M -Matrix Spike recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	Q. Qualifier A -Result by Method of Std. Addition

B - Analyte detected in the associated Method Blank	E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

IMS Vcrtioo fc 3.1.1.9 - 7/6/01 2^XhOO PM

Vriiiay.-uK	17 t'*M

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0516

Laboratory Results

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: PRTB06SD



Lab Order:

0107001

Alt. Client ED: PRTB06SD



Project:

Upper Columbia River Phase I

Collection Date: 6/27/01 5:15:00 PM



Lab ID:

0107001-30A Sample Type: SAMP

Matrix: SOIL

% Moist: 31.20

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

5490

2800 mg/Kg-dry

7/10/01

TOC5050A SSM 0107T0

RLG

w

¦-P

1

%)(

rinitlons:

ND - Not Detected at the Reporting Limit
i - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

IS Version#: 3.1,1.9 - 7/6/01 2:0000 PM

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

> rnia

51

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

Laboratory Results

NYS ELAP ID#: 10486
Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: PRTB07SD



Lab Order:

0107001

Alt. Client ID: PRTB07SD



Project:

Upper Columbia River Phase I

Collection Date: 6/27/01 6:05:00 PM



Lab ID:

0107001-31A Sample Type: SAMP

Matrii: SOIL

% Moist: 30.70

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1_LK_TOC_S

Total Organic Carbon

38100

2850 mg/Kg-dry 1

7/10/01

TOC 5050A_SSM 010710

RLG



>efinltions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B • Analyte detected in the associated Method Blank
H • Value exceeds Maximum Contaminant Level

* . Recovery outside limits
R • RPD outside recovery limits
E - Value above quantitation range
Surt - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

JMS VentoB »; 3.1.1.9 - 7/6*01 2.-0030 PM

S.fi

.52

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

Laboratory M

esults

NYSELAPID#: 10486
Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ID: PRTB08SD



Lab Order:

0107001

Alt. Client ID: PRTB08SD



Project:

Upper Columbia River Phase I

Collection Date: 6/28/01 12:35:00 PM



Lab ID:

0107001-32A Sample Type: SAMP

Matrix: SOIL

% Moist: 21.60

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1 LK TOC S

Total Organic Carbon

599 J

2500 mg/Kg-dry

7/10/01

TOC 5050A SSM 010710

RLG

:finltions: ND - Not Detected at the Reporting Limit
J - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Surr - Denotes Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Std. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

US VentoD #: 3.1.1.9 - 7/6/01 2KKMX3 PM

53

-------
Ecology and Environment, Inc.

Analytical Services Center
4493 Walden Avenue
Lancaster, New York 14086-

0519

Laboratory Results

NYS ELAP ID#: 10486
Phone: (716)685-8080

CLIENT:

E and E Seattle Office

Client Sample ED: PRTB09SD



Lab Order:

0107001

Alt. Client ID: PRTB09SD



Project:

Upper Columbia River Phase I

Collection Date: 6/28/01 1:10:00 PM



Lab ID:

Q107001-33A Sample Type: SAMP

Matrix: SOIL

% Moist: 22.90

Analyte

Result Q

Limit Units DF Date Analyzed Run Batch ID

Analyst

TOTAL ORGANIC CARBON BY METHOD LLOYD KAHN
1 LK TOC S

Total Organic Carbon

4270

2590 mg/Kg-dry

7/10/01

TOC 5050A_SSM 010710

RLG

•O n



>eflnitions: ND • Not Detected at the Reporting Limit
i - Analyte detected below Reporting limits
B - Analyte detected in the associated Method Blank
H - Value exceeds Maximum Contaminant Level

* - Recovery outside limits
R - RPD outside recovery limits
E - Value above quantitation range
Suit - Denote Surrogate Compound

M -Matrix Spike recovery outside limits
Q - Qualifier A -Result by Method of Sid. Addition
D - Diluted due to matrix or extended target compounds
N - Single Column Analysis

IMS Vein km #: 3.1,1.9 . 7/6/01 2«M» PM

J4 !

54

-------
0520

ecology ana environment, mc,

International Specialists in the Environment

2101 Fourth Avenue, Suite 1900, Seattle, WA 98121
Tel; (206) 624-9537, Fax: (206) 621-9832 ¦

MEMORANDUM

DATE;

TO:
FROM:
SUB J:

REF:

October 5,2001

Leatta Dahlhoff, Project Manager, E & E, Seattle, WA

Mark Woodke, Chemist, E & E, Seattle, WA

Total Organic Carbon Data Quality Assurance Review,

Upper Columbia River Mines/Mills ESI, Stevens & Pend Oreille Counties,

WA

TDD: 01-02-0028

PAN: 00128l.0073.01SR

The data quality assurance review of 23 sediment samples collected from the Upper
Columbia River Mines/Mills ESI in Stevens and Pend Oreille Counties, Washington, has been
completed. Total Organic Carbon (TOC) analysis (Method Lloyd Kahn) was performed by the
Ecology and Environment, Inc., Analytical Services Center, Lancaster, New York.

The samples were numbered:

01090401
01090407
01090413
01090431

01090402
01090408
01090426
01090432

01090403
01090409
01090427
01090441

01090404
01090410
01090428
01090442

01090405
01090411
01090429
01090443

01090406
01090412
01090430

Data Qualifications:

1.	Sample Holding Times: Acceptable.

The samples maintained within the QC limits of 4*C + 2*C. The samples were collected
between September 10 and 13,2001, and were analyzed by September 25,2001, therefore
meeting QC holding time criteria.

2.	Calibration: Acceptable.

A four-point initial calibration was performed prior to each analysis sequence with a
correlation coefficient > 0.995. A minimum of one calibration standard and a blank were
analyzed after every 10 samples with all recoveries within the QC limits of 90 % to 110 %.

3.	Blanks: Satisfactory.

A preparation blank was analyzed for each 20 samples or per matrix per concentration
level. Blanks were analyzed after each initial or continuing calibration. There were the
following detections in method blanks:

recycled paper

-------
0521

Batch / Date

Analyte

Concentration

010924101R/9-24-01

TOC

600 mg/kg

010925101R / 9-25-01

TOC

300 mg/kg

Sample results less than five times the associated blank concentration were qualified as
not detected (U).

4.	Laboratory Control Sample (LCS): Acceptable.

A LCS was analyzed with each batch of 20 samples with all recoveries within QC limits
of 71 %to 125 %.

5.	Quadruplicate Analysis: Acceptable.

A quadruplicate analysis was performed per 20 samples per matrix. Both sets of
quadruplicate results had relative percent differences greater than the QC limit of < 30 %. No
action was taken based on these outliers as the initial sample results were less than two times the
sample quantitation limit.

6.	Overall Assessment of Data for Use

The overall usefulness of the data is based on the criteria outlined in the OSWER
Guidance Document "Quality Assurance/Quality Control Guidance for Removal Activities,
Sampling QA/QC Plan, and Data Validation Procedures" (EPA/540/G-90/004) and the analytical
method. Based upon the information provided, the data are acceptable for use with the above
stated data qualifications.

Data Qualifiers and Definitions

U - The material was analyzed for but was not detected. The associated numerical value is
the sample quantitation limit.

J - '1 The associated numerical value is an estimated quantity because the reported

concentrations were less than the practical quantitation limits or because quality
control criteria limits were not met.

The following bias qualifier was added to estimated quantities:
Q - The sample result is less than the sample quantitation limit.,

-------
Ecology and Environment, Inc.

nalvtical Services Center
•93 Walden Avenue
incaster, New York 14086-

0522 -
Laboratory Results

ft/

NYS ELAP ID#: 10486
Phone: (716) 685-8080

ient: E and E Seattle Office
>b Order: 0109123

oject: Upper Columbia River Phase I

•b ID: 0109123-04A Sample Type: SAMP

Matrix: Soil

Client Sample ID: 01090441
Alt. Client ID: MDSB01SD
Collection Date: 9/12/01 9:30:00 AM

Test Code: 1_LK_TOC_S

% Moist:33.70

5TAL ORGANIC CARBON BY METHOD LLOYD KAHN

Method: LLOYD KAHN Prep Method: NA

lalvte

Result Q

Limit Units DF Date Analyzed Run Batch ID

Analyst

la I Organic Carbon

17100

2760 mg/Kg-dry

9/24/01

TOC5050A SSM 010924

MYO

¦itions: ND - Not Delected at the Reporting Limit	*- Recovery outside limits	M -Matrix Spike recovery outside limits

J - Analyte detected below Reporting limits	R - RPD outside recovery limits	Q-Qualifier A-Result by Method of Std. Addition

B - Analyte detected in the associated Method Blank E - Value above quantitation range	D - Diluted due to matrix or extended target compounds

H - Value exceeds Maximum Contaminant Level	Surr - Denotes Surrogate Compound	N - Single Column Analysis

-------
0523 '¦?

UNITED STATES ENVIRONMENTAL PROTECTION AGENCY
REGION 10 LABORATORY

7411 Beach Dr. East
Port Orchard, Washington 98366

July 25, 2001

MEMORANDUM

SUBJECT: Field Screening Metals Results, for the Upper Columbia
Riven - Mining Area Analyses

FROM: Gerald H. Dodo
US EPA

TO:	Monica Tonel

USEPA

cc:	Leatta Dahlhoff

Ecology and Environment

Attached to this memo are the field screening analysis
results for lead, zinc, and mercury acquired by ESAT for 84
samples at the Upper Columbia River mining areas. This work was
performed under site account code 01T10P50102D106XLA00. The
samples were analyzed in-situ using a Niton XL-723. Reference
sample ^nalyses were performed during each day of sample analyses
using NIST SRM 2710. The reference sample results were within
20% of the stated true value, however, mercury was present at a
concentration too low to be detected for this sample. All
results were qualified F, acquired by a field screening method.

If you have any questions, please contact me at (360)871-

8728.

/ ^ \

"7*7 67

i

II

Iff

USEPA8F

1133724

-------
0524

'Summary of XRF Screening.Results
Lake Roosevelt Mine Study

Results in mg/Kg

No Location

Sample ID

Date/Time

2n^Pb

Hg

6 Red Top Rock Pile



6/18/01

1720 £ 758 *



<26

7 Red Top Rock Pile

RDWR01SS

6/18/01

12896

15091



<96

8 Red Top Rock Pile



6/18/01

600

187



<18

9 Red Top Rock Pile

RDWR02SS

6/18/01

24589

8275



158

10 Red Top Rock Pile

RDWR03SS

6/18/01

7136

2640



<53

17 Copper King WR

CKWR01SS

6/19/01

434

327



<34

18 Copper, King WR



6/19/01

159

103



<23

19 Copper King WR

CKWR02SS

6/19/01

<225

01*5



<37

20 Copper King WR



6/19/01

<240

121



<45

21 Copper King WR



6/19/01

< 144

173



<29

23 Black Rock Mine

BRWR01SS

6/19/01

181965

3709



216

24 Black Rock Mine

BRWR02SS

6/19/01

126976

698



<93

25 Black Rock Mine



6/19/01

12499

44



<31

26 Black Rock Mine



6/19/01

40294

417



<48

27 Black Rock Mine

BRWR03SS

6/19/01

358810

1130



286

32 Last Chance TP

LCTP05SS

6/20/01

124928

84070



<360

33 Last Chance TP

LCTP06SS

6/20/01

99994

41984



<270

34 Last Chance TP



6/20/01

43699

16192



<116

35 Last Chance Interfac LCTP07SS

6/20/01

26394

7578



<85

36 Last Chance TP



6/20/01

21094

10694



<82

49 Great Western



6/21/01

39475

2570



75

50 Great Western

GWWR02SS

6/21/01

48077

3978



<70

51 Great Western



6/21/01

16691

1890



<42

53 Great Western



6/21/01

20595

1880



<48

54 Great Western



6/21/01

97792

10995



<195

55 Great Western

GWWR01SS

6/21/01

38784

2890



<74

57 Gladstone TP

GLTP01SS

6/21/01

14989

43085



<210

58 Gladstone TP



6/21/01

8608

18099



<134

59 Gladstone TP

GLTP02SS

6/21/01

17894

53965



<285

60 Gladstone TP



6/21/01

15898

30285



<195

61 Gladstone TP

GLTP03SS

6/21/01

16294

44493



<300

71 Electric Point Upper



6/22/01

1030

3920



<58

72 Electric Point Upper EPWR03SS

6/22/01

1810

4867



<44

73 Electric Point Upper



6/22/01

1380

3808



<41

74 Electric Point Upper EPWR02SS

6/22/01

2739

4218



<75

75 Electric Point Upper EPWR01SS

6/22/01

2789

4067



<48

77 Electric Point Lower



6/22/01

12096

10298



<94

78 Electric Point Lower

EPWR07SS

6/22/01

32589

, 17600

/

147

79 Electric Point Lower

EPWR08SS

6/22/01

23693^

f 19098)

/

<195



-------
No Location

Sample ID

Date/Time

Zn

Pb

Hg











85 Van Stone Mine



6/23/01

8467 f

379 f

<27

87 Van Stone Mine

VSWR01SS

6/23/01

17293

1440

<45

88 Van Stone Mine



6/23/01

1520

62

<17

90 Van Stone Mine



6/23/01

236

30

<14

91 Van Stone Mine

VSWR02SS

6/23/01

6944

344

<28

92 Van Stone Mine



6/23/01

5059

91

<25

94 Van Stone Mine



6/23/01

112

43

<13

95 Van Stone Mine

VSWR03SS

6/23/01

5827

154

<29

96 Van Stone Mine



6/23/01

3290

271

<24

97 Van Stone Mine



6/23/01

2629

299

<21

98 Van Stone Mine



6/23/01

5878

363

<27

99 Van Stone Mine

VSWR04SS

6/23/01

10797

847

<44

100 Van Stone Mine

VSWR05SS

6/23/01

11898

1730

<49

101 Van Stone Mine



6/23/01

4048

143

<26

102 Van Stone Mine



6/23/01

3920

687

<37

104 Van Stone Mine



6/23/01

18394

2210

<63

105 Van Stone Mine

VSWR06SS

6/23/01

34586

3878

<74

106 Van Stone Mine



6/23/01

29082

2629

<64

107 Van Stone Mine



6/23/01

4029

879

<28

108 Van Stone Mine

VSWR07SS

6/23/01

20890

6739

<68

109 Van Stone Mine

VSWR08SS

6/23/01

5600

361

<37

110 Van Stone Mine



6/23/01

5389

133

<24

112 Van Stone Mine



6/23/01

4730

128

<26

113 Van Stone Mine



6/23/01

4067

jt a r%

1 IO

<30

114 Van Stone Mine

VSWR09SS

6/23/01

5040

61

<20

115 Van Stone Mine



6/23/01

4490

331

<24

116 Van Stone Mine



6/23/01

3398

738

<44

117 Van Stone Mine

VSWR10SS

6/23/01

3760

796

<51

118 Van Stone Mine



6/23/01

3210

1300

<39

119 Van Stone Mine



6/23/01

3930

1540

<44

120 Van Stone Mine

VSWR11SS

6/23/01

3160

221

<25

121 Van Stone Mine



6/23/01

5139

<24

<19

122 Van Stone Mine



6/23/01

502

38

<20

123 Van Stone Mine

VSWR12SS

6/23/01

2939

906

<35

124 Van Stone Mine



6/23/01

3099

243

<23

125 Van Stone Mine



6/23/01

944

95

<36

133 Pend Oreille TP

POTP04SS

6/25/01

852

396

<21

134 Pend Oreille TP



6/25/01

648

413

<17

135 Pend Oreille TP



6/25/01

647

298

37

137 Pend Oreille TP



6/25/01

991

410

<24

138 Pend Oreille TP



6/25/01

595

416

<26

139 Pend Oreille TP

POTP05SS

6/25/01

1709

592

<30

141 Pend Oreille TP

POTP06SS

6/25/01

1890

612

<36

142 Pend Oreille TP •



6/25/01

973

381

<30

143 Pend Oreille TP



6/25/01

66K

/ 240,

/ <24

-------
0526





.Jr

V->

JliSfc

4
,:W
¦£' ¦





APPENDIX E

MYERS DAM DAT

#



M:

iiilei*





#



10:START-2\01080009VS714

-------
0527

Appendix E

MEYERS DAM SEDIMENT SAMPLE
ANALYTICAL RESULTS SUMMARY
LOWER PEND OREILLE RIVER
EXPANDED SITE INSPECTION
PEND OREILLE COUNTY. WASHINGTON

EPA Sample ID

01374222

CLP Inorganic ID

MJ0KK8

CLP Organic ID

J0KK8

E&E Sample ID

01090123

Station Location

MDSB01SD

TAL Metals (mg/kg)

Aluminum

7980

Barium

114

Calcium

11900 JK

Chromium

11.0

Copper

10.2

Iron

13500

Lead

12.9

Magnesium

6010

Manganese

252

Zinc

52.5

Total Organic Carbon (mg/kg)

TOC

17100

Note: Bold type, indicates the sample concentration is above the detection limit.

Key:

CLP	= Contract Laboratory Program,

E&E	a Ecology and Environment, Inc.

EPA	= United States Environmental Protection Agency.

ID	= Identification.

J	= The analyte was positively identified. The associated numerical value is an estimate.

K	= Unknow bias.

MD	= Meyets Dam.

-mgfkg	= milligrams per kilogram.

SB	= sand bar.

SD	= sediment,

TAL.	= Target Analyte List,

TOC	= Total Organic Carbon.

-------






.&M-	/a>	m

METALINE FALLS MUNICIPAL WATER INTAKE DATA

W

APPENDIX F ^&£sg»as;t'

M

^llllfS



J&

?:
-------
0529

Appendix F

METALINE FALLS MUNICIPAL WATER INTAKE
SURFACE WATER SAMPLES ANALYTICAL RESULTS
LOWER PEND OREILLE RIVER
EXPANDED SITE INSPECTION
PEND OREILLE COUNTY. WASHINGTON

EPA Sample Number

01264429

01264430

CLP Inorganic ID

MJ0GN8

MJ0GN9

CLP Organic ID

NU

NU

E & E Sample ID

NU

NU

Station Location

MFOISW

MF02SW

TAL Metals fyig/L)





Aluminum

IJ2JB

149 JB

Antimony

' 2.5 U

2.5 U

Arsenic

2.6 U

2.6 U

Barium

13.2 JB

14.7 JB

Beryllium

0.3 U

0.3 U

Cadmium

0.6 U

0.6 U

Calcium

24500

27300

Chromium

0.6 U

0.6 U

Cobalt

1 U

1 U

Copper

1 U

1 UJK

Iron

44.4 U

34.8 U

Lead

2.8 U

2.8 U

Magnesium

8900

9560

Manganese

6 JB

3.7 JB

Mercury

0.1 U

0.1 U

Nickel i

1.1 U

hi u

Potassium

792 JB

889 JB

Selenium

2 U

2 U

Silver 1,

0.5 UJK

0.5 UJK

Sodium

2200 U

2790 U

Thallium

3.4 U

3.4 U

Vanadium

1 U

1.6 JB

Zinc

3.9 JB

0.65 JB

Note: Bold type indicates the sample concentration is above the detection limit.

= Contract Laboratory Program.

= Domestic water intake.

= Ecology and Environment, Inc.

= Identification.

= micrograms per liter.

= Not utilized.

= surface water.

= The analyte was not detected. The associated numerical value is the contract required detection limit.
= The analyte was positively identified. The associated numerical value is an estimate.

= The reported concentration is between the instrument detection limit and the contract required detection limit.
= United States Environmental Protection Agency.

= Unknown bias.

Key:

CLP

DW

E&E

ID

ngfl-
NU

sw
u

J

B

EPA
K

-------
• *

0530





jr* l®iif®tl%. J

flPPENDIX

WESTON'S TRIP REPORT

4is

*g$»Z
#2#'

'£$*

**.



X	« V^T v*i-,

*t ^4 ^:? ¦«¦'<•>.c'"'

-iV'
*; %*»

\-
-------